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NC0021253_Renewal (Application)_20180103
NOATHC.i1?0 'ACORPORATED 15� CITY OF HAVELOCK Post Office Box 368 1 Governmental Ave. Havelock, NC 28532 December 15, 2017 Water Quality Permitting Section — NPDES Division of Water Resources North Carolina Department of Environmental Quality 1617 Mail Service Center Raleigh, NC, 27699-1617 Re: NPDES Permit Renewal Application (NC0021253) City of Havelock Wastewater Treatment Plant City of Havelock, North Carolina To whom it may concern: REDEIVEDIDeNRIDWR DEC 3 12017 Water Resources Permitting Section The City of Havelock Public Services Department is permitted to discharge 2.25 million gallons per day (mgd) of treated effluent from the City of Havelock Wastewater Treatment Plant (WWTP) to the Neuse River under North Carolina NPDES Permit NC0021253. This NPDES permit is scheduled to expire on June 30, 2018. The enclosed application is for the renewal of this permit In accordance with the requirements of federal (40 CFR 122) and state (15A NCAC 2H .0105(3)) regulations, we are submitting three signed copies of the completed application package and associated attachments and figures. The application package includes the following information: • NPDES Permit Application — EPA Form 2A • EPA Form 2A Additional Information (Process Narrative, Topographic Map, and Process Flow Diagrams) • City of Havelock WWTP Sludge Management Plan • First Species Effluent Toxicity Testing, 2015-2017 • Annual Priority Pollutant Analysis Results, 2014-2017 • Technical Memorandum in support of the Reduction of Monitoring Frequency for Exceptionally Performing Facilities At the time of this application submittal, the required second species toxicity testing events have not yet been completed. The four second species effluent toxicity tests are currently scheduled to be completed in December 2017, January 2018, March 2018, and May 2018. When the toxicity test results become available, they will be forwarded to the Division of Water Resources (DWR) along with revisions to Part E of EPA Form 2A to include these results. All second species toxicity tests will be submitted prior to the current permit expiration date of June 30, 2018. A sample for the annual priority pollutant analysis was not taken in 2016. In it's place, a second sample was taken in early December 2017. The annual priority pollutant analysis section is currently based on data collected in 2014, 2015, and 2017. Part D of form 2A as well as Tab E will be updated to replace the 2014 data with the additional 2017 data when that data becomes available. Phone (252) 444-6400 www.havelocknc us Fax (252) 447-0126 In accordance with 15A NCAC 2B 0508(b)(1) and the October 2012 DWR Guidance Docuinent for the Reduction of Monitoring Frequency for Exceptionally Performing Facilities, the City of Havelock respectfully requests a reduction in frequency monitoring for total suspended solids (TSS), ammonia (NH3-N), and fecal coliform. Effluent sampling results from the past three years deinonstrate that all state and regulatory and guidance requirements have been met in support of this request A complete summary of the sampling data and analysis for the reduction of monitoring frequency is attached in Tab G of this application If you have any questions regarding any of the NPDES permit renewal application materials, please contact me at (252) 444-6409 or msavaerOhavelocknc us Sincerely, 4-0�� Mark Sayger Public Services Director Attachments cc Raymond Burgos, City of Havelock Mary Sadler, Hazen and Sawyer Todd Davis, Hazen and Sawyer Ted Elshof, Hazen and Sawyer Phone (252) 444-6400 www havelocknc us Fax (252) 447-0126 NPDES Permit Application City of Havelock, North Carolina City of Havelock Wastewater Treatment Plant Table of Contents Tab A. EPA Form 2A Tab B. EPA Form 2A Additional Information a. Measures to Reduce Infiltration and Inflow b. Process Description c. Topographic Map d. Site Map e Process Flow Diagram Tab C. Sludge Management Plan Tab D. Summary of First Species Effluent Toxicity Testing, 2015-2017 Tab E. Annual Priority Pollutant Analysis Results, 2014-2017 Tab F. Second Species Toxicity Testing Results Tab G. Exceptionally Performing Facilities, Reduction in Frequency Monitoring Analysis City of Havelock Wastewater Treatment Plant City of Havelock, North Carolina EPA Form 2A, NPDES Renewal Application December 2017 FAGILITY NAME, AND PERMIT NUMBER,, PERMITACTION RE,QU15STED., RIVER BASIN City of Havelock VWVTP, NCO021253 Renewal Neuse River FORM 2A NPDES FORM 2A APPLICATION OVERVIEW NPDES APPLICATION OVERVIEW Form 2A has been developed in a modular format and consists of a "Basic Application Information" packet and a "Supplemental Application Information" packet. The Basic Application Information packet is divided into two parts. All applicants must complete Parts A and C Applicants with a design flow greater than or equal to 0.1 mgd must also complete Part B. Some applicants must also complete the Supplemental Application Information packet. The following items explain which parts of Form 2A you must complete. BASIC APPLICATION INFORMATION: A Basic Application Information for all Applicants All applicants must complete questions A 1 through A 8o A treatment works Chat discharges effluent to su'rf'ace waters of the United -States must also answer questions A 9 througti A 12. B Additional Application Information for Applicants with a Design Flow z 0 1 mgd All treatment works that have design flows greater than or equal to 0 1 million gallons per day most complete questions B 1 through 8.6 C„ Certification. All applicants must complete Part C (Certification)„ SUPPLEMENTAL APPLICATION INFORMATION. D Expanded Effluent Testing Data. A treatment works that discharges effluent to surface waters of the United States and meets one or more of the following crilera must complete Part D (Expanded Effluent Testing Data)' 1 Has a design flow rate greater than or equal to 1mgd, 2, Is required to have a pretreatment program (or has one In place), or 3 Is otherwise required by the permitting authority to provide the Information E. 'Toxicity Testing Data A treatment works that meets one or more of the following criteria must complete Part l= (Toxicity Testing Data)` I Has a design flow rate greater than or equal to 'I mgd, 2 Is required to have a pretreatment program (or has one in place), or I 3. Is otherwise, required by the permitting authority to submit results of tonicity testing. F Industrial User Discharges and RCRA%CERCLA Wastes- A treatment works that accepts process wastewater from any significant industrial users (SIUs) or receives RCRA or CERCLA wastes musf complete Part P (Industrial User Discharges and RCRAICE'RCLA Wastes) SIUs are defined as' 1 All Pndustrlal users subject to Categorical Pretreatment Standards under 40 Code of Federal Regulations (CFR) 403 6 and 40 CFR Chapter I, Subchapter N (see instructions), and '2a Any other industrial user that. a Discharges an average of 25,OOQ gallons ,per day or more of process wastewater to the treatment works (vuith oertam exclusions), or I b Contributes a process wastestream that makes, up 5 peroent or more of the, average dry weather hydraulic or organic capacity of the treatment plant, or c 'Is designated as an SIU by the, control authority G Combined Sewer,Systems A treatment works that ,has a combined sewer system must complete Part G (Combined Sewer Systems) ALL APPLICANTS MUST COMPLETE PART C (CERTIFICATION) ERA, Form 3510-2A (Rev 1-99), Replaces EPA forms 7550-6 & 7,550-2Z Page 1 of 17' FACILITY NAME AND PERMIT NUMBER- PERMIT ACTION REQUESTED RIVER BASIN• City of Havelock WWTP, NCO021253 Renewal Neuse River BASIC APPLICATION INFORMATION PART A. BASIC APPLICATION INFORMATION FOR ALL APPLICANTS: All treatment works must complete questions A.1 through A.8 of this Basic Application Information Packet Al Facility Information Facility Name City of Havelock Wastewater Treatment Plant Mailing Address P O Box 368, Havelock NC 28532 Contact Person Raymond Burgos Title Wastewater Treatment Plant B-ORC Telephone Number (252) 444-6421 Facility Address 304 North Jackson Dr (not P O Box) Havelock, NC 28532 A.2 Applicant Information If the applicant is different from the above, provide the following Applicant Name City of Havelock Mailing Address P O Box 368 Havelock, NC 28532 Contact Person Mark Sayger Title Public Services Director Telephone Number (252) 444-6409 Is the applicant the owner or operator (or both) of the treatment works? ® owner ® operator Indicate whether correspondence regarding this permit should be directed to the facility or the applicant ❑ facility ® applicant A.3 Existing Environmental Permits Provide the permit number of any existing environmental permits that have been issued to the treatment works (include state -issued permits) NPDES NCO021253 PSD 091101301 (General Air Permit) UIC Other WQ0000702 (Land Application Permit) _RCRA Other WQCS00104 (Collection System Permit) A.4 Collection System Information Provide information on municipalities and areas served by the facility Provide the name and population of each entity and, if known, provide information on the type of collection system (combined vs separate) and its ownership (municipal, private, etc) Name Population Served Type of Collection System Ownership Havelock, NC 12,500 Separate Municipal Total population served 12.500 EPA Form 3510-2A (Rev 1-99) Replaces EPA forms 7550-6 & 7550-22 Page 2 of 17 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED- RIVER BASIN: City of Havelock WWTP, NCO021253 Renewal Neuse River A.5 Indian Country a Is the treatment works located in Indian Country? ❑ Yes ® No b Does the treatment works discharge to a receiving water that is either in Indian Country or that is upstream from (and eventually flows through) Indian Country? ❑ Yes ® No A.6 Flow Indicate the design flow rate of the treatment plant (i e , the wastewater flow rate that the plant was built to handle) Also provide the average daily flow rate and maximum daily flow rate for each of the last three years Each year's data must be based on a 12 -month time period with the 12th month of "this year' occurring no more than three months prior to this application submittal a Design flow rate 2 25 mgd Two Years Apo Last Year This Year (10/1/2014 - 9/30/2015) (10/1/2015 - 9/30/2016) (10/1/2016 - 9/30/2017) b Annual average daily flow rate 1.377 1 356 1 304 c Maximum daily flow rate 2 810 3 161 3 233 A.7 Collection System Indicate the type(s) of collection system(s) used by the treatment plant Check all that apply Also estimate the percent contribution (by miles) of each ® Separate sanitary sewer 100 % ❑ Combined storm and sanitary sewer N/A % A.8 Discharges and Other Disposal Methods. a Does the treatment works discharge effluent to waters of the U S ? ® Yes ❑ No If yes, list how many of each of the following types of discharge points the treatment works uses I Discharges of treated effluent II Discharges of untreated or partially treated effluent 0 ui Combined sewer overflow points IV Constructed emergency overflows (prior to the headworks) V Other N/A b Does the treatment works discharge effluent to basins, ponds, or other surface impoundments that do not have outlets for discharge to waters of the U S ? ❑ Yes ® No If yes, provide the following for each surface impoundment Location Annual average daily volume discharge to surface impoundment(s) Is discharge ❑ continuous or ❑ intermittent? c Does the treatment works land -apply treated wastewater? If yes, provide the following for each land application site Location Number of acres ❑ Yes ® No Annual average daily volume applied to site Is land application ❑ continuous or ❑ intermittent? d Does the treatment works discharge or transport treated or untreated wastewater to another treatment works? ❑ Yes EPA Form 3510-2A (Rev 1-99) Replaces EPA forms 7550-6 & 7550-22 ® No mgd mgd Page 3 of 17 FACILITY NAME AND PERMIT NUMBER PERMIT ACTION REQUESTED RIVER BASIN - City of Havelock WWTP, NCO021253 Renewal Neuse River If yes, describe the mean(s) by which the wastewater from the treatment works is discharged or transported to the other treatment works (e g , tank truck, pipe) N/A If transport is by a party other than the applicant, provide Transporter Name Mailing Address Contact Person Title Telephone Number ( ) For each treatment works that receives this discharge, provide the following Name Mailing Address Contact Person Title Telephone Number ( ) If known, provide the NPDES permit number of the treatment works that receives this discharge Provide the average daily flow rate from the treatment works into the receiving facility e Does the treatment works discharge or dispose of its wastewater in a manner not included in A 8 through A 8 d above (e g , underground percolation, well injection) If yes, provide the following for each disposal method Description of method (including location and size of site(s) if applicable) Annual daily volume disposed by this method Is disposal through this method ❑ continuous or ❑ intermittent? mgd ❑ Yes ® No EPA Form 3510-2A (Rev 1-99) Replaces EPA forms 7550-6 & 7550-22 Page 4 of 17 FACILITY NAME AND PERMIT NUMBER- PERMIT ACTION REQUESTED RIVER BASIN' City of Havelock WWTP, NCO021253 Renewal Neuse River WASTEWATER DISCHARGES: If you answered "Yes" to question Ag a, complete questions A.9 through A.12 once for each outfall (including bypass points) through which effluent is discharged Do not include information on combined sewer overflows in this section If you answered "No" to question A.B.a, go to Part B, "Additional Application Information for Applicants with a Design Flow Greater than or Equal to 0.1 mgd." A.9 Description of Outfall a Outfall number 002 b Location City of Havelock 28532 (City ortown, if applicable) (Zip Code) Craven NC (County) (State) 34°57'11" 76°52'37" (Latitude) (Longitude) c Distance from shore (if applicable) 2.040 ft d Depth below surface (if applicable) 10 ft e Average daily flow rate 14 mgd f Does this outfall have either an intermittent or a periodic discharge? ❑ Yes ® No (go to A 9 g ) If yes, provide the following information Number f times per year discharge occurs Average duration of each discharge Average flow per discharge Months in which discharge occurs g Is outfall equipped with a diffuser? A.10. Description of Receiving Waters. ® Yes ❑ No mgd a Name of receiving water Neuse River b Name of watershed (if known) Neuse River United States Soil Conservation Service 14 -digit watershed code (if known) 03020204050020 c Name of State Management/River Basin (if known) Neuse River United States Geological Survey 8 -digit hydrologic cataloging unit code (if known) 03020204 d Critical low flow of receiving stream (if applicable) acute Unknown cfs chronic Unknown cfs e Total hardness of receiving stream at critical low flow (if applicable) Unknown mg/I of CaCO3 EPA Form 3510-2A (Rev 1-99) Replaces EPA forms 7550-6 $ 7550-22 Page 5 of 17 FACILITY NAME AND PERMIT NUMBER PERMIT ACTION REQUESTED- RIVER BASIN: City of Havelock WWTP, NCO021253 Renewal Neuse River A.11. Description of Treatment a What level of treatment are provided? Check all that apply ❑ Primary ® Secondary ® Advanced ® Other Describe Denitrification filters b Indicate the following removal rates (as applicable) Design BOD5 removal or Design CBOD5 removal 96 % Design SS removal 84 % Design P removal 78 % Design N removal 91% at current design flow of 2 25 mgd Other N/A % c What type of disinfection is used for the effluent from this outfall? If disinfection varies by season, please describe Ultraviolet Disinfection If disinfection is by chlorination is dechlonnation used for this outfalls ❑ Yes ❑ No Does the treatment plant have post aerations ® Yes ❑ No A.12. Effluent Testing Information. All Applicants that discharge to waters of the US must provide effluent testing data for the following parameters. Provide the indicated effluent testing required by the permitting authority for each outfall through which effluent is discharged Do not include information an combined sewer overflows in this section. All information reported must be based on data collected through analysis conducted using 40 CFR Part 136 methods In addition, this data must comply with QAIQC requirements of 40 CFR Part 136 and other appropriate QA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136 Ate minimum, effluent testing data must be based on at least three samples and must be no more than four and one-half years apart. Outfall number 002 MAXIMUM DAILY VALUE AVERAGE DAILY VALUE PARAMETER Value Units Value Units Number of Samples pH (Minimum) 6.10 s u pH (Maximum) 8.30 s u Flow Rate 3.16 mgd 1.46 mgd 1,093 Temperature (Winter) 23.90 °C 17.16 °C 227 Temperature (Summer) 28.60 °C 23.79 °C 446 ' For pH please report a minimum and a mawmum daily value MAXIMUM DAILY AVERAGE DAILY DISCHARGE DISCHARGE ANALYTICAL POLLUTANT METHOD ML/MDL Conc. Units Conc. Units Number of Samples CONVENTIONAL AND NON CONVENTIONAL COMPOUNDS BIOCHEMICAL OXYGEN BOD5 63.00 m /L 2.74 m /L 728 SM 5210B ML DEMAND (Report one) CBOD5 N/A N/A N/A N/A N/A N/A N/A FECAL COLIFORM 1210 No./ 10.088 No./ 718 SM 9222D ML 100mL 100mL TOTAL SUSPENDED SOLIDS (TSS) 22 m /L 2.64 1 m /L 734 SM 2540D ML END OF PART A - REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS OF FORM 2A YOU MUST COMPLETE EPA Form 3510-2A (Rev 1-99) Replaces EPA forms 7550-6 & 7550-22 Page 6 of 17 FACILITY NAME AND PERMIT NUMBER PERMIT ACTION REQUESTED- RIVER BASIN City of Havelock WWTP, NCO021253 Renewal Neuse River BASIC APPLICATION INFORMATION PART B. ADDITIONAL APPLICATION INFORMATION FOR APPLICANTS WITH A DESIGN FLOW GREATER THAN OR EQUAL TO 0.1 MGD (100,000 gallons per day). All applicants with a design flow rate 2 0 1 mgd must answer questions B 1 through B 6 All others go to Part C (Certification). B 1 Inflow and Infiltration Estimate the average number of gallons per day that flow into the treatment works from inflow and/or infiltration 230,000 gpd Briefly explain any steps underway or planned to minimize inflow and infiltration The City of Havelock Is maintaining ongoing efforts to Identify and rehabilitate sources of 1/1 In their collection system B 2 Topographic Map Attach to this application a topographic map of the area extending at least one mile beyond facility property boundaries This map must show the outline of the facility and the following information (You may submit more than one map if one map does not show the entire area ) Please reference Figure 1 for topographic map and Figure 2 for plant site map a The area surrounding the treatment plant, including all unit processes b The mayor pipes or other structures through which wastewater enters the treatment works and the pipes or other structures through which treated wastewater is discharged from the treatment plant Include outfalls from bypass piping, if applicable c Each well where wastewater from the treatment plant is infected underground d Wells, springs, other surface water bodies, and drinking water wells that are 1) within'/ mile of the property boundaries of the treatment works, and 2) listed in public record or otherwise known to the applicant e Any areas where the sewage sludge produced by the treatment works is stored, treated, or disposed f If the treatment works receives waste that is classified as hazardous under the Resource Conservation and Recovery Act (RCRA) by truck, rail, or special pipe, show on the map where the hazardous waste enters the treatment works and where It is treated, stored, and/or disposed B 3 Process Flow Diagram or Schematic Provide a diagram showing the processes of the treatment plant, including all bypass piping and all backup power sources or redunancy in the system Also provide a water balance showing all treatment units, including disinfection (e g , chlorination and dechlorination) The water balance must show dally average flow rates at influent and discharge points and approximate daily flow rates between treatment units Include a brief narrative description of the diagram Please reference Figure 3 through Figure 5 for process flow diagram and the "Additional Information" sheets for process description B 4 Operation/Maintenance Performed by Contractor(s) Are any operational or maintenance aspects (related to wastewater treatment and effluent quality) of the treatment works the responsibility of a contractor? ® Yes ❑ No If yes, list the name, address, telephone number, and status of each contractor and describe the contractor's responsibilities (attach additional pages if necessary) Name Svnagro Mailing Address 284 Boger Road Mocksville. NC 27028 Telephone Number (877) 267-2687 Responsibilities of Contractor Remove and land apply biosolids to permitted sites B 5 Scheduled improvements and Schedules of Implementation Provide information on any uncompleted implementation schedule or uncompleted plans for improvements that will affect the wastewater treatment, effluent quality, or design capacity of the treatment works If the treatment works has several different implementation schedules or is planning several improvements, submit separate responses to question B 5 for each (If none, go to question B 6 ) a List the outfall number (assigned in question A 9) for each outfall that is covered by this Implementation schedule N/A b Indicate whether the planned improvements or Implementation schedule are required by local, State, or Federal agencies ❑ Yes ❑ No EPA Form 3510-2A (Rev 1-99) Replaces EPA forms 7550-6 & 7550-22 Page 7 of 17 FACILITY NAME AND PERMIT NUMBER- PERMIT ACTION REQUESTED- RIVER BASIN - City of Havelock WWTP, NCO021253 Renewal Neuse River c If the answer to B 5 b is "Yes," briefly describe, including new maximum daily inflow rate (if applicable) N/A d Provide dates imposed by any compliance schedule or any actual dates of completion for the implementation steps listed below, as applicable For improvements planned independently of local, State, or Federal agencies, indicate planned or actual completion dates, as applicable Indicate dates as accurately as possible Schedule Actual Completion Implementation Stage MM/DD/YYYY MM/DD/YYYY - Begin Construction N/A N/A Plant expansion to 2.25 mgd has been completed since - End Construction N/A N/A the 2014 NPDES Permit Renewal. Expansion to 2.8 mgd or 3.5 mgd are not planned for this permit cycle. - Begin Discharge N/A N/A - Attain Operational Level N/A N/A e Have appropriate permits/clearances concerning other Federal/State requirements been obtained? ❑ Yes ® No Describe briefly B.6. EFFLUENT TESTING DATA (GREATER THAN 01 MGD ONLY) Applicants that discharge to waters of the US must provide effluent testing data for the following parameters Provide the indicated effluent testing required by the permitting authority for each outfall through which effluent is discharged. Do not include information on combine sewer overflows in this section All information reported must be based on data collected through analysis conducted using 40 CFR Part 136 methods In addition, this data must comply with QA/QC requirements of 40 CFR Part 136 and other appropriate QAIQC requirements for standard methods for analytes not addressed by 40 CFR Part 136 At a minimum effluent testing data must be based on at least three pollutant scans and must be no more than four and on -half years old Outfall Number 002 MAXIMUM DAILY AVERAGE DAILY DISCHARGE DISCHARGE ANALYTICAL POLLUTANT METHOD MLIMDL Conc. Units Conc. Units Number of Samples CONVENTIONAL AND NON CONVENTIONAL COMPOUNDS AMMONIA (as N) 1140 mg/L 0118 mg/L 735 EPA 350 1 ML 0 5/10 CHLORINE (TOTAL N/A NIA N/A N/A N/A NIA N/A RESIDUAL, TRC) DISSOLVED OXYGEN 480 mg/L 758 mg/L 661 SM 4500-H+B MDL>5.0 TOTAL KJELDAHL 3500 mg/L 1 287 mg/L 153 EPA 3512 AL 21,400 lbs NITROGEN (TKN) TN NITRATE PLUS NITRITE 9.1 mg/L 297 mg/L 152 EPA 353.2 AL 21,400 lbs NITROGEN TN OIL and GREASE N/A NIA NIA N/A N/A N/A N/A PHOSPHORUS (Total) 2.97 mg/L 070 mg/L 151 EPA 365 4 QL 0 7110 TOTAL DISSOLVED SOLIDS N/A NIA NIA N/A N/A N/A N/A (TDS) OTHER N/A NIA N/A NIA N/A NIA N/A END OF PART B. REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS OF FORM 2A YOU MUST COMPLETE EPA Form 3510-2A (Rev 1-99) Replaces EPA forms 7550-6 & 7550-22 Page 8 of 17 FACILITY NAME AND PERMIT NUMBER City of Havelock WWTP, NCO021253 BASIC APPLICATION INFORMATION PART C. CERTIFICATION PERMIT ACTION REQUESTED- I RIVER BASIN. Renewal Neuse River All applicants must complete the Certification Section Refer to instructions to determine who is an officer for the purposes of this certification All applicants must complete all applicable sections of Form 2A, as explained in the Application Overview Indicate below which parts of Form 2A you have completed and are submitting By signing this certification statement, applicants confirm that they have reviewed Form 2A and have completed all sections that apply to the facility for which this application is submitted Indicate which parts of Form 2A you have completed and are submitting: ® Basic Application Information packet Supplemental Application Information packet ® Part D (Expanded Effluent Testing Data) ® Part E (To)acity Testing Siomonitonng Data) ❑ Part F (Industrial User Discharges and RCRA/CERCLA Wastes) ❑ Part G (Combined Sewer Systems) ALL APPLICANTS MUST COMPLETE THE FOLLOWING CERTIFICATION I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief, true, accurate, and complete I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations Name and official title Signature Telephone number Date signed l$ mac- 2p� Upon request of the permitting authority, you must submit any other information necessary to assure wastewater treatment practices at the treatment works or identify appropnate permitting requirements SEND COMPLETED FORMS TO: NCDENR/ DWQ Attn: NPDES Unit 1617 Mail Service Center Raleigh, North Carolina 27699-1617 EPA Form 3510-2A (Rev 1-99) Replaces EPA forms 7550-6 & 7550-22 Page 9 of 17 FACILITY NAME AND PERMIT NUMBER City of Havelock WWTP, NCO021253 PERMIT ACTION REQUESTED Renewal RIVER BASIN Neuse River SUPPLEMENTAL APPLICATION INFORMATION PART D. EXPANDED EFFLUENT TESTING DATA Refer to the directions on the cover page to determine whether this section applies to the treatment works Effluent Testing, 1 0 mgd and Pretreatment Works If the treatment works has a design flow greater than or equal to 1 0 mgd or it has (or is required to have) a pretreatment program, or is otherwise required by the permitting authority to provide the data, then provide effluent testing data for the following pollutants Provide the indicated effluent testing information and any other information required by the permitting authority for each outfall through which effluent is discharged Do not include information on combined sewer overflows in this section All information reported must be based on data collected through analyses conducted using 40 CFR Part 136 methods In addition, these data must comply with QA/QC requirements of 40 CFR Part 136 and other appropriate QA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136 Indicate in the blank rows provided below any data you may have on pollutants not specifically listed in this form At a minimum, effluent testing data must be based on at least three pollutant scans and must be no more than four and one-halfyears old See attached analytical results in Tab E Outfall number 002 (Complete once for each outfall discharging effluent to waters of the United States ) POLLUTANT MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE ANALYTICAL METHOD MLIMDL Conc. Units Mass Units Conc Units Mass Units Number of Samples METALS (TOTAL RECOVERABLE), CYANIDE, PHENOLS, AND HARDNESS ANTIMONY < 3 0 pg/L < 0 056 Ib/d < 3 0 pg/L < 0 056 Ib/d 3 2008 3 ARSENIC < 5 0 pg/L < 0 094 Ib/d < 5 0 pg/L < 0 094 Ib/d 3 311313-04 5 BERYLLIUM 20 pg/L 00375 Ib/d < 1 33 Ng/L < 0 025 Ib/d 3 2007 1 CADMIUM < 1 0 pg/L <0019 Ib/d < 10 pg/L < 0 019 Ib/d 3 311313-04 1 CHROMIUM < 5 0 pg/L < 0 094 Ib/d < 5 0 pg/L < 0 094 Ib/d 3 2007 5 COPPER < 10 pg/L < 0188 Ib/d < 10 pg/L < 0188 Ib/d 3 2007 10 LEAD < 5 0 pg/L < 0 094 Ib/d < 5 0 pg/L < 0 094 Ib/d 3 311313-04 5 MERCURY <10 pg/L <0019 Ib/d <10 pg/L < 0 019 Ib/d 7 1631E 1 NICKEL <10 pg/L < 0188 Ib/d <10 pg/L < 0 188 Ib/d 3 2007 10 SELENIUM <10 pg/L < 0188 Ib/d <10 pg/L < 0 188 Ib/d 3 311313-04 10 SILVER <50 pg/L < 0 094 Ib/d <50 pg/L < 0 094 Ib/d 3 2007 5 THALLIUM <10 pg/L < 0 019 Ib/d <10 pg/L < 0 019 Ib/d 3 2008 1 ZINC 70 pg/L 1 316 Ib/d 4759 pg/L 0 894 Ib/d 3 3111B-99 10 CYANIDE <5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 450OCNE-99 5 TOTAL PHENOLIC COMPOUNDS <5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 4201-78 5 HARDNESS (as CaCO3) 119 mg/L 22330 Ib/d 111 3 mg/L 20892 Ib/d 3 2340C 1 EPA Form 3510-2A (Rev 1-99) Replaces EPA forms 7550-6 & 7550-22 Page 10 of 17 FACILITY NAME AND PERMIT NUMBER PERMIT ACTION REQUESTED' RIVER BASIN City of Havelock WWTP, NCO021253 Renewal Neuse River Outfall number 001 (Complete once for each outfall discharging effluent to waters of the United States ) MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE POLLUTANT ANALYTICAL ML/MDL Number Conc. Units Mass Units Conc. Units Mass Units of METHOD Samples VOLATILE ORGANIC COMPOUNDS ACROLEIN < 100 pg/L < 1 88 Ib/d < 100 pg/L < 1 88 Ib/d 3 EPA 624 100 ACRYLONITRILE < 50 pg/L < 0 939 Ib/d < 50 pg/L < 0 939 Ib/d 3 EPA 624 50 BENZENE <5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 EPA 624 5 BROMOFORM <5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 EPA 624 5 CARBON <5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 EPA 624 5 TETRACHLORIDE CHLOROBENZENE <5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 EPA 624 5 ROMO- < 5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 EPA 624 5 METHANE METHANE CHLOROETHANE <10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 624 10 2-CHLOROETHYLVINYL <5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 EPA 624 5 ETHER CHLOROFORM <5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 EPA 624 5 HLOROBROMO- <5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 EPA 624 5 METHANE ME 1,1-DICHLOROETHANE <5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 EPA 624 5 1,2-DICHLOROETHANE <5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 EPA 624 5 TRANS-1,2-DICHLORO- <5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 EPA 624 5 ETHYLENE - <5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 EPA 624 5 ETHYLENE ETHYLENE 1,2-DICHLOROPROPANE <5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 EPA 624 5 1, LORO- <5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 EPA 624 5 PROPYLOPYLENE ETHYLBENZENE <5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 EPA 624 5 METHYL BROMIDE < 10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 624 10 METHYL CHLORIDE < 10 pg/L < 0 188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 624 10 METHYLENE CHLORIDE <10 pg/L < 0 188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 624 10 1,1,2,2-TETRA- <5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 EPA 624 5 CHLOROETHANE TETRACHLORO- <5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 EPA 624 5 ETHYLENE TOLUENE <5 pg/L I < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 EPA 624 5 EPA Form 3510-2A (Rev 1-99) Replaces EPA forms 7550-6 & 7550-22 Page 11 of 17 FACILITY NAME AND PERMIT NUMBER City of Havelock WWTP, NCO021253 PERMIT ACTION REQUESTED' Renewal RIVER BASIN Neuse River Outfall number 001 (Complete once for each outfall discharging effluent to waters of the United States ) POLLUTANT MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE ANALYTICAL METHOD ML/MDL Conc Units Mass Units Conc. Units Mass Units Number of Samples 1,1,1 TRICHLOROETHANE <5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 LPA 624 5 1'1'2 TRICHLOROETHANE <5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 EPA 624 5 TRICHLOROETHYLENE <5 pg/L < 0 094 Ib/d <5 pg/L < 0 094 Ib/d 3 EPA 624 5 VINYL CHLORIDE <10 pg/L < 0188 Ib/d < 10 pg/L < 0188 Ib/d 3 EPA 624 10 Use this space (or a separate sheet) to provide information on other volatile organic compounds requested by the permit writer TRICHLOROFLUORO METHANE <5 pg/L < 0 094 Ib/d <4 pg/L < 0 094 Ib/d 3 EPA 624 5 ACID -EXTRACTABLE COMPOUNDS P -CHLORO -M -CRESOL < 20 pg/L < 0 375 Ib/d < 20 pg/L < 0 375 Ib/d 3 EPA 625 20 2 -CHLOROPHENOL <10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 2,4-DICHLOROPHENOL <10 pg/L < 0188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 625 10 2,4 -DIMETHYLPHENOL < 10 pg/L < 0 188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 625 10 4,6-DINITRO-0-CRESOL < 50 pg/L < 0 939 Ib/d < 50 pg/L < 0 939 Ib/d 3 EPA 625 50 2,4-DINITROPHENOL < 50 pg/L < 0 939 Ib/d < 50 pg/L < 0 939 Ib/d 3 EPA 625 50 2-NITROPHENOL < 10 pg/L < 0188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 625 10 4-NITROPHENOL < 50 pg/L < 0 939 Ib/d < 50 pg/L < 0 939 Ib/d 3 EPA 625 50 PENTACHLOROPHENOL < 50 pg/L < 0 939 Ib/d < 50 pg/L < 0 939 Ib/d 3 EPA 625 50 PHENOL <10 pg/L < 0188 Ib/d < 10 pg/L < 0188 Ib/d 3 EPA 625 10 2'4'6 TRICHLOROPHENOL <10 pg/L < 0 188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 625 10 BASE -NEUTRAL COMPOUNDS ACENAPHTHENE <10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 ACENAPHTHYLENE <10 pg/L < 0 188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 625 10 ANTHRACENE <10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 BENZIDINE < 100 pg/L < 1 88 Ib/d < 100 pg/L < 1 88 Ib/d 3 EPA 625 100 BENZO(A)ANTHRACENE <10 pg/L < 0188 Ib/d < 10 pg/L < 0 188 Ib/d 3 EPA 625 10 BENZO(A)PYRENE < 10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 EPA Form 3510-2A (Rev 1-99) Replaces EPA forms 7550-6 & 7550-22 Page 12 of 17 FACILITY NAME AND PERMIT NUMBER- PERMIT ACTION REQUESTED RIVER BASIN' City of Havelock WWTP, NC0021253 Renewal Neuse River Outfall number 001 (Complete once for each outfall discharging effluent to waters of the United States ) MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE POLLUTANT ANALYTICAL MLIMDL Number Conc Units Mass Units Conc. Units Mass Units of METHOD Samples 3,4 BENZO- < 10 pg/L < 0188 Ib/d < 10 pg/L < 0188 Ib/d 3 EPA 625 10 FLUORANTHENE BENZO(GHI)PERYLENE < 10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 BENZO(K) < 10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 FLUORANTHENE BIS (2-CHLOROETHOXY) < 10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 METHANE BIS (2-CHLOROETHYL)- <10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 ETHER BIS (2-CHLOROISO- <10 pg/L < 0188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 625 10 PROPYL)ETHER BIS (2-ETHYLHEXYL) < 20 pg/L < 0 375 Ib/d < 20 pg/L < 0 375 Ib/d 3 EPA 625 20 PHTHALATE HE <10 pg/L < 0 188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 625 10 PHENYLETHERR PHENYE BUTYL BENZYL <10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 PHTHALATE 2-CHLORO- <10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 NAPHTHALENE 4-CHLORPHENYL < 10 pg/L < 0188 Ib/d < 10 pg/L < 0188 Ib/d 3 EPA 625 10 PHENYLETHER CHRYSENE < 10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 DI-N-BUTYL PHTHALATE < 10 pg/L < 0188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 625 10 DI-N-OCTYL PHTHALATE <10 pg/L < 0 188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 625 10 DIBENZO(A,H) <10 pg/L < 0188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 625 10 ANTHRACENE 1,2-DICHLOROBENZENE <10 pg/L < 0188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 625 10 1,3-DICHLOROBENZENE <10 pg/L < 0 188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 1,4-DICHLOROBENZENE <10 pg/L < 0 188 Ib/d < 10 pg/L < 0 188 Ib/d 3 EPA 625 10 3,3-DICHLORO- < 50 pg/L < 0 939 Ib/d < 50 pg/L < 0 939 Ib/d 3 EPA 625 50 BENZIDINE DIETHYL PHTHALATE < 10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 DIMETHYL PHTHALATE <10 pg/L < 0 188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 625 10 2,4-DINITROTOLUENE <10 pg/L < 0 188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 625 10 2,6-DINITROTOLUENE <10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 1,2-DIPHENYL- <10 pg/L < 0188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 625 10 HYDRAZINE EPA Form 3510-2A (Rev 1-99) Replaces EPA forms 7550-6 & 7550-22 Page 13 of 17 FACILITY NAME AND PERMIT NUMBER PERMIT ACTION REQUESTED' RIVER BASIN City of Havelock WWTP, NCO021253 Renewal Neuse River Outfall number 001 (Complete once for each outfall discharging effluent to waters of the United States ) MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE POLLUTANT ANALYTICAL MLIMDL Number Conc Units Mass Units Conc. Units Mass Units of METHOD Samples FLUORANTHENE < 10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 FLUORENE <10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 HEXACHLOROBENZENE <10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 HEXACHLORO- <10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 BUTADIENE HEXACHLOROCYCLO- < 50 pg/L < 0 939 Ib/d < 50 pg/L < 0 939 Ib/d 3 EPA 625 50 PENTADIENE HEXACHLOROETHANE <10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 INDENO(1,2,3-CD) <10 pg/L < 0188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 625 10 PYRENE ISOPHORONE < 10 pg/L < 0188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 625 10 NAPHTHALENE <10 pg/L < 0188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 625 10 NITROBENZENE <10 pg/L < 0188 Ib/d < 10 pg/L < 0188 Ib/d 3 EPA 625 10 N-NITROSODI-N- <10 pg/L < 0188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 625 10 PROPYLAMINE N-NITROSODI- <10 pg/L < 0188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 625 10 METHYLAMINE N-NITROSODI- <10 pg/L < 0188 Ib/d <10 pg/L < 0 188 Ib/d 3 EPA 625 10 PHENYLAMINE PHENANTHRENE <10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 PYRENE <10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 1,2,4- <10 pg/L < 0188 Ib/d <10 pg/L < 0188 Ib/d 3 EPA 625 10 TRICHLOROBENZENE END OF PART D. REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS OF FORM 2A YOU MUST COMPLETE EPA Form 3510-2A (Rev 1-99) Replaces EPA forms 7550-6 & 7550-22 Page 14 of 17 FACILITY NAME AND PERMIT NUMBER PERMIT ACTION REQUESTED' RIVER BASIN• City of Havelock WWTP, NCO021253 Renewal Neuse River SUPPLEMENTAL APPLICATION INFORMATION PART E. TOXICITY TESTING DATA POTWs meeting one or more of the following criteria must provide the results of whole effluent toxicity tests for acute or chronic toxicity for each of the facility's discharge points 1) POTWs with a design flow rate greater than or equal to 1 0 mgd, 2) POTWs with a pretreatment program (or those that are required to have one under 40 CFR Part 403), or 3) POTWs required by the permitting authority to submit data for these parameters • At a minimum, these results must include quarterly testing for a 12 -month period within the past 1 year using multiple species (minimum of two species), or the results from four tests performed at least annually in the four and one-half years prior to the application, provided the results show no appreciable toxicity, and testing for acute and/or chronic toxicity, depending on the range of receiving water dilution Do not include information on combined sewer overflows in this section All information reported must be based on data collected through analysis conducted using 40 CFR Part 136 methods In addition, this data must comply with QA/QC requirements of 40 CFR Part 136 and other appropriate QA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136 • In addition, submit the results of any other whole effluent toxicity tests from the past four and one-half years If a whole effluent toxicity test conducted during the past four and one-half years revealed toxicity, provide any information on the cause of the toxicity or any results of a toxicity reduction evaluation, if one was conducted • If you have already submitted any of the information requested in Part E, you need not submit it again Rather, provide the information requested in question E 4 for previously submitted information If EPA methods were not used, report the reasons for using alternate methods If test summaries are available that contain all of the information requested below, they may be submitted in place of Part E If no biomonitonng data is required, do not complete Part E Refer to the Application Overview for directions on which other sections of the form to complete E 1 Required Tests apa_abw QVKhDV Q d3 pondln0 poo E �O bo- U@FA . a. o d CLQ Pcc.)ad @Roc C3 FQ-@URO�3 � M@0�0, A ZDl gDd dc,@ 8@Sd@w uc@MQ �-tll W embb@aWcd pffca Qo Lftc rq-,A k,'@ @R QW,15 pC-Fi7mB3 gra JUFRD �& 203 1Go Indicate the number of whole effluent toxicity tests conducted in the past four and one-half years ❑ chronic ❑ acute E 2 individual Test Data Complete the following chart for each whole effluent toxicity test conducted in the last four and one-half years Allow one column per test (where each species constitutes a test) Copy this page if more than three tests are being reported Test number Test number Test number a Test information Test Species & test method number Age at initiation of test Outfall number Dates sample collected Date test started Duration b Give toxicity test methods followed Manual title Edition number and year of publication Page number(s) c Give the sample collection method(s) used For multiple grab samples, indicate the number of grab samples used 24 -Hour composite Grab d Indicate where the sample was taken in relation to disinfection (Check all that apply for each Before disinfection After disinfection After dechlonnation EPA Form 3510-2A (Rev 1-99) Replaces EPA forms 7550-6 & 7550-22 Page 15 of 17 FACILITY NAME AND PERMIT NUMBER' City of Havelock WWTP, NCO021253 PERMIT ACTION REQUESTED Renewal RIVER BASIN• Neuse River Test number Test number Test number, e Describe the point in the treatment process at which the sample was collected Sample was collected f For each test, include whether the test was intended to assess chronic toxicity, acute toxicity, or both Chronic toxicity Acute toxicity g Provide the type of test performed Static Static -renewal Flow-through h Source of dilution water If laboratory water, specify type, if receiving water, specify source Laboratory water Receiving water I Type of dilution water If saltwater, specify "natural' or type of artificial sea salts or brine used Fresh water Salt water Give the percentage effluent used for all concentrations in the test series k Parameters measured during the test (State whether parameter meets test method specifications) pH Salinity Temperature Ammonia Dissolved oxygen I Test Results Acute Percent survival in 100% effluent LC50 95% C I % % % Control percent survival % % % Other (describe) EPA Form 3510-2A (Rev 1-99) Replaces EPA forms 7550-6 & 7550-22 Page 16 of 17 FACILITY NAME AND PERMIT NUMBER PERMIT ACTION REQUESTED RIVER BASIN City of Havelock WWTP, NCO021253 Renewal Neuse River Chronic NOEC % % % C25 % % % Control percent survival % % % Other (describe) m Quality Control/Quality Assurance Is reference toxicant data available? Was reference toxicant test within acceptable bounds? What date was reference toxicant test run (MM/DD/YYYY)? Other (describe) E 3 Toxicity Reduction Evaluation Is the treatment works involved in a Toxicity Reduction Evaluation? ❑ Yes ❑ No Ifyes, describe E 4 Summary of Submitted Biomonitormg Test Information If you have submitted biomorntonng test information, or information regarding the cause of toxicity, within the past four and one-half years, provide the dates the information was submitted to the permitting authority and a summary of the results Date submitted / / (MM/DD/YYYY) Summary of results (see instructions) END OF PART E. REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS OF FORM 2A YOU MUST COMPLETE. EPA Form 3510-2A (Rev 1-99) Replaces EPA forms 7550-6 & 7550-22 Page 17 of 17 City of Havelock Wastewater Treatment Plant City of Havelock, North Carolina EPA Form 2A Additional Information City of Havelock WWTP Permit No. NCO021253 Outfall 002 Additional Information B.2 Topographic Map See Figure 1 for topographic map and Figure 2 for plant site map. B.3.1 Process Flow Description — Permitted Capacity of 2.25 mgd The Havelock WWTP provides advanced wastewater treatment, including nitrogen removal, to meet effluent limits for discharge to the Neuse River. The major processes at the WWTP include screening, grit removal, a single - stage nitrification activated sludge process, denitrification filters, ultraviolet disinfection, re -aeration, gravity belt thickening, and stabilized solids storage. As part of the Phase 1 WWTP expansion, completed in May 2015, an effluent pump station, an outfall pipeline, a cascade aerator, and a diffuser in the Neuse River were constructed. Screening Influent wastewater is conveyed to the Havelock WWTP by a combination of gravity interceptors and force mains. The influent flow is combined into a 24 - inch pipeline at the screening facility that passes through a bar screen designed to remove large solids and debris from the influent wastewater to prevent clogging and interference with operation of downstream pumps and other process equipment. Grit Removal After passing through the bar screen, the influent wastewater flows to a vortex (Pista) grit collector through a 24 -inch pipe. After the grit is removed, the grit collector effluent flows to the influent pump stations. Influent Pump Stations The Havelock WWTP is equipped with two influent pump stations. Effluent from the grit removal facility flows through an 18 -inch pipe to a tee with a 20 - inch pipe. The 20 -inch pipe interconnects two wet wells, which are used in combination with pumps to convey the influent wastewater to the aeration basins. Each influent pump station is comprised of a wet well and three influent pumps. One influent pump station contains three submersible pumps. The second influent pump station is a dry pit/ wet pit configuration with three pumps. All pumps are controlled via float switches in the wet well to keep 0 \30906\006\ENG\Task 040-WWTP NPDES Permit Renewal\Tab B\Form 2A -Additional Information 2017 doc City of Havelock WWTP Permit No. NCO021253 Outfall 002 pace with the plant influent flow rate. In addition to raw wastewater, return activated sludge (RAS) from the secondary treatment stage is returned to the influent pump station for conveyance to the aeration basin distribution box. Flow from the influent pump stations are conveyed through 10 -inch and 12 - inch pipes to the aeration basin distribution box. Activated Sludge System The purpose of the activated sludge system is to achieve the BOD removal, phosphorus removal, and nitrification necessary to comply with the stringent effluent requirements in the permit. The activated sludge system includes fine and coarse bubble aeration basins, intermediate pumping, final clarifier distribution box, final clarifiers, and RAS and waste activated sludge (WAS) conveyance. Fine Bubble Aeration Wastewater enters the fine bubble aeration basins mixed with RAS through a distribution box. Two sharp -crested weirs split the flow equally between two aeration basins. The two circular tanks are equipped with a fine bubble aeration system with ceramic disc diffusers. The diffusers provide the dissolved oxygen and mixing necessary for operation of the activated sludge process. Coarse Bubble Aeration The mixed liquor from each of the fine bubble aeration basins flows through 16 -inch pipes to the coarse bubble aeration basins for additional BOD removal and/or nitrification. The three coarse bubble aeration basins are operated in series in normal operation and are equipped with a coarse bubble aeration system. Final Clarifier Pump Station Effluent from the second -stage aeration basin flows by gravity to the final clarifier pump station wet well via 16 -inch piping. The Final Clarifier Pump Station lifts the mixed liquor to a high enough elevation that the wastewater can flow by gravity through the rest of the treatment plant. A 20 -inch pipe conveys the pumped flow from the final clarifier pump station to the final clarifier distribution box. A polyaluminum chloride (PACT) storage and feed system is provided to feed PACI to the Final Clarifier Pump Station discharge to enhance suspended solids removal and provide phosphorus removal in the final clarifiers via precipitation. 0 13090610061ENGUask 040-WWTP NPDES Permit Renewal%Tab B%Form 2A -Additional Information 2017 doc 2 City of Havelock WWTP Permit No. NCO021253 Outfall 002 Final Clarifiers Two 65 -foot diameter clarifiers are provided to settle out solids from the mixed liquor. The final clarifiers provide quiescent flow conditions to allow the mixed liquor solids to settle to the bottom of the clarifiers. The settled solids are either returned to the first -stage aeration basins as RAS or wasted to the Waste Solids Holding Tank as WAS. The clarified effluent flows over the final clarifier effluent V -notch weirs to the denitrification filters, where the wastewater undergoes further treatment. RAS and WAS Conveyance The RAS and WAS Control Stations control the flow rate of settled activated sludge from the final clarifiers to the influent pump stations and the Waste Solids Holding Tank, respectively. WAS flows to the Waste Solids Holding Tank, and from there is periodically pumped to the gravity belt thickeners for thickening prior to stabilization and ultimate disposal. The RAS and WAS flows are measured by four strap -on ultrasonic flow meters, with one RAS flow meter and one WAS flow meter for each clarifier. RAS and WAS are conveyed by gravity and manually -operated pinch valves downstream of the flow meters are used to control the flow rates. Denitrification Filters The denitrification filters remove additional suspended solids from the final clarifier effluent and remove nitrogen through denitrification to comply with the total nitrogen limit. Final clarifier effluent flows by gravity to three denitrification filters. An underdrain system collects the filtered wastewater and directs it to a 20 -inch pipe that flows by gravity to the disinfection facilities. The Havelock WWTP uses methanol as its carbon source, and typically adds between 40 and 80 gallons per day to the filters. Backwash water is drained to the Filter Backwash Waste Detention Basin, and from there is returned to the influent pump stations. Ultraviolet Disinfection Disinfection is accomplished using ultraviolet (UV) disinfection technology. Filtered wastewater effluent enters the UV disinfection facilities through a 16 - inch and 20 -inch parallel pipeline. The old chlorine contact tank was retrofitted to accommodate the UV modules and now serves as the disinfection channel. 0 \30906\006\ENG\Task 040-WWTP NPDES Permit Renewal\Tab Worm 2A -Additional Information 2017 doc 3 City of Havelock WWTP Permit No. NCO021253 Outfall 002 Re -aeration The re -aeration facilities are located at the Re -aeration Basin and can be used to provide additional dissolved oxygen in the UV disinfection effluent. Two platform -mounted mechanical surface aerators are provided in the Re- aeration Basin. The backwash supply pumps for the denitrification filters are also located in the Re -aeration Basin. Effluent Pump Station The effluent pump station conveys flow through approximately 30,000 linear feet of 24 -inch piping to the Neuse River. Cascade Aerator Prior to discharging into the Neuse River, the effluent passes through a cascade aerator. The cascade aerator is located near the bank of the Neuse River and increases the effluent's dissolved oxygen levels to meet permit requirements. Diffuser in the Neuse River After passing through the cascade aerator, the effluent discharges into the Neuse River through a multi port diffuser located approximately 2,040 feet from the shoreline. Please reference Figure 3 for the process flow diagram at a permitted capacity of 2.25 mgd. B.3.2 Process Flow Description — Future Permitted Flow Capacity of 2.8 mgd The process flow at a permitted capacity of 2.8 mgd will be the same as at 2.25 mgd, with the exception that the Activated Sludge system will be upgraded to a 3 -Stage BNR basin to meet nutrient limits. Please reference Figure 4 for the process flow diagram at a permitted capacity of 2.8 mgd. 0 \30906\DO6\ENG\Task 040-W W TP NPDES Permit Renewal\Tab B\Fonn 2A- Additional Information 2017 doc 4 City of Havelock WWTP Permit No. NCO021253 Outfall 002 B.3.3 Process Flow Description — Future Permitted Flow Capacity of 3.5 mgd The process flow at a permitted capacity of 3.5 mgd will be the same as at 2.25 mgd, with the exception that the Activated Sludge system will be upgraded to a 5 -Stage BNR basin to meet nutrient limits. Please reference Figure 5 for the process flow diagram at a permitted capacity of 3.5 mgd. 0 \309061006\ENG\Task 040-WWTP NPDES Permit Renewal\Tab Worm 2A -Additional Information 2017 doc 5 Effluent Discharge Location 002 Constructed as Part of Phase 1 of WWTP Expansion Lat 34° 57' 11" ,uv Long 76° 52'37" '1Y. Cascade Aerator 7t \ *,.+ { t T 10 NVA:; , r -� X l � �' "• - ,rte" / � / � __. ,.. Its r I li`4 4 I RESt.6VATl �. i v IT ! w l!t.RRY INT --� V Ir $' Effluent Outfall Pi eline !' / Z - —r-- G t 4 �U S Marine Ct>•'ps At, Cherry Pouu . City of Havelock WWTP Site>, Influent Force Main I.+ r t Parallel Interceptors kw Copyright:© 2013"National, Geographic Society. cubed, Influent Force Mains N Figure 1 —Grev'tylnterceptos r v ` ` ' fWWTP Location Map 24-inch Effluent Pipe w� E VV � � City of Havelock, NC USATopoMaps s NCO021253 0 U OA 0.8B.2 of Form 2A Miles �Pnrcin�''..` 0:\30906\006\ENG\Task 040-WWTP NPDES Permit Renewal\WWTP Location map -Figure t.mxd rroay, Novemoer z4, w FINAL CLARIFIER NOA 30906-012 Figure 2. cdr CONTROL BUILDING ❑ ❑ ENGINE GENERATOR TRANSFORMER BUILDING BAR SCREEN AND GRIT REMOVAL (BYPASS UNIT) AERATION BASIN DISTRIBUTION BOX C STABILIZED SOLIDS HOLDING BASIN C FINE BUBBLE AERATION BASIN NO. 2 FINE BUBBLE AERATION BASIN NO. 1 `) � C0 O 111��� ��� INFLUENT PUMPING STATIONS 0 j� GRIT REMOVAL BAR 1 1 SCREEN SOLIDS HANDLING BUILDING O O SLUDGE UV PUMPING DISINFECTION STATION BASIN � REAERATION BASIN OEFFLUENT PUMPING STATION Figure 2 WWTP Site Map City of Havelock, NC NCO021253 13.2 of Form 2A a BLOWER BUILDING N0.2 ICAL STORAGE EED FACILITY FINAL CLARIFIER PUMPING STATION HIANDMI COARSE BUBBLE _ _- COARSE BUBBLE AERATION BASINS AERATION BASIN NO. 1 & 2 NO, 3 O FILTER BACKWASH WASTE DETENTION BASIN DENITRIFICATION FILTERS FINAL CLARIFIER WASTE SOLIDS HOLDING TANK NO.2 FINAL CLARIFIER WAS CONTROL STATION FLOW DISTRIBUTION STRUCTURE RAS CONTROL mInzIm,_ STATION FINAL CLARIFIER NOA 30906-012 Figure 2. cdr CONTROL BUILDING ❑ ❑ ENGINE GENERATOR TRANSFORMER BUILDING BAR SCREEN AND GRIT REMOVAL (BYPASS UNIT) AERATION BASIN DISTRIBUTION BOX C STABILIZED SOLIDS HOLDING BASIN C FINE BUBBLE AERATION BASIN NO. 2 FINE BUBBLE AERATION BASIN NO. 1 `) � C0 O 111��� ��� INFLUENT PUMPING STATIONS 0 j� GRIT REMOVAL BAR 1 1 SCREEN SOLIDS HANDLING BUILDING O O SLUDGE UV PUMPING DISINFECTION STATION BASIN � REAERATION BASIN OEFFLUENT PUMPING STATION Figure 2 WWTP Site Map City of Havelock, NC NCO021253 13.2 of Form 2A Grit Removal Plant Influent Q=2.25 mgd Bar ScreensZZ Q=2.25 mgd Q=2.25 mgd o --e:=> Cascade Aerator Ll:� Diffuser in Neuse River 30906-012 Figure 3. cdr Grit Q=2.25 mgd Q=3.55 mgd Legend FBW = Filter Backwash FBWR = Filter Backwash Return RAS = Return Activated Sludge WAS = Waste Activated Sludge TWAS = Thickened Waste Activated RAS Q=1.13 mgd Sludge EM =Flow Meter Aeration Basin i Distribution -� Box ► Fine Bubble Coarse Bubble Influent Pump Aeration Basins Aeration Basins Final Clarifier Stations Pump Station RAS Q=1.13 mgd FBWR Q=0.15 mgd FBW Waste Reaeration Detention Basin Tank Methanol Q=2.4 mgd � EU CU cur, UV Disinfection Effluent Pump Denitrification Station FBW Q=0.15 mgd Filters Q=0.02 mgd Polymer Polyaluminum Chloride Q=3.55 mgd Final f'-- Distribution Clarifiers Box Q=1.15 mgd Stabilized TWAS Pumps Gravity Belt GBT Feed Pump Waste Solids WAS Control RAS Control Solids Holding Thickener Holding Tank Station Station Basin Q=0.01 mgd Q=0.03 mgd Q=0.03 mgd Q=1.13 mgd 40 �O�aaaC, Truck Hauling �I to Land Application F Q=2.8 mgd Grit Removal Plant Influent ♦ Bar Screens 10 Influent Pump Stations Grit FBWR 0- Cascade Aerator Diffuser in Neuse River 30906-012 Figure 3.cdr Q=4.4 mgc, FBW Waste Reaeration Detention Basin Tank CQCQED Z- A- C C c� 3 Stage BNR Basin RAS Q=1.4 mgd Methanol Q=3.0 mgd 1 Effluent Pump UV Disinfection Denitrification Station FBW Q=0.2 mgd Filters Q=0.024 mgd Polymer Stabilized TWAS Pumps Gravity Belt GBT Feed Pump Waste Solids WAS Control Solids Holding Thickener Holding Tank Station Basin Q=0.014 mgd Q=0.038 mgd 47-0.038 mgd 'ilk Truck Hauling 'I IV' to Land Application Legend FBW = Filter Backwash FBWR = Filter Backwash Return RAS = Return Activated Sludge WAS = Waste Activated Sludge TWAS = Thickened Waste Activated Sludge FM =Flow Meter Final Clarifier Pump Station Polyaluminum Chloride Q=4.4 mgd Final Distribution Clarifiers Box Q=1.4 mgd RAS Control Station Q=1.4 mgd Plant Influent Bar Screens Q=3.5 mgd o� Cascade Aerator Diffuser in Neuse River 30906-012 Grit Removal F Q=3.5 mgd Influent Pump Stations Q=5.5 mgd Legend FBW = Filter Backwash FBWR = Filter Backwash Return RAS = Return Activated Sludge WAS = Waste Activated Sludge TWAS = Thickened Waste Activated Sludge =Flow Meter 00 • • °eP• t7-� ° b°■ • . • fie. +�• Grit FBWR _f� Polyaluminum Methanol Chloride FBW Waste Q=3.75 mgd Q=5.5 mgd Reaeration Detention Basin Tank M Final Distribution Clarifiers Box Effluent Pump UV Disinfection DenitrificaiMM tion Station FBW Q=0.25 mgd Filters Q=1.8 mgd Q=0.03 mgd Polymer IF � �jgvt M M Stabilized TWAS Pumps Gravity Belt GBT Feed Pump Waste Solids WAS Control RAS Control Solids Holding Thickener Holding Tank Station Station Basin Q=0.02 mgd Q=0.05 mgd 0=0.05 mgd — LQ=1.75 mgd Truck Hauling to Land Application City of Havelock Wastewater Treatment Plant City of Havelock, North Carolina Sludge Management Plan (Including Land Application Permit and Agreement with Synargo) Solids Treatment Solids in the form of WAS from the Havelock WWTP currently undergo further treatment for eventual disposal as a land application product. The existing solids processing facilities include thickening, WAS holding tank, one 1 -meter gravity belt thickener (GBT), polymer feed system, GBT feed pumps, thickened WAS (TWAS) feed pumps, and a stabilized solids holding basin. The solids thickening process is designed to reduce the volume of WAS from the activated sludge process. WAS is removed from the final clarifiers and drained by gravity to the Waste Solids Holding Tank for short-term storage prior to thickening. Each clarifier has a separate wasting line and pinch valve in the WAS Control Station for controlling WAS flow to the Waste Solids Holding Tank. Flow meters in the WAS Control Station indicate WAS flow rate for each final clarifier. Submersible pumps are provided in the Waste Solids Holding Tank for pumping WAS to the gravity belt thickeners in the Solids Handling Building. Chemical conditioning of the solids with polymer is provided to separate the flocculated solids from the free water. The thickened waste activated sludge (TWAS) from the GBT is collected in a thickened solids hopper, from which it is pumped to the Solids Stabilization Tank by two TWAS pumps. Free water is drained back to the Influent Pump Station. The stabilized solids holding basin is used to store thickened stabilized solids prior to liquid land application on permitted privately -owned farmland. Piping is provided for withdrawal of solids from the holding basin and to load the solids into a truck. Decanting of supernatant to the influent pump stations is also possible using a portable pump. NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES RALEIGH LAND APPLICATION OF CLASS B WASTEWATER TREATMENT PLANT RESIDUALS PERMIT (NON -DEDICATED) In accordance with the piovisions of Article 21 of Chapter 143, General Statutes of North Carolina as amended, and other applicable Laws, Rules, and Regulations PERMISSION IS HEREBY GRANTED TO City of Havelock Craven County FOR THE continued operation of a residuals management program for the City of Havelock and consisting of the land application of Class B Wastewater Tieatment Plant iesiduals generated by the approved facilities listed in Attachinent A to the approved sites listed in Attachment B with no discharge of wastes to surface waters, pursuant to the application received Januaiy 20, 2015, and in conformity with other suppoi ting data subsequently filed and approved by the Department of Environment and Natural Resources and considered a part of this permit. The use and disposal of residuals arc iegulated under Title 40 Code of Federal Regulations Pat 503. This perinnit does not exempt the Permittee from complying with the federal regulations. This pennit shall be effective fionn the date of issuance until March 31, 2017, shall void Permit No WQ0000702 issued April 7, 2008, and shall be subject to the follownng specified conditions and limitations I. SCHEDULES No later than six months prior to the expiration of this permit, the Permittee shall request ienewal of this pei mit on official Division forms Upon receipt of the request, the Division will review the adequacy of the facilities described therein, and if warranted, will i enew the permit for such period of time and undei such conditions and limitations as it may deem appropriate Please note Rule 15A NCAC 02T .0105(d) requires an updated site map to be submitted with the permit renewal application. [15A NCAC 02T .0108(b)(2), 02T .105(4), 02T .0109] 2. The Permittee shall be in full compliance with the regional office notification requirements established in Condition III 3. within 90 days of the effective date of this permit. [15A NCAC 02T .0108(b)(2)] 3 The Permittee shall subnut the Operation and Maintenance (O&M) plan as required in Condition II14 to the Division within 90 days of the effective date of this permit. [15A NCAC 02T 0108(b)(2)] WQ0000702 Veision 3 2 Slicll Version 150101 Page 1 of 12 4 The Permittee shall be in firll compliance with the signage requirements established in Condition 111 13 within 180 days of the effective date of this permit [15A NCAC 02T 0108(b)(2)] ll. PERFORMANCE STANDARDS The subject residuals management program shall be effectively maintained and operated at all times so there is no discharge to surface waters, inor any contravention of gnoundwatei or sulfate water standards. In the event the facilities fail to perform satisfactorily, including the creation of nuisance conditions due to nnploper operation and iliamtenance, the Perinittee shall immediately cease land applying residuals to the site, contact the Washington regional office supervisor, and take any immediate coinective actions. [G.S. 143-215.1] 2 Tlus permit shall not relieve the Pernuttee of responsibility for damages to groundwater or suiface water resulting fiom the operation of this iesiduals management program [15A NCAC 02B .0200, 02L .0100] 3. Only residuals generated by the facilities listed nn Attacluuent A ale approved for laud application in accordance with this peanut [G S 143-215 1] 4. Only the sites listed in Attachment B are approved for residuals land application. [G.S 143-215.1] 5 Pollutant concentrations in residuals applied to land application sites listed in Attachment B shall not exceed the following Ceiling Concentrations (i e., dry weight basis) or Cumulative Pollutant Loading Rates (CPLRs): Parameter Ceiling Concentration (nnIligrains per Idlograin) CPLR (poiinds per acre) Ai seine 75 36 Cadmium 85 34 Coppet 4,300 1,338 Lead 840 267 Mei cury 57 15 Molybdenum 75 n/a Nickel 420 374 Selenium 100 89 Zinc 7,500 2,498 The Permittee shall deternune compliance with the CPLRs using one of the following methods. a. By calculating the existing cumulative level of pollutants using actual analytical data from all historical land application events of residuals, or b. Foi land where residuals application have not occurred or foi which the required data is incomplete, by determining background concentrations through representative soil sampling [I 5A NCAC 02T. 1105] 6 Residuals that are land applied shall meet Class B pathogen reduction requirements in 15A NCAC 02T 1106 (a) and (c) Exceptions to this requirement shall be specified in Attaclnnent A. [15A NCAC 02T 1106] WQ0000702 Version 3 2 Shell Veision 150101 Page 2 of 12 7. Biological residuals (i.e. residuals genciatcd during the treatment of domestic or anunal piocessing wastewater, or the biological treatment of industrial wastewater, and as identified in Attachrnent A) that ale land applied shall meet one of the vector attraction reduction alternatives in 15A NCAC 02T .1107(a). Exceptions to this requirement shall be specified in Attachrnent A [15A NCAC 02T .1107] 8 Setbacks for Class B land application sites shall be as follows - [15A NCAC 02T 1108] 9. Land application areas shall be clearly masked on each site prior to and during any residuals application event. [15A NCAC 02T .0108(b)(1)] 10. Bulls residuals and other sources of Plant Available Nitrogen (PAN) shall not be applied in exceedance of agronomic rates. Appropuate agronomic rates shall be calculated using expected nitrogen iequiiements based on the determined Realistic Yield Expectations (RYE) using any of the following methods - a Division's pie -approved site specific historical data for specific crop of soil types by calculating the mean of the best three yields of the last five consecutive crop harvests for each field. WQ0000702 Version 3.2 Shell Version 150101 Page 3 of 12 Setback by application type (feet) Setback Description Vehicular Iuigation Surface Surface Li�ection/ Application Application hncorporation Habitable residence or place of public assembly under separate ownership of not to be maintained as 400 400 200 art of the project site Habitable residence or places of public assembly owned by the Permittee, the owner of the land, of the lessee/operator of the land to be maintained as part 0 200 0 of the piojcct site Property lines 50 150 50 Public riglit of way 50 50 50 Pi ivate or public water supply 100 100 100 Sulfate waters (streams — internuttent and peiemnial' perennial wateibodies, and wetlands 100 100 50 Surface water diveisions (ephemeral streams' wateiways, ditches) 25 100 25 Groundwater lowering ditches (where the bottom of the ditch intersects the SHWT) 25 100 25 Subsurface groundwater loweirng system 0 100 0 Wells with exception to monitoring wells 100 100 100 Bedi ock outcrops 25 25 25 Top of slope of embanlanents or cuts of two feet of more in ver tical height 15 15 15 Building foundations or basements 0 15 0 Watel lilies 0 10 0 Swtnlllllllg pools 100 100 100 Nits ification fields 0 20 0 [15A NCAC 02T 1108] 9. Land application areas shall be clearly masked on each site prior to and during any residuals application event. [15A NCAC 02T .0108(b)(1)] 10. Bulls residuals and other sources of Plant Available Nitrogen (PAN) shall not be applied in exceedance of agronomic rates. Appropuate agronomic rates shall be calculated using expected nitrogen iequiiements based on the determined Realistic Yield Expectations (RYE) using any of the following methods - a Division's pie -approved site specific historical data for specific crop of soil types by calculating the mean of the best three yields of the last five consecutive crop harvests for each field. WQ0000702 Version 3.2 Shell Version 150101 Page 3 of 12 b Noitli Carolina Historical Data for specific crop and soil types as provided by North Carolina State University Depa.tnnent of Soil Science(littp://iiutrieiits.soil.ncsti.edu/yields/ilidex.l)lip). A copy shall be kept on file and reprinted every five yeais in accordance with Condition IV.5. c. If the RYE cannot be determined using methods (a) of (b) above, the Permittee may use the RYE- and YEand appropi rate nutrier_t application rates reported in any of the following documents I Crop management plan as outlined by the local Cooperative Extension Office, the North Carolina Department of Agriculture and Consumer Services, the Nahual Resource Conservation Service, or other agronomist ii Waste Utilization Plan as outlined by the Senate Bill 1217 Interagency Group - Guidance Document. Chapter I (littp://www.iicagr izov/SWC/teclm/docutmments/9th Guidance Doc 100109 ])df) in Certified Nutrient Management Plan as outlined by the Natural Resources Conservation Services (NRCS). These plans must meet the USDA-NRCS 590 Nutrient Management Standards (ftp-Hftp-fc sc.egov.usda gov/NHQ/pi-actice-staiidal-ds/staiidards/590.pdf). d If the RYE and appropriate nutrient application rates cannot be determined, the Permittee shall contact the Division to determine necessary action. [15A NCAC 02T .1109(b) (1) (k)] 11 When residuals are land applied to grazed pasture, hay crop realistic nitrogen rate shall be reduced by 25% um accordance with the USDA-NRCS 590 Nutrient Management Standards. [15A NCAC 02T 0108(b)(1)] 12 If land application sites are to be over -seeded or double -cropped (e g, bermuda grass in the sununer and rye grass in the winter with both crops to receive residuals), then the second clop can receive an application of PAN at a rate not to exceed 50 pounds per acre per year (lbs/ac/yr) This practice may be allowed as long as the second crop is to be harvested or grazed If the second crop is to be planted for erosion control only and is to be tilled into the soil, then no additional PAN shall be applied. [15A NCAC 02T 0108(b)(1)] 13. Prior to land application of residuals containing a sodium adsoiptioti intro (SAR) of 10 or lughet, the Permittee shall obtain and implement recommendations fiorn at least one of the following, the local Cooperative Extension Office; the Department of Agi iculture and Consumer Ser vices, the Naluial Resource Conservation Service, a North Carolina Licensed Soil Scientist; of an agronomist. The recommendations shall address the sodium application rate, soil amendments (e g, gypsum, etc.), of a mechanism for maintaining ;rte integrity and conditions conducive to crop growth. The Permittee shall maintain written recores of these reconunnendations and details of their implementation [15A NCAC 02T .0108(b)(1)] 14 These residuals land application sites were individually permitted on or after December 30, 1983; therefore, the compliance boundary is established at either 250 feet from the residual land application area, or 50 feet within the property boundary, whichever is closest to the residual land application area. An exceedance of groundwater standards at or beyond the compliance boundary is subject to remediation action according to 15A NCAC 02L .0106(d) (2) as well as enforcement actions in accordance with North Carolina General Statute 143-215.6A through 143-215.60. Any approved relocation of the COMPLIANCE BOUNDARY will be noted in Attachment B. [15A NCAC 02L 0107(a)] 15. The review boundary shall be established midway between the compliance boundary and the residual land application area. Any exceedance of groundwater standards at the review boundary shall require action um accordance with 15A NCAC 02L .0106 [15A NCAC 02L .0108] WQ0000702 Version 3.2 Shell Version 150101 Page 4 of 12 III. OPERATION AND MAINTENANCE REQUIREMENTS The residuals management program shall be properly maintained and operated at all times The program shall be effectively maintained and operated as a non -discharge system to prevent any contravention of surface water of groundwater standards. [15A NCAC 02T 1110] 2. The Washington Regional Office, telephone number (252) 946-6481, and the appropriate local govcinnnent official (i e., county manager, city managei, or health director) shall be notified at least 48 1noLrls pllor to the Initial residuals land application to any new land application site Notification to the regional supervisoi shall be made from 8:00 a.m. until 5:00 p in on Monday through Friday, excluding State Holidays. [15A NCAC 02T .0108(b)(1)] 3 The Washington Regional Office shall be notified via email or telephone, (252) 946-6481, at least 24 hours prioi to conducting any land application activity. Such notification shall indicate, at a minimum, the anticipated application times, field IDs, and location of land application activities If it becomes necessaiy to apply to additional fields due to unforeseen events, the Regional Office shall be notified pi ioi to commencing the application to those fields [I 5A NCAC 02T .0108(b)(1)] The Pcrnuttee shall maintain an approved Opeiation and Maintenance Plan (O&M Plan) Modifications to the O&M Plan shall be approved by the Division prioi to utilization of the new plan The O&M Plan, at the minimum, shall include. a. Operational functions, b. Maintenance schedules; c Safety measures; d Spill response plan, e. Inspection plan including the following i nfonnation i. Names and/or titles of personnel responsible for conducting the inspections, n Frequency and location of inspections, Including those to be conducted by the ORC, and procedures to assure that the selected location(s) and inspection frequency are representative of the residuals management program; ur. Detailed description of inspection procedures including record keeping and actions to be taken by the inspector in the event that noncompliance is observed pursuant to tine noncompliance notification requirements under the monitoring and reporting section of the permit; Sampling and monitoring plan including the following information. I Names and/or titles of personnel responsible for conducting the sampling and monitoring, it Detailed desci iption of monitoring procedures including parameters to be monitored; in Sampling frequency and procedures to assure that representative samples are being collected Fluctuation in temperature, flow, and other operating conditions can affect the quality of the residuals gathered during a particular sampling event. The sampling plan shall account for any foreseen fluctuations in residuals quality and indicate the most lrnniting times for residuals to meet pathogen and vector attraction reduction requirements (e g. facilities that land apply multiple times per year but have an annual sampling frequency, may need to sample during winter months when pathogen reduction is most likely to be negatively affected by cold temperatures) [15A NCAC 02T. I 1001 WQ0000702 Version 3.2 Slicll Version 150101 Page 5 of 12 5 Upon the Watei 13ollutron Control System Opeiators Certification Collulusslon's (WPCSOCC) classification of the facility, the Peinuttee shall designate and employ a certified operator in responsible charge (ORC) and one of more certified operators as back-up ORCs in accordance with 15A NCAC 08G .0201. The ORC of his back-up shall visit the facilities in accordance with 15A NCAC 08G 0204, or as specified in the most recently approved O&M plan (i.e., see Condition I1I 4 ), and shall comply with all other conditions of 15A NCAC 08G. 0204. Fol mole information regarding classification and designation requirements, please contact the Division of Water Resources' Protection and LCnforcenlent Branch at (919) 707-9105. [ 15A NCAC 02T .01 17] 6. When the Permittee land applies bulk residuals, a copy of this permit and a copy of O&M Plan shall be maintained at the land application sites during land application activities. [15A NCAC 02T 0108(b)(1)] 7 When the Permittee transports of laud applies bulk residuals, the spill control Provisions shall be maintained mail residuals transport and application vehicles [15A NCAC 02T 1 1 10] 8 Residuals shall not be stored at any land application site, unless written approval has been requested and received fionn the Division. [G.S. 143-215 1] 9 When the Peinuttee land applies bulk residuals, adequate measures shall be taken to prevent wind erosion and surface runoff fiom conveying residuals from the land application sites onto adjacent Properties or into surface waters. [G.S 143-215.1] 10 When the Permittee land applies bulk residuals, a suitable vegetative cover shall be maintained on land application sites onto which residuals are applied, or application shall be in accordance with the crop management plan outlined by the local Cooperative Extension Office, the Department of Agriculture and Consumer Services, the Natural Resource Conservation Service, or an agiononust and as approved by the Division. [15A NCAC 02T .l 109(b)(1)] 11. Bulk residuals shall not be laud applied under the following conditions a. If the residuals are likely to adversely affect a threatened or endangered species listed Under section 4 of the Endangered Species Act or its designated critical habitat; b If the application causes �iolonged nuisance conditions; c If the land fails to assimilate the bulk residuals or the application causes the contravention of surface water of gi oundwater standards; d. If the land is flooded, fioi en or snow-covered, or is otherwise in a condition such that runoff of the residuals would occur e Within the 100 -year flood elevation, unless the bulk residuals are infected or incorporated within a 24-hour period following a residuals land application event; f. During a measurable precipitation event (Le, greater than 0.01 inch per hour), of witlurn 24 hours following a i ainfall event f 0.5 inches or gi eater m a 24 -!lour period, g. If tine slope is greater than 10% for surface applied liquid residuals, or if the slope is greater than 18% for injected or mcorprated bulk liquid iesiduals; h If the soil pH is not maintained at 6.0 or greater, unless sufficient amounts of lime are applied to achieve a final soil pH of least 6.0, or if an agrononnist provides information indicating that the pH of the soil, residuals land lune mixture is suitable for the specified crop. Any approved variations to the acceptable soil pH (6 0) will be noted in this permit; r If the land does not have aril established vegetative cover unless the residuals are incorporated or injected within a 24-hour period following a residuals land application event. Any field that is in a USDA no -till program shall be exempted from meeting this vegetative cover requirement; WQ0000702 Veision 3 2 Shell Veision 150101 Page 6 of 12 If the vertical separation between the seasonal high water table and the depth of residuals application is less than one foot, If the vertical separation of bedrock and the depth of residuals application is less than one foot, Application exceeds agronomic rates [ i SA NCAC 02T 1 109] 12 The following public access restrictions apply to residual land application sites. a Public access to public contact sites (e,g., golf couises, panes, ball fields, etc.) shall be restiicted for 365 days after a leslduals land application event, b Public access to 11011 -public contact sites shall be iestricted for 30 days after a residuals land application event. [15A NCAC 02T. I 109(b) (2)] 13. Public access controls shall include the posting of signs with a minimum area of 3 square feet (e.g., 1,5' x 2') Each sign shall indicate the activities conducted at each site, pernut number, and name and contact information, including the Permittee of applicator's telephone number. Signs shall be posted in a clearly visible and conspicuous manner at tine entrance to each land application site during a land application event, and for as long as the public access iestiretions requued under Condition III 12. apply. [15A NCAC 02T .0108(b)(1)] 14. The following harvesting and grazing restrictions apply to residual land application sites after each land application event, Harvesting and Grazing Description Restricted Duration Animals shall not be allowed to graze during land application activities and iestiicted period Sites that are to be used for grazing shall have fencing to 30 days pi event access after each land application event. Food crops, feed clops and fiber crops shall not be harvested for: 30 days Turf grown on land where residuals have been applied shall not be harvested for 12 months Food crops with harvested parts that touch the residual/soil mixture and are totally above the laud sur face (e g., tobacco, melons, cucumbers, squash, etc) 14 months shall not be harvested for - When the residuals remain oil the land surface for four months of longer prior to incorporation into the soil, f00d Uol)b With halVurtcd pacts below the land surface (e.g., root crops such as potatoes, carrots, radishes, etc.) shall not be 20 months harvested for When the residuals remain on the land surface for less than four months prior to incorporation into the soil, food crops with harvested parts below the land 38 months surface shall not be hai vested for [15A NCAC 02T.1 109(b) (3)] 15. The Peinuttec shall acquire from each landowner or lessee/operator a statement detailing the volume of other nutrient sources (i e., manufactured fertilizers, manures, of other animal waste products) that have been applied to the site, and a copy of the most recent Nutiicnt Management Plan (NMP) for those operations where a NMP is required by the US Department of Agncultui e — National Resoui ccs Conservation Seivice (MRCS) or other State Agencies. The Permittee shall calculate allowable nutrient loading rates based on the provided information and use appropriate reductions, WQ0000702 Version 3,2 Shell Veision 150101 Page 7 of 12 Foi the purpose of this permit condition, a Crop Management Plan (CMP), Waste Utilization Plan (WUP) on Certified Nut-ient Management Plan (CNMP) shall also be considered a Nutrient Management Plan. [15A NCAC 02T 0108(b) (1), 02T 1104(c) (4)] 16. No residuals shall be land applied unless the submitted Land Owner Agreement Attaclunent (LOAA) between the Permittee and landowners or lessees/operators of the land application site is in fiill force and effect. These agreements shall be considered expmed concuriemt with the permit expiration date, anct shall be renewed duluig tlnc peiiiul renewal process. [15A NCAC 02T .1104(c)(4)] IV. MONITORING AND REPORTING REQUIREMENTS 1 Any Division required monitoring (including groundwater, plant tissue, soil and surface water analyses) necessary to ensr.re groundwater and surface water protection shall be established, and an acceptable sample reporting schedule shall be followed. [15A NCAC 021' 0108(c)] Residuals shall be analyzed to demonstrate they are non-hazaidous under the Resource Conservation and Recovery Act (RCRA) Residuals that tests or is classified as a hazardous or toxic waste under 40 CFR Part 261 shall not be used or disposed under this pern-lit. The analyses [corrosivity, ignitability, reactivity, and toxicity characteristic leaching procedure (TCLP)l shall be performed at the frequency specified in Attachment A, and the Peinuttee shall maintain these results for a minimum of five years Any exceptions from the requirements in tills condition shall be specified in Attachment A The TCLP analysis shall include the following parameters (the regulatory level in nulligiams per liter is in parentheses): Arsenic (5.0) 1,4 -Dichlorobenzene (7.5) Nitiobenzene (2.0) Bai win (100 0) 1,2-Dielnloroethane (0 5) Pentachlorophenol (100.0) Benzene (0.5) 1,1-Dichloroethylene (0.7) Pyridine (5.0) Cadmium (1 0) 2,4 -Di nitrotolueme (0 13) Selenium (1 0) Caibon teti achloi ide (0.5) Endiin (0 02) Silver (5 0) Chlordane (0 03) Hexachlorobenzene (0.13) Teti achloroethylene (0.7) Chloiobenzene100 0 ( ) Heptachlor (and its hydioxide) (0 008) Toxaphene (0.5) Chloroform (6 0) Hexachloro-1,3-butadiene (0.5) Trichloroethylene (0.5) Chlomllum (5 0) I- Iexachloroethane (3,0) 2,4,5 -Trichlorophenol (400.0) m-Ciesol (200.0) Lead (5 0) 2,4,6 -Trichlorophenol (2 0) o -Cresol (200.0) Lindane (0.4) 2,4,5 -TP (Silvex) (1.0) p -Cresol (200.0) Meicury (0.2) Vinyl chloride (0.2) Cresol (200.0) Methoxychlor (10.0) 2,4-D (10.0) Methyl ethyl ketone (200.0) Once the iesicluals have been monitored for two years at the fiequency specified in Attachment A, the Permittee may submit a permit modification request to reduce the frequency of this monitoring requirement M no case shall the monitomig fiequency be less than once per permit cycle. [15A NCAC 13A .0102(b), 02T .1101, 02T .l 105] WQ0000702 Version 3 2 Shell Version 150101 Page 8 of 12 3. An analysis shall be conducted on residuals from each source generating facility at the frequency specified in Attachrrient A, and the Permittee shall maintain the results for a minimum of five years The analysis shall include the following paiameteis. Aluminum Mercury Potassium Anmrnonia-Nitrogen Molybdenum Selenium Ai senic Nickel Sodium Cadmium Nitrate -Nitrite Nitrogen Sodium Adsorption Ratio (SAR) Calcium Percent Total Solids TKN Coppei pH Zinc Lead Phosphorus Magnesium Plant Available Nitrogen (by calculation) [15A NCAC 02T 1101] 4 Residuals shall be monitored for compliance with pathogen and vector attraction reduction requirements at the frequency specified in Attachment A, and at the time indicated in the sampling and nmonitoring sections of the approved O&M plan. The rcquued data shall be specific to the stabilization process utilized, and sufficient to demonstrate compliance with the Class B pathogen reduction iequirements in 15A NCAC 02T 1106 (a) and (c), and one vector attraction reduction requirement in 15A NCAC 02T .1107 (a) shall be met Any exceptions fiom the iequiienments in this condition shall be specified in Attachment A [15A NCAC 02T .1106, 02T 1107, 02T .1111(c)] 5. An annual representative soils analysis (i.e, Standaid Soil Fertility Analysis) shall be conducted on each land application site listed in Attachment B on which a residuals land application event will occur in the respective calendar year. This analysis shall be m accordance with the "Guidance on Soil Sampling" located in the Sampling Instructions section of the NC Department of Agriculture & Consumer Seivices' website(lmttp•//www.ncaggov/a/arrononmr/imubs htimm) The Permittee shall maintain these results and a description of the sampling methodologies used to dctcrnmine soil fertility for a period of no less than five years, and shall be made available to the Division upon request At a minimum, the Standard Soil Fertility Analysis shall include the following pararrictcrs- Acidity parameters- Acidity [ 15A NCAC 02T 111 l ((I)] 6. Laboratory parameter analyses shall be peifoinmed on the residuals as they are land applied, and shall be in accordance with the monitoring requirements in 15A NCAC 02B .0505. [15A NCAC 02B .0505] WQ0000702 Version 3 2 Shell Version 150101 Page 9 of 12 Exchangeable Sodium Percentage Phosphorus Base Saturation (by calculation) Magnesium Potassium Calcium Manganese Sodium Cation Exchange Capacity Percent Huinic Matter Zinc Copper pH [ 15A NCAC 02T 111 l ((I)] 6. Laboratory parameter analyses shall be peifoinmed on the residuals as they are land applied, and shall be in accordance with the monitoring requirements in 15A NCAC 02B .0505. [15A NCAC 02B .0505] WQ0000702 Version 3 2 Shell Version 150101 Page 9 of 12 7 The Pernnittee shall nnai -am records tracking all residual land application events. At a nunimum, these records shall include the following a. Source of residuals, b. Date of land application; e. Location of land application (i e , site, field, or zone number as listed in Attachment B); cl Approximate areas applied to (acres), e Method of land application, f Weather conditions (e.g., sunny, cloudy, raining, etc.), g Piedonnrnant Soil Mapping Unit (e.g., CbB2), h Soil conditions (e.g., d -,-y, wet, frozen, etc.); t. Type of crop or crops to be giown on field, i Nitrogen Application Rate based on RYlrs (if using data obtained from the North Carolina State University Department of Soil Science Website, the printout page shall be kept on file and reptinted every five years), k Volume of residuals land applied in gallons per acre, cubic yard pet acre, dry tons per acre, of wet ton per acre; I Volume of animal waste or other rnutuent source applied in gallons per acre, diy ton pei acre, or wet tons per acre, Ill. Volume of soil amendtments (e.g, Rinne, gypsum, etc.) applied in gallons per acre, diy ton per aci e, or wet tons pet acre; and n Annual and cumulative totals in dry tons per acre of residuals as well as animal waste and other sources of nutrients (e g , if applicable), annual and cumulative pounds per acre of each heavy metal (e.g., shall include, but shall not be limited to, arsenic, cadmium, copper, lead, mercury, molybdenum, nickel, selenium, and zinc), annual pounds pet acre of PAN, and annual pounds per acre of phosphorus applied to each field [ 15A NCAC 02T .0109(a)] 8. Three copies of an annual report shall be submitted on or before March I" The atulual repolt shall meet the requirements described in the Instructions for Residuals Application Annual Repotting Forms, Instructions fo_ reporting and annual report forms arc available at lnttu•//aortal ncdenr oig/web/wq/aps/lair/reporting, or can be obtained by contactuig the Land Application Unit directly The annual rcpott shall be submitted to the following address - Division of Water Resouices Information Processing Unit 1617 Marl Service Center Raleigh, North Carolina 27699-1617 [15A NCAC 02T.1 I 1](a)] 9. Noncompliance Notification The Permittee shall report by telephone to the Washington Regional Office, telephone number (252) 946-6481, as soon as possible, but in no case more than 24 hours or on the next working clay following the occurrence or fust knowledge of the occuuence of any of the following: a. Laird application of residuals abnol7nnal in quantity or ehaiacteristic. b Any failure of the land applicat toil program resulting rrn a release of material to surface waters. WQ0000702 Vetston 3.2 Shell Vetston 150101 Page 10 of 12 C. Any time self-monitoring indicates the facility has gone out of compliance with its permit limitations d. Any piocess unit failure, due to known or unknown reasons, iendering the facility incapable of adequate iesidual treatment. c. Any spill of discharge from a vehicle or piping system cluiing residuals transportation. Airy emergency requiring innrnediate reporting (e.g , discharges to surface waters, imminent failure of a storage structure, etc.) outside normal business hours shall be reported to the Division's Emergency Response personnel at telephone number (800) 662-7956, (800) 858-0368, or (919) 733-3300.Peisons reporting such occurrences by telephone shall also file a written report in letter form within five clays following first knowledge of the occuuence This report shall outline the actions taken or proposed to betaken to ensure that the problem does not recur [15A NCAC 02T .0105(1), 02T .0108(b) (1)] V. INSPECTIONS 1. The Permrltec shall provide adequate inspection and maintenance to ensure proper operation of the subject facilities and shall be in accordance with the approved O&M Plan. [15A NCAC 02T .0108(b)] Priot to each bulls residuals land application event, the Pernuttee of his designee shall inspect the iesiduals transport and application facilities to prevent malfunctions, facility detciioiatiorr and operator errors iesultiing in discharges, which may cause the release of wastes to the environment, a tlueat to human health or a public nuisance. The Permittee shall maintain an inspection log that includes, at a munimum, the elate and time of inspection, observations made, and any maintenance, iepairs, or corrective actions taken. The Pernuttee shall maintain this inspection log for a period of five years from the date of inspection, and this log shall be made available to the Division upon request [ 15A NCAC 02T 0l 08(b)] 3 Any duly authorized Division representative may, upon presentation of credentials, enter and inspect any property, premises or place on or related to the land application sites or facilities peimitted herein at any reasonable time for the purpose of determining compliance with this pei mit, may inspect or copy any records required to be maintained under the terms and conditions of this permit, and may collect groundwater, surface water or leachate samples. [G.S. 143-215.3(x)(2)] VI. GENERAL CONDITIONS 1. Failure to comply with the conditions and limitations contained herein may subject the Permittee to an enforcement action by the Division in accordance with North Catoliina General Statutes 143- 215 6A to 143-215 6C [G S. 143-215 6A to 143-215 6C] This permit shall become voidable if the iesiduals land application events aie not carried out in accordance with the conditions of this permit. [15A NCAC 02T .0110] This permit is effective only with respect to the natui e and volume of residuals desci ibcd in the permit application and other supporting documentation [GS 143-215.1] WQ0000702 Version 3 2 Shell Veision 150101 Page 11 of 12 4 The issuance of this pein-in does not exempt the Permittee fiom complying with any and all statutes, rules, regulations, or ordinances, which may be imposed by other jurisdictional goverimient agencies (e.g., local, state, and fedeial) Of particular concern to the Division are applicable rivet buffet rules in 15A NCAC 02B 0200, erosion and sedimentation control requirements in 15A NCAC Chaptei 4 and Under the Division's General Permit NCG010000; any requirements pertaining to wetlands utndei 15A NCAC 02B .0200 and 02H 0500, and documentation of compliance with Article 21 Part 6 of Chapter 143 of the General Statutes [15A NCAC 02T 0105(c)(6)] 5. In the event the residuals program changes ownership or the Permittee changes his name, a formal permit modification request shall be submitted to the Division. This request shall be made on official Division foinns, and shall include appropriate documentation from the parties involved and other supporting documentation as necessary. The Peinnittee of record shall remain fully responsible for maintaining and operating the residuals piogiann peimitted herein until a permit is issued to the new owner. [15A NCAC 02T .0104] 6. This peinut is subject to revocation or unilateral modification upon 60 clays notice from the Division Director, in whole or pall fir the requirements listed in 15A NCAC 02T .0110 [15A NCAC 02T 01 10] Unless the Division Director giants a variance, expansion of tine permitted residuals program contained herein shall not be granted if the Permittee exemplifies any of the criteria in 15A NCAC 02T 0120(b) [15A NCAC 02T .0120] 8 The Permittee shall pay the annual fee witlun 30 days after being billed by the Division Failure to Pay the annual fee accordingly shall because for the Division to revoke this pernnit [15A NCAC 02T 0105(e)(3)] Perimmit issued this the 24th day of March 2015 NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION o Jay iumei man, Director ivisioi of Water Resources By Authoi ity of the Environmental Management Conunission Permit Number WQ0000702 WQ0000702 Version 3 2 Shell Version 150101 Page 12 of 12 ATTACHMENT A - Approved Residual Sources CITY OF HAVELOCK Certification Date: March 24, 2015 Permit Number: WQ0000702 Version: 3.2 I Maximum Dry Tons per Year is the amount of i esidual, approved fur land apphc.auon from each permitted facility 2 AnalysLs to demonstrate that residuals are non-ha/ardOUS (i c, TCLP, igmtability, reactivity, and corrosivity) as stipulated under penntt Condition IV 2 3 Testing of metals and nutrients as stipulated under permit Condition IV 3 4 Analyses of pathogen and N ector attraction reductions us stipulated under permit Condition IV 4 5 Monitoring frequencies are based on the actual dry tons applied pci yeas using the table below, unles% specitied above Dry Tons Generated short tons per year) Monitor ing Frequency (Establisiied in 40 CFR iO3 and 15A NCAC 02T.1110 <319 1 /Year =>319 - <1,650 I/ Quarter (4 times per car) =>1,650 - <16,500 1/60 Days (6 times per ear) Approved 1 /month ( i 2 times per ear) Maximum Monitoring Monitoring Monitoring Frequency for Mineralization Owner Facility Name County Permit Biological Dry Tons Frequency for Frequency for Pathosen & Rate Number Residuals Per Year I Non-haiardous� Metals and [Raw=04 Characteristics - Nutrients 3's Vector Attraction Aerobic = 0 3, Reductions'' Anaerobe. =03, Compost= 0 I City of Havelock Havelock W WTP Craven NCO021253 Ycs 415 Annually See Table Below See Table Below'* 03 Total 413 I Maximum Dry Tons per Year is the amount of i esidual, approved fur land apphc.auon from each permitted facility 2 AnalysLs to demonstrate that residuals are non-ha/ardOUS (i c, TCLP, igmtability, reactivity, and corrosivity) as stipulated under penntt Condition IV 2 3 Testing of metals and nutrients as stipulated under permit Condition IV 3 4 Analyses of pathogen and N ector attraction reductions us stipulated under permit Condition IV 4 5 Monitoring frequencies are based on the actual dry tons applied pci yeas using the table below, unles% specitied above Dry Tons Generated short tons per year) Monitor ing Frequency (Establisiied in 40 CFR iO3 and 15A NCAC 02T.1110 <319 1 /Year =>319 - <1,650 I/ Quarter (4 times per car) =>1,650 - <16,500 1/60 Days (6 times per ear) => 16.500 1 /month ( i 2 times per ear) If no land application events occur during a required sampling period (e.g. no land application occur during an entire year when annual monitoring is required), then no sampling data is required during the period of inactivity. The annual report shall include an explanation for missing sampling data. Those required to submit the annual report to EPA may be required to make up the missed sampling, contact the EPA for additional information and clarification. WQ0000702 Version 3 2 Attachment A Page 1 of I THIS PAGE BLANK ATTACHMENT B - Approved Land Application Sites CITY OF HAVELOCK Certification Date: March 24, 2015 Permit Number: WQ0000702 Version: 3.2 Field/ Site O,.tiner I essee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes NC -CV -I -I A' Campbell, Robert G McCoy, Charles Myron Craven 35012'39" 77°25'06' S 90 Pa- Pantego tine sandy loam NC -CV -I-1 B Campbell, Robert G. McCoy, Charles Myron Craven 35"12'38" 77"25'06' 700 Pa - Pantego line sandy loam NC -CV -I -I C' Campbell. Robert G McCoy, C harle, Myion Craven 35°12'31" 77025'09' 1290 Pa - Pantego tine bandy loam NC -CV -1-11) Campbell. Robert G McCoy, Charles Myron Craven 35012'32" 77025'15" 3120 Pa - Pantego fine sandy loam NC -CV -I -I E Campbell, Robert G McCoy, C harles Myron Craven 35012'32' 772518" 1640 Pa - Pantego fine sandy loam NC -CV -I -I G Campbell. Robert G McCoy, Charles Myron Ciaven 35"12'20- 77025'02" 940 Pa - Pante-o fine sandy loam NC -CV -I -I H Campbell. Robert G McCoy, Charles Myron Craven 35012'12'" 77°25'07' 2600 Pa - Pantcgo tine bandy loam NC -CV -I -2A Campbell, Robert G McCoy, C harles Myron Craven 35012'20" 77"25'39' 13.50 Pa - Pantego fine sandy loam NC -CV -I -2A Campbell Robert G McCoy, Charles Myron Craven 35012'10" 77025'23" 550 Pa- Pante,o tine sandy loam Total for Cowry 130.8 NC -PA -2-1 A Spencer Farms, Inc Pamlico 35"09'56' 76"49'32" 10 is Yo - Yonges loamy fine sand NC -PA -2-1 B Spencer Fauns, Inc Pamlico 35"09'55"' 76049'23" 9 71 Yo - YongLs loamy fine sand NC -PA -2 -IC Spencer Farms, Inc Pamlico 35009'55" 76049'26" 1024 Yo - Yonges loamy tine sand NC -PA -2-1 D Spencer Famis, Inc Pamlico 35009'55' 76"49'23" 1025 Yo - Yon -e% loamy fine sand NC -PA -2 -IE Spencer Farms, Inc Pamlico 35"09'55" 76°49'20" 1012 Yo- Yonges loamy fine sand NC -PA -2- I F Spencer Farms, Inc Pamlico 35009'55" 76 49' 17" 1005 Yo - Yonges loamy tine sand NC -PA -2 -IG Spencer Farms, Inc Pamlico 35°09'55" 76"49'15" 952 Yo - Yonges loamy fine sand NC -PA -2-2A Spencer Farms, Inc Pamlico 35009'17" 76049'20" 2 94 Ar - Argent loam NC -PA -2-213 Spencer Farms, Inc Pamlico 35°09'16' 76049' 15" 626 Ar - Argent loam NC -PA -2-2C Spencer Farms, Inc Pamlico 35009'16" 76049'11- 6 48 Yo- Yongcs loamy tine band NC -PA -2-2D Spencer Farms, Inc Pamlico 35009'16' 7V49'07' 7 04 Yo — Yonges loamy tine sand NC -PA -2-2E Spencer Farms, Inc. Pamlico 35"09'17" 76"49'03" 628 Yo — Yonges loamy fine sand NC -PA -2-3A Spencer Farms, Inc Pamlico 35009'19" 76"49'00" 542 Yo — Yonges loamy fine sand WQ0000702 Version 3 2 Attachment B Pale I of 3 ATTACHMENT B - Approved Land Application Sites CITY OF HAVELOCK Certification Date: March 24, 2015 Permit Number: WQ0000702 Version: 3.2 NC -PA -2-3B Spencer Farms, Inc Pamlico 35009'l 9' 76048'57" 404 Yo - Yonges loamy tine sand NC -PA -2-3C Spencer Farms, Inc. Pamlico 35009' 19' 76048'55" 564 Yo - Yonge�, loamy tine sand NC -PA -2-31) Spencer Farms, Inc Pamlico 35'09' 19' 76°43'51' 804 Sk- Stockade loamy tine sand NC -PA -2-3E Spencer Farms, Inc. Pamlico 35009 20' 76048'=18" 742 Sk- Stockade loamy fine sand NC -PA -2-317 Spencer Farms, Inc Pamlico 35009'20" 76"4S'45' 7.42 Sk- Stockade loamy tine sand NC -PA -2-3G Spencer Farms, Inc Pamlico 35009'20" 76048'42" 6 65 Sk- Stockade loamy fine sand NC -PA -2-4A Spencer Farms, Inc. Pamlico 35009'27" 76049'02" 2 43 Yo - Yongcs loamy tint sand NC -PA -2=113 Spencer Farms, Inc Pamlico 35009'34" 76'=18'54' 4.34 Sk- Stockade loamy fine sand NC -PA -24C Spencer Farms, Inc Pamlico 35"09 32' 76048'54" 4.51 Sk- Stockade loamy tine sand NC -PA -241) Spencer Farms, Inc Pamlico 35°09'31" 76048'53' 3.62 Sk- Stockade loamv tine sand NC -PA -2-4E Spencer Farms, Inc Pamlico 35°09'29" 76"48'52' 3 55 Sk- Stockade loamy fine sand NC -PA -24F Spencer Farms, Inc. Pamlico 35"09'28" 76"48'52" 3 60 Sk- Stockade loamy tine sand NC -PA -2-4G Spencer Farms, Inc Pamlico 35°09'26" 76"48'51" 3.55 Sk- Stockade loamy tine sand NC -PA -2-5A Spencer Farms, Inc Pamlico 35009'39" 76"49'04' 5.21 Sk- Stockade loamy tine sand NC -PA -2-513 Spencer Farms. Inc Pamlico 35"09'40" 76"49'02' 648 Sk- Stockade loamy tine sand NC -PA -2-5C Spencer Farris, Inc Pamlico 35009'40" 76043'58" 6 16 Sk- Stockade loamy fine sand NC -PA -2-51) Spencer Farms, Inc Pamlico 35"09'41" 76048'85" 626 Sk- Stockade loamy tine sand NC -PA -2-5E Spencer Farms, Inc Pamlico 35"09'41" 76048'52" 3 90 Sk- Stockade loamy fine sand NC -PA -2-5F Spencer Farms, Inc Pamlico 35"09'42' 76"48'49 ' 359 Sk- Stockade loamy fine sand NC -PA -2-6A Spencer Farms. Inc Pamlico 35"09'51" 76050'21" 521 Sk- Stockade loamy tine sand NC -PA -2-6B Spencer Farms, Inc Pamlico 35"09'52" 76050'] T' 648 Sk- Stockade loamy tine sand NC -PA -2-6C Spencer Farms, Inc. Pamlico 35"09"53" 76"50'13" 6 l6 Sk- Stockade loamy fine sand NC -PA -2-61) Spencer Farms. Inc Pamlico 35"09"54" 76050'10" 626 Yo - Yonaes loamy tine sand NC -PA -2-6E Spencer Farms. [nL Pamlico 35"09'55" 76°50'06" 3 90 Yo- Yonges loamy fine sand NC -PA -2-6F Spencer Farms, Inc. Pamlico 35009'55" 76"50'04" 3 59 Yo - Yonges loamy fine sand NC -PA -2-6G Spencer Farms, Inc Pamlico 35"09'56' 76"50'01" 3 S4 Ar- Argent loam WQ0000702 Version 3.2 Attachment B Pave 2 of 3 ATTACHMENT B - Approved Land Application Sites CITY OF HAVELOCK Certification Date: March 24, 2015 Permit Number: WQ0000702 Version: 3.2 NC -PA -2-7A Spencer Farms, Inc Pamlico 35°09'56- 76°49'59" 2 18 Ar- Argent loam NC -PA -2-7B Spencer Fanns, Inc Pamlico 35°09'57' 76°49'57' 257 Ar- Argent loam NC -PA -2-7C Spencer Fann,, Inc Pamlico 35009'57" 76049'55" 332 Ar - Argent loans NC -PA -2-713 Spencer Farin,, Inc Pamlico 35009'58' 76049'53" 3 32 Ai -Argent loam NC -PA -2-7E Spencer Farms, Inc Pamlico 35009'59" 76°49'50" 326 Ar- Ar-ent loam NC -PA -2-7F Spencer Farms, Inc Pamlico 35°09'59" 76049'48' 3 03 Ar- Argent loam NC -PA -2-7G Spencer Farm,. [nc Pamlico 35°10 00' 76°49'46' 353 Ar- Argent loam NC -PA -2-7H Spencer Farms, Inc. Pamhco 35°10'00" 76°49'43 ' 328 Yo - Yonges loamy tine sand NC -PA -2-71 Spencer Farm,, Inc Pamlico 35010'01" 76°49'41" 325 Yo - Yongesloamyfinesand NC -PA -2-7J Spcnccr Farms, Inc Pamlico 35°10'01" 76049'39" 325 Yo - Yonges loamy tine sand NC -PA -2-7K Spencer Farm,, Inc Pamlico 35"10'02" 76049'37" 247 Yo - Yonges loamy fine sand Tota/for County 269.80 Total 400.60 L. A re-uetmea compiiance uounuary na, uec:n approved for this iand application tine. ibis re -defined compliance boundary is between fielde NC -CV -1-1 A and NC -CV -1-1 C and shall be located at 50 feet from the water supply well on Robert G Campbell'~ property Note that the 100 -trot setback between wells and the land application area shall still be met. WQ0000702 Version 3.2 Attaclunent B Pale 3 of 3 THIS PAGE BLANK 1--- -1 Fields GA - GG L, Fields 2A - 2E ( - Alliance Grantsboro Fickis JA IG Fields 5A - 5F, J Fields 4A - 4G� L-- ,_. - --- - -- - Bayboro Stonewall D E C 5 k LL. n REFERENCE: GIS DATA LAYERS WERE OBTAINED FROM ESRI, INC. PLEASE NOT[ THIS MAP IS FOR INFORMATIONAL PURPOSES ONLY. IT IS NOT MEANT FOR DESIGN, LEGAL, OR ANY OTHER USES THERE AHE NO GUARANTEES ABOUT ITS ACCURACY, SSME, INC. ASSUMES NO RESPONSIBILITY FOR ANY DECISION MADE OR ANYACTIONS TAKEN BY THE USER BASED UPON THIS INFORMATION. i Field Boundary I n SCALE. z : 1 �� = 1 miles FIGURE 1 SPE -- -s S&ME (' SPENCER FAR DATE: 11-06-14 SITE NC -('CITY OF HAVELOCK Di A; BY MEM VICINITY It 503 LAND APPLICATION PROGRAM "WWW.SMEINC.COM 'ROJECTNO CITY OF HAVELOCK - LAND Af CRAVEN COUNTY 1588-09-059 ENGINEERING LICENSE NO F -W76 PAMLICO COUNTY, NO -- ---- WQ0000702 SITE LOCATION MAP u, SII vF1I9.1) 101 AI_ACRlti 81 MRI)A(RB NEI-A(!RIS SII F./MIA) TOTAL A('R1\ 111TI-1, F)A(RFS NEI'ACRES N(' -PA -2 -IA 15.08 4.90 10.18 NC -PA -2 -SA 6.85 2.66 5.11 NC -PA -2-I11 13.61 3.98 9.71 N(' -PA -2 -SR 6.51 1.56 6A8 NC -PA -24C 13.72 JAI 10.24 NC4PA-2-5(' 6.53 156 6.16 NC -PA -2 -ID 13.71 3.46 1025 NC-PM2S1) 6.52 1.10 636 NC -PA -2 -IE 13AS 3A8 11.12 NC -PA -2-5E 6.53 1.47 3.90 NC -PA -2-1 F 13.53 .1.48 10.05 NC -PA -2-5F 5.54 1.85 3.59 NC -PA -LIG 14.95 4.43 9.52 503 LAND APPLICATION PROGRAM NC -PA -2 -SA THROUGH 5F "ICI -2 •^ l 1Ili. FIF211 TUTALAI IIFN IIIc FJRFO At'RFN NF:[ At IN ADt., Fill 7JITALA(RIN Ut"'FAIDA(R1ti NIT AI RFN °I ;i Fleltl SF' NI -PA -3-2A 5.50 2.56 2.94 W -PA -2-71 9,71 2.11 713 Field 5E NC'-PA-2-28 IIJ! 5.47 6.I6 NC-PA•24C 9.99 liJ 6.65 �t`pJ 'm �• FI4Id'SD •. T1 N('-YA-2-2C 10.11 .7.70 A.JB VC -PA -7 -IA 7.19 I.K I.17 p yy LU o LU r FIeId SC { NC -PA -7 -ID 10.77 1 `l 7.04 N(' -PA -248 4.12 1A0 1.74 d 3 y LU W Field'5B NC-PA3-1F. 9.9) 7.6.5 614 NCrA-24C 1,42 1.91 1.51 I'; ',A N(' -PA -2.3A 7.30 2.16 5.43 NC -PA -240 3.19 IJ7 3.62 N('4'A-7-311 6.90 2.43 J.O+ NCJA"Ir 5.11 116 3-95 Ol s' VC-PA-7•JC 8.13 I.J9 S.AI N(' -PA -24F 3.16 I.tb l.10 - O W -PA -I -3O I2.TR J.,J A.04 NI'AA-34(: 5.41 I.K 3.55 IC -PA -2-0.9.7! 231 7.47 O It , W REFERENCE' - = N Field 48 _ OISUATA IAYFR9 WENF OBTAYiFII FROMESW,4K P(EASF NOTE INW MAP 16 fOR �NFURWTIONN PUNROSES WAY IT IS NOI MFAN7 TfMt DESIGN. uuji cif IOM.(II ANY OTHER USES THERE ARE NO 0IMAAN1EEt ABOUT ITS ACCURACY SAME. INC ASSUMFS W RFIDONSWt111 ANY OFCISIUN y` S: Uf Y s UI I7R ANY At T!' -.PIS IAKEN BY TIS USER BASFO UPON T195 NSOI0AATIRN IJi GQ • FIBIA iC >t=h+� COMPLIANCE BOUNDARY: ^.• iN[C01APlIAN(:F BWN(- FORrATUIIAM)AMP TION SITE IS FSTABIISNED AT F.ITNER 250 FFF7 _ � ' ' • iR(M IIIE RFSIOUAIS IARO AM'34: IONAWAOe t -ECT NTTMNIIS PNOI•ER7 Y MNMnARY F'nld 4D•'f REVIEW BOUNDARY' 0 0 �.+�'- • Y^��.^ " ^ INF REVIEW BWMMRY SINIL BE E6TAB(ISIEO AROUIB EAIOIIAND APPIK.ATi(Hl iIIC MIDWAY U .�� r - '�.-^` •1 BETWEEN TIS CO6iLUNCE ROU110MYAMD TIE PENITF.R OF TNF. RESMAIAl3 UtU APPIICATIW+ Fi„id 1C Z ..+�`• �sl �. W lr\•"' _ - • • Irrigation Well � ■ Dwelling °.a GW Lowering Ditch Buffer T'+s Field Boundary ,I F Property Boundary o Vi az Fie C f' A20 III Id E rield,3A Fitld,3B io1d�3C F.i4 d,3D Field JE Field 3F F ei:l y'.,•.4l Z U Field. B I...2AZ 1 r 1• •`` o LL Z W � '01 +M Lu yyy Z� W UF-� x0 i iF i-- 6 ',R�• UJI 00 {4 r1 LL. Q) 1JIFIGURE 3 • �e ♦ - M►. CITY OF HAVELOCK 503 LAND APPLICATION PROGRAM .1 I► I We 1 CRAVEN COUNTY '. �■ N WQ0000702 1` - ,� ,�\ p■,. I 1. DETAIL MAP FOR SITES FsN. DINi1alGlety+ l;r�tY^ I-nrbed, I11hMIr 6-glRph- GNI-SIAITbui 05. USDA. 11SG5. ACK 6efi-plee NC -PA -2-2A THROUGH 2E, 1 Nlpo, M the Use C O 111)"1100 •• NC -PA -2-3A THROUGH 3G AND NC -PA -2-4A THROUGH 4G COMPLIANCE BOUNDARY IDF CI Mr I:UWlIDANY I DN I ALIl l A 1 ICAIKM SIT -F'.1 BI ItiIIDATI I711ER W FI I T F NOM 111E RFS IAMI S --IK AIIONNI It'I IILIV11.TRC 111111 S- 'I 1N UUUV w1 .A' L/L 0 IW NI•. DINTS IANDAfl-AI IONARtA I N RF VIEW BOUNDARYi - y TIORFVIFV--DARYSIMI BF -81 IS11FDMCURO F. It -AND 1-111-A111)RI'll V-11 IFN:FrIlTlr trMPIMNCC OOIMDMYANIITIIC . 1 M RIMTfSf)I :It RLSKA- LS LAM) AIV•- ICA] NM ARCA - / t �` AINt� m 2 �� Lu LU Lu e� LU n iRId7BFilld.7C - - - __-.-- , Field 7A - - L _ 0 ..IdBG - - - - U -T ield 6E .. W Field 6D ly _ uj Field 6C h -� Fie Id 6B Field to field 1B .ield 1C leld 1D FWD- FIeId 1F f i?Id (•.A I 4, � µvNN��gfPRM _ Y � Z K a? V zo Z oQ UV �d no Z Lu aU� pz W F LL ?19� zym UV W °° r U) SFR:/FA7D TOTAI.ACR/S BILAIW IFDACIM NATACR9R SrM/FWD 717FAL AFFIti HI }}kH171.4t Itl:\ Vl l' 41 Nt� I n SIC -PA -24A 7.55 2.N 5-21 NC-PM2-7C IRn 1.54 3_12 FIGURE 4 W--PA-24B e u L"6AS NGFA-2-7B I.6A 1.51 »2 * • I Nt-1-A-26C 7.99 IJ3 6.16 NC -PA -2-7E 4.90 Iso 3.26 . CITY OF HAVELOCK \t -PA-3-60 8.13 u7 6.26 NC -PA -2.7F 45, 1.51 3.0. t� ' 503 LAND APPLICATION PROGRAM '('PA -24E 5.52 IA2 3.9e W -PA -2-7C 5.10 1.57 3.53 CRAVEN COUNTY 11PA-2.6F 5.16 1.57 3.59 NC -PA -24H 49I 1.54 3.29 I nC-YA-24(: 5.1e I.7L JJI IVC -PA -2-7I 1.79 I.51 3,25 REFERENCE: O WQODW702 NC4'A-2-7A 3.OF e.e2 IIF NC -PA -2-71 6.79 1.5/ 325 �S MTAIAYEN3 rLFRk CMr OFROMESRI.INL' PlhA'f U1Fr16SWPISFORI C,RMAT10 PUM NOWY RSNLtWAwTFORDF-. DE FAIL MAP FOR SITES Iil.AI OR ANV OTIIFR IRCS 1NFRF ARC MIFHNRAMTCCS ABDUf )TS ACCURAGv SFMi. MO ASLMFS ND RFSDON5iBl1 RY iDR ANY eCt'J:HwI ,5 W' -PA -2-7B 6.03 1.46 2.57 NC -PA -2-7K Lal 1.94 2.47 MAoe 1R+Awr ACTwm rAwcw er 7RE usER eASLD ImoN nnsIM ORMAnoR 1 NC -PA -2-6A THROUGH 6G AND NC -PA -2-7A THROUGH 7N BIOSOLIDS MANAGEMENT SERVICE AGREEMENT This SERVICE AGREEMENT (hereinafter called the AGREEMENT) made and entered into this Ist day of November 2006 (the EFFECTIVE DATE) by and between City of Havelock, NC (hereinafter called CUSTOMER), and Synagro Central, LLC, (hereinafter called CONTRACTOR which term shall include its successors and assigns). WITNESSETH: In consideration of the following covenants and AGREEMENTS, the CUSTOMER and the CONTRACTOR hereby mutually agree as follows: SCOPE 1.1. The CONTRACTOR shall provide b>osolids management services that include removal, transportation, and land application or other beneficial reuse in accordance with the terms of this AGREEMENT (hereinafter called SERVICES) of the CUSTOMER'S biosolids which constitute primarily (liquid semi-solids) residue generated during the treatment of wastewater (hereinafter called BIOSOLIDS) at the city's wastewater treatment plant located in Havelock, North Carolina (the PLANT). 2. CONTRACTOR OBLIGATIONS The CONTRACTOR shall: 2.1. Within four (4) weeks after receipt of notice from CUSTOMER, cause the removal, transportation, and land application of CUSTOMER'S BIOSOLIDS and, in connection with such activities, maintain AUTHORIZATIONS and landowner AGREEMENTS required of CONTRACTOR for agricultural land application and/or disturbed land reclamation in accordance with all applicable LEGAL REQUIREMENTS which are currently in effect, or which take effect during the term of this AGREEMENT. 2.2. At the written request of CUSTOMER, and as applicable, provide any AUTHORIZATIONS which are issued by applicable GOVERNMENTAL AUTHORITIES for all land approved for BIOSOLIDS land application. 2.3. Notify the CUSTOMER of any notice of violation, action, suit, claim, or legal proceeding against CONTRACTOR relating to any aspect of the CUSTOMER'S BIOSOLIDS managed pursuant to this AGREEMENT. 2.4. For BIOSOLIDS which are land applied, employ land application methods approved or allowed by applicable GOVERNMENTAL AUTHORITIES. -1- Havelock Agreement -Final 1107 06 doc 2.5. Develop and implement monitoring, record keeping, and reporting programs as required by applicable LEGAL REQUIREMENTS, and as set forth in Section 6 of this AGREEMENT. 2 6. Provide proof of liability and workers' compensation insurance, as set forth in Section 4 of this AGREEMENT. 2.7. Indemnify CUSTOMER, and hold harmless CUSTOMER, its subsidiaries, affiliates, successors and assigns and their respective directors, officers, employees, shareholders, representatives and agents (hereinafter referred to collectively in this section as CUSTOMER INDEMNITEES) from and against any and all claims, liabilities, lawsuits, and causes of action, together with reasonable costs, expenses, and attorneys' fees associated therewith and all amounts paid in defense or settlement of the foregoing, which may be imposed upon or incurred by CUSTOMER INDEMNITEES or asserted against CUSTOMER INDEMNITEES by any other person or persons (including GOVERNMENTAL AUTHORITIES), to the extent caused by CONTRACTOR'S breach of its obligations under this AGREEMENT or violation of applicable LEGAL REQUIREMENTS. 2.8. Comply in all material respects with all LEGAL REQUIREMENTS applicable to CONTRACTOR'S provision of the SERVICES. 2.9. CONTRACTOR'S obligations to take, receive or beneficially reuse BIOSOLIDS shall be suspended during a Force Majeure. 3. CUSTOMER The CUSTOMER shall: 3.1. Provide to CONTRACTOR for off-site beneficial reuse 100% of all liquid BIOSOLIDS generated at the PLANT. 3.2. Provide CONTRACTOR with reasonable access to the CUSTOMER'S BIOSOLID' S delivery system, except as reasonably required for safety or emergency considerations, or planned shutdown of the PLANT. It is agreed that when safety, emergency or shutdown conditions prevent access, that both parties will attempt to resolve such conditions as expeditiously as possible. -2- Havelock Agreement -Final 11 07 06 doc 3.3. Provide CONTRACTOR written notice of the concentration of total nitrogen (as N on a dry weight basis) in the BIOSOLIDS which CUSTOMER provides, plus all other information which CONTRACTOR may request to facilitate its compliance with applicable LEGAL REQUIREMENTS, including without limitation the requirements of 40 C.F.R. Part 503. Information wluch CONTRACTOR may obtain shall include, without limitation, the monthly average concentrations (in milligrains per kilogram) of arsenic, cadmium, copper, lead, mercury, nickel, selenium, and zinc or other potentially Hazardous Materials present in the BIOSOLIDS, the level of pathogen reduction which CUSTOMER has achieved. The methods and procedures by which CUSTOMER samples and analyzes concentrations of potentially HAZARDOUS MATERIALS, pathogen reduction, shall comply with methods and procedures prescribed by applicable LEGAL REQUIREMENTS, including without limitation 40 C.F R. Part 503. CUSTOMER shall provide CONTRACTOR with a certification regarding concentrations of HAZARDOUS MATERIALS, pathogen reduction, as well as certification that all methods and procedures used by customer for the sampling and analysis of BIOSOLIDS comply with requirements of 40 C F.R. Part 503, and any other applicable LEGAL REQUIREMENTS. The form of certification, and the type of information which the CONTRACTOR may request from CUSTOMER may include the form of certification or the type of information which CUSTOMER must maintain under 40 C.F.R. § 503 17. CONTRACTOR shall have the undisputed right to rely upon any information or certification provided by CUSTOMER, and shall not have any independent duty to investigate or inquire regarding the subject matter of the CUSTOMER'S certification or of the information which CUSTOMER provides to CONTRACTOR. 3.4. Not provide to CONTRACTOR any BIOSOLIDS which contain HAZARDOUS MATERIAL or are hazardous in accordance with 40 C.F.R. Part 261, other federal law, state law, or which contains a concentration of polychlorinated biphenyls equal to or greater than 50 milligrams per kilogram of total solids (on a dry weight basis). 3.5. Provide CONTRACTOR with at least [four (4) weeks] advance notice of when CUSTOMER desires for CONTRACTOR to remove BIOSOLIDS from the PLANT. 3.6. Indemnify, defend, and protect CONTRACTOR from and against all claims, damages, losses, costs, suits, settlements, causes of action, liabilities, fines, penalties, costs, and expenses (including but not limited to, investigation and legal expenses, and costs and expenses associated with Remedial Work) (collectively, CLAIMS) arising out of or in connection with any acts or omissions of CUSTOMER, or its employees, officers, directors, representatives, contractors, subcontractors, agents, or affiliates, or any licensee or mvitee of the PLANT (other than CONTRACTOR), or CUSTOMER'S breach of any of its obligations under this AGREEMENT, or any violation of any applicable LEGAL REQUIREMENT by CUSTOMER or any of its employees, officers, directors, representatives, agents, contractors, subcontractors, or affiliates, or -3- Havelock Agreement -Final 11 07 06 doc its licensees or invitees (other than CONTRACTOR) or any discrepancy in the character or composition of the BIOSOLIDS from the PLANT compared to analytical results, certifications or other information provided by CUSTOMER to CONTRACTOR. 3.7. From time to time, as requested by CONTRACTOR, review a list of proposed land application sites at which BIOSOLIDS from the PLANT maybe applied, and select from such sites those sites to which CUSTOMER desires for its BIOSOLIDS to be applied, and such sites to which it does not desire its BIOSOLIDS to be applied. In the absence of specific designations by CUSTOMER, CUSTOMER agrees that it shall have been deemed to select any and/or all of such application as satisfactory locations for its BIOSOLIDS. 3.8. Notify the CONTRACTOR of operating changes or any other conditions that would reasonably be expected to affect the BIOSOLIDS handled by CONTRACTOR under this AGREEMENT. 4. INSURANCE The CONTRACTOR shall maintain and provide the CUSTOMER evidence of insurance as follows: 4.1. Worker's Compensation meeting at least the mi iimum requirements of the laws of the State of North Carolina, and Employer's Liability with a minimum single limit of $1,000,000. 4.2. Commercial General Liability and Automobile Liability Insurance to include premises operations and subcontractors. Completed Operations and Contractual Liability are to be included under the Commercial General Liability coverage. The insurance policies will have limits of no less than $1,000,000.00 per occurrence and $ 2,000,000.00 aggregate. CUSTOMER shall be named as an additional insured. 5. PAYMENT The CONTRACTOR shall provide the CUSTOMER with an accounting of the gallons of BIOSOLIDS removed from the CUSTOMER'S PLANT, and such other information as shall be reasonably requested. CONTRACTOR will utilize a measurement method based on the number of tanker loads of BIOSOLIDS removed from the CUSTOMERS'S PLANT and the capacity, in gallons, of the tankers. The CUSTOMER will be provided with manifests for all loads removed by the CONTRACTOR. 5.1. The CONTRACTOR shall submit invoices once each month for SERVICES provided by CONTRACTOR, using the rates and the amounts agreed in Section 10 of this -4- Havelock Ao eement-Final 1107 06 doc AGREEMENT. The CUSTOMER shall pay all invoices within 30 days after receipt of the invoice. 5.2. It is agreed that in the event of any dispute concerning invoice amount, CUSTOMER will pay undisputed invoice amounts within 30 days after receipt of the invoice. 6. RECORD KEEPING The CONTRACTOR shall maintain records and submit sum mary reports to the CUSTOMER after each hauling event (as requested by CUSTOMER) and on an annual, cumulative basis. Reports shall include information regarding, but not be limited to: 6.1. Number of loads transported and applied with identification of utilization site(s) 6.2. Such other information as will reasonably allow CUSTOMER to fulfill its recordkeeping, and reporting requirements under applicable LEGAL REQUIREMENTS and such other information reasonably deemed by the CUSTOMER as necessary for this AGREEMENT and which is kept by CONTRACTOR in the normal course of its business. 7. NOTICES Except as otherwise provided herein, any notice, demand or other contract disputes or shall be in writing and shall be personally served, sent by commercial courier service or prepaid registered or certified mail, or sent by telephonic facsimile delivery with confirmation thereof. Any such notice shall be deemed communicated upon receipt. 7.1. The following address is hereby designated as the legal address of the CONTRACTOR. Such address may be changed at any time by notice in writing delivered to CUSTOMER. Synagro Central, LLC 7014 E. Baltimore Street Baltimore, MD 21224 (410) 284-4120 Fax: (410) 282-7466 Attention: [Stephen Toft] With a copy to: Alvin L. Thomas II General Counsel Synagro Technologies, Inc. -5- Havelock Agreement -Final 11 07 06 doc 1800 Bering Drive, Suite 1000 Houston, Texas 77057 (713) 369-1700 (713) 369-1750 (Fax) 7 2. The following address is hereby designated as the legal address of the CUSTOMER Such address may be changed at any time by notice in writing delivered to CONTRACTOR. Name: Street Address: Mailing Address: Phone Number: Contact Person: Fax: FORCE MAJEURE City of Havelock PO Drawer 368 Havelock, NC [28532] (252) 444-6410 Dave Harvell (252) 447-2616 Wherever the word "Force Ma]eure" is used, it should be understood to mean: 8.1. acts of God, landslides, lightning, earthquakes, hurricanes, tornadoes, blizzards and other adverse and inclement weather, fires, explosions, floods, acts of apublic enemy, wars, blockades, insurrections, riots or civil disturbances; 8.2. labor disputes, strikes, Work slowdowns, or Work stoppages; 8.3. orders or judgements of any Federal, State or local court, administrative agency or governmental body, if not the result of willful or negligent action of the party relying thereon; 8.4. power failure and outages affecting the Premises; and 8.5. any other similar cause or event, including a change in law, regulation, ordinance or permit, provided that the foregoing is beyond the reasonable control of the party claiming Force Majeure. If, because of Force Majeure any party's cost is increased by more than 15% or any party hereto is rendered unable, wholly or in part, to carry out its obligations under this Contract, then such party shall give to the other party prompt written notice of the Force Majeure with reasonable full details concerning it; thereupon the obligation of the party giving the notice, so far as they are affected by the Force Majeure, shall be suspended during, but no longer than, the continuance of the Force Majeure. The affected party shall use all possible diligence to remove the Force Majeure as quickly as possible, but his obligation shall not be deemed to -6- Havelock Agreement -Final 1107 06 do, require the settlement of any strike, lockout, or other labor difficulty contrary to the wishes of the party involved. 9. TERM 9.1. This AGREEMENT shall be effective from the EFFECTIVE DATE until the 30th day of September 2011 (the INITIAL TERM). At the end of this term, this AGREEMENT may be extended on a yearly basis for five (5) additional one year terms at the option of CUSTOMER and at the mutual agreement in writing of both parties. The non -defaulting party may terminate this AGREEMENT and shall have no further obligations to the other party under this AGREEMENT if (i) the other party fails to observe or perform any material covenant or agreement contained in this agreement for ten (10) business days after written notice thereof has been given to such other party by the non-default>ng party or (ii) at any time upon the insolvency of the other party, or the institution by or against the other party of any proceeding in bankruptcy or insolvency or for the appointment of a receiver or trustee or for an assignment for the benefit of creditors. 9.2. CONTRACTOR may terminate this AGREEMENT at any time upon written notice to CUSTOMER and have no further obligation to CUSTOMER if: 9.2.1. The CONTRACTOR is unable to utilize the BIOSOLIDS due to a change in any LEGAL REQUIREMENTS that renders the SERVICES illegal, or place such restrictions or requirements thereon so as to make the provision of the SERVICES cost prohibitive or to otherwise frustrate the commercial intent of this AGREEMENT. 9.2.2. The BIOSOLIDS become unsuitable for land application by the CONTRACTOR by reason of (i) the act or omission of any third party or CUSTOMER, and through no fault of CONTRACTOR, or (>i) the condition of the BIOSOLIDS is materially inconsistent with the description and analysis, certifications or other inforination the CUSTOMER has provided to the CONTRACTOR regarding the BIOSOLIDS, or (u>) CUSTOMER breaches its obligations hereunder regarding the quality of the BIOSOLIDS. 9.3. In the event of any change in federal, state or local law or regulation, or any change in any one of CONTRACTOR'S permits, which is implemented during the Term of this AGREEMENT and which results in a significant increase or decrease in the cost of performing the SERVICES, the CUSTOMER and CONTRACTOR agree to attempt to negotiate a mutually agreeable adjustment to that payment tern -is specified in this AGREEMENT. Should agreement not be reached, either party may terminate this AGREEMENT as specified in Article 9. -7- Havelock Agreement -Final 11 07 06 doc 10. PRICE 10.1. Except as otherwise provided in this AGREEMENT, CUSTOMER will pay the following fixed prices for CONTRACTOR'S SERVICES hereunder for the duration of the INITIAL TERM of this Agreement Liquid Land Application = $0.057 per gallon Mobilization = Included at no charge 503 Compliance Sampling (if needed) = Cost plus 15% Ag -lime (if needed) = Included at no charge Land Permitting (min 100 acres) = $25.00 per acre 10.2. Upon increases in CONTRACTOR'S costs due to changes in LEGAL REQUIREMENTS, CONTRACTOR may no more than once each an iiversary year, request an increase in the fixed prices set forth hereunder. The parties shall in good faith attempt to negotiate such increase and if successful such shall be effective as of the beginning of the then most current anniversary of the EFFECTIVE DATE. In addition, there will be an annual adjustment for price paid for SERVICES provided by the CONTRACTOR on the anniversary date of the EFFECIVE DATE. The first adjustment shall be on October 1, 2007, and shall be repeated at the end of each twelve months thereafter. The adjustment will be the percent increase or decrease in the Consumer price Index for All Urban Consumers (CPI -U) as published by the U.S. Department of Labor. The adjustment will be made by multiplying the percent increase or decrease in the CPI -U over the most recent twelve months reported tames the current unit price and adding or subtracting the adjustment to the price used during the previous twelve months. 11. MISCELLANEOUS PROVISIONS. 11 1. Assignment. The CUSTOMER and/or CONTRACTOR shall have the right to assign this AGREEMENT an writing to any successor in interest, subject to the written approval of the other party, which approval shall not be unreasonably withheld. 11.2. Governing Law. THIS AGREEMENT AND ALL THE RIGHTS AND DUTIES OF THE PARTIES ARISING FROM OR RELATING IN ANY WAY TO THE SUBJECT MATTER OF THIS AGREEMENT OR THE TRANSACTIONS CONTEMPLATED BY IT, SHALL BE GOVERNED BY, CONSTRUED, AND ENFORCED IN ACCORDANCE WITH THE LAWS OF THE STATE OF NORTH CAROLINA. 11.3. Costs and Fees. The prevailing party in any legal proceeding brought by or against the other party to enforce any provision or term of this AGREEMENT shall be entitled -s- Havelock Agreement -Final 11 07 06 doc to recover against the non -prevailing party the reasonable attorneys' fees, court costs and other expenses incurred by the prevailing party. 11.4. Consent to Breach Not Waiver. No term or provision hereof shall be deemed waived and no breach excused, unless such waiver or consent be in writing and signed by the party claimed to have waived or consented. No consent by any party to, or waiver of, a breach by the other party shall constitute a consent to, waiver of, or excuse of any other different or subsequent breach. 11.5. Severability. If any term or provision of this AGREEMENT should be declared invalid by a court of competent jurisdiction, (i) the remaining terms and provisions of this AGREEMENT shall be unimpaired, and (ii) the invalid tenn or provision shall be replaced by such valid tern or provision as comes closest to the intention underlying the invalid term or provision. 11.6. ENTIRE AGREEMENT. THIS AGREEMENT INCLUDES AND INCORPORATES BY REFERENCE AS IF FULLY SET FORTH HEREIN, ALL OF THE TERMS, CONDITIONS AND OBLIGATIONS CONTAINED IN THIS AGREEMENT, THE INFORMATION FOR PROPOSERS, SPECIFIC PROVISIONS, AND DRAFT SERVICE AGREEMENT (AS AMENDED). THIS AGREEMENT, TAKEN WITH THE INFORMATION FOR PROPOSERS, SPECIFIC PROVISIONS, AND DRAFT SERVICE AGREEMENT (AS AMENDED) HERETO CONSTITUTES THE COMPLETE AND EXCLUSIVE STATEMENT OF THE AGREEMENT BETWEEN THE PARTIES WITH REGARD TO THE MATTERS SET FORTH HEREIN, AND ALL OTHER AGREEMENTS, PROPOSALS, AND REPRESENTATIONS, ORAL OR WRITTEN, EXPRESS OR IMPLIED, WITH REGARD THERETO ARE SUPERSEDED.. 11.7. Amendments. This AGREEMENT may be amended from time to time only by an instrument in writing signed by the parties to this AGREEMENT 11.8. Counterparts. This AGREEMENT maybe executed in counterparts, which together shall constitute one and the same contract. The parties may execute more than one copy of this AGREEMENT, each of which shall constitute an original. 11.9 Preaudit Certification. This instrument has been preaudited in the manner required by the Local Government Budget and Fiscal Control Act. 41teeTillman, Director of Finance -9- Havelock Agreement -Final 11 07 06 doc 12. DEFINITIONS 12.1. "AUTHORIZATIONS" means all authorizations, permits, applications, notices of intent, registrations, variances, and exemptions, required for the removal, transportation and land application of BIOSOLIDS in compliance with all applicable LEGAL REQUIREMENTS. 12.2. `BIOSOLIDS" means sludge meeting Class B pathogen requirements, vector attraction reduction requirements and pollutant concentrations (as defined by 40 CFR Part 503 and State of North Carolina requirements for land application). Blosolhds do not include any hazardous materials or substance and must be suitable for land application under the applicable law. 123. "ENVIRONMENTAL LAWS" means any AUTHORIZATION and any applicable federal, state, or local law, rule, regulation, ordinance, order, decision, principle of common law, consent decree or order, of any GOVERNMENTAL AUTHORITY, now or hereafter in effect relating to HAZARDOUS MATERIALS, BIOSOLIDS, or the protection of the environment, health and safety, or a community's right to know, including without limitation, the Comprehensive Environmental Response, Compensation, and Liability Act, the Resource Conservation and Recovery Act, the Safe Drinking Water Act, the Clean Water Act, the Clean Air Act, the Emergency Planning and Community Right to Know Act, the Hazardous Materials Transportation Act, the Occupational Safety and Health Act, and any analogous state or local law. 12.4. "GOVERNMENTAL AUTHORITY" means any foreign governinental authority, the United States of America, any State of the United States of America, any local authority, and any political subdivision of any of the foregoing, and any agency, department, commission, board, bureau, court, tribunal or any other governmental authority having jurisdiction over this AGREEMENT, 13IOS OLIDS, or COMPANY, HAULER, or any of their respective assets, properties, sites, facilities or operations. 12.5. "HAZARDOUS MATERIALS" means any "petroleum," "oil," "hazardous waste," "hazardous substance," "toxic substance," and "extremely hazardous substance" as such terms are defined, listed, or regulated under ENVIRONMENTAL LAWS, or as they become defined, listed, or regulated under ENVIRONMENTAL LAWS. 12.6. "LEGAL REQUIREMENT" means any AUTHORIZATION and any applicable federal, state, or local law, rule, regulation, ordinance, order, decision, principle of common law, consent decree or order, of any GOVERNMENTAL AUTHORITY, now or hereafter in effect, including without limitation, ENVIRONMENTAL LAWS -10- Havelock Agreement -Final 1107 06 doc 12.7. "REMEDIAL WORK" means investigation, monitoring, clean-up, containment, removal, storage, remedial or restoration work associated with HAZARDOUS MATERIALS or BIOSOLIDS. IN WITNESS WHEREOF, the parties of flus AGREEMENT have hereunto set their hands and seals, dated as of the day and year first herein written. C. ("CUSTO R") ATTEST: 14 aa JJ Q YQS W. me &Title: RQ, Name &Title: Q2\f\6,, MN Go,,-, Synagro Central, LLC. ("CONTRACTOR") FATTEST: Naive & Title: Alvin L. Thomas, Vice President Name & Title: Dovsha G. Roscoe, Asst. Secretary Havelock Agreement -Final 1107 06 doe Amended Appendix A - Draft Service Agreement 1. General 1. No residuals management operations shall occur on Sundays or legal holidays without the approval of the Wastewater Treatment Supervisor. U. All operators shall be well versed with regulations and requirements stipulated in the EPA 40 C.F.R. Part 503 regulations and the Generator's land application permit WQ0000702 with the State of North Carolina Department of Environment and Natural Resources (NCDENR). III. The total percent solids of the residuals produced by the Generator's facilities shall vary from 3% #0 6%.A ATeS ons' , or musep ctionj Vgiupii enT rt is $l' fflion properly in this range. 1V. The Contractor shall remove all unused materials, tools, equipment and machinery, waste materials, refuse and other debris from loading area and land application sites. The Contractor shall see that these sites are at all times left in a neat and orderly condition. V. Liquid residuals shall be transported in sealed tank bodies. The capacity of all tankers and/or any other containers used to calculate the volume of residuals hauled for payment should be certified by an independent agency capable of performing such certification. This certification infonnation shall be supplied in writing to the Wastewater Treatment Supervisor before residuals are hauled for payment. Vi. All application and transportation, vehicles shall be cleaned no less than once per month. If residuals are spilled onto vehicles, contractor shall see that the vehicles are cleaned by the next working day. VII. The Contractor shall be responsible for repair/replacement of all pavement, driveways, fences, shrubs, lawns, trees and other public or private property damaged as result of work performed under agreement with the Generator. 30 VIII. The Contractor shall at all times have a competent project mana11 ger or other representative on the work site who shall have full authority to act for the Contractor and who shall see that the work under the Contract is executed in accordance with the agreement documents. All communications with the project manager shall be binding as if given to the Contractorbut must be confirmed In writing within 24 hours. 2. Permitting 1. The Contractor shall be responsible for the procurement of additional sites suitable for land application and shall be responsible for obtaining and compiling the information ^ I accordance with f sch dule necessary for generation of permit applications/renewals. At a ma,tumum, sukien acreage must be permitted to annually compensate for the number of acres lost during the prior year and any increase in biosoiids productions. which approval shall not be unreasonably withheld n H. All sites shall meet the approval of the Generator prior to permitting by the State. The Generator also reserves the right to prohibit the permitting of any site, but such prohibition is subtect to the reasonableness standard .III. A copy of the Land Application Permit WQ0000702 and all site maps shall be maintained on each application vehicle at all times when residuals are being applied. give Generator reasonable notice IV. The Contractor shall prior to any correspondence with regulatory agencies regarding regulatory issues concerning the Generator. All correspondences shall be copied to the Generator. V. On a yearly basis, every permitting event, or in the event that development or other issues require changes in buffers/maps, the Contractor shall be responsible for providing updated maps for the Land Application Site Books. The project manager shall evaluate each site during application event for possible adjustments to buffers/maps. 3. Emergency ResponselSpills 1. The Contractor shall submit to the Generator for approval a Spill Control Plan. II. A copy of the Spill Control Plan shall be maintained in each transport and application velucle used by the Contractor. 31 III. Any spills involved with the loading, transportation and/or application of the said residuals shall be deemed the responsibility of the Contractor and shall be cleaned up inunediately to the satiaspactibon of the Generator, NCDENR, Division of Water Quality and/or any landowner that may be involved. Any occurrences shall be inumdiately reported to the Wastewater Treatment Supervisor. 4. Beneficial Reuse I. The Contractor shall utilize equipment capable of both surface application and ,,ubsurface uijection/incorporation ind shall provide such capability at the request of the enerator 1dfi4& as is required to meet vector attraction reduction requirements. at a negotiated price) II. No residuals generated by the Generator shall be stored at facilities or land -applied on land not permitted/approved in the Generator's land application permit for NC DENR. III. All buffer zones shall be marked#x prior to land application. IV. Any interruption (other than inclement weather) of the beneficial reuse activities for any period of time longer than (2) days shall be reported to the Generator immediately, when such interruption is determined. V. The Contractor shall provide adequate supervision of its employees to mgr proper application tech-niques are being utilized at all times. VI. The Contractor shall provide individuals who are capable of and can maintain good relations with the program participants. Failure to do so shall be grounds for the immediate suspension of work and the possibility of the revocation of agreement, VII. The Contractor shall make every effort to provide residuals application to all program participants. VIII. The Contractor shall provide the landowner with a copy of the analysis of residuals land applied to his/her field.(farm report) IX. Transporters of the Contractor should be aware that they present an image of the Generator, therefore they should properly and professionally respond to any complaints by citizens and/or the Generator. This includes but is not limited to obeying all traffic laws. 32 5. Monitoring/Recordkeeping I. The Contractor shall be responsible for all monitoring at the land application sites as required by the Generator's Land Application permit nWQ0000702 and the EPA 40 C.F.R. Part. All residuals sampling shall be the responsibility of the Generator's V►WTP Personnel. H. All infonnation shall be kept on file with the Contractor and the Generator. The Generator requires that the Contractor have a database management system for the storage of data for residuals management activities performed for the Generator. Um III. The Contractor shall keep daily logs indicating tanker loading, transportation, and application volumes, These logs shall be totaled daily and a copy submitted to the Generator's Residuals Supervisor no later than 4:00 p.m. on the first working day of the following week. IV. A report, after each land application event, shall be provided to the Generator indicating volume of residuals, application rate per acre, land applied, and land application site information. This information shall include all information as required by the land application permit and 40 C.F.R. Part 503 regulations. These records shall be submitted to the Generator by the 15'h day of the following month after the application event 6. Public Education/Acceptance cooperate with Generator I. The Contractor shall h&inodywiin a Public Education Campaign for the Generator. H. The Contractor shall assist the Generator with the handling of complaints and/or questions regarding all residual management activities. III. The Contractor shall maintain good relations with program participants and shall provide documented notification of biosolids issues that could impact program/particip ants. N. The Contractor shall assist the Generator with any other public notification that maybe required by the regulatory agencies. 33 City of Havelock Wastewater Treatment Plant City of Havelock, North Carolina First Species Effluent Toxicity Testing Data 2015-2017 iceAnajt4ica' Plce Analytical Pa � 1 Laboratory Report Nit An Hough City of Havelock RCCOff tele 03. �� , Drawer 358 Date Rc c -;ped 304 N Jackson Dr Havelock, NC 28532 P-ole:.t BIOASSAY C2118115 Pate Protect No G2237S53 Sampla PIPE 007 Lab ID 92237953001 Collcc Pa amoters Rasuits C duh�a Ful--ange Chonlc Units Repert L mr AI ,'y r d nu l tiers Rei -..ed by-- S:a�y Tark- SiaCy t, "loot f)awlaos (o11) Raleigh Certification 1ps 3%'l Ccrrcion ; Di e r ., �i,l NC 27,50, No,it: (arehna l4'astc :ate1 Cc ficaUon r Nn't, iot n Bio;" ay C- „fi--a , un r 57 N0111 CargL'7a -)I ':'n.7 Mmol i erjifli P 'U ! 177,1 Effluent Aquatic Toxicity Report Form/Phase II Chronic Ceriodaphnia Facility Havelock VWVTP NPDES# NC 0021253 Pipe# 001 County Craven Laboratory Performing Test -Face Analytical Sernces Inc, Raleigh Comments INCO 92237953 x G n JG,I I� X Signature of O R C J :'Signature of Lab Supervisor SampEe Information Collection Start Date Grab Composite (DUralion) Hardness(mg1 Spec Cono (prnhos/cn Chlonne(mgf Sample temp at receip Sample 1 Sample 2 Control 02/16115 02/18/15 Er*1 Time 9 41 5far ---------- Start Reruw' penew, 24 24 24 " 824 786 822 48 678 672 210 <0 1 <0 1 782 783 790 630 05 "c ; Test Information` Treatment pH Initial pH Final D O Initial DO Final Temp Initial Temp Final Start Date 02118/ 15 End Date 02/25/15 ,wt Trnte 12 40 Er*1 Time 9 41 5far Renewl Re'rev,2 Start Reruw' penew, r 10o - 100 100 " Lonnul c-ontrol Conlrcl 824 786 822 780 7 70 792 866 862 856 784 796 780 8 19 874 f 769 782 783 790 630 830 344 7 00 8 11 859 24 1 253 244 24 2 243 24 5 251 253 253 254 259 24 1 Organism# Chronic Test Results 1 2 3 4 5 6 7 8 9 10 1' 12 Final Control Mortality 9 0 Control ',U Contiol 3rd 6roo. 100 Control Repro C4 48 Hour tulortaiity Control ivVC 1 23 4 5 G 7 8 9 10 11 12 ^�� Sign,ficant?� ® EAdult Effluent% # Young 23 25 25 24 1 24 18 26 25 25 # Young 21 26 25 28 22 24 25 25 20 31 L L 247 Adult (L)ive (D)ead L L L L L L L L L L 26 26 23 ',U Contiol 3rd 6roo. 100 Control Repro C4 48 Hour tulortaiity Control ivVC 1 23 4 5 G 7 8 9 10 11 12 ^�� Sign,ficant?� ® EAdult Effluent% # Young 23 25 25 24 1 24 18 26 25 25 26 31 za 4 12 (L)ive (D)ead L29 L L L L L L L L L L L °°°Final Mortality St ni icant °/u or N4 CGlit, — — 14— Effluent% # Young L36 2926 26 26 23 2921 2425 �cr Rep oJuctior lyAnasts RPprn t OEC=`110", NOEC= 100Adult Melt od Dunnelta(1-ave Normal Dslnn� �= atetnod KJIR76GO(OJ tic 0,30638 Crrcal 1 i,35 (D)ead L L L L L IL IL L L �.j , Effluent% 90 Effluent% 95 Lqual Vdnances?_ "it's Method 3aritetts Statstic 41E4f6 Cmical 150863 Non_Patanietnc, "^ riaiysis h appitcabie) Method _ Effluent N�- nh Sum Cr tical Sura 1 2 3 4 5 6 7 8 9 10 tl,, Effluent% # Young 20 23 1 28 27 32 21 26 26 23 23 249 Overall Analysis Rosull = Pass or 100 adult L L L L L L L L L L Test LOEC= 100 %. NOEC= 100 °rn (L)ive (D)ead es, Chronic Value= X100 °! Shou.d use highest test concenlration or ATT Environmental Sciences Branch highest concr,ntratio 1 with D 0 = f o mgn MAIL Div of Water Quality N C DENR TO: 1621 Mall Service Center Raleigh N C 27699-1621 DWQ form AT -3 (8/9') Rev 11195 # Young 26 26 31 19 12 24 25 27 1 21 24 23 5 Adult L L L L L L L L IL L 4 '` (L)ive (D)ead Lqual Vdnances?_ "it's Method 3aritetts Statstic 41E4f6 Cmical 150863 Non_Patanietnc, "^ riaiysis h appitcabie) Method _ Effluent N�- nh Sum Cr tical Sura 1 2 3 4 5 6 7 8 9 10 tl,, Effluent% # Young 20 23 1 28 27 32 21 26 26 23 23 249 Overall Analysis Rosull = Pass or 100 adult L L L L L L L L L L Test LOEC= 100 %. NOEC= 100 °rn (L)ive (D)ead es, Chronic Value= X100 °! Shou.d use highest test concenlration or ATT Environmental Sciences Branch highest concr,ntratio 1 with D 0 = f o mgn MAIL Div of Water Quality N C DENR TO: 1621 Mall Service Center Raleigh N C 27699-1621 DWQ form AT -3 (8/9') Rev 11195 Young 27 23 33 24 29 31 1 23 23 27 2726 7 Adult (L)Ive (D)ead L L L L L L L L L L t, tt Lqual Vdnances?_ "it's Method 3aritetts Statstic 41E4f6 Cmical 150863 Non_Patanietnc, "^ riaiysis h appitcabie) Method _ Effluent N�- nh Sum Cr tical Sura 1 2 3 4 5 6 7 8 9 10 tl,, Effluent% # Young 20 23 1 28 27 32 21 26 26 23 23 249 Overall Analysis Rosull = Pass or 100 adult L L L L L L L L L L Test LOEC= 100 %. NOEC= 100 °rn (L)ive (D)ead es, Chronic Value= X100 °! Shou.d use highest test concenlration or ATT Environmental Sciences Branch highest concr,ntratio 1 with D 0 = f o mgn MAIL Div of Water Quality N C DENR TO: 1621 Mall Service Center Raleigh N C 27699-1621 DWQ form AT -3 (8/9') Rev 11195 control Ceriodaphnia Survival and Reproduction Test -Reproduction Start Date 2/1$;2015 Test ID havelock Sample !D End Date 2125/2015 Lab ID FACE -Pace - Raleigh -016 Sample type Sample Date Protocol EPAF 91 -ERA Freshwater Test Saocies CD Cenodaphnia dubia Comments 25 000 2,1000 2.1 OOC Conc-% 1 2 3 4 5 6 7 8 9 10 control 21 UUU 26 000 25 000 28 000 22 000 2-1000 25 000 25 000 20 000 31 000 45 29 000 23 000 25 000 25 000 2,1000 2.1 OOC 18 000 26.000 25 000 25 000 675 36 000 29 000 2.6 000 26 000 26 000 94 000 29 ON 21 000 24 000 25 000 90 26 000 26 000 31 000 19 000 12 000 24 OUO 25 Off 27 000 21 000 2-1000 95 27000 23 000 33 000 24 000 29 000 31 000 23 OOC 23 000 ?1000 270,)o 100 20 000 23 000 28 nOO 27000 32 000 21 000 ?6,000 20 OOO 23 000 23 OOu Cone % Mean N -Mean Mean Transform- Untransformed Min Max CV°o N t -Stat 1 -Tailed Critical MSD control 2,1700 1 0000 24 700 20,000 31 000 13 230 10 MSB MSE F-Prob df 45 24 400 09879 24 400 18 000 29 000 11 298 10 0 175 2 287 3 9' 3 675 26 500 1 0729 26 500 21 000 36 000 15 635 10 -1 052 2 287 3 9':) 90 23 500 09514 23 50C 12 000 31 000 2208-D 10 0 701 2 287 3 913 95 26 700 1 0810 26 700 23 000 33 000 13 ? 18 10 -1 169 2 267 3 013 100 24 900 1 0081 24900 20 000 32 000 1447-1 10 -0 117 2287 3 913 Auxiliary Tests Statistic Critical Skew Kurt Kolmn9orov D Test indicates normal distnoution (p > 0 01) 066608 1 035 -C 0517 1 157.=8 Bartlett's Test indicates equal variances (p = 0 53) 4 16405 150863 Hypothesis Test (1 -tail, 0.05) NOEC LOEC ChV TU MSDu MSDp MSB MSE F-Prob df Dunnett's Tcst 100 >100 1 391266 0158,11 15 5367 14 6389 039193 5,54 40 35 30 225 =O 20 0 Q cc 15 10 F Dose -Response Piot T . . . . . . . y .. . . . . . .. . . . . . . y . . . . . . . . . . . . . . . � 04- 1 -tail 0 05 level at significance Page 1 ToxCalc, v5 0 23 Reviewed by T-) ) - t'oeacentration— Control 7 � I Total G L i L' Y � I Total c < � 2 - 7 - - --— •' ota l �A 2 � l 7 Total — Replicates - - - --- - — ---------� Lt:-- •'� I �! 1 1 �- 1 ite E7� r Pace lnaly tical 3•'es11sr l'nne C erlo(%fZf hifia dribia Chronic Fest _ 2 LLL' 5- I NPDhS ft •--�� � I�`l� '� !r � t lilt lit, [ratl,i�ilnAtCIltticl tf�'_. _-���`'-- Oro,tm,mHornIDat�'7llnli <_I_j'.��_, ��� -� ��. l!Z I „nc f r�i r( ulturi 1 �j�5_ Orvalli'm '-walt-r r' j` '�z'I �-`I 'r �'`- � Da" 1 ._)� „�• 1 t C)r .lnt`m �S— 01 U110 )ti 1 � _� 1tll Il l) 1t1t1U11 ��a`cI 1C1111, roolell lll"ll J 7 - DaN 4DLUL- _ I Illy -- �c r lnal ,I Ranuorm/cel V"' Incubator �� DaN _ c < 1 lrin,irr Dat, t5'— I lm� —� �nahst I ra t,trr DatC Tlmc --- - `-Yi " 1--nditn€ Date 111C alN `t Rc\ - t'oeacentration— Control 7 � I Total G L i L' Y � I Total c < � 2 - 7 - - --— •' ota l �A 2 � l 7 Total — Replicates - - - --- - — ---------� Lt:-- •'� I �! 1 1 �- 1 ite E7� r I otal I t « til l� _ 2 LLL' 5- I otal I LLL' I I. Pace Ana a tica i Incnhatot # 1I)A 1)alr m'])1 5 it: Raltdmmvecl �f --- 1't d 1) 11c ? 1 tlnc 2'�� D1lutlan 1l�atcr Batch- ��'�"�� Cul;utc !Valet '1'ct-,' 1 _�.-, •-___ : • Tc,t1--- ;lmctcl — Cmnirml Collection DatC � ��a ����.Qt; Sample 1"emp CC• ► , ,: i pII 100% ------ `: _ p Chlorine (ttl('/l_,l- '- CondlictICit) (pslent) I Tardncss (nr�!L) ---� ��._—�—...�N ___e�__w.. � IOO`i�cillilcnl) � (l�tl)`��':ilill�tll) _� Illi Start End St_��rt � hrttt Start t;tl[I__ Control � �r�•y xi � "lYcalment 2 „ L' � � c �• �.Ct �� -h '��� � � � t'-t�` � � ��'� r .:t �� I � j�„ mo. Start End st.11A I;rtd � ;start I I;atti ( nig/ l Cmntlol { c III -4 C)c,-- tri r GJ r 5\f- - `( TI e,ament 2 a _x Y-= - •-- J •' `� -`►t<iCt � u , Temp_{rattire End stat't � i' Itil � �tttf"t 1 i I'nd Colitiol Treatment ^ ;lmctcl — Cmnirml Collection DatC � ��a ����.Qt; Sample 1"emp CC• ► , ,: i pII 100% ------ `: _ p Chlorine (ttl('/l_,l- '- CondlictICit) (pslent) I Tardncss (nr�!L) ---� ��._—�—...�N IOO`i�cillilcnl) � (l�tl)`��':ilill�tll) _� kC� � �r�•y xi � 4r xA�ls `r 2 1 =l5' F Y, n irm El. -r L Dc.—sav Cham JL -;.Djn�v 1-9n lit Urlue,,-, DALItIO-1 IJVVC:). (!(Jc Pla-it Flo4� 8ariPle, Collector PlInt ------- --- -- Composite )aa Time ,)-A3 Ended q jj; Pi Sarnnlc"; P.'I' Hr H.s Grab Date Titre !L&.' or IDM , ajqp,e_ I lol I 11IR'd d Li HI I�Q 1&7 f It tMethod of to tne Lab ,.tlqlrl () (,,I:; Oc IV Ci 8£8 71 r7R,t,I:nquIbh(-�d B -v Time F.'-ue comments For Pace IrIc. US,1201-liy W o r k 0 i . Ie. r N U I - I b 0 r. Recumg ',empeiatura By tie Fac_ A-Illyt- -'11 Seg cAms, Inc Mdress 0701 3011"Mrc- 1"; , F'Ach 'Ac '7607 (91 Ali, 1, Ch-Rirl OI GU3t0dV FO011 cl D lutioc, (INC) 0 c C�h Qici6l,,) (A'Aector Print uuro ocamolc rwo composhe Date Stal tad Date, E-7,ided Sarl"plf:-, per H, G nab Date SarrlPl) VQ,Lfn,(-, '?, d, i5 T-11 1"c" JN In') Ll iod (if I rinspoi tation to tne Time All or U, chilled uun)g CIT2 1-11 OTC; L I F G or Gornments: r! 1.jr7 For Pace Analytieal, m-. Use -�) PaC 0 Woo,Ordol %lllb-:,r .1y Rcx,emng Tornponaturc- 5-T R.eccx'd By, �j," PaceAnalytiu-al SenJC�S, Inc P%ddMl�s Gonfron, r Fir rpip:g!,ri, 276o,, F,,,cfj- [rile zr, n -cj by Gornments: r! 1.jr7 For Pace Analytieal, m-. Use -�) PaC 0 Woo,Ordol %lllb-:,r .1y Rcx,emng Tornponaturc- 5-T R.eccx'd By, �j," PaceAnalytiu-al SenJC�S, Inc P%ddMl�s Gonfron, r Fir rpip:g!,ri, 276o,, F,,,cfj- Face Analytical ")-A",.1s"wi Mr Art Hough City of Havelock Drawer 368 304 N Jackson Dr Havelock, NC 28532 Project Metals 1%29 Pace Project No 92238951 Sample. HAVELOCK BIOASSAY METALS Laboratory Report Pace Analyttrai Servines, Inc 1225 AShcv �NC tcttl: Page 1 of i Report Date 03103/2015 Date Recelvea 02126/201 5 Lab ID 92238951001 Collected 01-29;15 08 00 Matrix mater Parameters Results Units Report L nut Analyzed 4loahfiors Aluminum ND -g'L 100 03/02/15 21 15 Antimony ND ugrL 50 33/02/15 21 15 Arsenic ND ugrL 10 0 0°•,02115 21 15 Barium ND ugrL 50 0 102' 15 1.1 15 Beryllium Nn ugrL 1 0 03/02/15 21 15 Boron 122 ugiL 500 03/03/15 15 2C Cadmium ND ugiL 1 0 03/02'15 21 15 Calc um 39000 ugrL 100 031C2 15 2' 15 Chromium ND UU/l- 50 03102,15 2. 15 Cobalt ND ug/L 5 0 031C2,15 2 15 Cooper ND ugrL 5 C 03/02.15 21 15 Iron ND a 11- 9 50 C 03102,15 � I 5 Lead ND uc;4- 5C 03107,1521'5 Maanesrum 2120 ug,'L 100 03'0211511 15 Manganese 6-0 ug/L 50 03,'02;15-1115 Molybcenum ND ug/L 5 0 03'02,15 21 15 Nickel ND uy/L 50 C3 02115 21 15 Potassium 6110 ug/L 530C 63,02_;1521 15 Selenium ND 119/1 10 0 03102 115 21 15 S.licon 6240 ugrL 100 0+'02/15 21 15 Silver ND ug/l- 5 0 03/02/15 71 15 SOCiLr11 80000 ugrL 5060 03,'02,15 21 I r Strontium 145 ug/L i 0 03102;15 2 115 Thallium ND ,1911- 100 03,'02,'15 2 1 15 Tin ND tg/L 5 0 03/02/15 21 15 Ti.anium ND u0/1 5 0 03102/15 2, 15 Vanadium ND ug/L 50 03i32115 2 1 1 r -i Zinc 370 ug; L 10 0 03/02 5 21 15 Revievied by Stacv Taile stacy tarle,c pacalabs com Asheville Certification IDs 2225 Riverside Drive Asheville, NC 28804 North CdroDna UVas'ewaler Certification # 40 Florida/NELAP Certification n E8l648 South Carolina Cer, ficatror # 99030001 Massachusetts Certification # M-NCO30 West Virginia Certification A 356 North Carolina Dnnki-ig Water Certification # 37712 Virgmia'VELAP Certlf cation a 46022" Cleaning lab wait .or WET testing Steps Initials/ date Clean pickle jar with 1/10 oz liquinox and tap water Rinse with cold tap water twice. Mix up 10% nirtic acid solution in fume hood wear appropriate PPE. Rinse pickle far with 10% nitric acid solution with lid on far Rinse jar with deionized water twice Rinse jar with pesticide grade acetone Use fume hood and wear PPE as required r' Rinse jar with deionized water three times. Take jar to sampling point effluent sampler. Replace sampler tubing with new food grade silicone tubing Rinse tubing and far 3 time with sample water. Ensure jar is filled with sample water. Empty jar and put in sampler and begin sampling. Repeat steps every sampling event effluent Toxicity Report Form - Chronic Pass/Fa3.1 and Acuti.- LCI-, Date: 04/21/15 Fa:ility: CITY C,F HAVELOCK WWTP NPDES# NCO021253 Fipeg, 001 County, CRAVEN Laboratory Performing Test: PACE ANALYTICAL Comment~. X � .�,-.nn X gna Work Order: 92244399 isor * PA2SED: 8.27% deduction Environmer,,al Sciences Branch MAIL ORIGINAL TO. Div. of Water Quality N.C. DENR 1621 Mail Service Center Raleigh, North Carolina 27699-1621 Iorth Carolina Ceriodapnnia Chronic Pass/Fall Reproduction Toxicity Test .ONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 4 Young Produced 1135133136128132134126133127129133129 Adult (L)ive (D)ead JAL IL IL IL IL IL IL IL IL IL IL IL effluent 6: 906 'REATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 Control CV 10.580% # Young Produced 33133125130 24 31129128 27 29 27 28 6 control orgs producing 3rd brood Adult (L) ive (D) ead TLL L JL_ L L L L L L IL L 11 1001-. Chronic Test Results Calculated t = 2.063 Tabular t = 2 508 Reduction = 8.27 6 Mortality Avg.Reprod. 0 00 31.25 Control Control 0.00 28.67 Treatment 2 Treatment 2 PASS FAIL F] El Check One 1st sample 1st sample 2nd sample Complete This For Either Test pH Test Start Date: 04/08/15 Control 7 71 7.20 7.38 7.69 7.58 7 68 Collection (Start) Date Sample 1: 04/06/15 Sample 2. 04/08/15 Treatment 2 8 30 7.95 8.26 8.59 8.40 8 45 Sample Type/Duration 2nd 1st P/F s s s Grab Comp Duration D t e t e t e - I S S a n a n a n Sample 1 X 24 hrs L A A r d r d r d U M M t t t Sample 2 X 24 hrs T P P lst sample 1st sample 2nd sample D.O. Hardness(mg/1) 50 ........ ......... Control 7.13 8.10 6 39 4 85 7.78 6.99 Spec. Cond.(µmhos) 241 779 762 Treatment 2 8 07 7.85 7.73 6.05 6.25 5.98 Chlorine(mg/1) ,,,,,.,. <0.1 <0.1 LC50/Acute Toxicity Test Sample temp_ at receipt(OC) ,,,,.,., 0 9 0.5 (Mortality expressed as 6, combining replicates) Note: Please % % % 6 % Concentration Complete This ° a ° o ° o o s ° Section Also o Mortality start/end start/end LC50 = - Method of Determination Control 95% Confidenceimits Moving Average Probit _ Spearman Karber — Other High Conc. pH D 0. Organism Tested: Ceriodaphnia dubia Duration(hrs): Copied from DWQ form AT -1 (3/87) rev. 11/95 (DUBIA ver. 4 41) e t Effluent Toxicity Statistical Results - Chronic Pass/Fail Date: 04/21/15 Facility: CITY OF HAVELOCK WWTP NPDES#: N00021253 Pipe#• 001 County.CRAVEN Laboratory Performing Test: PACE ANALYTICAL 0 3333 Reduction: 8.27% CONTROL 90a Effluent # Replicates 12 12 Female Live 12 12 Adult Male 0 0 Adult Dead 0 30 1 3333 4 0 Adult Mortality 0.001 0.0096 # Neonates 375 344 Mean # Neonates 31.250 28.667 Standard Deviation 3.306 2.807 Coefficient of Variation 10.580% 6 Fisher's Exact Test A = 12 B = 12 a = 12 b = 12 a/A = 1.00 b/B = 1.00 Success is survival Critical b value = 8 12 > 8 The test concludes that the proportion of survival is not significantly different for the control and the effluent groups. Test Passes! SHAPIRO-WILK'S TEST FOR NORMAL DISTRIBUTION OF DATA ORDERED OBSERVATIONS I Group Neonates Centered i Group Neonates Centered 1 C 26 -5.2500 13 E 29 0 3333 2 E 24 -4.6667 14 C 32 0.7500 3 C 27 -4.2500 15 E 30 1 3333 4 E 25 -3.6667 16 C 33 1.7500 5 C 28 -3.2500 17 C 33 1 7500 6 C 29 -2.2500 18 C 33 1 7500 7 C 29 -2.2500 19 E 31 2.3333 8 E 27 -1.6667 20 C 34 2 7500 9 E 27 -1.6667 21 C 35 3.7500 10 E 28 -0.6667 22 E 33 4 3333 11 E 28 -0.6667 23 E 33 4.3333 12 E 29 0.3333 24 C 36 4.7500 SHAPIRO-WILK'S TEST FOR NORMAL DISTRIBUTION OF DATA (cont ) COEFFICIENTS AND DIFFERENCES 1 x(n-i-1) x(I) a(i) x(n-i-1) - x(i) 1 2 4.7500 4.3333 -5.2500 0.4493 10.0000 3 4.3333 -4.6667 -4.2500 0 3098 9 0000 4 3.7500 -3.6667 0.2554 0.2145 8.5833 5 6 2.7500 -3.2500 0.1807 7 4167 6 6 0000 0000 7 2.3333 1.7500 -2.2500 0.1512 5833 8 1.7500 -2.2500 -1.6667 0.1245 4.0000 9 1.7500 -1.6667 0.0997 0.0764 3.4167 10 11 1.3333 -0.6667 0.0539 3 4167 2.0000 12 0.7500 0.3333 -0.6667 0.0321 1.4167 0.3333 0.0107 0.0000 1 W = 206.9167 Calculated W = 0.960 X 198.6524 Critical W = 0.884 0.960 a 0.884 The reproduction data is normally distributed evaluated at a 99% confidence interval. Test Passes! F test for Homogeneity of Variance Control variance 10.9318 F = - = 1.39 Effluent variance 7.8788 Numerator degrees of freedom: 11 Denominator degrees of freedom: 11 Critical F = 5.32 1.39 s 5.32 =► The Test PASSES, the variances of the two groups are significantly the same, homogeneous. EQUAL VARIANCE t TEST 31.3 - 28.7 t = = 2.063 1.252 Degrees of freedom = 22 Critical t = 2 508 2.063 < 2.508 Test passed. There is not a significant difference in reproduction between the Control and the effluent evaluated at a 990 confidence interval Chronic Test PASSES 0 e 'q"rdmdaFhnia dubia tCh onk Pass/Faf. T Client: NPDES #. NC Culture l:ansfer (Da1te,�/Ti,� e : - Age of Orga333zm { " i� Organism Born (Date/Time)- Ddution Water Batch: Time Ped (Culture) Start Date: Z44— Temp Dilution Water: I" Transfer Date -Time- y Analyst � ` Randomi 2 1�ansfer Date Tune: Ending Date - Analyst• _ --- Time, Analyst: C©�atr®1-------------------------- ----------------------------------------- - Day 1 2 3 4 5 6 7 8 ---. # Youngproduced �(C1 9 1 a Adult Live, Dead r i +- Day 5 1 4# Young Producedf i �3 4r _ 5 h �. g 9 10 U tet) P # Total produced Test �sj— — �- _ _` Days Fed ]By Time l� / -- 1��C� Organism source: -.�L�, Temp .Cock Day p Day I solution � ed: V Incubator: �A,Z Day 2 2-D Day 3 1 Z- uS ;wed by:S i Day 4 Day 51 2 ----------------; Day 6 11 12 Collection (Start) Date D.O. Start 1S` Sample. r 2nd Sample L— SaYmPle TylseMuua-tion Control 11 12 / . Grab is' sample- ample12 Cornposite Duratior_ 12i i COntT01 1S` Sample 2n Sample Hardness (mg/L) Ll 12 Conductivity (ILS1cm)I 2-14 `] --u 3 ' Chlorme Sample Temp (°C) c�> 5 11 12 pH 100% 3� PH Start Enol! Start End -Eand. Control 2-D I.6Z ,1• CC -1 Treatment D.O. Start End Start End � Start End Control I yJ 10 ' 25 11 1212 _ Temp` Start F,rnd Start End St:. n¢, i w'nti Control ------------------ Tzeaiznezlt; a-�-wuicni ivGlOe Uare ROVI3ed June 22, 2011 lCa/ Bioassay Chain of Custody Page 1 of 1 ° ( , Document Numbei RAL-CS-007-iev 01 issuing Authority — Pace Carolinas Quahiy r m n B10cqssay Chain ®f CUsfady Fora Facility Name �(� Address.�4 k -------- - - �h-a P.0 Box County l Ta\jen % Effluent Dilution (iWC)• 160110 __�� Plant Flow Is Sample Collector, Print Signat Samp— le- Type composite Date Started Date Ended Samples per Hr Grab Date Sample Volume. Contact _ �r-}- -�-I�•} �q� --- NPDES permit# ��I--a�'-- pipe - Test Method C.e�rll���I Ll _� Time.Q_ I &r PM :15 Tune; pyC; 6 -or PM Hrs jMethod of Transportation fio the Lab_ Time ___-_•________AM or PM Chilled during Collect%9Wes r No ®r PrValInc, Use Only Pace Work Order Dumber. ���t, Receiving Temperature. 0 y r� Ret;eued By: Pace Analytical Services, Inc Address* 67n1 Conference Dr, Raleigh NC 27607 Phone (919)834-4984 wbufnenl NaMO Bioassay Chain of Cush Document Number -MLL S -007 -rev 05 JB6Oa-ssay Chain ®f Cusi®dy Form Facility Name d r 40, V(-) 1 Address: uato Revised. June 22, 2012 Page 1 of 1 Issuing Authority Pace Carolinas Quality Office 56 r PO E3ox _ Va Gm lo/7 Contact P County: ���/en NPDES permit#.ISL°OSI �;SVo pipe: 6 4 Effluent Dilution (IWC): l— Test Method. r 0 6 J Plant Flow: J, r M (r k^j ff Sample Collector: Print Signa Sample Type: composite Date Started Date Ended Samples per Nr Grab Date: Sample Volume. ! Time -, PM a S Time: D M r PM # I irs: Time: Alti9 or PM Chilled during Collectun? Yes or No Tiatn o us o v e ease _ __ r■I��11M/i{!�/1I�/'1���,.'�!`l/,II/�.C�ill�,i.'I� �� I _.. i 111VIA 11"UMS: For Pace Analytical, Inc. Use only Pace Work Order Number. Receiving Temperature: I ' Receved gy: ' Pace Analytical Services, Inc Address 6701 Conference Dr., Raleigh, N 27607 Phone (9`19)834-4 84 environments , Inc. FU Box 15414, Greenville, SC 29606 (864) 877-6942 FAX (864) 877-6938 Craftsman Court, Greer, SC 29650 TOXICITY IDENTIFICATION EVALUATION USING EDTA CHELATION TO INVESTIGATE THE POTENTIAL ROLE OF COPPER AND ZINC IN EFFLUENT TOXICITY Facility: City of Havelock, NC Sample ID: WWTP Effluent April 2015 Page 1 of 22 1.0 INTRODUCTION In March 2015 a chronic pass/fail toxicity test of effluent from the City of Havelock wastewater treatment plant (WWTP) indicated a failure Under the Division of Water Resources ATB Action Level Document for Copper and Zinc (10/25/2000), a toxicity test failure must be followed either by acceptance of copper and zinc limits or by testing options to confirm that these metals were not the cause of toxicity. In response to the March 2015 toxicity failure, the City of Havelock has opted to use Option 3, which involves the EDTA treatment under a Toxicity Identification Evaluation to investigate the role of copper and zinc Specifically, a sample of effluent was tested for chronic toxicity with and without addition of the metal chelator EDTA EDTA is effective for removal of toxicity caused by cationic metals such as copper and zinc This report presents the results of the investigation. Page 2 of 22 Havelock: TIE/EDTA Investigation ETT; April 2015 2.0 SAMPLE COLLECTION A sample of effluent was collected on March 20, 2015 It was assigned ETT ID#44986 3.0 TREATMENT METHODOLOGY A stock solution of 500 mg/L of disodium EDTA was prepared by adding 0.5 g of solid to 1000 mL of deiomzed water. 10 mL of the 500 ing/L stock solution were added to 1000 mL of Havelock effluent. This provided an aliquot of effluent with 5 mg/L of EDTA The 5.0 mg/L EDTA spiked effluent was diluted with surface water to prepare test concentrations of 45, 60, 75, 90 and 100%. These samples were used to initiate the test and to renew the test solutions on Day 2 and Day 5 of the test, as per NCDENR protocols. An aliquot of surface water also was spiked with 5.0 mg/L of EDTA to function as an EDTA control Page 3 of 22 Havelock: TIE/EDTA Investigation ETT; April 2015 4.0 TOXICITY TESTING METHODS Toxicity testing was conducted using the Short-term Methods for Measia-117g the Chronic Toxicity of Effluents and Receiving Waters to Freshwater Organisms Method 2002 EPA -821-R-02-013 and modified per NCDENR protocols. The test organism was Cei iodaphnia dubia and the dilution water was Hardness Adjusted (45-50 mg/L) Surface Water. Test organisms were fed 2-5 hours prior to test initiation with Pseudokirchneriella subcapitata and YAT. Each test dilution was comprised of ten replicates of 1 test organism Page 4 of 22 Havelock: TIE/EDTA Investigation ETT; April 2015 Ceriodaphnia dubia I Temperature: 25°C f 1 2.Light- 100 ft -cd; 16 hr It/8 hr dk 3 Test Chamber Size: 30 mL plastic cup 4.Test Solution Volume- 15 mL 5.Renewal• Day 2 and day 5 6 Age of Test Organisms. <24 hours 7.No of Neonates / Test Chamber 1 8.No. Replicates /Dilution 10 9 Feeding: Daily 10 Cleaning of Test Chambers: None 11.Aeration. None 12 -Dilution Water Hardness adjusted (45-50 mg/L) surface water 13 Effluent Concentrations: 0, 45, 60, 75, 90, 100% 14.Dilution Factor- NA 15.Test Duration- 7 days Page 4 of 22 Havelock: TIE/EDTA Investigation ETT; April 2015 5.0 RESULTS AND DISCUSSION 5.1 Review of Results Measured Copper in untreated effluent <5 0 ug/L Measured Zinc in untreated effluent. 51 0 ug/L Toxicity test results for treated samples are summarized by treatment, as follows, Mean Reproduction By Test Concentration 0% 45% 60% 75% 90% 100% IC25 Results Untreated Effluent 21 8 169 19 1 194 21 8 226 >100% Sample not toxic (Baseline Test) 5 mg/L EDTA 21 8 203 198 22 1 209 187 >100% Sample not toxic Spiked Effluent 5.2 Baseline Test There was no chronic toxicity found in the untreated effluent In as much as the sample was identified as being chronically toxic in the March 2015 pass/fail chronic test, it seems likely that whatever toxicity may have been present had degraded or volatilized Toxicity due to cationic metals, such as copper and zinc, is persistent and would be expected to continue to be present in the sample after the holding period. Thus, this is evidence that toxicity in the original test was not a result of elevated aqueous copper or zinc 5.3 diked 5 mg/L EDTA Test No toxicity was present in the untreated sample, therefore the effect of EDTA could not be determined 5.4 Measured Metal Concentrations Measured concentrations of copper and zinc were too low to be a potential cause of toxicity It would be expected that copper concentrations would need to exceed 30 ug/L and zinc concentrations exceed 200 ug/L to result in chronic toxicity Page 5 of 22 Havelock: TIE/EDTA Investigation ETT; April 2015 6.0 SUMMARY • No toxicity was present in the untreated sample • Test results indicate that toxicity did not result from copper and zinc There are two lines of evidence for this conclusion; 1). Toxicity was not persistent Toxicity due to copper and/or zinc would be expected to be persistent in as much as these metals do not degrade or volatilize 2) Measured concentrations of copper and zinc were too low to result in chronic toxicity to the test organism Ceriodaphnia dubia • The effectiveness of EDTA treatment for chelation of copper and zinc could not be determined due to the absence of toxicity in the untreated sample. Page 6 of 22 Havelock: TIE/EDTA Investigation ETT; April 2015 Effluent Aquatic Toxicity Report Form/Phase II Chronic Ceriodaphnia Facility CITY OF HAVELOCK NPDES # NC 0021253 PI e� 001 County Craven Equal Var? yes Method Laboratory Performing Test ETT Environmental, Inc Comments 4 5 6 7 8 # Youn 29 18 18 20 16 19 Baseline for EDTA Treatment 20 21 Signature of 0 R C Signature of Lab Supervisor Adult Test e End Date Time Info 0 04/22/15 12 50 Sample Information Sampler Sample Control ewall Renewal2 tart Renewal Renewal2 Collection Start Date 320/15 Treatment100% 100% Control Control ffR Control Grab (D)ead L pH Init83 82 81 81 80 L Composite (Duration) X L L L L 124% L L pH Final85 86 82 81 80 L Hardness(mg/L) L 500 DOlnil 98 93 85 82 80 81 Spec Cond (umhos cm) 712 215 DO Final 76 79 76 80 Chlorine (mg/L) <0 05 7a7q Temp Init 243 247 245 243 247 24 7 Sample temp at Receipt 06 Temp Final 253 255 252 253 255 1 252 1 2 3 tonic Test Results 9 10 Mean Final Cont Mort % 0% Effluent % Organism # % Cont 3rd Brood 80% 1 2 3 4 5 6 7 8 9 10 11 12 Mean Control Repro CV 26% Control # Younq 31 27 1325 % Red 26 14 18 1 22 1 21 1 21 1 none none 21 8 48 Hour Mortality 00%1 (D)ead L L L (L)ive L L L 00% 1000% 10850 7500 (D)ead L L L L L L L L L L none I none Effluent % Control IWC 21 24 0of10 0of10 1 2 3 4 5 6 7 8 9 10 11 12 Mean Significant? No h Red (L)ive 100 0% (D)ead L L L Effluent % # Youn 27 22 0 22 0 24 25 14 20 15 none none 16 9 Final Mortality Sign @ Environmental Sciences Branch Adult (L)ive 'Should use highest test concentration or Division of Water Quality IL highest concentration with D O >5 0 mg/I %Red TO: N C DENR ° 45 0 /o L L L L L L L L L none none 22 5% % or DWQ form AT -3 (8/91) Rev 11/95 Page 8 of 22 no concl. Re roductlon Anal ses 1 2 3 4 5 6 7 8 9 10 Mean Repro LOEC=>100 00°/ Effluent % 60 0% p o NOEL= 1000% Method Steel's Test Normal Dist? no Method Kolmogorov Statistic 1141 Critical 1035 Equal Var? yes Method Bartletts 1 2 3 4 5 6 7 8 # Youn 29 18 18 20 16 19 23 20 21 7 191 Adult /Red (L)rve Method Steel's Test (L)Ive (D)ead L L L L L L L L L L 124% p o NOEL= 1000% Method Steel's Test Normal Dist? no Method Kolmogorov Statistic 1141 Critical 1035 Equal Var? yes Method Bartletts 1 2 3 4 5 6 7 8 9AM�anStatistic 1406 Critical 1510 Effluent % # Youn 25 20 0 22 16 22 25 24 22Non-Parametric Anal sis If a licableAdult Method Steel's Test (L)Ive 5 0% D ead L L L L L L L L L Effuent % Rank Sum Critical 450% 9350 7500 1 2 3 4 5 6 7 8 9 10 Mean 600% 9000 7500 Effluent % #Youn 24 21 19 23 281 22 26 17 211 17 21 8 750% 9800 7500 Adult % Red 900% 10400 7500 (L)Ive I IL 00%1 (D)ead L L L L L L L L L 00% 1000% 10850 7500 verall Analysis IC25= >100% 1 2 3 4 5 6 7 8 9 10 Mean Result = PASS/FAIL or Effluent % #Youn 25 21 24 23 25 21 27 21 24 15 22 6 est LOEC >100 00% NOEL= 1000% Adult h Red (L)ive 100 0% (D)ead L L L L L L L L L L -37% lChronic Value= >100% MAIL Environmental Sciences Branch 'Should use highest test concentration or Division of Water Quality highest concentration with D O >5 0 mg/I TO: N C DENR t% Reduction from Control Reproduction Mean 1621 Mail Service Center Raleigh, NC 27699-1621 DWQ form AT -3 (8/91) Rev 11/95 Page 8 of 22 Test Day I'Source D 1 2 3 d S a ' 44986 Client]EFFLUENT ITY OF HAVELOC Sample ID M3 4-9 ----�-�_ County M6 4-9 Start & fed Date 15 -Apr -15 Start & fed Time 08 4-3 Started & fed By AM Test Organism Cenodaphnia dubia Neo born date 14 -Apr -15 Neo born time 1700-2150 Test Type NCCD Dilution Water NC H20 4-8-15 Units for Conc 44950 E Test vessels 30 ml Test volume 14950 F449501 ©--�-�-�-® 1 Light 1 IU dk Initial Temp °C 5 Selenastrum F205ml AT 1 ,44950 PA 621 R 02 013 1002 W1f Page 9 of 22 Lauif 44986 Client]EFFLUENT ITY OF HAVELOC Sample ID NPDES#C County onth Start & fed Date 15 -Apr -15 Start & fed Time 1150 Started & fed By AM Test Organism Cenodaphnia dubia Neo born date 14 -Apr -15 Neo born time 1700-2150 Test Type NCCD Dilution Water NC H20 4-8-15 Units for Conc %3rd BROOD Test vessels 30 ml Test volume 15 ml Incubator # 1 Light 1 IU dk Initial Temp °C 5 Selenastrum F205ml AT 1 0 05 ml Test method PA 621 R 02 013 1002 ommen s 44950 CON E,F,I J CON TEMP INITIAL- 243 DAY 2- 247 DAY 5- 24 7 DAY 2, NCH2O 4-15-15 APPENDIX B EDTA Treated Effluent AT -3 form and Bench Sheet Page 10 of 22 Havelock: TIEIEDTA Investigation ETT; April 2015 Facility Laboratory Sampl Collec Comp( Hart Spec C Chi Sample Control Effluent % 45 0% Effluent % 60 0% Effluent % 75 0% Effluent % 90 0% Effluent % 100 0% Effluent Aquatic Toxicity Report Form/Phase II Chronic Ceriodaphnia �-i l T yr mAVtLUUK Eu rA TREATED NPDES # NC 0021253 Pt e# 001 County Craven Performing Test ETT Environmental, Inc Comments 41' Treated w/ 5 mg/L of EDTA )f O R C Signature of Lab Supervisor Test -Tate Time ---[End Date Tlme Info 04/15/15 1150 04/22/15 1213 e Information Sample 1 Sample 2 Control Start Renewal 1 Renewal 2 tartVReRenewal2 tion Start Date 320/15 Treatment 100% 100% 100% CoControl Control Grab pHlnit 81 83 82 78 )site (Duration) X pH Final 8s 8s 86 81 Iness (mg/L) 500 DO Init 86 81 81 85 83 81 )nd (umhoscm) 712 215 DO Final 78 80 73 80 77 Anne (mg/L) <0 05 Temp Inst 00 247 246. 00 00 73 00 temp at Receipt 06 Temp Final 253 255 25 2 25 3 25 s 25 2 ronic Test Results Final Cont Mort % 0% Organism # % Cont 3rd Brood 80% 1 2 3 4 5 6 7 B 9 10 11 12 ..an Control Repro CV 26% # Youn 31 27 13 25 26 14 18 22 21 21 none none 21 8 48 Hour Mortality (LEa Dd L L L L L L L L L L none none Control IWC 0Of10 10of10 1 2 3 4 5 6 7 8 9 10 11 12 Mean Significant? No # Young 23 20 17 23 24 21 ne none 203 Final Mortality Sign @ Adult (L)ive IL %Red L L L L L L L L L none none 6 9/ % or no conc Reproduction Anal ses 1 2 3 4 5 6 7 8 9jMean Repro LOEC=>100 00% NOEL= 1000% #Youn 24 19 22 27 5 23 25 20 15 Method Dunnetts t Test Normal Dist? yes Method Kotm °gorov Adult (L)ive (D)ead L L L L L L L L L Statistic 0 939 Critical 1 035 Equal Var7 yes Method Bartietts 1 2 3 4 5 6 7 8 9Statistic 080 Critical 1510 # You n 28 14 16 25 24 28 29 ?6 16Non-Parametric Anal sis if a IlcableAdultMethod (L)iveD Dunnetts t Test ead L L L L L L L L L Effuent % Calc t Critical 450% 057 228 1 2 3 4 5 6 7 8 9 10 Mean60 0% 076 750% -011 900% 034 228 228 228 # Young 24 22 14 22 11 25 261 241 211 20 209 Adult (L)ive IL IL IL % Red (D)ead L L L L L L L 4 1% 100 o% 1 18 228 Overall Analysis IC25= >100% 1 2 3 4 5 6 7 8 9 10 Mean Result = PASS/FAIL or # Young 27 17 5 13 25 17 23 19 20 2,r1871TestLOEC >100 00% NOEL= 1000% Adult /o Red (L)ive IL JChronic (D)ead L L L L L L L L L 142% Value= >100% Environmental Sciences Branch MAIL Division of Water Quality NC DENR TO: 1621 Mail Service Center Raleigh, NC 27699-1621 *Should use highest test concentration or highest concentration with D O >5 0 mg/I t% Reduction from Control Reproduction Mean Page 11 of 22 DWQ form AT -3 (8/91) Rev 11/95 Test Day rc r n 1 1 Page 12 of 22 a 44986 EDTA Client ITY OF HAVELOC Sample ID FFLUENT NPDES# NC County onth ----©-�- tart &fed Date 5 -Apr -15 Start 8 fed Time D8 4-3 Started & fed By M est Organism erlodaphnia dubia F6 4 14 -Apr -15 Neo born time 1700.2150 est Type CCD "! n Water C H20 4-6-1 Units for .one 4950 E ----©-�- est vessels 0 ml est volume .. r F©----�-�- ncubator# 1 Light 1611/8dk ... r 1144950 ----�-�' - 05 ml AT 1 est method 2f Ba 02a,3 coax Emu Page 12 of 22 a 44986 EDTA Client ITY OF HAVELOC Sample ID FFLUENT NPDES# NC County onth tart &fed Date 5 -Apr -15 Start 8 fed Time 1150 Started & fed By M est Organism erlodaphnia dubia Neo born date 14 -Apr -15 Neo born time 1700.2150 est Type CCD "! n Water C H20 4-6-1 Units for .one /o3rd BROOD est vessels 0 ml est volume 15 mI ncubator# 1 Light 1611/8dk nitlal Temp °C 25 elenastrum 05 ml AT OS ml est method 2f Ba 02a,3 coax 44950 CON E,F,I,J MPLE TREATED WITH EDTA E SPEC PROJ BOOK R DETAILS Y 2, NCH2O 4-15-15 APPENDIX C Chain of Custody Page 13 of 22 Havelock: TIE/EDTA Investigation ETT; April 2015 ET'f V 5, PO Box 1,6414, Greenville, SC 29 6 06-741 4 (804) 877-6942, (B00) 891-2325 Fax,(964) 877 6938 Shipping Address 4 Craftsman Ct, Greer, SC 29650 WWW MT CNYIFCNMENTAL.CCM CILAIIN OF CUSTODY RECORD Pate Client:o // 6 �/'� /C_ / Program Containers Preservntive Parameter Facility: / �j^� W ( . - 1j - < o M hole LmucrcT=x — v `,�a State: J C , tiPb> S r: 1°S �'J ♦ 9 7 J Acute Ch -omit Test Or�nntsms U(Composite only) (Gran or Commslt_) = U — Sign, and Pi in t below the dotted line c � U JW= IDTime COIlLctedby Uv1:n z — U > — =Z 4 < v __SADrIPLE U ^— - y ^ — v = I c Cnemr-e! nalysls �Otner Yv) . r171 � ( I'<%- "' \�1r� � r II ------------- ' o i7C "1; JP rNv --------- I 1 ------------- ------------------------- --- — — — — — — — — — — - Special Instructions Sample Custody Transfer Record +SeCL:e ( Recelpt SamDIC Date Time Relinquished By /Organization, Received B) /Organization kr�-a Temp =C Presen ear 330 i4nn'j [.z,' 1/ PP Awrl-r,"& OYL x111/3 r a zl,4' l r o ap _ COd.IPOSITE S4AfPLING PROCEDURES TEMPER-1TURE jWONITORIArG PROCEDURES HOLD TfWE PRO C-EDUPj'S Composite samples must be collected over a 2A bout pencd Sample tempetatire during collection and transport must be bet%%cel For to%icin rustipa the samole must n _i be wed u, 'fun 36 hours Time Proportional. 1 sample each hour For 24 hours Equal volul 0 0 anc 6 0'C Sampleb -nust not be frozen Use %j ater Ice in sealed bas of samlilc collection (comalez,on of composite samore) or at minimum 1 sample every 4 hours over 24 hours Sample may not be urea a ,er 72 hou—s from sa_-nole collection Plow Proportional As per instructions In tiPDES permit Rogers & Callcott ENVIRONMENTAL Client ETT Environmental Bob Kelley PO Boc 16414 Greenviile, SC 29606-7414 Dear Client pPCCR60 Laboratory Report PI o ject. Wastewater Work Order. 5040627 Received- 04/15/2015 10 00 Rogers and Callcott appreciates the opportunity to be of service to you The attached laboratory services report includes analytical results and chain of custody for samples that were received on April 15, 2015 Rogers and Callcott maintains a formal QA/QC program Unless otherwise noted, all analyses performed under NELAP certification have complied with all the requirements for the TNI standard The analyses met the QAIQC confidence interval for each test method unless otherwise qualified Estimated uncertainty is available upon request Privileged/ Confidential information maybe contained in this report and is intended only for the use of the addressee If you are not the addressee, or the person responsible for delivering to the person addressed you may not copy or deliver this message to anyone else If you receive this message by mistake, please notify Rogers and Callcott immediately We strive to prov tde a zeellent service to our clients Please contact Kara Hrkach, your Protect Manager, at kaia hrkach(a)rogersandeallcott com or (864)-335-4956 if you have any questions about this report Report Approved By Kara Hrkach Project Manager PO Bok 5655 &ccnAle t( 19606 42.6 fanforctit viav "-,,—, vii),- SC ?96U7 nu ib' t3'r I .r, i w -i 1S- umu rogersandcall cott.com 7his report may not be reproduced except infill, irdhout ivntten pernnssion frons Ragers & Callcott, bic Page 16 of 22 Page 1 of 7 . Rogers & Callcott ENVIRONMENTAL Certificate of Analysis Client ETT Environmental Bob Kelley PO Box 16414 Greenville, SC 29606-7414 Sample Number Sample Description 5040627-01 44986 2L~'Q PCCpp��� r, `1Q.01 South Cat ohna Gi eenwile Labor atony Identification 23105 South Cat olnm Columbia Labor atoi y Idenfcation 40572 NoitliCatohnaLabotatotyCeitificatioiiNumben 27 Not th Can ohna Di inking [FaterLab Number 45710 NEL4P Utah Cei trficate Number SC000042014-1 Georgia Di inking A%atet Lab ID 880 Project- Wastewater Work Order: 5040627 Received: 04/15/2015 10 00 Matrix Sampled Wastewater 03/20/15 10 30 T� pe PO Bo. 5655 G eanvil,e SC 2QbC,(, 426 F,; i•„ est V iv G, cc,-.nllc ,C 2Q601 ?(h .3. I , .b Rt,•i ? ? i .,1 #0 roger-sandeallcott.eom 04!_t3Q015 13 36 77ns report mm• not be repioducer4 esceot tri, 49L;1ttlt7ipjfiggen pemtissron ftomRogeis & Callcott, lilt Page 2 of 7 Rogers & Callcott ENVIRONMENTAL ETT Environmental PO Box 16.114 Greenville, SC 29606-7414 Sample Data Sample Number 5040627-01 Sample Description 44986 collected on 03/20/15 10 30 Project Wastewater Work Order 5040627 Reported- 04/23/15 13 36 Parameter Reporting Result Limit Units DF Analysed Method Flag Analyst Batch Total Metals Copper ND 0 005 mg/l, 100 04/21/15 14 32 EPA 200 7 A4LR 135D0574 Zinc 0.051 0 010 mg/L 1 00 04/21/15 14 32 EPA 200 7 1`4LR B5D0574 PO Bo, 5655 G,eennll. U- 291,06 112E Fan`oi _5L W.,. Gie,_i wllc SC ?9607 ipr, 1164 2 i !_',n F364 "i 1,10 roger-sandeallcott eom 04/_r3!_r013 13 36 77us report may not be reproduced evicept in ANge'*8 m fvPgen pemussron G om Rogers & Callcott, Inc Page 3 of 7 Rogers & Callcott ENVIRONMENTAL ETT Environmental Project Wastewater PO Box 16414 Work Order 5040627 Greenville, SC 29606-7414 Repotted 04/23/15 13 36 Sample Preparation Data Parameter Batch Sample ID P Prepared Analyst EPA 200.7 Metal Digestion EPA 200 7 B5D0574 5040627-01 04/16/2015 08 08 MLR a PO Box 5655 Ot^ennlhs 5C 296C6 426 F7 I tOl; sc VVIV Ciecr�dlc SC 29D07 rogersandcalleott,eom 04123!-015 13 36 Tins repo! mm,not be reproduced accpl niPdgErgiglibfiggen permission from Rogers & Callcon, inc Page 4 of 7 Rogers & Callcott ENVIRONMENTAL ETT Environmental Project Wastewater PO Box 16414 Work Order 5040627 Greenville, SC 29606-7414 Reported 04/23/15 13 36 Data Qualifiers and Definitions ND Analyte NO I DETECTED at or above the reporting limit NR Not reported PO go), 56$5 G•eonvdle SC 29666 426 Ft if,� _<_t W-i� G,eci ville SC X1)607 „ 46 � i IS'• t36r1 ?32 �I.10 rogersandcallcott.eom air nIr,i✓•� 04232015 13 36 77rrs report mai not be reproducec( except mP4(gaift btrggen permssron from Rogers & Callcott, brc Page 5 of 7 ETTCTTAIN OF CUSTODY RECORD - ex�ironrrl�ent PO Box 18414, GreenVitle, bC 29806.7414 Parc 1_ p f —L (864) 877-8942 (800) 891-2325 Fax (864 877 6938 Shrpping Address 4 Craftsman Ct, Greer, SC 29850 WWW CTTCNV'Q0NNCNTAL.00N Ciient: 9 -7 -7 -- Facilit): Program Containers Prescnatn'c Nranicters State-. )\PDES 4: Whole Crnacm iovcnt Acute Citron, Tcst Organisms i ICampos to ooh) tC--lb nr Cnmpesac} O J Sign, and Pi nit ocloxx 1250. 2- HCl. = cte coiled line c 'a_ '- SAMPLE ID p,rtTime Couectedu VD °- utermasnmpkemva,unn.re e, = =7,qc < <s= Chemrca Anat/srsBCther ------------- �L/ ! 1930 zh ------------- CD------------1 j N It — :tial Instructions mple Custody Transfei Record Date Time Relinquished By N 111POS1TES4,11PLPJG PROCEDURES TE-11PERATURE d1O)WORING PROCEDURES to nposite samples trust be collected oxer a 24 hour period S unplc temperature durinc collection and trampor, must be between to e Proportional 1 sample each hour for : 4 hours Equal volm 0 0 and G 0 nC Samples must not be frezcn Use xxater ice in sealed bays ot mmimurn I sample ever, <I hours over 24 hours -4 x' Proportional As per Instructions in NPDES nmol WIT 4ecirr Reccip I Samole Orsanleattone a Area Tcmn C Preserved, FI,'OLD TI 111 PROC 5D _ RES -- or in".", testing the sample must first be used tx rhvn 36 hours of sample collection (complei on of cnmpos,'e sample) Sample may not be used after 72 1101175 from samp)e collectton Rogers & Callcott ENVIRONMENTAL Sample Receipt Verification Date i Work Client: Received: - r I Order: L� I I✓ C� 1 CarnerName:Chent FedEx UPS Tracking Number US Mail Courier Field Services Other Receipt Criteria Y e HSP04 � Comments — — - - - ----- s, o A Shipping container/ cooler intact? Damaged I eaktng Other. Custody seals intact9 COC included with samples? COC signed when relinquished and received? Sample bottles intact9 Damaged Leaking Other - Sample ID on COC agree with label on bottle(s)? Date / time on COC agree with label on bottle(s)? Number of bottles on COC agrees with number of bottlesreceived'? Samples received within holding time? Sample volume sufficient for analysisO VOA vials tree of headspace (<6mm bubble)' Samples cooled' Temp at receipt recorded on COC Tcmp measured with 1R thermometer • SN 97050067 Ice Cold Packs Dry lce None Samples requiring pH preservation at proper pH' Note Samples for metals analysts may be prescr�ed upon receipt in the lab Samples dechlonmaled for parameterb requiring chlorine removal at — the time of sample collection? If to -house preservation used — record Lot # HCL HSP04 H,,SO4 - — — - - - ----- NaOH HNO3 Other Comments: Were non-conformance issues noted at sample recei Non -Conformance issue other than noted above. Revned July 2014 Yes or I[No Page 22 of 22 i Completed by --_-_- Page7 of 7 ETe,,,nnnT-b,r.1r P.O, BOX It414. Greeny lie, SC 25606 (664)677-6942 FAX (264)977-6938 4 Craftsman Cant, Greer, SC 29650 Americamysis bahia Survival, Growth and Fecundity Test EPA -821-R-02-014 Method 1007 Client: CITY OF HAVELOCK Facility: Wastewater Plant NPDES #: NCO021253 Test Date: Laboratory ID#: T45892 Test Reviewed and Approved By: A& 414 Robert W Kelley, PhD QA/QC Officer Certification #E87819 Test results presented to tits report conform to all requirements of NELAC, conducted under NELAC Certification Number E87819 Florida Dept. ofHealth Included results pertain only to provided samples Pat=e 1 of 6 13 -Oct -15 Farhad Rostampour Laboratory Director SCDHEC Certification #23104 NCDENR Certification # 022 Effluent Toxil Facility City of Havelock Lab ming Signature of Operator In f X Signature of Laboratory S rvlsor Form - Chronic Mys NPDES # N Pipe# 01 : v nvtronmental Sciences Bran Division of Water Quality NC DENR 1621 Mail Service Center Raleigh, NC 27699-1621 Control Replicates 1 2 3 4 5 6 7 8 Surviving C 5 5 4 3 4 4 4Q00 70 Original# 5 5 4 3 4 5Weight(per 58 41 Original) Fecundity (gmvidltotal females) 0 00097 0 00115 0 00075 0 00057 254 0 00077 0 00121 256 011 12 012 010 1H 0/2 1r1 art Treatment 2 Replicates 1 2 3 4 5 6 7 0 Survlwng # 3 5 5 5 5 Original # 4 5 5 5 5Weight �-0014 (per Original) Fecundity (gravidn.tal females) 000079 12 0 001100 1/3 00114 02 0 00110 113 00010 010 1A 112 0 00113 Oro I Water Quality Data Day Control 0 1 2 3 4 5 pH Initial pH Final DO Initial DO Final Temp Initial Temp Final Salinity initial 85 83 81 82 82 83 6 83 7 694 80 76 79 77 79 79 80 65 70 64 66 67 71 68 58 41 47 43 47 50 53 254 253 255 256 254 255 253 2581 2591 260 260 259 25 7 25 9 2491 251 1 2531 25.2 255 1 25.91 2511 Treatment 0 1 2 3 4 5 6 pH Initial pH Final DO Initial DO Final Temp Initial Temp Final Salinity Initial 87 83 83 83 82 82 83 7 694 81 79 79 78 75 80 81 65 69 61 64 69 71 69 51 49 38 48 49 51 55 256 255 4 254 254 �025 26 0 250 25 25 7 25 9 26 5 251 251 25 1 Sampls 1 2 3 Collection Start Date Grab Composite (Duration) Conductivity (pmhos/cm) Chlorine (mg/i.) Sample Temp at Receipt DWQ Form AT -4 (6199) 10/11/15 10/13/15 10/15115 24 hours 24 hours 24 hours 689 694 722 <0 05 006 <0 05 00 00 28 not frozen not frozen 23 -Oct -15 %Survival Avg Weight (mg) 0 226 Avg Fecundity 35 7% %Survival Avg Weight (mg) 0222 Avg Fecundity 443% Test Results Significant Mortality? Yes No X Check One Growth Col. t 0 159 Tabular 1 gq Fecundity Calc t NA' Tabular 177 control fecundity less than 50% PASS FAIL X Check Ono Effluent Test Concentration 15% 5 replicates were set for each control lest replicate, where <5 are shown the organisms were lost during renewal 5 replicates were set for each treatment test replicate, where <5 are shown the organisms were lost during renewal Page 2 of 6 Paee 2 of 6 V'M LoW'IT InM In M In In Lo In In m N N N N N N N m o C � m E c E m U e d (L LuC o N o U Z 0 0 0 0 0 0 m H L m O a H Y U a E = H W v1 J m w F o> x a y E E in O co N a E❑ in U 2'o O a Z U o Q N r w w T m c= o 'm' E E 0 a n o �• v a ?. .'. w E m E E n 3 V z m E ? 9 p r o J m 41 Z U S[ N N Orl F Z V'M LoW'IT InM In M In In Lo In In m N N N N N N N m o C � m E c E m U e d (L LuC o N o U Z 0 0 0 0 0 0 11111111111111 111111 111111111 I oil 11 1111111 ollsommis loss possomis 0o00o00o iMINE ii iiiiiiBRIOU ii loommom 1111111 111111 eee�eeee�eee�eeeeseee�eeeeeeeeeeee eeeeeeell�ll� �eeeeeeee ETI- M-�� PO Box 16414, Greenville, SC 29606-7414 (884) 877-6942, (800) 891-2325 Fa:c(854) 877 6938 Shipping Address 4 Craftsman Ct, Greer, SC 29650 W W W.riTTEN VIRONMENTAL.CCM CHAIN Or- CUSTODY RECORD Pace —j of-_ Client: ✓e OG Program Containers Presen•ative Parameters Facility y WeLllf Gia fe c - / rectf�e� f FQ � Whole L•filucntToxiciry Q State: a NPDES R: e "?&a acute Chronic I Test Organisms M o U(Composite only (Grab or Composite) < — 5 o L) _. Z U Sign, and Print below r > y o _ - cA 0 = 0 IgFL504 2=HCL A z � v r^_ lite dotted line .O s'13-1-11,103- —' �_ _f - SAMPLE ID V Composite Start Date Thne Sample Collection Dale Time Collected by U cry r�J rn O Z , C a ' C7 O > rj J=ZI.AC 6- other J < < U U CJ Q L rn =10 _ 3 L Chemical Analysis 8 Outer ^ y�G+ae:� I>GerYlc�eZ HA �} 1 . �a. d rr� � 'Iq 9.7 ------------- -------------------------Special ------------- ------------- ------------- SpecialInstructions: Sample Custody Transfer Record Secure Receipt I Sample Date Time Relinquished By/ Organization Received By / Organization Area Term) 'C Preser% ed? 0: o. 1-f-00 / iGIle- loe-d" S I I co -1 5 6,831, UPs Fn" I I o I I I COMPOSITE SAMPLIArG PROCEDURES I TEMPERATURE A10NITORING PROCEDURES HOLD TME PP,OCEDURES Composite samples must be collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing dhe sample must first be used within 36 hours Time Proportional. I sample each hour for 24 hours Equal volui 0.0 and 6 0 'C Samples most not be frozen Use water ice in sealed bas of sample collection (completion of composite sample). or at minimum I sample every 4 hours over 24 hours Sample may not be used after 72 hours from sample collection ET jL I h•�'+ax,�5t�r:�'=i'-"i-4'+J-17�JJ�_4��-C�ll�l'1h�'Li� PO Bax 16414, Greenville, SC 29606-7414 (864) B77-6942, (800) 691-2325 Fatc(864) 877 6938 Shipping Address- 4 Craftsman Ct, Greer, SC 29550 W W W.CTTEN V IRO NMENTAL COM CHAIN Vre CUSTODY RECORD CORD Pa --e —I— of c:ttent: - Program Containers Preservative Parameters Facility: �� �� �' n w a Whole [fttnentToriciq State NPDES R: D Acute Chronic Test Organisms rn i " a(Composite only (Grab or Composite) u = c _ o U 0 Sign, and Print below the dotted line j ' __ _ -0 U ' 1= HCL 3 Hno; = S------ Composite Start Date Time Sample Collection Date Timer2 _ rn Z � C y v > — 5-Zro1c 53 < o�,?T= UUChemicalAnal}51580 _SAMPLEID 6=Odor ler 10-15115 WDoi�t�la ------------ IIIc ------------- II I ------------- II Ilii V II IIII Special Instructions Sample Custody Transfer Record Secure Receipt I Sample Date Time Relin uislied By/ Organization Received By / Organization Area Temp eC Preserved9 d t0 -IS g3DtAfI5 LTi D COMPOSITE SAAIPLING PROCEDURES TEMPERATURE AdONITORIArG PROCEDURES HOLD TI.41E PP.00EDURES Composite samples must be collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing the sample must firsi be used iilthin 36 hours Time Proporhonal• 1 sample each hour for 24 hours. Equal voluu 0 0 and 6.0 eC Samples must not be frozen. Use nater ice in sealed bas. of sample collection (completion of composite sample) or at minimum 1 sample every 4 hours over 24 !tours Sample may not be used after 72 hours from sample collection. Flow Proportional- As per instructions In NPDES permit ET".t" PO Box 16414, Greenville, SC 29606-7414 (864) 877-6942, (800) 891-2325 Fax(864) 877 6938 Shipping Address 4 Craftsman Ct, Greer, SC 29650 W W W.6TTENV 1 RONM ENTAL.COM CHAIN OF CUSTODY RECORD Pa --e e Client: '/ G Program Containers Preservative Parameters Facility: We fete ,B t ��� f 3 U y _ ;_ cn L � z y o U o a U _ > — 1-1-1204 z=HCL '-HN,03 4=idaoH 5= ZTLA e=0d,cr lithof°CmucntTaxieicp Q = > Chemical Analysis E Other r•, t c Z s _ State C NPDTS Acute Chronic 7°st Organisms SAMPLE ID u U v (Composite only) Composft° swrt Date Time (Grab or Composite) Sample Cali �,ao Date Time Sian, and Print below the dotted line Collected by a < U — U J r — U _ U ;o t] 'o _ = _ _ U •., {�ivc.�r�- 1 • l , t 10. • 15tVA711,1 A��v G ' ------------- --------------------------------------Special ------------- -------------- ------------- SpecialInstructions: Sample Custody Transfer Record Date Time Relinquished B / Organization Received By / Oreamzation Secure Area Receipt TemD °C Sample Presened') I 2 I COMPOSITE SAMPLING PROCEDURES TEMPER-ITURE HOAUTORIArG PROCEDURES HOLD TME PROCEDURES Composite samples must be collected over a 24 hour period. Sample temperature during collection and transport must be betmcen For toxicit-, testing the sample must first be used vnthin 36 hour Time Proportional: i sample each hour for 24 hours. Equal volui 0.0 and 6 0 °C Samples must not be frozen. Use water ice in sealed bas of sample collection (completion of composite sample) or at minimum I sample even 4 hours over 24 hours Sample may not be used after 72 hours from sample collection_ Flow Pro ottiona er instructions in NPDES permit ET--,,-n-Tent-,,c P O. Box 1 E-414 Greenv Ile, SG Z3606 (664) B77-6942 FAX (864) 6.77-6938 4 Craftsman Court, Greta, SC 29650 Americamysis bahia Survival, Growth and Fecundity Test EPA -821-R-02-014 Method 1007 Client: CITY OF HAVELOCK Facility: Wastewater Plant NPDES # NCO021253 Test Date: Laboratory ID#: T46334 Test Reviewed and Approved By: wok 4/4 Robert W Kelley, Ph D QA/QC Officer 16'309'`!"`'M Certification #E87819 Test results presented to this report conform to all requirements of NELAC, conducted under NELAC Certification Number E87819 Florida Dept of Health Included results pertain only to provided samples Page 1 of 6 12 -Jan -16 Farhad Rostampour Laboratory Director SCDHEC Certification #23104 NCDENR Certiftcahon # 022 Effluent Toxici Facility City of Havelock X -A - Xlgnatu�e of Operator io,Rf1 � p Signature of Laboratory SuDerviso Form -Chronic Mysidopsis Pass/Fail �y NPDES # NCO021253 Pi e# yQOtinental Inc Comments Date 21 -Jan -16 County Craven : Environmental Sciences Branch Division of Water Quality NC DENR 1621 Mail Service Center Raleigh, NC 27699-1621 Control Replicates 1 2 3 4 5 6 7 8 Surviving # 4 4 5 5 5 5 4 4 Onginal # 5 4 5 5 5 5 5 4 Weight (per Original) 000097 000115 1 000075 000057 000104 000077 000121 000115 Fecundity (gravid/total females 1/2 0/0 1/3 0/1 1/3 0/1 0/0 0/1 Treatment 2 Replicates 1 2 3 4 5 6 7 8 Surviving # 4 4 4 4 4 5 5 3 Onginal # 5 5 5 5 4 5 5 5 Weight (per Original) 000111 000089 000083 000075 000090 0.00093 000128 000073 Fecundity (gravid/total females 0/1 1/1 0/0 1/3 012 0/4 0/2 0/1 Water Quality Data Day Control 0 1 2 3 4 5 6 7 pH Initial pH Final DO Initial DO Final Temp Initial Temp Final Salinity Initial 84 83 83 82 83 83 82 24 hours 24 hours 79 80 78 79 80 80 83 70 61 71 62 66 65 64 52 61 50 50 50 54 57 254 256 252. 253. 250. 254. 25 6 [E 2E24 257 261 1 2581 2,571 2581 261 259 25 3 257 2551 2491 2501 24 6 25 3 Treatment 0 1 2 3 4 5 6 7 pH Initial pH Final DO Initial DO Final Temp Initial Temp Final Salinity initial 84 83 83 82 83 83 82 24 hours 24 hours 80 81 78 80 82 80 83 72 67 71 62 66 63 65 51 54 47 44 50 47 54 253 256 253, 250 252 256 [E 2E24 261 2581 2571 258 261 259 246 2,921 2671 263 257 Sample 1 2 3 Collection Start Date Grab Composite (Duration) Conductivity (pmhos/cm) Chlorine (mg/L) Sample Temp at Receipt 1-10-16 1-12-16 1-14-16 24 hours 24 hours 24 hours 781 766 795 <0 05 1 <0 05 <0 05 1 1 00 24 partially frozen %Survival Avg Weight (mg) 0 205 Avg Fecundity 27 3% %Survival 84 6 Avg Weight (mg) 0 191 Avg Fecundity 14 3% Test Results Significant Mortality? Yes No X Check One Growth Calc t 051 Tabular 1 1 94 Fecundity Rank Sum Crit Value PASS FAIL X Check One Test Date 01/12/16 Effluent TestConrznfration 15% 'Control fecundity <50%, not used as endpoint 5 replicates were set for each control test replicate, where <5 are shown the organisms were lost during renewal 5 replicates were set for each treatment test replicate, where <5 are shown the organisms were lost during renewal Page 2 of 6 W 0 W 00 '0 DDDDDD M T-r,w N-•D�3 _ M. a O 'u O Q O m m N N N N N N CA CA N Cr CA C11 (A CA.[a CAw NCAA i- saloons1111 m C; a m 3 > O O O cn 0 cu 0a 3= p N z C) m= T D a C 3 3 z O D o < c m O a T D{ O b O = 3 Z -I x D in z rn � m i����������n��ee�eeeeeseeeeeeee� � .. NiiNE� ��n����e�e-eeeeee�eeeee� _e1eeeeeeeeeeeee 11111111 11111111111111111111 ���A���1 �����A�A� I�III III III III .IIII�IIIIIIIIIIII =III' �llllll 1: 1111111111 1 INS-sssss -1111111 ssss�sl� a �sissssssss'��snsssn�sssss�sn�"�"sss's'sssss�� 00 '0 DDDDDD M T-r,w N-•D�3 _ M. a O 'u O Q O m m N N N N N N CA CA N Cr CA C11 (A CA.[a CAw NCAA i- m C; a m 3 > O O O cn 0 cu 0a 3= p N z C) m= T D a C 3 3 z O D o < c m O a T D{ O b O = 3 Z -I x D in z rn � m ET'jL' PO Box 16414, Greenville, SC 29606-7414 (864) 877-6942, (800) 891-2325 Fax:(864) 877 6938 Shipping Address* 4 Craftsman Ct, Greer, SC 29650 WWW.CTTENVIRDNMENTAL COM CHAIN uF CUSTODY RECORD Pace _L 0, Client: �C k Program Containers Preservative Parameters Facility: /. le L �l/ 7 l re- 76i.,eYJTe,,/-Whole 7 c Un v _ �Tme c o - M-0^ Z J E2 �;' U `—' c> ti = 1-H2SO4 2-14CL 3-1-NO3 6 p c MountTocieit3 c n ' L c ChemOther ' Z _ / State: C NPD );S r": 1 00,242-5-3 Acute Chronic Test Organisms ID U U (Composite only) Composite Start Date Time (Grab or Composite) Sample Collection Date Sign, and Print below the dotted line Collected by = -.52 < < U v o a _ Ln _ U Tom= al M14cO//ein—A I ,fit T, A :, e o F ------------ --------------------------------------------- ----------- ------------- ------------- Special Special Instructions: Sample Custody Transfer Record Time me Relin uished By/ Organization Received By / Organization Securz Area I Recenpt Tzmo'C Sample Preser ed7 geNs a--. T� � oc ., 4 I -o2-16 093J 1. Z 611 COMPOSITE SAMPLING PROCEDURES TEA?PERdTURE MONITORING PROCEDURES HOLD TIME PROCEDURES Composite samples must be collected over a 24 (tour perSample temperature during collection and transport must be between For toxicnt) testing the sample must first be used v iihin 36 hours Time Proportional I sample each hour for 24 hours Equal volun 0.0 and 6 0 °C Samples must not be frozen Use water ice in sealed bas of sample collection (completion of composite sample) or at minimum 1 sample every 4 (tours over 24 (tours. Sample may not be used after 72 hours from sample collection .Elm"IL' jj:::::::::111 ;; 71 1T2 1 't � PO Boxn10414, Greenville, SC 29506-7414 (864) 877-6942, (800) 891-2325 Faic(864) 877 6938 Shipping Address 4 Craftsman Ct, Greer, SC 29650 W W W.ETTENVIAl7NMENTAL.00M CHAIN k,-, CUSTODY RECORD Page —1— of k.tient: C % Facility: 1 l�' G = G U Program v o cit cq = •- z �in Containers GL = (j c j Preservative u 1-H2S0J �- HCL 1=\SOH s=ZnAc 6= Odicr Parameters Whole Cmuent Toxicity ,� 2 21s o 2 Chemical Analvsis ✓i Other '- Ci n < _ State: NPDES R: Acute Chronic Test Organisms SAMPLE ID = a U s U O (Composite only) Composite Stain Date Time (Crab or Composite) sample Collection Date TimeCorrected Sion' and Print below Ute dotted line by _ m v '+ U -a v < `y—^ U - U ca a = ? I L�- L > ✓i oH = m U ` _ 1I2 II ------------- -------------------------Special ------------- SpecialInstructions - Sample Custody Transfer Record Date TlmeRelin uished 1300reanization Received Bvl Organization Secure Area Receipt TemD 'C Sample Preserved? t t'D Y t- iy-1 D 11 bGp >✓-rr Pa Hi 0j COMPOSITE SAMPLING PROCEDURES TEMPER<1TURE A10MITORING PROCEDURES HOLD TIME PROCEDURE'S Composite samples must be collected over a 24 hour period Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 hours Time Proportional. 1 sample each ]tour for 24 hours Equal volui 0 0 and 6 0 'C Samples must not be frozen Use water ice in sealed bas of sample collection (completion of composite sample) or at minimum 1 sample every 4 (tours over 24 hours. Sample may not be used after i2 (tours from sample collection Plow Proportional As per instructions in NPDES Demtit CILMN U- F CUSTODY RECORD PO Box 16414, Greenville, SC 29606-7414 (864) 877-6942, (800) 891-2325 Fax -(864) 877 6938 Shipping Address- 4 CraRsman Ct, Greer, SC 29550 W WW.I=rMN V IRONMWi,MA4Co M Pave of l:ltent: A!/ Facility:( 1��600 / q fef s.�er7f ��-�t 3 c_ U Program rq B cn o a o z o U o � Containers s ^_ y iJ E o > Presen-amble — I= HCL --tn.o� 4=Na014 6- Od,Q Parameters iq Whole timuentToOrg N o Chemical Analysis a Other � i J State C NPD)rs #: c �a�as3 Acutc Chhronic Test Organisms SAMPLE ID U(Composite U only) Camposrtc $tart Datc Time (Grab or Composite)< Sampic Collmmn Dntc Time Sten, and Print below rite dotted line Collected by ^ ¢ ¢ y U = U _ U U y' n ` fF%est /� /� //Q0. /( �- - -- r --- j ✓ S t�-�G `�ie33 �E C 1 - - - - - - - - - - - - - l ------------- ------------- Special Instructions. Sample Custody Transfer Record Date Time Relinquished B / Omanization Received By / Organization Secure :area Receipt TemiD 'C Sample Presermd? 1, 4 Ft>uQ G3 vet b (7�,, 11L rC, C1��1 _;r i y . CUA4PUS7iC SAMPLING PROCEDURES TEMPERATURE MONITORING PROCEDURES Composite samples must be collected over a 24 hour period. during temperature dung collection and transport must be between Time Proportional: I sample each hour for 24 hottrs Equal volut 0.0 and 6 0 'C. Samples must not be frozen rise.water tee in sealed bas or at minimum I sample every 4 hours over 24 hours ,er HOLD 713 PROCEDURES For toxicity testing the sample must first be used writhin 36 hours of sample collection (completion of composite sample) Sample may not be used after 72 hours from sample collection emlmrlm�li , Inc P 0, Sfax I E414, GreeflV Ile, SC 29606 (964) 677.6942 FAX (864) 879.6939 4 Craftman Court, Grier, SC 29550 Americamysis lbahia Survival, Growth and Fecundity Test EPA -821-R-02-014 Method 1007 Client: CI'T'Y OF HAVELOCK Facility: Wastewater Treatment Plant NPDES # NCO021253 Test Date: Laboratory ID#: T46884 Test Reviewed and Approved By. Robert W Kelley, PhD QA/QC Officer Certification #E87819 Test results presented to this report conform to all requirements of NELAC, conducted under NELAC Certification Number E87819 Florida Dept of Health Included results pertain only to provided samples Page 1 of 6 19 -Apr -16 Farhad Rostampour Laboratory Director SCDHEC Certification #23104 NCDENR Certification # 022 Effluent Toxicity Report Form - Chronic R Facility City of Havelock WWTP NPDES # X /fid y G��e r— Slgnature of Opera X Signature of Laboratory S s Pass/Fail Date 29 -Aar -16 County Craven MAIL ORIGINAL TO: Environmental Sciences Branch Division of Water Quality NC DENR 1621 Mail Service Center Raleigh, NC 27699-1621 Control Replicates 1 2 3 4 5 6 7 8 Surviving # 5 5 4 4 5 4 4 5 Original # 5 5 4 5 5 4 5 5 Weight (per Original) 000156 000179 000135 000149 0 00202 0 00151 000172 000183 Fecundity (gravid/total females 1/1 0/2 0/1 2/2 1/2 1/3 0/0 2/2 Treatment 2 Replicates 1 2 3 4 5 6 7 8 Surviving # 5 5 4 5 5 5 5 5 Original # 5 5 --T j 5 5 5 5 5 5 Weight (per Original) 0 00219 CO215 0 00181 000225 000228 000182 000162 000205 Fecundity (gravid/total females; 3/3 1/2 1/1 1/1 1/1 0/0 1/3 2/2 Water Quality Data Day Control 0 1 2 3 4 5 6 7 pH Initial pH Final DO Initial DO Final Temp Initial Temp Final Salinity Inifial 81 80 83 80 81 80 83 x x 78 77 76 76 77 78 77 75 67 64 66 74 73 67 57 45 53 50 52 50 54 252 253, 254, 251 1 253. 253, 253 2581 2601 2-5-7 25 6 260 260, 260 24 5 247 2491 2491 251 1 2501 2461 Treatment 0 1 2 3 4 5 6 7 pH Initial pH Final DO Initial DO Final Temp Initial Temp Final Salinity initial Sample Collection Start Dale Grab Composite (Duration) Conductivity (pmhos/cm) Chlorine (mg/L) Sample Temp at Receipt DWO Form ATA (6/99) 82 80 83 80 81 82 83 x x 79 79 79 79 76 79 79 74 66 64 67 75 71 65 54 41 55 49 53 40 47 250 253, 255. 252. 253 254 256. 25 B 26 0 25 7 25 8 26 0 26 0 26 0 24 4 2451 2501 2501 2461 2481 247 17 -Apr -16 19 -Apr -16 21 -Apr -16 x x x 738 758 777 006 <0 05 <0 05 01 02 09 %Survival 94 7 Avg Weight (mg) 1 66 Avg Fecundity 53 8% %Surnval Avg Weight (mg) 2 02 Avg Fecundity 76 9% Test Results Significant Mortality? Yes No X Check One Growth Calc t -2601 Tabular 1 1 94 Fecundity Rank Sum Cnt Value PASS FAIL X Check One Test Date 02/09/16 Effluent Test Concentration 3% 5 replicates were set for each control lest replicate, where <5 are shown the organisms were lost during renewal 5 replicates were set for each treatment test replicate, where <5 are shown the organisms were lost during renewal Page 2 of 6 III IIS 1i-11ITI I� � iIi fli Hill L� i' Ll hili ET"x" a 2 PO Box 16414, Greenville, SC 29506-7414 (864) 877-6942, (800) 891-2325 Fax(864) 877 6938 Shipping Address- 4 Craftsman Ct, Greer, SC 29650 WW W.=EN V n70NMENTAL.COM CHAIN u- F CUSTODY RECORD Page —4-- of 4— Client: Program Containers Preservative Parameters Facility: / I� l �� ler � L/111, e 17 WholeEmucntToxicity n State: NPDES 2 Acute Chronic I Test Organisms U (Composite only) (Grab or Composite) Z5 < o 12 U o — Stan, and Print below .UJ 3 - •3-HNO3 x o I=H?SO4 2mHCt = = _ = N' < die dotted line __ ^c U N y a=NaoH SAMPLE ID 6— Composite Start Date Time Sample Collection Date Time Collected by U J5 V'3Z —_ c- c7 > — a= other < < v U U ❑ t= Z I r;5 =101"P:*121 Chemical Analysis 8 Other 1 11, a' OfI I I I I Iq o q $3 'q A ------------- ------------- ------------- ------------- Special Instructions Sample Custody Transfer Record Secure Receipt I I Sample o Date Time Relinquished By/ Organization Received By / Or_amzation Area Temp eC Preserved /�16 /00-5 - IzIalr� I I I I COMPOSITE SAMPLING PROCEDURES TEt1,fPER_,1TURE IWOMTORING PROCEDURES FOLD TIME PROCEDURES Composite samples must be collected over a 24 hour period Sample temperature during collection and transport must be bemeen For toxicity testing die sample must first be used iNithin 36 hours Time Proportional 1 sample each hour for 24 hours Equal volui 0.0 and 6 0 °C Samples must not be frozen Use hater ice In sealed bas of sample collection (completion of composite sample) or at minimum 1 sample every 4 hours over 24 hours Sample may not be used after 72 hours from sample collection Flow Proportiom ler instructions in NPDES permit. M; ` PO Box 16414, Greenville, SC 29606-7414 (B64) 877-6942, (800) 891-2325 Fa:c(864) 877 6938 Shipping Address. 4 Craftsman Ct, Greer, SC 29650 W W W.CTTENV1GCNMENTAL.00M CHAIN VF CUSTODY RECORD Page of 7E7-1 Client: Program Containers Preservative Parameters Facility:e� -77e me,-'1 11'holaCmucatToxicity State: 1\`PDl $ ri'r: Acura Chronic Test Organisms ts — 0 ^ (Composite only) (Grab or Composite) < �_ _ = i o — z U Sign, and Print below Ej > aES ca oo a- HCL _ N 21 V tOCompositesmn the dotted line E o 3-HNO3 4-NaOH U uU _— ID Date Time Collection Dale Time Collected by , > i= Z:�c ¢Smple ^ jo _ CSAMPLE hemical Analysis & Other — a/e��o,7 la8l�'g - ------------- c -foil r---------- 0 D----------- ------------- Special Instructions Sample Custody Transfer Record Secure I.Axea I Receipt ( Sample Date Time Relinquished B1 y / Organization Received By / Organization Temp 'C Preserved9 CTT" I I I I COAfPOSITE SAMPLING PROCEDURES TEMPERATURE iWONITORING PROCEDURES HOLD TIME PROCEDURES Composite samples must be collected over a 24 hour period Sample temperature during collection and transport must be between For toxicity testing die sample must fist be used «ithtn 36 hours Time Proportional 1 sample each hour for 24 hours Equal volui 0.0 and 6 0 eC Samples must not be frozen Use water ice in sealed bas of sample collection (completion of composite sample) or at minimum I sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection Flow proportional- As per instructions in NPDES permit ET r o MINOR PO Box 16414, Greemnlle, SC 29605-7414 (864) 877-6942, (800) 891-2325 Far(864) 877 6938 Shipping Address- 4 Craftsman Ct, Greer, SC 29650 WWW-(C7TENVtRONMEN AL.COM CHCA.E�I U- f CUSTODY RECORD Page _Zof—j Client: Program Containers Presemntire Parameters Facility: // 1 1,� Te (It 16P-1 7f �mC>� �iil Whole LmucntTaxicth State: C NPDES m: Q" �2 Acute Chronic Test Organis ns o U (Composite only) (Grab or Composite) c U H y _o — Z r Sign, and Pont below _ = ca = 2 -HCL L > s the dotted line ❑ _ o ti = aOH — SAMPLE ID tj Composite Start Date Time Sample Collecooa Date Time Collected by U o rn ✓] o Z a CL U o — SsZaAe 6=Oilier ii ^ U U U p = [- 2 vi 5, — s U U — > Chemical Analysts o Other — cif CG//�c�t��l ------------- ---- ------------- ------------- -------------t ------------- ------------- I Li II Special Instructions Sample Custody Transfer Record Secure Receipt Sample Date Time Reh ished By I Oraamzatton Received By I Organization Area Temp eC Presen ed9 ra- -v r g0—bq' It 2 . Ogg) P5 617- I o. CO>VIPOSITE SAMPLING PROCEDURES TEAl, PERaTURE il<IONITORING PROCEDURES HOLD TIME PROCEDURES Composite samples must be collected over a 24 hour period Sample temperature during collection and transport must be bemcen For toaiciq testing die sample must first be used ivithin 36 hour Time Proportional. I sample each Hour for 24 hours Equal volui 0 0 and 6 0 eC Samples must not be frozen Use water ice in sealed bas of sample collection (completion of composite sample). or at minimum 1 sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection ETen,,-,etital, IRC P.O. Box 10414, Greenville. SC 29605 (964) B77-6042 FAX (264) 877-6938 4 Craftsman Court, Greer, 5C 29650 Americamysis bahia Survival, Growth and Fecundity Test EPA -821-R-02-014 Method 1007 Client: CITY OF HAVELOCK Facility: Wastewater Treatment Plant NPDES # NCO021253 Test Date: Laboratory ID#: T47373 Test Reviewed and Approved By. Robert W Kelley, PhD QA/QC Officer •rr==►" Certification #E87819 Test results presented in this report conform to all requirements of NELAC, conducted under NELAC Certification Number E87819 Florida Dept of Health Included results pertain only to provided samples Page 1 of 6 19 -Jul -16 Farhad Rostampour Laboratory Director SCDHEC Certification 423104 NCDENR Certification # 022 trnuent ( oxicity Report Form - Chronic M sido sis Pass/Fail Date 28 -Jul -16 Facility City of Havelock WWTP NPDES # PI e# County Craven Laborato 31,Comments x d f� le Signature of Operator in Re pons) Cbe x ,-, Signature of Laboratory Supervisor MAIL ORIGINAL TO: Environmental Sciences Rrarlch Division of Water Quality NC DENR 1621 Mail Service Center Raleigh, NC 27699-1621 Control Replicates 1 2 3 4 5 6 7 8 Surviving # 5 4 3 5 5 3 5 3 %Survival 97 1 Original # 5 4 3 5 5 3 5 4 52 Weight (per Original) —0342 0 473 1 0 393 0 442 0 398 0 373 0 222 0 148 Avg Weight (mg) 0 349 Avg Fecundity 75 0% Fecundity (gravid/total females 12 22 1/1 2/2 1/2 1/1 12 1/2 Treatment 2 Replicates 1 2 3 4 5 6 7 8 Surviving # 4 4 3 4 4 5 3 1 %Survival Original # 4 5 4 5 5 5 4 2 52 Weight (per Original) 0 255 0 272 1 0 238 0 370 0 334 OA48 0 318 0 230 Avg Weight (mg) 0 308 Avg Fecundity 90 6% Fecundity (gravid/total females 1/1 1/1 2/3 1/1 2/3 22 0/0 1/1 Water Quality Data Day Control 0 1 2 3 4 5 6 7 pH Initial pH Final DO Initial DO Final Temp Initial Temp Final Salinity Inibal Treatment pH Initial pH Final DO Initial DO Final Temp Initial Temp Final Salinity Initial 80 81 8Z 82 82 83 a3 x x 79 83 78 81 79 79 82 74 68 66 65 66 73 77 53 54 47 52 51 57 55 254 256 253 257 254 255 257 2611 25 9 1 25 9 2601 261 1 2591 25 9 2551 2571 2601 2651 2641 2661 2701 0 1 2 3 4 5 6 7 80 82 82 82 82 82 83 x x 80 79 79 80 81 81 82 75 67 67 67 66 73 77 56 44 47 52 52 57 62 250 257 253 257 264 265 255 261 2691 2591 2601 261 1 59 259j- 259 2571 2,561 2631 2631 2461 255 211 Sample 1 2 3 Collection Start Date Grab Composite (Duration) Conductivity (pmhos/cm) Chlorine (mgti-) Sample Temp at Receipt DWO Form ATA (6/99) 17 -Jul -16 19 -Jul -16 21 -Jul -16 x x x 723 733 660 4005 <0 05 <0 05 02 1 02 03 Test Results Significant Mortality? Yes No x Check One Growth Calc t 0 86 Tabulart 194 Fecundity Rank Sum 66 Cnt Value 51 PASS FAIL x Check One Test Date 07/19/16 Effluent Test Corcentration 15% 5 replicates were set for each control lest replicate, where <5 are shown the organisms were lost during renewal 5 replicates were set for each treatment test replicate, where <5 are shown the organisms were lost during renewal Page 2 of 6 I Mffl I 11TH V I llllll I 1 H i T -T I I I I I ill i E r. T �t PO Box 16414, Greenville, SC 29606-7414 (864) 877-6942, (800) 691-2325 Fax(864) 877 6938 Shipping Address 4 Craftsman Ct, Greer, SC 29550 -W -I rC—IRCNMCN Al CO. CHAIN OF CUSTODY RECORD Page of Client: OCit Program Contnmers Presen-etive Parameters Facility: ^CC'Z' � rvnele cmaent Toxictq � — i State: IYPDLS m: �0 �� Acute Chronic Tett Orgnnisms U (Composite only) (G2b or Composite) < p v c Lj i o M. i? Sian, and Print below a 3 y - _ o ?m HCL = z file dotted Iine = E c U o H E -Hi.oa -- —_ r _ ce SAMPLE ID ComPM'testan Date Time sampleCa1l.O=Date Time Collected bi U ti rn Z - U > — 6.Od- 4 4 U J U z n — U c 2 Chemical Analysis & Other 6/7373,1 ------------- ------------- LiLl Special Instructions: Sample Custody Transfer Record Secure I Receipt I Sample Date Time lin uished By/ Or;amzation Received BY / Organization .Area Temp eC Presen ed' l 03 3 S D. COMPOSITE SAMPLING PROCEDURES TEMPERATURE 411ONITORIA'G PROCEDURES HOLD TWE PROCEDURES Composite samples must be collected over a 24 hour period_ Sample temperature during collection and transport must be bemcen For to-,icity testing the sample must first be used c%ithin 36 hour. Time Proportional 1 sample each hour for 24 hours Equal volu 0 0 and 6 0 aC Samples must not be frozen Use hater ice in sealed bas of sample collection (completion of composite sample) or at minimum 1 sample every 4 (tours over 24 Hour Sample ma) not be used after 72 hours from sample collection Flow Proportional. As per instructions in NPDES permit ET c W .1 PO Box 16414, Greenville, SC 29606-7414 (564) 877-6942, (800) 891-2325 Fax:(864) 877 6938 Shipping Address, 4 Craftsman Ct, Greer, SC 29650 WWW CTTCNVIRn NH 6NTAl.COM CHAIN vF CUSTODY IAC®RD Page 7- of Client: Program Containers Preservative Parameters Facility:/,g Whole Muentroxidn 2 � State: 6 NPDES n: Cly©O /0-53 Acute Chronic I Test Organisms p e (Composite only) (Grab or Composite) G o V Sign, and Print below j yCIDo a -HCI - v the dotted line = F U ° y B a- ox ° tj — *,m SAMPLE ID U compositasiart Ome Time Samplc Calleo— Dale Time Collected b1 d U o rn o Z o 13 U o > — 5=ZaAc 6= 0� o < o < U U U L 2 r _ U i L Chemical Analysis 8 Other — •� U e�� 7/9jJ� 1 0 JCS o i ,r`UA ✓ I------------- I ------------ I n------------- ------------- ------------- ------------- Special Instructions Sample Custody Transfer Record (Secure I Receipt I Sample Date Time Relinquished By I Organization Received By I Organization Area Temo'C Preser\ed2 CN a i JL - 010 S Ir (o. COMPOSITE SAMPLING PROCEDURES TEMPERATURE MONITORING PROCEDURES HOLD TIME PROCEDURES Composite samples must be collected over a 24 (tour period Sample temperature during collection and transport must be beth+gen For toxicity testing the sample must first be used within 36 hour. Time Proportional 1 sample each hour for 24 hours Equal volui 0 0 and 6 0 aC Samples must not be frozen Use water ice in sealed bas of sample collection (completion of composite sample) or at minimum I sample every 4 hours over 24 hours Sample may not be used after 72 hours from sample collection Flow Proportional- As per instructions in NIPDES permit CD 0 ETT PO Box 16414, Greenville, SC 29606-7414 (864) 877-6942, (800) 891-2325 Fax:(864) 877 6938 Shipping Address 4 Craftsman Ct, Greer, SC 29650 WWW-CTMNVIRCNMENTA QOM CHAIN OF CUSTODY RECORD Client: �" Program Containers Preservative Parameters Facility: �Jh5 &- 6e r l eoih ���1 Cf,zf Whole Cmaent roximn• n State: /Pr, NPDES Acute Chronic Test Organisms o Ra U(Composite only) (Grab or Composite) U < o 12 L C U - a — n —_ J and Pi int below 9i o I=i -Sod CLSign, _ =n2m r- n ID t? the dotted line g cSAMPLE --HNO3 aaNaoH 5s Znac � Uc ° �N - composite Start Date lime smple Cotlecuon Date Time Collected by U i rn z 6 -other < <u J _ U r 2 Chemical Analysis 8 Other ------------- ------------- ------------- J -------- ---- IL LE I I Special Instructions Sample Custody Transfer Record Secure I Receipt I Sample a Time me_ -Relinquished By 1 Organization Received By 1 Oraanization ?sea Tem 'C Preserved' 1105 1 J Z� f. o i s I 0, 3 COMPOSITE.S14AIPLING PROCEDURES TVIPERATURE MONITORING PROCEDURES HOLD TIME PROCEDURES Composite samples must be collected over a 24 hour period Sample temperature during collection and transport must be between For tomcm testing the sample must firsbe used nithin 36 hour. Time Proportional l sample each hour for 24 )tours Equal volui 0.0 and 6 0'C Samples must not be frozen Use water ice in scaled bags of sample collection (completion of composite sample) or at minimum I sample every 4 hours over 24 hours Sample ma}• not be used after 72 hour from sample collection Flow Proportional As per instructions in NPDES permit. ET,-..,,Tm,b,= P.O. Box 1 E414, Gfeenv ile, SC 29606 (664) 877.6942 FAX (864) 877.8938 4 Craftsman Carrs, Greer, SC 29650 Americamysis bahia Survival, Growth and Fecundity Test EPA -821-R-02-014 Method 1007 Client: CITY OF HAVELOCK Facility: Wastewater Treatment Plant NPDES # NCO021253 Test Date: Laboratory ID#: T47853 Test Reviewed and Approved By 4/4 Robert W Kelley, Ph D QA/QC Officer Certification #E87819 Test results presented in this report conform to all requirements of NELAC, conducted under NELAC Certification Number E87819 Flonda Dept of Health Included results pertain only to provided samples Page 1 of 6 11 -Oct -16 Farhad Rostampour Laboratory Director SCDHEC Certtfrcatron #23104 NCDENR Certification # 022 Ffflunnt Tnvirifir 0---.4 C...... . ca—'. au Date 11 -Oct -16 Facility CITY OF HAVELOCK NPDES # NCO021253 PI e# 001 County— ount Craven Laboratory Pe . Comments X Signature of Operator In Respo>�le,arge Xls — �' " Signature of LaboratorySupervisor MATT nDTL'WA1i grd-1 Division of Water Quality NC DENR 1621 Mail Service Center Raleigh, NC 27699-1621 Control Replicates 1 2 3 4 5 6 7 8 7.7 Surviving # 4 4 5 5 5 5 4 5 %Survival 100 0% Original # 4 4 5 5 5 �; 5 4 5 69 Weight (per Original) 05200 04775 0 3880 04940 0 3980 0 3820 0 5550 04420 Avg Weight (mg) 0 457 Avg Fecundity 865% Fecundity(gravid/total females) 1/2 212 1/1 2/2 3/4 2/3 2/2 3/3 256 Treatment 2 Replicates 1 2 3 4 5 6 7 8 7.7 Surviving# 4 5 5 5 3 5 4 4 %Survival Original # 4 5 5 5 4 5 5 4 69 Weight (per Original) 04325 03740 03500 03580 05350 05520 03320 04725 Avg Weight (mg) 0 426 Avg Fecundity 750% Fecundity (graAdllotal females) 1/ 1 2/2 1/2 1/ 1 2/2 2/2 0/1 1/2 256 Water Quality Data Day Control 0 1 2 3 4 5 6 7 pH Initial pH Final DO Initial DO Final Temp Initial Temp Final Salinity Initiai 83 80 82 82 82 81 83 24 hr 24 hr 7.7 79 79 78 77 78 82 74 66 67 63 65 70 67 54 61 50 53 69 45 60 252 25 3 256 1 254 252 251 1 249 263 260 261 259 26 3 260 263 251 256 247 249 25 6 247 248 Treatment 0 1 2 3 4 5 6 7 pH Initial pH Final DO Initial DO Final Tamp Inlhal Temp Final Salinity Initial Semple Collection Start Date Grab Composite (Duration) Conductivity (pmhos/cm) Chlorine (mg1L) Sample Temp at Receipt DWQ Form AT -4 (6199) 83 81 82 83 82 83 83 24 hr 24 hr 78 79 79 80 82 80 82 75 75 62 61 62 65 62 55 50 46 51 67 49 61 250 1 254 256 1 257 256 1 253 1 257 26 3 260 261 259 26 3 26 0 263 248 1 26 3 255 257 248 249 1 250 09 -Oct -16 11 -Oct -16 13 -OG -16 082 Tabular t 1 76 24 hr 24 hr 24 hr 405 445 445 <0 05 <0 05 <0 05 02 1 02 22 Test Da e Effluent Test Concentration I Test Results I Significant Mortality? Yes No x Check One PLASS FAIL I - Check One 5 replicates were set for each control test replicate, where <5 are shown the organisms were lost during re 5 replicates were set for each treatment test replicate, where <5 are shown the organisms were lost during Page 2 of 6 Growth Calc t 082 Tabular t 1 76 Fecundity Calc t 0 36 Tabular t 1 76 PLASS FAIL I - Check One 5 replicates were set for each control test replicate, where <5 are shown the organisms were lost during re 5 replicates were set for each treatment test replicate, where <5 are shown the organisms were lost during Page 2 of 6 ET"jL' PO Box 16414, Greenville, SC 29505-7414 (864) 877-6942, (800) 891-2325 Fax(864) 677 6938 Slupping Address- 4 Craftsman Ct, Greer, SC 29650 W�-Vit rrMVIg0NMC YAL.COM CHAIN OF CUSTODY RECORD Page --`of 77 Client: C i I Facility: ' ) < v s ^ U Program v �c O rn n = w C O z o -55 = 0 O a Containers O a a U 52 = O > Preservative I -lis 04 2 -HCL 3=ZnAc b. p Parameters Whole Lmocntroxlan• 3 ^ _ o Z Chemical Analysis & Other C� _ State: L NPDLS�: Acute Chronic Test Organisms SAMPLE ID oU U e U (Composite only) CompntlleStnn pato Time (Grab or Compose) Sample Coucct on pme Tima Sign, and Print below file dotted line Collected by =_ c 4 iJ_= 2 ¢ 0 _ U J _ U - = U CI _ t ✓; — 2 _ s — -- p =— U C - dlacoo6.'wio o'yr l a J "� 1/ Iv, I I l�Caiiec `c ------------- ------------- ------------- IT ------------- -1 I L HT Special Instructions -- I . Sample Custody Transfer Record Date Time Relinquished -By /Organization Received By/ Organization Secure Area Receipt Temp'C I Sample Preserved? IN 10-A ga2 Yl u)OT-p D I PS err- O 0 U COMPOSITE SAMPLING PROCEDURES Composite samples must be collected over a 24 hour period Time Proportional I sample each (tour for 24 hours Equal volui or at minimum I sample every 4 hours over 24 hours I'low Proportional As per instructions in NPDES permit TEWERATURE AI0A7TORING PROCEDURES Sample temperature during collection and transport must be between 0 0 and 6 0'C Samples must not be frozen Use water ice in sealed bas HOLD TIDE PR0CED CtRES For toxicity testing the sample must first be used within 36 hours of sample collection (completion of composite sample) Sample may not be used after 72 hour from sample collection PO Box 16414, Greenville. SC 29608-7414 (864) 877-6942, (800) 891-2325 Fa:c(864) 877 6938 Shipping Address 4 Craftsman Ct. Greer, SC 29850 W W W.ETTCN V IGONH CNTAL.COM CHAIN uF CUSTODY RECORD Page Or Client: '"� j ` Program Containers Preservative Parameters Facility: Ips �� j,Z y i !�G a c 1 T \1'huleLmucntrnxicih State: Cw`i NPDL$R: � i3`r� Acute Chronic Test Organisms s c p (Composite only) (Grab orCompos.te) o o _ J U = U y _ Z Sign, and Print below > - ; o 2 -HCI Z- on ? �_ •_, r the dotted line e � U y U = ?-ta 03 y - _ SAMPLE ID U Camposneslart Daic Time Somplc Catimion Dote Time Co eted b U C. ti rn o 1 Z o c V-101 m o > 'j — 3=Zaic 6-od,cr ¢ Q U U U ci *= z n U _ 3 L Chemical Analysis 8: Other ------------- ------------- II II Special Instructions Sample Custody Transfer Record Secure Receipt Sample Date Time Relinquished By/ Organization Received By / Organization Area Tem =C Preseri ed9 •� �� Cl I 10 l3 �a gas I I p '0Z COMPOSITE SAMPLING PROCEDURES TEAfPERATURE 190NlTORIArG PROCEDURES HOLD TIME PROCEDURES Composite samples must be collected over a 24 hour period Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 houu3 Time Proportional l sample each hour for 24 hours Equal volui 0 0 and 6.0 aC Samples must not be frozen Use water ice in sealed bass of sample collection (completion of composite sample) or at minimum I sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection Flow Proportional As per instructions in NPDESpen-nit ET's' PO Box 16414, Greenville, SC 296D6-7414 (884) 877-6942, (800) 891-2325 Fax(864) 877 6938 Shipping Address 4 Craftsman Ct, Greer, SC 29650 WW X-"CNVIRONMiE—AL.CDM CION G -e CUSTODY RECORD Pale �_ of� t hent: , 1�G` AV Program Containers Preservative Parameters WholermucntTocicity Facility: , ep 60 State: NPDES / #: Acute Citronfc TestOrgantsms — � o n n U(Composite only) (Grab or Composite)G o 12 — o G V c = Sign, and Print below ea 3 a on ^ 2- HCL L a 2 `^ •_, = s the dotted hoe 3-HNO3 _" g = ? " ' = < SAMPLE ID V Composte Stan Daca rima Sample Collection Dale Time Collected b3 U en ri4 Z C U j u 4=UGH i= ZnAc u < V= < U U U - ri = 3 -776.OdLr rn U _ Chemical Analysis 8 Other WV7?53C I ------- III I ------------- i -------------IT I i TI ------------- I I I IT -F ---fl-I Special Instructions: Sample Custody Transfer Record Secure [krea Receipt I Sample Date Time Relinquished B / Orgaamzation Received By I Organization Tamp °C Presen•edv V i 1 CD l 4�-- l� .� I d Oj ✓C /Q;� Wk) / 7) `— 16IM-)161 ei3r Ur I I a �- �o r• � sY� av-l. C/ I I l ' COMPOSITE SA,IdPLING PROCEDURES TEMPERATURE ,VOAUTORING PROCEDURES HOLD TIME PROCEDURES Composite samples must be collected over a 24 hour period Sample temperature during collection and transport must be between For toxicity testing die sample must first be used within 36 hours Time Proportional I sample each (tour for 24 hours Equal volui 0 0 and 6 0 eC Samples must not be frozen Use water ice In sealed bans of sample collection (completion of composite sample) or at minimum I sample every 4 hours over 24 hours Sample may not be used after 72 hour from sample collection Flow Proportional As per instructions In NPDES permit ETE-.---T-,-,-c (EGA) B77-6942 PAX (864) 877-6938 P 0. 0vx IE414. Greeny tie. SC 23606 4 Craftsman Calm, Graer, SC 29650 Americamysis bahia Survival, Growth and Fecundity Test EPA -821-R-02-014 Method 1007 Client: CITY OF HAVELOCK Facility: Wastewater Treatment Plant NPDES # NCO021253 Test Date: 10 -Jan -17 Laboratory ID #: T48371 Test Reviewed and Approved By. 4/4 Robert W Kelley, Ph D QA/QC Officer Certification #E87819 Test results presented in taus report conform to all requirements of NELAC, conducted under NELAC Certification Number E87819 Flonda Dcpt of Health Included results pertam only to provided samples Page 1 of 6 Farhad Rostampour Laboratory Director SCDHEC Certification #23104 NCDENR Certification # 022 Effluent Toxicity Report Form - Chronic Mvstdoosts Pass/Fat ate an a ty Have ock NP E# NC 2 peg ty a e La a ry P rf m rag es ment -� — - & -- i, _ _ _ S g at e e t r Resp `n �e Charg x I oo - - - S g re ab t ry p ry .I It9vttIL, 1MN�%I- t,v %rronmcnt c s `tl v ion \1° re, u t IN I rl,VIR t�\ Ca I 's"I v z (n t Ftal tgh \ `) (; Wg Q a F' 9 i � � F l I I s e s I hS 4 O rl m a m m t n m E 0 °c E m U m o z m a f7 z ¢ w m - E C a ¢ c m m � c O m = U 4 m U O EF IL 0 U F- _ E E a R m F- x U 3 z m L) O N o¢¢¢ E K U Z O N (p N N E E m 0 d 9 0 n d o m i> a F E E i E o 1 H 0 H - J U m z U a m m Ul z z O O rl m a m m 0 0 J S c 5 m E 0 °c E m U m o z c E m - E C a ¢ c m m � c O U O O rl SOON 10 '0000000000�o�o-���iin 11iiiii 1iiiiiu�0���� foo 0000000000�o iiiiiiiiiiiiii� �000�oo 0000000iiiiiiiiiiiiiiiiniiiiii �000�oo�00001H�oiiiiii� �00000�oo�000�o MUM 11111111111111111111111! sasses �.ee� e�ee�ee eee�eeee ee�eee eeeeee�Illll� O rl ET r A Y�7 �tygq q 7HW114. ��.'�t 6 ° '�.4��+�i.L�lREENVILLE, 9C 29fiOfi-7414 (064) 677-6942, 1013131 091-2325 FAX (064) 077 6930 SNIPPING ADDRESS 4 CRAFTSMAN CT, GREER, $C 29650 WWW-ETTGNVIRONMENTAL DOM CHAIN Of CUSTODY RECORD Page Client:� / ° Qt Program Containers Preservative Parameters /• g4I l Facility: Pr /� T/�!E'1I7 �.�� ¢ 3:q? tIC'... C"� r, Zn' ME C O m ❑ O D O O 1-HZSO4 - 33-HN0 4 -NOON e -osier Whole Effluent Toxicity W .0.. � aea(Composite P Chemical Analysis & Other 7t 3 Colk4(on p ¢ .] W 0 vHCL ¢ U32A dState: NPDES #. � /3 Acute Chronic I Test Organisms ID =�,�tJen Y U f0.i only) i (Grab or Composite) y —-0.E1 A ¢ 12.U v ✓ U tip y _ `L v nm v p �; �c m�� a 3a) vE�F ZSAMPLE iL Special Instructions Sample Custody Transfer Record Time Relinquished B / Or a/nization/� Received By / Organization Secure Area Receipt Sample Tem °C Preserved? /D�atte-7 //C/// //C/' / VO� / s� 71 n a u Ps 6;T7— .0 COMPOSITE SAMPLING PROCEDURES TEMPERATURE MONITORING PROCEDURES HOLD TIME PROCEDURES Composite samples must be collected over a 24 (tour period Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 hours Time Proportional 1 sample each hour for 24 hours Equal volui 0 0 and 6 0 eC Samples must not be frozen Use water ice in sealed bags of sample collection (completion of composite sample) or at minimum 1 sample every 4 hours over 24 hours Sample may not be used after 72 hours from sample colleenon Flow Proportional As per instructions in NPDES permit .00 ET'i PO 60x 16414, GREENVILLE. SC 29606-7414 11364)1377-6942, (000) 691-2325 Fn -(864) 977 6935 SMIPPINO ADDRESS 4 CRAFTSMAN CT. GREER. SC 29650 t4V/W LTTENVIRO .MENTAL COM CHAIN vF CUSTODY RECORD Page of_7 Client: l.,�/ / oir {�T/c Program Containers Preservative Parameters Facility: ;lie Cry A �T n� /lf �� 3 .. �p U v a O _Cn iu � .- O z I ❑ M o U r,-, O at PV1 2 y m a rn m A V E _ O > L5q,71 U V✓ I-H2SO4 2• HCL 3-HNO3 4-NaOH S-ZMc e- oU cr whole Effluent T IP 1 ?: > O 1 Chemical Analysts & Other �:/vr Co% >1 _ a 0o z U ¢ LIJ +�83'r 1 State' G NPDES th r Acuto Chronic Test Organisms SAMPLE ID U V (Composite only) Composite Start Date Time (Grab or Composite)0 Sample Coaeuwn Date Time / Collected by -�=V1 — cs � y ¢ U � y ¢ r. C o U ^ M 0 C.3 m_ -O o U cD f ❑ c ^ u a ,? 9vVi c`a v, ;U E o 0 E11111 Special Instructions Sample Custody Transfer Record Dale Time Relinquished B I / Or arimbon //- /71 15X Received By / Organization Secure Area Receipt Tem °C Sample Preserved9 1 -II- 17 095r.UPS rich v COMPOSITE SAMPLING PROCEDURES Composite samples must be collected over a 24 hour period Time Proportional I sample each hour for 24 hours Equal voltu or at minimum l sample every 4 hours over 24 hours Flow Proportional: As per instructions in NPDES permit TEMPERATURE MONITORING PROCEDURES Sample temperature during collection and transport must be between 0 0 and 6 0 °C Samples must not be frozen Use water ice in sealed bags HOLD TIME PROCEDURES For toxicity testing the sample must fust be used within 36 hours of sample collection (completion of composite sample) Sample may not be used after 72 hours from sample collection N. FTI� PO BOX 1 641 4. BRCENVILLE. 9C 299505-741 4 (8641 877-6942. 180131 B91-2325 FAX (864) 877 6938 SHIPPING ADDRESS 4 OPAF 5MAN CT, GREER, SC 29650 WWW-CTYEN V IRONMENTAL.COM CHAIN t_,F CUSTODY RECORD - Page of - - - - . ,v rcrvi 1 unc mvrwI UrUIVU YRUC;EUURES FFortoxicity TIME PROCEDURES Composite samples must be collected over a 24 hour pcnod Sample temperature during collection and transport must be between Time Proportional 1 sample each hour for 24 hours Equal vola 0 0 and 6 0 °C Samples must not be frozen Use slater ice in sealed ba testing the sample must first be used within 36 hours or at minimum 1 sample every 4 hours over 24 hoursle collection (complenon ofcomposite sample) Flow Pro ortional As r mstruehons m NPDES permitmay not be used after 72 hours from sample collection ETe,,,,t,tniai, Inc P 0. Box 16414 Greenvile SG 28606 (S64) 877,6842 FAA (864) 877-6938 4 Craftman Courl, Greer, SG 29650 Americamysis bahia Survival, Growth and Fecundity Test EPA -821-12-02-014 Method 1007 Client: CITE' OF HAVELOCK Facility: WWTP NPDES # NCO021253 Test Date: 18 -Apr -17 Laboratory ID #: T49110 Test Reviewed and Approved By: Robert W Kelley, PhD QA/QC Officer Certification #E87819 Test results presented in this report conform to all requirements of NELAC, conducted under NELAC Certification Number E87819 Flonda Dept of Hedlth Included results pertain only to provided samples Page 1 of 6 Farhad Rostampour Laboratory Director SCDHEC Certification #23104 NCDENR Certification # 022 Effluent Tnxirity Rannrt Fnrm (hrnnlr Mvclrinncic D -1r: 1 Fa ty Have o N• NP # JC 02 5 P pe# 0 ounty C ave ab at ry Pe nrm x� r� ng,Te t /I sell mme ,t '!% r I e pe r esp Pte tha n S at e of ab a ry Su ery r Y t R R cat •••- o. •••�+•_ _tea. yap e_••• I l ll l l l l IV 111 a l ov lell uv" Dva 11411 D vi on f `NN ater Qua rtN 1) V R 62J Nla I Set% cc(:enter Ra cogh N(m27699-I0'21, a n R t a s �J Wa ty Da 4 nt 65 a T,re rn aS � e q s t ET yr ao eDx 1 ea 14, r3Reenva�E sc z98ots-741 a 11384) 077-6942, (800) 891-2325 FAX (8643 877 r938 SHIPPING ADDRESS 4 CRAFTtaMAN CT ORECR, SC 29690 WWW ETTENVIRONMENTAL COM CHAIN Of CUSTODY RECORD Page —L_ of Client: , [,��j-- Program Containers Preservative Parameters i ��"����n� Q� 2-1 We, Facility: 1e �P� (, ¢ a 3 U `y S rn c u to C o MOO o z �_ m O U 0� 4t v a 5 o > 1 ~ 1=H2504 2- HCL 3mHNO3 4-NaOH S=ZnAc w0he[ Whole Emuen[Tortnq ` = 3 y _ Ro 2 Chemical Analysis & Other Q < -- ) C7 [iii if9nofl State: NC NPDES #: /5? Acute Chronic Test Organisms SAMPLE ID K U fj V c (Composite only) Compos,teStart Date Time -"1116117 (Grab or Composite) SsmpleCoaclilanData Time 11117117 Collected by �,'. w y 0. U ¢ .V- U y = to) ¢ �_ C ^D^, o `^ v U_ p S o v 9 U ea ea -o c `� c) a h c `' y= A O d— rin T z U Ill --11TT Special instructions Sample Custody Transfer Record Date Time Relinquished B / Or anization Received B / Organization Secure Area Receipt Tem °C Sample Preserved9 f636 = r8 8�Ei dEx p v COMPOSITE SAMPLING PROCEDURES TEMPERATURE MONITORING PROCEDURES HOLD TIME PROCEDURES Composite samples must be collected over a 24 hour period Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 hours Time Proportional 1 sample each hour for 24 hours Equal vols 0 0 and 6 0 °C Samples must not be frozen Use water ice in sealed bags of sample collection (completion of composite sample) or at minimum I sample every 4 hours over 24 hours Sample may not be used after 72 hours from sample collection Flow Proportional As per uistruchons in NPDES Permit ET'jL",- PC] 13OX 1 641 4. SACENVILLE. SC 29 606-74 1 4 (864)877-15942. 18001 a91 -2325 F".18641 877 6938 SNIPPING AOOPESS 4 CPA1 SMAN Or. GRCEA, 8O 29650 W W W.ETTEN VniCNMCNTAL.COM CHAM OF CUSTODY RECORD Page of Client: r , (_,. � f � / Program Containers Preservative Parameters Facility: a`sa in o _ o > =s=oaM 1=H2504 2- HCL =[03 i- ZnAc Effluent Toxicity L�Lt]7 R Q ci h> e Q im W z UQ E v� State: AIC NPDES #: 00,? offWhole Acute lChronic I Test Organtslns SAMPLE ID pu o U U aC7 (Composite only) Composne Start Date Time (Grab or Composite) ®pleCollectionDnte Time Collected by 'c �= U _ t) U ... y 2 ?' o U c.0ee � o a m T>tQ 43N o Special Instructions- [Apn oye, YaQ I al-. b -P- kA5 t,i-nCj -4p�ryt +t I�U1+k '� k C D L `rky- cff�weds d t, I;Ls na-� sealed t -50 "t" li _ exL Y�v� eAk��Q i +Kk COO ( . _ 6-D3 d Sample Custody Transfer Record Date Time Relinquished By/ Organization Received By / Or anlzanon Secure Area Receipt Temp °C Sample Preserved9 1-2 UP5 i PLVAt- io It COMPOSITE SAMPLING PROCEDURES TEMPERATURE MONITORING PROCEDURES HOLD TIME PROCEDURES Composite samples must be collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing the sample must fust be used within 36 hours Time Proportional I sample each hour for 24 hours Equal voluj 0 0 and 6 0 PC Samples must not be frozen Use water Ice in sealed bags of sample collection (completion of composite sample) or at minimum I sample every 4 hours over 24 hours Sample may not be used after 72 hours from sample collection Flow Proportional: As per instructions in NPDES permit ET PO 13OX 1 641 4. GPEENVILLE. SC 29606-7414 (1964) 877-6942. (800) 891-2325 FAX (884) 877 6938 SHIPPING ADDRESS 4 rRAF S..N Cr. GREER Sc 2965❑ WWW ET CNVIRONMENTAL.COM CHAIN OF CUSTODY RECORD Page of Client: ci tq U`$_ f ' pav�.. t�LJ Facility:utV� 7�j� ¢ a U Program C W in 0 .- Z 0 L., a Containers vi iL t7 .• � Preservative 1=It2SO4to 4=NaOHLQ $= oche c=oaar Parameters Whole Effluent Toxicity P fir 3 [] R :2 Chemical Analysis & Other zm C] < r Pit State: NPDES th C, 0a 91; Acute Chronic Test Organisms SAMPLE ID E( lJ V Composite (Composite only) Composae Start Date Time (Grab or Composite) Sample Collection Date Time Collected b Y U d U d G �. U ^ U ,1 U ci e [� 3 o i9 T rs. v, _ - U i Special Instructions Sample Custody Transfer Record Date Time Relinquished By/ Organization Received By / Organization Secure Area Receipt Tem aC Sample Preserved? ,'311 li' 'OSS1 j 1 p &Litv1rC. Cat 1�c�1(21�C, �}�U� T U 2217 1 U5,6 COMPOSITE SAMPLING PROCEDURES TEMPERATURE MONITORING PROCEDURES HOLD TIME PROCEDURES Composite samples must be collected over a 24 hour period Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 hours Time Proportional 1 sample each hour for 24 hours Equal volui 0 0 and 6 0 °C Samples must not be frozen Use water ice in sealed bags of sample collection (completion of composite sample) or at minimum I sample every 4 hours over 24 hours Sample may not be used after 72 hours from sample collection Flow Proportional As per instructions in NPDES permit ET-.,,Mb1,nc P.O. BOX l W4. Greenvale. SC 23606 SEG4y 877-6942 FAX(264)877-6928 4 C!"Asman Coup, Grier, SC 29550 Americamysis bahia Survival, Growth and Fecundity Test EPA -821-R-02-014 Method 1007 Client: CITY OF HAVELOCK Facility: WWTP NPDES #• NCO021253 Test Date: 18 -Jul -17 Laboratory ID #: T49644 Test Reviewed and Approved By 4411 t1l Robert W Kelley, PhD QA/QC Officer J Certification #E87819 Test results presented in this report conform to all requirements of NELAC, conducted under NELAC Certification Number E87819 Florida Dept of Health Included results pertain only to provided samples Page 1 of 6 Farhad Rostampour Laboratory Director SCDHEC Certification #23104 NCDENR certification # 022 Facility Havelock - - - -.... _............. �...., �.� v aaarrall Date 18 -Jul -17 NPDES # NCO021253 PI e# 001 County Craven Lab na St now• - Comments X 5 Signature of Opera Jinespoq l e X �s SI nature of Laboratory Supervisor 4 MATT nDT!'iATAT grrN. r�__.e_______�_. .,-• v■uu■dua■ Ul,■carLc3 Ul A11CH Division of Water Quality NC DENR 1621 Mail Service Center Raleigh, NC 27699-1621 Control Replicates 1 2 3 4 5 6 7 8 78 Surviving # 4 3_ _ 4 5 4 5 5 5 %Surnval Original # 4 4 5 5 4 5 5 5 49 Weight (per Original) 0 390 0 213 0 262 _ 0 360 0 440 0 362 0 324 0 354 Avg Weight (mg) 0 338 Avg Fecundity 783% Fecundity (gravid/total females) 1/2 1 /1 2/3 1/2 1 /1 3/3 3/5 2/2 255 Treatment 2 Replicates 1 2 3 4 5 6 7 8 78 Surviving # 3 3 1 5 4 4 1 4 5 5 %Survival Original # 5 5 1 5 4 4 4 1 55 49 49 Weight (per Original) 0 212 0188 1 0 322 0 368 0 283 0 338 1 0 336 0 308 Avg Weight (mg) 0 294 Avg Fecundity 1000% Fecundity (gravid/total females) 2/2 2/2 0/0 2/2 2/2 2/2 2/2 3/3 255 Water Quality Data Day Control 0 1 2 3 4 5 6 7 pH Initial pH Final DO Initial DO Final Temp Initial Temp Final Salinity Initial Treatment pH Initial pH Final DO Initial DO Final Temp Initial Temp Final Salinity Initial Sample Collection Start Date Grab Composite (Duration) Conductivity (pmhos/cm) Chlorine (mg/L) Sample Temp at Receipt 80 80 82 80 82 82 83 24 hr 24 hr 78 78 73 77 77 7.9 80 70 66 64 63 68 72 62 51 53 5C 49 49 38 52 264 255 254 25L 1 254 1 252 252 267 26.7 269 265 267 267 265 247 255 260 21-0 1 262 262 171 n I o 81 80 83 V9 82 81 83 24 hr 24 hr 79 80 _ti6 79 78 80 80 68 68 67 52 68 67 64 52 50 44 47 48 45 59 50 257 256 '25 9 262 25,4 256 267 267 269 265 267 26,7 266 243 24,3 256 256 238 240 256 16 -Jul -17 18 -Jul -17 20 -Jul -17 24 hr 24 hr 24 hr 730 698 646 <0 05 007 <0 05 07 i 08 1 22 Results Significant Mortality? Yes No X Check One Growth Calc t 1 30 Tabular t 176 Fecundity Rank Sum 70 Crit value 49 PASS FAIL X Check One Test Date Effluent Test Concentration 5 replicates were set for each control test replicate, where <5 are shown the organisms were lost during rei 5 replicates were set for each treatment lest replicate, where <5 are shown the organisms were lost during DWQ Form AT -4 (6/99) Page 2 of 6 W 0 0 > 0 0 5� r� � y N O m a m .o 3 z N N Z m c a 2 N n � 0 3 o m N n 0 3 � o c n s m m 0- D f e Z Z 3 O n 0 0 3 3 —- _En 1 Ci D -0 -n C 0� �c z --I O w m IM Z m m 111111mmmmill ME 1111111MR111111 � illmilmols ����0��� 11111111111111111111111111111111���9��5� 0 > 0 0 5� r� � y N O m a m .o 3 z N N Z m c a 2 N n � 0 3 o m N n 0 3 � o c n s m m G Y� r� -� � a• � O m 2 2 0 N N N 3 m 2 N n � � 0- D f e Z Z 3 O n 0 0 3 3 —- _En 1 Ci D -0 -n C 0� �c z --I O w m IM Z m m Ery 3.4i" a�"" � SPC BOX 16414, GREENVILLE. SC 29606-7414 (864) 877-6942• I8001 891.2325 FAX (864) 877 6938 SHIPPING AODRE00 4 CRAFTSMAN CT. GREER. SC 29550 WWW LTTCNVIRONMENTAL.COM CHAIN Of CUSTODY RECORD Page ( of Client: ._r P—i Cat- \IeA jGv—) Program Containers Preservative Parameters Facility \re{'t' ¢ ai- 3 Urn e = e9j to o m O Z v c O a to 4 i y R O c O > u 1-HIS04 2m HCL 4-NaOH S-ZnAc 6=Other Whole Effluent Toxicity E- t✓ 3 Chemical Analysis & Other p < 2 CID < State: IVPDES #: Aeute Chronic Tat Organisms SAMPLE ID —° 1 (Composite only) Composite Start Date TimE (Grab or Composite) S=p)eCoaecuanDate nine Collided by F1 i e"a V < V = U ¢ n a. o D U - o c co c o [a o c c �. �- E US m T a T=i— z m ive, �' �" . ► i tl ib �L, �+t c? ✓ �. 9 @ CC VL -Hon `I A Special Instmctions Sample Custody Transfer Record Date Time Relinquished B / Organization Received By/ Organization Secure Area Receipt Tem aC Sample Preserved) 'c4. Vbr i �t i'1�`�°L�iXTl 1 Old COMPOSITE SAMPLING PROCEDURES TEMPERATURE MONITORING PROCEDURES HOLD TBfE PROCEDURES Composite samples must be collected over a 24 hour period Sample temperature during collection and transport must be beMeen For toxicity testing the sample must first be used withm 36 hours Time Proportional 1 sample each hour for 24 hours Equal volu 0 0 and 6 0 'C. Samples must not be frozen Use water ice to sealed bags of sample collection (completion of composite sample) or at minimum 1 sample every 4 boars over 24 hours Sample may not be used after 72 hours from sample collection. PO Box 16414, GREENVILLE, SC 29606.7414 (864) 877-6942, (BOO) 991 -2325 FAX (8641 877 6938 SHIPPING ADDRCSS 4 CRAFTSMAN Cr. GREER. SC 29650 WWW.LT ENVIRDNMKWAL.CCM CHAIN of CUSTODY RECORD Page of Client: py � "� � W � Program Pg Containers Preservative Parameters Facility: W Wdk t "� U $ in y rn p tz o z `m U o . Y ; E y a C7 " E o > y U 1-HSO4 3 -HCL NO3 4-NaOH 5s ZnAo �O�M whole Effluent ioxielty W F �. �] 3� a c Chemical Analysis &Other (� Q � Q u _ State: NPDES ai: 'y �j Acute Chrome I Test Organisms SAMPLE ID e(Composite C7 only) Composite Start Date Time (Grab or Composite) SempkCollecuonDala Time Collected by r y � 3 U Q U � = U Q O U V U � o U � U � �. Q � 4 � .y T— � G ? n � c T x 52 O U 5 $' ►i .i�ll�- No Vau (bufws, �� 11.1°�- C611ler-1' 47wh ILI Special Instructions Sample Custody Transfer Record Date Time Relinquished B /Organization Received B ! Organization Secure Area Receipt Tem DC Sample Preserved9 tcq, mq '7 093 PE) COMPOSITE SAMPLING PROCEDURES TEMPERATURE MONITORING PROCEDURES HOLD TIME PROCEDURES Composite samples must be collected over a 24 hour period Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 hours Time Proportional 1 sample each hour for 24 hours Equal voluj 0.0 and 6 0 DC Samples must not he frozen. Use water ice in sealed bags of sample collection (completion of composite sample) or at minimum I sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection Flow Proportional As per instructions in NPDES permit ET"jL' PO 8D% 16414, GREENVILLE. SC 29BO6-7414 (864) 877-6942, (80171 891-2325 F—:(1364) 977 6930 SHIPPIN13 ADDRESS 4 CRAFTSMAN CT, GREEK, SC 29650 WWW ET MNVIRDNMENTAL COM CHAIN OF CUSTODY RECORD Page Of�_ Client: I \1 Program Containers Preservative Parameters whole Effluent Toaetty Facility: qn y tC �1 State: NPDES 9: LL Coal W,52j Acule Chronic Test Organisms 2 c d D = n Q o U (Composite only) (Grab or Composite) __ ¢ 2' $ " _ o ;' e+ U D U 3 a ? c .0 3eo m I-NSO4 2=HCL -� a w 7 d r. _ > z _ Coll A �, y y _ 3-HNO3 4=Na0)i 0 o o E d o C Q SAMPLE ID Campos ac Start Date Time Sample Collection Date Time Collected by y U V1 rn pr (� �� 5=ZnAc =other v v ¢ ¢ U r a ct U o i �, E~ 3 Chemical Analysis & Other w 0 ) ) n ) I IT Special Instruct3ons Sample Custody Transfer Record Secure Receipt Sample P Date Time Relinquished B / Organization Received By / Organization Area Tem nC 7< Preserved9 Dry 9� - G✓%'� Z l P5 A . i! ah 2.Z COMPOSITE SAMPLING PROCEDURES TEMPERATURE MONITORING PROCEDURES HOLD TIME PROCEDURES Composite samples must be collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 hours Time Proportional 1 sample each hour for 24 hours. Equal volul 0 0 and 6 0 °C Samples must not be frozen Use water ice in scaled bags of sample collection (completion of composite sample) or at minimum 1 sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection Flow Proportional- As per instructions in NPDES permit. envirunmtatta .Inc P.O, Box 10414, Gfeei Ale, SC 29605 (E84) B77.G942 FAX (864) 877-G938 4 CraRsrnan Ccud, Glaer, 5C 20650 Americamysis bahia Survival, Growth and Fecundity Test EPA -821-R-02-014 Method 1007 Client: CITY OF HAVELOCK Facility: WWTP NPDES #• NCO021253 Test Date: 10 -Oct -17 Laboratory Sample ID #: T50175 Test Reviewed and Approved By: 4411 411� Robert W Kelley, PhD QA/QC Officer Certification #E87819 Test results presented in this report conform to all requirements of NELAC, conducted under NELAC Certification Number E87819 Florida Dept of Health Included results pertain only to provided samples Page 1 of 6 Farhad Rostampour Laboratory Director SCDHEC Certification #23104 NCDENR Certification # 022 Effluent Tnxicitv Rennrt Fnrm - Chrnnic Mvcirinnwic Pa-.c/Fail naso 1 n -n, f-1 7 Facility Havelock NPDES # NCO021253 PI e# 001 County Craven Laboratory Performing Test Comments x Signature of Operator In Responsible Charge x Signature of Laboratory Supervisor MAIL ORIGINAL TO: Environmental Sciences Branch Division of Water Quality NC DENR 1621 Mail Service Center Raleigh, NC 27699-1621 Control Replicates 1 2 3 4 5 6 7 8 Surviving # 5 4 5 3 / 4 4 5 5 Original # 5 4 5 3 4 4 5 5 Weight (per Original) 0 346 0 350 0 404 1 0 517 0 355 0 465 0 436 0 342 Fecundity (gravid/total females) 3/4 3/3 2/3 2/2 2/3 213 2/3 1/2 Treatment 2 Replicates 1 2 3 4 5 6 7 8 Surviving # 4 5 5 5 5 4 4 4 Original # 4 5 5 5 5 5 4 5 Weight (per Original) 0 395 0 362 0 380 1 0 402 0 404 0 216 0 288 0 300 Fecundity (gravid/total females) 2/3 1/2 2/2 1/ 1 1/2 0/0 1/ 1 313 Water Quality Data Day Control 0 1 2 3 4 5 6 7 pH Initial pH Final DO Initial DO Final Temp Initial Temp Final Salinity Indial 79 80 80 79 80 80 81 24 hr 24 hr 78 75 75 75 77 76 81 74 74 73 66 68 69 74 50 37 47 35 39 46 59 258 254 245 252 251 250 251 268 264 268 267 265 266 267 250 264 266 268 247 248 248 Treatment 0 1 2 3 4 5 6 7 pH Initial pH Final DO Initial DO Final Temp Initial Temp Final Salinity Initial BO 80 80 79 80 80 81 24 hr 24 hr 79 79 75 76 77 77 81 77 77 79 66 68 69 76 62 49 39 41 40 41 62 258 252 256 255 257 256 254 268 264 268 267 265 266 267 258 260 240 230 235 236 237 Sample Test Date Collection Start Date Grab Composite (Duration) Conductivity (pmhos/cm) Chlorine (mg/L) Sample Temp at Receipt 08 -Oct -17 10 -Oct -17 12 -Oct -17 24 hr 24 hr 24 hr 790 784 780 <0 05 <0 05 <0 C5 07 10 1' %Survival 100 0% Avg Weight (mg) 0 412 Avg Fecundity 740% %Survival Avg Weight (mg) 0 344 Avg Fecundity 810% Test Results Significant Mortality? Yes No x Check One Growth Calc t 1 75 Tabular t 1 1 76 Fecundity Rank Sum 61 Cnt Value 51 PASS FAIL x Check One Effluent Test Concentration 5 replicates were set for each control test replicate, where <5 are shown the organisms were lost during renewa 5 replicates were set for each treatment test replicate, where <5 are shown the organisms were lost during rene DWQ Form AT -4 (6/99) Page 2 of 6 w O ch d O) c0 d - ^ O m N a O Z ¢ C (/) ¢ If o Q m m It U N E in o O m U) W d a Q toil ❑ Z c d E : = Cl) �E O E a E E Z } a ¢N O `o o Q ^ 11 m W O all � O ^ �C H N o> o o a¢ Z �c m 3 o> O o W O U U E E m o m uoi F- m y 2? U" Z U o .- d O¢ U i g O O U Z Z e o V voi N .- in 04 voi a ^l w ° T 0-° a n o >> J V N 2 V w O ch d O) c0 d - ^ O N a O Z ¢ C 0 ¢ If o m m It U N E in o O m C U d a Q toil ❑ Z c d E : = Cl) �E O E a E E Z } a ¢N O `o o Q ^ 11 U W O all w O ch d O) c0 d �I�I�YN��I����In11111w1111�A1111A1����' � ■����� 1�����■I����Y��oO�ooO Y���� I�O�OOO 00000O�IN�����■����� 1�����■1����■��oO�ooO fo�o��i��iiii ■�iiii�iiiii�iiiii�u00000000������ �ii�i��o�o��00���� ERRO�i�idini iiii� ii�ii���ii-�-o-00�0����� 111111 111111 MORRIS �ee�e eee�e �ee�eee �eee� seeeee�see�eell w O ch d O) c0 d I" W"Woftl 19 -enwronih-enial- PO Bax 1641 4 GREENVILLE Sr 29606.745 4 (864) 677"6942 (BOOM 391»2325 FAX�YB64) 877 6922 SHIPPING Ap ORE55 4 CRGrT9t1A(,v CT GFEER- SC 29650 WWW ETTEyNVIRONMENTAL COM CHAIN uF CUSTODY RIECQRD l"a oF— Client: / ,r/�/ GC,"�/C Program Containi.rc� Presenatile PatametetS Facility. r � ,.'••7 �-;nI✓4 /�Cyl� '• cri Etc( o \1 fialG Efnuent Toilctn — Chemical Analyses & Other -- /'Il State, �)�,✓ APD);S it �r/�Ld� �C/J-h �' icutc Chronic Iest binum< SAI 1�.PLE 1D (Com osltc only p ) (Grab yr Gdmba>(,e} 5nnrt > u > a\/~ -2%' "t7 ' I � I i FIL 1 1 1 1 1 1 Special Instractions Sample Custody Tratisfei Record T_Ime ,— _Relinquished By s Oramzation P.ecehed B% Oreanazatinn 1 Secur area i ReCelpt I'emp'C Sample d,' ,,Date fop 10 0 - f C COMPOSITE S4 WFL1 i G PROCEDURES Composite samples must be collected ovCr a,24 hour period Time'ProportionaL 1 sample each hour for 24 hours Equal or at minimum I sample every 4 hours over 24 hours. Flow Proportiona �r instructions In NPDES permit TE,WPER4TURG A101'II'ORIAG PROCEDURES Sample temperature during collection and transport, must be bem eels 0 0 and 6 0 °C Samples must not be frozen Use Nater ice in sealed bags HOLD TPIIE'PROC,iDf RES For testing the SainoIo must first he LKCu %uth"p 36 hours of sample collection (,comolctlon o1 composite semplc) Sample maN, not be used atter i2 hpur5 from samnk; collection, 0 6 CHAIN Of CUSTODY RECORD y'O a'c r — — PO Baa 1 661 4 GPEENVILLE„ SC 29606 7414 (364) B77 6942 5900) 891 2325 F—,(863) 877 ,693E GylvrsiNG ADD' ESS 4 C—SMAN CT GREEK SC 29650 WWW ETTE�NVIRCNMENTAL DOM Client ick . r , K I , 1_ -, / ('i 1'• a't Program (o[rtuncr� I Preser'sahle F tame rS Facility I , —y— j i 1 � v(� � C' i r I �9�1 � d! CK ')� R hoTc Ff(luent I ct�ICI[s � i State: A/ INPD s M A � t ^ �-tL Chronic res[ OrL',1r3—Pr ! 11(t JiNo J SAMPLE ID � C),oppm��poppsltGSto D,te Time�,S—T,`!gCMI,1..n D,tL Time (7011eLt4d to -7 z � 3 � — or � � 9 �, -, wry; C = Chemical Anafysts & Other i )pcclal Instructions Sample Custody Transfer Record secure h 2cceIFl I -Sampl- Date -line Relinquished By OroanizatiotI Fcccived>3v Organization .yep -t.mp C �Presorvcd' zz i ( I i0 1� LI 0,11POSITE S 111PLING PROC'EDL',RES TEMPER--ITURE A10WTORING PROGMIRLS NOI D TI�11E PROGCEL (2rS 'omposite samples must be collected oyer a 24 hour per!Qd Sample temperature during. colbction and transport must be bemcen For IQvicin te,tTna,hu sample mpt t firt be used «lthali I)�) hours -ime Proportional 1 sample each hour for 24 hours Equal V`olut 0 0 and 6 0 °O Samples must not be lrozen C Se Mater ice III sealed baL,� of 'sample Collection ((AmpICU0I1 or cQntposite, satiiple it at minimum I sample ever} 4 hours over 24 hours Samnle ma} not be, us --o atter —2 hours From sample calfcaaon Io a Proportional, As per mstructiQns in NPDES permit CHAIN Of CUSTODY RECORD - environmental PO BOX 1 641 4, GPEEI-IL IE SC 29606 741 4 69641677-6942 'BOO) 891-2°3,25 F—,(E36�) 677 6933 SHTPFING AOORESS-� 4 CRArTSMAr, CT CREEP Sr 29650 WWW OTYGfNVfFjONMEfNTAI — Client: � % �/ �'� 1 % �� (� f f✓ � Piorram Containers Presenarne Pat ant eters Facility. iJ//..} / C �l�i'�/�'tr / J�'�C,'/•ti L�,� t"-> � s s z R•holc i(nuent 'I o—tl Chemical Analysis 8 Other State, NPD1:S i- `� ���r' �� % ✓�,�,� leuti C,ttronic 'fest 9r��nicttic _ _ SAMPLE ID v (COmI)OSIte OrIINJ Compostt� Start Dmf Time Grab z5r Compo�l.aj S� plyCuuection DI'L Time cottertea �� < j ! N f IIJ 111 I�� Special Instructions I i Sample Custody Transfer Record Date Time Relin uislte Fad/Ora. izaiiQn ReCU1ed 13%'Organization Secure. La RCOCI t 1 Iernp �C Sample �Prc5erncd'-' COdIPOSITCSAMPLING PROCEDURES TEA IPERATLRE VONIITORIV,G PROCEDCRF.S HOLD 71,1-L PR00CD2�RES Composite samples must be collected over a 24 hour period Sample temperature during collection and transport, must be betsseen, for (o\iclt} testing the sample must Ctrsf oe u;ed within 36 hour, Time Proportional 1 sample each hour for 24 hours Equal Volui 0.0 and 6 0'C Samples must not be frozen. Usc tater ice in sealed baps, of sample collection fcompletlon of compoirt, sample or at minimum 1 sample ever} 4 hours o> er 24 hours ,Sample maga not be used a lfrom m er �2 hour, om ,ample collectloa Cioxi Pronortiona er instructions in NPDES nermit City of Havelock Wastewater Treatment Plant City of Havelock, North Carolina Annual Priority Pollutant Analysis Data 2014-2017 -�- ---Min . 4, �%--- I -* =f �Dr+inking Wa Vi r.+�IDL. 3�771a5� � wastewater ID; 10 P O BOX 7085, 114 OAKMONT DRIVE PHONE (252) 75G -G208 GREENVILLE, N.0 27835-7085 FAX (252) 756-0633 CITY OF HAVELOCK MR. ART HOUGH WASTEWATER TREATMENT PLANT 304 N. JACKSON DRIVE HAVELOCK ,NC 28532 ID#: 204 H DATE COLLECTED: 05/29/14 DATE REPORTED : 06/25/14 REVIEWED BY: � � Effluent Analysis Method PARAMETERS Date Analyst Code Ammonia Nitrogen as N, mg/l 0.06 06/03/14 ALB 350.1 R2-93 Total Kjeldahl Nitrogen as N,mg/1 1.54 06/02/14 ANO 351.2 R2-93 Nitrate -Nitrite as N, mg/l 3.66 05/30/14 ANO 353.2 R2-93 Total Phosphorus as P, mg/l 0.93 06/02/14 ALB 365.4-74 Oil & Grease (HEM), mg/l <5.0 05/30/14 SEJ 1664B Phenol, ug/l <5 06/06/14 SEJ 420.1-78 Total Cyanide, mg/l <0.005 06/05/14 SEJ 450OCNE-99 Total Hardness, mg/l 119 06/04/14 TRB 2340C-97 Total Dissolved Residue, mg/l 461 06/02/14 LW 2540C-97 Antimony, ug/l <3.0 06/20/14 LFJ EPA200.8 Arsenic, ug/l <5.0 06/04/14 MEL 311313-04 Beryllium, ug/l < 1.0 06/03/14 LFJ EPA200.7 Cadmium, ug/l < 1.0 06/06/14 MEL 3113B-04 Copper, ug/I <10 06/03/14 LFJ EPA200.7 Total Chromium, ug/l <5.0 06/03/14 LFJ EPA200.7 Lead, ug/l < 5.0 06/09/14 MEL 311313-04 Nickei, ug/l <10 06/03/14 LFJ EPA200.7 Selenium, ug/l <10 06/04/14 MEL 3113B-04 Silver, ug/l <5.0 06/03/14 LFJ EPA200.7 Thallium, ug/1 < 1.0 06/20/14 LFJ EPA200.8 Zinc, ug/1 48 06/05/14 MTM 3111B-99 ID#: 204 H DATE COLLECTED: 05/29/14 DATE REPORTED : 06/25/14 REVIEWED BY: � � PO BOX 7085 114 OAKMONT DRIVE GREENVILLE N C 27835 085 CLIENT: CITY OF HAVELOCK MR. ART HOUGH WASTEWATER TREATMENT PLANT 304 N. JACKSON DRIVE HAVELOCK, NC 28532 REVIEWED BY: VOLATILE ORGANICS RPA MPTUnn C 7 A CLIENT ID: ANALYST: DATE COLLECTED DATE ANALYZED: DATE REPORTED: Wastewater ID: 9n PHONE (252) 756-6208 FAX (252) 756-0633 204 H MAO 06/20/14 06/27/14 07/07/14 PARAMETERS, ug/1 Effluent -I. Chloromeihane <10 00 - 2 Vinyl Chloride < 10.00 � 3. Bromomethane < 10.00 4 Chloroethane < 10.00 5. Trichlorcfluorontethane <5.00 -6 14-Dichloroethane < 5.00 �7. Meth) lene Chloride < 10.00 " 8. trans-1,;-Dichloroethene <5.00 "- 9. 1,1-Dichloroethene <5.00 <1-0 Chloroform <5.00 --11. 1,1,1 -Trichloroethane < 5.00 --12 Carbon Tetrachloride, <5.00 -13 Benzene <5.00 1.1 1.2-Dicliloroethane <5.00 -15 Trichloroethene <5 00 -16 1.2-Dichloropropane <5 00 -17 Bromodichloromethane <5 00 -18. 2-Chloroethyl,.tnyl Ether <5.00 19. cis-1,3-Dichloropropene < 5.00 .-20. Toluene <5.00 -21 - trans-1,3-Dichloropropene <5 00 -22. 1,1,2 -Trichloroethane <5.00 -.-23 Tetrachloroethene <5 00 -24. Dibromochloromethane <5 00 --25. Chlorobenzene <5 00 -26. EtliNlbencenc <5 00 --27 Bromoform <5.00 -28 1 1.2 2-Tetrachlcr"I ma< <5 00 1'29 1,3 -Dichlorobenzene <5.00 X30 1,4-Dichlorobeniene <5 00 =31. 1,2-Dichlorobeniene <5 00 - 32 Ac -olein < 100 00 �-- 33 Acrylonitrile <50 00 Wastewater ID: 9n PHONE (252) 756-6208 FAX (252) 756-0633 204 H MAO 06/20/14 06/27/14 07/07/14 NIMQ00��c��� alp D�c�o EENVILLE, N C 27835-7085 lod CLIENT: CITY OF HAVELOCK MR. ART HOUGH WASTEWATER TREATMENT PLANT 304 N. JACKSON DRIVE HAVELOCK, NC 2 532 REVIEWED BY: SEMIVOLATILE ORGANICS EPA METHOD 625 PARAMETERS, ug/l :1. f:21: N-Nitrosodimethylamine Phenol 13. Bis(2-Chloroethyl) Ether +1 4. 2 -Chlorophenol €� 5. 1,3 -Dichlorobenzene y 6. 1,4 -Dichlorobenzene -7. 1,2 -Dichlorobenzene rs- 8. Bis(2-Chloroisopropyl) Ether "" 9. Hexachloroethane -w10- N-Nitrosodi-N-Propylamine --11. Nitrobenzene x.12. Isophorone X13.2-Nitrophenol 14. • 2,4 -Dimethylphenol 15. Bis(2-Chloroethoxy) Methane -16. 2,4-Dichlorophenol ,017. 1,2,4-Trichlorobenzene .s18. Naphthalene ' 19. Hexachlorobutadiene 0.20., 4-Chloro-3-Methylphenol X21. Hexachlorocyclopentadiene 22. 2,4,6 -Trichlorophenol -- 23. 2-Chloronaphthalene -24. Acenaphthylene 25. Dimethylphthalate --26. 2, 6-Dinitroto ulene T' 27. Acenaphthene - 28. 2,4-Dinitroplienol 29. f.4-Nitrophenol 30. , 30I'Flu4ore 2,-Du- - -_ .�31. enitrotoluene -� 32. - Diethylphthalate 33. 4-Chlorophenyl Phenyl Ether -34.. 4, 6-Dinitro-2-Methylphenol -•35. N-Nitrosodiphenylamine ® 36. 4-Bromophenyl Phenyl Ether --37. Hexachlorobenzene r- 38. Pentachlorophenol ...-39. Phenanthrene -40. Anthracene -41. Di-N-Butylphthalate - 42. Fluoranthene 43. Benzidine .� 44. Pyrene X45. Butylbenzylphthlate X46. Benzo[a]anthracene 47. 3,3-Dichlorobenzadine •� 48. Chrysene CLIENT ID: 1-HUNE (252) 756-6208 FAX (252) 756-0633 204 H ANALYST: CHS DATE COLLECTED: 06/20/14 DATE EXTRACTED: 06/26/14 DATE ANALYZED: 07/01/14 DATE REPORTED: 07/07/14 Effluent < 10.00 < 10.00 < 10.00 < 10.00 < 10.00 < 10.00 < 10.00 < 10.00 < 10.00 < 10.00 <10.00 < 10.00 < 10.00 < 10.00 < 10.00 < 10.00 < 10.00 < 10.00 < 10.00 <20.00 < 10.00 < 10.00 < 10.00 < 10.00 < 10.00 < 10.00 < 10.00 < 50.00 < 50.00 -< 10.00 < 10.00 < 10.00 < 10.00 <50.00 < 10.00 < 10.00 < 10.00 < 50.00 < 10.00 < 10.00 <10.00 < 10.00 < 100.00 < 10.00 < 10.00 < 10.00 < 10.00 < 10.00 Page: 1 �r (iwuQ�C��� PO BOX 7085 114 OAKMONT DRIVE GREENViLLE N C 27835-70 5 CLIENT: CITY OF HAVELOCK MR. ART HOUGH WASTEWATER TREATMENT PLANT 304 N. JACKSON DRIVE HAVELOCK, NC 8532 REVIEWED BY: SEN_IVOLATILE ORGANICS EPA METHOD 625 PARAMETERS, ug/1 49. B►s(2-Ethy=hexyl)phthalate —50. Di-N-Octylphthalate — 51. Benzo[b]fluoranthene �— 52 Benro[k]fhioranthene x;53. Benzo[alpyrene x.54. Indeno(1,2,3-C,d)pyrene li 55 Dibenzo[a,h]anthracene —56 Benzo[g,h,i]perylene —57. 1,2-Dipheny1hydrazine Wastewater ID: PHONE (252) 756-6208 FAX 252) 756-0663 CLIENT ID: 204 H ANALYST: CHS DATE COLLECTED: 06/20/14 Page: 2 DATE EXTRACTED: 06/26/14 DATE ANALYZED: 07/01/14 DATE REPORTED: 07/07/14 Effluent <20 00 < 10.00 < 10.00 < 10.00 < 10.00 < 10.00 < 10.00 < 10.00 < 10 00 Envirorn P.O Box -70,15 114 Oakmont Dr Gicenvil l `. nC '7858 environ tz--v c m1 me com CHAIN OF CUSTODY RECORD Elio ,c (2 S z)156-6208 • Fax (252) 756-0633 DISINFLCI'ION w1 • 20 JCHLORINE Page of CHLORINE NEUTRALIZED AT COLLECTION � L . 4 H Week: 23 L! V Z L L Z LZ (✓� pH CHECK (LAB) CITY HAVELOCK AIR, ,!%,RT1H0UGH ❑ NONE P P P P G G P P P P G G G G G G WASTEH'ATER TREATIMENT PLANT 304 N_ JACKSON DRIVE C C C C C C D C A A A A A E E E HAVE LOCK NC 28532 �o I E F_ (252) 4-44-6421 u.r v v � o LU rr _ d N w O p 0 Z U Uc CC Rt U3 COLLECTION oo N W Q gg zz SAMPLE LOCATION DATE TIME o¢ Q F Z F v H aj W A A Wcc Effluent ✓ �O I 15 �+ -- (( f j ct�j RE 7E BY (SIG) DA ME COMMENTS 3 ' RECE IVED13Y(SIG)f DATEIi1ME RELINQJISHED BY (SIG) DATE/TIME RECEIVED BY Sif- �' r 1SE READ Instructions for completing this firm •n the reverse slde -ORM #5 wll CONTAINER TYPE, P/G CHEMICAL PRESERVATION A -NONE D-NAOH B-HNO, E -HCL C - H2SO, F -ZINC ACETATE/NAOi G - NATHIOSULFATE CLASSIFICATION UWASTEWATER(NPDES) JDRINKINGWATER DWQ/GW SOLID WASTE SECTION CHAIN OF CUSTODY MAINTAINED DURING S MENT/DEL[VERY ,Y N SAMPLES COLLECTED BY (Please Pnnt) , I ` i I SAMPLES RECEIVED IN LAB A7__QZ�°C 0 Sampler must place a 'C" for composite sample or a `G" for Grab ,amnla in tha hlnrkc nhnuo fnr onrh noromn}nr r —� f-4 EK..- Invironn , Inc. F-- <D �� ___., 1 14 Oakmont Dr CHAIN OF . _ ,'STODY RECORD G r'Ceuvlllc, NC 27858 Page 1 1 e Y"A V11011nlent I iac C011l of COO (257) 756_6208 . Fax (252) 756-0633 DISINFLCTION 77, 1 1 1 1 1 CHLORINE NEUTRALIZED AT COLLECTIOI X-111 7': CHL'0121NG 204 H Week: 23 t J (/7i �/ li� pH CHECK (LAB) CITZ' OF HAVELOCK nls - ART HOUGH NONE G G IG IG G G CONTAINER TYPE,PlG W^, STEWATER TREATMENT PLANT 304 N. JACKSON DRIVE HA VBLOCK NC 28532 A A A E E E CHEMICAL PRESERVATION cz o (252> 444-6421 A -NONE D-NAOH o f o z Q m a lu Q C B-HNO E -HCL COLLECTION _ ~ �¢ w "� c� o w Q, �y w SO, C- H SO F - ZINC ACETATE/NAC H, LOCATION o¢ w o o M InA A eq Q � � w ¢ G NATHIOSULFATE DATE TIME I. 0 aQ Effluent 0�0 « ` �I 15 1• CLASSIFICATION 1 WASTEWATER (NPDES) DRINKING WATER DWQ/GW i SOLID WASTE SECTION CHAIN OF CUSTODY MAINTAINED DURING 4 ' ENT/DELIVERY Y N SAMPLES (Please COL ECTED BY Pnnt) RELINQ HED S R) DATE/TIME SAMPLES RECEIVED IN LA �� r( 11120M DATERIME COMMENTS RE C BY (SIG) 0-36 511 Ye D RELINQUISH Y (SIG) DTE. [ME RECEI -D BY (SI ) DATEMME BY (SIG) I DATE/TIME I RECEIVED BY (SIG) PLEASE READ Instructions for completing this form on the reverse side Sampler must place a "C" for composite sample or a °G" for V " =ORM 05 Grab samnlP In fhP hlnrkc ahrnia fnr cash noromnfnr rnn-fn I 1% hCoo mugW21 GREE ILLS N C 27835-7085 :11kti 11 WETp� 11i' fEWH-TFP TREATMENT ACAP! f:, �s,� SOIV L�PT'J Lfiluent P �K,��lh�l fzRS Anah sis Method Date Nnah°st Gode lnunonia Nitrogen as \, ml;/1 <0.04 0512,1715 R\D 350 1, R2-93 Total Kleldahl Nitrogen is 1,mg/l 't 57 05f27/15 RNI) 351 2 R2-93 uV'/trate-Nnrr(C ati \, n1k/1 5 66 05122/15 KI)B 353 2 R2-93 total Phosphorus as P, ink/I 2 1l 05/28/15 kKI; 365 4-74 ()it R (,r(aj�C CHLM), nl�/1 <5 0 0512INS SLI 1664B Phenol, In, I <5 06/06//15 X1'.1 420 ,1-78 Total Glanuicp mg 1 <0 005 (15/29/'15 SLJ 45000NE-99 l otal Hardness, m-, 1 110 0j1261,15 'I RB 2340(-'-97 Total 'Dn,ohCd Re.idue, mK/I 465 0512611,5 KKK 2540('.-97 kntunom, uh I <3 0 051726/15 1, F.1 EPA200 8 Ar.uuc, u;;/l <5.0 06/112/15 '\1'111 311:38-04 Bet N 11111111 m, I <I 0 05129/15 I,F,I CP4200.7 Gadnuum, ui < 1 (1 06/01/15 111 11 311313-04 I otal Chromium. m, I <5 0 05729/15 14.1 LPA200 7 (popper, ul;'I < 10 ()5129/15 1 1',1 LPA200.7 Lead. ❑g 1 <5 0 05/29/15 NI I iNs 1 :311313-04 Nickel, u►; I < 10 05/29/15 IA I,PA200 ,7 15CICC111In1 [w I < 10 06/08/1 --; M 111 311311-04 Slher', ug:l <511 05129115 LIJ LPA200.7 1 halhum, a /I < 1 0 05126/15 LI..1 EPA200 8 Zinc. ugl 55 06/01/15 JAIN 3111B-99 DNE (252) 756-6208 FAX (252) 756-0633 ID#: 204 H DATE COLLECTED: 05/20/15 DATE REPORTED : 07/14/15 REVIEWED BY; �'�/ Fp _ _ n L' it I it PO BOX 7085 114 OAKMONT DRIVE PHONE (252) 756'6208 GREENVILLE N C 27835-7085 FAX (252) 756-0633 CLIENT: CITY OF HAVELOCK CLIENT ID: 204 H MR. ART HOUGH WASTEWATER TREATMENT PLANT ANALYST: MAO 304 N. JACKSON DRIVE DATE COLLECTED: 05/20/15 HAVELOCK, NC 28532 DATE ANALYZED: 05,/;23/15 DATE REPORTED: 07/14/15 REVIEWED BY:' VOLAT=LE' ORGANICS EPA METHOD 624 P 1R ��ik 1 FRS, ug 1 �— � I'(llnent I (_Jhloromethane 0 00 2 N mm I Chloride < i0 00 3 Bromomethanc i < lo oo 4 Chloroethane <10 00 5 `I'ri(hlorofluorontrthan(i -,5 00 6 1,1-1)1(hloroelhane <5 00 7 11etli lene Ghlornie < 10 00 8, trans-1,2-Dichlorixthen6 <5 00 9 1,1-Di(hlorocathenQ <, 00 10 (ahlorolorm <5.00 11 1,1,1-Tri(hloroethan(, <5 00 12 Garbon retrachlonde <5.00 I3 Beniene < 5 00 14 1,2-Dichloroethalm <5 00 15, '1 ri(hloroethem. < 5 00 7 16 1,2-Dlchloropl opanc. <5 00 17 Bromodlchloromethane <1 00 18 2-ChloroethN h nn 1 Lther < 5 00 19 cis-1,-Dtchk�ropropcne <5-0() 20 `toluene <5-00 21 trans-l,3-Di(hlor)piopcne <5_00 22 1,1,2-1 nchloroetnane < 5 00 23 Tetra,hloroethene <,5,00 24 Dibromo(hloromohanoD <5.o0 25 Chloroheni1•116 <5 00 26. 1, thv lben/enc <5 00 27 Rromolorm <5 00 28 1,1,2,2-Tetracehloroethane <5.00 29 1,3-Dichlorobeni ene < 5 110 1 30 1.4 -Di hlorobewene, <; 3I 7,2-Dlctllol ohenc en" < 5-oo 32 �(rolem < 100 00 1 33 k(rvionitrile <,511 ,00 1 oo��o�oor�� % hcoo T GREENVILLE N C 27835-7085 moo CLIENT: CITY OF HAVELOCK MR. ART HOUGH WASTEWATER TREATMENT PLANT 304 N. JACKSON DRIVE HAVELOCK, NC 28532 REVIEWED BY: ✓�� �o� p� SEMIVOLATILE ORGANICS EPA METHOD 625 DNE (252) 756-6208 FAX (252) 756-0633 CLIENT ID: 204 H ANALYST: CHS DATE COLLECTED: 05/20/15 Page: 1 DATE EXTRACTED: 05/22/15 DATE ANALYZED: 06/18/15 DATE REPORTED: 07/14/15 1'AKA\Ih"I'F�RS, ugil � hftlncnt I N-Nitrmochmeth\ lamme < 10 00 2 Phenol < 10 00 3 Bn(2-( hloroctln1) `Ether < 10 00 4 2-(.hlorophenol < 10 00 5 1,3-Dichlorohenicne <10 110 1,4-Dichlorobeniene, < 10 00 7 1,2-Dichlorobeniene < 10 00 8 13is(2-(.hloroctiopropNU Lthcr <1000 9 Hexachlorocthane < 10 00 10 N- sitroso(h-N-Prol)vl.iminc < 10 Olt I l Nitrobenzene < I0.00 U I.ophoronct <1(l o0 1: 2-Nrtrophenol < 10 00 14 2,4-Dunethylphenol < IO 00 15 13n(2-Chloroetho\0 \leth.me < 10 00 16 2,4-Dichlorophenol < 10 00 17 1,2,4-Trichlorobcnmic < 10 00 18 N'tphthalenc < 10 00 19. Hcxachlorobutadiene < 10 00 20 4-Chloro-3-11ethN Iphenol < 30.00 2,1 Hevachloro(Nclopentadtene < 10 00 22 2,4,6-1 richlorophenol < 10 00 21 2-( hloronaphth.denc I < 10 00 24 \cenaphtliN lent < 10.00 25 Dunetln Iphth.►late < lo o0 26 2,6-Duntrotoulene < 1(1.0(1 27 Acenaphthene < to (10 28 2,4-Duutrophenol <5O 00 29 4,Nrtrophenol <5o00 30 2,4-Duutrotoluene <10 . 00 I I Rluorene � < 10 00 32 Uie[hn Iphthalatc 1 < 10 00 33 4-C.hlorophem I Phenvl I"thc,r < 10 00 34 4,6-Duutro-2-Nicth,.lphenol <50 00 °t5 N-Nitrosochphemlanune <1(1011 36 4-13romophent I Phenvi Lther < 10 00 37 Hexaehlorobenienc < 10 00 38 Pentachlorophenol <50 00 39 Phenanthrene. < 0.00 40 Anthracene <10 00 41 Di-N-Buh Iphthalatc < 10 00 42 Fluoranthene < 10 00 43. 13cnndme. < 100 00 44 PN rene. < 10,00 45 13uh Ibenn 1phthlatc < 10 00 46 Beniola]:cntltraccn4 < 10 00 47 3,3-Dichlorobeniadute < 10 00 48 i Glin,,ene < 10 00 rr v GREENVILLE N C 27835-7085 CLIENT: CITY OFHAVELOCK MR. ART HOUGH WASTEWATER TREATMENT PLANT 304 N., JACKSON DRIVE HAVELOCK, NC 2,8532,E REVIEWED B'Y:`° SEMIVOLATILE ORGANICS EPA METHOD 625 FAX (252) 756-0633 --- CLIENT ID: 204 H ANALYST: CHS DATE COLLECTED: 05/20/15 DATE EXTRACTED: 05/22/15 DATE ANALYZED: 06/18/15 DATE REPORTED:, 07/14/15 Page: 2 PARS'NIF rL,RS. Lig, J l;fllucnt 49 liis(2-Eth�illexNl,)phthalate. <20 00 50 Di-A-Oct)lphthalate < 10 00 51 Beniolbjfluoranthene < 10, 00 52 Benrolk1fluoranthene < 10 00 53 Ben/ola]piienm < 10,00 54 Indeno(1,2,3-(A)p- rene < 10 00 55, Dibenrol'a,hlantliracene < 10 00 Ben/olg,h,i]perN lene < 10 00 57- 1,2-Diphem Itivdrazin" < 10 00 Page: 2 Environment 1, line. PO Box 7037, 114 Oak1nollr T)r Giccuvil1e. NC 27858 CRAIN OF CUSTODY RECORD Page I of _ I �u.u� uliouuiu I_iniY Ul)LNI1A_ I R)N Phone il252) 756-620 • Fax (252) 7i6-0633 CHLORINE NEUTRALIZED AT COLLECTION CLJLC)kNt ,� pHCHECK (LAB) CLIENT: 204H Week: 23 f� p p P P G G P PP CONTAINERTYPE P/G CITY OF HAVELOCK NONE MR. ART HOUGH P G G G G G G WASTEWATER TREATMENT PLANT (' 304 N. JACKSON DRIVE t (,fit C C C C C C D C A A A A A E E E CHEMICAL PRESERVATION HAVELOCK NC 28532 E � A -NONE D -NADH (252) 444-6421 6 HNO E HCL J L. (r d U Q Z Cr u v v u S w COLLECTION y i 1� `J w w G o g � y o C9 c 0 � C/) c ,n a A A C �, A A w C H,SO, F -ZINC ACETA fE NP,OH s G- NA THIOSULFATE SAMPLE LOCATIONDATE TIME ti a W Q W e Effluent*Mr'i e 15 w»a ' ;ra F, r; � r� ;�;y s ' E CLASSIFICATION WASTEWATER (NPDES) DRINKING WATER DVVQIGW SOLID WASTE SECTION CHAIN OF CUSTODY (SEAL) MAINTAINED DURING SHIPMENT/DELIVERY Y N SAMPLES CO TE BY (Please nnt) 7T] SAMPLES RE EIV IN LAB AT�C flELINOUISHED BY ($16b (5 PLEB) D4,TETIME RECEIV D -Y (SIG) COMMENTS AEICOUISH �,DATSTNIMIE � Y IG) OATEIFIME RECEIVED BY (Si DATE/TIME RELINQUISHED BY tSIG) DATFJTIME RECEIVED BY (SIG) DATETIME PLEASE READ Instl uctlons foi completing this furm on the re7,else sida Sampler must place a 'C" for composite sample or a `G' for �`"�``'"'S Crab sample in the blocks above for each parameter requested N_ ? 845 w o T (� Dp ra— R p (� 0 n" Lol ?O BOX 7085 114 OAKMONT DRIVE GREENVILLE N C 27835-7085 CITY OF HAVELOCK MR. TIM WEBB WASTEWATER TREATMENT PLANT 304 N. JACKSON DRIVE HAVELOCK ,NC 28532 PHONE (252) 756-6208 FAX (252) 756-0633 ID#: 204 H DATE COLLECTED: 0'2/23/17 DATE REPORTED : 04/03/17 REVIEWED BY: �� 2 Effluent 1nal�sis Nle(hod PARA\IL1'ERti Dale Anahsl ( o d u lnnnoma Nitrogen as N, mg/l 0 06 02 24/17 AKS 350 1 R2-93 Total Kjeldahl Ndiogen as N,mg/l 0 91 02127/17 AKS 351 ', R2-93 Nitrate -Nitrite a. N. mg 1 1:7.1 02f2)41117 iN IP 353,.2 R2-93 1 otal Phosphorus as P, mg/I 1.26 02/27417 RA.1 3654-74 (')d R Greatiu (110r). mg/I <5 02P24117 S,EJ 1664B Phenol, ug 1 <5 03/01/17 SI -1 420.1-78 l'otal GNanulu, mg I <0 005 03/02117 SE,1 4500CNE-99 Total Hardn"s, mg I 105 02/27 J7 KK'11 2340(-97 l'otal Diswh ed Residue, mg/I 444 02/28/17 SDB 254OC-97 AntmionN, ug 1 <3, 0 0324/17 ,111N EPA200 8 1rwmc, ug I <5 0 03/07 17 '\l IM 311313-04 Berrllmm, ug 1 2 03/06/17 IaF.I EPA200 7 Gadmlllm, ug 1 < 1 0 03/08/,17 '11TH 311311-04 'I oral (chromium, ug 1 <,5 0 03100 17 LFJ EPA200.7' (copper, ug I < 10 03/06/17 LFJ Ll'/X200.7 ['.call, ug I <5.0 03109/17 NIT11 31136-04 "SICKL1, ug I <10 03/06/17 1, 'I FPA200 7 Selennmi ug 1 < 10 03/15 17 N1`1 11 '3113B-0.1 5iher, ug/l <5.0 03/0617 LFJ EI'A2OO.7 fhalhum, ug I < 1 0 03 23/,17 J'11h EPA200.8 /im- ug I 70 03,106A7 LI I EPA200 7 PHONE (252) 756-6208 FAX (252) 756-0633 ID#: 204 H DATE COLLECTED: 0'2/23/17 DATE REPORTED : 04/03/17 REVIEWED BY: �� 2 PO BOX 7085 114 OAKMONT DRIVE GREENVILLE, N C 27835-7085 CLIENT: CITY OF HAVELOCK MR. TIM WEBB WASTEWATER TREATMENT PLANT 304 N. JACKSON DRIVE HAVELOCK, NC 28532 r REVIEWED BY:- . o , VOLATILE ORGANICS EPA METHOD 624 PHONE (252) 756-620;, FAX (252) 756-0633 CLIENT I'D• 204 H ANALYST:, MAO DATE COLLECTED: 02/23/17 DATE ANALYZED: 03/08/17 DATE REPORTED: 04/03/17 PARANlbTlfliti, i►g/1' k_filuent 1 Chloromethane < 10 00 2. Vinyl Chloride < 10 00 3 Bromomethane. < 10.00 �4 C;hloroethane <,10 00 5 "1'n(.hlorofluorom�lhane; <5 00 6 1,1-Dichloroethane < 5,.00 7 llethNlene Chlonde <10,00 8 tram-l.2-Dichlort)etheiie <5 00 9 1,1-Dachloroethene <5 00 10. Chloroform <5.00 11 1„1,1 -Trichloroethane <5.00 12 Carbon letrachlorado <5 00 13. Ben/em; <5 00 14 1,24* hloroethane <5.00 15. 1 riddoroethene <5 00 16 lag-Dichloropropane <5 00 17. Bromodichlorometh.ane <5.00 18 2-ChloroethN 1N ini I Esther <5'.00 19, us-I3-Dichloropropene <5.00 20, Toluene <5.00 21 tr.an-,-1,3-DichloropropEtic <5 00 22, 1,1,2-1 richlorwthane < 5.00 23 1 etra(hlorocthene < 5 00 24 Dibromochloronwthane <5 00 25 C hlorobeniene <5.00 26 Eth%lben^rc " <5 00 27- Bromoform <5 00 28'.1 1,1,2,2=Tetrachloro0hane �<5 00 29., 1,3-Dichlorobenfene <5.00 30 1,4 -Dichlorobenzene < 5.00 ;1, 1.2 -Dichlorobenzene <5 00 12 Acrole'm <100.00 33 Acrvlon'Itr11G <50.00 T 00 n»(�)ci 2 c 00 TF0(-io- � u O BOX 7085 114 OAKMONT DRIVE GREENVILLE N C 27835-7085 CLIENT: CITY OF HAVELOCK MR. TIM WEBB WASTEWATER TREATMENT PLANT 304 N. JACKSON DRIVE HAVELOCK, NC 28532 1 REVIEWED BY: SEMIVOLATILE ORGANICS EPA METHOD 625 CLIENT ID: PHONE (252) 756-6208 FAX (252) 756-0633 204 H ANALYST: JAP DATE COLLECTED: 02/23/17 DATE EXTRACTED: 02/27/17 DATE ANALYZED: 03/02/17 DATE REPORTED: 04/03/17 Page: 1 Effluent PARA11L'1'FR5, uk/l 1 N-NUroso(luuethZ lan►me < 10.00 2 Phenol < 10-00 3 il►,42-Cohloroctlivi) Ether < 10 00 4. 2 -Chlorophenol < 10 00 5 ,1,3-D►ehloroben/cm. < ]0-0(1 6 1,4-D'►(hlot oben/cne < 10.00 7 1,2-Duhlorobeniene < 10.00 3. i3�5(2-Chloro-i-methN lcthrl) Esther, < 10 00 9 Hexachloroethane < 10 00 IO \ ;lrtrosod►-A-Prop%Immi to < 10 00 11 N►trobeniene <JO 00 12 lsophoromt < 10 00 l3 2-A►trophenol < 10 00 14 2,4-DunctliN 1phenol < JO 00 15 Bis(2-ChloroethoxN) lletimne < 10.00 16- 2,4-D►chlorophcnol < 10, 00 17, 1,2,4-Tr►chlorobeniene < 10 00 18. FlN.iphthalene. < 10 00 19 Hexachlorobutad►enc < 10 00 20 4-CMoro-3-Meth 1phenol <2000 21 ilexachlorocNclopentadicne < 10 00 22 2,4,6-11►chlorophenol <J0.00 '23. 2-Chloronaphthalene < IO -00 24 A(enaphthvlenc < 10.00 25 DlmethN Iphthalate < 10 00 26 2,6-Dmrtrotoulen< < 10 00 27 %cenaphthene < 10 00 28 2;4-D►n►trophenol < 50.00 29 .4-N►trophenol <50 00 30 234-Dm►trotoluene < 10 00 31, Eluorene < 10 00 32 D►ethn Iphthala(c < 10 00 33 4-Ghlorophen} I Pl►eni 1 Cthet < 10 00 34 4,6-Dinnro-2-Nlethviphenol <50,00 35 lanune < 10 00 36 4-BromophenN I PhenN I Esther < 10-00 37. Hexachlorobeniene < 10.00 38. Pentachlorophenol < 50.00 39. Phenanthrene < 10 00 40 Anthracene < 10.00 41 Di-N-But%Iphthalate < 10 00 42 Eluoranthene < 10.00 43 Bene►dme < 100.00 44 I'v rene < 10 00 45- Butvibeimlphthlat" <l0()(I 46 Beniolalanthra(ene < 10.00 47 3.3-D►chlo►obeniadu►c < 10 00 48 (,hr%tcne < 10.110 Page: 1 c U'WoRUM hooTpown�o PO BOX 7085, 114 OAKMONT DRIVE GREENVILLE, N C 27835-7085 PHONE (252) 756-620, FAX (252) 756-0633 CLIENT: CITY OF HAVELOCK CLIENT TDs 204 H MR. TIM WEBB WASTEWATER TREATMENT PLANT ANALYST: JAP 304 N. JACKSON DRIVE DATE COLLECTED: 02/23/17 Page: 2 HAVELOCK, NC 28532 DATE EXTRACTED: 02/27/17 DATE ANALYZED: 03/02/17 REVIEWED BY,: ,=fir DATE REPORTED: 04/03/17 SEMIVOLATILE ORGANICS EPA METHOD 625 PARA1l' -1 h,FZ ltg/l Effluent 498�5�-E�th�lhe��'_�phthalatc: <20.00 50 Di-N"L0ch Iphthslate < 10.00 5'1 Ben^rQIbJtluoranthene < 1000 52 flenioIkIfluoranthen4 < 10-00 51 Beniolall)N row < 10.00 54 Indeno(l,2,-C,d)pN rent < 10.00 -55 Dibeniola,hlanthra(ene << 10.00 56 lien/olg,h,ijpe,-N lene < t0 00 57 1,p2-Diphcn%11ivdraiune < 10M I n%f1unnlcni I ('I-IAIN OF( -T4 IUl Idl',C'Okl) (,i,t:n,ilk- A(,'7SSti CA IIIdIIIkIItI IIIk. l,OII1 I)I�I\I I (,I I(=)\ Ph(,n, 25') 56 020,8 • I ' tO U(, CHLORINE NEUTRALIZED AT COLLECTION (.III t)I:I\I �) pHCHE K LAB C1,1ENI: 20-1 H Week 12 F I P P P P (` WAINER TYPE P CITY OF 111%,V1:1-0ch 'I NIR UNI WE13a HEMICAL PRESERVATION WASTE N%'ATER 'FREA'1 NIE11 1'1,AN1' 304 N JACKSO'1 DRIVE C C C C C C 1) C A A k A A E E E HAVELOCK NC 28532 A NONE D NADH (252) 671-6373 z- w z w L. „ r N "' N cn w B HNO E HCL 2 Q Z z L O _ !_ G :7 4 I 7 '� cc Q LL z G J v y c c W Lu w C H SO F Z N A El ATE NA H COLLE TION w LIJ `- 0 LL 0 `o E ° � y y G � a � � ^ " n = �, � = N N ,, C Q G NATHIOSULFATE SAMPLE LOCATION DATE TIME % lO� U 3 4- �-- Effluent ,r'�j 14 LASS FICATION WASTEWATER NPDES ❑ DR NK NG WATER DWQ,GW SOLID WASTE SECTION HAIN OF USFODY SEAL MIAIN(A NED DUR NG SHIPMENT DE IVFRY N SAMPLES COLLECTED BY Please Print SAMPLES RECEIVED IN LAB AT �� C RE N UISHED BY SIG SAMPLER DATETIME RECEIV SIG ATE'TIME COMMENTS /�V2A �?Sti REUT�QUISHED BY SIG DATETIME RECE VED B" SIG DATETIME REL NQUISHED BY SIG DATETIME RECE VED BY IG DATETIME PLEASE READ lFStl Luctions fol comp eting thI o mo n the reve15e Side Sampler must place a C for composite sample or a G for FORM Grab sample In the blocks above for each parameter requester: N ° 23 1 8 3 City of Havelock Wastewater Treatment Plant City of Havelock, North Carolina Second Species Toxicity Testing Results 2017-2018 (Results will be submitted prior to the expiration of the existing NPDES Permit on 6/30/2018) City of Havelock Wastewater Treatment Plant City of Havelock, North Carolina Exceptionally Performing Facilities, Reduction of Monitoring Frequency Analysis Attachment A Calculations for the City of Havelock WWTP Effluent Data for Monitoring Frequency Reduction Analysis Date BOD, (Summer) BOD, (Winter) TSS NH3-NNH3-N (Winter) Fecal Coliform (Summer) Units me/L me/L me/L me/L me/L #/100 mL 3 -year average 258 341 260 012 008 192 No. data points 44600 28900 73400 44600 28900 71700 Monthly Average Permit 5 10 30 05 1 35 Limit Avg % of Permit 52% 34% 9% 24% 8% 5% Limit Sampling Results 11 9 0 4 0 2 > 200% of PL Weekly Average 75 15 45 15 3 276 Permit Limit Weekly Average 0 3 0 0 0 0 Violations in Past Year Attachment B City of Havelock WWTP NPDES Permit Renewal Discharge Monitoring Report Data 10/1/2014 to 9/30/2017 Date BODS (Summer) BODS (Winter) TSS NH3-N (Summer) NHO (Winter) Fecal Coliform Units mg/L mg/L mg/L mg/L mg/L #/100 mL 10/1/2014 <2.0 <2.5 0.08 2 10/2/2014 <2.0 <2.5 011 <1 10/3/2014 <2.0 <2.5 <0 04 <1 10/4/2014 10/5/2014 10/6/2014 <2.0 <2.5 <0.04 <1 10/7/2014 Q.0 <2.5 <0 04 1 10/8/2014 <2 0 2.7 0.06 <1 10/9/2014 <2 0 <2 5 007 1 10/10/2014 2.9 Q.5 <0 04 1 10/11/2014 10/12/2014 10/13/2014 <2.0 3.8 <0.04 <1 10/14/2014 <2 0 <2 5 <0 04 <1 10/15/2014 <2 0 <2 5 008 <1 10/16/2014 <2 0 <2.5 <0 04 <1 10/17/2014 <2 0 <2 5 <0.04 1 10/18/2014 10/19/2014 10/20/2014 <2.0 <2 5 0.27 <1 10/21/2014 <2 0 <2 5 <0 04 3 10/22/2014 <2.0 <2 5 0.27 1 10/23/2014 <2 0 <2 5 0.07 1 10/24/2014 <2 0 <2.5 0.07 2 10/25/2014 10/26/2014 10/27/2014 <2 0 <2.5 0.05 <1 10/28/2014 <2 0 <2 5 0.05 3 10/29/2014 <2 0 <2 5 006 2 10/30/2014 <2 0 <2 5 007 3 10/31/2014 <2 0 <2 5 004 5 11/1/2014 11/2/2014 11/3/2014 3.2 <2 5 <0 04 1 11/4/2014 2.8 <2 5 0.06 5 11/5/2014 <2 0 <2 5 0.05 5 11/6/2014 <2 0 <2 5 0.07 1 11/7/2014 <2 0 <2 5 012 1 11/8/2014 11/9/2014 11/10/2014 2.5 <2.5 0.06 1 11/11/2014 11/12/2014 <2 0 <2 5 0.04 <1 11/13/2014 <2 0 <2 5 0.04 1 11/14/2014 3.6 <2 5 0.06 35 11/15/2014 11/16/2014 11/17/2014 11/18/2014 11/19/2014 Date BODS (Summer) BODS (Winter) TSS NH3-N NH3-N (Winter) (Summer) Fecal Coliform 11/20/2014 11/21/2014 11/22/2014 11/23/2014 11/24/2014 11/25/2014 11/26/2014 11/27/2014 11/28/2014 11/29/2014 11/30/2014 12/1/2014 29 6.0 006 <1 12/2/2014 <2.0 <2 5 007 <1 12/3/2014 <2 0 <2 5 0.04 2 12/4/2014 63 <2.5 <0 04 520 12/5/2014 <2.0 <2 5 0.06 11 12/6/2014 12/7/2014 12/8/2014 <2.0 <2.5 176 1 12/9/2014 <2 0 <2 5 033 <1 12/10/2014 3.0 <2 5 005 <1 12/11/2014 <2 0 <2 5 013 2 12/12/2014 <2 0 <2 5 Oil 14 12/13/2014 12/14/2014 12/15/2014 <2 0 <2 5 013 2 12/16/2014 <2.0 <2.5 014 <1 12/17/2014 <2.0 <2.5 0.11 <1 12/18/2014 <2 0 <2.5 <0 04 1 12/19/2014 <2 0 <2.5 <0 04 <1 12/20/2014 12/21/2014 12/22/2014 <2 0 <2.5 <0 04 <1 12/23/2014 25 <2 5 <0 04 7 12/24/2014 Q.0 <2 5 0.08 1 12/25/2014 12/26/2014 12/27/2014 12/28/2014 12/29/2014 <2 0 <2 5 0.07 1 12/30/2014 <2 0 <2.5 <0 04 2 12/31/2014 1/1/2015 1/2/2015 <2 0 <2.5 <0.04 <1 1/3/2015 1/4/2015 1/5/2015 <2.0 <2 5 0.04 1 1/6/2015 <2 0 <2 5 <0.04 3 1/7/2015 <2 0 <2 5 <0.04 3 1/8/2015 26 <2 5 <0 04 1 1/9/2015 <2.0 <2.5 0.04 1 1/10/2015 1/11/2015 1/12/2015 <2 0 <2 5 0.07 <1 Date BODS (Summer) BODS (Winter) TSS NH3-N NH37N (Winter) (Summer) Fecal Coliform 1/13/2015 <2.0 <2 5 0.06 <1 1/14/2015 <2 0 <2.5 0.09 2 1/15/2015 <2 0 <2 5 <0 04 1 1/16/2015 <2 0 <2 5 <0 04 <1 1/17/2015 1/18/2015 1/19/2015 1/20/2015 <2 0 <2.5 0.11 <1 1/21/2015 <2.0 <2.5 0.23 <1 1/22/2015 <2.0 <2 5 <0 04 <1 1/23/2015 <2.0 <2 5 <0 04 <1 1/24/2015 1/25/2015 1/26/2015 <2 0 <2 5 <0.04 1 1/27/2015 <2 0 <2.5 007 <1 1/28/2015 3.2 <2 5 010 8 1/29/2015 <2 0 <2.5 0.27 1 1/30/2015 <2 0 <2.5 <0 04 <1 1/31/2015 2/1/2015 2/2/2015 2/3/2015 <2.0 <2.5 <0.04 <1 2/4/2015 <2.0 <2 5 030 <1 2/5/2015 Q.0 110 Oil 1 2/6/2015 <2.0 <2 5 009 <1 2/7/2015 2/8/2015 2/9/2015 <2 0 <2 5 007 <1 2/10/2015 <2 0 <2.5 0.09 <1 2/11/2015 <2 0 Q.5 <0.04 <1 2/12/2015 <2.0 <2.5 009 1 2/13/2015 <2 0 <2.5 <0.04 5 2/14/2015 2/15/2015 2/16/2015 <2 0 <2.5 0.07 <1 2/17/2015 2.9 3.4 <0.04 5 2/18/2015 <2.0 <2.5 <0 04 <1 2/19/2015 <2.0 Q.5 <0 04 <1 2/20/2015 2/21/2015 2/22/2015 2/23/2015 2/24/2015 2/25/2015 2/26/2015 <2 0 <2.5 <0 04 1 2/27/2015 <2 0 <2 5 0.10 <1 2/28/2015 3/1/2015 3/2/2015 <2 0 <2 5 <0.04 <1 3/3/2015 <2 0 <2.5 005 <1 3/4/2015 <2 0 <2 5 0.05 <1 3/5/2015 <2 0 <2.5 0.08 1 3/6/2015 <2.0 <2.5 019 1 3/7/2015 Date BODS (Summer) BODS (Winter) TSS NH3-N (Summer) NH3-N (Winter) Fecal Coliform 3/8/2015 3/9/2015 <2 0 <2.5 0.20 <1 3/10/2015 <2 0 <2 5 <0.04 <1 3/11/2015 2.9 Q.5 010 <1 3/12/2015 <2 0 <2.5 <0.04 1 3/13/2015 Q.0 <2.5 006 <1 3/14/2015 3/15/2015 3/16/2015 <2.0 <2.5 013 <1 3/17/2015 <2.0 Q.5 011 <1 3/18/2015 <2.0 <2.5 0.63 <1 3/19/2015 <2.0 <2 5 0.63 <1 3/20/2015 <2.0 <2.5 0.20 2 3/21/2015 3/22/2015 3/23/2015 <2.0 <2 5 0.10 <1 3/24/2015 72 <2 5 Oil <1 3/25/2015 <2.0 <2.5 013 <1 3/26/2015 <2.0 Q.5 007 <1 3/27/2015 <2.0 <2 5 007 <1 3/28/2015 3/29/2015 3/30/2015 <2 0 <2 5 <0 04 <1 3/31/2015 <2 0 <2.5 <0 04 <1 4/1/2015 Q.0 <2.5 0.07 <1 4/2/2015 <2.0 <2.5 010 4 4/3/2015 4/4/2015 4/5/2015 4/6/2015 <2 0 <2.5 037 <1 4/7/2015 <2 0 <2 5 Oil <1 4/8/2015 <2 0 <2.5 007 <1 4/9/2015 <2.0 <2.5 011 3 4/10/2015 <2.0 <2 5 008 3 4/11/2015 4/12/2015 4/13/2015 <2 0 <2 5 014 0 4/14/2015 <2.0 <2.5 0.20 3 4/15/2015 2.2 <2.5 0.13 <1 4/16/2015 <2 0 <2.5 0.06 <1 4/17/2015 Q.0 <2.5 0.06 <1 4/18/2015 4/19/2015 4/20/2015 11.0 <2 5 0.08 1 4/21/2015 12.0 <2 5 <0 04 <1 4/22/2015 >15* <2 5 <0.04 3 4/23/2015 >11* <2 5 0.10 6 4/24/2015 4/25/2015 4/26/2015 4/27/2015 <2 0 <2.5 012 <1 4/28/2015 5.5 <2.5 014 <1 4/29/2015 <2 0 <2.5 0.09 <1 4/30/2015 <2 0 <2.5 0.08 12 Date BODS (Summer) BODS (Winter) TSS NH3-N (Summer) NH3-N (Winter) Fecal Coliform 5/1/2015 <2 <2.5 006 2 5/2/2015 5/3/2015 5/4/2015 < 2 < 2.5 0.06 <1 5/5/2015 < 2 < 2.5 0.09 <1 5/6/2015 < 2 < 2.5 008 8 5/7/2015 2.5 < 2.5 Oil 1 5/8/2015 < 2 < 2.5 0.2 4 5/9/2015 5/10/2015 5/11/2015 < 2 < 2 5 0.11 17 5/12/2015 < 2 < 2.5 018 5/13/2015 < 2 < 2.5 017 1 5/14/2015 < 2 < 2 5 < 0 04 < 1 5/15/2015 27 < 2 5 018 < 1 5/16/2015 5/17/2015 5/18/2015 21 < 2.5 0.05 < 1 5/19/2015 < 2 < 2 5 < 0.04 < 1 5/20/2015 3.5 8.3 < 0 07 2 5/21/2015 < 2 < 2 5 < 0.04 3 5/22/2015 < 2 < 2.5 006 < 1 5/23/2015 5/24/2015 5/25/2015 5/26/2015 3.4 < 2 5 < 0.04 5 5/27/2015 < 2 <25 0.91 4 5/28/2015 < 2 < 2 5 007 2 5/29/2015 <2 <2.5 0.08 < 1 5/30/2015 5/31/2015 6/1/2015 > 26 3.5 008 1 6/2/2015 > 13 <25 0 07 1 6/3/2015 > 13 < 2.5 01 2 6/4/2015 > 13 < 2.5 009 3 6/5/2015 > 13 <2.5 0.07 6/6/2015 6/7/2015 6/8/2015 2.5 <2.5 011 3 6/9/2015 <2 <2 5 005 < 1 6/10/2015 < 2 < 2.5 005 3 6/11/2015 < 2 < 2.5 < 0 04 6 6/12/2015 <2 <2 5 01 1 6/13/2015 6/14/2015 6/15/2015 < 2 < 2 5 0.09 5 6/16/2015 <2 <2 5 0.13 3 6/17/2015 <2 <2 5 0.12 23 6/18/2015 <2 <2 5 007 5 6/19/2015 <2 <2.5 006 < 1 6/20/2015 6/21/2015 6/22/2015 < 2 < 2 5 < 0 04 9 6/23/2015 <2 <2.5 019 6 00 \ 00 \ 00 \ OD \ 00 \ 00 \ 00 \ OO OO OO OD OO OO OO OO OO V \ V \ V \ V \ J \ J \ V \ V \ J \ V \ J \ V \ J \ V \ V \ V \ J \ J \ V \ V \ V \ V \ J V V V V J J V V 07 \ 01 \ O1 \ Q7 \ 01 \ 0l \ Q1 \ I-+- M N Ln N A N W F-• N N N N\\\\\\\\\ O UJ 00 V Cl Ul A W N N W F� W O N W N W N J N M N W N A N W N N N N N O N W I--� 00 F-• V F-� M F-• V7 N A I--' W F-� N N N N\\\\\\\\\ O l0 00 V 01 U7 A W N F+ W O N l0 N 00 N V N Cl) N Ln N A \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N Ol 0 0 0 0 0 0 0 O O O O O O O N O O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 O F, O F-� O N O N O F, O F, O O O N 0 0 0 0 0 0 0 4� Ul Ul Ul Ul Ul Ul Ul Ul N W F, U'I F, Ul lJl Ul lJl w W W Ul Ul N U1 W Ut 111 Ul N 111 N Ul U7 l71 Ul V7 Ul Ul Ul Ul Ut Ul Ul In V7 Ul U7 U'1 Ul U1 U7 Ul Ul Ul Ul Ul Ul Ul Ul O v A A A A A A A A A A A A A A A Ul A A A A A A A N A A A A A A A A A A A A A H N N N N N N N N N N N N N N N W N N N N N N N W N N N N N N N N N N N N N 3 3 00 O v NS 1 A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A N N N N N N N N N N N N N N N W N N N N N N N N N N N N N N N N N n7 N N N to Ul Ul Ul In Ul Ul Ul Ul Ul Ul Ul Ul Ul 1n Ul w Ul Ul U1 Ul Ul Ul U1 Ul Ul Ul Ul Ul Ul Ul Ul Ul Ln Ul Ul Ul (n H H O O AO O O F+ O A o O O O O O N O O O O O O O O A O A o A 0 O O O A 0 A 0 O O O A 0 O O O C Z 3 s 00 000 JN 000 0���. -+ wN ~' "C) oN 0000 ? 000 J 01 l77 00ui Cl lJl U7 3 w A Ln V J J F-� A Ol Ul W N W N Ql N N Cl) J O? 00 01 V A fD Z Z w CZ G 7 fD T n n m W w m w Ln N F' N W V N w O N A N O UlJ F-� 00 Ul V w 01 l--• J A O m 00 m w m n O N J N l0 E-+ J O 3 F� " �- �, �-- �-- �, " � w w w w w w w w w w w w w w w w w w w w w 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 -- 0 0 0 0 0 0 0 0 0 \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ N \ N \ N \ N \ N N \\\\\\\\ -- W N N N N N N N N N N N N N N N N F� N N \ \ \ \ \ \ \ \ \ W W N N N N N Ul N A N W N I--' O l0 00 V v l0 00 V Ol l!1 A W N F-� O l0 \ 00 \ V \ 01 \ W \ A \ W \ N \ F+ \ O l0 \ 00 00 \ V \ Cl) \ W \ A \ W \ N \ F-� \ O \ �' \ O \ W \ 00 \ V \ Cl \ \ \ \ \ \ \ \ \ \ 03 \ N \ N \ N \ NN \ \ N \ N \ N \ N \ N N N N N N N N N N \ N N N N N N N N N N N N O N O N O N O N O N O N O N O N O N N NN N N N N NN) N N N N N " m O O O O O O O O O O O O O O O O O O O O o O O O O O O O O O F-' N N N N N N O O o O O O O O O O O O O O O N N N N N N N N H H N N N N N N N N Ul Ul W W NLrl W LPA , Ul N N N N N N N N W w w W U1 Ln W Ul w Ul w Ul w Ul w U7 Ul Ul Ul w U7 w l/'I {A Ul U7 Ul Ul U7 Ul V7 Ul w Ul w U7 Ul W Ul U1 w Ul Uf Ln Ul Ln 11l Ul Ln Ui Ul Ul Ul Ul ll1 l!1 Ul w Ul Vl W Ul O v N A A A A A A A A KJA A A N A A A A A A A A A A A A A A A A A A A A A A A A A V1 N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N C 3 3 �o 0 v rr fD A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A N N N N N N N N W N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N LA Ul Ul Ul Ul Ul In Ul Ln Ul Ln Ln N Ut Ln Ul M Ul In l!7 Ln N U7 In Ul Ul Ul l!l Ul l!1 Ul In Ul 111 111 Ul In Ul V7 H N A 0 A 0 OA A 0 A 0 A 0 A 0 A o OA A o A o A o A 0 A 00 OOA OAA O 0 W O O O O O O O O O O O A 0 O O O = C O W 0 O O O O A O O O N 0, V O O O 00 W N O 00 O 00 O l0 O 00 O V O 00 O V O V O V 00 O O 0 O 0 O0 0 wZ A A A A A l0 A A A A mZ Z 2 W sZ r rt fD n d A A V-� A m W Ul W A N N M A~ W N F-` N N N ~ N N N N W W A Ul N n O N N f-+ O O 3 Date BODS (Summer) BODS (Winter) TSS NH3-N (Summer) NH3-N (Winter) Fecal Coliform 10/10/2015 10/11/2015 10/12/2015 < 2 < 2.5 < 0.04 < 1 10/13/2015 < 2 < 2.5 017 < 1 10/14/2015 < 2 < 2.5 0.04 < 1 10/15/2015 < 2 < 2.5 006 2 10/16/2015 < 2 < 2.5 006 < 1 10/17/2015 10/18/2015 10/19/2015 < 2 < 2.5 0.07 8 10/20/2015 < 2 < 2.5 0.07 4 10/21/2015 < 2 < 2.5 0.10 < 1 10/22/2015 < 2 < 2 5 < 0 04 < 1 10/23/2015 < 2 < 2 5 005 2 10/24/2015 10/25/2015 10/26/2015 < 2 < 2.5 005 < 1 10/27/2015 < 2 < 2 5 006 1 10/28/2015 < 2 < 2.5 0.05 1 10/29/2015 < 2 < 2.5 005 < 1 10/30/2015 < 2 < 2 5 0.09 <1 10/31/2015 11/1/2015 11/2/2015 <2 < 2 5 0.04 4 11/3/2015 <2 <2 5 0.14 3 11/4/2015 < 2 < 2 5 0.05 2 11/5/2015 < 2 < 2 5 < 0.04 1 11/6/2015 < 2 < 2 5 0.04 < 1 11/7/2015 11/8/2015 11/9/2015 <2 <2.5 <0 04 11/10/2015 < 2 < 2.5 < 0 04 2 11/11/2015 11/12/2015 < 2 < 2.5 < 0.04 11/13/2015 < 2 < 2 5 < 0.04 < 1 11/14/2015 11/15/2015 11/16/2015 < 2 < 2.5 < 0.04 < 1 11/17/2015 <2 <2.5 <0.04 < 1 11/18/2015 2.4 < 2.5 0.4 < 1 11/19/2015 < 2 < 2.5 005 0 11/20/2015 < 2 < 2.5 0.04 2 11/21/2015 11/22/2015 11/23/2015 < 2 < 2.5 007 < 1 11/24/2015 < 2 < 2 5 < 0 04 11/25/2015 < 2 < 2 5 < 0 04 1 11/26/2015 14 11/27/2015 11/28/2015 11/29/2015 11/30/2015 <2 <2 5 0.07 < 1 12/1/2015 <2 < 2 5 < 0.04 < 1 12/2/2015 <2 <2 5 0.04 4 Date BODS (Summer) BODS (Winter) TSS NH3-NNH3-N (Winter) (Summer) Fecal Coliform 12/3/2015 <2 <2 5 <0.04 2 12/4/2015 <2 < 2.5 <0.04 3 12/5/2015 12/6/2015 12/7/2015 3.2 <2.5 0.04 2 12/8/2015 < 2 < 2.5 0.05 < 1 12/9/2015 < 2 < 2.5 < 0 04 < 1 12/10/2015 < 2 < 2.5 < 0 04 < 1 12/11/2015 < 2 < 2.5 < 0.04 < 1 12/12/2015 12/13/2015 12/14/2015 <2 <2 5 <0 04 1 12/15/2015 < 2 < 2.5 < 0 04 1 12/16/2015 <2 <2.5 <0 04 < 1 12/17/2015 < 2 < 2.5 < 0 04 1 12/18/2015 < 2 < 2.5 < 0.04 < 1 12/19/2015 12/20/2015 12/21/2015 < 2 < 2.5 < 0 04 < 1 12/22/2015 < 2 < 2.5 < 0 04 < 1 12/23/2015 < 2 < 2.5 < 0.04 < 1 12/24/2015 12/25/2015 12/26/2015 12/27/2015 12/28/2015 25 < 2 5 < 0 04 1 12/29/2015 < 2 < 2 5 < 0 04 < 1 12/30/2015 < 2 < 2 5 < 0 04 1 12/31/2015 < 2 < 2 5 < 0.04 < 1 1/1/2016 1/2/2016 1/3/2016 1/4/2016 < 2 < 2.5 < 0.04 < 1 1/5/2016 4 < 2 5 < 0.04 1 1/6/2016 < 2 < 2 5 < 0.04 < 1 1/7/2016 < 2 < 2 5 < 0.04 1 1/8/2016 < 2 < 2 5 < 0 04 1 1/9/2016 1/10/2016 1/11/2016 < 2 < 2 5 < 0 04 < 1 1/12/2016 < 2 < 2.5 0.05 < 1 1/13/2016 < 2 < 2.5 0.07 < 1 1/14/2016 < 2 < 2.5 < 0.04 1 1/15/2016 < 2 < 2.5 < 0.04 < 1 1/16/2016 1/17/2016 1/18/2016 1/19/2016 < 2 < 2.5 < 0.04 < 1 1/20/2016 < 2 < 2.5 < 0 04 2 1/21/2016 < 2 < 2 5 < 0.04 < 1 1/22/2016 < 2 < 2.5 < 0.04 < 1 1/23/2016 1/24/2016 1/25/2016 < 2 < 2 5 < 0.04 11 Date BODS (Summer) BODS (Winter) TSS NH3-N NH3-N (Winter) (Summer) Fecal Coliform 1/26/2016 < 2 < 2.5 < 0.04 2 1/27/2016 < 2 < 2.5 < 0.64 4 1/28/2016 83 0.0811 5 1/29/2016 26 < 2.5 006 20 1/30/2016 1/31/2016 2/1/2016 < 2 <25 0 09 649 2/2/2016 67 10 0.18 6 2/3/2016 < 2 < 2 5 006 1 2/4/2016 4 6.5 0.18 10 2/5/2016 <2 2.7 0.12 9 2/6/2016 2/7/2016 2/8/2016 < 2 < 2.5 < 0 04 1 2/9/2016 < 2 10 0.04 < 1 2/10/2016 < 2 < 2.5 < 0 04 1 2/11/2016 < 2 < 2.5 < 0 04 1 2/12/2016 < 2 < 2.5 < 0 04 1 2/13/2016 2/14/2016 2/15/2016 <2 < 2 5 0.11 < 1 2/16/2016 < 2 < 2 5 0.05 2 2/17/2016 <2 < 2 5 <0 04 < 1 2/18/2016 < 2 < 2 5 0.07 1 2/19/2016 < 2 < 2 5 0.05 1 2/20/2016 2/21/2016 2/22/2016 <2 < 2 5 0.05 < 1 2/23/2016 <2 < 2.5 005 < 1 2/24/2016 < 2 < 2.5 007 2 2/25/2016 < 2 < 2.5 006 1 2/26/2016 < 2 < 2.5 009 1 2/27/2016 2/28/2016 2/29/2016 4 < 2 5 005 1 3/1/2016 < 2 < 2.5 0.07 1 3/2/2016 3.5 < 2 5 006 1 3/3/2016 < 2 < 2 5 0.06 < 1 3/4/2016 < 2 < 2.5 0.04 < 1 3/5/2016 3/6/2016 3/7/2016 < 2 < 2.5 < 0 04 1 3/8/2016 < 2 < 2 5 005 < 1 3/9/2016 < 2 < 2.5 007 24 3/10/2016 < 2 < 2 5 005 < 1 3/11/2016 < 2 3.7 006 < 1 3/12/2016 3/13/2016 3/14/2016 < 2 < 2.5 005 < 1 3/15/2016 < 2 < 2 5 0.08 1 3/16/2016 37 < 2.5 0.09 1 3/17/2016 < 2 < 2 5 0.04 < 1 3/18/2016 < 2 < 2.5 0.07 2 3/19/2016 to to U1 W W U'1 A A A A A \ A A A A A A A A A A A A A A A A A A A A A A A A A w w w w w W w w w w w w \ N \ N \ N\\\\\\\\\ \ W \ N \ N \ N N \ N \ N \ N \ N \ N \ N \ N \ I--' \ N \ N \ F-+ \ N \ I--� \ N \ F-� \ F-+ \\\\\\\\\ \ W \ W \ N \ N \ N \ \ \ N \ N \ N \ N \ N N N O lO 00 J Ol U'1 A W N I-� O W M J M 111 A W N N O W M J M U7 A W N I--� O l 00 V Ol l/'1 A W N N N O w w V N m N w A W N N O v \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ N N N N 0 N 0 N 0 N 0 N 0 N 0 N 0 N 0 N 0 N N N N N N N N N N N N N N N N N N N N N N 0 N 0 N 0 N 0 N 0 N 0 N 0 N 0 N 0 N N N N N N N N N N N N M O O O N N N N F+ N O O O O O O O O O O O O O O O O O O O O O N N N N F-) N O O O O O O O O O O O O �p N N N Ql m Ol a) O1 Ol m Ol Ol 01 01 Ol N N N N N N N Ql Ol 0) 01 Ol M 01 M 01 01 Cl) 01 N N N hm Ol Ol Ol Ql Ol Ol Ol m Ql m Ol 01 01 Ql 01 Ql C) Ol 0) Ol Ql m Ol Ol m Ol G) Ql Ql 0) Ol Ol D1 cn Ql m cn Ol Ol cn Ol cn Ol Ol cn Ql Ol m Ql Ol Ol m O v A A A w A A n A n n n A n N A n n A N A A A A A N n A A A A y N N N V N N N N N N N N N C N N N N C N N N N N N N N N N C 3 3 ro O v A A N A n A A A N N Cl) N N N N Ni 7 .M m A n n A A A n A n A A n n A n A n A n A A A A A A A A A A A A n A A A A n A N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N W N N N N y w w w w w w w w w w W In w w U'1 Ul Ul Ul Ul In W Ul W w N w w w Ul U'1 Ul Ul Ln Ul W U7 Ul y y O O C O O O O O O O O O O O O O O 0 0 0 0 0 0 0 0 0 O C Z 0 0 0 0 0 0 O 1-A 0 C ON o o o o 00000 CDOOM O 3 = U'1 Ul A A V V Ol w 00 00 0 N V LO Ol In V A V Ol 0) A U'1 U9 l0 m 00 fD Z Z 2 w O O O O O O O O OJ ~' ~' W A cZ LOO wOn G 7 M fD T n m n A nn N~+ ~+~+ n I--' n A n n A A n N n n n N n N �' n n n ni n A n n n n F+ F, N CD — O 3 Cl) M m m m m M m m m Q1 0 0 0 0 Ol m m m m m m M m M Ol 01 M 01 01 Ul w Ul W U7 Ul W Ul W W Ul w Ul Ul Ul N Ul Ul Ul V Ul\ V V \\\ V V \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \\\\ \ \ W \ W \ \ \ \ \ \ \ N \ N \ N \ N \ F -A \ N \ I -A \ F-- \ \ \ Ul \ A \ W \ N \ F-' \ W O N l0 N 00 N V N 01 N Ul N A N W N N N F+ N O N l0 N 00 F-� V N QI N Ul N A I-� W N N F-' N H\\\\ O l0 \ DD \ V \ Q1 \ Ul \ A \ W \ N \ N \ F-+ O N l0 N 00 Si V N O1 N V7 N A W N \ F' \ O \ l0 \ 00 \ V \ Qt \ Ul \ A W G Ol N N N N N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N \ N N O N O N O N O N O N O N O N O N O \ N \ N \ N \ N \ N \ N \ N \ N \ N N N N N N N N N \ N \ N A O O O O O O O O O O O O O O O O O O O O O O O O O O OO OO N 0)m N 01 N cn NNm N N N F -A F-' 1--' N N N F-' N M M M M m M 0) M m N N N F-` N F' " Ol 0 0 0 0 M 01 01 M m M M m m m m m m m mO M01 M m m M m 0) M M 01 Ol m 01 m M 0 0 0 N V A W A A N A A A A A N A A N A W W A W W N N A N A A A N A A A N A (/f A N Ln N N M N N N N F' N Ul N N W N N W LO A N 00 N m N N N N N N N U7 N 3 �o O 0 �o A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N A N W Ul Ul Ul Ul Ul Ul U7 Ul Ul Ul Ul Ul Ul Ul Ul Ul Ul Ul Ul Ul Ul Ul Ul W U1 Ul Ul Ul Ul Ul Ul in Ul Ul Ul H O O O O O O O O O O O A O A A A 0 A 0 O O O A 0 O O O O O O O O O A 0 A 0 O O O C Z 3= N o 0 0 0 o i-• i--� o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 o 0 3 M W w M V 00 M N 00 V 01 A m A .OP C A 00 A U7 U7 00 V M Ul V m V A A A W Ul Z M S w Cz G 7 e* fD T fD n d V W N A N N N N Ul W N N N A V N N N A W l0 A A A F-+ N N A F+ A F-' W A W N A r1 O 3 Date BODS (Summer) BODS (Winter) TSS NH3-N (Summer) NH3-N (Winter) Fecal Coliform 7/6/2016 < 2 < 2.5 Oil 8 7/7/2016 22 < 2 5 < 0 04 4 7/8/2016 < 2 < 2 5 0.09 3 7/9/2016 7/10/2016 7/11/2016 < 2 < 2.5 0.26 4 7/12/2016 < 2 <25 0.07 3 7/13/2016 < 2 < 2 5 0.08 2 7/14/2016 < 2 < 2 5 008 3 7/15/2016 < 2 < 2 5 0.11 4 7/16/2016 7/17/2016 7/18/2016 < 2 < 2.5 0.06 63 7/19/2016 < 2 < 2 5 0.08 231 7/20/2016 < 2 < 2.5 < 0 04 6 7/21/2016 < 2 < 2 5 0.05 9 7/22/2016 24 < 2.5 < 0 04 3 7/23/2016 7/24/2016 7/25/2016 2.4 < 2.5 004 42 7/26/2016 < 2 < 2.5 < 0.04 35 7/27/2016 < 2 < 2.5 < 0 04 < 1 7/28/2016 2.3 < 2.5 004 1 7/29/2016 28 < 2.5 005 4 7/30/2016 7/31/2016 8/1/2016 2.7 < 2.5 007 2 8/2/2016 2.8 < 2.5 008 1 8/3/2016 3.7 < 2.5 Oil 1 8/4/2016 3 < 2.5 012 1 8/5/2016 4.6 < 2.5 009 1 8/6/2016 8/7/2016 8/8/2016 3.9 < 2.5 012 < 1 8/9/2016 3.2 < 2.5 008 2 8/10/2016 2.8 < 2.5 0.08 3 8/11/2016 <2 < 2.5 0 2 8/12/2016 < 2 < 2.5 0.12 < 1 8/13/2016 8/14/2016 8/15/2016 27 <2.5 0.05 1 8/16/2016 <2 <2.5 0.05 1 8/17/2016 < 2 < 2.5 < 0.04 4 8/18/2016 <2 < 2 5 < 0 04 7 8/19/2016 2.5 < 2 5 007 8/20/2016 8/21/2016 8/22/2016 96 3.6 0.07 58 8/23/2016 4.4 2.9 012 d 8/24/2016 2.7 5.8 017 18 8/25/2016 4.2 < 2 5 013 4 8/26/2016 2.8 <25 0.1 2 8/27/2016 8/28/2016 Date BODS (Summer) BODS (Winter) TSS NH3-N (Summer) NH3-N (Winter) Fecal Coliform 8/29/2016 3.7 <2 5 006 6 8/30/2016 2.5 <25 < 0 04 2 8/31/2016 28 <2 5 <0.04 7 9/1/2016 26 < 2 5 006 6 9/2/2016 26 < 2 5 004 11 9/3/2016 9/4/2016 9/5/2016 9/6/2016 2.3 <25 0 07 154 9/7/2016 < 2 <25 0.06 9 9/8/2016 < 2 <25 < 0 04 7 9/9/2016 < 2 < 2.5 005 2 9/10/2016 9/11/2016 9/12/2016 < 2 28 0.06 25 9/13/2016 < 2 < 2.5 - 0.06 16 9/14/2016 <2 <2.5 007 13 9/15/2016 < 2 < 2.5 0.08 6 9/16/2016 < 2 < 2 5 0.09 5 9/17/2016 9/18/2016 9/19/2016 53 < 2.5 012 1 9/20/2016 <2 <2 5 0.06 14 9/21/2016 3.2 < 2 5 008 2 9/22/2016 < 2 < 2.5 Oil 1 9/23/2016 < 2 < 2 5 004 < 1 9/24/2016 9/25/2016 9/26/2016 < 2 < 2 5 < 0 04 1 9/27/2016 3.8 <2.5 004 < 1 9/28/2016 < 2 < 2 5 < 0 04 < 1 9/29/2016 < 2 < 2.5 < 0 04 1 9/30/2016 <2 <2.5 <0 04 1 10/1/2016 10/2/2016 10/3/2016 2.5 28 < 0.04 < 1 10/4/2016 <2 <2.5 0 060 1 10/5/2016 < 2 < 2.5 < 0.04 < 1 10/6/2016 3.2 <2,5 <0 04 < 1 10/7/2016 43 <2.5 <0 04 < 1 10/8/2016 10/9/2016 10/10/2016 <2 <2 5 <0.04 1 10/11/2016 < 2 < 2 5 < 0 04 < 1 10/12/2016 < 2 <25 < 0.04 3 10/13/2016 <2 < 2 5 < 0 04 < 1 10/14/2016 <2 < 2,5 < 0 04 < 1 10/15/2016 10/16/2016 10/17/2016 <2 <2.5 004 1 10/18/2016 <2 <25 0 04 1 10/19/2016 < 2 < 2 5 006 < 1 10/20/2016 < 2 < 2 5 0.05 < 1 10/21/2016 2 4 < 2 5 007 1 Date BODS (Summer) BODS (Winter) TSS NH3-N (Summer) NH3-N (Winter) Fecal Coliform 10/22/2016 10/23/2016 10/24/2016 2.1 <25 0.07 < 1 10/25/2016 2.2 <25 0.05 4 10/26/2016 <2 <2 5 0 < 1 10/27/2016 < 2 < 2.5 < 0 04 < 1 10/28/2016 <2 <2.5 006 1 10/29/2016 10/30/2016 10/31/2016 < 2 2.7 0.05 < 1 11/1/2016 <2 < 2.5 < 0 04 1 11/2/2016 9 < 2.5 006 < 1 11/3/2016 8.7 < 2 5 005 24 11/4/2016 96 <25 0 14 1 11/5/2016 11/6/2016 11/7/2016 < 2 < 2.5 0 5 11/8/2016 81 < 2.5 0.07 < 1 11/9/2016 46 <2.5 0.05 1 11/10/2016 6.5 Q.5 0 < 1 11/11/2016 11/12/2016 11/13/2016 11/14/2016 <2 <2.5 <0 04 < 1 11/15/2016 12 <2.5 <0.04 < 1 11/16/2016 12 < 2.5 005 < 1 11/17/2016 68 < 2.5 0.06 < 1 11/18/2016 26 < 2 5 <0.04 < 1 11/19/2016 11/20/2016 11/21/2016 <2 <2 5 0.09 < 1 11/22/2016 < 2 <2.5 0.09 < 1 11/23/2016 25 < 2 5 0.05 < 1 11/24/2016 11/25/2016 11/26/2016 11/27/2016 11/28/2016 24 < 2 5 <0 04 < 1 11/29/2016 26 <2 5 <0.04 < 1 11/30/2016 13 < 2 5 <0.04 < 1 12/1/2016 24 <2 5 0.05 < 1 12/2/2016 24 9.9 0.04 1 12/3/2016 12/4/2016 12/5/2016 12 2.6 004 < 1 12/6/2016 63 <2 5 < 0.04 < 1 12/7/2016 13 <2 5 0.060 < 1 12/8/2016 23 <2 5 0.08 < 1 12/9/2016 < 2 <2.5 014 < 1 12/10/2016 12/11/2016 12/12/2016 2 <2.5 012 1 12/13/2016 < 2 Q.5 0 < 1 12/14/2016 2 <2.5 < 0 04 < 1 N N N N N N \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ N N N N N N N N N N N N N N N N N N N N N N N N N N \ 0) \ Ln \ \ \ \ W W N N N N N N N N N N 0 l!7 NN W \D \0 \ \C \l! \ \W \ \ \WN \ \\N \\N \\N \\N \\N \\N \\N \\N \\N \\N \\N \\N \\N \\N \\NO 0�p \lN! \N \WN \NN \N\ 0 00 Cl) lJ W NNO 0 00 \ O 0 00 V O1 l! W NJ LD 00 U IUN 0 N 0 N 0 N 0 N 0 0 N NNN N N N N O N O O N O O O O O O O O O NO O O NNN O OO N N N\\ N NO N N OOOOO N N N O NN O NV N N N N O O O O O O O O O O O O O 0 V VVN V V V V VV VVV 14 V V V N N NNN N N N N N N N N N N N NV 0) 01 T O) M On O1 0) 0n On cn M m M M M 01 0 0 N C 3 3 A ao O 0 N AA A V A A N N A A A A N W A (n A A A A W A A A A A A A A A N A W l!1 N N N 00 N N N N N N N N o N N W N N N N N N N N N N N N N Nen N M Ln 7 fp A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A .� N N N N N N N N N N N N N N N N N N N N N N N N N N N N W N N N N N in V7 Ln Ul U7 Ln Ln Ul Ln Ln Ln U1 Ln Ln U1 U1 U7 V7 U1 V7 in Ln U7 Ln W N W Ln Ln lA (n Ln Ln 01 H c z 3 z x O O A O O O O O O AO 0 A 0O O o o O O A O O O O O A O O O O O A O A O A O ZC 0 O 0 0 0 olLl!1 OO 0 0 o o o O O o V d1 Ao C V . l!1 A 0 m 0 c 00 V A L U 00m m 0 0 A G 7 fD m r n lu A A A A A A A A A A A A A A A A A N A A A A A N A A A A N A A A N C N N N N N N N N N N N N N N N N N N N N N N N N N N N N N yi 0 1 3 W W W W W W W W W W W W W W W W W W W W W WN W W W W W W W W W N N N N N N N N N N N N N N N N N N N N N \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ F� F-' O l0 00 V Q1 l77 A W N F� O l0 00 V Q1 U'1 A W N F-' O l0 00 V 01 ll1 A W N N 00 J m y A W N F-A O w 00 J m Ul A W N N O LO 00 V \ N \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ N \ N \ N \ N \ N \ N \ N \ N \ N \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ N \ N \ N O NN O O N O N O N O N O N O N O NN O O NN O O NN O O N O N O N O N O N O N O N O N O O O O O O O O O O Nm O O N O N O NN O O N O N O N O N O N O N O N N N N N N N O O O rt m F� F-' ll H+ N N F� H F-A 1--' F-` " N N F, N N N N N O N O i" O " O I-• O " O F-- O N N N N V J V V V V V J J V V J V V V J V J J V V V J V J V J J J V V V V V V J J J V J V V V V W 0 O N N C 3 3 �o O v N N N W WW n N N NA n n n n N W n n n n n W N n n A n n n n n n n n N n n n A Ol Oo A NLD W A N N N N N F+ N N N N N l77 A N N N N N N N N N N N N N N N 7 fD n n n n n N n n n n n n n n n n n n n n n n n n n n n n n n n n n n n n N N N N N N N N N N N N N N N N N N N N N N N N W N N N N N N N N N N N l0 N y In In In In In In V7 U9 In In In In In Ln In (n In N In In Ln In Ln In F'" In In Ln In In In Ln In in Ln Ln 00 In V1 H C Z fD Z Z 2 W 0 0 0 0 0 0 0 0 0 O n p O O O n O O O n O O 0 0 0 0 0 O O O O O O O O O O 0 0 0 0 0 O0 O O 1.0 V l0 l0 O J 0 00 0 M 0 Ln O 0) O 0) O 00 O V O 0) O 00 O J F— Ln F-- N " O O O ~' O O O O O 00 O" O " O O O A 0 A F-' 00 w m V J 00 M M W 00 W 00 N y 00 M 7 rf f0 fD A d A n n n n n F, n n n n O n n n N nn F� F A n N N 00 N n n n n N~ r O 3 In \ l!7 \ (Jl \ l!7 \ lJl \ lJl \ lA \ lJl \ 111 \ Ul \ lJl \ lJl \ Ul \ l!7 \ lA \ lJl \ y y y N y w W A \ A \ A \ A \ A \ A \ A \ A \ A \ A \ A \ A \ A \ A \ A \ A \ A \ A \ A \ A \ A \ A A A A A A A A N Vl N A N W N N N r N O r l0 r 00 r V r Ol r In r A r W r N r r r O \\\\\\\\\ �O 0o V O1 l A w N r W O N LO N w N V N Ol N w N A N W N N N r N O r l0 r 00 r V r 01 r In r A r W r N r r r O \\\\\\\\ t0 0o V M vl A w N \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ N \ N \ N \ N \ N \ N \ N \ N \ N \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ N \ N \ \ N \ N \ \ \ OJ N N O N O N O N O N O N O N O N O N O N O N O N O N O N O N O Or Or Or Or Or Or O Or Or N N N N N N N N N N O N O N O N O N O N O N O N O N O N O N O N O Or Or N Or Or Or N O N O N O m pO r r V r V r V r V r r r r r r r r r r r VV r r r rrr r r rrrrr r V V r VVVV r r V V V V VV v N N A N N W N N A N W W W Pb W A N N N w A N A A N N W N "'' W N NN A N N A A w in V N A r N l0 r lO 00 lO U7 N N Ln r Ln Ln V l0 N N LO A V Ut r r A Ul N Ul Ol N CO c 3 �o 1 v r+ �o W N A N A A N A A N A N A N A A A A N A N A A N A N A N A A A N N N N A A N A A A A N A N A A A A A A N A N 111 L l N w y N Ul y y y N y N y N y W Ul N Ul Lrl Ul Ul N w N In Ol V l0 N lrl to N vl N ul N ul W W N Vl N Ul N Ln N M N In w N l!1 y y y O O O O O A O O O O O O A O O O O O O O O O O O O O O O O O O O O O O A O O O O C Z 3 = r Ul O 00 r A r Ul r N O w r A N 00 O Ol r WAO O Ul r N r (n r V r O) r W O W O l0 r r ~' r N r NW O r M r V r W O %a O M00 O O Ol O V O 00 O 00 O 00 A fD Z 1 Z cZ G 7 f0 7 T m d A A W N r l0 A ~' 0 A r �' W A A N r r A A r N l!7 A r V A A r r A A In A A W N Ol A A m O r r W w w r r r r r r r A r O 3 Date BODS (Summer) BODS (Winter) TSS NH3-N (Summer) NH3-N (Winter) Fecal Coliform 5/26/2017 29 Q.5 Oil < 1 5/27/2017 5/28/2017 5/29/2017 5/30/2017 2.5 <2.5 012 < 1 5/31/2017 3.3 <2 5 009 < 1 6/1/2017 2.9 <25 0 1 2 6/2/2017 2.1 < 2 5 008 1 6/3/2017 6/4/2017 6/5/2017 28 < 2.5 016 4 6/6/2017 21 < 2 5 0.34 < 1 6/7/2017 < 2 < 2.5 < 0.04 1 6/8/2017 < 2 < 2.5 0.11 2 6/9/2017 < 2 < 2 5 0.06 < 1 6/10/2017 6/11/2017 6/12/2017 24 < 2.5 009 1 6/13/2017 < 2 < 2.5 01 < 1 6/14/2017 < 2 < 2.5 018 < 1 6/15/2017 < 2 < 2.5 021 < 1 6/16/2017 < 2 < 2.5 014 < 1 6/17/2017 6/18/2017 6/19/2017 < 2 < 2.5 0.09 4 6/20/2017 < 2 < 2 5 0.04 2 6/21/2017 < 2 < 2 5 0.08 2 6/22/2017 < 2 27 0.13 1 6/23/2017 3.5 < 2 5 0.17 < 1 6/24/2017 6/25/2017 6/26/2017 < 2 < 2.5 0.11 < 1 6/27/2017 < 2 < 2.5 0.06 < 1 6/28/2017 < 2 < 2.5 0.06 4 6/29/2017 < 2 < 2.5 0.07 < 1 6/30/2017 < 2 < 2.5 0.07 < 1 7/1/2017 7/2/2017 7/3/2017 < 2 < 2 5 0.09 1 7/4/2017 7/5/2017 < 2 < 2 5 007 3 7/6/2017 < 2 < 2 5 006 1 7/7/2017 < 2 < 2 5 01 < 1 7/8/2017 7/9/2017 7/10/2017 < 2 < 2.5 01 1 7/11/2017 < 2 < 2 5 006 < 1 7/12/2017 < 2 < 2 5 008 < 1 7/13/2017 < 2 < 2.5 007 1 7/14/2017 < 2 < 2 5 02 < 1 7/15/2017 7/16/2017 7/17/2017 < 2 < 2.5 0.13 < 1 7/18/2017 < 2 < 2 5 009 1 Date BODS (Summer) BODS (Winter) TSS NH3-N (Summer) NH3-N (Winter) Fecal Coliform 7/19/2017 < 2 <25 0 16 < 1 7/20/2017 < 2 < 2 5 007 < 1 7/21/2017 < 2 < 2 5 0.1 < 1 7/22/2017 7/23/2017 7/24/2017 < 2 < 2 5 01 6 7/25/2017 < 2 < 2 5 01 < 1 7/26/2017 < 2 < 2 5 009 < 1 7/27/2017 < 2 < 2 5 007 1 7/28/2017 < 2 < 2 5 007 < 1 7/29/2017 7/30/2017 7/31/2017 < 2 < 2.5 007 < 1 8/1/2017 < 2 < 2 5 007 < 1 8/2/2017 < 2 < 2 5 01 2 8/3/2017 < 2 < 2 5 008 1 8/4/2017 < 2 < 2.5 008 < 1 8/5/2017 8/6/2017 8/7/2017 37 < 2.5 014 2 8/8/2017 < 2 < 2.5 Oil 3 8/9/2017 < 2 < 2 5 0.07 1 8/10/2017 < 2 < 2 5 0.06 < 1 8/11/2017 < 2 < 2 5 < 0.04 1 8/12/2017 8/13/2017 8/14/2017 < 2 < 2 5 016 < 1 8/15/2017 < 2 28 0.06 < 1 8/16/2017 < 2 < 2 5 006 1 8/17/2017 < 2 < 2 5 008 1 8/18/2017 22 < 2 5 Oil 5 8/19/2017 8/20/2017 Date BODS (Summer) BODS (Winter) TSS NH3-NNH3-N (Summer) (Winter) Fecal Coliform 8/21/2017 < 2 < 2.5 0.08 8 8/22/2017 < 2 < 2 5 0.1 4 8/23/2017 < 2 < 2.5 008 34 8/24/2017 < 2 < 2.5 0.05 12 8/25/2017 < 2 < 2.5 0.05 6 8/26/2017 8/27/2017 8/28/2017 < 2 < 2.5 006 10 8/29/2017 < 2 < 2.5 < 0.04 15 8/30/2017 < 2 < 2 5 005 11 8/31/2017 < 2 < 2.5 0.05 4 9/1/2017 <2 <2.5 005 < 1 9/2/2017 9/3/2017 9/4/2017 9/5/2017 < 2 < 2 5 < 0 04 98 9/6/2017 < 2 < 2.5 < 0.04 40 9/7/2017 < 2 < 2.5 < 0.04 147 9/8/2017 <2 <2 5 005 80 9/9/2017 9/10/2017 9/11/2017 <2 <2 5 006 14 9/12/2017 < 2 < 2.5 0.08 12 9/13/2017 < 2 < 2 5 008 2 9/14/2017 <2 Q.5 009 2 9/15/2017 < 2 < 2 5 004 10 9/16/2017 9/17/2017 9/18/2017 <2 <2.5 0.05 9 9/19/2017 13 < 2 5 006 35 9/20/2017 49 Q.5 <0 04 20 9/21/2017 <2 <2 5 <0 04 6 9/22/2017 < 2 < 2 5 0.27 10 9/23/2017 9/24/2017 9/25/2017 <2 <2 5 014 3 9/26/2017 2.5 <2.5 009 9/27/2017 < 2 < 2 5 0.18 < 1 9/28/2017 <2 <2 5 0.06 < 1 9/29/2017 <2 <2 5 0.05 1 9/30/2017 Water Resources EN YIRONNEWAI. OUACITY January 03, 2018 Frank Bottorff City of Havelock PO Box 368 Havelock, NC 28532 Subject: Permit Renewal Application No. NCO021253 Havelock WWTP Craven County Dear Applicant: ROY COOPER CTMWMT MICHAEL S- REGAN swratmy LnMA CULPEPPER Aterhn Direcfw The Water Quality Permitting Section acknowledges the December 21, 2017 receipt of your permit renewal application and supporting documentation. Your application will be assigned to a permit writer within the Section's NPDES WW permitting branch. Per G.S. 15OB-3 your current permit does not expire until permit decision on the application is made. Continuation of the current permit is contingent on timely and sufficient application for renewal of the current permit. The permit writer will contact you if additional information is required to complete your permit renewal. Please respond in a timely manner to requests for additional information necessary to allow a complete review of the application and renewal of the permit. Information regarding the status of your renewal application can be found online using the Department of Environmental Quality's Environmental Application Tracker at: https://deq. nc.gov/permits-regulations/permit-g uidancelenvironmenta I -application -tracker If you have any additional questions about the permit, please contact the primary reviewer of the application using the links available within the Application Tracker. Sincerely, _3c w Wren Thedford Administrative Assistant Water Quality Permitting Section cc: Central Files w/application ec: WQPS Laserfiche File w/application State of North Carolina I Environmental Quality I Water Resources 1617 Mail Service Center I Raleigh, North Carolina 27699-1617 919-R07-6300