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NC0026441_Report_19910516
MPDES DOCUMENT SCANNING COVER SHEET NPDES Permit: NCO026441 Siler City WWTP Document Type: Permit Issuance Wasteload Allocation Authorization to Construct (AtC) Permit Modification Engineering Alternatives Analysis 201 Facilities Plan Instream Assessment (SOC) -Rocky-River-subbasin nutrient budget Permit History Date Range: Document Date: May 16, 1991 THIS DOCUMENT 15 PRINTED ON REUSE PAPER - IGNORE ANY CONTENT ON THE REVERSE SIDE I State of North Carolina Department of Environment, Health, and Natural Resources Division of Environmental Management 512 North Salisbury Street • Raleigh, North Carolina 27604 James G. Martin, Governor George T. Everett, Ph.D. William W. Cobey, Jr., Secretary Director May 16, 1991 Mr. Jim Greenfield WLA Coordinator U.S. EPA, Water Division Region IV 345 Courtland Street Atlanta, GA 30365 Subject: Rocky River QUAL2E and nutrient budget analyses Cape Fear River Basin Chatham County Dear Mr. Greenfield: Enclosed, please find copies of the documents entitled "Town of Siler City WLA Modeling Analysis" and "Rocky River Subbasin Nutrient Budget (Chatham County)" for your review. You should note that the Division of Environmental Management (DEM) is planning on collecting AGPT samples in Loves Creek and the Rocky River this summer to validate the nutrient analysis, and the limits imposed on the Siler City WWTP. If you have questions or comments concerning either document, please do not hesitate to can Mike Scoville or me at (919)733-5083. Attachments J. r or Clements, hief W to Quality Section Pollution Prevention Pays P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone 919-733-7015 An Equal Opportunity Affirmative Action Employer ROCKY RIVER SUBBASIN NUTRIENT BUDGET (CHATHAM COUNTY) NORTH CAROLINA DEPARTMENT OF ENVIRONMENT, HEALTH AND NATURAL RESOURCES DIVISION OF ENVIRONMENTAL MANAGEMENT WATER QUALITY SECTION MAY. 1991 INTRODUCTION Nitrogen and phosphorus are important nutrients with respect to aquatic plant growth. Elevated nutrient levels are often associated with noxious algal blooms in aquatic systems. Numerous blooms have been observed in the lower reaches of the Rocky River in Chatham County during the last two years. According to the North Carolina Department of Environment, Health and Natural Resources (NCDEHNR) Raleigh Regional Office staff, the majority of the algal blooms occurred during the summer of 1990. The Town of Siler City WWTP discharges into Love's Creek, a tributary to the Rocky River (Figure 1). Samples collected on July 26, 1990 by the Raleigh Region- al Office in the Rocky River, downstream of the Love's Creek confluence, indicated high concentrations of chlorophyll A (44.0 ug/1). Also, nutrient analyses revealed elevated concentrations of total phosphorus (0.49 mg/1) and total nitrogen (5.9 mg/1) at this sampling location. Comprehensive sampling of the Rocky River was performed on August 3, 1990, by the Environmental Siences Branch (Appendix 1). Results indicated that high concentrations of total phosphorus occurred both upstream (0.13 mg/1) and down- stream (0.88 mg/1) of the Love's Creek confluence. However, high levels of total nitrogen (8.2 mg/1) were found only below the confluence with Love's Creek. In 1988 the Town of Siler City requested an expansion for its wastewater treatment plant to a wasteloow of 4.0 MGD from 1.8 MGD. A wasteload allocation (WLA) was performed for this expansion and permit limits were recommended based on a Level-B modeling analysis. However, due to public interest in this issue, a Level-C analysis was conducted to verify the previously recommended permit limita- tions at the expanded flow. The Level-C modeling analysis is documented in a memorandum from Mike Scoville dated November 1, 1990 (Appendix 2). The revised WLA resulted in more stringent permit limitations including a summer period total phosphorus limitation of 0.5 mg/1 as per NCAC 15A 2B .0211 (b)(3)(A), which states "the Commission or its designee may prohibit or limit any discharge of waste into surface waters if, in the opinion of the Director, the surface waters experience or the discharge would result in growths of microscopic vegetation such that the standard established pursuant to this Rule would be violated or the intended best usage of the waters would be impaired." This document develops a nutrient budget for total phosphorus and total nitrogen in the Rocky River subbasin. Nutrient loads are grouped into point source and non -point source categories. The analysis demonstrates a need to limit the total phosphorus input to the system from Siler City WWTP to 0.5 mg/l. ANALYSIS Non -point Source Loading Calculation Annual non -point loading estimates were calculated using land use information (U.S. Department of Agriculture, Soil Conservation Service, and Forest Service, 1985) and estimates of areal nutrient export: Li = Ai * Ri Where Li = total phosphorus or nitrogen loading (lbs/yr) Ai = area (acres) Ri = export coefficient (lbs/ac/yr) for phosphorus or nitrogen and i = land use The total phosphorus export coefficient estimates used in this analysis were derived from North Carolina Division of Environmental Management (NCDEM) guidance (Appendix 3). The total nitrogen export coefficient estimates for agricultural, urban and forest land were obtained from NCDEM Nutrient Management in the Lower Neuse Basin (1988). The atmospheric deposition export coefficient (applied to surface area of lakes) for total nitrogen was obtained from The Role of Acid Rain by the Environmental Defense Fund (1988). The results of the loading calculations are presented in Tables 1 and 2 and presented graphically in Figures 2 and 3. Note that although 23.1% of the basin is comprised of agricultural and pasture land, 59.2 % of non -point phosphorus and 51.3% of non -point nitrogen annual loading are attributed to these two land use types. According to U.S. Department of Agriculture, Soil Conservation Service and Forest Service (1985), the area of commercial forest land is decreasing. The conversion of forest land to cropland, urban land and water reduces the forest land base by about 2,000 acres each year, but is partly offset by tree planting on idle agricultural lands. This practice should stabilize the area of commercial forest land until 1995. The 1985 study further states that "cropland is the largest single contributor to the erosion and sedimentation problem in the area." Point -Source Loading Calculation Available data from September, 1989, to August, 1990, were retrieved from NCDEM's compliance monitoring system for all permitted discharges required to monitor their effluents in the subbasin. There are twenty one permitted discharg- ers in the subbasin (Figure 1). Two facilities are schools with average flow rates of 0.0025 MGD and 0.0020 MGD, respectively. One facility is a rest home with an average flow rate of 0.0816 MGD. Seventeen facilities are single family residences with permitted flow rates in the range of 0.0004 to 0.0006 MGD. The largest observed flow during this period corresponded to Siler City WWTP with an average flow of 1.8558 MGD. It should be noted that DEM has previously determined that the Siler City DMR's flow data are inaccurate; actual discharge rates are greater than those reported. Phosphorus and nitrogen data were sufficient to develop plant -specific load estimates for Siler City WWTP. For facilities with no available total phosphorus and total nitrogen data, an average total phosphorus concentration of 3.0 mg/1 and an average total nitrogen concentration of 15.0 mg/l were assumed to calculate load estimates. These are total phosphorus and total nitrogen values commonly observed in secondary treatment domestic effluent in North Carolina. The results of the point load calculations are presented in Tables 3 and 4. The total phosphorus loading attributed to point -sources is estimated to be 11,609.73 lbs/year while the total nitrogen loading originated from point -sources is estimated at 115,307.17 lbs/year. Siler/Ci Nutrient Loading Point Sources O_Siler City WWTP Bonlee O2 _Elementary School O3 Hill Forest _Res1 Home OChatham Central —High School ODeniece Orgeron _Resident O'Conner ORobert _Residence ORonald Phillips _Residence John W. Smith O$ _Residence Kathleen Hundly O _Residence James Scott 10 _Residence Swanie Cristle G> > _Residence FIGURE 1. ROCKY RIVER SUBBASIN AND ITS NUTRIENT LOADING POINT SOURCES 11 64 /c— Statute Niles 5 0 5 10 Receiving Nutrient Loading Receiving Stream Point Sources Stream 2 Elizabeth Headen Loves Creek t _Residence Bear Creek 13 Mark Rogers UT Bear Creek _Residence Harlands Creek Frank Clark Bear Creek 14 _Residence UT Greenbrier Creek Dwayne Chavis UT Bear Creek t 5 _Residence UT Greenbrier Creek Barry Park URocky River 16T _Residence UT Hans Creek Kevin S. Cieciorka ULoves Creek »T _Residence UT Rocky Creek David Hinton UT Bear Creek O18 _Residence Bear Creek J. Thomas Peace URocky River 19T _Residence Rocky River Jonnie Webster Rocky River _Residence Bear Creek Leonard Gunter UT Bear Creek 21 _Residence Pones Creek UT Bear Creek Table 1. Table 2 Rocky River Watershed Non -Point Source Annual Phosphorus Loading LAND USE I AREA IEXP. COEFF. I TP LOAD - [ (acres) 1(#/ac./yr.) I (#/year) Cropland I 10,462 1 1.80 1 18,831.6 Pasture I 27,172 1 0.49 1 13,314.3 Fallow Land I 1,772 1 0.18 1 319.0 Urban Land I 6,662 1 1.15 1 7,661.3 Forest Land 1 116,536 1 0.12 1 13,984.3 Lakes I 288 I 0.58 1 167.0 - ------------ TOTAL I ------------ 162,892 162,892 ------------ 1 I 54,277.5 Note: Urban land includes rural residences and churches, farmsteads, roads, mines, recreation areas and critical areas Rocky River Watershed Non -Point Source Annual Nitrogen Loading LAND USE I AREA IEXP. COEFF. I TN LOAD I (acres) 1(#/ac./yr.) (#/year) Agricultural[ 39,406 1 5.60 1 220,673.6 Urban 1 6,662 1 4.7 1 31,311.4 Forest Land I 116,536 I 1.5 1 174,804.0 Lakes 288 I 12.05 1 3,471.0 TOTAL I 162,892 1 I 430,260.0 Note: Agricultural land includes cropland, pasture and fallow land Urban land includes rural residences and churches, farmsteads, roads, mines, recreation areas and critical areas �. i ' s ice' �• ��e .pi �. y f _ � . cJ- gel C, �~ � 1 Table 3. Siler City WWTP Nutrient Loading Input from September 1989 to August 1990 DATE I FLOW I TP I TN ITP LOAD ITP LOAD I TP LOAD ITN LOAD 1 (MGD) I (mg/1) I (mg/1) 1(#/day) 1(#/day) I (#/mo) I (#/mo) 09-09-89 1 1.6 1 0.9 1 21.0 1 11.7 1 273.0 I 351.0 1 8,190.0 10-12-89 1 1.4 1 1.8 1 25.0 1 20.6 1 286.5 1 638.6 1 8,881.5 11-28-89 1 1.8 1 0.4 1 12.7 1 6.0 1 190.0 1 180.0 1 5,700.0 12-20-89 1 1.7 1 0.7 1 16.3 1 10.1 1 236.1 1 313.1 1 7,319.1 01-10-90 1 2.2 1 3.4 1 22.4 1 61.0 1 401.7 1 1,891.0 1 12,452.7 02-14-90 1 2.1 1 0.9 1 14.1 1 15.4 1 244.4 1 431.2 1 6,843.2 03-07-90 1 2.0 1 0.6 1 19.6 1 10.0 1 325.5 1 310.0 1 10,090.5 04-16-90 1 2.2 1 1.5 1 18.8 1 28.0 1 351.0 1 840.0 1 10,530.0 05-03-90 1 2.3 1 4.4 1 32.0 1 83.0 1 603.4 1 2,573.0 1 18,705.4 06-14-90 1 1.9 1 2.3 1 17.7 1 36.0 1 284.3 1 1,080.0 1 8,529.0 07-13-90 1 1.7 1 1.8 1 9.8 1 25.0 1 136.0 1 775.0 1 4,216.0 08-01-90 1 1.5 1 3.5 1 24.5 1 43.7 1 306.1 1 1,354.7 1 9,489.1 * AVERAGE I 1.9 1 1.8 1 19.5 1 29.2 1 303.2 1 I TOTAL I I I 1 1 110,737.6 1110,946.5 Average flow for Siler City WWTP represents the mean flow value of twelve daily flow rates concomitant with twelve 24-hr composite sample TP and TN concentrations reported from September 1989 to August 1990 Table 4. Rocky River Subbasin point -source Nutrient Loading Input at Effluent Average Flow from September 1989 to August 1990 FACILITY I FLOW RATE I (MGD) I Siler City WWTP I I I 1.8558 I Bonlee School I 0.0025 1 Hill Forest Rest Home I 0.0816 1 Chatham Central High I 0.0020 1 Orgeron SFR I 0.0004 1 O'Conner SFR 1 0.0006 I Phillips SFR I 0.0004 I Smith SFR I 0.0006 1 Hundley SFR I 0.0004 I Scott SFR I 0.0004 I Cristle SFR I 0.0006 I Headen SFR I 0.0006 1 Rodgers SFR I 0.0006 1 Clark SFR I 0.0006 1 Chavis SFR I 0.0006 1 Parker SFR I 0.0006 1 Cieciorka SFR I 0.0006 1 Hinton SFR I 0.0006 1 Peace SFR I 0.0006 1 Webster SFR 1 0.0006 1 Gunter SFR I 0.0006 1 TP LOAD I TN LOAD (lbs/year) I (lbs/year) I 10,737.60 1 110,946.50 22.83 1 114.15 745.20 1 3,725.98 18.26 1 91.32 3.65 1 18.26 5.48 1 27.40 3.65 1 18.26 5.48 1 27.40 3.65 1 18.26 3.65 1 18.26 5.48 1 27.40 5.48 1 27.40 5.48 1 27.40 5.48 1 27.40 5.48 1 27.40 5.48 1 27.40 5.48 1 27.40 5.48 1 27.40 5.48 1 27.40 5.48 1 27.40 5.48 1 27.40 TOTAL POINT SOURCE NUTRIENT LOAD = 11,609.73 115,307.17 Average flow for Siler City WWTP represents the mean flow value of twelve daily flow rates concomitant with twelve 24-hr composite sample TP and TN concentrations reported from September 1989 to August 1990 (See Table 3.) Average flow for Bonlee School, Hill Forest Rest Home and Chatham Central High are for period September 1989 to August 1990 as reported in self -monitoring data Single family residence (SFR) flow values are design flow Facilities for which no site specific TP and TN data were available, an average TP concentration of 3.0 mg/l and An averaae TN concentration of 15.0 m/1 were assumed Total Nutrient Budgets The annual nutrient budgets for total phosphorus and total nitrogen are depicted in Figures 4 and 5, respectively. The results indicate that non -point sources are the largest contributors of nutrients in the Rocky River watershed on an annual basis. However, the above results do not account for seasonality. They represent the total nutrient load per year but they do not describe the nutrient loads associated with summer low flow conditions when the algal blooms have been documented in the system. The most significant non -point loading occurs after rainfall events which produce relatively high stream flow conditions. Therefore, in order to account for seasonality, a method had to be designed to translate average non -point source loads into low flow loads present during critical conditions. To accomplish this task, the annual loads were input to the average river flow (224 cfs) to arrive at an average instream concentration. Using this average concentration as a best estimate, mass loads were subsequently calculated for several low flow conditions. are: The expected average instream nutrient concentrations from non -point sources Total Phosphorus: 0.12 mg/1 Total Nitrogen: 0.98 mg/1 These nutrient concentrations correspond to non -point source mass loads of 0.45 lbs/day total phosphorus and 3.7 lbs/day total nitrogen at the S7Q10 flow of 0.7 cfs. Other expected nutrient loads from non -point sources, based on the above concentrations, are presented for different river flow regimes in Figures 6 and 7. Note that the estimated 0.12 mg/l total phosphorus concentration compares favorably to total phosphorus samples collected by the Town of Siler City during August, 1989, in the Rocky River upstream from the Love's Creek confluence (0.16 mg/1) and samples collected by NCDEM on August 3, 1990, in the same general area (0.13 mg/1). The estimated 0.98 mg/1 total nitrogen concentration compares to 1.74 mg/1 and 0.93 mg/l total nitrogen from samples collected by the Town of Siler City during August, 1989, and by NCDEM on August 3, 1990, respectively. The average total phosphorus and total nitrogen daily loads from Siler City WWTP have also been plotted in figures 6 and 7 to compare the expected nutrient load from non -point sources under different river flow regimes to the documented average nutrient load from Siler City. Algebraic techniques were employed to determine the equations of the non -point source nutrient load lines in Figures 6 and 7. The results indicate the equation of the line in Figure 6 is: TP = (0.65 * riverflow) + 0.01 and, the equation of the line in figure 7 is: TN = (5.27 * riverflow) + 0.03 Figure 4. Sources of Total Phosphorus Load in the Rocky River Subbasin per Year ® Point Source Load 9 Non -point Source Load . 35 30 25 20 TP (#/day) 15 10 5 0 Figure 6. Total Phosphorus (TP) Concentrations Originating from Non point Sources at Different River Flow Regimes 0.7 10 20 30 40 50 Flow (cfs) —TP load from non -point sources at Annual average TP load from Siler City different river flow regimes TN Load (#/day) 350 300 250 200 150 100 50 0 Figure 7. Total Nitrogen (TN) Concentrations Originating from Non point Sources at Different River Flow Regimes 0.7 10 20 30 40 50 60 Flow (cfs) — TN load from non -point sources at Annual average TN load from Siler City different river flow regimes The above equations were used to determine the coordinate where the line representing the total nutrient load from non -point sources at different flow regimes intersects the line representing the average nutrient load from Siler City. This X-coordinate of this point represents the river flow necessary to produce a total nutrient mass load equivalent to the total nutrient mass load from the Siler City effluent. DISCUSSION Using the nutrient loading relationships depicted in Figures 6 and 7, the following conclusions may be drawn: A) Total Phosphorus (Figure 6) 1) A river flow of approximately 45 cfs is necessary to produce a total phosphorus mass load equivalent to the total phosphorus mass load from Siler City WWTP (29 lbs/day). 2) During summer low flow conditions (S7Q10 = 0.7 cfs) the expected non -point source contribution of total phosphorus is less than 0.45 lbs/dav (1.5 % of total TP) while the documented total phosphorus contribution from Siler City WWTP is 29 lbs/day (98.5 % of total TP); and, 3) During river flow periods of less than 45 cfs, the Siler City WWTP total phosphorus input exceeds the total phosphorus input from non -point sources. B) Total Nitrogen (Figure 7) 1) A river flow of approximately 58 cfs is necessary to produce a total nitrogen mass load equivalent to the total nitrogen mass load from Siler City WWTP (304 lbs/day); 2) During summer low flow conditions (i.e. S7Q10 = 0.7 cfs) the expected non -point source contribution of total nitrogen is less than 4 lbs/day (1.2 % of total TN) while the documented total nitrogen contribution from Siler City WWTP is 304 lbs/day (98.6 % of total TN); and, 3) During river flow periods of less than 58 cfs, the Siler City WWTP total nitrogen input exceeds the total nitrogen input from non -point sources. Furthermore, samples of total phosphorus taken by the Town of Siler City during August, 1989, in the Rocky River upstream from the Love's Creek confluence indicate an average concentration of 0.16 mg/l. Total phosphorus samples collected in the same general area by NCDEM's Environmental Sciences Branch on August 3, 1990, indicated a concentration of 0.13 mg/l. U.S.G.S. gauging station No. 0210166029 in the Rocky River, near Cruthfields Crossroads (upstream from the confluence of Love's Creek), indicated an average flow of 1.57 cfs during August, 1989 and an average flow of 0.58 cfs in August, 1990 (i.e. 0.50 cfs on August 3, 1990). Therefore, according to these limited data, while river flow conditions approximate S7Q10 flow conditions (i.e. 0.7 cfs), the river background total phosphorus concentration (i.e. attributed to non -point sources) approximates 0.16 mg/l. However, the monthly average of total phosphorus reported by Siler City WWTP was 0.80 mg/l and 3.5 mg/l in August, 1989 and August, 1990 respectively. These total phosphorus concentrations are five and twenty-two times the documented background concentrations for total phosphorus. Similarly, samples of total nitrogen taken by the Town of Siler City during August, 1989 in the Rocky River, upstream from the Love's Creek confluence, indicate a monthly average of 1.74 mg/l. Total nitrogen samples collected by NCDEM on August 3, 1990, indicated a concentration of 0.93 mg/l. Therefore, these data indicate that while river flow conditions approximate S7Q10 flow conditions, the river background total nitrogen concentration (i.e. attributed to non -point sources) approximates 1.74 mg/l. However, the monthly average of total nitrogen reported by Siler City WWTP was 21 mg/1 and 24.5 mg/1 in August, 1989 and August, 1990 respectively. These total nitrogen concentrations are twelve and fourteen times the documented background concentrations for total nitrogen. Although the total nitrogen input from Siler City discharge is significant, by reducing total phosphorus concentrations from the Siler City discharge the system can be driven to a phosphorus limited state. Data collected by the Town of Siler City in August, 1989, in the lower reaches of the Rocky River, indicate that the average total nitrogen concentration is 4.3 mg/1 while the total phosphorus concentration is 0.26 mg/l. These results indicate that the N/P ratio in the lower reaches of the Rocky River is more than 16:1. It is widely accepted that when the ratio of N/P is less than 10:1, nitrogen controls the growth of algae and for N/P greater than 10:1, phosphorus controls the growth (Thomann and Mueller 1987). Therefore, by reducing the available phosphorus for plant growth it is expected that the frequency and the severity of algal blooms will be reduced. However, since variability in plant stoichiometry results in variation of the accepted N/P limiting criteria NCDEM will conduct Algal Growth Potential Tests (AGPT's) in the system. AGPT results will be used to verify that controlling phosphorus input in this system will counteract the eutrophication experienced in the lower reaches of the Rocky River. It should be noted that the Siler City Reservoir (located upstream from the confluence with Love's Creek and downstream from the U.S.G.S. gaging station No. 0210166029) regulates the flow in the Rocky River. NCDEM field staff has reported that release from the reservoir during summer months is almost non-existent, so the instream waste concentration is expected to approach 100% in the lower reaches of the Rocky River. Thus, almost all nutrient input to the system would originate from the Siler City WWTP effluent. SUMMARY AND RECOMMENDATIONS Based on land use of the Rocky River watershed and export coefficients for total phosphorus and total nitrogen, non -point sources contribute 82.4 % of the total phosphorus and 79.9 % of the total nitrogen input in the subbasin annually. Although 23.1 % of the basin is agricultural and pasture land, 59.2 % of non -point phosphorus and 51.3 % of non -point nitrogen loading are annually attributed to these two particular land uses (Figures 2 and 3). However, data indicate that non -point sources are relatively unimportant during the critical low flow periods when eutrophication problems are exhibited in the Rocky River. Algal blooms that have occurred in the lower reaches of the Rocky River are correlated to summer months when the river flows approximate summer 7Q10 flow conditions. The Siler City mass loads of total phosphorus and total nitrogen dominate the total nutrient contribution to the system (i.e. nutrient inputs originating from point sources and non -point sources) during summer low flow periods (Figures 6 and 7). Siler City is the largest contributor of total phosphorus (92.5 %) and total nitrogen (96.2 %) originating from point sources. Limiting total phosphorus concentrations in the Siler City NPDES permit to reflect the best available treatment technology (i.e. a total phosphorus limitation of 0.5 mg/1) at a waste - flow of 4.0 MGD will result in a total phosphorus mass load of 16.7 lbs/day as opposed to the current total phosphorus mass load of 29 lbs/day at a "wasteflow rate of approximately 1.9 MGD. This represents a reduction of 42.5 9 from the current total phosphorus load from the Siler City discharge which would greatly reduce the probability of algal blooms during the summer months. Note that even at the reduced total phosphorus mass load, the Siler City total phosphorus concentration of 0.5 mg/1 is above the documented background levels for this nutrient in Love's Creek (i.e. 0.09 mg/1) and the Rocky River (i.e. 0.16 mg/1). Based on N/P ratio analysis, phosphorus is best target nutrient to control the growth of algae in this system. The system can be driven to a phosphorus limited state by reducing total phosphorus concentrations from the Siler City discharge. REFERENCES Environmental Defense Fund, The Role of Acid Rain. New York:Environmental Defense Fund, 1988. North Carolina Division of Environmental Management, "Nutrient Management in the Lower Neuse Basin," Raleigh, 1988. (Typewritten) Thomann, Robert V., and Mueller, John A. Principles of Surface Water Quality Modeling and Control. New York: Harper and Row, Publishers, 1987. U.S. Department of Agriculture, Soil and Conservation Service and Forest Service, Deep River Erosion Study. Raleigh: USDA -Soil Conservation Service, 1985. APPENDIX 1. DIVISION OF ENVIRONMENTAL MANAGEMENT October 2, 1990 MEMORANDUM TO: Ken Eagleson THROUGH: Jimmie Overton FROM:. Karen Lynch 41) RE: Rocky River, Chatham County R-9 The Rocky River was sampled on August 3 at the request of the -Raleigh .Regional Office after complaints of algal blooms. Sampling sites were chosen above and below the confluence with Love's Creek into which Siler City's wastewater treatment plant discharges. Laboratory and phytoplankton analyses are complete and are included in the attached table. The table includes chlorophyll -a and nutrient data along with phytoplankton biovolume and density estimates. Also attached is a map marking station locations. Nutrient analyses revealed elevations in total phosphorus at the four sites sampled, while high levels of total nitrogen and ammonia/ammonium were found at Rocky-2, below the confluence with Love's Creek. In addition, high chlorophyll -a concentrations were detected above and below Love's Creek at stations, Rocky-1 and Rocky-2. Quantitative phytoplankton counts were conducted on algal samples collected from Rocky-1 and Rocky-2. Moderate phytoplankton densities were found at both stations. Because of the slow -flowing nature of the Rocky River during the summer, free-floating phytoplankton populations were allowed to build up more than would be expected in a faster flowing creek. Algal biovolumes ranged from 1,250 to 1662 mm3/m3 while densities were 5,590 and 6,594 units/ml below and above Love's Creek, respectively. Typically biovolumes greater than 5,000 mm3/m3, densities higher than 10,000 units/ml or chlorophyll -a concentrations approaching 40 ug/I (the state standard) constitute 'algal bloom' conditions At the upper site, Rocky-1, algal classes were dominated by chlorophytes (green algae), chrysophytes (golden -brown algae) and cryptcphytes (cryptomonads). Downstream at Rocky-2, chlorophytes, chrysophytes and cyanophytes (blue-green algae) dominated the sample. The filamentous blue-green, Oscillatoria chlorina, which comprised 29% of the biovolume is a pollution tolerant algal species. cc: Trish MacPherson Steve Mitchell Tim Donnelly, RRO Ron Ferrell, RRO ROCKY RIVER NUTRIENT, CHLOROPHYLL AND PHYi-OPL /VJKTO.N DATA _ BIOVOLUME DENSITY CHL-A TOTALI NH3 I TOTAL NITROGEN PF LOSPHOR STATION JDATE mm3/m3 units/ml u /I m /I m /I m /I ------------------------------------------------------------- - ROCKY-1 900803 1662 6594 32 0.93 O.t4 0.13 ROCKY-2 900803 1250 5590 44 8.2 0.42 0.88 ROCKY-3 900803 ---NOT SAMPLED--- 1 0.6 0.05 0.23 ROCKY-5 900803 ---NOT. SAMPLED--- <1 0.68 0.08 0.23 ROCKY RIVER, CHATHAM COUNTY B AUGUST 3, 1990 WI � JY _ JL iau !r W! lin i.r T, W ' Q � =1X �� 1 1 12Y , • '3!r!. MY � •!n �;: � � JlM rJ lW i ,r ♦ ROCKY-1 vII ` �..Ja w M � l IAl IL'• �� ILC rLJ V��� Y 1� b r �� 11Ir � • ,y, , / OCKY_2 ni na m m uw • • ROCKY�3 'liu J rl. v , un ye. 1e !lll - ROCKY-5 - un nn ♦, Q'Y •• — 1 \, rlu� _ - ,,,, � rn \ �... `Tim, •�• ! •ar r �.• u 1 v�-Y\ rs 1LLL - t APPENDIX 2 Division of Environmental Management November 1, 1990 Memorandum To: Arthur Mouberry Alan Clark Steve Tedder Don Safrit Bobby Blowe Thor: Trevor Clements Ruth Swanek From: Mike Scoville Subject: Town of Siler City WLA Modeling Analysis (NPDES No. NC0026441, Chatham County) Summary In 1988 the Town of Siler City requested an expansion for its wastewater treatment plant to a wasteflow of 4.0 MGD from 1.8 MGD. At that time, a Level-B modeling analysis was performed and permit limits recommended. Since then, a Level-C analysis was required to verify the limits necessary to protect North Carolina's instream standards at an expanded wasteflow, due to public interest in the issue, the inadequacies of the Level-B model application to the Rocky River, requirements of the EIS process, and WWTP design considerations. The entire wasteload allocation analysis was re -initiated, and based on available information and data, the following limits should apply if an NPDES permit is issued for Siler City with a design flow of 4.0 MGD: Summer Winter Floc, MGD 4 4 BODS m g/I 5 10 NH3-N mg/l 1 2 DO mg/1 6 6 TSS mg/I 30 30 Fecal Coliform #/100 ml 200 200 pH SU 6-9 6-9 Oil & Grease mg/1 30 30 MBAS mg/I 0.5 0.5 Lem ug/I 26 26 Chromium ug/I 52 52 Cyanide ug/I 5.2 5.2 Mercury ug/I 0.012 0.012 Copper ug/I Monitor Monitor Nickel ug/I Monitor Monitor Zinc ug/I Monitor Monitor Silver ug/I Monitor Monitor Aluminum ug/I Monitor Monitor Total Residual Chlorine' ug/I 17 17 Total Phosphorus mg/1 0.5'" NR Not necessary if an alternate method of disinfection is utilized Total Phosphorus Limit required May through September only. The recommended limits are necessarily stringent to meet water quality criteria downstream of the discharge. Given the documented impacts downstream, an expanded Siler City WA'TP should be designed to meet [these limits at 4.0 MGD and at any future flows greater than 4.0 MGD; by taking appropriate actions now, retrofitting the plant to meet more stringent limits in the future can be avoided. Modelingof f Oxygen Consuming Wastes A modeling analysis of Loves Creek and the Rocky River below the Siler City WWTPdischarge was recently completed to evaluate the impact of the effluent on instream dissolved oxygen concentrations and to determine the NPDES limits necessary to protect NC water quality standards at a wasteflow of 4.0 MGD. A QUAL2E water quality model was developed for approximately 21 miles of stream below the plant. Hydraulic functions for the model were developed based on the results of a low flow time of travel study performed by Black & Veatch this past August and September. Rates and kinetics were estimated based on best professional judgement and on typical values observed in similar streams. The upstream characteristics of Loves Creek and Rocky River, averaged from Siler City's instmam monitoring data, were kept the same for each simulation, so any change in the model results are directly attributable to the effluent characteristics. Four scenarios were simulated: 1. Average conditions from August 1990 2. Current permit limits for 1.8 MGD 3. Proposed permit limits for 4.0 MGD 4. No discharge The model inputs for the upstream and various effluent conditions are shown in Table 1. While not a formally calibrated model, the DO profile predicted by the model for average low flow conditions provides a close fit to instream DO data collected on several separate occasions during warm, low flow conditions of 1989 and 1990. This is shown in Figure 1. Most importantly, the predicted DO profile accurately matches the observed DO in the impact and recovery zone; the model is appropriate for evaluating the impacts of the wastewater on the water quality in this area. It is important to remember that the model simulation represents mean conditions, while the data points in Figure I are instantaneous samples. Table 1. QUAL2 Model Input for Siler City WWTP Upstream Effluent Characteristics Parameter Loves C eek Rocky River 8/90 Average Existing Proposed Permit Expansion Flow 0.2 cfs 0.3 cfs 1.63 MGD 1.80 MGD 4.0 MGD BOD5 mg/l 1.670 2.130 5.33 12.00 5.00 DO mg/l 4.410 2.700 6.10 6.00 6.00 Organic N mg/I 0.600 0.650 6.92 5.00 5.00 NH3-N mg/1 0.325 0.575 6.90 2.00 1.00 NOx in 0.640 0.517 1 0.65 0.65 0.65 Low flow conditions are frequently experienced in the Rocky River, often for extended periods of time. This is due to the presence of a reservoir upstream that releases little or no water to provide assimilative capacity. As a result, 7Q10 conditions are experienced much more often than every ten years, and DO violations probably occur every summer. The lack of significant instream flow facilitates low velocities and substandard DO concentrations. Non -point loading also affects the water quality to some extent, particularly in Loves Creek above the Siler City WWTP. Since the flow characteristics of the Rocky River also lead to extended periods of time that the stream is dominated by the effluent, a very high quality of effluent is necessary to protect the water quality standards. Figure 2 shows the predicted DO profiles for each of the four scenarios previously mentioned. As can be seen, the discharge has a significant impact on the water quality for approximately five stream miles immediately below the plant. The average existing conditions produce the most severe DO sag, although substandard DO concentrations are predicted in each of the models in which the discharge was included. The E 0 Q Figure I. Observed Insiream DO Concentrations and Predicted DO Profile. 10 T 0 5 10 15 20 We model simulation with no discharge should be interpreted with caution, however, due to the uncertainty of how the stream would behave with so little flow. The DO profile for the most part reflects only changes in hydraulics; the oxygen -consuming parameters are absent for most of the model because of the slow velocity. In reality some son of equilibrium would most likely be reached. The no -discharge model provides a good indication of water quality in the upper part of the model, though, and it's results were included in Figure 2 for comparison. In every case that was modeled, the Rocky River seemed to recover by approximately the fifth mile, below which the effluent characteristics are expected to have little effect on instream DO. The existing permit limits were modeled at a now of 1.8 MGD, rather than 4.0 MGD. As can be seen in Figure 2, under this scenario substandard DO concentrations would be expected for an extended stretch of the stream. The results of other model runs (not shown) indicate the even lower DO concentrations would result from a 1.8 MGD discharge with secondary treatment and from a 4.0 MGD discharge with the existing limits. The predicted DO profile shown is included for comparison of the range of limits necessary for the maintainence of the DO stream standard. In other words, the lower flow with the better treatment has less impact than either of the existing permits, and it is still unacceptable from a DO standpoint. The Rocky River model is sensitive to organic nitrogen and ammonia nitrogen loading from the WWTP. For example, although the average effluent BODS was less than half of the permitted amount, the DO sag was more severe due to excessive levels of organic and ammonia nitrogen (see Table 1). In the allocation model runs, the amount of organic nitrogen in the effluent was a critical factor in the DO sag. For the average effluent concentration, a value of 6.92 was estimated based upon effluent values of total nitrogen and ammonia nitrogen. For the two allocation scenarios a conservative value of 5 mg/1 was assumed. Generally, as the removal of ammonia increases, the effluent organic nitrogen should decrease as well. Based on other facilities' effluent data, if Siler City were meeting an NH3-N limit of 1 mg/l, their organic nitrogen would be considerably less, probably around 2-3 mg/I. The sensitivity of the model to organic nitrogen was tested in allocation runs for the proposed expansion by modeling effluent concentrations of I, 5 and 10 mg/l. The predicted DO profiles resulting from this analysis are shown in Figure 3. It is evident that based on the model results, if the otter oxygen -consuming limits were met, organic nitrogen could potentially make die difference of whether the instream DO standard is maintained. If the Siler City WWTP were to maintain a high degree of nitrogen removal and consistently meet the proposed limits, the DO stream standard would not be expected to be violated. This modeling analysis confirms that the limits derived in the 1988 Level-B WLA would not adequately protect water quality in Loves Creek and the Rocky River. Figure 2. Rocky River Predicted DO Profiles 7 6 k, ij 1 0 0 5 10 15 20 Mile Figure 3. Sensitivity of Siler City WWTP Allocation Model to Organic Nitrogen (Values are effluent organic nitrogen) 8 7 6 5 4 3 2 1 0 0 5 10 15 20 Mile Nutrients A total phosphorus limit was recommended to prevent over -enrichment of the natural stream system per 15A NCAC 2B .0211 (b)(3)(A), which states "the Commission or its designee may prohibit or limit any discharge of waste into surface waters if, in the opinion of the Director, the surface waters experience or the discharge would result in growths of microscopic or macroscopic vegetation such that the standards established pursuant to this Rule would be violated or the intended best usage of the waters would be impaired." Due to the significance of Siler City's discharge on the downstream TP concentrations during low flow periods, and based on staff observations and citizen complaints of algal growth on the substrate and the water surface, a TP limit is appropriate. The above regulation specifically applies to slow moving waters not designated as trout waters. Toxics The toxics limits were all determined according to standard Division procedure. A mass balance was performed for each individual parameter and a limit derived which represents the maximum daily allowable effluent concentration that will protect the instream standard. The mass balance used the plant design flow (4.0 MGD) and the 7Q10 of Loves Creek at the point of discharge (0.25 cfs). Monitoring requirements for metals were based on the latest pretreatment headworks analysis and priority headworks analysis. The total residual chlorine limit is to prevent toxicity; it is suspected that elevated chlorine concentrations were a factor in the facility failing it's whole effluent toxicity test. The NC instream standard for total residual chlorine is 17 ug/l. If the facility utilizes a method of disinfection other than wastewater chormation, this limit would not be necessary, otherwise effluent dechlorination should be a written permit condition. The ammonia limit, while being limited for its oxygen consuming characteristic, is also limited as a toxic substance. The recognition and documentation of ammonia toxicity led to the adoption of Division procedure protecting the instream summer ammonia concentration to 1.0 mg/l or less. The ammonia limit would have to be 1.0 mg/1 whether protection of the DO standard required it or not. All major dischrgers in North Carolina are required to perform whole effluent toxicity tests, the type of which is determined by the instream waste concentration (IWC) during 7Q10 conditions. At the proposed 4.0 MGD wasteflow, Siler City's IWC is 96.1 %, which requires a quarterly chronic toxicity testing at 96% using Ceriodaphnia as the test organism. M APPENDIX 3 TABLE I RUNOFF COEFFICIENTS FOR NONPOINT SOURCE PHOSPHORUS - COEFFICIENT RANOE IN WHERE ' LAND USE USED LITERATURE MEASURED REFERENCE !lb/ac/yr> !lb/ac/yr) CROPLAND 1.8 0.13 Ohio T.-Pr.iri♦ o K.lft 1906 0.19-0.41 Various OH.rnik 19T6 0.3 Various Horner a Mar 1982 - p_49 Wake Co. DEN 1981 0.52 Ohio T.-Prairie 1 Kalft 1906 0.94 Florida Shahann. 1982 0.90 Chowan DEN 1982 1.8 N.C. DEN 1906 3.65-3.92 Arkansas U.sterdahl It •1. 1961 10.7 Chown Craig 0 Kuenzler 1983 PR5TURELRNO 0.45 0.06 Various Horner R Mar"3982 0.06 Ohio T.-Prairie: C Kalft 1986 0.19-0.41 Chowan Cra19 6 Kt�eAzler. 1903 0.27 Florida Shahan* 1902. 0.49 Wake Co. OEM 1984' 0.98 Chowan OEM 1982 FALLOW LAUO 0.18 0.06 V.rio�s Horner A Mar 1982 0.18 Wake Co. OEM 1984 0.19-0.41 Chowan Craip a Kuenzler 1183 0.98 Chowan DEN 1982 FORE5TLnHO 0.12 0.05 Maine Dennis 198S 0.07 Ohio T.-Pr.iri. 9 Kallt 1986 0.08 Various Horner R Mar 1902 0.01 Chowan DEN 1982 0.09 Wake Co. OEM 1904. 0.09-0.15 Varlous OH.rnik 39TS 0.09 Florid. Shahan .1904;- 0.17 Arkansas u.stir'�h;'k?!!'.1. 1981 0.5 Chowan Craig Q Kuenzler 1983 URBAN LAND 1.15 0.02-0.16 7 houses/ac iischlor it Ll. 1983 0.05 Various ONernik 1976 0.28 MiHad Urban NouotnV at al. 1985 0.2-1.3 Residential Horner 4 Mar 1962 0.39-1.34 .85 house/Ac Dennis 198S 0.4 .2 house/ac Randall et al. 1970 0.80-3.6 Industrial Horner A Mar 3982 0.89 .5 house/ac OEM 190A •.• •. y O•.89 1 house/ac . DEN 19" • 0.9 1 house/ac Randall .t al. 1978 0.9-1.0 1 hous#/.c 0EENN 1901;};,=.' 1.0 2.5 houses/ac DEfi 1984; 1.04 4 houses/ac. 09�} (l00] 1.1 B.6 houses/ac OEI7',1904 A. 1.1-0.0` Mimed Urban Cl�y1lan }'al. 19T0 1.2-1.4 multi-fakily HOrnet: a 'mar 3982 1.25 4.S houses/ac OEM 1984 -' 1.70 20 houss/Ac Dorned 4 Krrutzberyer 1586 1.78 MSHed Urban DEN 198] 2.0 Residential Shahan# 1982 • 2.23 R&D Park OEM 1986 2.4 C.... rcia1 Horner 4 Mar 3982 2.5 C8D Horner h Mar 1582 3.4 Mi..d Urban Bryan 1970 3.68 CBD DEN 190] 4.7 Mi.ed Urban Colston 1974 LAKES O.SB 0.58 50 in. .in OEM 1983 REFERENCES Note: DEI-1 refers to the North Carol Ina Divio,nn of CnvironmentaI Man.aoement - Bryan, E.H. 1970. Quality of Stormwater Drainage from Urban Land Areas in North Carolina. Water Resources Research _ Institute*Report No. 37. Raleigh, N.C. Cleveland, J.G., R.H. Ramsey, and P.R. Walters- 1970. Stormwater Pollution from Urban Land Activity. Proceedings of Symposium on Storm and Combined Sewer Overflows, FWQA, June 1970. Colston. N.V., Jr1974. Characterization and Treatment of Urban Land Runoff. Report No. F_PA-670/2-74-096. Research Triangle Park, N.C. 1 Craig. N.J., and E.J. Kuenzler. 1993. Land use, Nutrient Yield, and Eutrophication in the Chowan River Basin. Water Resources Research Institute Report No. 205. Raleigh, N.C. DEM. 1982a. Chowan River Water Quality MI[nagement Plan. Raleigh, N.C. DEM. 19B2b. Chowan/A,.l:bemarle Action 11 Plan. Raleigh, N.C. Water Quay n litDiscuSSos4.of Falls of the Neuse and DEM. 1983a. ' B. Everett Jordan Lakes. DEM 83-06. Reigh, N.C. DEM. 1983b. Nationwide Urban _RLrtg6ff Program, Winston-Salem, N.C. DEM Report No- 83-07. Ral'6i6h, N.C. DEM. 1984. Assessment of Nutra.erit Runoff from Projected Development in the Lake Wthee:ler Watershed. Raleigh, N.C. DEM. 1985a Toxic Substances in Surface Waters of the B. Everett Jordan Lake Watershed and September 1985 Update. DEM Report No. 85-02. Raleiah, N.C. DEM. 1985b. Toxic Substances in Surface Waters of the Fa115NOf the Meuse Lake Watershed. DEM Report No. HS-OH. Raleigh, DEM. 19H6- water Quality Progress in 'north Carolina 19H4-19H5 305h Report. Raleigh, N.C. DennSs, J. 1985- Phosphorus Ezport from a Logy: Dens ity Resirlr>ntial 6atershed and an Adjacent Fores�--d Watershed- T - , n1tr or'.M. .--tal Protection- . HhiLe Paper by Maine Depal-t, meat c- Uorney, J.R., and w-A. KI-eu tzberg e, 19©6, Sources, l_ocaCions, and Control of Urban Runoff Pollutants in the Piedmont of North Carolina. Proceedings of 5th Annual Conference and. International Symposium on Applied Lake and Watershed Management, North America Lake Management Sources, November 13-I6, 1995. Horner, R_R. and B.W. Nar. 1982.. A -Guide for Assessing the Water Quality Impacts of Hi ghwa4.. Op. erations and Maintenance. 'Washington State Department o Transportation Runoff Water Quality Research Report No. 14. Seattle, Washinoton. i<uenzler, E.J., and N.J. Craig. 1986. Land Use and Nutrient Yields of the Chowan River Watershed. In: D.L. Correll (ed.), Watershed Research Perspectives. Washinoton: Smithsonian, pp. 77-107. North Carolina Department of Agriculture. 19e5. North Carolina Agricultural Statistics. 1985_ NCDA Reoort No.-156. Raleigh, N.C_ Novotny, V., H.-M. Sung, R. Bannerman, and K. Baum. 1985. Estimating Nonpoint Pollution from Small Urban Watersheds. Journal WPCF 57 (4): 339-348. Omernik, J.M. 1976. The Influence of Land Use on Stream Nutrient Levels. Report No_ EPA-600/3-7a--014. Randall, C.W., T.J. Grizzard, and R.C. Hoehn. 197e. Impact of Urban Runoff on Water,$U.u'adity in the Occoquan Watershed:;,;: Virginia Water Resource ,2esearch Center Bulletin No`,z.80.- Blacksburg, Viroinia:'.-^';+!^�� .Shahane, 1962. Estimation of Pre- and Post -Development Nonpoint (Dater Quality-Laadii-ngs. Water Resources Bulletin le a (2): 231-237- Sheffield, R.M. and H.A. Kriljt, 'T 1986. North Carolina's Forests. USFS Resource Bi{—etin SE-88. Asheville: Southeastern Forest Ev.per.bleiht Station. Soil Conservation Service. 1983, Upper Neuse River Erosion S tudy; Paleigh, N.C. Soil Conservation Service. 1985. Haw River Erosion Study. Special Report. Raleigh, N.C- iischler, 1.1•., F.J. Castaldi, and R.5- Dykes. 19e-- Effects of Imperviou Cover on Urban Runoff Loadincs form Residential watersheds- WPCF Annual Conference, October 2-7, 1993. 1.-Pra!r ie. f.. and .I. F'alft. 19R6. Ei'eCL of CatChm2nt Size c,.: u•s >[Do rt:. Hater Resources ..._. _. I'r tangle J I of Government. S. I1?/6. Pollution Source Analysis. Research Triangle Park, N.C. Westerdahl, H.E., W.B. Ford, III, J. Harris, and C.R. Lee1 981. Evaluation of Techniques to Estimate Annual Water Quality,;',:;_,;. Coadinos to Reservoirs_ U.S. Army Corps of Engineers'<_=�'_;:,:;�_" Environmental and Water Quality Operational Studies, Techin i c a 1 Report E-81-I. Vicksburg, Ms. .-k-