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HomeMy WebLinkAboutNC0024406_04_BCSS CAP Update 2019_Tables_20191231Corrective Action Plan Update December 2019 Belews Creek Steam Station TABLES (CAP Content Section 9) SynTerra Corrective Action Plan Update December 2019 Belews Creek Steam Station SynTerra Table ES-1 Summary of BCSS Assessment Documentation Included in Executive Summary text Corrective Action Plan Update December 2019 Belews Creek Steam Station SynTerra Table ES-2 Summary of BCSS Assessment Activities Included in Executive Summary text Corrective Action Plan Update December 2019 Belews Creek Steam Station SynTerra Table ES-3 Components of Source Control, Active Remediation, and Monitoring Included in Executive Summary text TABLE 3-1 SUMMARY OF ONSITE FACILITIES CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Evaluated as Source Facility Area in CSA Operational Source Material Area or Rationale For Evaluation Name CAP Schedule Status Capacity Update Coal Ash/NPDES Ash Basin Yes NA Inactive Permitted waste 17,676,000 cy CAMA regulated unit streams Pine Hall Road Yes NA Closed Fly ash 8,500,000 cy Hydrologically connected to the Landfill ash basin Former part of the ash basin Steam station treatment system and Chemical Pond No NA Closed boiler and filter 2.9 acres hydrologically connected to the chemical cleaning ash basin, no evidence of wastes groundwater COI migration from source area Former part of the ash basin Constructed FGD wastewater/ treatment system and Wetlands No NA Closed Landfill contact 25 acres hydrologically connected to the Treatment water/sanitary ash basin, no evidence of System wastewater groundwater COI migration from source area Not hydrologically connected to Structural Fill No Mar-20 Closed Fly ash 968,000 cy the ash basin and with NCDEQ DWM regulatory oversight Craig Road CCR and Not hydrologically connected to Landfill No NA Operational operational waste 67.1 acres the ash basin and with NCDEQ DWM regulatory oversight FGD Residue CCR and Not hydrologically connected to Landfill No NA Operational operational waste 24 acres the ash basin and with NCDEQ DWM regulatory oversight Coal Pile No Mar-20 Operational Coal 42 acres Not hydrologically connected to the ash basin umNo F Mar-20 Operational Gypsum 5 acres Not hydrologically connected to Pad the ash basin Prepared by: ALA Checked by: CDE Notes: CSA Schedule - applicable only for units identified in the letter "Final Comprehensive Site Assessment and Corrective Action Plans Approvals for Duke Energy Coal Ash Facilities" (April 5, 2019) CAMA - North Carolina Coal Ash Management Act of 2014 CAP - Corrective Action Plan cy - cubic yards DWM - Division of Waste Management NA - not applicable NCDEQ - North Carolina Department of Environmental Quality NPDES - National Pollutant Discharge Elimination System Page 1 of 1 TABLE 4-1 BACKGROUND SOIL SAMPLE SUMMARY CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Soil Boring Depth Range (ft bgs) Number of Sampled Intervals BG-1D (1-31) 4 BG-2D (1-32) 4 BG-3S (1-22) 3 GWA-3D (34-35.5) 1 GWA-4S (45-47) 1 GWA-12D (10-27) 4 BGSB-01 (1-22) 5 BGSB-02 (1-32) 6 BGSB-03 (1-22) 5 GWASB-12 (5-27) 5 Note: ft bgs — feet below ground surface Prepared by: ALA Checked by: CDE Page 1 of 1 TABLE 4-2 BACKGROUND VALUES FOR SOIL CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Constituent Reporting Unit PSRG Protection of Groundwater 2018 Background 1 Threshold Value 2019 Updated Background Threshold Value 2 Piedmont Background s Threshold Value Range pH* S.U. NE 4.3-5.8 4.6-7.0 2.3-9.8 Aluminum mg/kg 110,000 31,253 28,880 25,978 - 81,619 Antimony mg/kg 0.9 0.6 0.6 0.177 - 0.9 Arsenic mg/kg 5.8 13 43 1.2 - 43.13 Barium mg/kg 580 139 122 122.2 - 1,063 Beryllium mg/kg 63 19 2.9 1.2 - 4.52 Boron mg/kg 45 17 35 14.4 - 56.3 Cadmium mg/kg 3 0.03 0.9 0.03 - 1 Calcium mg/kg NE 450 1,000 410 - 8,769 Chloride mg/kg 938^ 14 402 12 - 423 Chromium mg/kg 3.8 36 47 20 - 440 Cobalt mg/kg 0.9 51 60 27 - 81.68 Copper mg/kg 700 28 32 17.4 - 216 Iron mg/kg 150 40,400 61,967 24,500 - 85,345 Lead mg/kg 270 40 52 7.5 - 95.23 Magnesium mg/kg NE 3,600 4,492 760 - 51,829 Manganese mg/kg 65 1,117 1,257 370 - 3,388 Mercury mg/kg 1 0.1 0.1 0.04 - 0.113 Molybdenum mg/kg 71 9.8 4 1.83 - 12 Nickel mg/kg 130 12 21 9.2 - 237 Nitrate (as N) mg/kg NE 0.3 0.3 0.25 - 31.2 Nitrate mg/kg NE --- 40.3 40.3 - 48.8 Potassium mg/kg NE 2,114 3,458 427 - 35,600 Selenium mg/kg 2.1 5 5 1.58 - 6.857 Sodium mg/kg NE 393 393 338 - 1,500 Strontium mg/kg 1,500 9 7 7.1 - 200 Sulfate mg/kg 1,438^ 12 403 12 - 437 Thallium mg/kg 0.28 0.7 0.8 0.166 - 2.132 Total Organic Carbon mg/kg NE --- 4,070 742 - 4,960 Vanadium mg/kg 350 114 231 42 - 230.9 Zinc mg/kg 1,200 52 71 60.5 - 325.5 Prepared by: JHG Checked by: ALA Notes: 2018 Background values approved by NCDEQ on May 14, 2018. ^ - PSRG Protection of Groundwater value was calculated using the equation shown in Section 6 * - Upper and lower threshold values calculated for parameter ' - Background threshold values were calculated using data from background unsaturated soil samples collected June 2015 to April 2017. 2 - Updated background threshold values were calculated using data from background unsaturated soil samples collected June 2015 to April 2017. The background threshold value updates retained extreme outlier concentrations in background unsaturated soil datasets (SynTerra, 2019). 3 - Piedmont background threshold value ranges include the Duke Energy calculated 20174 and 20195 background threshold values from 10 Duke Energy facilities located in the Piedmont physiographic region (Allen Steam Stations, Belews Creek Steam Stations, Buck Steam Station4, Cape Fear Steam Electric Plant4, Cliffside Steam Stations, Dan River Steam Station4, Marshall Steam Stations, Mayo Steam Electric Plants, Riverbend Steam Station4, and Roxboro Steam Electric Plants). --- - 2017 background threshold value was not calculated for constituent. mg/kg - milligrams per kilogram NE - Not Established S.U. - Standard Unit PSRG - Preliminary Soil Remediation Goal Page 1 of 1 TABLE 4-3 BACKGROUND VALUES FOR GROUNDWATER CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Constituent Reporting Unit 1SA NCAC 02L Standard 2018 Background Threshold Values' 2019 Updated Background Threshold ValueS2 Piedmont Background Threshold Value Range3 Shallow Flow Zone Deep Flow Zone Bedrock Flow Zone Shallow Flow Zone Deep Flow Zone Bedrock Flow Zone pH S.U. 6.5-8.5 5.1-6.0 5.2-7.0 6.3-6.5 5.2-6.0 5.6-7.0 6.2-8.4 3.6-9 Alkalinity mg-CaCO3/L NE 23 64 81 20 53 91 19 - 379 Aluminum Ng/L NE 860 140 100 805 204 120 100 - 1,238 Antimony Ng/L 1* 1 1 1 1 1 1 0.5 - 2.9 Arsenic Ng/L 10 1 1 1 1 1 2 0.2 - 6.35 Barium Ng/L 700 58 13 6 123 16 11 10.52 - 840 Beryllium Ng/L 4* 0.4 0.2 0.2 0.3 0.1 0.2 0.0625 - 1 Bicarbonate mg-CaCO3/L NE 22 63 78 24 54 91 19 - 388 Boron Ng/L 700 50 50 50 50 50 50 50 - 176.8 Cadmium Ng/L 2 1 1 0.08 1 0.08 0.08 0.08- 1 Calcium mg/L NE 4 13 10 8 14 26 4 - 111 Carbonate mg-CaCO3/L NE 5 5 5 5 5 5 5- 10 Chloride mg/L 250 15 21 3 19 19 3 3.34 - 250 Chromium Ng/L 10 5 3 5 11 3 11 1-26 Chromium (VI) Ng/L NE 2 0.4 0.3 4 0.6 0.4 0.03 - 12 Cobalt Ng/L 1* 0.5 2 0.8 0.6 2 0.8 0.088 - 88.85 Copper Ng/L 1000 3 5 10 2 5 17 0.5 - 17.15 Fluoride mg/L 2 --- --- --- 0.1 0.1 0.6 0.1 - 1.8 Iron Ng/L 300 750 240 228 1,600 226 341 56.3 - 37,500 Lead Ng/L 15 1 1 0.1 1 0.6 0.2 0-2 Lithium Ng/L NE --- --- --- 2 95 30 2 - 95.39 Magnesium mg/L NE 3 7 3 4 7 4 1- 45 Manganese Ng/L 50 23 13 10 40 57 64 7-9,170 Mercury Ng/L 1 0.2 0.2 0.2 0.2 0.2 0.2 0.05 - 0.5 Methane Ng/L NE 3 3 10 3 10 10 1 - 2,505 Molybdenum Ng/L NE 1 1 4 0.5 2 6 0.5 - 26.2 Nickel Ng/L 100 4 5 3 8 5 7 0.87 - 48 Nitrate + Nitrite mg-N/L NE 4 4 0.2 3 4 0.2 0.02 - 6.3 Potassium mg/L NE 5 5 5 5 19 5 1.609 - 18.8 Selenium Ng/L 20 0.5 0.5 0.5 1 0.5 0.5 0.5 - 2.4 Sodium mg/L NE 6 11 12 7 11 15 6- 190 Strontium Ng/L NE 57 69 100 46 73 99 27 - 2,120 Sulfate mg/L 250 2 6 10 2 8 15 1.2 - 510 Sulfide mg/L NE 0.1 0.1 0.1 0.1 0.1 0.1 0.1 - 2 TDS mg/L 500 85 148 133 93 134 181 50- 1,200 Thallium Ng/L 0.2* 0.2 0.2 0.1 0.2 0.1 0.1 0.1 - 0.2 TOC mg/L NE 1 1 10 3 6 4 1- 12.3 Total Radium pCi/L 5^ 9 1 0.5 2 4 4 0.494 - 35 Total Uranium pg/mL 0.03^ 0.0005 0.0005 0.0005 0.0005 0.0005 0.002 0.0002 - 0.864 Vanadium Ng/L 0.3* 1 1 1 3 2 2 0.33 - 25.8 Zinc Ng/L 1000 1 10 1 43 1 16 39 23 41 5- 140 Prepared by: HES Checked by: JHG Notes: Revised by: DAA ' - Background threshold values were calculated using data from background groundwater samples collected June 2015 to April 2017 2 - Updated background threshold values were calculated using data from background groundwater samples collected October 2010 to December 2018 and submitted to NCDEO June 2019 3 - Piedmont background threshold value ranges include the Duke Energy calculated 20174 and 20195 background threshold values from 10 Duke Energy facilities located in the Piedmont physiographic region (Allen Steam Stations, Belews Creek Steam Stations, Buck Steam Station°, Cape Fear Steam Electric Plant°, Cliffside Steam Stations, Dan River Steam Station 4, Marshall Steam Stations, Mayo Steam Electric Plants, Riverbend Steam Station 4, and Roxboro Steam Electric Plants). 2018 background threshold values approved by North Carolina Department of Environmental Qualtity( NCDEQ) on May 14, 2018 Background threshold values have been rounded to similar levels of precision as 15A North Carolina Administrative Code (NCAC) 02L Standard or Interim Maximum Allowable Concentration (IMAC). - 2017 background threshold value was not calculated for constituent. * - IMAC of the 15A NCAC 02L Standard, Appendix 1, April 1, 2013. ^ - Federal Maximimum Contaminant Level iig/L - micrograms per liter iig/mL - micrograms per milliliter mg/L - milligrams per liter mg-CaCO3/L - milligrams calcium carbonate per liter mg-N/L - milligrams nitrogen per liter NE - not established pCi/L - picocuries per liter S.U. - standard units TDS - total dissolved solids TOC - total organic carbon Page 1 of 1 TABLE 4-4 BACKGROUND DATASET RANGES FOR SURFACE WATER CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK NC Constituent Reporting Unit Comparison Criteria Belews Reservoir Background Ranges Dan River Background Ranges Constituents with 15A NCAC 02B (Class C1, Water Supply: WS-IV1, WS-V1)1 Standards pH S.U. 6.0-9.0 6.8 - 7.9 6.5 - 7.7 Dissolved Oxygen mg/L <_ 4 5.3 - 10.8 4.4 - 8.8 Temperature deg C >_ 32 7 - 26.8 9 - 32.9 Turbidity NTU Lake and Reservoirs: >_ 25 Streams: >_ 50 5.2 - 137 0.01 - 33.5 Arsenic pg/L 10 0.15 - 0.27 0.19 - 0.78 Arsenic (Dissolved) pg/L acute: 340, chronic: 150 0.15 - <1 0.16 - 0.76 Barium pg/L 1000 20.8 -51 13.9 - 35.9 Beryllium (Dissolved) pg/L acute: 65, chronic: 6.5 <0.1 - <1 0.012 - 0.058 Cadmium (Dissolved )2 pg/L acute: 0.82, chronic: 0.15 <0.08 - <0.1 <0.08 - 0.22 Chloride mg/L 230 2.9 -26 5.3 - 8.5 Chromium (III) (Dissol pg/L acute: 183, chronic: 24 NA NA Chromium (VI) (Dissoly pg/L acute: 16, chronic: 11 NA NA Copper (Dissolved )2 pg/L acute: 3.6, chronic: 2.7 0.51 - 1.99 0.72 - 8.7 Fluoride mg/L 1.8 0.066 - 0.11 0.074 - <1 Lead (Dissolved )2 pg/L acute: 14, chronic: 0.54 0.061 - <1 0.028 - <1 Mercury pg/L chronic: 0.012 0.00078 - 0.00906 0.00004 - 0.0022 Nickel pg/L 25 0.14 - 2.11 0.19 - 1 Nickel (Dissolved )2 pg/L acute:140, chronic: 16 0.16 - <1 0.13 - 2.1 Nitrate + Nitrite mg-N/L 10 0.084 - 0.529 0.0200 - 0.17 Selenium pg/L chronic: 5 <0.5 - <1 0.25 - 0.63 Silver (Dissolved )2 pg/L acute: 0.3, chronic: 0.06 <0.3 <0.3 Sulfate mg/L 250 2.4 - 13 2.4 - 10.7 Thallium pg/L 2 <0.1 - <0.2 <0.1 - <0.2 Total Dissolved Solids mg/L 500 37 - 130 43 - 174 Total Hardness mg/L 100 12.9 - 36.8 20.3 - 32.9 Zinc (Dissolved )2 pg/L acute: 36, chronic: 36 <5 - <10 2.8 - 11 Constituents with USEPA National Recommended Water Quality Criteria Alkalinity mg/L chronic: 20 7.6 - 47 16 - 33 Aluminum pg/L acute: 620, chronic: 300 81 - 4,170 53 - 1,820 Antimony pg/L 5.6 <0.5 - <1 0.11 - 0.12 Iron pg/L 1000 436 - 5,700 27.1 - 1,740 Manganese pg/L 50 26 - 123 5.1 - 76 Constituents without 02B or USEPA Criteria Bicarbonate mg-CaCO3/L NE 7.6 - 47 16 - 33 Boron pg/L NE <50 25.4 - 72 Cadmium pg/L NE <0.08 - <0.1 <0.08 - <0.1 Calcium mg/L NE 2.99 - 8.94 3.4 - 8.11 Carbonate Alkalinity mg-CaCO3/L NE <0.5 <5 Chromium pg/L NE 0.27 - 4.5 0.12 - 1.55 Chromium (VI) pg/L NE 0.034 - 0.064 0.027 - 0.12 Page 1 of 2 TABLE 4-4 BACKGROUND DATASET RANGES FOR SURFACE WATER CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK NC Constituent Reporting Unit Comparison Criteria Belews Reservoir Background Ranges Dan River Background Ranges Constituents without 02B or USEPA Criteria (Continued) Cobalt pg/L NE 0.1 - 1.79 0.01 - 0.19 Copper pg/L NE 0.5 - 3.74 0.3 - 5.5 Lead pg/L NE 0.15 - 2.91 0.059 - 0.49 Lithium pg/L NE 1.1 - 1.3 0.3 - 0.37 Magnesium mg/L NE 1.31 - 3.52 1.8 - 3.67 Methane pg/L NE <10 2.1 - 561 Molybdenum pg/L NE <0.5 - 1.9 1.12 - 1.8 Potassium mg/L NE 1.68 - 2.98 1.59 - 3.86 Sodium mg/L NE <0.3 4.09 - 7.38 Strontium pg/L NE 22 - 75 23 - 74 Sulfide mg/L NE <0.1 <0.1 Total Organic Carbon mg/L NE 1.9 - 5.5 0.57 - 4.9 Total Radium pCi/L NE NA NA Total Uranium pg/mL NE NA NA Vanadium pg/L NE 0.49 - 8.77 0.32 - 3.85 Zinc pg/L NE 6 - 14 2.9 - 20.5 Prepared by: DAA Checked by: ALA Notes: Background locations, which were part of the evaluation of potential groundwater to surface water impacts, were approved by North Carolina Department of Environmental 115A NCAC 02B .0101 WS-IV (Water Supply) = Waters protected as water supplies which are generally in moderately to high developed watersheds. Suitable for all Class C uses. Based on sample location, samples SW-BL-D, SW-BL-GWA-04S/D, SW-BL-S-06, SW-BL-S-07, SW-BL-S-13/14, SW-DR-01, SW-DR-02, SW-DR-03 and SW-DR-04 are subject to WS-IV water quality standards. '15A NCAC 02B .0101 WS-V (Water Supply) = Waters protected as water supplies which are generally upstream of and draining to Class WS-IV waters. Suitable for all Class C uses. Based on sample location, samples SW-DR-BG, SW-DR-BG2, SW-DR-TFC are subject to WS-V water quality standards. 115A NCAC 02B .0101 Class C (Aquatic Life) = Freshwaters protected for secondary recreation, fishing, aquatic life including propagation and survival and wildlife; All freshwaters shall be classified to protect these at a minimum. All samples collected from the Dan River and Belews Reservoir are subject to Class C z Standard value dependent on hardness. Calculated hardness dependent metal standards represent most conservative value. Standards are calculated using 25 mg/L hardness, regardless if actual instream hardness values are greater than 25 mg/L. 3 Chromium speciation is not performed for trivalent chromium (Cr(III)). Trivalent values are derived by subtracting hexavalent chromium values from dissolved chromium values. Where a dissolved chromium value is less than the detection limit ("<"), it is considered a whole number for purposes of deriving a trivalent chromium value. Acute - "Compliance with acute instream metals standards shall only be evaluated using an average of two or more samples collected with one hour." Reference 15A NCAC 02B .0211 Chronic - "Compliance with chronic instream metals standards shall only be evaluated using averages of a minimum of four samples taken on consecutive days, or as a 96-hour average" Reference 15A NCAC 02B .0211. < - Concentration not detected at or above the adjusted reporting limit. mg/L - milligrams per liter pg/L - micrograms per liter pg/mL - micrograms per milliliter mg-CaCO3/L - milligrams calcium carbonate per liter mg-N/L - milligram nitrogen per liter NA - not available NE - not established pCi/L - picocuries per liter S.U. - standard unit USEPA - Unitesd States Environmental Protection Agency Page 2 of 2 TABLE 4-5 BACKGROUND DATASET RANGES FOR SEDIMENT CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Constituent Reporting Unit PSRG Protection of Groundwater Belews Reservoir Background Dataset Range Dan River Background Dataset Range pH S.U. NE 5.8 - 6.7 5.1 - 6.3 Aluminum mg/kg 110,000 3,200 - 28,000 13,000 - 16,000 Antimony mg/kg 0.9 0.16 - <0.72 <0.64 - <0.83 Arsenic mg/kg 5.8 0.52 - <6.7 0.76 - 3.6 Barium mg/kg 580 12 - 82 61 - 92 Beryllium mg/kg 63 0.22 - 3.5 0.8 - 1.3 Boron mg/kg 45 <2.9 - <16.8 <3.5 - <4.9 Cadmium mg/kg 3 0.022 - <0.81 0.034 - 0.091 Calcium mg/kg NE 437 - 1,600 480 - 820 Chloride mg/kg NE 6- <338 11 - <20 Chromium mg/kg 3.8 2.2 - 29 16 - 19 Chromium (III) mg/kg 360,000 2.2 7.7 - 8.5 Cobalt mg/kg 0.9 <6.7 - 16 7.7 - 8.5 Copper mg/kg 700 2.3 - 26 8.1 - 11 Iron mg/kg 150 3,100 - 20,000 13,000 - 15,000 Lead mg/kg 270 2.3 - 13 9.6 - 13 Magnesium mg/kg NE 260 - 4,700 1,800 - 2,500 Manganese mg/kg 65 20 - 670 130 - 240 Mercury mg/kg 1 0.0075 - <0.12 <0.13 - <0.16 Molybdenum mg/kg 7.1 <2.3 - <3.4 <2.8 - <3.9 Nickel mg/kg 130 1.4 - 16 7.6 - 8.5 Nitrate (as N) mg/kg NE <0.28 - <0.31 0.16 - <0.4 Nitrate mg/kg NE <33.8 NE Potassium mg/kg NE 260 - 2,200 1,200 - 2,300 Selenium mg/kg 2.1 <6.7 - <30 <11 - <20 Silver mg/kg 3.4 <0.59 - <0.68 <0.69 - <0.99 Sodium mg/kg NE <290 - <340 47 - <490 Strontium mg/kg 1500 0.7 - 14 6 - 7.8 Sulfate mg/kg 1438A <14 - <338 <16 - 34 Sulfide mg/kg NE <30.2 - <39.4 <36.9 - <42.2 Thallium mg/kg 0.28 0.05 - 0.28 0.18 - 0.19 Total Organic Carbon mg/kg NE 940 - 8,070 5,980 - 12,300 Vanadium mg/kg 350 14.6 - 80 40 - 42 Zinc mg/kg 1,200 4.8 - 40 31 - 44 Prepared by: DAA Checked by: ALA Notes: Background locations, which were part of the evaluation of potential groundwater to surface water impacts, were approved by North Carolina Department of Environmental Quality (NCDEQ). A - PSRG Protection of Groundwater value was calculated using the equation shown in Section 6 mg/kg - milligrams per kilogram NE - not established S.U. - standard unit PSRG - Preliminary Soil Remediation Goals Page 1 of 1 TABLE 5-1 APRIL 2019 WATER LEVEL MEASUREMENTS AND ELEVATIONS CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Well ID Top of Well Casing (ft. NAVD 88) Top of Screen Elevation (ft. NAVD 88) Bottom of Screen Elevation (ft. NAVD 88) April 2019 Measured Water Level' (ft. BTOC) April 2019 Water Elevation (ft. NAVD 88) Monitoring Flow Zone A13-113R 772.83 675.52 670.5 40.74 732.09 Bedrock AB-1BRD 769.53 469 459 97.42 672.11 Bedrock A13-11D 772.47 696.47 691.5 40.44 732.03 Dee A13-1S 772.42 734.49 719.5 42.21 730.21 Shallow A13-213R 770.57 605.81 595.8 43.73 726.84 Bedrock A13-26RD 770.64 501.85 491.9 94.63 676.01 Bedrock A13-21D 773.84 638.71 633.7 43.01 730.83 Dee A13-2S 773.94 739.69 724.7 31.59 742.35 Shallow A13-313R 769.91 506.69 496.7 95.45 674.46 Bedrock A13-31D 772.51 658.8 653.8 50.60 721.91 Dee A13-3S 772.62 733.92 718.9 38.23 734.39 Shallow A13-4 Ash Well 761.29 704.67 694.7 6.35 754.94 Ash Pore Water AB-4 Lower Ash 761.68 700.48 695.5 6.63 755.05 Ash Pore Water A13-4 Medium Ash 761.59 725.87 720.87 6.57 755.02 Ash Pore Water A13-4 Medium Ash 30 761.74 725.07 720.07 6.64 755.1 Ash Pore Water A13-4 SAP2 761.47 685.69 668.69 6.46 755.01 Shallow A13-4 Sa rolite Well NA NA NA 6.18 NA Shallow A13-4 Upper Ash 761.77 744.86 739.86 6.74 755.03 Ash Pore Water A13-413R 761.99 621.74 616.74 7.01 754.98 Bedrock A13-46RD 762.5 601.53 596.53 7.71 754.79 Bedrock A13-41D 762.21 669.75 664.75 7.19 755.02 Dee A13-4S 762.18 756.36 741.36 6.41 755.77 Ash Pore Water AB-4SAP 761.92 674.17 684.17 6.87 755.05 Shallow AB-4SL 762.25 707.85 697.85 7.11 755.14 Ash Pore Water A13-51D 762.13 661.94 656.94 7.06 755.07 Dee A13-5S 761.9 755.86 740.86 6.51 755.39 Ash Pore Water AB-5SL 761.85 725.01 715.01 6.33 755.52 Ash Pore Water AB-6D 765.33 677.22 672.22 7.89 757.44 Dee A13-6S 765.55 760.46 750.46 7.58 757.97 Ash Pore Water AB-6SL 765.5 749.08 744.08 7.67 757.83 Ash Pore Water A13-71D 771.14 683.72 678.72 13.31 757.83 Dee A13-7S 771.09 762.91 752.91 13.79 757.3 Ash Pore Water A13-81D 765.38 690.1 685.1 8.27 757.11 Dee A13-8S 765.1 758.16 743.16 7.61 757.49 Ash Pore Water AB-8SL 765.29 725.04 715.04 8.42 756.87 Ash Pore Water AB-9BR 782.84 649.84 644.84 23.81 759.03 Bedrock A13-96RD 783.26 589.2 584.2 23.78 759.48 Bedrock A13-91D 782.84 689.69 684.69 23.23 759.61 Dee A13-9S 783.15 766.74 751.74 22.53 760.62 Shallow BG-1D 808.48 758.63 753.63 40.07 768.41 Dee BG-IS 808.75 779.08 763.88 40.19 768.56 Shallow BG-213RA 813.59 713.17 708.17 43.94 769.65 Bedrock BG-21D 812.13 739.95 734.95 43.78 768.35 Dee BG-2S 811.8 769.72 754.72 45.84 765.96 Shallow BG-31D 844.61 779.72 774.72 24.4 820.21 Dee BG-3S 845.64 817.46 802.46 26.98 818.66 Shallow CCR-11D 790.11 736.7 721.7 37.32 752.79 Dee CCR-11S 790.16 747.59 742.59 36.54 753.62 Shallow CCR-12D 772.3 718.79 713.79 20.54 751.76 Dee CCR-12DA 776.07 725.1 720.1 21.31 754.76 Dee CCR-12S 772.24 756.8 741.8 20.69 751.55 Shallow CCR-13BR 705.36 656.8 646.8 16.78 688.58 Bedrock CCR-13D 705.61 682.15 677.15 15.73 689.88 Dee CCR-13S 704.27 694.81 689.81 14.45 689.82 Shallow CCR-11D 774.44 728.04 723.04 25.17 749.27 Dee CCR-1S 774.59 746.74 736.74 25.47 749.12 Shallow CCR-21D 767.4 702.23 697.23 20.3 747.1 Dee CCR-2S 768.66 750.46 735.46 21.58 747.08 Shallow CCR-41D 773.96 721.05 716.05 33.08 740.88 Dee CCR-4S2 773.78 733.55 728.55 BP NA Shallow CCR-51D 727.62 668.14 663.14 20.01 707.61 Dee CCR-5S 727.12 699.48 684.48 5.04 722.08 Shallow CCR-6D 658.05 632.49 627.49 14.16 643.89 Dee CCR-6S3 658.43 1 646.46 1 641.46 1 BP I NA I Shallow CCR-71D 688.88 1 635.43 1 630.43 1 13.76 1 675.12 1 Dee Page 1 of 3 TABLE 5-1 APRIL 2019 WATER LEVEL MEASUREMENTS AND ELEVATIONS CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Well ID Top of Well Casing (ft. NAVD 88) Top of Screen Elevation (ft. NAVD 88) Bottom of Screen Elevation (ft. NAVD 88) April 2019 Measured Water Level' (ft. BTOC) April 2019 Water Elevation (ft. NAVD 88) Monitoring Flow Zone CCR-7S 688.9 677.76 662.76 12.34 676.56 Shallow CCR-8AD 773.56 685.46 680.46 38.09 735.47 Dee CCR-8D 728.18 652.55 647.55 25.32 702.86 Dee CCR-8S4 727.9 711.06 696.06 BP NA Shallow CCR-9D 773.4 719.34 714.34 33.5 739.9 Dee CCR-9S 773.1 747.45 732.45 24.62 748.48 Shallow EX-OB-1 770.96 725.38 715.38 29.11 741.85 Dee EX-OB-2 762.8 732.77 722.77 16.26 746.54 Dee GWA-01BR 743.72 631.1 621.1 63.41 680.31 Dee GWA-01D 743.03 682.9 677.9 20.18 722.85 Dee GWA-01S 743.08 721.72 706.72 17.29 725.79 Shallow GWA-02D 787.51 726.58 721.58 39.46 748.05 Dee GWA-02S 787.58 750.5 735.5 38.96 748.62 Shallow GWA-03D 769.5 721.68 716.68 40.89 728.61 Dee GWA-03S 769.14 739.51 724.51 40.54 728.6 Shallow GWA-06D 793.25 689.93 684.93 37.19 756.06 Dee GWA-06S 793.37 762.95 747.95 31.07 762.3 Shallow GWA-07D 822.7 741.39 736.39 34.6 788.1 Dee GWA-07SA 822.87 792.87 777.87 33.34 789.53 Shallow GWA-08D 831.15 739.61 734.61 28.47 802.68 Dee GWA-08S 832.01 808.27 793.27 25.76 806.25 Shallow GWA-09BR 794.53 675.78 670.78 46.81 747.72 Bedrock GWA-09D 794.28 708.25 703.25 42.46 751.82 Dee GWA-09S 793.99 754.77 739.77 39.44 754.55 Shallow GWA-10DA 749.54 NA NA 8.02 741.52 Dee GWA-10S 749.11 742.78 727.78 6.93 742.18 Shallow GWA-11D 757.04 691.61 686.61 26.21 730.83 Dee GWA-11S 757.03 731.49 716.49 22.11 734.92 Shallow GWA-12BR 836.46 727.35 722.35 59.78 776.68 Bedrock GWA-12D 837.16 771.04 766.04 54.61 782.55 Dee GWA-12S 835.79 792.65 777.65 53.39 782.4 Shallow GWA-16BR 783.66 682.03 677.03 36.22 747.44 Bedrock GWA-16DA 783.78 729.27 724.27 35.74 748.04 Dee GWA-16S 784.41 752.51 737.51 35.23 749.18 Shallow GWA-17D 787.37 735.07 730.07 36.11 751.26 Dee GWA-17S5 787.61 760.07 745.07 BP NA Shallow GWA-18D 774.54 715.34 710.34 26.1 748.44 Dee GWA-18SA 774.59 760.33 745.33 26.5 748.09 Shallow GWA-19BR 743.06 661.00 656 23.58 719.48 Bedrock GWA-19D 743.24 702.19 697.19 13.25 729.99 Dee GWA-19SA 743.33 735.06 720.06 8.51 734.82 Shallow GWA-20BR 773.69 689.27 684.27 32.64 741.05 Bedrock GWA-20D 773.72 715.44 710.44 22.98 750.74 Dee GWA-20SA 773.53 743.65 728.65 27.57 745.96 Shallow GWA-21D 734.79 707.07 702.07 13.60 721.19 Dee GWA-21S 735.01 725.88 715.88 12.77 722.24 Shallow GWA-22D 735.73 703.23 698.23 8.58 727.15 Dee GWA-22S 738.1 729.23 719.23 11.54 726.56 Shallow GWA-23D 811.79 755.19 750.19 22.82 788.97 Dee GWA-23S 811.57 787.17 772.17 25.17 786.4 Shallow GWA-24BR 641.78 580 570 23.55 618.23 Bedrock GWA-24D 642.21 626.11 621.11 13.61 628.6 Dee GWA-24S 643.21 635.28 630.28 11.38 631.83 Shallow GWA-25BR 855.76 757.48 752.48 37.77 817.99 Bedrock GWA-26BR 854.99 768.86 763.86 37.66 817.33 Bedrock GWA-26D 856.8 791.01 786.01 39.37 817.43 Dee GWA-26S 856.16 819.87 804.87 38.37 817.79 Shallow GWA-27BR 758.32 647.46 642.46 30.72 727.6 Bedrock GWA-27D 758.3 717.73 712.73 13.68 744.62 Dee GWA-27S 758.42 748.79 733.79 12.3 746.12 Shallow GWA-30D 738.49 1 703 698 17.52 720.97 Dee GWA-30S 738.43 1 726.1 711.1 18.24 720.19 Shallow GWA-31D 715.67 657.8 652.8 4.66 711.01 Dee GWA-31S 714.26 707.2 692.2 12.87 701.39 Shallow GWA-32D 706.84 630.4 625.4 21.15 685.69 Dee Page 2 of 3 TABLE 5-1 APRIL 2019 WATER LEVEL MEASUREMENTS AND ELEVATIONS CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Well ID Top of Well Casing (ft. NAVD 88) Top of Screen Elevation (ft. NAVD 88) Bottom of Screen Elevation (ft. NAVD 88) April 2019 Measured Water Level' (ft. BTOC) April 2019 Water Elevation (ft. NAVD 88) Monitoring Flow Zone GWA-32S 707.68 691.3 676.3 18 689.68 Shallow LRB-113R 809.07 712.21 707.21 55.21 753.86 Bedrock LRB-ID 809.16 730.32 725.32 54.52 754.64 Dee LRB-IS 809.12 760.34 745.34 53.6 755.52 Shallow LRB-213R 804.28 721.6 716.6 40.93 763.35 Bedrock LRB-21D 804.32 736.54 731.54 40.47 763.85 Dee LRB-2S 804.20 761.83 746.83 39.27 764.93 Shallow MW-1 852.69 815.49 805.49 31.45 821.24 Shallow MW-104BR 798.56 652.2 647.2 38.7 759.86 Bedrock MW-104BRA 798.96 654.35 634.35 39.24 759.72 Bedrock MW-104D 798.34 717.81 712.81 38.54 759.8 Dee MW-104S 798.68 760.49 750.49 40.06 758.62 Shallow MW-11D 854.15 768.62 763.62 41 813.15 Bedrock MW-2 858.05 818.05 808.05 45.42 812.63 Shallow MW-200BR6 636.42 588.7 583.7 0 NA Bedrock MW-200D 636.05 618.8 613.8 5.54 630.51 Dee MW-200S 635.89 631.18 623.18 4.25 631.64 Shallow MW-201BR 783.77 683.37 678.37 35.92 747.85 Bedrock MW-201D 783.98 747.12 737.12 35.33 748.65 Dee MW-202BR 789.63 688.87 683.87 38.2 751.43 Bedrock MW-202D 790.78 701.47 696.47 39.73 751.05 Dee MW-202S 789.97 742.6 727.6 41.15 748.82 Shallow MW-203BR 787.26 690.09 685.09 33.55 753.71 Bedrock MW-203D 785.57 696.51 691.51 31.9 753.67 Dee MW-203S 786.14 755.95 740.95 31.9 754.24 Shallow MW-204D 776.78 737.85 732.85 28.16 748.62 Dee MW-204S 776.29 754.55 739.55 27.67 748.62 Shallow MW2-7 777.64 762.02 747.02 13.27 764.37 Dee MW2-9 797.38 792.77 782.77 4.91 792.47 Dee MW-3 842.81 803.31 793.31 37.93 804.88 Shallow MW-4 767.58 737.38 727.38 11.68 755.9 Shallow MW-5 786.77 736.57 726.57 23.47 763.3 Shallow MW-6 836.91 810.07 800.07 30.18 806.73 Shallow MW-7 815.57 811.31 801.31 4.62 810.95 Shallow 013-4 777.6 762.57 747.57 21.68 755.92 Shallow 013-5 780.93 759.33 744.33 23.94 756.99 Shallow 013-9 799.59 760.42 751.02 36.79 762.8 Dee SFMW 1D 823.62 779.62 774.62 35.25 788.37 Dee SFMW-2D 848.62 798.62 793.62 42.22 806.4 Dee SFMW-3D 794.99 748.23 743.23 34.91 760.08 Dee SFMW-4D 781.28 743.5 738.5 23.38 757.9 Dee SFMW-5D 808.46 774.09 769.09 35.89 772.57 Dee Notes: ' - Manual water levels collected on April 8, 2019 Z CCR-4S pump intake is approximately 43 feet below top of casing 3 CCR-6S pump intake is approximately 12 feet below top of casing 4 CCR-8S pump intake is approximately 29.34 feet below top of casing 5 GWA-17S pump intake is approximately 41 feet below top of casing 6 Artesian conditions present ft. BTOC - feet below top of casing ft. NAVD 88 - feet North American Vertical Datum of 1988 BP - field measurement recorded as water level below pump intake NA - not applicable due to no available data * Abandoned sampling location ** - Survey information incomplete/not available Prepared by: DAA Checked by: ALA Page 3 of 3 TABLE 5-2 GROUNDWATER BALANCE SUMMARY CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Closure -by - Modeling Scenario Pre -Decanting Post -Decanting Closure -in -Place Excavation 4. 4. 4. 4. Water Balance Components 3 a 0 3 a 3 0- 0 3 a � 0- 0 3 a 3 0- 0 3 a O O, p Ol O O, p Ol O a, p Ol O O, p Ol LL LL LL u_ Direct recharge to the ash basin 20 119 56 119 Direct recharge to the watershed outside of the ash 120 100 120 92 basin Ash basin pond 200 Drainage inside the ash basin' 70 174 157 195 Drainage outside of the ash basin 16 11 Domestic water supply wells Remediation wells (i.e. IAP extraction system) 2 2 2 Flow through and under the dam 150 45 Other 120 2 1 3 Prepared by: YG Checked by: ALA Notes: ' Drainage includes streams, seeps, ditch, channel, canal, etc. Drainage streams included are depending on the scenario, where the pre -decanting scenario includes streams present prior to closure and closure-bv excavation includes streams that form within the excavated ash basin footprint after closure. Z Other refers to groundwater flow in/out the watershed that are not accounted in the above categories Flow in refers to recharge to the groundwater system Flow out refers to discharge from the groundwater system Remediation wells (i.e. interim extraction system) were installed in late 2018, however the extent of the ash basin watershed under pre -decanting conditions does not include the interim extraction system. Under post -decanting conditions the watershed extent expands to include gpm - gallons per minute Page 1 of 1 TABLE 5-3 SURFACE WATER CLASSIFICATIONS CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Adjacent Surface Water Body Surface Water Classification (15A NCAC 02B .0300) Belews Reservoir Class C, WS-IV Dan River Class WS-IV, WS-V Prepared by: ALA Checked by: CDE Notes• 1. Class C waters are protected for uses such as secondary recreation, fishing, wildlife, fish consumption, aquatic life including propagation, and survival. 2. Class WS-IV waters are protected as water supplies that are generally in moderately to highly developed watersheds. WS-IV waters are also subject to Class C water quality standards. 3. Class WS-V waters are generally upstream of Class WS-IV waters or waters currently or formerly used by industry for water supply. These waters are also protected for Class C uses. NCAC - North Carolina Administrative Code WS - Water Supply Page 1of 1 TABLE 6-1 BORON CONCENTRATIONS IN GROUNDWATER BELOW SOURCE AREA CORRECTION ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Well Beneath Number of Boron Concentration Boron Concentration Ash Sample Time Period of Range in Range in Overlying Pore (Flow Zone) Events Record Groundwater Water (Ng/L) (pg/L) AB-04BR 14 07/16/2015 - 25.7 j - 54 (bedrock) 10/18/2018 AB-04BRD 7 05/13/2016 - 27.6 j - < 50 (deep bedrock) 10/18/2018 < 50 - 21,900 (-60' saturated ash) AB-04D 07/16/2015 - (Deep) 14 10/18/2018 37.6 j - 212 AB-04SAP 4 03/21/2018 - 31.6 j - 258 M 1 (shallow) 10/18/2018 AB-05D 14 07/14/2015 - 30.4 j - < 50 926 - 17,100 (deep) 10/17/2018 (-45' saturated ash) AB-06D 14 07/08/2015 - 27.5 j - < 50 69.2 - 1,600 (deep) 10/16/2018 (-13' saturated ash) AB-07D 15 06/16/2015 - 26.9 j - 54 294 - 20,800 (deep) 10/15/2018 (-13' saturated ash) AB-08D 15 06/17/2015 - 26.8 j - < 50 123 - 13,800 (deep) 10/16/2018 (-44' saturated ash) Notes: < - concentration not detected at or above the adjusted reporting limit. j - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. M1 - Matrix spike recovery was high: the associated Laboratory Control Spike (LCS) was acceptable. Prepared by: ALA Checked by: CDE Page 1 of 1 TABLE 6-2 SOIL PSRG POG STANDARD EQUATION PARAMETERS AND VALUES CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Csoil = Cgw [Kd + My + %H')/Pbldf Inorganic Parameter Definition Default Values Units Parameters Csoil Calculated source concentrations for soil NA mg/kg CQW Applicable groundwater target concentration: 15A NCAC 02L Standard mg/L 15A NCAC 02L Standard df Dilution factor' 20 unitless Kd Soil -water partition coefficient for inorganics 4 Constituent Specific L/kg (range) ew Water filled soil porosity - vadose soils2 0.3 Lwater/Lsoll ea Air filled soil porosity - vadose soils3 0.13 Lair/Lsoil Pb Dry bulk density2 1.6 kg/L Henry's law constant -dimensionless where: H' H' = Henry's law constant (atm - m3/mole) x Constituent Specific3­5 unitless conversion factor of 41 Prepared by: ALA Checked by: CDE Notes: ' - Default value from Soil Screeninq Guidance: Technical Backqround Document (USEPA, 1996) 2 - Site specific value (Murdoch et al., 2019). Effective porosity represents unconsolidated material. 3 - DEQ default value appropriate for North Carolina 4 - Constituent Specific- Soil water partition coefficients (Kd) were obtained from the Groundwater Quality Signatures for Assessing Potential Impacts from Coal Combustion Product Leachate (EPRI, 2012). Sulfate Kd ranges from 0.1 to 2.1, based on sands/sediments and a pH range of 4.6 to 7.2 5 - a value of 0 is used for sulfate NA - Not applicable mg/L - milligrams per liter L/kg - liters per kilogram Lw, ,/Lso;, - volume of water filled spaces per volume of soil La;r/Lso;, - volume of air filled spaces per volume of soil kg/L - kilogram per liter Page 1 of 1 TABLE 6-3 SUMMARY OF UNSATURATED SOIL ANALYTICAL RESULTS CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Analytical Parameter pH Antimony Arsenic Barium Beryllium Boron Cadmium Chloride Chromium Cobalt Iron Manganese Molybdenum Selenium Strontium Sulfate Thallium Vanadium Reporting Units S.U. mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg PSRG Protection of Groundwater NE 0.9 5.8 580 63 45 3 938* 3.8* 0.9 150 65 7.1 2.1 1,500 1438* 0.28 350 2018 Background Threshold Valued 4.3-5.8 1 0.6 1 13 1 139 1 19 1 17 1 0.03 1 14 1 36 1 51 1 40,400 1 1,117 1 9.8 5 9 12 0.7 114 2019 Background Threshold ValueS214.6-7.01 0.6 1 43 1 122 1 2.9 1 35 1 0.9 1 402 1 47 1 60 1 61,967 1 1,257 1 4 5 7 403 0.8 231 Sample ID Sample Collection Date Analytical Results Background Unsaturated Soil BG-01D (1-2) 03/26/2015 4.8 j <3.1 35 42 0.89 <15.5 <0.37 <305 29 1.7 j 38,100 58 <3.1 <3.1 1.9 j <305 <3.1 55 BG-01D (11-11) 03/27/2015 5.7 j <3.9 11 27 0.68 12 j <0.47 <396 4.7 29 j- 12,200 1,010 8.9 <3.9 <3.9 <396 <3.9 14 BG-01D (21-21) 03/27/2015 5.4 j <3.9 7.5 50 0.88 13 j <0.47 <400 2.3 6.8 12,400 j+ 257 j+ <3.9 2.2 j <3.9 <400 <3.9 16 BG-01D (31-31) 03/27/2015 5.6 j <3.5 31 42 2.8 39 <0.42 <358 17 38 40,400 871 <3.5 2.9 j <3.5 <358 <3.5 51 BG-02D (1-2) 03/23/2015 5.5 j <3.8 3.31 25 0.32 j <18.9 <0.45 <363 8.5 <3.8 24,100 53 <3.8 <3.8 <3.8 <363 <3.8 47 BG-02D (10-12) 03/24/2015 5.0 j <3.5 2.7 j 71 0.86 35 j <0.42 <352 5.3 5.5 32,300 245 <3.5 j 3 j <3.5 j <352 <3.5 105 BG-02D (20-22) 03/24/2015 5.1 j <3.7 <3.7 89 0.29 j <18.5 <0.45 <367 <1.9 j 5 9,570 450 <3.7 j <3.7 <3.7 j <367 <3.7 20 BG-02D (30-32) 03/24/2015 5.2 j <4 <4 92 0.33 j <20.1 <0.48 <403 <2 j 5 13,000 680 <4 j <4 <4 j <403 <4 27 BG-03S (1-2) 05/12/2015 5.4 j <6.4 <6.4 30 0.37 14 j <0.77 <329 16 <6.4 27,800 40 <3.2 <4.8 <3.2 <329 <6.4 60 BG-03S (10-12) 05/12/2015 4.9 j <7.6 <7.6 32 0.75 21 <0.91 <362 22 16 44,200 513 <3.8 <5.7 <3.8 <362 <7.6 141 BG-03S (20-22) 05/12/2015 5.0 j <6.1 <6.1 68 0.76 17 <0.73 <308 15 8.1 36,800 216 <3 <4.6 <3 <308 <6.1 55 BGSB-01 (1-2) 07/26/2017 4.8 <0.46 59 B 38 1.6 <8.1 <0.023 3.4 j 37 3.5 49,000 66 B 0.98 j 1.5 2.5 j <12 0.38 64 BGSB-01 (5-7) 07/26/2017 4.6 <0.47 22 B 18 1.6 <2.4 <0.023 1.9 j 19 1.1 21,000 39 B <1.9 0.84 j 0.82 j <12 0.15 42 BGSB-01 (10-12) 07/26/2017 4.7 <0.6 9.1 B 47 1.4 <1.6 <0.03 1.2 j 6.9 5.8 12,000 180 B 0.56 j 1 j 0.76 <12 0.39 13 BGSB-01 (15-17) 07/26/2017 5.0 <0.4 5.6 B 46 1.3 <3.8 <0.02 <12 6.7 16 8,700 230 B <3 1.9 1.9 <12 0.66 9.8 BGSB-01 (20-22) 07/26/2017 4.8 <0.52 6.3 B 62 1.3 1.2 j <0.026 <11 5 21 11,000 250 0.97 j 1.5 2.8 <11 M 0.6 8.6 BGSB-02 (1-2) 07/26/2017 4.9 <0.37 3.9 B 14 0.28 <2.8 <0.019 4.2 j 10 1.8 22,000 59 B <2.2 0.71 j 1.5 8 j 0.14 65 BGSB-02 (10-12) 07/26/2017 4.6 <0.51 0.5 j,B 27 0.27 <10 <0.026 <12 1.1 j 4.8 11,000 110 B <8.1 1.8 <4 <12 0.066 j 35 BGSB-02 (15-17) 07/26/2017 5.0 <0.45 0.54 B 42 0.37 <17 0.025 <11 2.6 j 7.2 12,000 490 <13 2.7 <6.7 <11 0.19 24 BGSB-02 (20-22) 07/26/2017 5.0 <0.57 1.2 B 70 0.51 <22 <0.029 <12 7.8 7.2 17,000 480 <18 4.5 <9 <12 0.26 35 BGSB-02 (25-27) 07/26/2017 5.0 <0.38 0.85 B 140 0.57 <23 <0.019 <12 1.2 j 6.2 14,000 490 <19 4.1 <9.3 <12 0.27 18 BGSB-02 (30-32) 07/26/2017 5.3 <0.38 0.77 B 71 0.47 <8.8 0.033 <12 3.6 17 14,000 550 B <7.1 2.2 <7.1 <12 0.34 23 BGSB-03 (1-2) 07/26/2017 5.0 <0.41 3.2 B 22 0.39 <3.7 0.032 <11 20 1.4 22,000 42 B 0.5 j 0.56 j 1.7 <11 0.1 j 37 BGSB-03 (5-7) 07/26/2017 5.0 <0.3 2.8 B 38 0.56 <2.3 <0.015 1.8 j 5.1 6.7 9,800 170 B 0.81 j 0.96 0.33 j <11 0.27 28 BGSB-03 (10-12) 07/26/2017 5.2 <0.39 2.2 B 64 0.66 <13 <0.02 <12 27 31 25,000 540 B <10 2.8 <5 <12 0.32 95 BGSB-03 (15-17) 07/26/2017 4.9 <0.43 3.6 B 82 1.1 <12 0.032 <14 4.4 32 18,000 470 B <9.8 5 <4.9 <14 0.65 99 BGSB-03 (20-22) 07/26/2017 4.9 0.14 j 4.9 B 53 5.9 <10 M 0.013 j <14 43 M 22 51,000 M 630 B,M <8.2 M 2.5 <4.1 <14 0.2 280 GWA-03D (34-35.5) 05/04/2015 7.0 j <7.7 <7.7 108 0.97 <19.3 <0.93 <366 1.1 j <7.7 9,110 460 <3.9 j <7.7 11 <366 <7.7 18 GWA-04S (45-47) 03/05/2015 6.4 j <2.8 <2.8 80 0.52 5 <0.33 <284 1 j+ 2.2 j 7,760 383 <0.56 <2.8 4.3 <284 <2.8 9.4 GWA-12D (10-12) 04/15/2015 5.6 j <6.2 <6.2 27 <0.31 <15.4 <0.74 <315 <1.5 j 6.5 912 296 <3.1 <6.2 <3.1 j <315 <6.2 j <6.2 GWA-12D (15-17) 04/15/2015 5.4 j <5.6 <5.6 99 0.39 <13.9 <0.67 <281 <1.4 j 2.9 j 7,740 187 <2.8 <5.6 <2.8 j <281 <5.6 j <5.6 GWA-12D (20-22) 04/15/2015 5.3 j <5.8 <5.8 91 0.43 <14.5 <0.69 <285 0.97 j 3.5 j 7,870 135 <2.9 <5.8 <2.9 j <285 <5.8 j 8.2 GWA-12D (25-27) 04/15/2015 NA <7.9 <7.9 83 0.59 <19.6 <0.94 <402 4.7 4.53 9,790 247 <3.9 <7.9 <3.9 j <402 <7.9 j 10.6 GWASB-12 (5-7) 07/26/2017 4.4 <0.42 M 6.7 B 16 0.36 <2.1 <0.021 2.2 j 9.4 1 11,000 43 B 1.2 j 1.1 1 <13 M 0.14 20 M GWASB-12 (10-12) 07/26/2017 4.6 0.09 j 3.2 B 20 0.42 <2.9 <0.019 7 j 6.8 2 7,100 130 B 1.1 j 1.7 1.6 8.7 j,M 0.099 j 12 GWASB-12 (15-17) 07/26/2017 5.0 <0.31 3.2 B 51 0.53 <9.2 <0.015 <12 3.1 7 7,200 200 B <7.4 2.8 <3.7 <12 0.22 12 GWASB-12 (20-22) 07/26/2017 5.1 <0.36 2 B 30 0.48 <42 0.016 j 1.2 j 6.6 j 2.7 9,900 380 <34 7.7 <17 <12 0.17 8.4 Page 1 of 2 TABLE 6-3 SUMMARY OF UNSATURATED SOIL ANALYTICAL RESULTS CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Analytical Parameter pH Antimony Arsenic Barium Beryllium Boron Cadmium Chloride Chromium Cobalt Iron Manganese Molybdenum Selenium Strontium Sulfate Thallium Vanadium Reporting Units S.U. mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg PSRG Protection of Groundwater NE 0.9 5.8 580 63 45 3 938* 3.8* 0.9 150 65 7.1 2.1 1,500 1438* 0.28 350 2018 Background Threshold Valued 4.3-5.8 1 0.6 1 13 1 139 1 19 1 17 1 0.03 1 14 1 36 1 51 1 40,400 1 1,117 1 9.8 5 9 12 0.7 114 2019 Background Threshold ValueS214.6-7.01 0.6 1 43 1 122 1 2.9 1 35 1 0.9 1 402 1 47 1 60 1 61,967 1 1,257 1 4 5 7 403 0.8 231 Sample ID Sample Collection Date Analytical Results GWASB-12 (25-27) 07/26/2017 5.5 1 0.32 1 1.2 B 46 0.59 <23 <0.016 <12 5.9 6.1 1 9,500 230 B <9.1 5.1 <9.1 <12 0.18 9.9 Upgradient of Ash Basin Unsaturated Soil GWA-05S (25-26.5) 03/18/2015 4.2 j <3.4 2.4 j 121 0.42 <17.1 <0.41 <332 <1.7 j 3.3 j 4,590 450 <0.68 j 2.6 j 3.8 <332 <3.4 7.9 GWA-07S (30-31.5) 03/10/2015 5.4 j <3.5 3.4 j 488 2.7 17 j <0.42 <362 3 11 26,100 226 <3.5 5.6 9.6 <362 <3.5 76 GWA-08D (20-21.5) 04/07/2015 5.1 j <7.6 <7.6 83 0.74 <19 <0.91 <387 2.2 <7.6 7,910 103 <3.8 <7.6 6.2 <387 <7.6 11 GWA-09GTB (40-41.5) 05/27/2015 5.9 j <6.1 j 10.2 j- 620 j- 5.1 j- 31 j- <0.74 <325 j 55 j- 16 j- 44,100 j- 640 j <3.1 j 3.6 j- 3.2 j- <325 j <6.1 96 j- MW-202BR (40-42) 03/20/2015 5.2 j <2.8 1.6 j 33 0.64 5.6 <0.34 <278 2 j+ 12 6,870 156 <0.57 2.3 j 1.5 <278 <2.8 7.3 MW-202BR (47-49) 03/20/2015 6.0 j <3.2 <3.2 28 0.33 <3.2 <0.38 <306 0.63 j+ <3.2 j 1,130 18.5 <0.64 <3.2 1.9 <306 <3.2 <3.2 MW-202BR (60-61.5) 03/09/2015 6.0 j <3.4 <3.4 117 1.9 10 0.24 j <329 10.1 8.7 12,000 213 <0.69 <3.4 7.3 <329 <3.4 25 MW-203BR (20-21.5) 03/18/2015 4.2 j <3.4 <3.4 62 0.38 11 j <0.41 <331 1.8 7.9 9,350 281 <0.69 j <3.4 0.86 <331 <3.4 32 Within Ash Basin Waste Boundary Unsaturated Soil (Fill Material) AB-01S (20-21.5) 05/09/2015 5.7 j <6 61 54 3.1 <15.1 <0.72 <290 25 23 40,600 583 <3 <6 <3 <290 <6 45 AB-03D (40-41.5) 04/14/2015 6.5 j <6.8 5.6 j 45 2.4 <16.9 j <0.81 173 j 9.6 18 18,400 306 <3.4 j <6.8 4.7 <338 <6.8 13 Downgradient of Ash Basin Unsaturated Soil GWA O1S (20-21.5) 03/26/2015 5.2 j <2.9 57 85 5.3 <14.6 <0.35 <283 33 13 34,400 358 <2.9 <2.9 <2.9 <283 <2.9 44 GWA-10D (2-3) 04/13/2015 5.2 j <7.6 62 39 1.9 <19.1 j <0.92 <364 j 19 27 32,600 689 2 j <7.6 <3.8 j <364 <7.6 29 MW-200BR (0-1.5) 04/24/2015 4.9 j <6.8 44 36 1.3 26 <0.81 <332 40 4.3 j 25,100 68 <3.4 <6.8 <3.4 <332 <6.8 25 Notes: Prepared by: DAA Checked by: ALA 1 - Background threshold values were calculated using data from background unsaturated soil samples collected June 2015 to April 2017. Background values approved by NCDEQ on May 14, 2018. Z - Updated background threshold values were calculated using data from background unsaturated soil samples collected June 2015 to April 2017. The background threshold value updates retained extreme outlier concentrations in background unsaturated soil datasets (SynTerra, 2019). O bold highlighted concentration indicates value is greater than applicable regulatory standarad (PSRG POG) 0 bold highlighted concentration indicates value is greater than greatest background threshold value where there is no regulatory standard, or background threshold values are greater than regulatory standard O highlighted concentration indicates value is within range of background threshold values for constituents where there is no regulatory standard, or a background threshold value greater than regulatory standard *NC PSRG for POG is for hexavalent chromium, soil analytical is for total chromium < - concentration not detected at or above the adjusted reporting limit. *Calculated PSRG for POG; Using NCDEQ IHSB Preliminary Soil Remediation Goals companion notes (February 2018) B - Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in sample is less than 1OX the concentration in the method blank. Analyte concentration in sample could be due to blank contamination. j - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. j- - Estimated concentration, biased low. j+ - Estimated concentration, biased high. M - Matrix spike / matrix spike dup failure. BTV - background threshold value mg/kg - milligrams per kilograms NA - not applicable due to no available data NE - Not Established PSRG - Preliminary Soil Remediation Goals for the Protection of Groundwater (POG); NCDEQ Inactive Hazardous Sites Branch (IHSB) Preliminary Soil Remediation Goals table (February 2018) POG - Protection of Groundwater S.U. - Standard Unit Page 2 of 2 TABLE 6-4 SOURCE AREA INTERIM ACTIONS CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Groundwater and Surface Groundwater and Surface Water Remedy Water Interim Actions Active source remediation by removing ponded water in the ash basin. Decanting will lower the hydraulic head within the coal ash basin and reduce hydraulic gradients, reducing groundwater seepage velocities and Ash Basin Decanting COI transport potential. Decanting will return the groundwater flow system to its approximate condition, prior to construction of the ash basin, with the re-establishment of groundwater flow divides and groundwater flowing toward the perennial stream and then northward. A 10-well groundwater extraction was installed adjacent to Parcel A in the area northwest of the ash basin. The system was activated on March 14, 2018. The system currently operates at approximately 12 gpm extraction Interim Action Plan Accelerated flow rate. As of November 2019, approximately 9,900,000 gallons of Remediation Groundwater water have extracted by the system. Post -decanting, the 10 interim Extraction System action extraction wells are expected to have reduced extraction rates as a result of the reduced hydraulic head of the ash basin. The system is predicted to remove a total of 2.5 gpm. Continued operation of the system is included in the remedial alternatives evaluated. Modifications to the BCSS dam include tree removal, installation of an aggregate seepage collection and filter overlay system, and installation of Source Area Stabilization flumes, riprap channels, and stormwater culverts, riprap lined ditches, seepage collection berm and a concrete ditch among other items that can be found in an August 5, 2016 letter of record documentation (Appendix A). A toe -drain water collection system that consists of a 16-inch diameter by 18-feet deep wet well has been installed below the ash basin dam adjacent to the un-named tributary. The wet well storage capacity is Toe -Drain Water Collection approximately 2,000 cubic feet. The system construction and testing is System complete and will begin operation in January 2020. Once in operation, the toe -drain system will collect water from the toe of the ash basin dam and route it to the Dan River through new discharge piping to a permitted NPDES outfall. Prepared by: ALA Checked by: CDE Page 1 of 1 TABLE 6-5 MEANS OF GROUNDWATER COIs - JANUARY 2018 TO APRIL 2019 CORRECTIVE ACTIVE PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Analytical Parameter pH Antimony Arsenic Barium Beryllium Boron Cadmium Chloride Chromium (VI) Chromium Cobalt Iron Lithium Manganese Molybdenum Selenium Strontium Sulfate Thallium Total Dissolved Solids Vanadium Reporting Units S.U. pg/L pg/L pg/L pg/L pg/L pg/L mg/L pg/L pg/L pg/L pg/L pg/L pg/L pg/L pg/L pg/L mg/L pg/L mg/L pg/L 15A NCAC 02L Standard 6.5-8.5 1* 10 700 4* 700 2 250 NE 10 1* 300 NE 50 NE 20 NE 250 0.2* 500 0.3* 2018 Background Threshold Values (Shallow Flow Zone)' 5.1-6.0 1 1 58 1 0.362 50 1 15 1.75 4.72 0.509 750 NE 22.9 1 0.5 56.5 1.93 0.2 85 1.33 2019 Background Threshold Values (Shallow Flow Zone)Z 5.2-6.0 1 1 123 0.3 50 1 19 4 11 0.6 1600 2 40 0.5 1 46 2.043 0.2 93 3 2019 Background Dataset Range (Shallow Flow Zone)Z 5.3-5.9 0.1-1.1 0.04-1 19-124 0.03-0.6 2.5-50 0.03-1.0 1.2-18.8 0.2-2.7 0.5-11.7 0.02-1.3 22-11,100 0.39-2 3-189 0.1-1.3 0.1-1.4 7.9-48 0.1-2.4 0.02-0.2 20-90 0.1-6.4 2018 Background Threshold Values (Deep Flow Zone)' 5.2-7.0 1 1 12.6 0.219 50 1 20.9 0.411 3.3 1.6 240 NE 13 1 0.5 68.5 6.35 0.2 148 1.45 2019 Background Threshold Values (Deep Flow Zone)Z 5.6-7.0 1 1 16 0.1 50 0.08 19 0.6 3 2 226 95 57 2 0.5 73 8.447 0.1 134 2 2019 Background Dataset Range (Deep Flow Zone)Z 5.6-7.0 0.1-1.5 0.05-1.1 0.004-0.2 0.01-0.02 11.9-58.8 0.03-0.2 2.0-20.3 0.03-0.5 0.1-5.0 0.02-1.8 13-850 2.2-52.2 2.5-104 0.1-5.3 0.2-3.7 29.3-87.8 0.5-11 0.02-0.1 25-126 0.1-1.4 2018 Background Threshold Values (Bedrock Flow Zone)' 6.2-8.4 0.5 0.51 6.2 0.2 50 0.08 3 0.33 5.3 0.76 228 NE 9.9 3.7 0.5 100 9.6 0.1 133 0.82 2019 Background Threshold Values (Bedrock Flow Zone)Z 6.3-6.5 1 2 11 0.2 50 0.08 3 0.4 11 0.8 341 30 64 6 0.5 99 15.4 0.1 181 2 2019 Background Threshold Values (Bedrock Flow Zone)Z 6.2-8.4 0.1-1.4 0.1-1.5 3.0-11 0.01-0.2 33.3-50 0.03-0.1 2.3-3.2 0.03-0.3 0.5-34.7 0.03-0.8 27-228 3.9-30 3.9-87.1 0.5-3.7 0.4-0.5 32.6-100 2.5-22.5 0.1-0.1 52-250 0.2-2.3 Sample ID Flow Zone Mean, Geomean, or Median Result3 Background Locations° BG-01D Transition Zone 7.5 <0.5 0.52 13 0.10 51 0.096 12 0.29 0.74 0.49 135 52.4 64 <0.5 <0.5 89 6.7 <0.1 209 <0.3 BG-01S Shallow 5.5 <0.5 0.083 9.8 0.18 3.6 <0.08 7.6 50 1.1 4.4 1.3 <0.5 0.87 0.14 49 BG-02BRA Bedrock 8.7 0.65 0.93 5.5 <0.1 <50 <0.08 3.1 0.12 1.5 0.19 103 35 39 8.4 <0.5 79 14 <0.1 154 0.69 BG-02D Transition Zone 6.6 <0.5 <0.1 5.8 <0.1 <50 <0.08 18 0.20 0.69 0.11 <50 15 <5 2.0 <0.5 38 2.6 <0.1 123 1.2 BG-02S Shallow 5.8 <0.5 0.11 77 0.10 <50 <0.08 13 2.2 2.3 0.11 357 2.5 12 0.72 <0.5 34 0.76 <0.1 71 0.98 BG-03D Transition Zone 6.0 <0.5 0.084 12 <0.1 <50 <0.08 4.9 0.045 <0.5 <0.1 75 2.5 5.8 <0.5 <0.5 46 <1 <0.1 70 0.51 BG-03S Shallow 5.4 <0.5 <0.1 40 0.25 <50 <0.08 2 0.42 1.1 0.12 261 1.5 14 <0.5 <0.5 27 <1 <0.1 52 0.48 MW-202BR Bedrock 6.4 <0.5 0.17 <5 <0.1 <50 <0.08 2.7 0.21 1.4 <0.1 <50 4.2 <5 0.57 :<5 34 3.7 <0.1 <250 0.48 MW-202D Transition Zone 6.0 <0.5 % <5 <0.1 <50 <0.08 2.5 0.25 0.60 <0.1 <50 3.3 <5 <0.5 <0.5 38 1.5 <0.1 <250 0.39 MW-202S Shallow 5.7 <0.5 <0.1 24 0.19 <50 <0.08 1.4 1.0 1.2 <0.1 <50 <0.5 <5 <0.5 <0.5 11 <1 <0.1 <250 0.30 At or Within the Waste Boundary Locations AB-01BR Bedrock 7.2 <0.5 1.0 129 0.11 5,630 <0.08 340 0.033 2.5 1.0 2,400 93 707 3.7 <0.5 824 7.6 <0.1 723 0.21 AB-01BRD Bedrock 12.3 - - - - 422 - - - - - - - - - - - - - - AB-01D Transition Zone 5.6 <0.5 3.3 160 0.63 9,265 0.53 396 0.034 2.0 35 156 5.9 1,833 0.68 1.5 590 117 0.37 914 0.13 AB-01S Shallow 5.9 <0.5 3.9 86 0.094 10,240 0.25 392 0.032 1.3 29 231 0.9 1,865 0.31 1.0 680 141 0.32 962 0.21 AB-02BR Bedrock 8.0 103 0.48 8,870 1.0 410 1.1 1.4 83 8.5 104 12,200 1.5 1,660 53 0.17 1 100 0.33 AB-02BRD Bedrock 12.2 - - - - 20.2 - - - - - - - - - - - - - - - AB-02D Transition Zone 5.8 1.1 2.2 92 0.57 9,552 0.49 408 <0.025 1.6 70 1,012 11.3 9,030 0.76 0.67 678 75 0.50 922 <0.3 AB-02S Shallow 6.6 <0.5 1.7 23 <0.1 50.7 <0.08 6.3 0.14 1.0 1.2 231 0.7 528 2.0 <0.5 34 6.9 0.15 95.4 10 AB-03BR Bedrock 11.1 - - - - 538 - - - - - - - - - - - - - - AB-03D Transition Zone 7.2 <0.5 15.4 8.0 <0.1 2,836 <0.08 292 <0.025 1.9 2.8 445 198 91 5.3 <0.5 436 33 <0.1 721 0.24 AB-03S Shallow 6.3 <0.5 0.97 131 0.087 10,510 <0.08 37S <0.025 0.76 9.0 412 0.7 3,538 5.6 0.41 666 118 0.49 919 0.37 AB-04BR Bedrock 7.5 <0.5 0.48 6 <0.1 <50 <0.08 1.8 0.15 <0.5 <0.1 <50 11 17 3.9 <0.5 86 5.5 <0.1 <250 2.4 AB-04BRD Bedrock 8.9 <0.5 0.75 5.4 <0.1 <50 <0.08 1.1 0.035 <0.5 <0.1 <50 6.6 11 7.3 <0.5 64 14 <0.1 143 <0.3 AB-04D Transition Zone 6.2 0.21 3.4 23 <0.1 56 <0.08 3.3 0.69 0.72 0.094 71.4 12 162 4.3 0.64 1 159 3.0 <0.1 1 172 4.2 AB-04LOWERASH Ash Pore Water 9 7.1 409 47 <0.1 1,015 0.14 18 0.063 <0.5 0.10 176 26 22 963 2.7 498 77 <0.1 361 2.4 AB-04S Ash Pore Water 7.1 <0.5 101 135 <0.1 15,850 <0.08 544 0.025 0.57 0.071 10,564 76 819 16 <0.5 1476 214 <0.1 1,376 <0.3 AB-04SAP Shallow 5.7 0.37 2.6 99 0.17 91 <0.08 3.9 0.52 0.88 0.67 94 7.5 131 1.5 1.1 195 3.7 0.38 158 5.3 AB-04SL Ash Pore Water 10.8 - - - - 14 000 - - - - - - - - - - - - - - - AB-05D Transition Zone 6.6 <0.5 0.90 10 <0.1 <50 <0.08 0.88 0.43 0.71 0.095 79 4.5 6.6 2.3 0.67 50 4.4 <0.1 <250 3.4 AB-05S Ash Pore Water 8.1 <0.5 100 224 0.11 7323 <0.08 327 <0.025 <0.5 0.11 1,002 75 1,098 26 <0.5 1,260 186 <0.1 849 0.24 AB-05SL Ash Pore Water 10.1 1 6.6 57 197 <0.1 12,008 <0.08 1 330 <0.025 0.97 0.045 <50 217 1 <5 304 4.1 3475 206 0.038 1465 157 AB-06D Transition Zone 6.6 <0.5 0.088 19 <0.1 <50 <0.08 1.4 1 0.31 0.43 <0.1 50 3.5 <5 1.3 <0.5 56 3.4 1 <0.1 <250 3.5 AB-06S Ash Pore Water 6.6 0.81 3.9 209 <0.1 115 <0.08 4.7 0.085 0.70 1.1 582 12 15 4.5 2.2 124 20 <0.1 <250 3.2 AB-06SL Ash Pore Water 6.9 <0.5 5.9 223 <0.1 507 <0.08 7.4 <0.025 0.57 <0.1 2,482 43 116 0.85 <0.5 735 <1 <0.1 <250 0.67 AB-07D Transition Zone 6.7 <0.5 0.19 20 <0.1 <50 <0.08 4.8 0.069 0.25 0.09 153 9.3 25 1.1 <0.5 42 12.0 <0.1 <250 1.0 AB-07S Ash Pore Water 5.1 <0.5 30 30 1.2 2,315 0.68 108 0.030 1.2 34 53,040 56 2,768 1.9 1.7 494 320 3.1 765 0.61 AB-08D Transition Zone 6.1 <0.5 0.92 8.2 <0.1 <50 0.04 15.6 0.029 0.79 0.36 66 15 37 0.22 <0.5 71.6 <1 <0.1 <250 0.41 AB-08S Ash Pore Water 5.6 0.74 1 2.1 125 0.32 3,871 0.51 128 0.028 0.45 12 1,254 37 165 6.9 11 467 69 4.3 401 1 1.4 AB-08SL Ash Pore Water 6.8 0.22 259 335 0.11 6,733 <0.08 7.4 <0.025 1.8 0.52 56,475 45 1,030 80 0.56 1,187 1 6.8 0.064 376 23 AB-09BR Bedrock 7.7 <0.5 16 14 <0.1 <50 <0.08 4.4 0.029 0.54 0.071 1024 12 585 1.9 <0.5 115 4.8 <0.1 179 <0.3 AB-09D Transition Zone 7.3 0.25 3.3 5.3 <0.1 72.3 <0.08 5 <0.025 0.45 0.18 289 6.6 95 8.2 <0.5 71.2 13 <0.1 205 0.22 AB-09S Shallow 5.2 <0.5 0.094 52 0.11 <50 <0.08 6.2 0.066 0.46 16 241 0.7 559 <0.5 <0.5 6.8 <1 0.12 34 <0.3 CCR-01D Transition Zone 6.9 <0.5 9.1 5.7 <0.1 11 <0.08 26 1.3 0.78 - 78 3.8 0.57 20.1 <0.1 155 CCR-01S Shallow 4.8 <0.5 0.47 54 0.38 28 0.083 17 1.0 8.7 7.3 <0.5 0.30 <1 0.14 45 CCR-02D Transition Zone 5.2 <0.5 1.4 16 1.2 3,862 0.97 237 0.060 <0.5 7.5 <50 72 2 605 I <0.5 <0.5 621 3.0 <0.1 477 <0.3 CCR-02S Shallow 4.3 <0.5 15 411 2.7 6,266 0.36 292 0.028 4.3 256 109 9.1 6,350 <0.5 15 25 36 0.80 575 <0.3 CCR-04D Transition Zone 7.1 <0.5 1.8 49 <0.1 6,685 <0.08 386 1.8 1.7 218 2.3 <0.5 27 1 <0.1 866 CCR-04S Shallow 5.2 <0.5 1.3 1 275 1 2.4 7,793 0.65 291 1.5 9.0 12 <0.5 1.8 46 0.65 563 CCR-05D Transition Zone 12 55 CCR-05S Shallow 5.5 <0.5 2.3 164 0.28 10,630 0.1 398 - <0.5 35 3.6 <0.5 2.5 125 0.36 941 CCR-06D Transition Zone 5.5 <0.5 0.80 195 0.88 10,825 0.51 404 0.54 15 10 <0.5 1.4 110 0.52 892 R- 7D Transition Zn <0.5 0.2 17 <0.1 1 5,148<0.08 317 <0.5 1 1.1 59 < <0.5 1 32 1 <0.1 761 Page 1 of 4 TABLE 6-5 MEANS OF GROUNDWATER COIs - JANUARY 2018 TO APRIL 2019 CORRECTIVE ACTIVE PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Analytical Parameter pH Antimony Arsenic Barium Beryllium Boron Cadmium Chloride Chromium (VI) Chromium Cobalt Iron Lithium Manganese Molybdenum Selenium Strontium Sulfate Thallium Total Dissolved Solids Vanadium Reporting Units S.U. pg/L pg/L pg/L pg/L pg/L pg/L mg/L pg/L pg/L pg/L pg/L pg/L pg/L pg/L pg/L pg/L mg/L pg/L mg/L pg/L 15A NCAC 02L Standard 6.5-8.5 1* 10 700 4* 700 2 250 NE 10 1* 300 NE 50 NE 20 NE 250 0.2* 500 0.3* 2018 Background Threshold Values (Shallow Flow Zone)' 5.1-6.0 1 1 58 1 0.362 50 1 15 1.75 4.72 0.509 750 NE 22.9 1 0.5 56.5 1.93 0.2 85 1.33 2019 Background Threshold Values (Shallow Flow Zone)2 5.2-6.0 1 1 123 0.3 50 1 19 4 11 0.6 1600 2 40 0.5 1 46 2.043 0.2 93 3 2019 Background Dataset Range (Shallow Flow Zone)2 5.3-5.9 0.1-1.1 0.04-1 19-124 0.03-0.6 2.5-50 0.03-1.0 1.2-18.8 0.2-2.7 0.5-11.7 0.02-1.3 22-11,100 0.39-2 3-189 0.1-1.3 0.1-1.4 7.9-48 0.1-2.4 0.02-0.2 20-90 0.1-6.4 2018 Background Threshold Values (Deep Flow Zone)' 5.2-7.0 1 1 12.6 0.219 50 1 20.9 0.411 3.3 1.6 240 NE 13 1 0.5 68.5 6.35 0.2 148 1.45 2019 Background Threshold Values (Deep Flow Zone)2 5.6-7.0 1 1 16 0.1 50 0.08 19 0.6 3 2 226 95 57 2 0.5 73 8.447 0.1 134 2 2019 Background Dataset Range (Deep Flow Zone)2 5.6-7.0 0.1-1.5 0.05-1.1 0.004-0.2 0.01-0.02 11.9-58.8 0.03-0.2 2.0-20.3 0.03-0.5 0.1-5.0 0.02-1.8 13-850 2.2-52.2 2.5-104 0.1-5.3 0.2-3.7 29.3-87.8 0.5-11 0.02-0.1 25-126 0.1-1.4 2018 Background Threshold Values (Bedrock Flow Zone)' 6.2-8.4 0.5 0.51 6.2 0.2 50 0.08 3 0.33 5.3 0.76 228 NE 9.9 3.7 0.5 100 9.6 0.1 133 0.82 2019 Background Threshold Values (Bedrock Flow Zone)2 6.3-6.5 1 2 11 0.2 50 0.08 3 0.4 11 0.8 341 30 64 6 0.5 99 15.4 0.1 181 2 2019 Background Threshold Values (Bedrock Flow Zone)2 6.2-8.4 0.1-1.4 0.1-1.5 3.0-11 0.01-0.2 33.3-50 0.03-0.1 2.3-3.2 0.03-0.3 0.5-34.7 0.03-0.8 27-228 3.9-30 3.9-87.1 0.5-3.7 0.4-0.5 32.6-100 2.5-22.5 0.1-0.1 52-250 0.2-2.3 Sample ID Flow Zone Mean, Geomean, or Median Result3 At or Within the Waste Boundary Locations Continued CCR-07S Shallow 4.8 <0.5 0.13 162 3.9 84 0.26 82 <0.5 16 7.4 <0.5 <0.5 <1 0.26 183 CCR-08AD Transition Zone 5.6 <0.5 0.69 204 1.1 9,363 1.8 415 0.70 0.81 29 <0.5 <0.5 84 0.17 788 CCR-08D Transition Zone 5.8 <0.5 0.48 50 0.32 10,017 0.73 430 <0.5 43 60 <0.5 <0.5 80 0.13 773 CCR-08S Shallow 5.5 <0.5 0.60 175 1.6 9,793 1.2 377 3.7 18 4.8 0.54 0.83 104 0.45 746 CCR-09D Transition Zone 6.2 <0.5 0.17 5.1 <0.1 42 <0.08 18 1.1 0.14 16 0.86 0.61 18 <0.1 150 CCR-09S Shallow 6.0 <0.5 <0.1 21 <0.1 289 <0.08 25 1.8 <0.1 5.2 <0.5 0.51 8.7 <0.1 152 CCR-11S Shallow 6.3 <0.5 2.4 221 <0.1 6.9 <0.08 22 0.76 32 <2.5 0.66 <0.5 7.4 <0.1 377 CCR-1113 Transition Zone 1 5.8 1 0.5 0.25 42 0.063 4.5 0.08 16 0.61 0.96 7.6 1.11 0.5 1 17 0.1 1 250 CCR-12DA Transition Zone 9.0 0.95 1.4 11 <0.1 4.7 <0.08 2.3 1.1 0.11 27.7 6.0 <0.5 21 <0.1 147 CCR-12S Shallow 5.4 <0.5 <0.1 85 0.18 12 <0.08 2.8 0.68 <0.1 0.8 <0.5 <0.5 <1 <0.1 41 EXOB-01 Transition Zone 6.7 <0.5 25 24 <0.1 7,845 0.13 381 <0.025 4.3 192 12.772 70 3,180 2.4 <0.5 1 797 37 <0.1 864 <0.3 EXOB-02 Transition Zone 5.2 <0.5 4.9 218 1.6 8,083 0.69 423 0.043 1.0 139 1 99 1 11 4,600 <0.5 5.6 I 390 93 0.84 I 989 <0.3 At or Beyond the Compliance Boundary Locations Upgradient or the Ash Basin GWA-03D Transition Zone 6.1 <0.5 0.12 22.3 <0.1 <50 <0.08 9.7 1.0 3.0 0.095 201 2.4 10.3 0.54 <0.5 97.7 <1 <0.1 94 0.79 GWA-03S Shallow 5.8 <0.5 0.05 64.5 <0.1 <50 <0.08 9 0.23 1.2 0.15 104 <2.5 10.2 1.7 <0.5 109 <1 <0.1 101 0.44 GWA-06D Transition Zone 7.0 <0.5 2.0 19.5 <0.1 <50 <0.08 4.9 <0.025 0.69 1.2 1,570 7.6 514 5.1 <0.5 120 17.3 <0.1 <250 0.24 GWA-06S Shallow 5.1 <0.5 0.15 124 1.6 37.6 0.62 8.6 0.89 3.4 0.52 260 3.6 250 0.7 <0.5 34.3 14.1 0.26 <250 0.47 GWA-07D Transition Zone 7.5 0.78 1.1 14.5 <0.1 <50 <0.08 23.0 0.71 1.1 0.056 100 26.7 <5 8.6 <0.5 251 2.2 <0.1 <250 2.5 GWA-07SA Shallow 4.8 <0.5 <0.1 189 3.2 69.3 0.13 23.8 1.1 2.0 12.7 357 4.2 261 <0.5 <0.5 37.8 18.4 0.084 <250 0.68 GWA-08D Transition Zone 6.9 <0.5 1 0.29 6.5 <0.1 <50 <0.08 5.5 0.059 0.63 0.10 122 13.1 37.4 4.6 <0.5 59.1 11.9 <0.1 126 0.81 GWA-08S Shallow 5.4 <0.5 0.12 53.1 1 0.79 210 0.10 2.8 0.11 0.69 0.16 237 1.1 37.0 <0.5 11.2 230 55.9 <0.1 141 0.48 GWA-09BR Bedrock 6.6 <0.5 0.26 <5 <0.1 223 <0.08 57.0 0.22 1.8 0.26 1 128 18.3 135 1.7 <0.5 89.3 2.4 1 <0.1 <250 0.72 GWA-09D Transition Zone 6.2 0.30 0.25 9.8 <0.1 <50 <0.08 43.2 0.058 3.1 1.1 126 12.9 17.1 2.7 <0.5 106 4.8 <0.1 1 <250 0.43 GWA-09S Shallow 5.3 <0.5 0.47 83.5 0.45 <50 0.075 2.5 0.22 2.0 0.59 647 2.5 19.1 <0.5 <0.5 6.3 <1 0.14 49.5 0.74 GWA-22D Transition Zone 8.9 <0.5 0.91 16.1 <0.1 <50 <0.08 10.9 0.23 0.72 <0.1 56.6 33.6 13.5 5.1 0.51 86.7 7.7 <0.1 146 5.3 GWA-22S Shallow 5.9 <0.5 <0.1 <5 <0.1 <50 <0.08 2.2 0.31 1.1 0.15 <50 3.0 5.6 <0.5 <0.5 42.2 8.4 <0.1 64.4 1.2 GWA-25BR Bedrock 8.4 <0.5 0.67 7.3 <0.1 <50 <0.08 2.3 0.034 0.95 <0.1 54.7 4.8 9.7 12.8 <0.5 48.2 23.1 <0.1 134 <0.3 GWA-26BR Bedrock 7.7 <0.5 0.60 12.9 <0.1 <50 <0.08 10.0 0.026 1.0 2.9 228 2.2 104 11.3 <0.5 46.2 3.8 <0.1 <250 0.71 GWA-26D Transition Zone 5.6 <0.5 <0.1 41.9 0.17 <50 0.19 10.2 0.076 0.76 0.100 140 1 2.3 17.4 0.58 <0.5 30.3 1 0.77 <0.1 <250 0.17 GWA-26S Shallow 5.5 <0.5 <0.1 39.3 0.14 <50 <0.08 6.5 0.057 0.54 <0.1 101 2.6 13.0 <0.5 <0.5 16.2 0.54 <0.1 <250 0.19 LRB-01BR Bedrock 7.4 <0.5 0.34 5.5 <0.1 <50 <0.08 1.8 0.17 0.51 0.38 70.2 15.4 120 1.1 <0.5 46.1 1.4 1 <0.1 105 4.1 LRB-01D Transition Zone 6.4 <0.5 0.11 20.8 <0.1 <50 <0.08 2.4 22.3 15.0 <0.1 <50 3.0 <5 <0.5 0.61 67.3 21.6 <0.1 128 6 LRB-01S Shallow 6.3 <0.5 0.13 73.2 <0.1 <50 <0.08 1.1 8.0 7.9 0.44 196 1.0 23.3 0.29 <0.5 73.1 <1 <0.1 100 2.8 LRB-02BR Bedrock 7.0 <0.5 1 0.091 4.6 <0.1 <50 <0.08 4.2 0.083 <0.5 <0.1 <50 14.5 21.1 2 <0.5 106 2.2 <0.1 156 M1.5 LRB-02D Transition Zone 6.2 <0.5 0.10 15.3 <0.1 <50 <0.08 6.2 0.14 0.73 1.4 59.4 6.8 10.1 0.88 <0.5 149 1.2 <0.1 135 1.1 LRB-02S Shallow 5.8 <0.5 0.053 82.1 1 0.083 <50 <0.08 13.8 0.15 0.90 0.27 116 <2.5 59.9 <0.5 <0.5 80.1 <1 <0.1 119 0.32 MW-01 Shallow 5.2 20.5 0.11 <50 2.2 0.65 1.0 263 34.0 0.57 0.14 <25 MW-01D Bedrock 6.5 3.5 0.028 <50 8.1 0.83 0.72 28.0 28.1 0.86 0.11 76.3 0.51 MW-02 Shallow 5.9 0.37 - 73.4 0.36 60.3 - 3.7 - 2.4 0.36 724 - 31.9 - - - 0.41 0.16 60.5 0.81 MW-03 Shallow 5.6 <0.5 0.22 54.4 0.17 <50 <0.08 7.5 1.5 4.2 0.19 127 1.8 8.0 <0.5 <0.5 34.3 1.0 <0.1 44.7 0.65 MW-04 Shallow 5.9 <0.5 0.10 3.9 <0.1 746 <0.08 2.7 10.7 13.3 0.23 432 <2.5 8.5 <0.5 15.5 76.1 80.7 0.10 183 2.6 MW-05 Shallow 5.6 0.59 32.3 0.22 <50 2.1 0.77 199 6.1 0.083 35.0 0.58 MW-06 Shallow 5.7 - 62.8 0.68 <50 7.8 0.28 - 54.7 - 2.4 - <0.1 54.7 0.35 MW-07 Shallow 5.5 34.1 0.30 1309 6.2 0.77 111 9.8 13.4 89.9 173 0.40 MW-104BRA Bedrock 7.9 0.27 1.4 22 <0.1 <50 <0.08 3.6 0.27 23.9 0.57 186 4.8 38.8 10.5 <0.5 291 9.5 <0.1 1 135 6.5 MW-104D Transition Zone 6.9 <0.5 0.12 5.6 <0.1 <50 <0.08 1.2 0.89 1.8 0.057 167 5.2 8.2 2.9 1 <0.5 73.8 1.0 <0.1 109 4.2 MW-104S Shallow 5.4 <0.5 <0.1 67.7 0.15 <50 <0.08 0.94 1.4 3.9 0.12 139 0.9 8.4 1.3 <0.5 28.4 <1 <0.1 42.3 0.32 MW-203BR Bedrock 6.7 <0.5 0.12 <5 <0.1 <50 <0.08 9.8 0.74 1.8 0.05 89.7 11.7 6.1 2.3 <0.5 48.6 2.1 <0.1 117 2.7 MW-203D Transition Zone 6.6 <0.5 0.11 8.7 <0.1 <50 <0.08 3.6 1.5 1.8 <0.1 89.4 9.6 6.8 <0.5 34.7 1.0 <0.1 94.8 3.4 MW-203S Shallow 5.6 1 <0.5 I <0.1 48.8 0.17 1 <50 1 <0.08 1 1.4 1 0.30 1.1 <0.1 <50 0.8 1 <5 <0.5 <0.5 19.7 <1 <0.1 1 35.4 <0.3 Page 2 of 4 TABLE 6-5 MEANS OF GROUNDWATER COIs - JANUARY 2018 TO APRIL 2019 CORRECTIVE ACTIVE PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Analytical Parameter pH Antimony Arsenic Barium Beryllium Boron Cadmium Chloride Chromium (VI) Chromium Cobalt Iron Lithium Manganese Molybdenum Selenium Strontium Sulfate Thallium Total Dissolved Solids Vanadium Reporting Units S.U. pg/L pg/L pg/L pg/L pg/L pg/L mg/L pg/L pg/L pg/L pg/L pg/L pg/L pg/L pg/L pg/L mg/L pg/L mg/L pg/L 15A NCAC 02L Standard 6.5-8.5 1* 10 700 4* 700 2 250 NE 10 1* 300 NE 50 NE 20 NE 250 0.2* 500 0.3* 2018 Background Threshold Values (Shallow Flow Zone)' 5.1-6.0 1 1 58 1 0.362 50 1 15 1.75 4.72 0.509 750 NE 22.9 1 0.5 56.5 1.93 0.2 85 1.33 2019 Background Threshold Values (Shallow Flow Zone)Z 5.2-6.0 1 1 123 0.3 50 1 19 4 11 0.6 1600 2 40 0.5 1 46 2.043 0.2 93 3 2019 Background Dataset Range (Shallow Flow Zone)Z 5.3-5.9 0.1-1.1 0.04-1 19-124 0.03-0.6 2.5-50 0.03-1.0 1.2-18.8 0.2-2.7 0.5-11.7 0.02-1.3 22-11,100 0.39-2 3-189 0.1-1.3 0.1-1.4 7.9-48 0.1-2.4 0.02-0.2 20-90 0.1-6.4 2018 Background Threshold Values (Deep Flow Zone)' 5.2-7.0 1 1 12.6 0.219 50 1 20.9 0.411 3.3 1.6 240 NE 13 1 0.5 68.5 6.35 0.2 148 1.45 2019 Background Threshold Values (Deep Flow Zone)Z 5.6-7.0 1 1 16 0.1 50 0.08 19 0.6 3 2 226 95 57 2 0.5 73 8.447 0.1 134 2 2019 Background Dataset Range (Deep Flow Zone)Z 5.6-7.0 0.1-1.5 0.05-1.1 0.004-0.2 0.01-0.02 11.9-58.8 0.03-0.2 2.0-20.3 0.03-0.5 0.1-5.0 0.02-1.8 13-850 2.2-52.2 2.5-104 0.1-5.3 0.2-3.7 29.3-87.8 0.5-11 0.02-0.1 25-126 0.1-1.4 2018 Background Threshold Values (Bedrock Flow Zone)' 6.2-8.4 0.5 0.51 6.2 0.2 50 0.08 3 0.33 5.3 0.76 228 NE 9.9 3.7 0.5 100 9.6 0.1 133 0.82 2019 Background Threshold Values (Bedrock Flow Zone)Z 6.3-6.5 1 2 11 0.2 50 0.08 3 0.4 11 0.8 341 30 64 6 0.5 99 15.4 0.1 181 2 2019 Background Threshold Values (Bedrock Flow Zone)Z 6.2-8.4 0.1-1.4 0.1-1.5 3.0-11 0.01-0.2 33.3-50 0.03-0.1 2.3-3.2 0.03-0.3 0.5-34.7 0.03-0.8 27-228 3.9-30 3.9-87.1 0.5-3.7 0.4-0.5 32.6-100 2.5-22.5 0.1-0.1 52-250 0.2-2.3 Sample ID Flow Zone Mean, Geomean, or Median Result3 Upgradient or the Ash Basin Continued MW2-07 Transition Zone 5.2 0.33 19.7 2.35 1 13,600 1 0.59 10.1 0.22 0.44 18.8 298 120 681 1,123 0.46 MW2-09 Transition Zone 6.1 0.35 59.4 0.023 292 3.5 1.6 1 1.0 1 564 1 1 288 1 1 0.60 1 32.1 1 0.10 1 141 1 0.80 OB-05 Shallow 5.3 0.51 1 113 1 0.52 1 <50 3.8 1.3 1 0.32 1 687 1 1 34.7 0.079 0.12 <25 1 1.3 OB-09 Transition Zone 5.1 0.71 1 13.6 1 2.0 26 233 1 1.7 1 9.9 1.1 0.36 I 26.8 I 1 079 277 955 1 493 1 54 Downgradient of the Ash Basin CCR-13BR Bedrock 7.6 0.41 1.7 10 <0.1 <50 <0.08 22 0.21 2.5 0.18 107 30 31 9.4 <0.5 133 87 <0.1 300 1.5 CCR-13D Transition Zone 6.0 <0.5 0.72 13 0.13 <50 <0.08 14 <0.025 0.58 2.8 70 4.8 92 0.20 <0.5 52 13 0.077 73 <0.3 CCR-13S Shallow 5.6 <0.5 0.12 14 0.23 <50 <0.08 13 0.074 <0.5 0.78 134 4.2 34 <0.5 <0.5 44 0.78 0.076 54 0.33 GWA-01BR Bedrock 10.0 0.26 0.34 5.9 <0.1 <50 <0.08 2.4 <0.025 2.4 0.15 153 64 9.1 7.3 <0.5 75 6.4 <0.1 110 0.28 GWA-0113 Transition Zone 6.1 0.70 0.99 9.7 <0.1 <50 <0.08 89 0.040 4.8 9.0 198 36 40 6.4 <0.5 120 4.2 0.053 233 0.63 GWA-01S Shallow 4.7 0.44 0.22 192 4.5 633 0.16 55 0.17 0.87 3.7 186 it 131 0.4 0.4 68 0.99 0.25 102 0.25 GWA-02D Transition Zone 6.2 <0.5 3.3 <5 0.072 <50 <0.08 1.8 0.16 2.4 0.31 73.5 29 12 0.62 <0.5 24 0.82 <0.1 55 0.30 GWA-02S Shallow 5.3 <0.5 0.69 17 1 0.21 <50 <0.08 1 1.5 0.078 0.63 0.33 553 4.7 16 <0.5 <0.5 3.2 <1 0.082 <25 0.29 GWA-10DA Transition Zone 7.7 <0.5 2.4 10 <0.1 <50 <0.08 8.4 0.22 1.1 0.24 243 1 45 12 0.33 <0.5 90 9.0 <0.1 1 128 0.63 GWA-10S Shallow 4.0 <0.5 5.5 583 0.91 327 0.45 116 0.026 1.2 14 153 5.0 2 753 <0.5 3.3 46 <1 0.24 200 0.32 GWA-11D Transition Zone 6.0 <0.5 3.0 17 0.56 419 <0.08 251 <0.025 4.6 3.4 3,743 117 153 0.56 <0.5 538 4.2 <0.1 553 0.38 GWA-11S Shallow 4.6 <0.5 1.9 547 11 1338 0.81 203 0.032 2.4 10 377 33 162 <0.5 1.4 432 <1 0.38 415 0.44 GWA-16BR Bedrock 9.6 0.91 1.7 8.1 <0.1 <50 <0.08 0.95 0.079 0.64 <0.1 50 17 <5 1.6 <0.5 136 14 <0.1 130 0.54 GWA-16DA Transition Zone 6.5 <0.5 0.11 5.7 <0.1 1 <50 <0.08 0.99 0.051 0.80 0.92 1,972 4.3 19 0.63 <0.5 42 8.5 <0.1 <250 <0.3 GWA-16S Shallow 5.0 <0.5 <0.1 38 0.10 <50 <0.08 0.78 0.25 0.58 1.2 65 2.0 50 <0.5 <0.5 7.1 <1 <0.1 34 <0.3 GWA-17D Transition Zone 6.9 <0.5 0.11 8.1 <0.1 51 <0.08 1.1 <0.025 1.3 0.31 2,090 1.0 43 0.47 <0.5 41 12 <0.1 100 0.34 GWA-17S Shallow 5.3 <0.5 0.12 52 <0.1 55 0.079 1.1 0.037 0.66 11 237 1 2.4 167 <0.5 <0.5 1 10 19 <0.1 1 52 0.33 GWA-18D Transition Zone 6.4 <0.5 0.56 <5 <0.1 <50 <0.08 21 1.4 1.7 0.12 <50 12 30 0.86 <0.5 62 6.4 <0.1 <250 0.49 GWA-18SA Shallow 4.4 <0.5 2.6 644 5.9 693 0.94 145 0.026 1.1 89 188 36 1937 <0.5 1.3 138 <1 1.2 <250 <0.3 GWA-19BR Bedrock 10.4 0.77 0.32 7.9 <0.1 <50 <0.08 1.3 0.10 1.1 <0.1 53 57 <5 2.3 <0.5 51 14 <0.1 136 0.19 GWA-19D Transition Zone 7.2 <0.5 15 6.3 1 <0.1 <50 <0.08 3.6 0.043 <0.5 0.33 2,449 60 87 1.2 <0.5 80 13 <0.1 <250 0.20 GWA-19SA Shallow 4.7 <0.5 6.1 686 9.5 2,225 0.82 191 0.030 1.2 48 137 20 2,033 <0.5 5.9 153 <1 0.48 331 <0.3 GWA-20BR Bedrock 9.6 0.67 30 <5 <0.1 63 <0.08 27 0.047 1.7 <0.1 92 93 6.6 50 <0.5 55 15 <0.1 <250 0.43 GWA-20D Transition Zone 5.2 <0.5 4.1 42 1.5 9,690 1 1.9 425 0.030 1.1 2.9 54 63 1,987 <0.5 <0.5 863 68 0.2 885 <0.3 GWA-20SA Shallow 5.1 <0.5 3.0 198 5.8 11,176 1 1.1 415 0.050 0.92 17 148 18 5,000 <0.5 0.70 494 87 1 0.44 919 <0.3 GWA-21D Transition Zone 5.1 0.5 0.23 220 5.0 507 0.96 238 0.03 0.68 0.9 47 17 48 0.5 0.45 643 1 0.29 468 0.23 GWA-21S Shallow 4.7 <0.5 1.8 400 9.9 364 0.7 137 0.036 1.1 20 101 15 208 <0.5 1.3 194 1.9 0.27 247 <0.3 GWA-24BR Bedrock 7.7 1 <0.5 2.3 <5 <0.1 <50 <0.08 2.0 0.034 2.1 0.17 227 29 15 3.7 <0.5 108 5.3 <0.1 144 0.35 GWA-24D Transition Zone 5.4 0.58 <0.1 9.5 1 0.16 <50 0.089 56 0.16 4.0 0.22 105 1.8 13 0.59 <0.5 110 1.6 <0.1 157 <0.3 GWA-24S Shallow 5.8 - - - - <50 - - - - - - - - - - - 1.1 - 105 - GWA-27BR Bedrock 11.5 - - - - <50 - - - - - - - - - - - - - - - GWA-27D Transition Zone 5.1 <0.5 2.5 91 3.2 7,663 1.9 431 0.079 0.72 9.6 <50 1 58 2 810 0.4 0.42 1 833 23 0.37 1 834 <0.3 GWA-27S Shallow 4.6 <0.5 2.4 111 1.6 533 0.25 47 0.035 1.3 41 228 13 884 <0.5 1.3 38 4.1 0.25 154 <0.3 GWA-30D Transition Zone 7.4 <0.5 1.3 31 <0.1 <50 <0.08 4.3 0.14 <0.5 0.087 <50 25 70 3.2 <0.5 70 1.0 <0.1 116 0.58 GWA-30S Shallow 5.1 <0.5 0.34 18 0.54 <50 <0.08 5.2 0.042 <0.5 1.4 58 7.9 19 <0.5 <0.5 35 <1 <0.1 46 <0.3 GWA-31D Transition Zone 7.4 <0.5 1 0.28 4.2 0.16 <50 <0.08 2.3 1 <0.025 0.73 <0.1 819 26.2 33 0.34 <0.5 54 5.5 <0.1 104 <0.3 GWA-31S Shallow 5.5 <0.5 0.23 17 1 0.37 <50 <0.08 2.7 0.057 1.1 0.19 304 2.3 9.7 <0.5 <0.5 13 <1 <0.1 31 1 0.40 GWA-32D Transition Zone 8.0 0.56 0.49 9.7 <0.1 42 <0.08 71 0.073 0.80 0.050 1,004 64 213 1.4 <0.5 145 48 <0.1 356 <0.3 GWA-32S Shallow 6.3 <0.5 53 27 0.24 87 <0.08 50 0.034 1.2 58 34,820 1 9,180 0.67 <0.5 6.4 <1 0.70 128 <0.3 MW-200BR Bedrock 7.3 <0.5 1.3 <5 0.21 156 <0.08 62 <0.025 <0.5 0.08 237 42 132 0.43 <0.5 1 191 6.5 <0.1 273 <0.3 MW-200D Transition Zone 6.1 <0.5 0.79 <5 0.077 159 <0.08 39 0.10 0.54 0.064 56 13 13 0.29 <0.5 113 3.2 <0.1 156 <0.3 MW-200S Shallow 1 5.6 <0.5 1.6 48 0.32 62 <0.08 26 0.063 1 1.3 1 4.0 953 1.7 1 123 1 <0.5 <0.5 55 6.4 <0.1 107 0.67 MW-201BR Bedrock 7.6 0.54 0.46 <5 <0.1 <50 <0.08 5.0 0.080 0.85 0.054 63 14 44 11 <0.5 40 8.1 <0.1 127 0.32 MW-201D Transition Zone 6.1 <0.5 0.064 <5 <0.1 <50 <0.08 4.9 3.1 4.0 0.043 64 4.5 6.4 0.47 <0.5 62 1.1 <0.1 99 1.3 MW-204D Transition Zone 5.6 <0.5 <0.1 45 <0.1 <50 <0.08 1.9 0.098 <0.5 26 104 1.8 38 <0.5 <0.5 15 4.9 0.068 <250 0.39 MW-204S Shallow 5.6 <0.5 0.17 253 0.069 <50 0.15 2.9 <0.025 0.68 14 4 221 2.6 503 <0.5 <0.5 21 2.4 6.12 <250 0.43 Page 3 of 4 TABLE 6-5 MEANS OF GROUNDWATER COIs - JANUARY 2018 TO APRIL 2019 CORRECTIVE ACTIVE PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Analytical Parameter pH Antimony Arsenic Barium Beryllium Boron Cadmium Chloride Chromium (VI) Chromium Cobalt Iron Lithium Manganese Molybdenum Selenium Strontium Sulfate Thallium Total Dissolved Solids Vanadium Reporting Units S.U. pg/L pg/L pg/L pg/L pg/L pg/L mg/L pg/L pg/L pg/L pg/L pg/L pg/L pg/L pg/L pg/L mg/L pg/L mg/L pg/L 15A NCAC 02L Standard 6.5-8.5 1* 10 700 4* 700 2 250 NE 10 1* 300 NE 50 NE 20 NE 250 0.2* 500 0.3* 2018 Background Threshold Values (Shallow Flow Zone)' 5.1-6.0 1 1 1 58 1 0.362 50 1 15 1.75 4.72 0.509 1 750 NE 22.9 1 0.5 56.5 1.93 1 0.2 85 1.33 2019 Background Threshold Values (Shallow Flow Zone)2 5.2-6.0 1 1 123 0.3 50 1 19 4 11 0.6 1600 2 40 0.5 1 46 2.043 0.2 93 3 2019 Background Dataset Range (Shallow Flow Zone)2 5.3-5.9 0.1-1.1 0.04-1 19-124 0.03-0.6 2.5-50 0.03-1.0 1.2-18.8 0.2-2.7 0.5-11.7 0.02-1.3 22-11,100 0.39-2 3-189 0.1-1.3 0.1-1.4 7.9-48 0.1-2.4 0.02-0.2 20-90 0.1-6.4 2018 Background Threshold Values (Deep Flow Zone)' 5.2-7.0 1 1 12.6 0.219 50 1 20.9 0.411 3.3 1.6 240 NE 13 1 0.5 68.5 6.35 0.2 148 1.45 2019 Background Threshold Values (Deep Flow Zone)2 5.6-7.0 1 1 16 0.1 50 0.08 19 0.6 3 2 226 95 57 2 0.5 73 8.447 0.1 134 2 2019 Background Dataset Range (Deep Flow Zone)2 5.6-7.0 0.1-1.5 0.05-1.1 0.004-0.2 0.01-0.02 11.9-58.8 0.03-0.2 2.0-20.3 0.03-0.5 0.1-5.0 0.02-1.8 13-850 2.2-52.2 2.5-104 0.1-5.3 0.2-3.7 29.3-87.8 0.5-11 0.02-0.1 25-126 0.1-1.4 2018 Background Threshold Values (Bedrock Flow Zone)' 6.2-8.4 0.5 0.51 6.2 0.2 50 0.08 3 0.33 5.3 0.76 228 NE 9.9 3.7 0.5 100 9.6 0.1 133 0.82 2019 Background Threshold Values (Bedrock Flow Zone)2 6.3-6.5 1 2 11 0.2 50 0.08 3 0.4 11 0.8 341 30 64 6 0.5 99 15.4 0.1 181 2 2019 Background Threshold Values (Bedrock Flow Zone)2 6.2-8.4 0.1-1.4 0.1-1.5 3.0-11 0.01-0.2 33.3-50 0.03-0.1 2.3-3.2 0.03-0.3 0.5-34.7 0.03-0.8 27-228 3.9-30 3.9-87.1 0.5-3.7 0.4-0.5 32.6-100 2.5-22.5 0.1-0.1 52-250 0.2-2.3 Sample ID Flow Zone Mean, Geomean, or Median Result3 IMP Extraction System EX-01 Transition Zone 5.3 1.1 2.8 102 4.3 9,877 1.6 412 0.071 1.9 10 121 38 3,940 0.30 <0.5 853 69 0.37 893 <0.3 EX-02 Transition Zone 5.0 <0.5 3.0 146 7.1 10,157 1.5 538 0.18 4.5 17 <50 24 3,843 0.30 0.71 592 116 0.37 922 <0.3 EX-03 Transition Zone 5.2 <0.5 3.2 210 2.7 9,663 0.48 540 0.078 0.55 43 28 12 4,523 0.22 1.3 507 112 0.63 958 <0.3 EX-04 Transition Zone 5.2 <0.5 2.5 259 1.9 9,897 0.47 461 0.13 0.69 81 26 13 6,073 0.22 1.3 475 76 0.60 998 <0.3 EX-05 Transition Zone 5.3 <0.5 3.0 229 0.86 10,083 0.37 450 0.069 0.82 100 36 10 5,060 0.14 1.9 492 118 0.74 980 <0.3 EX-06 Transition Zone 5.5 <0.5 1.1 278 1.2 9,983 0.84 463 0.078 0.97 124 <50 16 7,313 <0.5 0.73 709 74 0.86 984 <0.3 EX-07 Transition Zone 5.3 <0.5 1.7 192 1.5 6,140 0.86 329 0.069 1.0 57 86 32 3,510 0.12 0.36 711 24 0.59 705 <0.3 EX-08 Transition Zone 5.2 <0.1 0.63 371 1.8 2 790 0.80 235 0.100 <0.5 9.7 <50 24 1 570 <0.5 <0.5 534 1.9 0.76 464 <0.3 EX-09 Transition Zone 5.1 0.97 471 2.4 2 600 1.1 285 0.073 7.0 153 43 1 365 795 0.97 0.56 595 <0.3 EX-10 Transition Zone 1 5.6 <0.5 1 1.0 1 7.5 1 1.3 1 3,970 0.38 1 264 1 0.038 1 4.3 7.3 31 1 125 1 1,450 1 0.29 1 <0.5 1 553 1 3.3 1 0.095 1 569 <0.3 Prepares by: ALA/LWU CneCxeg by: DAA/MUK Notes: ' - Background threshold values were calculated using data from background groundwater samples collected June 2015 to April 2017 z - Background threshold values were calculated using data from background groundwater samples collected October 2010 to December 2018 and sumbmitted to NCDEQ June 2019 3 - Statistical mean, geomean, or median calculated from data ranging from January 2018 to April 2019. Ash pore water results are not compared to groundwater standards or criteria. 4 - Background groundwater results are not compared to compartive criteria. Background concentrations greater than background threshold values are within background dataset ranges or piedmont setting background ranges. Groundwater flow directions across the Site indicate all approved background locations are representative of naturally occuring conditions. Mean or geomean results were used based on the central tendency of the data set. Median results were used for total radium only. For wells with datasets containing fewer than four valid results, the most recent valid sample data was used. Means were calculated for wells with four or more valid sample results. Sample results were excluded from calculations: 1) if turbidity > 10 NTU (for COIs other than boron) 2) for unusable data (RO qualified) 3) if a result was non -detect at a reporting limit (RL) greater than the normal laboratory RL Bold text - greatest comparative value O - bold highlighted concentration indicates value is greater than applicable regulatory standarad (02L or IMAC) O - bold highlighted concentration indicates value is greater than greatest background threshold value where there is no regulatory standard, or background threshold values are greater than regulatory standard O - highlighted concentration indicates value is within range of background threshold values for constituents where there is no regulatory standard, or background threshold values are greater than regulatory standard * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April 1, 2013. < - concentration not detected at or above the adjusted reporting limit. -' - no available data to conduct mean analysis NE - not established mg/L - Milligrams per liter pq/L - Micrograms per liter S.U. Standard unit Page 4 of 4 TABLE 6-6 COI MANAGEMENT MATRIX CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINA, LLC, BELEWS CREEK, NC Constituent Standards and Values - 02L Criterion Lines of Evidence (LOE) - 02L Criterion Rationale - 02L Criterion Single location with mean greater than 02L at or beyond the compliance boundary. Does not exhibit a discernable plume and Is Shallow 1 1 52.54 5.25 1 GWA-32S 9 9 1 Y not within the 02L boron plume footprint. Location is adjacent to a wetland; reducing conditions may enhance constituent solubility. No means of constituent greater than 02L in deep Flow zone at this location. Transition Zone 1 t 14.56 1.46 1 GWA-19D y i 6 1 y Single location with mean greater than background value at or beyond the compliance boundary. Does not exhibit a discemable plume but Is within the 02L boron plume footprint. arsenic µg/L 10 0.04-1.5 0.04 - 1.5 0.1 - 6.35 Non -conservative Single location with mean greater than background value at or beyond the compliance boundary. Does not exhibit a discernable Betlrock 1 2 30.42 3.04 1 GWA-20BR- 3 3 1 V plume but is within the 02L boron plume. Bedrock location exhibits slightly alkaline pH conditions which may enhance constituent solubility. Shallow 58 123 685.50 0.98 0 6 6 0 N No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. Transition Zone 13 16 220.83 0.32 0 N 15 0 0 N No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. Barium µg/L 700 0.004-124 0.004 - 124 11 - 840 Non -Conservative Bedrock 6 11 10.35 0.01 0 0 0 0 N No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. Shallow Zone 50 50 11176 15.97 4 GWS-1S, GWA-11S, GWA-19SA, GWA-20SA 9 9 7 V Mulitple locations with means greater than 02L at or beyond the compliance boundary and which exhibit a discernable plume. Transition zone 50 50 9690 13.84 2 4 4 3 y Mulitple locations with means greater than 02L at or beyond the compliance boundary and which exhibit a discernable plume. Boron µg/L 700 2.5-58.8 2.5 - 58.8 49.09 - 176.8 GWA-2013, GWA-27D V Conservative Bedrock zone 50 5o 156 0.22 0 2 2 0 N No means greater than 02L at or beyond the compliance boundary, however, flow and transport modeling predicts 02L plume migration at or beyond the compliance boundary. Shallow Zone 1 1 1.10 0.55 0 1 1 1 N No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. Transition Zone 1 0.08 1.92 0.96 0 N 2 2 2 N No means greater than 02L at or beyond the Compliance boundary. Does not warrant Corrective action. Cadmium µg/L 2 0.03-1.0 0.03 - 1.0 0.06 - 1 Non -Conservative Bedrock Zone 0,8 0.D8 <0.08 NA 0 0 0 0 N No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. Shallow zone 15 19 415 1.66 1 GWA-20SA 9 9 1 y Single location with mean greater than background value at or beyond the compliance boundary. Does not exhibit a discernable plume but is within the 02L boron plume footprint. Transition Zone 21 19 431 1.72 3 GWA-IID, GWA-20D, GWA-27D Y 8 8 3 V Mulitple locations with means greater than 02L at or beyond the compliance boundary and which exhibit a discernable plume. chloride mg/L 250 1.2-20.3 1.2 - 20.3 3 - 250 conservative Bedrock Zone 3 3 62 0.25 0 4 3 0 N No means greater than 02L at or beyond the compliance boundary, however, flow and transport modeling predicts 02L plume migration at or beyond the compliance boundary. Shallow Zone 5 11 2 0.22 0 0 0 0 N No means greater than background value at or beyond the compliance boundary. Does not warrant corrective action. Transition Zone 3 3 5 0.48 0 N 0 0 0 N No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. Chromium (Total) µg/L 10 0.1-34.7 0.1 - 34.7 1 - 26 Non -Conservative Bedrock Zone 5 11 2 0.22 0 0 0 0 N No means greater than background value at or beyond the compliance boundary. Does not warrant corrective action. Single location with mean greater than background value at or beyond the compliance boundary. Does not exhibit a discernable Shallow Zone 750 1600 34820 21.76 1 GWA-32S 1 1 0 V plume and is not within the 02L boron plume footprint. Location is adjacent to a wetland; reducing conditions may enhance constituent solubility. 300 Iron µg/L (Deep Flaw Transition Zone 24 226 13-11,100 13- 11,100 56.3 - 37,500 3743 12.48 4 GWA-111), GWA-1913, GWA-311), GWA-32D y 3 0 0 y Variable Mulitple locations with means greater than 02L at ar beyond the compliance boundary and which exhibit a discernable plume. Zone only) Bedrock Zone 228 341 237 0.70 0 1 0 0 N No means greater than background value at or beyond the compliance boundary. Does not warrant corrective action. Shallow Zone 23 40 9180 183.60 12 GWA-01S, GWA-10S, GWA-11S, GWA-16S, GWA37S, GWA-195A, GWA-20SA, GWA-21S, GWA-27S, GWA-32S, MW-200S, MW-2045 7 7 1 V Mulitple locations with means greater than 02L at or beyond the compliance boundary and which exhibit a discernable plume. Manganese µg/L 50 (Shallow Flow Zone only) 2.5-189 2.5 - 189 7 - 9,170 CCR-13D, GWA-IID, GWA-19D, GWA-20D, GWA-27D, GWA-30D, GWA-32D y Variable Transition Zone 13 57 2810 49.30 7 4 3 0 V Mulitple locations with means greater than background value at or beyond the compliance boundary and which exhibit a dible plume. discernable Bedrock zone 10 64 132 2.06 1 1 0 0 y Single location with mean greater than background value at or beyond the compliance boundary. Does not exhibit a discernable plume but is within the predicted 02L boron plume footprint. MW-200BR Shallow Zone 0.5 1 6 0.30 0 3 1 2 N No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. Transition Zone 0.5 0.5 0 0.02 0 0 0 0 N No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. Selenium l,g/L 20 0.1-3.7 0.1 - 3.7 0.5-2 Variable Bedrock zone 0.5 0.5 <0.5 NA 0 0 0 0 N No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. TABLE 6-6 COI MANAGEMENT MATRIX CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINA, LLC, BELEWS CREEK, NC Sulfate mg/L 250 Shallow Zone 2 2 0.1-22.5 0.1 - 22.5 1.2 - 510 87 0.35 0 V 1 o N 3 0 N Variable 1 0 N No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. 3 Transition Zone 6 8 68 0.27 0 5 No means greater than 02L at or beyond the compliance boundary. Does not warrant corrective action. Bedrock Zone 10 15 87 0.35 0 1 No means greater than 021- at or beyond the compliance boundary. Does not warrant corrective action. Total Dissolved Solids mg/L 500 Shallow Zone 85 93 20-250 20 - 250 50 - 1,200 919 1.84 1 GWA-20SA y 10 3 0 y Conservative Single location with mean greater than background value at or beyond the compliance boundary. Does not exhibit a discernable plume but is within the 02L boron plume footprint. Transition Zone 148 134 885 1.77 3 GWA-11D, GWA-201), GWA-27D 10 4 0 V Mulitple locations with means greater than 02L at or beyond the compliance boundary and which exhibit a discernable plume. Bedrock Zone 133 181 300 0.60 0 2 2 0 No means greater than 02L at or beyond the compliance boundary, however, flow and transport modeling predicts 02L plume migration at or beyond the compliance boundary. Constituent Standards and Values - IMAC Criterion Lines of Evidence (LOE) - IMAC Criterion Rationale - IMAC Criterion Antimony µg/L 1 Shallow Zone 1 1 0.1-1.5 0.1 - 1.5 0.5 - 4.247 <0.5 NA 0 V 0 0 0 N Conservative No means greater than IMAC value at or beyond the compliance boundary. Does not warrant corrective action. Transition Zone 1 1 1 0.70 0 1 o 0 N No means greater than IMAC value at or beyond the compliance boundary. Does not warrant corrective action. Bedrock Zone 1 1 1 0.77 0 1 o 0 N No means greater than IMAC value at or beyond the compliance boundary. Does not warrant corrective action. Beryllium µg/L 4 Shallow Zone 0.4 0.3 0.01-0.6 0.01 - 0.6 0.053 - 1 11 2.74 5 GWA-01S, GWA-11S, GWA-19SA, GWA-20SA, GWA-21S 0 0 0 y Non -Conservative Mulitple locations with means greater IMAC value at or beyond the compliance boundary and which exhibit a discernable plume. Transition Zone 0.2 0.1 5 1.24 1 GWA-21D 0 0 0 V Single location with mean greater than background value at or beyond the compliance boundary. Does not exhibit a discernable plume but is within the 02L boron plume footprint. Bedrock Zone 0.2 0.2 0 0.05 0 o 0 0 N No means greater than IMAC value at or beyond the compliance boundary. Does not warrant corrective action. Cobalt µg/L 1 Shallow Zone 0.5 0.6 0.02-1.8 0.02 - 1.8 0.2 - 88.85 58 58.00 13 GWA-01S, GWA-10S, GWA-11S, GWA-16S, GWA-17S, GWA-19SA, GWA-20SA, GWA-21S, GWA-27S, GWA-30S, GWA-32S, MW-200S, MW-2045 y 16 6 o V Variable Mulitple locations with means greater than IMAC value at or beyond the compliance boundary and which exhibit a discernable plume. Transition Zone 2 2 25 12.30 6 CCR-13D, GWA-01D, GWA-11D, GWA-20D, GWA-2]D, MW-204D 5 0 0 V Mulitple locations with means greater than background value at or beyond the compliance boundary and which exhibit a discernable plume. Bedrock Zone 0.8 0.6 0 0.18 0 0 c 0 N No means greater than IMAC value at or beyond the compliance boundary. Does not warrant corrective action. rhal6vm µg/L 0.2 Shallow Zone 0.2 0.2 0.02-0.2 0.02 - 0.1 0.1-0.2 0.7 3.48 g GWA-01S, GWA-10S, GWA-1IS, GWA-19SA, GWA-20SA, GWA-21S, GWA-27S, GWA-325 y o o 0 y variable Mulitple locations with means greater than IMAC value at or beyond the compliance boundary and which exhibit a discernable plume. Transition Zone 0.2 0.1 0.4 1.87 2 GWA-21D, GWA-27D o 0 o V Mulitple locations with means greater than IMAC value at or beyond the compliance boundary and which exhibit a discernable plume. Bedrock Zone 0.1 0.1 <0.1 NA 0 0 0 0 N No means greater than IMAC value at or beyond the compliance boundary. Does not warrant corrective action. vanadium lic/L 0.3 Shallow Zone 1 3 0.1-6.4 0.1- 6.4 0.36 - 26 0.7 0.22 0 V 0 0 o N Non -Conservative No means greater than background value at or beyond the compliance boundary. Does not warrant corrective action. Transition Zone 1 2 1.3 0.63 0 0 0 0 N No means greater than background value at or beyond the compliance boundary. Does not warrant corrective action. Bedrock Zone 1 2 1.5 0.75 0 o 0 o No means greater than background value at or beyond the compliance boundary. Does not warrant corrective action. Constituent Standards and Values - Background Criterion Lines of Evidence (LOE) - Background Criterion Rationale - Background Criterion chromium (Hexavalent) µg/L NE Shallow Zone 2 4 0.03-2.7 0.03 - 2.7 0.03 - 12 0.2 0.04 0 N 5 5 0 N Variable No means greater than background value at or beyond the compliance boundary. Does not warrant corrective action. Transition Zone 0.4 0.6 3.1 5.13 1 MW-201D 7 2 0 V Single location with mean greater than background value at or beyond the compliance boundary. Does not exhibit a discernable plume and is not within the 02L boron plume footprint. Bedrock Zone 0.3 0.4 0.2 0.52 0 2 g 0 N No means greater than background value at or beyond the compliance boundary. Does not warrant corrective action. TABLE 6-6 COI MANAGEMENT MATRIX CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINA, LLC, BELEWS CREEK, NC Constituents of Interest 201J CSA U tlate P ) Reporting po g Unit 02L or IMAC Criterion Groundwater Zone Statistically Background Thresholtl Derivetl Back Value'•a Flow Zone l9 Belews Creek Steam Station Flow Zone Background Dataset Range Belews Creek Steam Station 9roun Background net aset Range Piedmont Background groan Value Range maximum Mean Concentration Yon at or Beyond Compliance Boundary Groundwater Exceedance Rat"' Number of Wells Greater Than Com Comparative Criteria At or Beyond Compliance Boundary ao° M1° Groundwater Monitoring Wells With COI Concentration Greater a g Qde' a Than Comparative Criteria Para ive °Pyr to aFx at°° �:•'�` Fe x a ° N� lTQ ' F cv 'L` c 0� O E �a �qao a b pT ¢c, p Q PQ 3 °,S aF° ayv JQp° E Q� G° `a°° ° c0 JQ ; 4 c°p5 �a ( Rationale for Selection of COIs for Corrective Action Evaluation `Eati ) gr P o (constituents where no means are greater than comparative criteria � o I P PP n all flow iOn¢s and/or multiple lines Of evidence support that <OnsLILU¢nt OC<DYrent¢s a `s are not related to the source area, no corrective action is warranted) Ve locations with means greater than background value at or beyond the compliance boundary and , ®®© ®®® MEMOMulitiple Transiti.n �onc ME plume but is within the 02L boron plume footprint Mulitiple locations with means greater than background value at or beyond the compliance boundary and which exhibit a Bedrock Zone NONNI ENMEN CCR--.R, CiVIA4.Bl-, GW-213.1-, MW-2 ... I cl_r nal,le plume. leveral bedrock locations exhibit slightly alkaline I conditions which may enhance constituent -lub! iity. Remaining bedrock wells am within the 02L boron plume footprint. plume and is not within the 02L boron plume footprint. MEN MIMMIN ME MO Molybdenum plume and are not within the 02L boron plume footprint. =00 MM0 MOOD WAl 3WAl .--2.-, Mulitiple locations with means greater than background value at or beyond the compliance boundary and which exhibit a ME MMEN GWA21SMW200S discerrable plume. ®■■ 00M ®MOM M.1itiple locations with means gre.ter than background value at or beyond the compliance boundary and which exhibit a di—rinable plume. MMENCCR-�M'.WA-A.' G---.R,.W-2 ... R Vilulitiple locations with mean. greater than background value at or beyond the compliance boundary and which exhibit a =MEN Prepared by: DAA Checked by: ALA Real � - 0.e erence Crirenen o - Evidence appppw= inelpaipn � - Eeeenee eppporca «dpnpn nai u n1la re ettz a C01 Bt daliffie,1in ffie 2017 CSA Update (sy—rm, 201]), -, the atldift onithl— ackground t1--ltl values were calculatetl using tlare hom backgrountl grountlwatar samples coH—d 3une 201E re April 2017 3- Ux_d background MresM1old values are in the thiN wlumn and were calculated using tlata from backgrountl groundwater samples.11—d October 2010 to December 2018 antl sumbmittM W NCDEQ]une 2019 - Bedrock well [ha[ exM1lEl[s sIIgM1[ly alkllne pH (e10 S.U.) water gualiry. SIIgMIy alkaline wntli[ipnz appear localizetl and unchamcterlstic of betlrock flaw zone and mlgM1[ be attributable [p well Inztallatlon aRivi[les. 30 wells were usetl in tM1e evaluation, inclutling: CCR-1360., CC0.-13D, CC0.-13g,GWA-S1D,GWA-115,GWA-1680.,GWA-S6DA,GWA-169,GWA-1]D,GWA-1]s,GWA-1980.,GWA-19D, GWA-195A, GWA-180., G WA-1D, 49/L-mcro rams er liter mg/L- milligrams per Ilrer —Applicable NE No[ B[ablisM1etl .. w d-4nita Wells Within the Waste Boundary Well ID Boron Chloride Lithium Total Dissolved Solids Ash Pore Water Wells S NE NE NE E S S D NE AB-06SL D D S S S AB-07S AB-08S S AB-08SL S S Shallow Flow Zone AB-01S S S S S AB-02S D D ND D AB-03S D D S D AB-04SAP D S S S AB-09S ND S Deep Flow Zone AB-01D D D S D AB-02D D D S D AB-03D S S S S AB-04D D S S S AB-05D ND S S S AB-06D ND S S S AB-07D ND D S AB-08D ND S S AB-09D S D S Bedrock Flow Zone AB-01BR S S S S AB-04BR S S S AB-04BRD ND D S AB-09BR ND D S AB-09BRD NE NE NE NE TABLE 6-7 SUMMARY TREND ANALYSIS RESULTS FOR MONITORING WELLS CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Wells Between Waste Boundary and Compliance Boundary Well ID Boron Chloride Lithium Total Dissolved Solids Shallow Flow Zone CCR-01S ND CCR-02S S CCR-04S S D D CCR-05S S D D S CCR-06S CCR-07S NE D NE D NE S NE D CCR-08S CCR-09S S S CCR-11S ND S D S CCR-12S ND S S EXOB-01 C D S S EXOB-02 S S S S GWA-02S ND S D ND GWA-18S NE NE NE NE Deep Flow Zone CCR-01D ND CCR-02D S S D CCR-04D S S D CCR-05D D S S S CCR-06D S D S D CCR-07D S S CCR-08AD S D D D CCR-08D S D S D CCR-09D S S CCR-11D ND D CCR-12D ND NE NE NE CCR-12DA ND D S GWA 62D ND S S S GWA 18D ND S S Wells Downgradient of the Source Area At or Beyond Compliance Boundary Well ID Boron Chloride Lithium Total Dissolved Solids Shallow Flow Zone CCR-13S NE NE NE NE GWA-01S S GWA-10S GWA-11S S D S GWA-19SA S S D D GWA-20SA S D D D GWA-21S S D S GWA-24S NE NE NE NE GWA-27S D GWA-30S ND S GWA-31S ND S S GWA-32S S MW-200S Deep Flow Zone lE CCR-13D NE NE NE GWA-01D ND GWA lODA ND GWA-11D S S GWA-19D ND S S S GWA-20D D D D GWA-21D S S GWA-24D ND S S GWA-27D S S S S GWA-30D ND S S GWA-31D ND S S GWA-32D S S S MW-200D D D S D MW-201D ND S D Bedrock Flow Zone CCR-13BR NE NE NE NE GWA-01BR ND S NE S GWA-19BR ND NE NE NE GWA-20BR S S S GWA-24BR ND S S S GWA-27BR NE NE NE MW-2006R S S MW-201BR ND S D S Notes: 1. Summary of results and trends are presented for samples collected from 2011 - 2019. 2. Trend results are presented when at least four samples were available and frequency of detection was >50 % . Statistically significant trends are reported at the 90 % confidence level. 3. Variability Index (VI) is calculated as the (maximum - minimum) / median concentration and is calculated using detected concentrations only. Values less than 1 indicate low variability in the dataset. ND - Greater than 50 percent of constituent concentrations were non -detect D - Statistically significant, decreasing concentration trend S = Stable. No significant trend and variability is low (VI < 1) = No significant trend and variability is high (VI > 1) = Statistically significant, increasing concentration trend. NE = Insufficient number of samples to evaluate trend (n < 4) Mann -Kendall trend analysis ano results are preparea DY Arcaals D.S. Inc. and included in a technical memorandum titled Plume Stability Evaluation - Belews Creek Steam Station (Arcadis 2019) Page 1 of 1 TABLE 6-8 SEEP CORRECTIVE ACTION STRATEGY CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Regulatory Approximate Average Seep ID General Location Present Flow Seep Corrective Action Strategy Program (cfs) Channel flow northwest of ash Further decanting, and groundwater corrective action might cause seep to become dry. S-02 SOC basin to the Dan River 0.07 Besides source control measures (i.e. decanting and ash basin closure), no additional corrective action for this location is anticipated. East of ash basin; former ash Further decanting and ash basin closure might cause flow to cease in the future S-06 SOC basin permitted outfall to Belews 0.01 Besides source control measures (i.e. decanting and ash basin closure), no additional corrective Reservoir action for this location is anticipated. S-08 SOC South of Pine Hall Road Landfill 0.05 Because of the seeps relatively remote location and low flowing conditions, corrective action using phytoremediation technology would be considered. 5-09 SOC South of ash basin and hydraulic 0'1 Location is associated with the Structural Fill, therefore corrective action for this location will be divide, west of Structural Fill addressed in the corrective action plan for the Structural Fill. S-11 NPDES North of ash basin, at toe of ash 0.75 No corrective action necessary. This location is part of the ash basin waste water treatment basin dam system and included in the NPDES permit. Seeps are comingled. North of Further decanting and groundwater corrective action might cause flow to cease. S-10 and S-18* SOC and NPDES ash basin, downstream of ash 0.15 Potential corrective action remedies to address seeps include, but not limited to, basin dam phytoremediation and/or an extraction trench or shallow extraction well(s). Notes: cfs- cubic feet per second NPDES - National Pollution Discharge Elimination System SOC - Special Order by Consent *Seep S-18 flows into seep S-11 Prepared by: ALA Checked by: 1EC Page 1 of 1 TABLE 6-9 WATER SUPPLY WELL ANALYTICAL RESULTS SUMMARY CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Chromium Total(VI) Analytical Parameter Antimony Arsenic Barium Beryllium Boron Cadmium Chloride Chromium Cobalt Iron Lithium Manganese Molybdenum Selenium Strontium Sulfate Thallium Dissolved Vanadium Solids Impacted by Coal Ash Comments Reporting Units ug/L ug/L ug/L ug/L ug/L ug/L mg/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L mg/L ug/L mg/L ug/L 15A NCAC 02L Standard 1* 10 700 4* 700 2 250 NE 10 1* 300 NE 50 NE 20 NE 250 0.2* Soo 0.3* 2017 Background Threshold Values (Bedrock Unit)' 1 1 6 0.2 50 0.8 3 0.3 5 0.8 228 NE 10 4 0.5 100 10 0.1 133 1 2019 Background Threshold Values (Bedrock Unit)' 1 2 11 0.2 50 0.08 3 0.4 11 0.8 341 30 64 6 0.5 99 IS 0.1 181 2 2019Background Data Set Range (Bedrock Unit)2 0.1 - 1.4 0.1 - 1.5 3.0 -11 0.01 - 0.2 33 -50 0.03 - 0.1 2.3 - 3.2 0.03 - 0.3 0.5 - 34.7 0.03 - 0.8 27 - 228 3.9-30 3.9 - 87.1 0.5 - 3.7 0.4 - 0.5 32.6 - 100 2.5 - 22.5 0.1- 0.1 52 - 250 0.2 - 2.3 SynTerm Sample ID Sample Collection Date Analytical Results Map ID BC-1002 BC-1002 10/27/2016 <0.5 <0.1 16.5 0.1 <25 <0.08 1.4 <0.03 <0.5 <0.1 <50 NA 1.8 <0.5 <0.5 13.5 <2 <0.1 <25 <0.3 NO Southwest and upgradient of the ash basin. Not within the direction of groundwater Flow from the ash basin and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. BC-2000 BC2000-RAW 07/18/2017 <0.5 0.44 18.7 <0.1 <25 <0.08 2.1 <0.075 <5 <0.1 NA 8.7 <0.5 32.5 9.2 <0.1 87 <0.3 NO West and upgradient of the ash basin. Not within the direction of groundwater flow from the ash basin and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 02/01/2018 <0.5 2 0.42 <0.1 5.5 <0.08 4.3 <0.025 <0.5 <0.1 <50 NA 1.8 3.6 <0.5 54.3 9.5 <0.1 107 0.46 NO BC-2002 BC2002-RAW Southwest and upgradient of the ash basin. Not within the direction of groundwater Flow from the ash basin O6/12/2018 <0.5 2 0.59 <0.1 <5 <0.08 4.6 <0.025 <0.5 <0.1 <50 NA 1.8 <0.5 63.3 8.3 <0.1 108 <0.3 NO and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 11/14/2017 <0.5 0.39 0.74 <0.1 <25 <0.08 1.6 <0.025 <0.5 <0.1 <50 NA 52.8 1.5 <0.5 24.5 2 <0.1 74 <0.3 NO Southwest and upgradient of the ash basin. Not within the direction of groundwater Flow from the ash basin BC-2003 BC2003-RAW 02/O1/2018 <0.5 <0.1 7.5 <0.1 <5 0.085 1.6 <0.025 <0.5 <0.1 <50 NA 2.3 <0.5 <0.5 24.3 2.4 <0.1 55 <0.3 No and PHR Landfill. Outride of the ash basin drainage system, separated by hydrologic divides. 05/15/2018 <0.5 <0.1 7.2 <0.1 <5 <0.08 1.5 0.065 <0.5 <0.1 <50 NA 2 <0.5 <0.5 23.4 2.2 <0.1 58 <0.3 NO 07/18/2017 <0.5 0.66 20.1 0.11 <25 <0.08 1.8 <0.025 <0.5 <0.1 <50 NA 7.5 0.58 <0.5 15.2 1.2 <0.1 48 <0.3 NO BC-2004 BC2004-RAW Southwest and upgradient of the ash basin. Not within the direction of groundwater Flow from the ash basin 03/25/2018 <0.5 0.2 18.4 0.1 <25 <0.08 2 <0.025 <0.5 <0.1 <50 NA 7.6 0.72 <0.5 17 1.4 <0.1 38 <0.3 NO and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 04/10/2018 <0.5 0.2 20.5 0.1 <25 <0.08 2 <0.025 <0.5 <0.1 <50 NA 7.7 0.59 <0.5 17.4 1.3 <0.1 47 <0.3 NO BC-2005 BC2005-RAW 10/05/2017 <0.5 0.2 0.94 <0.1 <25 <0.08 1.5 0.037 <0.5 <0.1 <50 NA 1.7 <0.5 <0.5 24.3 1 <0.1 49 0.34 NO Southwest and upgradient of the ash basin. Not within the direction of groundwater Flow from the ash basin and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 05/14/2018 <0.5 1.8 4.5 <0.1 <5 0.24 11.9 <0.025 <0.5 <0.1 <50 NA <0.5 2.1 <0.5 75 3.6 <0.1 170 0.37 NO Bc-2006 BC2006-RAW Southwest and upgradient of the ash basin. Not within the direction of groundwater Flow from the ash basin and PHR Landfill. Outride of the ash basin drainage system, separated by hydrologic divides. 06/13/2016 <0.5 0.49 1.2 <0.1 <10 <0.08 62.8 <0.025 <0.5 <0.1 <50 NA 6.6 <0.5 <0.5 33.8 <1 <0.1 155 <0.3 NO BC-200] BC2007-RAW Ol/29/2018 <5 2 2.6 <0.1 <5 <0.08 1.2 0.5 <0.1 <50 NA 0.62 <0.5 <0.5 45.6 <1 <0.1 81 1 NO West and upgradient of the ash basin. Not within the direction of groundwater flow from the ash basin and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 02/06/2018 <0.5 11.4 21.7 <0.1 <5 0.081 7.4 <0.025 <0.5 <0.1 <50 NA 10.4 1.9 <0.5 55.7 2.4 <0.1 89 0.52 NO BC-2008 BC2008-RAW West and upgradient of the ash basin. Not within the direction of groundwater flow from the ash basin and O6/12/2018 <0.5 12.8 18.9 <0.1 <5 <0.08 6.4 <0.025 <0.5 <0.1 <50 NA 8.4 2.7 0.58 54.8 3.4 <0.1 110 0.58 NO PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 01/25/2018 <0.5 19.4 1.9 <0.1 5.8 <0.08 2.8 <0.025 <0.5 <0.1 <50 NA 8.5 3 <0.5 135 8.2 <0.1 121 <0.3 NO BC-2009 BC2009-RAW West and upgradient of the ash basin. Not within the direction of groundwater flow from the ash basin and 05/03/2018 <0.5 17.4 2.3 <0.1 5.6 <0.08 2.8 <0.025 <0.5 <0.1 <50 NA 3 2.8 <0.5 126 6.9 <0.1 116 <0.3 NO PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. BC25 10/13/2016 <0.5 0.39 0.61 <0.1 <25 <0.08 3.7 0.049 <0.5 <0.1 <50 NA 0.74 0.56 <0.5 24.8 3 <0.1 69 0.46 NO BC-1001 10/13/2016 <0.5 <0.1 16.5 0.13 <25 <0.08 1.1 1 1.3 <0.1 <50 NA 6.1 <0.5 <0.5 25.2 <2 <0.1 39 0.68 NO BC-2011 Southwest and upgradient of the ash basin. Not within the direction of groundwater Flow from the ash basin BC-1006 08/11/2015 <0.5 <I <5 <0.2 <50 <0.08 3 NA <5 <1 <10 NA <5 <1 <1 25 2.8 <0.2 61 0.396 NO and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. O8/11/2015 <1 <0.5 0.46 <1 <5 <1 3.1 0.037 <0.5 <0.5 <50 NA 1.4 0.68 <0.5 23.3 3.5 <0.1 76 <1 NO BC2011-RAW 09/19/2017 <0.5 0.81 1.4 <0.1 29 <0.08 3.5 0.079 0.72 <0.1 <50 NA 3 1.3 0.97 60.9 4.2 <0.1 72 0.76 NO BC-2010 BC2010-RAW 01/25/2018 <0.5 2.4 33.2 0.17 <5 <0.08 1.7 <0.025 <0.5 0.11 3,010 NA 487 0.7 <0.5 73.9 9.6 <0.1 143 <0.3 NO West and upgradient of the ash basin. Not within the direction of groundwater flow from the ash basin and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 10/03/2017 <0.5 0.15 7.7 0.21 <25 <0.08 2.1 0.8 1.2 <0.1 <50 NA 1.5 <0.5 <0.5 28.1 <1 <0.1 73 0.95 NO BC-2012 BC2012-RAW Southwest of and upgradient of ash basin. Not within the direction of groundwater flow from the ash basin 05/03/2018 <0.5 0.11 9.5 0.32 <5 <0.08 3.9 0.66 0.98 <0.1 <50 NA 1.8 <0.5 <0.5 34.3 <1 <0.1 63 0.59 NO and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. BC-2013 BC2013-RAW O1/16/2018 <0.5 31.8 59.7 0.2 <5 <0.08 10.9 0.032 <0.5 <0.1 <50 NA 0.93 2.2 <0.5 81.4 3.2 <0.1 144 0.37 NO Southwest and upgradient of the ash basin. Not within the direction of groundwater Flow from the ash basin and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 11/14/2017 <0.5 <0.1 7 <0.1 <25 <0.08 1.5 <0.025 <0.5 <0.1 <50 NA 1.8 <0.5 <0.5 21.9 9.9 <0.1 95 <0.3 NO BC-2014 BC2014-RAW Southwest of and upgradient of ash basin. Not within the direction of groundwater flow from the ash basin 01/25/2018 <0.5 0.41 0.89 <0.1 <5 <0.08 1.6 <0.025 0.74 <0.1 74.1 NA 1.5 <0.5 23.9 9.5 <0.1 102 <0.3 No and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 05/15/2018 <0.5 0.49 0.75 <0.1 <5 <0.08 1.3 <0.025 <0.5 <0.1 57.2 NA 1.5 <0.5 22.4 8.9 <0.1 83 <0.3 No BC-2015 BC2015-RAW 07/28/2017 <0.5 15.1 5.9 <0.1 <25 <0.08 5.8 <0.025 <0.5 <0.1 <50 NA 0.9 3.2 <0.5 190 6.3 <0.1 141 <0.3 No Southwest and upgradient of the ash basin. Not within the direction of groundwater Flow from the ash basin and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. BC13 08/31/2017 <0.5 9.3 2.3 <0.1 64.2 <0.08 19.9 0.028 <0.5 <0.1 <50 NA 3.3 1.5 <0.5 <0.1 7.5 <0.1 179 3.3 No BC2016-RAW 01/25/2018 <0.5 5.7 2.6 <0.1 85.7 <0.08 25.7 0.033 <0.5 <0.1 <50 NA 5.3 1.7 0.54 <0.1 8.6 <0.1 197 4 No BC-2016 West and upgradient of the ash basin. Not within the direction of groundwater flow from the ash basin and BC2016-RAW 03/03/2018 <0.5 6 2.4 <0.1 86.8 <0.08 25.7 <0.025 <0.5 <0.1 <50 NA 3.7 1.7 0.5 <0.1 7.8 <0.1 200 9.1 No PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. BC2016-RAW 05/15/2018 2 4.9 2.9 <0.1 80.5 <0.08 26.4 0.027 0.64 <0.1 <50 NA 9.7 1.9 <0.5 <0.1 7.9 <0.1 223 4.3 No BC2017-RAW 11/21/2017 <0.5 <0.1 19 <0.1 <25 0.12 5.9 <0.025 3.6 <0.1 50.9 NA 4.4 <0.5 <0.5 41.7 3 <0.1 74 <0.3 NO BC-201] Southwest and upgradient of the ash basin. Not within the direction of groundwater Flow from the ash basin and PHR Landfill. Outride of the ash basin drainage system, separated by hydrologic divides. BC2017-RAW O5/30/2016 <0.5 <0.1 16.9 <0.1 <5 <0.08 5.4 <0.025 <0.5 <0.1 <50 NA 2.4 <0.5 <0.5 37.2 3.3 <0.1 79 <0.3 No BC-2019 BC2019-RAW 0]/16/201] <0.5 <0.1 10.6 <0.1 <25 <0.08 1.8 0.65 <0.5 0.13 2,140 NA 16 1.7 <0.5 48.9 8.1 <0.1 96 0.32 NO West and upgradient of the ash basin. Not within the direction of groundwater flow from the ash basin and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. Urryllim TABLE 6-9 WATER SUPPLY WELL ANALYTICAL RESULTS SUMMARY CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Chromium Total(VI) Analytical Parameter Antimony Arsenic Barium Beryllium Boron Cadmium Chloride Chromium Cobalt Iron Lithium Manganese Molybdenum Selenium Strontium Sulfate Thallium Dissolved Vanadium Solids Impacted by Coal Ash Comments Reporting Units ug/L ug/L ug/L ug/L ug/L ug/L mg/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L mg/L ug/L mg/L ug/L 15A NCAC 02L Standard 1* 10 700 4* 700 2 250 NE 10 1* 300 NE 50 NE 20 NE 250 0.2* Soo 0.3* 2017 Background Threshold Values (Bedrock Unit)' 1 1 6 0.2 50 0.8 3 0.3 5 0.8 228 NE 10 4 0.5 100 10 0.1 133 1 2019 Background Threshold Values (Bedrock Unit)' 1 2 11 0.2 50 0.08 3 0.4 11 0.8 341 30 64 6 0.5 99 IS 0.1 181 2 2019Background Data Set Range (Bedrock Unit)2 0.1 - 1.4 0.1- 1.5 3.0 -11 0.01 - 0.2 33 -50 0.03 - 0.1 2.3 - 3.2 0.03 - 0.3 0.5 - 34.7 0.03 - 0.8 27 - 228 3.9-30 3.9 - 87.1 0.5 - 3.7 0.4 - 0.5 32.6 - 100 2.5 - 22.5 0.1- 0.1 52 - 250 0.2 - 2.3 Sy.Terra Sample ID Sample Collection Date Analytical Results Map ID BC4 Well A 01/24/2018 <0.5 0.17 5.6 <0.1 <5 <0.08 2.5 0.11 <0.5 <0.1 <50 NA <0.5 3.4 <0.5 43.7 4.3 <0.1 99 2.2 NO BC4 Well A 03/08/2018 <0.5 <0.1 9.1 <0.1 <5 <0.08 1.8 0.12 <0.5 <0.1 <50 NA <0.5 2.1 <0.5 41.3 2.6 <0.1 81 2.4 No 6C-2020 West and upgradient of the ash basin. Not within the direction of groundwater flow from the ash basin and 02/18/2015 6.9 1 NA 2.98 43 5 112 2 <0.5 <2 <0.5 <50 <0.15 <5 <2 <3 <25 <2 <2 <0.5 NO PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 02/18/2015 <1 <1 7 <1 <50 <1 1.5 NA <5 <1 18 NA <5 2.78 <1 41 3.9 <0.2 91 2.22 No BC2020-RAW 8/26/2015 <0.5 <0.5 3.6 <0.2 <5 <0.08 1.6 0.085 <0.5 <0.5 <50 NA NA 4.1 <0.5 44.8 4.8 <0.1 102 2.4 NO BC9 03/05/2015 <1 2.2 <5 <1 <50 <1 5.7 NA <5 <1 374 NA 37 <1 <1 72 9.3 <0.2 120 <0.3 No BC-2021 North and upgradient of the ash basin. Not within the direction of groundwater flaw from the ash basin and BC9 08/11/2015 <0.5 1.8 0.74 <0.2 <5 <0.08 6.3 <0.03 <0.5 <0.5 322 NA 19.5 <0.5 <0.5 73.2 9.8 <0.1 119 <1 NO PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. BC2021-RAW O6/27/2017 <0.5 1.8 0.72 0.11 <25 <0.08 5.7 <0.025 <0.5 0.1 321 NA 34.7 <0.5 <0.5 67.6 9.7 <0.1 124 <0.3 NO BC6 10/16/2017 <0.5 0.2 4.1 0.25 <25 0.12 9.7 <0.025 1.6 0.11 576 NA 30.8 <0.5 <0.5 63.9 6.6 <0.1 106 <0.3 NO Northeast and upgradient of the ash basin. Not within the direction of groundwater Flow from the ash basin BC-2022 BC2022-RAW O6/27/2018 <0.5 0.16 3.9 0.24 <10 <0.08 12.8 <0.025 c0.5 <0.1 762 NA 35.3 <0.5 <0.5 65.2 9.1 <0.1 109 <0.3 NO and PHR Landfill. Outride of the ash basin drainage system, separated by hydrologic divides. BC2022-RAW 03/04/2015 <I <1 <5 <1 <50 <1 12 NA <5 <1 354 NA 43 <I <1 65 10 <0.2 110 <0.3 NO O1/16/2018 <0.5 1 0.5 <0.1 :5 <0.08 2.3 <0.025 <0.5 <0.1 <50 NA 9.2 0.87 <0.5 98 9.4 <0.1 123 <0.3 NO BC-2025 BC2025-RAW North and upgradient of the ash basin. Not within the direction of groundwater flow from the ash basin and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 06/06/2018 <0.5 1 0.46 <0.1 6 <0.08 2.1 <0.025 <0.5 <0.1 <50 NA 9.1 0.91 <0.5 93.4 9.4 <0.1 135 <0.3 NO BC-2026 BC2026-RAW 07/18/2017 <0.5 3.5 <0.1 <0.1 c25 <0.08 1.2 0.2 <0.5 0.21 217 NA 17.5 1 <0.5 45.9 2 <0.1 105 1.6 NO West and upgradient of the ash basin. Not within the direction of groundwater flow from the ash basin and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. BC15 09/19/2017 1.9 0.88 0.19 0.19 <25 <0.08 5.2 0.62 3.9 1.5 NA 32.5 <0.5 <0.5 61 1.1 <0.1 53 1.1 NO BC2027 Northeast and upgradient of the ash basin. Not within the direction of groundwater Flow from the ash basin BC2027-RAW O5/30/2018 <0.5 0.42 c0.1 <0.1 <5 <0.08 5.8 0.24 0.64 0.22 <50 NA 6.9 <0.5 <0.5 60.6 1 <0.1 81 <0.3 NO and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 02/01/2018 <0.5 <0.1 22.3 0.13 <5 <0.08 5 0.048 <0.5 <0.1 103 NA 2.7 <0.5 <0.5 36.6 <1 <0.1 66 <0.3 NO BC-2031 BC2031-RAW Southwest and upgradient of the ash basin. Not within the direction of groundwater flow from the ash basin O6/12/2018 <0.5 <0.1 23.8 0.12 <5 <0.08 5 0.031 <0.5 <0.1 194 NA 2.9 <0.5 <0.5 39.7 <1 <0.1 60 <0.3 No and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. BC2034-RAW 02/01/2018 <0.5 0.62 <0.1 <0.1 <5 <0.08 3.9 0.062 <0.5 <0.1 <50 NA 1.3 0.94 <0.5 53.4 2.2 <0.1 74 0.52 NO BC-2034 Southwest and upgradient of the ash basin. Not within the direction of groundwater flaw from the ash basin BC2034-RAW 04/25/2018 <0.5 0.48 <0.1 <0.1 <5 <0.08 3.7 0.06 <0.5 <0.1 <50 NA 0.69 0.93 <0.5 54.9 2.5 <0.1 96 0.38 No and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. BC-2036 BC2036-RAW 09/19/2017 <0.5 <0.1 0.13 0.13 <25 <0.08 1.2 0.97 1.3 <0.1 <50 NA 3.4 <0.5 <0.5 24.4 <I <0.1 27 0.48 No Southwest and upgradient of the ash basin. Not within the direction of groundwater Flow from the ash basin and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. BC-2037 BC2037-RAW 03/06/2018 <0.5 <0.1 <0.1 <0.1 9.1 <0.08 3.9 1.1 1.5 <0.1 <50 NA 1 1.5 <0.5 59.7 3 <0.1 97 NO Northeast and upgradient of the ash basin. Not within the direction of groundwater Flow from the ash basin and PHR Landfill. Outride of the ash basin drainage system, separated by hydrologic divides. BC-2040 BC2040-RAW 05/18/2018 <0.5 0.84 29.3 0.12 <5 <0.08 1.9 0.79 <0.1 <50 NA 0.7 <0.5 <0.5 21.7 <1 <0.1 67 0.85 NO Southwest antl upgratlient of the ash basin. Not within the direction of groundwater Flow from the ash basin and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. BC-1 BC1 10/07/2015 <0.5 1.3 2.4 <0.2 <5 <0.08 7 0.093 1.4 <0.5 261 NA 173 <0.5 <0.5 165 12.2 <0.1 95 <1 NO Northeast and upgradient of the ash basin. Not within the direction of groundwater Flow from the ash basin and PHR Landfill. Outride of the ash basin drainage system, separated by hydrologic divides. 04/09/2015 <1 <1 7 <1 <50 <1 3.4 NA <5 <1 <10 NA <5 <1 <1 51 2.5 <0.2 80 0.451 NO 08/25/2015 <0.5 0.77 6.1 <0.2 <5 <0.08 3.2 0.06 <0.5 <0.5 <50 NA NA 1.1 <0.5 51.9 3 <0.1 64 <1 NO BC-8 BC8 Southwest and upgradient of the ash basin. Not within the direction of groundwater Flow from the ash basin and PHR Landfill. Outride of the ash basin drainage system, separated by hydrologic divides. 09/15/2015 <0.5 0.77 6.6 <0.2 <5 <0.08 3.5 0.06 0.91 <0.5 <50 NA 1.4 1 <0.5 53.8 3.1 <0.1 71 <1 NO 09/15/2015 <1 <1 7 <1 <50 <1 3.5 NA <5 <1 <10 NA <5 <1 <1 53 2.3 <0.2 75 0.489 NO BC-10 BC10 09/15/2015 <0.5 <0.5 18.6 <0.2 <5 <0.08 3 0.057 1.6 <0.5 56.8 NA 4 <0.5 <0.5 33.6 <2 <0.1 42 <1 No Southwest and upgradient of the ash basin. Not within the direction of groundwater flaw from the ash basin and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 08/10/2015 <0.5 10.8 3 <0.2 <5 <0.08 2.2 <0.3 <0.5 <0.5 <50 NA 3.6 20.2 <0.5 94.2 8.1 <0.1 136 <1 NO BC-20 BC20 West and upgradient of the ash basin. Not within the direction of groundwater flow from the ash basin and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 08/10/2015 <1 10.6 <5 <I <50 <1 2.1 NA <5 <3 28 NA <5 19.4 <1 98 8 <0.2 150 <0.3 NO BC-21 BC21 02/23/2016 <1 <1 11 <1 <50 <1 4 NA <5 <1 11 NA <5 <1 <1 19 1 <0.2 71 0.365 NO West and upgradient of the ash basin. Not within the direction of groundwater flow from the ash basin and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 08/12/2015 <0.5 <0.5 5.8 <0.2 <5 <0.08 1.6 2.1 2.5 <0.5 <50 NA <0.5 1.1 <0.5 25.2 3.2 <0.1 74 1.7 NO BC-23-1 BC23-1 Northeast and upgradient of the ash basin. Not within the direction of groundwater Flow from the ash basin 08/12/2015 <1 <1 6 <1 <50 <1 1.4 NA <5 <1 11 NA <5 1.21 <1 27 1 <0.2 52 1.69 NO and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 08/12/2015 <0.5 1.6 8.3 <0.2 <5 <0.08 18.6 1.9 2.3 <0.5 <50 NA 0.62 0.76 <0.5 87.7 3.5 <0.1 166 1.3 NO BC-23-2 BC23-2 Northeast and upgradient of the ash basin. Not within the direction of groundwater Flow from the ash basin 08/12/2015 <1 1.7 9 <1 <50 <1 17 NA <5 <1 14 NA <5 <1 <1 99 1.5 <0.2 150 1.33 NO and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 08/12/2015 <0.5 0.69 1 <0.2 <5 <0.08 14.1 <0.03 <0.5 <0.5 <50 NA 148 <0.5 <0.5 122 16.8 <0.1 223 <1 NO BC-23-3 BC23-3 Northeast and upgradient of the ash basin. Not within the direction of groundwater Flow from the ash basin 08/12/2015 <1 <1 <5 <1 <50 <1 13 NA <5 <1 14 NA 159 <1 <3 133 16 <0.2 210 <0.3 No and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 08/12/2015 <0.5 1.5 1.2 0.22 <5 <0.08 8.3 <0.03 <0.5 <0.5 155 NA 144 1.4 <0.5 92.7 20.2 <0.1 169 <3 NO BC-23-4 BC 3-4 Northeast and upgradient of ash basin. Not within the direction of groundwater Flaw from the ash basin and 08/12/2015 <1 1.6 <5 <1 <50 <1 7.8 NA <5 <1 164 NA 150 1.59 <3 103 19 <0.2 150 <0.3 No PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. O1/12/2011 <0.5 <0.5 7.2 0.3 <5 <0.08 14.6 <0.03 <0.5 4.3 <50 NA 23.8 <0.5 <0.5 102 17.4 <0.1 122 <1 No BC-23-5 BC23-5 Northeast and upgradient of the ash basin. Not within the direction of groundwater Flow from the ash basin 08/12/2015 <1 <1 7 <1 <50 <1 13 NA <5 4.06 <10 NA 26 <1 <1 110 11 1 <0.2 1 120 1 <0.3 NO and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. TABLE 6-9 WATER SUPPLY WELL ANALYTICAL RESULTS SUMMARY CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Chromium Total(VI) Analytical Parameter Antimony Arsenic Barium Beryllium Boron Cadmium Chloride Chromium Cobalt Iron Lithium Manganese Molybdenum Selenium Strontium Sulfate Thallium Dissolved Vanadium Solids Impacted by Coal Ash Comments Reporting Units ug/L ug/L ug/L ug/L ug/L ug/L mg/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L mg/L ug/L mg/L ug/L 15A NCAC 02L Standard 1* 10 700 4* 700 2 250 NE 10 1* 300 NE 50 NE 20 NE 250 0.2* Soo 0.3* 2017 Background Threshold Values (Bedrock Unit)' 1 1 6 0.2 50 0.8 3 0.3 5 0.8 228 NE 10 4 0.5 100 10 0.1 133 1 2019 Background Threshold Values (Bedrock Unit)' 1 2 11 0.2 50 0.08 3 0.4 11 0.8 341 30 64 6 0.5 99 IS 0.1 181 2 2019Background Data Set Range (Bedrock Unit)2 0.1 - 1.4 0.1 - 1.5 3.0 -11 0.01 - 0.2 33 -50 0.03 - 0.1 2.3 - 3.2 0.03 - 0.3 0.5 - 34.7 0.03 - 0.8 1 27 - 228 3.9-30 3.9 - 87.1 0.5 - 3.7 0.4 - 0.5 32.6 - 100 2.5 - 22.5 0.1- 0.1 52 - 250 0.2 - 2.3 SynTerra Sample ID Sample Collection Date Analytical Results Map ID BC-28 BC28 10/07/2015 <[ 3.03 <5 <I <50 <3 1.5 NA <5 <1 17 NA <5 3.49 <1 175 19 <0.2 120 <0.3 NO West and upgradient of the ash basin. Not within the direction of groundwater flow from the ash basin and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. BC-29 BC29 10/07/2015 <1 <1 12 <1 <50 <1 3.2 NA <5 <1 17 NA <5 <1 <1 23 1.3 <0.2 78 0.557 No West and upgradient of the ash basin. Not within the direction of groundwater flow from the ash basin and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 10/07/2015 <0.5 Los 2.2 <0.2 <5 <0.08 7.5 <0.03 <0.5 <0.5 <50 NA 0.7 10.5 1.8 64.6 8.7 <0.1 152 <1 NO BC-30 BC30 West and upgradient of the ash basin. Not within the direction of groundwater flow from the ash basin and 10/07/2015 <1 114 <5 <1 <50 <1 6.9 NA <5 <1 <10 NA <5 11.7 2.22 76 8.7 <0.2 160 0.468 NO PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 10/07/2015 <0.5 22.5 3.1 <0.2 <5 <0.08 4.1 <0.03 <0.5 <0.5 <50 NA 23.8 6.8 <0.5 3.2 <0.1 127 <I NO BC-32 BC32 West and upgradient of the ash basin. Not within the direction of groundwater flow from the ash basin and 10/07/2015 <1 23.7 <5 <1 <50 <1 3.6 NA <5 <1 13 NA 29 7.21 <1 3.4 <0.2 140 <0.3 NO PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 11/03/2015 <0.5 1.9 7.7 <0.2 <5 <0.08 2.8 <0.03 19.3 <0.5 269 NA 67.6 1.9 <0.5 85.2 9.1 <0.1 148 <3 NO BC-33 BC33 West and upgradient of the ash basin. Not within the direction of groundwater flow from the ash basin and 11/03/2015 <1 1.97 17 <1 <50 <1 2.5 NA 21 <1 262 NA 79 1.46 <1 94 11 <0.2 130 <0.3 NO PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 12/29/2015 <0.5 40.3 <0.2 <0.2 <5 <0.08 8.3 <0.03 0.52 <0.5 <50 NA 0.8 4.5 <0.5 94.4 6.1 <0.1 156 <3 NO BC34 BC34 Soutw and upgradient of the ash basin. Not within the of groundwater flow from the ash basin 12/29/2015 <1 42.9 <1 <1 <50 <1 8.1 NA <5 <1 13 NA <5 4.89 <1 110 6.2 <0.2 180 0.748 NO an system, and PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. 12/29/2015 <0.5 15.7 3.9 <0.2 <5 <0.08 7.2 JAB 1.6 <0.5 365 NA 253 2,1 <0.5 44.1 14.2 <0.1 143 <3 NO BC-35 BC35 West and upgradient of the ash basin. Not within the direction of groundwater flow from the ash basin and 12/29/2015 <1 16.7 <5 <1 <50 <1 7.1 NA <5 <1 44] NA 332 3.15 <1 52 15 <0.2 160 OA89 No PHR Landfill. Outside of the ash basin drainage system, separated by hydrologic divides. Notes: - Background threshold values were calculated using data from background groundwater samples collected June 2015 to April 2111 2 - Updated background threshold values were calculated using data from background groundwater samples collected October 2010 to December 2018 and sumbmitted to NCDEQ June 2019 Background threshold values have been rounded to similar levels of precision as 15A North Carolina Administrative Code (NCAC) 02L Standard or Interim Maximum Allowable Concentration (IMAC). Bold text - greatest comparative value 0 - Bold highlighted concentration indicates exceedance of the 15A NCAC 02L .0202 Standard or the IMAC. (Effective date for 15A NCAC 02L .0202 Standard and IMAC is April 1, 2013) 0 - Bold highlighted concentration indicates exceedance BN from April 2017 or December 2018, whichever is greater. EM - Highlighted concentration indicates value is either within range of background threshold values for constituents where there is no regulatory standard/background threshold values are greater than regulatory standard, or within range of background threshold value and the regulatory standard Bold text - Constituent concentration exceeds applicable comparison criteria. * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April 1, 2013 - Concentration not detected at or above the adjusted reporting limit. COI - Constituent of Interest NA - not available NE - not established NM - Not measured mg/L - Milligrams Per Liter pg/L - Micrograms Per Liter S.U. - standard units Prepared by: DAA Checked by: JHC TABLE 6-10 NPDES PERMIT LIMITS AND ANTICIPATED GROUNDWATER REMEDIATION PARAMETER LEVELS CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC NPDES Outfalls Internal Outfall 006A Outfall 006 IAP System Mean Groundwater Mean Concentration by Flow Concentration Zone' Effluent Limitations and Monitoring Requirements o 0 3 N O O 3 N O O V �Ol >.C1 4-1i 3 �� +S+ i 3 �� LL 0 �N LL O ON Parameter o y M •x p x C s y y iQ � iQ pM � Flow2 2.0 MGD NS NS NS 13 GPM NA NA NA Oil and Grease 15.0 mg/L 20.0 mg/L 15.0 mg/L 20.0 mg/L NA NA NA NA TSS 30.0 mg/L 50.0 mg/L 30.0 mg/L 50.0 mg/L 5.0 mg/L 6 mg/L 5 mg/L 4 mg/L Total Copper 211.3 pg/L 231.4 pg/L 1.0 mg/L 1.0 mg/L 0.001 mg/L 0.002 mg/L 0.001 mg/L 0.0009 mg/L Total Lead 78.9 pg/L 1668 pg/L 16.9 pg/L 367.7 pg/L 0.8 pg/L 0.3 pg/L 0.2 pg/L 0.1 pg/L Total Selenium 134 pg/L 1237 pg/L NS NS 1 pg/L 5 pg/L 1 pg/L 0.7 pg/L Total Molybdenum 4289 pg/L 4289 pg/L NS NS 3 pg/L 1 pg/L 2 pg/L 8 pg/L Total Aluminum 174.2 mg/L 174.2 mg/L NS NS 0.1 mg/L 0.7 mg/L 0.2 mg/L 0.2 mg/L Ammonia 1.0 mg/L 5.0 mg/L 1.0 mg/L 5.0 mg/L NA NA NA NA Total Iron4 1.0 mg/L 1.0 mg/L 1.0 mg/L 1.0 mg/L 0.2 mg/L 0.3 mg/L 0.2 mg/L 0.1 mg/L Chronic Toxicity5 See Note 5 See Note 5 NA NA NA NA Turbidity6 See Note 6 See Note 6 NA NA NA NA pH Between 6.0 and 9.0 S.U. Between 6.0 and 9.0 S.U. 5.3 S.U. 5.3 S.U. 6.3 S.U. 8.9 S.U. Notes: 1 - Downqradient groundwater monitoring wells in the area of groundwater remediation; Q1 2018 throuqh Q2 2019 data. z - The flow limit for Internal Outfall 006A is only applicable to interstitial water. 3 - Ammonia limit and monitoring only applicable in the event of the emergency release of anhydrous ammonia. 4 - Limits apply only when chemical metal cleaning wastewaters are being discharged. 5 - Whole effluent toxicity shall be monitored by chronic toxicity (Ceriodaphnia) Pass/Fail at 3.7% for Outfall 006A and 17.4% for Outfall 006. 6 - The discharge from this facility shall not cause turbidity in the receiving stream to exceed 50 NTU. GPM - gallons per minute IAP - Interim Action Plan MGD - million gallons per day NA - not analyzed NS - not specified mg/L - milligrams per liter TSS - total suspended solids pg/L - micrograms per liter S.U. - standard units Prepared by: ALA Checked by: CDE Page 1 of 1 TABLE 6-11 FEATURE IRRIGATION SYSTEM SETBACK CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Feature Irrigation System Setback (feet) Spray Drip Private residence 400 100 Place of assembly owned by permittee 200 15 Surface waters 100 100 Property line 150 50 Note: References: 15A NCAC 02T.056 Prepared by: VTV Checked by: CDE Page 1 of 1 TABLE 6-12 REMEDIAL TECHNOLOGY SCREENING SUMMARY CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC BELEWS CREEK, NC Summary of Remedial Technology Retain Technology for Further Consideration Screening Technology Yes/No Rationale COIs pose no unacceptable risk to human health or the environment under Monitored Natural Attenuation Yes conservative exposure scenarios and could be implemented in conjunction with source control measures. In -Situ Technologies Low Permeability Barriers No Installation to depths greater than 50 feet would be technically challenging and costly. Groundwater Infiltration and Flushing Yes Possible application to enhance capture of mobile COIs (e.g., boron). The area, depth and heterogeneity of geological conditions requiring Encapsulation No groundwater remediation are greater in size and complexity for uniform implementation of this technology. The area, depth and heterogeneity of geological conditions requiring Permeable Reactive Barrier No groundwater remediation are too large for feasible trenching. Injection of reagents through boreholes is possible; however, technology is not well established for boron. Groundwater Extraction Technologies Vertical Extraction Wells Yes Applicable for groundwater extraction of mobile COIs. This technology will be considered for corrective action of seep(s) north of the ash basin dam. Although, applicable for groundwater extraction of mobile COIs, vertical Horizontal/Angular Extraction Wells No extraction wells are just as effective in achieving hydraulic control and are cost effective than horizontal wells. This technology is not capable of achieving depths necessary to remediate Extraction Trenches Yes groundwater, however this technology will be considered for corrective action of seep(s) north of the ash basin dam. Hydraulic Fracturing No Not warranted based on the limited concern about COIs in bedrock. This technology is not capable of achieving extraction rates necessary to achieve groundwater remediation at depths greater than 50 feet within Phytoremediation Yes reasonable timeframes, however this technology will be considered for corrective action of low flowing seep(s) north of the ash basin dam and in remote locations of the Site. Groundwater Treatment Technologies pH Adjustment Yes Retained for remedial alternatives that include clean water infiltration or extraction. Precipitation Yes Retained for remedial alternatives that include groundwater clean water infiltration or extraction. No feasible or economical method to dispose of the regeneration effluent and Ion Exchange No groundwater influent streams might have geochemical characteristics that interfere with other treatment technology. Pretreatment and a high volume of reject effluent that requires additional Membrane Filtration No treatment prior to disposal make this technology costly and high maintenance. Other treatment options to remove soluble metals from extracted groundwater are better suited for the Site. Dis osal of Extracted Groundwater NPDES Permitted Discharge Yes Existing permitted discharges for wastewater are already in place. POTW No There is extensive distance between the WWTS and the Site. Non -Discharge Permit/Infiltration Gallery No Treatment prior to application could result in a complicated systems with significant operation and maintenance efforts. Non -Discharge Permit/Land Application No Treatment prior to application could result in a complicated systems with significant operation and maintenance efforts Beneficial Reuse Potential application, but only as a system improvement and supplemental Fire Protection No source of water. To be determined at a later date, and based on actual extraction rates of operational system. Potential application, but only as a system improvement and supplemental Non -Contact Cooling Water No source of water. To be determined at a later date, and based on actual extraction rates of operational system. Dust Suppression and Truck Wash No Limited use, and effort is not justified to substituent extracted groundwater for currently established procedures. Prepared by: ALA Checked by: CDE Page 1 of 1 TABLE 6-13 ALTERNATIVE 3 GROUNDWATER EXTRACTION AND CLEAN WATER INFILTRATION SUMMARY CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Groundwater Extraction Well System Vertical Wells Number of Wells Flow Zone Total Depth ft b s 4 Shallow <30 3 Shallow 30-59 19 Deep/Bedrock 60-89 87 Bedrock 90-119 Total Well Count: 113 System flow and operation assumptions: Flow rate: 0.8 gpm per well. Total system extraction flow rate of approximately 90 gpm. Extraction wells operate to maintain water level near bottom of the well. The groundwater extraction well system also includes 10 already existing extraction wells, as part of the interim action system. Post -decanting, the 10 interim action extraction wells are predicted to remove a total of about 2.5 gpm. Clean Water Infiltration Well System Vertical Wells Number of Wells Flow Zone Total Depth ft b s 2 Shallow 30-59 22 TRZ/Bedrock 60-89 15 Bedrock 90-119 0 Bedrock 120-149 1 Bedrock 150-179 7 Bedrock 180+ Total Well Count: 47 System flow and operation assumptions: Flow rate: 1.2 gpm per well. Total system infiltration flow rate of approximately 55 gpm.The groundwater infiltration rate is based on predictive flow and transport modeling, which assumes a 25 percent well efficiency. Clean water infiltration wells operate with pressure head set to 10 feet above the ground surface. Horizontal Well Number of Wells Flow Zone Total Depth ft b s 1 (900 foot long) Shallow 60 System flow and operation assumptions: Flow rate: Total infiltration flow rate of 110 gpm.The groundwater infiltration rate is based on predictive flow and transport modeling, which assumes a 25 percent well efficiency. Clean water infiltration wells operate with pressure head set to 10 feet above the ground surface. Notes: ft bgs - feet below qround surface gpm - gallons per minute Prepared by: ALA Checked by: CDE Page 1 of 1 TABLE 6-14 ENVIRONMENTAL SUSTAINABILITY COMPARISONS FOR REMEDIATION ALTERNATIVES CORRECTIVE ACTION PLAN UPDATE BELEW'S CREEK STEAM STATION DUKE ENERGY CAROLINAS LLC, BELEW'S CREEK, NC Remedial Alternative Remedial Alternative 1 — Monitored Natural Attenuation Remedial Alternative 2 — Groundwater Extraction and Treatment Remedial Alternative 3 — Groundwater Extraction combined with Clean Water Infiltration and Treatement Emissions Units CO2 Emissions metric ton 5.36E+01 4.88E+04 1.65E+04 Onsite NO, Emissions metric ton 6.79E-02 1.45E+00 3.30E+01 Onsite SOx Emissions metric ton 6.93E-03 1.49E-01 3.37E+00 Onsite PMIo Emissions metric ton 6.11E-03 1.31E-01 2.97E+00 Total NOx Emissions metric ton 1.00E-01 1.77E+02 7.55E+01 Total SOx Emissions metric ton 3.67E-02 1.63E+02 3.81E+01 Total PMIo Emissions metric ton 1.07E-02 1.92E+01 1.58E+01 Total Energy Used MMBTU 1.11E+04 2.84E+06 6.26E+06 Total Emissions metric ton 5.38E+01 4.92E+04 1.66E+04 Notes: CO2 - Airborne emissions of carbon dioxide MMBTU - Million British Thermal Units NOX - Airborne emissions of nitrogen oxides (combination of nitrogen monoxide and nitrogen dioxide) SOX - Airborne emissions of sulfur oxides (combination of sulfur monoxide, sulfur dioxide, sulfur trioxide, and others) PMIo - Airborne emissions of particulate matter that is 10 micrometers or less in diameter Prepared by: GTC Checked by: CBC Page 1of1 TABLE 6-15 MODELED CLEAN WATER INFILTRATION WELL DETAILS CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Well ID Fasting (NAD 88) Northing (NAD 88) Approximate Ground Surface Elevation (feet) Pressure at Well Head (ft of Head Above Ground Surface) Well Depth (ft BGS) Targeted Flow Zones Total Simulated Flow (gpm) Vertical Injection Wells IW-1 1681274.70 929063.70 727 10 160 Saprolite/Transition Zone/Bedrock 1.2 IW-2 1681230.20 929033.40 714 10 148 Saprolite/Transition Zone/Bedrock 1.2 IW-3 1681179.70 928997.00 717 10 148 Saprolite/Transition Zone/Bedrock 1.2 IW-4 1681121.10 928956.60 726 10 156 Saprolite/Transition Zone/Bedrock 1.2 IW-5 1681068.60 928918.30 717 10 145 Saprolite/Transition Zone/Bedrock 1.2 IW-6 1681022.10 928890.00 715 10 144 Saprolite/Transition Zone/Bedrock 1.2 IW-7 1680963.50 928851.60 725 10 153 Saprolite/Transition Zone/Bedrock 1.2 IW-8 1680927.20 928815.20 736 10 162 Saprolite/Transition Zone/Bedrock 1.2 IW-9 1681420.93 928813.43 753 10 171 Saprolite/Transition Zone/Bedrock 1.2 IW-10 1681409.13 928745.43 761 10 176 Saprolite/Transition Zone/Bedrock 1.2 IW-11 1681394.33 928659.73 763 10 174 Saprolite/Transition Zone/Bedrock 1.2 IW-12 1681379.53 928571.13 761 10 172 Saprolite/Transition Zone/Bedrock 1.2 IW-13 1681376.63 928479.53 755 10 164 Saprolite/Transition Zone/Bedrock 1.2 IW-14 1681364.83 928408.63 757 10 166 Saprolite/Transition Zone/Bedrock 1.2 IW-15 1681471.13 928881.33 748 10 172 Saprolite/Transition Zone/Bedrock 1.2 IW-16 1681547.93 928899.03 753 10 178 Saprolite/Transition Zone/Bedrock 1.2 IW-17 1681624.83 928899.03 752 10 172 Saprolite/Transition Zone/Bedrock 1.2 IW-18 1681710.43 928896.13 754 10 172 Saprolite/Transition Zone/Bedrock 1.2 IW-19 1681787.23 928881.33 758 10 170 Saprolite/Transition Zone/Bedrock 1.2 IW-20 1681217.80 928484.70 763 10 176 Saprolite/Transition Zone/Bedrock 1.2 IW-21 1681312.20 928701.50 753 10 168 Saprolite/Transition Zone/Bedrock 1.2 IW-22 1681323.40 928683.80 753 10 168 Saprolite/Transition Zone/Bedrock 1.2 IW-23 1681337.40 928717.90 750 10 166 Saprolite/Transition Zone/Bedrock 1.2 IW-24 1681296.60 928669.20 743 10 159 Saprolite/Transition Zone/Bedrock 1.2 IW-25 1681282.10 928630.10 745 10 159 Saprolite/Transition Zone/Bedrock 1.2 IW-26 1681254.00 928617.00 745 10 159 Saprolite/Transition Zone/Bedrock 1.2 IW-27 1681266.30 928595.70 745 10 159 Saprolite/Transition Zone/Bedrock 1.2 IW-28 1681294.50 928694.00 743 10 159 Saprolite/Transition Zone/Bedrock 1.2 IW-29 1681305.50 928735.90 750 10 166 Saprolite/Transition Zone/Bedrock 1.2 IW-30 1681332.30 928737.90 750 10 166 Saprolite/Transition Zone/Bedrock 1.2 IW-31 1681347.10 928624.70 755 10 168 Saprolite/Transition Zone/Bedrock 1.2 IW-32 1681333.50 928537.00 750 10 161 Saprolite/Transition Zone/Bedrock 1.2 IW-33 1681308.60 928595.90 754 10 166 Saprolite/Transition Zone/Bedrock 1.2 IW-34 1682913.20 929443.20 635 10 126 Saprolite/Transition Zone/Bedrock 1.2 IW-35 1681319.48 928632.14 755 10 59 Saprolite/Transition Zone/Bedrock 1.2 IW-36 1681044.90 928145.50 761 10 71 Saprolite 1.2 IW-37 1680961.30 927954.30 744 10 59 Saprolite 1.2 IW-38 1682874.47 929473.17 649 10 43 Saprolite/Transition Zone 1.2 IW-39 1682753.44 929435.93 704 10 84 Saprolite/Transition Zone 1.2 IW-40 1682602.16 929391.71 740 10 108 Saprolite/Transition Zone 1.2 IW-41 1681347.30 928895.70 729 10 223 Saprolite/Transition Zone/Bedrock 1.2 IW-42 1681302.20 928843.10 737 10 229 Saprolite/Transition Zone/Bedrock 1.2 IW-43 1681262.10 928798.00 740 10 232 Saprolite/Transition Zone/Bedrock 1.2 IW-44 1681222.10 928752.90 734 10 225 Saprolite/Transition Zone/Bedrock 1.2 IW-45 1681169.40 928707.80 742 10 232 Saprolite/Transition Zone/Bedrock 1.2 IW-46 1681124.30 928647.70 755 10 244 Saprolite/Transition Zone/Bedrock 1.2 IW-47 1680979.30 928664.80 751 10 242 Saprolite/Transition Zone/Bedrock 1.2 Horizontal Injection Wells HZ-1 NA NA 595 1 10 1 60 Saprolite/Transition Zone/Bedrock 110 Notes: All depths are approximated and may change depending on site conditions. Flowrates are approximate and may change depending on site conditions. DTW - depth to water ft - feet ft BGS - feet below ground surface gpm - gallons per minute Prepared by: GTC Checked by: YG Page 1 of 1 TABLE 6-16 MODELED GROUNDWATER EXTRACTION WELL DETAILS CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Well ID Easting Northing Approximate Ground Surface Elevation (feet) Operational DTW Maintained In Well (ft BGS) Well Depth (ft BGS) Targeted Flow Zones Total Simulated Flow (gpm) Vertical Extraction Wells EX-1 1681288.20 928942.50 722 129 149 Saprolite/Transition Zone/Bedrock 0.8 EX-2 1681219.00 928898.70 728 132 152 Saprolite/Transition Zone/Bedrock 0.8 EX-3 1681175.30 928855.00 725 129 149 Saprolite/Transition Zone/Bedrock 0.8 EX-4 1681115.30 928808.90 731 133 153 Saprolite/Transition Zone/Bedrock 0.8 EX-5 1681064.60 928762.80 742 143 163 Saprolite/Transition Zone/Bedrock 0.8 EX-6 1681392.71 928860.30 740 140 160 Saprolite/Transition Zone/Bedrock 0.8 EX-7 1681365.20 928815.70 749 147 167 Saprolite/Transition Zone/Bedrock 0.8 EX-8 1681334.50 928768.00 750 146 166 Saprolite/Transition Zone/Bedrock 0.8 EX-9 1681319.20 928723.80 750 146 166 Saprolite/Transition Zone/Bedrock 0.8 EX-10 1681305.60 928684.60 753 148 168 Saprolite/Transition Zone/Bedrock 0.8 EX-11 1681274.90 928611.40 745 139 159 Saprolite/Transition Zone/Bedrock 0.8 EX-12 1681244.30 928548.40 755 148 168 Saprolite/Transition Zone/Bedrock 0.8 EX-13 1681081.30 928592.80 762 158 178 Saprolite/Transition Zone/Bedrock 0.8 EX-14 1681324.50 928696.70 753 148 168 Saprolite/Transition Zone/Bedrock 0.8 EX-15 1681358.90 928672.60 761 154 174 Saprolite/Transition Zone/Bedrock 0.8 EX-16 1681339.80 928587.80 754 146 166 Saprolite/Transition Zone/Bedrock 0.8 EX-17 1681387.50 928624.90 763 154 174 Saprolite/Transition Zone/Bedrock 0.8 EX-18 1681375.70 928526.10 757 146 166 Saprolite/Transition Zone/Bedrock 0.8 EX-19 1681286.40 928649.60 745 139 159 Saprolite/Transition Zone/Bedrock 0.8 EX-20 1681234.30 928629.70 740 136 156 Saprolite/Transition Zone/Bedrock 0.8 EX-21 1681269.70 928705.60 743 139 159 Saprolite/Transition Zone/Bedrock 0.8 EX-22 1681262.60 928470.20 756 149 169 Saprolite/Transition Zone/Bedrock 0.8 EX-23 1681371.80 928444.20 757 146 166 Saprolite/Transition Zone/Bedrock 0.8 EX-24 1681322.90 928655.20 755 148 168 Saprolite/Transition Zone/Bedrock 0.8 EX-25 1681282.00 928561.90 745 139 159 Saprolite/Transition Zone/Bedrock 0.8 EX-26 1682318.20 929284.60 755 168 188 Saprolite/Transition Zone/Bedrock 0.8 EX-27 1681482.22 928678.80 770 125 145 Saprolite/Transition Zone/Bedrock 0.8 EX-28 1681481.12 928700.52 770 125 145 Saprolite/Transition Zone/Bedrock 0.8 EX-29 1681482.20 928722.49 765 123 143 Saprolite/Transition Zone/Bedrock 0.8 EX-30 1681474.86 928550.68 766 116 136 Saprolite/Transition Zone/Bedrock 0.8 EX-31 1681478.54 928595.60 768 119 139 Saprolite/Transition Zone/Bedrock 0.8 EX-32 1681478.54 928630.94 771 123 143 Saprolite/Transition Zone/Bedrock 0.8 EX-33 1681474.49 928537.43 766 116 136 Saprolite/Transition Zone/Bedrock 0.8 EX-34 1681477.43 928584.18 768 119 139 Saprolite/Transition Zone/Bedrock 0.8 EX-35 1681478.54 928623.21 771 123 143 Saprolite/Transition Zone/Bedrock 0.8 EX-36 1681481.12 928667.39 770 125 145 Saprolite/Transition Zone/Bedrock 0.8 EX-37 1681480.75 928713.78 770 125 145 Saprolite/Transition Zone/Bedrock 0.8 EX-38 1681481.51 928750.91 765 123 143 Saprolite/Transition Zone/Bedrock 0.8 EX-39 1681481.51 928790.91 758 120 140 Saprolite/Transition Zone/Bedrock 0.8 EX-40 1681525.32 928803.55 762 123 143 Saprolite/Transition Zone/Bedrock 0.8 EX-41 1681571.72 928801.45 764 124 144 Saprolite/Transition Zone/Bedrock 0.8 EX-42 1681611.56 928797.98 764 124 144 Saprolite/Transition Zone/Bedrock 0.8 EX-43 1681648.46 928794.95 767 125 145 Saprolite/Transition Zone/Bedrock 0.8 EX-44 1681682.52 928794.22 771 127 147 Saprolite/Transition Zone/Bedrock 0.8 EX-45 1681724.62 928792.12 774 129 149 Saprolite/Transition Zone/Bedrock 0.8 EX-46 1681775.22 928787.82 777 131 151 Saprolite/Transition Zone/Bedrock 0.8 EX-47 1681602.90 928798.57 764 124 144 Saprolite/Transition Zone/Bedrock 0.8 EX-48 1681582.10 928800.65 764 124 144 Saprolite/Transition Zone/Bedrock 0.8 EX-49 1681473.02 928524.17 766 116 136 Saprolite/Transition Zone/Bedrock 0.8 EX-50 1681475.96 928573.51 768 119 139 Saprolite/Transition Zone/Bedrock 0.8 EX-51 1681478.17 928614.37 771 123 143 Saprolite/Transition Zone/Bedrock 0.8 EX-52 1681472.65 928512.76 766 116 136 Saprolite/Transition Zone/Bedrock 0.8 EX-53 1681475.59 928560.99 766 116 136 Saprolite/Transition Zone/Bedrock 0.8 EX-54 1681478.17 928604.80 768 119 139 Saprolite/Transition Zone/Bedrock 0.8 EX-55 1681480.38 928648.61 771 123 143 Saprolite/Transition Zone/Bedrock 0.8 EX-56 1681481.48 928689.48 770 125 145 Saprolite/Transition Zone/Bedrock 0.8 EX-57 1681481.91 928733.61 765 123 143 Saprolite/Transition Zone/Bedrock 0.8 EX-58 1681482.91 928771.41 758 120 140 Saprolite/Transition Zone/Bedrock 0.8 EX-59 1681549.02 928799.75 762 123 143 Saprolite/Transition Zone/Bedrock 0.8 EX-60 1681593.72 928798.75 764 124 144 Saprolite/Transition Zone/Bedrock 0.8 EX-61 1681632.36 928797.28 767 125 145 Sap rolite/Transition Zone/Bedrock 0.8 EX-62 1681667.32 928794.02 771 127 147 Saprolite/Transition Zone/Bedrock 0.8 Page 1 of 2 TABLE 6-16 MODELED GROUNDWATER EXTRACTION WELL DETAILS CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Well ID Easting Northing Approximate Ground Surface Elevation (feet) Operational DTW Maintained In Well (ft BGS) Well Depth (ft BGS) Targeted Flow Zones Total Simulated Flow (gpm) Vertical Extraction Wells EX-63 1681704.12 928792.02 771 127 147 Saprolite/Transition Zone/Bedrock 0.8 EX-64 1681750.82 928789.02 774 129 149 Saprolite/Transition Zone/Bedrock 0.8 EX-65 1681640.23 928796.83 767 125 145 Saprolite/Transition Zone/Bedrock 0.8 EX-66 1681502.33 928802.75 758 120 140 Saprolite/Transition Zone/Bedrock 0.8 EX-67 1681662.04 928794.19 767 125 145 Saprolite/Transition Zone/Bedrock 0.8 EX-68 1681673.38 928793.83 771 127 147 Saprolite/Transition Zone/Bedrock 0.8 EX-69 1681678.52 928793.66 771 127 147 Saprolite/Transition Zone/Bedrock 0.8 EX-70 1681688.27 928792.41 771 127 147 Saprolite/Transition Zone/Bedrock 0.8 EX-71 1681693.76 928792.59 771 127 147 Saprolite/Transition Zone/Bedrock 0.8 EX-72 1681698.90 928791.88 771 127 147 Saprolite/Transition Zone/Bedrock 0.8 EX-73 1681708.82 928791.18 771 127 147 Saprolite/Transition Zone/Bedrock 0.8 EX-74 1681714.85 928791.00 771 127 147 Saprolite/Transition Zone/Bedrock 0.8 EX-75 1681719.63 928791.00 774 129 149 Saprolite/Transition Zone/Bedrock 0.8 EX-76 1681730.44 928790.11 774 129 149 Saprolite/Transition Zone/Bedrock 0.8 EX-77 1681735.40 928790.11 774 129 149 Saprolite/Transition Zone/Bedrock 0.8 EX-78 1681739.65 928790.11 774 129 149 Saprolite/Transition Zone/Bedrock 0.8 EX-79 1681745.68 928788.87 774 129 149 Saprolite/Transition Zone/Bedrock 0.8 EX-80 1681754.89 928788.87 774 129 149 Saprolite/Transition Zone/Bedrock 0.8 EX-81 1681759.68 928787.99 774 129 149 Saprolite/Transition Zone/Bedrock 0.8 EX-82 1681763.93 928787.81 774 129 149 Saprolite/Transition Zone/Bedrock 0.8 EX-83 1681767.65 928787.81 774 129 149 Saprolite/Transition Zone/Bedrock 0.8 EX-84 1681771.90 928787.63 777 131 151 Saprolite/Transition Zone/Bedrock 0.8 EX-85 1681779.35 928786.92 777 131 151 Saprolite/Transition Zone/Bedrock 0.8 EX-86 1681783.78 928786.57 777 131 151 Saprolite/Transition Zone/Bedrock 0.8 EX-87 1681787.14 928786.21 777 131 151 Saprolite/Transition Zone/Bedrock 0.8 EX-88 1681481.48 928657.45 771 123 143 Saprolite/Transition Zone/Bedrock 0.8 EX-89 1 1681622.63 928798.26 767 125 145 Saprolite/Transition Zone/Bedrock 0.8 EX-90 1681479.27 928638.30 771 123 143 Saprolite/Transition Zone/Bedrock 0.8 EX-91 1681560.75 928800.36 762 123 143 Saprolite/Transition Zone/Bedrock 0.8 EX-92 1681481.70 928741.62 765 123 143 Saprolite/Transition Zone/Bedrock 0.8 EX-93 1681482.33 928761.83 765 123 143 Saprolite/Transition Zone/Bedrock 0.8 EX-94 1681537.71 928800.05 762 123 143 Saprolite/Transition Zone/Bedrock 0.8 EX-95 1681482.33 928782.11 758 120 140 Saprolite/Transition Zone/Bedrock 0.8 EX-96 1681515.48 928803.17 762 123 143 Saprolite/Transition Zone/Bedrock 0.8 EX-97 1681748.09 928612.99 774 124 144 Saprolite/Transition Zone/Bedrock 0.8 EX-98 1681738.09 928602.19 774 124 144 Saprolite/Transition Zone/Bedrock 0.8 EX-99 1681731.75 928591.70 774 124 144 Sap rolite/Transition Zone/Bedrock 0.8 EX-100 1681742.60 928607.00 774 124 144 Saprolite/Transition Zone/Bedrock 0.8 EX-101 1681734.30 928596.20 774 124 144 Saprolite/Transition Zone/Bedrock 0.8 EX-102 1681728.50 928585.40 774 124 144 Saprolite/Transition Zone/Bedrock 0.8 EX-103 1682698.22 929347.70 722 86 106 Saprolite/Transition Zone/Bedrock 0.8 EX-104 1682578.24 929276.28 751 99 119 Saprolite/Transition Zone/Bedrock 0.8 EX-105 1682826.77 929390.55 650 26 46 Saprolite/Transition Zone/Bedrock 0.8 EX-106 1681930.81 928557.94 742 20 40 Saprolite 0.8 EX-107 1681911.35 928500.94 747 25 45 Saprolite 0.8 EX-108 1681770.94 928282.67 748 32 52 Saprolite 0.8 EX-109 1681839.06 928366.08 750 32 52 Saprolite 0.8 EX-110 1681877.98 928445.33 745 25 45 Saprolite 0.8 EX-111 1681634.40 929008.60 745 36 56 Saprolite 0.8 EX-112 1681171.64 928093.38 765 54 74 Saprolite 0.8 EX-113 1681164.012 928005.4152 758 49 69 Saprolite 0.8 Notes: All depths are approximated and may change depending on site conditions. Flowrates are approximate and may change depending on site conditions. DTW - depth to water ft - feet ft BGS - feet below ground surface gpm - gallons per minute NA - Not applicable Prepared by: GTC Checked by: YG Page 2 of 2 u TABLE 6-17 EFFECTIVENESS MONITORING PLAN ELEMENTS CORRECTIVE ACTION PLAN UPDATE BELEWS CREEK STEAM STATION DUKE ENERGY CAROLINAS, LLC, BELEWS CREEK, NC Effectiveness Monitoring Plan (EMP) Post -Closure Monitoring Plan (PCMP) Implemented 30 days after CAP Approval Implemented after completion of ash basin closure activities EMP Groundwater Well Monitoring Network (flow paths downgradient, locations downgraident and sidegradient, and background of ash basin) Downgradient Downgradient Downgradient Downgradient and 1 Background Flow Path 1 Flow Path 2 Flow Path 3 Sidegradient CCR-2D GWA-20BR CCR-6S EXOB-1 BG-IS CCR-2S GWA-20SA CCR-6D EXOB-2 BG-1D GWA-IOSA GWA-20D CCR-6BR* GWA-16S BG-2S GWA-10D GWA-11S MW-200BR GWA-16DA BG-2D GWA-19D GWA-11D MW-200D GWA-16BR BG-2BRA GWA-19SA GWA-21S MW-200S GWA-17S BG-3S GWA-19BR GWA-21D GWA-24BR GWA-17D BG-3D GWA-31S GWA-27S GWA-24D GWA-18SA MW-202S GWA-31D GWA-27D GWA-24S GWA-18D MW-202D GWA-27BR GWA-1S MW-202BR CCR-13S GWA-ID CCR-13D GWA-1BR CCR-13BR GWA-30S GWA-30D GWA-32S GWA-32D M W -204S M W -204D PCMP Groundwater Well Monitoring Network (background, downgradient of ash basin) A PCMP will be implemented at the Site in accordance with G.S. Section 130A-309.214(a)(4)k.2 after completion of ash basin closure activities. EMP Groundwater Quality',O PCMP Groundwater Quality (Semi -Annual Sampling Frequency) (Sampling frequency to be determined) Alkalinity Borons Iron Nitrate + Nitrite Sulfate Aluminum Calcium Lithium Potassium Thallium Parameters and sampling frequency to be included in the PCMP in Arsenic Chlorides Magnesium Total Dissolved Sodium accordance with G.S. Section 130A-309.214(a)() 4 k.2 when Solids' submitted. Beryllium Cobalt Manganese Strontium Total Organic Carbon Bicarbonate Ferrous Iron CMP and PCMP Groundwater Field Parameters Water Level Specific Conductivity Temperature PH Oxidation Reduction Potential Dissolved Oxygen Annual Effectiveness Monitoring Evaluation and Reporting 1) Summary of annual groundwater monitoring results 2) Evaluate statistical concentration trends 2) Comparison of observed concentrations to model predictions 3) Evaluation of compliance with applicable Standards 4) Evaluation of system performance and effectiveness 4) Recommend plan adjustments, if applicable, to optimize the remedial action 5-Year Performance Review Reporting 1) Update background analysis 2) Confirm Risk Assessment assumptions remain valid 3) Re-evaluate effectiveness of technology 4) Verify modeling results, update model if needed 5) Modify corrective action approach, as needed, to achieve compliance goal established 30 days after CAP approval, the EMP will be implemented at the Site and will continue until there is a total of three years of data confirming COIs are below applicable Standards at or beyond the compliance boundary, at which time a request for termination of active remediation will be filed with NCDEQ. If applicable standards are not met, the EMP will continue and transition to post -closure monitoring if necessary. Annual Evaluation and Reporting: 1) Summary of annual groundwater monitoring results 2) Evaluate statistical concentration trends 2) Comparison of observed concentrations to model predictions 3) Evaluation 02L compliance 4) Recommend plan adjustments, if applicable At a freguencv no greater than 5 years: 1) Update background analysis 2) Confirm Risk Assessment assumptions remain valid 3) Verify model results, update if needed After ash basin closure and following ash basin closure certification, a PCMP will be implemented at the Site for a minimum of 30 years in accordance with G.S. Section 130A-309.214(4)(k)(2). Reguest for termination: If groundwater monitoring results are below applicable Standards at the compliance boundary for three years, Duke Energy will request completion of corrective action in accordance with G.S. Section 130A 309.214(a)(3)b. If groundwater monitoring results are above applicable Standards, the PCMP will continue. Prepared by: ALA Checked by: 1 Approved background groundwater monitoring locations ' Geochemirally non -reactive constituents fi.e.. conservative corrective action COW that best depict the area extent of the plume: monitors plume stability and phvsical afte.u.ti.n 3 The number of monitoring wells and parameters may be adiusted based on additional data and the effects of corrective action. ° Groundwater standards may be modified over time in accordance with 02L .0106(k) * Proposed new well for effectiveness monitoring Italicized parameters - parameters for water quality to evaluate monitoring data quality