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PREPARED FOR:
GRANVILLE COUNTY
SOLID WASTE DEPARTMENT
P.O. BOX 906
OXFORD, NORTH CAROLINA 27565

BUTNER LANDFILL
PERMIT NO. 39-02

FIRST SEMIANNUAL
WATER QUALITY MONITORING REPORT
OF 2016
APRIL 2016

PREPARED BY:

2211 WEST MEADOWVIEW ROAD, SUITE 101
GREENSBORO, NORTH CAROLINA 27407 NC LICENSE NUMBER C-0782 PHONE: [phone] FAX: [phone] JOYCE PROJECT NO. 660.1601.12
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First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Granville County - Butner Landfill, Permit No. 39-02 April 2016
i
First Semiannual Water Quality Monitoring Report of 2016 Butner Landfill, Permit No. 39-02
Granville County, North Carolina
TABLE OF CONTENTS

1.0 INTRODUCTION..............................................................................................................1 1.1 Site Information ...................................................................................................................1
1.2 Site Geology.........................................................................................................................1
1.3 Groundwater Monitoring History ........................................................................................1
1.4 Regulatory Status .................................................................................................................2
2.0 FACILITY MONITORING PROGRAM .......................................................................2 2.1 Groundwater Monitoring Program ......................................................................................2
2.2 Surface Water Monitoring Program .....................................................................................3
3.0 FIRST SEMIANNUAL SAMPLING EVENT OF 2016 ................................................4
3.1 Field Work ...........................................................................................................................4 3.2 Laboratory Analysis and JOYCE Quality Control ..............................................................4
4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSES....................................5 4.1 Analytical Results for Groundwater and Comparisons to Standards ...................................5
4.1.1 Inorganic Analyses.................................................................................................... 5
4.1.2 Organic Analyses ...................................................................................................... 5 4.2 Statistical Analyses ..............................................................................................................6 4.2.1 Statistical Methods .................................................................................................... 6
4.2.2 Results of Statistical Analyses .................................................................................. 6
4.3 Analytical Results for Surface Water and Comparisons to Standards .................................7
5.0 HYDROGEOLOGICAL CONDITIONS ........................................................................7
6.0 CORRECTIVE ACTION EVALUATION .....................................................................8 6.1 Monitored Natural Attenuation Parameters .........................................................................8
6.2 Phytoremediation .................................................................................................................8
6.3 Evaluation of Plume Stability and Trends ...........................................................................8
7.0 CONCLUSIONS ................................................................................................................8
8.0 REFERENCES ...................................................................................................................9
9.0 ACRONYMS ......................................................................................................................9

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First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Granville County - Butner Landfill, Permit No. 39-02 April 2016
ii

TABLE OF CONTENTS (Continued)

Tables Table 1 Monitoring Well Construction Data Table 2 Historical Groundwater Elevation Data Table 3 Hydraulic Gradients and Groundwater Flow Velocities Table 4 Quantified Detections of Groundwater Constituents (February 2016) Table 5 Exceedances of Groundwater Standards (February 2016) Table 6 Field Parameters (February 2016) Table 7 Monitored Natural Attenuation Parameters
Chart Chart 1 Benzene Concentrations vs. Time
Figure Figure 1 Site Location Map

Drawing Drawing 1 Groundwater Potentiometric Surface Map (February 2016)

Appendices
Appendix A Field Data Logs Appendix B Laboratory Analytical Reports
Appendix C Historical Constituents in Groundwater Appendix D Historical Constituents in Surface Water Appendix E Statistical Analyses Worksheets & Summary

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First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Granville County - Butner Landfill, Permit No. 39-02 April 2016 1

First Semiannual Water Quality Monitoring Report of 2016 Butner Landfill, Permit No. 39-02

1.0 INTRODUCTION
1.1 Site Information
The Butner Landfill is a closed municipal solid waste (MSW) landfill, located off State Route
1004 near the town of Butner, in Granville County, North Carolina (Figure No. 1). The Butner
facility started receiving waste prior to May 1973. Permit Number 39-02, was issued by the
State of North Carolina on March 3, 1982. The facility stopped receiving waste in August 1998. A small recycling center and transfer station are operated by the County of Granville at the entrance of the closed landfill.

In accordance with North Carolina Solid Waste Management Regulations (NCSWMR), the
Butner Landfill entered an Assessment Monitoring Program in December of 1997 as a result of detections of volatile organic compounds and pesticide above 15A-NCAC-2L (NC-2L) Groundwater Standards. An Assessment of Corrective Measures (ACM) was initiated in 2003,
and then suspended by North Carolina Department of Environment and Natural Resources
(DENR) [now the Department of Environmental Quality (NCDEQ)] since there had been no
more NC-2L exceedances. The Nature and Extent Study (NES) and ACM recommenced in 2007 when apparent volatile organic compound (VOC) exceedances of the NC-2L Standards began to appear; however, they were again suspended when it was determined that the apparent
exceedances were not statistically significant increases (SSIs) above background. An ACM was
reinitiated after an exceedance of benzene in MW-2R in December 2012, and was submitted to
DENR in May 2013. Approval of the ACM was granted in a letter from DENR dated June 27, 2013. A Corrective Action Plan (CAP) was submitted to DENR on May 23, 2014, and was approved by DENR on June 18, 2014.

1.2 Site Geology
The Butner Landfill lies within the Piedmont physiographic province. The topography of the area consists of rolling hills that support farmland and forest. The majority of the landfill area is underlain by Carolina Slate Belt felsic volcanic rocks, which have been metamorphosed into
greenish grey foliated tuffs. The southeastern portion of the site is underlain by Triassic Sanford
Formation (conglomerate, sandstone, and mudstone), which unconformably overlies the Carolina
Slate Belt felsic volcanic rocks. There is no exposure of the Sanford Formation at the site;
however, float material consisting of grey, coarse-grained sandstone with quartz pebbles was observed. Diabase dikes have also been observed in the vicinity of the site. Geologic
descriptions were taken from GAI Consultants’ Groundwater and Surface Water Monitoring
System report (GAI, 1994).

1.3 Groundwater Monitoring History
 April 1994 – Current Monitoring Well Network installed.
 Dec. 1997 - The facility entered Assessment Monitoring.
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First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Granville County - Butner Landfill, Permit No. 39-02 April 2016 2

 June 2003 – NC-2L exceedances for heptachlor in MW-2R and MW-3R initiated an
ACM.
 Dec. 2004 & June 2005 – There were no NC-2L exceedances, so DENR agreed to put the ACM on hold pending future monitoring results. At first, DENR said the facility
needed deed restrictions on adjoining property owned by the County, but this was
apparently based on false information (the County did not own the property) so the
requirement for deed restrictions was dropped.
 Dec. 2006 – Benzene in MW-2R and 1,4-dichlorobenzene in MW-2R and MW-3R detected above NC-2L standards.
 June 14, 2007 - Granville County and JOYCE met with DENR to discuss a strategy for
performing a Nature and Extent Study (NES) and an ACM.
 Nov. 2007 – Nature & Extent well NES-1 was installed downgradient of MW-2R & MW-3R.
 Dec. 2007 – NES & MNA sampling event on selected wells.
 Dec. 2008 – Organic results above the NC-2L standards were determined to not represent statistically significant exceedances, so corrective action and ACM were suspended with
the concurrence of the DENR and in accordance with the NCSWMR.
 Dec. 2012 – Benzene detections above the NC-2L in MW-2R initiated the ACM.
 May 17, 2013 – ACM addressing the benzene detections above the NC 2L in MW-2R submitted to DENR.
 June 27, 2013 – ACM approved by DENR.
 September 3, 2013 – Public meeting and selection of remedy.
 May 23, 2014 – CAP submitted to DENR.
 June 18, 2014 – CAP approved by DENR.
 February 2, 2016- Corrective Action Evaluation Report (CAER) reviewed and approved byNCDEQ. NCDEQ denied the request to remove selected MNA parameters but allowed
a modified monitoring frequency beginning August 2016.

1.4 Regulatory Status
Groundwater and surface water monitoring at the Butner Landfill is completed in accordance with North Carolina Solid Waste Management Regulations (NCSWMR) §.1634. The site is
currently in a Corrective Action Monitoring Program. Groundwater samples are collected
semiannually and analyzed in accordance with the approved Corrective Action Plan. Surface
water samples are collected and sampled for Appendix I constituents during each sampling
event.
2.0 FACILITY MONITORING PROGRAM
2.1 Groundwater Monitoring Program
Six active groundwater monitoring wells comprise the monitoring network at the Butner
Landfill. The current compliance network consists of the following monitoring wells: MW-1R (facility background well), MW-2R, MW-3R, MW-4, MW-5, and MW-6. An additional well,
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First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Granville County - Butner Landfill, Permit No. 39-02 April 2016 3

NES-1, was installed as part of a Nature and Extent Study on November 14, 2007. The following
table summarizes the monitoring network and required analytical parameters.

Groundwater Monitoring Network
Monitoring Well Date Installed Classification Monitoring Program TD (ft) Lithology of Screened Interval
1st SA Event Analyses 2nd SA Event Analyses
MW-1R 4/21/94 Background Assessment/CAMP 45.1 Saprolite App. II, MNA App. I + Det., MNA
MW-2R 4/12/94 Compliance/ Performance Assessment/ CAMP 19.0 Saprolite App. II, MNA App. I + Det., MNA
MW-3R 4/14/94 Compliance/ Performance Assessment/ CAMP 37.2 Bedrock App. II, MNA App. I + Det., MNA
MW-4 4/18/94 Compliance Detection 31.5 Bedrock App. I App. I
MW-5 4/18/94 Compliance Detection 23.4 Saprolite App. I App. I
MW-6 4/19/94 Compliance Detection 31.7 Saprolite/ Bedrock App. I App. I
NES-1 11/14/07 Nature &
Extent Sentinel 33.0 Saprolite/
Bedrock COCs, MNA COCs, MNA
App. I = NCSWMR Appendix I list of constituents. App. II = NCSWMR Appendix II list of constituents.
MNA = Monitoring Natural Attenuation parameters. COCs = Constituents of Concern App. I + Det. = App. I list plus detected App. II constituents. CAMP = Corrective Action Monitoring Plan
Current Appendix II detected constituents: tin, gamma-BHC, heptachlor, 2,4-D, and
endrin aldehyde.
Current COC: Benzene.
MNA Field Parameters: Temperature, pH, specific conductance, oxidation reduction potential, turbidity, dissolved oxygen, and ferrous iron. Dissolved carbon dioxide every
third year.
MNA Laboratory Parameters: Dissolved methane, alkalinity, sulfate, nitrate, chloride,
biological oxygen demand (BOD), chemical oxygen demand (COD), and total organic carbon (TOC). Dissolved hydrogen, volatile fatty acids, sulfide, ethane and ethene every third year.

2.2 Surface Water Monitoring Program
Two surface water samples have been collected semiannually since September 1994 at the Butner Landfill. The points SW-1 and SW-2 are located respectively upstream and downstream of the facility, along an unnamed tributary of Picture Creek. The surface water samples are
analyzed for the NCSWMR Appendix I list of constituents during both semiannual events.

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First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Granville County - Butner Landfill, Permit No. 39-02 April 2016 4

3.0 FIRST SEMIANNUAL SAMPLING EVENT OF 2016
3.1 Field Work
On February 16, 2016, Joyce Engineering, (JOYCE) personnel visited the Butner Landfill to
purge and sample monitoring wells MW-1R, MW-2R, MW-3R, MW-4, MW-5, MW-6, and NES-1.
All monitoring wells were purged and sampled using new, disposable bailers. Measurements of
temperature, pH, turbidity and specific conductivity were recorded in a field log. Prior to
sampling, laboratory-supplied containers were prepared with the following information:
 Monitoring well number (completed by laboratory/field personnel),
 Date and time of sample collection (completed by laboratory/field personnel),
 Initials of sampling personnel (completed by laboratory/field personnel),
 Project name and number (completed by the laboratory/field personnel),
 Chemical preservative (completed by the laboratory/field personnel); and
 Requested chemical analysis (completed by the laboratory/field personnel).
Groundwater samples from each monitoring well were collected directly from the bailers into the
provided laboratory containers, either immediately after purging or within 24 hours of the final
purge volume. Immediately after collection, the samples were placed in a laboratory provided cooler and chilled on ice. Field Logs are provided in Appendix A and field parameters are summarized in Table 6.

Surface water points SW-1 and SW-2 were sampled. Field Logs are included in Appendix A.

3.2 Laboratory Analysis and JOYCE Quality Control
Pace Analytical Services Inc. of Huntersville, North Carolina, analyzed the February 2016,
groundwater and surface water samples under chain-of-custody control. The groundwater
samples from MW-1R, MW-2R, and MW-3R were analyzed for the NC Appendix II list of
constituents. The groundwater samples from MW-4, MW-5, and MW-6 were analyzed for the NC Appendix I list of constituents. The sample from sentinel well NES-1 was analyzed for Appendix I VOCs only. Samples from MW-1R, MW-2R, MW-3R, and NES-1 were also
analyzed for MNA parameters. The surface water samples were analyzed for NC Appendix I
constituents. The samples were received by the laboratory on February 17, 2016, in good
condition, properly preserved, at proper temperatures, and within analysis hold times. In addition to samples collected for compliance monitoring at the Butner Landfill, JOYCE
personnel collected a Field Blank as part of the February 2016 sampling event. The Field Blank
was analyzed for the NC Appendix II constituents. Also, a Trip Blank that was prepared by the
laboratory accompanied the volatile sampling containers to and from the laboratory. The Trip Blank was analyzed for the Appendix II volatile organic compounds. The complete laboratory analytical reports are included in Appendix B.

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First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Granville County - Butner Landfill, Permit No. 39-02 April 2016 5

Upon receipt of the laboratory data package, JOYCE personnel reviewed the following data for:
 General typographical errors;
 Correct analyses performed and within method specified hold times;
 Biased data results based on Matrix Spike, Matrix Spike Duplicate, and Laboratory
Control Samples;
 Blank qualified data (B-flags);
 Detections above the 15A NCAC 2l.0202 (NC 2L) Groundwater Standards or the NCDEQ Solid Waste Section (SWS) Groundwater Water Protection Standards (GWPS);
and
 Detections that are above historical levels. The complete laboratory analytical reports and the chains of custody from the August 2015 event
are included in Appendix B. Historical analytical results for groundwater and surface water are
presented in Appendices C and D, respectively.

4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSES
4.1 Analytical Results for Groundwater and Comparisons to Standards
4.1.1 Inorganic Analyses
The following inorganic constituents were detected at quantified concentrations above the
NCDEQ-SWS reporting limits (SWSL’s) in one or more wells during the February 2016 sampling event: antimony, barium, cobalt, nickel, and zinc. Table 4 summarizes all of the quantified detections from the February 2016 event. These results are consistent with historical
data.

Antimony in MW-2R and MW-3R and cobalt in MW-5 were detected above their respective GWPS; however, not above the calculated background concentration (see section 4.2). Since the antimony and cobalt detections were below the site specific calculated background values, there
were no exceedances of the GPS as defined by 15A NCAC 13B.1634.g. Exceedances of
groundwater standards from the February 2016 event are summarized in Table 5. The laboratory
analytical reports and the chains of custody are included in Appendix B. Complete historical analytical results for inorganic constituents are included in Appendix C.
4.1.2 Organic Analyses
The following organic constituents were detected at quantified concentrations above the solid
waste section report limits (SWSL’s) in one or more wells during the February 2016 sampling
event: benzene, chlorobenzene, and 1,4-dichlorobenzene. Table 4 summarizes all of the quantified detections from the February 2016 event. These results are consistent with historical data.

Benzene was detected above the NC 2L and the GPS in MW-2R. Exceedances of groundwater
standards from the February 2016 event are summarized in Table 5. The benzene exceedance in MW-2R has been addressed in the ACM, approved in June 2013, and the CAP, approved in June
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First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Granville County - Butner Landfill, Permit No. 39-02 April 2016 6

2014. No other organic constituents were detected above their GPS during the February 2016
sampling event. The laboratory analytical reports and the chains of custody are included in
Appendix B. Historical analytical results for organic constituents are presented in Appendix C.

4.2 Statistical Analyses
4.2.1 Statistical Methods
Monitoring well MW-1R is designated as the up-gradient background well for the facility. Data
from MW-1R between September 1994 and February 2016 have been used to determine
statistical background concentrations for constituents detected at the facility. The background data were evaluated using the Shapiro-Wilk Test, Parametric Prediction Limits,
Parametric Tolerance Intervals, Aitchison’s Adjustment, Non-Parametric Prediction Limits, and
Poisson Prediction Limits, as appropriate. Background data, tests for normality, outliers,
Aitchison’s adjustment, tolerance interval, or prediction limits are used, as appropriate based on the background data. The statistical test by which downgradient data are compared to facility background data is based upon the nature of the data and the number of data values that are less
than the laboratory limit of detection. All statistical tests are evaluated at the 0.05 level of
significance, 95% confidence level, and are conducted as one-tailed tests. The data set was
evaluated to determine the appropriate procedure for calculation of the background value for each parameter.
4.2.2 Results of Statistical Analyses
Antimony and cobalt were the only inorganic constituents detected in exceedance of their NC 2L
or GWPS during the February 2016 sampling event. The calculated background concentrations for antimony and cobalt are proposed as the Groundwater Protection Standards specific to the site per rule .1634(g.5) of the NCSWMR. Statistical analysis worksheets can be found in
Appendix E. The results of the February 2016 statistical background calculations are
summarized in the following table.

Constituent Data Distribution
Statistical
Method used to Establish Background
Background Concentration GWPS GPS GPS Exceedances
Antimony 96% ND Upper Poisson Prediction Limit 56 1 56 None
Cobalt 74% ND Nonparametric
Prediction Interval 130 1 130 None
GWPS = Solid Waste Section Groundwater Standard for constituents with no listed NC 2L. GPS = Groundwater Protection Standard as defined in 15A NCAC .1634(g). %ND = percentage of background data that is truncated (non-detect). All concentrations are in µg/L (micrograms per liter).
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First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Granville County - Butner Landfill, Permit No. 39-02 April 2016 7

4.3 Analytical Results for Surface Water and Comparisons to Standards
Surface water points SW-1 and SW-2 were sampled during the February 2016 sampling event.
No constituents, organic or inorganic were detected above the SWSL during the February 2016
sampling event.
5.0 HYDROGEOLOGICAL CONDITIONS
Groundwater in the saprolite feeds the fractures in the bedrock and discharges into creeks
northeast of the landfill. Groundwater flow direction at deeper levels within the fractured
bedrock is controlled by fracture orientation. A groundwater surface contour map, developed with static water level data obtained February 16, 2016, is presented as Drawing 1. The static water elevations depict groundwater flow to the southeast.

Depth to groundwater was measured in the compliance monitoring wells at the site prior to
purging. The groundwater elevations were calculated relative to the surveyed measuring point (top of casing) for each monitoring well. The historical groundwater elevations are summarized in Table 2. The groundwater elevation contours shown on Drawing 1 are based on data from the
February 2016 sampling event. Horizontal groundwater gradients along representative flow
paths were estimated from the February 2016 groundwater contours shown on Drawing 1 and are
summarized in Table 3. Horizontal gradients across the site ranged from 0.045 to 0.056 ft/ft, with an average of approximately 0.0498 ft/ft. This is consistent with previous estimates.

Linear groundwater flow velocities were computed using the modified Darcy equation:
V = Ki/ne where V = average linear velocity (feet/year),
K = hydraulic conductivity (feet/day),
i = horizontal hydraulic gradient, and
ne = effective porosity.
The average of hydraulic conductivities (K = 2.18x10-05 cm/sec = 6.18x10-02 feet/day) from slug-tests conducted in 1994 (GAI, 1994) was used in these calculations. The average effective
porosity (ne = 18%) based on 90% of reported total porosity for soils (GAI, 1994), and ne = 10%
for fractured bedrock were also used. Although the regolith and bedrock are hydraulically
connected, the effective porosity generally decreases with depth into the underlying fractured
bedrock. The modified Darcy equation makes the simplifying assumption of a homogeneous and isotropic aquifer. Groundwater flow direction beneath the landfill is predominantly to the south
and southeast.

Because of our conservative estimate of effective porosity, actual groundwater velocities may be
significantly less than the calculated values. Also, the modified Darcy equation makes the simplifying assumptions of a homogeneous and isotropic aquifer, which may not be accurate for
this site.

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First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Granville County - Butner Landfill, Permit No. 39-02 April 2016 8

6.0 CORRECTIVE ACTION EVALUATION
6.1 Monitored Natural Attenuation Parameters
Wells MW-1R (background), MW-2R, MW-3R, and NES-1 were analyzed for the following
MNA parameters during the February 2016 sampling event: MNA Field Parameters: Temperature, pH, specific conductance, oxidation reduction
potential, turbidity, dissolved oxygen, dissolved carbon dioxide, and ferrous iron.

MNA Laboratory Parameters: Dissolved hydrogen, volatile fatty acids, dissolved methane, ethane, ethane, alkalinity, sulfide, sulfate, nitrate, chloride, biological oxygen demand (BOD), chemical oxygen demand (COD), and total organic carbon (TOC).

The current and historical MNA parameter data are presented in Table 7, and the laboratory
analytical report for the February 2016 sampling event is included in Appendix B. The February 2016 sampling event represents the fourth of four required baseline sampling events for the MNA remedy. The MNA data will be evaluated and reported in the first Corrective Action
Evaluation Report (CAER) for the facility, which will be submitted concurrently with this report.

6.2 Phytoremediation
The second phytoremediation tree survey for the Butner Landfill was conduction in April 2015 and the results were presented in the 2015 CAER. The CAP requires annual tree surveys, and
the next survey is scheduled for spring 2016.

6.3 Evaluation of Plume Stability and Trends
Chart 1 presents a plot of the benzene concentrations versus time in all monitoring wells where it has been detected (MW-2R, MW-3R, and MW-4). There were no benzene detections prior to
December 2006, possibly due to a higher quantitation limit and the fact that estimated detections
below the quantitation limit were not reported prior to December 2006. From December 2006 to
present, benzene in MW-2R has fluctuated between 1µg/L and 2 µg/L with no clear trend. From December 2007 to present, benzene in MW-3R has fluctuated between 0.3 µg/L and 0.7 µg/L, and benzene in MW 4R has fluctuated between non-detect and 0.4 µg/L.

The benzene concentrations from the February 2016 sampling event were slightly higher in all
three wells than the previous (August 2015) event; however, they are within the range of
historical fluctuations. Since there have been no detections of benzene in either the surface water or sentinel well NES-1, there is no indication that the plume in migrating toward the property
boundary. The plume appears to be stable.
7.0 CONCLUSIONS
Antimony in MW-2R and MW-3R and cobalt in MW-5 were detected above their respective
GWPS; however, they were not above the calculated background concentrations. The County of Granville requests that the background values for antimony and cobalt be considered the GPS at
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First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Granville County - Butner Landfill, Permit No. 39-02 April 2016 9

the Butner Landfill per rule .1634(g.5) of the NCSWMR; in which case there was no
exceedances of the GPS for inorganic constituents from the February 2016 sampling event.

Benzene was detected above the NC-2L in MW-2R during the February 2016 sampling event. In response to the historical benzene exceedances in MW-2R, Granville County submitted an ACM on May 17, 2013, which was approved on June 27, 2013. A CAP was submitted on May 23,
2014 and approved on June 18, 2014. Review of MNA parameter data, plume stability, and
benzene trends indicate that the selected remedies of natural attenuation and phytoremediation
are adequately controlling the plume. The groundwater flow regime is consistent with previous events and the groundwater monitoring
network remains adequate to monitor the site. The next semiannual sampling event is scheduled
for tentatively for August 2016.

8.0 REFERENCES
GAI Consultants – NC, Inc. (GAI), 1994. Ground and Surface Water Monitoring System,
Granville County, Butner Landfill, NC Permit No. 39-02. June, 1994.

Joyce Engineering (JOYCE), 2013. Assessment of Corrective Action, Butner Landfill, Granville County, Permit No. 39-02. May 2013.
Joyce Engineering (JOYCE), 2014. Corrective Action Plan, Butner Landfill, Granville County,
Permit No. 39-02. May 2014.
Newell, Charles J., Ph.D., P.E., R. Kevin McLeod, and James R. Gonzales, 1996. BIOSCREEN Natural Attenuation Decision Support System User’s Manual, Version 1.3. United States
Environmental Protection Agency, Office of Research and Development, Washington
DC. EPA/600/R-96/087. August 1996.
Newell, Charles J., Ph.D., P.E., R. Kevin McLeod, and James R. Gonzales, 1997. BIOSCREEN Natural Attenuation Decision Support System, Version 1.4 Revisions. United States
Environmental Protection Agency, Office of Research and Development, Washington
DC. July 1997.

North Carolina Department of Environment and Natural Resources (NC-DENR), 2011. North Carolina Solid Waste Management Rules. 15 NCAC 13B. Amended April 2011.

NC-DENR, 2007. North Carolina Solid Waste Section Guidelines for Corrective Action at
Solid Waste Management Facilities. March 2007.

9.0 ACRONYMS
ACM Assessment of Corrective Measures (Report)
AOC Area of Concern
______________________________________________________________________________
First Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Granville County - Butner Landfill, Permit No. 39-02 April 2016 10

C&D Construction and Demolition Waste
CAP Corrective Action Plan (Report)
CAER Corrective Action Evaluation Report (Report)
COC Constituent of Concern DENR See NCDENR DL Detection Limit (for laboratory data)
DO Dissolved Oxygen
EPA United States Environmental Protection Agency
GPS Site-specific Groundwater Protection Standards per NCSWMR §1634.g-h GWPS Groundwater Protection Standards (established by DENR-SWS) JOYCE Joyce Engineering
LFG Landfill Gas
MNA Monitored Natural Attenuation
MSW Municipal Solid Waste NC-2B North Carolina Surface Water Standards found in 15A NCAC 2B NC-2L North Carolina Groundwater Standards found in 15A NCAC 2L
NCAC North Carolina Administrative Code
NCDENR North Carolina Department of Environment and Natural Resources (now NCDEQ)
NCDEQ North Carolina Department of Environmental Quality (formerly NCDENR) NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 13B.1600) ND Not Detected (for laboratory data)
NES Nature and Extent Study (Report)
O&M Operations and Maintenance
QL Quantitation Limit (for laboratory data) QRA Quantitative Risk Assessment (Report) RL Reporting Limit (for laboratory data)
SWQS Surface Water Quality Standards
SWS Solid Waste Section (of NCDENR/NCDEQ)
SWSL North Carolina Solid Waste Section Reporting Limits VOC Volatile Organic Compound WQMP Water Quality Monitoring Plan (Report)
WQMR Water Quality Monitoring Report (Report)

TABLES

Table 1 Monitoring Well Construction Data Table 2 Historical Groundwater Elevation Data Table 3 Hydraulic Gradients and Groundwater Flow Velocities
Table 4 Quantified Detections of Groundwater Constituents (February 2016)
Table 5 Exceedances of Groundwater Standards (February 2016)
Table 6 Field Parameters (February 2016)
Table 7 Monitored Natural Attenuation Parameters

TABLE 1: Monitoring Well Construction Data
Permit #Well ID Lat.Long. Surface
Elevation
Top of
Casing
Top of
Screen
Bottom of
Screen
Total
Depth 2WL-24 3WL
8/17/2015
Depth to
Bedrock 4Geologic Unit Construction
Date
Driller's
Reg. #Comments
39-02 MW-1R N36º 09' 55.49"W78º 45' 37.80"461.01 461.01 420.01 405.01 405.01 420.01 417.71 431.01 Fractured
Bedrock 4/21/1994 446 background well
replacement
39-02 MW-2R N36º 09' 38.57"W78º 45' 34.97"326.60 328.94 322.75 307.75 307.75 324.00 328.65 313.60 Weathered
Bedrock 4/12/1994 446 compliance well
replacement
39-02 MW-3R N36º 09' 38.58"W78º 45' 34.85"328.77 330.95 302.94 292.94 292.94 325.77 327.81 315.77 Fractured
Bedrock 4/14/1994 446 compliance well
replacement
39-02 MW-4 N36º 09' 38.93"W78º 45' 30.15"338.97 340.92 322.54 307.54 307.54 329.17 331.05 325.97 Fractured
Bedrock 4/18/1994 446 compliance well
39-02 MW-5 N36º 09' 39.35"W78º 45' 23.77"341.88 344.00 333.36 318.36 318.36 329.08 327.73 324.88 Fractured
Bedrock 4/18/1994 446 compliance well
39-02 MW-6 N36º 09' 47.00"W78º 45' 25.47"360.80 362.80 343.17 328.17 328.17 349.10 347.63 339.60 Fractured
Bedrock 4/19/1994 446 compliance well
39-02 NES-1 N36º 09' 35.65"W78º 45' 31.59"326.22 328.72 311.22 296.22 296.22 304.22 308.80 300.22 Fractured
Bedrock 11/14/2007 2675 sentinel well
Notes:1. Locations & Elevations based on March 2013 survey.Ft-AMSL = Feet above mean sea level.
2. WL-24 = Water Levels approx. 24 hours after well installation.
3. WL = Water Levels measured on 8/17/2015.
4. Geology where well bore ends, documented as fractured metavolcanic bedrock of Carolina slate belt.
Typical Montoring Well Construction, materials are 2 inch SCH40 PVC casing and screen with 0.010 inch slot, sand pack, bentonite seal, grout pad, & steel outer casing.
Montoring Well Summary data is from well construction records, GAI Consultants June 1994, & Joyce Engineering November 2007, and field observations.
WELL ID Other Information1LOCATION1Elevation (Ft-AMSL)
Butner Landfill, Granville County
Permit No. 39-02
Joyce Engineering
TABLE 2: HISTORICAL GROUNDWATER ELEVATION DATA
Background
MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1
Well TOC Elev.:460.51 331.60 330.96 340.80 343.88 362.53 328.40
Well Depth:56.00 18.85 35.83 31.43 23.52 32.63 32.80
21-Aug-99 418.68 329.13 328.06 330.50 330.83 352.10 NI
16-Nov-99 419.75 325.38 324.51 331.53 334.33 352.97 NI
10-May-00 424.53 329.60 328.83 334.15 334.49 355.72 NI
26-Oct-00 419.21 329.26 328.15 331.33 330.94 352.78 NI
18-Apr-01 418.76 329.42 328.63 333.57 334.36 354.22 NI
26-Oct-01 412.53 329.04 327.94 330.57 330.23 350.92 NI
13-Jun-02 413.70 328.38 327.41 330.21 330.29 351.04 NI
19-Nov-02 413.40 329.25 328.35 331.57 337.17 350.94 NI
27-Jun-03 423.61 329.57 328.93 334.24 333.99 355.21 NI
29-Dec-03 420.23 329.70 329.11 334.49 334.78 354.92 NI
30-Jun-04 418.81 329.38 328.48 332.26 331.39 353.10 NI
28-Dec-04 418.02 329.50 328.91 333.45 334.14 355.14 NI
29-Jun-05 418.81 329.10 329.26 331.62 330.90 352.76 NI
29-Dec-05 413.38 329.29 328.71 332.78 334.27 351.52 NI
27-Jun-06 414.75 329.17 328.40 332.18 333.56 353.43 NI
28-Dec-06 415.54 329.40 328.86 333.57 335.24 354.02 NI
12-Jul-07 438.64 328.69 327.97 331.31 330.52 352.30 NI
18-Dec-07 412.59 328.94 328.08 330.32 327.92 347.90 306.54
8-Jul-08 414.52 329.20 326.00 331.46 330.85 351.03 NM
17-Dec-08 412.79 329.39 328.84 333.15 335.03 350.82 NM
9-Jul-09 417.16 329.17 329.48 332.30 331.36 352.17 310.12
16-Dec-09 418.11 329.55 329.09 334.57 336.94 352.87 NM
24-Jun-10 422.42 329.41 328.77 333.65 333.15 353.62 NM
13-Dec-10 415.96 329.49 328.85 332.81 330.34 350.08 NM
20-Jun-11 416.00 328.95 328.18 336.77 331.38 351.83 NM
5-Dec-11 412.94 329.31 328.65 332.32 329.51 349.87 NM
11-Jun-12 414.56 329.10 328.35 332.52 331.33 351.75 312.50
12-Dec-12 412.83 329.19 328.36 331.67 330.35 349.48 NM
1-May-13 415.69 329.65 329.13 334.49 335.15 353.63 317.11
5-Aug-13 417.97 329.02 328.41 333.32 332.83 353.01 NM
24-Feb-14 415.81 329.68 329.17 334.48 331.63 351.78 316.15
11-Aug-14 416.23 329.38 328.48 332.04 329.08 350.08 310.93
10-Mar-15 417.09 329.87 329.45 335.07 336.42 353.13 317.55
17-Aug-15 417.71 328.65 327.81 331.05 327.73 347.63 308.80
17-Feb-16 418.51 330.10 329.71 335.05 337.53 353.44 317.87
Notes: TOC = Top of casing.Groundwater levels and well depth are measured from TOC.
NM = Water level not measured.Groundwater elevations in feet above mean sea level.
NI = Well not yet installed.
Well ID:
Downgradient
Granville County
Butner Landfill, Permit No. 39-02 Joyce Engineering
TABLE 3: ESTIMATED HYDRAULIC GRADIENTS AND GROUNDWATER FLOW VELOCITIES
GROUND-HORIZ.HYDRAULIC EFFECTIVE LINEAR
FLOW WATER GRADIENT,CONDUCTIVITY,POROSITY VELOCITY,
DIRECTION ELEVATION i K ne V
(feet)(ft/ft)(ft/day)(ft/year)
410
350
400
320
410
320
Average 0.0498 Average 6.24
Notes:Hydraulic conductivity (K) value is the average of results from slug-tests conducted in 1994 (GAI, 1994).
Effective Porosity based on average of 90% of reported Total Porosity (GAI, 1995) for soils, or 10% (estimated) for fractured rock.
Linear flow velocity = Ki/n (modified Darcy equation).
i 3 1612
6.14
SSE 0.0558 6.18E-02 0.18
0.18
7.00
6.18E-02
0.18
0.0445
i 2 1633 SE 0.0490 6.18E-02
5.59
February 16, 2016
GRADIENT
CALCULATION
SEGMENT
FLOW LINE
LENGTH
(feet)
i 1 1347 ESE
Based on Water Level Data obtained on:
Granville County
Butner Landfill, Permit No. 39-02
Joyce Engineering
TABLE 4: Quantified Detections of Groundwater Constituents (February 2016)
WELL ID PARAMETER RESULT UNITS SWSL NC2L/*GWPS COLLECT DATE
3902-MW1R Zinc 14.5 µg/L 10 1000 2/16/2016
3902-MW2R Antimony 9.9 µg/L 6 1*2/16/2016
3902-MW2R Barium 123 µg/L 100 700 2/16/2016
3902-MW2R Cobalt 10 µg/L 10 1 2/16/2016
3902-MW2R Nickel 92.0 µg/L 50 100 2/16/2016
3902-MW2R Zinc 16.7 µg/L 10 1000 2/16/2016
3902-MW2R Benzene 1.3 µg/L 1 1 2/16/2016
3902-MW2R 1,4-Dichlorobenzene 2 µg/L 1 6 2/16/2016
3902-MW2R Chlorobenzene 13.5 µg/L 3 50 2/16/2016
3902-MW3R Antimony 6.5 µg/L 6 1*2/16/2016
3902-MW3R Zinc 17.8 µg/L 10 1000 2/16/2016
3902-MW3R 1,4-Dichlorobenzene 1.0 µg/L 1 6 2/16/2016
3902-MW3R Chlorobenzene 16.4 µg/L 3 50 2/16/2016
3902-MW4 Zinc 46.1 µg/L 10 1000 2/16/2016
3902-MW5 Barium 126 µg/L 100 700 2/16/2016
3902-MW5 Cobalt 13.1 µg/L 10 1 2/16/2016
NOTES:All Results in micorgrams per liter (µg/L)
MDL = Method Detection Limit
SWSL = NC Soild Waste Section Reporting Limit
NC2L = NC Groundwater Standard from 15A NCAC 2L.0202
GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L)
Bold= Exceedance of NC2L/GWPS
Butner Landfill, Granville Co.
Permit No. 39-02
Joyce Engineering
TABLE 5: Exceedances of Groundwater Standards (February 2016)
WELL ID PARAMETER RESULT UNITS SWSL NC2L/*GWPS GPS COLLECT DATE
3902-MW2R Antimony 9.9 µg/L 6 1*56 2/16/2016
3902-MW2R Cobalt 10 µg/L 10 1*130 2/16/2016
3902-MW2R Benzene 1.3 µg/L 1 1 1 2/16/2016
3902-MW3R Antimony 6.5 µg/L 6 1*56 2/16/2016
3902-MW5 Cobalt 13.1 µg/L 10 1*130 2/16/2016
NOTES:All Results in micorgrams per liter (µg/L)
SWSL = NC Soild Waste Section Reporting Limit
NC2L = NC Groundwater Standard from 15A NCAC 2L.0202
GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L)
GPS = Groundwater Protection Standard as defined by 15A NCAC 13B.1634(g)
GPS for antimony and cobalt are based on the statistical backgound for the facility.
Bold = GPS Exceedance.
Butner Landfill, Granville Co.
Permit No. 39-02
Joyce Engineering
TABLE 6: Field Parameters (February 2016)
WELL ID PARAMETER RESULT UNITS COLLECT DATE
3902-MW1R pH 6.15 s.u 2/16/2016
3902-MW1R Temperature 14.6 ºC 2/16/2016
3902-MW1R Conductivity 72.4 µS/cm 2/16/2016
3902-MW1R Turbidity 10.50 NTU 2/16/2016
3902-MW1R Dissolved Carbon Dioxide 30.0 mg/L 2/16/2016
3902-MW1R Dissolved Oxygen 4.45 mg/L 2/16/2016
3902-MW1R Ferrous Iron 0.0 mg/L 2/16/2016
3902-MW1R Oxidation Reduction Potential 11.7 mV 2/16/2016
3902-MW1R Static Water Level 42.00 ft 2/16/2016
3902-MW1R Well Depth 56.00 ft 2/16/2016
3902-MW2R pH 6.15 s.u 2/16/2016
3902-MW2R Temperature 13.8 ºC 2/16/2016
3902-MW2R Conductivity 1,611 µS/cm 2/16/2016
3902-MW2R Turbidity 20.2 NTU 2/16/2016
3902-MW2R Dissolved Carbon Dioxide 210 mg/L 2/16/2016
3902-MW2R Dissolved Oxygen 3.66 mg/L 2/16/2016
3902-MW2R Ferrous Iron 4.0 mg/L 2/16/2016
3902-MW2R Oxidation Reduction Potential -47.3 mV 2/16/2016
3902-MW2R Static Water Level 1.50 ft 2/16/2016
3902-MW2R Well Depth 18.85 ft 2/16/2016
3902-MW3R pH 6.61 s.u 2/16/2016
3902-MW3R Temperature 14.4 ºC 2/16/2016
3902-MW3R Conductivity 1,369 µS/cm 2/16/2016
3902-MW3R Turbidity 9.25 NTU 2/16/2016
3902-MW3R Dissolved Carbon Dioxide 230 mg/L 2/16/2016
3902-MW3R Dissolved Oxygen 2.51 mg/L 2/16/2016
3902-MW3R Ferrous Iron 1.3 mg/L 2/16/2016
3902-MW3R Oxidation Reduction Potential 16.9 mV 2/16/2016
3902-MW3R Static Water Level 1.25 ft 2/16/2016
3902-MW3R Well Depth 35.83 ft 2/16/2016
3902-MW4 pH 6.69 s.u 2/16/2016
3902-MW4 Temperature 14.0 ºC 2/16/2016
3902-MW4 Conductivity 1,234 µS/cm 2/16/2016
3902-MW4 Turbidity 10.21 NTU 2/16/2016
3902-MW4 Static Water Level 5.75 ft 2/16/2016
3902-MW4 Well Depth 31.43 ft 2/16/2016
3902-MW5 pH 7.14 s.u 2/16/2016
3902-MW5 Temperature 12.0 ºC 2/16/2016
3902-MW5 Conductivity 164 µS/cm 2/16/2016
3902-MW5 Turbidity 15.3 NTU 2/16/2016
3902-MW5 Static Water Level 6.35 ft 2/16/2016
3902-MW5 Well Depth 23.52 ft 2/16/2016
Butner Landfill, Granville Co.
Permit No. 39-02 1 of 2 Joyce Engineering
TABLE 6: Field Parameters (February 2016)
WELL ID PARAMETER RESULT UNITS COLLECT DATE
3902-MW6 pH 6.10 s.u 2/16/2016
3902-MW6 Temperature 13.4 ºC 2/16/2016
3902-MW6 Conductivity 473.6 µS/cm 2/16/2016
3902-MW6 Turbidity 15.2 NTU 2/16/2016
3902-MW6 Static Water Level 9.09 ft 2/16/2016
3902-MW6 Well Depth 32.63 ft 2/16/2016
3902-NES1 pH 5.62 s.u 2/16/2016
3902-NES1 Temperature 13.1 ºC 2/16/2016
3902-NES1 Conductivity 78.2 µS/cm 2/16/2016
3902-NES1 Turbidity 8.75 NTU 2/16/2016
3902-NES1 Dissolved Carbon Dioxide 20 mg/L 2/16/2016
3902-NES1 Dissolved Oxygen 3.72 mg/L 2/16/2016
3902-NES1 Ferrous Iron 0.0 mg/L 2/16/2016
3902-NES1 Oxidation Reduction Potential 173.4 mV 2/16/2016
3902-NES1 Static Water Level 10.53 ft 2/16/2016
3902-NES1 Well Depth 36.1 ft 2/16/2016
3902-SW1 Conductivity 44.5 µS/cm 2/16/2016
3902-SW1 pH 6.29 S.U.2/16/2016
3902-SW1 Temperature 7.9 ºC 2/16/2016
3902-SW1 Turbidity 27.8 NTU 2/16/2016
3902-SW2 Conductivity 40.2 µS/cm 2/16/2016
3902-SW2 pH 5.61 S.U.2/16/2016
3902-SW2 Temperature 7.6 ºC 2/16/2016
3902-SW2 Turbidity 25 NTU 2/16/2016
Units: ºC= degrees Centigrade
S.U.= Standard Units
µS/cm = micro-Seimens per centimeter
NTU = Nephelometric Turbidity Units
mV= milivolts
mg/L= miligrams per liter
Butner Landfill, Granville Co.
Permit No. 39-02 2 of 2 Joyce Engineering
TABLE 7: MONITORED NATURAL ATTENUATION PARAMETERS
Background Sentinel
Parameter Date Units DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1
Temperature 12/30/03 ºC --15.4 11.1 11.2 12.5 13.6 14.2 -(FP)12/19/07 ºC --12.3 12.5 13.1 14.4 14.9 14.4 13.3
05/01/13 ºC --15.7 13.7 15.1 14.4 14.2 14.2 12.5
08/14/14 ºC --17.8 18.0 19.2 19.4 16.8 17.2 16.0
03/10/15 ºC --17.3 16.0 15.9 13.8 13.3 13.7 16.108/18/15 ºC --16.4 17.8 17.8 17.3 16.5 16.6 16.1
02/16/16 ºC --14.6 13.8 14.4 14.0 12.0 13.4 13.1
pH 12/30/03 SU --7.31 6.54 6.81 6.90 7.24 7.29 -(FP)12/19/07 SU --6.89 6.90 7.07 6.87 7.39 6.67 7.64
05/01/13 SU --7.32 6.37 6.61 6.42 6.92 7.13 6.10
08/14/14 SU --5.84 6.36 6.96 6.79 7.00 6.48 5.59
03/10/15 SU --6.11 6.37 6.56 6.30 6.25 6.55 5.68
08/18/15 SU --5.12 6.68 6.48 6.76 7.03 6.78 4.94
02/16/16 SU --6.15 6.15 6.61 6.69 7.14 6.10 6.52
Conductivity 12/19/07 µS/cm --96 1,964 1,591 1,245 --510
(FP)05/01/13 µS/cm --111 1,587 1,357 1,150 195 594 69.6
08/14/14 µS/cm --231 1,897 1,534 1,413 522 565 172.6
03/10/15 µS/cm --90 996 1,277 1,186 106 504 114
08/18/15 µS/cm --134 1,630 1,680 1,244 617 534 83
02/16/16 µS/cm --72.4 1,611 1,369 1,234 164 474 78.2
Redox Potential 12/30/03 mV --257.2 76.2 207.6 212.7 187.3 123.6 -
ORP 12/19/07 mV --146 45.0 142 134 --138
(FP)05/01/13 mV --111.7 -26.7 55.2 120.5 - -227.108/14/14 mV --115.8 -37.2 86.9 -- --
03/10/15 mV --87.0 0.8 56.3 -- -96.7
08/18/15 mV --134.7 -96.3 -68.8 -33.9 -49.9 -182.8
02/16/16 mV --111.7 -47.3 16.9 NS NS -173.4
Dissolved Oxygen 12/30/03 mg/L --9.49 4.84 26.19 24.19 15.31 20.17 -
DO 12/19/07 mg/L ---1.88 1.44 3.21 --0.70
(FP)05/01/13 mg/L --4.40 1.37 1.79 4.65 --2.9008/14/14 mg/L --4.44 3.26 2.48 ---2.80
03/10/15 mg/L --3.84 1.47 1.80 ---1.85
08/18/15 mg/L --4.95 5.75 1.30 -3.79 -1.77
02/16/16 mg/L --4.45 3.66 2.51 ---3.72
Dissolved CO2 12/19/07 mg/L --25 365 175 295 --60
(FP)05/01/13 mg/L --30.0 245 125 225 --45
08/14/14 mg/L --60.0 390 185 ---75
03/10/15 mg/L --50.0 110 75 ---5008/18/15 mg/L --30.0 275 125 ---60
02/16/16 mg/L --30.0 210 230 ---20
Downgradient
Butner Landfill, Granville Co.
Permit No. 39-02 Page 1 of 4
Joyce Engineering
TABLE 7: MONITORED NATURAL ATTENUATION PARAMETERS
Background Sentinel
Parameter Date Units DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1
Downgradient
Fe, Ferrous (+2)12/30/03 mg/L --ND 1.5 ND ND 0.22 ND -
(FP)12/19/07 mg/L --ND 7.2 ND ND --0.2
05/01/13 mg/L --0.0 1.0 0.0 0.0 --0.0
08/14/14 mg/L --0.0 2.5 0 ---0.0
03/10/15 mg/L --0.0 5.3 0 ---0.008/18/15 mg/L --0.0 4.5 1 ---0.0
02/16/16 mg/L --0.0 4.0 1 ---0.0
Alkalinity (as CaCO3)12/30/03 mg/L 9.00 10.0 37.0 800 690 640 68.0 350 -12/19/07 mg/L -5.00 39.0 763 726 619 --190
05/01/13 mg/L 1.00 5.00 43.4 757 660.0 645.0 --10.4
08/14/14 mg/L 1.00 5.00 41.1 784.0 661.0 ---14.5
03/10/15 mg/L 1.00 5.00 38.0 744.0 653.0 ---8.8
08/18/15 mg/L 1.00 5.00 37.8 772.0 664.0 ---10.3
02/16/16 mg/L 1.00 5.00 41.2 792.0 741.0 ---8.73
Chloride 12/30/03 mg/L 0.200 1.00 3.50 280 170 82.0 13.0 44.0 -
12/19/07 mg/L -5.00 ND 13.1 297 89.1 --7.90
05/01/13 mg/L 0.5 1.00 3.54 258 180 123 --2.85
08/14/14 mg/L 0.5 1.00 5.53 264 144 ---5.00
03/10/15 mg/L 0.5 1.00 3.80 266 194 ---4.09
08/18/15 mg/L 0.5 1.00 4.69 267 178 ---3.9002/16/16 mg/L 0.5 1.00 3.92 274 186 ---3.24
Dissolved Hydrogen 05/01/13 nM 0.074 0.60 0.400 0.630 0.610 0.500 --0.470
08/14/14 nM 0.13 0.60 1.4 1.6 5.4 ---1.403/10/15 nM 0.13 0.60 1.2 1.4 1.4 1.0 --1.4
08/18/15 nM 0.13 0.60 1.7 2.2 1.7 ---1.5
02/16/16 nM 0.13 0.60 2.0 1.7 1.9 ---1.5
Nitrate-N 12/30/03 mg/L 0.0200 0.0500 0.120 ND ND ND ND 0.13 -
12/19/07 mg/L -0.100 ND ND ND ND --13.0
05/01/13 mg/L 0.001 10.0 0.163 ND ND ND --3.58
08/14/14 mg/L 0.001 10.0 0.115 J ND ND ---2.02 J03/10/15 mg/L 0.001 10.0 0.252 J ND ND ---2.56 J
08/18/15 mg/L 0.001 10.0 .124 J ND ND ---3.27 J
02/16/16 mg/L 0.001 10.0 .36 J ND ND ---2.54 J
Sulfate 12/30/03 mg/L 0.0600 2.00 ND ND ND 2.60 9.60 9.00 -
12/19/07 mg/L -5.00 ND ND ND ND --36.8
05/01/13 mg/L 1 250 ND ND ND 4.69 --10.7
08/14/14 mg/L 1 250 1.08 J 1.2 J ND ---5.84 J
03/10/15 mg/L 1 250 1.52 J 1.13 J 1.52 J ---7.04 J
08/18/15 mg/L 1 250 1.56 J 1.31 J 2.49 J ---524 J
02/16/16 mg/L 1 250 1.5 J 1.7 J 1.8 J ---10.0 J
Sulfide 08/14/14 mg/L 0.05 1.00 ND ND ND ---ND
03/10/15 mg/L 0.05 1.00 ND ND ND ---ND
08/18/15 mg/L 0.05 1.00 ND ND ND ---1.0
02/16/16 mg/L 0.05 1.00 ND ND ND ---ND
Butner Landfill, Granville Co.
Permit No. 39-02 Page 2 of 4
Joyce Engineering
TABLE 7: MONITORED NATURAL ATTENUATION PARAMETERS
Background Sentinel
Parameter Date Units DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1
Downgradient
Total Organic Carbon 12/19/07 mg/L -1.0 *2.9 54.3 23.2 17.2 --7.2005/01/13 mg/L 0.5 1.00 2.24 29.5 30.0 19.4 --5.74
08/14/14 mg/L 0.5 1.00 ND 229.00 25.5 ---8.39
03/10/15 mg/L 0.5 1.00 .781J 34.8 9.5 ---1.88
08/18/15 mg/L 0.5 1.00 0.917J 32.9 9.86 ---27.8002/16/16 mg/L 0.5 1.00 1.500 27.6 8.46 ---40.90
Biochemical Oxygen Demand 08/14/14 mg/L 2.0 2.00 ND 83.4 2.49 ----
BOD 03/10/15 mg/L 2.0 2.00 2.55 10.6 ND ---ND08/18/15 mg/L 2.0 2.00 2.22 11.8 2.0 ---2.00
02/16/16 mg/L 2.0 2.00 ND 60.0 6.6 ---ND
Chemical Oxygen Demand 08/14/14 mg/L 12.5 25.0 ND 132.0 ND ---50.00
COD 03/10/15 mg/L 12.5 25.00 15.0J 235.0 96.0 ---ND
08/18/15 mg/L 12.5 25.00 25.00 110.0 756.0 ---25.00
02/16/16 mg/L 12.5 25.00 ND 295.0 50.0 ---ND
Dissolved Ethane 12/30/03 mg/L 0.0002 0.0010 ND ND ND ND ND ND -
12/19/07 mg/L -20.0 ND ND ND ND --ND
05/01/13 mg/L 0.0031 0.0062 ND ND ND ND --ND
08/14/14 mg/L 0.0031 0.0062 ND ND 0.0036 J ---ND
03/10/15 mg/L 0.0031 0.0062 ND ND ND ---ND08/18/15 mg/L 0.0031 0.0062 0.01 0.01 0.01 ---0.01
02/16/16 mg/L 0.0031 0.0062 ND ND ND ---ND
Dissolved Ethene 12/01/03 mg/L 0.0003 0.0010 ND ND ND ND ND ND -12/19/07 mg/L -20.0 ND ND ND ND --ND
05/01/13 mg/L 0.0031 0.0062 ND ND 0.0017 ND --ND
08/14/14 mg/L 0.0031 0.0062 ND ND ND ---ND
03/10/15 mg/L 0.0031 0.0062 ND ND ND ---ND08/18/15 mg/L 0.0031 0.0062 0.01 0.01 0.01 ---0.01
02/16/16 mg/L 0.0031 0.0062 ND ND ND ---ND
Dissolved Methane 12/30/03 mg/L 0.0002 0.0010 ND 0.660 0.130 0.0099 0.0010 ND -12/19/07 mg/L -10.0 ND 0.116 0.186 ND --ND
05/01/13 mg/L 0.0033 0.0066 ND 0.0379 0.100 0.0337 --ND
08/14/14 mg/L 0.0033 0.0066 ND 1.2900 0.284 ---ND
03/10/15 mg/L 0.0033 0.0066 0.0072 0.9960 0.158 ---ND
08/18/15 mg/L 0.0033 0.0066 0.0027 2.16 0.316 ---0.0013
02/16/16 mg/L 0.0033 0.0066 0.007 J 0.87 0.098 ---0.0016 J
Butner Landfill, Granville Co.
Permit No. 39-02 Page 3 of 4
Joyce Engineering
TABLE 7: MONITORED NATURAL ATTENUATION PARAMETERS
Background Sentinel
Parameter Date Units DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1
Downgradient
Pyruvic Acid 12/19/07 mg/L 2.50 ND 1.50 2.00 --1.2005/01/13 mg/L 2 10 ND ND ND ND --ND
08/14/14 mg/L 0.77 10 ND ND ND ---ND
03/10/15 mg/L 0.77 10 0.41J 0.41J 0.41J ---0.41J
08/18/15 mg/L 0.77 10 ND ND ND ---ND02/16/16 mg/L 0.77 10 ND ND ND ---ND
Lactic Acid 12/19/07 mg/L ND 5.40 11.9 3.10 --ND
05/01/13 mg/L 2.3 25 ND ND ND ND --ND08/14/14 mg/L 2.5 25 4.2 J ND ND ---ND
03/10/15 mg/L 2.5 25 ND ND ND ---ND
08/18/15 mg/L 2.5 25 ND ND ND ---ND
02/16/16 mg/L 2.5 25 ND ND ND ---ND
Acetic Acid 12/19/07 mg/L ND ND ND ND --ND
05/01/13 mg/L 1.8 5 ND ND ND ND --ND
08/14/14 mg/L 0.81 5.0 ND ND ND ---ND
03/10/15 mg/L 0.81 5.0 ND ND ND ---ND
08/18/15 mg/L 0.81 5.0 ND ND 0.97 J ---ND
02/16/16 mg/L 0.81 5.0 ND ND ND ---ND
Propionic Acid 12/19/07 mg/L ND 63.7 38.3 12.8 --ND05/01/13 mg/L 1 5 ND ND ND ND --ND
08/14/14 mg/L 0.66 5.0 ND ND ND ---ND
03/10/15 mg/L 0.66 5.0 ND ND ND ---ND
08/18/15 mg/L 0.66 5.0 ND ND ND ---ND02/16/16 mg/L 0.66 5.0 ND ND ND ---ND
Butyric Acid 12/19/07 mg/L ND ND ND ND --ND
05/01/13 mg/L 0.87 5 ND ND ND ND --ND08/14/14 mg/L 0.70 5.0 ND ND ND ---ND
03/10/15 mg/L 0.70 5.0 ND ND ND ---ND
08/18/15 mg/L 0.70 5.0 ND ND ND ---ND
02/16/16 mg/L 0.70 5.0 ND ND ND ---ND
Total Volatile Fatty Acids 12/19/07 mg/L 2.50 69.10 51.70 17.90 --1.20
(sum of above 5 acids)05/01/13 mg/L ND ND ND ---ND
08/14/14 mg/L 4.2 J ND ND ---ND
03/10/15 mg/L ND ND ND ---ND
08/18/15 mg/L ND ND 0.97 J ---ND
02/16/16 mg/L ND ND ND ---ND
NOTES:
DL = laboratory detection limit.mg/L = milligrams per liter ºC = degress Celcius
RL = laboratory reporting limit.mV = millivolt µS/cm = micro-Siemen per centimeter
ND = not detected above detection limit.SU = standard unit ntu = nephelometric turbidity units
J = estimated concentration between the DL and the RL.nM = nano-Molar
- = not analyzed.
DL and QL for Alkalinity for Dec. 03 event was 1 and 2 respectively for wells MW-2R, -3R, and -4 due to different methods used by the labrotory.
* = RL for MW-1R - 1.0, MW-2R - 5.0, MW-3R - 5.0, MW-4 - 2.0, NES-1 - 5.0.
Methane in December 2007 was out of hold time for MW-2R, MW-3R, MW-4, and NES-1.
Butner Landfill, Granville Co.
Permit No. 39-02 Page 4 of 4
Joyce Engineering

CHART

Chart 1 Benzene Concentrations vs. Time

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Joyce Engineering December 2015
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MW-1R MW-2R MW-3R MW-4R MW-5 MW-6 NES-1 NC 2L = 1.0

FIGURE

Figure 1 Site Location Map

DRAWING

Drawing 1 Groundwater Potentiometric Surface Map

APPENDICES

Appendix A Field Data Logs
Appendix B Laboratory Analytical Reports
Appendix C Historical Constituents in Groundwater Appendix D Historical Constituents in Surface Water
Appendix E Statistical Analyses Worksheets & Summary

Appendix A

Field Data Logs

Appendix B

Laboratory Analytical Reports

#=CL#
February 25, 2016
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92286780
92286780
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
Butner Landfill Compliance
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on February 17, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Dale Ingram
[e-mail]
Project Manager
Enclosures
cc: Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 79
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174Alabama Certification #: 41320
Connecticut Certification #: PH-0216Delaware Certification: FL NELAC ReciprocityFlorida Certification #: E83079
Georgia Certification #: 955Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC ReciprocityIllinois Certification #: 200068Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007Maryland Certification: #346Michigan Certification #: 9911
Mississippi Certification: FL NELAC ReciprocityMissouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608North Carolina Environmental Certificate #: 667North Carolina Certification #: 12710
North Dakota Certification #: R-216Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547Puerto Rico Certification #: FL01264South Carolina Certification: #96042001
Tennessee Certification #: TN02974Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC ReciprocityVirginia Environmental Certification #: 460165Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962CWisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 79
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Lab ID Sample ID Matrix Date Collected Date Received
92286780001 3902-MW1R Water 02/16/16 17:45 02/17/16 09:25
92286780002 3902-MW2R Water 02/16/16 14:55 02/17/16 09:25
92286780003 3902-MW3R Water 02/16/16 15:15 02/17/16 09:25
92286780004 3902-Field Blank Water 02/16/16 18:05 02/17/16 09:25
92286780005 3902-MW4 Water 02/16/16 15:55 02/17/16 09:25
92286780006 3902-MW5 Water 02/16/16 16:02 02/17/16 09:25
92286780007 3902-MW6 Water 02/16/16 16:20 02/17/16 09:25
92286780008 3902-SW1 Water 02/16/16 16:10 02/17/16 09:25
92286780009 3902-SW2 Water 02/16/16 13:24 02/17/16 09:25
92286780010 3902-NES1 Water 02/16/16 17:05 02/17/16 09:25
92286780011 3902-Trip Blank Water 02/16/16 08:00 02/17/16 09:25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 79
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92286780001 3902-MW1R EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 12 PASI-OJTJ
EPA 6010 16 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8270 111 PASI-CBPJ
EPA 8260 67 PASI-CGAW
SM 4500-S2D 1 PASI-ASAM
SM 4500-CN-E 1 PASI-AAES2
92286780002 3902-MW2R EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 12 PASI-OJTJ
EPA 6010 16 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8270 111 PASI-CBPJ
EPA 8260 67 PASI-CGAW
SM 4500-S2D 1 PASI-ASAM
SM 4500-CN-E 1 PASI-AAES2
92286780003 3902-MW3R EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 12 PASI-OJTJ
EPA 6010 16 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8270 111 PASI-CBPJ
EPA 8260 67 PASI-CGAW
SM 4500-S2D 1 PASI-ASAM
SM 4500-CN-E 1 PASI-AAES2
92286780004 3902-Field Blank EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 12 PASI-OJTJ
EPA 6010 16 PASI-ACDF
EPA 7470 1 PASI-AHVK
EPA 8270 111 PASI-CBPJ
EPA 8260 67 PASI-CGAW
SM 4500-S2D 1 PASI-ASAM
SM 4500-CN-E 1 PASI-AAES2
92286780005 3902-MW4 EPA 6010 15 PASI-ACDF
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 79
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
EPA 8260 50 PASI-CGAW
92286780006 3902-MW5 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CGAW
92286780007 3902-MW6 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CGAW
92286780008 3902-SW1 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CGAW
92286780009 3902-SW2 EPA 6010 15 PASI-ACDF
EPA 8260 50 PASI-CGAW
92286780010 3902-NES1 EPA 8260 50 PASI-CGAW
92286780011 3902-Trip Blank EPA 8260 67 PASI-CGAW
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 79
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92286780001 3902-MW1R
Barium 5.2J ug/L 02/23/16 17:35100EPA 6010
Vanadium 2.7J ug/L 02/23/16 17:3525.0EPA 6010
Zinc 14.5 ug/L 02/19/16 23:2410.0EPA 6010
92286780002 3902-MW2R
Antimony 9.9 ug/L 02/19/16 23:276.0EPA 6010
Barium 123 ug/L 02/23/16 17:39100EPA 6010
Cobalt 10.0 ug/L 02/19/16 23:2710.0EPA 6010
Nickel 92.0 ug/L 02/23/16 17:3950.0EPA 6010
Tin 28.6J ug/L 02/19/16 23:27100EPA 6010
Vanadium 3.3J ug/L 02/23/16 17:3925.0EPA 6010
Zinc 16.7 ug/L 02/19/16 23:2710.0EPA 6010
Benzene 1.3 ug/L 02/18/16 19:411.0EPA 8260
Chlorobenzene 13.5 ug/L 02/18/16 19:413.0EPA 8260
Chloroethane 1.1J ug/L 02/18/16 19:4110.0EPA 8260
1,2-Dichlorobenzene 1.1J ug/L 02/18/16 19:415.0EPA 8260
1,4-Dichlorobenzene 2.0 ug/L 02/18/16 19:411.0EPA 8260
Isobutanol 42.5J ug/L 02/18/16 19:41100EPA 8260
Naphthalene 5.7J ug/L 02/18/16 19:4110.0EPA 8260
92286780003 3902-MW3R
Antimony 6.5 ug/L 02/19/16 23:306.0EPA 6010
Barium 72.7J ug/L 02/23/16 17:54100EPA 6010
Copper 7.8J ug/L 02/19/16 23:3010.0EPA 6010
Nickel 35.4J ug/L 02/23/16 17:5450.0EPA 6010
Tin 10.4J ug/L 02/19/16 23:30100EPA 6010
Zinc 17.8 ug/L 02/19/16 23:3010.0EPA 6010
Benzene 0.56J ug/L 02/18/16 19:581.0EPA 8260
Chlorobenzene 16.4 ug/L 02/18/16 19:583.0EPA 8260
Chloroethane 1.8J ug/L 02/18/16 19:5810.0EPA 8260
1,2-Dichlorobenzene 1.4J ug/L 02/18/16 19:585.0EPA 8260
1,4-Dichlorobenzene 1.0 ug/L 02/18/16 19:581.0EPA 8260
92286780005 3902-MW4
Antimony 4.3J ug/L 02/19/16 23:376.0EPA 6010
Barium 3.0J ug/L 02/23/16 18:01100EPA 6010
Nickel 12.7J ug/L 02/23/16 18:0150.0EPA 6010
Vanadium 14.4J ug/L 02/23/16 18:0125.0EPA 6010
Zinc 46.1 ug/L 02/19/16 23:3710.0EPA 6010
Chlorobenzene 1.5J ug/L 02/18/16 20:323.0EPA 8260
Chloroethane 0.79J ug/L 02/18/16 20:3210.0EPA 8260
1,1-Dichloroethane 0.45J ug/L 02/18/16 20:325.0EPA 8260
92286780006 3902-MW5
Barium 126 ug/L 02/23/16 18:04100EPA 6010
Cobalt 13.1 ug/L 02/19/16 23:4010.0EPA 6010
Copper 5.1J ug/L 02/19/16 23:4010.0EPA 6010
Nickel 3.7J ug/L 02/23/16 18:0450.0EPA 6010
Zinc 5.9J ug/L 02/19/16 23:4010.0EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 79
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92286780008 3902-SW1
Barium 33.1J ug/L 02/23/16 18:10100EPA 6010
Chromium 4.6J ug/L 02/19/16 23:4610.0EPA 6010
Copper 2.9J ug/L 02/19/16 23:4610.0EPA 6010
Nickel 2.9J ug/L 02/23/16 18:1050.0EPA 6010
Vanadium 4.1J ug/L 02/23/16 18:1025.0EPA 6010
Zinc 7.0J ug/L 02/19/16 23:4610.0EPA 6010
92286780009 3902-SW2
Barium 33.5J ug/L 02/23/16 18:13100EPA 6010
Chromium 6.8J ug/L 02/19/16 23:5910.0EPA 6010
Copper 3.4J ug/L 02/19/16 23:5910.0EPA 6010
Nickel 4.7J ug/L 02/19/16 23:5950.0EPA 6010
Vanadium 5.8J ug/L 02/23/16 18:1325.0EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW1R Lab ID: 92286780001 Collected: 02/16/16 17:45 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 02/20/16 02:06 309-00-202/18/16 09:150.050 0.050 1
alpha-BHC ND ug/L 02/20/16 02:06 319-84-602/18/16 09:150.050 0.050 1
beta-BHC ND ug/L 02/20/16 02:06 319-85-702/18/16 09:150.050 0.050 1
delta-BHC ND ug/L 02/20/16 02:06 319-86-802/18/16 09:150.050 0.050 1
gamma-BHC (Lindane)ND ug/L 02/20/16 02:06 58-89-902/18/16 09:150.050 0.050 1
Chlordane (Technical)ND ug/L 02/20/16 02:06 57-74-902/18/16 09:150.50 0.20 1
4,4'-DDD ND ug/L 02/20/16 02:06 72-54-802/18/16 09:150.10 0.050 1
4,4'-DDE ND ug/L 02/20/16 02:06 72-55-902/18/16 09:150.10 0.050 1
4,4'-DDT ND ug/L 02/20/16 02:06 50-29-302/18/16 09:150.10 0.050 1
Dieldrin ND ug/L 02/20/16 02:06 60-57-102/18/16 09:150.075 0.050 1
Endosulfan I ND ug/L 02/20/16 02:06 959-98-802/18/16 09:150.10 0.050 1
Endosulfan II ND ug/L 02/20/16 02:06 33213-65-902/18/16 09:150.10 0.050 1
Endosulfan sulfate ND ug/L 02/20/16 02:06 1031-07-802/18/16 09:150.10 0.050 1
Endrin ND ug/L 02/20/16 02:06 72-20-802/18/16 09:150.10 0.050 1
Endrin aldehyde ND ug/L 02/20/16 02:06 7421-93-402/18/16 09:150.10 0.050 1
Heptachlor ND ug/L 02/20/16 02:06 76-44-802/18/16 09:150.050 0.050 1
Heptachlor epoxide ND ug/L 02/20/16 02:06 1024-57-302/18/16 09:150.075 0.050 1
Methoxychlor ND ug/L 02/20/16 02:06 72-43-502/18/16 09:151.0 0.15 1
Toxaphene ND ug/L 02/20/16 02:06 8001-35-202/18/16 09:151.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)77 %02/20/16 02:06 877-09-802/18/16 09:1520-130 1
Decachlorobiphenyl (S)61 %02/20/16 02:06 2051-24-302/18/16 09:1520-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 02/19/16 00:28 12674-11-202/17/16 14:000.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 02/19/16 00:28 11104-28-202/17/16 14:000.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 02/19/16 00:28 11141-16-502/17/16 14:000.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 02/19/16 00:28 53469-21-902/17/16 14:000.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 02/19/16 00:28 12672-29-602/17/16 14:000.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 02/19/16 00:28 11097-69-102/17/16 14:000.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 02/19/16 00:28 11096-82-502/17/16 14:000.50 0.50 1
Surrogates
Decachlorobiphenyl (S)42 %02/19/16 00:28 2051-24-302/17/16 14:0010-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
Bentazon ND ug/L 02/23/16 01:04 25057-89-002/22/16 08:200.097 0.016 1
2,4-D ND ug/L 02/23/16 01:04 94-75-702/22/16 08:200.96 0.23 1
Dalapon ND ug/L 02/23/16 01:04 75-99-002/22/16 08:200.93 0.44 1
2,4-DB ND ug/L 02/23/16 01:04 94-82-602/22/16 08:201.9 0.52 1
Dicamba ND ug/L 02/23/16 01:04 1918-00-902/22/16 08:200.096 0.031 1
Dichlorprop ND ug/L 02/23/16 01:04 120-36-502/22/16 08:200.67 0.20 1
Dinoseb ND ug/L 02/23/16 01:04 88-85-702/22/16 08:200.19 0.058 1
Pentachlorophenol ND ug/L 02/23/16 01:04 87-86-502/22/16 08:200.029 0.017 1
Picloram ND ug/L 02/23/16 01:04 1918-02-102/22/16 08:200.097 0.019 1
2,4,5-T ND ug/L 02/23/16 01:04 93-76-502/22/16 08:200.19 0.043 1
2,4,5-TP (Silvex)ND ug/L 02/23/16 01:04 93-72-102/22/16 08:200.19 0.050 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW1R Lab ID: 92286780001 Collected: 02/16/16 17:45 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
Surrogates
2,4-DCAA (S)82 %02/23/16 01:04 19719-28-902/22/16 08:2036-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 02/19/16 23:24 7440-36-002/18/16 18:306.0 3.8 1
Arsenic ND ug/L 02/19/16 23:24 7440-38-202/18/16 18:3010.0 2.5 1
Barium 5.2J ug/L 02/23/16 17:35 7440-39-302/18/16 18:30100 2.5 1
Beryllium ND ug/L 02/23/16 17:35 7440-41-702/18/16 18:301.0 0.50 1
Cadmium ND ug/L 02/19/16 23:24 7440-43-902/18/16 18:301.0 0.50 1
Chromium ND ug/L 02/19/16 23:24 7440-47-302/18/16 18:3010.0 2.5 1
Cobalt ND ug/L 02/19/16 23:24 7440-48-402/18/16 18:3010.0 2.5 1
Copper ND ug/L 02/19/16 23:24 7440-50-802/18/16 18:3010.0 2.5 1
Lead ND ug/L 02/19/16 23:24 7439-92-102/18/16 18:3010.0 2.5 1
Nickel ND ug/L 02/23/16 17:35 7440-02-002/18/16 18:3050.0 2.5 1
Selenium ND ug/L 02/19/16 23:24 7782-49-202/18/16 18:3010.0 5.0 1
Silver ND ug/L 02/19/16 23:24 7440-22-402/18/16 18:3010.0 2.5 1
Thallium ND ug/L 02/19/16 23:24 7440-28-002/18/16 18:305.5 5.0 1
Tin ND ug/L 02/19/16 23:24 7440-31-502/18/16 18:30100 2.5 1
Vanadium 2.7J ug/L 02/23/16 17:35 7440-62-202/18/16 18:3025.0 2.5 1
Zinc 14.5 ug/L 02/19/16 23:24 7440-66-602/18/16 18:3010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 02/24/16 14:53 7439-97-602/22/16 16:200.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 02/23/16 18:59 83-32-902/18/16 11:0010.0 0.25 1
Acenaphthylene ND ug/L 02/23/16 18:59 208-96-802/18/16 11:0010.0 0.21 1
Acetophenone ND ug/L 02/23/16 18:59 98-86-202/18/16 11:0010.0 2.0 1
2-Acetylaminofluorene ND ug/L 02/23/16 18:59 53-96-302/18/16 11:0020.0 0.84 1
4-Aminobiphenyl ND ug/L 02/23/16 18:59 92-67-102/18/16 11:0020.0 0.92 1
Anthracene ND ug/L 02/23/16 18:59 120-12-702/18/16 11:0010.0 0.14 1
Benzo(a)anthracene ND ug/L 02/23/16 18:59 56-55-302/18/16 11:0010.0 0.33 1
Benzo(a)pyrene ND ug/L 02/23/16 18:59 50-32-802/18/16 11:0010.0 0.30 1
Benzo(b)fluoranthene ND ug/L 02/23/16 18:59 205-99-202/18/16 11:0010.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 02/23/16 18:59 191-24-202/18/16 11:0010.0 0.38 1
Benzo(k)fluoranthene ND ug/L 02/23/16 18:59 207-08-902/18/16 11:0010.0 0.43 1
Benzyl alcohol ND ug/L 02/23/16 18:59 100-51-602/18/16 11:0020.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 02/23/16 18:59 101-55-302/18/16 11:0010.0 1.3 1
Butylbenzylphthalate ND ug/L 02/23/16 18:59 85-68-702/18/16 11:0010.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 02/23/16 18:59 59-50-702/18/16 11:0020.0 4.2 1
4-Chloroaniline ND ug/L 02/23/16 18:59 106-47-802/18/16 11:0020.0 3.4 1
Chlorobenzilate ND ug/L 02/23/16 18:59 510-15-602/18/16 11:0010.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 02/23/16 18:59 111-91-102/18/16 11:0010.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 02/23/16 18:59 111-44-402/18/16 11:0010.0 1.5 1
bis(2-Chloroisopropyl) ether ND ug/L 02/23/16 18:59 108-60-102/18/16 11:0010.0 1.6 1
2-Chloronaphthalene ND ug/L 02/23/16 18:59 91-58-702/18/16 11:0010.0 2.2 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW1R Lab ID: 92286780001 Collected: 02/16/16 17:45 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
2-Chlorophenol ND ug/L 02/23/16 18:59 95-57-802/18/16 11:0010.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 02/23/16 18:59 7005-72-302/18/16 11:0010.0 2.1 1
Chrysene ND ug/L 02/23/16 18:59 218-01-902/18/16 11:0010.0 0.21 1
Diallate ND ug/L 02/23/16 18:59 2303-16-402/18/16 11:0010.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 02/23/16 18:59 53-70-302/18/16 11:0010.0 0.55 1
Dibenzofuran ND ug/L 02/23/16 18:59 132-64-902/18/16 11:0010.0 1.8 1
3,3'-Dichlorobenzidine ND ug/L 02/23/16 18:59 91-94-102/18/16 11:0020.0 1.4 1
2,4-Dichlorophenol ND ug/L 02/23/16 18:59 120-83-202/18/16 11:0010.0 1.7 1
2,6-Dichlorophenol ND ug/L 02/23/16 18:59 87-65-002/18/16 11:0010.0 1.8 1
Diethylphthalate ND ug/L 02/23/16 18:59 84-66-202/18/16 11:006000 1.3 1
Dimethoate ND ug/L 02/23/16 18:59 60-51-502/18/16 11:0020.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 02/23/16 18:59 60-11-702/18/16 11:0010.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 02/23/16 18:59 57-97-602/18/16 11:0010.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 02/23/16 18:59 119-93-702/18/16 11:0010.0 2.1 1
2,4-Dimethylphenol ND ug/L 02/23/16 18:59 105-67-902/18/16 11:0010.0 2.2 1
Dimethylphthalate ND ug/L 02/23/16 18:59 131-11-302/18/16 11:0010.0 1.5 1
Di-n-butylphthalate ND ug/L 02/23/16 18:59 84-74-202/18/16 11:0010.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 02/23/16 18:59 534-52-102/18/16 11:0050.0 1.7 1
1,3-Dinitrobenzene ND ug/L 02/23/16 18:59 99-65-002/18/16 11:0020.0 1.5 1
2,4-Dinitrophenol ND ug/L 02/23/16 18:59 51-28-502/18/16 11:0050.0 6.5 1
2,4-Dinitrotoluene ND ug/L 02/23/16 18:59 121-14-202/18/16 11:0010.0 1.2 1
2,6-Dinitrotoluene ND ug/L 02/23/16 18:59 606-20-202/18/16 11:0010.0 1.7 1
Di-n-octylphthalate ND ug/L 02/23/16 18:59 117-84-002/18/16 11:0010.0 0.86 1
Diphenylamine ND ug/L 02/23/16 18:59 122-39-402/18/16 11:0010.0 1.3 1
Disulfoton ND ug/L 02/23/16 18:59 298-04-402/18/16 11:0010.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 02/23/16 18:59 117-81-702/18/16 11:0015.0 0.85 1
Ethyl methanesulfonate ND ug/L 02/23/16 18:59 62-50-002/18/16 11:0020.0 1.8 1
Famphur ND ug/L 02/23/16 18:59 52-85-702/18/16 11:0020.0 1.7 1
Fluoranthene ND ug/L 02/23/16 18:59 206-44-002/18/16 11:0010.0 0.21 1
Fluorene ND ug/L 02/23/16 18:59 86-73-702/18/16 11:0010.0 0.21 1
Hexachlorobenzene ND ug/L 02/23/16 18:59 118-74-102/18/16 11:0010.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 02/23/16 18:59 77-47-402/18/16 11:0010.0 1.8 1
Hexachloroethane ND ug/L 02/23/16 18:59 67-72-102/18/16 11:0010.0 1.5 1
Hexachloropropene ND ug/L 02/23/16 18:59 1888-71-702/18/16 11:0010.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 02/23/16 18:59 193-39-502/18/16 11:0010.0 0.29 1
Isodrin ND ug/L 02/23/16 18:59 465-73-602/18/16 11:0020.0 2.0 1
Isophorone ND ug/L 02/23/16 18:59 78-59-102/18/16 11:0010.0 1.8 1
Isosafrole ND ug/L 02/23/16 18:59 120-58-102/18/16 11:0010.0 1.8 1
Kepone ND ug/L 02/23/16 18:59 143-50-0 L202/18/16 11:0020.0 3.1 1
Methapyrilene ND ug/L 02/23/16 18:59 91-80-502/18/16 11:00100 2.7 1
3-Methylcholanthrene ND ug/L 02/23/16 18:59 56-49-502/18/16 11:0010.0 0.82 1
Methyl methanesulfonate ND ug/L 02/23/16 18:59 66-27-302/18/16 11:0010.0 1.3 1
2-Methylnaphthalene ND ug/L 02/23/16 18:59 91-57-602/18/16 11:0010.0 0.28 1
Methyl parathion ND ug/L 02/23/16 18:59 298-00-002/18/16 11:0010.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 02/23/16 18:59 95-48-702/18/16 11:0010.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 02/23/16 18:5902/18/16 11:0010.0 1.7 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW1R Lab ID: 92286780001 Collected: 02/16/16 17:45 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
1-Naphthalenamine ND ug/L 02/23/16 18:59 134-32-702/18/16 11:0010.0 0.96 1
2-Naphthalenamine ND ug/L 02/23/16 18:59 91-59-802/18/16 11:0010.0 0.98 1
1,4-Naphthoquinone ND ug/L 02/23/16 18:59 130-15-402/18/16 11:0010.0 1.8 1
2-Nitroaniline ND ug/L 02/23/16 18:59 88-74-402/18/16 11:0050.0 2.8 1
3-Nitroaniline ND ug/L 02/23/16 18:59 99-09-202/18/16 11:0050.0 2.4 1
4-Nitroaniline ND ug/L 02/23/16 18:59 100-01-602/18/16 11:0020.0 2.5 1
Nitrobenzene ND ug/L 02/23/16 18:59 98-95-302/18/16 11:0010.0 1.7 1
2-Nitrophenol ND ug/L 02/23/16 18:59 88-75-502/18/16 11:0010.0 1.7 1
4-Nitrophenol ND ug/L 02/23/16 18:59 100-02-702/18/16 11:0050.0 5.8 1
5-Nitro-o-toluidine ND ug/L 02/23/16 18:59 99-55-802/18/16 11:0010.0 1.2 1
N-Nitrosodiethylamine ND ug/L 02/23/16 18:59 55-18-502/18/16 11:0020.0 1.8 1
N-Nitrosodimethylamine ND ug/L 02/23/16 18:59 62-75-902/18/16 11:0010.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 02/23/16 18:59 924-16-302/18/16 11:0010.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 02/23/16 18:59 621-64-702/18/16 11:0010.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 02/23/16 18:59 86-30-602/18/16 11:0010.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 02/23/16 18:59 10595-95-602/18/16 11:0010.0 1.8 1
N-Nitrosopiperidine ND ug/L 02/23/16 18:59 100-75-402/18/16 11:0020.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 02/23/16 18:59 930-55-202/18/16 11:0010.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 02/23/16 18:59 126-68-102/18/16 11:0010.0 1.8 1
Parathion (Ethyl parathion)ND ug/L 02/23/16 18:59 56-38-202/18/16 11:0010.0 1.1 1
Pentachlorobenzene ND ug/L 02/23/16 18:59 608-93-502/18/16 11:0010.0 2.0 1
Pentachloronitrobenzene ND ug/L 02/23/16 18:59 82-68-802/18/16 11:0020.0 1.0 1
Pentachlorophenol ND ug/L 02/23/16 18:59 87-86-502/18/16 11:0025.0 2.3 1
Phenacetin ND ug/L 02/23/16 18:59 62-44-202/18/16 11:0020.0 0.97 1
Phenanthrene ND ug/L 02/23/16 18:59 85-01-802/18/16 11:0010.0 0.22 1
Phenol ND ug/L 02/23/16 18:59 108-95-202/18/16 11:0010.0 1.7 1
p-Phenylenediamine ND ug/L 02/23/16 18:59 106-50-302/18/16 11:0010.0 0.96 1
Phorate ND ug/L 02/23/16 18:59 298-02-202/18/16 11:0010.0 1.1 1
Pronamide ND ug/L 02/23/16 18:59 23950-58-502/18/16 11:0010.0 0.97 1
Pyrene ND ug/L 02/23/16 18:59 129-00-002/18/16 11:0010.0 0.19 1
Safrole ND ug/L 02/23/16 18:59 94-59-702/18/16 11:0010.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 02/23/16 18:59 95-94-302/18/16 11:0010.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 02/23/16 18:59 58-90-202/18/16 11:0010.0 2.3 1
Thionazin ND ug/L 02/23/16 18:59 297-97-202/18/16 11:0020.0 1.2 1
O-Toluidine ND ug/L 02/23/16 18:59 95-53-402/18/16 11:0010.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 02/23/16 18:59 95-95-402/18/16 11:0010.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 02/23/16 18:59 88-06-202/18/16 11:0010.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 02/23/16 18:59 99-35-402/18/16 11:0010.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)54 %02/23/16 18:59 4165-60-002/18/16 11:0021-110 1
2-Fluorobiphenyl (S)68 %02/23/16 18:59 321-60-802/18/16 11:0027-110 1
Terphenyl-d14 (S)75 %02/23/16 18:59 1718-51-002/18/16 11:0031-107 1
Phenol-d6 (S)21 %02/23/16 18:59 13127-88-302/18/16 11:0010-110 1
2-Fluorophenol (S)33 %02/23/16 18:59 367-12-402/18/16 11:0012-110 1
2,4,6-Tribromophenol (S)79 %02/23/16 18:59 118-79-602/18/16 11:0027-110 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW1R Lab ID: 92286780001 Collected: 02/16/16 17:45 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/18/16 19:24 67-64-1100 10.0 1
Acetonitrile ND ug/L 02/18/16 19:24 75-05-855.0 2.2 1
Acrolein ND ug/L 02/18/16 19:24 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 02/18/16 19:24 107-13-1200 1.9 1
Allyl chloride ND ug/L 02/18/16 19:24 107-05-110.0 1.5 1
Benzene ND ug/L 02/18/16 19:24 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/18/16 19:24 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/18/16 19:24 75-27-41.0 0.18 1
Bromoform ND ug/L 02/18/16 19:24 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/18/16 19:24 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/18/16 19:24 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/18/16 19:24 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/18/16 19:24 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/18/16 19:24 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/18/16 19:24 75-00-310.0 0.54 1
Chloroform ND ug/L 02/18/16 19:24 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/18/16 19:24 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/18/16 19:24 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/18/16 19:24 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/18/16 19:24 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/18/16 19:24 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/18/16 19:24 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/18/16 19:24 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 02/18/16 19:24 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 02/18/16 19:24 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/18/16 19:24 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 02/18/16 19:24 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/18/16 19:24 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/18/16 19:24 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/18/16 19:24 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/18/16 19:24 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/18/16 19:24 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/18/16 19:24 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/18/16 19:24 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/18/16 19:24 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/18/16 19:24 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/18/16 19:24 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/18/16 19:24 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/18/16 19:24 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/18/16 19:24 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 02/18/16 19:24 87-68-310.0 0.71 1
2-Hexanone ND ug/L 02/18/16 19:24 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/18/16 19:24 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/18/16 19:24 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 02/18/16 19:24 126-98-7100 0.93 1
Methylene Chloride ND ug/L 02/18/16 19:24 75-09-21.0 0.97 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW1R Lab ID: 92286780001 Collected: 02/16/16 17:45 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Methyl methacrylate ND ug/L 02/18/16 19:24 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/18/16 19:24 108-10-1100 0.33 1
Naphthalene ND ug/L 02/18/16 19:24 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/18/16 19:24 107-12-0150 3.6 1
Styrene ND ug/L 02/18/16 19:24 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/18/16 19:24 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/18/16 19:24 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/18/16 19:24 127-18-41.0 0.46 1
Toluene ND ug/L 02/18/16 19:24 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/18/16 19:24 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/18/16 19:24 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/18/16 19:24 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/18/16 19:24 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/18/16 19:24 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/18/16 19:24 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/18/16 19:24 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/18/16 19:24 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/18/16 19:24 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %02/18/16 19:24 460-00-470-130 1
1,2-Dichloroethane-d4 (S)107 %02/18/16 19:24 17060-07-070-130 1
Toluene-d8 (S)104 %02/18/16 19:24 2037-26-570-130 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 02/18/16 13:30 18496-25-81000 100 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 02/19/16 17:43 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW2R Lab ID: 92286780002 Collected: 02/16/16 14:55 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 02/20/16 02:24 309-00-202/18/16 09:150.050 0.050 1
alpha-BHC ND ug/L 02/20/16 02:24 319-84-602/18/16 09:150.050 0.050 1
beta-BHC ND ug/L 02/20/16 02:24 319-85-702/18/16 09:150.050 0.050 1
delta-BHC ND ug/L 02/20/16 02:24 319-86-802/18/16 09:150.050 0.050 1
gamma-BHC (Lindane)ND ug/L 02/20/16 02:24 58-89-902/18/16 09:150.050 0.050 1
Chlordane (Technical)ND ug/L 02/20/16 02:24 57-74-902/18/16 09:150.50 0.20 1
4,4'-DDD ND ug/L 02/20/16 02:24 72-54-802/18/16 09:150.10 0.050 1
4,4'-DDE ND ug/L 02/20/16 02:24 72-55-902/18/16 09:150.10 0.050 1
4,4'-DDT ND ug/L 02/20/16 02:24 50-29-302/18/16 09:150.10 0.050 1
Dieldrin ND ug/L 02/20/16 02:24 60-57-102/18/16 09:150.075 0.050 1
Endosulfan I ND ug/L 02/20/16 02:24 959-98-802/18/16 09:150.10 0.050 1
Endosulfan II ND ug/L 02/20/16 02:24 33213-65-902/18/16 09:150.10 0.050 1
Endosulfan sulfate ND ug/L 02/20/16 02:24 1031-07-802/18/16 09:150.10 0.050 1
Endrin ND ug/L 02/20/16 02:24 72-20-802/18/16 09:150.10 0.050 1
Endrin aldehyde ND ug/L 02/20/16 02:24 7421-93-402/18/16 09:150.10 0.050 1
Heptachlor ND ug/L 02/20/16 02:24 76-44-802/18/16 09:150.050 0.050 1
Heptachlor epoxide ND ug/L 02/20/16 02:24 1024-57-302/18/16 09:150.075 0.050 1
Methoxychlor ND ug/L 02/20/16 02:24 72-43-502/18/16 09:151.0 0.15 1
Toxaphene ND ug/L 02/20/16 02:24 8001-35-202/18/16 09:151.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)56 %02/20/16 02:24 877-09-802/18/16 09:1520-130 1
Decachlorobiphenyl (S)60 %02/20/16 02:24 2051-24-302/18/16 09:1520-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 02/19/16 01:09 12674-11-202/17/16 14:000.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 02/19/16 01:09 11104-28-202/17/16 14:000.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 02/19/16 01:09 11141-16-502/17/16 14:000.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 02/19/16 01:09 53469-21-902/17/16 14:000.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 02/19/16 01:09 12672-29-602/17/16 14:000.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 02/19/16 01:09 11097-69-102/17/16 14:000.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 02/19/16 01:09 11096-82-502/17/16 14:000.50 0.50 1
Surrogates
Decachlorobiphenyl (S)50 %02/19/16 01:09 2051-24-302/17/16 14:0010-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
Bentazon ND ug/L 02/23/16 01:34 25057-89-002/22/16 08:200.097 0.016 1
2,4-D ND ug/L 02/23/16 01:34 94-75-702/22/16 08:200.96 0.23 1
Dalapon ND ug/L 02/23/16 01:34 75-99-002/22/16 08:200.93 0.44 1
2,4-DB ND ug/L 02/23/16 01:34 94-82-602/22/16 08:201.9 0.52 1
Dicamba ND ug/L 02/23/16 01:34 1918-00-902/22/16 08:200.096 0.031 1
Dichlorprop ND ug/L 02/23/16 01:34 120-36-502/22/16 08:200.67 0.20 1
Dinoseb ND ug/L 02/23/16 01:34 88-85-702/22/16 08:200.19 0.058 1
Pentachlorophenol ND ug/L 02/23/16 01:34 87-86-502/22/16 08:200.029 0.017 1
Picloram ND ug/L 02/23/16 01:34 1918-02-102/22/16 08:200.097 0.019 1
2,4,5-T ND ug/L 02/23/16 01:34 93-76-502/22/16 08:200.19 0.043 1
2,4,5-TP (Silvex)ND ug/L 02/23/16 01:34 93-72-102/22/16 08:200.19 0.050 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW2R Lab ID: 92286780002 Collected: 02/16/16 14:55 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
Surrogates
2,4-DCAA (S)94 %02/23/16 01:34 19719-28-902/22/16 08:2036-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony 9.9 ug/L 02/19/16 23:27 7440-36-002/18/16 18:306.0 3.8 1
Arsenic ND ug/L 02/19/16 23:27 7440-38-202/18/16 18:3010.0 2.5 1
Barium 123 ug/L 02/23/16 17:39 7440-39-302/18/16 18:30100 2.5 1
Beryllium ND ug/L 02/23/16 17:39 7440-41-702/18/16 18:301.0 0.50 1
Cadmium ND ug/L 02/19/16 23:27 7440-43-902/18/16 18:301.0 0.50 1
Chromium ND ug/L 02/19/16 23:27 7440-47-302/18/16 18:3010.0 2.5 1
Cobalt 10.0 ug/L 02/19/16 23:27 7440-48-402/18/16 18:3010.0 2.5 1
Copper ND ug/L 02/19/16 23:27 7440-50-802/18/16 18:3010.0 2.5 1
Lead ND ug/L 02/19/16 23:27 7439-92-102/18/16 18:3010.0 2.5 1
Nickel 92.0 ug/L 02/23/16 17:39 7440-02-002/18/16 18:3050.0 2.5 1
Selenium ND ug/L 02/19/16 23:27 7782-49-202/18/16 18:3010.0 5.0 1
Silver ND ug/L 02/19/16 23:27 7440-22-402/18/16 18:3010.0 2.5 1
Thallium ND ug/L 02/19/16 23:27 7440-28-002/18/16 18:305.5 5.0 1
Tin 28.6J ug/L 02/19/16 23:27 7440-31-502/18/16 18:30100 2.5 1
Vanadium 3.3J ug/L 02/23/16 17:39 7440-62-202/18/16 18:3025.0 2.5 1
Zinc 16.7 ug/L 02/19/16 23:27 7440-66-602/18/16 18:3010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 02/24/16 15:00 7439-97-602/22/16 16:200.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 02/23/16 19:30 83-32-902/18/16 11:0010.0 0.25 1
Acenaphthylene ND ug/L 02/23/16 19:30 208-96-802/18/16 11:0010.0 0.21 1
Acetophenone ND ug/L 02/23/16 19:30 98-86-202/18/16 11:0010.0 2.0 1
2-Acetylaminofluorene ND ug/L 02/23/16 19:30 53-96-302/18/16 11:0020.0 0.84 1
4-Aminobiphenyl ND ug/L 02/23/16 19:30 92-67-102/18/16 11:0020.0 0.92 1
Anthracene ND ug/L 02/23/16 19:30 120-12-702/18/16 11:0010.0 0.14 1
Benzo(a)anthracene ND ug/L 02/23/16 19:30 56-55-302/18/16 11:0010.0 0.33 1
Benzo(a)pyrene ND ug/L 02/23/16 19:30 50-32-802/18/16 11:0010.0 0.30 1
Benzo(b)fluoranthene ND ug/L 02/23/16 19:30 205-99-202/18/16 11:0010.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 02/23/16 19:30 191-24-202/18/16 11:0010.0 0.38 1
Benzo(k)fluoranthene ND ug/L 02/23/16 19:30 207-08-902/18/16 11:0010.0 0.43 1
Benzyl alcohol ND ug/L 02/23/16 19:30 100-51-602/18/16 11:0020.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 02/23/16 19:30 101-55-302/18/16 11:0010.0 1.3 1
Butylbenzylphthalate ND ug/L 02/23/16 19:30 85-68-702/18/16 11:0010.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 02/23/16 19:30 59-50-702/18/16 11:0020.0 4.2 1
4-Chloroaniline ND ug/L 02/23/16 19:30 106-47-802/18/16 11:0020.0 3.4 1
Chlorobenzilate ND ug/L 02/23/16 19:30 510-15-602/18/16 11:0010.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 02/23/16 19:30 111-91-102/18/16 11:0010.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 02/23/16 19:30 111-44-402/18/16 11:0010.0 1.5 1
bis(2-Chloroisopropyl) ether ND ug/L 02/23/16 19:30 108-60-102/18/16 11:0010.0 1.6 1
2-Chloronaphthalene ND ug/L 02/23/16 19:30 91-58-702/18/16 11:0010.0 2.2 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW2R Lab ID: 92286780002 Collected: 02/16/16 14:55 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
2-Chlorophenol ND ug/L 02/23/16 19:30 95-57-802/18/16 11:0010.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 02/23/16 19:30 7005-72-302/18/16 11:0010.0 2.1 1
Chrysene ND ug/L 02/23/16 19:30 218-01-902/18/16 11:0010.0 0.21 1
Diallate ND ug/L 02/23/16 19:30 2303-16-402/18/16 11:0010.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 02/23/16 19:30 53-70-302/18/16 11:0010.0 0.55 1
Dibenzofuran ND ug/L 02/23/16 19:30 132-64-902/18/16 11:0010.0 1.8 1
3,3'-Dichlorobenzidine ND ug/L 02/23/16 19:30 91-94-102/18/16 11:0020.0 1.4 1
2,4-Dichlorophenol ND ug/L 02/23/16 19:30 120-83-202/18/16 11:0010.0 1.7 1
2,6-Dichlorophenol ND ug/L 02/23/16 19:30 87-65-002/18/16 11:0010.0 1.8 1
Diethylphthalate ND ug/L 02/23/16 19:30 84-66-202/18/16 11:006000 1.3 1
Dimethoate ND ug/L 02/23/16 19:30 60-51-502/18/16 11:0020.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 02/23/16 19:30 60-11-702/18/16 11:0010.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 02/23/16 19:30 57-97-602/18/16 11:0010.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 02/23/16 19:30 119-93-702/18/16 11:0010.0 2.1 1
2,4-Dimethylphenol ND ug/L 02/23/16 19:30 105-67-902/18/16 11:0010.0 2.2 1
Dimethylphthalate ND ug/L 02/23/16 19:30 131-11-302/18/16 11:0010.0 1.5 1
Di-n-butylphthalate ND ug/L 02/23/16 19:30 84-74-202/18/16 11:0010.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 02/23/16 19:30 534-52-102/18/16 11:0050.0 1.7 1
1,3-Dinitrobenzene ND ug/L 02/23/16 19:30 99-65-002/18/16 11:0020.0 1.5 1
2,4-Dinitrophenol ND ug/L 02/23/16 19:30 51-28-502/18/16 11:0050.0 6.5 1
2,4-Dinitrotoluene ND ug/L 02/23/16 19:30 121-14-202/18/16 11:0010.0 1.2 1
2,6-Dinitrotoluene ND ug/L 02/23/16 19:30 606-20-202/18/16 11:0010.0 1.7 1
Di-n-octylphthalate ND ug/L 02/23/16 19:30 117-84-002/18/16 11:0010.0 0.86 1
Diphenylamine ND ug/L 02/23/16 19:30 122-39-402/18/16 11:0010.0 1.3 1
Disulfoton ND ug/L 02/23/16 19:30 298-04-402/18/16 11:0010.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 02/23/16 19:30 117-81-702/18/16 11:0015.0 0.85 1
Ethyl methanesulfonate ND ug/L 02/23/16 19:30 62-50-002/18/16 11:0020.0 1.8 1
Famphur ND ug/L 02/23/16 19:30 52-85-702/18/16 11:0020.0 1.7 1
Fluoranthene ND ug/L 02/23/16 19:30 206-44-002/18/16 11:0010.0 0.21 1
Fluorene ND ug/L 02/23/16 19:30 86-73-702/18/16 11:0010.0 0.21 1
Hexachlorobenzene ND ug/L 02/23/16 19:30 118-74-102/18/16 11:0010.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 02/23/16 19:30 77-47-402/18/16 11:0010.0 1.8 1
Hexachloroethane ND ug/L 02/23/16 19:30 67-72-102/18/16 11:0010.0 1.5 1
Hexachloropropene ND ug/L 02/23/16 19:30 1888-71-702/18/16 11:0010.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 02/23/16 19:30 193-39-502/18/16 11:0010.0 0.29 1
Isodrin ND ug/L 02/23/16 19:30 465-73-602/18/16 11:0020.0 2.0 1
Isophorone ND ug/L 02/23/16 19:30 78-59-102/18/16 11:0010.0 1.8 1
Isosafrole ND ug/L 02/23/16 19:30 120-58-102/18/16 11:0010.0 1.8 1
Kepone ND ug/L 02/23/16 19:30 143-50-0 L202/18/16 11:0020.0 3.1 1
Methapyrilene ND ug/L 02/23/16 19:30 91-80-502/18/16 11:00100 2.7 1
3-Methylcholanthrene ND ug/L 02/23/16 19:30 56-49-502/18/16 11:0010.0 0.82 1
Methyl methanesulfonate ND ug/L 02/23/16 19:30 66-27-302/18/16 11:0010.0 1.3 1
2-Methylnaphthalene ND ug/L 02/23/16 19:30 91-57-602/18/16 11:0010.0 0.28 1
Methyl parathion ND ug/L 02/23/16 19:30 298-00-002/18/16 11:0010.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 02/23/16 19:30 95-48-702/18/16 11:0010.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 02/23/16 19:3002/18/16 11:0010.0 1.7 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW2R Lab ID: 92286780002 Collected: 02/16/16 14:55 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
1-Naphthalenamine ND ug/L 02/23/16 19:30 134-32-702/18/16 11:0010.0 0.96 1
2-Naphthalenamine ND ug/L 02/23/16 19:30 91-59-802/18/16 11:0010.0 0.98 1
1,4-Naphthoquinone ND ug/L 02/23/16 19:30 130-15-402/18/16 11:0010.0 1.8 1
2-Nitroaniline ND ug/L 02/23/16 19:30 88-74-402/18/16 11:0050.0 2.8 1
3-Nitroaniline ND ug/L 02/23/16 19:30 99-09-202/18/16 11:0050.0 2.4 1
4-Nitroaniline ND ug/L 02/23/16 19:30 100-01-602/18/16 11:0020.0 2.5 1
Nitrobenzene ND ug/L 02/23/16 19:30 98-95-302/18/16 11:0010.0 1.7 1
2-Nitrophenol ND ug/L 02/23/16 19:30 88-75-502/18/16 11:0010.0 1.7 1
4-Nitrophenol ND ug/L 02/23/16 19:30 100-02-702/18/16 11:0050.0 5.8 1
5-Nitro-o-toluidine ND ug/L 02/23/16 19:30 99-55-802/18/16 11:0010.0 1.2 1
N-Nitrosodiethylamine ND ug/L 02/23/16 19:30 55-18-502/18/16 11:0020.0 1.8 1
N-Nitrosodimethylamine ND ug/L 02/23/16 19:30 62-75-902/18/16 11:0010.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 02/23/16 19:30 924-16-302/18/16 11:0010.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 02/23/16 19:30 621-64-702/18/16 11:0010.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 02/23/16 19:30 86-30-602/18/16 11:0010.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 02/23/16 19:30 10595-95-602/18/16 11:0010.0 1.8 1
N-Nitrosopiperidine ND ug/L 02/23/16 19:30 100-75-402/18/16 11:0020.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 02/23/16 19:30 930-55-202/18/16 11:0010.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 02/23/16 19:30 126-68-102/18/16 11:0010.0 1.8 1
Parathion (Ethyl parathion)ND ug/L 02/23/16 19:30 56-38-202/18/16 11:0010.0 1.1 1
Pentachlorobenzene ND ug/L 02/23/16 19:30 608-93-502/18/16 11:0010.0 2.0 1
Pentachloronitrobenzene ND ug/L 02/23/16 19:30 82-68-802/18/16 11:0020.0 1.0 1
Pentachlorophenol ND ug/L 02/23/16 19:30 87-86-502/18/16 11:0025.0 2.3 1
Phenacetin ND ug/L 02/23/16 19:30 62-44-202/18/16 11:0020.0 0.97 1
Phenanthrene ND ug/L 02/23/16 19:30 85-01-802/18/16 11:0010.0 0.22 1
Phenol ND ug/L 02/23/16 19:30 108-95-202/18/16 11:0010.0 1.7 1
p-Phenylenediamine ND ug/L 02/23/16 19:30 106-50-302/18/16 11:0010.0 0.96 1
Phorate ND ug/L 02/23/16 19:30 298-02-202/18/16 11:0010.0 1.1 1
Pronamide ND ug/L 02/23/16 19:30 23950-58-502/18/16 11:0010.0 0.97 1
Pyrene ND ug/L 02/23/16 19:30 129-00-002/18/16 11:0010.0 0.19 1
Safrole ND ug/L 02/23/16 19:30 94-59-702/18/16 11:0010.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 02/23/16 19:30 95-94-302/18/16 11:0010.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 02/23/16 19:30 58-90-202/18/16 11:0010.0 2.3 1
Thionazin ND ug/L 02/23/16 19:30 297-97-202/18/16 11:0020.0 1.2 1
O-Toluidine ND ug/L 02/23/16 19:30 95-53-402/18/16 11:0010.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 02/23/16 19:30 95-95-402/18/16 11:0010.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 02/23/16 19:30 88-06-202/18/16 11:0010.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 02/23/16 19:30 99-35-402/18/16 11:0010.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)49 %02/23/16 19:30 4165-60-002/18/16 11:0021-110 1
2-Fluorobiphenyl (S)61 %02/23/16 19:30 321-60-802/18/16 11:0027-110 1
Terphenyl-d14 (S)58 %02/23/16 19:30 1718-51-002/18/16 11:0031-107 1
Phenol-d6 (S)30 %02/23/16 19:30 13127-88-302/18/16 11:0010-110 1
2-Fluorophenol (S)35 %02/23/16 19:30 367-12-402/18/16 11:0012-110 1
2,4,6-Tribromophenol (S)94 %02/23/16 19:30 118-79-602/18/16 11:0027-110 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
Page 17 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW2R Lab ID: 92286780002 Collected: 02/16/16 14:55 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/18/16 19:41 67-64-1100 10.0 1
Acetonitrile ND ug/L 02/18/16 19:41 75-05-855.0 2.2 1
Acrolein ND ug/L 02/18/16 19:41 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 02/18/16 19:41 107-13-1200 1.9 1
Allyl chloride ND ug/L 02/18/16 19:41 107-05-110.0 1.5 1
Benzene 1.3 ug/L 02/18/16 19:41 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/18/16 19:41 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/18/16 19:41 75-27-41.0 0.18 1
Bromoform ND ug/L 02/18/16 19:41 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/18/16 19:41 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/18/16 19:41 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/18/16 19:41 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/18/16 19:41 56-23-51.0 0.25 1
Chlorobenzene 13.5 ug/L 02/18/16 19:41 108-90-73.0 0.23 1
Chloroethane 1.1J ug/L 02/18/16 19:41 75-00-310.0 0.54 1
Chloroform ND ug/L 02/18/16 19:41 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/18/16 19:41 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/18/16 19:41 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/18/16 19:41 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/18/16 19:41 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/18/16 19:41 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/18/16 19:41 74-95-310.0 0.21 1
1,2-Dichlorobenzene 1.1J ug/L 02/18/16 19:41 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 02/18/16 19:41 541-73-15.0 0.24 1
1,4-Dichlorobenzene 2.0 ug/L 02/18/16 19:41 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/18/16 19:41 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 02/18/16 19:41 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/18/16 19:41 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/18/16 19:41 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/18/16 19:41 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/18/16 19:41 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/18/16 19:41 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/18/16 19:41 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/18/16 19:41 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/18/16 19:41 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/18/16 19:41 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/18/16 19:41 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/18/16 19:41 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/18/16 19:41 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/18/16 19:41 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 02/18/16 19:41 87-68-310.0 0.71 1
2-Hexanone ND ug/L 02/18/16 19:41 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/18/16 19:41 74-88-410.0 0.32 1
Isobutanol 42.5J ug/L 02/18/16 19:41 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 02/18/16 19:41 126-98-7100 0.93 1
Methylene Chloride ND ug/L 02/18/16 19:41 75-09-21.0 0.97 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 18 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW2R Lab ID: 92286780002 Collected: 02/16/16 14:55 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Methyl methacrylate ND ug/L 02/18/16 19:41 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/18/16 19:41 108-10-1100 0.33 1
Naphthalene 5.7J ug/L 02/18/16 19:41 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/18/16 19:41 107-12-0150 3.6 1
Styrene ND ug/L 02/18/16 19:41 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/18/16 19:41 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/18/16 19:41 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/18/16 19:41 127-18-41.0 0.46 1
Toluene ND ug/L 02/18/16 19:41 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/18/16 19:41 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/18/16 19:41 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/18/16 19:41 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/18/16 19:41 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/18/16 19:41 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/18/16 19:41 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/18/16 19:41 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/18/16 19:41 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/18/16 19:41 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %02/18/16 19:41 460-00-470-130 1
1,2-Dichloroethane-d4 (S)107 %02/18/16 19:41 17060-07-070-130 1
Toluene-d8 (S)104 %02/18/16 19:41 2037-26-570-130 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 02/18/16 13:30 18496-25-81000 100 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 02/19/16 17:46 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW3R Lab ID: 92286780003 Collected: 02/16/16 15:15 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 02/20/16 02:42 309-00-202/18/16 09:150.050 0.050 1
alpha-BHC ND ug/L 02/20/16 02:42 319-84-602/18/16 09:150.050 0.050 1
beta-BHC ND ug/L 02/20/16 02:42 319-85-702/18/16 09:150.050 0.050 1
delta-BHC ND ug/L 02/20/16 02:42 319-86-802/18/16 09:150.050 0.050 1
gamma-BHC (Lindane)ND ug/L 02/20/16 02:42 58-89-902/18/16 09:150.050 0.050 1
Chlordane (Technical)ND ug/L 02/20/16 02:42 57-74-902/18/16 09:150.50 0.20 1
4,4'-DDD ND ug/L 02/20/16 02:42 72-54-802/18/16 09:150.10 0.050 1
4,4'-DDE ND ug/L 02/20/16 02:42 72-55-902/18/16 09:150.10 0.050 1
4,4'-DDT ND ug/L 02/20/16 02:42 50-29-302/18/16 09:150.10 0.050 1
Dieldrin ND ug/L 02/20/16 02:42 60-57-102/18/16 09:150.075 0.050 1
Endosulfan I ND ug/L 02/20/16 02:42 959-98-802/18/16 09:150.10 0.050 1
Endosulfan II ND ug/L 02/20/16 02:42 33213-65-902/18/16 09:150.10 0.050 1
Endosulfan sulfate ND ug/L 02/20/16 02:42 1031-07-8 M102/18/16 09:150.10 0.050 1
Endrin ND ug/L 02/20/16 02:42 72-20-802/18/16 09:150.10 0.050 1
Endrin aldehyde ND ug/L 02/20/16 02:42 7421-93-402/18/16 09:150.10 0.050 1
Heptachlor ND ug/L 02/20/16 02:42 76-44-802/18/16 09:150.050 0.050 1
Heptachlor epoxide ND ug/L 02/20/16 02:42 1024-57-302/18/16 09:150.075 0.050 1
Methoxychlor ND ug/L 02/20/16 02:42 72-43-502/18/16 09:151.0 0.15 1
Toxaphene ND ug/L 02/20/16 02:42 8001-35-202/18/16 09:151.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)62 %02/20/16 02:42 877-09-802/18/16 09:1520-130 1
Decachlorobiphenyl (S)64 %02/20/16 02:42 2051-24-302/18/16 09:1520-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 02/19/16 01:30 12674-11-202/17/16 14:000.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 02/19/16 01:30 11104-28-202/17/16 14:000.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 02/19/16 01:30 11141-16-502/17/16 14:000.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 02/19/16 01:30 53469-21-902/17/16 14:000.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 02/19/16 01:30 12672-29-602/17/16 14:000.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 02/19/16 01:30 11097-69-102/17/16 14:000.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 02/19/16 01:30 11096-82-502/17/16 14:000.50 0.50 1
Surrogates
Decachlorobiphenyl (S)77 %02/19/16 01:30 2051-24-302/17/16 14:0010-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
Bentazon ND ug/L 02/23/16 02:04 25057-89-002/22/16 08:200.097 0.016 1
2,4-D ND ug/L 02/23/16 02:04 94-75-702/22/16 08:200.97 0.23 1
Dalapon ND ug/L 02/23/16 02:04 75-99-002/22/16 08:200.94 0.44 1
2,4-DB ND ug/L 02/23/16 02:04 94-82-602/22/16 08:202.0 0.52 1
Dicamba ND ug/L 02/23/16 02:04 1918-00-902/22/16 08:200.097 0.031 1
Dichlorprop ND ug/L 02/23/16 02:04 120-36-502/22/16 08:200.67 0.20 1
Dinoseb ND ug/L 02/23/16 02:04 88-85-702/22/16 08:200.19 0.059 1
Pentachlorophenol ND ug/L 02/23/16 02:04 87-86-502/22/16 08:200.029 0.018 1
Picloram ND ug/L 02/23/16 02:04 1918-02-102/22/16 08:200.097 0.020 1
2,4,5-T ND ug/L 02/23/16 02:04 93-76-502/22/16 08:200.20 0.043 1
2,4,5-TP (Silvex)ND ug/L 02/23/16 02:04 93-72-102/22/16 08:200.20 0.050 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW3R Lab ID: 92286780003 Collected: 02/16/16 15:15 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
Surrogates
2,4-DCAA (S)82 %02/23/16 02:04 19719-28-902/22/16 08:2036-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony 6.5 ug/L 02/19/16 23:30 7440-36-002/18/16 18:306.0 3.8 1
Arsenic ND ug/L 02/19/16 23:30 7440-38-202/18/16 18:3010.0 2.5 1
Barium 72.7J ug/L 02/23/16 17:54 7440-39-302/18/16 18:30100 2.5 1
Beryllium ND ug/L 02/23/16 17:54 7440-41-702/18/16 18:301.0 0.50 1
Cadmium ND ug/L 02/19/16 23:30 7440-43-902/18/16 18:301.0 0.50 1
Chromium ND ug/L 02/19/16 23:30 7440-47-302/18/16 18:3010.0 2.5 1
Cobalt ND ug/L 02/19/16 23:30 7440-48-402/18/16 18:3010.0 2.5 1
Copper 7.8J ug/L 02/19/16 23:30 7440-50-802/18/16 18:3010.0 2.5 1
Lead ND ug/L 02/19/16 23:30 7439-92-102/18/16 18:3010.0 2.5 1
Nickel 35.4J ug/L 02/23/16 17:54 7440-02-002/18/16 18:3050.0 2.5 1
Selenium ND ug/L 02/19/16 23:30 7782-49-202/18/16 18:3010.0 5.0 1
Silver ND ug/L 02/19/16 23:30 7440-22-402/18/16 18:3010.0 2.5 1
Thallium ND ug/L 02/19/16 23:30 7440-28-002/18/16 18:305.5 5.0 1
Tin 10.4J ug/L 02/19/16 23:30 7440-31-502/18/16 18:30100 2.5 1
Vanadium ND ug/L 02/23/16 17:54 7440-62-202/18/16 18:3025.0 2.5 1
Zinc 17.8 ug/L 02/19/16 23:30 7440-66-602/18/16 18:3010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 02/24/16 15:02 7439-97-602/22/16 16:200.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 02/24/16 10:58 83-32-902/18/16 11:0010.0 0.25 1
Acenaphthylene ND ug/L 02/24/16 10:58 208-96-802/18/16 11:0010.0 0.21 1
Acetophenone ND ug/L 02/24/16 10:58 98-86-202/18/16 11:0010.0 2.0 1
2-Acetylaminofluorene ND ug/L 02/24/16 10:58 53-96-302/18/16 11:0020.0 0.84 1
4-Aminobiphenyl ND ug/L 02/24/16 10:58 92-67-102/18/16 11:0020.0 0.92 1
Anthracene ND ug/L 02/24/16 10:58 120-12-702/18/16 11:0010.0 0.14 1
Benzo(a)anthracene ND ug/L 02/24/16 10:58 56-55-302/18/16 11:0010.0 0.33 1
Benzo(a)pyrene ND ug/L 02/24/16 10:58 50-32-802/18/16 11:0010.0 0.30 1
Benzo(b)fluoranthene ND ug/L 02/24/16 10:58 205-99-202/18/16 11:0010.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 02/24/16 10:58 191-24-202/18/16 11:0010.0 0.38 1
Benzo(k)fluoranthene ND ug/L 02/24/16 10:58 207-08-902/18/16 11:0010.0 0.43 1
Benzyl alcohol ND ug/L 02/24/16 10:58 100-51-602/18/16 11:0020.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 02/24/16 10:58 101-55-302/18/16 11:0010.0 1.3 1
Butylbenzylphthalate ND ug/L 02/24/16 10:58 85-68-702/18/16 11:0010.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 02/24/16 10:58 59-50-702/18/16 11:0020.0 4.2 1
4-Chloroaniline ND ug/L 02/24/16 10:58 106-47-802/18/16 11:0020.0 3.4 1
Chlorobenzilate ND ug/L 02/24/16 10:58 510-15-602/18/16 11:0010.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 02/24/16 10:58 111-91-102/18/16 11:0010.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 02/24/16 10:58 111-44-402/18/16 11:0010.0 1.5 1
bis(2-Chloroisopropyl) ether ND ug/L 02/24/16 10:58 108-60-102/18/16 11:0010.0 1.6 1
2-Chloronaphthalene ND ug/L 02/24/16 10:58 91-58-702/18/16 11:0010.0 2.2 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW3R Lab ID: 92286780003 Collected: 02/16/16 15:15 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
2-Chlorophenol ND ug/L 02/24/16 10:58 95-57-802/18/16 11:0010.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 02/24/16 10:58 7005-72-302/18/16 11:0010.0 2.1 1
Chrysene ND ug/L 02/24/16 10:58 218-01-902/18/16 11:0010.0 0.21 1
Diallate ND ug/L 02/24/16 10:58 2303-16-402/18/16 11:0010.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 02/24/16 10:58 53-70-302/18/16 11:0010.0 0.55 1
Dibenzofuran ND ug/L 02/24/16 10:58 132-64-902/18/16 11:0010.0 1.8 1
3,3'-Dichlorobenzidine ND ug/L 02/24/16 10:58 91-94-102/18/16 11:0020.0 1.4 1
2,4-Dichlorophenol ND ug/L 02/24/16 10:58 120-83-202/18/16 11:0010.0 1.7 1
2,6-Dichlorophenol ND ug/L 02/24/16 10:58 87-65-002/18/16 11:0010.0 1.8 1
Diethylphthalate ND ug/L 02/24/16 10:58 84-66-202/18/16 11:006000 1.3 1
Dimethoate ND ug/L 02/24/16 10:58 60-51-502/18/16 11:0020.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 02/24/16 10:58 60-11-702/18/16 11:0010.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 02/24/16 10:58 57-97-602/18/16 11:0010.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 02/24/16 10:58 119-93-702/18/16 11:0010.0 2.1 1
2,4-Dimethylphenol ND ug/L 02/24/16 10:58 105-67-902/18/16 11:0010.0 2.2 1
Dimethylphthalate ND ug/L 02/24/16 10:58 131-11-302/18/16 11:0010.0 1.5 1
Di-n-butylphthalate ND ug/L 02/24/16 10:58 84-74-202/18/16 11:0010.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 02/24/16 10:58 534-52-102/18/16 11:0050.0 1.7 1
1,3-Dinitrobenzene ND ug/L 02/24/16 10:58 99-65-002/18/16 11:0020.0 1.5 1
2,4-Dinitrophenol ND ug/L 02/24/16 10:58 51-28-502/18/16 11:0050.0 6.5 1
2,4-Dinitrotoluene ND ug/L 02/24/16 10:58 121-14-202/18/16 11:0010.0 1.2 1
2,6-Dinitrotoluene ND ug/L 02/24/16 10:58 606-20-202/18/16 11:0010.0 1.7 1
Di-n-octylphthalate ND ug/L 02/24/16 10:58 117-84-002/18/16 11:0010.0 0.86 1
Diphenylamine ND ug/L 02/24/16 10:58 122-39-402/18/16 11:0010.0 1.3 1
Disulfoton ND ug/L 02/24/16 10:58 298-04-402/18/16 11:0010.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 02/24/16 10:58 117-81-702/18/16 11:0015.0 0.85 1
Ethyl methanesulfonate ND ug/L 02/24/16 10:58 62-50-002/18/16 11:0020.0 1.8 1
Famphur ND ug/L 02/24/16 10:58 52-85-702/18/16 11:0020.0 1.7 1
Fluoranthene ND ug/L 02/24/16 10:58 206-44-002/18/16 11:0010.0 0.21 1
Fluorene ND ug/L 02/24/16 10:58 86-73-702/18/16 11:0010.0 0.21 1
Hexachlorobenzene ND ug/L 02/24/16 10:58 118-74-102/18/16 11:0010.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 02/24/16 10:58 77-47-402/18/16 11:0010.0 1.8 1
Hexachloroethane ND ug/L 02/24/16 10:58 67-72-102/18/16 11:0010.0 1.5 1
Hexachloropropene ND ug/L 02/24/16 10:58 1888-71-702/18/16 11:0010.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 02/24/16 10:58 193-39-502/18/16 11:0010.0 0.29 1
Isodrin ND ug/L 02/24/16 10:58 465-73-602/18/16 11:0020.0 2.0 1
Isophorone ND ug/L 02/24/16 10:58 78-59-102/18/16 11:0010.0 1.8 1
Isosafrole ND ug/L 02/24/16 10:58 120-58-102/18/16 11:0010.0 1.8 1
Kepone ND ug/L 02/24/16 10:58 143-50-0 L202/18/16 11:0020.0 3.1 1
Methapyrilene ND ug/L 02/24/16 10:58 91-80-502/18/16 11:00100 2.7 1
3-Methylcholanthrene ND ug/L 02/24/16 10:58 56-49-502/18/16 11:0010.0 0.82 1
Methyl methanesulfonate ND ug/L 02/24/16 10:58 66-27-302/18/16 11:0010.0 1.3 1
2-Methylnaphthalene ND ug/L 02/24/16 10:58 91-57-602/18/16 11:0010.0 0.28 1
Methyl parathion ND ug/L 02/24/16 10:58 298-00-002/18/16 11:0010.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 02/24/16 10:58 95-48-702/18/16 11:0010.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 02/24/16 10:5802/18/16 11:0010.0 1.7 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
Page 22 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW3R Lab ID: 92286780003 Collected: 02/16/16 15:15 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
1-Naphthalenamine ND ug/L 02/24/16 10:58 134-32-702/18/16 11:0010.0 0.96 1
2-Naphthalenamine ND ug/L 02/24/16 10:58 91-59-802/18/16 11:0010.0 0.98 1
1,4-Naphthoquinone ND ug/L 02/24/16 10:58 130-15-402/18/16 11:0010.0 1.8 1
2-Nitroaniline ND ug/L 02/24/16 10:58 88-74-402/18/16 11:0050.0 2.8 1
3-Nitroaniline ND ug/L 02/24/16 10:58 99-09-202/18/16 11:0050.0 2.4 1
4-Nitroaniline ND ug/L 02/24/16 10:58 100-01-602/18/16 11:0020.0 2.5 1
Nitrobenzene ND ug/L 02/24/16 10:58 98-95-302/18/16 11:0010.0 1.7 1
2-Nitrophenol ND ug/L 02/24/16 10:58 88-75-502/18/16 11:0010.0 1.7 1
4-Nitrophenol ND ug/L 02/24/16 10:58 100-02-702/18/16 11:0050.0 5.8 1
5-Nitro-o-toluidine ND ug/L 02/24/16 10:58 99-55-802/18/16 11:0010.0 1.2 1
N-Nitrosodiethylamine ND ug/L 02/24/16 10:58 55-18-502/18/16 11:0020.0 1.8 1
N-Nitrosodimethylamine ND ug/L 02/24/16 10:58 62-75-902/18/16 11:0010.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 02/24/16 10:58 924-16-302/18/16 11:0010.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 02/24/16 10:58 621-64-702/18/16 11:0010.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 02/24/16 10:58 86-30-602/18/16 11:0010.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 02/24/16 10:58 10595-95-602/18/16 11:0010.0 1.8 1
N-Nitrosopiperidine ND ug/L 02/24/16 10:58 100-75-402/18/16 11:0020.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 02/24/16 10:58 930-55-202/18/16 11:0010.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 02/24/16 10:58 126-68-102/18/16 11:0010.0 1.8 1
Parathion (Ethyl parathion)ND ug/L 02/24/16 10:58 56-38-202/18/16 11:0010.0 1.1 1
Pentachlorobenzene ND ug/L 02/24/16 10:58 608-93-502/18/16 11:0010.0 2.0 1
Pentachloronitrobenzene ND ug/L 02/24/16 10:58 82-68-802/18/16 11:0020.0 1.0 1
Pentachlorophenol ND ug/L 02/24/16 10:58 87-86-502/18/16 11:0025.0 2.3 1
Phenacetin ND ug/L 02/24/16 10:58 62-44-202/18/16 11:0020.0 0.97 1
Phenanthrene ND ug/L 02/24/16 10:58 85-01-802/18/16 11:0010.0 0.22 1
Phenol ND ug/L 02/24/16 10:58 108-95-202/18/16 11:0010.0 1.7 1
p-Phenylenediamine ND ug/L 02/24/16 10:58 106-50-302/18/16 11:0010.0 0.96 1
Phorate ND ug/L 02/24/16 10:58 298-02-202/18/16 11:0010.0 1.1 1
Pronamide ND ug/L 02/24/16 10:58 23950-58-502/18/16 11:0010.0 0.97 1
Pyrene ND ug/L 02/24/16 10:58 129-00-002/18/16 11:0010.0 0.19 1
Safrole ND ug/L 02/24/16 10:58 94-59-702/18/16 11:0010.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 02/24/16 10:58 95-94-302/18/16 11:0010.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 02/24/16 10:58 58-90-202/18/16 11:0010.0 2.3 1
Thionazin ND ug/L 02/24/16 10:58 297-97-202/18/16 11:0020.0 1.2 1
O-Toluidine ND ug/L 02/24/16 10:58 95-53-402/18/16 11:0010.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 02/24/16 10:58 95-95-402/18/16 11:0010.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 02/24/16 10:58 88-06-202/18/16 11:0010.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 02/24/16 10:58 99-35-402/18/16 11:0010.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)52 %02/24/16 10:58 4165-60-002/18/16 11:0021-110 1
2-Fluorobiphenyl (S)64 %02/24/16 10:58 321-60-802/18/16 11:0027-110 1
Terphenyl-d14 (S)60 %02/24/16 10:58 1718-51-002/18/16 11:0031-107 1
Phenol-d6 (S)20 %02/24/16 10:58 13127-88-302/18/16 11:0010-110 1
2-Fluorophenol (S)32 %02/24/16 10:58 367-12-402/18/16 11:0012-110 1
2,4,6-Tribromophenol (S)88 %02/24/16 10:58 118-79-602/18/16 11:0027-110 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW3R Lab ID: 92286780003 Collected: 02/16/16 15:15 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/18/16 19:58 67-64-1100 10.0 1
Acetonitrile ND ug/L 02/18/16 19:58 75-05-855.0 2.2 1
Acrolein ND ug/L 02/18/16 19:58 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 02/18/16 19:58 107-13-1200 1.9 1
Allyl chloride ND ug/L 02/18/16 19:58 107-05-110.0 1.5 1
Benzene 0.56J ug/L 02/18/16 19:58 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/18/16 19:58 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/18/16 19:58 75-27-41.0 0.18 1
Bromoform ND ug/L 02/18/16 19:58 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/18/16 19:58 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/18/16 19:58 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/18/16 19:58 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/18/16 19:58 56-23-51.0 0.25 1
Chlorobenzene 16.4 ug/L 02/18/16 19:58 108-90-73.0 0.23 1
Chloroethane 1.8J ug/L 02/18/16 19:58 75-00-310.0 0.54 1
Chloroform ND ug/L 02/18/16 19:58 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/18/16 19:58 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/18/16 19:58 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/18/16 19:58 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/18/16 19:58 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/18/16 19:58 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/18/16 19:58 74-95-310.0 0.21 1
1,2-Dichlorobenzene 1.4J ug/L 02/18/16 19:58 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 02/18/16 19:58 541-73-15.0 0.24 1
1,4-Dichlorobenzene 1.0 ug/L 02/18/16 19:58 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/18/16 19:58 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 02/18/16 19:58 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/18/16 19:58 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/18/16 19:58 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/18/16 19:58 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/18/16 19:58 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/18/16 19:58 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/18/16 19:58 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/18/16 19:58 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/18/16 19:58 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/18/16 19:58 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/18/16 19:58 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/18/16 19:58 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/18/16 19:58 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/18/16 19:58 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 02/18/16 19:58 87-68-310.0 0.71 1
2-Hexanone ND ug/L 02/18/16 19:58 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/18/16 19:58 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/18/16 19:58 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 02/18/16 19:58 126-98-7100 0.93 1
Methylene Chloride ND ug/L 02/18/16 19:58 75-09-21.0 0.97 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW3R Lab ID: 92286780003 Collected: 02/16/16 15:15 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Methyl methacrylate ND ug/L 02/18/16 19:58 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/18/16 19:58 108-10-1100 0.33 1
Naphthalene ND ug/L 02/18/16 19:58 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/18/16 19:58 107-12-0150 3.6 1
Styrene ND ug/L 02/18/16 19:58 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/18/16 19:58 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/18/16 19:58 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/18/16 19:58 127-18-41.0 0.46 1
Toluene ND ug/L 02/18/16 19:58 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/18/16 19:58 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/18/16 19:58 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/18/16 19:58 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/18/16 19:58 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/18/16 19:58 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/18/16 19:58 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/18/16 19:58 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/18/16 19:58 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/18/16 19:58 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %02/18/16 19:58 460-00-470-130 1
1,2-Dichloroethane-d4 (S)105 %02/18/16 19:58 17060-07-070-130 1
Toluene-d8 (S)102 %02/18/16 19:58 2037-26-570-130 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 02/18/16 13:30 18496-25-81000 100 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 02/19/16 17:47 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-Field Blank Lab ID: 92286780004 Collected: 02/16/16 18:05 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 02/20/16 03:18 309-00-202/18/16 09:150.050 0.050 1
alpha-BHC ND ug/L 02/20/16 03:18 319-84-602/18/16 09:150.050 0.050 1
beta-BHC ND ug/L 02/20/16 03:18 319-85-702/18/16 09:150.050 0.050 1
delta-BHC ND ug/L 02/20/16 03:18 319-86-802/18/16 09:150.050 0.050 1
gamma-BHC (Lindane)ND ug/L 02/20/16 03:18 58-89-902/18/16 09:150.050 0.050 1
Chlordane (Technical)ND ug/L 02/20/16 03:18 57-74-902/18/16 09:150.50 0.20 1
4,4'-DDD ND ug/L 02/20/16 03:18 72-54-802/18/16 09:150.10 0.050 1
4,4'-DDE ND ug/L 02/20/16 03:18 72-55-902/18/16 09:150.10 0.050 1
4,4'-DDT ND ug/L 02/20/16 03:18 50-29-302/18/16 09:150.10 0.050 1
Dieldrin ND ug/L 02/20/16 03:18 60-57-102/18/16 09:150.075 0.050 1
Endosulfan I ND ug/L 02/20/16 03:18 959-98-802/18/16 09:150.10 0.050 1
Endosulfan II ND ug/L 02/20/16 03:18 33213-65-902/18/16 09:150.10 0.050 1
Endosulfan sulfate ND ug/L 02/20/16 03:18 1031-07-802/18/16 09:150.10 0.050 1
Endrin ND ug/L 02/20/16 03:18 72-20-802/18/16 09:150.10 0.050 1
Endrin aldehyde ND ug/L 02/20/16 03:18 7421-93-402/18/16 09:150.10 0.050 1
Heptachlor ND ug/L 02/20/16 03:18 76-44-802/18/16 09:150.050 0.050 1
Heptachlor epoxide ND ug/L 02/20/16 03:18 1024-57-302/18/16 09:150.075 0.050 1
Methoxychlor ND ug/L 02/20/16 03:18 72-43-502/18/16 09:151.0 0.15 1
Toxaphene ND ug/L 02/20/16 03:18 8001-35-202/18/16 09:151.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)92 %02/20/16 03:18 877-09-802/18/16 09:1520-130 1
Decachlorobiphenyl (S)44 %02/20/16 03:18 2051-24-302/18/16 09:1520-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 02/19/16 02:11 12674-11-202/17/16 14:000.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 02/19/16 02:11 11104-28-202/17/16 14:000.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 02/19/16 02:11 11141-16-502/17/16 14:000.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 02/19/16 02:11 53469-21-902/17/16 14:000.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 02/19/16 02:11 12672-29-602/17/16 14:000.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 02/19/16 02:11 11097-69-102/17/16 14:000.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 02/19/16 02:11 11096-82-502/17/16 14:000.50 0.50 1
Surrogates
Decachlorobiphenyl (S)37 %02/19/16 02:11 2051-24-302/17/16 14:0010-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
Bentazon ND ug/L 02/23/16 03:04 25057-89-002/22/16 08:200.099 0.017 1
2,4-D ND ug/L 02/23/16 03:04 94-75-702/22/16 08:200.98 0.23 1
Dalapon ND ug/L 02/23/16 03:04 75-99-002/22/16 08:200.95 0.45 1
2,4-DB ND ug/L 02/23/16 03:04 94-82-602/22/16 08:202.0 0.53 1
Dicamba ND ug/L 02/23/16 03:04 1918-00-902/22/16 08:200.098 0.031 1
Dichlorprop ND ug/L 02/23/16 03:04 120-36-502/22/16 08:200.68 0.20 1
Dinoseb ND ug/L 02/23/16 03:04 88-85-702/22/16 08:200.20 0.060 1
Pentachlorophenol ND ug/L 02/23/16 03:04 87-86-502/22/16 08:200.030 0.018 1
Picloram ND ug/L 02/23/16 03:04 1918-02-102/22/16 08:200.099 0.020 1
2,4,5-T ND ug/L 02/23/16 03:04 93-76-502/22/16 08:200.20 0.044 1
2,4,5-TP (Silvex)ND ug/L 02/23/16 03:04 93-72-102/22/16 08:200.20 0.051 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-Field Blank Lab ID: 92286780004 Collected: 02/16/16 18:05 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
Surrogates
2,4-DCAA (S)81 %02/23/16 03:04 19719-28-902/22/16 08:2036-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 02/19/16 23:34 7440-36-002/18/16 18:306.0 3.8 1
Arsenic ND ug/L 02/19/16 23:34 7440-38-202/18/16 18:3010.0 2.5 1
Barium ND ug/L 02/23/16 17:58 7440-39-302/18/16 18:30100 2.5 1
Beryllium ND ug/L 02/23/16 17:58 7440-41-702/18/16 18:301.0 0.50 1
Cadmium ND ug/L 02/19/16 23:34 7440-43-902/18/16 18:301.0 0.50 1
Chromium ND ug/L 02/19/16 23:34 7440-47-302/18/16 18:3010.0 2.5 1
Cobalt ND ug/L 02/19/16 23:34 7440-48-402/18/16 18:3010.0 2.5 1
Copper ND ug/L 02/19/16 23:34 7440-50-802/18/16 18:3010.0 2.5 1
Lead ND ug/L 02/19/16 23:34 7439-92-102/18/16 18:3010.0 2.5 1
Nickel ND ug/L 02/23/16 17:58 7440-02-002/18/16 18:3050.0 2.5 1
Selenium ND ug/L 02/19/16 23:34 7782-49-202/18/16 18:3010.0 5.0 1
Silver ND ug/L 02/19/16 23:34 7440-22-402/18/16 18:3010.0 2.5 1
Thallium ND ug/L 02/19/16 23:34 7440-28-002/18/16 18:305.5 5.0 1
Tin ND ug/L 02/19/16 23:34 7440-31-502/18/16 18:30100 2.5 1
Vanadium ND ug/L 02/23/16 17:58 7440-62-202/18/16 18:3025.0 2.5 1
Zinc ND ug/L 02/19/16 23:34 7440-66-602/18/16 18:3010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 02/24/16 15:04 7439-97-602/22/16 16:200.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 02/23/16 20:32 83-32-902/18/16 11:0010.0 0.25 1
Acenaphthylene ND ug/L 02/23/16 20:32 208-96-802/18/16 11:0010.0 0.21 1
Acetophenone ND ug/L 02/23/16 20:32 98-86-202/18/16 11:0010.0 2.0 1
2-Acetylaminofluorene ND ug/L 02/23/16 20:32 53-96-302/18/16 11:0020.0 0.84 1
4-Aminobiphenyl ND ug/L 02/23/16 20:32 92-67-102/18/16 11:0020.0 0.92 1
Anthracene ND ug/L 02/23/16 20:32 120-12-702/18/16 11:0010.0 0.14 1
Benzo(a)anthracene ND ug/L 02/23/16 20:32 56-55-302/18/16 11:0010.0 0.33 1
Benzo(a)pyrene ND ug/L 02/23/16 20:32 50-32-802/18/16 11:0010.0 0.30 1
Benzo(b)fluoranthene ND ug/L 02/23/16 20:32 205-99-202/18/16 11:0010.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 02/23/16 20:32 191-24-202/18/16 11:0010.0 0.38 1
Benzo(k)fluoranthene ND ug/L 02/23/16 20:32 207-08-902/18/16 11:0010.0 0.43 1
Benzyl alcohol ND ug/L 02/23/16 20:32 100-51-602/18/16 11:0020.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 02/23/16 20:32 101-55-302/18/16 11:0010.0 1.3 1
Butylbenzylphthalate ND ug/L 02/23/16 20:32 85-68-702/18/16 11:0010.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 02/23/16 20:32 59-50-702/18/16 11:0020.0 4.2 1
4-Chloroaniline ND ug/L 02/23/16 20:32 106-47-802/18/16 11:0020.0 3.4 1
Chlorobenzilate ND ug/L 02/23/16 20:32 510-15-602/18/16 11:0010.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 02/23/16 20:32 111-91-102/18/16 11:0010.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 02/23/16 20:32 111-44-402/18/16 11:0010.0 1.5 1
bis(2-Chloroisopropyl) ether ND ug/L 02/23/16 20:32 108-60-102/18/16 11:0010.0 1.6 1
2-Chloronaphthalene ND ug/L 02/23/16 20:32 91-58-702/18/16 11:0010.0 2.2 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 27 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-Field Blank Lab ID: 92286780004 Collected: 02/16/16 18:05 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
2-Chlorophenol ND ug/L 02/23/16 20:32 95-57-802/18/16 11:0010.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 02/23/16 20:32 7005-72-302/18/16 11:0010.0 2.1 1
Chrysene ND ug/L 02/23/16 20:32 218-01-902/18/16 11:0010.0 0.21 1
Diallate ND ug/L 02/23/16 20:32 2303-16-402/18/16 11:0010.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 02/23/16 20:32 53-70-302/18/16 11:0010.0 0.55 1
Dibenzofuran ND ug/L 02/23/16 20:32 132-64-902/18/16 11:0010.0 1.8 1
3,3'-Dichlorobenzidine ND ug/L 02/23/16 20:32 91-94-102/18/16 11:0020.0 1.4 1
2,4-Dichlorophenol ND ug/L 02/23/16 20:32 120-83-202/18/16 11:0010.0 1.7 1
2,6-Dichlorophenol ND ug/L 02/23/16 20:32 87-65-002/18/16 11:0010.0 1.8 1
Diethylphthalate ND ug/L 02/23/16 20:32 84-66-202/18/16 11:006000 1.3 1
Dimethoate ND ug/L 02/23/16 20:32 60-51-502/18/16 11:0020.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 02/23/16 20:32 60-11-702/18/16 11:0010.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 02/23/16 20:32 57-97-602/18/16 11:0010.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 02/23/16 20:32 119-93-702/18/16 11:0010.0 2.1 1
2,4-Dimethylphenol ND ug/L 02/23/16 20:32 105-67-902/18/16 11:0010.0 2.2 1
Dimethylphthalate ND ug/L 02/23/16 20:32 131-11-302/18/16 11:0010.0 1.5 1
Di-n-butylphthalate ND ug/L 02/23/16 20:32 84-74-202/18/16 11:0010.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 02/23/16 20:32 534-52-102/18/16 11:0050.0 1.7 1
1,3-Dinitrobenzene ND ug/L 02/23/16 20:32 99-65-002/18/16 11:0020.0 1.5 1
2,4-Dinitrophenol ND ug/L 02/23/16 20:32 51-28-502/18/16 11:0050.0 6.5 1
2,4-Dinitrotoluene ND ug/L 02/23/16 20:32 121-14-202/18/16 11:0010.0 1.2 1
2,6-Dinitrotoluene ND ug/L 02/23/16 20:32 606-20-202/18/16 11:0010.0 1.7 1
Di-n-octylphthalate ND ug/L 02/23/16 20:32 117-84-002/18/16 11:0010.0 0.86 1
Diphenylamine ND ug/L 02/23/16 20:32 122-39-402/18/16 11:0010.0 1.3 1
Disulfoton ND ug/L 02/23/16 20:32 298-04-402/18/16 11:0010.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 02/23/16 20:32 117-81-702/18/16 11:0015.0 0.85 1
Ethyl methanesulfonate ND ug/L 02/23/16 20:32 62-50-002/18/16 11:0020.0 1.8 1
Famphur ND ug/L 02/23/16 20:32 52-85-702/18/16 11:0020.0 1.7 1
Fluoranthene ND ug/L 02/23/16 20:32 206-44-002/18/16 11:0010.0 0.21 1
Fluorene ND ug/L 02/23/16 20:32 86-73-702/18/16 11:0010.0 0.21 1
Hexachlorobenzene ND ug/L 02/23/16 20:32 118-74-102/18/16 11:0010.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 02/23/16 20:32 77-47-402/18/16 11:0010.0 1.8 1
Hexachloroethane ND ug/L 02/23/16 20:32 67-72-102/18/16 11:0010.0 1.5 1
Hexachloropropene ND ug/L 02/23/16 20:32 1888-71-702/18/16 11:0010.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 02/23/16 20:32 193-39-502/18/16 11:0010.0 0.29 1
Isodrin ND ug/L 02/23/16 20:32 465-73-602/18/16 11:0020.0 2.0 1
Isophorone ND ug/L 02/23/16 20:32 78-59-102/18/16 11:0010.0 1.8 1
Isosafrole ND ug/L 02/23/16 20:32 120-58-102/18/16 11:0010.0 1.8 1
Kepone ND ug/L 02/23/16 20:32 143-50-0 L202/18/16 11:0020.0 3.1 1
Methapyrilene ND ug/L 02/23/16 20:32 91-80-502/18/16 11:00100 2.7 1
3-Methylcholanthrene ND ug/L 02/23/16 20:32 56-49-502/18/16 11:0010.0 0.82 1
Methyl methanesulfonate ND ug/L 02/23/16 20:32 66-27-302/18/16 11:0010.0 1.3 1
2-Methylnaphthalene ND ug/L 02/23/16 20:32 91-57-602/18/16 11:0010.0 0.28 1
Methyl parathion ND ug/L 02/23/16 20:32 298-00-002/18/16 11:0010.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 02/23/16 20:32 95-48-702/18/16 11:0010.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 02/23/16 20:3202/18/16 11:0010.0 1.7 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-Field Blank Lab ID: 92286780004 Collected: 02/16/16 18:05 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
1-Naphthalenamine ND ug/L 02/23/16 20:32 134-32-702/18/16 11:0010.0 0.96 1
2-Naphthalenamine ND ug/L 02/23/16 20:32 91-59-802/18/16 11:0010.0 0.98 1
1,4-Naphthoquinone ND ug/L 02/23/16 20:32 130-15-402/18/16 11:0010.0 1.8 1
2-Nitroaniline ND ug/L 02/23/16 20:32 88-74-402/18/16 11:0050.0 2.8 1
3-Nitroaniline ND ug/L 02/23/16 20:32 99-09-202/18/16 11:0050.0 2.4 1
4-Nitroaniline ND ug/L 02/23/16 20:32 100-01-602/18/16 11:0020.0 2.5 1
Nitrobenzene ND ug/L 02/23/16 20:32 98-95-302/18/16 11:0010.0 1.7 1
2-Nitrophenol ND ug/L 02/23/16 20:32 88-75-502/18/16 11:0010.0 1.7 1
4-Nitrophenol ND ug/L 02/23/16 20:32 100-02-702/18/16 11:0050.0 5.8 1
5-Nitro-o-toluidine ND ug/L 02/23/16 20:32 99-55-802/18/16 11:0010.0 1.2 1
N-Nitrosodiethylamine ND ug/L 02/23/16 20:32 55-18-502/18/16 11:0020.0 1.8 1
N-Nitrosodimethylamine ND ug/L 02/23/16 20:32 62-75-902/18/16 11:0010.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 02/23/16 20:32 924-16-302/18/16 11:0010.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 02/23/16 20:32 621-64-702/18/16 11:0010.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 02/23/16 20:32 86-30-602/18/16 11:0010.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 02/23/16 20:32 10595-95-602/18/16 11:0010.0 1.8 1
N-Nitrosopiperidine ND ug/L 02/23/16 20:32 100-75-402/18/16 11:0020.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 02/23/16 20:32 930-55-202/18/16 11:0010.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 02/23/16 20:32 126-68-102/18/16 11:0010.0 1.8 1
Parathion (Ethyl parathion)ND ug/L 02/23/16 20:32 56-38-202/18/16 11:0010.0 1.1 1
Pentachlorobenzene ND ug/L 02/23/16 20:32 608-93-502/18/16 11:0010.0 2.0 1
Pentachloronitrobenzene ND ug/L 02/23/16 20:32 82-68-802/18/16 11:0020.0 1.0 1
Pentachlorophenol ND ug/L 02/23/16 20:32 87-86-502/18/16 11:0025.0 2.3 1
Phenacetin ND ug/L 02/23/16 20:32 62-44-202/18/16 11:0020.0 0.97 1
Phenanthrene ND ug/L 02/23/16 20:32 85-01-802/18/16 11:0010.0 0.22 1
Phenol ND ug/L 02/23/16 20:32 108-95-202/18/16 11:0010.0 1.7 1
p-Phenylenediamine ND ug/L 02/23/16 20:32 106-50-302/18/16 11:0010.0 0.96 1
Phorate ND ug/L 02/23/16 20:32 298-02-202/18/16 11:0010.0 1.1 1
Pronamide ND ug/L 02/23/16 20:32 23950-58-502/18/16 11:0010.0 0.97 1
Pyrene ND ug/L 02/23/16 20:32 129-00-002/18/16 11:0010.0 0.19 1
Safrole ND ug/L 02/23/16 20:32 94-59-702/18/16 11:0010.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 02/23/16 20:32 95-94-302/18/16 11:0010.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 02/23/16 20:32 58-90-202/18/16 11:0010.0 2.3 1
Thionazin ND ug/L 02/23/16 20:32 297-97-202/18/16 11:0020.0 1.2 1
O-Toluidine ND ug/L 02/23/16 20:32 95-53-402/18/16 11:0010.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 02/23/16 20:32 95-95-402/18/16 11:0010.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 02/23/16 20:32 88-06-202/18/16 11:0010.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 02/23/16 20:32 99-35-402/18/16 11:0010.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)56 %02/23/16 20:32 4165-60-002/18/16 11:0021-110 1
2-Fluorobiphenyl (S)68 %02/23/16 20:32 321-60-802/18/16 11:0027-110 1
Terphenyl-d14 (S)96 %02/23/16 20:32 1718-51-002/18/16 11:0031-107 1
Phenol-d6 (S)19 %02/23/16 20:32 13127-88-302/18/16 11:0010-110 1
2-Fluorophenol (S)32 %02/23/16 20:32 367-12-402/18/16 11:0012-110 1
2,4,6-Tribromophenol (S)80 %02/23/16 20:32 118-79-602/18/16 11:0027-110 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-Field Blank Lab ID: 92286780004 Collected: 02/16/16 18:05 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/18/16 20:15 67-64-1100 10.0 1
Acetonitrile ND ug/L 02/18/16 20:15 75-05-855.0 2.2 1
Acrolein ND ug/L 02/18/16 20:15 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 02/18/16 20:15 107-13-1200 1.9 1
Allyl chloride ND ug/L 02/18/16 20:15 107-05-110.0 1.5 1
Benzene ND ug/L 02/18/16 20:15 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/18/16 20:15 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/18/16 20:15 75-27-41.0 0.18 1
Bromoform ND ug/L 02/18/16 20:15 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/18/16 20:15 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/18/16 20:15 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/18/16 20:15 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/18/16 20:15 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/18/16 20:15 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/18/16 20:15 75-00-310.0 0.54 1
Chloroform ND ug/L 02/18/16 20:15 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/18/16 20:15 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/18/16 20:15 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/18/16 20:15 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/18/16 20:15 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/18/16 20:15 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/18/16 20:15 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/18/16 20:15 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 02/18/16 20:15 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 02/18/16 20:15 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/18/16 20:15 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 02/18/16 20:15 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/18/16 20:15 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/18/16 20:15 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/18/16 20:15 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/18/16 20:15 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/18/16 20:15 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/18/16 20:15 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/18/16 20:15 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/18/16 20:15 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/18/16 20:15 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/18/16 20:15 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/18/16 20:15 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/18/16 20:15 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/18/16 20:15 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 02/18/16 20:15 87-68-310.0 0.71 1
2-Hexanone ND ug/L 02/18/16 20:15 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/18/16 20:15 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/18/16 20:15 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 02/18/16 20:15 126-98-7100 0.93 1
Methylene Chloride ND ug/L 02/18/16 20:15 75-09-21.0 0.97 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-Field Blank Lab ID: 92286780004 Collected: 02/16/16 18:05 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Methyl methacrylate ND ug/L 02/18/16 20:15 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/18/16 20:15 108-10-1100 0.33 1
Naphthalene ND ug/L 02/18/16 20:15 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/18/16 20:15 107-12-0150 3.6 1
Styrene ND ug/L 02/18/16 20:15 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/18/16 20:15 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/18/16 20:15 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/18/16 20:15 127-18-41.0 0.46 1
Toluene ND ug/L 02/18/16 20:15 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/18/16 20:15 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/18/16 20:15 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/18/16 20:15 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/18/16 20:15 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/18/16 20:15 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/18/16 20:15 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/18/16 20:15 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/18/16 20:15 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/18/16 20:15 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %02/18/16 20:15 460-00-470-130 1
1,2-Dichloroethane-d4 (S)105 %02/18/16 20:15 17060-07-070-130 1
Toluene-d8 (S)102 %02/18/16 20:15 2037-26-570-130 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 02/18/16 13:30 18496-25-81000 100 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 02/19/16 17:48 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW4 Lab ID: 92286780005 Collected: 02/16/16 15:55 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony 4.3J ug/L 02/19/16 23:37 7440-36-002/18/16 18:306.0 3.8 1
Arsenic ND ug/L 02/19/16 23:37 7440-38-202/18/16 18:3010.0 2.5 1
Barium 3.0J ug/L 02/23/16 18:01 7440-39-302/18/16 18:30100 2.5 1
Beryllium ND ug/L 02/23/16 18:01 7440-41-702/18/16 18:301.0 0.50 1
Cadmium ND ug/L 02/19/16 23:37 7440-43-902/18/16 18:301.0 0.50 1
Chromium ND ug/L 02/19/16 23:37 7440-47-302/18/16 18:3010.0 2.5 1
Cobalt ND ug/L 02/19/16 23:37 7440-48-402/18/16 18:3010.0 2.5 1
Copper ND ug/L 02/19/16 23:37 7440-50-802/18/16 18:3010.0 2.5 1
Lead ND ug/L 02/19/16 23:37 7439-92-102/18/16 18:3010.0 2.5 1
Nickel 12.7J ug/L 02/23/16 18:01 7440-02-002/18/16 18:3050.0 2.5 1
Selenium ND ug/L 02/19/16 23:37 7782-49-202/18/16 18:3010.0 5.0 1
Silver ND ug/L 02/19/16 23:37 7440-22-402/18/16 18:3010.0 2.5 1
Thallium ND ug/L 02/19/16 23:37 7440-28-002/18/16 18:305.5 5.0 1
Vanadium 14.4J ug/L 02/23/16 18:01 7440-62-202/18/16 18:3025.0 2.5 1
Zinc 46.1 ug/L 02/19/16 23:37 7440-66-602/18/16 18:3010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/18/16 20:32 67-64-1100 10.0 1
Acetonitrile ND ug/L 02/18/16 20:32 75-05-855.0 2.2 1
Benzene ND ug/L 02/18/16 20:32 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/18/16 20:32 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/18/16 20:32 75-27-41.0 0.18 1
Bromoform ND ug/L 02/18/16 20:32 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/18/16 20:32 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/18/16 20:32 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/18/16 20:32 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/18/16 20:32 56-23-51.0 0.25 1
Chlorobenzene 1.5J ug/L 02/18/16 20:32 108-90-73.0 0.23 1
Chloroethane 0.79J ug/L 02/18/16 20:32 75-00-310.0 0.54 1
Chloroform ND ug/L 02/18/16 20:32 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/18/16 20:32 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/18/16 20:32 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/18/16 20:32 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/18/16 20:32 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/18/16 20:32 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/18/16 20:32 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/18/16 20:32 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/18/16 20:32 110-57-6100 1.0 1
1,1-Dichloroethane 0.45J ug/L 02/18/16 20:32 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/18/16 20:32 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/18/16 20:32 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/18/16 20:32 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/18/16 20:32 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/18/16 20:32 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 02/18/16 20:32 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/18/16 20:32 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW4 Lab ID: 92286780005 Collected: 02/16/16 15:55 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 02/18/16 20:32 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/18/16 20:32 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/18/16 20:32 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/18/16 20:32 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/18/16 20:32 108-10-1100 0.33 1
Styrene ND ug/L 02/18/16 20:32 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/18/16 20:32 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/18/16 20:32 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/18/16 20:32 127-18-41.0 0.46 1
Toluene ND ug/L 02/18/16 20:32 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/18/16 20:32 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/18/16 20:32 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/18/16 20:32 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/18/16 20:32 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/18/16 20:32 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/18/16 20:32 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/18/16 20:32 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/18/16 20:32 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %02/18/16 20:32 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %02/18/16 20:32 17060-07-070-130 1
Toluene-d8 (S)104 %02/18/16 20:32 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW5 Lab ID: 92286780006 Collected: 02/16/16 16:02 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 02/19/16 23:40 7440-36-002/18/16 18:306.0 3.8 1
Arsenic ND ug/L 02/19/16 23:40 7440-38-202/18/16 18:3010.0 2.5 1
Barium 126 ug/L 02/23/16 18:04 7440-39-302/18/16 18:30100 2.5 1
Beryllium ND ug/L 02/23/16 18:04 7440-41-702/18/16 18:301.0 0.50 1
Cadmium ND ug/L 02/19/16 23:40 7440-43-902/18/16 18:301.0 0.50 1
Chromium ND ug/L 02/19/16 23:40 7440-47-302/18/16 18:3010.0 2.5 1
Cobalt 13.1 ug/L 02/19/16 23:40 7440-48-402/18/16 18:3010.0 2.5 1
Copper 5.1J ug/L 02/19/16 23:40 7440-50-802/18/16 18:3010.0 2.5 1
Lead ND ug/L 02/19/16 23:40 7439-92-102/18/16 18:3010.0 2.5 1
Nickel 3.7J ug/L 02/23/16 18:04 7440-02-002/18/16 18:3050.0 2.5 1
Selenium ND ug/L 02/19/16 23:40 7782-49-202/18/16 18:3010.0 5.0 1
Silver ND ug/L 02/19/16 23:40 7440-22-402/18/16 18:3010.0 2.5 1
Thallium ND ug/L 02/19/16 23:40 7440-28-002/18/16 18:305.5 5.0 1
Vanadium ND ug/L 02/23/16 18:04 7440-62-202/18/16 18:3025.0 2.5 1
Zinc 5.9J ug/L 02/19/16 23:40 7440-66-602/18/16 18:3010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/18/16 20:49 67-64-1100 10.0 1
Acetonitrile ND ug/L 02/18/16 20:49 75-05-855.0 2.2 1
Benzene ND ug/L 02/18/16 20:49 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/18/16 20:49 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/18/16 20:49 75-27-41.0 0.18 1
Bromoform ND ug/L 02/18/16 20:49 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/18/16 20:49 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/18/16 20:49 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/18/16 20:49 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/18/16 20:49 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/18/16 20:49 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/18/16 20:49 75-00-310.0 0.54 1
Chloroform ND ug/L 02/18/16 20:49 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/18/16 20:49 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/18/16 20:49 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/18/16 20:49 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/18/16 20:49 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/18/16 20:49 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/18/16 20:49 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/18/16 20:49 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/18/16 20:49 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/18/16 20:49 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/18/16 20:49 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/18/16 20:49 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/18/16 20:49 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/18/16 20:49 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/18/16 20:49 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 02/18/16 20:49 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/18/16 20:49 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW5 Lab ID: 92286780006 Collected: 02/16/16 16:02 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 02/18/16 20:49 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/18/16 20:49 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/18/16 20:49 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/18/16 20:49 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/18/16 20:49 108-10-1100 0.33 1
Styrene ND ug/L 02/18/16 20:49 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/18/16 20:49 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/18/16 20:49 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/18/16 20:49 127-18-41.0 0.46 1
Toluene ND ug/L 02/18/16 20:49 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/18/16 20:49 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/18/16 20:49 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/18/16 20:49 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/18/16 20:49 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/18/16 20:49 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/18/16 20:49 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/18/16 20:49 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/18/16 20:49 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)94 %02/18/16 20:49 460-00-470-130 1
1,2-Dichloroethane-d4 (S)105 %02/18/16 20:49 17060-07-070-130 1
Toluene-d8 (S)103 %02/18/16 20:49 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW6 Lab ID: 92286780007 Collected: 02/16/16 16:20 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 02/19/16 23:43 7440-36-002/18/16 18:306.0 3.8 1
Arsenic ND ug/L 02/19/16 23:43 7440-38-202/18/16 18:3010.0 2.5 1
Barium ND ug/L 02/23/16 18:07 7440-39-302/18/16 18:30100 2.5 1
Beryllium ND ug/L 02/23/16 18:07 7440-41-702/18/16 18:301.0 0.50 1
Cadmium ND ug/L 02/19/16 23:43 7440-43-902/18/16 18:301.0 0.50 1
Chromium ND ug/L 02/19/16 23:43 7440-47-302/18/16 18:3010.0 2.5 1
Cobalt ND ug/L 02/19/16 23:43 7440-48-402/18/16 18:3010.0 2.5 1
Copper ND ug/L 02/19/16 23:43 7440-50-802/18/16 18:3010.0 2.5 1
Lead ND ug/L 02/19/16 23:43 7439-92-102/18/16 18:3010.0 2.5 1
Nickel ND ug/L 02/23/16 18:07 7440-02-002/18/16 18:3050.0 2.5 1
Selenium ND ug/L 02/19/16 23:43 7782-49-202/18/16 18:3010.0 5.0 1
Silver ND ug/L 02/19/16 23:43 7440-22-402/18/16 18:3010.0 2.5 1
Thallium ND ug/L 02/19/16 23:43 7440-28-002/18/16 18:305.5 5.0 1
Vanadium ND ug/L 02/23/16 18:07 7440-62-202/18/16 18:3025.0 2.5 1
Zinc ND ug/L 02/19/16 23:43 7440-66-602/18/16 18:3010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/18/16 21:06 67-64-1100 10.0 1
Acetonitrile ND ug/L 02/18/16 21:06 75-05-855.0 2.2 1
Benzene ND ug/L 02/18/16 21:06 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/18/16 21:06 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/18/16 21:06 75-27-41.0 0.18 1
Bromoform ND ug/L 02/18/16 21:06 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/18/16 21:06 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/18/16 21:06 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/18/16 21:06 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/18/16 21:06 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/18/16 21:06 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/18/16 21:06 75-00-310.0 0.54 1
Chloroform ND ug/L 02/18/16 21:06 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/18/16 21:06 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/18/16 21:06 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/18/16 21:06 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/18/16 21:06 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/18/16 21:06 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/18/16 21:06 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/18/16 21:06 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/18/16 21:06 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/18/16 21:06 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/18/16 21:06 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/18/16 21:06 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/18/16 21:06 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/18/16 21:06 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/18/16 21:06 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 02/18/16 21:06 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/18/16 21:06 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-MW6 Lab ID: 92286780007 Collected: 02/16/16 16:20 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 02/18/16 21:06 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/18/16 21:06 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/18/16 21:06 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/18/16 21:06 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/18/16 21:06 108-10-1100 0.33 1
Styrene ND ug/L 02/18/16 21:06 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/18/16 21:06 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/18/16 21:06 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/18/16 21:06 127-18-41.0 0.46 1
Toluene ND ug/L 02/18/16 21:06 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/18/16 21:06 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/18/16 21:06 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/18/16 21:06 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/18/16 21:06 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/18/16 21:06 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/18/16 21:06 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/18/16 21:06 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/18/16 21:06 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %02/18/16 21:06 460-00-470-130 1
1,2-Dichloroethane-d4 (S)106 %02/18/16 21:06 17060-07-070-130 1
Toluene-d8 (S)103 %02/18/16 21:06 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-SW1 Lab ID: 92286780008 Collected: 02/16/16 16:10 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 02/19/16 23:46 7440-36-002/18/16 18:306.0 3.8 1
Arsenic ND ug/L 02/19/16 23:46 7440-38-202/18/16 18:3010.0 2.5 1
Barium 33.1J ug/L 02/23/16 18:10 7440-39-302/18/16 18:30100 2.5 1
Beryllium ND ug/L 02/23/16 18:10 7440-41-702/18/16 18:301.0 0.50 1
Cadmium ND ug/L 02/19/16 23:46 7440-43-902/18/16 18:301.0 0.50 1
Chromium 4.6J ug/L 02/19/16 23:46 7440-47-302/18/16 18:3010.0 2.5 1
Cobalt ND ug/L 02/19/16 23:46 7440-48-402/18/16 18:3010.0 2.5 1
Copper 2.9J ug/L 02/19/16 23:46 7440-50-802/18/16 18:3010.0 2.5 1
Lead ND ug/L 02/19/16 23:46 7439-92-102/18/16 18:3010.0 2.5 1
Nickel 2.9J ug/L 02/23/16 18:10 7440-02-002/18/16 18:3050.0 2.5 1
Selenium ND ug/L 02/19/16 23:46 7782-49-202/18/16 18:3010.0 5.0 1
Silver ND ug/L 02/19/16 23:46 7440-22-402/18/16 18:3010.0 2.5 1
Thallium ND ug/L 02/19/16 23:46 7440-28-002/18/16 18:305.5 5.0 1
Vanadium 4.1J ug/L 02/23/16 18:10 7440-62-202/18/16 18:3025.0 2.5 1
Zinc 7.0J ug/L 02/19/16 23:46 7440-66-602/18/16 18:3010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/18/16 21:23 67-64-1100 10.0 1
Acetonitrile ND ug/L 02/18/16 21:23 75-05-855.0 2.2 1
Benzene ND ug/L 02/18/16 21:23 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/18/16 21:23 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/18/16 21:23 75-27-41.0 0.18 1
Bromoform ND ug/L 02/18/16 21:23 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/18/16 21:23 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/18/16 21:23 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/18/16 21:23 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/18/16 21:23 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/18/16 21:23 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/18/16 21:23 75-00-310.0 0.54 1
Chloroform ND ug/L 02/18/16 21:23 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/18/16 21:23 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/18/16 21:23 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/18/16 21:23 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/18/16 21:23 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/18/16 21:23 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/18/16 21:23 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/18/16 21:23 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/18/16 21:23 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/18/16 21:23 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/18/16 21:23 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/18/16 21:23 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/18/16 21:23 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/18/16 21:23 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/18/16 21:23 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 02/18/16 21:23 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/18/16 21:23 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-SW1 Lab ID: 92286780008 Collected: 02/16/16 16:10 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 02/18/16 21:23 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/18/16 21:23 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/18/16 21:23 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/18/16 21:23 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/18/16 21:23 108-10-1100 0.33 1
Styrene ND ug/L 02/18/16 21:23 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/18/16 21:23 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/18/16 21:23 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/18/16 21:23 127-18-41.0 0.46 1
Toluene ND ug/L 02/18/16 21:23 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/18/16 21:23 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/18/16 21:23 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/18/16 21:23 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/18/16 21:23 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/18/16 21:23 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/18/16 21:23 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/18/16 21:23 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/18/16 21:23 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %02/18/16 21:23 460-00-470-130 1
1,2-Dichloroethane-d4 (S)108 %02/18/16 21:23 17060-07-070-130 1
Toluene-d8 (S)103 %02/18/16 21:23 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-SW2 Lab ID: 92286780009 Collected: 02/16/16 13:24 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 02/19/16 23:59 7440-36-002/18/16 18:306.0 3.8 1
Arsenic ND ug/L 02/19/16 23:59 7440-38-202/18/16 18:3010.0 2.5 1
Barium 33.5J ug/L 02/23/16 18:13 7440-39-302/18/16 18:30100 2.5 1
Beryllium ND ug/L 02/23/16 18:13 7440-41-702/18/16 18:301.0 0.50 1
Cadmium ND ug/L 02/19/16 23:59 7440-43-902/18/16 18:301.0 0.50 1
Chromium 6.8J ug/L 02/19/16 23:59 7440-47-302/18/16 18:3010.0 2.5 1
Cobalt ND ug/L 02/19/16 23:59 7440-48-402/18/16 18:3010.0 2.5 1
Copper 3.4J ug/L 02/19/16 23:59 7440-50-802/18/16 18:3010.0 2.5 1
Lead ND ug/L 02/19/16 23:59 7439-92-102/18/16 18:3010.0 2.5 1
Nickel 4.7J ug/L 02/19/16 23:59 7440-02-002/18/16 18:3050.0 2.5 1
Selenium ND ug/L 02/19/16 23:59 7782-49-202/18/16 18:3010.0 5.0 1
Silver ND ug/L 02/19/16 23:59 7440-22-402/18/16 18:3010.0 2.5 1
Thallium ND ug/L 02/19/16 23:59 7440-28-002/18/16 18:305.5 5.0 1
Vanadium 5.8J ug/L 02/23/16 18:13 7440-62-202/18/16 18:3025.0 2.5 1
Zinc ND ug/L 02/19/16 23:59 7440-66-602/18/16 18:3010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/18/16 21:40 67-64-1100 10.0 1
Acetonitrile ND ug/L 02/18/16 21:40 75-05-855.0 2.2 1
Benzene ND ug/L 02/18/16 21:40 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/18/16 21:40 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/18/16 21:40 75-27-41.0 0.18 1
Bromoform ND ug/L 02/18/16 21:40 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/18/16 21:40 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/18/16 21:40 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/18/16 21:40 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/18/16 21:40 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/18/16 21:40 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/18/16 21:40 75-00-310.0 0.54 1
Chloroform ND ug/L 02/18/16 21:40 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/18/16 21:40 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/18/16 21:40 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/18/16 21:40 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/18/16 21:40 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/18/16 21:40 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/18/16 21:40 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/18/16 21:40 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/18/16 21:40 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/18/16 21:40 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/18/16 21:40 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/18/16 21:40 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/18/16 21:40 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/18/16 21:40 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/18/16 21:40 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 02/18/16 21:40 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/18/16 21:40 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-SW2 Lab ID: 92286780009 Collected: 02/16/16 13:24 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 02/18/16 21:40 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/18/16 21:40 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/18/16 21:40 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/18/16 21:40 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/18/16 21:40 108-10-1100 0.33 1
Styrene ND ug/L 02/18/16 21:40 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/18/16 21:40 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/18/16 21:40 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/18/16 21:40 127-18-41.0 0.46 1
Toluene ND ug/L 02/18/16 21:40 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/18/16 21:40 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/18/16 21:40 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/18/16 21:40 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/18/16 21:40 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/18/16 21:40 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/18/16 21:40 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/18/16 21:40 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/18/16 21:40 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %02/18/16 21:40 460-00-470-130 1
1,2-Dichloroethane-d4 (S)106 %02/18/16 21:40 17060-07-070-130 1
Toluene-d8 (S)104 %02/18/16 21:40 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-NES1 Lab ID: 92286780010 Collected: 02/16/16 17:05 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/18/16 21:57 67-64-1100 10.0 1
Acetonitrile ND ug/L 02/18/16 21:57 75-05-855.0 2.2 1
Benzene ND ug/L 02/18/16 21:57 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/18/16 21:57 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/18/16 21:57 75-27-41.0 0.18 1
Bromoform ND ug/L 02/18/16 21:57 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/18/16 21:57 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/18/16 21:57 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/18/16 21:57 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/18/16 21:57 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/18/16 21:57 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/18/16 21:57 75-00-310.0 0.54 1
Chloroform ND ug/L 02/18/16 21:57 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/18/16 21:57 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/18/16 21:57 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/18/16 21:57 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/18/16 21:57 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/18/16 21:57 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/18/16 21:57 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/18/16 21:57 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/18/16 21:57 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/18/16 21:57 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/18/16 21:57 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/18/16 21:57 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/18/16 21:57 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/18/16 21:57 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/18/16 21:57 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 02/18/16 21:57 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/18/16 21:57 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/18/16 21:57 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/18/16 21:57 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/18/16 21:57 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/18/16 21:57 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/18/16 21:57 108-10-1100 0.33 1
Styrene ND ug/L 02/18/16 21:57 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/18/16 21:57 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/18/16 21:57 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/18/16 21:57 127-18-41.0 0.46 1
Toluene ND ug/L 02/18/16 21:57 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/18/16 21:57 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/18/16 21:57 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/18/16 21:57 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/18/16 21:57 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/18/16 21:57 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/18/16 21:57 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/18/16 21:57 75-01-41.0 0.62 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-NES1 Lab ID: 92286780010 Collected: 02/16/16 17:05 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Xylene (Total)ND ug/L 02/18/16 21:57 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %02/18/16 21:57 460-00-470-130 1
1,2-Dichloroethane-d4 (S)108 %02/18/16 21:57 17060-07-070-130 1
Toluene-d8 (S)103 %02/18/16 21:57 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-Trip Blank Lab ID: 92286780011 Collected: 02/16/16 08:00 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/18/16 18:16 67-64-1100 10.0 1
Acetonitrile ND ug/L 02/18/16 18:16 75-05-855.0 2.2 1
Acrolein ND ug/L 02/18/16 18:16 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 02/18/16 18:16 107-13-1200 1.9 1
Allyl chloride ND ug/L 02/18/16 18:16 107-05-110.0 1.5 1
Benzene ND ug/L 02/18/16 18:16 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/18/16 18:16 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/18/16 18:16 75-27-41.0 0.18 1
Bromoform ND ug/L 02/18/16 18:16 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/18/16 18:16 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/18/16 18:16 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/18/16 18:16 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/18/16 18:16 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/18/16 18:16 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/18/16 18:16 75-00-310.0 0.54 1
Chloroform ND ug/L 02/18/16 18:16 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/18/16 18:16 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/18/16 18:16 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/18/16 18:16 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/18/16 18:16 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/18/16 18:16 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/18/16 18:16 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/18/16 18:16 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 02/18/16 18:16 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 02/18/16 18:16 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/18/16 18:16 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 02/18/16 18:16 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/18/16 18:16 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/18/16 18:16 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/18/16 18:16 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/18/16 18:16 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/18/16 18:16 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/18/16 18:16 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/18/16 18:16 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/18/16 18:16 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/18/16 18:16 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/18/16 18:16 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/18/16 18:16 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/18/16 18:16 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/18/16 18:16 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 02/18/16 18:16 87-68-310.0 0.71 1
2-Hexanone ND ug/L 02/18/16 18:16 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/18/16 18:16 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/18/16 18:16 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 02/18/16 18:16 126-98-7100 0.93 1
Methylene Chloride ND ug/L 02/18/16 18:16 75-09-21.0 0.97 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Sample: 3902-Trip Blank Lab ID: 92286780011 Collected: 02/16/16 08:00 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Methyl methacrylate ND ug/L 02/18/16 18:16 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/18/16 18:16 108-10-1100 0.33 1
Naphthalene ND ug/L 02/18/16 18:16 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/18/16 18:16 107-12-0150 3.6 1
Styrene ND ug/L 02/18/16 18:16 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/18/16 18:16 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/18/16 18:16 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/18/16 18:16 127-18-41.0 0.46 1
Toluene ND ug/L 02/18/16 18:16 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/18/16 18:16 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/18/16 18:16 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/18/16 18:16 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/18/16 18:16 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/18/16 18:16 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/18/16 18:16 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/18/16 18:16 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/18/16 18:16 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/18/16 18:16 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)97 %02/18/16 18:16 460-00-470-130 1
1,2-Dichloroethane-d4 (S)107 %02/18/16 18:16 17060-07-070-130 1
Toluene-d8 (S)103 %02/18/16 18:16 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8979
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92286780001, 92286780002, 92286780003, 92286780004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1669821
Associated Lab Samples:92286780001, 92286780002, 92286780003, 92286780004
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 02/24/16 14:030.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1669822LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.62.5 104 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1669823MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286924008
1669825
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 91 75-12588 3 252.5ND 2.3 2.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20737
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92286780001, 92286780002, 92286780003, 92286780004, 92286780005, 92286780006, 92286780007,
92286780008, 92286780009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1669003
Associated Lab Samples: 92286780001, 92286780002, 92286780003, 92286780004, 92286780005, 92286780006, 92286780007,
92286780008, 92286780009
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 6.0 02/19/16 22:373.8
Arsenic ug/L ND 10.0 02/19/16 22:372.5
Barium ug/L ND 100 02/19/16 22:372.5
Beryllium ug/L ND 1.0 02/19/16 22:370.50
Cadmium ug/L ND 1.0 02/19/16 22:370.50
Chromium ug/L ND 10.0 02/19/16 22:372.5
Cobalt ug/L ND 10.0 02/19/16 22:372.5
Copper ug/L ND 10.0 02/19/16 22:372.5
Lead ug/L ND 10.0 02/19/16 22:372.5
Nickel ug/L ND 50.0 02/19/16 22:372.5
Selenium ug/L ND 10.0 02/19/16 22:375.0
Silver ug/L ND 10.0 02/19/16 22:372.5
Thallium ug/L ND 5.5 02/19/16 22:375.0
Tin ug/L ND 100 02/19/16 22:372.5
Vanadium ug/L ND 25.0 02/23/16 16:462.5
Zinc ug/L ND 10.0 02/19/16 22:375.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1669004LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 460500 92 80-120
Arsenic ug/L 487500 97 80-120
Barium ug/L 540500 108 80-120
Beryllium ug/L 537500 107 80-120
Cadmium ug/L 524500 105 80-120
Chromium ug/L 522500 104 80-120
Cobalt ug/L 519500 104 80-120
Copper ug/L 528500 106 80-120
Lead ug/L 515500 103 80-120
Nickel ug/L 526500 105 80-120
Selenium ug/L 514500 103 80-120
Silver ug/L 226250 91 80-120
Thallium ug/L 475500 95 80-120
Tin ug/L 462500 92 80-120
Vanadium ug/L 498500 100 80-120
Zinc ug/L 511500 102 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 47 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1669005MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286895001
1669006
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 90 75-12593 3 25500ND452 465
Arsenic ug/L 500 98 75-125101 3 25500ND490 504
Barium ug/L 500 104 75-125106 1 25500354873 884
Beryllium ug/L 500 104 75-125108 3 25500ND521 539
Cadmium ug/L 500 102 75-125105 3 25500ND509 526
Chromium ug/L 500 100 75-125104 4 25500ND501 523
Cobalt ug/L 500 98 75-125101 3 25500ND491 506
Copper ug/L 500 103 75-125107 4 25500ND515 535
Lead ug/L 500 96 75-12599 3 25500ND478 494
Nickel ug/L 500 99 75-125102 4 25500ND494 512
Selenium ug/L 500 100 75-125104 3 25500ND503 519
Silver ug/L 250 88 75-12591 4 25250ND220 228
Thallium ug/L 500 84 75-12591 8 2550013.7 434 470
Tin ug/L 500 89 75-12592 4 25500ND443 459
Vanadium ug/L 500 99 75-125106 6 255005.1 502 535
Zinc ug/L 500 98 75-125101 3 25500ND502 516
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 48 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/35624
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92286780001, 92286780002, 92286780003, 92286780004, 92286780005, 92286780006, 92286780007,
92286780008, 92286780009, 92286780010, 92286780011
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1669161
Associated Lab Samples: 92286780001, 92286780002, 92286780003, 92286780004, 92286780005, 92286780006, 92286780007,
92286780008, 92286780009, 92286780010, 92286780011
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 02/18/16 13:450.33
1,1,1-Trichloroethane ug/L ND 1.0 02/18/16 13:450.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 02/18/16 13:450.40
1,1,2-Trichloroethane ug/L ND 1.0 02/18/16 13:450.29
1,1-Dichloroethane ug/L ND 5.0 02/18/16 13:450.32
1,1-Dichloroethene ug/L ND 5.0 02/18/16 13:450.56
1,1-Dichloropropene ug/L ND 5.0 02/18/16 13:450.49
1,2,3-Trichloropropane ug/L ND 1.0 02/18/16 13:450.41
1,2,4-Trichlorobenzene ug/L ND 10.0 02/18/16 13:450.35
1,2-Dibromo-3-chloropropane ug/L ND 13.0 02/18/16 13:452.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 02/18/16 13:450.27
1,2-Dichlorobenzene ug/L ND 5.0 02/18/16 13:450.30
1,2-Dichloroethane ug/L ND 1.0 02/18/16 13:450.24
1,2-Dichloropropane ug/L ND 1.0 02/18/16 13:450.27
1,3-Dichlorobenzene ug/L ND 5.0 02/18/16 13:450.24
1,3-Dichloropropane ug/L ND 1.0 02/18/16 13:450.28
1,4-Dichlorobenzene ug/L ND 1.0 02/18/16 13:450.33
2,2-Dichloropropane ug/L ND 15.0 02/18/16 13:450.13
2-Butanone (MEK)ug/L ND 100 02/18/16 13:450.96
2-Hexanone ug/L ND 50.0 02/18/16 13:450.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 02/18/16 13:450.33
Acetone ug/L ND 100 02/18/16 13:4510.0
Acetonitrile ug/L ND 55.0 02/18/16 13:452.2
Acrolein ug/L ND 53.0 02/18/16 13:451.6
Acrylonitrile ug/L ND 200 02/18/16 13:451.9
Allyl chloride ug/L ND 10.0 02/18/16 13:451.5
Benzene ug/L ND 1.0 02/18/16 13:450.25
Bromochloromethane ug/L ND 3.0 02/18/16 13:450.17
Bromodichloromethane ug/L ND 1.0 02/18/16 13:450.18
Bromoform ug/L ND 3.0 02/18/16 13:450.26
Bromomethane ug/L ND 10.0 02/18/16 13:450.29
Carbon disulfide ug/L ND 100 02/18/16 13:451.2
Carbon tetrachloride ug/L ND 1.0 02/18/16 13:450.25
Chlorobenzene ug/L ND 3.0 02/18/16 13:450.23
Chloroethane ug/L ND 10.0 02/18/16 13:450.54
Chloroform ug/L ND 5.0 02/18/16 13:450.14
Chloromethane ug/L ND 1.0 02/18/16 13:450.11
Chloroprene ug/L ND 20.0 02/18/16 13:450.27
cis-1,2-Dichloroethene ug/L ND 5.0 02/18/16 13:450.19
cis-1,3-Dichloropropene ug/L ND 1.0 02/18/16 13:450.13
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 49 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1669161
Associated Lab Samples: 92286780001, 92286780002, 92286780003, 92286780004, 92286780005, 92286780006, 92286780007,
92286780008, 92286780009, 92286780010, 92286780011
Matrix: Water
AnalyzedMDL
Dibromochloromethane ug/L ND 3.0 02/18/16 13:450.21
Dibromomethane ug/L ND 10.0 02/18/16 13:450.21
Dichlorodifluoromethane ug/L ND 5.0 02/18/16 13:450.21
Ethyl methacrylate ug/L ND 10.0 02/18/16 13:450.20
Ethylbenzene ug/L ND 1.0 02/18/16 13:450.30
Hexachloro-1,3-butadiene ug/L ND 10.0 02/18/16 13:450.71
Iodomethane ug/L ND 10.0 02/18/16 13:450.32
Isobutanol ug/L ND 100 02/18/16 13:4535.0
Methacrylonitrile ug/L ND 100 02/18/16 13:450.93
Methyl methacrylate ug/L ND 30.0 02/18/16 13:452.0
Methylene Chloride ug/L ND 1.0 02/18/16 13:450.97
Naphthalene ug/L ND 10.0 02/18/16 13:450.24
Propionitrile ug/L ND 150 02/18/16 13:453.6
Styrene ug/L ND 1.0 02/18/16 13:450.26
Tetrachloroethene ug/L ND 1.0 02/18/16 13:450.46
Toluene ug/L ND 1.0 02/18/16 13:450.26
trans-1,2-Dichloroethene ug/L ND 5.0 02/18/16 13:450.49
trans-1,3-Dichloropropene ug/L ND 1.0 02/18/16 13:450.26
trans-1,4-Dichloro-2-butene ug/L ND 100 02/18/16 13:451.0
Trichloroethene ug/L ND 1.0 02/18/16 13:450.47
Trichlorofluoromethane ug/L ND 1.0 02/18/16 13:450.20
Vinyl acetate ug/L ND 50.0 02/18/16 13:450.35
Vinyl chloride ug/L ND 1.0 02/18/16 13:450.62
Xylene (Total)ug/L ND 5.0 02/18/16 13:450.66
1,2-Dichloroethane-d4 (S)%108 70-130 02/18/16 13:45
4-Bromofluorobenzene (S)%96 70-130 02/18/16 13:45
Toluene-d8 (S)%102 70-130 02/18/16 13:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1669162LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 48.350 97 80-125
1,1,1-Trichloroethane ug/L 49.050 98 71-129
1,1,2,2-Tetrachloroethane ug/L 46.750 93 79-124
1,1,2-Trichloroethane ug/L 45.850 92 85-125
1,1-Dichloroethane ug/L 47.550 95 73-126
1,1-Dichloroethene ug/L 50.850 102 66-135
1,1-Dichloropropene ug/L 49.850 100 74-135
1,2,3-Trichloropropane ug/L 47.850 96 75-130
1,2,4-Trichlorobenzene ug/L 45.750 91 75-134
1,2-Dibromo-3-chloropropane ug/L 52.250 104 71-133
1,2-Dibromoethane (EDB)ug/L 48.150 96 83-124
1,2-Dichlorobenzene ug/L 45.350 91 80-133
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 50 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1669162LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichloroethane ug/L 51.150 102 67-128
1,2-Dichloropropane ug/L 47.950 96 75-132
1,3-Dichlorobenzene ug/L 47.450 95 77-130
1,3-Dichloropropane ug/L 46.850 94 76-131
1,4-Dichlorobenzene ug/L 46.650 93 78-130
2,2-Dichloropropane ug/L 48.150 96 40-160
2-Butanone (MEK)ug/L 121100 121 61-144
2-Hexanone ug/L 106100 106 68-143
4-Methyl-2-pentanone (MIBK)ug/L 107100 107 72-135
Acetone ug/L 123100 123 48-146
Acetonitrile ug/L 576500 115 62-150
Acrolein ug/L 234250 94 24-160
Acrylonitrile ug/L 264250 105 40-160
Allyl chloride ug/L 46.750 93 66-137
Benzene ug/L 47.150 94 80-125
Bromochloromethane ug/L 45.750 91 71-125
Bromodichloromethane ug/L 48.450 97 78-124
Bromoform ug/L 53.850 108 71-128
Bromomethane ug/L 57.650 115 40-160
Carbon disulfide ug/L 52.1J50 104 50-160
Carbon tetrachloride ug/L 49.350 99 69-131
Chlorobenzene ug/L 46.450 93 81-122
Chloroethane ug/L 52.350 105 39-148
Chloroform ug/L 46.050 92 73-127
Chloromethane ug/L 60.550 121 44-146
Chloroprene ug/L 49.950 100 75-145
cis-1,2-Dichloroethene ug/L 47.550 95 74-124
cis-1,3-Dichloropropene ug/L 50.050 100 72-132
Dibromochloromethane ug/L 52.150 104 78-125
Dibromomethane ug/L 44.950 90 82-120
Dichlorodifluoromethane ug/L 40.750 81 34-157
Ethyl methacrylate ug/L 50.050 100 82-121
Ethylbenzene ug/L 47.150 94 79-121
Hexachloro-1,3-butadiene ug/L 48.250 96 72-131
Iodomethane ug/L 132100 132 39-154
Isobutanol ug/L 10601000 106 34-160
Methacrylonitrile ug/L 497500 99 74-134
Methyl methacrylate ug/L 46.950 94 84-124
Methylene Chloride ug/L 54.950 110 64-133
Naphthalene ug/L 47.450 95 73-133
Propionitrile ug/L 491500 98 73-140
Styrene ug/L 47.250 94 84-126
Tetrachloroethene ug/L 46.750 93 78-122
Toluene ug/L 46.050 92 80-121
trans-1,2-Dichloroethene ug/L 49.250 98 71-127
trans-1,3-Dichloropropene ug/L 49.150 98 69-141
trans-1,4-Dichloro-2-butene ug/L 68.2J50 136 40-160
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 51 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1669162LABORATORY CONTROL SAMPLE:
LCSSpike
Trichloroethene ug/L 44.950 90 78-122
Trichlorofluoromethane ug/L 47.950 96 53-137
Vinyl acetate ug/L 95.0100 95 40-160
Vinyl chloride ug/L 51.850 104 58-137
Xylene (Total)ug/L 141150 94 81-126
1,2-Dichloroethane-d4 (S)%103 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%102 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1669164MATRIX SPIKE SAMPLE:
MSSpike
Result
92286895002
1,1,1,2-Tetrachloroethane ug/L 19.820 99 70-130ND
1,1,1-Trichloroethane ug/L 21.320 106 70-130ND
1,1,2,2-Tetrachloroethane ug/L 19.720 98 70-130ND
1,1,2-Trichloroethane ug/L 19.520 98 70-130ND
1,1-Dichloroethane ug/L 20.620 103 70-130ND
1,1-Dichloroethene ug/L 22.520 113 70-166ND
1,1-Dichloropropene ug/L 22.020 110 70-130ND
1,2,3-Trichloropropane ug/L 20.220 101 70-130ND
1,2,4-Trichlorobenzene ug/L 19.620 98 70-130ND
1,2-Dibromo-3-chloropropane ug/L 20.620 103 70-130ND
1,2-Dibromoethane (EDB)ug/L 20.120 101 70-130ND
1,2-Dichlorobenzene ug/L 19.820 99 70-130ND
1,2-Dichloroethane ug/L 20.520 102 70-130ND
1,2-Dichloropropane ug/L 20.220 101 70-130ND
1,3-Dichlorobenzene ug/L 20.720 103 70-130ND
1,3-Dichloropropane ug/L 19.620 98 70-130ND
1,4-Dichlorobenzene ug/L 20.620 103 70-130ND
2,2-Dichloropropane ug/L 18.420 92 70-130ND
2-Butanone (MEK)ug/L 47.4J40 119 70-130ND
2-Hexanone ug/L 43.9J40 110 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 44.9J40 112 70-130ND
Acetone ug/L 44.5J40 111 70-130ND
Acetonitrile ug/L 219200 109 70-130ND
Acrolein ug/L 83.6100 84 70-130ND
Acrylonitrile ug/L 108J100 108 70-130ND
Allyl chloride ug/L 19.620 98 70-130ND
Benzene ug/L 20.720 104 70-148ND
Bromochloromethane ug/L 19.120 95 70-130ND
Bromodichloromethane ug/L 19.620 98 70-130ND
Bromoform ug/L 16.620 83 70-130ND
Bromomethane ug/L 17.920 89 70-130ND
Carbon disulfide ug/L 21.7J20 109 70-130ND
Carbon tetrachloride ug/L 21.420 107 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 52 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1669164MATRIX SPIKE SAMPLE:
MSSpike
Result
92286895002
Chlorobenzene ug/L 20.220 101 70-146ND
Chloroethane ug/L 22.920 115 70-130ND
Chloroform ug/L 20.220 101 70-130ND
Chloromethane ug/L 24.820 124 70-130ND
Chloroprene ug/L 22.320 112 70-130ND
cis-1,2-Dichloroethene ug/L 20.520 103 70-130ND
cis-1,3-Dichloropropene ug/L 19.720 98 70-130ND
Dibromochloromethane ug/L 19.520 97 70-130ND
Dibromomethane ug/L 18.920 95 70-130ND
Dichlorodifluoromethane ug/L 19.320 96 70-130ND
Ethyl methacrylate ug/L 20.320 101 70-130ND
Ethylbenzene ug/L 20.920 105 70-130ND
Hexachloro-1,3-butadiene ug/L 20.220 101 70-130ND
Iodomethane ug/L 43.940 110 70-130ND
Isobutanol ug/L 1520 M1400380 70-130ND
Methacrylonitrile ug/L 206200 103 70-130ND
Methyl methacrylate ug/L 18.7J20 93 70-130ND
Methylene Chloride ug/L 22.120 110 70-130ND
Naphthalene ug/L 20.120 101 70-130ND
Propionitrile ug/L 209200 105 70-130ND
Styrene ug/L 19.920 100 70-130ND
Tetrachloroethene ug/L 20.320 102 70-130ND
Toluene ug/L 20.720 103 70-155ND
trans-1,2-Dichloroethene ug/L 21.720 108 70-130ND
trans-1,3-Dichloropropene ug/L 18.920 95 70-130ND
trans-1,4-Dichloro-2-butene ug/L 22.6J20 113 70-130ND
Trichloroethene ug/L 20.120 100 69-151ND
Trichlorofluoromethane ug/L 22.420 112 70-130ND
Vinyl acetate ug/L 34.3J40 86 70-130ND
Vinyl chloride ug/L 23.120 116 70-130ND
1,2-Dichloroethane-d4 (S)%103 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92286895001
1669163SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,1-Dichloropropene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 53 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92286895001
1669163SAMPLE DUPLICATE:
1,2,4-Trichlorobenzene ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichlorobenzene ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2,2-Dichloropropane ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acetonitrile ug/L ND 30ND
Acrolein ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Allyl chloride ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
Chloroprene ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Ethyl methacrylate ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Hexachloro-1,3-butadiene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Isobutanol ug/L ND 30ND
Methacrylonitrile ug/L ND 30ND
Methyl methacrylate ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Naphthalene ug/L ND 30ND
Propionitrile ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 54 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92286895001
1669163SAMPLE DUPLICATE:
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%102 4107
4-Bromofluorobenzene (S)%97 096
Toluene-d8 (S)%101 3104
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 55 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/40861
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples: 92286780001, 92286780002, 92286780003, 92286780004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1668611
Associated Lab Samples:92286780001, 92286780002, 92286780003, 92286780004
Matrix: Water
AnalyzedMDL
4,4'-DDD ug/L ND 0.10 02/20/16 03:540.050
4,4'-DDE ug/L ND 0.10 02/20/16 03:540.050
4,4'-DDT ug/L ND 0.10 02/20/16 03:540.050
Aldrin ug/L ND 0.050 02/20/16 03:540.050
alpha-BHC ug/L ND 0.050 02/20/16 03:540.050
beta-BHC ug/L ND 0.050 02/20/16 03:540.050
Chlordane (Technical)ug/L ND 0.50 02/20/16 03:540.20
delta-BHC ug/L ND 0.050 02/20/16 03:540.050
Dieldrin ug/L ND 0.075 02/20/16 03:540.050
Endosulfan I ug/L ND 0.10 02/20/16 03:540.050
Endosulfan II ug/L ND 0.10 02/20/16 03:540.050
Endosulfan sulfate ug/L ND 0.10 02/20/16 03:540.050
Endrin ug/L ND 0.10 02/20/16 03:540.050
Endrin aldehyde ug/L ND 0.10 02/20/16 03:540.050
gamma-BHC (Lindane)ug/L ND 0.050 02/20/16 03:540.050
Heptachlor ug/L ND 0.050 02/20/16 03:540.050
Heptachlor epoxide ug/L ND 0.075 02/20/16 03:540.050
Methoxychlor ug/L ND 1.0 02/20/16 03:540.15
Toxaphene ug/L ND 1.5 02/20/16 03:540.20
Decachlorobiphenyl (S)%79 20-130 02/20/16 03:54
Tetrachloro-m-xylene (S)%93 20-130 02/20/16 03:54
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1668612LABORATORY CONTROL SAMPLE:
LCSSpike
4,4'-DDD ug/L 0.21.25 87 20-150
4,4'-DDE ug/L 0.20.25 82 20-150
4,4'-DDT ug/L 0.22.25 89 20-150
Aldrin ug/L 0.17.25 69 20-150
alpha-BHC ug/L 0.22.25 89 20-150
beta-BHC ug/L 0.22.25 91 20-150
delta-BHC ug/L 0.24.25 96 20-150
Dieldrin ug/L 0.22.25 88 20-150
Endosulfan I ug/L 0.23.25 95 20-150
Endosulfan II ug/L 0.24.25 99 20-150
Endosulfan sulfate ug/L 0.26.25 104 20-150
Endrin ug/L 0.22.25 90 20-150
Endrin aldehyde ug/L 0.24.25 97 20-150
gamma-BHC (Lindane)ug/L 0.23.25 91 20-150
Heptachlor ug/L 0.20.25 80 20-150
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 56 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1668612LABORATORY CONTROL SAMPLE:
LCSSpike
Heptachlor epoxide ug/L 0.23.25 92 20-150
Methoxychlor ug/L 0.79J.74 106 20-150
Decachlorobiphenyl (S)%74 20-130
Tetrachloro-m-xylene (S)%91 20-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1668613MATRIX SPIKE SAMPLE:
MSSpike
Result
92286780003
4,4'-DDD ug/L 0.29.25 115 20-150ND
4,4'-DDE ug/L 0.26.25 105 20-150ND
4,4'-DDT ug/L 0.28.25 115 20-150ND
Aldrin ug/L 0.20.25 81 20-150ND
alpha-BHC ug/L 0.20.25 82 20-150ND
beta-BHC ug/L 0.33.25 134 20-150ND
delta-BHC ug/L 0.27.25 108 20-150ND
Dieldrin ug/L 0.30.25 120 20-150ND
Endosulfan I ug/L 0.33.25 132 20-150ND
Endosulfan II ug/L 0.32.25 131 20-150ND
Endosulfan sulfate ug/L 0.47 M1.25 188 20-150ND
Endrin ug/L 0.30.25 123 20-150ND
Endrin aldehyde ug/L 0.35.25 143 20-150ND
gamma-BHC (Lindane)ug/L 0.22.25 88 20-150ND
Heptachlor ug/L 0.21.25 85 20-150ND
Heptachlor epoxide ug/L 0.27.25 111 20-150ND
Methoxychlor ug/L 1.1.74 142 20-150ND
Decachlorobiphenyl (S)%108 20-130
Tetrachloro-m-xylene (S)%74 20-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92286780004
1668614SAMPLE DUPLICATE:
4,4'-DDD ug/L ND 30ND
4,4'-DDE ug/L ND 30ND
4,4'-DDT ug/L ND 30ND
Aldrin ug/L ND 30ND
alpha-BHC ug/L ND 30ND
beta-BHC ug/L ND 30ND
Chlordane (Technical)ug/L ND 30ND
delta-BHC ug/L ND 30ND
Dieldrin ug/L ND 30ND
Endosulfan I ug/L ND 30ND
Endosulfan II ug/L ND 30ND
Endosulfan sulfate ug/L ND 30ND
Endrin ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 57 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92286780004
1668614SAMPLE DUPLICATE:
Endrin aldehyde ug/L ND 30ND
gamma-BHC (Lindane)ug/L ND 30ND
Heptachlor ug/L ND 30ND
Heptachlor epoxide ug/L ND 30ND
Methoxychlor ug/L ND 30ND
Toxaphene ug/L ND 30ND
Decachlorobiphenyl (S)%32 3144
Tetrachloro-m-xylene (S)%77 1792
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 58 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/40846
EPA 3510
EPA 8082
8082 GCS PCB
Associated Lab Samples: 92286780001, 92286780002, 92286780003, 92286780004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1667835
Associated Lab Samples:92286780001, 92286780002, 92286780003, 92286780004
Matrix: Water
AnalyzedMDL
PCB-1016 (Aroclor 1016)ug/L ND 0.50 02/19/16 02:310.50
PCB-1221 (Aroclor 1221)ug/L ND 0.50 02/19/16 02:310.50
PCB-1232 (Aroclor 1232)ug/L ND 0.50 02/19/16 02:310.50
PCB-1242 (Aroclor 1242)ug/L ND 0.50 02/19/16 02:310.50
PCB-1248 (Aroclor 1248)ug/L ND 0.50 02/19/16 02:310.50
PCB-1254 (Aroclor 1254)ug/L ND 0.50 02/19/16 02:310.50
PCB-1260 (Aroclor 1260)ug/L ND 0.50 02/19/16 02:310.50
Decachlorobiphenyl (S)%51 10-132 02/19/16 02:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1667836LABORATORY CONTROL SAMPLE:
LCSSpike
PCB-1016 (Aroclor 1016)ug/L 4.05 81 50-150
PCB-1260 (Aroclor 1260)ug/L 4.45 88 50-150
Decachlorobiphenyl (S)%60 10-132
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1667837MATRIX SPIKE SAMPLE:
MSSpike
Result
92286780001
PCB-1016 (Aroclor 1016)ug/L 3.45 69 50-150ND
PCB-1260 (Aroclor 1260)ug/L 3.75 74 50-150ND
Decachlorobiphenyl (S)%45 10-132
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92286780003
1667838SAMPLE DUPLICATE:
PCB-1016 (Aroclor 1016)ug/L ND 30ND
PCB-1221 (Aroclor 1221)ug/L ND 30ND
PCB-1232 (Aroclor 1232)ug/L ND 30ND
PCB-1242 (Aroclor 1242)ug/L ND 30ND
PCB-1248 (Aroclor 1248)ug/L ND 30ND
PCB-1254 (Aroclor 1254)ug/L ND 30ND
PCB-1260 (Aroclor 1260)ug/L ND 30ND
Decachlorobiphenyl (S)%75 377
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 59 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/26669
EPA 8151
EPA 8151
8151A GCS Herbicides
Associated Lab Samples: 92286780001, 92286780002, 92286780003, 92286780004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1485629
Associated Lab Samples:92286780001, 92286780002, 92286780003, 92286780004
Matrix: Water
AnalyzedMDL
2,4,5-T ug/L ND 0.19 02/22/16 21:320.042
2,4,5-TP (Silvex)ug/L ND 0.19 02/22/16 21:320.049
2,4-D ug/L ND 0.94 02/22/16 21:320.22
2,4-DB ug/L ND 1.9 02/22/16 21:320.51
Bentazon ug/L ND 0.094 02/22/16 21:320.016
Dalapon ug/L ND 0.91 02/22/16 21:320.43
Dicamba ug/L ND 0.094 02/22/16 21:320.030
Dichlorprop ug/L ND 0.65 02/22/16 21:320.19
Dinoseb ug/L ND 0.19 02/22/16 21:320.057
Pentachlorophenol ug/L ND 0.028 02/22/16 21:320.017
Picloram ug/L ND 0.094 02/22/16 21:320.019
2,4-DCAA (S)%77 36-130 02/22/16 21:32
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1485630LABORATORY CONTROL SAMPLE:
LCSSpike
2,4,5-T ug/L 0.951.2 79 40-130
2,4,5-TP (Silvex)ug/L 1.01.2 84 58-130
2,4-D ug/L 4.86 80 42-134
2,4-DB ug/L 9.412 78 65-130
Bentazon ug/L 0.48.6 80 52-130
Dalapon ug/L 4.66 77 22-130
Dicamba ug/L 0.47.6 79 42-130
Dichlorprop ug/L 3.64.2 85 70-130
Dinoseb ug/L 0.581.2 48 10-157
Pentachlorophenol ug/L 0.15.18 86 62-154
Picloram ug/L 0.32.6 53 10-145
2,4-DCAA (S)%77 36-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1486172MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286789001
1486173
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2,4,5-T ug/L 2.7 91 40-13090 2 402.7ND 2.4 2.4
2,4,5-TP (Silvex)ug/L 2.7 93 58-13092 1 402.7ND 2.5 2.4
2,4-D ug/L 13.3 91 42-13488 3 4013.3ND 12.1 11.8
2,4-DB ug/L 26.7 88 65-13086 2 4026.7ND 23.4 23.0
Bentazon ug/L 1.3 82 52-13090 9 401.3ND 1.1 1.2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 60 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1486172MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286789001
1486173
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Dalapon ug/L 13.3 97 22-13097 0 4013.3ND 12.9 12.9
Dicamba ug/L 1.3 86 42-13086 0 401.3ND 1.1 1.1
Dichlorprop ug/L 9.3 92 70-13091 1 409.3ND 8.6 8.5
Dinoseb ug/L 2.7 62 10-15760 2 402.7ND 1.6 1.6
Pentachlorophenol ug/L .4 91 62-15491 0 40.4ND 0.36 0.36
Picloram ug/L 1.3 75 10-14572 4 401.3ND 1.0 0.95
2,4-DCAA (S)%85 36-13084 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 61 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/40867
EPA 3510
EPA 8270
8270 Water MSSV
Associated Lab Samples: 92286780001, 92286780002, 92286780003, 92286780004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1668690
Associated Lab Samples:92286780001, 92286780002, 92286780003, 92286780004
Matrix: Water
AnalyzedMDL
1,2,4,5-Tetrachlorobenzene ug/L ND 10.0 02/23/16 16:261.7
1,3,5-Trinitrobenzene ug/L ND 10.0 02/23/16 16:261.1
1,3-Dinitrobenzene ug/L ND 20.0 02/23/16 16:261.5
1,4-Naphthoquinone ug/L ND 10.0 02/23/16 16:261.8
1-Naphthalenamine ug/L ND 10.0 02/23/16 16:260.96
2,3,4,6-Tetrachlorophenol ug/L ND 10.0 02/23/16 16:262.3
2,4,5-Trichlorophenol ug/L ND 10.0 02/23/16 16:262.2
2,4,6-Trichlorophenol ug/L ND 10.0 02/23/16 16:261.9
2,4-Dichlorophenol ug/L ND 10.0 02/23/16 16:261.7
2,4-Dimethylphenol ug/L ND 10.0 02/23/16 16:262.2
2,4-Dinitrophenol ug/L ND 50.0 02/23/16 16:266.5
2,4-Dinitrotoluene ug/L ND 10.0 02/23/16 16:261.2
2,6-Dichlorophenol ug/L ND 10.0 02/23/16 16:261.8
2,6-Dinitrotoluene ug/L ND 10.0 02/23/16 16:261.7
2-Acetylaminofluorene ug/L ND 20.0 02/23/16 16:260.84
2-Chloronaphthalene ug/L ND 10.0 02/23/16 16:262.2
2-Chlorophenol ug/L ND 10.0 02/23/16 16:261.5
2-Methylnaphthalene ug/L ND 10.0 02/23/16 16:260.28
2-Methylphenol(o-Cresol)ug/L ND 10.0 02/23/16 16:261.7
2-Naphthalenamine ug/L ND 10.0 02/23/16 16:260.98
2-Nitroaniline ug/L ND 50.0 02/23/16 16:262.8
2-Nitrophenol ug/L ND 10.0 02/23/16 16:261.7
3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 02/23/16 16:261.7
3,3'-Dichlorobenzidine ug/L ND 20.0 02/23/16 16:261.4
3,3'-Dimethylbenzidine ug/L ND 10.0 02/23/16 16:262.1
3-Methylcholanthrene ug/L ND 10.0 02/23/16 16:260.82
3-Nitroaniline ug/L ND 50.0 02/23/16 16:262.4
4,6-Dinitro-2-methylphenol ug/L ND 50.0 02/23/16 16:261.7
4-Aminobiphenyl ug/L ND 20.0 02/23/16 16:260.92
4-Bromophenylphenyl ether ug/L ND 10.0 02/23/16 16:261.3
4-Chloro-3-methylphenol ug/L ND 20.0 02/23/16 16:264.2
4-Chloroaniline ug/L ND 20.0 02/23/16 16:263.4
4-Chlorophenylphenyl ether ug/L ND 10.0 02/23/16 16:262.1
4-Nitroaniline ug/L ND 20.0 02/23/16 16:262.5
4-Nitrophenol ug/L ND 50.0 02/23/16 16:265.8
5-Nitro-o-toluidine ug/L ND 10.0 02/23/16 16:261.2
7,12-Dimethylbenz(a)anthracene ug/L ND 10.0 02/23/16 16:260.77
Acenaphthene ug/L ND 10.0 02/23/16 16:260.25
Acenaphthylene ug/L ND 10.0 02/23/16 16:260.21
Acetophenone ug/L ND 10.0 02/23/16 16:262.0
Anthracene ug/L ND 10.0 02/23/16 16:260.14
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
Page 62 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1668690
Associated Lab Samples:92286780001, 92286780002, 92286780003, 92286780004
Matrix: Water
AnalyzedMDL
Benzo(a)anthracene ug/L ND 10.0 02/23/16 16:260.33
Benzo(a)pyrene ug/L ND 10.0 02/23/16 16:260.30
Benzo(b)fluoranthene ug/L ND 10.0 02/23/16 16:260.28
Benzo(g,h,i)perylene ug/L ND 10.0 02/23/16 16:260.38
Benzo(k)fluoranthene ug/L ND 10.0 02/23/16 16:260.43
Benzyl alcohol ug/L ND 20.0 02/23/16 16:263.4
bis(2-Chloroethoxy)methane ug/L ND 10.0 02/23/16 16:261.7
bis(2-Chloroethyl) ether ug/L ND 10.0 02/23/16 16:261.5
bis(2-Chloroisopropyl) ether ug/L ND 10.0 02/23/16 16:261.6
bis(2-Ethylhexyl)phthalate ug/L ND 15.0 02/23/16 16:260.85
Butylbenzylphthalate ug/L ND 10.0 02/23/16 16:260.75
Chlorobenzilate ug/L ND 10.0 02/23/16 16:260.72
Chrysene ug/L ND 10.0 02/23/16 16:260.21
Di-n-butylphthalate ug/L ND 10.0 02/23/16 16:261.1
Di-n-octylphthalate ug/L ND 10.0 02/23/16 16:260.86
Diallate ug/L ND 10.0 02/23/16 16:261.3
Dibenz(a,h)anthracene ug/L ND 10.0 02/23/16 16:260.55
Dibenzofuran ug/L ND 10.0 02/23/16 16:261.8
Diethylphthalate ug/L ND 6000 02/23/16 16:261.3
Dimethoate ug/L ND 20.0 02/23/16 16:260.92
Dimethylphthalate ug/L ND 10.0 02/23/16 16:261.5
Diphenylamine ug/L ND 10.0 02/23/16 16:261.3
Disulfoton ug/L ND 10.0 02/23/16 16:261.4
Ethyl methanesulfonate ug/L ND 20.0 02/23/16 16:261.8
Famphur ug/L ND 20.0 02/23/16 16:261.7
Fluoranthene ug/L ND 10.0 02/23/16 16:260.21
Fluorene ug/L ND 10.0 02/23/16 16:260.21
Hexachlorobenzene ug/L ND 10.0 02/23/16 16:261.1
Hexachlorocyclopentadiene ug/L ND 10.0 02/23/16 16:261.8
Hexachloroethane ug/L ND 10.0 02/23/16 16:261.5
Hexachloropropene ug/L ND 10.0 02/23/16 16:261.6
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 02/23/16 16:260.29
Isodrin ug/L ND 20.0 02/23/16 16:262.0
Isophorone ug/L ND 10.0 02/23/16 16:261.8
Isosafrole ug/L ND 10.0 02/23/16 16:261.8
Kepone ug/L ND 20.0 02/23/16 16:263.1
Methapyrilene ug/L ND 100 02/23/16 16:262.7
Methyl methanesulfonate ug/L ND 10.0 02/23/16 16:261.3
Methyl parathion ug/L ND 10.0 02/23/16 16:261.1
N-Nitroso-di-n-butylamine ug/L ND 10.0 02/23/16 16:262.2
N-Nitroso-di-n-propylamine ug/L ND 10.0 02/23/16 16:262.1
N-Nitrosodiethylamine ug/L ND 20.0 02/23/16 16:261.8
N-Nitrosodimethylamine ug/L ND 10.0 02/23/16 16:261.3
N-Nitrosodiphenylamine ug/L ND 10.0 02/23/16 16:261.3
N-Nitrosomethylethylamine ug/L ND 10.0 02/23/16 16:261.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 63 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1668690
Associated Lab Samples:92286780001, 92286780002, 92286780003, 92286780004
Matrix: Water
AnalyzedMDL
N-Nitrosopiperidine ug/L ND 20.0 02/23/16 16:261.9
N-Nitrosopyrrolidine ug/L ND 10.0 02/23/16 16:262.5
Nitrobenzene ug/L ND 10.0 02/23/16 16:261.7
O,O,O-Triethylphosphorothioate ug/L ND 10.0 02/23/16 16:261.8
O-Toluidine ug/L ND 10.0 02/23/16 16:261.6
P-Dimethylaminoazobenzene ug/L ND 10.0 02/23/16 16:260.35
p-Phenylenediamine ug/L ND 10.0 02/23/16 16:260.96
Parathion (Ethyl parathion)ug/L ND 10.0 02/23/16 16:261.1
Pentachlorobenzene ug/L ND 10.0 02/23/16 16:262.0
Pentachloronitrobenzene ug/L ND 20.0 02/23/16 16:261.0
Pentachlorophenol ug/L ND 25.0 02/23/16 16:262.3
Phenacetin ug/L ND 20.0 02/23/16 16:260.97
Phenanthrene ug/L ND 10.0 02/23/16 16:260.22
Phenol ug/L ND 10.0 02/23/16 16:261.7
Phorate ug/L ND 10.0 02/23/16 16:261.1
Pronamide ug/L ND 10.0 02/23/16 16:260.97
Pyrene ug/L ND 10.0 02/23/16 16:260.19
Safrole ug/L ND 10.0 02/23/16 16:261.5
Thionazin ug/L ND 20.0 02/23/16 16:261.2
2,4,6-Tribromophenol (S)%47 27-110 02/23/16 16:26
2-Fluorobiphenyl (S)%48 27-110 02/23/16 16:26
2-Fluorophenol (S)%25 12-110 02/23/16 16:26
Nitrobenzene-d5 (S)%40 21-110 02/23/16 16:26
Phenol-d6 (S)%15 10-110 02/23/16 16:26
Terphenyl-d14 (S)%64 31-107 02/23/16 16:26
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1668691LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4,5-Tetrachlorobenzene ug/L 36.550 73 16-129
1,3,5-Trinitrobenzene ug/L 35.150 70 55-125
1,3-Dinitrobenzene ug/L 42.150 84 30-122
1,4-Naphthoquinone ug/L 32.450 65 31-120
1-Naphthalenamine ug/L 33.550 67 37-126
2,3,4,6-Tetrachlorophenol ug/L 84.550 169 54-276
2,4,5-Trichlorophenol ug/L 39.150 78 43-113
2,4,6-Trichlorophenol ug/L 40.450 81 42-120
2,4-Dichlorophenol ug/L 31.250 62 30-120
2,4-Dimethylphenol ug/L 29.050 58 29-111
2,4-Dinitrophenol ug/L 188250 75 19-132
2,4-Dinitrotoluene ug/L 45.250 90 58-128
2,6-Dichlorophenol ug/L 31.450 63 54-128
2,6-Dinitrotoluene ug/L 43.850 88 54-129
2-Acetylaminofluorene ug/L 43.750 87 81-160
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 64 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1668691LABORATORY CONTROL SAMPLE:
LCSSpike
2-Chloronaphthalene ug/L 38.650 77 43-117
2-Chlorophenol ug/L 28.850 58 37-120
2-Methylnaphthalene ug/L 28.050 56 33-120
2-Methylphenol(o-Cresol)ug/L 22.550 45 31-120
2-Naphthalenamine ug/L 38.650 77 41-136
2-Nitroaniline ug/L 53.3100 53 48-121
2-Nitrophenol ug/L 32.450 65 25-116
3&4-Methylphenol(m&p Cresol)ug/L 18.250 36 23-120
3,3'-Dichlorobenzidine ug/L 91.6250 37 10-154
3,3'-Dimethylbenzidine ug/L 64.9100 65 10-157
3-Methylcholanthrene ug/L 46.650 93 65-130
3-Nitroaniline ug/L 78.1100 78 43-115
4,6-Dinitro-2-methylphenol ug/L 78.2100 78 44-124
4-Aminobiphenyl ug/L 31.650 63 21-125
4-Bromophenylphenyl ether ug/L 40.250 80 34-113
4-Chloro-3-methylphenol ug/L 62.7100 63 31-110
4-Chloroaniline ug/L 55.9100 56 20-120
4-Chlorophenylphenyl ether ug/L 41.850 84 34-116
4-Nitroaniline ug/L 85.1100 85 46-128
4-Nitrophenol ug/L 84.8250 34 11-120
5-Nitro-o-toluidine ug/L 45.350 91 78-160
7,12-Dimethylbenz(a)anthracene ug/L 41.050 82 47-124
Acenaphthene ug/L 33.550 67 48-114
Acenaphthylene ug/L 34.650 69 48-112
Acetophenone ug/L 27.950 56 24-120
Anthracene ug/L 36.050 72 57-118
Benzo(a)anthracene ug/L 41.550 83 56-121
Benzo(a)pyrene ug/L 40.050 80 55-127
Benzo(b)fluoranthene ug/L 38.150 76 53-128
Benzo(g,h,i)perylene ug/L 41.650 83 54-125
Benzo(k)fluoranthene ug/L 35.950 72 51-123
Benzyl alcohol ug/L 44.6100 45 27-120
bis(2-Chloroethoxy)methane ug/L 24.750 49 32-120
bis(2-Chloroethyl) ether ug/L 26.750 53 33-111
bis(2-Chloroisopropyl) ether ug/L 14.750 29 15-120
bis(2-Ethylhexyl)phthalate ug/L 41.950 84 50-145
Butylbenzylphthalate ug/L 43.350 87 54-138
Chlorobenzilate ug/L 41.350 83 65-132
Chrysene ug/L 40.950 82 58-127
Di-n-butylphthalate ug/L 41.750 83 56-125
Di-n-octylphthalate ug/L 39.550 79 50-134
Diallate ug/L 28.550 57 47-123
Dibenz(a,h)anthracene ug/L 42.250 84 53-129
Dibenzofuran ug/L 40.550 81 45-120
Diethylphthalate ug/L 41.8J50 84 53-120
Dimethoate ug/L 31.050 62 57-139
Dimethylphthalate ug/L 40.250 80 55-116
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 65 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1668691LABORATORY CONTROL SAMPLE:
LCSSpike
Diphenylamine ug/L 33.650 67 42-120
Disulfoton ug/L 29.450 59 49-156
Ethyl methanesulfonate ug/L 24.350 49 43-120
Famphur ug/L 61.6100 62 40-160
Fluoranthene ug/L 41.550 83 57-125
Fluorene ug/L 40.150 80 53-118
Hexachlorobenzene ug/L 40.550 81 49-116
Hexachlorocyclopentadiene ug/L 30.250 60 26-158
Hexachloroethane ug/L 27.750 55 30-114
Hexachloropropene ug/L 28.150 56 13-137
Indeno(1,2,3-cd)pyrene ug/L 47.050 94 55-128
Isodrin ug/L 42.650 85 68-129
Isophorone ug/L 24.350 49 31-118
Isosafrole ug/L 40.050 80 48-107
Kepone ug/L ND L01003 10-124
Methapyrilene ug/L 38.4J50 77 40-160
Methyl methanesulfonate ug/L 20.050 40 25-114
Methyl parathion ug/L 37.550 75 58-137
N-Nitroso-di-n-butylamine ug/L 22.550 45 36-115
N-Nitroso-di-n-propylamine ug/L 23.850 48 32-119
N-Nitrosodiethylamine ug/L 29.750 59 47-115
N-Nitrosodimethylamine ug/L 15.550 31 13-120
N-Nitrosodiphenylamine ug/L 33.650 67 43-120
N-Nitrosomethylethylamine ug/L 27.350 55 39-120
N-Nitrosopiperidine ug/L 32.150 64 43-113
N-Nitrosopyrrolidine ug/L 26.750 53 32-110
Nitrobenzene ug/L 23.750 47 33-110
O,O,O-Triethylphosphorothioate ug/L 34.350 69 51-127
O-Toluidine ug/L 26.850 54 27-120
P-Dimethylaminoazobenzene ug/L 19.7100 20 10-120
p-Phenylenediamine ug/L 39.950 80 72-143
Parathion (Ethyl parathion)ug/L 36.950 74 56-140
Pentachlorobenzene ug/L 42.650 85 30-137
Pentachloronitrobenzene ug/L 48.550 97 70-124
Pentachlorophenol ug/L 79.9250 32 10-137
Phenacetin ug/L 37.350 75 60-130
Phenanthrene ug/L 35.450 71 57-117
Phenol ug/L 12.550 25 10-120
Phorate ug/L 27.950 56 55-126
Pronamide ug/L 43.450 87 75-124
Pyrene ug/L 34.550 69 55-122
Safrole ug/L 30.550 61 41-120
Thionazin ug/L 39.450 79 63-137
2,4,6-Tribromophenol (S)%96 27-110
2-Fluorobiphenyl (S)%67 27-110
2-Fluorophenol (S)%31 12-110
Nitrobenzene-d5 (S)%50 21-110
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 66 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1668691LABORATORY CONTROL SAMPLE:
LCSSpike
Phenol-d6 (S)%19 10-110
Terphenyl-d14 (S)%82 31-107
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1668692MATRIX SPIKE SAMPLE:
MSSpike
Result
92286620001
1,2,4,5-Tetrachlorobenzene ug/L 37.550 75 50-150ND
1,3,5-Trinitrobenzene ug/L 38.350 77 50-150ND
1,3-Dinitrobenzene ug/L 49.350 99 50-150ND
1,4-Naphthoquinone ug/L 38.150 76 50-150ND
1-Naphthalenamine ug/L 37.650 75 50-150ND
2,3,4,6-Tetrachlorophenol ug/L 98.9 M150198 50-150ND
2,4,5-Trichlorophenol ug/L 44.050 88 19-105ND
2,4,6-Trichlorophenol ug/L 44.250 88 13-108ND
2,4-Dichlorophenol ug/L 37.450 75 29-111ND
2,4-Dimethylphenol ug/L 32.950 66 21-103ND
2,4-Dinitrophenol ug/L 222250 89 10-109ND
2,4-Dinitrotoluene ug/L 52.150 104 27-104ND
2,6-Dichlorophenol ug/L 35.650 71 50-150ND
2,6-Dinitrotoluene ug/L 51.3 M150103 28-101ND
2-Acetylaminofluorene ug/L 53.150 106 50-150ND
2-Chloronaphthalene ug/L 41.150 82 14-102ND
2-Chlorophenol ug/L 31.450 63 16-110ND
2-Methylnaphthalene ug/L 34.450 69 13-110ND
2-Methylphenol(o-Cresol)ug/L 25.150 50 19-110ND
2-Naphthalenamine ug/L 43.650 87 50-150ND
2-Nitroaniline ug/L 61.4100 61 26-103ND
2-Nitrophenol ug/L 36.550 73 20-110ND
3&4-Methylphenol(m&p Cresol)ug/L 20.350 41 20-110ND
3,3'-Dichlorobenzidine ug/L 103250 41 25-112ND
3,3'-Dimethylbenzidine ug/L 72.0100 72 50-150ND
3-Methylcholanthrene ug/L 54.550 109 50-150ND
3-Nitroaniline ug/L 88.9100 89 29-110ND
4,6-Dinitro-2-methylphenol ug/L 92.5100 92 10-117ND
4-Aminobiphenyl ug/L 35.150 70 50-150ND
4-Bromophenylphenyl ether ug/L 45.450 91 20-105ND
4-Chloro-3-methylphenol ug/L 75.9100 76 22-110ND
4-Chloroaniline ug/L 66.5100 67 20-100ND
4-Chlorophenylphenyl ether ug/L 46.650 93 19-102ND
4-Nitroaniline ug/L 91.2100 91 29-110ND
4-Nitrophenol ug/L 96.6250 39 10-110ND
5-Nitro-o-toluidine ug/L 52.450 105 50-150ND
7,12-Dimethylbenz(a)anthracene ug/L 47.750 95 50-150ND
Acenaphthene ug/L 37.450 75 17-100ND
Acenaphthylene ug/L 38.750 77 21-100ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 67 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1668692MATRIX SPIKE SAMPLE:
MSSpike
Result
92286620001
Acetophenone ug/L 31.750 63 50-150ND
Anthracene ug/L 40.950 82 24-109ND
Benzo(a)anthracene ug/L 47.250 94 22-117ND
Benzo(a)pyrene ug/L 45.450 91 23-104ND
Benzo(b)fluoranthene ug/L 45.050 90 23-103ND
Benzo(g,h,i)perylene ug/L 45.350 91 18-111ND
Benzo(k)fluoranthene ug/L 40.950 82 22-113ND
Benzyl alcohol ug/L 49.0100 49 19-101ND
bis(2-Chloroethoxy)methane ug/L 28.750 57 22-110ND
bis(2-Chloroethyl) ether ug/L 29.750 59 16-110ND
bis(2-Chloroisopropyl) ether ug/L 16.550 33 14-110ND
bis(2-Ethylhexyl)phthalate ug/L 49.450 99 23-102ND
Butylbenzylphthalate ug/L 51.150 102 25-110ND
Chlorobenzilate ug/L 49.150 98 50-150ND
Chrysene ug/L 47.050 94 23-115ND
Di-n-butylphthalate ug/L 48.150 96 26-110ND
Di-n-octylphthalate ug/L 47.050 94 22-110ND
Diallate ug/L 33.150 66 50-150ND
Dibenz(a,h)anthracene ug/L 46.750 93 21-112ND
Dibenzofuran ug/L 43.750 87 19-102ND
Diethylphthalate ug/L 47.5J50 95 29-110ND
Dimethoate ug/L 35.950 72 50-150ND
Dimethylphthalate ug/L 46.150 92 27-110ND
Diphenylamine ug/L 38.150 76 50-150ND
Disulfoton ug/L 33.150 66 50-150ND
Ethyl methanesulfonate ug/L 26.950 54 50-150ND
Famphur ug/L 46.7 M110047 50-150ND
Fluoranthene ug/L 45.250 90 23-112ND
Fluorene ug/L 44.850 90 22-104ND
Hexachlorobenzene ug/L 47.050 94 21-116ND
Hexachlorocyclopentadiene ug/L 32.250 64 10-110ND
Hexachloroethane ug/L 30.350 61 10-110ND
Hexachloropropene ug/L 32.850 66 50-150ND
Indeno(1,2,3-cd)pyrene ug/L 52.450 105 20-113ND
Isodrin ug/L 47.450 95 50-150ND
Isophorone ug/L 27.550 55 50-150ND
Isosafrole ug/L 42.950 86 50-150ND
Kepone ug/L 4.8J M01005 50-150ND
Methapyrilene ug/L 44.5J50 89 50-150ND
Methyl methanesulfonate ug/L 22.8 M15046 50-150ND
Methyl parathion ug/L 42.750 85 50-150ND
N-Nitroso-di-n-butylamine ug/L 26.950 54 50-150ND
N-Nitroso-di-n-propylamine ug/L 26.450 53 21-105ND
N-Nitrosodiethylamine ug/L 32.850 66 50-150ND
N-Nitrosodimethylamine ug/L 18.150 36 10-110ND
N-Nitrosodiphenylamine ug/L 38.150 76 23-107ND
N-Nitrosomethylethylamine ug/L 29.350 59 50-150ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 68 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1668692MATRIX SPIKE SAMPLE:
MSSpike
Result
92286620001
N-Nitrosopiperidine ug/L 38.050 76 50-150ND
N-Nitrosopyrrolidine ug/L 31.450 63 50-150ND
Nitrobenzene ug/L 26.150 52 20-110ND
O,O,O-Triethylphosphorothioate ug/L 37.650 75 50-150ND
O-Toluidine ug/L 30.350 61 50-150ND
P-Dimethylaminoazobenzene ug/L 24.5 M110025 50-150ND
p-Phenylenediamine ug/L 51.750 103 50-150ND
Parathion (Ethyl parathion)ug/L 42.750 85 50-150ND
Pentachlorobenzene ug/L 45.650 91 50-150ND
Pentachloronitrobenzene ug/L 55.450 111 50-150ND
Pentachlorophenol ug/L 96.3250 39 10-118ND
Phenacetin ug/L 41.650 83 50-150ND
Phenanthrene ug/L 40.050 80 24-106ND
Phenol ug/L 13.350 27 12-110ND
Phorate ug/L 34.250 68 50-150ND
Pronamide ug/L 48.750 97 50-150ND
Pyrene ug/L 40.650 81 24-114ND
Safrole ug/L 35.650 71 50-150ND
Thionazin ug/L 45.250 90 50-150ND
2,4,6-Tribromophenol (S)%110 27-110
2-Fluorobiphenyl (S)%72 27-110
2-Fluorophenol (S)%34 12-110
Nitrobenzene-d5 (S)%58 21-110
Phenol-d6 (S)%21 10-110
Terphenyl-d14 (S)%94 31-107
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92286780004
1668693SAMPLE DUPLICATE:
1,2,4,5-Tetrachlorobenzene ug/L ND 30ND
1,3,5-Trinitrobenzene ug/L ND 30ND
1,3-Dinitrobenzene ug/L ND 30ND
1,4-Naphthoquinone ug/L ND 30ND
1-Naphthalenamine ug/L ND 30ND
2,3,4,6-Tetrachlorophenol ug/L ND 30ND
2,4,5-Trichlorophenol ug/L ND 30ND
2,4,6-Trichlorophenol ug/L ND 30ND
2,4-Dichlorophenol ug/L ND 30ND
2,4-Dimethylphenol ug/L ND 30ND
2,4-Dinitrophenol ug/L ND 30ND
2,4-Dinitrotoluene ug/L ND 30ND
2,6-Dichlorophenol ug/L ND 30ND
2,6-Dinitrotoluene ug/L ND 30ND
2-Acetylaminofluorene ug/L ND 30ND
2-Chloronaphthalene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 10:22 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 69 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92286780004
1668693SAMPLE DUPLICATE:
2-Chlorophenol ug/L ND 30ND
2-Methylnaphthalene ug/L ND 30ND
2-Methylphenol(o-Cresol)ug/L ND 30ND
2-Naphthalenamine ug/L ND 30ND
2-Nitroaniline ug/L ND 30ND
2-Nitrophenol ug/L ND 30ND
3&4-Methylphenol(m&p Cresol)ug/L ND 30ND
3,3'-Dichlorobenzidine ug/L ND 30ND
3,3'-Dimethylbenzidine ug/L ND 30ND
3-Methylcholanthrene ug/L ND 30ND
3-Nitroaniline ug/L ND 30ND
4,6-Dinitro-2-methylphenol ug/L ND 30ND
4-Aminobiphenyl ug/L ND 30ND
4-Bromophenylphenyl ether ug/L ND 30ND
4-Chloro-3-methylphenol ug/L ND 30ND
4-Chloroaniline ug/L ND 30ND
4-Chlorophenylphenyl ether ug/L ND 30ND
4-Nitroaniline ug/L ND 30ND
4-Nitrophenol ug/L ND 30ND
5-Nitro-o-toluidine ug/L NDND
7,12-Dimethylbenz(a)anthracene ug/L ND 30ND
Acenaphthene ug/L ND 30ND
Acenaphthylene ug/L ND 30ND
Acetophenone ug/L ND 30ND
Anthracene ug/L ND 30ND
Benzo(a)anthracene ug/L ND 30ND
Benzo(a)pyrene ug/L ND 30ND
Benzo(b)fluoranthene ug/L ND 30ND
Benzo(g,h,i)perylene ug/L ND 30ND
Benzo(k)fluoranthene ug/L ND 30ND
Benzyl alcohol ug/L ND 30ND
bis(2-Chloroethoxy)methane ug/L ND 30ND
bis(2-Chloroethyl) ether ug/L ND 30ND
bis(2-Chloroisopropyl) ether ug/L ND 30ND
bis(2-Ethylhexyl)phthalate ug/L ND 30ND
Butylbenzylphthalate ug/L ND 30ND
Chlorobenzilate ug/L ND 30ND
Chrysene ug/L ND 30ND
Di-n-butylphthalate ug/L ND 30ND
Di-n-octylphthalate ug/L ND 30ND
Diallate ug/L ND 30ND
Dibenz(a,h)anthracene ug/L ND 30ND
Dibenzofuran ug/L ND 30ND
Diethylphthalate ug/L ND 30ND
Dimethoate ug/L ND 30ND
Dimethylphthalate ug/L ND 30ND
Diphenylamine ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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Page 70 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92286780004
1668693SAMPLE DUPLICATE:
Disulfoton ug/L ND 30ND
Ethyl methanesulfonate ug/L ND 30ND
Famphur ug/L ND 30ND
Fluoranthene ug/L ND 30ND
Fluorene ug/L ND 30ND
Hexachlorobenzene ug/L ND 30ND
Hexachlorocyclopentadiene ug/L ND 30ND
Hexachloroethane ug/L ND 30ND
Hexachloropropene ug/L ND 30ND
Indeno(1,2,3-cd)pyrene ug/L ND 30ND
Isodrin ug/L ND 30ND
Isophorone ug/L ND 30ND
Isosafrole ug/L ND 30ND
Kepone ug/L ND 30ND
Methapyrilene ug/L ND 30ND
Methyl methanesulfonate ug/L ND 30ND
Methyl parathion ug/L ND 30ND
N-Nitroso-di-n-butylamine ug/L ND 30ND
N-Nitroso-di-n-propylamine ug/L ND 30ND
N-Nitrosodiethylamine ug/L ND 30ND
N-Nitrosodimethylamine ug/L ND 30ND
N-Nitrosodiphenylamine ug/L ND 30ND
N-Nitrosomethylethylamine ug/L ND 30ND
N-Nitrosopiperidine ug/L ND 30ND
N-Nitrosopyrrolidine ug/L ND 30ND
Nitrobenzene ug/L ND 30ND
O,O,O-Triethylphosphorothioate ug/L ND 30ND
O-Toluidine ug/L ND 30ND
P-Dimethylaminoazobenzene ug/L ND 30ND
p-Phenylenediamine ug/L ND 30ND
Parathion (Ethyl parathion)ug/L ND 30ND
Pentachlorobenzene ug/L ND 30ND
Pentachloronitrobenzene ug/L ND 30ND
Pentachlorophenol ug/L ND 30ND
Phenacetin ug/L ND 30ND
Phenanthrene ug/L ND 30ND
Phenol ug/L ND 30ND
Phorate ug/L ND 30ND
Pronamide ug/L ND 30ND
Pyrene ug/L ND 30ND
Safrole ug/L ND 30ND
Thionazin ug/L ND 30ND
2,4,6-Tribromophenol (S)%84 580
2-Fluorobiphenyl (S)%77 1368
2-Fluorophenol (S)%36 1032
Nitrobenzene-d5 (S)%62 956
Phenol-d6 (S)%22 1419
REPORT OF LABORATORY ANALYSIS
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Page 71 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92286780004
1668693SAMPLE DUPLICATE:
Terphenyl-d14 (S)%92 496
REPORT OF LABORATORY ANALYSIS
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Page 72 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/43119
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples: 92286780001, 92286780002, 92286780003, 92286780004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1668592
Associated Lab Samples:92286780001, 92286780002, 92286780003, 92286780004
Matrix: Water
AnalyzedMDL
Sulfide ug/L ND 1000 02/18/16 13:30100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1668593LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 500J500 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1668594MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286538001
1668595
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L M15007990-11079 0 10500ND395J 395J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1668596MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286780001
1668597
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L M15008290-11082 0 10500ND411J 411J
REPORT OF LABORATORY ANALYSIS
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Page 73 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/26491
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples: 92286780001, 92286780002, 92286780003, 92286780004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1669553
Associated Lab Samples:92286780001, 92286780002, 92286780003, 92286780004
Matrix: Water
AnalyzedMDL
Cyanide ug/L ND 10.0 02/19/16 17:294.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1669554LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 108100 108 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1669555MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286236001
1669556
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L M1100675-125-25 101000.027
mg/L 32.8 ND
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1669557MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286780001
1669558
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 99 75-12599 0 10100ND101 101
REPORT OF LABORATORY ANALYSIS
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Page 74 of 79
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associatedsamples may be biased low.L2
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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Page 75 of 79
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92286780001 OEXT/40861 GCSV/241563902-MW1R EPA 3510 EPA 8081
92286780002 OEXT/40861 GCSV/241563902-MW2R EPA 3510 EPA 8081
92286780003 OEXT/40861 GCSV/241563902-MW3R EPA 3510 EPA 8081
92286780004 OEXT/40861 GCSV/241563902-Field Blank EPA 3510 EPA 8081
92286780001 OEXT/40846 GCSV/241353902-MW1R EPA 3510 EPA 8082
92286780002 OEXT/40846 GCSV/241353902-MW2R EPA 3510 EPA 8082
92286780003 OEXT/40846 GCSV/241353902-MW3R EPA 3510 EPA 8082
92286780004 OEXT/40846 GCSV/241353902-Field Blank EPA 3510 EPA 8082
92286780001 OEXT/26669 GCSV/173533902-MW1R EPA 8151 EPA 8151
92286780002 OEXT/26669 GCSV/173533902-MW2R EPA 8151 EPA 8151
92286780003 OEXT/26669 GCSV/173533902-MW3R EPA 8151 EPA 8151
92286780004 OEXT/26669 GCSV/173533902-Field Blank EPA 8151 EPA 8151
92286780001 MPRP/20737 ICP/186903902-MW1R EPA 3010A EPA 6010
92286780002 MPRP/20737 ICP/186903902-MW2R EPA 3010A EPA 6010
92286780003 MPRP/20737 ICP/186903902-MW3R EPA 3010A EPA 6010
92286780004 MPRP/20737 ICP/186903902-Field Blank EPA 3010A EPA 6010
92286780005 MPRP/20737 ICP/186903902-MW4 EPA 3010A EPA 6010
92286780006 MPRP/20737 ICP/186903902-MW5 EPA 3010A EPA 6010
92286780007 MPRP/20737 ICP/186903902-MW6 EPA 3010A EPA 6010
92286780008 MPRP/20737 ICP/186903902-SW1 EPA 3010A EPA 6010
92286780009 MPRP/20737 ICP/186903902-SW2 EPA 3010A EPA 6010
92286780001 MERP/8979 MERC/86313902-MW1R EPA 7470 EPA 7470
92286780002 MERP/8979 MERC/86313902-MW2R EPA 7470 EPA 7470
92286780003 MERP/8979 MERC/86313902-MW3R EPA 7470 EPA 7470
92286780004 MERP/8979 MERC/86313902-Field Blank EPA 7470 EPA 7470
92286780001 OEXT/40867 MSSV/119043902-MW1R EPA 3510 EPA 8270
92286780002 OEXT/40867 MSSV/119043902-MW2R EPA 3510 EPA 8270
92286780003 OEXT/40867 MSSV/119043902-MW3R EPA 3510 EPA 8270
92286780004 OEXT/40867 MSSV/119043902-Field Blank EPA 3510 EPA 8270
92286780001 MSV/356243902-MW1R EPA 8260
92286780002 MSV/356243902-MW2R EPA 8260
92286780003 MSV/356243902-MW3R EPA 8260
92286780004 MSV/356243902-Field Blank EPA 8260
92286780005 MSV/356243902-MW4 EPA 8260
92286780006 MSV/356243902-MW5 EPA 8260
92286780007 MSV/356243902-MW6 EPA 8260
92286780008 MSV/356243902-SW1 EPA 8260
92286780009 MSV/356243902-SW2 EPA 8260
92286780010 MSV/356243902-NES1 EPA 8260
92286780011 MSV/356243902-Trip Blank EPA 8260
92286780001 WET/431193902-MW1R SM 4500-S2D
92286780002 WET/431193902-MW2R SM 4500-S2D
92286780003 WET/431193902-MW3R SM 4500-S2D
92286780004 WET/431193902-Field Blank SM 4500-S2D
92286780001 WETA/264913902-MW1R SM 4500-CN-E
REPORT OF LABORATORY ANALYSIS
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Page 76 of 79
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92286780
Butner Landfill Compliance
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92286780002 WETA/264913902-MW2R SM 4500-CN-E
92286780003 WETA/264913902-MW3R SM 4500-CN-E
92286780004 WETA/264913902-Field Blank SM 4500-CN-E
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 77 of 79
Page 78 of 79
Page 79 of 79
#=CL#
March 04, 2016
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92286756
92286756
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
BUTNER LANDFILL MNA
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on February 17, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Dale Ingram
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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Page 1 of 36
#=CL#
March 04, 2016
Page 2
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92286756
cc: Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 2 of 36
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92286756
BUTNER LANDFILL MNA
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414525 N 8th Street, Salina, KS 67401
A2LA Certification #: 2926.01Alaska Certification #: UST-078Alaska Certification #MN00064
Alabama Certification #40770Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680California Certification #: 01155CAColorado Certification #Pace
Connecticut Certification #: PH-0256EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605Guam Certification #:14-008rGeorgia Certification #: 959
Georgia EPD #: PaceIdaho Certification #: MN00064
Hawaii Certification #MN00064Illinois Certification #: 200011Indiana Certification#C-MN-01
Iowa Certification #: 368Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062Kentucky Dept of Envi. Protection - WW #:90062Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001Maine Certification #: 2013011
Maryland Certification #: 322Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137Mississippi Certification #: Pace
Montana Certification #: MT0092Nevada Certification #: MN_00064Nebraska Certification #: Pace
New Jersey Certification #: MN-002New York Certification #: 11647
North Carolina Certification #: 530North Carolina State Public Health #: 27700North Dakota Certification #: R-036
Ohio EPA #: 4150Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507Oregon Certification #: MN200001Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563Puerto Rico Certification
Saipan (CNMI) #:MP0003South Carolina #:74003001Texas Certification #: T104704192
Tennessee Certification #: 02818Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251Virginia/VELAP Certification #: PaceWashington Certification #: C486
West Virginia Certification #: 382West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Asheville Certification IDs2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92286756
BUTNER LANDFILL MNA
Lab ID Sample ID Matrix Date Collected Date Received
92286756001 3902-MW1R Water 02/16/16 17:45 02/17/16 09:25
92286756002 3902-MW2R Water 02/16/16 14:55 02/17/16 09:25
92286756003 3902-MW3R Water 02/16/16 15:15 02/17/16 09:25
92286756004 3902-NES1 Water 02/16/16 17:05 02/17/16 09:25
REPORT OF LABORATORY ANALYSIS
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92286756
BUTNER LANDFILL MNA
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92286756001 3902-MW1R RSK 175 3 PASI-MDR1
SM 2320B 1 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
SM 5210B 1 PASI-ABRJ
EPA 300.0 1 PASI-AMDW
EPA 353.2 1 PASI-ADMN
SM 4500-Cl-E 1 PASI-AWRC
SM 5220D 1 PASI-AWRC
SM 5310B 1 PASI-AMDW
92286756002 3902-MW2R RSK 175 3 PASI-MDR1
SM 2320B 1 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
SM 5210B 1 PASI-ABRJ
EPA 300.0 1 PASI-AMDW
EPA 353.2 1 PASI-ADMN
SM 4500-Cl-E 1 PASI-AWRC
SM 5220D 1 PASI-AWRC
SM 5310B 1 PASI-AMDW
92286756003 3902-MW3R RSK 175 3 PASI-MDR1
SM 2320B 1 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
SM 5210B 1 PASI-ABRJ
EPA 300.0 1 PASI-AMDW
EPA 353.2 1 PASI-ADMN
SM 4500-Cl-E 1 PASI-AWRC
SM 5220D 1 PASI-AWRC
SM 5310B 1 PASI-AMDW
92286756004 3902-NES1 RSK 175 3 PASI-MDR1
SM 2320B 1 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
SM 5210B 1 PASI-ABRJ
EPA 300.0 1 PASI-AMDW
EPA 353.2 1 PASI-ADMN
SM 4500-Cl-E 1 PASI-AWRC
SM 5220D 1 PASI-AWRC
SM 5310B 1 PASI-AMDW
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 5 of 36
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92286756
BUTNER LANDFILL MNA
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92286756001 3902-MW1R
Methane 7.0J ug/L 02/22/16 16:1710.0RSK 175
Alkalinity, Total as CaCO3 41200 ug/L 02/18/16 18:315000SM 2320B
Sulfate 1.5J mg/L 02/22/16 14:31250EPA 300.0
Nitrogen, Nitrate 360J ug/L 02/18/16 08:1510000EPA 353.2
Chloride 3920 ug/L 02/25/16 19:581000SM 4500-Cl-E
Total Organic Carbon 1500 ug/L 02/23/16 15:361000SM 5310B
92286756002 3902-MW2R
Methane 866 ug/L 02/22/16 16:3310.0RSK 175
Alkalinity, Total as CaCO3 792000 ug/L 02/18/16 18:435000SM 2320B
BOD, 5 day 60000 ug/L 02/22/16 23:16 B22000SM 5210B
Sulfate 1.7J mg/L 02/22/16 15:12250EPA 300.0
Chloride 274000 ug/L 02/25/16 20:0215000SM 4500-Cl-E
Chemical Oxygen Demand 295000 ug/L 02/19/16 17:0525000SM 5220D
Total Organic Carbon 27600 ug/L 02/23/16 15:5010000SM 5310B
92286756003 3902-MW3R
Methane 97.5 ug/L 02/22/16 16:4210.0RSK 175
Alkalinity, Total as CaCO3 741000 ug/L 02/18/16 19:285000SM 2320B
BOD, 5 day 6600 ug/L 02/22/16 23:162000SM 5210B
Sulfate 1.8J mg/L 02/22/16 15:26250EPA 300.0
Chloride 186000 ug/L 02/25/16 20:0310000SM 4500-Cl-E
Chemical Oxygen Demand 50000 ug/L 02/19/16 17:0525000SM 5220D
Total Organic Carbon 8460 ug/L 02/23/16 16:011000SM 5310B
92286756004 3902-NES1
Methane 1.6J ug/L 02/22/16 16:5010.0RSK 175
Alkalinity, Total as CaCO3 8730 ug/L 02/18/16 19:515000SM 2320B
Sulfate 10.0J mg/L 02/22/16 15:39250EPA 300.0
Nitrogen, Nitrate 2540J ug/L 02/18/16 08:1410000EPA 353.2
Chloride 3240 ug/L 02/25/16 20:031000SM 4500-Cl-E
Total Organic Carbon 4090 ug/L 02/23/16 16:11 M11000SM 5310B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286756
BUTNER LANDFILL MNA
Sample: 3902-MW1R Lab ID: 92286756001 Collected: 02/16/16 17:45 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Ethane ND ug/L 02/22/16 16:17 74-84-010.0 5.0 1
Ethene ND ug/L 02/22/16 16:17 74-85-110.0 0.47 1
Methane 7.0J ug/L 02/22/16 16:17 74-82-810.0 0.63 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 41200 ug/L 02/18/16 18:315000 1000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/18/16 13:30 18496-25-81.0 0.10 1
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day ND ug/L 02/22/16 23:1602/18/16 05:002000 2000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 1.5J mg/L 02/22/16 14:31 14808-79-8250 1.0 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 360J ug/L 02/18/16 08:1510000 10.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 3920 ug/L 02/25/16 19:58 16887-00-61000 500 1
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand ND ug/L 02/19/16 17:0525000 12500 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 1500 ug/L 02/23/16 15:36 7440-44-01000 500 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:42 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286756
BUTNER LANDFILL MNA
Sample: 3902-MW2R Lab ID: 92286756002 Collected: 02/16/16 14:55 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Ethane ND ug/L 02/22/16 16:33 74-84-010.0 5.0 1
Ethene ND ug/L 02/22/16 16:33 74-85-110.0 0.47 1
Methane 866 ug/L 02/22/16 16:33 74-82-810.0 0.63 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 792000 ug/L 02/18/16 18:435000 1000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/18/16 13:30 18496-25-81.0 0.10 1
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day 60000 ug/L 02/22/16 23:16 B202/18/16 05:002000 2000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 1.7J mg/L 02/22/16 15:12 14808-79-8250 1.0 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate ND ug/L 02/18/16 08:1210000 10.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 274000 ug/L 02/25/16 20:02 16887-00-615000 7500 15
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand 295000 ug/L 02/19/16 17:0525000 12500 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 27600 ug/L 02/23/16 15:50 7440-44-010000 5000 10
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:42 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286756
BUTNER LANDFILL MNA
Sample: 3902-MW3R Lab ID: 92286756003 Collected: 02/16/16 15:15 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Ethane ND ug/L 02/22/16 16:42 74-84-010.0 5.0 1
Ethene ND ug/L 02/22/16 16:42 74-85-110.0 0.47 1
Methane 97.5 ug/L 02/22/16 16:42 74-82-810.0 0.63 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 741000 ug/L 02/18/16 19:285000 1000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/18/16 13:30 18496-25-81.0 0.10 1
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day 6600 ug/L 02/22/16 23:1602/18/16 05:002000 2000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 1.8J mg/L 02/22/16 15:26 14808-79-8250 1.0 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate ND ug/L 02/18/16 08:1310000 10.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 186000 ug/L 02/25/16 20:03 16887-00-610000 5000 10
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand 50000 ug/L 02/19/16 17:0525000 12500 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 8460 ug/L 02/23/16 16:01 7440-44-01000 500 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:42 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286756
BUTNER LANDFILL MNA
Sample: 3902-NES1 Lab ID: 92286756004 Collected: 02/16/16 17:05 Received: 02/17/16 09:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Ethane ND ug/L 02/22/16 16:50 74-84-010.0 5.0 1
Ethene ND ug/L 02/22/16 16:50 74-85-110.0 0.47 1
Methane 1.6J ug/L 02/22/16 16:50 74-82-810.0 0.63 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 8730 ug/L 02/18/16 19:515000 1000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/18/16 13:30 18496-25-81.0 0.10 1
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day ND ug/L 02/22/16 23:1602/18/16 05:002000 2000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 10.0J mg/L 02/22/16 15:39 14808-79-8250 1.0 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 2540J ug/L 02/18/16 08:1410000 10.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 3240 ug/L 02/25/16 20:03 16887-00-61000 500 1
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand ND ug/L 02/19/16 17:0525000 12500 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 4090 ug/L 02/23/16 16:11 7440-44-0 M11000 500 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:42 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286756
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/25280
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples: 92286756001, 92286756002, 92286756003, 92286756004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2196258
Associated Lab Samples:92286756001, 92286756002, 92286756003, 92286756004
Matrix: Water
AnalyzedMDL
Ethane ug/L ND 10.0 02/22/16 16:095.0
Ethene ug/L ND 10.0 02/22/16 16:090.47
Methane ug/L 1.5J 10.0 02/22/16 16:090.63
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2196259LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2196260
Ethane ug/L 107114 94 85-11596109 3 20
Ethene ug/L 98.7106 93 85-11596102 3 20
Methane ug/L 56.260.7 93 85-1159557.4 2 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92286756001
2196850SAMPLE DUPLICATE:
Ethane ug/L ND 20ND
Ethene ug/L ND 20ND
Methane ug/L 4.3J 207.0J
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92287093004
2196851SAMPLE DUPLICATE:
Ethane ug/L ND 20ND
Ethene ug/L ND 20ND
Methane ug/L 1.9J 20ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:42 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286756
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/43113
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples: 92286756001, 92286756002, 92286756003, 92286756004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1668569
Associated Lab Samples:92286756001, 92286756002, 92286756003, 92286756004
Matrix: Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 02/18/16 14:491000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1668570LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 5080050000 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1668571MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286712006
1668572
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 94 80-120103 4 255000057.2 mg/L 104000 109000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1668573MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286712021
1668574
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 103 80-12097 2 2550000113 mg/L 165000 162000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:42 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286756
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/43119
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples: 92286756001, 92286756002, 92286756003, 92286756004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1668592
Associated Lab Samples:92286756001, 92286756002, 92286756003, 92286756004
Matrix: Water
AnalyzedMDL
Sulfide mg/L ND 1.0 02/18/16 13:300.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1668593LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.50J.5 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1668594MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286538001
1668595
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M1.5 79 90-11079 0 10.5ND 0.40J 0.40J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1668596MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286780001
1668597
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M1.5 82 90-11082 0 10.5ND 0.41J 0.41J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:42 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286756
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/43110
SM 5210B
SM 5210B
5210B BOD, 5 day
Associated Lab Samples: 92286756001, 92286756002, 92286756003, 92286756004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1668484
Associated Lab Samples:92286756001, 92286756002, 92286756003, 92286756004
Matrix: Water
AnalyzedMDL
BOD, 5 day ug/L ND 2000 02/22/16 23:162000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1668485LABORATORY CONTROL SAMPLE:
LCSSpike
BOD, 5 day ug/L 188000198000 95 84.6-115.4
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92286922001
1668486SAMPLE DUPLICATE:
BOD, 5 day ug/L 5400000 10 105950 mg/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:42 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286756
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/26476
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples: 92286756001, 92286756002, 92286756003, 92286756004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1668668
Associated Lab Samples:92286756001, 92286756002, 92286756003, 92286756004
Matrix: Water
AnalyzedMDL
Sulfate mg/L ND 250 02/22/16 14:041.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1668669LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate mg/L 19.2J20 96 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1668670MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286756001
1668671
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate mg/L 20 98 90-11098 0 10201.5J 21.1J 21.1J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:42 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286756
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/26473
EPA 353.2
EPA 353.2
353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92286756001, 92286756002, 92286756003, 92286756004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1668549
Associated Lab Samples:92286756001, 92286756002, 92286756003, 92286756004
Matrix: Water
AnalyzedMDL
Nitrogen, Nitrate ug/L ND 10000 02/18/16 07:5610.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1668550LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Nitrate ug/L 2470J2500 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1668551MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286789001
1668552
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Nitrate ug/L 2500 93 90-11094 0 1025004.7 mg/L 6980J 7010J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:42 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286756
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/26556
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples: 92286756001, 92286756002, 92286756003, 92286756004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1673086
Associated Lab Samples:92286756001, 92286756002, 92286756003, 92286756004
Matrix: Water
AnalyzedMDL
Chloride ug/L ND 1000 02/25/16 19:39500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1673087LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 2000020000 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1673088MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287007002
1673089
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L 10000 96 90-11096 0 1010000ND9580 9560
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1673090MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286950001
1673091
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L 40000 96 90-11095 0 104000019.5 mg/L 57900 57600
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:42 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286756
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/26480
SM 5220D
SM 5220D
5220D COD
Associated Lab Samples: 92286756001, 92286756002, 92286756003, 92286756004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1669175
Associated Lab Samples:92286756001, 92286756002, 92286756003, 92286756004
Matrix: Water
AnalyzedMDL
Chemical Oxygen Demand ug/L ND 25000 02/19/16 17:0512500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1669176LABORATORY CONTROL SAMPLE:
LCSSpike
Chemical Oxygen Demand ug/L 747000750000 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1669177MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286717001
1669178
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chemical Oxygen Demand ug/L 750000 97 90-11097 0 375000059.0 mg/L 790000 790000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1669179MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286667003
1669180
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chemical Oxygen Demand ug/L 750000 98 90-11098 0 375000082.0 mg/L 817000 817000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:42 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286756
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/26520
SM 5310B
SM 5310B
5310B TOC
Associated Lab Samples: 92286756001, 92286756002, 92286756003, 92286756004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1671220
Associated Lab Samples:92286756001, 92286756002, 92286756003, 92286756004
Matrix: Water
AnalyzedMDL
Total Organic Carbon ug/L ND 1000 02/23/16 12:40500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1671221LABORATORY CONTROL SAMPLE:
LCSSpike
Total Organic Carbon ug/L 2320025000 93 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1671222MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286799006
1671223
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Total Organic Carbon ug/L M1250008990-11089 1 1025000ND22700 22600
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1671224MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286756004
1671225
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Total Organic Carbon ug/L M1250008390-11093 9 1025000409024900 27200
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:42 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 36
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92286756
BUTNER LANDFILL MNA
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - MinneapolisPASI-M
ANALYTE QUALIFIERS
Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated
for the dilution using the most amount of sample.B2
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:42 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 36
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92286756
BUTNER LANDFILL MNA
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92286756001 AIR/252803902-MW1R RSK 175
92286756002 AIR/252803902-MW2R RSK 175
92286756003 AIR/252803902-MW3R RSK 175
92286756004 AIR/252803902-NES1 RSK 175
92286756001 WET/431133902-MW1R SM 2320B
92286756002 WET/431133902-MW2R SM 2320B
92286756003 WET/431133902-MW3R SM 2320B
92286756004 WET/431133902-NES1 SM 2320B
92286756001 WET/431193902-MW1R SM 4500-S2D
92286756002 WET/431193902-MW2R SM 4500-S2D
92286756003 WET/431193902-MW3R SM 4500-S2D
92286756004 WET/431193902-NES1 SM 4500-S2D
92286756001 WET/43110 WET/431123902-MW1R SM 5210B SM 5210B
92286756002 WET/43110 WET/431123902-MW2R SM 5210B SM 5210B
92286756003 WET/43110 WET/431123902-MW3R SM 5210B SM 5210B
92286756004 WET/43110 WET/431123902-NES1 SM 5210B SM 5210B
92286756001 WETA/264763902-MW1R EPA 300.0
92286756002 WETA/264763902-MW2R EPA 300.0
92286756003 WETA/264763902-MW3R EPA 300.0
92286756004 WETA/264763902-NES1 EPA 300.0
92286756001 WETA/264733902-MW1R EPA 353.2
92286756002 WETA/264733902-MW2R EPA 353.2
92286756003 WETA/264733902-MW3R EPA 353.2
92286756004 WETA/264733902-NES1 EPA 353.2
92286756001 WETA/265563902-MW1R SM 4500-Cl-E
92286756002 WETA/265563902-MW2R SM 4500-Cl-E
92286756003 WETA/265563902-MW3R SM 4500-Cl-E
92286756004 WETA/265563902-NES1 SM 4500-Cl-E
92286756001 WETA/264803902-MW1R SM 5220D
92286756002 WETA/264803902-MW2R SM 5220D
92286756003 WETA/264803902-MW3R SM 5220D
92286756004 WETA/264803902-NES1 SM 5220D
92286756001 WETA/265203902-MW1R SM 5310B
92286756002 WETA/265203902-MW2R SM 5310B
92286756003 WETA/265203902-MW3R SM 5310B
92286756004 WETA/265203902-NES1 SM 5310B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:42 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 36
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#=CL#
February 25, 2016
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92286784
92286784
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
Butner Landfill Dissolved H
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on February 17, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Dale Ingram
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 17
#=CL#
February 25, 2016
Page 2
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92286784
cc: Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 17
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92286784
Butner Landfill Dissolved H
Lab ID Sample ID Matrix Date Collected Date Received
92286784001 3902-MW1R Water 02/16/16 17:45 02/17/16 09:25
92286784002 3902-MW2R Water 02/16/16 14:55 02/17/16 09:25
92286784003 3902-MW3R Water 02/16/16 15:15 02/17/16 09:25
92286784004 3902-NES1 Water 02/16/16 17:05 02/17/16 09:25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 17
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Appendix C

Historical Groundwater Analytical Data
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
INORGANICSAntimony 8-Sep-94 ---30 ND ND ND ND ND ND ------1-Dec-94 ---30 ND ND ND ND ND ND ------9-Feb-95 ---30 ND ND ND ND ND ND ------2-Mar-95 ---30 ND ND ND ND ND ND ------15-Nov-95 ---30 ND ND ND ND ND ND ------28-May-96 ---30 ND ND ND ND ND ND ------22-Nov-96 ---30 ND ND ND ND ND ND ------17-Jun-97 ---30 ND ND ND ND ND ND ------1-Dec-97 ---30 ND ND ND ND ND ND ------20-May-98 ---30 ND ND ND ND ND ND ------19-Nov-98 ---30 ND ND ND ND ND ND ------21-Jul-99 ---30 ND ND ND ND ND ND ------16-Nov-99 ---30 ND ND ND ND ND ND ------10-May-00 ---30 ND 80.0 38.0 32.0 33.0 31.0 ------26-Oct-00 ---30 30.0 ND ND ND ND ND ------18-Apr-01 ---30 ND ND ND ND ND ND ------27-Oct-01 ---30 ND ND ND ND ND ND ------13-Jun-02 ---30 ND ND ND ND ND ND ------19-Nov-02 ---30 ND ND ND ND ND ND ------27-Jun-03 ---30 ND ND ND ND ND ND ------30-Dec-03 ---30 ND ND ND ND ND ND ---ND30-Jun-04 ---30 ND ND ND ND ND ND ---ND29-Dec-04 ---30 ND ND ND ND ND ND ---ND29-Jun-05 ---30 ND ND ND ND ND ND ---ND29-Dec-05 ---30 ND ND ND ND ND ND ---ND28-Jun-06 ---30 ND ND ND ND ND ND ---ND29-Dec-06 ---6 ND ND ND ND ND ND ---ND12-Jul-07 ---6 ND ND ND ND ND ND ---NDGWPS = 1.4 µg/L (10/23/07)19-Dec-07 ---6 ND ND ND ND ND ND ND ND8-Jul-08 ---6 ND ND ND ND ND ND ---ND17-Dec-08 2.6 6.0 ND ND ND ND ND ND ---ND9-Jul-09 2.6 6.0 ND ND ND ND ND ND ND ND16-Dec-09 2.6 6.0 ND ND ND ND ND ND ---NDNC 2B = NE (03/24/10)24-Jun-10 2.6 6.0 ND ND ND 2.9 J ND ND ---NDGWPS = 1 µg/L (8/1/10)13-Dec-10 2.6 6.0 ND ND 3.0 J ND 2.8 J ND ---ND20-Jun-11 5.0 6.0 ND ND ND ND 6.0 ND ---ND5-Dec-11 5.0 6.0 ND ND ND ND ND ND ---ND11-Jun-12 5.0 6.0 ND ND ND ND ND ND ND ND12-Dec-12 5.0 6.0 ND ND ND ND ND ND ---ND1-May-13 5.0 6.0 ND ND ND ND ND ND ND ND5-Aug-13 5.0 6.0 ND ND ND ND ND ND ---ND24-Feb-14 5.0 6.0 8.8 ND ND ND ND ND ND ND12-Aug-14 EPA 6010 5.0 6.0 ND 10.5 8.0 ND ND ND ---ND10-Mar-15 EPA 6010 3.8 6.0 ND 7.1 6.5 3.9 J ND ND ---ND18-Aug-15 EPA 6010 3.8 6.0 ND 6.2 4.8 J 4.1 J ND ND ---ND16-Feb-16 EPA 6010 3.8 6.0 ND 9.9 6.5 4.3 J ND ND ---ND
Arsenic 8-Sep-94 ---10 ND ND ND ND ND ND ------1-Dec-94 ---10 ND ND ND ND ND ND ------9-Feb-95 ---10 ND ND ND ND ND ND ------2-Mar-95 ---10 ND ND ND ND ND ND ------15-Nov-95 ---10 ND ND ND ND ND ND ------28-May-96 ---10 ND ND ND ND ND ND ------22-Nov-96 ---10 ND ND ND ND ND ND ------17-Jun-97 ---10 6.0 J 15.0 ND ND ND ND ------1-Dec-97 ---10 ND 5.0 J ND ND ND ND ------20-May-98 ---10 ND ND ND ND ND ND ------19-Nov-98 ---10 ND ND ND ND ND ND ------21-Jul-99 ---10 ND ND ND ND ND ND ------16-Nov-99 ---10 ND ND ND ND ND ND ------10-May-00 ---10 ND ND ND ND ND ND ------26-Oct-00 ---10 ND ND ND ND ND ND ------18-Apr-01 ---10 ND ND ND ND ND ND ------27-Oct-01 ---10 ND ND ND ND ND ND ------13-Jun-02 ---10 ND ND ND ND ND ND ------19-Nov-02 ---10 ND ND ND ND ND ND ------27-Jun-03 ---10 ND ND ND ND ND ND ------30-Dec-03 ---10 ND ND ND ND ND ND ---ND30-Jun-04 ---10 ND ND ND ND ND ND ---ND29-Dec-04 ---10 ND ND ND ND ND ND ---ND29-Jun-05 ---10 ND ND ND ND ND ND ---ND29-Dec-05 ---10 ND ND ND ND ND ND ---ND28-Jun-06 ---10 ND ND ND ND ND ND ---ND29-Dec-06 ---10 2.0 J ND ND ND ND ND ---ND12-Jul-07 ---10 ND ND ND ND ND ND ---NDNC 2L = 50 µg/L (10/23/07)19-Dec-07 ---10 ND 4.1 J ND ND ND ND ND ND8-Jul-08 ---10 ND 4.9 J ND ND ND ND ---ND17-Dec-08 2.7 10.0 ND ND ND ND ND ND ---ND9-Jul-09 2.7 10.0 ND 13.5 10.9 5.6 J ND 4.0 J ND ND16-Dec-09 2.7 10.0 ND 10.6 6.4 J 5.0 J ND 3.6 J ---NDNC 2L = 10 µg/L (02/05/10)24-Jun-10 2.7 10.0 ND 11.8 8.1 J 8.2 J 3.3 J 3.1 J ---NDResample >12-Aug-10 2.7 10.0 ------7.2 J ------------NDResample >31-Aug-10 2.7 10.0 ---15.4 ---------------ND13-Dec-10 2.7 10.0 ND 4.9 J 2.7 J 5.4 J ND ND ---ND20-Jun-11 5.0 10.0 ND ND ND ND ND ND ---ND5-Dec-11 5.0 10.0 ND ND ND ND ND ND ---ND11-Jun-12 5.0 10.0 ND 5.4 J ND ND ND ND ND ND12-Dec-12 5.0 10.0 ND ND ND ND ND ND ---ND1-May-13 5.0 10.0 ND ND ND ND ND ND ND ND5-Aug-13 5.0 10.0 ND ND 5.6 J ND ND ND ---ND24-Feb-14 5.0 10.0 ND 6.4 J ND ND ND ND ND ND12-Aug-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ---ND10-Mar-15 EPA 6010 2.5 10.0 4.1 J 5.4 J ND ND 3.1 J 3.2 J ---3.0 J18-Aug-15 EPA 6011 2.5 10.0 ND 5.1 J ND ND ND ND ---ND16-Feb-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 1 of 19
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Barium 8-Sep-94 ---500 ND 270 ND ND 830 860 ------1-Dec-94 ---500 ND ND ND ND ND ND ------9-Feb-95 ---500 ND ND ND ND 510 ND ------2-Mar-95 ---500 ND ND ND ND ND ND ------15-Nov-95 ---500 ND ND ND ND ND ND ------28-May-96 ---500 ND ND ND ND ND ND ------22-Nov-96 ---500 ND 82.0 30.0 ND 15.0 ND ------17-Jun-97 ---500 200 320 37.0 17.0 210 31.0 ------1-Dec-97 ---500 61.0 180 43.0 46.0 220 33.0 ------20-May-98 ---500 30.0 150 45.0 13.0 180 22.0 ------19-Nov-98 ---500 48.0 120 42.0 ND 380 12.0 ------21-Jul-99 ---500 ND ND ND ND ND ND ------16-Nov-99 ---500 ND ND ND ND ND ND ------10-May-00 ---500 ND ND ND ND ND ND ------26-Oct-00 ---500 ND ND ND ND ND ND ------18-Apr-01 ---500 ND ND ND ND ND ND ------27-Oct-01 ---500 ND ND ND ND ND ND ------13-Jun-02 ---500 ND ND ND ND ND ND ------19-Nov-02 ---500 ND ND ND ND ND ND ------27-Jun-03 ---500 ND ND ND ND ND ND ------30-Dec-03 ---500 ND ND ND ND ND ND ---ND30-Jun-04 ---500 ND ND ND ND ND ND ---ND29-Dec-04 ---500 ND ND ND ND ND ND ---ND29-Dec-04 ---500 ND ND ND ND ND ND ---ND29-Jun-05 ---500 ND ND ND ND ND ND ---ND29-Dec-05 ---500 ND ND ND ND ND ND ---ND28-Jun-06 ---500 ND ND ND ND ND ND ---ND29-Dec-06 ---100 5.2 J 120 64.9 1.5 J 64.1 1.8 J ---0.20 J12-Jul-07 ---100 2.5 J 129 65.7 J 1.1 J 77.0 J 1.3 J ---NDNC 2L = 2,000 µg/L (10/23/07)19-Dec-07 ---100 2.8 B 99.2 50.0 B 1.4 B 49.6 B 1.7 B 87.8 11.78-Jul-08 ---100 5.8 J 102 58.4 J 1.1 B 57.9 J 1.2 B ---0.29 J17-Dec-08 0.20 100 2.7 B 92.9 J 53.1 B 1.2 B 55.5 J 1.1 B ---10.7 J9-Jul-09 0.20 100 4.6 B 121 63.4 B 0.37 B 81.4 B 0.94 B 72.4 B 17.6 J16-Dec-09 0.20 100 2.9 B 108 62.8 B 0.61 B 56.8 B 0.87 B ---17.1 JNC 2L = 700 µg/L (02/05/10)24-Jun-10 0.20 100 2.5 B 115 B 61.1 B 1.6 B 93.5 B 1.4 B ---27.3 J13-Dec-10 0.20 100 4.3 B 122 67.9 J 1.3 B 90.6 J 1.5 B ---12.1 J20-Jun-11 5.0 100 ND 108 70.7 J ND 84.7 J ND ---ND5-Dec-11 5.0 100 ND 118 73.0 J ND 90.6 J ND ---ND11-Jun-12 5.0 100 ND 138 65.2 J ND 76.4 J ND 61.3 J ND12-Dec-12 5.0 100 ND 113 64.7 J ND 73.6 J ND ---ND1-May-13 5.0 100 ND 118 69.1 J ND 84.2 J ND 81.2 J ND5-Aug-13 5.0 100 ND 111 65.1 J ND 95.6 J ND ---ND24-Feb-14 5.0 100 ND 93.8 J 44.8 J ND 139 ND ND ND12-Aug-14 EPA 6010 5.0 100 ND 125 66.4 J ND 121 ND ---ND10-Mar-15 EPA 6010 2.5 100 3.0 J 109 61.8 J ND 116 ND ---ND18-Aug-15 EPA 6010 2.5 100 4.4 J 119 63.1 J ND 81.3 J ND ---ND16-Feb-16 EPA 6010 2.5 100 5.2 J 123 72.7 J 3.0 J 126 ND ---ND
Beryllium 8-Sep-94 ---2 ND ND ND ND ND ND ------1-Dec-94 ---2 ND ND ND ND 4.0 ND ------9-Feb-95 ---2 ND ND ND ND ND ND ------2-Mar-95 ---2 ND ND ND ND 2.0 ND ------15-Nov-95 ---2 ND ND ND ND ND ND ------28-May-96 ---2 ND ND ND ND 6.0 ND ------22-Nov-96 ---2 ND ND ND ND 3.0 ND ------17-Jun-97 ---2 2.0 3.0 ND ND 1.0 ND ------1-Dec-97 ---2 ND ND ND ND ND ND ------20-May-98 ---2 ND ND ND ND ND ND ------19-Nov-98 ---2 ND ND ND ND 2.0 ND ------21-Jul-99 ---2 ND ND ND ND ND ND ------16-Nov-99 ---2 ND ND ND ND ND ND ------10-May-00 ---2 ND ND ND ND ND ND ------26-Oct-00 ---2 ND ND ND ND ND ND ------18-Apr-01 ---2 ND 12.0 ND ND ND ND ------27-Oct-01 ---2 ND ND ND ND ND ND ------13-Jun-02 ---2 ND ND ND ND ND ND ------19-Nov-02 ---2 ND ND ND ND ND ND ------27-Jun-03 ---2 ND ND ND ND ND ND ------30-Dec-03 ---2 ND ND ND ND ND ND ---ND30-Jun-04 ---2 ND ND ND ND ND ND ---ND29-Dec-04 ---2 ND ND ND ND ND ND ---ND29-Dec-04 ---2 ND ND ND ND ND ND ---ND29-Jun-05 ---2 ND ND ND ND ND ND ---ND29-Dec-05 ---2 ND ND ND ND ND ND ---ND28-Jun-06 ---2 ND ND ND ND ND ND ---ND29-Dec-06 ---1 ND ND ND ND ND ND ---ND12-Jul-07 ---1 ND ND ND ND ND ND ---NDGWPS = 4 µg/L (10/23/07)19-Dec-07 ---1 ND ND ND ND ND ND ND ND8-Jul-08 ---1 ND ND ND ND ND ND ---ND17-Dec-08 0.10 1.0 ND ND ND ND 0.14 J ND ---ND9-Jul-09 0.10 1.0 ND 0.18 J 0.22 J 0.17 J ND ND 0.23 J ND16-Dec-09 0.10 1.0 ND 0.15 J 0.17 J 0.15 J 0.25 J ND ---NDNC 2B = 6.5 µg/L (02/05/10)24-Jun-10 0.10 1.0 ND ND 0.27 J 0.16 J ND ND ---ND13-Dec-10 0.10 1.0 ND ND ND ND ND ND ---ND20-Jun-11 1.0 1.0 ND ND ND ND ND ND ---ND5-Dec-11 1.0 1.0 ND ND ND ND ND ND ---ND11-Jun-12 1.0 1.0 ND ND ND ND ND ND ND ND12-Dec-12 1.0 1.0 ND ND ND ND ND ND ---ND1-May-13 1.0 1.0 ND ND ND ND ND ND ND ND5-Aug-13 1.0 1.0 ND ND ND ND ND ND ---ND24-Feb-14 1.0 1.0 ND ND ND ND ND ND ND ND12-Aug-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ---ND10-Mar-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ---ND18-Aug-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ---ND16-Feb-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 2 of 19
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Cadmium 8-Sep-94 ---1 ND ND ND ND ND 4.0 ------1-Dec-94 ---1 ND ND ND ND ND ND ------9-Feb-95 ---1 ND ND ND ND ND ND ------2-Mar-95 ---1 ND ND ND ND ND ND ------15-Nov-95 ---1 ND ND ND ND ND ND ------28-May-96 ---1 ND ND ND ND ND ND ------22-Nov-96 ---1 ND ND ND ND ND ND ------17-Jun-97 ---1 ND 3.0 1.0 ND ND ND ------1-Dec-97 ---1 ND 2.0 ND ND ND ND ------20-May-98 ---1 ND ND ND ND ND ND ------19-Nov-98 ---1 ND ND ND ND ND ND ------21-Jul-99 ---1 ND ND ND ND ND ND ------16-Nov-99 ---1 ND 3.0 3.0 ND 2.0 ND ------10-May-00 ---1 5.0 ND ND ND ND ND ------26-Oct-00 ---1 ND 2.0 ND ND ND ND ------18-Apr-01 ---1 ND 11.0 ND ND ND ND ------27-Oct-01 ---1 ND ND ND ND ND ND ------13-Jun-02 ---1 ND 2.0 ND ND ND ND ------19-Nov-02 ---1 2.0 2.0 ND ND 2.0 ND ------27-Jun-03 ---1 ND ND ND ND ND ND ------30-Dec-03 ---1 ND 1.0 ND ND ND ND ---ND30-Jun-04 ---1 ND ND ND ND ND ND ---ND29-Dec-04 ---1 ND ND ND ND ND ND ---ND29-Jun-05 ---1 ND ND ND ND ND ND ---ND29-Dec-05 ---1 ND ND ND ND ND ND ---ND28-Jun-06 ---1 ND ND ND ND ND ND ---ND29-Dec-06 ---1 ND ND ND ND ND ND ---ND12-Jul-07 ---1 ND ND ND ND ND ND ---NDNC 2L = 1.75 µg/L (10/23/07)19-Dec-07 ---1 ND ND ND ND ND ND ND ND8-Jul-08 ---1 ND ND ND ND ND ND ---ND17-Dec-08 0.50 1.0 ND ND ND ND ND ND ---ND9-Jul-09 0.50 1.0 ND 1.4 ND ND ND ND ND ND16-Dec-09 0.50 1.0 ND ND ND ND ND ND ---NDNC 2L = 2 µg/L (02/05/10)24-Jun-10 0.50 1.0 ND ND ND ND ND ND ---ND13-Dec-10 0.50 1.0 ND ND ND ND ND ND ---ND20-Jun-11 1.0 1.0 ND ND ND ND ND ND ---ND5-Dec-11 1.0 1.0 ND ND ND ND ND ND ---ND11-Jun-12 1.0 1.0 ND ND ND ND ND ND ND ND12-Dec-12 1.0 1.0 ND ND ND ND ND ND ---ND1-May-13 1.0 1.0 ND ND ND ND ND ND ND ND5-Aug-13 1.0 1.0 ND ND ND ND ND ND ---ND24-Feb-14 1.0 1.0 ND ND ND ND ND ND ND ND12-Aug-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ---ND10-Mar-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ---ND18-Aug-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ---ND16-Feb-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ---ND
Chromium 8-Sep-94 ---10 8.0 44.0 ND 6.0 48.0 80.0 ------1-Dec-94 ---10 14.0 ND ND ND 18.0 ND ------9-Feb-95 ---10 14.0 ND ND 10.0 ND ND ------2-Mar-95 ---10 ND ND ND ND ND ND ------15-Nov-95 ---10 13.0 13.0 ND ND ND ND ------28-May-96 ---10 33.0 ND ND ND ND ND ------22-Nov-96 ---10 3.0 ND ND ND ND 3.0 ------17-Jun-97 ---10 57.0 43.0 ND 3.0 2.0 6.0 ------1-Dec-97 ---10 29.0 ND ND ND ND ND ------20-May-98 ---10 10.0 3.0 ND ND 12.0 ND ------19-Nov-98 ---10 17.0 3.0 ND ND 5.0 ND ------21-Jul-99 ---10 ND ND ND ND ND ND ------16-Nov-99 ---10 ND ND ND ND ND ND ------10-May-00 ---10 ND ND ND ND ND ND ------26-Oct-00 ---10 ND ND ND ND ND ND ------18-Apr-01 ---10 ND 12.0 ND ND ND ND ------27-Oct-01 ---10 ND ND ND ND ND ND ------13-Jun-02 ---10 ND ND ND ND ND ND ------19-Nov-02 ---10 ND ND ND ND ND ND ------27-Jun-03 ---10 ND ND ND ND ND ND ------30-Dec-03 ---10 ND ND ND ND ND ND ---ND30-Jun-04 ---10 ND ND ND ND ND ND ---ND29-Dec-04 ---10 ND ND ND ND ND ND ---ND29-Jun-05 ---10 ND ND ND ND ND ND ---ND29-Dec-05 ---10 ND ND ND ND ND ND ---ND28-Jun-06 ---10 ND ND ND ND ND ND ---ND29-Dec-06 ---10 ND ND ND ND ND ND ---ND12-Jul-07 ---10 ND ND ND ND ND ND ---NDNC 2L = 50 µg/L (10/23/07)19-Dec-07 ---10 ND 2.0 B ND ND ND ND 1.1 B 1.4 J8-Jul-08 ---10 ND 0.54 J 0.58 J ND ND ND ---ND17-Dec-08 0.40 10.0 0.73 J 1.8 J 0.96 J ND 0.96 J 0.70 J ---ND9-Jul-09 0.40 10.0 1.2 J 2.4 J 1.1 J 1.6 J 0.68 J 0.53 J 4.8 J ND16-Dec-09 0.40 10.0 1.3 J ND ND ND 0.95 J ND ---NDNC 2L = 10 µg/L (02/05/10)24-Jun-10 0.40 10.0 1.1 B 3.5 B 2.8 B 2.4 B 1.2 B 1.4 B ---0.71 J13-Dec-10 0.40 10.0 2.5 J 1.3 J 1.8 J 0.69 J 0.57 J 1.2 J ---ND20-Jun-11 5.0 10.0 ND ND ND ND ND ND ---ND5-Dec-11 5.0 10.0 ND ND ND ND ND ND ---ND11-Jun-12 5.0 10.0 ND 8.6 J ND ND ND ND ND ND12-Dec-12 5.0 10.0 ND 5.2 J ND ND ND ND ---ND1-May-13 5.0 10.0 ND ND ND ND ND ND ND ND5-Aug-13 5.0 10.0 ND ND ND ND ND ND ---ND24-Feb-14 5.0 10.0 ND ND ND ND ND ND ND ND12-Aug-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ---ND10-Mar-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND18-Aug-15 EPA 6010 2.5 10.0 ND 2.7 J ND ND ND 6.7 J ---ND16-Feb-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 3 of 19
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Cobalt 8-Sep-94 ---10 ND ND ND ND ND ND ------1-Dec-94 ---10 11.0 ND 13.0 16.0 22.0 ND ------9-Feb-95 ---10 20.0 14.0 ND 48.0 39.0 ND ------2-Mar-95 ---10 16.0 21.0 ND 29.0 121.0 ND ------15-Nov-95 ---10 20.0 21.0 ND ND 27.0 ND ------28-May-96 ---10 30.0 16.0 ND ND 122 ND ------22-Nov-96 ---10 6.0 13.0 ND 4.7 93.0 ND ------17-Jun-97 ---10 130 38.0 ND 6.0 45.0 3.0 ------1-Dec-97 ---10 32.0 21.0 ND 12.0 36.0 4.0 ------20-May-98 ---10 15.0 16.0 2.0 9.0 100 3.0 ------19-Nov-98 ---10 21.0 16.0 2.0 7.0 180 3.0 ------21-Jul-99 ---10 ND 16.0 ND ND 100 ND ------16-Nov-99 ---10 ND 15.0 ND ND 38.0 ND ------10-May-00 ---10 ND 17.0 ND ND 61.0 ND ------26-Oct-00 ---10 ND 15.0 ND ND ND ND ------18-Apr-01 ---10 ND 27.0 ND ND 74.0 ND ------27-Oct-01 ---10 ND 12.0 ND ND 47.0 ND ------13-Jun-02 ---10 ND 14.0 ND ND 251 ND ------19-Nov-02 ---10 ND 10.0 ND ND 57.0 ND ------27-Jun-03 ---10 ND 15.0 ND ND 75.0 ND ------30-Dec-03 ---10 ND 17.0 ND ND 52.0 ND ---ND30-Jun-04 ---10 ND 16.0 ND ND 31.0 ND ---ND29-Dec-04 ---10 ND 11.0 ND ND 46.0 ND ---ND29-Jun-05 ---10 ND 11.0 ND ND 43.0 ND ---ND29-Dec-05 ---10 ND 12.0 ND ND 30.0 ND ---ND28-Jun-06 ---10 ND ND ND ND 72.5 ND ---ND29-Dec-06 ---10 ND 11.4 ND ND 37.5 ND ---ND12-Jul-07 ---10 ND 11.8 ND 2.7 58.4 ND ---NDGWPS = 70 µg/L (10/23/07)19-Dec-07 ---10 2.5 B ND ND 2.0 B 103 2.6 B 8.0 B 1.8 J8-Jul-08 ---10 10.3 B 12.1 B 2.0 B 9.0 B 130 4.8 B ---6.2 J17-Dec-08 0.60 10.0 2.1 B 11.8 B 2.3 B 3.6 B 43.7 1.6 B ---2.5 J9-Jul-09 0.60 10.0 ND 6.2 J ND ND 100 ND 2.2 J ND16-Dec-09 0.60 10.0 ND 4.7 J ND ND 6.6 J ND ---ND24-Jun-10 0.60 10.0 ND 16.3 ND ND 25.0 ND ---NDGWPS = 1 µg/L (2/05/10)13-Dec-10 0.60 10.0 2.5 B 15.5 ND ND {129}{ND}---1.6 {1.0 J}J20-Jun-11 5.0 10.0 ND 14.2 ND ND 81.8 ND ---ND5-Dec-11 5.0 10.0 ND 12.7 ND ND 146 ND ---NDResample >25-Jan-12 5.0 10.0 ------------47.5 ------ND11-Jun-12 5.0 10.0 ND 14.2 ND ND 101 ND ND ND12-Dec-12 5.0 10.0 ND 11.3 ND ND 113 ND ---ND1-May-13 5.0 10.0 ND 24.3 ND ND 34.0 ND ND ND5-Aug-13 5.0 10.0 ND 24.7 ND ND 50.9 ND ---ND24-Feb-14 5.0 10.0 ND 18.4 ND ND 9.6 J ND ND ND12-Aug-14 EPA 6010 5.0 10.0 ND 9.4 J ND ND 46.3 ND ---ND10-Mar-15 EPA 6010 2.5 10.0 ND 8.7 J ND ND 39.2 ND ---ND18-Aug-15 EPA 6010 2.5 10.0 ND 9.3 J ND ND 116 ND ---ND16-Feb-16 EPA 6010 2.5 10.0 ND 10.0 ND ND 13.1 ND ---ND
Copper 8-Sep-94 ---200 ND ND ND ND ND 660 ------1-Dec-94 ---200 ND ND ND ND ND ND ------9-Feb-95 ---200 ND ND ND ND ND ND ------2-Mar-95 ---200 ND ND ND ND ND ND ------15-Nov-95 ---200 ND ND ND ND ND ND ------28-May-96 ---200 ND ND ND ND ND ND ------22-Nov-96 ---200 ND ND 32.0 13.0 100 ND ------17-Jun-97 ---200 34.0 350 13.0 37.0 28.0 77.0 ------1-Dec-97 ---200 19.0 72.0 14.0 88.0 15.0 34.0 ------20-May-98 ---200 12.0 48.0 380 41.0 53.0 28.0 ------19-Nov-98 ---200 10.0 ND 410 28.0 53.0 14.0 ------21-Jul-99 ---200 ND ND ND ND ND ND ------16-Nov-99 ---200 ND ND ND ND ND ND ------10-May-00 ---200 ND ND ND ND ND ND ------26-Oct-00 ---200 ND ND ND ND ND ND ------18-Apr-01 ---200 ND ND ND ND ND ND ------27-Oct-01 ---200 ND ND ND ND ND ND ------13-Jun-02 ---200 ND ND ND ND ND ND ------19-Nov-02 ---200 ND ND ND ND ND ND ------27-Jun-03 ---200 ND ND ND ND ND ND ------30-Dec-03 ---200 ND ND ND ND ND ND ---ND30-Jun-04 ---200 ND ND ND ND ND ND ---ND29-Dec-04 ---200 ND ND ND ND ND ND ---ND29-Jun-05 ---200 ND ND ND ND ND ND ---ND29-Dec-05 ---200 ND ND ND ND ND ND ---ND28-Jun-06 ---200 ND ND ND ND ND ND ---ND29-Dec-06 ---10 ND ND 11.3 5.50 J 10.4 1.90 B ---0.60 J12-Jul-07 ---10 ND ND 13.4 7.90 2.6 J ND ---NDNC 2L = 1,000 µg/L (10/23/07)19-Dec-07 ---10 2.0 B ND 8.6 B 3.8 B 7.0 B 0.73 B 5.8 B 9.88-Jul-08 ---10 0.64 J ND 12.1 3.7 J 8.5 J ND ---ND17-Dec-08 0.30 10.0 0.80 J 13.6 10.2 3.9 J 11.9 0.37 J ---ND9-Jul-09 0.30 10.0 ND ND 6.3 J ND 5.7 J ND 8.8 J ND16-Dec-09 0.30 10.0 ND ND 9.2 J 1.6 J 5.7 J ND ---ND24-Jun-10 0.30 10.0 ND ND 10 1.2 J 5.1 J ND ---ND13-Dec-10 0.30 10.0 1.1 B ND 13.6 5.8 J 5.6 J 0.59 B ---0.49 J20-Jun-11 5.0 10.0 ND ND 15.3 8.1 J 8.7 J ND ---ND5-Dec-11 5.0 10.0 ND ND 16.9 10.0 J 7.6 J ND ---ND11-Jun-12 5.0 10.0 ND 10.7 12.2 6.3 J 7.4 J ND ND ND12-Dec-12 5.0 10.0 ND ND 11.6 8.5 J 10.4 ND ---ND1-May-13 5.0 10.0 ND ND 13.6 5.8 J 9.6 J ND ND ND5-Aug-13 5.0 10.0 ND ND 14.3 ND 10.2 ND ---ND24-Feb-14 5.0 10.0 ND ND 12.2 ND 5.1 J ND ND ND12-Aug-14 EPA 6010 5.0 10.0 ND ND 10.5 ND ND ND ---ND10-Mar-15 EPA 6010 2.5 10.0 ND ND 8.7 J ND 15.5 ND ---ND18-Aug-15 EPA 6010 2.5 10.0 ND ND 6.7 J 5.6 J 10.1 ND ---ND16-Feb-16 EPA 6010 2.5 10.0 ND ND 7.8 J ND 5.1 J ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 4 of 19
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Lead 8-Sep-94 ---10 ND 13.0 ND ND 30.0 36.0 ------1-Dec-94 ---10 11.0 ND ND ND 36.0 ND ------9-Feb-95 ---10 ND ND ND 10.0 37.0 ND ------2-Mar-95 ---10 ND ND ND ND 44.0 ND ------15-Nov-95 ---10 ND ND ND ND ND ND ------28-May-96 ---10 ND ND ND ND 42.0 ND ------22-Nov-96 ---10 ND ND ND ND 13.0 ND ------17-Jun-97 ---10 20.0 29.0 ND ND 13.0 ND ------1-Dec-97 ---10 8.0 14.0 ND 5.0 14.0 ND ------20-May-98 ---10 ND 6.0 ND 6.0 21.0 ND ------19-Nov-98 ---10 5.0 ND ND ND 58.0 ND ------21-Jul-99 ---10 ND 12.0 14.0 ND ND ND ------16-Nov-99 ---10 ND ND ND ND ND ND ------10-May-00 ---10 ND ND ND ND ND ND ------26-Oct-00 ---10 ND ND ND ND ND ND ------18-Apr-01 ---10 ND ND ND ND ND ND ------27-Oct-01 ---10 ND ND ND ND ND ND ------13-Jun-02 ---10 11.0 ND ND ND ND ND ------19-Nov-02 ---10 ND ND ND ND 12.0 ND ------27-Jun-03 ---10 ND ND ND ND ND ND ------30-Dec-03 ---10 ND ND ND ND ND ND ---ND30-Jun-04 ---10 ND ND ND ND ND ND ---ND29-Dec-04 ---10 ND ND ND ND ND ND ---ND29-Jun-05 ---10 ND ND ND ND ND ND ---ND29-Dec-05 ---10 ND ND ND ND ND ND ---ND28-Jun-06 ---10 ND ND ND ND ND ND ---ND29-Dec-06 ---10 ND ND ND ND ND 2.1 J ---ND12-Jul-07 ---10 ND ND ND ND ND ND ---NDNC 2L = 15 µg/L (10/23/07)19-Dec-07 ---10 ND ND ND ND ND ND ND ND8-Jul-08 ---10 ND ND ND ND ND ND ---ND17-Dec-08 4.0 10.0 ND ND ND ND ND ND ---ND9-Jul-09 4.0 10.0 ND ND ND ND ND ND ND ND16-Dec-09 4.0 10.0 ND ND ND ND ND ND ---ND24-Jun-10 4.0 10.0 ND ND ND ND ND ND ---ND13-Dec-10 4.0 10.0 ND ND ND ND ND ND ---ND20-Jun-11 5.0 10.0 ND ND ND ND ND ND ---ND5-Dec-11 5.0 10.0 ND ND ND ND ND ND ---ND11-Jun-12 5.0 10.0 ND ND ND ND ND ND ND ND12-Dec-12 5.0 10.0 ND ND ND ND ND ND ---ND1-May-13 5.0 10.0 ND ND ND ND ND ND ND ND5-Aug-13 5.0 10.0 ND ND ND ND ND ND ---ND24-Feb-14 5.0 10.0 ND ND ND ND ND ND ND ND12-Aug-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ---ND10-Mar-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND18-Aug-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND16-Feb-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND
Mercury 1-Dec-97 ---0.5 ND ND ND ND ND ND ------19-Nov-98 ---0.5 ND ND ND ND ND ND ------16-Nov-99 ---0.5 ND 0.59 0.65 0.65 0.76 ND ------10-May-00 ---0.5 ---ND ND ND ND ---------26-Oct-00 ---0.5 ---ND ND ND ND ---------18-Apr-01 ---0.5 ---ND ND ND ND ---------13-Jun-02 ---0.5 ---ND ND ND ND ---------27-Jun-03 ---0.5 ---ND ND ND ND ---------30-Dec-03 ---0.5 ------------------------30-Jun-04 ---0.5 ND ND ND ND ND ND ---ND29-Dec-04 ------------------------------29-Jun-05 ---0.5 ND ND ND ND ND ND ---ND29-Dec-05 ------------------------------28-Jun-06 ---2 ND ND ND ND ND ND ---ND29-Dec-06 ------------------------------12-Jul-07 ---0.2 ND ND ND ND ND ND ---NDNC 2L = 1.05 µg/L (10/23/07)19-Dec-07 ------------------------ND ---8-Jul-08 ---0.2 ND ND ND ND ND ND ---ND17-Dec-08 ------------------------------9-Jul-09 0.070 0.2 ND ND ND ND ND ND ---ND16-Dec-09 ------------------------------NC 2L = 1 µg/L (02/05/10)24-Jun-10 0.070 0.20 ND ND ND ND ND 0.098 J ---ND13-Dec-10 ------------------------------20-Jun-11 0.10 0.20 ND ND ND ND ND ND ---ND5-Dec-11 ------------------------------11-Jun-12 0.10 0.20 ND ND ND ND ND ND ND ND12-Dec-12 ------------------------------1-May-13 0.10 0.20 ND ND ND ND ND ND ---ND5-Aug-13 ------------------------------24-Feb-14 0.10 0.20 ND ND ND ND ND ND ND ND12-Aug-14 ------------------------------10-Mar-15 EPA 7470 0.10 0.20 ND ND ND ------------ND16-Feb-16 EPA 7470 0.10 0.20 ND ND ND ------------ND
Granville County
Butner Landfill, Permit No. 39-02 Page 5 of 19
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Nickel 8-Sep-94 ---50 ND ND ND ND ND ND ------1-Dec-94 ---50 ND ND ND ND ND ND ------9-Feb-95 ---50 ND 72 ND ND ND ND ------2-Mar-95 ---50 ND 100 ND ND ND ND ------15-Nov-95 ---50 ND 61.0 ND ND ND ND ------28-May-96 ---50 ND 85.0 ND ND ND ND ------22-Nov-96 ---50 ND 72.0 ND ND ND ND ------17-Jun-97 ---50 75 98.0 ND ND ND ND ------1-Dec-97 ---50 ND 89.0 ND ND ND ND ------20-May-98 ---50 ND 91.0 ND ND ND ND ------19-Nov-98 ---50 ND 83.0 ND ND ND ND ------21-Jul-99 ---50 ND 109 ND ND ND ND ------16-Nov-99 ---50 ND 122 ND ND ND ND ------10-May-00 ---50 ND 104 ND ND ND ND ------26-Oct-00 ---50 ND 93.0 ND ND ND ND ------18-Apr-01 ---50 ND 107 ND ND ND ND ------27-Oct-01 ---50 ND 92.0 ND ND ND ND ------13-Jun-02 ---50 ND 98.0 ND ND ND ND ------19-Nov-02 ---50 ND 74.0 ND ND ND ND ------27-Jun-03 ---50 ND 85.0 ND ND ND ND ------30-Dec-03 ---50 ND 100 ND ND ND ND ---ND30-Jun-04 ---50 ND 120 (81.0)ND ND ND ND ---ND29-Dec-04 ---50 ND 100 ND ND ND ND ---ND29-Jun-05 ---50 ND 150 (92.0)ND ND ND ND ---ND29-Dec-05 ---50 ND 96.0 ND ND ND ND ---ND28-Jun-06 ---50 ND 88.7 ND ND ND ND ---ND29-Dec-06 ---50 ND 94.7 30.1 14.2 8.9 J ND ---ND12-Jul-07 ---50 ND 99.0 30.6 J 13.9 J 13.7 J ND ---NDNC 2L = 100 µg/L (10/23/07)19-Dec-07 ---50 ND 83.4 23.7 11.0 18.3 ND 11.4 ND8-Jul-08 ---50 ND 76.0 28.1 J 11.5 J 27.0 J ND ---ND17-Dec-08 1.7 50.0 ND 75.5 27.8 J 12.2 J 11.0 B ND ---2.4 J9-Jul-09 1.7 50.0 2.2 J 93.5 29.4 J 11.7 J 23.2 J ND 13.1 J ND16-Dec-09 1.7 50.0 ND 81.2 28.2 J 11.8 B 2.6 B ND ---3.0 J24-Jun-10 1.7 50.0 ND 76.3 19.7 J 9.0 J 7.0 J 4.5 J ---ND13-Dec-10 1.7 50.0 ND 83.0 23.5 J 6.8 B 20.7 J ND ---2.7 J20-Jun-11 5.0 50.0 ND 78.8 30.1 J 11.2 J 15.3 J ND ---ND5-Dec-11 5.0 50.0 ND 89.1 32.8 J 11.7 J 24.3 J ND ---ND11-Jun-12 5.0 50.0 ND 91.8 28.9 J 10.0 J 17.3 J ND ND ND12-Dec-12 5.0 50.0 ND 91.8 29.2 J 9.3 J 21.1 J ND ---ND1-May-13 5.0 50.0 ND 89.6 31.9 J 10.4 J 5.7 J ND ND ND5-Aug-13 5.0 50.0 ND 87.9 28.1 J 9.0 J 8.4 J ND ---ND24-Feb-14 5.0 50.0 ND 83.1 16.7 J 10.4 J ND ND ND ND12-Aug-14 EPA 6010 5.0 50.0 ND 97.9 29 J 12.9 J 13.2 J ND ---ND10-Mar-15 EPA 6010 2.5 50.0 ND 91.9 32.9 J 12.3 J 8.2 J ND ---ND18-Aug-15 EPA 6010 2.5 50.0 ND 98.0 28.0 J 11.9 J 26.2 J 5.4 J ---ND16-Feb-16 EPA 6010 2.5 50.0 ND 92.0 35.4 J 12.7 J 3.7 J ND ---ND
Selenium 8-Sep-94 ---20 ND ND ND ND ND ND ------1-Dec-94 ---20 ND ND ND ND ND ND ------9-Feb-95 ---20 ND ND ND ND ND ND ------2-Mar-95 ---20 ND ND ND ND ND ND ------15-Nov-95 ---20 ND ND ND ND ND ND ------28-May-96 ---20 ND ND ND ND ND ND ------22-Nov-96 ---20 ND ND ND ND ND ND ------17-Jun-97 ---20 ND ND ND ND ND ND ------1-Dec-97 ---20 ND ND ND ND ND ND ------20-May-98 ---20 ND ND ND ND ND ND ------19-Nov-98 ---20 ND ND ND ND ND ND ------21-Jul-99 ---20 ND ND ND ND 36.0 ND ------16-Nov-99 ---20 ND ND ND ND ND ND ------10-May-00 ---20 ND ND ND ND ND ND ------26-Oct-00 ---20 ND ND ND ND ND ND ------18-Apr-01 ---20 ND ND ND ND ND ND ------27-Oct-01 ---20 ND ND ND ND ND ND ------13-Jun-02 ---20 ND ND ND ND ND ND ------19-Nov-02 ---20 ND ND ND ND ND ND ------27-Jun-03 ---20 ND ND ND ND ND ND ------30-Dec-03 ---20 ND ND ND ND ND ND ---ND30-Jun-04 ---20 ND ND ND ND ND ND ---ND29-Dec-04 ---20 ND ND ND ND ND ND ---ND29-Jun-05 ---20 ND ND ND ND ND ND ---ND29-Dec-05 ---20 ND ND ND ND ND ND ---ND28-Jun-06 ---20 ND ND ND ND ND ND ---ND29-Dec-06 ---10 ND ND ND ND ND ND ---ND12-Jul-07 ---10 ND ND ND ND ND ND ---NDNC 2L = 50 µg/L (10/23/07)19-Dec-07 ---10 ND 11.5 ND ND ND ND ND ND8-Jul-08 ---10 ND ND ND ND ND ND ---ND17-Dec-08 3.8 10 4.8 B 5.1 B 4.8 B ND ND ND ---4.9 J9-Jul-09 3.8 10 ND ND 4.2 J ND ND ND ND ND16-Dec-09 3.8 10 ND ND ND 5.1 J ND ND ---NDNC 2L = 20 µg/L (02/05/10)24-Jun-10 3.8 10 ND ND ND ND ND ND ---ND13-Dec-10 3.8 10 ND ND ND ND ND ND ---ND20-Jun-11 10.0 10 ND ND ND ND ND ND ---ND5-Dec-11 10.0 10 ND ND ND ND ND ND ---ND11-Jun-12 10.0 10 ND ND ND ND ND ND ND ND12-Dec-12 10.0 10 ND ND ND ND ND ND ---ND1-May-13 10.0 10 ND ND ND ND ND ND ND ND5-Aug-13 10.0 10 ND ND ND ND ND ND ---ND24-Feb-14 10.0 10 ND ND ND ND ND ND ND ND12-Aug-14 EPA 6010 10.0 10 ND ND ND ND ND ND ---ND10-Mar-15 EPA 6010 5.0 10 ND ND ND ND ND ND ---ND18-Aug-15 EPA 6010 5.0 10 ND ND ND ND ND ND ---ND16-Feb-16 EPA 6010 5.0 10 ND ND ND ND ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 6 of 19
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Silver 8-Sep-94 ---10 ND ND ND ND ND ND ------1-Dec-94 ---10 ND ND ND ND ND ND ------9-Feb-95 ---10 ND ND ND ND ND ND ------2-Mar-95 ---10 ND ND ND ND ND ND ------15-Nov-95 ---10 ND ND ND ND ND ND ------28-May-96 ---10 ND ND ND ND ND ND ------22-Nov-96 ---10 ND ND ND ND ND ND ------17-Jun-97 ---10 ND ND ND ND ND ND ------1-Dec-97 ---10 ND 8.0 ND ND ND 3 ------20-May-98 ---10 ND ND ND ND ND ND ------19-Nov-98 ---10 ND ND ND ND ND ND ------21-Jul-99 ---10 ND ND ND ND ND ND ------16-Nov-99 ---10 ND ND ND ND ND ND ------10-May-00 ---10 ND ND ND ND ND ND ------26-Oct-00 ---10 ND ND ND ND ND ND ------18-Apr-01 ---10 ND 15.0 ND ND ND ND ------27-Oct-01 ---10 ND ND ND ND ND ND ------13-Jun-02 ---10 ND ND ND ND ND ND ------19-Nov-02 ---10 ND ND ND ND ND ND ------27-Jun-03 ---10 ND ND ND ND ND ND ------30-Dec-03 ---10 ND ND ND ND ND ND ---ND30-Jun-04 ---10 ND ND ND ND ND ND ---ND29-Dec-04 ---10 ND ND ND ND ND ND ---ND29-Jun-05 ---10 ND ND ND ND ND ND ---ND29-Dec-05 ---10 ND ND ND ND ND ND ---ND28-Jun-06 ---10 ND ND ND ND ND ND ---ND29-Dec-06 ---10 ND ND ND ND ND ND ---ND12-Jul-07 ---10 ND ND ND ND ND ND ---NDNC 2L = 17.5 µg/L (10/23/07)19-Dec-07 ---10 ND 0.57 J 0.60 J 0.55 J ND 0.33 J ND ND8-Jul-08 ---10 ND 2.7 J 2.3 J 1.1 J 0.22 J 0.69 J ---0.12 J17-Dec-08 0.10 10.0 0.13 J 1.8 J 1.4 J 0.85 J 0.12 J 0.51 J ---ND9-Jul-09 0.10 10.0 ND 0.84 J 0.63 J 0.45 J ND 0.11 J ND ND16-Dec-09 0.10 10.0 0.12 J 2.0 J 1.6 J 1.0 J 0.12 J 0.52 J ---NDNC 2L = 20 µg/L (02/05/10)24-Jun-10 0.10 10.0 ND 0.38 J 0.33 J 0.35 J ND ND ---ND13-Dec-10 0.10 10.0 0.15 B 1.3 J 0.99 J 0.45 B {ND}{ND}---0.21 {0.19 J}J20-Jun-11 5.0 10.0 ND ND ND ND ND ND ---ND5-Dec-11 5.0 10.0 ND ND ND ND ND ND ---ND11-Jun-12 5.0 10.0 ND ND ND ND ND ND ND ND12-Dec-12 5.0 10.0 ND ND ND ND ND ND ---ND1-May-13 5.0 10.0 ND ND ND ND ND ND ND ND5-Aug-13 5.0 10.0 ND ND ND ND ND ND ---ND24-Feb-14 5.0 10.0 ND ND ND ND ND ND ND ND12-Aug-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ---ND10-Mar-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND18-Aug-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND16-Feb-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND
Thallium 8-Sep-94 ---10 ND ND ND ND ND ND ------1-Dec-94 ---10 ND ND ND ND ND ND ------9-Feb-95 ---10 ND ND ND ND ND ND ------2-Mar-95 ---10 ND ND ND ND ND ND ------15-Nov-95 ---10 ND ND ND ND ND ND ------28-May-96 ---10 ND ND ND ND ND ND ------22-Nov-96 ---10 ND ND ND ND ND ND ------17-Jun-97 ---10 ND 3.0 ND ND ND ND ------1-Dec-97 ---10 ND ND ND ND ND ND ------20-May-98 ---10 ND ND ND ND ND ND ------19-Nov-98 ---10 ND ND ND ND ND ND ------21-Jul-99 ---10 ND ND ND ND ND ND ------16-Nov-99 ---10 ND ND ND ND ND ND ------10-May-00 ---10 ND ND ND ND ND ND ------26-Oct-00 ---10 ND ND ND ND ND ND ------18-Apr-01 ---10 ND ND ND ND ND ND ------27-Oct-01 ---10 ND ND ND ND ND ND ------13-Jun-02 ---10 ND ND ND ND ND ND ------19-Nov-02 ---10 ND ND ND ND ND ND ------27-Jun-03 ---10 ND ND ND ND ND ND ------30-Dec-03 ---10 ND ND ND ND ND ND ---ND30-Jun-04 ---10 ND ND ND ND ND ND ---ND29-Dec-04 ---10 ND 10 J (ND)ND ND ND ND ---ND29-Jun-05 ---10 ND 22.0 (30.0)13.0 (24.0)ND ND ND ---ND29-Dec-05 ---10 ND 23.0 20.0 ND ND ND ---ND28-Jun-06 ---10 ND 25.7 12.6 ND ND ND ---ND29-Dec-06 ---6 ND ND ND ND ND ND ---ND12-Jul-07 ---5.5 ND ND ND ND ND ND ---NDGWPS = 0.28 µg/L (10/23/07)19-Dec-07 ---5.5 ND 4.0 J ND ND ND ND ND ND8-Jul-08 ---5.5 ND ND ND ND ND ND ---ND17-Dec-08 3.0 5.5 ND 3.2 J 3.2 J ND ND ND ---ND9-Jul-09 3.0 5.5 ND ND ND 4.1 J ND ND ND ND16-Dec-09 3.0 5.5 ND ND ND ND ND ND ---ND24-Jun-10 3.0 5.5 ND ND 5.2 J 3.1 J ND ND ---NDGWPS = 0.2 µg/L (10/1/10)13-Dec-10 3.0 5.5 ND ND 7.7 ND ND ND ---ND20-Jun-11 5.4 5.5 ND ND ND ND ND ND ---ND5-Dec-11 5.4 5.5 ND ND ND ND ND ND ---ND11-Jun-12 5.4 5.5 ND ND ND ND ND ND ND ND12-Dec-12 5.4 5.5 ND ND ND ND ND ND ---ND1-May-13 5.4 5.5 ND ND ND ND ND ND ND ND5-Aug-13 5.4 5.5 ND ND ND ND ND ND ---ND24-Feb-14 5.4 5.5 ND ND ND ND ND ND ND ND12-Aug-14 EPA 6010 5.4 5.5 ND ND ND ND ND ND ---ND10-Mar-15 EPA 6010 5.0 5.5 ND ND ND ND ND ND ---ND18-Aug-15 EPA 6010 5.0 5.5 ND ND ND ND ND ND ---ND16-Feb-16 EPA 6010 5.0 5.5 ND ND ND ND ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 7 of 19
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Tin 1-Dec-97 ---100 ND ND ND ND ND ND ------19-Nov-98 ---100 ND ND ND ND ND ND ------16-Nov-99 ---100 ND ND ND ND ND ND ------26-Oct-00 ---100 ---ND ND ND ND ---------18-Apr-01 ---100 ---ND ND ND ND ---------27-Oct-01 ---100 ------------------------13-Jun-02 ---100 ND ND ND ND ND ND ------19-Nov-02 ---100 ------------------------27-Jun-03 ---100 ND 149 127 ND ND ND ------30-Dec-03 ---100 ND ND ND ND ND ND ---ND30-Jun-04 ---100 ND ND ND ND ND ND ---ND29-Dec-04 ---100 ND ND ND ND ND ND ---ND29-Jun-05 ---100 ND ND ND ND ND ND ---ND29-Dec-05 ---100 ND ND ND ND ND ND ---ND28-Jun-06 ---100 ND ND ND ND ND ND ---ND29-Dec-06 ---100 ND 41.1 14.4 3.2 J ND ND ---ND12-Jul-07 ---100 ND 35.2 J 13.9 J 5.2 J ND ND ---NDNC 2L = NE µg/L (10/23/07)19-Dec-07 ---100 ND 33.6 7.4 ND ND ND ND ND8-Jul-08 ---100 4.4 J 28.6 J 15.1 J 5.4 J 3.0 J 3.6 J ---ND17-Dec-08 1.8 100 ND 22.5 J 9.2 J ND ND ND ---ND9-Jul-09 1.8 100 ND 21.4 J 8.6 J ND ND ND ---ND16-Dec-09 1.8 100 ND 26.3 J 10.7 J ND ND ND ---NDGWPS = 2100 µg/L (02/05/10)24-Jun-10 1.8 100 ND 23.4 J 10.7 J 3.2 J 2.2 J 1.9 J ---ND13-Dec-10 1.8 100 ND 30.3 J 12.1 J 5.8 J ND ND ---ND20-Jun-11 5.0 100 ND 26.8 J 13.8 J ND ND ND ---ND5-Dec-11 5.0 100 ND 25.8 J 13.9 J ND ND ND ---ND11-Jun-12 5.0 100 ND 22.2 J 9.0 J ND ND ND ND ND12-Dec-12 5.0 100 ND 30.0 J 13.2 J ND ND ND ---ND1-May-13 5.0 100 ND 25.8 J 12.2 J ND ND ND ---ND5-Aug-13 5.0 100 ND 22.7 J 12.5 J ND ND ND ---ND24-Feb-14 5.0 100 ND 26.7 J 11.7 J 9.8 J ND ND ND ND12-Aug-14 EPA 6010 5.0 100 ND 30.7 J 8.2 J ND ND ND ---ND10-Mar-15 EPA 6010 2.5 100 ND 28.7 J 11.1 J ND ND ND ---ND18-Aug-15 EPA 6010 2.5 100 ND 27.7 J 7.5 J ND ND ND ---ND16-Feb-16 EPA 6010 2.5 100 ND 28.6 J 10.4 J ------------ND
Vanadium 8-Sep-94 ---40 ND ND ND ND ND 130 ------1-Dec-94 ---40 63.0 ND ND 45.0 ND ND ------9-Feb-95 ---40 ND ND ND ND ND ND ------2-Mar-95 ---40 41.0 ND ND 45.0 ND ND ------15-Nov-95 ---40 ND ND ND ND ND ND ------28-May-96 ---40 83.0 ND ND ND ND ND ------22-Nov-96 ---40 7.0 17 ND 21.0 ND ND ------17-Jun-97 ---40 450 560 ND 19.0 ND ND ------1-Dec-97 ---40 62.0 88.0 ND 41.0 ND 10.0 ------20-May-98 ---40 25.0 15.0 ND 10.0 5.0 ND ------19-Nov-98 ---40 33.0 29.0 5.0 16.0 9.0 5.0 ------21-Jul-99 ---40 ND ND ND ND ND ND ------16-Nov-99 ---40 ND ND ND ND ND ND ------10-May-00 ---40 ND ND ND ND ND ND ------26-Oct-00 ---40 ND ND ND ND ND ND ------18-Apr-01 ---40 ND ND ND ND ND ND ------27-Oct-01 ---40 ND ND ND ND ND ND ------13-Jun-02 ---40 ND ND ND ND ND ND ------19-Nov-02 ---40 ND ND ND ND ND ND ------27-Jun-03 ---40 ND ND ND ND ND ND ------30-Dec-03 ---40 ND ND ND ND ND ND ---ND30-Jun-04 ---40 ND ND ND ND ND ND ---ND29-Dec-04 ---40 ND ND ND ND ND ND ---ND29-Jun-05 ---40 ND ND ND ND ND ND ---ND29-Dec-05 ---40 ND ND ND ND ND ND ---ND28-Jun-06 ---40 ND ND ND ND ND ND ---ND29-Dec-06 ---25 2.7 J ND ND 14.5 ND 1.0 J ---ND12-Jul-07 ---25 ND ND ND 19.4 J ND ND ---NDGWPS = 3.5 µg/L (10/23/07)19-Dec-07 ---25 2.2 B 2.2 B ND 15.7 J 3.0 B 1.2 B 4.0 J 0.62 J8-Jul-08 ---25 2.6 J 2.4 J ND 14.6 J 1.4 J 1.2 J ---0.20 J17-Dec-08 0.20 25.0 1.9 B 2.3 B ND 13.9 J 2.5 B 1.2 B ---0.76 J9-Jul-09 0.20 25.0 3.9 B 9.7 J 2.5 B 18.4 J 2.9 B 2.2 B 8.5 J 1.30 J16-Dec-09 0.20 25.0 2.0 B 4.4 J 1.3 B 14.0 J 2.2 B 1.5 B ---0.53 J24-Jun-10 0.20 25.0 1.8 J 4.4 J 1.5 J 13.3 J 2.2 J 1.3 J ---NDGWPS = 0.3 µg/L (10/1/10)13-Dec-10 0.20 25.0 3.2 J 3.6 J 0.35 B 16.6 J 1.8 B 1.0 B ---0.36 J20-Jun-11 5.0 25.0 ND ND ND 14.5 J ND ND ---ND5-Dec-11 5.0 25.0 ND ND ND 13.5 J ND ND ---ND11-Jun-12 5.0 25.0 ND 18.0 J ND 12.3 J ND ND ND ND12-Dec-12 5.0 25.0 ND ND ND 13.6 J ND ND ---ND1-May-13 5.0 25.0 ND ND ND 6.3 J ND ND ND ND5-Aug-13 5.0 25.0 ND ND ND 10.2 J ND ND ---ND24-Feb-14 5.0 25.0 ND ND ND 12.9 J ND ND ND ND12-Aug-14 EPA 6010 5.0 25.0 ND ND ND 18.6 J ND ND ---ND10-Mar-15 EPA 6010 2.5 25.0 3.1 J 11.6 J 6.2 J 13.4 J ND ND ---ND18-Aug-15 EPA 6010 2.5 25.0 3.4 J 6.8 J 3.6 J 19.6 J 2.8 J ND ---ND16-Feb-16 EPA 6010 2.5 25.0 2.7 J 3.3 J ND 14.4 J ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 8 of 19
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Zinc 8-Sep-94 ---50 110 160 ND ND 320 430 ------1-Dec-94 ---50 132 ND ND 70 164 ND ------9-Feb-95 ---50 144 89 ND 91 79 74 ------2-Mar-95 ---50 67 ND ND ND 111 ND ------15-Nov-95 ---50 ND 50 ND ND ND ND ------28-May-96 ---50 136 ND ND ND 122 ND ------22-Nov-96 ---50 79.0 48.0 28.0 ND 38.0 ND ------17-Jun-97 ---50 370 410 33.0 39.0 36.0 69.0 ------1-Dec-97 ---50 140 110 11.0 45.0 34.0 30.0 ------20-May-98 ---50 70.0 63.0 23.0 31.0 47.0 34.0 ------19-Nov-98 ---50 61.0 33.0 21.0 17.0 53.0 10.0 ------21-Jul-99 ---50 ND ND ND ND ND ND ------16-Nov-99 ---50 ND ND ND ND ND ND ------10-May-00 ---50 ND ND ND ND ND ND ------26-Oct-00 ---50 ND ND ND ND ND ND ------18-Apr-01 ---50 ND ND ND ND ND ND ------27-Oct-01 ---50 ND ND ND ND ND ND ------13-Jun-02 ---50 ND ND ND ND 382 ND ------19-Nov-02 ---50 ND ND ND ND ND ND ------27-Jun-03 ---50 ND ND ND ND ND ND ------30-Dec-03 ---50 ND ND ND ND ND ND ---ND30-Jun-04 ---50 ND ND ND ND ND ND ---ND29-Dec-04 ---50 ND ND ND 66.0 ND ND ---ND29-Jun-05 ---50 ND 54.0 56.0 ND ND ND ---ND29-Dec-05 ---50 ND ND ND ND ND ND ---ND28-Jun-06 ---50 ND ND ND ND ND ND ---ND29-Dec-06 ---50 8.0 J ND ND 4.1 J 4.3 J 4.1 J ---ND12-Jul-07 ---10 9.6 J ND ND ND ND ND ---NDNC 2L = 1,050 µg/L (10/23/07)19-Dec-07 ---10 4.3 B 14.3 B 6.3 B ND ND ND 2.4 B 1028-Jul-08 ---10 5.9 B ND ND ND 4.1 B ND ---1.2 J17-Dec-08 0.40 10.0 2.4 B 6.3 J ND ND 4.6 J 0.60 B ---0.49 J9-Jul-09 0.40 10.0 3.4 B ND ND ND ND ND 6.1 B 1.6 J16-Dec-09 0.40 10.0 4.6 B ND ND ND 7.4 B ND ---7.7 JNC 2L = 1,000 µg/L (02/05/10)24-Jun-10 0.40 10.0 0.58 J ND ND ND ND 1.3 J ---ND13-Dec-10 0.40 10.0 4.5 B ND ND ND ND ND ---6.7 J20-Jun-11 10.0 10.0 ND ND ND ND ND ND ---ND5-Dec-11 10.0 10.0 ND ND ND ND ND ND ---12.411-Jun-12 10.0 10.0 ND 20.9 ND ND ND ND ND ND12-Dec-12 10.0 10.0 ND ND ND ND ND ND ---ND1-May-13 10.0 10.0 ND ND ND ND 11.8 ND 10.0 ND5-Aug-13 10.0 10.0 ND ND ND ND ND ND ---ND24-Feb-14 10.0 10.0 ND ND ND ND ND ND ND ND12-Aug-14 EPA 6010 10.0 10.0 ND ND ND ND 16.9 ND ---ND18-Aug-15 EPA 6010 5.0 10.0 7.4 J ND ND ND 5.2 J ND ---ND16-Feb-16 EPA 6010 5.0 10.0 14.5 16.7 17.8 46.1 5.9 J ND ---ND
Cyanide 9-Jul-09 5.0 10 ND ND ND ND 46.9 ND ND ND
Resample >28-Sep-09 5.0 10 ------------ND ------NDNC 2L = 70 µg/L (10/23/07)16-Dec-09 ------------------------------24-Jun-10 5.0 10.0 ND ND ND ND ND ND ---ND
13-Dec-10 ------------------------------Resample >20-Jun-11 5.0 10.0 ND ND ND ND ND ND ---ND5-Dec-11 ------------------------------
11-Jun-12 5.0 10.0 ND 6.4 J ND ND 8.7 J ND ---ND12-Dec-12 ------------------------------1-May-13 5.0 10.0 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------24-Feb-14 5.0 10.0 ND ND ND ND ND ND ND 5.5 J12-Aug-14 5.0 10.0 ND ND ND ND ND ND ND ND10-Mar-15 EPA 6010 5.0 10.0 9.5 B 7.5 B 8.5 B 8.8 B 11.8 B 6.6 B ---5.6 J16-Feb-16 SM 4500-CN-E 4.0 10.0 ND ND ND ------------ND
Granville County
Butner Landfill, Permit No. 39-02 Page 9 of 19
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
ORGANICSAcetone 27-Oct-01 ---100 244 B 109 B ND 130 B 128 B 476 B ---47913-Jun-02 ---100 ND ND ND ND ND ND ------13-Jun-02 ---100 ND ND ND ND ND ND ------19-Nov-02 ---100 ND ND ND ND ND ND ------27-Jun-03 ---100 ND ND ND ND ND ND ------30-Dec-03 ---100 ND ND ND ND ND ND ---ND30-Jun-04 ---100 ND ND ND ND ND ND ---ND29-Dec-04 ---100 ND ND ND ND ND ND ---ND29-Jun-05 ---100 ND ND ND ND ND ND ---ND29-Dec-05 ---100 ND ND ND ND ND ND ---ND28-Jun-06 ---100 ND ND ND ND ND ND ---ND29-Dec-06 ---100 ND ND ND ND ND ND ---ND12-Jul-07 ---100 ND ND ND ND ND ND ---NDNC 2L = 700 µg/L (10/23/07)19-Dec-07 ---100 ND ND ND ND ND ND ND 4.5 J8-Jul-08 ---100 ND ND ND ND ND ND ---ND17-Dec-08 20.0 100 ND ND ND ND ND ND ---ND9-Jul-09 20.0 100 ND ND ND ND ND ND ND ND16-Dec-09 2.2 100 ND ND ND ND ND ND ---2.8 JNC 2L = 6,000 µg/L (02/05/10)24-Jun-10 2.2 100 ND 18.5 B 6.5 B ND 2.2 B ND ---7.7 J13-Dec-10 2.2 100 ND ND ND ND ND ND ---ND20-Jun-11 2.2 100 ND ND ND ND ND 2.4 B ---3.9 J5-Dec-11 2.2 100 ND 2.3 B ND ND ND ND ---8.8 J11-Jun-12 2.2 100 ND 3.5 B ND ND ND ND ND 4.7 J12-Dec-12 10.0 100 ND ND ND ND ND ND ---ND1-May-13 10.0 100 ND ND ND ND ND ND ND 14.6 J5-Aug-13 10.0 100 ND ND ND ND ND ND ---ND24-Feb-14 10.0 100 ND ND ND ND ND ND ND 25.7 J*12-Aug-14 EPA 8260 10.0 100 ND ND ND ND ND ND ND 22.0 J10-Mar-15 EPA 8260 10.0 100 ND ND ND ND ND ND ND ND18-Aug-15 EPA 8260 10.0 100 ND ND ND ND ND ND ND ND16-Feb-16 EPA 8260 10.0 100 ND ND ND ND ND ND ND ND
Benzene 8-Sep-94 ---5 ND ND ND ND ND ND ------1-Dec-94 ---5 ND ND ND ND ND ND ------9-Feb-95 ---5 ND ND ND ND ND ND ------2-Mar-95 ---5 ND ND ND ND ND ND ------15-Nov-95 ---5 ND ND ND ND ND ND ------28-May-96 ---5 ND ND ND ND ND ND ------22-Nov-96 ---5 ND ND ND ND ND ND ------17-Jun-97 ---5 ND ND ND ND ND ND ------1-Dec-97 ---5 ND ND ND ND ND ND ------20-May-98 ---5 ND ND ND ND ND ND ------19-Nov-98 ---5 ND ND ND ND ND ND ------21-Jul-99 ---5 ND ND ND ND ND ND ------16-Nov-99 ---5 ND ND ND ND ND ND ------10-May-00 ---5 ND ND ND ND ND ND ------26-Oct-00 ---5 ND ND ND ND ND ND ------18-Apr-01 ---5 ND ND ND ND ND ND ------27-Oct-01 ---5 ND ND ND ND ND ND ------13-Jun-02 ---5 ND ND ND ND ND ND ------19-Nov-02 ---5 ND ND ND ND ND ND ------27-Jun-03 ---5 ND ND ND ND ND ND ------30-Dec-03 ---5 ND ND ND ND ND ND ---ND30-Jun-04 ---5 ND ND ND ND ND ND ---ND29-Dec-04 ---5 ND ND ND ND ND ND ---ND29-Jun-05 ---5 ND ND ND ND ND ND ---ND29-Dec-05 ---5 ND ND ND ND ND ND ---ND28-Jun-06 ---5 ND ND ND ND ND ND ---ND29-Dec-06 ---3 ND 1.5 ND ND ND ND ---NDResample >23-Feb-07 ---3 ---1.2 ---------------ND12-Jul-07 ---1 ND 1.9 ND ND ND ND ---NDNC 2L = 1 µg/L (10/23/07)19-Dec-07 ---1 ND 1.8 0.48 J 0.26 J ND ND ND ND8-Jul-08 ---1 ND 1.4 0.51 J 0.32 J ND ND ---ND17-Dec-08 0.25 1.0 ND 1.7 0.54 J ND ND ND ---ND9-Jul-09 0.25 1.0 ND 1.7 0.34 J ND ND ND ND ND16-Dec-09 0.25 1.0 ND 1.7 0.60 J 0.29 J ND ND ---ND24-Jun-10 0.25 1.0 ND 0.77 J 0.49 J 0.33 J ND ND ---ND13-Dec-10 0.25 1.0 ND 1.8 0.59 J 0.37 J ND ND ---NDResample >8-Feb-11 0.25 1.0 ---1.4 ---------------ND20-Jun-11 0.25 1.0 ND 1.7 0.60 J 0.39 J ND ND ---ND5-Dec-11 0.25 1.0 ND 1.4 0.69 J 0.40 J ND ND ---ND11-Jun-12 0.25 1.0 ND ND 0.51 J ND ND ND ND ND12-Dec-12 0.25 1.0 ND 1.6 0.73 J 0.32 J ND ND ---NDResample >10-Jan-13 0.25 1.0 ND 1.4 ------------ND ND1-May-13 0.25 1.0 ND 1.3 0.56 J 0.27 J ND ND ND ND5-Aug-13 0.25 1.0 ND 1.6 0.64 J 0.44 J ND ND ---ND24-Feb-14 0.25 1.0 ND 1.4 ND ND ND ND ND ND*12-Aug-14 EPA 8260 0.25 1.0 ND 1.7 0.61 J 0.25 J ND ND ND ND10-Mar-15 EPA 8260 0.25 1.0 ND 1.3 0.54 J ND ND ND ND ND18-Aug-15 EPA 8260 0.25 1.0 ND 1.5 0.66 J 0.32 J ND ND ---ND16-Feb-16 EPA 8260 0.25 1.0 ND 1.3 0.56 J ND ND ND ND ND
Granville County
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Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Bromomethane 17-Dec-08 0.29 10.0 ND ND 0.58 J ND ND ND ---NDNC 2L = NE µg/L (10/23/07)9-Jul-09 0.29 10.0 ND ND ND ND ND ND ND ND16-Dec-09 0.29 10.0 ND ND ND ND ND ND ---ND24-Jun-10 0.29 10.0 ND ND ND ND ND ND ---NDGWPS = 10 µg/L (8/1/10)13-Dec-10 0.29 10.0 ND ND ND ND ND ND ---ND20-Jun-11 0.29 10.0 ND ND ND ND ND ND ---ND5-Dec-11 0.29 10.0 ND ND ND ND ND ND ND ND11-Jun-12 0.29 10.0 ND ND ND ND ND ND ND ND12-Dec-12 0.29 10.0 ND ND ND ND ND ND ---ND1-May-13 0.29 10.0 ND ND ND ND ND ND ND ND5-Aug-13 0.29 10.0 ND ND ND ND ND ND ---ND24-Feb-14 0.29 10.0 ND ND ND ND ND ND ND ND*12-Aug-14 EPA 8260 0.29 10.0 ND ND ND ND ND ND ND ND10-Mar-15 EPA 8260 0.29 10.0 ND ND ND ND ND ND ND ND18-Aug-15 EPA 8260 0.29 10.0 ND ND ND ND ND ND ---ND16-Feb-16 EPA 8260 0.29 10.0 ND ND ND ND ND ND ND ND
2-Butanone (MEK)17-Dec-08 0.96 100 ND ND ND ND 1.2 J ND ---NDNC 2L = 4,200 µg/L (10/23/07)9-Jul-09 0.96 100 ND ND ND ND ND ND ND ND16-Dec-09 0.96 100 ND ND ND ND ND ND ---NDNC 2L = 4,000 µg/L (02/05/10)24-Jun-10 0.96 100 ND ND ND ND ND ND ---ND13-Dec-10 0.96 100 ND ND ND ND ND ND ---ND20-Jun-11 0.96 100 ND ND ND ND ND ND ---ND5-Dec-11 0.96 100 ND ND ND ND ND ND ---ND11-Jun-12 0.96 100 ND ND ND ND ND ND ND ND12-Dec-12 0.96 100 ND ND ND ND ND ND ---ND1-May-13 0.96 100 ND ND ND ND ND ND ND ND8-May-13 0.96 100 ND ND ND ND ND ND ---ND24-Feb-14 0.96 100 ND ND ND ND ND ND ND ND*12-Aug-14 0.96 100 ND ND ND ND ND ND ND ND10-Mar-15 EPA 8260 0.96 100 ND ND ND ND ND ND ND ND18-Aug-15 EPA 8260 0.96 100 ND ND ND ND ND ND ---ND16-Feb-16 EPA 8260 0.96 100 ND ND ND ND ND ND ND ND
Carbon Disulfide 17-Jun-97 ---100 ND 64.0 ND ND ND ND ------1-Dec-97 ---100 ND 5.0 8.0 ND ND ND ------20-May-98 ---100 ND 7.5 6.2 ND ND ND ------19-Nov-98 ---100 ND ND ND ND ND ND ------21-Jul-99 ---100 ND ND ND ND ND ND ------16-Nov-99 ---100 ND ND ND ND ND ND ------10-May-00 ---100 ND ND ND ND ND ND ------26-Oct-00 ---100 ND ND ND ND ND ND ------18-Apr-01 ---100 ND ND ND ND ND ND ------27-Oct-01 ---100 ND ND ND ND ND ND ------13-Jun-02 ---5 ND ND ND ND ND ND ------19-Nov-02 ---100 ND ND ND ND ND ND ------27-Jun-03 ---100 ND ND ND ND ND ND ------30-Dec-03 ---100 ND ND ND ND ND ND ---ND30-Jun-04 ---100 ND ND ND ND ND ND ---ND29-Dec-04 ---100 ND ND ND ND ND ND ---ND29-Jun-05 ---100 ND ND ND ND ND ND ---ND29-Dec-05 ---100 ND ND ND ND ND ND ---ND28-Jun-06 ---100 ND ND ND ND ND ND ---ND29-Dec-06 ---100 ND ND ND ND ND ND ---ND12-Jul-07 ---100 ND ND ND ND ND ND ---NDNC 2L = 700 µg/L (10/23/07)19-Dec-07 ---100 ND ND ND ND ND ND ND ND8-Jul-08 ---100 ND ND ND ND ND ND ---ND17-Dec-08 1.2 100 ND ND ND ND ND ND ---ND9-Jul-09 1.2 100 ND ND ND ND ND ND ND ND16-Dec-09 1.2 100 ND ND ND ND ND ND ---ND24-Jun-10 1.2 100 ND ND ND ND ND ND ---ND13-Dec-10 1.2 100 ND ND ND ND ND ND ---ND20-Jun-11 1.2 100 ND ND ND ND ND ND ---ND5-Dec-11 1.2 100 ND ND ND ND ND ND ---ND11-Jun-12 1.2 100 ND ND ND ND ND ND ND ND12-Dec-12 1.2 100 ND ND ND ND ND ND ---ND1-May-13 1.2 100 ND ND ND ND ND ND ND ND5-Aug-13 1.2 100 ND ND ND ND ND ND ---ND24-Feb-14 1.2 100 ND ND ND ND ND ND ND ND*12-Aug-14 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND10-Mar-15 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND18-Aug-15 EPA 8260 1.2 100 ND ND ND ND ND ND ---ND16-Feb-16 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND
Granville County
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Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Chlorobenzene 8-Sep-94 ---5 ND 10.0 7.0 ND ND ND ------1-Dec-94 ---5 ND ND 7.0 ND ND ND ------9-Feb-95 ---5 ND 13.0 8.0 6.0 ND ND ------2-Mar-95 ---5 ND 12.0 9.0 ND ND ND ------15-Nov-95 ---5 ND 14.0 8.0 9.0 ND ND ------28-May-96 ---5 ND 15.0 9.0 10.0 ND ND ------22-Nov-96 ---5 ND 15.0 ND 11.0 ND ND ------17-Jun-97 ---5 ND 19.0 11.0 14.0 ND ND ------1-Dec-97 ---5 ND 17.0 9.0 14.0 ND ND ------20-May-98 ---5 ND 20.0 8.6 12.0 ND ND ------19-Nov-98 ---5 ND 17.2 9.2 10.0 ND ND ------21-Jul-99 ---5 ND 14.0 10.0 11.0 ND ND ------16-Nov-99 ---5 ND 16.0 10.0 8.0 ND ND ------10-May-00 ---5 ND 17.0 11.0 10.0 ND ND ------26-Oct-00 ---5 ND 16.0 12.0 9.0 ND ND ------18-Apr-01 ---5 ND 16.0 13.0 6.0 ND ND ------27-Oct-01 ---0.5 ND 17.0 12.0 9.0 ND ND ------13-Jun-02 ---0.5 ND 16.0 11.0 8.0 ND ND ------19-Nov-02 ---0.5 ND 18.0 15.0 9.0 ND ND ------27-Jun-03 ---0.5 ND 17.7 13.3 7.4 ND ND ---ND30-Dec-03 ---5 ND 20.0 15.0 6.1 ND ND ---ND30-Jun-04 ---5 ND 18.0 15.0 9.9 ND ND ---ND29-Dec-04 ---5 ND 19.0 16.0 9.4 ND ND ---ND29-Jun-05 ---5 ND 15.0 13.0 8.0 ND ND ---ND29-Dec-05 ---5 ND 18.0 16.0 5.0 ND ND ---ND28-Jun-06 ---5 ND 16.5 10.8 7.8 ND ND ---ND29-Dec-06 ---3 ND 17.0 17.0 4.2 ND ND ---ND12-Jul-07 ---3 ND 17.0 16.0 ND ND ND ---NDNC 2L = 50 µg/L (10/23/07)19-Dec-07 ---3 ND 17.3 16.9 4.7 ND ND ND ND8-Jul-08 ---3 ND 17.2 17.4 6.5 ND ND ---ND17-Dec-08 0.23 3.0 ND 15.9 15.6 2.6 J ND ND ---ND9-Jul-09 0.23 3.0 ND 16.1 17.2 6.1 ND ND ND ND16-Dec-09 0.23 3.0 ND 15.5 17.7 4.8 ND ND ---ND24-Jun-10 0.23 3.0 ND 8.3 15.7 6.3 ND ND ---ND13-Dec-10 0.23 3.0 ND 17.7 18.2 6.4 ND ND ---0.28 J20-Jun-11 0.23 3.0 ND 16.3 17.2 6.7 ND ND ---ND5-Dec-11 0.23 3.0 ND 14.2 17.0 5.8 ND ND ---ND11-Jun-12 0.23 3.0 ND 12 14.8 4.4 ND ND ND ND12-Dec-12 0.23 3.0 ND 15.8 17.9 4.5 ND ND ---ND1-May-13 0.23 3.0 ND 14.0 16.6 3.0 J ND ND ND ND5-Aug-13 0.23 3.0 ND 14.4 15.9 4.6 ND ND ---ND24-Feb-14 0.23 3.0 ND 16.3 2.5 J 1.4 J ND ND ND ND*12-Aug-14 EPA 8260 0.23 3.0 ND 15.6 18.3 3.6 ND ND ND ND10-Mar-15 EPA 8260 0.23 3.0 ND 16.0 17.0 2.1 J ND ND ND ND18-Aug-15 EPA 8260 0.23 3.0 ND 12.8 17.6 4.3 ND ND ---ND16-Feb-16 EPA 8260 0.23 3.0 ND 13.5 16.4 1.5 J ND ND ND ND
Chloroethane 1-Dec-97 ---10 ND 5.0 2.0 2.0 ND ND ------20-May-98 ---10 ND ND ND ND ND ND ------19-Nov-98 ---10 ND ND ND ND ND ND ------21-Jul-99 ---10 ND ND ND ND ND ND ------16-Nov-99 ---10 ND ND ND ND ND ND ------10-May-00 ---10 ND ND ND ND ND ND ------26-Oct-00 ---10 ND ND ND ND ND ND ------18-Apr-01 ---10 ND ND ND ND ND ND ------27-Oct-01 ---10 ND ND ND ND ND ND ------13-Jun-02 ---10 ND ND ND ND ND ND ------19-Nov-02 ---10 ND ND ND ND ND ND ------27-Jun-03 ---10 ND ND ND ND ND ND ------30-Dec-03 ---10 ND ND ND ND ND ND ---ND30-Jun-04 ---10 ND ND ND ND ND ND ---ND29-Dec-04 ---10 ND ND ND ND ND ND ---ND29-Jun-05 ---10 ND ND ND ND ND ND ---ND29-Dec-05 ---10 ND ND ND ND ND ND ---ND28-Jun-06 ---10 ND ND ND ND ND ND ---ND29-Dec-06 ---10 ND 2.2 1.9 ND ND ND ---ND12-Jul-07 ---10 ND ND ND ND ND ND ---NDNC 2L = 2,800 µg/L (10/23/07)19-Dec-07 ---10 ND 1.9 1.9 1.5 ND ND ND ND8-Jul-08 ---10 ND 2.2 J 2.5 J 1.8 J ND ND ---ND17-Dec-08 0.54 10.0 ND 1.6 J ND ND ND ND ---ND9-Jul-09 0.54 10.0 ND ND ND 3.8 J ND ND ND ND16-Dec-09 0.54 10.0 ND ND 2.2 J 2.0 J ND ND ---NDNC 2L = 3,000 µg/L (02/05/10)24-Jun-10 0.54 10.0 ND ND 2.1 J 2.0 J ND ND ---ND13-Dec-10 0.54 10.0 ND 1.8 J 2.0 J 1.7 J ND ND ---ND20-Jun-11 0.54 10.0 ND 1.2 J 2.2 J 2.0 J ND ND ---ND5-Dec-11 0.54 10.0 ND 1.3 J 2.0 J 1.7 J ND ND ---ND11-Jun-12 0.54 10.0 ND ND ND ND ND ND ND ND12-Dec-12 0.54 10.0 ND ND ND ND ND ND ---ND1-May-13 0.54 10.0 ND ND 1.9 J 2.7 J ND ND ND ND5-Aug-13 0.54 10.0 ND ND 2.0 J 2.2 J ND ND ---ND24-Feb-14 0.54 10.0 ND 1.1 J 0.82 J ND ND ND ND ND*12-Aug-14 EPA 8260 0.54 10.0 ND 1.1 J 1.50 J 1.1 J ND ND ND ND10-Mar-15 EPA 8260 0.54 10.0 ND 1.0 J 1.80 J 0.81 J ND ND ND ND18-Aug-15 EPA 8260 0.54 10.0 ND 1.2 J 2.0 J 3.7 J ND ND ---ND16-Feb-16 EPA 8260 0.54 10.0 ND 1.1 J 1.8 J 0.79 J ND ND ND ND
Chloromethane 9-Jul-09 0.11 1.0 ND ND ND ND ND ND ND NDNC 2L = 2.6 µg/L (10/23/07)16-Dec-09 0.11 1.0 ND ND ND ND ND ND ---ND24-Jun-10 0.11 1.0 ND ND ND ND ND 0.11 J ---NDNC 2L = 3 µg/L (02/05/10)13-Dec-10 0.11 1.0 ND ND ND ND ND ND ---ND20-Jun-11 0.11 1.0 ND ND ND ND ND ND ---ND5-Dec-11 0.11 1.0 ND ND ND ND ND ND ---ND11-Jun-12 0.11 1.0 ND ND ND ND ND ND ND ND12-Dec-12 0.11 1.0 ND ND ND ND ND ND ---ND1-May-13 0.11 1.0 ND ND ND ND ND ND ND ND5-Aug-13 0.11 1.0 ND ND ND ND ND ND ---ND24-Feb-14 0.11 1.0 ND ND ND ND ND ND ND 0.25 J12-Aug-14 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND10-Mar-15 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND18-Aug-15 EPA 8260 0.11 1.0 ND ND ND ND ND ND ---ND16-Feb-16 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND
Granville County
Butner Landfill, Permit No. 39-02 Page 12 of 19
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
1,2-Dichlorobenzene 1-Dec-97 ---5 ND 3.0 2.0 1.0 ND ND ------20-May-98 ---5 ND ND ND ND ND ND ------19-Nov-98 ---5 ND 2.4 2.3 ND ND ND ------21-Jul-99 ---5 ND ND ND ND ND ND ------16-Nov-99 ---5 ND ND ND ND ND ND ------10-May-00 ---5 ND ND ND ND ND ND ------26-Oct-00 ---5 ND ND ND ND ND ND ------18-Apr-01 ---5 ND ND ND ND ND ND ------27-Oct-01 ---5 ND ND ND ND ND ND ------13-Jun-02 ---5 ND ND ND ND ND ND ------19-Nov-02 ---5 ND ND ND ND ND ND ------27-Jun-03 ---5 ND ND ND ND ND ND ------30-Dec-03 ---5 ND ND ND ND ND ND ---ND30-Jun-04 ---5 ND ND ND ND ND ND ---ND29-Dec-04 ---5 ND ND ND ND ND ND ---ND29-Jun-05 ---5 ND ND ND ND ND ND ---ND29-Dec-05 ---5 ND ND ND ND ND ND ---ND28-Jun-06 ---5 ND ND ND ND ND ND ---ND29-Dec-06 ---5 ND 1.5 2.3 ND ND ND ---ND12-Jul-07 ---5 ND 1.4 J 1.7 J 0.31 J ND ND ---NDNC 2L = 24 µg/L (10/23/07)19-Dec-07 ---5 ND 1.6 2.0 0.37 J ND ND ND ND8-Jul-08 ---5 ND 1.6 J 2.0 J 0.39 J ND ND ---ND17-Dec-08 0.30 5.0 ND 1.4 J 1.9 J ND ND ND ---ND9-Jul-09 0.30 5.0 ND 1.6 J 2.0 J 0.36 J ND ND ND ND16-Dec-09 0.30 5.0 ND 1.6 J 2.0 J 0.33 J ND ND ---NDNC 2L = 20 µg/L (02/05/10)24-Jun-10 0.30 5.0 ND 0.96 J 1.7 J 0.31 J ND ND ---ND13-Dec-10 0.30 5.0 ND 1.9 J 1.9 J 0.43 J ND ND ---ND20-Jun-11 0.30 5.0 ND 1.5 J 1.7 J 0.37 J ND ND ---ND5-Dec-11 0.30 5.0 ND 1.3 J 1.6 J ND ND ND ---ND11-Jun-12 0.30 5.0 ND 1.0 J 1.5 J ND ND ND ND ND12-Dec-12 0.30 5.0 ND 1.3 J 1.7 J ND ND ND ---ND1-May-13 0.30 5.0 ND 1.2 J 1.6 J ND ND ND ND ND5-Aug-13 0.30 5.0 ND 1.2 J 1.6 J 0.30 J ND ND ---ND24-Feb-14 0.30 5.0 ND 1.4 J 0.64 J ND ND ND ND ND*12-Aug-14 EPA 8260 0.30 5.0 ND 1.2 J 1.5 J ND ND ND ND ND10-Mar-15 EPA 8260 0.30 5.0 ND 1.1 J 1.1 J ND ND ND ND ND18-Aug-15 EPA 8260 0.30 5.0 ND 0.88 J 1.3 J ND ND ND ---ND16-Feb-16 EPA 8260 0.30 5.0 ND 1.1 J 1.4 J ND ND ND ND ND
1,4-Dichlorobenzene 8-Sep-94 ---5 ND ND 5.0 ND ND ND ------1-Dec-94 ---5 ND ND 5.0 ND ND ND ------9-Feb-95 ---5 ND 8.0 6.0 ND ND ND ------2-Mar-95 ---5 ND 7.0 6.0 ND ND ND ------15-Nov-95 ---5 ND 7.0 6.0 ND ND ND ------28-May-96 ---5 ND ND ND ND ND ND ------22-Nov-96 ---5 ND ND ND ND ND ND ------17-Jun-97 ---5 ND 7.6 6.2 ND ND ND ------1-Dec-97 ---5 ND 6.0 5.0 4.0 ND ND ------20-May-98 ---5 ND 7.6 ND ND ND ND ------19-Nov-98 ---5 ND 3.7 2.8 ND ND ND ------21-Jul-99 ---5 ND ND ND ND ND ND ------16-Nov-99 ---5 ND ND ND ND ND ND ------10-May-00 ---5 ND ND ND ND ND ND ------26-Oct-00 ---5 ND 5.0 6.0 ND ND ND ------18-Apr-01 ---5 ND ND 5.0 6.0 ND ND ------27-Oct-01 ---5 ND ND ND ND ND ND ------13-Jun-02 ---5 ND ND ND ND ND ND ------19-Nov-02 ---5 ND ND ND ND ND ND ------27-Jun-03 ---5 ND ND ND ND ND ND ------30-Dec-03 ---5 ND ND ND ND ND ND ---ND30-Jun-04 ---5 ND ND ND ND ND ND ---ND29-Dec-04 ---5 ND ND ND ND ND ND ---ND29-Jun-05 ---5 ND ND ND ND ND ND ---ND29-Dec-05 ---5 ND ND ND ND ND ND ---ND28-Jun-06 ---5 ND ND ND ND ND ND ---ND29-Dec-06 ---3 ND 3.0 3.3 ND ND ND ---NDResample >23-Feb-07 ---3 ---3.2 3.3 ------------ND12-Jul-07 ---1 ND 3.3 2.9 0.31 J ND ND ---NDNC 2L = 1.4 µg/L (10/23/07)19-Dec-07 ---1 ND 3.0 2.7 ND ND ND ND ND8-Jul-08 ---1 ND 3.0 2.4 ND ND ND ---ND17-Dec-08 0.33 1.0 ND 2.9 2.5 ND ND ND ---ND9-Jul-09 0.33 1.0 ND ND ND ND ND ND ND ND16-Dec-09 0.33 1.0 ND 2.8 2.2 ND ND ND ---NDNC 2L = 6 µg/L (02/05/10)24-Jun-10 0.33 1.0 ND 1.6 ND ND ND ND ---ND13-Dec-10 0.33 1.0 ND 3.1 1.9 ND ND ND ---ND20-Jun-11 0.33 1.0 ND 2.7 1.6 ND ND ND ---ND5-Dec-11 0.33 1.0 ND 2.2 1.4 ND ND ND ---ND11-Jun-12 0.33 1.0 ND 1.8 1.4 ND ND ND ND ND12-Dec-12 0.33 1.0 ND 2.4 1.3 ND ND ND ---ND1-May-13 0.33 1.0 ND 2.1 1.2 ND ND ND ND ND5-Aug-13 0.33 1.0 ND 2.0 1.3 ND ND ND ---ND24-Feb-14 0.33 1.0 ND 2.2 1.8 ND ND ND ND ND*12-Aug-14 EPA 8260 0.33 1.0 ND 2.4 1.3 ND ND ND ND ND10-Mar-15 EPA 8260 0.33 1.0 ND 2.2 1.1 ND ND ND ND ND18-Aug-15 EPA 8260 0.33 1.0 ND 1.5 1.1 ND ND ND ---ND16-Feb-16 EPA 8260 0.33 1.0 ND 2.0 1.0 ND ND ND ND ND
Trans-1,4-Dichloro-2-Butene 20-May-98 ---100 ND ND 5.1 ND ND ND ------19-Nov-98 ---100 ND ND ND ND ND ND ------21-Jul-99 ---100 ND ND ND ND ND ND ------16-Nov-99 ---100 ND ND ND ND ND ND ------10-May-00 ---100 ND ND ND ND ND ND ------26-Oct-00 ---100 ND ND ND ND ND ND ------18-Apr-01 ---100 ND ND ND ND ND ND ------27-Oct-01 ---100 ND ND ND ND ND ND ------19-Nov-02 ---100 ND ND ND ND ND ND ------27-Jun-03 ---100 ND ND ND ND ND ND ------30-Dec-03 ---100 ND ND ND ND ND ND ---ND30-Jun-04 ---100 ND ND ND ND ND ND ---ND29-Dec-04 ---100 ND ND ND ND ND ND ---ND29-Jun-05 ---100 ND ND ND ND ND ND ---ND29-Dec-05 ---100 ND ND ND ND ND ND ---ND28-Jun-06 ---100 ND ND ND ND ND ND ---ND29-Dec-06 ---100 ND ND ND ND ND ND ---ND12-Jul-07 ---100 ND ND ND ND ND ND ---NDNC 2L = NE µg/L (10/23/07)19-Dec-07 ---100 ND ND ND ND ND ND ND ND8-Jul-08 ---100 ND ND ND ND ND ND ---ND17-Dec-08 1.0 100 ND ND ND ND ND ND ---ND9-Jul-09 1.0 100 ND ND ND ND ND ND ND ND16-Dec-09 1.0 100 ND ND ND ND ND ND ---ND24-Jun-10 1.0 100 ND ND ND ND ND ND ---ND13-Dec-10 1.0 100 ND ND ND ND ND ND ---ND20-Jun-11 1.0 100 ND ND ND ND ND ND ---ND5-Dec-11 1.0 100 ND ND ND ND ND ND ---ND11-Jun-12 1.0 100 ND ND ND ND ND ND ND ND12-Dec-12 1.0 100 ND ND ND ND ND ND ---ND1-May-13 1.0 100 ND ND ND ND ND ND ND ND5-Aug-13 1.0 100 ND ND ND ND ND ND ---ND24-Feb-14 1.0 100 ND ND ND ND ND ND ND ND*12-Aug-14 EPA 8260 1.0 100 ND ND ND ND ND ND ND ND10-Mar-15 EPA 8260 1.0 100 ND ND ND ND ND ND ND ND18-Aug-15 EPA 8260 1.0 100 ND ND ND ND ND ND ---ND16-Feb-16 EPA 8260 1.0 100 ND ND ND ND ND ND ND ND
Granville County
Butner Landfill, Permit No. 39-02 Page 13 of 19
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
1,1-Dichloroethane 1-Dec-97 ---5 ND ND 1.0 ND ND ND ------20-May-98 ---5 ND ND ND ND ND ND ------19-Nov-98 ---5 ND ND ND ND ND ND ------21-Jul-99 ---5 ND ND ND ND ND ND ------16-Nov-99 ---5 ND ND ND ND ND ND ------10-May-00 ---5 ND ND ND ND ND ND ------26-Oct-00 ---5 ND ND ND ND ND ND ------18-Apr-01 ---5 ND ND ND ND ND ND ------27-Oct-01 ---5 ND ND ND ND ND ND ------13-Jun-02 ---5 ND ND ND ND ND ND ------19-Nov-02 ---5 ND ND ND ND ND ND ------27-Jun-03 ---5 ND ND ND ND ND ND ------30-Dec-03 ---5 ND ND ND ND ND ND ---ND30-Jun-04 ---5 ND ND ND ND ND ND ---ND29-Dec-04 ---5 ND ND ND ND ND ND ---ND29-Jun-05 ---5 ND ND ND ND ND ND ---ND29-Dec-05 ---5 ND ND ND ND ND ND ---ND28-Jun-06 ---5 ND ND ND ND ND ND ---ND29-Dec-06 ---5 ND ND ND ND ND ND ---ND12-Jul-07 ---5 ND ND 0.36 J 0.52 J ND ND ---NDNC 2L = 70 µg/L (10/23/07)19-Dec-07 ---5 ND ND ND 0.57 J ND ND ND ND8-Jul-08 ---5 ND ND ND 0.60 J ND ND ---ND17-Dec-08 0.32 5.0 ND ND ND 0.51 J ND ND ---ND9-Jul-09 0.32 5.0 ND ND ND 0.84 J ND ND ND ND16-Dec-09 0.32 5.0 ND ND ND 0.73 J ND ND ---NDNC 2L = 6 µg/L (02/05/10)24-Jun-10 0.32 5.0 ND ND ND 0.53 J ND ND ---ND13-Dec-10 0.32 5.0 ND ND ND 0.60 J ND ND ---ND20-Jun-11 0.32 5.0 ND ND ND 0.63 J ND ND ---ND5-Dec-11 0.32 5.0 ND ND ND 0.67 J ND ND ---ND11-Jun-12 0.32 5.0 ND ND ND ND ND ND ND ND12-Dec-12 0.32 5.0 ND ND ND 0.61 J ND ND ---ND1-May-13 0.32 5.0 ND ND ND 0.62 J ND ND ND ND8-May-13 0.32 5.0 ND ND ND 0.53 J ND ND ---ND24-Feb-14 0.32 5.0 ND ND ND 0.50 J ND ND ND ND*12-Aug-14 EPA 8260 0.32 5.0 ND ND ND 0.47 J ND ND ND ND10-Mar-15 EPA 8260 0.32 5.0 ND ND ND 0.50 J ND ND ND ND18-Aug-15 EPA 8260 0.32 5.0 ND ND ND 0.49 J ND ND ---ND16-Feb-16 EPA 8260 0.32 5.0 ND ND ND 0.45 J ND ND ND ND
1,2-Dichloroethane 17-Dec-08 0.12 1.0 ND ND 0.15 J ND ND ND ---NDNC 2L = 0.38 µg/L (10/23/07)9-Jul-09 0.12 1.0 ND ND ND ND ND ND ND 0.19 J16-Dec-09 0.12 1.0 ND ND 0.14 J ND ND ND ---NDNC 2L = 0.4 µg/L (02/05/10)24-Jun-10 0.12 1.0 ND ND ND ND ND ND ---ND13-Dec-10 0.12 1.0 ND ND ND ND ND ND ---ND20-Jun-11 0.12 1.0 ND ND ND ND ND ND ---ND5-Dec-11 0.12 1.0 ND ND ND ND 0.18 J ND ---ND11-Jun-12 0.12 1.0 ND ND ND ND ND ND ND ND12-Dec-12 0.12 1.0 ND ND ND ND -0.20 J ND ---0.20 (ND)J1-May-13 0.12 1.0 ND ND ND ND ND ND ND ND5-Aug-13 0.12 1.0 ND ND ND ND ND ND ---ND24-Feb-14 0.12 1.0 ND ND ND ND ND ND ND ND*12-Aug-14 EPA 8260 0.12 1.0 ND ND ND ND ND ND ND ND10-Mar-15 EPA 8260 0.12 1.0 ND ND ND ND ND ND ND ND18-Aug-15 EPA 8260 0.24 1.0 ND ND 0.33 J 0.29 J 0.36 J ND ------16-Feb-16 EPA 8260 0.24 1.0 ND ND ND ND ND ND ND ND
Ethylbenzene 17-Dec-08 0.30 1.0 ND 0.31 J ND ND ND ND ---NDNC 2L = 550 µg/L (10/23/07)9-Jul-09 0.30 1.0 ND ND ND ND ND ND ND ND16-Dec-09 0.30 1.0 ND ND ND ND ND ND ---NDNC 2L = 600 µg/L (02/05/10)24-Jun-10 0.30 1.0 ND ND ND ND ND ND ---ND13-Dec-10 0.30 1.0 ND ND ND ND ND ND ---ND20-Jun-11 0.30 1.0 ND ND ND ND ND ND ---ND5-Dec-11 0.30 1.0 ND ND ND ND ND ND ---ND11-Jun-12 0.30 1.0 ND ND ND ND ND ND ND ND12-Dec-12 0.30 1.0 ND ND ND ND ND ND ---ND1-May-13 0.30 1.0 ND ND ND ND ND ND ND ND5-Aug-13 0.30 1.0 ND ND ND ND ND ND ---ND24-Feb-14 0.30 1.0 ND ND ND ND ND ND ND ND*12-Aug-14 EPA 8260 0.30 1.0 ND ND ND ND ND ND ND ND10-Mar-15 EPA 8260 0.30 1.0 ND ND ND ND ND ND ND ND18-Aug-15 EPA 8260 0.30 1.0 ND ND ND ND ND ND ---ND16-Feb-16 EPA 8260 0.30 1.0 ND ND ND ND ND ND ND ND
Isobutanol 24-Jun-10 35.0 100 ND 59.0 J ND ND ND ND ---NDNC 2L = NE µg/L (02/05/10)13-Dec-10 ------------------------------20-Jun-11 35.0 100 ND 39.5 J ND ND ND ND ---ND5-Dec-11 ------------------------------11-Jun-12 35.0 100.0 ND ND ND ND ND ND ND ND12-Dec-12 ------------------------------1-May-13 35.0 100 ND ND ND ND ND ND ---ND5-Aug-13 ------------------------------24-Feb-14 35.0 100 ND ND ND ND ND ND ---ND*12-Aug-14 35.0 100 ND ND ND ND ND ND ---ND10-Mar-15 EPA 8260 35.0 100 ND ND ND ------------ND16-Feb-16 EPA 8260 35.0 100 ND 42.5 J ND ------------ND
Methylene Chloride 9-Jul-09 0.97 2.0 ND ND ND ND ND ND ND 9.6NC 2L = 4.3 µg/L (10/23/07)16-Dec-09 0.97 2.0 ND ND ND ND ND ND ---ND24-Jun-10 0.97 1.0 ND 19.0 ND ND ND ND ---NDNC 2L = 5 µg/L (02/05/10) Resample >12-Aug-10 0.97 1.0 ---ND ---------------ND13-Dec-10 0.97 1.0 ND ND ND ND ND ND ---ND20-Jun-11 0.97 1.0 ND ND ND ND ND ND ---ND5-Dec-11 0.97 1.0 ND ND ND ND ND ND ---ND11-Jun-12 0.97 1.0 ND ND ND ND ND ND ND ND12-Dec-12 0.97 1.0 ND ND ND ND ND ND ---ND1-May-13 0.97 1.0 ND ND ND ND ND ND ND ND5-Aug-13 0.97 1.0 ND ND ND ND ND ND ---ND24-Feb-14 0.97 1.0 1.0 ND ND ND ND ND ND ND*12-Aug-14 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND10-Mar-15 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND18-Aug-15 EPA 8260 0.97 1.0 1.3 1.1 1.6 ND ND ND ND ND16-Feb-16 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND
Naphthalene 8-Jul-08 ---10 ND 3.8 J ND ND ND ND ---NDNC 2L = 21 µg/L (10/23/07)17-Dec-08 ------------------------------9-Jul-09 0.24 10.0 ND 2.4 J ND ND ND ND ---ND16-Dec-09 ------------------------------NC 2L = 6 µg/L (02/05/10)24-Jun-10 0.24 10.0 ND 7.4 J ND ND ND ND ---ND13-Dec-10 ------------------------------20-Jun-11 0.24 10.0 ND 4.6 J ND ND ND ND ---0.39 J5-Dec-11 --------- ---------------------11-Jun-12 0.2 10.0 ND 4.6 J ND ND ND ND ND ND12-Dec-12 ------------------------------1-May-13 0.24 10.0 ND 5.1 J ND ND ND ND ---ND5-Aug-13 ------------------------------24-Feb-14 0.24 10.0 ND 5.8 J ND ND ND ND ---ND*12-Aug-14 ------------------------------10-Mar-15 EPA 8260 0.2 10 ND 5.4 J ND ------------ND16-Feb-16 EPA 8260 0.2 10 ND 5.7 J ND ------------ND
Granville County
Butner Landfill, Permit No. 39-02 Page 14 of 19
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Toluene 20-May-98 ---5 ND ND 8.1 ND ND ND ------19-Nov-98 ---5 ND ND ND ND ND ND ------21-Jul-99 ---5 ND ND ND ND ND ND ------16-Nov-99 ---5 ND ND ND ND ND ND ------10-May-00 ---5 ND ND ND ND ND ND ------26-Oct-00 ---5 ND ND ND ND ND ND ------18-Apr-01 ---5 ND ND ND ND ND ND ------27-Oct-01 ---5 ND ND ND ND ND ND ------13-Jun-02 ---5 ND ND ND ND ND ND ------19-Nov-02 ---5 ND ND ND ND ND ND ------27-Jun-03 ---5 ND ND ND ND ND ND ----30-Dec-03 ---5 ND ND ND ND ND ND ---ND30-Jun-04 ---5 ND ND ND ND ND ND ---ND29-Dec-04 ---5 ND ND ND ND ND ND ---ND29-Jun-05 ---5 ND ND ND ND ND ND ---ND29-Dec-05 ---5 ND ND ND ND ND ND ---ND28-Jun-06 ---5 ND ND ND ND ND ND ---ND29-Dec-06 ---5 ND ND ND ND ND ND ---ND12-Jul-07 ---1 ND 0.49 B ND ND ND ND ---0.34 JNC 2L = 1,000 µg/L (10/23/07)19-Dec-07 ---1 ND 0.51 J ND ND ND ND ND ND8-Jul-08 ---1 ND 0.39 J ND ND 1.3 ND ---ND17-Dec-08 0.26 1.0 1.4 1.6 ND ND 11.7 ND ---ND9-Jul-09 0.26 1.0 ND 0.46 J ND ND ND ND ND ND16-Dec-09 0.26 1.0 ND 0.42 J ND ND ND ND ---NDNC 2L = 600 µg/L (02/05/10)24-Jun-10 0.26 1.0 ND ND ND ND ND ND ---ND13-Dec-10 0.26 1.0 ND 0.54 J ND ND ND ND ---ND20-Jun-11 0.26 1.0 ND 0.34 J ND ND ND ND ---ND5-Dec-11 0.26 1.0 ND 0.28 J ND ND 0.30 J ND ---ND11-Jun-12 0.26 1.0 ND 0.28 J ND ND ND ND ND ND12-Dec-12 0.26 1.0 ND 0.29 J ND ND 0.36 J ND ---ND1-May-13 0.26 1.0 ND ND ND ND ND ND ND ND5-Aug-13 0.26 1.0 ND 0.29 J ND ND ND ND ---ND24-Feb-14 0.26 1.0 ND ND ND ND ND ND ND ND*12-Aug-14 EPA 8260 0.26 1.0 ND ND ND ND ND ND ND ND10-Mar-15 EPA 8260 0.26 1.0 ND ND ND ND ND ND ND ND18-Aug-15 EPA 8260 0.26 1.0 ND ND ND ND ND ND ---ND16-Feb-16 EPA 8260 0.26 1.0 ND ND ND ND ND ND ND ND
Vinyl Chloride 8-Sep-94 ---10 ND ND 12.0 ND ND ND ------1-Dec-94 ---10 ND ND 13.0 ND ND ND ------9-Feb-95 ---10 ND ND 15.0 ND ND ND ------2-Mar-95 ---10 ND ND 14.0 ND ND ND ------15-Nov-95 ---10 ND ND 11.0 ND ND ND ------28-May-96 ---10 ND ND ND ND ND ND ------22-Nov-96 ---10 ND ND ND ND ND ND ------17-Jun-97 ---10 ND ND ND ND ND ND ------1-Dec-97 ---10 ND ND 7.0 4.0 ND ND ------20-May-98 ---10 ND ND ND ND ND ND ------19-Nov-98 ---10 ND ND ND ND ND ND ------21-Jul-99 ---10 ND ND ND ND ND ND ------16-Nov-99 ---10 ND ND ND ND ND ND ------10-May-00 ---10 ND ND ND ND ND ND ------26-Oct-00 ---10 ND ND ND ND ND ND ------18-Apr-01 ---10 ND ND ND ND ND ND ------27-Oct-01 ---10 ND ND ND ND ND ND ------13-Jun-02 ---10 ND ND ND ND ND ND ------19-Nov-02 ---10 ND ND ND ND ND ND ------27-Jun-03 ---10 ND ND ND ND ND ND ------30-Dec-03 ---10 ND ND ND ND ND ND ---ND30-Jun-04 ---10 ND ND ND ND ND ND ---ND29-Dec-04 ---10 ND ND ND ND ND ND ---ND29-Jun-05 ---10 ND ND ND ND ND ND ---ND29-Dec-05 ---10 ND ND ND ND ND ND ---ND28-Jun-06 ---10 ND ND ND ND ND ND ---ND29-Dec-06 ---5.5 ND ND 0.98 J ND ND ND ---NDResample >23-Feb-07 ---5.5 ------1.0 ------------ND12-Jul-07 ---1 ND ND ND ND ND ND ---NDNC 2L = 0.015 µg/L (10/23/07)19-Dec-07 ---1 ND ND ND ND ND ND ND ND8-Jul-08 ---1 ND ND 0.76 J ND ND ND ---ND17-Dec-08 0.62 1.0 ND ND 0.76 J ND ND ND ---ND9-Jul-09 0.62 1.0 ND ND 0.99 J ND ND ND ND ND16-Dec-09 0.62 1.0 ND ND 0.81 J ND ND ND ---NDNC 2L = 0.03 µg/L (02/05/10)24-Jun-10 0.62 1.0 ND ND 0.77 J ND ND ND ---ND13-Dec-10 0.62 1.0 ND ND ND ND ND ND ---ND20-Jun-11 0.62 1.0 ND ND ND ND ND ND ---ND5-Dec-11 0.62 1.0 ND ND ND ND ND ND ---ND11-Jun-12 0.62 1.0 ND ND ND ND ND ND ND ND12-Dec-12 0.62 1.0 ND ND ND ND ND ND ---ND1-May-13 0.62 1.0 ND ND ND ND ND ND ND ND5-Aug-13 0.62 1.0 ND ND ND ND ND ND ---ND24-Feb-14 0.62 1.0 ND ND ND ND ND ND ND ND*12-Aug-14 EPA 8260 0.62 1.0 ND ND ND ND ND ND ND ND10-Mar-15 EPA 8260 0.62 1.0 ND ND ND ND ND ND ND ND18-Aug-15 EPA 8260 0.62 1.0 ND ND ND ND ND ND ---ND16-Feb-16 EPA 8260 0.62 1.0 ND ND ND ND ND ND ND ND
Granville County
Butner Landfill, Permit No. 39-02 Page 15 of 19
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APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Xylene (Total)29-Dec-06 ---5 ND 1.4 ND ND ND ND ---ND12-Jul-07 ---4 ND 1.2 J ND ND ND ND ---NDNC 2L = 530 µg/L (10/23/07)19-Dec-07 ---4 ND 2.0 ND ND ND ND ND ND8-Jul-08 ---4 ND 1.1 J ND ND ND ND ---ND17-Dec-08 0.66 2.0 1.4 J 2.7 ND ND ND ND ---ND9-Jul-09 0.66 2.0 ND 1.5 J ND ND ND ND ND ND16-Dec-09 0.66 2.0 ND 2.2 ND ND ND ND ---NDNC 2L = 500 µg/L (02/05/10)24-Jun-10 0.66 2.0 ND 0.73 J ND ND ND ND ---ND13-Dec-10 0.66 2.0 ND 2.0 ND ND ND ND ---ND20-Jun-11 0.66 2.0 ND 1.4 J ND ND ND ND ---ND5-Dec-11 0.66 2.0 ND 1.1 J ND ND ND ND ---ND11-Jun-12 0.66 2.0 ND 0.91 J ND ND ND ND ND ND12-Dec-12 0.66 5.0 ND 0.97 J ND ND ND ND ---ND1-May-13 0.66 5.0 ND 0.68 J ND ND ND ND ND ND5-Aug-13 0.66 5.0 ND ND ND ND ND ND ---ND24-Feb-14 0.66 5.0 ND ND ND ND ND ND ND ND*12-Aug-14 0.66 5.0 ND ND ND ND ND ND ND ND10-Mar-15 EPA 8260 0.66 5.0 ND ND ND ND ND ND ND ND18-Aug-15 EPA 8260 0.66 5.0 ND ND ND ND ND ND ---ND16-Feb-16 EPA 8260 0.66 5.0 ND ND ND ND ND ND ND ND
Bis(2-Ethylhexyl)phthalate 24-Feb-14 0.79 15.0 2.6 J ND ND ND ND ND ND NDNC 2L = 3 µg/L (2/5/10)15-Apr-14 0.79 15.0 ND ND ND ND ND ND ND ND12-Aug-14 ------------------------------10-Mar-15 EPA 8270 0.5 15 ND ND ND ------------ND16-Feb-16 EPA 8270 0.9 15 ND ND ND ------------ND
N-Nitroso-di-n-butylamine 24-Feb-14 7.5 10.0 ND ND ND 8.6 J ND ND ND ND12-Aug-14 ------------------------------10-Mar-15 EPA 8270 1.3 10 ND ND ND ------------ND16-Feb-16 EPA 8270 2.2 10 ND ND ND ------------ND
Benzo(g,h,i)perylene 20-Jun-11 0.4 10.0 ND ND ND ND ND 1.4 J ---NDNC 2L = 200 µg/L (2/5/10)5-Dec-11 ------------------------------11-Jun-12 0.38 10.0 ND ND ND ND ND ND ---ND12-Dec-12 ------------------------------1-May-13 0.38 10.0 ND ND ND ND ND ND ---ND5-Aug-13 ------------------------------24-Feb-14 0.38 10.0 ND ND ND ND ND ND ---ND12-Aug-14 ------------------------------10-Mar-15 EPA 8270 0.5 10.0 ND ND ND ------------ND16-Feb-16 EPA 8270 0.4 10.0 ND ND ND ------------ND
Granville County
Butner Landfill, Permit No. 39-02 Page 16 of 19
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APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Dibenz(a,h)anthracene 20-Jun-11 0.55 10.0 ND ND ND ND ND 1.5 J ---NDNC 2L = 0.005 µg/L (2/5/10)5-Dec-11 ------------------------------11-Jun-12 0.55 10.0 ND ND ND ND ND ND ---ND12-Dec-12 ------------------------------1-May-13 0.55 10.0 ND ND ND ND ND ND ---ND5-Aug-13 ------------------------------24-Feb-14 0.55 10.0 ND ND ND ND ND ND ---ND12-Aug-14 ------------------------------10-Mar-15 EPA 8270 0.5 10.0 ND ND ND ------------ND16-Feb-16 EPA 8270 0.6 10.0 ND ND ND ------------ND
Fluorene 24-Jun-10 3.8 12.2 ND 4.3 J ND ND ND ND ---NDNC 2L = 300 µg/L (2/5/10) Resample > 12-Aug-10 3.1 10.0 ---ND ---------------ND13-Dec-10 ------------------------------20-Jun-11 0.2 10.0 ND ND ND ND ND ND ---ND5-Dec-11 ------------------------------11-Jun-12 0.21 10.0 ND ND ND ND ND ND ---ND12-Dec-12 ------------------------------1-May-13 0.21 10.0 ND ND ND ND ND ND ---ND5-Aug-13 ------------------------------24-Feb-14 0.21 10.0 ND ND ND ND ND ND ---ND12-Aug-14 ------------------------------10-Mar-15 EPA 8270 1.0 10.0 ND ND ND ------------ND16-Feb-16 EPA 8270 0.2 10.0 ND ND ND ------------ND
Indeno(1,2,3-cd)pyrene 20-Jun-11 0.29 10.0 ND ND ND ND ND 1.3 J ---NDNC 2L = 0.05 µg/L (2/5/10)5-Dec-11 ------------------------------11-Jun-12 0.29 10.0 ND ND ND ND ND ND ---ND12-Dec-12 ------------------------------1-May-13 0.29 10.0 ND ND ND ND ND ND ---ND5-Aug-13 ------------------------------24-Feb-14 0.29 10.0 ND ND ND ND ND ND ---ND12-Aug-14 ------------------------------10-Mar-15 EPA 8270 0.5 10.0 ND ND ND ------------ND16-Feb-16 EPA 8270 0.3 10.0 ND ND ND ------------ND
2-Methylnaphthalene 24-Jun-10 5.1 12.2 ND 38.9 ND ND ND ND ---NDNC 2L = 30 µg/L (02/05/10) Resample>12-Aug-10 4.2 10 ---ND ---------------ND13-Dec-10 ------------------------------20-Jun-11 0.3 10.0 ND ND ND ND ND ND ---ND5-Dec-11 ------------------------------11-Jun-12 0.28 10.0 ND ND ND ND ND ND ---ND12-Dec-12 ------------------------------1-May-13 0.28 10.0 ND ND ND ND ND ND ---ND5-Aug-13 ------------------------------24-Feb-14 0.28 10.0 ND ND ND ND ND ND ---ND12-Aug-14 ------------------------------10-Mar-15 EPA 8270 1.0 10.0 ND ND ND ------------ND16-Feb-16 EPA 8270 0.3 10.0 ND ND ND ------------ND
Phorate 18-Apr-01 ---10 ---3.2 ND ND ND ---------27-Oct-01 ---5 ND 8.1 ND ND ND ND ------27-Oct-01 ---0.5 ---8.1 1.3 ND ND ---------13-Jun-02 ---5 ND ND ND ND ND ND ------13-Jun-02 ---0.5 ---ND ND ND ND ---------19-Nov-02 ---5 ND ND ND ND ND ND ------27-Jun-03 ---5 ND ND ND ND ND ND ---ND30-Jun-04 ---10 ND ND ND ND ND ND ---ND29-Jun-05 ---10 ND ND ND ND ND ND ---ND29-Dec-05 ------------------------------28-Jun-06 ---10 ND ND ND ND ND ND ---ND29-Dec-06 ------------------------------12-Jul-07 ---10 ND ND ND ND ND ND ---NDNC 2L = 1.4 µg/L (10/23/07)19-Dec-07 ------------------------ND ---8-Jul-08 ---10 ND ND ND ND ND ND ---ND17-Dec-08 ------------------------------9-Jul-09 6.6 22.2 ND ND ND ND ND ND ---ND16-Dec-09 ------------------------------NC 2L = 1 µg/L (02/05/10)24-Jun-10 6.5 24.1 ND ND ND ND ND ND ---ND13-Dec-10 ------------------------------20-Jun-11 5.4 10.0 ND ND ND ND ND ND ---ND5-Dec-11 ------------------------------11-Jun-12 5.4 10.0 ND ND ND ND ND ND ---ND12-Dec-12 ------------------------------1-May-13 5.4 10.0 ND ND ND ND ND ND ---ND5-Aug-13 ------------------------------24-Feb-14 5.4 10.0 ND ND ND ND ND ND ---ND12-Aug-14 ------------------------------10-Mar-15 EPA 8270 0.8 10.0 ND ND ND ------------ND16-Feb-16 EPA 8270 1.1 10.0 ND ND ND ------------ND
Beta-BHC 11-Jun-12 0.050 0.050 ND ND 0.16 ND ND ND ---NDNC 2L = 0.019 µg/L (10/23/07) Resample>19-Jul-12 0.050 0.050 ------ND ---------------12-Dec-12 ------------------------------1-May-13 0.050 0.050 ND ND ND ND ND ND ---ND5-Aug-13 ------------------------------24-Feb-14 0.050 0.050 ND 0.052 ND ND ND ND ---NDResample >15-Apr-14 0.050 0.050 ---ND ---------------ND12-Aug-14 ------------------------------10-Mar-15 EPA 8081 0.1 0.1 ND ND ND ------------ND16-Feb-16 EPA 8081 0.1 0.1 ND ND ND ------------ND
Delta-BHC 11-Jun-12 0.050 0.050 ND ND 0.090 ND ND ND ---NDNC 2L = 0.019 µg/L (10/23/07) Resample>19-Jul-12 0.050 0.050 ------ND ---------------12-Dec-12 ------------------------------1-May-13 0.050 0.050 ND ND ND ND ND ND ---ND5-Aug-13 ------------------------------24-Feb-14 0.050 0.050 ND ND ND ND ND ND ---ND12-Aug-14 ------------------------------10-Mar-15 EPA 8081 0.1 0.1 ND ND ND ------------ND16-Feb-16 EPA 8081 0.1 0.1 ND ND ND ------------ND
Granville County
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APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
gamma-BHC (Lindane)27-Jun-03 ---1.05 ND 0.085 ND ND ND ND ---ND30-Dec-03 ---0.05 ND ND ND ND ND ND ---ND30-Jun-04 ---0.05 ND ND ND ND ND ND ---ND29-Dec-04 ---0.05 ND ND ND ND ND ND ---ND29-Jun-05 ---0.05 ND ND ND ND ND ND ---ND29-Dec-05 ---0.05 ND ND ND ND ND ND ---ND28-Jun-06 ---0.05 ND ND ND ND ND ND ---ND29-Dec-06 ---0.05 ND ND ND ND ND ND ---ND12-Jul-07 ---0.05 ND ND ND ND ND ND ---NDNC 2L = 0.2 µg/L (10/23/07)19-Dec-07 ---0.05 ND ND ND ND ND ND ND ND8-Jul-08 ---0.50 ND ND ND ND ND ND ---ND17-Dec-08 0.050 0.050 ND ND ND ND ND ND ---ND9-Jul-09 0.050 0.050 ND ND ND ND ND ND ---ND16-Dec-09 0.01 0.1 ND ND ND ND ND ND ---NDNC 2L = 0.03 µg/L (02/05/10)24-Jun-10 0.00021 0.010 ND ND 0.052 ND ND ND ---NDResample >12-Aug-10 0.00020 0.010 ------ND ------------ND13-Dec-10 0.00020 0.050 ND ND 0.013 J ND ND ND ---ND20-Jun-11 0.00020 0.050 ND ND 0.066 ND ND ND ---NDResample >28-Jul-11 0.00020 0.010 ------ND ------------ND5-Dec-11 0.050 0.050 ND ND ND ND ND ND ---ND11-Jun-12 0.050 0.050 ND ND ND ND ND ND ---ND12-Dec-12 0.050 0.050 ND ND ND ND ND ND ---ND1-May-13 0.050 0.050 ND ND ND ND ND ND ---ND5-Aug-13 0.050 0.050 ND ND ND ND ND ND ---ND24-Feb-14 0.050 0.050 ND ND ND ND ND ND ---ND12-Aug-14 0.050 0.050 ND ND ND ------------ND10-Mar-15 EPA 8081 0.050 0.050 ND ND ND ------------ND18-Aug-15 EPA 8081 0.050 0.050 ND ND ND ------------ND16-Feb-16 EPA 8081 0.050 0.050 ND ND ND ------------ND
Heptachlor 27-Jun-03 ---1.05 ND 0.03 0.17 ND ND ND ---ND30-Dec-03 ---0.05 ND ND ND ND ND ND ---ND30-Jun-04 ---0.05 ND ND ND ND ND ND ---ND29-Dec-04 ---0.05 ND ND ND ND ND ND ---ND29-Jun-05 ---0.05 ND ND ND ND ND ND ---ND29-Dec-05 ---0.05 ND ND ND ND ND ND ---ND28-Jun-06 ---0.05 ND ND ND ND ND ND ---ND29-Dec-06 ---0.05 ND ND ND ND ND ND ---ND12-Jul-07 ---0.05 ND ND ND ND ND ND ---NDNC 2L = 0.0078 µg/L (10/23/07)19-Dec-07 ---0.05 ND ND ND ND ND ND ND ND8-Jul-08 ---0.05 ND ND ND ND ND ND ---ND17-Dec-08 0.050 0.050 ND ND ND ND ND ND ---ND9-Jul-09 0.050 0.050 ND ND ND ND ND ND ---ND16-Dec-09 0.02 0.1 ND ND ND ND ND ND ---NDNC 2L = 0.008 µg/L (02/05/10)24-Jun-10 0.0015 0.010 ND ND ND ND ND ND ---ND13-Dec-10 0.0500 0.0015 ND ND ND ND ND ND ---ND20-Jun-11 0.050 0.0015 ND ND ND ND ND ND ---ND5-Dec-11 0.050 0.056 ND 0.062 ND ND ND ND ---NDResample >25-Jan-12 0.050 0.0500 ---ND ---------------ND11-Jun-12 0.050 0.050 ND ND ND ND ND ND ---ND12-Dec-12 0.050 0.050 ND ND ND ND ND ND ---ND1-May-13 0.050 0.050 ND ND ND ND ND ND ---ND5-Aug-13 0.050 0.050 ND ND ND ND ND ND ---ND24-Feb-14 0.050 0.050 ND ND ND ND ND ND ---ND12-Aug-14 0.050 0.050 ND ND ND ------------ND10-Mar-15 EPA 8081 0.050 0.050 ND ND ND ------------ND18-Aug-15 EPA 8081 0.050 0.050 ND ND ND ------------ND16-Feb-16 EPA 8081 0.050 0.050 ND ND ND ------------ND
2,4-D 27-Jun-03 ---3 ---5.9 ND ND ND ---------30-Dec-03 ---2 ND ND ND ND ND ND ---ND30-Jun-04 ---2 ND ND ND ND ND ND ---ND29-Dec-04 ---2 ND ND ND ND ND ND ---ND29-Jun-05 ---2 ND ND ND ND ND ND ---ND29-Dec-05 ---2 ND ND ND ND ND ND ---ND28-Jun-06 ---2 ND ND ND ND ND ND ---ND29-Dec-06 ---2 ND ND ND ND ND ND ---ND12-Jul-07 ---2 ND ND ND ND ND ND ---NDNC 2L = 70 µg/L (10/23/07)19-Dec-07 ---2 ND ND ND ND ND ND ND ND8-Apr-08 ---2 ND ND ND ND ND ND ---ND17-Dec-08 ---2.0 ND ND ND ND ND ND ---ND9-Jul-09 ---2.0 ND ND ND ND ND ND ---ND16-Dec-09 0.11 5.0 ND ND ND ND ND ND ---ND24-Jun-10 0.23 2.1 ND ND ND ND ND ND ---ND10-Dec-10 0.22 2.0 ND ND ND ND ND ND ---ND20-Jun-11 0.22 2.0 ND ND ND ND ND ND ---ND5-Dec-11 0.22 2.0 ND ND ND ND ND ND ---ND11-Jun-12 0.22 2.0 ND ND ND ND ND ND ---ND12-Dec-12 0.22 2.0 ND ND ND ND ND ND ---ND1-May-13 0.22 2.0 ND ND ND ND ND ND ---ND5-Aug-13 0.22 2.0 ND ND ND ND ND ND ---ND24-Feb-14 0.22 2.0 ND ND ND ND ND ND ---ND12-Aug-14 EPA 8151 0.22 2.0 ND ND ND ------------ND10-Mar-15 EPA 8151 0.24 2.1 ND ND ND ------------ND18-Aug-15 EPA 8151 0.24 2.1 ND ND ND ------------ND16-Feb-16 EPA 8151 0.23 1.0 ND ND ND ------------ND
4,4'-DDD 11-Jun-12 0.05 0.05 ND ND 0.13 ND ND ND ---NDNC 2L = 0.1 µg/L (2/5/10) Resample>19-Jul-12 0.05 0.10 ------ND ---------------12-Dec-12 ------------------------------1-May-13 0.050 0.10 ND ND ND ND ND ND ---ND5-Aug-13 ------------------------------24-Feb-14 0.050 0.10 ND ND ND ND ND ND ---ND12-Aug-14 ------------------------------10-Mar-15 EPA 8081 0.1 0.1 ND ND ND ------------ND16-Feb-16 EPA 8081 0.1 0.1 ND ND ND ------------ND
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APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
4,4'-DDT 11-Jun-12 0.05 0.05 ND ND 0.10 ND ND ND ---NDNC 2L = 0.1 µg/L (2/5/10) Resample>19-Jul-12 0.05 0.10 ------0.063 J ---------------12-Dec-12 ------------------------------1-May-13 0.050 0.10 ND ND ND ND ND ND ---ND5-Aug-13 ------------------------------24-Feb-14 0.050 0.10 ND ND ND ND ND ND ---ND12-Aug-14 ------------------------------10-Mar-15 EPA 8081 0.1 0.1 ND ND ND ------------ND16-Feb-16 EPA 8081 0.1 0.1 ND ND ND ------------ND
Dinoseb 10-Mar-15 EPA 8151 0.1 1.1 ND ND 0.11 J ------------ND16-Feb-16 EPA 8151 0.1 0.2 ND ND ND ------------ND
Endrin aldehyde 11-Jun-12 0.050 0.050 ND ND 0.14 ND ND ND ------NC 2L= 2 (2/5/10)12-Dec-12 0.050 0.10 ND ND ND ND ND ND ------1-May-13 0.050 0.10 ND ND ND ND ND ND ---ND5-Aug-13 0.050 0.10 ND ND ND ND ND ND ---ND24-Feb-14 0.050 0.10 ND ND ND ND ND ND ---ND12-Aug-14 EPA 8081 0.050 0.10 ND ND ND ------------ND10-Mar-15 EPA 8081 0.050 0.10 ND ND ND ------------ND18-Aug-15 EPA 8081 0.050 0.10 ND ND ND ------------ND16-Feb-16 EPA 8081 0.050 0.10 ND ND ND ------------ND
Notes:All concentrations are in micrograms per liter (µg/L).RL = Reporting Limit (SWSL for December 2006 - present).DL = Laboratory detection limit.J = Estimated value between the DL and the RL.B = Blank-qualified data; result is expected to be biased high based on concentrations in the blanks.ND = Not detected above laboratory reporting limit.NC 2L = North Carolina Groundwater Standards from 15A NCAC 2L.0202.GWPS = Groundwater Protection Standards established by the DENR Solid Waste Section (SWS).When the NC 2L has not been established, the GWPS will be used.Bold values for groundwater are above the NC 2L Standards or GWPS.--- = Well was not monitored and/or not reported.
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Appendix D

Historical Surface Water Analytical Data

APPENDIX D: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
INORGANICS
Arsenic 06/24/10 2.7 10.00 4.30 J 2.90 J ND
NC 2B = 10 µg/L (03/28/08)12/13/10 2.7 10.0 ND ND ND06/20/11 5.0 10.0 ND ND ND
12/05/11 5.0 10.0 ND ND ND
06/11/12 5.0 10.0 ND ND ND12/12/12 5.0 10.0 ND ND ND05/01/13 5.0 10.0 ND ND ND
08/05/13 5.0 10.0 ND ND ND
02/24/14 5.0 10.0 ND ND ND08/12/14 EPA 6010 5.0 10.0 ---ND ND03/10/15 EPA 6010 2.5 10.0 ND ND 3.0 J
08/18/15 ------Dry Dry ---
02/16/16 EPA 6010 2.5 10.0 ND ND ND
Barium 11/22/96 ---500 37.0 37.0 ---
06/17/97 ---500 37.0 62.0 ---12/01/97 ---500 53.0 45.0 ---05/20/98 ---500 24.0 69.0 ---
11/19/98 ---500 ND 100.0 ---
07/21/99 ---500 ND ND ---11/16/99 ---500 ND ND ---05/10/00 ---500 ND ND ---
10/26/00 ---500 ND ND ---
04/18/01 ---500 ND ND ---10/27/01 ---500 ND ND ---06/13/02 ---500 ---------
11/19/02 ---500 ND ND ---
06/27/03 ---500 ND ND ---12/30/03 ---500 ND ND ND06/30/04 ---500 ND ND ND
12/29/04 ---500 ND ND ND
12/29/04 ---500 ND ND ND
06/29/05 ---500 ND ND ND12/29/05 ---500 ND ND ND
06/28/06 ---500 ND ND ND
12/29/06 ---100 37.5 40.6 0.20 J
07/12/07 ---100 33.3 J ---ND12/19/07 ---100 52.6 B 149.0 11.7
NC 2B = 1,000 µg/L (03/28/08)07/08/08 ---100 33.8 J 161.0 0.3 J
12/17/08 0.2 100 30.2 B 33.5 B 10.7 J
07/09/09 0.2 100 36.8 B 78.4 B 17.6 J12/16/09 0.2 100 31.2 B 36.2 B 17.1 J06/24/10 0.2 100 34.5 B 71.3 B 27.3 J
12/13/10 0.2 100 36.1 B 91.0 J 12.1 J
06/20/11 5.0 100 40.3 J 93.0 J ND12/05/11 5.0 100 32.9 J 59.0 J ND06/11/12 5.0 100 40.0 J 95.6 J ND
12/12/12 5.0 100 45.0 J 97.8 J ND
05/01/13 5.0 100 32.7 J 43.1 J ND08/05/13 5.0 100 49.9 J 79.8 J ND02/24/14 5.0 100 29.0 J 30.4 J ND
08/12/14 EPA 6010 5.0 100 ---121 ND
03/10/15 EPA 6010 2.5 100 29.0 J 32.1 J ND
08/18/15 ------Dry Dry ---02/16/16 EPA 6010 2.5 100 33.1 J 33.5 J ND
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APPENDIX D: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
Beryllium 07/08/08 ---1.0 0.32 J ND ND
12/17/08 0.1 1.0 ND ND ND07/09/09 0.1 1.0 ND ND ND12/16/09 0.1 1.0 0.12 J ND ND
NC 2B = 6.5 µg/L (02/05/10)06/24/10 0.1 1.0 ND ND ND
12/13/10 0.1 1.0 ND ND ND06/20/11 1.0 1.0 ND ND ND12/05/11 1.0 1.0 ND ND ND
06/11/12 1.0 1.0 ND ND ND
12/12/12 1.0 1.0 ND ND ND05/01/13 1.0 1.0 ND ND ND08/05/13 1.0 1.0 ND ND ND
02/24/14 1.0 1.0 ND ND ND
08/12/14 EPA 6010 1.0 1.0 ---ND ND
03/10/15 EPA 6010 0.5 1.0 ND ND ND08/18/15 ------Dry Dry ---
02/16/16 EPA 6010 0.5 1.0 ND ND ND
Chromium 06/17/97 ---10.0 ND 3.00 ---
12/01/97 ---10.0 ND ND ---
05/20/98 ---10.0 ND ND ---11/19/98 ---10.0 ND ND ---07/21/99 ---10.0 ND ND ---
11/16/99 ---10.0 ND ND ---
05/10/00 ---10.0 ND ND ---10/26/00 ---10.0 ND ND ---04/18/01 ---10.0 ND ND ---
10/27/01 ---10.0 ND ND ---
06/13/02 ---10.0 ---------11/19/02 ---10.0 ND ND ---06/27/03 ---10.0 ND ND ---
12/30/03 ---10.0 ND ND ND
06/30/04 ---10.0 ND ND ND
12/29/04 ---10.0 ND ND ND06/29/05 ---10.0 ND ND ND
12/29/05 ---10.0 ND ND ND
06/28/06 ---10.0 ND ND ND
12/29/06 ---10.0 ND ND ND07/12/07 ---10.0 ND ---ND
12/19/07 ---10.0 2.20 B 2.60 B 1.40 J
NC 2B = 50 µg/L (03/28/08)07/08/08 ---10.0 2.50 J 2.20 J ND
12/17/08 0.4 10.0 1.40 J 2.60 J ND07/09/09 0.4 10.0 2.6 J 1.2 J ND12/16/09 0.4 10.0 4.1 J 3.4 J ND
06/24/10 0.4 10.0 3.3 B 7.3 J 0.71 J
12/13/10 0.4 10.0 1.4 J 1.5 J ND06/20/11 5.0 10.0 ND ND ND12/05/11 5.0 10.0 ND ND ND
06/11/12 5.0 10.0 ND 7.2 J ND
12/12/12 5.0 10.0 ND 8.2 J ND05/01/13 5.0 10.0 5.7 J ND ND08/05/13 5.0 10.0 ND ND ND
02/24/14 5.0 10.0 ND ND ND
08/12/14 EPA 6010 5.0 10.0 ---ND ND
03/10/15 EPA 6010 2.5 10.0 4.4 J 3.6 J ND08/18/15 ------Dry Dry ---
02/16/16 EPA 6010 2.5 10.0 4.6 J 6.8 J ND
Granville County
Butner Landfill, Permit No. 39-02 Page 2 of 8
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APPENDIX D: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
Cobalt 05/20/98 ---10 2.0 2.0 ---
11/19/98 ---10 ND 3.0 ---07/21/99 ---10 ND ND ---11/16/99 ---10 ND ND ---
05/10/00 ---10 ND ND ---
10/26/00 ---10 ND ND ---04/18/01 ---10 ND ND ---10/27/01 ---10.0 ND 22.0 ---
06/13/02 ---10.0 ---------
11/19/02 ---10.0 ND ND ---06/27/03 ---10.0 ND 10.0 ---12/30/03 ---10.0 ND ND ND
06/30/04 ---10.0 ND ND ND
12/29/04 ---10.0 ND ND ND
06/29/05 ---10.0 ND ND ND12/29/05 ---10.0 ND ND ND
06/28/06 ---10.0 ND ND ND
12/29/06 ---10.0 ND ND ND
07/12/07 ---10.0 ND ---ND12/19/07 ---10.0 4.2 B 1.20 B 1.8 J
07/08/08 ---10.0 4.80 B 10.5 B 6.20 J
12/17/08 0.6 10.0 1.70 B 1.1 B 2.50 J
07/09/09 0.6 10.0 ND ND ND12/16/09 0.6 10.0 ND 1.0 J NDNC 2B = NE µg/L (03/24/10)06/24/10 0.6 10.0 ND ND ND
12/13/10 0.6 10.0 {4.4}B {ND}1.6 {1.0 J}J
06/20/11 5.0 10.0 ND ND ND12/05/11 5.0 10.0 ND ND NDResample >01/25/12 5.0 10.0 ------ND
06/11/12 5.0 10.0 ND 5.10 J ND
12/12/12 5.0 10.0 ND ND ND05/01/13 5.0 10.0 ND ND ND08/05/13 5.0 10.0 ND ND ND
02/24/14 5.0 10.0 ND ND ND
08/12/14 EPA 6010 5.0 10.0 ---ND ND03/10/15 EPA 6010 2.5 10.0 ND ND ND08/18/15 ------Dry Dry ---
02/16/16 EPA 6010 2.5 10.0 ND ND ND
Copper 12/29/06 ---10.0 1.3 B 1.10 B 0.60 J
07/12/07 ---10.0 ND ---ND
12/19/07 ---10.0 5.3 B ND 9.8NC 2B = 7 µg/L (03/28/08)07/08/08 ---10.0 1.7 J 4.20 J ND12/17/08 0.3 10.0 1.40 J 1.50 J ND
07/09/09 0.3 10.0 ND ND ND
12/16/09 0.3 10.0 1.90 J 2.00 J ND06/24/10 0.3 10.0 ND 3.10 J ND12/13/10 0.3 10.0 0.31 B ND 0.49 J
06/20/11 5.0 10.0 ND ND ND
12/05/11 5.0 10.0 ND ND ND06/11/12 5.0 10.0 ND 5.50 J ND12/12/12 5.0 10.0 ND ND ND
05/01/13 5.0 10.0 ND ND ND
08/05/13 5.0 10.0 ND ND ND
02/24/14 5.0 10.0 ND ND ND08/12/14 EPA 6010 5.0 10.0 ---ND ND
03/10/15 EPA 6010 2.5 10.0 ND ND ND
08/18/15 ------Dry Dry ---
02/16/16 EPA 6010 2.5 10.0 2.90 J 3.40 J ND
Granville County
Butner Landfill, Permit No. 39-02 Page 3 of 8
Joyce Engineering
APPENDIX D: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
Lead 05/20/98 ---10.0 ND 8.00 ---
11/19/98 ---10.0 ND ND ---07/21/99 ---10.0 ND 10.0 ---11/16/99 ---10.0 ND ND ---
05/10/00 ---10.0 ND ND ---
10/26/00 ---10.0 ND ND ---04/18/01 ---10.0 ND ND ---10/27/01 ---10.0 ND ND ---
06/13/02 ---10.0 ---------
11/19/02 ---10.0 ND ND ---06/27/03 ---10.0 ND ND ---12/30/03 ---10.0 ND ND ND
06/30/04 ---10.0 ND ND ND
12/29/04 ---10.0 ND ND ND
06/29/05 ---10.0 ND ND ND12/29/05 ---10.0 ND ND ND
06/28/06 ---10.0 ND ND ND
12/29/06 ---10.0 ND ND ND
07/12/07 ---10.0 ND ---ND12/19/07 ---10.0 ND ND ND
NC 2B = 25 µg/L (03/28/08)07/08/08 ---10.0 ND ND ND
12/17/08 4.0 10.0 ND ND ND
07/09/09 4.0 10.0 ND ND ND12/16/09 4.0 10.0 ND ND ND06/24/10 4.0 10.0 ND ND ND
12/13/10 4.0 10.0 ND ND ND
06/20/11 5.0 10.0 ND ND ND12/05/11 5.0 10.0 ND ND ND06/11/12 5.0 10.0 ND ND ND
12/12/12 5.0 10.0 ND ND ND
05/01/13 5.0 10.0 ND ND ND08/05/13 5.0 10.0 ND ND ND02/24/14 5.0 10.0 ND ND ND
08/12/14 EPA 6010 5.0 10.0 ---ND ND
03/10/15 EPA 6010 2.5 10.0 ND ND ND08/18/15 ------Dry Dry ---02/16/16 EPA 6010 2.5 10.0 ND ND ND
Nickel 12/29/04 ---50.0 ND 50.0 (ND)ND
06/29/05 ---50.0 ND ND ND
12/29/05 ---50.0 ND ND ND
06/28/06 ---50.0 ND ND ND12/29/06 ---50.0 ND 2.9 J ND07/12/07 ---50.0 3.8 J ---ND
12/19/07 ---50.0 6.0 31.5 ND
NC 2B = 25 µg/L (03/28/08)07/08/08 ---50.0 3.2 J 29.8 J ND12/17/08 1.7 50.0 2.4 B 4.0 B 2.4 J07/09/09 1.7 50.0 4.1 J 12.3 J ND
12/16/09 1.7 50.0 3.8 B 4.4 B 3.0 J
06/24/10 1.7 50.0 ND 2.0 J ND12/13/10 1.7 50.0 ND 14.2 J 2.7 J06/20/11 5.0 50.0 ND 7.8 J ND
12/05/11 5.0 50.0 ND 5.3 J ND
06/11/12 5.0 50.0 ND 11.0 J ND
12/12/12 5.0 50.0 ND 13.8 J ND05/01/13 5.0 50.0 ND ND ND
08/05/13 5.0 50.0 ND 5.6 J ND
02/24/14 5.0 50.0 ND ND ND
08/12/14 EPA 6010 5.0 50.0 ---20.3 J ND03/10/15 EPA 6010 2.5 50.0 3.0 J 3.8 J ND
08/18/15 ------Dry Dry ---
02/16/16 EPA 6010 2.5 50.0 2.9 J 4.7 J ND
Granville County
Butner Landfill, Permit No. 39-02 Page 4 of 8
Joyce Engineering
APPENDIX D: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
Silver 07/12/07 ---10.0 2.20 J ---ND
12/19/07 ---10.0 ND 0.34 J NDNC 2B = 0.06 µg/L (03/28/08)07/08/08 ---10.0 0.35 B 1.00 J 0.12 J12/17/08 0.1 10.0 ND ND ND
07/09/09 0.1 10.0 ND 0.10 J ND
12/16/09 0.1 10.0 ND 0.16 J ND06/24/10 0.1 10.0 ND 0.26 J ND12/13/10 0.1 10.0 {ND}{0.28}B 0.21 {0.19 J}J
06/20/11 5.0 10.0 ND ND ND
12/05/11 5.0 10.0 ND ND ND06/11/12 5.0 10.0 ND ND ND12/12/12 5.0 10.0 ND ND ND
05/01/13 5.0 10.0 ND ND ND
08/05/13 5.0 10.0 ND ND ND
02/24/14 5.0 10.0 ND ND ND08/12/14 EPA 6010 5.0 10.0 ---ND ND
03/10/15 EPA 6010 2.5 10.0 ND ND ND
08/18/15 ------Dry Dry ---
02/16/16 EPA 6010 2.5 10.0 ND ND ND
Thallium 12/29/04 ---10.0 ND 10.0 (ND)ND
06/29/05 ---10.0 ND ND ND12/29/05 ---10.0 ND ND ND
06/28/06 ---10.0 ND ND ND
12/29/06 ---6.00 ND ND ND07/12/07 ---5.5 ND ---ND12/19/07 ---5.5 3.60 J ND ND
07/08/08 ---5.5 3.40 J ND ND
12/17/08 3.0 5.5 ND ND ND07/09/09 3.0 5.5 ND ND ND12/16/09 3.0 5.5 ND ND ND
NC 2B = NE (03/24/10)06/24/10 3.0 5.5 ND ND ND
12/13/10 3.0 5.5 3.80 J ND ND
06/20/11 5.4 5.5 ND ND ND12/05/11 5.4 5.5 ND ND ND
06/11/12 5.4 5.5 ND ND ND
12/12/12 5.4 5.5 ND ND ND
05/01/13 5.4 5.5 ND ND ND08/05/13 5.4 5.5 ND ND ND
02/24/14 5.4 5.5 ND ND ND
08/12/14 EPA 6010 5.4 5.5 ---ND ND
03/10/15 EPA 6010 5.0 5.5 ND ND ND08/18/15 ------Dry Dry ---02/16/16 EPA 6010 5.0 5.5 ND ND ND
Vanadium 12/29/06 ---25.0 1.60 J 2.00 J ND
07/12/07 ---25.0 4.60 J ---ND
12/19/07 ---25.0 3.30 J 1.40 B 0.62 J
NC 2B = NE µg/L (03/28/08)07/08/08 ---25.0 5.20 J 2.30 J 0.20 J12/17/08 0.2 25.0 1.80 B 2.70 B 0.76 J
07/09/09 0.2 25.0 5.00 B 3.40 B 1.30 J
12/16/09 0.2 25.0 3.60 J 3.50 J 0.53 J
06/24/10 0.2 25.0 5.80 J 2.60 J ND12/13/10 0.2 25.0 1.60 B 0.67 B 0.36 J
06/20/11 5.0 25.0 ND ND ND
12/05/11 5.0 25.0 ND ND ND
06/11/12 5.0 25.0 ND 11.50 J ND12/12/12 5.0 25.0 ND ND ND05/01/13 5.0 25.0 ND ND ND
08/05/13 5.0 25.0 ND ND ND
02/24/14 5.0 25.0 ND ND ND08/12/14 EPA 6010 5.0 25.0 ---ND ND03/10/15 EPA 6010 2.5 25.0 3.9 J 4.7 J ND
08/18/15 ------Dry Dry ---
02/16/16 EPA 6010 2.5 25.0 4.1 J 5.8 J ND
Granville County
Butner Landfill, Permit No. 39-02 Page 5 of 8
Joyce Engineering
APPENDIX D: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
Zinc 11/22/96 ---50.0 11.0 ND ---
06/17/97 ---50.0 ND ND ---12/01/97 ---50.0 20.0 ND ---05/20/98 ---50.0 20.0 28.0 ---
11/19/98 ---50.0 ND ND ---
07/21/99 ---50.0 ND ND ---11/16/99 ---50.0 ND ND ---05/10/00 ---50.0 ND ND ---
10/26/00 ---50.0 ND ND ---
04/18/01 ---50.0 ND ND ---10/27/01 ---50.0 ND ND ---06/13/02 ---50.0 ---------
11/19/02 ---50.0 ND ND ---
06/27/03 ---50.0 ND ND ---
12/30/03 ---50.0 ND ND ND06/30/04 ---50.0 ND ND ND
12/29/04 ---50.0 ND ND ND
06/29/05 ---50.0 ND ND ND
12/29/05 ---50.0 ND ND ND06/28/06 ---50.0 ND ND ND
12/29/06 ---50.0 ND ND ND
07/12/07 ---10.0 ND ---ND
12/19/07 ---10.0 24.6 B ND 102NC 2B = 50 µg/L (03/28/08)07/08/08 ---10.0 ND ND 1.20 J12/17/08 0.4 10.0 ND 0.89 B 0.49 J
07/09/09 0.4 10.0 ND 4.90 B 1.60 J
12/16/09 0.4 10.0 2.60 B 2.60 B 7.70 J06/24/10 0.4 10.0 ND 14.9 ND12/13/10 0.4 10.0 ND 9.80 B 6.70 J
06/20/11 10.0 10.0 ND ND ND
12/05/11 10.0 10.0 ND ND 12.406/11/12 10.0 10.0 ND ND ND12/12/12 10.0 10.0 ND ND ND
05/01/13 10.0 10.0 ND 16.80 ND
08/05/13 10.0 10.0 ND ND ND02/24/14 10.0 10.0 ND ND ND08/12/14 EPA 6010 10.0 10.0 ---ND ND
03/10/15 EPA 6010 5.0 10.0 7.7 B 7.8 B 5.6 J
08/18/15 ------Dry Dry ---
02/16/16 EPA 6010 5.0 10.0 7.0 J ND ND
Granville County
Butner Landfill, Permit No. 39-02 Page 6 of 8
Joyce Engineering
APPENDIX D: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
ORGANICS
Acetone 10/27/01 ---100 168.0 B 337.0 B 479.0
06/13/02 ---100 ---------06/13/02 ---100 ---------
11/19/02 ---100 ND ND ---
06/27/03 ---100 ND ND ---12/30/03 ---100 ND ND ND06/30/04 ---100 ND ND ND
12/29/04 ---100 ND ND ND
06/29/05 ---100 ND ND ND12/29/05 ---100 ND ND ND06/28/06 ---100 ND ND ND
12/29/06 ---100 ND ND ND
07/12/07 ---100 ND ---ND
12/19/07 ---100 12.70 B ND 4.50 JNC 2B = 2,000 µg/L (03/28/08)07/08/08 ---100 ND ND ND
12/17/08 20 100 ND ND ND
07/09/09 20 100 ND ND ND
NC 2B = NE (03/24/10)12/16/09 2.2 100 ND ND 2.80 J06/24/10 2.2 100 2.80 B ND 7.70 J
12/13/10 2.2 100 ND 3.00 J ND
06/20/11 2.2 100 ND 3.80 B 3.90 J
12/05/11 2.2 100 ND 7.20 B 8.80 J06/11/12 2.2 100 ND 5.50 B 4.70 J12/12/12 10.0 100 ND ND ND
05/01/13 10.0 100 ND ND 14.6 J
08/05/13 10.0 100 ND ND ND02/24/14 10.0 100 ND ND 25.7 J08/12/14 EPA 8260 10.0 100 ---ND 22.0 J
03/10/15 EPA 8260 10.0 100 ND ND ND
08/18/15 ------Dry Dry ---02/16/16 EPA 8260 10.0 100 ND ND ND
Granville County
Butner Landfill, Permit No. 39-02 Page 7 of 8
Joyce Engineering
APPENDIX D: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
Chlorobenzene 06/27/03 ---5.0 ND 7.20 ND
12/30/03 ---5.0 ND ND ND06/30/04 ---5.0 ND ND ND12/29/04 ---5.0 ND ND ND
06/29/05 ---5.0 ND ND ND
12/29/05 ---5.0 ND ND ND06/28/06 ---5.0 ND ND ND12/29/06 ---3.0 ND ND ND
07/12/07 ---3.0 ND ---ND
12/19/07 ---3.0 ND ND NDNC 2B = 130 µg/L (03/28/08)07/08/08 ---3.0 ND ND ND12/17/08 0.23 3.0 ND ND ND
07/09/09 0.23 3.0 ND ND ND
12/16/09 0.23 3.0 ND ND ND
06/24/10 0.23 3.0 ND ND ND12/13/10 0.23 3.0 ND ND 0.28 J
06/20/11 0.23 3.0 ND ND ND
12/05/11 0.23 3.0 ND ND ND
06/11/12 0.23 3.0 ND ND ND12/12/12 0.23 3.0 ND ND ND
05/01/13 0.23 3.0 ND ND ND
08/05/13 0.23 3.0 ND ND ND
02/24/14 0.23 3.0 ND ND ND08/12/14 EPA 8260 0.23 3.0 ---ND ND03/10/15 EPA 8260 0.23 3.0 ND ND ND
08/18/15 ------Dry Dry ---
02/16/16 EPA 8260 0.23 3.0 ND ND ND
Chloromethane 07/09/09 0.11 1.0 ND 0.19 J ND
12/16/09 0.11 1.0 ND ND ND
NC 2B = NE (03/24/10)06/24/10 0.11 1.0 ND ND ND12/13/10 0.11 1.0 ND ND ND06/20/11 0.11 1.0 ND ND ND
12/05/11 0.11 1.0 ND ND ND
06/11/12 0.11 1.0 ND ND ND
12/12/12 0.11 1.0 ND ND ND05/01/13 0.11 1.0 ND ND ND
08/05/13 0.11 1.0 ND ND ND
02/24/14 0.11 1.0 ND ND 0.25 J
08/12/14 EPA 8260 0.11 1.0 ---ND ND03/10/15 EPA 8260 0.11 1.0 ND ND ND
08/18/15 ------Dry Dry ---
02/16/16 EPA 8260 0.11 1.0 ND ND ND
Notes:
All concentrations are in micrograms per liter (µg/L).
RL = Reporting Limit (SWSL for December 2006 - present).DL = Laboratory detection limit.J = Estimated value between the DL and the RL.
B = Blank-qualified data; result is expected to be biased high based on concentrations in the blanks.
ND = Not detected above laboratory reporting limit.NS = Not sampled.NR = Not Reported.
Dry =Surface water point considered to be dry.
NC 2B = North Carolina Surface Water Standards from 15A NCAC 2B.NE = Not established.Shaded values for surface water are above the NC 2B.
Surface waters are classified as fresh-water aquatic life.
**SW- 1 and SW-2 were both dry and unable to be sampled on the 8/18/2015 sampling event.**
Granville County
Butner Landfill, Permit No. 39-02 Page 8 of 8
Joyce Engineering

Appendix E

Statistical Analysis Worksheets & Summary

APPENDIX E: Results of Statistical Analyses (February 2016)
Analyte Data Statistical Method used Background NC 2L or GWPS Point(s) Above Point(s) above NC 2L
Distribution to Establish Background (µg/L)(µg/L)Background or GWPS
Antimony 96% Truncated Upper Poisson Prediction Limit 56 1 None MW-2R
Cobalt 74% Truncated Non-parametric Prediction Limit 130 1 None MW-5
Notes:
NC 2L = Groundwater Protection Standard from 15A NCAC 2L.0202.
GWPS = Groundwater Protection Standard (Soild Waste Section) for constituents with no NC 2L Standard.
Granville County - Butner Landfill Permit 39-02 Joyce Engineering