HomeMy WebLinkAbout3612_DukeAllen_March2017_1stSemiAnnualLeachate_DIN27770_20170517526 South Church Street
Charlotte, NC 28202
Mailing Address:
PO Box 1006
Mail Code EC13K
Charlotte, NC 28201-1006
704 382 4761
704 382 6240 fax
May 17, 2017
Ms. Elizabeth Werner
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
1646 Mail Service Center
Raleigh, NC 27699-1646
Subject: Semi-annual Leachate Sampling Results – March 2017
Duke Energy Carolinas, LLC
Allen Steam Station
Retired Ash Basin (RAB) Ash Landfill, Phase I, Cells 1 and 2, Permit #36-12
Dear Ms. Werner:
In accordance with the landfill Operations Plan, Duke Energy is providing the results of semi-
annual leachate sampling for the Allen Retired Ash Basin (RAB) Ash Landfill located in Belmont,
North Carolina.
On March 8, 2017, leachate samples were collected from the leachate collection system. The
samples were collected by Duke Energy personnel. A summary of sampling results can be found
in Table 1. As noted in the table, 15 NCAC 2L .0202 standards are provided for reference only.
The parameters tested are not bound by state groundwater or surface water standards. The
leachate is conveyed to the station’s ash impoundment, which discharges via a NPDES permitted
outfall. All laboratory analytical and field results are provided as Attachments 1 and 2, respectively.
Duke Energy personnel sample landfill leachate at Allen Steam Station’s RAB Ash Landfill semi-
annually during March and September. The next landfill leachate sampling event will occur during
September 2017 with documentation to follow.
If you have any questions or concerns, please contact me at 704-382-4761 or at
Sean.DeNeale@duke-energy.com
Sincerely,
Sean DeNeale, Engineer III
Environmental Services
Cc: Mr. Scott Harris – Allen Steam Station
Mr. Randy Gantt – Allen Steam Station
Ms. Kimberlee Witt – Duke Energy Corporation
Arsenic 10 ug/L 184 ug/L 131 ug/L
Barium 700 ug/L < 50 ug/L < 50 ug/L
Boron 700 ug/L 68,100 ug/L 113,000 ug/L
Cadmium 2 ug/L 16.1 ug/L 3.16 ug/L
Chloride 250 mg/L 86 mg/L 120 mg/L
Chromium 10 ug/L < 50 ug/L < 50 ug/L
Copper 1 mg/L 0.474 mg/L 0.188 mg/L
Fluoride 2 mg/L < 10 mg/L < 10 mg/L
Iron 300 ug/L 235 ug/L < 100 ug/L
Lead 15 ug/L 3.76 ug/L < 1 ug/L
Manganese 50 ug/L 34,100 ug/L 30,000 ug/L
Mercury 1 ug/L 0.07 ug/L 0.06 ug/L
Nickel 100 ug/L 1,690 ug/L 299 ug/L
Nitrate (as N)10 mg‐N/L 24 mg‐N/L 66 mg‐N/L
pH 6.5‐8.5 SU 4.09 SU 4.25 SU
Selenium 20 ug/L 75.7 ug/L 282 ug/L
Silver 20 ug/L < 50 ug/L < 50 ug/L
Sulfate 250 mg/L 7,100 mg/L 6,200 mg/L
Temperature (°C)n/a °C 19.82 °C 19.99 °C
TDS 500 mg/L 4,800 mg/L 5,100 mg/L
Zinc 1 mg/L 2.33 mg/L 0.518 mg/L
NOTE: 15A NCAC 2L .0202 Standards are provided only for reference. Analytical results
are for landfill leachate, which is NOT bound by state groundwater or surface water
standards. Landfill leachate is conveyed to the station's ash impoundment, which
discharges via a NPDES permitted outfall.
Table 1
Allen Steam Station
Retired Ash Basin (RAB) Ash Landfill (Permit No. 36‐12)
Leachate Analytical Data
15A NCAC 2L .0202
Standard March 8, 2017
Cell 1 Cell 2
Analytical Result
Constituent
Attachment 1
Allen Retired Ash Basin (RAB) Ash Landfill
Semi‐Annual Monitoring Event
Leachate Analytical Results
March 8, 2017
13339 Hagers Ferry RoadHuntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: 980-875-5245 Fax: 980-875-4349
Order Summary Report
Analytical Laboratory
Order Number:J17020482
Project Name:ALLEN - GW LEACHATE
Lab Contact: Anne Pridgeon
Date:3/24/2017
Customer Address:253 Plant Allen Road
Customer Name(s):C. Campbell, T Hunsucker, R Gantt,S DeNeale
Belmont, NC 28012
Phone: 980-875-6610
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pridgeon) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods.
Anne Pridgeon
Page 1 of 12
Reason: I have reviewed
this document.
Date: 2017.03.27
11:00:08 -04'00'
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection Date and Time Collected By Sample Description
2017005667 ALLEN 08-Mar-17 9:25 AM LDC LEACHATE LCS-CELL 1
2017005668 ALLEN 08-Mar-17 9:50 AM LDC LEACHATE LCS-CELL 2
2017005669 ALLEN 08-Mar-17 10:00 AM LDC FIELD BLANK
3 Total Samples
Page 2 of 12
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:3/24/2017
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020482
2017005667
Collection Date:08-Mar-17 9:25 AM
Site:LEACHATE LCS-CELL 1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 86 mg/L EPA 300.0 03/09/2017 00:13 BGN903410100
Fluoride < 10 mg/L EPA 300.0 03/09/2017 00:13 BGN903410100
Nitrate 110 mg/L EPA 300.0 03/09/2017 00:13B2 BGN903410100
Nitrate as N 24 mg-N/L EPA 300.0 03/09/2017 00:13 BGN90340.023 1
Sulfate 7100 mg/L EPA 300.0 03/09/2017 00:13 BGN90341001000
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)0.07 ug/L EPA 245.1 03/15/2017 14:55 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.05 mg/L EPA 200.7 03/22/2017 09:37 MHH71310.05 10
Boron (B)68.1 mg/L EPA 200.7 03/22/2017 09:37 MHH71310.5 10
Chromium (Cr)< 0.05 mg/L EPA 200.7 03/22/2017 09:37 MHH71310.05 10
Copper (Cu)0.474 mg/L EPA 200.7 03/22/2017 09:37 MHH71310.05 10
Iron (Fe)0.235 mg/L EPA 200.7 03/22/2017 09:37 MHH71310.1 10
Manganese (Mn)34.1 mg/L EPA 200.7 03/22/2017 09:37 MHH71310.05 10
Nickel (Ni)1.69 mg/L EPA 200.7 03/22/2017 09:37 MHH71310.05 10
Silver (Ag)< 0.05 mg/L EPA 200.7 03/22/2017 09:37 MHH71310.05 10
Zinc (Zn)2.33 mg/L EPA 200.7 03/22/2017 09:37 MHH71310.05 10
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)184 ug/L EPA 200.8 03/21/2017 11:49 JAHERMA11
Cadmium (Cd)16.1 ug/L EPA 200.8 03/21/2017 11:49 JAHERMA11
Lead (Pb)3.76 ug/L EPA 200.8 03/21/2017 11:49 JAHERMA11
Selenium (Se)75.7 ug/L EPA 200.8 03/21/2017 11:49 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 4800 mg/L SM2540C 03/14/2017 15:00 MGIGANT5001
Page 4 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020482
2017005668
Collection Date:08-Mar-17 9:50 AM
Site:LEACHATE LCS-CELL 2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride 120 mg/L EPA 300.0 03/09/2017 00:30 BGN903410100
Fluoride < 10 mg/L EPA 300.0 03/09/2017 00:30 BGN903410100
Nitrate 290 mg/L EPA 300.0 03/09/2017 00:30B2 BGN903410100
Nitrate as N 66 mg-N/L EPA 300.0 03/09/2017 00:30 BGN90340.023 1
Sulfate 6200 mg/L EPA 300.0 03/09/2017 00:30 BGN90341001000
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)0.06 ug/L EPA 245.1 03/15/2017 14:57 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.05 mg/L EPA 200.7 03/22/2017 09:41 MHH71310.05 10
Boron (B)113 mg/L EPA 200.7 03/22/2017 09:41 MHH71310.5 10
Chromium (Cr)< 0.05 mg/L EPA 200.7 03/22/2017 09:41 MHH71310.05 10
Copper (Cu)0.188 mg/L EPA 200.7 03/22/2017 09:41 MHH71310.05 10
Iron (Fe)< 0.1 mg/L EPA 200.7 03/22/2017 09:41 MHH71310.1 10
Manganese (Mn)30.0 mg/L EPA 200.7 03/22/2017 09:41 MHH71310.05 10
Nickel (Ni)0.299 mg/L EPA 200.7 03/22/2017 09:41 MHH71310.05 10
Silver (Ag)< 0.05 mg/L EPA 200.7 03/22/2017 09:41 MHH71310.05 10
Zinc (Zn)0.518 mg/L EPA 200.7 03/22/2017 09:41 MHH71310.05 10
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)131 ug/L EPA 200.8 03/21/2017 11:58 JAHERMA11
Cadmium (Cd)3.16 ug/L EPA 200.8 03/21/2017 11:58 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 03/21/2017 11:58 JAHERMA11
Selenium (Se)282 ug/L EPA 200.8 03/21/2017 11:58 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 5100 mg/L SM2540C 03/14/2017 15:00 MGIGANT5001
Page 5 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020482
2017005669
Collection Date:08-Mar-17 10:00 AM
Site:FIELD BLANK
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 03/08/2017 22:31 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 03/08/2017 22:31 BGN90340.1 1
Nitrate 0.12 mg/L EPA 300.0 03/08/2017 22:31B2 BGN90340.1 1
Nitrate as N 0.03 mg-N/L EPA 300.0 03/08/2017 22:31 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 300.0 03/08/2017 22:31 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 03/15/2017 14:59 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L EPA 200.7 03/22/2017 09:33 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 03/22/2017 09:33 MHH71310.05 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 03/22/2017 09:33 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 03/22/2017 09:33 MHH71310.005 1
Iron (Fe)< 0.01 mg/L EPA 200.7 03/22/2017 09:33 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 03/22/2017 09:33 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 03/22/2017 09:33 MHH71310.005 1
Silver (Ag)< 0.005 mg/L EPA 200.7 03/22/2017 09:33 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 03/22/2017 09:33 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 03/21/2017 12:07 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 03/21/2017 12:07 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 03/21/2017 12:07 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 03/21/2017 12:07 JAHERMA11
Qualifiers:
B2 Target analyte was detected in Method Blank(s) at a concentration greater than ½ the reporting limit but less
than the reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
Page 6 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020482
Q17030180 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0336 mg/L -10.0336 0.1 < 1/2 RDL
Fluoride 0.0391 mg/L -10.0391 0.1 < 1/2 RDL
Nitrate 0.0691 mg/L -10.0691 0.1 > 1/2 RDL
Sulfate -0.0344 mg/L -1-0.0344 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 6.11 50 108mg/L -120801061.1
Fluoride 50mg/L -120801Not Tested
Nitrate 50mg/L -120801Not Tested
Sulfate 6.37 50 102mg/L -120801063.7
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 6.09 50 107 0.44mg/L -120801060.9
Fluoride 50mg/L -120801Not Tested
Nitrate 50mg/L -120801Not Tested
Sulfate 6.33 50 101 0.827mg/L -120801063.3
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 8.73 5 105mg/L -1208018.73
Fluoride 5.07 5 99mg/L -1208015.07
Nitrate 5.43 5 109mg/L -1208015.43
Sulfate 5.61 5 110mg/L -1208015.61
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 8.78 5 106 0.956mg/L -1208018.78
Fluoride 5.06 5 98.7 0.273mg/L -1208015.06
Nitrate 5.43 5 109 0.0295mg/L -1208015.43
Sulfate 5.6 5 109 0.111mg/L -1208015.6
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.1 5 102mg/L -1109015.1
Fluoride 5.06 5 101mg/L -1109015.06
Nitrate 5.13 5 103mg/L -1109015.13
Sulfate 5.14 5 103mg/L -1109015.14
Page 7 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020482
Q17030382 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.002 ug/L -10.002 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.017 ug/L -10.017 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 0.918 20 85.4ug/L -130702018.4
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.918 20 85.4 0ug/L -130702018.4
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2 2 100ug/L -1158512
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.99 2 99.5ug/L -1158511.99
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J17020370 -- 2017005148
Mercury (Hg) 0.997 1 98.4ug/L -1307010.997
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J17020370 -- 2017005148
Mercury (Hg) 0.984 1 97.1 1.33ug/L -1307010.984
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J17020480 -- 2017005655
Mercury (Hg) 1.05 1 103ug/L -1307011.05
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J17020480 -- 2017005655
Mercury (Hg) 1.06 1 104 0.58ug/L -1307011.06
Page 8 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020482
Q17030356 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) 0.00002 mg/L -10.00002 0.005 < 1/2 RDL
Boron (B) 0.00394 mg/L -10.00394 0.05 < 1/2 RDL
Chromium (Cr) 0.000195 mg/L -10.000195 0.005 < 1/2 RDL
Copper (Cu) 0.00054 mg/L -10.00054 0.005 < 1/2 RDL
Iron (Fe) 0.00149 mg/L -10.00149 0.01 < 1/2 RDL
Manganese (Mn) 0.000134 mg/L -10.000134 0.005 < 1/2 RDL
Nickel (Ni) 0.00008 mg/L -10.00008 0.005 < 1/2 RDL
Silver (Ag) 0.000529 mg/L -10.000529 0.005 < 1/2 RDL
Zinc (Zn) -0.00132 mg/L -1-0.00132 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 4.99 5 99.8mg/L -1158514.99
Boron (B) 5.09 5 102mg/L -1158515.09
Chromium (Cr) 5.17 5 103mg/L -1158515.17
Copper (Cu) 5.11 5 102mg/L -1158515.11
Iron (Fe) 5.16 5 103mg/L -1158515.16
Manganese (Mn) 5.19 5 104mg/L -1158515.19
Nickel (Ni) 5.2 5 104mg/L -1158515.2
Silver (Ag) 0.496 0.5 99.2mg/L -1158510.496
Zinc (Zn) 5.21 5 104mg/L -1158515.21
Final QualifierDilMeasuredUnits:Parameter
LCSD # 1
RPD% Recovery LCL UCLSpike
Barium (Ba) 4.96 5 99.1 0.664mg/L -1158514.96
Boron (B) 5.13 5 103 0.646mg/L -1158515.13
Chromium (Cr) 5.17 5 103 0.0193mg/L -1158515.17
Copper (Cu) 5.11 5 102 0.0587mg/L -1158515.11
Iron (Fe) 5.16 5 103 0.136mg/L -1158515.16
Manganese (Mn) 5.18 5 104 0.116mg/L -1158515.18
Nickel (Ni) 5.2 5 104 0.0769mg/L -1158515.2
Silver (Ag) 0.497 0.5 99.3 0.127mg/L -1158510.497
Zinc (Zn) 5.21 5 104 0.0768mg/L -1158515.21
Page 9 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020482
Q17030365 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) 0.148 ug/L -10.148 1 < 1/2 RDL
Cadmium (Cd) 0.0007 ug/L -10.0007 1 < 1/2 RDL
Lead (Pb) 0.0208 ug/L -10.0208 1 < 1/2 RDL
Selenium (Se) 0.138 ug/L -10.138 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 50.5 50 101ug/L -11585150.5
Cadmium (Cd) 50 50 100ug/L -11585150
Lead (Pb) 50.8 50 102ug/L -11585150.8
Selenium (Se) 48.9 50 97.8ug/L -11585148.9
Final QualifierDilMeasuredUnits:Parameter
LCSD # 1
RPD% Recovery LCL UCLSpike
Arsenic (As) 49.2 50 98.3 2.63ug/L -11585149.2
Cadmium (Cd) 50.5 50 101 0.816ug/L -11585150.5
Lead (Pb) 50 50 99.9 1.59ug/L -11585150
Selenium (Se) 49.4 50 98.7 0.895ug/L -11585149.4
Page 10 of 12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17020482
Q17030328 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS 0 mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J17020482 -- 2017005667
TDS 4820 0.414mg/L -14820
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J17020482 -- 2017005668
TDS 5140 0.781mg/L -15140
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J17030048 -- 2017006912
TDS 172 1.73mg/L -1172
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 94 100 94mg/L -11090194
Page 11 of 12
Attachment 2
Allen Retired Ash Basin (RAB) Ash Landfill
Semi‐Annual Monitoring Event
Leachate Field Results
March 8, 2017
STUDY:
ANALYZER SERIAL #:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬/▬►0.0
SS 227.7 ▬▬►227 227.2 ▬/▬►227
SS 75.0 ▬/▬►75 76.3 ▬/▬►75
SS ▬/▬►1410 ▬/▬►1410
SS
B (7.00)7.05 ▬▬►7.02 6.99 ▬/▬►7.02
B (4.00)4.04 ▬▬►4.00 3.97 ▬/▬►4.00
B (10.00)10.03 ▬/▬►10.06 10.01 ▬/▬►10.06
19.90 19.96
pH Check B (7.00)▬▬►7.13
Time:0.00
442 ▬▬►442 443 ▬/▬►442
N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 19.73 19.68
TEMP (CO)
BP (mmHg)
COND
100 % mg/L 9.04 ▬▬►9.06 9.11 ▬/▬►9.03
After Cal 9.05 99.91 9.09 100.62
LCS 9.09 100.35 9.13 101.06
LCSD 9.10 0.11 9.11 -0.22
SS 54.5 ▬/▬►53.4 54.5 ▬/▬►53.4
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
N/A = Not Applicable W = WinklerBP = Barometric Pressure AW = Average Winkler
NOTES:
(mmHg)
B = Buffer LCS = Lab Control Standard ▬▬► = Adjusted To
SS = Standard solution LCSD = Lab Control Standard Duplicate ▬/▬►= Not Adjusted To
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 751.56 (mmHg)Ending BP 747.85
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK Replaced ref Electrode KCL
CALIBRATION PASS
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Temp Cert Device #
100.60 100.70
ORP Temp.ORP Temp.
DO
(mg/L)
19.60 19.48
751.56
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
CALIBRATION PASS CALIBRATION PASS
747.85
CALIBRATION PASS
Buffer Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.Buffer Temp.
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION BP (mmHg)751.56 CALIBRATION BP (mmHg)747.85
Parameter Calibration Results Calibration Results
3210.6 VALIDATED BY:
Calibration Date / Time 8-Mar-17 715 8-Mar-17 1210
HYDROLAB PROCEDURE #:
FIELD SAMPLING CALIBRATION FORM
DATE (s):March 8, 2017 SURFACE UNIT READER:
ALLEN STEAM STATION - LEACHATE COLLECTION SYSTEM
OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW WEATHER CONDITIONS:
LDC
COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:0970
ANALYZER MODEL#:HL4 400439
N/A
@
QC By:
LDC, PSP
SITE ID N/APERMIT #ALLEN STEAM STATION
FIELD CREWLEACHATE COLLECTION SYSTEM
(METERS)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
SAMPLING NOTES
Access cleared around wellACCESS AROUND WELL
Access cleared into well
WELL SECURITY
WELL LOCK CONDITION
DEPTH OF TEMP SPECIFIC
Well Impacted By Silting:
N/A
SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
LDC 3/8/2017 0925 N/A
N/A 19.82 7293 4.09
COND.OXYGENINTAKE
FLOW
CONDITIONS:
549 3.993.2
WELL USE
FOSSIL LANDFILL NPDES
DETECTED ODOR None
APPEARANCE Normal
SAMPLING INFORMATION
pH TURBIDITY ORP DISSOLVED
SITE NAME
SURFACE WATER MONITORING DATA SHEET
FOR SURFACE WATER SAMPLING
PROJECT NAME
SAMPLING DATE(s)8-Mar-2017 WELL/LOCATION NAME
DUKE ENERGY
SURFACE WATER LOCATION INFORMATION
YESWAS THERE A NOTICABLE FLOW:
SAMPLING METHOD:GRAB LOCATION ENVIRONMENT:
LOCATION TYPE:LEACHATE/DRAINAGE WAS WATER PRESENT:YES
PURGE METHOD
Surface Water Sample
WELL TYPE WELL INFORMATION
PIPE
ODOR STRENGTH None
WELL/SAMPLING INFORMATION
N/A
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
ACCESS TO WELLS
WELL CAPS
FLUSH MOUNT WELLS
< 2.0Sample preservation verified to pH
(units)
SAMPLING PROCEDURE NO.3175.4
LCS-CELL 1
GAMMA H3 SO4,CL SR 89/90 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
N/A
@
QC By:
SITE NAME ALLEN STEAM STATION PERMIT #N/A SITE ID
PROJECT NAME LEACHATE COLLECTION SYSTEM FIELD CREW LDC, PSP
DUKE ENERGY
SURFACE WATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO.3175.4
FOR SURFACE WATER SAMPLING
LCS-CELL 2SAMPLING DATE(s)8-Mar-2017 WELL/LOCATION NAME
SAMPLING METHOD:GRAB LOCATION ENVIRONMENT:PIPE
SURFACE WATER LOCATION INFORMATION
LOCATION TYPE:LEACHATE/DRAINAGE WAS WATER PRESENT:YES WAS THERE A NOTICABLE FLOW:YES
WELL/SAMPLING INFORMATION
WELL TYPE WELL INFORMATION WELL USE PURGE METHOD
FOSSIL LANDFILL NPDES Surface Water Sample
DETECTED ODOR None
ODOR STRENGTH None
APPEARANCE Normal
SAMPLING INFORMATION
DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
(METERS)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
INTAKE COND.OXYGEN
TIME
LDC 3/8/2017 0950 N/A
Sample preservation verified to pH
(units)< 2.0
1.8 527 3.42 N/A
FLOW
CONDITIONS:
SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE
N/A 19.99 6138 4.25
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL CAPS
WELL CASING
ACCESS TO WELLS Access cleared into well
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Well Impacted By Silting:N/A
SAMPLING NOTES
WELL SECURITY
WELL LOCK CONDITION
WELL TAG
ACCESS AROUND WELL Access cleared around well
GAMMA H3 SO4,CL SR 89/90 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON
METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228
METALS F_ALK CO2 VOC's RSK 175 TPH-DRO
METALS NO3-N, CL, F, SO4, F_ALK TDS
ALPHA SPEC
LCS-CELL 1 LCS-CELL 2
YES YES
YES YES
N/A N/A
N/A N/A
N/A N/A
N/A N/A
N/A N/A
N/A N/A
N/A N/A
N/A N/A
N/A N/A
NORTH CAROLINA GROUNDWATER SAMPLING SITE CHECK LIST
SITE:SAMPLE DATE March 8, 2017
SITE CONTACT
FIELD CREW LDC, PSPPROJECT:
ALLEN STEAM STATION
LEACHATE COLLECTION SYSTEM
Randy Gantt
FLUSH MOUNT WELLS
WELL PROTECTIVE CASINGS
CONCRETE PADS
WELL SECURITY
Well found locked
Well found unlocked
WELL LOCK CONDITION
Lock in good condition
Lock rusted, difficult to open / needs replacing
Replaced damaged lock
WELL CASINGS
Casing in good condition
Damaged casing / still functional
WELL CAPS
NOTE:
Damaged casing / repair required
Pad in good condition
Minor cracks
Well tag damaged / illegible
Lacks required information - Static WL / date
Undermined / washing out
Fire ants around concrete pad
Lacks required information - Driller Reg #
Lacks required information - Completion date
Lacks required information - Total well depth
Vault in good condition
Casing in good condition
Lacks required info - Casing depth / diam.
Lacks required information - Screen interval
Lacks required information - Non potable tag
Lacks required information - Depth to screen
Water inside vault
Vault bolt holes broken or stripped
Bolts strippedVault lid cracked or broken
WELL ID TAGS
Well tag in good condition
Well tag missing
Replaced damaged well cap
Major cracks / broken / repair required
Ants inside protective casing
Damaged casing / still functional
Damaged casing / repair required
Broken hinge on protective lid
Wasp nest inside protective casing
Well cap in good conditon
Damaged / needs replacement
Road washing out / muddy / needs grading
Fallen tree blocking access
WELL DEPTH
Well impacted by silting
Access cleared around well
Tall grass or weeds - needs mowing
WEATHER 3/8/2017
PAGE 1 OF 1
ACCESS TO WELLS
Access cleared into well
DATE WELL NO
WELL
DEPTH (ft - TOC)
DEPTH TO
WATER (ft - TOC)
WATER
ELEV. (ft)APPEARANCE ODOR PURGE METHOD
PUMP RATE (ml/min)
WELL
VOL. (gal)
EVAC
VOL. (gal)
EVAC
(YES/NO)
TEMP. (deg. C)
SPECIFIC
CONDUCTANCE (umho/cm)
pH (units)TURBIDITY (NTU's)ORP (mV-NHE)DO (mg/L)
3/8/2017 LCS-CELL 1 Normal None SWS N/A N/A N/A 19.82 7293 4.09 3.2 549 3.99
3/8/2017 LCS-CELL 2 Normal None SWS N/A N/A N/A 19.99 6138 4.25 1.8 527 3.42
ALLEN STEAM STATION
LEACHATE COLLECTION SYSTEM
GROUNDWATER MONITORING FIELD DATA
PERMIT #N/A
Purge MethodsLF = Low Flow NP = No PurgeEOP = Equip. Only Purge LO = Level Only LF(M) = Low Flow (Mod.)* = Applicable to LF & LF(M) Purging OnlyC = Connventional