1910_Brickhaven_RiverbendPCBSampleResults_March2017_DIN27753_20170309

#=CL#
March 09, 2017
LIMS USE: FR Prelim - PROGRAM
LIMS OBJECT ID: 92332076
92332076
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J17030104
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on March 03, 2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Tyriek Hooks for
[e-mail]
HORIZON Database Administrator
Kevin Herring
1(704)875-9092
Enclosures
cc:Program Manager, Duke Energy
REPORT OF LABORATORY ANALYSIS
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#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92332076
J17030104
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92332076
J17030104
Lab ID Sample ID Matrix Date Collected Date Received
92332076001 2017007194 Solid 03/03/17 09:30 03/03/17 13:20
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services, LLC
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92332076
J17030104
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92332076001 2017007194 EPA 8082 8 PASI-CHSK
ASTM D2974-87 1 PASI-CCLW
REPORT OF LABORATORY ANALYSIS
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SUMMARY OF DETECTION
Pace Project No.:
Project:
92332076
J17030104
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92332076001 2017007194
PCB-1260 (Aroclor 1260)0.48 mg/kg 03/07/17 09:550.045EPA 8082
Percent Moisture 26.4 %03/06/17 09:310.10ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
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#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92332076
J17030104
Method:
Client:Duke Energy
EPA 8082
Date:March 09, 2017
Description:8082 GCS PCB
General Information:
1 sample was analyzed for EPA 8082. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3546 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services, LLC
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92332076
J17030104
Sample:2017007194 Lab ID:92332076001 Collected:03/03/17 09:30 Received:03/03/17 13:20 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8082 Preparation Method: EPA 35468082 GCS PCB
PCB-1016 (Aroclor 1016)ND mg/kg 03/07/17 09:55 12674-11-203/06/17 14:300.045 1
PCB-1221 (Aroclor 1221)ND mg/kg 03/07/17 09:55 11104-28-203/06/17 14:300.045 1
PCB-1232 (Aroclor 1232)ND mg/kg 03/07/17 09:55 11141-16-503/06/17 14:300.045 1
PCB-1242 (Aroclor 1242)ND mg/kg 03/07/17 09:55 53469-21-903/06/17 14:300.045 1
PCB-1248 (Aroclor 1248)ND mg/kg 03/07/17 09:55 12672-29-603/06/17 14:300.045 1
PCB-1254 (Aroclor 1254)ND mg/kg 03/07/17 09:55 11097-69-103/06/17 14:300.045 1
PCB-1260 (Aroclor 1260)0.48 mg/kg 03/07/17 09:55 11096-82-503/06/17 14:300.045 1
Surrogates
Decachlorobiphenyl (S)64 %03/07/17 09:55 2051-24-303/06/17 14:3021-132 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 26.4 %03/06/17 09:310.10 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/09/2017 11:43 AM Page 7 of 11
Pace Analytical Services, LLC
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92332076
J17030104
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
350983
EPA 3546
EPA 8082
8082 GCS PCB
Associated Lab Samples:92332076001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1946904
Associated Lab Samples:92332076001
Matrix:Solid
Analyzed
PCB-1016 (Aroclor 1016)mg/kg ND 0.033 03/07/17 10:16
PCB-1221 (Aroclor 1221)mg/kg ND 0.033 03/07/17 10:16
PCB-1232 (Aroclor 1232)mg/kg ND 0.033 03/07/17 10:16
PCB-1242 (Aroclor 1242)mg/kg ND 0.033 03/07/17 10:16
PCB-1248 (Aroclor 1248)mg/kg ND 0.033 03/07/17 10:16
PCB-1254 (Aroclor 1254)mg/kg ND 0.033 03/07/17 10:16
PCB-1260 (Aroclor 1260)mg/kg ND 0.033 03/07/17 10:16
Decachlorobiphenyl (S)%85 21-132 03/07/17 10:16
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1946905LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1946906
PCB-1016 (Aroclor 1016)mg/kg 0.096.17 57 31-120670.11 15 30
PCB-1260 (Aroclor 1260)mg/kg 0.14.17 81 32-120790.13 3 30
Decachlorobiphenyl (S)%92 21-13285
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/09/2017 11:43 AM Page 8 of 11
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92332076
J17030104
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
350779
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:92332076001
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92331866001
1945901SAMPLE DUPLICATE:
Percent Moisture %34.7 R1272545.3
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92332076001
1945902SAMPLE DUPLICATE:
Percent Moisture %26.1 1 2526.4
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/09/2017 11:43 AM Page 9 of 11
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92332076
J17030104
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
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Huntersville, NC 28078
[phone]
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92332076
J17030104
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92332076001 350983 3510842017007194EPA 3546 EPA 8082
92332076001 3507792017007194ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/09/2017 11:43 AM Page 11 of 11
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]