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HomeMy WebLinkAboutWQ0035576_Residual Annual Report 2014_20150216P9- 6-6-3 5 576 Broad River Water Authority Broad River Water Authority 2014 Annual Report Land Application Program NC Permit No. WQ0035576 fRECEIVEL) FEB ]67015 INFOR'VIA /O ASROC ,SING UNIT ANN UAL LAIN1) APYLIUATION CERTIFICATION FORM NVQ Permit#: WQ0035576 County: Facility Name (as shown on permit): Land Application Operator: Rutherford Year: 2014 Broad River Water Authority Southern Soil Builders, Inc. Phone: 336-957-89Q9 Land application of residuals as allowed by the permit occurred during the past calendar year? [A' Yes 0 No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A - Residuals Application Summarv: Total number of application fields in thepen-nit: I - NA Total number of fields utilized for land application during the year: 3 Total amount of dry tons applied during the year for all application sites: 592.79 Total number of acres utilizes for land application during the year: 90 Part B - Annual Compiance Statement: Facility was compliant during calendar year 2014 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Resources. Yes El No If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1) Only residuals approved for this permit were applied to the permitted sites. 2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities). 7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Resources. 10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as specified in the permit. 12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13) All buffer requirements as specified on the permit were maintained during each application of residuals. Part C - Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." ermittee Name and Title (type or print) U Signature of Permittee Date a-6-ly of LaaApplier Date (if different fro Pe itd.ee) (if different from Permittee and Preparer) * Preparer is defin-0 in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: WQ0035576 Facility Name: Broad River Water Authority Residual Source WQ # or WQ0035576 NPDES #: WWTP Name: Broad River Water Authority RPairinnl Analvcic Data Laboratory: 1) A&L Eastern Labs. 2) 3) 4) 5) ParameterConc. (mg/kg) S le or Composite Date Now WR 'For "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." of Prey * 2.o \ Date *Preparer is defined in 40 CPR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM RSSF (1212006) CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM WQ PERMIT #: WQ0035576 FACILITY NAME:, Broad River Water Authority PHONE: 828-287-7776 COUNTY: Rutherford OPERATOR: Brad Joyner FACILITY TYPE (please check one): D Surface Disposal (complete Part A (Source(s) and "Residual In" Volume only) and Part C) & Distribution and Marketing (complete Parts A, B, and C) Was the facility in operation during the past calendar year? Yes &, No ® — * If No skip parts A, B, C and certify form below Part A*: Part B*: Month Sources(s) (include NPDES # if applicable) Volume (dry tons) Recipient Information Amendment/ Bulking Agent Residual In Product Out Name(s) Volume (dry tons) Intended use(s) January February March April May June July August September October. November December WQ0035576 0 592.79 592.79 Todd Hunnicutt 592.79 Soil Admendment Total from FORM DMSDF (sup) Totals: Annual (dry tons): 0 592.79 592.79 _. ,.. 592.79 Amendment(s) used:-Bulkin Agent(s) used: - * If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Supp) l Part C: Facility was compliant during the past calendar year with all conditions of the land application permit Of Yes (including but not limited to items 1-3 below) issued by the Division of Water Resources: ® No o If No, Explain in Narritive 1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached. 2. All'operation and maintenance requirements were compiled with or, in the case .of a deviation, prior authorization was received from the Division of Water Resources. 3. No contravention of Ground Water Quality Standards occurred at a monitoring well. "I certify, under penalty of law, that the above information is, to the bestlof my knowledge and belief, true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." a ignature of Permittee Date **Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) Signture of Prep er (if different from ermi e) z Date DENR FORM DMSDF (12/2006) Page: 1 of 2 Report Number: 14-227-0207 Account Number: 46381 Send To: SOUTHERN SOIL BUILDERS DENNIS KEY 958 HOOTS ROAD ROARING RIVER, NC 28669 Lab Number: 57063 Sample Id: BRWA �L A &L Eastern Laboratories, Inc. 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271-W6 WWw.aleastem.com Project: BRWA NC CERT # 257 REPORT OF ANALYSIS Date Sampled: 8/13/2014 12:05:00 Date Received: 08/15/2014 00:00 Date Reported: 08/21/2014 Total Solids * 32.86 328600 100.0 JM 08/15/2014 15:00 SM-2540G Moisture * 67.14 100.0 JM 08/15/2014 15:00 SM-2540G Total Kjeldahl Nitrogen 0.34 3440 10.0 TW 08/20/2014 08:35 SM-4500-NH3C-TKN Total Phosphorus 0.10 981 100 KM 08/19/2014 13:04 SW 6010C Total Potassium 0.24 2420 100 KM 08/19/2014 13:04 SW 6010C Total Sulfur 0.25 2520 100 KM 08/19/2014 13:04 SW 6010C Total Calcium 0.11 1130 100 KM 08/19/2014 13:04 SW 6010C Total Magnesium 0.33 3280 100 KM 08/19/2014 13:04 SW 6010C Total Sodium <0.01 <100 100 KM 08/19/2014 13:04 SW 6010C Total Iron 45300 100 KM 08/19/2014 13:04 SW 6010C Total Aluminum 125000 100 KM 08/19/2014 13:04 SW 6010C Total Manganese 593 5 KM 08/19/2014 13:04 SW 6010C Total Copper 33 5 KM 08/19/2014 13:04 SW 6010C Total Zinc 90 5 KM 08/19/2014 13:04 SW 6010C Ammonia Nitrogen 0.02 243 10.0 MW 08/18/2014 09:09 SM-4500-NI3C Organic N 0.32 3197 10.0 08/18/2014 09:09 CALCULATION Nitrate+Nitrite-N 38.3 2.00 MW 08/18/2014 09:10 SM-450ONO3F Total Cadmium <2.0 2.0 KM 08/19/2014 13:04 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. 9 Our reports and letters are for the exclusive and confidential use of our chenis. and may not be reproduced in whole or part, nor may a. ry reference be made M�l to the work, the results. or the company in any advertising, news release, or other public announcements mrithout obtaining our prior written. authorization. Debbie Holt Page: 2 of 2 Report Number: 14-227-0207 Account Number: 46381 Send To: SOUTHERN SOIL BUILDERS DENNIS KEY 958 HOOTS ROAD ROARING RIVER, NC 28669 Lab Number: 57063 Sample Id: BRWA ® A&L Eastern Laboratories Inc. ■ ■Y� 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271-6446 wwwaleastem.com Project: BRWA NC CERT # 257 REPORT OF ANALYSIS Date Sampled: 8/13/2014 12:05:00 Date Received: 08/15/2014 00:00 Date Reported: 08/21/2014 Total Chromium 57 5 KM 08/19/2014 13:04 SW 6010C Total Nickel 22 5 KM 08/19/2014 13:04 SW 6010C Total Lead 18 5 KM 08/19/2014 13:04 SW 6010C Total Arsenic 7.0 3.0 KM 08/19/2014 13:04 SW 6010C Total Mercury <0.4 0.4 KM 08/20/2014 08:50 SW-7471 B Total Selenium <5.0 5.0 KM 08/19/2014 13:04 SW 6010C pH (Standard Units) * 6.18 2.00 TW 08/18/2014 09:49 SW-9045D Total Molybdenum <5 5 KM 08/19/2014 13:04 SW 6010C Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Cr" AND "Ni". ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis Our reports and letters are for the exciusive and confidential use of our clients, and may not be reproduced ir, w,hoie or parr, nor t-oay any reference be made to the work. the results, or the company in any advertising, news release. or other public announcements without obtaining our prior written authorization. Debbie Holt PAN Mineralization as decimal ITotal dry tons/yea jAcres Applied -on 90 Rate 0.4 TKN 3440 K 3 : - F 342 NO3 38.3-1 NO2 0 % Solids 0.3286 592.79 PAN Surface 1448.5jmglkg 2.897 lbs/dry ton 1717.313 lbs total PAN 19.08125 lbs PAN/acre PAN In-c'j U0 C O 1619.51mg/kg 3-239 lbs/dry ton 1920.047 1 ibs total PAN 21.333851lbs PAN/acre Pry Tons/1000 gal. 1.-370262 1st year PAN Surface lbs. 1717.31263 1st year PAN Injected lbs. 1920.04681 lbs./acre Surface 19.08125144 lbs./acre Injected 21.33385344 MR(TKN-NH3)+ +.5(NH3)+NO3+NO2 =mg/kg mg/kg x.002 =Ibs/dry ton MR(-r,KN"NH3',i I I + NH3jl+N%ID',3+NO2 =Mgll,- k mg/kg x.002 =Ibs/dry ton 1000 X 8.34 X %solids X sp. gravity "=dry tons/1 000gal." 2000 SAR Sodium Absorption Ratio Na :'Sodium (Mg/L) Equivalent weight: 23 Ca: Calcium (Mg/L) Equivalent weight: 20 Mg : Magnesium (Mg/L) Equivalent weight: 12 Milli Equivalent = Mg/L / Equivalent weight Na(Mg/L) Ca M /L M M /L 32.86 1 371.3 1 1077.8 Lig KEA I �icl (M_ Q I Mg_LNI 1.4-28696 '18.565 89,81667 SAR:= Na Milli Equivalent/[0.5 X (Ca Milli Equivalent + Mg Milli equivalent)]0.5 power SAR = 0.194078 1 (Frorn Mg/L entered above) SAR= 0.192907 (From ME entered below) Na ME Ca ME Mgt 1.42 1 18.56 1 89.81 The amour amount of E Permitting c Analytical Results Southern Soil Builders 958 Hoots Road Roaring River NC 28669 Entered 8/13/2014 Reported: 8/19/2014 For: BRWA Sample ID Parameter Cust ID Result Units Method Date Analyzed Analyst 140813-28.1 % Solids 1 28.7 % SM2540B-1997 8/14/14 WL 140813-28.1 Fecal Coliform MTF 1 <7 MPN/g SM92210E-2006 8/14/14 WL 140813-28.2 % Solids 2 29.8 % SM2540B-1997 8/14/14 WL 140813-28.2 Fecal Coliform MTF 2 <6.7 MPN/g SM9221 CE-2006 8/14/14 WL 140813-28.3 % Solids 3 30.5 % SM2540B-1997 8/14/14 WL 140813-28.3 Fecal Coliform MTF 3 <6.6 MPN/g SM9221 CE-2006 8/14/14 WL 140813-28.4 % Solids 4 29.5 % SM2540B-1997 8/14/14 WL 140813-28.4 Fecal Coliform MTF 4 <6.8 MPN/g SM9221 CE-2006 8/14/14 WL 140813-28.5 % Solids 5 28.6 % SM2540B-1997 8/14/14 WL 140813-28.5 Fecal Coliform MTF 5 <7 MPN/g SM92210E-2006 8/14/14 WL 140813-28.6 % Solids 6 31.3 % SM2540B-1997 8/14/14 WL 140813-28.6 Fecal Coliform MTF 6 <6.4 MPN/g SM92210E-2006 8/14/14 WL 140813-28.7 % Solids 7 29.8 % SM2540B-1997 8/14/14 WL 140813-28.7 Fecal Coliform MTF 7 <6.7 MPN/g SM9221 CE-2006 8/14/14 WL Respectfully submitted, U/-�A'/OL Dena Myers NC Cert #440, NCDW Gert #37755, EPA NCdO9O9 P.O. Box 228 • Statesville, North Carolina 28687 • 704/872/4697 Client: AC' STATESVILLE ANALYTICAL 122 Court Street • P.O. Box 228 Address: �j �y v� ! {J -..�.i Statesville, NC 28687 .(Z04)' 872-4697 % .� r / - _ - - - - - - - - - -- - - - - - - - - - Contact Person: '7 (/'l (7`� Phone # [) 7 n FAX# • - 4_(h ! 6�A-- 3 `-' — �J �7 I 3 CIS '� , E � f f Chain of Custody Record PO # u Requisitioned by: Crime Date) Customer Sample ID# Lab -ID # Time Sampled Grab Onl ( y) Date Sampled (Grab Only) a a o Matrix Parameters requested for analysis Sludge w ww �Q' IF• ag a� � -j � y ��( t� Relinquished by: �. Time t "� am, Date / j �/ Sampled by:� ( 1 Received by: (/f 2 y Time `; : �; am,Imi Date % / Transported by: Relinquished b :'"� q Y Time am, pm Date / Holding times met: Received by: Time an ; pm Date / / Compliance work: Composite Sampling #1: Time begin am, pm Date / / Non-compliance work: Time end am, pm Date / / Lab Comments: Composite Sampling #2: Time begin am, pm Date Time end am, pm Date /_/ Condition of Receipt Sample ID 140813-28.1-28.7 Client Southern Soil Builders Temp on Arrival pH upon Arrival Parameter Schedule % solids ❑ HNO3 ❑ HCl ❑ NaOH ❑ H2SO ❑ Na2S2O ❑ Dechlorinated —' pH'upon Arrival - —. Parameter Schedule _-__Fecal ColifoM MTF ❑ HNO3 ❑ HCl ❑ NaOH ❑ H2SO ❑ Na2S2O ❑ Dechlorinated ❑ Chemicals in containers, client ❑ Chemicals upon receipt ❑ Received on Ice ❑ Samples chilled upon receipt ❑ Chemicals in containers, lab ❑ Chemicals in containers, client ❑ Chemicals upon receipt Received on Ice ❑ Samples chilled upon receipt ❑ Chemicals in containers, lab Page 1 of 1 Analytical Results Southern Soil Builders 958 Hoots Road Roaring River NC 28669 Entered 8/13/2014 Reported; 8/27/2014 For: BRWA Sample ID Parameter Cust ID Result Units Method Date Anal st Analyzed Y 140813-3T Corrosivity BRWA See Attached SW-846 8/22/14 PACE 140813-31 Ignitability BRWA See Attached 1010M 8/22/14 PACE 140813-31 Reactivity BRWA See Attached SW-846 8/22/14 PACE 140813-31 TCLP BRWA See Attached 1311 8/22/14 PACE Respectfully submitted, Dena Myers NC Cert#440, NCDW Cert #37755, EPA NC00909 P.O. Box 228 • Statesville, North Carolina 28687. 704/872/4697 Client: C f I ' `'�) 4' t3 • ✓ ° C4 r = a r STATESVILLE ANALYTICAL 122 Court Street - P.O. Box 228 Statesville, NC 28687 -�' . - (704 8--)- 72-4693-.. fi Address: g j ° Contact Person: r a Phone # -� FAX# f) v V Chain of Custody Record PO # Requisitioned by: (Time Date) Customer Sample ID# Lab-ID Time Sampled (Grab Only) Date Sampled (Grab Only) a 0 Matrix Parameters requested for analysis sludge WWW B R" j A yy#�� , %} ' V j� J 1 � l "�' f' (; `� ,� l i . �7 d 1�� rrSia), �`!) •ls_ /+' Relinquished by: Received by: Relinquished by: Received by: Composite Sampling Time begin Time end Composite Sampling Time begin Time end �,1� !� , r _ #1- am, pm Date / / am, pm Date / / #2: am, pm Date am, pm Date / / de Time Time Time Time Lab Comments: am, pm)Date 26 / /1 am m Date / t r�' am, pm Date / / am, pm Date / / Sampled by: Transported by. jy Holding times met: Compliance work: Non-compliance work: s ` Condition of Receipt Sample ID 140813-31 Client Southern Soil Builders Temp on Arrival pH upon Arrival Parameter Schedule Corrosivity ❑ HNO3 ❑ HCl ❑ NaOH ❑ H2SO ❑ Na2S2O ❑ Dechlorinated pH upon Arrival Parameter Schedule Ignitability ❑ HNO3 ❑ HCl ❑ NaOH ❑ 1i2SO ❑ Na2S2O ❑ Dechlorinated pH upon Arrival Parameter Schedule Reactivity ❑ HNO3 ❑ HCl ❑ NaOH ❑ 112SO ❑ Na2S2O ❑ Dechlorinated pH upon Arrival Parameter Schedule TCLP ❑ HNO3 ❑ HCl ❑ NaOH ❑ 112SO ❑ Na2S2O ❑ Dechlorinated ❑ Chemicals in containers, client ❑ Chemicals upon receipt ❑ Received on Ice ❑ Samples chilled upon receipt ❑ Chemicals in containers,, lab ❑ Chemicals in containers, client ❑ Chemicals upon receipt ❑ Received on Ice ❑ Samples chilled upon receipt ❑ Chemicals 'in containers, lab ❑ Chemicals in containers, client ❑ Chemicals upon receipt ❑ Received on Ice ❑ Samples chilled upon receipt ❑ Chemicals in containers, lab ❑ Chemicals in containers, client ❑ Chemicals upon receipt ❑ Received on Ice ❑ Samples chilled upon receipt ❑ Chemicals in containers, lab Page 1 of I aceAnalXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: 08/13/14 140813-31 Pace Project No.: 92213461 Sample: 140813-31 Lab ID: 92213461001 Collected: 08/13/14 13:15 Received: 08/14/14 15:10 Matrix: Solid Results reported on a "dry -weight" basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides, TCLP Analytical Method: EPA 8081 Preparation Method: EPA 3510 Leachate Method/Date: EPA 1311; 08/18/14 15:15 amma-BHC L' d g ( m ane) Chlordane (Technical) ND ug/L 0.50 1 08/19/14 10:01 08/20/14 11:00 58-89-9 Endrin ND ug/L 3.0 1 08/19/14 10:01 08/20/14 11:00 57-74-9 Heptachlor epoxide ND ug/L ND ug/L 0.50 1 0.50 08/19/14 10:01 08/20/14 11:00 72-20-8 Methoxychlor ND ug/L 1 1000 08/19/14 10:01 08/20/14 11:00 1024-57-3 Toxaphene 1 08/19/14 10:01 08/20/14 11:00 72-43-5 Surrogates ND ug/L 3.0 1 08/19/14 10:01 08/2011411:00 8001-35-2 Decachlorobiphenyi (S) 49 % 10-138 1 08/19/14 10:01 08/20/14 11:00 2051-24-3 Tetrachloro-m-xylene (S) 52 % 10-110 1 08/19/14 10:01 08/20/14 11:00 877-09-8 8082 GCS PCB Analytical Method: EPA 8082 Preparation Method: EPA 3546 PCB-1016 (Aroclor 1016) ND ug/kg 127 1 08/15/14 15:02 08/18/14 16:44 12674-11-2 PCB-1221 (Aroclor 1221) ND ug/kg 127 1 08/15/14 15:02 08/18/14 16:44 11104-28-2 PCB-1232 (Aroclor 1232) ND ug/kg 127 1 08/15/14 16:02 08/18/14 16:44 11141-16-5 PCB-1242 (Aroclor 1242) ND ug/kg 127 1 08/15/14 15:02 08/18/14 16:44 53469-21-9 PCB-1248 (Aroclor 1248) ND ug/kg 127 1 08/15/14 15:02 08/18/14 16:44 12672-29-6 PCB-12541 (Aroclor 1254) ND Llg/kg 127 1 08/15/14 15:02 08/18/14 16:44 11097-69-1 PCB-1260 (Aroclor 1260) ND ug/kg 127 1 08/15/14 15:02 08/18/14 16:44 11096-82-5 Surrogates Decachlorobiphenyl (S) 51 % 21-132 1 08/15/14 15:02 08/18/14 16:44 2051-24-3 8151 Chlorinate Herbicide TCLP Analytical Method: EPA 8161 Preparation Method: EPA 3510 2,4-D ND mg/L 0.038 1 08/22/14 08:00 08/22/14 22:19 94-75-7 2,4,5-TP (Silvex) Surrogates ND mg/L 0.038 1 08/22/14 08:00 08/22/14 22:19 93-72-1 2,4-DCAA'(S) 98 % 42-142 1 08/22/14 08:00 08/22/14 22:19 19719-28-9 6010 MET'ICP, TCLP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Leachate Method/Date: EPA 1311; 08/15/14 16:30 Arsenic ND mg/L 01050 1 08/18/14 19:05 08/19/14 11:26 7440-38-2 Barium 0.67 mg/L 0.25 1 08/18/14 19:05 08/19/14 11:26 7440-39-3 Cadmium ND mg/L 0.0060 1 08/18/14 19:05 08/19/14 11:26 7440-43-9 Chromium ND mg/L 0.025 1 08/18/14 19:05 08119/1411:26 7440-47-3 Lead ND mg/L 0.025 1 08/18/14 19:05 08/19/14 11:26 7439-92-1 Selenium ND mg/L 0.10 1 08/18/14 19:05 08/19/14 11:26 7782-49-2 Silver ND mg/L 0.025 1 08/18/14 19:05 08/19/14 11:26 7440-22-4 7470 Mercury, TCLP Analytical Method: EPA 7470 Preparation Method: EPA 7470 Leachate Method/Date: EPA 1311; 08/15/14 16:30 Mercury ND ug/L 0.20 1 08/18/14 20:00 08/21/14 14:08 7439-97-6 8270 MSSV TCLP Sep Funnel Analytical Method: EPA 8270 Preparation Method: EPA 3510 Leachate Method/Date: EPA 1311; 08/18/14 15:15 1,4-Dichlor'obenzene ND ug/L 50.0 1 08/1911410:01 08/20/1412:54 106-46-7 2,4-Dinitrot'oluene ND ug/L 50.0 1 08/19/14 10:01 08/20/14 12:54 121-14-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/27/2014 09:52 AM without the written consent of Pace Analytical Services, Inc.. Page 4 of 21 aceAnaljdical www.pecolabs.com ANALYTICAL RESULTS Project: 08/13/ 14 140813-31 Pace Project No.: 92213461 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NO 28078 (704)875-9092 Sample: 140813-31 Lab ID: 92213461001 Collected: 08/13/14 13:15 Received: 08/14/14 15:10 Matrix: Solid Results reported on a "dry -weight" basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[ 8270 MSSV TCLP Sep Funnel Analytical Method: EPA 8270 Preparation Method: EPA 3510 Leachate Method/Date:•.EPA 1311; 08/18/14 15:15 Hexachloro-1,3-'butadiene ND ug/L 50.0 1 08/19/14 10:01 08/20/14 12:54 87-68-3 Hexachlorobenzene ND ug/L 50.0 1 08/19/14 10:01 08/20/14 12:54 118-74-1 Hexachloroethane ND ug/L 50.0 1 08/19/14 10:01 08/20/1412:64 67-72-1 2-Methyl phenoI(o-Cresol) ND ug/L 50.0 1 08/19/14 10:01 08/20/14 12:54 95-48-7 3&4-Methylphenol(m&p Cresol) ND ug/L 50.0 1 08/19/14 10:01 08/20/14 12:54 Nitrobenzene ND ug/L 50.0 1 08/19/14 10:01 08120/1412:54 98-95-3 Pentachlorophenol ND ug/L 100 1 08/19/14 10:01 08/20/14 12:54 87-86-5 Pyridine ND ug/L 50.0 1 08/19/14 10:01 08/20/14 12:54 110-86-1 2,4,5-Trichlorophenol ND ug/L 50.0 1 08/19/14 10:01 08/20/14 12:54 95-95-4 2,4,6-Trichlorophenol ND ug/L 50.0 1 08/19/14 10:01 08/20/14 12:54 88-06-2 Surrogates Nitrobenzene-d5 (S) 25 % 12-102 1 08/19/14 10:01 08/20/14 12:54 4165-60-0 2-Fluorobiphenyl (S) 26 % 13-107 1 08/19/14 10:01 08/20/14 12:54 321-60-8 Terphenyl-d14 (S) 53 % 21-132 1 08/19/14 10:01 08/20/14 12:54 1718-51-0 Phenol-d6 (S) 9 % 10-110 1 08/19/14 10:01 08/20/14 12:54 13127-88-3 SO 2-Fluorophenol (S) 15 % 10-110 1 08/19/14 10:01 08/20/14 12:54 367-12-4 2,4,6-TrlI*omophenol (S) 32 % 27-108 1 08/19/14 10:01 08/20/14 12:54 118-79-6 8260 MSV TCLP Analytical Method: EPA 8260 Leachate Method/Date: EPA 1311; 08/19/14 11:34 Benzene ND ug/L 192 38.5 08/20/14 21:25 71-43-2 2-Butanone (MEK) ND ug/L 385 38.5 08/20/14 21:25 78-93-3 Carbon tetrachloride ND ug/L 192 38.5 08/20/14 21:25 56-23-5 Chlorobenzene ND ug/L 192 38.5 08/20/14 21:25 108-90-7 Chloroform ND ug/L 192 38.5 08/20/14 21:25 67-66-3 1,4-Dichl6robenzene ND ug/L 192 38.5 08/20/14 21:25 106-46-7 1,2-Dichloroethane ND ug/L 192 38.5 08/20/14 21:25 107-06-2 1,1-Dichloroethene ND ug/L 192 38.5 08/20/14 21:25 75-35-4 Tetrachloroethene ND ug/L 192 38.5 08/20/14 21:25 127-18-4 Trichlorodthene ND ug/L 192 38.5 08/20/14 21:25 79-01-6 Vinyl chloride ND ug/L 192 38.5 08/20/14 21:25 '75-01-4 Surrogates 1„2-Dichloroethane-d4 (S) 103 % 70-130 38.5 08/20/14 21:25 17060-07-0 1g Toluene-d8 (S) 94 % 67-135 38.5 08/20/14 21:25 2037-26-5 4-Bromofluorobenzene (S) 96 % 70-130 38.5 08/20/14 21:25 460-00-4 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 73.9 % 0.10 1 08/15/14 14:51 1010 Flashpoint,Closed Cup Analytical Method: EPA 1010 Flashpoint >200 deg F 70.0 1 08/27/14 03:40 733C S Reactive Cyanide Analytical Method: SW-846 7.3.3.2 Cyanide, Reactive ND mg/kg 3.8 1 08/18/14 19:34 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/2` 12014 09:62 AM without the written consent of Pace Analytical Services, Inc.. Page 5 of 21 aceAnalytkal www.pacelabs.com ANALYTICAL RESULTS Project: 08/13/14 140813-31 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Project No.: 92213461 Sample: 140813.31 Lab ID: 92213461001 Collected: 08/13/14 13:15 Received: 08/14/14 15:10 Matrix: Solid Resuits reported on a "dry -weight" basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 7358 Reactive Sulfide Analytical Method: SW-846 7.3.4.2 Sulfide, Reactive Date: 08/27/2014 09:62 AM ND mg/kg 38.2 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 08/18/14 15:00 Page 6 of 21 Analytical Results Southern Soil Builders 958 Hoots Road Roaring River, NC 28669� Receive Date: 09/22/2014 Reported: 09/26/2014 For: BRWA Comments: Sample, Number Parameter Sample ID Result Unit Method Analyzed Analyst 140922-17-01 Corrosivity BRWA 5.0 SW-846 09/23/2014 Pace Respectfully submitted, hO'P%-VVO-, Dena Myers NC Cert #440, NCDW Lert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 1 Client: d� P ' i � ' �J1 STATESVIILEANALYTICAL 122 Court Street • P.O. Box 228 Address: ' j �!" Statesville, NC 28687 (704) 872-4697 6 q Contact Person: e Phone # 3-c`iS7 �, j, .j f FAX# 5 3 Chain of. Custody Record . PO # Requisitioned by: (Time. Date) Customer Sample ID# Lab -ID # Time Sampled ( Grab Only) y) Date Sampled (Grab Only). a o Matrix Parameters requested for analysis Sludge w ww t i RL'L.i920 — y i7 ) !j C%U�.c ` / G? �2 /�l i y� .'C U ! itrr:s.�.4 Relinquished. by: Time 1.0 am, pm Date // :. Sampled by: F� Received by: Y ', -� -�. ;_ .. -- ' �. � Time I 1�_ �? .am,:p'� Date? �' _' /��. — Transported by: Relinquished by: Time -am,.pm Date Holding times met: Received by: Time am, pm Date —./_/_,,-� Compliance work: Composite Sampling #1: Time begin am, pm Date % / Non-compliance work: Time end am, pm Date 'Composite Lab Comments: Sampling #2 -lima begin am, pm Date 'Time end am, pm Date / / aceAnalXkal www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersviile, NC 28078 (704)875-9092 Project: 140922-17 Pace Project No.: 92218545 Sample: 140922-17 Lab ID: 92218645001 Collected: 09/22/14 11:00 Received: 09/23/14 16:00 Matrix: Solid Results reported on a "wet -weight" basis Parameters R I esu is Units Report Limit DF Prepared Analyzed CAS No, Qual 9045 pH toll Analytical Method: EPA 9045 pH at 25 Degrees C 5.0 Std. Units 0.10 1 09/25/14 15:45 H1 Date: 09/26/2014 01:34 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 9 ANN UAL PATHOGEN AND VEUTOK ATTRACTION RED UUTION FORM (02T Rules) Facility Name: Broad River Water Authority WWTP Name: Broad River Water Authority Monitoring Period: From 1/l/2014 To WQ Permit Number: NPDES Number: 12/31/2014 WQ0035576 NCO181035 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) D I Alt B (Alk Treatment) D Alt. C (Prior Testing) AID (No Prior Test) Process to Further Reduce Pathogengs D If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost 131 Heat Drying D Heat Treatment D Thermophilic D Beta Ray D Gamma Ray D Pasteurization Class B: Alt. (1) Fecal Density ® Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization D Air Drying D Composting D Aerobic Digestion D Anaerobic Digestion g on C] , If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in in Sludge Pathogen Density Nurn er o Excee- c Frequency' of Analysis Y Sample Type Analytical Tech - niame Minim Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids WN CFu 1000 mpn per gram of total solid (dry weight) 6.4 6.73 7 MPN/g 0 7' grab sm9221e Salmonella bacteria (in lieu of fecal coliform) 3 NTN per 4 grams total solid (dry weight) vector Attraction Reduction (15A NCAC 02T .1107) -Please indicate alternative performed: Alt.I (VS reduction) ® Alt. 2 (40-day bench) ® Alt. 3 (30-day bench) D I Alt. 4 (Spec. 02 uptake) Alt. 5 (14-Day Aerobic) ® Alt. 6 (Alk. Stabilization ® Alt 7 (Drying - Stable) D JAIt. 8 (Drying - Unstable) Alt. 9 (Injection) ® Alt. 10 (Incorporation) ® No vector attraction reduction alternatives were performed CEKTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." D "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction,and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." 5eft 6 04 -- � 0 �C.� Dennis Key Southern Soil Builders, Inc. ?re arer me and Title (type or print) Land Applier Name and Title (if applicable)(type or print) 3i ture o r � ' gn f epa Date Signature of Land Applier (if applicable) Date *Preparer is define n 40 CFR Part 503.9(r) and 15A NCAC '2T .1102 (26) DENR FORM PVRF 02T (12/2006)