NCG060039_MONITORING INFO_20190417 (FIX)

STORMWATER DIVISION CODING SHEET
NCG PERMITS
PERMIT NO.
DOC TYPE ❑HISTORICAL FILE
MONITORING REPORTS
DOC DATE ❑ �"1 0
YYYYMMDD

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
RE1 9, N�REPORT
COt./ d L.� L.Jy
APR fft 20}TAMPLES COLLECTED DURING CALENDAR YEAR: 2019
(This monitoring report is due at the Division no later than 30 days from the date
CENTRAL FILEtbe facility receives the sampling results from the laboratory.)
0k,"IR SECT10,",! COUNTY Johnston
PHONE NO. [phone]
Lab #NCIWW cert #012
PLEASE SIGN ON THE REVERSE 4
Outfall
No.
Date
Sample Collected,
mo/dd/ yr
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
m /L
pH,
Standard units
Total Suspended Solids,
m IL
Benchmark
-
120
30
6.0 — 9.0
100
1
03-26-19
ND < .0
ND <5.0
6.9
3.1
Note: if you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?_ yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample Collected,
molddlvr
00556
00530
00400
Oil and Grease,
m IL
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
RECEIVED
APR 15 2oi9
CCNTruL FILES
C)I"fR SPEC--10i1?
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH; you.must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 03-26-19 (first event sampled) Mail Original and one copy to:
Total Event Precipitation (inches): 0.42 Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Date (list each additional event sampled this reporting period, and rainfall amount) Raleigh, NC 27699-1617
Total Event Precipitation (inches):
SWU-248-102107
Page] of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee)
q 6SAFt
(Date)
SWU-248-102107 '
Page 2 of 2

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2019
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert #012
PLEASE SIGN ON THE REVERSE 4
O u tfall
No.
Date
Sample Collected,
mo/dd/yr
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
m /L
pH,
Standard units
Total Suspended Solids,
m IL
Benchmark
-
120 .
30
6.0 — 9.0
100
2
03-26-19
12.2
ND <5.0
6.5
ND 2.5
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes X no
(if yes, complete Part 13)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample Collected,
molddlvr
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m IL
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
Note: If you repori a sampled va_ lue in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 03-26-19 (first event sampled)
Total Event Precipitation (inches): 0.42
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
SWU-248-102107
Pagel of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
(Signature of
4/S/Iq
(Date)
S W U-248-102107
Page 2 of 2

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2019
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NCIWW cert #012
PLEASE SIGN ON THE REVERSE 4
Outfall
No.
Date
Sample Collected,
mo/dd/ r
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
m /L
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
3
03-26-19
45.0
ND <5.0)
6.9
2.5
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample Collected,
mo/dd/vr
00556
00530
00400
Oil and Grease,
m IL
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
30 .
100
6.0 — 9.0
-
Note: if you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier I or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 03-26-19 (first event sampled)
Total Event Precipitation (inches): 0.42
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S WU-248-102107
Page 1 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
(Signature of Permi
(Date)
S WU-248-102107
Page 2 of 2

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Anal tical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2019
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NCIWW cert #012
PLEASE SIGN ON THE REVERSE 4
Outfall
No.
Date
Sample Collected,
mo/dd/ r
00340
00556
00400
00530
Chemical Oxygen Demand,
MWL
Oil and Grease,
m IL
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
4
03-26-19
13.6
ND <5.0
6.9
6.6
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier I or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?_ yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample Collected,
mo/dd/vr
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m /L
pH;
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 —9.0
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text..
STORM EVENT CHARACTERISTICS:
Date 03-26-19 (first event sampled)
Total Event Precipitation (inches): 0.42
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S WU-248-102107
Pagel of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee)
(Date)
S WU-248-102107
Page 2 of 2

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCGO60039
FACILITY NAME Grifols Thera eutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2019
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NCIWW cert #012
PLEASE SIGN ON THE REVERSE 4
Outfall
No.
Date
Sample Collected,
mo/dd/vr
00340
00556
00400
00530
Chemical Oxygen Demand,
m
Oil and Grease,
m IL
pH,
Standard units
Total Suspended Solids,
m
Benchmark
-
120
30
6.0 — 9.0
100
5
03-26-19
ND 10.0
ND <5.0
7.1
4.1
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?_ yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity onitoring Requirements
Outfall
No.
Date
Sample Collected,
mo/dd/yr
00556
00530
00400
Oil and Grease,
m IL
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier I or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 03-26-19 (first event sampled)
Total Event Precipitation (inches): 0.42
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S WU-248-102107
Page) of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. l am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
/�
(Signature of
4 / 5/�9
(Date)
SWU-248-102107
Page 2 of 2

Environmental
Qualify
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
For guidance onfilling our this form, please visit littps://deq,nc.gov/about/divisions/energy-mineral-land-resources/
npdes-stonnwater-gps
Permit No.: NICICTIO/ C9l //0��/ 0/ of01 or Certificate of Coverage No.: N_ICIGI0161 0/ Cal 3 I ?1
Facility Name: rr [,a r �` 7o IS � h e rQ pe Le ��SC 5
County: n 5 4-anJ Phone No. q q" 3Sy- S y 73
Inspector: Da ✓ l'd 6- 6 ra kO "l
Date of Inspection: 0.3 - 2 6 - 1 `%
Time of Inspection: 1010
Total Event Precipitation (inches)-
- LlZ
All permits require qualitative monitoring to be performed during a "measurable storm event."
A "measurable storm event' is a storm event that results in an actual discharge from the permitted site
outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm
interval does not apply if the permittee is able to document that a shorter interval is representative for
local stone events during the sampling period, and the permittee obtains approval from the local DEMLR
Regional Office.
By this signature, I certify that this report is accurate and complete to the best of my knowledge:
t
(Signature of Permittee or Designee)
1. Outfall Description:
Outfall No. I
Receivin Stream•
Structure (pipe, ditch, etc.):
g
4 t'; bu �a r
S� rea m
4U �-t-�C N eu S RW e r
Describe the industrial activities that o cur within the outfall drainage area:
N arwcice Lt- ,' C.a 1 Mc9,
Pagel of 2
S W U-242, Last modified 06101 /201 S

2. Color: Describe the color of the discharge usm basic colors red, brown, blue, etc,) and tint
(light, medium, dark) as descriptors: C lea r- W /'�A ct Med l' L/M b rpW ti 4/i J-�
3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak
chlorine odor, etc.): Np A) e-
4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear
and 5 is very cloudy:
0 2 3 4 5
5. Floating Solids: Choose the number which best describes the amount of floating solids in the
stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids:
1 2 3 4 5
b. Suspended Solids: Choose the number which best describes the amount of suspended solids in
the stormwater discharge, where 1 is no solids and 5 is extremely muddy:
2 3 4 5
7. Is there any foam in the stonmwater discharge? O Yes A No.
8. Is there an oil sheen in the stormwater discharge? OYes 0 No.
9. Is there evidence of erosion or deposition at the outfall? O Yes 40 No.
10. Other Obvious Indicators of Stormwater Pollution:%
List and describe ' " olye-
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be
indicative of pollutant exposure. These conditions warrant further investigation.
Page 2 of 2
SWU-242, Last modified 06/01/2018

Environmental
Quality
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Forguidance on filling out This form, please visit https://deq.nc.gov/about/divisions/energy-mineral-land-resources/
npdes-stormwater-gps
Permit No.: N_IC/(`l 0l.6 / 0 / a/ 0/0/ or Certificate of Coverage No.: N_/C/G/. Ul6 I010131 R I
Facility Name: -w"rOIS -FA er"a ec.l4j'c S
County: -i a k N.5 4-6 ^1 Phone No. S q 73
Inspector: 0ca v )'d 5. Cara {Ia wl
Date of Inspection: 03 - 2-6 - I
Time of Inspection: 07SS
Total Event Precipitation (inches):
O • 2
All permits require qualitative monitoring to be performed during a "measurable storm event."
A "measurable storm event" is a storm event that results in an actual discharge from the permitted site
outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm
interval does not apply if the permittee is able to document that a shorter interval is representative for
local storm events during the sampling period, and the pertittee obtains approval from the local DEMLR
Regional Office.
By this signature, I certify that this report is accurate and complete to the best of my knowledge:
I
(Signature of Perrmttee or Designee)
1. Outfall Description:
Outfall No. Z Structure (pipe, ditch, etc.): / i k A C,c tS 4% aNd
Receiving Stream: // �� ,� l "�
r� , 6 U �Q r �/ h / � e El se- /� i� ve r
i e the industrial activities that oc�cyyr�within the outfall drainage area:
r)a ��d C��� Al'Cca / =1
Page 1 of 2
SWU-242, Last modified 06101/2019

2. Color: Describe the color of the discharge usin = basic colors (Ted, brown, blue, etc.) and tint
(light, medium, dark) as descriptors: G l eur 4V"4h u Me6fluj'" brCJ4-UAl -4"iy�
3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak
chlorine odor, etc.): /LO Ill E
4. Clarity: Choose the number which best describes the clarity of the discharge, where I is clear
and 5 is very cloudy:
6) 2 3 4 5
5. Floating Solids: Choose the number which best describes the amount of floating solids in the
stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids:
V 2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended solids in
the stormwater dischargc, where 1 is no solids and 5 is extremely muddy:
01 2 3 4 5
7. Is there any foam in the stormwater discharge'? O Yes o No.
8. Is there an oil sheen in the stormwater discharge? OYes Q No.
9. Is there evidence of erosion or deposition at the outfall? O Yes ® No.
10. Other Obvious Indicators of Stormwater Pollution:
List and describe 11,,0/`vE
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be
indicative of pollutant exposure. These conditions warrant further investigation.
Page 2 of 2
SW U-242, Last modified 06/01/201 &

Environmental'
Quality
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
For guidance on filling out this fornr, please visit littps://deq,nc.gov/about/divisions/energy-mineral-land-resources/
n pdes-stone water-gps
Permit No.: N_lC/G/ OI (Ol 010/O/0/ or Certificate of Coverage No.: N/C/G/o /6 /O /O/3/91
Facility Name: Gr, -P)S -k'ra -eaY A`G S
County: \,�o � N S -oN Phone No. -119 3 S 9 - S q 7.3
Inspector: ✓ avl'G' S. 6,-a 'ZI
Date of Inspection: D-3 -
Time of Inspection: 1 QLA 0
Total Event Precipitation (inches):
y2-
All permits require qualitative monitoring to be performed during a "measurable storm event."
A "measurable storm event" is a storm event that results in an actual discharge from the pennitted site
outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm
interval does not apply if the permittee is able to document that a shorter interval is representative for
local stone events during the sampling period, and the perinittee obtains approval from the local DEMLR
Regional Office.
By this signature, I certify that this report is accurate and complete to the best of my knowledge:
(Signature of Permittee or Designee)
1. Outfall Description:
Outfall No. 3— Structure (pipe, ditch, etc.): ✓ ra i%ll i
Receiving Stream: `J
Describe the industrial activities that cur within the outfall drainage area:
Ala,-ma<ea-A'ra J ✓1iPa .
Page I of 2
5 W U-242, Last modificd 06101/201 R

2. Color: Describe the color of the discharge usin basic colors red, brown, blue, etc.) and ti t
(light, medium, dark) as descriptors: C feu,- W IR e, /fleet "../ 'i brow,,-1
3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak
chlorine odor, etc.): �Jo" 1 C.
4. Clarity: Choose the number which best describes the clarity of the discharge, where I is clear
and 5 is very cloudy:
1 © 3 4 5
5. Floating Solids: Choose the number which best describes the amount of floating solids in the
stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids:
Ql 2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended solids in
the stormwater discharge, where 1 is no solids and 5 is extremely muddy:
01 2 3 4 5
7. Is there any foam in the stormwater discharge'? 0 Yes B No.
8. Is there an oil sheen in the stormwater discharge? CYes 49 No.
9. Is there evidence of erosion or deposition at the outfall? O Yes 0 No.
10. Other Obvious Indicators of Stormwater Pollution:
List and describe / 1 d A)iS
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be
indicative of pollutant exposure. These conditions warrant further investigation.
Page 2 of 2
S W tJ-242, Last modified 06101 /201 S

Environmental
Quality
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
For guidance onfilling oul this form, please visit https://deq.nc.gov/about/divisions/energy-mineral-land-resources/
npdes-stoniiwater-gps
Permit No.: NICI� I016I U/0/ 0/0 or Certificate} of Coverage No.: N_ICIG1016 /01013/91
Facility Name: ` fir; �Ols ! /tLIra
►'7��u �-►GS
County: jo N,5 �^l Phone No. q19 --3.5q - SDI 7-3
Inspector: _2)a✓1',d s I-u l7oi�
Date of Inspection: ®3` 26
Time of Inspection: / 0
Total Event Precipitation (inches): 1 ` 2—
All permits require qualitative monitoring to be performed during a "measurable storm event."
A "measurable storm event" is a storm event that results in an actual discharge from the permitted site
outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm
interval does not apply if the pernittee is able to document that a shorter interval is representative for
local storm events during the sampling period, and the pennittee obtains approval from the local DEMLR
Regional Office.
By this signature, I certify that this report is accurate and complete to the best of my knowledge:
(Signature of Pennittee or Designee)
1. Outfall Description: Il
Outfall No. Structure (pipe, ditch, etc.): PiVe—
Receiving Strum: J 4
De ribe the industrial activities that occur the outfall drainage area:
�h�rr�lct
Page] of 2
SWU-242, Last modified 06/0112018

2. Color: Describe the color of the discharge usi} basic colors (red, brown, lue, etc.) a d tintj
(light, medium, dark) as descriptors: G l e-a v- Gel, Y� ✓l7e, �/ vIn brQW n!
3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak
chlorine odor, etc.): IV (9 N C'.
4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear
and 5 is very cloudy:
1 l) 3 4 5
5. Floating Solids: Choose the number which best describes the amount of floating solids in the
stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids:
6) 2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended solids in
the stormwater discharge, where 1 is no solids and 5 is extremely muddy:
@1 2 3 4 5
7. Is there any foam in the stormwater discharge? O Yes o No.
8. Is there an oil sheen in the stormwater discharge'? OYes o No.
9. Is there evidence of erosion or deposition at the outfall? O Yes ® No.
10. Other Obvious I dicators of Stormwater Pollution:
List and describe oNe
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be
indicative of pollutant exposure. 'These conditions warrant further investigation.
Page 2 of 2
SWU-242, Last modified 06/0112018

Environmental
Quailry
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
For guidance on filling out this form, please visit littps://deq.nc.gov/about/divisions/energy-mineral-land-resources/
npdes-stormwater-gps
Permit No.: N_/C/� /mod l6l01010l Ul or Certificate of Coverage No.: N/C/GI D/6l O/Oi,3/ 7/
Facility Nam--e::~~ ( r,40,S •
County: tJo 4iNS-/eN Phone No. `��`{ ~ 3S9—S4/ 7-3
Inspector: :1Da v1'J rrz AO v
Date of Inspection: 0-3- !!26 — /9
Time of Inspection: 6q,1S
Total Event Precipitation (inches): • `7 2—
All permits require qualitative monitoring to be performed during a "measurable storm event."
A "measurable storm event" is a storm event that results in an actual discharge from the permitted site
outfall. The previous measurable stone event must have been at least 72 hours prior. The 72-hour storm
interval does not apply if the permittee is able to document that a shorter interval is representative for
local stonn events during the sampling period, and the permittee obtains approval from the local DEMLR
onal Office.
By this signature, I certi fy that this report is accurate and complete to the best of 1ny knowledge:
(Signature of Pennittee or Designee)
I. Outfall Description:
Outfall No. S Structure (pipe, ditch, etc.):
Receiving Stream:
�r,hcr �a r
6U 5e
Describe the industrial activities that occur thin the outfall drainage area:
phaY,mo ccit-Lt'cd ( 10 �.
Page 1 of 2
SWU-242, Last modified 06/01/2018

2. Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and ti t
(light, medium, dark) as descriptors: C�e�rr w� a vyt %,'�, h/'p euA) -/./`n!7
3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak
chlorine odor, etc.): A10A)C
4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear
and 5 is very cloudy:
3 4 5
5. Floating Solids: Choose the number which best describes the amount of floating solids in the
stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids:
2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended solids in
the stormwater discharge, where 1 is no solids and 5 is extremely muddy:
0 2 3 4 5
7. is there any foam in the stonnwater discharge? O Yes ® No.
8. Is there an oil sheen in the stonnwater discharge? OYes ® No.
9. Is there evidence of erosion or deposition at the outfall? O Yes ® No.
to. Other Obvious Indicators of Stormwater Pollution:
List and describe A/0N(2-
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be
indicative of pollutant exposure. These conditions warrant further investigation.
Page 2 of 2
S W CJ-242, Last modif icd 06101 /201 S

/55ceA.nalyfical"
pecefa6s.[nm
I
April 02, 2019
Sam Vedder
Grifols Therapeutics, LLC
8368 US 70 West
Clayton, NC 27520
RE: Project: STORMWATER
Pace Project No.: 92422930
Pate Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Dear Sam Vedder:
Enclosed are the analytical results for sample(s) received by the laboratory on March 27, 2019, The
results relate only to the samples included in this report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
[phone]
Project Manager
Enclosures
cc: David Graham, Grifols Therapeutics, LLC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 1 of 16

1 4
acmnalytical
W" pacelabs.com
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
CERTIFICATIONS
Project: STORMWATER
Pace Project No.: 92422930
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
South Carolina Certification #: 99006001
Lou isia n a/NE LAP Certification # LA170028
FloridalNELAP Certification #: E87627
North Carolina Drinking Water Certification #: 37706
Kentucky UST Certification #: 84
North Carolina Field Services Certification #: 5342
VirginiaNELAP Certification #: 460221
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
Eden Certification IDs
205 East Meadow Road Suite A, Eden, NC 27288
North Carolina Drinking Water Certification #: 37738
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
North Carolina Wastewater Certification #: 633
VirginiaNELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 16

Pace Analytical
Services, LLC
aceAnalytical •
6701
Conference Drive
Raleigh, NC 27607
www.p&catabs.com
[phone]
SAMPLE ANALYTE COUNT
Project: STORMWATER
Pace Project No.: 92422930
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
92422930001 OUTFALL#1
SM2540D-2011
MWF
1
PASI-E
EPA1664B
JMS
1
PASI-C
SM 5220D-2011
GC
1
PASI-A
92422930002 #3 SOUTH PLANT PIPE
SM 2540D-2011
MWF
1
PASI-E
EPA 1664B
JMS
1
PASI-C
SM 5220D-2011
GC
1
PASI-A
92422930003 #4 SE POND
SM 254OD-2011
MWF
1
PASI-E
EPA 1664B
JMS
1
PASI-C
SM 5220D-2011
GC
1
PASI-A
92422930004 #5 CONSOLIDATED OUTFALL
SM 254OD-2011
MWF
1
PASI-E
EPA 16646
JMS
1
PASI-C
SM 5220D-2011
GC
1
PASI-A
92422930005 #2 BASIN #2
SM 2540D-2011
MWF
1
PASI-E
EPA 1664B
JMS
1
PASI-C
SM 5220D-2011
GC
1
PASI-A
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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ANALYTICAL RESULTS
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Project: STORMWATER
Pace Project No.: 92422930
Sample: OUTFALL #1 Lab ID: 92422930001 Collected: 03/26/19 10:10 Received: 03127/19 11:43 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids Analytical Method: SM 254OD-2011
Total Suspended Solids 3.1 mg/L 2.5 1 03/29/19 11:23
HEM, Oil and Grease Analytical Method: EPA 1664B
Oil and Grease ND mg/L 5.0 1 03/29/19 07:32
5220D COD Low Level Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
Chemical Oxygen Demand N❑ mg/L 10.0 1 03/28/19 15:04 03/29/19 23:55
REPORT OF LABORATORY ANALYSIS
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Date: 04/02/2019 08:10 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 16

aceAnalytical o
I www.paoslabs.crom
I
ANALYTICAL RESULTS
Project: STORMWATER
Pace Project No.: 92422930
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Sample: #3 SOUTH PLANT PIPE Lab ID: 92422930002 Collected: 03/26/19 10:40 Received: 03/27/19 11:43 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids Analytical Method: SM 254OD-2011
Total Suspended Solids 2.5 mg/L 2.5 1 03/29/19 11:24
HEM, Oil and Grease Analytical Method: EPA 1664B
Oil and Grease ND mg/L 5.0 1 03/29/19 07.33
5220D COD Low Level Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
Chemical Oxygen Demand 45.0 mg/L 10.0 1 03/28/19 15:04 03/29/19 23:55
Date: 04/02/2019 08:10 AM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 5 of 16

aceAnalytical e
www.pacelabs.cora
ANALYTICAL RESULTS
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Project: STORMWATER
Pace Project No.: 92422930
Sample: #4 SE POND Lab ID: 92422930003 Collected: 03/26/19 10:35 Received: 03/27/19 11:43 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Total Suspended Solids
HEM, Oil and Grease
Oil and Grease
5220D COD Low Level
Chemical Oxygen Demand
Date: 04/02/2019 08:10 AM
Analytical Method: SM 254OD-2011
6.6 mg1L 3.6 1 03/29/1911:24
Analytical Method: EPA 1664E
ND mg/L 5.0 1 03/29/19 07:33
Analytical Method: SM 52200-2011 Preparation Method: SM 5220D-2011
13.6 mg1L 10.0 1 03/28/19 15:04 03/29119 23:56
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in fuP,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 16

Pace Analytical Services, LLG
0
lacieAnalytical 6701 Conference Drive
Raleigh, NC 27607
www.pacelabstom [phone]
ANALYTICAL RESULTS
Project: STORMWATER
Pace Project No.: 92422930
Sample: #5 CONSOLIDATED
OUTFALL
Parameters
Lab ID: 92422930004 Collected: 03/26/19 09:45
Results Units Report Limit OF
Received: 03/27/19 11:43 Matrix: Water
Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 2540D-2011
Total Suspended Solids
4.1 mg/L 2.5 1
03/29/19 11:24
HEM, Oil and Grease
Analytical Method: EPA 16648
Oil and Grease
ND mg/L 5.0 1
03/29/19 07:35
5220D COD Low Level
Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
Chemical Oxygen Demand
ND mg/L 10.0 1
03/28/19 15:04 03/29/19 23:56
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/02/2019 08:10 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 16

Pace Analytical Services, LLC
aceAnalytical a 5701 Conference Drive
Raleigh, NC 27607
WWW.X 11 [phone]
ANALYTICAL RESULTS
Project: STORMWATER
Pace Project No.: 92422930
Sample: #2 BASIN #2 Lab ID: 92422930005 Collected: 03/26/19 09:55 Received: 03/27/19 11:43 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids Analytical Method: SM 254OD-2011
Total Suspended Solids ND mg/L 2.5 1 03/29/19 11:25
HEM, Oil and Grease Analytical Method: EPA 1664B
Oil and Grease ND mg/L 5.0 1 03/29/19 07:35
5220D COD Low Level Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
Chemical Oxygen Demand 12.2 mg/L 10.0 1 03/28/19 15:04 03/29/19 23:56
REPORT OF LABORATORY ANALYSIS
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Date: 04/02/2019 08:10 AM without the written consent of Pace Analytical Services, L.L.C. Page 8 of 16

aceAnalytrcals
wtrw.pnotis-tam
QUALITY CONTROL DATA
Project: STORMWATER
Pace Project No.: 92422930
OC Hatch: 466237 Analysis Method: SM 2540D-2011
QC Hatch Method: SM 254OD-2011 Analysis Description: 2540D Total Suspended Solids
Associated Lab Samples. 92422930001, 92422930002, 92422930003, 92422930004, 92422930005
METHOD BLANK: 2534308 Matrix: Water
Associated Lab Samples: 92422930001, 92422930002, 92422930003, 92422930004, 92422930005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Suspended Solids mg/L ND 2.5 03/29/19 11:23
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
LABORATORY CONTROL. SAMPLE: 2534309
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Suspended Solids mg/L 250 262 105 90-110
SAMPLE DUPLICATE: 2534310
92422905001 Dup
Parameter Units Result Result RPD Qualifiers
Total Suspended Solids mg/L ND ND
SAMPLE DUPLICATE: 2534311
92422955001 Dup
Parameter Units Result Result RPD Qualifiers
Total Suspended Solids mg1L <5.0 ND
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/02/2019 08:10 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 16

aceAnalytrcaI
www.pacelabs.t:om
QUALITY CONTROL DATA
Project: STORMWATER
Pace Project No.: 92422930
QC Batch: 466214 Analysis Method: EPA 1664B
QC Batch Method: EPA 1664B Analysis Description: 1664 HEM, Oil and Grease
Associated Lab Samples: 92422930001, 92422930002, 92422930003, 92422930004, 92422930005
METHOD BLANK: 2534260 Matrix: Water
Associated Lab Samples: 92422930001, 92422930002, 92422930003, 92422930004, 92422930005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mglL ND 4.8 03/29/19 06:57
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
LABORATORY CONTROL SAMPLE:
2534261
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits
Qualifiers
Oil and Grease
mg1L
38.5 36.7
96
78-114
MATRIX SPIKE SAMPLE:
2534262
R
_
92422923003 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
% Rec
Limits Qualifiers
Oil and Grease
mglL
ND 40
37.9
94 78-114
Results presented on this page are in the units indicated by the -Units" column except where an alternate unit Is presented to the right or the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04102/2019 08:10 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 16

aceAnalytrcal
wwwpmelabs.c m
QUALITY CONTROL DATA
Project: STORMWATER
Pace Project No.: 92422930
QC Batch: 466083 Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD, Low Level
Associated Lab Samples: 92422930001,92422930002,92422930003,92422930004,92422930005
METHOD BLANK: 2533729 Matrix: Water
Associated Lab Samples: 92422930001, 92422930002, 92422930003, 92422930004, 92422930005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chemical Oxygen Demand mg/L ND 10.0 03/29/19 23:49
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
LABORATORY CONTROL SAMPLE: 2533730
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Chemical Oxygen Demand mg1L 75 73.7 98 90-110
MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE: 2533731 2533732
MS MSD
92422287001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Conc, Result Result % Rec % Rec Limits RPD Qual
Chemical Oxygen Demand mg/L 11.5 75 75 97,3 96.3 114 113 90-110 1 M1
Results presented on this page are In the units Indicated Ey the "units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Dale: 04/02/2019 08:10 AM without the written consent of Pace Analyhcaf Services, LLC.
Page 11 of 16

e
aceAnalytrca!
www.pacefa6s.00m
QUALIFIERS
Project: STORMWATER
Pace Project No.: 92422930
DEFINITIONS
OF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
NO - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MOIL - Adjusted Method Detection Limit.
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
PQL - Practical Quantitalion Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-E Pace Analytical Services - Eden
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
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Date: 04/02/2019 08:10 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 16

aceAnalytical
www.pwelabs.com
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
6701 Conference drive
Raleigh, NC 27607
[phone]
Project:
Pace Project No.:
STORMWATER
92422930
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical
Method
Batch
92422930001
OUTFALL #1
SM 2540D-2011
466237
92422930002
#3 SOUTH PLANT PIPE
SM 25400-2011
466237
92422930003
#4 SE POND
SM 2540D-2011
466237
92422930004
#5 CONSOLIDATED OUTFALL
SM 2540D-2011
466237
92422930005
#2 BASIN #2
SM 2540D-2011
466237
92422930001
OUTFALL #1
EPA 1664B
466214
92422930002
#3 SOUTH PLANT PIPE
EPA 1664B
466214
92422930003
#4 SE POND
EPA 1664E
466214
92422930004
#5 CONSOLIDATED OUTFALL
EPA 1664B
466214
92422930005
#2 BASIN #2
EPA 1664E
466214
92422930001
OUTFALL #1
SM 5220D-2011
466083
SM
52200-2014
466423
92422930002
#3 SOUTH PLANT PIPE
SM 5220D-2011
466083
SM
5220D-2011
466423
92422930003
#4 SE POND
SM 52200-2011
466083
SM
52200-2011
466423
92422930004
#5 CONSOLIDATED OUTFALL
SM 5220D-2011
466083
SM
5220D-2011
466423
92422930005
#2 BASIN #2
SM 52201)-2011
466083
SM
5220D-2011
466423
Date: 04/02/2019 08:10 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 16

Laboratory receiving samples:
Asheville ❑ Eden❑
Courier:
0 Commercial
Greenwood hluntersvilie ❑ Raleigh❑ Mechanlcsvllle❑
Client Nitltie, . _..___...._.._._..._..--_-.. _._.............. Project Wa 9242293�
Fed Ex - .QUPS QUSPS
f ]Other: 1911241229130
Custody Seat Present? []Yes ONO Seats intact? Dyes ONO
Packing Material: ❑Bubble Wrap "P�8ubble Bags ❑None Q• Other
Thermometer:
Typo of ice: , [jVet QBlue
Xl Gun 16 Q
Cooler Temp ('C): —2 —7_ Correction Factor: Add(ubtra t C) // Q
Cooler Temp Corrected (°C)r 2 -
Dateflnititls Person Examining Contents
—z*--)�
Biological Tissue Frozen?
[]None DesQNo ❑N/A
Temp should be above freezing to VC
D2mples out of temp crtteda. Samples on Ice, cooling process
has tegun
USDA Regulated Sail (?N/A, water sample)
Old samples originate In a quararitine zone within the United States: CA, NY, or SC (check maps)? Did samples originate $cm a foreign source tintemat.onallY,
F- Yes nNo Ine dine Hawaii aid Pterto R!cal? F lYes Flao
Comments/Dlscrepanty:
Chain of Custgdy present?
7es
ONO
N/A
1.
5amplesArrivedwithinHold rime?
5Ler
I]No
❑N/A
2.
Short Hold Time Ana! sls (02 hr.)?
Yes
❑rrlA
3.
Rush Turn Around-nme Requested?
0ye,
3aS2
QNIA
4.
Sufficlent Volume?
ONO
ONIA
S.
Correc, Containers Used?
-Pace Containers Used?
DNZ
❑rro
[)No
❑H/A
N/A
G.
Containers Intact?
NO
N/A
?.
Dissolved amlysls: Sarnples Field Filtered?
Yes
orla
a.
Sample tahels Match CDC?
-includesDateMme/ID/Analysis Matdx:
a
❑No
❑N/A
9.
Headspace in V0A vials (>5-6rnm)?
❑Yes
QNo
/A
10.
Trip Blank Present?
Trip Dfank Custnd' S.Is Present?
❑Yes
__❑Yes
(-JNo
nrvo
(?k/A
Or/A _..
11.
—E9Rfht£fFESfSAMPtf f)rSCttMRTr fS 6315FiEtliI -
.._..-^.-_..,...-.,—_•--•--•--�-�--�-------,-"--�Lot lDofsplit containers:
CLIENT NOTIFICATION/RES01.1.1710N - -
Person contacted:
Project Manager SCURF Review:
DateMme:
Date: t7 I ,
Page 14 of 16
Project Managor SRF Review:
Dace:
' 11 -" -1
, 0,

'Check mark top half of box If pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions. VOA, Colifcirm, MC, oil and Grease, DROISOiS (water) 00(, LLHg
"Bottom half of box is to list number of bottle
pr.a,ect � wa ' 9242293®
PM: MWB Due Date: 04/05/19
CLIENT: 91-GrlfolEHS
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pH Adjustment Log for Preserved Samples
Sampio ID Type of preservative ptl upon receipt Elate preservation adjusted Time presarvatian Amount of Preservative lot Y
adjusted added
I1
E Page 15 of 16
Note; Whenever there is a discrepancy affacting North Carolina compliance samples, a copy of this form will he sent to cie North Carolina OEHNR Cerillcation Office (I,o.

CHAIN -OF -CUSTODY I Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Seddon C
RequW*d
CIkTd Info ... = on: Required Projoet information: htvoiw Irif.". om Page: 1 Of
Ckffab Therweik= Rap- Ta Sam VC-dd, Anemon:
8368 US 10 West COPY To: comwry Name:
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C 27520
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PRINT Nagim of SAMPLER:
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SIGNATURE at SAMPLER: DATE Sligned:
/-Y
CD

SEMI-ANNUAL STORMWATER DISCHARGE MONITORING REPORT
for North Carolina Division of Water Resources General Permit No. NCG060000
Date submitted
CERTIFICATE OF COVERAGE NO. NCG060 O 3 9 pr ���v�11lIPLE COLLECTION YEAR 2018
FACILITY NAME Grito:s Therapeutics C FACILITY ACTIVITIES INCLUDE (check all that apply):
COUNTY Johnston � p 1 241$ [] use/process meats ❑ use animal fats/byproducts
PERSON COLLECTING SAMPLES David S. Graham ISCHARGING TO SALTWATERS? ❑YES ■❑NO
LABORATORY Pace Analytical Lab Cert. #t Nr-NM 12 CEI T ''�- FIL��
C
K-T10�1 PLEASE REMEMBER TO SIGN ON THE REVERSE 4
Part A: Stormwater Benchmarks and Monitoring Results
Total event rainfall 2 2.72 or ❑ No discharge this period3
Outfall No.
Sample Collected,
mo/dd/yr
TSS,
mg/L
pH,
Standard units
COD,
mg/L
Oil and Grease,
mg/L
Fecal Coliform ,
Colonies per 100 ml
Enterococci ,
Colonies per 100 ml
Benchmark
-
100 or 50
Within 6.0 — 9.0
120
30
1000
500
1
11/13/18
8.1
6.8
38.6
ND
2
11/13/18
21.8
6.8
35.2
ND
3
11113118
9.1
7.0
36.3
ND
4
11113/18
35.3
6.9
20.7
ND
5
11/13/18
60.9
6.7
34.8
ND
1 Only applies to facilities that use/process meats.
ZThe total precipitation must be recorded using data from an on -site rain gauge.
3 For sampling periods with no discharge at any outfalls. You must still submit this discharge monitoring report with a checkmark here.
4See General Permit text, Table 3, identifying the especially sensitive receiving water classifications where the more protective benchmark applies.
Did this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? ❑ yes Ono
Part B: Vehicle Maintenance Area Monitoring Results: only for facilities averaging > 55 gal of new motor oil/month.
Outfall No.
Sample Collected,
mo/dd/yr
Oil and Grease,
mg/L
TSS,
mg/L
pH,
Standard units
New Motor Oil Usage,
Annual average gal/mo
Benchmark
-
30
100 or 50
6.0-9.0
-
Only applies to facilities that use/process meats.
ZThe total precipitation must be recorded using data from an on -site rain gauge.
3 For sampling periods with no discharge at any outfalls, you must still submit this discharge monitoring report with a checkmark here.
4See General Permit text, Table 3, identifying the especially sensitive receiving water classifications where the more protective benchmark applies
(if yes, complete Part B)
SWU-249 Last Revised: October 18, 2012
Page 1 of 2

*FOR PART A AND PART B MONITORING RESULTS:
• A BENCHMARK EXCEEDANCE TRIGGERS TIER 1 REQUIREMENTS. SEE PERMIT PART II SECTION B.
• 2 EXCEEDANCES IN A ROW FOR THE SAME PARAMETER AT THE SAME OUTFALL TRIGGER TIER 2 REQUIREMENTS. SEE PERMIT PART II SECTION B.
• TIER 3: HAS YOUR FACILITY HAD 4 OR MORE BENCHMARK EXCEEDENCES FOR THE SAME PARAMETER AT ANYONE OUTFALL? YES ❑ NO ❑
IF YES, HAVE YOU CONTACTED THE DWQ REGIONAL OFFICE? YES ❑ NO ❑
REGIONAL OFFICE CONTACT NAME:
Mail an original and one copy of this DMR, including all "No Discharge" reports, within 30 days of receipt of the lab results for at end of
monitoring period in the case of "No Discharge" reports) to:
Division of Water Resources
Attn: DWR Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
YOU MUST SIGN THIS CERTIFICATION FOR ANY INFORMATION REPORTED:
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the
person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is,
to the best of my knowle a nd belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false
information, including �sibility of fines and imprisonment for knowing violations."
(Signature of Perm
f// 2 1)7
(Date)
Additional copies of this form may be downloaded at: http://portal.ncdenr.org/web/wq/ws/su/npdessw#tab-4
S W U-249
Last Revised: October 18. 2012
Page 2 of 2

Environmental
Quality
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
For guidance on filling out this form, please visit https://deq.nc.gov/about/divisions/energy-mineral-land-resources/
npdes-stormwater-gps
Permit No.: N_IC_l 61. 0l /6� 16l 01.0101 or Certificate of Coverage No.: N_/C/G/ o f 6 /` 0 /0 /,3 /.1j l
Facility Name: (y r, fry /5 pet<e L
County: Jo 6N S -1-toA) Phone No. 919 - 35 9 - Sal 73
Inspector-, '2)14 v r"d S• G)-0 A 0 M
Date of Inspection: // - / 3 —/ 1,
Time of Inspection: Oq L-)
Total Event Precipitation (inches): 2 • 7 2
All permits require qualitative monitoring to be performed during a "measurable storm event."
A "measurable storm event" is a storm event that results in an actual discharge from the permitted site
outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm
interval does not apply if the permittee is able to document that a shorter interval is representative for
local storm events during the sampling period, and the permittee obtains approval from the local DEMLR
Regional Office.
By this signature, I c*j}(tl4iat this report is accurate and complete to the best of my knowledge:
(Signature of Penni�tee or Designee)
1. Outfall Description:
Outfall No. ! Structure (pipe, ditch, etc.): edr✓T
Receiving Streams: / 11 �,, II �t'
rr � AU r4 r �p Y � / v sq 5,
Describe the industrial activities that occur within the outfall drainage area:
PAdr1na Cea4-, co/ ATo.
Page 1 of 2
SWU-242, Lust modified 0&01l2018

2. Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tin
(light, medium, dark) as descriptors: G' lea-r a)AA I- edi'u Y� N 'ln
racuJ
3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak
chlorine odor, etc.): oNc
4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear
and 5 is very cloudy:
O 2 3 4 5
5. Floating Solids: Choose the number which best describes the amount of floating solids in the
stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids:
2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended solids in
the stormwater discharge, where I is no solids and 5 is extremely muddy:
(3 2 3 4 5
7. Is there any foam in the stormwater discharge? O Yes O No.
8. Is there an oil sheen in the stormwater discharge`? OYes 4D No.
9, is there evidence of erosion or deposition at the outfall? O Yes • No.
10. Other Obvious Indicators of Stormwater Pollution:
List and describe AloAJe—
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may he
indicative of pollutant exposure. These conditions warrant further investigation.
Page 2 of 2
S W U-242, Last modified 06/0112019

Environmental
Qualify
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Forguidance on filling out this form, please visit https:lldeq.nc.gov/about/divisions/energy-mineral-land-resources/
npd es -stone water-gps
Permit No.: N_ICIGI dl.61610101 U1 or Certificate of Coverage No.: N_IC_lG_10 /610 /O/ 3191
Facility Name: e , �& l5 e-na e l,'Gs L L G
County: _ .S.r D `1 N5 4aN Phone No. l 19 - -359 - 5; q 73
Inspector: / J1xy --5, G ro ti wi
Date of Inspection: —
Time of Inspection:
Total Event Precipitation (inches)
2, 72
All permits require qualitative monitoring to be performed during a "measurable storm event."
A "measurable storm event" is a storm event that results in an actual discharge from the permitted site
outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour stone
interval does not apply if the permittee is able to document that a shorter interval is representative for
local storm events during the sampling period, and the permittee obtains approval from the local DEMLR
Regional Office.
By this signature, Vc t� y that this report is accurate and complete to the best of my Knowledge:
(Signature of Permittee or Designee)
1. outfall Description: / 1
Outfall No. ',?- Structure (pipe, ditch, etc.): d4cA e u,'/, Nq to 6lid
Receiving Stream: . f I'
r r'6 ac -a r
e-u/-<l,Ver
industrial activities that occur w' h' the outfall drainage area:
rM a- 4f&-U�vUeej / A
Page I of 2
5WU-242, Last modified 06/01/2019

2. Color: Describe the color of the discharge using basic colors (red, brApwn, blue, a c.) and tint
(light, medium, dark) as descriptors: c lea+" 6VI M a M E e/0 pn 0 rO CO AJ 4rUl-
3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak
chlorine odor, etc.): O/ti/ f-
4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear
and 5 is very cloudy:
O 2 3 4 5
5. Floating Solids: Choose the number which best describes the amount of floating solids in the
stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids:
el 2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended solids in
the stormwater discharge, -where 1 is no solids and 5 is extremely muddy:
0 2 3 4 5
7. is there any foam in the stormwater discharge? O Yes O No.
8. Is there an oil sheen in the stormwater discharge? OYes © No.
9. Is there evidence of erosion or deposition at the outfall? O Yes • No.
10. Other Obvious Indicators of Stormwater Pollution:
List and describe
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be
indicative of pollutant exposure. These conditions warrant further investigation.
Page 2 of 2
S W U-242, Last modified 06/01 /2018

Environmental
Quality
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Forguidance on filling out this form, please visit https://deq.nc.gov/about/divisions/energy-mineral-land-resources/
npdes-stomiwater-gps
Permit No.: NICI(5I0I &/.rJl !U CY,CY or Certificate of Coverage No.: NIC_IG1.61
Facility Name: t
County: A AJ.$ �0ti1 Phone No. `� - ,5q - 5 y 7,3
Inspector: 2>gU1, '1 5- 6ra ha M
Date of Inspection: _ ! 1 — / 18
Time of Inspection: 0 Q 55
Total Event Precipitation (inches):
�2. 7Z-
All permits require qualitative monitoring to be performed during a "measurable storm event."
A "measurable storm event" is a storm event that results in an actual discharge from the permitted site
_1,
outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm
interval does not apply if the permittee is able to document that a shorter interval is representative for
local storm events during the sampling period, and the permittee obtains approval from the local DEMLR
Office.
By this signature, I e�rtl� oAt this report is accurate and complete to the best of my knowledge:
(Signature of Permittee or Designee)
1. Outfall Description: ��J/
Outfall No. _� __— Structure (pipe, ditch, etc.): Cerra /AJ !
Receiving Stream:
Descthe industrial activities t6t occur wAhm the outfall drainage area:
{�harinc, eecc�/gal 'WJ4.
Page I of 2
S W U-242, Last modified 06/01 /2018

2. Color: Describe the color of the discharge using basic colors (red, brown, lue, etc.) and tint
(light, medium, dark) as descriptors: I edr 4j)I I? Q d' m Pro wN ��"'j
3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak
chlorine odor, etc.): AlOAl e-
4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear
and 5 is very cloudy:
1 0 3 4 5
5. Floating Solids: Choose the number which best describes the amount of floating solids in the
stonnwater discharge, where 1 is no solids and 5 is the surface covered with floating solids:
`6) 2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended solids in
the stormwater discharge, where 1 is no solids and 5 is extremely muddy:
D1 2 3 4 5
7. Is there any foam in the stormwater discharge? O Yes er No.
S. Is there an oil sheen in the stormwater discharge? OYes 0 No.
9. Is there evidence of erosion or deposition at the outfall? O Yes • No.
10. Other Obvious Indicators of Stormwater Pollution:
List and describe A10A) ✓
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be
indicative of pollutant exposure. These conditions warrant further investigation.
Page 2 of 2
SWU-242, Last modified 06/01/2018

Environmental
Quality
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
For guidance on f lling out this forni, please visit https:Hdeq.nc.gov/about/divisions/energy-mineral-land-resources/
npdes-storniwater-gps
Permit No.: NIC_I(SIO/ 6 / 0/lil 0/ 0/ or Certificate of Coverage No.: N_ICIGI 616 /01.61,31 ?1
Facility Name:
County: \:J D A N S 10 A) Phone No.
Inspector:
)avid Jam• _bra k4
Date of Inspection:
Time of Inspection
11- 13 -19
V t q5
Total Event Precipitation (inches):
2 . 72.
All permits require qualitative monitoring to be performed during a "measurable storm event."
i
A "measurable storm event" is a storm event that results in an actual discharge from the permitted site
outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm
interval does not apply if the permittee is able to document that a shorter interval is representative for
local storin events during the sampling period, and the permittee obtains approval from the local DEMLR
Regional Office.
By this signature, I cer>jif f t46� this report is accurate and complete to the best of my knowledge:
(Signature of
Designee)
1. Outfall Description:
Outfall No. 41
R St
Structure (pipe, ditch, etc.): t'�' e Ton? 100AJJ
ecelvmg ream. -- /I
Describe t . Industrial activities that occur within the
karma c•eu./ M
Page I of 2
y eptl5e-
1 drainage area
SWU-242, Last modified 06/011201 S

2. Color: Describe the color of the discharge using bpc colors (r, brown, lue, etc.) and tint
(light, medium, dark) as descriptors: fir' W i A M e l '+J n,? / 6 w Aj -/ i Aj
3. Odor: Describeg) any distinct odors that the discharge may have (i.e., smells strongly of oil, weak
chlorine odor, etc.): IVON e-
4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear
and 5 is very cloudy:
1 20 3 4 5
5. Floating Solids: Choose the number which best describes the amount of floating solids in the
stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids:
2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended solids in
the stormwater discharge, where 1 is no solids and 5 is extremely muddy:
Sl 2 3 4 5
7. Is there any foam in the stormwater discharge? O Yes 4b No.
S. Is there an oil sheen in the stormwater discharge? OYes O No.
9. Is there evidence of erosion or deposition at the outfall? O Yes 4D No.
10. Other Obvious Indicators of Stormwater Pollution:
List and describe / LAle-
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be
indicative of pollutant exposure. These conditions warrant further investigation.
Page 2 of 2
SWU-242, Last modified 06101/2018

Environmental
Quali ry
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
For guidance on filling out this form, please visit https://deq.nc.gov/about/divisions/energy-mineral-land-resources/
npdes-stormwater-gps
Permit No.: NIC161016/0/p a lj' or Certificate of Coverage No.: NICIG1016 /01.0131 ?l
Facility Name: _ C 1114--e> %5 L 4-C
County: D h Al -S tOAI / Phone No. R'<cf - 35 9 - .� q73
Inspector: -Do y/� C7
S r'aAa/M
Date of Inspection: 1 / ` 4 3 - ! 8
Time of Inspection: 0,700
Total Event Precipitation (inches):
2. 72
All permits require qualitative monitoring to be performed during a "measurable stone event."
A "measurable storm event" is a storm event that results in an actual discharge from the permitted site
outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm
interval does not apply if the permittee is able to document that a shorter interval is representative for
local stone events during the sampling period, and the permittee obtains approval from the local DEMLR
Office.
By this signature,) c, kifyAat this report is accurate and complete to the best of my knowledge:
V1
(Signature of Pcrmitter Designee)
1. Outfall Description:
Outfall No. -5- Structure (pipe, ditch, etc.):
Gr-eQ-k
Receiving Stream: � ` 7 /� N !
-f,- u 4 r. e y se 1 t'v,
Describe the 'ndustnal activities that occur within the out II drainage area:
1) a r Nl. a s%' a c4--�r'C-A /L( ? -
Page 1 of 2
S W LJ-242, Last modified 06/01 /20l S

2. Color: Describe the color of the discharge usi�n� basic colors �jed brow , blue, etc. and tint
(light, medium, dark) as descriptors: C teer Gel2't`yl a /1'2�'4'" , " �r"o4u j etc.) and
3. Odor: Describe pny distinct odors that the discharge may have (i.e., smells strongly of oil, weak
chlorine odor, etc.): O A/ F✓
4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear
and 5 is very cloudy:
I 20 3 4 5
5. Floating Solids: Choose the number which best describes the amount of floating solids in the
stormwater discharge, where I is no solids and 5 is the surface covered with floating solids:
(@ 2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended solids in
the stormwater discharge, where 1 is no solids and 5 is extremely muddy:
S 2 3 4 5
7. Is there any foam in the stormwater discharge? O Yes B No.
8. Is there an oil sheen in the stormwater discharge? Oyes O No.
9. Is there evidence of erosion or deposition at the outfall?. O Yes 4D No.
10. Other Obviou
s
Indicators of Stormwater Pollution:
List and describe
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be
indicative of pollutant exposure. These conditions warrant further investigation.
Page 2 of 2
SWU-242, Last modified 06/01/2018

f
aceAnalyfical
www.pacehb&c*M
November 28, 2018
Sam Vedder
Grifols Therapeutics, LLC
8368 US 70 West
Clayton, NC 27520
RE: Project: Stormwater Testing
Pace Project No.: 92407467
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
(919)8344984
Dear Sam Vedder:
Enclosed are the analytical results for sample(s) received by the laboratory on November 15, 2018.
The results relate only to the samples included in this report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
[phone]
Project Manager
Enclosures
cc: David Graham, Grifols Therapeutics, LLC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 1 of 16

IaciceAnalyfical"
"W..pacelebs.mm
Project: Stormwater Testing
Pace Project No.: 92407467
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Charlotte Certification IDS
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
FloridalNELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
Eden Certification IDs
205 East Meadow Road Suite A, Eden, NC 27288
North Carolina Drinking Water Certification #: 37738
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
VirginiaNELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
North Carolina Wastewater Certification #: 633
VirginiaNELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 16

aceAnalytical
wew.pacelabs.com
SAMPLE ANALYTE COUNT
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Project:
Pace Project No.:
Stormwater Testing
92407467
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92407467001
OUTFALL #1
SM 254OD-2011
SOB
1
PASI-E
EPA 1664B
JMS
1
PASI-C
SM 5220D-2011
GC
1
PAS1-A
92407467002
#3-SOUTH PLANT PIPE
SM 254OD-2011
SOB
1
PASI-E
EPA 1664B
JMS
1
PASI-C
SM 5220D-2011
GC
1
PASI-A
92407467003
#4-SE POND
SM 254OD-2011
SOB
1
PASI-E
EPA 1664B
JMS
1
PASI-C
SM 5220D-2011
GC
1
PASI-A
92407467004
#5-CONSOLIDATED OUTFALL
SM 2540D-2011
SOB
1
PASI-E
EPA 16645
JMS
1
PASI-C
SM 5220D-2011
GC
1
PASI-A
92407467005
#2-BASIN #2
SM 254OD-2011
SOB
1
PASI-E
EPA 1664E
JMS
1
PASI-C
SM 5220D-2011
GC
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 16

aceAnalX calo
www.paoelaes.com
ANALYTICAL RESULTS
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Project: Stormwater Testing
Pace Project No.: 92407467
Sample: OUTFALL #1 Lab ID: 92407467001 Collected: 11/13/18 09:30 Received: 11/15/18 10:23 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids Analytical Method: SM 2540D-2011
Total Suspended Solids 8.1 mg/L 2.6 1 11/16/18 12:37
HEM, Oil and Grease Analytical Method: EPA 1664B
Oil and Grease ND mg/L 5.0 1 11/27/18 05:44
5220D COD Low Level Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
Chemical Oxygen Demand 38.6 mg/L 10.0 1 11/2711817:30 1112711823:02 M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/28/2018 12:30 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 16

lceAnalytical
www.pacelabs.corn
ANALYTICAL RESULTS
Project: Stormwater Testing
Pace Project No.: 92407467
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Sample: #3-SOUTH PLANT PIPE Lab ID: 92407467002 Collected: 11/13/18 09:55 Received: 11115118 10:23 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids Analytical Method: SM 25400-2011
Total Suspended Solids 9.1 mg/L 2.6 1 11/16/18 12:37
HEM, Oil and Grease Analytical Method: EPA 16648
Oil and Grease ND mg/L 5.0 1 11/27/18 05:45
5220D COD Low Level Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
Chemical Oxygen Demand 36.3 mg/1- 10.0 1 11/27/18 17:30 11/27/18 23:03
REPORT OF LABORATORY ANALYSIS
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Date: 11 /28/2018 12:30 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 16

aceAnalytical o
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ANALYTICAL RESULTS
Pace Analytical Services, LLG
6701 Conference Drive
Raleigh, NC 27607
[phone]
Project: Stormwater Testing
Pace Project No.: 92407467
Sample: #4-SE POND Lab ID: 92407467003 Collected: 11/13/18 09A5 Received: 11115/18 10:23 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids Analytical Method: SM 254OD-2011
Total Suspended Solids 35.3 mg/L 5.1 1 11/16/18 12:38
HEM, Oil and Grease Analytical Method: EPA 1664B
Oil and Grease ND mg/L 5.0 1 11/27/18 05:46
5220D COD Low Level Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
Chemical Oxygen Demand 20.7 mg/L 10.0 1 11/27/18 17.30 11127/18 23:03
REPORT OF LABORATORY ANALYSIS
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Date: 11/28/2018 12:30 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 16

Pace Analytical Services, LLC
laneAnalytr'cal �
6741 Conference Drive
Raleigh, NC 27607
www.pawtabs.com
[phone]
ANALYTICAL RESULTS
Project: Stormwater Testing
Pace Project No.: 92407467
Sample: #5-CONSOLIDATED
Lab ID: 92407467004 Collected: 11/13/1809:00
Received' 1111511810:23 Matrix: Water
OUTFALL
Parameters
Results Units Report Limit DF
Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 2540D-2011
Total Suspended Solids
60.9 mg1L 5.7 1
11/16/18 12:38
HEM, Oil and Grease
Analytical Method: EPA 1664B
Oil and Grease
ND mg1L 5.0 1
11/27/18 05:46
5220D COD Low Level
Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
Chemical Oxygen Demand
34.8 mglL 10.0 1
11/2711817:30 11/27/1823:03
REPORT OF LABORATORY ANALYSIS
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lceAnalytical"
www.pacelabs.rom
ANALYTICAL RESULTS
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Project: Stormwater Testing
Pace Project No.: 92407467
Sample: #2-BASIN #2
LabID: 92407467005 Collected: 11/13/18 08:50
Received: 11/15/18 10:23 Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed CAS No. Qua!
2540D Total Suspended Solids
Analytical Method: SM 2540D-2011
Total Suspended Solids
21.8 mg1L 2.7 1
11/16/18 12:38
HEM, Oil and Grease
Analytical Method: EPA 1664E
Oil and Grease
ND mglL 5.0 1
11/27/18 05:46
5220D COD Low Level
Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
Chemical Oxygen Demand
35.2 mg/L 10.0 1
11/27/18 17:30 11/27/18 2103
Date: 11/28/2018 12:30 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 8 of 16

aceAnalytical.
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QUALITY CONTROL DATA
Project: Slormwater Testing
Pace Project No.: 92407467
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
QC Batch: 442832
Analysis Method: SM 254OD-2011
QC Batch Method: SM 25400-2011
Analysis Description: 25401) Total Suspended Solids
Associated Lab Samples: 92407467001, 92407467002, 92407467003, 92407467004, 92407467005
METHOD BLANK: 2430440
Matrix: Water
Associated Lab Samples: 92407467001, 92407467002, 92407467003, 92407467004, 92407467005
Blank Reporting
Parameter
Units
Result Limit Analyzed Qualifiers
Total Suspended Solids
mg/L
ND 2.5 11/16/18 12:36
LABORATORY CONTROL SAMPLE:
2430441
Spike LCS LCS % Rec
Parameter
Units
Conc. Result % Rec Limits Qualifiers
Total Suspended Solids
mglL
250 246 98 90-110
SAMPLE DUPLICATE: 2430442
92407395001 Dup
Parameter
Units
Result Result RPD Qualifiers
Total Suspended Solids
mg1L
ND 5.4
SAMPLE DUPLICATE: 2430443
92407395002 Dup
Parameter
Units
Result Result RPD Qualifiers
Total Suspended Solids
mg/L
ND ND
Results presented on thls page are In the units Indicated by the "Units' column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical.
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I
QUALITY CONTROL DATA
IN
Project: Stormwater Testing
Pace Project No.: 92407467
QC Batch: 444059 Analysis Method: EPA 1664B
QC Batch Method: EPA 1664E Analysis Description: 1664 HEM, Oil and Grease
Associated Lab Samples: 92407467001, 92407467002, 92407467003, 92407467004, 92407467005
Pace Analytical Servlces, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
METHOD BLANK: 2435901
Matrix:
Water
Associated Lab Samples: 92407467001,
92407467002, 92407467003, 92407467004, 92407467005
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Oil and Grease
mglL
ND
4.8
11/27/18 05:38
LABORATORY CONTROL SAMPLE:
2435902
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Oil and Grease
mglL
38.5
37.1
96 78-114
MATRIX SPIKE SAMPLE: 2435903
92407857003 Spike MS MS % Rec
Parameter Units Result Conc. Result % Rec Limits Qualifiers
Oil and Grease mglL ND 38.5 36.2 92 78-114
Results presented on this page are in the units Indicated by the "Unite" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Dale: 11/28/2018 12:30 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 16

aceAnalylfical
- www.pacefabs.cam
I
QUALITY CONTROL DATA
Project: Stormwater Testing
Pace Project No.: 92407467
QC Batch: 444276 Analysis Method: SM 52200-2011
QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD, Low Level
Associated Lab Samples: 92407467001, 92407467002, 92407467003, 92407467004„92407467005
METHOD BLANK: 2436963 Matrix: Water
Associated Lab Samples: 92407467001, 92407467002, 92407467003, 92407467004, 92407467005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chemical Oxygen Demand mg/L ND 10.0 11/27/18 23:02
Pace Analytical Services, LLC
6701 Conference Drive
Ra$eigh, NC 27607
[phone]
LABORATORY CONTROL SAMPLE: 2436964
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chemical Oxygen Demand mg1L 75 74.8 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2436965 2436966
MS MSD
92407467001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua]
Chemical Oxygen Demand mg/L 38.6 7.5 7.5 127 126 1160 1160 90-110 1 M1
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11/28/2018 12:30 PM without the written consent of Pace Analytical Services, LLC.
Page 11 of 16

IacceAnalyficale
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QUALIFIERS
Project: Stormwater Testing
Pace Project No.: 92407467
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MID -Adjusted Method Detection Limit.
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270, The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroelhylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosod iphenyla mine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
LABORATORIES
PASI-A Pace Analytical Services -Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-E Pace Analytical Services - Eden
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
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Date: 11/28/2018 12:30 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 16

aceAnalytical
wwwpacelabs.cam
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Stormwater Testing
Pace Project No.: 92407467
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Analytical
Batch
92407467001
OUTFALL #1
SM 2540D-2011
442832
92407467002
#3-SOUTH PLANT PIPE
SM 254OD-2011
442832
92407467003
#4-SE POND
SM 2540D-2011
442832
92407467004
#5-CONSOLIDATED OUTFALL
SM 254OD-2011
442832
92407467005
#2-BASIN #2
SM 2540D-2011
442832
92407467001
OUTFALL #1
EPA 1664B
444059
92407467002
#3-SOUTH PLANT PIPE
EPA 1664B
444059
92407467003
#4-SE POND
EPA 1664B
444059
92407467004
#5-CONSOLIDATED OUTFALL
EPA 1664B
444059
92407467005
#2-BASIN #2
EPA 1664B
444059
92407467001
OUTFALL #1
SM 5220D-2011
444276
SM
5220D-2011
444301
92407467002
#3-SOUTH PLANT PIPE
SM 5220D-2011
444276
SM
5220D-2011
444301
92407467003
#4-SE POND
SM 5220D-2011
444276
SM
5220D-2011
444301
92407467004
#5-CONSOLIDATED OUTFALL
SM 522OD-2011
444276
SM
522OD-2011
444301
92407467005
#2-BASIN #2
SM 5220D-2011
444276
SM
5220D-2011
444301
Date: 11/28/2018 12:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 16

Document Name:
Document
Document Revised: February 7, 2018
Pace Carolinas
Laboratory receiving samples:
Asheville ❑ Eden[] Greenwood ❑ Huntersville❑ Raleigh[] Mechanicsville[]
Client Name: IWO# : 92407467
r 1� Project
t�fi So1�
Courier: ❑Fed �>< ❑UPS USPS ❑talent �l III III I III IN 111111
❑ Commercial []Pace ❑Other. 92407467
Custody. Seal Present? []Yes R9111 ' Seals Intact? FlYes jtw
DatehnitlatsPerson ExamielnsContents: %11tS 106
8 3
Packing Material: ❑Bubble Wrap bubble Bags ❑None ❑ Other Blologl_No [! +
cal Tissue �Frozen?
Thermometer: Des❑
❑IR Gun ID:
12903 Type of ice: []Wet❑Blue ❑None
Cooler Tamp ('C): �{, 1 Correction Factor; Add/subtract ('C) ; p,
Temp should be above freeiing to 6'C
Cooler Temp Corrected (-C): L}.2 ❑Sampks out oftemp criteria. Samples on Ice, cooling process
has begun
USDA Regulated Soll (E�N/A, water sample)
Did samples odgiryate in a quaraAne zone within the United States: CA, NY, or SC (check maps)? Did samples originate From a foreign source (Nterna onally,
11Yes o Inrhidtno Havr. 11 and puprin Rknli IWIYes o
Comments/Discrepancy
Chain afCustod Present?
cs
❑No
❑N/A
1.
Samples Arrived within Hold Time?
❑Vo
0 N/A
2,
Short Hold Time Arral sis 42 hr.)?
Qles
No
N/A
3.
Rush Turn Around Time Requested?
Yes
Na
N/A
4.
Sufficient Volume?
EUYLS
QND
EINLA
S.
Correct Containers Used7
-Pace Containers Used?
Yes
9Ys
[]NO
No
-❑N/A
NIA
6.
Containers Intact?
rs
No
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
No
CK11
9.
Sample Labels Match CDC?
-Includes Date/tlme/la/Anal Is Matrix:
es
U L
©ND
[]N/A
9.
Headspace In VOA Vials 5-5-6mm)?
Yes
No
N/A
10,
Trip Blank Present?
Trip Blank Custody Seals Present?
OYES
es
(]No
[]No
N/A
�N/A
11.
COMMENTS/SAMPLE DISCREPANCY
Lot 10 of sprit containers:
CLIENT NOTINCATION/RESOLLITION
Field Data Required? []Yes ❑No
Person contacted: Date/Time:
Project Manager SCURF Review: l Date:
Project Manager SRF Review: Date:
Page 14 of 16

Document Name:
I Document Revised: February 7, 2018
Sam fe CandHion Upon Recef t(SCUR)
Page 1 of 2
aeeAmlytieal
Document No.:
ISsuing Authortty:
F•CAR•CS-033•Rev.06
Pace Caroffnas Quahty Office
'Check mark top half of box If pH and/or deehior(nation Is
verified and within the acceptance range for preservation
samples.
Fxeaptlou VOA, Cordorm, TOC, 011 and Grease, DRO/8015 (water) DOC, Wig
"Bottom half of box Is to list number of bottle
Project l IWO# : 924Q7467
I3M: MWl Due Date: 11/28/18
CLIENT: 91-Grlf*IEHS
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Log for Preserved Samples
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Type of Preservative
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Date preservatlon adjusted
Time preservation
adjusted
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out of hod, Incarrectpresemative, out of temp, Incorroct conU Inars,
Page 15 of

/ CHAIN -OF -CUSTODY I Analytical Request Document
yfCy pCG if f , _/J The Chain -of -Custody is a LEGAL DOCUMENT. Ad relevant fiNtls must be completed acc"ey.
Soctlon A S3ecftnn 8 I�•� Sec�ian C
Rea6ed Ciknt h ftnTmdac RequhW Protect WornotloW me Page : 1 Of t
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0

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics LLC
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2018
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NCIWW cert #012
PLEASE SIGN ON THE REVERSE 4
Outfall
No.
Date
Sample Collected,
mo/dd/yr
00340
00556
00400
00530
Chemical Oxygen Demand,
m L
Oil and Grease,
m /L
pH,
Standard units
Total Suspended Solids,
m IL
Benchmark
-
120
30
6.0 — 9.0
100
5
01-29-18
17.0
<5.0
6.9
27.8
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier I or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample Collected,
moldd/ r
00556
00530
00400
Oil and Grease,
m
Total Suspended Solids,
m IL
pH, _ . — .
Standard units
—New Motor Oil Usage, "
Average annual allmo
Benchmark
-
30
100
6.0 — 9.0
-
Note: if you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier I or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 01-29-18 (first event sampled)
Total Event Precipitation (inches): 1.54
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
RECEIVED
CENTRAL FILES
DWR SECTION?
S WU-248-102107
Page 1 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of finks and iriAnment for knowing violations."
t(Signature of-Permittce)
l/ bl
C(Date)3
SWU-248-102107
Page 2 of 2

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics LLC
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analvtical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2018
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert #012
PLEASE SIGN ON THE REVERSE 4
Outfall
No.
Date
Sample Collected,
mo/ddl r
00340 100556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
m
pH,
Standard units
Total Suspended Solids,
m IL
Benchmark
-
120
30
6.0 — 9.0
100
1
01-29-18
23
<5.0
6.7
11.5
Note: if you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?_ yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity onitoring Re uirements
Outfall
No.
Date
Sample Collected,
mo/ddl r
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m L
pH,
Standard units
New Motor Oil Usage,
Average annual allmo
Benchmark
-
30
100
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 01-29-18 (first event sampled)
Total Event Precipitation (inches): 1.54
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
SWU-248-102107
Pagel of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and compleam aware that there are significant penalties for submitting false information, including
the possibility of Miffi jand r onment for knowing violations."
((Signature of Permiftce)
/�Fc,ti/�
U(Da_te.)::3
S WU-248-102107
Page 2 of 2

Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit No NCGO60000 or Certificate of Coverage No.: N CGO60039
Facility Name: Grifols Therapeutics LLC
County: Johnston County Phone No 919-359-5473
Inspector: David S. Graham
Date of Inspection: 1/2912018
By this signature, I ceftify that ftiis t�port is accurate and complete to the best of my knowledge:
1.Outfali Description
Outfall No. 1 Structure (pipe, ditch, etc.) Stream
Receiving Stream: tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _ Clear with a medium brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 ® 4 5 6 7 8 9 10
Page 1

SW U-242-020705
5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
0 2 3, 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where 1 is nos s and 10 is extremely muddy:
1 2 d 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes No
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes No
9. Deposition at Outfail
Is there deposition of material (sediment, etc.) at or immediately below the outfall? YdQ
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes G
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SW U-242-020705

r
GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics LLC
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2018
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert #012
PLEASE SIGN ON THE REVERSE 4
Outfall
No.
Date
Sample Collected,
moldd/ r
00340
00556
00400
00530
Chemical Oxygen Demand,
m L
Oil and Grease,
m L
pH,
Standard units
Total Suspended Solids,
m L
Benchmark
-
120
30
6.0 — 9.0
100
2
01-29-18
16.0
<5.0
6.7
36.1
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity onitoring Requirements
Outfall
No.
Date
Sample Collected,
mo/dd/ r
00556
00530
00400
Oil and Grease,
m IL
Total Suspended Solids,
mg1L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 01-29-18 (first event sampled)
Total Event Precipitation (inches): 1.54
Date T(list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S WU-248-102107
Page 1 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines nd prisonment for knowing violations."
{Signature-of-Permittee �Da
SWU-248-102107
Page 2 of 2

`o�ot w n r"Zy
�? r
7 y
fl Y
Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit Nc NCG060000 or Certificate of Coverage No.: N CGO60039
Facility Name: Grifols Therapeutics LLC
County: Johnston Count Phone No.919-359-5473
Inspector: David S. Graham
Date of Inspection: 1/2912018
By this signature, I certifyqthat tfiiis�eNrt is accurate and complete to the best of my knowledge:
1.Outfall Description
Outfall No. 2 Structure (pipe, ditch, etc.) ditch exiting existing pond
Receiving Stream: tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _ Clear with a medium brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 ® 4 5 6 7 8 9 10
Page 1

SW U-242-020705
5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
O 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where 1 is no solids and 10 is extremely muddy:
1 2 0 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes No
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes(D
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? YeQ
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes No
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SW U-242-020705

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics LLC
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2018
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NCIWW cert #012
PLEASE SIGN ON THE REVERSE 4
O u tfall
No.
Date
Sample Collected,
moldd/vr
00340
00556
00400
00530
Chemical Oxygen Demand,
m L
Oil and Grease,
mg!
pH,
Standard units
Total Suspended Solids,
m IL
Benchmark
-
120
30
6.0 — 9.0
100
3
01-29-18
27.0
<5.0
7.0
7.1
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes. X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample Collected,
mo/dd/ yr
00556
00530
00400
Oil and Grease,
m L
Total Suspended Solids,
m IL
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier I or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 01-29-18 (first event sampled)
Total Event Precipitation (inches): 1.54
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S WU-248-102107
Page 1 of 2

r
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware hat there are significant penalties for submitting false information, including
the possibility of fines and imprisonn� t fo knowing violations."
I
((Date)
SWU-248-102107
Page 2 of 2

�F�jW�AtFq�G
Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit No NCGO60000 or Certificate of Coverage No.: N CG060039
Facility Name: Grifols Therapeutics LLC
County: Johnston Count Phone No.919-359-5473
Inspector: David S. Graham
Date of Inspection: 1/2912018
By this signature, I certifNh#fjWjs teport is accurate and complete to the best of my knowledge:
1.Outfall Description
Outfall No. 3 Structure (pipe, ditch, etc.) Pipe _
Receiving Stream: tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _Clear with a medium brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 ® 4 5 6 7 8 9 10
Page 1

SW U-242-020705
5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
1O 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where 1 is no s s and 10 is extremely muddy:
1 2 Id 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes G
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes No
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? Yd(a
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes G
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SW U-242-020705

,416 _
GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics LLC
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analvdcal
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2018
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NCIWW cert #012
PLEASE SIGN ON THE REVERSE 4
Outfall
No.
Date
Sample Collected,
mo/ddl r
00340
00556
00400
00530
Chemical Oxygen Demand,
m IL
Oil and Grease,
m L
pH,
Standard units
Total Suspended Solids,
m L
Benchmark
-
120
30
6.0 — 9.0
100
4
01-29-18
22.0
<5.0
6.5
7.8
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?_ yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity onitoring Requirements
Outfall
No.
Date
Sample Collected,
mo/dd/vr
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 01-29-18 (first event sampled)
Total Event Precipitation (inches): 1.54
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S WU-248-102107
Pagel of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I anj aware that there are significant penalties for submitting false information, including
the possibility of fines and imp'fisoh*A for knowing violations."
Y
(Signature fue—rmittee- [(D,ate})
S WU-248-102107
Page 2 of 2

Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit Ne NCGO60000 or Certificate of Coverage No.: N CG060039
Facility Name: Grifols Therapeutics LLC
County: Johnston Count Phone No.919-359-5473
Inspector: David S. Graham
Date of Inspection: 1/29/2018
By.this signature, I certify'th4tktt�4 report is accurate and complete to the best of my knowledge:
1.Outfall Description
Outfall No. 4 Structure (pipe, ditch, etc.) Pipe from pond
Receiving Stream: tributa to the Neuse River
Describe the industrial activities that occur within the outfail drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _ clear with a medium brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 ® 4 5 6 7 8 9 10
Page 1

SW U-242-020705
5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
O 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where 1 is no solids and 10 is extremely muddy:
1 2 ® 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes G
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes No
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? Ydja
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes G
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SW U-242-020705

Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit No NCG060000 or Certificate of Coverage No.: N. CG060039
Facility Name: Grifols Therapeutics LLC
County: Johnston County Phone No. 919-359-5473
Inspector: David S. Graham
Date of Inspection: 1/29/2018
By this signature, I celgif}tejt #his report is accurate and complete to the best of my knowledge:
1.Outfall Description
Outfall No. 5 Structure (pipe, ditch, etc.) creek
Receiving Stream: tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _ clear with a medium brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 © 4 5 6 7 8 9 10
Page 1

SW U-242-020705
5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
O 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where 1 is nos ids and 10 is extremely muddy:
1 2 U 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes No
B. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes No
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? YEG
10. Erosion at Outfall
Is there erosion at or immediately below the outfaii? Yes G
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SW U-242-020705

aceAnalj&al.
www.pacebbs.com
February 12, 2018
Sam Vedder
Grifols Therapeutics, LLC
8368 US 70 West
Clayton, NC 27520
RE: Project: Stormwater
Pace Project No.: 92371235
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
(919 )834-4984
Dear Sam Vedder:
Enclosed are the analytical results for sample(s) received by the laboratory on January 30, 2018.
The results relate only to the samples included in this report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: David Graham, Grifols Therapeutics, LLC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 1 of 16

Pace Analytical Services, LLC
1 Conference Drive
aceMalXical a fi7D Raleigh, NC 27607
www.px&abs.com [phone]
CERTIFICATIONS
Project: Stormwater
Pace Project No.: 92371235
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, INC 28078
South Carolina Certification #: 99006001
LouisianalNELAP Certification # LA170028
Florida/NELAP Certification #: E87627
North Carolina Drinking Water Certification #: 37706
Kentucky UST Certification #: 84
North Carolina Field Services Certification #: 5342
VirginiaNELAP Certification #: 460221
North Carolina Wastewater Certification #: 12
Asheville Certification Ws
2225 Riverside Drive, Asheville, NC 28804 North Carolina Wastewater Certification #: 40
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
Massachusetts Certification #: M-NC030 VirginiaNELAP Certification #: 460222
North Carolina Drinking Water Certification #: 37712
Eden Certification IDs
205 East Meadow Road Suite A, Eden, NC 27288
North Carolina Drinking Water Certification #: 37738
North Carolina Wastewater Certification #: 633
VirginiaNELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 16

Pace Analytical Services, LLC
aceAnalytrcal
fi701 Conference Drive
Raleigh, NC 27607
www.psmjabs.com
[phone]
SAMPLE ANALYTE COUNT
Project: Stormwater
Pace Project No.: 92371235
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
92371235001 Outfall #1
SM 2540D
WCP
1
PASI-E
EPA 16648
JMS
1
PASI-C
SM 5220D
NAL
1
PASI-A
92371235(102 #2 - Basin #2
SM 2540D
WCP
1
PASI-E
EPA 1664B
JMS
1
PASI-C
SM 5220D
NAL
1
PASI-A
92371235003 #3 - South Plant Pipe
SM 2540D
WCP
1
PASI-E
EPA 1664B
JMS
1
PASI-C
SM 5220D
NAL
1
PASI-A
92371235004 44 - SE Pond
SM 2540D
WCP
1
PASI-E
EPA 166413
JMS
1
PASI-C
SM 5220D
NAL
1
PASI-A
92371235005 #5 - Consolidated Outfall
SM 2540D
WCP
1
PASI-E
EPA 1664E
JMS
1
PASI-C
SM 5220D
NAL
1
PASI-A
REPORT Of LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 16

aceAnalyfical
www,parco4bs.com
ANALYTICAL RESULTS
Project: Stormwater
Pace Project No.: 92371235
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Sample: Outfall #1
Lab ID: 92371235001 Collected: 01/29/18 10:55
Received: 01/30/18 09:30 Matrix: Water
Parameters
Results Units
Report Limit DF
Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
11.5 mg/L
2.6 1
02/01/18 15:22
HEM, Oil and Grease
Analytical Method: EPA 1664E
Oil and Grease
ND mg/L
5.0 1
02/06/18 04:53
5220D COD Low Level
Analytical Method: SM 5220D
Chemical Oxygen Demand
23.0 mg/L
10.0 1
02/08/18 13:04 M1
Date: 0211212018 04:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the w(Ren consent of Pace Analytical Services, LLC.
Page 4 of 16

Pace Analytical Services, LLC
"ac,Analytical •
$701 ConferenceDrive
Raleigh, NC 2767607
www.pamws.com
[phone]
ANALYTICAL RESULTS
Project: Stormwater
Pace Project No.: 92371235
Sample: #2 - Basin #2
Lab ID: 92371235002 Collected: 01/29/18 10:40
Received: 01/30/18 09:30 Matrix: Water
Parameters
Results Units Report limit OF
Prepared Analyzed CAS No. Oual
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
36.1 mg/L 3.7 1
02/01/18 15:22
HEM, Oil and Grease
Analytical Method: EPA 1664E
Oil and Grease
ND mg/L 5.0 1
02/06/18 04:53
5220D COD Low Level
Analytical Method: SM 5220D
Chemical Oxygen Demand
16.0 mg/L 10.0 1
02/08/18 13:04
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2018 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 16

acmnalytical
WW pecelabs.c=
ANALYTICAL RESULTS
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Project: Stormwater
Pace Project No.: 92371235
Sample: #3 - South Plant Pipe
Lab ID: 92371235003 Collected: 01/29118 11:25
Received: 01/30/18 09:30 Matrix: Water
Parameters
Results Units
Report Limit DF
Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
7.1 mg/L
2.6 1
02/01/18 15:23
HEM, Oil and Grease
Analytical Method: EPA 1664E
Oil and Grease
ND mg/L
5.0 1
02/06/18 04:53
5220D COD Low Level
Analytical Method: SM 5220D
Chemical Oxygen Demand
27.0 mg/L
10.0 1
02/08/18 13:04
Date: 02/12/2018 04:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 16

Pace Analytical Services, LLC
aiCeMalXical• 6701 Conference Drive
Raleigh, NC 27607
www.pacwabs.com
[phone]
ANALYTICAL RESULTS
Project: Stormwater
Pace Project No.: 92371235
Sample: 94 - SE Pond
Lab ID: 92371235004 Collected: 01/29/18 11:15
Received: 01/30/18 09:30 Matrix: Water
Parameters
Results Units
Report Limit DF
Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
7.8 mg/L
2.8 1
02l01118 15:23
HEM, Oil and Grease
Analytical Method: EPA 1664E
Oil and Grease
ND mg1L
5.0 1
02/06/18 04:53
5220D COD Low Level
Analytical Method: SM 5220D
Chemical Oxygen Demand
22.0 mg1L
10.0 1
02/08/18 13:04
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2018 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 16

Pace Analytical Services, LLC
IacieAnalj6calo fi701 Conference Drive
Raleigh, NC 27807
www.pacelobs.com [phone]
ANALYTICAL RESULTS
Project: Stormwater
Pace Project No.: 92371235
Sample: #5 - Consolidated Outfall
Lab ID: 92371235005 Collected: 01129/18 10:25
Received: 01/30/18 09:30 Matrix: Water
Parameters
Results Units
Report Limit DF
Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
27.8 mg/L
2.8 1
02/01/113 15:24
HEM, Oil and Grease
Analytical Method: EPA 1664B
Oil and Grease
ND mg/L
5.0 1
02/06/18 04:54
5220D COD Low Level
Analytical Method: SM 5220D
Chemical Oxygen Demand
17.0 mg/L
10.0 1
02/08/18 13:04
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2018 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 16

aceAnalytical
www.paoofos.com
QUALITY CONTROL DATA
Project: Stormwater
Pace Project No.: 92371235
OC Batch: 396385 Analysis Method: SM 2540D
QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids
Associated Lab Samples: 92371235001, 92371235002, 92371235003, 92371235004, 92371235005
METHOD BLANK: 2197641 Matrix: Water
Associated Lab Samples: 92371235001, 92371235002, 92371235003, 92371235004, 92371235005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Suspended Solids mg/L ND 2.5 02/01/18 15:17
LABORATORY CONTROL SAMPLE:
2197642
Spike
LCS
Parameter
Units
Conc.
Result
Total Suspended Solids
mg/L
250
242
SAMPLE DUPLICATE: 2197643
92371182002
Dup
Parameter
Units
Result
Result
Total Suspended Solids
mg/L
136
175
SAMPLE DUPLICATE: 2197644
92371178001
Dup
Parameter
Units
Result
Result
Total Suspended Solids
mg/L
46.2
48.9
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
�919)834-4984
LCS % Rec
% Rec Limits Qualifiers
97 90-110
RPD Qualifiers
25 D6
RPD Qualifiers
6 D6
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the resuh.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/1212018 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 16

acmnalytical
Nww.pacelabs.com
QUALITY CONTROL DATA
Project: Stormwater
Pace Project No.: 92371235
QC Batch: 396817 Analysis Method: EPA 16646
QC Batch Method: EPA 1664E Analysis Description: 1664 HEM, Oil and Grease
Associated Lab Samples: 92371235001, 92371235002, 92371235003, 92371235004, 92371235005
METHOD BLANK: 2200134 Matrix: Water
Associated Lab Samples: 92371235001, 92371235002, 92371235003, 92371235004, 92371235005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg/L ND 5.0 02/06/18 04:44
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
LABORATORY CONTROL SAMPLE:
2200135
Spike LCS
LCS
% Rec
Parameter
Units
Cone. Result
% Rec
Limits
Qualifiers
Oil and Grease
mg/L
40 37.8
94
78-114
MATRIX SPIKE SAMPLE:
2200136
35371516002 Spike
MS
MS
% Rec
Parameter
Units
Result Cone.
Result
% Rec
Limits Qualifiers
Oil and Grease
mg/L
1 A U 40
38.2
93 78-114
Results presented on this page are in the units indicated by the -Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2018 04;48 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 16

s
aceAnalytical
www.pecelabs.corn
QUALITY CONTROL DATA
Project: Stormwater
Pace Project No.: 92371235
QC Batch: 397050 Analysis Method: SM 5220D
QC Batch Method: SM 5220D Analysis Description: 52200 COD, Low Level
Associated Lab Samples: 92371235001, 92371235002, 92371235003, 92371235004, 92371235005
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
METHOD BLANK: 2201633
Matrix: Water
Associated Lab Samples: 92371235001, 92371235002, 92371235003, 92371235004, 92371235005
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Chemical Oxygen Demand
mg1L
ND 10,0
02108/18 13:04
LABORATORY CONTROL SAMPLE:
2201634
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Chemical Oxygen Demand
mg/L
75 74.0
99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2201635 2201636
MS MSD
92371235001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chemical Oxygen Demand mglL 23.0 75 75 117 117 125 125 90-110 0 M1
Results presented on this page are in the units indicated by the 'units" column except where an alternate unit Is presented to the right of the result,
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2018 04:48 PM without the written consent of Pace Analytical Services, LLC.
Page 11 of 16

5ceAna1j6ca1
w»w:pacefebstom
QUALIFIERS
Project: Stormwater
Pace Project No.. 92371235
DEFINITIONS
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
{919)834-4984
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-E Pace Analytical Services - Eden
ANALYTE QUALIFIERS
D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2018 04:48 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 16

aceAnalytilca!
www.pacelabs.aom
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Stormwater
Pace Project No.: 92371235
Lab ID Sample ID
92371235001
Outfall #1
92371235002
#2 - Basin #2
92371235003
#3 - South Plant Pipe
92371235004
#4 - SE Pond
92371235005
#5 - Consolidated Outfall
92371235001
Outfall #1
92371235002
#2 - Basin #2
92371235003
#3 - South Plant Pipe
92371235004
#4 - SE Pond
92371235005
#5 - Consolidated Outfall
92371235001
Outfall #1
92371235002
#2 - Basin #2
92371235003
#3 - South Plant Pipe
92371235004
#4 - SE Pond
92371235005
#5 - Consolidated Outfall
Date: 02/12/2018 04:48 PM
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Analytical
QC Batch Method OC Batch Analytical Method Batch
SM
2540D
396385
SM
2540D
396385
SM
2540D
396385
SM
2540D
396385
SM
2540D
396385
EPA 1664B
396817
EPA 1664B
396817
EPA 1664B
395817
EPA 1664B
396817
EPA 1664B
396817
SM 5220D
397050
SM 5220D
397050
SM 5220D
397050
SM 5220D
397050
SM 5220D
397050
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 13 of 16

•
0
Document flame: Document Revised: January 16, 2018
napicai<
Sample Condition Upon Receipt(SCUR} Page 1 of 2
Document No.: i Issuing Authority:
/�._.,-Pr9C
F-CAR-CS-033-Rev,05 Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ HLIntersville ❑ Raleigh Mechanicsville❑
• •
Client Name:
Project ql W V# : 92371235
Courier:
❑Client
I
Fe— .—❑`
❑UPSDU5P5_ .—
❑ Commercial
Custody Seal Present?
ace .- ❑Other:
❑Yes No Seals Intact? ❑Yes
`92371235
-- - -
Date/Initials Person Examining Contents:' L% - (�
Packing Material:
❑Bubble Wrap ubble Bags ❑None
❑ other
Biological Tissue Frozen?
Thermometer;
(r
lI
��, ( Type of Ice: (4
❑Blue
❑Yes [_]NO/A
©None
lR Gun IO.
Correction F ctor. Cooler Temp Corrected ('C): Temp should be above freezing to VC
�, I ❑Samples out of temp criteria. Samples on ice, cooling process
has begun
_ — - - - — — — -
L,
USDA Regulated Soil ( - N/A, water sample)
Did samples C, iry a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internatio
dyes IiTNn including Hawaii and ?uertn Rirnl? r1Ym I;ir a
Comments/Discrepancy:
Chain of Custody Present?
s
❑No ❑N/A
1.
Samples Arrived within Hold Time?
s
No []NIA
2.
Short Hold Time Analysis (02 hr.)?
❑Yes
o ❑NIA
3.
Rush Turn Around Time Requested?
❑Yes
❑N/A
4.
Sufficient Volume?
No ❑N/A
5.
Correct Containers Used?
-Pace Containers Used?
Y
No ❑N/A
Na ❑N/A
6.
Containers Intact?
No ❑MIA
Dissolved analysis: 5ampl es Field Filtered?
Yes
No
A
g.
Sample Labels Match COC?
-Includes Date/lime/ID/Analysis Matrix:
es
[:)NO ❑NIA
9.
Heads pace in VOA Vials (>5-6mml?
❑Yes
D No
N/A
I 10.
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
❑Yes
❑No
No
NIA
N/A
11.
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted;
Date/Time:
Lot ID of soffit containers:
Field Data Required? UYes (JNo
Project Manager SCURF Review: -j ,� Date: G I I 1 y
Project Manager SRF Review: t Date:
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers)
Page 14 of 16

Document Name:
Document Revised: January 16, 2018
A •
Sample Condition U an Receipt(5CUR)
Page 2 of 2
-,,2eAaalytrcal
Document No.:
Issuing Authority:
F-CAR•CS-033-Rev.05
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination Is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
*--*Bottorn half.of-box is to list number -of -bottle _ —
Project # IWO*:92371235
IPM: NMG Due Date: 02/08/18
iCLIENT: 91-GrifolEHS
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Page 15 of 16

c
.FareAflltj6c�!
CHAIN -OF -CUSTODY 1 Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
i
Section A I Section B Section C
j
Required Client Infofhlation: Required Project Information: Invoice Information: Pe 0 : 1 Of t
Company: Gnfols Therapeutics 1 Report To: Sam Vedder I Allention:
Address' - 836B US 10 West I Copy Toy Company Name:
Clayton. NC 27520 I
Address:
Regulatory Agency
Email. i
Purchase Ordor C
Pace Ouolw
Phone: JFax [
Project Name: Stonnwaler
Pace Project Manger. nicofe.gosiorowski0pacelabs.com,
State i Location _
Requesled Due Dow: I
Prujecl 0: 1
Pace Profile W 7122.2
NC
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DATE*'.
T_IjM:Ei"c" _
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SAMPLER NAME AND SIGNATURE -.. `. ,.' ,• ''_ - -' - _ �� ,
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PRINT Name of SAMPLER:
SIGNATURE of SAMPLER:
DATE Signed: t Y
j
0
to

STORMWATER DISCHARGE OUTFALL (SDO)
RECEIVE 6111TORING REPORT
GENERAL PERMIT NO. NCG060000 SAMPLES COLLECTED DURING CALENDAR YEAR. 2017
CERTIFICATE OF COVERAGE NO. NCG060039 OCT 0 3 2017 (This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
FACILITY NAME Grifols Therapeutics CC-NTRAL FILES COUNTY Johnston
PERSON COLLECTING SAMPLES David S. GrahamWR SECTION PHONE NO. [phone]
CERTIFIED LABORATORY Pace Analytical Lab #NC/WW cert #012
PLEASE SIGN ON THE REVERSE 4
Part A: Specific Monitoring Requirements
jQntfaiJ
Nol
Date
Sample Collected,
mo/ddl r
00340
00556
00400
00530
Chemical Oxygen Demand,
m
Oil and Grease,
m /L
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
1101
08-29-17
<10.0
<5.0
6.8
4.2
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier I or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?_ yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample Collected,
mo/dd/ r
00556
00530
00400
Oil and Grease,
m
Total Suspended Solids,
m
pH,
Standard units
New Motor Oil Usage,
Average annual gaUmo
Benchmark
-
30
100
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 08-29-17 (first event sampled)
Total Event Precipitation (inches): 0.14
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
SWU-248-102107
Page 1 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines andw%"sonment for knowing violations."
(Signature of Permittee)
e7�1 /-Zo
(Date)
SWU-248-102107
Page 2 of 2

�i11 Y�r _\1y
plqiii�_C
Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit Nc NCG060000 or Certificate of Coverage No.: N CG060039
Facility Name: Grifols Therapeutics
County: Johnston County Phone No.919-359-5473
Inspector: David S. Graham
Date of Inspection: 8/29/2017
n
By this signature, I c6kiajth}s report is accurate and complete to the best of my knowledge:
(Signature of Permittee �Dignee)
1I.Outfall Description
tOuifall;No 1 Structure (pipe, ditch, etc.) Stream
Receiving Stream: tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _ Clear with a light brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 ® 4 5 6 7 8 9 10
Page 1

SW U-242-020705
5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
0 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where 1 " no solids and 10 is extremely muddy:
1 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes 0
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes No
9. Deposition at Outfall
Is there deposition of material (sediment, etc,) at or immediately below the outfall? YdQN
10. Erosion at 0utfalI x
Is there erosion at or immediately below the outfall? Yes No
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SW U-242-020705

1\1
Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit No NCGO60000 or Certificate of Coverage No.: N CG060039
Facility Name: Grifols Therapeutics
County: Johnston County _ Phone No.919-359-5473
Inspector: David S. Graham
Date of Inspection: 8/29/2017
By this signatu?6,,l cftWaj this report is accurate and complete to the best of my knowledge:
(Signature of Perm
ee)
1.Outfall Description
Outfa No.�. 3,Structure (pipe, ditch, etc.) Pik
a
Receiving Stream: tributes to the Neuse River
Describe the industrial activities, that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _ light brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 © 4 5 6 7 8 9 10
Page 1

SW U-242-020705
5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
9O 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where 1 ' no solids and 10 is extremely muddy:
1 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes G
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes No
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? Yd(D
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes G
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SW U-242-020705

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analvtical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2017
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert #012
PLEASE SIGN ON THE REVERSE 4
tOatfa11
lN�o'
Date
Sample Collected,
mo/dd/vr
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
mgfL
pH,
Standard units
Total Suspended Solids,
m
Benchmark i
-
120
30
6.0 — 9.0
100
F3W
08-29-17
27.0
<5.0
8.4
6.9
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?_ yes X no
(if yes, complete Part 13)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample Collected,
mo/ddl r
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier I or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 08-29-17 (first event sampled)
Total Event Precipitation (inches): 0.14
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S W U-248-102107
Pagel of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and inkp�i oo ment for knowing violations."
(Signature of Permittee)
(Date
S W U-248-102107
Page 2 of 2

`o�oF W,arfR pG
O lqiii� Y
Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit No NCG060000 or Certificate of Coverage No.: N CGO60039
Facility Name: Grifols Therapeutics
County: Johnston County Phone No, 919-359-5473
Inspector: David S. Graham
Date of Inspection: 8/29/2017
By this signature:\ ce44 #hot this report is accurate and complete to the best of my knowledge:
(Signature of Permits* Or Designee
1I.Outfall Description
Outfall.No4;Structure (pipe, ditch, etc.) Pipe from pond
Receiving Stream: tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _light brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 © 4 5 6 7 8 9 10
Page 1

SW U-242-020705
5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
O 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where 1 ' no solids and 10 is extremely muddy:
1 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes No
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes No
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? YdQ
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes G b
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SW U-242-020705

SW U-242-020705
5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
1O 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where no solids and 10 is extremely muddy:
1 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes G
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes No
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? YG
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes G
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SW U-242-020705

Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit No NCG060000 or Certificate of Coverage No.: N CG060039
Facility Name: Grifols Therapeutics
County: Johnston County Phone No.919-359-5473 .
Inspector: David S. Graham
Date of Inspection: 8/29/2017
By this signature, I certify that this rgQqrt i� accurate and complete to the best of my knowledge:
(Signature of Permittee or Desig
1.Outfall Description
0utfall.No.-----57Structure (pipe, ditch, etc.) creek
Receiving Stream: tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _clear with a light brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 ® 4 5 6 7 8 9 10
Page 1

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2017
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cent #012
PLEASE SIGN ON THE REVERSE 4
Ou`tfally
N
Date
Sample Collected,
mo/dd/ yr
00340
00556
00400
00530
Chemical Oxygen Demand,
m
Oil and Grease,
m L
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
4®
08-29-17
31.0
<5.0
6.3
13.2
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier I or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?_ yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Ou tfall
No.
Date
Sample Collected,
moldd/ r
00556
00530
00400
Oil and Grease,
m tL
Total Suspended Solids,
m
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier I or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 08-29-17 (first event sampled)
Total Event Precipitation (inches): 0.14
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S WU-248-102107
Page I of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, -
true, accurate, and comp Ue!V am aware that there are significant penalties for submitting false information, including
the possibility of fines aidprisonment for knowing violations."
(Signature of Permittee)
oc) //
(Date)
SWU-248-102107
Page 2 of 2

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2017
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert #012
PLEASE SIGN ON THE REVERSE 4
Acotfilf
JNo
Date
Sample Collected,
mo/ddl r
00340
00556
00400
00530
Chemical Oxygen Demand,
m L
Oil and Grease,
m L
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
r5�
08-29-17
<10.0
<5.0
6.9
<2.5
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier I or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?_ yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample Collected,
mo/dd/ yr
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
t00
6.0 — 9.0
-
Note: if you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 08-29-17 (first event sampled)
Total Event Precipitation (inches): 0.14
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S WIJ-248-102107
Page 1 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines,,.and impment for knowing violations."
(Signature of Permittee)
0 M 120 /a -
(Date) `
S WU-248-102107
Page 2 of 2

(�5aceAnalytical
wivw.pacefa6s.com
September 11, 2017
Sam Vedder
Grifols Therapeutics, Inc.
8368 US 70 West
Clayton, NC 27520
RE: Project: Stormwater
Pace Project No.: 92353467
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
(9)9)834-4984
Dear Sam Vedder:
Enclosed are the analytical results for sample(s) received by the laboratory on August 30, 2017. The
results relate only to the samples included in this report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: David Graham, Grifols Therapeutics, Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wntten consent of Pace Analytical Services, LLC, Page 3 of 15

(�'a'neAnalyfical*
www.p&*Ma.com
CERTIFICATIONS
Project: Stormwater
Pace Project No.: 92353467
Charlotte Certification IDs
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
9800 Kincey Ave. Ste 100, Huntersvil le, NC 28076
South Carolina Certification #: 99006001
North Carolina Drinking Water Certification #: 37706
Florida/NELAP Certification #: E87627
North Carolina Field Services Certification #: 5342
Kentucky UST Certification #: 84
North Carolina Wastewater Certification #: 12
VirginiaNELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
Eden Certification iDs
205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Wastewater Certification #: 633
North Carolina Drinking Water Certification #: 37738 VirginiaNELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 15

Pace Analytical Services, LLC
6701 Conference Drive
(�157ceMalyfiml* Raleigh, NC 27607
wxw.Pecelabs-mm [phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Stormwater
92353467
Analytes
Lab 1D
Sample ID
Method
Analysts
Reported
Laboratory
92353467001
Outfall #1
SM 2540D
CTB
1
PASI-E
EPA 1664B
JMS
1
PASI-C
SM 52200
MVC
1
PASI-A
92353467002
#3-South Plant Pipe
SM 2540D
CTB
1
PASI-E
EPA 1664B
JMS
1
PASI-C
SM 5220D
MVC
1
PASI-A
92353467003
#4-SE Pond
SM 2540D
CTB
1
PASI-E
EPA 1664B
JMS
1
PASI-C
SM 5220D
MVC
1
PASI-A
92353467004
#5-Consolidated Outfall
SM 2540D
CTB
1
PASI-E
EPA 1664B
JMS
1
PASI-C
SM 5220D
MVC
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written Consent of Pace Analytical Services, LLC. Page 3 of 15

Pace Analytical Services, LLC
6701 Conference Drive
(�5a'ceMalXical* Raleigh, NC 27607
wwwpac&wscom [phone]
ANALYTICAL RESULTS
Project: Stormwater
Pace Project No.: 92353467
Sample: Outfall #1
Parameters
Lab ID: 92353467001 Collected: 08/29/17 11:30
Results Units Report Limit DF
Received: 08/30/17 10:00 Matrix: Water
Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
4.2 mglL
2.5 1
08/31/17 13:33
HEM, Oil and Grease
Analytical Method. EPA 1664B
Oil and Grease
ND mg1L
5.0 1
09/11/17 05:23
5220D COD Low Level
Analytical Method: SM 52200
Chemical Oxygen Demand
ND mg/L
10.0 1
09/07/17 02:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/11/2017 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 15

aceAnalytical.
www.pecekhs.csm
ANALYTICAL RESULTS
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Project: Stormwater
Pace Project No.: 92353467
Sample: #3-South Plant Pipe Lab ID: 92353467002 Collected: 08129/17 11:45 Received: 08/30/17 10:00 Matrix: Water
Parameters
Results Units
Report Limit DF
Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
6.9 mg/L
4.8 1
08/31/17 13:34
HEM, Oil and Grease
Analytical Method: EPA 1664E
Oil and Grease
ND mg/L
5.0 1
09/11/17 05:23
5220D COD Low Level
Analytical Method: SM 5220D
Chemical Oxygen Demand
27.0 mglL
10.0 1
09/07/17 02:00
Date: 09/11/2017 01:22 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 15

(�'a?ceAnaljdicale
wwwpecelabs.00m
ANALYTICAL RESULTS
Project: Stormwatef
Pace Project No.: 92353467
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Sample: #4-SE Pond
Parameters
Lab ID: 92353467003 Collected: 08/29/17 11740
Results Units Report Limit DF
Received: 08/30/17 10:00 Matrix: Water
Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 25400
Total Suspended Solids
13.2 mg/L
6.1 1
08/31/17 13:34
HEM, Oil and Grease
Analytical Method: EPA 166413
Oil and Grease
ND mg/L
5.0 1
09/11/17 05:24
5220D COD Low Level
Analytical Method: SM 5220D
Chemical Oxygen Demand
31.0 mg/L
10.0 1
09/07/17 02:00
REPORT OF LABORATORY ANALYSIS
This report shag not be reproduced, except in full,
Date: 09/11 /2017 01:22 PM without the written consent of Pace Analytical Services, LLC, Page 6 of 15

laceAnalj4ical
wrw.pacela8s.com
ANALYTICAL RESULTS
Project. Stormwater
Pace Project No.: 92353467
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Sample: #5-Consolidated Outfall
Parameters
Lab ID: 92353467004 Collected: 08/29/17 11:05
Results Units Report Limit DF
Received: 08/30/17 10:00 Matrix: Water
Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
ND mg/L
2.5 1
08/31/17 13:35
HEM, Oil and Grease
Analytical Method: EPA 1664B
Oil and Grease
ND mg/L
5.0 1
09/11/17 05:24
5220D COD Low Level
Analytical Method: SM 5220D
Chemical Oxygen Demand
ND mg/L
10.0 1
09/07/17 02:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/11 /2017 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 15

(�5a'ceAnalyficalo
w+vw.paoetab�.cem
QUALITY CONTROL DATA
Project: Stormwater
Pace Project No.: 92353467
QC Batch: 375948 Analysis Method: SM 2540D
QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids
Associated Lab Samples: 92353467001, 92353467002, 92353467003, 92353467004
METHOD BLANK: 2082593 Matrix: Water
Associated Lab Samples: 92353467001, 92353467002, 92353467003, 92353467004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Suspended Solids mglL ND 2.5 08/31/17 13:32
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
LABORATORY CONTROL SAMPLE:
2082594
Spike
LCS LCS
% Rec
Parameter -
Units
Conc.
Result % Rec
Limits Qualifiers
Total Suspended Solids
mg/L
250
250 100
90-110
SAMPLE DUPLICATE: 2082595
92353389001
Dup
Parameter
Units
Result
Result RPD
Qualifiers
Total Suspended Solids
mglL
37,1
37.1
0
SAMPLE DUPLICATE. 2082596
"
92353451001
Dup
Parameter
Units
Result
Result RPD
Qualifiers
Total Suspended Solids
mglL
91.0
79.1
14 D6
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in Putt.
Date: 09/11/2017 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 15

laneAnalyfical�
www.pecekhs.cvm
QUALITY CONTROL DATA
Project: Stormwater
Pace Project No.: 92353467
QC Batch: 377090 Analysis Method: EPA 1664B
QC Batch Method: EPA 1664B Analysis Description: 1664 HEM, Oil and Grease
Associated Lab Samples: 92353467001, 92353467002, 92353467003, 92353467004
METHOD BLANK: 2089068 Matrix: Water
Associated Lab Samples: 92353467001, 92353467002, 92353467003, 92353467004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg/L ND 5.0 09/11/17 05:19
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
LABORATORY CONTROL SAMPLE:
2089069
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits
Qualifiers
Oil and Grease
mg/L
40 38.5
96
78-114
MATRIX SPIKE SAMPLE:
2089070
92353349001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
% Rec
Limits Qualifiers
Oil and Grease
mg1L
NO 40
38.5
95
78-114
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
Date: 09/11/2017 01:22 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 15

aceAnalytical
www.pocoiob3.com
QUALITY CONTROL DATA
Project: Stormwater
Pace Project No.: 92353467
QC Batch: 376416 Analysis Method: SM 5220D
QC Batch Method: SM 5220D Analysis Description: 5220D COD, Low Level
Associated Lab Samples: 92353467001, 92353467002, 92353467003, 92353467004
METHOD BLANK: 2085337 Matrix: Water
Associated Lab Samples: 92353467001, 92353467002, 92353467003, 92353467004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chemical Oxygen Demand mg/L ND 10.0 09/07/17 02:00
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
LABORATORY CONTROL SAMPLE: 2085338
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Chemical Oxygen Demand mg/L 75 75.0 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2085339 2085340
MS MSD
92353576001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
Chemical Oxygen Demand mg/L 33.0 75 75 73.0 72.0 53 52 90-110 1 M1
Results presented on this page are In the unite indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/11/2017 01:22 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 15

axAnalytical
www.pecews.cam
QUALIFIERS
Project: Stormwater
Pace Project No.: 92353467
DEFINITIONS
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RFD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenyla mine decomposes and cannot be separated from Diphenylamine using Method 8270, The result reported for
each analyte is a combined concentration.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-E Pace Analytical Services - Eden
ANALYTE QUALIFIERS
D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/11/2017 0112 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 15

,aceAnalytical
www.pe¢e1eb3.00m
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project. Stormwater
Pace Project No.: 92353467
Lab ID Sample ID QC Batch Method
92353467001
Outfall #1
SM 2540D
92353467002
#3-South Plant Pipe
SM 25400
92353467003
#4-SE Pond
SM 2540D
92353467004
#5-Consolidated Outfall
SM 2540D
92353467001
Outfall #1
EPA 1664B
92353467002
#3-South Plant Pipe
EPA 16648
92353467003
#4-SE Pond
EPA 1664B
92353467004
#5-Consolidated Outfall
EPA 1664B
92353467001
Outfall #1
SM 5220D
92353467002
#3-South Plant Pipe
SM 5220D
92353467003
#4-SE Pond
SM 5220D
92353467004
#S-Consolidated Outfall
SM 5220D
Date: 09/11/2017 01:22 PM
QC Batch
375948
375948
375948
375948
377090
377090
377090
377090
376416
376416
376416
376416
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Analytical Method
Analytical
Batch
Page 12 of 15

�f �]
Document Name:
Document Revised: August 4, 2017
ra
„/��a
Sample Condition Upon Recel t SGURj
Page 1 of 2
`////'
___;
Document No.:
Issuing Authority:
F-CAR-CS-033-Rev.04
Pace Quality Office
Laboratory receiving samples:
_._ Asheville _ Eden[_]
gNenwpjDi�___... Huntersyfie_❑. .___...Baleigh*...---McCh4nic viilt
Client Name:
WD# 923534fi7
Upon 11�-ailpt�
ProJect p:
Courier:
ed Ex ff ❑UPS ❑USPS Client
II
III
II
I II
II
eII
D Commercial
Pace ❑other:
92353467
Custody Seal Present?
��/�
[:]Yes di( -'Seals Intact? ❑Yes Vi No
�1
Dau/Initials Parson FxaminingCootcnts: `y/�
Packing Material;
[]Bubble Wrap ❑Bubble Sags ,None ❑ Other Biological Tissue F zen?
Thermometer.
%LR Gun ID:
',? y type Ice -.wet ❑Blue
❑Yes ❑No N/A
[]None
Correction Factor:
of
Cooler Temp Corrected (•C): er „3 _
Temp should be above freezing to 5'C
— o
❑Samples out of temp criteria, Samples on ice, cooling process
- (
hasbegun
USDA Regulated Sob (J�fN/A,
water sample)
old samplesV�I�pate in
IlYnc Arun
a quarantine zone within the United States: CA, NY, ar SC (check maps)?
Did samples orlglrate from a foreign source (internationally,
Indudlna Hawali and Puerto Rkal? f1Yr "te
Comments/Dismpan ;
Chain of Custody Present?
es No
N/A
3-
Samples Arrived within Hold Time?
Yes No
N A
2.
Short Hold Time Ana sis c7Z hr.)?
OYes N
N/A
3.
Rush Turn Around Time Requested?
Yea Na
N A
4.
Sufficient Volume?
YA& C114o
NIA
S.
Correct Containers Used?
-Pace Containers Used?
[]NO QN/A
9Yes MNo N/A
G.
Containers Intact?
ONo
N/A
7.
Dissolved analysis: Samples Field Filtered?
[]Yes No
N/A
B.
Sample Labels Match C00
-Includes Date/rtme/ID Ana is Matrix;
Enf-yes EiNo ❑N/A
✓ -
9.
Heads ace in VDA Vials (>5-6mm)?
OYU QN0
NIA
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
DYes QNp I
es ONo
INIA
N/A
11.
CLIENT NOTIFICATICW/RESOLUT1oN
0
Person Contacted: Dare/rime:
Comments/Sample Discrepancy:
Field Date Required? Oyes ONO
Lot 10 of split containers:
Project Manager SCURF Review: _ n f] . Date -
Project Manager Siff Review: r'G Date:�'-
Note: Whenever there Is a dttaepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR CertifiationOffim (Le•
Out of hold, Incorrect preservative, out ortemp, Incarrect containers)
Page 13 of 15

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Analytical Request Document
DOCUMENT Ali relevant fields must be COMPleteC accurately.
Section A r • Section 0
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Acquired Client Information: Required ProieCl Intunnrticiw
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DATE Signed:
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GRIFOLS
8368 U.S. 70 Bus. West
Clayton, NC 27520
David S. Graham
ESS III
Tel [phone]
Fax [phone]
Cell 919, 724.5979
[e-mail]
September 19, 2017
Division of Water Quality
Attn: DWQ Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
To whom it may concern:
Attached you will find the semi-annual analytical SDO monitoring report following a representative storm event for
the Grifols Therapeutics Clayton, NC facility. If you have any questions, please don't hesitate to contact me at
919-359-5473
Sincerely,
C
David S. Graham
ESS III

GIRI i OLV
8368 U.S. 70 Bus, West
Clayton, NC 27620
David S. Graham
ESS III
Tel [phone]
Fax [phone]
Cell 919.724.5979
[e-mail]
May 26, 2017
Division of Water Quality
Attn: DWQ Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
To whom it may concern:
Attached you will find the corrected semi-annual analytical SDO monitoring report following a representative storm
event for the Grifols Therapeutics Clayton, NC facility for Outfall #5 as well as the Pace Analytical results. If you
have any questions, please don't hesitate to contact me at 919-359-5473
WSincerelym
ESS III

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Thera eutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
42
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2017
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert #012
PLEASE SIGN ON THE REVERSE 4
OtitfalC
Na: -•
Date
�SampleCollected,
mo/dd/ r.
"40340' ::
'00556.
'00400�
'00530,
�Vieniical_Oxygen�Demand, `"
m
-Oilland{Grease,
m /L
pH;
Standard.units
TiitalSuspeifded'Solids
m 7L
iW1 chma-rlc-
-
120'
30'
.6:6=9.V'
400-
•5' 'L
05-05-17
22. r% 1'f
C5.0
6.7
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Qutfall
No._
`Date
Sample,Collected,.
mo/dd/ r.
00556
00530.-
'00400
"'UiI and -Grease?
m /L-
Total'Suspenii'ed�Soliiis;
rn /L.
p`H,.
Stanilafd:units.
New. Motor -Oil Wage;
AVera e-annual, aVmb,
'Benclimarlt•
r Y =
`i '30',
100:
RECEIVED
JUN 0 8 2017
CCN , 'Z/-'%L RLES
DWR SECTION
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 05-05-17 (first event sampled) Mail Original and one copy to:
Total Event Precipitation (inches): 1.30 Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Date (list each additional evenfsampled this reporting period, and rainfall amount) Raleigh, NTC 27699-1617
Total Event Precipitation (inches):
SWU-248-102107
Paae 1 of 2

Pace Analytical Services, LLC
acmnaly#lcal ° 6701 Conference Drive
Raleigh, NC 27so7
rvmvpacelabs.c m [phone]
ANALYTICAL RESULTS
Project: Stormwater
Pace Project No.: 92339734
Sample: 45-Consolidated
Lab ID: 92339734005 Collected: 05/05/17 13:30
Received: 05108/17 15:45 Maldx: Water
Parameters
Results Units
Report Limit DF
Prepared Analyzed CAS No. Qual
HEM, Oil and Grease
Analytical Method: EPA 16648
Off and Grease
ND mglL
5.0 1
05/12/17 07:05
2540D Total Suspended Solids
Analytical Method: SM 2540❑
Total Suspended Solids
14.6 mglL
2.7 1
05/10117 21:36
6220D GOD Low Level
Analytical Method: SM 5220D
Chemical Oxygen Demand
16.0 mglL
10.0 1
0511911710:25
REPORT Of LABORATORY ANALYSIS
This report shall not he reproduced, except In full,
Dale: 05119/2017 11:10AM wilhout the written consent of PacoAnalyliical Services, LLC. Page 8 of 116

s
r>
o�
oFwarFR RECEIVED
0�
p Y MAY 2 3 2017
CENTRAL FILES
Page 14: Stormwater Discharge Outfall (SDO) DWR SECTION
Qualitative Monitoring Report
Permit Na NCG060000 or Certificate of Coverage No.: N CGO60039
Facility Name: Grifols Therapeutics
County: Johnston Count Phone No, 919-359-5473
Inspector: David S. Graham
Date of Inspection: 515/2017
By this signatirr�, I ce*ikfljat this report is accurate and complete to the best of my knowledge:
(Signature of Permittee\orf Designee)
1.Outfall Description
Outfall No. 1 Structure (pipe, ditch, etc.) Stream
Receiving Stream: tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _Clear with alight brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 ® 4 5 6 7 8 9 10
Page 1
SW U-242-020705

5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
O 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where 1 ' no solids and 10 is extremely muddy:
1 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes G
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes No
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? Yd
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes G
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SWU-242-020705

GENERAL PERMIT NO. NCC060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A. Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2017
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NCIWW cert #012
PLEASE SIGN ON THE REVERSE 4
Outfalt
No.
Date
Sample Collected,
mo/dd/yr
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
m /L
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
1
05-05-17
<10.0
<5.0
6.6
6.7
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier I or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample Collected,
mo/dd/ yr
00556
00530
00400
Oil and Crease,
m IL
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 05-05-17 (first event sampled)
Total Event Precipitation (inches): 1.30
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S WU-248-102107
Page 1 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imArnent for knowing violations."
(Signature of Permittee)
20�
(Date)
S WU-248-102107
Page 2 of 2

Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit Nc NCG060000 or Certificate of Coverage No.: N CG060039
Facility Name: Grifols Therapeutics
County: Johnston County Phone No.919-359-5473
Inspector: David S. Graham
Date of Inspection: 5/512017
By this signaturb�j c f1lat this report is accurate and complete to the best of my knowledge:
(Signature of
r Designee)
1.Outfall Description
Outfall No. 2 Structure (pipe, ditch, etc.) ditch exiting existing and
Receiving Stream: tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _Clear with a light brown tint
3.Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.)-. None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 V 3 4 5 6 7 8 9 10
Page 1
SWU-242-020705

5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids..
O 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where 1 's no solids and 10 is extremely muddy:
16 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes G
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? YesG)
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? Ye No
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes G
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SW U-242-020705

7
GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analvtical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2017
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert ##012
PLEASE SIGN ON THE REVERSE 4
O utfa l l
No.
Date
Sample Collected,
mo/dd/ yr
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
m /L
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
2
05-05-17
18.0
<5.0
6.4
51.8
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity onitoring Re uirements
Outfail
No.
Date
Sample Collected,
mo/dd/vr
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 05-05-17 (first event sampled)
Total Event Precipitation (inches): 1.30
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S W U-248-102107
Page 1 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and comp etc. I am aware that there are significant penalties for submitting false information, including
the possibility of fines an4jiTtNisonment for knowing violations."
(Signature of Permittee)
4 10/ �-
(Date)
S WU-248- l 02107
Page 2 of 2

o�0F W A rFRQG
Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit Na NCGO60000 or Certificate of Coverage No.: N CG060039
Facility Name: Grifols Therapeutics
County: Johnston County Phone No.919-359-5473
Inspector: David S. Graham
Date of Inspection: 5/5/2017
8y this signature;11 cehWat this report is accurate and complete to the best of my knowledge:
(Signature of Permi
Designee)
1.Outfall Description
Outfall No 3 Structure (pipe, ditch, etc.) Pipe
Receiving Stream: tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _ light brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 ® 4 5 6 7 8 9 10
Page 1
SWU-242-020705

5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
0 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where 1 ' no solids and 10 is extremely muddy:
1 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes G
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes No
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? YEN
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes G
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SWU-242-020705

GENERAL PERMIT NO. NCC060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2017
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert 9012
PLEASE SIGN ON THE REVERSE 4
Outfall
No.
Date
Sample Collected,
mo/dd/ r
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
m /L
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
3
05-05-17
20.0
<5.0
6.8
47.0
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfali
No.
Date
Sample Collected,
mo/dd/ r
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
Average annual allmo
Benchmark
-
30
100
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier i or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 05-05-17 (first event sampled)
Total Event Precipitation (inches): 1.30
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to.,
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S W U-248-102107
Page 1 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
rtify, under penalty of later, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am a are that there are significant penalties for submitting false information, including
the possibility of fines and impriskpnt for knowing violations."
(Signature of Permittee)
h, i
Ul-
(Date)
S W U-24 8-102107
Page 2 of 2

Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit Nc NCGO60000 or Certificate of Coverage No.: N CG060039
Facility Name: Grifols Therapeutics
County: Johnston County _ Phone No.919-359-5473
Inspector: David S. Graham
Date of Inspection: 51512017
By this signature, I certify tho this report is accurate and complete to the best of my knowledge:
(Signature of Perm
ignee)
1.Outfall Description
Outfall No. 4 Structure (pipe, ditch, etc.) Pipe from pond
Receiving Stream: tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _ light brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 © 4 5 6 7 8 9 10
Page 1
SW U-242-020705

5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
0 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where 1 ' no solids and 10 is extremely muddy:
1 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes No
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes No
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? YEI
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes G
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SW U-242-020705

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analvtical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2017
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert #012
PLEASE SIGN ON THE REVERSE 4
Outfall
No.
Date
Sample Collected,
mo/dd/yr
00340
00556
00400
00530
Chemical Oxygen Demand,
m IL
Oil and Grease,
m /L
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
4
05-05-17
22.0
<5.0
6.6
8.5
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes X no
(if yes, complete Part 13)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample Collected,
mo/dd/vr
00556
00530
00400
Oil and Grease,
mg/L
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
Note: Ifyou report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 05-05-17 (First event sampled)
Total Event Precipitation (inches): 1.30
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S WU-248-102107
Page I of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and compl to I am aware that there are significant penalties for submitting false information, including
the possibility of fines an�,d'isonment for knowing violations."
(Signature of Permittee
S WU-248-102107
Page 2 of 2

Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit Nc NCG060000 or Certificate of Coverage No.: N CG060039
Facility Name: Grifols Therapeutics
County: Johnston County �- Phone No. 919-359-5473
Inspector: David S. Graham
Date of Inspection: 5/512017
By this signature, I cerfttoaj this report is accurate and complete to the best of my knowledge:
(Signature of
nee)
1.0utfall Description
Outfall No. 5 Structure (pipe, ditch, etc.) creek
Receiving Stream: tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _ clear with a light brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 © 4 5 6 7 8 9 10
Page 1
SW U-242-020705

5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
O 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where 1 ' no solids and 10 is extremely muddy:
1 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes G
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes No
9. Deposition at Outfall
is there deposition of material (sediment, etc.) at or immediately below the outfall? YEG
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes G
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
R TAMUMMiKiWiR

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analvtical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2017
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert #012
PLEASE SIGN ON THE REVERSE 4
Outfail
No.
Date -
Sample Collected,
mo/dd/yr
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
m /L
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
5
05-05-17
22.0
<5.0
6.7
8.5
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activitv Monitoring Requirements
O u tfa l l
No.
Date
Sample Collected,
mo/dd/vr
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
Note: Ifyou report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier l or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 05-05-17 (first event sampled)
Total Event Precipitation (inches): 1.30
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S W U-24 8-102 l 07
Page 1 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I aware that there are significant penalties for submitting false information, including
the possibility of fines and imhpr on ent for knowing violations."
(Signature of Permittee)
0.
/zla
(Date)
S W U-248-102107
Page 2 of 2

(�.Iane.MalXicals
Kww.pacelabaaom
May 19, 2017
Sam Vedder
Grifols Therapeutics, Inc.
8368 US 70 West
Clayton, NC 27520
RE: Project: Stormwater
Pace Project No.: 92339734
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Dear Sam Vedder: -
Enclosed are the analytical results for sample(s) received by the laboratory on May 08, 2017. The
results relate only to the samples included in this report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: David Graham, Grifols Therapeutics, Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 1 of 16

�.IacbAnalj&al
wwwpamlabacom
Project: Stormwater
Pace Project No.: 92339734
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
FloridalNELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
FloridalNELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Page 2 of 16

�.IaneMalyticalo
www.pBcelabs.com
Project: Stormwater
Pace Project No.: 92339734
Lab ID Sample 1D
92339734001 Outfall #1
92339734002 #2-Basin #2
92339734003 #3-S.E.Pipe
92339734004 #4-S.E.Pond
92339734005 #5-Consolidated
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
SAMPLE ANALYTE COUNT
Method
Analysts
Analytes
Reported
Laboratory
EPA 1664B
JMS
1
PASI-C
SM 2540D
MDW
1
PASI-A
SM 5220D
EWS
1
PASI-A
EPA 1664B
JMS
1
PASI-C
SM 2540D
MDW
1
PASI-A
SM 5220D
EWS
1
PASI-A
EPA 1664B
JMS
1
PASI-C
SM 2540D
MDW
1
PASI-A
SM 5220D
EWS
1
PASI-A
EPA 1664E
JMS
1
PASI-C
SM 2540D
MDW
1
PASI-A
SM 5220D
EWS
1
PASI-A
EPA 1664B
JMS
1
PASI-C
SM 2540D
MDW
1
PASI-A
SM 5220❑
EWS
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 16

aceAnalytical s
www.pac&bimn
ANALYTICAL RESULTS
Pace Analytical Services, LLC
6701 Conference Drive
Raicigh, NC 27607
[phone]
Project: Stormwater
Pace Project No.: 92339734
Sample: Outfall #1
Lab ID: 92339734001 Collected: 05105117 13:55
Received: 05/08/17 15:45 Matrix: Water
Parameters
Results Units
Report Limit DF
Prepared Analyzed CAS No. Qual
HEM, Oil and Grease
Analytical Method: EPA 1664B
Oil and Grease
ND mg/L
5.0 1
05/12/17 07:04
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
6.7 mg/L
2.6 1
05/10/17 21:34
5220D COD Low Level
Analytical Method: SM 5220D
Chemical Oxygen Demand
ND mg/L
10.0 1
05/19/17 10:25
REPORT OF LABORATORY ANALYSIS
This report shaft not be reproduced, except in full,
Date: 05/19/2017 11:10 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 16

Pace Analytical Services, LLC
lanemalytical" 6701 Conference NC Drive
Raleigh, NC 27607
w»wpecehftcom
[phone]
ANALYTICAL RESULTS
Project: Stormwater
Pace Project No.: 92339734
Sample: #2-Basin #2
Parameters
Lab ID: 92339734002 Collected: 05105117 13:40
Results Units Report Limit OF
Received: 05/08/17 15:45 Matrix: Water
Prepared Analyzed CAS No. Qual
HEM, Oil and Grease
Analytical Method: EPA 1664B
Oil and Grease
ND mg/L
5.0 1
05/12/17 07:04
2640D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
51.8 mg/L
11.4 1
05/10/17 21:35
5220D COD Low Level
Analytical Method: SM 5220D
Chemical Oxygen Demand
18.0 mg1L
10.0 1
05/19/17 10:25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/19/2017 11:10 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 16

Pace Analytical Services, LLC
aceAnalytical 6741 Conference Drive
Raleigh, NC 27607
wwwpacelabacom (919)834A 984
ANALYTICAL RESULTS
Project: Slormwater
Pace Project No.: 92339734
Sample: #3-S.E. Pipe
Parameters
Lab 1D: 92339734003 Collected: 05/05/17 14:20
Results Units Report Limit DF
Received: 05/08117 15:45 Matrix: Water
Prepared Analyzed CAS No. Qual
HEM, Oil and Grease
Analytical Method: EPA 1664E
Oil and Grease
ND mgll-
5.0 1
(15112117 07:04
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
47.0 mg1L
8.3 1
05/10/17 21:35
5220D COD Low Level
Analytical Method: SM 5220D
Chemical Oxygen Demand
20.0 mg1L
10.0 1
05/19/17 10:25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05119/2017 11:10 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 16

lacieMalytical
Pace Analytical Services, LLC
®
6701 Conference 07
Raleigh, NC 276750
wwwpacefabs.mm
[phone]
ANALYTICAL RESULTS
Project: Stormwater
Pace Project No.: 92339734
Sample: #4-S.E. Pond
Parameters
Lab ID7 92339734004 Collected: 05/05/17 14:15
Results Units Report Limit OF
Received: 05/08/17 15:45 Matrix: Water
Prepared Analyzed CAS No. Qual
HEM, Oil and Grease
Analytical Method: EPA 1664B
Oil and Grease
NO mg1L
5.0 1
05/12/17 07:05
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
8.5 mglL
3.1 1
05/10/17 21.35
5220D COD Low Level
Analytical Method: SM 5220D
Chemical Oxygen Demand
22.0 mglL
10.0 1
05/19/17 10:25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/19/2017 11:10 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 16

�.IaeAnalytical.
www.peaa'ebs.com
ANALYTICAL RESULTS
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Project: Stormwater
Pace Project No.: 92339734
Sample: #5-Consolidated
Lab ID: 92339734005 Collected:
05/05117 13:30
Received: 05/08/17 15:45 Matrix: Water
Parameters
Results Units
Report Limit DF
Prepared Analyzed CAS No. Qual
HEM, Oil and Grease
Analytical Method: EPA 1664B
Oil and Grease
ND mg1L
5.0 1
05112/17 07:05
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
14.6 mg/L
2.7 1
05/10/17 21:36
5220D COD Low Level
Analytical Method: SM 5220D
Chemical Oxygen Demand
15.0 mg1L
10.0 1
05/19/17 10:25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/19/2017 11:10 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 16

admnalXical
wwwpacelsbs wm
QUALITY CONTROL DATA
Project: Stormwater
Pace Project No.: 92339734
QC Batch: 360253 Analysis Method: EPA 1664B
QC Batch Method: EPA 1664B Analysis Description: 1664 HEM, Oil and Grease
Associated Lab Samples. 92339734001,92339734002,92339734003,92339734004,92339734005
METHOD BLANK: 1998035 Matrix: Water
Associated Lab Samples: 92339734001, 92339734002, 92339734003, 92339734004, 92339734005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg1L ND 5.0 D5112I17 07:03
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
LABORATORY CONTROL SAMPLE:
1998036
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits
Qualifiers
Oil and Grease
mglL
40 37.5
94
78-114
MATRIX SPIKE SAMPLE:
1998037
92339385001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
% Rec
Limits Qualifiers
Oil and Grease
mg1L
ND 40
37.7
93
78-114
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in fuii,
Date: 05119/2017 11:10 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 16

acmnalytical
WW.pacsfabs.carn
QUALITY CONTROL DATA
Project: Stormwater
Pace Project No.: 92339734
QC Batch: 360043 Analysis Method: SM 2540D
QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids
Associated Lab Samples: 92339734001, 92339734002, 92339734003, 92339734004, 92339734005
METHOD BLANK: 1996751 Matrix: Water
Associated Lab Samples: 92339734001, 92339734002, 92339734003, 92339734004, 92339734005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Suspended Solids mg/L ND 2.5 0511OY17 21:26
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
LABORATORY CONTROL SAMPLE:
1996752
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
Total Suspended Solids
mg1L
250 230 92
90-110
SAMPLE DUPLICATE: 1996753
92339649002 Dup
Parameter
Units
Result Result RPD
Qualifiers
Total Suspended Solids
mg1L
507 480
5
SAMPLE DUPLICATE: 1996754
92339564001 Dup
Parameter Units Result Result RPD Qualifiers
Total Suspended Solids mg1L 18.6 19.4 4
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result,
REPORT OF LABORATORY ANALYSIS
This report shall not he reproduced, except in full,
Date: 05/19/2017 11:10 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 16

l
eAnalytical
www.pBcofabs.com
QUALITY CONTROL DATA
Project: Stormwater
Pace Project No.: 92339734
QC Batch: 361017 Analysis Method: SM 5220D
QC Batch Method: SM 5220D Analysis Description: 5220D COD, Low Level
Associated Lab Samples. 92339734001,92339734002,92339734003,92339734004,92339734005
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, IVC 27607
[phone]
METHOD BLANK: 2002234
Matrix: Water
Associated Lab Samples: 92339734001, 92339734002, 92339734003, 92339734004, 92339734005
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Chemical Oxygen Demand
mg/L
ND 10.0
05/19/17 10:25
LABORATORY CONTROL SAMPLE:
2002235
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Chemical Oxygen Demand
mg/L
75 73.0
97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2002236 2002237
MS MSD
92339734001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chemical Oxygen Demand mg1L ND 75 75 89.0 86.0 107 103 90-110 3
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/19/2017 11:10 AM without the written consent of Pace Analytical Services, LLC.
Page 11 of 16

aceAnalytrcal.
www.pacelab&=n
QUALIFIERS
Project: Stormwater
Pace Project No.: 92339734
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit,
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL- Practical Quantitation Limit.
RL- Reporting Limit.
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
❑UP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
LABORATORIES
PASI-A Pace Analytical Services -Asheville
PAS!-C Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/1912017 11:10 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 16

kmnalytical
wwwpacalaba.aorn
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Stormwater
Pace Project No.: 92339734
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
92339734001
Outfall #1
EPA 1664E
360253
92339734002
#2-Basin #2
EPA1664B
360253
92339734003
#3-S.E.Pipe
EPA16648
360253
92339734004
#4-S.E.Pond
EPA1664B
360253
92339734005
#5-Consolidated
EPA 1664E
360253
92339734001
Outfall #1
SM 2540D
360043
92339734002
#2-Basin #2
SM 2540D
360043
92339734003
#3-S.E. Pipe
SM 2540D
360043
92339734004
#4-S.E. Pond
SM 2540D
360043
92339734005
#5-Consolidated
SM 2540D
360043
92339734001
Outfall #1
SM 5220D
361017
92339734002
#2-Basin #2
SM 5220D
361017
92339734003
#3-S.E.Pipe
SM 5220D
361017
92339734004
#4-S.E.Pond
SM 5220D
361017
92339734005
#5-Consolidated
SM 5220D
361017
Date: 05/19/2017 11:10 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical
Batch
Page 13 of 16

LlULU IIIenL Ndrne: ear r ecn spec. UOcument Kevlseo: Sept. 21, 201b
/aceAW ,0'• Sample Condition Upon Receipt(SCUR) Page 1 of 2
Document No.: Issuing Authority:
F-CAR-QA-003-Rev.02 Pace Quality Office
Laboratory receiving samples:
Asheville ❑ Edenn Greenwood
Client Name:
Huntersville ❑ Raleigh® Mechanicsville❑
Project; W0W 92339734
❑ Commercial Pace ❑UPS Oother. ❑Client 11111111111111111111111
92339734
Custody Seal Present? ❑Yes��No ;u-b-ble
s Into ❑Yes �a­
/ j��
Date/InlUais Person Examining Contents;
Packing Material: []Bubble Wrap Bags ❑None Qother:
Thermometer: Wet ❑Blue ❑None 05amples on ice, cooling process has begun
® IR Gun ID; W IS-3492 _ Type of ice:
Correction factor: Add a. Cooler emp Corrected ('C): Biological Tissue Frozen? ❑Yes ❑No /A
Temp should be above free
USDA Regulated SDI! /A; water sample)
Did samples origi n a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (intern
[:)Yesincluding Hawaii and Puerto Rico)? ❑Yes No
Comma nts/Discre a
Chain of Custody Present?
❑
1.
Samples Arrived within Hold Time?
2.
Short Hold Time Analysis J02 hr.)?
3.
Rush Turn Around Time Requested?
❑
4.
Sufficient Volume?
5.
Correct Containers Used?
-Pace Containers Used?
6.
Containers Intact?
Er
11
Samples Field Filtered?
g. Note If sediment is visible in the dissolved container
Sample Labels Match COC?
-Includes Date/Time/ID/Analysis
�
9.
Heads ace In VOA Vials (>5-Gmm)?
Yes
No N
10,
Trip Blank Present?
Trip Blank Custody Seals Present?
Yes
❑
Yes
No N
❑
No N
11.
CLIENT NOTIFICATION/RESOLUTION
Person Contacted:
Comments/Sample Discrepancy:
1 Field Data Required? UYes UNo
Date/Time:
Project Manager SCURF
Review: Date: 1
Project Manager SRF „ !
Review: Date:
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le.
Out of hold, Incorrect preservative, out of temp, incorrect containers)
Page 14 of 16

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9P1U-1 Ster Plastic Unpreserved (N/A)
BP3S-2S0 mL Plastic H2SO4(pH <2) (CJ.)
BP3N-250 mL plastic HNO3 (pH < 21
9P3Z-250 mL Plastic ZN Acetate & NaOH (>9)
BP3C-250 mL Plastic NaOH (pH!;, t2) (Cl-)
WGFU-Wide-mouthed Glass jar Unpreserved
AMU-t liter Amber Unpreserved (NIA) (Cl-)
AG11-1-1 liter Amber HCl (pH < 2)
AGM-250 mL Amber Unpreserved (N/A) (Cl-)
AG15-1 Ater Amber H2SO4 (pH < 2)
AG3S-250 mL Amber H2.504 (pH < 2)
zzzzzzzzzzzAGSA(
OG3A)-250 m L Amber N H4Ct (N/A)(Ct-)
OG9H-40 m L VOA HCI (NIA)
VG9T-40 mL VOA N32S203 (NIA)
VG9U-40 mLVOA Unp (N/A)
OW-40 mL VOA H31`04 (NIA)
VOAK (6 vtols per kit)-5035 kit (N/A)
V/GK (3 vials per ldt)-VPH/Gas kit (N/A)
SPST 125 mL Sterile Plastic (N/A= lap)
SPIT-250 mL Sterile Plastlt (N/A — tab)
MA-250 mL Plastic (NH2)Z504 (9.3-9.7)
Cubitainer
VSGU-20MIL Scintillation vials (N/A)
GN
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CHAIN -OF -CUSTODY / Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section A socuon B Section C
Required Client Information: Required Project Information: Invoice tnfomation: Pa e • 1 Of t
R To: David Graham Attention
Company'. Grifots Therapeutics Report
Address: 9368 US 10 West Copy To: Company Nam:
Clayton. NC 27520
Address:
aLtd::- _ :u%Rc ulalo A enc r _
Email:
Purchase Order #:
Pace Quoin:
Phone: Fai[
Project Name: TCLP Chromku n
Pace Project Manager nkale.pasiorouvsld petala6s.mm,
-- - _. -:LSWe r Location:-_
Requested Due Date:
Project #:
Pace Prone P. qaw
NC
?"�..`
Re
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-N =ase � - _ l:FS ��3.-x�' •�..�re _:._f�• -:3. ..� r., -i • r � x �._: w:_k'a.+{,3� -
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SIGNATURE of SAMPLER:
AV
DATE Signed:
1 1 7
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Cn

GRIFOLS
January 5, 2017
Central Files
North Carolina Department of
Environmental Quality
Division of Water Quality
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Subject: Additional Monitoring of Pollutants
Permit No. NCG060039
Grifols Therapeutics
Clayton, North Carolina
Dear Sir/Ma'am:
Grifols
8368 US 70 Bus. Hwy W
Clayton, NC 27520
USA
www.gdfols corn
& Jyc-t ii
Jq N 1 '��
8ctz
�C���F
710N S
In accordance with Part III, Section E, Paragraph 1, Grifols is submitting this additional test result and Tier One
record of action taken as a result of finding a higher than expected value for COD on November 14, 2016.
Based on information and belief formed after reasonable inquiry, the statement and information in the document
are true, accurate, and complete.
'Sincerely,
Sergi Roura
President, Grifols Therapeutics Inc.
Attachments: 1. Action taken to comply with Tier One requirements.
2. Qualitative Monitoring Report
3. Lab results of testing.

Tier One Requirements
If: The first valid sampling results are above a benchmark value, or outside of the benchmark range, for any
parameter at any outfall;
Then: The permittee shall:
1. Conduct a stormwater management inspection of the facility within two weeks of receiving sampling
results.
The ditch upstream of Outfall 3 was inspected on the same day as the elevated COD was reported
(results received 11/28/16 for samples taken on 11/15/16 where the COD was measured as 126 mg/L).
The only suspect area observed was where the storm sewer from B300 enters the ditch near the pipe
bridge. The water in the ditch in that area had a septic smell. A sample was taken and tested for COD in-
house, and although the results were elevated, they were below the limits for COD. A sample taken at
the same time from Outfall 3 also was well below the limits for COD. A sample taken at ditch on 12/1/16
had a COD of <10 mg/L. Another sample taken on 12/5/16 at Outfall 3 also had a COD of <10 mg/L.
On 11/29/16 a video camera was used to inspect the storm sewer that flows from B300 to the ditch.
Nothing was observed that could be correlated with an elevated COD Outfall 3.
2. Identify and evaluate possible causes of the benchmark value exceedance.
The weeks preceding the 11/15/16 sample were very dry. On 11/15/16 0.22 inches of rain was measured
at the site. The ditch that leads to Outfall 3 usually has standing water near the pipe bridge area, even
during times of drought, because HVAC condensate on the roof of B300 drains to the stormwater piping
that empties into the ditch. However, because of the lack of rainfall, this water probably became very
stagnant. The volume of rain that fell on 11/15/16 was probably only enough to move the stagnant
water to the outfall, without thoroughly flushing it through the system.
3. Identify potential and select the specific: source controls, operational controls, or physical improvements
to reduce concentrations of the parameters of concern, and/or to bring concentrations within the
benchmark range.
Grifols will continue to monitor the COD of stormwater at the ditch on a periodic basis. If elevated COD is
observed, further investigation to determine where the source enters the storm sewer will be conducted.
4. Implement the selected actions within two months of the inspection.
Resampling and camera investigation were conducted during the week that the elevated COD was
reported. Test results of the resampling were within the acceptable range, and the video did not reveal
any anomalies.

ft
5. Record each instance of a Tier One response in the SPPP. Include the date and value of the benchmark
exceedance, the inspection date, the personnel conducting the inspection, the selected actions, and the
date the selected actions were implemented.
The SPPP is included in the site's Integrated Contigency Plan (ICP). The ICP will be revised during January
2017 to include this issue, as well as other releases that occurred in 2016.

GENERAL PERMIT NO. NC6060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analvtical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2016
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/W W cert #012
PLEASE SIGN ON THE REVERSE 4
Outfall
No.
Date
Sample Collected,
mo/dd/vr
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
m /L
pH,
Standard units
Total Suspended Solids,
m IL
Benchmark
-
120
30
6.0 — 9.0
100
3
11-14-16
126
<5.0
6.7
3.3
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
RECEiVED
Outfall
No.
Date
Sample Collected,
mo/dd/vr
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage'j�
Average annual al
Benchmark
-
30
100
6.0 — 9.0
-
Nz7201?
linort r��F IFILES
]`Tote: if you report a sampled value in excess of the benchmark value.. or outside the benchmark range for pH. you must implement Tier l or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date (first event sampled) Mail Original and one copy to:
Total Event Precipitation (inches):.22 Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Date (list each additional event sampled this reporting period, and rainfall amount) Raleigh, NC 27699-1617
Total Event Precipitation (inches):
S WU-248-102107
Page 1 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee)
1-5--17
(Date)
S WU-248- l 02107
Page 2 of 2

aceAnalWical o
www.Paefeb1com
December 15, 2016
Sam Vedder
Grifols Therapeutics, Inc.
8368 US 70 West
Clayton, NC 27520
RE: Project: Stormwater
Pace Project No.: 92322024
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Nc-e-v�o(D39
Red
UEC 2 9�i6
CENTRAL FILES
DWR SECTION
Dear Sam Vedder:
Enclosed are the analytical results for sample(s) received by the laboratory on December 06, 2016.
The results relate only to the samples included in this report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
1 � „
Nicole Gasiorowski
[e-mail]
Project Manager
Enclosures
cc: David Graham, Grifols Therapeutics, Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical services, LLC.
Page 1 of 15

aceAnalytical
I..paceldumn
CERTIFICATIONS
Project. Stormwater
Pace Project No.; 92322024
Charlotte Certification lDs
9800 Kincey Ave. Ste 100, Huntersville, INC 28078 South Carolina Certification #: 99006001
North Carolina Drinking Water Certification #: 37706 Florida/NELAP Certification #: E87627
North Carolina Field Services Certification #: 5342 Kentucky UST Certification #: 84
North Carolina Wastewater Certification #: 12 VirginiaNELAP Certification #: 460221
Asheville Certification iDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #; E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
Eden Certification IDs
205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Wastewater Certification #: 633
North Carolina Drinking Water Certification #: 37738 Virginia/VELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Page 2 of 15

aceAnalytr'caI
wwwpaceh a.00m
Project: Stormwater
Pace Projecl No.: 92322024
Lab ID Sample ID
92322024001 Outfall #1
92322024002 #3 - South Plant Pipe
92322024003 #4 - SE Pond
92322024004 5 - Consolidated Outfall
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
SAMPLE ANALYTE COUNT
Method
Analysts
Analytes
Reported
Laboratory
SM 2540D
DWJ
1
PASI-E
EPA 1664B
JMS
1
PASI-C
SM 5220D
EWS
1
PASI-A
SM 2540D
DWJ
1
PASI-E
EPA 1664B
JMS
1
PASI-C
SM 5220D
EWS
1
PASI-A
SM 2540D
DWJ
1
PASI-E
EPA 1664B
JMS
1
PASI-C
SM 5220D
EWS
1
PASI-A
SM 2540D
DWJ
1
PASI-E
EPA 1664B
JMS
1
PASI-C
SM 5220D
EWS
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 15

Pace Analytical Services, LLC
aceAnalytical 0 6701 Conference Drive
Raleigh, NC 27607
wwwpscelaUCOM [phone]
ANALYTICAL RESULTS
Project. Stormwater
Pace Project No.: 92322024
Sample: Oulfall #1
Parameters
Lab ID: 92322024001 Collected: 12/05/16 15:20
Results Units Report Limit DF
Received: 12/06/16 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
6.9 mg1L
2.5 1
12/07/16 14:07
HEM, Oil and Grease
Analytical Method: EPA 1664B
Oil and Grease
ND mglL
5.0 1
12/13/16 07:45
5220D COD Low Level
Analytical Method: SM 52200
Chemical Oxygen Demand
ND mg1L
10.0 1
12/15/16 11:54
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
Date: 12115/2016 03:00 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 15

Pace Analytical Services, LLC
e
aceAnalytical
6701 Conference give
Raleigh, NC 27607
www.patelab&ccm
[phone]
ANALYTICAL RESULTS
Project: Stormwater
Pace Project No.: 92322024
Sample: #3 - South Plant Pipe
Lab lD: 92322024002 Collected: 12/05/16 14:15
Received: 12/06/16 11:00 Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
ND mg/L 2.5 1
12/07/16 14:07
HEM, Oil and Grease
Analytical Method: EPA 1664B
Ol and Grease
ND mg/L 5.0 1
12/13/16 07:46
5220D COD Low Level
Analytical Method: SM 5220D
Chemical Oxygen Demand
ND mg1L 10.0 1
12/15/16 11:54
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/15/2016 03:00 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 15

, Pace Analytical Services, LLC
n 670 Conference
RaleighNG 277607
WWW..pacelaAsoom [phone]
ANALYTICAL RESULTS
Project. Stormwater
Pace Project No.: 92322024
Sample: #4 - SE Pond
Parameters
Lab ID: 92322024003 Collecled: 12/05/16 14:05
Results Units Report Limit DF
Received: 12/06/16 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
6.4 mg/L
3.1 1
12/07/16 14:08
HEM, Oil and Grease
Analytical Method: EPA 1664B
Oil and Grease
ND mg/L
5.0 1
12/13/16 07:46
5220D COD Low Level
Analytical Method: SM 5220D
Chemical Oxygen Demand
11.0 mg/L
10.0 1
12/15/16 11:54
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/15/2016 03:00 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 15

Pace Analytical Services, LLC
lacieAnalXical 6701 Conference give
Raleigh, NC 27607
WWW'P&C Ufa MMM
[phone]
ANALYTICAL RESULTS
Project: Stormwater
Pace Project No.: 92322024
Sample: 5 - Consolidated Outfall
Lab ID: 92322024004 Collected: 12/05/16 14:55
Received: 12/06/16 11:00 Matrix: Water
Parameters
Results Units
Report Limit DF
Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
2.8 mg/L
2.5 1
12/07/16 14:08
HEM, Oil and Grease
Analytical Method: EPA 1664B
Oil and Grease
ND mg1L
5.D 1
12/13/16 07:47
5220D COD Low Level
Analytical Method: SM 5220D
Chemical Oxygen Demand
ND mg/L
10.0 1
12/15/16 11:54
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/15/2016 03:00 PM without the written consent of Pace Analytical Services, LLC- Page 7 of 15

aceAnalytical
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QUALITY CONTROL DATA
Project: Stormwater
Pace Project No.: 92322024
QC Batch: 339774 Analysis Method: SM 2540D
QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids
Associated Lab Samples: 92322024001, 92322024002, 92322024003, 92322024004
METHOD BLANK: 1884342 Matrix: Water
Associated Lab Samples: 92322024001, 92322024002, 92322024003, 92322024004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Suspended Solids mg/L ND 2.5 12/07/16 14:05
LABORATORY CONTROL SAMPLE:
1884343
Spike
Parameter
Units
Cone.
Total Suspended Solids
mg/L
250
SAMPLE DUPLICATE: 1884344
92322030001
Parameter
Units
Result
Total Suspended Solids
mg/L
166
LCS LCS
Result % Rec
246 98
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
% Rec
Limits Qualifiers
90-110
Dup
Result RPD Qualifiers
209 23 D6
SAMPLE DUPLICATE: 1884345
92322107002 Dup
Parameter Units Result Result
Total Suspended Solids mg1L 10.8 21.3
RPD Qualifiers
66 D6
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 1211512016 03:00 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 15

(� acMnalytrcal
tt W..pecefebatorn
QUALITY CONTROL DATA
Project: Stormwater
Pace Project No.: 92322024
QC Batch: 340543 Analysis Method: EPA 1664E
QC Batch Method: EPA 1664B Analysis Description: 1664 HEM, Oil and Grease
Associated Lab Samples: 92322024001, 92322024002, 92322024003, 92322024004
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
METHOD BLANK: 1888686
Matrix:
Water
Associated Lab Samples: 92322024001, 92322024002, 92322024003, 92322024004
Blank
Reporting
Parameter
Units
Result
Limit Analyzed Qualifiers
Oil and Grease
mg1L
ND
5.0 12113/16 07:41
LABORATORY CONTROL SAMPLE:
1888687
Spike
LCS LCS % Rec
Parameter
Units
Cone.
Result % Rec Limits Qualifiers
Oil and Grease
mg1L
40
36.8 92 78-114
MATRIX SPIKE SAMPLE: 1888688
92321611002 Spike MS MS % Rec
Parameter Units Result Cone. Result % Rec Limits Qualifiers
Oil and Grease mg/L ND 40 36.5 90 78-114
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/15/2016 03:00 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 15

aceAnalytical
www.paaelah&oom
QUALITY CONTROL DATA
Project: Stormwater
Pace Project No.: 92322024
QC Batch: 340482 Analysis Method: SM 5220D
QC Batch Method: SM 5220D Analysis Description: 5220D COD, Low Level
Associated Lab Samples: 92322024001, 92322024002, 92322024003, 92322024004
METHOD BLANK: 1888471 Matrix: Water
Associated Lab Samples: 92322024001, 92322024002, 92322024003, 92322024004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chemical Oxygen Demand mg/L ND 10.0 12115/16 11:54
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
LABORATORY CONTROL SAMPLE: 1888472
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chemical Oxygen Demand mg/L 75 73.0 97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1888473 1888474
MS MSD
92322024001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chemical Oxygen Demand mg/L ND 75 75 73.0 73.0 97 97 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1888475 1888476
MS MSD
92322682001 Spike Spike MS MSD MS MSD %9 Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chemical Oxygen Demand mg/L 33.0 75 75 107 107 99 99 90-110 0
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
❑ate: 12/1512016 03:00 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 15

aceAnalytical
www.pscelsrx wm
QUALIFIERS
Project: Stormwater
Pace Project No.: 92322024
DEFINITIONS
Pace Analytical Services, LLC
6701 conference Drive
Raleigh, NC 27607
[phone]
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL- Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
LABORATORIES
PASI-A Pace Analytical Services -Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-E Pace Analytical Services - Eden
ANALYTE QUALIFIERS
D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/15/2016 03:00 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 15

aceAnalytrcal e
WWW'pacefah&=M
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project. Stormwater
Pace Project No.: 92322024
Lab ID Sample ID QC Batch Method QC Batch
92322024001
Outfall #1
SM 2540D
339774
92322024002
#3 - South Plant Pipe
SM 2540D
339774
92322024003
#4 - SE Pond
SM 2540D
339774
92322024004
5 - Consolidated Outfall
SM 2540D
339774
92322024001
Outfall #1
EPA 1664B
340543
92322024002
#3 - South Plant Pipe
EPA 16648
340543
92322024003
#4-SE Pond
EPA1664B
340543
92322024004
5 - Consolidated Outfall
EPA 1654B
340543
92322024001
Outfall #1
SM 5220D
340482
92322024002
#3 - South Plant Pipe
SM 5220D
340482
92322024003
#4 - SE Pond
SM 5220D
340482
92322024004
5 - Consolidated Outfall
SM 5220D
340482
Date: 12115/2016 03:00 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Analytical Method
Analytical
Batch
Page 12 of 15

j ./.gace,Malytical'
Uboratory receiving samples:
Asheville ❑ EdenEj
mrialmerrt vev,sea: -x!pt. el, euiQ
dition U on Page 1 of 2
Document No.: Issuing Autharlty:
AR•C"33-Rev.01 Pace Qua lity office'
Greenwood
,W.
ClientName: G�rare W0#� : 92322024
Laurier Face❑UPS ❑UPS ❑Cllent Commercial. ❑0 er. III
I 923ZZ
024
CLstodySeal Present? ❑Yes No SealsIntact? []YesNo
Datefrnhials Person EmminIq Contents: •7
P"ng Material: ❑Bubble Wrap E39ubble Bags ❑None ❑Other_
Titermometer: . -
S• rYpeuf ❑Wet ©Blue •❑None ❑Samples ontw,coolIngprocesshas begun
�1RGunID:
CorrectionFactorYUdS CoolerTempCorrected(*C): flologlcalTissue Frozen? []Yes , ONO /A•
Temp should be above freeting to WC
USDA Regulated Solt ([:j.N/At, water sarnoe)
Pld sainpfes originate In a quarantine zone within the United States CA, NY, orSC (check maps)? Did samples ortOnatefmm a forelp same (inkmatkinallY
MdudlnaHaivaiiand PueRoRim)?❑Yes ©No
Ci.atri of 0ZWdy Present?
Yes
No
N A
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Sam es Atrrlved Within HaIRIme?
ea'
No
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ShortllotdTime 8p is OZhr
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26
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Yes
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7.
Sam uReldFiltered?
Yes
No
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Nob lfsedlmenlisvlsibleInthe dissolved container
Stm.Ale Labels Match COO,
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[]No ❑rz/A
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Person Contacted.
Dateliirre:
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Pmjeta Manager SCURF Review:
6 ykb
Date.
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CHAIN -OF -CUSTODY 1 Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must he Completed accurately.
Section A Section B Section C
Required Client Information: Required Project Mforrn ation: tmreice Information- Pape
Company: Grdols TherapeLnics Report To: Sam Vedder Attention.
Address' 83W US 10 Wesl Copy To; Company Name,
Clayton, NC 27520
Address:
Reautatory
Email:
Purchase Order k
Pace Chicle;
Phone: Fax
Project Name: Stormwater
Pace Project Manager nicole, pasxwowski oacelabs.com.
State ! Location
RequeVed Due Date:
Prajed 0:
Pace Profile R: 7122-1
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SAMPLER NAME AND SiGNATURLE
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SIGNATURE of SAMPLER: DATE Signed: ) S /
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GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2016
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert #012
PLEASE SIGN ON THE REVERSE 4
Outfall
No.
Date
Sample Collected,
mo/dd/ yr
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
m /L
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
1
12-05-16
<10.0
<5.0
7.0
6.9
Note:. If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perfonn Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity onitoring Re uirements
Outfall
No.
Date
Sample Collected.
mo/dd/yr
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
Average annual gallmo
Benchmark
-
30
100
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value; or outside the benchmark range for pH, you must implement Tier I or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 12-05-16 (first event sampled)
Total Event Precipitation (inches):.62
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S W U-248-102107
Page I of 2

STORMWATER DISCHARGE OUTF'ALL (SDO)
MONITORING REPORT '
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry'of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
14 Acc 20 /G
C(DateP
S W U-248-102107
Page 2 of 2

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCC060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2016
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert 9012
PLEASE SIGN ON THE REVERSE 4
O u tfa I I
No.
Date
Sample Collected,
mo/dd/vr
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
m /L
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
.3_, %
12-05-16
<l 0.0
<5.0
6.8
<2.5
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier I or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Ou tfa I I
No.
Date
Sample Collected,
mo/dd/vr
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 12-05-16 (first event sampled)
Total Event Precipitation (inches):.62
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S W U-248-102107
Page 1 of 2

STORMWATER DISCHARGE OUTF'ALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
�(Signatu er of_�ermittee)� C Date) —
S W U-24 8-102107
Page 2 of 2

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2016
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert #012
PLEASE SIGN ON THE REVERSE 4
Outfal I
No.
Date
Sample Collected,
mo/dd/yr
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
m /L
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
4
12-05-16
11.0
<5.0
6.8
6.4
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?_ yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfa I I
No.
Date
Sample Collected,
mo/dd/ rr
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 12-05-16 (first event sampled)
Total Event Precipitation (inches):.62
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
SWU-248-102107
Page I of 2

STORMWATER DISCHARGE OUTF'ALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
G`(Signature•of-Per-mitte� C(Date) •
f
S W U-248-102107
Page 2 of 2

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analvtical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2016
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NCIWW cert #012
PLEASE SIGN ON THE REVERSE 4
&-.0D—atle6
te�
00340 . ,r,_.,..,,06556
;• rdia00400`"``
-
00530
Chemical Oxygen Dema �
+m ILnd
Oil and Grease,W
� m I,L ..
PHA l
PX=Staudard units
Ti5't`al Sus ende`d 5oliiisti
P ,d/.y,r
m /L •
4Berichmarl.�
W: a!ia . .._. z
- -
. 1 -a
120
�r'Sca .:-x Wiz,:
30 ,tea -ter _
sir fi
_ __ _6.0;:9;0 _
iOO tiu g
-5
12-05-16
<10
<5.0
7.0
2.8
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier I or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
{4 No
Date
Sample Collected,
moLdd/.ys �.
O.O�sti00530
00400��
Oil and Grease,
m /L
Total Sus"perided Slolids,
m /L
pH,
Standard units .r
New Motor OillUsage,
Ayes a annual allmo
;Benchmarl.^0._
,;�
I*
:�..."�:�I'00�'=:F..: �m
+ 1 T 7� 4 'hi
���:�6.OZ�9 0., �
`k�"-
�
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier I or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 12-05-16 (first event sampled)
Total Event Precipitation (inches):.62
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S W U-24 5-102107
Page I of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. 1 am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
[(Signature-of-ke mittee)-,->
/G DEG �16
MDate)=
S W U-24 8-102107
Page 2 of 2

�o�OF warFRQ�
r
RECEIVED
CENTRA FILES
DWR SECTION
Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit Nc NCG060000 or Certificate of Coverage No.: N CG060039
Facility Name: Grifols Therapeutics
County: Johnston County Phone No.919-359-5473
Inspector: David S. Graham
Date of Inspection: 6I2412016
By this signature, I certify that this report is accurate and complete to the best of my knowledge:
ignature of Permittee or Designee)
1.Outfall Description
COutfall•No-- 3JStructure (pipe, ditch, etc.)
Receiving Stream: tributary to the Neuse River
Pipe
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _ light brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 4 5 6 7 8 9 10
Page 1
SWU-242-020705

5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
O 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where 1 ' no solids and 10 is extremely muddy:
1 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes G
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes IVo
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? Yee
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes G
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SWU-242-020705

o�0F %NAP 9q c
RECEIVED
jut. 1 8
CENTRAL FILES
DWR SECTION
Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit Nc NCG060000 or Certificate of Coverage No.: N CG060039
Facility Name: Grifols Therapeutics
County: Johnston County Phone No.919-359-5473
Inspector: David S. Graham
Date of inspection: 6/24/2016
By this signature, I certify that this report is accurate and complete to the best of my knowledge:
(Signature of Permittee or Designee)
1.Outfall Description
Outfaii-No:--�1 Structure (pipe, ditch, etc.) Stream
Receiving Stream: tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _ Clear with a light brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 ® 4 5 6 7 8 9 10
Page 1
SWU-242-020705

5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
0 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where 1 ' no solids and 10 is extremely muddy:
1 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes G
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes No
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? Ydo
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes G
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SW U-242-020705

GENERAL PERMIT NO. NCC060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analvtical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2016
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NCIWW cert #012
PLEASE SIGN ON THE REVERSE 4
l'o faller
NO.
Date
Sample Collected,
mo/dd/ yr
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
m IL
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
[10
06-24-16
<10.0
<5.1
7.0
<2.5
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier I or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Ou t fa I I
No.
Date
Sample Collected,
mo/dd/vr
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
annual gallmo
Benchmark
-
30
100
6.0 — 9.0
_Average
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 06-24-16 (first event sampled)
Total Event Precipitation (inches):.1
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
SWU-248-102107
Page I of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
(Signature of Permittec)
12.1yeY avl6
(Date)
SWU-248-102107
Page 2 of 2

AR-
W ATg9PG
A
pvlqk� `C
Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit Nc NCGO60000 or Certificate of Coverage No.: N CG060039
Facility Name: Grifols Therapeutics
County: Johnston County Phone No.919-359-5473
Inspector: David S. Graham
Date of Inspection: 6/24/2016
By this signature, I certify that this report is accurate and complete to the best of my knowledge:
(Signat a of Permittee or Desi
1.Outfall Description
Gutfa`II=No lVStructure (pipe, ditch, etc.) Pipe from pond
Receiving Stream: tributary to the Neuse River T
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _clear with a light brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 ® 4 5 6 7 8 9 10
Page 1
SWU-242-020705

5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
O 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where 1 ' no solids and 10 is extremely muddy:
1 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes G
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes No
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? Yd
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes G
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SWU-242-020705

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCC060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2016
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY .Johnston
PHONE NO. [phone]
Lab #NC/WW cert 9012
PLEASE SIGN ON THE REVERSE 4
'O-54411ft
Vo
Date
Sample Collected,
mo/dd/vr
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
m IL
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
t00
N111111111111111110i
06-24-16
18.0
<5.1
7.1
<10.9
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _yes X no
(if yes. complete Part 13)
Part B: Vehicle Maintenance Activity Monitoring Requirements
O u tfa I I
No.
Date
Sample Collected,
mo/dd/vr
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
Note: if you report a sampled value in excess of the benchmark value. or outside the benchmark range for pH, you must implement Tier I or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 06-24-16 (first event sampled)
Total Event Precipitation (inches):.l
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh. NC 27699-1617
S W U-248-102107
Page I of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee)
/2 it), Y Z AI
(Date)
S WU-248-102107
Page 2 of 2

}
Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit Ne NCG060000 or Certificate of Coverage No.: N CG060039
Facility Name: Grifols Therapeutics
County: Johnston County Phone No.919-359-5473
Inspector: David S. Graham
Date of Inspection: 6/24/2016
By this signature, I certify that this report is accurate and complete to the best of my knowledge:
(Signature of Permittee or Designee)
1.Outfall Description
CO'utfa`irN LL ,5)Structure (pipe, ditch, etc.)
Receiving Stream: tributary to the Neuse River
creek
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: -clear with a light brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 4 5 6 7 8 9 10
Page 1
SW U-242-020705

t
5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
O 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where 1 ' no solids and 10 is extremely muddy:
1 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes No
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes No
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? Ye(
10. Erosion at Out#all
Is there erosion at or immediately below the outfall? Yes G
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SW U-242-020705

VO► { -
GENERAL PERMIT NO. NCC060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analvtical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2016
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab ##NC/WW cert #012
PLEASE SIGN ON THE REVERSE 4
ticru—i ilk
&Noll
Date
Sample Collected,
mo/dd/ =r
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
m /L
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
15am
06-24-16
<10
<5.0
7.2
4.1
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes X no
(if yes, complete Part 13)
Part B: Vehicle Maintenance Activity Monitoring Requirements
O u tfa I I
No.
Date
Sample Collected,
mo/dd/vr
00556
00530
00400
Oil and Grease,
m /L .
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier l or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 06-24-16 (first event sampled)
Total Event Precipitation (inches):.1
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to-
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S W U-248-102107
Page 1 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee)
/Z -1ve y 2o//e;
(Date)
SWU-248-102107
Page 2 of 2

r�-
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
GENERAL PERMIT NO. NCG060000 SAMPLES COLLECTED DURING CALENDAR YEAR: 2016
CERTIFICATE OF COVERAGE NO. NCG060039 (This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
FACILITY NAME Grifols_Therapeutics_ 8�COUNTY Johnston
PERSON COLLECTING SAMPLES David S. Graham ylb PHONE NO. [phone]
CERTIFIED LABORATORY Pace Analvtical SUL $ Tab #NC/WW cert #012
CEt4 AL F11.ES
Part A: Specific Monitoring Requirements MNR SECTION
PLEASE SIGN ON THE REVERSE ->
WDu t fa Il
�1yo.
Date
Sample Collected,
moldd/vr
00340
00556
00400
00530
Chemical Oxygen Demand,
m IL
Oil and Grease,
m IL
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
.3—Y
06-24-16
21.0
<5.3
6.9
<3.0
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier I or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity onitoring Re uirements
Ou t fa I I
No.
Date
Sample Collected,
mo/dd/vr
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
k�
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responsesi
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 06-24-16 (first event sampled) Mail Original and one copy to:
Total Event Precipitation (inches):.1 Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Date (list each additional event sampled this reporting period, and rainfall amount) Raleigh, NC 27699-1617
Total Event Precipitation (inches):
S W U-24 9-102107
Pagel of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee)
/2 wcY zve6
(Date) T
S W U-248-102107
Page 2 of 2

aceAnalytical o
www.pecelaUcom
July 11, 2016
Sam Vedder
Grifols Therapeutics, Inc.
8368 US 70 West
Clayton, NC 27520
RE: Project: Stormwater
Pace Project No.: 92302994
Pace Analytical Services, Inc.
6701 Conference [give
Raleigh, NC 27607
[phone]
NCC.,- Obb o 3 q
RECEIVED
JUL 18 ZUin
CENTRAL FILES
DWR SECTION
Dear Sam Vedder:
Enclosed are the analytical results for sample(s) received by the laboratory on June 27, 2016. The
results relate only to the samples included in this report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Nicole Gasiorowski
[e-mail]
Project Manager
Enclosures
cc: David Graham, Grifols Therapeutics, Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
wlthoutthe written consent of Pace Analytical Services, Inc,.
Page 1 of 24

aceAnalytical
' NwwpoewaA3.mm
Project: Stormwater
Pace Project No.: 92302994
Asheville Certification iDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
Eden Certification IDs
205 East Meadow Road Suite A, Eden, NC 27288
North Carolina Drinking Water Certification #: 37738
CERTIFICATIONS
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 633
VirginiaNELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
6701 conference Drive
Raleigh, NC 27607
[phone]
Page 2 of 24

M aceAnalytical0
r www.pacelebs.com
SAMPLE ANALYTE COUNT
Project: Stormwater
Pace Project No.: 92302994
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
92302994001
#3-SOUTH PLANT PIPE
SM 25400
CHM
1
PAS-E
SM 5220D
WRC
1
PASI-A
92302994002
#4-SE Pond
SM 2540D
CHM
1
PASf-E
SM 5220D
WRC
1
PASI-A
92302994003
#5-Consolidated Outfall
SM 2540D
CHM
1
PASI-E
SM 5220D
WRC
1
PASI-A
92302994004
Outfall #1
SM 2540D
CHM
1
PASI-E
SM 5220D
WRC
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except'in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 24

Pace Analytical Services, Inc.
acemalytical • 6701 Conference Chive
Raleigh, NC 27607
r K'wwPao91ab&CoM [phone]
ANALYTICAL RESULTS
Project: Stormwater
Pace Project No.: 92302994
Sample: #3-SOUTH PLANT PIPE Lab ID: 92302994001 Collected: 06/24/16 10:05 Received: 06/27/16 14:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed GAS No. Qual
2540D Total Suspended Solids Analytical Method: SM 2540D
Total Suspended Solids ND mg/L 3.0 1 06/29/16 14:00
5220D COD Low Level Analytical Method: SM 5220D
Chemical Oxygen Demand 21.0 mg1L 10.0 1 07/08/16 14:50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/11/2016 10:5B AM without the written consent of Pace Analytical Services, Inc.. Page 4 of 24

-�� aceAnalytical o
www.pacelabacmn
ANALYTICAL RESULTS
Project: Stormwater
Pace Project No.: 92302994
Paco Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
Sample: 94-SE Pond Lab ID: 92302994002 Collected: 06/24/16 10:15 Received: 06/27/16 14:15 Matrix: Water
Parameters Results Units Report Limit DP Prepared Analyzed CAS No, Qual
2540D Total Suspended Solids Analytical Method: SM 2540D
Total Suspended Solids ND mglL 10.9 1 06/29/16 14:01
5220D COD Low Level Analytical Method: SM 52200
Chemical Oxygen Demand 18.0 mglL 10.0 1 07/08/16 14:50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/11/2016 10:58 AM without the written consent of Pace Analytical Services, Inc.. Page 5 o

aceAnalytical
www.pacelahe.Gam
ANALYTICAL RESULTS
Project: Stormwater
Pace Project No.: 92302994
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
(919)8344984
Sample: #5-Consolidated Outfall Lab ID: 92302994003 Collected: 06I24116 09:15 Received: 06/27/16 14:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids Analytical Method: SM 2540D
Total Suspended Solids 4.1 mg/i_ 2.6 1 06/29/16 14:01
5220D COD Low Level Analytical Method: SM 5220D
Chemical Oxygen Demand ND mg1L 10.0 1 07108l16 14:50
Date: 07/11 /2016 10:56 AM
REPORT OF LABORATORY ANALYSIS
Thls report shall not be reproduced, except'infull,
without the written consent of Pace Analytical Services, Inc,.
Page 6 of 24

;aneAnalyficalo
wwwpmidbs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
Project: Stormwater
Pace Project No.: 92302994
Sample: Outfall #1 Lab ID: 92302994004 Collected: 06/24/16 09:35 Received: 06/27/16 14:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids Analytical Method: SM 2540D
Total Suspended Solids ND mg1L 2.5 1 06/29/16 14:02
5220D COD Low Level Analytical Method: SM 5220❑
Chemical Oxygen Demand ND mg/L 10.0 1 07/08/16 14:50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in Full,
Date: 07/11/2016 10:58 AM without the written consent of Pace Analytical Services, Inc,. Page 7 of 24

aceAnalytical0
www.pacefeb&mm
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
Project: Stormwater
Pace Project No.: 92302994
QC Batch; EDEN123295
Analysis Method:
SM 2540D
QC Batch Method: SM 2540D
Analysis Description:
2540D Total Suspended Solids
Associated Lab Samples: 92302994001,
92302994002, 92302994003, 92302994004
METHOD BLANK: 1768700
i Matrix: Water
Associated Lab Samples: 92302994001,
92302994002, 92302994003, 92302994004
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Total Suspended Solids
mg/L
ND 2.5 06/29/16 13:59
LABORATORY CONTROL SAMPLE:
1768701
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Total Suspended Solids
mg/L
250 258
103 90-110
SAMPLE DUPLICATE: 1769669
92302994002
Dup
Parameter
Units
Result
Result RPD Qualiflers
Total Suspended Solids
mg1L
ND
ND
SAMPLE DUPLICATE: 1769670
r
92303054001
Dup
Parameter
Units
Result
Result RPD Qualifiers
Total Suspended Solids
mg/L
53.3
52.6 1
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/11/2016 10:58 AM without the wr1ten consent of Pace Analytical Services, Inc.. Page 8 of 24

►(5aneAnalj6calo
/ wwwPacefBbs.mnt
QUALITY CONTROL DATA
Project: Stormwater
Pace Project No.: 92302994
QC Batch: WETA128251 Analysis Method: SM 5220D
QC Batch Method: SM 5220D Analysis Description: 5220D COD, Low Level
Associated Lab Samples: 92302994001, 92302994002, 92302994003, 92302994004
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
METHOD BLANK: 1775296
Matrix:
Water
Associated Lab Samples: 92302994001,
92302994002,
92302994003,
92302994004
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Chemical Oxygen Demand
mglL
NO
10.0
07/08/16 14:50
LABORATORY CONTROL SAMPLE:
1775297
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Chemical Oxygen Demand
mglL
75
75.0
100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1775298 1775299
MS MSD
92302672001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result e% Rec % Rec Limits RPD Qual
Chemical Oxygen Demand mglL 49.0 150 150 216 216 111 111 90-110 0 M1
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 071l112016 10:58 AM without the written consent of Pace Analytical Services, Inc..
Page 9 of 24

aceAnalytical
xww.pacelahacom
QUALIFIERS
Project: Stormwater
Pace Project No.: 92302994
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SVV846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-E Pace Analytical Services - Eden
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/11/2016 10:58 AM without the written consent of Pace Analytical Services, Inc.. Page 10 of 24

_ - aceAnalytical o
www.pecelabs.com
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Stormwater
Pace Project No.: 92302994
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
92302994001
#3-SOUTH PLANT PIPE
SM 2540D
EDEN123295
92302994002
#4-SE Pond
SM 2540D
EDEN123295
92302994003
#5-Consolidated Outfall
SM 2540D
EDEN123295
92302994004
Outfall #1
SM 2540D
EDEN123295
92302994001
#3-SOUTH PLANT PIPE
SM 5220D
WETA128251
92302994002
#4-SE Pond
SM 5220D
WETA128251
92302994003
#5-Consolidated Outfall
SM 5220D
WETA128251
92302994004
Outfall #1
SM 5220D
WETA/28251
Date: 07/11/2016 10:58 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, tnc..
Analytical
Batch
Page 11 of 24

Document Name: Document Revised: May24,2016
�,aceAnaYkHl' Sample Condition Upon Rece[ t(SCUR) Pa e i of 2
Document No.: Issuing Authority:
F-RAL•CS-001-Rev,04 Pace Raleigh Quality Office
n- 9.I nL.., In&-1 tI—hAli ,•
Client fVame: WO# ; 92302994
CReceipt Project #:
Courier: Fed Ex �J❑UPS ❑U5 S []Client 1111111111111111111111
ElCommercial 0 Pace ❑ 0ther:
92302994
Custody Seal Presents ❑Yes ONo Seals Intact? ❑Yes j�No
Date/laitsals Person Examining Canhntso t
packing Material: []Bubble Wrap ❑Bubble Bags f None ❑Other;
Thermometer: T1505 Type of Ice: et ❑slue ❑None (]samples on ice, cooling process has begun
Correction Factor: 0.01c Cooler Temp Corrected ('C): Biological Tissue Frozen? Oyes []NO ON/A
'temp should be above fr ezing to 6'C
USDA Regulated Sail (Y N/A, water sample)
via sample
rlginate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (intemationally,
❑Yes
No
including Hawaii and Puerto Rico)? Des Na
commenLOIscrepamr,
Chain of Custody Present?
es
Na
N/A
1.
Samples Arrived within Hold Time?
gy.,
ON.
A
2.
Short Hold Time Analysis (<72 hr,)?
❑Yes
o
A
3.
Rush Turn Around Time Re uested?
Yes
No
N/A
4.
Sufficlent Volume?
16Y,
Na
© a
S.
Correct Containers Used?
Yes
❑No
❑N/A
6.
-Pace Containers Used?
s
No
ON/A
Containers Intact?
Yes
No
A
7.
Samples Field Filtered?
ayes
No
PINIA
B. Note if sediment Is visible In the dissolved container
Sample Labels Match COC?
Yes
❑No
❑N/A
9.
-Includes Date/Time/ID/Ana! is Matrix:
All containers needingacid/base preservation have been
�[
10. „as DWI
checked?
(1Yes
QNn
©N/A
All containers needing preservation are found to be in
((
"opwl
compl lance with EPA recommendation?
KUNOna
(HNO3, H2$04, HCIc2; NaOH>95ulftde, NaOH>32 Cyanided
IY s
ONO
❑N/A
wa�renu
Exceptlons. VOA, Coliform, TOG Oil and Grease,
DR2/8015 water) DOr-LILlig
les
nNo
nNiA
NAHJUM W,I
Samples checked for dechlorination7
Yes
❑No
/A
11,
He a d sp ace In VOA Vials >S-6mm ?
[]Yes
ONO
N/A
12.
Trip Blank Present?
❑Yes
©No
(KJA
13.
Trip Blank Custody Seals Present?
❑Yes
ONO
[aN/A
Pace Trip Blank Lot # If purchased):
CLIENT NOTIFICATION/RESOLUIiCIN
Person Contacted:
Comments/Sample
Discrepancy:
Date/Time:
Field Data RequirW []Yes []NO
Project Manager SCURF Review: r ` Date: _ ,W2
Project Manager SRF Review: Date:
Note: Whenover there Is a discrepancy affecting North Carolina compilance samples, a copy of this form will he sent to the North Carolina DEHNA Certification Office 4e.
out of hold, incorrect preservative, out of temp, incorrect containers)
Page 12 of 24

,! ,-YaceMaly[iral
Section A
Required Client Information:
Section B
Reouirad Proi-4 W.—H.-
CHAIN-OF-CUSTODY CHAIN -OF -CUSTODY 1 Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section C
In....ene Inln•.nuHnw•
m
m
Pana - t of 1 0_
Comperty: GriSols Therapeutics
Report To: San Vedder
Attention
Address: 8365 US 10 West
Copy To:
Company Name:
Clayton, NO 27520Emait
Address:
'ter-ti:�=:t::1 - - - -a" " - ,:•-��'3:'' T:
Purchase Order #:
Pere Quota:
Phone; Fax
Projzcd Name: Slormwater
Paco Pnaect Manager nicalo.9wkwowskjopacelaba.cem.
.m ar .-==+iw�a=•I State l Locatlon M=.:' �-•`-^�>"��
Requested Due Date:
Project #:
Pace Pmrlla #: 7122-1
RecFuestedAitial
Filtered
fY1N1Al
Zip
MAsunt cooE
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Sample ids mast be unique n— �s
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aceAnalytical
PACE ANALYTICAL SERVICES, INC.
Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Peachtree Corners, GA 30092
[phone] FAX [phone]
Laboratory Report
Prepared For:
Pace Analytical Services Inc. - Huntersville
9800 Kincey Avenue Suite 100
Huntersville, NC 28078
Attention: Ms. Nicole Gasiorowski
Report Number: AZF1092
July 07, 2016
Project: Pace Analytical Services, Inc.
Project #:923029941 Stormwater
We appreciate the opportunity to provide the analytical support for your project. The analytical results in this report are based
upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data
package, please do not hesitate to call.
Approved:
Signature
This report may not be reproduced, except in full, without written approval from Pace Analytical Services, Inc.
Pace Analytical Services, Inc. certifies that the following analytical results meet all requirements of the National
Environmental Laboratory Accreditation Conference(NELAC).
All test results relate only to the samples analyzed.
Page 14 of 24
Page 1 of 10

aceAnalytical
Pace Analytical Services Inc. - Huntersville
9800 Kincey Avenue Suite 100
Huntersville NC, 28078
Attention: Ms. Nicole Gasiorowski
Sample ID
#3-South Plant Pipe192302994001
#4 SE Pond192302994002
#5-Consolidated Outfall/92302994003
Outfall #1192302994004
PACE ANALYTICAL SERVICES, INC.
Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Peachtree Corners, GA 30092
[phone] FAX [phone]
July 07, 2016
ANALYTICAL REPORT FOR SAMPLES
Laboratory ID Matrix
Date Sampled
Date Received
AZF1092-01
Water
06124/1610:06
06/29/1610:00
AZF1092-02
Water
06/24/1610:15
06129/1610:00
AZF1092-03
Water
06/24/16 09:15
06/29/16 10:00
AZF1092-04
Water
06/24/16 09:35
06/29/16 10:00
Page 15 of 24
Page 2 of 10

aceAnalyficW
Pace Analytical Services Inc. - Huntersville
9800 Kincey Avenue Suite 100
Huntersville NC, 28078
Attention: Ms. Nicole Gasiorowski
Report No.. AZF1092
Client ID: #3-South Plant Pipe192302994001
DatelTime Sampled: 6/2412016 10:05:00AM
Matrix: Water
Analyte
General Chemistry
Oil & Grease (HEM)
PACE ANALYTICAL SERVICES, INC.
Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Peachtree Corners, GA 30092
[phone] FAX [phone]
July 07. 2016
Project: Pace Analytical Services, Inc.
Lab Number ID: AZF1092-01
Daterrime Received: 612912016 10:00:00AM
Preparation Analytical
Result RL Units Method QuaL DF Date Date Batch Init_
ND 5.3 mglL EPA 1664E 1 7/06/16 7:50 7/06116 7:50 6070084 KN!
Page 16 of 24
Page 3 of 10

PACE ANALYTICAL SERVICES, INC.
Analyfical "'
Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Peachtree Corners, GA 30092
[phone] FAX [phone]
Pace Analytical Services Inc. - Huntersville
July 07, 2016
9800 Kincey Avenue Suite 100
Huntersville NC, 28078
Attention: Ms. Nicole Gasiorowski
Report No.: AZF1092
Project: Pace Analytical Services, Inc.
Client ID: #4 SE Pond192302994002
Lab Number ID; AZF1092-02
Datefrime Sampled: 6/24/2016 10:15:00AM
DalefTime Received: 6/2912016 10:00:OOAM
Matrix: Water
Preparation Analytical
Analyte
Result RL Units Method Qual. DF Date Date Batch Init.
General Chemistry
Oil & Grease (HEM)
ND 5.1 mg1L EPA 16646 1 7l06116 7:50 7/06116 7:50 6070084 KN1
as
Page 17 of 24
Page 4 of 10

aceAnalytical
Pace Analytical Services Inc. - Huntersville
9800 Kincey Avenue Suite 100
Huntersville NC, 28078
Attention: Ms. Nicole Gasiorowski
Report No.: AZF1092
Client ID: #5-Consolidated Outfa11/92302994003
Daterrime Sampled: 6/24/2016 9:15:00AM
Matrix: Water
Analyte
General Chemistry
Oil & Grease (HEM)
PACE ANALYTICAL SERVICES, INC.
Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Peachtree Corners, GA 30092
[phone] FAX [phone]
July 07, 2016
Project: Pace Analytical Services, Inc.
Lab Number ID: AZF1092-03
Daterrime Received: 6129/2016 10:00:OOAM
Preparation Analytical
Result RL Units Method Dual. OF Date Date Batch Init.
ND 5.0 mg/L EPA 1664B 1 7106116 7:50 7106/16 7:50 6070084 KNI
Page 18 of 24
Page 5 of 10

aceAnalyfical
Pace Analytical Services Inc- - Huntersville
9800 Kincey Avenue Suite 100
Huntersville NC, 28078
Attention: Ms. Nicole Gasiorowski
Report No.: AZF1092
Client ID: Outfall #1l92301994004
DatelTime Sampled: 6/2412016 9:36:00AM
Matrix: Water
Analyte
PACE ANALYTICAL SERVICES, INC.
Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Peachtree Corners, GA 30092
[phone] FAX [phone]
July 07, 2016
Project: Pace Analytical Services, Inc.
Lab Number ID: AZF1092-04
Daterrime Received: 6/2912016 10:00:00AM
Preparation Analytical
Result RL Units Method Qual. DF Date Date Batch snit.
General Chemistry
Oil 8 Grease (HEM) ND 5.1 mg1L EPA 1664B 1 7106116 7:50 7106/16 7:50 6070084 KN!
Page 19 of 24
Page 6 of 10

4-,
aceAnalytical o
Pace Analytical Services Inc, - HuntersvWe
9800 Kincey Avenue Suite 100
Huntersville NC, 28078
Attention: Ms. Nicole Gasiorowski
Report No.: AZF1092
Analyte
Batch 6070084 - EPA 1664
PACE ANALYTICAL SERVICES, INC.
Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Peachtree Corners, GA 30092
[phone] FAX [phone]
July 07, 2016
General Chemistry - Quality Control
Reporting Spike Source %REC RPD
Result Limit Units Level Result %REC Limits RPD Limit Qual
Blank (6070084-BLK1)
Prepared & Analyzed: 07/06/16
W & Grease (HEM)
ND 5.0 mg/L
LCS (6070084-BS1)
Prepared & Analyzed: 07/06/16
Oil & Grease (HEM)
40 5.0 mg/L 40.000
100 78-114
Duplicate (6070084-DUP1)
Source: AZF0696-01
Prepared & Analyzed: 07/06/16
Oil & Grease (HEM)
ND 6.2 mg1L
ND 75
Matrix Spike (6070084-MS1)
Source: AZF0623-02
Prepared & Analyzed: 07/06/16
Oil & Grease (HEM)
46 6.1 mg/L 48.780
ND 95 78-114
Page 20 of 24
Page 7 of 10

aceAnalytical o
Pace Analytical Services Inc. - Huntersville
9800 Kincey Avenue Suite 100
Huntersville NC, 28078
Attention: Ms. Nicole Gasiorowski
Code Description
PACE ANALYTICAL SERVICES, INC.
Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Peachtree Corners, GA 30092
[phone] FAX [phone]
Laboratory Certifications
NC North Carolina
NELAC FL DOH (Non -Pot. Water, Solids) Eff:: 07/0112015
Number
381
E87315
July 07, 2016
Expires
12/31/2016
06/30/2017
Page 21 of 24
Page 8 of 10

err �
aceAnalyfical o
Pace Analytical Services Inc. - Huntersville
9800 Kincey Avenue Suite 100
Huntersville NC, 28078
Attention: Ms. Nicole Gasiorowski
Definition of Laboratory Terms
ND - None Detected at the Reporting Limit
TIC - Tentatively Identified Compound
CFU - Colony Forming Units
PACE ANALYTICAL SERVICES, INC.
Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Peachtree Corners, GA 30092
[phone] FAX [phone]
Legend
SOP - Method run per Pace Standard Operating Procedure
RL - Reporting Limit
DF - Dilution Factor
* - Analyte not included in the NELAC list of certified analytes.
Sample Information
N-Nitrosodiphenylamine breaks down to diphenylamine in the GCMS; both analytes are reported as
N-Nitrososdiphenylamine. Pace is not NELAC certified for diphenylamine.
Phthalic acid and phthalic anhydride are reported as dimethyl phthalate
Maleic acid and maleic anhydride are reported as dimethyl malate
1,2-Diphenylhydrazine breaks down to azobenzene in the GCMS; both analytes are reported as azobenzene
Definition of Qualifiers
July 07, 2016
Note: Unless otherwise noted, all results are reported on an as received basis.
Page 22 of 24
Page 9 of 10

r-
Chain of Custody
/7
1aceAnalytical
rv►w.yacelaesmm
i
Workorder: 92302994 Workorder Name:Stormwaler Owner Received Cate: 6/27/2016 Results Requested By: 717/2016
:-•�:'a� -q,<"_ SubcontractTo,:-:� r"� =x
RepoiYTo a";f
E ;� _ RequcstedAnal sis
Nicole Gasiorowski Pace Analytical AUanta
Pace Analytical Charlotte 110 Technology Parkway
9800 Kincey Ave. Suite 100 Peachtree Comers, GA 30092
Huntersville, NC 28078 Phone [phone]
Phone [phone]
Presbrved Containers,._-
L
o
y��
Sample'
Collect.. ;•
Y'
` " i f .:'
Item
ID j;
Type
DateMme';•
ID ;.r -
Matrrx+ -
LAB USE ONLY
_Sample - ,4:
sLab
1
#3-SOUTH PLANT PIPE
PS
6/24/2016 10.05
92302994001
Water
1
X
2
#4-SE Pond
PS
6/24/2016 10:15
92302994002
Water
1
X
3
95-Consoridated Outtall
PS
1 6/2412016 09:15
192302994003
1 Water
1
X
4
Outfau #1
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DatefTime
R95eived By
Datarrime
�L%i1V
1(am
2
3
Cooler Temperature on Receipt °C
I Custody Seal n or N
Received on Ice or N Samples Inta or N
'*In order to maintain client confidentiality, localion/name of the sampling site, sampler's name and signature may not be provided on this COC document.
This chain of custody is considered complete as is since this information is available in the owner laboratory.
H M bnday. June 27, 2016 4:35:51 PM FMT-ALL-C-002rev.00 24March2009 Page 1 of 1
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aceAnaiytical "
Attn: Ms. Nicole Gasioro%vski
PACE ANALYTICAL SERVICES, INC.
Environmental Monitoring & Laboratory Analysis
110 Technology Parkway, Peachtree Corners, GA 30092
[phone] FAX [phone]
LOG -IN CFIECKLIS'I'
Client: Pace Analytical Services Inc. - Fluntersville
Project: Pace Analytical Services, Inc.
Date Received: 06/29/16 10:00
OBSERVATIONS
#Samples: 4 #Containers: 4
Minimum Temp(C): 2.0 Maximum Temp(C):
CHECKLIST ITEMS
COC included with Samples
Sample Container(s) Intact
Chain of Custody Complete
Sample Container(s) Match COC
Custody seal Intact
Temperature in Compliance
Sufficient Sample Volume for Analysis
Zero Headspace Maintained for VOA Analyses
Samples labeled preserved (IfApplicabie)
Samples received within Allowable Hold Times
Samples Received on Ice
Preservation Confirmed
Comments:
Work Order: AZF1092
Logged In By: Charles Hawks
Printed: 7/7/2016 7:09:27PM
2.0 Custody Seal(s) Used: Yes
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
Page l of I
Page 24 of 24

650� i Gr`+
Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit Nc NCG060000
Facility Name: - Grifols
cs )
RECEIVED
DEC 10Z015
CENTRAL FILES
PWR_5_5MQ N
or Certificate of Coverage,llo.: N CGO60039
County: Johnston County _ Phone No.919-359-5473\�
Inspector: David S. Graham
Date of Inspection: 10/28/2015
By this signature, I certify that this report is accurate and complete to the best of my knowledge:
(Signature of Permittee or Designee) 0
1.Outfall Description �
Outfall No. 3 Structure (pipe, ditch, etc.) Pipe
Receiving Stream: tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors. _ fight brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 © 4 5
SW U-242-020705
6 7 S 9 10
Page 1

5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
0 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where 1 ' no solids and 10 is extremely muddy:
16 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes No
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes No
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? Yd
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes No
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note. Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SWU-242-020705

`o�oF W AT �R�G
f
alqii;�'NIZW-r
Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit Nc NCG060000 or Certificate of Coverage No.: N CG060039
Facility Name: Grifols Therapeutics
County: Johnston County `Phone No.919-359-5473
Inspector: David S. Graham
Date of Inspection: 10/28/2015 ©©� ec
By this signature, I certify that this report is accurate and complete to the best of my kn0?k dg-YE1VED
DEC 10 2015
CENTRAL FILES
(Signature of Permittee or Designee) DWR SEC I
1.Outfall Description
Outfall No, 4 Structure (pipe, ditch, etc.) Pipe from pond
Receiving Stream: tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _clear with a light brown tint -
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 ® 4 5 6 7 8 9 10
Page 1
SW U-242-020705

5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
10 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where no solids and 10 is extremely muddy:
1 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes No
B. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes No
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? Yde
10. Erosion at Outfall
Is there erosion at or immediately below the outfali? Yes G
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SWU-242-020705

_oaoF W a r�9Q�
?b�i
Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit Na NCG060000 or Certificate of Coverage No.: N CG060039
Facility Name: Grifols Therapeutics
County: Johnston County Phone No. 919-359-5473
Inspector: David S. Graham
Date of Inspection: 1012812015
By this signature, I certify that this report is accurate and complete to the best of my knowledge:
(Signature of Permittee or Designee)
1.Outfall Description
Outfall No. 5 Structure (pipe, ditch, etc.) creek
Receiving Stream: tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: clear with a light brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 ® 4 5 6 7 8 9 10
Page 1
SWU-242-020705

5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
0 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where 1 ' no solids and 10 is extremely muddy:
1 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes No
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes No
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? YEG
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes G
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SWU-242-020705

GRIFOLS
8368 U.S. 70 Bus. West
Clayton, NC 27520
David S. Graham
ESS III
Tel [phone]
Fax 919.359,5851
Cell 919.724.5979
[e-mail]
December 7, 2015
Division of Water Quality
Attn: DWQ Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
To whom it may concern:
Attached you will find the semi-annual analytical SDO monitoring report following a representative storm event for
the Grifols Therapeutics Clayton, NC facility. If you have any questions, please don't hesitate to contact me at
919-359-5473
Sincerely,
David S. Graham
ESS III

r
aceAnalytical
www.pacelsbaaom
Laboratory Report
Sam Vedder
Grifols Therapeutics, Inc.
8368 US 70 West
Clayton, NC 27520
Project: STORMWATER
Pace Project No.: 92274183
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
Page 1 of 1
Report Date: 11/10/2015
Date Received: 10/30/2015
Sample: #3 SOUTH PLANT PIPE
Lab ID: 92274183001 Collected: 10/28/15 11:45 Matrix: Water
Method
Parameters
Results
Units
Report Limit
Analyzed Qualifiers
SM 2540D
Total Suspended Solids
15.2
mglL
3A
11/02/15 12:27
EPA 1664B
Oil and Grease
ND
mg/L
5.0
11/05/15 10:43
SM 5220D
Chemical Oxygen Demand
29.0
mg1L
10.0
11/09/15 13:31
Sample: #4 SE POND
Lab ID: 92274183002 Collected: 10/28/15 11;40 Matrix: Water
Method
Parameters
Results
Units
Report Limit
Analyzed Qualifiers
SM 2540D
Total Suspended Solids
ND
mg/L
5.0
11/02/15 12:28
EPA 1664B
Oil and Grease
ND
mg/L
5.0
11/05/15 10:43
SM 5220D
Chemical Oxygen Demand
ND
mg/L
10.0
11/09/15 13:31
Sample: #5 CONSOLIDATED OUTFALL
Lab ID: 92274183003 Collected: 10/28/15 11:15 Matrix:
Water
Method
Parameters
Results
Units
Report Limit
Analyzed Qualifiers
SM 2540D
Total Suspended Solids
2.8
mg/L
2.5
11/02/15 12:28
EPA 1664B
Oil and Grease
ND
mg/L
5.0
11/05/15 10:44
SM 5220D
Chemical Oxygen Demand
ND
mg/L
10.0
11/09/15 13:31
Sample: OUTFALL #1
Lab ID:
92274183004 Collected: 10/28/15 10;45 Matrix:
Water
Method
Parameters
Results Units
Report Limit
Analyzed Qualifiers
SM 2540D
Total Suspended Solids
5.7 mg/L
2.5
11/02/15 12:28
EPA 1664B
Oil and Grease
ND mg/L
5.0
11/05/15 10:44
SM 5220D
Chemical Oxygen Demand
ND mglL
10.0
11/09/15 13:31
Reviewed by:
Nicole Gasiorowski
nicol e.gasiorowski@pace labs, com
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
Eden Certification IDs
205 East Meadow Road Suite A, Eden, NC 27288
North Carolina Drinking Water Certification #: 37738
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
West Virginia Certification #: 357
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
VirginiaNELAP Certification #: 460222
North Carolina Wastewater Certification #: 633
VirginiaNEtAP Certification #; 460025
Page 1 of 3

�
Document Name: Sample Condition Upon
Document Revised: May 15, 2015
��..F'aCeAnalytlCa!
Recei 1' SCUR
Page 1 of 2'
document No,:
issuing Authorities:
F-RAL-CS-641-rev.03
Pace Ralei h Quality Office
'Page 2 of 2 is for Internal Use Only
Client Name: � � � (_S
Courler (Circle): Fed Ex UPS USPS Client Commercial crac lher
Custody Seal on Cooler/Box Present: yes Qj�--no Seals Intact: (D yes (jY no
Packing Material: ❑ Bubble Wrap Bubble Bags ❑ NoneX Other
Circle Thermometer Used: IR Gun SNa22g65387Type of Ice: C Blue Samples on lcel cooling process has begun
IR Gun Back Uo SN:1220053T1 I
Temp Correction Factor: Add f Subtract G C
Corrected Cooler Tam C Blotogical Tissue Is Frozen: Yes No wA
p^
Ternp should be above freezing to WC Comments:
Date and Initials of person examining
co ! Preservation
chock:
I
Chain of Custody Present:
y ❑No ❑NIA
1.
Chain of Custody Filled Out:
Ye ONo ON,
2•
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Chain of Custody Relinquished:
Ya ❑No dN1A
3•
I
Sampler Name & Signature on CDC:
9614o ❑NIA
4.
Samples Arrived within Hold Tlme:
ErYas ONO ONIA
5.
�
Short Hold Time Analysis <72hr :
Dyes Na ❑NIA
6.
f;ush Turn Around Time Requested:
❑Ya No ❑N,A
7.
Sufficient Volume:
ffYas ONO EINIA
8.
Correct Containers Used:
-Pace Containers Used:
Ye. ON. ❑NIA
Qves i lNa ❑N1A
9.
Containers Intact:
Yce ON., ON
10.
Filtered volume received for Dissolved tests
MYes ONO
rA
11.
Sample Labels match CDC:
-includes dateltimeAD/Anal sis Malrix:
tJYes No OwA
`
12.
All containers needing preservation have been chocked.
All containers needing preservalion are found to be In
compliance with EPA recommendation.
excewions: VOA, coldorm, TOC, MG, YJI-ORO(wator)
l7Ycs ONO E�wA
❑Yus ❑NO �jI
❑Yes CINo
NIA
13.
,
I
Samples checked for dechlorination:
❑Yes ONO
NIA
14,
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l{{
Headspace in VOA Vials ( >6rnm):
❑Yes ONO C
NrA
15.
I
Trip Blank Present:
Trip Blank Custody Seals Present
Pace Trip Blank Lot ik (If purchased
Oyes ONO E
Dyes ❑No E
NrA
NIA
16.
Client Notification/ Resolution: Flold Data Required? y ! N
Person Contacted: DaleMme: i
Comment:.! Resolution:
SCURF ISRF I Date: r6-w- WOE: 92
Review:: NK C 10 3d I 111111111111111
Note: Whenever there Is a discrepancy affecting North Carolina compilancesamples, a copy of this form will be sent to the North Carolina DEHNR ' 741e
Certification Office ( I,e out of hold, Incorrect preservative, out of temp,
Incorrect containers)
274183
1111111
l r1 -Page 2'6f.3
f- Ll 1. t.�ri �I � { fi - , _ �k;, -�,• -

CHAIN -OF -CUSTODY 1 Analytical Request Document
*,;.ft
cela , •ire Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
anion A section B Jr
rl Section C
Required Client Information: Required Projectlriorma0en: Inrdce bdornration: Page : 1 Of t
Gwols The ics Report To: Sam veddw Anentwr
Address: $368 US 10 West Copy To: Company Name:
Cla on. NC 27520.
Address:
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Email:
Pwchase Order #:
Pace QU01W
Pam: Fax
Project Name: SlarnrAmler
Pam Prujod Manager: nicde. iworrski labs.mrn,
; 1 `--.`:,;:Stafa l Eocatiott.�r :-'-
Requastw Due Date:
Ptojerl #;
Pace Profile M 7122.1
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Document Revised: May i5, 2015
��...Y3C$AITai}�lCBI
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Page 1 of 2'
Document No.:
Issuing Authorities:
F-RAL-CS-001-rev.03
Pace Ralel hQualit Offce
I
'Page 2 of 2 is for internal Use Only
Client Name: +� • � � s
Courier (Circle): Fed Ex UPS USPS Client Commercial ac ther
Custody Seal on Cooler/Box Present: El yes Q�-no Seals intact: 0 yes Or no
Packing Material-, ❑ Bubble Wrap ❑ Bubble Bags ❑ NoneX Other
Circle Thermometer Used: IR Gun SN:1220653877ypo of Ice: � Blue [Samples on in, coaling process has begun
IR Gun Back uo SN:1220653T1 I
Tamp Correction Factor. Add 1 Subtract —i1 ' J C
Dato and Inttla)a of person examining
Corrected Cooler Temp.:3 C
Biological Tissue is Frozen: Yes No NrA
choco /I 1 Preservation
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Comments:
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Ye ❑No ❑MA
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YelL ONO ❑MA
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ve No ❑NrA
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Yes ONO ONIA
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Oyes 1i1. ❑NIA
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❑Ye No ON,
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yee ❑No ON1A
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ye ONO ❑WA
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❑Yes ON.
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❑Yes ONO
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❑Yes ONO IJ
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❑Yes ONO
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15.
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❑Yes ONO, E
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OYos ❑No L
WA
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Pace Trip Blank Lot 4 (if purchased):
Giant Notification/ Resolution: Field Data Requ red7 Y I N
Person_ Contacted: DateMme: i
I
Commenl-d Resolution;
SCURF ISRF WO# : 92274183
Data:
Review:: Ito 3d- 5 I111111
1 11111
Notot Whonever there Is a discrepancy affecting North Carolina compliance �� F samples• a copy of this loan will be sent to the North Cerolina DEHNR g22741�1311 I j
Confutation Office ( 1.0 out of hold. Incorrect preservative, out of temp,
Incorrect containers}

ae
CHAIN -OF -CUSTODY 1 Analytical Request Document
• '- _4-�-,ft C(/ � , (/_eChain-of-Custody is a LEGAL DOCUMENT. AM relevant fields must ce completed accurately.
Section A Section B }--w— Section C
Required Client Information: Reeulrnd Pmkeet le,r,,.,n.nm• o•...., - ns
CornpaMr. Gr leis Therapeutics
Report To: Sam Vedder
Attention:
Address: 0368 US 10 West
COPY To:
Como" Name:
Clayton, NC 27520
Address:
Email:
Purchase Order 0:
Pam Quote:
Phone: Fax
Project Name: SlOrmwater
Paw Project Manager. niwle. labs.com,
• - t ate, : �-
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Requested Due Date:
Project II:
Pan PrQfile #: 7122-1
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Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit Nc NCG060000 or
Facility Name: Grifols Therapeutics
County: Johnston Count_
Inspector: David S. Graham
Date of Inspection: 1012812015
Certificate of Coverage No.: N CG060039
Phone No. 919-359-5473
By this signature, I certify that this report is accurate and complete to the best of my knowledge:
re of Nermittee or Designee)
1.Outfall Description
Outfall No. 1 Structure (pipe, ditch, etc.) Stream
Receiving Stream: tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _Clear with a light brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 ® 4 5 6 7 8 9 10
Page 1
SW U-242-020705

5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
1O 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where 1 ' solids and 10 is extremely muddy:
10 no 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes No
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes No
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? YE(
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes G
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low. clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SW U-242-020705

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
GENERAL PERMIT NO. NCG060000 SAMPLES COLLECTED DURING CALENDARAter
A 2015
CERTIFICATE OF COVERAGE NO. NCGO60039 (This monitoring report is due at the Division no I�jt� 30 days from the date
the facility receives the sampling results from the lab r or .
FACILITY NAME Grifols Therapeutics COUNTY Johnston
PERSON COLLECTING SAMPLES David S. Graham PHONE NO. [phone]
CERTIFIED LABORATORY Pace Analytical Lab #NC/WW cert #012
PLEASE SIGN ON THE REVERSE 4
Part A: Specific Monitoring Requirements
Outfall
No.
Date
Sample Collected,
mo/dd/ r
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
m /L
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
3
10-28-15
29.0
<5.0
7.0
15.2 -
Note: if you report a sampled value in excess of the benchmark value, you must implement Tier I or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity onitorin2 Re uirements
Ou t fa ll
No.
Date
Sample Collected,
mo/dd/yr
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH; you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 10-28-15 (first event sampled)
Total Event Precipitation (inches):.5
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S W U-24 5-102107
Page l of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for kawing violations."
(Signature of Permittee)
■
,!I C ZO/
(Date)
S W U-248-102107
Page 2 of 2

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2015
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert #012
PLEASE SIGN ON THE REVERSE 4
Outrall
No.
Date
Sample Collected,
mo/dd/ r
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
m /L
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
4
10-28-15
<10
<5.0
6.8
<5.0
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _yes X no
(if yes, complete Part 13)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Ou tfall
No.
Date
Sample Collected,
mo/dd/ r
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 10-28-15 (first event sampled)
Total Event Precipitation (inches):.5
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S WU-248-102107
Page 1 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee)
gDEc A91f
(Date)
SWU-248-102107
Page 2 of 2

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analvtical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2015
(This monitoring report is due at the Division no Iater than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert 4012
PLEASE SIGN ON THE REVERSE ->
Outfa I I
No.
Date
Sample Collected,
mo/dd/ r
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Crease,
m /L
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
5
10-28-15
<10
<5.0 117.0
2.8
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier I or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _yes X no
(if yes, complete Part B)
Part B. Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample Collected,
mo/dd/vr
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
Note: 1 f you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier I or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 10-28-15 (first event sampled)
Total Event Precipitation (inches):.5
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S W U-248-102107
Page 1 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee)
,F
(Date)
S W U-248-102107
Page 2 of 2

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analvtical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2015
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/W W cent #012
PLEASE SIGN ON THE REVERSE 4
O utfa 1I
No.
Date
Sample Collected,
mo/dd/yr
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
m /L
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
1
10-28-15
<10.0
<5.0
6.9
5.7
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier I or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ ves X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activitv onitoring Requirements
O u tfa i I
No.
Date
Sample Collected,
mo/dd/ yr
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value. or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Pen -nit text.
STORM EVENT CHARACTERISTICS:
Date 10-28-15 (first event sampled)
Total Event Precipitation (inches):.5
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S W U-248-102107
Page 1 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee)
8 per ZaiS
(Date)
S W U-24 8-102107
Page 2 of 2

GENERAL PERMIT NO. NCG120000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2015
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert #067
PLEASE SIGN ON THE REVERSE 4
ll
OutfaIE�
N61
�: ° - -.Date - :--.
Sample Collected;,
"mo/ddlyr
, 003,40
_, _,:� '00556
00400
00530
-Chemical_Oxygen Demand, �,
m /L
.;:., Oil4nd"Grease;
mg/L.
.pH;
Standard units
Total Suspended Solids,
m /L
Benchtarks
-
120'`
30
6 0 - 9;0"
100
1
03-26-15
<25.0
<5.0
6.2
6.5
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier I or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes X no
(if yes; complete Part B)
Part B: Vehicle Maintenance Activity onitoring Requirements
utfa11.1.,
Date' :„ ...
Sample Collected;
.'-mo/dd/vr
00556
00530
'00400
Oil and:Grease,
m /L
Total' Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage;
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS: RCLi{
Date 03-26-15 (first event sampled) GI ED
Total Event Precipitation (inches):.24 APR 2
CENTRA
Date (list each additional event sampled this reporting fPA
M amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENRI DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S W U-248-102107
Page 1 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee)
/Y IP010 C 20/S
(Date)
SW U-248-102 l 07
Page 2 of 2

GENERAL PERMIT NO. NCG120000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analvtical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2015
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab 4NC/WW cert #067
PLEASE SIGN ON THE REVERSE 4
Outfall
No.
Date
Sample Collected,
moldd/ r
00340
00556
00400
00530
Chemical Oxygen Demand,
m IL
Oil and Grease,
m /L
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
2
03-26-15
<25.0
<5.0
6.5
9.6
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? —yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements
Outfall
No.
Date
Sample Collected,
mo/dd/ r
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m IL
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
Note: if you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier I or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 03-26-15 (first event sampled)
Total Event Precipitation (inches):.24
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
SWU-248-102107
Page 1 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee)
/f AIM' ZP/,S
(Date)
S WU-248-102107
Page 2 of 2

1W . R ...
aceAnalytical
wwwcpacelabacom
Sam Vedder
Grifols Therapeutics, Inc.
8368 US 70 West
Clayton, NC 27520
Project: Monthly Stormwater Outfalls
Pace Project No.: 92243016
Sample: Outfall #1
Parameters
Oil and Grease
Total Suspended Solids
Chemical Oxygen Demand
Sample: Outfall #2
Parameters
Oil and Grease
Total Suspended Solids
Chemical Oxygen Demand
Laboratory Report
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
Page 1 of 1
Report Date: 04/02/2015
Date Received: 03/27/2015
Lab ID: 92243016001 Collected.
03/26115 13:35
Matrix: Water
Results
Units
Report Limit
Analyzed
Qualifiers
ND
mg/L
5.0
04/01/15 09:48
6.5
mg1L
4.5
03131/1510:28
ND
mg1L
25.0
03/30/15 08:50
Lab
ID: 92243016002
Collected: 03126/15 13:45
Matrix: Water
Results
Units
Report Limit
Analyzed
Qualifiers
ND
mg/L
5.0
04/01/15 09:48
9.6
mg/1-
2.5
03/31/1510:28
ND
mg/L
25.0
03/30115 08:50
Reviewed by:x
Nicole Gasiorowski
[e-mail]
Raleigh Certification IDs
6701 Conference Drive, Raleigh, NC 27607
North Carolina Wastewater Certification #: 67
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
North Carolina Bioassay Certification #: 16
North Carolina Drinking Water Certification #: 37731
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
West Virginia Certification #: 357
VirginiaNELAP Certification #: 460221
Page 1 of 3

+
aceAnallca1
Document Name: Sample Condition Upon
Receipt SCUR
Document Revised: April 04, 2013
Page 1 of 2
w� Dom
Document No,.
issuing Authorities:
F-RAL•-001-4evA2
Pace Asheville Quality Office
Client Name:
Where Received: Ej Huntersville (] Asheville
(] Eden
6.
Ralelgh
Courier (Circle): • Fed Ex UPS USPS Client
Commercial
.
Other
Custody9sat on CooleriBox Present: [] yes 0 no
Seats Intact:
yes
no
Pecking Material: D Bubble Wrap B e Bags None Other
Circle Thermometer used: iR Gun/22085387 A0 of Ica: Wot Blue
10
tone
sampleaon W. caatfng process has begun
IR Oun Sao 5�1
Temp Correction Factor. Add 1 ubtrac 0 + G
Corrected Cooler Temp., C HIoiogieal Tissue, is Frdzenr Yes WA
Temp. should be above haazing to 8.O Comments,
Date and nIt a s o parson examining
Qe t e P e $tja
chock,
Chaln of Castod Present:
AY, ON,
• OWA
4. - - - -
Chain of Custod •Fifl6d Out:
6yo ❑Na
E3wA
2. '
Chain of Custody Relln tdshed:
6y,, ON,
OHIA
3.
Sam !er Name & Signature on COC:
ea ONO
❑WA
4.
Sam lesArrived within bold Time:
Yea ONO
OWA
5.
Short Hold Time Anal Is tl2trr :
CIYes t
OWA
B.
Rush Turn Around Time Requested:
❑Ysa No
E INIA
1.
Sufficient Volume:
Yea 13HO
OWA
B.
Correct Containers Used:
-Face Containers Used:
Yee ONO
w 0No
OWA
❑WA
9. '
Containers Intact
Y1s ON.
OWA
10.
Filtered volume•reoelved for Dissolved tests
OYes ONo
VWA
11.
Sample Labels match COC:
-Includes date1Ume1lDlAnal sEs Matrix: __A
arm
OVA
12.
All contaloara needing preserve0on have Gwen ehacked.
All conterners needing preservatlon are found to be In
compliance vdth EPA recommendation.
exceptions: VOA, od"orm,TOO, 040,WWROtwatorj
You ©Ne
Yee ONO
yes ONO
E7WA
ONlA
13.
Samples chocked for deehkxlnatlon:
Yes ❑No
OWA
14.
Heads ace In VOA Vfela >Umm :
Gres ❑Na
A
16.
Trip Blank Present:
Trip Blank Custody Seals Present
Paco Trip Blank Lot # Of urchased : -
❑Yoi ONO
❑Yea PRO
7w,.A
16.
Client Notification/ Resolution: Field Data Required? Y 1 N
Parson Contacted: Datefii ie:
Comments! ReaDiUWn:
SCURFiSRF
Review::
pate:
Note: Whenaver there Is a discrepancy affecting North Carolina compliance
samples, a Dopy of this forni vAll be sent to the North Carolina DEHNR
Certification Office ( is out of hold. Incorrect preservative, out of temp,
Incorrect Containers)
,WO#:92243016
II I I� II I III I!I 1pl111
Page 2 of 3

aceAnaljftal
www,pacelaits,cmn
6701 Conference Drive, Raleigh, NC 27607
ph: [phone], fax: [phone]
NCWW Cen#87, NCDW CertR37731
Chain of Custody wO# g2JZg3 LLy
Report Resuitta To, Bill To: J�
Company: C.� h r_�o 15 -- - VeIJJe;,' Aea4 -
Address, 9 36f� U5 14 w y 76 - -
—D., )rj t r1 .. _t kite
Ann Z�&rn. VMdt ✓`
Phono: q!-q' 5q .. qj bS
Fax.
Sampled by (signature):
IrTce:'yProject R�.'dol a`1C� ll 5
Project Number:
Pur Order #:
tandard Report Delivery
❑ Flush Report Delivery (wlsurcharge)
"Rush projects are sub)W to prbr approval by
the laboratory
Re uested Due Date:
4,r;s4d: ?hv�i' wiy(i'Kfn•
+.ti s,. ( 7+ �0'�,,7
L t�., �.11..
•l' +,:�,�,x.n i"r ii�•k: [,,✓.. �h
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-y�'rhf�.(=lli.r..L ��.�C•:1 �r1
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rl, �E�rf—�+.f5•.:.y
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0 Yes ❑ No ❑ We
Base prom. }127
❑ Yes ❑ No ❑ Wa
Page 3 of 3

4
Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit Ne NCG060000 or Certificate of Coverage No.: N CG060039
Facility Name: Grifols Therapeutics
County: Johnston County Phone No. 919-359-5473
Inspector: David S. Graham
Date of Inspection: 312612015
By this signature, I certify that this report is accurate and complete to the best of my knowledge:
(Signature of Permittee or Designee)
1.Outfall Description
Outfall No. 2 Structure (pipe, ditch, etc.) ditch exiting existing pond
Receiving Stream: tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _ Clear with a light brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 0 3 4 5 6 7 8 9 10
Page 1
SWU-242-020705

5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
O 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where s no solids and 10 is extremely muddy:
1 2 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes G
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? YesG)
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? YeQ
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes No
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SWU-242-020705

`o�oF \NA F9 G
r
aviql:� Y
Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
RECEIVED
APR 2 8 2015
CENTRAL FILES
DWR SECTION
Permit Nc NCGO60000 or Certificate of Coverage No.: N CG060039
Facility Name: Grifols Therapeutics
County: Johnston County Phone No.919-359-5473
Inspector: David S. Graham
Date of Inspection: 3/26/2015
By this signature, I certify that this report is accurate and complete to the best of my knowledge. -
(Signature of Permittee or Designee)
1I.Outfall Description
Outfall No. 1 Structure (pipe, ditch, etc.) Stream
Receiving Stream: tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _ Clear with a light brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 0 4 5 6 7 8 9 10
Page 1
SWU-242-020705

5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
O 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where J.Ls no solids and 10 is extremely muddy:
1 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes G
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes(D
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? YdQ
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes G
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SWU-242-020705

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG06_&53q
FACILITY NAME )am Ens
PERSON COLLECTING SA ES
CERTIFIED LABORATORY Lab # l
Lab #
Part A: Specific Monitoring Requirements
SAMPLES COLLECTED DURING CALENDAR YEAR:
(This monitoring report is due at the Division no later than 30 da s from
the date the facility receives th� .sfmpling results from the laboratory.)
COUNTY Cj4et - iA)A^
PHONE NO. (}.) —
PLEASE SIGN ON THE REVERSE 4
;O' tfall x
No
k
' Date
Sa ple
�Colle to ed, .
�,jmo/dd/ r�,
f 'Y00530 ,
4x,!00400
r ��00340
"005S6
31'6l'GA
total-Susie
�SoI ds,
..m'
pH,
Standard units'
Chemical Uzygena 1
'Dem.
v -t m
=, OiLandGrease,
-'mg
Fecal Coliform,
Colomeper 100`ml }
$ericlitnark
" „i - 100
; Witliiii16:0`=.9:0's
WW- 20y
30. -
1000'
I,
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Pennit text. R EE C E,v E D
Did this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes no 1�
(if yes, complete Part B) DEC 2 9 2014
Part B: Vehicle Maintenance Activitv Monitoring Requirements
CENTRAL FILES
SECTION
Outfall
No":Y
D"aie _ k r
Sample'C�llected
-ALR 00556 ::
- 0053fl
00400
tti4 "Otl andiGrease �'-lotal
01 ' r+t:
5tispen`dedtSolids
N m L
'°,pH,"� m'.iz
Sta lard unit'M �
NewAMotor OilUsage; `
Annual ave a'e: g3lli`noY:
Beiicliniiirk
" "
30 7 X
O'->9-0.
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS: Mail Original and one copy to:
Division of Water Quality
Date (first event sampled) Attn: DWQ Central Files
Total Event Precipitation (inches): 1, iY 1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
S W U-249-102107
Page I of 2

STORMWATER DISCHARGE OUTF'ALL (SDO)
MONITORING REPORT
,ERAL PERMIT NO. NCG060000
tTIFICATE OF COVERAGE NO. NCG06 0;3
FACILITY NAME )1
PERSON COLLECTING SAMPLES
CERTIFIED LABORATORY Lab #
Lab #
Part A: Specific Monitoring Requirements
SAMPLES COLLECTED DURING CALENDAR YEAR: r
(This monitoring report is due at the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY
PHONE NO. ( )
PLEASE SIGN ON THE REVERSE 4
Outfall -
N6.-
Date
Sample
Collected,
mo/dd/ r
00530
00400
00340
00556
31616
Total Suspended
Solids,:
pH,
Standard units
Chemical Oxygen
Demand,
nt
Oil and Grease,-
mg/L
Fecal Coliform,
Colonies per 100 ml
Benchmark.:
-
100
Within 6.0 — 9.0
120
30
1000
r
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
Did this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes -�no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activit Monitoring Requirements
Outfall
No. =
Date
, -_Sample .Collected,
mo/dd/ r
00556
' 00530
00400
Oil and Grease,
f m
" Total Suspended Solids,
pH,
Standard units
isfe�r ]Motor Oil Usage,
:Annual average al/mo
Benchmark
-
30
100 `'
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date (first event sampled)
Total Event Precipitation (inches):
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Division of Water Quality
Attn: DWQ Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
SWU-249-102107
Page 1 of 2

"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee)
12
(Date)
S W U-249- t 02 l 07
Page 2 of 2

RECEIVED
o�0F WArfR DEC 10 Z01'+
CENTRAL FILES
Y DWR SECTION
Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit Nc NCG060000 or Certificate of Coverage No.: N CG060039
Facility Name: Grifols Therapeutics
County: Johnston Count Phone No.919-359-5473
Inspector: David S. Graham
Date of Inspection: 11/17/2014
By this signature, I certify that this report is accurate and complete to the best of my knowledge:
re_
1.Outfall Description
Outfall No. 1 Structure (pipe, ditch, etc.) Stream
Receiving Stream: tributary to the Neuse River
Describe the industrial activities that occur within the outfail drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _ Clear with a light brown tint
3. Odor
Describe any distinct odors that the discharge may have (Le., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 O 4 5 6 7 8 9 10
Page 1
SWU-242-020705

5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
O 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where no solids and 10 is extremely muddy:
1 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes G
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes No
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? YdQ
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes No
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SWU-242-020705

GENERAL PERMIT NO. NCG120000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2014
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert 067
PLEASE SIGN ON THE REVERSE 4
Ou tfa I I
No.
Date
Sample Collected,
mo/dd/vr
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
m IL
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
1
11-17-14
<25.0
<5.0
6.66
8.2
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes no
(if yes, complete Part 13)
Part B: Vehicle Maintenance Activity MonitorinZ Requirements
Outfall
No.
Date
Sample Collected,
mo/dd/vr
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
l00
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 11-17-14 (first event sampled)
Total Event Precipitation (inches): .2
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S W U-248-102107
Page 1 of 2

A
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
/Z v y 0/y
C(Date)j
S W U-248-102107
Page 2 of 2

o�oF�wa�rFR4�
0lii;�,04111WC
Page 14: Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit Nc NCGO60000 or Certificate of Coverage No.: N CG060039
Facility Name: . Grifols Therapeutics
County: Johnston County Phone No.919-359-5473
Inspector: David S. Graham
Date of Inspection: 11/17/2014
By this signature, I certify that this report is accurate and complete to the best of my knowledge:
[(Signature oLFrerm
nee
1.Outfall Description
Outfall No. 2 Structure (pipe, ditch, etc.) ditch exiting existing pond
Receiving Stream: tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _ Clear with a light brown tint
3. Odor
Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 O 3 4 5 6 7 8 9 10
Page 1
SW U-242-020705

5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
is no solids and 10 is the surface covered with floating solids:
2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where no solids and 10 is extremely muddy:
1 6 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes No
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? YeQ
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes G
11. Other Obvious Indicators of Stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may be
indicative of conditions that warrant further investigation and corrective action.
Page 2
SWU-242-020705

GENERAL PERMIT NO. NCG120000
CERTIFICATE OF COVERAGE NO. NCGO60039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analvtical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2014
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert #067
PLEASE SIGN ON THE REVERSE 4
Ou t fa I I
No.
Date
Sample Collected,
mo/dd/vr
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
m /L
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
-
120
30
6.0 — 9.0
100
2
11-17-14
<25.0
<5.0
6.99
3.5
Note: if you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes _no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity onitoring Re uirements
Outfall
No.
Date
Sample Collected,
mo/dd/vr
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m /L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
-
30
100
6.0 — 9.0
-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 11-17-14 (first event sampled)
Total Event Precipitation (inches): .2
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S W U-248-102107
Page I of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
z0/
{'Date)=�
S WU-248-102107
Page 2 of 2

1
44
(� aceAnalytr'cal
xnvwpeoelaftcom
Laboratory Report
Sam Vedder
Grifols Therapeutics, Inc.
8368 US 70 West
Clayton, NC 27520
Project: Stormwater
Pace Project No.: 92225914
Sample: Outfall #1
Lab ID:
92225914001 Collected:
11/17/14 10:30
Parameters
Results
Units Report Limit
Analyzed
Oil and Grease
ND mg/L
5.0
11/21/14 07:23
Total Suspended Solids
8.2 mg1L
4.2
11/18/14 08:54
Chemical Oxygen Demand
ND mg/L
25.0
11/18/14 08:50
Sample: Outfail #2
Lab ID: 92225914002 Collected:
11/17/14 10:45
Parameters
Results
Units Report Limit
Analyzed
Oil and Grease
ND mg/L
5.0
11/21/14 07:23
Total Suspended Solids
3.5 mg1L
2.5
11I18/14 08:54
Chemical Oxygen Demand
N❑ mg1L
25.0
11/18/14 08:50
Reviewed by:/Y1IJIOZ"
Nicole Gasiorowski
[e-mail]
Raleigh Certification IDs
6701 Conference Drive, Raleigh, NC 27607
North Carolina Wastewater Certification #: 67
Charlotte Certification Ids
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
Page 1 of 1
Report Date: 11/21/2014
Date Received: 11/18/2014
Matrix: Water
Qualifiers
Matrix: Water
Qualifiers
North Carolina Bioassay Certification #: 16
North Carolina Drinking Water Certification #: 37731
FloridalNELAP Certification #: E87627
Kentucky UST Certification #: 84
West Virginia Certification #: 357
Virginia/VELAP Certification #; 460221
Page 1 of 3

{
aceAnalWical
www.pacelabs.com
67p1 Conference Drive, Raleigh, NC 27607
ph: (m) 83"984, tax: [phone]
NCWW Ce067, NCDW Cert#37731
Chain of Custody
Report Results To:
Company:. G hr TO 5
ddress: S 3 S LC 5 70 IW&s-V
US, C // .� Q �
Attn: C �Qnp V Qr
Prone: R lq - _ 25 q - 9 1 U +8
Fax:
Sampled by (signature):
gZZZ��I
w.o. # ;
Bill Two:: , r J /� 1 J
f'v1- v-eJ o►' Ann 7� Project Reference: Al Wet jet -
Project Num r:
Purchas Orderly:
tandard Report Delivery
❑ Rush Report Delivery (wlsurcharge)
"Rush projects are subject to prior approval by
iho laboratory
Requested Due Dale:
Sampte Descriptfori t
t�Ba
�,5tart Date_i:nd�Date
, t r
' Start€Tlnre �
f..dEnciJIme t '
Ma1�ix�
SYW.OW. SW
ow,
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3
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CO b 755 al 6reoTe
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e ved by (signature)
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Time
06La
signature)
a ived b sig 1 e
Date
Time
PlInquIshed
sign u )
Received by (signatu)
Date
Time
Recelpt Conditions (Lab Use Only)
❑ 4t2°C ❑ Temp:6,--5--°C
Res. Chlorine.
❑ Absent ❑ Present ❑ nla
Acid preserv. <2?
❑ Yes ❑ No ❑ rVe
Base preserv. >12?
11 Yes 0 No ❑ Wage 3 of 3

"
��
Document Name: Sample Condition Upon
Document Revised: April 04, 2013
Ana! icah
Recel t SCUR
Pa e 1 of 2
Document.No.:
Issulfig Authorities:.
""'
-F-RAL-CS-001-rev.02 •
Pace Asheville Quality Office
Client Name:�n _
Where Received: El Huntersville D Asheville 0 Eden' '/j Raleigh
Courier (Circle): - Fed Ex UPS USPS Client Commercial (Lace)Other
Custody Seal on CoolerfBox Present: ❑ yes V no Seals Intact: yes. no
Packing Material; Bubble Wrap E] Bubble Bags 0 No�w5et
Other
Circle Thermometor' : 2206538 Used: IR Gun f1e of too;BlueNone D Samples on Ice, cooling process has begun
IR Gun Backup/122065371
Temp Correction Factor: Add Subtract •
Corrected Cosier Temp.: C
Temp.should be abov© freaxirttj to WC
Q� U C
Biological Tissue Is Froieni You ttodNJA
Cornments:.
Date and Initials of perpon examining
a co 1 ! pr
check:
Chain of Custody Present:
Yes• [IN, • 6N1A
T.
Chain of Custod Filled Out:
es ON;
❑i•NA
2.
Chainof Custod� Relin Ulshed:
es: ❑No
❑k[A
3.
Sam'ler Name & Signature on COO:
Yes ONO
Ow
4..
Sam Ales Arrived within Hold Time:
Yes ON.
❑wA
5..
Short Hold Time Ana! sls <72hr :
ClYesPfNo
❑NIA
6.
Rush Turn'AroundTime. Re ueste'd:
Dyes No
❑WA
i.
Suff(clent Volume:
VYes ONO
❑WA
8.
Correct Containers Used:
-Pace Contalners Used:
Yes ONO
66 ONO
QWA
❑WA
9. .
,
Contalners Intact:
Yes ON,__
❑WA
10.
Filtered volume -received for Dissolved tests
❑Yes ONO
fVIA
11.
Sample Labels match COC:
-Includes dateltimellDlAnal sis Matrix
Yes Qtto
�S-
❑N!A
12.
ZI contalners needing preservation have been checked.
All Contalners needing preservation are found to be In
compliance with EPA recommendation.
exceptions: VOA, colitorm, TOC, ORG, W1-DR0 (water)
f Yes ❑hlo
rYes ONO
Ayes ONO,
❑WA
❑ WA
13.
Samples checked for dechlorination:
Yes ONO
❑WA
14.
Beads ace In VOA Vials >6mm :
❑Yes ONO
h/A
15.
Trip Blarik Present:
Trip Blank Custody Seals Present
Pace Trip Blank Lot # if urchased :
[]Yes ❑No
❑Yes ONO
14A
,C.1NlA
16,
Client Notification! Resolution: Field Data Required? Y I N
Person Contacted:. DatelTime:
Commen{sl Resolution:
SCURFlSRF
Review::
Data:
Note; Whenever there Is a discrepancy affecting North Carolina compliance
samples, a copy of this form will be sent to the North Carolina DEHNR
Certification -Office (Le out of hold, incorrect preservaf'rve, out of temp.
Incorrect containers)
ll?'L..yK, 4 s '�}f {{{{1ir•�1y'�ji(�i :i7.� 4��
II{j{j II II111I!! IIjIjIIII IIjj lY 1_-.f€a tt s, ♦�4 F�il�'!
� ������I1�{IkIl��ill �1�� � •� it t�1,v it
-9222S914yt d , L`,'.! `• r h .'t ,I
Page 2 of 3.

GRIFOLs
8368 U.S. 70 Bus. West
Clayton, NC 27520
David S. Graham
ESS III
Tel [phone]
Fax [phone]
Cell 919.724.5979
[e-mail]
December 2, 2014
Division of Water Quality
Attn: DWQ Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
To whom it may concern:
Attached you will find the analytical SDQ monitoring report following a representative storm event for the Grifols
Therapeutics Clayton, NC facility. If you have any questions, please don't hesitate to contact me at 919-359-5473
Sincerely,
David S. Graham
ESS III

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
CERTIFICATE OF COVERAGE NO. NCG100 0 3 2 RECEIVS&PLES COLLECTED DURING CALENDAR YEAR: 2014
DEC 10 20 (This monitoring report shall be received by the Division no later than 30 days
Worn the date the facility receives the sampling results from the laboratory.)
CENTRAL FILES
FACILITY NAME _Good News Auto Parts and Salvage, Inc. OWR SECTION
PERSON COLLECTING SAMPLE(S) N/A
CERTIFIED LABORATORY(S) TestAmerica Pensacola Lab # 314
Lab #
Part A: Stormwater Benchmarks and Monitoring Results
COUNTY 44erKYrrd Z�
PHONE NO.( 800 ) 678-3098
PLEASE REMEMBER TO SIGN ON THE REVERSE 4
For sampling periods with no discharge, you must submit this discharge monitoring form noting "No Flow" or "No Discharge" within
30 days of the end of that period to comply with permit reporting requirements.
Outfall
Date
,_ 00400
00530
-
- - -
7._70z3
U1051 :�
�78i41 _�
No
Sample Collected,*
Total
pH
:Total Suspended
Nonpolar
Ethylene Glycol,
` 'Lead, Total``
Total Toxic
r�,��
I mo/dd/year
�S
Ramfall,f
�'�#e
. Standards
x r
--Solids (TS5)``
O&G/TPH
mg/L
Recoverable,
3
-
a ° r
inches
Units
mg
(Method 1664
`' mg/L
Organics ,
•:.�,
mg/L
MTN
Benchmark
6 0.."9 0
100 50
15
{Tiers:2 and°3);FO.t}3
`
>: :.
001
11/06/2014
1.0
6.9
23
<2.6
1.4
0.013
Exempt
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses in the General
Permit.
1See If pH values outside this range are recorded in sampled Stormwater discharges, but ambient precipitation pH levels are lower, then the lower threshold of this benchmark
range is the pH of the precipitation (within instrument accuracy) instead of 6 S.U. Readings from an on -site or local rain gauge (or local precipitation data) must be documented
to demonstrate background concentrations were below the benchmark pH range of 6-9.
2See General Permit text to identify whether the more protective benchmark applies for especially sensitive receiving waters.
3For purposes of this permit the definition of Total Toxic Organics is that list as stated in Appendix D, Table II of Chapter 40 Code of Federal Regulations (CFR) Part 122.
Form SWU-251, last revised October 25, 2012
Page 1 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Facilities that incorporate a solvent management plan into the Stormwater Pollution Prevention Plan may request that DWQ waive monitoring of total toxic organics. The solvent
management plan shall include a list of the total toxic organic compounds used and the other elements listed in the General Permit. For those facilities allowed such a waiver, the
discharger shall sign the following certification statement:
Solvent Management Plan Certification Statement
"Based upon my inquiry of the person or persons directly responsible for managing compliance with the permit monitoring requirement for total toxic organics (TTO),
certify that to the best of my knowledge and belief, no dumping of concentrated toxic organics into the stormwater or areas which are exposed to rainfall or stormwater
runoff has occurred since filing the last discharge monitoring report. I further certify that this facility is implementing all the provisions of the solvent management plan
included in the Stormwater Pollution Prevention Plan."
49 "ZZ4, �desr
Name (Print name)
�/-1U
Title (Print title)
Signature Date
Mail Original and one copy to:
Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or
those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete.
am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
7�e� AIIIZ4��� 1,:Z-f-41
(Signature of Permittee or Designee) (Date)
Form SWU-251, lost revised October 25, 2012
Page 2 of 2

GENERAL PERMIT NO. NCG120000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2013
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/W W cert 4067
PLEASE SIGN ON THE REVERSE ->
rt2utfall;:
1\'0 -
-_v
:=
_Sampiellect
-dt�-•-]� '...
00340°
-
Chemical OjgenilDemand,
_L
m /L_4
�OiIland�Grease
NW /L-_ ,}�
_. . ----
r ,;,;IrH,'! n ,,'TotallSus�iendediSolids,
,fie
Standard units ..rc... ;
°.
- `--
din /L,.�.
Benchmark.:-
�._'" ?4
�i..::::120 ..::.s:....d���
�_..30z -
6:0 `.9:0 w_x..
x. :.100
1
4-15-14
<25.0
<5.0
6.68
15.9
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _yes _no
(if yes. complete Part B)
Part B: Vehicle Maintenance Activity Monitorinp_ Requirements
Outfall
Noti
,'•�f-
;Date <
Samle'Collected
p
00556 ,
:. 0053.Q+:
00400
"^
Oil aiiii�Grease,TotaE
.,�'f - .t'.'r1 '.`Y''•.M -
Suspendyed Solids,pH,
t . .. •;sr; '..y3'L "y .WY ae K -
'4 "E""r -p "4
_Standard units
Ne►v MotorxOiE;Usage;
.r.fJu�"•i'- 4P:
�Avera a annuals` al/mo
�e
Benchmarks
h..
R-'30I
1
M�
xx� _ �.t;µi
RECEi V ED
MAY 0 7 Z014
CENTRAL FILES
DWQIBOG
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier I or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 4-15-14 (First event sampled) Mail Original and one copy to:
Total Event Precipitation (inches):.50 Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Date (list each additional event sampled this reporting period, and rainfall amount) Raleigh, NC 27699-1617
Total Event Precipitation (inches):
SWU-248-102107
Page I of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee)
05Zo2/ iy
(Date)
S W U-248-102107
Page 2 of 2

i 1 -
wnrF�9Qc
O liiWAIIWY
Page 14: Stormwater Discharge Out#all (SDO)
Qualitative Monitoring Report
Permit Nc NCGO60000 or Certificate of Coverage No.: N CGO60039
Facility Name: Grifols Therapeutics
County: Johnston County Phone No.919-359-5473 -
Inspector: David S. Graham
Date of Inspection: 4/15/2014
By this signature, I certify that this report is accurate and complete to the best of my knowledge:
(Signature of Permittee or Designee)
1.Outfali Description
Outfall No. 1 Structure (pipe, ditch, etc.)
Receiving Stream: tributary to the Neuse River
Stream
Describe the industrial activities that occur within the outfall drainage area: Pharmaceutical Mfg.
2. Color
Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium,
dark) as descriptors: _ Clear with a light brown tint
3. Odor
Describe any disfinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor,
etc.): None
4. Clarity
Choose the number which best describes the clarity of the discharge where 1 is clear and 10 is very
cloudy:
1 2 0 4 5 6 7 8 9 10
SWU-242-020705
Page 1

r
5. Floating Solids
Choose the number which best describes the amount of floating solids in the stormwater discharge where
1 is no solids and 10 is the surface covered with floating solids:
O 2 3 4 5 6 7 8 9 10
6. Suspended Solids
Choose the number which best describes the amount of suspended solids in the stormwater discharge
where 1,js no solids and 10 is extremely muddy:
1 3 4 5 6 7 8 9 10
7. Foam
Is there any foam in the stormwater discharge? Yes G
8. Oil Sheen
Is there an oil sheen in the stormwater discharge? Yes No
9. Deposition at Outfall
Is there deposition of material (sediment, etc.) at or immediately below the outfall? YEN
10. Erosion at Outfall
Is there erosion at or immediately below the outfall? Yes G
11. Other Obvious Indicators of stormwater Pollution
List and describe None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, deposition or erosion may
indicative of conditions that warrant further investigation and corrective action.
SWU-242-020705
Page 2

GRIFOLS
8368 U.S. 70 Bus. West
Clayton, NC 27620
David S. Graham
HES III
Tel [phone]
Fax [phone]
Cell 919.724.5979
[e-mail]
April 21, 2014
Division of Water Quality
Attn: DWQ Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
To whom it may concern:
Attached you will find the analytical SDQ monitoring report following a representative storm event for the Grifols
Therapeutics Clayton, NC facility. If you have any questions, please don't hesitate to contact me at 919-359-5473
Sincerely,
David S. Graham
ESS III

acmnalytical
wwwpecelahscom
Laboratory Report
Sam Vedder
Grifols Therapeutics, Inc.
8368 US 70 West
Clayton, NC 27520
Project: STORMWATER
Pace Project No.: 92197573
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
Page 1 of 1
Report Date: 04/18/2014
Date Received: 04/16/2014
Sample: OUTFALL #1
Lab ID:
92197573001 Collected:
04/15/14 11:30
Matrix: Water
Parameters
Results
Units Report Limit
Analyzed
Qualifiers
Oil and Grease
ND mglL
5.0
04/18114 07:53
Total Suspended Solids
15.9 mglL
2.8
04/16114 09:28
Chemical Oxygen Demand
ND mglL
25.0
04/16/14 09:23
Sample: OUTFALL #2
Lab ID:
92197573002 Collected:
04/15/14 11:45
Matrix: Water
Parameters
Results
Units Report Limit
Analyzed
Qualifiers
Oil and Grease
NO mg1L
5.0
04/18/14 07:53
Total Suspended Solids
8.2 mglL
2.6
04/16/14 09:29
Chemical Oxygen Demand
ND mg1L
25.0
04/16/14 09:23
Reviewed by: Y
Jon D Bradley
[e-mail]
Raleigh Certification Ill
6701 Conference Drive Raleigh, NC 27607
North Carolina Wastewater Certification #: 67
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
North Carolina Bioassay Certification #: 16
North Carolina Drinking Water Certification #: 37731
FloridalNELAP Certification #: E87627
Kentucky UST Certification #: 84
West Virginia Certification #: 357
VirgirriaNELAP Certification #: 460221
Page 1 of 3

aceAnalyfical" Chain of Custody
w.o. r
Ilnrrt.paralstrs.som
1 6701 Contcrmrco Drive, Raleigh. NC 27607
I.Ir (91 a) 834, 4-W. fax: (919) 88d.6497
lJuWW CM#67, NCOW Cert#37731
Roporl Results�o: TSV rk" U-Ae,/pi 1r ProJcctReferenco:Company: T
r-
Address:
Project Number:
P Order a:
Phone:ndartl Report Delivery
Fax: Qr Cl ` f=,S ❑ Rash Report Delivery (w/surcharp)
"Rush projects are wbiw to prior approvd by
Sampled by (signature): v me laboratory
Requested Due Dale:
R r by I e) ew v ;s gaatvo Dam Trw Utazkm
❑ Receipt
CCordox (La
l J •C
- — Res. Croodw
alirgm by (slg Lure) iv _by(.' t to Tine ❑ Absent ❑ Prowl O rdo
Acid praserv. <27
�fSuttrylnlpn ece-WbY(eignalurei Dam TYno ❑ Yea ❑ NO ❑ Ne
prowrv. �127 '
❑ Yoe ❑ No ❑ We
Page 3 of 3

vucumenr Name: Sample Condition Upon Document Revised; April 04, 2013
f'LAlral riaal Recel t SCUM Pape 1 of 2
Document No.: Issuing Authorities:
Client Name:
Where Received: i- Huntersvi)le ❑ Asheville Eden Raleigh
Courier (Circio): Fed Ex UPS USPS Cllenl Camasercial ace Other
Custody Seal on Coolerleox Present: [] yes {71 no Seals intact: Zyes E] no
Packing Material; 0 Dubblc Wrap _ age f i( No Other
Circle Thermometer Used: IR Gun 122065867T of Ice: Wet Blue None n samples an ice, cooling process hoe bagun
IR Gun 13a 1
Temp Collection Factor: Add 1 ubtraet U.0 C
Date and InWale of person oxamining
Corrected Coalur Temp.: I C
131ofogical
Tissue is Froxem Yes N. WA
t ! rqs +
L
Temp should be above froo2Jng to M
Cammonts:
check I
Chaln of custody Prosenl:
na ONO
❑NIA
1.
Chain of Custody Filled Out:
yes i _.
Q
2.
Chain cf C usiDdy Rclingaished:
Yes ONO
❑M
3.
Sam ler Name A Si nalure on COC:
Yaa ONO
CINIA
4.
,Ornpies Arrived within Hold Time;
ADYe, ONO
DWA
5.
Short Hold Time Analysis (<72hr):
❑Yes L44o
DWA
6,
_
Rush Turn Around Time Requested:
❑yea
❑NA
7.
Sufficient Volume:
Yea DN.
CJrOA
8.
COGeet Containers used:
Yes ❑No
GNrA
9.
-Pace Containers Used:
Y.. ONO
❑NIA
Containers Intact:
kYes ONO
❑w.a
10.
Filtered volume received for Dissolved tests
Dyes ON.
P<VA
11,
Sample LaWS match COC:
Yes ❑N,
❑ WA
12,
-Includes dateltlrnWIDlAnal s:s Matrix:
All containers needng prlservaltun have hoop checked.
}2fYse ❑No
❑WA
13.
N1 centalpers needing preservation are found to be in
y�Yes ❑Na
❑NM
compliance with EPA recommancatlon.
I
6xeWiona: VOA, co ilonn, 70C. 030, WI-DRO (water)
Yas ❑Na
Samples checked for dochlorinstlon:
/ Ycs ON.
0K/A
14-
1 lcadspacL in VOA V AIS (>6mtn L,
❑Yes ❑No
1A
15.
?'rip Blank Present:
❑Yes C1No
NIA
16
Trip plank Custody Seals Present
L)Yes ❑Nn
Z4A
Pace Tr�p Blank Lot # (it purchased): _
Client Notification) Resolution: Field Data Required? Y 1 N
Person Contacted: Date/Time:
Comments! Resclution:
SCURF ISRP Date:
Review:;
t4ole: Whenever there is a discreparcy affecting North Carolina compliance
sompiex, a copy of M9 form will be sent to the North Carolina DEHNR
Certlncabon Office (V.e out of hold, ioearrect praSOrvative. out of temp,
nmerect contoinafa)
Place label here
OR
Handwrite project number
(if no (abet evollable)
2(-)l 7'3- 7 -S
Page 2 of 3

NCDENR
North Carolina Department of Environment and Natural Resources
Beverly Eaves Perdue
Governor
David D. Auge, Manager, ESS
Talecris Biotherapeutics, Inc.
8368 US 70 West
Clayton, North Carolina 27520
Dear Mr. Auge:
Division of Water Quality
Coleen N. Sullins Dee Freeman
Director Secretary
March 14, 2011
Subject: Compliance Evaluation Inspection
Talecris Wastewater Collection System
Permit Number WQCSD0313
Stormwater Permit Number_NCG060039
Johnston County
I, Mitch Hayes, of the Raleigh Regional Office conducted the evaluation inspections for the
subject wastewater collection system and the stormwater permit on January 24, 2011. 1 appreciate the
time and assistance that you and other Talecris staff provided with this inspection. Please find the
attached Basinwide Information Management System (BIMS) checklist summarizing the inspection.
Below is a list of findings and recommendations developed from the inspection:
Wastewater Collection Deemed Permit WQCSD0313
1. The Water Pollution Control System Operators Certification Commission has not classified the
wastewater collection system and therefore an Operator in Responsible Charge (ORC) and
back-up ORC are not required. Basinwide Information Management System (BIMS) does list.
you, David Auge, as the contact person for the collection system.
2. The subject permit was issued and became effective on March 01, 2000. Adoption of deemed
permit rules became effective April 17, 2006. All deemed permitted facilities are required to
adhere to the requirements and procedures for permitting, operation and maintenance of
collection systems. A copy of the deemed permit was handed to you during inspection.
3. A collection system map has been developed and includes all required parameters except
direction of flow. You stated that direction of flow would be added to the map. Please ensure
to update the map when new lines or pump stations are added.
4. A review of logbooks and records indicated the following:
a) An operation and maintenance plan has been developed. This plan includes spill
response and preventative maintenance procedures. The deemed collection permit does
not require line cleaning however, line cleaning is considered one type of preventive
maintenance. Preventative maintenance is essential in meeting permit requirement (1).
b) A spill response plan has been developed and contains all the permit requirements.
c) There is one high -priority line listed for the collection system. This is an aerial line that
crosses the railroad tracks behind the main facility. The line is inspected once per every
six months as required.
North Carolina Divisbn of Water Quality Raleigh Regional Office Surface Water Protection Phone [phone] Customer gervice
Internet, www,ncwaterquality arg 1628 Mail Service Center Raleigh, NC 27699-1628 FAX [phone]
Location, 3800 Barrett Drive Raleigh, NC 27609 One
No rfflCarol i/na
An Equal Opportunity/AffirmativeActionEmployer— 50%Recycled110%Post ConsumerPaper ]�]atlthal[y

Tal�cris CEI
Page �2(dI I
.,.-,.,--,,d)—Grease=education is geared toward the kitchen staff. Employee education is documented
every 6 months. Educational flyers are placed in the facility on proper food and waste
disposal.
e) There have been 11 sanitary sewer overflows (SSO's) reported to this office during the
review period April 2005 through January 2011. Three SSO's were located at a manhole
near the pipe bridge due to a manhole collapse and broken line. The manhole and line
have been repaired. No spills have occurred at this site since the repair.
5. There are 8 pump stations within the collection system. A review of the pump stations
indicated the following:
a) There is no telemetry at any of the pump stations. Audible 1 visual alarms and pumps are
checked daily to ensure operation.
b) Six stations have contact information signs. The Alpha MP Courtyard temporary pump
station and the NFF pump station do not have contact information signs. Please ensure
that contact information signs are added to these two pump stations.
c) Pump Stations: Alpha MP Courtyard, number 2, 3, and 5 are simplex pump stations.
Pump station 5 had no power at the time of inspection due to a bad pump. Although
these pump stations do have emergency by pass capability, this office highly
recommends that spare pumps be provided at all simplex pump stations to avoid
possible overflows.
d) All control panels and wet wells have secured access. Ail pump stations have
functioning audible 1 visual alarms. There is one site generator located at the Alpha MP
Courtyard pump station. Fuel level is monitored daily. You stated that an on site
generator is being considered for pump station #1 (the WWTP pump station).
6. The aerial sewer line crossing over the railroad tracks is the only high priority line in the
collection system. According to your records, this line is inspected once every six months.
Stormwater permit NCG060039
7. Permit NCG060039 was reissued and became effective November 01, 2007 and expires
October 31, 2012. Permit renewal is required 180 days before expiration date, May 02, 2012.
A review of the permit requirements was conducted after the CEI for WQCSD0313. A copy of
the permit was on hand and contained all permit requirements.
8. Talecris is currently expanding its Clayton facility. This expansion includes new buildings,
roadways, and drainage features that are not shown on the facility site map. Please ensure
that any new additions are added to the map within one year of completion.
9. According to the permit, there are two Stormwater Discharge Outfalls (SDO's). SDO 001 is
located on the northeastern side of the property. SDO 001 receives flow from a stormwater
pond located on the eastern side of the main property. Areas draining into this pond as
depicted on the stormwater map include: E 500, F500, E800, E630, E620, F600, and building
300. The stormwater pond was being drained to clean out sediment at the time of inspection.
Any flow from the stormwater pond flows under railroad tracks and into a wetland area. There
was no discharge at the time of inspection. SDO 002 is the discharge of large pond located on
the northwestern side of the property. At the time of inspection, the pond was in the process of
being drained. This area will be allowed for a creek to reform and letting the area develop
back to a natural state. The outfall was not observed due to the ongoing construction. Areas
draining into SDO include the western half of the facility.
10. A copy of the permit was available for inspection. All elements of the stormwater pollution
prevention plan were being implemented. Schedules for facility site inspection and employee
training on spill response, cleanup procedures and preventative maintenance are generated
by computer.

Talecris CEI
Page J
11. Qualitative monitoring is done according to schedule. There is no vehicle maintenance
performed on site.
12.There have been 15 spills that have occurred during the review period April 2005 through
January 2011. This includes the 100 gallons of 50:50 propylene glycol: water spill on May 30,
2007 and the 6,033 pounds of ethylene glycol release on September 16, 2008. None of the
spills were repetitive. Problems are identified and corrected.
I would like to thank you and the staff of Talecris Biotherapeutics for their time and assistance with
this inspection. If you have any questions about the inspection or this letter, please contact me at
919.791.4261 or by email mitch.hayes@ncdenr.g_ov
Sincerely,
ci�v U[
Mitch Hayes
Environmental Specialist
Cc: Pe�rNt Files, Central Files

Compliance Inspection Report
Permit: NCG060039 Effective: 11/01/07 Expiration: 10/31/12 Owner: Talecris Biotherapeutics, Inc,
SOC: Effective: Expiration: Facility: Talecris Biotherapeutics, Inc.
County: Johnston 8368 Hwy 70 W
Region: Raleigh
Clayton NC 27520
Contact Person: Karen Cook Title: Manager Phone: [phone]
Directions to Facility:
System Classifications:
Primary ORC:
Secondary ORC(s):
On -Site Representative(s):
Certification:
24 hour contact name Karen H Cook
On -site representative David Auge
Related Permits:
WQCSD0313 Talecris Biotherapeutics, Inc. - Talecris Biotherapeutics, Inc.
NCO025453 Town of Clayton - Little Creek WWTP
Inspection Date: 01/24/2011 Entry Time: 10:30 AM Exit Time: 01:30 PM
Primary Inspector: Mitchell S Hayes
Secondary p ector(Ins s):
Phone:
Phone: [phone] ext 4802
Phone: [phone]
Phone: [phone]
Reason for Inspection: Routine Inspection Type: Compliance Evaluation
Permit Inspection Type: FoodlTobaccolSoapslCosmeticslPublic Warehousing
Stormwater Discharge COC
Facility Status: ■ Compliant ❑ Not Compliant
Question Areas:
0 Storm Water
(See attachment summary)
Page: 1

Permit: NCG060039 Owner - Facility: Talecris Biotherapeutics, Inc.
Inspection Date: 01/24/2011 Inspection Type: Compliance Evaluation Reason for Visit: Routine
Inspection Summary:
Permit NCGO60039 was reissued and became effective November 01, 2007 and expires October 31, 2012. Permit
renewal is required 180 days before expiration date, May 02, 2012.
Talecris is currently expanding its Clayton facility. This expansion includes new buildings, roadways, and drainage
features that are not shown on the facility site map.
According to the permit, there are two Stormwater Discharge Outfalls (SDO's). SDO 001 is located on the northeastern
side of the property. SDO 001 receives flow from a stormwater pond located on the eastern side of the main property.
Areas draining into this pond as depicted on the stormwater map include: E 500, F500, E800, E630, E620. F600, and
building 300. The stormwater pond was being drained to clean out sediment at the time of inspection, Any flow from the
stormwater pond flows under railroad tracks and into a wetland area. There was no discharge at the time of inspection.
SDO 002 is the discharge of large pond located on the northwestern side of the property. At the time of inspection, the
pond was in the process of being drained. This area will be allowed for a creek to reform and letting the area develop
back to a natural state. The outfall was not observed due to the ongoing construction. Areas draining into SDO include the
western half of the facility. There are other stormwater ponds constructed on the property due to the expansion and are
covered under NCG010000 permit.
A copy of the permit was available for inspection. All elements of the stormwater pollution prevention plan were being
implemented. Schedules for facility site inspection and employee training on spill response, cleanup procedures and
preventative maintenance are generated by computer.
There have been 15 spills that have occurred during the review period April 2005 through January 2011. This includes the
100 gallons of 50:50 propylene glycol: water spill on May 30, 2007 and the 6,033 pounds of ethylene glycol release on
September 16, 2008. None of the spills were repetitive. Problems are identified and corrected.
Page: 2

Permit: NCG060039 Owner - Facility: Taiecris 6iotherapeutics, Inc.
Inspection Date: 01/24/2011 Inspection Typo: Compliance Evaluation Reason for Visit: Routine
Stormwater Pollution Prevention Plan Yes No NA NE
Does the site have a Stormwater Pollution Prevention Plan?
■
❑
❑
❑
# Does the Plan include a General Location (USGS) map?
■
❑
❑
❑
# Does the Plan include a "Narrative Description of Practices"?
■
❑
❑
❑
# Does the Plan include a detailed site map including outfall locations and drainage areas?
■
Cl
❑
❑
# Does the Plan include a list of significant spills occurring during the past 3 years?
■
❑
❑
❑
# Has the facility evaluated feasible alternatives to current practices?
■
Cl
❑
❑
# Does the facility provide all necessary secondary containment?
■
❑
❑
❑
# Does the Plan include a BMP summary?
■
❑
❑
❑
# Does the Plan include a Spill Prevention and Response Plan (SPRP)?
■
❑
❑
❑
# Does the Plan include a Preventative Maintenance and Good Housekeeping Plan?
■
❑
❑
❑
# Does the facility provide and document Employee Training?
■
❑
❑
❑
# Does the Plan include a list of Responsible Party(s)?
■
❑
❑
❑
# Is the Plan reviewed and updated annually?
■
❑
❑
❑
# Does the Plan include a Stormwater Facility inspection Program?
■
❑
❑
❑
Has the Stormwater Pollution Prevention Plan been implemented?
❑
❑
❑
Comment: Karen Cook is listed as the responsible party. Facility is undergoing
expansion. Map will be updated as required.
Qualitative_ Monitoring
Yes
No
NA
NE
Has the facility conducted its Qualitative Monitoring semi-annually?
■
❑
❑
❑
Comment:
Permit and Outfalls
Yes
No
NA
NE
# Is a copy of the Permit and the Certificate of Coverage available at the site?
■
❑
❑
❑
# Were all outfalls observed during the inspection?
❑
■
❑
❑
# if the facility has representative outfall status, is it properly documented by the Division?
❑
❑
■
❑
# Has the facility evaluated all illicit (non stormwater) discharges?
■
Cl
❑
❑
Comment: SDO 002 was not observed due to earth moving equipement operating in
the area.
Page: 3