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HomeMy WebLinkAbout2601_CumberlandCoAnnSt_GWMR_DIN28534_20170630 (2)Cumberland County Closed Ann Street Landfill Facility Permit No. 2601-MSWLF-1980 Semi-Annual Sampling Report (March 2017 Sampling Event) Report Prepared June 2017 5400 Glenwood Avenue, Suite 400 Raleigh, North Carolina 27612 tel: 919 325-3500 fax: 919 781-5730 June 30, 2017 Mr. Ervin Lane North Carolina Department of Environmental Quality Division of Waste Management Solid Waste Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Subject: March 2017 Semi-Annual Monitoring Sampling Report Cumberland County Closed Ann Street Landfill Facility Permit No. 2601-MSWLF-1980 Dear Mr. Lane: CDM Smith Inc. (CDM Smith), on behalf of Cumberland County (County), is submitting an electronic copy of the March 2017 semi-annual sampling event report. This letter report presents the results of the semi-annual sampling event that was recently completed at the closed Cumberland County Ann Street Landfill and constitutes the first semi-annual sampling event for 2017. The current groundwater monitoring network consists of the following wells: MW-A, -1a, -B, -H, AW-1s, -1d, -2, -3, and -4. Surface water sample locations include SW-3, -4, -5, and -6. Field activities, sampling results, and an evaluation of the groundwater corrective action are discussed below. Field Activities Groundwater and surface water samples from the closed Cumberland County Ann Street Landfill were collected on March 7-8, 2017. Groundwater samples were collected by use of a peristaltic pump using low-flow sampling techniques. Groundwater and surface water sample locations are presented on Figure 1. Well construction details for each monitoring well are summarized in Table 1. Groundwater elevations were measured at each well prior to sampling and are presented in Table 2. These groundwater elevations were used to construct the potentiometric contours for this sampling event as shown on Figure 1. The groundwater elevations and potentiometric contours were used to estimate groundwater velocities at each well as presented in Table 3. After depth to groundwater was measured, water was purged from each well to provide fresh formation water within the well water column prior to sampling. Each well volume and surface water sample was measured for pH, conductivity, temperature, turbidity, dissolved oxygen, and oxidation-reduction potential using a YSI-556 multi-parameter water quality meter and a HANNA HI 98703 turbidity meter. The water quality parameters at the time of sampling are presented in Table 4. Mr. Ervin Lane June 30, 2017 Page 2 Sampling Results Environmental Conservation Laboratories, Inc., located in Cary, North Carolina, analyzed the groundwater and surface water samples for the North Carolina Appendix I volatile organic compounds (VOCs) and metals. VOCs were analyzed using U.S Environmental Protection Agency (EPA) Method 8260B and metals were analyzed using EPA Methods 6010D and 6020B. Monitoring wells MW-A, -B, -H, and AW-2 were sampled for geochemical constituents as part of the corrective action, monitored natural attenuation (MNA), for the closed landfill. The MNA sampling results are discussed in the Corrective Action Effectiveness Evaluation section of this report. In accordance with the North Carolina Department of Environmental Quality’s (NCDEQ) - Solid Waste Section (SWS) guidelines the analytical results were reported to the laboratory specific method detection limit (MDL) and are quantifiable at or below SWS Limits (SWSLs). All monitoring wells and surface water sample locations for the closed Cumberland County Ann Street Landfill had detections of analytes above the laboratory specific MDL but below the SWSL. These detections were qualified with “J” flags, which indicate an estimated concentration. The following list indicates which analytes were detected above the laboratory MDL at each sampling location. No “J” flag detections are provided. Underlined analytes exceeded the 15A NCAC 02L .0202 (NC 2L) Groundwater Quality Standard, Groundwater Protection Standard, or the 15A NCAC 02B Surface Water Quality Standard for Class C Waters. A complete summary of all detected and estimated concentrations from the March 2011 to the March 2017 sampling event is presented in Table 5. The laboratory analytical data reports are provided in Appendix A. MW-A (Background) Metals: Barium Volatile Organic Compounds: None Detected MW-1A Metals: Arsenic, Barium Volatile Organic Compounds: None Detected MW-B Metals: Arsenic, Barium Volatile Organic Compounds: Benzene, Chlorobenzene, 1,4-Dichlorobenzene MW-H Metals: Arsenic, Barium, Zinc Volatile Organic Compounds: Benzene, Chlorobenzene, 1,4-Dichlorobenzene Mr. Ervin Lane June 30, 2017 Page 3 AW-1s Metals: Barium, Cobalt, Zinc Volatile Organic Compounds: None Detected AW-1d Metals: Barium Volatile Organic Compounds: None Detected AW-2 Metals: Barium, Cobalt Volatile Organic Compounds: None Detected AW-3 Metals: None Detected Volatile Organic Compounds: None Detected AW-4 Metals: Barium Volatile Organic Compounds: None Detected SW-3 Metals: Dry Volatile Organic Compounds: Dry SW-4 Metals: Barium Volatile Organic Compounds: None Detected SW-5 Metals: Barium Volatile Organic Compounds: Chlorobenzene, 1,4-Dichlorobenzene SW-6 Metals: Barium Volatile Organic Compounds: None Detected “J” flags were not included in the previous list, but several sampling locations had “J” flag detections that exceeded the standards. The “J” flag constituents above the standards along with their location are listed below. Cobalt: MW-1A, -A, -B, -H, AW-3, -4, SW-4, and -6 Silver: SW-4 Mr. Ervin Lane June 30, 2017 Page 4 Thallium: MW-1A, -A, AW-1s, -1d, -2, and -4 Vanadium: MW-1A, -A, -B, -H, AW-1s, -1d, -2, -3, and -4 Quality assurance and quality control samples were analyzed for the March 2017 sampling event. A duplicate sample, identified as Dup, was collected from MW-1A. The duplicate sample had similar analyte concentrations as those detected in MW-1A, with the exception of an estimated detection of silver in the duplicate sample. No analytes were detected in the trip blank. Table 6 presents a summary of all parameters detected during the March 2017 sampling event that exceeded the NC 2L or Groundwater Protection Standards. Metals detected above the standards are likely natural occurring based on concentrations in the background monitoring well (MW-A) or are from elevated turbidity at the time of sample collection. Corrective Action Effectiveness Evaluation Vinyl chloride was detected in AW-2 from March 2007 to March 2009 as an estimated concentration above the NC 2L Standard. As a result, in August 2007 CDM Smith, on behalf of the County, submitted an Assessment of Corrective Measures Report for the Closed Unlined Landfill in accordance with the North Carolina Solid Waste Management Rule 15 NCAC 13B .1635. MNA along with institutional controls was selected as the remedy to address groundwater contamination at the facility. In a letter dated February 5, 2009, from the SWS to Cumberland County, the SWS determined that MNA should not be used as the sole remedial measure due to vinyl chloride concentrations exceeding the NC 2L Standard beyond the relevant point of compliance, 250 feet from the waste boundary in the vicinity of assessment monitoring well AW-2. In response, the contingency plan of in situ remediation by enhanced anaerobic bioremediation was implemented. Following the approval of the injection permit and the installation of five injection wells, emulsified oil substrate (EOS) was injected upgradient of assessment well AW-2 in November 2009. The initial EOS injection successfully eliminated VOCs in groundwater for approximately 2.5 years with the exception of a “J” flag detection of acetone in August 2010. At the time of the original design, it was expected that re- injection would be necessary in 3 to 5 years. Groundwater samples collected from AW-2 during the March 2012 semi-annual sampling event had detections of vinyl chloride above the NC 2L Standard. Confirmatory samples collected from AW-2 on March 27, 2012, had concentrations of vinyl chloride similar to the semi-annual sampling event completed earlier in the month. Additionally, samples collected during the September 2012 semi-annual sampling event had detections of vinyl chloride and benzene above the NC 2L Standard. As stated in the approved Corrective Action Plan for the landfill, re-injection would be necessary when contaminants were detected above NC 2L Standards in assessment wells (i.e. AW-1s, -1d, -2, -3, and -4) located near the landfill property boundary. Groundwater samples were collected from injection well IW-3 and assessment well AW-2 on November 28, 2012, to determine the populations of Mr. Ervin Lane June 30, 2017 Page 5 Dehalococcoides spp bacteria and the specific genes of the bacteria that promote dechlorination. Samples were also collected to evaluate geochemical conditions and VOC concentrations. A work plan detailing this additional assessment was submitted to the SWS on December 13, 2012. Based on an evaluation of the sample data it was determined that re-injection would be necessary to reduce the concentration of vinyl chloride and benzene below their respective NC 2L Standards. Under reducing conditions, vinyl chloride can degrade through multiple mechanisms (e.g. anaerobic oxidation, anaerobic biodegradation, and co-metabolism). Biodegradation of vinyl chloride can be sustained for as long as sufficient concentrations of biologically degradable organic carbon remain in groundwater. For this reason, LactOil© was selected as the re-injection substrate because it is a slow-release compound, and therefore will release organic carbon into the groundwater for up to three years. This substrate will enhance biologically reducing conditions that will favor and support complete dechlorination of vinyl chloride to the non-toxic end-products ethene and ethane. An injection permit was submitted to the NCDEQ Division of Water Quality - Aquifer Protection Section (APS) on February 22, 2013. Following approval of the permit, the re-injection event was completed from April 29 through May 8, 2013, using LactOil© as the substrate. A total of 18,333 gallons of a 3.0% LactOil© and water solution was injected with each well receiving approximately 3,652 gallons of solution with the exception of injection well IW-5 which received 3,723 gallons of solution. Approximately 50 gallons of water was flushed through each well to ensure that no substrate remained in the well upon completion of the injection. As required by the injection permit, an Injection Event Record was submitted to the APS on May 28, 2013. Samples collected from AW-2 during the June 2013 semi-annual sampling event and the August 2013 injection performance monitoring event were below laboratory MDLs for vinyl chloride. However, vinyl chloride was detected as an estimated concentration above the NC 2L Standard in samples collected from AW-2 during the November 2013 sampling event. It is common for contaminant concentrations to rebound following an injection event as VOCs adsorbed to soil enter the dissolved phase where they then become available for biodegradation. As expected, vinyl chloride has been detected below laboratory MDLs in samples collected from AW-2 since the April 2014 sampling event. Benzene was detected above the NC 2L Standard in AW-2 at 1.4 parts per billion (ppb) in September 2012. The concentration of benzene has decreased in AW-2 since the September 2012 sampling event and has been detected below laboratory MDLs in samples collected from AW-2 since the April 2014 sampling event. Additional groundwater samples were collected from the background well MW-A, monitoring wells MW-B and -H, and assessment well AW-2. The samples were analyzed for alkalinity, biochemical oxygen demand, chemical oxygen demand, carbon dioxide, chloride, dissolved hydrogen, ethane, ethene, volatile fatty acids (i.e. acetic, butyric, lactic, propionic, and pyruvic), ferrous iron, methane, nitrate, sulfate, sulfide, and total organic carbon. These additional samples were collected to monitor for natural Mr. Ervin Lane June 30, 2017 Page 6 attenuation and to evaluate the substrate injected into the area upgradient of AW-2 as part of the approved corrective action program as required by SWS guidelines. A complete summary of the geochemical results is presented in Table 5e. The geochemical results indicate reducing conditions at the wells sampled for natural attenuation parameters. As part of the corrective action, contaminant concentration trends for monitoring wells MW-B, -H, and AW-2 were evaluated. Total VOC contaminant concentration trends for each well are presented on Figures 2 through 4. Trend results for each well are discussed below. The trend analysis for total VOC concentrations in MW-B is presented on Figure 2 and shows a decrease in contaminant concentrations with time. VOCs were not detected in samples from MW-B from March 2004 to October 2006. The March 2007 sampling event was the first event that estimated concentrations (i.e. “J” flags) were reported. VOCs were not detected above the NC 2L Standards in MW-B from March 2011 through May 2015. Benzene was detected slightly above the NC 2L Standard (1 ppb) at 1.1 ppb in November 2015 and March 2016, and at the NC 2L Standard in August 2016 and March 2017 (1.0 ppb). Figure 3 presents the trend analysis for total VOC concentrations in MW-H. The trend line shows an increase in total VOC concentrations since January 1995. Benzene and 1,4-dichlorobenzene are the only two analytes that have been detected above the NC 2L Standard in MW-H since the May 2010 sampling event. Benzene was initially detected in MW-H in January 1995 at 9 ppb and was detected at 3.3 ppb in March 2017. The concentration of 1,4-dichlorobenzene has historically fluctuated in MW-H, but has shown a decreasing trend since the April 2006 sampling event. The concentration of benzene and 1,4-dichlorobenzene in MW-H are expected to continue to decrease by natural attenuation. The trend analysis for total VOC concentrations in AW-2 is presented on Figure 4 and shows an increase in contaminant concentrations with time. The increase in total VOC concentration in September 2012 is from the estimated detection of acetone at 6.3 ppb. Acetone is a common laboratory contaminant and has only been detected in AW-2 in August 2010 and September 2012. Historically, vinyl chloride and benzene are the only two analytes that have been detected above the NC 2L Standard in AW-2. No VOCs have been detected in AW-2 above the NC 2L Standards since the November 2013 sampling event. Assessment wells AW-1s and -1d are located directly downgradient of MW-H. As of yet, there have only been a few estimated “J” flag detections of VOCs in either well below NC 2L Standards, with the exception of vinyl chloride at 1 ppb in AW-1s during the May 1999 sampling event. Future analytical data will be monitored to determine if any trends appear. All of the wells will continue to be monitored on a semi-annual basis, and trend analyses will be performed after each sampling event. The next sampling event will be completed in the fall of 2017. Mr. Ervin Lane June 30, 2017 Page 7 Landfill Gas Monitoring The approved landfill gas (LFG) monitoring network consists of the following wells: M-1, -2, -3, -4, -5, -6, -7, and -8 as shown on Figure 1. LFG monitoring wells M-7 and M-8 were installed at the compliance boundary in 2012 due to elevated concentrations in M-3 and M-5. Quarterly landfill gas monitoring of the Subtitle D Landfill was completed on March 9 and June 19, 2017, using either a GEM 2000 Plus or a GEM 5000 landfill gas analyzer. Hydrogen sulfide was not detected in any LFG monitoring wells, however methane was detected above the lower explosive limit (LEL) in LFG monitoring wells M-3 and M-5 during both events. The LEL was not exceeded in M-7 or M-8 during either event. Copies of the quarterly landfill gas monitoring results and GEM 5000 calibration data have been placed in the landfill operating record and are provided in Appendix B. If you have any questions or require further explanation, do not hesitate to call me at (919) 325-3500 or by email at weispfenningam@cdmsmith.com. Very truly yours, Aaron M. Weispfenning, P.E. CDM Smith Inc. Attachments cc: Jerod Roberts, Cumberland County Tables Table 1 Monitoring Well Construction Summary Cumberland County Closed Landfill Facility Permit Number 2601-MSWLF-1980 Screened Interval Filter Interval Seal Interval 2601-MSWLF-1980 MW-A (Background Well)8/1/1994 35.06656 78.87113 Surficial Aquifer 26 16.0-26.0 14.0-26.0 12.0-14.0 2.0 2601-MSWLF-1980 MW-1A 8/1/1994 35.06240 78.86430 Surficial Aquifer 26 16.0-26.0 14.0-26.0 12.0-14.0 2.0 2601-MSWLF-1980 MW-B 5/1/1995 35.06338 78.86399 Surficial Aquifer 26 16.0-26.0 14.0-26.0 12.0-14.0 2.0 2601-MSWLF-1980 MW-H 1/1/1995 35.06286 78.86622 Surficial Aquifer 20 10.0-20.0 8.0-20.0 6.0-8.0 2.0 2601-MSWLF-1980 AW-1s 4/19/1999 35.06174 78.86591 Surficial Aquifer 18 8.0-18.0 6.0-18.0 4.0-6.0 2.0 2601-MSWLF-1980 AW-1d 4/19/1999 35.06171 78.86608 Surficial Aquifer 40 30.0-40.0 28.0-40.0 26.0-28.0 2.0 2601-MSWLF-1980 AW-2 4/17/1999 35.06132 78.86731 Surficial Aquifer 23 8.0-23.0 6.0-23.0 4.0-6.0 2.0 2601-MSWLF-1980 AW-3 4/19/1999 35.06112 78.86934 Surficial Aquifer 17 7.0-17.0 5.0-17.0 3.0-5.0 2.0 2601-MSWLF-1980 AW-4 4/17/1999 35.06401 78.87086 Surficial Aquifer 17 7.0-17.0 5.0-17.0 3.0-5.0 2.0 Notes: 1. bgs - Below Ground Surface 2. Horizontal Control - World Geodetic System 1984 Facility Permit Number Depth (feet bgs)Total Depth (feet bgs) Monitoring Well Diameter (inches) Monitoring Well Code Geology of Screened Interval Completion Date Latitude Longitude Page 1 of 1 June 2017 Table 2 Groundwater Elevations March 2017 Semi-Annual Sampling Event Cumberland County Closed Landfill Facility Permit Number 2601-MSWLF-1980 3/28/11 9/27/11 3/6/12 9/26/12 6/5/13 11/12/13 4/22/14 11/5/14 5/27/15 11/10/15 2601-MSWLF-1980 MW-A 93.49 91.2 82.20 82.15 81.88 82.52 82.32 82.08 83.10 82.44 82.49 83.79 2601-MSWLF-1980 MW-B 87.78 85.1 71.24 71.42 71.08 71.69 71.37 71.42 71.94 71.61 71.53 71.69 2601-MSWLF-1980 MW-1A 87.32 85.1 73.51 74.57 73.98 75.00 74.57 72.59 74.76 74.14 74.11 74.01 2601-MSWLF-1980 MW-H 88.08 85.5 72.78 72.59 72.69 73.26 72.89 73.11 74.15 73.24 73.41 73.75 2601-MSWLF-1980 AW-1s 83.88 81.7 71.29 70.77 70.70 71.72 71.46 71.67 73.19 71.79 72.02 72.00 2601-MSWLF-1980 AW-1d 84.26 81.7 70.46 70.58 70.08 71.36 70.63 71.37 71.80 71.43 71.12 71.40 2601-MSWLF-1980 AW-2 90.25 87.9 70.08 69.81 69.68 70.70 70.49 70.73 71.76 70.88 71.13 70.64 2601-MSWLF-1980 AW-3 87.01 84.2 80.79 80.40 81.45 80.70 80.30 79.32 81.79 80.27 80.47 82.40 2601-MSWLF-1980 AW-4 92.76 89.6 81.17 81.36 81.16 81.08 81.04 80.85 81.49 81.13 81.23 81.45 Notes: 1. AMSL - Above Mean Sea Level 2. Replacement well (MW-B) installed 4/95. 3. MW-H installed 12/94. AW-1s thru AW-4 installed March 1999. Groundwater Elevations (AMSL)Facility Permit Number Monitoring Well Code TOC Elevation (AMSL) Ground Elevation (AMSL) Page 1 of 2 June 2017 Table 2 Groundwater Elevations March 2017 Semi-Annual Sampling Event Cumberland County Closed Landfill Facility Permit Number 2601-MSWLF-1980 2601-MSWLF-1980 MW-A 93.49 91.2 2601-MSWLF-1980 MW-B 87.78 85.1 2601-MSWLF-1980 MW-1A 87.32 85.1 2601-MSWLF-1980 MW-H 88.08 85.5 2601-MSWLF-1980 AW-1s 83.88 81.7 2601-MSWLF-1980 AW-1d 84.26 81.7 2601-MSWLF-1980 AW-2 90.25 87.9 2601-MSWLF-1980 AW-3 87.01 84.2 2601-MSWLF-1980 AW-4 92.76 89.6 Notes: 1. AMSL - Above Mean Sea Level 2. Replacement well (MW-B) installed 4/95. 3. MW-H installed 12/94. AW-1s thru AW-4 installed March 1999. Facility Permit Number Monitoring Well Code TOC Elevation (AMSL) Ground Elevation (AMSL)3/15/16 8/25/16 3/7/17 83.33 80.65 80.38 72.09 71.73 71.67 74.90 71.98 72.83 73.85 73.09 73.10 73.46 71.57 71.57 72.81 69.36 68.80 72.94 70.72 70.99 81.39 79.21 79.92 81.36 80.06 81.31 Groundwater Elevations (AMSL) Page 2 of 2 June 2017 Table 3Summary of Calculated Groundwater Flow VelocitiesMarch 2017 Semi-Annual Sampling EventCumberland County Closed LandfillFacility Permit Number 2601-MSWLF-1980Hydraulic Average Average Average Average Average ConductivityLinear VelocityLinear VelocityLinear VelocityLinear VelocityLinear Velocityfeet/day (cm/s)feet/dayfeet/dayfeet/dayfeet/dayfeet/day2601-MSWLF-1980MW-A0.200.4230.150.00364.74E-030.00354.69E-030.00344.52E-030.00354.73E-030.00364.76E-037.06E-052601-MSWLF-1980MW-B0.140.4960.100.00456.34E-030.00446.21E-030.00456.25E-030.00456.27E-030.00456.33E-034.94E-052601-MSWLF-1980MW-1A0.140.4960.100.00344.79E-030.00304.18E-030.00314.35E-030.00304.14E-030.00314.27E-034.94E-052601-MSWLF-1980MW-H0.140.4960.100.00486.66E-030.00486.76E-030.00466.50E-030.00476.55E-030.00486.67E-034.94E-052601-MSWLF-1980AW-1s4.230.3310.150.00471.34E-010.00491.40E-010.00491.37E-010.00471.33E-010.00471.33E-011.49E-032601-MSWLF-1980AW-1d0.140.4960.104.92E-052601-MSWLF-1980AW-22.980.4960.100.00551.64E-010.00561.67E-010.00551.65E-010.00541.60E-010.00541.60E-011.05E-032601-MSWLF-1980AW-30.790.4960.150.00073.59E-030.00084.46E-030.00021.10E-030.00094.64E-030.00105.15E-032.78E-042601-MSWLF-1980AW-42.480.4960.150.00132.07E-020.00101.59E-020.00091.45E-020.00182.90E-020.00162.58E-028.74E-04Notes:1. Porosity values are from laboratory analysis.2. Effective porosity is estimated from "Specific Yields of Various Geologic Materials," USGS Water Supply Paper 1662-D.3. AW-1s through AW-4 were installed in March 1999.4. Blank cells indicate no data.09/27/11Facility Permit NumberMonitoring Well CodePorosityEffective Porosity09/26/12Sampling Date:03/06/1206/05/1303/28/11Gradient Gradient Gradient GradientGradientPage 1 of 3June 2017 Table 3Summary of Calculated Groundwater Flow VelocitiesMarch 2017 Semi-Annual Sampling EventCumberland County Closed LandfillFacility Permit Number 2601-MSWLF-1980Hydraulic Conductivityfeet/day (cm/s)2601-MSWLF-1980MW-A0.200.4230.157.06E-052601-MSWLF-1980MW-B0.140.4960.104.94E-052601-MSWLF-1980MW-1A0.140.4960.104.94E-052601-MSWLF-1980MW-H0.140.4960.104.94E-052601-MSWLF-1980AW-1s4.230.3310.151.49E-032601-MSWLF-1980AW-1d0.140.4960.104.92E-052601-MSWLF-1980AW-22.980.4960.101.05E-032601-MSWLF-1980AW-30.790.4960.152.78E-042601-MSWLF-1980AW-42.480.4960.158.74E-04Facility Permit NumberMonitoring Well CodePorosityEffective PorositySampling Date:Average Average Average Average Average Linear VelocityLinear VelocityLinear VelocityLinear VelocityLinear Velocityfeet/dayfeet/dayfeet/dayfeet/dayfeet/day0.00364.80E-030.00354.66E-030.00364.75E-030.00354.69E-030.00415.44E-030.00446.17E-030.00466.46E-030.00456.27E-030.00456.34E-030.00507.00E-030.00375.23E-030.00334.60E-030.00334.57E-030.00334.62E-030.00395.39E-030.00456.34E-030.00456.33E-030.00466.51E-030.00466.42E-030.00517.10E-030.00451.28E-010.00431.22E-010.00461.31E-010.00461.28E-010.00511.45E-010.00521.54E-010.00521.54E-010.00531.57E-010.00521.54E-010.00601.78E-010.00137.04E-030.00063.34E-030.00115.53E-030.00105.15E-030.00073.54E-030.00152.48E-020.00203.24E-020.00162.64E-020.00152.54E-020.00294.71E-02Notes:1. Porosity values are from laboratory analysis.2. Effective porosity is estimated from "Specific Yields of Various Geologic Materials," USGS Water Supply Paper 1662-D.3. AW-1s through AW-4 were installed in March 1999.4. Blank cells indicate no data.11/12/1311/05/1404/22/1411/10/15Gradient05/27/15GradientGradient Gradient GradientPage 2 of 3June 2017 Table 3Summary of Calculated Groundwater Flow VelocitiesMarch 2017 Semi-Annual Sampling EventCumberland County Closed LandfillFacility Permit Number 2601-MSWLF-1980Hydraulic Conductivityfeet/day (cm/s)2601-MSWLF-1980MW-A0.200.4230.157.06E-052601-MSWLF-1980MW-B0.140.4960.104.94E-052601-MSWLF-1980MW-1A0.140.4960.104.94E-052601-MSWLF-1980MW-H0.140.4960.104.94E-052601-MSWLF-1980AW-1s4.230.3310.151.49E-032601-MSWLF-1980AW-1d0.140.4960.104.92E-052601-MSWLF-1980AW-22.980.4960.101.05E-032601-MSWLF-1980AW-30.790.4960.152.78E-042601-MSWLF-1980AW-42.480.4960.158.74E-04Facility Permit NumberMonitoring Well CodePorosityEffective PorositySampling Date:Average Average Average Linear VelocityLinear VelocityLinear Velocityfeet/dayfeet/dayfeet/day0.00364.78E-030.00303.97E-030.00283.75E-030.00466.50E-030.00375.16E-030.00365.04E-030.00334.65E-030.00344.78E-030.00304.16E-030.00486.70E-030.00385.35E-030.00375.15E-030.00431.21E-010.00401.12E-010.00381.08E-010.00471.41E-010.00451.35E-010.00431.27E-010.00094.95E-030.00073.67E-030.00021.17E-030.00243.97E-020.00071.19E-020.00111.87E-02Notes:1. Porosity values are from laboratory analysis.2. Effective porosity is estimated from "Specific Yields of Various Geologic Materials," USGS Water Supply Paper 1662-D.3. AW-1s through AW-4 were installed in March 1999.4. Blank cells indicate no data.03/07/17Gradient08/25/16Gradient03/15/16GradientPage 3 of 3June 2017 Table 4 Water Quality Parameters March 2017 Semi-Annual Sampling Event Cumberland County Closed Landfill Facility Permit Number 2601-MSWLF-1980 pH Cond.Temp.Turb.DO ORP pH Cond.Temp.Turb.DO ORP pH Cond.Temp.Turb.DO ORP (S.U.)(µS/cm)(deg. C)(NTUs)(mg/L)(mVs)(S.U.)(µS/cm)(deg. C)(NTUs)(mg/L)(mVs)(S.U.)(µS/cm)(deg. C)(NTUs)(mg/L)(mVs) 2601-MSWLF-1980 MW-A 6.10 203 17.1 39 1.49 56.4 6.19 280 19.9 26 0.50 -23.3 5.81 219 18.2 54 2.29 83.5 2601-MSWLF-1980 MW-B 6.16 1,436 16.5 25 0.25 56.2 6.21 1,579 21.0 43 0.53 -67.1 5.99 1,412 17.5 11 0.32 -43.1 2601-MSWLF-1980 MW-1A 6.31 1,201 15.5 36 1.75 43.3 6.38 1,462 18.0 31 3.64 -94.5 6.15 1,546 16.3 27 1.68 -86.6 2601-MSWLF-1980 MW-H 6.01 1,575 14.5 8 0.43 54.2 6.06 1,867 20.9 11 0.28 -67.9 5.91 1,980 16.8 6 0.17 -37.6 2601-MSWLF-1980 AW-1s 4.91 408 13.6 20 2.83 60.2 5.43 376 20.6 6 1.69 -4.5 4.96 335 15.4 4 2.69 67.1 2601-MSWLF-1980 AW-1d 6.37 171 15.7 9 3.68 56.5 6.29 211 18.9 12 2.10 -12.9 6.24 240 16.7 6 3.03 -6.8 2601-MSWLF-1980 AW-2 6.23 578 14.5 15 0.65 52.3 6.20 683 19.0 27 0.54 -56.5 6.06 1,091 14.4 81 0.61 -37.4 2601-MSWLF-1980 AW-3 4.69 54 12.2 58 3.89 63.3 4.72 57 21.6 38 5.66 301.7 4.46 79 12.5 9 3.17 213.7 2601-MSWLF-1980 AW-4 5.43 259 15.2 9 3.06 35.9 5.55 329 23.0 16 1.17 10.4 5.47 327 16.3 4 3.42 30.2 2601-MSWLF-1980 SW-3 6.27 926 8.9 80 9.26 60.5 6.82 319 23.5 536 5.27 -27.1 6.55 795 13.1 68 10.74 0.7 2601-MSWLF-1980 SW-4 6.83 984 10.6 84 13.65 50.8 7.63 321 28.1 132 8.71 -24.1 7.12 723 15.8 129 8.69 -62.8 2601-MSWLF-1980 SW-5 6.99 1,117 11.9 43 9.26 43.5 7.26 1,407 24.6 23 4.05 22.9 6.68 1,194 15.6 51 7.65 34.1 2601-MSWLF-1980 SW-6 8.06 549 13.4 33 8.89 35.8 7.41 380 22.8 19 5.07 28.2 7.25 457 14.9 10 10.65 33.8 1. Replacement well MW-B installed 4/95.8. Cond. - Conductivity (µS/cm - Microsiemens per centimeter) 2. MW-H installed 12/94. AW-1s thru AW-4 installed March 1999.9. S.U. - Standard Units 3. SW-6 was first sampled in May 2010.10. Temp. - Temperature (deg. C - degrees Celsius) 4. Turbidity recorded at time of sampling.` 5. ORP - Oxidation-Reduction Potential (mVs - millivolts) 6. DO - Dissolved Oxygen (mg/L - milligrams per liter) 7. Turb. - Turbidity (NTUs - Nephelometric Turbidity Units) 3/6-7/2012 No.38 9/27-28/2011 No.37 No.39 3/28-29/2011 Event: Sampling Date: Notes: Facility Permit Number Monitoring Well Code Surface Water Sample Location Page 1 of 5 June 2017 Table 4 Water Quality Parameters March 2017 Semi-Annual Sampling Event Cumberland County Closed Landfill Facility Permit Number 2601-MSWLF-1980 pH Cond.Temp.Turb.DO ORP pH Cond.Temp.Turb.DO ORP pH Cond.Temp.Turb.DO ORP (S.U.)(µS/cm)(deg. C)(NTUs)(mg/L)(mVs)(S.U.)(µS/cm)(deg. C)(NTUs)(mg/L)(mVs)(S.U.)(µS/cm)(deg. C)(NTUs)(mg/L)(mVs) 2601-MSWLF-1980 MW-A 6.14 294 20.2 11 0.59 12.4 6.18 297 19.8 44 0.52 -5.1 6.55 291 16.5 16 0.46 -2.2 2601-MSWLF-1980 MW-B 6.23 1,451 20.1 28 0.35 -37.5 6.26 1,381 20.1 48 0.46 -60.3 6.52 1,311 17.1 45 0.42 -40.6 2601-MSWLF-1980 MW-1A 6.27 1,179 19.0 7 0.47 -65.2 6.33 1,366 17.5 35 0.43 -87.4 6.44 1,186 17.9 16 0.48 49.4 2601-MSWLF-1980 MW-H 6.06 1,808 20.2 3 0.24 -19.4 6.19 1,729 18.7 12 0.45 -72.2 6.42 1,718 17.9 18 0.43 -33.1 2601-MSWLF-1980 AW-1s 5.25 212 21.0 29 0.15 -21.4 5.19 249 17.7 29 0.41 41.7 5.91 204 19.5 24 0.33 61.7 2601-MSWLF-1980 AW-1d 6.20 197 18.9 41 1.58 -12.1 6.31 189 18.4 82 2.52 76.4 6.46 197 18.4 59 0.96 89.8 2601-MSWLF-1980 AW-2 6.20 1,311 17.6 26 0.38 -20.1 6.32 1,339 17.1 38 0.58 -65.9 6.64 1,124 14.3 32 0.63 -33.4 2601-MSWLF-1980 AW-3 4.88 43 21.7 14 0.38 103.8 4.62 51 18.6 29 0.69 177.1 5.42 50 18.1 70 2.78 179.1 2601-MSWLF-1980 AW-4 5.39 311 23.6 6 0.78 -11.8 5.44 291 19.4 51 0.44 55.9 5.58 269 20.7 24 0.75 77.5 2601-MSWLF-1980 SW-3 6.46 944 20.4 62 3.82 -26.8 7.01 1,170 23.2 42 4.14 -15.8 6.61 1,239 12.7 128 5.76 114.7 2601-MSWLF-1980 SW-4 6.83 736 20.1 44 4.11 155.2 6.93 1,106 24.7 49 3.91 122.4 7.22 1,459 13.2 22 8.31 107.2 2601-MSWLF-1980 SW-5 6.94 1,155 23.9 55 4.08 17.1 7.14 1,715 23.2 72 3.61 85.5 6.61 2,535 13.9 37 5.08 122.6 2601-MSWLF-1980 SW-6 7.09 612 20.8 22 4.29 28.2 6.56 445 21.7 58 3.26 30.9 7.11 589 13.9 31 7.38 111.8 1. Replacement well MW-B installed 4/95.8. Cond. - Conductivity (µS/cm - Microsiemens per centimeter) 2. MW-H installed 12/94. AW-1s thru AW-4 installed March 1999.9. S.U. - Standard Units 3. SW-6 was first sampled in May 2010.10. Temp. - Temperature (deg. C - degrees Celsius) 4. Turbidity recorded at time of sampling. 5. ORP - Oxidation-Reduction Potential (mVs - millivolts) 6. DO - Dissolved Oxygen (mg/L - milligrams per liter) 7. Turb. - Turbidity (NTUs - Nephelometric Turbidity Units) 11/12-13/2013 No.41 6/5-6/2013 No.42 Monitoring Well Code No.40 9/26-27/2012 Event: Sampling Date: Facility Permit Number Notes: Surface Water Sample Location Page 2 of 5 June 2017 Table 4 Water Quality Parameters March 2017 Semi-Annual Sampling Event Cumberland County Closed Landfill Facility Permit Number 2601-MSWLF-1980 pH Cond.Temp.Turb.DO ORP pH Cond.Temp.Turb.DO ORP pH Cond.Temp.Turb.DO ORP (S.U.)(µS/cm)(deg. C)(NTUs)(mg/L)(mVs)(S.U.)(µS/cm)(deg. C)(NTUs)(mg/L)(mVs)(S.U.)(µS/cm)(deg. C)(NTUs)(mg/L)(mVs) 2601-MSWLF-1980 MW-A 6.27 275 19.8 22 0.62 29.2 6.32 294 19.5 17 0.34 -15.1 5.93 246 17.5 43 0.38 -85.6 2601-MSWLF-1980 MW-B 6.38 1,578 18.3 61 1.64 -58.3 6.47 1,958 19.2 79 0.33 -81.2 6.32 2,214 19.0 58 0.42 -138.7 2601-MSWLF-1980 MW-1A 6.22 1,450 15.5 15 1.47 -58.1 6.47 1,331 18.1 12 0.28 -68.9 5.93 1,217 17.5 16 1.34 -91.3 2601-MSWLF-1980 MW-H 6.23 2,291 15.9 10 1.90 -41.1 6.33 2,004 19.9 6 0.26 -90.1 6.05 1,911 17.8 14 0.33 -107.1 2601-MSWLF-1980 AW-1s 5.48 234 14.9 11 0.95 24.6 5.76 198 19.6 7 0.25 9.1 5.10 209 17.2 10 0.29 -38.8 2601-MSWLF-1980 AW-1d 6.42 184 17.3 8 4.59 22.1 6.39 184 18.7 35 2.22 76.1 6.12 163 18.1 45 3.04 20.9 2601-MSWLF-1980 AW-2 6.24 813 15.7 68 1.34 -51.9 6.52 769 17.6 52 0.58 -75.7 5.81 395 17.2 42 0.74 -116.9 2601-MSWLF-1980 AW-3 5.23 66 14.0 6 1.01 238.1 4.80 37 18.5 31 1.23 276.7 4.53 46 18.8 24 0.48 35.8 2601-MSWLF-1980 AW-4 5.40 270 16.9 11 1.12 37.6 5.67 257 21.7 47 0.26 -23.2 5.24 278 19.5 9 0.27 -72.4 Surface Water Sample Location 2601-MSWLF-1980 SW-3 6.73 747 20.2 55 6.64 -19.5 7.21 1,303 15.7 43 3.32 -1.4 6.84 1,003 20.1 62 4.89 -8.7 2601-MSWLF-1980 SW-4 7.38 681 24.1 44 6.41 18.7 7.69 1,995 17.8 28 8.63 49.2 7.39 1,205 29.1 26 6.93 30.2 2601-MSWLF-1980 SW-5 6.54 806 20.1 40 8.83 -68.7 6.71 1,749 16.0 51 1.63 -71.2 6.31 711 23.1 108 4.56 -73.4 2601-MSWLF-1980 SW-6 6.89 517 17.6 35 6.91 10.2 6.81 516 15.7 12 4.09 -1.1 6.77 475 21.0 41 4.72 2.7 1. Replacement well MW-B installed 4/95.8. Cond. - Conductivity (µS/cm - Microsiemens per centimeter) 2. MW-H installed 12/94. AW-1s thru AW-4 installed March 1999.9. S.U. - Standard Units 3. SW-6 was first sampled in May 2010.10. Temp. - Temperature (deg. C - degrees Celsius) 4. Turbidity recorded at time of sampling. 5. ORP - Oxidation-Reduction Potential (mVs - millivolts) 6. DO - Dissolved Oxygen (mg/L - milligrams per liter) 7. Turb. - Turbidity (NTUs - Nephelometric Turbidity Units) Notes: No.43 Sampling Date:4/22-23/2014 Facility Permit Number Monitoring Well Code Event:No.45 5/27-28/2015 No.44 11/5-6/2014 Page 3 of 5 June 2017 Table 4 Water Quality Parameters March 2017 Semi-Annual Sampling Event Cumberland County Closed Landfill Facility Permit Number 2601-MSWLF-1980 pH Cond.Temp.Turb.DO ORP pH Cond.Temp.Turb.DO ORP (S.U.)(µS/cm)(deg. C)(NTUs)(mg/L)(mVs)(S.U.)(µS/cm)(deg. C)(NTUs)(mg/L)(mVs) 2601-MSWLF-1980 MW-A 5.61 256 19.2 7 1.52 1.3 6.39 286 19.3 6 1.16 -88.6 2601-MSWLF-1980 MW-B 6.23 2,117 19.0 84 0.15 -67.4 6.43 2,698 19.6 37 0.37 -151.0 2601-MSWLF-1980 MW-1A 6.10 1,086 18.2 6 0.17 -55.2 6.34 1,436 16.2 95 0.51 -170.4 2601-MSWLF-1980 MW-H 5.94 1,896 20.7 4 0.10 -50.1 6.19 2,080 16.1 25 0.60 -143.2 2601-MSWLF-1980 AW-1s 5.25 211 19.0 1 0.14 23.9 5.90 271 15.0 36 0.31 -247.3 2601-MSWLF-1980 AW-1d 6.01 96 18.3 160 0.75 21.0 6.64 201 17.9 98 2.15 -97.6 2601-MSWLF-1980 AW-2 6.04 537 17.4 64 0.28 -40.7 6.27 404 16.8 79 0.54 -87.8 2601-MSWLF-1980 AW-3 4.50 39 18.2 47 2.76 37.0 4.99 72 14.5 27 1.00 -79.8 2601-MSWLF-1980 AW-4 5.50 294 20.8 16 0.35 -31.3 5.51 225 16.0 10 1.44 -166.5 Surface Water Sample Location 2601-MSWLF-1980 SW-3 6.58 588 14.5 24 6.93 31.2 6.96 1,352 19.1 142 7.52 -61.9 2601-MSWLF-1980 SW-4 7.04 636 18.5 77 5.61 19.6 6.70 1,543 18.2 76 6.77 -88.6 2601-MSWLF-1980 SW-5 6.53 780 16.0 65 2.80 -52.9 7.10 966 19.1 107 2.54 -136.3 2601-MSWLF-1980 SW-6 6.62 676 16.6 250 4.15 -20.4 7.13 1,093 21.9 124 4.01 -121.0 1. Replacement well MW-B installed 4/95.8. Cond. - Conductivity (µS/cm - Microsiemens per centimeter) 2. MW-H installed 12/94. AW-1s thru AW-4 installed March 1999.9. S.U. - Standard Units 3. SW-6 was first sampled in May 2010.10. Temp. - Temperature (deg. C - degrees Celsius) 4. Turbidity recorded at time of sampling.11. SW-4 was dry during the August 2016 sampling event. 5. ORP - Oxidation-Reduction Potential (mVs - millivolts)12. (--) - Not Sampled. 6. DO - Dissolved Oxygen (mg/L - milligrams per liter) 7. Turb. - Turbidity (NTUs - Nephelometric Turbidity Units) Notes: No.47 3/15-16/2016 No.46 11/10-12/2015 Event: Sampling Date: Facility Permit Number Monitoring Well Code Page 4 of 5 June 2017 Table 4 Water Quality Parameters March 2017 Semi-Annual Sampling Event Cumberland County Closed Landfill Facility Permit Number 2601-MSWLF-1980 pH Cond.Temp.Turb.DO ORP pH Cond.Temp.Turb.DO ORP (S.U.)(µS/cm)(deg. C)(NTUs)(mg/L)(mVs)(S.U.)(µS/cm)(deg. C)(NTUs)(mg/L)(mVs) 2601-MSWLF-1980 MW-A 6.14 257 21.1 23 3.53 -34.2 6.24 216 18.2 30 1.34 39.1 2601-MSWLF-1980 MW-B 6.4 2,360 21.4 48 0.83 -102.5 6.46 2,259 17.7 40 0.34 -78.4 2601-MSWLF-1980 MW-1A 6.14 1,047 19.4 5 0.90 -110.3 6.31 1,073 16.9 16 0.30 -88.6 2601-MSWLF-1980 MW-H 6.15 1,554 21.0 1 1.82 -83.5 6.22 1,459 16.7 1 0.34 -71.1 2601-MSWLF-1980 AW-1s 5.60 190 21.2 38 1.29 -6.8 5.67 279 16.3 10 0.26 35.5 2601-MSWLF-1980 AW-1d 6.08 170 19.9 49 2.57 6.2 6.51 169 17.8 53 2.05 21.3 2601-MSWLF-1980 AW-2 6.00 295 19.4 46 1.16 -17.0 6.11 250 16.9 46 0.14 9.2 2601-MSWLF-1980 AW-3 4.65 31 23.2 48 3.45 210.5 4.89 37 14.4 43 0.70 132.8 2601-MSWLF-1980 AW-4 5.47 347 24.2 22 3.51 -13.9 5.58 244 17.2 7 0.29 25.1 Surface Water Sample Location 2601-MSWLF-1980 SW-3 ------------------------ 2601-MSWLF-1980 SW-4 7.90 802 26.7 74 10.50 12.2 7.31 1,190 14.3 29 2.43 -123.1 2601-MSWLF-1980 SW-5 6.61 1,211 23.2 205 3.49 -83.5 6.41 648 14.3 23 2.61 -30.4 2601-MSWLF-1980 SW-6 6.76 1,281 23.7 251 1.84 -98.4 7.24 989 14.3 76 4.74 -14.2 1. Replacement well MW-B installed 4/95.8. Cond. - Conductivity (µS/cm - Microsiemens per centimeter) 2. MW-H installed 12/94. AW-1s thru AW-4 installed March 1999.9. S.U. - Standard Units 3. SW-6 was first sampled in May 2010.10. Temp. - Temperature (deg. C - degrees Celsius) 4. Turbidity recorded at time of sampling.11. SW-3 was dry during the August 2016 and March 2017 5. ORP - Oxidation-Reduction Potential (mVs - millivolts)sampling events. 6. DO - Dissolved Oxygen (mg/L - milligrams per liter)12. (--) - Not Sampled. 7. Turb. - Turbidity (NTUs - Nephelometric Turbidity Units) No.49 3/7-8/2017 Notes: Event: Sampling Date: Facility Permit Number Monitoring Well Code No.48 8/25-26/2016 Page 5 of 5 June 2017 Table 5ADetected Groundwater Constituents - MetalsMarch 2017 Semi-Annual Sampling EventCumberland County Closed LandfillFacility Permit Number 2601-MSWLF-1980Facility Permit NumberMonitoring Well CodeSample DateAntimonyArsenicBariumBerylliumCadmiumChromiumCobaltCopperLeadNickelSilverSeleniumThalliumVanadiumZinc0.001* 0.01 0.7 0.004* 0.002 0.01 0.001* 1 0.015 0.1 0.02 0.02 0.00028* 0.0003* 10.006 0.01 0.1 0.001 0.001 0.01 0.01 0.01 0.01 0.05 0.01 0.01 0.0055 0.025 0.012601-MSWLF-1980MW-1A28-Mar-110.00473J0.4080.000145J0.00256J0.00866J0.00202J0.00225J0.00335J0.03292601-MSWLF-1980MW-1A27-Sep-110.000242J0.01720.6500.00286J0.01010.00465J0.02582601-MSWLF-1980MW-1A6-Mar-120.00417J0.5400.00209J0.00980J0.00555J0.00748J2601-MSWLF-1980MW-1A26-Sep-120.02170.4190.000136J0.00209J0.00643J0.00353J0.00649J2601-MSWLF-1980MW-1A5-Jun-130.02770.5030.00765J0.00728J0.004332601-MSWLF-1980MW-1A12-Nov-130.02410.5190.00724J0.00212J0.00355J0.00903J2601-MSWLF-1980MW-1A22-Apr-140.03010.5560.00140J0.00907J0.00589J0.00730J2601-MSWLF-1980MW-1A27-May-150.000289J0.01920.4900.00619J0.00376J2601-MSWLF-1980MW-1A10-Nov-150.000750J0.02770.4320.00561J0.00402J0.00448J2601-MSWLF-1980MW-1A15-Mar-160.000369J0.01650.4780.00683J0.00614J2601-MSWLF-1980MW-1A25-Aug-160.04080.4390.00587J0.00315J2601-MSWLF-1980MW-1A7-Mar-170.02720.4650.00182J0.00560J0.00150J0.000730J0.00410J2601-MSWLF-1980MW-1A (dup)7-Mar-170.02240.4700.00175J0.00565J0.00233J0.000854J0.000482J0.00392J2601-MSWLF-1980MW-A29-Mar-110.3250.000186J0.00219J0.00210J0.00263J0.00180J0.00151J0.00653J2601-MSWLF-1980MW-A28-Sep-110.4330.000140J0.00105J0.00265J0.000770J0.00621J2601-MSWLF-1980MW-A7-Mar-120.5120.00202J0.00323J0.00220J2601-MSWLF-1980MW-A27-Sep-120.3620.00179J0.00312J0.00740J2601-MSWLF-1980MW-A6-Jun-130.4760.00719J0.00428J0.00246JB0.00485J2601-MSWLF-1980MW-A13-Nov-130.3950.00283J0.00192J0.03882601-MSWLF-1980MW-A23-Apr-140.5090.00254J0.00308J0.00264J0.00236J0.00636J2601-MSWLF-1980MW-A28-May-150.000720J0.4850.00377J0.00284J0.00598JB2601-MSWLF-1980MW-A12-Nov-150.000235J0.4430.00235J0.00333J0.00235J0.00472J2601-MSWLF-1980MW-A16-Mar-160.000334J0.4720.000106J0.00294J0.00264J2601-MSWLF-1980MW-A26-Aug-160.01110.5140.00286J0.00230J2601-MSWLF-1980MW-A8-Mar-170.4810.00314J0.00235J0.000508J0.00108J0.00850J2601-MSWLF-1980MW-H29-Mar-110.01400.8330.00160J0.00537J0.00367J0.00673J0.00342J0.00537J0.00266J0.00707J2601-MSWLF-1980MW-H28-Sep-110.01371.680.00297J0.00552J0.00799J0.00511J0.00529J2601-MSWLF-1980MW-H7-Mar-120.00456J1.390.00261J0.00855J0.00699J0.00615J0.00649J2601-MSWLF-1980MW-H (dup)7-Mar-120.00411J1.490.00276J0.00912J0.00218J0.00740J0.00599J0.00381J2601-MSWLF-1980MW-H27-Sep-120.06330.8860.01710.00546J0.00853J0.01852601-MSWLF-1980MW-H6-Jun-130.02201.070.00566J0.00623J0.00588J2601-MSWLF-1980MW-H13-Nov-130.03850.9270.00520J0.00567J0.00310J0.00481J2601-MSWLF-1980MW-H23-Apr-140.02071.360.00153J0.00443J0.00314J0.0113J0.00188J0.01872601-MSWLF-1980MW-H (dup)23-Apr-140.02531.380.00141J0.00440J0.00269J0.0118J0.00155J2601-MSWLF-1980MW-H28-May-150.04041.1110.00601J0.00926J0.00417J2601-MSWLF-1980MW-H12-Nov-150.02611.3400.00433J0.0110J0.00294J0.00184J0.00757J2601-MSWLF-1980MW-H16-Mar-160.000242J0.00853J1.1300.00511J0.0103J0.00548J2601-MSWLF-1980MW-H26-Aug-160.06250.8510.00563J0.00731J0.00317J2601-MSWLF-1980MW-H8-Mar-170.03850.9390.00602J0.00590J0.000269J0.00380J1.39DNorth Carolina 2L or Groundwater Protection StandardSolid Waste Section LimitPage 1 of 12June 2017 Table 5ADetected Groundwater Constituents - MetalsMarch 2017 Semi-Annual Sampling EventCumberland County Closed LandfillFacility Permit Number 2601-MSWLF-1980Facility Permit NumberMonitoring Well CodeSample DateAntimonyArsenicBariumBerylliumCadmiumChromiumCobaltCopperLeadNickelSilverSeleniumThalliumVanadiumZinc0.001* 0.01 0.7 0.004* 0.002 0.01 0.001* 1 0.015 0.1 0.02 0.02 0.00028* 0.0003* 10.006 0.01 0.1 0.001 0.001 0.01 0.01 0.01 0.01 0.05 0.01 0.01 0.0055 0.025 0.01North Carolina 2L or Groundwater Protection StandardSolid Waste Section Limit2601-MSWLF-1980MW-B29-Mar-110.01080.7940.00157J0.00465J0.00379J0.00478J0.00402J0.00438J0.00659J2601-MSWLF-1980MW-B28-Sep-110.01560.8440.00160J0.00419J0.00497J0.00473J0.00401J0.1632601-MSWLF-1980MW-B7-Mar-120.6000.00145J0.00614J0.00376J0.00610J0.1842601-MSWLF-1980MW-B27-Sep-120.02350.6970.00617J0.00435J0.00318J0.00641J0.00996J2601-MSWLF-1980MW-B6-Jun-130.000754J0.02010.6430.00396J0.00474J0.00504J2601-MSWLF-1980MW-B13-Nov-130.01730.7350.00550J0.00238J0.00504J0.00259J0.00323J0.01082601-MSWLF-1980MW-B23-Apr-140.00101J0.02970.9280.00396J0.00539J0.00482J2601-MSWLF-1980MW-B28-May-150.000323J0.03432.2800.000282J0.00274J0.00770J0.00839J0.000956J0.0140J0.015B2601-MSWLF-1980MW-B12-Nov-150.00167J0.03921.9800.000515J0.00456J0.00534J0.01460.00616J0.0112J0.00269J0.00160J0.0209J0.06372601-MSWLF-1980MW-B16-Mar-160.000425J0.02832.2700.00214J0.0129J0.00962J2601-MSWLF-1980MW-B26-Aug-160.000231J0.05702.3900.00258J0.00486J0.0139J0.0109J0.00875J2601-MSWLF-1980MW-B8-Mar-170.04142.330.00575J0.0113J0.000196J0.00860J0.00786J2601-MSWLF-1980AW-1s28-Mar-110.00142JB0.00488J0.0647J0.001090.00304J0.06710.00926J0.00208J0.0196J0.00227J0.0117J0.10202601-MSWLF-1980AW-1s27-Sep-110.000597J0.1110.000461J0.00129J0.04240.0102J0.00493J0.00587J2601-MSWLF-1980AW-1s6-Mar-120.000442J0.1080.000842J0.00127J0.03060.00404J0.00847J0.00285J0.04962601-MSWLF-1980AW-1s26-Sep-120.1180.000715J0.00292J0.01640.01470.00229J0.00678J0.0175J0.02752601-MSWLF-1980AW-1s5-Jun-130.000361J0.1030.000322J0.02890.00793J0.00608J0.00541J2601-MSWLF-1980AW-1s12-Nov-130.1110.000319J0.01710.00176J0.00476J0.00877J0.01222601-MSWLF-1980AW-1s22-Apr-140.1060.000524J0.02950.00253J0.00239J0.00510J0.00436J0.00581J2601-MSWLF-1980AW-1s27-May-150.0993J0.000238J0.01510.00253J0.00320J0.0226B2601-MSWLF-1980AW-1s10-Nov-150.1310.000314J0.01470.00296J0.00405J0.00948J2601-MSWLF-1980AW-1s15-Mar-160.000574J0.0845J0.000154J0.01910.01390.00281J0.00583J0.1152601-MSWLF-1980AW-1s25-Aug-160.000656J0.0949J0.000233J0.00606J0.00624J0.00843J0.03742601-MSWLF-1980AW-1s7-Mar-170.1310.000253J0.01940.00666J0.00362J0.000426J0.00439J0.01972601-MSWLF-1980AW-1d28-Mar-110.00393J0.3320.00231J0.00184J2601-MSWLF-1980AW-1d27-Sep-110.3912601-MSWLF-1980AW-1d6-Mar-120.4160.00179J2601-MSWLF-1980AW-1d26-Sep-120.00299J0.4050.000281J0.00303J0.00255J0.00436J2601-MSWLF-1980AW-1d5-Jun-130.00562J0.4120.000503J0.00706J0.00447J0.000307J0.00188J0.00215JB0.00112J0.00909J0.01012601-MSWLF-1980AW-1d12-Nov-130.00540J0.4400.000234J0.00351J0.00303J0.00405J0.01132601-MSWLF-1980AW-1d22-Apr-140.3600.00260J2601-MSWLF-1980AW-1d 27-May-150.3340.00313J0.0119B2601-MSWLF-1980AW-1d (dup)27-May-150.3410.000110J0.00346J0.00965JB2601-MSWLF-1980AW-1d10-Nov-150.00817J0.3980.000182J0.00229J0.00388J0.00489J2601-MSWLF-1980AW-1d15-Mar-160.3990.000269J0.00301J0.00463J0.00476J2601-MSWLF-1980AW-1d25-Aug-160.4170.00221J0.00160J0.00440J2601-MSWLF-1980AW-1d7-Mar-170.4180.000144J0.00135J0.00120J0.000405J0.00171J0.00636JPage 2 of 12June 2017 Table 5ADetected Groundwater Constituents - MetalsMarch 2017 Semi-Annual Sampling EventCumberland County Closed LandfillFacility Permit Number 2601-MSWLF-1980Facility Permit NumberMonitoring Well CodeSample DateAntimonyArsenicBariumBerylliumCadmiumChromiumCobaltCopperLeadNickelSilverSeleniumThalliumVanadiumZinc0.001* 0.01 0.7 0.004* 0.002 0.01 0.001* 1 0.015 0.1 0.02 0.02 0.00028* 0.0003* 10.006 0.01 0.1 0.001 0.001 0.01 0.01 0.01 0.01 0.05 0.01 0.01 0.0055 0.025 0.01North Carolina 2L or Groundwater Protection StandardSolid Waste Section Limit2601-MSWLF-1980AW-229-Mar-110.3320.00191J0.04430.00233J0.00228J0.00331J0.00221J0.02442601-MSWLF-1980AW-228-Sep-110.3760.00207J0.05110.00577J0.00272J0.00370J0.00887J2601-MSWLF-1980AW-27-Mar-120.4980.00257J0.05940.00403J0.00334J0.00479J0.02422601-MSWLF-1980AW-227-Sep-120.00611J0.5500.00161J0.05310.00516J0.004J0.00605J0.00977J2601-MSWLF-1980AW-26-Jun-130.5530.07050.00607J0.0056J0.00742J2601-MSWLF-1980AW-2 (dup)6-Jun-130.5390.07030.00616J0.00498J0.00779J2601-MSWLF-1980AW-213-Nov-130.4400.05060.00328J0.00452J0.00326J0.00151J0.00779J2601-MSWLF-1980AW-2 (dup)13-Nov-130.4610.000116J0.05130.00519J0.00493J0.00521J0.00324J0.00673J0.00974J2601-MSWLF-1980AW-2 23-Apr-140.3480.04130.00354J0.00390J0.00665J2601-MSWLF-1980AW-228-May-150.2310.02460.00329J0.00254J0.00431JB2601-MSWLF-1980AW-212-Nov-150.2790.02980.00373J0.00190J0.00201J0.00670J2601-MSWLF-1980AW-216-Mar-160.1450.07090.00259J0.00185J2601-MSWLF-1980AW-226-Aug-160.1690.04810.00448J0.00297J0.00309J0.00462J2601-MSWLF-1980AW-28-Mar-170.00876J0.1590.04380.00319J0.000487J0.00291J2601-MSWLF-1980AW-328-Mar-110.00495J0.0851J0.000643J0.00156J0.00282J0.00355J0.00267J0.00320J0.00413J2601-MSWLF-1980AW-327-Sep-110.0889J0.000606J0.00112J0.00194J0.00342J0.00210J0.00174J2601-MSWLF-1980AW-3 (dup)27-Sep-110.0900J0.000619J0.00106J0.00159J0.00319J0.00214J0.00161J2601-MSWLF-1980AW-3 6-Mar-120.0939J0.000531J0.00235J0.00296J0.00340J2601-MSWLF-1980AW-3 26-Sep-120.00397J0.0576J0.000275J0.00273J0.00238J0.00241J0.00270J0.00558J2601-MSWLF-1980AW-3 (dup)26-Sep-120.00415J0.0607J0.000242J0.00392J0.00244J0.00311J0.00269J0.00682J0.00460J2601-MSWLF-1980AW-3 5-Jun-130.0698J0.000338J0.00147J0.00224J0.00228J0.00278JB0.00278J2601-MSWLF-1980AW-3 12-Nov-130.0807J0.000357J0.00183J0.00419J2601-MSWLF-1980AW-3 22-Apr-140.0862J0.000650J0.00226J0.00320J2601-MSWLF-1980AW-327-May-150.0648J0.000412J0.00160J0.00336J2601-MSWLF-1980AW-310-Nov-150.0643J0.000478J0.00119J0.00295J2601-MSWLF-1980AW-315-Mar-160.0964J0.000573J0.00230J0.00146J2601-MSWLF-1980AW-325-Aug-160.00834J0.0472J0.000322J0.00178J0.00142J0.00439J0.00361J0.00462J2601-MSWLF-1980AW-3 (dup)25-Aug-160.0481J0.000222J0.00313J0.00183J0.00459J0.00325J0.00586J0.00483J2601-MSWLF-1980AW-37-Mar-170.0716J0.000552J0.00285J0.00164J0.00211J0.00369J0.000149J0.00440JPage 3 of 12June 2017 Table 5ADetected Groundwater Constituents - MetalsMarch 2017 Semi-Annual Sampling EventCumberland County Closed LandfillFacility Permit Number 2601-MSWLF-1980Facility Permit NumberMonitoring Well CodeSample DateAntimonyArsenicBariumBerylliumCadmiumChromiumCobaltCopperLeadNickelSilverSeleniumThalliumVanadiumZinc0.001* 0.01 0.7 0.004* 0.002 0.01 0.001* 1 0.015 0.1 0.02 0.02 0.00028* 0.0003* 10.006 0.01 0.1 0.001 0.001 0.01 0.01 0.01 0.01 0.05 0.01 0.01 0.0055 0.025 0.01North Carolina 2L or Groundwater Protection StandardSolid Waste Section Limit2601-MSWLF-1980AW-428-Mar-110.00823J0.1590.000705J0.00241J0.00855J0.0105J0.00225J0.0133J2601-MSWLF-1980AW-4 (dup)28-Mar-110.00569J0.1580.000655J0.00214J0.00862J0.0102J0.00298J0.0130J2601-MSWLF-1980AW-427-Sep-110.00295J0.2310.000581J0.00181J0.00863J0.0117J0.00158J0.00474J0.00590J2601-MSWLF-1980AW-46-Mar-120.2540.000447J0.00198J0.00715J0.00200J0.0103J0.000978J0.00829J2601-MSWLF-1980AW-426-Sep-120.00618J0.2560.000550J0.00164J0.00756J0.0101J0.00679J2601-MSWLF-1980AW-45-Jun-130.2120.000493J0.00759J0.00967J0.00222JB0.00481J2601-MSWLF-1980AW-412-Nov-130.1910.000720J0.00146J0.00663J0.00654J0.00401J0.01702601-MSWLF-1980AW-422-Apr-140.00551J0.1640.000464J0.00953J0.00241J0.0104J0.00331J0.00387J2601-MSWLF-1980AW-427-May-150.1820.000744J0.00820J0.00753J0.00255J2601-MSWLF-1980AW-412-Nov-150.1570.000561J0.00867J0.00916J0.00382J2601-MSWLF-1980AW-4 (dup)12-Nov-150.1560.000583J0.00931J0.00979J0.00400J0.00544J2601-MSWLF-1980AW-416-Mar-160.1100.000764J0.00840J0.00768J0.00260J2601-MSWLF-1980AW-4 (dup)16-Mar-160.1150.000827J0.00847J0.00762J0.00375J2601-MSWLF-1980AW-425-Aug-160.1700.000435J0.00933J0.00207J0.0102J0.00361J2601-MSWLF-1980AW-47-Mar-170.1220.000586J0.00129J0.00876J0.00851J0.000465J0.00394JNotes:1. All units are in milligrams per liter (parts per million). 2. * - Groundwater Protection Standard6. D - Indicates that the sample was analyzed at dilution. - Indicates the result is below the detection limit.5. B - Indicates the amount detected in the method blank was greater than the method detection limit. 4. J - Indicates the analytical result is an estimated concentration between the method detection limit and the Solid Waste Section Reporting Limit.- Concentration exceeds the 15A NCAC 02L.0202 (North Carolina 2L) or Groundwater Protection Standard.3. (dup) - Duplicate SamplePage 4 of 12June 2017 Table 5B Detected Groundwater Constituents - Volatile Organic Compounds March 2017 Semi-Annual Sampling Event Cumberland County Closed Landfill Facility Permit Number 2601-MSWLF-1980 Facility Permit NumberMonitoring Well CodeSample DateAcetoneBenzene2-ButanoneChlorobenzeneChloroethane1,2-Dichlorobenzene1,4-Dichlorobenzene1,1-Dichloroethanecis 1,2-Dichloroethene2-HexanoneTolueneVinyl ChlorideTotal Xylenes6,000 1 4,000 50 3,000 20 6 6 70 40* 600 0.03 500 100 1 100 3 10 5 1 5 5 50 1 1 5 2601-MSWLF-1980 MW-1A 28-Mar-11 12J 2601-MSWLF-1980 MW-1A 27-Sep-11 8.4J 2601-MSWLF-1980 MW-1A 6-Mar-12 16J 2601-MSWLF-1980 MW-1A 26-Sep-12 2601-MSWLF-1980 MW-1A 5-Jun-13 2601-MSWLF-1980 MW-1A 12-Nov-13 2601-MSWLF-1980 MW-1A 22-Apr-14 2601-MSWLF-1980 MW-1A 27-May-15 2601-MSWLF-1980 MW-1A 10-Nov-15 2601-MSWLF-1980 MW-1A 15-Mar-16 2601-MSWLF-1980 MW-1A 25-Aug-16 2601-MSWLF-1980 MW-1A 7-Mar-17 2601-MSWLF-1980 MW-1A (dup)7-Mar-17 2601-MSWLF-1980 MW-A 29-Mar-11 2601-MSWLF-1980 MW-A 28-Sep-11 2601-MSWLF-1980 MW-A 7-Mar-12 2601-MSWLF-1980 MW-A 27-Sep-12 2601-MSWLF-1980 MW-A 6-Jun-13 2601-MSWLF-1980 MW-A 13-Nov-13 2601-MSWLF-1980 MW-A 23-Apr-14 2601-MSWLF-1980 MW-A 28-May-15 2601-MSWLF-1980 MW-A 12-Nov-15 2601-MSWLF-1980 MW-A 16-Mar-16 2601-MSWLF-1980 MW-A 26-Aug-16 2601-MSWLF-1980 MW-A 8-Mar-17 2601-MSWLF-1980 MW-H 29-Mar-11 2.60 7.2 0.41J 5.70 1.2J 2601-MSWLF-1980 MW-H 28-Sep-11 5.8J 3.50 11 0.58J 8.80 0.63J 1.1J 2601-MSWLF-1980 MW-H 7-Mar-12 3.0 8.6 0.43J 7.0 0.58J 1.1J 2601-MSWLF-1980 MW-H (dup)7-Mar-12 5.9J 3.2 9.9 0.63J 7.4 0.51J 1.1J 2601-MSWLF-1980 MW-H 27-Sep-12 21J 3.1 9.6J 9.7 0.47J 7.2 0.42J 0.44J 0.96J 2601-MSWLF-1980 MW-H 6-Jun-13 2.4 6.8 4.8 0.69J 0.53J 0.83J 2601-MSWLF-1980 MW-H 13-Nov-13 2.9 9.1 0.77J 7.7 0.72J 0.76J 2601-MSWLF-1980 MW-H 23-Apr-14 7.3J 2.8 11.0 0.51J 8.5 2601-MSWLF-1980 MW-H (dup)23-Apr-14 6.7J 2.9 11.0 0.52J 8.4 0.52J 2601-MSWLF-1980 MW-H 28-May-15 3.0 9.3 0.48J 6.4 0.61J 0.80J 2601-MSWLF-1980 MW-H 12-Nov-15 18J 2.9 8.6 0.50J 6.3 0.45J 0.42J 2601-MSWLF-1980 MW-H 16-Mar-16 7.7J 3.3 9.7 0.48J 7.2 0.42J 0.44J 0.99J 2601-MSWLF-1980 MW-H 26-Aug-16 3.0 9.4 0.59J 7.8 0.52J 0.51J 2601-MSWLF-1980 MW-H 8-Mar-17 3.3 9.8 0.45J 8.2 0.54J 2601-MSWLF-1980 MW-B 29-Mar-11 2.7J 2.5 0.64J 2.4J 2601-MSWLF-1980 MW-B 28-Sep-11 2.6J 2.7 0.58J 1.3J 2601-MSWLF-1980 MW-B 7-Mar-12 5.2J 1.4J 2.1 0.50J 0.66J 2601-MSWLF-1980 MW-B 27-Sep-12 2.1J 2.3 0.49J 0.89J 2601-MSWLF-1980 MW-B 6-Jun-13 4.2J 2J 1.6 2601-MSWLF-1980 MW-B 13-Nov-13 1.9J 0.62J 2.0 0.43J 0.54J 2601-MSWLF-1980 MW-B 23-Apr-14 3.8 1.5J 2.4 2601-MSWLF-1980 MW-B 28-May-15 0.60J 5.1 2.6 0.52J 1.6J 2601-MSWLF-1980 MW-B 12-Nov-15 1.1 5.2 1.4J 3.3 0.51J 2601-MSWLF-1980 MW-B 16-Mar-16 1.1 5.3 3.2 0.44J 0.46J 2601-MSWLF-1980 MW-B 26-Aug-16 1.0 5.8 0.79J 4.6 0.47J 2.8J 2601-MSWLF-1980 MW-B 8-Mar-17 1.0 5.6 3.6 0.50J 4.7J North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit Page 5 of 12 June 2017 Table 5B Detected Groundwater Constituents - Volatile Organic Compounds March 2017 Semi-Annual Sampling Event Cumberland County Closed Landfill Facility Permit Number 2601-MSWLF-1980 Facility Permit NumberMonitoring Well CodeSample DateAcetoneBenzene2-ButanoneChlorobenzeneChloroethane1,2-Dichlorobenzene1,4-Dichlorobenzene1,1-Dichloroethanecis 1,2-Dichloroethene2-HexanoneTolueneVinyl ChlorideTotal Xylenes6,000 1 4,000 50 3,000 20 6 6 70 40* 600 0.03 500 100 1 100 3 10 5 1 5 5 50 1 1 5 North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit 2601-MSWLF-1980 AW-1s 28-Mar-11 2601-MSWLF-1980 AW-1s 27-Sep-11 23J 2601-MSWLF-1980 AW-1s 6-Mar-12 2601-MSWLF-1980 AW-1s 26-Sep-12 2601-MSWLF-1980 AW-1s 5-Jun-13 2601-MSWLF-1980 AW-1s 12-Nov-13 2601-MSWLF-1980 AW-1s 22-Apr-14 99J 2601-MSWLF-1980 AW-1s 27-May-15 2601-MSWLF-1980 AW-1s 10-Nov-15 2601-MSWLF-1980 AW-1s 15-Mar-16 90J 0.54J 2601-MSWLF-1980 AW-1s 25-Aug-16 2601-MSWLF-1980 AW-1s 7-Mar-17 2601-MSWLF-1980 AW-1d 28-Mar-11 2601-MSWLF-1980 AW-1d 27-Sep-11 2601-MSWLF-1980 AW-1d 6-Mar-12 2601-MSWLF-1980 AW-1d 26-Sep-12 2601-MSWLF-1980 AW-1d 5-Jun-13 2601-MSWLF-1980 AW-1d 12-Nov-13 2601-MSWLF-1980 AW-1d 22-Apr-14 2601-MSWLF-1980 AW-1d 27-May-15 2601-MSWLF-1980 AW-1d (dup)27-May-15 2601-MSWLF-1980 AW-1d 10-Nov-15 2601-MSWLF-1980 AW-1d 15-Mar-16 2601-MSWLF-1980 AW-1d 25-Aug-16 2601-MSWLF-1980 AW-1d 7-Mar-17 2601-MSWLF-1980 AW-2 29-Mar-11 2601-MSWLF-1980 AW-2 28-Sep-11 2601-MSWLF-1980 AW-2 7-Mar-12 0.94J 0.45J 0.75J 1.3J 0.85J 2601-MSWLF-1980 AW-2 (confirmatory sample)27-Mar-12 0.95J 0.43J 0.60J 1.1J 0.74J 2601-MSWLF-1980 AW-2 27-Sep-12 6.3J 1.4 0.67J 0.42J 0.81J 1.6J 0.98J 2601-MSWLF-1980 AW-2 6-Jun-13 1 0.53J 0.41J 0.74J 2601-MSWLF-1980 AW-2 (dup)6-Jun-13 1 0.54J 0.42J 0.66J 2601-MSWLF-1980 AW-2 1-Aug-13 0.93J 0.47J 0.46J 2601-MSWLF-1980 AW-2 13-Nov-13 0.89J 0.45J 0.44J 0.79J 0.45J 2601-MSWLF-1980 AW-2 (dup)13-Nov-13 0.82J 0.44J 0.41J 0.79J 2601-MSWLF-1980 AW-2 23-Apr-14 0.50J 2601-MSWLF-1980 AW-2 28-May-15 2601-MSWLF-1980 AW-2 12-Nov-15 2601-MSWLF-1980 AW-2 16-Mar-16 2601-MSWLF-1980 AW-2 26-Aug-16 2601-MSWLF-1980 AW-2 8-Mar-17 2601-MSWLF-1980 AW-3 28-Mar-11 2601-MSWLF-1980 AW-3 27-Sep-11 2601-MSWLF-1980 AW-3 (dup)27-Sep-11 2601-MSWLF-1980 AW-3 6-Mar-12 2601-MSWLF-1980 AW-3 26-Sep-12 2601-MSWLF-1980 AW-3 (dup)26-Sep-12 2601-MSWLF-1980 AW-3 5-Jun-13 2601-MSWLF-1980 AW-3 12-Nov-13 2601-MSWLF-1980 AW-3 22-Apr-14 2601-MSWLF-1980 AW-3 27-May-15 2601-MSWLF-1980 AW-3 10-Nov-15 2601-MSWLF-1980 AW-3 15-Mar-16 2601-MSWLF-1980 AW-3 25-Aug-16 2601-MSWLF-1980 AW-3 (dup)25-Aug-16 2601-MSWLF-1980 AW-3 7-Mar-17 Page 6 of 12 June 2017 Table 5B Detected Groundwater Constituents - Volatile Organic Compounds March 2017 Semi-Annual Sampling Event Cumberland County Closed Landfill Facility Permit Number 2601-MSWLF-1980 Facility Permit NumberMonitoring Well CodeSample DateAcetoneBenzene2-ButanoneChlorobenzeneChloroethane1,2-Dichlorobenzene1,4-Dichlorobenzene1,1-Dichloroethanecis 1,2-Dichloroethene2-HexanoneTolueneVinyl ChlorideTotal Xylenes6,000 1 4,000 50 3,000 20 6 6 70 40* 600 0.03 500 100 1 100 3 10 5 1 5 5 50 1 1 5 North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit 2601-MSWLF-1980 AW-4 28-Mar-11 2601-MSWLF-1980 AW-4 (dup)28-Mar-11 2601-MSWLF-1980 AW-4 27-Sep-11 2601-MSWLF-1980 AW-4 6-Mar-12 2601-MSWLF-1980 AW-4 26-Sep-12 2601-MSWLF-1980 AW-4 5-Jun-13 2601-MSWLF-1980 AW-4 12-Nov-13 2601-MSWLF-1980 AW-4 22-Apr-14 2601-MSWLF-1980 AW-4 27-May-15 2601-MSWLF-1980 AW-4 12-Nov-15 2601-MSWLF-1980 AW-4 (dup)12-Nov-15 2601-MSWLF-1980 AW-4 16-Mar-16 2601-MSWLF-1980 AW-4 (dup)16-Mar-16 2601-MSWLF-1980 AW-4 25-Aug-16 2601-MSWLF-1980 AW-4 7-Mar-17 Notes: 1. All units are in micrograms per liter (parts per billion). 2. * - Groundwater Protection Standard - Indicates the result is below the detection limit. - Concentration exceeds the 15A NCAC 02L.0202 (North Carolina 2L) or Groundwater Protection Standard. 3. (dup) - Duplicate Sample 4. J - Indicates the analytical result is an estimated concentration between the method detection limit and the Solid Waste Section Reporting Limit. 5. B - Indicates the amount detected in the method blank was greater than the method detection limit. Page 7 of 12 June 2017 Table 5CDetected Surface Water Constituents - MetalsMarch 2017 Semi-Annual Sampling EventCumberland County Closed LandfillFacility Permit Number 2601-MSWLF-1980Facility Permit NumberSurface Water Sample LocationSample DateAntimonyArsenicBariumBerylliumCadmiumChromiumCobaltCopperLeadNickelSeleniumSilverThalliumVanadiumZinc0.64* 0.01* 200* 0.0065 0.00015 0.024 0.004* 0.0027 0.00054 0.016 0.005 0.00006 0.00047* NS 0.0360.006 0.01 0.1 0.001 0.001 0.01 0.01 0.01 0.01 0.05 0.01 0.01 0.0055 0.025 0.012601-MSWLF-1980SW-328-Mar-110.2760.00249J0.00400J0.00624J0.00332J0.0122601-MSWLF-1980SW-327-Sep-110.00381J0.2160.00066J0.00935J0.00407J0.0110.01190.00655J0.00104J0.0218J0.06152601-MSWLF-1980SW-36-Mar-120.000472J0.2000.000102J0.00276J0.00329J0.00389J0.00570J0.000912J0.00406J0.0162601-MSWLF-1980SW-326-Sep-120.000419J0.3060.00127J0.00524J0.00297J0.00473J2601-MSWLF-1980SW-35-Jun-130.4780.00592J0.00336J0.00314JB0.00148J0.01022601-MSWLF-1980SW-312-Nov-130.00745J0.3960.000237J0.00900J0.01180.00444J0.00410J0.00719J0.00217J0.0134J0.05142601-MSWLF-1980SW-322-Apr-140.01250.3630.000238J0.00500J0.00578J0.00470JB0.00798J0.00661J0.00854J0.03582601-MSWLF-1980SW-327-May-150.000371J0.8040.000251J0.00177J0.00689J0.00279J0.00614J0.00124J0.00335J0.03352601-MSWLF-1980SW-312-Nov-150.000244J0.3580.000914J0.01120.01350.01050.01340.00929J0.02260.09832601-MSWLF-1980SW-316-Mar-160.000693J0.3670.00277J0.00574J0.00672J0.00248J0.00521J2601-MSWLF-1980SW-326-Aug-162601-MSWLF-1980SW-38-Mar-172601-MSWLF-1980SW-428-Mar-110.000365JB0.01020.2730.00397J0.00430J0.00171J0.00980J0.00353J0.00409J0.00494J2601-MSWLF-1980SW-427-Sep-110.1080.000247J0.00370J0.00193J0.00626J0.00660J0.00492J0.00110J0.00850J0.0251J2601-MSWLF-1980SW-46-Mar-120.00145J0.1810.000270J0.00444J0.00370J0.00592J0.00393J0.00672J0.00118J0.00860J0.01592601-MSWLF-1980SW-426-Sep-120.00114J0.2000.00277J0.00192J0.00582J0.00118J0.00350J0.00395J2601-MSWLF-1980SW-45-Jun-130.00802J0.3050.00587J0.00335J0.00376J0.0101J0.00107J0.00271JB0.011J0.01632601-MSWLF-1980SW-412-Nov-130.2940.00984J0.00477J0.0101J0.00624J0.01322601-MSWLF-1980SW-422-Apr-140.00680J0.2080.00455J0.00250J0.00450JB0.00584J0.00722J0.00626J0.00976J2601-MSWLF-1980SW-427-May-150.000317J0.3740.00388J0.00371J0.00747J0.00480J2601-MSWLF-1980SW-412-Nov-150.000258J0.1640.000194J0.00394J0.00329J0.00298J0.00796J0.00678J0.00570J0.01502601-MSWLF-1980SW-415-Mar-160.000581J0.3260.00397J0.00522J0.00733J0.00205J2601-MSWLF-1980SW-426-Aug-160.000254J0.0662J0.00311J0.00301J0.00315J0.00969J0.00337J0.00567J2601-MSWLF-1980SW-48-Mar-170.000577J0.00874J0.4060.00445J0.00486J0.00831J0.000971J0.000251J0.000675J2601-MSWLF-1980SW-529-Mar-110.00299J0.4570.00218J0.00384J0.0144J0.00320J0.00596J2601-MSWLF-1980SW-528-Sep-110.00291J0.6340.00425J0.00670J0.00447J0.0251J0.00389J0.00147J0.01672601-MSWLF-1980SW-57-Mar-120.000313J0.3440.00207J0.00426J0.0109J0.00602J2601-MSWLF-1980SW-527-Sep-120.000282J0.2390.00193J0.00337J0.0102J0.00143J0.00185J2601-MSWLF-1980SW-55-Jun-130.7050.00393J0.0048J0.0202J0.00211JB0.00147J0.00487J2601-MSWLF-1980SW-512-Nov-130.8180.00822J0.01030.0376J0.00676J2601-MSWLF-1980SW-522-Apr-140.2140.00290J0.00279J0.00560J2601-MSWLF-1980SW-527-May-150.310.00207J0.00485J2601-MSWLF-1980SW-512-Nov-150.2580.00421J0.00521J0.00678J0.00186J2601-MSWLF-1980SW-516-Mar-160.000345J0.2170.00396J0.00863J0.00148J2601-MSWLF-1980SW-526-Aug-160.5420.00415J0.00497J0.00174J0.0104J0.00394J0.01372601-MSWLF-1980SW-58-Mar-170.00905J0.3330.00174J0.00186J0.00142J0.000460J0.00220JNorth Carolina 2B Freshwater Aquatic Life or Human Health StandardSolid Waste Section LimitdrydryPage 8 of 12June 2017 Table 5CDetected Surface Water Constituents - MetalsMarch 2017 Semi-Annual Sampling EventCumberland County Closed LandfillFacility Permit Number 2601-MSWLF-1980Facility Permit NumberSurface Water Sample LocationSample DateAntimonyArsenicBariumBerylliumCadmiumChromiumCobaltCopperLeadNickelSeleniumSilverThalliumVanadiumZinc0.64* 0.01* 200* 0.0065 0.00015 0.024 0.004* 0.0027 0.00054 0.016 0.005 0.00006 0.00047* NS 0.0360.006 0.01 0.1 0.001 0.001 0.01 0.01 0.01 0.01 0.05 0.01 0.01 0.0055 0.025 0.01North Carolina 2B Freshwater Aquatic Life or Human Health StandardSolid Waste Section Limit2601-MSWLF-1980SW-617-May-100.2740.00336J0.00270J0.000871J0.00392J2601-MSWLF-1980SW-67-Oct-100.2070.00303J0.00270J0.0010J0.00513J2601-MSWLF-1980SW-629-Mar-110.2260.00239J0.00592J0.00177J2601-MSWLF-1980SW-628-Sep-110.1670.00217J0.00407J0.00122J0.00466J2601-MSWLF-1980SW-67-Mar-120.1710.00158J0.00480J0.00401J2601-MSWLF-1980SW-627-Sep-120.4110.000108J0.00160J0.01350.00575J0.00295J0.03852601-MSWLF-1980SW-65-Jun-130.2510.00405J0.00357J0.00284JB2601-MSWLF-1980SW-612-Nov-130.3260.01300.00459J0.00173J0.01032601-MSWLF-1980SW-622-Apr-140.2990.00378J0.00215JB0.00288J0.00562J2601-MSWLF-1980SW-627-May-150.3360.00551J0.00638J2601-MSWLF-1980SW-612-Nov-150.2330.000120J0.00349J0.00680J0.00153J0.00602J2601-MSWLF-1980SW-616-Mar-160.000324J0.2640.00179J0.00502J0.0120J2601-MSWLF-1980SW-626-Aug-160.000700J0.5460.00345J0.00581J0.00162J0.0114J0.00308J0.02112601-MSWLF-1980SW-68-Mar-170.5550.00312J0.00430J0.0118J0.000299J0.00112JNotes:1. All units for are in milligrams per liter (parts per million).2. NS - No Standard3. Standards obtained from 15A NCAC 02B (North Carolina 2B) Surface Water Standards for Class C Waters or are National Criteria per the U.S. Environmental Protection Agency (June 2016).4. * - Human Health Standard- Concentration exceeds the North Carolina 2B Freshwater Aquatic Life or Human Health Standard.- Indicates the result is below the detection limit6. B - Indicates the amount detected in the method blank was greater than the method detection limit. 5. J - Indicates the analytical result is an estimated concentration between the method detection limit and the Solid Waste Section Reporting Limit. Page 9 of 12June 2017 Table 5D Detected Surface Water Constituents - Volatile Organic Compounds March 2017 Semi-Annual Sampling Event Cumberland County Closed Landfill Facility Permit Number 2601-MSWLF-1980 Facility Permit NumberSurface Water Sample LocationSample DateAcetoneBenzeneCarbon DisulfideChlorobenzene1,4-DichlorobenzeneToluene2,000 51* 20,000** 140 100 11 100 1 100 3 1 1 2601-MSWLF-1980 SW-3 28-Mar-11 20J 2601-MSWLF-1980 SW-3 27-Sep-11 13J 2601-MSWLF-1980 SW-3 6-Mar-12 14J 2601-MSWLF-1980 SW-3 26-Sep-12 11J 2601-MSWLF-1980 SW-3 5-Jun-13 14J 0.43J 2601-MSWLF-1980 SW-3 12-Nov-13 2601-MSWLF-1980 SW-3 22-Apr-14 20J 2601-MSWLF-1980 SW-3 27-May-15 6.8J 2601-MSWLF-1980 SW-3 12-Nov-15 6.3J 2601-MSWLF-1980 SW-3 16-Mar-16 4.3J 2601-MSWLF-1980 SW-3 26-Aug-16 2601-MSWLF-1980 SW-3 8-Mar-17 2601-MSWLF-1980 SW-4 28-Mar-11 7.9J 2601-MSWLF-1980 SW-4 27-Sep-11 12J 2601-MSWLF-1980 SW-4 6-Mar-12 13J 2601-MSWLF-1980 SW-4 26-Sep-12 4.1J 2601-MSWLF-1980 SW-4 5-Jun-13 12J 2601-MSWLF-1980 SW-4 12-Nov-13 2601-MSWLF-1980 SW-4 22-Apr-14 29J 2601-MSWLF-1980 SW-4 27-May-15 2601-MSWLF-1980 SW-4 12-Nov-15 9.1J 2601-MSWLF-1980 SW-4 15-Mar-16 3.0J 0.54J 2601-MSWLF-1980 SW-4 26-Aug-16 2601-MSWLF-1980 SW-4 8-Mar-17 12J 2601-MSWLF-1980 SW-5 29-Mar-11 8.8J 1.3J 2601-MSWLF-1980 SW-5 28-Sep-11 7.1J 2601-MSWLF-1980 SW-5 7-Mar-12 14J 2601-MSWLF-1980 SW-5 27-Sep-12 15J 2601-MSWLF-1980 SW-5 5-Jun-13 13J 0.54J 2601-MSWLF-1980 SW-5 12-Nov-13 6.0J 0.53J 2601-MSWLF-1980 SW-5 22-Apr-14 10J 0.77J 2601-MSWLF-1980 SW-5 27-May-15 0.42J 2601-MSWLF-1980 SW-5 12-Nov-15 11J 2601-MSWLF-1980 SW-5 16-Mar-16 3.4J 0.66J 0.89J 2601-MSWLF-1980 SW-5 26-Aug-16 2.0J 0.77J 2601-MSWLF-1980 SW-5 8-Mar-17 14 1.9 2601-MSWLF-1980 SW-6 17-May-10 2601-MSWLF-1980 SW-6 7-Oct-10 2601-MSWLF-1980 SW-6 29-Mar-11 2601-MSWLF-1980 SW-6 28-Sep-11 2601-MSWLF-1980 SW-6 7-Mar-12 4.4J 2601-MSWLF-1980 SW-6 27-Sep-12 3.5J 2601-MSWLF-1980 SW-6 5-Jun-13 2601-MSWLF-1980 SW-6 12-Nov-13 2601-MSWLF-1980 SW-6 22-Apr-14 2601-MSWLF-1980 SW-6 27-May-15 2601-MSWLF-1980 SW-6 12-Nov-15 11J 0.45J 2601-MSWLF-1980 SW-6 16-Mar-16 6.0J 0.42J 2601-MSWLF-1980 SW-6 26-Aug-16 11J 1.8J 0.70J 0.64J 2601-MSWLF-1980 SW-6 8-Mar-17 0.57J 0.43J Notes: 1. All units are in micrograms per liter (parts per billion) 2. NS - No Standard 4. * - Human Health Standard - Indicates the result is below the detection limit North Carolina 2B Freshwater Aquatic Life or Human Health Standard Solid Waste Section Limit 5. J - Indicates the analytical result is an estimated concentration between the method detection limit and the Solid Waste Section Reporting Limit. 6. B - Indicates the amount detected in the method blank was greater than the method detection limit. dry dry 3. Standards obtained from 15A NCAC 02B (North Carolina 2B) Surface Water Standards for Class C Waters or are National Criteria per the U.S. Environmental Protection Agency (June 2016). Page 10 of 12 June 2017 Table 5EGeochemical DataMarch 2017 Semi-Annual Sampling EventCumberland County Closed LandfillFacility Permit Number 2601-MSWLF-1980Facility Permit NumberMonitoring Well CodeSample DateEthaneEtheneMethaneAcetic AcidButyric AcidLactic Acid (HIBA)iso-Hexanoic AcidHexanoic AcidPropionic AcidPyruvuc AcidDissolved HydrogenCarbon DioxideAlkalinityBiochemical Oxygen DemandChemical Oxygen DemandChlorideFerrous Iron - LabFerrous Iron - FieldNitrateSulfateSulfideTotal Organic CarbonDissolved OxygenOxidation-Reduction Potentialug/l ug/l ug/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l nM mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mVs2601-MSWLF-1980AW-229-Mar-11<2<215.3<0.5<0.5<0.5<0.08<0.078<0.5<0.51.90236210<2321226--0.34J21<0.18.50.6552.32601-MSWLF-1980AW-228-Sep-11<2<393.90.69<0.070.25<0.08<0.078<0.07<0.073.403972903.6471327--0.12J21J<0.1100.54-56.52601-MSWLF-1980AW-27-Mar-121.52J<2.3810D<0.04<0.024<0.062<0.08<0.0782.3<0.0610.71515D340D<26173B35--0.62J19JB<0.01140.61-37.42601-MSWLF-1980AW-227-Sep-122.03<0.5401,170D<0.031<0.031<0.095<0.08<0.078<0.0630.01J7.8637D390D3.198140BD45--0.520J11J<0.01210.38-20.12601-MSWLF-1980AW-26-Jun-132.49<1.5357D8.1<0.031<0.095<0.08<0.078<0.063<0.018.7567D300D2.298130D--7.20.079J8.1J<0.01210.58-65.92601-MSWLF-1980AW-21-Aug-13<1.3<1.5163D----------------491D250D--68----58.80.260J9.4JB----0.99-48.32601-MSWLF-1980AW-213-Nov-13<1.3<1.578.3<0.031<0.031<0.095<0.08<0.0783.3<0.013.5476D350D6.35788--45.20.240J8.2J<0.01170.63-33.42601-MSWLF-1980AW-223-Apr-14<1.3<1.522.8<0.031<0.031<0.095<0.08<0.078<0.063<0.01--323D230D5.64347--4.00.100J13J<0.01121.34-51.92601-MSWLF-1980AW-228-May-15<0.470<0.62065.1<0.031<0.031<0.095<0.08<0.078<0.063<0.0154.0229D150D3.6<1025--2.50.400J26J<0.015.50.74-116.92601-MSWLF-1980AW-212-Nov-15<0.470<0.62010.4<0.16<0.089<0.095<0.44<0.26<0.065<0.01213309D230D23514--7.00.072J14J<0.01100.28-40.72601-MSWLF-1980AW-216-Mar-16<0.470<0.6205,430D0.21<0.089<0.095<0.44<0.26<0.065<0.01229219D150D2.93320--4.50.098J10J<0.018.50.54-87.82601-MSWLF-1980AW-226-Aug-16<1.30<1.50.602J<0.16<0.089<0.095<0.44<0.26<0.065<0.01230159D91D2.31218--6.0<0.02526J<0.013.81.16-17.02601-MSWLF-1980AW-28-Mar-17<1.30<1.5025.7<0.16<0.089<0.095<0.44<0.26<0.065<0.01234143D95D<21719--7.00.16J26J<0.0102.80.149.22601-MSWLF-1980MW-A29-Mar-11<2<234<0.5<0.5<0.5<0.08<0.078<0.5<0.51.8078.370<211260.33--0.18J3.7J<0.15.51.4956.42601-MSWLF-1980MW-A28-Sep-11<2<32370.44<0.070.12<0.08<0.078<0.07<0.073.5015182<230254.3--1.0J3.1J<0.16.20.50-23.32601-MSWLF-1980MW-A7-Mar-12<1<2.3611D<0.04<0.024<0.062<0.08<0.0781.2<0.0613.70153100<25729B3.6--0.120J2.3JB0.019J9.12.2983.52601-MSWLF-1980MW-A27-Sep-12<0.200<0.540300D<0.031<0.031<0.095<0.08<0.078<0.0630.01J1115171<22828B4--4.2J3.8J<0.018.30.5912.42601-MSWLF-1980MW-A6-Jun-13<1.3<1.5122D<0.031<0.031<0.095<0.08<0.078<0.063<0.017.813569D<22828--4.80.066J2.9J<0.016.40.52-5.12601-MSWLF-1980MW-A13-Nov-13<1.3<1.588.1<0.031<0.031<0.095<0.08<0.0780.830<0.016.2115852.23027--3.20.14J2.9J<0.017.80.46-2.22601-MSWLF-1980MW-A23-Apr-14<1.3<1.560.0<0.031<0.031<0.095<0.08<0.078<0.063<0.013.210486<22827--2.5<0.025<0.012.9J8.70.6229.22601-MSWLF-1980MW-A28-May-15<0.470<0.62088.1<0.031<0.031<0.095<0.080<0.078<0.063<0.01011.013090<2<1032--2.00.078J3.0J<0.018.30.38-85.62601-MSWLF-1980MW-A12-Nov-15<0.470<0.62077.4<0.16<0.089<0.095<0.44<0.260.57<0.0125012867<22929--4.00.140J<2.9<0.0110.01.521.32601-MSWLF-1980MW-A16-Mar-16<0.470<0.620171<0.16<0.089<0.095<0.44<0.26<0.065<0.01228110110<23130--3.00.120J<2.90.018J8.91.16-88.62601-MSWLF-1980MW-A26-Aug-16<1.30<1.500.708J<0.16<0.089<0.095<0.44<0.26<0.065<0.0123411793<22531--7.00.11J<2.9<0.018.73.53-34.22601-MSWLF-1980MW-A8-Mar-17<1.30<1.5074.8<0.16<0.089<0.095<0.44<0.26<0.065<0.0123411078<22629--7.00.1J3J<0.017.21.3439.12601-MSWLF-1980MW-B29-Mar-11<2<23,670<0.5<0.5<0.5<0.08<0.078<0.5<0.52.50513550<212013042--0.14J1.90J<0.1330.2556.22601-MSWLF-1980MW-B28-Sep-111.63J<310,8000.84<0.071.10<0.08<0.0782.80<0.074.00821560<213015033--1.1J1.70J<0.1390.53-67.12601-MSWLF-1980MW-B7-Mar-121.71J<2.312,400D<0.04<0.024<0.062<0.08<0.0780.930<0.0610.72842D460D<2110110BD41--3.7J1.6JB0.030J310.32-43.12601-MSWLF-1980MW-B27-Sep-121.13J<0.5405,370D<0.031<0.031<0.095<0.08<0.078<0.063<0.018.1763D450D<2130150BD45--0.410J2J0.025J330.35-37.52601-MSWLF-1980MW-B6-Jun-13<1.3<1.53,820D<0.031<0.031<0.0953.6<0.078<0.063<0.018.1684D370D<2120140D--4.60.14J2.5J0.025J270.46-60.32601-MSWLF-1980MW-B13-Nov-13<1.3<1.53,840D<0.031<0.031<0.095<0.08<0.0783.2<0.012.1623D530D7120150D--4.40.410J<2.9<0.01350.42-40.62601-MSWLF-1980MW-B23-Apr-14<1.3<1.51,430D<0.031<0.031<0.095<0.08<0.078<0.063<0.014.1315D470D6130180D--1.7<0.025<2.90.085J441.64-58.32601-MSWLF-1980MW-B28-May-15<0.470<0.6202,280D<0.031<0.031<0.095<0.08<0.078<0.063<0.0147.0597D790D11190350D--1.50.490J<2.9<0.01590.42-138.72601-MSWLF-1980MW-B12-Nov-15<0.470<0.6204,480D<0.16<0.089<0.095<0.44<0.26<0.065<0.01212915D780D5.8240320D--5.01.4J<2.90.011J750.15-67.42601-MSWLF-1980MW-B16-Mar-16<0.470<0.6206,060D<0.16<0.089<0.095<0.44<0.26<0.065<0.01226884D840D4.5250380D--6.50.078<2.9<0.01780.37-151.02601-MSWLF-1980MW-B26-Aug-16<1.30<1.503,750D<0.16<0.089<0.095<0.44<0.26<0.065<0.01227803D870D5.8250410D--6.50.53J<2.9<0.01810.83-102.52601-MSWLF-1980MW-B8-Mar-17<1.30<1.504,710D<0.16<0.089<0.095<0.44<0.26<0.065<0.0129.2790D870D<2 250380D--4.50.12J<2.9<0.0174D0.34-78.4UnitsPage 11 of 12June 2017 Table 5EGeochemical DataMarch 2017 Semi-Annual Sampling EventCumberland County Closed LandfillFacility Permit Number 2601-MSWLF-1980Facility Permit NumberMonitoring Well CodeSample DateEthaneEtheneMethaneAcetic AcidButyric AcidLactic Acid (HIBA)iso-Hexanoic AcidHexanoic AcidPropionic AcidPyruvuc AcidDissolved HydrogenCarbon DioxideAlkalinityBiochemical Oxygen DemandChemical Oxygen DemandChlorideFerrous Iron - LabFerrous Iron - FieldNitrateSulfateSulfideTotal Organic CarbonDissolved OxygenOxidation-Reduction Potentialug/l ug/l ug/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l nM mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mVsUnits2601-MSWLF-1980MW-H29-Mar-11<2<22,860<0.5<0.5<0.5<0.08<0.078<0.5<0.54.105324503.211019038--0.33J8.60J<0.1310.4354.22601-MSWLF-1980MW-H28-Sep-112.57<39,140<0.07<0.0721<0.08<0.07813<0.074.901,0406002.715024052--0.086J1.90J<0.1380.28-67.92601-MSWLF-1980MW-H7-Mar-121.60J<2.38,950D<0.04<0.024<0.062<0.08<0.07814<0.0612.201,000D560D4140240BD40--0.092J1.9JB0.05J410.17-37.62601-MSWLF-1980MW-H27-Sep-121.39J<0.54011,000D38<0.031<0.095<0.08<0.07814<0.0110919D410D25170170BD78--0.080J2.8J<0.01430.24-19.42601-MSWLF-1980MW-H6-Jun-131.7J<1.54,510D22<0.031<0.095<0.08<0.078<0.063<0.0110913D460D4.5140170D--7.50.1J2.7J<0.01300.45-72.22601-MSWLF-1980MW-H13-Nov-13<1.3<1.56,470D<0.031<0.031<0.095<0.082.912<0.011.6841D630D9.7130210D--8.20.095J<2.90.028J360.43-33.12601-MSWLF-1980MW-H23-Apr-14<1.3<1.53,530D<0.031<0.031<0.095<0.083.3<0.063<0.013.6493D760D6.6190350D--3.5<0.025<2.90.072J611.90-41.12601-MSWLF-1980MW-H28-May-15<0.470<0.6202,470D20<0.0319.8<0.080<0.07813<0.0115692D670D12130320D--20.100J<2.90.046J430.33-107.12601-MSWLF-1980MW-H12-Nov-15<0.470<0.6203,390D26<0.089<0.095<0.44<0.2617<0.01219983D530D12190330D--3.50.620J<2.90.110J540.10-50.12601-MSWLF-1980MW-H16-Mar-16<0.470<0.6206,930D22<0.08910<0.44<0.2615<0.012481,260D650D9.4190310D--4.50.72J<2.90.130J550.60-143.22601-MSWLF-1980MW-H26-Aug-16<1.30<1.502,020D17<0.089<0.095<0.44<0.2611<0.01229645D520D11140250D--6.00.080J<2.90.066J351.82-83.52601-MSWLF-1980MW-H8-Mar-17<1.30<1.504,970D17<0.0897.9<0.44<0.2610<0.01236799D490D<2130250--4.50.093J<2.90.067J410.34-71.1Notes:1. mg/L - milligrams per liter (parts per million)6. mVs - Millivolts2. ug/L - micrograms per liter (parts per billion)3. nM - nanomoles4. -- Not Measured9. D - Analyzed at dilution5. HIBA - (2-Hydroxyisobutyric Acid) 7. J - Indicates the analytical result is an estimated concentration between the method detection limit and the Solid Waste Section Reporting Limit. 8. B - Indicates the amount detected in the method blank was greater than the method detection limit.Page 12 of 12June 2017 Table 6 Constituents Exceeding Standards March 2017 Semi-Annual Sampling Event Cumberland County Closed Landfill Facility Permit Number 2601-MSWLF-1980 2601-MSWLF-1980 MW-A Cobalt*, Thallium*, Vanadium* 2601-MSWLF-1980 MW-1A Arsenic, Cobalt*, Thallium*, Vanadium* 2601-MSWLF-1980 MW-B Arsenic, Barium, Cobalt*, Vanadium*, Benzene 2601-MSWLF-1980 MW-H Arsenic, Barium, Cobalt*, Vanadium*, Zinc, Benzene, 1,4-Dichlorobenzene 2601-MSWLF-1980 AW-1s Cobalt*, Thallium*, Vanadium* 2601-MSWLF-1980 AW-1d Thallium*, Vanadium* 2601-MSWLF-1980 AW-2 Cobalt*, Thallium*, Vanadium* 2601-MSWLF-1980 AW-3 Cobalt*, Vanadium* 2601-MSWLF-1980 AW-4 Cobalt*, Thallium*, Vanadium* Notes: 1. * - Groundwater Protection Standard 2. Bold - J flag detection that indicates the analytical result is an estimated concentration between the method detection limit and the Solid Waste Section Reporting Limit. MONITORING WELL CODE PARAMETERS EXCEEDING THE NORTH CAROLINA 2L OR GROUNDWATER PROTECTION STANDARD SAMPLING EVENT - MARCH 2017 FACILITY PERMIT NUMBER Page 1 of 1 June 2017 Figures M-8M-2M-3M-7M-5SW-5SW-4MW-B71.67MW-1A72.83SW-3AW-1s71.57AW-1d68.80MW-H73.10AW-270.99AW-379.92AW-481.31MW-A80.38Figure 1: Potentiometric Surface MapLEGENDSurface Water Sample LocationGroundwater Monitoring WellPotentiometric Contour(dashed where inferred)Contour Interval = 2 feetNotes: Groundwater elevations were measured on March 7, 2017.SW-6 is located east of SW-5 near the Cape Fear River.Potentiometric contours are derived from previous site investigationsand are adjusted based on recent groundwater elevations.78Landfill Gas Monitoring WellScale in FeetClosed LandfillC&D LandfillSubtitle D LandfillMap Source: Microsoft Bing, 2011 Aerial, Fayetteville, North Carolina Figure 2 MW-B Total Volatile Organic Compounds Concentration Trend Cumberland County Ann Street Landfill Facility Permit Number 2601-MSWLF-1980 Figure 2 0 20 40 60 80 100 120 Mar-95Sep-95Mar-96Sep-96Mar-97Sep-97Mar-98Sep-98Mar-99Sep-99Mar-00Sep-00Mar-01Sep-01Mar-02Sep-02Mar-03Sep-03Mar-04Sep-04Mar-05Sep-05Mar-06Sep-06Mar-07Sep-07Mar-08Sep-08Mar-09Sep-09Mar-10Sep-10Mar-11Sep-11Mar-12Sep-12Mar-13Sep-13Mar-14Sep-14Mar-15Sep-15Mar-16Sep-16Mar-17Concentration (parts per billion)Date Total Volatile Organic Compounds Trend Line Figure 3 MW-H Total Volatile Organic Compound Concentration Trend Cumberland County Ann Street Landfill Facility Permit Number 2601-MSWLF-1980 Figure 3 0 10 20 30 40 50 60 Sep-94Mar-95Sep-95Mar-96Sep-96Mar-97Sep-97Mar-98Sep-98Mar-99Sep-99Mar-00Sep-00Mar-01Sep-01Mar-02Sep-02Mar-03Sep-03Mar-04Sep-04Mar-05Sep-05Mar-06Sep-06Mar-07Sep-07Mar-08Sep-08Mar-09Sep-09Mar-10Sep-10Mar-11Sep-11Mar-12Sep-12Mar-13Sep-13Mar-14Sep-14Mar-15Sep-15Mar-16Sep-16Mar-17Concentration (parts per billion)Date Total Volatile Organic Compounds Trend Line Figure 4 AW-2 Total Volatile Organic Compound Concentration Trend Cumberland County Ann Street Landfill Facility Permit Number 2601-MSWLF-1980 Figure 4 0 2 4 6 8 10 12 14 Feb-99Sep-99Apr-00Nov-00Jun-01Jan-02Aug-02Mar-03Oct-03May-04Dec-04Jul-05Feb-06Sep-06Apr-07Nov-07Jun-08Jan-09Aug-09Mar-10Oct-10May-11Dec-11Jul-12Feb-13Sep-13Apr-14Nov-14Jun-15Jan-16Aug-16Mar-17Concentration (parts per billion)Date Series1 Trend Line November 2009 Injection May 2013 Injection Appendix A Laboratory Analytical Data Pace Analytical Energy Services LLC CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, Report ID: 21952 - 901045 Page 1 of 11 Chuck Smith Environmental Conservation Labs, Inc. 102A Woodwinds Industrial Ct. Cary, NC 27511 March 22, 2017 RE: Pace Workorder: CA02346 Dear Chuck Smith: 21952 Enclosed are the analytical results for sample(s) received by the laboratory on Friday, March 10, 2017. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Enclosures Ruth Welsh 03/22/2017 Ruth.Welsh@pacelabs.com Total Number of Pages ____ As a valued client we would appreciate your comments on our service. Please email PAESfeedback@pacelabs.com. Customer Service Representative 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 without the written consent of Pace Analytical Energy Services LLC. 12 Pace Analytical Energy Services LLC CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, Report ID: 21952 - 901045 Page 2 of 11 LABORATORY ACCREDITATIONS & CERTIFICATIONS Pennsylvania Department of Environmental Protection, Bureau of Laboratories 02-00538 NELAP Non-Potable Water and Solid & Hazardous Waste Accreditor: Accreditation ID: Scope: West Virginia Department of Environmental Protection, Division of Water and Waste Management 395 Non-Potable Water Accreditor: Accreditation ID: Scope: South Carolina Department of Health and Environmental Control, Office of Environmental Laboratory Certification 89009003 Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA) Accreditor: Accreditation ID: Scope: NELAP: New Jersey, Department of Environmental Protection PA026 Non-Potable Water; Solid and Chemical Materials Accreditor: Accreditation ID: Scope: NELAP: New York, Department of Health Wadsworth Center 11815 Non-Potable Water; Solid and Hazardous Waste Accreditor: Accreditation ID: Scope: State of Connecticut, Department of Public Health, Division of Environmental Health PH-0263 Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA) Accreditor: Accreditation ID: Scope: NELAP: Texas, Commission on Environmental Quality T104704453-09-TX Non-Potable Water Accreditor: Accreditation ID: Scope: State of New Hampshire 299409 Non-potable water Accreditor: Accreditation ID: Scope: State of Georgia Chapter 391-3-26 As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is accredited by the Pennsylvania Department of Environmental Protection Bureau of Laboratories under the National Environmental Laboratory Approval Program (NELAC). Accreditor: Accreditation ID: Scope: 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, Report ID: 21952 - 901045 Page 3 of 11 SAMPLE SUMMARY Workorder:21952 CA02346 Lab ID Sample ID Matrix Date Collected Date Received 219520001 2601-MWA DISSOLVED Bubble Strip 3/8/2017 13:40 3/10/2017 12:50 219520002 2601-MWB DISSOLVED Bubble Strip 3/8/2017 10:50 3/10/2017 12:50 219520003 2601-MWH DISSOLVED Bubble Strip 3/8/2017 11:45 3/10/2017 12:50 219520004 2601-AW2 DISSOLVED Bubble Strip 3/8/2017 12:45 3/10/2017 12:50 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, Report ID: 21952 - 901045 Page 4 of 11 ANALYTICAL RESULTS Workorder:21952 CA02346 3/10/2017 12:50 2601-MWA DISSOLVED Matrix:Bubble Strip RegLmtParameters Lab ID: Sample ID: RegLmt 219520001 Results Units PQL DF ByAnalyzedMDL Qualifiers Date Collected: Date Received: 3/8/2017 13:40 RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 34 nM 0.60 1 3/16/2017 15:25 TD n0.075 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, Report ID: 21952 - 901045 Page 5 of 11 ANALYTICAL RESULTS Workorder:21952 CA02346 3/10/2017 12:50 2601-MWB DISSOLVED Matrix:Bubble Strip RegLmtParameters Lab ID: Sample ID: RegLmt 219520002 Results Units PQL DF ByAnalyzedMDL Qualifiers Date Collected: Date Received: 3/8/2017 10:50 RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 9.2 nM 0.60 1 3/16/2017 15:47 TD n0.075 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, Report ID: 21952 - 901045 Page 6 of 11 ANALYTICAL RESULTS Workorder:21952 CA02346 3/10/2017 12:50 2601-MWH DISSOLVED Matrix:Bubble Strip RegLmtParameters Lab ID: Sample ID: RegLmt 219520003 Results Units PQL DF ByAnalyzedMDL Qualifiers Date Collected: Date Received: 3/8/2017 11:45 RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 36 nM 1.2 2 3/16/2017 16:41 TD d,n0.15 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, Report ID: 21952 - 901045 Page 7 of 11 ANALYTICAL RESULTS Workorder:21952 CA02346 3/10/2017 12:50 2601-AW2 DISSOLVED Matrix:Bubble Strip RegLmtParameters Lab ID: Sample ID: RegLmt 219520004 Results Units PQL DF ByAnalyzedMDL Qualifiers Date Collected: Date Received: 3/8/2017 12:45 RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 34 nM 1.2 2 3/16/2017 16:53 TD d,n0.15 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, Report ID: 21952 - 901045 Page 8 of 11 ANALYTICAL RESULTS QUALIFIERS Workorder:21952 CA02346 DEFINITIONS/QUALIFIERS U J Indicates the compound was analyzed for, but not detected at or above the noted concentration. Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL). MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection. PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation. ND Not detected at or above reporting limit. DF Dilution Factor. S Surrogate. RPD Relative Percent Difference. % Rec Percent Recovery. The laboratory does not hold NELAP/TNI accreditation for this method or analyte.n The analyte concentration was determined from a dilution.d 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, Report ID: 21952 - 901045 Page 9 of 11 QUALITY CONTROL DATA Workorder:21952 CA02346 QC Batch: QC Batch Method: DISG/5978 AM20GAX Analysis Method:AM20GAX Associated Lab Samples:219520001, 219520002, 219520003, 219520004 METHOD BLANK:47562 Parameter Units Result Blank Limit Reporting Qualifiers RISK Hydrogen <0.60nM 0.60 n LABORATORY CONTROL SAMPLE & LCSD: Parameter Units Conc. Spike Result LCS 47563 47564 LCSD Result % Rec LCS LCSD % Rec % Rec Limit RPD RPD Max Qualifiers RISK Hydrogen nM 24 23 93 80-120 n23963.2 20 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, Report ID: 21952 - 901045 Page 10 of 11 QUALITY CONTROL DATA QUALIFIERS Workorder:21952 CA02346 QUALITY CONTROL PARAMETER QUALIFIERS The laboratory does not hold NELAP/TNI accreditation for this method or analyte.n 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, Report ID: 21952 - 901045 Page 11 of 11 QUALITY CONTROL DATA CROSS REFERENCE TABLE Workorder:21952 CA02346 Lab ID Sample ID Prep Method Analysis MethodPrep Batch Batch Analysis 219520001 2601-MWA DISSOLVED DISG/5978AM20GAX 219520002 2601-MWB DISSOLVED DISG/5978AM20GAX 219520003 2601-MWH DISSOLVED DISG/5978AM20GAX 219520004 2601-AW2 DISSOLVED DISG/5978AM20GAX 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 without the written consent of Pace Analytical Energy Services LLC. Appendix B Landfill Gas Monitoring Data cdmsmith.com