3901_GranvilleOxfordC&D_GWMR_DIN27799_20160810

PREPARED FOR:
GRANVILLE COUNTY
SOLID WASTE DEPARTMENT
P.O. BOX 906
OXFORD, NORTH CAROLINA 27565

OXFORD UNIT 1 LANDFILL
PERMIT NO. 3901-CDLF-1997

SECOND SEMIANNUAL WATER QUALITY
MONITORING REPORT OF 2016

OCTOBER 2016

PREPARED BY:

2211 WEST MEADOWVIEW ROAD, SUITE 101
GREENSBORO, NORTH CAROLINA 27407
NC LICENSE NUMBER C-0782
PHONE: [phone]
FAX: [phone]
JOYCE PROJECT NO. 660.1701.12

SECOND SEMIANNUAL WATER QUALITY MONITORING REPORT OF 2016
Oxford Unit 1 Landfill - Granville County - Permit No. 3901-CDLF-1997

TABLE OF CONTENTS

Second Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 October 2016
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1.0 INTRODUCTION ................................................................................................................. 1
1.1 Site Background .................................................................................................................. 1
1.2 Site Conceptual Model ........................................................................................................ 2
1.2.1 Site Geology ............................................................................................................ 2
1.2.2 Site Hydrogeology ................................................................................................... 2
1.3 Aquifer Characteristics & Groundwater Flow Regime ....................................................... 3
1.4 Monitoring History and Regulatory Status ......................................................................... 3
1.4.1 Monitoring History .................................................................................................. 3
1.4.2 Regulatory Status .................................................................................................... 4
2.0 FACILITY MONITORING PROGRAM ........................................................................... 5
2.1 Groundwater Monitoring Program ...................................................................................... 5
2.2 Surface Water Monitoring Program .................................................................................... 7
3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2016 ............................................... 7
3.1 Field Work ........................................................................................................................... 7
3.2 Laboratory Analysis and Quality Control ........................................................................... 7
3.3 Data Analyses ...................................................................................................................... 8
3.3.1 Analytical Results for Groundwater ........................................................................ 8
3.3.1.1 Inorganic Analyses ............................................................................................................................................ 8
3.3.1.2 Organic Analyses .............................................................................................................................................. 9
3.3.1.3 Performance and Sentinel Wells ........................................................................................................................ 9
3.3.2 Analytical Results for Surface Water ...................................................................... 9
3.3.3 Statistical Analyses ............................................................................................... 10
3.3.3.1 Statistical Methods ............................................................................................................................................ 10
3.3.3.2 Results of Statistical Analyses ............................................................................................................................. 10
4.0 EVALUATION OF MONITORED NATURAL ATTENUATION (MNA) .................. 11
4.1 MNA Parameters and Biodegradation Screening Matrix ................................................. 11
4.2 Trend Analysis and Plume Stability .................................................................................. 12
5.0 CONCLUSIONS .................................................................................................................. 12
6.0 REFERENCES .................................................................................................................... 13
7.0 ACRONYMS ....................................................................................................................... 14

SECOND SEMIANNUAL WATER QUALITY MONITORING REPORT OF 2016
Oxford Unit 1 Landfill - Granville County - Permit No. 3901-CDLF-1997

TABLE OF CONTENTS

Second Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
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TABLES:
Table 1 Monitoring Well Construction Data
Table 2 Historical Groundwater Elevation Data
Table 3 Groundwater Gradients and Calculated Flow Rates
Table 4 Quantified Detections in Groundwater and Surface Water
Table 5 Exceedances of Groundwater and Surface Water Standards
Table 6 Field Parameters
Table 7 Statistical Background Results
Table 8 Biodegradation Screening Matrix

CHARTS:
Chart 1 Vinyl Chloride in MW-5 & MW-5R vs. Time
Chart 2 1,1-Dichloroethane in MW-5 & MW-5R vs. Time

FIGURE:
Figure 1 Site Location Map (USGS Topographic Map)

DRAWING:
Drawing 1 Groundwater Potentiometric Surface Map

APPENDICES:
Appendix A Field Sampling Logs
Appendix B Laboratory Reports with Chains of Custody
Appendix C Historical Detected Inorganic Constituents in Compliance Wells
Appendix D Historical Detected Organic Constituents in Compliance Wells
Appendix E Historical Detected COCs in Performance and Sentinel Wells
Appendix F Historical Detected Constituents in Surface Water
Appendix G Historical MNA Parameter Data
Appendix H Statistical Analysis Worksheets

Second Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
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1.0 INTRODUCTION
On behalf of Granville County, Joyce Engineering, (JOYCE) has prepared this Water Quality
Monitoring Report for the Oxford Unit 1 Landfill, Solid Waste Permit Number
3901-CDLF-1997 (facility), in accordance with 15A NCAC 13B.1632 of the North Carolina
Solid Waste Management Rules (NCSWMR).

1.1 Site Background
The Oxford Landfill is located at 6584 Landfill Road, Oxford, Granville County, North Carolina,
near the town of Kinton Fork (Figure 1). The facility is owned and operated by Granville
County under Permit Number 3901-CDLF-1997, issued by the North Carolina Department of
Environment and Natural Resources (NCDENR), now the Department of Environmental Quality
(NCDEQ), Solid Waste Section (SWS). The Oxford Landfill consists of two separate waste
disposal units. Unit 1 is a former unlined municipal solid waste (MSW) landfill originally
permitted for disposal of domestic, institutional, industrial, agricultural, and demolition wastes,
with an active C&D landfill on top. Unit 2 is a Subtitle-D MSW landfill. Currently, the facility
is disposing of construction and demolition (C&D) wastes in Unit 1 on top of the closed MSW
landfill in accordance with their Transition Plan dated 1994. The permitted facility consists of
approximately 283 acres, of which approximately 29 acres constitutes the Unit 1 Landfill waste
unit.

The groundwater monitoring network at the Unit 1 landfill consists of one upgradient well
(MW-7) and five downgradient wells (MW-2, MW-3R, MW-4R, MW-5R and MW-6R) as
shown on Drawing 1. Monitoring wells MW-3R, MW-4R, MW-5R, and MW-6R replaced
MW-3, MW-4, MW-5, and MW-6, respectively, in 1999, due to the close proximity to waste of
the original wells. Wells NES-1S&D and NES-2S&D were installed down-gradient of MW-4R
and MW-5R, respectively in May 2004 as part of the Nature and Extent Study (NES). The
Corrective Action Plan (CAP) dated April 23, 2009 designated NES-1S and NES-2S as
performance wells and NES-1D and NES-2D as sentinel wells; however, NES-1D and NES-1S
were removed from the monitoring network in June 2014. NES-1D was abandoned in July 2016.
MW-7 replaced MW-1A as the facility background well beginning with the first semiannual
monitoring event of 2011. The monitoring wells are screened within the uppermost aquifer
underlying the facility. Well construction details are summarized in Table 1.

In addition, there are two surface water sampling points, SW-1 and SW-2 associated with Unit 1.
Sampling point SW-1 is a sedimentation pond located near the southeast corner of the waste unit,
and is up-stream of waste. Sampling point SW-2 is a small creek located northeast of the waste
unit and is downstream of the waste unit. The locations of SW-1 and SW-2 are shown on
Drawing 1.

Second Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
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1.2 Site Conceptual Model
1.2.1 Site Geology
The Oxford Unit 1 Landfill is located in the Carolina Slate Belt of the Piedmont Physiographic
Province of North Carolina. The geologic province is characterized by a rolling topography with
a thick mantle of saprolite overlying Late Proterozoic and Paleozoic igneous and metamorphic
bedrock. The Carolina Slate Belt is comprised of 550 to 650 million year old, metamorphosed
sedimentary and volcanic rocks, intruded by granitic rocks.

The Oxford Unit 1 Landfill is underlain by the Flat River Complex, which is a shallow intrusive
complex of granitic composition, which comprises a large portion of the northern Carolina Slate
Belt (Butler, 1991). The landfill is approximately 18 miles east of the Virgilina Synclinorium,
approximately 10 miles west of the Nutbush Creek Fault Zone, and approximately 4 miles
northwest of the Durham Basin (Butler, 1991).

Previous investigations discovered limited exposures in the borrow area of a competent, massive,
gray to greenish gray meta-volcanic rock that is moderately fractured with prominent fractures
with near vertical dips and striking approximately N25o to 30oW (Woodward-Clyde, 1994).
Boring logs indicate that the depth to bedrock at Oxford Unit 1 Landfill ranges from 5 to 30 feet
below ground surface. The overlying saprolite consists of brownish sandy to clayey silt
(Woodward-Clyde, 1994).

1.2.2 Site Hydrogeology
Groundwater in the Piedmont can occur in substantial volumes where soils and regolith are thick,
but groundwater is typically found in minimal volumes in bedrock, primarily restricted to
fractures. The water table under the area of investigation was encountered in the unconfined
aquifer that is mostly in the transition zone that consists of saprolite and highly fractured
bedrock. This unconfined aquifer is pervasive across the site and generally mimics the surface
topography. The saturated portion of the uppermost aquifer beneath the study area is vertically
continuous to bedrock, and no confining layers have been encountered during site investigations.
There is a high degree of connectivity between the saprolite and underlying fractured bedrock
such that they behave as a single continuous aquifer. Depth to water ranged from 5 to 10 feet
below grade in wells MW-4R, MW-6R, NES-2S, and NES-2D; and 10 to 25 feet below grade in
MW-1A, MW-2, MW-3R, MW-5R, MW-7, NES-1S, and NES-1D (Table 2). In general, the
water table is near the saprolite/bedrock interface.

Groundwater in the saprolite feeds the fractures in the bedrock and is discharged into creeks
north of the landfill. Groundwater flow at deeper levels within the fractured bedrock is
controlled by fractures. A groundwater potentiometric surface map, based on static water level
data obtained on August 10, 2016, is presented as Drawing 1. The groundwater map depicts
groundwater flow to the north.

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1.3 Aquifer Characteristics & Groundwater Flow Regime
Depth to groundwater is measured in all compliance monitoring wells at the site prior to each
sampling event. The groundwater elevations calculated relative to the surveyed measuring point
(top of casing) for each monitoring well are summarized in Table 2. The groundwater elevation
contours shown in Drawing 1 are based on data from the August 2016 sampling event.
Groundwater flow beneath the Unit 1 Landfill is primarily to the north. Horizontal groundwater
gradients were estimated from the August 2016 groundwater levels and are summarized in Table
3. Horizontal gradients across the site ranged from 0.0145 to 0.0196 ft/ft. These values are
consistent with previous estimates.

Linear groundwater flow velocities for wells screened in saprolite were computed using the
following modified Darcy equation: V = Ki/n , where V = average linear velocity
(feet/year), K = hydraulic conductivity (feet/day), i = horizontal hydraulic gradient, and n =
effective porosity. The mean of hydraulic conductivities from slug-tests conducted in 1995,
1999 and 2004 (K = 4.36 ft/day) were used in these calculations, along with an estimated
effective porosity of 0.31 based on 85% of the average of laboratory-determined porosities for
site soil. The average estimated linear groundwater flow velocity under the facility was
calculated at 100.38 ft/year (Table 3). The linear velocity equation makes the simplifying
assumptions of a homogeneous and isotropic aquifer.

1.4 Monitoring History and Regulatory Status
1.4.1 Monitoring History
 1995: Oxford Unit 1 entered Assessment Monitoring due to detections of organic
constituents in several monitoring wells.
 1998: Monitoring wells MW-3R, MW-4R, MW-5R, and MW-6R replaced MW-3,
MW-4, MW-5, and MW-6, respectively.
 2003: Assessment of Corrective Measures (ACM) and Nature and Extent Study (NES)
initiated due to 15A NCAC 2L.0202(NC-2L) Groundwater Standard exceedances of
benzene in MW-4R and vinyl chloride in MW-5R.
 May 2004: Nature and Extent wells NES-1S&D and NES-2S&D installed.
 May 2005: NES, ACM, & Risk Assessment submitted to the SWS.
 August 21, 2006: ACM Public Meeting held in Oxford, NC.
 June 2008: Corrective Action Plan (CAP) submitted to the SWS.
 December 2008: First Baseline sampling event for MNA
 March 2009: Final Revision of CAP submitted to the SWS.
 April 23, 2009: CAP Approved by the SWS.
 June 2010: Final Baseline sampling event for MNA.
 December 23, 2010: Request for Background Well Replacement approved by the SWS
makes MW-7 (formerly P-2) the new site background monitoring well.
 January 27, 2011: Corrective Action Evaluation Report (CAER) reviewed and approved
by the SWS with an updated list of constituents of concern (COCs), along with the

Second Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
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Alternate Source Demonstration (ASD) for Chromium, Thallium and TDS in MW-1A.
The SWS denied the request to remove selected MNA parameters but allowed a modified
monitoring frequency (beginning June 2011).
 June 9, 2011: The ASD for Iron and Manganese approved by the SWS.
 February 24, 2012: Beta-BHC added to COC list due to confirmed exceedance during
the December 2011 sampling event.
 June 3, 2014: The SWS approved the following: Monitoring wells MW-2, MW-3R,
MW-4R, and MW-6R reverted back to detection monitoring (Appendix I) from assessment
monitoring (Appendix II). NES-1S and NES-1D were removed from the groundwater
corrective action monitoring network. Sampling for Monitored Natural Attenuation
parameters in monitoring wells MW-3R and MW-4R was discontinued.
 July 30, 2015: Corrective Action Evaluation Report (CAER) reviewed and approved by
the SWS with an updated list of COCs, removing 1,1-dichloroethane and beta-BHC from
the COC list.
 July 8, 2016: Well NES-1D abandoned.

1.4.2 Regulatory Status
The Oxford Unit 1 Landfill has remained in Assessment Monitoring since 1995 due to detections
of organic constituents. There were NC-2L Standard exceedances of benzene in MW-4R in
2003, which have not been detected since, and there have been persistent NC-2L exceedances of
vinyl chloride in MW-5R from 2003 to present. The County received a letter from the SWS
dated August 20, 2003, that requested the County to proceed with assessment activities at Oxford
Unit 1 Landfill. A meeting between JOYCE and the SWS was held on February 11, 2004, to
discuss the SWS’s requirements for a Nature and Extent Study (NES) and an Assessment of
Corrective Measures (ACM). In May 2005, Granville County submitted a NES (JOYCE,
2005a), and an ACM (JOYCE, 2005b) and a Quantitative Risk Assessment (QRA) (JOYCE,
2005c) to the SWS in accordance with 15A NCAC 13B.1634. Granville County held a public
meeting for the ACM on August 21, 2006. A CAP was submitted in June 2008, with revisions in
October 2008 and March 2009 (JOYCE, 2009). The CAP proposed Monitored Natural
Attenuation (MNA) as the primary remedy, supplemented with Control of Decomposition
Gasses as a secondary remedy. The CAP was approved in a letter from the SWS dated April 23,
2009. The gas interception trench proposed in the Control of Decomposition Gasses was
installed July 2009. The last sampling event for the Baseline MNA was completed in December
2010.

A Request for Background Well Replacement was submitted to the SWS October 25, 2010
because the background monitoring well, MW-1A, was dry or affected by low water levels and
excessive sediment as well as possible bore seal damage. The request proposed piezometer P-2
to be upgraded and re-named MW-7 to become the facility background monitoring well. The
SWS approved the request on December 23, 2010. MW-7 became the background monitoring
well for the first semiannual sampling event of 2011.

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An Alternate Source Demonstration for Iron and Manganese was submitted to the SWS October
26, 2010, after the requirements for additional constituent monitoring for C&D facilities showed
elevated concentrations of iron and manganese across multiple site wells in June 2010. The ASD
showed that the concentrations of iron and manganese were a result of natural occurrence in site
soil and not a release from the landfill. The ASD for Iron and Manganese was approved as
described by the SWS on June 9, 2011.

The first CAER was submitted to the SWS on November 29, 2010, and in a letter dated January
27, 2011, the SWS reviewed and approved the CAER. The SWS denied a request to remove
some of the MNA parameters made on behalf of the county, but did approve a reduced alternate
monitoring frequency as follows; carbon dioxide, ferrous iron, volatile fatty acids, total organic
carbon (TOC), sulfide, and dissolved ethane and ethane for every third year on a semiannual
basis. The SWS also approved removing benzene and cis-1,2-dichloroethylene from the COC
list and adding 1,1-dichloroethane. As a result, the current COC list includes vinyl chloride and
1,1-dichloroethane. The ASD for chromium, thallium, and total dissolved solids in MW-1A was
also approved. The Oxford Unit 1 landfill continues in Assessment Monitoring, with additional
C&D indicator parameters and selected MNA parameters and COC monitored at designated
wells at frequencies presented in the January 27, 2011 SWS review of the CAER and ASD and
summarized in the next section.

Beta-BHC was added to the COC list due to confirmed exceedance during the December 2011
sampling event.

In a letter dated May 22, 2014 Joyce Engineering requested the following changes:
 Revert groundwater monitoring wells MW-2, MW-3R, MW-4R, and MW-6R from
assessment monitoring (Appendix II) to detection monitoring (Appendix I).
 Remove groundwater monitoring wells NES-1S and NES-1D from the groundwater
corrective action monitoring network.
 Discontinue sampling for Monitored Natural Attenuation parameters in groundwater
monitoring wells MW-3R and MW-4R.
The SWS granted approval of the changes in a letter dated June 3, 2014.

The second CAER was submitted to the SWS on July 10, 2015, and in a letter dated July 30, 2015,
the SWS reviewed and approved the CAER. The SWS approval included removal of
1,1-dichloroethane and beta-BHC from the COC list due to the lack of recent exceedances. This left
vinyl chloride as the only COC for the facility.

2.0 FACILITY MONITORING PROGRAM
2.1 Groundwater Monitoring Program
Six groundwater monitoring wells comprise the compliance monitoring network at the Oxford
Unit 1 Landfill. The compliance network includes monitoring wells MW-7 (the current facility

Second Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
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background well), MW-2, MW-3R, MW-4R, MW-5R, and MW-6R. In addition, there is one
performance well (NES-2S) that is sampled under the Corrective Action Plan (CAP) for the
facility. Monitoring wells MW-3R, MW-4R, MW-5R, and MW-6R replaced MW-3, MW-4,
MW-5, and MW-6, respectively, in August 1999, due to the close proximity to waste of the
original wells. The former background well, MW-1, was abandoned in 2001 after being
damaged by a vehicle. MW-1A was replaced as the background monitoring well by MW-7 in
2011, as described in Section 1.4.2, above. MW-1A is still monitored for static water level.
Monitoring wells NES-2S, and NES-2D were installed as part of the NES in May 2004. The
following table summarizes the monitoring network and required analytical parameters for the
second semiannual sampling event of 2016:

Groundwater Monitoring Network
Monitoring
Well
Date
Installed Classification Monitoring
Program TD Lithology of Screened
Interval
1st SA Event
Analyses
2nd SA Event
Analyses
MW-1A unknown Observation Water
Level 28.77 Saprolite NS NS
MW-2 unknown Compliance Detection 29.34 Saprolite/Bedrock App. I, C&D App. I, C&D
MW-3R 8/25/99 Compliance Detection 27.12 Partially Weathered
Rock App. I, C&D App. I, C&D
MW-4R 8/26/99 Compliance Detection 63.22 Bedrock App. I, C&D App. I, C&D
MW-5R 8/25/99 Compliance Assessment 40.25 Bedrock App. II, C&D,
MNA
App. I + Det.,
C&D, MNA
MW-6R 8/25/99 Compliance Detection 42.90 Bedrock App. I, C&D App. I, C&D
MW-7 7/28/08 Background Assessment 34.50 Partially Weathered
Rock
App. II, C&D,
MNA
App. I + Det.,
C&D, MNA
NES-2S 5/11/04 Performance CAMP 21.5 Saprolite COC, MNA COC, MNA
NES-2D 5/11/04 Sentinel CAMP 66.5 Bedrock COC, MNA NS
App. I = NCSWMR Appendix I list of constituents. COC = Constituents of concern.
App. II = NCSWMR Appendix II list of constituents. MNA = Monitoring Natural Attenuation parameters.
App. I + Det. = App. I list plus detected App. II constituents. C&D = C&D indicator parameters.
NS = Not Sampled (After baseline period, sentinel wells are sampled annually).
CAMP = Corrective Action Monitoring Plan.

C&D indicator parameters: mercury, manganese, iron, sulfate, chloride, alkalinity, total
dissolved solids (TDS), temperature, pH, and specific conductance.

Current Appendix II detected constituents: mercury, sulfide, endosulfan I, and beta-
BHC.

Constituents of Concern: 1,1-dichloroethane, vinyl chloride, and beta-BHC.

MNA Field Parameters: Temperature, pH, specific conductance, oxidation reduction
potential, turbidity, dissolved oxygen on a semiannual basis. Dissolved carbon dioxide,
and ferrous iron are sampled for both sampling events every third year.

MNA Laboratory Parameters: Dissolved hydrogen, dissolved methane, nitrate, sulfate,
chloride, alkalinity on a semiannual basis. Sulfide, TOC, ethane, ethene, and volatile
fatty acids are sampled for both sampling events every third year.

Second Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
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2.2 Surface Water Monitoring Program
There are two surface water sampling points, SW-1 and SW-2 associated with the Unit 1 landfill.
Sampling point SW-1 is located in a sedimentation basin near the southeast corner of the waste
unit, upgradient of the waste. Sampling point SW-2 is located northeast of the waste unit along a
tributary of Little Grassy Creek, down-gradient of the waste. The surface water samples are
analyzed for the NCSWMR Appendix I list of constituents during both semiannual events.

3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2016
3.1 Field Work
On August 10-11, 2016, JOYCE personnel visited Oxford Unit 1 Landfill to purge and sample
monitoring wells MW-7, MW-2, MW-3R, MW-4R, MW-5R, MW-6R, and NES-2S, collect
samples from surface points SW-1 and SW-2, and obtain a water level for MW-1A.

Monitoring wells were purged and sampled using a 12 volt submersible pump or disposable
bailers. Field measurements of temperature, pH, specific conductivity, and turbidity were
recorded in a field log for all wells and surface water points. For selected wells, additional MNA
field parameters were also measured and recorded. Prior to sampling, laboratory-supplied
containers were prepared with the following information:
 Monitoring well ID (completed by laboratory or field personnel);
 Date and time of sample collection (completed by field personnel);
 Initials of sampling personnel (completed by field personnel);
 Project name and number (completed by the laboratory or field personnel);
 Chemical preservative (completed by the laboratory or field personnel); and
 Requested chemical analysis (completed by the laboratory or field personnel).

Groundwater samples from each monitoring well were collected either immediately after purging
or within 24 hours of the final purge volume and were dispensed directly from the pump flow or
bailers into the provided laboratory containers. Immediately after collection, the samples were
placed in a laboratory provided cooler and chilled on ice. Field sampling logs are provided in
Appendix A.

Surface water point SW-1 and SW-2 were sampled using a decontaminated graduated dipper.
Prepared sampling containers were filled from the dipper, placed in a cooler, and chilled on ice.
Field sampling logs are provided in Appendix A.

3.2 Laboratory Analysis and Quality Control
Pace Analytical Services Inc. of Huntersville, North Carolina analyzed the August 2016
groundwater and surface water samples under chain-of-custody control. Groundwater samples
from the compliance wells were analyzed for the parameters summarized in Section 2.1. The
surface water samples were analyzed for NC Appendix I constituents. The samples were

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received by the laboratory August 12, 2016, in good condition, properly preserved, at proper
temperatures, and within analysis hold times.

In addition to samples collected for compliance monitoring at the Oxford Unit 1 Landfill,
JOYCE personnel collected a Field Blank as part of the August 2016 sampling event. The Field
Blank was analyzed for the NC Appendix I plus previously detected Appendix II constituents,
plus iron, manganese and tetrahydrofuran. Also, a Trip Blank that was prepared by the
laboratory accompanied the volatile sampling containers to and from the laboratory. The Trip
Blank was analyzed for the NC Appendix II list of volatile organic compounds and
tetrahydrofuran.

Upon receipt of the laboratory data package, JOYCE personnel reviewed the following data:

 General typographical errors;
 Correct analyses performed and within method specified hold times;
 Biased data results based on Matrix Spike, Matrix Spike Duplicate, and Laboratory Control
Samples;
 Blank qualified data (B-flags);
 Detections above the 15A NCAC 2L (NC-2L) Groundwater Standards or NCDEQ Solid
Waste Section Groundwater Water Protection Standards (GWPS), or 15A NCAC 2B (NC-
2B) Surface Water Standards; and
 Detections above historical levels.

The complete laboratory analytical packages and chains of custody for the August 2016
sampling event are included in Appendix B. Historical data tables are included in Appendices C,
D, E, F, and G. Constituents with quantified detections during the August 2016 sampling event
are summarized in Table 4. Constituents with exceedances of groundwater or surf ace water
standards during the August 2016 sampling event are summarized in Table 5. Field parameters
for the August 2016 event are summarized in Table 6.

3.3 Data Analyses
3.3.1 Analytical Results for Groundwater
3.3.1.1 Inorganic Analyses
Inorganic constituents detected at quantified concentrations above the NCDEQ Solid Waste
Section (SWS) report limits (SWSL) in one or monitoring wells during the August 2016 event
include: barium, cobalt, chromium, iron, manganese, vanadium, zinc, alkalinity, chloride,
vanadium, zinc and TDS. A summary of all constituents with quantified detections for the
August 2016 event is presented as Table 4. The laboratory analytical reports, the laboratory
quality assurance/quality control information, and the chains of custody, are included in the
Appendix B. Complete historical analytical results for inorganic constituents are presented in
Appendix C.

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Cobalt, chromium, iron, vanadium, manganese, and TDS were detected at quantified
concentrations above their NC 2L or GWPS in one or more monitoring well samples. Iron and
manganese were shown to be naturally occurring in an ASD approved by the NCDEQ-SWS on
June 9, 2011. The detections of chromium, cobalt, and vanadium in MW-2 were below the
statistical background for those constituents (see Section 3.3.3). The TDS in MW-6R was below
the statistical background based on intrawell statistical data for MW-6R (see Section 3.3.3). We
request that the background values be considered the GPS for chromium, cobalt, vanadium, and
TDS per NCSWMR rule .1634.g.5

3.3.1.2 Organic Analyses
The only organic constituent detected at a quantified concentration above the SWSL during the
August 2016 sampling event was vinyl chloride in MW-5R. Vinyl chloride in MW-5R was also
above the NC 2L Standard, and therefore is in exceedance of the Groundwater Protection
Standard (GPS) as defined in 15A NCAC 13B.1634.g. There were no other quantified detections
or exceedances for organic constituents.

A summary of all constituents with quantified detections for the August 2016 event is presented
as Table 4, and a summary of groundwater and surface water exceedances for the August 2016
event is presented as Table 5. The laboratory analytical reports, the laboratory quality
assurance/quality control information, and the chains of custody, are included in the Appendix B.
Complete historical analytical results for organic constituents are presented in Appendix D.

3.3.1.3 Performance and Sentinel Wells
Corrective action performance well, NES-2S was sampled for the contaminants of concern
(COCs) list approved by the SWS and for MNA parameters. No COCs were detected above the
SWSL, and therefore there were no GPS exceedances in the sample from the performance well.
A summary of historical detections of COCs in performance and sentinel wells for the facility is
provided in Appendix E.

3.3.2 Analytical Results for Surface Water
Sampling point SW-1 is located in a sedimentation basin near the southeast corner of the waste
unit, upstream of the waste. Sampling point SW-2 is located northeast of the waste unit along a
tributary of Little Grassy Creek, downstream of the waste.

Surface water analytical results from the site were compared to the 15A-NCAC-2B (NC 2B)
surface water standards for protection of freshwater aquatic life or human health, whichever is
lower (more protective) for a given constituent. Barium, beryllium, chromium, cobalt, copper,
lead, vanadium, and zinc were all detected above their SWSL’s in SW-1 and SW-2 during the
August 2016 event. Chromium, copper, and zinc were detected at levels exceeding their
respective NC2B standards in both SW-1 and SW-2, Lead was also exceeding the NC2B
standard in SW-1.

Second Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 October 2016
10

Verification sampling for metals in SW-1 and SW-2 was conducted on September 13, 2016 but
due to seasonably dry conditions, SW-2 was unable to be sampled. The resample results refuted
all exceedances in SW-1.

The analytical results from the August 2016 surface water sampling event and the September
2016 resample of SW-1 at the Oxford Unit 1 Landfill are presented along with historical data in
Appendix F. The laboratory analytical reports, the laboratory quality assurance/quality control
information, and the chain of custody, are included in Appendix B.

3.3.3 Statistical Analyses
3.3.3.1 Statistical Methods
Monitoring well MW-1A was designated as the background well for the facility until the first
semiannual sampling of 2011. Prior to the spring 2001 sampling event, the site had two
background wells, MW-1 and MW-1A. MW-1 was damaged by a vehicle and, with the approval
of NCDEQ, was abandoned in early 2001. MW-1A was affected by low water levels and impact
from high turbidity levels during more recent events, and was therefore approved to be replaced
by MW-7 as the background for the first semiannual sampling event of 2011. Data from MW-1
between September 1994 and October 2000, data from MW-1A from September 1994 to June
2010 and data from MW-7 from June 2011 to present have been used to determine statistical
background concentrations for inorganic constituents detected at the facility in exceedance of
their respective NC-2L or GWPS. Alternatively, intrawell statistics may be used for a
downgradient well by excluding the most recent 6-8 samples and using the earlier results from
that well as the background data.

The background data for inorganic constituents are evaluated in accordance with the procedures
outlined in 15A NCAC 13B.1632 (g) and (h) to determine if the reported concentrations
exceeded the facility background concentrations using the Shapiro-Wilk Test, Parametric
Prediction Limits, Parametric Tolerance Intervals, Aitchison’s Adjustment, Non-Parametric
Prediction Limits, and Poisson Prediction Limits as appropriate. Background data, tests for
normality, outliers, Aitchison’s adjustment, tolerance interval, or prediction limits are used, as
appropriate based on the background data. The statistical test by which downgradient data are
compared to facility background data is based upon the nature of the data and the number of data
values that are less than the laboratory limit of detection. All statistical tests are evaluated at the
0.05 level of significance, 95% confidence level, and are conducted as one-tailed tests.

3.3.3.2 Results of Statistical Analyses
Iron and manganese were detected in several wells at concentrations above the NC-2L standard
in the August 2016 samples. Iron and manganese were shown to be naturally occurring in an
ASD approved by the NCDEQ-SWS on June 9, 2011.

Second Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 October 2016
11

Chromium, cobalt, and vanadium were detected above their respective NC2L or GWPS in
MW-2 during the August 2016 sampling event. Interwell statistics based on the data from the
upgradient background wells were used to determine the background concentration for these
three metals. TDS was detected above its NC2L standard in MW-6R during the August 2016
monitoring event. Intrawell statistics was performed on the TDS results from MW-6R between
June 2010 and August 2013 (i.e., excluding the most recent 6 measurements). The results of the
statistical background analyses are summarized in Table 7 and the complete statistical analysis
worksheets are included as Appendix H.

On behalf of Granville County, JOYCE requests that the background values for chromium,
cobalt, vanadium, and TDS be considered the GPS per NCSWMR rule .1634.g.5.

4.0 EVALUATION OF MONITORED NATURAL ATTENUATION (MNA)
4.1 MNA Parameters and Biodegradation Screening Matrix
In accordance with the CAP for the facility, MNA baseline sampling was initiated with the
December 2008 sampling event. The June 2010 sampling event was the fourth and final baseline
sampling event for MNA. MNA sampling was continued in accordance with the modified
sampling frequency approved by NCDEQ-SWS on January 27, 2011.

During the August 2016 sampling event, the MNA parameters were obtained for the:
background well MW-7, downgradient compliance well MW-5R; and performance well
NES-2S. MNA parameters included field parameters temperature, pH, specific conductance,
oxidation reduction potential, turbidity, dissolved oxygen, as well as laboratory parameters
dissolved hydrogen, nitrate, sulfate, chloride, alkalinity, and methane. In addition, the
performance well (NES-2S) was sampled and analyzed for the COC vinyl chloride. Field
parameter data for the August 2016 event are summarized in Table 6. Field data logs and
laboratory reports are included in Appendices A and B, respectively. The MNA parameter data
from the August 2016 event, as well as historical MNA data, are presented in Appendix G.

The MNA parameter data were evaluated in general accordance with the United States
Environmental Protection Agency’s (EPA’s) Technical Protocol Manual (EPA, 1998) to
determine whether the conditions are conducive to, or whether there is evidence for anaerobic
degradation of the chlorinated hydrocarbons. Specifically, the results were evaluated according
to the weighted system presented in Table 2.3 of the Technical Protocol Manual, referred to
hereafter as the Biodegradation Screening Matrix. According to this manual, a score less than 5
indicates that there is inadequate evidence for anaerobic natural attenuation, a score of 6 to 14
indicates that there is limited evidence for anaerobic natural attenuation, a score of 15 to 19
indicates that there is adequate evidence for anaerobic natural attenuation, and a score of 20 or
more indicates that there is strong evidence that anaerobic natural attenuation is occurring.

The evaluation was performed for data from MW-5R based on the results from the August 2016
sampling event. The Biodegradation Screening Matrix is presented in Table 8 of this report.

Second Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 October 2016
12

One aspect of the scoring process is ambiguous with respect to how it should be applied to a
landfill site such as this facility, and that is the issue of daughter products. Methane, carbon
dioxide (CO2), cis-1,2-dichloroethylene, vinyl chloride, and 1,1-dichlroethane can all be
daughter products produced by the biodegradation of higher-order chlorinated ethanes and
ethenes, and as such, their presence can be strong indicators that biodegradation is occurring, and
are therefore included in the EPA scoring matrix. On the other hand, methane and CO2 are gases
produced by the natural metabolization of biomass by microorganisms in a landfill, and cis-1,2-
dichloroethylene, vinyl chloride, and 1,1-dichloroethane can be primary contaminants leached
from waste in landfills. Some of these compounds are present in the groundwater plume;
however, it is unclear whether or not they are daughter products indicating natural attenuation.
For this reason, the score for MW-5R has been calculated both with and without the points for
daughter products.

The following table summarizes the scoring results from Table 8 for both options for interpreting
the data. The scores ranged from 8 to 16 (limited evidence of natural attenuation to adequate
evidence of natural attenuation). In reality, the best score is probably in the middle of this range.

Points Awarded
including DP’s
Points Awarded
excluding DP’s
16 8
DP’s = Points for possible daughter products.

4.2 Trend Analysis and Plume Stability
Chart 1 shows the concentration of vinyl chloride (VC) versus time for MW-5 and MW-5R from
June 1994 through August 2016. Similarly, Chart 2 shows the 1,1-dichloroethane (1,1-DCA)
concentration versus time for the same time period and the same wells. Both charts include best-
fit trend lines through the MW-5R data and both display decreasing trends. 1,1-dichloroethane
has not been detected n exceedance of the NC2L standard since June 2011. These data show that
the plume is generally stable and/or decreasing, and that natural attenuation is adequately
controlling the plume.

5.0 CONCLUSIONS
Iron and manganese were again detected in several wells at concentrations above the NC-2L
standard in the August 2016 samples; however, an ASD showing that iron and manganese are
naturally occurring was approved by NCDEQ-SWS. Chromium, cobalt, and vanadium were
detected in exceedance of their respective NC2L or GWPS in MW-2 during the August 2016
event. TDS was detected in exceedance of its NC2L in MW-6R during the August 2016 event.
On behalf of Granville County, JOYCE requests that the background values for chromium,
cobalt, vanadium, and TDS be considered the GPS per NCSWMR rule .1634.g.5.

Vinyl chloride was detected in MW-5R in exceedance of its NC-2L Standard during the August
2015 sampling, which is consistent with historical data. There were no other exceedances for

Second Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 October 2016
13

organic constituents. Overall, the organic detections are consistent with historical data from the
site and indicate decreasing trends. MNA data continues to indicate some evidence that natural
attenuation is occurring in the vicinity of MW-5R. There have been downward trends for all
VOCs included the only remaining COC, vinyl chloride, indicating that natural attenuation is
adequately controlling the plume.

The groundwater flow regime is consistent with previous data and the groundwater monitoring
system remains adequate for monitoring the site. The next semiannual sampling event is
tentatively scheduled for February 2017.

6.0 REFERENCES
The references cited herein were used to prepare this document and may or may not be cited in
the text of this report.

Butler, J. Robert, and Secor, Jr., Donald T., 1991, The Central Piedmont, in Horton, J. W., Jr.,
and Zullo, V. A., eds., The Geology of the Carolinas: The University of Tennessee Press,
p. 59-78.

Cowie, S. (2004). Emission of Non-methane Organic Compounds (NMOCs) and hazardous air
Pollutants (HAPs) from Decomposing Refuse and Individual Waste Components and
Under Different Conditions. Master’s Thesis, North Carolina State University.

Deisper, A. and Stegmann, R. (1994). The Origin and Fate of Volatile Trace Components in
Municipal Solid Waste Landfills. Waste Management & Research. v. 12, p. 129-139.

Joyce Engineering, (JOYCE), 2005a. Nature and Extent Study, Granville County Oxford
Landfill. May 2005.

JOYCE, 2005b. Assessment of Corrective Measures, Granville County Oxford Landfill. May
2005.

JOYCE, 2005c. Quantitative Risk Assessment, Granville County Oxford Landfill. May 2005.

JOYCE, 2009. Corrective Action Plan, Granville County Oxford Landfill. March 2009.

JOYCE, 2010a. Request for Background Well Replacement, Granville County Oxford Landfill,
Permit # 39-01. October 25, 2010.

JOYCE, 2010b. Alternate Source Demonstration for Iron and Manganese, Granville County
Oxford C&D Over MSW Landfill, Permit # 39-01. October 26, 2010.

Second Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 October 2016
14

JOYCE, 2010c. Corrective Action Evaluation Report and Alternate Source
Demonstrations,Granville County Oxford C&D Over MSW Landfill, Permit # 39-01.
November 29, 2010.

JOYCE, 2011. Second Semiannual Water Quality Report of 2010, Oxford Landfill, Granville
County, Permit Number 39-01. May 2011.

North Carolina Department of Environment, Health, and Natural Resources, 1997. North
Carolina Solid Waste Management Rules. 15 NCAC 13B.1600. January 1, 1997.

North Carolina Geological Survey, 1985, Geologic map of North Carolina: North Carolina
Department of Natural Resources and Community Development, scale 1:500000.

NRC, 2000. Natural Attenuation for Groundwater Remediation. National Academy Press,
Washington, D.C. pp. 108-111.

USEPA, 1998. Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents
in Groundwater. ORD, EPA/600/R-98/128. September 1998.

USEAP, 1992. Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities,
Addendum to Interim Final Guidance. July 1992.

Woodward-Clyde Consultants, 1994. Transition Plan, Oxford Landfill Granville County, North
Carolina. April 1994.

7.0 ACRONYMS
ACM Assessment of Corrective Measures (report)
AOC Area of Concern
ASD Alternate Source Demonstration (report)
C&D Construction and Demolition Waste
CAP Corrective Action Plan (report)
CAER Corrective Action Evaluation Report (report)
CPVC Chlorinated Poly Vinyl Chloride
CO2 Carbon Dioxide
COC Contaminant of Concern
DCA Dichloroethane
DCE Dichloroethylene
DENR See NCDEQ
DEQ See NCDENR
DH Dissolved Hydrogen
DL Detection Limit (for laboratory data)
DO Dissolved Oxygen
EPA United States Environmental Protection Agency

Second Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 October 2016
15

Fe2+ Ferrous Iron
GEU Gas Extraction Unit
GPS Groundwater Protection Standards per NCSWMR rule .1634.g.5.
GWPS Groundwater Protection Standards set by the NCDEQ-SWS for constituents with
no NC-2L standard.
HASP Site-specific Health and Safety Plan
HDPE High-density Polyethylene
JE Joyce Engineering
JOYCE Joyce Engineering
LFG Landfill Gas
LEL Lower Explosive Limit
MNA Monitored Natural Attenuation
MSW Municipal Solid Waste
MW Monitoring Well
NC-2B North Carolina Surface Water Standards found in 15A NCAC 2B.0101
NC-2L North Carolina Groundwater Standards found in 15A NCAC 2L.0202
NCAC North Carolina Administrative Code
NCDENR North Carolina Department of Environment and Natural Resources
(now NCDEQ)
NCDEQ North Carolina Department of Environmental Quality
(formerly NCDENR)
NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 13B.1600)
ND Not Detected (for laboratory data)
NES Nature and Extent Study (report)
O&M Operations and Maintenance
ORP Oxidation-Reduction Potential
OSHA Occupational Health and Safety Association
PCE perchloroethylene (aka – tetrachloroethylene)
PVC Poly Vinyl Chloride
QL Quantitation Limit (for laboratory data)
QRA Quantitative Risk Assessment (report)
RL Reporting Limit (for laboratory data)
SC Specific Conductance
SSI Statistically Significant Increase (over background concentration)
SWQS Surface Water Quality Standards
SWS NCDEQ (or NCDENR) Division of Waste Management, Solid Waste Section
SWSL North Carolina Solid Waste Section Reporting Limits (for laboratory data)
TCE Trichloroethylene
TDS Total Dissolved Solids
TOC Total Organic Carbon
TSS Total Suspended Solids
VC Vinyl Chloride
VFA Volatile Fatty Acid
VOC Volatile Organic Compound

Second Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 October 2016
16

WQMP Water Quality Monitoring Plan (report)

TABLES

Table 1 Monitoring Well Construction Data
Table 2 Historical Groundwater Elevation Data
Table 3 Groundwater Gradients and Calculated Flow Rates
Table 4 Quantified Detections in Groundwater and Surface Water
Table 5 Exceedances of Groundwater and Surface Water Standards
Table 6 Field Parameters
Table 7 Biodegradation Screening Matrix

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Joyce Engineering
TABLE 2: Histroical Groundwater Elevation Data
Background
Well ID:MW-1 MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Well TOC Elev.:121.46 538.18 534.24 518.62 503.82 507.34 489.95 506.81 516.93 516.62 477.20 477.43
Well Total Depth:28.77 34.50 29.34 31.63 63.22 40.25 42.90 36.10 57.75 24.20 69.20
10-Sep-99 101.71 517.91 -507.76 481.40 493.62 467.65 496.53 ----
16-Nov-99 105.76 522.86 -506.32 483.55 494.83 468.75 498.24 ----
10-May-00 109.47 527.66 -507.89 487.20 499.63 470.65 500.59 ----
26-Oct-00 103.54 518.89 -504.12 480.86 495.21 467.39 496.95 ----
18-Apr-01 107.87 526.23 -508.01 486.62 498.50 470.79 500.21 ----
27-Oct-01 -514.65 -501.42 478.79 494.79 466.70 494.92 ----
10-Jun-02 -515.06 -502.91 480.10 495.19 467.06 496.26 ----
19-Nov-02 -518.61 -512.08 489.84 498.82 471.80 498.70 ----
27-Jun-03 -529.42 -508.76 488.69 500.79 471.72 501.38 ----
29-Dec-03 -528.91 -509.06 488.06 499.94 471.10 501.21 ----
29-Jun-04 -520.03 -505.24 481.10 497.84 467.72 499.21 ----
28-Dec-04 -526.73 -509.09 485.27 499.14 469.51 500.76 ----
29-Jun-05 -520.37 -504.64 481.10 497.60 467.63 499.15 ----
29-Dec-05 -519.54 -509.66 482.69 498.33 468.57 499.25 ----
27-Jun-06 -517.93 -507.85 481.85 497.64 468.00 498.63 ----
27-Dec-06 -523.00 -511.07 489.81 499.43 471.76 500.83 493.70 -469.82 -
12-Jul-07 -516.94 -502.49 479.84 497.17 467.18 497.59 ----
18-Dec-07 -510.35 -501.46 477.54 495.40 464.09 493.14 ----
7-Jul-08 -515.96 -501.99 479.52 497.04 466.79 496.71 ----
16-Dec-08 -532.53 -509.80 487.98 498.08 470.11 499.29 489.19 488.63 469.47 472.71
7-Jul-09 -518.28 -505.37 481.57 497.43 467.88 499.36 490.38 490.07 467.73 470.91
14-Dec-09 -533.10 -511.89 491.93 500.61 473.65 501.48 494.70 493.21 470.98 467.14
22-Jun-10 -518.45 -506.72 485.92 499.94 469.67 499.68 493.47 493.07 468.97 471.53
13-Dec-10 -509.41 -507.89 482.82 498.20 467.87 496.65 488.89 -468.03 -
20-Jun-11 -515.17 513.91 504.60 482.72 499.96 467.76 498.63 492.11 491.51 468.03 474.35
5-Dec-11 -513.35 507.92 507.44 484.94 498.29 468.45 497.17 488.15 487.45 468.25 464.93
13-Jun-12 -514.08 513.48 507.48 485.36 499.29 468.04 498.85 487.08 490.33 468.81 467.64
12-Dec-12 -511.34 506.86 503.10 481.55 497.24 466.90 494.83 486.84 486.26 467.26 461.41
29-Apr-13 -515.88 513.26 509.38 485.47 500.82 469.60 501.15 492.31 491.64 470.45 455.26
5-Aug-13 -517.21 514.33 505.98 484.47 500.29 468.65 500.83 494.12 -469.29 -
25-Feb-14 -514.06 511.75 509.82 486.32 501.50 473.05 501.99 491.83 491.54 470.28 461.18
12-Aug-14 -519.34 511.98 507.52 485.44 499.25 468.90 499.30 491.92 491.41 470.29 460.31
11-Mar-15 -524.32 516.39 510.37 487.12 502.94 474.18 504.41 500.98 500.12 470.63 473.63
18-Aug-15 -516.53 512.39 503.47 482.97 500.94 466.45 498.81 492.38 -469.25 449.71
16-Feb-16 -526.03 515.79 510.07 486.93 501.84 475.45 503.66 500.23 -471.15 469.18
10-Aug-16 -520.07 514.29 507.08 484.07 500.34 468.20 500.89 491.95 -470.40 453.23
Notes:
TOC = top of casing. - = data not available.
Water levels are measured from TOC.MW-7 added to monitoring network in early 2011.
All elevations are in feet above mean sea level (ft-amsl).Prior to December 2012, the TOC elevation for MW-3R was 498.35 ft-amsl.
Downgradient Performance/Sentinel
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Joyce Engineering
TABLE 3: Groundwater Gradients and Calculated Flow Rates
Date of Water Table Measurements:
SEGMENT HORIZ.HYDRAULIC EFFECTIVE LINEAR
FLOW BEGIN & END GRADIENT CONDUCTIVITY POROSITY VELOCITY
DIRECTION GW ELEVATION i K n e V
(feet-AMSL)(ft/ft) (ft/day)(ft/year)
505
490
505
470
Average 0.0196 Average 100.38
Notes:
Linear flow velocity: V = Ki/n e (modified Darcy equation).
Hydraulic conductivity (K ) is based on the arithmetic mean of values from slug tests conducted at the facility.
Effective porosity (n e ) value is estimated at 85% of the laboratory-determined porosity for soil samples from the facility.
Refer to Drawing 1 for flow line segments.
74.69
August-16
0.31 100.384.36E+000.0196
0.0145 4.36E+00 0.31
FLOW LINE
SEGMENT
SEGMENT
LENGTH
(feet)
i 2 1790 N
i 1 1031 N
Granville Co. - Oxford Landfill, Unit 1
Permit # 3901-CDLF-1997 Joyce Engineering
TABLE 4: Quantified Detections of Groundwater and Surface Water Constituents
NC2L/
GWPS*/NC2B**
3901-MW2 Chromium 11 µg/L 10 10 8/10/2016
3901-MW2 Cobalt 12.7 µg/L 10 1*8/10/2016
3901-MW2 Iron 10,400 µg/L 300 300 8/10/2016
3901-MW2 Manganese 336 µg/L 50 50 8/10/2016
3901-MW2 Vanadium 25.2 µg/L 25 0.3*8/10/2016
3901-MW2 Chloride 4,430 µg/L -250,000 8/10/2016
3901-MW2 Alkalinity, Total CaCO3 24,400 µg/L 1000 NE 8/10/2016
3901-MW2 Zinc 18.2 µg/L 10 1,000 8/10/2016
3901-MW3R Iron 839 µg/L 300 300 8/11/2016
3901-MW3R Manganese 122 µg/L 50 50 8/11/2016
3901-MW3R Alkalinity, Total CaCO3 91,800 µg/L 1000 NE 8/11/2016
3901-MW3R Chloride 23,200 µg/L -250,000 8/11/2016
3901-MW3R Total Dissolved Solids 171,000 µg/L -500,000 8/11/2016
3901-MW4R Manganese 1,550 µg/L 50 50 8/11/2016
3901-MW4R Alkalinity, Total CaCO3 304,000 µg/L 1000 NE 8/11/2016
3901-MW4R Chloride 57,300 µg/L -250,000 8/11/2016
3901-MW4R Total Dissolved Solids 437,000 µg/L -500,000 8/11/2016
3901-MW5R Manganese 100 µg/L 50 50 8/11/2016
3901-MW5R Vinyl Chloride 5.6 µg/L 1 0.03 8/11/2016
3901-MW5R Alkalinity, Total CaCO3 176,000 µg/L 1000 NE 8/11/2016
3901-MW5R Chloride 51,300 µg/L -250,000 8/11/2016
3901-MW5R Total Dissolved Solids 301,000 µg/L -500,000 8/11/2016
COLLECT DATEWELL ID PARAMETER RESULT UNITS SWSL
Oxford Unit 1, Granville Co.
Permit No. 39-01
Joyce Engineering
TABLE 4: Quantified Detections of Groundwater and Surface Water Constituents
NC2L/
GWPS*/NC2B**COLLECT DATEWELL ID PARAMETER RESULT UNITS SWSL
3901-MW6R Barium 102 µg/L 100 700 8/11/2016
3901-MW6R Iron 2,090 µg/L 300 300 8/11/2016
3901-MW6R Manganese 1,770 µg/L 50 50 8/11/2016
3901-MW6R Alkalinity, Total CaCO3 173,000 µg/L 1000 NE 8/11/2016
3901-MW6R Chloride 147,000 µg/L -250,000 8/11/2016
3901-MW6R Total Dissolved Solids 516,000 µg/L -500,000 8/11/2016
3901-MW7 Alkalinity, Total CaCO3 108,000 µg/L 1000 NE 8/11/2016
3901-MW7 Chloride 9,410 µg/L -250,000 8/11/2016
3901-MW7 Total Dissolved Solids 213,000 µg/L -500,000 8/11/2016
3901-SW1 Barium 175 µg/L 100 200,000**8/11/2016
3901-SW1 Beryllium 1.9 µg/L 1 6.5**8/11/2016
3901-SW1 Chromium 63.0 µg/L 10 24**8/11/2016
Oxford Unit 1, Granville Co.
Permit No. 39-01
Joyce Engineering
TABLE 4: Quantified Detections of Groundwater and Surface Water Constituents
NC2L/
GWPS*/NC2B**COLLECT DATEWELL ID PARAMETER RESULT UNITS SWSL
3901-SW1#Chromium 13.8 (ND)µg/L 10 24**9/13/2016
3901-SW1 Cobalt 16.7 µg/L 10 NE 8/11/2016
3901-SW1 Copper 39.9 µg/L 10 2.7**8/11/2016
3901-SW1#Copper 9.3 J (2.5 J)µg/L 10 2.7**9/13/2016
3901-SW1 Lead 16.6 µg/L 10 0.54**8/11/2016
3901-SW1#Lead 4.1 J (2.6 J)µg/L 10 14**9/13/2016
3901-SW1 Vanadium 160 µg/L 25 NE 8/11/2016
3901-SW1 Zinc 66.4 µg/L 10 36**8/11/2016
3901-SW1#Zinc 14.5 B (5.9 J)µg/L 10 36**9/13/2016
3901-SW2 Barium 152 µg/L 100 200,000**8/11/2016
3901-SW2 Beryllium 1.7 µg/L 1 6.5**8/11/2016
3901-SW2 Chromium 55.1 µg/L 10 24**8/11/2016
3901-SW2 Cobalt 12.7 µg/L 10 NE 8/11/2016
3901-SW2 Copper 34.5 µg/L 10 2.7**8/11/2016
3901-SW2 Lead 13.6 µg/L 10 0.54**8/11/2016
3901-SW2 Vanadium 144 µg/L 25 NE 8/11/2016
3901-SW2 Zinc 54.1 µg/L 10 36**8/11/2016
NOTES:All Results in micorgrams per liter (µg/L)
MDL = Method Detection Limit
SWSL = NC Soild Waste Section Reporting Limit
NC2L = NC Groundwater Standard from 15A NCAC 2L.0202
NC2B = NC Surface Water standards for fresh-water aquatic life from 15A-NCAC-2B
GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L)
NE= Not Established
J = Estimated concentration below the MRL or SWSL
Bold values= Detections above the NC2L, GWPS, or NC2B stardards (see Table 5)
# 9/13/16 RESAMPLE= Parenthesis indicate Dissolved concentrations.
Oxford Unit 1, Granville Co.
Permit No. 39-01
Joyce Engineering
TABLE 5: Exceedances of Groundwater and Surface Water Standards
WELL ID PARAMETER RESULT UNITS SWSL NC2L/*GWPS COLLECT DATE
3901-MW2 Chromium 11.0 µg/L 10 10 8/10/2016
3901-MW2 Cobalt 12.7 µg/L 10 1*8/10/2016
3901-MW2 Iron 10,400 µg/L 300 300 8/10/2016
3901-MW2 Manganese 336 µg/L 50 50 8/10/2016
3901-MW2 Vanadium 25.2 µg/L 25 0.3*8/10/2016
3901-MW3R Iron 839 µg/L 300 300 8/11/2016
3901-MW3R Manganese 122 µg/L 50 50 8/11/2016
3901-MW4R Manganese 1,550 µg/L 50 50 8/11/2016
3901-MW5R Manganese 100.0 µg/L 50 50 8/11/2016
3901-MW5R Vinyl Chloride 5.6 µg/L 1 0.03 8/11/2016
3901-MW6R Iron 2,090 µg/L 300 300 8/11/2016
3901-MW6R Manganese 1,770 µg/L 50 50 8/11/2016
3901-MW6R Total Dissolved Solids 516,000 µg/L -500,000 8/11/2016
3901-SW1 Chromium 63.0 µg/L 10 24**8/11/2016
3901-SW1#Chromium 13.8 (ND)µg/L 10 24**9/13/2016
3901-SW1 Copper 39.9 µg/L 10 2.7**8/11/2016
3901-SW1#Copper 9.3 J (2.5 J)µg/L 10 2.7**9/13/2016
3901-SW1 Lead 16.6 µg/L 10 14**8/11/2016
3901-SW1#Lead 4.1 J (2.6 J)µg/L 10 14**9/13/2016
3901-SW1 Zinc 66.4 µg/L 10 36**8/11/2016
3901-SW1#Zinc 14.5 B (5.9 J)µg/L 10 36**9/13/2016
3901-SW2 Chromium 55.1 µg/L 10 24**8/11/2016
3901-SW2 Copper 34.5 µg/L 10 2.7**8/11/2016
3901-SW2 Zinc 54.1 µg/L 10 36**8/11/2016
NOTES:All Results in micorgrams per liter (µg/L)
SWSL = NC Soild Waste Section Reporting Limit
NC2L = NC Groundwater Standard from 15A NCAC 2L.0202
GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L)
GPS = Groundwater Protection Standard as defined by 15A NCAC 13B.1634(g)
GPS for antimony and cobalt are based on the statistical backgound for the facility.
Bold = GPS Exceedance.
# 9/13/16 RESAMPLE- Parenthesis indicate Dissolved concentrations.
Oxford Unit 1 Landfill, Granville Co.
Permit No. 39-01
Joyce Engineering
TABLE 6: Field Parameters
WELL ID PARAMETER RESULT UNITS DATE
3901-MW2 Conductivity 79.9 µS/cm 8/10/2016
3901-MW2 pH 6.17 S.U.8/10/2016
3901-MW2 Static Water Level 11.54 ft 8/10/2016
3901-MW2 Temperature 15.8 ºC 8/10/2016
3901-MW2 Turbidity 21.3 NTU 8/10/2016
3901-MW2 Well Depth 29.34 ft 8/10/2016
3901-MW3R Conductivity 232.0 µS/cm 8/11/2016
3901-MW3R pH 4.83 S.U.8/11/2016
3901-MW3R Static Water Level 19.75 ft 8/11/2016
3901-MW3R Temperature 17.3 ºC 8/11/2016
3901-MW3R Turbidity 11.13 NTU 8/11/2016
3901-MW3R Well Depth 31.63 ft 8/11/2016
3901-MW4R Conductivity 670.0 µS/cm 8/11/2016
3901-MW4R pH 4.67 S.U.8/11/2016
3901-MW4R Static Water Level 7.00 ft 8/11/2016
3901-MW4R Temperature 18.9 ºC 8/11/2016
3901-MW4R Turbidity 6.89 NTU 8/11/2016
3901-MW4R Well Depth 63.22 ft 8/11/2016
3901-MW5R Conductivity 434.4 µS/cm 8/11/2016
3901-MW5R Dissolved Oxygen 1.45 mg/l 8/11/2016
3901-MW5R Oxidation Reduction Potential 57.4 mV 8/11/2016
3901-MW5R pH 4.66 S.U.8/11/2016
3901-MW5R Static Water Level 21.75 ft 8/11/2016
3901-MW5R Temperature 18.8 ºC 8/11/2016
3901-MW5R Turbidity 6.63 NTU 8/11/2016
3901-MW5R Well Depth 40.25 ft 8/11/2016
3901-MW6R Conductivity 704 µS/cm 8/11/2016
3901-MW6R pH 4.84 S.U.8/11/2016
3901-MW6R Static Water Level 5.92 ft 8/11/2016
3901-MW6R Temperature 18.4 ºC 8/11/2016
3901-MW6R Turbidity 7.41 NTU 8/11/2016
3901-MW6R Well Depth 42.90 ft 8/11/2016
3901-MW7 Conductivity 287.1 µS/cm 8/11/2016
3901-MW7 Dissolved Oxygen 3.60 mg/l 8/11/2016
3901-MW7 Oxidation Reduction Potential 58.8 mV 8/11/2016
3901-MW7 pH 4.55 S.U.8/11/2016
3901-MW7 Static Water Level 19.95 ft 8/11/2016
3901-MW7 Temperature 16.7 ºC 8/11/2016
3901-MW7 Turbidity 7.95 NTU 8/11/2016
3901-MW7 Well Depth 37.32 ft 8/11/2016
Oxford Unit 1 Landfill, Granville Co.
Permit No. 39-01 1 of 2
Joyce Engineering
TABLE 6: Field Parameters
WELL ID PARAMETER RESULT UNITS DATE
3901-NES2S Conductivity 123.7 µS/cm 8/11/2016
3901-NES2S Dissolved Oxygen 1.74 mg/l 8/11/2016
3901-NES2S Oxidation Reduction Potential 61.9 mV 8/11/2016
3901-NES2S pH 4.58 S.U.8/11/2016
3901-NES2S Static Water Level 6.8 ft 8/11/2016
3901-NES2S Temperature 18.3 ºC 8/11/2016
3901-NES2S Turbidity 16.41 NTU 8/11/2016
3901-NES2S Well Depth 24.20 ft 8/11/2016
3901-SW1 Conductivity 71.6 µS/cm 8/11/2016
3901-SW1 pH 6.09 S.U.8/11/2016
3901-SW1 Temperature 27.1 ºC 8/11/2016
3901-SW1 Turbidity 750 NTU 8/11/2016
3901-SW2 Conductivity 109 µS/cm 8/11/2016
3901-SW2 pH 5.33 S.U.8/11/2016
3901-SW2 Temperature 24.4 ºC 8/11/2016
3901-SW2 Turbidity 621 NTU 8/11/2016
3901-SW1**Conductivity 163.1 µS/cm 9/13/2016
3901-SW1**pH 7.82 S.U.9/13/2016
3901-SW1**Temperature 27 ºC 9/13/2016
3901-SW1**Turbidity 172.9 NTU 9/13/2016
Notes:ºC= degrees Centigrade µS/cm = microSemens per centimeter
S.U.= Standard Units NTU = Nephelometric Turbidity Units
ft = feet
**=Resample 9/13/2016
Oxford Unit 1 Landfill, Granville Co.
Permit No. 39-01 2 of 2
Joyce Engineering
TABLE 7:
STATISTICAL BACKGROUND RESULTS
Analyte Data Distribution Statistical Method used to Establish Background Background
(µg/L)
SWSL
(µg/L)
NC2L or
*GWPS
(µg/L)
GPS
(µg/L)
Sampling
Result
(Max.)
(µg/L)
GPS
Exceedances
Chromium 51.7%ND Non-parametric Prediction Limit: Interwell 1,000 10 10 1,000 11.0 None
Cobalt 58.6%ND Non-parametric Prediction Limit: Interwell 430 10 1*430 12.7 None
Vanadium 58.6%ND Non-parametric Prediction Limit: Interwell 1,600 25 0.3*1,600 25.2 None
TDS 0%ND, Normal Upper Prediction Limit (UPL): Intrawell (MW-6R)528,672 25,000 500,000 528,672 516,000 None
Notes:
SWSL = NC Solid Waste Section Limits
NC 2L = NC Groundwater Standards (15A NCAC 2L.0202)
GWPS = Solid Waste Section Groundwater Protection Standards for Constituents with no NC 2L (indicated by *)
%ND = percentage of data that were non-detect (i.e., truncated).
GPS = Groundwater Protection Standard per 15A NCAC .1634(g) - Assuming NCDEQ approval of using background as the GPS.
Granville Co. - Oxford Landfill, Unit 1
Permit No. 3901-CDLF-1997 Joyce Engineering
TABLE 8: BIODEGRADATION SCREENING MATRIX (MW-5R)
Parameter Concentration Interpretation Possible Points Awarded Points Awarded
in Plume Points with DP points without DP points
Oxygen < 0.5 mg/L Tolerated, suppresses the reductive pathway at higher 3 0 0
concentrations
> 5 mg/L Not tolerated; however, vinyl chloride may be oxidized -3 0 0
aerobically
Nitrate < 1 mg/L At higher concentrations may compete with reductive 2 0 0
pathway
Iron II (Ferrous Iron)> 1 mg/L Reductive pathway possible; vinyl chloride may be 3 0 0
oxidized under Fe (III) - reducing conditions
Sulfate < 20 mg/L At higher concentrations may compete with reductive 2 2 2
pathway
Sulfide > 1 mg/L Reductive pathway possible 3 0 0
Methane < 0.5 mg/L Vinyl chloride oxidizes 0 0 0
> 0.5 mg/L Ultimate reductive daughter product, vinyl chloride 3 0 0
accumulates
Oxidation Reduction < 50 mV Reductive pathway possible 1 1 1
Potential < -100 mV Reductive pathway likely 2 0 0
pH 5 < pH < 9 Optimal range for reductive pathway 0 0 0
5 > pH > 9 Outside optimal range for reductive pathway -2 -2 -2
TOC > 20 mg/L Carbon and energy source; drives dechlorination; can 2 2 2
be natural or anthropogenic
Temperature >20o C At T > 20oC biochemical process is accelerated 1 0 0
Carbon Dioxide > 2x background Ultimate oxidative daughter product 1 0 0
Alkalinity > 2x background Results from interaction between CO2 and 1 0 0
aquifer minerals
Chloride > 2x background Daughter product of organic chlorine 2 2 2
Hydrogen > 1 nM Reductive pathway possible 3 3 3
< 1 nM Vinyl chloride oxidizes 0 0 0
Volatile Fatty Acids > 0.1 mg/L Intermediates resulting from biodegradation of more 2 0 0
complex compounds; carbon and energy source
BTEX > 0.1 mg/L Carbon and energy source; drives dechlorination 2 0 0
Tetrachloroethene (PCE)---Material released 0 0 0
Trichloroethene (TCE)---Material released 0 0 0
---Daughter product of PCE 2 0 0
Dichloroethenes (DCE)---Material released 0 0
Daughter product of TCE 2 2
Dichloroethene, cis-1,2,---Material released 0 0
---Daughter product of trichlorethene 2 2
Vinyl Chloride (VC)---Material released 0 0
---Daughter product of DCE 2 2
1,1,1-Trichloroethane (TCA)---Material released 0 0 0
1,1-Dichloroethane (DCA)---Material released 0 0
Daughter product of TCA 2 2
Chloroethane ---Daughter product of dichloroethane or vinyl chloride
under reducing conditions 2 0 0
Ethene/Ethane > 0.01 mg/L Daughter products of vinyl chloride/ethene 2
> 0.1 mg/L 3 0 0
Chloroform ---Material released 0 0 0
---Daughter product of carbon tetrachloride 2 0 0
Dichloromethane (MC)---Material released 0 0 0
(Methylene Chloride)---Daughter product of chloroform 2 0 0
Based on data collected in August 2014.Total Points Awarded:16 8
mg/L = miligrams per liter
mV = millivolts NOTE: Chloroethane, Methane, TCE, DCE, cis-1,2-DCE, MC, VC, DCA, and CO2 are all present in the plume; however,
nM = Nanometer it is uncertain whether these are primary leachate constituents or daughter products (DPs); therefore, we
C = Celcius have two calculation columns. The first column assumes all of these are daughter products, and the
NA = Not Analyzed second column assumes none of them are. The true score is probably between the two.
BTEX = Sum of Benzene, Toluene, Ethylbenzene, and Total Xylenes
SCORE:Evid. of Nat. Atten.
This screening matrix is prepared in general accordance with the United Stated Environmental Protection Agency's < 5 inadequate
(EPA's) Table 2.3 Analytical Parameters and Weighted for Preliminary Screening for Anaerobic Biodegradation 6-14 limited
Process presented in the EPA's Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents 15-19 adequate
in Groundwater, September 1988.> 20 strong
Granville County - Oxford Landfill Permit 3901-CDLF-1997 Joyce Engineering

CHARTS
(Reference Section 4.2)

Chart 1 Vinyl Chloride in MW-5 & MW-5R vs. Time
Chart 2 1,1-Dichloroethane in MW-5 & MW-5R vs. Time

Granville Co., Oxford Landfill, Unit 1
Permit # 3901-CDLF-1997 Joyce Engineering
0.00
5.00
10.00
15.00
20.00
25.00
30.00
35.00
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(
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CHART 1: Vinyl Chloride vs. Time in MW-5 & MW-5R
MW-5
MW-5R
Linear (MW-5R)
NC 2L Standard for Vinyl Chloride:
Prior to February 2010 = 0.015 µg/L;
Feb. 2010 to Present = 0.03 µg/L.
Granville Co., Oxford Landfill, Unit 1
Permit # 3901-CDLF-1997 Joyce Engineering
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CHART 2: 1,1-Dichloroethane vs. Time in MW-5 & MW-5R
MW-5
MW-5R
Linear (MW-5R)
NC 2L Standard for 1,1-Dichloroethane:
Prior to February 2010 = 70 µg/L;
Feb. 2010 to Present = 6 µg/L.

FIGURE

Figure 1 Site Location Map (USGS Topographic Map)

DRAWING

Drawing 1 Groundwater Potentiometric Surface Map

APPENDICES

Appendix A Field Sampling Logs
Appendix B Laboratory Reports with Chains of Custody
Appendix C Historical Detected Inorganic Constituents in Compliance Wells
Appendix D Historical Detected Organic Constituents in Compliance Wells
Appendix E Historical Detected COCs in Performance and Sentinel Wells
Appendix F Historical Detected Constituents in Surface Water
Appendix G Historical MNA Parameter Data

Appendix A

Field Sampling Logs

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Appendix B

Laboratory Reports with Chains of Custody

#=CL#
August 25, 2016
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92308661
92308661
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
OXFORD COMPLIANCE UNIT 1
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on August 12, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc:Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 52
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 52
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Lab ID Sample ID Matrix Date Collected Date Received
92308661001 3901-MW7 Water 08/11/16 08:25 08/12/16 10:20
92308661002 3901-MW5R Water 08/11/16 09:00 08/12/16 10:20
92308661003 3901-MW2 Water 08/10/16 13:37 08/12/16 10:20
92308661004 3901-MW3R Water 08/11/16 07:45 08/12/16 10:20
92308661005 3901-MW4R Water 08/11/16 09:30 08/12/16 10:20
92308661006 3901-MW6R Water 08/11/16 09:42 08/12/16 10:20
92308661007 3901-SW1 Water 08/11/16 10:10 08/12/16 10:20
92308661008 3901-SW2 Water 08/11/16 09:45 08/12/16 10:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 52
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92308661001 3901-MW7 EPA 8081 4 PASI-CSWB
EPA 6010 17 PASI-AJMW, SH1
EPA 7470 1 PASI-ASER
EPA 8260 51 PASI-CGAW
SM 2320B 1 PASI-AKDF
SM 2540C 1 PASI-AMJP
SM 4500-S2D 1 PASI-AWRC
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-ABRJ
92308661002 3901-MW5R EPA 8081 4 PASI-CSWB
EPA 6010 17 PASI-AJMW, SH1
EPA 7470 1 PASI-ASER
EPA 8260 51 PASI-CGAW
SM 2320B 1 PASI-AKDF
SM 2540C 1 PASI-AMJP
SM 4500-S2D 1 PASI-AWRC
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-ABRJ
92308661003 3901-MW2 EPA 6010 17 PASI-AJMW, SH1
EPA 7470 1 PASI-ASER
EPA 8260 51 PASI-CGAW
SM 2320B 1 PASI-AKDF
SM 2540C 1 PASI-AMJP
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-ABRJ
92308661004 3901-MW3R EPA 6010 17 PASI-AJMW, SH1
EPA 7470 1 PASI-ASER
EPA 8260 51 PASI-CGAW
SM 2320B 1 PASI-AKDF
SM 2540C 1 PASI-AMJP
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-ABRJ
92308661005 3901-MW4R EPA 6010 17 PASI-AJMW, SH1
EPA 7470 1 PASI-ASER
EPA 8260 51 PASI-CGAW
SM 2320B 1 PASI-AKDF
SM 2540C 1 PASI-AMJP
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 52
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-ABRJ
92308661006 3901-MW6R EPA 6010 17 PASI-AJMW, SH1
EPA 7470 1 PASI-ASER
EPA 8260 51 PASI-CGAW
SM 2320B 1 PASI-AKDF
SM 2540C 1 PASI-AMJP
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-ABRJ
92308661007 3901-SW1 EPA 6010 15 PASI-AJMW, SH1
EPA 8260 50 PASI-CGAW
92308661008 3901-SW2 EPA 6010 15 PASI-AJMW, SH1
EPA 8260 50 PASI-CGAW
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 52
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92308661001 3901-MW7
Barium 3.9J ug/L 08/18/16 04:13100EPA 6010
Chromium 3.4J ug/L 08/18/16 04:1310.0EPA 6010
Iron 292J ug/L 08/18/16 04:13300EPA 6010
Manganese 5.9J ug/L 08/18/16 04:1350.0EPA 6010
Alkalinity, Total as CaCO3 108000 ug/L 08/17/16 13:075000SM 2320B
Total Dissolved Solids 213000 ug/L 08/18/16 10:5325000SM 2540C
Sulfate 112000J ug/L 08/18/16 14:271250000EPA 300.0
Chloride 9410 ug/L 08/17/16 00:131000SM 4500-Cl-E
92308661002 3901-MW5R
Barium 38.6J ug/L 08/18/16 04:22100EPA 6010
Manganese 100 ug/L 08/18/16 04:2250.0EPA 6010
Benzene 0.34J ug/L 08/14/16 18:331.0EPA 8260
Chlorobenzene 0.96J ug/L 08/14/16 18:333.0EPA 8260
Chloromethane 0.12J ug/L 08/14/16 18:331.0EPA 8260
1,2-Dichlorobenzene 1.2J ug/L 08/14/16 18:335.0EPA 8260
1,4-Dichlorobenzene 0.93J ug/L 08/14/16 18:331.0EPA 8260
1,1-Dichloroethane 3.4J ug/L 08/14/16 18:335.0EPA 8260
cis-1,2-Dichloroethene 2.7J ug/L 08/14/16 18:335.0EPA 8260
Vinyl chloride 5.6 ug/L 08/14/16 18:331.0EPA 8260
Alkalinity, Total as CaCO3 176000 ug/L 08/17/16 13:455000SM 2320B
Total Dissolved Solids 301000 ug/L 08/18/16 10:5325000SM 2540C
Sulfate 3100J ug/L 08/18/16 12:09250000EPA 300.0
Chloride 51300 ug/L 08/17/16 01:2010000SM 4500-Cl-E
92308661003 3901-MW2
Arsenic 3.5J ug/L 08/18/16 04:3410.0EPA 6010
Barium 22.4J ug/L 08/18/16 04:34100EPA 6010
Chromium 11.0 ug/L 08/18/16 04:3410.0EPA 6010
Cobalt 12.7 ug/L 08/18/16 04:3410.0EPA 6010
Copper 7.8J ug/L 08/18/16 04:3410.0EPA 6010
Iron 10400 ug/L 08/18/16 04:34300EPA 6010
Lead 2.7J ug/L 08/18/16 04:3410.0EPA 6010
Manganese 336 ug/L 08/18/16 04:3450.0EPA 6010
Nickel 6.4J ug/L 08/18/16 04:3450.0EPA 6010
Vanadium 25.2 ug/L 08/18/16 04:3425.0EPA 6010
Zinc 18.2 ug/L 08/18/16 04:3410.0EPA 6010
Mercury 0.11J ug/L 08/18/16 14:290.20EPA 7470
Alkalinity, Total as CaCO3 24400 ug/L 08/17/16 13:595000SM 2320B
Total Dissolved Solids 122000 ug/L 08/18/16 12:05 D6,H125000SM 2540C
Sulfate 8500J ug/L 08/18/16 12:20250000EPA 300.0
Chloride 4430 ug/L 08/17/16 00:151000SM 4500-Cl-E
92308661004 3901-MW3R
Barium 16.1J ug/L 08/18/16 04:37100EPA 6010
Chromium 3.1J ug/L 08/18/16 04:3710.0EPA 6010
Iron 839 ug/L 08/18/16 04:37300EPA 6010
Manganese 122 ug/L 08/18/16 04:3750.0EPA 6010
Nickel 6.7J ug/L 08/18/16 04:3750.0EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 52
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92308661004 3901-MW3R
Zinc 8.6J ug/L 08/18/16 04:3710.0EPA 6010
Alkalinity, Total as CaCO3 91800 ug/L 08/17/16 14:105000SM 2320B
Total Dissolved Solids 171000 ug/L 08/18/16 10:5325000SM 2540C
Sulfate 7700J ug/L 08/18/16 12:52250000EPA 300.0
Chloride 23200 ug/L 08/17/16 00:161000SM 4500-Cl-E
92308661005 3901-MW4R
Arsenic 3.2J ug/L 08/18/16 04:4010.0EPA 6010
Barium 42.1J ug/L 08/18/16 04:40100EPA 6010
Chromium 2.7J ug/L 08/18/16 04:4010.0EPA 6010
Iron 104J ug/L 08/18/16 04:40300EPA 6010
Manganese 1550 ug/L 08/18/16 04:4050.0EPA 6010
Alkalinity, Total as CaCO3 304000 ug/L 08/17/16 14:235000SM 2320B
Total Dissolved Solids 437000 ug/L 08/18/16 10:5425000SM 2540C
Sulfate 10300J ug/L 08/18/16 13:02250000EPA 300.0
Chloride 57300 ug/L 08/17/16 00:175000SM 4500-Cl-E
92308661006 3901-MW6R
Arsenic 3.7J ug/L 08/18/16 04:4310.0EPA 6010
Barium 102 ug/L 08/18/16 04:43100EPA 6010
Iron 2090 ug/L 08/18/16 04:43300EPA 6010
Manganese 1770 ug/L 08/18/16 04:4350.0EPA 6010
1,1-Dichloroethane 0.77J ug/L 08/14/16 19:255.0EPA 8260
cis-1,2-Dichloroethene 0.50J ug/L 08/14/16 19:255.0EPA 8260
Alkalinity, Total as CaCO3 173000 ug/L 08/17/16 14:385000SM 2320B
Total Dissolved Solids 516000 ug/L 08/18/16 10:5425000SM 2540C
Sulfate 3140J ug/L 08/18/16 13:13250000EPA 300.0
Chloride 147000 ug/L 08/17/16 00:185000SM 4500-Cl-E
92308661007 3901-SW1
Arsenic 6.8J ug/L 08/18/16 04:4610.0EPA 6010
Barium 175 ug/L 08/18/16 04:46100EPA 6010
Beryllium 1.9 ug/L 08/18/16 04:461.0EPA 6010
Chromium 63.0 ug/L 08/18/16 04:4610.0EPA 6010
Cobalt 16.7 ug/L 08/18/16 04:4610.0EPA 6010
Copper 39.9 ug/L 08/18/16 04:4610.0EPA 6010
Lead 16.6 ug/L 08/18/16 04:4610.0EPA 6010
Nickel 22.8J ug/L 08/18/16 04:4650.0EPA 6010
Vanadium 160 ug/L 08/18/16 04:4625.0EPA 6010
Zinc 66.4 ug/L 08/18/16 04:4610.0EPA 6010
2-Hexanone 1.2J ug/L 08/14/16 19:5950.0EPA 8260
92308661008 3901-SW2
Arsenic 7.3J ug/L 08/18/16 04:4910.0EPA 6010
Barium 152 ug/L 08/18/16 04:49100EPA 6010
Beryllium 1.7 ug/L 08/18/16 04:491.0EPA 6010
Chromium 55.1 ug/L 08/18/16 04:4910.0EPA 6010
Cobalt 12.7 ug/L 08/18/16 04:4910.0EPA 6010
Copper 34.5 ug/L 08/18/16 04:4910.0EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 52
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92308661008 3901-SW2
Lead 13.6 ug/L 08/18/16 04:4910.0EPA 6010
Nickel 19.4J ug/L 08/18/16 04:4950.0EPA 6010
Selenium 6.0J ug/L 08/18/16 04:4910.0EPA 6010
Vanadium 144 ug/L 08/18/16 04:4925.0EPA 6010
Zinc 54.1 ug/L 08/18/16 04:4910.0EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Sample:3901-MW7 Lab ID:92308661001 Collected:08/11/16 08:25 Received:08/12/16 10:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
beta-BHC ND ug/L 08/16/16 23:44 319-85-708/15/16 15:390.050 0.050 1
Endosulfan I ND ug/L 08/16/16 23:44 959-98-808/15/16 15:390.10 0.050 1
Surrogates
Tetrachloro-m-xylene (S)75 %08/16/16 23:44 877-09-808/15/16 15:3920-130 1
Decachlorobiphenyl (S)49 %08/16/16 23:44 2051-24-308/15/16 15:3920-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 08/18/16 04:13 7440-36-008/15/16 21:106.0 3.8 1
Arsenic ND ug/L 08/18/16 04:13 7440-38-208/15/16 21:1010.0 2.5 1
Barium 3.9J ug/L 08/18/16 04:13 7440-39-308/15/16 21:101002.5 1
Beryllium ND ug/L 08/18/16 04:13 7440-41-708/15/16 21:101.0 0.50 1
Cadmium ND ug/L 08/18/16 04:13 7440-43-908/15/16 21:101.0 0.50 1
Chromium 3.4J ug/L 08/18/16 04:13 7440-47-308/15/16 21:1010.0 2.5 1
Cobalt ND ug/L 08/18/16 04:13 7440-48-408/15/16 21:1010.0 2.5 1
Copper ND ug/L 08/18/16 04:13 7440-50-808/15/16 21:1010.0 2.5 1
Iron 292J ug/L 08/18/16 04:13 7439-89-608/15/16 21:1030025.0 1
Lead ND ug/L 08/18/16 04:13 7439-92-108/15/16 21:1010.0 2.5 1
Manganese 5.9J ug/L 08/18/16 04:13 7439-96-508/15/16 21:1050.0 2.5 1
Nickel ND ug/L 08/18/16 04:13 7440-02-008/15/16 21:1050.0 2.5 1
Selenium ND ug/L 08/18/16 04:13 7782-49-208/15/16 21:1010.0 5.0 1
Silver ND ug/L 08/18/16 04:13 7440-22-408/15/16 21:1010.0 2.5 1
Thallium ND ug/L 08/18/16 17:20 7440-28-008/15/16 21:105.5 5.0 1
Vanadium ND ug/L 08/18/16 04:13 7440-62-208/15/16 21:1025.0 2.5 1
Zinc ND ug/L 08/18/16 04:13 7440-66-608/15/16 21:1010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 08/18/16 14:19 7439-97-608/15/16 17:100.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 08/15/16 02:30 67-64-110010.0 1
Acrylonitrile ND ug/L 08/15/16 02:30 107-13-12001.9 1
Benzene ND ug/L 08/15/16 02:30 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 08/15/16 02:30 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 08/15/16 02:30 75-27-41.0 0.18 1
Bromoform ND ug/L 08/15/16 02:30 75-25-23.0 0.26 1
Bromomethane ND ug/L 08/15/16 02:30 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 08/15/16 02:30 78-93-31000.96 1
Carbon disulfide ND ug/L 08/15/16 02:30 75-15-01001.2 1
Carbon tetrachloride ND ug/L 08/15/16 02:30 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 08/15/16 02:30 108-90-73.0 0.23 1
Chloroethane ND ug/L 08/15/16 02:30 75-00-310.0 0.54 1
Chloroform ND ug/L 08/15/16 02:30 67-66-35.0 0.14 1
Chloromethane ND ug/L 08/15/16 02:30 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 08/15/16 02:30 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 08/15/16 02:30 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 08/15/16 02:30 106-93-41.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 9 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Sample:3901-MW7 Lab ID:92308661001 Collected:08/11/16 08:25 Received:08/12/16 10:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Dibromomethane ND ug/L 08/15/16 02:30 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 08/15/16 02:30 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 08/15/16 02:30 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 08/15/16 02:30 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 08/15/16 02:30 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 08/15/16 02:30 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 08/15/16 02:30 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 08/15/16 02:30 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 08/15/16 02:30 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 08/15/16 02:30 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 08/15/16 02:30 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 08/15/16 02:30 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 08/15/16 02:30 100-41-41.0 0.30 1
2-Hexanone ND ug/L 08/15/16 02:30 591-78-650.0 0.46 1
Iodomethane ND ug/L 08/15/16 02:30 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 08/15/16 02:30 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 08/15/16 02:30 108-10-11000.33 1
Styrene ND ug/L 08/15/16 02:30 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 08/15/16 02:30 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 08/15/16 02:30 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 08/15/16 02:30 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 08/15/16 02:30 109-99-910.0 3.1 1
Toluene ND ug/L 08/15/16 02:30 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 08/15/16 02:30 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 08/15/16 02:30 79-00-51.0 0.29 1
Trichloroethene ND ug/L 08/15/16 02:30 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 08/15/16 02:30 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 08/15/16 02:30 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 08/15/16 02:30 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 08/15/16 02:30 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 08/15/16 02:30 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %08/15/16 02:30 460-00-470-130 1
1,2-Dichloroethane-d4 (S)93 %08/15/16 02:30 17060-07-070-130 1
Toluene-d8 (S)102 %08/15/16 02:30 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 108000 ug/L 08/17/16 13:07500010001
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 213000 ug/L 08/18/16 10:5325000250001
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 08/17/16 21:40 18496-25-810001001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Sample:3901-MW7 Lab ID:92308661001 Collected:08/11/16 08:25 Received:08/12/16 10:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 112000J ug/L 08/18/16 14:27 14808-79-8125000050005
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 9410 ug/L 08/17/16 00:13 16887-00-610005001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Sample:3901-MW5R Lab ID:92308661002 Collected:08/11/16 09:00 Received:08/12/16 10:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
beta-BHC ND ug/L 08/17/16 00:01 319-85-708/15/16 15:390.050 0.050 1
Endosulfan I ND ug/L 08/17/16 00:01 959-98-808/15/16 15:390.10 0.050 1
Surrogates
Tetrachloro-m-xylene (S)97 %08/17/16 00:01 877-09-808/15/16 15:3920-130 1
Decachlorobiphenyl (S)68 %08/17/16 00:01 2051-24-308/15/16 15:3920-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 08/18/16 04:22 7440-36-008/15/16 21:106.0 3.8 1
Arsenic ND ug/L 08/18/16 04:22 7440-38-208/15/16 21:1010.0 2.5 1
Barium 38.6J ug/L 08/18/16 04:22 7440-39-308/15/16 21:101002.5 1
Beryllium ND ug/L 08/18/16 04:22 7440-41-708/15/16 21:101.0 0.50 1
Cadmium ND ug/L 08/18/16 04:22 7440-43-908/15/16 21:101.0 0.50 1
Chromium ND ug/L 08/18/16 04:22 7440-47-308/15/16 21:1010.0 2.5 1
Cobalt ND ug/L 08/18/16 04:22 7440-48-408/15/16 21:1010.0 2.5 1
Copper ND ug/L 08/18/16 04:22 7440-50-808/15/16 21:1010.0 2.5 1
Iron ND ug/L 08/18/16 04:22 7439-89-608/15/16 21:1030025.0 1
Lead ND ug/L 08/18/16 04:22 7439-92-108/15/16 21:1010.0 2.5 1
Manganese 100 ug/L 08/18/16 04:22 7439-96-508/15/16 21:1050.0 2.5 1
Nickel ND ug/L 08/18/16 04:22 7440-02-008/15/16 21:1050.0 2.5 1
Selenium ND ug/L 08/18/16 04:22 7782-49-208/15/16 21:1010.0 5.0 1
Silver ND ug/L 08/18/16 04:22 7440-22-408/15/16 21:1010.0 2.5 1
Thallium ND ug/L 08/18/16 17:29 7440-28-008/15/16 21:105.5 5.0 1
Vanadium ND ug/L 08/18/16 04:22 7440-62-208/15/16 21:1025.0 2.5 1
Zinc ND ug/L 08/18/16 04:22 7440-66-608/15/16 21:1010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 08/18/16 14:22 7439-97-608/15/16 17:100.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 08/14/16 18:33 67-64-110010.0 1
Acrylonitrile ND ug/L 08/14/16 18:33 107-13-12001.9 1
Benzene 0.34J ug/L 08/14/16 18:33 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 08/14/16 18:33 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 08/14/16 18:33 75-27-41.0 0.18 1
Bromoform ND ug/L 08/14/16 18:33 75-25-23.0 0.26 1
Bromomethane ND ug/L 08/14/16 18:33 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 08/14/16 18:33 78-93-31000.96 1
Carbon disulfide ND ug/L 08/14/16 18:33 75-15-01001.2 1
Carbon tetrachloride ND ug/L 08/14/16 18:33 56-23-51.0 0.25 1
Chlorobenzene 0.96J ug/L 08/14/16 18:33 108-90-73.0 0.23 1
Chloroethane ND ug/L 08/14/16 18:33 75-00-310.0 0.54 1
Chloroform ND ug/L 08/14/16 18:33 67-66-35.0 0.14 1
Chloromethane 0.12J ug/L 08/14/16 18:33 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 08/14/16 18:33 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 08/14/16 18:33 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 08/14/16 18:33 106-93-41.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Sample:3901-MW5R Lab ID:92308661002 Collected:08/11/16 09:00 Received:08/12/16 10:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Dibromomethane ND ug/L 08/14/16 18:33 74-95-310.0 0.21 1
1,2-Dichlorobenzene 1.2J ug/L 08/14/16 18:33 95-50-15.0 0.30 1
1,4-Dichlorobenzene 0.93J ug/L 08/14/16 18:33 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 08/14/16 18:33 110-57-61001.0 1
1,1-Dichloroethane 3.4J ug/L 08/14/16 18:33 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 08/14/16 18:33 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 08/14/16 18:33 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 2.7J ug/L 08/14/16 18:33 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 08/14/16 18:33 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 08/14/16 18:33 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 08/14/16 18:33 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 08/14/16 18:33 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 08/14/16 18:33 100-41-41.0 0.30 1
2-Hexanone ND ug/L 08/14/16 18:33 591-78-650.0 0.46 1
Iodomethane ND ug/L 08/14/16 18:33 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 08/14/16 18:33 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 08/14/16 18:33 108-10-11000.33 1
Styrene ND ug/L 08/14/16 18:33 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 08/14/16 18:33 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 08/14/16 18:33 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 08/14/16 18:33 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 08/14/16 18:33 109-99-910.0 3.1 1
Toluene ND ug/L 08/14/16 18:33 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 08/14/16 18:33 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 08/14/16 18:33 79-00-51.0 0.29 1
Trichloroethene ND ug/L 08/14/16 18:33 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 08/14/16 18:33 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 08/14/16 18:33 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 08/14/16 18:33 108-05-450.0 0.35 1
Vinyl chloride 5.6 ug/L 08/14/16 18:33 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 08/14/16 18:33 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)102 %08/14/16 18:33 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %08/14/16 18:33 17060-07-070-130 1
Toluene-d8 (S)103 %08/14/16 18:33 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 176000 ug/L 08/17/16 13:45500010001
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 301000 ug/L 08/18/16 10:5325000250001
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 08/17/16 21:40 18496-25-810001001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Sample:3901-MW5R Lab ID:92308661002 Collected:08/11/16 09:00 Received:08/12/16 10:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 3100J ug/L 08/18/16 12:09 14808-79-825000010001
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 51300 ug/L 08/17/16 01:20 16887-00-610000500010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Sample:3901-MW2 Lab ID:92308661003 Collected:08/10/16 13:37 Received:08/12/16 10:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 08/18/16 04:34 7440-36-008/15/16 21:106.0 3.8 1
Arsenic 3.5J ug/L 08/18/16 04:34 7440-38-208/15/16 21:1010.0 2.5 1
Barium 22.4J ug/L 08/18/16 04:34 7440-39-308/15/16 21:101002.5 1
Beryllium ND ug/L 08/18/16 04:34 7440-41-708/15/16 21:101.0 0.50 1
Cadmium ND ug/L 08/18/16 04:34 7440-43-908/15/16 21:101.0 0.50 1
Chromium 11.0 ug/L 08/18/16 04:34 7440-47-308/15/16 21:1010.0 2.5 1
Cobalt 12.7 ug/L 08/18/16 04:34 7440-48-408/15/16 21:1010.0 2.5 1
Copper 7.8J ug/L 08/18/16 04:34 7440-50-808/15/16 21:1010.0 2.5 1
Iron 10400 ug/L 08/18/16 04:34 7439-89-608/15/16 21:1030025.0 1
Lead 2.7J ug/L 08/18/16 04:34 7439-92-108/15/16 21:1010.0 2.5 1
Manganese 336 ug/L 08/18/16 04:34 7439-96-508/15/16 21:1050.0 2.5 1
Nickel 6.4J ug/L 08/18/16 04:34 7440-02-008/15/16 21:1050.0 2.5 1
Selenium ND ug/L 08/18/16 04:34 7782-49-208/15/16 21:1010.0 5.0 1
Silver ND ug/L 08/18/16 04:34 7440-22-408/15/16 21:1010.0 2.5 1
Thallium ND ug/L 08/18/16 17:32 7440-28-008/15/16 21:105.5 5.0 1
Vanadium 25.2 ug/L 08/18/16 04:34 7440-62-208/15/16 21:1025.0 2.5 1
Zinc 18.2 ug/L 08/18/16 04:34 7440-66-608/15/16 21:1010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury 0.11J ug/L 08/18/16 14:29 7439-97-608/15/16 17:100.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 08/14/16 18:50 67-64-110010.0 1
Acrylonitrile ND ug/L 08/14/16 18:50 107-13-12001.9 1
Benzene ND ug/L 08/14/16 18:50 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 08/14/16 18:50 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 08/14/16 18:50 75-27-41.0 0.18 1
Bromoform ND ug/L 08/14/16 18:50 75-25-23.0 0.26 1
Bromomethane ND ug/L 08/14/16 18:50 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 08/14/16 18:50 78-93-31000.96 1
Carbon disulfide ND ug/L 08/14/16 18:50 75-15-01001.2 1
Carbon tetrachloride ND ug/L 08/14/16 18:50 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 08/14/16 18:50 108-90-73.0 0.23 1
Chloroethane ND ug/L 08/14/16 18:50 75-00-310.0 0.54 1
Chloroform ND ug/L 08/14/16 18:50 67-66-35.0 0.14 1
Chloromethane ND ug/L 08/14/16 18:50 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 08/14/16 18:50 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 08/14/16 18:50 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 08/14/16 18:50 106-93-41.0 0.27 1
Dibromomethane ND ug/L 08/14/16 18:50 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 08/14/16 18:50 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 08/14/16 18:50 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 08/14/16 18:50 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 08/14/16 18:50 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 08/14/16 18:50 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 08/14/16 18:50 75-35-45.0 0.56 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Sample:3901-MW2 Lab ID:92308661003 Collected:08/10/16 13:37 Received:08/12/16 10:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,2-Dichloroethene ND ug/L 08/14/16 18:50 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 08/14/16 18:50 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 08/14/16 18:50 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 08/14/16 18:50 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 08/14/16 18:50 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 08/14/16 18:50 100-41-41.0 0.30 1
2-Hexanone ND ug/L 08/14/16 18:50 591-78-650.0 0.46 1
Iodomethane ND ug/L 08/14/16 18:50 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 08/14/16 18:50 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 08/14/16 18:50 108-10-11000.33 1
Styrene ND ug/L 08/14/16 18:50 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 08/14/16 18:50 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 08/14/16 18:50 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 08/14/16 18:50 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 08/14/16 18:50 109-99-910.0 3.1 1
Toluene ND ug/L 08/14/16 18:50 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 08/14/16 18:50 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 08/14/16 18:50 79-00-51.0 0.29 1
Trichloroethene ND ug/L 08/14/16 18:50 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 08/14/16 18:50 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 08/14/16 18:50 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 08/14/16 18:50 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 08/14/16 18:50 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 08/14/16 18:50 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %08/14/16 18:50 460-00-470-130 1
1,2-Dichloroethane-d4 (S)97 %08/14/16 18:50 17060-07-070-130 1
Toluene-d8 (S)103 %08/14/16 18:50 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 24400 ug/L 08/17/16 13:59500010001
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 122000 ug/L 08/18/16 12:05 D6,H125000250001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 8500J ug/L 08/18/16 12:20 14808-79-825000010001
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 4430 ug/L 08/17/16 00:15 16887-00-610005001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Sample:3901-MW3R Lab ID:92308661004 Collected:08/11/16 07:45 Received:08/12/16 10:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 08/18/16 04:37 7440-36-008/15/16 21:106.0 3.8 1
Arsenic ND ug/L 08/18/16 04:37 7440-38-208/15/16 21:1010.0 2.5 1
Barium 16.1J ug/L 08/18/16 04:37 7440-39-308/15/16 21:101002.5 1
Beryllium ND ug/L 08/18/16 04:37 7440-41-708/15/16 21:101.0 0.50 1
Cadmium ND ug/L 08/18/16 04:37 7440-43-908/15/16 21:101.0 0.50 1
Chromium 3.1J ug/L 08/18/16 04:37 7440-47-308/15/16 21:1010.0 2.5 1
Cobalt ND ug/L 08/18/16 04:37 7440-48-408/15/16 21:1010.0 2.5 1
Copper ND ug/L 08/18/16 04:37 7440-50-808/15/16 21:1010.0 2.5 1
Iron 839 ug/L 08/18/16 04:37 7439-89-608/15/16 21:1030025.0 1
Lead ND ug/L 08/18/16 04:37 7439-92-108/15/16 21:1010.0 2.5 1
Manganese 122 ug/L 08/18/16 04:37 7439-96-508/15/16 21:1050.0 2.5 1
Nickel 6.7J ug/L 08/18/16 04:37 7440-02-008/15/16 21:1050.0 2.5 1
Selenium ND ug/L 08/18/16 04:37 7782-49-208/15/16 21:1010.0 5.0 1
Silver ND ug/L 08/18/16 04:37 7440-22-408/15/16 21:1010.0 2.5 1
Thallium ND ug/L 08/18/16 17:35 7440-28-008/15/16 21:105.5 5.0 1
Vanadium ND ug/L 08/18/16 04:37 7440-62-208/15/16 21:1025.0 2.5 1
Zinc 8.6J ug/L 08/18/16 04:37 7440-66-608/15/16 21:1010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 08/18/16 16:36 7439-97-608/16/16 19:350.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 08/14/16 19:07 67-64-110010.0 1
Acrylonitrile ND ug/L 08/14/16 19:07 107-13-12001.9 1
Benzene ND ug/L 08/14/16 19:07 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 08/14/16 19:07 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 08/14/16 19:07 75-27-41.0 0.18 1
Bromoform ND ug/L 08/14/16 19:07 75-25-23.0 0.26 1
Bromomethane ND ug/L 08/14/16 19:07 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 08/14/16 19:07 78-93-31000.96 1
Carbon disulfide ND ug/L 08/14/16 19:07 75-15-01001.2 1
Carbon tetrachloride ND ug/L 08/14/16 19:07 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 08/14/16 19:07 108-90-73.0 0.23 1
Chloroethane ND ug/L 08/14/16 19:07 75-00-310.0 0.54 1
Chloroform ND ug/L 08/14/16 19:07 67-66-35.0 0.14 1
Chloromethane ND ug/L 08/14/16 19:07 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 08/14/16 19:07 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 08/14/16 19:07 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 08/14/16 19:07 106-93-41.0 0.27 1
Dibromomethane ND ug/L 08/14/16 19:07 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 08/14/16 19:07 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 08/14/16 19:07 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 08/14/16 19:07 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 08/14/16 19:07 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 08/14/16 19:07 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 08/14/16 19:07 75-35-45.0 0.56 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Sample:3901-MW3R Lab ID:92308661004 Collected:08/11/16 07:45 Received:08/12/16 10:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,2-Dichloroethene ND ug/L 08/14/16 19:07 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 08/14/16 19:07 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 08/14/16 19:07 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 08/14/16 19:07 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 08/14/16 19:07 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 08/14/16 19:07 100-41-41.0 0.30 1
2-Hexanone ND ug/L 08/14/16 19:07 591-78-650.0 0.46 1
Iodomethane ND ug/L 08/14/16 19:07 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 08/14/16 19:07 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 08/14/16 19:07 108-10-11000.33 1
Styrene ND ug/L 08/14/16 19:07 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 08/14/16 19:07 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 08/14/16 19:07 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 08/14/16 19:07 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 08/14/16 19:07 109-99-910.0 3.1 1
Toluene ND ug/L 08/14/16 19:07 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 08/14/16 19:07 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 08/14/16 19:07 79-00-51.0 0.29 1
Trichloroethene ND ug/L 08/14/16 19:07 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 08/14/16 19:07 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 08/14/16 19:07 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 08/14/16 19:07 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 08/14/16 19:07 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 08/14/16 19:07 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %08/14/16 19:07 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %08/14/16 19:07 17060-07-070-130 1
Toluene-d8 (S)108 %08/14/16 19:07 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 91800 ug/L 08/17/16 14:10500010001
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 171000 ug/L 08/18/16 10:5325000250001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 7700J ug/L 08/18/16 12:52 14808-79-825000010001
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 23200 ug/L 08/17/16 00:16 16887-00-610005001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Sample:3901-MW4R Lab ID:92308661005 Collected:08/11/16 09:30 Received:08/12/16 10:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 08/18/16 04:40 7440-36-008/15/16 21:106.0 3.8 1
Arsenic 3.2J ug/L 08/18/16 04:40 7440-38-208/15/16 21:1010.0 2.5 1
Barium 42.1J ug/L 08/18/16 04:40 7440-39-308/15/16 21:101002.5 1
Beryllium ND ug/L 08/18/16 04:40 7440-41-708/15/16 21:101.0 0.50 1
Cadmium ND ug/L 08/18/16 04:40 7440-43-908/15/16 21:101.0 0.50 1
Chromium 2.7J ug/L 08/18/16 04:40 7440-47-308/15/16 21:1010.0 2.5 1
Cobalt ND ug/L 08/18/16 04:40 7440-48-408/15/16 21:1010.0 2.5 1
Copper ND ug/L 08/18/16 04:40 7440-50-808/15/16 21:1010.0 2.5 1
Iron 104J ug/L 08/18/16 04:40 7439-89-608/15/16 21:1030025.0 1
Lead ND ug/L 08/18/16 04:40 7439-92-108/15/16 21:1010.0 2.5 1
Manganese 1550 ug/L 08/18/16 04:40 7439-96-508/15/16 21:1050.0 2.5 1
Nickel ND ug/L 08/18/16 04:40 7440-02-008/15/16 21:1050.0 2.5 1
Selenium ND ug/L 08/18/16 04:40 7782-49-208/15/16 21:1010.0 5.0 1
Silver ND ug/L 08/18/16 04:40 7440-22-408/15/16 21:1010.0 2.5 1
Thallium ND ug/L 08/18/16 17:38 7440-28-008/15/16 21:105.5 5.0 1
Vanadium ND ug/L 08/18/16 04:40 7440-62-208/15/16 21:1025.0 2.5 1
Zinc ND ug/L 08/18/16 04:40 7440-66-608/15/16 21:1010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 08/18/16 16:38 7439-97-608/16/16 19:350.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 08/15/16 02:47 67-64-110010.0 1
Acrylonitrile ND ug/L 08/15/16 02:47 107-13-12001.9 1
Benzene ND ug/L 08/15/16 02:47 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 08/15/16 02:47 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 08/15/16 02:47 75-27-41.0 0.18 1
Bromoform ND ug/L 08/15/16 02:47 75-25-23.0 0.26 1
Bromomethane ND ug/L 08/15/16 02:47 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 08/15/16 02:47 78-93-31000.96 1
Carbon disulfide ND ug/L 08/15/16 02:47 75-15-01001.2 1
Carbon tetrachloride ND ug/L 08/15/16 02:47 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 08/15/16 02:47 108-90-73.0 0.23 1
Chloroethane ND ug/L 08/15/16 02:47 75-00-310.0 0.54 1
Chloroform ND ug/L 08/15/16 02:47 67-66-35.0 0.14 1
Chloromethane ND ug/L 08/15/16 02:47 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 08/15/16 02:47 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 08/15/16 02:47 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 08/15/16 02:47 106-93-41.0 0.27 1
Dibromomethane ND ug/L 08/15/16 02:47 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 08/15/16 02:47 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 08/15/16 02:47 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 08/15/16 02:47 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 08/15/16 02:47 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 08/15/16 02:47 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 08/15/16 02:47 75-35-45.0 0.56 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Sample:3901-MW4R Lab ID:92308661005 Collected:08/11/16 09:30 Received:08/12/16 10:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,2-Dichloroethene ND ug/L 08/15/16 02:47 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 08/15/16 02:47 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 08/15/16 02:47 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 08/15/16 02:47 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 08/15/16 02:47 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 08/15/16 02:47 100-41-41.0 0.30 1
2-Hexanone ND ug/L 08/15/16 02:47 591-78-650.0 0.46 1
Iodomethane ND ug/L 08/15/16 02:47 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 08/15/16 02:47 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 08/15/16 02:47 108-10-11000.33 1
Styrene ND ug/L 08/15/16 02:47 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 08/15/16 02:47 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 08/15/16 02:47 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 08/15/16 02:47 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 08/15/16 02:47 109-99-910.0 3.1 1
Toluene ND ug/L 08/15/16 02:47 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 08/15/16 02:47 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 08/15/16 02:47 79-00-51.0 0.29 1
Trichloroethene ND ug/L 08/15/16 02:47 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 08/15/16 02:47 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 08/15/16 02:47 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 08/15/16 02:47 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 08/15/16 02:47 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 08/15/16 02:47 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)101 %08/15/16 02:47 460-00-470-130 1
1,2-Dichloroethane-d4 (S)97 %08/15/16 02:47 17060-07-070-130 1
Toluene-d8 (S)103 %08/15/16 02:47 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 304000 ug/L 08/17/16 14:23500010001
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 437000 ug/L 08/18/16 10:5425000250001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 10300J ug/L 08/18/16 13:02 14808-79-825000010001
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 57300 ug/L 08/17/16 00:17 16887-00-6500025005
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Sample:3901-MW6R Lab ID:92308661006 Collected:08/11/16 09:42 Received:08/12/16 10:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 08/18/16 04:43 7440-36-008/15/16 21:106.0 3.8 1
Arsenic 3.7J ug/L 08/18/16 04:43 7440-38-208/15/16 21:1010.0 2.5 1
Barium 102 ug/L 08/18/16 04:43 7440-39-308/15/16 21:101002.5 1
Beryllium ND ug/L 08/18/16 04:43 7440-41-708/15/16 21:101.0 0.50 1
Cadmium ND ug/L 08/18/16 04:43 7440-43-908/15/16 21:101.0 0.50 1
Chromium ND ug/L 08/18/16 04:43 7440-47-308/15/16 21:1010.0 2.5 1
Cobalt ND ug/L 08/18/16 04:43 7440-48-408/15/16 21:1010.0 2.5 1
Copper ND ug/L 08/18/16 04:43 7440-50-808/15/16 21:1010.0 2.5 1
Iron 2090 ug/L 08/18/16 04:43 7439-89-608/15/16 21:1030025.0 1
Lead ND ug/L 08/18/16 04:43 7439-92-108/15/16 21:1010.0 2.5 1
Manganese 1770 ug/L 08/18/16 04:43 7439-96-508/15/16 21:1050.0 2.5 1
Nickel ND ug/L 08/18/16 04:43 7440-02-008/15/16 21:1050.0 2.5 1
Selenium ND ug/L 08/18/16 04:43 7782-49-208/15/16 21:1010.0 5.0 1
Silver ND ug/L 08/18/16 04:43 7440-22-408/15/16 21:1010.0 2.5 1
Thallium ND ug/L 08/18/16 17:42 7440-28-008/15/16 21:105.5 5.0 1
Vanadium ND ug/L 08/18/16 04:43 7440-62-208/15/16 21:1025.0 2.5 1
Zinc ND ug/L 08/18/16 04:43 7440-66-608/15/16 21:1010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 08/18/16 16:40 7439-97-608/16/16 19:350.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 08/14/16 19:25 67-64-110010.0 1
Acrylonitrile ND ug/L 08/14/16 19:25 107-13-12001.9 1
Benzene ND ug/L 08/14/16 19:25 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 08/14/16 19:25 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 08/14/16 19:25 75-27-41.0 0.18 1
Bromoform ND ug/L 08/14/16 19:25 75-25-23.0 0.26 1
Bromomethane ND ug/L 08/14/16 19:25 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 08/14/16 19:25 78-93-31000.96 1
Carbon disulfide ND ug/L 08/14/16 19:25 75-15-01001.2 1
Carbon tetrachloride ND ug/L 08/14/16 19:25 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 08/14/16 19:25 108-90-73.0 0.23 1
Chloroethane ND ug/L 08/14/16 19:25 75-00-310.0 0.54 1
Chloroform ND ug/L 08/14/16 19:25 67-66-35.0 0.14 1
Chloromethane ND ug/L 08/14/16 19:25 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 08/14/16 19:25 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 08/14/16 19:25 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 08/14/16 19:25 106-93-41.0 0.27 1
Dibromomethane ND ug/L 08/14/16 19:25 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 08/14/16 19:25 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 08/14/16 19:25 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 08/14/16 19:25 110-57-61001.0 1
1,1-Dichloroethane 0.77J ug/L 08/14/16 19:25 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 08/14/16 19:25 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 08/14/16 19:25 75-35-45.0 0.56 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Sample:3901-MW6R Lab ID:92308661006 Collected:08/11/16 09:42 Received:08/12/16 10:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,2-Dichloroethene 0.50J ug/L 08/14/16 19:25 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 08/14/16 19:25 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 08/14/16 19:25 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 08/14/16 19:25 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 08/14/16 19:25 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 08/14/16 19:25 100-41-41.0 0.30 1
2-Hexanone ND ug/L 08/14/16 19:25 591-78-650.0 0.46 1
Iodomethane ND ug/L 08/14/16 19:25 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 08/14/16 19:25 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 08/14/16 19:25 108-10-11000.33 1
Styrene ND ug/L 08/14/16 19:25 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 08/14/16 19:25 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 08/14/16 19:25 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 08/14/16 19:25 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 08/14/16 19:25 109-99-910.0 3.1 1
Toluene ND ug/L 08/14/16 19:25 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 08/14/16 19:25 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 08/14/16 19:25 79-00-51.0 0.29 1
Trichloroethene ND ug/L 08/14/16 19:25 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 08/14/16 19:25 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 08/14/16 19:25 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 08/14/16 19:25 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 08/14/16 19:25 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 08/14/16 19:25 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %08/14/16 19:25 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %08/14/16 19:25 17060-07-070-130 1
Toluene-d8 (S)103 %08/14/16 19:25 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 173000 ug/L 08/17/16 14:38500010001
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 516000 ug/L 08/18/16 10:5425000250001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 3140J ug/L 08/18/16 13:13 14808-79-825000010001
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 147000 ug/L 08/17/16 00:18 16887-00-6500025005
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
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Page 22 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Sample:3901-SW1 Lab ID:92308661007 Collected:08/11/16 10:10 Received:08/12/16 10:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 08/18/16 04:46 7440-36-008/15/16 21:106.0 3.8 1
Arsenic 6.8J ug/L 08/18/16 04:46 7440-38-208/15/16 21:1010.0 2.5 1
Barium 175 ug/L 08/18/16 04:46 7440-39-308/15/16 21:101002.5 1
Beryllium 1.9 ug/L 08/18/16 04:46 7440-41-708/15/16 21:101.0 0.50 1
Cadmium ND ug/L 08/18/16 04:46 7440-43-908/15/16 21:101.0 0.50 1
Chromium 63.0 ug/L 08/18/16 04:46 7440-47-308/15/16 21:1010.0 2.5 1
Cobalt 16.7 ug/L 08/18/16 04:46 7440-48-408/15/16 21:1010.0 2.5 1
Copper 39.9 ug/L 08/18/16 04:46 7440-50-808/15/16 21:1010.0 2.5 1
Lead 16.6 ug/L 08/18/16 04:46 7439-92-108/15/16 21:1010.0 2.5 1
Nickel 22.8J ug/L 08/18/16 04:46 7440-02-008/15/16 21:1050.0 2.5 1
Selenium ND ug/L 08/18/16 04:46 7782-49-208/15/16 21:1010.0 5.0 1
Silver ND ug/L 08/18/16 04:46 7440-22-408/15/16 21:1010.0 2.5 1
Thallium ND ug/L 08/18/16 17:54 7440-28-008/15/16 21:105.5 5.0 1
Vanadium 160 ug/L 08/18/16 04:46 7440-62-208/15/16 21:1025.0 2.5 1
Zinc 66.4 ug/L 08/18/16 04:46 7440-66-608/15/16 21:1010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 08/14/16 19:59 67-64-110010.0 1
Acrylonitrile ND ug/L 08/14/16 19:59 107-13-12001.9 1
Benzene ND ug/L 08/14/16 19:59 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 08/14/16 19:59 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 08/14/16 19:59 75-27-41.0 0.18 1
Bromoform ND ug/L 08/14/16 19:59 75-25-23.0 0.26 1
Bromomethane ND ug/L 08/14/16 19:59 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 08/14/16 19:59 78-93-31000.96 1
Carbon disulfide ND ug/L 08/14/16 19:59 75-15-01001.2 1
Carbon tetrachloride ND ug/L 08/14/16 19:59 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 08/14/16 19:59 108-90-73.0 0.23 1
Chloroethane ND ug/L 08/14/16 19:59 75-00-310.0 0.54 1
Chloroform ND ug/L 08/14/16 19:59 67-66-35.0 0.14 1
Chloromethane ND ug/L 08/14/16 19:59 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 08/14/16 19:59 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 08/14/16 19:59 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 08/14/16 19:59 106-93-41.0 0.27 1
Dibromomethane ND ug/L 08/14/16 19:59 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 08/14/16 19:59 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 08/14/16 19:59 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 08/14/16 19:59 110-57-6 M11001.0 1
1,1-Dichloroethane ND ug/L 08/14/16 19:59 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 08/14/16 19:59 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 08/14/16 19:59 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 08/14/16 19:59 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 08/14/16 19:59 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 08/14/16 19:59 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 08/14/16 19:59 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 08/14/16 19:59 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
Page 23 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Sample:3901-SW1 Lab ID:92308661007 Collected:08/11/16 10:10 Received:08/12/16 10:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 08/14/16 19:59 100-41-41.0 0.30 1
2-Hexanone 1.2J ug/L 08/14/16 19:59 591-78-650.0 0.46 1
Iodomethane ND ug/L 08/14/16 19:59 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 08/14/16 19:59 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 08/14/16 19:59 108-10-11000.33 1
Styrene ND ug/L 08/14/16 19:59 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 08/14/16 19:59 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 08/14/16 19:59 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 08/14/16 19:59 127-18-41.0 0.46 1
Toluene ND ug/L 08/14/16 19:59 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 08/14/16 19:59 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 08/14/16 19:59 79-00-51.0 0.29 1
Trichloroethene ND ug/L 08/14/16 19:59 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 08/14/16 19:59 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 08/14/16 19:59 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 08/14/16 19:59 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 08/14/16 19:59 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 08/14/16 19:59 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %08/14/16 19:59 460-00-470-130 1
1,2-Dichloroethane-d4 (S)97 %08/14/16 19:59 17060-07-070-130 1
Toluene-d8 (S)104 %08/14/16 19:59 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Sample:3901-SW2 Lab ID:92308661008 Collected:08/11/16 09:45 Received:08/12/16 10:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 08/18/16 04:49 7440-36-008/15/16 21:106.0 3.8 1
Arsenic 7.3J ug/L 08/18/16 04:49 7440-38-208/15/16 21:1010.0 2.5 1
Barium 152 ug/L 08/18/16 04:49 7440-39-308/15/16 21:101002.5 1
Beryllium 1.7 ug/L 08/18/16 04:49 7440-41-708/15/16 21:101.0 0.50 1
Cadmium ND ug/L 08/18/16 04:49 7440-43-908/15/16 21:101.0 0.50 1
Chromium 55.1 ug/L 08/18/16 04:49 7440-47-308/15/16 21:1010.0 2.5 1
Cobalt 12.7 ug/L 08/18/16 04:49 7440-48-408/15/16 21:1010.0 2.5 1
Copper 34.5 ug/L 08/18/16 04:49 7440-50-808/15/16 21:1010.0 2.5 1
Lead 13.6 ug/L 08/18/16 04:49 7439-92-108/15/16 21:1010.0 2.5 1
Nickel 19.4J ug/L 08/18/16 04:49 7440-02-008/15/16 21:1050.0 2.5 1
Selenium 6.0J ug/L 08/18/16 04:49 7782-49-208/15/16 21:1010.0 5.0 1
Silver ND ug/L 08/18/16 04:49 7440-22-408/15/16 21:1010.0 2.5 1
Thallium ND ug/L 08/18/16 17:57 7440-28-008/15/16 21:105.5 5.0 1
Vanadium 144 ug/L 08/18/16 04:49 7440-62-208/15/16 21:1025.0 2.5 1
Zinc 54.1 ug/L 08/18/16 04:49 7440-66-608/15/16 21:1010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 08/15/16 03:04 67-64-110010.0 1
Acrylonitrile ND ug/L 08/15/16 03:04 107-13-12001.9 1
Benzene ND ug/L 08/15/16 03:04 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 08/15/16 03:04 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 08/15/16 03:04 75-27-41.0 0.18 1
Bromoform ND ug/L 08/15/16 03:04 75-25-23.0 0.26 1
Bromomethane ND ug/L 08/15/16 03:04 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 08/15/16 03:04 78-93-31000.96 1
Carbon disulfide ND ug/L 08/15/16 03:04 75-15-01001.2 1
Carbon tetrachloride ND ug/L 08/15/16 03:04 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 08/15/16 03:04 108-90-73.0 0.23 1
Chloroethane ND ug/L 08/15/16 03:04 75-00-310.0 0.54 1
Chloroform ND ug/L 08/15/16 03:04 67-66-35.0 0.14 1
Chloromethane ND ug/L 08/15/16 03:04 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 08/15/16 03:04 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 08/15/16 03:04 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 08/15/16 03:04 106-93-41.0 0.27 1
Dibromomethane ND ug/L 08/15/16 03:04 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 08/15/16 03:04 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 08/15/16 03:04 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 08/15/16 03:04 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 08/15/16 03:04 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 08/15/16 03:04 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 08/15/16 03:04 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 08/15/16 03:04 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 08/15/16 03:04 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 08/15/16 03:04 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 08/15/16 03:04 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 08/15/16 03:04 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Sample:3901-SW2 Lab ID:92308661008 Collected:08/11/16 09:45 Received:08/12/16 10:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 08/15/16 03:04 100-41-41.0 0.30 1
2-Hexanone ND ug/L 08/15/16 03:04 591-78-650.0 0.46 1
Iodomethane ND ug/L 08/15/16 03:04 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 08/15/16 03:04 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 08/15/16 03:04 108-10-11000.33 1
Styrene ND ug/L 08/15/16 03:04 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 08/15/16 03:04 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 08/15/16 03:04 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 08/15/16 03:04 127-18-41.0 0.46 1
Toluene ND ug/L 08/15/16 03:04 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 08/15/16 03:04 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 08/15/16 03:04 79-00-51.0 0.29 1
Trichloroethene ND ug/L 08/15/16 03:04 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 08/15/16 03:04 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 08/15/16 03:04 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 08/15/16 03:04 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 08/15/16 03:04 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 08/15/16 03:04 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)101 %08/15/16 03:04 460-00-470-130 1
1,2-Dichloroethane-d4 (S)94 %08/15/16 03:04 17060-07-070-130 1
Toluene-d8 (S)103 %08/15/16 03:04 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 26 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
324995
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92308661001, 92308661002, 92308661003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1800616
Associated Lab Samples:92308661001, 92308661002, 92308661003
Matrix:Water
AnalyzedMDL
Mercury ug/L ND 0.20 08/18/16 12:540.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1800617LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.62.5 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1800618MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92307940041
1800619
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 100 75-12599 1 252.5ND 2.5 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
325127
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92308661004, 92308661005, 92308661006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1801100
Associated Lab Samples:92308661004, 92308661005, 92308661006
Matrix:Water
AnalyzedMDL
Mercury ug/L ND 0.20 08/18/16 16:060.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1801101LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.42.5 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1801102MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92308645009
1801103
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L M1,R12.5 56 75-12576 29 252.5ND 1.5 2.0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
325039
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92308661001, 92308661002, 92308661003, 92308661004, 92308661005, 92308661006, 92308661007,
92308661008
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1800845
Associated Lab Samples:92308661001, 92308661002, 92308661003, 92308661004, 92308661005, 92308661006, 92308661007,
92308661008
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 08/18/16 04:073.8
Arsenic ug/L ND 10.0 08/18/16 04:072.5
Barium ug/L ND 100 08/18/16 04:072.5
Beryllium ug/L ND 1.0 08/18/16 04:070.50
Cadmium ug/L ND 1.0 08/18/16 04:070.50
Chromium ug/L ND 10.0 08/18/16 04:072.5
Cobalt ug/L ND 10.0 08/18/16 04:072.5
Copper ug/L ND 10.0 08/18/16 04:072.5
Iron ug/L ND 300 08/18/16 04:0725.0
Lead ug/L ND 10.0 08/18/16 04:072.5
Manganese ug/L ND 50.0 08/18/16 04:072.5
Nickel ug/L ND 50.0 08/18/16 04:072.5
Selenium ug/L ND 10.0 08/18/16 04:075.0
Silver ug/L ND 10.0 08/18/16 04:072.5
Thallium ug/L ND 5.5 08/18/16 17:145.0
Vanadium ug/L ND 25.0 08/18/16 04:072.5
Zinc ug/L ND 10.0 08/18/16 04:075.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1800846LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 469500 94 80-120
Arsenic ug/L 456500 91 80-120
Barium ug/L 493500 99 80-120
Beryllium ug/L 518500 104 80-120
Cadmium ug/L 486500 97 80-120
Chromium ug/L 520500 104 80-120
Cobalt ug/L 488500 98 80-120
Copper ug/L 489500 98 80-120
Iron ug/L 50005000 100 80-120
Lead ug/L 485500 97 80-120
Manganese ug/L 512500 102 80-120
Nickel ug/L 481500 96 80-120
Selenium ug/L 477500 95 80-120
Silver ug/L 250250 100 80-120
Thallium ug/L 473500 95 80-120
Vanadium ug/L 498500 100 80-120
Zinc ug/L 510500 102 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1800847MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92308661001
1800848
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 94 75-12595 1 25500ND471475
Arsenic ug/L 500 93 75-12593 0 25500ND464464
Barium ug/L 500 99 75-12599 0 255003.9J 497 499
Beryllium ug/L 500 104 75-125105 1 25500ND518523
Cadmium ug/L 500 97 75-12598 1 25500ND485488
Chromium ug/L 500 103 75-125104 1 255003.4J 517 525
Cobalt ug/L 500 96 75-12596 0 25500ND478480
Copper ug/L 500 98 75-12598 1 25500ND489492
Iron ug/L 5000 99 75-125101 1 255000292J52505320
Lead ug/L 500 94 75-12595 1 25500ND472476
Manganese ug/L 500 101 75-125102 1 255005.9J 512 515
Nickel ug/L 500 94 75-12594 0 25500ND471473
Selenium ug/L 500 94 75-12595 1 25500ND472475
Silver ug/L 250 99 75-125100 1 25250ND249252
Thallium ug/L 500 91 75-12592 1 25500ND457463
Vanadium ug/L 500 100 75-125101 1 25500ND503508
Zinc ug/L 500 100 75-125101 1 25500ND505512
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
324951
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92308661002, 92308661003, 92308661004, 92308661006, 92308661007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1800439
Associated Lab Samples:92308661002, 92308661003, 92308661004, 92308661006, 92308661007
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 08/14/16 14:360.33
1,1,1-Trichloroethane ug/L ND 1.0 08/14/16 14:360.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 08/14/16 14:360.40
1,1,2-Trichloroethane ug/L ND 1.0 08/14/16 14:360.29
1,1-Dichloroethane ug/L ND 5.0 08/14/16 14:360.32
1,1-Dichloroethene ug/L ND 5.0 08/14/16 14:360.56
1,2,3-Trichloropropane ug/L ND 1.0 08/14/16 14:360.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 08/14/16 14:362.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 08/14/16 14:360.27
1,2-Dichlorobenzene ug/L ND 5.0 08/14/16 14:360.30
1,2-Dichloroethane ug/L ND 1.0 08/14/16 14:360.24
1,2-Dichloropropane ug/L ND 1.0 08/14/16 14:360.27
1,4-Dichlorobenzene ug/L ND 1.0 08/14/16 14:360.33
2-Butanone (MEK)ug/L ND 100 08/14/16 14:360.96
2-Hexanone ug/L ND 50.0 08/14/16 14:360.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 08/14/16 14:360.33
Acetone ug/L ND 100 08/14/16 14:3610.0
Acrylonitrile ug/L ND 200 08/14/16 14:361.9
Benzene ug/L ND 1.0 08/14/16 14:360.25
Bromochloromethane ug/L ND 3.0 08/14/16 14:360.17
Bromodichloromethane ug/L ND 1.0 08/14/16 14:360.18
Bromoform ug/L ND 3.0 08/14/16 14:360.26
Bromomethane ug/L ND 10.0 08/14/16 14:360.29
Carbon disulfide ug/L ND 100 08/14/16 14:361.2
Carbon tetrachloride ug/L ND 1.0 08/14/16 14:360.25
Chlorobenzene ug/L ND 3.0 08/14/16 14:360.23
Chloroethane ug/L ND 10.0 08/14/16 14:360.54
Chloroform ug/L ND 5.0 08/14/16 14:360.14
Chloromethane ug/L ND 1.0 08/14/16 14:360.11
cis-1,2-Dichloroethene ug/L ND 5.0 08/14/16 14:360.19
cis-1,3-Dichloropropene ug/L ND 1.0 08/14/16 14:360.13
Dibromochloromethane ug/L ND 3.0 08/14/16 14:360.21
Dibromomethane ug/L ND 10.0 08/14/16 14:360.21
Ethylbenzene ug/L ND 1.0 08/14/16 14:360.30
Iodomethane ug/L ND 10.0 08/14/16 14:360.32
Methylene Chloride ug/L ND 1.0 08/14/16 14:360.97
Styrene ug/L ND 1.0 08/14/16 14:360.26
Tetrachloroethene ug/L ND 1.0 08/14/16 14:360.46
Tetrahydrofuran ug/L ND 10.0 08/14/16 14:363.1
Toluene ug/L ND 1.0 08/14/16 14:360.26
trans-1,2-Dichloroethene ug/L ND 5.0 08/14/16 14:360.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1800439
Associated Lab Samples:92308661002, 92308661003, 92308661004, 92308661006, 92308661007
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 08/14/16 14:360.26
trans-1,4-Dichloro-2-butene ug/L ND 100 08/14/16 14:361.0
Trichloroethene ug/L ND 1.0 08/14/16 14:360.47
Trichlorofluoromethane ug/L ND 1.0 08/14/16 14:360.20
Vinyl acetate ug/L ND 50.0 08/14/16 14:360.35
Vinyl chloride ug/L ND 1.0 08/14/16 14:360.62
Xylene (Total)ug/L ND 5.0 08/14/16 14:360.66
1,2-Dichloroethane-d4 (S)%95 70-130 08/14/16 14:36
4-Bromofluorobenzene (S)%100 70-130 08/14/16 14:36
Toluene-d8 (S)%103 70-130 08/14/16 14:36
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1800440LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 51.250 102 80-125
1,1,1-Trichloroethane ug/L 49.850 100 71-129
1,1,2,2-Tetrachloroethane ug/L 45.950 92 79-124
1,1,2-Trichloroethane ug/L 49.450 99 85-125
1,1-Dichloroethane ug/L 49.250 98 73-126
1,1-Dichloroethene ug/L 50.050 100 66-135
1,2,3-Trichloropropane ug/L 45.750 91 75-130
1,2-Dibromo-3-chloropropane ug/L 49.150 98 71-133
1,2-Dibromoethane (EDB)ug/L 54.450 109 83-124
1,2-Dichlorobenzene ug/L 53.150 106 80-133
1,2-Dichloroethane ug/L 45.550 91 67-128
1,2-Dichloropropane ug/L 47.450 95 75-132
1,4-Dichlorobenzene ug/L 49.350 99 78-130
2-Butanone (MEK)ug/L 87.1J100 87 61-144
2-Hexanone ug/L 88.2100 88 68-143
4-Methyl-2-pentanone (MIBK)ug/L 92.0J100 92 72-135
Acetone ug/L 85.1J100 85 48-146
Acrylonitrile ug/L 245250 98 40-160
Benzene ug/L 50.050 100 80-125
Bromochloromethane ug/L 50.750 101 71-125
Bromodichloromethane ug/L 49.150 98 78-124
Bromoform ug/L 46.950 94 71-128
Bromomethane ug/L 35.650 71 40-160
Carbon disulfide ug/L 46.9J50 94 50-160
Carbon tetrachloride ug/L 50.050 100 69-131
Chlorobenzene ug/L 50.750 101 81-122
Chloroethane ug/L 44.950 90 39-148
Chloroform ug/L 47.550 95 73-127
Chloromethane ug/L 46.350 93 44-146
cis-1,2-Dichloroethene ug/L 49.350 99 74-124
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1800440LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,3-Dichloropropene ug/L 52.050 104 72-132
Dibromochloromethane ug/L 50.750 101 78-125
Dibromomethane ug/L 49.550 99 82-120
Ethylbenzene ug/L 47.750 95 79-121
Iodomethane ug/L 78.6100 79 39-154
Methylene Chloride ug/L 51.250 102 64-133
Styrene ug/L 53.050 106 84-126
Tetrachloroethene ug/L 46.750 93 78-122
Tetrahydrofuran ug/L 444500 89 69-148
Toluene ug/L 49.050 98 80-121
trans-1,2-Dichloroethene ug/L 50.550 101 71-127
trans-1,3-Dichloropropene ug/L 51.050 102 69-141
trans-1,4-Dichloro-2-butene ug/L 39.7J50 79 40-160
Trichloroethene ug/L 49.850 100 78-122
Trichlorofluoromethane ug/L 48.350 97 53-137
Vinyl acetate ug/L 98.4100 98 40-160
Vinyl chloride ug/L 50.950 102 58-137
Xylene (Total)ug/L 142150 95 81-126
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1800442MATRIX SPIKE SAMPLE:
MSSpike
Result
92308661007
1,1,1,2-Tetrachloroethane ug/L 21.120 105 70-130ND
1,1,1-Trichloroethane ug/L 24.120 121 70-130ND
1,1,2,2-Tetrachloroethane ug/L 19.720 98 70-130ND
1,1,2-Trichloroethane ug/L 21.720 109 70-130ND
1,1-Dichloroethane ug/L 24.220 121 70-130ND
1,1-Dichloroethene ug/L 26.020 130 70-166ND
1,2,3-Trichloropropane ug/L 19.020 95 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.120 95 70-130ND
1,2-Dibromoethane (EDB)ug/L 23.420 117 70-130ND
1,2-Dichlorobenzene ug/L 22.720 114 70-130ND
1,2-Dichloroethane ug/L 22.120 110 70-130ND
1,2-Dichloropropane ug/L 22.720 113 70-130ND
1,4-Dichlorobenzene ug/L 20.820 104 70-130ND
2-Butanone (MEK)ug/L 44.4J40 111 70-130ND
2-Hexanone ug/L 42.9J40 104 70-1301.2J
4-Methyl-2-pentanone (MIBK)ug/L 42.1J40 105 70-130ND
Acetone ug/L 46.7J40 110 70-130ND
Acrylonitrile ug/L 115J100 115 70-130ND
Benzene ug/L 23.320 117 70-148ND
Bromochloromethane ug/L 25.220 126 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1800442MATRIX SPIKE SAMPLE:
MSSpike
Result
92308661007
Bromodichloromethane ug/L 21.520 108 70-130ND
Bromoform ug/L 18.520 92 70-130ND
Bromomethane ug/L 14.320 71 70-130ND
Carbon disulfide ug/L 25.9J20 129 70-130ND
Carbon tetrachloride ug/L 22.920 115 70-130ND
Chlorobenzene ug/L 22.920 115 70-146ND
Chloroethane ug/L 24.620 123 70-130ND
Chloroform ug/L 23.020 115 70-130ND
Chloromethane ug/L 22.420 112 70-130ND
cis-1,2-Dichloroethene ug/L 24.220 121 70-130ND
cis-1,3-Dichloropropene ug/L 22.120 111 70-130ND
Dibromochloromethane ug/L 20.820 104 70-130ND
Dibromomethane ug/L 23.220 116 70-130ND
Ethylbenzene ug/L 22.020 110 70-130ND
Iodomethane ug/L 30.840 77 70-130ND
Methylene Chloride ug/L 23.520 118 70-130ND
Styrene ug/L 23.020 115 70-130ND
Tetrachloroethene ug/L 21.620 108 70-130ND
Tetrahydrofuran ug/L 225200 113 70-130ND
Toluene ug/L 22.620 113 70-155ND
trans-1,2-Dichloroethene ug/L 23.920 120 70-130ND
trans-1,3-Dichloropropene ug/L 20.920 105 70-130ND
trans-1,4-Dichloro-2-butene ug/L 7.9J M1203970-130ND
Trichloroethene ug/L 23.120 115 69-151ND
Trichlorofluoromethane ug/L 23.220 116 70-130ND
Vinyl acetate ug/L 40.0J40 100 70-130ND
Vinyl chloride ug/L 24.920 124 70-130ND
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92308661006
1800441SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 0.72J 300.77J
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92308661006
1800441SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L 0.45J 300.50J
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%102 399
4-Bromofluorobenzene (S)%102 2100
Toluene-d8 (S)%102 1103
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
324953
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92308661001, 92308661005, 92308661008
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1800448
Associated Lab Samples:92308661001, 92308661005, 92308661008
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 08/15/16 01:220.33
1,1,1-Trichloroethane ug/L ND 1.0 08/15/16 01:220.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 08/15/16 01:220.40
1,1,2-Trichloroethane ug/L ND 1.0 08/15/16 01:220.29
1,1-Dichloroethane ug/L ND 5.0 08/15/16 01:220.32
1,1-Dichloroethene ug/L ND 5.0 08/15/16 01:220.56
1,2,3-Trichloropropane ug/L ND 1.0 08/15/16 01:220.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 08/15/16 01:222.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 08/15/16 01:220.27
1,2-Dichlorobenzene ug/L ND 5.0 08/15/16 01:220.30
1,2-Dichloroethane ug/L ND 1.0 08/15/16 01:220.24
1,2-Dichloropropane ug/L ND 1.0 08/15/16 01:220.27
1,4-Dichlorobenzene ug/L ND 1.0 08/15/16 01:220.33
2-Butanone (MEK)ug/L ND 100 08/15/16 01:220.96
2-Hexanone ug/L ND 50.0 08/15/16 01:220.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 08/15/16 01:220.33
Acetone ug/L ND 100 08/15/16 01:2210.0
Acrylonitrile ug/L ND 200 08/15/16 01:221.9
Benzene ug/L ND 1.0 08/15/16 01:220.25
Bromochloromethane ug/L ND 3.0 08/15/16 01:220.17
Bromodichloromethane ug/L ND 1.0 08/15/16 01:220.18
Bromoform ug/L ND 3.0 08/15/16 01:220.26
Bromomethane ug/L ND 10.0 08/15/16 01:220.29
Carbon disulfide ug/L ND 100 08/15/16 01:221.2
Carbon tetrachloride ug/L ND 1.0 08/15/16 01:220.25
Chlorobenzene ug/L ND 3.0 08/15/16 01:220.23
Chloroethane ug/L ND 10.0 08/15/16 01:220.54
Chloroform ug/L ND 5.0 08/15/16 01:220.14
Chloromethane ug/L ND 1.0 08/15/16 01:220.11
cis-1,2-Dichloroethene ug/L ND 5.0 08/15/16 01:220.19
cis-1,3-Dichloropropene ug/L ND 1.0 08/15/16 01:220.13
Dibromochloromethane ug/L ND 3.0 08/15/16 01:220.21
Dibromomethane ug/L ND 10.0 08/15/16 01:220.21
Ethylbenzene ug/L ND 1.0 08/15/16 01:220.30
Iodomethane ug/L ND 10.0 08/15/16 01:220.32
Methylene Chloride ug/L ND 1.0 08/15/16 01:220.97
Styrene ug/L ND 1.0 08/15/16 01:220.26
Tetrachloroethene ug/L ND 1.0 08/15/16 01:220.46
Tetrahydrofuran ug/L ND 10.0 08/15/16 01:223.1
Toluene ug/L ND 1.0 08/15/16 01:220.26
trans-1,2-Dichloroethene ug/L ND 5.0 08/15/16 01:220.49
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1800448
Associated Lab Samples:92308661001, 92308661005, 92308661008
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 08/15/16 01:220.26
trans-1,4-Dichloro-2-butene ug/L ND 100 08/15/16 01:221.0
Trichloroethene ug/L ND 1.0 08/15/16 01:220.47
Trichlorofluoromethane ug/L ND 1.0 08/15/16 01:220.20
Vinyl acetate ug/L ND 50.0 08/15/16 01:220.35
Vinyl chloride ug/L ND 1.0 08/15/16 01:220.62
Xylene (Total)ug/L ND 5.0 08/15/16 01:220.66
1,2-Dichloroethane-d4 (S)%95 70-130 08/15/16 01:22
4-Bromofluorobenzene (S)%102 70-130 08/15/16 01:22
Toluene-d8 (S)%102 70-130 08/15/16 01:22
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1800449LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.250 100 80-125
1,1,1-Trichloroethane ug/L 50.050 100 71-129
1,1,2,2-Tetrachloroethane ug/L 46.150 92 79-124
1,1,2-Trichloroethane ug/L 51.450 103 85-125
1,1-Dichloroethane ug/L 50.650 101 73-126
1,1-Dichloroethene ug/L 52.650 105 66-135
1,2,3-Trichloropropane ug/L 45.550 91 75-130
1,2-Dibromo-3-chloropropane ug/L 48.950 98 71-133
1,2-Dibromoethane (EDB)ug/L 55.750 111 83-124
1,2-Dichlorobenzene ug/L 52.250 104 80-133
1,2-Dichloroethane ug/L 46.950 94 67-128
1,2-Dichloropropane ug/L 50.150 100 75-132
1,4-Dichlorobenzene ug/L 48.550 97 78-130
2-Butanone (MEK)ug/L 101100 101 61-144
2-Hexanone ug/L 99.3100 99 68-143
4-Methyl-2-pentanone (MIBK)ug/L 103100 103 72-135
Acetone ug/L 97.4J100 97 48-146
Acrylonitrile ug/L 252250 101 40-160
Benzene ug/L 51.850 104 80-125
Bromochloromethane ug/L 52.150 104 71-125
Bromodichloromethane ug/L 50.550 101 78-124
Bromoform ug/L 44.350 89 71-128
Bromomethane ug/L 41.150 82 40-160
Carbon disulfide ug/L 54.0J50 108 50-160
Carbon tetrachloride ug/L 50.950 102 69-131
Chlorobenzene ug/L 50.250 100 81-122
Chloroethane ug/L 46.250 92 39-148
Chloroform ug/L 49.350 99 73-127
Chloromethane ug/L 48.750 97 44-146
cis-1,2-Dichloroethene ug/L 50.750 101 74-124
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1800449LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,3-Dichloropropene ug/L 51.950 104 72-132
Dibromochloromethane ug/L 50.150 100 78-125
Dibromomethane ug/L 52.450 105 82-120
Ethylbenzene ug/L 47.950 96 79-121
Iodomethane ug/L 101100 101 39-154
Methylene Chloride ug/L 53.250 106 64-133
Styrene ug/L 53.550 107 84-126
Tetrachloroethene ug/L 47.450 95 78-122
Tetrahydrofuran ug/L 505500 101 69-148
Toluene ug/L 50.450 101 80-121
trans-1,2-Dichloroethene ug/L 52.450 105 71-127
trans-1,3-Dichloropropene ug/L 50.650 101 69-141
trans-1,4-Dichloro-2-butene ug/L 34.6J50 69 40-160
Trichloroethene ug/L 51.150 102 78-122
Trichlorofluoromethane ug/L 48.950 98 53-137
Vinyl acetate ug/L 101100 101 40-160
Vinyl chloride ug/L 53.150 106 58-137
Xylene (Total)ug/L 144150 96 81-126
1,2-Dichloroethane-d4 (S)%90 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1800451MATRIX SPIKE SAMPLE:
MSSpike
Result
92308664003
1,1,1,2-Tetrachloroethane ug/L 20.620 103 70-130ND
1,1,1-Trichloroethane ug/L 22.120 111 70-130ND
1,1,2,2-Tetrachloroethane ug/L 18.820 94 70-130ND
1,1,2-Trichloroethane ug/L 21.620 108 70-130ND
1,1-Dichloroethane ug/L 22.720 114 70-130ND
1,1-Dichloroethene ug/L 24.520 122 70-166ND
1,2,3-Trichloropropane ug/L 20.020 100 70-130ND
1,2-Dibromo-3-chloropropane ug/L 20.220 101 70-130ND
1,2-Dibromoethane (EDB)ug/L 22.420 112 70-130ND
1,2-Dichlorobenzene ug/L 21.920 110 70-130ND
1,2-Dichloroethane ug/L 20.820 104 70-130ND
1,2-Dichloropropane ug/L 21.720 109 70-130ND
1,4-Dichlorobenzene ug/L 20.420 102 70-130ND
2-Butanone (MEK)ug/L 43.1J40 108 70-130ND
2-Hexanone ug/L 40.2J40 100 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 41.0J40 103 70-130ND
Acetone ug/L 42.6J40 107 70-130ND
Acrylonitrile ug/L 110J100 110 70-130ND
Benzene ug/L 23.820 119 70-148ND
Bromochloromethane ug/L 24.020 120 70-130ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1800451MATRIX SPIKE SAMPLE:
MSSpike
Result
92308664003
Bromodichloromethane ug/L 21.820 109 70-130ND
Bromoform ug/L 17.720 89 70-130ND
Bromomethane ug/L 12.6 M1206370-130ND
Carbon disulfide ug/L 24.8J20 124 70-130ND
Carbon tetrachloride ug/L 23.520 118 70-130ND
Chlorobenzene ug/L 21.820 109 70-146ND
Chloroethane ug/L 23.920 119 70-130ND
Chloroform ug/L 22.120 110 70-130ND
Chloromethane ug/L 20.920 104 70-130ND
cis-1,2-Dichloroethene ug/L 23.220 116 70-130ND
cis-1,3-Dichloropropene ug/L 20.820 104 70-130ND
Dibromochloromethane ug/L 19.920 100 70-130ND
Dibromomethane ug/L 22.220 111 70-130ND
Ethylbenzene ug/L 21.120 106 70-130ND
Iodomethane ug/L 33.940 85 70-130ND
Methylene Chloride ug/L 21.720 108 70-130ND
Styrene ug/L 21.620 108 70-130ND
Tetrachloroethene ug/L 19.720 98 70-130ND
Tetrahydrofuran ug/L 213200 107 70-130ND
Toluene ug/L 22.520 112 70-155ND
trans-1,2-Dichloroethene ug/L 23.020 115 70-130ND
trans-1,3-Dichloropropene ug/L 19.620 98 70-130ND
trans-1,4-Dichloro-2-butene ug/L 6.1J M1203070-130ND
Trichloroethene ug/L 23.020 115 69-151ND
Trichlorofluoromethane ug/L 24.020 120 70-130ND
Vinyl acetate ug/L 28.5J40 71 70-130ND
Vinyl chloride ug/L 24.320 122 70-130ND
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92308664002
1800450SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92308664002
1800450SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%95 095
4-Bromofluorobenzene (S)%101 0101
Toluene-d8 (S)%102 1101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
325043
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples:92308661001, 92308661002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1800863
Associated Lab Samples:92308661001, 92308661002
Matrix:Water
AnalyzedMDL
beta-BHC ug/L ND 0.050 08/17/16 00:190.050
Endosulfan I ug/L ND 0.10 08/17/16 00:190.050
Decachlorobiphenyl (S)%59 20-130 08/17/16 00:19
Tetrachloro-m-xylene (S)%64 20-130 08/17/16 00:19
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1800864LABORATORY CONTROL SAMPLE:
LCSSpike
beta-BHC ug/L 0.22.25 88 20-150
Endosulfan I ug/L 0.22.25 88 20-150
Decachlorobiphenyl (S)%69 20-130
Tetrachloro-m-xylene (S)%69 20-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1800865MATRIX SPIKE SAMPLE:
MSSpike
Result
92308300001
beta-BHC ug/L 0.18.25 74 20-150ND
Endosulfan I ug/L 0.19.25 76 20-150ND
Decachlorobiphenyl (S)%55 20-130
Tetrachloro-m-xylene (S)%65 20-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92308300002
1800866SAMPLE DUPLICATE:
beta-BHC ug/L ND 30ND
Endosulfan I ug/L ND 30ND
Decachlorobiphenyl (S)%53 757
Tetrachloro-m-xylene (S)%66 165
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
325266
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92308661001, 92308661002, 92308661003, 92308661004, 92308661005, 92308661006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1802039
Associated Lab Samples:92308661001, 92308661002, 92308661003, 92308661004, 92308661005, 92308661006
Matrix:Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 08/17/16 12:461000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1802040LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4520050000 90 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1802041MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92308661001
1802042
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 99 80-12095 1 2550000108000158000156000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1802043MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92308879002
1802044
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 99 80-12096 2 255000017.1 mg/L 66500 65200
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
325215
SM 2540C
SM 2540C
2540C Total Dissolved Solids
Associated Lab Samples:92308661003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1801826
Associated Lab Samples:92308661003
Matrix:Water
AnalyzedMDL
Total Dissolved Solids ug/L ND 25000 08/18/16 12:0525000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1801827LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids ug/L 226000250000 90 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92308250019
1801828SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 524000 2 5515 mg/L
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92308661003
1801829SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 108000 D6125122000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
325401
SM 2540C
SM 2540C
2540C Total Dissolved Solids
Associated Lab Samples:92308661001, 92308661002, 92308661004, 92308661005, 92308661006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1802830
Associated Lab Samples:92308661001, 92308661002, 92308661004, 92308661005, 92308661006
Matrix:Water
AnalyzedMDL
Total Dissolved Solids ug/L ND 25000 08/18/16 10:4925000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1802831LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids ug/L 226000250000 90 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92307940046
1802832SAMPLE DUPLICATE:
Total Dissolved Solids ug/L ND 5ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92308416031
1802833SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 320000 2 5314 mg/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
325419
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92308661001, 92308661002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1803031
Associated Lab Samples:92308661001, 92308661002
Matrix:Water
AnalyzedMDL
Sulfide ug/L ND 1000 08/17/16 21:40100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1803032LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 500J500 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1803033MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92308587002
1803034
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L M35006480-12064 0 10500ND319J319J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1803035MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92308743006
1803036
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 103 80-120103 0 10500ND513J513J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
325309
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples:92308661001, 92308661002, 92308661003, 92308661004, 92308661005, 92308661006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1802222
Associated Lab Samples:92308661001, 92308661002, 92308661003, 92308661004, 92308661005, 92308661006
Matrix:Water
AnalyzedMDL
Sulfate ug/L ND 250000 08/17/16 15:421000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1802223LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 20600J20000 103 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1802224MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92308673001
1802225
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 96 90-11096 0 102000099.6 mg/L 119000J 119000J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1802226MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92308473009
1802227
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 102 90-110102 0 10200006.2 mg/L 26500J 26500J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/25/2016 03:34 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
325179
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples:92308661001, 92308661002, 92308661003, 92308661004, 92308661005, 92308661006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1801465
Associated Lab Samples:92308661001, 92308661002, 92308661003, 92308661004, 92308661005, 92308661006
Matrix:Water
AnalyzedMDL
Chloride ug/L ND 1000 08/16/16 23:48500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1801466LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 2060020000 103 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1801467MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92308564014
1801468
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M6,R1100005190-110-1040 16 1010000728 mg/L 733000 624000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1801469MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92308129001
1801470
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M6,R110000-2650 90-110-1420 21 1010000786 mg/L 521000 644000
REPORT OF LABORATORY ANALYSIS
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Page 47 of 52
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The precision between the sample and sample duplicate exceeded laboratory control limits.D6
Analysis conducted outside the EPA method holding time.H1
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Matrix spike recovery was outside laboratory control limits due to matrix interferences.M3
Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
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Page 48 of 52
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92308661001 325043 3251833901-MW7 EPA 3510 EPA 8081
92308661002 325043 3251833901-MW5R EPA 3510 EPA 8081
92308661001 325039 3250923901-MW7 EPA 3010A EPA 6010
92308661002 325039 3250923901-MW5R EPA 3010A EPA 6010
92308661003 325039 3250923901-MW2 EPA 3010A EPA 6010
92308661004 325039 3250923901-MW3R EPA 3010A EPA 6010
92308661005 325039 3250923901-MW4R EPA 3010A EPA 6010
92308661006 325039 3250923901-MW6R EPA 3010A EPA 6010
92308661007 325039 3250923901-SW1 EPA 3010A EPA 6010
92308661008 325039 3250923901-SW2 EPA 3010A EPA 6010
92308661001 324995 3251283901-MW7 EPA 7470 EPA 7470
92308661002 324995 3251283901-MW5R EPA 7470 EPA 7470
92308661003 324995 3251283901-MW2 EPA 7470 EPA 7470
92308661004 325127 3252303901-MW3R EPA 7470 EPA 7470
92308661005 325127 3252303901-MW4R EPA 7470 EPA 7470
92308661006 325127 3252303901-MW6R EPA 7470 EPA 7470
92308661001 3249533901-MW7 EPA 8260
92308661002 3249513901-MW5R EPA 8260
92308661003 3249513901-MW2 EPA 8260
92308661004 3249513901-MW3R EPA 8260
92308661005 3249533901-MW4R EPA 8260
92308661006 3249513901-MW6R EPA 8260
92308661007 3249513901-SW1 EPA 8260
92308661008 3249533901-SW2 EPA 8260
92308661001 3252663901-MW7 SM 2320B
92308661002 3252663901-MW5R SM 2320B
92308661003 3252663901-MW2 SM 2320B
92308661004 3252663901-MW3R SM 2320B
92308661005 3252663901-MW4R SM 2320B
92308661006 3252663901-MW6R SM 2320B
92308661001 3254013901-MW7 SM 2540C
92308661002 3254013901-MW5R SM 2540C
92308661003 3252153901-MW2 SM 2540C
92308661004 3254013901-MW3R SM 2540C
92308661005 3254013901-MW4R SM 2540C
92308661006 3254013901-MW6R SM 2540C
92308661001 3254193901-MW7 SM 4500-S2D
92308661002 3254193901-MW5R SM 4500-S2D
92308661001 3253093901-MW7 EPA 300.0
92308661002 3253093901-MW5R EPA 300.0
92308661003 3253093901-MW2 EPA 300.0
92308661004 3253093901-MW3R EPA 300.0
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92308661
OXFORD COMPLIANCE UNIT 1
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92308661005 3253093901-MW4R EPA 300.0
92308661006 3253093901-MW6R EPA 300.0
92308661001 3251793901-MW7 SM 4500-Cl-E
92308661002 3251793901-MW5R SM 4500-Cl-E
92308661003 3251793901-MW2 SM 4500-Cl-E
92308661004 3251793901-MW3R SM 4500-Cl-E
92308661005 3251793901-MW4R SM 4500-Cl-E
92308661006 3251793901-MW6R SM 4500-Cl-E
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Page 50 of 52
Page 51 of 52
Page 52 of 52
#=CL#
August 23, 2016
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92308662
92308662
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
OXFORD UNIT 1 MNA
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on August 12, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc:Alex Everhart, Joyce Engineering-NC
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Page 1 of 18
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92308662
OXFORD UNIT 1 MNA
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
525 N 8th Street, Salina, KS 67401
A2LA Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA #: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92308662
OXFORD UNIT 1 MNA
Lab ID Sample ID Matrix Date Collected Date Received
92308662001 3901-MW7 Water 08/11/16 08:25 08/12/16 10:30
92308662002 3901-MW5R Water 08/11/16 09:00 08/12/16 10:30
92308662003 3901-NES2S Water 08/11/16 07:55 08/12/16 10:30
REPORT OF LABORATORY ANALYSIS
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92308662
OXFORD UNIT 1 MNA
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92308662001 3901-MW7 RSK 175 1 PASI-MDR1
EPA 353.2 1 PASI-ADMN
92308662002 3901-MW5R RSK 175 1 PASI-MDR1
EPA 353.2 1 PASI-ADMN
92308662003 3901-NES2S RSK 175 1 PASI-MDR1
EPA 8260 4 PASI-CGAW
SM 2320B 1 PASI-AKDF
EPA 300.0 1 PASI-AAES2
EPA 353.2 1 PASI-ADMN
SM 4500-Cl-E 1 PASI-AWRC
REPORT OF LABORATORY ANALYSIS
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Page 4 of 18
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92308662
OXFORD UNIT 1 MNA
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92308662001 3901-MW7
Methane 2.5J ug/L 08/16/16 16:5410.0RSK 175
Nitrogen, Nitrate 196J ug/L 08/12/16 17:5210000EPA 353.2
92308662002 3901-MW5R
Methane 67.6 ug/L 08/16/16 17:0210.0RSK 175
Nitrogen, Nitrate 21.1J ug/L 08/12/16 17:5310000EPA 353.2
92308662003 3901-NES2S
Methane 409 ug/L 08/16/16 17:1010.0RSK 175
Alkalinity, Total as CaCO3 51600 ug/L 08/16/16 23:435000SM 2320B
Sulfate 5330J ug/L 08/19/16 16:36250000EPA 300.0
Nitrogen, Nitrate 12.6J ug/L 08/12/16 17:4710000EPA 353.2
Chloride 7080 ug/L 08/22/16 18:111000SM 4500-Cl-E
REPORT OF LABORATORY ANALYSIS
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Page 5 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92308662
OXFORD UNIT 1 MNA
Sample:3901-MW7 Lab ID:92308662001 Collected:08/11/16 08:25 Received:08/12/16 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 2.5J ug/L 08/16/16 16:54 74-82-810.0 0.49 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 196J ug/L 08/12/16 17:521000010.0 1
REPORT OF LABORATORY ANALYSIS
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Page 6 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92308662
OXFORD UNIT 1 MNA
Sample:3901-MW5R Lab ID:92308662002 Collected:08/11/16 09:00 Received:08/12/16 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 67.6 ug/L 08/16/16 17:02 74-82-810.0 0.49 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 21.1J ug/L 08/12/16 17:531000010.0 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92308662
OXFORD UNIT 1 MNA
Sample:3901-NES2S Lab ID:92308662003 Collected:08/11/16 07:55 Received:08/12/16 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 409 ug/L 08/16/16 17:10 74-82-810.0 0.49 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Vinyl chloride ND ug/L 08/15/16 02:13 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)102 %08/15/16 02:13 460-00-470-130 1
1,2-Dichloroethane-d4 (S)96 %08/15/16 02:13 17060-07-070-130 1
Toluene-d8 (S)104 %08/15/16 02:13 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 51600 ug/L 08/16/16 23:43500010001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 5330J ug/L 08/19/16 16:36 14808-79-825000010001
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 12.6J ug/L 08/12/16 17:471000010.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 7080 ug/L 08/22/16 18:11 16887-00-610005001
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Page 8 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308662
OXFORD UNIT 1 MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
430566
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92308662001, 92308662002, 92308662003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2342391
Associated Lab Samples:92308662001, 92308662002, 92308662003
Matrix:Water
AnalyzedMDL
Methane ug/L 1.8J 10.0 08/16/16 13:350.49
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2342392LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2342393
Methane ug/L 56.760.7 93 85-1159758.6 3 20
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Page 9 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308662
OXFORD UNIT 1 MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
324953
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92308662003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1800448
Associated Lab Samples:92308662003
Matrix:Water
AnalyzedMDL
Vinyl chloride ug/L ND 1.0 08/15/16 01:220.62
1,2-Dichloroethane-d4 (S)%95 70-130 08/15/16 01:22
4-Bromofluorobenzene (S)%102 70-130 08/15/16 01:22
Toluene-d8 (S)%102 70-130 08/15/16 01:22
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1800449LABORATORY CONTROL SAMPLE:
LCSSpike
Vinyl chloride ug/L 53.150 106 58-137
1,2-Dichloroethane-d4 (S)%90 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1800451MATRIX SPIKE SAMPLE:
MSSpike
Result
92308664003
Vinyl chloride ug/L 24.320 122 70-130ND
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92308664002
1800450SAMPLE DUPLICATE:
Vinyl chloride ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%95 095
4-Bromofluorobenzene (S)%101 0101
Toluene-d8 (S)%102 1101
REPORT OF LABORATORY ANALYSIS
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Page 10 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308662
OXFORD UNIT 1 MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
325097
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92308662003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1801038
Associated Lab Samples:92308662003
Matrix:Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 08/16/16 17:591000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1801039LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4770050000 95 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1801040MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92308473003
1801041
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 101 80-120100 0 255000063.1 mg/L 114000 113000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1801042MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92308250024
1801043
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 98 80-12097 1 2550000ND4920048500
REPORT OF LABORATORY ANALYSIS
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Page 11 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308662
OXFORD UNIT 1 MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
325637
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples:92308662003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1804012
Associated Lab Samples:92308662003
Matrix:Water
AnalyzedMDL
Sulfate ug/L ND 250000 08/19/16 13:021000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1804013LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 19500J20000 97 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1804014MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92308879002
1804015
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L M12000011190-110111 0 102000014.2 mg/L 36400J 36400J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1804016MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92308924002
1804017
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L M620000-2120 90-110105 2 102000023200
mg/L
2280000
0J
2320000
0J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/23/2016 03:56 PM
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[phone]
Page 12 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308662
OXFORD UNIT 1 MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
324914
EPA 353.2
EPA 353.2
353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples:92308662001, 92308662002, 92308662003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1800296
Associated Lab Samples:92308662001, 92308662002, 92308662003
Matrix:Water
AnalyzedMDL
Nitrogen, Nitrate ug/L ND 10000 08/12/16 17:4310.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1800297LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Nitrate ug/L 2540J2500 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1800298MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92308662003
1800299
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Nitrate ug/L 2500 101 90-110101 1 10250012.6J 2530J 2540J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/23/2016 03:56 PM
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Page 13 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92308662
OXFORD UNIT 1 MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
325670
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples:92308662003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1804246
Associated Lab Samples:92308662003
Matrix:Water
AnalyzedMDL
Chloride ug/L ND 1000 08/22/16 17:50500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1804247LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 2070020000 104 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1804248MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92308886001
1804249
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L 10000 103 90-110103 0 101000012.4 mg/L 22700 22700
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1804250MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92308924003
1804251
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M61000017590-110108 1 1010000578 mg/L 595000 589000
REPORT OF LABORATORY ANALYSIS
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Page 14 of 18
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92308662
OXFORD UNIT 1 MNA
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - MinneapolisPASI-M
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6
REPORT OF LABORATORY ANALYSIS
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Page 15 of 18
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92308662
OXFORD UNIT 1 MNA
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92308662001 4305663901-MW7 RSK 175
92308662002 4305663901-MW5R RSK 175
92308662003 4305663901-NES2S RSK 175
92308662003 3249533901-NES2S EPA 8260
92308662003 3250973901-NES2S SM 2320B
92308662003 3256373901-NES2S EPA 300.0
92308662001 3249143901-MW7 EPA 353.2
92308662002 3249143901-MW5R EPA 353.2
92308662003 3249143901-NES2S EPA 353.2
92308662003 3256703901-NES2S SM 4500-Cl-E
REPORT OF LABORATORY ANALYSIS
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Page 16 of 18
Page 17 of 18
Page 18 of 18
#=CL#
August 25, 2016
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92308666
92308666
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
OXFORD DISSOLVED HYDROGEN
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on August 12, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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Page 1 of 16
#=CL#
August 25, 2016
Page 2
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92308666
cc:Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 2 of 16
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92308666
OXFORD DISSOLVED HYDROGEN
Lab ID Sample ID Matrix Date Collected Date Received
92308666001 3901-MW7 Water 08/11/16 08:25 08/12/16 10:30
92308666002 3901-MW5R Water 08/11/16 09:00 08/12/16 10:30
92308666003 3901-NES2S Water 08/11/16 07:55 08/12/16 10:30
REPORT OF LABORATORY ANALYSIS
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Page 3 of 16
Page 4 of 16
Page 5 of 16
Page 1 of 11 Page 6 of 16
Page 2 of 11 Page 7 of 16
Page 3 of 11 Page 8 of 16
Page 4 of 11 Page 9 of 16
Page 5 of 11 Page 10 of 16
Page 6 of 11 Page 11 of 16
Page 7 of 11 Page 12 of 16
Page 8 of 11 Page 13 of 16
Page 9 of 11 Page 14 of 16
Page 10 of 11 Page 15 of 16
Page 11 of 11 Page 16 of 16
#=CL#
September 19, 2016
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92312391
92312391
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
OXFORD SW RESAMPLE 660.1701.12
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on September 14, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc:Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
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[phone]
Page 1 of 13
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92312391
OXFORD SW RESAMPLE 660.1701.12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 2 of 13
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92312391
OXFORD SW RESAMPLE 660.1701.12
Lab ID Sample ID Matrix Date Collected Date Received
92312391001 3901-SW1 Water 09/13/16 11:03 09/14/16 10:17
92312391002 3901-FIELD BLANK Water 09/13/16 11:35 09/14/16 10:17
REPORT OF LABORATORY ANALYSIS
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Page 3 of 13
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92312391
OXFORD SW RESAMPLE 660.1701.12
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92312391001 3901-SW1 EPA 6010 5 PASI-ASH1
EPA 6010 4 PASI-ASH1
92312391002 3901-FIELD BLANK EPA 6010 5 PASI-ASH1
REPORT OF LABORATORY ANALYSIS
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Page 4 of 13
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92312391
OXFORD SW RESAMPLE 660.1701.12
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92312391001 3901-SW1
Chromium 13.8 ug/L 09/18/16 03:1910.0EPA 6010
Copper 9.3J ug/L 09/18/16 03:1910.0EPA 6010
Lead 4.1J ug/L 09/18/16 03:1910.0EPA 6010
Hardness, Total (SM 2340B)49900 ug/L 09/18/16 03:19672EPA 6010
Zinc 14.5 ug/L 09/18/16 03:19 B10.0EPA 6010
Copper, Dissolved 2.5J ug/L 09/17/16 17:195.0EPA 6010
Lead, Dissolved 2.6J ug/L 09/17/16 03:335.0EPA 6010
Zinc, Dissolved 5.9J ug/L 09/17/16 03:3310.0EPA 6010
92312391002 3901-FIELD BLANK
Copper 3.5J ug/L 09/18/16 03:3710.0EPA 6010
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 5 of 13
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92312391
OXFORD SW RESAMPLE 660.1701.12
Sample:3901-SW1 Lab ID:92312391001 Collected:09/13/16 11:03 Received:09/14/16 10:17 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Chromium 13.8 ug/L 09/18/16 03:19 7440-47-309/16/16 22:4510.0 2.5 1
Copper 9.3J ug/L 09/18/16 03:19 7440-50-809/16/16 22:4510.0 2.5 1
Lead 4.1J ug/L 09/18/16 03:19 7439-92-109/16/16 22:4510.0 2.5 1
Hardness, Total (SM 2340B)49900 ug/L 09/18/16 03:1909/16/16 22:456721
Zinc 14.5 ug/L 09/18/16 03:19 7440-66-6 B09/16/16 22:4510.0 5.0 1
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP, Lab Filtered
Chromium, Dissolved ND ug/L 09/17/16 03:33 7440-47-309/16/16 01:295.0 2.5 1
Copper, Dissolved 2.5J ug/L 09/17/16 17:19 7440-50-809/16/16 01:295.0 2.5 1
Lead, Dissolved 2.6J ug/L 09/17/16 03:33 7439-92-109/16/16 01:295.0 2.5 1
Zinc, Dissolved 5.9J ug/L 09/17/16 03:33 7440-66-609/16/16 01:2910.0 2.5 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/19/2016 04:25 PM
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Page 6 of 13
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92312391
OXFORD SW RESAMPLE 660.1701.12
Sample:3901-FIELD BLANK Lab ID:92312391002 Collected:09/13/16 11:35 Received:09/14/16 10:17 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Chromium ND ug/L 09/18/16 03:37 7440-47-309/16/16 22:4510.0 2.5 1
Copper 3.5J ug/L 09/18/16 03:37 7440-50-809/16/16 22:4510.0 2.5 1
Lead ND ug/L 09/18/16 03:37 7439-92-109/16/16 22:4510.0 2.5 1
Hardness, Total (SM 2340B)0.0000000
0010J
ug/L 09/18/16 03:3709/16/16 22:456721
Zinc ND ug/L 09/18/16 03:37 7440-66-609/16/16 22:4510.0 5.0 1
REPORT OF LABORATORY ANALYSIS
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Page 7 of 13
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92312391
OXFORD SW RESAMPLE 660.1701.12
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
328850
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92312391001, 92312391002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1822619
Associated Lab Samples:92312391001, 92312391002
Matrix:Water
AnalyzedMDL
Chromium ug/L ND 10.0 09/18/16 03:132.5
Copper ug/L ND 10.0 09/18/16 03:132.5
Hardness, Total (SM 2340B)ug/L 0.0000000001 672 09/18/16 03:13
Lead ug/L ND 10.0 09/18/16 03:132.5
Zinc ug/L 7.0J 10.0 09/18/16 03:135.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1822620LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium ug/L 487500 97 80-120
Copper ug/L 502500 100 80-120
Hardness, Total (SM 2340B)ug/L 32900
Lead ug/L 487500 97 80-120
Zinc ug/L 495500 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1822621MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92312391001
1822622
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium ug/L 500 96 75-12597 0 2550013.8 496 497
Copper ug/L 500 103 75-125102 0 255009.3J 522 522
Hardness, Total (SM 2340B)ug/L 1499008150082400
Lead ug/L 500 93 75-12593 0 255004.1J 469 469
Zinc ug/L 500 96 75-12595 1 2550014.5 493 488
REPORT OF LABORATORY ANALYSIS
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Page 8 of 13
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92312391
OXFORD SW RESAMPLE 660.1701.12
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
328799
EPA 3010
EPA 6010
6010 MET Filtered Diss.
Associated Lab Samples:92312391001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1822451
Associated Lab Samples:92312391001
Matrix:Water
AnalyzedMDL
Chromium, Dissolved ug/L ND 5.0 09/17/16 03:272.5
Copper, Dissolved ug/L ND 5.0 09/17/16 17:132.5
Lead, Dissolved ug/L ND 5.0 09/17/16 03:272.5
Zinc, Dissolved ug/L ND 10.0 09/17/16 03:272.5
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1822452LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Dissolved ug/L 477500 95 80-120
Copper, Dissolved ug/L 525500 105 80-120
Lead, Dissolved ug/L 493500 99 80-120
Zinc, Dissolved ug/L 498500 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1822453MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92312391001
1822454
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Dissolved ug/L 500 90 75-12587 3 20500ND450439
Copper, Dissolved ug/L 500 95 75-12593 2 205002.5J 480 469
Lead, Dissolved ug/L 500 91 75-12589 2 205002.6J 458 450
Zinc, Dissolved ug/L 500 93 75-12591 1 205005.9J 469 463
REPORT OF LABORATORY ANALYSIS
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Page 9 of 13
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92312391
OXFORD SW RESAMPLE 660.1701.12
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
ANALYTE QUALIFIERS
Analyte was detected in the associated method blank.B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/19/2016 04:25 PM
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Page 10 of 13
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92312391
OXFORD SW RESAMPLE 660.1701.12
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92312391001 328850 3290393901-SW1 EPA 3010A EPA 6010
92312391002 328850 3290393901-FIELD BLANK EPA 3010A EPA 6010
92312391001 328799 3288253901-SW1 EPA 3010 EPA 6010
REPORT OF LABORATORY ANALYSIS
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Page 11 of 13
Page 12 of 13
Page 13 of 13

Appendix C

Historical Detected Inorganic Constituents in Compliance Wells

APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Inorganic Compounds
Antimony 14-Sep-94 ---30 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-94 ---30 ND ND ---ND ND ---ND ---ND ---ND ------
8-Feb-95 ---30.0 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 ---30.0 ND ND ---ND ND ---ND ---ND ---ND ------
17-Nov-95 ---30.0 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---30.0 ND ND ---ND ND ---ND ---ND ---ND ------
14-Nov-96 ---30.0 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 ---30.0 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---30.0 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---30.0 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---30.0 6 ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---30.0 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---30.0 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---30.0 32 ND ---ND ---ND ---ND ---68 ---ND ---
26-Oct-00 ---30.0 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---30 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---30 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---30 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---30.0 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---30.0 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---30.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---30.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---30.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---30.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---30.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---30.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---6.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
2-Jul-07 ---6.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
GWPS = 1.4 µg/L (10/23/07)19-Dec-07 ---6.0 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---6.0 ---ND#---ND ---ND ---ND ---ND ---ND ND
16-Dec-08 2.6 6.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 2.6 6.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 2.6 6.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
23-Jun-10 2.6 6.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
GWPS = 1 µg/L (08/01/10)14-Dec-10 2.6 6.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 3.8 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 3.8 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 3.8 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 3.8 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
Arsenic 14-Sep-94 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-94 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
8-Feb-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
17-Nov-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
14-Nov-96 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 ---10 ND 7.0 ---14.0 14.0 ---ND ---ND ---5.0 ------
2-Dec-97 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---10 ND ND ---ND 5.0 ---ND ---ND ---ND ------
16-Nov-98 ---10 ND ND ---12.0 8.0 ---ND ---ND ---6.0 ------
10-Sep-99 ---10 ND ND ---ND ---ND ---ND ---11.0 ---ND ---
16-Nov-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---10 ---4.4 J ---ND ---ND ---ND ---ND ---ND ND
12-Jul-07 ---10 ---ND ---4.9 J ---ND ---ND ---ND ---ND ND
NC 2L = 50 µg/L (10/23/07)19-Dec-07 ---10 ---------2.9 J ---ND ---ND ---ND ---ND ND
8-Jul-08 ---10.0 ---182#---3.7 J ---ND ---ND ---ND ---ND ND
16-Dec-08 2.7 11.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 2.7 10.0 ---9.7 J ---ND ---ND ---4.9 J ---ND ---2.9 J ND
15-Dec-09 2.7 10.0 ---ND ---3.2 J ---ND ---ND ---ND ---ND ND
NC 2L = 10 µg/L (2/5/10)23-Jun-10 2.7 10.0 ---5.9 J ---2.7 J ---ND ---5.2 J ---ND ---4.4 J ND
14-Dec-10 2.7 10.0 ---------ND ---ND ---4.4 J ---ND ---ND ND
21-Jun-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 2.5 10.0 ------ND 5.5 J ---2.9 J ---3.8 J ---ND ---ND ND
19-Aug-15 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 2.5 10.0 ------ND 3.5 J ---ND ---3.2 J ---ND ---3.7 J ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 1 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Barium 14-Sep-94 ---500 680 680 ---260 580 ---30,300 ---ND ---1,740 ------
2-Dec-94 ---500 ND ND ---ND ND ---540 ---ND ---ND ------
8-Feb-95 ---500 ND ND ---ND ND ---621 ---ND ---ND ------
2-Mar-95 ---500 ND ND ---ND 541 ---2,710 ---ND ---ND ------
17-Nov-95 ---500 ND ND ---ND ND ---2,440 ---ND ---ND ------
23-May-96 ---500 ND ND ---ND ND ---0 ---ND ---ND ------
14-Nov-96 ---500 2,500 510 ---600 480 ---1,700 ---39 ---21 ------
18-Jun-97 ---500 960 1,200 ---280 720 ---3,400 ---93 ---700 ------
2-Dec-97 ---500 1,100 410 ---150 510 ---4,300 ---68 ---260 ------
27-May-98 ---500 2,100 310 ---95 660 ---2,800 ---69 ---350 ------
16-Nov-98 ---500 5,000 3,200 ---4,800 7,600 ---10,000 ---100 ---5,900 ------
10-Sep-99 ---500 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---500 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---500 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---500 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---500 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---100 ---15.4 ---30.8 ---24.8 ---78.5 ---33.4 ---77.4 0.20 J
NC 2L = 2,000 µg/L (10/23/07)12-Jul-07 ---100 ---19.4 J ---13.8 J ---24.5 J ---82.5 J ---27.3 J ---76.2 J ND
19-Dec-07 ---100 ---------14.7 B ---20.1 B ---28.7 B ---27.2 B ---64.9 10.5
8-Jul-08 ---100 ---5360#---21.7 J ---19.6 J ---54.1 J ---35.3 J ---78.2 J 0.29 J
16-Dec-08 0.20 100 ---19.4 B ---11.2 B ---16.5 B ---27.0 B ---38.8 B ---66.7 J 10.7 J
8-Jul-09 0.20 100 ---213 ---11.9 B ---26.6 B ---74.6 B ---34.2 B ---78.4 B 17.6 J
15-Dec-09 0.20 100 ---12.6 B ---16.4 B ---18.8 B ---38.2 B ---39.8 B ---89.3 J 17.1 J
NC 2L = 700 µg/L (2/5/10)23-Jun-10 0.20 100 ---61.2 B ---12.0 B ---17.7 B ---107 B ---36.7 B ---74.2 B 27.3 J
14-Dec-10 0.20 100 ---------11.7 B ---26.8 B ---37.6 B ---46.1 B ---79.0 J 12.1 J
21-Jun-11 5.0 100 ------6.8 J 14.6 J ---18.6 J ---37.2 J ---41.7 J ---78.7 J ND
6-Dec-11 5.0 100 ------16.2 J 13.2 J ---27.8 J ---38.4 J ---43.3 J ---83.7 J ND
13-Jun-12 5.0 100 ------9.2 J 16.5 J ---20.4 J ---52.2 J ---39.0 J ---82.2 J ND
11-Dec-12 5.0 100 ------5.2 J 12.6 J ---17.2 J ---32.1 J ---47.3 J ---81.9 J ND
29-Apr-13 5.0 100 ------ND 14.7 J ---19.6 J ---37.6 J ---42.2 J ---81.8 J ND
6-Aug-13 5.0 100 ------ND 19.7 J ---18.7 J ---39.8 J ---43.1 J ---84.7 J ND
25-Feb-14 5.0 100 ------5.6 J 15.3 J ---52.7 J ---38.0 J ---48.0 J ---77.0 J ND
13-Aug-14 5.0 100 ------ND 19.0 J ---28.4 J ---37.7 J ---49.6 J ---92.6 J ND
12-Mar-15 2.5 100 ------12.4 J 13.3 J ---28.0 J ---38.6 J ---38.9 J ---93.1 J ND
19-Aug-15 2.5 100 ------4.9 J 17.5 J ---25.3 J ---36.2 J ---42.2 J ---90.5 J ND
18-Feb-16 2.5 100 ------4.4 J 12.1 J ---15.7 J ---36.4 J ---36.7 J ---98.2 J ND
11-Aug-16 2.5 100 ------3.9 J 22.4 J ---16.1 J ---42.1 J ---38.6 J ---102 ND
Beryllium 14-Sep-94 ---2 ND ND ---ND ND ---200 ---ND ---ND ------
2-Dec-94 ---2 2.0 ND ---ND 4.0 ---2.0 ---ND ---ND ------
8-Feb-95 ---2 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 ---2 ND ND ---ND 6.0 ---7.0 ---ND ---ND ------
17-Nov-95 ---2 ND ND ---ND 2.0 ---7.0 ---ND ---ND ------
23-May-96 ---2 ND ND ---ND ND ---ND ---ND ---ND ------
14-Nov-96 ---2 1.0 2.0 ---ND 2.0 ---2.0 ---ND ---ND ------
18-Jun-97 ---2 5.0 14.0 ---3.0 7.0 ---13.0 ---ND ---3.0 ------
2-Dec-97 ---2 1.0 2.0 ---ND 2.0 ---5.0 ---ND ---1.0 ------
27-May-98 ---2 7.0 4.0 ---2.0 8.0 ---10.0 ---ND ---3.0 ------
16-Nov-98 ---2 9.0 5.0 ---2.0 5.0 ---4.0 ---ND ---4.0 ------
10-Sep-99 ---2 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---2 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---2 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---2 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---2 ---ND ---ND ---ND ---ND ---ND ---4.0 ---
10-Jun-02 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
12-Jul-07 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
GWPS = 4 µg/L (10/23/07)19-Dec-07 ---1 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---1.0 ---65.2 ---0.14 J ---0.10 J ---ND ---ND ---ND ND
16-Dec-08 0.10 1.0 ---0.21 J ---ND ---ND ---ND ---0.18 J ---ND ND
8-Jul-09 0.10 1.0 ---4.9 ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 0.10 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
23-Jun-10 0.10 1.0 ---1.3 ---ND ---ND ---ND ---ND ---ND ND
GWPS = 4 µg/L (10/01/10)14-Dec-10 0.10 1.0 ---------ND ---{ND}---{ND}---{ND}---ND ND {0.15} J
21-Jun-11 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 2 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Cadmium 14-Sep-94 ---1 ND ND ---ND 2.0 ---4.0 ---ND ---1.0 ------
2-Dec-94 ---1 ND ND ---ND 1.0 ---ND ---ND ---ND ------
8-Feb-95 ---1 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 ---1 ND ND ---ND 1.0 ---1.0 ---ND ---ND ------
17-Nov-95 ---1 ND ND ---ND 1.0 ---ND ---ND ---ND ------
23-May-96 ---1 ND ND ---ND 1.0 ---ND ---ND ---ND ------
14-Nov-96 ---1 ND ND ---ND 1.0 ---ND ---ND ---ND ------
18-Jun-97 ---1 ND ND ---ND 2.0 ---1.0 ---ND ---3.0 ------
2-Dec-97 ---1 ND ND ---ND ND ---2.0 ---ND ---ND ------
27-May-98 ---1 ND ND ---ND 1.0 ---ND ---ND ---1.0 ------
16-Nov-98 ---1 2.0 ND ---ND 2.0 ---1.0 ---ND ---4.0 ------
10-Sep-99 ---1 ND ND ---ND ---1.0 ---ND ---ND ---ND ---
16-Nov-99 ---1 2.0 ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---1 ND ND ---ND ---ND ---ND ---ND ---1.0 ---
26-Oct-00 ---1 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---1 ---ND ---2.0 ---2.0 ---ND ---ND ---2.0 ---
10-Jun-02 ---1 ---ND ---ND ---3.0 ---ND ---ND ---3.0 ---
13-Jun-02 ---1 ---ND ---ND ---3.0 ---ND ---ND ---3.0 ---
19-Nov-02 ---1 ---4.0 ---3.0 ---2.0 ---ND ---1.0 ---ND ---
27-Jun-03 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---1 ---ND ---ND ---1.0 ---ND ---ND ---ND ND
29-Dec-04 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---1 ---0.90 J ---ND ---ND ---ND ---ND ---ND ND
12-Jul-07 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 1.75 µg/L (10/23/07)19-Dec-07 ---1 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---1.0 ---213#---ND ---ND ---ND ---ND ---ND ND
16-Dec-08 0.50 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 0.50 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 0.50 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
23-Jun-10 0.50 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 0.50 1.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
Chromium 14-Sep-94 ---10 74.0 74.0 ---91.0 340 ---457 ---ND ---177 ------
2-Dec-94 ---10 93.0 ND ---88.0 106 ---18.0 ---ND ---24.0 ------
8-Feb-95 ---10 ND 48.0 ---56.0 87.0 ---15.0 ---ND ---19.0 ------
2-Mar-95 ---10 ND 41.0 ---66.0 313 ---79.0 ---ND ---10 ------
17-Nov-95 ---10 130.0 11.0 ---53.0 92.0 ---79.0 ---ND ---ND ------
23-May-96 ---10 71.0 ND ---34.0 51.0 ---11.0 ---ND ---ND ------
14-Nov-96 ---10 3.0 6.0 ---8.0 11.0 ---4.0 ---ND ---8.0 ------
18-Jun-97 ---10 470 340 ---100 270 ---100 ---10.0 ---83.0 ------
2-Dec-97 ---10 17.0 8.0 ---14.0 ND ---18.0 ---5.0 ---26.0 ------
27-May-98 ---10 470 150 ---31.0 190 ---69.0 ---6.0 ---40.0 ------
16-Nov-98 ---10 1000 220 ---130 190 ---44.0 ---4.0 ---260 ------
10-Sep-99 ---10 23.0 ND ---ND ---40.0 ---ND ---ND ---23.0 ---
16-Nov-99 ---10 28.0 ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---10 16.0 ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---10 ---ND ---ND ---13.0 ---ND ---ND ---ND ---
27-Oct-01 ---10 ---ND ---16.0 ---56.0 ---10 ---ND ---ND ---
10-Jun-02 ---10 ---ND ---ND ---13.0 ---ND ---ND ---ND ---
13-Jun-02 ---10 ---ND ---ND ---17.0 ---ND ---ND ---ND ---
19-Nov-02 ---10 ---12.0 ---12.0 ---ND ---ND ---ND ---ND ---
27-Jun-03 ---10 ---ND ---13.0 ---ND ---ND ---37.0 ---ND ---
30-Dec-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---10 ---ND ---ND ---67.0 ---ND ---ND ---ND ND
28-Dec-06 ---10 ---2.8 J ---8.9 J ---ND ---ND ---ND ---ND ND
12-Jul-07 ---10 ---3.3 J ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 50 µg/L (10/23/07)19-Dec-07 ---10 ---------2.4 J ---2.5 J ---ND ---2.4 J ---ND ND
8-Jul-08 ---10.0 ---488#---8.0 J ---2.8 J ---ND ---1.8 J ---ND ND
6-Dec-08 0.40 10.0 ---1.5 J ---2.0 J ---3.2 J ---ND ---1.9 J ---ND ND
8-Jul-09 0.40 10.0 ---22.1 ---3.3 J ---7.2 J ---ND ---0.86 J ---ND ND
15-Dec-09 0.40 10.0 ---0.60 J ---4.6 J ---3.6 J ---ND ---0.64 J ---ND ND
NC 2L = 10 µg/L (2/5/10)23-Jun-10 0.40 10.0 ---12.0 ---4.1 J ---2.6 B ---0.90 B ---1.3 B ---1.1 B 0.71 J
Resample >12-Aug-10 0.40 10.0 ---87.8#J ------------------------------ND
14-Dec-10 0.40 10.0 ---------2.8 J ---9.1 J ---1.0 J ---1.2 J ---0.43 J ND
21-Jun-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 10.0 ------ND ND ---11.6 ---ND ---ND ---ND ND
Resample >25-Jan-12 5.0 10.0 ---------------6.1 J ------------------ND
13-Jun-12 5.0 10.0 ------ND 5.1 J ---7.5 J ---ND ---ND ---ND ND
11-Dec-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 5.0 10.0 ------ND 7.4 J ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 10.0 ------ND ND ---19.6 ---ND ---ND ---ND ND
13-Aug-14 5.0 10.0 ------ND 6.1 J ---6.6 J ---ND ---ND ---ND ND
12-Mar-15 2.5 10.0 ------ND 3.3 J ---10.6 ---ND ---ND ---ND ND
19-Aug-15 2.5 10.0 ------ND 5.9 J ---7.5 J ---ND ---ND ---ND ND
18-Feb-16 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 2.5 10.0 ------3.4 J 11 ---3.1 J ---2.7 J ---ND ---ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 3 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Cobalt 14-Sep-94 ---10 160 160 ---ND 250 ---2810 ---ND ---ND ------
2-Dec-94 ---10 47.0 ND ---53.0 133 ---31.0 ---ND ---ND ------
8-Feb-95 ---10 ND 45.0 ---ND 158 ---42.0 ---ND ---23.0 ------
2-Mar-95 ---10 ND 35.0 ---22.0 258 ---89.0 ---ND ---24.0 ------
17-Nov-95 ---10 58.0 13.0 ---31.0 86.0 ---76.0 ---ND ---15.0 ------
23-May-96 ---10 29.0 ND ---19.0 88.0 ---34.0 ---ND ---16.0 ------
14-Nov-96 ---10 12.0 93.0 ---55.0 120 ---90.0 ---2.0 ---16.0 ------
18-Jun-97 ---10 200 430 ---52.0 520 ---550 ---4.0 ---28.0 ------
2-Dec-97 ---10 7.0 34.0 ---16.0 99.0 ---240 ---6.0 ---14.0 ------
27-May-98 ---10 150 73.0 ---13.0 180 ---350 ---4.0 ---18.0 ------
16-Nov-98 ---10 380 120 ---54.0 100 ---440 ---12.0 ---45.0 ------
10-Sep-99 ---10 11.0 ND ---ND ---32.0 ---ND ---ND ---ND ---
16-Nov-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---10 10.0 ND ---15.0 ---11.0 ---ND ---ND ---ND ---
18-Apr-01 ---10 ---17.0 ---ND ---21.0 ---ND ---ND ---ND ---
27-Oct-01 ---10 ---ND ---ND ---28.0 ---ND ---ND ---ND ---
10-Jun-02 ---10 ---ND ---11.0 ---15.0 ---ND ---ND ---ND ---
13-Jun-02 ---10 ---ND ---11.0 ---15.0 ---ND ---ND ---ND ---
19-Nov-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---10 ---ND ---12.0 ---ND ---ND ---ND ---ND ---
30-Dec-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---10 ---ND ---12.0 ---ND ---ND ---ND ---ND ND
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---10 ---ND ---11.0 ---ND ---ND ---ND ---ND ND
28-Jun-06 ---10 ---ND ---ND ---21.3 ---ND ---ND ---ND ND
28-Dec-06 ---10 ---2.1 J ---16.4 ---ND ---ND ---ND ---ND ND
12-Jul-07 ---10 ---ND ---11.2 ---ND ---ND ---ND ---ND ND
GWPS = 70 µg/L (10/23/07)19-Dec-07 ---10 ---------17.0 ---4.6 B ---1.1 B ---1.4 B ---ND 1.6 J
8-Jul-08 ---10.0 ---436#---15.0 B ---4.2 B ---3.1 B ---5.0 B ---6.1 B 6.2 J
16-Dec-08 0.60 10.0 ---2.5 B ---11.0 ---3.2 B ---1.4 B ---3.1 B ---2.5 B 2.4 J
8-Jul-09 0.60 10.0 ---8.1 J ---10.6 ---ND ---ND ---ND ---ND ND
15-Dec-09 0.60 10.0 ---ND ---8.8 J ---ND ---ND ---ND ---ND ND
23-Jun-10 0.60 10.0 ---3.9 J ---11.8 ---ND ---ND ---ND ---ND ND
Resample >12-Aug-10 0.60 10.0 ------------------------------------ND
GWPS = 1 µg/L (10/01/10)14-Dec-10 0.60 10.0 ---------10.9 ---3.7 B ---ND ---3.1 B ---0.71 B 1.6 J
21-Jun-11 5.0 10.0 ------ND 11.6 ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 10.0 ------5.0 J 9.3 J ---ND ---ND ---ND ---ND ND
13-Jun-12 5.0 10.0 ------ND 10.7 ---ND ---ND ---ND ---ND ND
11-Dec-12 5.0 10.0 ------ND 10.1 ---ND ---ND ---ND ---ND ND
29-Apr-13 5.0 10.0 ------ND 13.0 ---ND ---ND ---ND ---5.1 J ND
6-Aug-13 5.0 10.0 ------ND 20.5 ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 10.0 ------ND 13.9 ---11.4 ---ND ---ND ---ND ND
13-Aug-14 5.0 10.0 ------ND 9.5 J ---ND ---ND ---ND ---ND ND
12-Mar-15 2.5 10.0 ------ND 8.0 J ---ND ---ND ---ND ---ND ND
19-Aug-15 2.5 10.0 ------ND 11.8 ---ND ---ND ---ND ---ND ND
18-Feb-16 2.5 10.0 ------ND 7.5 J ---ND ---ND ---ND ---ND ND
11-Aug-16 2.5 10.0 ------ND 12.7 ---ND ---ND ---ND ---ND ND
Copper 14-Sep-94 ---200 260 260 ---130 340 ---4780 ---ND ---ND ------
2-Dec-94 ---200 ND ND ---ND 237 ---ND ---ND ---ND ------
8-Feb-95 ---200 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 ---200 ND ND ---ND 270 ---545 ---ND ---ND ------
17-Nov-95 ---200 ND ND ---ND ND ---456 ---ND ---ND ------
23-May-96 ---200 ND ND ---ND ND ---ND ---200 ---ND ------
14-Nov-96 ---200 10.0 31.0 ---54.0 17.0 ---60.0 ---12.0 ---15.0 ------
18-Jun-97 ---200 96.0 340 ---97.0 310 ---660 ---170 ---45.0 ------
2-Dec-97 ---200 10.0 13.0 ---24.0 26 ---210 ---130 ---17.0 ------
27-May-98 ---200 84.0 100 ---26.0 300 ---400 ---91.0 ---28.0 ------
16-Nov-98 ---200 280 320 ---150 290 ---400 ---320 ---80.0 ------
10-Sep-99 ---200 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---200 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---200 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---200 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---200 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---10 ---1.7 B ---3.5 J ---1.7 B ---2.5 B ---0.90 B ---ND 0.60 J
12-Jul-07 ---10 ---ND ---ND ---2.0 J ---ND ---ND ---ND ND
NC 2L = 1,000 µg/L (10/23/07)19-Dec-07 ---10 ---------4.6 B ---3.8 B ---0.56 B ---1.9 B ---0.58 B 10.5 B
8-Jul-08 ---10.0 ---828#---9.3 J ---1.6 J ---ND ---ND ---0.75 J ND
16-Dec-08 0.30 10.0 ---2.0 J ---2.1 J ---2.3 J ---ND ---6.9 J ---ND ND
8-Jul-09 0.30 10.0 ---32.7 ---1.6 J ---3.3 J ---ND ---ND ---ND ND
15-Dec-09 0.30 10.0 ---0.79 J ---2.9 J ---2.7 J ---ND ---2.1 J ---ND ND
23-Jun-10 0.30 10.0 ---23.2 ---2.0 J ---1.1 J ---ND ---0.86 J ---ND ND
Resample >12-Aug-10 0.30 10.0 ------------------------------------ND
14-Dec-10 0.30 10.0 ---------1.8 B ---8.1 J ---0.39 B ---5.9 J ---ND 0.49 J
21-Jun-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 10.0 ------15.5 ND ---10.0 ---ND ---ND ---ND ND
13-Jun-12 5.0 10.0 ------ND ND ---5.6 J ---ND ---ND ---ND ND
11-Dec-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 5.0 10.0 ------ND 6.6 J ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 10.0 ------ND ND ---14.7 ---ND ---6.4 J ---ND ND
13-Aug-14 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 2.5 10.0 ------ND ND ---7.6 J ---ND ---ND ---ND ND
19-Aug-15 2.5 10.0 ------ND 5.0 J ---6.8 J ---ND ---ND ---ND ND
18-Feb-16 2.5 10.0 ------ND ND ---3.6 J ---ND ---ND ---ND ND
11-Aug-16 2.5 10.0 ------ND 7.8 J ---ND ---ND ---ND ---ND ND
Iron 23-Jun-10 14.0 300 ---11800 ---4150 ---1040 ---102 J ---413 ---776 ND
NC 2L = 300 µg/L (2/5/10) Resample >12-Aug-10 140 3000 ---123,000 ------------------------------ND
14-Dec-10 14 300 ---------3210 ---3880 ---141 J ---877 ---1100 ND
21-Jun-11 50.0 300 ------2190 6030 ---667 ---114 J ---981 ---1020 ND
6-Dec-11 50.0 300 ------8610 2680 ---5420 ---86.1 J ---287 J ---1040 ND
13-Jun-12 50.0 300 ------1770 5610 ---3280 ---63.4 J ---698 ---1680 ND
11-Dec-12 50.0 300 ------1680 4020 ---1260 ---ND ---545 ---981 ND
29-Apr-13 50.0 300 ------414 3500 ---1130 ---112 J ---635 ---1750 ND
6-Aug-13 50.0 300 ------397 8970 ---307 ---ND ---378 ---2130 ND
25-Feb-14 50.0 300 ------1040 7060 ---9750 ---102 J ---2030 ---1710 ND
13-Aug-14 50.0 300 ------209 J 5380 ---3030 ---107 J ---904 ---2140 ND
12-Mar-15 25.0 300 ------269 J 3680 ---6040 ---40.8 J ---262 J ---2650 ND
19-Aug-15 25.0 300 ------156 J 7250 ---3780 ---34.9 J ---58.0 J ---1460 ND
18-Feb-16 25.0 300 ------243 J 792 ---270 J ---43.0 J ---86.3 J ---1500 ND
11-Aug-16 25.0 300 ------292 J 10400 ---839 ---104.0 J ---ND ---2090 ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 4 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Lead 14-Sep-94 ---10 31.0 31.0 ---230 23.0 ---355 ---ND ---190 ------
2-Dec-94 ---10 17.0 ND ---26.0 30.0 ---11.0 ---ND ---31.0 ------
8-Feb-95 ---10 ND 13.0 ---23.0 10.0 ---19.0 ---ND ---15.0 ------
2-Mar-95 ---10 ND 11.0 ---14.0 27.0 ---47.0 ---ND ---ND ------
17-Nov-95 ---10 ND ND ---ND 13.0 ---51.0 ---ND ---ND ------
23-May-96 ---10 ND ND ---10.0 ND ---ND ---ND ---ND ------
14-Nov-96 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 ---10 33.0 69.0 ---21.0 40.0 ---78.0 ---8 ---70.0 ------
2-Dec-97 ---10 8.0 8.0 ---20.0 14.0 ---21.0 ---11 ---24.0 ------
27-May-98 ---10 27.0 18.0 ---23.0 31.0 ---32.0 ---ND ---32.0 ------
16-Nov-98 ---10 43.0 36.0 ---33.0 34.0 ---32.0 ---ND ---110 ------
10-Sep-99 ---10 ND 18.0 ---ND ---14.0 ---ND ---ND ---ND ---
16-Nov-99 ---10 11.0 ND ---ND ---ND ---ND ---11.0 ---ND ---
10-May-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---10 ---ND ---28.0 ---15.0 ---ND ---18.0 ---29.0 ---
10-Jun-02 ---10 ---ND ---13.0 ---ND ---ND ---ND ---ND ---
13-Jun-02 ---10 ---ND ---13.0 ---ND ---ND ---ND ---ND ---
19-Nov-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---10 ---ND ---ND ---ND ---ND ---10.0 ---ND ---
30-Dec-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---10 ---ND ---2.0 J ---ND ---ND ---ND ---ND ND
12-Jul-07 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 15 µg/L (10/23/07)19-Dec-07 ---10 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---10.0 ---78#---ND ---ND ---ND ---ND ---ND ND
16-Dec-08 4.0 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 4.0 10.0 ---22.5 ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 4.0 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
23-Jun-10 4.0 10.0 ---6.7 J ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 4.0 10.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 2.5 10.0 ------ND 2.9 J ---ND ---ND ---ND ---ND ND
18-Feb-16 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 2.5 10.0 ------ND 2.7 J ---ND ---ND ---ND ---ND ND
Mercury 17-Nov-95 ---0.5 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---0.5 ND ND ---ND ND ---ND ---ND ---ND ------
23-Mar-98 ---0.5 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---0.5 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---0.5 ND ND ---ND 1.0 ---ND ---ND ---ND ------
10-Sep-99 ---0.5 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---0.5 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---0.5 ---------ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---0.5 ---------ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---0.5 ---------ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---------------------------------------------
10-Jun-02 ---0.5 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---0.5 ---------ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---------------------------------------------
27-Jun-03 ---1.5 ---ND ---ND ---ND ---ND ---0.78 ---ND ---
30-Dec-03 ---0.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---0.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---0.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---0.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---0.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---2 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---0.2 ---ND ---ND ---ND ---ND ---ND ---ND ND
12-Jul-07 ---0.2 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 1.05 µg/L (10/23/07)19-Dec-07 ---0.2 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---0.20 ---0.34#---ND ---ND ---ND ---ND ---ND ND
16-Dec-08 0.090 0.20 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 0.070 0.20 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 0.070 0.20 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 1 µg/L (2/5/10)23-Jun-10 0.070 0.20 ---ND ---ND ---ND ---0.094 J ---ND ---ND ND
14-Dec-10 0.070 0.20 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 0.10 0.20 ------ND 0.11 J ---ND ---ND ---ND ---ND ND
Manganese 23-Jun-10 0.30 50.0 ---88.3 ---217 ---44.0 B ---513 ---127 ---1470 9.0 J
NC 2L = 50 µg/L (2/5/10) Resample>12-Aug-10 3.00 500 ---972 ------------------------------0.35 J
14-Dec-10 0.30 50.0 ---------208 ---139 ---730 ---194 ---1260 1.1 J
21-Jun-11 5.0 50.0 ------38.2 J 245 ---36.9 J ---833 ---130 ---1400 ND
6-Dec-11 5.0 50.0 ------198 216 ---170 ---808 ---187 ---1350 ND
13-Jun-12 5.0 50.0 ------41.7 J 226 ---95.8 ---760 ---125 ---1360 ND
11-Dec-12 5.0 50.0 ------33.8 J 230 ---28.9 J ---770 ---279 ---1340 ND
29-Apr-13 5.0 50.0 ------14.2 J 193 ---47.3 J ---724 ---139 ---1220 ND
6-Aug-13 5.0 50.0 ------10.3 J 273 ---38.5 J ---749 ---135 ---1220 ND
25-Feb-14 5.0 50.0 ------29.8 J 222 ---340 ---897 ---154 ---862 ND
13-Aug-14 5.0 50.0 ------5.8 J 209 ---108 ---1230 ---125 ---1450 ND
12-Mar-15 2.5 50.0 ------6.0 J 210 ---200 ---676 ---104 ---1370 ND
19-Aug-15 2.5 50.0 ------4.3 J 288 ---199 ---802 ---103 ---1490 ND
18-Feb-16 2.5 50.0 ------5.4 J 201 ---72.7 ---981 ---82.4 ---1620 ND
11-Aug-16 2.5 50.0 ------5.9 J 336 ---122 ---1550 ---100.0 ---1770 ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 5 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Nickel 14-Sep-94 ---50 180 18.0 ---ND 250 ---680 ---ND ---ND ------
2-Dec-94 ---50 118 ND ---119 164 ---ND ---ND ---ND ------
8-Feb-95 ---50 ND ND ---ND 84.0 ---ND ---ND ---ND ------
2-Mar-95 ---50 ND ND ---ND 204 ---75.0 ---ND ---ND ------
17-Nov-95 ---50 71.0 ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---50 69.0 ND ---ND 51 ---ND ---ND ---ND ------
14-Nov-96 ---50 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 ---50 330 280 ---65.0 200 ---ND ---ND ---ND ------
2-Dec-97 ---50 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---50 310 88.0 ---ND 170 ---61 ---ND ---ND ------
16-Nov-98 ---50 840 270 ---ND ND ---ND ---ND ---150 ------
10-Sep-99 ---50 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---50 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---50 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---50 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---50 ---ND ---ND ---59 ---ND ---ND ---ND ---
10-Jun-02 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---50 ---4.7 J ---7.0 J ---7.2 J ---2.4 J ---ND ---ND ND
12-Jul-07 ---50 ---4.6 J ---3.2 J ---2.5 J ---ND ---ND ---ND ND
NC 2L = 100 µg/L (10/23/07)19-Dec-07 ---50 ---------3.2 J ---5.0 ---ND ---2.3 J ---ND ND
8-Jul-08 ---50.0 ---122 J ---5.3 J ---2.3 J ---ND ---1.7 J ---ND ND
16-Dec-08 1.7 50.0 ---ND ---2.3 B ---2.5 B ---ND ---2.7 B ---ND 2.4 J
8-Jul-09 1.7 50.0 ---38.6 J ---3.2 J ---6.0 J ---ND ---1.8 J ---ND ND
15-Dec-09 1.7 50.0 ---ND ---3.6 B ---4.4 B ---2.1 B ---2.6 B ---2.0 B 3.0 J
23-Jun-10 1.7 50.0 ---10 J ---2.3 J ---ND ---ND ---ND ---ND ND
14-Dec-10 1.7 50.0 ---------1.8 B ---2.6 B ---ND ---ND ---ND 2.7 J
21-Jun-11 5.0 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 50.0 ------ND ND ---6.4 J ---ND ---ND ---ND ND
13-Jun-12 5.0 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 5.0 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 5.0 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 5.0 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 50.0 ------ND ND ---11.3 J ---ND ---ND ---ND ND
13-Aug-14 5.0 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 2.5 50.0 ------ND ND ---11.7 J ---ND ---ND ---ND ND
19-Aug-15 2.5 50.0 ------ND 3.7 J ---8.9 J ---ND ---ND ---ND ND
18-Feb-16 2.5 50.0 ------ND ND ---3.2 J ---ND ---ND ---ND ND
11-Aug-16 2.5 50.0 ------ND 6.4 J ---6.7 J ---ND ---ND ---22.8 J ND
Selenium 14-Sep-94 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-94 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
8-Feb-95 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
17-Nov-95 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
14-Nov-96 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---20 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---20 ND 24.0 ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---20 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---20 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---20 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---20 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
12-Jul-07 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 50 µg/L (10/23/07)19-Dec-07 ---10 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---10.0 ---ND#---ND ---ND ---ND ---ND ---ND ND
16-Dec-08 3.8 10.0 ---4.2 B ---ND ---ND ---ND ---ND ---ND 4.9 J
8-Jul-09 3.8 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 3.8 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 20 µg/L (2/5/10)23-Jun-10 3.8 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 3.8 10.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 5.0 10.0 ------ND ND ---ND ---ND ---ND ---6.0 J ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 6 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Silver 14-Sep-94 ---10 ND ND ---ND ND ---50.0 ---ND ---ND ------
2-Dec-94 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
8-Feb-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
17-Nov-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
14-Nov-96 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---10 ND ND ---ND ND ---ND ---ND ---4.0 ------
27-May-98 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
12-Jul-07 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 17.5 µg/L (10/23/07)19-Dec-07 ---10 ---------ND ---ND ---0.26 J ---ND ---ND ND
8-Jul-08 ---10.0 ---14.6#J ---0.27 J ---0.41 J ---0.83 J ---0.39 J ---0.56 J ND
16-Dec-08 0.10 10.0 ---ND ---ND ---0.25 J ---0.53 J ---0.40 J ---0.46 J ND
8-Jul-09 0.10 10.0 ---0.16 J ---ND ---ND ---0.17 J ---ND ---ND ND
15-Dec-09 0.10 10.0 ---ND ---ND ---0.32 J ---0.64 J ---0.53 J ---0.53 J ND
NC 2L = 20 µg/L (2/5/10)23-Jun-10 0.10 10.0 ---ND ---ND ---ND ---0.13 J ---0.13 J ---ND ND
14-Dec-10 0.10 10.0 ---------ND ---{0.24}B ---{0.58}B ---{0.34}B ---0.17 B {0.25 J}
0.19 J
21-Jun-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
Thallium 14-Sep-94 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-94 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
8-Feb-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
17-Nov-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
14-Nov-96 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 ---10 ND ND ---ND ND ---5.0 ---ND ---ND ------
2-Dec-97 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---0.01 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---6 ---ND ---ND ---ND ---ND ---ND ---ND ND
12-Jul-07 ---5.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
GWPS = 0.28 µg/L (10/23/07)19-Dec-07 ---5.5 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---5.5 ---31.7#---4.5 J ---ND ---ND ---ND ---ND ND
16-Dec-08 3.0 5.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 3.0 5.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 3.0 5.5 ---ND ---ND ---ND ---ND ---3.8 J ---ND ND
23-Jun-10 3.0 5.5 ---6.6 ---ND ---ND ---ND ---ND ---ND ND
Resample >12-Aug-10 30.0 55.0 ---ND#------------------------------ND
GWPS = 0.2 µg/L (10/01/10)14-Dec-10 3.0 5.5 ---------ND ---ND ---8.1 ---ND ---ND ND
21-Jun-11 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 5.0 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 5.0 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 5.0 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 5.0 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
Tin 8-Jul-08 ---100 ---232#J ---1.9 J ---3.0 J ---3.0 J ---3.6 J ---3.6 J ND
16-Dec-08 1.8 100 ------------------------------------ND
8-Jul-09 1.8 100 ---7.4 J ---ND ---ND ---1.8 J ---ND ---ND ND
15-Dec-09 ---------------------------------------------
GWPS = 2100 µg/L (2/5/10)23-Jun-10 1.8 100 ---2.9 J ---ND ---ND ---1.9 J ---2.5 J ---3.3 J ND
GWPS = 2000 µg/L (10/01/10)14-Dec-10 ---------------------------------------------
21-Jun-11 5.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 100 ---------------------------------------
13-Jun-12 5.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 ---------------------------------------------
29-Apr-13 5.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 5.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 2.5 100 ------ND ------------------ND ------ND
18-Feb-16 2.5 100 ------ND ------------------ND ------ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 7 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Vanadium 14-Sep-94 ---40 580 580 ---390 540 ---12800 ---ND ---340 ------
2-Dec-94 ---40 107 ND ---233 316 ---201 ---ND ---ND ------
8-Feb-95 ---40 ND 81.0 ---132 162 ---190 ---ND ---ND ------
2-Mar-95 ---40 ND 62.0 ---173 468 ---1260 ---ND ---ND ------
17-Nov-95 ---40 100 ND ---84.0 120 ---984 ---ND ---ND ------
23-May-96 ---40 92.0 ND ---103 139 ---196 ---ND ---ND ------
14-Nov-96 ---40 16.0 10.0 ---140 280 ---320 ---10.0 ---22.0 ------
18-Jun-97 ---40 470 1600 ---310 600 ---1700 ---57.0 ---82.0 ------
2-Dec-97 ---40 32.0 15.0 ---52.0 120 ---970 ---22.0 ---27.0 ------
27-May-98 ---40 330 120 ---71.0 460 ---1000 ---34.0 ---41.0 ------
16-Nov-98 ---40 900 280 ---340 470 ---730 ---49.0 ---97.0 ------
10-Sep-99 ---40 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---40 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---40 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---40 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---40 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---40 ---ND ---67.0 ---53.0 ---ND ---63.0 ---ND ---
10-Jun-02 ---40 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---40 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---40 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---40 ---ND ---ND ---ND ---ND ---94.0 ---ND ---
30-Dec-03 ---40 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---40 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---40 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---40 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---40 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---40 ---ND ---ND ---71.1 ---ND ---ND ---ND ND
28-Dec-06 ---25 ---2.2 J ---28.4 ---ND ---ND ---1.8 J ---ND ND
12-Jul-07 ---25 ---3.7 J ---3.4 J ---2.2 J ---ND ---ND ---ND ND
GWPS = 3.5 µg/L (10/23/07)19-Dec-07 ---25 ---------7.6 ---3.2 J ---1.1 B ---0.82 B ---0.93 B 0.51 J
Resample >14-Feb-08 ---25 ---------7.2 ------------------------0.24 J
Filtered >14-Feb-08 ---25 ---------3.2 J ------------------------ND
8-Jul-08 ---25.0 ---772#---21.9 J ---2.2 J ---0.94 B ---0.78 B ---2.3 J 0.20 J
16-Dec-08 0.20 25.0 ---3.4 J ---4.9 J ---3.4 J ---0.84 B ---6.1 J ---0.47 B 0.76 J
8-Jul-09 0.20 25.0 ---39.6 ---10.6 J ---8.3 J ---1.7 B ---1.9 B ---1.4 B 1.3 J
15-Dec-09 0.20 25.0 ---1.2 B ---12.1 J ---3.8 J ---1.3 B ---2.3 B ---ND 0.53 J
23-Jun-10 0.20 25.0 ---18.7 J ---10.7 J ---2.0 J ---0.51 J ---1.2 J ---0.54 J ND
Resample >12-Aug-10 0.20 25.0 ------------------------------------0.33 J
GWPS = 0.3 µg/L (10/01/10)14-Dec-10 0.20 25.0 ---------7.3 J ---{8.0}J ---{1.2}B ---{4.0}J ---ND {0.57 J} 0.36 J
21-Jun-11 5.0 25.0 ------5.9 J 14.6 J ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 25.0 ------19.8 J 5.3 J ---10 J ---ND ---ND ---ND ND
13-Jun-12 5.0 25.0 ------5.2 J 13.0 J ---6.5 J ---ND ---ND ---ND ND
11-Dec-12 5.0 25.0 ------ND 7.4 J ---ND ---ND ---ND ---ND ND
29-Apr-13 5.0 25.0 ------ND 8.4 J ---ND ---ND ---ND ---ND ND
6-Aug-13 5.0 25.0 ------ND 27.6 ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 25.0 ------ND 18.6 J ---19.0 J ---ND ---7.0 J ---ND ND
13-Aug-14 5.0 25.0 ------ND 15.0 J ---7.2 J ---ND ---ND ---ND ND
12-Mar-15 2.5 25.0 ------ND 9.5 J ---14.8 J ---ND ---3.3 J ---ND ND
19-Aug-15 2.5 25.0 ------ND 19.2 J ---8.3 J ---ND ---ND ---ND ND
18-Feb-16 2.5 25.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 2.5 25.0 ------ND 25.2 ---ND ---ND ---ND ---ND ND
Zinc 14-Sep-94 ---50 680 680 ---400 910 ---17,400 ---ND ---640 ------
2-Dec-94 ---50 299 ND ---380 553 ---279 ---ND ---98.0 ------
8-Feb-95 ---50 ND 185 ---236 255 ---320 ---156 ---108 ------
2-Mar-95 ---50 ND 114 ---102 601 ---1,530 ---191 ---ND ------
17-Nov-95 ---50 309 67.0 ---154 199 ---1,300 ---59.0 ---ND ------
23-May-96 ---50 237 94.0 ---116 237 ---314 ---149 ---ND ------
14-Nov-96 ---50 240 180 ---140 120 ---140 ---15.0 ---48.0 ------
18-Jun-97 ---50 930 800 ---250 650 ---1,800 ---160 ---190 ------
2-Dec-97 ---50 140 150 ---110 120 ---510 ---150 ---130 ------
27-May-98 ---50 1,000 280 ---90.0 560 ---1,300 ---100 ---110 ------
16-Nov-98 ---50 4,300 2,500 ---3,600 5,600 ---7,000 ---230 ---3,900 ------
10-Sep-99 ---50 153 ND ---ND ---96.0 ---ND ---ND ---ND ---
16-Nov-99 ---50 140 119 ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---50 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---50 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---50 ---ND ---ND ---64.0 ---ND ---ND ---ND ---
27-Oct-01 ---50 ---23.0 ---55.0 ---136.0 ---ND ---32.0 ---ND ---
10-Jun-02 ---50 ---ND ---ND ---72.0 ---ND ---ND ---370 ---
13-Jun-02 ---50 ---ND ---ND ---72.0 ---ND ---ND ---370 ---
19-Nov-02 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---50 ---ND ---ND ---ND ---ND ---52.0 ---ND ---
30-Dec-03 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---50 ---ND ---ND ---126 ---ND ---ND ---ND ND
28-Dec-06 ---10 ---7.7 J ---14.0 ---7.8 J ---ND ---ND ---1.5 J ND
12-Jul-07 ---10 ---48.1 ---3.6 J ---6.5 J ---ND ---ND ---ND ND
NC 2L = 1,050 µg/L (10/23/07)19-Dec-07 ---10 ---------0.4 B ---ND ---4.5 B ---ND ---ND 87.9
8-Jul-08 ---10.0 ---4,540#---12.6 ---ND ---ND ---ND ---ND 1.2 J
16-Dec-08 0.40 10.0 ---9.6 J ---0.45 J ---3.8 J ---ND ---12.3 ---ND ND
8-Jul-09 0.40 10.0 ---169 ---0.67 J ---7.0 J ---ND ---ND ---ND 1.6 J
15-Dec-09 0.40 10.0 ---6.6 B ---5.5 B ---6.9 B ---ND ---1.9 B ---ND 7.7 J
NC 2L = 1,000 µg/L (2/5/10)23-Jun-10 0.40 10.0 ---55.2 ---2.2 J ---1.0 J ---ND ---ND ---ND ND
14-Dec-10 0.40 10.0 ---------16.3 B ---12.6 B ---ND ---ND ---2.6 B 6.7 J
21-Jun-11 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 10.0 10.0 ------21.8 B ND ---21.0 B ---ND ---ND ---ND 12.4
13-Jun-12 10.0 10.0 ------ND ND ---14.0 ---ND ---ND ---ND ND
11-Dec-12 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 10.0 10.0 ------ND ND ---31.9 ---ND ---ND ---ND ND
13-Aug-14 10.0 10.0 ------ND ND ---24.1 ---ND ---ND ---ND ND
12-Mar-15 5.0 10.0 ------9.2 B 11.5 B ---24.3 B ---6.8 B ---7.5 B ---7.1 B 6.1 J
19-Aug-15 5.0 10.0 ------ND 7.2 B ---16.3 B ---ND ---ND ---ND 11.5
18-Feb-16 5.0 10.0 ------14.8 ND ---ND ---6.6 J ---ND ---ND ND
11-Aug-16 5.0 10.0 ------ND 18.2 ---8.6 J ---ND ---ND ---ND ND
Alkalinity, Total as CaCO3 23-Jun-10 5,000 5,000 ---7,290 ---20,400 ---82,100 ---253,000 ---135,000 ------ND
NC 2L = NE µg/L (2/5/10)14-Dec-10 5,000 5,000 ---------17,600 ---99,800 ---291,000 ---169,000 ---178,000 ND
21-Jun-11 5,000 5,000 ------100,000 20,800 ---77,000 ---269,000 ---194,000 ---156,000 ND
6-Dec-11 5,000 5,000 ------98,700 10,500 ---81,900 ---274,000 ---164,000 ---151,000 ND
13-Jun-12 1,000 1,000 ------101,000 13,700 ---87,500 ---271,000 ---152,000 ---149,000 ND
11-Dec-12 1,000 5,000 ------100,000 16,500 ---98,300 ---284,000 ---147,000 ---152,000 ND
29-Apr-13 1,000 5,000 ------99,300 13,800 ---97,300 ---293,000 ---156,000 ---122,000 ND
6-Aug-13 1,000 5,000 ------102,000 14,300 ---99,100 ---148,000 ---86,800 ---159,000 ND
25-Feb-14 1,000 5,000 ------107,000 15,800 ---123,000 ---298,000 ---178,000 ---153,000 ND
13-Aug-14 1000 5000 ------103000 14300 ---93800 ---301000 ---187000 ---164000 ND
12-Mar-15 1000 5000 ------99700 14700 ---88300 ---306000 ---151000 ---164000 ND
19-Aug-15 1000 5000 ------102000 19600 ---88200 ---294000 ---180000 ---164000 ND
18-Feb-16 1000 5000 ------108000 4350 J ---89800 ---308000 ---141000 ---168000 ND
11-Aug-16 1000 5000 ------108000 24400 ---91800 ---304000 ---176000 ---173000 ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 8 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Chloride 23-Jun-10 5,000 5,000 ---7,950 ---ND ---37,400 ---40,000 ---39,700 ---97,900 ND
NC 2L = 250000 µg/L (2/5/10)14-Dec-10 5,000 5,000 ---------5,100 ---38,400 ---44,500 ---39,600 ---108,000 ND
21-Jun-11 5,000 5,000 ------8,600 ND ---35,800 ---45,300 ---41,400 ---106,000 ND
6-Dec-11 5,000 5,000 ------9,340 ND ---28,600 ---49,200 ---39,200 ---110,000 ND
13-Jun-12 1,000 1,000 ------9,410 4,540 ---29,400 ---49,300 ---46,400 ---109,000 ND
11-Dec-12 1,000 1,000 ------8,570 5,220 ---30,800 ---50,600 ---46,600 ---107,000 ND
29-Apr-13 1,000 1,000 ------9,550 4,120 ---30,000 ---49,800 ---22,300 ---122,000 ND
6-Aug-13 1,000 1,000 ------7,590 5,180 ---25,700 ---50,100 ---48,700 ---107,000 ND
25-Feb-14 1,000 1,000 ------9,140 5,510 ---33,200 ---60,300 ---57,400 ---120,000 ND
13-Aug-14 500 1,000 ------8,030 4,070 ---21,300 ---97,600 ---43,400 ---106,000 ND
12-Mar-15 500 1,000 ------8,840 4,350 ---20,700 ---51,700 ---42,600 ---121,000 ND
19-Aug-15 500 1,000 ------9,440 5,160 ---23,200 ---51,500 ---48,500 ---111,000 ND
18-Feb-16 500 1,000 ------17,200 4,600 ---20,600 ---69,500 ---49,700 ---153,000 ND
11-Aug-16 500 1,000 ------9,410 4,430 ---23,200 ---57,300 ---51,300 ---147,000 ND
Total Cyanide 8-Jul-08 ---10.0 ---------ND ---ND ---6.2 J ---ND ---ND ND
NC 2L = 70 µg/L (10/23/07)16-Dec-08 ---------------------------------------------
8-Jul-09 5.0 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 ---------ND ---------------------------------
23-Jun-10 5.0 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 ---------------------------------------------
13-Jun-12 5.0 10 ---------5.8 J ---6.2 J ---5.2 J ---------------
11-Dec-12 ---------------------------------------------
29-Apr-13 5.0 10 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 5.0 10 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ------------------------------------------ND
Sulfide 17-Nov-95 ---1,000 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---1,000 ND ND ---ND ND ---ND ---ND ---ND ------
23-Mar-98 ---1,000 ND ND ---1,000 ND ---ND ---1,200 ---1400 ------
27-May-98 ---1,000 ND ND ---1,000 ND ---ND ---ND ---ND ------
16-Nov-98 ---1,000 12,000 1,200 ---13,000 2,200 ---ND ---13,000 ---ND ------
10-Sep-99 ---1,000 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---1,000 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---1,000 ---------17,000 ---5,000 ---47,000 ---33,000 ---36,000 ---
26-Oct-00 ---1,000 ---------ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---1,000 ---------ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---1,000 ---------ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---1,000 ---------------------------------ND ---
30-Dec-03 ---1,000 ---------------------------------------
30-Jun-04 ---1,000 ---ND ---ND ---7 ---ND ---ND ---ND ---
29-Dec-04 ---1,000 ---------------------------------------
29-Jun-05 ---1,000 ---ND ---ND ---ND ---ND ---ND ---1,200 ND
29-Dec-05 ---1,000 ---1,200 B ---ND ---ND ---1,700 B ---ND ---ND 1,200
28-Jun-06 ---1,000 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---1,000 ---700 J ---ND ---500 J ---ND ---ND ---ND ND
12-Jul-07 ---1,000 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = NE µg/L (10/23/07)19-Dec-07 ---1,000 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---1,000 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 100 1,000 ---259 J ---ND ---150 J ---ND ---141 J ---ND ND
8-Jul-09 100 1,000 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 100 1,000 ---ND ---ND ---ND ---ND ---ND ---ND ND
23-Jun-10 100 1,000 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 100 1,000 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 100 1,000 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 100 1,000 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 100 1,000 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 100 1,000 ------ND ND ---ND ---ND ---117 J ---ND ND
29-Apr-13 100 1,000 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 100 1,000 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 100 1,000 ------ND ND ---141 J ---189 J ---ND ---ND ND
13-Aug-14 50 1,000 ------ND ------------------ND ------ND
12-Mar-15 100 1,000 ------ND ------------------ND ------ND
19-Aug-15 100 1,000 ------ND ------------------ND ------ND
18-Feb-16 100 1,000 ------ND ------------------ND ------ND
11-Aug-16 100 1,000 ------ND ------------------ND ------ND
Sulfate 23-Jun-10 ---5,000 ---5,160 ---14,800 ---7,180 ---9,140 ---ND ------ND
NC 2L = 250000 µg/L (2/5/10)14-Dec-10 ---5,000 ---------14,500 ---9,210 ---9,700 ---ND ---ND ND
21-Jun-11 ---5,000 ------24,400 11,400 ---7,490 ---7,740 ---ND ---ND ND
6-Dec-11 5,000 5,000 ------39,800 13,800 ---8,000 ---7,730 ---ND ---ND ND
13-Jun-12 2,000 250,000 ------25,400 J 13,700 J ---8,140 J ---8,400 J ---2,790 J ---3,040 J ND
11-Dec-12 2,000 250,000 ------28,000 J 14,800 J ---9,120 J ---10,100 J ---4,420 J ---2,900 J ND
29-Apr-13 2,000 250,000 ------26,100 J 12,300 J ---9,150 J ---17,100 J ---2,730 J ---3,200 J ND
6-Aug-13 2,000 250,000 ------25,300 J 7,370 J ---7,830 J ---11,700 J ---2,760 J ---3,320 J ND
25-Feb-14 2,000 250,000 ------28,900 J 11,200 J ---8,130 J ---9,550 J ---2,590 J ---4,620 J ND
13-Aug-14 1,000 250,000 ------31,900 J 9,370 J ---7,910 J ---11,600 J ---2,450 J ---2,780 J ND
12-Mar-15 1,000 250,000 ------32,600 J 12,100 J ---8,040 J ---8,340 J ---3,400 J ---3,330 J ND
19-Aug-15 10,000 250,000 ------42,900 J 10,200 J ---8,110 J ---10,400 J ---2,890 J ---3,210 J ND
18-Feb-16 2,000 500,000 ------39,300 J 11,200 J ---7,960 J ---10,300 J ---3,830 J ---3,310 J ND
11-Aug-16 5,000 1,250,000 ------112,000 J 8,500 J ---7,700 J ---10,300 J ---3,100 J ---3,140 J ND
Total Dissolved Solids, Dissolved 23-Jun-10 250,000 250,000 ---710,000 ---96,200 ---184,000 ---364,000 ---237,000 ---360,000 ND
NC 2L = 500,000 µg/L (2/5/10)14-Dec-10 25,000 25,000 ---------100,000 ---218,000 ---372,000 ---260,000 ---347,000 ND
21-Jun-11 5,000 5,000 ------170,000 89,000 ---194,000 ---374,000 ---238,000 ---378,000 ND
6-Dec-11 25,000 25,000 ------174,000 92,000 ---168,000 ---378,000 ---242,000 ---408,000 ND
13-Jun-12 25,000 25,000 ------189,000 98,000 ---184,000 ---390,000 ---253,000 ---402,000 ND
11-Dec-12 25,000 25,000 ------199,000 141,000 ---199,000 ---427,000 ---274,000 ---419,000 ND
29-Apr-13 25,000 25,000 ------170,000 114,000 ---183,000 ---416,000 ---276,000 ---466,000 ND
6-Aug-13 25,000 25,000 ------179,000 142,000 ---175,000 ---421,000 ---291,000 ---423,000 ND
25-Feb-14 25,000 25,000 ------173,000 109,000 ---206,000 ---405,000 ---281,000 ---421,000 ND
13-Aug-14 25,000 25,000 ------172,000 184,000 ---187,000 ---446,000 ---319,000 ---504,000 ND
12-Mar-15 25,000 25,000 ------229,000 113,000 ---184,000 ---430,000 ---256,000 ---470,000 ND
19-Aug-15 25,000 25,000 ------217,000 149,000 ---172,000 ---431,000 ---303,000 ---487,000 ND
18-Feb-16 25,000 25,000 ------162,000 84,000 ---140,000 ---412,000 ---237,000 ---475,000 ND
11-Aug-16 25,000 25,000 ------213,000 122,000 H1,D6 ---171,000 ---437,000 ---301,000 ---516,000 ND
Notes:
All concentrations are in micrograms per liter (µg/L).
RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present).
DL = Laboratory detection limit.
J = Estimated value between the DL and the RL.
B = Blank-qualified data; result is expected to be biased high based on concentrations in the blanks.
ND = Not detected above laboratory reporting limit.
NC 2L = North Carolina Groundwater Standards from 15A NCAC 2L.0202.
GWPS = Groundwater Protection Standards established by the DENR Solid Waste Section (SWS).
When the NC 2L has not been established, the GWPS will be used.
Bold values for groundwater are above the NC 2L Standards or GWPS.
--- = Well was not monitored and/or not reported.
# = Data for MW-1A during the July 2008 event was not used in background calculations because samples were composed of too much sediment due to basically dry conditions, leading to skewed values of inorganic constituents.
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 9 of 9
Joyce Engineering

Appendix D

Historical Detected Organic Constituents in Compliance Wells

APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Organic Compounds
Acetone 15-Dec-09 2.2 100 ---ND ---ND ---ND ---ND ---ND ---ND 2.8 J
23-Jun-10 2.2 100 ---ND ---ND ---ND ---ND ---ND ---ND 7.7 J
NC 2L = 700 µg/L (10/23/07)14-Dec-10 2.2 100 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 2.2 100 ------ND 3.8 B ---2.8 B ---ND ---ND ---ND 3.9 J
NC 2B = NE µg/L (05/01/07)6-Dec-11 2.2 100 ------ND ND ---ND ---ND ---ND ---ND 8.8 J
NC 2L = 6,000 µg/L (2/5/10)13-Jun-12 2.2 100 ------ND ND ---ND ---ND ---ND ---ND 4.7 J
12-Dec-12 10.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 10.0 100 ------ND ND ---ND ---ND ---ND ---ND 14.6 J
6-Aug-13 10.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 10.0 100 ------ND ND ---ND ---ND ---ND ---ND 19.3 J
13-Aug-14 10.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 10.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 10.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 10.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 10.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
Benzene 14-Sep-94 ---5 ND ND ---ND 12.0 ---ND ---ND ---ND ------
2-Dec-94 ---5 ND ND ---ND 14.0 ---ND ---ND ---ND ------
8-Feb-95 ---5 ND ND ---ND 15.0 ---ND ---ND ---ND ------
2-Mar-95 ---5 ND ND ---ND 13.0 ---ND ---ND ---ND ------
17-Nov-95 ---5 ND ND ---ND 16.0 ---ND ---ND ---ND ------
23-May-96 ---5 ND ND ---ND 15.0 ---ND ---ND ---ND ------
14-Nov-96 ---5 ND ND ---ND 9.0 ---ND ---ND ---ND ------
18-Jun-97 ---5 ND ND ---ND 13.0 ---ND ---ND ---ND ------
2-Dec-97 ---5 ND ND ---ND 13.0 ---ND ---ND ---ND ------
27-May-98 ---5 ND ND ---ND 12.0 ---ND ---ND ---ND ------
16-Nov-98 ---5 ND ND ---ND 12.4 ---ND ---ND ---ND ------
10-Sep-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
10-Jun-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---5 ---ND ---ND ---ND ---7.0 ---ND ---ND ND
30-Dec-03 ---5 ---ND ---ND ---ND ---12.0 ---ND ---ND ND
30-Jun-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---3 ---ND ---ND ---ND 1.3 ND ND ND ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---1 ---ND ---ND ---ND ---ND ---0.40 J ---ND ND
NC 2L = 1 µg/L (10/23/07)19-Dec-07 ---1 ---------ND ---ND ---ND ---0.53 J ---ND ND
8-Jul-08 ---1.0 ---------ND ---ND ---ND ---0.59 J ---ND ND
16-Dec-08 0.25 1.0 ---ND ---ND ---ND ---ND ---0.40 J ---ND ND
8-Jul-09 0.25 1.0 ---ND ---ND ---ND ---ND ---0.54 J ---ND ND
15-Dec-09 0.25 1.0 ---ND ---ND ---ND ---ND ---0.37 J ---ND ND
23-Jun-10 0.25 1.0 ---ND ---ND ---ND ---ND ---0.42 J ---ND ND
14-Dec-10 0.25 1.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 0.25 1.0 ------ND ND ---ND ---ND ---0.39 J ---ND ND
6-Dec-11 0.25 1.0 ------ND ND ---ND ---ND ---0.40 J ---ND ND
13-Jun-12 0.25 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 0.25 1.0 ------ND ND ---ND ---ND ---0.41 J ---ND ND
29-Apr-13 0.25 1.0 ------ND ND ---ND ---ND ---0.33 J ---ND ND
6-Aug-13 0.25 1.0 ------ND ND ---ND ---ND ---0.40 J ---ND ND
25-Feb-14 0.25 1.0 ------ND ND ---ND ---ND ---0.40 J ---ND ND
13-Aug-14 0.25 1.0 ------ND ND ---ND ---ND ---0.41 J ---ND ND
12-Mar-15 0.25 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.25 1.0 ------ND ND ---ND ---ND ---0.35 J ---ND ND
18-Feb-16 0.25 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 0.25 1.0 ------ND ND ---ND ---ND ---0.34 J ---ND ND
Carbon Disulfide 18-Jun-97 ---100 ND ND ---ND ND ---ND ---ND ---16.0 ------
2-Dec-97 ---100 ND ND ---ND 12.0 ---ND ---ND ---23.0 ------
27-May-98 ---100 ND ND ---ND ND ---ND ---ND ---46.0 ------
16-Nov-98 ---100 ND ND ---ND 3.3 ---ND ---ND ---33.5 ------
10-Sep-99 ---100 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---100 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---100 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---100 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---100 ---ND ---ND ---ND ND ND ND ND ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 700 µg/L (10/23/07)19-Dec-07 ---100 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---100 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 1.2 100 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 1.2 100 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 1.2 100 ---ND ---ND ---ND ---ND ---ND ---ND ND
23-Jun-10 1.2 100 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 1.2 100 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 1.2 100 ------ND ND ---ND ---ND ---ND ---ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 1 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Chlorobenzene 16-Nov-98 ---5 ND ND ---ND ND ---2.7 ---ND ---ND ------
10-Sep-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---3 ---ND ---ND ---ND ---ND ND ND ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---3 ---ND ---ND ---ND ---ND ---0.34 J ---ND ND
NC 2L = 50 µg/L (10/23/07)19-Dec-07 ---3 ---------ND ---0.64 J ---ND ---0.44 J ---ND ND
8-Jul-08 ---3.0 ---------ND ---ND ---ND ---0.97 J ---ND ND
16-Dec-08 0.23 3.0 ---ND ---ND ---ND ---ND ---0.42 J ---ND ND
8-Jul-09 0.23 3.0 ---ND ---ND ---0.25 J ---ND ---0.57 J ---ND ND
15-Dec-09 0.23 3.0 ---ND ---ND ---0.25 J ---ND ---0.49 J ---ND ND
23-Jun-10 0.23 3.0 ---ND ---ND ---0.26 J ---ND ---0.53 J ---ND ND
14-Dec-10 0.23 3.0 ---------ND ---ND ---ND ---0.93 B ---ND 0.43 J
21-Jun-11 0.23 3.0 ------ND ND ---0.27 J ---ND ---0.65 J ---ND ND
6-Dec-11 0.23 3.0 ------ND ND ---ND ---ND ---0.63 J ---ND ND
13-Jun-12 0.23 3.0 ------ND ND ---ND ---ND ---0.55 J ---ND ND
12-Dec-12 0.23 3.0 ------ND ND ---ND ---ND ---1.0 J ---ND ND
29-Apr-13 0.23 3.0 ------ND ND ---ND ---ND ---0.70 J ---ND ND
6-Aug-13 0.23 3.0 ------ND ND ---ND ---ND ---0.83 J ---ND ND
25-Feb-14 0.23 3.0 ------ND ND ---ND ---ND ---0.78 J ---ND ND
13-Aug-14 0.23 3.0 ------ND ND ---ND ---ND ---0.87 J ---ND ND
12-Mar-15 0.23 3.0 ------ND ND ---ND ---ND ---0.64 J ---ND ND
19-Aug-15 0.23 3.0 ------ND ND ---ND ---ND ---0.89 J ---ND ND
18-Feb-16 0.23 3.0 ------ND ND ---ND ---ND ---0.79 J ---ND ND
11-Aug-16 0.23 3.0 ------ND ND ---ND ---ND ---0.96 J ---ND ND
Chloroethane 14-Sep-94 ---10 ND ND ---ND 30.0 ---ND ---ND ---ND ------
2-Dec-94 ---10 ND ND ---ND 26.0 ---ND ---ND ---ND ------
8-Feb-95 ---10 ND ND ---ND 33.0 ---ND ---ND ---35.0 ------
2-Mar-95 ---10 ND ND ---ND 26.0 ---ND ---ND ---24.0 ------
17-Nov-95 ---10 ND ND ---ND 25.0 ---ND ---ND ---27.0 ------
23-May-96 ---10 ND ND ---ND 26.0 ---ND ---ND ---56.0 ------
14-Nov-96 ---10 ND ND ---ND 16.0 ---ND ---ND ---ND ------
18-Jun-97 ---10 ND ND ---ND 21.0 ---ND ---ND ---63.0 ------
2-Dec-97 ---10 ND ND ---ND 22.0 ---2.0 ---ND ---64.0 ------
27-May-98 ---10 ND ND ---ND 16.0 ---ND ---ND ---78.0 ------
16-Nov-98 ---10 ND ND ---ND 15.8 ---ND ---ND ---36.2 ------
10-Sep-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---10 ---ND ---ND ---ND ND ND ND ND ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 2,800 µg/L (10/23/07)19-Dec-07 ---10 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---10.0 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 0.54 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 0.54 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 0.54 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 3,000 µg/L (2/5/10)23-Jun-10 0.54 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 0.54 10.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 0.54 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
Chloromethane 23-Jun-10 0.11 1.0 ---0.14 J ---ND ---0.12 J ---ND ---ND ---0.16 J ND
NC 2L = 3 µg/L (2/5/10)14-Dec-10 0.11 1.0 ---------ND ---ND ---ND ---ND ---ND ND
NC 2B = NE µg/L (05/01/07)21-Jun-11 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 0.11 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 0.11 1.0 ------ND ND ---ND ---ND ---0.12 J ---ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 2 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
1,2-Dichlorobenzene 12-Jul-07 ---5 ---ND ---ND ---ND ---ND ---0.6 J ---ND ND
NC 2B = NE µg/L (05/01/07)19-Dec-07 ---5 ---------ND ---0.32 J ---ND ---0.99 J ---ND ND
NC 2L = 24 µg/L (10/23/07)8-Jul-08 ---5.0 ---------ND ---ND ---ND ---1.3 J ---ND ND
16-Dec-08 0.30 5.0 ---ND ---ND ---ND ---ND ---0.73 J ---ND ND
8-Jul-09 0.30 5.0 ---ND ---ND ---ND ---ND ---1.1 J ---ND ND
15-Dec-09 0.30 5.0 ---ND ---ND ---ND ---ND ---0.99 J ---ND ND
NC 2L = 20 µg/L (2/5/10)23-Jun-10 0.30 5.0 ---ND ---ND ---ND ---ND ---1.0 J ---ND ND
14-Dec-10 0.30 5.0 ---------ND ---ND ---ND ---0.78 J ---ND ND
21-Jun-11 0.30 5.0 ------ND ND ---ND ---ND ---1.1 J ---ND ND
6-Dec-11 0.30 5.0 ------ND ND ---ND ---ND ---0.74 J ---ND ND
13-Jun-12 0.30 5.0 ------ND ND ---ND ---ND ---1.1 J ---ND ND
12-Dec-12 0.30 5.0 ------ND ND ---ND ---ND ---1.1 J ---ND ND
29-Apr-13 0.30 5.0 ------ND ND ---ND ---ND ---1.2 J ---ND ND
6-Aug-13 0.30 5.0 ------ND ND ---ND ---ND ---1.2 J ---ND ND
25-Feb-14 0.30 5.0 ------ND ND ---ND ---ND ---1.1 J ---ND ND
13-Aug-14 0.30 5.0 ------ND ND ---ND ---ND ---1.1 J ---ND ND
12-Mar-15 0.30 5.0 ------ND ND ---ND ---ND ---0.89 J ---ND ND
19-Aug-15 0.30 5.0 ------ND ND ---ND ---ND ---1.2 J ---ND ND
18-Feb-16 0.30 5.0 ------ND ND ---ND ---ND ---1.0 J ---ND ND
11-Aug-16 0.30 5.0 ------ND ND ---ND ---ND ---1.2 J ---ND ND
1,3-Dichlorobenzene 8-Jul-08 ---5.0 ---------ND ---ND ---ND ---0.29 J ---ND ND
NC 2L = 170 µg/L (10/23/07)16-Dec-08 ---------------------------------------------
NC 2B = NE µg/L (05/01/07)8-Jul-09 0.24 5.0 ---ND ---ND ---ND ---ND ---0.38 J ---ND ND
15-Dec-09 ---------------------------------------------
NC 2L = 200 µg/L (2/5/10)23-Jun-10 0.24 5.0 ---------ND ---------ND ---0.35 J ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 0.24 5.0 ------ND ND ---------ND ---0.32 J ---ND ND
6-Dec-11 ---------------------------------------------
13-Jun-12 0.24 5.0 ------ND ND ---ND ---ND ---0.29 J ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 0.24 5.0 ------ND ND ---ND ---ND ---0.36 J ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 0.24 5.0 ------ND ND ---ND ---ND ---0.29 J ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.24 5.0 ------ND ------------------ND ------ND
18-Feb-16 0.24 5.0 ------ND ------------------0.31 J ------ND
11-Aug-16 0.24 5.0 ------ND ------------------ND ------ND
1,4-Dichlorobenzene 14-Sep-94 ---5 ND ND ---ND 5.0 ---ND ---ND ---ND ---NA
2-Dec-94 ---5 ND ND ---ND ND ---ND ---ND ---ND ---NA
8-Feb-95 ---5 ND ND ---ND ND ---ND ---ND ---ND ---NA
2-Mar-95 ---5 ND ND ---ND ND ---ND ---ND ---ND ---NA
17-Nov-95 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
14-Nov-96 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---5 ND ND ---ND 2.0 ---2.0 ---ND ---ND ------
27-May-98 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---5 ND ND ---ND 2.1 ---3.2 ---ND ---2.2 ------
10-Sep-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---10.5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---3 ---ND ---ND ---ND 3.7 ND ND ND ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---1 ---ND ---ND ---0.32 J ---ND ---ND ---ND ND
Resample >21-Aug-07 ---1 ---------------0.30 J ---------------------
NC 2L = 1.4 µg/L (10/23/07)19-Dec-07 ---1 ---------ND ---0.52 J ---ND ---0.71 J ---ND ND
8-Jul-08 ---1.0 ---------ND ---ND ---ND ---0.96 J ---ND ND
16-Dec-08 0.33 1.0 ---ND ---ND ---ND ---ND ---0.64 J ---ND ND
8-Jul-09 0.33 1.0 ---ND ---ND ---ND ---ND ---0.84 J ---ND ND
15-Dec-09 0.33 1.0 ---ND ---ND ---ND ---ND ---0.76 J ---ND ND
NC 2L = 6 µg/L (2/5/10)23-Jun-10 0.33 1.0 ---ND ---ND ---ND ---ND ---0.79 J ---ND ND
14-Dec-10 0.33 1.0 ---------ND ---ND ---ND ---0.96 B ---ND 0.35 J
21-Jun-11 0.33 1.0 ------ND ND ---ND ---ND ---1.0 ---ND ND
6-Dec-11 0.33 1.0 ------ND ND ---ND ---ND ---0.81 J ---ND ND
13-Jun-12 0.33 1.0 ------ND ND ---ND ---ND ---0.77 J ---ND ND
12-Dec-12 0.33 1.0 ------ND ND ---ND ---ND ---0.83 J ---ND ND
29-Apr-13 0.33 1.0 ------ND ND ---ND ---ND ---1.0 ---ND ND
6-Aug-13 0.33 1.0 ------ND ND ---ND ---ND ---1.0 ---ND ND
25-Feb-14 0.33 1.0 ------ND ND ---ND ---ND ---0.82 J ---ND ND
13-Aug-14 0.33 1.0 ------ND ND ---ND ---ND ---0.97 J ---ND ND
12-Mar-15 0.33 1.0 ------ND ND ---ND ---ND ---0.86 J ---ND ND
19-Aug-15 0.33 1.0 ------ND ND ---ND ---ND ---1.00 ---ND ND
18-Feb-16 0.33 1.0 ------ND ND ---ND ---ND ---0.92 J ---ND ND
11-Aug-16 0.33 1.0 ------ND ND ---ND ---ND ---0.93 J ---ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 3 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Trans-1,4-Dichloro-2-Butene 27-May-98 ---100 ND ND ---ND ND ---ND ---ND ---6.9 ------
16-Nov-98 ---100 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---100 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---100 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---100 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---100 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---100 ---ND ---ND ---ND ND ND ND ND ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---100 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = NE µg/L (10/23/07)19-Dec-07 ---100 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---100 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 1.0 100 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 1.0 100 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 1.0 100 ---ND ---ND ---ND ---ND ---ND ---ND ND
23-Jun-10 1.0 100 ---------ND ---ND ---ND ---ND ---ND ND
14-Dec-10 1.0 100 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 1.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
Dichlorodifluoromethane 17-Nov-95 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
23-Mar-98 ---5 ND ND ---ND ND ---6.1 ---ND ---6.0 ------
27-May-98 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---5 ---------ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---5 ---------ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---5 ---------ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---5 ---------ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---5 ---------ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---5 ---------------------------------------
30-Jun-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---------------------------------------------
29-Jun-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---5 ---------------------------------------
28-Jun-06 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ------------------------ND ---ND ------------
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 1,400 µg/L (10/23/07)19-Dec-07 ---------------------------------------------
8-Jul-08 ---5.0 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 ---------------ND ---------------------------
8-Jul-09 0.21 5.0 ---ND ---ND ---ND ---ND ---0.37 J ---ND ND
15-Dec-09 ---------------------------------------------
NC 2L = 1000 µg/L (2/5/10)23-Jun-10 0.21 5.0 ---------ND ---ND ---ND ---0.29 J ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 0.21 5.0 ------ND ND ---ND ---ND ---0.36 J ---ND ND
6-Dec-11 ---------------------------------------------
13-Jun-12 0.21 5.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 0.21 5.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 0.21 5.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.21 5.0 ------ND ------------------ND ------ND
18-Feb-16 0.21 5.0 ------ND ------------------ND ------ND
11-Aug-16 0.21 5.0 ---------------------------------------
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 4 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
1,1-Dichloroethane 14-Sep-94 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-94 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
8-Feb-95 ---5 ND ND ---ND ND ---ND ---7.0 ---ND ------
2-Mar-95 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
17-Nov-95 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---5 ND ND ---ND ND ---ND ---5.0 ---7.0 ------
14-Nov-96 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 ---5 ND ND ---ND ND ---ND ---ND ---9.7 ------
2-Dec-97 ---5 ND ND ---ND ND ---2.0 ---10.0 ---ND ------
27-May-98 ---5 ND ND ---ND ND ---ND ---6.0 ---12.0 ------
16-Nov-98 ---5 ND ND ---ND ND ---ND ---9.0 ---5.2 ------
10-Sep-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---5 ND ND ---ND ---ND ---ND ---6.0 ---ND ---
16-Dec-99 ---5 ---------------------------5.0 ---------
10-May-00 ---5 ND ND ---ND ---ND ---ND ---6.0 ---ND ---
26-Oct-00 ---5 ND ND ---ND ---ND ---ND ---7.0 ---ND ---
18-Apr-01 ---5 ---ND ---ND ---ND ---ND ---6.0 ---ND ---
27-Oct-01 ---5 ---ND ---ND ---ND ---ND ---7.0 ---ND ---
10-Jun-02 ---5 ---ND ---ND ---ND ---ND ---6.0 ---ND ---
13-Jun-02 ---5 ---ND ---ND ---ND ---ND ---6.0 ---ND ---
19-Nov-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---5 ---ND ---ND ---ND ---ND ---7.2 ---ND ND
30-Dec-03 ---5 ---ND ---ND ---ND ---ND ---6.3 ---ND ND
30-Jun-04 ---5 ---ND ---ND ---ND ---ND ---6.5 ---ND ND
29-Dec-04 ---5 ---ND ---ND ---ND ---ND ---6.9 ---ND ND
29-Jun-05 ---5 ---ND ---ND ---ND ---ND ---7.0 ---ND ND
29-Dec-05 ---5 ---ND ---ND ---ND ---ND ---6.0 ---ND ND
28-Jun-06 ---5 ---ND ---ND ---ND ---ND ---6.6 ---ND ND
28-Dec-06 ---5 ---ND ---ND ---ND ND ND 1.7 5.3 ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---5 ---ND ---ND ---0.33 J ---ND ---5.4 ---ND ND
Resample >21-Aug-07 ---5 ---------------0.40 J ---------------------
NC 2L = 70 µg/L (10/23/07)19-Dec-07 ---5 ---------ND ---ND ---ND ---6.2 ---ND ND
8-Jul-08 ---5.0 ---------ND ---ND ---ND ---5.1 ---ND ND
16-Dec-08 0.32 5.0 ---ND ---ND ---ND ---ND ---3.4 J ---ND ND
8-Jul-09 0.32 5.0 ---ND ---ND ---ND ---ND ---9.3 ---ND ND
15-Dec-09 0.32 5.0 ---ND ---ND ---ND ---ND ---6.4 ---ND ND
NC 2L = 6 µg/L (2/5/10)23-Jun-10 0.32 5.0 ---ND ---ND ---ND ---ND ---6.5 ---ND ND
14-Dec-10 0.32 5.0 ---------ND ---ND ---ND ---3.9 J ---ND ND
21-Jun-11 0.32 5.0 ------ND ND ---ND ---ND ---6.7 ---ND ND
6-Dec-11 0.32 5.0 ------ND ND ---ND ---ND ---3.0 J ---ND ND
13-Jun-12 0.32 5.0 ------ND ND ---ND ---ND ---3.7 J ---ND ND
12-Dec-12 0.32 5.0 ------ND ND ---ND ---ND ---2.5 J ---ND ND
29-Apr-13 0.32 5.0 ------ND ND ---ND ---ND ---5.8 ---ND ND
6-Aug-13 0.32 5.0 ------ND ND ---ND ---ND ---5.0 ---ND ND
25-Feb-14 0.32 5.0 ------ND ND ---ND ---ND ---4.5 J ---0.35 J ND
13-Aug-14 0.32 5.0 ------ND ND ---ND ---ND ---3.4 J ---0.39 J ND
12-Mar-15 0.32 5.0 ------ND ND ---ND ---ND ---4.2 J ---ND ND
19-Aug-15 0.32 5.0 ------ND ND ---ND ---ND ---3.7 J ---0.54 J ND
18-Feb-16 0.32 5.0 ------ND ND ---ND ---ND ---3.4 J ---0.59 J ND
11-Aug-16 0.32 5.0 ------ND ND ---ND ---ND ---3.4 J ---0.77 J ND
1,2-Dichloroethane 6-Aug-13 0.12 1.0 ------ND ND ---0.62 J ---ND ---ND ---ND ND
NC 2L = 0.4 µg/L (2/5/10)25-Feb-14 0.12 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 0.12 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 0.12 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.24 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 0.24 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 0.24 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
cis-1,2-Dichloroethene 14-Sep-94 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-94 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
8-Feb-95 ---5 ND ND ---ND ND ---ND ---23.0 ---ND ------
2-Mar-95 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
17-Nov-95 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---5 ND ND ---ND ND ---ND ---14.0 ---ND ------
14-Nov-96 ---5 ND ND ---ND ND ---ND ---19.0 ---ND ------
18-Jun-97 ---5 ND ND ---ND ND ---ND ---12.0 ---ND ------
2-Dec-97 ---5 ND ND ---ND ND ---ND ---23.0 ---ND ------
27-May-98 ---5 ND ND ---ND ND ---ND ---12.0 ---5.8 ------
16-Nov-98 ---5 ND ND ---ND ND ---ND ---24.8 ---3.7 ------
10-Sep-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---5 ND ND ---ND ---ND ---ND ---7.0 ---ND ---
16-Dec-99 ---5 ---------------------------7.0 ---------
10-May-00 ---5 ND ND ---ND ---ND ---ND ---8.0 ---ND ---
26-Oct-00 ---5 ND ND ---ND ---ND ---ND ---9.0 ---ND ---
18-Apr-01 ---5 ---ND ---ND ---ND ---ND ---7.0 ---ND ---
27-Oct-01 ---5 ---ND ---ND ---ND ---ND ---13.0 ---ND ---
10-Jun-02 ---5 ---ND ---ND ---ND ---ND ---8.0 ---ND ---
13-Jun-02 ---5 ---ND ---ND ---ND ---ND ---8.0 ---ND ---
19-Nov-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---5 ---ND ---ND ---ND ---ND ---12.0 ---ND ND
30-Dec-03 ---5 ---ND ---ND ---ND ---ND ---10.0 ---ND ND
30-Jun-04 ---5 ---ND ---ND ---ND ---ND ---9.3 ---ND ND
29-Dec-04 ---5 ---ND ---ND ---ND ---ND ---9.4 ---ND ND
29-Jun-05 ---5 ---ND ---ND ---ND ---ND ---8.0 ---ND ND
29-Dec-05 ---5 ---ND ---ND ---ND ---ND ---8.0 ---ND ND
28-Jun-06 ---5 ---ND ---ND ---ND ND ND ---8.8 ---ND ND
28-Dec-06 ---5 ---ND ---ND ---ND ---ND 5.3 6.0 ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---5 ---ND ---ND ---ND ---ND ---6.2 ---ND ND
NC 2L = 70 µg/L (10/23/07)19-Dec-07 ---5 ---------ND ---ND ---ND ---7.2 ---ND ND
8-Jul-08 ---5.0 ---------ND ---ND ---ND ---9.8 ---ND ND
16-Dec-08 1.9 5.0 ---ND ---ND ---ND ---0.91 B ---4.2 J ---ND 0.31 J
8-Jul-09 0.19 5.0 ---ND ---ND ---ND ---ND ---7.7 ---ND ND
15-Dec-09 0.19 5.0 ---ND ---ND ---ND ---ND ---7.4 ---ND ND
23-Jun-10 0.19 5.0 ---ND ---ND ---ND ---ND ---7.1 ---ND ND
14-Dec-10 0.19 5.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 0.19 5.0 ------ND ND ---ND ---ND ---6.4 ---ND ND
6-Dec-11 0.19 5.0 ------ND ND ---ND ---ND ---3.0 J ---ND ND
13-Jun-12 0.19 5.0 ------ND ND ---ND ---ND ---4.3 J ---ND ND
12-Dec-12 0.19 5.0 ------ND ND ---ND ---ND ---3.3 J ---ND ND
29-Apr-13 0.19 5.0 ------ND ND ---ND ---ND ---4.8 J ---ND ND
6-Aug-13 0.19 5.0 ------ND ND ---ND ---ND ---3.6 J ---ND ND
25-Feb-14 0.19 5.0 ------ND ND ---ND ---ND ---3.7 J ---ND ND
13-Aug-14 0.19 5.0 ------ND ND ---ND ---ND ---2.8 J ---ND ND
12-Mar-15 0.19 5.0 ------ND ND ---ND ---ND ---2.6 J ---ND ND
19-Aug-15 0.19 5.0 ------ND ND ---ND ---ND ---3.1 J ---0.35 J ND
18-Feb-16 0.19 5.0 ------ND ND ---ND ---ND ---2.5 J ---0.32 J ND
11-Aug-16 0.19 5.0 ------ND ND ---ND ---ND ---2.7 J ---0.5 J ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 5 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
2-Hexanone 27-May-98 ---50 ND ND ---ND ND ---ND ---ND ---61.0 ------
16-Nov-98 ---50 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---50 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---50 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---50 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---50 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---50 ---ND ---ND ---ND ND ND ND ND ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---50 ---ND ---ND ---ND ---ND ---ND ---ND ND
GWPS = 280 µg/L (10/23/07)19-Dec-07 ---50 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---50.0 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 0.46 50.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 0.46 50.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 0.46 50.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
23-Jun-10 0.46 50.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 0.46 50.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 0.46 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 0.46 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 0.46 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 0.46 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 0.46 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 0.46 50.0 ------ND ND ---0.55 J ---ND ---ND ---ND ND
25-Feb-14 0.46 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 0.46 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 0.46 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.46 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 0.46 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 0.46 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
Methylene Chloride 14-Sep-94 ---10 ND ND ---ND ND ---ND ---ND ---ND ---NA
2-Dec-94 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
8-Feb-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 ---10 ND ND ---ND ND ---ND ---ND ---6.0 ------
17-Nov-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---10 ND ND ---ND ND ---ND ---ND ---17.0 ------
14-Nov-96 ---10 ND ND ---ND ND ---ND ---ND ---8.2 ------
18-Jun-97 ---10 ND ND ---ND ND ---ND ---ND ---12.0 ------
2-Dec-97 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---10 ND ND ---ND ND ---ND ---ND ---15.0 ------
16-Nov-98 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---6 ---ND ---ND ---ND ND ND ND ND ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 4.6 µg/L (10/23/07)19-Dec-07 ---1 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---2.0 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 0.97 2.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 0.97 2.0 ---ND ---ND ---ND ---ND ---ND ---ND 9.6
15-Dec-09 0.97 2.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 5 µg/L (2/5/10)23-Jun-10 0.97 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 0.97 1.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND 1.9 J
13-Aug-14 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND 1.1
18-Feb-16 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 0.97 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
Naphthalene 8-Jul-08 ---10.0 ---------ND ---ND ---ND ---ND ---2.9 J ND
NC 2L = 21 µg/L (10/23/07)16-Dec-08 ---------------------------------------------
NC 2B = NE µg/L (05/01/07)8-Jul-09 0.24 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 ---------------------------------------------
NC 2L = 6 µg/L (2/5/10)23-Jun-10 0.24 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 0.24 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 ---------------------------------------------
13-Jun-12 0.24 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 0.24 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 0.24 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.24 10.0 ------ND ------------------ND ------ND
18-Feb-16 0.24 10.0 ------ND ------------------ND ------ND
11-Aug-16 0.24 10.0 ---------------------------------------
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 6 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Toluene 18-Jun-97 ---5 ND ND ---ND 13 ---ND ---ND ---ND ------
2-Dec-97 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---5 ND ND ---7 ---ND ---ND ---ND ---ND ---
19-Oct-99 ---5 ---------ND ---------------------------
16-Nov-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---1 ---ND ---ND ---ND ---ND ---ND ---ND 0.34 J
NC 2L = 1,000 µg/L (10/23/07)19-Dec-07 ---1 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---1.0 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 0.26 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 0.26 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 0.26 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 600 µg/L (2/5/10)23-Jun-10 0.26 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 0.26 1.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 0.26 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
Trichloroethene 2-Dec-97 ---5 ND ND ---ND ND ---ND ---2.0 ---ND ------
27-May-98 ---5 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---5 ND ND ---ND ND ---ND ---2.7 ---2.9 ------
10-Sep-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---5 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---3 ---ND ---ND ---ND ND ND ND ND ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---1 ---ND ---ND ---ND ---ND ---0.68 J ---ND ND
NC 2L = 2.8 µg/L (10/23/07)19-Dec-07 ---1 ---------ND ---ND ---ND ---0.64 J ---ND ND
8-Jul-08 ---1.0 ---------ND ---ND ---ND ---0.51 J ---ND ND
16-Dec-08 0.47 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 0.47 1.0 ---ND ---ND ---ND ---ND ---0.53 J ---ND ND
15-Dec-09 0.47 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 3 µg/L (2/5/10)23-Jun-10 0.47 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 0.47 1.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 0.47 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 7 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Vinyl chloride 14-Sep-94 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-94 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
8-Feb-95 ---10 ND ND ---ND ND ---ND ---26.0 ---ND ------
2-Mar-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
17-Nov-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 ---10 ND ND ---ND ND ---ND ---13.0 ---ND ------
14-Nov-96 ---10 ND ND ---ND ND ---ND ---17.0 ---ND ------
18-Jun-97 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---10 ND ND ---ND 2.0 ---ND ---33.0 ---ND ------
27-May-98 ---10 ND ND ---ND ND ---ND ---13.0 ---ND ------
16-Nov-98 ---10 ND ND ---ND ND ---ND ---25.8 ---ND ------
10-Sep-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---10 ND ND ---ND ---ND ---ND ---12.0 ---ND ---
26-Oct-00 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
10-Jun-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---10 ---ND ---ND ---ND ---ND ---26.9 ---ND ND
30-Dec-03 ---10 ---ND ---ND ---ND ---ND ---10.0 ---ND ND
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---11.0 ---ND ND
29-Dec-04 ---10 ---ND ---ND ---ND ---ND ---12.0 ---ND ND
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---14.0 ---ND ND
29-Dec-05 ---10 ---ND ---ND ---ND ---ND ---15.0 ---ND ND
28-Jun-06 ---10 ---ND ---ND ---ND ---ND ---12.5 ---ND ND
28-Dec-06 ---6 ---ND ---ND ---ND ND ND 8.1 8.9 ---ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---1 ---ND ---ND ---ND ---ND ---8.3 ---ND ND
NC 2L = 0.015 µg/L (10/23/07)19-Dec-07 ---1 ---------ND ---ND ---ND ---8.4 ---ND ND
8-Jul-08 ---1.0 ---------ND ---ND ---ND ---10.6 ---ND ND
16-Dec-08 0.62 1.0 ---ND ---ND ---ND ---ND ---5.0 ---ND ND
8-Jul-09 0.62 1.0 ---ND ---ND ---ND ---ND ---13.3 ---ND ND
15-Dec-09 0.62 1.0 ---ND ---ND ---ND ---ND ---9.9 ---ND ND
NC 2L = 0.03 µg/L (2/5/10)23-Jun-10 0.62 1.0 ---ND ---ND ---ND ---ND ---11.2 ---ND ND
14-Dec-10 0.62 1.0 ---------ND ---ND ---ND ---8.4 ---ND ND
21-Jun-11 0.62 1.0 ------ND ND ---ND ---ND ---10.5 ---ND ND
6-Dec-11 0.62 1.0 ------ND ND ---ND ---ND ---4.1 ---ND ND
13-Jun-12 0.62 1.0 ------ND ND ---ND ---ND ---6.6 ---ND ND
12-Dec-12 0.62 1.0 ------ND ND ---ND ---ND ---3.3 ---ND ND
29-Apr-13 0.62 1.0 ------ND ND ---ND ---ND ---7.6 ---ND ND
6-Aug-13 0.62 1.0 ------ND ND ---ND ---ND ---9.1 ---ND ND
25-Feb-14 0.62 1.0 ------ND ND ---ND ---ND ---6.8 ---ND ND
13-Aug-14 0.62 1.0 ------ND ND ---ND ---ND ---5.4 ---ND ND
12-Mar-15 0.62 1.0 ------ND ND ---ND ---ND ---5.1 ---ND ND
19-Aug-15 0.62 1.0 ------ND ND ---ND ---ND ---5.0 ---ND ND
18-Feb-16 0.62 1.0 ------ND ND ---ND ---ND ---5.4 ---ND ND
11-Aug-16 0.62 1.0 ------ND ND ---ND ---ND ---5.6 ---ND ND
Bis(2-ethylhexyl)phthalate 21-Jun-11 0.79 15.0 ------ND 2.5 J ---ND ---4.5 J ---ND ---ND ND
NC 2L = 3 µg/L (2/5/10)6-Dec-11 ---------------------------------------------
13-Jun-12 0.79 15.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 0.79 15.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 0.79 15.0 ------ND ND ---40.4 ---5.0 J ---ND ---ND ND
Resample >15-Apr-14 0.79 15.0 ---------------ND ------------------ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.49 15.0 ------ND ------------------ND ------ND
18-Feb-16 0.85 15.0 ------ND ------------------ND ------ND
11-Aug-16 0.85 15.0 ---------------------------------------
Diethylphthalate 17-Nov-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---10 ND ND ---ND ND ---24.0 ---ND ---ND ------
23-Mar-98 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---10 ND ND ---ND ND ---10 ---ND ---ND ------
10-Sep-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---10 ---------ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---10 ---------ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---10 ---------ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---10.5 ---------ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---10 ---------ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---10 ---------------------------------------
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---------------------------------------------
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---------------------------------------------
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 5,000 µg/L (10/23/07)19-Dec-07 ---------------------------------------------
8-Jul-08 ---20.0 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 ---------------------------------------------
8-Jul-09 2.7 11.1 ---ND ---------ND ---ND ---ND ---ND ND
15-Dec-09 ---------------------------------------------
NC 2L = 6,000 µg/L (2/5/10)23-Jun-10 3.9 14.3 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 0.58 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 ---------------------------------------------
13-Jun-12 0.58 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 0.58 6000 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 0.58 6000 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.91 6000 ------ND ------------------ND ------ND
18-Feb-16 1.30 6000 ------ND ------------------ND ------ND
11-Aug-16 1.30 6000 ------------------------
Benzo(g,h,i)perylene 21-Jun-11 0.79 15.0 ------ND ND ---ND ---ND ---1.1 J ---ND ND
NC 2L = 200 µg/L (2/5/10)6-Dec-11 ---------------------------------------------
13-Jun-12 0.38 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 0.38 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 0.38 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.45 10.0 ------ND ------------------ND ------ND
18-Feb-16 0.38 10.0 ------ND ------------------ND ------ND
11-Aug-16 0.38 10.0 ---------------------------------------
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 8 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Dibenz(a,h)anthracene 21-Jun-11 0.79 15.0 ------ND ND ---ND ---ND ---1.2 J ---ND ND
NC 2L = 0.005 µg/L (2/5/10)6-Dec-11 ---------------------------------------------
13-Jun-12 0.55 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 0.55 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 0.55 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.49 10.0 ------ND ------------------ND ------ND
18-Feb-16 0.55 10.0 ------ND ------------------ND ------ND
11-Aug-16 0.55 10.0 ---------------------------------------
Indeno(1,2,3-cd)pyrene 21-Jun-11 0.79 15.0 ------ND ND ---ND ---ND ---1.2 J ---ND ND
NC 2L = 0.05 µg/L (2/5/10)6-Dec-11 ---------------------------------------------
13-Jun-12 0.29 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 0.29 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 0.29 10.0 ------ND ------ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.53 10.0 ------ND ------------------ND ------ND
18-Feb-16 0.29 10.0 ------ND ------------------ND ------ND
11-Aug-16 0.29 10.0 ---------------------------------------
Phorate 17-Nov-95 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---10 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---10 ---------ND ---1.0 ---ND ---0.8 ---ND ---
26-Oct-00 ---1.5 ---------ND ---5.2 ---ND ---ND ---ND ---
18-Apr-01 ---10 ---------ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---0.5 ---------ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---10 ---------ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---10 ---------------------------------------
30-Jun-04 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---------------------------------------------
29-Jun-05 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---10 ---------------------------------------
28-Jun-06 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---------------------------------------------
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---10 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 1.4 µg/L (10/23/07)19-Dec-07 ---------------------------------------------
8-Jul-08 ---40.0 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 ---------------------------------------------
8-Jul-09 6.6 22.2 ---ND ---------ND ---ND ---ND ---ND ND
15-Dec-09 ---------------------------------------------
NC 2L = 1 µg/L (2/5/10)23-Jun-10 7.7 28.6 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 5.4 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 ---------------------------------------------
13-Jun-12 5.4 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 5.4 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 5.4 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.83 10.0 ------ND ------------------ND ------ND
18-Feb-16 1.10 10.0 ------ND ------------------ND ------ND
11-Aug-16 1.10 10.0 ---------------------------------------
Aldrin 17-Nov-95 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
23-Mar-98 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---0.05 ND ND ---ND ND ---0.073 ---ND ---ND ------
10-Sep-99 ---0.05 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---0.05 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---0.05 ---------------------------------------
30-Jun-04 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---------------------------------------------
29-Jun-05 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---0.05 ---------------------------------------
28-Jun-06 ---0.05 ---------ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---------------------------------------------
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = NE µg/L (10/23/07)19-Dec-07 ---------------------------------------------
8-Jul-08 ---0.050 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 ---------------------------------------------
8-Jul-09 0.050 0.050 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 ---------------------------------------------
23-Jun-10 0.00053 0.011 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 0.00050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 ---------------------------------------------
13-Jun-12 0.05 0.05 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 0.050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 0.050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.050 0.050 ------ND ------------------ND ------ND
18-Feb-16 0.050 0.050 ------ND ------------------ND ------ND
11-Aug-16 0.050 0.050 ---------------------------------------
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 9 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Alpha-BHC 17-Nov-95 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---0.05 ND ND ---ND ND ---0.20 ---ND ---ND ------
23-Mar-98 ---0.05 ND ND ---ND 0.073 ---0.16 ---ND ---ND ------
27-May-98 ---0.05 ND ND ---ND ND ---ND ---0.095 ---0.053 ------
16-Nov-98 ---0.05 ND ND ---ND ND ---0.23 ---ND ---ND ------
10-Sep-99 ---0.05 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---0.05 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---0.05 ---------------------------------------
30-Jun-04 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---------------------------------------------
29-Jun-05 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---0.05 ---------------------------------------
28-Jun-06 ---0.05 ---------ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---------------------------------------------
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ---
GWPS = 0.006 µg/L (10/23/07)19-Dec-07 ---------------------------------------------
8-Jul-08 ---0.050 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 ---------------------------------------------
8-Jul-09 0.050 0.050 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 ---------------------------------------------
23-Jun-10 0.00032 0.011 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 0.00030 0.050 ------ND ND ---0.054 ---ND ---ND ---ND ND
Resample >28-Jul-11 0.00030 0.050 ---------------ND ------------------ND
6-Dec-11 ---------------------------------------------
13-Jun-12 0.05 0.05 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------------------
29-Apr-13 0.050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------------------
25-Feb-14 0.050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.050 0.050 ------ND ------------------ND ------ND
18-Feb-16 0.050 0.050 ------ND ------------------ND ------ND
11-Aug-16 0.050 0.050 ---------------------------------------
Beta-BHC 27-Jun-03 ---1.05 ---ND ---ND ---0.068 ---ND ---ND ---ND ---
30-Dec-03 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 ---0.05 ---------ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---------------------------------------------
NC 2B = NE µg/L (05/01/07)12-Jul-07 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
GWPS = 0.019 µg/L (10/23/07)19-Dec-07 ---0.05 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 ---0.050 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 0.050 0.050 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 0.050 0.050 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 0.010 0.100 ---ND ---ND ---ND ---ND ---ND ---ND ND
23-Jun-10 0.00053 0.011 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 0.00050 0.050 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 0.00050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 0.050 0.050 ------ND ND ---ND ---ND ---0.059 ---ND ND
Resample >25-Jan-12 0.050 0.050 ------ND ------------------0.082 ------ND
13-Jun-12 0.050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 0.050 0.050 ------ND ND ---ND ---ND ---0.078 ---ND ND
29-Apr-13 0.050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 0.050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 0.050 0.050 ------ND ND ---ND ---ND ---0.056 ---ND ND
13-Aug-14 0.050 0.050 ------ND ------------------ND ------ND
12-Mar-15 0.050 0.050 ------ND ------------------ND ------ND
19-Aug-15 0.050 0.050 ------ND ------------------ND ------ND
18-Feb-16 0.050 0.050 ------ND ------------------ND ------ND
11-Aug-16 0.050 0.050 ------ND ------------------ND ------ND
4,4'-DDT 23-Jun-10 0.0037 0.010 ---ND ---ND ---ND ---ND ---0.016 J ---ND ND
NC 2L = 0.1 µg/L (2/5/10)14-Dec-10 ---------------------------------ND ---------
NC 2B = 0.001 µg/L (05/01/07)21-Jun-11 0.0036 0.10 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 ---------------------------------ND ---------
13-Jun-12 0.05 0.10 ------ND ND ---ND ---ND ---0.090 J ---ND ND
12-Dec-12 ---------------------------------ND ---------
29-Apr-13 0.050 0.10 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------ND ---------
25-Feb-14 0.050 0.10 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.050 0.10 ------ND ------------------ND ------ND
18-Feb-16 0.050 0.10 ------ND ------------------ND ------ND
11-Aug-16 0.050 0.10 ---------------------------------------
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 10 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Dieldrin 17-Nov-95 ---0.1 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---0.1 ND ND ---ND ND ---0.10 ---ND ---ND ------
23-Mar-98 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---0.1 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 ---0.1 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---0.05 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---0.1 ---------ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---0.1 ---------ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---0.1 ---------ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---0.1 ---------ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---0.1 ---------ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---0.1 ---------------------------------------
30-Jun-04 ---0.1 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---------------------------------------------
29-Jun-05 ---0.1 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---0.1 ---------------------------------------
28-Jun-06 ---0.1 ---------ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---------------------------------------------
NC 2B = 0.002 µg/L (05/01/07)12-Jul-07 ---0.075 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 0.0022 µg/L (10/23/07)19-Dec-07 ---------------------------------------------
8-Jul-08 ---0.075 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 ---------------------------------------------
8-Jul-09 0.050 0.075 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 ---------------------------------------------
NC 2L = 0.002 µg/L (2/5/10)23-Jun-10 0.00053 0.011 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 0.00050 0.075 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 ---------------------------------------------
13-Jun-12 0.05 0.05 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------------------ND ---------
29-Apr-13 0.050 0.075 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------ND ---------
25-Feb-14 0.050 0.075 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.050 0.075 ------ND ------------------ND ------ND
18-Feb-16 0.050 0.075 ------ND ------------------ND ------ND
11-Aug-16 0.050 0.075 ---------------------------------------
Endosulfan I 21-Jun-11 0.00070 0.10 ------ND ND ---0.52 ---ND ---ND ---ND ND
NC 2L = 40 µg/L (2/5/10) Resample >28-Jul-11 0.00070 0.10 ---------------ND ------------------ND
6-Dec-11 ---------------------ND ------------------ND
13-Jun-12 0.050 0.10 ------ND ND ---0.33 ---ND ---ND ---ND ND
12-Dec-12 0.050 0.10 ------ND ND ---1.33 ---ND ---ND ---ND ND
29-Apr-13 0.050 0.10 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 0.050 0.10 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 0.050 0.10 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 0.050 0.10 ------ND ------------------ND ------ND
12-Mar-15 0.050 0.10 ------ND ------------------ND ------ND
19-Aug-15 0.050 0.10 ------ND ------------------ND ------ND
18-Feb-16 0.050 0.10 ------ND ------------------ND ------ND
11-Aug-16 0.050 0.10 ------ND ------------------ND ------ND
Endosulfan Sulfate 13-Jun-12 0.050 0.10 ------ND ND ---0.090 J ---ND ---ND ---ND ND
12-Dec-12 ---------------------ND ---------------------
29-Apr-13 0.050 0.10 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------ND ---------
25-Feb-14 0.050 0.10 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.05 0.10 ------ND ------------------ND ------ND
18-Feb-16 0.05 0.10 ------ND ------------------ND ------ND
11-Aug-16 0.05 0.10 ---------------------------------------
Heptachlor 17-Nov-95 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
23-Mar-98 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---0.05 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---0.05 ND ND ---ND ND ---0.068 ---ND ---ND ------
10-Sep-99 ---0.05 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---0.05 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
27-Jun-03 ---0.05 ---------ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---0.05 ------------------------------------ND
30-Jun-04 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---0.05 ------------------------------------ND
29-Jun-05 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---0.05 ------------------------------------ND
28-Jun-06 ---0.05 ---------ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2B = 0.004 µg/L (05/01/07)12-Jul-07 ---0.05 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 0.0078 µg/L (10/23/07)19-Dec-07 ---0.05 ------------------------------------ND
8-Jul-08 ---0.050 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 ---------------------------------------------
8-Jul-09 0.050 0.050 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 ---------------------------------------------
NC 2L = 0.008 µg/L (2/5/10)23-Jun-10 0.0016 0.011 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 0.0015 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 ---------------------------------------------
13-Jun-12 0.05 0.05 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------ND ---------------------
29-Apr-13 0.050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------ND ---------
25-Feb-14 0.050 0.050 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.050 0.050 ------ND ------------------ND ------ND
18-Feb-16 0.050 0.050 ------ND ------------------ND ------ND
11-Aug-16 0.050 0.050 ------------------------------------
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 11 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Methoxychlor 17-Nov-95 ---1 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 ---1 ND ND ---ND ND ---ND ---ND ---ND ------
23-Mar-98 ---2 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 ---2 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 ---1 ND ND ---ND ND ---0.51 ---ND ---ND ------
10-Sep-99 ---1 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 ---2 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 ---1 ---------ND ---ND ---ND ---ND ---ND ---
26-Oct-00 ---1 ---------ND ---ND ---ND ---ND ---ND ---
18-Apr-01 ---1 ---------ND ---ND ---ND ---ND ---ND ---
13-Jun-02 ---1 ---------ND ---ND ---ND ---ND ---ND ---
30-Dec-03 ---------------------------------------------
30-Jun-04 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 ---------------------------------------------
29-Jun-05 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 ---1 ---------------------------------------
28-Jun-06 ---1 ---------ND ---ND ---ND ---ND ---ND ND
28-Dec-06 ---------------------------------------------
NC 2B = 0.03 µg/L (05/01/07)12-Jul-07 ---1 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 35 µg/L (10/23/07)19-Dec-07 ---------------------------------------------
8-Jul-08 ---1.0 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 ---------------------------------------------
8-Jul-09 0.50 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 ---------------------------------------------
NC 2L = 40 µg/L (2/5/10)23-Jun-10 0.0074 1.1 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 ---------------------------------------------
21-Jun-11 0.0070 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 ---------------------------------------------
13-Jun-12 0.15 0.15 ------ND ND ---ND ---ND ---ND ---ND ND
12-Dec-12 ---------------------ND ---------------------
29-Apr-13 0.15 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 ---------------------------------ND ---------
25-Feb-14 0.15 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 ---------------------------------------------
12-Mar-15 0.15 1.0 ------ND ------------------ND ------ND
18-Feb-16 0.15 1.0 ------ND ------------------ND ------ND
11-Aug-16 0.15 1.0 ---------------------------------------
Notes:
All concentrations are in micrograms per liter (µg/L).
RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present).
DL = Laboratory detection limit.
J = Estimated value between the DL and the RL.
B = Blank-qualified data; result is expected to be biased high based on concentrations in the blanks.
ND = Not detected above laboratory reporting limit.
NC 2L = North Carolina Groundwater Standards from 15A NCAC 2L.0202.
GWPS = Groundwater Protection Standards established by the DENR Solid Waste Section (SWS).
When the NC 2L has not been established, the GWPS will be used.
Bold values for groundwater are above the NC 2L Standards or GWPS.
--- = Well was not monitored and/or not reported.
# = Constituent is included on the NC Appendix II list but not on the NC Appendix I list.
There was a resamplinging event on August 2, 2007 for MW-16D because the prevoius samples from the May 2007 were analyzed out of hold time. There were no detects in the resample.
Volatile organics (8260) for MW-9 for November 10, 2004 sampling event were unable to be analyzed and were resampled on December 1, 2004.
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 12 of 12
Joyce Engineering

Appendix E

Historical Detected COCs in Performance and Sentinel Wells

APPENDIX E:
Historical Detected COCs in Performance and Sentinel Wells
Sample
Analyte Collection Date RL NES-1S NES-1D NES-2S NES-2D Blanks
ORGANICS
Vinyl Chloride 18-May-04 10 ND ND ND ND ND
30-Jun-04 10 ND ND ND ND ND
28-Dec-06 6 ND NS ND NS ND
NC 2L = 0.015 µg/L (10/23/07)16-Dec-08 1 ND ND ND ND ND
8-Jul-09 1 ND ND ND ND ND
15-Dec-09 2 ND ND ND ND ND
NC 2L = 0.03 µg/L (01/01/10)23-Jun-10 1.0 ND ND ND ND ND
14-Dec-10 1.0 ND NS ND NS ND
21-Jun-11 1.0 ND ND ND ND ND
5-Dec-11 1.0 ND ND ND ND ND
13-Jun-12 1.0 ND ND ND ND ND
10-Dec-12 1.0 ND ND ND ND ND
30-Apr-13 1.0 ND ND ND ND ND
7-Aug-13 1.0 ND NS ND NS ND
25-Feb-14 1.0 ND ND ND ND ND
13-Aug-14 1.0 NS NS ND NS ND
12-Mar-15 1.0 NS NS ND NS ND
19-Aug-15 1.0 NS NS ND NS ND
18-Feb-16 1.0 NS NS ND NS ND
11-Aug-16 1.0 NS NS ND NS ND
1,1-Dichloroethane *18-May-04 5 ND ND ND ND ND
30-Jun-04 5 ND ND ND ND ND
28-Dec-06 5 ND NS ND NS ND
NC 2L = 70 µg/L (10/23/07)16-Dec-08 5 NS NS NS NS NS
8-Jul-09 5 NS NS NS NS NS
15-Dec-09 5 NS NS NS NS NS
NC 2L = 6 µg/L (01/01/10)23-Jun-10 5.0 NS NS ND*ND*ND
14-Dec-10 5.0 0.32 J NS ND NS ND
21-Jun-11 5.0 ND 0.33 J ND ND ND
5-Dec-11 5.0 ND ND ND ND ND
13-Jun-12 5.0 ND ND ND ND ND
10-Dec-12 5.0 ND 0.38 J ND ND ND
30-Apr-13 5.0 ND 0.38 J ND ND ND
7-Aug-13 5.0 ND NS ND NS ND
25-Feb-14 5.0 ND 0.33 J ND ND ND
13-Aug-14 5.0 NS NS ND NS ND
12-Mar-15 5.0 NS NS ND NS ND
18-Feb-16 5.0 NS NS ND NS ND
11-Aug-16 5.0 NS NS NS NS NS
beta-BHC *13-Jun-12 5.0 ND ND ND ND ND
10-Dec-12 5.0 ND ND ND ND ND
GWPS = 0.019 µg/L (10/23/07)30-Apr-13 5.0 ND ND ND ND ND
7-Aug-13 5.0 ND ND ND ND ND
25-Feb-14 5.0 ND ND ND ND ND
13-Aug-14 5.0 NS NS ND NS ND
12-Mar-15 5.0 NS NS ND NS ND
18-Feb-16 5.0 NS NS ND NS ND
11-Aug-16 5.0 NS NS NS NS NS
Notes:
COC = Constituents of Concern.µg/L = micrograms per liter = parts per billion.
RL = Reporting Limit. J = Estimated concentraion below the RL.
B = Blank-qualified detection.
* 1,1-DCA was added to the COC list and Benzene and cis-1,2-dichloroethylene ND = Not detected above the laboratory detection limit.
were dropped following DENR SWS approval dataed January 27, 2011.NS = Not sampled for this parameter during this event.
1,1-DCA and beta-BHC were dropped from the COC list following DENR-SWS
approval dated July 30, 2015.
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Joyce Engineering

Appendix F

Historical Detected Constituents in Surface Water

APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
INORGANICS
Antimony 23-Jun-10 2.6 6.0 2.8 J ND ND
NC 2B = NE (05/01/07)14-Dec-10 2.6 6.0 ND Dry ND
21-Jun-11 5.0 6.0 ND Dry ND
6-Dec-11 5.0 6.0 ND ND ND
13-Jun-12 5.0 6.0 ND ND ND
11-Dec-12 5.0 6.0 ND Dry ND
29-Apr-13 5.0 6.0 ND ND ND
6-Aug-13 5.0 6.0 ND ND ND
25-Feb-14 5.0 6.0 ND ND ND
13-Aug-14 5.0 6.0 ND ND ND
11-Mar-15 3.8 6.0 ND ND ND
19-Aug-15 3.8 6.0 ND Dry ND
18-Feb-16 3.8 6.0 ND ND ND
11-Aug-16 3.8 6.0 ND ND ND
Arsenic 19-Dec-07 NR 10 5.3 Dry ND
NC 2B = 50 µg/L (05/01/07)8-Jul-08 NR 10.0 ND Dry ND
16-Dec-08 2.7 11.0 ND ND ND
8-Jul-09 2.7 10.0 ND Dry ND
15-Dec-09 2.7 10.0 ND 2.7 J ND
23-Jun-10 2.7 10.0 9.2 J ND ND
14-Dec-10 2.7 10.0 3.1 J Dry ND
21-Jun-11 5.0 10.0 ND Dry ND
6-Dec-11 5.0 10.0 ND ND ND
13-Jun-12 5.0 10.0 6.5 J ND ND
11-Dec-12 5.0 10.0 ND Dry ND
29-Apr-13 5.0 10.0 ND ND ND
6-Aug-13 5.0 10.0 5.5 J ND ND
25-Feb-14 5.0 10.0 ND ND ND
13-Aug-14 5.0 10.0 ND ND ND
11-Mar-15 2.5 10.0 4.9 J 2.7 J ND
19-Aug-15 2.5 10.0 ND Dry ND
18-Feb-16 2.5 10.0 ND ND ND
11-Aug-16 2.5 10.0 6.8 J 7.3 J ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 1 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Barium 14-Sep-94 NR 500 160 ND NS
2-Dec-94 NR 500 ND ND NS
8-Feb-95 NR 500 ND ND NS
2-Mar-95 NR 500 ND ND NS
17-Nov-95 NR 500 ND ND NS
23-May-96 NR 500 ND ND NS
14-Nov-96 NR 500 69 29 NS
18-Jun-97 NR 500 64 25 NS
2-Dec-97 NR 500 61 41 NS
27-May-98 NR 500 130 50 NS
16-Nov-98 NR 500 93 100 NS
10-Sep-99 NR 500 ND ND NS
16-Nov-99 NR 500 ND ND NS
10-May-00 NR 500 ND ND NS
26-Oct-00 NR 500 ND ND NS
18-Apr-01 NR 500 ND ND NS
19-Nov-02 NR 500 NS ND NS
27-Jun-03 NR 500 ND ND NS
30-Dec-03 NR 500 ND ND ND
30-Jun-04 NR 500 ND ND ND
29-Dec-04 NR 500 ND ND ND
29-Jun-05 NR 500 ND ND ND
29-Dec-05 NR 500 ND ND ND
28-Jun-06 NR 500 ND ND ND
NC 2B = NE (05/01/07)28-Dec-06 NR 100 40.0 47.2 0.20 J
12-Jul-07 NR 100 66.2 J Dry ND
19-Dec-07 NR 100 112 Dry 10.5
8-Jul-08 NR 100 89.0 J Dry 0.29 J
16-Dec-08 0.20 100 42.1 B 54.8 J 10.7 J
8-Jul-09 0.20 100 101 Dry 17.6 J
15-Dec-09 0.20 100 36.3 B 48.4 B 17.1 J
23-Jun-10 0.20 100 115 B 39.1 B 27.3 J
14-Dec-10 0.20 100 97.4 J Dry 12.1 J
21-Jun-11 5.0 100 66.3 J Dry ND
6-Dec-11 5.0 100 59.7 J 55.3 J ND
13-Jun-12 5.0 100 161 85.4 J ND
11-Dec-12 5.0 100 71.1 J Dry ND
29-Apr-13 5.0 100 43.5 J 43.5 J ND
6-Aug-13 5.0 100 80.3 J 23.8 J ND
25-Feb-14 5.0 100 63.9 J 61.8 J ND
13-Aug-14 5.0 100 47.4 J 43.9 J ND
11-Mar-15 2.5 100 28.5 J 42.0 J ND
19-Aug-15 2.5 100 37.0 J Dry ND
18-Feb-16 2.5 100 58.2 J 55.0 J ND
11-Aug-16 2.5 100 175 152 ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 2 of 13
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APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Beryllium 16-Nov-98 NR 2 1.0 1.0 NS
NC 2B = 6.5 µg/L (05/01/07)10-Sep-99 NR 2 ND ND NS
16-Nov-99 NR 2 ND ND NS
10-May-00 NR 2 ND ND NS
26-Oct-00 NR 2 ND ND NS
18-Apr-01 NR 2 ND ND NS
19-Nov-02 NR 2 ND ND NS
27-Jun-03 NR 2 ND ND NS
30-Dec-03 NR 2 ND ND ND
30-Jun-04 NR 2 ND ND ND
29-Dec-04 NR 2 ND ND ND
29-Jun-05 NR 2 ND ND ND
29-Dec-05 NR 2 ND ND ND
28-Jun-06 NR 2 ND ND ND
28-Dec-06 NR 1 ND ND ND
NC 2B = 6.5 µg/L (05/01/07)12-Jul-07 NR 1 ND Dry ND
19-Dec-07 NR 1 0.93 J Dry ND
8-Jul-08 NR 1.0 0.47 J Dry ND
16-Dec-08 0.10 1.0 0.21 J 0.27 J ND
8-Jul-09 0.10 1.0 0.29 J Dry ND
15-Dec-09 0.10 1.0 0.27 J 0.22 J ND
23-Jun-10 0.10 1.0 1.2 ND ND
14-Dec-10 0.10 1.0 0.78 J Dry ND {0.15} J
21-Jun-11 1.0 1.0 ND Dry ND
6-Dec-11 1.0 1.0 ND ND ND
13-Jun-12 1.0 1.0 1.5 ND ND
11-Dec-12 1.0 1.0 ND Dry ND
29-Apr-13 1.0 1.0 ND ND ND
6-Aug-13 1.0 1.0 ND ND ND
25-Feb-14 1.0 1.0 ND ND ND
13-Aug-14 1.0 1.0 ND ND ND
11-Mar-15 0.5 1.0 ND ND ND
19-Aug-15 0.5 1.0 ND Dry ND
18-Feb-16 0.5 1.0 ND ND ND
11-Aug-16 0.5 1.0 1.9 1.7 ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 3 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Cadmium 19-Nov-02 NR 1 ND 1.0 NS
27-Jun-03 NR 1 ND ND NS
30-Dec-03 NR 1 ND ND ND
30-Jun-04 NR 1 ND ND ND
29-Dec-04 NR 1 ND ND ND
29-Jun-05 NR 1 ND ND ND
29-Dec-05 NR 1 ND ND ND
28-Jun-06 NR 1 ND ND ND
28-Dec-06 NR 1 ND ND ND
NC 2B = 2 µg/L (05/01/07)12-Jul-07 NR 1 ND Dry ND
NC 2L = 1.75 µg/L (10/23/07)19-Dec-07 NR 1 ND Dry ND
8-Jul-08 NR 1.0 ND Dry ND
16-Dec-08 0.50 1.0 ND ND ND
8-Jul-09 0.50 1.0 ND Dry ND
15-Dec-09 0.50 1.0 ND ND ND
23-Jun-10 0.50 1.0 ND ND ND
14-Dec-10 0.50 1.0 ND Dry ND
21-Jun-11 1.0 1.0 ND Dry ND
6-Dec-11 1.0 1.0 ND ND ND
13-Jun-12 1.0 1.0 ND ND ND
11-Dec-12 1.0 1.0 ND Dry ND
29-Apr-13 1.0 1.0 ND ND ND
6-Aug-13 1.0 1.0 ND ND ND
25-Feb-14 1.0 1.0 ND ND ND
13-Aug-14 1.0 1.0 ND ND ND
11-Mar-15 0.5 1.0 ND ND ND
19-Aug-15 0.5 1.0 ND ND ND
18-Feb-16 0.5 1.0 ND ND ND
11-Aug-16 0.5 1.0 ND ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 4 of 13
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APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Chromium 18-Jun-97 NR 10 12.0 ND NS
2-Dec-97 NR 10 8.0 ND NS
27-May-98 NR 10 15.0 ND NS
16-Nov-98 NR 10 30.0 31.0 NS
10-Sep-99 NR 10 24.0 ND NS
16-Nov-99 NR 10 ND ND NS
10-May-00 NR 10 ND ND NS
26-Oct-00 NR 10 ND ND NS
18-Apr-01 NR 10 ND ND NS
19-Nov-02 NR 10 ND ND NS
27-Jun-03 NR 10 ND ND NS
30-Dec-03 NR 10 ND ND ND
30-Jun-04 NR 10 ND ND ND
29-Dec-04 NR 10 ND ND ND
29-Jun-05 NR 10 ND ND ND
29-Dec-05 NR 10 ND ND ND
28-Jun-06 NR 10 12.6 ND ND
28-Dec-06 NR 10 4.8 J 6.1 J ND
NC 2B = 50 µg/L (05/01/07)12-Jul-07 NR 10 ND Dry ND
19-Dec-07 NR 10 27.9 Dry ND
8-Jul-08 NR 10.0 19.3 Dry ND
6-Dec-08 0.40 10.0 6.4 J 8.4 J ND
8-Jul-09 0.40 10.0 12.9 Dry ND
15-Dec-09 0.40 10.0 6.0 J 5.0 J ND
23-Jun-10 0.40 10.0 41.8 4.8 J 0.71 J
Resample >12-Aug-10 0.40 10.0 44.4 NS ND
14-Dec-10 0.40 10.0 32.4 Dry ND
21-Jun-11 5.0 10.0 12.1 Dry ND
6-Dec-11 5.0 10.0 11.8 7.5 J ND
13-Jun-12 5.0 10.0 46.1 20.7 ND
11-Dec-12 5.0 10.0 19.1 Dry ND
29-Apr-13 5.0 10.0 5.8 J 5.8 J ND
6-Aug-13 5.0 10.0 ND ND ND
25-Feb-14 5.0 10.0 13.5 13.2 ND
13-Aug-14 5.0 10.0 10.8 10 J ND
NC 2B = 11 µg/L 03/01/16)11-Mar-15 2.5 10.0 4.0 J 3.1 J ND
19-Aug-15 2.5 10.0 ND Dry ND
18-Feb-16 2.5 10.0 ND ND ND
11-Aug-16 2.5 10.0 63.0 55.1 ND
Resample >13-Sep-16 2.5 10.0 13.8 (ND)DRY ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 5 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Cobalt 14-Nov-96 NR 10 3.0 ND NS
18-Jun-97 NR 10 3.0 ND NS
2-Dec-97 NR 10 ND ND NS
27-May-98 NR 10 8.0 5.0 NS
16-Nov-98 NR 10 4.9 5.9 NS
10-Sep-99 NR 10 ND ND NS
16-Nov-99 NR 10 ND ND NS
10-May-00 NR 10 ND ND NS
26-Oct-00 NR 10 ND ND NS
18-Apr-01 NR 10 ND ND NS
19-Nov-02 NR 10 ND ND NS
27-Jun-03 NR 10 ND ND NS
30-Dec-03 NR 10 ND ND ND
30-Jun-04 NR 10 ND ND ND
29-Dec-04 NR 10 ND ND ND
29-Jun-05 NR 10 ND ND ND
29-Dec-05 NR 10 ND ND ND
28-Jun-06 NR 10 ND ND ND
28-Dec-06 NR 10 ND 2.8 J ND
NC 2B = NE (05/01/07)12-Jul-07 NR 10 ND Dry ND
19-Dec-07 NR 10 34.3 Dry 1.6 J
8-Jul-08 NR 10.0 10.0 B Dry 6.2 J
16-Dec-08 0.60 10.0 4.8 B 5.1 B 2.4 J
8-Jul-09 0.60 10.0 7.2 J Dry ND
15-Dec-09 0.60 10.0 1.6 J 1.3 J ND
23-Jun-10 0.60 10.0 23.0 2.7 J ND
Resample >12-Aug-10 0.60 10.0 30.5 NS ND
14-Dec-10 0.60 10.0 27.0 Dry 1.6 J
21-Jun-11 5.0 10.0 5.4 J Dry ND
6-Dec-11 5.0 10.0 ND ND ND
13-Jun-12 5.0 10.0 12.5 6.5 J ND
11-Dec-12 5.0 10.0 ND Dry ND
29-Apr-13 5.0 10.0 10.2 10.8 ND
6-Aug-13 5.0 10.0 9.0 J ND ND
25-Feb-14 5.0 10.0 10.1 10.6 ND
13-Aug-14 5.0 10.0 ND ND ND
11-Mar-15 2.5 10.0 ND ND ND
19-Aug-15 2.5 10.0 ND Dry ND
18-Feb-16 2.5 10.0 ND ND ND
11-Aug-16 2.5 10.0 16.7 12.7 ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 6 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Copper 18-Jun-97 NR 200 11.0 ND NS
2-Dec-97 NR 200 11.0 ND NS
27-May-98 NR 200 21.0 ND NS
16-Nov-98 NR 200 14.0 16.0 NS
10-Sep-99 NR 200 ND ND NS
16-Nov-99 NR 200 ND ND NS
10-May-00 NR 200 ND ND NS
26-Oct-00 NR 200 ND ND NS
18-Apr-01 NR 200 ND ND NS
19-Nov-02 NR 200 NS ND NS
27-Jun-03 NR 200 ND ND NS
30-Dec-03 NR 200 ND ND ND
30-Jun-04 NR 200 ND ND ND
29-Dec-04 NR 200 ND ND ND
29-Jun-05 NR 200 ND ND ND
29-Dec-05 NR 200 ND ND ND
28-Jun-06 NR 200 ND ND ND
28-Dec-06 NR 10 3.0 B 3.9 0.60 J
NC 2B = 7 µg/L (05/01/07)12-Jul-07 NR 10 ND Dry ND
19-Dec-07 NR 10 23.7 B Dry 10.5 B
8-Jul-08 NR 10.0 14.7 Dry ND
16-Dec-08 0.30 10.0 6.4 J 8.0 J ND
8-Jul-09 0.30 10.0 7.0 J Dry ND
15-Dec-09 0.30 10.0 5.2 J 4.4 J ND
23-Jun-10 0.30 10.0 23.9 2.7 J ND
Resample >12-Aug-10 0.30 10.0 25.9 ND ND
14-Dec-10 0.30 10.0 21.1 Dry 0.49 J
21-Jun-11 5.0 10.0 7.7 J Dry ND
6-Dec-11 5.0 10.0 12.5 7.7 J ND
13-Jun-12 5.0 10.0 34.5 14.8 ND
11-Dec-12 5.0 10.0 16.4 Dry ND
29-Apr-13 5.0 10.0 7.7 J 7.4 J ND
6-Aug-13 5.0 10.0 5.5 J ND ND
25-Feb-14 5.0 10.0 11.2 10.3 ND
13-Aug-14 5.0 10.0 9.6 J 7.7 J ND
11-Mar-15 2.5 10.0 3.1 J 2.6 J ND
NC 2B = 2.7 µg/L 03/01/16)19-Aug-15 2.5 10.0 ND Dry ND
18-Feb-16 2.5 10.0 6.3 J 5.7 J ND
11-Aug-16 2.5 10.0 39.9 34.5 ND
Resample >13-Sep-16 2.5 10.0 9.3 (2.5 B)B DRY 3.5 B
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 7 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Lead 2-Dec-97 NR 10 ND 6.0 NS
27-May-98 NR 10 8.0 ND NS
16-Nov-98 NR 10 7.3 8.9 NS
10-Sep-99 NR 10 ND ND NS
16-Nov-99 NR 10 ND ND NS
10-May-00 NR 10 ND ND NS
26-Oct-00 NR 10 ND ND NS
18-Apr-01 NR 10 ND ND NS
19-Nov-02 NR 10 ND ND NS
27-Jun-03 NR 10 ND ND NS
30-Dec-03 NR 10 ND ND ND
30-Jun-04 NR 10 ND ND ND
29-Dec-04 NR 10 ND ND ND
29-Jun-05 NR 10 ND ND ND
29-Dec-05 NR 10 ND ND ND
28-Jun-06 NR 10 ND ND ND
28-Dec-06 NR 10 ND 4.8 J ND
NC 2B = 25 µg/L (05/01/07)12-Jul-07 NR 10 3.2 J Dry ND
19-Dec-07 NR 10 ND Dry ND
8-Jul-08 NR 10.0 ND Dry ND
16-Dec-08 4.0 10.0 ND ND ND
8-Jul-09 4.0 10.0 ND Dry ND
15-Dec-09 4.0 10.0 ND ND ND
23-Jun-10 4.0 10.0 9.2 J ND ND
14-Dec-10 4.0 10.0 5.1 J Dry ND
21-Jun-11 5.0 10.0 ND Dry ND
6-Dec-11 5.0 10.0 ND ND ND
13-Jun-12 5.0 10.0 14.3 5.5 J ND
11-Dec-12 5.0 10.0 ND Dry ND
29-Apr-13 5.0 10.0 ND ND ND
6-Aug-13 5.0 10.0 ND ND ND
25-Feb-14 5.0 10.0 ND ND ND
13-Aug-14 5.0 10.0 ND ND ND
11-Mar-15 2.5 10.0 ND ND ND
19-Aug-15 2.5 10.0 ND Dry ND
NC 2B = 14 µg/L 03/01/16)18-Feb-16 2.5 10.0 4.0 J 2.6 J ND
11-Aug-16 2.5 10.0 16.6 13.6 ND
Resample >13-Sep-16 2.5 10.0 4.1 (2.6 J)J DRY ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 8 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Nickel 28-Dec-06 NR 50 4.6 J 6.2 J ND
NC 2B = 88 µg/L (05/01/07)12-Jul-07 NR 50 4.0 J Dry ND
19-Dec-07 NR 50 21.9 Dry ND
8-Jul-08 NR 50.0 12.1 J Dry ND
16-Dec-08 1.7 50.0 5.2 B 6.8 B 2.4 J
8-Jul-09 1.7 50.0 10.0 J Dry ND
15-Dec-09 1.7 50.0 4.8 B 4.7 B 3.0 J
23-Jun-10 1.7 50.0 21.5 J ND ND
14-Dec-10 1.7 50.0 14.4 J Dry 2.7 J
21-Jun-11 5.0 50.0 5.8 J Dry ND
6-Dec-11 5.0 50.0 7.2 J ND ND
13-Jun-12 5.0 50.0 17.1 J 7.5 J ND
11-Dec-12 5.0 50.0 7.6 J Dry ND
29-Apr-13 5.0 50.0 ND ND ND
6-Aug-13 5.0 50.0 ND ND ND
25-Feb-14 5.0 50.0 7.3 J 6.6 J ND
13-Aug-14 5.0 50.0 7.5 J 5.4 J ND
11-Mar-15 2.5 50.0 3.0 J 2.8 J ND
19-Aug-15 2.5 50.0 ND Dry ND
18-Feb-16 2.5 50.0 3.3 J 3.0 J ND
11-Aug-16 2.5 50.0 22.8 J 19.4 J ND
Selenium 19-Dec-07 NR 10 15.6 Dry ND
NC 2B = 5 µg/L (05/01/07)8-Jul-08 NR 10.0 ND Dry ND
16-Dec-08 3.8 10.0 3.9 B ND 4.9 J
8-Jul-09 3.8 10.0 ND Dry ND
15-Dec-09 3.8 10.0 ND ND ND
NC 2L = 20 µg/L (2/5/10)23-Jun-10 3.8 10.0 ND ND ND
14-Dec-10 3.8 10.0 5.9 J Dry ND
21-Jun-11 10.0 10.0 ND Dry ND
6-Dec-11 10.0 10.0 ND ND ND
13-Jun-12 10.0 10.0 ND ND ND
11-Dec-12 10.0 10.0 ND Dry ND
29-Apr-13 10.0 10.0 ND ND ND
6-Aug-13 10.0 10.0 ND ND ND
25-Feb-14 10.0 10.0 ND ND ND
13-Aug-14 10.0 10.0 ND ND ND
11-Mar-15 5.0 10.0 ND ND ND
19-Aug-15 5.0 10.0 ND Dry ND
18-Feb-16 5.0 10.0 ND ND ND
11-Aug-16 5.0 10.0 ND 6.0 J ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 9 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Silver 8-Jul-08 NR 10.0 0.22 J Dry ND
NC 2B = 0.06 µg/L (05/01/07)16-Dec-08 0.10 10.0 ND 0.11 J ND
8-Jul-09 0.10 10.0 ND Dry ND
15-Dec-09 0.10 10.0 ND 0.19 J ND
NC 2L = 20 µg/L (2/5/10)23-Jun-10 0.10 10.0 ND ND ND
14-Dec-10 0.10 10.0 0.21 B Dry {0.25 J} 0.19 J
21-Jun-11 5.0 10.0 ND Dry ND
6-Dec-11 5.0 10.0 ND ND ND
13-Jun-12 5.0 10.0 ND ND ND
11-Dec-12 5.0 10.0 ND Dry ND
29-Apr-13 5.0 10.0 ND ND ND
6-Aug-13 5.0 10.0 ND ND ND
25-Feb-14 5.0 10.0 ND ND ND
13-Aug-14 5.0 10.0 ND ND ND
11-Mar-15 2.5 10.0 ND ND ND
19-Aug-15 2.5 10.0 ND Dry ND
18-Feb-16 2.5 10.0 ND ND ND
11-Aug-16 2.5 10.0 ND ND ND
Thallium 19-Dec-07 NR 5.5 5.1 J Dry ND
NC 2B = NE (05/01/07)8-Jul-08 NR 5.5 5.2 J Dry ND
16-Dec-08 3.0 5.5 ND ND ND
8-Jul-09 3.0 5.5 ND Dry ND
15-Dec-09 3.0 5.5 ND ND ND
23-Jun-10 3.0 5.5 ND ND ND
Resample >12-Aug-10 30.0 55.0 NS NS ND
GWPS = 0.2 µg/L (10/01/10)14-Dec-10 3.0 5.5 6.5 Dry ND
21-Jun-11 5.4 5.5 8.2 Dry ND
6-Dec-11 5.4 5.5 ND ND ND
13-Jun-12 5.4 5.5 ND ND ND
11-Dec-12 5.4 5.5 ND Dry ND
29-Apr-13 5.4 5.5 ND ND ND
6-Aug-13 5.4 5.5 ND ND ND
25-Feb-14 5.4 5.5 ND ND ND
13-Aug-14 5.4 5.5 ND ND ND
11-Mar-15 5.0 5.5 ND ND ND
19-Aug-15 5.0 5.5 ND Dry ND
18-Feb-16 5.0 5.5 ND ND ND
11-Aug-16 5.0 5.5 ND ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 10 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Vanadium 14-Nov-96 NR 40 11.0 5.0 NS
18-Jun-97 NR 40 20.0 ND NS
2-Dec-97 NR 40 16.0 ND NS
27-May-98 NR 40 44.0 ND NS
16-Nov-98 NR 40 44.0 47.0 NS
10-Sep-99 NR 40 ND ND NS
16-Nov-99 NR 40 ND ND NS
10-May-00 NR 40 ND ND NS
26-Oct-00 NR 40 ND ND NS
18-Apr-01 NR 40 ND ND NS
19-Nov-02 NR 40 ND ND NS
27-Jun-03 NR 40 ND ND NS
30-Dec-03 NR 40 ND ND ND
30-Jun-04 NR 40 ND ND ND
29-Dec-04 NR 40 ND ND ND
29-Jun-05 NR 40 ND ND ND
29-Dec-05 NR 40 ND ND ND
28-Jun-06 NR 40 ND ND ND
28-Dec-06 NR 25 8.6 J 10.7 ND
NC 2B = NE (05/01/07)12-Jul-07 NR 25 5.3 J ND ND
19-Dec-07 NR 25 41.2 ND 0.51 J
Resample >14-Feb-08 NR 25 12.4 Dry 0.24 J
Filtered >14-Feb-08 NR 25 1.6 J Dry ND
8-Jul-08 NR 25.0 38.2 Dry 0.20 J
16-Dec-08 0.20 25.0 11.5 J 14.1 J 0.76 J
8-Jul-09 0.20 25.0 24.3 J Dry 1.3 J
15-Dec-09 0.20 25.0 10 J 7.0 J 0.53 J
23-Jun-10 0.20 25.0 63.4 8.3 J ND
Resample >12-Aug-10 0.20 25.0 67.9 NS 0.33 J
14-Dec-10 0.20 25.0 52.3 Dry {0.57 J} 0.36 J
21-Jun-11 5.0 25.0 25.3 Dry ND
6-Dec-11 5.0 25.0 19.7 J 13.0 J ND
13-Jun-12 5.0 25.0 130 61.5 ND
11-Dec-12 5.0 25.0 50.7 Dry ND
29-Apr-13 5.0 25.0 16.9 J 18.4 J ND
6-Aug-13 5.0 25.0 15.4 J ND ND
25-Feb-14 5.0 25.0 29.2 29.4 ND
13-Aug-14 5.0 25.0 18.0 J 18.2 J ND
11-Mar-15 2.5 25.0 7.8 J 8.3 J ND
19-Aug-15 2.5 25.0 2.8 J Dry ND
18-Feb-16 2.5 25.0 6.4 J 6.1 J ND
11-Aug-16 2.5 25.0 160 144 ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 11 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Zinc 14-Sep-94 NR 50 ND ND NS
2-Dec-94 NR 50 61.0 ND NS
8-Feb-95 NR 50 ND ND NS
2-Mar-95 NR 50 64.0 ND NS
17-Nov-95 NR 50 ND ND NS
23-May-96 NR 50 ND ND NS
14-Nov-96 NR 50 ND ND NS
18-Jun-97 NR 50 26.0 ND NS
2-Dec-97 NR 50 32.0 40.0 NS
27-May-98 NR 50 57.0 28.0 NS
16-Nov-98 NR 50 28.0 31.0 NS
10-Sep-99 NR 50 ND ND NS
16-Nov-99 NR 50 ND ND NS
10-May-00 NR 50 ND ND NS
26-Oct-00 NR 50 ND ND NS
18-Apr-01 NR 50 ND ND NS
19-Nov-02 NR 50 NS ND NS
27-Jun-03 NR 50 ND ND NS
30-Dec-03 NR 50 ND ND ND
30-Jun-04 NR 50 ND ND ND
29-Dec-04 NR 50 ND ND ND
29-Jun-05 NR 50 ND ND ND
29-Dec-05 NR 50 ND ND ND
28-Jun-06 NR 50 ND ND ND
28-Dec-06 NR 10 7.4 J 8.5 J ND
NC 2B = 50 µg/L (05/01/07)12-Jul-07 NR 10 10.2 Dry ND
19-Dec-07 NR 10 24.1 B Dry 87.9
8-Jul-08 NR 10.0 17.2 Dry 1.2 J
16-Dec-08 0.40 10.0 8.9 J 11.9 ND
8-Jul-09 0.40 10.0 9.4 J Dry 1.6 J
15-Dec-09 0.40 10.0 8.3 B 8.5 B 7.7 J
23-Jun-10 0.40 10.0 29.3 4.0 J ND
14-Dec-10 0.40 10.0 25.1 B Dry 6.7 J
21-Jun-11 10.0 10.0 10.9 Dry ND
6-Dec-11 10.0 10.0 15.0 B 10.3 B 12.4
13-Jun-12 10.0 10.0 46.3 19.8 ND
11-Dec-12 10.0 10.0 25.4 Dry ND
29-Apr-13 10.0 10.0 13.8 12.5 ND
6-Aug-13 10.0 10.0 11.3 ND ND
25-Feb-14 10.0 10.0 15.0 14.8 ND
13-Aug-14 10.0 10.0 14.3 ND ND
11-Mar-15 5.0 10.0 62.3 11.6 B 6.1 J
NC 2B = 36 µg/L (03/01/16)19-Aug-15 5.0 10.0 ND Dry 11.5
18-Feb-16 5.0 10.0 13.0 11.0 ND
11-Aug-16 5.0 10.0 66.4 54.1 ND
Resample >13-Sep-16 5.0 10.0 14.5 (5.9 J)B DRY ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 12 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Organic Compounds
Acetone 15-Dec-09 2.2 100 3.9 B 3.2 B 2.8 J
NC 2B = NE (05/01/07)23-Jun-10 2.2 100 5.4 B 2.2 B 7.7 J
14-Dec-10 2.2 100 ND Dry ND
21-Jun-11 2.2 100 3.4 B Dry 3.9 J
6-Dec-11 2.2 100 ND ND 8.8 J
13-Jun-12 2.2 100 2.2 B ND 4.7 J
12-Dec-12 10.0 100 ND Dry ND
29-Apr-13 10.0 100 ND ND 14.6 J
6-Aug-13 10.0 100 ND ND ND
25-Feb-14 10.0 100 ND ND ND
13-Aug-14 10.0 100 ND ND 19.3 J
11-Mar-15 10.0 100 ND ND ND
19-Aug-15 10.0 100 ND Dry ND
18-Feb-16 10.0 100 ND ND ND
11-Aug-16 10.0 100 ND ND ND
2-Hexanone 23-Jun-10 0.46 50.0 1.5 J ND ND
NC 2B = NE (05/01/07)14-Dec-10 0.46 50.0 ND Dry ND
21-Jun-11 0.46 50.0 ND Dry ND
6-Dec-11 0.46 50.0 ND ND ND
13-Jun-12 0.46 50.0 ND ND ND
12-Dec-12 0.46 50.0 0.47 J Dry ND
29-Apr-13 0.46 50.0 ND ND ND
6-Aug-13 0.46 50.0 ND ND ND
25-Feb-14 0.46 50.0 ND ND ND
13-Aug-14 0.46 50.0 ND ND ND
11-Mar-15 0.46 50.0 ND ND ND
19-Aug-15 0.46 50.0 ND Dry ND
18-Feb-16 0.46 50.0 ND ND ND
11-Aug-16 0.46 50.0 1.2 J ND ND
Methylene Chloride 29-Apr-13 0.97 1.0 0.98 J ND ND
NC 2B = NE (05/01/07)6-Aug-13 0.97 1.0 ND ND ND
25-Feb-14 0.97 1.0 ND ND ND
13-Aug-14 0.97 1.0 ND ND ND
11-Mar-15 0.97 1.0 ND ND ND
19-Aug-15 0.97 1.0 ND Dry ND
18-Feb-16 0.97 1.0 ND ND ND
11-Aug-16 0.97 1.0 ND ND ND
Notes:
All concentrations are in micrograms per liter (µg/L).
RL = Reporting Limit (SWSL for December 2006 - present).
DL = Laboratory detection limit.
J = Estimated value between the DL and the RL.
B = Blank-qualified data; result is expected to be biased high based on concentrations in the blanks.
ND = Not detected above laboratory reporting limit.
NS = Not sampled.
NR = Not Reported.
Dry =Surface water point considered to be dry (12/14/10 SW-2 sample attempted, but stream was frozen solid).
NC 2B = North Carolina Surface Water Standards from 15A NCAC 2B.
NE = Not established.
Shaded values for surface water are above the NC 2B.
Surface waters are classified as fresh-water aquatic life.
Please see the report for information regarding NC 2B exceedences of surface water samples.
9/13/16 RESAMPLE= Parenthesis indicate Dissolved concentrations.
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 13 of 13
Joyce Engineering

Appendix G

Historical MNA Parameter Data

APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Temperature 30-Dec-03 oC 15.40 NI NA NS 12.51 13.58 NA NS NS NS NS
18-May-04 oC 14.05 NI NA NS 18.17 14.53 NA 15.04 17.15 12.86 16.41
30-Jun-04 oC 13.88 NI NA NS 14.33 14.18 NA 14.37 17.98 15.67 15.66
29-Dec-04 oC 14.30 NI NA NS 14.80 14.40 NA NS NS NS NS
28-Dec-06 ºC 11.60 NI 15.10 NS 14.60 13.40 14.50 14.30 NS 11.20 NS
11-Jul-07 ºC 15.90 NI 15.70 NS 17.30 15.90 19.00 NS NS NS NS
19-Dec-08 ºC 14.50 NM 13.50 12.30 12.80 15.70 12.40 13.90 14.30 12.50 13.20
8-Jul-09 ºC 14.80 NM 15.20 16.00 16.10 17.00 16.90 15.40 14.80 16.00 17.50
14-Dec-09 ºC 9.20 NM 12.50 12.80 12.70 12.50 11.30 13.70 14.60 13.20 13.40
23-Jun-10 ºC 18.50 NM 16.69 18.93 18.43 15.76 19.05 18.10 20.28 19.65 20.22
14-Dec-10 ºC Dry NM 11.80 11.31 10.63 12.20 13.20 12.12 NS 10.80 NS
21-Jun-11 ºC WL 15.26 15.90 15.85 17.20 15.66 18.20 15.56 18.40 18.33 16.53
6-Dec-11 ºC WL 16.75 16.70 15.99 16.18 14.97 15.70 15.10 15.01 15.37 14.77
13-Jun-12 ºC WL 18.18 15.60 16.60 15.88 14.90 17.50 15.50 15.60 19.20 17.07
11-Dec-12 ºC WL 16.70 15.00 16.60 16.10 14.90 15.10 15.80 15.20 16.30 15.10
29-Apr-13 ºC WL 16.40 15.90 17.20 16.70 14.90 17.00 15.20 15.20 14.60 16.20
6-Aug-13 ºC WL 18.2 15.9 18.1 18.3 16.1 16.7 15.4 NS 19.4 NS
25-Feb-14 ºC WL 14.9 14.1 15.7 13.4 14.6 13.0 12.6 12.5 12.5 12.5
13-Aug-14 ºC WL 22.4 19.7 19.8 17.3 16.1 15.9 NS NS 21.0 NS
12-Mar-15 ºC WL 13.9 11.6 17.0 11.6 12.5 15.2 NS NS 15.9 20.7
19-Aug-15 ºC WL 17.26 17.80 18.69 16.36 15.75 19.2 NS NS 19.04 NS
18-Feb-16 ºC WL 12.80 13.90 14.20 13.40 12.50 8.5 NS NS 11.3 14.1
11-Aug-16 ºC WL 16.7 15.8 17.3 18.9 18.8 18.4 NS NS 18.3 NS
pH 30-Dec-03 SU 7.31 NI NA NS 6.90 7.24 NA NS NS NS NS
[Field Test]18-May-04 SU 6.31 NI NA NS 7.27 6.39 NA 7.29 7.46 7.43 7.73
30-Jun-04 SU 8.03 NI NA NS 7.74 7.11 NA 6.70 6.79 6.93 7.64
29-Dec-04 SU 6.31 NI NA NS 7.47 6.67 NA NS NS NS NS
28-Dec-06 SU 7.50 NI 6.51 NS 7.38 6.46 8.02 6.06 NS 6.52 NS
11-Jul-07 SU 6.73 NI 6.58 NS 7.65 6.72 7.42 NS NS NS NS
19-Dec-08 SU 6.26 NM 5.92 7.81 7.10 6.63 7.03 7.61 5.81 8.12 7.35
8-Jul-09 SU 6.75 NM 7.90 6.13 8.43 7.86 7.46 8.12 8.43 5.93 8.64
14-Dec-09 SU 6.82 NM 6.76 6.20 7.65 6.70 7.23 6.38 7.50 7.43 6.86
23-Jun-10 SU 5.28 NM 5.45 5.90 6.98 6.11 6.69 5.52 7.35 5.71 6.92
14-Dec-10 SU Dry NM 7.09 5.92 7.61 6.12 7.20 5.67 NS 6.36 NS
21-Jun-11 SU WL 6.20 5.98 6.13 7.07 6.58 7.15 6.07 7.14 6.04 7.12
6-Dec-11 SU WL 6.79 6.10 6.61 7.54 6.73 6.92 6.28 7.05 6.46 7.17
13-Jun-12 SU WL 7.49 6.15 6.43 6.95 6.43 6.88 6.46 7.02 7.15 7.31
11-Dec-12 SU WL 6.48 6.15 7.47 7.38 6.25 6.92 5.79 6.99 5.99 7.60
29-Apr-13 SU WL 6.11 5.68 5.96 7.15 6.23 6.91 5.85 6.54 6.69 7.01
6-Aug-13 SU WL 6.29 7.56 5.96 7.00 6.48 6.96 7.23 NS 5.82 NS
25-Feb-14 SU WL 6.73 5.77 5.98 6.61 6.81 6.41 5.89 6.60 6.70 7.61
13-Aug-14 SU WL 6.16 6.86 6.16 7.11 6.69 6.79 NS NS 5.89 NS
12-Mar-15 SU WL 6.53 6.77 6.61 6.26 6.33 6.77 NS NS 6.50 7.49
19-Aug-15 SU WL 6.27 6.67 5.88 7.21 6.46 6.79 NS NS 5.88 NS
18-Feb-16 SU WL 6.89 6.56 6.55 6.36 6.23 5.69 NS NS 6.13 6.52
11-Aug-16 SU WL 4.55 6.17 4.83 4.67 4.66 4.84 NS NS 4.58 NS
Oxidation-Reduction Potential 30-Dec-03 mV 257.2 NI NS NS 212.7 187.3 NS NS NS NS NS
(ORP) (Redox Potential)18-May-04 mV 352.8 NI NS NS 158.6 173.2 NS 150.5 105.7 129.1 55.1
[Field Test]30-Jun-04 mV 275.0 NI NS NS 154.1 174.7 NS 182.8 223.0 179.4 199.7
28-Dec-06 mV 70.2 NI NS NS 72.6 75.8 NS 84.7 NS 69.3 NS
11-Jul-07 mV 281.0 NI NS NS 269.0 296.0 NS NS NS NS NS
19-Dec-08 mV 186.0 NM NS 210.0 181.0 149.0 NS 218.0 240.0 44.0 207.0
8-Jul-09 mV 104.0 NM NS 219.0 115.0 124.0 NS 144.0 146.0 160.0 159.0
14-Dec-09 mV 195.0 NM NS 138.0 175.0 92.0 NS 96.0 126.0 147.0 119.0
23-Jun-10 mV 139.6 NM NS 32.0 -15.0 52.8 NS 33.8 22.8 61.7 1.3
14-Dec-10 mV Dry NM NS 50.0 48.0 40.2 NS 42.5 NS 46.2 NS
21-Jun-11 mV WL 89.90 NS 52.8 38.1 50.8 NS 19.9 9.6 44.8 46.4
6-Dec-11 mV WL 119.6 NS 68.8 38.9 38.4 NS 28.1 25.0 75.1 87.0
13-Jun-12 mV WL -32.2 NS -14.3 136.0 67.5 NS -4.1 105.6 -18.1 21.8
11-Dec-12 mV WL 114.9 NS 158.8 105.5 98.9 NS 123.7 164.8 157.8 121.9
29-Apr-13 mV WL 78.4 NS 146.9 65.5 117.7 NS 61.3 90.0 142.3 74.3
6-Aug-13 mV WL 89.0 NS 110.6 62.3 83.7 NS 112.7 NS 101.0 NS
25-Feb-14 mV WL 102.3 NS 140.0 -44.2 137.8 NS 60.6 88.0 74.3 102.1
13-Aug-14 mV WL 76.0 NS NS NS 49.2 NS NS NS 90.4 NS
12-Mar-15 mV WL 71.8 NS NS NS 68.1 NS NS NS 72.2 49.6
19-Aug-15 mV WL 61.9 NS NS NS 22.5 NS NS NS 57.9 NS
18-Feb-16 mV WL 104.2 NS NS NS 123.5 NS NS NS 105.7 52.9
11-Aug-16 mV WL 58.5 NS NS NS 48.7 NS NS NS 61.9 NS
Conductivity 28-Dec-06 µS/cm 65.3 NI 104.8 NS 588.0 355.0 642.0 173.4 NS 172.2 NS
[Field Test]11-Jul-07 µS/cm 62.5 NI 122.4 NS 631.0 373.0 604.0 NS NS NS NS
19-Dec-08 µS/cm 61.0 NM 100.4 291.0 562.0 384.0 530.0 155.0 1137.0 165.0 376.0
8-Jul-09 µS/cm 17.7 NM 111.8 377.0 625.0 421.0 578.0 321.0 792.0 159.0 369.0
14-Dec-09 µS/cm 60.2 NM 83.6 304.0 564.0 373.0 540.0 374.0 527.0 109.7 382.0
23-Jun-10 µS/cm 38.0 NM 68.0 269.0 540.0 347.0 528.0 282.0 466.0 111.0 427.0
14-Dec-10 µS/cm Dry NM 114.3 229.0 355.0 294.0 589.0 236.0 NS 104.0 NS
21-Jun-11 µS/cm WL 230.0 123.5 279.0 568.0 368.0 633.0 297.0 640.0 103.0 401.0
6-Dec-11 µS/cm WL 237.0 104.3 251.0 548.0 360.0 607.0 348.0 518.0 129.0 331.0
13-Jun-12 µS/cm WL 259.0 82.7 246.0 553.0 416.0 586.0 405.0 641.0 122.0 392.0
11-Dec-12 µS/cm WL 222.2 101.6 246.5 548.0 432.0 624.0 204.6 575.0 165.6 354.5
29-Apr-13 µS/cm WL 215.7 75.7 242.3 562.0 328.9 537.0 389.1 609.0 98.8 356.7
6-Aug-13 µS/cm WL 286.8 81.9 292.7 636.0 414.8 590 272.4 NS 151.2 NS
25-Feb-14 µS/cm WL 231.3 61.5 289.2 470.2 399.2 502 341.1 450.8 95.3 288.3
13-Aug-14 µS/cm WL 307.3 95.4 283.0 634.0 452.4 591 NS NS 135.2 NS
12-Mar-15 µS/cm WL 123.4 36.9 222.8 482.9 323.5 553 NS NS 114.2 447.9
19-Aug-15 µS/cm WL 28.4 13.4 215.0 565.0 386.0 556 NS NS 112.0 NS
18-Feb-16 µS/cm WL 250.0 88.7 220.8 547.0 311.6 380 NS NS 95.7 293.9
11-Aug-16 µS/cm WL 287.1 79.9 232.0 670.0 434.4 704 NS NS 123.7 NS
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 1 of 8 Joyce Engineering
APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Ferrous Iron (Fe2+)30-Dec-03 0.1 mg/L ND NI NS NS ND ND NS NS NS NS NS
[Field Test]18-May-04 0.1 mg/L ND NI NS NS ND 0.5 NS ND ND ND ND
30-Jun-04 0.1 mg/L ND NI NS NS ND ND NS ND ND ND NS
28-Dec-06 0.1 mg/L 0.0 NI NS NS 0.0 0.0 NS 0.0 NS 0.0 NS
11-Jul-07 0.1 mg/L 0.2 NI NS NS 0.1 0.0 NS NS NS NS NS
19-Dec-08 0.1 mg/L 0.0 NM NS 0.0 0.0 0.0 NS 0.0 0.0 0.0 0.0
8-Jul-09 0.1 mg/L 0.0 NM NS 0.0 0.0 0.0 NS 1.8 0.0 0.0 0.0
14-Dec-09 0.1 mg/L 0.0 NM NS 0.0 0.0 0.0 NS 2.0 0.0 0.0 0.0
23-Jun-10 0.1 mg/L 0.0 NM NS 0.0 0.0 0.0 NS 4.1 0.0 0.0 0.0
14-Dec-10 0.1 mg/L Dry NM NS 0.0 0.0 0.0 NS 1.1 NS 0.0 NS
21-Jun-11 NR NS WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR NS WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 0.1 mg/L WL 0.0 NS NS NS NS NS NS NS NS NS
11-Dec-12 NR NS WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR mg/L WL 0.0 NS 0.0 0.0 0.0 NS 3.5 0.0 0.0 0.0
6-Aug-13 NR mg/L WL 0.0 NS 0.0 0.0 0.0 NS 1.0 NS 0.75 NS
25-Feb-14 NR mg/L WL 0.0 NS 0.0 0.0 0.0 NS 2.0 0.0 1.0 0.0
13-Aug-14 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
12-Mar-15 0.1 mg/L WL 0.0 NS NS NS 0.0 NS NS NS 0.5 0.0
19-Aug-15 1.1 mg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 1.1 mg/L WL 0.0 NS NS NS 0.0 NS NS NS 1.0 0.0
11-Aug-16 1.1 mg/L WL 0.0 NS NS NS 0.0 NS NS NS 0.5 NS
Dissolved Carbon Dioxide 11-Jul-07 mg/L 60 NI NS NS 50 100 NS NS NS NS NS
[Field Test]19-Dec-08 mg/L 30 NM NS 60 25 102 NS 40 35 35 30
8-Jul-09 mg/L 28 NM NS 120 50 170 NS 175 40 116 40
14-Dec-09 mg/L 40 NM NS 130 50 50 NS 235 30 70 60
23-Jun-10 mg/L 40 NM NS 160 65 140 NS 300 60 90 30
14-Dec-10 mg/L Dry NM NS 135 60 136 NS 435 NS 50 NS
21-Jun-11 NS WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NS WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 mg/L WL 60 NS NS NS NS NS NS NS NS NS
11-Dec-12 NS WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 mg/L WL 65 NS 55 35 70 NS 85 65 15 55
6-Aug-13 mg/L WL 50 NS 120 55 115 NS 155 NS 45 NS
25-Feb-14 mg/L WL 55 NS 95 60 85 NS 95 50 30 55
13-Aug-14 mg/L WL NS NS NS NS NS NS NS NS NS NS
12-Mar-15 mg/L WL 45 NS NS NS 50 NS NS NS 35 20
19-Aug-15 mg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 mg/L WL 55 NS NS NS 45 NS NS NS 105 85
11-Aug-16 mg/L WL 70 NS NS NS 75 NS NS NS 90 NS
Dissolved Oxygen (DO)30-Dec-03 0.01 mg/L 9.49 NI NS NS 24.19 15.31 NS NS NS NS NS
[Field Test]18-May-04 0.01 mg/L 7.15 NI NS NS 11.77 1.15 NS 3.48 19.25 2.24 10.70
30-Jun-04 0.01 mg/L -NI NS NS --NS 12.71 9.20 3.59 4.37
28-Dec-06 0.01 mg/L 10.30 NI NS NS 3.18 7.99 NS 1.62 NS 5.11 NS
11-Jul-07 0.01 mg/L 8.20 NI NS NS 3.70 3.60 NS NS NS NS NS
19-Dec-08 0.01 mg/L 2.86 NM NS 4.38 3.56 1.55 NS 1.22 NS NS 8.10
8-Jul-09 0.01 mg/L 2.78 NM NS 1.98 0.88 0.48 NS 0.54 4.51 0.91 7.76
14-Dec-09 0.01 mg/L 1.34 NM NS 4.50 3.46 2.96 NS 0.57 NS 1.89 NS
23-Jun-10 0.01 mg/L 4.09 NM NS 3.35 3.49 2.89 NS 4.76 7.98 1.56 6.06
14-Dec-10 0.01 mg/L Dry NM NS 8.18 4.55 2.97 NS 1.60 NS 5.85 NS
21-Jun-11 0.01 mg/L WL 7.57 NS 3.94 2.68 3.49 NS 1.55 9.12 2.63 6.20
6-Dec-11 0.01 mg/L WL 3.82 NS 6.24 3.13 2.01 NS 1.50 8.50 1.79 8.08
13-Jun-12 0.01 mg/L WL 13.78 NS 16.46 12.22 11.31 NS 12.57 12.69 13.09 16.32
11-Dec-12 0.01 mg/L WL 3.51 NS 3.38 3.17 6.21 NS 0.86 8.72 1.53 7.93
29-Apr-13 0.01 mg/L WL 3.51 NS 1.27 2.75 1.87 NS 0.98 9.04 2.01 6.68
6-Aug-13 0.01 mg/L WL 2.56 NS 1.26 2.08 1.33 NS 2.43 NS 1.38 NS
25-Feb-14 0.01 mg/L WL 3.90 NS 2.11 1.42 1.42 NS 1.69 8.33 1.88 7.12
13-Aug-14 0.01 mg/L WL 3.96 NS NS NS 4.14 NS NS NS 2.22 NS
12-Mar-15 0.01 mg/L WL 3.62 NS NS NS 1.24 NS NS NS 0.74 6.17
19-Aug-15 0.01 mg/L WL 5.29 NS NS NS 2.46 NS NS NS 2.74 NS
18-Feb-16 0.01 mg/L WL 3.51 NS NS NS 2.59 NS NS NS 2.54 7.07
11-Aug-16 0.01 mg/L WL 3.60 NS NS NS 1.45 NS NS NS 1.75 NS
Dissolved Hydrogen 19-Dec-08 0.600 nM 0.920 NM NS 1.300 2.500 1.300 NS 1.100 NS 1.1 NS
8-Jul-09 1.600 nM NS(dry)NM NS 1.100 2.100 1.400 NS 1.900 4.200 4.900 NS(dry)
14-Dec-09 0.600 nM 1.000 NM NS 1.100 3.000 1.000 NS 0.880 2.500 0.750 NS(dry)
23-Jun-10 0.600 nM 4.400 NM NS 4.500 5.600 3.700 NS 4.000 9.100 4.000 NS(dry)
14-Dec-10 0.600 nM Dry NM NS 0.800 1.500 1.000 NS 1.000 NS 0.620 NS(dry)
21-Jun-11 0.600 nM WL 1.30 NS 1.400 2.900 1.400 NS 1.100 3.800 1.100 NS(dry)
6-Dec-11 0.60 nM WL 2.4 NS 3.6 5.4 5.6 NS 5.3 5.2 3.4 NS(dry)
13-Jun-12 0.60 nM WL 0.81 NS 2.7 4.7 3.8 NS 2.8 3.5 0.83 NS(dry)
11-Dec-12 0.60 nM WL 0.53 J NS 0.46 J 3.0 0.6 NS 0.056 J 0.53 J 0.22 J NS
29-Apr-13 0.60 nM WL 0.38 J NS 0.41 J 1.9 NS NS 0.37 J 1.3 0.39 J 0.42 J
6-Aug-13 0.60 nM WL 0.84 NS 0.98 0.83 0.79 NS 1.0 NS 0.84 NS
25-Feb-14 0.60 nM WL 0.65 NS 0.92 0.77 0.86 NS 1.1 0.81 0.70 0.81
13-Aug-14 0.60 nM WL 1.3 NS NS NS 1.2 NS NS NS 1.1 NS
12-Mar-15 0.60 nM WL 1.5 NS NS NS -NS NS NS 1.2 1.5
30-Apr-15 0.60 nM WL NS NS NS NS 1.5 NS NS NS NS NS
19-Aug-15 0.60 nM WL 1.6 NS NS NS 2.0 NS NS NS 1.7 NS
18-Feb-16 0.60 nM WL 2.9 NS NS NS 10.0 NS NS NS 2.2 NS
11-Aug-16 0.60 nM WL 0.9 NS NS NS 1.6 NS NS NS 1.3 NS
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 2 of 8 Joyce Engineering
APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Chloride 30-Dec-03 1 mg/L 3 NI NS NS 17 24 NS NS NS NS NS
18-May-04 1 mg/L 3.2 NI NS NS 26 26 NS 6.3 16 6.2 9.1
30-Jun-04 1 mg/L 2.5 NI NS NS 28 26 NS 8.1 15 7.8 4.3
28-Dec-06 5 mg/L 1.8 NI NS NS 22 18 NS 4.7 NS 6.6 NS
11-Jul-07 5 mg/L 0.66 (2.6)NI NS NS 17 (34)15 (29)NS NS NS NS NS
19-Dec-08 5 mg/L 5.7 NM NS 37.0 39.4 36.4 NS 16.0 10.8 12.6 6.2
8-Jul-09 5 mg/L 6.8 NM NS 46.8 39.1 38.6 NS 23.1 11.3 7.7 28.4
14-Dec-09 5.0 mg/L ND NM NS 36.4 38.8 37.6 NS 33.0 11.5 5.5 6.2
23-Jun-10 5.0 mg/L 7.95 NM ND 37.4 40.0 39.7 97.9 17.6 13.4 5.97 6.5
14-Dec-10 5.0 mg/L Dry NM 5.1 38.4 44.5 39.6 108.0 29.1 NS 16.40 NS
NC-2L 250,000 ug/L 21-Jun-11 5.0 mg/L WL 8.6 ND 35.8 45.3 41.4 106.0 23.3 13.5 6.60 6.07
6-Dec-11 5.0 nM WL 9.34 ND 28.6 49.2 39.2 110.0 47.8 22.5 13.9 6.2
13-Jun-12 5.0 mg/L WL 9.41 4.54 29.4 49.3 46.4 109.0 44.4 26.7 7.77 6.36
11-Dec-12 1.0 mg/L WL 8.57 5.22 30.8 50.6 46.6 107.0 40.1 25.7 15.6 6.26
29-Apr-13 1.0 mg/L WL 9.55 4.12 30.0 49.8 22.3 122.0 44.9 31.1 5.84 6.08
6-Aug-13 1.0 mg/L WL 7.59 5.18 25.7 50.1 48.7 107.0 24.8 NS 7.05 NS
25-Feb-14 1.0 mg/L WL 9.22 5.51 33.2 60.3 57.4 120.0 26.9 29.2 5.39 6.53
13-Aug-14 1.0 mg/L WL 8.03 4.07 21.3 97.6 43.4 106.0 NS NS 5.61 NS
12-Mar-15 1.0 mg/L WL 8.84 43.5 20.7 51.7 42.6 121.0 NS NS 5.81 5.58
19-Aug-15 1.0 mg/L WL 9.44 5.16 23.2 51.5 48.5 111.0 NS NS 6.35 NS
18-Feb-16 1.0 mg/L WL 17.20 4.60 20.6 69.5 49.7 153.0 NS NS 6.28 5.65
11-Aug-16 1.0 mg/L WL NS NS NS NS NS NS NS NS 7.08 NS
Nitrate 30-Dec-03 0.10 mg/L 0.23 NI NS NS ND ND NS NS NS NS NS
18-May-04 0.10 mg/L 0.21 NI NS NS ND ND NS ND 1.10 0.14 ND
30-Jun-04 0.10 mg/L 0.15 NI NS NS ND ND NS ND 0.95 0.20 ND
28-Dec-06 100.0 mg/L 0.15 NI NS NS 0.51 0.33 NS 0.36 NS 0.43 NS
11-Jul-07 100.0 mg/L 0.14 NI NS NS 0.111 0.031 NS NS NS NS NS
19-Dec-08 100.0 mg/L ND NM NS ND ND ND NS ND ND ND ND
8-Jul-09 200.0 mg/L ND NM NS ND ND ND NS ND ND ND 0.30
14-Dec-09 0.10 mg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 0.10 mg/L ND NM NS ND ND ND NS ND ND 183 107
14-Dec-10 0.10 mg/L Dry NM NS ND ND ND NS ND NS ND NS
21-Jun-11 0.10 mg/L WL ND NS ND ND ND NS ND ND 0.146 ND
6-Dec-11 0.10 mg/L WL ND NS ND ND ND NS ND ND ND ND
13-Jun-12 0.10 mg/L WL 0.181 NS 0.0743 ND ND NS ND 0.0798 0.162 0.251
11-Dec-12 10.00 mg/L WL 0.115 J NS 0.0655 J ND 0.0326 J NS 0.0557 J 0.022 ND 0.192 J
29-Apr-13 0.02 mg/L WL 0.0938 NS 0.0280 ND ND NS ND 0.0298 0.0851 0.141
6-Aug-13 10.00 mg/L WL 0.0999 J NS ND ND ND NS ND NS ND NS
25-Feb-14 10.00 mg/L WL NS NS ND ND ND ND ND ND ND 0.417 J
13-Aug-14 10.00 mg/L WL 0.144 J NS NS NS ND NS NS NS ND NS
12-Mar-15 10.00 mg/L WL 0.134 J NS NS NS 0.0224 J NS NS NS ND 0.229 J
19-Aug-15 10.00 mg/L WL 0.186 J NS NS NS ND NS NS NS ND NS
18-Feb-16 10.00 mg/L WL 0.179 J NS NS NS 0.0373 J NS NS NS ND 0.122 J
11-Aug-16 10.00 mg/L WL 0.196 J NS NS NS 0.0211 J NS NS NS 0.0126 J NS
Nitrite 28-Dec-06 mg/L <0.100 NI NS NS <0.100 <0.100 NS <0.100 NS <0.100 NS
11-Jul-07 mg/L <0.1 NI NS NS <0.1 <0.1 NS NS NS NS NS
14-Dec-10 mg/L Dry NM NS NS NS NS NS NS NS NS NS
21-Jun-11 mg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 mg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 mg/L WL NS NS NS NS NS NS NS NS NS NS
11-Dec-12 mg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 mg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 mg/L WL NS NS NS NS NS NS NS NS NS NS
25-Feb-14 mg/L WL NS NS NS NS NS NS NS NS NS NS
13-Aug-14 mg/L WL NS NS NS NS NS NS NS NS NS NS
12-Mar-15 mg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 mg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 mg/L WL NS NS NS NS NS NS NS NS NS NS
11-Aug-16 mg/L WL NS NS NS NS NS NS NS NS NS NS
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 3 of 8 Joyce Engineering
APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Sulfate 30-Dec-03 2.0 mg/L 4.0 NI NS NS 17 2.7 NS NS NS NS NS
18-May-04 2.0 mg/L 3.3 NI NS NS 40 2.8 NS 21 120 5.6 13
30-Jun-04 2.0 mg/L ND NI NS NS 29 ND NS 5.5 180 4.7 12
28-Dec-06 5 mg/L 0.03 NI NS NS 10 4.6 NS 5.2 NS 12 NS
11-Jul-07 5 mg/L 1.6 NI NS NS 13 2.2 NS NS NS NS NS
19-Dec-08 5 mg/L 11.2 NM NS 9.6 9 ND NS 5.3 191 16.1 18.3
8-Jul-09 5 mg/L 1140 NM NS 8.4 9.3 ND NS 5.2 161 8.4 39.2
14-Dec-09 5 mg/L ND NM NS 6.9 7.3 ND NS ND 79.5 6.5 49.7
23-Jun-10 5 mg/L 5.16 NM 14.8 7.18 9.14 ND ND ND ND 25.1 ND
14-Dec-10 5 mg/L Dry NM 14.5 9.21 9.7 ND ND 5.38 NS 10.80 NS
21-Jun-11 5 mg/L WL 24.4 11.4 7.49 7.74 ND ND ND 91.9 ND ND
NC-2L 250,000 ug/L 6-Dec-11 5 mg/L WL ND NS ND ND ND NS ND 31.4 11.80 52.9
13-Jun-12 5 mg/L WL 25.4 13.7 8.14 8.4 2.79 3.04 4.70 24.5 5.38 83.1
11-Dec-12 2 mg/L WL 28.0 J 14.8 J 9.12 J 10.1 J 4.42 J 2.90 J 3.16 J 36.0 7.91 J 78.8
29-Apr-13 250 mg/L WL 26.1 J 12.3 J 9.15 J 17.1 J 2.73 J 3.20 J 5.23 J 57.0 J 4.61 J 73.8 J
6-Aug-13 250 mg/L WL 25.3 J 7.37 J 7.83 J 11.7 J 2.76 J 3.32 J 4.29 J NS 5.07 J NS
25-Feb-14 250 mg/L WL 28.9 J 11.2 J 8.13 J 9.55 J 2.59 J 4.62 J 3.59 J 10.4 J 33.8 J 4.56 J
13-Aug-14 250 mg/L WL 31.9 J 9.37 J 7.91 J 11.6 J 2.45 J 2.78 J NS NS 4.46 J NS
12-Mar-15 250 mg/L WL 32.6 J 12.1 J 8.04 J 8.34 J 3.34 J 3.33 J NS NS 4.81 J 83.4 J
19-Aug-15 250 mg/L WL 42.9 J 102 J 8.11 J 10.4 J 2.89 J 3.21 J NS NS 4.93 J NS
18-Feb-16 250 mg/L WL 39.9 J 112 J 7.96 J 10.3 J 3.83 J 3.31 NS NS 4.84 J 54.7 J
11-Aug-16 250 mg/L WL NS NS NS NS NS NS NS NS 5.33 J NS
Sulfide 30-Dec-03 1.0 mg/L ND NI NS NS 5.0 ND NS NS NS NS NS
18-May-04 1.0 mg/L ND NI NS NS ND ND NS ND ND ND ND
30-Jun-04 1.0 mg/L ND NI NS NS ND ND NS ND ND ND ND
19-Dec-08 1000 µg/L 259 J NM ND 150 J ND 141 J ND ND ND ND ND
8-Jul-09 1000 µg/L ND NM ND ND ND ND ND ND ND ND ND
14-Dec-09 1000 µg/L ND NM ND ND ND ND ND ND ND ND ND
23-Jun-10 1000 µg/L ND NM ND ND ND ND ND ND ND ND ND
14-Dec-10 1000 µg/L Dry NM ND ND ND ND ND ND NS ND NS
21-Jun-11 1000 µg/L WL ND ND ND ND ND ND NS NS NS NS
6-Dec-11 1000 µg/L WL ND ND ND ND ND ND NS NS NS NS
13-Jun-12 1000 µg/L WL ND ND ND ND ND ND NS NS NS NS
11-Dec-12 1000 µg/L WL ND ND ND ND 117 J NS NS NS NS NS
29-Apr-13 1000 µg/L WL ND ND ND ND ND ND NS NS NS NS
6-Aug-13 1000 µg/L WL ND ND ND ND ND ND ND NS ND NS
25-Feb-14 1000 µg/L WL ND ND ND ND ND ND ND ND ND ND
13-Aug-14 1000 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 1000 µg/L WL ND NS NS NS ND NS NS NS ND NS
19-Aug-15 1000 µg/L WL ND NS NS NS ND NS NS NS ND NS
18-Feb-16 1000 µg/L WL ND NS NS NS ND NS NS NS ND NS
11-Aug-16 1000 mg/L WL NS NS NS NS NS NS NS NS NS NS
Hydrogen Sulfide 30-Dec-03 1.0 mg/L ND NI NS NS 21 ND NS NS NS NS NS
18-May-04 1.0 mg/L ND NI NS NS ND ND NS ND ND ND ND
30-Jun-04 1.0 mg/L ND NI NS NS ND ND NS ND ND ND ND
28-Dec-06 1.0 mg/L ND NI NS NS ND ND NS ND NS ND NS
11-Jul-07 1.0 mg/L ND NI NS NS ND ND NS ND NS ND NS
14-Dec-10 NR mg/L Dry NM NS NS NS NS NS NS NS NS NS
21-Jun-11 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 1.0 mg/L WL NS NS NS NS NS NS NS NS NS NS
11-Dec-12 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
25-Feb-14 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
13-Aug-14 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
12-Mar-15 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
11-Aug-16 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 4 of 8 Joyce Engineering
APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Total Organic Carbon (TOC)11-Jul-07 1 mg/L 0.48 NI NS NS 3.2 1.9 NS NS NS NS NS
19-Dec-08 1 mg/L 6.3 NM NS 48 24.7 21.1 NS 21.2 22.8 11.4 19.1
8-Jul-09 1 mg/L 28.1 NM NS 6.6 5.9 6.2 NS 3.4 5.7 4.2 4.4
14-Dec-09 1 mg/L 3.0 NM NS 32.4 48.2 ND NS 11.5 5.0 2.9 3.8
23-Jun-10 1 mg/L 3.7 NM NS 3.16 5.8 6.07 NS 2.91 5.96 2.82 3.61
14-Dec-10 1 mg/L Dry NM NS 23.7 7.52 7.77 NS 23 NS 5.01 NS
21-Jun-11 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 1 mg/L WL 3.71 NS NS NS NS NS NS NS NS NS
11-Dec-12 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 1 mg/L WL 4.68 NS 7.42 8.93 9.63 NS 12.4 NS 4.08 NS
25-Feb-14 1 mg/L WL NS NS 8.62 20.4 19.9 NS 33.7 26.2 9.50 8.03
13-Aug-14 1 mg/L WL 4.55 NS NS NS 8.34 NS NS NS 4.33 NS
12-Mar-15 1 mg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 1 mg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 1 mg/L WL NS NS NS NS NS NS NS NS NS NS
11-Aug-16 1 mg/L WL NS NS NS NS NS NS NS NS NS NS
Alkalinity 30-Dec-03 10 mg/L 14 NI NS NS 90 130 NS NS NS NS NS
(total as CaCO3)18-May-04 10 mg/L ND NI NS NS 210 140 NS 56 260 63 81
30-Jun-04 10 mg/L 11 NI NS NS 240 160 NS 120 280 46 130
28-Dec-06 5 mg/L 10 NI NS NS 255 133 NS 57 NS 42 NS
11-Jul-07 5 mg/L 20 NI NS NS 220 150 NS NS NS NS NS
19-Dec-08 5 mg/L 18.9 NM NS 88.2 296 163 NS 76.7 202 44.2 222
8-Jul-09 6 mg/L 16.5 NM NS 110 301 176 NS 137 278 44.0 155
14-Dec-09 5 mg/L 6.7 NM NS 82.1 253 135 NS 134 210 29.6 137
23-Jun-10 5 mg/L 7.29 NM 20.4 99.8 291 169 178.0 134 262 39.7 170
14-Dec-10 5 mg/L Dry NM 17.6 99.6 292 168 156 168 NS 39.4 NS
21-Jun-11 5 mg/L WL 100 20.8 77 269 194 156 128 288.0 42.2 153.0
6-Dec-11 5 mg/L WL 98.7 10.5 81.9 274 164 151 146 297 35.7 144
13-Jun-12 5 mg/L WL 101 13.7 87.5 271 152 149 152 309 46.2 147
11-Dec-12 5 mg/L WL 100 16.5 98.3 284 147 152 130 339 44.6 148
29-Apr-13 5 mg/L WL 99.3 13.8 97.3 293 156 153 180 339 46.2 143
6-Aug-13 5 mg/L WL 102 14.3 99.1 148 86.8 159 123 NS 43.3 NS
25-Feb-14 5 mg/L WL 98 15.8 123 298 178 153 145 303 164 3.87
13-Aug-14 5 mg/L WL 103 14.3 93.8 301 187 164 NS NS 49.8 NS
12-Mar-15 5 mg/L WL 99.7 14.7 88.3 306 151 164 NS NS 39.5 139
19-Aug-15 5 mg/L WL 102 19.6 88.2 294 180 164 NS NS 46.9 NS
18-Feb-16 5 mg/L WL 108 4.35 J 89.8 308 141 168 NS NS 49.6 150
11-Aug-16 5 mg/L WL NS NS NS NS NS NS NS NS 51.6 NS
Ethane 30-Dec-03 0.001 mg/L ND NI NS NS ND ND NS NS NS NS NS
18-May-04 0.001 mg/L ND NI NS NS ND ND NS ND ND ND ND
30-Jun-04 0.001 mg/L ND NI NS NS ND ND NS ND ND ND ND
28-Dec-06 20.0 mg/L ND NI NS NS ND ND NS ND NS ND NS
11-Jul-07 20.0 mg/L ND NI NS NS ND ND NS NS NS NS NS
19-Dec-08 20.0 µg/L ND NM NS ND ND ND NS ND ND ND ND
8-Jul-09 10.0 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-09 10.0 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 10.0 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-10 10.0 µg/L Dry NM NS ND ND ND NS ND NS ND NS
21-Jun-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 10.0 µg/L WL NS NS NS NS NS NS NS NS NS NS
11-Dec-12 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 6.2 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-14 6.2 µg/L WL NS NS ND ND ND NS ND ND ND ND
13-Aug-14 6.2 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 6.2 µg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 6.2 µg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 6.2 µg/L WL NS NS NS NS NS NS NS NS NS NS
11-Aug-16 6.2 µg/L WL NS NS NS NS NS NS NS NS NS NS
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 5 of 8 Joyce Engineering
APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Ethylene (Ethene)30-Dec-03 0.001 mg/L ND NI NS NS ND ND NS NS NS NS NS
18-May-04 0.001 mg/L ND NI NS NS ND ND NS ND ND ND ND
30-Jun-04 0.001 mg/L ND NI NS NS ND ND NS ND ND ND ND
28-Dec-06 20.0 mg/L ND NI NS NS ND ND NS ND NS ND NS
11-Jul-07 20.0 mg/L ND NI NS NS ND ND NS NS NS NS NS
19-Dec-08 20.0 µg/L ND NM NS ND ND ND NS ND ND ND ND
8-Jul-09 10.0 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-09 10.0 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 11.0 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-10 10.0 µg/L Dry NM NS ND ND ND NS ND NS ND NS
21-Jun-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 10.0 µg/L WL NS NS NS NS NS NS NS NS NS NS
11-Dec-12 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 6.2 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-14 6.2 µg/L WL NS NS ND ND ND NS ND ND ND ND
13-Aug-14 6.2 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 6.2 µg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 6.2 µg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 6.2 µg/L WL NS NS NS NS NS NS NS NS NS NS
11-Aug-16 6.2 µg/L WL NS NS NS NS NS NS NS NS NS NS
Methane 30-Dec-03 0.001 mg/L ND NI NS NS 1.8 0.1 NS NS NS NS NS
18-May-04 0.001 mg/L ND NI NS NS 1.50 0.12 NS 0.09 0.46 0.004 ND
30-Jun-04 0.001 mg/L ND NI NS NS 0.66 0.06 NS 0.26 ND ND ND
28-Dec-06 10.0 mg/L 0.01 NI NS NS 0.173 0.044 NS 0.021 NS 0.001 NS
11-Jul-07 10.0 mg/L 0.001 NI NS NS 0.189 0.008 NS NS NS NS NS
19-Dec-08 10.0 mg/L ND NM NS 0.0054 J 0.162 0.102 NS 0.0164 ND ND ND
8-Jul-09 10.0 mg/L ND NM NS 0.0202 0.088 0.128 NS 0.226 ND ND ND
14-Dec-09 10.0 mg/L ND NM NS 0.0083 J 0.0205 0.0648 NS 1.130 ND ND ND
23-Jun-10 0.010 mg/L 0.0018 B NM NS 0.0117 B 0.064 0.101 NS 0.415 0.002 B 0.0012 B 0.0013 B
14-Dec-10 0.010 mg/L Dry NM NS 0.0025 J 0.155 0.102 NS 0.510 NS ND NS
21-Jun-11 0.010 mg/L WL 0.0016 J NS 0.099 J 0.103 0.108 NS 0.770 0.0017 J 0.0014 J 0.0017 J
6-Dec-11 0.010 mg/L WL ND NS 0.009 J 0.032 0.086 NS 0.376 ND ND ND
13-Jun-12 0.010 mg/L WL 0.0011 J NS 0.0062 J 0.0524 0.0698 NS 0.157 0.0017 J 0.0015 J 0.0013 J
11-Dec-12 0.01 mg/L WL ND NS 0.0036 0.0825 0.0506 NS 0.183 ND ND ND
29-Apr-13 0.01 mg/L WL ND NS 0.0180 0.0737 0.0923 NS 1.290 ND ND ND
6-Aug-13 0.0066 mg/L WL ND NS 0.0229 0.0590 0.113 NS 0.284 NS 0.060 NS
25-Feb-14 0.0066 mg/L WL ND NS 0.0170 0.0703 0.0263 NS 0.498 ND ND ND
13-Aug-14 0.0066 mg/L WL ND NS NS NS 0.108 NS NS NS 0.339 NS
12-Mar-15 0.0066 mg/L WL ND NS NS NS 0.0188 NS NS NS 0.330 0.0119
19-Aug-15 0.0066 mg/L WL 0.89 J NS NS NS 0.0398 NS NS NS 0.340 NS
18-Feb-16 0.0066 mg/L WL 0.0018 J NS NS NS 0.0218 NS NS NS 0.512 0.0019 J
11-Aug-16 0.0066 mg/L WL 0.0025 J NS NS NS 0.0676 NS NS NS 0.409 NS
Pyruvic Acid 28-Dec-06 100 µg/L ND NI NS ND ND ND NS ND ND ND NS
19-Dec-08 100 µg/L ND NM NS ND ND ND NS ND ND ND ND
8-Jul-09 10000 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-09 10000 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 10000 µg/L ND NM NS ND ND ND NS ND ND ND 2800 J
14-Dec-10 10000 µg/L Dry NM NS ND ND ND NS ND NS ND NS
21-Jun-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 10000 µg/L WL ND NS NS NS NS NS NS NS NS NS
11-Dec-12 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 10000 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-14 10000 µg/L WL NS NS ND ND ND NS ND ND ND ND
13-Aug-14 10000 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 10000 µg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 10000 µg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 10000 µg/L WL NS NS NS NS NS NS NS NS NS NS
11-Aug-16 10000 µg/L WL NS NS NS NS NS NS NS NS NS NS
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 6 of 8 Joyce Engineering
APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Lactic Acid 28-Dec-06 1000 µg/L ND NI NS ND ND NS NS ND ND ND NS
19-Dec-08 1000 µg/L ND NM NS ND ND 4300 NS ND ND ND ND
8-Jul-09 25000 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-09 25000 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 25000 µg/L ND NM NS ND ND ND NS ND ND 1900 J ND
14-Dec-10 25000 µg/L Dry NM NS ND ND ND NS ND NS ND NS
21-Jun-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 25000 µg/L WL ND NS NS NS NS NS NS NS NS NS
11-Dec-12 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 25000 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-14 25000 µg/L WL NS NS ND ND ND NS ND ND ND ND
13-Aug-14 25000 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 25000 µg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 25000 µg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 25000 µg/L WL NS NS NS NS NS NS NS NS NS NS
11-Aug-16 25000 µg/L WL NS NS NS NS NS NS NS NS NS NS
Acetic Acid 28-Dec-06 1000 µg/L ND NI NS NS ND ND NS ND NS ND NS
19-Dec-08 1000 µg/L ND NM NS 1200 ND ND NS ND 1000 ND 1600
8-Jul-09 1000 µg/L ND NM NS 700 J ND ND NS ND ND 700 J ND
14-Dec-09 1000 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 1000 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-10 1000 µg/L Dry NM NS ND 600 J 2400 NS ND NS ND NS
21-Jun-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 1000 µg/L WL ND NS NS NS NS NS NS NS NS NS
11-Dec-12 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 5000 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-14 5000 µg/L WL NS NS ND ND ND NS ND ND ND ND
13-Aug-14 5000 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
11-Aug-16 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
Propionic Acid 28-Dec-06 1000 µg/L ND NI NS NS ND NS NS NS ND ND NS
19-Dec-08 1000 µg/L ND NM NS 9900 ND 64200 NS 1300 ND ND ND
8-Jul-09 1000 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-09 1000 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 1000 µg/L ND NM NS 800 J ND ND NS ND 3800 ND ND
14-Dec-10 1000 µg/L Dry NM NS ND ND ND NS ND NS ND NS
21-Jun-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 1000 µg/L WL ND NS NS NS NS NS NS NS NS NS
11-Dec-12 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 5000 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-14 5000 µg/L WL NS NS ND ND ND NS ND ND ND ND
13-Aug-14 5000 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
11-Aug-16 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
Butyric Acid 28-Dec-06 1000 µg/L ND NI NS NS ND ND NS ND ND ND NS
19-Dec-08 1000 µg/L ND NM NS 1500 ND ND NS ND ND ND ND
8-Jul-09 1000 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-09 1000 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 1000 µg/L ND NM NS ND 600 J ND NS 1000 J ND ND ND
14-Dec-10 1000 µg/L Dry NM NS ND ND ND NS ND NS ND NS
21-Jun-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 1000 µg/L WL ND NS NS NS NS NS NS NS NS NS
11-Dec-12 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 5000 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-14 5000 µg/L WL NS NS ND ND ND NS ND ND ND ND
13-Aug-14 5000 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
11-Aug-16 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 7 of 8 Joyce Engineering
APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Total Volatile Fatty Acids 19-Dec-08 µg/L ND NM NS 12600 ND 68500 NS 1300 1000 ND ND
(sum of above 5 parameters)8-Jul-09 µg/L ND NM NS 700 J ND ND NS ND ND 700 J ND
14-Dec-09 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 µg/L ND NM NS 800 J 600 J ND NS 1000 J 3800 1900 J 2800 J
14-Dec-10 µg/L Dry NM NS ND 600 J 2400 NS ND NS ND NS
21-Jun-11 µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 µg/L WL ND NS NS NS NS NS NS NS NS NS
11-Dec-12 µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-14 µg/L WL NS NS ND ND ND NS ND ND ND ND
13-Aug-14 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 µg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 µg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 µg/L WL NS NS NS NS NS NS NS NS NS NS
11-Aug-16 µg/L WL NS NS NS NS NS NS NS NS NS NS
BTEX 28-Dec-06 µg/L ND NI ND ND ND NS ND ND ND ND NS
(sum of benzene, toluene,19-Dec-08 µg/L ND NM ND ND ND 0.40 J ND ND ND ND ND
ethylbenzene, & xylenes)8-Jul-09 µg/L ND NM ND ND ND 0.54 J ND 0.60 J ND ND ND
14-Dec-09 µg/L ND NM ND ND ND 0.37 J ND NS J NS NS NS
23-Jun-10 µg/L ND NM ND ND ND 0.42 J ND ND ND ND ND
14-Dec-10 µg/L Dry NM ND ND ND ND ND 0.53 J NS ND NS
21-Jun-11 µg/L WL ND ND ND ND ND ND NS NS NS NS
6-Dec-11 µg/L WL ND ND ND ND 0.40 J ND NS NS NS NS
13-Jun-12 µg/L WL ND ND ND ND ND ND NS NS NS NS
11-Dec-12 µg/L WL ND ND ND ND 0.41 J ND NS NS NS NS
29-Apr-13 µg/L WL ND ND ND ND 0.33 J ND NS NS NS NS
6-Aug-13 µg/L WL ND ND ND ND 0.40 J ND NS NS NS NS
25-Feb-14 µg/L WL ND ND ND ND 0.40 J ND NS ND ND ND
13-Aug-14 µg/L WL ND ND ND ND 0.41 J ND NS NS ND NS
12-Mar-15 µg/L WL ND ND ND ND ND ND NS NS ND ND
19-Aug-15 µg/L WL ND ND ND ND 0.35 J ND NS NS ND ND
18-Feb-16 µg/L WL ND ND ND ND ND ND NS NS ND ND
11-Aug-16 µg/L WL ND ND ND ND ND ND NS NS ND ND
DCE 28-Dec-06 µg/L ND NI ND NS ND 6 ND 0.84 J NS ND NS
(sum of dichloroethylenes )11-Jul-07 µg/L ND NI ND NS ND 6.2 ND NS NS NS NS
19-Dec-08 µg/L ND NM ND ND ND ND ND ND ND ND ND
8-Jul-09 µg/L ND NM ND ND ND 7.7 ND 4.1 J 0.30 J ND ND
14-Dec-09 µg/L ND NM ND ND ND 7.4 ND NS NS NS NS
23-Jun-10 µg/L ND NM ND ND ND 13.6 ND 5.6 0.55 J ND ND
14-Dec-10 µg/L Dry NM ND ND ND ND ND 5.9 NS ND NS
21-Jun-11 µg/L WL ND ND ND ND 6.4 ND NS NS NS NS
6-Dec-11 µg/L WL ND ND ND ND 3.0 J ND NS NS NS NS
13-Jun-12 µg/L WL ND ND ND ND 4.3 J ND NS NS NS NS
11-Dec-12 µg/L WL ND ND ND ND 3.3 J ND NS NS NS NS
29-Apr-13 µg/L WL ND ND ND ND 4.8 J ND NS NS NS NS
6-Aug-13 µg/L WL ND ND ND ND 3.6 J ND NS NS NS NS
25-Feb-14 µg/L WL ND ND ND ND 3.7 J ND NS ND ND ND
13-Aug-14 µg/L WL ND ND ND ND 2.8 J 0.39 J NS NS ND NS
12-Mar-15 µg/L WL ND ND ND ND 2.6 J ND NS NS ND ND
19-Aug-15 µg/L WL ND ND ND ND 3.1 J 0.89 J NS NS NS NS
18-Feb-16 µg/L WL ND ND ND ND 2.5 J 0.32 J NS NS NS NS
11-Aug-16 µg/L WL ND ND ND ND 2.7 J 0.5 J NS NS NS NS
Notes: ND = Not detected above the laboratory detection limit.mV = millivolts.NA= Data not avaliable
NS = Not sampled for this parameter during this event.mS/cm = milliseimens/centimeter.
mg/L = milligrams per liter = parts per million.SU = standard units.
µg/L = micrograms per liter = parts per billion.ºC = degrees centigrade
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 8 of 8 Joyce Engineering

Appendix H

Statistical Analyses Worksheets and Summary

JOYCE Project: Oxford Landfill - Granville County
Project No: 660.1701.12
Date: August 2016
Analyte:Cobalt
Reporting
Sample Sample Sample Concentration Limit
No.Date Location (µg/L)(µg/l)
1 9/14/1994 MW-1 160 10 2.1 430
2 12/2/1994 MW-1 47 10 3.9 380
3 2/8/1995 MW-1 ND 10 7.0 200
4 3/2/1995 MW-1 ND 10 8.1 160
5 11/17/1995 MW-1 58 10 10 160
6 5/23/1996 MW-1 29 10 11 150
7 11/14/1996 MW-1 12 10 12 120
8 6/18/1997 MW-1 200 10 13 93
9 12/2/1997 MW-1 7 10 17 73
10 5/27/1998 MW-1 150 10 29 58
11 11/16/1998 MW-1 380 10 34 47
12 9/10/1999 MW-1 11 10 35 45
13 11/16/1999 MW-1 ND 10 45 35
14 5/10/2000 MW-1 ND 10 47 34
15 10/26/2000 MW-1 10 10 58 29
16 9/14/1994 MW-1A 160 10 73 17
17 12/2/1994 MW-1A ND 10 93 13
18 2/8/1995 MW-1A 45 10 120 12
19 3/2/1995 MW-1A 35 10 150 11
20 11/17/1995 MW-1A 13 10 160 10
21 5/23/1996 MW-1A ND 10 160 8.1
22 11/14/1996 MW-1A 93 10 200 7.0
23 6/18/1997 MW-1A 430 10 380 3.9
24 12/2/1997 MW-1A 34 10 430 2.1
25 5/27/1998 MW-1A 73 10
26 11/16/1998 MW-1A 120 10
27 9/10/1999 MW-1A ND 10
28 11/16/1999 MW-1A ND 10
29 5/10/2000 MW-1A ND 10
30 10/26/2000 MW-1A ND 10
31 4/18/2001 MW-1A 17 10
32 10/27/2001 MW-1A ND 10
33 6/10/2002 MW-1A ND 10
34 6/13/2002 MW-1A ND 10
35 11/19/2002 MW-1A ND 10
36 6/27/2003 MW-1A ND 10
37 12/30/2003 MW-1A ND 10
38 6/30/2004 MW-1A ND 10
39 12/29/2004 MW-1A ND 10
40 6/29/2005 MW-1A ND 10
41 12/29/2005 MW-1A ND 10
42 6/28/2006 MW-1A ND 10
43 12/28/2006 MW-1A 2.1 J 10
44 7/12/2007 MW-1A ND 10
45 7/8/2008 MW-1A 436 #10
46 12/6/2008 MW-1A 2.5 B 10
47 7/8/2009 MW-1A 8.1 J 10
48 12/15/2009 MW-1A ND 10
49 6/23/2010 MW-1A 3.9 J 10
50 6/21/2011 MW-7 ND 10
51 6/13/2012 MW-7 ND 10
52 12/12/2012 MW-7 ND 10
53 4/29/2013 MW-7 ND 10
54 8/6/2013 MW-7 ND 10
55 2/26/2014 MW-7 ND 10
56 8/13/2014 MW-7 ND 10
57 3/12/2015 MW-7 ND 10
58 8/19/2015 MW-7 ND 10
59 2/18/2016 MW-7 ND 10
60 8/11/2016 MW-7 ND 10
Number of Data: 58
Number of Truncated Data: 34
Percentage of Truncated Data: 58.6%
Nonparametric Predition Interval:430 µg/L
Notes:
All concentrations in micrograms per liter (µg/l).
ND = Not detected (truncated).
J = Estimated concentration below the reporing limit (used in stattistical calculations).
B = Blank-qualified data (not used in statistical calculations).
# - Data rejected due to extreamly high tubidity in the samples (not used in satatistical calculations).
B = Blank-qualified data (not used in calculations).
Concentration
(µg/l)
Sorted
JOYCE Project: Oxford Landfill - Granville County
Project No: 660.1701.12
Date: August 2016
Analyte: Chromium
Reporting
Sample Sample Sample Concentration Limit
No.Date Location (µg/l)(µg/l)
1 9/14/1994 MW-1 74.0 10 0.60 1,000
2 12/2/1994 MW-1 93.0 10 1.5 470
3 2/8/1995 MW-1 ND 10 2.8 470
4 3/2/1995 MW-1 ND 10 3.0 340
5 11/17/1995 MW-1 130 10 3.3 220
6 5/23/1996 MW-1 71.0 10 3.4 150
7 11/14/1996 MW-1 3.0 10 6.0 130
8 6/18/1997 MW-1 470 10 8.0 93.0
9 12/2/1997 MW-1 17.0 10 11.0 74.0
10 5/27/1998 MW-1 470 10 12.0 74.0
11 11/16/1998 MW-1 1,000 10 12.0 71.0
12 9/10/1999 MW-1 23.0 10 16.0 48.0
13 11/16/1999 MW-1 28.0 10 17.0 41.0
14 5/10/2000 MW-1 ND 10 22.1 28.0
15 10/26/2000 MW-1 16.0 10 23.0 23.0
16 9/14/1994 MW-1A 74.0 10 28.0 22.1
17 12/2/1994 MW-1A ND 10 41.0 17.0
18 2/8/1995 MW-1A 48.0 10 48.0 16.0
19 3/2/1995 MW-1A 41.0 10 71.0 12.0
20 11/17/1995 MW-1A 11.0 10 74.0 12.0
21 5/23/1996 MW-1A ND 10 74.0 11.0
22 11/14/1996 MW-1A 6.0 10 93.0 8.0
23 6/18/1997 MW-1A 340 10 130 6.0
24 12/2/1997 MW-1A 8.0 10 150 3.4
25 5/27/1998 MW-1A 150 10 220 3.3
26 11/16/1998 MW-1A 220 10 340 3.0
27 9/10/1999 MW-1A ND 10 470 2.8
28 11/16/1999 MW-1A ND 10 470 1.5
29 5/10/2000 MW-1A ND 10 1,000 0.60
30 10/26/2000 MW-1A ND 10
31 4/18/2001 MW-1A ND 10
32 10/27/2001 MW-1A ND 10
33 6/10/2002 MW-1A ND 10
34 6/13/2002 MW-1A ND 10
35 11/19/2002 MW-1A 12.0 10
36 6/27/2003 MW-1A ND 10
37 12/30/2003 MW-1A ND 10
38 6/30/2004 MW-1A ND 10
39 12/29/2004 MW-1A ND 10
40 6/29/2005 MW-1A ND 10
41 12/29/2005 MW-1A ND 10
42 6/28/2006 MW-1A ND 10
43 12/28/2006 MW-1A 2.8 J 10
44 7/12/2007 MW-1A 3.3 J 10
45 7/8/2008 MW-1A 488 #10
46 12/6/2008 MW-1A 1.5 J 10
47 7/8/2009 MW-1A 22.1 10
48 12/15/2009 MW-1A 0.60 J 10
49 6/23/2010 MW-1A 12.0 10
50 8/12/2010 MW-1A 87.8 #10
51 6/21/2011 MW-7 ND 10
52 12/6/2011 MW-7 ND 10
53 6/13/2012 MW-7 ND 10
54 12/11/2012 MW-7 ND 10
55 4/29/2013 MW-7 ND 10
56 8/6/2013 MW-7 ND 10
57 2/25/2014 MW-7 ND 10
58 8/13/2014 MW-7 ND 10
59 3/12/2015 MW-7 ND 10
60 8/19/2015 MW-7 ND 10
61 2/18/2016 MW-7 ND 10
62 8/11/2016 MW-7 3.4 J 10
Number of Data:60
Number of Truncated Data:31
Percentage of Truncated Data:51.7%
Nonparametric Prediction Interval: 1,000 µg/l
Notes:
All concentrations in micrograms per liter (µg/l).
ND = Not detected (truncated).
J = Estimated concentration below the reporing limit (used in stattistical calculations).
B = Blank-qualified data (not used in statistical calculations).
# - Data rejected due to extreamly high tubidity in the samples (not used in satatistical calculations).
Concentration
(µg/l)
Sorted
JOYCE Project: Oxford Landfill - Granville County
Project No: 660.1701.12
Date: August 2016
Analyte: Vanadium
Reporting
Sample Sample Sample Concentration Limit
No.Date Location (µg/l)(µg/l)
1 9/14/1994 MW-1 580 40 2.2 1,600
2 12/2/1994 MW-1 107 40 3.4 900
3 2/8/1995 MW-1 ND 40 3.7 580
4 3/2/1995 MW-1 ND 40 5.2 580
5 11/17/1995 MW-1 100 40 5.9 470
6 5/23/1996 MW-1 92.0 40 10.0 330
7 11/14/1996 MW-1 16.0 40 15.0 280
8 6/18/1997 MW-1 470 40 16.0 120
9 12/2/1997 MW-1 32.0 40 18.7 107
10 5/27/1998 MW-1 330 40 19.8 100
11 11/16/1998 MW-1 900 40 32.0 92.0
12 9/10/1999 MW-1 ND 40 39.6 81.0
13 11/16/1999 MW-1 ND 40 62.0 62.0
14 5/10/2000 MW-1 ND 40 81.0 39.6
15 10/26/2000 MW-1 ND 40 92.0 32.0
16 9/14/1994 MW-1A 580 40 100 19.8
17 12/2/1994 MW-1A ND 40 107 18.7
18 2/8/1995 MW-1A 81.0 40 120 16.0
19 3/2/1995 MW-1A 62.0 40 280 15.0
20 11/17/1995 MW-1A ND 40 330 10.0
21 5/23/1996 MW-1A ND 40 470 5.9
22 11/14/1996 MW-1A 10.0 40 580 5.2
23 6/18/1997 MW-1A 1,600 40 580 3.7
24 12/2/1997 MW-1A 15.0 40 900 3.4
25 5/27/1998 MW-1A 120 40 1,600 2.2
26 11/16/1998 MW-1A 280 40
27 9/10/1999 MW-1A ND 40
28 11/16/1999 MW-1A ND 40
29 5/10/2000 MW-1A ND 40
30 10/26/2000 MW-1A ND 40
31 4/18/2001 MW-1A ND 40
32 10/27/2001 MW-1A ND 40
33 6/10/2002 MW-1A ND 40
34 6/13/2002 MW-1A ND 40
35 11/19/2002 MW-1A ND 40
36 6/27/2003 MW-1A ND 40
37 12/30/2003 MW-1A ND 40
38 6/30/2004 MW-1A ND 40
39 12/29/2004 MW-1A ND 40
40 6/29/2005 MW-1A ND 40
41 12/29/2005 MW-1A ND 40
42 6/28/2006 MW-1A ND 40
43 12/28/2006 MW-1A 2.2 J 25
44 7/12/2007 MW-1A 3.7 J 25
45 7/8/2008 MW-1A 772 #25
46 12/16/2008 MW-1A 3.4 J 25
47 7/8/2009 MW-1A 39.6 25
48 12/15/2009 MW-1A 1.2 B 25
49 6/23/2010 MW-1A 18.7 J 25
50 6/21/2011 MW-7 5.9 J 25
51 12/6/2011 MW-7 19.8 J 25
52 6/13/2012 MW-7 5.2 J 25
53 12/11/2012 MW-7 ND 25
54 4/29/2013 MW-7 ND 25
55 8/6/2013 MW-7 ND 25
56 2/25/2014 MW-7 ND 25
57 8/13/2014 MW-7 ND 25
58 3/12/2015 MW-7 ND 25
59 8/19/2015 MW-7 ND 25
60 2/18/2016 MW-7 ND 25
61 8/11/2016 MW-7 ND 25
Number of Data:59
Number of Truncated Data:34
Percentage of Truncated Data:57.6%
Nonparametric Prediction Interval: 1,600 µg/l
Notes:
All concentrations in micrograms per liter (µg/l).
ND = Not detected (truncated).
J = Estimated concentration below the reporing limit (used in stattistical calculations).
B = Blank-qualified data (not used in statistical calculations).
# - Data rejected due to extreamly high tubidity in the samples (not used in satatistical calculations).
Concentration
(µg/l)
Sorted
JOYCE Project: Oxford Landfill - Granville County
Project No: 660.1701.12
Date: August 2016
Analyte: TDS
Reporting
Sample Sample Sample Concentration Limit
No.Date Location (µg/l)(µg/l)
1 6/21/2011 MW-7 170,000 25,000 162,000 229,000
2 12/6/2011 MW-7 174,000 5,000 170,000 217,000
3 6/13/2012 MW-7 189,000 25,000 170,000 213,000
4 12/11/2012 MW-7 199,000 25,000 172,000 199,000
5 4/29/2013 MW-7 170,000 25,000 173,000 189,000
6 8/6/2013 MW-7 179,000 25,000 174,000 179,000
7 2/25/2014 MW-7 173,000 25,000 179,000 174,000
8 8/13/2014 MW-7 172,000 25,000 189,000 173,000
9 3/12/2015 MW-7 229,000 25,000 199,000 172,000
10 8/19/2015 MW-7 217,000 25,000 213,000 170,000
11 2/18/2016 MW-7 162,000 25,000 217,000 170,000
12 8/11/2016 MW-7 213,000 25,000 229,000 162,000
Number of Data:12
Number of Truncated Data:0
Percentage of Truncated Data:0.0%
Upper Prediction Limit (UPL): 226,837 µg/l
Notes:
All concentrations in micrograms per liter (µg/l).
ND = Not detected (truncated).
J = Estimated concentration below the reporing limit (used in stattistical calculations).
B = Blank-qualified data (not used in statistical calculations).
# - Data rejected due to extreamly high tubidity in the samples (not used in satatistical calculations).
Concentration
(µg/l)
Sorted
JOYCE Project: Oxford Landfill - Granville County
Project No: 660.1701.12
Date: August 2016
Analyte: TDS
Reporting
Sample Sample Sample Concentration Limit
No.Date Location (µg/l)(µg/l)
1 6/23/2010 MW-1A 710,000 250,000 162,000 710,000
2 6/21/2011 MW-7 170,000 25,000 170,000 229,000
3 12/6/2011 MW-7 174,000 5,000 170,000 217,000
4 6/13/2012 MW-7 189,000 25,000 172,000 213,000
5 12/11/2012 MW-7 199,000 25,000 173,000 199,000
6 4/29/2013 MW-7 170,000 25,000 174,000 189,000
7 8/6/2013 MW-7 179,000 25,000 179,000 179,000
8 2/25/2014 MW-7 173,000 25,000 189,000 174,000
9 8/13/2014 MW-7 172,000 25,000 199,000 173,000
10 3/12/2015 MW-7 229,000 25,000 213,000 172,000
11 8/19/2015 MW-7 217,000 25,000 217,000 170,000
12 2/18/2016 MW-7 162,000 25,000 229,000 170,000
13 8/11/2016 MW-7 213,000 25,000 710,000 162,000
Number of Data:12
Number of Truncated Data:0
Percentage of Truncated Data:0.0%
Non-parametric Prediction Interval:710,000 µg/l
Notes:
All concentrations in micrograms per liter (µg/l).
ND = Not detected (truncated).
J = Estimated concentration below the reporing limit (used in stattistical calculations).
B = Blank-qualified data (not used in statistical calculations).
# - Data rejected due to extreamly high tubidity in the samples (not used in satatistical calculations).
Concentration
(µg/l)
Sorted
JOYCE Project: Oxford Landfill - Granville County
Project No: 660.1701.12
Date: August 2016
Analyte: TDS (MW-6R Intrawell)
Reporting
Sample Sample Sample Concentration Limit
No.Date Location (µg/l)(µg/l)
1 6/23/2010 MW-6R 360,000 250,000 347,000 466,000
2 12/14/2010 MW-6R 347,000 25,000 360,000 423,000
3 6/21/2011 MW-6R 378,000 5,000 378,000 419,000
4 12/6/2011 MW-6R 408,000 25,000 402,000 408,000
5 6/13/2012 MW-6R 402,000 25,000 408,000 402,000
6 12/11/2012 MW-6R 419,000 25,000 419,000 378,000
7 4/29/2013 MW-6R 466,000 25,000 423,000 360,000
8 8/6/2013 MW-6R 423,000 25,000 466,000 347,000
Number of Data:8
Number of Truncated Data:0
Percentage of Truncated Data:0.0%
Upper Prediction Limit (UPL): 528,672 µg/l
Notes:
All concentrations in micrograms per liter (µg/l).
ND = Not detected (truncated).
J = Estimated concentration below the reporing limit (used in stattistical calculations).
B = Blank-qualified data (not used in statistical calculations).
# - Data rejected due to extreamly high tubidity in the samples (not used in satatistical calculations).
Concentration
(µg/l)
Sorted