9602_WayneCountyPikeville_GWMR_DIN28167_20160923

Northern Wayne County Closed Unlined MSWLF - Pikeville
Pikeville, North Carolina
September 2016
MESCO Project Number: G16016.0
Annual Water Quality Monitoring Report
Prepared for
Municipal Engineering Services Company, P.A.Garner and Boone , North Carolina
Permit Number: 96-02-MSWLF-1981
Tables
Wayne County Closed Landfill, Pikeville Page 1 of 1
Table 1
Groundwater Monitoring Well Construction Table
September 23, 2016
Latitude Longitude
(inches)(ft)
MW-2 1.25 24.85 soil 2.92 35.483875 -78.004758
MW-3 1.25 25.20 soil 0.00 35.481458 -78.000765
MW-4 1.25 20.50 soil 8.60 35.476471 -78.002436
MW-5 1.25 21.95 soil 20.07 35.481289 -78.003996
Monitoring
Well
Date
Installed
Well
Diameter
Total
Well Depth
Top of Screen
Depth
Screen
Length Geology of Screened
Interval
Top of
Casing Elevation
Ground
Elevation
Groundwater
Elevation
Depth to
Water
(ft btoc)(ft bgs)(ft amsl)(ft amsl)(ft amsl)(ft btoc)
na na na na na na
na na na na na na
na na na na na na
na na na na na na
na = not available
bgs = below ground surface
amsl= above mean sea level
btoc = below top of PVC well casing
Wayne County Closed Landfill, Pikeville Page 1 of 1
Table 2
Field Observations of Monitoring Locations
September 23, 2016
Locked Comments
MW-2 Yes Yes Yes Yes No Yes
MW-3 Yes Yes Yes Yes No Yes Lock is poor
MW-4 Yes Yes Yes Yes No Yes
MW-5 Yes Yes Yes Yes No Yes
SW-1 No - - --- Dry
Any unusual field conditions, observations, or events:
All wells locked but not labeled very well.
All wells 1.25” nominal PVC
Sample
Location
Viable
Monitoring
Location
Lack of Any
Evidence of
Tampering
Hinge/Hasp
Operational
Tagged
or
Labeled
Concrete
Surface Pad
Assumed
Effective
Wayne County Subtitle D Lined MSWLF Page 1 of 1
Table 3
Field Parameter Data Summary
September 23, 2016
Parameter Temp.ORP DO pH TDS Turbidity
Units C mg/L SU visual %/vol
MW-2 2.92 19.3 NR NR 6.90 303 NR Clear NR
MW-3 0.00 20.9 NR NR 6.90 200 NR Clear NR
MW-4 8.60 20.1 NR NR 5.70 198 NR Clear NR
MW-5 20.07 17.5 NR NR 4.70 182 NR Clear NR
Minimum 0.00 17.5 NR NR 4.70 182 NR Clear NR
Average 7.90 19.5 NR NR 6.05 221 NR Clear NR
Maximum 20.07 20.9 NR NR 6.90 303 NR Clear NR
NR = No Reading Attempted and not required
Depth to
Water
Water
Elevation
TOC
Elevation
Specific
Conductance
Methane Gas
in Well
Headspace
ft (btoc)ft (amsl)ft (amsl)mV цs/cm ppb
na na
na na
na na
na na
na na
na na
na na
Wayne County Closed MSWLF (Pikeville)Page 1 of 1
Table 4
September 23, 2016
Result Unit
MW-4 Cadmium,total 9/23/16 1.9 0.5 1 2 5
MW-4 Zinc,total 9/23/16 18.9 5 10 1000 5000
MW-5 Barium,total 9/23/16 244 2.5 100 700 2000
MW-5 Cadmium,total 9/23/16 1.2 0.5 1 2 5
MW-5 Copper,total 9/23/16 10.2 2.5 10 1000 1300
MW-5 Zinc,total 9/23/16 34.3 5 10 1000 5000
A definitive source of the detection was not determined as part of this report. Preliminary cause only listed pursuant to instructions
Concentration > 2L, GWP or MCL Standard
Detections in Water Samples above Established SWSL, GWP, 2L or MCL (Appendix I)
Sample
ID Parameter Name 1 Sample
Date MDL 2 SWSL 3 2L 4 GWP 5 MCL 6 Preliminary Cause 7
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1 Table contains constituents detected at or above SWSL, GWP, 2L, or MCL
2 MDL = Method Detection Limit
3 SWSL = Solid Waste Section Reporting Limit
4 2L = North Carolina 15A NCAC 2L Groundwater Quality Standard
5 GWP = Groundwater Protection Standard
6 MCL = Primary Drinking Water Standard (not currently applicable for regulatory comparisons)
7 Preliminary Cause = Refers to a preliminary analysis of the cause and/or source of a detection over the respective 2L Standard.
BOLD =
Appendix A
Laboratory Analysis Reports
Chains of Custody
#=CL#
October 13, 2016
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92313975
92313975
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
68 Shipwash Dr.
Garner, NC 27529
PIKEVILLE
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on September 28, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 23
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92313975
PIKEVILLE
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 23
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92313975
PIKEVILLE
Lab ID Sample ID Matrix Date Collected Date Received
92313975001 MW-2 Water 09/23/16 15:50 09/28/16 08:16
92313975002 MW-3 Water 09/23/16 16:15 09/28/16 08:16
92313975003 MW-4 Water 09/23/16 16:57 09/28/16 08:16
92313975004 MW-5 Water 09/23/16 16:40 09/28/16 08:16
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 23
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92313975
PIKEVILLE
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92313975001 MW-2 EPA 6010 15 PASI-AJMW, SH1
EPA 8260 50 PASI-CZDO
92313975002 MW-3 EPA 6010 15 PASI-AJMW
EPA 8260 50 PASI-CZDO
92313975003 MW-4 EPA 6010 15 PASI-ASH1
EPA 8260 50 PASI-CZDO
92313975004 MW-5 EPA 6010 15 PASI-ASH1
EPA 8260 50 PASI-CZDO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92313975
PIKEVILLE
Sample:MW-2 Lab ID:92313975001 Collected:09/23/16 15:50 Received:09/28/16 08:16 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 10/05/16 00:02 7440-36-009/30/16 22:056.0 3.8 1
Arsenic ND ug/L 10/05/16 15:23 7440-38-209/30/16 22:0510.0 2.5 1
Barium 41.0J ug/L 10/05/16 00:02 7440-39-309/30/16 22:051002.5 1
Beryllium ND ug/L 10/05/16 00:02 7440-41-709/30/16 22:051.0 0.50 1
Cadmium 0.72J ug/L 10/05/16 00:02 7440-43-909/30/16 22:051.0 0.50 1
Chromium ND ug/L 10/05/16 00:02 7440-47-309/30/16 22:0510.0 2.5 1
Cobalt ND ug/L 10/05/16 00:02 7440-48-409/30/16 22:0510.0 2.5 1
Copper ND ug/L 10/05/16 00:02 7440-50-809/30/16 22:0510.0 2.5 1
Lead ND ug/L 10/05/16 00:02 7439-92-109/30/16 22:0510.0 2.5 1
Nickel ND ug/L 10/05/16 00:02 7440-02-009/30/16 22:0550.0 2.5 1
Selenium ND ug/L 10/05/16 00:02 7782-49-209/30/16 22:0510.0 5.0 1
Silver ND ug/L 10/05/16 00:02 7440-22-409/30/16 22:0510.0 2.5 1
Thallium ND ug/L 10/05/16 00:02 7440-28-009/30/16 22:055.5 5.0 1
Vanadium ND ug/L 10/05/16 00:02 7440-62-209/30/16 22:0525.0 2.5 1
Zinc 14.0 ug/L 10/05/16 00:02 7440-66-609/30/16 22:0510.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/02/16 21:07 67-64-110010.0 1
Acrylonitrile ND ug/L 10/02/16 21:07 107-13-12001.9 1
Benzene ND ug/L 10/02/16 21:07 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/02/16 21:07 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/02/16 21:07 75-27-41.0 0.18 1
Bromoform ND ug/L 10/02/16 21:07 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/02/16 21:07 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/02/16 21:07 78-93-31000.96 1
Carbon disulfide ND ug/L 10/02/16 21:07 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/02/16 21:07 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/02/16 21:07 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/02/16 21:07 75-00-310.0 0.54 1
Chloroform ND ug/L 10/02/16 21:07 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/02/16 21:07 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/02/16 21:07 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/02/16 21:07 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/02/16 21:07 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/02/16 21:07 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/02/16 21:07 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 10/02/16 21:07 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/02/16 21:07 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 10/02/16 21:07 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/02/16 21:07 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/02/16 21:07 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/02/16 21:07 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/02/16 21:07 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/02/16 21:07 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 10/02/16 21:07 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 10/02/16 21:07 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/13/2016 10:34 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92313975
PIKEVILLE
Sample:MW-2 Lab ID:92313975001 Collected:09/23/16 15:50 Received:09/28/16 08:16 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 10/02/16 21:07 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/02/16 21:07 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/02/16 21:07 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/02/16 21:07 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/02/16 21:07 108-10-11000.33 1
Styrene ND ug/L 10/02/16 21:07 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/02/16 21:07 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/02/16 21:07 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/02/16 21:07 127-18-41.0 0.46 1
Toluene ND ug/L 10/02/16 21:07 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/02/16 21:07 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/02/16 21:07 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/02/16 21:07 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/02/16 21:07 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/02/16 21:07 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/02/16 21:07 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/02/16 21:07 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/02/16 21:07 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)102 %10/02/16 21:07 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %10/02/16 21:07 17060-07-070-130 1
Toluene-d8 (S)104 %10/02/16 21:07 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/13/2016 10:34 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92313975
PIKEVILLE
Sample:MW-3 Lab ID:92313975002 Collected:09/23/16 16:15 Received:09/28/16 08:16 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 10/05/16 15:35 7440-36-009/30/16 22:056.0 3.8 1
Arsenic ND ug/L 10/05/16 15:35 7440-38-209/30/16 22:0510.0 2.5 1
Barium 70.0J ug/L 10/05/16 15:35 7440-39-309/30/16 22:051002.5 1
Beryllium ND ug/L 10/05/16 15:35 7440-41-709/30/16 22:051.0 0.50 1
Cadmium 0.79J ug/L 10/05/16 15:35 7440-43-909/30/16 22:051.0 0.50 1
Chromium ND ug/L 10/05/16 15:35 7440-47-309/30/16 22:0510.0 2.5 1
Cobalt ND ug/L 10/05/16 15:35 7440-48-409/30/16 22:0510.0 2.5 1
Copper ND ug/L 10/05/16 15:35 7440-50-809/30/16 22:0510.0 2.5 1
Lead ND ug/L 10/05/16 15:35 7439-92-109/30/16 22:0510.0 2.5 1
Nickel ND ug/L 10/05/16 15:35 7440-02-009/30/16 22:0550.0 2.5 1
Selenium ND ug/L 10/05/16 15:35 7782-49-209/30/16 22:0510.0 5.0 1
Silver ND ug/L 10/05/16 15:35 7440-22-409/30/16 22:0510.0 2.5 1
Thallium ND ug/L 10/05/16 15:35 7440-28-009/30/16 22:055.5 5.0 1
Vanadium ND ug/L 10/05/16 15:35 7440-62-209/30/16 22:0525.0 2.5 1
Zinc 9.2J ug/L 10/05/16 15:35 7440-66-609/30/16 22:0510.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/02/16 21:25 67-64-110010.0 1
Acrylonitrile ND ug/L 10/02/16 21:25 107-13-12001.9 1
Benzene ND ug/L 10/02/16 21:25 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/02/16 21:25 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/02/16 21:25 75-27-41.0 0.18 1
Bromoform ND ug/L 10/02/16 21:25 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/02/16 21:25 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/02/16 21:25 78-93-31000.96 1
Carbon disulfide ND ug/L 10/02/16 21:25 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/02/16 21:25 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/02/16 21:25 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/02/16 21:25 75-00-310.0 0.54 1
Chloroform ND ug/L 10/02/16 21:25 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/02/16 21:25 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/02/16 21:25 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/02/16 21:25 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/02/16 21:25 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/02/16 21:25 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/02/16 21:25 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 10/02/16 21:25 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/02/16 21:25 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 10/02/16 21:25 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/02/16 21:25 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/02/16 21:25 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/02/16 21:25 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/02/16 21:25 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/02/16 21:25 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 10/02/16 21:25 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 10/02/16 21:25 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/13/2016 10:34 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92313975
PIKEVILLE
Sample:MW-3 Lab ID:92313975002 Collected:09/23/16 16:15 Received:09/28/16 08:16 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 10/02/16 21:25 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/02/16 21:25 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/02/16 21:25 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/02/16 21:25 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/02/16 21:25 108-10-11000.33 1
Styrene ND ug/L 10/02/16 21:25 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/02/16 21:25 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/02/16 21:25 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/02/16 21:25 127-18-41.0 0.46 1
Toluene ND ug/L 10/02/16 21:25 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/02/16 21:25 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/02/16 21:25 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/02/16 21:25 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/02/16 21:25 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/02/16 21:25 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/02/16 21:25 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/02/16 21:25 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/02/16 21:25 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)101 %10/02/16 21:25 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %10/02/16 21:25 17060-07-070-130 1
Toluene-d8 (S)108 %10/02/16 21:25 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/13/2016 10:34 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92313975
PIKEVILLE
Sample:MW-4 Lab ID:92313975003 Collected:09/23/16 16:57 Received:09/28/16 08:16 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 10/05/16 00:18 7440-36-009/30/16 22:056.0 3.8 1
Arsenic ND ug/L 10/05/16 00:18 7440-38-209/30/16 22:0510.0 2.5 1
Barium 24.5J ug/L 10/05/16 00:18 7440-39-309/30/16 22:051002.5 1
Beryllium ND ug/L 10/05/16 00:18 7440-41-709/30/16 22:051.0 0.50 1
Cadmium 1.9 ug/L 10/05/16 00:18 7440-43-909/30/16 22:051.0 0.50 1
Chromium ND ug/L 10/05/16 00:18 7440-47-309/30/16 22:0510.0 2.5 1
Cobalt ND ug/L 10/05/16 00:18 7440-48-409/30/16 22:0510.0 2.5 1
Copper ND ug/L 10/05/16 00:18 7440-50-809/30/16 22:0510.0 2.5 1
Lead ND ug/L 10/05/16 00:18 7439-92-109/30/16 22:0510.0 2.5 1
Nickel ND ug/L 10/05/16 00:18 7440-02-009/30/16 22:0550.0 2.5 1
Selenium ND ug/L 10/05/16 00:18 7782-49-209/30/16 22:0510.0 5.0 1
Silver ND ug/L 10/05/16 00:18 7440-22-409/30/16 22:0510.0 2.5 1
Thallium ND ug/L 10/05/16 00:18 7440-28-009/30/16 22:055.5 5.0 1
Vanadium ND ug/L 10/05/16 00:18 7440-62-209/30/16 22:0525.0 2.5 1
Zinc 18.9 ug/L 10/05/16 00:18 7440-66-609/30/16 22:0510.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/02/16 21:42 67-64-110010.0 1
Acrylonitrile ND ug/L 10/02/16 21:42 107-13-12001.9 1
Benzene ND ug/L 10/02/16 21:42 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/02/16 21:42 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/02/16 21:42 75-27-41.0 0.18 1
Bromoform ND ug/L 10/02/16 21:42 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/02/16 21:42 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/02/16 21:42 78-93-31000.96 1
Carbon disulfide ND ug/L 10/02/16 21:42 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/02/16 21:42 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/02/16 21:42 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/02/16 21:42 75-00-310.0 0.54 1
Chloroform ND ug/L 10/02/16 21:42 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/02/16 21:42 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/02/16 21:42 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/02/16 21:42 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/02/16 21:42 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/02/16 21:42 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/02/16 21:42 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 10/02/16 21:42 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/02/16 21:42 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 10/02/16 21:42 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/02/16 21:42 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/02/16 21:42 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/02/16 21:42 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/02/16 21:42 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/02/16 21:42 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 10/02/16 21:42 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 10/02/16 21:42 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/13/2016 10:34 AM
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Page 9 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92313975
PIKEVILLE
Sample:MW-4 Lab ID:92313975003 Collected:09/23/16 16:57 Received:09/28/16 08:16 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 10/02/16 21:42 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/02/16 21:42 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/02/16 21:42 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/02/16 21:42 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/02/16 21:42 108-10-11000.33 1
Styrene ND ug/L 10/02/16 21:42 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/02/16 21:42 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/02/16 21:42 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/02/16 21:42 127-18-41.0 0.46 1
Toluene ND ug/L 10/02/16 21:42 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/02/16 21:42 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/02/16 21:42 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/02/16 21:42 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/02/16 21:42 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/02/16 21:42 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/02/16 21:42 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/02/16 21:42 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/02/16 21:42 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)103 %10/02/16 21:42 460-00-470-130 1
1,2-Dichloroethane-d4 (S)96 %10/02/16 21:42 17060-07-070-130 1
Toluene-d8 (S)105 %10/02/16 21:42 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/13/2016 10:34 AM
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Page 10 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92313975
PIKEVILLE
Sample:MW-5 Lab ID:92313975004 Collected:09/23/16 16:40 Received:09/28/16 08:16 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 10/05/16 00:21 7440-36-009/30/16 22:056.0 3.8 1
Arsenic 3.3J ug/L 10/05/16 00:21 7440-38-209/30/16 22:0510.0 2.5 1
Barium 244 ug/L 10/05/16 00:21 7440-39-309/30/16 22:051002.5 1
Beryllium 0.56J ug/L 10/05/16 00:21 7440-41-709/30/16 22:051.0 0.50 1
Cadmium 1.2 ug/L 10/05/16 00:21 7440-43-909/30/16 22:051.0 0.50 1
Chromium ND ug/L 10/05/16 00:21 7440-47-309/30/16 22:0510.0 2.5 1
Cobalt 4.2J ug/L 10/05/16 00:21 7440-48-409/30/16 22:0510.0 2.5 1
Copper 10.2 ug/L 10/05/16 00:21 7440-50-809/30/16 22:0510.0 2.5 1
Lead 5.0J ug/L 10/05/16 00:21 7439-92-109/30/16 22:0510.0 2.5 1
Nickel 6.5J ug/L 10/05/16 00:21 7440-02-009/30/16 22:0550.0 2.5 1
Selenium ND ug/L 10/05/16 00:21 7782-49-209/30/16 22:0510.0 5.0 1
Silver ND ug/L 10/05/16 00:21 7440-22-409/30/16 22:0510.0 2.5 1
Thallium ND ug/L 10/05/16 00:21 7440-28-009/30/16 22:055.5 5.0 1
Vanadium ND ug/L 10/05/16 00:21 7440-62-209/30/16 22:0525.0 2.5 1
Zinc 34.3 ug/L 10/05/16 00:21 7440-66-609/30/16 22:0510.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 10/02/16 22:00 67-64-110010.0 1
Acrylonitrile ND ug/L 10/02/16 22:00 107-13-12001.9 1
Benzene ND ug/L 10/02/16 22:00 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 10/02/16 22:00 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 10/02/16 22:00 75-27-41.0 0.18 1
Bromoform ND ug/L 10/02/16 22:00 75-25-23.0 0.26 1
Bromomethane ND ug/L 10/02/16 22:00 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 10/02/16 22:00 78-93-31000.96 1
Carbon disulfide ND ug/L 10/02/16 22:00 75-15-01001.2 1
Carbon tetrachloride ND ug/L 10/02/16 22:00 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 10/02/16 22:00 108-90-73.0 0.23 1
Chloroethane ND ug/L 10/02/16 22:00 75-00-310.0 0.54 1
Chloroform ND ug/L 10/02/16 22:00 67-66-35.0 0.14 1
Chloromethane ND ug/L 10/02/16 22:00 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 10/02/16 22:00 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 10/02/16 22:00 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 10/02/16 22:00 106-93-41.0 0.27 1
Dibromomethane ND ug/L 10/02/16 22:00 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 10/02/16 22:00 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 10/02/16 22:00 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/02/16 22:00 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 10/02/16 22:00 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 10/02/16 22:00 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 10/02/16 22:00 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 10/02/16 22:00 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 10/02/16 22:00 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 10/02/16 22:00 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 10/02/16 22:00 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 10/02/16 22:00 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/13/2016 10:34 AM
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Page 11 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92313975
PIKEVILLE
Sample:MW-5 Lab ID:92313975004 Collected:09/23/16 16:40 Received:09/28/16 08:16 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 10/02/16 22:00 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/02/16 22:00 591-78-650.0 0.46 1
Iodomethane ND ug/L 10/02/16 22:00 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 10/02/16 22:00 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/02/16 22:00 108-10-11000.33 1
Styrene ND ug/L 10/02/16 22:00 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/02/16 22:00 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 10/02/16 22:00 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 10/02/16 22:00 127-18-41.0 0.46 1
Toluene ND ug/L 10/02/16 22:00 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 10/02/16 22:00 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 10/02/16 22:00 79-00-51.0 0.29 1
Trichloroethene ND ug/L 10/02/16 22:00 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 10/02/16 22:00 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 10/02/16 22:00 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 10/02/16 22:00 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 10/02/16 22:00 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 10/02/16 22:00 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)101 %10/02/16 22:00 460-00-470-130 1
1,2-Dichloroethane-d4 (S)96 %10/02/16 22:00 17060-07-070-130 1
Toluene-d8 (S)105 %10/02/16 22:00 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/13/2016 10:34 AM
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Page 12 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92313975
PIKEVILLE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
331123
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92313975001, 92313975002, 92313975003, 92313975004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1834776
Associated Lab Samples:92313975001, 92313975002, 92313975003, 92313975004
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 10/04/16 23:213.8
Arsenic ug/L ND 10.0 10/05/16 14:422.5
Barium ug/L ND 100 10/04/16 23:212.5
Beryllium ug/L ND 1.0 10/04/16 23:210.50
Cadmium ug/L ND 1.0 10/04/16 23:210.50
Chromium ug/L ND 10.0 10/04/16 23:212.5
Cobalt ug/L ND 10.0 10/04/16 23:212.5
Copper ug/L ND 10.0 10/04/16 23:212.5
Lead ug/L ND 10.0 10/04/16 23:212.5
Nickel ug/L ND 50.0 10/04/16 23:212.5
Selenium ug/L ND 10.0 10/04/16 23:215.0
Silver ug/L ND 10.0 10/04/16 23:212.5
Thallium ug/L ND 5.5 10/04/16 23:215.0
Vanadium ug/L ND 25.0 10/04/16 23:212.5
Zinc ug/L ND 10.0 10/04/16 23:215.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1834777LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 510500 102 80-120
Arsenic ug/L 501500 100 80-120
Barium ug/L 520500 104 80-120
Beryllium ug/L 520500 104 80-120
Cadmium ug/L 522500 104 80-120
Chromium ug/L 517500 103 80-120
Cobalt ug/L 526500 105 80-120
Copper ug/L 551500 110 80-120
Lead ug/L 513500 103 80-120
Nickel ug/L 513500 103 80-120
Selenium ug/L 512500 102 80-120
Silver ug/L 257250 103 80-120
Thallium ug/L 526500 105 80-120
Vanadium ug/L 513500 103 80-120
Zinc ug/L 536500 107 80-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/13/2016 10:34 AM
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Page 13 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92313975
PIKEVILLE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1834778MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92313951024
1834779
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 98 75-12599 1 25500ND491494
Arsenic ug/L 500 102 75-125102 0 25500ND512512
Barium ug/L 500 100 75-125100 0 25500142642644
Beryllium ug/L 500 98 75-12599 0 25500ND491493
Cadmium ug/L 500 98 75-125100 2 2550015.6 506 514
Chromium ug/L 500 95 75-12596 1 25500ND478483
Cobalt ug/L 500 97 75-12598 1 25500ND486492
Copper ug/L 500 103 75-125103 0 25500ND519519
Lead ug/L 500 96 75-12596 1 25500ND481485
Nickel ug/L 500 94 75-12595 1 25500ND473480
Selenium ug/L 500 97 75-12598 1 25500ND484489
Silver ug/L 250 99 75-12599 0 25250ND247248
Thallium ug/L 500 99 75-125100 1 25500ND499505
Vanadium ug/L 500 93 75-12593 1 25500ND463467
Zinc ug/L 500 97 75-12598 1 2550012.2 495 502
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/13/2016 10:34 AM
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[phone]
Page 14 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92313975
PIKEVILLE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
331436
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92313975001, 92313975002, 92313975003, 92313975004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1836349
Associated Lab Samples:92313975001, 92313975002, 92313975003, 92313975004
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 10/02/16 14:080.33
1,1,1-Trichloroethane ug/L ND 1.0 10/02/16 14:080.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 10/02/16 14:080.40
1,1,2-Trichloroethane ug/L ND 1.0 10/02/16 14:080.29
1,1-Dichloroethane ug/L ND 5.0 10/02/16 14:080.32
1,1-Dichloroethene ug/L ND 5.0 10/02/16 14:080.56
1,2,3-Trichloropropane ug/L ND 1.0 10/02/16 14:080.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 10/02/16 14:082.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 10/02/16 14:080.27
1,2-Dichlorobenzene ug/L ND 5.0 10/02/16 14:080.30
1,2-Dichloroethane ug/L ND 1.0 10/02/16 14:080.24
1,2-Dichloropropane ug/L ND 1.0 10/02/16 14:080.27
1,4-Dichlorobenzene ug/L ND 1.0 10/02/16 14:080.33
2-Butanone (MEK)ug/L ND 100 10/02/16 14:080.96
2-Hexanone ug/L ND 50.0 10/02/16 14:080.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 10/02/16 14:080.33
Acetone ug/L ND 100 10/02/16 14:0810.0
Acrylonitrile ug/L ND 200 10/02/16 14:081.9
Benzene ug/L ND 1.0 10/02/16 14:080.25
Bromochloromethane ug/L ND 3.0 10/02/16 14:080.17
Bromodichloromethane ug/L ND 1.0 10/02/16 14:080.18
Bromoform ug/L ND 3.0 10/02/16 14:080.26
Bromomethane ug/L ND 10.0 10/02/16 14:080.29
Carbon disulfide ug/L ND 100 10/02/16 14:081.2
Carbon tetrachloride ug/L ND 1.0 10/02/16 14:080.25
Chlorobenzene ug/L ND 3.0 10/02/16 14:080.23
Chloroethane ug/L ND 10.0 10/02/16 14:080.54
Chloroform ug/L ND 5.0 10/02/16 14:080.14
Chloromethane ug/L ND 1.0 10/02/16 14:080.11
cis-1,2-Dichloroethene ug/L ND 5.0 10/02/16 14:080.19
cis-1,3-Dichloropropene ug/L ND 1.0 10/02/16 14:080.13
Dibromochloromethane ug/L ND 3.0 10/02/16 14:080.21
Dibromomethane ug/L ND 10.0 10/02/16 14:080.21
Ethylbenzene ug/L ND 1.0 10/02/16 14:080.30
Iodomethane ug/L ND 10.0 10/02/16 14:080.32
Methylene Chloride ug/L ND 1.0 10/02/16 14:080.97
Styrene ug/L ND 1.0 10/02/16 14:080.26
Tetrachloroethene ug/L ND 1.0 10/02/16 14:080.46
Toluene ug/L ND 1.0 10/02/16 14:080.26
trans-1,2-Dichloroethene ug/L ND 5.0 10/02/16 14:080.49
trans-1,3-Dichloropropene ug/L ND 1.0 10/02/16 14:080.26
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/13/2016 10:34 AM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 15 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92313975
PIKEVILLE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1836349
Associated Lab Samples:92313975001, 92313975002, 92313975003, 92313975004
Matrix:Water
AnalyzedMDL
trans-1,4-Dichloro-2-butene ug/L ND 100 10/02/16 14:081.0
Trichloroethene ug/L ND 1.0 10/02/16 14:080.47
Trichlorofluoromethane ug/L ND 1.0 10/02/16 14:080.20
Vinyl acetate ug/L ND 50.0 10/02/16 14:080.35
Vinyl chloride ug/L ND 1.0 10/02/16 14:080.62
Xylene (Total)ug/L ND 5.0 10/02/16 14:080.66
1,2-Dichloroethane-d4 (S)%97 70-130 10/02/16 14:08
4-Bromofluorobenzene (S)%102 70-130 10/02/16 14:08
Toluene-d8 (S)%104 70-130 10/02/16 14:08
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1836350LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 53.250 106 80-125
1,1,1-Trichloroethane ug/L 49.650 99 71-129
1,1,2,2-Tetrachloroethane ug/L 50.350 101 79-124
1,1,2-Trichloroethane ug/L 51.150 102 85-125
1,1-Dichloroethane ug/L 49.450 99 73-126
1,1-Dichloroethene ug/L 51.450 103 66-135
1,2,3-Trichloropropane ug/L 50.350 101 75-130
1,2-Dibromo-3-chloropropane ug/L 50.750 101 71-133
1,2-Dibromoethane (EDB)ug/L 55.450 111 83-124
1,2-Dichlorobenzene ug/L 52.650 105 80-133
1,2-Dichloroethane ug/L 47.550 95 67-128
1,2-Dichloropropane ug/L 50.450 101 75-132
1,4-Dichlorobenzene ug/L 50.850 102 78-130
2-Butanone (MEK)ug/L 102100 102 61-144
2-Hexanone ug/L 97.9100 98 68-143
4-Methyl-2-pentanone (MIBK)ug/L 102100 102 72-135
Acetone ug/L 98.7J100 99 48-146
Acrylonitrile ug/L 247250 99 40-160
Benzene ug/L 52.850 106 80-125
Bromochloromethane ug/L 50.750 101 71-125
Bromodichloromethane ug/L 51.250 102 78-124
Bromoform ug/L 45.250 90 71-128
Bromomethane ug/L 47.750 95 40-160
Carbon disulfide ug/L 51.9J50 104 50-160
Carbon tetrachloride ug/L 51.050 102 69-131
Chlorobenzene ug/L 51.350 103 81-122
Chloroethane ug/L 47.150 94 39-148
Chloroform ug/L 49.450 99 73-127
Chloromethane ug/L 55.250 110 44-146
cis-1,2-Dichloroethene ug/L 49.350 99 74-124
cis-1,3-Dichloropropene ug/L 53.750 107 72-132
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/13/2016 10:34 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92313975
PIKEVILLE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1836350LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromochloromethane ug/L 47.150 94 78-125
Dibromomethane ug/L 50.050 100 82-120
Ethylbenzene ug/L 49.850 100 79-121
Iodomethane ug/L 95.1100 95 39-154
Methylene Chloride ug/L 48.250 96 64-133
Styrene ug/L 52.450 105 84-126
Tetrachloroethene ug/L 48.150 96 78-122
Toluene ug/L 50.850 102 80-121
trans-1,2-Dichloroethene ug/L 50.350 101 71-127
trans-1,3-Dichloropropene ug/L 51.550 103 69-141
trans-1,4-Dichloro-2-butene ug/L 39.7J50 79 40-160
Trichloroethene ug/L 50.950 102 78-122
Trichlorofluoromethane ug/L 49.450 99 53-137
Vinyl acetate ug/L 114100 114 40-160
Vinyl chloride ug/L 51.150 102 58-137
Xylene (Total)ug/L 148150 99 81-126
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1836353MATRIX SPIKE SAMPLE:
MSSpike
Result
92313951026
1,1,1,2-Tetrachloroethane ug/L 21.520 108 70-130ND
1,1,1-Trichloroethane ug/L 22.820 114 70-130ND
1,1,2,2-Tetrachloroethane ug/L 20.620 103 70-130ND
1,1,2-Trichloroethane ug/L 22.420 112 70-130ND
1,1-Dichloroethane ug/L 22.420 112 70-130ND
1,1-Dichloroethene ug/L 24.020 120 70-166ND
1,2,3-Trichloropropane ug/L 21.720 108 70-130ND
1,2-Dibromo-3-chloropropane ug/L 21.920 110 70-130ND
1,2-Dibromoethane (EDB)ug/L 23.420 117 70-130ND
1,2-Dichlorobenzene ug/L 22.620 113 70-130ND
1,2-Dichloroethane ug/L 21.220 106 70-130ND
1,2-Dichloropropane ug/L 22.220 111 70-130ND
1,4-Dichlorobenzene ug/L 21.920 110 70-130ND
2-Butanone (MEK)ug/L 42.8J40 107 70-130ND
2-Hexanone ug/L 39.9J40 100 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 42.6J40 107 70-130ND
Acetone ug/L 40.1J40 93 70-130ND
Acrylonitrile ug/L 103J100 103 70-130ND
Benzene ug/L 23.520 118 70-148ND
Bromochloromethane ug/L 23.520 117 70-130ND
Bromodichloromethane ug/L 22.420 112 70-130ND
Bromoform ug/L 19.020 95 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/13/2016 10:34 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92313975
PIKEVILLE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1836353MATRIX SPIKE SAMPLE:
MSSpike
Result
92313951026
Bromomethane ug/L 19.020 95 70-130ND
Carbon disulfide ug/L 24.5J20 122 70-130ND
Carbon tetrachloride ug/L 23.620 118 70-130ND
Chlorobenzene ug/L 22.620 113 70-146ND
Chloroethane ug/L 23.020 115 70-130ND
Chloroform ug/L 22.520 112 70-130ND
Chloromethane ug/L 26.3 M12013270-130ND
cis-1,2-Dichloroethene ug/L 22.220 111 70-130ND
cis-1,3-Dichloropropene ug/L 21.620 108 70-130ND
Dibromochloromethane ug/L 19.820 99 70-130ND
Dibromomethane ug/L 22.220 111 70-130ND
Ethylbenzene ug/L 22.320 111 70-130ND
Iodomethane ug/L 36.440 91 70-130ND
Methylene Chloride ug/L 20.520 103 70-130ND
Styrene ug/L 22.220 111 70-130ND
Tetrachloroethene ug/L 20.420 102 70-130ND
Toluene ug/L 22.520 113 70-155ND
trans-1,2-Dichloroethene ug/L 23.320 117 70-130ND
trans-1,3-Dichloropropene ug/L 20.520 103 70-130ND
trans-1,4-Dichloro-2-butene ug/L 16.5J20 83 70-130ND
Trichloroethene ug/L 22.820 114 69-151ND
Trichlorofluoromethane ug/L 24.320 122 70-130ND
Vinyl acetate ug/L 38.1J40 95 70-130ND
Vinyl chloride ug/L 23.620 118 70-130ND
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92313951027
1836354SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 2.2J 6 302.3
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L 0.50J 30ND
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/13/2016 10:34 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92313975
PIKEVILLE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92313951027
1836354SAMPLE DUPLICATE:
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 1.4J 2 301.5
Chloroethane ug/L 20.4 3 3019.7
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%101 0100
4-Bromofluorobenzene (S)%103 0103
Toluene-d8 (S)%107 3104
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/13/2016 10:34 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 23
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92313975
PIKEVILLE
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/13/2016 10:34 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 23
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92313975
PIKEVILLE
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92313975001 331123 331356MW-2 EPA 3010A EPA 6010
92313975002 331123 331356MW-3 EPA 3010A EPA 6010
92313975003 331123 331356MW-4 EPA 3010A EPA 6010
92313975004 331123 331356MW-5 EPA 3010A EPA 6010
92313975001 331436MW-2 EPA 8260
92313975002 331436MW-3 EPA 8260
92313975003 331436MW-4 EPA 8260
92313975004 331436MW-5 EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/13/2016 10:34 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 23
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