WQ0034397_2014 Residual Annual Report_20150223

r7
Murphy -Brown LLC PO Drawer 856
2822 Hwy. 24 West
Warsaw, NC 28398
Tel: [phone]
Fax: [phone]
February 16, 2015
North Carolina Department of Environment and Natural Resources
Division of Water Quality
Aquifer Protection Section
Land Application Unit
1636 Mail Service Center
Raleigh, NC 2769901636
To Whom It May Concern:
Enclosed you will find the 2014 Annual Reporting Forms as required by Permit
WQ0034397 (Murphy -Brown Bladen/Scotland Residuals Program). The attachments are
submitted in the following order:
FORM ACF
FORM RSSF
FORM MFLSF
FORM FSF
LAB SHEETS
FIELD SOIL TESTS
Murphy -Brown did not conducted land application on seven occasions in 2014.
Residuals produced and tested at the Tarheel TW facility were land applied to AMMONI and
AMMON2 residual sites on one occasion. In addition stormwater residuals produced at the
Warsaw Feed Mill were land applied to sites DUPBOARI-3 on six occasions. All applications
were done under the supervision of Mr. Eric Smith.
Please feel free to contact me for both Permittee and preparer inquiries at
kraigwesterbeekgmurphybrownllc.com or [phone].
TAsst.,
C 1A1
beek R�uMVEDIDENOWR
S Co ce . FEB 23 2015
waftTQualey
pertwal sedon

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit#: WQ0034397 County: Bladen/Scotland Year: 2014
Facility Name (as shown on permit): Murphy -Brown Bladen/Scotland Residuals Progam
Land Application Operator: Murphy -Brown LLC Phone: [phone]
Land application of residuals as allowed by the permit occurred during the past calendar year?
❑ Yes ❑ No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A - Residuals Application Summary:
Total number of application fields in thepermit:
1 9
Total number of fields utilized for land application during the year:
5
Total amount of dry tons applied during the year for all application sites:
16.31
Total number of acres utilizes for land'application during the year:
1 28.3
Part B - Annual Compiance Statement:
Facility was compliant during calendar year 2014 with all conditions of the land application permit
(including but not limited to items 1-13 below) issued by the Division of Water Resources. Yes ❑ No
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action
taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the
limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies
of laboratory results are attached.
4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant
Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part
503 regulated facilities).
8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503
regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Resources.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as specified
in the permit.
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13) All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Kira; cs�a�c&(L
Permitte Name and Title (type or print) ignature of Permittee Date
Signature of Preparer* Date Signature of Land App ier Date
(if different from Permittee) (if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number: WQ0034397
Facility Name:
White Oak TW
Residual Source WQ # or WQ0011360
NPDES #:
WWTP Name:
112acirinal Analvcic Dnta
Laboratory: 1) envirochem
2)
3)
4)
5)
Parameter
(mg/kg)
Conc.
Limit
m a
Sample or Composite Date
12/29/14
Percent Solids (%)
NA
40.8
Arsenic
75
3.58
Cadmium
85
<0.585
Copper
4,300
480
Chromium
NA
2.96
Lead
840
2.1
Mercury
57
<.002
Molybdenum
75
2.64
Nickel
420
2.94
Selenium
100
2.36
Zinc
7,500
673
Total Phosphorus
NA
774
TKN
NA
941
Ammonia -Nitrogen
NA
64.6
Nitrate and Nitrite
NA
5140
a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with.a system designed
to assure that qualified personn"operly gathered and evaluated the information submitted. I am aware that there are significant
penaltfor subm.'ttin ation, including the possibility of fines and imprisonment for knowing violations."
SYdnature of P eparer * Date
is dtfined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM RSSF. (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional'parameters to be analyzed. The parameters can be reported in FORM RSSF -1I
WQ Permit Number: WQ0034397
Facility Name:
Residual Source WQ # or
NPDES #:
WWTP Name:
Recirinal Analvcic Data
Tarheel TW
WQ0011360
Laboratory: 1) envirochem
2)
3)
4)
5)
Parameter
(mg/kg)
Conc.
Limit
m /k a
Sample or Composite Date
12/29/ 14
Percent Solids (%)
NA
38.5
Arsenic
75
3.4
Cadmium
85
<.576
Copper
4,300
395
Chromium
NA
1.89
Lead
840
0.761
Mercury
57
<.002
Molybdenum
75
2.3
Nickel
420
2.7
Selenium
100
2.44
Zinc
7,500
556
Total Phosphorus
NA
3670
TKN
NA
820
Ammonia -Nitrogen
NA
74.1
Nitrate and Nitrite
NA
6090
a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law,. that this document was prepared under my direction or supervision in accordance with a system designed
to assurepat t qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
pen ' s for subs' g false information, including the possibility of fines and imprisonment for knowing violations."
Si ature of Preparer * Date
is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number: WQ0034397
Facility Name: Laurinburg TW
Residual Source WQ # or WQ0030190
NPDES #:
WWTP Name:
Dociflnal Analveie nota
Laboratory:
1)
2)
3)
4)
5)
envirochem
Parameter
(mg/kg)
Conc.
Limit
m a
Sample or Composite Date
12/29/14
Percent Solids (%)
NA
34.1
Arsenic
75
0.733
Cadmium
85
0.733
Copper
4,300
26.7
Chromium
NA
1.36
Lead
840
0.733
Mercury
57
<.002
Molybdenum
75
0.874
Nickel
420
0.733
Selenium
100
1.44
Zinc
7,500
346
Total Phosphorus
NA
606
TKN
NA
271
Ammonia -Nitrogen
NA
0.587
Nitrate and Nitrite
NA
16.7
a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for bmi g alse information including the possibility of fines and imprisonment for knowing violations."
f6 s
Signs a of Preparer * Date
is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number: WQ0034397
Facility Name: Warsaw Mill Stormwater residuals
Residual Source WQ # or NC060209
NPDES #:
WWTP Name:
Residual Analysis Data
Laboratory: 1) envirochem
2)
3)
4)
5)
Parameter
(mg/kg)
Conc.
Limit
m a
Sample or Composite Date
12/29/14
Percent Solids (%)
NA
0.1
Arsenic
75
<10
Cadmium
85
<10
Copper
4,300
17
Chromium
NA
<10
Lead
840
<10
Mercury
57
<.200
Molybdenum
75
<10
Nickel
420
13
Selenium
100
<10
Zinc
7,500
44
Total Phosphorus
NA
2330
TKN
NA
8740
Ammonia -Nitrogen
NA
344
Nitrate and Nitrite
NA
6210
a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared. under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penaltulp&or submitting false information, including the possibility of fines and imprisonment for knowing violations."
of Preparer *
2"(J�-Y5
Date
is defined in 40 CFR Part 503.9(r) and 15A.NCAC 2T .1102 (26) DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The.parameters can be reported in FORM RSSF - B
WQ Permit Number: WQ0034397
Facility Name: Laurinburg Storm Water Residuals
Residual Source WQ # or
NPDES #:
WWTP Name:
Residual Analysis Data
Laboratory: 1) envirochem
2)
3)
4)
5)
Parameter
(mg/kg)
Conc.
Limit
m a
Sample or Composite Date
12/29/14
Percent Solids (%)
NA
34.2
Arsenic
75
0.692
Cadmium
85
0.692
Copper
4,300
25.8
Chromium
NA
1.32
Lead
840
0.692
Mercury
57
<.200
Molybdenum
75
0.692
Nickel
420
0.748
Selenium
100
1.23
Zinc
7,500
318
Total Phosphorus
NA
292
TKN
NA
305
Ammonia -Nitrogen
NA
8.4
Nitrate and Nitrite
NA
3.62
a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penaltifisl-or submiglag f nfor--cation, including the possibility of fines and imprisonment for knowing violations."
of Preparer *
Date
is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM RSSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM[*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Murphy -Brown Bladen/Sampson Residuals Program Total Dry Tons Applied (Annual):
Permit #: WQ034397 Cation Exchange Capacity (non 503 only):
Operator: Triple S Farms Owner: Murphy -Brown LLC Predominant Soil Series: Foreston
Acres Used: 10 Acres Permitted: 15.1 Site #: AMMON1 Field #:
Residual Analvsis Data (Heave Metals and Total Phosphorus use me/k2, % Solids use Raw Percent
C
posite
Date
Phos-
phorus
Annual
Heavy
Metal Field Loadings
(Calculated
in lbs/acre):
Total
Ill
21
31
141
51
L6 j
71
81
1 9
10
11
12]
DT/Ac./
rt
App.
Event
1.00
Arsenic
.%O00A
. ... .. ..... -
� 00
�,O 0
....... ...
L­0_000:�.:
.. .... .........................
0...000::::
i0o 0'
0 .00 0:;:::
0 OGG:,
04,114"OX
0. 0:
0., 000:1�
0007
Cadmium
.0
0 04.
0.1.0.0.0.
0.009.�:;.
�-
....
O...OW�;::
G GO:
.0 :i
::..*'.%Q_ 0 .
6.6i 00011!
......
�1.0 O1:i:.O-0QW�!
.0 .9
00:1,1:
Copper
;0
Gi.000,1.
O'OOO!;:;:::OA00
*;:::0,.**0..00::
r::G.--'.'OOO:!;:V
. .... .....
G'OOO:
0.' OQQ.:::
O:�
0
0 01.0
-1* 9
Chromium.:
...
.:.0. 0
O.OGYJ
"0: 0
- .0 4
........ ....
OG­
..........
!.T;0000i�
0 GO
. ...... ..... Mi!
04i:-�
Lead
0.0001:
_O.O0O&&:..:
�Iiii;�G;000
:0.000::
0
.0 :'RO
iiii�!O..'QOO:�,:!
000.
ti�!O; i
V.O 2 1
Mercury
boal:
.000:4"
:!�::!0.0.0�0*-*.�;!iii!�:...000.
f :0 oo*;.::.
.0
0 .00 0:
.00 0
Molyb-
(!;i
(!;i
00001:�:
��_O.000:i:�l
0000:i�:
0.000:i
0*'000 -F��P-GQQ*:
0
1Q,
0
0.000:
000:;
0 0.
0.0 �;�i: Ni�:
0.0 5
denum
.&&..&.
& I &
_.
' -
Nickel
_O�*Q­65:::;�'
11�!' .000:1
0**
0
OU W*
.000
000,0:
0 0
0 GO:`
Selenium,
-0 005:!:;:
0 0 �-:
.,QO
0 6: 0 0
:i::O;OQ0.�:
iiip*..O _O
Q0i.*.*-.!O--.0OO:-
.
6:
... .. ....
.0-0 09*
1;;110*10010
'0 0 GO:
0
_ Q....5
Zinc
::J; .:..;:;o
"1
W .
0 &.
Q 0.;
99 .4
AM :41.
.000!�;�:
0.
0 OG::
OGG,
0 00
L
Total
Phos-
711$W:i
OQ:.
0,000
0.0004:*
000
.000
0 00:0
340*
Dhorus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowft violation
ir
Signature of Land Applier Date
DENR FORM MFLSF (12/2006)

ANNUAL METALS FIELD LOADING SUAEMIARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Murphy -Brown Bladen/Sampson Residuals Program Total ]Dry Tons Applied (Annual):
Permit WQ034397 Cation Exchange Capacity (non 503 only):
Operator: Triple S Farms Owner: Murphy -Brown LLC Predominant Soil Series: Foreston
Acres Used: 6 Acres Permitted: 6.9 Site #: AMMONI Field #: 2
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorusMENEENEENEEN
,annual rieaV y 1 Kletul ivlelu
Total 111 121
DT/Ac./
App.
Event 1.00
in iDsiacre):
j SeniC,
-0.000:V1:0,0 0, 0O 000::;:.�il! 00:-000 00 4, Arj`�L* 1`1*-,
W
rt
Chromiun�
0.000'
W0,00,
011.00:
1:Q*1.0*0 :r:
.0,000
00.
.0
B.' 04'
Lead
V. 02`1
.0
01* 00
.0 ii.!
4 -0.000:
-0.000
oeoo.0:
0000
0 .000 1
0 . 000TIi!
0:
0 00
.000
. Q.O. ......
Mercury
.,,.!:.0 6
�0
0-00 0;:.:
0;00.0
0.00
�11.0..
61.0,00J
q . i0.... .
W;,006.
.0.00::
0: 000
0`000
0.0. 0
Molyb-
00'.Aw.&O00:
�;;-10.00
0 00,11.
-00-
0
denum
Nickel
05-*
1;!iff.Q00::J;:�;-1.0
0 0 .0-1
":0,400:
0:,
::.Q.00 :
0 .0
-0
Ti!! .0 0
..... .....
. ....... . . QW1.
A; 0
00.
0 0
6
t.i: .000;!i;
%4.005-
Seleniuml--i'.0,005A.
.0. 000..
�0.'o 00. :J:.�0.000t!
i
-;�0.000: :::0.000
0
Zinc
00.:7-:
-1*000:1
0002:
`:::0`000*
-�:!:O*. .0;
-:0 000:
A412
Total
Phos-
3 4-0
-GQ1
0. 0 �j:j�
10...
-;0 0-00:
: 0 00 q!
V
fib.o- 00..
oib 00,
0.0 00.
0 MCC[
-7 3 0**
4 A
Dhorus
j:
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowin violations".
Signature of Land Applier Date
DENR FORM MFLSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Murphy -Brown Bladen/Sampson Residuals Program Total Dry Tons Applied (Annual): V., Wi"-
Permit #: WQ034397 Cation Exchange Capacity (non 503 only):
Operator: Triple S Farms Owner: Murphy -Brown LLC Predominant Soil Series: Foreston
Acres Used: 1.5 Acres Permitted: 2.3 Site #: DUPBOAR Field #: I
Residual Analysis Data (Heave Metals and Total Phosphorus use me/ka. % Solids use Raw Percent
k M-AT"M
Com-
posite
Date
Non
on
0
NOUN
Emmons
Total
Phos-
: --phorus�MEEEEEEEEEEE
Annual
Heavy Metal Meld Loadings
(Calculated
in lbs/acre):
Total
Ill
2 J
31
141
151
L 6 j
171
181
191
101
11 j
12
DT/Ac./
App.
Event
0.03
Arsenic
�-.�OWOQI
0
.0. 00
0- 0.
0 a 0
0,000:
00::
.......... . .....
0 000:
Ab�
��Oi 0,
0
.. .. ... ......
Cadmium
0 0.0.
!;A000:
.00 0-
0
0: 0:
:4.00.
...........
.1.
.. . .....
.0
00,;
Copper
U0 0
A.0,0 Q*:
.... .... .... ...
-�V.000:*
0
0' a
0
:0 0,00
0: 0.0.0]:
.
0. 0.1.
... ..... . . ...
io
0 Q.
Chromium
00.0:!�
0'J"
. . . ..... ...
a 00.0'.
�0.000:
0.000:
V-0 00
000
-0 ON.::
.00 :1
0
Lead
0.00,1,!,::�t
;A. -00.::J:
-.�Oroao.:J.::
0.01
0.000
6.000::.
0.000
0. 0
0
D*� 60
1:&1000:..
0,
.0.0.0;
0 0 Q-1
��ib. at;i�
Mercury
6; 66V
0*:0 0:
..0
.:0,100;-�.
Ir.;01:
.00 0.::
. 0000
00
::,O,o 00
1000.
0.'0.0.T.:T*
0.00W!1!;i:0.
000:.*
Molyb-
0-001:
'
T000
000:0;
.
00:Q.
0
004
000S
0:000
0 000
'.
O.OQ1
denum
.
Nickel
ff--.001.;
6--­
�OO*:�0..'!-'..-...�-.-.�I
6466*
0-6
-.00
i�i: 0*-*0b­
;;!:�0.000::
14 0-.0. 0:51
.0 0.:
6!U002
0-00
0 000!1!�
0.
-000
0 1-
0
Selenium
��:0;000;:
1. :000:-,;
0.
.0
0 .00
: ; :
.0-0.
(Y -0-0
-10
.000 F
X .
. .... -
F-A000
:;�:01'000:;
...... ..... -
�:.0.00. OJ
0.0 01
Zinc
.002:.:*.
0 ;0 0-
0-'.0.00
1! 0.000.:
:4.. GO-:
0004!
0:000-:
0.0W
0.00:
Total
. ..... . ...
Phos-
'0: -1-1:7,'*
-0*000
"4.60.10 00
0 QW!
ili`
0.00-
0-.[:!;00
A.0 t OA7
I -A000::
0 -.'Q00
-(Y.QOQ.
71
Dhoras
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier Date
DENR FORM MFLSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Murphy -Brown Bladen/Sampson Residuals Program Total Dry Tons Applied (Annual):
Permit #: WQ034397 Cation Exchange Capacity (non 503 only):
Operator: Triple S Farms Owner: Murphy -Brown LLC Predominant Soil Series: Foreston
Acres Used: 1 Acres Permitted: 1.8 She #: DUPBOAR Field #: 2
Residual Analvsis Data (Heavv Metals and Total Phosphorus use me/kg. % Solids use Raw Percent #):
MTV M-1.
Com-
posite
Date
Total
Phos-
phorus
Annual
Heavy Metal
Held Loadings
(Ualculatecl
in lbs/acre):
Total Ill
L2
j
3
4
1 1
L_ 5
j
61
171
81
191
10
11
12
DT/Ac./
App.
Event
0.03
Arsenic
rTo-oi 00
':'b Q0 . Q
C* .00, ��i
........... . .....
.. .. ...... . . 0
. .. . .. ... ...
0000
i!Ho` 0.0.
. . ...... .
-OU000.,
0.0 m!fi
Cadrnium.'.�..Q.
0
...... . ... . ..
0.0 00
.... .. .... .. ..
.0
....... 0 ......
......... ..
�0. 0-0*7
0
.0.0
V�o
Copper
0.000
00
..........
V* 00..:*
.. ..... ...
�0.000 il
1:1: 1:
Chromium.
.. .. .... ..
:G.'00 a.
i4:0.:00
:0 00.0
0 �il!!
0
�AOOQ;1�
.0
��0.000;4:�11001�:
Lead
COW:-
0.000:
.T.0
.:0.Q00
0
G:bo
�0.
!1;1! 0.00
'0.0
Mercury
.0.0.06.t]:1!
0.000
ji:0 0"
t:i0A00:-:i�'
0 Goo;.::
0.0.,G0:.1:::&00
0.:*:
01*00W
00
0.*00(Y7!
Molyb-
0.001
0.000
0.000
�;1�4 .00 0 i�:!::O*A.
0 0:!i
Q-000:
0
0
0*.* OQ
A
.0 00
0.000:!
i!:;.'QA01-
denum
denuin
..... .. . .....
Nickel
i:o' 0061;
Q.: 00.,
.0
"0'
oo 0.
.01.0;:i
0
i� 00
T;7%00W�:
. . .. . .....
0
Selenium *0.00V!�41.0.600***
�i�Fo 0.0
0,000''.:.
0.*O�G�0!..�.-:.o-*.�o�oo:.:
... ..... . ..
.... ... ........ .
Y 000*.�;
0. .000
0 NO:,
W.
. .. .......
0.000
00
... ....... ...
0.0.0 1.
Zinc
:.�.0.000...O*Ao&��
�.:A
0.0
-01 00
0.000
11!� W O�
T 'Q Tf:0.000`:�:
0
'0002..
Total
Phos-
t;l�7..::�,�:;O.*00�0-:--;�!-',.�Oi(,
..006::
0 .000:
0.000:�A*�1'04.
07::
0.000
0 7
0.000:
0: 0QQ:
0 1.7
Dhorus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing vniollati ns".
Signature of Land Applier Date
DENR FORM MFLSF (12/2006)

I ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Murphy -Brown Bladen/Sampson Residuals Program Total Dry Tons Applied (Annual):
Permit #: WQ034397 Cation Exchange Capacity (non 503 only):
Operator: Triple S Farms Owner: Murphy -Brown LLC Predominant Soil Series: Autryville
Acres Used: 1.5 Acres Permitted: 2.2 Site #: DUPBOAR Field #: 3
Residual Analvsis Data (Heave Metals and Total Phosphorus use me/ka. % Solids use Raw Percent #):
"Mr. M.
Com-
posite
Date
a
MENo
a
Total
Phos-
phorusMENEENEENE00-
Annual . ivietai r iciu
Total 1 11 121 1 3
DT/Ac./
App.
Event 0.03
Cadmiumi
t%-aicuiateu in ius/acre);
Lead
L
Lead
J
0.00.0
0-00
m.0J:*0*1
Mercury
LMercury-0000:-
-0
-4.* .0
0, .000:1
;VM00%
0.: 00
�O
0.01��io�'000
i
Molyb-
Moly
i�:O'.0007;:i
0**00.0:;�
0T;!1�i:!0i000.;.
qi:�OAQ0!�
-0.0
--o
0.0,06
0.
io.oft�
W1
denum
e m
-0.001,�
. . ......
.0;
Nickel
-0----00l::J:-'z,,06JOO
-.0006
400 V
0
-:�:0-0
G.. Q.0 0 i:!�
.0.. 00 0
00
;:0 0.00
90*
Selenium
0r* .0.0
000'::
.
:P QQ0G:;
. .. ... ...
0
-.0.0
-000;1!1;�;i3O
...
. ... .. .. .. .:.!!1A
.0
Zinc
0.`002::,.*!
i: 0.000
QOQQ
.0*0.0:
0.**;* 0.06
:00000000
0.,.0000.*000*�7;0�
.0.00,Aj.!!0.000
:-
::;:.
0 000
Total
Phos-
117;
i.*-,ii0.*000
00 0
0A 0
0:0
000,�!�:!
Qiii:
0.,
:1
i;! 0.0
IT
chorus.
.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: AMMON 1 WQ Permit #: WQ0034397 Field #: 1 Acres Utilized: 10
Land Owner: Murphy -Brown LLC Annual Dry Tons, Applied."T0 0513`:'.:':;'! Site #: Acres Permitted: 15.1
Operator: Eric Smith Predominant Soil Series: Foreston Cation Exchange Capacity (non 503):
Crop 1 Name: Bermuda Crop 1 Max. PAN: 300 Crop 2 Name: Small Grain Crop 2 Max. PAN:
50
�.
Volume applied
Volume
Residual Sources
Soil
Cond.
Precip.
Y
v
o
4
!e
Z
Ft
Nitrate
PAN
Applied
PP
Name of Crop Type
° +,
(enter one) Solids/
%
Applied per
(NPDES # WQ#
Past 24
cob
0'
w
w co
o
TKN
o
and
( lbs/acre)
Receiving Residual
o
Liquid
Solids
Acre
Fert., Animal
(Dry,
Hrs.
a W
o
* �'
* w
o w
Nitrite
Application
A
Cu. Yds
Gallons
(Dry Tons/Ac)
Waste, etc)
Wet,*
Moist)
inches
o
0
mg/kg
mg/kg
mg/kg
Crop 1
Crop 2
Crop 1
Crop 2
11/14/14
31
0
38.5
Tarheel TW
Dry
0
S
0.5
0.4
820
74.1
6090
:;:12, 917
12 9'17:
;O,OOQ..
:._0:000:;:
0:::
;:.00.0
;.b 000..:,,
0.000:11
0110:0.0'.
0.00.0
...... ........... ._..............................
.
F1Oc000;.:.
0000:;:
:000
0000.
iQ Q00s
0000:
........................................
Q:Qoo
° :o 000.... ..
.....
.................
.
......::::>:<:>::......;
:::>:<::::>
. :: ' : ; ;.
........::.::.:-:.:...,
F F su attach
Residuals Applications totals on FORM S PP (
FORM
FSF su to this
PP
form):
.: <:;:;::.:::
::::::::::::::>::::::::::>:<;:>:::<:::::<:»
..................................
::::::::::::..:.::::::.::::::::::.::.
_...........
TOTALS:
::..........:..::.
; ':..:s::..:::3:1
. ...
+.':.y:::::::::;o::>::>:<:>:::>::>::::>
>::»:<:>:::<:::>:::
As
Cd
Cu
Cr
Pb
H
Mo
Ni
Se
Zn
P
12:917
';12 9:11r:
...............
Lime Applied
Annual lbs/acre
0.001:.:.:.::;.0.001
.
,0:001.Q...:...:...:,-::.....
1
.1,
0.000.:
0. Ol `
: 0:001 ,..
_0.001.
0:002
0.117 .
........
:>'»>><><>:>:>>»
»::.»;;;;:;;;;.
.... ..
....................
Date
lbs/ac
s
Prior Years Cumulative lb /ac
...
....................................
Current Cumulative lbs/ac
0001 . ...:,:
OooY:; ......
000l :..::
0 ;.:`
0,0 :1, .:.:..
.:.::001...
Q...
0000':
0;001::
.::0:001 ..::
0001 ''
''000 :;<>>::>:>:><
�:..:
<;>:<:»>>><'<>»>
Permitted C. P. L. R. ***
Permit PAN Limit lst/2nd Crop
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly athered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the p ibility of f es and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
%/ �J **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: AMMON2 WQ Permit #: WQ0034397 Field #: 1 Acres Utilized: 6
...................... .
Land Owner: Murphy -Brown LLC Annual Dry Tons Applied: 5 99$4' Site #: Acres Permitted: 15.1
Operator: Eric Smith Predominant Soil Series: Foreston Cation Exchange Capacity (non 503):
Crop 1 Name: Bermuda Crop 1 Max. PAN: 300 Crop 2 Name: Small Grain Crop 2 Max. PAN: 50
Volume applied
Volume
Residual Sources
Soil
Precip.
Y
c
Z
Nitrate
Name of Crop Type
S
(enter one) Solids/
%
Applied per
(NPDES #, WQ#,
Cond.
Past 24
� 10
co 'n
�.
:h �
TKN
�
o
and
PAN Applied
Receiving Residual
�, O
Liquid
Solids
Acre
Fert., Animal
(Dry,='
Hrs.
o�
* w
*
o �.
Nitrite
( lbs/acre)
Application
A
Waste, etc)
Wet
o
o
Pfft
w
Cu. Yds
Gallons
(Dry Tons/Ac)
Moist)
inches
p
0
mg/kg
mg/kg
mg/kg
Crop 1
Crop 2
Crop 1
Crop 2
11/14/14
18.5
0
38.5
:;; ;1; .0' 0*0 >; :
Tarheel TW
Dry
0
S
0.5
0.4
820
74.1
6090
12.847:
12847:..
Os000 `'
l7 0:000
..........
0.: ..
0; 000:`:0:000:
Oc000G::.::::
::: 0 0.00
00;00:::
O;Obr:
000:0; :: ;:
0000'
:0.000::
0:000
0
Residuals Applications totals on FORM FSF su attach FORM
FSF supp to this form):
TOTALS:
As
Cd
Cu
Cr
Pb
H
Mo
Ni
Se
Zn
P
2 $
1, .. 47:,
..,12.847::,;
Lime A lied
Annual lbs/acre
o 001
0 001
0;001 °
: ; 0 001__,
...Oi001.
0.000
.i;0 001 _: _
.0:001; _ '
0.001`:I:.'
.:.:0.002
0:117
:: ::
...................................
. ........::
Date
lbs/ac
Prior Years Cumulative lbs/ac
....................................
......................
Current Cumulative lbs/ac
0 00 ;:
]
0:001
0:001
0: Ol
0...
0.001:::
0: 00
0.....:
OA01
..
0.00:1
0.001 :
0:002
......
:>::;:::>::>:::
::
Permitted C. P. L. R. ***
Limit 1 sPz
Permit PAN L t/2nd Crop
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including t possib' 'ty f fines and imprisonment for knowing violations."
�/ *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: DUPBOARI WQ Permit #: WQ0034397 Field #: 2 Acres Utilized: 1
Land Owner: Murphy -Brown LLC Annual D Tons Applied:
Dry pp Site #: Acres Permitted: 1.8
Operator: Eric Smith Predominant Soil Series: Foreston Cation Exchange Capacity (non 503):
Crop 1 Name: Bermuda Crop 1 Max. PAN: 300 Crop 2 Name: Small Grain Crop 2 Max. PAN:
50
I. �
Volume applied
Volume
Residual Sources .
Soil
Cond.
Precip.
Y
410
o
Z Y
�
Nitrate
PAN Applied
Name of Crop Type
+-
enter one Solids/
1 )
u
/a
Applied per
PP P
(NPDES #, WQ#,
Past 24
c•o b
%° w.
,.,,,
w .,
TKN
o
and
( Ibs/acre)
Receiving Residual
Y c
Liquid
Solids
Acre
Fert., Animal
(Dty�
Hrs.
o �.
oa
* N
*
0
w
Nitrite
Application
A
Waste, etc)
Wet
o
o
°p
Cu. Yds
Gallons
(Dry Tons/Ac)
Moist)
inches
�
mg/kg
mg/kg
mg/kg
Crop 1
Crop 2
Crop 1
Crop 2
26
0.1
;:::0 022.:,' .
Warsaw FM
Dry
0
S
0.5
0.4
8740
344
1 6210
0 427 1.10
.................
427':;
0,000
0.000
........... .
0000.
0�000::::
0000;
..:.:::.:::..............................
0:000:,:;
o 000000:':
Q 0
:.:
........
.0.000...:;.:
._::......:.....................:..........
_...........__.......... .
-X ..........
,:.:,:::.::::,;:.:: '::; ::>''-`.
Residuals Applications totals on FORM FSF su attach
FORM
FSF supp to this
form):
TOTALS :
;, : ; .26
<,:: r: ' :'':; o::><CrPb
::.::.:...:..::...:..:.:..::.:.:::.:::....
As
Cd
Cu
C
b
Mo
N i
Se
Zn
P
0.:427i ' ..
Lime Applied
Annual lbs/acre
; ;:;: ;;_0 001.:
o...00l:.
o,00l, ..,.
l.r
,;,..0_00;,,,,;;;,
..:0.001 ...:0:000:;.;
,,,,,, ;,,, „_,, .....
:....o.00 :::
: 0,001:..
;::0:001:::.;:;;:::0
0 '.:.::;0A
:7::.:::::>::>::::>::>::::>::>::>::::>
::<:>::>::::>::>::>:
Date
lbs/ac
Prior Years Cumulative lbs/ac
Current Cumulative lbs/ac
0,001, .
0.001;.,.;
0
,.;,..O...Ol.,;
0.001 .
; 0.001 :
a:000
o.00l:::_
o:ool :
0:001
o:oor
:<<:>:;<>:<«<<:::><>:«<<<:<::
Permitted C. P. L. R. ***
Permit PAN Limit 1 st/2nd Crop
.........................................................
3
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the p0sibility.5frines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
r **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
I Ids 1AP 66A R 1 ' 3 a» ****C.P.L.R.: Cumulative Pollutant Loading Rate
1- o n o a,.l
&, Lf6 9 `i DENR FORM FSF (1212006)
Li, 000�al

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: DUPBOARl WQ Permit M WQ0034397 Field #: 1 Acres Utilized: 1.5
Landowner: Murphy -Brown LLC Annual Dry Tons Appliedc;;0:0328`^'; `; :, ;:. ; . Site #: Acres Permitted: 2.3
Operator: Eric Smith Predominant Soil Series: Foreston Cation Exchange Capacity (non 503):
Crop 1 Name: Bermuda Crop 1 Max. PAN: 300 Crop 2 Name: Small Grain Crop 2 Max. PAN:
50
&.
Volume applied
Volume
Residual Sources
Soil
Precip.
Y
d
o
Z
Nitrate
PAN
Applied
pP
Name of Crop Type
.c
+r
(enter one) Solids/
%
Applied per
(NPDES # WQ#
>
Cond.
Past 24
'E
'* �
`'� w•.
�'..-
9
TKN
o
and
(lbs/acre)
Receiving Residual
Liquid
Solids
Acre
Fert., Animal
(Dry,
Hrs.
o w'
N'
* N
Nitrite
Application
A
Cu. Yds
Gallons
(Dry Tons/Ac)
Waste, etc)
Wet,
Moist)
inches
0.
* o.
0
0
mg/kg
mg/kg
mg/kg
Crop 1
Crop 2
Crop 1
Crop 2
11/14/14
39
0.1
::ri4 0.022`; ':.`.'?"
Warsaw FM
Dry
0
S
0.5
0.4
8740
344
6210
0 427 ::
.................
"0.42,
0.000.,
0 00;0 ?;
0:00.0r""::
. _....... .
0,000:...:';.;Oy000::.:
000:
.........................
......
"?:0.000:.:;00.00.....
....... .
.......... ... :.:..:....:
...........:.................
O:000
0:00:;:
: 0 0:0..0.:;.
0:000.,.:.::::Q
O OOO::.
......
0000
0.000::.
_......
0000'':::.:;00
'0... Q....
::0:000:::
Residuals Applications totals
Residu I APP
on FORM FSF su attach
PP (
FORM
FSF su to this
PP
form):
)
:>::>::»:<:»>:<:»>
>:<:»>:::
TOTALS:
>;
AS
Cd
Cu
Cr
Pb
H
Mo
Ni
Se
Zn
P
`;;;0427;;.::..
;: g427:::;;
Lime A ie
Annuallbs/acre
-..:0.001
0.001.:...,:.:0...0.....:..:.....X.:.:
0 1.
..:.0.00 :.:
0:001..:::O.00o
... _
:
0:001'
_:...::....:..:.:......:::..:....,
0.001
0 001-.
0.002
0:1'17
>: >>::;< >»>:>:<'
> : ; >'..«
Date
lbs ac
/
Prior Years Cumulative lbs/ac
.:..........:....................................
.
Cumulative lbs/ac
o001
,:
..
o.00l...
:.a.00
,...
..
000.
...:.:....:.:............0......._
`
............................:'...Current
><
Permltted C. P. L. R. ****
7-1
Limit l st/2nd Crop
Permit PAN p
::::::
300"
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the pose' ility of fi es d imprisonment for knowing violations "
/ *Application Method: S - Surface, IN - Injection,'INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: DUPBOAR WQ Permit #: WQ0034397 Field #: 3 Acres Utilized: 1_5
Landowner: Murphy -Brown LLC Annual Dry Tons Applied: 0_p328::':`;;'` 9 Site #: Acres Permitted: 1_8
Operator: Eric Smith Predominant Soil Series: Autryville Cation Exchange Capacity (non 503):
Crop 1 Name: Bermuda Crop 1 Max. PAN: 275 Crop 2 Name: Small Grain Crop 2 Max. PAN:
50
Volume applied
pp
Volume
Residual Sources
Soil
Cond.
Precip.
Y
b
C
o
Z g
o
Nitrate
PAN Applied
Name of Crop Type
�
�
enter one Solids/
( )
o
/a
Applied per
(NPDES # WQ#
past 24
'E
�. �•
w•
'w� ...
=°
� �,
TKN
B
w c
and
(lbs/acre)
Receiving Residual
g
�
ALiquid
Solids
Acre
Fert., Animal
Wet'
Hrs.
c �'.
�
*
* w'
w•
Nitrite
Application
Cu. Yds Gallons
(Dry Tons/Ac)
Waste, etc)
Moist)
inches
0
°p
p
mg/kg
mg/kg
mg/kg
Crop 1
Crop 2
Crop 1
Crop 2
39
0.1
O Q22 ; ;;
Warsaw FM
Dry
0
S
0.5
0.4
8740
344
6210
;;: 0 427 ,1
0:
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the pos 'bility of fn and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
���� **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
*** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
Signature of Land Applier Date
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

Environmental Chemists, Inc.
envirochem 6602 Windmill Way • Wilmington, NC 28405
[phone] (Lab) • [phone] (Fax)
SM
710 Bowsertown Road • Manteo, NC 27954
ANALYTICAL &CONSULTING [phone].
CHEMISTS NCDEN& DWQ.CERTIRCATE #94. DTS CERTIFICATE #37729
Murphy Brown, LLC
Date of Report: 'Jan 23, 2015
Post Office Box 856
Customer PO #:
Warsaw NC 28398
Customer ID: 08110011
Attention: Kraig Westerbeek
Report #: 2014-16064
Project ID: White Oak Truck Wash
Lab ID Sample ID:
Collect Date/Time Matrix Sampled by
14-39149 Site: Sludge
12/29/2014 9:00 AM Solid/Sludge Client
Test Method 'Results Date Analyzed
Chlordane
SW 846 Method 6081813610
<0.005 mg/L
01113/2015
Endrin
SW 846 Method 8081B/3510
<0.00005 mg/L
01113/2015
Heptachlor
SW 846 Method 8081BM510
<0.00005 mg/L
01/13/2015
Heptachlor epoxide
SW 846 Method 8081 B1351 0
<0.00005 mg/L
01/13/2015
Lindane
SW 846 Method 8081BI3510
.<0.00005 mg/L
01/13/2015
Methoxychlor
SW 846 Method 8081 813510
<0.00005 mg/L
01/13/2015
Toxaphene
SW 846 Method 8081B/3510
<0.005 mg/L
01/13/2015
1,4-Dichlorobenzene (TCLP)
SW 846 method 8270/351 a
<0.050 mq/L
01/12/2015
2,4,5-Trichlorophenol (TCLP)
SW 846 method 827013510
<0.050 mg/L
01/12/2015
2,4,6-Trichlorophenol (TCLP)
SW M method 8270/3510
<0.050 mg/L
01/12/2015
2,4-Dinitrotoluene (TCLP)
SW 648 method 8270/3510
<0.050 mg/L
01/12/2015
Cresol (TCLP)
SW 646 method 8270/3510
<0.050 mg/L
01/12/2015
Hexachloro-1,3-butadiene (TCLP)
SW 846 method 6270/3510
<0.050 mg/L
01/12/2015
Hexachlorobenzene (TCLP)
SW 846 method 827013510
<0.050 mg/L
0111212015
Hexachloroethane (TCLP)
SW 846 method 82701351D
<0.050 mg/L
01/12/2015
m + p-Cresol (TCLP)
SW 846 method 827013610
<0.050 mg/L
01/12/2015
Nitrobenzene (TCLP)
SW 846 method 8270/3510
<0.050 mg/l_
01/12/2015
o-Cresol (TCLP)
SW 846 method 827013510
<0.050 mg/L
01/12/2015
Pentachlorophenol (TCLP)
SW 846 method 827013510
<0.250 mg/L
01/12/2015
Pyridine (TCLP)
SW 846 method 8270/351D
<0.050 mg/L
01/12/2015
2,4,5-TP
SW846 Method 8151A
<0.003 mq/L
01/14/2015
2,4-D
SW846 Method 8151A
<0.003 mq/L
01/14/2015
1,1-Dichloroethylene
SW846 Method8260/5030
<0.01 mg/L
01/09/2015
1,2-Dichloroethane
SW846 Method826015030
<0.01 mg/L
01/09/2015
Benzene
SW845 Method 8260/6030
<0.01 mg/L
01/09/2015
Carbon Tetrachloride
SW846 Method 8260/5030
<0.01 mg/L-
01/09/2015
Report#_: 2014-18064 Page 1 of 3

0
Environmental Chemists, Inc.
envirochem 6602 Windmill Way • Wilmington, NC 28405
[phone] (Lab) • [phone] (Fax)
4
710 Bowsertown Road • Manteo, NC 27954
ANALYTICAL &CONSULTING [phone]
CHEMISTS NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729
Murphy Brown, LLC
Date of Report: Jan 23, 2015
Post Office Box 856
Customer PO #:
Warsaw NC 28398
Customer ID: 08110011
Attention: Kraig Westerbeek
Report #: 2014-16064
Project ID: White Oak Truck Wash
Chlorobenzene
SW846 Method 8260/5030
<0.01 mg/L
01/09/2015
Chloroform
SW846 Method 826015030
<0.01 mg/L
01/09/2015
Methyl ethyl ketone
SW846 Method B26015030
<0.05 mg/L
01/09/2015
Tetrachloroethylene
SW846 Method 826015030
<0.01 mg/L
01/09/2015
Trichloroethylene
SW846 Method 8260/5030
<0.01 mg/L
01/09/2015
Vinyl Chloride
SW846 Method 826015030
<0.01 mg/L
01109/2015
RCI
Ignitability
EPA1030
<0.8 mm/sec
01/12/2015
Cyanide
EPA335.4
<0.122mg/kg
01/16/2015
Sulfide
SM4600 S D
0.56 mg/kg
01/15/2015
PH
SW 846 Method 8045D
5.44 units
01/16/2015
Sludge Residuals
Aluminum
EPA200.7
869 mg/kg
01/13/2015
Arsenic
EPA200.7
3.58 mg/kg
01/13/2015
Cadmium
EPA200.7
<0.585mg/kg
01/13/2015
Calcium
EPA200.7
50700 mglkg
01/13/2015
Chromium
EPA200.7
2.96 mg/kg
01/13/2015
Copper
EPA 200.7
480 mg/kg
01/13/2015
Lead
EPA200.7
2.10 mg/kg
01/13/2015
Magnesium
EPA200.7
4970 mg/kg
01/12/2015
Molybdenum
EPA200.7
2.64 mg/kg
01/13/2015
Nickel
EPA200.7.
2.94 mg/kg
01/13/2015
Potassium
EPA 200.7
9210 mg/kg
01 /12/2015
Selenium
EPA200.7
2.36 mg/kg
01/13/2015
Sodium
EPA200.7
2570 mg/kg
01/12/2015
Zinc
EPA 200.7
673 mg/kg
01/13/2015
Ammonia Nitrogen
EPA350.1
94.6 mg/kg
01/07/2015•
Total Kjeldahl Nitrogen (TKN)
EPA351.2
941 mg/kg
01/06/2015
Nitrate+Nitrite-Nitrogen
EPA363.2
5140 mg/kg
01/06/2015
Total Solids (%)
SM2540 a
40.8 %
01/02/2015
Report #:: 2014-16064
Page 2 of 3

ANALYTICAL & CONSULTING
CHEMISTS
Environmental Chemists, Inc.
6602 Windmill Way • Wilmington, NC 28405
[phone] (Lab) • (910) 392-4.424 (Fax)
710 Bowsertown Road • Manteo, NC 27954
[phone]
NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729
Murphy Brown, LLC Date of Report: Jan 23, 2015
Post Office Box 856 Customer PO #:
Warsaw NC 28398 Customer ID: 08110011
Attention: Kraig Westerbeek Report #: 2014-16064
Project ID: White Oak Truck Wash
Total Phosphorus 5M4500 P F 774 mg/kg 01/06/2015
Mercury SW84674718 <0.039mg/kg 01/14/2015
TCLP Metals
Arsenic
EPA200.7
<0.100mg/L
01/14/2015
Chromium
EPA200.7
<0.100mg/L
01/14/2015
Barium
EPA200.8
0.132mg/L
01/13/2015
Cadmium
EPA 200.8
<0.100 mg/L
01/13/2015
Lead
EPA200.5
<0.100mg/L
01/13/2015
Selenium
EPA200.8
<0.100 mg/L
01/1312015
Silver
EPA20a.8
<0.100 mg/L
01/13/2015
Mercury
EPA245.1
<0.002mg/L
01/19/2015
Comment: Sludge residuals, except pH, reported. on a dry weight basis. pH reported on an as received basis
Reviewed by: Y" �L
Report#:: 2014-16064 Page 3 of 3

mington, NC
ENVIRONMENTAL CHEMISTS, I N C OFFICE: 910i 392-0223'IFAX 910 392-44245
Analytical & Consulting Chemists NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 [e-mail]
MI 1 FCTION ANn CHAIN OF CUSTODY
Client: Murphy Brown, LLC
PROJECT NAME: LJ
REPORT NO: 141 /E vG
ADDRESS:
CONTACT NAME:
PO NO:
REPORT TO: Kraig Westerbeek
PHONE/FAX:
COPY TO:
email:
Sarnnlarl Rv- SAMPLE TYPE: I = Influent. E = Effluent. W = Well. ST = Stream. SO = Soil. SL = Sludge, Other:
+
Sample Identification
Collection
E '�
mr-
y
a
E c9
0
;,
`o
ca
V L
„
$ a�
r E
U
m
g�
z
PRESERVATION
ANALYSIS REQUESTED
Date
Time
Temp
z
o
z
x
x
o
w
z
o
z
x
c
�
z
o
iE
w
x
p
Residuals
ra �91!
C,: 0b R
d
C
P
�� I
X
Full TCLP, RCI, Nutrients/metals
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
Transfer
Relinquished By:
Date/Time
Received By:
Date/Time
2.
Temperature when Received: V L Accepted: f Rejected: Resample
Delivered By: Received By:
, Comments:
Time:

Environmental Chemists, Inc.
envirochem 6602 Windmill Way • Wilmington, NC 28405
[phone] (Lab) • (910)3924424(Fax)
SM
710 Bowsertown Road • Manteo, NC 27954
[phone]
ANALYTICAL & CONSULTING
CHEMISTS NCDENR: DWQ CERTIFICATE 994. US CERTIFICATE #37729
Murphy Brown, LLC Date of Report: Jan 23, 2015
Post Office Box 856 Customer PO #:
Warsaw NC 28398 Customer ID: 08110011
Attention: Kraig Westerbeek Report #: 2014-16063
Project ID: Tar Heel Truck Wash
Lab ID Sample ID: Collect Date/Time Matrix Sampled by.
14-39144 Site: Residuals 12/29/2014 9:30 AM Solid/Sludge. Client
Test Method Results Date Analyzed
Chlordane
SW 846 Method 8081Ba5l0
<0.05 mg/L
01/13/2015
Endrin
SW 846 Method 808113/3510
<0.0005 mg/L
01/13/2015
Heptachlor
SW 846 Method 808113/3510
<0.0005 mg/L
01/13/2015
Heptachlor epoxide
SW 846 Method 80811313510
<0.0005 mg/L
01/13/2015
Lindane
SW 846 Method 80818/3610
<0.0005 mg/L
01/13/2015
Methoxychlor
SW 846 Method 8081 B1351 0
<0.0005 mg/L
01/13/2015
Toxaphene
SW 846 Method 608113/3510
<0.05 mg/L
01/13/2015
1,4-Dichlorobenzene (TCLP)
SW 846 method 8270/3610
<0.050 mq/L
01/12/2015
2,4,5-Tdchlorophenol (TCLP)
SW 846 method 8270/3510
<0.050 mg/L
01/12/2015
2,4,6-Trichlorophenol (TCLP)
SW 846 method 8270/351a
<0.050 mg/L
01/12/2015
2,4-Dinitrotoluene (TCLP)
SW s46 method 8270/3510
<0.050 mg/L
01/12/2015
Cresol (TCLP)
SW 846 method 827013510
<0.050 mg/L
01112/21015
Hexachloro-1,3-butadiene (TCLP)
SW 846 method 827013510
<0.050 mg/L
01/12/2015
Hexachlorobenzene (TCLP)
SW 846 method 827013510
<0.050 mg/L
01/12/2015
Hexachloroethane (TCLP)
SW 846 method 8270/3510
<0.050 mg/L
01/12/2015
m + p-Cresol (TCLP)
SW N6 method 8270/3510
<0.050 mg/L
01/1212015
Nitrobenzene (TCLP)
SW 846 method $270/3510
<0.050 mg/L
01/12/2015
o-Cresol (TCLP)
SW 846 method 8270/3510
<0.050 mg/L
01/12/2015
Pentachlorophenol (TCLP)
SW 846 method 8270/3510
<0.250 mg/L
0111212015
Pyridine (TCLP)
SW 846 method 8270/3510
<0.050 mg/L
0111212015
2,4, 5-TP
SW846 Method 8151A
<0.003 mg/L
01 /14/2015
2,4=D
SW846 Method 8161A
<0.003 mg1L
01/14/2015
1,1-Dichloroethylene
SW846 Method 826016030
<0.01 mg/L
01/09/2015
1,2-Dichloroethane
SW846 Method 826015030
<0.01 mg/L
01/09/2015
Benzene
SW846 Method 8260/5030
<0.01 mg/L
01/09/2015
Carbon Tetrachloride
SW846 Method 826015030
<0.01 mg/L
01/09/2015
Report #.: 2014-16063 Page 1 of 3

Environmental Chemists, Inc.
envirochem 6602 Windmill Way • Wilmington, NC 2W5
© [phone] (Lab) • [phone] (Fax)
M
710 Bowsertown Road • Manteo, NC 27954
ANALYTICAL 8: CONSULTING [phone]
CHEMISTS NCDENR: DWQ CERTMCATE #94. DLS CERTIRCATE #37729
Murphy Brown, LLC
Date of Report: Jan 23, 2015
Post Office Box 856
Customer PO #:
Warsaw NC 28398
Customer ID: 08110011
Attention: Kraig Westerbeek
Report #: 2014-16063
Project ID: Tar Heel Truck Wash
Chlorobenzene
SW846 Method $260/5030
<0.01 mg/L
01/09/2015
Chloroform
SW846 Method 8260/6030
<0.01 mg/L
01/09/2015
Methyl ethyl ketone
SW846 Method 826D/5030
<0.05 mg/L
01/09/2015
Tetrachloroethylene
SW846 Method 8260/5D30
<0.01 mg/L
01/09/2015
Trichloroethylene
SW846 Method826015030
<0.01 mg/L
01/09/2015
Vinyl Chloride
SW846 Method8260/5030
<0.01 mg/L
01/09/2015
RCI
Ignitability
EPA 103D
<0.8 mm/sec
01/12/2015
Cyanide
EPA335.4
<0.124 mg/kg
01/16/2015
Sulfide
SM 4500 S D
0.27 mg/kg
01/15/2015
pH
SW 846 Method 90450
5.42 units
01/16/2015
Sludge Residuals
Aluminum
EPA200.7
519 mg/kg
01/13/2015
Arsenic
EPA 200.7
3.40 mg/kg
01/13/2015
Cadmium
EPA200.7
<0.576mg/kg
01/13/2015
Calcium
EPA200.7
35300 mg/kg
01/13/2015
Chromium
EPA200.7
1.89 mg/kg
01/13/2015
Copper
EPA200.7
395 mg/kg
01/13/2015
Lead
EPA200.7
0.761 mg/kg
01113/2015
Magnesium
EPA200.7
5970 mg/kg
01/12/2015
Molybdenum
EPA20D.7
2.30 mg/kg
01/13/2016
Nickel
EPA200.7
2.70 mg/kg
01/13/2015
Potassium
EPA200.7
12400 mg/kg
01/13/2015
Selenium
EPA200.7
2.44 mg/kg
01/13/2015
Sodium
EPA200.7
3580 mg/kg
01/12/2015
Zinc
EPA200.7
556 mg/kg
01/13/2015
Ammonia Nitrogen
EPA350.1
74.1 mg/kg
01/07/2015
Total Kjeldahl Nitrogen (TKN)
EPA351.2
820 mg/kg
01/06/2015
Nitrate+Nitrite-Nitrogen
EPA353.2
6090 mg/kg
01/06/2015
Total Solids (%)
SM2640 8
38.5 %
01/02/2015
Report#:: 20144 063
Page 2 of 3

Environmental Chemists, Inc.
envirochem., 6602 Windmill Way • Wilmington, NC 28405
[phone] (Lab) • [phone] (Fax)
SM
710 Bowsertown Road • Manteo, NC 27954
ANALYTICAL &CONSULTING [phone]
CHEMISTS NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729
Murphy Brown, LLC Date of Report: Jan 23, 2015
Post Office Box 856 Customer PO #:
Warsaw NC 28398 Customer ID: 08110011
Attention: Kraig Westerbeek Report #: 2014-16063
Project ID: Tar Heel Truck Wash
Total Phosphorus SM 4600 P F 3670 mg/kg 01/06/2015
Mercury SW8487471B 0.0560 mg/kg 01/09/2015
TCLP Metals
Arsenic
EPA200.7
<0.100 mg/L
01/14/2015
Chromium
EPA200.7
<0.100 mg/L
01/14/2015
Barium
EPA200.8
<0.100 mg/L
01/13/2015
Cadmium
EPA200.8
<0.100 mg/L
01/13/2015
Lead
EPA200.8
<0.100 mg/L
01/13/2015
Selenium
EPA200.8
<0.100 mg/L
01/13/2015
Silver
EPA200.8
<0.100mg/L
01/13/2015
Mercury
EPA245.1
<0.002mg/L
01/19/2015
Comment: Sludge residuals, except pH, reported on a dry weight basis. pH reported on an as received basis.
Reviewed by:
Report !#:: 2014-16063 Page 3 of 3

a
Analytical & Consulting Chemists
ENVIRONMENTAL CHEMISTS, INC
NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729
COLLECTION AND CHAIN OF CUSTODY
6602 Windmill Way Wilmington, NC 28405
OFFICE: 910-392-0223 FAX [phone]
[e-mail]
Client: Murphy Brown, LLC
PROJECT NAME: -rG r ll ee-
REPORT NO:
ADDRESS:
CONTACT NAME:
PO NO:
REPORT TO: Kraig Westerbeek
PHONEIFAX:
COPY TO:
email:
Samnled Bv: SAMPLE TYPE: I = Influent, E = Effluent, W = Well, ST = Stream, SO = Soil, SL = Sludge, Other:
Sample Identification
Collection
m
w
'n
a
w a
C `o
;, „
cC7
`o
va
i
a E
t�
nuf
m
�z
PRESERVATION
ANALYSIS REQUESTED
Date
Time
Temp
i
°z
x
w
s
ii
x
o
z
o
o
Residuals
1d a�'/i
3dp�1
5
C
P
X
Full TCLP, RCI, Nutrients/metals
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
Transfer
Relinquished By:
Date/Time
Received By:
Date/Time
1.
2.
Temperature when Received: lj G Accepted: Rejected: Resample Req s d:
Dellvered By: Received By: Date: IL s= 1J Time: 3 �_
Comments: TURNA OUND:

qj
Environmental Chemists, Inc.
6602 Windmill Way • Wilmington, NC 28405
[phone] (Lab) • [phone] (Fax)
SM
710 Bowsertown Road • Manteo, NC 27954
[phone]
ANALYTICAL & CONSULTING
CHEMISTS NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729
Murphy Brown, LLC
Date of Report:
Jan 23, 2015
Post Office Box 856.
Customer PO #:
Warsaw NC 28398
Customer ID:
08110011
Attention: Kraig Westerbeek
Report #:
2014-16065
Project ID: Vffii@vffa
t—AcA ����
Lab ID Sample ID:
Collect Date/Time Matrix
Sampled by
14-39150 Site: Sludge
12/29/2014 4:00 PM Solid/Sludge
Client
Test Method Results Date Analyzed
Chlordane
SW 846 Method 8081 B/3510
<0.05 mg/L
01113/2015
Endri n
SW 846 Method 8081 B/3510
<0.0005 mg/L
01/13/2015
Heptachlor
SW 846 Method 8081 B13510
<0.0005 mg/L
01/13/2015
Heptachlor epoxide
SW 846 Method 6081813510
<0.0005 mg/L
01113/2015
Lindane
SW 846 Method 8081BI3510
<0.0005 mg/L
01113/2015
Methoxychlor
SW 846 Method 8081813510
<0.0005 mg/L
01/13/2015
Toxaphene
SW 846 Method 8081S13510 ,
<0.05 mg/L
01/13/2015
1,4-Dichlorobenzene (TCLP)
SW 846 method 8VOI3510
<0.050 mg/L
01/12/2015
2,4,5 Trichlorophenol (TCLP)
SW 846 method 8270/3510
<0.050 mg/L
01/12/2015
2,4,6 Trichlorophenol (TCLP)
SW 846 method 8270/3510
<0.050 mg/L
01/12/2015
2,4-Dinitrotoluene (TCLP)
SW 846 method 8270/3510
<0.050 mg/L
01/12/2015
Cresol (TCLP)
SW 846 method 8270/3510
<0.050 mg/L
01/12/2015
Hexachloro-1,3-butadiene (TCLP)
SW 846 method 8270/3510
<0.050 mg/L
01/12/2015
Hexachlorobenzene (TCLP)
SW 846 method 8270/3510
<0.050 mg/L
01/1212015
Hexachioroethane (TCLP)
SW 846 method 8270/3510
<0.050 mg/L
01/12/2015
m + p-Cresol (TCLP)
SW 846 method 8270/3510
<0.050 mg/L
01/12/2015
Nitrobenzene*(TCLP)
SW 846 method 827013510
<0.050 mg/L
01/12/2015
o-Cresol (TCLP)
SW 846 method 8270/3610
<0.050 mg/L
01/12/2015
Pentachlorophenol (TCLP)
SW 846 method 8270/3510
<0.250 mg/L
01/12/2015
Pyridine (TCLP)
SW 846 method 8270)3510
<0.050 mg/L
01/12/2015
2,4,5-TP
SW846 Method 8151A
<0.003 mg/L
01/14/2015
2,4-D
SW846 Method 8151A
<0.003 mg/L
01/14/2015
1,1-Dichloroethylene
SW846 MethodB26015030
<0.01mg/L
01/09/2015
1,2-Dichloroethane
SW846 Method8260/5030
<0.01 mg/L
01/09/2015
Benzene
SW846 Method 8260/5030
<0.01 mg/L
01/09/2015
Carbon Tetrachloride
SW846 Method 8260/503D
<0.01 mg/L
01/09/2015
ReportW: 2014-16055 Page t of 3

Environmental Chemists, Inc.
envirochem 6602 Windmill Way • Wilmington, NC 28405
SM [phone] (Lab) [phone] (Fax)
710 Bowsertown Road • Manteo, NC 27954
ANALYTICAL &CONSULTING [phone]
CHEMISTS NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE 4137729
Murphy Brown, LLC
Date of Report: Jan 23, 2015
Post Office Box 856
Customer PO #:
Warsaw NC 28398
Customer ID: 08110011
Attention: Kraig Westerbeek
Report #: 2014-16065
Project ID: Warsaw
Chlorobenzene
SW846 Method 8260/6030
<0.01 mg/L
01/09/2015
Chloroform
SW846 Method 826015030
<0.01 mg/L
01/09/2015
Methyl ethyl ketone
SW846 Method 8260/5030
<0.05 mg/L
01/09/2015
Tetrachloroethylene
SW846 Method 825015030
<0.01 mg/L
01/09/2015
Trichloroethylene
SW846 Method 826015030
<0.01 mg/L
01/09/2015
Vinyl Chloride
SW846 Method 826015030
<0.01 mg/L
01/09/2015
RCI
Ignitability
EPA1030
<0.8mm/sec
01/12/2015
Cyanide
EPA335.4
<0.122mg/kg
01/16/2015
Sulfide
SM 4500 8 D
0.58 mg/kg
01/15/2015
PH
SW 846 Method 9045D
7.99 units
01/16/2016
Sludge Residuals
Aluminum
EPA2o0.7
1,06 mg/kg
01/13/2015
Arsenic
EPA 200.7
<0.733 mg/kg
01/13/2015
Cadmium
EPA200.7
<0.733mg/kg
01/13/2015
Calcium
EPA200.7
6250 mg/kg
01/12/2015
Chromium
EPA200.7
1.36 mg/kg
01/13/2015
Copper
EPA200.7
26.7 mg/kg
01/13/2016
Lead
EPA200.7
<0.733 mg/kg
01/13/2015
Magnesium
EPA200.7
637 mg/kg
01/12/2015
Molybdenum
EPA200.7
0.874 mg/kg
01/13/2015
Nickel
EPA200,7
<0.733 mg/kg
01/13/2015
Potassium
EPA200.7
513 mg/kg
01/12/2015
Selenium
EPA200.7
1.44 mg/kg
01/13/2015
Sodium
EPA200.7
250 mq/kq
01/1212015
Zinc
EPA200.7
346 mg/kg
01/16/2015
Ammonia Nitrogen
EPA350.1
<0.587 mg/kg
01/07/2015
Total Kjeldahl Nitrogen (TKN)
EPA351.2
271 mg/kg
01/05/2015
Nitrate}Nitrite-Nitrogen
EPA353.2
16.7 mg/kg
01/05/2015
Total Solids M
SM2540 s
34.1 %
01/02/2015
Report#:: 2014-16065
Pabe 2 of 3

Environmental Chemists, Inc.
envirochem 6602 Windmill Way • Wilmington, NC 28405
© [phone] (Lab) • [phone] (Fax)
710 Bowsertown Road • Manteo, NC 27954
ANALYTICAL & CONSULTING [phone]
CHEMIST'S NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729
Murphy Brown, LLC
Date of Report: Jan 23, 2015
Post Office Box 856
Customer PO #:
Warsaw NC 28398
CustomerlD: 08110011
Attention:. Kraig Westerbeek
Report M 2014-16065
Project 10: Warsaw
Total Phosphorus
SM4500 P F
606 mg/kg
01/06/2015
Mercury
SWB4674718
<0.047mg/kg
01/14/2015
TCLP Metals
Arsenic
EPA 200.7
<0.100 mg/L
01 /14/2015
Chromium
EPA200.7
<0.100mg/L
01/14/2015
Barium
EPA200.8
<0.100mg/L
01/13/2015
Cadmium
EPA200.8
<0.100mg/L
01/13/2015
Lead
EPA200.8
<0.100 mg/L
01/13/2015
Selenium
EPA200.8
<0.100 mg/L
01/13/2015
Silver
EPA200.8
<0.100 mg/L
01113/2015
Mercury
EPA245.1
<0.002 mq/L
01/20/2015
Comment: Sludge residuals, exce t pH, reported on a dry weight basis. pH reported on an as received basis.
Reviewed by:
Report#:: 2014-16065 Page 3 of 3

6602
l Way
ENVIRONMENTAL CHEMISTS, INC OFFICE: 910i1392-02 311FAX [phone]
NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 [e-mail]
Analytical & Consulting Chemists
CC>ILLFCTION AND CHAIN OF CUSTODY
Client: Murphy Brown, LLC
PROJECT NAME: grSa W
REPORT NO: / `(- ko 6 S
ADDRESS:
1
CONTACT NAME:
PO NO:
REPORT TO: Kraig Westerbeek
PHONE/FAX:
COPY TO:
email:
Samnled Bv: SAMPLE TYPE: I = influent, E = Effluent, W = Well, ST =.Stream, SO = Soil, SL = Sludge, Other:
Sample Identification
Collection
m y
A
N
N
E `o
.q
CJ
d �,
eC7
a `o
d
=J
.2 E
m
�W
a
x
PRESERVATION
ANALYSIS REQUESTED
Date
Time
TemCD
z
N
o
0
0
Residuals
50 F
C
P
��t�
X
Full TCLP, RCi, Nutrients/metals
MOO
H: doPAM
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
Transfer
Relinquished By:
DatelTime
Received By:
DatelTime
1.
2.
Temperature when Received: L L Accepted: / Rejected: Resample
Delivered By: Received
Time: 3 " f
Comments: TURNAROUND:

Environmental Chemists, Inc.
envirochem 6602 Windmill Way • Wilmington, NC 28405
[phone] (Lab) • [phone] (Fax)
sM 710 Bowsertown Road • Manteo, NC 27954
ANALYTICAL &CONSULTING [phone]
CHEMISTS NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729
Murphy Brown, LLC Date of Report: Jan 23, 2015
Post Office Box 856 Customer PO #:
Warsaw NC 28398 Customer ID: 08110011
Attention: Kraig Westerbeek Report #: 2014-16052
Project ID: Warsaw Mill
Lab ID Sample ID: Collect Date/Time Matrix Sampled by
14-39122 Site: Sludge 12/29/2014 4:30 PM Solid/Sludge Client
Test Method Results Date Analyzed
Total Solids (%)
SM 2540 B
<.1 %
01/02/2016
RCI
Cyanide
EPA335.4
<0.124 mg/kg
01/16/2015
Sulfide
SM4500S D
0.12 mg/kg
01/15/2015
Ignitability
Sw846method 1010
>212 OF
01/13/2015
Sludge Residuals
Aluminum
EPA200.7
471 mg/kg
01/14/2015
Arsenic
EPA200.7
<10.0 mg/kg
01/14/2015
Cadmium
EPA200.7
<10.0 mg/kg
01/14/2015
Calcium
EPA200.7
54700 mg/kg
01/13/2015
Chromium
EPA200.7
<10.0 mg/kg
01/14/2015
Copper
EPA200.7
17.0 mg/kg
01/14/2015
Lead
EPA200.7
<10.0 mg/kg
01/14/2015
Magnesium
EPA200.7
5020 mg/kg
01/13/2016
Nickel
EPA200.7
13.0mg/kg
01/14/2015
Potassium
EPA200.7
21100 mg/kg
01/13/2015
Selenium
EPA20a•7
<10.0 mg/kg
01/14/2015
Sodium
EPA200.7
30100 mg/kg
01/13/2015
Zinc
EPA200.7
44.0 mg/kg
01/14/2015
Molybdenum
EPA200.8
<10.0 mg/kg
01/15/2015
Mercury
EPA245.1
<0.200 mg/kg
01/19/2015
Ammonia Nitrogen
EPA350.1
344mg/kg
01/02/2015
Total Kjeldahl Nitrogen (TKN)
EPA3512
8740 mg/kg
01/06/2015
Nitrate+Nitrite-Nitrogen
EPA3532
6210 mg/kg
01/05/2015
pH
SM4500 H B
7.84 units
01/09/2015
Total Phosphorus
SM4500 P F
2330 mg/kg
01/06/2015
Report #:: 2014-16052 Page 1 of 3

Environmental Chemists, Inc.
■ 6602 Windmill Way • Wilmington, NC 28405
[phone] (Lab) • (910) 3924424 (Fax)
sM 710 Bowsertown Road • Manteo, NC 27954
ANALYTICAL & CONSULTING [phone]
CHEMISTS NCDENR: DWQ CERnKCATE #94. DLS CERTIRCATE #37729
Murphy Brown, LLC Date of Report: Jan 23, 2015
Post Office Box 856 Customer PO #:
Warsaw NC 28398 Customer ID: 08110011
Attention: Kraig Westerbeek Report #: 2014-16052
Project ID: Warsaw Mill
TCLP - Volatiles
1,1-Dichloroethylene
SW846 Method 826016030
<0.01 mg/L
01/09/2015
1,2-Dichloroethane
SW846Method 82601503o
<0.01 mg/L
01/09/2015
Benzene
SW846 Method 826015MO
<0.01 mg/L
01/09/2015
Carbon Tetrachloride
SW846 Method 826015MO
<0.01 mg/L
01/09/2015
Chlorobenzene
SW80 Method 8260/5030
<0.01 mg/L
01/09/2015
Chloroform
SW846 Method 8260/5030
<0.01 mg/L
01/09/2015
Methyl ethyl ketone
SW646 Method 8260/5030
<0.05 mg/L
01/09/2015
Tetrachloroethylene
SW846 Method U6015030
<0.01 mgIL
01/09/2015
Trichloroethylene
SW846 Method 8260/5030
<0.01 mgIL
01/09/2016
Vinyl Chloride
SW848 Method 8260/5030
<0.01 mg/L
01/09/2015
TCLP Herbicides
2,4,5-TP
SW848 Method 8151A
<0.003 mg/L
01/14/2015
2,4-D
SW848 Method 8151A
<0.003 mg/L
01/14/2015
TCLP Metals
Arsenic
EPA200.7
<0.100 mgIL
01/14/2015
Chromium
EPA200.7
<0.100 mgIL
01/14/2015
Barium
EPA 200.8
0.150 mg/L
01/15/2015
Cadmium
EPA 200.8
<0.100 mg/L
01/15/2015
Lead
EPA 200.8
<0.100 mgIL
01115/2015
Selenium
EPA 200.8
<0.100 mg/L
01/15/2015
Silver
EPA 200.8
<0.100 mgIL
01/15/2015
Mercury
EPA 246.1
<0.200 mg/L
01/19/2015
TCLP Pesticides
Chlordane
SW846 Method 8081BI3510
<0.05mg/L
01/13/2015
Endrin
SW846Method 8081B/8510
<0.0005mg/L
01/13/2015
Heptachlor
SW 846 Method 8081 B13510
<0.0005 mgIL
01/13/2015
Heptachlor epoxide
SW 846 Method 8081B13510
<0.0005 mgIL
01/13/2015
Lindane
SW 846 Method 8081BI3510
<0.0005 mg/L
01/1312015
Methoxychlor
SW 846 Method 808113/3610
<0.0005 mg/L
01/13/2015
Report #:: 2014-16052
Page 2 of 3

envirochem
ANALYTICAL & CONSULTING
CHEMISTS
Environmental Chemists, Inc.
6602 Windmill Way • Wilmington, NC 28405
[phone] (Lab) • [phone] (Fax)
710 Bowsertown Road • Manteo, NC 27954
[phone]
NCDENR: DWQ CERTIFICATE #94. DES CERTIFICATE #37729'
Murphy Brown, LLC Date of Report: Jan 23, 2015
Post Office Box 856 Customer PO #:
Warsaw NC 28398 Customer ID: 08110011
Attention: Kraig Westerbeek Report #: 2014-16052
Project ID: Warsaw Mill
Toxaphene SW846Method 8081B13510 <0.05mg/L 01/13/2015
TCLP-Semivolatiles
1,4=Dichlorobenzene (TCLP)
SW 846 method 8270/3510
<0.050 mg/L
01/12/2015
2,4,5Trichlorophenol(TCLP)
SW 846 method 827013510
<0.050mg1L
01/12/2015
2,4,6-Trichlorophenol (TCLP)
SW 846 method 8270/3510
<0.050 mg/L
01/12/2015
2,4-Dinitrotoluene (TCLP)
SW 846 method 8270/3510
<0.050 mg/L
01/12/2015
Cresol (TCLP)
SW 846 Method 827013510
<0.050 mg/L
61/12/2015
Hexachioro-1,3-butadiene (TCLP)
SW $46method SZ70/3510
<0.050 mg/L
01/12/2015
Hexachiorobenzene(TCLP)
SW846 method 8270/3510
<0.050mg/L
01/12/2015
Hexachloroethane (TCLP)
SW 846 method $27013510
<0.050 mg/L
01/12/2015
m + p-Cresol (TCLP)
SW 846 method 8270/3510
<0.050 mg/L
01/12/2015
Nitrobenzene (TCLP)
SW 846 method 8270=10
<0.050 mg/L
01/12/2015
o-Cresol (TCLP)
SW 646 method W013610
<0.050 mg/L
01/12/2015
Pentachlorophenol (TCLP) SW 846 method 8270/3510 <0.250 mg/L 01/12MO15
Pyridine (TCLP) SW 846 method 8270/3510 <0.050 mg/L 01/12/2015
Comment: Sludge residuals, except pH, reported on a dry weight basis. pH reported on an as received basis.
Reviewed by:
Report#:: 2014-16052 Page 3 of 3

—doddommolms— 6602 Windmill Way NC
ENVIRONMENTAL CHEMISTS, INC OFFICE: 910-3202 3i1FAX[phone]
Analytical & Consulting Chemists NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 [e-mail]
COLLECTION AND CHAIN OF CUSTODY
Client: Murphy Brown, LLC
PROJECT NAME: FA
REPORT NO.z—
ADDRESS:
CONTACT NAME:
PO NO:
REPORT TO: Kraig Westerbeek
PHONEIFAX:
COPY TO:
email:
Ramnlpd Rv: r, .s.. SAMPLE TYPE: I = Influent, E = Effluent. W = Well. ST = Stream. SO = Soil. SL = Sludge. Other:
Sample Identification
Collection
m
�T
y
2
H
E `o
d ,
` o
" a
d
"
x
m g'
Z
PRESERVATION
ANALYSIS REQUESTED
Date
Time
Temp
z
x
o
z~
ii
o
E
w
o
Residuals
JoP
a
5a
C
P
3�'j°Z'
X
Full TCLP, RCI, Nutrients/metals
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
Transfer
Relinquished By:
Date/Time
Received By:
DatelTime
4.
2.
Temperature when Received: 1. Accepted: / Rejected: Kesample Ke s a:
Delivered By: __ y: Date: So Time:
Received B
Cnmmpnfim. TURNA OUND:

Poll". qq Environmental Chemists, Inc.
envirochem 6602 Windmill Way • Wilmington, NC 28405
© [phone] (Lab) • [phone] (Fax)
s
710 Bowsertown Road • Manteo, NC 27954
ANALYTICAL & CONSUL7iNG [phone]
CHEMISTS NCDENIL• DWQ CERTIFICATE #94. DLS CERTIFICATE #37729
Murphy Brown, LLC Date of Report: Jan 23, 2015
Post -Office Box 856 Customer PO #:
Warsaw NC 28398 Customer ID: 08110011
Attention: Kraig Westerbeek Report #: 2014-16061
Project ID: Laurinburg Mill
Lab ID Sample ID: Collect Date/Time Matrix Sampled by
14-39143 Site: Residuals 12/29/2014 11:30 AM Solid/Sludge Client
Test Method Results Date Analyzed
Chlordane
SW 846 Method 8001 W351 0
<0.05 mg/L
01/13/2015
Endrin
SW 846 Method 8081B/3510
<0.0005 mg/L
01/13/2015
Heptachlor
SW 846Method 8081B/3510
<0.0005 mg/L
01/1312015
Heptachlor epoxide
SW 646 Method 8081 B1351 0
<0.0005mg/L
01/13/2015
Lindane
SW 846 Method 8081 B/3510
<0.0005 mg/L
01/13/2015
Methoxychlor
SW 846 Method 8081 B/3510
<0.0005 mg/L
01/13/2015
Toxaphene
SW $48 Method 8081B/3510
<0.05 mg/L
01/13/2015
1,4-Dichlorobenzene (TCLP)
SW 846 method 827013510
<0.050 mq/L
01112/2015
2,4,5-Trichlorophenol (TCLP)
SW 846 method 8270/3510
<0.050 mg/L
01/1212015
2,4,6-Trichlorophenol (TCLP)
SW 846 method 9270/3510
<0.050 mg/L
01/12/2016
2,4-Dinitrotoluene (TCLP)
SW 846 method 8270/3510
<0.050 mg/L
01/12/2015
Cresoi (TCLP)
SW 845 method 8270/3510
<0.050 mg/L
01/12/2016
Hexachloro-1,3-butadiene (TCLP)
SW 846 method 8270/3510
<0.050 mg/L
01/12/2015
Hexachlorobenzene (TCLP)
SW 846 method 8270/3510
<0.050 mg/L
01 /12/2015
Hexachloroethane (TCLP).
SW 846 method 8270/3510
<0.050 mg/L
01/12/2015
m + p-Cresol (TCLP)
SW 846 method 8270/3510
<0.050 mg/L
01/12/2015
Nitrobenzene (TCLP)
SW 846 method 3270/3510
<0.050 mg/L
01112/2015
o-Cresol (TCLP)
SW 848 method 8270/3510
<0.050 mg/L
01/12/2015
Pentachlorophenol (TCLP)
SW 846 method 8270/3510
<0.250 mg/L
01/12/2015
Pyridine (TCLP)
SW 846 method 827013510
<0.050 mg/L
01/12/2015
2,4,5-TP
SW846 Method 8151A
<0.003 mq/L
01/14/2015
2,4-D
SW046 Method 8151A
<0.003 mq/L
01/14/2015
1,1-Dichloroethylene
SW846 Method $26016030
<0.01 mg/L
01/09/2015
1,2-Dichloroethane
SW846 Method 8260/8030
<6.01 mg/L
01109/2015
Benzene
SW846 Method 8260/6030
<0.01 mg/L
01/09/2015
Carbon Tetrachloride
SW846 Method 826016030
<0.0'f mg/L
01/09/2015
Report#:: 2014-16061 Page 1 of 3

• Environmental Chemists, Inc.
6602 Windmill Way • Wilmington, NC 28403
O [phone] (Lab) • [phone] (Fax)
sna
710 Bowsertown Road • Manteo, NC 27954
ANALYTICAL &CONSULTING [phone]
CHEMISTS NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729
Murphy Brown, LLC
Date of Report: Jan 23, 2015
Post Office Box 866
Customer PO #:
Warsaw NC 28398
Customer ID: 08110011
Attention: Kraig Westerbeek
Report #: 2014-16061
Project ID: Laurinburg Mill
Chlorobenzene
SW846 Method 8260/5030
<0.01 mg/L
01/0912015
Chloroform
SW846 Method 8260/6030
<0.01 mg/L
01/09/2015
Methyl ethyl ketone
SW846 Method 8260/5030
<0.05 mg/L
01/09/2015
Tetrachloroethylene
SW846 Method 8260/6030
<0.01 mg/L
01/09/2015
Tdchloroethylene
SW846 Method 8260/5030
<0.01 mg/L
01/09/2015
Vinyl Chloride
SW846 Method 8260/6030
<0.01 mg/L
01/09/2015
RCI
Ignitability
EPA 1030
<0.8 mm/sec
01/12/2015
Cyanide
EPA335.4
<0.124mg/kg
01/16/2015
Sulfide
SM 4500 S D
0.77 mg/kg
01/15/2015
pH
SW 846 Method 9045D
8.02 units
01/16/2015
Sludge Residuals
Aluminum
EPA200.7
126 mg/kg
01/13/2015
Arsenic-
EPA200.7
<0.692 mg/kg
01/13/2015
Cadmium
EPA200.7
<0.692mg/kg
01/13/2016
Calcium
EPA200.7
6340 mg/kg
01/12/2015
Chromium
EPA200.7
1.32 mg/kg
01/13/2015
Copper
EPA200.7
25.8 mg/kg
01/13/2015
Lead
EPA200.7
<0.692mg/kg
01/13/2015
Magnesium
EPA200.7
654 mg/kg
01/12/2015
Molybdenum
EPA200.7
<0.692 mg/kg
01/13/2015
Nickel
EPA200.7
0.748 mg/kg
01/13/2015
Potassium
EPA200.7
-546 mg/kg
01/12/2015
Selenium
EPA200.7
1.23 mg/kg
01/13/2015
Sodium
EPA200.7
313 mg/kg
01/12/2015
Zinc
EPA200.7
318 mg/kg
01/13/2015
Ammonia Nitrogen
EPA350.1
8.4 mg/kg
01/0712015
Total K}eidahl Nitrogen (TKN)
EPA351.2
305 mg/kg
01/05/2015
Nitrate+Nitrite-Nitrogen
EPA353.2
3.62 mg/kg
01/05/2015
Total Solids (%)
SM2640 s
34.2 %
01/02/2015
Report#:: 2014-16061
Page 2 of 3

Environmental Chemists,. Inc.
envirochem 6602 Windmill Way • Wilmington, NC 28405
[phone] (Lab) • [phone] (Fax)
710 Bowsertown Road • Manteo, NC 27954
[phone]
ANALYTICAL $ CONSULTING
CHEMISTS NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729
Murphy Brown, LLC
Post Office Box 856
Warsaw NC 28398
Attention: Kraig Westerbeek
Total Phosphorus sM 4500 P F
Mercury SW846 7471 B
TCLP Metals
Date of Report: Jan 23, 2015
Customer PO #:
Customer ID: 08110011
Report #: 2014-16061
Project ID: Laurinburg Mill
292 mg/kg 01/06/2015
<0.058 mg/kg 01/14/2015
Arsenic
EPA 200.7
<0.100 mg/L
01/14/2015
Chromium
EPA 200.7
<0.100 mg/L
01/14/2015
Barium
EPA200.8
<0.100mg/L
01/13/2015
Cadmium
EPA200.8
<0.100mg/L
01/13/2015
Lead
EPA 200.8
<0.100 mg/L
01/13/2015
Selenium
EPA200.8
<0.100mg/L
01/13/2015
Silver
EPA200.8
<0.100mg/L
01/13/2015
Mercury
EPA245.1
<0.200mglL
01/19/2015
Comment: Sludge residuals, except pH, reported on a dry weight basis. pH reported on an as received basis.
Reviewed by:
Report#:: 2014-16061 Page 3 of 3

Analytical & Consulting Chemists
ENVIRONMENTAL CHEMISTS, INC
NCDEMR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729
COLLECTION AND CHAIN OF CUSTODY
6602 Windmill Way Wilmington, NC 28405
OFFICE: 910-392-0223 FAX [phone]
[e-mail]
Client: Murphy Brown, LLC
PROJECT NAME: L-Gkr, n bw
REPORT NO:
ADDRESS:
CONTACT NAME:
PO NO:
REPORT TO: Kraig Westerbeek
PHONE/FAX:
COPY TO:
email:
Samnlpd Rv- z✓ SAMPLE TYPE: I = Influent, E = Effluent, W = Well, ST = Stream, SO = Soil, SL = Sludge, Other:
Sample Identification
Collection
E
w
0 o
is
o
"IL
d
s E
a
m g
PRESERVATION
ANALYSIS REQUESTED
Date
Time
Temp
Z
d
N
o
0
o
w
Residuals
P
i �I
X
Full TCLP, .RCI, Nutrients/metals
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
C
P
G
G
Transfer
Relinquished By:
Date/Time
Received By:
Daterrime
1.
2.
Temperature when Received: v"v Accepted: If
Delivered By: !!9!0 Received By:
Comments:
Time: 3yr p

101 RS IC = RA
0 IE
axe 1976
Ship To:
Murphy Brown, LLC
PO Box 856
Warsaw, NC 28398
Grower:
Murphy Brown, LLC
Waters Agricultural Laboratories, Inc.
364 West Park Drive
Warsaw, NC 28398
[phone] fax [phone]
Soil Texture Determinations
Date Of Report:
1/8/2015
�C
S--[�"T
r.
AMMON1
6161 MC
SAND.
8.40
91.60
2.40
6.00
AMMON2
6162MC
SAND
8.80
91.20
4.80
4.00
DUPB OAR1
6163MC
SAND
4.80
95.20
0.80
4.00
DUPBOAR2
6164MC
SAND
6.80
93.20
2.80
4.00
DUPBOAR3
6165MC
SAND
9.20
90.8
2.80
6.40
This document may be reproduced only in its entirety. As we have no control over the matter in which the sample was taken, the analysis
is based solely on the sample received. Our liability is limited to the sample received and for the fee assessed on same.

Waters Agricultural Laboratories, Inc.
0 E
1976 Lab Analysis Report
9nca364 West Park Drive Warsaw, NC 28398
Phone: [phone] Fax: [phone]
Shiffix Murphy -Brown LLC
PO Box 856
Warsaw, NC 28398
Grower: Date Submitted: 1/2/2015
lurphv-Brown Report Date: 01/06/2015
ym�e
ub -its
MM.'Os
Ressoper
AMNON1
81936
0.103
Ressoper
AmNON2
81937
0.064
Ressoper
DUPBOAR1
81938
0.02
Ressoper
DUPBOAR2
81939
0.019
Ressoper
DUPBOAR3
81940
0.031

Waters Agricultural Laboratories, Inc.
1NAT RS Ic RAL'?
o IE 364 West Park Drive Warsaw, NC 28398 257 Newton Hwy - P.O. Box 382 : os I ie Rc�r`:
[phone] FAX [phone] Camilla, Georgia 31730
[phone] FAX [phone]
MURPHY-BROWN LLC .Soil Analysis Report Grower: MURPHY-BROWN Account#: 5338
677 Curtis Ivey Rd NCDA Index Field ID: RESSOPER Received: 01/02/2015
WARSAW, NC 28398
Processed: 01/06/2015
P I K-I Mg% Ca% Water ❑
Lab Number Sample ID ❑ ❑ ❑ pH Ac S-I Zn-I Zn-AI Mn-I Mn-AI Cu-I CEC BS /o HM /o Soil Class
881936ZW ! AMMONI 397, 43 18.8
Recommendations - lbs./A Lime-Tons/A
69.6 6.1 0.7 31 2236 2236 78 63 490 7.1 91.5 0.42 Min
❑N P205 K20 Mg OS Cu Zn © Mn See Note
Crop BERMUDA Pasture M
0.0
220
0 120
0
0
0
0
12
881937ZW ,AMMON2
356 34.
16.1
65A 5.8 0.8 j
25 1605
1605
43
35
518
5.2. 84:7
0.81 Min.
Recommendations - lbs./A
Crop BERMUDA Pasture M
0.3
220
P205 K20
0 150
Mg
0
❑S
20
Cu
0
Zn
0
©
IME
ISee Note
12
881938ZW DUPBOAR1
„ 40 9
! 30.2
58.8 6.6 0.4
12 123
123
15
18
54
4.1 90.2
0.73 Min
Recommendations - lbs./A
Crop BERMUDA Pasture M
Lime-Tons/A
0.0
9
220
P205 K20
40 220
Mg
0
�S
20
Cu
0
Zn
0
©
Mn
$pH
See Note
12
881939ZW DUPBOAR2
12 5
24.8
67.8 6.6 0.2
11 32
32
21
21
10
3.1 93.6
0.44 Min
Recommendations - lbs./A
Crop BERMUDA Pasture M
Lime-Tons/A9
0.0
220
P205 K20
120 230
Mg
0
SO
20
Cu
$
Zn
0
©
Mn
$pH
See Note
12
881940ZW DUPBOAR3
16 8
19.7
70.0 6.3 0.3
28 49
49
34
32
11
4.3 90.6
0.69 Min
Recommendations - Ibs./A
Crop BERMUDA Pasture M
0.0
220
P205 K20
110 220
Mg
0
�S
0
Cu
$
Zn
0
©
Mn
See Note
12
Fertilizer recommendations are based on the philosophy and recommendations of the NCDA Agronomic Division
DWQ Laboratory Certification Number 636