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Home My WebLink AboutNC0021962_625 Compound Scan_20191121Action History (UTC-05:00) Eastern Time (US & Canada) Submit by Anonymous User 11/21/2019 8:57:21 AM (Supplemental Submittal) Submit by Bennett, Bradley 1/7/2020 9:27:50 AM (Supplemental Info Submittal) • Bennett, Bradley assigned the task to Bennett, Bradley 1/7/2020 9:26 AM • The task was assigned to Thedford, Wren, Bennett, Bradley 11/21/2019 8:57 AM Initial Review Information Updated ID#:* IWORTANf:FEVIBAERSHOLLDVERIFY and revise here ifnecessary. NC0021962 How should this project be handled?* r File r Discard Information Submitted on 11/21/2019 Submitter Information Name: James Utke Vft is subrritting the inforrretion? Email Address:* jutke@citgo.com Submittal Information The Division of Water Resources (DWR) is providing this site to allow for the upload of required supplemental information associated with discharge monitoring reports (DMR). All DMR data is required to be submitted electronically through the eDMR system and should not be submitted here. Division staff will reviewall uploaded documents and will only maintain required information. Documents such as laboratory reports are not required to be submitted and will not be maintained in the system. Project Information: Rease SUDDly the Dernit nun ber for this Existing ID#* PerrritNurrber NC0021962 Exarrples: NOKxxxxxx or NO&xxxxx Facility Name:* CITGO Petroleum Corporation County: Mecklenburg Please upload all files that need to be submited. * Gick the upload button or drag and drop files here to attach docurrent L 1153378. pdf 1.16MB Only pdf files are accepted. Comments about the attachments: 625Compound Scan Submittal * V By checking the box and signing box below, I certify that: o I have given true, accurate, and complete information on this form; • I agree that submission of this Supplemental Information form is a "transaction" subject to Chapter 66, Article 40 of the NC General Statutes (the "Uniform Electronic Transactions Act) • I agree to conduct this transaction by electronic means pursuant to Chapter 66, Article 40 of the NC General Statutes (the "Uniform Electronic Transactions Act'); • I understand that an electronic signature has the same legal effect and can be enforced in the same way as a written signature; AND • I intend to electronically sign and submit the Supplemental Information form." Full Name: James Earl Utke Signature: Date Submitted: 11/21/2019 ANALYTICAL REPORT October 30, 2019 CITGO-Charlotte, NC Sample Delivery Group:L1153378 Samples Received:10/24/2019 Project Number:SEMIANN Description:treated stormwater Report To:Mr. Jim Utke 7600 Mount Holly Road Charlotte, NC 28214 Entire Report Reviewed By: October 30, 2019 [Preliminary Report] Stacy Kennedy Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided, and as the samples are received. 12065 Lebanon Rd Mount Juliet, TN 37122 615-758-5858 800-767-5859 www.pacenational.com 1 Cp 2 Tc 3 Ss 4 Cn 5 Sr 6 Qc 7 Gl 8 Al 9 Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/30/19 09:10 1 of 14 October 31, 2019 Cassandra Foster Project Manager ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/31/19 09:51 1 of 14 ONE LAB. NATIONWIDE.TABLE OF CONTENTS Cp: Cover Page 1 Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 4 Sr: Sample Results 5 OUTFALL 001 L1153378-01 5 Qc: Quality Control Summary 7 Semi Volatile Organic Compounds (GC/MS) by Method 625.1 7 Gl: Glossary of Terms 12 Al: Accreditations & Locations 13 Sc: Sample Chain of Custody 14 1 Cp 2 Tc 3 Ss 4 Cn 5 Sr 6 Qc 7 Gl 8 Al 9 Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/30/19 09:10 2 of 14 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/31/19 09:51 2 of 14 ONE LAB. NATIONWIDE.SAMPLE SUMMARY Collected by Collected date/time Received date/time OUTFALL 001 L1153378-01 WW Rob Durham 10/23/19 10:15 10/24/19 08:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Semi Volatile Organic Compounds (GC/MS) by Method 625.1 WG1369707 1.05 10/28/19 07:03 10/28/19 22:51 LEA Mt. Juliet, TN 1 Cp 2 Tc 3 Ss 4 Cn 5 Sr 6 Qc 7 Gl 8 Al 9 Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/30/19 09:10 3 of 14 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/31/19 09:51 3 of 14 ONE LAB. NATIONWIDE.CASE NARRATIVE All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. [Preliminary Report] Stacy Kennedy Project Manager 1 Cp 2 Tc 3 Ss 4 Cn 5 Sr 6 Qc 7 Gl 8 Al 9 Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/30/19 09:10 4 of 14 Cassandra Foster Project Manager ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/31/19 09:51 4 of 14 ONE LAB. NATIONWIDE.SAMPLE RESULTS - 01 L1153378 OUTFALL 001 Collected date/time: 10/23/19 10:15 Semi Volatile Organic Compounds (GC/MS) by Method 625.1 Result Qualifier MDL RDL Dilution Analysis Batch Analyte mg/l mg/l mg/l date / time Acenaphthene U 0.000332 0.00105 1.05 10/28/2019 22:51 WG1369707 Acenaphthylene U 0.000324 0.00105 1.05 10/28/2019 22:51 WG1369707 Anthracene U 0.000306 0.00105 1.05 10/28/2019 22:51 WG1369707 Benzidine U 0.00454 0.0105 1.05 10/28/2019 22:51 WG1369707 Benzo(a)anthracene U 0.000102 0.00105 1.05 10/28/2019 22:51 WG1369707 Benzo(b)fluoranthene U 0.0000941 0.00105 1.05 10/28/2019 22:51 WG1369707 Benzo(k)fluoranthene U 0.000373 0.00105 1.05 10/28/2019 22:51 WG1369707 Benzo(g,h,i)perylene U 0.000169 0.00105 1.05 10/28/2019 22:51 WG1369707 Benzo(a)pyrene U 0.000357 0.00105 1.05 10/28/2019 22:51 WG1369707 Bis(2-chlorethoxy)methane U 0.000345 0.0105 1.05 10/28/2019 22:51 WG1369707 Bis(2-chloroethyl)ether U 0.00170 0.0105 1.05 10/28/2019 22:51 WG1369707 Bis(2-chloroisopropyl)ether U 0.000467 0.0105 1.05 10/28/2019 22:51 WG1369707 4-Bromophenyl-phenylether U 0.000352 0.0105 1.05 10/28/2019 22:51 WG1369707 2-Chloronaphthalene U 0.000347 0.00105 1.05 10/28/2019 22:51 WG1369707 4-Chlorophenyl-phenylether U 0.000318 0.0105 1.05 10/28/2019 22:51 WG1369707 Chrysene U 0.000349 0.00105 1.05 10/28/2019 22:51 WG1369707 Dibenz(a,h)anthracene U 0.000293 0.00105 1.05 10/28/2019 22:51 WG1369707 3,3-Dichlorobenzidine U 0.00212 0.0105 1.05 10/28/2019 22:51 WG1369707 2,4-Dinitrotoluene U 0.00173 0.0105 1.05 10/28/2019 22:51 WG1369707 2,6-Dinitrotoluene U 0.000293 0.0105 1.05 10/28/2019 22:51 WG1369707 1,2-Diphenylhydrazine U 0.000334 0.0105 1.05 10/28/2019 22:51 WG1369707 Fluoranthene U 0.000326 0.00105 1.05 10/28/2019 22:51 WG1369707 Fluorene U 0.000339 0.00105 1.05 10/28/2019 22:51 WG1369707 Hexachlorobenzene U 0.000358 0.00105 1.05 10/28/2019 22:51 WG1369707 Hexachloro-1,3-butadiene U 0.000345 0.0105 1.05 10/28/2019 22:51 WG1369707 Hexachlorocyclopentadiene U 0.00245 0.0105 1.05 10/28/2019 22:51 WG1369707 Hexachloroethane U 0.000383 0.0105 1.05 10/28/2019 22:51 WG1369707 Indeno(1,2,3-cd)pyrene U 0.000293 0.00105 1.05 10/28/2019 22:51 WG1369707 Isophorone U 0.000286 0.0105 1.05 10/28/2019 22:51 WG1369707 Naphthalene U 0.000391 0.00105 1.05 10/28/2019 22:51 WG1369707 Nitrobenzene U 0.000385 0.0105 1.05 10/28/2019 22:51 WG1369707 n-Nitrosodimethylamine U 0.00132 0.0105 1.05 10/28/2019 22:51 WG1369707 n-Nitrosodiphenylamine U 0.00125 0.0105 1.05 10/28/2019 22:51 WG1369707 n-Nitrosodi-n-propylamine U 0.000423 0.0105 1.05 10/28/2019 22:51 WG1369707 Phenanthrene U 0.000384 0.00105 1.05 10/28/2019 22:51 WG1369707 Benzylbutyl phthalate U 0.000289 0.00315 1.05 10/28/2019 22:51 WG1369707 Bis(2-ethylhexyl)phthalate U 0.000744 0.00315 1.05 10/28/2019 22:51 WG1369707 Di-n-butyl phthalate 0.000289 J 0.000279 0.00315 1.05 10/28/2019 22:51 WG1369707 Diethyl phthalate U 0.000296 0.00315 1.05 10/28/2019 22:51 WG1369707 Dimethyl phthalate U 0.000297 0.00315 1.05 10/28/2019 22:51 WG1369707 Di-n-octyl phthalate U 0.000292 0.00315 1.05 10/28/2019 22:51 WG1369707 Pyrene U 0.000347 0.00105 1.05 10/28/2019 22:51 WG1369707 1,2,4-Trichlorobenzene U 0.000373 0.0105 1.05 10/28/2019 22:51 WG1369707 4-Chloro-3-methylphenol U 0.000276 0.0105 1.05 10/28/2019 22:51 WG1369707 2-Chlorophenol U 0.000297 0.0105 1.05 10/28/2019 22:51 WG1369707 2,4-Dichlorophenol U 0.000298 0.0105 1.05 10/28/2019 22:51 WG1369707 2,4-Dimethylphenol U 0.000655 0.0105 1.05 10/28/2019 22:51 WG1369707 4,6-Dinitro-2-methylphenol U 0.00275 0.0105 1.05 10/28/2019 22:51 WG1369707 2,4-Dinitrophenol U 0.00341 0.0105 1.05 10/28/2019 22:51 WG1369707 2-Nitrophenol U 0.000336 0.0105 1.05 10/28/2019 22:51 WG1369707 4-Nitrophenol U 0.00211 0.0105 1.05 10/28/2019 22:51 WG1369707 Pentachlorophenol U 0.000329 0.0105 1.05 10/28/2019 22:51 WG1369707 Phenol 0.00228 J 0.000351 0.0105 1.05 10/28/2019 22:51 WG1369707 2,4,6-Trichlorophenol U 0.000312 0.0105 1.05 10/28/2019 22:51 WG1369707 (S) Nitrobenzene-d5 56.0 15.0-314 10/28/2019 22:51 WG1369707 (S) 2-Fluorobiphenyl 71.2 22.0-127 10/28/2019 22:51 WG1369707 1 Cp 2 Tc 3 Ss 4 Cn 5 Sr 6 Qc 7 Gl 8 Al 9 Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/30/19 09:10 5 of 14 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/31/19 09:51 5 of 14 ONE LAB. NATIONWIDE.SAMPLE RESULTS - 01 L1153378 OUTFALL 001 Collected date/time: 10/23/19 10:15 Semi Volatile Organic Compounds (GC/MS) by Method 625.1 Result Qualifier MDL RDL Dilution Analysis Batch Analyte mg/l mg/l mg/l date / time (S) p-Terphenyl-d14 76.5 29.0-141 10/28/2019 22:51 WG1369707 (S) Phenol-d5 24.8 8.00-424 10/28/2019 22:51 WG1369707 (S) 2-Fluorophenol 43.0 10.0-120 10/28/2019 22:51 WG1369707 (S) 2,4,6-Tribromophenol 61.0 10.0-153 10/28/2019 22:51 WG1369707 1 Cp 2 Tc 3 Ss 4 Cn 5 Sr 6 Qc 7 Gl 8 Al 9 Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/30/19 09:10 6 of 14 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/31/19 09:51 6 of 14 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1369707 Semi Volatile Organic Compounds (GC/MS) by Method 625.1 L1153378-01 Method Blank (MB) (MB) R3466063-2 10/28/19 16:31 MB Result MB Qualifier MB MDL MB RDL Analyte mg/l mg/l mg/l Acenaphthene U 0.000316 0.00100 Acenaphthylene U 0.000309 0.00100 Anthracene U 0.000291 0.00100 Azobenzene U 0.000318 0.0100 Benzidine U 0.00432 0.0100 Benzo(a)anthracene U 0.0000975 0.00100 Benzo(b)fluoranthene U 0.0000896 0.00100 Benzo(k)fluoranthene U 0.000355 0.00100 Benzo(g,h,i)perylene U 0.000161 0.00100 Benzo(a)pyrene U 0.000340 0.00100 Bis(2-chlorethoxy)methane U 0.000329 0.0100 Bis(2-chloroethyl)ether U 0.00162 0.0100 Bis(2-chloroisopropyl)ether U 0.000445 0.0100 4-Bromophenyl-phenylether U 0.000335 0.0100 2-Chloronaphthalene U 0.000330 0.00100 4-Chlorophenyl-phenylether U 0.000303 0.0100 Chrysene U 0.000332 0.00100 Dibenz(a,h)anthracene U 0.000279 0.00100 3,3-Dichlorobenzidine U 0.00202 0.0100 2,4-Dinitrotoluene U 0.00165 0.0100 2,6-Dinitrotoluene U 0.000279 0.0100 Fluoranthene U 0.000310 0.00100 Fluorene U 0.000323 0.00100 Hexachlorobenzene U 0.000341 0.00100 Hexachloro-1,3-butadiene U 0.000329 0.0100 Hexachlorocyclopentadiene U 0.00233 0.0100 Hexachloroethane U 0.000365 0.0100 Indeno(1,2,3-cd)pyrene U 0.000279 0.00100 Isophorone U 0.000272 0.0100 Naphthalene U 0.000372 0.00100 Nitrobenzene U 0.000367 0.0100 n-Nitrosodimethylamine U 0.00126 0.0100 n-Nitrosodiphenylamine U 0.00119 0.0100 n-Nitrosodi-n-propylamine U 0.000403 0.0100 Phenanthrene U 0.000366 0.00100 Benzylbutyl phthalate U 0.000275 0.00300 Bis(2-ethylhexyl)phthalate U 0.000709 0.00300 Di-n-butyl phthalate U 0.000266 0.00300 Diethyl phthalate U 0.000282 0.00300 Dimethyl phthalate U 0.000283 0.00300 1 Cp 2 Tc 3 Ss 4 Cn 5 Sr 6 Qc 7 Gl 8 Al 9 Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/30/19 09:10 7 of 14 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/31/19 09:51 7 of 14 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1369707 Semi Volatile Organic Compounds (GC/MS) by Method 625.1 L1153378-01 Method Blank (MB) (MB) R3466063-2 10/28/19 16:31 MB Result MB Qualifier MB MDL MB RDL Analyte mg/l mg/l mg/l Di-n-octyl phthalate U 0.000278 0.00300 Pyrene U 0.000330 0.00100 1,2,4-Trichlorobenzene U 0.000355 0.0100 4-Chloro-3-methylphenol U 0.000263 0.0100 2-Chlorophenol U 0.000283 0.0100 2,4-Dichlorophenol U 0.000284 0.0100 2,4-Dimethylphenol U 0.000624 0.0100 4,6-Dinitro-2-methylphenol U 0.00262 0.0100 2,4-Dinitrophenol U 0.00325 0.0100 2-Nitrophenol U 0.000320 0.0100 4-Nitrophenol U 0.00201 0.0100 Pentachlorophenol U 0.000313 0.0100 Phenol U 0.000334 0.0100 2,4,6-Trichlorophenol U 0.000297 0.0100 (S) Nitrobenzene-d5 47.9 15.0-314 (S) 2-Fluorobiphenyl 59.7 22.0-127 (S) p-Terphenyl-d14 70.7 29.0-141 (S) Phenol-d5 18.3 8.00-424 (S) 2-Fluorophenol 31.9 10.0-120 (S) 2,4,6-Tribromophenol 48.8 10.0-153 Laboratory Control Sample (LCS) (LCS) R3466063-1 10/28/19 16:11 Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier Analyte mg/l mg/l %% Acenaphthene 0.0500 0.0338 67.6 47.0-145 Acenaphthylene 0.0500 0.0371 74.2 33.0-145 Anthracene 0.0500 0.0336 67.2 27.0-133 Azobenzene 0.0500 0.0377 75.4 37.0-125 Benzidine 0.100 0.0652 65.2 1.00-120 Benzo(a)anthracene 0.0500 0.0370 74.0 33.0-143 Benzo(b)fluoranthene 0.0500 0.0386 77.2 24.0-159 Benzo(k)fluoranthene 0.0500 0.0379 75.8 11.0-162 Benzo(g,h,i)perylene 0.0500 0.0351 70.2 1.00-219 Benzo(a)pyrene 0.0500 0.0400 80.0 17.0-163 Bis(2-chlorethoxy)methane 0.0500 0.0291 58.2 1.00-219 Bis(2-chloroethyl)ether 0.0500 0.0316 63.2 33.0-185 Bis(2-chloroisopropyl)ether 0.0500 0.0299 59.8 36.0-166 1 Cp 2 Tc 3 Ss 4 Cn 5 Sr 6 Qc 7 Gl 8 Al 9 Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/30/19 09:10 8 of 14 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/31/19 09:51 8 of 14 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1369707 Semi Volatile Organic Compounds (GC/MS) by Method 625.1 L1153378-01 Laboratory Control Sample (LCS) (LCS) R3466063-1 10/28/19 16:11 Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier Analyte mg/l mg/l %% 4-Bromophenyl-phenylether 0.0500 0.0310 62.0 53.0-127 2-Chloronaphthalene 0.0500 0.0335 67.0 60.0-120 4-Chlorophenyl-phenylether 0.0500 0.0358 71.6 25.0-158 Chrysene 0.0500 0.0347 69.4 17.0-168 Dibenz(a,h)anthracene 0.0500 0.0344 68.8 1.00-227 3,3-Dichlorobenzidine 0.100 0.0831 83.1 1.00-262 2,4-Dinitrotoluene 0.0500 0.0386 77.2 39.0-139 2,6-Dinitrotoluene 0.0500 0.0385 77.0 50.0-158 Fluoranthene 0.0500 0.0345 69.0 26.0-137 Fluorene 0.0500 0.0368 73.6 59.0-121 Hexachlorobenzene 0.0500 0.0313 62.6 1.00-152 Hexachloro-1,3-butadiene 0.0500 0.0270 54.0 24.0-120 Hexachlorocyclopentadiene 0.0500 0.0280 56.0 10.0-120 Hexachloroethane 0.0500 0.0279 55.8 40.0-120 Indeno(1,2,3-cd)pyrene 0.0500 0.0358 71.6 1.00-171 Isophorone 0.0500 0.0296 59.2 21.0-196 Naphthalene 0.0500 0.0268 53.6 21.0-133 Nitrobenzene 0.0500 0.0279 55.8 35.0-180 n-Nitrosodimethylamine 0.0500 0.0155 31.0 10.0-120 n-Nitrosodiphenylamine 0.0500 0.0333 66.6 44.0-120 n-Nitrosodi-n-propylamine 0.0500 0.0328 65.6 1.00-230 Phenanthrene 0.0500 0.0333 66.6 54.0-120 Benzylbutyl phthalate 0.0500 0.0418 83.6 1.00-152 Bis(2-ethylhexyl)phthalate 0.0500 0.0426 85.2 8.00-158 Di-n-butyl phthalate 0.0500 0.0385 77.0 1.00-120 Diethyl phthalate 0.0500 0.0404 80.8 1.00-120 Dimethyl phthalate 0.0500 0.0368 73.6 1.00-120 Di-n-octyl phthalate 0.0500 0.0375 75.0 4.00-146 Pyrene 0.0500 0.0358 71.6 52.0-120 1,2,4-Trichlorobenzene 0.0500 0.0276 55.2 44.0-142 4-Chloro-3-methylphenol 0.0500 0.0300 60.0 22.0-147 2-Chlorophenol 0.0500 0.0270 54.0 23.0-134 2,4-Dichlorophenol 0.0500 0.0285 57.0 39.0-135 2,4-Dimethylphenol 0.0500 0.0277 55.4 32.0-120 4,6-Dinitro-2-methylphenol 0.0500 0.0354 70.8 1.00-181 2,4-Dinitrophenol 0.0500 0.0400 80.0 1.00-191 2-Nitrophenol 0.0500 0.0310 62.0 29.0-182 4-Nitrophenol 0.0500 0.0120 24.0 1.00-132 Pentachlorophenol 0.0500 0.0309 61.8 14.0-176 Phenol 0.0500 0.0126 25.2 5.00-120 1 Cp 2 Tc 3 Ss 4 Cn 5 Sr 6 Qc 7 Gl 8 Al 9 Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/30/19 09:10 9 of 14 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/31/19 09:51 9 of 14 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1369707 Semi Volatile Organic Compounds (GC/MS) by Method 625.1 L1153378-01 Laboratory Control Sample (LCS) (LCS) R3466063-1 10/28/19 16:11 Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier Analyte mg/l mg/l %% 2,4,6-Trichlorophenol 0.0500 0.0356 71.2 37.0-144 (S) Nitrobenzene-d5 50.5 15.0-314 (S) 2-Fluorobiphenyl 66.5 22.0-127 (S) p-Terphenyl-d14 70.3 29.0-141 (S) Phenol-d5 20.8 8.00-424 (S) 2-Fluorophenol 34.7 10.0-120 (S) 2,4,6-Tribromophenol 61.5 10.0-153 L1154398-10 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1154398-10 10/28/19 18:50 • (MS) R3466063-3 10/28/19 19:10 • (MSD) R3466063-4 10/28/19 19:30 Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/l mg/l mg/l mg/l %%%%% Acenaphthene 0.0526 ND 0.0379 0.0354 72.1 67.3 1.05 47.0-145 6.82 48 Acenaphthylene 0.0526 ND 0.0421 0.0389 80.0 74.0 1.05 33.0-145 7.90 74 Anthracene 0.0526 ND 0.0375 0.0364 71.3 69.2 1.05 27.0-133 2.98 66 1,2-Diphenylhydrazine 0.0526 ND 0.0422 0.0406 80.2 77.2 1.05 18.0-156 3.86 34 Benzidine 0.105 ND 0.0514 0.0414 49.0 39.4 1.05 1.00-120 21.6 40 Benzo(a)anthracene 0.0526 ND 0.0411 0.0402 78.1 76.4 1.05 33.0-143 2.21 53 Benzo(b)fluoranthene 0.0526 ND 0.0433 0.0424 82.3 80.6 1.05 24.0-159 2.10 71 Benzo(k)fluoranthene 0.0526 ND 0.0412 0.0416 78.3 79.1 1.05 11.0-162 0.966 63 Benzo(g,h,i)perylene 0.0526 ND 0.0387 0.0386 73.6 73.4 1.05 1.00-219 0.259 97 Benzo(a)pyrene 0.0526 ND 0.0446 0.0442 84.8 84.0 1.05 17.0-163 0.901 72 Bis(2-chlorethoxy)methane 0.0526 ND 0.0328 0.0302 62.4 57.4 1.05 33.0-184 8.25 54 Bis(2-chloroethyl)ether 0.0526 ND 0.0366 0.0312 69.6 59.3 1.05 12.0-158 15.9 108 Bis(2-chloroisopropyl)ether 0.0526 ND 0.0350 0.0294 66.5 55.9 1.05 36.0-166 17.4 76 4-Bromophenyl-phenylether 0.0526 ND 0.0344 0.0337 65.4 64.1 1.05 53.0-127 2.06 43 2-Chloronaphthalene 0.0526 ND 0.0381 0.0352 72.4 66.9 1.05 60.0-120 7.91 24 4-Chlorophenyl-phenylether 0.0526 ND 0.0399 0.0376 75.9 71.5 1.05 25.0-158 5.94 61 Chrysene 0.0526 ND 0.0386 0.0384 73.4 73.0 1.05 17.0-168 0.519 87 Dibenz(a,h)anthracene 0.0526 ND 0.0381 0.0374 72.4 71.1 1.05 1.00-227 1.85 126 3,3-Dichlorobenzidine 0.105 ND 0.0884 0.0861 84.2 82.0 1.05 1.00-262 2.64 108 2,4-Dinitrotoluene 0.0526 ND 0.0428 0.0420 81.4 79.8 1.05 39.0-139 1.89 42 2,6-Dinitrotoluene 0.0526 ND 0.0433 0.0420 82.3 79.8 1.05 50.0-158 3.05 48 Fluoranthene 0.0526 ND 0.0387 0.0375 73.6 71.3 1.05 26.0-137 3.15 66 Fluorene 0.0526 ND 0.0411 0.0393 78.1 74.7 1.05 59.0-121 4.48 38 Hexachlorobenzene 0.0526 ND 0.0348 0.0336 66.2 63.9 1.05 1.00-152 3.51 55 Hexachloro-1,3-butadiene 0.0526 ND 0.0303 0.0270 57.6 51.3 1.05 24.0-120 11.5 62 Hexachlorocyclopentadiene 0.0526 ND 0.0324 0.0281 61.6 53.4 1.05 10.0-146 14.2 34 1 Cp 2 Tc 3 Ss 4 Cn 5 Sr 6 Qc 7 Gl 8 Al 9 Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/30/19 09:10 10 of 14 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/31/19 09:51 10 of 14 ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1369707 Semi Volatile Organic Compounds (GC/MS) by Method 625.1 L1153378-01 L1154398-10 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1154398-10 10/28/19 18:50 • (MS) R3466063-3 10/28/19 19:10 • (MSD) R3466063-4 10/28/19 19:30 Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/l mg/l mg/l mg/l %%%%% Hexachloroethane 0.0526 ND 0.0341 0.0294 64.8 55.9 1.05 40.0-120 14.8 52 Indeno(1,2,3-cd)pyrene 0.0526 ND 0.0395 0.0384 75.1 73.0 1.05 1.00-171 2.82 99 Isophorone 0.0526 ND 0.0335 0.0308 63.7 58.6 1.05 21.0-196 8.40 93 Naphthalene 0.0526 ND 0.0301 0.0266 57.2 50.6 1.05 21.0-133 12.3 65 Nitrobenzene 0.0526 ND 0.0309 0.0274 58.7 52.1 1.05 35.0-180 12.0 62 n-Nitrosodimethylamine 0.0526 ND 0.0220 0.0179 41.8 34.0 1.05 10.0-120 20.6 40 n-Nitrosodiphenylamine 0.0526 ND 0.0348 0.0334 66.2 63.5 1.05 16.0-160 4.11 28 n-Nitrosodi-n-propylamine 0.0526 ND 0.0376 0.0332 71.5 63.1 1.05 1.00-230 12.4 87 Phenanthrene 0.0526 ND 0.0370 0.0359 70.3 68.3 1.05 54.0-120 3.02 39 Benzylbutyl phthalate 0.0526 ND 0.0466 0.0463 88.6 88.0 1.05 1.00-152 0.646 60 Bis(2-ethylhexyl)phthalate 0.0526 ND 0.0470 0.0458 89.4 87.1 1.05 8.00-158 2.59 82 Di-n-butyl phthalate 0.0526 ND 0.0437 0.0427 83.1 81.2 1.05 1.00-120 2.31 47 Diethyl phthalate 0.0526 ND 0.0452 0.0438 85.9 83.3 1.05 1.00-120 3.15 100 Dimethyl phthalate 0.0526 ND 0.0415 0.0411 78.9 78.1 1.05 1.00-120 0.969 183 Di-n-octyl phthalate 0.0526 ND 0.0418 0.0408 79.5 77.6 1.05 4.00-146 2.42 69 Pyrene 0.0526 ND 0.0390 0.0390 74.1 74.1 1.05 52.0-120 0.000 49 1,2,4-Trichlorobenzene 0.0526 ND 0.0310 0.0273 58.9 51.9 1.05 44.0-142 12.7 50 4-Chloro-3-methylphenol 0.0526 ND 0.0348 0.0317 66.2 60.3 1.05 22.0-147 9.32 73 2-Chlorophenol 0.0526 ND 0.0329 0.0271 62.5 51.5 1.05 23.0-134 19.3 61 2,4-Dichlorophenol 0.0526 ND 0.0326 0.0286 62.0 54.4 1.05 39.0-135 13.1 50 2,4-Dimethylphenol 0.0526 ND 0.0319 0.0284 60.6 54.0 1.05 32.0-120 11.6 58 4,6-Dinitro-2-methylphenol 0.0526 ND 0.0390 0.0378 74.1 71.9 1.05 1.00-181 3.13 203 2,4-Dinitrophenol 0.0526 ND 0.0452 0.0421 85.9 80.0 1.05 1.00-191 7.10 132 2-Nitrophenol 0.0526 ND 0.0341 0.0307 64.8 58.4 1.05 29.0-182 10.5 55 4-Nitrophenol 0.0526 ND 0.0194 0.0181 36.9 34.4 1.05 1.00-132 6.93 131 Pentachlorophenol 0.0526 ND 0.0348 0.0324 66.2 61.6 1.05 14.0-176 7.14 86 Phenol 0.0526 ND 0.0244 0.0183 38.0 26.4 1.05 5.00-120 28.6 64 2,4,6-Trichlorophenol 0.0526 ND 0.0398 0.0374 75.7 71.1 1.05 37.0-144 6.22 58 (S) Nitrobenzene-d5 53.2 47.7 15.0-314 (S) 2-Fluorobiphenyl 73.3 66.2 22.0-127 (S) p-Terphenyl-d14 72.9 71.7 29.0-141 (S) Phenol-d5 30.1 23.9 8.00-424 (S) 2-Fluorophenol 46.9 38.0 10.0-120 (S) 2,4,6-Tribromophenol 64.8 63.8 10.0-153 1 Cp 2 Tc 3 Ss 4 Cn 5 Sr 6 Qc 7 Gl 8 Al 9 Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/30/19 09:10 11 of 14 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/31/19 09:51 11 of 14 ONE LAB. NATIONWIDE.GLOSSARY OF TERMS Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name, Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On-Site Data, Sampling Collection Dates/Times, and Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received. Abbreviations and Definitions MDL Method Detection Limit. ND Not detected at the Reporting Limit (or MDL where applicable). RDL Reported Detection Limit. Rec.Recovery. RPD Relative Percent Difference. SDG Sample Delivery Group. (S) Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. U Not detected at the Reporting Limit (or MDL where applicable). Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. Dilution If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. Limits These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges. Original Sample The non-spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG. Qualifier This column provides a letter and/or number designation that corresponds to additional information concerning the result reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. Result The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state “ND” (Not Detected) or “BDL” (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Uncertainty (Radiochemistry)Confidence level of 2 sigma. Case Narrative (Cn) A brief discussion about the included sample results, including a discussion of any non-conformances to protocol observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. Quality Control Summary (Qc) This section of the report includes the results of the laboratory quality control analyses required by procedure or analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. Sample Chain of Custody (Sc) This is the document created in the field when your samples were initially collected. This is used to verify the time and date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. Sample Results (Sr) This section of your report will provide the results of all testing performed on your samples. These results are provided by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. Sample Summary (Ss)This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Qualifier Description J The identification of the analyte is acceptable; the reported value is an estimate. 1 Cp 2 Tc 3 Ss 4 Cn 5 Sr 6 Qc 7 Gl 8 Al 9 Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/30/19 09:10 12 of 14 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/31/19 09:51 12 of 14 ONE LAB. NATIONWIDE. Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing turn-around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. * Not all certifications held by the laboratory are applicable to the results reported in the attached report. * Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National. 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If you would like assistance from one of our support offices, please contact our main office. Pace National performs all testing at our central laboratory. 1 Cp 2 Tc 3 Ss 4 Cn 5 Sr 6 Qc 7 Gl 8 Al 9 Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/30/19 09:10 13 of 14 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: CITGO-Charlotte, NC SEMIANN L1153378 10/31/19 09:51 13 of 14 r_— I�CITGO-Charlotte, Billing Information: Analysis/Container/Preservative Chaln of Custody Page of Y H NC Rob Durham Pres 7600 Mount Holly Rd. cr`... WeMalyttdl' 7600 Mount Holly Road Charlotte, NC 28214 _ n•e, �. -mot„N a,a,� Charlotte, NC 28214 12o6s Lebanon Rd Q 'Q Report toEmail To: Mr. Jim Utke lutke@citgocom,rpattel@citgo.com,rdurham@cit -� Mount iI'tTNan22 Phone 615 7585858 - Project Gfy/$tote ` Description: treated stormwater Collected: o ra Z Q 0 uT ry FM1 800767d859 F :615.758-SP59 O Ci L # L"S 3 3 l �i J032 Actinium: CITGOCNC 7emplate:T45464 j Prelogln: P717980 n TSR: 650 -Linda Cashman a PB:-S' I9 is Phone: 704-392- 6 Fa Client Project # SEMIANN Lab Project # II (p-t). Site/Facility ID# P.O.# C ec y l nature : I Immediately / Packed on Ice N_ Yam[ v Rush. (Lab MUST Be Notified) Quote # _Same Day _Five Day _ NsA Day _ S Day (Bad Only) Date Results Needed _Two Day _ 10 Day (Bad Only) No, _Three Day of Shipped Via: Fed EX Ground $ample lD Camp/Grab Matrix' Depth Date Time Mrs Rem„s, samRie n0a6 omxl OUTFALL001 ,Ai> WW 10/03//9 10 J'S 2 X * Matrix: emarks: ml r ] CDC Seal Present/Intact: _NP _N CDC Signed/Accurate: N Bottles arrive intact: 2Af N Correct bottles used: N Sufficient volume sent: 7—N 5-Soul AIR -Air F- Filter GW- Groundwater B- Bioassay WW- Wastewater OW - Drip Water pH Temp Flow Other Samples rel ed via: OT- 7her.),—_UPS )Ex _Courier _ Tracking# ( go % / If Applicable VOA zero Readsoace: Y N Pres Y31' n, Lorrect/Checkedi _a _N 'nr.4r-rei. ter: fff111ttt111LLU11 ,J` Reli qu b : (Sig(ature) Date AA- 1 l//U /�� t Time'. U 1 Received by. (Signature) Trip Blank ceived: Yes / J. HCL/MeoH TBR Relin hed b Si nature) q y : (Signature) Date: Time: Received b : $i nature) y (-g T/ p: =C Bottles Received: /t " C4, a If preservation required by Login: Date/Time Relinquished by: (Signature) Date: Time: Received for by: (S nature) Date: Time: Hold: Conditio