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Home My WebLink About9231_BrownfieldRdCDLF_GWMR_DIN28083_20160607 Golder, Golder Associates and the GA globe design are trademarks of Golder Associates Corporation FIRST SEMI-ANNUAL 2016 SAMPLING EVENT Wake Reclamation, LLC – Brownfield Road Construction and Demolition Landfill, Permit No. 92-31 Wake County, North Carolina Submitted To: Wake Reclamation, LLC Brownfield Road C&D Landfill 2600 Brown-Field Road Raleigh, NC 27610 Submitted By: Golder Associates NC, Inc. 5B Oak Branch Drive Greensboro, NC 27407 August 2016 1239-643816.100 WA T E R Q U A L I T Y M O N I T O R I N G RE P O R T Golder Associates NC, Inc. 5B Oak Branch Drive Greensboro, NC 27407 USA Tel: (336) 852-4903 Fax: (336) 852-4904 www.golder.com Engineering Lic. No. C-2862/Geology Lic. No. C-399 Golder, Golder Associates and the GA globe design are trademarks of Golder Associates Corporation August 25, 2016 1239-643816.100 Ms. Jaclynne Drummond North Carolina Department of Environmental Quality Division of Waste Management 2090 US Highway 70 Swannanoa, NC 28778 (828) 296-4604 RE: WATER QUALITY MONITORING REPORT, FIRST SEMI-ANNUAL 2016 SAMPLING EVENT WAKE RECLAMATION, LLC, BROWNFIELD ROAD CONSTRUCTION AND DEMOLITION LANDFILL, PERMIT NO. 92-31 WAKE COUNTY, NORTH CAROLINA Dear Ms. Drummond: Golder Associates NC, Inc. (Golder) is submitting the enclosed Water Quality Monitoring Report, which documents the results of the first semi-annual compliance monitoring event at the Wake Reclamation, LLC Brownfield Road Construction and Demolition (C&D) Landfill. Personnel from Golder visited the facility on June 7 - 8, 2016, to sample monitoring wells MW-1, MW-2, MW-3, MW-4, MW-5, and MW-6As, and surface water monitoring points SW-1, SW-2, and SW-3. Wake Reclamation, LLC currently monitors groundwater at the facility for parameters listed in Title 15A NCAC 13B.0544 of the North Carolina Solid Waste Management Rules (NCSWMR). During the first semi- annual event, two NC Appendix I inorganic constituents (barium and beryllium) were detected at quantifiable concentrations above their respective Solid Waste Section Limits (SWSLs) in samples from one or more downgradient monitoring wells at the facility. The concentration of beryllium in the sample from MW-2 exceeded the Solid Waste Section Groundwater Protection Standard during the June 2016 event. An additional C&D parameter, mercury, was reported at a concentration that exceeded the SWSL and NC 2L Standard in the sample from MW-3. Indicator parameters iron and manganese were detected at concentrations above their respective SWSLs and NC 2L Standards in samples from one or more downgradient wells during this event, as they have during previous events. To determine the source of the above-standard concentrations, beryllium, mercury, iron, and manganese were statistically compared to background concentrations. The concentrations of beryllium, mercury, and iron were determined to be below the background concentrations and are interpreted to represent naturally occurring conditions. The concentrations of manganese in samples from MW-2 and MW-4 were statistically determined to be above background concentrations. Based on published soil and stream sediment metals data for Wake County and North Carolina, the manganese concentrations reported in groundwater samples from MW-2 and MW-4 were visually compared to and are within natural background concentrations. Further, the absence of leachate indicators (i.e., detections of volatile organic constituents or increasing trends for field parameter indicators) for samples from MW-2 and MW-4 do not support a leachate release from the facility. Therefore, future manganese results will continue to be monitored, and no further action is warranted at this time. Cobalt and vanadium were detected in samples from one or more downgradient wells at estimated concentrations below their SWSLs, but above their respective groundwater standards. The concentrations of cobalt and vanadium are consistent with historical background data and are interpreted to represent naturally occurring conditions, and no further action is required for these estimated concentrations. No NC Appendix I organic constituents were detected at concentrations above the SWSLs or NC 2L Standards during this event. Barium was reported at a quantifiable concentration above the SWSL, but August 2016 i 1239-643816.100 Table of Contents COVER LETTER 1.0 INTRODUCTION .............................................................................................................................. 1 1.1 Site Description and Background ................................................................................................. 1 1.2 Compliance Monitoring History .................................................................................................... 1 1.3 Hydrogeologic Setting .................................................................................................................. 2 2.0 FIELD PROGRAM, MONITORING RESULTS, AND DISCUSSION ............................................... 3 2.1 Visual Inspection Program ........................................................................................................... 3 2.2 Well Network and Groundwater Elevation Measurements .......................................................... 4 2.3 June 2016 Groundwater and Surface Water Monitoring Event ................................................... 4 2.4 Laboratory Analysis Program ....................................................................................................... 5 2.5 June 2016 Sampling Results ....................................................................................................... 5 3.0 LABORATORY AND FIELD QA/QC ................................................................................................ 6 4.0 DATA EVALUATIONS ..................................................................................................................... 6 4.1 June 2016 Groundwater and Surface Water Quality Standard Comparisons ............................. 6 4.2 June 2016 Statistical Evaluations ................................................................................................ 6 4.3 Evaluation of Manganese Concentrations ................................................................................... 7 5.0 CONCLUSIONS ............................................................................................................................... 8 6.0 REFERENCES ................................................................................................................................. 8 Tables Table 1 Summary of Historical Groundwater Elevation Data in Monitoring Wells Table 2 Summary of Estimated Horizontal Flow Velocities Table 3 Summary of Well Construction Information Table 4 Summary of Detected Constituents in Groundwater Table 5 Summary of Field Parameters from Groundwater Monitoring Points Table 6 Summary of Detected Constituents in Surface Water Table 7 Summary of Field Parameters from Surface Water Monitoring Points Figures Figure 1 Manganese and Chloride Trend Graph for MW-2 Figure 2 Manganese and pH Trend Graph for MW-2 Figure 3 Manganese and Chloride Trend Graph for MW-4 Figure 4 Manganese and pH Trend Graph for MW-4 Drawing Drawing 1 Groundwater Contour Map, June 7, 2016 Appendices Appendix A Groundwater and Surface Water Sampling Logs Appendix B June 2016 Groundwater and Surface Water Certificate-of-Analysis, Chain-of-Custody Forms, and Laboratory Data Review Appendix C Statistical Evaluation Worksheets & Summary Table Appendix D Soil and Stream Sediment Data August 2016 1 1239-643816.100 1.0 INTRODUCTION This report summarizes the monitoring results from the June 7 - 8, 2016, groundwater and surface water sampling event at the Brownfield Road Construction & Demolition (C&D) Landfill in Wake County, North Carolina (NC) in accordance with Title 15A of the North Carolina Administrative Code (NCAC) Subchapter 13B.0544. The Brownfield Road C&D Landfill, an active C&D landfill, is owned and operated by Wake Reclamation, LLC, a subsidiary of Waste Industries USA, Inc. (Waste Industries) under Permit No. 92-31 issued by the NC Department of Environmental Quality (DEQ, formally known as the NC Department of Environment and Natural Resources). 1.1 Site Description and Background The location of the facility is shown on the inlay on Drawing 1. As presented, the Brownfield Road C&D Landfill is located along Brown-Field Road near the town of Garner in Wake County, NC. The site consists of approximately 210 acres, of which, approximately 19 acres are permitted as the Phase 1 waste unit and approximately 16.7 acres are permitted as the Phase 2A waste unit. Three northwest-trending unnamed streams traverse the site to intersect a north-trending unnamed stream that parallels the western facility property line. The two smaller drainages originate at 2- to 4-acre man- made ponds. The larger stream along the property line coincides with the location of a regional-scale diabase dike. A storm water basin was constructed along the western boundary of Phase 1. Topographic surface elevations at the facility range from approximately 180 to 290 feet above mean sea level. The northern portion of the site was previously used by the City of Raleigh for land application of wastewater sludge for approximately 11 years. Some of the parcels surrounding the site are still used for this purpose. The remainder of the facility consists of wooded areas, grass, and heavy brush. 1.2 Compliance Monitoring History Groundwater monitoring at the facility was initiated in May 2002 after approval of the Groundwater Monitoring Plan by the NC DEQ. Waste was first accepted at the site in October 2003. The facility’s original monitoring network was comprised of five monitoring wells (MW-1, MW-2, MW-3, MW-4, and MW-5), which monitor the uppermost aquifer beneath the facility. In addition to the groundwater monitoring points, the facility’s original monitoring network included three surface water sampling points: SW-1, which is upstream of the waste area along the major tributary, and SW-2 and SW-3, which are downstream monitoring points relative to the waste area. A voluntary Alternate Source Demonstration (ASD) was approved by the NC DEQ Division of Waste Management, Solid Waste Section on May 15, 2008, and evaluated the source of trichlorofluoromethane in samples from MW-3. Based on the findings of the ASD, the most likely source of trichlorofluoromethane detected in samples from MW-3 is landfill gas, rather than leachate. Subsequently, a Landfill Gas Remediation Plan (LGRP) was submitted to address methane migration in the vicinity of MW-3, and was August 2016 2 1239-643816.100 approved by NC DEQ on July 1, 2010. As proposed in the LGRP, a cut-off trench was installed prior to the December 2010 monitoring event. The effectiveness of the corrective measures was to be evaluated 2 years after the installation of the cut-off trench, per the requirements of the July 1, 2010, approval letter. The evaluation was presented in the Second Semi-Annual Water Quality Monitoring Report of 2012, which determined that, based on the available data and expected groundwater travel times, it was unlikely that recent samples from MW-3 had sufficient time to reflect positive effects the cut-off trench may have on groundwater quality. In a letter dated September 16, 2013, NC DEQ approved an additional 3 years to re- evaluate groundwater quality at MW-3. The effectiveness of the cut-off trench was re-evaluated after the December 2015 semi-annual water quality monitoring event. The installation of the cut-off trench appears to have positively affected water quality in the vicinity of MW-3. Four groundwater monitoring wells (MW-6As, MW-6Ad, MW-7As, and MW-7Ad) were installed in May and June 2011 related to the Phase 2A expansion of the landfill. Background sampling of the new wells took place during the June 2011 water quality monitoring event, and was documented in the Summary of Piezometer Decommissioning, Monitoring Well and Gas Probe Installation, Monitoring Well Development, Pump Installations, and Background Sampling for Phase 2A Landfill Expansion, dated September 22, 2011. The wells were sampled as part of the monitoring network for the first time during the June 2012 routine sampling event. A letter titled “Groundwater Monitoring Network Adjustment” was submitted to NC DEQ on September 10, 2014, to request changes to the groundwater monitoring network. The proposed modifications included the removal of three monitoring wells (MW-6Ad, MW-7As, and MW-7Ad) from the current monitoring network and the elimination of three future wells (MW-8, MW-9s, and MW-9d) that were to be installed as part of the Phase 2 expansion. Approval of the request was received from NC DEQ on September 16, 2014. The existing wells removed from the monitoring network are to remain in place as groundwater depth measurement points and future monitoring locations, should conditions change (Smith Gardner 2014). 1.3 Hydrogeologic Setting Geologically, the facility is located within the southern portion of the Raleigh Belt, which is near the eastern boundary of the Piedmont Physiographic Province. The bedrock at the facility consists of the granite of the Rolesville Batholith. The granite observed at the site is predominantly a medium-grained biotite granite and biotite-muscovite granite with garnets. Northwest trending Mesozoic diabase dikes are also common in this region (Stoddard et al. 1991). A magnetometer survey was performed during the initial site investigation and revealed a regional-scale diabase dike, which is shown on the NC State Geologic Map (NCGS 1985) and coincides with the stream along the western property boundary. Smaller anomalies were also identified across the site and were interpreted to represent smaller dikes (JEI 2001). August 2016 3 1239-643816.100 The uppermost groundwater beneath the facility is present in a shallow, unconfined aquifer comprised of saprolite, partially weathered rock, and granitic bedrock (JEI 2001). Groundwater occurs at depths of approximately 25 feet below grade along the upgradient side of the waste disposal area, and at depths of approximately 10 feet below grade along the downgradient boundary. Groundwater elevations obtained during the June 2016 monitoring event, as summarized in Table 1, were used to prepare a groundwater surface contour map presented as Drawing 1. Surface water and groundwater at the site generally flow west and northwest, and discharge to the surrounding tributaries that flow into the Neuse River. Groundwater beneath the site flows in three distinguishable and vertically interconnected hydrogeologic units: saprolite, partially weathered rock, and bedrock. Based on the June 7, 2016, groundwater contour map, the average hydraulic gradient in the shallow aquifer underlying the site, as measured along the conceptual flow path shown on the contour map, was calculated to be approximately 0.025 feet per foot. Groundwater velocities were calculated using a hydraulic conductivity of 1.20E-04 centimeters per second, which is the geometric mean of the hydraulic conductivities for each of the hydrogeologic units present at the facility (JEI 2001). The estimated effective porosity of the shallow aquifer is 0.20 (Heath 1982). Using the above values, the estimated rate of groundwater flow for the uppermost aquifer beneath the facility was calculated using the following modified Darcy equation: Vgw = Ki/ne where Vgw = average linear velocity (feet per year), K = hydraulic conductivity (feet per year), i = horizontal hydraulic gradient, and ne = effective porosity. The average estimated linear groundwater flow velocity under the waste management unit is approximately 15.3 feet per year, which is consistent with previous estimates (Table 2). The range of groundwater flow is expected to vary depending on the hydrogeologic unit in which it occurs. The linear velocity equation above makes the simplified assumptions of a homogeneous and isotropic aquifer. Therefore, this equation represents a likely average value for the uppermost aquifer and does not account for heterogeneous and/or anisotropic conditions that may be present in the uppermost aquifer at the facility. 2.0 FIELD PROGRAM, MONITORING RESULTS, AND DISCUSSION Field activities conducted for the June 2016 sampling event are discussed in the following sections. 2.1 Visual Inspection Program In order to detect a potential release at the earliest indication, the visual inspection program is used by the sampling crews at the Brownfield Road C&D Landfill. This program includes physical indicators such as August 2016 4 1239-643816.100 potential water table mounding beneath the waste management unit, physical examination of any stresses in biological communities, visible signs of leachate migration (i.e., leachate seeps), unexplained changes in soil characteristics, and any other change to the environment due to the waste management unit. During the June 2016 compliance monitoring event, no physical indicators of a potential release were observed in the vicinity of the waste management area. 2.2 Well Network and Groundwater Elevation Measurements The approved network of groundwater monitoring wells at the facility consists of wells MW-1, MW-2, MW-3, MW-4, MW-5, and MW-6As; water level measurements are also collected from MW-6Ad, MW-7As, and MW-7Ad. Monitoring well construction information is summarized on Table 3, and the well locations are shown on Drawing 1. The well locations were selected to yield groundwater samples representative of the conditions in the uppermost aquifer underlying the facility and to monitor for potential releases from the landfill unit. One upstream (SW-1) and two downstream (SW-2 and SW-3) surface water monitoring points are also monitored. Monitoring well MW-1 is the facility’s background well and is located hydraulically upgradient of the waste disposal area. Monitoring wells MW-2, MW-3, MW-4, MW-5, and MW-6As are located downgradient of the waste disposal area and represent the facility’s downgradient compliance wells. Depth-to-water measurements were recorded to the nearest 0.01 foot prior to initiating groundwater purging and sampling activities. The groundwater level elevations for this event are presented in Table 1. The historical water level data are also shown on this table. As presented, the data indicate that the hydraulic head level in the uppermost aquifer beneath the facility is fairly consistent, with temporal variation from the long-term average limited to approximately 5 feet. As expected, the range in fluctuation appears to be greater in upgradient well MW-1, as this well is located in a groundwater recharge area. The range in fluctuation in compliance wells MW-2, MW-3, MW-4, MW-5, and MW-6As, which are located near groundwater discharge areas, is less, presumably due to the stabilizing effect of the hydraulic discharge boundary. 2.3 June 2016 Groundwater and Surface Water Monitoring Event Personnel from Golder visited the facility on June 7 - 8, 2016, to purge and sample monitoring wells MW-1, MW-2, MW-3, MW-4, MW-5, and MW-6As, and to sample surface water monitoring points SW-1, SW-2, and SW-3. Monitoring wells were purged and sampled using low-flow sampling techniques with dedicated bladder pumps. Measurements of temperature, pH, specific conductivity, dissolved oxygen, oxidation- reduction potential, and turbidity were recorded at approximately 3- to 5-minute intervals during the purge, depending on the purge rate. In general, the purge rate was matched to the yield of the monitoring well, as determined by continuously monitoring the depth to water, never allowing the purge rate to exceed 500 milliliters per minute. Purging was continued until stabilization was indicated by the field parameters. August 2016 5 1239-643816.100 Prior to sampling, the laboratory-supplied sample containers were prepared. Each sample container was labeled with the sample identification number, sampling personnel, date and time of sample collection, project name and number, and requested chemical analyses. The required groundwater samples were collected directly from the dedicated bladder pump discharge lines into the labeled, laboratory-supplied, pre-preserved sample containers after purging was completed based on stabilization of field parameters. The surface water samples were collected directly from the stream flow, by lowering the sample containers into the stream flow with the opening facing away from the current flow, taking care to prevent the overflow of the sample containers and to minimize sample-induced turbidity. Measurements of pH, specific conductivity, temperature, dissolved oxygen, oxidation reduction potential, and turbidity were recorded during the collection of the surface water samples. The samples were placed in a cooler on ice, under chain-of-custody control. Copies of the sampling logs are presented in Appendix A. Included in each log is a description of the sampling location and equipment, sampling method, field observations, and field parameter measurements. 2.4 Laboratory Analysis Program The June 2016 groundwater and surface water samples were shipped to Environmental Conservation Laboratories, Inc. (ENCO) of Cary, NC under chain-of-custody control for analysis. As presented, groundwater samples at the facility were analyzed for the NC Appendix I constituents plus tetrahydrofuran and several indicator parameters specific to the C&D rules effective January 1, 2007. The surface water samples at the facility were analyzed for the NC Appendix I list of constituents and tetrahydrofuran. The samples were received by the laboratory in good condition and properly preserved. 2.5 June 2016 Sampling Results Analytical results for the June 2016 groundwater samples are summarized in Table 4, and groundwater field parameters are summarized in Table 5, with available historical data. Analytical results for surface water samples are provided in Table 6, and surface water field parameters are provided in Table 7, with available historical data. The laboratory certificate-of-analysis, chain-of-custody form, and laboratory data review for the sampling event are included in Appendix B. As presented, two NC Appendix I inorganic constituents (barium and beryllium) were detected at quantifiable concentrations above their respective Solid Waste Section Limits (SWSLs) in samples from one or more downgradient monitoring wells at the facility. Indicator parameters iron, manganese, mercury, total alkalinity, chloride, and total dissolved solids were also detected at quantifiable concentrations in samples from one or more wells, as they have during previous events. No NC Appendix I organic constituents were detected at concentrations above their respective SWSLs during the June 2016 event. August 2016 6 1239-643816.100 Barium was detected at a quantifiable concentration above the SWSL in the sample from downstream surface water monitoring point SW-3. No other NC Appendix I constituents were detected in downstream surface water monitoring points at concentrations above the SWSLs during the June 2016 event. 3.0 LABORATORY AND FIELD QA/QC A field blank was collected by Golder personnel as part of the June 2016 groundwater sampling event. In addition to the field blank, a laboratory-prepared trip blank accompanied the volatile sample containers for the June 2016 sampling event to and from the laboratory. ENCO analyzed the field blank for NC Appendix I constituents plus iron, manganese, mercury and tetrahydrofuran and the trip blank for NC Appendix I organic constituents and tetrahydrofuran. A review of the laboratory data was performed by Golder personnel and is included in Appendix B. Copper and tetrahydrofuran were detected in the field blank at estimated concentrations. Based on our review, the concentrations of copper in the sample from MW-1 is considered blank-qualified. 4.0 DATA EVALUATIONS The results of the data evaluations are presented in the following sections. 4.1 June 2016 Groundwater and Surface Water Quality Standard Comparisons As presented in Table 4, beryllium was reported at a concentration above the SWSL and the Solid Waste Section’s Groundwater Protection Standard (GPS) in the sample from MW-2. Cobalt and vanadium were reported at estimated concentrations below the SWSL, but above GPSs in the samples from one or more monitoring wells during this event, as they have during previous events. No further action is warranted for the detections of cobalt and vanadium because they are estimated concentrations. Indicator parameter mercury was reported at a concentration above the SWSL and the NC 2L Standard in the sample from MW-3. Indicator parameters iron and manganese were detected above their respective SWSLs and NC 2L Standards in samples from one or more downgradient wells, as they have during previous events. No NC Appendix I organic constituents were detected at concentrations above the NC 2L Standards. Lead was reported at an estimated concentration, below the SWSL, but above the Freshwater Chronic Surface Water Standard, in the sample from downstream surface water monitoring point SW-2. Lead has been detected at similar concentrations in the upstream surface water monitoring point SW-1 and is considered naturally occurring. No other NC Appendix I constituents were detected at concentrations that exceeded applicable surface water standards in samples from surface water monitoring points during this event. 4.2 June 2016 Statistical Evaluations As presented above, beryllium in the sample from MW-2 was reported at a concentration that exceeds the SWSL and GPS during the June 2016 event. To determine the source of the exceedance, the concentration August 2016 7 1239-643816.100 was statistically evaluated and compared to the background concentration. The statistical worksheets and summary table are presented as Appendix C. As presented, the concentration of beryllium in the sample from MW-2 was determined to be below the background concentration, and is interpreted to represent naturally occurring conditions. Statistical evaluation of indicator parameters that exceeded their respective SWSLs and groundwater standards in samples from downgradient wells was also performed. These include mercury reported in the sample from MW-3, iron in the samples from MW-4 and MW-5, and manganese in the samples from MW-2, MW-4, and MW-5. The concentrations of mercury and iron were determined to be below their respective background concentrations. The concentration of manganese in the sample from MW-5 was also determined to be below the background concentration, but the concentrations of manganese in MW-2 and MW-4 were determined to exceed the background concentration. These concentration are evaluated further in the following section. 4.3 Evaluation of Manganese Concentrations Manganese and indicator parameters were graphed to identify if correlations and trends through time are evident with data collected from MW-2 (Figures 1 and 2) and MW-4 (Figures 3 and 4). The graphs in Figures 1 and 2 show that there has been an increasing trend of manganese concentrations in samples from MW-2 since the June 2013 monitoring event. Figure 1 shows that there may be some correlation between chloride and manganese trends since the increase in manganese concentrations began in June 2013. However, Figure 1 also illustrates that chloride concentrations have historically been erratic and the recent increase in chloride may not be related to the increase in manganese concentrations. Figure 2 shows there is also a poor correlation between manganese and pH trends in samples from MW-2. The graphs in Figures 3 and 4 show that there has been an increasing trend of manganese concentrations in samples from MW-4 between the June 2010 and June 2015 monitoring events. Figure 3 shows that there may be some correlation between chloride and manganese trends since the June 2013 event. However, Figure 3 also illustrates that chloride concentrations declined from December 2007 to June 2013. Further, the concentrations of chloride during the two most recent sampling events have declined and do not correlate with the manganese concentrations. Figure 4 shows there is also a poor correlation between manganese and pH trends in samples from MW-4. Chloride concentrations are present at similar concentrations in samples from other facility monitoring wells, including the upgradient well MW-1. A literature search of manganese concentrations in soils and stream sediment was conducted to provide additional evidence that the source of manganese in samples from MW-2 and MW-4 are naturally occurring. Data presented in the November 2003 United States (US) Environmental Protection Agency (EPA) document “Guidance for Developing Ecological Soil Screening Levels” indicate that manganese concentrations in NC soils represent a substantial naturally occurring source in local soil that would account for the concentrations detected in groundwater samples from MW-2 and MW-4. This document presents August 2016 8 1239-643816.100 mean soil metal background concentrations for each state, including NC, in milligrams per kilogram (mg/kg). The mean concentration of manganese in NC is 563 mg/kg (equivalent to 563,000 parts per billion [ppb]), which would account for the concentrations detected in groundwater samples from MW-2 and MW-4. The United States Geological Survey (USGS) National Geochemical Survey Database is a collection of stream sediment data from across the US. This database was used to locate 13 stream sediment samples collected between 1 to 15 miles from the Brownfield Road Landfill. Manganese concentrations from the nearby stream sediment samples ranged from 43 to 1,960 parts per million (ppm) (equivalent to 43,000 to 1,960,000 ppb), with a mean concentration of 525 ppm (equivalent to 525,000 ppb). These concentrations of manganese in sediment would account for the concentrations detected in groundwater samples from MW-2 and MW-4. Summary tables from each of the above-referenced geochemical studies are included in Appendix D for reference. Based on the soil and stream sediment metals data presented above, the manganese concentrations reported in groundwater samples from MW-2 and MW-4 are within natural background concentrations. The absence of increasing trends for leachate indicators and the absence of volatile organic constituents for samples from wells MW-2 and MW-4 do not support a leachate release from the facility. Therefore, future manganese results will continue to be monitored, and no further action is warranted at this time. 5.0 CONCLUSIONS Based on the results summarized herein, Wake Reclamation, LLC will continue monitoring this facility in accordance with the requirements of the Detection Monitoring Program for C&D Landfills as outlined in Title 15A NCAC 13B.0544. The next groundwater monitoring event is tentatively scheduled for December 2016. 6.0 REFERENCES Smith Gardner, Inc., 2014, Wake Reclamation, LLC – Brownfield Road CDLF (Permit No. 92-31); Groundwater Monitoring Network Adjustment. September 10. Golder Associates NC, Inc., 2007, Material Recovery, LLC C&D Landfill; Alternate Source Demonstration. November 5. Golder Associates NC, Inc., 2011, Material Recovery, LLC C&D Landfill; Summary of Piezometer Decommissioning, Monitoring Well and Gas Probe Installation, Monitoring Well Development, Pump Installations, and Background Sampling for Phase 2A Landfill Expansion. September 22. Heath, Ralph C., 1982, Basic Ground-Water Hydrology, USGS Water Supply Paper 2220. August 2016 9 1239-643816.100 JEI (Joyce Engineering, Inc.), 2001, Hydrogeologic Report & Groundwater Monitoring Plan; Volume One; Site Application, Section II; Material Recovery, LLC Construction and Demolition Debris Landfill, Wake County, North Carolina. NCGS (North Carolina Geologic Survey), 1985, Geologic Map of North Carolina. Stoddard, Edward F., Farrar, Stewart S., Horton, Jr. J. Wright, Butler, J. Robert and Durhan, Robert M., 1991, The Eastern Piedmont in North Carolina, in Horton, J. W., Jr., and Zullo, V.A., eds., The Geology of the Carolinas: The University of Tennessee Press, p. 59 - 78. g:\projects\waste industries\wake reclamation\groundwater\wqmr\2016 june\final\final wake_recovery_1st_semi-annual_wqmr_2015.docx TABLES August 2016 Page 1 of 1 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx Well ID TOC Elevation (ft AMSL) Date Elevation (ft AMSL) DTW (ft) Elevation (ft AMSL) DTW (ft) Elevation (ft AMSL) DTW (ft) Elevation (ft AMSL) DTW (ft) Elevation (ft AMSL) DTW (ft) Elevation (ft AMSL) DTW (ft) Elevation (ft AMSL) DTW (ft) Elevation (ft AMSL) DTW (ft) Elevation (ft AMSL) DTW (ft) 08/07/02 252.13 27.97 195.39 18.00 191.02 27.41 186.53 15.09 191.82 11.56 ----------------06/16/03 257.44 22.66 197.12 16.27 194.98 23.45 191.82 9.80 193.45 9.93 ---------------- 12/01/03 257.32 22.78 197.57 15.82 195.51 22.92 191.98 9.64 194.13 9.25 ----------------06/10/04 256.32 23.78 196.91 16.48 194.43 24.00 191.22 10.40 193.43 9.95 ----------------12/16/04 255.86 24.24 196.87 16.52 193.82 24.61 190.80 10.82 193.38 10.00 ---------------- 06/05/05 255.88 24.22 196.42 16.97 193.3 25.13 190.23 11.39 193.01 10.37 ----------------12/27/05 253.25 26.85 196.18 17.21 191.53 26.90 189.94 11.68 193.38 10.00 ----------------06/21/06 253.13 26.97 196.29 17.10 191.96 26.47 189.67 11.95 193.18 10.20 ---------------- 12/01/06 252.26 27.84 196.45 16.94 191.72 26.71 189.54 12.08 193.67 9.71 ---------------- 06/28/07 253.26 26.84 196.31 17.08 192.10 26.33 189.42 12.20 192.83 10.55 ----------------12/13/07 250.67 29.43 195.91 17.48 190.70 27.73 188.02 13.60 192.52 10.86 ---------------- 06/19/08 251.07 29.03 195.88 17.51 191.84 26.59 190.01 11.61 192.46 10.92 ---------------- 12/02/08 249.53 30.57 195.88 17.51 190.64 27.79 190.00 11.62 193.09 10.29 ----------------01/23/09 --------191.14 27.29 ------------------------ 06/11/09 252.09 28.01 196.17 17.22 191.81 26.62 190.40 11.22 193.38 10.00 ---------------- 12/10/09 251.84 28.26 196.39 17.00 191.31 27.12 191.55 10.07 194.82 8.56 ----------------06/15/10 255.14 24.96 196.13 17.26 192.40 26.03 191.20 10.42 193.37 10.01 ----------------12/09/10 253.59 26.51 196.00 17.39 191.23 27.20 189.77 11.85 192.56 10.82 ---------------- 06/15/11 253.20 26.90 195.81 17.58 191.22 27.21 190.14 11.48 192.57 10.81 206.81 9.41 206.88 8.56 223.62 13.37 223.54 12.4412/06/11 251.15 28.95 195.84 17.55 190.51 27.92 188.97 12.65 192.60 10.78 206.51 9.71 206.26 9.18 224.11 12.88 224.16 11.8206/14/12 251.38 28.72 195.88 17.51 191.13 27.30 189.89 11.73 192.57 10.81 207.10 9.12 206.85 8.59 224.39 12.60 224.51 11.47 12/03/12 250.34 29.76 195.81 17.58 190.53 27.90 188.71 12.91 192.37 11.01 206.37 9.85 206.13 9.31 223.97 13.02 224.09 11.8906/11/13 251.45 28.65 196.53 16.86 191.63 26.80 190.20 11.42 194.19 9.19 208.12 8.10 207.56 7.88 226.42 10.57 226.21 9.7712/02/13 252.30 27.80 195.85 17.54 191.00 27.43 189.21 12.41 192.61 10.77 207.04 9.18 206.79 8.65 224.22 12.77 224.12 11.86 06/10/14 254.61 25.49 196.02 17.37 192.56 25.87 190.28 11.34 192.56 10.82 207.51 8.71 207.57 7.87 223.59 13.40 223.73 12.2512/03/14 254.59 25.51 196.07 17.32 191.58 26.85 190.39 11.23 193.01 10.37 207.59 8.63 ------------06/08/15 256.45 23.65 196.09 17.30 192.62 25.81 190.49 11.13 192.58 10.80 207.71 8.51 207.49 7.95 224.23 12.76 224.32 11.66 12/02/15 254.96 25.14 196.01 17.38 191.43 27.00 192.53 9.09 193.98 9.40 207.41 8.81 207.14 8.3 224.77 12.22 224.80 11.1806/07/16 256.43 23.67 195.89 17.50 192.19 26.24 191.86 9.76 192.86 10.52 207.41 8.81 207.32 8.12 223.76 13.23 223.88 12.1MEAN253.49 26.61 196.20 17.19 191.99 26.44 190.17 11.45 193.09 10.30 207.23 8.99 207.00 8.44 224.31 12.68 224.34 11.64 MAXIMUM 257.44 30.57 197.57 18.00 195.51 27.92 192.53 15.09 194.82 11.56 208.12 9.85 207.57 9.31 226.42 13.40 226.21 12.44MINIMUM249.53 22.66 195.39 15.82 190.51 22.92 186.53 9.09 191.82 8.56 206.37 8.10 206.13 7.87 223.59 10.57 223.54 9.77 Notes: TOC = Top of casingft AMSL = Feet above mean sea level DTW = Depth to water (as measured from TOC) 1)Monitoring well MW-1 is the facility background well.2)Groundwater monitoring wells were re-surveyed by Survey Solutions, PC prior to the June 2014 monitoring event 235.98236.99 MW-7AsMW-6Ad 215.44 MW-7AdMW-4 201.62 MW-5 203.38 MW-6As 216.22 MW-1 280.10 213.39 MW-3MW-2 218.43 TABLE 1 Wake County, North CarolinaBrownfield Road Construction and Demolition Landfill, Permit No. 92-31 Summary of Historical Groundwater Elevation Data in Monitoring Wells August 2016 Page 1 of 1 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx Gradient Calculation Segment Flow Direction Gradient Segment Length (feet) Gradient Segment Elevations (feet) Horizontal Gradient (i, feet/feet) Effective Porosity (ne) Hydraulic Conductivity (K, cm/sec) Velocity (Vgw, feet/year) 230 200 250 190 230 200 Notes: 1)Horizontal velocities based on the modified Darcy equation Vgw = Ki/ne. 2)The geometric mean of K from individual well aquifer tests was used to calculate the hydraulic conductivity (tests conducted by Joyce Engineering Inc. as part of the Site Application, 2001). 3)An effective porosity of 20% was used in velocity calculations. 14.29 NNW 1224 1137 TABLE 2 Summary of Estimated Horizontal Flow Velocities Brownfield Road Construction and Demolition Landfill, Permit No. 92-31 June 2015 Wake County, North Carolina i 1 i 2 i 3 0.0264 15.21 16.38 0.20 0.20 1.20E-04 1.20E-04 0.0245NW NW 2606 0.0230 0.20 1.20E-04 August 2016 Page 1 of 1 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx from to from to MW-1 08/22/01 2 712426.22 2148023.74 277.26 280.10 49.0 229.17 4 273.26 24.0 49.0 254.17 229.17 Saprolite Compliance Well MW-2 08/02/02 2 714497.25 2147102.88 210.41 213.39 35.0 175.41 8.5 201.91 19.5 34.5 190.91 175.91 Saprolite/PWR Compliance Well MW-3 07/31/02 2 714622.99 2146546.20 216.05 218.43 34.5 181.55 13.5 202.55 19.0 34.0 197.05 182.05 Saprolite/PWR Compliance Well MW-4 8/1/2002 2 714384.58 2146091.68 199.02 201.62 27.0 172.02 7 192.02 11.5 26.5 187.52 172.52 Saprolite/PWR Compliance Well MW-5 8/1/2002 2 713725.44 2146088.95 200.72 203.38 24.0 176.72 3.0 197.72 8.5 23.5 192.22 177.22 Saprolite/PWR Compliance Well MW-6As 05/11/11 2 713227.04 2146252.22 213.66 216.22 16.0 229.17 >16 <197.72 5.0 15.0 208.66 198.66 Saprolite/PWR Compliance Well MW-6Ad 06/01/11 2 713224.61 2146246.34 213.05 215.44 57.0 156.05 20 193.05 47.0 57.0 166.05 156.05 Bedrock Water Levels Only MW-7As 05/11/11 2 712908.67 2147005.19 234.32 236.99 34.0 200.32 >34 <200.32 9.0 24.0 225.32 210.32 PWR Water Levels Only MW-7Ad 05/31/11 2 712908.43 2146993.33 234.12 235.98 48.0 186.12 38 196.12 38.0 48.0 196.12 186.12 Bedrock Water Levels Only Notes: AMSL = Above mean sea level BGS = Below ground surface TOC = Top of casing PWR = Partially weathered rock 1)All elevations are referenced to mean sea level (MSL); depths are referenced to ground surface (GS) 2)MW-1 was originally installed as P-4. 3)Groundwater monitoring wells were re-surveyed by Survey Solutions, PC prior to the June 2014 monitoring event. 4)NC DENR approved request on 09/16/14 to discontinue monitoring of wells MW-6Ad, MW-7As, and MW-7Ad. Lithology of Screened IntervalTOC Well Elevations ft AMSL TOP OF BEDROCK Depth (ft BGS) Total Depth Drilled Elevation (ft AMSL) Ground Surface TABLE 3 Summary of Well Construction Information Brownfield Road Construction and Demolition Landfill, Permit No. 92-31 Wake County, North Carolina Status Screened IntervalWell & Piezometer Number Date Installed Depth (ft BGS) Elevation (ft AMSL) DEPTH (feet B.G.S.) ELEV. (feet M.S.L.) Coordinates Northing Easting Casing Diameter (inches) August 2016 Page 1 of 10 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx Blanks MW-1 MW-2 MW-3 MW-4 MW-5 MW-6As Antimony ug/L 05/07/02 --30 ------------ND SWS GPS = 1 ug/L ug/L 08/07/02 --30 -------------- EPA MCL = 6 ug/L ug/L 06/29/07 0.68 6 ND ND ND ND ND --ND ug/L 12/13/07 0.68 6 ND ND ND ND ND --ND ug/L 06/19/08 0.68 6 ND ND ND ND ND --ND ug/L 12/02/08 0.68 6 ND ND ND ND ND --ND ug/L 06/11/09 0.68 6 ND ND ND 1.05 J ND --ND `ug/L 12/10/09 0.0730 6 ND ND ND ND ND --ND ug/L 06/15/10 0.220 6 ND ND ND ND ND --ND ug/L 12/09/10 0.220 6 ND ND 0.276 J ND ND --ND ug/L 06/15/11 0.220 6 ND ND ND ND ND ND ND ug/L 12/06/11 0.220 6 0.267 J ND ND ND ND --ND ug/L 06/14/12 0.220 6 0.561 J 1.05 J 0.769 J ND ND ND ND ug/L 12/03/12 0.220 6 ND ND 0.351 J ND ND ND ND ug/L 06/11/13 0.220 6 0.267 J 0.753 J ND ND 0.414 J ND ND ug/L 12/02/13 0.220 6 ND ND ND ND ND ND ND ug/L 06/10/14 0.220 6 ND ND ND ND ND ND ND ug/L 12/03/14 0.220 6 ND 0.695 J ND ND ND ND ND ug/L 06/08/15 0.220 6 ND 0.973 J ND ND ND ND ND ug/L 12/02/15 0.220 6 0.875 J 0.802 J 0.386 J ND ND 0.295 J ND ug/L 06/07/16 0.220 6 ND ND ND ND ND ND ND Arsenic ug/L 08/07/02 --10 ND ND ND ND ND --ND NC 2L = 10 ug/L ug/L 06/16/03 --10 ND ND ND ND ND --ND EPA MCL = 10 ug/L ug/L 12/16/03 --10 ND ND ND ND ND --ND ug/L 06/16/04 --10 ND ND ND ND ND --ND ug/L 12/16/04 --10 ND ND ND ND ND --ND ug/L 06/14/05 --10 ND ND ND ND ND --ND ug/L 12/27/05 --10 ND ND ND ND ND --ND ug/L 06/21/06 --10 ND ND ND ND ND --ND ug/L 12/13/06 2 10 3.2 B 3.8 B 9.2 B 3.0 B 4.0 B --3.5 J ug/L 06/29/07 3.6 10 ND ND 4.7 J ND ND --ND ug/L 12/13/07 2 10 2.2 B ND 4.6 B ND 2.2 B --2.5 J ug/L 06/19/08 2 10 ND ND 4.1 J ND ND --ND ug/L 12/02/08 2.8 10 ND ND ND ND ND --ND ug/L 06/11/09 2.8 10 4.4 B ND 5.4 B ND ND --3.5 J ug/L 12/10/09 2.80 10 ND ND 5.01 J ND 3.75 --ND ug/L 06/15/10 2.80 10 ND 3.60 J ND ND ND --ND ug/L 12/09/10 2.80 10 ND ND 3.28 J ND ND --ND ug/L 06/15/11 2.80 10 3.39 J ND ND ND 4.64 ND ND ug/L 12/06/11 2.80 10 ND ND ND ND ND --ND ug/L 06/14/12 2.80 10 2.90 J ND ND ND ND ND ND ug/L 12/03/12 2.80 10 ND ND ND ND ND ND ND ug/L 06/11/13 5.40 10 ND ND ND ND ND ND ND ug/L 12/02/13 5.40 10 ND ND ND ND ND ND ND ug/L 06/10/14 5.40 10 ND ND ND ND ND ND ND ug/L 12/03/14 5.40 10 ND ND ND ND ND ND ND ug/L 06/08/15 5.40 10 ND ND ND ND ND ND ND ug/L 12/02/15 5.40 10 ND ND ND ND ND ND 9.10 J ug/L 06/07/16 5.40 10 ND ND ND ND ND ND ND Barium ug/L 08/07/02 --500 ND ND 4000 ND ND --ND NC 2L = 700 ug/L ug/L 06/16/03 --500 ND ND 3100 ND ND --ND EPA MCL = 2000 ug/L ug/L 12/16/03 --500 160 420 1200 120 120 --ND (dissolved)ug/L 12/16/03 --500 ----1000 -------- ug/L 06/16/04 --500 ND 540 1500 ND ND --ND (dissolved)ug/L 06/16/04 --500 ----1400 -------- ug/L 12/16/04 --500 ND 570 3100 ND ND --ND ug/L 06/14/05 --500 ND 520 2600 ND ND --ND (dissolved)ug/L 06/14/05 --500 ----2700 -------- ug/L 12/27/05 --500 ND 640 5700 ND ND --ND (dissolved)ug/L 12/27/05 --500 ----5900 -------- ug/L 06/21/06 --500 ND 708 4690 ND ND --ND (dissolved)ug/L 06/21/06 --500 ----4990 -------- ug/L 12/13/06 0.2 100 217 681 6510 121 136 --0.4 J (dissolved)ug/L 12/13/06 0.2 100 ----6860 -------- ug/L 06/29/07 1 100 269 628 3140 99.5 J 42.1 B --10.4 J (dissolved)ug/L 06/29/07 1 100 ----4160 -------- ug/L 12/13/07 0.2 100 417 697 5640 147 47.0 --0.30 J ug/L 06/19/08 0.2 100 426 623 3750 123 38.6 --ND ug/L 12/02/08 1 100 488 565 3130 109 40.3 --ND ug/L 06/11/09 4.20 100 502 607 2380 94.2 J 45.2 --ND ug/L 12/10/09 1.00 100 489 544 1970 99.9 J 36.0 --ND ug/L 06/15/10 1.00 100 359 560 1100 130 29.2 --ND ug/L 12/09/10 1.00 100 433 650 987 151 41.3 --1.72 J ug/L 06/15/11 1.00 100 447 597 1170 110 37.4 32.5 J ND ug/L 12/06/11 1.00 100 521 487 1330 155 59.8 --ND ug/L 06/14/12 1.00 100 499 496 949 117 49.3 J 61.4 J ND ug/L 12/03/12 1.00 100 456 441 1100 144 34.3 J 45.6 J ND ug/L 06/11/13 1.00 100 430 464 899 124 39.7 J 27.0 J 4.59 J ug/L 12/02/13 1.00 100 347 474 726 147 38.0 J 27.8 J ND ug/L 06/10/14 1.00 100 224 530 510 114 38.9 J 18.6 J ND ug/L 12/03/14 1.00 100 236 572 417 162 40.8 J 19.2 J ND ug/L 06/08/15 1.00 100 217 518 291 179 50.6 J 21.4 J ND ug/L 12/02/15 1.00 100 222 473 277 160 41.7 J 23.5 J 3.35 J ug/L 06/07/16 1.00 100 210 182 252 146 47.4 J 15.5 J ND Parameter Reporting Units Date MDL TABLE 4 Summary of Detected Constituents in Groundwater Brownfield Road Construction and Demolition Landfill, Permit No. 92-31 Wake County, North Carolina SWS Reporting Limit Upgradient Downgradient August 2016 Page 2 of 10 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx Blanks MW-1 MW-2 MW-3 MW-4 MW-5 MW-6AsParameterReporting Units Date MDL TABLE 4 Summary of Detected Constituents in Groundwater Brownfield Road Construction and Demolition Landfill, Permit No. 92-31 Wake County, North Carolina SWS Reporting Limit Upgradient Downgradient Beryllium ug/L 06/29/07 0.19 1 ND 3.50 5.90 1.00 0.80 --ND SWS GPS = 4 ug/L ug/L 12/13/07 0.7 1 ND 3.00 10.8 1.00 1.00 --ND EPA MCL = 4 ug/L ug/L 06/19/08 0.7 1 ND 3.50 7.60 1.00 0.80 --ND ug/L 12/02/08 0.1 1 0.40 J 2.80 6.70 0.90 J 1.00 --ND ug/L 06/11/09 0.08 1 1.04 4.02 5.82 1.04 2.03 --0.08 J ug/L 12/10/09 0.100 1 0.633 J 3.31 4.83 0.931 J 0.895 --ND ug/L 06/15/10 0.100 1 0.435 J 4.03 2.73 1.04 0.597 --ND ug/L 12/09/10 0.100 1 0.531 J 3.55 2.41 1.60 1.37 --ND ug/L 06/15/11 0.100 1 0.592 J 4.04 2.95 1.26 0.757 0.177 J ND ug/L 12/06/11 0.100 1 0.585 J 3.22 3.35 1.73 4.75 --ND (dissolved)ug/L 12/06/11 0.100 ----------0.287 --ND ug/L 06/14/12 0.100 1 0.609 J 3.61 2.47 1.36 2.41 1.00 ND ug/L 12/03/12 0.100 1 0.622 J 3.16 3.04 1.89 0.927 J 0.729 J ND ug/L 06/11/13 0.100 1 0.536 J 3.96 2.31 1.43 2.08 0.552 J ND ug/L 12/02/13 0.100 1 0.479 J 3.75 1.97 1.74 1.27 1.10 ND ug/L 06/10/14 0.100 1 0.305 J 4.45 1.34 1.30 1.24 0.737 J ND ug/L 12/03/14 0.100 1 0.313 J 4.44 1.11 1.85 0.937 J 1.04 ND ug/L 06/08/15 0.100 1 0.284 J 4.44 0.710 J 1.80 4.29 0.756 J ND (dissolved)ug/L 06/08/15 0.100 1 --------0.276 J ---- ug/L 12/02/15 0.100 1 0.309 J 4.38 0.666 J 1.75 1.69 1.09 ND ug/L 06/07/16 0.100 1 0.293 J 4.63 0.658 J 1.73 3.12 0.936 J ND Cadmium ug/L 05/07/02 --1 ------------ND NC 2L = 2 ug/L ug/L 08/07/02 --1 1.4 1.1 1.8 1.2 1.0 --ND EPA MCL = 5 ug/L ug/L 06/16/03 --1 1.2 1.1 1.7 1.8 3.4 --ND ug/L 12/16/03 --1 ND 1.3 ND ND ND --ND ug/L 06/16/04 --1 ND ND ND ND ND --ND ug/L 12/16/04 --1 ND ND ND ND 1.1 --ND ug/L 06/14/05 --1 ND ND ND ND ND --ND ug/L 12/27/05 --1 ND ND ND ND ND --ND ug/L 06/21/06 --1 ND ND ND ND ND --ND ug/L 12/13/06 0.5 1 ND ND 0.50 J ND ND --ND ug/L 06/29/07 0.38 1 ND ND 0.50 J ND ND --ND ug/L 12/13/07 0.5 1 ND ND ND ND ND --ND ug/L 06/19/08 0.5 1 ND ND ND ND ND --ND ug/L 12/02/08 0.36 1 ND ND ND ND ND --ND ug/L 06/11/09 0.09 1 0.26 J 0.36 J 0.58 J 0.19 J 0.34 --ND ug/L 12/10/09 0.360 1 ND ND 0.516 J ND ND --ND ug/L 06/15/10 0.360 1 ND ND ND ND ND --ND ug/L 12/09/10 0.360 1 ND ND 0.523 J ND ND --ND ug/L 06/15/11 0.360 1 ND ND ND ND ND ND ND ug/L 12/06/11 0.360 1 ND ND ND ND ND --ND ug/L 06/14/12 0.360 1 ND ND ND ND ND ND ND ug/L 12/03/12 0.360 1 ND ND 0.397 J ND ND ND ND ug/L 06/11/13 0.360 1 ND ND ND ND ND 0.448 J ND ug/L 12/02/13 0.360 1 ND 0.442 J ND ND ND ND ND ug/L 06/10/14 0.360 1 ND 0.417 J 2.06 (1.96)0.460 J ND ND ND ug/L 12/03/14 0.360 1 ND ND ND ND ND ND ND ug/L 06/08/15 0.360 1 ND ND ND ND ND ND ND ug/L 12/02/15 0.360 1 ND 0.394 J ND ND ND ND ND ug/L 06/07/16 0.360 1 ND ND ND ND ND ND ND Chromium ug/L 08/07/02 --10 ND ND ND ND ND --ND NC 2L = 10 ug/L ug/L 06/16/03 --10 ND ND ND ND ND --ND EPA MCL = 100 ug/L ug/L 12/16/03 --10 ND ND ND ND ND --ND ug/L 06/16/04 --10 ND ND ND ND ND --ND ug/L 12/16/04 --10 ND ND ND ND ND --ND ug/L 06/14/05 --10 ND ND ND ND ND --ND ug/L 12/27/05 --10 ND ND ND ND 15 --ND ug/L 06/21/06 --10 ND ND ND ND ND --ND ug/L 12/13/06 2 10 ND ND ND ND ND --ND ug/L 06/29/07 1.7 10 ND ND ND ND ND --ND ug/L 12/13/07 2 10 ND ND ND ND ND --ND ug/L 06/19/08 2 10 ND ND ND ND ND --ND ug/L 12/02/08 1 10 ND ND ND ND ND --ND ug/L 06/11/09 0.7 10 2.4 J 1.1 J ND ND ND --ND ug/L 12/10/09 1.00 10 ND ND ND ND ND --ND ug/L 06/15/10 1.00 10 1.79 J ND ND ND ND --ND ug/L 12/09/10 1.00 10 1.04 J ND 1.89 J ND ND --ND ug/L 06/15/11 1.00 10 ND ND ND ND ND 1.33 J ND ug/L 12/06/11 1.00 10 ND ND ND ND 2.12 --ND ug/L 06/14/12 1.00 10 ND ND ND ND 1.82 J 2.17 J ND ug/L 12/03/12 1.00 10 ND ND ND ND ND 1.24 J ND (dissolved)ug/L 12/03/12 1.00 10 ------------ND ug/L 06/11/13 1.40 10 ND ND ND ND ND ND ND ug/L 12/02/13 1.40 10 ND ND ND ND ND ND ND ug/L 06/10/14 1.40 10 ND ND ND ND ND ND ND ug/L 12/03/14 1.40 10 ND ND ND ND ND ND ND ug/L 06/08/15 1.40 10 ND ND ND ND ND ND ND ug/L 12/02/15 1.40 10 ND ND ND ND 2.36 J ND ND ug/L 06/07/16 1.40 10 ND ND ND ND ND ND ND August 2016 Page 3 of 10 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx Blanks MW-1 MW-2 MW-3 MW-4 MW-5 MW-6AsParameterReporting Units Date MDL TABLE 4 Summary of Detected Constituents in Groundwater Brownfield Road Construction and Demolition Landfill, Permit No. 92-31 Wake County, North Carolina SWS Reporting Limit Upgradient Downgradient Cobalt ug/L 06/29/07 2.5 10 5.8 J ND 6.3 J ND ND --ND SWS GPS = 1 ug/L ug/L 12/13/07 2 10 6.3 J ND 6.5 J ND ND --ND No EPA MCL ug/L 06/19/08 2 10 6.1 J ND 7.0 J ND ND --ND ug/L 12/02/08 1.1 10 4.7 J ND 3.9 J ND ND --ND ug/L 06/11/09 0.6 10 7.5 J ND 2.3 J ND 1.4 --ND ug/L 12/10/09 1.10 10 5.84 J ND 2.19 J ND 1.25 --ND ug/L 06/15/10 1.10 10 5.84 J ND ND ND ND --ND ug/L 12/09/10 1.10 10 6.64 J ND 1.87 J ND 1.40 --ND ug/L 06/15/11 1.10 10 6.17 J ND 1.50 J ND ND 1.65 J ND ug/L 12/06/11 1.10 10 5.39 J ND 1.16 J ND 1.79 --ND ug/L 06/14/12 1.10 10 5.21 J ND 2.89 J ND 1.39 J ND ND ug/L 12/03/12 1.10 10 5.32 J ND 2.17 J ND 1.46 J ND ND ug/L 06/11/13 1.10 10 4.53 J ND 2.91 J ND 1.67 J ND ND ug/L 12/02/13 1.10 10 4.33 J ND 2.76 J ND ND ND ND ug/L 06/10/14 1.10 10 3.52 J ND 2.48 J ND 1.19 J ND ND ug/L 12/03/14 1.10 10 3.60 J ND 2.76 J 1.17 J ND ND ND ug/L 06/08/15 1.10 10 5.51 J ND 2.29 J 2.03 J 2.01 J 1.47 J ND ug/L 12/02/15 1.10 10 5.65 J ND 2.24 J 3.26 J 1.24 J ND ND ug/L 06/07/16 1.10 10 6.39 J ND 1.53 J 3.55 J 1.56 J ND ND Copper ug/L 08/07/02 --0.05 ND ND ND ND ND --ND NC 2L = 1000 ug/L ug/L 06/29/07 1.8 10 ND ND 2.0 J ND ND --ND EPA MCL = 1300 ug/L#ug/L 12/13/07 0.6 10 13.6 ND 1.40 J 0.80 J 2.20 --ND ug/L 06/19/08 0.6 10 6.30 B ND 1.30 B 10.5 ND --1.30 J ug/L 12/02/08 1.6 10 13.1 ND ND ND ND --ND ug/L 06/11/09 0.81 10 13.9 ND ND 1.20 J 3.59 --ND ug/L 12/10/09 1.60 10 3.62 J ND ND ND ND --ND ug/L 06/15/10 1.60 10 3.99 J ND ND ND ND --ND ug/L 12/09/10 1.60 10 4.23 J ND ND ND 1.87 --ND ug/L 06/15/11 1.60 10 3.18 J ND ND 1.70 J ND ND ND ug/L 12/06/11 1.60 10 2.48 J ND ND ND 7.00 J --ND ug/L 06/14/12 1.60 10 3.18 J ND ND ND 4.52 J 2.85 J ND ug/L 12/03/12 1.60 10 ND ND ND ND ND ND ND ug/L 06/11/13 1.60 10 3.13 J 1.69 J ND ND ND ND ND ug/L 12/02/13 1.60 10 2.36 J 4.30 J ND ND ND ND ND ug/L 06/10/14 1.60 10 1.82 J ND 2.09 J ND ND ND ND ug/L 12/03/14 1.60 10 ND ND ND ND ND ND ND ug/L 06/08/15 1.60 10 2.85 B ND 2.02 B 18.6 3.92 B ND 3.34 J ug/L 12/02/15 1.60 10 ND ND ND ND ND ND 4.56 J ug/L 06/07/16 1.60 10 2.00 B ND ND ND ND ND 1.87 J Lead ug/L 08/07/02 --10 ND ND ND ND 19 --ND NC 2L = 15 ug/L ug/L 06/16/03 --10 ND ND ND ND 21 --ND EPA MCL = 15 ug/L#ug/L 12/16/03 --10 ND ND ND ND 34 --ND (dissolved)ug/L 12/16/03 --10 --------ND ---- ug/L 06/16/04 --10 ND ND ND ND 15 --ND (dissolved)ug/L 06/16/04 --10 --------ND ---- ug/L 12/16/04 --10 ND ND ND ND 62 --ND ug/L 06/14/05 --10 ND ND ND ND 92 --ND (dissolved)ug/L 06/14/05 --10 --------ND ---- ug/L 12/27/05 --10 ND ND ND ND 81 --ND (dissolved)ug/L 12/27/05 --10 --------ND ---- ug/L 06/21/06 --10 ND ND ND ND 33.4 --ND (dissolved)ug/L 06/21/06 --10 --------ND ---- ug/L 12/13/06 2 10 2.7 J ND 4.6 J 2.5 J 44.0 --ND (dissolved)ug/L 12/13/06 2 10 --------3.5 ---- ug/L 06/29/07 3.1 10 ND ND ND ND ND --ND (dissolved)ug/L 06/29/07 3.1 10 --------ND ---- ug/L 12/13/07 2 10 ND ND ND ND 2.4 --ND ug/L 06/19/08 2 10 2.7 J ND 3.0 J ND ND --ND ug/L 12/02/08 1.9 10 3.4 J ND ND ND ND --ND ug/L 06/11/09 1.6 10 5.2 J 2.4 J 3.5 J 2.4 J 5.1 --ND ug/L 12/10/09 1.90 10 ND ND ND ND ND --ND ug/L 06/15/10 1.90 10 ND ND ND ND ND --ND ug/L 12/09/10 1.90 10 ND ND ND ND ND --ND ug/L 06/15/11 1.90 10 2.23 J ND ND ND 3.12 1.97 J ND ug/L 12/06/11 1.90 10 ND ND ND ND 8.99 --ND ug/L 06/14/12 1.90 10 ND ND ND ND 5.50 J ND ND ug/L 12/03/12 1.90 10 ND ND ND ND ND ND ND (dissolved)ug/L 12/03/12 --10 ------------ND ug/L 06/11/13 2.10 10 ND ND ND ND ND ND ND ug/L 12/02/13 2.10 10 ND ND ND ND ND ND ND ug/L 06/10/14 2.10 10 ND 2.55 J 2.27 J ND 3.05 J ND ND ug/L 12/03/14 2.10 10 ND ND ND ND ND ND ND ug/L 06/08/15 2.10 10 ND ND ND ND 5.99 J ND ND ug/L 12/02/15 2.10 10 ND ND ND ND ND ND ND ug/L 06/07/16 2.10 10 ND ND ND ND 6.57 J ND ND August 2016 Page 4 of 10 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx Blanks MW-1 MW-2 MW-3 MW-4 MW-5 MW-6AsParameterReporting Units Date MDL TABLE 4 Summary of Detected Constituents in Groundwater Brownfield Road Construction and Demolition Landfill, Permit No. 92-31 Wake County, North Carolina SWS Reporting Limit Upgradient Downgradient Mercury ug/L 08/07/02 --0.5 ND ND ND ND ND --ND NC 2L = 1 ug/L ug/L 06/16/03 --0.5 ND ND ND ND ND --ND EPA MCL = 2 ug/L ug/L 12/16/03 --0.5 ND ND ND ND ND --ND ug/L 06/16/04 --0.5 ND ND ND ND ND --ND ug/L 12/16/04 --0.5 ND ND ND ND ND --ND ug/L 06/14/05 --0.5 ND ND ND ND ND --ND ug/L 12/27/05 --0.5 ND ND ND ND ND --ND ug/L 06/21/06 --2 ND ND ND ND ND --ND ug/L 12/13/06 0.11 0.2 ND ND ND ND ND --ND ug/L 06/29/07 0.11 0.2 ND ND 2.24 ND ND --ND ug/L 08/09/07 0.11 0.2 ----1.30 ------ND ug/L 12/13/07 0.11 0.2 ND ND ND ND ND --ND ug/L 06/19/08 0.11 0.2 ND ND 0.58 0.12 J ND --ND ug/L 12/02/08 0.11 0.2 ND ND 0.59 ND ND --ND ug/L 06/11/09 0.05 0.2 ND ND 0.75 0.07 J ND --ND ug/L 12/10/09 0.0540 0.2 ND ND 1.03 0.113 J ND --ND ug/L 06/15/10 0.170 0.2 0.201 ND 1.53 ND ND --ND ug/L 12/09/10 0.170 0.2 ND ND 0.848 ND ND --ND ug/L 06/15/11 0.170 0.2 ND ND 0.768 ND ND ND ND ug/L 12/06/11 0.170 0.2 ND ND 1.03 ND ND --ND ug/L 06/14/12 0.170 0.2 ND ND 0.621 ND ND ND ND ug/L 12/03/12 0.170 0.2 ND ND 0.729 ND ND ND ND ug/L 06/11/13 0.170 0.2 ND ND 0.759 ND ND ND ND ug/L 12/02/13 0.170 0.2 ND 1.36 0.540 ND ND ND ND Verification Event ug/L 01/09/14 0.170 0.2 --ND --------ND ug/L 06/10/14 0.170 0.2 ND ND 0.667 ND ND ND ND ug/L 12/03/14 0.170 0.2 ND ND 0.604 ND ND ND ND ug/L 06/08/15 0.170 0.2 0.262 0.218 0.725 0.219 ND ND ND ug/L 12/02/15 0.170 0.2 0.192 J ND 1.18 ND ND ND ND ug/L 06/07/16 0.170 0.2 ND ND 1.94 ND ND ND ND Nickel ug/L 08/07/02 --50 ND ND ND ND ND --ND NC 2L = 100 ug/L ug/L 06/29/07 1.3 50 ND ND ND ND ND --ND No EPA MCL ug/L 12/13/07 2 50 3.4 J ND 8.0 J 4.0 J 2.3 --ND ug/L 06/19/08 2 50 ND ND ND 2.1 J ND --ND ug/L 12/02/08 1.8 50 ND ND ND ND ND --ND ug/L 06/11/09 0.6 50 2.3 J 0.7 J 2.1 J 1.5 J 1.2 --ND ug/L 12/10/09 1.80 50 ND ND ND ND ND --ND ug/L 06/15/10 1.80 50 ND ND ND ND ND --ND ug/L 12/09/10 1.80 50 2.21 J ND ND 2.98 J ND --ND ug/L 06/15/11 1.80 50 ND ND ND ND ND 2.00 J ND ug/L 12/06/11 1.80 50 2.09 J ND ND 2.96 J ND --ND ug/L 06/14/12 1.80 50 ND ND ND 4.85 J 3.30 J ND ND ug/L 12/03/12 1.80 50 ND ND ND 2.49 J ND ND ND ug/L 06/11/13 1.80 50 3.39 J ND ND ND ND ND ND ug/L 12/02/13 1.80 50 ND ND ND ND ND ND ND ug/L 06/10/14 1.80 50 ND ND ND ND ND ND ND ug/L 12/03/14 1.80 50 ND ND ND 2.48 J ND ND ND ug/L 06/08/15 1.80 50 ND ND ND 2.24 J ND ND ND ug/L 12/02/15 1.80 50 ND ND ND 2.10 J ND ND ND ug/L 06/07/16 1.80 50 ND ND ND 4.11 J ND ND ND Selenium ug/L 08/07/02 --20 ND ND ND ND ND --ND NC 2L = 20 ug/L ug/L 06/16/03 --20 ND ND ND ND ND --ND EPA MCL = 50 ug/L ug/L 12/16/03 --20 ND ND ND ND ND --ND ug/L 06/16/04 --20 ND ND ND ND ND --ND ug/L 12/16/04 --20 ND ND ND ND ND --ND ug/L 06/14/05 --20 ND ND ND ND ND --ND ug/L 12/27/05 --20 ND ND ND ND ND --ND ug/L 06/21/06 --20 ND ND ND ND ND --ND ug/L 12/13/06 2 10 4.3 B 2.1 B ND 5.4 B ND --4.5 J ug/L 06/29/07 2.8 10 ND ND 2.8 J ND ND --ND ug/L 12/13/07 2 10 ND ND ND ND ND --ND ug/L 06/19/08 2 10 ND ND ND 2.7 J ND --ND ug/L 12/02/08 2.7 10 ND ND ND ND ND --ND ug/L 06/11/09 3.4 10 ND ND 4.8 J ND ND --ND ug/L 12/10/09 0.830 10 ND ND ND ND ND --ND ug/L 06/15/10 2.70 10 ND ND ND ND ND --ND ug/L 12/09/10 0.830 10 ND ND ND 1.85 J ND --ND ug/L 06/15/11 0.830 10 ND ND ND ND ND ND ND ug/L 12/06/11 2.70 10 ND ND ND ND ND --ND ug/L 06/14/12 0.830 10 ND ND ND ND ND ND ND ug/L 12/03/12 4.50 10 ND ND ND ND ND ND ND ug/L 06/11/13 5.00 10 ND ND ND ND ND ND ND ug/L 12/02/13 5.00 10 ND ND ND ND ND ND ND ug/L 06/10/14 5.00 10 ND ND ND ND ND ND ND ug/L 12/03/14 5.00 10 ND ND ND ND ND ND ND ug/L 06/08/15 5.00 10 ND ND ND ND 5.43 J (ND ND ND (dissolved)ug/L 06/08/15 5.00 10 --------ND --ND ug/L 12/02/15 5.00 10 ND ND ND ND ND ND ND ug/L 06/07/16 5.00 10 ND ND ND ND ND ND ND August 2016 Page 5 of 10 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx Blanks MW-1 MW-2 MW-3 MW-4 MW-5 MW-6AsParameterReporting Units Date MDL TABLE 4 Summary of Detected Constituents in Groundwater Brownfield Road Construction and Demolition Landfill, Permit No. 92-31 Wake County, North Carolina SWS Reporting Limit Upgradient Downgradient Silver ug/L 08/07/02 --10 ND ND ND ND ND --ND SWS GPS = 20 ug/L ug/L 06/16/03 --10 ND ND ND ND ND --ND EPA MCL = 100 ug/L ug/L 12/16/03 --10 ND ND ND ND ND --ND ug/L 06/16/04 --10 ND ND ND ND ND --ND ug/L 12/16/04 --10 ND ND ND ND ND --ND ug/L 06/14/05 --10 ND ND ND ND ND --ND ug/L 12/27/05 --10 ND ND ND ND ND --ND ug/L 06/21/06 --10 ND ND ND ND ND --ND ug/L 12/13/06 2 10 ND 3.1 J ND ND ND --ND ug/L 06/29/07 2 10 ND ND ND ND ND --ND ug/L 12/13/07 2 10 ND ND ND ND ND --ND ug/L 06/19/08 2 10 ND ND ND ND ND --ND ug/L 12/02/08 1.9 10 ND ND ND ND ND --ND ug/L 06/11/09 1.0 10 2.7 J ND 1.4 J 6.8 J ND --ND ug/L 12/10/09 1.90 10 ND 2.08 J ND ND ND --ND ug/L 06/15/10 1.90 10 ND ND ND ND ND --ND ug/L 12/09/10 1.90 10 ND ND ND ND ND --ND ug/L 06/15/11 1.90 10 ND ND ND ND ND ND ND ug/L 12/06/11 1.90 10 2.67 J ND ND ND 3.09 --ND ug/L 06/14/12 1.90 10 ND ND ND 2.28 J 2.53 J ND ND ug/L 12/03/12 1.90 10 ND ND ND ND ND ND ND ug/L 06/11/13 1.90 10 5.10 B 2.95 B ND ND ND ND 2.02 J ug/L 12/02/13 1.90 10 ND ND 3.69 J ND ND ND ND ug/L 06/10/14 1.90 10 ND ND ND ND ND ND ND ug/L 12/03/14 1.90 10 12.0 ND ND ND ND ND ND ug/L 06/08/15 1.90 10 5.67 J ND ND ND 6.37 J ND ND ug/L 12/02/15 1.90 10 ND ND 5.37 J ND ND ND ND ug/L 06/07/16 1.90 10 ND 2.59 J ND ND 2.26 J ND ND Thallium ug/L 06/29/07 0.036 5.5 0.246 J 0.137 J 0.390 J 0.039 J ND --ND SWS GPS = 0.28 ug/L ug/L 12/13/07 0.036 5.5 0.372 J 0.141 J 0.492 J 0.050 J ND --ND EPA MCL = 2 ug/L ug/L 06/19/08 0.036 5.5 0.352 J 0.143 J 0.450 J 0.047 J ND --ND ug/L 12/02/08 0.036 5.5 ND ND ND ND ND --ND ug/L 06/11/09 0.036 5.5 0.304 J ND 0.210 J ND ND --ND ug/L 12/10/09 0.110 5.5 0.325 J 0.111 J 0.318 J ND ND --ND ug/L 06/15/10 0.110 5.5 0.144 J ND 0.126 J ND ND --ND ug/L 12/09/10 0.110 5.5 0.126 J ND ND ND ND --ND ug/L 06/15/11 0.110 5.5 ND ND ND ND ND --ND ug/L 12/06/11 0.110 5.5 0.319 J 0.119 J 0.226 J ND ND ND ND ug/L 06/14/12 0.110 5.5 0.316 B 0.126 B 0.225 B ND ND 0.157 B 0.195 J ug/L 12/03/12 0.110 5.5 0.318 J ND 0.243 J ND ND ND ND ug/L 06/11/13 0.110 5.5 0.310 J 0.129 J 0.217 J ND ND ND ND ug/L 12/02/13 0.110 5.5 0.285 J 0.128 J 0.224 J ND ND ND ND ug/L 06/10/14 0.110 5.5 0.207 J 0.115 J 0.164 J ND ND ND ND ug/L 12/03/14 0.110 5.5 0.211 J 0.112 J 0.162 J ND ND ND ND ug/L 06/08/15 0.110 5.5 0.196 J 0.193 J 0.137 J ND ND ND ND ug/L 12/02/15 0.110 5.5 0.237 J ND 0.146 J ND ND ND ND ug/L 06/07/16 0.110 6 0.255 J 0.152 J 0.181 J ND ND ND ND Vanadium ug/L 06/29/07 1.7 25 ND ND ND ND 2.9 --ND SWS GPS = 0.3 ug/L ug/L 12/13/07 1 25 4.9 J ND ND ND 4.0 --ND No EPA MCL ug/L 06/19/08 1 25 1.3 J ND ND ND 1.1 --ND ug/L 12/02/08 1.4 25 4.1 J ND ND ND ND --ND ug/L 06/11/09 0.7 25 5.9 J ND ND ND 6.6 --ND ug/L 12/10/09 1.40 25 ND ND ND ND 2.15 --ND ug/L 06/15/10 1.40 25 ND ND ND ND ND --ND ug/L 12/09/10 1.40 25 ND ND ND ND 4.33 --ND ug/L 06/15/11 1.40 25 ND ND ND ND 2.41 ND ND ug/L 12/06/11 1.40 25 ND ND ND ND 16.4 --ND ug/L 06/14/12 1.40 25 ND ND ND ND 9.34 J 2.92 J ND ug/L 12/03/12 1.40 25 ND ND ND ND 2.19 J 1.93 J ND ug/L 12/03/12 1.40 25 ------------ND ug/L 06/11/13 1.40 25 ND ND ND ND 8.91 J ND ND ug/L 12/02/13 1.40 25 ND ND ND ND 4.16 J ND ND ug/L 06/10/14 1.40 25 ND ND ND ND 2.87 J ND ND ug/L 12/03/14 1.40 25 ND ND ND ND 2.02 J ND ND ug/L 06/08/15 1.40 25 ND ND ND ND 17.3 J ND ND ug/L 12/02/15 1.40 25 ND ND ND ND 5.31 J 1.89 J ND ug/L 06/07/16 1.40 25 ND ND ND ND 11.5 J ND ND August 2016 Page 6 of 10 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx Blanks MW-1 MW-2 MW-3 MW-4 MW-5 MW-6AsParameterReporting Units Date MDL TABLE 4 Summary of Detected Constituents in Groundwater Brownfield Road Construction and Demolition Landfill, Permit No. 92-31 Wake County, North Carolina SWS Reporting Limit Upgradient Downgradient Zinc ug/L 08/07/02 --50 ND ND ND ND ND --ND NC 2L = 1000 ug/L ug/L 06/29/07 3.4 10 9.1 J ND 26.1 ND ND --ND EPA MCL = 5000 ug/L*ug/L 12/13/07 1 10 22.2 3.3 B 33.4 3.2 B 5.0 --2.6 J ug/L 06/19/08 1 10 15.6 2.5 B 26.2 15.3 2.7 --1.0 J ug/L 12/02/08 3.8 10 22.2 ND 13.7 ND ND --ND ug/L 06/11/09 3.4 10 32.7 B 4.6 B 15.7 B 13.8 B 31.0 --8.4 J ug/L 12/10/09 3.80 10 12.9 ND 11.0 ND ND --ND ug/L 06/15/10 3.80 10 13.9 ND 7.62 J 4.03 J ND --ND ug/L 12/09/10 3.80 10 27.0 ND 7.78 J ND ND --ND ug/L 06/15/11 3.80 10 12.5 ND 7.94 J ND ND 11.0 ND ug/L 12/06/11 3.80 10 15.7 5.51 J 14.5 ND 13.4 --ND ug/L 06/14/12 3.80 10 13.9 ND 7.65 J ND 7.96 J 22.1 ND ug/L 12/03/12 3.80 10 11.8 ND 7.39 J ND ND 10.8 ND ug/L 06/11/13 3.80 10 12.8 ND 5.92 J ND 5.03 J 4.47 J ND ug/L 12/02/13 3.80 10 11.3 4.88 J 6.30 J ND 3.92 J 6.24 J ND ug/L 06/10/14 3.80 10 8.35 J ND 7.98 J ND 4.43 J 4.84 J ND ug/L 12/03/14 3.80 10 7.35 J ND 4.35 J ND ND ND ND ug/L 06/08/15 3.80 10 7.31 J ND ND ND 5.39 J 6.17 J ND ug/L 12/02/15 3.80 10 6.41 J ND ND ND 4.15 J 6.79 J ND ug/L 06/07/16 3.80 10 5.96 J ND ND ND 5.16 J ND ND Iron ug/L 06/29/07 15 300 ND ND 239 J ND 4180 --ND NC 2L = 300 ug/L ug/L 08/09/07 20 300 364 --2920 ------23 J EPA MCL = 300 ug/L*ug/L 12/13/07 20 300 2970 328 124 J 321 7340 --ND ug/L 06/19/08 20 300 1230 86 J 75 J 203 J 16100 --ND ug/L 12/02/08 22 300 3780 66 J 32 J 32 J 15500 --ND ug/L 06/11/09 31 300 3150 40 J 35 J 158 J 25300 --ND ug/L 12/10/09 22.0 300 409 41.4 J 32.8 J 58.3 J 6370 --ND ug/L 06/15/10 22.0 300 517 109 J 48.9 J 78.6 J 8750 --ND ug/L 12/09/10 22.0 300 210 J ND 26.1 J 134 J 22300 --ND ug/L 06/15/11 22.0 300 149 J 31.4 J ND 111 J 9750 970 ND ug/L 12/06/11 22.0 300 73.1 J ND ND 29.7 J 41800 --ND ug/L 06/14/12 22.0 300 80.9 J 38.9 J ND 38.0 J 20500 2320 ND ug/L 12/03/12 22.0 300 68.5 J 32.8 J ND 25.1 J 10800 1240 ND ug/L 06/11/13 22.0 300 188 J 102 B ND 23.0 B 29600 664 32.8 J ug/L 12/02/13 22.0 300 116 J ND ND ND 13500 748 ND ug/L 06/10/14 22.0 300 72.0 J ND 31.4 J ND 10600 164 J ND ug/L 12/03/14 22.0 300 78.6 J ND ND 52.4 J 7180 151 J ND ug/L 06/08/15 22.0 300 182 J ND 34.2 J 277 J 54100 848 ND ug/L 12/02/15 22.0 300 179 J ND ND 1020 20300 928 ND ug/L 06/07/16 22.0 300 261 J ND ND 1920 36800 234 J ND Manganese ug/L 06/29/07 1.4 50 71.2 174 256 52.6 151 --ND NC 2L = 50 ug/L ug/L 12/13/07 1.4 50 121 123 356 72.3 170 --ND EPA MCL = 50 ug/L*ug/L 06/19/08 1.4 50 86.6 113 274 78.9 155 --ND ug/L 12/02/08 1.1 50 137 72.3 237 63.0 158 --2.6 J ug/L 06/11/09 1.1 50 125 111 195 68.0 158 --ND ug/L 12/10/09 1.10 50 71.6 62.8 177 65.3 151 --ND ug/L 06/15/10 1.10 50 62.8 158 108 85.4 136 --ND ug/L 12/09/10 1.10 50 66.4 89.9 116 136 158 --ND ug/L 06/15/11 1.10 50 68.2 118 142 106 157 1230 ND ug/L 12/06/11 1.10 50 67.5 86.9 171 188 164 --1.46 J ug/L 06/14/12 1.10 50 66.4 121 159 143 163 122 ND ug/L 12/03/12 1.10 50 57.5 93.6 176 246 138 182 ND ug/L 06/11/13 1.10 50 58.9 190 168 227 151 18.9 J ND ug/L 12/02/13 1.10 50 47.4 J 162 145 396 144 71.8 ND ug/L 06/10/14 1.10 50 36.2 J 299 109 387 151 14.1 J ND ug/L 12/03/14 1.10 50 37.3 J 295 102 906 156 16.2 J ND ug/L 06/08/15 1.10 50 56.2 486 78.2 1790 162 25.1 J 2.85 J ug/L 12/02/15 1.10 50 55.3 361 79.6 3100 152 33.3 J 1.25 J ug/L 06/07/16 1.10 50 71.9 544 76.3 4700 162 13.5 J ND (disolved)ug/L 06/07/16 1.10 50 --539 --4570 ----ND Benzene ug/L 06/16/03 --5 ND ND ND ND ND --ND NC 2L = 1 ug/L ug/L 12/16/03 --5 ND ND ND ND ND --ND EPA MCL = 5 ug/L ug/L 06/16/04 --5 ND ND ND ND ND --ND ug/L 12/16/04 --5 ND ND ND ND ND --ND ug/L 06/14/05 --5 ND ND ND ND ND --ND ug/L 12/27/05 --5 ND ND ND ND ND --ND ug/L 06/21/06 --5 ND ND ND ND ND --ND ug/L 12/13/06 --5 ND ND ND ND ND --ND ug/L 06/29/07 0.12 1 ND ND ND ND ND --ND ug/L 12/13/07 0.12 1 ND ND ND ND ND --ND ug/L 06/19/08 0.2 1 ND ND ND ND ND --ND ug/L 12/02/08 0.2 1 ND ND ND ND ND --ND ug/L 06/11/09 0.20 1 ND ND ND ND ND --ND ug/L 12/10/09 0.20 1 ND ND ND ND ND --ND ug/L 06/15/10 0.050 1 ND ND ND ND ND --ND ug/L 12/09/10 0.20 1 ND ND ND ND ND --ND ug/L 06/15/11 0.68 1 ND ND ND ND ND ND ND ug/L 12/06/11 0.68 1 ND ND ND ND ND --ND ug/L 06/14/12 0.15 1 ND ND ND ND ND ND ND ug/L 12/03/12 0.15 1 ND ND 0.58 J ND ND ND ND ug/L 06/11/13 0.15 1 ND ND 0.70 J ND ND ND ND ug/L 12/02/13 0.15 1 ND ND 0.45 J ND ND ND ND ug/L 06/10/14 0.15 1 ND ND ND ND ND ND ND ug/L 12/03/14 0.15 1 ND ND ND ND ND ND ND ug/L 06/08/15 0.15 1 ND ND ND 0.52 J ND ND ND ug/L 12/02/15 0.15 1 ND ND ND 0.52 J ND ND ND ug/L 06/07/16 0.15 1 ND ND ND ND ND ND ND August 2016 Page 7 of 10 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx Blanks MW-1 MW-2 MW-3 MW-4 MW-5 MW-6AsParameterReporting Units Date MDL TABLE 4 Summary of Detected Constituents in Groundwater Brownfield Road Construction and Demolition Landfill, Permit No. 92-31 Wake County, North Carolina SWS Reporting Limit Upgradient Downgradient cis-1,2-Dichloroethene ug/L 06/16/03 --5 ND ND ND ND ND --ND NC 2L = 70 ug/L ug/L 12/16/03 --5 ND ND ND ND ND --ND EPA MCL = 70 ug/L ug/L 06/16/04 --5 ND ND ND ND ND --ND ug/L 12/16/04 --5 ND ND ND ND ND --ND ug/L 06/14/05 --5 ND ND ND ND ND --ND ug/L 12/27/05 --5 ND ND ND ND ND --ND ug/L 06/21/06 --5 ND ND ND ND ND --ND ug/L 12/13/06 --5 ND ND ND ND ND --ND ug/L 06/29/07 0.14 5 ND ND ND ND ND --ND ug/L 12/13/07 0.14 5 ND ND ND ND ND --ND ug/L 06/19/08 0.3 5 ND ND ND ND ND --ND ug/L 12/02/08 0.36 5 ND ND ND ND ND --ND ug/L 06/11/09 0.36 5 ND ND ND ND ND --ND ug/L 12/10/09 0.36 5 ND ND ND ND ND --ND ug/L 06/15/10 0.075 5 ND ND ND ND ND --ND ug/L 12/09/10 0.36 5 ND ND ND ND ND --ND ug/L 06/15/11 0.72 5 ND ND ND ND ND ND ND ug/L 12/06/11 0.72 5 ND ND ND ND ND --ND ug/L 06/14/12 0.15 5 ND ND ND ND ND ND ND ug/L 12/03/12 0.15 5 ND ND 0.50 J ND ND ND ND ug/L 06/11/13 0.15 5 ND ND 0.80 J ND ND ND ND ug/L 12/02/13 0.15 5 ND ND 0.55 J ND ND ND ND ug/L 06/10/14 0.15 5 ND ND ND ND ND ND ND ug/L 12/03/14 0.15 5 ND ND ND ND ND ND ND ug/L 06/08/15 0.15 5 ND ND ND 0.47 J ND ND ND ug/L 12/02/15 0.15 5 ND ND 0.56 J 0.46 J ND ND ND ug/L 06/07/16 0.15 5 ND ND 0.72 J ND ND ND ND Methylene Chloride ug/L 06/16/03 --10 ND ND ND ND ND --ND NC 2L = 5 ug/L ug/L 12/16/03 --10 ND ND ND ND ND --ND EPA MCL = 5 ug/L ug/L 06/16/04 --10 ND ND ND ND ND --ND ug/L 12/16/04 --10 ND ND ND ND ND --ND ug/L 06/14/05 --10 ND ND ND ND ND --ND ug/L 12/27/05 --10 ND ND ND ND ND --ND ug/L 06/21/06 --10 ND ND ND ND ND --ND ug/L 12/13/06 --10 ND ND ND ND ND --ND ug/L 06/29/07 0.088 1 ND ND ND ND ND --ND ug/L 12/13/07 0.088 1 ND ND ND ND ND --ND ug/L 06/19/08 0.24 1 ND ND ND ND ND --ND ug/L 12/02/08 0.53 1 ND ND ND ND ND --ND ug/L 06/11/09 0.53 1 ND ND ND ND ND --ND ug/L 12/10/09 0.53 1 ND ND ND ND ND --ND ug/L 06/15/10 0.070 1 ND ND ND ND ND --ND ug/L 12/09/10 0.53 1 ND ND ND ND ND --ND ug/L 06/15/11 0.14 1 ND ND ND ND ND ND ND ug/L 12/06/11 0.14 1 ND ND 1.0 ND ND --ND ug/L 06/14/12 0.23 1 ND ND ND ND ND ND ND ug/L 12/03/12 0.23 1 ND ND 1.5 ND ND ND ND ug/L 06/11/13 0.23 1 ND ND 2.0 ND ND ND ND ug/L 12/02/13 0.23 1 ND ND ND ND ND ND ND ug/L 06/10/14 0.23 1 ND ND ND ND ND ND ND ug/L 12/03/14 0.23 1 ND ND ND ND ND ND ND ug/L 06/08/15 0.23 1 ND ND ND ND ND ND ND ug/L 12/02/15 0.23 1 ND ND 0.56 J ND ND ND ND ug/L 06/07/16 0.23 1 ND ND ND ND ND ND ND Tetrachloroethene ug/L 06/16/03 --5 ND ND ND ND ND --ND NC 2L = 0.7 ug/L ug/L 12/16/03 --5 ND ND ND ND ND --ND EPA MCL = 5 ug/L ug/L 06/16/04 --5 ND ND ND ND ND --ND ug/L 12/16/04 --5 ND ND ND ND ND --ND ug/L 06/14/05 --5 ND ND ND ND ND --ND ug/L 12/27/05 --5 ND ND ND ND ND --ND ug/L 06/21/06 --5 ND ND ND ND ND --ND ug/L 12/13/06 --5 ND ND ND ND ND --ND ug/L 06/29/07 0.25 1 ND ND ND ND ND --ND ug/L 12/13/07 0.25 1 ND ND ND ND ND --ND ug/L 06/19/08 0.36 1 ND ND ND ND ND --ND ug/L 12/02/08 0.36 1 ND ND 0.77 J ND ND --ND ug/L 06/11/09 0.36 1 ND ND 0.82 J ND ND --ND ug/L 12/10/09 0.36 1 ND ND 1.2 ND ND --ND ug/L 06/15/10 0.099 1 ND ND 1.0 ND ND --ND ug/L 12/09/10 0.36 1 ND ND 1.4 ND ND --ND ug/L 06/15/11 0.73 1 ND ND 1.9 ND ND ND ND ug/L 12/06/11 0.73 1 ND ND 2.9 ND ND --ND ug/L 06/14/12 0.17 1 ND ND 0.64 J ND ND ND ND ug/L 12/03/12 0.17 1 ND ND 2.9 ND ND ND ND ug/L 06/11/13 0.17 1 ND ND 2.4 ND ND ND ND ug/L 12/02/13 0.17 1 ND ND 1.8 ND ND ND ND ug/L 06/10/14 0.17 1 ND ND 1.5 ND ND ND ND ug/L 12/03/14 0.17 1 ND ND 0.84 J ND ND ND ND ug/L 06/08/15 0.17 1 ND ND 0.53 J ND ND ND ND ug/L 12/02/15 0.17 1 ND ND 0.58 J ND ND ND ND ug/L 06/07/16 0.17 1 ND ND 0.40 J ND ND ND ND August 2016 Page 8 of 10 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx Blanks MW-1 MW-2 MW-3 MW-4 MW-5 MW-6AsParameterReporting Units Date MDL TABLE 4 Summary of Detected Constituents in Groundwater Brownfield Road Construction and Demolition Landfill, Permit No. 92-31 Wake County, North Carolina SWS Reporting Limit Upgradient Downgradient Trichloroethene ug/L 06/16/03 --5 ND ND ND ND ND --ND NC 2L = 3 ug/L ug/L 12/16/03 --5 ND ND ND ND ND --ND EPA MCL = 5 ug/L ug/L 06/16/04 --5 ND ND ND ND ND --ND ug/L 12/16/04 --5 ND ND ND ND ND --ND ug/L 06/14/05 --5 ND ND ND ND ND --ND ug/L 12/27/05 --5 ND ND ND ND ND --ND ug/L 06/21/06 --5 ND ND ND ND ND --ND ug/L 12/13/06 --5 ND ND ND ND ND --ND ug/L 06/29/07 0.23 1 ND ND ND ND ND --ND ug/L 12/13/07 0.23 1 ND ND ND ND ND --ND ug/L 06/19/08 0.25 1 ND ND 0.60 J ND ND --ND ug/L 12/02/08 0.38 1 ND ND 1.6 ND ND --ND (verification event)ug/L 01/23/09 0.56 1 ----1.7 (4.2)ND ND --ND ug/L 06/11/09 0.38 1 ND ND 2.2 ND ND --ND ug/L 12/10/09 0.38 1 ND ND 3.4 ND ND --ND ug/L 06/15/10 0.13 1 ND ND 2.1 ND ND --ND ug/L 12/09/10 0.38 1 ND ND 3.0 ND ND --ND ug/L 06/15/11 0.72 1 ND ND 4.6 ND ND ND ND ug/L 12/06/11 0.72 1 ND ND 4.8 ND ND --ND ug/L 06/14/12 0.15 1 ND ND 3.2 ND ND ND ND ug/L 12/03/12 0.15 1 ND ND 3.4 ND ND ND ND ug/L 06/11/13 0.15 1 ND ND 2.4 ND ND ND ND ug/L 12/02/13 0.15 1 ND ND 1.4 ND ND ND ND ug/L 06/10/14 0.15 1 ND ND 0.73 J ND ND ND ND ug/L 12/03/14 0.15 1 ND ND 0.44 J ND ND ND ND ug/L 06/08/15 0.15 1 ND ND ND ND ND ND ND ug/L 12/02/15 0.15 1 ND ND ND ND ND ND ND ug/L 06/07/16 0.15 1 ND ND ND ND ND ND ND Trichlorofluoromethane ug/L 06/16/03 --5 ND ND ND ND ND --ND NC 2L = 2000 ug/L ug/L 12/16/03 --5 ND ND ND ND ND --ND No EPA MCL ug/L 06/16/04 --5 ND ND ND ND ND --ND ug/L 12/16/04 --5 ND ND ND ND ND --ND ug/L 06/14/05 --5 ND ND ND ND ND --ND ug/L 12/27/05 --5 ND ND ND ND ND --ND ug/L 06/21/06 --5 ND ND ND ND ND --ND ug/L 12/13/06 0.2 5 ND ND 3.3 J ND ND --ND ug/L 06/29/07 0.16 1 ND 0.53 J 34 ND ND --ND ug/L 08/09/07 0.16 1 ----11 ------ND ug/L 12/13/07 0.16 1 ND ND 23 ND ND --ND ug/L 06/19/08 0.28 1 ND ND 25 ND ND --ND ug/L 12/02/08 0.28 1 ND ND 13 ND ND --ND ug/L 06/11/09 0.28 1 ND ND 9.2 ND ND --ND ug/L 12/10/09 0.28 1 ND ND 7.8 ND ND --ND ug/L 06/15/10 0.15 1 ND ND 3.1 ND ND --ND ug/L 12/09/10 0.28 1 ND ND 2.6 ND ND --ND ug/L 06/15/11 0.66 1 ND ND 2.2 ND ND ND ND ug/L 12/06/11 0.66 1 ND ND 1.4 ND ND --ND ug/L 06/14/12 0.24 1 ND ND ND ND ND ND ND ug/L 12/03/12 0.24 1 ND ND 0.91 J ND ND ND ND ug/L 06/11/13 0.24 1 ND ND 0.52 J ND ND ND ND ug/L 12/02/13 0.24 1 ND ND ND ND ND ND ND ug/L 06/10/14 0.24 1 ND ND ND ND ND ND ND ug/L 12/03/14 0.24 1 ND ND ND ND ND ND ND ug/L 06/08/15 0.24 1 ND ND ND ND ND ND ND ug/L 12/02/15 0.24 1 ND ND ND ND ND ND ND ug/L 06/07/16 0.24 1 ND ND ND ND ND ND ND Total Xylenes ug/L 06/16/03 --10 ND ND ND ND ND --ND NC 2L = 500 ug/L ug/L 12/16/03 --10 5 ND ND ND ND --ND EPA MCL = 10000 ug/L ug/L 06/16/04 --10 ND ND ND ND ND --ND ug/L 12/16/04 --10 ND ND ND ND ND --ND ug/L 06/14/05 --10 ND ND ND ND ND --ND ug/L 12/27/05 --5 ND ND ND ND ND --ND ug/L 06/21/06 --5 ND ND ND ND ND --ND ug/L 12/13/06 --5 ND ND ND ND ND --ND ug/L 06/29/07 0.21 4 ND ND ND ND ND --ND ug/L 12/13/07 0.21 5 ND ND ND ND ND --ND ug/L 06/19/08 0.4 5 ND ND ND ND ND --ND ug/L 12/02/08 0.4 5 ND ND ND ND ND --ND ug/L 06/11/09 0.40 5 ND ND ND ND ND --ND ug/L 12/10/09 0.40 5 ND ND ND ND ND --ND ug/L 06/15/10 0.22 5 ND ND ND ND ND --ND ug/L 12/09/10 0.40 5 ND ND ND ND ND --ND ug/L 06/15/11 2.1 5 ND ND ND ND ND ND ND ug/L 12/06/11 2.1 5 ND ND ND ND ND --ND ug/L 06/14/12 0.45 5 ND ND ND ND ND ND ND ug/L 12/03/12 0.45 5 ND ND 1.6 J ND ND ND ND ug/L 06/11/13 0.45 5 ND ND 2.0 J ND ND ND ND ug/L 12/02/13 0.45 5 ND ND 0.62 J ND ND ND ND ug/L 06/10/14 0.45 5 ND ND ND ND ND ND ND ug/L 12/03/14 0.45 5 ND ND ND ND ND ND ND ug/L 06/08/15 0.45 5 ND ND ND ND ND ND ND ug/L 12/02/15 0.45 5 ND ND ND ND ND ND ND ug/L 06/07/16 0.45 5 ND ND ND ND ND ND ND August 2016 Page 9 of 10 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx Blanks MW-1 MW-2 MW-3 MW-4 MW-5 MW-6AsParameterReporting Units Date MDL TABLE 4 Summary of Detected Constituents in Groundwater Brownfield Road Construction and Demolition Landfill, Permit No. 92-31 Wake County, North Carolina SWS Reporting Limit Upgradient Downgradient Tetrahydrofuran ug/L 06/15/11 0.80 --ND ND 4.8 ND ND --ND No Standard ug/L 12/06/11 0.80 --ND ND 8.5 ND ND --ND No EPA MCL ug/L 06/14/12 0.80 --ND ND 11 ND ND ND ND ug/L 12/03/12 0.80 --ND ND 22 ND ND ND ND ug/L 06/11/13 0.80 --ND ND 55 ND ND ND ND ug/L 12/02/13 0.80 --ND ND 45 ND ND ND ND ug/L 06/10/14 0.80 --ND ND 19 ND ND ND ND ug/L 12/03/14 0.80 --ND ND 10 ND ND ND ND ug/L 06/08/15 0.80 --ND ND 2.0 ND ND ND ND ug/L 12/02/15 0.80 --ND ND 2.2 ND ND ND ND ug/L 12/02/15 0.80 --ND ND 2.2 ND ND ND ND ug/L 06/07/16 0.80 --ND ND ND ND ND ND 3.1 Chloride mg/L 06/29/07 0.05 --16 15 27 3.6 3.1 --0.54 J NC 2L = 250 mg/L mg/L 08/09/07 2 --24 --39 ------ND EPA MCL = 250 mg/L mg/L 12/13/07 0.48 --27 21 47 9.0 4.3 --ND mg/L 06/19/08 2 --29 16 33 5.4 B 4.1 --1.7 J mg/L 12/02/08 0.5 --32 15 33 4.7 J 2.9 --ND mg/L 06/11/09 0.018 --35 16 25 4.9 J 4.8 --ND mg/L 12/10/09 0.018 --40 16 24 5.6 9.2 --ND mg/L 06/15/10 0.018 --31 19 18 4.9 J 5.1 --ND mg/L 12/09/10 0.018 --36 18 14 5.0 4.2 --ND mg/L 06/15/11 0.29 --38 18 19 4.5 J 4.6 3.6 J ND mg/L 12/06/11 0.047 --42 15 21 4.4 B 3.7 --1.4 J mg/L 06/14/12 0.43 --40 14 16 4.1 B 4.1 B 3.7 B 1.5 mg/L 12/03/12 0.43 --41 14 20 4.7 B 3.7 B 3.5 B 1.4 mg/L 06/11/13 2.2 --37 15 17 3.7 J 4.4 J 2.5 J ND mg/L 12/02/13 2.2 --31 16 15 4.0 J 3.7 J 2.4 J ND mg/L 06/10/14 2.2 --20 23 12 4.1 J 7.0 2.4 J ND mg/L 12/03/14 2.2 --19 20 10 4.6 J 4.2 J 2.2 J ND mg/L 06/08/15 2.2 --16 23 9.7 5.9 4.5 J 2.4 J ND mg/L 12/02/15 2.2 --15 19 8.1 5.2 3.4 J ND ND mg/L 06/07/16 2.2 --14 19 8.4 4.3 J 3.5 J ND ND Total Dissolved Solids mg/L 06/29/07 10 --88 310 490 92 76 --ND NC 2L = 1000 mg/L mg/L 08/09/07 10 --82 --620 ------ND No EPA MCL mg/L 12/13/07 10 --70 360 690 110 66 --ND mg/L 06/19/08 10 --86 350 490 90 58 --ND mg/L 12/02/08 10 --78 350 520 110 76 --ND mg/L 06/11/09 10 --68 330 370 48 54 --ND mg/L 12/10/09 10 --64 310 350 46 100 --ND mg/L 06/15/10 10 --76 390 240 130 62 --ND mg/L 12/09/10 10 --72 340 130 130 50 --ND mg/L 06/15/11 10 --60 330 200 80 54 110 ND mg/L 12/06/11 10 --68 280 220 110 52 --ND mg/L 06/14/12 10 --72 320 200 80 44 66 ND mg/L 12/03/12 10 --140 260 120 130 50 120 ND mg/L 06/11/13 10 --50 180 170 34 ND 28 ND mg/L 12/02/13 10 --52 330 140 110 26 36 ND mg/L 06/10/14 10 --38 350 90 76 32 26 ND mg/L 12/03/14 10 --24 270 30 110 12 12 ND mg/L 06/08/15 10 --ND 290 ND 130 ND ND ND mg/L 12/02/15 10 --ND 320 ND 140 56 ND ND mg/L 06/07/16 10 --ND 320 ND 200 ND ND ND Sulfate mg/L 06/29/07 0.6 250 4.0 B 3.9 B 3.8 B 8.8 B 5.6 --3.9 J NC 2L = 250 mg/L mg/L 08/09/07 0.03 250 1.4 J --1.8 J ------ND No EPA MCL mg/L 12/13/07 0.03 250 0.86 J 1.2 J 1.4 J 3.6 J 0.88 --ND mg/L 06/19/08 0.05 250 1.6 J 1.7 J 1.6 J 4.6 J 3.6 --ND mg/L 12/02/08 0.05 250 ND 2.0 J 2.0 J 5.5 J 4.0 --ND mg/L 06/11/09 0.078 250 1.9 J 1.9 J 1.8 J 6.2 J 4.9 --ND mg/L 12/10/09 0.078 250 2.0 J 2.1 J 2.0 J 8.2 J 5.5 --ND mg/L 06/15/10 0.12 250 3.1 J 2.0 J ND 42 J 5.0 --ND mg/L 12/09/10 0.12 250 2.5 J 2.1 J 1.9 J 59 J 3.7 --ND mg/L 06/15/11 0.07 250 1.2 J 1.1 J 0.81 J 27 J 3.6 6.3 J ND mg/L 12/06/11 0.02 250 1.6 J 1.7 J 1.5 J 63 J 2.9 --ND mg/L 06/14/12 0.04 250 1.9 J 2.2 J 1.9 J 27 J 3.7 J 7.5 J ND mg/L 12/03/12 0.04 250 2.1 J 2.3 J 2.0 J 64 J 3.2 J 6.4 J ND mg/L 06/11/13 0.04 250 2.1 J 2.8 J ND 26 J 5.2 J 15 J ND mg/L 12/02/13 2.9 250 ND ND ND 44 J 3.1 J 6.6 J ND mg/L 06/10/14 2.9 250 3.5 J 6.3 J ND 31 J 4.1 J 9.3 J ND mg/L 12/03/14 2.9 250 3.2 J 7.9 J ND 62 J 4.4 J 10 J ND mg/L 06/08/15 2.9 250 5.0 J 35 J ND 78 J 4.0 J 9.6 J ND mg/L 12/02/15 2.9 250 3.8 J 65 J ND 67 J 3.5 J 6.6 J ND mg/L 06/07/16 2.9 250 4.8 J 110 J ND 110 J 3.8 J 7.2 J ND August 2016 Page 10 of 10 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx Blanks MW-1 MW-2 MW-3 MW-4 MW-5 MW-6AsParameterReporting Units Date MDL TABLE 4 Summary of Detected Constituents in Groundwater Brownfield Road Construction and Demolition Landfill, Permit No. 92-31 Wake County, North Carolina SWS Reporting Limit Upgradient Downgradient Total Alkalinity mg/L 08/07/02 ----3.0 J 5.0 J ND 26 20 --ND No Standard mg/L 06/29/07 5.2 --ND ND ND 17 67 ---- No EPA MCL mg/L 08/09/07 5.2 --ND --ND ------ND mg/L 12/13/07 4.7 --4.7 J 5.4 J ND 24 24 --ND mg/L 06/19/08 4.7 --6.1 B 7.9 B ND 27 B 22 --7.0 J mg/L 12/02/08 2.7 --20 19 22 39 30 --ND mg/L 06/11/09 8.3 --ND ND ND 16 21 --ND mg/L 12/10/09 8.3 --10 J 10 J 16 27 15 --ND mg/L 06/15/10 8.0 --8.7 J ND 11 J 18 23 --ND mg/L 12/09/10 8 --ND ND 9.5 J 21 24 --ND mg/L 06/15/11 12 --ND 12 J ND 18 22 14 J ND mg/L 12/06/11 12 --ND ND ND 17 12 --ND mg/L 06/14/12 12 --ND ND ND 25 18 ND ND mg/L 12/03/12 12 --ND ND ND 20 16 ND ND mg/L 06/11/13 14 --ND ND ND 29 21 ND ND mg/L 12/02/13 14 --14 J ND 24 38 32 21 ND mg/L 06/10/14 14 --ND ND ND 31 ND ND ND mg/L 12/03/14 14 --ND ND ND 31 25 ND ND mg/L 06/08/15 14 --ND ND ND 42 29 ND ND mg/L 12/02/15 14 --ND 18 ND 34 18 ND ND mg/L 06/07/16 14 --ND 21 ND 32 22 ND ND Notes: MW = groundwater monitoring well ug/L = micrograms per liter mg/L = milligrams per liter J = Estimated Value B = Blank-qualified data -- = No data available # = EPA Action Level * = EPA Secondary MCL ND = Not detected at or above the stated reporting limit EPA MCL = Environmental Protection Agency's Maximum Contaminant Level for drinking water. MDL = Method Detection Limit NC 2L = North Carolina groundwater quality standard established under 15A NCAC 2L .0202 SWS GPS = North Carolina Solid Waste Section Groundwater Protection Standard Blanks = Field, trip, and laboratory method blanks Bolded = Concentrations above the current NC 2L Groundwater Standards or SWS GPS. Shaded = Concentration exceeds the current EPA MCL for associated parameter. SWS Reporting Limit = NCPQL or lab-specific reporting limit prior to 2007 and NCSWSL starting on 01/18/07. 1)Results in parentheses reflect laboratory re-analysis data 2)NC DENR approved request on 09/16/14 to discontinue monitoring at existing wells MW-6Ad, MW-7As, and MW-7Ad. August 2016 Page 1 of 3 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx MW-1 MW-2 MW-3 MW-4 MW-5 MW-6As pH S.U.08/07/02 4.74 6.11 5.57 6.35 6.15 -- S.U.12/13/06 5.19 4.82 4.14 5.15 5.71 -- S.U.06/29/07 5.67 4.82 4.30 4.97 5.37 -- S.U.08/09/07 4.03 --3.70 ------ S.U.12/13/07 4.55 4.82 4.12 4.94 5.58 -- S.U.06/19/08 4.44 4.77 4.22 5.05 5.65 -- S.U.12/02/08 4.60 5.03 4.28 5.10 5.65 -- Verification event S.U.01/23/09 ----4.09 ------ S.U.06/11/09 4.77 5.00 4.46 5.21 5.62 -- S.U.12/10/09 4.53 4.82 4.31 5.12 5.34 -- S.U.06/15/10 4.99 5.12 4.96 5.55 5.78 -- S.U.12/09/10 4.45 4.90 4.53 4.82 5.35 -- S.U.06/15/11 6.45 6.43 6.53 5.97 6.88 6.56 S.U.12/06/11 4.22 4.62 4.24 4.71 5.50 -- S.U.06/14/12 4.71 4.71 4.26 4.83 5.40 5.00 S.U.12/03/12 3.91 4.37 4.43 4.42 5.49 4.77 S.U.06/11/13 4.06 3.68 3.44 3.39 3.97 3.74 S.U.12/02/13 4.69 4.92 4.64 5.07 5.86 5.33 Verification event S.U.01/09/14 --4.80 -------- S.U.06/10/14 4.78 4.89 4.82 5.30 5.20 5.17 S.U.12/03/14 3.98 4.33 4.43 4.89 5.46 4.97 S.U.06/08/15 3.51 3.45 3.03 3.74 3.96 4.08 S.U.12/02/15 3.82 4.44 4.08 4.58 4.91 4.33 S.U.06/07/16 3.97 4.35 3.89 4.77 4.59 3.99 Specific Conductance uS/cm 12/13/06 97.7 485 1208 143.8 88.5 -- uS/cm 06/29/07 105 457 696 102 68 -- uS/cm 08/09/07 114 --785 ------ uS/cm 12/13/07 156 567 1040 402 222 -- uS/cm 06/19/08 149 452 707 124 76 -- uS/cm 12/02/08 131 374 586 101 61 -- Verification event uS/cm 01/23/09 ----347 ------ uS/cm 06/11/09 166 452 494 82 74 -- uS/cm 12/10/09 185 450 457 103 74 -- uS/cm 06/15/10 143 464 274 157 75 -- uS/cm 12/09/10 148 435 195 191 66 -- uS/cm 06/15/11 164 436 264 129 72 71 uS/cm 12/06/11 170 382 321 206 68 -- uS/cm 06/14/12 164 105 187 109 61 81 uS/cm 12/03/12 146 322 267 188 58 73 uS/cm 06/11/13 137 332 200 121 60 76 uS/cm 12/02/13 177 408 221 208 104 74 Verification event uS/cm 01/09/14 --474 -------- uS/cm 06/10/14 134 452 164 186 97 79 uS/cm 12/03/14 105 450 106 241 78 61 uS/cm 06/08/15 83 384 78 237 67 44 uS/cm 12/02/15 85 458 76 240 68 39 uS/cm 06/07/16 89 482 80 345 79 40 TABLE 5 Summary of Field Parameters from Groundwater Monitoring Points Brownfield Road Construction and Demolition Landfill, Permit No. 92-31 Wake County, North Carolina Parameter Reporting Units Date Upgradient Downgradient August 2016 Page 2 of 3 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx MW-1 MW-2 MW-3 MW-4 MW-5 MW-6As TABLE 5 Summary of Field Parameters from Groundwater Monitoring Points Brownfield Road Construction and Demolition Landfill, Permit No. 92-31 Wake County, North Carolina Parameter Reporting Units Date Upgradient Downgradient Temperature oC 12/13/06 17.5 16.1 16.2 17.4 15.1 -- oC 06/29/07 20.25 21.3 20.53 20.88 20.64 -- oC 08/09/07 19.13 --17.51 ------ oC 12/13/07 17.42 17.06 16.99 19.01 16.99 -- oC 06/19/08 18.52 17.58 17.38 17.38 16.02 -- oC 12/02/08 15.63 15.55 16.09 17.15 14.53 -- Verification event oC 01/23/09 ----14.76 ------ oC 06/11/09 20.49 18.35 17.64 18.82 19.25 -- oC 12/10/09 16.76 15.70 16.05 16.47 14.63 -- oC 06/15/10 20.84 19.16 18.42 17.93 18.64 -- oC 12/09/10 16.14 15.30 15.26 16.58 13.62 -- oC 06/15/11 19.25 17.45 16.71 17.47 17.61 19.13 oC 12/06/11 17.62 17.09 16.77 18.09 16.91 -- oC 06/14/12 18.81 16.71 17.16 17.16 15.82 17.26 oC 12/03/12 17.62 16.64 16.44 17.55 15.99 16.67 oC 06/11/13 19.31 18.91 17.77 18.40 16.60 17.62 oC 12/02/13 17.5 16.4 16.5 17.2 15.1 15.6 Verification event oC 01/09/14 --16.5 -------- oC 06/10/14 20.2 16.9 16.9 16.7 15.7 16.8 oC 12/03/14 16.3 15.9 15.9 16.8 15.3 15.1 oC 06/08/15 19.2 17.2 17.2 16.4 14.7 15.6 oC 12/02/15 17.4 16.6 16.6 17.6 16.2 16.3 oC 06/07/16 19.4 17.5 17.0 17.1 15.1 16.2 Turbidity NTU 12/13/06 21.6 10.5 16.8 28.7 992 -- NTU 06/29/07 28.4 7.6 0.0 0.0 152 -- NTU 08/09/07 33.5 --96.2 ------ NTU 12/13/07 846 69.8 8.2 21.3 253 -- NTU 06/19/08 65.9 7.94 16.8 11.2 91.1 -- NTU 12/02/08 50.4 7.91 3.49 8.53 99.7 -- Verification event NTU 01/23/09 ----3.33 ------ NTU 06/11/09 84.1 7.67 4.38 14.3 191 -- NTU 12/10/09 33.1 5.12 1.67 7.68 42.9 -- NTU 06/15/10 15.1 10.6 2.10 8.28 44.7 -- NTU 12/09/10 6.96 3.21 1.53 6.40 98.5 -- NTU 06/15/11 3.04 3.40 1.06 6.17 235 30.5 NTU 12/06/11 5.68 4.68 3.09 3.62 461 -- NTU 06/14/12 5.22 14.5 2.44 3.70 270 97.8 NTU 12/03/12 4.07 6.21 2.32 2.14 64.2 47.5 NTU 06/11/13 12.9 14.4 1.23 1.77 354 17.3 NTU 12/02/13 5.10 52.7 2.19 1.16 135 24.4 Verification event NTU 01/09/14 --5.20 -------- NTU 06/10/14 6.83 4.25 2.56 2.14 96.7 8.66 NTU 12/03/14 2.41 1.12 1.69 0.30 43.0 4.17 NTU 06/08/15 7.17 1.14 2.18 2.22 374 12.6 NTU 12/02/15 4.39 1.18 2.24 1.15 160 15.8 NTU 06/07/16 11.80 2.48 2.37 1.63 223 6.17 August 2016 Page 3 of 3 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx MW-1 MW-2 MW-3 MW-4 MW-5 MW-6As TABLE 5 Summary of Field Parameters from Groundwater Monitoring Points Brownfield Road Construction and Demolition Landfill, Permit No. 92-31 Wake County, North Carolina Parameter Reporting Units Date Upgradient Downgradient Dissolved Oxygen mg/L 12/13/07 7.72 5.91 1.18 2.45 0.57 -- mg/L 06/19/08 7.28 5.40 2.18 1.16 0.95 -- mg/L 12/02/08 7.37 6.56 4.03 4.36 1.38 -- Verification event mg/L 01/23/09 ----2.34 ------ mg/L 06/11/09 7.66 5.68 3.06 1.29 0.85 -- mg/L 12/10/09 6.77 6.14 1.53 0.89 2.24 -- mg/L 06/15/10 6.56 1.80 2.50 1.33 2.64 -- mg/L 12/09/10 7.27 4.31 3.21 5.81 5.34 -- mg/L 06/15/11 4.96 4.01 1.67 1.48 0.49 3.70 mg/L 12/06/11 6.42 5.40 1.41 1.08 1.27 -- mg/L 06/14/12 6.00 4.75 3.45 1.78 1.41 6.62 mg/L 12/03/12 4.57 3.39 1.16 0.28 0.76 3.50 mg/L 06/11/13 5.92 2.65 1.44 0.92 1.17 7.27 mg/L 12/02/13 5.68 1.81 1.37 0.45 2.02 5.86 Verification event mg/L 01/09/14 --1.55 -------- mg/L 06/10/14 5.47 0.60 1.63 0.39 0.42 6.17 mg/L 12/03/14 5.34 1.24 1.32 0.45 0.39 5.02 mg/L 06/08/15 5.06 1.46 2.01 0.50 0.23 5.39 mg/L 12/02/15 4.89 0.65 1.59 0.83 1.34 6.37 mg/L 06/07/16 5.56 1.41 2.38 0.61 1.14 5.72 Oxidation-Reduction Potential mV 12/13/07 334 338 396 375 85 -- mV 06/19/08 307 306 358 344 72 -- mV 12/02/08 232.0 321.8 401.5 464.2 160.4 -- Verification event mV 01/23/09 ----328.0 ------ mV 06/11/09 263.6 191.1 266.6 184.1 103.9 -- mV 12/10/09 235.4 215.6 236.9 172.5 123.5 -- mV 06/15/10 255.7 190.3 250.5 177.9 92.1 -- mV 12/09/10 278.9 285.7 279.7 238.2 80.8 -- mV 06/15/11 257.3 229.3 271.1 234.7 141.1 202.3 mV 12/06/11 145.3 128.2 153.4 122.1 95.6 -- mV 06/14/12 -265.0#-278.5#-241.5#-312.8#-318.6#-281.7# mV 12/03/12 127.4 74.3 52.5 8.2 -1.1 37.3 mV 06/11/13 97.8 85.0 99.6 87.3 98.3 92.2 mV 12/02/13 349.7 363.8 452.6 301.7 59.5 281.4 Verification event mV 01/09/14 --330.8 -------- mV 06/10/14 328.6 380.0 577.6 314.4 150.9 311.4 mV 12/03/14 282.6 326.9 318.1 244.7 98.8 201.5 mV 06/08/15 388.5 598.7 616.6 282.5 131.4 316.7 mV 12/02/15 460.7 579.9 568.4 282.8 227.2 483.4 mV 06/07/16 367.3 598.4 608.5 189.8 97.2 328.2 Notes: MW = groundwater monitoring well mg/L = milligrams per liter S.U. = Standard Units uS/cm = microsiemens per centimeter oC = degrees Celsius NTU = Nephelometric Turbidity Units mV = millivolts -- = no data available Blanks = Field, trip, and laboratory blanks # = Data considered suspect due to instrument error August 2016 Page 1 of 6 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx Blanks SW-1 SW-2 SW-3 Antimony ug/L 05/07/02 --30 --ND --ND No SW Standard ug/L 06/29/07 --6 ND ND ND ND ug/L 12/13/07 --6 ND ND ND ND ug/L 06/19/08 --6 ND ND dry ND ug/L 12/02/08 --6 ND ND ND ND ug/L 06/11/09 --6 ND ND ND ND ug/L 12/10/09 --6 ND ND ND NDug/L 06/15/10 --6 ND ND ND NDug/L 12/09/10 --6 ND ND 0.503 J NDug/L 06/15/11 --6 ND ND ND NDug/L 12/06/11 --6 ND ND ND NDug/L 06/14/12 --6 ND ND ND NDug/L 12/03/12 --6 ND ND ND NDug/L 06/11/13 --6 ND ND ND NDug/L 12/02/13 --6 ND ND ND NDug/L 06/10/14 --6 ND ND ND NDug/L 12/03/14 0.22 6 ND ND ND NDug/L 06/08/15 0.22 6 ND ND ND NDug/L 12/02/15 0.22 6 ND ND ND ND ug/L 06/07/16 0.22 6 ND ND ND ND Arsenic ug/L 05/07/02 --10 --ND --ND Human Health SW Standard = 10 ug/L ug/L 08/07/02 --10 ----ND ND ug/L 06/16/03 --10 ND ND ND ND ug/L 12/16/03 --10 ND ND ND ND ug/L 06/16/04 --10 ND ND ND ND ug/L 12/16/04 --10 ND ND ND ND ug/L 06/14/05 --10 ND ND ND ND ug/L 12/27/05 --10 ND ND ND ND ug/L 06/21/06 --10 ND ND ND ND ug/L 12/13/06 --10 2.8 B 3.0 B 2.0 B 3.5 J ug/L 06/29/07 --10 3.7 J ND ND ND ug/L 12/13/07 --10 ND ND ND 2.5 Jug/L 06/19/08 --10 ND ND dry NDug/L 12/02/08 --10 ND ND ND NDug/L 06/11/09 --10 ND ND ND 3.5 Jug/L 12/10/09 --10 ND ND 5.15 J NDug/L 06/15/10 --10 ND ND ND NDug/L 12/09/10 --10 ND ND ND NDug/L 06/15/11 --10 3.09 J ND ND NDug/L 12/06/11 --10 ND ND ND NDug/L 06/14/12 --10 ND ND ND NDug/L 12/03/12 --10 ND ND ND NDug/L 06/11/13 --10 ND ND ND NDug/L 12/02/13 --10 ND ND ND ND ug/L 06/10/14 --10 ND ND ND ND ug/L 12/03/14 5.40 10 ND ND ND ND ug/L 06/08/15 5.40 10 ND ND ND ND ug/L 12/02/15 5.40 10 ND ND ND 9.10 J ug/L 06/07/16 5.40 10 ND ND ND ND Barium ug/L 05/07/02 --500 --ND --ND Human Health SW Standard = 200000 ug/L ug/L 08/07/02 --500 ----ND ND ug/L 06/16/03 --500 ND ND ND ND ug/L 12/16/03 --500 ND ND 230 ND ug/L 06/16/04 --500 ND ND ND ND ug/L 12/16/04 --500 ND ND ND ND ug/L 06/14/05 --500 ND ND ND ND ug/L 12/27/05 --500 ND ND ND ND ug/L 06/21/06 --500 ND ND ND NDug/L 12/13/06 --100 98.4 J 37.8 J 265 0.4 Jug/L 06/29/07 --100 28.2 B 28.8 B 232 10.4 Jug/L 12/13/07 --100 31.3 J 36.5 J 299 0.30 Jug/L 06/19/08 --100 31.8 J 32.0 J dry NDug/L 12/02/08 --100 36.0 J 40.8 J 271 NDug/L 06/11/09 --100 41.2 J 48.3 J 264 NDug/L 12/10/09 --100 46.0 J 43.9 J 190 NDug/L 06/15/10 --100 34.0 J 32.0 J 245 NDug/L 12/09/10 --100 29.6 J 32.6 J 277 1.72 Jug/L 06/15/11 --100 27.5 J 33.3 J 259 NDug/L 12/06/11 --100 31.6 J 34.5 J 277 ND ug/L 06/14/12 --100 35.2 J 37.9 J 263 ND ug/L 12/03/12 --100 27.1 J 33.2 J 266 ND ug/L 06/11/13 --100 53.6 J 54.0 J 107 4.59 J ug/L 12/02/13 --100 27.9 J 31.9 J 191 ND ug/L 06/10/14 --100 31.3 J 267 191 ND ug/L 12/03/14 1.00 100 36.2 J 38.2 J 188 ND ug/L 06/08/15 1.00 100 31.1 J 37.9 J 233 ND ug/L 12/02/15 1.00 100 32.5 J 39.8 J 162 3.35 J ug/L 06/07/16 1.00 100 97.8 J 46.1 J 175 ND TABLE 6 Summary of Detected Constituents in Surface WaterBrownfield Road Construction and Demolition Landfill, Permit No. 92-31Wake County, North Carolina Parameter Reporting Units Date SWS Reporting Limit Upstream DownstreamMDL August 2016 Page 2 of 6 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx Blanks SW-1 SW-2 SW-3 TABLE 6 Summary of Detected Constituents in Surface WaterBrownfield Road Construction and Demolition Landfill, Permit No. 92-31Wake County, North Carolina Parameter Reporting Units Date SWS Reporting Limit Upstream DownstreamMDL Beryllium ug/L 05/07/02 --2 --ND --ND Freshwater Acute SW Standard = 65 ug/L ug/L 06/29/07 --1 ND ND ND ND Freshwater Chronic SW Standard = 6.5 ug/L ug/L 12/13/07 --1 ND ND ND ND ug/L 06/19/08 --1 ND ND dry ND ug/L 12/02/08 --1 ND ND ND ND ug/L 06/11/09 --1 0.14 B 0.15 B 0.22 B 0.08 J ug/L 12/10/09 --1 0.114 J 0.154 J 0.592 J NDug/L 06/15/10 --1 ND ND ND NDug/L 12/09/10 --1 ND ND ND NDug/L 06/15/11 --1 ND ND 0.216 J NDug/L 12/06/11 --1 ND ND ND NDug/L 06/14/12 --1 ND 0.132 J 0.180 J NDug/L 12/03/12 --1 ND ND 0.104 J NDug/L 06/11/13 --1 0.133 J ND 0.176 J NDug/L 12/02/13 --1 ND ND 0.135 J NDug/L 06/10/14 --1 ND 0.757 J 0.133 J NDug/L 12/03/14 0.10 1 ND ND 0.275 J NDug/L 06/08/15 0.10 1 ND ND 0.344 J NDug/L 12/02/15 0.10 1 ND ND 0.169 J ND ug/L 06/07/16 0.10 1 0.464 J 0.177 J 0.183 J ND Cadmium ug/L 05/07/02 --1 --ND --ND Freshwater Acute SW Standard = 0.82 ug/L ug/L 08/07/02 --1 ----1.6 ND Freshwater Chronic SW Standard = 0.15 ug/L ug/L 06/16/03 --1 1.0 ND 1.1 ND ug/L 12/16/03 --1 ND ND ND ND ug/L 06/16/04 --1 ND ND ND ND ug/L 12/16/04 --1 ND ND ND ND ug/L 06/14/05 --1 ND ND ND ND ug/L 12/27/05 --1 ND ND ND ND ug/L 06/21/06 --1 ND ND ND ND ug/L 12/13/06 --1 ND ND ND ND ug/L 06/29/07 --1 ND ND ND ND ug/L 12/13/07 --1 ND ND ND NDug/L 06/19/08 --1 ND ND dry NDug/L 12/02/08 --1 ND ND ND NDug/L 06/11/09 --1 0.20 J ND 0.28 J NDug/L 12/10/09 --1 ND ND ND NDug/L 06/15/10 --1 ND ND ND NDug/L 12/09/10 --1 ND ND ND NDug/L 06/15/11 --1 ND ND ND NDug/L 12/06/11 --1 ND ND ND NDug/L 06/14/12 --1 2.15 0.732 J ND NDug/L 12/03/12 --1 ND ND ND NDug/L 06/11/13 --1 ND ND ND NDug/L 12/02/13 --1 ND ND ND ND ug/L 06/10/14 --1 ND ND ND ND ug/L 12/03/14 0.36 1 ND ND 1.64 ND ug/L 06/08/15 0.36 1 ND ND ND ND ug/L 12/02/15 0.36 1 ND ND ND ND ug/L 06/07/16 0.36 1 ND ND ND ND Chromium ug/L 05/07/02 --10 --ND --ND Freshwater Acute SW Standard = 180 ug/L ug/L 08/07/02 --10 ----ND ND Freshwater Chronic SW Standard = 24 ug/L ug/L 06/16/03 --10 ND ND ND ND ug/L 12/16/03 --10 ND ND ND ND ug/L 06/16/04 --10 ND ND ND ND ug/L 12/16/04 --10 ND ND ND ND ug/L 06/14/05 --10 ND ND ND ND ug/L 12/27/05 --10 ND ND ND ND ug/L 06/21/06 --10 ND ND ND NDug/L 12/13/06 --10 ND ND ND NDug/L 06/29/07 --10 ND ND ND NDug/L 12/13/07 --10 ND ND ND NDug/L 06/19/08 --10 ND ND dry NDug/L 12/02/08 --10 ND ND ND NDug/L 06/11/09 --10 1.1 J 1.2 J 0.7 J NDug/L 12/10/09 --10 1.70 J ND 3.41 J NDug/L 06/15/10 --10 ND 1.00 J ND NDug/L 12/09/10 --10 ND ND ND NDug/L 06/15/11 --10 ND ND ND NDug/L 12/06/11 --10 ND ND ND ND ug/L 06/14/12 --10 ND 1.18 J ND ND ug/L 12/03/12 --10 ND ND ND ND ug/L 06/11/13 --10 2.37 J 2.75 J 4.68 J ND ug/L 12/02/13 --10 ND ND ND ND ug/L 06/10/14 --10 ND ND ND ND ug/L 12/03/14 1.40 10 ND ND ND ND ug/L 06/08/15 1.40 10 ND ND ND ND ug/L 12/02/15 1.40 10 ND ND ND ND ug/L 06/07/16 1.40 10 ND 2.02 J ND ND August 2016 Page 3 of 6 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx Blanks SW-1 SW-2 SW-3 TABLE 6 Summary of Detected Constituents in Surface WaterBrownfield Road Construction and Demolition Landfill, Permit No. 92-31Wake County, North Carolina Parameter Reporting Units Date SWS Reporting Limit Upstream DownstreamMDL Cobalt ug/L 05/07/02 --10 --ND --ND No SW Standard ug/L 06/29/07 --10 ND ND ND ND ug/L 12/13/07 --10 ND ND ND ND ug/L 06/19/08 --10 ND ND dry ND ug/L 12/02/08 --10 ND ND ND ND ug/L 06/11/09 --10 0.7 J ND ND ND ug/L 12/10/09 --10 ND ND 3.20 J NDug/L 06/15/10 --10 ND ND ND NDug/L 12/09/10 --10 ND ND ND NDug/L 06/15/11 --10 ND ND ND NDug/L 12/06/11 --10 ND ND ND NDug/L 06/14/12 --10 ND ND ND NDug/L 12/03/12 --10 ND ND ND NDug/L 06/11/13 --10 1.63 J 1.16 J 1.58 J NDug/L 12/02/13 --10 ND ND ND NDug/L 06/10/14 --10 ND ND ND NDug/L 12/03/14 1.10 10 ND ND ND NDug/L 06/08/15 1.10 10 ND ND 1.87 J NDug/L 12/02/15 1.10 10 ND ND ND ND ug/L 06/07/16 1.10 10 ND ND ND ND Copper ug/L 05/07/02 --0.05 --ND --ND Freshwater Acute SW Standard = 3.6 ug/L ug/L 08/07/02 --0.05 ----ND ND Freshwater Chronic SW Standard = 2.7 ug/L ug/L 06/29/07 --10 ND ND ND ND ug/L 12/13/07 --10 ND ND ND ND ug/L 06/19/08 --10 1.60 B ND dry 1.30 J ug/L 12/02/08 --10 1.70 J ND ND ND ug/L 06/11/09 --10 2.02 J 1.03 J ND ND ug/L 12/10/09 --10 3.13 J 2.67 J 4.41 J ND ug/L 06/15/10 --10 ND ND ND ND ug/L 12/09/10 --10 ND ND ND ND ug/L 06/15/11 --10 ND ND ND ND ug/L 12/06/11 --10 ND ND ND NDug/L 06/14/12 --10 6.38 J 3.62 J ND NDug/L 12/03/12 --10 ND ND ND NDug/L 06/11/13 --10 3.63 J 3.34 J 3.90 J NDug/L 12/02/13 --10 ND ND ND NDug/L 06/10/14 --10 ND ND ND NDug/L 12/03/14 1.60 10 ND ND ND NDug/L 06/08/15 1.60 10 ND ND 2.06 B 3.34 Jug/L 12/02/15 1.60 10 ND ND ND 4.56 Jug/L 06/07/16 1.60 10 ND ND ND 1.87 JLead ug/L 05/07/02 --10 --ND --NDFreshwater Acute SW Standard = 14 ug/L ug/L 08/07/02 --10 ----ND NDFreshwater Chronic SW Standard = 0.54 ug/L ug/L 06/16/03 --10 ND ND ND ND ug/L 12/16/03 --10 ND ND ND ND ug/L 06/16/04 --10 ND ND ND NDug/L 12/16/04 --10 ND ND ND ND ug/L 06/14/05 --10 ND ND ND ND ug/L 12/27/05 --10 ND ND ND ND ug/L 06/21/06 --10 ND ND ND ND ug/L 12/13/06 --10 2.1 J ND 3.8 J ND ug/L 06/29/07 --10 ND ND ND ND ug/L 12/13/07 --10 ND ND ND ND ug/L 06/19/08 --10 ND ND dry ND ug/L 12/02/08 --10 ND ND ND ND ug/L 06/11/09 --10 2.5 J 3.5 J 2.2 J ND ug/L 12/10/09 --10 3.51 J ND 10.2 ND ug/L 06/15/10 --10 ND ND ND NDug/L 12/09/10 --10 ND ND ND NDug/L 06/15/11 --10 ND 2.15 J 1.96 J NDug/L 12/06/11 --10 ND ND ND NDug/L 06/14/12 --10 ND ND ND NDug/L 12/03/12 --10 ND ND ND NDug/L 06/11/13 --10 2.75 J 2.30 J 5.81 J NDug/L 12/02/13 --10 ND ND ND NDug/L 06/10/14 --10 ND ND ND NDug/L 12/03/14 2.10 10 ND ND ND NDug/L 06/08/15 2.10 10 ND ND 5.48 J NDug/L 12/02/15 2.10 10 ND ND ND ND ug/L 06/07/16 2.10 10 ND 4.27 J ND ND August 2016 Page 4 of 6 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx Blanks SW-1 SW-2 SW-3 TABLE 6 Summary of Detected Constituents in Surface WaterBrownfield Road Construction and Demolition Landfill, Permit No. 92-31Wake County, North Carolina Parameter Reporting Units Date SWS Reporting Limit Upstream DownstreamMDL Nickel ug/L 05/07/02 --50 --ND --ND Freshwater Acute SW Standard = 140 ug/L ug/L 08/07/02 --50 ----ND ND Freshwater Chronic SW Standard = 16 ug/L ug/L 06/29/07 --50 ND ND ND ND ug/L 12/13/07 --50 ND ND ND ND ug/L 06/19/08 --50 ND ND dry ND ug/L 12/02/08 --50 ND ND ND ND ug/L 06/11/09 --50 0.9 J 1.0 J 1.8 J NDug/L 12/10/09 --50 ND ND 2.94 J NDug/L 06/15/10 --50 ND ND ND NDug/L 12/09/10 --50 ND ND ND NDug/L 06/15/11 --50 ND ND ND NDug/L 12/06/11 --50 ND ND ND NDug/L 06/14/12 --50 ND ND ND NDug/L 12/03/12 --50 ND ND ND NDug/L 06/11/13 --50 2.08 J ND 3.25 J NDug/L 12/02/13 --50 ND ND ND NDug/L 06/10/14 --50 ND ND ND NDug/L 12/03/14 1.80 50 ND ND 3.00 J NDug/L 06/08/15 1.80 50 ND ND ND ND ug/L 12/02/15 1.80 50 ND ND ND ND ug/L 06/07/16 1.80 50 ND ND ND ND Selenium ug/L 05/07/02 --20 --ND --ND Freshwater Acute SW Standard = 5 ug/L ug/L 08/07/02 --20 ----ND ND Freshwater Chronic SW Standard = 5 ug/L ug/L 06/16/03 --20 ND ND ND ND ug/L 12/16/03 --20 ND ND ND ND ug/L 06/16/04 --20 ND ND ND ND ug/L 12/16/04 --20 ND ND ND ND ug/L 06/14/05 --20 ND ND ND ND ug/L 12/27/05 --20 ND ND ND ND ug/L 06/21/06 --20 ND ND ND ND ug/L 12/13/06 --10 2.8 B 4.1 B 3.1 B 4.5 J ug/L 06/29/07 --10 ND ND ND NDug/L 12/13/07 --10 ND ND ND NDug/L 06/19/08 --10 ND ND dry NDug/L 12/02/08 --10 ND ND ND NDug/L 06/11/09 --10 ND 4.8 J ND NDug/L 12/10/09 --10 ND ND ND NDug/L 06/15/10 --10 ND ND ND NDug/L 12/09/10 --10 ND ND 0.830 J NDug/L 06/15/11 --10 ND ND 1.15 J NDug/L 12/06/11 --10 ND ND ND NDug/L 06/14/12 --10 ND ND ND NDug/L 12/03/12 --10 ND ND ND NDug/L 06/11/13 --10 ND ND ND ND ug/L 12/02/13 --10 ND ND ND ND ug/L 06/10/14 --10 ND ND ND ND ug/L 12/03/14 5.00 10 ND ND ND ND ug/L 06/08/15 5.00 10 ND ND ND ND ug/L 12/02/15 5.00 10 ND ND ND ND ug/L 06/07/16 5.00 10 ND ND ND ND Thallium ug/L 05/07/02 --10 --ND --ND No SW Standard ug/L 06/29/07 --5.5 ND ND 0.042 J ND ug/L 12/13/07 --5.5 ND ND 0.041 J ND ug/L 06/19/08 --5.5 ND ND dry ND ug/L 12/02/08 --5.5 ND ND ND ND ug/L 06/11/09 --5.5 ND ND ND ND ug/L 12/10/09 --5.5 ND ND 0.173 J NDug/L 06/15/10 --5.5 ND ND ND NDug/L 12/09/10 --5.5 ND ND ND NDug/L 06/15/11 --5.5 ND ND ND NDug/L 12/06/11 --5.5 ND ND ND NDug/L 06/14/12 --5.5 ND ND ND 0.195 Jug/L 12/03/12 --5.5 ND ND ND NDug/L 06/11/13 --5.5 ND ND 0.113 J NDug/L 12/02/13 --5.5 ND ND ND NDug/L 06/10/14 --5.5 ND ND ND NDug/L 12/03/14 0.11 5.5 ND ND ND NDug/L 06/08/15 0.11 5.5 ND ND ND NDug/L 12/02/15 0.11 5.5 ND ND ND ND ug/L 06/07/16 0.11 5.5 ND ND ND ND August 2016 Page 5 of 6 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx Blanks SW-1 SW-2 SW-3 TABLE 6 Summary of Detected Constituents in Surface WaterBrownfield Road Construction and Demolition Landfill, Permit No. 92-31Wake County, North Carolina Parameter Reporting Units Date SWS Reporting Limit Upstream DownstreamMDL Vanadium ug/L 05/07/02 --40 --ND --ND No SW Standard ug/L 06/29/07 --25 1.9 J ND ND ND ug/L 12/13/07 --25 ND ND ND ND ug/L 06/19/08 --25 ND ND dry ND ug/L 12/02/08 --25 ND ND ND ND ug/L 06/11/09 --25 1.8 J 1.3 J 0.9 J ND ug/L 12/10/09 --25 3.52 J 2.22 J 8.66 J NDug/L 06/15/10 --25 ND ND ND NDug/L 12/09/10 --25 ND ND ND NDug/L 06/15/11 --25 1.43 J ND 1.75 J NDug/L 12/06/11 --25 ND ND ND NDug/L 06/14/12 --25 2.11 J 2.19 J ND NDug/L 12/03/12 --25 ND ND ND NDug/L 06/11/13 --25 6.94 J 6.42 J 6.73 J NDug/L 12/02/13 --25 ND ND ND NDug/L 06/10/14 --25 ND ND ND NDug/L 12/03/14 1.40 25 ND ND ND NDug/L 06/08/15 1.40 25 ND ND 2.34 J NDug/L 12/02/15 1.40 25 ND ND ND ND ug/L 06/07/16 1.40 25 ND 6.75 J ND ND Zinc ug/L 05/07/02 --50 --ND --ND Freshwater Acute SW Standard = 36 ug/L ug/L 08/07/02 --50 ----ND ND Freshwater Chronic SW Standard = 36 ug/L ug/L 06/29/07 --10 ND ND ND ND ug/L 12/13/07 --10 1.0 B 1.0 B 2.2 B 2.6 J ug/L 06/19/08 --10 1.1 B 1.4 B dry 1.0 J ug/L 12/02/08 --10 7.1 J ND ND ND ug/L 06/11/09 --10 11.0 B 38.8 B 7.8 B 8.4 J ug/L 12/10/09 --10 7.72 J 6.93 J 26.3 ND ug/L 06/15/10 --10 4.85 J ND 6.62 J ND ug/L 12/09/10 --10 ND ND ND ND ug/L 06/15/11 --10 ND ND 7.08 J ND ug/L 12/06/11 --10 ND 34.6 4.87 J NDug/L 06/14/12 --10 16.0 7.39 J 9.68 J NDug/L 12/03/12 --10 ND ND 3.80 J NDug/L 06/11/13 --10 12.1 12.2 12.0 NDug/L 12/02/13 --10 ND ND 4.36 J NDug/L 06/10/14 --10 ND 8.29 J ND NDug/L 12/03/14 3.80 10 4.07 J ND 7.52 J NDug/L 06/08/15 3.80 10 4.08 J ND 12.6 NDug/L 12/02/15 3.80 10 3.93 J ND 4.04 J NDug/L 06/07/16 3.80 10 ND ND ND NDAcetoneug/L 05/07/02 --100 --ND --NDSW Standard = 2000 ug/L ug/L 06/16/03 --100 ND ND ND NDug/L 12/16/03 --100 ND ND ND ND ug/L 06/16/04 --100 ND ND ND NDug/L 12/16/04 --100 ND ND ND NDug/L 06/14/05 --100 ND ND ND ND ug/L 12/27/05 --100 ND ND ND ND ug/L 06/21/06 --100 ND ND ND ND ug/L 12/13/06 --100 1.6 J ND ND ND ug/L 06/29/07 --100 ND ND ND 1.5 J ug/L 12/13/07 --100 ND ND ND ND ug/L 06/19/08 --100 ND ND dry ND ug/L 12/02/08 --100 ND ND ND ND ug/L 06/11/09 --100 ND ND ND ND ug/L 12/10/09 --100 ND ND ND ND ug/L 06/15/10 --100 ND ND ND NDug/L 12/09/10 --100 ND ND ND NDug/L 06/15/11 --100 ND ND ND NDug/L 12/06/11 --100 ND ND ND NDug/L 06/14/12 --100 ND ND ND NDug/L 12/03/12 --100 ND ND ND NDug/L 06/11/13 --100 ND ND ND NDug/L 12/02/13 --100 ND ND ND NDug/L 06/10/14 --100 ND ND ND 1.5 Jug/L 12/03/14 1.20 100 ND ND ND NDug/L 06/08/15 1.20 100 ND ND ND NDug/L 12/02/15 1.20 100 ND ND ND NDug/L 06/07/16 1.20 100 ND ND ND ND August 2016 Page 6 of 6 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx Blanks SW-1 SW-2 SW-3 TABLE 6 Summary of Detected Constituents in Surface WaterBrownfield Road Construction and Demolition Landfill, Permit No. 92-31Wake County, North Carolina Parameter Reporting Units Date SWS Reporting Limit Upstream DownstreamMDL Toluene ug/L 05/07/02 --5 --ND --ND SW Standard = 11 ug/L ug/L 06/16/03 --5 ND ND ND ND ug/L 12/16/03 --5 ND ND ND ND ug/L 06/16/04 --5 ND ND ND ND ug/L 12/16/04 --5 ND ND ND ND ug/L 06/14/05 --5 ND ND ND ND ug/L 12/27/05 --5 ND ND ND ND ug/L 06/21/06 --5 ND ND ND NDug/L 12/13/06 --5 ND ND ND NDug/L 06/29/07 --1 ND ND ND 0.63 Jug/L 12/13/07 --1 ND ND ND NDug/L 06/19/08 --1 ND ND dry NDug/L 12/02/08 --1 ND ND ND NDug/L 06/11/09 --1 ND ND ND NDug/L 12/10/09 --1 ND ND ND NDug/L 06/15/10 --1 0.41 J ND ND NDug/L 12/09/10 --1 ND ND ND NDug/L 06/15/11 --1 ND ND ND NDug/L 12/06/11 --1 ND ND ND ND ug/L 06/14/12 --1 ND ND ND ND ug/L 12/03/12 --1 ND ND ND ND ug/L 06/11/13 --1 ND ND ND ND ug/L 12/02/13 --1 ND ND ND ND ug/L 06/10/14 --1 ND ND ND ND ug/L 12/03/14 0.14 1 ND ND ND ND ug/L 06/08/15 0.14 1 ND ND ND ND ug/L 12/02/15 0.14 1 ND ND ND ND ug/L 06/07/16 0.14 1 ND ND ND ND Notes: SW = surface water monitoring point ug/L = micrograms per litermg/L = milligrams per literJ = estimated ValueB = blank-qualified dataND = not detected at or above the stated reporting limit-- = no data available dry = no flowing water at time of sampling and no sample was collectedMDL = Method Detection LimitBlanks = Field, trip, and laboratory blanksSW Standard = Surface Water Standard based on Class C Freshwater Aquatic Life Classification per 15 NCAC 2B.(A) = Action Level Standard per 15A NCAC 2B.0211(N) = Narrative Standard per 15A NCAC 2B.0211# = Data considered suspect due to instrument error Bold = Values are above their current respective NC Surface Water Chronic standard Shaded = Values are above their current respective NC Surface Water Standards under 15A NCAC 2B.0211 for Freshwater Aquatic Life classification or above their Acute SW Standard August 2016 Page 1 of 2 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx SW-1 SW-2 SW-3 pH S.U.08/07/02 ----5.76 S.U.12/13/06 6.10 6.09 5.90S.U.06/29/07 6.62 5.86 6.31 S.U.12/13/07 5.93 5.96 5.46S.U.06/19/08 6.66 6.69 dry S.U.12/02/08 6.60 6.56 6.82S.U.06/11/09 6.56 6.46 6.25 S.U.12/10/09 6.38 5.75 6.00S.U.06/15/10 6.32 6.51 6.62 S.U.12/09/10 5.78 5.78 5.65S.U.06/15/11 8.28 7.94 7.87 S.U.12/06/11 6.53 6.28 6.01S.U.06/14/12 6.47 6.73 6.45 S.U.12/03/12 4.64 5.59 8.48S.U.06/11/13 5.87 5.76 6.27 S.U.12/02/13 6.47 6.85 6.89S.U.06/10/14 6.38 6.17 6.03 S.U.12/03/14 5.66 5.14 5.25S.U.06/08/15 4.76 4.79 5.05 S.U.12/02/15 5.50 5.67 5.84S.U.06/07/16 5.30 6.16 5.55 Specific Conductance uS/cm 12/13/06 183 113 476uS/cm 06/29/07 71 81 454 uS/cm 12/13/07 119 145 626uS/cm 06/19/08 97 119 dry uS/cm 12/02/08 79 134 442 uS/cm 06/11/09 99 353 440uS/cm 12/10/09 63 183 274 uS/cm 06/15/10 87 126 438uS/cm 12/09/10 82 98 409 uS/cm 06/15/11 89 131 460uS/cm 12/06/11 83 91 451 uS/cm 06/14/12 77 147 405uS/cm 12/03/12 59 78 335 uS/cm 06/11/13 63 133 171uS/cm 12/02/13 108 108 366 uS/cm 06/10/14 111 438 376uS/cm 12/03/14 88 101 314 uS/cm 06/08/15 81 103 318uS/cm 12/02/15 79 123 274 uS/cm 06/07/16 195 121 323TemperatureoC12/13/06 12.8 10.6 11.2oC06/29/07 27.92 23.41 22.96oC12/13/07 15.22 14.57 15.72oC06/19/08 22.71 20.16 dryoC12/02/08 8.91 8.98 9.62oC06/11/09 24.98 23.07 20.52oC12/10/09 10.91 10.79 10.98oC06/15/10 26.00 22.70 22.02oC12/09/10 4.79 4.64 5.78oC06/15/11 23.25 19.85 20.63oC12/06/11 14.62 13.67 14.44oC06/14/12 21.19 19.97 18.06oC12/03/12 9.48 10.12 11.33oC06/11/13 22.07 24.19 23.22oC12/02/13 12.1 10.2 11.9oC06/10/14 24.2 19.4 18.9oC12/03/14 11.0 11.0 12.0oC06/08/15 21.2 20.0 20.2oC12/02/15 13.9 13.7 14.5oC06/07/16 18.5 22.2 21.0 TABLE 7 Summary of Field Parameters from Surface Water Monitoring Points Brownfield Road Construction and Demolition Landfill, Permit No. 92-31 Wake County, North Carolina Parameter Reporting Units Date Upstream Downstream August 2016 Page 2 of 2 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Tables\Wake Recovery Tables June 2016.xlsx SW-1 SW-2 SW-3 TABLE 7 Summary of Field Parameters from Surface Water Monitoring Points Brownfield Road Construction and Demolition Landfill, Permit No. 92-31 Wake County, North Carolina Parameter Reporting Units Date Upstream Downstream Turbidity (Field)NTU 12/13/06 4.2 11.4 16.3 NTU 06/29/07 8.7 0.0 80.5NTU12/13/07 0.0 0.0 39.5 NTU 06/19/08 35.2 20.1 dryNTU12/02/08 16.3 12.5 6.34 NTU 06/11/09 56.2 18.4 11.8NTU12/10/09 95.2 54.2 51.3 NTU 06/15/10 18.3 12.7 3.59NTU12/09/10 18.1 16.7 15.1 NTU 06/15/11 13.9 8.41 15.2NTU12/06/11 45.5 26.7 1.39 NTU 06/14/12 60.8 57.0 19.6NTU12/03/12 16.5 7.63 2.32 NTU 06/11/13 159 116 88.6NTU12/02/13 18.9 4.89 3.34 NTU 06/10/14 37.2 9.51 13.9NTU12/03/14 8.93 6.87 4.88 NTU 06/08/15 5.86 5.31 14.8NTU12/02/15 7.64 5.43 2.51 NTU 06/07/16 12.00 92.70 2.85Dissolved Oxygen mg/L 12/13/07 8.82 14.57 8.26 mg/L 06/19/08 7.66 8.54 drymg/L 12/02/08 8.23 10.83 9.33 mg/L 06/11/09 4.58 8.47 9.36mg/L 12/10/09 9.76 11.26 10.82 mg/L 06/15/10 4.51 8.58 8.93 mg/L 12/09/10 13.10 14.56 10.93mg/L 06/15/11 6.25 8.42 7.64 mg/L 12/06/11 9.71 11.29 9.69mg/L 06/14/12 7.25 8.98 9.14 mg/L 12/03/12 7.67 10.95 11.19mg/L 06/11/13 8.24 8.73 8.29 mg/L 12/02/13 11.16 11.59 9.78mg/L 06/10/14 7.24 8.77 9.36 mg/L 12/03/14 10.30 10.93 9.98mg/L 06/08/15 9.08 9.34 9.36 mg/L 12/02/15 8.80 9.52 8.51mg/L 06/07/16 -8.02 5.34 Oxidation-Reduction Potential mV 12/13/07 111 305 331mV06/19/08 26 64 dry mV 12/02/08 171.7 324.3 269.1mV06/11/09 62.5 207.3 192.6 mV 12/10/09 168.4 181.3 190.3mV06/15/10 130.2 106.3 120.3 mV 12/09/10 206.9 174.4 292.6mV06/15/11 179.2 119.6 98.0 mV 12/06/11 90.2 92.0 111.3mV06/14/12 -298.3#-295.1#-269.3# mV 12/03/12 77.7 77.6 83.4mV06/11/13 73.4 57.9 59.5 mV 12/02/13 135.8 177.6 201.4 mV 06/10/14 112.6 317.1 351.3mV12/03/14 203.4 258.0 237.4 mV 06/08/15 211.6 224.5 381.1mV12/02/15 387.2 394.4 421.0 mV 06/07/16 -275.8 483.1 Notes:SW = surface water monitoring point mg/L = milligrams per liter S.U. = Standard UnitsuS/cm = microsiemens per centimeter⁰C = Degrees CelsiusNTU = Nephelometric Turbidity Units mV = millivolts -- = no data available dry = no flowing water at time of sampling and no sample was collected Blanks = Field, trip, and laboratory blanks * = Standard is a National Criteria per EPA# = Data considered suspect due to instrument error FIGURES 10 12 14 16 18 20 22 24 0 100 200 300 400 500 600 Ch l o r i d e C o n c e n t r a t i o n s ( m g / L ) Ma g n e s i u m C o n c e n t r a t i o n s ( u g / L ) Magnesium Magnesium NC 2L Chloride MANGANESE AND CHLORIDE TREND GRAPH FOR MW-2 PROJECT No. XXXXXXX Rev FIGURE 1239643816 100 0 FIGURE 1 WASTE INDUSTRIES USA, INC. WATER QUALITY MONITORING REPORT BROWNFIELD ROAD C&D LANDFILL PERMIT NO. 92-31 CLIENT CONSULTANT PROJECT TITLE YYYY-MM-DD PREPARED DESIGN REVIEW APPROVED DYR DYR RPK RPK 2016-07-21 Path: g:\projects\waste industries\wake recovery\groundwater\wqmr\2016 june\figure\figure 1.docx | FileName: FIGURE 1.DOCX 3 3.5 4 4.5 5 5.5 6 6.5 7 0 100 200 300 400 500 600 06 / 0 1 / 0 7 09 / 0 1 / 0 7 12 / 0 1 / 0 7 03 / 0 1 / 0 8 06 / 0 1 / 0 8 09 / 0 1 / 0 8 12 / 0 1 / 0 8 03 / 0 1 / 0 9 06 / 0 1 / 0 9 09 / 0 1 / 0 9 12 / 0 1 / 0 9 03 / 0 1 / 1 0 06 / 0 1 / 1 0 09 / 0 1 / 1 0 12 / 0 1 / 1 0 03 / 0 1 / 1 1 06 / 0 1 / 1 1 09 / 0 1 / 1 1 12 / 0 1 / 1 1 03 / 0 1 / 1 2 06 / 0 1 / 1 2 09 / 0 1 / 1 2 12 / 0 1 / 1 2 03 / 0 1 / 1 3 06 / 0 1 / 1 3 09 / 0 1 / 1 3 12 / 0 1 / 1 3 03 / 0 1 / 1 4 06 / 0 1 / 1 4 09 / 0 1 / 1 4 12 / 0 1 / 1 4 03 / 0 1 / 1 5 06 / 0 1 / 1 5 09 / 0 1 / 1 5 12 / 0 1 / 1 5 03 / 0 1 / 1 6 06 / 0 1 / 1 6 pH ( S . U . ) Ma g n e s i u m C o n c e n t r a t i o n s ( u g / L ) Magnesium Magnesium NC 2L pH MANGANESE AND PH TREND GRAPH FOR MW-2 PROJECT No. XXXXXXX Rev FIGURE 1239643816 100 0 FIGURE 2 WASTE INDUSTRIES USA, INC. WATER QUALITY MONITORING REPORT BROWNFIELD ROAD C&D LANDFILL PERMIT NO. 92-31 CLIENT CONSULTANT PROJECT TITLE YYYY-MM-DD PREPARED DESIGN REVIEW APPROVED DYR DYR RPK RPK 2016-07-21 Path: g:\projects\waste industries\wake recovery\groundwater\wqmr\2016 june\figure\figure 1.docx | FileName: FIGURE 1.DOCX 3 4 5 6 7 8 9 10 0 500 1000 1500 2000 2500 3000 3500 4000 4500 5000 06 / 0 1 / 0 7 09 / 0 1 / 0 7 12 / 0 1 / 0 7 03 / 0 1 / 0 8 06 / 0 1 / 0 8 09 / 0 1 / 0 8 12 / 0 1 / 0 8 03 / 0 1 / 0 9 06 / 0 1 / 0 9 09 / 0 1 / 0 9 12 / 0 1 / 0 9 03 / 0 1 / 1 0 06 / 0 1 / 1 0 09 / 0 1 / 1 0 12 / 0 1 / 1 0 03 / 0 1 / 1 1 06 / 0 1 / 1 1 09 / 0 1 / 1 1 12 / 0 1 / 1 1 03 / 0 1 / 1 2 06 / 0 1 / 1 2 09 / 0 1 / 1 2 12 / 0 1 / 1 2 03 / 0 1 / 1 3 06 / 0 1 / 1 3 09 / 0 1 / 1 3 12 / 0 1 / 1 3 03 / 0 1 / 1 4 06 / 0 1 / 1 4 09 / 0 1 / 1 4 12 / 0 1 / 1 4 03 / 0 1 / 1 5 06 / 0 1 / 1 5 09 / 0 1 / 1 5 12 / 0 1 / 1 5 03 / 0 1 / 1 6 06 / 0 1 / 1 6 Ch l o r i d e C o n c e n t r a t i o n s ( m g / L ) Ma g n e s i u m C o n c e n t r a t i o n s ( u g / L ) Magnesium Magnesium NC 2L Chloride MANGANESE AND CHLORIDE TREND GRAPH FOR MW-4 PROJECT No. XXXXXXX Rev FIGURE 1239643816 100 0 FIGURE 3 WASTE INDUSTRIES USA, INC. WATER QUALITY MONITORING REPORT BROWNFIELD ROAD C&D LANDFILL PERMIT NO. 92-31 CLIENT CONSULTANT PROJECT TITLE YYYY-MM-DD PREPARED DESIGN REVIEW APPROVED DYR DYR RPK RPK 2016-07-21 Path: g:\projects\waste industries\wake recovery\groundwater\wqmr\2016 june\figure\figure 1.docx | FileName: FIGURE 1.DOCX 3 3.5 4 4.5 5 5.5 6 0 500 1000 1500 2000 2500 3000 3500 4000 4500 5000 06 / 0 1 / 0 7 09 / 0 1 / 0 7 12 / 0 1 / 0 7 03 / 0 1 / 0 8 06 / 0 1 / 0 8 09 / 0 1 / 0 8 12 / 0 1 / 0 8 03 / 0 1 / 0 9 06 / 0 1 / 0 9 09 / 0 1 / 0 9 12 / 0 1 / 0 9 03 / 0 1 / 1 0 06 / 0 1 / 1 0 09 / 0 1 / 1 0 12 / 0 1 / 1 0 03 / 0 1 / 1 1 06 / 0 1 / 1 1 09 / 0 1 / 1 1 12 / 0 1 / 1 1 03 / 0 1 / 1 2 06 / 0 1 / 1 2 09 / 0 1 / 1 2 12 / 0 1 / 1 2 03 / 0 1 / 1 3 06 / 0 1 / 1 3 09 / 0 1 / 1 3 12 / 0 1 / 1 3 03 / 0 1 / 1 4 06 / 0 1 / 1 4 09 / 0 1 / 1 4 12 / 0 1 / 1 4 03 / 0 1 / 1 5 06 / 0 1 / 1 5 09 / 0 1 / 1 5 12 / 0 1 / 1 5 03 / 0 1 / 1 6 06 / 0 1 / 1 6 pH ( S . U . ) Ma g n e s i u m C o n c e n t r a t i o n s ( u g / L ) Magnesium Magnesium NC 2L pH MANGANESE AND PH TREND GRAPH FOR MW-4 PROJECT No. XXXXXXX Rev FIGURE 1239643816 100 0 FIGURE 4 WASTE INDUSTRIES USA, INC. WATER QUALITY MONITORING REPORT BROWNFIELD ROAD C&D LANDFILL PERMIT NO. 92-31 CLIENT CONSULTANT PROJECT TITLE YYYY-MM-DD PREPARED DESIGN REVIEW APPROVED DYR DYR RPK RPK 2016-07-21 Path: g:\projects\waste industries\wake recovery\groundwater\wqmr\2016 june\figure\figure 1.docx | FileName: FIGURE 1.DOCX DRAWING 220 200 2 2 0 26 0 27 0 28 0 2 3 0 24 0 25 0 260 270 280 290 230 240 250 210 220 230 24 0 25 0 26 0 23 0 240 260 270 280 250 25 0 270 260 250 250 26 0 27 0 28 0 29 0 25 0 29 0 26 0 27 0 28 0 29 0 23 0 24 0 25 0 2 1 0 2 2 0 2 2 0 2 3 0 260 270 240 250 220 230 280 280 29 0 28 0 29 0 2 6 0 2 7 0 28 0 260 250 260 270 280 270 260 270 250 280 2 7 0 2 6 0 2 5 0 260 25 0 2 7 0 270 250 260 24 0 25 0 260240 250 26 0 27 0 280 25 0 27 0 25 0 290 WE 200.5' WE 244.5' i1 i2 i3 FUTURE SOUTHERN DISPOSAL AREA FUTURE DISPOSAL AREA PHASE 1 (19 ACRES) 250 240 23 0 220 21 0 19 0 190 200 210 220 240 250 200 230 LFG-6 LFG-7 BH-1 BH-2 BH-3 BH-4 LFG-5 LFG-9 LFG-8 LFG-10 SITE LOCATION MW-3 MW-2 MW-4 MW-5 SW-1 SW-2 SW-3 MW-1 195.89 191.19 191.86 192.86 256.43 GAS VENT 2 MW-6Ad MW-6As MW-7AD MW-7AS223.76 207.41207.32 223.88 GAS VENT 1 CONSULTANT DESIGN PREPARED REVIEW APPROVED YYYY-MM-DD TITLE PROJECT No.Rev. PROJECTCLIENT Pa t h : \\ g r e e n s b o r o \ C A D \ _ 2 0 1 2 \ 1 2 3 9 6 4 3 8 - W I - W a k e R e c o v e r y \ P R O D U C T I O N \ _ F - 2 0 1 6 G W \ | F i l e N a m e : 12 3 9 6 4 3 8 1 6 F 0 0 1 . d w g IF T H I S M E A S U R E M E N T D O E S N O T M A T C H W H A T I S S H O W N , T H E S H E E T S I Z E H A S B E E N M O D I F I E D F R O M : A N S I D 0 1 i n 1239643816 PHASE 100 DRAWING 10 2016-07-08 BSD TJM DYR RPK WAKE RECLAMATION, LLC BROWNFIELD ROAD C&D LANDFILL WAKE COUNTY, NORTH CAROLINA WASTE INDUSTRIES USA, INC. GROUNDWATER CONTOUR MAP JUNE 7, 2016 EXISTING 10-FOOT GROUND SURFACE CONTOUR EXISTING 2-FOOT GROUND SURFACE CONTOUR PROPERTY LINE APPROXIMATE LIMITS OF WASTE EXISTING ROAD LANDFILL GAS MONITORING POINT GROUNDWATER MONITORING POINT AND GROUNDWATER ELEVATION SURFACE WATER MONITORING POINT LANDFILL GAS VENT GROUNDWATER SURFACE CONTOURS APPROXIMATE GROUNDWATER FLOW SEGMENT USED TO CALCULATE GRADIENT TREELINE TOPOGRAPHIC DIVIDING LINE (SEE NOTE 10) 250 i1 MW-1 SW-3 256.43 1) TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET 2) GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET 3) GROUNDWATER ELEVATIONS MEASURED ON JUNE 7, 2016. 4) GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION BETWEEN AND EXTRAPOLATION FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWN FIELD CONDITIONS. THEREFORE, GROUNDWATER CONTOURS MAY NOT REFLECT ACTUAL CONDITIONS. 5) GROUNDWATER CONTOUR LINES SHOW THE WATER TABLE SHAPE AND ELEVATION. THESE CONTOURS ARE INFERRED LINES FOLLOWING THE GROUNDWATER SURFACE AT A CONSTANT ELEVATION ABOVE SEA LEVEL. THE GROUNDWATER FLOW DIRECTION IS GENERALLY PERPENDICULAR TO THE GROUNDWATER SURFACE CONTOURS, SIMILAR TO THE RELATIONSHIP BETWEEN SURFACE WATER FLOW AND TOPOGRAPHIC CONTOURS. 6) BASE MAP PROVIDED BY RICHARDSON SMITH GARDNER & ASSOCIATES. TOPOGRAPHY PROVIDED FROM AERIAL SURVEYS PREPARED BY SURVEY SOLUTIONS P.C., PHOTOGRAPHY DATES JANUARY 7, 2015 AND FEBRUARY 05, 2014. 7) LANDFILL GAS MONITORING POINTS AND SURFACE WATER MONITORING POINT LOCATIONS ARE APPROXIMATE. 8) ELEVATIONS SHOWN IN THIS DRAWING ARE IN FEET ABOVE SEA LEVEL DATUM ("SEA LEVEL DATUM" REFERS TO THE NATIONAL GEODETIC VERTICAL DATUM (NGVD) OF 1929); AND COORDINATES ARE EXPRESSED IN TERMS OF THE STATE PLANE COORDINATE SYSTEM. 9) GROUNDWATER ELEVATIONS FOR MW-6AD AND MW-7AD WERE NOT USED IN THE CONSTRUCTION OF THE GROUNDWATER CONTOURS SINCE THESE WELLS ARE SCREENED IN THE BEDROCK AQUIFER. 10) TOPOGRAPHIC DIVIDING LINE SEPARATES BASE MAP TOPOGRAPHIC CONTOURS FROM UPDATED CONTOURS. GAS VENT 1 LFG-5 0 FEET 200 400 SCALE LEGEND NOTES PG C-399 GOLDER ASSOCIATES NC, INC. APPENDIX A GROUNDWATER AND SURFACE WATER SAMPLING LOGS Caption Text APPENDIX B JUNE 2016 GROUNDWATER AND SURFACE WATER CERTIFICATE-OF-ANALYSIS, CHAIN-OF-CUSTODY FORMS, AND LABORATORY DATA REVIEWS Caption Text Page 1 of 68 Page 2 of 68 Page 3 of 68 Page 4 of 68 Page 5 of 68 Page 6 of 68 Page 7 of 68 Page 8 of 68 Page 9 of 68 Page 10 of 68 Page 11 of 68 Page 12 of 68 Page 13 of 68 Page 14 of 68 Page 15 of 68 Page 16 of 68 Page 17 of 68 Page 18 of 68 Page 19 of 68 Page 20 of 68 Page 21 of 68 Page 22 of 68 Page 23 of 68 Page 24 of 68 Page 25 of 68 Page 26 of 68 Page 27 of 68 Page 28 of 68 Page 29 of 68 Page 30 of 68 Page 31 of 68 Page 32 of 68 Page 33 of 68 Page 34 of 68 Page 35 of 68 Page 36 of 68 Page 37 of 68 Page 38 of 68 Page 39 of 68 Page 40 of 68 Page 41 of 68 Page 42 of 68 Page 43 of 68 Page 44 of 68 Page 45 of 68 Page 46 of 68 Page 47 of 68 Page 48 of 68 Page 49 of 68 Page 50 of 68 Page 51 of 68 Page 52 of 68 Page 53 of 68 Page 54 of 68 Page 55 of 68 Page 56 of 68 Page 57 of 68 Page 58 of 68 Page 59 of 68 Page 60 of 68 Page 61 of 68 Page 62 of 68 Page 63 of 68 Page 64 of 68 Page 65 of 68 Page 66 of 68 Page 67 of 68 Page 68 of 68 Page 1 of 1 GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 1 of 5 Project Name: Waste Industries – Wake Recovery Project Reference Number: 1239643816.100 Sampling Event Date: June 7-8, 2016 Review Date: June 14, 2016 Initials: WB Report #: CZ07139 Person(s) performing the review are to initial each item on this form as acknowledgement of data acceptance, or as acknowledgement of a review issue. In the case of the latter, a brief explanation should follow the applicable item. Golder Associates Inc. has reviewed the laboratory certificates of analysis, chain-of-custody form, and laboratory provided sample group quality assurance and quality control data for the above referenced sample group to identify potential bias or inaccuracy, in general accordance with the following United States Environmental Protection Agency documents: • Region III Modifications to Functional Guidelines for Organic Data Review Multi-Media, Multi- Concentration, September 1994; • Region III Modifications to the Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, April 1993; and • Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, July 1998. COMPLIANCE ANALYTE LIST(S) (check all that apply) NC Closed Facility List (.500 Rules) NC C & D List (New Rules) X NC Appendix I NC Appendix I + Detects NC Appendix II NC Subtitle D Leachate List Other: 1.0 CHAIN OF CUSTODY (COC) REVIEW WB COC was properly signed by all parties. WB Correct project name and number are on the form. WB Sample receipt condition at laboratory was acceptable. WB Each sample and blank submitted for analysis appears in the report. GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 2 of 5 2.0 SAMPLE HOLDING TIMES WB Holding times for extraction and/or analysis were met for each analytical method (see below for reference). Notes: Review Criteria Method Analytes Holding Time SW-846 Method 8260 and 8011 VOCs 14 days SW-846 Methods 8270, 8080, 8081, 8082, and 8151 SVOCs, PCBs, pesticides and herbicides 7 days for extraction, 40 days from extraction for analysis SW-846 Methods 6000 and 7000 Series Metals except mercury 6 months (no temperature requirements) SW-846 Method 7470 Mercury 28 days SW-846 Method 376.1 Sulfide 7 days SW-846 Method 9010 Cyanide 14 days EPA Method 300 Nitrate/Sulfate 48 hours/28 days EPA Method 405.1 BOD 48 hours EPA Method 410.4 COD 28 days EPA Method 365.4 Phosphorous 28 days 3.0 LABORATORY QUALITY CONTROL REVIEW WB Laboratory analyzed at least one internal blank for each method, where applicable. WB Laboratory blank is interference-free. WB Surrogate recoveries are provided for each analytical method, where applicable. WB Surrogate recoveries for each method are within the acceptable limits (i.e., at least 50% of the surrogates were within range). WB MS/MSD/LCS data results are provided for each analytical method. WB MS/MSD/LCS recoveries for each method are within the acceptable limits (i.e., at least 1 of the 3 were within range).  The spike recovery of Chlorobenzene was outside of control limits for the 8260B MSD sample. The QC batch was approved based on acceptable LCS recovery of this analyte.  The spike recovery of Mercury was outside of control limits for the Post Spike sample. The QC batch was approved based on acceptable LCS recovery of this element. GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 3 of 5  The spike recovery of Sulfate was outside of control limits for the MS sample. The QC batch was approved based on acceptable LCS recovery of this analyte. 4.0 ANALYTE LISTS/METHODS WB The proper number of constituents are present for each analyte list as identified above (including detects where applicable). WB Proper EPA SW-846 analytical methods were used for analysis. 5.0 DATA REPORTING WB All analytical reporting associated with the event was performed by the contracted lab. WB Trip, field and/or equipment, and laboratory blank results have all been reported. All detects for blanks are listed below by constituent. All laboratory method blanks, if any, have been ‘flagged’ with a ‘B’ where detected in other samples as appropriate and a laboratory narrative was provided. If the sample was flagged by the laboratory and is not within 5X of the concentration in the blank (or 10X for commonly detected laboratory contaminants-acetone, methylene chloride and phthalates), list below with explanation if flags should be removed. If flags need to be added for samples, also list below.  Field Blank o Copper @ 1.87 ug/L (J)  B Flag o MW-1 Copper @ 2.00 ug/L (J)  Trip Blank o Tetrahydrofuran @ 3.1 ug/L WB It is clear from the laboratory report that samples have or have not been diluted during analysis, and if the samples have been diluted, the result is reported as a multiple of the dilution (e.g., a sample diluted 10x resulting in an analytical detection of 1.0 should be reported as 10). Those that have been diluted are listed below with the dilution factor.  MW-2, Sulfate (2x) WB The report provides the reporting limit for each constituent. WB The results were reported at or below their proper reporting limits (e.g., NC Solid Waste Section Approved QLs). Those that are not reported correctly are listed below (by constituent) with the proper reporting limit listed beside them. State if the reporting limit error is due to dilutions. GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 4 of 5  Barium (NC SWSL = 100 ug/L) o MW-1 @ 210 ug/L o MW-2 @ 182 ug/L o MW-3 @ 252 ug/L o MW-4 @ 146 ug/L  Beryllium (NC SWSL = 1 ug/L) o MW-2 @ 4.63 ug/L o MW-4 @ 1.73 ug/L o MW-5 @ 3.12 ug/L  Iron (NC SWSL = 300 ug/L) o MW-4 @ 1920 ug/L o MW-5 @ 36800 ug/L  Manganese (NC SWSL = 50 ug/L) o MW-1 @ 71.9 ug/L o MW-2 @ 544 ug/L o MW-3 @ 76.3 ug/L o MW-4 @ 4700 ug/L o MW-5 @ 162 ug/L  Mercury (NC SWSL = 0.2 ug/L) o MW-3 @ 1.94 ug/L  Vanadium (NC SWSL = 10 ug/L) o MW-5 @ 11.5 ug/L WB No inorganic or organic constituents were reported above their respective NC 2L Drinking Water Standards or Groundwater Protection Standards in wells or field/equipment/trip blanks or Surface Water Standards for surface points  Beryllium (SWS GWPS = 4 ug/L) o MW-2 @ 4.63 ug/L  Cobalt (SWS GWPS = 1 ug/L) o MW-1 @ 6.39 ug/L o MW-3 @ 1.53 ug/L (J) o MW-4 @ 3.55 ug/L  Iron (NC 2L = 300 ug/L) o MW-4 @ 1920 ug/L o MW-5 @ 36800 ug/L  Manganese (NC 2L = 50 ug/L) o MW-1 @ 71.9 ug/L o MW-2 @ 544 ug/L o MW-3 @ 76.3 ug/L o MW-4 @ 4700 ug/L o MW-5 @ 162 ug/L  Vanadium (SWS GWPS = 0.3 ug/L) o MW-5 @ 11.5 ug/L o SW-2 @ 6.75 ug/L GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 5 of 5 WB No inorganic and organic constituents were detected in a well or surface water point at concentrations outside of their historical range (more than 5X previous concentrations or first-time detections). WB Other report issues/Communications with laboratory/etc.:  Tetrahydrofuran was detected in the 8260B Trip Blank, however, this analyte was not detected in any of the other samples submitted under this project. APPENDIX C STATISTICAL EVALUATION WORKSHEETS & SUMMARY TABLES Caption Text August 2016 1 of 1 1239-643816.100 G:\Projects\Waste Industries\Wake Reclamation\Groundwater\WQMR\2016 June\Stats\Wake Stats Summary June 2016.xls MW-3 MW-5 MW-6As Interwell Nonparametric Prediction Limit 1.04 MW-2 Intrawell Upper Tolerance Limit 5.24 Interwell Nonparametric Prediction Limit 0.262 MW-3 Intrawell Upper Tolerance Limit 2.37 Interwell Nonparametric Prediction Limit 3780 MW-5 Intrawell Upper Tolerance Limit 56181 Interwell Upper Prediction Limit 148 MW-2 Intrawell Upper Tolerance Limit 506 MW-4 Intrawell Upper Tolerance Limit 2736 MW-5 Intrawell Upper Tolerance Limit 179 Notes: 1. Shaded values represent apparent statistically significant increases (SSIs) over background concentrations. 2. Statistical worksheets are provided as Appendix C. 3. ug/L = micrograms per liter 4. ND = Not Detected 5. J = estimated concentration below the Solid Waste Section Limit 6. * = dissolved beryllium concentration Reporting Units Prediction Interval 1.94 .658 J MW-2 MW-4 162 13.5 J 234 J Manganese ug/L 544 76.3 4700 36800 0.936 J ug/LIron ND NDMercuryug/L ND Summary of Statistical Analysis Brownfield Road Construction and Demolition Landfill, Permit No. 92-31 Wake County, North Carolina Downgradient Monitoring Wells and Concentrations 3.12Berylliumug/L Detected Monitoring Constituent/Analytes Statistical Evaluation Method June 2016 539*4570* 4.63 ND ND 1920 ND 1.73 APPENDIX D SOIL AND STREAM SEDIMENT DATA Caption Text Guidance for Developing Eco-SSLs November 20032 - 9 Table 2.3. Mean Reported Soil Metal Background Concentrations (mg/kg dry weight) by State* Al u m i n u m An t i m o n y Ar s e n i c Ba r i u m Be r y l l i u m Ca d m i u m Ch r o m i u m Co b a l t Co p p e r Ir o n Ma n g a n e s e Ni c k e l Le a d Se l e n i u m Si l v e r Va n a d i u m Zi n c Alabama 23100 3.6 4.7 200 0.6 30.6 4.4 9.6 11950 420 11 9.3 0.3 38 26 Arkansas 33429 1.2 9.7 336 0.9 53.1 12 17 19857 731 18 21 0.7 52 39 Arizona 32933 1.4 9.6 364 1.0 0.4 37.3 9.9 23 20787 447 23 16 0.4 0.5 42 51 California 75633 0.8 5.1 598 1.1 0.4 119.9 14 39 36867 640 48 26 0.2 0.8 118 113 Colorado 61557 1.1 6.7 662 1.4 41.7 6.8 21 23048 343 13 31 0.4 74 87 Connecticut 85000 4.1 400 0.5 40.0 7.5 15 17500 450 13 5.0 0.8 60 40 Delaware 22500 1.0 1.4 400 0.5 30.0 3.3 5.0 7500 85 6.0 15 0.3 20 23 Florida 9944 0.9 3.0 48 0.6 0.1 15.4 1.6 5.6 3705 86 8.5 12 0.3 0.5 11 12 Georgia 38250 1.0 5.0 232 0.6 32.4 6.9 21 16976 252 17 19 0.4 43 47 Iowa 64667 1.0 7.3 617 1.3 64.7 11 31 23278 603 26 19 0.4 97 57 Idaho 58500 1.0 6.4 757 1.1 52.1 12 28 32000 580 22 22 0.3 90 83 Illinois 48714 1.1 7.1 551 0.7 48.4 9.8 24 19159 646 19 39 0.5 62 67 Indiana 50000 1.0 7.5 500 0.7 46.8 10 27 21364 518 18 18 0.4 74 56 Kansas 61818 1.1 6.8 694 1.0 49.0 8.9 25 18788 452 17 32 0.4 77 67 Kentucky 54123 1.0 7.8 349 1.1 79.8 11 17 30432 483 23 16 0.5 66 35 Louisiana 42188 1.0 7.6 441 0.6 60.8 8.6 33 19688 470 33 16 0.7 76 55 Massachusetts 34083 1.0 8.6 203 1.3 0.2 39.5 7.8 16 19000 439 13 13 1.9 87 54 Maryland 39167 1.2 3.8 393 1.3 47.9 7.5 20 28571 291 13 22 0.2 63 39 Maine 65385 1.0 9.4 319 1.6 71.2 10 28 45385 581 30 19 0.7 98 80 Michigan 10964 1.3 4.2 127 0.7 0.9 13.8 4.6 12 10520 230 12 9.2 0.3 0.5 44 33 Minnesota 49457 1.0 5.5 571 0.7 0.3 25.4 7.2 20 19581 583 14 9.9 0.3 72 38 Missouri 42094 1.0 10 499 1.0 50.0 12 19 24733 940 20 23 0.5 72 53 Mississippi 45368 1.0 8.8 390 0.9 53.2 12 20 19684 471 21 18 0.5 68 45 Montana 70938 1.1 8.8 739 1.1 63.3 7.5 29 27766 366 20 14 0.4 101 69 Nebraska 59474 1.0 5.5 711 1.1 32.5 5.9 15 16000 306 15 16 0.4 62 54 North Carolina 60105 1.0 4.8 356 0.6 64.8 15 34 37053 563 24 17 0.4 107 56 North Dakota 62857 1.0 7.0 682 0.9 53.2 6.9 23 25357 530 20 13 0.4 83 64 New Hampshire 66667 4.4 500 2.3 0.6 18.4 5.3 12 33333 633 10 28 0.3 57 23 New Jersey 10075 1.4 7.0 54 0.3 0.3 13.9 1.7 14 11632 221 3.8 35 0.9 30 22 New Mexico 54423 1.0 5.9 727 1.0 55.5 8.8 21 20898 367 28 18 0.3 72 44 Nevada 66078 1.0 9.0 822 1.3 36.8 8.4 25 22725 481 15 25 0.3 78 69 New York 58800 1.0 6.4 666 1.4 0.2 66.9 9.1 36 38900 418 21 20 0.3 132 82 Ohio 54615 12 469 1.0 55.0 13 28 27308 550 25 23 0.6 88 69 Oklahoma 39200 1.0 7.0 430 1.1 46.0 7.1 16 19320 465 15 18 0.3 50 50 Oregon 94412 1.2 5.1 682 0.9 121.6 16 53 50147 725 23 15 0.3 168 70 Pennsylvania 63438 1.0 13 366 1.4 52.8 15 37 36063 609 24 23 0.5 80 81 Rhode Island 100000 3.5 500 0.5 50.0 10 15 30000 500 15 15 0.9 70 30 South Carolina 39143 3.9 151 1.4 21.4 3.5 16 12500 87.1 7.8 5.0 0.3 45 25 South Dakota 74333 1.3 8.5 1043 1.4 58.7 7.7 29 25667 1013 28 16 0.5 108 75 Tennessee 31894 0.7 16 193 0.8 0.2 40.3 14 17 28479 1112 18 23 0.6 1.2 49 57 Texas 41958 1.1 6.4 404 0.9 39.6 5.3 15 16328 303 12 14 0.3 52 39 Utah 45638 1.1 8.0 493 0.9 45.6 6.6 26 18830 371 13 35 0.3 70 96 Virginia 60438 1.2 5.1 436 0.9 54.3 9.7 33 27750 441 17 36 0.4 77 233 Vermont 56667 3.6 333 1.7 66.7 12 18 30000 800 25 20 0.4 70 43 Washington 66834 1.0 4.5 606 0.9 0.8 49.9 18 31 42635 760 23 14 0.3 0.7 160 78 Wisconsin 48000 1.0 4.4 543 2.0 40.3 7.7 12 15667 365 14 12 0.3 48 44 West Virginia 67000 1.3 8.6 360 1.0 46.0 14 22 28500 770 23 17 0.5 65 60 Wyoming 56125 1.1 6.5 756 0.7 47.9 8.3 21 25250 416 16 17 0.5 84 57 * Summary of background soil concentration data provided as Attachment 1-4. Show data for sample C-110278 http://mrdata.usgs.gov/geochem/show.php?labno=C-110278[7/25/2016 3:06:23 PM] USGS Home Contact USGS Search USGS Mineral Resources On-Line Spatial Data Mineral Resources > Online Spatial Data > National Geochemical Survey Database Data for C-110278 Report shows selected fields. [Full report] Show this location using [Google Earth] or [Google Maps] Sample identification NURE record ID 5286678 Lab identification number C-110278 Sample set NURE800 Database join ID Sample category NURE Short description of sample type STRM-SED-DRY Geographic location Map datum NAD27 Latitude 35.5422 Longitude -78.5658 1:24k quadrangle 36080NED4 1:250k quadrangle 36080 1:100,000 quadrangle 36080NE FIPS of county f37101 Hydrologic unit 03020201 1:250k quad name Raleigh Zip code, 3-digit 275 Congressional district 3702C2 Sample characteristics Real field name NCJO041S1 Collection date 19760831 Description NURE sample Sample type code 750 Soil horizon Show data for sample C-110278 http://mrdata.usgs.gov/geochem/show.php?labno=C-110278[7/25/2016 3:06:23 PM] Color of reanalyzed powder Sample grain size Sample medium Sediment Sample source Stream Source modifier Dry Upper limit of sieve size 150 Drying procedure <110oC Sample type note Original NURE code was 50, but stream was dry Site characteristics Setting Active channel width dry Water depth dry Water color other Flow stage dry Flow rate dry Stream bed sand Contamination source unknown Contamination potential Contamination degree Vegetation deciduous pH of water Sample characteristics (details) Lab grain size Collector 57 Primary ID NCJO041S1 LANL field name ORGDP field name SRNL field name NCJO041S1 LLNL field name Other name info QA/QC info Replicate codes 000 Conductivity meas. in lab No. grabs 5 Show data for sample C-110278 http://mrdata.usgs.gov/geochem/show.php?labno=C-110278[7/25/2016 3:06:23 PM] Collection hour Est. %organics Study code Odor Site characteristics (details) Photographs Flood plain width Relief low Geologic formation Geologic unit Total alkalinity of water Dissolved oxygen (ppm) Gamma activity Air temperature Water temperature Conductivity of water Stream velocity (m/s) Stream channel depositing Weather sunny/clear Vegetation density moderate Rock type Rock color Analyses by ICP/Acid dissolution ICP40 job GF42 Al (wt%)0.73 Ca (wt%)0.03 Fe (wt%)0.66 K (wt%)0.14 Mg (wt%)0.04 Na (wt%)0.02 P (wt%)0.01 Ti (wt%)0.49 Ag (ppm)< 2 As (ppm)< 10 Au (ppb)< 8 Show data for sample C-110278 http://mrdata.usgs.gov/geochem/show.php?labno=C-110278[7/25/2016 3:06:23 PM] Ba (ppm)44 Be (ppm)< 1 Bi (ppm)14 Cd (ppm)< 2 Ce (ppm)31 Co (ppm)< 2 Cr (ppm)< 2 Cu (ppm)3 Eu (ppm)1 Ga (ppm)< 4 Ho (ppm)< 4 La (ppm)10 Li (ppm)4 Mn (ppm)146 Mo (ppm)< 2 Nb (ppm)< 4 Nd (ppm)< 9 Ni (ppm)3 Pb (ppm)17 Sc (ppm)< 2 Sn (ppm)31 Sr (ppm)8 Ta (ppm)< 40 Th (ppm)6 U (ppm)< 100 V (ppm)17 Y (ppm)2 Yb (ppm)< 1 Zn (ppm)15 Cs (ppm) Rb (ppm) Sb (ppm) Zr (ppm) Analyses by AA As job number GF42 Show data for sample C-110278 http://mrdata.usgs.gov/geochem/show.php?labno=C-110278[7/25/2016 3:06:23 PM] As (ppm)1.3 Se job number GF42 Se (ppm)< 0.2 Hg job number GF42 Hg (ppm)0.03 Sb job number Sb (ppm) Te job number Te (ppm) Tl job number Tl (ppm) W job number W (ppm) Au job number Au (ppb) Pd-Pt job number Pd (ppb) Pt (ppb) Analyses by ICP Partial Chem ICP10 job number GF42 Ag (ppm)< 0.08 As (ppm)< 1 Au (ppb)< 0.1 Bi (ppm)< 1 Cd (ppm)< 0.05 Cu (ppm)2.7 Mo (ppm)0.2 Pb (ppm)8 Sb (ppm)< 1 Zn (ppm)13.3 Ga (ppm) Hg (ppm) Se (ppm) Te (ppm) Tl (ppm) Show data for sample C-110278 http://mrdata.usgs.gov/geochem/show.php?labno=C-110278[7/25/2016 3:06:23 PM] Analyses by Fusion ICP ICP16 job number Al (wt%) Ca (wt%) Fe (wt%) K (wt%) Mg (wt%) Na (wt%) P (wt%) Si (wt%) Ti (wt%) Ba (ppm) Cr (ppm) Mn (ppm) Nb (ppm) Sr (ppm) Y (ppm) Zr (ppm) Analyses by NAA INAA job no. (USGS)WR90 INAA job no. (Becquerel) Na (wt%)0.023 Sc (ppm)2.4 Ti (wt%) Cr (ppm)21.7 Fe (wt%)0.765 Co (ppm)2.22 Ni (ppm)11 Zn (ppm)58.2 As (ppm)1.62 Br (ppm) Rb (ppm)7.29 Sr (ppm)21 Zr (ppm)1530 Mo (ppm) Show data for sample C-110278 http://mrdata.usgs.gov/geochem/show.php?labno=C-110278[7/25/2016 3:06:23 PM] Sb (ppm)0.311 Cs (ppm)0.627 Ba (ppm)54.5 La (ppm)11.5 Ce (ppm)25.4 Nd (ppm)15.3 Sm (ppm)2.28 Eu (ppm)0.248 Tb (ppm)0.359 Yb (ppm)2.5 Lu (ppm)0.435 Hf (ppm)44.5 Ta (ppm)1.43 W (ppm)0.964 Au (ppb)< 0.33 Th (ppm)4.94 U (ppm)2.84 DN job number U (ppm) Th (ppm) Analyses by XRF XRF job number WR90 SiO2 (wt%)93.1 Al2O3 (wt%)1.82 Fe2O3 (wt%)1.11 MgO (wt%)< 0.1 CaO (wt%)0.05 Na2O (wt%)< 0.15 K2O (wt%)0.13 TiO2 (wt%)1.21 P2O5 (wt%)0.13 MnO (wt%)0.02 LOI (wt%)1.03 Analyses for light elements C-S job number Show data for sample C-110278 http://mrdata.usgs.gov/geochem/show.php?labno=C-110278[7/25/2016 3:06:23 PM] C-total (wt%) C-org (wt%) C-CO3 (wt%) S (wt%) Analyses by NURE program Al (wt%)0.9 Ca (wt%)0.01 Fe (wt%)0.89 K (wt%)0.1 Mg (wt%)0.045 Na (wt%)0.02 Ag (ppm)< 0.1 As (ppm) Au (ppb)< 0.01 B (ppm) Ba (ppm)7 Be (ppm)0.5 Bi (ppm) Br (ppm) Cd (ppm) Ce (ppm)28 Cl (ppm) Co (ppm)12 Cr (ppm)5 Cs (ppm) Cu (ppm)3 Dy (ppm) Eu (ppm)2.3 F (ppm) Hf (ppm)40 Hg (ppm) La (ppm)13 Li (ppm)5 Lu (ppm)0.5 Mn (ppm)150 Show data for sample C-110278 http://mrdata.usgs.gov/geochem/show.php?labno=C-110278[7/25/2016 3:06:23 PM] Mo (ppm)< 2 Nb (ppm)5 Ni (ppm)5 P (ppm)800 Pb (ppm)< 10 Pt (ppm) Rb (ppm) Sb (ppm) Sc (ppm)1.9 Se (ppm)< 1 Sm (ppm)3 Sn (ppm)< 5 Sr (ppm) Ta (ppm) Tb (ppm) Th (ppm)6 Ti (wt%)5800 V (ppm)20 W (ppm)2 Y (ppm)< 5 Yb (ppm)2.8 Zn (ppm)7 Zr (ppm) U (ppm) best NURE 2.6 Processing information 2nd labno Previous lab number Field name as analyzed NCJO041 AOV code Replicate code Location count 1 Analytical notes NURE method codes SR1, SR2, SR3-AA;CA;FE;XU;XX Accessibility FOIA Privacy Policies and Notices Show data for sample C-110278 http://mrdata.usgs.gov/geochem/show.php?labno=C-110278[7/25/2016 3:06:23 PM] U.S. Department of the Interior | U.S. Geological Survey URL: http://mrdata.usgs.gov/geochem/show.php?labno=C-110278 Page Contact Information: pschweitzer@usgs.gov Page Last modified: 15:03 on 28-Aug-2015 Show data for sample C-110316 http://mrdata.usgs.gov/geochem/show.php?labno=C-110316[7/25/2016 2:54:29 PM] USGS Home Contact USGS Search USGS Mineral Resources On-Line Spatial Data Mineral Resources > Online Spatial Data > National Geochemical Survey Database Data for C-110316 Report shows selected fields. [Full report] Show this location using [Google Earth] or [Google Maps] Sample identification NURE record ID 5287365 Lab identification number C-110316 Sample set NURE800 Database join ID Sample category NURE Short description of sample type STRM-SED-WET Geographic location Map datum NAD27 Latitude 35.8045 Longitude -78.3756 1:24k quadrangle 36080NEE2 1:250k quadrangle 36080 1:100,000 quadrangle 36080NE FIPS of county f37183 Hydrologic unit 03020201 1:250k quad name Raleigh Zip code, 3-digit 275 Congressional district 3713C2 Sample characteristics Real field name NCWA087S1 Collection date 19760818 Description NURE sample Sample type code 50 Soil horizon Show data for sample C-110316 http://mrdata.usgs.gov/geochem/show.php?labno=C-110316[7/25/2016 2:54:29 PM] Color of reanalyzed powder Sample grain size Sample medium Sediment Sample source Stream Source modifier Wet Upper limit of sieve size 150 Drying procedure <110oC Sample type note Site characteristics Setting Active channel width 2-4' Water depth 0.5-1.0' Water color brown/clear Flow stage low Flow rate mod Stream bed sand Contamination source farm, sewage Contamination potential Contamination degree Vegetation brush pH of water 6.8 Sample characteristics (details) Lab grain size Collector 71 Primary ID NCWA087S1 LANL field name ORGDP field name SRNL field name NCWA087S1 LLNL field name Other name info QA/QC info Replicate codes 000 Conductivity meas. in lab No. grabs 6 Collection hour Show data for sample C-110316 http://mrdata.usgs.gov/geochem/show.php?labno=C-110316[7/25/2016 2:54:29 PM] Est. %organics Study code Odor Site characteristics (details) Photographs Flood plain width Relief low Geologic formation Geologic unit Total alkalinity of water 0.2 Dissolved oxygen (ppm) Gamma activity Air temperature Water temperature 20 Conductivity of water 50 Stream velocity (m/s) Stream channel eroding Weather sunny/clear Vegetation density dense Rock type Rock color Analyses by ICP/Acid dissolution ICP40 job GF43 Al (wt%)5.7 Ca (wt%)0.36 Fe (wt%)1.3 K (wt%)5 Mg (wt%)0.03 Na (wt%)1 P (wt%)0.02 Ti (wt%)0.61 Ag (ppm)< 2 As (ppm)16 Au (ppb)< 8 Ba (ppm)1130 Show data for sample C-110316 http://mrdata.usgs.gov/geochem/show.php?labno=C-110316[7/25/2016 2:54:29 PM] Be (ppm)1 Bi (ppm)19 Cd (ppm)< 2 Ce (ppm)99 Co (ppm)< 2 Cr (ppm)< 2 Cu (ppm)5 Eu (ppm)1 Ga (ppm)9 Ho (ppm)< 4 La (ppm)41 Li (ppm)7 Mn (ppm)417 Mo (ppm)< 2 Nb (ppm)17 Nd (ppm)33 Ni (ppm)< 3 Pb (ppm)49 Sc (ppm)3 Sn (ppm)51 Sr (ppm)212 Ta (ppm)< 40 Th (ppm)40 U (ppm)< 100 V (ppm)41 Y (ppm)6 Yb (ppm)< 1 Zn (ppm)29 Cs (ppm) Rb (ppm) Sb (ppm) Zr (ppm) Analyses by AA As job number GF43 As (ppm)0.8 Show data for sample C-110316 http://mrdata.usgs.gov/geochem/show.php?labno=C-110316[7/25/2016 2:54:29 PM] Se job number GF43 Se (ppm)< 0.2 Hg job number GF43 Hg (ppm)0.03 Sb job number Sb (ppm) Te job number Te (ppm) Tl job number Tl (ppm) W job number W (ppm) Au job number Au (ppb) Pd-Pt job number Pd (ppb) Pt (ppb) Analyses by ICP Partial Chem ICP10 job number GF43 Ag (ppm)< 0.08 As (ppm)< 1 Au (ppb)0.5 Bi (ppm)< 1 Cd (ppm)< 0.05 Cu (ppm)5.5 Mo (ppm)0.4 Pb (ppm)15 Sb (ppm)< 1 Zn (ppm)26.7 Ga (ppm) Hg (ppm) Se (ppm) Te (ppm) Tl (ppm) Analyses by Fusion ICP Show data for sample C-110316 http://mrdata.usgs.gov/geochem/show.php?labno=C-110316[7/25/2016 2:54:29 PM] ICP16 job number Al (wt%) Ca (wt%) Fe (wt%) K (wt%) Mg (wt%) Na (wt%) P (wt%) Si (wt%) Ti (wt%) Ba (ppm) Cr (ppm) Mn (ppm) Nb (ppm) Sr (ppm) Y (ppm) Zr (ppm) Analyses by NAA INAA job no. (USGS)WR91 INAA job no. (Becquerel) Na (wt%)1.01 Sc (ppm)3.3 Ti (wt%) Cr (ppm)9.6 Fe (wt%)1.64 Co (ppm)1.53 Ni (ppm)8.3 Zn (ppm)62.6 As (ppm)0.604 Br (ppm) Rb (ppm)142 Sr (ppm)252 Zr (ppm)1020 Mo (ppm) Sb (ppm)0.136 Show data for sample C-110316 http://mrdata.usgs.gov/geochem/show.php?labno=C-110316[7/25/2016 2:54:29 PM] Cs (ppm)1.92 Ba (ppm)1130 La (ppm)52.1 Ce (ppm)104 Nd (ppm)44.5 Sm (ppm)7.31 Eu (ppm)0.761 Tb (ppm)0.46 Yb (ppm)1.8 Lu (ppm)0.284 Hf (ppm)30.2 Ta (ppm)4.6 W (ppm)0.6 Au (ppb)< 0.29 Th (ppm)38.6 U (ppm)5.66 DN job number U (ppm) Th (ppm) Analyses by XRF XRF job number WR91 SiO2 (wt%)75.9 Al2O3 (wt%)10.9 Fe2O3 (wt%)2.36 MgO (wt%)< 0.1 CaO (wt%)0.57 Na2O (wt%)1.39 K2O (wt%)4.68 TiO2 (wt%)1.32 P2O5 (wt%)0.13 MnO (wt%)0.06 LOI (wt%)1.76 Analyses for light elements C-S job number C-total (wt%) Show data for sample C-110316 http://mrdata.usgs.gov/geochem/show.php?labno=C-110316[7/25/2016 2:54:29 PM] C-org (wt%) C-CO3 (wt%) S (wt%) Analyses by NURE program Al (wt%)5.85 Ca (wt%)0.01 Fe (wt%)1.77 K (wt%)1.7 Mg (wt%)0.03 Na (wt%)0.95 Ag (ppm)0.1 As (ppm)8 Au (ppb)< 0.01 B (ppm) Ba (ppm)340 Be (ppm)1.5 Bi (ppm) Br (ppm) Cd (ppm) Ce (ppm)140 Cl (ppm) Co (ppm)< 5 Cr (ppm)< 5 Cs (ppm) Cu (ppm)3 Dy (ppm) Eu (ppm)5.5 F (ppm) Hf (ppm)30 Hg (ppm) La (ppm)74 Li (ppm)< 5 Lu (ppm)0.4 Mn (ppm)470 Mo (ppm)< 2 Show data for sample C-110316 http://mrdata.usgs.gov/geochem/show.php?labno=C-110316[7/25/2016 2:54:29 PM] Nb (ppm)5 Ni (ppm)< 5 P (ppm)600 Pb (ppm)10 Pt (ppm) Rb (ppm) Sb (ppm) Sc (ppm)2.4 Se (ppm)1 Sm (ppm)9 Sn (ppm)< 5 Sr (ppm) Ta (ppm) Tb (ppm) Th (ppm)60 Ti (wt%)6800 V (ppm)40 W (ppm)< 2 Y (ppm)< 5 Yb (ppm) Zn (ppm)10 Zr (ppm) U (ppm) best NURE 6.8 Processing information 2nd labno Previous lab number Field name as analyzed NCWA087 AOV code Replicate code Location count 1 Analytical notes NURE method codes SR1, SR2, SR3-AA;CA;FE;XU;XX Accessibility FOIA Privacy Policies and Notices U.S. Department of the Interior | U.S. Geological Survey URL: http://mrdata.usgs.gov/geochem/show.php?labno=C-110316 Show data for sample C-110316 http://mrdata.usgs.gov/geochem/show.php?labno=C-110316[7/25/2016 2:54:29 PM] Page Contact Information: pschweitzer@usgs.gov Page Last modified: 15:03 on 28-Aug-2015 Show data for sample C-110773 http://mrdata.usgs.gov/geochem/show.php?labno=C-110773[7/25/2016 2:57:40 PM] USGS Home Contact USGS Search USGS Mineral Resources On-Line Spatial Data Mineral Resources > Online Spatial Data > National Geochemical Survey Database Data for C-110773 Report shows selected fields. [Full report] Show this location using [Google Earth] or [Google Maps] Sample identification NURE record ID 5286695 Lab identification number C-110773 Sample set NURE800 Database join ID Sample category NURE Short description of sample type STRM-SED-WET Geographic location Map datum NAD27 Latitude 35.5581 Longitude -78.3999 1:24k quadrangle 36080NEE4 1:250k quadrangle 36080 1:100,000 quadrangle 36080NE FIPS of county f37101 Hydrologic unit 03020201 1:250k quad name Raleigh Zip code, 3-digit 275 Congressional district 3702C2 Sample characteristics Real field name NCJO058S1 Collection date 19760901 Description NURE sample Sample type code 50 Soil horizon Show data for sample C-110773 http://mrdata.usgs.gov/geochem/show.php?labno=C-110773[7/25/2016 2:57:40 PM] Color of reanalyzed powder Sample grain size Sample medium Sediment Sample source Stream Source modifier Wet Upper limit of sieve size 150 Drying procedure <110oC Sample type note Site characteristics Setting Active channel width 1-2' Water depth <0.5' Water color clear Flow stage low Flow rate slow Stream bed sand Contamination source unknown Contamination potential Contamination degree Vegetation deciduous pH of water 6.9 Sample characteristics (details) Lab grain size Collector 57 Primary ID NCJO058S1 LANL field name ORGDP field name SRNL field name NCJO058S1 LLNL field name Other name info QA/QC info Replicate codes 000 Conductivity meas. in lab No. grabs 5 Collection hour Show data for sample C-110773 http://mrdata.usgs.gov/geochem/show.php?labno=C-110773[7/25/2016 2:57:40 PM] Est. %organics Study code Odor Site characteristics (details) Photographs Flood plain width Relief low Geologic formation Geologic unit Total alkalinity of water 0.22 Dissolved oxygen (ppm) Gamma activity Air temperature Water temperature 19 Conductivity of water 78 Stream velocity (m/s) Stream channel depositing Weather sunny/clear Vegetation density moderate Rock type Rock color Analyses by ICP/Acid dissolution ICP40 job GF58 Al (wt%)1.4 Ca (wt%)0.24 Fe (wt%)0.78 K (wt%)0.61 Mg (wt%)0.03 Na (wt%)0.05 P (wt%)0.01 Ti (wt%)0.43 Ag (ppm)< 2 As (ppm)< 10 Au (ppb)< 8 Ba (ppm)167 Show data for sample C-110773 http://mrdata.usgs.gov/geochem/show.php?labno=C-110773[7/25/2016 2:57:40 PM] Be (ppm)< 1 Bi (ppm)14 Cd (ppm)< 2 Ce (ppm)20 Co (ppm)< 2 Cr (ppm)3 Cu (ppm)3 Eu (ppm)1 Ga (ppm)< 4 Ho (ppm)< 4 La (ppm)8 Li (ppm)4 Mn (ppm)197 Mo (ppm)< 2 Nb (ppm)4 Nd (ppm)< 9 Ni (ppm)4 Pb (ppm)22 Sc (ppm)3 Sn (ppm)33 Sr (ppm)15 Ta (ppm)< 40 Th (ppm)< 6 U (ppm)< 100 V (ppm)23 Y (ppm)5 Yb (ppm)< 1 Zn (ppm)14 Cs (ppm) Rb (ppm) Sb (ppm) Zr (ppm) Analyses by AA As job number GF58 As (ppm)1.2 Show data for sample C-110773 http://mrdata.usgs.gov/geochem/show.php?labno=C-110773[7/25/2016 2:57:40 PM] Se job number GF58 Se (ppm)< 0.2 Hg job number GF58 Hg (ppm)0.04 Sb job number Sb (ppm) Te job number Te (ppm) Tl job number Tl (ppm) W job number W (ppm) Au job number Au (ppb) Pd-Pt job number Pd (ppb) Pt (ppb) Analyses by ICP Partial Chem ICP10 job number GF58 Ag (ppm)< 0.08 As (ppm)< 1 Au (ppb)< 0.1 Bi (ppm)< 1 Cd (ppm)< 0.05 Cu (ppm)1.9 Mo (ppm)0.4 Pb (ppm)14 Sb (ppm)< 1 Zn (ppm)9.9 Ga (ppm) Hg (ppm) Se (ppm) Te (ppm) Tl (ppm) Analyses by Fusion ICP Show data for sample C-110773 http://mrdata.usgs.gov/geochem/show.php?labno=C-110773[7/25/2016 2:57:40 PM] ICP16 job number Al (wt%) Ca (wt%) Fe (wt%) K (wt%) Mg (wt%) Na (wt%) P (wt%) Si (wt%) Ti (wt%) Ba (ppm) Cr (ppm) Mn (ppm) Nb (ppm) Sr (ppm) Y (ppm) Zr (ppm) Analyses by NAA INAA job no. (USGS)WS02 INAA job no. (Becquerel) Na (wt%)0.056 Sc (ppm)4.03 Ti (wt%) Cr (ppm)40.6 Fe (wt%)0.834 Co (ppm)1.41 Ni (ppm)8.6 Zn (ppm) As (ppm)0.963 Br (ppm) Rb (ppm)22.5 Sr (ppm)22 Zr (ppm)1010 Mo (ppm) Sb (ppm)0.494 Show data for sample C-110773 http://mrdata.usgs.gov/geochem/show.php?labno=C-110773[7/25/2016 2:57:40 PM] Cs (ppm)0.663 Ba (ppm)159 La (ppm)10.6 Ce (ppm)23.1 Nd (ppm)10.6 Sm (ppm)2.14 Eu (ppm)0.307 Tb (ppm)0.417 Yb (ppm)3.41 Lu (ppm)0.554 Hf (ppm)28.8 Ta (ppm)1.51 W (ppm)1.65 Au (ppb)< 0.45 Th (ppm)4.85 U (ppm)1.92 DN job number U (ppm) Th (ppm) Analyses by XRF XRF job number WS02 SiO2 (wt%)90.5 Al2O3 (wt%)3.3 Fe2O3 (wt%)1.17 MgO (wt%)< 0.1 CaO (wt%)0.37 Na2O (wt%)< 0.15 K2O (wt%)0.74 TiO2 (wt%)1.08 P2O5 (wt%)0.14 MnO (wt%)0.03 LOI (wt%)1.65 Analyses for light elements C-S job number C-total (wt%) Show data for sample C-110773 http://mrdata.usgs.gov/geochem/show.php?labno=C-110773[7/25/2016 2:57:40 PM] C-org (wt%) C-CO3 (wt%) S (wt%) Analyses by NURE program Al (wt%)1.42 Ca (wt%)< 0.01 Fe (wt%)1.01 K (wt%)0.4 Mg (wt%)0.09 Na (wt%)0.05 Ag (ppm)0.1 As (ppm)1 Au (ppb)< 0.01 B (ppm) Ba (ppm)10 Be (ppm)0.5 Bi (ppm) Br (ppm) Cd (ppm) Ce (ppm)22 Cl (ppm) Co (ppm)10 Cr (ppm)8 Cs (ppm) Cu (ppm)< 2 Dy (ppm)3.3 Eu (ppm)< 1 F (ppm) Hf (ppm)27 Hg (ppm) La (ppm)9 Li (ppm)5 Lu (ppm)0.4 Mn (ppm)210 Mo (ppm)< 2 Show data for sample C-110773 http://mrdata.usgs.gov/geochem/show.php?labno=C-110773[7/25/2016 2:57:40 PM] Nb (ppm)10 Ni (ppm)< 5 P (ppm)700 Pb (ppm)< 10 Pt (ppm) Rb (ppm) Sb (ppm) Sc (ppm)2.2 Se (ppm)< 1 Sm (ppm)2 Sn (ppm)< 5 Sr (ppm) Ta (ppm) Tb (ppm) Th (ppm)3 Ti (wt%)5200 V (ppm)30 W (ppm)2 Y (ppm)< 5 Yb (ppm)3 Zn (ppm)5 Zr (ppm) U (ppm) best NURE 2 Processing information 2nd labno Previous lab number Field name as analyzed NCJO058 AOV code Replicate code Location count 1 Analytical notes NURE method codes SR1, SR2, SR3-AA;CA;FE;XU;XX Accessibility FOIA Privacy Policies and Notices U.S. Department of the Interior | U.S. Geological Survey Show data for sample C-110773 http://mrdata.usgs.gov/geochem/show.php?labno=C-110773[7/25/2016 2:57:40 PM] URL: http://mrdata.usgs.gov/geochem/show.php?labno=C-110773 Page Contact Information: pschweitzer@usgs.gov Page Last modified: 15:03 on 28-Aug-2015 Show data for sample C-110862 http://mrdata.usgs.gov/geochem/show.php?labno=C-110862[7/25/2016 3:07:45 PM] USGS Home Contact USGS Search USGS Mineral Resources On-Line Spatial Data Mineral Resources > Online Spatial Data > National Geochemical Survey Database Data for C-110862 Report shows selected fields. [Full report] Show this location using [Google Earth] or [Google Maps] Sample identification NURE record ID 5287324 Lab identification number C-110862 Sample set NURE800 Database join ID Sample category NURE Short description of sample type STRM-SED-WET Geographic location Map datum NAD27 Latitude 35.7 Longitude -78.7678 1:24k quadrangle 36080NEB3 1:250k quadrangle 36080 1:100,000 quadrangle 36080NE FIPS of county f37183 Hydrologic unit 03020201 1:250k quad name Raleigh Zip code, 3-digit 275 Congressional district 3704C2 Sample characteristics Real field name NCWA046S1 Collection date 19760816 Description NURE sample Sample type code 50 Soil horizon Show data for sample C-110862 http://mrdata.usgs.gov/geochem/show.php?labno=C-110862[7/25/2016 3:07:45 PM] Color of reanalyzed powder Sample grain size Sample medium Sediment Sample source Stream Source modifier Wet Upper limit of sieve size 150 Drying procedure <110oC Sample type note Site characteristics Setting Active channel width 8-16' Water depth 0.5-1.0' Water color cloudy Flow stage low Flow rate slow Stream bed sand Contamination source urban, dump Contamination potential Contamination degree Vegetation deciduous pH of water 7.3 Sample characteristics (details) Lab grain size Collector 71 Primary ID NCWA046S1 LANL field name ORGDP field name SRNL field name NCWA046S1 LLNL field name Other name info QA/QC info Replicate codes 000 Conductivity meas. in lab No. grabs 5 Collection hour Show data for sample C-110862 http://mrdata.usgs.gov/geochem/show.php?labno=C-110862[7/25/2016 3:07:45 PM] Est. %organics Study code Odor Site characteristics (details) Photographs Flood plain width Relief low Geologic formation Geologic unit Total alkalinity of water 0.28 Dissolved oxygen (ppm) Gamma activity Air temperature Water temperature 20 Conductivity of water 62 Stream velocity (m/s) Stream channel eroding Weather overcast Vegetation density moderate Rock type Rock color Analyses by ICP/Acid dissolution ICP40 job GF61 Al (wt%)2.2 Ca (wt%)0.45 Fe (wt%)4.8 K (wt%)0.18 Mg (wt%)0.09 Na (wt%)0.27 P (wt%)< 0.005 Ti (wt%)0.62 Ag (ppm)< 2 As (ppm)< 10 Au (ppb)< 8 Ba (ppm)99 Show data for sample C-110862 http://mrdata.usgs.gov/geochem/show.php?labno=C-110862[7/25/2016 3:07:45 PM] Be (ppm)< 1 Bi (ppm)20 Cd (ppm)< 2 Ce (ppm)23 Co (ppm)6 Cr (ppm)3 Cu (ppm)5 Eu (ppm)1 Ga (ppm)4 Ho (ppm)< 4 La (ppm)8 Li (ppm)3 Mn (ppm)1960 Mo (ppm)< 2 Nb (ppm)< 4 Nd (ppm)< 9 Ni (ppm)5 Pb (ppm)24 Sc (ppm)8 Sn (ppm)59 Sr (ppm)57 Ta (ppm)< 40 Th (ppm)< 6 U (ppm)< 100 V (ppm)31 Y (ppm)8 Yb (ppm)< 1 Zn (ppm)69 Cs (ppm) Rb (ppm) Sb (ppm) Zr (ppm) Analyses by AA As job number GF61 As (ppm)1.1 Show data for sample C-110862 http://mrdata.usgs.gov/geochem/show.php?labno=C-110862[7/25/2016 3:07:45 PM] Se job number GF61 Se (ppm)< 0.2 Hg job number GF61 Hg (ppm)0.03 Sb job number Sb (ppm) Te job number Te (ppm) Tl job number Tl (ppm) W job number W (ppm) Au job number Au (ppb) Pd-Pt job number Pd (ppb) Pt (ppb) Analyses by ICP Partial Chem ICP10 job number GF61 Ag (ppm)< 0.08 As (ppm)< 1 Au (ppb)0.3 Bi (ppm)< 1 Cd (ppm)0.07 Cu (ppm)5 Mo (ppm)0.5 Pb (ppm)12 Sb (ppm)< 1 Zn (ppm)49 Ga (ppm) Hg (ppm) Se (ppm) Te (ppm) Tl (ppm) Analyses by Fusion ICP Show data for sample C-110862 http://mrdata.usgs.gov/geochem/show.php?labno=C-110862[7/25/2016 3:07:45 PM] ICP16 job number Al (wt%) Ca (wt%) Fe (wt%) K (wt%) Mg (wt%) Na (wt%) P (wt%) Si (wt%) Ti (wt%) Ba (ppm) Cr (ppm) Mn (ppm) Nb (ppm) Sr (ppm) Y (ppm) Zr (ppm) Analyses by NAA INAA job no. (USGS)WS04 INAA job no. (Becquerel) Na (wt%)0.29 Sc (ppm)8.98 Ti (wt%) Cr (ppm)13.1 Fe (wt%)5.05 Co (ppm)6.92 Ni (ppm)< 2 Zn (ppm) As (ppm)0.991 Br (ppm) Rb (ppm)11 Sr (ppm)82 Zr (ppm)255 Mo (ppm) Sb (ppm)0.534 Show data for sample C-110862 http://mrdata.usgs.gov/geochem/show.php?labno=C-110862[7/25/2016 3:07:45 PM] Cs (ppm)0.427 Ba (ppm)123 La (ppm)8.21 Ce (ppm)21.1 Nd (ppm)10.7 Sm (ppm)2.36 Eu (ppm)0.569 Tb (ppm)0.319 Yb (ppm)1.75 Lu (ppm)0.288 Hf (ppm)7.1 Ta (ppm)1.64 W (ppm)1.09 Au (ppb)< 0.92 Th (ppm)3.58 U (ppm)1.02 DN job number U (ppm) Th (ppm) Analyses by XRF XRF job number WS04 SiO2 (wt%)78.3 Al2O3 (wt%)4.04 Fe2O3 (wt%)7.26 MgO (wt%)0.16 CaO (wt%)0.65 Na2O (wt%)0.54 K2O (wt%)0.23 TiO2 (wt%)5.96 P2O5 (wt%)0.15 MnO (wt%)0.33 LOI (wt%)1.41 Analyses for light elements C-S job number C-total (wt%) Show data for sample C-110862 http://mrdata.usgs.gov/geochem/show.php?labno=C-110862[7/25/2016 3:07:45 PM] C-org (wt%) C-CO3 (wt%) S (wt%) Analyses by NURE program Al (wt%)1.84 Ca (wt%)0.02 Fe (wt%)4.96 K (wt%)0.1 Mg (wt%)0.105 Na (wt%)0.25 Ag (ppm)< 0.1 As (ppm)3 Au (ppb)< 0.01 B (ppm) Ba (ppm)5 Be (ppm)< 0.5 Bi (ppm) Br (ppm) Cd (ppm) Ce (ppm)< 22 Cl (ppm) Co (ppm)5 Cr (ppm)< 5 Cs (ppm) Cu (ppm)3 Dy (ppm) Eu (ppm)< 1 F (ppm) Hf (ppm)3 Hg (ppm) La (ppm)6 Li (ppm)< 5 Lu (ppm)0.3 Mn (ppm)2310 Mo (ppm)< 2 Show data for sample C-110862 http://mrdata.usgs.gov/geochem/show.php?labno=C-110862[7/25/2016 3:07:45 PM] Nb (ppm)< 5 Ni (ppm)< 5 P (ppm)900 Pb (ppm)< 10 Pt (ppm) Rb (ppm) Sb (ppm) Sc (ppm)6.3 Se (ppm)2 Sm (ppm)2 Sn (ppm)< 5 Sr (ppm) Ta (ppm) Tb (ppm) Th (ppm)4 Ti (wt%)29400 V (ppm)60 W (ppm)< 2 Y (ppm)10 Yb (ppm)1.5 Zn (ppm)15 Zr (ppm) U (ppm) best NURE 1 Processing information 2nd labno Previous lab number Field name as analyzed NCWA046 AOV code Replicate code Location count 1 Analytical notes NURE method codes SR1, SR2, SR3-AA;CA;FE;XU;XX Accessibility FOIA Privacy Policies and Notices U.S. Department of the Interior | U.S. Geological Survey Show data for sample C-110862 http://mrdata.usgs.gov/geochem/show.php?labno=C-110862[7/25/2016 3:07:45 PM] URL: http://mrdata.usgs.gov/geochem/show.php?labno=C-110862 Page Contact Information: pschweitzer@usgs.gov Page Last modified: 15:03 on 28-Aug-2015 Show data for sample C-126931 http://mrdata.usgs.gov/geochem/show.php?labno=C-126931[7/25/2016 2:55:30 PM] USGS Home Contact USGS Search USGS Mineral Resources On-Line Spatial Data Mineral Resources > Online Spatial Data > National Geochemical Survey Database Data for C-126931 Report shows selected fields. [Full report] Show this location using [Google Earth] or [Google Maps] Sample identification NURE record ID 5286702 Lab identification number C-126931 Sample set NURE Coastal 99 Database join ID Sample category NURE Short description of sample type STRM-SED-WET Geographic location Map datum NAD27 Latitude 35.5894 Longitude -78.3977 1:24k quadrangle 36080NEE4 1:250k quadrangle 36080 1:100,000 quadrangle 36080NE FIPS of county f37101 Hydrologic unit 03020201 1:250k quad name Raleigh Zip code, 3-digit 275 Congressional district 3702C2 Sample characteristics Real field name NCJO065S1 Collection date 19760901 Description NURE STREAM SEDIMENT Sample type code 50 Soil horizon Show data for sample C-126931 http://mrdata.usgs.gov/geochem/show.php?labno=C-126931[7/25/2016 2:55:30 PM] Color of reanalyzed powder Sample grain size Sample medium Sediment Sample source Stream Source modifier Wet Upper limit of sieve size 150 Drying procedure <110oC Sample type note Site characteristics Setting Active channel width 2-4' Water depth 0.5-1.0' Water color brown/clear Flow stage low Flow rate slow Stream bed sand Contamination source Contamination potential Contamination degree Vegetation deciduous pH of water 7.2 Sample characteristics (details) Lab grain size Collector 57 Primary ID NCJO065S1 LANL field name ORGDP field name SRNL field name NCJO065S1 LLNL field name Other name info QA/QC info Replicate codes 000 Conductivity meas. in lab No. grabs 5 Collection hour Show data for sample C-126931 http://mrdata.usgs.gov/geochem/show.php?labno=C-126931[7/25/2016 2:55:30 PM] Est. %organics Study code Odor Site characteristics (details) Photographs Flood plain width Relief low Geologic formation Geologic unit Total alkalinity of water 0.56 Dissolved oxygen (ppm) Gamma activity Air temperature Water temperature 20 Conductivity of water 100 Stream velocity (m/s) Stream channel depositing Weather sunny/clear Vegetation density moderate Rock type Rock color Analyses by ICP/Acid dissolution ICP40 job MRP-01313 Al (wt%)2.815 Ca (wt%)0.045 Fe (wt%)1.53 K (wt%)0.32 Mg (wt%)0.04 Na (wt%)0.03 P (wt%)0.015 Ti (wt%)0.421 Ag (ppm)< 2 As (ppm)< 10 Au (ppb)< 8 Ba (ppm)88 Show data for sample C-126931 http://mrdata.usgs.gov/geochem/show.php?labno=C-126931[7/25/2016 2:55:30 PM] Be (ppm)< 1 Bi (ppm)< 50 Cd (ppm)< 2 Ce (ppm)40 Co (ppm)< 2 Cr (ppm)27 Cu (ppm)6 Eu (ppm)1 Ga (ppm)6 Ho (ppm)4 La (ppm)18 Li (ppm)9 Mn (ppm)43 Mo (ppm)< 2 Nb (ppm)7 Nd (ppm)11 Ni (ppm)9 Pb (ppm)6 Sc (ppm)4 Sn (ppm)< 50 Sr (ppm)10 Ta (ppm)< 40 Th (ppm)17 U (ppm)< 100 V (ppm)40 Y (ppm)6 Yb (ppm)< 1 Zn (ppm)11 Cs (ppm) Rb (ppm) Sb (ppm) Zr (ppm) Analyses by AA As job number MRP-01313 As (ppm)9 Show data for sample C-126931 http://mrdata.usgs.gov/geochem/show.php?labno=C-126931[7/25/2016 2:55:30 PM] Se job number MRP-01313 Se (ppm)0.4 Hg job number MRP-01313 Hg (ppm)0.05 Sb job number Sb (ppm) Te job number Te (ppm) Tl job number Tl (ppm) W job number W (ppm) Au job number Au (ppb) Pd-Pt job number Pd (ppb) Pt (ppb) Analyses by ICP Partial Chem ICP10 job number MRP-01313 Ag (ppm)< 0.08 As (ppm)2 Au (ppb)< 0.1 Bi (ppm)< 1 Cd (ppm)< 0.05 Cu (ppm)4.03 Mo (ppm)1 Pb (ppm)9 Sb (ppm)< 1 Zn (ppm)9.94 Ga (ppm) Hg (ppm) Se (ppm) Te (ppm) Tl (ppm) Analyses by Fusion ICP Show data for sample C-126931 http://mrdata.usgs.gov/geochem/show.php?labno=C-126931[7/25/2016 2:55:30 PM] ICP16 job number Al (wt%) Ca (wt%) Fe (wt%) K (wt%) Mg (wt%) Na (wt%) P (wt%) Si (wt%) Ti (wt%) Ba (ppm) Cr (ppm) Mn (ppm) Nb (ppm) Sr (ppm) Y (ppm) Zr (ppm) Analyses by NAA INAA job no. (USGS) INAA job no. (Becquerel) Na (wt%) Sc (ppm) Ti (wt%) Cr (ppm) Fe (wt%) Co (ppm) Ni (ppm) Zn (ppm) As (ppm) Br (ppm) Rb (ppm) Sr (ppm) Zr (ppm) Mo (ppm) Sb (ppm) Cs (ppm) Show data for sample C-126931 http://mrdata.usgs.gov/geochem/show.php?labno=C-126931[7/25/2016 2:55:30 PM] Ba (ppm) La (ppm) Ce (ppm) Nd (ppm) Sm (ppm) Eu (ppm) Tb (ppm) Yb (ppm) Lu (ppm) Hf (ppm) Ta (ppm) W (ppm) Au (ppb) Th (ppm) U (ppm) DN job number U (ppm) Th (ppm) Analyses by XRF XRF job number SiO2 (wt%) Al2O3 (wt%) Fe2O3 (wt%) MgO (wt%) CaO (wt%) Na2O (wt%) K2O (wt%) TiO2 (wt%) P2O5 (wt%) MnO (wt%) LOI (wt%) Analyses for light elements C-S job number C-total (wt%) C-org (wt%) C-CO3 (wt%) Show data for sample C-126931 http://mrdata.usgs.gov/geochem/show.php?labno=C-126931[7/25/2016 2:55:30 PM] S (wt%) Analyses by NURE program Al (wt%)2.2 Ca (wt%)< 0.01 Fe (wt%)1.04 K (wt%)0.2 Mg (wt%)0.15 Na (wt%)0.02 Ag (ppm)0.3 As (ppm) Au (ppb)< 0.01 B (ppm) Ba (ppm)47 Be (ppm)0.5 Bi (ppm) Br (ppm) Cd (ppm) Ce (ppm)21 Cl (ppm) Co (ppm)12 Cr (ppm)10 Cs (ppm) Cu (ppm)3 Dy (ppm) Eu (ppm)< 1 F (ppm) Hf (ppm)33 Hg (ppm) La (ppm)11 Li (ppm)10 Lu (ppm)0.3 Mn (ppm)40 Mo (ppm)< 2 Nb (ppm)5 Ni (ppm)5 Show data for sample C-126931 http://mrdata.usgs.gov/geochem/show.php?labno=C-126931[7/25/2016 2:55:30 PM] P (ppm)700 Pb (ppm)< 10 Pt (ppm) Rb (ppm) Sb (ppm) Sc (ppm)2.8 Se (ppm)< 1 Sm (ppm)2 Sn (ppm)< 5 Sr (ppm) Ta (ppm) Tb (ppm) Th (ppm)9 Ti (wt%)3400 V (ppm)30 W (ppm)< 2 Y (ppm)< 5 Yb (ppm)3.4 Zn (ppm)5 Zr (ppm) U (ppm) best NURE 3 Processing information 2nd labno Previous lab number Field name as analyzed NCJO065 AOV code Replicate code Location count 1 Analytical notes NURE method codes SR1, SR2, SR3-AA;CA;FE;XU;XX Accessibility FOIA Privacy Policies and Notices U.S. Department of the Interior | U.S. Geological Survey URL: http://mrdata.usgs.gov/geochem/show.php?labno=C-126931 Page Contact Information: pschweitzer@usgs.gov Page Last modified: 15:03 on 28-Aug-2015 Show data for sample C-126932 http://mrdata.usgs.gov/geochem/show.php?labno=C-126932[7/20/2016 2:53:03 PM] USGS Home Contact USGS Search USGS Mineral Resources On-Line Spatial Data Mineral Resources > Online Spatial Data > National Geochemical Survey Database Data for C-126932 Report shows selected fields. [Full report] Show this location using [Google Earth] or [Google Maps] Sample identification NURE record ID 5286747 Lab identification number C-126932 Sample set NURE Coastal 99 Database join ID Sample category NURE Short description of sample type STRM-SED-WET Geographic location Map datum NAD27 Latitude 35.6603 Longitude -78.4434 1:24k quadrangle 36080NEE3 1:250k quadrangle 36080 1:100,000 quadrangle 36080NE FIPS of county f37101 Hydrologic unit 03020201 1:250k quad name Raleigh Zip code, 3-digit 275 Congressional district 3702C2 Sample characteristics Real field name NCJO110S1 Collection date 19760903 Description NURE STREAM SEDIMENT Sample type code 50 Soil horizon Show data for sample C-126932 http://mrdata.usgs.gov/geochem/show.php?labno=C-126932[7/20/2016 2:53:03 PM] Color of reanalyzed powder Sample grain size Sample medium Sediment Sample source Stream Source modifier Wet Upper limit of sieve size 150 Drying procedure <110oC Sample type note Site characteristics Setting Active channel width 2-4' Water depth 1-2' Water color clear Flow stage low Flow rate slow Stream bed sand Contamination source Contamination potential Contamination degree Vegetation deciduous pH of water 7.6 Sample characteristics (details) Lab grain size Collector 57 Primary ID NCJO110S1 LANL field name ORGDP field name SRNL field name NCJO110S1 LLNL field name Other name info QA/QC info Replicate codes 000 Conductivity meas. in lab No. grabs 5 Collection hour Show data for sample C-126932 http://mrdata.usgs.gov/geochem/show.php?labno=C-126932[7/20/2016 2:53:03 PM] Est. %organics Study code Odor Site characteristics (details) Photographs Flood plain width Relief low Geologic formation Geologic unit Total alkalinity of water 1 Dissolved oxygen (ppm) Gamma activity Air temperature Water temperature 20 Conductivity of water 144 Stream velocity (m/s) Stream channel depositing Weather overcast Vegetation density moderate Rock type Rock color Analyses by ICP/Acid dissolution ICP40 job MRP-01313 Al (wt%)3.215 Ca (wt%)1.03 Fe (wt%)4.46 K (wt%)0.55 Mg (wt%)0.36 Na (wt%)0.32 P (wt%)0.015 Ti (wt%)0.573 Ag (ppm)< 2 As (ppm)< 10 Au (ppb)< 8 Ba (ppm)197 Show data for sample C-126932 http://mrdata.usgs.gov/geochem/show.php?labno=C-126932[7/20/2016 2:53:03 PM] Be (ppm)< 1 Bi (ppm)< 50 Cd (ppm)< 2 Ce (ppm)48 Co (ppm)13 Cr (ppm)38 Cu (ppm)17 Eu (ppm)1 Ga (ppm)5 Ho (ppm)< 4 La (ppm)23 Li (ppm)8 Mn (ppm)691 Mo (ppm)< 2 Nb (ppm)< 4 Nd (ppm)19 Ni (ppm)18 Pb (ppm)5 Sc (ppm)13 Sn (ppm)< 50 Sr (ppm)52 Ta (ppm)< 40 Th (ppm)19 U (ppm)< 100 V (ppm)104 Y (ppm)12 Yb (ppm)2 Zn (ppm)34 Cs (ppm) Rb (ppm) Sb (ppm) Zr (ppm) Analyses by AA As job number MRP-01313 As (ppm)1.1 Show data for sample C-126932 http://mrdata.usgs.gov/geochem/show.php?labno=C-126932[7/20/2016 2:53:03 PM] Se job number MRP-01313 Se (ppm)< 0.2 Hg job number MRP-01313 Hg (ppm)0.04 Sb job number Sb (ppm) Te job number Te (ppm) Tl job number Tl (ppm) W job number W (ppm) Au job number Au (ppb) Pd-Pt job number Pd (ppb) Pt (ppb) Analyses by ICP Partial Chem ICP10 job number MRP-01313 Ag (ppm)< 0.08 As (ppm)< 1 Au (ppb)< 0.1 Bi (ppm)< 1 Cd (ppm)0.08 Cu (ppm)11.6 Mo (ppm)0.5 Pb (ppm)7 Sb (ppm)< 1 Zn (ppm)25.3 Ga (ppm) Hg (ppm) Se (ppm) Te (ppm) Tl (ppm) Analyses by Fusion ICP Show data for sample C-126932 http://mrdata.usgs.gov/geochem/show.php?labno=C-126932[7/20/2016 2:53:03 PM] ICP16 job number Al (wt%) Ca (wt%) Fe (wt%) K (wt%) Mg (wt%) Na (wt%) P (wt%) Si (wt%) Ti (wt%) Ba (ppm) Cr (ppm) Mn (ppm) Nb (ppm) Sr (ppm) Y (ppm) Zr (ppm) Analyses by NAA INAA job no. (USGS) INAA job no. (Becquerel)T99004010 Na (wt%)0.32 Sc (ppm)14 Ti (wt%)1 Cr (ppm)73 Fe (wt%)6.7 Co (ppm)17 Ni (ppm)< 10 Zn (ppm)< 100 As (ppm)< 0.5 Br (ppm)2.4 Rb (ppm)< 5 Sr (ppm) Zr (ppm)830 Mo (ppm)< 1 Sb (ppm)0.5 Show data for sample C-126932 http://mrdata.usgs.gov/geochem/show.php?labno=C-126932[7/20/2016 2:53:03 PM] Cs (ppm)1.5 Ba (ppm)270 La (ppm)18 Ce (ppm)37 Nd (ppm)16 Sm (ppm)3.2 Eu (ppm)0.7 Tb (ppm)0.5 Yb (ppm)< 2 Lu (ppm)0.3 Hf (ppm)16 Ta (ppm)1.1 W (ppm)< 1 Au (ppb)5 Th (ppm)8.2 U (ppm)1.8 DN job number U (ppm) Th (ppm) Analyses by XRF XRF job number SiO2 (wt%) Al2O3 (wt%) Fe2O3 (wt%) MgO (wt%) CaO (wt%) Na2O (wt%) K2O (wt%) TiO2 (wt%) P2O5 (wt%) MnO (wt%) LOI (wt%) Analyses for light elements C-S job number C-total (wt%) Show data for sample C-126932 http://mrdata.usgs.gov/geochem/show.php?labno=C-126932[7/20/2016 2:53:03 PM] C-org (wt%) C-CO3 (wt%) S (wt%) Analyses by NURE program Al (wt%)2.97 Ca (wt%)0.05 Fe (wt%)7.37 K (wt%)0.2 Mg (wt%)0.195 Na (wt%)0.27 Ag (ppm)0.1 As (ppm)0 Au (ppb)< 0.01 B (ppm) Ba (ppm)17 Be (ppm)1 Bi (ppm) Br (ppm) Cd (ppm) Ce (ppm)< 20 Cl (ppm) Co (ppm)22 Cr (ppm)15 Cs (ppm) Cu (ppm)11 Dy (ppm)2.1 Eu (ppm)< 1 F (ppm) Hf (ppm)13 Hg (ppm) La (ppm)14 Li (ppm)9 Lu (ppm)0.4 Mn (ppm)700 Mo (ppm)< 2 Show data for sample C-126932 http://mrdata.usgs.gov/geochem/show.php?labno=C-126932[7/20/2016 2:53:03 PM] Nb (ppm)< 5 Ni (ppm)7 P (ppm)700 Pb (ppm)< 10 Pt (ppm) Rb (ppm) Sb (ppm) Sc (ppm)9.9 Se (ppm)< 1 Sm (ppm)2 Sn (ppm)< 5 Sr (ppm) Ta (ppm) Tb (ppm) Th (ppm)8 Ti (wt%)8400 V (ppm)200 W (ppm)< 2 Y (ppm)15 Yb (ppm) Zn (ppm)20 Zr (ppm) U (ppm) best NURE 2.1 Processing information 2nd labno BQ1-155 Previous lab number Field name as analyzed NCJO110 AOV code Replicate code Location count 1 Analytical notes NURE method codes SR1, SR2, SR3-AA;CA;FE;XU;XX Accessibility FOIA Privacy Policies and Notices U.S. Department of the Interior | U.S. Geological Survey URL: http://mrdata.usgs.gov/geochem/show.php?labno=C-126932 Show data for sample C-126932 http://mrdata.usgs.gov/geochem/show.php?labno=C-126932[7/20/2016 2:53:03 PM] Page Contact Information: pschweitzer@usgs.gov Page Last modified: 15:03 on 28-Aug-2015 Show data for sample C-126961 http://mrdata.usgs.gov/geochem/show.php?labno=C-126961[7/25/2016 2:56:30 PM] USGS Home Contact USGS Search USGS Mineral Resources On-Line Spatial Data Mineral Resources > Online Spatial Data > National Geochemical Survey Database Data for C-126961 Report shows selected fields. [Full report] Show this location using [Google Earth] or [Google Maps] Sample identification NURE record ID 5286756 Lab identification number C-126961 Sample set NURE Coastal 99 Database join ID Sample category NURE Short description of sample type STRM-SED-WET Geographic location Map datum NAD27 Latitude 35.6324 Longitude -78.3184 1:24k quadrangle 36080NEF3 1:250k quadrangle 36080 1:100,000 quadrangle 36080NE FIPS of county f37101 Hydrologic unit 03020201 1:250k quad name Raleigh Zip code, 3-digit 275 Congressional district 3702C2 Sample characteristics Real field name NCJO119S1 Collection date 19760904 Description NURE STREAM SEDIMENT Sample type code 50 Soil horizon Show data for sample C-126961 http://mrdata.usgs.gov/geochem/show.php?labno=C-126961[7/25/2016 2:56:30 PM] Color of reanalyzed powder Sample grain size Sample medium Sediment Sample source Stream Source modifier Wet Upper limit of sieve size 150 Drying procedure <110oC Sample type note Site characteristics Setting Active channel width 4-8' Water depth 1-2' Water color clear Flow stage low Flow rate slow Stream bed sand Contamination source Contamination potential Contamination degree Vegetation deciduous pH of water 7.3 Sample characteristics (details) Lab grain size Collector 57 Primary ID NCJO119S1 LANL field name ORGDP field name SRNL field name NCJO119S1 LLNL field name Other name info QA/QC info Replicate codes 000 Conductivity meas. in lab No. grabs 7 Collection hour Show data for sample C-126961 http://mrdata.usgs.gov/geochem/show.php?labno=C-126961[7/25/2016 2:56:30 PM] Est. %organics Study code Odor Site characteristics (details) Photographs Flood plain width Relief low Geologic formation Geologic unit Total alkalinity of water 0.4 Dissolved oxygen (ppm) Gamma activity Air temperature Water temperature 20 Conductivity of water 70 Stream velocity (m/s) Stream channel depositing Weather sunny/clear Vegetation density moderate Rock type Rock color Analyses by ICP/Acid dissolution ICP40 job MRP-01313 Al (wt%)2.035 Ca (wt%)0.235 Fe (wt%)0.57 K (wt%)1.46 Mg (wt%)0.03 Na (wt%)0.33 P (wt%)0.015 Ti (wt%)0.396 Ag (ppm)< 2 As (ppm)< 10 Au (ppb)< 8 Ba (ppm)502 Show data for sample C-126961 http://mrdata.usgs.gov/geochem/show.php?labno=C-126961[7/25/2016 2:56:30 PM] Be (ppm)< 1 Bi (ppm)< 50 Cd (ppm)< 2 Ce (ppm)106 Co (ppm)< 2 Cr (ppm)11 Cu (ppm)5 Eu (ppm)1 Ga (ppm)6 Ho (ppm)< 4 La (ppm)56 Li (ppm)4 Mn (ppm)199 Mo (ppm)< 2 Nb (ppm)5 Nd (ppm)35 Ni (ppm)< 3 Pb (ppm)10 Sc (ppm)3 Sn (ppm)< 50 Sr (ppm)81 Ta (ppm)< 40 Th (ppm)38 U (ppm)< 100 V (ppm)14 Y (ppm)7 Yb (ppm)< 1 Zn (ppm)13 Cs (ppm) Rb (ppm) Sb (ppm) Zr (ppm) Analyses by AA As job number MRP-01313 As (ppm)0.8 Show data for sample C-126961 http://mrdata.usgs.gov/geochem/show.php?labno=C-126961[7/25/2016 2:56:30 PM] Se job number MRP-01313 Se (ppm)< 0.2 Hg job number MRP-01313 Hg (ppm)0.04 Sb job number Sb (ppm) Te job number Te (ppm) Tl job number Tl (ppm) W job number W (ppm) Au job number Au (ppb) Pd-Pt job number Pd (ppb) Pt (ppb) Analyses by ICP Partial Chem ICP10 job number MRP-01313 Ag (ppm)< 0.08 As (ppm)< 1 Au (ppb)< 0.1 Bi (ppm)< 1 Cd (ppm)< 0.05 Cu (ppm)2.8 Mo (ppm)0.3 Pb (ppm)6 Sb (ppm)< 1 Zn (ppm)9.32 Ga (ppm) Hg (ppm) Se (ppm) Te (ppm) Tl (ppm) Analyses by Fusion ICP Show data for sample C-126961 http://mrdata.usgs.gov/geochem/show.php?labno=C-126961[7/25/2016 2:56:30 PM] ICP16 job number Al (wt%) Ca (wt%) Fe (wt%) K (wt%) Mg (wt%) Na (wt%) P (wt%) Si (wt%) Ti (wt%) Ba (ppm) Cr (ppm) Mn (ppm) Nb (ppm) Sr (ppm) Y (ppm) Zr (ppm) Analyses by NAA INAA job no. (USGS) INAA job no. (Becquerel) Na (wt%) Sc (ppm) Ti (wt%) Cr (ppm) Fe (wt%) Co (ppm) Ni (ppm) Zn (ppm) As (ppm) Br (ppm) Rb (ppm) Sr (ppm) Zr (ppm) Mo (ppm) Sb (ppm) Cs (ppm) Show data for sample C-126961 http://mrdata.usgs.gov/geochem/show.php?labno=C-126961[7/25/2016 2:56:30 PM] Ba (ppm) La (ppm) Ce (ppm) Nd (ppm) Sm (ppm) Eu (ppm) Tb (ppm) Yb (ppm) Lu (ppm) Hf (ppm) Ta (ppm) W (ppm) Au (ppb) Th (ppm) U (ppm) DN job number U (ppm) Th (ppm) Analyses by XRF XRF job number SiO2 (wt%) Al2O3 (wt%) Fe2O3 (wt%) MgO (wt%) CaO (wt%) Na2O (wt%) K2O (wt%) TiO2 (wt%) P2O5 (wt%) MnO (wt%) LOI (wt%) Analyses for light elements C-S job number C-total (wt%) C-org (wt%) C-CO3 (wt%) Show data for sample C-126961 http://mrdata.usgs.gov/geochem/show.php?labno=C-126961[7/25/2016 2:56:30 PM] S (wt%) Analyses by NURE program Al (wt%)1.84 Ca (wt%)0.01 Fe (wt%)0.77 K (wt%)1 Mg (wt%)0.045 Na (wt%)0.31 Ag (ppm)< 0.1 As (ppm)0 Au (ppb)< 0.01 B (ppm) Ba (ppm)27 Be (ppm)0.5 Bi (ppm) Br (ppm) Cd (ppm) Ce (ppm)40 Cl (ppm) Co (ppm)7 Cr (ppm)< 5 Cs (ppm) Cu (ppm)2 Dy (ppm)1.3 Eu (ppm)< 1.4 F (ppm) Hf (ppm)24 Hg (ppm) La (ppm)23 Li (ppm)6 Lu (ppm)0.2 Mn (ppm)160 Mo (ppm)< 2 Nb (ppm)< 5 Ni (ppm)< 5 Show data for sample C-126961 http://mrdata.usgs.gov/geochem/show.php?labno=C-126961[7/25/2016 2:56:30 PM] P (ppm)700 Pb (ppm)< 10 Pt (ppm) Rb (ppm) Sb (ppm) Sc (ppm)1.7 Se (ppm)1 Sm (ppm)2 Sn (ppm)< 5 Sr (ppm) Ta (ppm) Tb (ppm) Th (ppm)19 Ti (wt%)3100 V (ppm)10 W (ppm)< 2 Y (ppm)< 5 Yb (ppm) Zn (ppm)5 Zr (ppm) U (ppm) best NURE 2.4 Processing information 2nd labno Previous lab number Field name as analyzed NCJO119 AOV code Replicate code Location count 1 Analytical notes NURE method codes SR1, SR2, SR3-AA;CA;FE;XU;XX Accessibility FOIA Privacy Policies and Notices U.S. Department of the Interior | U.S. Geological Survey URL: http://mrdata.usgs.gov/geochem/show.php?labno=C-126961 Page Contact Information: pschweitzer@usgs.gov Page Last modified: 15:03 on 28-Aug-2015 Show data for sample C-143268 http://mrdata.usgs.gov/geochem/show.php?labno=C-143268[7/25/2016 3:03:31 PM] USGS Home Contact USGS Search USGS Mineral Resources On-Line Spatial Data Mineral Resources > Online Spatial Data > National Geochemical Survey Database Data for C-143268 Report shows selected fields. [Full report] Show this location using [Google Earth] or [Google Maps] Sample identification NURE record ID 5286769 Lab identification number C-143268 Sample set NURE2000 Database join ID Sample category NURE Short description of sample type STRM-SED-DRY Geographic location Map datum NAD27 Latitude 35.7755 Longitude -78.2779 1:24k quadrangle 36080NEF2 1:250k quadrangle 36080 1:100,000 quadrangle 36080NE FIPS of county f37101 Hydrologic unit 03020201 1:250k quad name Raleigh Zip code, 3-digit 275 Congressional district 3702C2 Sample characteristics Real field name NCJO132S1 Collection date 19760903 Description NURE sample, AEG013 1-02-245 Sample type code 750 Soil horizon Show data for sample C-143268 http://mrdata.usgs.gov/geochem/show.php?labno=C-143268[7/25/2016 3:03:31 PM] Color of reanalyzed powder tan Sample grain size Sample medium Sediment Sample source Stream Source modifier Dry Upper limit of sieve size 150 Drying procedure <110oC Sample type note Original NURE code was 50, but stream was dry Site characteristics Setting Active channel width dry Water depth dry Water color other Flow stage dry Flow rate dry Stream bed sand Contamination source Contamination potential Contamination degree Vegetation deciduous pH of water Sample characteristics (details) Lab grain size Fine Collector 57 Primary ID NCJO132S1 LANL field name ORGDP field name SRNL field name NCJO132S1 LLNL field name Other name info QA/QC info Replicate codes 000 Conductivity meas. in lab No. grabs 6 Show data for sample C-143268 http://mrdata.usgs.gov/geochem/show.php?labno=C-143268[7/25/2016 3:03:31 PM] Collection hour Est. %organics Study code Odor Site characteristics (details) Photographs Flood plain width Relief low Geologic formation Geologic unit Total alkalinity of water Dissolved oxygen (ppm) Gamma activity Air temperature Water temperature Conductivity of water Stream velocity (m/s) Stream channel unknown Weather light rain Vegetation density moderate Rock type Rock color Analyses by ICP/Acid dissolution ICP40 job MRP-01958 Al (wt%)1.97 Ca (wt%)0.06 Fe (wt%)1.14 K (wt%)0.48 Mg (wt%)0.08 Na (wt%)0.07 P (wt%)0.015 Ti (wt%)0.677 Ag (ppm)< 2 As (ppm)11 Au (ppb)< 8 Show data for sample C-143268 http://mrdata.usgs.gov/geochem/show.php?labno=C-143268[7/25/2016 3:03:31 PM] Ba (ppm)147 Be (ppm)< 1 Bi (ppm)< 50 Cd (ppm)< 2 Ce (ppm)21 Co (ppm)4 Cr (ppm)80 Cu (ppm)7 Eu (ppm)1 Ga (ppm)6 Ho (ppm)< 4 La (ppm)9 Li (ppm)8 Mn (ppm)739 Mo (ppm)< 2 Nb (ppm)15 Nd (ppm)< 9 Ni (ppm)4 Pb (ppm)8 Sc (ppm)4 Sn (ppm)< 50 Sr (ppm)18 Ta (ppm)< 40 Th (ppm)< 6 U (ppm)< 100 V (ppm)26 Y (ppm)5 Yb (ppm)< 1 Zn (ppm)19 Cs (ppm) Rb (ppm) Sb (ppm) Zr (ppm) Analyses by AA As job number MRP-01958 Show data for sample C-143268 http://mrdata.usgs.gov/geochem/show.php?labno=C-143268[7/25/2016 3:03:31 PM] As (ppm)1.3 Se job number MRP-01958 Se (ppm)< 0.2 Hg job number MRP-01958 Hg (ppm)0.05 Sb job number Sb (ppm) Te job number Te (ppm) Tl job number Tl (ppm) W job number W (ppm) Au job number Au (ppb) Pd-Pt job number Pd (ppb) Pt (ppb) Analyses by ICP Partial Chem ICP10 job number Ag (ppm) As (ppm) Au (ppb) Bi (ppm) Cd (ppm) Cu (ppm) Mo (ppm) Pb (ppm) Sb (ppm) Zn (ppm) Ga (ppm) Hg (ppm) Se (ppm) Te (ppm) Tl (ppm) Analyses by Fusion ICP Show data for sample C-143268 http://mrdata.usgs.gov/geochem/show.php?labno=C-143268[7/25/2016 3:03:31 PM] ICP16 job number Al (wt%) Ca (wt%) Fe (wt%) K (wt%) Mg (wt%) Na (wt%) P (wt%) Si (wt%) Ti (wt%) Ba (ppm) Cr (ppm) Mn (ppm) Nb (ppm) Sr (ppm) Y (ppm) Zr (ppm) Analyses by NAA INAA job no. (USGS) INAA job no. (Becquerel) Na (wt%) Sc (ppm) Ti (wt%) Cr (ppm) Fe (wt%) Co (ppm) Ni (ppm) Zn (ppm) As (ppm) Br (ppm) Rb (ppm) Sr (ppm) Zr (ppm) Mo (ppm) Sb (ppm) Cs (ppm) Show data for sample C-143268 http://mrdata.usgs.gov/geochem/show.php?labno=C-143268[7/25/2016 3:03:31 PM] Ba (ppm) La (ppm) Ce (ppm) Nd (ppm) Sm (ppm) Eu (ppm) Tb (ppm) Yb (ppm) Lu (ppm) Hf (ppm) Ta (ppm) W (ppm) Au (ppb) Th (ppm) U (ppm) DN job number U (ppm) Th (ppm) Analyses by XRF XRF job number SiO2 (wt%) Al2O3 (wt%) Fe2O3 (wt%) MgO (wt%) CaO (wt%) Na2O (wt%) K2O (wt%) TiO2 (wt%) P2O5 (wt%) MnO (wt%) LOI (wt%) Analyses for light elements C-S job number C-total (wt%) C-org (wt%) C-CO3 (wt%) Show data for sample C-143268 http://mrdata.usgs.gov/geochem/show.php?labno=C-143268[7/25/2016 3:03:31 PM] S (wt%) Analyses by NURE program Al (wt%)1.23 Ca (wt%)< 0.01 Fe (wt%)1.01 K (wt%)0.2 Mg (wt%)0.08 Na (wt%)0.04 Ag (ppm)0.1 As (ppm)1 Au (ppb)< 0.01 B (ppm) Ba (ppm)45 Be (ppm)0.5 Bi (ppm) Br (ppm) Cd (ppm) Ce (ppm)< 20 Cl (ppm) Co (ppm)12 Cr (ppm)5 Cs (ppm) Cu (ppm)3 Dy (ppm) Eu (ppm)< 1 F (ppm) Hf (ppm)29 Hg (ppm) La (ppm)4 Li (ppm)10 Lu (ppm)0.3 Mn (ppm)690 Mo (ppm)< 2 Nb (ppm)5 Ni (ppm)< 5 Show data for sample C-143268 http://mrdata.usgs.gov/geochem/show.php?labno=C-143268[7/25/2016 3:03:31 PM] P (ppm)800 Pb (ppm)< 10 Pt (ppm) Rb (ppm) Sb (ppm) Sc (ppm)3.3 Se (ppm)20 Sm (ppm)1 Sn (ppm)< 5 Sr (ppm) Ta (ppm) Tb (ppm) Th (ppm)3 Ti (wt%)5200 V (ppm)20 W (ppm)< 2 Y (ppm)< 5 Yb (ppm)2.7 Zn (ppm)10 Zr (ppm) U (ppm) best NURE 1.9 Processing information 2nd labno Previous lab number Field name as analyzed NCJO132S1 AOV code Replicate code Location count 1 Analytical notes NURE method codes SR1, SR2, SR3-AA;CA;FE;XU;XX Accessibility FOIA Privacy Policies and Notices U.S. Department of the Interior | U.S. Geological Survey URL: http://mrdata.usgs.gov/geochem/show.php?labno=C-143268 Page Contact Information: pschweitzer@usgs.gov Page Last modified: 15:03 on 28-Aug-2015 Show data for sample C-143434 http://mrdata.usgs.gov/geochem/show.php?labno=C-143434[7/25/2016 3:07:02 PM] USGS Home Contact USGS Search USGS Mineral Resources On-Line Spatial Data Mineral Resources > Online Spatial Data > National Geochemical Survey Database Data for C-143434 Report shows selected fields. [Full report] Show this location using [Google Earth] or [Google Maps] Sample identification NURE record ID 5287342 Lab identification number C-143434 Sample set NURE2000 Database join ID Sample category NURE Short description of sample type STRM-SED-WET Geographic location Map datum NAD27 Latitude 35.6118 Longitude -78.7266 1:24k quadrangle 36080NEC4 1:250k quadrangle 36080 1:100,000 quadrangle 36080NE FIPS of county f37183 Hydrologic unit 03020201 1:250k quad name Raleigh Zip code, 3-digit 275 Congressional district 3704C2 Sample characteristics Real field name NCWA064S1 Collection date 19760817 Description NURE sample, AEG015 1-02-411 Sample type code 50 Soil horizon Show data for sample C-143434 http://mrdata.usgs.gov/geochem/show.php?labno=C-143434[7/25/2016 3:07:02 PM] Color of reanalyzed powder tan Sample grain size Sample medium Sediment Sample source Stream Source modifier Wet Upper limit of sieve size 150 Drying procedure <110oC Sample type note Site characteristics Setting Active channel width 4-8' Water depth 0.5-1.0' Water color brown/clear Flow stage low Flow rate slow Stream bed sand Contamination source farm, sewage, unknown Contamination potential Contamination degree Vegetation deciduous pH of water 6.6 Sample characteristics (details) Lab grain size Fine Collector 71 Primary ID NCWA064S1 LANL field name ORGDP field name SRNL field name NCWA064S1 LLNL field name Other name info QA/QC info Replicate codes 000 Conductivity meas. in lab No. grabs 6 Collection hour Show data for sample C-143434 http://mrdata.usgs.gov/geochem/show.php?labno=C-143434[7/25/2016 3:07:02 PM] Est. %organics Study code Odor Site characteristics (details) Photographs Flood plain width Relief low Geologic formation Geologic unit Total alkalinity of water 0.22 Dissolved oxygen (ppm) Gamma activity Air temperature Water temperature 21 Conductivity of water 68 Stream velocity (m/s) Stream channel eroding Weather sunny/clear Vegetation density moderate Rock type Rock color Analyses by ICP/Acid dissolution ICP40 job MRP-01960 Al (wt%)1.087 Ca (wt%)0.165 Fe (wt%)0.99 K (wt%)0.21 Mg (wt%)0.06 Na (wt%)0.055 P (wt%)0.016 Ti (wt%)0.504 Ag (ppm)< 2 As (ppm)< 10 Au (ppb)< 8 Ba (ppm)84 Show data for sample C-143434 http://mrdata.usgs.gov/geochem/show.php?labno=C-143434[7/25/2016 3:07:02 PM] Be (ppm)< 1 Bi (ppm)< 50 Cd (ppm)< 2 Ce (ppm)53 Co (ppm)2 Cr (ppm)58 Cu (ppm)9 Eu (ppm)1 Ga (ppm)5 Ho (ppm)< 4 La (ppm)27 Li (ppm)4 Mn (ppm)339 Mo (ppm)< 2 Nb (ppm)6 Nd (ppm)24 Ni (ppm)< 3 Pb (ppm)8 Sc (ppm)3 Sn (ppm)< 50 Sr (ppm)16 Ta (ppm)< 40 Th (ppm)12 U (ppm)< 100 V (ppm)22 Y (ppm)7 Yb (ppm)< 1 Zn (ppm)37 Cs (ppm) Rb (ppm) Sb (ppm) Zr (ppm) Analyses by AA As job number MRP-01960 As (ppm)4.5 Show data for sample C-143434 http://mrdata.usgs.gov/geochem/show.php?labno=C-143434[7/25/2016 3:07:02 PM] Se job number MRP-01960 Se (ppm)< 0.2 Hg job number MRP-01960 Hg (ppm)0.05 Sb job number Sb (ppm) Te job number Te (ppm) Tl job number Tl (ppm) W job number W (ppm) Au job number Au (ppb) Pd-Pt job number Pd (ppb) Pt (ppb) Analyses by ICP Partial Chem ICP10 job number Ag (ppm) As (ppm) Au (ppb) Bi (ppm) Cd (ppm) Cu (ppm) Mo (ppm) Pb (ppm) Sb (ppm) Zn (ppm) Ga (ppm) Hg (ppm) Se (ppm) Te (ppm) Tl (ppm) Analyses by Fusion ICP ICP16 job number Show data for sample C-143434 http://mrdata.usgs.gov/geochem/show.php?labno=C-143434[7/25/2016 3:07:02 PM] Al (wt%) Ca (wt%) Fe (wt%) K (wt%) Mg (wt%) Na (wt%) P (wt%) Si (wt%) Ti (wt%) Ba (ppm) Cr (ppm) Mn (ppm) Nb (ppm) Sr (ppm) Y (ppm) Zr (ppm) Analyses by NAA INAA job no. (USGS) INAA job no. (Becquerel) Na (wt%) Sc (ppm) Ti (wt%) Cr (ppm) Fe (wt%) Co (ppm) Ni (ppm) Zn (ppm) As (ppm) Br (ppm) Rb (ppm) Sr (ppm) Zr (ppm) Mo (ppm) Sb (ppm) Cs (ppm) Ba (ppm) Show data for sample C-143434 http://mrdata.usgs.gov/geochem/show.php?labno=C-143434[7/25/2016 3:07:02 PM] La (ppm) Ce (ppm) Nd (ppm) Sm (ppm) Eu (ppm) Tb (ppm) Yb (ppm) Lu (ppm) Hf (ppm) Ta (ppm) W (ppm) Au (ppb) Th (ppm) U (ppm) DN job number U (ppm) Th (ppm) Analyses by XRF XRF job number SiO2 (wt%) Al2O3 (wt%) Fe2O3 (wt%) MgO (wt%) CaO (wt%) Na2O (wt%) K2O (wt%) TiO2 (wt%) P2O5 (wt%) MnO (wt%) LOI (wt%) Analyses for light elements C-S job number C-total (wt%) C-org (wt%) C-CO3 (wt%) S (wt%) Show data for sample C-143434 http://mrdata.usgs.gov/geochem/show.php?labno=C-143434[7/25/2016 3:07:02 PM] Analyses by NURE program Al (wt%)0.95 Ca (wt%)0.01 Fe (wt%)1.13 K (wt%)< 0.1 Mg (wt%)0.06 Na (wt%)0.04 Ag (ppm)< 0.1 As (ppm)5 Au (ppb)< 0.01 B (ppm) Ba (ppm)5 Be (ppm)< 0.5 Bi (ppm) Br (ppm) Cd (ppm) Ce (ppm)49 Cl (ppm) Co (ppm)5 Cr (ppm)< 5 Cs (ppm) Cu (ppm)4 Dy (ppm) Eu (ppm)< 1 F (ppm) Hf (ppm)35 Hg (ppm) La (ppm)21 Li (ppm)6 Lu (ppm)0.5 Mn (ppm) Mo (ppm)< 2 Nb (ppm)< 5 Ni (ppm)5 P (ppm)1000 Show data for sample C-143434 http://mrdata.usgs.gov/geochem/show.php?labno=C-143434[7/25/2016 3:07:02 PM] Pb (ppm)< 10 Pt (ppm) Rb (ppm) Sb (ppm) Sc (ppm)2.9 Se (ppm)1 Sm (ppm)3 Sn (ppm)< 5 Sr (ppm) Ta (ppm) Tb (ppm) Th (ppm)9 Ti (wt%)2900 V (ppm)20 W (ppm)< 2 Y (ppm)5 Yb (ppm)3 Zn (ppm)12 Zr (ppm) U (ppm) best NURE 2.8 Processing information 2nd labno Previous lab number Field name as analyzed NCWA064S1 AOV code Replicate code Location count 1 Analytical notes NURE method codes SR1, SR2, SR3-AA;CA;FE;XU;XX Accessibility FOIA Privacy Policies and Notices U.S. Department of the Interior | U.S. Geological Survey URL: http://mrdata.usgs.gov/geochem/show.php?labno=C-143434 Page Contact Information: pschweitzer@usgs.gov Page Last modified: 15:03 on 28-Aug-2015 Show data for sample C-143678 http://mrdata.usgs.gov/geochem/show.php?labno=C-143678[7/25/2016 2:57:02 PM] USGS Home Contact USGS Search USGS Mineral Resources On-Line Spatial Data Mineral Resources > Online Spatial Data > National Geochemical Survey Database Data for C-143678 Report shows selected fields. [Full report] Show this location using [Google Earth] or [Google Maps] Sample identification NURE record ID 5286764 Lab identification number C-143678 Sample set NURE2000 Database join ID Sample category NURE Short description of sample type STRM-SED-WET Geographic location Map datum NAD27 Latitude 35.6349 Longitude -78.2528 1:24k quadrangle 36080NEF3 1:250k quadrangle 36080 1:100,000 quadrangle 36080NE FIPS of county f37101 Hydrologic unit 03020201 1:250k quad name Raleigh Zip code, 3-digit 275 Congressional district 3702C2 Sample characteristics Real field name NCJO127S1 Collection date 19760904 Description NURE sample, AEG017 1-02-655 Sample type code 50 Soil horizon Show data for sample C-143678 http://mrdata.usgs.gov/geochem/show.php?labno=C-143678[7/25/2016 2:57:02 PM] Color of reanalyzed powder tan Sample grain size Sample medium Sediment Sample source Stream Source modifier Wet Upper limit of sieve size 150 Drying procedure <110oC Sample type note Site characteristics Setting Active channel width 2-4' Water depth <0.5' Water color brown/clear Flow stage low Flow rate slow Stream bed sand Contamination source Contamination potential Contamination degree Vegetation deciduous pH of water 7.2 Sample characteristics (details) Lab grain size Fine Collector 57 Primary ID NCJO127S1 LANL field name ORGDP field name SRNL field name NCJO127S1 LLNL field name Other name info QA/QC info Replicate codes 000 Conductivity meas. in lab No. grabs 6 Collection hour Show data for sample C-143678 http://mrdata.usgs.gov/geochem/show.php?labno=C-143678[7/25/2016 2:57:02 PM] Est. %organics Study code Odor Site characteristics (details) Photographs Flood plain width Relief low Geologic formation Geologic unit Total alkalinity of water 0.72 Dissolved oxygen (ppm) Gamma activity Air temperature Water temperature 19 Conductivity of water 120 Stream velocity (m/s) Stream channel unknown Weather overcast Vegetation density moderate Rock type Rock color Analyses by ICP/Acid dissolution ICP40 job MRP-01962 Al (wt%)1.393 Ca (wt%)0.608 Fe (wt%)0.88 K (wt%)0.14 Mg (wt%)0.031 Na (wt%)0.18 P (wt%)0.011 Ti (wt%)0.704 Ag (ppm)< 2 As (ppm)< 10 Au (ppb)< 8 Ba (ppm)70 Show data for sample C-143678 http://mrdata.usgs.gov/geochem/show.php?labno=C-143678[7/25/2016 2:57:02 PM] Be (ppm)< 1 Bi (ppm)< 50 Cd (ppm)< 2 Ce (ppm)20 Co (ppm)3 Cr (ppm)10 Cu (ppm)7 Eu (ppm)1 Ga (ppm)4 Ho (ppm)< 4 La (ppm)10 Li (ppm)4 Mn (ppm)320 Mo (ppm)< 2 Nb (ppm)11 Nd (ppm)< 9 Ni (ppm)< 3 Pb (ppm)11 Sc (ppm)7 Sn (ppm)< 50 Sr (ppm)37 Ta (ppm)< 40 Th (ppm)< 6 U (ppm)< 100 V (ppm)28 Y (ppm)6 Yb (ppm)< 1 Zn (ppm)21 Cs (ppm) Rb (ppm) Sb (ppm) Zr (ppm) Analyses by AA As job number MRP-01962 As (ppm)0.9 Show data for sample C-143678 http://mrdata.usgs.gov/geochem/show.php?labno=C-143678[7/25/2016 2:57:02 PM] Se job number MRP-01962 Se (ppm)0.6 Hg job number MRP-01962 Hg (ppm)0.08 Sb job number Sb (ppm) Te job number Te (ppm) Tl job number Tl (ppm) W job number W (ppm) Au job number Au (ppb) Pd-Pt job number Pd (ppb) Pt (ppb) Analyses by ICP Partial Chem ICP10 job number Ag (ppm) As (ppm) Au (ppb) Bi (ppm) Cd (ppm) Cu (ppm) Mo (ppm) Pb (ppm) Sb (ppm) Zn (ppm) Ga (ppm) Hg (ppm) Se (ppm) Te (ppm) Tl (ppm) Analyses by Fusion ICP ICP16 job number Show data for sample C-143678 http://mrdata.usgs.gov/geochem/show.php?labno=C-143678[7/25/2016 2:57:02 PM] Al (wt%) Ca (wt%) Fe (wt%) K (wt%) Mg (wt%) Na (wt%) P (wt%) Si (wt%) Ti (wt%) Ba (ppm) Cr (ppm) Mn (ppm) Nb (ppm) Sr (ppm) Y (ppm) Zr (ppm) Analyses by NAA INAA job no. (USGS) INAA job no. (Becquerel) Na (wt%) Sc (ppm) Ti (wt%) Cr (ppm) Fe (wt%) Co (ppm) Ni (ppm) Zn (ppm) As (ppm) Br (ppm) Rb (ppm) Sr (ppm) Zr (ppm) Mo (ppm) Sb (ppm) Cs (ppm) Ba (ppm) Show data for sample C-143678 http://mrdata.usgs.gov/geochem/show.php?labno=C-143678[7/25/2016 2:57:02 PM] La (ppm) Ce (ppm) Nd (ppm) Sm (ppm) Eu (ppm) Tb (ppm) Yb (ppm) Lu (ppm) Hf (ppm) Ta (ppm) W (ppm) Au (ppb) Th (ppm) U (ppm) DN job number U (ppm) Th (ppm) Analyses by XRF XRF job number SiO2 (wt%) Al2O3 (wt%) Fe2O3 (wt%) MgO (wt%) CaO (wt%) Na2O (wt%) K2O (wt%) TiO2 (wt%) P2O5 (wt%) MnO (wt%) LOI (wt%) Analyses for light elements C-S job number C-total (wt%) C-org (wt%) C-CO3 (wt%) S (wt%) Show data for sample C-143678 http://mrdata.usgs.gov/geochem/show.php?labno=C-143678[7/25/2016 2:57:02 PM] Analyses by NURE program Al (wt%)1.12 Ca (wt%)0.01 Fe (wt%)1.78 K (wt%)0.1 Mg (wt%)0.05 Na (wt%)0.15 Ag (ppm)0.1 As (ppm) Au (ppb)< 0.01 B (ppm) Ba (ppm)22 Be (ppm)0.5 Bi (ppm) Br (ppm) Cd (ppm) Ce (ppm)< 94 Cl (ppm) Co (ppm)5 Cr (ppm)5 Cs (ppm) Cu (ppm)3 Dy (ppm) Eu (ppm) F (ppm) Hf (ppm)25 Hg (ppm) La (ppm)3 Li (ppm)5 Lu (ppm)< 0.6 Mn (ppm)250 Mo (ppm)< 2 Nb (ppm)5 Ni (ppm)< 5 P (ppm)700 Show data for sample C-143678 http://mrdata.usgs.gov/geochem/show.php?labno=C-143678[7/25/2016 2:57:02 PM] Pb (ppm)< 10 Pt (ppm) Rb (ppm) Sb (ppm) Sc (ppm)3.2 Se (ppm)1 Sm (ppm)1 Sn (ppm)< 5 Sr (ppm) Ta (ppm) Tb (ppm) Th (ppm)3 Ti (wt%)6500 V (ppm)30 W (ppm)< 2 Y (ppm)< 5 Yb (ppm) Zn (ppm)7 Zr (ppm) U (ppm) best NURE 1.4 Processing information 2nd labno Previous lab number Field name as analyzed NCJO127S1 AOV code Replicate code Location count 1 Analytical notes NURE method codes SR1, SR2, SR3-AA;CA;FE;XU;XX Accessibility FOIA Privacy Policies and Notices U.S. Department of the Interior | U.S. Geological Survey URL: http://mrdata.usgs.gov/geochem/show.php?labno=C-143678 Page Contact Information: pschweitzer@usgs.gov Page Last modified: 15:03 on 28-Aug-2015 Show data for sample C-143910 http://mrdata.usgs.gov/geochem/show.php?labno=C-143910[7/25/2016 3:04:13 PM] USGS Home Contact USGS Search USGS Mineral Resources On-Line Spatial Data Mineral Resources > Online Spatial Data > National Geochemical Survey Database Data for C-143910 Report shows selected fields. [Full report] Show this location using [Google Earth] or [Google Maps] Sample identification NURE record ID 5286773 Lab identification number C-143910 Sample set NURE2000 Database join ID Sample category NURE Short description of sample type STRM-SED-WET Geographic location Map datum NAD27 Latitude 35.7508 Longitude -78.2965 1:24k quadrangle 36080NEF2 1:250k quadrangle 36080 1:100,000 quadrangle 36080NE FIPS of county f37101 Hydrologic unit 03020201 1:250k quad name Raleigh Zip code, 3-digit 275 Congressional district 3702C2 Sample characteristics Real field name NCJO136S1 Collection date 19760903 Description NURE sample, AEG019 1-02-887 Sample type code 50 Soil horizon Show data for sample C-143910 http://mrdata.usgs.gov/geochem/show.php?labno=C-143910[7/25/2016 3:04:13 PM] Color of reanalyzed powder tan Sample grain size Sample medium Sediment Sample source Stream Source modifier Wet Upper limit of sieve size 150 Drying procedure <110oC Sample type note Site characteristics Setting Active channel width 8-16' Water depth 2-4' Water color clear Flow stage low Flow rate slow Stream bed sand Contamination source Contamination potential Contamination degree Vegetation deciduous pH of water 7.3 Sample characteristics (details) Lab grain size Collector 57 Primary ID NCJO136S1 LANL field name ORGDP field name SRNL field name NCJO136S1 LLNL field name Other name info QA/QC info Replicate codes 000 Conductivity meas. in lab No. grabs 5 Collection hour Show data for sample C-143910 http://mrdata.usgs.gov/geochem/show.php?labno=C-143910[7/25/2016 3:04:13 PM] Est. %organics Study code Odor Site characteristics (details) Photographs Flood plain width Relief low Geologic formation Geologic unit Total alkalinity of water 0.36 Dissolved oxygen (ppm) Gamma activity Air temperature Water temperature 20 Conductivity of water 58 Stream velocity (m/s) Stream channel depositing Weather overcast Vegetation density moderate Rock type Rock color Analyses by ICP/Acid dissolution ICP40 job MRP-01964 Al (wt%)4.84 Ca (wt%)0.404 Fe (wt%)0.98 K (wt%)2.89 Mg (wt%)0.121 Na (wt%)0.736 P (wt%)0.035 Ti (wt%)0.464 Ag (ppm)< 2 As (ppm)< 10 Au (ppb)< 8 Ba (ppm)1270 Show data for sample C-143910 http://mrdata.usgs.gov/geochem/show.php?labno=C-143910[7/25/2016 3:04:13 PM] Be (ppm)1 Bi (ppm)< 50 Cd (ppm)< 2 Ce (ppm)144 Co (ppm)3 Cr (ppm)24 Cu (ppm)7 Eu (ppm)1 Ga (ppm)13 Ho (ppm)< 4 La (ppm)75 Li (ppm)7 Mn (ppm)275 Mo (ppm)< 2 Nb (ppm)20 Nd (ppm)54 Ni (ppm)6 Pb (ppm)35 Sc (ppm)4 Sn (ppm)< 50 Sr (ppm)250 Ta (ppm)< 40 Th (ppm)39 U (ppm)< 100 V (ppm)29 Y (ppm)9 Yb (ppm)< 1 Zn (ppm)26 Cs (ppm) Rb (ppm) Sb (ppm) Zr (ppm) Analyses by AA As job number MRP-01964 As (ppm)< 0.6 Show data for sample C-143910 http://mrdata.usgs.gov/geochem/show.php?labno=C-143910[7/25/2016 3:04:13 PM] Se job number MRP-01964 Se (ppm)< 0.2 Hg job number MRP-01964 Hg (ppm)0.04 Sb job number Sb (ppm) Te job number Te (ppm) Tl job number Tl (ppm) W job number W (ppm) Au job number Au (ppb) Pd-Pt job number Pd (ppb) Pt (ppb) Analyses by ICP Partial Chem ICP10 job number Ag (ppm) As (ppm) Au (ppb) Bi (ppm) Cd (ppm) Cu (ppm) Mo (ppm) Pb (ppm) Sb (ppm) Zn (ppm) Ga (ppm) Hg (ppm) Se (ppm) Te (ppm) Tl (ppm) Analyses by Fusion ICP ICP16 job number Show data for sample C-143910 http://mrdata.usgs.gov/geochem/show.php?labno=C-143910[7/25/2016 3:04:13 PM] Al (wt%) Ca (wt%) Fe (wt%) K (wt%) Mg (wt%) Na (wt%) P (wt%) Si (wt%) Ti (wt%) Ba (ppm) Cr (ppm) Mn (ppm) Nb (ppm) Sr (ppm) Y (ppm) Zr (ppm) Analyses by NAA INAA job no. (USGS) INAA job no. (Becquerel) Na (wt%) Sc (ppm) Ti (wt%) Cr (ppm) Fe (wt%) Co (ppm) Ni (ppm) Zn (ppm) As (ppm) Br (ppm) Rb (ppm) Sr (ppm) Zr (ppm) Mo (ppm) Sb (ppm) Cs (ppm) Ba (ppm) Show data for sample C-143910 http://mrdata.usgs.gov/geochem/show.php?labno=C-143910[7/25/2016 3:04:13 PM] La (ppm) Ce (ppm) Nd (ppm) Sm (ppm) Eu (ppm) Tb (ppm) Yb (ppm) Lu (ppm) Hf (ppm) Ta (ppm) W (ppm) Au (ppb) Th (ppm) U (ppm) DN job number U (ppm) Th (ppm) Analyses by XRF XRF job number SiO2 (wt%) Al2O3 (wt%) Fe2O3 (wt%) MgO (wt%) CaO (wt%) Na2O (wt%) K2O (wt%) TiO2 (wt%) P2O5 (wt%) MnO (wt%) LOI (wt%) Analyses for light elements C-S job number C-total (wt%) C-org (wt%) C-CO3 (wt%) S (wt%) Show data for sample C-143910 http://mrdata.usgs.gov/geochem/show.php?labno=C-143910[7/25/2016 3:04:13 PM] Analyses by NURE program Al (wt%)3.94 Ca (wt%)0.02 Fe (wt%)0.62 K (wt%)1.2 Mg (wt%)0.1 Na (wt%)0.69 Ag (ppm)< 0.1 As (ppm)1 Au (ppb)< 0.01 B (ppm) Ba (ppm)102 Be (ppm)1 Bi (ppm) Br (ppm) Cd (ppm) Ce (ppm)251 Cl (ppm) Co (ppm)10 Cr (ppm)14 Cs (ppm) Cu (ppm)5 Dy (ppm)4.2 Eu (ppm) F (ppm) Hf (ppm)43 Hg (ppm) La (ppm)118 Li (ppm)9 Lu (ppm)< 0.3 Mn (ppm)380 Mo (ppm)< 2 Nb (ppm)< 5 Ni (ppm)5 P (ppm)1000 Show data for sample C-143910 http://mrdata.usgs.gov/geochem/show.php?labno=C-143910[7/25/2016 3:04:13 PM] Pb (ppm)< 10 Pt (ppm) Rb (ppm) Sb (ppm) Sc (ppm)2.3 Se (ppm)1 Sm (ppm)13 Sn (ppm)< 5 Sr (ppm) Ta (ppm) Tb (ppm) Th (ppm)81 Ti (wt%)5700 V (ppm)30 W (ppm)< 2 Y (ppm)5 Yb (ppm) Zn (ppm)15 Zr (ppm) U (ppm) best NURE 7.6 Processing information 2nd labno Previous lab number Field name as analyzed NCJO136S1 AOV code Replicate code Location count 1 Analytical notes NURE method codes SR1, SR2, SR3-AA;CA;FE;XU;XX Accessibility FOIA Privacy Policies and Notices U.S. Department of the Interior | U.S. Geological Survey URL: http://mrdata.usgs.gov/geochem/show.php?labno=C-143910 Page Contact Information: pschweitzer@usgs.gov Page Last modified: 15:03 on 28-Aug-2015 Show data for sample C-210806 http://mrdata.usgs.gov/geochem/show.php?labno=C-210806[7/20/2016 2:51:34 PM] USGS Home Contact USGS Search USGS Mineral Resources On-Line Spatial Data Mineral Resources > Online Spatial Data > National Geochemical Survey Database Data for C-210806 Report shows selected fields. [Full report] Show this location using [Google Earth] or [Google Maps] Sample identification NURE record ID 5287357 Lab identification number C-210806 Sample set NURE2002 Database join ID Sample category NURE Short description of sample type STRM-SED-WET Geographic location Map datum NAD27 Latitude 35.7271 Longitude -78.5137 1:24k quadrangle 36080NED3 1:250k quadrangle 36080 1:100,000 quadrangle 36080NE FIPS of county f37183 Hydrologic unit 03020201 1:250k quad name Raleigh Zip code, 3-digit 276 Congressional district 3713C2 Sample characteristics Real field name NCWA079S1 Collection date 19760817 Description NURE sample, AEG301 1-30-081 Sample type code 50 Soil horizon Show data for sample C-210806 http://mrdata.usgs.gov/geochem/show.php?labno=C-210806[7/20/2016 2:51:34 PM] Color of reanalyzed powder tan Sample grain size Sample medium Sediment Sample source Stream Source modifier Wet Upper limit of sieve size 150 Drying procedure <110oC Sample type note Site characteristics Setting Active channel width >16' Water depth 4-8' Water color cloudy Flow stage low Flow rate mod Stream bed sand Contamination source urban, sewage, farm Contamination potential Contamination degree Vegetation deciduous pH of water 7.5 Sample characteristics (details) Lab grain size Fine Collector 71 Primary ID NCWA079S1 LANL field name ORGDP field name SRNL field name NCWA079S1 LLNL field name Other name info QA/QC info Replicate codes 000 Conductivity meas. in lab No. grabs 8 Collection hour Show data for sample C-210806 http://mrdata.usgs.gov/geochem/show.php?labno=C-210806[7/20/2016 2:51:34 PM] Est. %organics Study code Odor Site characteristics (details) Photographs Flood plain width Relief low Geologic formation Geologic unit Total alkalinity of water 0.44 Dissolved oxygen (ppm) Gamma activity Air temperature Water temperature 25 Conductivity of water 180 Stream velocity (m/s) Stream channel eroding Weather sunny/clear Vegetation density moderate Rock type Rock color Analyses by ICP/Acid dissolution ICP40 job MRP-04168 Al (wt%)6.386 Ca (wt%)0.983 Fe (wt%)3.1 K (wt%)2.39 Mg (wt%)0.254 Na (wt%)1.107 P (wt%)0.044 Ti (wt%)0.571 Ag (ppm)< 2 As (ppm)< 10 Au (ppb)< 8 Ba (ppm)644 Show data for sample C-210806 http://mrdata.usgs.gov/geochem/show.php?labno=C-210806[7/20/2016 2:51:34 PM] Be (ppm)2 Bi (ppm)< 50 Cd (ppm)< 2 Ce (ppm)52 Co (ppm)7 Cr (ppm)21 Cu (ppm)24 Eu (ppm)< 2 Ga (ppm)17 Ho (ppm)< 4 La (ppm)27 Li (ppm)12 Mn (ppm)555 Mo (ppm)< 2 Nb (ppm)11 Nd (ppm)23 Ni (ppm)25 Pb (ppm)60 Sc (ppm)9 Sn (ppm)< 50 Sr (ppm)193 Ta (ppm)< 40 Th (ppm)14 U (ppm)< 100 V (ppm)91 Y (ppm)11 Yb (ppm)2 Zn (ppm)81 Cs (ppm) Rb (ppm) Sb (ppm) Zr (ppm) Analyses by AA As job number MRP-04168 As (ppm)1.3 Show data for sample C-210806 http://mrdata.usgs.gov/geochem/show.php?labno=C-210806[7/20/2016 2:51:34 PM] Se job number MRP-04168 Se (ppm)< 0.2 Hg job number MRP-04168 Hg (ppm)0.16 Sb job number Sb (ppm) Te job number Te (ppm) Tl job number Tl (ppm) W job number W (ppm) Au job number Au (ppb) Pd-Pt job number Pd (ppb) Pt (ppb) Analyses by ICP Partial Chem ICP10 job number Ag (ppm) As (ppm) Au (ppb) Bi (ppm) Cd (ppm) Cu (ppm) Mo (ppm) Pb (ppm) Sb (ppm) Zn (ppm) Ga (ppm) Hg (ppm) Se (ppm) Te (ppm) Tl (ppm) Analyses by Fusion ICP ICP16 job number Show data for sample C-210806 http://mrdata.usgs.gov/geochem/show.php?labno=C-210806[7/20/2016 2:51:34 PM] Al (wt%) Ca (wt%) Fe (wt%) K (wt%) Mg (wt%) Na (wt%) P (wt%) Si (wt%) Ti (wt%) Ba (ppm) Cr (ppm) Mn (ppm) Nb (ppm) Sr (ppm) Y (ppm) Zr (ppm) Analyses by NAA INAA job no. (USGS) INAA job no. (Becquerel) Na (wt%) Sc (ppm) Ti (wt%) Cr (ppm) Fe (wt%) Co (ppm) Ni (ppm) Zn (ppm) As (ppm) Br (ppm) Rb (ppm) Sr (ppm) Zr (ppm) Mo (ppm) Sb (ppm) Cs (ppm) Ba (ppm) Show data for sample C-210806 http://mrdata.usgs.gov/geochem/show.php?labno=C-210806[7/20/2016 2:51:34 PM] La (ppm) Ce (ppm) Nd (ppm) Sm (ppm) Eu (ppm) Tb (ppm) Yb (ppm) Lu (ppm) Hf (ppm) Ta (ppm) W (ppm) Au (ppb) Th (ppm) U (ppm) DN job number U (ppm) Th (ppm) Analyses by XRF XRF job number SiO2 (wt%) Al2O3 (wt%) Fe2O3 (wt%) MgO (wt%) CaO (wt%) Na2O (wt%) K2O (wt%) TiO2 (wt%) P2O5 (wt%) MnO (wt%) LOI (wt%) Analyses for light elements C-S job number C-total (wt%) C-org (wt%) C-CO3 (wt%) S (wt%) Show data for sample C-210806 http://mrdata.usgs.gov/geochem/show.php?labno=C-210806[7/20/2016 2:51:34 PM] Analyses by NURE program Al (wt%)5.34 Ca (wt%)0.03 Fe (wt%)2.08 K (wt%)1.2 Mg (wt%)0.15 Na (wt%)1.35 Ag (ppm)0.4 As (ppm)6 Au (ppb)< 0.01 B (ppm) Ba (ppm)270 Be (ppm)2 Bi (ppm) Br (ppm) Cd (ppm) Ce (ppm)48 Cl (ppm) Co (ppm)12 Cr (ppm)6 Cs (ppm) Cu (ppm)17 Dy (ppm)4.9 Eu (ppm)3.9 F (ppm) Hf (ppm)7 Hg (ppm) La (ppm)15 Li (ppm)7 Lu (ppm)0.2 Mn (ppm) Mo (ppm)< 2 Nb (ppm)< 5 Ni (ppm)5 P (ppm)1000 Show data for sample C-210806 http://mrdata.usgs.gov/geochem/show.php?labno=C-210806[7/20/2016 2:51:34 PM] Pb (ppm)47 Pt (ppm) Rb (ppm) Sb (ppm) Sc (ppm)5.8 Se (ppm)< 1 Sm (ppm)2 Sn (ppm)10 Sr (ppm) Ta (ppm) Tb (ppm) Th (ppm)16 Ti (wt%)4900 V (ppm)80 W (ppm)< 2 Y (ppm)< 5 Yb (ppm) Zn (ppm)60 Zr (ppm) U (ppm) best NURE 3.7 Processing information 2nd labno Previous lab number Field name as analyzed NCWA079S1 AOV code Replicate code Location count 1 Analytical notes NURE method codes SR1, SR2, SR3-AA;CA;FE;XU;XX Accessibility FOIA Privacy Policies and Notices U.S. Department of the Interior | U.S. Geological Survey URL: http://mrdata.usgs.gov/geochem/show.php?labno=C-210806 Page Contact Information: pschweitzer@usgs.gov Page Last modified: 15:03 on 28-Aug-2015 Show data for sample C-210808 http://mrdata.usgs.gov/geochem/show.php?labno=C-210808[7/25/2016 3:08:21 PM] USGS Home Contact USGS Search USGS Mineral Resources On-Line Spatial Data Mineral Resources > Online Spatial Data > National Geochemical Survey Database Data for C-210808 Report shows selected fields. [Full report] Show this location using [Google Earth] or [Google Maps] Sample identification NURE record ID 5287322 Lab identification number C-210808 Sample set NURE2002 Database join ID Sample category NURE Short description of sample type STRM-SED-WET Geographic location Map datum NAD27 Latitude 35.7249 Longitude -78.7786 1:24k quadrangle 36080NEB3 1:250k quadrangle 36080 1:100,000 quadrangle 36080NE FIPS of county f37183 Hydrologic unit 03020201 1:250k quad name Raleigh Zip code, 3-digit 275 Congressional district 3704C2 Sample characteristics Real field name NCWA044S1 Collection date 19760816 Description NURE sample, AEG301 1-30-092 Sample type code 50 Soil horizon Show data for sample C-210808 http://mrdata.usgs.gov/geochem/show.php?labno=C-210808[7/25/2016 3:08:21 PM] Color of reanalyzed powder tan Sample grain size Sample medium Sediment Sample source Stream Source modifier Wet Upper limit of sieve size 150 Drying procedure <110oC Sample type note Site characteristics Setting Active channel width >16' Water depth 0.5-1.0' Water color brown/clear Flow stage low Flow rate slow Stream bed sand Contamination source urban Contamination potential Contamination degree Vegetation deciduous pH of water 7.3 Sample characteristics (details) Lab grain size Fine Collector 71 Primary ID NCWA044S1 LANL field name ORGDP field name SRNL field name NCWA044S1 LLNL field name Other name info QA/QC info Replicate codes 000 Conductivity meas. in lab No. grabs 5 Collection hour Show data for sample C-210808 http://mrdata.usgs.gov/geochem/show.php?labno=C-210808[7/25/2016 3:08:21 PM] Est. %organics Study code Odor Site characteristics (details) Photographs Flood plain width Relief low Geologic formation Geologic unit Total alkalinity of water 0.34 Dissolved oxygen (ppm) Gamma activity Air temperature Water temperature 21 Conductivity of water 98 Stream velocity (m/s) Stream channel eroding Weather overcast Vegetation density moderate Rock type Rock color Analyses by ICP/Acid dissolution ICP40 job MRP-04168 Al (wt%)2.582 Ca (wt%)0.772 Fe (wt%)2.26 K (wt%)0.35 Mg (wt%)0.115 Na (wt%)0.523 P (wt%)< 0.005 Ti (wt%)0.292 Ag (ppm)< 2 As (ppm)< 10 Au (ppb)< 8 Ba (ppm)116 Show data for sample C-210808 http://mrdata.usgs.gov/geochem/show.php?labno=C-210808[7/25/2016 3:08:21 PM] Be (ppm)< 1 Bi (ppm)< 50 Cd (ppm)< 2 Ce (ppm)22 Co (ppm)5 Cr (ppm)9 Cu (ppm)6 Eu (ppm)< 2 Ga (ppm)7 Ho (ppm)< 4 La (ppm)11 Li (ppm)5 Mn (ppm)938 Mo (ppm)< 2 Nb (ppm)< 4 Nd (ppm)11 Ni (ppm)10 Pb (ppm)12 Sc (ppm)8 Sn (ppm)< 50 Sr (ppm)97 Ta (ppm)< 40 Th (ppm)< 6 U (ppm)< 100 V (ppm)9 Y (ppm)9 Yb (ppm)1 Zn (ppm)41 Cs (ppm) Rb (ppm) Sb (ppm) Zr (ppm) Analyses by AA As job number MRP-04168 As (ppm)4.9 Show data for sample C-210808 http://mrdata.usgs.gov/geochem/show.php?labno=C-210808[7/25/2016 3:08:21 PM] Se job number MRP-04168 Se (ppm)< 0.2 Hg job number MRP-04168 Hg (ppm)0.07 Sb job number Sb (ppm) Te job number Te (ppm) Tl job number Tl (ppm) W job number W (ppm) Au job number Au (ppb) Pd-Pt job number Pd (ppb) Pt (ppb) Analyses by ICP Partial Chem ICP10 job number Ag (ppm) As (ppm) Au (ppb) Bi (ppm) Cd (ppm) Cu (ppm) Mo (ppm) Pb (ppm) Sb (ppm) Zn (ppm) Ga (ppm) Hg (ppm) Se (ppm) Te (ppm) Tl (ppm) Analyses by Fusion ICP ICP16 job number Show data for sample C-210808 http://mrdata.usgs.gov/geochem/show.php?labno=C-210808[7/25/2016 3:08:21 PM] Al (wt%) Ca (wt%) Fe (wt%) K (wt%) Mg (wt%) Na (wt%) P (wt%) Si (wt%) Ti (wt%) Ba (ppm) Cr (ppm) Mn (ppm) Nb (ppm) Sr (ppm) Y (ppm) Zr (ppm) Analyses by NAA INAA job no. (USGS) INAA job no. (Becquerel) Na (wt%) Sc (ppm) Ti (wt%) Cr (ppm) Fe (wt%) Co (ppm) Ni (ppm) Zn (ppm) As (ppm) Br (ppm) Rb (ppm) Sr (ppm) Zr (ppm) Mo (ppm) Sb (ppm) Cs (ppm) Ba (ppm) Show data for sample C-210808 http://mrdata.usgs.gov/geochem/show.php?labno=C-210808[7/25/2016 3:08:21 PM] La (ppm) Ce (ppm) Nd (ppm) Sm (ppm) Eu (ppm) Tb (ppm) Yb (ppm) Lu (ppm) Hf (ppm) Ta (ppm) W (ppm) Au (ppb) Th (ppm) U (ppm) DN job number U (ppm) Th (ppm) Analyses by XRF XRF job number SiO2 (wt%) Al2O3 (wt%) Fe2O3 (wt%) MgO (wt%) CaO (wt%) Na2O (wt%) K2O (wt%) TiO2 (wt%) P2O5 (wt%) MnO (wt%) LOI (wt%) Analyses for light elements C-S job number C-total (wt%) C-org (wt%) C-CO3 (wt%) S (wt%) Show data for sample C-210808 http://mrdata.usgs.gov/geochem/show.php?labno=C-210808[7/25/2016 3:08:21 PM] Analyses by NURE program Al (wt%)1.93 Ca (wt%)0.02 Fe (wt%) K (wt%)0.1 Mg (wt%)0.085 Na (wt%)0.44 Ag (ppm)0.1 As (ppm)2 Au (ppb)< 0.01 B (ppm) Ba (ppm)< 5 Be (ppm)< 0.5 Bi (ppm) Br (ppm) Cd (ppm) Ce (ppm) Cl (ppm) Co (ppm)7 Cr (ppm)< 5 Cs (ppm) Cu (ppm)4 Dy (ppm) Eu (ppm) F (ppm) Hf (ppm)5 Hg (ppm) La (ppm) Li (ppm)6 Lu (ppm) Mn (ppm)840 Mo (ppm)< 2 Nb (ppm)5 Ni (ppm)7 P (ppm)700 Show data for sample C-210808 http://mrdata.usgs.gov/geochem/show.php?labno=C-210808[7/25/2016 3:08:21 PM] Pb (ppm)< 10 Pt (ppm) Rb (ppm) Sb (ppm) Sc (ppm)3.8 Se (ppm)1 Sm (ppm) Sn (ppm)< 5 Sr (ppm) Ta (ppm) Tb (ppm) Th (ppm) Ti (wt%)10200 V (ppm)50 W (ppm)< 2 Y (ppm)5 Yb (ppm) Zn (ppm)15 Zr (ppm) U (ppm) best NURE 1 Processing information 2nd labno Previous lab number Field name as analyzed NCWA044S1 AOV code Replicate code Location count 1 Analytical notes NURE method codes SR1, SR2, SR3-AA;CA;FE;XU;XX Accessibility FOIA Privacy Policies and Notices U.S. Department of the Interior | U.S. Geological Survey URL: http://mrdata.usgs.gov/geochem/show.php?labno=C-210808 Page Contact Information: pschweitzer@usgs.gov Page Last modified: 15:03 on 28-Aug-2015 Golder Associates NC, Inc. 5B Oak Branch Drive Greensboro, NC 27407 USA (336) 852-4903 - Phone (336) 852-4904 - Fax