Loading...
HomeMy WebLinkAboutWQ0035207_Residual Annual Report 2014_201503025�� RFcFll/F0 MAR Q 2 2015 'NFORMA T" NpROCE SI NG UNIT SYNAGRO CENTRAL, LLC, NC CLASS A RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0035207 2014 ANNUAL REPORT Synagro Central, LLC.. NC � f Class A Residuals Land Application Program 2014 Annual Report TABLE OF CONTENTS 1. Certification Form & Annual Operations Summary 2. Brunswick County WTP 3. Franklin WTP 4. Mooresville WTP S. Piedmont Triad Regional WTP ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: W00035207 County Statewide Year 2014 Facility Name (as shown on permit) Hood Creek WTP Lake Townsend WTP, Reidsville WTP, Franklin WTP. Chatham County North Water System, Randleman Lake WTP; Philadelphia Renewable BioFuels NPDES No. NC0057533, NC0081671, NC0046345, PWS 01-57-010, NC0084093, NC0087866. PAG-070012 Land Application Operator Synagro Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip PartA, and PartB and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summary: Total number of application fields in the permit: N/A Total number of fields utilized for land application during the year: 24 Total amount of dry tons applied during the year for all application sites: 1.489.75 Total number of acres utilized for land application during the year: 311.2 Part B — Annual Compliance Statement: Facility was compliant during calendar year 2014 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality X YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during,the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including thq�possibility of fines and imprisonment for knowing violations." Marshall Puryear, Technical Service Manager Permittee Name and Title (type or print) rm Date Jere- t9 2015 Signature of Preparer* Date gnature of Land Applier Date (if different from Permittee) (if different from Permittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T. 1102 (26) DENR FORM ACF (12/2006) 2014 ANNUAL OPERATIONS SUMMARY - LAND APPLICATION RRUNSWICK COUNTY, NC rsRUNSWICK COUNTY, NC HOOD CREEK WTP CAKE DRY METRIC MONTHNEAR AMOUNT UNIT DRY TONS UNIT TONS March 2014 870.49 W 167.40 D 151.84 April 2014 679.98 W 135.65 D 123.03 July 2014 1,486.97 W 207.72 D 188.38 September 2014 1,431.80 W 200.04 D 181.43 November 2014 918.22 W 121.76 D 110.44 December 2014 207.88 W 27.56 D 25.01 YEARLY TOTAL 5,595.34 W 860.13 D 780.13 2/17/2015 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: Laboratory Facility Name: BRUNSWICK COUNTY, NC A&L Eastern Laboratories Inc. NPDES#: or WQ# (residual only) WWTP Name: HOOD CREEK WTP Residuals Analysis Data Product Type WPC WPC WPC WPC Date Sampled (grab) or 01/27/14 04/14/14 07/15/14 10/01/14 Date Composited Percent Solids 19.23 19.95 13.97 13.26 PARAMETERS (mg/kg dry Weight) Arsenic 7 7 20 12 Cadmium <2 <2 <2 <2 Mercury <0.4 <0.4 <0.4 <0.4 Chromium 64 45 36 40 Copper 34 38 41 40 Lead 15 13 15 12 Molybdenum <5 <5 <5 <5 Nickel 27 20 17 16 Selenium <5 <5 <5 <5 Zinc 103 175 116 98 Total Phosphorus 4170 6750 890,0 7270 TKN 6140 6470 9160 7470 Ammonia -Nitrogen 312 952 1150 1510 Nitrate and Nitrite 39.5 <2 <2 <2 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties,pr submitting falsepformation, including the possibility of fines and imprisonment for knowing violations." �:l raV Date c DENR FORM RSSF (5/2003) Printed: Tuesday - February 17 2015 at 14:04:43 for: 2189 01 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: Laboratory Facility Name: BRUNSWICK COUNTY, NC A&L EasternLaboratories Inc. NPDES#: or WQ# (residual only) WWTP Name: HOOD CREEK WTP Residuals Analysis Data Product Type WPC WPC WPC WPC Date Sampled (grab) or 01/27/14 04/14/14 07/15/14 10/01/14 Date Composited Percent Solids 19.23 19.95 13.97 13.26 PARAMETERS (mg/kg dry weight) Aluminum 95700 97800 145000 131000 Calcium 3950 2260 2000 1590 Magnesium 1590 1150 1050 85'6 pH 6.24 6.88 6.84 6.56 Potassium 1080 668 684 647 Sodium 268 272 267 370 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties forobmitting falsAinforma�P, including the possibility of fines and imprisonment for knowing violations." X NATURE OF PREPARER) NR - Data Not Reported or Data Not Required Date DENR FORM RSSF-B (7/2002). Printed Tuesday - February 17, 2015 at 14:06:38 for: 2189 01 Page: 1 of 2 Report Number: 14-028-0204 Account Number: 46622 Submitted By: EDWARD STEPHENS Send To: SYNAGRO CENTRAUTECHNICAL MARY BREWER 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 97667 Sample Id : BRUNSWICK WTP A&L Eastern Laboratories, Inc.. 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271-696 wwwaleastern.com Project: BRUNSWICK WTP NC CERT#257 REPORT OF ANALYSIS Date Sampled: 1/27/2014 09:00:00 Date Received: 01/28/2014 00:00 Date Reported: 02/03/2014 Total Solids * 19.23 192300 100.0 JM 01/28/2014 15:00 SM-2540G Moisture * 80.77 100.0 JM 01/28/2014 15:00 SM-2540G Total Kjeldahl Nitrogen 0.61 6140 10.0 JM 01/29/2014 09:29 SM-4500-NH3C-TKN Total Phosphorus 0.42 4170 100 KM 01/29/2014 13:31 SW 6010C Total Potassium 0.11 1080 100 KM 01/29/2014 13:31 SW 6010C Total Sulfur 0.37 3700 100 KM 01/29/2014 13:31 SW 6010C Total Calcium 0.40 3950 100 KM 01/29/2014 13:31 SW 6010C Total Magnesium 0.16 1590 100 KM 01/29/2014 13:31 SW 6010C Total Sodium 0.03 268 100 KM 01/29/2014 13:31 SW 6010C Total Iron 29500 100 KM 01/29/2014 13:31 SW 6010C Total Aluminum 95700 100 KM 01/29/2014 13:31 SW 6010C Total Manganese 876 5 KM 01/29/2014 13:31 SW 6010C Total Copper 34 5 KM 01/29/2014 13:31 SW 6010C Total Zinc 103 5 KM 01/29/2014 13:31 SW 6010C Ammonia Nitrogen 0.03 312 10.0 JM 01/29/2024 00:00 SM-4500-NH3C Organic N 0.58 5828 10.0 01/29/2014 09:29 CALCULATION Nitrate+Nitrite-N 39.5 2.00 JM 01/29/2014 09:30 SM-450ONO3F Total Cadmium <2.0 2.0 KM 01/29/2014 13:31 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Page: 2 of 2 Report Number: 14-028-0204 Account Number: 46622 Submitted By: EDWARD STEPHENS Send TO: •SYNAGRO CENTRAL/TECHNICAL MARY BREWER 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 97667 Sample Id : BRUNSWICK WTP �LA&L Eastern, Laboratories, Inc._ .7621 Whitepine Road Richmond, Virginia 23237 (804)'743.9401 Fax (804) 271.6446 wwwaleastern.com Project: BRUNSWICK WTP NC CERT#257 REPORT OF ANALYSIS Date Sampled: 1/27/2014 09:00:00 Date Received: 01/28/2014 00:00 Date Reported: 02/03/2014 Total Chromium 64 5 KM 01/29/2014 13:31 SW 601OC Total Nickel 27 5 KM 01/29/2014 13:31 SW 601OC Total Lead 15 5 KM 01/29/2014 13:31 SW 601OC Total Arsenic 7.0 3.0 KM 01/29/2014 13:31 SW 601OC Total Mercury <0.4 0.4 KM 01/29/2014 09:00 SW-7471 B Total Selenium <5.0 5.0 KM 01/29/2014 13:31 SW 601OC pH (Standard Units) * 6.24 2.00 JM 01/29/2014 09:29 SW-9045D Total Molybdenum <5 5 KM 01/29/2014 13:31 SW 601OC Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Al"; ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt SAMPLING LOG N A , f N ® I' q� IpAIN IIIIIIIIIIIIaIiIII�IIIIIII�IIIINI�I�IIIIIIIIIIIIIII�IQI OF CUSTODY ORD & ANALYS S R6 os,�a cusroMER SYN14GR4 SOUTHEAST 80 SYNAGROCENTRAUTECHNICAL 10:47:26 RECORD BRUNSWICK WTP sampling �,,, r m%�(efl-Qsd PROJECT MANAGER:were procedures used during collection of these samples. Phone: 7� J� 0A SAMPLER A & L CUSTOMER SAMPLING SAMPLE # OF SAMPLING METHOD METHOD LAB # SAMPLE I.D. LOCATION TYPE CONTAINERS DATE TIME PRESERVED SHIPPED RelinWish mpler: Date Time Recieved by: REMARKS: — Izz w M�� . /-,2 r-A is 30 Relinquist d by: �,� Date Time Recieved by: Relinquished by: ate Time Reaie by: 0� 1 U'ou SPECIAL INSTRUCTIONS: For monitoring purposes. PO#: SAMPLE ANALYSIS REQUEST 1'D' SL1 SL2 NH4 N N037N Or N Cd Cr Ni Pb As Hg Se pH CaCO3 e uiv. Volatile Solids Mo CI NO2 -NI `` t ry 140 ko k0o A0001" Po 100r to ko 1.0" po toot 1,00f i to SL1; Total Solids (Moisture), Total Kjeldahl Nitrogen, Phosphorus, and Potassium SL2: Basic Test SL1 plus Sulfur, Calcium, Magnesium, Sodium, Iron, Aluminum, Manganese, Copper and Zinc White - A & L Canary - MANAGER COPY Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date Report Range Ratio 2189-01-WPC-NC BRUNSWICK COUNTY, NC HOOD CREEK WTP 1/27/2014 1/l/2014-3/31/2014 0.3978 CAKE Na mg/I = (Na mg/kg x % Solids) -= 100 = (268 x 19.2300) _ 100 = 51.5364 Ca mg/I = (Ca mg/kg x % Solids) = 100 = (3950 x 19.2300) =100 = 759.585 Mg mg/I = (mg mg/kg x % Solids) _ 100 = (1590 x 19.2300) = 100 = 305.757 Na meq = Na mg/I = Molec.Wgt.Na = 51.5364 + 23 = 2.24071 Ca meq = Ca mg/I = Molec.Wgt.Ca = 759.585 _ 20 = 37.9793 Mg meq = Mg mg/I = Molec.Wgt.Mg = 305.757 _ 12 = 25.4797 SAR = Na meq + SgrRoot[0.5 x (Ca meq + Mg meq)] = 2.24071 = SgrRoot[0.5(37.9793+25.4797)] = 0.397791 Printed: 2/17/2015 Page 1 14:11 Page: 1 of 2 Report Number: 14-105-0205 Account Number: 46622 Submitted By: EDWARD STEPHENS Send To: SYNAGRO CENTRAL/TECHNICAL MARY BREWER 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 98972 Sample Id : BRUNSWICK WTP w A&L Eastern Laboratories, Inc- 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271-6446 wwW.aleastern,gom Project: BRUNSWICK WTP/NC CERT#257 REPORT OF ANALYSIS Date Sampled: 4/14/2014 13:00:00 Date Received: 04/15/2014 00:00 Date Reported: 04/22/2014 Total Solids " 19.95 199500 100.0 JM 04/15/2014 14:10 SM-2540G Moisture * 80.05 100.0 JM 04/15/2014 14:10 SM-2540G Total Kjeldahl Nitrogen 0.65 6470 10.0 JM 04/16/2014 08:30 SM-4500-NH3C-TKN Total Phosphorus 0.68 6750 100 KM 04/16/2014 14:52 SW 6010C Total Potassium 0.07 .668 100 KM 04/16/2014 14:52 SW 6010C Total Sulfur 0.27 2650 100 KM 04/16/2014 14:52 SW 6010C Total Calcium 0.23 2260 100 KM 04/16/2014 14:52 SW 6010C Total Magnesium 0.12 1150 100 KM 04/16/2014 14:52 SW 6010C Total Sodium 0.03 272 100 KM 04/16/2014 14:52 SW 6010C Total Iron 21600 100 KM 04/16/2014 14:52 SW 6010C Total Aluminum 97800 100 KM 04/16/2014 14:52 SW 6010C Total Manganese 917 5 KM 04/16/2014 14:52 SW 6010C Total Copper 38 5 KM 04/16/2014 14:52 SW 6010C Total Zinc 175 5 KM 04/16/2014 14:52 SW 6010C Ammonia Nitrogen 0.10 952 10.0 JM 04/16/2014 08:30 SM-4500-NI3C Organic N 0.55 5518 10.0 04/16/2014 08:30 CALCULATION Nitrate+Nitrite-N <2.00 2.00 im 04/16/2014 08:40 SM-450ONO3F Total Cadmium <2.0 2.0 KM 04/16/2014 14:52 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Page: 2 of 2 Report Number: 14-105-0205 Account Number: 46622 Submitted By: EDWARD STEPHENS Send To: SYNAGRO CENTRAL/TECHNICAL MARY BREWER 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 98972 Sample Id : BRUNSWICK WTP A � A&L Eastem Laboratories, Inc.. 7.621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271-WG WWW.aleastern.com Project: BRUNSWICK WTP/NC CERT#257 REPORT OF ANALYSIS Date Sampled: 4/14/2014 13:00:00 Date Received: 04/15/2014 00:00 Date Reported: 04/22/2014 Total Chromium 45 5 KM 04/16/2014 14:52 SW 6010C Total Nickel 20 5 KM 04/16/2014 14:52 SW 6010C Total Lead 13 5 KM 04/16/2014 14:52 SW 6010C Total Arsenic 7.0 3.0 KM 04/16/2014 14:52 SW 6010C Total Mercury <0.4 0.4 KM 04/16/2014 09:00 SW-7471 B Total Selenium <5.0 5.0 KM 04/16/2014 14:52 SW 6010C pH (Standard Units) * 6.88 2.00 JM 04/16/2014 08:30 SW-9045D Total Molybdenum <5 5 KM 04/16/2014 14:52 SW 6010C Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Al", "Ca", AND "NO3/NO2-N". ALL OTHER QC DATA IS ACCEPTABLE. All,values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date Report Range Ratio 2189-01-WPC-NC BRUNSWICK COUNTY, NC HOOD CREEK WTP4114/2014 4/1/2014-6/30/2014 0.5169 CAKE Na mg/I = (Na mg/kg x % Solids) _ 100 = (272 x 19.9500) =100 = 54.264 Ca mg/I = (Ca mg/kg x % Solids) + 100 = (2260 x 19.9500) =100 = 450.87 Mg mg/I = (mg mg/kg x % Solids) _ 100 = (1150 x 19.9500) _ 100 = 229.425 Na meq = Na mg/I = Molec.Wgt.Na = 54.264 = 23 = 2.3593 Ca meq = Ca mg/I + Molec.Wgt.Ca = 450.87 _ 20 = 22.5435 Mg meq = Mg mg/I + Molec.Wgt.Mg = 229.425 _ 12 = 19.1188 SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 2.3593 + SgrRoot[0.5(22.5435+19.1188)] = 0.516925 Printed: 2/17/2015 Page 1 14:11 Page: 1 of 2 Report Number: 14-199-0201 � L A&L Eastern Laboratones, Inc.. Account Number: 46622 •7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401, Fax (804) 271-6446 Submitted By: MARSHALL PURYEAR www.aleastern.com Send To: SYNAGRO CENTRAL/TECHNICAL Project: BRUNSWICK WTP MAR BREWER NC CERT#257 284 BOGER RD MOCKSVILLE , NC 27028 REPORT OF ANALYSIS Lab Number: 56556 Sample Id : BRUNSWICK WTP Date Sampled: 7/15/2014 14:00:00 Date Received: 07/18/2014 00:00 Date Reported: 07/24/2014 Total Solids * 13.97 139700 100.0 JM 07/18/2014 15:35 SM-2540G Moisture 86.03 100.0 JM 07/18/201415:35 SM-2540G Total Kjeldahl Nitrogen 0.92 9160 10.0 JM 07/21/2014 07:59 SM-4500-NH3C-TKN Total Phosphorus 0.89 8900 100 KM 07/22/2014 14:36 SW 6010C Total Potassium 0.07 684 100 KM 07/22/2014 14:36 SW 6010C Total Sulfur 0.37 3650 100 KM 07/22/2014 14:36 SW 6010C Total Calcium 0.20 2000 100 KM 07/22/2014 14:36 SW 6010C Total Magnesium 0.11 1050 100 KM 07/22/2014 14:36 SW 6010C Total Sodium 0.03 267 100 KM 07/22/2014 14:36 SW 6010C Total Iron 29500 100 KM 07/22/2014 14:36 SW 6010C Total Aluminum 145000 100 KM 07/22/2014 14:36 SW 6010C Total Manganese 2640 5 KM 07/22/2014 14:36 SW 6010C Total Copper 41 5 KM 07/22/2014 14:36 SW 6010C Total Zinc 116 5 KM 07/22/2014 14:36 SW 6010C Ammonia Nitrogen 0.12 1150 10.0 JM 07/21/2014 07:59 SM-4500-NI3C Organic N 0.80 8010 10.0 07/21/2014 07:59 CALCULATION Nitrate+Nitrite-N <2.00 2.00 JM 07/21/2014 08:00 SM-450ONO3F Total Cadmium <2.0 2.0 KM 07/22/2014 14:36 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining bur prior written authorization. Debbie Holt Page: 2 of 2 Report Number: 14-199-0201 Account Number: 46622 Submitted By: MARSHALL PURYEAR Send To: SYNAGRO CENTRAUTECHNICAL MARY BREWER 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 56556 Sample Id: BRUNSWICK WTP �LA&L Eastern Laboratories,, Inc._ 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271-8446 wwwaleaAern.00.M Project: BRUNSWICK WTP NC CERT#257 REPORT OF ANALYSIS Date Sampled: 7/15/2014 14:00:00 Date Received: 07/18/2014 00:00 Date Reported: 07/24/2014 Total Chromium 36 5 KM 07/22/2014 14:36 SW 6010C Total Nickel 17 5 KM 07/22/2014 14:36 SW 6010C Total Lead 15 5 KM 07/22/2014 14:36 SW 6010C Total Arsenic 20.0 3.0 KM 07/22/2014 14:36 SW 6010C Total Mercury <0.4 0.4 KM 07/23/2014 09:00 SW-7471 B Total Selenium <5.0 5.0 KM 07/22/2014 14:36 SW 6010C pH (Standard Units) * 6.84 2.00 JM 07/21/2014 07:59 SW-9045D Total Volatile Solids 40.97 409700 100.0 JM 07/18/2014 15:35 SM-2540G Total Molybdenum <5 5 KM 07/22/2014 14:36 SW 6010C Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR "API. ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date Report Range Ratio 2189-01-WPC-NC BRUNSWICK COUNTY, NC HOOD CREEK WTP7/15/2014 711/2014-9130/2014 0.4481 CAKE Na mg/I = (Na mg/kg x % Solids) _ 100 = (267 x 13.9700) = 100 = 37.2999 Ca mg/I = (Ca mg/kg x % Solids) _ 100 = (2000 x 13.9700) + 100 = 279.4 Mg mg/I = (mg mg/kg x % Solids) = 100 = (1050 x 13.9700) = 100 = 146.685 Na meq = Na mg/I _ Molec.Wgt.Na = 37.2999 _ 23 = 1.62173 Ca meq = Ca mg/I _ Molec.Wgt.Ca = 279.4 = 20 = 13.97 Mg meq = Mg mg/I = Molec.Wgt.Mg = 146.685 = 12 = 12.2238 SAR = Na meq _ SgrRoot[0.5 x (Ca meq + Mg meq)] = 1.62173 = SgrRoot[0.5(13.97+12.2238)] = 0.448122 Printed: 2/17/2015 Page 1 14:11 Page: i of 2 Report Number: 14-276-0214 Account Number: 46622 Submitted By: CREIGHTON BROWIN Send To: SYNAGRO CENTRAL/TECHNICAL MARY BREWER 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 57937 Sample Id : BRUNSWICK WTP @IDL A&L Eastern Laboratories, Inc._ .7621 Whitepine Road Richmond, Virginia 23237 (804) 743 9901 Fax (804) 271 6446 www,aleastem.com Project: BRUNSWICK WTP/NC CERT#257 REPORT OF ANALYSIS Date Sampled: 10/1/2014 11:30:00 Date Received: 10/03/2014 00:00 Date Reported: 10/08/2014 Total Solids * 13.26 132600 100.0 JM 10/03/2014 14:35 SM-254OG Moisture * 86.74 100.0 JM 10/03/2014 14:35 SM-2540G Total Kjeldahl Nitrogen 0.75 7470 10.0 JM 10/07/2014 08:30 SM-4500-NH3C-TKN Total Phosphorus 0.73 7270 100 KM 10/06/2014 11:30 SW 601 OC Total Potassium 0.06 647 100 KM 10/06/2014 11:30 SW 601 OC Total Sulfur 0.33 3310 100 KM 10/06/2014 11:30 SW 601 OC Total Calcium 0.16 1590 100 KM 10/06/2014 11:30 SW 601 OC Total Magnesium 0.09 856 100 KM 10/06/2014 11:30 SW 601 OC Total Sodium 0.04 370 100 KM 10/06/2014 11:30 SW 601 OC Total Iron 24500 100 KM 10/06/2014 11:30 SW 601 OC Total Aluminum 131000 100 KM 10/06/2014 11:30 SW 601 OC Total Manganese 811 5 KM 10/06/2014 11:30 SW 601 OC Total Copper 40 5 KM 10/06/2014 11:30 SW 601 OC Total Zinc 98 5 KM 10/06/2014 11:30 SW 601 OC Ammonia Nitrogen 0.15 1510 10.0 JM 10/06/2014 08:30 SM-4500-NI3C Organic N 0.60 5960 10.0 10/06/2014 08:30 CALCULATION Nitrate+Nitrite-N <2.00 2.00 JM 10/06/2014 08:30 SM-450ONO3F Total Cadmium <2.0' 2.0 KM 10/06/2014 11:30 SW 601 OC All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Page: 2 of 2 Report. Number: 14-276-0214 Account Number: 46622 Submitted By: CREIGHTON BROWIN Send To: SYNAGRO CENTRAL/TECHNICAL MARY BREWER 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 57937, Sample Id : BRUNSWICK WTP A&L Eastern Laboratories, Inc._ 7621 Whitepine Road Richmond, Virginia 23237(804) 743-9401 Fax (804) 271-6446 wwwaleastem.com Project: BRUNSWICK WTP/NC CERT#257 REPORT OF ANALYSIS Date Sampled: 10/1/2014 11:30:00 Date Received: 10/03/2014 00:00 Date Reported: 10/08/2014 Total Chromium 40 5 KM 10/06/2014 11:30 SW 6010C Total Nickel 16 5 KM 10/06/2014,11:30 SIN 6010C Total Lead 12 5 KM 10/06/2014 11:30 SW 6010C Total Arsenic 12.0 3.0 KM 10/06/2014 11:30 SW 6010C Total Mercury <0.4 0.4 KM 10/07/2014 14:00 SW-7471 B Total Selenium <5.0 5.0 KM 10/06/2014 11:30 SW 6010C pH (Standard Units) * 6.56 2.00 JM 10/06/2014 08:30 SW-9045D Total Volatile Solids 41.40 414000 100.0 JM 10/03/2014 14:35 SM-254OG Total Molybdenum <5 5 KM 10/06/2014 11:30 SW 6010C Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE LRB WAS OUT OF LIMITS FOR "NO3/NO2-N". THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Se". THE MSD WAS OUT OF LIMITS FOR "Al". ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or otherpublic announcements without obtaining our prior written authorization. 10077rair•7III Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date ReportRange Ratio 2189-01-WPC-NC BRUNSWICK COUNTY, NC HOOD CREEK WTP10/1/2014 10/1/2014-12/31/2014 0.6745 CAKE Na mg/I = (Na mg/kg x % Solids) = 100 = (370 x 13.2600) _ 100 = 49.062 Ca mg/I = (Ca mg/kg x % Solids) _ 100 = (1590 x 13.2600) _ 100 = 210,834 Mg mg/I = (mg mg/kg x % Solids) _ 100 = (856 x 13.2600) t- 100 = 113.506 Na meq = Na mg/I — Molec.Wgt.Na = 49.062 _ 23 = 2.13313 Ca meq = Ca mg/I + Molec.Wgt.Ca = 210.834 _ 20 = 10.5417 Mg meq = Mg mg/I _ Molec.Wgt.Mg = 113.506 _ 12 = 9.4588 SAR = Na meq - SgrRoot[0.5 x (Ca meq + Mg meq)] = 2.13313 _ SgrRoot[0.5(10.5417+9.4588)] = 0.674547 Printed: 2/17/2015 Page 1 14:11 ANNUAL LAND APPLICATION FIELD SUMMARY FORM FACILITY NAME: BRUNSWICK COUNTY, NC PREDOMINANT SOIL SERIES: KRUEB OWNER: ORTON PLANTATION HOLDINGS PERMIT #: NC-BR-X20 ANNUAL DRY TONS APPLIED: 7.69 SITE #: NC BR OOX20 FIELD# : BR OOX20 0092 OPERATOR: DILLON EPP CATION EXCHANGE CAPACITY (NON-503): RESIDUAL SOURCE(S):* See list at bottom of report ACRES UTILIZED: 4.10 ACRES PERMITTED: 4.10 Page Lune Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Acre Solids 3/8/14 39.98 (W) 9.751 19.23 1.875 BRCHCWI MOIST 0-<1/2" SUR 0.5 0.40 6,140.0 p 312.00 p 39.50 p F 2527 1 CAUCASION/OLD WORLD BLUESTE Mar-14 39.98 (W) 9.751 1 Total Wet Tons/Ac: 9.75 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 0.026 0.008 0.240 0.128 0.056 0.002 0.019 0.101 0.019 0.386 15.64 9 Cumulative lbs/acre 0.146 1 0.027 1 0.727 1 0.406 1 0.195 0.005 0.068 1 0.300 0.068 1.320 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 ^^ BRCHCWPC = BRUNSWICK COUNTY, NC HOOD CREEK WTP CAKE Xli ©,0?0/ts- (SIGNATURE OF LAND APPLIER)_- DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Licorporation 1.0 * Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 FACILITY NAME: BRUNSWICK COUNTY, NC OWNER: ORTON PLANTATION HOLDINGS SITE #: NC BR OOX20 FIELD# : BR OOX20 0095 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: KRUEB PERMIT #: NC-BR-X20 ANNUAL DRY TONS APPLIED: 38.34 OPERATOR: DILLON EPP CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 2.10 ACRES PERMITTED: 2.10 Page Lune Applied *** Date Lbs/Ac DATE or allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Dry Tons Per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppin) Crop MONTH Total Per Acre Solids 3/8/14 23.22 (W) 11.057 19.23 2.126 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,140.0 p 312.00 p 39.50 p 2527 I CAUCASION/OLD WORLD BLUESTE 3/8/14 43.09 (W) 20.519 19.23 3.946 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,140.0 p 312.00 p 39.50 p 2527 I CAUCASION/OLD WORLD BLUESTE 3/8/14 43.43 (W) 20.681 19.23 3977 BRCHCWF MOIST 0-<I/2" SUR 0.5 0.40 6,140.0 p 312.00 p 39.50 p 2527 I CAUCASION/OLD WORLD BLUESTE 3/8/14 44.41 (W) 21.148 19.23 4.067 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,140.0 p 312.00 p 39.50 p 2527 I CAUCASION/OLD WORLD BLUESTE 3/8/14 45.20 (W) 21.524 19.23 4.139 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,140.0 p 312.00 p 39.50 p 2527 CAUCASION/OLD WORLD BLUESTE Mar-14 199.35 (W) 94.929 Total Wet Tons/Ac: 94.93 As Cd Cr Cu Ph Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 0.256 0.073 2.337 1.241 0.548 0.015 0.183 0.986 0.183 3.760 152.24 92 Cumulative lbs/acre 0.416 0.100 2.992 1.616 0.735 0.020 0.249 1.253 0.249 5.017 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop 110 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 BRCHCWPC = BRUNSWICK COUNTY, NC HOOD CREEK WTP CAKE X Ik/ leQ41 S, (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/hicorporation 1.0 * Application Method: SUR - Surface, INJ -Injection, SURIN - Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 FACILITY NAME: BRUNS WICK COUNTY, NC OWNER: ORTON PLANTATION HOLDINGS SITE #: NC BR OOX20 FIELD# : BR OOX20 0096 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: KRUEB PERMIT #: NC-BR-X20 ANNUAL DRY TONS APPLIED: 12.67 OPERATOR: DILLON EPP CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 1.90 ACRES PERMITTED: 1.90 Page Lune Applied *** Date Lbs/Ac DATE or allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Dry Tons per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppm) Crop MONTH Total Per Acre Solids 3/8/14 21.09 (W) 11.100 19.23 2.135 BRCHCWI MOIST 0-<1/2" SUR 0.5 0.40 6,140.0 p 312.00 p 39.50 p 2527 I CAUCASION/OLD WORLD BLUESTE 3/8/14 22.11 (W) 11.637 19.23 2.238 BRCHCWF MOIST 0-<I/2" SUR 0.5 0.40 6,140.0 p 312.00 p 39.50 p 2527 I CAUCASION/OLD WORLD BLUESTE 3/8/14 22.71 (W) 11.953 19.23 2.298 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,140.0 p 312.00 p 39.50 p 2527 CAUCASION/OLD WORLD BLUESTE Mar-14 65.91 (W) 34.690 Total Wet Tons/Ac: 34.69 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 34 0.093 0.027 0.854 0.454 0.200 0.005 0.067 0.360 0.067 1.374 55.63 Cumulative Ibs/acre 0.136 0.034 1.026 0.552 0.249 0.007 0.084 0.431 0.084 3•�,r'.,�,°..;� 1.705 ;, ,;, „-: Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop " 1.. FD Cumulative Pollutant Loading Rate Limit (Ibs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 BRCHCWPC = BRUNSWICK COUNTY, NC HOOD CREEK WTP CAKE e" - X 01- 20 r (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = pp- or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 FACILITY NAME: BRUNSWICK COUNTY, NC OWNER: ORTON PLANTATION HOLDINGS SITE #: NC BR 0OX20 FIELD# : BR 0OX20 0098 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: BAYMEADE PERMIT #: NC-BR-X20 ANNUAL DRY TONS APPLIED: 121.76 OPERATOR: DILLON EPP CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 13.00 ACRES PERMITTED: 13.00 Page Lime Applied *** Date Lbs/Ac DATE or allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Dry Tons Per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppm) Crop MONTH Total Per Acre Solids 11/3/14 20.72 (W) 1.594 13.26 0.211 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 7,470.0 p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 11/3/14 21.15 (W) 1.627 13.26 0.216 BRCHCWF MOIST 0-<I/2" SUR 0.5 0.40 7,470.0 p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 11/3/14 21.35 (W) 1.642 13.26 0.218 BRCHCWF MOIST 0-<I/2" SUR 0.5 0.40 7,470.0 p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 11/3/14 82.41 (W) 6.339 13.26 0.841 BRCHCWI MOIST 0-<I/2" SUR 0.5 0.40 7,470.0 p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 11/3/14 84.86 (W) 6.528 13.26 0.866 BRCHCWF MOIST 0-<I/2" SUR 0.5 0.40 7,470.0 p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 11/4/14 19.88 (W) 1.529 13.26 0.203 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 7,470.0 p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 11/4/14 20.95 (W) 1.612 13.26 0.214 BRCHCWF MOIST 0-<I/2" SUR 0.5 0.40 7,470.0,p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 11/4/14 21.25 (W) 1.635 13.26 0.217 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 7,470.0 p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 11/4/14 41.04 (W) 3.157 13.26 0.419 BRCHCWF . MOIST 0-<I/2" SUR 0.5 0.40 7,470.0�p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 11/4/14 62.95 (W) 4.842 13.26 0.642 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 7,470.0,p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 11/5/14 20.61 (W) 1.585 13.26 0.210 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 7,470.0-p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 11/5/14 21.66 (W) 1.666 13.26 0.221 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 7,470.0 p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 11/5/14 42.12 (W) 3.240 13.26 0.430 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 7,470.0,p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 11/5/14 42.55 (W) 3.273 13.26 0.434 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 7,470.0,p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 11/5/14 42.69 (W) 3.284 13.26 0.435 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 7,470.0-p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 11/5/14 97.33 (W) 7.487 13.26 0.993 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 7,470.0�p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 11/7/14 22.06 (W) 1.697 13.26 0.225 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 7,470.0 p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 11/7/14 42.75 (W) 3.288 13.26 0.436 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 7,470.0-p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 11/7/14 63.97 (W) 4.921 13.26 0.652 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 7,470.0-p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 11/18/14 20.54 (W) 1.580 13.26 0.210 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 7,470.0-p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 11/18/14 20.82 (W) 1.602 13.26 0.212 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 7,470.0-p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE I1/18/14 21.19 (W) 1.630 13.26 0.216 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 7,470.0-p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 11/18/14 63.37 (W) 4.875 13.26 0.646 BRCHCWF MOIST 0-<I/2" SUR 0.5 0.40 7,470.0-p 1,510.00 p 2.00 p 3141 CAUCASION/OLD WORLD BLUESTE Nov-14 918.22 (W) 70.633 FACILITY NAME: BRUNSWICK COUNTY, NC OWNER: ORTON PLANTATION HOLDINGS SITE #: NC BR 0OX20 FIELD#: BR 0OX20 0098 RESIDUAL SOURCE(S):* See list at bottom ofreport IANNUAL LAND APPLICATION FIELD SUMMARY FORM I PREDOMINANT SOIL SERIES: BAYMEADE PERMIT #: NC-BR-X20 ANNUAL DRY TONS APPLIED: 121.76 OPERATOR: DILLON EPP CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 13.00 ACRES PERMITTED: 13.00 Page : 2 Lime Applied *** Date Lbs/Ac jallons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppni) Crop MONTH Total Per Acre Solids Total Wet Tons/Ac: 70.63 As Cd Cr Cu. Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 59 0.225 0.037 0.749 0.749 0.225 0.007 0.094 0.300 0.094 1.836 136.18 Cumulative lbs/acre 0.225 0.037 0.749 0.749 0.225 0.007 0.094 0.300 0.094 1.836 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop W %* 192 4 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 V 15.0 375.0 89.0 2500.0 BRCHCWPC = BRUNSWICK COUNTY, NC HOOD CREEK WTP CAKE x 41ra 0 (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A =Not Applicable NR =Not Reported or Not Required % = percent p = ppm or mg/kg Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 Application Method: SUR-Surface, INJ -Injection, SURIN - Incorporation See Site pH &Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 ANNUAL LAND APPLICATION FIELD SUMMARY FORM FACILITY NAME: BRUNSWICK COUNTY, NC PREDOMINANT SOIL SERIES: KRUEB OWNER: ORTON PLANTATION HOLDINGS PERMIT #: NC-BR-X20 ANNUAL DRY TONS APPLIED: 244.35 SITE #: NC BR OOX20 FIELD# : BR OOX20 0099 OPERATOR: DILLON EPP CATION EXCHANGE CAPACITY (NON-503): RESIDUAL SOURCE(S):* See list at bottom of report ACRES UTILIZED: 11.80 ACRES PERMITTED: 11.80 Page Lime Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Acre Solids 3/8/14 21.14 (W) 1.792 19.23 0.345 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,140.0 p 312.00 p 39.50 p 2527 I CAUCASION/OLD WORLD BLUESTE 3/8/14 41.05 (W) 3.479 19.23 0.669 BRCHCWF MOIST 0-<I/2" SUR 0.5 0.40 6,140.0 p 312.00 p 39.50 p 2527 I CAUCASION/OLD WORLD BLUESTE 3/8/14 87.78 (W) 7.439 19.23 1.431 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,140.0 p 312.00 p 39.50 p 2527 I CAUCASION/OLD WORLD BLUESTE 3/10/14 21.31 (W) 1.806 19.23 0.347 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,140.0 p 312.00 p 39.50 p 2527 I CAUCASION/OLD WORLD BLUESTE 3/10/14 42.81 (W) 3.628 19.23 0.698 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,140.0 p 312.00 p 39.50 p 2527 I CAUCASION/OLD WORLD BLUESTE 3/10/14 42.99 (W) 3.643 19.23 0.701 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,140.0 p 312.00 p 39.50 p 2527 I CAUCASION/OLD WORLD BLUESTE 3/10/14 43.02 (W) 3.646 19.23 0.701 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,140.O,p 312.00 p 39.50 p 2527 I CAUCASION/OLD WORLD BLUESTE 3/10/14 43.62 (W) 3.697 19.23 0.711 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,140.O,p 312.00 p 39.50 p 2527 I CAUCASION/OLD WORLD BLUESTE 3/10/14 43.88 (W) 3.719 19.23 0.715 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,140.O-p 312.00 p 39.50 p 2527 I CAUCASION/OLD WORLD BLUESTE 3/10/14 44.32 (W) 3.756 19.23 0.722 BRCHCWF MOIST 0-<I/2" SUR 0.5 0.40 6,140.O-p 312.00 p 39.50 p 2527 CAUCASION/OLD WORLD BLUESTE 3/10/14 44.32 (W) 3.756 19.23 0.722 BRCHCWF MOIST 0-<I/2" SUR 0.5 0.40 6,140.O-p 312.00 p 39.50 p 2527 CAUCASION/OLD WORLD BLUESTE 3/10/14 44.43 (W) 3.765 19.23 0.724 BRCHCWF MOIST 0-<I/2" SUR 0.5 0.40 6,140.O-p 312.00 p 39.50 p 2527 CAUCASION/OLD WORLD BLUESTE 3/10/14 44.58 (W) 3.778 19.23 0.727 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,140.O-p 312.00 p 39.50 p 2527 CAUCASION/OLD WORLD BLUESTE Mar-14 565.25 (W) 47.904 4/1/14 41.64 (W) 3.529 19.95 0.704 BRCHCWF MOIST 0-<112" SUR 0.5 0.40 6,470.O p 952.00 p 2.00 p 2685 I CAUCASION/OLD WORLD BLUESTE 4/1/14 43.27 (W) 3.667 19.95 0.732 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,470.O p 952.00 p 2.00 p 2685 I CAUCASION/OLD WORLD BLUESTE 4/1/14 43.86 (W) 3.717 19.95 0.742 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,470.O p 952.00 p 2.00 p 2685 I CAUCASION/OLD WORLD BLUESTE 4/12/14 18.65 (W) 1.581 1995 0.315 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,470.O p 952.00 p 2.00 p 2685 I CAUCASION/OLD WORLD BLUESTE 4/12/14 65.87 (W) 5.582 19.95 1.114 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,470.O-p 952.00 p 2.00 p 2685 I CAUCASION/OLD WORLD BLUESTE 4/14/14 44.13 (W) 3.740 19.95 0.746 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,470.O-p 952.00 p 2.00 p 2685 I CAUCASION/OLD WORLD BLUESTE 4/14/14 64.15 (W) 5.436 19.95 1.085 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,470.O,p 952.00 p 2.00 p 2685 I CAUCASION/OLD WORLD BLUESTE 4/18/14 22.18 (W) 1.880 19.95 0.375 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,470.O-p 952.00 p 2.00 p 2685 I CAUCASION/OLD WORLD BLUESTE 4/18/14 22.27 (W) 1.887 19.95 0.377 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,470.O-p 952.00 p 2.00 p 2685 I CAUCASION/OLD WORLD BLUESTE 4/18/14 63.99 (W) 5.423 19.95 1.082 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,470.O p 952.00 p 2.00 p 2685 I CAUCASION/OLD WORLD BLUESTE 4/22/14 21.84 (W) 1.851 19.95 0.369 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,470.O,p 952.00 p 2.00 p 2685 I CAUCASION/OLD WORLD BLUESTE 4/22/14 63.38. (W) 5.371 19.95 1.072 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,470.O p 952.00 p 2.00 p 2685 I CAUCASION/OLD WORLD BLUESTE 4/22/14 64.17 (W) 5.438 19.95 1.085 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,470.O p 952.00 p 2.00 p 2685 I CAUCASION/OLD WORLD BLUESTE 4/25/14 18.48 (W) 1.566 19.95 0.312 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,470.0p 952.00 p 2.00 p 2685 I CAUCASION/OLD WORLD BLUESTE 4/25/14 37.87 (W) 3.209 19.95 0.640 BRCHCWF MOIST 0-<1/21" SUR 0.5 0.40 6,470.O,p 952.00 p 2.00 p 2685 I CAUCASION/OLD WORLD BLUESTE 4/25/14 44.23 (W) 3.748 19.95 0.748 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 6,470.O p 952.00 p 2.00 p 2685 CAUCASION/OLD WORLD BLUESTE Apr-14 679.98 (W) 57.625 ANNUAL LAND APPLICATION FIELD SUMMARY FORM FACILITY NAME: BRUNSWICK COUNTY, NC PREDOMINANT SOIL SERIES: KRUEB OWNER: ORTON PLANTATION HOLDINGS PERMIT #: NC-BR-X20 ANNUAL DRY TONS APPLIED: 244.35 SITE #: NC BR OOX20 FIELD# : BR OOX20 0099 OPERATOR: DILLON EPP CATION EXCHANGE CAPACITY (NON-503): RESIDUAL SOURCE(S):* See list at bottom of report ACRES UTILIZED: 11.80 ACRES PERMITTED: 11.80 Page : 2 Lime Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip, cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Acre Solids Total Wet Tons/Ac: 105.53 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 108 0.290 0.083 2.214 1.500 0.575 0.017 0.207 0.957 0.207 5.921 232.02 Cumulative lbs/acre 0.290 0.083 2.214 1.500 0.575 6.017 0.207 0.957 0.207 5.921 Permit PAN Limit (Ibs/acre) 1st Crop/2nd Crop i �. 110 , FD Cumulative Pollutant Loading Rate Limit (Ibs/acre) 36.6 34.8 '1 " 1339.0 267.9 15.0 375.0 89.0 2500.0 . BRCHCWPC = BRUNSWICK COUNTY, NC HOOD CREEK WTP CAKE x D!� 20/ice (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be Applied in 2015 ANNUAL LAND APPLICATION FIELD SUMMARY FORM FACILITY NAME: BRUNSWICK COUNTY, NC PREDOMINANT SOIL SERIES: KRUEB OWNER: ORTON PLANTATION HOLDINGS PERMIT #: NC-BR-X20 ANNUAL DRY TONS APPLIED: 207.73 SITE #: NC BR OOX20 FIELD# : BR OOX20 0100 OPERATOR: DILLON EPP CATION EXCHANGE CAPACITY (NON-503): RESIDUAL SOURCE(S):* See list at bottom of report ACRES UTILIZED: 15.00 ACRES PERMITTED: 15.00 Page Lune Applied *** Date Lbs/Ac DATE or allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Dry Tons per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppm) Crop MONTH Total Per Acre Solids 7/1/14 21.15 (W) 1.410 13.97 0.197 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.0p 1,150.00 p 2.00 p 3 881 I CAUCASION/OLD WORLD BLUESTE 7/1/14 21.84 (W) 1.456 13.97 0.203 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.0p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/1/14 22.45 (W) 1.497 13.97 0.209 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.0p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/1/14 45.17 (W) 3.011 13.97 0.421 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.0p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/1/14 53.04 (W) 3.536 13.97 0.494 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.0 p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/2/14 21.53 (W) 1.435 13.97 0.201 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.0p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/2/14 23.06 (W) 1.537 13.97 0.215 BRCHCWI DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/2/14 68.12 (W) 4.541 13.97 0.634 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/2/14 82.66 (W) 5.511 13.97 0.770 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/3/14 21.49 (W) 1.433 13.97 0.200 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/3/14 22.29 (W) 1.486 13.97 0.208 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/3/14 22.43 (W) 1.495 13.97 0.209 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O�p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/3/14 22.58 (W) 1.505 13.97 0.210 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/3/14 41.55 (W) 2.770 13.97 0.387 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/3/14 42.11 (W) 2.807 13.97 0.392 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/3/14 43.15 (W) 2.877 13.97 0.402 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/3/14 62.10 (W) 4.140 13.97 0.578 BRCHCWI DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/3/14 86.05 (W) 5.737 13.97 0.801 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/7/14 19.83 (W) 1.322 13.97 0.185 BRCHCWI DRY 0-<1/2" SUR 0.5 0.40 9,160.O,p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/7/14 20.42 (W) 1.361 13.97 0.190 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/7/14 20.53 (W) 1.369 13.97 0.191 BRCHCWI DRY 0-<1/2" SUR 0.5 0.40 9,160.O p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/7/14 61.83 (W) 4.122 13.97 0.576 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/7/14 84.38 (W) 5.625 13.97 0.786 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/7/14 102.90 (W) 6.860 13.97 0.958 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40- 9,160.O p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/8/14 21.29 (W) 1.419 13.97 0.198 BRCHCWI DRY 0-<1/2" SUR 0.5 0.40 9,160,O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/8/14 21.78 (W) 1.452 13.97 0.203 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/8/14 81.00 (W) 5.400 13.97 0.754 BRCHCWF DRY 0-<l/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/11/14 20.33 (W) 1.355 13.97 0.189 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/11/14 20.95 (W) 1.397 13.97 0.195 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/11/14 61.65 (W) 4.110 13.97 0.574 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/11/14 62.01 (W) 4.134 13.97 0.578 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/11/14 82.24 (W) 5.483 13.97 0.766 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.Op 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 7/11/14 83.06 (W) 5,537 13.97 0.774 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.Op 1,150.00 p 2.00 p 3781 CAUCASION/OLD WORLD BLUESTE Jul-14 1 1,486.97 (W) 1 99.130 FACILITY NAME: BRUNSWICK COUNTY, NC OWNER: ORTON PLANTATION HOLDINGS SITE #: NC BR OOX20 FIELD# : BR OOX20 0100 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: KRUEB PERMIT #: NC-BR-X20 ANNUAL DRY TONS APPLIED: 207.73 OPERATOR: DILLON EPP CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 15.00 ACRES PERMITTED: 15.00 Page Lune Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Acre Solids Total Wet Tons/Ac: 99.13 As . Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 0.554 0.055 0.997 1.136 0.416 0.011 0.138 0.471 0.138 3.213 246.51 105 Cumulative Ibs/acre 0.554 0.055 0.997 1.136 0.416 0.011 0.138 0.471 0.138 3.213 ' Permit PAN Limit (Ibs/acre) 1st Crop/2nd Crop � FD Cumulative Pollutant LoadingRate Limit lbs/acre ( ) 36.6 34.8 :. 1339.0 267.9 15.0 `:." 375.0 89.0 2500.0 BRCHCWPC = BRUNSWICK COUNTY, NC HOOD CREEK WTP CAKE X © l� (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 s Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation **'k See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 FACILITY NAME: BRUNSWICK COUNTY, NC OWNER: ORTON PLANTATION HOLDINGS SITE #: NC BR OOX20 FIELD# : BR OOX20 0101 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: KREUB PERMIT #: NC-BR-X20 ANNUAL DRY TONS APPLIED: 200.02 OPERATOR: DILLON EPP CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 10.00 ACRES PERMITTED: 10.00 Page Lune Applied *** Date Lbs/Ac DATE or allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Dry Tons Per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppm) Crop MONTH Total Per Acre Solids 9/1/14 20.20 (W) 2.020 13.97 0.282 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.0 p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/1/14 22.02 (W) 2.202 13.97 0.308 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.0 p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/1/14 37.19 (W) 3.719 13.97 0.520 BRCHCWF DRY 0-<I/2" SUR 0.5 0.40 9,160.0p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/1/14 37.65 (W) 3.765 13.97 0.526 BRCHCWF DRY 0-<I/2" SUR 0.5 0.40 9,160.0p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/1/14 40.17 (W) 4.017 13.97 0.561 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.0 p 1,150.00 p 2.00 p 3781 Ij CAUCASION/OLD WORLD BLUESTE 9/1/14 41.69 (W) 4.169 13.97 0.582 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.0p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/1/14 41.96 (W) 4.196 13.97 0.586 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/1/14 43.04 (W) 4.304 13.97 0.601 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/1/14 61.31 (W) 6.131 13.97 0.857 BRCHCWF DRY 0-<I/2" SUR 0.5 0.40 9,160.O p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/3/14 19.65 (W) 1.965 13.97 0.275 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.Gp 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/3/14 20.12 (W) 2.012 13.97 0.281 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/3/14 20.26 (W) 2.026 13.97 0.283 BRCHCWF DRY 0-<I/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/3/14 21.87 (W) 2.187 13.97 0.306 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.0,p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/3/14 37.79 (W) 3.779 13.97 0.528 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O p 1,150.00 p 2.00 p 3781 CAUCASION/OLD WORLD BLUESTE 9/3/14 42.19 (W) 4.219 13.97 0.589 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O p 1,150.00 p 2.00 p 3781 CAUCASION/OLD WORLD BLUESTE 9/3/14 42.20 (W) 4.220 13.97 0.590 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/3/14 62.26 (W) 6.226 13.97 0.870 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/3/14 62.67 (W) 6.267 13.97 0.875 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O.p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/3/14 81.24 (W) 8.124 13.97 1.135 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/23/14 20.13 (W) 2.013 13.97 0.281 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O,p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/23/14 42.06 (W) 4.206 13.97 0.588 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.Op 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/23/14 42.09 (W) 4.209 13.97 0.588 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.Op 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/23/14 64.08 (W) 6.408 13.97 0.895 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/23/14 83.53 (W) 8.353 13.97 1.167 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/23/14 85.31 (W) 8.531 13.97 1.192 BRCHCWF DRY 0-<I/2" SUR 0.5 0.40 9,160.O,p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/23/14 86.32 (W) 8.632 13.97 1.206 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/29/14 20.65 (W) 2.065 13.97 0.288 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/29/14 41.59 (W) 4.159 13.97 0.581 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/29/14 41.88 (W) 4.188 13.97 0.585 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.Op 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/29/14 42.70 (W) 4.270 13.97 0.597 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.Op 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/29/14 42.82 (W) 4.282 13.97 0.598 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O p 1,150.00 p 2.00 p 3781 I CAUCASION/OLD WORLD BLUESTE 9/29/14 63.16 (W) 6.316 1397 0.882 BRCHCWF DRY 0-<1/2" SUR 0.5 0.40 9,160.O-p 1,150.00 p 2.00 p 3781 CAUCASION/OLD WORLD BLUESTE Sep-14 1 1,431.80 (W)l 143.180 ANNUAL LAND APPLICATION FIELD SUMMARY FORM FACILITY NAME: BRUNSWICK COUNTY, NC PREDOMINANT SOIL SERIES: KREUB OWNER: ORTON PLANTATION HOLDINGS PERMIT #: NC-BR-X20 ANNUAL DRY TONS APPLIED: 200.02 SITE #: NCBROOX20 FIELD#: BROOX20 0101 OPERATOR: DILLON EPP CATION EXCHANGE CAPACITY (NON-503): RESIDUAL SOURCE(S):* See list at bottom of report ACRES UTILIZED: 10.00 ACRES PERMITTED: 10.00 Page: 2 Lime Applied *** Date Lbs/Ac 3allons (G) or Cubic Yards (CY) Dry Site Inches Appli-_ Vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Acre Solids Total Wet Tons/Ac: 143.18 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 151 0.800 0.080 1.440 1.640 0.600 0.016 0.200 0.680 0.200 4.641 356.04 Cumulative lbs/acre 0.800 0.080 1.440 1.640 0.600 0.016 0.200 0.680 0.200 1 4.641T' Permit PAN Limit (lbstacre) I st Crop/2nd Crop 159 . ... . ...... Fl) Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 BRCHCWPC = BRUNSWICK COUNTY, NC HOOD CREEK WTP CAKE X A4�0(__ (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A= Not Applicable NR =Not Reported or Not Required % = percent p = pp- or -g/,<g Volatilization Rate: Surface 0.5, Injectiorulticorporation 1.0 Application Method: SUR-Surface, INJ -Injection, SURIN -Incorporation See Site pH &Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 ANNUAL LAND APPLICATION FIELD SUMMARY FORM FACILITY NAME: BRUNSWICK COUNTY, NC PREDOMINANT SOIL SERIES: BAYMEADE FINE SAND OWNER: ORTON PLANTATION PERMIT #: NC-BR-X20 ANNUAL DRY TONS APPLIED: 27.57 SITE #: NC BR OOX20 FIELD# : BR OOX20 0102 OPERATOR: DILLON EPP CATION EXCHANGE CAPACITY (NON-503): RESIDUAL SOURCE(S):* See list at bottom of report ACRES UTILIZED: 6.50 ACRES PERMITTED: 6.50 Page Lime Applied *** Date Lbs/Ac DATE or allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Dry Tons Per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppm) Crop MONTH Total Per Acre Solids 12/1/14 61.55 (W) 9.469 13.26 1.256 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 7,470.0 p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 12/15/14 21.09 (W) 3.245 13.26 0.430 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 7,470.0 p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 12/15/14 41.06 (W) 6.317 13.26 0.838 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 7,470.0 p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 12/15/14 41.45 (W) 6.377 13.26 0.846 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 7,470.0 p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 12/29/14 20.98 (W) 3.228 13.26 0.428 BRCHCWF MOIST 0-<1/2" SUR 0.5 0.40 7,470.0 p 1,510.00 p 2.00 p 3141 I CAUCASION/OLD WORLD BLUESTE 12/29/14 21.75 (W) 3.346 13.26 0.444 BRCHCWF MOIST 0-<I/2" SUR 0.5 0.40 7,470.0 p 1,510.00 p. 2.00 p .3141 CAUCASION/OLD WORLD BLUESTE Dec-14 1 207.88 (W) 31.982 Total Wet Tons/Ac: 31.98 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 0.102 0.017 0.339 0.339 0.102 0.003 0.042 0.136 0.042 0.831 61.66 27 Cumulative Ibs/acre 0.102 0.017 0.339 0.339 0.102 0.003 0.042 0.136 0.042 0.831 z Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop ' 192 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 BRCHCWPC = BRUNSWICK COUNTY, NC HOOD CREEK WTP CAKE X JA W/, lt� W t (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR= Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, hijection/Incorporation 1.0 * Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 L9P.�FVIROi11+i PhJTrS L'T�CHtd6 L�+~1cShd� 'suxammlr Analyff"I.Lo60'a#af els February 14, 2014 Edward Stephens Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: (336) 998-7150 FAX: (336) 998-8450 RE: Brunswick Water Plant Dear Edward Stephens: Summit Environmental Technologies, Inc. 3310 Win St. Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: huy.-Iliviviv.settek.com Order No.: 14020242 Summit Environmental Technologies, hlc. received 1 sample(s) on 2/5/2014 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, Dr. Mo Osman Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 A2LA 0724.01, Alabama 41600, Arkansas 88-0735, California 07256CA, Colorado, Connecticut PH-0105, Delaware, Florida NELAC E87688, Georgia E87688 and 943, Idaho 01100923, Illinois 200061 and Reg.5, Indiana C-OH-13, Kansas E-10347, Kentucky (underground Storage Tank) 3, Kentucky 90146, Louisiana 04061 and LA12004, Maine 2012015, Maryland 339, Massachusetts M-OPH923, Minnesota 409711, Montana CERT0099, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705'and 631, Olio 4170, Ohio VAP CL0052, Oklahoma 9940, Oregon 0112O0001, Pennsylvania 68-01335, Rhode Island LA000317, South Carolina 92016001, Tennessee TN04018, Texas T104704466-I 1-5, Region 8 8TMS- L, USDA/APHIS P330-11-00244, Utah OH009232011-1, Vermont VT-87688, Virginia 00440 and 1581, Washington C891, West Virginia 248 and 9957C and E87688, Wisconsin 399013010 Summit EnWronmental Technologies, Inc. Workorder M's ^` 10 M k 3310 Win St. 1�FVIRti#I��TEiaitlL,1'BfdL3,Ga�,'?tG. Cuyahoga Falls, Ohio44223 Sample Summary AiTalyfica3 TEL: (330) 253-8211 FAX: (330) 253-4489 WO#• 14020242 Web site: htto://www.settek.com 14-Feb-14 CLIENT: Synagro Project: Brunswick Water Plant Lab SampleID Client Sample ID Tag No Date Collected Date Received Matrix 14020242-001 Brunswick WTP 1/27/2014 11:00:00 AM 2/5/2014 11:00:00 AM Sludge S ....... it Envi,vn.e,,Il Technologies, Inc. C 3310 Win St. ase Narrative Es'; . iftc. Cuyahoga Falls, Ohio 44223 WO#: 14020242 TEL: (330) 253-8211 FAX.- (330) 253-4489 Date: 2/14/2014 Website: hUP.-1Avwiv.seUekcom CLIENT: Synagro Project: Brunswick Water Plant This report in its entirety consists of the documents listed below. All documents contain the Summit Environmental Technologies, Inc. Work Order Number assigned to this report. Paginated Report including: Cover Letter, Case Narrative, Analytical Results, Applicable Quality Control Summary Reports and copies of the Chain of Custody Documents supplied with this sample set. Concentrations reported with a J flag in the Qual field are values below the Limit of Quantitation (LOQ) but greater than the established Limit of Detection (LOD). There is greater uncertainty associated with these results and data should be considered as estimated. - Method numbers, unless specified as SM (Standard Methods) or ASTM, are EPA methods. Estimated uncertainty values are available upon request. Any comments or problems with the analytical events associated with this report are noted below. Original Summit Environmental Technologies, Inc. 3310 Win St. WO#: 14020242 :fVIH[SP96,1liiL'4�3tLb'd;.iP1_, Cuyahoga Falls, Ohio44223 Date Reported: 2/14/2014 e' Ltn3rtrfiic&l d Ra'pra tf TEL: (330) 253-8211 FAX: (330) 253-4489 Company: Synagro Website: htto://www.settek.com Address: 284 Boger Rd. Mocksville NC 27028 Received: 2/5/2014 Project#: Brunswick Water TCLP Metals Analysis (6010) Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Brunswick WTP 001 . 1/27/2014 TCLP Arsenic(As) 0.50 ND mg/L Sludge EPA 6010 C 1 5.0 2/10/2014 WK Brunswick WTP 001 1/27/2014 TCLP Barium(Ba) 5.0 ND mg/L Sludge EPA 6010 C 1 100 2/10/2014 'WK Brunswick WTP 001 1/27/2014 TCLP Cadmium(Cd) 0.10 ND mg/L Sludge EPA 6010 C 1 1.0 2/10/2014 WK Brunswick WTP 001 1/27/2014 TCLP Chromium(Cr) 0.20 ND mg/L Sludge EPA 6010 C 1 5.0 2/10/2014 WK Brunswick WTP 001 1/27/2014 TCLP Lead(Pb) 0.50 ND mg/L Sludge EPA 6010 C 1 5.0 2/10/2014 WK Brunswick WTP 001 1/27/2014 TCLP Selenium(Se) 0.50 ND mg/L Sludge EPA 6010 C 1 1.0 2/10/2014 ' WK Brunswick WTP 001 1/27/2014 TCLP Silver(Ag) 0.50 ND mg/L Sludge EPA 6010 C 1 5.0 2/10/2014 WK TCLP Mercury Analysis (1311/7470) Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Brunswick WTP 001 1/27/2014 TCLP Mercury 0.0020 ND mg/L Sludge EPA 7470 A 1 0.20 2/11/2014 ALJ •a SVOC SW-846: 8081-TCLP Pesticides Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Brunswick WTP 001 1/27/2014 Chlordane, total 0.010 ND mg/L Sludge EPA 8081 B 1 0.030 2/10/2014 JBN Brunswick WTP 001 1/27/2014 Toxaphene. 0.10 ND mg/L Sludge EPA 8081 B 1 0.50 2/10/2014 JBN Brunswick WTP 001 1/27/2014 Endrin 0.0020 ND mg/L Sludge EPA 8081 B 1 0.020 2/10/2014 JBN Brunswick WTP 001 1/27/2014 gamma-BHC 0.0020 ND mg/L Sludge EPA 8081 B 1 0.40 2/10/2014 JBN Brunswick WTP 001 1/27/2014 Heptachlor 0.0020 ND mg/L Sludge EPA 8081 B 1 0.0080 2/10/2014 JBN Brunswick WTP 001 1/27/2014 Heptachlor epoxide 0.0020 ND mg/L Sludge EPA 8081 B 1 0.0080 2/10/2014 JBN Brunswick WTP 001 1/27/2014 Methoxychlor 0.0020 ND mg/L Sludge EPA 8081 B 1 10 2/10/2014 JBN VOC by GC/MS (8260)-TCLP Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Brunswick WTP 001 1/27/2014 1,1-Dichloroethene 0.10 ND mg/L Sludge EPA 8260 B 1 0.70 2/10/2014 MES Brunswick WTP 001 1/27/2014 1,2-Dichloroethane 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 2/10/2014 MES Brunswick WTP 001 1/27/2014 Benzene 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 2/10/2014 MES Brunswick WTP 001 1/27/2014 Carbon tetrachloride 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 2/10/2014 MES Brunswick WTP 001 1/27/2014 Chlorobenzene 0.10 ND mg/L Sludge EPA 8260 B 1 100 2/10/2014 MES Brunswick WTP 001 1/27/2014 Chloroform 0.10 ND mg/L Sludge EPA 8260 B 1 6.0 2/10/2014 MES Brunswick WTP 001 1/27/2014 Tetrachloroethene 0.10 ND mg/L Sludge EPA 8260 B 1 0.70 2/10/2014 MES Brunswick WTP 001 1/27/2014 Trichloroethene 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 2/10/2014 MES Brunswick WTP 001 1/27/2014 Vinyl chloride 0.20 ND mg/L Sludge EPA 8260 B 1 0.20 2/10/2014 MES Brunswick WTP 001 1/27/2014 MEK 2.0 ND mg/L Sludge EPA 8260 B 1 200 2/10/2014 MES �, - Summit Environmental Technologies, Inc. WO#: 14020242 l� �1 €9 3310 Win St. �A64PIfi4tli'elf;tFJT',1L"E1=�3'dC',�L�'�3r�:,7�1�, C ahogaFalls,Ohio44223 Date Reported: 2/14/2014 tine%;tict�l't,'vYA7e7r/e TEL: (330) 253-8211 FAX.- (330) 253-4489 Company: Synagro Website: htto://wiviv.settek.com Address: 284 Boger Rd. Mocksville NC 27028 Received: 2/5/2014 Project#: Brunswick Water SVOC 8270 TCLP BNA List Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Brunswick WTP 001 1/27/2014 1,4-Dichlorobenzene 0.10 ND mg/L Sludge EPA 8270 C 1 7.5 2/10/2014 AKE Brunswick WTP 001 1/27/2014 2,4,5-Trichlorophenol 0.25 ND mg/L Sludge , EPA 8270 C 1 400 2/10/2014 AKE Brunswick WTP 001 1/27/2014 2,4,6-Trichlorophenol 0.25 ND mg/L Sludge EPA 8270 C 1 2.0 2/10/2014 AKE Brunswick WTP 001 1/27/2014 2,4-Dinitrotoluene 0.10 ND mg/L Sludge EPA 8270 C 1 0.13 2/10/2014 AKE Brunswick WTP 001 1/27/2014 Cresols, Total 5.0 ND mg/L Sludge EPA 8270 C 1 200 2/10/2014 AKE Brunswick WTP 001 1/27/2014 Hexachloro-1,3- 0.10 ND mg/L Sludge EPA 8270 C 1 0.50 2/10/2014 AKE butadiene Brunswick WTP 001 1/27/2014 Hexachlorobenzene 0.10 ND mg/L Sludge EPA 8270 C 1 0.13 2/10/2014 AKE Brunswick WTP 001 1/27/2014 Hexachloroethane 0.10 ND mg/L Sludge EPA 8270 C 1 3.0 2/10/2014 AKE Brunswick WTP 001 1/27/2014 Nitrobenzene 0.10 ND mg/L Sludge EPA 8270 C 1 2.0 2/10/2014 AKE Brunswick WTP 001 1/27/2014 Pentachlorophenol 0.25 ND mg/L Sludge EPA 8270 C 1 100 2/10/2014 AKE Brunswick WTP 001 1/27/2014 Pyridine 0.25 ND mg/L Sludge EPA 8270 C 1 5.0 2/10/2014 AKE SVOC SW-846: 8321 Herbicides-TCLP Client ID# Lab ID# Collected Analyte Rep Lmt Result Units - Matrix Method DF RegLvl Run Analyst Brunswick WTP 001 1/27/2014 2,4-D 5.0 ND mg/L Sludge EPA 8321 A 1 10 2/12/2014 AMZ Brunswick WTP 001 1/27/2014 2,4,5-TP 0.50 ND mg/L Sludge EPA 8321 A 1 1.0 2/12/2014 AMZ Summit Environmental Technologies, Inc. g WO#: 14020242 3310 Win St. F OG94{Ift4hlPetEh'P L �£ 3 C9L LCsG.i;5p3p q Cuyahoga Falls, Ohio 44223 Date Reported: 2/14/2014 natltra�a�l t>�4ir�r�1 rtl TEL (330) 253-8211 FAX.- (330) 253-4489 Company: Synagro Website: hna://www.settek.coni Address: 284 Boger Rd. Mocksville NC 27028 Received: 2/5/2014 Project#: Brunswick Water Client ID# Lab ID# Collected Analyte Result Units Matrix Method DF RL Run Analyst Brunswick WTP 001 1/27/2014 Flashpoint (140°F) >140 °F Sludge EPA 1010 1 2/7/2014 TJR Brunswick WTP 001 1/27/2014 Cyanide, Reactive Brunswick WTP 001 1/27/2014 pH Brunswick WTP 001 1/27/2014 Sulfide, Reactive ND ppm Sludge EPA 9014 1 0.50 2/7/2014 TIR 6.8 s.u. Sludge EPA 9045 D 1 2/6/2014 AYS ND ppm Sludge EPA 9034 1 25 2/7/2014 TIR of Cul�to'ft. JnAIYSISRetjui��WIQW" 3310, Wirt Street For Summit EnvironmentalI Technologies I Inc. use, OWY 'Cuyahoga Fa%,- Ohio 44223 Tol. -330,25,3.'kl I i,kx: 330.25 .4489 :page —of—,, FSET,Na 'Com � an ame (Plea Print) Project Name= rameters C( Troj;R -Address 44d Client Phone Nff Report to, 0- `AIN Client Fox No.- 13 PP# A Client Ernail cl anh CoIntact-. erson, Sampled by ChecR if Ohio El !C6 -FCollected -T - - A �Sqihpleldenflficafiqn CoJJCdtdColleded 0113 .1 1 4 -- — I 'Notes/Comments: h Requemedpy., I ANNUAL, PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Brunswick County WTP WWTP Name: Hood Creek WTP WQ Permit Number: WQ0035207 NPDES Number: NCO0575333 Monitoring Period: From 01/01/14 To 03/31/14 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2/13 (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion TV .. ..1:.... L.I.. 4-...-f — -A !f'l...o A — 01... M n nln4n +hn f lln nn mnnU—i— rlo+a- Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dences Analysis Fecal 2x10 to the Oh MPN MPN/g Coliform power per gram of total solids CFU/g CFU 1000 MPN per gram of <11 11 <12 MPN/g 0 4 Grab SM 9221 C total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: Option/Alt. l Option/Alt. 2 Option/Alt. 3 'Option/Alt. 4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed N/A CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been Vagt. i am aware that there a;e�significant penalties for false certification including fine and imprisonment." Preparer a fi an Title e r print) 2 � Signature of Preparer* Da Land Applier Name and Title (if applicable) (type or print) Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Environmental Chemists, Inc. envirochem 6602 Windmill Way • Wilmington, NC 28405 (910) 392-0223 (Lab) • (910) 392-4424 (Fax) sM 710 Bowsertown Road • Manteo, NC 27954 (252) 473-5702 ANALYTICAL & CONSULTING CHEMISTS NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729 Synagro Date of Report: Feb 07, 2014 284 Boger Road Customer PO P. Mocksville NC 27028 Report M 2014-01076 Attention: E. Stephens Report to: E. Stephens Project ID. - Lab ID Sample ID: Collect Date/Time Matrix Sampled by 14-02694 Site: Brunswick 1 1/27/2014 8:50 AM Solid/Sludge E. Stephens Test Method Results . Date Analyzed Total Solids (%) - SM 2540 B 19.8 % 01/28/2014 Fecal Density SM 9221C E MPN• 24 hr 503 11 MPN/g 01/28/2014 Lab ID Sample ID: Collect Date/Time Matrix Sampled by 14-02695 Site: Brunswick 2 1/27/2014 8:55 AM Solid/Sludge E. Stephens Test Method Results Date Analyzed Total Solids (%) SM 2540 a 19.2 % 01/28/2014 Fecal Density SM92210EMPN 24hr503 <11 MPN/g 01/28/2014 Lab ID Sample ID: Collect Date/Time Matrix Sampled by 14-02696 Site: Brunswick 3 1/27/2014 8:56 AM Solid/Sludge E. Stephens Test Method Results Date Analyzed Total Solids (%) SM 2540 B 17.4 % 01/28/2014 Fecal Density SM92210EMPN 24hr503 <12MPN/g 01/28/2014 Comment: Results reported on a dry weight basis. Reviewed by:. ����l p f l �c e�- Report#:: 2014-01076 Page 1 of 1 ENVIRONMENTA .-- CHEMISTS, INC OFFICE:9101392.0 23FA).'._ J 2-"24 Analytical &Consulting Chemists NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 Info@environmentaichemists.com COLLECTION AND CHAIN OF CUSTODY CLIENT: r 4Yq } PROJECT NAME: &VOWICK W REPORT NO: - d (o�-� ADDRESS: ;Lq Kze d CONTACT NAME: gaw �J-C a �gws PO NO: i/ o Svtrl lUC, REPORT TO: 5 >�ar0.0 PHONEII=Ax: 3Y 3 -�U COPY TO: email: Sampled Bv: Ail SAMPLE TYPE: I = Influent, E = Effluent, W = Well, ST = Stream, SO = Soil, SL = Sludge, Other: Sample Identification Collection R w' N C `o 2 ;, 3 c a V V o °' u E o � in � g z PRESERVATION ANALYSIS REQUESTED Date Time Temp z z � o Q a o_ w 6r dq G 19 `Z c1 �- 1 G C P G G. C P G G C P G G C P G G C P G G C P G G C P G G Tran fer Relinquished By: Received By: DatelTime J �Date/Time r 2. Temperature when Received: Accepted: Delivered By: Received By:, le : 1—L, , i TURNAROUND: ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Brunswick County WTP WQ Permit Number: WQ0035207 WWTP Name: Hood Creek WTP NPDES Number: NCO0575333 Monitoring Period: From 04/01/14 To 06/30/14 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2/13 (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion rf annli—hln fn al4arna4iva nnrfnrmad !(lace A nr Clace Rl rmmnlafa tha fallnwina mnnitnrina data - Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units deuces Analysis Fecal 2x10 to the 61 MPN MPN/g Coliform power per gram of total solids CFU/g CFU 1000 MPN per gram of 11 13 15 MPN/g 0 4 Grab SM 9221 C total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: 0 tion/Alt. 1 Option/Alt.2 Option/Alt.3 Option/Alt.4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed N/A CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. am a are that there are si ifi t p alties for false certification including fine and imprisonment." or print) ate Land Applier.Name and Title (if applicable) (type or print) Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 5039(r) and 15A NCAC 2T.1102 (26) F07 . "41 7 1 Environmental Chemists, Inc. ,. 6602 Windmill Way o Wilmington, NC 28405 (910)392-0223(Lab) 9 (910)392-4424(Fax) ` SM 710 Bowsertown Road . Manteo, NC 27954 (252)473-5702 ANALYTICAL & CONSULTING CHEMISTS NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729 Synagro Date of Report: Apr 21, 2014 284 Boger Road Customer PO #: Mocksville NC 27028 Report #: 2014-04361 Attention: E. Stephens Report to: E. Stephens Project ID: Brunswick Co. Water Plant Lab ID Sample ID: Collect Date/Time Matrix Sampled by 14-10465 Site: BWTP-1 4/14/2014 1:05 PM Solid/Sludge Edward Stephens Test Method Results Date Analyzed Total Solids (%) SM 2540 B 21.3 % 04/15/2014 Fecal Density SM 9221C E MPN 24 hr 503 15 M PN/g 04A 5/2014 Lab ID Sample ID: Collect Date/Time Matrix Sampled by 14-10466 Site: BWTP-2 4/14/2014 1:06 PM Solid/Sludge Edward Stephens Test Method Results Date Analyzed Total Solids (%} SM 2540 B 22.2 % 04/15/2014 Fecal Density SM 9221C E MPN 24 hr503 11 MPN/g 04/15/2014 Lab ID Sample ID: Collect Date/Time Matrix Sampled by 14-10467 Site: BWTP-3 4/14/2014 1:07 PM Solid/Sludge Edward Stephens Test Method Results Date Analyzed Total Solids (%) SM 2540 B 21.8 % 04/15/2014 Fecal Density SM 9221C E MPN 24 hn503 14 MPN/g 04/15/2014 Comment: Results reported on a dry weight basis. Reviewed by: / . /ze'k - Report M.: 2014-04361 Page 1 of 1 ENVIR0NMENTk__.. CHEMISTS, INC OFFICE- 910392.0 23FA 7,.:-3924424 Analytical & Consulting Chemists NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 info@environmentatchemists.com COLLECTION AND CHAIN OF CUSTODY CLIENT: PROJECT NAME: rui sw)(,K Tr REPORT NO: ADDRESS: if Aieyok J CONTACT NAME: PO NO: %.,1-06 ' V1 C �% L REPORT TO: L S�'�e I,.�+� p PHONE/FAX: 06 COPY TO: M S1 I`,, a. QV\- email: Samnlprl Rv: n ik, ,4 SAMPLE TYPE: I = Influent. E = Effluent. W = Well. ST = Stream, SO = Soil. SL = Slud-ne, Other: + Sample Identification Collection E a �~ c c �L° o " d , , A o �, o �+ a Lu m gx D PRESERVATION ANALYSIS REQUESTED Date Time Temp z z "o c o x o W o t./ fir o SL G G w C P G G C P G G C P G G C P z G G C P G G C P G G C P G G Transfer Relinquished. By: Date/Time Received By: Dateffime 2. V - Temperature when Received: Accepted: / Kejected: Kesampie Kequestea: Delivered By: Received By:' 2, 6(t � r�� Date: LI -4-«( Time; .l SDc� Comments. TURNAROUND:' Sfv �e— ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Brunswick County WTP WWTP Name: Hood Creek WTP Monitoring Period: From ' 07/01/14 To 09/30/14 WQ Permit Number: WQ0035207 NPDES Number: NCO0575333 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 4/D (No Prior Test) . Alt. 2/13 (Alk Treatment) Alt. 5/Process to Further Reduce Pathogens Alt. 3/C (Prior Testing) Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Anaerobic Digestion Composting Aerobic Digestion If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum _ Units dences Analysis Fecal 2x10 to the 6` MPN MPN/g Coliform power per gram of total solids CFU CFU/g 1000 MPN per gram of 24 MPN/g 0 4 Grab SM 9221C total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: Option/Alt. 1 Option/Mt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed N/A CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X_ reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/f5A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware hat ere are significant penalties for false certification including fine and imprisonment." a m a Titl pe or print) ? Land Applier Name and Title (if applicable) (type or print) Signature of Preparer* at " Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Environmental Chemists, Inc. env fl 6602 Windmill Wi Way a lmington, NC 29405 (910) 392-0223 (Lab) * (910) 392-4424 (Fax) su+ 710 Bowsertown Road • Manteo, NC 27954 (252)473-5702 ANALYTICAL & CONSULTING CHEMISTS NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729 Synagro Date of Report: Jul 31, 2014 284 Boger Road Customer PO #: Mocksville NC 27028 Customer ID: 13030023 Attention: Marshall Puryear, CCA Report #: 2014-08684 Project ID: Brunswick Co. Water Plant Lab ID Sample ID: Collect Date/Time Matrix Sampled by 14-21486 Site: Brunswick WTP 7/22/2014 9:10 AM Solid/Sludge Froncy Dail Test Method Results Date Analyzed Total Solids (%) sM 2540 s 12.8 % 07/23/2014 Fecal Density SM 9221C E MPN 24 hr 503 24 MPN/g 07/23/2014 Comment: Results reported on a dry weight basis. Reviewed by: WAI'091), 1 Report #:: 2014-08684 Page i of 1 6602 WindilWay ENVIRONMENTAL CHEMISTS, INC OFFICE:910I392-0 23FAX _._ 24424 info@environmerrtalchemists,com Analytical &Consulting Chemists NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 COLLECTION AND CHAIN OF CUSTODY CLIENT: lel- ,17 r D PROJECT NAME: REPORT NO: ADDRESS: CONTACTNAME: PO NO: REPORT TO: PHONEIFAX: COPY TO: email: M fLj Y-xf S vn C< nr� _ n—.1 CF - Clnrinu hfhAr_ Sampled By: r-ionCW UR I I ,� eo SAMPLE :9 E W V TYPE: o a V — i = inrluen; d c E U G = w m 3 Z ztriuenE, PRESERVATION YY YYCu, %J I — W— .., — - --••a -- - ANALYSIS REQUESTED Sample Identification Collection o z It ° x z o 6 o Date Time Temp P Ct"nslNIC-Ic- C �10 P .� ) C G G P C G G C P G G Ci P G C G P G G C P G C G P G C G P G C G P G I G Transfer. Relinquished By: Date/Time Received By: DatelTime 1. 2. l!T/Iemperature w N fnfivornri R.,• n Rec v Accepted: R ected• Resample Re uest d: �% • , —cam Rpcpivpd E r� 7 Date: ,i Time:, omments:' �� �_ TURNAROUND: ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Brunswick County WTP WQ Permit Number: WQ0035207 WWTP Name: Hood Creek WTP Monitoring Period: From 10/01/14 To 12/31/14 NPDES Number: NCO0575333 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable .to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units deuces Analysis Fecal 2x10to the 6th MPN MPN/g Coliform power per gram of total solids CFU CFU/g 1000 MPN per gram of 23 MPN/g 0 4 GRAB SM 9221 C total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: 0 tion/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt.4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed N/A CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have e et. :Iam iwA lat there are significant penalties for false certification including fine and imprisonment." Pre ar n itle (tyy or print) Land Applier Name and Title (if applicable) (type or print) Signature of Preparer* D e Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) - sM ANALYTICAL & CONSULTING CHEMISTS Synagro . 284 Boger Road Mocksville NC 27028 Attention: Marshall Puryear, CCA Lab ID Sample ID: 14-29832 Site: Brunswick WTP Test Total Solids (%) Environmental Chemists, Inc. 6602 Wuidmill Way - Wilmington, NC 28405 (910) 392-0223 (Lab) - (910) 392-4424 (Fax) 710 Bomertown Road - Manteo,-NC 27954 (252) 473-5702 INCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729 Date of Report: Oct 14, 2014 Customer PO #: Customer ID: 13030023 Report #: 2014-12152 Project ID: Brunswick Co. Water Plant Collect Date/Time Matrix Sampled by 10/1/2014 11:30 AM . Solid/Sludge C. Brown Method Results Date Analyzed SM 2540 B 13.3 % 10106/2014 Fecal Density SM 9221C E MPN 24 hr503 23 MPN/g 10/02/2014 Comment: Results reported on a dry weight basis. Reviewed Report #:: 2014-12152 Page 1 of 1 6602 Wind PENVIRQNMENTA� -CHEMISTS, INC OFFICE;91�01392-0 23FAX sio-a 2-4424 Analytical & Consulting Chemists NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 info@environmentalchemists.com COLLECTION AND CHAIN OF CUSTODY CLIENT: .. u �k2, t''U� PROJECT NAME: ✓ vk5wiLk- W REPORT NO: ADDRESS: 2- c7 nr CA CONTACT NAME: ;x ; 4 L rt vti l'� , C, v'r PO NO: v t r ` iG 71P lic- ,-:2 9 ; REPORT TO: w,; ' h '•� v PHONE/FAX: COPY TO: email: Saml flsvSAMPLE TYPE: I = Influent, E = Effluent, W = Well, ST = Stream, SO = Soil, SL = Sludge, Other.' - Sample Identification Collection E w a o e .1 o 2tm m PRESERVATION ANALYSIS REQUESTED Date Time Temp W ., o M. = o W ��wcGic t f A 14 1t; D J`L" C P �3 �.tcc55£'�( f 5�i;VS ` G G C P G G C P G G C P G G C P G G C P G G C P G G C P G G C P G G C P G G Transfer J Relin wished By: Date/Time Received By: Date/Time 2. Temperature whg4 Received: Accepted: Delivered B Received rle Requested: d-I� I`'; Timer; TURNAROUND: 2014 ANNUAL OPERATIONS SUMMARY - LAND APPLICATION �RANKLIN, NC FRANKLIN, NC WTP LIQUID MONTHNEAR August 2014 YEARLY TOTAL AMOUNT UNIT 598, 500.00 G 598,500.00 G DRY TONS UNIT 133.28 D 133.28 D DRY METRIC TONS 120.87 120.87 2/17/2015 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: Facility Name: FRANKLIN, NC NPDES#: or WQ# (residual only) WWTP Name: FRANKLIN WTP Residuals Analysis Data Product Type WPL Date Sampled (grab) or 07/28/14 Date Composited Percent Solids 5.34 PARAMETERS (mg/kg dry weight) Arsenic 4 Cadmium <2 Mercury <0.4 Chromium 57 Copper 49 Lead 7 Molybdenum <5 Nickel 23 Selenium <5 Zinc 104 Total Phosphorus 995 TKN 5990 Ammonia -Nitrogen 1500 Nitrate and Nitrite <2 Laboratory A&L Eastern Laboratories Inc. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." X EPARER) Date Y DENR FORM RSSF (5/2003) Printed: Tuesday- February 17, 2015 at 14:05:52 for:2254 01 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: Facility Name: FRANKLIN, NC NPDES#: or WQ# (residual only) WWTP Name: FRANKLIN WTP Residuals Analysis Data Product Type WPL Date Sampled (grab) or 07/28/14 Date Composited Percent Solids 5.34 PARAMETERS (mg/kg dry weight) Aluminum 159000 Calcium 1500 Magnesium 2880 pH 6.75 Potassium 1460 Sodium <100 Laboratory A&L Eastern Laboratories Inc. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." X (SIGNATVJRFOF PRE NR - Data Not Reported or Data Not Required Date a- 2 7 1 5- DENR FORM RSSF-B (7/2002) Printed: Tuesday - February 17 2015 at 14:07:10 for: 2254 01 Page: 1 of 2 Report Number: 14-211-0205 A&L Eastern Laboratories, Inc. Account Number: 46622 7621 Whitepine Road Rich mond,Virginia 23237 (804)743.9401 Fax (804)2711-G4464 Submitted By: WILL HODGES viwmaleastern,conn Send To: SYNAGRO CENTRAL/TECHNICAL Project: FRANKLIN WTP MARY BREWER NC CERT#257 284 BOGER RD MOCKSVILLE , NC 27028 REPORT OF ANALYSIS Date Sampled: 7/28/2014 11:40:00 Lab Number: 56770 Date Received: 07/30/2014 00:00 Sample Id: FRANKLIN WTP Date Reported: 08/05/2014 � QUANTITATION DATUTIMIE— METH •. Total Solids * 5.34 53400 100.0 JM 07/30/2014 14:10 SM-254OG Moisture * 94.66 100.0 JM 07/30/2014 14:10 SM-2540G Total Kjeldahl Nitrogen 0.60 5990 10.0 JM 07/31/2014 09:00 SM-4500-NH3C-TKN Total Phosphorus 0.10 995 100 KM 07/31/2014 13:09 SW 6010C Total Potassium 0.15 1460 100 KM 07/31/2014 13:09 SW 6010C Total Sulfur 0.34 3380 100 KM 07/31/2014 13:09 SW 6010C Total Calcium 0.15 1500 100 KM 07/31/2014 13:09 SW 6010C Total Magnesium 0,29 2880 100 KM 07/31/2014 13:09 SW 6010C Total Sodium <0.01 <100 100 KM 07/31/2014 13:09 SW 6010C Total Iron 31300 100 KM 07/31/2014 13:09 SW 6010C Total Aluminum 159000 100 KM 07/31/2014 13:09 SW 6010C Total Manganese 589 5 KM 07/31/2014 13:09 SW 6010C Total Copper 49 5 KM 07/31/2014 13:09 SW 6010C Total Zinc 104 5 KM 07/31/2014 13:09 SW 6010C Ammonia Nitrogen 0.15 1500 10.0 JM 07/31/2014 09:00 SM-4500-NH3C Organic N 0.45 4490 10.0 07/31/2014 09:00 CALCULATION Nitrate+Nitrite-N <2.00 2.00 JM 07/31/2014 09:00 SM-450ONO3F Total Cadmium <2.0 2.0 KM 07/31/2014 13:09 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. ot�� Debbie Holt Page: 2 of 2 Report Number: 14-211-0205 Account Number: 46622 Submitted By: WILL HODGES Send To: SYNAGRO CENTRAUTECHNICAL MARY BREWER 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 56770 Sample Id: FRANKLIN WTP A&L Eastern Laboratories, Inc. 7621 1Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271.6446 www.aleastern,com Project: FRANKLIN WTP NC CERT#257 REPORT OF ANALYSIS Total Chromium 57 Total Nickel 23 Total Lead 7 Total Arsenic 4.0 Total Mercury <0.4 Total Selenium <5.0 pH (Standard Units) ' 6.75 Total Molybdenum <5 Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. Date Sampled: 7/28/2014 11:40:00 Date Received: 07/30/2014 00:00 Date Reported: 08/05/2014 5 KM 07/31/2014 13:09 SW 6010C 5 KM 07/31/2014 13:09 SW 6010C 5 KM 07/31/2014 13:09 SW 6010C 3.0 KM 07/31/2014 13:09 SW 6010C 0.4 KM 07131 /2014 09:00 S W-7471 B 5.0 KM 07/31/2014 13:09 SW 6010C 2.00 JM 07/31/2014 09:00 SW-9045D 5 KM 07/31/2014 13:09 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Debbie Holt u;AMPLINC LOG a CUSTOMER. SYNAGRO SOUTHEAST PROJECT MANAGER: A & L CUSTOMER LAB tt rSAMPLE I.D. )/+� HetlnquisheO by ampler: Relinquished by: -- T Relinquished by: SAMPLING LOCATION # At L Rick , 1 lil (IIIIIiII�Hl►1 IIII a4-2.1-0"<OS 804i30 ; �IUIIIilllllll (ii�lUllll{I�II�(�I Gr _01a SYNAGROCENTRALTECHNICAL 13.0638 N OF CUSTODY ,RD & ANALYSIS RECORD FRANKLIN WTP zxnpling procedures ion of these samples. SAMPLER SAMPLE # OF SAMPLING METHOD METHOD TYPE CONTAINERS DATE TIME PRESERVED SHIPPED Date Time Recieved by: REMARKS: -7 ,X -14! /D : �(G Date Time Recieved by. Date Time Recieved by: SPECIAL INSTRUCTIONS: L",^lzci 5C, 00-3 6 For Ak—' ___ monitoring purposes. S.'-C PO#: SAMPLE ANALYSIS REQUEST I.D. I SLt SL2 Organic NH4 N'.. NOS N N Cd ` Cr Ni Pb As Hg Se pH CaCO� a uiv. Volatile Solids MCI Cl NOZ N / L )� l� J�� / r� F+� rF�' i� i� !� !. f I I I i SL1: Total Solids (Moisture), Total Kjeldahl Nitrogen, Phosphorus, and Potassium SI-2: Basic Test SL1 plus Sulfur, Calcium, Magnesium, Sodium. Iron, Aluminum, Manganese_, Copper and Zinc White — A & L Canary — MANAGER COPY Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date Report Range Ratio 2254-01=WPL-NC FRANKLIN, NC WTP LIQUID 7/28/2014 1/1/2014-12/31/2014 0.0801 Na mg/I = (Na mg/kg x % Solids) _ 100 = (100 x 5.3400) + 100 = 5.34 Ca mg/I = (Ca mg/kg x % Solids) = 100 = (1500 x 5.3400) + 100 = 80.1 Mg mg/1 = (mg mg/kg x % Solids) = 100 = (2880 x 5.3400) _ 100 = 153.792 Na meq = Na mg/1= Molec.Wgt.Na = 5.34 _ 23 = 0.232174 Ca meq = Ca mg/I _ Molec.Wgt.Ca = 80.1 = 20 = 4.005 Mg meq = Mg mg/I Molec.Wgt.Mg = 153.792 + 12 = 12.816 SAR = Na meq _ SgrRoot[0.5 x (Ca meq + Mg meq)] = 0.232174 + SgrRoot[0.5(4.005+12.816)] = 0.0800576 Printed: 2/17/2015 Page 1 14:13 FACILITY NAME: FRANKLIN, NC OWNER: SAM GREENWOOD SITE #: NC MA OOOX2 FIELD# : MA OOOX2 0001 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: DILLARD LOAM PERMIT #: WQ0035207 ANNUAL DRY TONS APPLIED: 67.34 OPERATOR: STEVE LEDFORD CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 14.00 ACRES PERMITTED: 14.00 Page Lune Applied *** Date Lbs/Ac DATE or allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) oho Dry Tons per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppm) Crop MONTH' Total Per Acre Solids 8/26/14 63,000.00 (G) 4500.000 5.34 1.002 FWPL DRY 0-<1/2" SUR 0.5 0.40 5,990.0 p 1,500.00 p 2.00 p 2548 I FESCUE 8/27/14 239,400.00 (G) 17100.000 5.34 3.808 FWPL DRY 0-<1/2" SUR 0.5 0.40 5,990.0 p 1,500.00 p 2.00 p 2548 FESCUE Aug-14 1 302,400.00 (G) 1 21,600.000 1 Total Gallons/Ac: 21,600.00 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 25 0.038 0.019 0.548 0.471 0.067 0.004 0.048 0.221 0.048 1.000 9.57 Cumulative Ibs/acre 0.038 0.019 0.548 0.471 0.067 0.004 0.048 0.221 0.048 1.000 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 FWPL = FRANKLIN, NC WTP LIQUID . e 45 X � ?0 x/ 1 �4, C, (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 ANNUAL LAND APPLICATION FIELD SUMMARY FORM FACILITY NAME: FRANKLIN, NC PREDOMINANT SOIL SERIES: DILLSBORO LOAM OWNER: EDGAR SHOPE PERMIT #: W00035207 ANNUAL DRY TONS APPLIED: 30.86 SITE #: NC MA OOOX3 FIELD# : MA OOOX3 0001 OPERATOR: WAYNE MOSS CATION EXCHANGE CAPACITY (NON-503): RESIDUAL SOURCE(S):* See list at bottom of report ACRES UTILIZED: 7.80 ACRES PERMITTED: 7.80 Page : 1 Lime Applied *** Date Lbs/Ae DATE or MONTH allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Solids Dry Tons Per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppin) Crop Total Per Acre 8/28/14 12,600.00 (G) 1615.385 5.34 0.360 FWPL DRY 0-<1/2" SUR 0.5 0.40 5,990.0p 1,500.00 p 2.00 p 2548 FESCUE V29/14 126,000.00 (G) 16153.846 5.34 3.597 FWPL DRY 0-<1/2" SUR 0.5 0.40 5,990.0 p 1,500.00 p 2.00 p 2548 FESCUE Aug-14 1 138,600.00 (G) 17,769.231 1 Unll trial lolls/h1G: 1 /, / bY.LJ As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annuallbs/acre 20 0.032 0.016. 0.451 0.388 0.055 0.003 0.040 0.182 0.040 0.823 7.87 Cumulative lbs/acre 0.032 0.016 0.451 0.388 0.055 0.003 0.040 0.182 0.040 0.823 Permit PAN Limit (Ibs/acre) 1st Crop/2nd Crop 4°. J y .ti T 200 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 f . FWPL = FRANKLIN, NC WTP LIQUID X 41414 (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ - hijection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 FACILITY NAME: FRANKLIN, NC OWNER: EDGAR SHOPE SITE #: NC MA OOOX3 FIELD# : MA OOOX3 0002 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: DILLSBORO LOAM PERMIT #: WQ0035207 ANNUAL DRY TONS APPLIED: 35.07 OPERATOR: WAYNE MOSS CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 7.00 ACRES PERMITTED: 7.00 Page : 1 Lime Applied Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip. ' cation tili- ali- Ammonia Nitrate PAN DATE or MONTH Solids per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop Total FPer Acre 8/28/14 157,500.00 (G) 22500.000 5.34 5.010 FWPL DRY 0-<I/2" SUR 0.5 0.40 5,990.0 p 1,500.00 p 2.00 p 2548 FESCUE Aug-14 157,500.00 (G) 22,500.000 noun vanons/Ac: ZZ'nuu.uu As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annuallbs/acre 26 0.040 0.020 0.571 0.491 0.070 0.004 0.050 0.230 0.050 1.042 9.97 Cumulative Ibs/acre 0.040 0.020 0.571 0.491 0.070 0.004 0.050 0.230 0.050 1.042 Permit PAN Limit (lbs/acre) 1 st Crop/2nd Crop 200 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 FWPL = FRANKLIN, NC WTP LIQUID (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for luiowing violations." N/A = Not Applicable NR = Not Reported or Not Required %= percent p = pp- or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ -injection, SURIN- Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 - l FJ6UIR 1'Pd7{ENTALTE I .aCSL(�t }eS; ArtC ,TaiyreHl L�'t'�orsiorWg- August 06, 2014 Will Hodges Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: (336) 998-7150 FAX: (336) 998-8450 RE: Franklin WTP Dear Will Hodges: Summit Environmental Technologies, Inc. 3310 Win St. Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX. • (330) 253-4489 Website: hQ.-1 vivw.settek.com Order No.: 14072882 Summit Environmental Technologies, Inc. received 1 sample(s) on 7/30/2014 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, Dr. Mo Osman Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 A2LA 0724.01, Alabama 4I600, Arizona AZ0788, Arkansas 88-0735, California 07256CA, Colorado, Connecticut PH-0105, Delaware, Florida NELAC E87688, Georgia E87688 and 943, Idaho OH00923,.Illinois 200061 and Reg.5, Indiana C-OH-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Louisiana 04061 and LA12004, Maine 2012015, Maryland 339, Massachusetts M-OPH923, Minnesota 409711, Montana CERT0099, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, Ohio Drinking Water 4170, Ohio VAP CL0052, Oklahoma 9940, Oregon 0112O0001, Pennsylvania 68-01335, Rhode Island LA000317, South Carolina 92016001, Tennessee TN04018, Texas T104704466-11-5, Region 8 8TMS-L, USDA/APHIS P330-11-00244, Utah OH009232011-I, Vermont VT-87688, Virginia 00440 and 1581, Washington C891, West Virginia 248 and 9957C and E87688, Wisconsin 399013010 Page 1 of 6 Page 1 of 8 k ` , mamI at SummitEnvironniental Technologies, Inc. 3310 Win St. Workorder Sample Summary Pi-1VI13O7 O,IE�rml-TECIINOLO'GtES,^ INQC Cuyahoga Falls, Ohio 44223 13 a�iyfir€! �sh[trsi t7c'S TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#• 14072882 Website: hU.-Ilwwiv.settek.conr 06 Aug-14 CLIENT: Synagro Project: Franklin WTP Lab SampleID Client Sample ID Tag No Date Collected Date Received Matrix 14072882-001 Franklin WTP 7/28/2014 11:40:00 AM 7/30/2014 10:00:00 AM Sludge Page 2 of 6 Page 2 of 8 Summit Environmental Technologies, Inc. Case Narrative ao Alma ` or 3310 Win St. �€VIRCidI�1,EP1'PL t€CSidit�til;`e5,.3�t_. Cuyahoga Falls, Ohio 44223 WO#• 14072882 /ti craFrr�ia1 l�ic�rs�catlGs TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: httn://ivwiv.settek.com Date: 8/6/2014 CLIENT: Synagro Project: Franklin WTP This report in its entirety consists of the documents listed below. All documents contain the Summit Environmental Technologies, Inc. Work Order Number assigned to this report. Paginated Report including: Cover Letter, Case Narrative, Analytical Results, Applicable Quality Control Summary Reports and copies of the Chain of Custody Documents supplied with this sample set. Concentrations reported with a J flag in the Qual field are values below the Limit of Quantitation (LOQ) but greater than the established Limit of Detection (LOD). There is greater uncertainty associated with these results and data should be considered as estimated. Method numbers, unless specified as SM (Standard Methods) or ASTM, are EPA methods. Estimated uncertainty values are available upon request. Any comments or problems with the analytical events associated with this report are noted below. Original Page 3 of 6 Page 3 of 8 Summit Environmental Technologies, Inc. WO#: 14072882 f °NT �3310 Win St. Cuyahoga Falls, Ohio Date Reported: 8/6/2014 °''fC54if#tC7h1�11;hJ'PsiL<`BEt;�$i'At�L,C1'G;�5�9�EC, J f+� i'l t ralr�rs"e TEL: (330) 253-8211 FAX: (330) 253-4489 Company: Synagro Website: htto:/Avww.settek.com Address: 284 Boger Rd. Mocksville NC 27028 Received: 7/30/2014 Project#: Franklin WTP TCLP Metals Analysis (6010) Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Franklin WTP 001 7/28/2014• TCLP Arsenic(As) 0.50 ND mg/L Sludge EPA 6010 C 1 5.0 8/1/2014 WK Franklin WTP 001 7/28/2014 TCLP Barium(Ba) 5.0 ND mg/L Sludge EPA 6010 C 1 100 8/1/2014 WK Franklin WTP 001 7/28/2014 TCLP Cadmium(Cd) 0.10 ND mg/L Sludge EPA 6010 C 1 1.0 8/1/2014 WK Franklin WTP 001 7/28/2014 TCLP Chromium(Cr) 0.20 ND mg/L Sludge EPA 6010 C 1 5.0 8/1/2014 WK Franklin WTP 001 7/28/2014 TCLP Lead(Pb) 0.50 ND mg/L Sludge EPA 6010 C 1 5.0 8/1/2014 WK Franklin WTP 001 7/28/2014 TCLP Selenium(Se) 0.50 ND mg/L Sludge EPA 6010 C 1 1.0 8/1/2014 WK Franklin WTP 001 7/28/2014 TCLP Silver(Ag) 0.50 ND mg/L Sludge EPA 6010 C 1 5.0 8/1/2014 WK TCLP Mercury Analysis (1311/7470) Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Franklin WTP 001 7/28/2014 TCLP Mercury 0.0020 ND mg/L Sludge EPA 7470 A 1 0.20 8/1/2014 ALJ SVOC SW-846: 8081-TCLP Pesticides Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Franklin WTP 001 7/28/2014 Chlordane, total 0.010 ND mg/L Sludge EPA 8081 B 1 0.030 8/2/2014 JBN Franklin WTP 001 7/28/2014 Toxaphene 0.10 ND mg/L Sludge EPA 8081 B 1 0.50 8/2/2014 JBN Franklin WTP 001 7/28/2014 Endrin 0.0020 ND mg/L Sludge EPA 8081 B 1 0.020 8/2/2014 JBN Franklin WTP 001 7/28/2014 gamma-BHC 0.0020 ND mg/L Sludge EPA 8081 B 1 0.40 8/2/2014 JBN Franklin WTP 001 7/28/2014 Heptachlor 0.0020 ND mg/L Sludge EPA 8081 B 1 0.0080 8/2/2014 JBN Franklin WTP 001 7/28/2014 Heptachlor epoxide 0.0020 ND mg/L Sludge EPA 8081 B 1 0.0080 8/2/2014 JBN Franklin WTP 001 7/28/2014 Methoxychlor 0.0020 ND mg/L Sludge EPA 8081 B 1 10 8/2/2014 JBN VOC by GC/MS (8260)-TCLP Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Franklin WTP 001 7/28/2014 1,1-Dichloroethene 0.10 ND mg/L I Sludge EPA 8260 B 1 0.70 8/1/2014 MES Franklin WTP 001 7/28/2014 1,2-Dichloroethane 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 8/1/2014 MES Franklin WTP 001 7/28/2014 Benzene 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 8/1/2014 MES Franklin WTP 001 7/28/2014 Carbon tetrachloride 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 8/1/2014 MES Franklin WTP 001 7/28/2014 Chlorobenzene 0.10 ND mg/L Sludge EPA 8260 B 1 100 8/1/2014 MES Franklin WTP 001 7/28/2014 Chloroform 0.10 ND mg/L Sludge EPA 8260 B 1 6.0 8/1/2014 MES Franklin WTP 001 7/28/2014 Tetrachloroethene 0.10 ND mg/L Sludge EPA 8260 B 1 0.70 8/1/2014 MES Franklin WTP 001 7/28/2014 Trichloroethene 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 8/1/2014 MES Franklin WTP 001 7/28/2014 Vinyl chloride 0.20 ND mg/L Sludge EPA 8260 B 1 0.20 8/1/2014 MES Franklin WTP 001 7/28/2014 MEK 2.0 ND mg/L Sludge EPA 8260 B 1 200 8/1/2014 MES Summnvronmeaecnoo ies, Inc. Summit Environmental Technologies, WO#: 14072882 •„ 3310 Win St. ENVIROt1FatE'PJ'Pd,L t' BCt LC IaS, ]Pic; Cuyahoga Falls, Ohio 44223 Date Reported: 8/6/2014 �#rpai�i� a1 G3lzrrx�raA'! TEL: (330) 253-8211 FAX: (330) 253-4489 Company: Synagro Website: htin://wwlv.settek.com Address: 284 Boger Rd. Mocksville NC 27028 Received: 7/30/2014 Project#: Franklin WTP SV®C 8270 TCLP BNA List Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Franklin WTP 001 7/28/2014 1,4-Dichlorobenzene 0.10 ND mg/L Sludge EPA 8270 C 1 7.5 8/1/2014 JRT Franklin WTP 001 7/28/2014 2,4,5-Trichlorophenol 0.25 ND mg/L Sludge EPA 8270 C 1 400 8/1/2014 JRT Franklin WTP 001 7/28/2014 2,4,6-Trichlorophenol 0.25 ND mg/L Sludge EPA 8270 C 1 2.0 8/1/2014 JRT Franklin WTP 001 7/28/2014 2,4-Dinitrotoluene 0.10 ND mg/L Sludge EPA 8270 C 1 0.13 8/1/2014 JRT Franklin WTP 001 7/28/2014 Cresols, Total 5.0 ND mg/L Sludge EPA 8270 C 1 200 8/1/2014 JRT Franklin WTP 001 7/28/2014 Hexachloro-1,3- 0.10 ND mg/L Sludge EPA 8270 C 1 0.50 8/1/2014 JRT butadiene Franklin WTP 001 7/28/2014 Hexachlorobenzene 0.10 ND mg/L Sludge EPA 8270 C 1 0.13 8/1/2014 JRT Franklin WTP 001 7/28/2014 Hexachloroethane 0.10 ND mg/L Sludge EPA 8270 C 1 3.0 8/1/2014 JRT Franklin WTP 001 7/28/2014 Nitrobenzene 0.10 ND mg/L Sludge EPA 8270 C 1 2.0 8/1/2014 JRT Franklin WTP 001 7/28/2014 Pentachlorophenol 0.25 ND mg/L Sludge EPA 8270 C 1 100 8/1/2014 JRT Franklin WTP 001 7/28/2014 Pyridine 0.25 ND mg/L Sludge EPA 8270 C 1 5.0 8/1/2014 JRT SV®C SW-846: 8321 Herbicides-TCLP Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Franklin WTP 001 7/28/2014 2,4-D 5.0 ND mg/L Sludge EPA 8321 A 1 10 8/1/2014 AMZ Franklin WTP 001 7/28/2014 2,4,5-TP 0.50 ND mg/L Sludge EPA 8321 A 1 1.0 8/1/2014 AMZ - Summit Environmentaecnooges,Inc.l Technologies, I 3310 Win St. WO#: 14072882 Eff'VIRO NPal E NTt1L12101100,L,OCI.E-Silf4C Cuyahoga Falls, Ohio 44223 Date Reported: 8/6/2014 Ar'aly6ra3t Lwii?.ratorfer TEL: (330) 253-8211 FAX.- (330) 253-4489 Company: Synagro Website: hap://wwiv.settek.com Address: 284 Boger Rd. Mocksville NC 27028 Received: 7/30/2014 Project#: Franklin WTP Client ID# Lab ID# Collected Analyte Result Units Matrix Method DF RL Run Analyst Franklin WTP 001 7/28/2014 Flashpoint (140°F) >140 'F Sludge EPA 1010 1 8/2/2014 TAH Franklin WTP 001 7/28/2014 Total PCBs ND mg/Kg Sludge EPA 8082 1 0.20 8/2/2014 JBN Franklin WTP 001 7/28/2014 Cyanide, Reactive ND ppm Sludge EPA 9014 1 0.50 7/31/2014 TIR Franklin WTP 001 7/28/2014 pH 7.3 s.u. Sludge EPA 9045 D 1 7/31/2014 AYS Franklin WTP 001 7/28/2014 Sulfide, Reactive ND ppm Sludge EPA 9034 1 25 7/31/2014 TIR -U (D ---4 0 h 00 Analysis Request/Chain of Custody For Swrijuit Environmental Technofogje,, Ific. usc c)nl% FLU No Analvfical A 141 41 13aramtter.s and Me(hods 1 Z c .11-11 H, te, L -fv Of Y- 1 �nw - /klx;t e-cmlf.- +-box 4-0 LkItt Sc MUIL 11C JJTT,,NlCd 'allipic" to tile lawritut)''I'he Ault rclam, j —1 1+ Page 1 of Rev 12 Date 07l27113 SLIM >wit Fnvirc n,--entan 1 eehnolcgies., Pnc. Cooler Receipt Farm Initials of person inspecting cooler and sample Client: C L Order Number Date Receiv - -V r Time Received: Date cooler(s) opened and samples inspected:'7 :z"i (-/ � t Number o rsI NIA Shipper D UPS DHL Airborne US Postal Walk-in Pickup Other. Packaging Peanuts ie' ap Paper Foam None Qher: _ Type on cooledbox. N NIA Custody Seals intact < � N NIA C-O-C in plastic N NIA Ice .w Blue ice Je f absent elted WA Sample Temperature IR Gun #1602p459 CF °C "C N A Radiolog:cal Testing Instrument sepal #35127 Y N A (see page 2 for scan results) -Use 1 sheet per sample for Radiological Testing. If sample is HOT. the Radiological Sa Immediately#eiy officer must he notified . C-O-C filled out property N NIA Samples in separate bags N NIA Sample containers Intact' N NIA 'If no, list broken sample(s) Sample labels) complete (ID, date, etc.) N NIA Label(s) agree with C-C+-C N NIA Correct containers used N N/A Sufficient sample received N NIA Bubbles absent from 40 mL vials— Y N NIA — Samples with bubbles <6mm are acceptable. Indicate bubble size if >6mm. Was client contacted about samples Y N Wit client send new samples Y N Client contact- DaterTime: Logged in by: G'QC SHARED\Document Control Templates - TrackinglCooler receipt form Rev. 12 07-27-13.doc Page 1 of 2 CV O (14 0) ca n Page 8 of 8 ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Town of Franklin WTP WQ Permit Number: WQ0035207 WWTP Name: Town of Franklin WTP NPDES Number: PWS 0157010 Monitoring Period: From 01/01/14 To 12/31/14 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/13 (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion If applicable to alternative Derformed (Class A or Class B) comulete the followine monitoring data: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dences Analysis Fecal 2x10 to the 6 th MPN MPN/9 Coliform power per gram of total solids CFU/g CFU 1000 MPN per gram of <337 <337 <337 MPN/g 0 Yearly Grab SM9222D total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: 0 tion/Alt. 1 (VS reduction) Option/Alt.2 (40-day bench) Option/Alt._3 (30-day bench) Option/Alt.4 (Spec. 02 uptake) Option/Mt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed N/A CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met: I am aware that there are significant penalties for false certification including fine and imprisonment." �4 / �' • 5d,n ntr, P pare Name And Title ,Land Applier Name and Title (if applicable) (type or. print) SigfiatYe of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Rogers & Callcott ENVIRONMENTAL Client Synagro-Mocksville Will Hodges 284 Boger Road Mocksville, NC 27028 Dear Client: "cc", Laboratory Report Project: Work Order: Received: Routine 4071159 07/28/2014 16:25 Rogers and Callcott appreciates the opportunity to be of service to you. The attached laboratory services report includes analytical results and chain of custody for samples that were received on July 28, 2014. Rogers and Callcott maintains a formal QA/QC program. Unless otherwise noted, all analyses performed under NELAP certification have complied with all the requirements for the TNI standard. The analyses met the QA/QC confidence interval for each test method unless otherwise qualified. Estimated uncertainty is available upon request. Privileged / Confidential information may be contained in this report and is intended only for the use of the addressee. If you are not the addressee, or the person responsible for delivering to the person addressed, you may not copy or deliver this message to anyone else. If you receive this message by mistake, please notify Rogers and Callcott immediately. "le strive to provide excellent service to our clients. Please contact Melissa Riddle, your Project Manager, at melissa.riddle@rogersandcalleott.com or 164)-232-1556 ifyou have any questions about this report. Report Approved By: Melissa Riddle Project Manager PO Box 5655 I Greenville, SC 29606 1426 Fairforest Way I Greenville, SC 29607 I main 864.232.1556 I fax 864.232.6140 rogersandcallcott.com an employee -owned company This report may not he reproduced, except in full, without wrinen permission from Rogers & Callcott, Inc. Page 1 of 6 Rogers &Callcott ENVIRONMENTAL Certificate of Analysis Client Synagro-Mocksville Will Hodges 284 Boger Road Mocksville, NC 27028 Sample Number Sample Description 4071159-01 Franklin Fecal cAUR� ,l y�geORA'CO i South Carolina Greenville Laboratory Identification 23105 South Carolina Columbia Laboratory Identification 40572 North Carolina Laboratory Certification Number 27 North Carolina Drinking Water lab Number 45710 NELAP Utah Certificate Number SC000042014-1 Georgia Drinking Water Lab ID 880 Project: Routine Work Order: 4071159 Received: 07/28/2014 16:25 Matrix Sampled Type Sludge 07/28/14 11:40 Grab PO Box 5655 I Greenville, SC 29606 1 426 Fairforest Way I Greenville, SC 29607 I main 864.232.1556 I fax 864.232.6140 rogersandeallcott.com an employee -owned company 0810712014 08: 33 This report may not be reproduced, except in full, u-ithout written permission from Rogers & Callcoa, Inc. Page 2 of 6 Rogers &Callc®tt ENVIRONMENTAL Synagro-Mocksville Project: Routine 284 Boger Road Work Order: 4071159 Mocksville, NC 27028 Reported: 08/07/14 08:33 Sample Data Sample Number 4071159-01 Sample Description Franklin Fecal collected on 07/28/14 11:40 Reporting Parameter Result Limit Units DF Analyzed Method Flag Analyst Batch Microbiological Parameters Fecal Coliform, MPN ND 377 MPN/g dry 1.00 07/29/14 09:00 SM 92210E-2006 BLM 1341-10105 Wt General Chemistry Parameters Total Solids 5.30 0.10 % 1.00 07/31/14 14:40 SM 254OG MLR 134G1246 PO Box 5655 1 Greenville, SC 29606 1 426 Fairforest Way I Greenville, SC 29607 1 main 864.232.1556 1 fax 864.232.6140 rogersandcallcott.eom an employee -owned company 0810712014 08:33 This report inay not be reproduced, except in full, without written permission front Rogers & Callcon, Inc. Page 3,of 6 r Rogers, &Callcott t ENVIRONMENTAL Synagro-Mocksville Project: Routine 284 Boger Road Work Order: 4071159 Mocksville, NC 27028 Reported: 08/07/14 08:33 Data Qualifiers and Definitions ND Analyte NOT DETECTED at or above the reporting limit NR Not reported PO Box 5655 1 Greenville, SC 29606 1 426 Fairforest Way I Greenville, SC 29607 1 main 864.232.1556 1 fax 864.232.6140 rogersandcallcott.com an employee -owned company 0810712014 08:33 This report may not be reproduced, except in full, without written permission from Rogers & Callcott, Inc. Page m CD m cn 'o Li a Rogers &Callcott CHAIN '1 ENVIRONMENTAL Mailing PO Box 5655 Shipping 426 Fairforest Way 215E Stoneridge Drive 4ddress: Greenville, SC 29606 Address: Greenville, SC 29607 Columbia, SC 29210 Phone (864) 232-1556 Fax (864) 232-6140 Phone (803) 509-8999 Client Name AddressrXA r A C azaa Report To: r i Email Address C S M Telephone # At'c�' ?�' 31 � PO # Project # F,,,Ati !, OF CUSTODY RECORD WORK ORDER I '' ► i I > 1 u o �, ,. Z E M ) _ �'_ Filtered (yes/No) Cooled (Yes/No) Container Type Llastic/Glass) Container Volume (mL) Sample Type (Grab&omposite) Sample Source (WW, GW, DW, SW, S, Other) A -None E e HrClvation Code Is' Zn Acetate B-HNO3 F-Na25203 J-%PO4 C—NaOH G-Boric Acid K-MCAA D-NaOH H-Ascorbic Acid l- ORDER DATE TIME SAMPLE DESCRIPTION COMMENTS -WORK 01 -28 ZINZI -a1 1 C. S LE SAMPIR-jBELI UI HED BY: 1- DATE/TIME: _1 -/4 RECE V BY: 2. DATE/TI E: - I L Composite Start Date: Composite Start Time: Time or Flow (Circle one) Initials: RELINQUISHE BY: 3. DATE/T_ E: RECEIVED Y: 4• DATE/TIME: RELINQUISHED BY: 5 DATEITIME: RECEIVED BY: 6. DATE/TIME: Temperature of blank or representative sample At time of collection °C At time of lab receipt 5 .S °C RELINQUISHED BY: 7. DATE/TIME: RECEIVED BY: 8 DATEITIME: Possible Hazards associated with samples: Non -Hazard ❑Flammable ❑Skin Irritant 7 Poison FlUnknown Other Form Revised July, 2014 Page of Rogers &Callcott ENVIRONMENTAL Sample Receipt Verification Date �,�( Work I �� Client: Received:' 0 Order: I Carrier Name: lient FedEx UPS US Mail Courier Field Services Other: racking Number: Receipt Criteria Y e s o A Comments Shipping container / cooler intact? Damaged Leaking Other: Custody seals intact? COC included with samples? COC signed when relinquished and received? Sample bottles intact? Damaged Leaking Other: Sample ID on COC agree with label on bottle(s)? Date / time on COC agree with label on bottle(s)? Number of bottles on COC agrees with number of bottles received? Samples received within holding time? Sample volume sufficient for analysis? VOA vials free of headspace (<6mm bubble)? Samples cooled? Temp at receipt recorded on COC Temp measured with IR thermometer - SN: 97050067 Ice Cold Packs Dry Ice None Samples requiring pH preservation at proper pH? Note: Samples for metals analysis may be preserved upon receipt in the lab. Yj Samples dechlorinated for parameters requiring chlorine removal at the time of sample collection? I Y_ I If in-house preservation used — record Lot # HCL H3PO4 H2SO4 NaOH HNO3 Other Comments: Were non-conformance issues noted at sample receipt? Yes or No J Non -Conformance issue other than noted above:. Revised July 2014 Completed by: v Page,;§ of r- 2014 ANNUAL OPERATIONS SUMMARY - LAND APPLICATION "IIOORESVILLE, NC MOORESVILLE, NC WTP #2 LIQUID DRY METRIC MONTHNEAR AMOUNT UNIT DRY TONS UNIT TONS December 2014 899,000.00 G 76.11 D 69.01 YEARLY TOTAL 899,000.00 G 76.11 D 69.01 2/17/2015 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: W00035207 Facility Name: MOORESVILLE, NC NPDES#: or WQ# (residual only) WWTP Name: MOORESVILLE WTP #2 Residuals Analysis Data Product Type WPL Date Sampled (grab) or 07/30/14 Date Composited Percent Solids 2.03 PARAMETERS (mg/kg dry weight) Arsenic 15 Cadmium <2 Mercury <0.4 Chromium 66 Copper 107 Lead 8 Molybdenum <5 Nickel 13 Selenium <5 Zinc 60 Total Phosphorus 1680 TKN 14300 Ammonia -Nitrogen 3940 Nitrate and Nitrite <2 Laboratory A&L Eastern Laboratories Inc. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Date Z' Z�Z, 1,6, (SIGNATURE OF PREP, DENR FORM RSSF (5/2003) Printed: Tuesday - February 17, 2015 at 14:04:05 for: 2099 02 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0035207 Facility Name: MOORESVILLE, NC NPDES#: or WQ# (residual only) WWTP Name: MOORESVILLE WTP #2 Residuals Analysis Data Product Type WPL Date Sampled (grab) or 07/30/14 Date Composited Percent Solids 2.03 PARAMETERS (mg/kg dry weight) Aluminum 147000 Calcium 2520 Magnesium 1200 pH 7.00 Potassium 1230 Sodium 390 Laboratory A&L Eastern Laboratories Inc. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." X TU NR - Data Not Reported or Data Not Required Date Z- Z (f • /,!§- DENR FORM RSSF-B (7/2002) Printed: Tuesday - February 17 2015 at 14:06:21 for: 2099 02 Page: 1 of 2• Report Number: 14-212-0202 Account Number: 46511 Submitted By: DREW CULP Send To: SYNAGRO CENTRAL LLC/MOORESVILL Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 A&L Eastern Laboratories, Inc. @P. 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271.6446 www.aleastern.com Project: MOORESVILLE WTP NC CERT#257 REPORT OF ANALYSIS Date Sampled: 7/30/2014 11:15:00 Lab Number: 56791 Date Received: 07/31/2014 00:00 Samnle Id : MOORESVILLE WTP Date Reported: 08/08/2014 Total Solids * L.W cuOw I VN.V- Moisture * 97.97 100.0 JM 08/01/2014 08:30 SM-254OG Total Kjeldahl Nitrogen 1.43 14300 10.0 JM 08/01/2014 08:15 SM-4500-NH3C-TKN Total Phosphorus 0.17 1680 100 KM 08/01/2014 11:57 SW 6010C Total Potassium 0.12 1230 100 KM 08/01/2014 11:57 SW 6010C Total Sulfur 0.73 7300 100 KM 08/01/2014 11:57 SW 6010C Total Calcium 0.25 2520 100 KM 08/01/2014 11:57 SW 6010C Total Magnesium 0.12 1200 100 KM 08/01/2014 11:57 SW 6010C Total Sodium 0.04 390 100 KM 08/01/2014 11:57 SW 6010C Total Iron 25100 100 KM 08/01/2014 11:57 SW 6010C Total Aluminum 147000 100 KM 08/01/2014 11:57 SW 6010C Total Manganese 868 5 KM 08/01/2014 11:57 SW 6010C Total Copper 107 5 KM 08/01/2014 11:57 SW 6010C Total Zinc 60 5 KM 08/01/2014 11:57 SW 6010C Ammonia Nitrogen 0.39 3940 10.0 JM 08/01/2014 08:15 SM-4500-NH3C Organic N 1.04 10360 10.0 08/01/2014 08:15 CALCULATION Nitrate+Nitrite-N <2.00 2.00 TW 08/04/201410:20 SM-450ONO3F Total Cadmium <2.0 2.0 1KM 08/01/2014 11:57 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. not be reproduced in whole or art, nor may any reference be made Our reports and letters are for the exclusive and confidential use of our clients, and may p p to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Page: 2 of 2 Report Number: 14-212-0202 Account Number: 46511 Submitted By: DREW CULP Send To: SYNAGRO CENTRAL LLC/MOORESVILL Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 56791 Sample Id : MOORESVILLE WTP �LA&L Eastern Laboratories, Inc._ 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271.W6 wwwaleastern.com Project: MOORESVILLE WTP NC CERT#257 REPORT OF ANALYSIS Date Sampled: 7/30/2014 11:15:00 Date Received: 07/31/2014 00:00 Date Reported: 08/08/2014 Total Chromium 66 5 KM 08/01/2014 11:57 SW 6010C Total Nickel 13 5 KM 08/01/2014 11:57 SW 6010C Total Lead 8 5 KM 08/01/2014 11:57 SW 6010C Total Arsenic 15.0 3.0 KM 08/01/2014 11:57 SW 6010C Total Mercury <0.4 0.4 KM 08/04/2014 14:00 SW-7471 B Total Selenium <5.0 5.0 KM 08/01/2014 11:57 SW 6010C pH (Standard Units) * 7.00 2.00 JM 08/01/2014 08:15 SW-9045D Total Molybdenum <5 5 KM 08/01/2014 11:57 SW 6010C Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE MATRIX SPIKE DUPLICATE WAS OUT OF LIMITS FOR NO3+NO2-N, ALL OTHER QC DATA WAS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt SAMPUNG LOG CUSTOMER: SYNAGROSOUTHEA! PROJECT' MANAGER:: pl�prje: 5-a AA L CUSTOMER' SAI LAS #i SAMPLE I;Dz L01 t.-e—fi6quis.fied 6y_.Sar%1er.-. IIIIIIIIIIIIIIIhil�lllllllllllll(IIIllllillllll(Ilillllllllllll '14212-0202 6 , I-2014 I j4L. SYNAGRO - CENTRAL LLCIMOORESVILLOR' IAIN OF'CUSTCOV & 7� MOORESV!LLE WTP DdADkAij4A.LvS1.s O:R" _94U_ RECORD 804/743- 1 av-tr�f - , — I attest,that the proper field sampling procedures were used during the, collecUon of these samples. .0AMPLE 9. OF SAMPLING METHOD METHOD 'TYPE 'CONTAINERS DATE TIME PRESERVED SHIPPED 7r IQL-1 Q I Time 1. 07/�v/IY IPj5-,q,.P, Fajt,,� by: Miulh Rell wished by: Date, Time R - e 57 .Rq1inquiA67d'd hNT I Date Time 'Reckkied by SPECIAL INSTRUCTIONS: 44 ,REMARKS: 'SAMPLE ANALSISAEQUEST SLI SL.2 NHeN N0,14 Od Cr. Ni Pb As fig So pH c8co voldule 0 Cl NOeN t� Mlle 1090f ow X�o 9000 P00 140f 1000 Pot: 1400' 1409 MAI'. 240t'4' MOistur6)� TbWL Wjeldahl: Niiro"d, l6m,8odn' ho-sphorus, -and, Potassium. ,ptaL Soil ., j SO;, E3ci-j'-1ens-t,8L1- �pftfotijll`Ur, C orn, Mi%gn iii �lrorfAlumiinym-..Maqg-atiqs�,,Q-oppqr,and:Zino sic Ae Um 'White —.A &L Canary,.=MANAGEMCOPY Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date Report Range Ratio 2099-02-WPL-NC MOORESVILLE, NC WTP #2 LIQUID 7/30/2014 811/2014-12/31/2014 0.2273 Na mg/I = (Na mg/kg x % Solids) _ 100 = (390 x 2.0300) = 100 = 7.917 Ca mg/I = (Ca mg/kg x % Solids) = 100 = (2520 x 2.0300) = 100 = 51.156 Mg mg/1 = (mg mg/kg x % Solids) = 100 = (1200 x 2.0300) t- 100 = 24.36 Na meq = Na mg/I — Molec.Wgt.Na = 7.917 + 23 = 0.344217 Ca meq = Ca mg/I = Molec.Wgt.Ca = 51.156 = 20 = 2.5578 Mg meq = Mg mg/1 _ Molec.Wgt.Mg = 24.36 = 12 = 2.03 SAR = Na meq s- SgrRoot[0.5 x (Ca meq + Mg meq)] = 0.344217 + SgrRoot[0.5(2.5578+2.03)] = 0.227272 Printed: 2/17/2015 Page 1 14:09 FACILITY NAME: MOORESVILLE, NC OWNER: LARRY EDWARDS SITE #: NC IR 00021 FIELD# : IR 00021 0001 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: BETHLEHEM PERMIT #: WQ0014136 ANNUAL DRY TONS APPLIED: 7.87 OPERATOR: LARRY EDWARDS CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 13.80 ACRES PERMITTED: 13.80 Page Lime Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Acre Solids 12/17/14 93,000.00 (G) 6739.130 2.03 0.570 M2WPL MOIST 0-<I/2" SUR 0.5 0.40 [T�i3,940.00 p 2.00 p 6116 FESCUE Dec-14 93,000.00 (G) 6,739.130 Total Gallons/Ac: 6,739.13 As Cd Cr Cu Pb I-lg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 7 0.017 0.002 0.075 0.122 0.009 <.001 0.006 0.015 0.006 0.068 1.92 Cumulative lbs/acre 0.017 0.002 0.075 0.122 0.009 <.001 0.006 0.015 0.006 0.068 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop 216 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 M2WPL = MOORESVILLE, NC WTP #2 LIQUID (SIGNATURE OF LAND APPLIER) DATE "I certify; under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required %= percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 FACILITY NAME: MOORESVILLE, NC OWNER: LARRY EDWARDS SITE #: NC IR 00021 FIELD# : IR 00021 0002 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: PACOLET PERMIT #: W00014136 ANNUAL DRY TONS APPLIED: 24.67 OPERATOR: LARRY EDWARDS CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 15.90 ACRES PERMITTED: 15.90 Page Lime Applied *** Date Lbs/Ac DATE or allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) ado Solids Dry Tons per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppm) Crop Total MONTH Per Acre 12/I1/14 49,600.00 (G) 3119.497 2.03 0.264 M2WPL MOIST 0-<1/2" SUR 0.5 0.40 14,300. p 3,940.00 p 2.00 p 6 116 I FESCUE 12/12/14 186,000.00 (G) 11698.113 2.03 0.990 M2WPL DRY 0-<1/2" SUR 0.5 0.40 14,300. p 3,940.00 p 2.00 p 6116 I FESCUE 12/15/14 55,800.00 (G) 3509.434 2.03 0.297 M2WPL DRY 0-<I/2" SUR 0.5 0.40 14,300. p 3,940.00 p 2.00 p 6116 FESCUE Dec-14 1 291,400.00 (G) 18,327.044 iorai vanons/Ac: 15,Jri.u4 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annuallbs/acre 19 0.047 0.006 0.205 0.332 0.025 0.001 0.016 0.040 0.016 0.186 5.21 Cumulative lbs/acre 0.061 0.010 0.305 1.057 0.090 0.007 0.047 0.090 0.030 2.403 ; Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop 77. 216 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 M2WPL = MOORESVILLE, NC WTP #2 LIQUID X !, Z/ 2Q l (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for Imowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent ' p = ppm or mg/kg * * Volatilization Rate: Surface 0.5, Injection/lacorporation 1.0 * Application Method: SUR - Surface, INJ -Injection, SURIN - Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 FACILITY NAME: MOORESVILLE, NC OWNER: LARRY EDWARDS SITE #: NC IR 00021 FIELD# : IR 00021 0003 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: PACOLET PERMIT #: W00014136 ANNUAL DRY TONS APPLIED: 30.44 OPERATOR: LARRY EDWARDS CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 33.90 ACRES PERMITTED: 33.90 Page : 1 Lime Applied *** Date Lbs/Ac DATE or allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Dry Tons Per Residual Site Cond. Dry, Wet, " Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (pptn) Crop MONTH Total Per Acre Solids 12/11/14 86,800.00 (G) 2560.472 2.03 0.217 M2WPL . MOIST 0-<I/2" SUR 0.5 0.40 14,300. p 3,940.00 p 2.00 p F 6116 I FESCUE 12/15/14 124,000.00 (G) 3657.817 2.03 0.310 M2WPL DRY 0-<1/2" SUR 0.5 0.40 14,300.p 3,940.00 p 2.00 p 6116 Ij FESCUE 12/16/14 148,800.00 (G) 4389.381 2.03 0.372 M2WPL MOIST 0-<1/2" SUR 0.5 0.40 14,300.p 3,940.00 p 2.00 p 6116 FESCUE Dec-14 359,600.00 (G) 10,607.670 1 Total Gallons/Ac: 10,607.67 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 11 0.027 0.004 0.119 0.192 0.014 <.001 0.009 0.023 0.009 0.108 3.02 Cumulative lbs/acre 0.027 0.004 0.119 0.192 0.014 <.001 0.009 0.023 0.009 0.108 Permit PAN Limit (Ibs/acre) 1st Crop/2nd Crop 216 FD Cumulative Pollutant LoadingRate Limit Ibs/acre ( ) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 M2WPL = MOORESVILLE, NC WTP #2 LIQUID Aia�,r�, — ez6a ,s- (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 ANNUAL LAND APPLICATION FIELD SUMMARY FORM FACILITY NAME: MOORESVILLE, NC PREDOMINANT SOIL SERIES: CECIL OWNER: LARRY EDWARDS PERMIT #: W00014136 ANNUAL DRY TONS APPLIED: 13.12 SITE #: NC IR 00021 FIELD# : IR 00021 0005 OPERATOR: LARRY EDWARDS CATION EXCHANGE CAPACITY (NON-503): RESIDUAL SOURCE(S):* See list at bottom of report ACRES UTILIZED: 29.50 ACRES PERMITTED: 29.50 Page Lime Applied *** Date Lbs/Ae DATE or allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) °�" Dry Tons Per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- till- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppm) Crop MONTH Total Per Acre Solids 12/16/14 55,800.00 (G) 1891.525 2.03 0.160 M2WPL MOIST 0-<1/2" SUR 0.5 0.40 14,300. p 3,940.00 p 2.00 p 6116 I FESCUE 12/17/14 99,200.00 (G) 3362.712 2.03 0.285 M2WPL MOIST 0-<1/2" SUR 0.5 0.40 14,300. p 3,940.00 p 2.00 p 6116 1 FESCUE Dec-14 1 155,000.00 (G) 5,254.237 Total Gallons/Ac: 5,254.24 iotat t;uuic Yas/AC: U.UU As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 0.013 0.002 0.059 0.095 0.007 <.001 0.004 0.012 0.004 0.053 1.49 5 Cumulative lbs/acre 0.013 0.002 0.059 0.095 0.007 <,001 0.004 0.012 0.004 0.053 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop 216 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0,, - M2WPL = MOORESVILLE, NC WTP #2 LIQUID x Akx/ /aw b��ol5` (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg * * Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records. Section of Report for Fields where Lime is to be applied in 2015 ' �:��'1rIFi�AI1+7@hJT.1�L���l�wa![3L{bC�1c5,Etd�. �a��lyiicaP %naa�+lba�li=�: August 12, 2014 Drew Culp Synagro, NC 28134 12701 Lancaster Hwy Pineville, NC 28134 TEL: 704-752-8673 FAX: 704 752 8736 RE: Mooresville WTP Dear Drew Culp: Summit Environmental Technologies, Inc. 3310 Win St. Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: h1tp.-1APivw.settek.con: Order No.: 14072988 Summit Environmental Technologies, Inc. received I sample(s) on 7/31/2014 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, W �� Dr. Mo Osman Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 A2LA 0724.01, Alabama 41600, Arizona AZ0788, Arkansas 88-0735, California 07256CA, Colorado, Connecticut PH-0105, Delaware, Florida NELAC E87688, Georgia E87688 and 943, Idaho OH00923, Illinois 200061 and Reg.5, Indiana C-OH-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Louisiana 04061 and LA12004, Maine 2012015, Maryland 339, Massachusetts M-OPH923, Minnesota 409711, Montana CERT0099, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, Ohio Drinking Water 4170, Ohio VAP CL0052, Oklahoma 9940, Oregon OH200001, Pennsylvania 68-01335, Rhode Island LA000317, South Carolina 92016001, Tennessee TN04018, Texas T104704466-11-5, Region 8 8TMS-L, USDA/APHIS P330-11-00244, Utah OH009232011-1, Vermont VT-87688, Virginia 00440 and 1581, Washington C891, West Virginia 248 and 9957C and E87688, Wisconsin 399013010 Page 1 of 9 'S U NAI V r I Summit Environmental Technologies, Inc. Workorder 3310 Win St. K-HVIROtdPa1'ENTAL` ECIV-1r l,d 1E.ciINC. Cuyahoga Falls, Ohio 44223 Sample Summary t�caiyt4ral L<9fiprslgs'h TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 14072988 Website: http://iviviv.settek.com 12 Aug-14 CLIENT: Synagro, NC 28134 Project: Mooresville WTP Lab SampleID Client Sample ID Tag No Date Collected Date Received Matrix 14072988-001 Mooresville WTP 2014 7/30/2014 11:15:00 AM 7/31/2014 9:30:00 AM Sludge Page 2 of 9 Summit Environmental Technologies, Inc. ��-vv ` } 3310 Win St. 4�`sllSe Narrative or 6 Cd4+f tLYh1N+tEAiY!!L�'�GtRdvc7LgGl�iS JNQQ Cuyahoga Falls, Ohio 44223 WO#: 14072988 Ae�iafyt r.'af t �i'aysi ,rF s TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http.-Aviviv.settek.com Date: 8/12/2014 CLIENT: Synagro, NC 28134 Project: Mooresville WTP This report in its entirety consists of the documents listed below. All documents contain the Summit Environmental Technologies, Inc. Work Order Number assigned to this report. Paginated Report including: Cover Letter, Case Narrative, Analytical Results, Applicable Quality Control Summary Reports and copies of the Chain of Custody Documents supplied with this sample set. Concentrations reported with a J flag in the Qual field are values below the Limit of Quantitation (LOQ) but greater than the established Limit of Detection (LOD). There is greater uncertainty associated with these results and data should be considered as estimated. Method numbers, unless specified as SM (Standard Methods) or ASTM, are EPA methods. Estimated uncertainty values are available upon request. Any comments or problems with the analytical events associated with this report are noted below. Revision v1 Page 3 of 9 Zb Summit Environmental Technologies, Inc. WO#: 14072988 3310 Win St. BtSvlit�irilfa9f:�!'i�L"t�Ct�a�+�_ l,�c�3� a,,9Pf� CeryahogaFalls, Ohio 44223 Date Reported: 8/12/2014 trrastf +r.'a} l :l1orleirAt?s TEL: (330) 253-8211 FAX.- (330) 253-4489 Company: Synagro, NC 28134 Website: http://ivwiv.settek.coni Address: 12701 Lancaster Hwy Pineville NC 28134 Received: 7/31 /2014 Project#: Mooresville WT TCLP Metals Analysis (6010) Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Mooresville WTP 001 7/30/2014 TCLP Arsenic(As) 0.50 ND mg/L Sludge EPA 6010 C 1 5.0 8/4/2014 WK 2014 Mooresville WTP 001 7/30/2014 TCLP Barium(Ba) 5.0 ND mg/L Sludge EPA 6010 C 1 100 8/4/2014 WK 2014 Mooresville WTP 001 7/30/2014 TCLP Cadmium(Cd) 0.10 ND mg/L Sludge EPA 6010 C 1 1.0 8/4/2014 WK 2014 Mooresville WTP 001 7/30/2014 TCLP Chromium(Cr) 0.20 ND mg/L Sludge EPA 6010 C 1 5.0 8/4/2014 WK 2014 Mooresville WTP 001 7/30/2014 TCLP Lead(Pb) 0.50 ND mg/L Sludge EPA 6010 C 1 5.0 8/4/2014 WK 2014 Mooresville WTP 001 7/30/2014 TCLP Selenium(Se) 0.50 ND mg/L Sludge EPA 6010 C 1 1.0 8/4/2014 WK 2014 Mooresville WTP 001 7/30/2014 TCLP Silver(Ag) 0.50 ND mg/L Sludge EPA 6010 C 1 - 5.0 8/4/2014 WK 2014 TCLP Mercury Analysis (1311/7470) Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Mooresville WTP 001 7/30/2014 TCLP Mercury 0.0020 ND mg/L Sludge EPA 7470 A 1 0.20 8/4/2014 ALJ 2014 SVOC SW-846: 8081-TCLP Pesticides Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Mooresville WTP 001 7/30/2014 Chlordane, total 0.010 ND mg/L Sludge EPA 8081 B 1 0.030 8/5/2014 JBN 2014 Mooresville WTP 001 7/30/2014 Toxaphene 0.10 ND mg/L Sludge EPA 8081 B 1 0.50 8/5/2014 JBN 2014 Mooresville WTP 001 7/30/2014 Endrin 0.0020 ND mg/L Sludge EPA 8081 B 1 0.020 8/5/2014 JBN 2014 Mooresville WTP 001 7/30/2014 gamma-BHC 0.0020 ND mg/L Sludge EPA 8081 B 1 0.40 8/5/2014 JBN 2014 Mooresville WTP 001 7/30/2014 Heptachlor 0.0020 ND mg/L Sludge EPA 8081 B 1 0.0080 8/5/2014 JBN 2014 Mooresville WTP 001 7/30/2014 Heptachlor epoxide 0.0020 ND mg/L Sludge EPA 8081 B 1 0.0080 8/5/2014 JBN 2014 Mooresville WTP 001 7/30/2014 Methoxychlor 0.0020 ND mg/L Sludge EPA 8081 B 1 10 8/5/2014 JBN 2014 Page 4 of 9 1 . Summit Environmental Technologies, Inc. 3310 Win St. WO#: 14072988 ffl,su.pm S i t;NtihiOPdWa•J`Pi°tL`C`fq�He°dO,L,aG3.r5,.I,tC Cuyahoga Falls, Ohio94223 Date Reported: 8/12/2014 Arrafjfi 6alLiil araipriei5 TEL: (330) 253-8211 FAX.- (330) 253-4489 Company: Synagro, NC 28134 Website: huy.-Ilwiviv.settek.com Address: 12701 Lancaster Hwy Pineville NC 28134 Received: 7/31 /2014 Project#: Mooresville WT VOC by GC/MS (8260)-TCLP Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Mooresville WTP 001 7/30/2014 1,1-Dichloroethene 0.10 ND mg/L Sludge EPA 8260 B 1 0.70 8/6/2014 MES 2014 Mooresville WTP 001 7/30/2014 1,2-Dichloroethane 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 8/6/2014 MES 2014 Mooresville WTP 001 7/30/2014 Benzene 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 8/6/2014 MES 2014 Mooresville WTP 001 7/30/2014 Carbon tetrachloride 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 8/6/2014 MES 2014 Mooresville WTP 001 7/30/2014 Chlorobenzene 0.10 ND mg/L Sludge EPA 8260 B 1 100 8/6/2014 MES 2014 Mooresville WTP 001 7/30/2014 Chloroform 0.10 ND mg/L Sludge EPA 8260 B 1 6.0 8/6/2014 MES 2014 Mooresville WTP 001 7/30/2014 Tetrachloroethene 0.10 ND mg/L Sludge EPA 8260 B 1 0.70 8/6/2014 MES 2014 Mooresville WTP 001 7/30/2014 Trichlo(bethene 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 8/6/2014 MES 14 oresville WTP 001 7/30/2014 Vinyl chloride 0.20 ND mg/L Sludge EPA 8260 B 1 0.20 8/6/2014 MES zu14 Mooresville WTP 001 7/30/2014 MEK 2.0 ND mg/L Sludge EPA 8260 B 1 200 8/6/2014 MES 2014 SVOC 8270 TCLP BNA List Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Mooresville WTP 001 7/30/2014 1,4-Dichlorobenzene 0.10 ND mg/L Sludge EPA 8270 C 1 7.5 8/9/2014 JRT 2014 Mooresville WTP 001 7/30/2014 2,4,5-Trichlorophenol 0.25 ND mg/L Sludge EPA 8270 C 1 400 8/9/2014 JRT 2014 Mooresville WTP 001 7/30/2014 2,4,6-Trichlorophenol 0.25 ND mg/L Sludge EPA 8270 C 1 2.0 8/9/2014 JRT 2014 Mooresville WTP 001 7/30/2014 2,4-Dinitrotoluene 0.10 ND mg/L Sludge EPA 8270 C 1 0.13 8/9/2014 JRT 2014 Mooresville WTP 001 7/30/2014 Cresols, Total 5.0 ND mg/L Sludge EPA 8270 C 1 200 8/9/2014 JRT 2014 Mooresville WTP 001 7/30/2014 Hexachloro-1,3- 0.10 ND mg/L Sludge EPA 8270 C 1 0.50 8/9/2014 JRT 2014 butadiene Mooresville WTP 001 7/30/2014 Hexachlorobenzene 0.10 ND mg/L Sludge EPA 8270 C 1 0.13 8/9/2014 JRT 2014 Mooresville WTP 001 7/30/2014 Hexachlorbethane 0.10 ND mg/L Sludge EPA 8270 C 1 3.0 8/9/2014 JRT 2014 Mooresville WTP 001 7/30/2014 Nitrobenzene 0.10 ND mg/L Sludge EPA 8270 C 1 2.0 8/9/2014 JRT 2014 Mooresville WTP 001 7/30/2014 Pentachlorophenol 0.25 ND mg/L Sludge EPA 8270 C 1 100 8/9/2014 JRT 2014 Mooresville WTP 001 7/30/2014 Pyridine 0.25 ND mg/L Sludge EPA 8270 C 1 5.0 8/9/2014 JRT 14 Page 5 of •9 x Sumrnit Environmental Technologies, Inc. WO#: 14072988 3310 Win St. Date Reported: 8/12/2014 : Fr4FIRC5Npa1Eh!(n�L.3"E 61:171t i 5. IPic Cuyahoga Falls, Ohio44223 P t�rFa�x tT��s i P_; E�irr icw�N TEL: (330) 253-8211 FAX. (330) 253-4489 Company: Synagro, NC 28134 Website: http://www.settek.com Address: 12701 Lancaster Hwy Pineville NC 28134 Received: 7/31/2014 Project#: Mooresville WT SVOC SW-846: 8321 Herbicides-TCLP Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method D)+ RegLvl Run Analyst Mooresville WTP 001 7/30/2014 2,4-D 5.0 ND mg/L Sludge EPA 8321 A 1 10 8/6/2014 AMZ 2014 Mooresville WTP 001 7/30/2014 2,4,5-TP 0.50 ND mg/L Sludge EPA 8321 A 1 1.0 8/6/2014 AMZ 2014 Page 6 of 9 Summit Environmental Technologies, Inc. WO#: 14072988 -S U AN M I T 3310 Win St. Date Reported: 8/12/2014 Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX- (330) 253-4489 Company: Synagro, NC 28134 Websile: huy.-Iliviviv.settekcom Address: 12701 Lancaster Hwy Pineville NC 28134 Received: 7/31/2014 Proj ect#: Mooresville WT Client ID# Lab ID# Collected Analyte Result Units Matrix Method DF RL Run Analyst Mooresville WTP 001 7/30/2014 Flashpoint (140°F) 2014 Mooresville WTP 001 7/30/2014 Cyanide, Reactive 2014 Mooresville WTP 001 7/30/2014 Free Liquid 2014 Mooresville WTP 001 7/30/2014 pH 2014 Mooresville WTP 001 7130/2014 Sulfide, Reactive 2014 >200 *F Sludge EPA1010 1 8/2/2014 TAH ND pprn Sludge EPA 9014 1 0.50 8/1/2014 TIR Fail Sludge EPA 9095 1 7/31/2014 AYS 6.2 s.u. Sludge EPA 9045D 1 7/31/2014 AYS ND pprn Sludge EPA 9034 1 25 8/1/2014 TIR Page 7 of 9 "SUMMIT i;NViHOMMCNTA.L IECHNOLOGrieS.INC 33 i G YJIn Street culrat.ogp falls, ON. 4.12:.J Analysis Request I Chain of Custody For Summit i aviroruaental Technologies, Inc. use only nuc.-ua-U1.1u Page 3 of SET No 17%,11 td;m)e S na roCentral Project lt;L arc9mo❑ vr11,. WP /V&a+rCST Pr.—i Addre- WTp ':n • u �- ..i F 'C! ,e �—�„ � r y G v Analyticalaratttetei's and Metbods Cik:rt Aiiw,-, 12701 Lancaster Hwy Pineville NC. 28134 sIi r��/ `'t �{y + V) � Z< ,� 1 'x r. ` ('"I:aat r;1c+n 704 752-8673 tCcp�ut 'ro Zi R E W G Lrt t-f' PO 1,wvix r Chtnu Fat N,, tkc:c. 1k;,ulrs nv i a..N 704-752-8736 (',�1i1: o Pers ill QuArSi: N'mnbj--, Sampled t3y DRE W t "A L i7 if Ohio VAP Samples fd Este: 4 " ftira��i:st z}tinn ALC Collected Timey (.1,11ectc1l kxrc,5v;116 WTP Ci 4 to 41H INS 5 L x 4—tT 51AII-N i 611 Ilished bv; Date Time Received by: �pikl- C -----� \Uic< <�'1t11 [I}gili5: �a t u 1 LF Sync{ '-O . Ga'v) � P ! (' 07 30 ly /S= 00 Received in Lab by. I).ite t t,n. Rush Requested:i1a: i4t 1MuA be approved h! L.a6'Mal w I _ Rev 12 Date: 07127113 Summit Envirotirrentai Tachrlologies, irtc. CCOier Receipt Form Initials Uf person inspecting rrodlr.arrd Simples Client Q\uk k LW order Number. - _ -- -- - Date RPr::eiVed—JfN.J1q Time Rereivei_AI Date coolertsl opened and samp as .respected: / �II ui.[ Number of Coo(erst$ax NA Shipper DE"?t�U�PPS�'lDHL Airborne US Postal Watk-in Pickup Other;_._ Packaging Peanuts ubbleWr p paper Foam None 01her_ Tape on cooter/box- Y �f N NA Clstody Seals intact i Yf N C-0-C in plastic NA Y N N A presen absent r melted N�A 17ai Sample Temperature iR Gun >Y1r�02rIG59 CF -----1C ---'C N.A Radiniog:raa Testing lnstrurnent sen;ai el3§127 Y N NA (see pa.,je 2 rrr scan results) "Use 1 sheet per sample for Radiological Testing. If sample is HOT. the Radiological Safety Officer must immediately be norAed C-d-C filled out properly N � WA Samples in separate bags N t NIA) Sample containers intact' /Y N aNIA 'if no. Irst broken sarnplesl_._ �^ Sample label(s) complete (ID, date. etc I N NA Label(s) agree with C-O-t; Y N N/A Correct containers used Y N NIA Su'bcient sample received o Y� N N/A Eubbles absent from 40 mL vials" Y N NtA — Samples with bubbles <6mm are acceptable. Indicate bubble size it >6mm Was client contacted about samples Y N Will client send new samples Y N Client contact Dater�ime Logged in by _. Comments' G'tQC SHAREDtDocument Control Templates - TraclunglCooler receipt form Rev. 12 07.27.13 doc Page 1 of 2 Page 9 of 9 ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Mooresville WTP WQ Permit Number: WQ0035207 WWTP Name: Mooresville WTP NPDES Number: PWS 0149015 Monitoring Period: From 01/01/14 To 12/31/14 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: . Alt. 1/A (time/temp) Alt. 2/13 (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/1) (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion If annlicable to alternative nerformed (Class A nr Clasc R) rmmnlete the fnllnwina mnnitnrina data - Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dences Analysis Fecal 2x10to the 6 1h MPN MPN/g Coliform power per gram of total solids CFU CFU/g 1000 MPN per gram of <6 <6 <6 MPN/g 0 Yearly Grab SM9222D total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: Option/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed N/A CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X_ reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement to 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Preparer Name And 'tle Land Applier Name and Title (if applicable) (type or print) Signature of PreparerO Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Cf 1 NC Certification No. 402 SC Certification No. 99012 Case Narrative DI S M FUII-Service Analytical & NC Drinking Water Cert No. 37735 08/04/2014 t-7 Environmental Solutions VA Certification No. 460211 `✓ LABORATORIES, INC. DoD ELAP: L-A-B Accredited Certificate No. L2307 ISO/IEC 17025: L-A-B Accredited Certificate No. L2307 Synagro Project: 2014 Production-MPN Drew Culp 12701 Lancaster Hwy. Lab Submittal Date: 07/30/2014 Pineville, NC 28134 Prism Work Order: 4070585 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. Cara C. Rusmisell Project Manager Data Qualifiers Key Reference: Reviewed By Cara C. Rusmisell Project Manager BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041526-0409 Page 1 of 6 &Am" I� M I Full -Service Analytical s Environmental Solutions ®IAOOMTOF Client Sample ID Sample Receipt Summary 08/04/2014 Prism Work Order: 4070585 Lab Sample ID - Matrix Date Sampled Date Received Mooresville WTP Fecal 2014 4070585-01 Solid 07/30/14 07/30/14 Samples were received at 13.9 degrees C. See case narrative for further information. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/52"409 ,age2'of`6. ` �0!sn nFull-Service Analyticals' V' Environmental SolutionsRIES, INC. 4 Laboratory Report 08/04/2014 riynagro Project: 2014 Production-MPN Client Sample ID: Mooresville wTP Fecal 2014 Attn: Drew Culp Prism Sample ID: 4070585-01 12701 Lancaster Hwy. Prism Work Order: 4070585 Pineville, NC 28134 Sample Matrix: Solid Time Collected: 07/30/14 11:15 Time Submitted: 07/30/14 12:25 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters % Solids 3.40 % by 0.100 0.100 1 "SM2540 G 7130114 16:00 JAB P4G0531 Weight Microbiologibal Parameters Fecal Coliforms BRL MPN/g dry 6 1 'SM9221 E 7/30114 13:39 JHB . P41-10023 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 "` Rage.3,of`6. PoR I S I� nFull-Service Analytical&' V'Evironmental Solutions IES ING Level II QC Report 8/4/14 ;ynagro Project: 2014 Production-MPN Prism Work Order: 4070585 Attn: Drew Culp Time Submitted: 7/30/2014 12:25:OOPM 12701 Lancaster Hwy. Pineville, NC 28134 General Chemistry Parameters - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch M0531 - NO PREP Blank (P4G0531-BLK'I) Prepared & Analyzed: 07/30/14 % Solids 100 0.100 % by Weight This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 -.Charlotte, NC 28224-0643 Phone: 704I529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 4.Of,6 .. . "\ C A� i1 �/ {�� Full -Service Analytical & 9 S tl Y Y Environmental Solutions ®LABORATORIES, INC ynagro Project: 2014 Production-MPN /Attn: Drew Culp 12701 Lancaster Hwy. Pineville, NC 28134 Microbiological Parameters - Quality Control Level II QC Report 8/4/14 Prism Work Order: 4070585 Time Submitted: 7/30/2014 12:25:OOPM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P41-10023 - NO PREP Blank (P41-10023-131-K1) Prepared & Analyzed: 07/30/14 Fecal Coliforms BRL 0.2 MPN/g wet This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 -Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 5 of 6 CHAIN OF CUSTODY RECORD m PRISM Full -Service Analytical & YES NO N/A Environmental Solutions PAGE OF QUOTE 0 TO ENSURE PROPER BILLING: Samples INTACT upon arrival? � � O �"�k�n ` LA80FlATORIES, INC- ✓�r� � " �-r,G� Project Name: fi)00� PSV lie_ VV 1 1 Received ON WET ICE? T 449 Springbrook Road • Charlotte, NC 28217 Phone 704/529-6364 Fax: 7041525-0409 Short Hold Analysis: (Yes) (No) UST Project: (Yes) (NO) PROPER PRESERVATIVES indicated? — -- - Ill T �� *Please ATTACH any project specific reporting (QC LEVEL 1 II III IV) Received WITHIN HOLDING TIMES? Client Company Name: provisions and/or QC Requirements CUSTODY SEALS INTACT? Report To/Contact Name: DkV,11' CIA )l2 Invoice To: �h1�}C��+`ty VOLArILES ec'd w!OUT HEADSPACE? - - _ Reporting Address: 1 17o p g /_cl nG SFc,n � -� Address: PROPER CONTAINERS used? at �l ___ !3 °C °C TEMP: Therm ID: r Observed: / Corr. /1.,F Phone: 7w-57r/-S 2-1/ Fax (Yes) to Email Address:=uAc,"jt-.P 6 S'; AJ,44 /to • EDD Type: PDF X Excel Other Site Location Name: Site Location Physical Address: 1'n�<� Yj'/I,�, Purchase Order No./Billing Reference S0 -- ,-/ 67 C4 1 Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days "Working Days" ❑ 6-9 Days ❑ Standard 10 days ❑ Rush re h Work Must Be Samples received after 14:00 will be processed next business day. oved iyC Turnaround time is based on business days, excluding weekends and holidays. (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Certification: NELAC DOD FL NCB_ SC OTHER NIA Water Chlorinated: YES_ NO K Sample Iced Upon Collection: YES_ r NO_ CLIENT SAMPLE DESCRIPTION DATE COLLECTED TIME COLLECTED MILITARY HOURS MATRIX (SOIL, WATER OR SLUDGE) SAMPLE CONTAINER PRESERVA- TIVES ANALYSIS REQUESTED REMARKS PRISM LAB ID NO. *TYPE SEE BELOW NO. SIZE m.r;7 inz.s v, r� WrF' �� 2�;1� c`7f3�%iy =IS'>�•t�l S%-—� � t, c� ��� Ccl Yh N ! UI,,- CI M10 Sampler's Signature ✓ / Sampled By (Print Name) ��1� CL4 /-16 Affiliation S 0 1111 IN t 7- Upon relinquishing, this Chain of Custody i4 your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been initialized. Relinquish By: (Signature) Received By: (Signature) Date Military/Hours /Z_ ZS Additional Comments: me: Relinqui y: (Signature) �' Received By: (Signature) Date Field Tech Fee: Relinquished By: (Signature) Re For Prism oratories By: Date `�-3� •! C2� j Mileage: Method of Shipment: NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WI CUSTOD SEALS FOR TRANSPORTATION TO THE LABORATORY. SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST CT UNTIL 7RCEIVED AT THE LABORATORY, ❑ Fed Ex ❑ UPS ❑ Hand -delivered ❑ Prism Field Service ❑ Other COC Group No. 1 U(� - - —' NPDES: UST: I GROUNDWATER: DRINKING WATER: SOLID WASTE: RGRA: GERGLA LANDFILL UIHEK: ilalli El NC ❑ SC ❑ NC ❑ SC i ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC �J3i1uCZ31JL ❑ 1 ❑ ❑ ❑ ❑- _ ❑ ❑ ❑ *CONTAII YPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined C )A = Volatile Organics Analysis (Zero Head Space) 2014 ANNUAL OPERATIONS SUMMARY - LAND APPLICATION -PIEDMONT TRIAD RWA, NC `PIEDMONT TRIAD RWA, NC RANDLEMAN LAKE WTP CAKE DRY METRIC MONTHNEAR AMOUNT UNIT DRY TONS UNIT TONS January 2014 11.00 Y 1.39 D 1.26 February 2014 120.00 Y 15.20 D 13.78 March 2014 90.00 Y 11.40 D 10.34 April 2014 495.00 Y 91.47 D 82.97 May 2014 270.00 Y 49.89 D 45.24 June 2014 404.00 Y 74.65 D 67.71 July 2014 240.00 Y 29.37 D 26.63 August 2014 300.00 Y 36.72 D 33.28 September 2014 180.00 Y 22.03 D 19.97 October 2014 150.00 Y 33.60 D 30.49 November 2014 127.00 Y 28.45 D 25.81 YEARLY TOTAL 2,387.00 Y 394.17 D 357.48 PIEDMONT TRIAD RWA, NC RANDLEMAN LAKE WTP LIQUID DRY METRIC MONTHNEAR AMOUNT UNIT DRY TONS UNIT TONS June 2014 1,085,000.00 G 16.28 D 14.77 July 2014 651,000.00 G 9.78 D 8.86 YEARLY TOTAL 1,736,000.00 G 26.06 D 23.63 2/17/2015 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: Laboratory Facility Name: PIEDMONT TRIAD RWA, NC A&L Eastern Laboratories Inc. NPDES#: or WQ# (residual only) WWTP Name: RANDLEMAN LAKE WTP Residuals Analysis Data Product Type WPC WPC WPC WPL WPC Date Sampled (grab) or 01/07/14 04/23/14 07/02/14 07/02/14 10/08/14 Date Composited Percent Solids 15.04 21.94 14.53 0.36 26.60 PARAMETERS (mg/kg dry weight) Arsenic 7 5 6 6 5 Cadmium <2 <2 <2 <2 4 Mercury <0.4 <0.4 <0.4 <0.4 0.4 Chromium 167 123 53 35 30 Copper 18 37 171 54 28 Lead <5 8 <5 <5 31 Molybdenum 6 <5 <5 5 16 Nickel 8 13 14 11 11 Selenium 5 6 <5 6 <5 Zinc 34 44 39 37 68 Total Phosphorus 1450 1510 1620 1330 894 TKN 12400 11300 13400 19400 8830 Ammonia -Nitrogen 2330 1910 2270 2780 3800 Nitrate and Nitrite 6.65 7.75 8.95 167 <2 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." X OF PREP Date DENR FORM RSSF (5/2003) Printed: Tuesday - February 17 2015 at 14:05:32 for: 2196 01 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: Laboratory Facility Name: PIEDMONT TRIAD RWA, NC A&L Eastern Laboratories Inc. NPDES#: or WQ# (residual only) WWTP Name: RANDLEMAN LAKE WTP Residuals Analysis Data Product Type WPC WPC WPC WPL WPC Date Sampled (grab) or 01/07/14 04/23/14 07/02/14 07/02/14 10/08/14 Date Composited Percent Solids 15.04 21.94 14.53 0.36 26.60 PARAMETERS (mg/kg dry weight) Aluminum 178000 124000 177000 180000 12200 Calcium 2880 4210 1510 2840 1570 Magnesium 595 869 1480 1370 467 pH 6.48 6.46 6.68 6.71 5.46 Potassium 296 401 341 685 206 Sodium 161 267 157 3180 468 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Date 2 --2 3—/5 (SIGNATURE OF PREPAR NR - Data Not Reported or Data Not Required DENR FORM RSSF-B (7/2002) Printed: Tuesday - February 17 2015 at 14:06:52 for: 2196 01 Page: 1 of 2 Report Number: 14-010-0205 Account Number: 46622 Submitted By: JAMES BLACKWELL Send To: SYNAGRO CENTRAUTECHNICAL MARY BREWER 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 97424 Sample Id : PIEDMONT TRIAD RWA @9. A&L Eastern Laboratories, Inc._ 7621 Whitepine Road ,Richmond, Virginia 23237 (804)'743-9401 Fax (804) 271-696 wwwaleastem.com Project: PIEDMONT TRIAD RWA NC CERT#257 REPORT" OF ANALYSIS Date Sampled: 1/7/2014 12:20:00 Date Received: 01/10/2014 00:00 Date Reported: 01/15/2014 Total Solids * 15.04 150400 100.0 JM 01/10/2014 14:19 SM-2540G Moisture * 84.96 100.0 JM 01/10/2014 14:19 SM-2540G Total Kjeldahl Nitrogen 1.24 12400 10.0 JM 01/13/2014 08:30 SM-4500-NH3C-TKN Total Phosphorus 0.15 1450 100 KM 01/13/2014 11:35 SW 6010C Total Potassium 0.03 296 100 KM 01/13/2014 11:35 SW 6010C Total Sulfur 1.60 16000 100 KM 01/13/2014 11:35 SW 6010C Total Calcium 0.29 2880 100 KM 01/13/2014 11:35 SW 6010C Total Magnesium 0.06 595 100 KM 01/13/2014 11:35 SW 6010C Total Sodium 0.02 161 100 KM 01/13/2014 11:35 SW 6010C Total Iron 18900 100 KM 01/13/2014 11:35 SW 6010C Total Aluminum 178000 100 KM 01/13/2014 11:35 SW 6010C Total Manganese 4490 5 KM 01/13/2014 11:35 SW 6010C Total Copper 18 5 KM 01/13/2014 11:35 SW 6010C Total Zinc 34 5 KM 01/13/2014 11:35 SW 6010C Ammonia Nitrogen 0.23 2330 10.0 JM 01/15/2014 08:05 SM-4500-NH3C Organic N 1.01 10070 10.0 01/13/2014 08:30 CALCULATION Nitrate+Nitrite-N 6.65' 2.00 JM 01/13/2014 08:30 SM-450ONO3F Total Cadmium <2.0 2.0 KM 01/13/2014 11:35 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work,. the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Page: 2 of 2 Report Number: 14-010-0205 Account Number: 46622 Submitted By: JAMES BLACKWELL Send To: SYNAGRO CENTRAL/TECHNICAL MARY BREWER 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 97424 Sample Id : PIEDMONT TRIAD RWA A&L Eastern- Laboratories, Inc- 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 • Fax (804) 271-6446 wwwaleastem,com Project: PIEDMONT TRIAD RWA NC CERT#257 REPORT OF ANALYSIS Date Sampled: 1/7/2014 12:20:00 Date Received: 01/10/2014 00:00 Date Reported: 01/15/2014 Total Chromium 167 5 KM 01/13/2014 11:35 SW 601OC Total Nickel 8 5 KM 01/13/2014 11:35 SW 601OC Total Lead <5 5 KM 01/13/2014 11:35 SW 601OC Total Arsenic 7.0 3.0 KM 01/13/2014 11:35 SW 6010C Total Mercury <0.4 0.4 KM 01/13/2014 09:00 SW-7471 B Total Selenium 5.0 5.0 KM 01/13/2014 11:35 SW 601OC pH (Standard Units) * 6.48 2.00 JM 01/13/2014 08:30 SW-9045D Total Volatile Solids 40.19 401900 •100.0 JM 01/10/2014 14:19 SM-2540G Total Molybdenum 6 5 KM 01/13/2014 11:35 SW 601OC Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE MSD WAS OUT OF LIMITS FOR "NO3/NO2-N" AND "Se". THE MATRIX SPIKE WAS OUT OF LIMITS FOR "As" AND "S". ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and lettersarefor the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt SAMPLING LOG # CUSTOMER: SYNAGRO SOUTHEAST PROJECT MANAGER: Phone: rr II :RAIN OF CUSTODY IIIIIIIIIIIIIlII�IIII�III I�II��I�I) I�IIIIIIIII) 65 .ECOR ER® ANALYSIS SYNAcRO (EN RqLrECHNIICAL o2o,aA 13:07 46 PIEDMONT TRIAD RWA field sampling procedures vvcr c u.^cu uur n ry j„C collection of these samples. SAM A & L CUSTOMER LAB # SAMPLE I.D. SAMPLING LOCATION SAMPLE TYPE # OF CONTAINERS SAMPLING DATES TIME METHOD PRESERVED METHOD SHIPPED 1 ,jG. ."A- �'r � 4i v, 4y W �7 � .J " � .. L'T i �+: •N� i�•ti �i. �. V � i.i�.f I Rel' quished by Sampler: Date Time Recieved by: REMARKS: a ' gelinquished by: Date Time Recieved by: Relinquished by: Date Time Recieved by: SPECIAL INSTRUCTIONS: For ha t-- rc1nrc monitoring purposes. PO#: '50— --; -rev SAMPLE ANALYSIS REQUEST I.D. SL1 SL2 NH4-N NO3 N Organic i N Cd Cr I Ni Pb As Hg Se PH CeaCO3 e uiv. Volatile Solids Mo CI NO_ N CwA 11001, 1000 t*of POO t-40 toot po toor SL1: Total Solids (Moisture), Total Kjetdahl Nitrogen, Phosphorus, and Potassium SL2: Basic Test SL1 plus Sulfur, Calcium, Magnesium. Sodium, Iron, Aluminum. Manganese, Copper and Zinc White —A & L Canary — MANAGER COPY Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date Report Range Ratio 2196-01-WPC-NC PIEDMONT TRIAD RWA, NC RANDLEMAN 1/7/2014 111/2014-3131/2014 0.2759 LAKE WTP CAKE Na mg/I = (Na mg/kg x % Solids) _ 100 = (161 x 15.0400) = 100 = 24.2144 Ca mg/I = (Ca mg/kg x % Solids) _ 100 = (2880 x 15.0400) _ 100 = 433.152 Mg mg/I = (mg mg/kg x % Solids) = 100 = (595 x 15.0400) = 100 = 89.488 Na meq = Na mg/I = Molec.Wgt.Na = 24.2144 + 23 = 1.0528 Ca meq = Ca mg/I = Molec.Wgt.Ca = 433.152 = 20 = 21.6576 Mg meq = Mg mg/I = Molec.Wgt.Mg = 89.488 _ 12 = 7.45733 SAR = Na meq + SgrRoot[0.5 x (Ca meq + Mg meq)] = 1.0528 _ SgrRoot[0.5(21.6576+7.45733)] = 0.275933 Printed: 2/17/2015 Page 1 14:12 Page: 1 of 2 Report Number: 14-119-0201 Account Number: 46622 Submitted By: MARSHALL PURYEAR Send To: SYNAGRO CENTRAL/TECHNICAL MARY BREWER 284 BOGER RD MOCKSVILLE , NC 27028 A&L Eastern Laboratories, ,Inc 990 7,621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271-6446 wmAeastem.c_om Project: PIEDMONT TRIAD WTP NC CERT#257 REPORT OF ANALYSIS Date Sampled: 4/23/2014 12:30:00 Lab Number: 55060 Date Received: 04/29/2014 00:00 SamDle Id : PIEDMONT TRIAD WTP Date Reported: 05/02/2014 Total Solids " Moisture * Total Kjeldahl Nitrogen Total Phosphorus Total Potassium Total Sulfur 21.94 78.06 1.13 0.15 0.04 0.76 Z"I u4uu 11300 1510 401 7610 1 UU.0 100.0 10.0 100 100 100 .nr, JM JM KM KM KM 04/29/2014 15:00 04/30/2014 08:35 05/01/2014 08:58 05/01/2014 08:58 05/01/2014 08:58 - -- - - SM-254OG SM-4500-NH3C-TKN SW 6010C SW 6010C SW 6010C Total Calcium Total Magnesium Total Sodium Total Iron Total Aluminum Total Manganese Total Copper Total Zinc Ammonia Nitrogen Organic N Nitrate+Nitrite-N 0.42 0.09 0.03 0.19 0.94 4210 869 267 21900 124000 1980 37 44 1910 9390 7.75 100 100 100 100 1.00 5 5 5 10.0 10.0 2.00 KM KM KM KM KM KM KM KM JM JM 05/01/2014 08:58 05/01/2014 08:58 05/01/2014 08:58 05/01/2014 08:58 05/01/2014 08:58 05/01/2014 08:58 05/01/2014 08:58 05/01/2014 08:58 04/30/2014 08:35 04/30/2014 08:35 04/30/2014 08:35 SW 6010C SW 6010C SW 6010C SW 6010C SW 6010C SW 6010C SW 6010C SW 6010C SM-4500-NH3C CALCULATION SM-450ONO3F Total Cadmium <2.0 2.0 KM 05/01/2014 08:58 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. clients, and may not be re Our reports and letters are for the exclusive and confidential use of our cG y produced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Page: 2 of 2 Report Number: 14-119-0201 Account Number: 46622 Submitted By: MARSHALL PURYEAR Send To: SYNAGRO CENTRAL/TECHNICAL MARY BREWER 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 55060 Sample Id : PIEDMONT TRIAD WTP utA&L Eastern Laboratories, Inc._ 7621 Whitepine Road Richmond, Virginia 23237 (804)'743-9401 Fax (804) 271.6446 wwwaleastem.com Project: PIEDMONT TRIAD WTP NC CERT#257 REPORT OF ANALYSIS Date Sampled: 4/23/2014 12:30:00 Date Received: 04/29/2014 00:00 Date Reported: 05/02/2014 Total Chromium 123 5 KM 05/01/2014 08:58 SW 6010C Total Nickel 13 5 KM 05/01/2014 08:58 SW 6010C Total Lead 8 5 KM 05/01/2014 08:58 SW 6010C Total Arsenic 5.0 3.0 KM 05/01/2014 08:58 SW 6010C Total Mercury <0.4 0.4 KM 04/30/2014 09:00 SW-7471 B Total Selenium 6.0 5.0 KM 05/01/2014 08:58 SW 6010C pH (Standard Units) * 6.46 2.00 JM 04/30/2014 08:35 SW-9045D Total Molybdenum <5 5 KM 05/01/2014 08:58 SW 6010C Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR "NO3/NO2-N", "Al", "K", "P", AND "S". ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date Report Range Ratio 2196-01-WPC-NC PIEDMONT TRIAD RWA, NC RANDLEMAN 4/23/2014 4/1/2014-6/30/2014 0.4572 LAKE WTP CAKE Na mg/I = (Na mg/kg x % Solids) = 100 = (267 x 21.9400) = 100 = 58.5798 Ca mg/1= (Ca mg/kg x % Solids) = 100 = (4210 x 21.9400) =100 = 923.674 Mg mg/I = (mg mg/kg x % Solids) = 100 = (869 x 21.9400) =100 = 190.659 Na meq = Na mg/I _ Molec.Wgt.Na = 58.5798 _ 23 = 2.54695 Ca meq = Ca mg/I — Molec.Wgt.Ca = 923.674 = 20 = 46.1837 Mg meq = Mg mg/I _ Molec.Wgt.Mg = 190.659 = 12 = 15.8882 SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 2.54695 _ SgrRoot[0.5(46.1837+15.8882)] = 0.45718 Printed: 2/17/2015 Page 1 14:12 Page: 1 of 2 Report Number: 14-189-0211 w A&L Eastern Laboratories, Inc:_ Account Number: 46622 � 7621WhitepineRoad Richmond,Virginia 23237 (804)743-9401 Fax (804) 271 . U46 o Submitted By: WILL HODGES wwwaleastern.t:om Send To: SYNAGRO CENTRAL/TECHNICAL Project: PIEDMONT TRIAD WTP MARY BREWER NC CERT # 257 284 BOGER RD MOCKSVILLE , NC 27028 REPORT OF ANALYSIS Lab Number: 56321 Sample Id : PIEDMONT TRIAD WTP CAKE Date Sampled: 7/2/2014 11:00:00 Date Received: 07/08/2014 00:00 Date Reported: 07/11/2014 Total Solids * 14.53 145300 100.0 JM 07/08/2014 14:24 SM-2540G Moisture * 85.47 100.0 JM 07/08/2014 14:24 SM-2540G Total Kjeldahl Nitrogen 1.34 13400 10.0 JM 07/09/2014 07:59 SM-4500-NH3C-TKN Total Phosphorus 0.16 1620 100 KM 07/09/2014 13:05 SW 6010C Total Potassium 0.03 341 100 KM 07/09/2014 13:05 SW 6010C Total Sulfur 1.52 15200 100 KM 07/09/2014 13:05 SW 6010C Total Calcium 0.15 1510 100 KM 07/09/2014 13:05 SW 6010C Total Magnesium 0.15 1480 100 KM 07/09/2014 13:05 SW 6010C Total Sodium 0.02 157 100 KM 07/09/2014 13:05 SW 6010C Total Iron 13900 100 KM 07/09/2014 13:05 SW 6010C Total Aluminum 177000 100 KM 07/09/2014 13:05 SW 6010C Total Manganese 1710 5 KM 07/09/2014 13:05 SW 6010C Total Copper 171 5 KM 07/09/2014 13:05 SW 6010C Total Zinc 39 5 KM 07/09/2014 13:05 SW 6010C Ammonia Nitrogen 0.23 2270 10.0 JM 07/09/2014 07:59 SM-4500-NI3C Organic N 1.11 11130 10.0 07/09/2014 07:59 CALCULATION Nitrate+Nitrite-N 8.95 2.00 JM 07/09/201410:00 SM-450ONO3F Total Cadmium <2.0 2.0 KM 07/09/2014 13:05 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may hot be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Page: 2 of 2 Report Number: 14-189-0211 Account Number: 46622 Submitted By: WILLHODGES Send To: SYNAGRO CENTRAL/TECHNICAL MARY BREWER 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 56321 Sample Id : PIEDMONT TRIAD WTP CAKE A&L Eastern- -Laboratories, Inc._ 7621 Whitepirie Road Richmond, Virginia 23237 (804)143.9401 Fax (804) 271.6446 wwwaleastern.com Project: PIEDMONT TRIAD WTP NC CERT # 257 REPORT OF ANALYSIS Date Sampled: 7/2/2014 11:00:00 Date Received: 07/08/2014 00:00 Date Reported: 07/11/2014 Total Chromium 53 5 KM 07/09/2014 13:05 SW 6010C Total Nickel 14 5 KM 07/09/2014 13:05 SW 6010C Total Lead <5 5 KM 07/09/2014 13:05 SW 6010C Total Arsenic 6.0 3.0 KM 07/09/2014 13:05 SW 6010C Total Mercury <0.4 0.4 KM 07/09/2014 09:00 SW-7471 B Total Selenium <5.0 5.0 KM 07/09/2014 13:05 SW 6010C pH (Standard Units) * 6.68 2.00 JM 07/09/2014 07:59 SW-9045D Total Molybdenum <5 5 KM 07/09/2014 13:05 SW 6010C Comments: SULFUR AND ORGANIC NITROGEN,NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE LRB WAS OUT OF LIMITS FOR "Zn", THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Ca" AND "Cr," ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date Report Range Ratio 2196-01-WPC-NC PIEDMONT TRIAD RWA, NC RANDLEMAN 7/2/2014 711/2014-9/30/2014 0.2610 LAKE WTP CAKE Na mg/I = (Na mg/kg x % Solids) _ 100 = (157 x 14.5300) =100 = 22.8121 Ca mg/I = (Ca mg/kg x % Solids) = 100 = (1510 x 14.5300) _ 100 = 219.403 Mg mg/I = (mg mg/kg x % Solids) = 100 = (1480 x 14.5300) _ 100 = 215.044 Na meq = Na mg/I _ Molec.Wgt.Na = 22.8121 _ 23 = 0.99183 Ca meq = Ca mg/I _ Molec.Wgt.Ca = 219.403 _ 20 = 10.9702 Mg meq = Mg mg/1= Molec.Wgt.Mg = 215.044 = 12 = 17.9203 SAR = Na meq - SgrRoot[0.5 x (Ca meq + Mg meq)] = 0.99183 _ SgrRoot[0.5(10.9702+17.9203)] = 0.260961 Printed: 2/17/2015 Page 1 14:12 Page: 1 of 2 Report Number: 14-189-0212 Account Number: 46622 Submitted By: MARSHALL PURYEAR Send To: SYNAGRO CENTRAL/TECHNICAL MARY BREWER 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 56322 Sample Id: PIEDMONT TRIAD WTP LIQUID AY A&L Eastern• Laboratories, Inc- � LL 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271-6446 wwmr,aleastern.com Project: PIEDMONT TRIAD WTP LIQUID REPORT OF ANALYSIS Date Sampled: 7/2/2014 11:05:00 Date Received: 07/08/2014 00:00 Date Reported: 07/11/2014 Total Solids * 0.36 3600 100.0 JM 07/08/2014 14:24 SM-2540G Moisture * 99.64 100.0 JM 07/08/2014 14:24 SM-2540G Total Kjeldahl Nitrogen 1.94 19400 10.0 JM 07/09/2014 07:59 SM-4500-NH3C-TKN Total Phosphorus 0.13 1330 100 KM 07/09/2014 13:05 SW 6010C Total Potassium 0.07 685 100 KM 07/09/2014 13:05 SW 6010C Total Sulfur 1.55 15500 100 KM 07/09/2014 13:05 SW 6010C Total Calcium 0.28 2840 100 KM 07/09/2014 13:05 SW 6010C Total Magnesium 0.14 1370 100 KM 07/09/2014 13:05 SW 6010C Total Sodium 0.32 3180 100 KM 07/09/2014 13:05 SW 6010C Total Iron 11800 100 KM 07/09/2014 13:05 SW 6010C Total Aluminum 180000 100 KM 07/09/2014 13:05 SW 6010C Total Manganese 4010 5 KM 07/09/2014 13:05 SW 6010C Total Copper 54 5 KM 07/09/2014 13:05 SW 6010C Total Zinc 37 5 KM 07/09/2014 13:05 SW 6010C Ammonia Nitrogen 0.28 2780 10.0 JM 07/09/2014 07:59 SM-4500-NH3C Organic N 1.66 16620 10.0 07/09/2014 07:59 CALCULATION Nitrate+Nitrite-N 167 2.00 JM 07/09/201410:00 SM-450ONO3F Total Cadmium <2.0 2.0 KM 07/09/2014 13:05 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made , to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Page: 2 of 2 Report Number: 14-189-0212 Account Number: 46622 Submitted By: MARSHALL PURYEAR Send To: SYNAGRO CENTRAL/TECHNICAL MARY BREWER 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 56322 Sample Id : PIEDMONT TRIAD WTP LIQUID NAFL Eastern Laboratories, Inc._ 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271."46 www.aleastern.com Project: PIEDMONT TRIAD WTP LIQUID REPORT OF ANALYSIS Date Sampled: 7/2%2014 11:05:00 Date Received: 07/08/2014 00:00 Date Reported: 07/11/2014 Total Chromium 35 5 KM 07/09/2014 13:05 SW 6010C Total Nickel 11 5 KM 07/09/2014 13:05 SW 6010C Total Lead <5 5 KM 07/09/2014 13:05 SW 6010C Total Arsenic 6.0 3.0 KM 07/09/2014 13:05 SW 6010C Total Mercury <0.4 0.4 KM 07/09/2014 09:00 SW-7471 B Total Selenium 6.0 5.0 KM 07/09/2014 13:05 SW 6010C pH (Standard Units) 6.71 2.00 JM 07/09/2014 07:59 SW-9045D Total Molybdenum 5 5 KM 07/09/2014 13:05 SW 6010C Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE LRB WAS OUT OF LIMITS FOR "Zn", THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Ca" AND "Cr," ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt SAMPLING LOG # CUSTOMER: SYNAGR® 12 iL LABS, Inc. A & L EASTERN LASS INC 00M12014 PIEDMONT TRIAD WTP LIQUID 13:14:41 46 CHAIN OF CUSTODY RECORD & ANALYSIS RECORD PROJECT MANAGER: t�'��ti�ha l� i��,•,� u. attest that the proper field sampling procedures were used during the collection of these samples. Phone: i 430 -7t,-6 ` Erco z. e S LER A & L CUSTOMER SAMPLING SAMPLE # OF SAMPLING METHOD METHOD LAB # SAMPLE I.D. LOCATION TYPE CONTAINERS DATE TIME PRESERVED SHIPPED 6p?�2114 ReIinq qed by Sample[; Date Time Recieved by: REMARKS: C'xSo63a305 Relinquished by: SPECIAL INSTRUCTIONS: For /1Aa monitoring purposes. -„ r_ Time. Recieved by: 110 3e Time Recieved by: pn#- SAMPLE ANALYSIS REQUEST I.D. SL1 SL2 NH4 N NO3 N Organic N Cd Cr Ni Pb As H 9 Se PH CaCO3 equiv. Valatiie Solids M° CI NO2 N �fiWT- j r,'ac.1 � � !0 ka � f0 � � r� l� l� to !0 „ P�'ea�wwwt- 'T'-d LJL'Q / JL.1: [ULU.I JOIIOS (moisture), Iotal Kleldahl Nitrogen, Phosphorus, and Potassium SL2: Basic Test SLi plus Sulfur, Calcium, Magnesium, Sodium, Iron, Aluminum, Manganese, Copper and Zinc Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date ReportRange Ratio 2196-01-WPL-NC PIEDMONT TRIAD RWA, NC RANDLEMAN 7/2/2014 6/1/2014-9/30/2014 0.7330 LAKE WTP LIQUID Na mg/I = (Na mg/kg x % Solids) _ 100 = (3180 x 0.3600) _ 100 = 11.448 Ca mg/I = (Ca mg/kg x % Solids) = 100 = (2840 x 0.3600) + 100 = 10.224 Mg mg/I = (mg mg/kg x % Solids) _ 100 = (1370 x 0.3600) _ 100 = 4.932 Na meq = Na mg/I + Molec.Wgt.Na = 11.448 _ 23 = 0.497739 Ca meq = Ca mg/I _ Molec.Wgt.Ca = 10.224 _ 20 = 0.5112 Mg meq = Mg mg/I = Molec.Wgt.Mg = 4.932 + 12 = 0.411 SAR = Na meq _ SgrRoot[0.5 x (Ca meq + Mg meq)] = 0.497739 + SgrRoot[0.5(0.5112+0.411)] = 0.733 Printed: 2/17/2015 Page 1 14:12. Page: 1 of 2 Report Number: 14-283-0209 Acco u nt' N um ber: 46622 Submitted By: M.ARSHALL PURYEAR Send To:, SYNAGRO CENTRAL/TECHNICAL MARY BREWER 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 58053 SampleId : PIEDMONT TRIAD WTP A&L. Eastern Laboratories, Inc.. TL -7621 Whitepine Road Richmond, Virginia 23237 .(804)'743-9401 Fax (804) 271-6446 wwWaleastern.com Project: PIEDMONT TRIAD WTP NC CERT#257 REPORT OF ANALYSIS Date Sampled: 10/8/2014 08:00:00 Date Received: 10/10/2014 00:00 Date Reported: 10/21/2014 Total Solids * 26.60 266000 100.0 JM 10/10/2014 14:35 SM-2540G Moisture * 73.40 100.0 JM 1rO/10/2014 14:35 SM-2540G Total Kjeldahl Nitrogen 0.88 8830 10.0 JM 10/13/2014 07:54 SM-4500-NH3C-TKN Total Phosphorus 0.09 894 100 KM 10/17/2014 11:35 SW 6010C Total Potassium 0.02 206 100 KM 10/17/2014 11:35 SW 6010C Total Sulfur 0.40 4020, 100 KM 10/17/2014 11:35 SW 6010C Total Calcium 0.16 1570 100 KM 10/17/2014 11:35 SW 6010C Total Magnesium 0.05 467 100 KM 10/17/2014 11:35 SW 6010C Total Sodium 0.05 468 100 KM 10/17/2014 11:35 SW 6010C Total Iron 431000 100 KM 10/17/2014 11:35 SW 6010C Total Aluminum 12200 100 KM 10/17/2014 11:35 SW 6010C Total Manganese 1110 5 KM 10/17/2014 11:35 SW 6010C Total Copper 28 5 KM 10/17/2014 11:35 SW 6010C Total Zinc 68 5 KM 10/17/2014 11:35 SW 6010C Ammonia Nitrogen 0.38 3800 10.0 JM 10/13/2014 07:54 SM-4500-NH3C Organic N 0.50 5030 10.0 10/13/2014 07:54 CALCULATION Nitrate+Nitrite-N <2.00 2.00 JM 10/13/2014 07:55 SM-450ONO3F Total Cadmium 4.0 2.0 KM 10/17/2014 11:35 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our rep orts'and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made , (` to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Page: 2 of 2 Report Number: 14-283-0209 Account Number: 46622 Submitted By: MARSHALL PURYEAR Send To: SYNAGRO CENTRAL/TECHNICAL MARY BREWER 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 58053 Sample Id : PIEDMONT TRIAD WTP A&L Eastern Laboratories, Inc._ 7621 Whitepine Road Richmond, Virginia 23237 (804)'743-9401 Fax (804) 271.6446 wwwaleastem.com Project: PIEDMONT TRIAD WTP NC CERT#257 REPORT OF ANALYSIS Date Sampled: 10/8/2014 08:00:00 Date Received: 10/10/2014 00:00 Date Reported: 10/21/2014 Total Chromium 30 5 KM 10/17/2014 11:35 SW 6010C Total Nickel 11 5 KM 10/17/2014 11:35 SW 6010C Total Lead 31 5 KM 10/17/2014 11:35 SW 6010C Total Arsenic 5.0 3.0 KM 10/17/2014 11:35 SW 6010C Total Mercury 0.4 0.4 KM 10/13/2014 09:00 SW-7471 B Total Selenium <5.0 5.0 KM 10/17/2014 11:35 SW 6010C pH (Standard Units) * 5.46 2.00 JM 10/13/2014 07:54 SW-9045D Total Molybdenum 16 5 KM 10/17/2014 11:35 SW 6010C Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Al", "Cr", "P", AND "S". ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date Report Range Ratio 2196-01-WPC-NC PIEDMONT TRIAD RWA, NC RANDLEMAN 10/8/2014 10/112014-12/31/2014 1.3696 LAKE WTP CAKE Na mg/1= (Na mg/kg x % Solids) _ 100 = (468 x 26.6000) + 100 = 124.488 Ca mg/I = (Ca mg/kg x % Solids) + 100 = (1570 x 26.6000) _ 100 = 417.62 Mg mg/I = (mg mg/kg x % Solids) _ 100 = (467 x 26.6000) + 100 = 124.222 Na meq = Na mg/1— Molec.Wgt.Na = 124.488 _ 23 = 5.41252 Ca meq = Ca mg/I + Molec.Wgt.Ca = 417.62 _ 20 = 20.881 Mg meq = Mg mg/1 _ Molec.Wgt.Mg = 124.222 + 12 = 10.3518 SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 5.41252 _ SgrRoot[0.5(20.881+10.3518)] = 1.36965 Printed: 2/17/2015 Page 1 14:12 FACILITY NAME: PIEDMONT TRIAD RWA, NC OWNER: ROCKING FARM LLC SITE #: NC GU 0OX16 FIELD# : GU 0OX16 0001 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: CORONACA PERMIT #: W00035207 OPERATOR: STEVE FIELDS ANNUAL DRY TONS APPLIED: 94.55 CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 4.40 ACRES PERMITTED: 4.40 Page : 1 Lime Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) oh Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dryo, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Acre Solids 3/28/14 90.00 (CY) 20.455 15.04 2.591 PTRWARL MOIST 0-<1/2" SUR 0.5 0.40 12,400. p 2,330.00 p 6.65 p 5200 FESCUE Mar-14 90.00 (CY) 20.455 4/2/14 105.00 (CY) 23.864 21.94 4.410 PTRWARL MOIST 0-<1/2" SUR 0.5 0.40 11,300. p 1,910.00 p 7.75 p 4719 I FESCUE 4/3/14 90.00 (CY) 20.455 21.94 3.780 pTRWARL MOIST 0-<1/2" SUR 0.5 0.40 11,300. p 1,910.00 p 7.75 p 4719 I FESCUE 4/4/14 60.00 (CY) 13.636 21.94 2.520 PTRWARL MOIST 0-<1/2" SUR 0.5 0.40 11,300. p 1,910.00 p 7.75 p 4719 FESCUE Apr-14 255.00 (CY) 57.955 6/2/14 105.00 (CY) 23.864 21.94 4.410 pTRWARL DRY 0-<1/2" SUR 0.5 0.40 11,300. p 1,910.00 p 7.75 p 4719 FESCUE 6/3114 60.00 (CY) 13.636 21.94 2.520 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 11,300. p 1,910.00 p 7.75 p 4719 FESCUE 6/6/14 30.00 (CY) 6.818 21.94 1.260 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 11,300. p. 1,910.00 p 7.75 p 4719 FESCUE Jun-14 195.00 (CY)l 44.318 FACILITY NAME: PIEDMONT TRIAD RWA, NC OWNER: ROCKING FARM LLC SITE #: NC GU 0OX16 FIELD# : GU 0OX16 0001 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: CORONACA PERMIT #: W00035207 ANNUAL DRY TONS APPLIED: 94.55 OPERATOR: STEVE FIELDS CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 4.40 ACRES PERMITTED: 4.40 Page : 2 Lane Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and Win) Crop MONTH Total Per Acre Solids Total Gallons/Ac: Total Cubic Yds(Ac: 122.73 As Cd Cr - Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 0.225 0.086 5.514 1.492 0.328 0.017 0.220 0.533 0.253 1.839 64.59 205 Cumulative lbs/acre 0.225 0.086 5.514 1.492 0.328 0.017 0.220 0.533 0.253 1.839 (04 a 216 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop" FD Cumulative Pollutant Loading Rate Limit (]bs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 PTRWARLWPC = PIEDMONT TRIAD RWA, NC RANDLEMAN LAKE WTP CAKE X (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 FACILITY NAME: PIEDMONT TRIAD RWA NC OWNER: ROCKING FARM LLC SITE #: NC GU OOX16 FIELD# : GU OOX16 0002 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: CORONACA PERMIT #: W00035207. ANNUAL DRY TONS APPLIED: 16.59 OPERATOR: STEVE FIELDS CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 8.00 ACRES PERMITTED: 8.00 Page Lime Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppnl) Crop MONTH Total Per Acre Solids 1/31/14 11.00 (CY) 1.375 15.04 0.174 PTRWARL MOIST 0-<1/2" SUR 0.5 0.40 12,400. p 2,330.00 p 6.65 p 7 5200 FESCUE PASTURE Jan-14 11.00 (CY) 1.375 2/10/14 60.00 (CY) 7.500 15.04 0.950 PTRWARL MOIST 0-<1/2" SUR 0.5 0.40 12,400. p 2,330.00 p 6.65 p 5200 I FESCUE PASTURE 2/24/14 15.00 (CY) 1.875 15.04 0.238 PTRWARL MOIST 0-<1/2" SUR 0.5 0.40 12,400. p 2,330.00 p 6.65 p 5200 I FESCUE PASTURE t 2/28/14 45.00 (CY) 5.625 15.04 0.713 PTRWARL MOIST 0-<1/2" SUR 0.5 0.40 12,400. p 2,330.00 p 6.65 p 5200 FESCUE PASTURE Feb-14 120.00 (CY) 15.000 Total uunic Yos/AC: 16.38 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 0.029 0.008 0.693 0.075 0.021 0.002 0.025 0.033 0.021 0.141 6.02 22 Cumulative lbs/acre 0.029 0.008 0.693 0.075 0.021 0.002 0.025 0.033 0.021 0.141 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop 162 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 I 1339.0 267.9 15.0 375.0 89.0 2500.0 PTRWARLWPC = PIEDMONT TRIAD RWA, NC RANDLEMAN LAKE WTP CAKE X /Y� (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 FACILITY NAME: PIEDMONT TRIAD RWA, NC OWNER: ROCKING FARM LLC SITE #: NC GU 0OX16 FIELD# : GU 0OX16 0005 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: APPLING PERMIT #: W00035207 ANNUAL DRY TONS APPLIED: 50.78 OPERATOR: STEVE FIELDS CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 9.10 ACRES PERMITTED: 9.10 Page Lime Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (VM (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Acre Solids 6/6/14 15.00 (CY) 1.648 21.94 0.305 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 11,300. p 1,910.00 p 7.75 p 74719 I FESCUE 6/9/14 75.00 (CY) 8.242 21.94 1.523 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 11,300. p 1,910.00 p 7.75 p 4719 I FESCUE 6/10/14 15.00 (CY) 1.648 21.94 0.305 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 11,300. p 1,910.00 p 7.75 p 4719 FESCUE 6/13/14 60.00 (CY) 6.593 21.94 1.218 PTRWARL MOIST 0-<1/2" SUR 0.5 0.40 11,300. p 1,910.00 p 7.75 p 4719 FESCUE Jun-14 165.00 (CY) 18.131 6/16/14 74,400.00 (G) 8175.824 0.36 0.123 PTRWARL DRY 0-<I/2" SUR 0.5 0.40 19,400. p 2,780.00 p 167.00 p 8205 I FESCUE 6/17/14 136,400.00 (G) 14989.011 0.36 0.225 pTRWARL DRY 0-<1/2" SUR 0.5 0.40 19,400. p 2,780.00 p 167.00 p 8205 I FESCUE 6/18/14 68,200.00 (G) 7494.505 0.36 0.113 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 19,400. p 2,780.00 p 167.00 p 8205 I FESCUE 6/19/14 93,000.00 (G) 10219.780 0.36 0.153 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 19,400. p 2,780.00 p 167.00 p 8205 I FESCUE 6/23/14 86,800.00 (G) 9538.462 0.36 0.143 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 19,400. p 2,780.00 p 167.00 p 8205 I FESCUE 6/24/14 99,200.00 (G) 10901.099 0.36 0.164 PTRWARL DRY 0-<I/2" SUR 0.5 0.40 19,400. p 2,780.00 p 167.00 p 8205 I FESCUE 6/25/14 130,200.00 (G) 14307.692 0.36 0.215 PTRWARL DRY 0-<I/2" SUR 0.5 0.40 19,400. p 2,780.00 p 167.00 p 8205 I FESCUE 6/26/14 148,800.00 (G) 16351.648 0.36 0.245 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 19,400. p 2,780.00 p 167.00 p 8205 I FESCUE 6/27/14 142,600.00 (G) 15670.330 0.36 0.235 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 19,400. p 2,780.00 p 167.00 p 8205 I FESCUE 6/30/14 18,600.00 (G) 2043.956 0.36 0.031 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 19,400. p 2,780.00 p 167.00 p 8205 FESCUE Jun-14 998,200.00 (G) 109,692.307 7/1/14 173,600.00 (G) 19076.923 0.36 0.286 PTRWARL MOIST 0-<1/2" SUR 0.5 0.40 19,400. p 2,780.00 p 167.00 p 8205 FESCUE 7/2/14 155,000.00 (G) 17032.967 0.36 0.256 PTRWARL MOIST 0-<1/2" SUR 0.5 0.40 19,400. p 2,780.00 p 167.00 p 8205 FESCUE 7/3/14 24,800.00 (G) 2725.275 0.36 0.041 PTRWARL MOIST 0-<1/2" SUR 0.5 0.40 19,400. p 2,780.00 p 167.00 p 8205 FESCUE Jul-14 353,400.00 (G) 38,835.165 ANNUAL LAND APPLICATION FIELD SUMMARY FORM FACILITY NAME: PIEDMONT TRIAD RWA, NC PREDOMINANT SOIL SERIES: APPLING OWNER: ROCKING FARM LLC PERMIT #: W00035207 ANNUAL DRY TONS APPLIED: 50.78 SITE #: NC GU OOX16 FIELD# : GU OOX16 0005 OPERATOR: STEVE FIELDS CATION EXCHANGE CAPACITY (NON-503): RESIDUAL SOURCE(S):* See list at bottom of report ACRES UTILIZED: 9.10 ACRES PERMITTED: 9.10 Page: 2 Lime Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Acre Solids Total Gallons/Ac: 148,527.47 iumi %.,uuiu i uwr u. 1b.1J As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual Ibs/acre 68 0.060 0.022 0.980 0.489 0.076 0.004 0.056 0.136 0.067 0.460 16.05 Cumulative lbs/acre 0.060 0.022 0.980 0.489 0.076 0.004 0.056 0.136 0.067 0.460 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop 206 FD Cumulative Pollutant Loading Rate Limit (Ibs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 PTRWARLWPC = PIEDMONT TRIAD RWA, NC RANDLEMAN LAKE WTP CAKE PTRWARLWPL = PIEDMONT TRIAD RWA, NC RANDLEMAN LAKE WTP LIQUID x (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 ANNUAL LAND APPLICATION FIELD SUMMARY FORM FACILITY NAME: PIEDMONT TRIAD RWA, NC PREDOMINANT SOIL SERIES: APPLING OWNER: ROCKING FARM LLC PERMIT #: WQ0035207 ANNUAL DRY TONS APPLIED: 1.77 SITE #: NC GU OOX16 FIELD# : GU OOX16 0006 OPERATOR: STEVE FIELDS CATION EXCHANGE CAPACITY (NON-503): RESIDUAL SOURCE(S):* See list at bottom of report ACRES UTILIZED: 2.00 ACRES PERMITTED: 2.00 Page Lime Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppni) Crop MONTH Total Per Acre Solids 6/30/14 86,800.00 (G) , 43400.000 0.36 0.652 pTRWARL DRY 0-<1/2" SUR 0.5 0.40 19,400. p 2,780.00 p 167.00 p 78205 FESCUE Jun-14 86,800.00 (G) 43,400.000 7/3/14 12,400.00 (G) 6200.000 0.36 0.093 PTRWARL MOIST 0-<1/2" SUR 0.5 0.40 19,400. p 2,780.00 p 167.00 p 8205 I FESCUE 7/9/14 18,600.00 (G) 9300.000 0.36 0.140 PTRWARL MOIST 0-<1/2" SUR 0.5 0.40 19,400. p 2,780.00 p 1 167.00 p 8205 FESCUE Jul-14 31,000.00 (G) 15,500.000 1 Total Gallons/Ac: 58,900.00 1 Vl11 l.UU1U 1 Ub/ 1U. U.UU As Cd • Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 15 0.011 0.004 0.062 0.096' 0.009 <.001 0.009 0.019 0.011 0.065 2.35 Cumulative Ibs/acre 0.011 0.004 0.062 0.096 0.009 <.001 0.009 0.019 0.011 0.065 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop 206 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 PTRWARLWPL = PIEDMONT TRIAD RWA, NC RANDLEMAN LAKE WTP LIQUID (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR= Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 ANNUAL LAND APPLICATION FIELD SUMMARY FORM FACILITY NAME: PIEDMONT TRIAD RWA, NC PREDOMINANT SOIL SERIES: HELENA OWNER: ROCKING FARM LLC PERMIT #: W00035207 ANNUAL DRY TONS APPLIED: 4.00 SITE #: NC GU OOX16 FIELD# : GU OOX16 0007 OPERATOR: STEVE FIELDS CATION EXCHANGE CAPACITY (NON-503): RESIDUAL SOURCE(S):* See list at bottom of report ACRES UTILIZED: 6.90 ACRES PERMITTED: 6.90 Page Lime Applied *** Date Lbs/Ac DATE or allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Dry Tons per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppm) Crop MONTH Total Per Acre Solids 7/7/14 86,800.00 (G) 12579.710 0.36 0.189 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 19,400. p 2,780.00 p 167.00 p 8205 I FESCUE 7/8/14 179,800.00 (G) 26057.971 0.36 0.391 PTRWARL DRY ' 0-<1/2" SUR 0.5 0.40 19,400. p 2,780.00 p 167.00 p 8205 FESCUE Jul-14 1 266,600.00 (G) 38,637.681 1 Total Gallons/Ac: 38,637.68 i oiai uuoic z asf,-ic: U.uu As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 0.007 0.002 0.041 0.063 0.006 <.001 0.006 0.013 0.007 0.043 1.54 10 Cumulative Ibs/acre 0.007 0.002 0.041 0.063 0.006 <,001 0.006 0.013 0.007 0.043 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop :. : '. 216 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 PTRWARLWPL = PIEDMONT TRIAD RWA, NC RANDLEMAN LAKE WTP LIQUID X Ji 20 !s_ (SIGNATURE OF LAND APPLIER) • DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg * * Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 ANNUAL LAND APPLICATION FIELD SUMMARY FORM FACILITY NAME: PIEDMONT TRIAD RWA, NC PREDOMINANT SOIL SERIES: ENON OWNER: LEONARD ICEAN PERMIT #: WQ0035207 ANNUAL DRY TONS APPLIED: 8.13 SITE #: NC GU OOX19 FIELD# : GU 0OX19 0004 OPERATOR: STEVE FIELDS CATION EXCHANGE CAPACITY (NON-503): RESIDUAL SOURCE(S):* See list at bottom of report ACRES UTILIZED: 29.40 ACRES PERMITTED: 29.40 Page Lime Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppttt) Crop MONTH Total Per Acre Solids 6/13/14 44.00 (CY) 1.497 21.94 0.277 PTRWARL MOIST 0-<1/2" SUR 0.5 0.40 11,300. p 1,910.00 p 7.75 p 7 FESCUE Jun-14 1 44.00 (CY) 1.497 1 1 l vial I. UUI IUNAli. L.JU As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 3 0.003 0.001 0.068 0.020 0.004 <.001 0.003 0.007 0.003 0.024 0.84 Cumulative lbs/acre 0.003 0.001 0.068 0.020 0.004 <.001 0.003 0.007 0.003 0.024 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop 194 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) - 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 PTRWARLWPC = PIEDMONT TRIAD RWA, NC RANDLEMAN LAKE WTP CAKE X V*x/,0/1x_ 0��r (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required %= percent p = pp- or mg/kg ** Volatilization Rate: Surface 0.5, hijection/hicorporation 1.0 * Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 FACILITY NAME: PIEDMONT TRIAD RWA, NC OWNER: ROCKING FARM LLC SITE #: NC GU 0OX28 FIELD# : GU 0OX28 0001 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: CORORNCA PERMIT #: W00035207 ANNUAL DRY TONS APPLIED: 145.24 OPERATOR: STEVE FIELDS CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 39.80 ACRES PERMITTED: 39.80 Page Lime Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and Win) Crop MONTH Total Per Acre Solids 7/15/14 30.00 (CY) 0.754 14.53 0.092 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 13,400. p 2,270.00 p 8.95 p 5596 I FESCUE 7/17/14 90.00 (CY) 2.261 14.53 0.277 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 13,400. p 2,270.00 p 8.95 p 5596 I FESCUE 7/18/14 45.00 (CY) 1.131 14.53 0.138 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 13,400. p 2,270.00 p 8.95 p 5596 Ij FESCUE 7/29/14 75.00 (CY) 1.884 14.53 0.231 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 13,400. p 2,270.00 p 8.95 p 5596 FESCUE Jul-14 240.00 (CY)j 6.030 8/7/14 45.00 (CY) 1.131 14.53 0.138 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 13,400. p 2,270.00 p 8.95 p 5596 I FESCUE 8/15/14 75.00 (CY) 1.884 14.53 0.231 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 13,400. p 2,270.00 p 8.95 p 5596 I FESCUE 8/20/14 45.00 (CY) 1.131 14.53 0.138 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 13,400. p 2,270.00 p 8.95 p 5596 I FESCUE 8/21/14 90.00 (CY) 2.261 14.53 0.277 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 13,400. p 2,270.00 p 8.95 p 5596 I FESCUE 8/22/14 45.00 (CY) 1.131 14.53 0.138 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 13,400. p 2,270.00 p 8.95 p 5596 FESCUE Aug-14 300.00 (CY) 7.538 9/10/14 135.00 (CY) 3.392 14.53 0.415 PTRWARL DRY 0-<1/2" SUR I 0.5 0.40 13,400. p 2,270.00 p 8.95 p 5596 I FESCUE 9/18/14 45.00 (CY) 1.131 14.53 0.138 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 13,400. p 2,270.00 p 8.95 p 5596 FESCUE Sep-14 180.00 (CY) 4.523 10/6/14 30.00 (CY) 0.754 26.60 0.169 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 8,830.0-p 3,800.00 p 2.00 p 3914 I FESCUE 10/7/14 90.00 (CY) 2.261 26.60 0.507 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 8,830.0,p 3,800.00 p 2.00 p 3914 I FESCUE 10/27/14 30.00 (CY) 0.754 26.60 0.169 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 8,830.0,p 3,800.00 p 2.00 p 3114 FESCUE Oct-14 150.00 (CY) 3.769 11/10/14 75.00 (CY) 1.884 26.60 0.422 PTRWARL MOIST 0-<1/2" SUR 0.5 0.40 8,830.0 p 3,800.00 p 2.00 p 3914 I FESCUE 11/12/14 30.00 (CY) 0.754 1 26.60 0.169 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 8,830.0-p 3,800.00 p 2.00 p 3914 FESCUE Nov-14 105.00 (CY) 1 2.638 FACILITY NAME: PIEDMONT TRIAD RWA, NC OWNER: ROCKING FARM LLC SITE #: NC GU OOX28 FIELD# : GU OOX28 0001 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: CORORNCA PERMIT #: W00035207 ANNUAL DRY TONS APPLIED: 145.24 OPERATOR: STEVE FIELDS CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 39.80 ACRES PERMITTED: 39.80 Page : 2 Lune Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) Tons Cond. Precip. cation till- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Acre Solids lotal Cubic Yds/Ac: 24.50 As Cd Cr Cu Pb Hg - Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 0.041 0.020 0.321 0.838 0.111 0.003 0.068 0.094 0.036 0.368 9.74 36 Cumulative Ibs/acre 0.041 0.020 0.321 0.838 1 0.111 0.003 0.068 0.094 0.036 0.368 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop 216 FD Cumulative Pollutant Loading Rate Limit (Ibs/acre) 36.6 34.8 x 1339.0 267.9 15.0 375.0 89.0 2500.0 V. PTRWARLWPC = PIEDMONT TRIAD RWA, NC RANDLEMAN LAKE WTP CAKE x �A/�N- U�(��rS' (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = pp- or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ -Injection, SURIN - Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 FACILITY NAME: PIEDMONT TRIAD RWA, NC OWNER: JOHN LAMB SITE #: NC RD 00OX6 FIELD# : RD 00OX6 0001 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: WYNOTT-ENON PERMIT #: W00035207 ANNUAL DRY TONS APPLIED: 4.93 OPERATOR: JOHN LAMB CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 16.50 ACRES PERMITTED: 16.50 Page Line Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Acre Solids 11/20/14 22.00 (CY) 1.333 1 26.60 0.299 PTRWARL MOIST 0-<1/2" SUR 0.5 0.40 8,830.0 p 3,800.00 p 2.00 p 3914 FESCUE Nov-14 1 22.00 (CY) 1.333 Total Cubic Yds/Ac: 1.33 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: 2 Annuallbs/acre 0.003 0.002 0.018 0.017 0.019 <.001 0.010 0.007 0.003 0.041 0.53 Cumulative Ibs/acre 0.003 0.002 0.018 0.017 0.019 <.001 0.010 0.007 0.003 0.041 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop 146 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 PTRWARLWPC = PIEDMONT TRIAD RWA, NC RANDLEMAN LAKE WTP CAKE X A�& (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate : Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 FACILITY NAME: PIEDMONT TRIAD RWA, NC OWNER: W. HOWARD FIELDS SITE #: NC RD OOX18 FIELD# : RD OOX18 0002 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: BADIN-TARRUS PERMIT #: WQ0035207 ANNUAL DRY TONS APPLIED: 94.24 OPERATOR: W. HOWARD FIELDS CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 8.80 ACRES PERMITTED: 8.80 Page : 1 Lime Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Acre Solids 4/24/14 105.00 (CY) 11.932 21.94 2.205 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 11,300. p 1,910.00 p 7.75 p 4719 I FESCUE 4/25/14 60.00 (CY) 6.818 21.94 1.260 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 11,300. p 1,910.00 p 7.75 p 4719 I FESCUE 4/28/14 75.00 (CY) 8.523 21.94 1.575 PTRWARL MOIST 0-<1/2" SUR 0.5 0.40 11,300. p 1,910.00 p 7.75 p 4719 FESCUE Apr-14 240.00 (CY) 27.273 5/9/14 90.00 (CY) 10.227 21.94 1.890 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 11,300. p 1,910.00 p 7.75 p 4719 I FESCUE 5/12/14 90.00 (CY) 10.227 21.94 1.890 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 11,300. p 1,910.00 p 7.75 p 4719 I FESCUE 5/13/14 90.00 (CY) 10.227 21.94 1.890 PTRWARL DRY 0-<1/2" SUR 0.5 0.40 11,300. p 1,910.00 p 7.75 p 4719 FESCUE May-14 270.00 (CY) 30.681 1 1-.1 L..0 . -1. J / y' As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual Ibs/acre 101 0.107 0.043 2.634 0.792 0.171 0.009 0.107 0.278 0.129 0.942 32.34 Cumulative Ibs/acre 0.107 0.043 2.634 0.792 0.171 0.009 0.107 0.278 0.129 0.942 „.„ Permit PAN Limit (]bs/acre) 1st Crop/2nd Crop 77 P 150 *�' F FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 1 375.0 89.0 2500.0 74 i PTRWARLWPC = PIEDMONT TRIAD RWA, NC RANDLEMAN LAKE WTP CAKE (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 Summit Environmental Technologies, Inc. I god 11 3310 Win St. FHk?lFfQNb1ENTALTFCI OLty(71L:5,INQ Cuyahoga Falls, Ohio44223 ;aal�%izea4l r � t�#FPS. TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: htto://wivw.settek.com January 16, 2014 James Blackwell Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: (336) 998-7150 FAX: (336) 998-8450 RE: Piedmont Triad RWA Dear James Blackwell: Order No.: 14010511 Summit Environmental Technologies, Inc. received 1 sample(s) on 1/10/2014 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, V� Dr. Mo Osman Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 A2LA 0724.01, Alabama 41600, Arkansas 88-0735, California 07256CA, Colorado, Connecticut PH-0105, Delaware, Florida NELAC E87688, Georgia E87688 and 943, Idaho OH00923, Illinois 200061 and Reg.5, Indiana C-01-1-13, Kansas E-10347, Kentucky (underground Storage Tank) 3, Kentucky 90146, Louisiana 04061 and LA12004, Maine 2012015, Maryland 339, Massachusetts M-OPH923, Minnesota 409711, Montana CERT0099, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, Ohio 4170, Ohio VAP CL0052, Oklahoma 9940, Oregon 01-12O0001, Pennsylvania 68-01335, Rhode Island LA000317, South Carolina 92016001, Tennessee TN04018, Texas T104704466-11-5, Region 8 8TMS- L, USDA/APH1S P330-11-00244, Utah OH009232011-1, Vermont VT-87688, Virginia 00440 and 1581, Washington C891, West Virginia 248 and 9957C and E87688, Wisconsin 399013010 Page 1 of 7 ,q Summit Environmental Technologies, Inc. Workorder 1 3310 Win St. l fvrVIRCS3dP�1EA1'Y1iL P 31CdgCt3G1 , KC, Cuyahoga Falls, Ohio 44223 Sample Summary t2 xaij+ti:"Z r,4bO 'ON605' TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 14010511 Website: hQ.-11ivww.settek.com 17-Jan-14 CLIENT: Synagro Project: Piedmont Triad RWA Lab SampleID Client Sample ID Tag No Date Collected Date Received Matrix 14010511-001 Piedmont Triad RWA 1/7/2014 12:20:00 PM 1/10/2014 9:52:00 AM Sludge Page 2 of 7 Summit Environmental Technologies, Inc. q , 3310 Win St. Case Narrative FINViF?C7.INN. Cuyahoga Falls, Ohio 44223 WO#• 14010511 tI'ara?,rn:�aa' L'a h€ar�pe�t TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: htto://wwiv.settek.com Date: 1/16/2014 CLIENT: Synagro Project: Piedmont Triad RWA This report in its entirety consists of the documents listed below. All documents contain the Summit Environmental Technologies, Inc. Work Order Number assigned to this report. Paginated Report including: Cover Letter, Case Narrative, Analytical Results, Applicable Quality Control Summary Reports and copies of the Chain of Custody Documents supplied with this sample set. Concentrations reported with a J flag in the Qual field are values below the Limit of Quantitation (LOQ) but greater than the established Limit of Detection (LOD). There is greater uncertainty associated with these results and data should be considered as estimated. Method numbers, unless specified as SM (Standard Methods) or ASTM, are EPA methods.. . Estimated uncertainty values are available upon request. Any comments or problems with the analytical events associated with this report are noted below. Revision v1 Page 3 of 7 t Summit Enrit omnental Technologies, Inc. ,�� 3310 Win St. C+yVIRC54dFatEDJi'L. S`i tiPdC7li Sp9Me; Cuyahoga Falls, Ohio 44223 M ,i'm3g;t[da C:�C�"ora flpj TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: htta://wiviv.settekcom WO#: 14010511 Date Reported: 1/16/2014 Company: Synagro Address: 284 Boger Rd. Mocksville NC 27028 Received: 1/10/2014 Project#: Piedmont Triad TCLP Metals Analysis (6010) Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Piedmont Triad RWA 001 1/7/2014 TCLP Arsenic(As) 0.50 ND mg/L Sludge EPA 6010 C 1 5.0 1/15/2014 WK Piedmont Triad RWA 001 1/7/2014 TCLP Barium(Ba) 5.0 ND mg/L Sludge EPA 6010 C 1 100 1/15/2014 WK Piedmont Triad RWA 001 1/7/2014 TCLP Cadmium(Cd) 0.10 ND mg/L Sludge EPA 6010 C 1 1.0 1/15/2014 WK Piedmont Triad RWA 001 1/7/2014 TCLP Chromium(Cr) 0.20 ND mg/L Sludge EPA-6010 C 1 5.0 1/15/2014 WK Piedmont Triad RWA 001 1/7/2014 TCLP Lead(Pb) 0.50 ND mg/L Sludge EPA 6010 C 1 5.0 1/15/2014 WK Piedmont Triad RWA 001 1/7/2014 TCLP Selenium(Se) 0.50 ND mg/L Sludge EPA 6010 C 1 1.0 1/15/2014 WK Piedmont Triad RWA 001 1/7/2014 TCLP Silver(Ag) 0.50 ND mg/L Sludge EPA 6010 C 1 5.0 1/15/2014 WK TCLP Mercury Analysis (1311/7470) Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Piedmont Triad RWA 001 1/7/2014 TCLP Mercury 0.0020 ND mg/L Sludge EPA 7470 A 1 0.20 1/14/2014 ALJ SVOC SW-846: 8081-TCLP Pesticides Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Piedmont Triad RWA 001 1/7/2014 Chlordane, total 0.010 ND mg/L Sludge EPA 8081 B 1 0.030 1/15/2014 JBN Piedmont Triad RWA 001 1/7/2014 Toxaphene 0.10 ND mg/L Sludge EPA 8081 B 1 0.50 1/15/2014 JBN Piedmont Triad RWA 001 1/7/2014 Endrin 0.0020 ND mg/L Sludge EPA 8081 B 1 0.020 1/15/2014 JBN Piedmont Triad RWA 001 1/7/2014 gamma-BHC 0.0020 ND mg/L Sludge EPA 8081 B 1 0.40 1/15/2014 JBN Piedmont Triad RWA 001 1/7/2014 Heptachlor 0.0020 ND mg/L Sludge EPA 8081 B 1 0.0080 1/15/2014 JBN Piedmont Triad RWA 001 1/7/2014 Heptachlor epoxide 0.0020 ND mg/L Sludge EPA 8081 B 1 0.0080 1/15/2014 JBN Piedmont Triad RWA 001 1/7/2014 Methoxychlor 0.0020 ND mg/L Sludge EPA 8081 B 1 10 1/15/2014 JBN VOC by GC/MS (8260)-TCLP Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Piedmont Triad RWA 001 1/7/2014 1,1-Dichloroethene 0.10 ND mg/L Sludge EPA 8260 B 1 0.70 1/15/2014 MES Piedmont Triad RWA 001 1/7/2014 1,2-Dichloroethane 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 1/15/2014 MES Piedmont Triad RWA 001 1/7/2014 Benzene 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 1/15/2014 MES Piedmont Triad RWA 001 1/7/2014 Carbon tetrachloride 0.90 ND mg/L Sludge EPA 8260 B 1 0.50 1/15/2014 MES Piedmont Triad RWA 001 1/7/2014 Chlorobenzene 0.10 ND mg/L Sludge EPA 8260 B 1 100 1/15/2014 MES Piedmont Triad RWA 001 1/7/2014 Chloroform 0.10 ND mg/L Sludge EPA 8260 B 1 6.0 1/15/2014 MES Piedmont Triad RWA 001 1/7/2014 Tetrachloroethene 0.10 ND mg/L Sludge EPA 8260 B 1 0.70 1/15/2014 MES Piedmont Triad RWA 001 1/7/2014 Trichloroethene 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 1/15/2014 MES Piedmont Triad RWA 001 1/7/2014 Vinyl chloride 0.20 ND mg/L Sludge EPA 8260 B 1 0.20 1/15/2014 MES Piedmont Triad RWA 001 1/7/2014 MEK 2.0 ND mg/L Sludge EPA 8260 B 1 200 1/15/2014 MES Page 4 of 7 ffizuAmfin'll SunnnitEnvironmental Technologies, Inc. WO#: 14010511 3310 Win St. FtAhIRON1,1 41TAL TECHNI t1�A�5,.sptc Cuyahoga Falls, Ohio 44223 Date Reported: 1/16/2014 Arraf rMeal TEL: (330) 253-8211 FAX.- (330) 253-4489 Company: Synagro Website: htto://ivwiv.settek.com Address: 284 Boger Rd. Mocksville NC 27028 Received: 1/10/2014 Project#: Piedmont Triad SVOC 8270 TCLP BNA List Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Piedmont Triad RWA 001 1/7/2014 1,4-Dichlorobenzene 0.10 ND mg/L Sludge EPA 8270 C 1 7.5 1/14/2014 AKE Piedmont Triad RWA 001 1/7/2014 2,4,5-Trichlorophenol 0.25 ND mg/L Sludge EPA 8270 C 1 400 .1/14/2014 AKE Piedmont Triad RWA 001 1/7/2014 2,4,6-Trichlorophenol 0.25 ND mg/L Sludge EPA 8270 C 1 2.0 1/14/2014 AKE Piedmont Triad RWA 001 1/7/2014 2,4-Dinitrotoluene 0.10 ND mg/L Sludge EPA 8270 C 1 0.13 1/14/2014 AKE Piedmont Triad RWA 001 1/7/2014 Cresols, Total 5.0 ND mg/L Sludge EPA 8270 C 1 200 1/14/2014 AKE Piedmont Triad RWA 001 1/7/2014 Hexachloro-1,3- 0.10 ND mg/L Sludge EPA 8270 C 1 0.50 1/14/2014 AKE butadiene Piedmont Triad RWA 001 1/7/2014 Hexachlorobenzene 0.10 ND mg/L Sludge EPA 8270 C 1 0.13 1/14/2014 AKE Piedmont Triad RWA 001 1/7/2014 Hexachloroethane 0.10 ND mg/L Sludge EPA 8270 C 1 3.0 1/14/2014 AKE Piedmont Triad RWA 001 1/7/2014 Nitrobenzene 0.10 ND mg/L Sludge EPA 8270 C 1 2.0 1/14/2014 AKE Piedmont Triad RWA 001 1/7/2014 Pentachlorophenol 0.25 ND mg/L Sludge EPA 8270 C 1 100 1/14/2014 AKE Piedmont Triad RWA 001 1/7/2014 Pyridine 0.25 ND mg/L Sludge EPA 8270 C 1 5.0 1/14/2014 AKE SVOC SW-846: 8321 Herbicides-TCLP Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Piedmont Triad RWA 001 1/7/2014 2,4-D 5.0 ND mg/L Sludge EPA 8321 A 1 10 1/14/2014 AMZ Piedmont Triad RWA 001 1/7/2014 2,4,5-TP 0.50 ND mg/L Sludge EPA 8321 A 1 1.0 1/14/2014 AMZ Page 5 of 7 Summit Environmental Technologies, Inc. 3310 Win St. WO#: 14010511 i�. t P6VIRtJttFatt? rml- S'c^�31a�1 L0: �9,.➢TBt, Cuyahoga Falls, Ohio 44223 Date Reported: 1/16/2014 AnH,, Ne-,3( L.,91'7arzTo e TEL: (330) 253-8211 FAX.- (330) 253-4489 Company: Synagro Website: htto://wwiv.settek.com Address: 284 Boger Rd. Mocksville NC 27028 Received: 1/10/2014 Project#: Piedmont Triad Client ID# Lab ID# Collected Analyte Result Units Matrix Method DF RL Run Analyst Piedmont Triad RWA 001 1/7/2014 Flashpoint (140°F) >140 °F Piedmont Triad RWA 001 1/7/2014 Cyanide, Reactive ND ppm Piedmont Triad RWA 001 1/7/2014 pH 6.6 s.u. Piedmont Triad RWA 001 1/7/2014 Sulfide, Reactive ND ppm Sludge EPA 1010 1 1/13/2014 TAH Sludge EPA 9014 1 0.50 1/13/2014 TIR Sludge EPA 9045 D 1 1/13/2014 AYS Sludge EPA 9034 1 25 1/13/2014 TIR Page 6 of 7 Summit Envirop.mental Technologies, lnc. Analysis Request/Cbain of Custody -1310 Win Street F6,- Summit Environmental Teclinolog , ics. Inc. use only )2' Tel: 3? - �3..821 pa-e-of- I SET. No. Cuyahoga Fall, Ohio 442 1 50.25 1 Fax: 330.253.4489� Ct)mpanName (PICUSPr L Name Analytical -Parameter and Mcthod& y e O-Pfint) P A C'umpanv P-ddres. , Client Phona'No, Rcp6a to eA,,k%—q-rn— Client Fax.No- P` 156 r Zv6o.,, rii,w Fmaii il QitulcltA Sani pliAdeilti.110tiOn Received in 1.111) S. 4- vAj- —sumples,/" Dto Collecied COMM U Z-- hc 1,S" b --)I Rush PlcquLMcd BY: *, Rdi m an,,Wcr tTttc jj;jas to ihe laboratoi dic pink pa-uc, j ,4 5-6 ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: WWTP Name: Piedmont Triad RWA Randleman Lake WTP Monitoring Period: From 01/01/14 To 03/31/14 WQ Permit Number: WQ 0035207 NPDES Number: NC 0087866 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2/13 (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/1) (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion If annlicable to alternative nerformed (Class A or Class Bl comnlete the following, monitoring, data: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dences Analysis Fecal 2x10 to the 6 1h MPN MPN/g Coliform power per gram of total solids CFU 69 72 77 CFU/g 0 4/yr Grab 9222D 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: 0 tion/Alt. 1 Option/Alt.2 Option/Alt.3 Option/Alt.4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed X CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisomnent." i^ rPT FIrwrlE eak 're -A r PreparL4 N me and Titl type or print) Land Applier Name and Title (if applicable) (type or print) 44 A. 5�;/k a-Za--f Sigma of Preparer* # Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Meritech, Inc. Environmental Laboratory Laboratory Certification No.165 Contact: James Blackwell Report Date 1/10/2014 Client: Synagro 284 Boger Road Mocksville, NC 27028 Date Sample Rcvd: 1/7/2014 Meritech Work Order # 01071464 Sample: Piedmont Triad RWA Grab 1/7/14 Parameters Results Analysis Date Reporting Limit Method Qualifler % Total Solids 14.4 % 1/8/14 0-100 % SM 2540B Fecal Coliform (Sludge) < 69 col/g dry wt 1/7/14 463 col/g dry wt SM 9222D B2 Meritech Work Order # 01071465 Sample: Piedmont Triad RWA Grab 1/7/14 Parameters Results Analysis Date Reporting Limit Mpth Qualifler % Total Solids 13.0 % 1/8/14 0-100 % SM 2540B Fecal Coliform (Sludge) < 77 col/g dry wt 1/7/14 397 col/g dry wt SM 9222D B2 Meritech Work Order # 01071466 Sample: Piedmont Triad RWA Grab 1/7/14 Parameters Re ultA AnalysiN Date Reporting Limit Method Qualifler % Total Solids 14.1 % 1/8/14 0-100. % SM 2540B Fecal Coliform CSludge) < 71 col/g dry wt 1/7/14 518 col/g dry wt SM 9222D B2 Bz Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been reported if there had been one colony on the filter representing the largest filtration volume (reported as a less than "<" value). _ I hereby certify that I have reviewed and approve these data. Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1S22 Chain of Custody Record (COC) Client: N NPDES# Phone: Fax: MER/ TECH, INC. ENVIRONMENTAL LABORATORIES * A Division of Water Technology and Controls, Inc. Phone: 1-336-342-4748 642 Tamco Rd. Fax: 1-336-342-1522 Reidsville, NC 27320 Email: srmrtech@bellsouth.net w� Web Site: w .meritech-labs.com Address: ��� ��� a,v y g�'i 1 j f �\ Attention: 7!y-'K t�\A cK-'J'' Email: Project# P o. # Turn Around Time" *RUSH work must have prior approval. Slid (10 days) 0 3 - 5 Day C] 24 - 48 Hr le Location/ID # Sampling Dates & Times Person Sam le Si nature : Required Method Lab UseSam only START END Comp? Grab? #of Conts. Tests Required 200.8/200.7 pH OK? ? Date Time Date Time `'fir i �S. P � � � .."I - \�{ '1 \'• � � n,,. � A � � � L� 1 (n, , 1 ar^'� lQ Compositor # Jug # ***Dechlorination (<0.5 ppm) of Ammonia, Cyanide, Phenol or TKN samples must be done in the field prior to preservation.*** Comments: Method of Shipment: ❑ UPS ❑ Fed Ex H�. and Delive ry ❑ Other Are these results for regulatory purposes? YES NO ❑ Report results in mg/L ❑ mg/Kg ❑ µg/L Q On Ice? Temperature On Receipt /r Re' wish by Date Time �50 Received by Date Time Relin fished by Daie Time Received by Date Time ,, Relinquished by Dale Time ceiv it by D to ` � ,. -7 " � t ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: WWTP Name: Monitoring Period; Piedmont Triad RWA Randleman Lake WTP From 4/01/14 To 06/30/14 WQ Permit Number: WQ 0035207 NPDES Number: NC 0087866 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2/13 (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/1) (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion If apolicable to alternative nerformed (Class A or Class B) comnlete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dences Analysis Fecal 2x10to the 6t MPN CFU/g Coliform power per gram of total solids CFU 58 CFU/g 0 4/yr Grab 9222 D 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: Option/Alt. l Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed X CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC-02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." r a t< "r Ur' Preparer Na e And Title type or print) Land Applier Name and Title (if applicable) (type or print) SignatLYeqf Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Meritech, Inc. Environmental Laboratory laboratory Certification No.165 Contact: Marshall Puryear Report Date 4/29/2014 Client: Synagro Project: Piedmont Triad 284 Boger Road Mocksville, NC 27028 Date Sample Rcvd: 4/24/2014 Meritech Work Order # 04241401 Sample: Plant/Piedmont Triad Grab 4/23/14 Parameters Results Analysis Date Reporting limit Method %Total Solids 15.5 % 4/25/14 0-100-% SM 2540B Fecal Coliform (Sludge) < 58 col/g dry wt 4/24/14 130 col/g dry wt SM 9222D I hereby certify that I have reviewed and approve these data. Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 Chain of Custody Record (COC) NPDES#: Client: 1,® Phone:,-- �` �Do Z Address. eZ A Fax: ® U -e ;Zw702 y Email: Project: ! ,0 ,0(/-r its J VA. V 1964 4ajL6 P.O.#: Attention: Turn Around Time* How would you like your report sent? "RUSH work needs prior approval. Circle all that apply: mail (preferred) Fax, Mail Std 10 days 3 - 5�Days 24�48 Hirs ® ENVIRONMENTAL LABORATORIES 642TamcoRd. Phone: 336-342-4748 r, w Reidsville NC 27320 Fax: 336-342-1522 Email: info@meritech-labs.com www, m e rite e h—"I a bs . c ®ill Sample Location and/or ID # .Sampling Dates & Tomes Person Taking Sample (Sign/Print): Lab..Use-Ohly t°. Start —D—ate-7. End Comp? Grab? #of Cont. Test(s) Required �.:. on ice.....pH Yes /: No: OK. ..'CI:OK?: Time Date Time Temperature. Upon. :Receipt.-:'' Method of Shipment: Dechlorination (<O.5 ppm) of Ammonia, Cyanide, Phenol and TKN samples must be done in the field prior to preservation. *** Comments: Compositor#.::::..:: ' []: UPS Jug # Fed Ex Are th a Its ` r regulatory purposes? Yes .r' No Cl Report results in: mg/L mg/kg (�.�'" ug/L nnQi! Hand Delivery Relinquished b Dat : e Received by: Date: Time: Z.1 Other Relinquished by: Date: Time: Received by: Date Time: Relinquished by: Date: Time: Recen,tC" Tipie- ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: WWTP Name: Monitoring Period Piedmont Triad RWA Randleman Lake WTP From 07/01/14 To 09/30/14 WQ Permit Number: WQ 0035207 NPDES Number: NC 0087866 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2/13 (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion If nnnlirnhle to alternative nerfnrmed (Iris A nr Class Rl rmmnlete the follnwinu mnnitorinu data: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units deuces Analysis Fecal 2x10 to the 6` MPN MPN/g Coliform power per gram of total solids CFU 51 CFU/g 0 4/yr Grab 9222 D 1000 MPN per gram of total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: Option/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Mt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Mt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed X CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR:503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) - "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." ISrettnr-j T Flora z Ex2c bye. 1a;re-Jbr PrepPrep nrera name And Title (p •int or type) Land Applier Name and Title (if applicable) (type or print) 4 Signa of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Meiritech, Incur Environmental Laboratory Laboratory Certification No.165 Contact: Marshall Puryear Report Date 7/14/2014 Client: Synagro 284 Boger Road Mocksville, NC 27028 Date Sample Rcvd; 7/7/2014 Meritech Work Order # 07071421 Sample: Piedmont Triad WTP Grab 7/7/14 Parameters esults Analysis Date Reporting Lim! Method Total Solids 19.6 % 7/8/14 0-100 % SM 2540B Fecal Coliform (Sludge) < 51 col/g dry wt. 7/7/14 51 col/g dry wt SM 9222D I hereby certify that I have reviewed and approve these data, aboratory Representative 642 Tainco Road, Reidsville, North Carolina 27320 tei.(336)342-4748 fax.(336)342-1522 3-20-2023 Chain of Custody Record (COC) NPDES#: Client: �M K4 �, +� Phone: ���� � MERAddress: ® Ro<.w FFax: j= ENVIRONMENTAL LABORATORIES !�'l c��l�sv,'���, �C 9762!1� Email: 642 TamcoRd. Phone: 336-3424748 Project: Reidsville NC 27320 Fax: 336-342-1522 P.O.#: Email: info@meritech-labs.com Turn Attention: Sim ( �v �� — works needsund `RUSH work needs prior approval. How would you like our report sent? �{-j p,_, WWWa erIIech—ioll s-com Std Circle all that apply: Email (preferred), ax, Mai{ loda } 3-5 Das as -aaHrs Dates & Times PersanTakings Veign/Pr ): a � �syw-� Lab Use Only .Sampling + Sample Location and/or ID # Start End Comp. ? #of �` fl � est(s) Required on Ice? Y� / NO pH OK? C{ OK? Date Jime Date Time Grab? Cont. W i I ��? %�f �1 aS� 71 ll, a .,.r. C-ub f lEEE '71-74Y Z 7 !Y bortt, % l q 1 ,, 4 rf: J ,r 7 } :13Arw7 ZJV1'! 14 A = l7a l0 c r� t /K �5�. ��r yam, c� C. l �- ��� l C.J C-111r) Temperature Upon f ,ill Receipt: Method of *** Dechlorination (<0.5 ppm) of Ammonia, Cyanide, Phenol and TKN samples must be done in the field priorto preservation. "** Compositor # Comments: Shipment: lug # f UPS Fed Ex Are t s results for regulatory purposes? Yes Q. No Report results in: mg/L Q. mg/kg ug/L 0' Relinquished by Date: Time: Received by: Date: P"Hand Delivery c..f Time: Relinquished VDate: [Zil' Other Time: Received by: Date: Time; Relinquished by: Date: Time: Received by La Da l Time: ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: WWTP Name: _ Monitoring Period Piedmont Triad RWA Randleman Lake WTP From 10/01/14 To 12/31/14 WQ Permit Number: WQ 0035207 NPDES Number: NC 0087866 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2/13 (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion Ile ..I:.. M� +n nl+aron+:o rf vma.l !f In e A nr (90 a Rl O T1a+a +ha fnif—ina mnnifnrina dnta- Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dences Analysis Fecal 2x10to the 6` MPN MPN/g Coliform power per gram of total solids 40 CFU/g 0 4/yr Grab 9222D CFU 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: Option/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed X CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement 1n 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Ron, Fxecu ve Der-eJDt— Preparer Na e and Titlef Land Applier Name and Title (if applicable) (type or print) Signaf6gof Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Meritech, Inc® .: Environmental Laboratory. . Laboratory Certification No.165 .....-mom::..:..... . Contact: Marshall Puryear Report Date 10/28/2014 Client: Synagro 284 Boger Road Mocksville, NC 27028 Date Sample Rcvd: 10/17/2014 Meritech Work Order 4 10171435 Sample: Piedmont Triad Water Grab 10/17/14' Parameters Results Analysis Date Reporting Limit Method %Total Solids . 25.1 % 10/20/14 0-100 % SM 2540B Fecal Coliform (Sludge) < 40 col/g dry wt 10/17/14 40 col/g dry wt SM 9222D . hereby certify that I have reviewed and approve these data. t a Laboratoiy Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342.4748 fax.(336)342-152Z. 3-20-2013 Chain of Custody Record (COC) NPDES#: Client: -57iAA - A0 Phone: Address: Fax: Email: Project: P.O.#: Attention: Turn Around Time* How would:you I:ike your report sent? *RUSH work needs prior approval. Std lOda s) 3-5 Davs, 24-48Hrs Circle all that apply: Email(preferred), Fax, Mail ' ® MERITRCM. INC ENVIRONMENTAL LABORATORIES - ' 542 Tamco.Rd. Phone: 336-3424748 Reidsville NC 27320 Fax: 336-342-1522 Email: info@meritech-labs.com 0�,� �"�. ` erlte h—labs.c® Sample Location and/or ID # ��� ��� ®���S�CT6PB]�S ''Person Sampling Taking Sample (Sign/Print): Lab Use ®Silly Start End Comp. Grab? .. n of Cont. ��5t5 l Re �.ed , On Ice. Yes / No � pH OK. CI OK? Date Time Date Time e I Temperature Upon Receipt:. Method of:: 1 *** Dechlorination (<0.5 ppm) of Ammonia, Cyanide, Phenol and TKN samples must be done in the field prior to preservation. Comments: Shipment: UPS Compositor # Ju # g Fed Ex Are these results for regulatory purposes? Yes No ED R.e port results in: mg/L mg/kg ug/L f Relinquished by: Date: Time: QHand Delivery Received by: Date: Time: UOther iRelinqu:shed by: Dare: Time: d relinquished by: Date: Time: iRec Received by: Date: Time: ived by : � , D t "I