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HomeMy WebLinkAbout3404_ForsythCoKernersvilleWQMR_GWMR_DIN28654_20161221 7011 Albert Pick Road, Suite G | Greensboro, NC 27409 t: 336.605.3009 | f: 919.467.6008 | www.withersravenel.com | License No. C-0832 Cary | Greensboro | Pittsboro | Raleigh | Wilmington WithersRavenel Our People. Your Success. March 31, 2017 Ms. Jaclynne Drummond Compliance Hydrogeologist NC Department of Environment and Natural Resources Division of Waste Management –Solid Waste Section 2090 US Highway 70 Swannanoa, NC 28778 RE: December 2016 Water Quality Monitoring Report Town of Kernersville Landfill, Permit No. 34-04 Forsyth County, North Carolina WR Project No. 06140180.11 Dear Ms. Drummond: On behalf of the Town of Kernersville, WithersRavenel appreciates the opportunity to submit the attached December 2016 Water Quality Monitoring Report for the Town of Kernersville Closed Landfill, Permit No. 34-04. The attached report contains electronic versions of the complete report, appendices for the December 2016 sampling event, and historic data from the semiannual sampling events performed in 2015 and in July 2016. Also attached is the North Carolina Environmental Monitoring Reporting Form for the December 2016 monitoring event. Please contact me at 919.469.3340 or mbrown@withersravenel.com with comments, questions or requests. Sincerely WithersRavenel Attachment Copy to: Thad Buck –Town of Kernersville, Solid Waste Superintendent WithersRavenel Our People. Your Success. Page i of i TABLE OF CONTENTS 1.0 INTRODUCTION .............................................................................................................................................. 1 1.1 Site Information ............................................................................................................................................. 1 1.2 Site Geology and Hydrogeology .............................................................................................................. 1 1.3 Regulatory Status ......................................................................................................................................... 1 2.0 FACILITY MONITORING PROGRAM ....................................................................................................... 2 2.1 Groundwater Monitoring Program ........................................................................................................ 2 2.2 Surface Water Monitoring Program ...................................................................................................... 2 3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2016 ...................................................................... 3 3.1 Field Services .................................................................................................................................................. 3 3.2 Quality Control .............................................................................................................................................. 4 4.0 ANALYTICAL RESULTS .................................................................................................................................. 4 4.1 Groundwater .................................................................................................................................................. 4 4.2 Surface Water ................................................................................................................................................ 4 5.0 EVALUATION OF MONITORED NATURAL ATTENUATION (MNA) ........................................... 5 5.1 MNA Parameters .......................................................................................................................................... 5 5.2 Biodegradation Screening Matrix ........................................................................................................... 6 6.0 FINDINGS ............................................................................................................................................................ 6 7.0 REFERENCES ...................................................................................................................................................... 7 Figures Figure 1 General Location Map Figure 2 Monitoring Well Location Map Figure 3A Potentiometric Map July 2016 Figure 3B Potentiometric Map December 2016 Figure 4 Groundwater 2L/GWP Exceedances Tables Table 1 Monitoring Well Construction Details Table 2 Groundwater Surface Elevations Table 3 Historical Groundwater Elevations Table 4 Groundwater Analytical Results Table 5 Surface Water Analytical Results Table 6 Summary of MNA Constituents Appendices Appendix I Laboratory Analytical Reports and Field Data Logs Appendix II Historical Summary Tables (reproduced from Joyce Reports) Table 1A Summary of Historical Groundwater Elevations Table 1B Monitoring Well and Boring Completion Summary Table 2 Summary of Estimated Hydraulic Gradient and Linear Velocity Table 3 Summary of Historical Groundwater Constituents Table 4 Summary of Historical Surface Water Constituents Table 5 Summary of MNA Constituents Table 6 MNA Screening Matrix WithersRavenel Our People. Your Success. Second Semiannual Water Quality Report WR Project Number 06140180.11 Town of Kernersville Closed Landfill, Permit 34-04 March 2017 Page 1 of 7 1.0 INTRODUCTION 1.1 Site Information The Town of Kernersville Landfill is a closed, unlined municipal solid waste landfill located on approximately 58.2 acres in Forsyth and Guilford Counties, NC, approximately 10 miles north of the City of Kernersville. The waste disposal area comprises approximately 13.8 acres. Figure 1, General Location Map illustrates the general location of the landfill on top of a 7.5 minute United States Geologic Survey (USGS) topographic map for the Belews Creek, North Carolina quadrangle (quad). The facility was issued a Permit to Operate by the North Carolina Department of Waste Management (DWM) on May 15, 1985 and a letter of closure on December 10, 1991. The landfill is zoned residential/agricultural and is bounded on the east and west by open fields and woodlands. The landfill is bounded on the north by property owned by Waste Management and farther north by Freeman Road, and on the south by an unnamed tributary of Belews Creek. Figure 2, Water Quality Sampling Locations Map illustrates the property boundaries, waste disposal boundaries, monitoring well locations, and surface water sample locations. 1.2 Site Geology and Hydrogeology The Town of Kernersville Landfill is located in the Piedmont Physiographic Providence (Piedmont) of North Carolina and is underlain by intrusive granitic rocks of Pennsylvanian-to- Permian age which are part of the Charlotte Belt Geologic Unit. The uppermost aquifer is unconfined and includes both saprolite and fractured bedrock, which are well connected. Groundwater at the site has historically been reported flowing generally to the southwest. Joyce Engineering (JOYCE) conducted hydraulic conductivity testing in November 2013 and, using the modified Darcy equation (V=Ki/n), reported the following: • Hydraulic gradient (i) is 0.04 ft/ft; • An effective porosity value (n) of 30 percent was estimated; • Hydraulic conductivity (K) 1.73 ft/day: and • The calculated groundwater flow rate averaged approximately 0.20 ft/day. 1.3 Regulatory Status The Town of Kernersville(Town) is currently monitoring groundwater at the landfill in accordance with criteria set forth in Title 15A Subchapter 13B .0500 of the North Carolina Solid Waste Management Rules for municipal solid waste landfills (MSWLF) closed prior to October 9, 1993. Samples are analyzed for all constituents listed in 40 CFR Part 258, Appendix I Constituents for Detection Monitoring (“Appendix I”) and compared to the North Carolina Groundwater Quality Standards as listed in 15A NCAC 2L (the “2L Standards”), or, when a 2L Standard is not established, the Solid Waste Section’s Groundwater Protection Standards (GWPs). Based on the presence of targeted Appendix I constituents detected at concentrations above the referenced standards that could potentially be crossing the facility boundary, the North Carolina Department of Environment and Natural Resources (NCDENR), Solid Waste Section (Section) requested that the Town submit a Groundwater Assessment Plan to evaluate site conditions as they relate to groundwater quality. JOYCE submitted a Groundwater Assessment Report to the WithersRavenel Our People. Your Success. Second Semiannual Water Quality Report WR Project Number 06140180.11 Town of Kernersville Closed Landfill, Permit 34-04 March 2017 Page 2 of 7 Section on May 13, 2013, and concluded that, based on site hydrogeology, it would be very unlikely that the site impacts at concentrations above their respective standards would cross the property boundaries. In a July 16, 2013 response to information presented in the Groundwater Assessment Report, the Section determined that, despite the conclusions presented in JOYCE’s Groundwater Assessment Report, the detection of volatile organic compounds (VOCs) at concentrations that exceeded the referenced standards beyond the compliance boundary of the site constituted a violation of Section regulations. JOYCE submitted a Corrective Action Plan (CAP) on behalf of the Town in July 2014, which the Section approved on November 4, 2014. Note that the NCDENR is now doing business as the North Carolina Department of Environmental Quality (NCDEQ). 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program The current groundwater quality monitoring network consists of six monitoring wells, including one upgradient (background) well and five downgradient (compliance) wells. Monitoring well locations are illustrated on Figure 2. Monitoring well MW-6 currently serves as the background well for the facility. Former background well MW-1 was replaced (by MW-6) due to MW-1’s slow recharge, low well volumes or even being dry during sampling events. Downgradient monitoring wells MW-2, MW-3S, MW-3D, MW-4, and MW-5 are monitored for the Appendix I list of constituents as part of the compliance network for the facility. MW-1 is currently monitored for water levels only. Well construction parameters are presented in Table 1, Monitoring Well Construction Details. As a condition of the aforementioned CAP, monitoring wells MW-2, MW-3S, MW-3D, MW-4 and MW-6 are also monitored for the following Monitored Natural Attenuation (MNA) constituents; • Nitrate, sulfate, chloride, sulfide, alkalinity; • Total organic carbon (TOC); • Methane, ethane, and ethane • Volatile fatty acids; • Dissolved hydrogen; • Biological oxygen demand (BOD) and Chemical oxygen demand (COD). Groundwater samples collected semiannually are analyzed for the Appendix I list of constituents and for the above-referenced MNA parameters. Sample analyses are then compared to the 2L Standards or GWPs, where appropriate. 2.2 Surface Water Monitoring Program Surface water at the landfill is monitored semiannually in conjunction with the groundwater sampling events. Samples are collected from three surface water monitoring points (designated SW-1, SW-2, and SW-3). Surface water sample locations are also illustrated on Figure 2. These surface water monitoring points are summarized below, along with their current monitoring program status. WithersRavenel Our People. Your Success. Second Semiannual Water Quality Report WR Project Number 06140180.11 Town of Kernersville Closed Landfill, Permit 34-04 March 2017 Page 3 of 7 Surface Water Designation Classification SW-1 Upstream/Compliance SW-2 Compliance SW-3 Compliance Surface water samples are collected and analyzed for the Appendix I list of constituents during both semiannual monitoring events. Analytical results are compared to the Classifications and Water Quality Standards Applicable to Surface Waters and Wetlands of NC as listed in 15A NCAC 2B (2B Standards). 3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2016 3.1 Field Services On December 21, 2016, WithersRavenel (WR) personnel returned to the facility to purge and sample monitor wells MW-1, MW-2, MW-3S, MW-3D, MW-4, MW-5 and MW -6 and surface water sample locations SW-1, SW-2, and SW-3. Prior to purging each well, the depth to the static water level was measured with an electronic water level indicator accurate to 0.01 foot. Due to the volume of water encountered within the well, MW-1 was measured for a static water level only. Table 2, Groundwater Surface Elevations presents groundwater surface elevations calculated from static water levels recorded by WR personnel compared to top-of-well casing elevations reported by JOYCE in their 2015 reports. For comparison purposes, data reported during the Initial Semiannual Sampling Event (July 2016) is included in the tables, and illustrated on some of the figures. Figure 3A, Potentiometric Map (July 2016) illustrates estimated groundwater flow across the landfill site based on the reported groundwater surface elevations during the July 2016 sampling event. Figure 3B, Potentiometric Map (December 2016) illustrates estimated groundwater flow across the landfill site based on the reported groundwater surface elevations during the December 2016 sampling event. As shown on both figures, groundwater appears to be flowing in a southwesterly direction towards an unnamed tributary of Belews Creek. Table 3, Historical Groundwater Elevations presents groundwater surface elevations reported by JOYCE between 2009 and 2015, and by WR in 2016. The wells were purged and sampled using either disposable bailers or a peristaltic pump. Field parameters, including temperature, pH, specific conductivity, dissolved oxygen, oxidation reduction potential and turbidity, were recorded in the site-specific log book prior to purging, after each purge volume, and during sampling. Groundwater samples from each monitoring well were collected directly from a peristaltic pump into laboratory-cleaned and -provided containers or decanted from disposable bailers into the containers immediately after purging. Samples were then placed into laboratory-provided coolers, chilled on ice to approximately 40C, and delivered to a State of North Carolina-certified laboratory (Pace Laboratories) under standard Chain-of-Custody (COC) protocol. Field data logs are provided in the Appendix to this report. Surface water samples were collected either directly into laboratory-provided, non-preserved sample containers, or by decanting the sample from a non-preserved 1-liter amber glass container into the appropriate containers. In both methods, samples were collected with the container opening facing into the current flow. When used, care was taken to not overflow the preserved sample containers (which could lead to preservative loss) and avoid sample-induced turbidity. WithersRavenel Our People. Your Success. Second Semiannual Water Quality Report WR Project Number 06140180.11 Town of Kernersville Closed Landfill, Permit 34-04 March 2017 Page 4 of 7 Samples were collected initially from the downstream sample location (SW-2), and proceeding upstream, to sample location SW –3, and then to sample location SW-1. Again, surface water sample locations are depicted on Figure 2. After sample collection, the samples were placed in a laboratory-provided cooler, chilled on ice to approximately 40C, and submitted to Pace Laboratories under standard COC protocol. 3.2 Quality Control One Field Blank was collected by WR personnel as part of the December 2016 sampling event. Also, a Trip Blank was prepared by the laboratory to accompany the volatile sampling containers during shipment to and from the laboratory. The Field Blank was analyzed for the Appendix I list of constituents only, while the Trip Blank was analyzed for VOCs only. 4.0 ANALYTICAL RESULTS 4.1 Groundwater Groundwater samples were analyzed for the Appendix I list and the modified list of MNA constituents and compared to their respective 2L Standards or GWPs where appropriate. As shown on Table 4, Groundwater Analytical Results, the following organic and/or inorganic constituents were detected in groundwater samples during the December 2106 sampling event. All concentrations are reported in micrograms per liter (µg/L). Concentrations detected above the 2L Standard or GWPs are illustrated in “bold”. Figure 4, Groundwater Standard Exceedances Map illustrates exceedances to the referenced standards at the monitoring well locations. In general, the organic and inorganic results are consistent with historical data. Historical groundwater data, laboratory quality assurance/quality control information and the chain-of-custody records are included in the Appendix. 4.2 Surface Water Surface water samples were analyzed for the Appendix I list only. There were no constituents detected with concentrations at, or above, the 2B Standard in the surface water samples collected during the December 2016 sampling events. In general, the results are consistent with historical data. Surface water data can be found in Table 5, Surface Water Analytical Results. The results, as reported by the laboratory, historical surface water data, the laboratory quality/assurance/quality control information, and the chain-of-custody records are included in the Appendix. Constituent Referenced Standard Background Well Compliance Wells (2L/GWP) MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Benzene 1.0 <0.25 4.2 <0.25 <0.25 <0.25 <0.25 1,1,-Dichloroethane 6.0 <0.32 16.8 <0.32 <0.32 <0.32 <0.32 1,2-Dichloropropane 0.6 <0.27 4.0 <0.27 1.1 <0.27 <0.27 Trichloroethene 3 <0.47 4.2 <0.47 <0.47 <0.47 <0.47 Vinyl chloride 0.03 <0.62 3.2 2.2 8.2 14.5 <0.62 Vanadium 0.3 6.8 <2.5 31.6 <2.5 <2.5 7.0 WithersRavenel Our People. Your Success. Second Semiannual Water Quality Report WR Project Number 06140180.11 Town of Kernersville Closed Landfill, Permit 34-04 March 2017 Page 5 of 7 5.0 EVALUATION OF MONITORED NATURAL ATTENUATION (MNA) 5.1 MNA Parameters According to previous reports, in accordance with the facility CAP, MNA baseline sampling was initiated during the November 2014 sampling event and finished during the November 2015 sampling event. During those events, the full list of MNA parameters (shown below) were measured in samples collected from monitoring wells MW-2, MW-3S, MW-3D, and MW-4. MW- 6 was dry and was not sampled. MNA field (geochemical) parameters included: • Temperature; • pH; • specific conductance; • Oxidation reduction potential (ORP); • Turbidity; and • Dissolved oxygen. Laboratory parameters included: • Biological Oxygen Demand (BOD); • Chemical Oxygen Demand (COD); • Dissolved hydrogen; • Nitrate; • Sulfate: • Chloride; • Alkalinity; • Sulfide; • Total Organic Carbon (TOC); • Ethane, ethene, and methane; and • Volatile fatty acids. In response to the Corrective Action Evaluation Report (CAER) submitted by JOYCE in October 2016, the Section agreed to reduce the sampling frequency of several MNA parameters from semiannually (twice per year) to triannually (every three years). The MNA parameters reduced to triannual sampling, meaning they would be sampled again in 2019, included: • BOD; • COD; • Ethane, ethene, and methane; • Dissolved carbon dioxide; • Volatile fatty acids; and • Ferrous iron. As shown on Table 6, Summary of MNA Constituents, WR sampled for the full list of MNA parameters during the July 2016 sampling event but not during the December 2016 sampling event. Laboratory reports and field data forms are included in the Appendix. WithersRavenel Our People. Your Success. Second Semiannual Water Quality Report WR Project Number 06140180.11 Town of Kernersville Closed Landfill, Permit 34-04 March 2017 Page 6 of 7 5.2 Biodegradation Screening Matrix The MNA parameter data were evaluated in general accordance with the weighted system presented in Table 2.3, Biodegradation Screening Matrix (Matrix) of the United States Environmental Protection Agency’s (USEPA’s) Technical Protocol for Evaluation of Natural Attenuation of Chlorinated Solvents in Groundwater, (Manual) to determine whether the conditions are conducive to, or whether there is evidence of, anaerobic degradation of the chlorinated hydrocarbons. According to information presented in the Manual, • A score less than 5 indicates that there is “inadequate evidence” for anaerobic natural attenuation; • A score of 6 to 14 indicates that there is “limited evidence” for anaerobic natural attenuation; • A score of 15 to 19 indicates that there is “adequate evidence” for anaerobic natural attenuation; and • A score of 20 or more indicates that there is “strong evidence” that anaerobic natural attenuation is occurring. The MNA evaluation was performed based on the results from the December 2016 sampling event for downgradient wells located within the contaminant plume and compared, where appropriate, to samples collected from the background well (MW-6). Because it is unclear whether some of the target analytes are naturally-occurring or daughter products resulting from natural attenuation, the scores have been calculated with and without the daughter product points. The site-specific Matrix for this sampling event is presented in the Appendix. As shown, the scores ranged from 12 to 24 (characterized as “limited evidence of natural attenuation” to “strong evidence of natural attenuation”). The mid-range (or average score of 18), indicates there is “adequate evidence of natural attenuation”. 6.0 FINDINGS Target analytes detected above their respective 2L Standards and/or GWPs in groundwater samples collected during the December 2016 sampling event appear to generally be consistent with previous events. In addition, there were no target analytes detected in the surface water samples at concentrations above their respective 2B Standards. The Town of Kernersville Landfill will continue to monitor groundwater in accordance with the approved CAP. The next semiannual sampling event is tentatively scheduled for July 2017. WithersRavenel Our People. Your Success. Second Semiannual Water Quality Report WR Project Number 06140180.11 Town of Kernersville Closed Landfill, Permit 34-04 March 2017 Page 7 of 7 7.0 REFERENCES Brown, Philip M., Chief Geologist, 1985, Geologic Map of North Carolina, The North Carolina Geologic Survey, scale 1:500,000. Joyce Engineering, Inc. Water Quality Monitoring Plan, Piedmont Landfill & Recycling Center, September 2010. -----, Second Semiannual Water Quality Monitoring Report of 2014, Town of Kernersville Landfill, Permit 34-04, March 2015. -----, Second Semiannual Water Quality Monitoring Report of 2015, Town of Kernersville Landfill, Permit 34-04, March 2016. -----, Corrective Action Evaluation Report (CAER), Town of Kernersville Landfill, Permit 34-04, October 16, 2016. North Carolina Department of Environment and Natural Resources, 2016 Solid Waste Section Guidelines for Groundwater, Soil and Surface Water Sampling. -----, MNA Excerpt from Examples of Approved Groundwater Corrective Measures for Solid Waste Management Facilities, 2008. Technical Protocol for Evaluation Natural Attenuation of Chlorinated Solvents in Groundwater, EPA/600/R-98/128, September 1998. United States Geological Survey, 7.5-Minute Quadrangle, Belews Creek, North Carolina. FIGURES WASTE DISPOSAL BOUNDARY FORSYTH COUNTYGUILFORD COUNTYMDF SMB DRAWN BY: 10/18/2016 06140180.11 1 FACILITY BOUNDARY SCALE:FIGURE NO.: PROJECT NO.:DATE:APPROVED BY: GENERAL LOCATION MAP WithersRavenel Engineers | Planners | Surveyors 115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340 | license #: C-0832 | www.withersravenel.com 1"=1000 ' GRAPHIC SCALE 1 inch = 1000 ft. 0 1000500 2000 TOWN OF KERNERSVILLE CLOSED LANDFILL - PERMIT #34-04 GOODWILL CHURCH ROAD KERNERSVILLE, GUILFORD/FORSYTH COUNTY, NC TABLES 1 of 1 Well ID Date Installed Well Casing Diameter (Inches) Casing Depth (ft-bTOC) Screen Interval (ft-bTOC) Total Depth (ft-bTOC) Top of Casing Elevation (feet above MSL) MW-1 Not Listed 2 24.96 24.96 - 34.96 34.96 806.42 MW-2R Not Listed 2 3.18 3.18 - 13.18 13.18 762.19 MW-3S Not Listed 2 14.00 14.00 - 24.00 24.00 764.57 MW-3D Not Listed 2 36.96 36.96 - 56.96 56.96 764.56 MW-4 Not Listed 2 4.40 4.40 - 14.40 14.40 760.26 MW-5 Not Listed 2 6.36 6.36 - 11.36 11.36 773.32 MW-6 Not Listed 2 10.46 10.46 - 20.46 20.46 804.87 Notes: 1)ft-bTOC = Feet below top of casing 2)MSL = Mean sea level 3) WR Project # 06140180.11 Data, including "Top of Casing Elevation", reproduced from Second Semiannual Water Quality Monitoring Report of 2014; Joyce Engineering; March 10, 2015. TABLE 1 MONITORING WELL CONSTRUCTION DETAILS TOWN OF KERNERSVILLE LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA 1 of 1 DEPTH TO WATER (ft-bTOC) GROUNDWATER SURFACE ELEVATION (feet above MSL) DEPTH TO WATER (ft-bTOC) GROUNDWATER SURFACE ELEVATION (feet above MSL) MW-1 24.96 - 34.96 806.42 33.91 772.51 34.47 771.95 MW-2R 3.18 - 13.18 762.19 4.01 758.18 3.85 758.34 MW-3S 14.00 - 24.00 764.57 14.04 750.53 14.00 750.57 MW-3D 36.96 - 56.96 764.56 12.32 752.24 12.46 752.10 MW-4 4.40 - 14.40 760.26 7.00 753.26 7.00 753.26 MW-5 6.36 - 11.36 773.32 11.36 761.96 3.41 769.91 MW-6 10.46 - 20.46 804.87 20.46 784.41 20.22 784.65 Notes: 1)All measurements are in feet. 2)Elevation data is measured in feet above Mean Sea Level (MSL). 3)Depth to water measured in feet below top of casing (ft-bTOC) 4)"Screened Interval" and "Top of Casing Elevation" components are reproduced from Second Semiannual Water Quality Monitoring Report of 2014; Joyce Engineering; March 10, 2015. WR Project # 06140180.11 7/29/2016 TABLE 2 GROUNDWATER SURFACE ELEVATIONS TOWN OF KERNERSVILLE LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA 12/22/2016 SCREENED INTERVAL (ft-bTOC) TOP OF CASING ELEVATION (feet above MSL) WELL ID 1 of 2 12/30/2009 33.97 772.45 6/1/2010 32.97 773.45 11/16/2010 32.87 773.55 12/29/2010 33.13 773.29 6/29/2011 33.32 773.10 11/1/2011 34.50 771.92 5/1/2012 34.54 771.88 11/7/2012 34.77 771.65 5/9/2013 36.47 769.95 11/7/2013 34.96 771.46 6/5/2014 34.20 772.22 11/20/2014 34.69 771.73 7/29/2016 33.91 772.51 12/21/2016 34.47 771.95 12/30/2009 3.03 759.16 6/1/2010 3.29 758.90 11/16/2010 3.05 759.14 12/29/2010 3.36 758.83 6/29/2011 3.81 758.38 11/1/2011 3.70 758.49 5/1/2012 3.65 758.54 11/7/2012 3.99 758.20 5/9/2013 2.99 759.20 11/7/2013 4.10 758.09 6/5/2014 3.74 758.45 11/20/2014 4.11 758.08 7/29/2016 4.01 758.18 12/21/2016 3.85 758.34 12/30/2009 13.03 751.54 6/1/2010 13.81 750.76 11/16/2010 13.59 750.98 12/29/2010 14.75 749.82 6/29/2011 14.03 750.54 11/1/2011 9.84 754.73 5/1/2012 13.71 750.86 11/7/2012 14.27 750.30 5/9/2013 12.05 752.52 11/7/2013 14.45 750.12 6/5/2014 13.90 750.67 11/20/2014 14.33 750.24 7/29/2016 14.04 750.53 12/21/2016 14.00 750.57 12/30/2009 11.77 752.79 6/1/2010 11.93 752.63 11/16/2010 11.97 752.59 12/29/2010 12.11 752.45 6/29/2011 12.40 752.16 11/1/2011 12.66 751.90 5/1/2012 12.22 752.34 11/7/2012 12.95 751.61 5/9/2013 11.32 753.24 11/7/2013 13.06 751.50 6/5/2014 12.42 752.14 11/20/2014 13.03 751.53 7/29/2016 12.32 752.24 12/21/2016 12.46 752.10 Notes: All measurements are in feet. Elevation data is relative to Mean Sea Level. Depth to water measured in feet below top of casing. NM = Not Measured NA = Not Applicable NS = Not surveyed MW-3D 764.56 MW-3S 764.57 MW-2 762.19 MW-1 806.42 WELL ID Top of Casing Elevation (feet)Date Depth to Groundwater (feet) Groundwater Elevation (feet) KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.11 TOWN OF KERNERSVILLE LANDFILL PERMIT #: 34-04 TABLE 3 HISTORICAL GROUNDWATER ELEVATIONS 2 of 2 12/30/2009 5.93 754.33 6/1/2010 6.36 753.90 11/16/2010 6.52 753.74 12/29/2010 6.58 753.68 6/29/2011 6.85 753.41 11/1/2011 7.18 753.08 5/1/2012 6.71 753.55 11/7/2012 7.39 752.87 5/9/2013 5.82 754.44 11/7/2013 7.47 752.79 6/5/2014 6.90 753.36 11/20/2014 7.45 752.81 7/29/2016 7.00 753.26 12/21/2016 7.00 753.26 12/30/2009 4.11 769.21 6/1/2010 3.63 769.69 11/16/2010 3.51 769.81 12/29/2010 3.76 769.56 6/29/2011 3.59 769.73 11/1/2011 3.69 769.63 5/1/2012 3.77 769.55 11/7/2012 4.75 768.57 5/9/2013 NM NM 11/7/2013 5.19 768.13 6/5/2014 4.75 768.57 11/20/2014 4.09 769.23 7/29/2016 11.36 761.96 12/21/2016 3.41 769.91 12/30/2009 18.21 786.66 6/1/2010 16.55 788.32 11/16/2010 16.94 787.93 12/29/2010 17.50 787.37 6/29/2011 18.06 786.81 11/1/2011 19.77 785.10 5/1/2012 19.55 785.32 11/7/2012 DRY DRY 5/9/2013 17.31 787.56 11/7/2013 DRY DRY 6/5/2014 19.03 785.84 11/20/2014 20.46 784.41 7/29/2016 20.46 784.41 12/21/2016 20.22 784.65 Notes: All measurements are in feet. Elevation data is relative to Mean Sea Level. Depth to water measured in feet below top of casing. NM = Not Measured NA = Not Applicable NS = Not surveyed MW-6 804.87 MW-5 773.32 MW-4 760.26 Top of Casing Elevation (feet)Date Depth to Groundwater (feet) Groundwater Elevation (feet)WELL ID KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.11 TOWN OF KERNERSVILLE LANDFILL PERMIT #: 34-04 TABLE 3 HISTORICAL GROUNDWATER ELEVATIONS TABLE 4 GROUNDWATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE PERMIT # 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.11 Page 1 of 5 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual 7/29/2016 <3.8 <2.5 292 <0.5 <0.5 <2.5 <2.5 <2.5 <2.5 <2.5 <5 <2.5 <5 <2.5 <5 12/21/2016 <3.8 <2.5 262 <0.5 <0.5 <2.5 <2.5 <2.5 <2.5 <2.5 <5 <2.5 <5 <2.5 <5 7/29/2016 <3.8 <2.5 115 <0.5 <0.5 <2.5 <2.5 <2.5 <2.5 <2.5 <5 <2.5 <5 <2.5 <5 12/21/2016 <3.8 <2.5 91.4 <0.5 <0.5 <2.5 <2.5 <2.5 <2.5 <2.5 <5 <2.5 <5 <2.5 <5 EXTRA*7/29/2016 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA DUPLICATE **7/29/2016 <3.8 <2.5 170 <0.5 1.9 12.9 5.1 14.5 <2.5 6.0 <5 <2.5 <5 31.6 314 7/29/2016 <3.8 <2.5 40.9 <0.5 <0.5 <2.5 <2.5 <2.5 <2.5 <2.5 <5 <2.5 <5 <2.5 <5 12/21/2016 <3.8 <2.5 41.2 <0.5 <0.5 <2.5 <2.5 <2.5 <2.5 <2.5 <5 <2.5 <5 <2.5 <5 7/29/2016 <3.8 <2.5 92.6 <0.5 <0.5 5.2 <2.5 <2.5 <2.5 <2.5 <5 <2.5 <5 <2.5 <5 12/21/2016 <3.8 <2.5 <2.5 <0.5 <0.5 <2.5 <2.5 <2.5 <2.5 <2.5 <5 <2.5 <5 <2.5 <5 7/29/2016 <3.8 <2.5 108 <0.5 <0.5 6 11.2 19.9 17.5 <2.5 <5 <2.5 <5 24.7 46.6 12/22/2016 <3.8 <2.5 58.6 <0.5 <0.5 <2.5 <2.5 <2.5 <2.5 <2.5 <5 <2.5 <5 <2.5 13.4 Duplicate ***12/22/2016 <3.8 <2.5 110 <0.5 <0.5 <2.5 <2.5 <2.5 5 <2.5 <5 <2.5 <5 7 16 7/29/2016 <3.8 <2.5 146 <0.5 <0.5 5.8 <2.5 <2.5 12.6 <2.5 <5 <2.5 <5 16.8 25.1 12/22/2016 <3.8 <2.5 108 <0.5 <0.5 <2.5 <2.5 <2.5 6 <2.5 <5 <2.5 <5 6.8 14.3 Trip Blank 7/29/2016 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Field Blank 12/22/2016 <3.8 <2.5 <2.5 <0.5 <0.5 <2.5 <2.5 <2.5 <2.5 <2.5 <5 <2.5 <5 <2.5 13.3 Notes: 1)All results provided in µg/L (micrograms per liter) or parts per billion * =Laboratory blind duplicated sample of MW-3S 2)2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L **=Laboratory blind duplicated sample of MW-3S 3)Interim Maximum Allowable Concentration (IMAC)***=Laboratory blind duplicated sample of MW-5 4)GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5)NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6)Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. Qualifiers H1=Analysis conducted outside the EPA method holding time. NA Not Analyzed by Method Shown M1=Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample recovery. Result Result Exceeds 2L Standard or GWP N2=The lab does not hold TNI accreditation for this parameter. D3=Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.Cadmium7440-43-9 Chromium7440-47-3 Thallium7440-28-0CAS #Nickel7440-02-0 Selenium7782-49-2 Silver7440-22-4Cobalt7440-48-4 Copper7440-50-8 Lead7439-92-1BerylliumContaminant Of Concern Analytical Method MW-2 Antimony7440-36-0 Arsenic7440-38-2 Barium7440-39-3 7440-41-7 1 3 10 700 4 3 2 10 1 3 1,000 15 100 20 20 0.2 MW-6 2L Standard/GWP (µg/L) MW-3S MW-3D MW-4 MW-5 VanadiumZinc7440-62-2 7440-66-6 0.3 3 1,000 EPA 6010 TABLE 4 GROUNDWATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE PERMIT # 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.11 Page 2 of 5 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual 7/29/2016 <10 <1.9 4.2 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 12/21/2016 <10 <1.9 4.2 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 7/29/2016 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 12/21/2016 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 1.1 <0.54 <0.14 EXTRA*7/29/2016 NA NA NA NA NA NA NA NA NA NA NA NA NA DUPLICATE **7/29/2016 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 7/29/2016 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 12/21/2016 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 7/29/2016 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 12/21/2016 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 7/29/2016 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 12/22/2016 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 Duplicate ***12/22/2016 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 7/29/2016 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 12/22/2016 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 Trip Blank 7/29/2016 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 Field Blank 12/22/2016 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 Notes: 1)All results provided in µg/L (micrograms per liter) or parts per billion * =Laboratory blind duplicated sample of MW-3S 2)2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L **=Laboratory blind duplicated sample of MW-3S 3)Interim Maximum Allowable Concentration (IMAC)***=Laboratory blind duplicated sample of MW-5 4)GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5)NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6)Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. Qualifiers H1=Analysis conducted outside the EPA method holding time. NA Not Analyzed by Method Shown M1=Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample recovery. Result Result Exceeds 2L Standard or GWP N2=The lab does not hold TNI accreditation for this parameter. D3=Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. NE 1 0.6 4 0.6 4 100 4,000AcetoneAcrylonitrileBenzene67-64-1 107-13-1 71-43-2 BromochloromethaneBromodichloromethaneBromoformBromomethane74-97-5 75-27-4 75-25-2 74-83-9 56-23-5 ChloroformCarbon tetrachlorideChloroethaneChlorobenzeneCarbon disulfide67-66-375-00-3108-90-778-93-3 75-15-02-Butanone (MEK)Analytical Method Contaminant Of Concern CAS # 2L Standard/GWP (µg/L) EPA 8260 706,000 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6 700 0.3 50 3,000 TABLE 4 GROUNDWATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE PERMIT # 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.11 Page 3 of 5 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual 7/29/2016 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 3.8 <1.0 15.7 <0.24 <0.56 34.3 1.1 12/21/2016 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 3.8 <1.0 16.8 <0.24 <0.56 37.2 1.2 7/29/2016 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 1.7 <1.0 <0.32 <0.24 <0.56 7.1 <0.49 12/21/2016 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 1.8 <1.0 <0.32 <0.24 <0.56 7.3 <0.49 EXTRA*7/29/2016 NA NA NA NA NA NA NA NA NA NA NA NA NA DUPLICATE **7/29/2016 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 1.5 <1.0 <0.32 <0.24 <0.56 7.3 <0.49 7/29/2016 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 3.5 <1.0 2.7 <0.24 <0.56 45.7 <0.49 12/21/2016 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 3.7 <1.0 2.8 <0.24 <0.56 48.5 <0.49 7/29/2016 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 2.1 <1.0 1.9 <0.24 <0.56 16.4 <0.49 12/21/2016 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 2.2 <1.0 2 <0.24 <0.56 18.2 <0.49 7/29/2016 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 <0.32 <0.24 <0.56 <0.19 <0.49 12/22/2016 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 <0.32 <0.24 <0.56 <0.19 <0.49 Duplicate ***12/22/2016 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 <0.32 <0.24 <0.56 <0.19 <0.49 7/29/2016 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 <0.32 <0.24 <0.56 <0.19 <0.49 12/22/2016 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 <0.32 <0.24 <0.56 <0.19 <0.49 Trip Blank 7/29/2016 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 <0.32 <0.24 <0.56 <0.19 <0.49 Field Blank 12/22/2016 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 <0.32 <0.24 <0.56 <0.19 <0.49 Notes: 1)All results provided in µg/L (micrograms per liter) or parts per billion * =Laboratory blind duplicated sample of MW-3S 2)2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L **=Laboratory blind duplicated sample of MW-3S 3)Interim Maximum Allowable Concentration (IMAC)***=Laboratory blind duplicated sample of MW-5 4)GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5)NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6)Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. Qualifiers H1=Analysis conducted outside the EPA method holding time. NA Not Analyzed by Method Shown M1=Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample recovery. Result Result Exceeds 2L Standard or GWP N2=The lab does not hold TNI accreditation for this parameter. D3=Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.1,4-DichlorobenzeneChloromethane1,2-Dibromo-3-chloropropaneContaminant Of Concern CAS #124-48-1 106-93-4 74-95-3 95-50-1 106-46-7 110-57-6 75-34-3 107-06-2 75-35-4 156-59-2 156-60-5trans-1,2-Dichloroethene1,2-Dichloroethane70 20 6 NE0.4 0.022L Standard/GWP (µg/L)0.04 Analytical Method trans-1,4-Dichloro-2-butene1,1-DichloroethaneEPA 8260 96-12-874-87-3 1,1-Dichloroethenecis-1,2-DichloroetheneDibromochloromethane1,2-Dibromoethane (EDB)Dibromomethane1,2-Dichlorobenzene3 1006770 MW-3S MW-3D MW-4 MW-5 MW-6 0.4 MW-2 TABLE 4 GROUNDWATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE PERMIT # 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.11 Page 4 of 5 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual 7/29/2016 3.6 <0.13 <0.26 <0.3 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 12/21/2016 4.0 <0.13 <0.26 <0.3 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 7/29/2016 <0.27 <0.13 <0.26 <0.3 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 12/21/2016 <0.27 <0.13 <0.26 <0.3 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 EXTRA*7/29/2016 NA NA NA NA NA NA NA NA NA NA NA NA NA DUPLICATE **7/29/2016 <1.0 <0.13 <0.26 <0.3 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 7/29/2016 1.1 <0.13 <0.26 <0.3 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 12/21/2016 1.1 <0.13 <0.26 <0.3 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 7/29/2016 <0.27 <0.13 <0.26 <0.3 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 12/21/2016 <0.27 <0.13 <0.26 <0.3 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 7/29/2016 <0.27 <0.13 <0.26 <0.3 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 12/22/2016 <0.27 <0.13 <0.26 <0.3 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 Duplicate ***12/22/2016 <0.27 <0.13 <0.26 <0.3 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 7/29/2016 <0.27 <0.13 <0.26 <0.3 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 12/22/2016 <0.27 <0.13 <0.26 <0.3 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 Trip Blank 7/29/2016 <0.27 <0.13 <0.26 <0.3 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 Field Blank 12/22/2016 <0.27 <0.13 <0.26 <0.3 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 Notes: 1)All results provided in µg/L (micrograms per liter) or parts per billion * =Laboratory blind duplicated sample of MW-3S 2)2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L **=Laboratory blind duplicated sample of MW-3S 3)Interim Maximum Allowable Concentration (IMAC)***=Laboratory blind duplicated sample of MW-5 4)GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5)NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6)Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. Qualifiers H1=Analysis conducted outside the EPA method holding time. NA Not Analyzed by Method Shown M1=Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample recovery. Result Result Exceeds 2L Standard or GWP N2=The lab does not hold TNI accreditation for this parameter. D3=Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.Methylene Chloride4-Methyl-2-pentanone (MIBKStyrene1,1,1,2-Tetrachloroethane2-Hexanone10061-02-6 100-41-4 591-78-6 100 70 1,1,2,2-TetrachloroethaneTetrachloroetheneToluene79-34-5 127-18-4 108-88-3 EPA 8260 74-88-4 0.4 600trans-1,3-DichloropropeneEthylbenzeneMW-2 MW-3S MW-3D MW-4 MW-5 MW-6 IodomethaneAnalytical Method Contaminant Of Concern CAS # 2L Standard/GWP (µg/L)1 0.2 6000.740NE5 75-09-2 108-10-1 100-42-5 630-20-61,2-Dichloropropanecis-1,3-Dichloropropene78-87-5 10061-01-5 0.6 0.4 TABLE 4 GROUNDWATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE PERMIT # 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.11 Page 5 of 5 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual 7/29/2016 <0.48 <0.29 4.0 <0.2 <0.41 <0.35 4.0 <0.66 12/21/2016 <0.48 <0.29 4.2 <0.2 <0.41 <0.35 3.2 <0.66 7/29/2016 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 2.4 <0.66 12/21/2016 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 2.2 <0.66 EXTRA*7/29/2016 NA NA NA NA NA NA NA NA DUPLICATE **7/29/2016 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 2.6 <0.66 7/29/2016 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 6.6 <0.66 12/21/2016 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 8.2 <0.66 7/29/2016 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 14.9 <0.66 12/21/2016 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 14.5 <0.66 7/29/2016 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 <0.62 <0.66 12/22/2016 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 <0.62 <0.66 Duplicate ***12/22/2016 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 <0.62 <0.66 7/29/2016 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 <0.62 <0.66 12/22/2016 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 <0.62 <0.66 Trip Blank 7/29/2016 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 <0.62 <0.66 Field Blank 12/22/2016 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 <0.62 <0.66 Notes: 1)All results provided in µg/L (micrograms per liter) or parts per billion * =Laboratory blind duplicated sample of MW-3S 2)2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L **=Laboratory blind duplicated sample of MW-3S 3)Interim Maximum Allowable Concentration (IMAC)***=Laboratory blind duplicated sample of MW-5 4)GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5)NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6)Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. Qualifiers H1=Analysis conducted outside the EPA method holding time. NA Not Analyzed by Method Shown M1=Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample recovery. Result Result Exceeds 2L Standard or GWP N2=The lab does not hold TNI accreditation for this parameter. D3=Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.Xylene (Total)96-18-4 108-05-4 75-01-4 1330-20-7CAS #1,2,3-TrichloropropaneVinyl acetateContaminant Of Concern Analytical Method Vinyl chloride0.005 88 MW-6 2L Standard/GWP (µg/L)0.03 500 71-55-6 79-00-5 MW-2 MW-3S MW-3D MW-4 MW-5 200 0.6 EPA 8260 TrichloroetheneTrichlorofluoromethane79-01-6 75-69-4 3 2,0001,1,1-Trichloroethane1,1,2-Trichloroethane Page 1 of 4 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual 7/29/2016 <3.8 <2.5 33.7 <0.5 <0.5 <2.5 <2.5 <2.5 <2.5 <2.5 <5 <2.5 <5 <2.5 <5 12/21/2016 <3.8 <2.5 29.3 <0.5 <0.5 <2.5 <2.5 <2.5 <2.5 <2.5 <5 <2.5 <5 <2.5 <5 7/29/2016 <3.8 <2.5 39.1 <0.5 <0.5 <2.5 <2.5 <2.5 <2.5 <2.5 <5 <2.5 <5 <2.5 <5 12/21/2016 <3.8 <2.5 31.0 <0.5 <0.5 <2.5 <2.5 <2.5 <2.5 <2.5 <5 <2.5 <5 <2.5 <5 7/29/2016 <3.8 <2.5 37.9 <0.5 <0.5 <2.5 <2.5 <2.5 <2.5 <2.5 <5 <2.5 <5 <2.5 <5 12/21/2016 <3.8 <2.5 36.4 <0.5 <0.5 <2.5 <2.5 <2.5 <2.5 <2.5 <5 <2.5 <5 <2.5 <5 Notes: 1)All results provided in µg/L (micrograms per liter) or parts per billion 2)2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3)Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown Result Result Exceeds 2B Standard 2B Standard (µg/L)NE 10 SW-2 0.54 16 5 0.06 NE200,000 6.5 0.15 11 NE 2.7 SW-3 SW-1 7440-02-0 7782-49-2 7440-22-4 7440-28-07440-41-7 7440-43-9 7440-47-3 7440-48-4 7440-50-8 7439-92-1 7440-62-2 7440-66-6CAS #7440-36-0 7440-38-2 7440-39-3 Analytical Method SeleniumSilverThalliumCadmiumChromiumCobaltCopperLeadNickelVanadiumZincEPA 6010 EPA 6010 Contaminant Of Concern AntimonyArsenicBariumBerylliumNE 36 TABLE 5 SURFACE WATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.11 Page 2 of 4 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual 7/29/2016 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 <0.11 <2.0 12/21/2016 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 <0.11 <2.0 7/29/2016 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 <0.11 <2.0 12/21/2016 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 <0.11 <2.0 7/29/2016 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 <0.11 <2.0 12/21/2016 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 <0.11 <2.0 Notes: 1)All results provided in µg/L (micrograms per liter) or parts per billion 2)2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3)Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown Result Result Exceeds 2B Standard 140 NE NENENE1.6NENE51NE SW-2 2B Standard (µg/L)NE NE NE SW-3 SW-1 75-00-3 67-66-375-15-0 56-23-5 108-90-767-64-1 107-13-1 71-43-2 74-97-5 75-27-4CAS #ChloroformContaminant Of Concern Bromomethane2-Butanone (MEK)Carbon disulfideCarbon tetrachlorideChlorobenzeneChloroethaneAcetoneAnalytical Method EPA 8260 Chloromethane1,2-Dibromo-3-chloropropane74-87-3 96-12-8 NE NEAcrylonitrileBenzeneBromochloromethaneBromodichloromethaneBromoform75-25-2 74-83-9 78-93-3 TABLE 5 SURFACE WATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.11 Page 3 of 4 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual 7/29/2016 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 <0.32 <0.24 <0.56 <0.19 <0.49 <0.27 <0.13 <0.26 <0.3 12/21/2016 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 <0.32 <0.24 <0.56 <0.19 <0.49 <0.27 <0.13 <0.26 <0.3 7/29/2016 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 <0.32 <0.24 <0.56 <0.19 <0.49 <0.27 <0.13 <0.26 <0.3 12/21/2016 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 <0.32 <0.24 <0.56 <0.19 <0.49 <0.27 <0.13 <0.26 <0.3 7/29/2016 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 <0.32 <0.24 <0.56 <0.19 <0.49 <0.27 <0.13 <0.26 <0.3 12/21/2016 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 <0.32 <0.24 <0.56 <0.19 <0.49 <0.27 <0.13 <0.26 <0.3 Notes: 1)All results provided in µg/L (micrograms per liter) or parts per billion 2)2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3)Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown Result Result Exceeds 2B Standard NENENENENENENE NE NENENENE470100NE2B Standard (µg/L) SW-2 SW-3 SW-1 107-06-2 75-35-4 156-59-2 156-60-5 78-87-5 10061-01-5 10061-02-6 100-41-4106-93-4 74-95-3 95-50-1 106-46-7 110-57-6 75-34-3CAS #124-48-1 Contaminant Of Concern Dibromochloromethane1,2-Dibromoethane (EDB)1,1-Dichloroethenecis-1,2-Dichloroethenetrans-1,2-Dichloroethene1,2-Dichloropropanecis-1,3-Dichloropropenetrans-1,3-DichloropropeneEthylbenzeneAnalytical Method EPA 8260 TABLE 5 SURFACE WATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.11 Dibromomethane1,2-Dichlorobenzene1,4-Dichlorobenzenetrans-1,4-Dichloro-2-butene1,1-Dichloroethane1,2-Dichloroethane Page 4 of 4 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual 7/29/2016 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 <0.62 <0.66 12/21/2016 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 <0.62 <0.66 7/29/2016 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 <0.62 <0.66 12/21/2016 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 <0.62 <0.66 7/29/2016 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 <0.62 <0.66 12/21/2016 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 <0.62 <0.66 Notes: 1)All results provided in µg/L (micrograms per liter) or parts per billion 2)2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3)Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown Result Result Exceeds 2B Standard 11 NE NE 30 NENENENENENE4.0 NE NE 2.4 NE2B Standard (µg/L)NE NE SW-2 SW-3 SW-1 71-55-6 79-00-5 79-01-6 75-69-4108-10-1 100-42-5 630-20-6 79-34-5 127-18-4 108-88-3CAS #591-78-6 74-88-4 75-09-2 1,1,2-TrichloroethaneTrichloroetheneTrichlorofluoromethaneStyrene1,1,1,2-Tetrachloroethane1,1,2,2-TetrachloroethaneTetrachloroetheneToluene1,1,1-Trichloroethane2-HexanoneIodomethaneMethylene Chloride4-Methyl-2-pentanone (MIBK)Contaminant Of Concern EPA 8260 1,2,3-TrichloropropaneVinyl acetateVinyl chlorideTABLE 5 SURFACE WATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.11 Analytical Method EPA 8260 Xylene (Total)96-18-4 108-05-4 75-01-4 1330-20-7 Page 1 OF 1 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual 7/29/2016 <1000 82.7 <0.87 <0.77 2440 140,000 <500 H1,N2 10,100 <100 M3 7,710 <12,500 <10 2,900 12/21/2016 <1000 81.3 NA NA NA 138,000 NA 8,960 <100 NA NA <20 <500 7/29/2016 <1000 <10 <0.87 <0.77 56.4 149,000 <500 H1,N2 28,600 <100 3,210 <12,500 <10 4,180 12/21/2016 <1000 <10 NA NA NA 157,000 NA 30,100 <100 NA NA <20 <2,000 D3 EXTRA*7/29/2016 <1000 <10 <0.87 <0.77 74.1 147,000 <500 H1,N2 29,100 <100 <2000 <12,500 NA 2,090 DUPLICATE **7/29/2016 NA NA NA NA NA NA NA NA NA NA NA NA NA 7/29/2016 <1000 <10 <0.87 <0.77 90 155,000 M1 <500 H1,N2 18,000 <100 <2000 <12,500 <10 <500 12/21/2016 <1000 <10 NA NA NA 164,000 NA 17,400 <100 M1 NA NA <20 <500 7/29/2016 <1000 <10 <0.87 <0.77 315 174,000 <500 H1,N2 17,800 <100 3,360 <12,500 <10 1,730 12/21/2016 <1000 <10 NA NA NA 183,000 NA 16,500 <100 NA NA <20 <500 7/29/2016 NA NA NA NA NA NA NA NA NA NA NA NA NA 12/22/2016 NA NA NA NA NA NA NA NA NA NA NA NA NA Duplicate ***12/22/2016 NA NA NA NA NA NA NA NA NA NA NA NA NA 7/29/2016 6,750 20.1 <0.87 <0.77 <0.49 8,520 <500 H1,N2 1,840 <100 <2000 <12,500 <10 2,540 12/22/2016 8,260 86.8 NA NA NA 6,650 NA 1,580 <100 NA NA <20 <2,000 D3 Trip Blank 7/29/2016 NA NA NA NA NA NA NA NA NA NA NA NA NA Field Blank 12/22/2016 NA NA NA NA NA NA NA NA NA NA NA NA NA Notes: 1)All results provided in µg/L (micrograms per liter) or parts per billion * =Laboratory blind duplicated sample of MW-3S 2)2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L **=Laboratory blind duplicated sample of MW-3S 3)Interim Maximum Allowable Concentration (IMAC)***=Laboratory blind duplicated sample of MW-5 4)GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5)NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6)Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. Qualifiers NA Not Analyzed by Method Shown H1=Analysis conducted outside the EPA method holding time. Result Result Exceeds 2L Standard or GWP M3=Matrix spike recovery was outside laboratory control limits due to matrix interference. N2=The lab does not hold TNI accreditation for this parameter. D3=Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. NENE300250,000 NE NE NE2L Standard/GWP (µg/L)250,000 10000 2 MW-5 NENENENE MW-2 MW-3S MW-6 MW-3D MW-4 NA NA AM20GAX 7440-44-074-84-0 74-85-1 74-82-8 NA NA Dissolved HydrogenTotal Organic Carbon (TOC)CAS #14808-79-8 NA Alkalinity, Total as CaCO3Iron, FerrousChlorideSulfideBiological Oxygen Demand (BOD)Chemical Oxygen Demand (COD)EthaneEtheneMethane16887-00-6 18496-25-8 Contaminant Of Concern SulfateNitrogen, NitrateRSK 175 SM 2320BAnalytical Method EPA 300.0 TABLE 6 SUMMARY OF MNA CONSTITUENTS TOWN OF KERNERSVILLE LANDFILL PERMIT #: 34-04 EPA 353.2 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.11 SM 5210B SM 5220D AM20GAX SM 5310BSM 3500-Fe B SM 4500-Cl-E SM 4500-S2D APPENDIX BIODEGRADATION SCREENING MATRIX Town of Kernersville Closed Landfill Permit #34-04 December 2016 Page 1 of 1 Parameter Concentration in Plume Interpretation Possible Points Points Awarded with DP Points Points Awarded w/out DP Points Oxygen < 0.5 mg/L Tolerated, suppresses the reductive pathway at higher concentrations 3 0 0 > 5 mg/L Not tolerated, vinyl chloride may be oxidized aerobically -3 0 0 Nitrate < 1 mg/L At higher concentrations may compete with reductive pathway 2 2 2 Iron II (Ferrous Iron)> 1 mg/L Reductive pathway possible; vinyl chloride may be oxidized under Fe (III) - reducing conditions 3 0 0 Sulfate < 20 mg/l At higher concentrations may compete with reductive pathway 2 2 2 Sulfide > 1 mg/L Reductive pathway possible 3 0 0 Methane < 0.5 mg/L Vinyl chloride oxidizes 0 0 0 > 0.5 mg/L Ultimate reductive daughter product, vinyl chloride accumulates 3 0 0 Oxidation Reduction Potential < 50 mV Reductive pathway possible 1 1 1 < -100 mV Reductive pathway likely 2 0 0 pH 5 < pH > 9 Optimal range for reductive pathway 0 0 0 5 > ph < 9 Outside optimal range for reductive pathway -2 0 0 TOC > 20 mg/L Carbon and enegy source; drives dechlorination; can be natural or anthropogenic 2 0 0 Temperature > 20OC At T> 20OC, biochemical process is accelerated 1 1 1 Carbon Dioxide (CO2)> 2x background Ultimate oxidative daughter product 1 0 0 Alkalinity > 2x background Results from interaction between CO2 and aquifer minerals 1 1 1 Chloride > 2x background Daugher product of organic chlorine 2 2 2 Hydrogen > 1 nM Reductive pathway possible 3 2 3 < 1 nM Vinyl chloride oxidizes 0 0 0 Volatile Fatty Acids > 0.1 mg/L Intermediates resulting from biodegradation of more complex compounds; carbon and energy source 2 0 0 BTEX > 0.1 mg/L Carbon and enegy source; drives dechlorination 2 0 0 Tetrachloroethane (PCE)---Material released 0 0 0 0 Trichloroethane (TCE)---Material released 0 0 0 Daughter product of PCE 2 2 0 Dichloroethane (DCE)---Material released 0 0 0 Daughter product of TCE 2 2 0 Dichloroethene, cis-1,2 ---Material released 0 0 0 Daughter product of trichlorethene 2 2 0 Vinyl Chloride ---Material released 0 0 0 Daughter product of DCE 2 2 0 1,1,1-Trichloroethane (TCA)---Material released 0 0 0 0 1,1-Dichloroethane (DCA)---Material released 0 0 0 Daughter product of TCA 2 2 0 Chloroethane ---Daughter product of dichloroethane or vinyl chloride under reducing conditions 2 2 0 Ethene/Ethane > 0.01 mg/L Daughter products of vinyl chloride/ethene 2 0 0 > 0.1 mg/L 3 0 0 Chloroform ---Material released 0 0 0 Daghter product of carbon tetrachloride 2 0 0 Dichloromethane (MC)---Material released 0 0 0 (Methylene Chloride) Daughter product of chloroform 2 0 0 23 12 mg/L = miligrams per Liter mV = millivolts nM = Nanometer C = Celcius NA = Not analyzed SCORE: This screening matrix is prepared in general accordance with the USEPA's Table 2.3 Analytical Parameters and < 5 Weighted for Preliminary Screening for Anaerobic Biodegradation Process presented in the EPA's Technical 6-14 Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Groundwater, September 1988.15-19 >20 Strong Adequate BTEX = Sum of benzene, toluene, true score is presumably between the two. Evidence of Natural Attentuation Inadequate Limited daughter products, and the second column assumes none of them. The ethylbenzene and total xylenes Total Points Awarded: NOTE: Chloroethane, methane, TCE, DCE, cis-1,2-DCE, MC, VC, DCA and CO2 are all present in the plume; however, it is uncertain whether these are primary leachate constituents or daughter products (DPs); therefore we have two calculations columns. The first column assumes all of these are APPENDIX I Laboratory Analytical Reports and Field Data Logs #=CL# January 03, 2017 LIMS USE: FR - MARK BROWN LIMS OBJECT ID: 92324275 92324275 Project: Pace Project No.: RE: Mark Brown Withers & Ravenel 7011 Albert Pick Rd Suite G Greensboro, NC 27409 Town of Kernersville Dear Mark Brown: Enclosed are the analytical results for sample(s) received by the laboratory between December 21, 2016 and December 22, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Taylor Ezell taylor.ezell@pacelabs.com Project Manager Enclosures cc:Ross Perry, Withers & Ravenel REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 42 #=CL# January 13, 2017 LIMS USE: FR - MARK BROWN LIMS OBJECT ID: 92324286 92324286 Project: Pace Project No.: RE: Mark Brown Withers & Ravenel 7011 Albert Pick Rd Suite G Greensboro, NC 27409 Town of Kernersville MNA Dear Mark Brown: Enclosed are the analytical results for sample(s) received by the laboratory between December 21, 2016 and December 22, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. If you have any questions concerning this report, please feel free to contact me. Sincerely, Taylor Ezell taylor.ezell@pacelabs.com Project Manager Enclosures cc:Ross Perry, Withers & Ravenel REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 39 #=CP# CERTIFICATIONS Pace Project No.: Project: 92324286 Town of Kernersville MNA Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Wyoming Certification: FL NELAC Reciprocity West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 39 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92324286 Town of Kernersville MNA Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92324286001 3404-MW-2 SM 2320B 1 PASI-ASER SM 4500-S2D 1 PASI-AMDW EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-AWRC SM 4500-Cl-E 1 PASI-AWRC SM 5310B 1 PASI-OAEM 92324286002 3404-MW-3S SM 2320B 1 PASI-ASER SM 4500-S2D 1 PASI-AMDW EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-AWRC SM 4500-Cl-E 1 PASI-AWRC SM 5310B 1 PASI-OAEM 92324286003 3404-MW-3D SM 2320B 1 PASI-ASER SM 4500-S2D 1 PASI-AMDW EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-AWRC SM 4500-Cl-E 1 PASI-AWRC SM 5310B 1 PASI-OAEM 92324286004 3404-MW-4 SM 2320B 1 PASI-ASER SM 4500-S2D 1 PASI-AMDW EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-AWRC SM 4500-Cl-E 1 PASI-AWRC SM 5310B 1 PASI-OAEM 92324286005 3404-MW-6 SM 2320B 1 PASI-AKDF SM 4500-S2D 1 PASI-AEWS EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-AWRC SM 4500-Cl-E 1 PASI-AWRC SM 5310B 1 PASI-OAEM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324286 Town of Kernersville MNA Sample:3404-MW-2 Lab ID:92324286001 Collected:12/21/16 11:40 Received:12/21/16 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: SM 2320B2320B Alkalinity Alkalinity, Total as CaCO3 138000 ug/L 12/31/16 01:5050001 Analytical Method: SM 4500-S2D4500S2D Sulfide Water Sulfide ND ug/L 12/24/16 00:43 18496-25-81001 Analytical Method: EPA 300.0300.0 IC Anions 28 Days Sulfate ND ug/L 12/30/16 16:04 14808-79-820001 Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate 81.3 ug/L 12/23/16 01:2120.0 1 Analytical Method: SM 4500-Cl-E4500 Chloride Chloride 8960 ug/L 01/03/17 17:41 16887-00-610001 Analytical Method: SM 5310B5310B TOC Total Organic Carbon ND mg/L 01/13/17 02:01 7440-44-01.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/13/2017 01:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324286 Town of Kernersville MNA Sample:3404-MW-3S Lab ID:92324286002 Collected:12/21/16 09:50 Received:12/21/16 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: SM 2320B2320B Alkalinity Alkalinity, Total as CaCO3 157000 ug/L 12/31/16 02:0250001 Analytical Method: SM 4500-S2D4500S2D Sulfide Water Sulfide ND ug/L 12/24/16 00:43 18496-25-81001 Analytical Method: EPA 300.0300.0 IC Anions 28 Days Sulfate ND ug/L 12/30/16 16:23 14808-79-820001 Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate ND ug/L 12/23/16 01:1620.0 1 Analytical Method: SM 4500-Cl-E4500 Chloride Chloride 30100 ug/L 01/03/17 17:43 16887-00-610001 Analytical Method: SM 5310B5310B TOC Total Organic Carbon ND mg/L 01/13/17 02:50 7440-44-0 D34.0 4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/13/2017 01:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324286 Town of Kernersville MNA Sample:3404-MW-3D Lab ID:92324286003 Collected:12/21/16 09:20 Received:12/21/16 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: SM 2320B2320B Alkalinity Alkalinity, Total as CaCO3 164000 ug/L 12/31/16 02:1350001 Analytical Method: SM 4500-S2D4500S2D Sulfide Water Sulfide ND ug/L 12/24/16 00:43 18496-25-8 M11001 Analytical Method: EPA 300.0300.0 IC Anions 28 Days Sulfate ND ug/L 12/30/16 16:59 14808-79-820001 Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate ND ug/L 12/23/16 01:1020.0 1 Analytical Method: SM 4500-Cl-E4500 Chloride Chloride 17400 ug/L 01/03/17 17:47 16887-00-610001 Analytical Method: SM 5310B5310B TOC Total Organic Carbon ND mg/L 01/13/17 03:04 7440-44-01.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/13/2017 01:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324286 Town of Kernersville MNA Sample:3404-MW-4 Lab ID:92324286004 Collected:12/21/16 11:00 Received:12/21/16 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: SM 2320B2320B Alkalinity Alkalinity, Total as CaCO3 183000 ug/L 12/31/16 02:2650001 Analytical Method: SM 4500-S2D4500S2D Sulfide Water Sulfide ND ug/L 12/24/16 00:43 18496-25-81001 Analytical Method: EPA 300.0300.0 IC Anions 28 Days Sulfate ND ug/L 01/04/17 18:23 14808-79-820001 Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate ND ug/L 12/23/16 01:1720.0 1 Analytical Method: SM 4500-Cl-E4500 Chloride Chloride 16500 ug/L 01/03/17 17:48 16887-00-610001 Analytical Method: SM 5310B5310B TOC Total Organic Carbon ND mg/L 01/13/17 03:42 7440-44-01.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/13/2017 01:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 39 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324286 Town of Kernersville MNA Sample:3404-MW-6 Lab ID:92324286005 Collected:12/22/16 09:15 Received:12/22/16 14:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: SM 2320B2320B Alkalinity Alkalinity, Total as CaCO3 6650 ug/L 01/03/17 20:1350001 Analytical Method: SM 4500-S2D4500S2D Sulfide Water Sulfide ND ug/L 12/27/16 15:30 18496-25-81001 Analytical Method: EPA 300.0300.0 IC Anions 28 Days Sulfate 8260 ug/L 01/04/17 18:32 14808-79-820001 Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate 86.8 ug/L 12/24/16 00:0020.0 1 Analytical Method: SM 4500-Cl-E4500 Chloride Chloride 1580 ug/L 01/03/17 17:53 16887-00-610001 Analytical Method: SM 5310B5310B TOC Total Organic Carbon ND mg/L 01/13/17 03:57 7440-44-0 D34.0 4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/13/2017 01:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324286 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 342861 SM 2320B SM 2320B 2320B Alkalinity Associated Lab Samples:92324286001, 92324286002, 92324286003, 92324286004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1901711 Associated Lab Samples:92324286001, 92324286002, 92324286003, 92324286004 Matrix:Water Analyzed Alkalinity, Total as CaCO3 ug/L ND 5000 12/30/16 20:44 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1901712LABORATORY CONTROL SAMPLE: LCSSpike Alkalinity, Total as CaCO3 ug/L 4970050000 99 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1901713MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92324363015 1901714 MSD Result MSD % Rec RPD MSDMS Spike Conc. Alkalinity, Total as CaCO3 ug/L M1500008080-12073 35000097.9 mg/L 138000 134000 Parameter Units MS Result % Rec Limits Qual% RecConc. 1901715MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92324368006 1901716 MSD Result MSD % Rec RPD MSDMS Spike Conc. Alkalinity, Total as CaCO3 ug/L 50000 101 80-120100 15000012.4 mg/L 62900 62300 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/13/2017 01:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324286 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343132 SM 2320B SM 2320B 2320B Alkalinity Associated Lab Samples:92324286005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1903260 Associated Lab Samples:92324286005 Matrix:Water Analyzed Alkalinity, Total as CaCO3 ug/L ND 5000 01/03/17 15:08 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1903261LABORATORY CONTROL SAMPLE: LCSSpike Alkalinity, Total as CaCO3 ug/L 4820050000 96 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1903262MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92324507001 1903263 MSD Result MSD % Rec RPD MSDMS Spike Conc. Alkalinity, Total as CaCO3 ug/L 50000 102 80-120106 35000012.6 mg/L 63600 65600 Parameter Units MS Result % Rec Limits Qual% RecConc. 1903264MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92324507011 1903265 MSD Result MSD % Rec RPD MSDMS Spike Conc. Alkalinity, Total as CaCO3 ug/L 50000 100 80-12099 15000013.9 mg/L 64000 63500 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/13/2017 01:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324286 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 342411 SM 4500-S2D SM 4500-S2D 4500S2D Sulfide Water Associated Lab Samples:92324286001, 92324286002, 92324286003, 92324286004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1899843 Associated Lab Samples:92324286001, 92324286002, 92324286003, 92324286004 Matrix:Water Analyzed Sulfide ug/L ND 100 12/24/16 00:43 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1899844LABORATORY CONTROL SAMPLE: LCSSpike Sulfide ug/L 469500 94 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1899845MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92324197015 1899846 MSD Result MSD % Rec RPD MSDMS Spike Conc. Sulfide ug/L 500 92 80-12092 0500ND462461 Parameter Units MS Result % Rec Limits Qual% RecConc. 1899847MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92324286003 1899848 MSD Result MSD % Rec RPD MSDMS Spike Conc. Sulfide ug/L M15007780-12077 0500ND387386 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/13/2017 01:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324286 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 342529 SM 4500-S2D SM 4500-S2D 4500S2D Sulfide Water Associated Lab Samples:92324286005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1900198 Associated Lab Samples:92324286005 Matrix:Water Analyzed Sulfide ug/L ND 100 12/27/16 15:30 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1900199LABORATORY CONTROL SAMPLE: LCSSpike Sulfide ug/L 482500 96 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1900200MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92324363010 1900201 MSD Result MSD % Rec RPD MSDMS Spike Conc. Sulfide ug/L 500 90 80-12093 3500ND469484 Parameter Units MS Result % Rec Limits Qual% RecConc. 1900202MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92324368001 1900203 MSD Result MSD % Rec RPD MSDMS Spike Conc. Sulfide ug/L 500 84 80-12084 0500ND419418 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/13/2017 01:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324286 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 342832 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples:92324286001, 92324286002, 92324286003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1901526 Associated Lab Samples:92324286001, 92324286002, 92324286003 Matrix:Water Analyzed Sulfate ug/L ND 2000 12/30/16 12:17 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1901527LABORATORY CONTROL SAMPLE: LCSSpike Sulfate ug/L 1810020000 91 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1901528MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92324373002 1901529 MSD Result MSD % Rec RPD MSDMS Spike Conc. Sulfate ug/L 20000 100 90-110100 0200005.1 mg/L 25100 25000 Parameter Units MS Result % Rec Limits Qual% RecConc. 1901530MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92324257002 1901531 MSD Result MSD % Rec RPD MSDMS Spike Conc. Sulfate ug/L 20000 98 90-11098 0200005.7 mg/L 25400 25300 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/13/2017 01:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324286 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343338 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples:92324286004, 92324286005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1904351 Associated Lab Samples:92324286004, 92324286005 Matrix:Water Analyzed Sulfate ug/L ND 2000 01/04/17 17:20 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1904352LABORATORY CONTROL SAMPLE: LCSSpike Sulfate ug/L 2050020000 103 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1904353MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92324351001 1904354 MSD Result MSD % Rec RPD MSDMS Spike Conc. Sulfate ug/L 20000 92 90-11093 1200009.4 mg/L 27800 28000 Parameter Units MS Result % Rec Limits Qual% RecConc. 1904355MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92325025002 1904356 MSD Result MSD % Rec RPD MSDMS Spike Conc. Sulfate ug/L 20000 92 90-11092 0200003230J2170021700 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/13/2017 01:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324286 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 342296 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92324286001, 92324286002, 92324286003, 92324286004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1899122 Associated Lab Samples:92324286001, 92324286002, 92324286003, 92324286004 Matrix:Water Analyzed Nitrogen, Nitrate ug/L ND 20.0 12/23/16 01:07 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1899123LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate ug/L 24002500 96 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1899124MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92324286003 1899125 MSD Result MSD % Rec RPD MSDMS Spike Conc. Nitrogen, Nitrate ug/L 2500 91 90-11090 12500ND22902260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/13/2017 01:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324286 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 342429 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92324286005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1899900 Associated Lab Samples:92324286005 Matrix:Water Analyzed Nitrogen, Nitrate ug/L ND 20.0 12/23/16 23:47 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1899901LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate ug/L 23802500 95 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1899902MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92324370003 1899903 MSD Result MSD % Rec RPD MSDMS Spike Conc. Nitrogen, Nitrate ug/L 2500 91 90-11093 22500ND22802330 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/13/2017 01:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324286 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343216 SM 4500-Cl-E SM 4500-Cl-E 4500 Chloride Associated Lab Samples:92324286001, 92324286002, 92324286003, 92324286004, 92324286005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1903778 Associated Lab Samples:92324286001, 92324286002, 92324286003, 92324286004, 92324286005 Matrix:Water Analyzed Chloride ug/L ND 1000 01/03/17 17:29 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1903779LABORATORY CONTROL SAMPLE: LCSSpike Chloride ug/L 1930020000 96 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1903780MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92323984001 1903781 MSD Result MSD % Rec RPD MSDMS Spike Conc. Chloride ug/L 10000 105 90-110104 01000038701430014300 Parameter Units MS Result % Rec Limits Qual% RecConc. 1903782MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92324286002 1903783 MSD Result MSD % Rec RPD MSDMS Spike Conc. Chloride ug/L 10000 95 90-11092 110000301003960039300 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/13/2017 01:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324286 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343916 SM 5310B SM 5310B 5310B TOC Associated Lab Samples:92324286001, 92324286002, 92324286003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1845439 Associated Lab Samples:92324286001, 92324286002, 92324286003 Matrix:Water Analyzed Total Organic Carbon mg/L ND 1.0 01/12/17 19:43 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1845440LABORATORY CONTROL SAMPLE: LCSSpike Total Organic Carbon mg/L 20.120 100 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1845441MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92324757009 1845442 MSD Result MSD % Rec RPD MSDMS Spike Conc. Total Organic Carbon mg/L 20 100 80-120100 020ND20.0 20.0 Parameter Units MS Result % Rec Limits Qual% RecConc. 1845443MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 35287517007 1845444 MSD Result MSD % Rec RPD MSDMS Spike Conc. Total Organic Carbon mg/L 20 98 80-12099 220<0.50 19.5 19.8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/13/2017 01:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 39 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324286 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343917 SM 5310B SM 5310B 5310B TOC Associated Lab Samples:92324286004, 92324286005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1845445 Associated Lab Samples:92324286004, 92324286005 Matrix:Water Analyzed Total Organic Carbon mg/L ND 1.0 01/13/17 03:14 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1845446LABORATORY CONTROL SAMPLE: LCSSpike Total Organic Carbon mg/L 20.020 100 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1845447MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 35287284001 1845448 MSD Result MSD % Rec RPD MSDMS Spike Conc. Total Organic Carbon mg/L 20 97 80-12099 1208.8 28.2 28.5 Parameter Units MS Result % Rec Limits Qual% RecConc. 1845449MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 35287284009 1845450 MSD Result MSD % Rec RPD MSDMS Spike Conc. Total Organic Carbon mg/L 20 95 80-12094 12010.0 29.0 28.8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/13/2017 01:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 39 #=QL# QUALIFIERS Pace Project No.: Project: 92324286 Town of Kernersville MNA DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - Ormond BeachPASI-O ANALYTE QUALIFIERS Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/13/2017 01:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 39 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92324286 Town of Kernersville MNA Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92324286001 3428613404-MW-2 SM 2320B 92324286002 3428613404-MW-3S SM 2320B 92324286003 3428613404-MW-3D SM 2320B 92324286004 3428613404-MW-4 SM 2320B 92324286005 3431323404-MW-6 SM 2320B 92324286001 3424113404-MW-2 SM 4500-S2D 92324286002 3424113404-MW-3S SM 4500-S2D 92324286003 3424113404-MW-3D SM 4500-S2D 92324286004 3424113404-MW-4 SM 4500-S2D 92324286005 3425293404-MW-6 SM 4500-S2D 92324286001 3428323404-MW-2 EPA 300.0 92324286002 3428323404-MW-3S EPA 300.0 92324286003 3428323404-MW-3D EPA 300.0 92324286004 3433383404-MW-4 EPA 300.0 92324286005 3433383404-MW-6 EPA 300.0 92324286001 3422963404-MW-2 EPA 353.2 92324286002 3422963404-MW-3S EPA 353.2 92324286003 3422963404-MW-3D EPA 353.2 92324286004 3422963404-MW-4 EPA 353.2 92324286005 3424293404-MW-6 EPA 353.2 92324286001 3432163404-MW-2 SM 4500-Cl-E 92324286002 3432163404-MW-3S SM 4500-Cl-E 92324286003 3432163404-MW-3D SM 4500-Cl-E 92324286004 3432163404-MW-4 SM 4500-Cl-E 92324286005 3432163404-MW-6 SM 4500-Cl-E 92324286001 3439163404-MW-2 SM 5310B 92324286002 3439163404-MW-3S SM 5310B 92324286003 3439163404-MW-3D SM 5310B 92324286004 3439173404-MW-4 SM 5310B 92324286005 3439173404-MW-6 SM 5310B REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/13/2017 01:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 39 Page 22 of 39 Page 23 of 39 Page 24 of 39 Page 25 of 39 Page 26 of 39 Page 27 of 39 Page 28 of 39 Page 29 of 39 Page 30 of 39 Page 31 of 39 Page 32 of 39 Page 33 of 39 Page 34 of 39 Page 35 of 39 Page 36 of 39 Page 37 of 39 Page 38 of 39 Page 39 of 39 #=CP# CERTIFICATIONS Pace Project No.: Project: 92324275 Town of Kernersville Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 42 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92324275 Town of Kernersville Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92324275001 3404-MW-3D EPA 6010 15 PASI-AJMW EPA 8260 50 PASI-CDLK 92324275002 3404-MW-3S EPA 6010 15 PASI-AJMW EPA 8260 50 PASI-CDLK 92324275003 3404-MW-4 EPA 6010 15 PASI-AJMW EPA 8260 50 PASI-CDLK 92324275004 3404-SW-2 EPA 6010 15 PASI-AJMW EPA 8260 50 PASI-CDLK 92324275005 3404-SW-1 EPA 6010 15 PASI-AJMW EPA 8260 50 PASI-CDLK 92324275006 3404-SW-3 EPA 6010 15 PASI-AJMW EPA 8260 50 PASI-CDLK 92324275007 3404-MW-2 EPA 6010 15 PASI-AJMW EPA 8260 50 PASI-CDLK 92324275008 Duplicate EPA 6010 15 PASI-AJMW EPA 8260 50 PASI-CDLK 92324275009 3404-MW-5 EPA 6010 15 PASI-AJMW EPA 8260 50 PASI-CDLK 92324275010 3404-MW-6 EPA 6010 15 PASI-AJMW EPA 8260 50 PASI-CDLK 92324275011 3404-Field Blank EPA 6010 15 PASI-AJMW EPA 8260 50 PASI-CDLK REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:3404-MW-3D Lab ID:92324275001 Collected:12/21/16 09:20 Received:12/21/16 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 01/01/17 07:45 7440-36-012/28/16 20:455.0 1 Arsenic ND ug/L 01/01/17 07:45 7440-38-212/28/16 20:4510.0 1 Barium 41.2 ug/L 01/01/17 07:45 7440-39-312/28/16 20:455.0 1 Beryllium ND ug/L 01/01/17 07:45 7440-41-712/28/16 20:451.0 1 Cadmium ND ug/L 01/01/17 07:45 7440-43-912/28/16 20:451.0 1 Chromium ND ug/L 01/01/17 07:45 7440-47-312/28/16 20:455.0 1 Cobalt ND ug/L 01/01/17 07:45 7440-48-412/28/16 20:455.0 1 Copper ND ug/L 01/01/17 07:45 7440-50-812/28/16 20:455.0 1 Lead ND ug/L 01/01/17 07:45 7439-92-112/28/16 20:455.0 1 Nickel ND ug/L 01/01/17 07:45 7440-02-012/28/16 20:455.0 1 Selenium ND ug/L 01/01/17 07:45 7782-49-212/28/16 20:4510.0 1 Silver ND ug/L 01/01/17 07:45 7440-22-412/28/16 20:455.0 1 Thallium ND ug/L 01/01/17 07:45 7440-28-012/28/16 20:455.4 1 Vanadium ND ug/L 01/01/17 07:45 7440-62-212/28/16 20:455.0 1 Zinc ND ug/L 01/01/17 07:45 7440-66-612/28/16 20:4510.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 12/27/16 17:34 67-64-125.0 1 Acrylonitrile ND ug/L 12/27/16 17:34 107-13-110.0 1 Benzene ND ug/L 12/27/16 17:34 71-43-21.0 1 Bromochloromethane ND ug/L 12/27/16 17:34 74-97-51.0 1 Bromodichloromethane ND ug/L 12/27/16 17:34 75-27-41.0 1 Bromoform ND ug/L 12/27/16 17:34 75-25-21.0 1 Bromomethane ND ug/L 12/27/16 17:34 74-83-92.0 1 2-Butanone (MEK)ND ug/L 12/27/16 17:34 78-93-35.0 1 Carbon disulfide ND ug/L 12/27/16 17:34 75-15-02.0 1 Carbon tetrachloride ND ug/L 12/27/16 17:34 56-23-51.0 1 Chlorobenzene ND ug/L 12/27/16 17:34 108-90-71.0 1 Chloroethane ND ug/L 12/27/16 17:34 75-00-31.0 1 Chloroform ND ug/L 12/27/16 17:34 67-66-31.0 1 Chloromethane ND ug/L 12/27/16 17:34 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 12/27/16 17:34 96-12-82.0 1 Dibromochloromethane ND ug/L 12/27/16 17:34 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 12/27/16 17:34 106-93-41.0 1 Dibromomethane ND ug/L 12/27/16 17:34 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 12/27/16 17:34 95-50-11.0 1 1,4-Dichlorobenzene 3.7 ug/L 12/27/16 17:34 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 12/27/16 17:34 110-57-61.0 1 1,1-Dichloroethane 2.8 ug/L 12/27/16 17:34 75-34-31.0 1 1,2-Dichloroethane ND ug/L 12/27/16 17:34 107-06-21.0 1 1,1-Dichloroethene ND ug/L 12/27/16 17:34 75-35-41.0 1 cis-1,2-Dichloroethene 48.5 ug/L 12/27/16 17:34 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 12/27/16 17:34 156-60-51.0 1 1,2-Dichloropropane 1.1 ug/L 12/27/16 17:34 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 12/27/16 17:34 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 12/27/16 17:34 10061-02-61.0 1 Ethylbenzene ND ug/L 12/27/16 17:34 100-41-41.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:3404-MW-3D Lab ID:92324275001 Collected:12/21/16 09:20 Received:12/21/16 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 2-Hexanone ND ug/L 12/27/16 17:34 591-78-65.0 1 Iodomethane ND ug/L 12/27/16 17:34 74-88-45.0 1 Methylene Chloride ND ug/L 12/27/16 17:34 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 12/27/16 17:34 108-10-15.0 1 Styrene ND ug/L 12/27/16 17:34 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 12/27/16 17:34 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 12/27/16 17:34 79-34-51.0 1 Tetrachloroethene ND ug/L 12/27/16 17:34 127-18-41.0 1 Toluene ND ug/L 12/27/16 17:34 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 12/27/16 17:34 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 12/27/16 17:34 79-00-51.0 1 Trichloroethene ND ug/L 12/27/16 17:34 79-01-61.0 1 Trichlorofluoromethane ND ug/L 12/27/16 17:34 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 12/27/16 17:34 96-18-41.0 1 Vinyl acetate ND ug/L 12/27/16 17:34 108-05-42.0 1 Vinyl chloride 8.2 ug/L 12/27/16 17:34 75-01-41.0 1 Xylene (Total)ND ug/L 12/27/16 17:34 1330-20-71.0 1 Surrogates 4-Bromofluorobenzene (S)100 %12/27/16 17:34 460-00-470-130 1 1,2-Dichloroethane-d4 (S)99 %12/27/16 17:34 17060-07-070-130 1 Toluene-d8 (S)100 %12/27/16 17:34 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:3404-MW-3S Lab ID:92324275002 Collected:12/21/16 09:50 Received:12/21/16 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 01/01/17 07:48 7440-36-012/28/16 20:455.0 1 Arsenic ND ug/L 01/01/17 07:48 7440-38-212/28/16 20:4510.0 1 Barium 91.4 ug/L 01/01/17 07:48 7440-39-312/28/16 20:455.0 1 Beryllium ND ug/L 01/01/17 07:48 7440-41-712/28/16 20:451.0 1 Cadmium ND ug/L 01/01/17 07:48 7440-43-912/28/16 20:451.0 1 Chromium ND ug/L 01/01/17 07:48 7440-47-312/28/16 20:455.0 1 Cobalt ND ug/L 01/01/17 07:48 7440-48-412/28/16 20:455.0 1 Copper ND ug/L 01/01/17 07:48 7440-50-812/28/16 20:455.0 1 Lead ND ug/L 01/01/17 07:48 7439-92-112/28/16 20:455.0 1 Nickel ND ug/L 01/01/17 07:48 7440-02-012/28/16 20:455.0 1 Selenium ND ug/L 01/01/17 07:48 7782-49-212/28/16 20:4510.0 1 Silver ND ug/L 01/01/17 07:48 7440-22-412/28/16 20:455.0 1 Thallium ND ug/L 01/01/17 07:48 7440-28-012/28/16 20:455.4 1 Vanadium ND ug/L 01/01/17 07:48 7440-62-212/28/16 20:455.0 1 Zinc ND ug/L 01/01/17 07:48 7440-66-612/28/16 20:4510.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 12/27/16 17:50 67-64-125.0 1 Acrylonitrile ND ug/L 12/27/16 17:50 107-13-110.0 1 Benzene ND ug/L 12/27/16 17:50 71-43-21.0 1 Bromochloromethane ND ug/L 12/27/16 17:50 74-97-51.0 1 Bromodichloromethane ND ug/L 12/27/16 17:50 75-27-41.0 1 Bromoform ND ug/L 12/27/16 17:50 75-25-21.0 1 Bromomethane ND ug/L 12/27/16 17:50 74-83-92.0 1 2-Butanone (MEK)ND ug/L 12/27/16 17:50 78-93-35.0 1 Carbon disulfide ND ug/L 12/27/16 17:50 75-15-02.0 1 Carbon tetrachloride ND ug/L 12/27/16 17:50 56-23-51.0 1 Chlorobenzene 1.1 ug/L 12/27/16 17:50 108-90-71.0 1 Chloroethane ND ug/L 12/27/16 17:50 75-00-31.0 1 Chloroform ND ug/L 12/27/16 17:50 67-66-31.0 1 Chloromethane ND ug/L 12/27/16 17:50 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 12/27/16 17:50 96-12-82.0 1 Dibromochloromethane ND ug/L 12/27/16 17:50 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 12/27/16 17:50 106-93-41.0 1 Dibromomethane ND ug/L 12/27/16 17:50 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 12/27/16 17:50 95-50-11.0 1 1,4-Dichlorobenzene 1.8 ug/L 12/27/16 17:50 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 12/27/16 17:50 110-57-61.0 1 1,1-Dichloroethane ND ug/L 12/27/16 17:50 75-34-31.0 1 1,2-Dichloroethane ND ug/L 12/27/16 17:50 107-06-21.0 1 1,1-Dichloroethene ND ug/L 12/27/16 17:50 75-35-41.0 1 cis-1,2-Dichloroethene 7.3 ug/L 12/27/16 17:50 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 12/27/16 17:50 156-60-51.0 1 1,2-Dichloropropane ND ug/L 12/27/16 17:50 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 12/27/16 17:50 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 12/27/16 17:50 10061-02-61.0 1 Ethylbenzene ND ug/L 12/27/16 17:50 100-41-41.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:3404-MW-3S Lab ID:92324275002 Collected:12/21/16 09:50 Received:12/21/16 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 2-Hexanone ND ug/L 12/27/16 17:50 591-78-65.0 1 Iodomethane ND ug/L 12/27/16 17:50 74-88-45.0 1 Methylene Chloride ND ug/L 12/27/16 17:50 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 12/27/16 17:50 108-10-15.0 1 Styrene ND ug/L 12/27/16 17:50 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 12/27/16 17:50 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 12/27/16 17:50 79-34-51.0 1 Tetrachloroethene ND ug/L 12/27/16 17:50 127-18-41.0 1 Toluene ND ug/L 12/27/16 17:50 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 12/27/16 17:50 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 12/27/16 17:50 79-00-51.0 1 Trichloroethene ND ug/L 12/27/16 17:50 79-01-61.0 1 Trichlorofluoromethane ND ug/L 12/27/16 17:50 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 12/27/16 17:50 96-18-41.0 1 Vinyl acetate ND ug/L 12/27/16 17:50 108-05-42.0 1 Vinyl chloride 2.2 ug/L 12/27/16 17:50 75-01-41.0 1 Xylene (Total)ND ug/L 12/27/16 17:50 1330-20-71.0 1 Surrogates 4-Bromofluorobenzene (S)100 %12/27/16 17:50 460-00-470-130 1 1,2-Dichloroethane-d4 (S)100 %12/27/16 17:50 17060-07-070-130 1 Toluene-d8 (S)99 %12/27/16 17:50 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:3404-MW-4 Lab ID:92324275003 Collected:12/21/16 11:00 Received:12/21/16 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 01/01/17 07:51 7440-36-012/28/16 20:455.0 1 Arsenic ND ug/L 01/01/17 07:51 7440-38-212/28/16 20:4510.0 1 Barium ND ug/L 01/01/17 07:51 7440-39-312/28/16 20:455.0 1 Beryllium ND ug/L 01/01/17 07:51 7440-41-712/28/16 20:451.0 1 Cadmium ND ug/L 01/01/17 07:51 7440-43-912/28/16 20:451.0 1 Chromium ND ug/L 01/01/17 07:51 7440-47-312/28/16 20:455.0 1 Cobalt ND ug/L 01/01/17 07:51 7440-48-412/28/16 20:455.0 1 Copper ND ug/L 01/01/17 07:51 7440-50-812/28/16 20:455.0 1 Lead ND ug/L 01/01/17 07:51 7439-92-112/28/16 20:455.0 1 Nickel ND ug/L 01/01/17 07:51 7440-02-012/28/16 20:455.0 1 Selenium ND ug/L 01/01/17 07:51 7782-49-212/28/16 20:4510.0 1 Silver ND ug/L 01/01/17 07:51 7440-22-412/28/16 20:455.0 1 Thallium ND ug/L 01/01/17 07:51 7440-28-012/28/16 20:455.4 1 Vanadium ND ug/L 01/01/17 07:51 7440-62-212/28/16 20:455.0 1 Zinc ND ug/L 01/01/17 07:51 7440-66-612/28/16 20:4510.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 12/27/16 18:06 67-64-125.0 1 Acrylonitrile ND ug/L 12/27/16 18:06 107-13-110.0 1 Benzene ND ug/L 12/27/16 18:06 71-43-21.0 1 Bromochloromethane ND ug/L 12/27/16 18:06 74-97-51.0 1 Bromodichloromethane ND ug/L 12/27/16 18:06 75-27-41.0 1 Bromoform ND ug/L 12/27/16 18:06 75-25-21.0 1 Bromomethane ND ug/L 12/27/16 18:06 74-83-92.0 1 2-Butanone (MEK)ND ug/L 12/27/16 18:06 78-93-35.0 1 Carbon disulfide ND ug/L 12/27/16 18:06 75-15-02.0 1 Carbon tetrachloride ND ug/L 12/27/16 18:06 56-23-51.0 1 Chlorobenzene ND ug/L 12/27/16 18:06 108-90-71.0 1 Chloroethane ND ug/L 12/27/16 18:06 75-00-31.0 1 Chloroform ND ug/L 12/27/16 18:06 67-66-31.0 1 Chloromethane ND ug/L 12/27/16 18:06 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 12/27/16 18:06 96-12-82.0 1 Dibromochloromethane ND ug/L 12/27/16 18:06 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 12/27/16 18:06 106-93-41.0 1 Dibromomethane ND ug/L 12/27/16 18:06 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 12/27/16 18:06 95-50-11.0 1 1,4-Dichlorobenzene 2.2 ug/L 12/27/16 18:06 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 12/27/16 18:06 110-57-61.0 1 1,1-Dichloroethane 2.0 ug/L 12/27/16 18:06 75-34-31.0 1 1,2-Dichloroethane ND ug/L 12/27/16 18:06 107-06-21.0 1 1,1-Dichloroethene ND ug/L 12/27/16 18:06 75-35-41.0 1 cis-1,2-Dichloroethene 18.2 ug/L 12/27/16 18:06 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 12/27/16 18:06 156-60-51.0 1 1,2-Dichloropropane ND ug/L 12/27/16 18:06 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 12/27/16 18:06 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 12/27/16 18:06 10061-02-61.0 1 Ethylbenzene ND ug/L 12/27/16 18:06 100-41-41.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:3404-MW-4 Lab ID:92324275003 Collected:12/21/16 11:00 Received:12/21/16 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 2-Hexanone ND ug/L 12/27/16 18:06 591-78-65.0 1 Iodomethane ND ug/L 12/27/16 18:06 74-88-45.0 1 Methylene Chloride ND ug/L 12/27/16 18:06 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 12/27/16 18:06 108-10-15.0 1 Styrene ND ug/L 12/27/16 18:06 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 12/27/16 18:06 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 12/27/16 18:06 79-34-51.0 1 Tetrachloroethene ND ug/L 12/27/16 18:06 127-18-41.0 1 Toluene ND ug/L 12/27/16 18:06 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 12/27/16 18:06 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 12/27/16 18:06 79-00-51.0 1 Trichloroethene ND ug/L 12/27/16 18:06 79-01-61.0 1 Trichlorofluoromethane ND ug/L 12/27/16 18:06 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 12/27/16 18:06 96-18-41.0 1 Vinyl acetate ND ug/L 12/27/16 18:06 108-05-42.0 1 Vinyl chloride 14.5 ug/L 12/27/16 18:06 75-01-41.0 1 Xylene (Total)ND ug/L 12/27/16 18:06 1330-20-71.0 1 Surrogates 4-Bromofluorobenzene (S)101 %12/27/16 18:06 460-00-470-130 1 1,2-Dichloroethane-d4 (S)100 %12/27/16 18:06 17060-07-070-130 1 Toluene-d8 (S)99 %12/27/16 18:06 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:3404-SW-2 Lab ID:92324275004 Collected:12/21/16 10:40 Received:12/21/16 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 01/01/17 08:03 7440-36-012/28/16 20:455.0 1 Arsenic ND ug/L 01/01/17 08:03 7440-38-212/28/16 20:4510.0 1 Barium 31.0 ug/L 01/01/17 08:03 7440-39-312/28/16 20:455.0 1 Beryllium ND ug/L 01/01/17 08:03 7440-41-712/28/16 20:451.0 1 Cadmium ND ug/L 01/01/17 08:03 7440-43-912/28/16 20:451.0 1 Chromium ND ug/L 01/01/17 08:03 7440-47-312/28/16 20:455.0 1 Cobalt ND ug/L 01/01/17 08:03 7440-48-412/28/16 20:455.0 1 Copper ND ug/L 01/01/17 08:03 7440-50-812/28/16 20:455.0 1 Lead ND ug/L 01/01/17 08:03 7439-92-112/28/16 20:455.0 1 Nickel ND ug/L 01/01/17 08:03 7440-02-012/28/16 20:455.0 1 Selenium ND ug/L 01/01/17 08:03 7782-49-212/28/16 20:4510.0 1 Silver ND ug/L 01/01/17 08:03 7440-22-412/28/16 20:455.0 1 Thallium ND ug/L 01/01/17 08:03 7440-28-012/28/16 20:455.4 1 Vanadium ND ug/L 01/01/17 08:03 7440-62-212/28/16 20:455.0 1 Zinc ND ug/L 01/01/17 08:03 7440-66-612/28/16 20:4510.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 12/27/16 18:22 67-64-125.0 1 Acrylonitrile ND ug/L 12/27/16 18:22 107-13-110.0 1 Benzene ND ug/L 12/27/16 18:22 71-43-21.0 1 Bromochloromethane ND ug/L 12/27/16 18:22 74-97-51.0 1 Bromodichloromethane ND ug/L 12/27/16 18:22 75-27-41.0 1 Bromoform ND ug/L 12/27/16 18:22 75-25-21.0 1 Bromomethane ND ug/L 12/27/16 18:22 74-83-92.0 1 2-Butanone (MEK)ND ug/L 12/27/16 18:22 78-93-35.0 1 Carbon disulfide ND ug/L 12/27/16 18:22 75-15-02.0 1 Carbon tetrachloride ND ug/L 12/27/16 18:22 56-23-51.0 1 Chlorobenzene ND ug/L 12/27/16 18:22 108-90-71.0 1 Chloroethane ND ug/L 12/27/16 18:22 75-00-31.0 1 Chloroform ND ug/L 12/27/16 18:22 67-66-31.0 1 Chloromethane ND ug/L 12/27/16 18:22 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 12/27/16 18:22 96-12-82.0 1 Dibromochloromethane ND ug/L 12/27/16 18:22 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 12/27/16 18:22 106-93-41.0 1 Dibromomethane ND ug/L 12/27/16 18:22 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 12/27/16 18:22 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 12/27/16 18:22 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 12/27/16 18:22 110-57-61.0 1 1,1-Dichloroethane ND ug/L 12/27/16 18:22 75-34-31.0 1 1,2-Dichloroethane ND ug/L 12/27/16 18:22 107-06-21.0 1 1,1-Dichloroethene ND ug/L 12/27/16 18:22 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 12/27/16 18:22 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 12/27/16 18:22 156-60-51.0 1 1,2-Dichloropropane ND ug/L 12/27/16 18:22 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 12/27/16 18:22 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 12/27/16 18:22 10061-02-61.0 1 Ethylbenzene ND ug/L 12/27/16 18:22 100-41-41.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:3404-SW-2 Lab ID:92324275004 Collected:12/21/16 10:40 Received:12/21/16 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 2-Hexanone ND ug/L 12/27/16 18:22 591-78-65.0 1 Iodomethane ND ug/L 12/27/16 18:22 74-88-45.0 1 Methylene Chloride ND ug/L 12/27/16 18:22 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 12/27/16 18:22 108-10-15.0 1 Styrene ND ug/L 12/27/16 18:22 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 12/27/16 18:22 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 12/27/16 18:22 79-34-51.0 1 Tetrachloroethene ND ug/L 12/27/16 18:22 127-18-41.0 1 Toluene ND ug/L 12/27/16 18:22 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 12/27/16 18:22 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 12/27/16 18:22 79-00-51.0 1 Trichloroethene ND ug/L 12/27/16 18:22 79-01-61.0 1 Trichlorofluoromethane ND ug/L 12/27/16 18:22 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 12/27/16 18:22 96-18-41.0 1 Vinyl acetate ND ug/L 12/27/16 18:22 108-05-42.0 1 Vinyl chloride ND ug/L 12/27/16 18:22 75-01-41.0 1 Xylene (Total)ND ug/L 12/27/16 18:22 1330-20-71.0 1 Surrogates 4-Bromofluorobenzene (S)100 %12/27/16 18:22 460-00-470-130 1 1,2-Dichloroethane-d4 (S)101 %12/27/16 18:22 17060-07-070-130 1 Toluene-d8 (S)99 %12/27/16 18:22 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:3404-SW-1 Lab ID:92324275005 Collected:12/21/16 11:15 Received:12/21/16 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 01/01/17 08:06 7440-36-012/28/16 20:455.0 1 Arsenic ND ug/L 01/01/17 08:06 7440-38-212/28/16 20:4510.0 1 Barium 29.3 ug/L 01/01/17 08:06 7440-39-312/28/16 20:455.0 1 Beryllium ND ug/L 01/01/17 08:06 7440-41-712/28/16 20:451.0 1 Cadmium ND ug/L 01/01/17 08:06 7440-43-912/28/16 20:451.0 1 Chromium ND ug/L 01/01/17 08:06 7440-47-312/28/16 20:455.0 1 Cobalt ND ug/L 01/01/17 08:06 7440-48-412/28/16 20:455.0 1 Copper ND ug/L 01/01/17 08:06 7440-50-812/28/16 20:455.0 1 Lead ND ug/L 01/01/17 08:06 7439-92-112/28/16 20:455.0 1 Nickel ND ug/L 01/01/17 08:06 7440-02-012/28/16 20:455.0 1 Selenium ND ug/L 01/01/17 08:06 7782-49-212/28/16 20:4510.0 1 Silver ND ug/L 01/01/17 08:06 7440-22-412/28/16 20:455.0 1 Thallium ND ug/L 01/01/17 08:06 7440-28-012/28/16 20:455.4 1 Vanadium ND ug/L 01/01/17 08:06 7440-62-212/28/16 20:455.0 1 Zinc ND ug/L 01/01/17 08:06 7440-66-612/28/16 20:4510.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 12/27/16 18:38 67-64-125.0 1 Acrylonitrile ND ug/L 12/27/16 18:38 107-13-110.0 1 Benzene ND ug/L 12/27/16 18:38 71-43-21.0 1 Bromochloromethane ND ug/L 12/27/16 18:38 74-97-51.0 1 Bromodichloromethane ND ug/L 12/27/16 18:38 75-27-41.0 1 Bromoform ND ug/L 12/27/16 18:38 75-25-21.0 1 Bromomethane ND ug/L 12/27/16 18:38 74-83-92.0 1 2-Butanone (MEK)ND ug/L 12/27/16 18:38 78-93-35.0 1 Carbon disulfide ND ug/L 12/27/16 18:38 75-15-02.0 1 Carbon tetrachloride ND ug/L 12/27/16 18:38 56-23-51.0 1 Chlorobenzene ND ug/L 12/27/16 18:38 108-90-71.0 1 Chloroethane ND ug/L 12/27/16 18:38 75-00-31.0 1 Chloroform ND ug/L 12/27/16 18:38 67-66-31.0 1 Chloromethane ND ug/L 12/27/16 18:38 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 12/27/16 18:38 96-12-82.0 1 Dibromochloromethane ND ug/L 12/27/16 18:38 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 12/27/16 18:38 106-93-41.0 1 Dibromomethane ND ug/L 12/27/16 18:38 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 12/27/16 18:38 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 12/27/16 18:38 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 12/27/16 18:38 110-57-61.0 1 1,1-Dichloroethane ND ug/L 12/27/16 18:38 75-34-31.0 1 1,2-Dichloroethane ND ug/L 12/27/16 18:38 107-06-21.0 1 1,1-Dichloroethene ND ug/L 12/27/16 18:38 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 12/27/16 18:38 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 12/27/16 18:38 156-60-51.0 1 1,2-Dichloropropane ND ug/L 12/27/16 18:38 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 12/27/16 18:38 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 12/27/16 18:38 10061-02-61.0 1 Ethylbenzene ND ug/L 12/27/16 18:38 100-41-41.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:3404-SW-1 Lab ID:92324275005 Collected:12/21/16 11:15 Received:12/21/16 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 2-Hexanone ND ug/L 12/27/16 18:38 591-78-65.0 1 Iodomethane ND ug/L 12/27/16 18:38 74-88-45.0 1 Methylene Chloride ND ug/L 12/27/16 18:38 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 12/27/16 18:38 108-10-15.0 1 Styrene ND ug/L 12/27/16 18:38 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 12/27/16 18:38 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 12/27/16 18:38 79-34-51.0 1 Tetrachloroethene ND ug/L 12/27/16 18:38 127-18-41.0 1 Toluene ND ug/L 12/27/16 18:38 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 12/27/16 18:38 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 12/27/16 18:38 79-00-51.0 1 Trichloroethene ND ug/L 12/27/16 18:38 79-01-61.0 1 Trichlorofluoromethane ND ug/L 12/27/16 18:38 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 12/27/16 18:38 96-18-41.0 1 Vinyl acetate ND ug/L 12/27/16 18:38 108-05-42.0 1 Vinyl chloride ND ug/L 12/27/16 18:38 75-01-41.0 1 Xylene (Total)ND ug/L 12/27/16 18:38 1330-20-71.0 1 Surrogates 4-Bromofluorobenzene (S)100 %12/27/16 18:38 460-00-470-130 1 1,2-Dichloroethane-d4 (S)101 %12/27/16 18:38 17060-07-070-130 1 Toluene-d8 (S)100 %12/27/16 18:38 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:3404-SW-3 Lab ID:92324275006 Collected:12/21/16 11:10 Received:12/21/16 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 01/01/17 08:09 7440-36-012/28/16 20:455.0 1 Arsenic ND ug/L 01/01/17 08:09 7440-38-212/28/16 20:4510.0 1 Barium 36.4 ug/L 01/01/17 08:09 7440-39-312/28/16 20:455.0 1 Beryllium ND ug/L 01/01/17 08:09 7440-41-712/28/16 20:451.0 1 Cadmium ND ug/L 01/01/17 08:09 7440-43-912/28/16 20:451.0 1 Chromium ND ug/L 01/01/17 08:09 7440-47-312/28/16 20:455.0 1 Cobalt ND ug/L 01/01/17 08:09 7440-48-412/28/16 20:455.0 1 Copper ND ug/L 01/01/17 08:09 7440-50-812/28/16 20:455.0 1 Lead ND ug/L 01/01/17 08:09 7439-92-112/28/16 20:455.0 1 Nickel ND ug/L 01/01/17 08:09 7440-02-012/28/16 20:455.0 1 Selenium ND ug/L 01/01/17 08:09 7782-49-212/28/16 20:4510.0 1 Silver ND ug/L 01/01/17 08:09 7440-22-412/28/16 20:455.0 1 Thallium ND ug/L 01/01/17 08:09 7440-28-012/28/16 20:455.4 1 Vanadium ND ug/L 01/01/17 08:09 7440-62-212/28/16 20:455.0 1 Zinc ND ug/L 01/01/17 08:09 7440-66-612/28/16 20:4510.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 12/27/16 18:54 67-64-125.0 1 Acrylonitrile ND ug/L 12/27/16 18:54 107-13-110.0 1 Benzene ND ug/L 12/27/16 18:54 71-43-21.0 1 Bromochloromethane ND ug/L 12/27/16 18:54 74-97-51.0 1 Bromodichloromethane ND ug/L 12/27/16 18:54 75-27-41.0 1 Bromoform ND ug/L 12/27/16 18:54 75-25-21.0 1 Bromomethane ND ug/L 12/27/16 18:54 74-83-92.0 1 2-Butanone (MEK)ND ug/L 12/27/16 18:54 78-93-35.0 1 Carbon disulfide ND ug/L 12/27/16 18:54 75-15-02.0 1 Carbon tetrachloride ND ug/L 12/27/16 18:54 56-23-51.0 1 Chlorobenzene ND ug/L 12/27/16 18:54 108-90-71.0 1 Chloroethane ND ug/L 12/27/16 18:54 75-00-31.0 1 Chloroform ND ug/L 12/27/16 18:54 67-66-31.0 1 Chloromethane ND ug/L 12/27/16 18:54 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 12/27/16 18:54 96-12-82.0 1 Dibromochloromethane ND ug/L 12/27/16 18:54 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 12/27/16 18:54 106-93-41.0 1 Dibromomethane ND ug/L 12/27/16 18:54 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 12/27/16 18:54 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 12/27/16 18:54 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 12/27/16 18:54 110-57-61.0 1 1,1-Dichloroethane ND ug/L 12/27/16 18:54 75-34-31.0 1 1,2-Dichloroethane ND ug/L 12/27/16 18:54 107-06-21.0 1 1,1-Dichloroethene ND ug/L 12/27/16 18:54 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 12/27/16 18:54 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 12/27/16 18:54 156-60-51.0 1 1,2-Dichloropropane ND ug/L 12/27/16 18:54 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 12/27/16 18:54 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 12/27/16 18:54 10061-02-61.0 1 Ethylbenzene ND ug/L 12/27/16 18:54 100-41-41.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:3404-SW-3 Lab ID:92324275006 Collected:12/21/16 11:10 Received:12/21/16 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 2-Hexanone ND ug/L 12/27/16 18:54 591-78-65.0 1 Iodomethane ND ug/L 12/27/16 18:54 74-88-45.0 1 Methylene Chloride ND ug/L 12/27/16 18:54 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 12/27/16 18:54 108-10-15.0 1 Styrene ND ug/L 12/27/16 18:54 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 12/27/16 18:54 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 12/27/16 18:54 79-34-51.0 1 Tetrachloroethene ND ug/L 12/27/16 18:54 127-18-41.0 1 Toluene ND ug/L 12/27/16 18:54 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 12/27/16 18:54 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 12/27/16 18:54 79-00-51.0 1 Trichloroethene ND ug/L 12/27/16 18:54 79-01-61.0 1 Trichlorofluoromethane ND ug/L 12/27/16 18:54 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 12/27/16 18:54 96-18-41.0 1 Vinyl acetate ND ug/L 12/27/16 18:54 108-05-42.0 1 Vinyl chloride ND ug/L 12/27/16 18:54 75-01-41.0 1 Xylene (Total)ND ug/L 12/27/16 18:54 1330-20-71.0 1 Surrogates 4-Bromofluorobenzene (S)102 %12/27/16 18:54 460-00-470-130 1 1,2-Dichloroethane-d4 (S)101 %12/27/16 18:54 17060-07-070-130 1 Toluene-d8 (S)99 %12/27/16 18:54 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:3404-MW-2 Lab ID:92324275007 Collected:12/21/16 11:40 Received:12/21/16 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 01/01/17 08:12 7440-36-012/28/16 20:455.0 1 Arsenic ND ug/L 01/01/17 08:12 7440-38-212/28/16 20:4510.0 1 Barium 262 ug/L 01/01/17 08:12 7440-39-312/28/16 20:455.0 1 Beryllium ND ug/L 01/01/17 08:12 7440-41-712/28/16 20:451.0 1 Cadmium ND ug/L 01/01/17 08:12 7440-43-912/28/16 20:451.0 1 Chromium ND ug/L 01/01/17 08:12 7440-47-312/28/16 20:455.0 1 Cobalt ND ug/L 01/01/17 08:12 7440-48-412/28/16 20:455.0 1 Copper ND ug/L 01/01/17 08:12 7440-50-812/28/16 20:455.0 1 Lead ND ug/L 01/01/17 08:12 7439-92-112/28/16 20:455.0 1 Nickel ND ug/L 01/01/17 08:12 7440-02-012/28/16 20:455.0 1 Selenium ND ug/L 01/01/17 08:12 7782-49-212/28/16 20:4510.0 1 Silver ND ug/L 01/01/17 08:12 7440-22-412/28/16 20:455.0 1 Thallium ND ug/L 01/01/17 08:12 7440-28-012/28/16 20:455.4 1 Vanadium ND ug/L 01/01/17 08:12 7440-62-212/28/16 20:455.0 1 Zinc ND ug/L 01/01/17 08:12 7440-66-612/28/16 20:4510.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 12/27/16 19:10 67-64-125.0 1 Acrylonitrile ND ug/L 12/27/16 19:10 107-13-110.0 1 Benzene 4.2 ug/L 12/27/16 19:10 71-43-21.0 1 Bromochloromethane ND ug/L 12/27/16 19:10 74-97-51.0 1 Bromodichloromethane ND ug/L 12/27/16 19:10 75-27-41.0 1 Bromoform ND ug/L 12/27/16 19:10 75-25-21.0 1 Bromomethane ND ug/L 12/27/16 19:10 74-83-92.0 1 2-Butanone (MEK)ND ug/L 12/27/16 19:10 78-93-35.0 1 Carbon disulfide ND ug/L 12/27/16 19:10 75-15-02.0 1 Carbon tetrachloride ND ug/L 12/27/16 19:10 56-23-51.0 1 Chlorobenzene ND ug/L 12/27/16 19:10 108-90-71.0 1 Chloroethane ND ug/L 12/27/16 19:10 75-00-31.0 1 Chloroform ND ug/L 12/27/16 19:10 67-66-31.0 1 Chloromethane ND ug/L 12/27/16 19:10 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 12/27/16 19:10 96-12-82.0 1 Dibromochloromethane ND ug/L 12/27/16 19:10 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 12/27/16 19:10 106-93-41.0 1 Dibromomethane ND ug/L 12/27/16 19:10 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 12/27/16 19:10 95-50-11.0 1 1,4-Dichlorobenzene 3.8 ug/L 12/27/16 19:10 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 12/27/16 19:10 110-57-61.0 1 1,1-Dichloroethane 16.8 ug/L 12/27/16 19:10 75-34-31.0 1 1,2-Dichloroethane ND ug/L 12/27/16 19:10 107-06-21.0 1 1,1-Dichloroethene ND ug/L 12/27/16 19:10 75-35-41.0 1 cis-1,2-Dichloroethene 37.2 ug/L 12/27/16 19:10 156-59-21.0 1 trans-1,2-Dichloroethene 1.2 ug/L 12/27/16 19:10 156-60-51.0 1 1,2-Dichloropropane 4.0 ug/L 12/27/16 19:10 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 12/27/16 19:10 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 12/27/16 19:10 10061-02-61.0 1 Ethylbenzene ND ug/L 12/27/16 19:10 100-41-41.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:3404-MW-2 Lab ID:92324275007 Collected:12/21/16 11:40 Received:12/21/16 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 2-Hexanone ND ug/L 12/27/16 19:10 591-78-65.0 1 Iodomethane ND ug/L 12/27/16 19:10 74-88-45.0 1 Methylene Chloride ND ug/L 12/27/16 19:10 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 12/27/16 19:10 108-10-15.0 1 Styrene ND ug/L 12/27/16 19:10 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 12/27/16 19:10 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 12/27/16 19:10 79-34-51.0 1 Tetrachloroethene ND ug/L 12/27/16 19:10 127-18-41.0 1 Toluene ND ug/L 12/27/16 19:10 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 12/27/16 19:10 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 12/27/16 19:10 79-00-51.0 1 Trichloroethene 4.2 ug/L 12/27/16 19:10 79-01-61.0 1 Trichlorofluoromethane ND ug/L 12/27/16 19:10 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 12/27/16 19:10 96-18-41.0 1 Vinyl acetate ND ug/L 12/27/16 19:10 108-05-42.0 1 Vinyl chloride 3.2 ug/L 12/27/16 19:10 75-01-41.0 1 Xylene (Total)ND ug/L 12/27/16 19:10 1330-20-71.0 1 Surrogates 4-Bromofluorobenzene (S)103 %12/27/16 19:10 460-00-470-130 1 1,2-Dichloroethane-d4 (S)101 %12/27/16 19:10 17060-07-070-130 1 Toluene-d8 (S)99 %12/27/16 19:10 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:Duplicate Lab ID:92324275008 Collected:12/22/16 09:45 Received:12/22/16 14:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 01/01/17 08:15 7440-36-012/28/16 20:455.0 1 Arsenic ND ug/L 01/01/17 08:15 7440-38-212/28/16 20:4510.0 1 Barium 110 ug/L 01/01/17 08:15 7440-39-312/28/16 20:455.0 1 Beryllium ND ug/L 01/01/17 08:15 7440-41-712/28/16 20:451.0 1 Cadmium ND ug/L 01/01/17 08:15 7440-43-912/28/16 20:451.0 1 Chromium ND ug/L 01/01/17 08:15 7440-47-312/28/16 20:455.0 1 Cobalt ND ug/L 01/01/17 08:15 7440-48-412/28/16 20:455.0 1 Copper ND ug/L 01/01/17 08:15 7440-50-812/28/16 20:455.0 1 Lead 5.0 ug/L 01/01/17 08:15 7439-92-112/28/16 20:455.0 1 Nickel ND ug/L 01/01/17 08:15 7440-02-012/28/16 20:455.0 1 Selenium ND ug/L 01/01/17 08:15 7782-49-212/28/16 20:4510.0 1 Silver ND ug/L 01/01/17 08:15 7440-22-412/28/16 20:455.0 1 Thallium ND ug/L 01/01/17 08:15 7440-28-012/28/16 20:455.4 1 Vanadium 7.0 ug/L 01/01/17 08:15 7440-62-212/28/16 20:455.0 1 Zinc 16.0 ug/L 01/01/17 08:15 7440-66-612/28/16 20:4510.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 12/27/16 22:07 67-64-125.0 1 Acrylonitrile ND ug/L 12/27/16 22:07 107-13-110.0 1 Benzene ND ug/L 12/27/16 22:07 71-43-21.0 1 Bromochloromethane ND ug/L 12/27/16 22:07 74-97-51.0 1 Bromodichloromethane ND ug/L 12/27/16 22:07 75-27-41.0 1 Bromoform ND ug/L 12/27/16 22:07 75-25-21.0 1 Bromomethane ND ug/L 12/27/16 22:07 74-83-92.0 1 2-Butanone (MEK)ND ug/L 12/27/16 22:07 78-93-35.0 1 Carbon disulfide ND ug/L 12/27/16 22:07 75-15-02.0 1 Carbon tetrachloride ND ug/L 12/27/16 22:07 56-23-51.0 1 Chlorobenzene ND ug/L 12/27/16 22:07 108-90-71.0 1 Chloroethane ND ug/L 12/27/16 22:07 75-00-31.0 1 Chloroform ND ug/L 12/27/16 22:07 67-66-31.0 1 Chloromethane ND ug/L 12/27/16 22:07 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 12/27/16 22:07 96-12-82.0 1 Dibromochloromethane ND ug/L 12/27/16 22:07 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 12/27/16 22:07 106-93-41.0 1 Dibromomethane ND ug/L 12/27/16 22:07 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 12/27/16 22:07 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 12/27/16 22:07 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 12/27/16 22:07 110-57-61.0 1 1,1-Dichloroethane ND ug/L 12/27/16 22:07 75-34-31.0 1 1,2-Dichloroethane ND ug/L 12/27/16 22:07 107-06-21.0 1 1,1-Dichloroethene ND ug/L 12/27/16 22:07 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 12/27/16 22:07 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 12/27/16 22:07 156-60-51.0 1 1,2-Dichloropropane ND ug/L 12/27/16 22:07 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 12/27/16 22:07 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 12/27/16 22:07 10061-02-61.0 1 Ethylbenzene ND ug/L 12/27/16 22:07 100-41-41.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:Duplicate Lab ID:92324275008 Collected:12/22/16 09:45 Received:12/22/16 14:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 2-Hexanone ND ug/L 12/27/16 22:07 591-78-65.0 1 Iodomethane ND ug/L 12/27/16 22:07 74-88-45.0 1 Methylene Chloride ND ug/L 12/27/16 22:07 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 12/27/16 22:07 108-10-15.0 1 Styrene ND ug/L 12/27/16 22:07 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 12/27/16 22:07 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 12/27/16 22:07 79-34-51.0 1 Tetrachloroethene ND ug/L 12/27/16 22:07 127-18-41.0 1 Toluene ND ug/L 12/27/16 22:07 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 12/27/16 22:07 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 12/27/16 22:07 79-00-51.0 1 Trichloroethene ND ug/L 12/27/16 22:07 79-01-61.0 1 Trichlorofluoromethane ND ug/L 12/27/16 22:07 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 12/27/16 22:07 96-18-41.0 1 Vinyl acetate ND ug/L 12/27/16 22:07 108-05-42.0 1 Vinyl chloride ND ug/L 12/27/16 22:07 75-01-41.0 1 Xylene (Total)ND ug/L 12/27/16 22:07 1330-20-71.0 1 Surrogates 4-Bromofluorobenzene (S)100 %12/27/16 22:07 460-00-470-130 1 1,2-Dichloroethane-d4 (S)101 %12/27/16 22:07 17060-07-070-130 1 Toluene-d8 (S)100 %12/27/16 22:07 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:3404-MW-5 Lab ID:92324275009 Collected:12/22/16 08:40 Received:12/22/16 14:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 01/01/17 08:18 7440-36-012/28/16 20:455.0 1 Arsenic ND ug/L 01/01/17 08:18 7440-38-212/28/16 20:4510.0 1 Barium 58.6 ug/L 01/01/17 08:18 7440-39-312/28/16 20:455.0 1 Beryllium ND ug/L 01/01/17 08:18 7440-41-712/28/16 20:451.0 1 Cadmium ND ug/L 01/01/17 08:18 7440-43-912/28/16 20:451.0 1 Chromium ND ug/L 01/01/17 08:18 7440-47-312/28/16 20:455.0 1 Cobalt ND ug/L 01/01/17 08:18 7440-48-412/28/16 20:455.0 1 Copper ND ug/L 01/01/17 08:18 7440-50-812/28/16 20:455.0 1 Lead ND ug/L 01/01/17 08:18 7439-92-112/28/16 20:455.0 1 Nickel ND ug/L 01/01/17 08:18 7440-02-012/28/16 20:455.0 1 Selenium ND ug/L 01/01/17 08:18 7782-49-212/28/16 20:4510.0 1 Silver ND ug/L 01/01/17 08:18 7440-22-412/28/16 20:455.0 1 Thallium ND ug/L 01/01/17 08:18 7440-28-012/28/16 20:455.4 1 Vanadium ND ug/L 01/01/17 08:18 7440-62-212/28/16 20:455.0 1 Zinc 13.4 ug/L 01/01/17 08:18 7440-66-612/28/16 20:4510.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 12/27/16 22:23 67-64-125.0 1 Acrylonitrile ND ug/L 12/27/16 22:23 107-13-110.0 1 Benzene ND ug/L 12/27/16 22:23 71-43-21.0 1 Bromochloromethane ND ug/L 12/27/16 22:23 74-97-51.0 1 Bromodichloromethane ND ug/L 12/27/16 22:23 75-27-41.0 1 Bromoform ND ug/L 12/27/16 22:23 75-25-21.0 1 Bromomethane ND ug/L 12/27/16 22:23 74-83-92.0 1 2-Butanone (MEK)ND ug/L 12/27/16 22:23 78-93-35.0 1 Carbon disulfide ND ug/L 12/27/16 22:23 75-15-02.0 1 Carbon tetrachloride ND ug/L 12/27/16 22:23 56-23-51.0 1 Chlorobenzene ND ug/L 12/27/16 22:23 108-90-71.0 1 Chloroethane ND ug/L 12/27/16 22:23 75-00-31.0 1 Chloroform ND ug/L 12/27/16 22:23 67-66-31.0 1 Chloromethane ND ug/L 12/27/16 22:23 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 12/27/16 22:23 96-12-82.0 1 Dibromochloromethane ND ug/L 12/27/16 22:23 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 12/27/16 22:23 106-93-41.0 1 Dibromomethane ND ug/L 12/27/16 22:23 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 12/27/16 22:23 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 12/27/16 22:23 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 12/27/16 22:23 110-57-61.0 1 1,1-Dichloroethane ND ug/L 12/27/16 22:23 75-34-31.0 1 1,2-Dichloroethane ND ug/L 12/27/16 22:23 107-06-21.0 1 1,1-Dichloroethene ND ug/L 12/27/16 22:23 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 12/27/16 22:23 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 12/27/16 22:23 156-60-51.0 1 1,2-Dichloropropane ND ug/L 12/27/16 22:23 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 12/27/16 22:23 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 12/27/16 22:23 10061-02-61.0 1 Ethylbenzene ND ug/L 12/27/16 22:23 100-41-41.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:3404-MW-5 Lab ID:92324275009 Collected:12/22/16 08:40 Received:12/22/16 14:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 2-Hexanone ND ug/L 12/27/16 22:23 591-78-65.0 1 Iodomethane ND ug/L 12/27/16 22:23 74-88-45.0 1 Methylene Chloride ND ug/L 12/27/16 22:23 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 12/27/16 22:23 108-10-15.0 1 Styrene ND ug/L 12/27/16 22:23 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 12/27/16 22:23 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 12/27/16 22:23 79-34-51.0 1 Tetrachloroethene ND ug/L 12/27/16 22:23 127-18-41.0 1 Toluene ND ug/L 12/27/16 22:23 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 12/27/16 22:23 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 12/27/16 22:23 79-00-51.0 1 Trichloroethene ND ug/L 12/27/16 22:23 79-01-61.0 1 Trichlorofluoromethane ND ug/L 12/27/16 22:23 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 12/27/16 22:23 96-18-41.0 1 Vinyl acetate ND ug/L 12/27/16 22:23 108-05-42.0 1 Vinyl chloride ND ug/L 12/27/16 22:23 75-01-41.0 1 Xylene (Total)ND ug/L 12/27/16 22:23 1330-20-71.0 1 Surrogates 4-Bromofluorobenzene (S)101 %12/27/16 22:23 460-00-470-130 1 1,2-Dichloroethane-d4 (S)103 %12/27/16 22:23 17060-07-070-130 1 Toluene-d8 (S)99 %12/27/16 22:23 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:3404-MW-6 Lab ID:92324275010 Collected:12/22/16 09:15 Received:12/22/16 14:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 01/01/17 08:21 7440-36-012/28/16 20:455.0 1 Arsenic ND ug/L 01/01/17 08:21 7440-38-212/28/16 20:4510.0 1 Barium 108 ug/L 01/01/17 08:21 7440-39-312/28/16 20:455.0 1 Beryllium ND ug/L 01/01/17 08:21 7440-41-712/28/16 20:451.0 1 Cadmium ND ug/L 01/01/17 08:21 7440-43-912/28/16 20:451.0 1 Chromium ND ug/L 01/01/17 08:21 7440-47-312/28/16 20:455.0 1 Cobalt ND ug/L 01/01/17 08:21 7440-48-412/28/16 20:455.0 1 Copper ND ug/L 01/01/17 08:21 7440-50-812/28/16 20:455.0 1 Lead 6.0 ug/L 01/01/17 08:21 7439-92-112/28/16 20:455.0 1 Nickel ND ug/L 01/01/17 08:21 7440-02-012/28/16 20:455.0 1 Selenium ND ug/L 01/01/17 08:21 7782-49-212/28/16 20:4510.0 1 Silver ND ug/L 01/01/17 08:21 7440-22-412/28/16 20:455.0 1 Thallium ND ug/L 01/01/17 08:21 7440-28-012/28/16 20:455.4 1 Vanadium 6.8 ug/L 01/01/17 08:21 7440-62-212/28/16 20:455.0 1 Zinc 14.3 ug/L 01/01/17 08:21 7440-66-612/28/16 20:4510.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 12/27/16 22:38 67-64-125.0 1 Acrylonitrile ND ug/L 12/27/16 22:38 107-13-110.0 1 Benzene ND ug/L 12/27/16 22:38 71-43-21.0 1 Bromochloromethane ND ug/L 12/27/16 22:38 74-97-51.0 1 Bromodichloromethane ND ug/L 12/27/16 22:38 75-27-41.0 1 Bromoform ND ug/L 12/27/16 22:38 75-25-21.0 1 Bromomethane ND ug/L 12/27/16 22:38 74-83-92.0 1 2-Butanone (MEK)ND ug/L 12/27/16 22:38 78-93-35.0 1 Carbon disulfide ND ug/L 12/27/16 22:38 75-15-02.0 1 Carbon tetrachloride ND ug/L 12/27/16 22:38 56-23-51.0 1 Chlorobenzene ND ug/L 12/27/16 22:38 108-90-71.0 1 Chloroethane ND ug/L 12/27/16 22:38 75-00-31.0 1 Chloroform ND ug/L 12/27/16 22:38 67-66-31.0 1 Chloromethane ND ug/L 12/27/16 22:38 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 12/27/16 22:38 96-12-82.0 1 Dibromochloromethane ND ug/L 12/27/16 22:38 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 12/27/16 22:38 106-93-41.0 1 Dibromomethane ND ug/L 12/27/16 22:38 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 12/27/16 22:38 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 12/27/16 22:38 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 12/27/16 22:38 110-57-61.0 1 1,1-Dichloroethane ND ug/L 12/27/16 22:38 75-34-31.0 1 1,2-Dichloroethane ND ug/L 12/27/16 22:38 107-06-21.0 1 1,1-Dichloroethene ND ug/L 12/27/16 22:38 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 12/27/16 22:38 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 12/27/16 22:38 156-60-51.0 1 1,2-Dichloropropane ND ug/L 12/27/16 22:38 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 12/27/16 22:38 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 12/27/16 22:38 10061-02-61.0 1 Ethylbenzene ND ug/L 12/27/16 22:38 100-41-41.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:3404-MW-6 Lab ID:92324275010 Collected:12/22/16 09:15 Received:12/22/16 14:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 2-Hexanone ND ug/L 12/27/16 22:38 591-78-65.0 1 Iodomethane ND ug/L 12/27/16 22:38 74-88-45.0 1 Methylene Chloride ND ug/L 12/27/16 22:38 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 12/27/16 22:38 108-10-15.0 1 Styrene ND ug/L 12/27/16 22:38 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 12/27/16 22:38 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 12/27/16 22:38 79-34-51.0 1 Tetrachloroethene ND ug/L 12/27/16 22:38 127-18-41.0 1 Toluene ND ug/L 12/27/16 22:38 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 12/27/16 22:38 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 12/27/16 22:38 79-00-51.0 1 Trichloroethene ND ug/L 12/27/16 22:38 79-01-61.0 1 Trichlorofluoromethane ND ug/L 12/27/16 22:38 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 12/27/16 22:38 96-18-41.0 1 Vinyl acetate ND ug/L 12/27/16 22:38 108-05-42.0 1 Vinyl chloride ND ug/L 12/27/16 22:38 75-01-41.0 1 Xylene (Total)ND ug/L 12/27/16 22:38 1330-20-71.0 1 Surrogates 4-Bromofluorobenzene (S)100 %12/27/16 22:38 460-00-470-130 1 1,2-Dichloroethane-d4 (S)101 %12/27/16 22:38 17060-07-070-130 1 Toluene-d8 (S)99 %12/27/16 22:38 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:3404-Field Blank Lab ID:92324275011 Collected:12/22/16 10:30 Received:12/22/16 14:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater Antimony ND ug/L 01/01/17 08:24 7440-36-012/28/16 20:455.0 1 Arsenic ND ug/L 01/01/17 08:24 7440-38-212/28/16 20:4510.0 1 Barium ND ug/L 01/01/17 08:24 7440-39-312/28/16 20:455.0 1 Beryllium ND ug/L 01/01/17 08:24 7440-41-712/28/16 20:451.0 1 Cadmium ND ug/L 01/01/17 08:24 7440-43-912/28/16 20:451.0 1 Chromium ND ug/L 01/01/17 08:24 7440-47-312/28/16 20:455.0 1 Cobalt ND ug/L 01/01/17 08:24 7440-48-412/28/16 20:455.0 1 Copper ND ug/L 01/01/17 08:24 7440-50-812/28/16 20:455.0 1 Lead ND ug/L 01/01/17 08:24 7439-92-112/28/16 20:455.0 1 Nickel ND ug/L 01/01/17 08:24 7440-02-012/28/16 20:455.0 1 Selenium ND ug/L 01/01/17 08:24 7782-49-212/28/16 20:4510.0 1 Silver ND ug/L 01/01/17 08:24 7440-22-412/28/16 20:455.0 1 Thallium ND ug/L 01/01/17 08:24 7440-28-012/28/16 20:455.4 1 Vanadium ND ug/L 01/01/17 08:24 7440-62-212/28/16 20:455.0 1 Zinc 13.3 ug/L 01/01/17 08:24 7440-66-612/28/16 20:4510.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 12/27/16 22:55 67-64-125.0 1 Acrylonitrile ND ug/L 12/27/16 22:55 107-13-110.0 1 Benzene ND ug/L 12/27/16 22:55 71-43-21.0 1 Bromochloromethane ND ug/L 12/27/16 22:55 74-97-51.0 1 Bromodichloromethane ND ug/L 12/27/16 22:55 75-27-41.0 1 Bromoform ND ug/L 12/27/16 22:55 75-25-21.0 1 Bromomethane ND ug/L 12/27/16 22:55 74-83-92.0 1 2-Butanone (MEK)ND ug/L 12/27/16 22:55 78-93-35.0 1 Carbon disulfide ND ug/L 12/27/16 22:55 75-15-02.0 1 Carbon tetrachloride ND ug/L 12/27/16 22:55 56-23-51.0 1 Chlorobenzene ND ug/L 12/27/16 22:55 108-90-71.0 1 Chloroethane ND ug/L 12/27/16 22:55 75-00-31.0 1 Chloroform ND ug/L 12/27/16 22:55 67-66-31.0 1 Chloromethane ND ug/L 12/27/16 22:55 74-87-31.0 1 1,2-Dibromo-3-chloropropane ND ug/L 12/27/16 22:55 96-12-82.0 1 Dibromochloromethane ND ug/L 12/27/16 22:55 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 12/27/16 22:55 106-93-41.0 1 Dibromomethane ND ug/L 12/27/16 22:55 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 12/27/16 22:55 95-50-11.0 1 1,4-Dichlorobenzene ND ug/L 12/27/16 22:55 106-46-71.0 1 trans-1,4-Dichloro-2-butene ND ug/L 12/27/16 22:55 110-57-61.0 1 1,1-Dichloroethane ND ug/L 12/27/16 22:55 75-34-31.0 1 1,2-Dichloroethane ND ug/L 12/27/16 22:55 107-06-21.0 1 1,1-Dichloroethene ND ug/L 12/27/16 22:55 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 12/27/16 22:55 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 12/27/16 22:55 156-60-51.0 1 1,2-Dichloropropane ND ug/L 12/27/16 22:55 78-87-51.0 1 cis-1,3-Dichloropropene ND ug/L 12/27/16 22:55 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 12/27/16 22:55 10061-02-61.0 1 Ethylbenzene ND ug/L 12/27/16 22:55 100-41-41.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92324275 Town of Kernersville Sample:3404-Field Blank Lab ID:92324275011 Collected:12/22/16 10:30 Received:12/22/16 14:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Low Level Landfill 2-Hexanone ND ug/L 12/27/16 22:55 591-78-65.0 1 Iodomethane ND ug/L 12/27/16 22:55 74-88-45.0 1 Methylene Chloride ND ug/L 12/27/16 22:55 75-09-21.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 12/27/16 22:55 108-10-15.0 1 Styrene ND ug/L 12/27/16 22:55 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 12/27/16 22:55 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 12/27/16 22:55 79-34-51.0 1 Tetrachloroethene ND ug/L 12/27/16 22:55 127-18-41.0 1 Toluene ND ug/L 12/27/16 22:55 108-88-31.0 1 1,1,1-Trichloroethane ND ug/L 12/27/16 22:55 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 12/27/16 22:55 79-00-51.0 1 Trichloroethene ND ug/L 12/27/16 22:55 79-01-61.0 1 Trichlorofluoromethane ND ug/L 12/27/16 22:55 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 12/27/16 22:55 96-18-41.0 1 Vinyl acetate ND ug/L 12/27/16 22:55 108-05-42.0 1 Vinyl chloride ND ug/L 12/27/16 22:55 75-01-41.0 1 Xylene (Total)ND ug/L 12/27/16 22:55 1330-20-71.0 1 Surrogates 4-Bromofluorobenzene (S)99 %12/27/16 22:55 460-00-470-130 1 1,2-Dichloroethane-d4 (S)100 %12/27/16 22:55 17060-07-070-130 1 Toluene-d8 (S)99 %12/27/16 22:55 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324275 Town of Kernersville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 342311 EPA 3010A EPA 6010 6010 MET NC Groundwater Associated Lab Samples:92324275001, 92324275002, 92324275003, 92324275004, 92324275005, 92324275006, 92324275007, 92324275008, 92324275009, 92324275010, 92324275011 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1899183 Associated Lab Samples:92324275001, 92324275002, 92324275003, 92324275004, 92324275005, 92324275006, 92324275007, 92324275008, 92324275009, 92324275010, 92324275011 Matrix:Water Analyzed Antimony ug/L ND 5.0 01/01/17 06:59 Arsenic ug/L ND 10.0 01/01/17 06:59 Barium ug/L ND 5.0 01/01/17 06:59 Beryllium ug/L ND 1.0 01/01/17 06:59 Cadmium ug/L ND 1.0 01/01/17 06:59 Chromium ug/L ND 5.0 01/01/17 06:59 Cobalt ug/L ND 5.0 01/01/17 06:59 Copper ug/L ND 5.0 01/01/17 06:59 Lead ug/L ND 5.0 01/01/17 06:59 Nickel ug/L ND 5.0 01/01/17 06:59 Selenium ug/L ND 10.0 01/01/17 06:59 Silver ug/L ND 5.0 01/01/17 06:59 Thallium ug/L ND 5.4 01/01/17 06:59 Vanadium ug/L ND 5.0 01/01/17 06:59 Zinc ug/L ND 10.0 01/01/17 06:59 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1899184LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 502500 100 80-120 Arsenic ug/L 485500 97 80-120 Barium ug/L 496500 99 80-120 Beryllium ug/L 484500 97 80-120 Cadmium ug/L 490500 98 80-120 Chromium ug/L 477500 95 80-120 Cobalt ug/L 496500 99 80-120 Copper ug/L 520500 104 80-120 Lead ug/L 486500 97 80-120 Nickel ug/L 480500 96 80-120 Selenium ug/L 507500 101 80-120 Silver ug/L 251250 100 80-120 Thallium ug/L 486500 97 80-120 Vanadium ug/L 482500 96 80-120 Zinc ug/L 482500 96 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324275 Town of Kernersville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1901202MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92323984001 1901203 MSD Result MSD % Rec RPD MSDMS Spike Conc. Antimony ug/L 500 105 75-125105 0500ND526526 Arsenic ug/L 500 102 75-125102 0500ND508508 Barium ug/L 500 104 75-125105 150019.5 539 544 Beryllium ug/L 500 101 75-125101 1500ND503506 Cadmium ug/L 500 103 75-125102 1500ND515512 Chromium ug/L 500 99 75-125100 1500ND496503 Cobalt ug/L 500 104 75-125103 1500ND521518 Copper ug/L 500 108 75-125109 1500ND542547 Lead ug/L 500 102 75-125101 1500ND510505 Nickel ug/L 500 101 75-125100 1500ND506501 Selenium ug/L 500 105 75-125105 0500ND527526 Silver ug/L 250 104 75-125105 0250ND261262 Thallium ug/L 500 103 75-125102 1500ND516511 Vanadium ug/L 500 101 75-125101 1500ND504507 Zinc ug/L 500 101 75-125101 1500ND508506 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324275 Town of Kernersville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 342559 EPA 8260 EPA 8260 8260 MSV Low Level Landfill Associated Lab Samples:92324275001, 92324275002, 92324275003, 92324275004, 92324275005, 92324275006, 92324275007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1900328 Associated Lab Samples:92324275001, 92324275002, 92324275003, 92324275004, 92324275005, 92324275006, 92324275007 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/27/16 15:10 1,1,1-Trichloroethane ug/L ND 1.0 12/27/16 15:10 1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/27/16 15:10 1,1,2-Trichloroethane ug/L ND 1.0 12/27/16 15:10 1,1-Dichloroethane ug/L ND 1.0 12/27/16 15:10 1,1-Dichloroethene ug/L ND 1.0 12/27/16 15:10 1,2,3-Trichloropropane ug/L ND 1.0 12/27/16 15:10 1,2-Dibromo-3-chloropropane ug/L ND 2.0 12/27/16 15:10 1,2-Dibromoethane (EDB)ug/L ND 1.0 12/27/16 15:10 1,2-Dichlorobenzene ug/L ND 1.0 12/27/16 15:10 1,2-Dichloroethane ug/L ND 1.0 12/27/16 15:10 1,2-Dichloropropane ug/L ND 1.0 12/27/16 15:10 1,4-Dichlorobenzene ug/L ND 1.0 12/27/16 15:10 2-Butanone (MEK)ug/L ND 5.0 12/27/16 15:10 2-Hexanone ug/L ND 5.0 12/27/16 15:10 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/27/16 15:10 Acetone ug/L ND 25.0 12/27/16 15:10 Acrylonitrile ug/L ND 10.0 12/27/16 15:10 Benzene ug/L ND 1.0 12/27/16 15:10 Bromochloromethane ug/L ND 1.0 12/27/16 15:10 Bromodichloromethane ug/L ND 1.0 12/27/16 15:10 Bromoform ug/L ND 1.0 12/27/16 15:10 Bromomethane ug/L ND 2.0 12/27/16 15:10 Carbon disulfide ug/L ND 2.0 12/27/16 15:10 Carbon tetrachloride ug/L ND 1.0 12/27/16 15:10 Chlorobenzene ug/L ND 1.0 12/27/16 15:10 Chloroethane ug/L ND 1.0 12/27/16 15:10 Chloroform ug/L ND 1.0 12/27/16 15:10 Chloromethane ug/L ND 1.0 12/27/16 15:10 cis-1,2-Dichloroethene ug/L ND 1.0 12/27/16 15:10 cis-1,3-Dichloropropene ug/L ND 1.0 12/27/16 15:10 Dibromochloromethane ug/L ND 1.0 12/27/16 15:10 Dibromomethane ug/L ND 1.0 12/27/16 15:10 Ethylbenzene ug/L ND 1.0 12/27/16 15:10 Iodomethane ug/L ND 5.0 12/27/16 15:10 Methylene Chloride ug/L ND 1.0 12/27/16 15:10 Styrene ug/L ND 1.0 12/27/16 15:10 Tetrachloroethene ug/L ND 1.0 12/27/16 15:10 Toluene ug/L ND 1.0 12/27/16 15:10 trans-1,2-Dichloroethene ug/L ND 1.0 12/27/16 15:10 trans-1,3-Dichloropropene ug/L ND 1.0 12/27/16 15:10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324275 Town of Kernersville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1900328 Associated Lab Samples:92324275001, 92324275002, 92324275003, 92324275004, 92324275005, 92324275006, 92324275007 Matrix:Water Analyzed trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/27/16 15:10 Trichloroethene ug/L ND 1.0 12/27/16 15:10 Trichlorofluoromethane ug/L ND 1.0 12/27/16 15:10 Vinyl acetate ug/L ND 2.0 12/27/16 15:10 Vinyl chloride ug/L ND 1.0 12/27/16 15:10 Xylene (Total)ug/L ND 1.0 12/27/16 15:10 1,2-Dichloroethane-d4 (S)%96 70-130 12/27/16 15:10 4-Bromofluorobenzene (S)%100 70-130 12/27/16 15:10 Toluene-d8 (S)%99 70-130 12/27/16 15:10 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1900329LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 51.350 103 80-125 1,1,1-Trichloroethane ug/L 50.750 101 71-129 1,1,2,2-Tetrachloroethane ug/L 51.150 102 79-124 1,1,2-Trichloroethane ug/L 52.850 106 85-125 1,1-Dichloroethane ug/L 51.550 103 73-126 1,1-Dichloroethene ug/L 54.650 109 66-135 1,2,3-Trichloropropane ug/L 49.050 98 75-130 1,2-Dibromo-3-chloropropane ug/L 48.850 98 71-133 1,2-Dibromoethane (EDB)ug/L 50.450 101 83-124 1,2-Dichlorobenzene ug/L 52.050 104 80-133 1,2-Dichloroethane ug/L 47.650 95 67-128 1,2-Dichloropropane ug/L 53.950 108 75-132 1,4-Dichlorobenzene ug/L 50.550 101 78-130 2-Butanone (MEK)ug/L 86.7100 87 61-144 2-Hexanone ug/L 101100 101 68-143 4-Methyl-2-pentanone (MIBK)ug/L 103100 103 72-135 Acetone ug/L 86.7100 87 48-146 Acrylonitrile ug/L 262250 105 40-160 Benzene ug/L 53.950 108 80-125 Bromochloromethane ug/L 51.050 102 71-125 Bromodichloromethane ug/L 54.550 109 78-124 Bromoform ug/L 50.750 101 71-128 Bromomethane ug/L 49.050 98 40-160 Carbon disulfide ug/L 53.950 108 50-160 Carbon tetrachloride ug/L 52.350 105 69-131 Chlorobenzene ug/L 52.350 105 81-122 Chloroethane ug/L 54.350 109 39-148 Chloroform ug/L 49.950 100 73-127 Chloromethane ug/L 52.250 104 44-146 cis-1,2-Dichloroethene ug/L 50.150 100 74-124 cis-1,3-Dichloropropene ug/L 54.350 109 72-132 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324275 Town of Kernersville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1900329LABORATORY CONTROL SAMPLE: LCSSpike Dibromochloromethane ug/L 52.350 105 78-125 Dibromomethane ug/L 52.050 104 82-120 Ethylbenzene ug/L 51.550 103 79-121 Iodomethane ug/L 96.4100 96 39-154 Methylene Chloride ug/L 50.250 100 64-133 Styrene ug/L 54.050 108 84-126 Tetrachloroethene ug/L 50.450 101 78-122 Toluene ug/L 53.550 107 80-121 trans-1,2-Dichloroethene ug/L 52.350 105 71-127 trans-1,3-Dichloropropene ug/L 54.150 108 69-141 trans-1,4-Dichloro-2-butene ug/L 45.950 92 40-160 Trichloroethene ug/L 52.850 106 78-122 Trichlorofluoromethane ug/L 55.750 111 53-137 Vinyl acetate ug/L 101100 101 40-160 Vinyl chloride ug/L 47.950 96 58-137 Xylene (Total)ug/L 156150 104 81-126 1,2-Dichloroethane-d4 (S)%96 70-130 4-Bromofluorobenzene (S)%101 70-130 Toluene-d8 (S)%99 70-130 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1900331MATRIX SPIKE SAMPLE: MSSpike Result 92324506014 1,1,1,2-Tetrachloroethane ug/L 22.320 112 70-130ND 1,1,1-Trichloroethane ug/L 20.420 102 70-130ND 1,1,2,2-Tetrachloroethane ug/L 22.520 112 70-130ND 1,1,2-Trichloroethane ug/L 22.920 115 70-130ND 1,1-Dichloroethane ug/L 19.620 98 70-130ND 1,1-Dichloroethene ug/L 13.1 M1206570-166ND 1,2,3-Trichloropropane ug/L 22.220 111 70-130ND 1,2-Dibromo-3-chloropropane ug/L 21.720 109 70-130ND 1,2-Dibromoethane (EDB)ug/L 21.520 108 70-130ND 1,2-Dichlorobenzene ug/L 22.020 110 70-130ND 1,2-Dichloroethane ug/L 20.320 101 70-130ND 1,2-Dichloropropane ug/L 22.120 111 70-130ND 1,4-Dichlorobenzene ug/L 21.520 108 70-130ND 2-Butanone (MEK)ug/L 42.940 107 70-130ND 2-Hexanone ug/L 44.540 111 70-130ND 4-Methyl-2-pentanone (MIBK)ug/L 45.040 112 70-130ND Acetone ug/L 34.640 82 70-130ND Acrylonitrile ug/L 99.8100 100 70-130ND Benzene ug/L 21.120 105 70-148ND Bromochloromethane ug/L 21.120 105 70-130ND Bromodichloromethane ug/L 22.920 115 70-130ND Bromoform ug/L 21.120 105 70-130ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324275 Town of Kernersville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1900331MATRIX SPIKE SAMPLE: MSSpike Result 92324506014 Bromomethane ug/L 10.8 M1205470-130ND Carbon disulfide ug/L 8.6 M1204370-130ND Carbon tetrachloride ug/L 20.920 105 70-130ND Chlorobenzene ug/L 22.520 113 70-146ND Chloroethane ug/L 7.0 M1203570-130ND Chloroform ug/L 20.520 103 70-130ND Chloromethane ug/L 1.7 M120870-130ND cis-1,2-Dichloroethene ug/L 19.920 99 70-130ND cis-1,3-Dichloropropene ug/L 21.220 106 70-130ND Dibromochloromethane ug/L 22.520 112 70-130ND Dibromomethane ug/L 21.520 107 70-130ND Ethylbenzene ug/L 22.020 110 70-130ND Iodomethane ug/L 9.7 M1402470-130ND Methylene Chloride ug/L 17.120 85 70-130ND Styrene ug/L 22.420 112 70-130ND Tetrachloroethene ug/L 20.820 104 70-130ND Toluene ug/L 22.120 111 70-155ND trans-1,2-Dichloroethene ug/L 18.320 92 70-130ND trans-1,3-Dichloropropene ug/L 21.920 109 70-130ND trans-1,4-Dichloro-2-butene ug/L 17.420 87 70-130ND Trichloroethene ug/L 21.520 107 69-151ND Trichlorofluoromethane ug/L 11.3 M1205770-130ND Vinyl acetate ug/L 34.740 87 70-130ND Vinyl chloride ug/L 1.3 M120770-130ND 1,2-Dichloroethane-d4 (S)%99 70-130 4-Bromofluorobenzene (S)%101 70-130 Toluene-d8 (S)%99 70-130 Parameter Units Dup Result QualifiersRPDResult 92324275001 1900330SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/L NDND 1,1,1-Trichloroethane ug/L NDND 1,1,2,2-Tetrachloroethane ug/L NDND 1,1,2-Trichloroethane ug/L NDND 1,1-Dichloroethane ug/L 3.0 82.8 1,1-Dichloroethene ug/L NDND 1,2,3-Trichloropropane ug/L NDND 1,2-Dibromo-3-chloropropane ug/L NDND 1,2-Dibromoethane (EDB)ug/L NDND 1,2-Dichlorobenzene ug/L NDND 1,2-Dichloroethane ug/L .84JND 1,2-Dichloropropane ug/L 1.2 41.1 1,4-Dichlorobenzene ug/L 3.6 33.7 2-Butanone (MEK)ug/L NDND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324275 Town of Kernersville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result QualifiersRPDResult 92324275001 1900330SAMPLE DUPLICATE: 2-Hexanone ug/L NDND 4-Methyl-2-pentanone (MIBK)ug/L NDND Acetone ug/L NDND Acrylonitrile ug/L NDND Benzene ug/L .4JND Bromochloromethane ug/L NDND Bromodichloromethane ug/L NDND Bromoform ug/L NDND Bromomethane ug/L NDND Carbon disulfide ug/L NDND Carbon tetrachloride ug/L NDND Chlorobenzene ug/L .37JND Chloroethane ug/L NDND Chloroform ug/L NDND Chloromethane ug/L NDND cis-1,2-Dichloroethene ug/L 48.5 048.5 cis-1,3-Dichloropropene ug/L NDND Dibromochloromethane ug/L NDND Dibromomethane ug/L NDND Ethylbenzene ug/L NDND Iodomethane ug/L NDND Methylene Chloride ug/L NDND Styrene ug/L NDND Tetrachloroethene ug/L NDND Toluene ug/L NDND trans-1,2-Dichloroethene ug/L NDND trans-1,3-Dichloropropene ug/L NDND trans-1,4-Dichloro-2-butene ug/L NDND Trichloroethene ug/L NDND Trichlorofluoromethane ug/L NDND Vinyl acetate ug/L NDND Vinyl chloride ug/L 7.5 108.2 Xylene (Total)ug/L NDND 1,2-Dichloroethane-d4 (S)%99 099 4-Bromofluorobenzene (S)%102 2100 Toluene-d8 (S)%99 0100 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324275 Town of Kernersville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 342560 EPA 8260 EPA 8260 8260 MSV Low Level Landfill Associated Lab Samples:92324275008, 92324275009, 92324275010, 92324275011 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1900335 Associated Lab Samples:92324275008, 92324275009, 92324275010, 92324275011 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/27/16 14:54 1,1,1-Trichloroethane ug/L ND 1.0 12/27/16 14:54 1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/27/16 14:54 1,1,2-Trichloroethane ug/L ND 1.0 12/27/16 14:54 1,1-Dichloroethane ug/L ND 1.0 12/27/16 14:54 1,1-Dichloroethene ug/L ND 1.0 12/27/16 14:54 1,2,3-Trichloropropane ug/L ND 1.0 12/27/16 14:54 1,2-Dibromo-3-chloropropane ug/L ND 2.0 12/27/16 14:54 1,2-Dibromoethane (EDB)ug/L ND 1.0 12/27/16 14:54 1,2-Dichlorobenzene ug/L ND 1.0 12/27/16 14:54 1,2-Dichloroethane ug/L ND 1.0 12/27/16 14:54 1,2-Dichloropropane ug/L ND 1.0 12/27/16 14:54 1,4-Dichlorobenzene ug/L ND 1.0 12/27/16 14:54 2-Butanone (MEK)ug/L ND 5.0 12/27/16 14:54 2-Hexanone ug/L ND 5.0 12/27/16 14:54 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/27/16 14:54 Acetone ug/L ND 25.0 12/27/16 14:54 Acrylonitrile ug/L ND 10.0 12/27/16 14:54 Benzene ug/L ND 1.0 12/27/16 14:54 Bromochloromethane ug/L ND 1.0 12/27/16 14:54 Bromodichloromethane ug/L ND 1.0 12/27/16 14:54 Bromoform ug/L ND 1.0 12/27/16 14:54 Bromomethane ug/L ND 2.0 12/27/16 14:54 Carbon disulfide ug/L ND 2.0 12/27/16 14:54 Carbon tetrachloride ug/L ND 1.0 12/27/16 14:54 Chlorobenzene ug/L ND 1.0 12/27/16 14:54 Chloroethane ug/L ND 1.0 12/27/16 14:54 Chloroform ug/L ND 1.0 12/27/16 14:54 Chloromethane ug/L ND 1.0 12/27/16 14:54 cis-1,2-Dichloroethene ug/L ND 1.0 12/27/16 14:54 cis-1,3-Dichloropropene ug/L ND 1.0 12/27/16 14:54 Dibromochloromethane ug/L ND 1.0 12/27/16 14:54 Dibromomethane ug/L ND 1.0 12/27/16 14:54 Ethylbenzene ug/L ND 1.0 12/27/16 14:54 Iodomethane ug/L ND 5.0 12/27/16 14:54 Methylene Chloride ug/L ND 1.0 12/27/16 14:54 Styrene ug/L ND 1.0 12/27/16 14:54 Tetrachloroethene ug/L ND 1.0 12/27/16 14:54 Toluene ug/L ND 1.0 12/27/16 14:54 trans-1,2-Dichloroethene ug/L ND 1.0 12/27/16 14:54 trans-1,3-Dichloropropene ug/L ND 1.0 12/27/16 14:54 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324275 Town of Kernersville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1900335 Associated Lab Samples:92324275008, 92324275009, 92324275010, 92324275011 Matrix:Water Analyzed trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/27/16 14:54 Trichloroethene ug/L ND 1.0 12/27/16 14:54 Trichlorofluoromethane ug/L ND 1.0 12/27/16 14:54 Vinyl acetate ug/L ND 2.0 12/27/16 14:54 Vinyl chloride ug/L ND 1.0 12/27/16 14:54 Xylene (Total)ug/L ND 1.0 12/27/16 14:54 1,2-Dichloroethane-d4 (S)%95 70-130 12/27/16 14:54 4-Bromofluorobenzene (S)%102 70-130 12/27/16 14:54 Toluene-d8 (S)%96 70-130 12/27/16 14:54 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1900336LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 50.550 101 80-125 1,1,1-Trichloroethane ug/L 50.250 100 71-129 1,1,2,2-Tetrachloroethane ug/L 50.350 101 79-124 1,1,2-Trichloroethane ug/L 54.250 108 85-125 1,1-Dichloroethane ug/L 51.750 103 73-126 1,1-Dichloroethene ug/L 54.750 109 66-135 1,2,3-Trichloropropane ug/L 49.050 98 75-130 1,2-Dibromo-3-chloropropane ug/L 50.750 101 71-133 1,2-Dibromoethane (EDB)ug/L 50.250 100 83-124 1,2-Dichlorobenzene ug/L 51.150 102 80-133 1,2-Dichloroethane ug/L 47.350 95 67-128 1,2-Dichloropropane ug/L 54.150 108 75-132 1,4-Dichlorobenzene ug/L 49.850 100 78-130 2-Butanone (MEK)ug/L 93.6100 94 61-144 2-Hexanone ug/L 101100 101 68-143 4-Methyl-2-pentanone (MIBK)ug/L 106100 106 72-135 Acetone ug/L 91.3100 91 48-146 Acrylonitrile ug/L 268250 107 40-160 Benzene ug/L 53.450 107 80-125 Bromochloromethane ug/L 51.650 103 71-125 Bromodichloromethane ug/L 55.850 112 78-124 Bromoform ug/L 50.950 102 71-128 Bromomethane ug/L 47.350 95 40-160 Carbon disulfide ug/L 53.750 107 50-160 Carbon tetrachloride ug/L 52.250 104 69-131 Chlorobenzene ug/L 51.050 102 81-122 Chloroethane ug/L 55.250 110 39-148 Chloroform ug/L 49.850 100 73-127 Chloromethane ug/L 52.850 106 44-146 cis-1,2-Dichloroethene ug/L 50.250 100 74-124 cis-1,3-Dichloropropene ug/L 54.550 109 72-132 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324275 Town of Kernersville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1900336LABORATORY CONTROL SAMPLE: LCSSpike Dibromochloromethane ug/L 52.050 104 78-125 Dibromomethane ug/L 53.150 106 82-120 Ethylbenzene ug/L 50.250 100 79-121 Iodomethane ug/L 92.9100 93 39-154 Methylene Chloride ug/L 50.850 102 64-133 Styrene ug/L 51.950 104 84-126 Tetrachloroethene ug/L 49.250 98 78-122 Toluene ug/L 53.250 106 80-121 trans-1,2-Dichloroethene ug/L 51.450 103 71-127 trans-1,3-Dichloropropene ug/L 53.650 107 69-141 trans-1,4-Dichloro-2-butene ug/L 45.350 91 40-160 Trichloroethene ug/L 52.350 105 78-122 Trichlorofluoromethane ug/L 57.650 115 53-137 Vinyl acetate ug/L 103100 103 40-160 Vinyl chloride ug/L 47.550 95 58-137 Xylene (Total)ug/L 151150 101 81-126 1,2-Dichloroethane-d4 (S)%88 70-130 4-Bromofluorobenzene (S)%100 70-130 Toluene-d8 (S)%101 70-130 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1900338MATRIX SPIKE SAMPLE: MSSpike Result 92324563001 1,1,1,2-Tetrachloroethane ug/L 21.420 107 70-130ND 1,1,1-Trichloroethane ug/L 19.420 97 70-130ND 1,1,2,2-Tetrachloroethane ug/L 22.020 110 70-130ND 1,1,2-Trichloroethane ug/L 22.420 112 70-130ND 1,1-Dichloroethane ug/L 40.420 93 70-13021.8 1,1-Dichloroethene ug/L 13.7 M1206770-166ND 1,2,3-Trichloropropane ug/L 21.520 107 70-130ND 1,2-Dibromo-3-chloropropane ug/L 21.320 106 70-130ND 1,2-Dibromoethane (EDB)ug/L 21.120 105 70-130ND 1,2-Dichlorobenzene ug/L 21.720 108 70-130ND 1,2-Dichloroethane ug/L 19.620 98 70-130ND 1,2-Dichloropropane ug/L 21.820 109 70-130ND 1,4-Dichlorobenzene ug/L 21.520 105 70-1300.59J 2-Butanone (MEK)ug/L 41.140 103 70-130ND 2-Hexanone ug/L 42.940 107 70-130ND 4-Methyl-2-pentanone (MIBK)ug/L 43.740 109 70-130ND Acetone ug/L 32.140 80 70-130ND Acrylonitrile ug/L 97.0100 97 70-130ND Benzene ug/L 21.220 104 70-1480.40J Bromochloromethane ug/L 20.720 104 70-130ND Bromodichloromethane ug/L 22.820 114 70-130ND Bromoform ug/L 20.620 103 70-130ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324275 Town of Kernersville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1900338MATRIX SPIKE SAMPLE: MSSpike Result 92324563001 Bromomethane ug/L 10.4 M1205270-130ND Carbon disulfide ug/L 8.5 M1204270-130ND Carbon tetrachloride ug/L 19.620 98 70-130ND Chlorobenzene ug/L 21.920 109 70-146ND Chloroethane ug/L 7.5 M1203870-130ND Chloroform ug/L 19.720 98 70-130ND Chloromethane ug/L 1.8 M120970-130ND cis-1,2-Dichloroethene ug/L 23.420 94 70-1304.6J cis-1,3-Dichloropropene ug/L 21.220 106 70-130ND Dibromochloromethane ug/L 21.220 106 70-130ND Dibromomethane ug/L 20.920 104 70-130ND Ethylbenzene ug/L 21.720 109 70-130ND Iodomethane ug/L 12.3 M1403170-130ND Methylene Chloride ug/L 19.520 95 70-130ND Styrene ug/L 22.120 111 70-130ND Tetrachloroethene ug/L 27.020 103 70-1306.5 Toluene ug/L 21.620 108 70-155ND trans-1,2-Dichloroethene ug/L 17.520 87 70-130ND trans-1,3-Dichloropropene ug/L 20.920 104 70-130ND trans-1,4-Dichloro-2-butene ug/L 17.120 85 70-130ND Trichloroethene ug/L 27.720 107 69-1516.2 Trichlorofluoromethane ug/L 10.7 M1205170-1300.59J Vinyl acetate ug/L 34.140 85 70-130ND Vinyl chloride ug/L 1.2 M120670-130ND 1,2-Dichloroethane-d4 (S)%96 70-130 4-Bromofluorobenzene (S)%101 70-130 Toluene-d8 (S)%100 70-130 Parameter Units Dup Result QualifiersRPDResult 92324275008 1900337SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/L NDND 1,1,1-Trichloroethane ug/L NDND 1,1,2,2-Tetrachloroethane ug/L NDND 1,1,2-Trichloroethane ug/L NDND 1,1-Dichloroethane ug/L NDND 1,1-Dichloroethene ug/L NDND 1,2,3-Trichloropropane ug/L NDND 1,2-Dibromo-3-chloropropane ug/L NDND 1,2-Dibromoethane (EDB)ug/L NDND 1,2-Dichlorobenzene ug/L NDND 1,2-Dichloroethane ug/L NDND 1,2-Dichloropropane ug/L NDND 1,4-Dichlorobenzene ug/L NDND 2-Butanone (MEK)ug/L NDND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92324275 Town of Kernersville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result QualifiersRPDResult 92324275008 1900337SAMPLE DUPLICATE: 2-Hexanone ug/L NDND 4-Methyl-2-pentanone (MIBK)ug/L NDND Acetone ug/L NDND Acrylonitrile ug/L NDND Benzene ug/L NDND Bromochloromethane ug/L NDND Bromodichloromethane ug/L NDND Bromoform ug/L NDND Bromomethane ug/L NDND Carbon disulfide ug/L NDND Carbon tetrachloride ug/L NDND Chlorobenzene ug/L NDND Chloroethane ug/L NDND Chloroform ug/L NDND Chloromethane ug/L NDND cis-1,2-Dichloroethene ug/L NDND cis-1,3-Dichloropropene ug/L NDND Dibromochloromethane ug/L NDND Dibromomethane ug/L NDND Ethylbenzene ug/L NDND Iodomethane ug/L NDND Methylene Chloride ug/L NDND Styrene ug/L NDND Tetrachloroethene ug/L NDND Toluene ug/L NDND trans-1,2-Dichloroethene ug/L NDND trans-1,3-Dichloropropene ug/L NDND trans-1,4-Dichloro-2-butene ug/L NDND Trichloroethene ug/L NDND Trichlorofluoromethane ug/L NDND Vinyl acetate ug/L NDND Vinyl chloride ug/L NDND Xylene (Total)ug/L NDND 1,2-Dichloroethane-d4 (S)%96 5101 4-Bromofluorobenzene (S)%100 0100 Toluene-d8 (S)%99 1100 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 42 #=QL# QUALIFIERS Pace Project No.: Project: 92324275 Town of Kernersville DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C ANALYTE QUALIFIERS Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 38 of 42 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92324275 Town of Kernersville Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92324275001 342311 3429503404-MW-3D EPA 3010A EPA 6010 92324275002 342311 3429503404-MW-3S EPA 3010A EPA 6010 92324275003 342311 3429503404-MW-4 EPA 3010A EPA 6010 92324275004 342311 3429503404-SW-2 EPA 3010A EPA 6010 92324275005 342311 3429503404-SW-1 EPA 3010A EPA 6010 92324275006 342311 3429503404-SW-3 EPA 3010A EPA 6010 92324275007 342311 3429503404-MW-2 EPA 3010A EPA 6010 92324275008 342311 342950DuplicateEPA 3010A EPA 6010 92324275009 342311 3429503404-MW-5 EPA 3010A EPA 6010 92324275010 342311 3429503404-MW-6 EPA 3010A EPA 6010 92324275011 342311 3429503404-Field Blank EPA 3010A EPA 6010 92324275001 3425593404-MW-3D EPA 8260 92324275002 3425593404-MW-3S EPA 8260 92324275003 3425593404-MW-4 EPA 8260 92324275004 3425593404-SW-2 EPA 8260 92324275005 3425593404-SW-1 EPA 8260 92324275006 3425593404-SW-3 EPA 8260 92324275007 3425593404-MW-2 EPA 8260 92324275008 342560DuplicateEPA 8260 92324275009 3425603404-MW-5 EPA 8260 92324275010 3425603404-MW-6 EPA 8260 92324275011 3425603404-Field Blank EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:07 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 39 of 42 Page 40 of 42 Page 41 of 42 Page 42 of 42 APPENDIX II Historical Summary Tables TABLE 1A SUMMARY OF HISTORICAL GROUNDWATER ELEVATIONS MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 TOC Elevation:806.42 804.87 762.19 764.57 764.56 760.26 773.32 Well Depth:34.69 20.46 13.18 24.00 56.96 14.40 11.36 30-Dec-09 772.45 786.66 759.16 751.54 752.79 754.33 769.21 01-Jun-10 773.45 788.32 758.90 750.76 752.63 753.90 769.69 16-Nov-10 773.55 787.93 759.14 750.98 752.59 753.74 769.81 29-Dec-10 773.29 787.37 758.83 749.82 752.45 753.68 769.56 29-Jun-11 773.10 786.81 758.38 750.54 752.16 753.41 769.73 01-Nov-11 771.92 785.10 758.49 754.73 751.90 753.08 769.63 01-May-12 771.88 785.32 758.54 750.86 752.34 753.55 769.55 07-Nov-12 771.65 DRY 758.20 750.30 751.61 752.87 768.57 09-May-13 769.95 787.56 759.20 752.52 753.24 754.44 - 07-Nov-13 771.46 DRY 758.09 750.12 751.50 752.79 768.13 05-Jun-14 772.22 785.84 758.45 750.67 752.14 753.36 768.57 20-Nov-14 771.73 784.41 758.08 750.24 751.53 752.81 769.23 Notes: TOC = Top of PVC well casing. Elevations in feet above mean sea level. Well depths in feet below TOC. Well ID: DowngradientBackground Town of Kernersville Landfill Permit No. 34-04 Joyce Engineering TABLE 1B MONITORING WELL AND BORING COMPLETION SUMMARY CASING GROUND DIAMETER SURFACE B.G.S.B.T.O.C. inches feet feet from to from to MW-1 2 803.89 806.42 32.16 34.69 24.69 34.96 779.2 768.9 SAPROLITE MW-2 2 760.07 762.19 11.06 13.18 3.18 13.18 756.9 746.9 SAPROLITE MW-3S 2 761.98 764.57 21.41 24.00 14 24 748.0 738.0 SAPROLITE MW-3D 2 762.02 764.56 54.42 56.96 36.96 56.96 725.1 705.1 SAPROLITE MW-4 2 757.00 760.26 11.14 14.40 4.4 14.4 752.6 742.6 SAPROLITE MW-5 2 771.00 773.32 9.04 11.36 6.36 11.36 764.6 759.6 SAPROLITE MW-6 2 801.77 804.87 17.36 20.46 10.46 20.46 791.3 781.3 SAPROLITE NOTES: B.G.S.Below Ground Surface M.S.L.Mean Sea Level B.T.O.C.Below Top of Casing T.O.C.Top of Casing *= Due to limited information this data is assumed based on field conditions TOTAL DEPTH WELL NUMBER LITHOLOGY OF SCREENED INTERVAL*T.O.C. WELL ELEVATIONS feet above M.S.L. SCREENED INTERVAL* DEPTH B.G.S.ELEV. M.S.L. Town of Kernersville Landfill Page 1 of 1 Joyce Engineering TABLE 2 SUMMARY OF ESTIMATED HYDRAULIC GRADIENT AND LINEAR VELOCITY GROUND-HORIZ.HYDRAULIC EFFECTIVE LINEAR WATER GRADIENT,CONDUCTIVITY POROSITY VELOCITY, ELEV.i K n V (feet)(ft/ft) (ft/day)(ft/day) 785 755 Notes: 1. Hydraulic conductivities (“K”) was estimated from slug test completed by JOYCE in April 2013 2. Velocity = Ki/n; assume homogeneous isotropic porous aquifer. 0.20i1SW November 2014 1.730.04 GRADIENT CALCULATION SEGMENT FLOW LINE LENGTH (feet) FLOW DIRECTION 0.30851 Town of Kernersville Landfill Permit No. 34-04 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Inorganic Compounds Antimony 30-Dec-09 1.2 6.0 ---ND 5.4 B ND ND 4.5 B ---1.4 J GWPS = 1.4 µg/L (10/23/07)01-Jun-10 1.2 6.0 ---ND ND ND ND ND ---3.9 J GWPS = 1 µg/L (8/1/10)29-Dec-10 2.6 6.0 ---ND ND ND ND ND ND ND 29-Jun-11 5.0 6.0 ---ND ND ND ND ND ND ND 01-Nov-11 5.0 6.0 ---ND ND ND ND ND ND ND 01-May-12 5.0 6.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.48 6.0 ------ND ND ND ND ---ND 09-May-13 5.0 6.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 6.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 6.0 ---ND ND ND ND ND ND ND 20-Nov-14 3.8 6.0 ------ND ND ND ND ND ND Arsenic 29-Jun-11 5.0 10.0 ---ND ND ND ND ND 6.2 J ND NC 2L = 10 µg/L (1/11/10)01-Nov-11 5.0 10.0 ---ND ND ND ND ND ND ND 01-May-12 5.0 10.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.094 10.0 ------1.43 B 1.42 B 0.87 B 1.04 B ---1.0 J 09-May-13 5.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 10.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 10.0 ---ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 ------ND 2.5 J ND ND 2.7 J ND Barium 30-Dec-09 1.1 100 ---74.1 J 496 178 18.2 J 89.0 J ---3.6 J NC 2L = 700 µg/L (1/11/10)01-Jun-10 1.1 100 ---58.1 J 326 187 22.2 J 94.9 J ---2.0 J 29-Dec-10 0.20 100 ---46.3 B 430 112 38.0 B 92.1 J 72.6 J 11.3 J 29-Jun-11 5.0 100 ---77.7 J 370 128 41.2 J 98.4 J 113 ND 01-Nov-11 5.0 100 ---125 413 132 41.7 J 111 72.1 J ND 01-May-12 5.0 100 ---78.8 J 323 121 40.0 J 99.7 J 66.1 J ND 07-Nov-12 0.39 100 ------369 127 41.0 B 98.7 J ---12.2 J 09-May-13 5.0 100 ---78.6 J 307 112 40.0 J 85.6 J ---ND 07-Nov-13 5.0 100 ------302 113 38.0 J 89.6 J ---ND 05-Jun-14 5.0 100 ---60.3 J 285 117 39.2 J 80.3 J 75.0 J ND 20-Nov-14 2.5 100 ------301 113 39.5 J 83.3 J 108 ND Beryllium 30-Dec-09 0.2 1.0 ---ND 0.5 J ND ND ND ---ND GWPS = 4 µg/L (10/23/07)01-Jun-10 0.2 1.0 ---0.6 J 0.7 J ND ND ND ---ND 29-Dec-10 0.10 1.0 ---ND ND ND ND ND 0.48 J ND 29-Jun-11 1.0 1.0 ---ND ND ND ND ND ND ND 01-Nov-11 1.0 1.0 ---ND ND ND ND ND ND ND 01-May-12 1.0 1.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.049 1.00 ------0.34 J ND ND 0.099 J ---ND 09-May-13 1.0 1.0 ---ND ND ND ND ND ---ND 07-Nov-13 1.0 1.0 ------ND ND ND ND ---ND 05-Jun-14 1.0 1.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.5 1.0 ------ND ND ND ND ND ND Cadmium 30-Dec-09 0.2 1.0 ---ND 0.5 J 5.6 ND ND ---ND NC 2L = 2 µg/L (1/11/10)01-Jun-10 0.2 1.0 ---2.9 1.0 B 5.3 0.4 B 0.4 B ---0.4 J 29-Dec-10 0.50 1.0 ---ND ND ND ND ND ND ND 29-Jun-11 1.0 1.0 ---ND ND ND ND ND ND ND 01-Nov-11 1.0 1.0 ---ND ND ND ND ND ND ND 01-May-12 1.0 1.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.026 1.00 ------0.15 J ND ND 0.043 J ---ND 09-May-13 1.0 1.0 ---ND ND ND ND ND ---ND 07-Nov-13 1.0 1.0 ------ND ND ND ND ---ND 05-Jun-14 1.0 1.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.5 1.0 ------ND ND ND ND ND ND Chromium 30-Dec-09 0.7 10.0 ---ND 2.7 J 9.7 J ND 3.1 J ---ND NC 2L = 10 µg/L (1/11/10)01-Jun-10 0.7 10.0 ---3.5 J 1.6 J 12.4 1.2 J 3.2 J ---ND 29-Dec-10 0.40 10.0 ---0.48 J 1.3 J 0.57 J ND 5.5 J 3.8 J ND 29-Jun-11 5.0 10.0 ---ND ND ND ND ND ND ND 01-Nov-11 5.0 10.0 ---ND ND ND ND 10.3 ND ND 01-May-12 5.0 10.0 ---ND ND ND ND 5.8 J ND ND 07-Nov-12 0.030 10.0 ------0.71 J 0.12 B 0.094 B 7.31 J ---0.099 J 09-May-13 5.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 10.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 10.0 ---ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 ------ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 1 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Cobalt 30-Dec-09 0.7 10.0 ---ND 6.4 J 11.2 ND 1.8 J ---ND GWPS = 70 µg/L (10/23/07)01-Jun-10 0.7 10.0 ---1.8 J 2.5 J 8.5 J ND 1.7 J ---ND GWPS = 1 µg/L (10/1/10)29-Dec-10 0.60 10.0 ---ND 4.9 J 1.7 J ND 1.6 J 10.2 ND 29-Jun-11 5.0 10.0 ---ND ND ND ND ND 9.9 J ND 01-Nov-11 5.0 10.0 ---ND ND ND ND ND 5.2 J ND 01-May-12 5.0 10.0 ---ND ND ND ND ND 13.9 ND 07-Nov-12 0.053 10.0 ------1.98 J 3.89 J 0.43 B 2.02 J ---0.24 J 09-May-13 5.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 10.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 10.0 ---ND ND ND ND ND 12.0 ND 20-Nov-14 2.5 10.0 ------ND 2.5 J ND ND 10.2 ND Copper 30-Dec-09 2.0 10.0 ---ND ND 10.6 ND 1.5 J ---ND NC 2L = 1,000 µg/L (10/23/07)01-Jun-10 2.0 10.0 ---12.2 B 3.3 B 33.2 3.9 B 6.8 B ---4.8 J 29-Dec-10 0.30 10.0 ---ND ND 0.49 J 0.59 J 1.5 J 7.9 J ND 29-Jun-11 5.0 10.0 ---ND ND ND ND ND 16.6 ND 01-Nov-11 5.0 10.0 ---ND ND ND ND 5.4 J ND ND 01-May-12 5.0 10.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.093 10.0 ------3.56 B 0.54 B 0.98 B 1.83 B ---1.23 J 09-May-13 5.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 10.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 10.0 ---ND ND ND ND ND 6.1 J ND 20-Nov-14 2.5 10.0 ------ND ND ND ND 5.3 J ND Lead 30-Dec-09 2.0 10.0 ---ND ND 10.2 ND ND ---ND NC 2L = 15 µg/L (10/23/07)01-Jun-10 2.0 10.0 ---9.1 B 8.2 B 8.7 B 3.0 B 3.9 B ---3.2 J 29-Dec-10 4.0 10.0 ---ND ND ND ND ND 6.5 J ND 29-Jun-11 5.0 10.0 ---ND ND ND ND ND 19.9 ND 01-Nov-11 5.0 10.0 ---5.5 J ND ND ND ND ND ND 01-May-12 5.0 10.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.025 10.0 ------1.00 B 0.091 B 0.066 B 1.12 B ---0.58 J 09-May-13 5.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 10.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 10.0 ---ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 ------ND ND ND ND 4.2 J ND Nickel 30-Dec-09 0.6 50.0 ---ND ND 8.1 J 1.8 J 1.6 J ---ND NC 2L = 100 µg/L (10/23/07)01-Jun-10 0.6 50.0 ---ND ND 6.0 J ND 0.9 J ---ND 29-Dec-10 1.7 50.0 ---ND ND ND ND ND 2.0 B 3.1 J 29-Jun-11 5.0 50.0 ---ND ND ND ND ND ND ND 01-Nov-11 5.0 50.0 ---ND ND ND ND ND ND ND 01-May-12 5.0 50.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.26 50.0 ------0.73 B 1.19 B 0.65 B 5.57 J ---0.84 J 09-May-13 5.0 50.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 50.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 50.0 ---ND ND ND ND ND ND ND 20-Nov-14 2.5 50.0 ------ND ND ND ND ND ND Selenium 30-Dec-09 6.3 10.0 ---ND ND 8.4 J ND ND ---ND NC 2L = 20 µg/L (1/11/10)01-Jun-10 6.3 10.0 ---ND ND 6.3 J ND ND ---ND 29-Dec-10 3.8 10.0 ---ND ND ND ND ND ND ND 29-Jun-11 10.0 10.0 ---ND ND ND ND ND ND ND 01-Nov-11 10.0 10.0 ---ND ND ND ND ND ND ND 01-May-12 10.0 10.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.11 10.0 ------0.16 J 0.38 J 0.20 J 0.25 J ---ND 09-May-13 10.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 10.0 10.0 ------ND ND ND ND ---ND 05-Jun-14 10.0 10.0 ---ND ND ND ND ND ND ND 20-Nov-14 5.0 10.0 ------ND ND ND ND ND ND Silver 30-Dec-09 1.1 10.0 ---ND 1.7 B 2.2 B ND ND ---1.9 J NC 2L = 20 µg/L (1/11/10)01-Jun-10 1.1 10.0 ---ND ND ND ND ND ---ND 29-Dec-10 0.10 10.0 ---ND 1.8 J 0.36 J 0.19 J 0.23 J ND ND 29-Jun-11 5.0 10.0 ---ND ND ND ND ND ND ND 01-Nov-11 5.0 10.0 ---ND ND ND ND ND ND ND 01-May-12 5.0 10.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.017 10.0 ------0.18 J ND ND 0.078 J ---ND 09-May-13 5.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 10.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 10.0 ---ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 ------ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 2 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Thallium 30-Dec-09 2.7 5.5 ---ND ND ND ND ND ---3.7 J GWPS = 0.28 µg/L (10/23/07)01-Jun-10 2.7 5.5 ---ND ND ND ND ND ---ND GWPS = 0.2 µg/L (10/1/10)29-Dec-10 3.0 5.5 ---ND 3.2 J ND ND 4.8 J ND ND 29-Jun-11 5.4 5.5 ---ND ND ND ND ND ND ND 01-Nov-11 5.4 5.5 ---ND ND ND ND ND ND ND 01-May-12 5.4 5.5 ---ND ND ND ND ND ND ND 07-Nov-12 0.060 5.50 ------0.16 J ND ND 0.76 J ---ND 09-May-13 5.4 5.5 ---ND ND ND ND ND ---ND 07-Nov-13 5.4 5.5 ------ND ND ND ND ---ND 05-Jun-14 5.4 5.5 ---ND ND ND ND ND ND ND 20-Nov-14 5.0 5.5 ------ND ND ND ND ND ND Vanadium 30-Dec-09 0.4 25.0 ---ND 1.4 J 37.4 1.5 J 4.3 J ---ND GWPS = 3.5 µg/L (10/23/07)01-Jun-10 0.4 25.0 ---1.2 J 3.4 J 84.2 1.4 J 4.8 J ---ND GWPS = 0.3 µg/L (10/1/10)29-Dec-10 0.20 25.0 ---1.2 B 2.8 J 2.3 J 1.6 J 5.5 J 14.5 J 0.26 J 29-Jun-11 5.0 25.0 ---ND ND ND ND ND 22.0 J ND 01-Nov-11 5.0 25.0 ---7.2 J ND ND ND 12.0 J 7.2 J ND 01-May-12 5.0 25.0 ---ND ND ND ND 7.2 J 7.6 J ND 07-Nov-12 0.085 25.0 ------2.48 J 2.02 J 2.35 J 4.55 J ---ND 09-May-13 5.0 25.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 25.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 25.0 ---ND ND 11.4 J ND ND ND ND 20-Nov-14 2.5 25.0 ------ND 3.2 J ND ND 9.4 J ND Zinc 30-Dec-09 2.7 10.0 ---ND 10.1 B 204 15.9 B 24.8 B ---5.8 J NC 2L = 1,000 µg/L (1/11/10)01-Jun-10 2.7 10.0 ---16.2 13.5 415 8.5 J 22.2 ---ND 29-Dec-10 0.40 10.0 ---12.2 B 15.8 B 8.9 B ND 4.6 B 38.1 B 12.5 29-Jun-11 10.0 10.0 ---ND 23.6 B 22.3 B ND 15.5 B 91.2 10.5 01-Nov-11 10.0 10.0 ---16.6 ND 40.0 ND 16.2 31.4 ND 01-May-12 10.0 10.0 ---ND ND 13.5 ND 10.2 12.0 ND 07-Nov-12 1.31 10.0 ------8.61 J 5.20 J 3.98 J 4.65 J ---ND 09-May-13 10.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 10.0 10.0 ------13.8 10.4 ND ND ---ND 05-Jun-14 10.0 10.0 ---ND ND 89.0 ND ND 19.4 ND 20-Nov-14 5.0 10.0 ------ND 20.9 ND ND 55.0 ND Organic Compounds Acetone 29-Jun-11 2.2 100 ---ND 2.3 B 2.4 B 3.9 B ND 3.8 B 5.3 J NC 2L = 6,000 µg/L (1/11/10)01-Nov-11 2.2 100 ---ND ND ND ND ND ND 14.6 J 01-May-12 2.2 100 ---ND ND ND ND ND ND ND 07-Nov-12 0.193 100 ------ND ND ND ND ---ND 09-May-13 10.0 100 ---ND ND ND ND ND ---12.0 J 07-Nov-13 10.0 100 ------ND ND ND ND ---ND 05-Jun-14 10.0 100 ---ND ND ND ND ND ND ND 20-Nov-14 10.0 100 ------ND ND ND ND ND ND Benzene 30-Dec-09 0.1 1.0 ---ND 8.4 0.3 J 0.4 J 0.3 J ---ND NC 2L = 1 µg/L (10/23/07)01-Jun-10 0.1 1.0 ---ND 2.9 ND ND ND ---ND 29-Dec-10 0.25 1.0 ---ND 8.1 ND ND ND ND ND 29-Jun-11 0.25 1.0 ---ND 7.2 0.38 J 0.45 J 0.42 J ND ND 01-Nov-11 0.25 1.0 ---ND 8.6 ND ND ND ND ND 01-May-12 0.25 1.0 ---ND 6.7 0.36 J 0.45 J 0.42 J ND ND 07-Nov-12 0.111 1.0 ------8.63 0.430 J 0.504 J 0.478 J ---ND 09-May-13 0.25 1.0 ---ND 5.2 0.27 J 0.32 J 0.30 J ---ND 07-Nov-13 0.25 1.0 ------6.9 0.33 J 0.38 J 0.39 J ---ND 05-Jun-14 0.25 1.0 ---ND 6.0 ND 0.42 J 0.40 J ND ND 20-Nov-14 0.25 1.0 ------6.2 0.30 J ND 0.32 J ND ND Bromoform 09-May-13 0.26 3.0 ---ND ND 0.37 B ND ND ---0.37 J NC 2L = µg/L 4 (10/23/07)07-Nov-13 0.26 3.0 ------ND ND ND ND ---ND 05-Jun-14 0.26 3.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.26 3.0 ------ND ND ND ND ND ND Chlorobenzene 30-Dec-09 0.1 3.0 ---ND 0.5 J 0.6 J ND ND ---ND NC 2L = 50 µg/L (10/23/07)01-Jun-10 0.1 3.0 ---ND ND ND ND ND ---ND 29-Dec-10 0.23 3.0 ---ND 0.61 J ND ND ND ND ND 29-Jun-11 0.23 3.0 ---ND 0.46 J 1.0 J 0.37 J ND ND ND 01-Nov-11 0.23 3.0 ---ND 0.59 J 1.1 J 0.37 J ND ND ND 01-May-12 0.23 3.0 ---ND {0.42}J 0.94 B 0.38 B ND ND 0.30 {ND}J 07-Nov-12 0.083 3.00 ------0.468 J 1.30 J 0.476 J ND ---ND 09-May-13 0.23 3.0 ---ND 0.27 J 0.72 J 0.27 J ND ---ND 07-Nov-13 0.23 3.0 ------0.42 J 0.97 J 0.38 J ND ---ND 05-Jun-14 0.23 3.0 ---ND 0.30 J 0.78 J 0.33 J ND ND ND 20-Nov-14 0.23 3.0 ------0.37 J 0.95 J 0.36 J ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 3 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Chloroethane 30-Dec-09 0.1 10.0 ---ND ND 0.5 J 0.5 J ND ---0.1 J NC 2L = 3,000 µg/L (1/11/10)01-Jun-10 0.1 10.0 ---ND ND 0.4 J ND ND ---ND 29-Dec-10 0.54 10.0 ---ND ND ND ND ND ND ND 29-Jun-11 0.54 10.0 ---ND ND 0.77 J ND 0.57 J ND ND 01-Nov-11 0.54 10.0 ---ND ND 0.79 J ND ND ND ND 01-May-12 0.54 10.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.235 10.0 ------ND ND ND ND ---ND 09-May-13 0.54 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 0.54 10.0 ------ND ND ND ND ---ND 05-Jun-14 0.54 10.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.54 10.0 ------ND ND ND ND ND ND 1,4-Dichlorobenzene 30-Dec-09 0.1 1.0 ---ND 3.8 2.2 2.3 3.1 ---ND NC 2L = 6 µg/L (1/11/10)01-Jun-10 0.1 1.0 ---ND 1.2 0.9 J ND 1.2 ---ND 29-Dec-10 0.33 1.0 ---ND 3.9 1.1 2.3 1.9 ND ND 29-Jun-11 0.33 1.0 ---ND 3.8 2.8 3.6 3.2 ND ND 01-Nov-11 0.33 1.0 ---ND 4.7 4.1 4.1 3.5 ND ND 01-May-12 0.33 1.0 ---ND 4.0 2.7 4.1 3.2 ND ND 07-Nov-12 0.083 1.00 ------5.12 2.93 4.08 3.64 ---ND 09-May-13 0.33 1.0 ---ND 3.6 2.0 3.1 2.3 ---ND 07-Nov-13 0.33 1.0 ------5.4 2.5 4.2 3.2 ---ND 05-Jun-14 0.33 1.0 ---ND 5.0 1.9 4.0 2.7 ND ND 20-Nov-14 0.33 1.0 ------4.7 1.9 3.8 2.6 ND ND 1,1-Dichloroethane 30-Dec-09 0.2 5.0 ---ND 22.8 1.9 J 4.0 J 2.4 J ---ND NC 2L = 6 µg/L (1/11/10)01-Jun-10 0.2 5.0 ---ND 11.0 1.1 J ND 1.2 J ---ND 29-Dec-10 0.32 5.0 ---ND 28.2 2.4 J 4.1 J 2.6 J ND ND 29-Jun-11 0.32 5.0 ---ND 25.0 2.5 J 3.9 J 2.6 J ND ND 01-Nov-11 0.32 5.0 ---ND 27.2 2.3 J 4.0 J 2.3 J ND ND 01-May-12 0.32 5.0 ---ND 22.6 2.0 J 3.8 J 2.0 J ND ND 07-Nov-12 0.208 5.0 ------28.1 2.06 J 4.08 J ND ---ND 09-May-13 0.32 5.0 ---ND 18.7 1.4 J 3.0 J 1.6 J ---ND 07-Nov-13 0.32 5.0 ------26.6 1.7 J 4.2 J 2.2 J ---ND 05-Jun-14 0.32 5.0 ---ND 21.9 1.4 J 3.9 J 1.9 J ND ND 20-Nov-14 0.32 5.0 ------21.5 1.3 J 3.2 J 1.8 J ND ND 1,2-Dichloroethane 30-Dec-09 0.1 1.0 ---ND 1.2 0.7 J 1.2 ND ---ND NC 2L = 0.4 µg/L (1/11/10)01-Jun-10 0.1 1.0 ---ND ND ND ND ND ---ND 29-Dec-10 0.12 1.0 ---ND ND 0.82 J 1.1 ND ND ND 29-Jun-11 0.12 1.0 ---ND 0.76 J 0.86 J 1.3 ND ND ND 01-Nov-11 0.12 1.0 ---ND 0.95 J ND 1.3 ND ND ND 01-May-12 0.12 1.0 ---ND 0.71 J 0.70 J 1.1 ND ND ND 07-Nov-12 0.171 1.00 ------ND ND ND ND ---ND 09-May-13 0.12 1.0 ---ND 0.50 J 0.49 J 0.81 J ND ---ND 07-Nov-13 0.12 1.0 ------0.93 J 0.66 J 1.3 ND ---ND 05-Jun-14 0.12 1.0 ---ND 0.76 J 0.52 J 0.99 J ND ND ND 20-Nov-14 0.12 1.0 ------0.68 J 0.47 J 0.81 J ND ND ND 1,1-Dichloroethylene 30-Dec-09 0.1 5.0 ---ND 0.4 J ND ND ND ---ND NC 2L = 7 µg/L (10/23/07)01-Jun-10 0.1 5.0 ---ND ND ND ND ND ---ND 29-Dec-10 0.56 5.0 ---ND ND ND ND ND ND ND 29-Jun-11 0.56 5.0 ---ND ND ND ND ND ND ND 01-Nov-11 0.56 5.0 ---ND ND ND ND ND ND ND 01-May-12 0.56 5.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.208 5.00 ------ND ND ND ND ---ND NC 2L = 350 µg/L (04/01/2013)09-May-13 0.56 5.0 ---ND ND ND ND ND ---ND 07-Nov-13 0.56 5.0 ------ND ND ND ND ---ND 05-Jun-14 0.56 5.0 ---ND 4.7 J ND ND ND ND ND 20-Nov-14 0.56 5.0 ---ND ND ND ND ND ND ND cis-1,2-Dichloroethene 30-Dec-09 0.1 5.0 ---ND 68.2 11.0 51.0 21.8 ---ND NC 2L = 70 µg/L (10/23/07)01-Jun-10 0.1 5.0 ---ND 23.0 7.6 ND 10.2 ---ND 29-Dec-10 0.19 5.0 ---ND 66.7 16.8 56.7 24.1 ND ND 29-Jun-11 0.19 5.0 ---ND 55.1 16.5 62.7 25.1 ND ND 01-Nov-11 0.19 5.0 ---ND 59.4 15.2 59.3 23.2 ND ND 01-May-12 0.19 5.0 ---ND {48.7}14.2 59.5 22.1 ND 0.21 {ND}J 07-Nov-12 0.103 5.00 ------59.7 13.6 71.3 26.4 ---ND 09-May-13 0.19 5.0 ---ND 39.9 10.9 49.7 17.4 ---ND 07-Nov-13 0.19 5.0 ------53.9 10.7 67.1 21.8 ---ND 05-Jun-14 0.19 5.0 ---ND 47.0 11.2 58.1 20.0 ND ND 20-Nov-14 0.19 5.0 ------44.9 9.6 55.4 19.3 ND ND Town of Kernersville Landfill Permit No. 34-04 Page 4 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks trans-1,2-Dichloroethene 30-Dec-09 0.1 5.0 ---ND 1.4 J ND 0.2 J 0.2 J ---ND NC 2L = 100 µg/L (10/23/07)01-Jun-10 0.1 5.0 ---ND 0.6 J ND ND ND ---ND 29-Dec-10 0.49 5.0 ---ND 1.7 J ND ND ND ND ND 29-Jun-11 0.49 5.0 ---ND 1.5 J ND ND ND ND ND 01-Nov-11 0.49 5.0 ---ND 1.6 J ND ND ND ND ND 01-May-12 0.49 5.0 ---ND 1.4 J ND ND ND ND ND 07-Nov-12 0.077 5.00 ------1.59 J ND ND ND ---ND 09-May-13 0.49 5.0 ---ND 1.1 J ND ND ND ---ND 07-Nov-13 0.49 5.0 ------1.6 J ND ND ND ---ND 05-Jun-14 0.49 5.0 ---ND 1.4 J ND ND ND ND ND 20-Nov-14 0.49 5.0 ------1.4 J ND ND ND ND ND 1,2-Dichloropropane 30-Dec-09 0.1 1.0 ---ND 5.7 0.6 J 1.1 0.7 J ---ND NC 2L = 0.6 µg/L (1/11/10)01-Jun-10 0.1 1.0 ---ND 1.9 ND ND ND ---ND 29-Dec-10 0.27 1.0 ---ND 5.3 ND ND ND ND ND 29-Jun-11 0.27 1.0 ---ND 4.8 0.90 J 1.3 0.73 J ND ND 01-Nov-11 0.27 1.0 ---ND 4.9 0.76 J 1.3 ND ND ND 01-May-12 0.27 1.0 ---ND 4.4 0.76 J 1.4 0.62 J ND ND 07-Nov-12 0.150 1.0 ------4.93 ND 1.66 ND ---ND 09-May-13 0.27 1.0 ---ND 3.3 0.51 J 0.96 J 0.45 J ---ND 07-Nov-13 0.27 1.0 ------4.4 0.63 J 1.3 0.57 J ---ND 05-Jun-14 0.27 1.0 ---ND 4.0 0.51 J ND 0.41 J ND ND 20-Nov-14 0.27 1.0 ------4.1 0.56 J 1.2 0.36 J ND ND Ethylbenzene 30-Dec-09 0.1 1.0 ---ND ND ND 0.4 J ND ---ND NC 2L = 600 µg/L (10/23/07)01-Jun-10 0.1 1.0 ---ND ND ND ND ND ---ND 29-Dec-10 0.30 1.0 ---ND ND ND ND ND ND ND 29-Jun-11 0.30 1.0 ---ND ND ND ND ND ND ND 01-Nov-11 0.30 1.0 ---ND ND ND ND ND ND ND 01-May-12 0.30 1.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.109 1.00 ------ND ND ND ND ---ND 09-May-13 0.30 1.0 ---ND ND ND ND ND ---ND 07-Nov-13 0.30 1.0 ------ND ND ND ND ---ND 05-Jun-14 0.30 1.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.30 1.0 ------ND ND ND ND ND ND Tetrachloroethene 30-Dec-09 0.2 1.0 ---ND 1.2 ND ND ND ---ND NC 2L = 0.7 µg/L (10/23/07)01-Jun-10 0.2 1.0 ---ND 1.4 ND ND ND ---ND 29-Dec-10 0.46 1.0 ---ND 2.8 ND ND ND ND ND 29-Jun-11 0.46 1.0 ---ND 3.6 ND ND ND ND ND 01-Nov-11 0.46 1.0 ---ND 2.9 ND ND ND ND ND 01-May-12 0.46 1.0 ---ND 3.0 ND ND ND ND ND 07-Nov-12 0.193 1.00 ------2.52 ND ND ND ---ND 09-May-13 0.46 1.0 ---ND 1.9 ND ND ND ---ND 07-Nov-13 0.46 1.0 ------1.8 ND ND ND ---ND 05-Jun-14 0.46 1.0 ---ND 2.3 ND ND ND ND ND 20-Nov-14 0.46 1.0 ------1.1 ND ND ND ND ND Toluene 29-Jun-11 0.26 1.0 ---ND ND ND ND ND 0.76 J ND NC 2L = 600 µg/L (1/11/10)01-Nov-11 0.26 1.0 ---ND ND ND ND ND ND ND 01-May-12 0.26 1.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.122 1.00 ------ND ND ND ND ---ND 09-May-13 0.26 1.0 ---ND ND ND ND ND ---ND 07-Nov-13 0.26 1.0 ------ND ND ND ND ---ND 05-Jun-14 0.26 1.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.26 1.0 ------ND ND ND ND ND ND Trichloroethene 30-Dec-09 0.1 1.0 ---ND 8.0 ND ND 0.2 J ---ND NC 2L = 3 µg/L (1/11/10)01-Jun-10 0.1 1.0 ---ND 6.4 ND ND ND ---ND 29-Dec-10 0.47 1.0 ---ND 10.1 ND ND ND ND ND 29-Jun-11 0.47 1.0 ---ND 14.6 ND ND ND ND ND 01-Nov-11 0.47 1.0 ---ND 10.2 ND ND ND ND ND 01-May-12 0.47 1.0 ---ND 11.6 ND ND ND ND ND 07-Nov-12 0.161 1.00 ------9.97 ND ND ND ---ND 09-May-13 0.47 1.0 ---ND 8.4 ND ND ND ---ND 07-Nov-13 0.47 1.0 ------8.0 ND ND ND ---ND 05-Jun-14 0.47 1.0 ---ND 8.9 ND ND ND ND ND 20-Nov-14 0.47 1.0 ------5.1 ND ND ND ND ND Trichlorofluoromethane 29-Jun-11 0.20 1.0 ---ND 0.95 J ND ND ND ND ND NC 2L = 2000 µg/L (1/11/10)01-Nov-11 0.20 1.0 ---ND ND ND ND ND ND ND 01-May-12 0.20 1.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.157 1.00 ------ND ND ND ND ---ND 09-May-13 0.20 1.0 ---ND 0.66 J ND ND ND ---ND 07-Nov-13 0.20 1.0 ------ND ND ND ND ---ND 05-Jun-14 0.20 1.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.20 1.0 ------ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 5 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Vinyl chloride 30-Dec-09 0.1 1.0 ---ND 4.0 2.8 4.1 26.2 ---ND NC 2L = 0.03 µg/L (1/11/10)01-Jun-10 0.1 1.0 ---ND 2.2 3.0 ND 26.7 ---ND 29-Dec-10 0.62 1.0 ---ND 3.5 2.4 4.7 25.6 ND ND 29-Jun-11 0.62 1.0 ---ND 2.8 2.8 4.6 28.7 ND ND 01-Nov-11 0.62 1.0 ---ND 5.1 2.6 6.9 24.0 ND ND 01-May-12 0.62 1.0 ---ND 3.5 2.0 4.8 21.8 ND ND 07-Nov-12 0.127 1.00 ------7.94 2.73 6.99 29.9 ---ND 09-May-13 0.62 1.0 ---ND 2.8 1.9 4.2 18.6 ---ND 07-Nov-13 0.62 1.0 ------6.3 2.1 6.0 21.9 ---ND 05-Jun-14 0.62 1.0 ---ND 7.1 5.6 8.9 21.9 ND ND 20-Nov-14 0.62 1.0 ------5.2 2.1 5.3 16.2 ND ND Xylene (Total)30-Dec-09 0.3 4.0 ---ND ND ND 3.5 J ND ---ND NC 2L = 500 µg/L (1/11/10)01-Jun-10 0.3 4.0 ---ND ND ND ND ND ---ND 29-Dec-10 0.66 2.0 ---ND ND ND ND ND ND ND 29-Jun-11 0.66 2.0 ---ND ND ND ND ND ND ND 01-Nov-11 0.66 2.0 ---ND ND ND ND ND ND ND 01-May-12 0.66 2.0 ---ND 0.89 J ND ND ND ND ND 07-Nov-12 0.179 5.00 ------ND ND ND ND ---ND 09-May-13 0.66 5.0 ---ND ND ND ND ND ---ND 07-Nov-13 0.66 5.0 ------ND ND ND ND ---ND 05-Jun-14 0.66 5.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.66 5.0 ------ND ND ND ND ND ND Notes: 1. RL = Reporting limit (NC SWSL). 2. All concentrations are in micrograms per liter (ug/L). 3. NC 2L Standard is the groundwater quality standard established under 15A NCAC 2L. 4. MW = Monitoring well. 5. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. 6. ND = Not detected at the laboratory's detection limit. 7. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. 8. B = Probable field and/or laboratory contamination since the concentration is within five times the concentration reported in the associated quality control blanks. 9. Bold values are greater than the NC 2L Standard or GWPS. 10. DL = Detection limit. 11. GWPS = Groundwater Protection Standard (GWPS is used when the NC 2L Standard has not been established.) 12. --- = Monitoring well was no sampled. Town of Kernersville Landfill Permit No. 34-04 Page 6 of 6 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Inorganic Compounds Antimony 30-Dec-09 1.2 6.0 1.5 B 6.4 B NS 1.4 J NC 2B = NE µg/L (05/01/07)01-Jun-10 1.2 6.0 6.7 B 2.5 B NS 3.9 J 29-Dec-10 2.6 6.0 ND ND ND ND 29-Jun-11 5.0 6.0 ND ND ND ND 01-Nov-11 5.0 6.0 ND ND ND ND 01-May-12 5.0 6.0 ND ND ND ND 07-Nov-12 0.48 6.0 ND ND ND ND 09-May-13 5.0 6.0 ND ND ND ND 07-Nov-13 5.0 6.0 ND ND ND ND 05-Jun-14 5.0 6.0 ND ND ND ND 20-Nov-14 3.8 6.0 ND ND ND ND Arsenic 07-Nov-12 0.094 10.0 0.17 B 0.26 B 0.24 B 1.0 J NC 2B = 50 µg/L (05/01/07)09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Barium 30-Dec-09 1.1 100 25.1 J 34 J NS 3.4 J NC 2B = NE µg/L (05/01/07)01-Jun-10 1.1 100 28.8 J 31.5 J NS 2.0 J 29-Dec-10 0.20 100 22.3 B 27.8 B 27.9 B 11.3 J 29-Jun-11 5.0 100 40.0 J 39.4 J 39.3 J ND 01-Nov-11 5.0 100 30.1 J 35.2 J 34.3 J ND 01-May-12 5.0 100 66.1 J 35.4 J 33.3 J ND 07-Nov-12 0.39 100 27.6 B 31.5 B 29.9 B 12.2 J 09-May-13 5.0 100 33.6 J 33.8 J 32.6 J ND 07-Nov-13 5.0 100 36.6 J 32.0 J 29.8 J ND 05-Jun-14 5.0 100 31.2 J 35.8 J 33.6 J ND 20-Nov-14 2.5 100 26.6 J 31.2 J 29.4 J ND Cadmium 30-Dec-09 0.2 1.0 ND ND NS ND NC 2B = 2 µg/L (05/01/07)01-Jun-10 0.2 1.0 0.9 B 0.4 B NS 0.4 J 29-Dec-10 0.50 1.0 ND ND ND ND 29-Jun-11 1.0 1.0 ND ND ND ND 01-Nov-11 1.0 1.0 ND ND ND ND 01-May-12 1.0 1.0 ND ND ND ND 07-Nov-12 0.026 1.000 ND ND ND ND 09-May-13 1.0 1.0 ND ND ND ND 07-Nov-13 1.0 1.0 ND ND ND ND 05-Jun-14 1.0 1.0 ND ND ND ND 20-Nov-14 0.5 1.0 ND ND ND ND Chromium 30-Dec-09 0.7 10.0 ND ND NS ND NC 2B = 50 µg/L (05/01/07)01-Jun-10 0.7 10.0 1.7 J 1.2 J NS ND 29-Dec-10 0.40 10.0 0.69 J 0.53 J 0.41 J ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.030 10.0 0.29 B 0.13 B 0.11 B 0.099 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND 2.7 J ND Town of Kernersville Landfill Permit No. 34-04 Page 1 of 3 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Cobalt 30-Dec-09 0.7 10.0 ND ND NS ND NC 2B = NE µg/L (05/01/07)01-Jun-10 0.7 10.0 ND ND NS ND 29-Dec-10 0.60 10.0 ND 1.8 J 1.9 J ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.053 10.0 0.34 B 0.76 B 0.76 B 0.24 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Copper 30-Dec-09 2.0 10.0 ND ND NS ND NC 2B = 7 µg/L (05/01/07)01-Jun-10 2.0 10.0 6.9 B 5.8 B NS 4.8 J 29-Dec-10 0.30 10.0 0.38 J ND ND ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.093 10.0 0.27 B 0.38 B 0.38 B 1.23 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Lead 30-Dec-09 2.0 10.0 ND ND NS ND NC 2B = 25 µg/L (05/01/07)01-Jun-10 2.0 10.0 2.7 B 2.8 B NS 3.2 J 29-Dec-10 4.0 10.0 ND ND ND ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.025 10.0 0.071 B 0.049 B 0.060 B 0.58 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Nickel 07-Nov-12 0.26 50.0 0.46 B 0.39 B 0.35 B 0.84 J NC 2B = 88 µg/L (05/01/07)09-May-13 5.0 50.0 ND ND ND ND 07-Nov-13 5.0 50.0 ND ND ND ND 05-Jun-14 5.0 50.0 ND ND ND ND 20-Nov-14 2.5 50.0 ND ND ND ND Vanadium 30-Dec-09 0.4 25.0 2.0 J 0.8 J NS ND NC 2B = NE µg/L (05/01/07)01-Jun-10 0.4 25.0 2.2 J 2.4 J NS ND 29-Dec-10 0.20 25.0 0.67 B 0.37 B 0.62 B 0.26 J 29-Jun-11 5.0 25.0 ND ND ND ND 01-Nov-11 5.0 25.0 ND ND ND ND 01-May-12 5.0 25.0 ND ND ND ND 07-Nov-12 0.085 25.0 0.63 J 0.44 J 0.52 J ND 09-May-13 5.0 25.0 7.8 J 9.1 J 9.4 J ND 07-Nov-13 5.0 25.0 ND ND ND ND 05-Jun-14 5.0 25.0 ND ND ND ND 20-Nov-14 2.5 25.0 ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 2 of 3 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Zinc 30-Dec-09 2.7 10.0 6.7 B ND NS 4.7 J NC 2B = 50 µg/L (05/01/07)01-Jun-10 2.7 10.0 6.7 J 8.7 J NS ND 29-Dec-10 0.40 10.0 ND 1.2 B 1.2 B 12.5 29-Jun-11 10.0 10.0 ND ND ND 10.5 01-Nov-11 10.0 10.0 ND ND ND ND 01-May-12 10.0 10.0 ND ND ND ND 07-Nov-12 1.31 10.0 ND ND 1.56 J ND 09-May-13 10.0 10.0 ND ND ND ND 07-Nov-13 10.0 10.0 ND ND ND ND 05-Jun-14 10.0 10.0 ND ND ND ND 20-Nov-14 5.0 10.0 ND ND ND ND Organic Compounds Acetone 29-Jun-11 2.2 100 2.8 B 3.3 B 4.4 B 5.3 J NC 2B = NE µg/L (05/01/07)01-Nov-11 2.2 100 ND ND ND 14.6 J 01-May-12 2.2 100 ND ND ND ND 07-Nov-12 0.193 100 ND ND ND ND 09-May-13 10.0 100 ND ND ND 12.0 J 07-Nov-13 10.0 100 ND ND ND ND 05-Jun-14 10.0 100 ND ND ND ND 20-Nov-14 10.0 100 ND ND ND ND cis-1,2-Dichloroethene 30-Dec-09 0.1 5.0 ND ND NS ND NC 2B = NE µg/L (05/01/07)01-Jun-10 0.1 5.0 ND ND NS ND 29-Dec-10 0.19 5.0 ND 0.39 J ND ND 29-Jun-11 0.19 5.0 0.26 J 0.30 J 0.33 J ND 01-Nov-11 0.19 5.0 ND ND ND ND 01-May-12 0.19 5.0 0.31 B ND ND 0.21 (ND)J 07-Nov-12 0.103 5.00 ND ND ND ND 09-May-13 0.19 5.0 ND ND ND ND 07-Nov-13 0.19 5.0 ND 0.38 J ND ND 05-Jun-14 0.19 5.0 ND 0.33 J ND ND 20-Nov-14 0.19 5.0 ND 0.49 J ND ND Notes: 1. RL = Reporting limit (NC SWSL). 2. All concentrations are in micrograms per liter (ug/L). 3. NC 2B Standard is the surface water quality standard. Classification is currently Freshwater Aquatic Life. 4. NS = Not sampled. 5. SMP = Surface water monitoring point. 6. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. 7. ND = Not detected at the laboratory's detection limit. 8. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. 9. B = Blank Qualifed 10. Shaded values are greater than the established NC 2B Surface Water Quality Standards. 11. DL = Detection limit. 12. NE = Not established. Town of Kernersville Landfill Permit No. 34-04 Page 3 of 3 Joyce Engineering TABLE 5 SUMMARY OF MNA CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 Alkalinity, Total as CaCO3 Jun-14 1000.0 5000 ---4600 J 148000 147000 160000 186000 (ug/L)Nov-14 1000.0 5000 ------159000 151000 159000 181000 Sulfate Jun-14 2000 250000 ---6500 J ND ND ND ND (ug/L)Nov-14 1000 250000 ------1760 J 1730 J 1870 J 1560 J Nitrogen, Nitrate Jun-14 20.0 1000 ---72 J 56 J ND ND ND (ug/L)Nov-14 10.0 1000 ------45 J ND ND ND Methane Jun-14 3.3 6.6 ------5530 254 242 515 (ug/L)Nov-14 3.3 6.6 ------4980 159 182 186 Chloride Jun-14 1000 1000 ---2220 11200 25900 16800 15600 (ug/L)Nov-14 500 1000 ------17100 27900 17300 17100 Total Organic Carbon Jun-14 1000 1000 ---3100 10600 8300 1500 8200 (ug/L)Nov-14 500 1000 ------2150 1750 1370 1100 Hydrogen Jun-14 0.13 0.6 ------1.5 1.2 120 3.5 (nM)Nov-14 0.13 0.6 ------2.0 1.1 4.4 1.4 BOD, 5 day Jun-14 2000 2000 ---ND ND ND ND ND (ug/L)Nov-14 2000 2000 ------4900 ND ND ND Chemical Oxygen Demand Jun-14 12500 25000 ---ND ND ND ND ND (ug/L)Nov-14 12500 25000 ------ND ND 431000 ND Notes: MW = Monitoring well. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. ND = Not detected at the laboratory's detection limit. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. B = Probable field and/or laboratory contamination since the concentration is within five times the concentration reported in the associated quality control blanks. DL = Detection limit. QL = Quantitation limit (NC SWSL). --- = Monitoring well was not sampled. Town of Kernersville Landfill Permit No. 34-04 Page 1 of 1 Joyce Engineering TABLE 6: BIODEGRADATION SCREENING MATRIX Parameter Concentration Interpretation Possible Points Awarded Points Awarded in Plume Points with DP points without DP points Oxygen < 0.5 mg/L Tolerated, suppresses the reductive pathway at higher 3 0 0 concentrations > 5 mg/L Not tolerated; however, vinyl chloride may be oxidized -3 0 0 aerobically Nitrate < 1 mg/L At higher concentrations may compete with reductive 2 2 2 pathway Iron II (Ferrous Iron)> 1 mg/L Reductive pathway possible; vinyl chloride may be 3 0 0 oxidized under Fe (III) - reducing conditions Sulfate < 20 mg/L At higher concentrations may compete with reductive 2 2 2 pathway Sulfide > 1 mg/L Reductive pathway possible 3 0 0 Methane < 0.5 mg/L Vinyl chloride oxidizes 0 > 0.5 mg/L Ultimate reductive daughter product, vinyl chloride 3 0 0 accumulates Oxidation Reduction < 50 mV Reductive pathway possible 1 1 1 Potential < -100 mV Reductive pathway likely 2 pH 5 < pH < 9 Optimal range for reductive pathway 0 0 0 5 > pH > 9 Outside optimal range for reductive pathway -2 0 0 TOC > 20 mg/L Carbon and energy source; drives dechlorination; can 2 0 0 be natural or anthropogenic Temperature >20o C At T > 20oC biochemical process is accelerated 1 0 0 Carbon Dioxide > 2x background Ultimate oxidative daughter product 1 0 0 Alkalinity > 2x background Results from interaction between CO2 and 1 1 1 aquifer minerals Chloride > 2x background Daughter product of organic chlorine 2 2 2 Hydrogen > 1 nM Reductive pathway possible 3 3 3 < 1 nM Vinyl chloride oxidizes 0 Volatile Fatty Acids > 0.1 mg/L Intermediates resulting from biodegradation of more 2 0 0 complex compounds; carbon and energy source BTEX > 0.1 mg/L Carbon and energy source; drives dechlorination 2 0 0 Tetrachloroethene (PCE)---Material released 0 0 0 Trichloroethene (TCE)---Material released 0 0 0 ---Daughter product of PCE 2 2 0 Dichloroethenes (DCE)---Material released 0 0 0 Daughter product of TCE 2 2 0 Dichloroethene, cis-1,2,---Material released 0 0 0 ---Daughter product of trichlorethene 2 2 0 Vinyl Chloride (VC)---Material released 0 0 0 ---Daughter product of DCE 2 2 0 1,1,1-Trichloroethane (TCA)---Material released 0 0 0 1,1-Dichloroethane (DCA)---Material released 0 0 0 Daughter product of TCA 2 2 0 Chloroethane ---Daughter product of dichloroethane or vinyl chloride 0 0 0 under reducing conditions 2 2 0 Ethene/Ethane > 0.01 mg/L Daughter products of vinyl chloride/ethene 2 0 0 > 0.1 mg/L 3 0 0 Chloroform ---Material released 0 0 0 ---Daughter product of carbon tetrachloride 2 0 0 Dichloromethane (MC)---Material released 0 0 0 (Methylene Chloride)---Daughter product of chloroform 2 0 0 Based on data collected in November 2014.Total Points Awarded :23 11 mg/L = miligrams per liter mV = millivolts NOTE: Chloroethane, Methane, TCE, DCE, cis-1,2-DCE, MC, VC, DCA, and CO2 are all present in the plume; however, nM = Nanometer it is uncertain whether these are primary leachate constituents or daughter products (DPs); therefore, we C = Celcius have two calculation columns. The first column assumes all of these are daughter products, and the NA = Not Analyzed second column assumes none of them are. The true score is probably between the two. BTEX = Sum of Benzene, Toluene, Ethylbenzene, and Total Xylenes SCORE:Evid. of Nat. Atten. This screening matrix is prepared in general accordance with the United Stated Environmental Protection Agency's < 5 inadequate (EPA's) Table 2.3 Analytical Parameters and Weighted for Preliminary Screening for Anaerobic Biodegradation 6-14 limited Process presented in the EPA's Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents 15-19 adequate in Groundwater , September 1988.> 20 strong Town of Kernersville Joyce Engineering Appendix II Summary of Detections WELL ID PARAMETER RESULT UNITS METHOD MDL SWSL COLLECT DATE 3404-MW2 Hydrogen 2 nM AM20GAX 0.13 NE 11/20/2014 3404-MW2 Barium 301 ug/L EPA 6010 2.5 100 11/20/2014 3404-MW2 1,1-Dichloroethane 21.5 ug/L EPA 8260 0.32 5 11/20/2014 3404-MW2 1,2-Dichloropropane 4.1 ug/L EPA 8260 0.27 1 11/20/2014 3404-MW2 1,4-Dichlorobenzene 4.7 ug/L EPA 8260 0.33 1 11/20/2014 3404-MW2 Benzene 6.2 ug/L EPA 8260 0.25 1 11/20/2014 3404-MW2 cis-1,2-Dichloroethene 44.9 ug/L EPA 8260 0.19 5 11/20/2014 3404-MW2 Tetrachloroethene 1.1 ug/L EPA 8260 0.46 1 11/20/2014 3404-MW2 Trichloroethene 5.1 ug/L EPA 8260 0.47 1 11/20/2014 3404-MW2 Vinyl chloride 5.2 ug/L EPA 8260 0.62 1 11/20/2014 3404-MW2 Methane 4980 ug/L RSK 175 3.3 NE 11/20/2014 3404-MW2 Alkalinity, Total as CaCO3 159000 ug/L SM 2320B 1000 NE 11/20/2014 3404-MW2 Chloride 17100 ug/L SM 4500-Cl-E 500 NE 11/20/2014 3404-MW2 BOD, 5 day 4900 ug/L SM 5210B 2000 NE 11/20/2014 3404-MW2 Total Organic Carbon 2150 ug/L SM 5310B 500 NE 11/20/2014 3404-MW3D Hydrogen 4.4 nM AM20GAX 0.13 NE 11/20/2014 3404-MW3D 1,2-Dichloropropane 1.2 ug/L EPA 8260 0.27 1 11/20/2014 3404-MW3D 1,4-Dichlorobenzene 3.8 ug/L EPA 8260 0.33 1 11/20/2014 3404-MW3D cis-1,2-Dichloroethene 55.4 ug/L EPA 8260 0.19 5 11/20/2014 3404-MW3D Vinyl chloride 5.3 ug/L EPA 8260 0.62 1 11/20/2014 3404-MW3D Methane 182 ug/L RSK 175 3.3 NE 11/20/2014 3404-MW3D Alkalinity, Total as CaCO3 159000 ug/L SM 2320B 1000 NE 11/20/2014 3404-MW3D Chloride 17300 ug/L SM 4500-Cl-E 500 NE 11/20/2014 3404-MW3D Chemical Oxygen Demand 431000 ug/L SM 5220D 12500 NE 11/20/2014 3404-MW3D Total Organic Carbon 1370 ug/L SM 5310B 500 NE 11/20/2014 3404-MW3S Hydrogen 1.1 nM AM20GAX 0.13 NE 11/20/2014 3404-MW3S Barium 113 ug/L EPA 6010 2.5 100 11/20/2014 3404-MW3S Zinc 20.9 ug/L EPA 6010 5 10 11/20/2014 3404-MW3S 1,4-Dichlorobenzene 1.9 ug/L EPA 8260 0.33 1 11/20/2014 3404-MW3S cis-1,2-Dichloroethene 9.6 ug/L EPA 8260 0.19 5 11/20/2014 3404-MW3S Vinyl chloride 2.1 ug/L EPA 8260 0.62 1 11/20/2014 3404-MW3S Methane 159 ug/L RSK 175 3.3 NE 11/20/2014 3404-MW3S Alkalinity, Total as CaCO3 151000 ug/L SM 2320B 1000 NE 11/20/2014 3404-MW3S Chloride 27900 ug/L SM 4500-Cl-E 500 NE 11/20/2014 3404-MW3S Total Organic Carbon 1750 ug/L SM 5310B 500 NE 11/20/2014 3404-MW4 Hydrogen 1.4 nM AM20GAX 0.13 NE 11/20/2014 3404-MW4 1,4-Dichlorobenzene 2.6 ug/L EPA 8260 0.33 1 11/20/2014 3404-MW4 cis-1,2-Dichloroethene 19.3 ug/L EPA 8260 0.19 5 11/20/2014 3404-MW4 Vinyl chloride 16.2 ug/L EPA 8260 0.62 1 11/20/2014 3404-MW4 Methane 186 ug/L RSK 175 3.3 NE 11/20/2014 3404-MW4 Alkalinity, Total as CaCO3 181000 ug/L SM 2320B 1000 NE 11/20/2014 3404-MW4 Chloride 17100 ug/L SM 4500-Cl-E 500 NE 11/20/2014 3404-MW4 Total Organic Carbon 1100 ug/L SM 5310B 500 NE 11/20/2014 3404-MW5 Barium 108 ug/L EPA 6010 2.5 100 11/20/2014 3404-MW5 Cobalt 10.2 ug/L EPA 6010 2.5 10 11/20/2014 3404-MW5 Zinc 55 ug/L EPA 6010 5 10 11/20/2014 Town of Kernersville Landfill Joyce Engineering Appendix III Summary of Exceedances WELL ID PARAMETER RESULT UNITS METHOD MDL NC2L or GWPS COLLECT DATE 3404-MW2 1,1-Dichloroethane 21.5 ug/L EPA 8260 0.32 6 11/20/2014 3404-MW2 1,2-Dichloropropane 4.1 ug/L EPA 8260 0.27 0.6 11/20/2014 3404-MW2 Benzene 6.2 ug/L EPA 8260 0.25 1 11/20/2014 3404-MW2 Tetrachloroethene 1.1 ug/L EPA 8260 0.46 0.7 11/20/2014 3404-MW2 Trichloroethene 5.1 ug/L EPA 8260 0.47 3 11/20/2014 3404-MW2 Vinyl chloride 5.2 ug/L EPA 8260 0.62 0.03 11/20/2014 3404-MW3D 1,2-Dichloropropane 1.2 ug/L EPA 8260 0.27 0.6 11/20/2014 3404-MW3D Vinyl chloride 5.3 ug/L EPA 8260 0.62 0.03 11/20/2014 3404-MW3S Vinyl chloride 2.1 ug/L EPA 8260 0.62 0.03 11/20/2014 3404-MW4 Vinyl chloride 16.2 ug/L EPA 8260 0.62 0.03 11/20/2014 3404-MW5 Cobalt 10.2 ug/L EPA 6010 2.5 1 11/20/2014 Town of Kernersville Landfill Joyce Engineering