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Home My WebLink About8504_DukeBelewsCreek_CraigRd_Jan2017_1stSemiAnnual_DIN27647_20170417 Belews Creek Steam Station Semiannual Groundwater Monitoring Report Craig Road Ash Landfill, Phase 1 and 2 Permit No. 8504 January 2017 Sampling Event May 1, 2017 Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2 January 2017 Sampling Event TABLE OF CONTENTS ii Table of Contents Page Report Verification ......................................................................................................................... i Table of Contents .......................................................................................................................... ii Section 1 - Background ................................................................................................................. 1 Section 2 - Methods ...................................................................................................................... 4 2.1 Sampling and Analysis Methods .................................................................................... 4 2.2 Statement of Work .......................................................................................................... 4 Section 3 - Results ........................................................................................................................ 6 3.1 Site Groundwater Flow ................................................................................................... 6 3.2 Analytical Results ........................................................................................................... 6 FIGURES 1. Site Location Map 2. Sample Locations 3. Generalized Groundwater Surface Contours TABLES 1. Well Construction Information 2. Groundwater Flow Velocities 3. Field Data Parameters 4. Groundwater Field and Analytical Results 5. Field and Analytical Results that Equal or Exceed NCAC 2L Groundwater Quality Standards 6. Surface Water Field and Analytical Results 7. Field and Analytical Results that Equal or Exceed NCAC 2B Surface Water Quality Standards 8. Leachate Field and Analytical Results APPENDICES A. Field Sampling Forms B. Laboratory Report and Chain-of-Custody Forms Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2 January 2017 Sampling Event SECTION 1 - BACKGROUND 1 Section 1 - Background Belews Creek Steam Station is located on Belews Lake in southwestern Stokes County near Pine Hall, North Carolina. The station is owned and operated by Duke Energy Carolinas, LLC (Duke Energy) and generates electricity by combustion of coal. The Craig Road Ash Landfill is owned by Duke Energy and is permitted to receive coal ash, wastewater treatment sludge, and off-spec flue gas desulfurization (FGD) residue (gypsum) generated at the Belews Creek Steam Station under North Carolina Department of Environmental Quality (NCDEQ) Solid Waste Permit No. 8504. Phase 1 of the landfill was constructed with an engineered liner system and the waste boundary contains an area of approximately 32.4 acres. Phase 1 began accepting waste in February 2008. Phase 2 of the landfill was constructed with an engineered liner system and the waste boundary contains an area of approximately 34.7 acres. Placement of a protective cover layer of approximately 137,000 tons of bottom ash on top of the Phase 2 liner system began on June 11, 2013. Phase 2 of the landfill received a Permit to Operate January 16, 2014, and started receiving waste on June 13, 2014. Phase 1 and Phase 2 of the Craig Road Ash Landfill and nearby area are portrayed on Figure 1. The highest topographic area of the landfill site is at the center portion of the landfill along its southern boundary. The predominant groundwater discharge areas are expected to be the adjacent areas of Belews Lake located to the west, north, and east of the landfill. Figure 2 shows the landfill and the topography at the site. As described in the Water Quality Monitoring Plan, the monitoring system for the landfill consists of the following1: Monitoring Wells: CRW-1 2 CRW-7 CRW-13 CRW-2 CRW-83 CRW-14 CRW-3 CRW-9 CRW-15 CRW-4 CRW-10 CRW-16 CRW-5 CRW-11 CRW-17 CRW-6 CRW-12 Surface Water Sample Locations: CRS-1 CRS-4 CRS-2 CRS-5 CRS-3 CRS-6 Leachate Sample Locations4:CWB-1 CWB-2 CWB-3 1 Water Quality Monitoring Plan – Phase1/Phase 2 Craig Road Landfill Expansion Duke Energy – Belews Creek Steam Station, Belews Creek, North Carolina, S&ME Project No. 1356-10-041, April 26, 2012. 2 Monitoring well CRW-1 was abandoned on July 13, 2012, due to construction of Phase 2 of the landfill. 3 Monitoring well CRW-8 was damaged and subsequently replaced by CRW-8R on April 11, 2013. 4 The leachate sample locations are not described in the Water Quality Monitoring Plan but monitoring the leachate in conjunction with the groundwater monitoring event is a requirement of the Permit to Operate. Leachate sample locations CWB-1 and CWB-2 were formerly referred to as E-WWBLeachate and W-WWBLeachate, respectively. Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2 January 2017 Sampling Event SECTION 1 - BACKGROUND 2 The sampling locations are depicted on Figure 2. A summary of monitoring well construction information is presented in Table 1. According to the Water Quality Monitoring Plan, monitoring well CRW-10 serves as a background water quality monitoring well. Surface water sampling locations CRS-1 and CRS-2 are located on perennial streams which drain to Belews Lake. Sampling locations CRS-4 and CRS-5 are located at groundwater seeps. Sampling locations CRS-3 and CRS-6 are located at the outlets of the two landfill under-drains. There is a single non-contact stormwater basin located to the north of the landfill. This basin is located just north of CRW-4 and shown on Figure 2 as “Primary BMP.” There are three stormwater basins that receive contact stormwater and leachate. These basins are shown on Figure 2 as “West Ash Runoff Storage Basin,” “East Ash Runoff Storage Basin,” and “Phase 2 Contact Water Basin.” Leachate sample locations are located where the leachate collection pipes drain into the contact stormwater/leachate basins. The contact stormwater/leachate basins and leachate sample locations are shown on Figure 2. Monitoring wells CRHS-9 and CRHS-31 were installed as part of the site suitability study for Phase 2 and were left in place during the January 2013 sampling event with the intent that they would become part of the permanent groundwater monitoring network for the landfill. Due to the poor performance of these wells with respect to recharge, these wells were replaced in April 2013 with monitoring wells CRW-12 and CRW-13, respectively. Monitoring wells CRW-3, CRW-8R, CRW-11, CRW-12, and CRW-17 have had historically high turbidity measurements reported in the wells. On May 2, 2015, Duke Energy attempted to redevelop these monitoring wells. On June 29, 2015, Duke Energy purged additional well volumes from these wells using each well’s dedicated pump in an effort to reduce the turbidity in the wells. During the July 2016 sampling event, the turbidity measurements in these wells were reported at 73.5, 32.7, 13.2, 500, and 37.7 Nephelometric Turbidity Units (NTU), respectively. Due to the continued high turbidity measurements in the monitoring wells, Duke Energy is considering the replacement of CRW-3, CRW-8R, CRW-11, CRW-12, and CRW-17. Due to the elevated turbidity measurements at these wells and in other wells in the monitoring system, HDR reviewed the turbidity results at landfill monitoring wells and made recommendations to Duke Energy concerning redevelopment and/or replacement. The results of this review were submitted to NCDEQ DWM in October 2016.5 Based on the results of the evaluation the following monitoring wells were recommended for replacement:  CRW-2  CRW-3  CRW-8R  CRW-11  CRW-17 5 Groundwater Monitoring Well Evaluation – Craig Road Ash Landfill, Phase1 and 2, Permit No. 8504 – Belews Creek Steam Station, Belews Creek, North Carolina, HDR, October 31, 2016. Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2 January 2017 Sampling Event SECTION 1 - BACKGROUND 3 Preparation for the replacement of these monitoring wells is currently underway. Based on the results of the evaluation the following monitoring wells were recommended for redevelopment:  CRW-6  CRW-7  CRW-9  CRW-10  CRW-12  CRW-13 Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2 January 2017 Sampling Event SECTION 2 - METHODS 4 Section 2 - Methods 2.1 Sampling and Analysis Methods The collection of samples and documentation of sampling was performed by Duke Energy personnel (Duke Energy Carolinas Field Certification #5193) according to the North Carolina Solid Waste Management Guidelines. Copies of the field sampling forms are included in Appendix A. The parameters and constituents sampled were selected by Duke Energy and the NCDEQ Division of Solid Waste and were analyzed by Duke Energy Analytical Laboratory (North Carolina Laboratory Certification #248) and provided to HDR by Duke Energy. The laboratory report and chain-of-custody forms are included in Appendix B. The groundwater, surface water, and leachate samples were analyzed using the following analytical methods:  Barium, boron, chromium, copper, iron, manganese, nickel, and zinc using Solid Waste (SW)-8466 Method 6010D  Arsenic, cadmium, lead, selenium, and silver using SW-846 Method 6020B  Chloride, fluoride, nitrate as nitrogen, and sulfate using US Environmental Protection Agency (EPA) SW-846 Method 9056A  Mercury using EPA SW-846 Method 7470A  Total dissolved solids using Standard Method (SM) 2540C 2.2 Statement of Work HDR completed the following tasks:  Received field sampling information provided by Duke Energy (performed by Duke Energy personnel) for monitoring wells CRW-2, CRW-3, CRW-4, CRW-5, CRW-6, CRW-8R, CRW-9, CRW-10, CRW-11, CRW-12, CRW-13, CRW-14, CRW-15, CRW-16, and CRW-17. Data was also received for surface water sample locations CRS-1, CRS-2, CRS-4, CRS-5, and CRS-6. Leachate sample data was received for locations CWB-1 and CWB-2. A groundwater sample was not collected from CRW-7 as there was insufficient water volume in the well. A surface water sample was not collected from CRS-3 as it was dry. A leachate sample was not collected at CWB-3 due to lack of discharge from the leachate pipe at this location. The samples were collected on January 30 and 31, 2017, and HDR received the data on February 23, 2017.  Reviewed the laboratory analytical results for the samples. The Electronic Data Deliverables (EDDs) provided by Duke Energy were adapted to conform to the format 6 EPA Hazardous Waste Test Methods (SW-846); available online at https://www.epa.gov/hw-sw846 (Accessed August 30, 2016) Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2 January 2017 Sampling Event SECTION 2 - METHODS 5 requirements of the NCDEQ EDD template. HDR added an italicized J data qualifier (J) to indicate a measured concentration that is equal to or greater than the laboratory’s method reporting limit (MRL) but less than the Solid Waste Section Limit7 (SWSL). Copies of the original EDDs are retained in HDR’s files.  Developed a generalized groundwater surface contour map using map data and groundwater elevation data supplied by Duke Energy. Calculated groundwater flow velocities based on groundwater surface contours.  Prepared and submitted this Semiannual Groundwater Monitoring Report to Duke Energy. 7 The Solid Waste Section Limit (SWSL) is defined by NCDEQ as the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy. The SWSL is the concentration below which reported results must be qualified as estimated. NCDEQ Division of Waste Management Memorandum dated February 23, 2007. Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2 January 2017 Sampling Event SECTION 3 - RESULTS 6 Section 3 - Results 3.1 Site Groundwater Flow Generalized groundwater surface contours and groundwater flow direction arrows from the sampling event for the site are shown on Figure 3. These contours were developed using the groundwater elevations measured on the date of sampling. The surface water elevation for Belews Lake was assumed at 724.5 feet. Calculated groundwater flow velocities are presented on Table 2. Groundwater flow at the site is from areas of higher topography located along the southern, central portion of the landfill toward Belews Lake to the northwest, north, and to the northeast and east toward the canal. 3.2 Analytical Results A summary of the field data is presented in Table 3. The field and analytical results of groundwater samples collected at the monitoring wells and at surface water locations CRS-4 and CRS-5 are summarized in Table 4. The analysis results for these locations are compared to the groundwater standards found in Title 15A NCAC 02L .0202 (g) (2L Standards)8. Concentrations with values that attain or exceed the 2L Standards are noted in Table 4 by bold font. A summary of the field and analytical results that attain or exceed the 2L Standards and a preliminary analysis of the cause and significance of the exceedances are presented in Table 5. Surface water sample locations CRS-1 and CRS-2 are located on perennial streams and CRS-3 and CRS-6 are located at the outlets of landfill under-drains. The streams and under-drains flow to Belews Lake. Belews Lake is classified by the NCDEQ Division of Water Quality as a Class C water body. As a result, the field and analytical results from these locations are compared to Title 15A, NCAC, Subchapter 2B Standards (2B Standards) for Class C water. The field and analytical results of the surface water sampling are summarized in Table 6. A summary of the field and analytical results that attain or exceed the 2B Standards and a preliminary analysis of the cause and significance of the exceedances are presented in Table 7. The field and analytical results for leachate sampling are summarized in Table 8. Concentrations with values that are equal to or greater than the SWSLs are noted by gray cells in Tables 4, 6, and 8. Selected samples were diluted as is normal laboratory practice to bring samples within the calibrated range of the analysis. Specifics regarding the samples that were diluted, including the dilution amount, are reported in the EDD. 8 Surface water locations CRS-4 and CRS-5 are located at groundwater seeps. Therefore, the analytical results at these locations are compared to the Title 15A NCAC 02L .0202 (g) groundwater quality standards (2L Standards). Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Belews Creek Steam Station, Craig Road Ash Landfill Phase 1 and 2 January 2017 Sampling Event SECTION 3 - RESULTS 7 HDR prepared and submitted an assessment to NCDEQ on exceedances of the 2L and 2B Standards at Phase 1 of this landfill (Groundwater Assessment, Belews Creek Steam Station, Craig Road Ash Landfill, December 21, 2012). The report assessed 2L Standard exceedances for:  Chromium at CRW-2 and CRW-9  Iron at CRW-2, CRW-3, CRW-5, CRW-6, CRW-7, CRW-8, CRW-9, CRS-4, and CRS-5  Manganese at CRW-2, CRW-3, CRW-5, CRW-6, CRW-7, CRW-9, CRS-4, and CRS-5 The report assessed 2B Standard exceedances for:  Iron at CRS-2 and CRS-3 The assessment report concluded that at the time of the assessment the exceedances evaluated were naturally occurring and were not related to impacts from the landfill. Figures $GNGYU%TGGM5VGCO5VCVKQP #UJ$CUKP #RRTQZKOCVG2JCUG .CPFHKNN$QWPFCT[ PINE HALL ROAD ASH LANDFILL PERMIT NO. 8503 FGD LANDFILL PERMIT NO. 8505 %TCKI4QCF CRAIG ROAD ASH LANDFILL PERMIT NO. 8504 1000 2000 5%#.' (''6 0 1000 0QVGU 5QWTEG75)56QRQITCRJKE/CRÄ$GNGYU.CMG 3WCFTCPING%TGCVGF4GXKUGF 6QRQITCRJKEOCRFQGUPQVTGHNGEVTGCNKIPOGPVQH%TCKI 4QCF FIGURE SITE LOCATION MAP BELEWS CREEK STEAM STATION CRAIG ROAD ASH LANDFILL, PHASE 1 & 2 PERMIT NO. 8504 1 APRIL 2017 440 South Church Street Charlotte, NC 28202 License Number: F-0116 DATE )TQWPFYCVGT/QPKVQTKPI9GNN5WTHCEG9CVGT5CORNKPI.QECVKQP.GCEJCVG5CORNG.QECVKQP .CPFHK N N 4 G X K G Y $ Q W P F C T [ .CPFHK N N % Q O R N K C P E G $ Q W P F C T [ (CEKNKV [ $ Q W P F C T [ 5VTGCO #RRTQZ K O C V G . K O K V Q H 9 C U V G .GIGPF 5 V T G C O N Q E C V K Q P E Q T T G U R Q P F U Y K V J ( C E K N K V [ $ Q W P F C T [ 2 4 + / # 4 ; $ / 2 9'56#5*4701((5614#)'$#5+02*#5'%106#%69#6'4$#5+0 ' # 5 6 # 5 * 4 7 0 1 ( ( 5 6 1 4 # ) ' $ # 5 + 0 6 1 $ ' . ' 9 5 % 4 ' ' - 5 6 ' # / 5 6 # 6 + 1 0 Belews Lake(Elevation 724.5') C R S - 2 CRS-6 CWB-2 C R S - 4 C W B - 1 C R S - 5 C R S - 1 CRS-3 5 % # . ' ( ' ' 6 2 0 0 0 2 0 0 4 0 0 0QVGU'NGXCVKQPQH$GNGYU.CMGKUCUUWOGF$CUGOCRCPFUVTGCOFCVCRTQXKFGF D [ & W M G ' P G T I [ % C T Q N K P C U . . % & C V G F / C [ D A T E F I G U R E F I G U R E D A T E 4 4 0 S o u t h C h u r c h S t r e e t C h a r l o t t e , N C 2 8 2 0 2 L i c e n s e N u m b e r : F - 0 1 1 6 S A M P L E L O C A T I O N S B E L E W S C R E E K S T E A M S T A T I O N C R A I G R O A D A S H L A N D F I L L , P H A S E 1 & 2 P E R M I T N O . 8 5 0 4 A P R I L 2 0 1 7 2 P 5 V T G C O N Q E C V K Q P E Q T T G U R Q P F U Y K V J ( C E K N K V [ $ Q W P F C T [ 6 1 $ ' . ' 9 5 % 4 ' ' - 5 6 ' # / 5 6 # 6 + 1 0 Belews Lake(Elevation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o u t h C h u r c h S t r e e t C h a r l o t t e , N C 2 8 2 0 2 L i c e n s e N u m b e r : F - 0 1 1 6 A P R I L 2 0 1 7 3 G E N E R A L I Z E D G R O U N D W A T E R S U R F A C E C O N T O U R S J A N U A R Y 2 0 1 7 B E L E W S C R E E K S T E A M S T A T I O N C R A I G R O A D A S H L A N D F I L L , P H A S E 1 & 2 P E R M I T N O . 8 5 0 4 P Tables Ta b l e 1 ‐ We l l Co n s t r u c t i o n In f o r m a t i o n Du k e En e r g y Ca r o l i n a s , LL C / B e l e w s Cr e e k St e a m St a t i o n Cr a i g Ro a d As h La n d f i l l Ph a s e 1 an d 2 ‐ Pe r m i t No . 85 0 4 We l l ID We l l In s t a l l a t i o n Da t e La t i t u d e L o n g i t u d e TO C El e v a t i o n (f t ) Gr o u n d Su r f a c e El e v a t i o n (f t ) We l l St i c k ‐up He i g h t Ab o v e Gr o u n d Su r f a c e (f t ) Gr o u n d w a t e r El e v a t i o n (f t ) De p t h to Wa t e r Be l o w TO C (f t ) To t a l Well De p t h Be l o w TO C (f t ) Depth to Top of Screen Below TOC (ft)Screened Interval Below TOC (ft)Geology of Screened IntervalWellDiameter (in)Casing Type CR W ‐2 1 2 / 1 3 / 2 0 0 6 3 6 . 2 6 9 0 9 9 1 ‐80 . 0 7 1 0 2 6 3 7 6 1 . 4 6 7 5 8 . 1 6 3 . 3 0 7 3 7 . 3 3 2 4 . 1 3 3 8 . 3 0 2 8 . 3 0 3 8 . 3 0 ‐ 28.30 S a p r o l i t e / P W R 2 P V C CR W ‐3 1 2 / 1 2 / 2 0 0 6 3 6 . 2 7 0 0 0 7 8 ‐80 . 0 7 0 0 5 8 3 7 4 6 . 3 9 7 4 3 . 0 1 3 . 3 8 7 3 7 . 9 1 8 . 4 8 1 8 . 3 8 8 . 3 8 1 8 . 3 8 ‐ 08.38 S a p r o l i t e 2 P V C CR W ‐4 1 2 / 1 2 / 2 0 0 6 3 6 . 2 7 0 5 3 4 8 ‐80 . 0 6 8 0 9 8 5 7 7 3 . 5 3 7 7 0 . 7 3 2 . 8 0 7 5 1 . 3 5 2 2 . 1 8 2 9 . 8 0 1 9 . 8 0 2 9 . 8 0 ‐ 19.80 P W R 2 P V C CR W ‐5 2 / 8 / 2 0 0 6 3 6 . 2 7 0 6 7 0 5 ‐80 . 0 6 6 3 4 4 6 7 6 4 . 7 4 7 6 1 . 4 4 3 . 3 0 7 4 7 . 6 9 1 7 . 0 5 2 3 . 3 0 1 3 . 3 0 2 3 . 3 0 ‐ 13.30 P W R 2 P V C CR W ‐6 1 2 / 1 4 / 2 0 0 6 3 6 . 2 7 0 6 6 4 9 ‐80 . 0 6 4 8 4 6 6 7 8 3 . 1 0 7 8 0 . 3 2 2 . 7 8 7 5 8 . 5 4 2 4 . 5 6 3 0 . 2 8 2 0 . 2 8 3 0 . 2 8 ‐ 20.28 S a p r o l i t e / P W R 2 P V C CR W ‐7 2 / 8 / 2 0 0 6 3 6 . 2 7 0 2 9 1 0 ‐80 . 0 6 4 6 0 0 7 7 8 5 . 0 8 7 8 1 . 0 9 3 . 9 9 7 5 7 . 5 8 2 7 . 5 0 3 0 . 9 9 2 0 . 9 9 3 0 . 9 9 ‐ 20.99 P W R 2 P V C CR W ‐8R 4 / 1 1 / 2 0 1 3 3 6 . 2 6 9 1 8 5 6 ‐80 . 0 6 4 7 7 3 9 7 7 6 . 3 9 7 7 3 . 6 8 2 . 7 1 7 4 7 . 8 7 2 8 . 5 2 3 9 . 7 1 2 9 . 7 1 3 9 . 7 1 ‐ 29.71 S a p r o l i t e / P W R 2 P V C CR W ‐9 1 2 / 1 4 / 2 0 0 6 3 6 . 2 6 7 6 7 6 1 ‐80 . 0 6 5 5 0 5 0 7 6 9 . 6 7 7 6 6 . 6 3 3 . 0 4 7 4 2 . 5 1 2 7 . 1 6 3 9 . 0 4 2 9 . 0 4 3 9 . 0 4 ‐ 29.04 S a p r o l i t e 2 P V C CR W ‐10 1 2 / 1 8 / 2 0 0 6 3 6 . 2 6 5 6 7 8 8 ‐80 . 0 6 6 1 8 4 9 7 7 7 . 2 3 7 7 3 . 9 4 3 . 2 9 7 5 3 . 4 9 2 3 . 7 4 3 1 . 2 9 2 1 . 2 9 3 1 . 2 9 ‐ 21.29 S a p r o l i t e / P W R 2 P V C CR W ‐11 1 2 / 1 8 / 2 0 1 2 3 6 . 2 6 3 7 6 3 4 ‐80 . 0 6 6 8 4 8 1 8 1 6 . 1 2 8 1 3 . 3 8 2 . 7 4 7 8 5 . 0 2 3 1 . 1 0 3 8 . 0 4 2 8 . 0 4 3 8 . 0 4 ‐ 28.04 P W R 2 P V C CR W ‐12 4 / 1 0 / 2 0 1 3 3 6 . 2 6 3 8 7 4 1 ‐80 . 0 6 8 5 8 3 1 8 3 7 . 9 3 8 3 5 . 0 0 2 . 9 3 8 0 1 . 4 1 3 6 . 5 2 4 4 . 6 3 3 4 . 6 3 4 4 . 6 3 ‐ 34.63 S a p r o l i t e / P W R 2 P V C CR W ‐13 4 / 1 0 / 2 0 1 3 3 6 . 2 6 5 1 7 3 0 ‐80 . 0 7 1 4 2 6 8 8 2 2 . 4 9 8 1 9 . 4 4 3 . 0 5 7 8 8 . 4 1 3 4 . 0 8 3 9 . 0 5 2 9 . 0 5 3 9 . 0 5 ‐ 29.05 S a p r o l i t e / P W R 2 P V C CR W ‐14 1 2 / 1 8 / 2 0 1 2 3 6 . 2 6 5 8 3 7 6 ‐80 . 0 7 2 9 3 0 5 7 9 4 . 8 7 7 9 2 . 2 3 2 . 6 4 7 7 1 . 3 1 2 3 . 5 6 4 0 . 8 4 2 5 . 8 4 4 0 . 8 4 ‐ 25.84 B e d r o c k 2 P V C CR W ‐15 4 / 9 / 2 0 1 3 3 6 . 2 6 6 9 8 2 7 ‐80 . 0 7 2 1 0 9 5 7 6 8 . 4 3 7 6 5 . 6 9 2 . 7 4 7 3 2 . 2 3 3 6 . 2 0 3 8 . 4 4 2 8 . 4 4 3 8 . 4 4 ‐ 28.44 P W R 2 P V C CR W ‐16 4 / 9 / 2 0 1 3 3 6 . 2 6 8 4 7 7 5 ‐80 . 0 7 1 7 8 0 5 7 7 3 . 5 9 7 7 0 . 5 8 3 . 0 1 7 3 0 . 2 6 4 3 . 3 3 5 0 . 0 1 4 0 . 0 1 5 0 . 0 1 ‐ 40.01 S a p r o l i t e / P W R 2 P V C CR W ‐17 1 / 6 / 2 0 1 1 3 6 . 2 6 2 7 8 5 4 ‐80 . 0 6 7 1 9 8 0 8 3 4 . 5 6 8 3 1 . 6 2 2 . 9 4 7 9 9 . 0 5 3 5 . 5 1 4 1 . 9 4 3 1 . 9 4 4 1 . 9 4 ‐ 31.94 S a p r o l i t e 2 P V C No t e s : 1.2.3.4.5.6.7.8.9. El e v a t i o n s ba s e d on NA V D 88 ve r t i c a l da t u m De p t h to wa t e r ga u g e d on Ja n u a r y 30 an d 31 , 20 1 7 In f o r m a t i o n pr o v i d e d by Du k e En e r g y Ca r o l i n a s , LL C on Fe b r u a r y 23 , 20 1 7 TO C in d i c a t e s to p of ca s i n g ft in d i c a t e s fe e t in in d i c a t e s in c h e s no m i n a l di a m e t e r PW R in d i c a t e s pa r t i a l l y we a t h e r e d ro c k PV C in d i c a t e s po l y v i n y l ch l o r i d e Ho r i z o n t a l da t u m as s u m e d to be NA D 8 3 Ta b l e 2 ‐ Gr o u n d w a t e r Fl o w Ve l o c i t i e s ‐ Ju l y 20 1 6 Du k e En e r g y Ca r o l i n a s , LL C / B e l e w s Cr e e k St e a m St a t i o n Cr a i g Ro a d As h La n d f i l l Ph a s e 1 an d 2 ‐ Pe r m i t No . 85 0 4 We l l ID Up g r a d i e n t Co n t o u r El e v a t i o n (f t ) Do w n g r a d i e n t Co n t o u r El e v a t i o n (f t ) Li n e a r Fl o w Di s t a n c e (f t ) Hy d r a u l i c Gr a d i e n t Hy d r a u l i c Co n d u c t i v i t y (f t / d a y ) Ef f e c t i v e Po r o s i t y (% ) Groundwater Velocity (ft/day) CR W ‐2 7 4 0 7 3 5 2 8 5 0 . 0 2 0 . 4 1 0 . 2 5 9 0 . 0 3 CR W ‐3 7 4 0 7 3 5 2 3 5 0 . 0 2 0 . 4 1 0 . 2 5 9 0 . 0 3 CR W ‐4 7 5 5 7 5 0 1 7 5 0 . 0 3 0 . 4 1 0 . 2 5 9 0 . 0 5 CR W ‐5 7 5 0 7 4 7 . 6 9 5 1 0 . 0 4 0 . 4 1 0 . 2 5 9 0 . 0 7 CR W ‐6 7 6 0 7 5 5 5 1 9 0 . 0 1 0 . 4 1 0 . 2 5 9 0 . 0 2 CR W ‐7 7 6 0 7 5 5 5 8 7 0 . 0 1 0 . 4 1 0 . 2 5 9 0 . 0 1 CR W ‐8R 7 5 0 7 4 7 . 8 7 6 0 0 . 0 4 0 . 4 1 0 . 2 5 9 0 . 0 6 CR W ‐9 7 4 5 7 4 2 . 5 1 5 1 0 . 0 5 0 . 4 1 0 . 2 5 9 0 . 0 8 CR W ‐10 7 5 5 7 5 0 1 2 4 0 . 0 4 0 . 4 1 0 . 2 5 9 0 . 0 6 CR W ‐11 7 9 0 7 8 5 1 3 5 0 . 0 4 0 . 4 1 0 . 2 5 9 0 . 0 6 CR W ‐12 8 0 1 . 4 1 8 0 0 6 0 0 . 0 2 0 . 4 1 0 . 2 5 9 0 . 0 4 CR W ‐13 7 9 0 7 8 5 1 7 9 0 . 0 3 0 . 4 1 0 . 2 5 9 0 . 0 4 CR W ‐14 7 7 5 7 7 0 1 2 9 0 . 0 4 0 . 4 1 0 . 2 5 9 0 . 0 6 CR W ‐15 7 3 5 7 3 0 9 6 0 . 0 5 0 . 4 1 0 . 2 5 9 0 . 0 8 CR W ‐16 7 3 5 7 3 0 2 2 0 0 . 0 2 0 . 4 1 0 . 2 5 9 0 . 0 4 CR W ‐17 8 0 0 7 9 5 1 5 5 0 . 0 3 0 . 4 1 0 . 2 5 9 0 . 0 5 No t e s : 1.2.3.4.5.6.7.8.9. ft in d i c a t e s fe e t Li n e a r di s t a n c e me a s u r e d th r o u g h mo n i t o r i n g we l l s is ge n e r a l l y pe r p e n d i c u l a r to gr o u n d w a t e r co n t o u r s At mo n i t o r i n g we l l lo c a t i o n s wh e r e do w n g r a d i e n t co n t o u r s ar e no t pr e s e n t , th e gr o u n d w a t e r el e v a t i o n at th e mo n i t o r i n g we l l is us e d as th e do w n g r a d i e n t gr o u n d w a t e r el e v a t i o n At mo n i t o r i n g we l l lo c a t i o n s wh e r e up g r a d i e n t co n t o u r s ar e no t pr e s e n t , th e gr o u n d w a t e r el e v a t i o n at th e mo n i t o r i n g we l l is us e d as th e up g r a d i e n t gr o u n d w a t e r el e v a t i o n . Mo n i t o r i n g we l l s ar e no t li s t e d wh e r e in s u f f i c i e n t gr o u n d w a t e r co n t o u r in f o r m a t i o n is av a i l a b l e to ca l c u l a t e ve l o c i t y Hy d r a u l i c gr a d i e n t s an d gr o u n d w a t e r ve l o c i t i e s ar e ap p r o x i m a t e . Hy d r a u l i c co n d u c t i v i t y pr e s e n t e d is th e ge o m e t r i c me a n of th e co n d u c t i v i t y da t a fo r th e on Ja n u a r y 30 an d 31 , 20 1 7 al l u v i u m / s o i l / s a p r o l i t e hy d r o s t r a t i g r a p h i c la y e r in th e HD R Co n d u c t i v i t y Da t a b a s e (u n p u b l i s h e d da t a fr o m Ca r o l i n a si t e s wi t h fo l i a t e d / l a y e r e d be d r o c k ) Ef f e c t i v e po r o s i t y pr e s e n t e d is th e me a n va l u e of th e al l u v i u m / s o i l / s a p r o l i t e hy d r o s t r a t i g r a p h i c la y e r es t i m a t e d fr o m so i l te s t i n g us i n g Fe t t e r / B e a r Di a g r a m s Hy d r a u l i c gr a d i e n t s an d gr o u n d w a t e r ve l o c i t i e s ca l c u l a t e d us i n g gr o u n d w a t e r de p t h me a s u r e d Ta b l e 3 ‐ Fi e l d Da t a Pa r a m e t e r s Du k e En e r g y Ca r o l i n a s , LL C / B e l e w s Cr e e k St e a m St a t i o n Cr a i g Ro a d As h La n d f i l l Ph a s e 1 an d 2 ‐ Pe r m i t No . 85 0 4 Da t e S a m p l e ID We l l De p t h Be l o w TO C (f t ) De p t h to Wa t e r Be l o w TO C (f t ) Gr o u n d w a t e r El e v a t i o n (f t ) A p p e a r a n c e O d o r P u r g e Me t h o d Av e r a g e Pu m p Ra t e (m L / m i n ) We l l Vo l u m e (g a l ) EV A C Vo l u m e (g a l ) EV A C (Y E S / N O ) Temperature (°C)Specific Conductance (µԼ /cm)pH (SU)Turbidity (NTU)ORP (mV ‐NHE)DO (mg/L) 1/ 3 0 / 2 0 1 7 C R W ‐2 3 8 . 2 4 2 4 . 1 3 7 3 7 . 3 3 N o r m a l N o n e L F 2 0 0 2 . 3 0 4 . 2 N / A 1 4 . 4 0 4 0 5 . 7 1 6 . 8 5 6 8 7 . 4 9 1/ 3 0 / 2 0 1 7 C R W ‐3 1 8 . 8 4 8 . 4 8 7 3 7 . 9 1 T u r b i d N o n e C P N / A 1 . 6 9 1 2 . 0 N O 1 4 . 0 2 6 2 5 . 6 6 2 . 6 5 3 1 6 . 2 2 1/ 3 0 / 2 0 1 7 C R W ‐4 3 0 . 1 9 2 2 . 1 8 7 5 1 . 3 5 N o r m a l N o n e C P N / A 1 . 3 1 7 . 5 N O 1 5 . 9 0 6 4 6 . 3 1 1 . 8 5 5 6 8 . 3 4 1/ 3 1 / 2 0 1 7 C R W ‐5 2 3 . 1 6 1 7 . 0 5 7 4 7 . 6 9 N o r m a l N o n e C P N / A 1 . 0 0 3 . 0 N O 1 4 . 9 8 9 1 5 . 8 3 . 9 2 6 6 0 . 0 0 1/ 3 0 / 2 0 1 7 C R W ‐6 3 0 . 2 0 2 4 . 5 6 7 5 8 . 5 4 N o r m a l N o n e C P N / A 0 . 9 2 1 . 0 Y E S 1 6 . 9 2 6 5 5 . 1 3 4 . 5 5 4 3 0 . 0 0 1/ 3 0 / 2 0 1 7 C R W ‐7 2 9 . 9 0 2 7 . 5 0 7 5 7 . 5 8 N / A N / A C P N / A 0 . 3 9 N / A N / A N / A N / A N / A N / A N / A N / A 1/ 3 1 / 2 0 1 7 C R W ‐8R 4 0 . 1 8 2 8 . 5 2 7 4 7 . 8 7 N o r m a l N o n e L F 2 7 0 1 . 9 0 3 . 0 N / A 1 4 . 4 3 9 2 5 . 7 1 7 . 5 5 3 9 8 . 4 4 1/ 3 1 / 2 0 1 7 C R W ‐9 3 9 . 6 2 2 7 . 1 6 7 4 2 . 5 1 N o r m a l N o n e L F 3 0 0 2 . 0 3 1 . 6 N / A 1 5 . 5 2 5 0 5 . 8 1 5 . 6 5 4 8 6 . 8 8 1/ 3 1 / 2 0 1 7 C R W ‐10 3 0 . 1 6 2 3 . 7 4 7 5 3 . 4 9 N o r m a l N o n e C P N / A 1 . 0 5 4 . 5 N O 1 3 . 7 0 1 9 5 5 . 6 5 . 4 5 4 2 3 . 5 7 1/ 3 1 / 2 0 1 7 C R W ‐11 3 8 . 5 2 3 1 . 1 0 7 8 5 . 0 2 N o r m a l N o n e E O P N / A 1 . 2 1 0 . 5 N / A 1 4 . 0 6 1 2 5 6 . 3 9 . 3 4 7 7 8 . 4 8 1/ 3 0 / 2 0 1 7 C R W ‐12 4 4 . 6 5 3 6 . 5 2 8 0 1 . 4 1 N o r m a l N o n e L F 1 5 0 1 . 3 3 0 . 9 N / A 1 3 . 4 2 5 4 5 . 5 9 . 4 5 5 7 7 . 7 5 1/ 3 0 / 2 0 1 7 C R W ‐13 3 9 . 2 8 3 4 . 0 8 7 8 8 . 4 1 N o r m a l N o n e C P N / A 0 . 8 5 4 . 0 N O 1 2 . 8 8 1 5 1 6 . 0 6 . 8 5 0 3 7 . 9 9 1/ 3 0 / 2 0 1 7 C R W ‐14 4 1 . 4 4 2 3 . 5 6 7 7 1 . 3 1 N o r m a l N o n e L F 4 0 0 2 . 9 2 4 . 2 N / A 1 4 . 8 6 2 6 6 6 . 0 5 . 4 5 0 8 6 . 4 6 1/ 3 0 / 2 0 1 7 C R W ‐15 3 8 . 8 2 3 6 . 2 0 7 3 2 . 2 3 N o r m a l N o n e E O P N / A 0 . 4 3 0 . 5 N / A 1 3 . 4 8 9 4 5 . 8 2 . 1 5 0 4 8 . 2 2 1/ 3 0 / 2 0 1 7 C R W ‐16 5 0 . 6 6 4 3 . 3 3 7 3 0 . 2 6 N o r m a l N o n e L F 1 9 2 1 . 2 0 3 . 3 N / A 1 1 . 8 0 7 0 5 . 7 1 0 . 7 5 5 6 3 . 2 6 1/ 3 1 / 2 0 1 7 C R W ‐17 4 1 . 7 0 3 5 . 5 1 7 9 9 . 0 5 N o r m a l N o n e E O P N / A 1 . 0 1 0 . 5 N / A 1 4 . 8 0 7 0 5 . 8 3 . 4 4 9 7 6 . 3 8 1/ 3 1 / 2 0 1 7 C R S ‐1 N / A N / A N / A N o r m a l N o n e N / A N / A N / A N / A N / A 4 . 8 9 1 0 7 6 . 5 4 . 4 4 0 7 1 0 . 3 6 1/ 3 1 / 2 0 1 7 C R S ‐2 N / A N / A N / A N o r m a l N o n e N / A N / A N / A N / A N / A 4 . 8 4 1 1 6 6 . 5 3 . 4 2 9 6 1 1 . 6 9 1/ 3 0 / 2 0 1 7 C R S ‐3 N / A N / A N / A N / A N / A N / A N / A N / A 1/ 3 0 / 2 0 1 7 C R S ‐4 N / A N / A N / A N o r m a l N o n e N / A N / A N / A N / A N / A 1 1 . 9 0 1 0 7 5 . 8 5 . 2 4 1 6 4 . 5 7 1/ 3 1 / 2 0 1 7 C R S ‐5 N / A N / A N / A O i l / S h e e n N o n e N / A N / A N / A N / A N / A 1 0 . 9 4 8 0 5 . 7 2 6 . 5 3 2 9 6 . 0 1 1/ 3 1 / 2 0 1 7 C R S ‐6 N / A N / A N / A N o r m a l N o n e N / A N / A N / A N / A N / A 1 4 . 9 4 9 8 5 . 9 1 2 . 7 4 9 2 8 . 1 9 1/ 3 0 / 2 0 1 7 C W B ‐1 N / A N / A N / A N o r m a l N o n e N / A N / A N / A N / A N / A 1 4 . 4 0 4 , 3 4 4 4 . 7 1 . 4 5 5 5 9 . 3 2 1/ 3 0 / 2 0 1 7 C W B ‐2 N / A N / A N / A N o r m a l N o n e N / A N / A N / A N / A N / A 1 6 . 0 5 6 , 3 8 9 3 . 8 1 . 3 5 9 6 8 . 5 0 1/ 3 0 / 2 0 1 7 C W B ‐3 N / A N / A N / A N / A N / A N / A N / A N / A No t e s : 1.2.3.4.5.6.7.8.9. 10 . 11 . 12 . 13 . 14 . 15 . 16 . 17 . Le a c h a t e sa m p l e s CW B ‐1 an d CW B ‐2 we r e fo r m e r l y id e n t i f i e d as E ‐WW B Le a c h a t e an d W ‐WW B Le a c h a t e , re s p e c t i v e l y Dry ‐ No SampleDry ‐ No Sample Gr o u n d w a t e r sa m p l e CR W ‐7, su r f a c e wa t e r sa m p l e CR S ‐3, an d le a c h a t e sa m p l e CW B ‐3 we r e no t co l l e c t e d du e to in s u f f i c i e n t wa t e r Fi e l d sa m p l i n g pe r f o r m e d by Du k e En e r g y Ca r o l i n a s , LL C pe r s o n n e l N/ A in d i c a t e s no t ap p l i c a b l e In f o r m a t i o n pr o v i d e d by Br y a n Mo e l l e r of Du k e En e r g y Ca r o l i n a s , LL C on Fe b r u a r y 23 , 20 1 7 Pu r g e Me t h o d s : LF = Lo w Fl o w , CP = Co n v e n t i o n a l Pu r g e (3 ‐5 we l l vo l u m e s ) , NP = No Pu r g e (H y d r a S l e e v e ) , EO P = Eq u i p m e n t On l y Pu r g e ; av e r a g e pu m p ra t e applicable to LF purging only EV A C in d i c a t e s wh e t h e r th e wa t e r le v e l in th e we l l wa s dr a w n do w n to th e le v e l of th e pu m p du r i n g pu r g i n g Laboratory Certification Codes: NT U in d i c a t e s ne p h e l o m e t r i c tu r b i d i t y un i t s mV ‐NH E in d i c a t e s mi l l i v o l t s ‐no r m a l hy d r o g e n el e c t r o d e ft in d i c a t e s fe e t mL / m i n in d i c a t e s mi l l i l i t e r s pe r mi n u t e ga l in d i c a t e s US ga l l o n s mg / L in d i c a t e s mi l l i g r a m s pe r li t e r °C in d i c a t e s de g r e e s ce l s i u s µԼ /c m in d i c a t e s mi c r o m h o s pe r ce n t i m e t e r TO C in d i c a t e s to p of ca s i n g SU in d i c a t e s st a n d a r d un i t s Duke Energy Carolinas Field #5193 Ta b l e 4A ‐ Gr o u n d w a t e r Fi e l d an d An a l y t i c a l Re s u l t s Du k e En e r g y Ca r o l i n a s , LL C / B e l e w s Cr e e k St e a m St a t i o n Cr a i g Ro a d As h La n d f i l l Ph a s e 1 an d 2 ‐ Pe r m i t No . 85 0 4 Sa m p l e Da t e : Fi e l d Sa m p l i n g Pe r f o r m e d By : Pa r a m e t e r S W S ID U n i t s Ce r t i f i c a t i o n Co d e MDL S W S L 15A NCAC 2L Standard Federal MCL Fi e l d pH 3 2 0 S U 5 1 9 3 ‐‐NE 6 . 5 ‐8.5 6 . 5 ‐8.5* Sp e c i f i c Co n d u c t a n c e 3 2 3 µ Լ /c m 5 1 9 3 ‐‐NE N E N E Te m p e r a t u r e 3 2 5 ° C 5 1 9 3 ‐‐NE N E N E To p of Ca s i n g 3 2 8 f e e t ‐ ‐‐NE N E N E De p t h to Wa t e r 3 1 8 f e e t ‐ ‐‐NE N E N E Wa t e r El e v a t i o n 4 2 7 f e e t ‐ ‐‐NE N E N E We l l De p t h 4 1 1 f e e t ‐ ‐‐NE N E N E Ar s e n i c 1 4 µ g / L 2 4 8 0. 2 0 5 J 0 . 3 1 8 J 0 . 1 6 J 0 . 0 7 8 U 0 . 3 8 5 J 0.078 1 0 1 0 1 0 Ba r i u m 1 5 µ g / L 2 4 8 48 . 6 J' 29 . 4 J' 5. 7 4 J' 14 . 4 J' 34.7 J'0.1 1 0 0 7 0 0 2 , 0 0 0 Bo r o n 4 2 8 µ g / L 2 4 8 3. 3 U 1 0 . 1 J 3 . 3 U 8 . 8 4 J 1 0 . 4 J 3.3 N E 7 0 0 N E Ca d m i u m 3 4 µ g / L 2 4 8 0. 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 U 0.101 1 2 5 Ch l o r i d e 4 5 5 µ g / L 2 4 8 1, 8 0 0 3 , 7 5 0 2 , 3 9 0 2 , 3 5 0 1 , 1 9 0 22 N E 2 5 0 , 0 0 0 2 5 0 , 0 0 0 * Ch r o m i u m 5 1 µ g / L 2 4 8 6. 9 J' 7. 5 7 J' 3. 9 2 J 0 . 5 U 5 . 0 7 J'0.5 1 0 1 0 1 0 0 Co p p e r 5 4 µ g / L 2 4 8 1U 1 U 1 U 1 U 5 . 0 4 J'1 1 0 1 , 0 0 0 1 , 0 0 0 * Fl u o r i d e 3 1 2 µ g / L 2 4 8 55 . 5 J 7 3 J 7 8 . 8 J 7 6 . 3 J 8 3 . 2 J 17 2 , 0 0 0 2 , 0 0 0 2 , 0 0 0 * Ir o n 3 4 0 µ g / L 2 4 8 1, 1 1 0 3 , 1 7 0 7 2 0 6 , 9 5 0 2 , 8 9 0 1.3 3 0 0 3 0 0 3 0 0 * Le a d 1 3 1 µ g / L 2 4 8 0. 5 3 2 J 1 . 4 4 J' 0. 2 2 2 J 0 . 0 6 5 U 1 . 6 3 J'0.065 1 0 1 5 1 5 Ma n g a n e s e 3 4 2 µ g / L 2 4 8 15 . 3 J' 58 . 7 10 . 6 J' 98 . 3 1 1 8 0.2 5 0 5 0 5 0 * Me r c u r y 1 3 2 µ g / L 2 4 8 0. 0 3 3 4 U 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0.0334 0 . 2 1 2 Ni c k e l 1 5 2 µ g / L 2 4 8 2. 5 2 J 2 . 6 7 J 0 . 7 1 6 J 1 1 . 9 J' 20.3 J'0.5 5 0 1 0 0 N E Ni t r a t e (a s Ni t r o g e n ) 3 0 3 µ g / L 2 4 8 71 . 3 J' 14 8 J' 95 4 J' 5. 4 U 5 . 4 U 5.4 1 0 , 0 0 0 1 0 , 0 0 0 1 0 , 0 0 0 Se l e n i u m 18 3 µ g / L 2 4 8 0. 0 9 2 U 0 . 0 9 2 U 0 . 0 9 2 U 0 . 0 9 2 U 0 . 0 9 2 U 0.092 1 0 2 0 5 0 Si l v e r 1 8 4 µ g / L 2 4 8 0. 0 8 6 J 0 . 0 5 1 U 0 . 0 5 1 U 0 . 0 5 1 U 0 . 1 2 8 J 0.051 1 0 2 0 1 0 0 * Su l f a t e 3 1 5 µ g / L 2 4 8 33 5 J' 5, 2 5 0 J' 21 2 0 J' 13 , 1 0 0 J' 22,100 J'18 2 5 0 , 0 0 0 2 5 0 , 0 0 0 2 5 0 , 0 0 0 * To t a l Di s s o l v e d So l i d s 3 1 1 µ g / L 2 4 8 54 , 0 0 0 8 9 , 0 0 0 7 3 , 0 0 0 7 8 , 0 0 0 7 6 , 0 0 0 16,700 N E 5 0 0 , 0 0 0 5 0 0 , 0 0 0 * Zi n c 2 1 3 µ g / L 2 4 8 7. 7 8 J' 11 . 8 3 . 0 8 J 1 7 . 3 2 2 . 3 2.6 1 0 1 , 0 0 0 5 , 0 0 0 * No t e s : 1.2.3.4.5.6.7.8.9. 10 . 11 . 12 . 13 . 14 . 15 . 16 . 17 . Laboratory Certification Codes:Duke Energy Carolinas Field #5193 Duke Energy Analytical Laboratory #248 CR W ‐2C R W ‐3C R W ‐4C R W ‐5C R W ‐6 Ja n u a r y 30 an d 31 , 20 1 7 CRW ‐7 Du k e En e r g y Ca r o l i n a s , LL C °C in d i c a t e s de g r e e s ce l s i u s "J " is us e d to id e n t i f y es t i m a t e d co n c e n t r a t i o n s wh i c h eq u a l or ar e gr e a t e r th a n th e MD L bu t ar e le s s th a n th e la b o r a t o r y ' s me t h o d re p o r t i n g li m i t (M R L ) , an d an it a l i c i z e d J' ‐fl a g is a da t a qu a l i f i e r , ad d e d by HD R to in d i c a t e co n c e n t r a t i o n s wh i c h eq u a l or ar e gr e a t e r th a n th e la b o r a t o r y ' s MR L bu t ar e le s s th a n th e SW S L SU in d i c a t e s st a n d a r d un i t s µԼ /c m in d i c a t e s mi c r o m h o s pe r ce n t i m e t e r Ac c o r d i n g to th e Co n s t i t u e n t Lo o k ‐up we b p a g e on th e NC D E Q Di v i s i o n of Wa s t e Ma n a g e m e n t we b p a g e , th e r e is no SW S L or 2L St a n d a r d fo r ch o r i d e as s o c i a t e d wi t h CA S nu m b e r 16887 ‐08 ‐6, which is the CAS reported by th e la b o r a t o r y fo r th e an a l y s e s co m p l e t e d ; th e r e f o r e , th e SW S L an d 2L St a n d a r d li s t e d ar e fo r th e ch l o r i d e wi t h CA S nu m b e r SW 3 0 1 as sp e c i f i e d on th e Co n s t i t u e n t Lo o k ‐up we b p a g e (last updated June 13, 2011) * Co n c e n t r a t i o n li s t e d is a se c o n d a r y ma x i m u m co n t a m i n a n t le v e l (S M C L ) ; SM C L s ar e es t a b l i s h e d by EP A in th e Na t i o n a l Se c o n d a r y Dr i n k i n g Wa t e r Re g u l a t i o n s as fo u n d in 40 CFR §143.330.20 76 4 . 7 4 7 8 3 . 1 0 7 8 5 . 0 8 29.90757.5827.50 23 . 1 6 76 1 . 4 6 7 4 6 . 3 9 7 7 3 . 5 3 24.56 758.54 74 7 . 6 9 17 . 0 5 24 . 1 3 73 7 . 3 3 38 . 2 4 22 . 1 8 75 1 . 3 5 30 . 1 9 18 . 8 4 73 7 . 9 1 8. 4 8 5. 6 5. 7 40 14 . 4 0 1 4 . 9 8 915. 8 6. 3 64 15 . 9 0 62 14 . 0 2 NSNS5.1 65 16.92 N S NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS No sa m p l e wa s co l l e c t e d fr o m CR W ‐7 du e to in s u f f i c i e n t wa t e r NS NS NS NS Qu a l i f i e r s in no n ‐it a l i c i z e d te x t ar e la b o r a t o r y da t a qu a l i f i e r s or "f l a g s " , "U " is us e d to id e n t i f y re s u l t s no t de t e c t e d at co n c e n t r a t i o n s wh i c h eq u a l th e la b o r a t o r y ' s MD L , NE in d i c a t e s no t es t a b l i s h e d ; NA in d i c a t e s no t an a l y z e d ; NS in d i c a t e s no sa m p l e wa s co l l e c t e d ; bl a n k ce l l s in d i c a t e th a t th e r e is no in f o r m a t i o n re l e v a n t to th e re s p e c t i v e ro w Bo l d va l u e s in d i c a t e va l u e s th a t at t a i n or ex c e e d th e 15 A NC A C 2L St a n d a r d An a l y t i c a l re s u l t s ob t a i n e d fr o m El e c t r o n i c Da t a De l i v e r a b l e (E D D ) pr o v i d e d by Br y a n Mo e l l e r of Du k e En e r g y Ca r o l i n a s , LL C on Fe b r u a r y 23 , 20 1 7 Gr a y e d va l u e s in d i c a t e va l u e s th a t eq u a l or ar e gr e a t e r th a n th e SW S L µg / L in d i c a t e s mi c r o g r a m s pe r li t e r SW S ID is th e So l i d Wa s t e Se c t i o n Id e n t i f i c a t i o n Nu m b e r MD L is th e la b o r a t o r y me t h o d de t e c t i o n li m i t . Th e MD L va l u e s pr e s e n t e d ar e fo r sa m p l e s no t di l u t e d by th e la b o r a t o r y du r i n g an a l y s i s SW S L is th e So l i d Wa s t e Se c t i o n Li m i t . NC D E Q de f i n e s th e SW S L as th e lo w e s t am o u n t of an a l y t e in a sa m p l e th a t ca n be qu a n t i t a t i v e l y de t e r m i n e d wi t h su i t a b l e pr e c i s i o n an d accuracy 15 A NC A C 2L St a n d a r d re f e r s to Cl a s s GA St a n d a r d s as fo u n d in 15 A NC A C 02 L .0 2 0 2 Gr o u n d w a t e r Qu a l i t y St a n d a r d s , la s t am e n d e d on Ap r i l 1, 20 1 3 MC L is th e Fe d e r a l Ma x i m u m Co n t a m i n a n t Le v e l as fo u n d in 40 CF R , Su b p a r t G, §1 4 1 . 6 2 Ta b l e 4B ‐ Gr o u n d w a t e r Fi e l d an d An a l y t i c a l Re s u l t s Du k e En e r g y Ca r o l i n a s , LL C / B e l e w s Cr e e k St e a m St a t i o n Cr a i g Ro a d As h La n d f i l l Ph a s e 1 an d 2 ‐ Pe r m i t No . 85 0 4 Sa m p l e Da t e : Fi e l d Sa m p l i n g Pe r f o r m e d By : Pa r a m e t e r S W S ID U n i t s Ce r t i f i c a t i o n Co d e MDL S W S L 15A NCAC 2L Standard Federal MCL Fi e l d pH 3 2 0 S U 5 1 9 3 ‐‐NE 6 . 5 ‐8.5 6 . 5 ‐8.5* Sp e c i f i c Co n d u c t a n c e 3 2 3 µ Լ /c m 5 1 9 3 ‐‐NE N E N E Te m p e r a t u r e 3 2 5 ° C 5 1 9 3 ‐‐NE N E N E To p of Ca s i n g 3 2 8 f e e t ‐ ‐‐NE N E N E De p t h to Wa t e r 3 1 8 f e e t ‐ ‐‐NE N E N E Wa t e r El e v a t i o n 4 2 7 f e e t ‐ ‐‐NE N E N E We l l De p t h 4 1 1 f e e t ‐ ‐‐NE N E N E Ar s e n i c 1 4 µ g / L 2 4 8 0. 1 3 7 J 0 . 2 9 1 J 0 . 0 9 6 6 J 0 . 0 8 6 4 J 0 . 0 7 8 U 0.078 1 0 1 0 1 0 Ba r i u m 1 5 µ g / L 2 4 8 65 . 8 J' 17 . 1 J' 11 . 1 J' 22 . 2 J' 21.7 J'0.1 1 0 0 7 0 0 2 , 0 0 0 Bo r o n 4 2 8 µ g / L 2 4 8 4. 5 4 J 3 . 8 3 J 1 3 . 1 J 3 . 7 9 J 3 . 6 J 3.3 N E 7 0 0 N E Ca d m i u m 3 4 µ g / L 2 4 8 0. 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 U 0.101 1 2 5 Ch l o r i d e 4 5 5 µ g / L 2 4 8 4, 3 6 0 2 , 2 8 0 1 3 , 6 0 0 4 , 5 9 0 2 , 0 2 0 22 N E 2 5 0 , 0 0 0 2 5 0 , 0 0 0 * Ch r o m i u m 5 1 µ g / L 2 4 8 2. 5 9 J 5 . 1 J' 0. 9 1 9 J 4 . 4 1 J 1 . 9 3 J 0.5 1 0 1 0 1 0 0 Co p p e r 5 4 µ g / L 2 4 8 1 U 1 . 7 9 J 1 U 1 U 1 U 1 1 0 1 , 0 0 0 1 , 0 0 0 * Fl u o r i d e 3 1 2 µ g / L 2 4 8 45 . 8 J 1 7 U 5 5 . 6 J 5 2 . 4 J 1 7 U 17 2 , 0 0 0 2 , 0 0 0 2 , 0 0 0 * Ir o n 3 4 0 µ g / L 2 4 8 65 1 7 9 3 3 5 6 19 1 J' 358 1.3 3 0 0 3 0 0 3 0 0 * Le a d 1 3 1 µ g / L 2 4 8 0. 4 2 4 J 0 . 3 3 3 J 0 . 1 0 1 J 0 . 0 6 5 U 0 . 2 1 4 J 0.065 1 0 1 5 1 5 Ma n g a n e s e 3 4 2 µ g / L 2 4 8 10 . 9 J' 11 . 3 J' 28 . 8 J' 3. 2 4 J 9 . 9 2 J'0.2 5 0 5 0 5 0 * Me r c u r y 1 3 2 µ g / L 2 4 8 0. 0 3 3 4 U 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0.0334 0 . 2 1 2 Ni c k e l 1 5 2 µ g / L 2 4 8 0. 7 9 5 J 1 . 5 5 J 0 . 7 1 5 J 1 . 6 1 J 0 . 5 U 0.5 5 0 1 0 0 N E Ni t r a t e (a s Ni t r o g e n ) 3 0 3 µ g / L 2 4 8 3, 1 3 0 J' 59 6 J' 45 1 J' 2, 7 5 0 J' 266 J'5.4 1 0 , 0 0 0 1 0 , 0 0 0 1 0 , 0 0 0 Se l e n i u m 18 3 µ g / L 2 4 8 0. 0 9 2 U 0 . 0 9 2 U 0 . 0 9 2 U 0 . 0 9 2 U 0 . 0 9 2 U 0.092 1 0 2 0 5 0 Si l v e r 1 8 4 µ g / L 2 4 8 0. 0 5 1 U 0 . 0 5 1 U 0 . 0 5 1 U 0 . 0 5 1 U 0 . 0 5 1 U 0.051 1 0 2 0 1 0 0 * Su l f a t e 3 1 5 µ g / L 2 4 8 1, 3 6 0 J' 1, 7 2 0 J' 48 , 9 0 0 J' 62 6 J' 163 J'18 2 5 0 , 0 0 0 2 5 0 , 0 0 0 2 5 0 , 0 0 0 * To t a l Di s s o l v e d So l i d s 3 1 1 µ g / L 2 4 8 90 , 0 0 0 5 5 , 0 0 0 1 3 6 , 0 0 0 9 4 , 0 0 0 6 0 , 0 0 0 16,700 N E 5 0 0 , 0 0 0 5 0 0 , 0 0 0 * Zi n c 2 1 3 µ g / L 2 4 8 3. 4 3 J 3 . 8 2 J 2 . 7 7 J 2 . 6 U 2 . 6 5 J 2.6 1 0 1 , 0 0 0 5 , 0 0 0 * No t e s : 1.2.3.4.5.6.7.8.9. 10 . 11 . 12 . 13 . 14 . 15 . 16 . 44.65 38 . 5 2 78 5 . 0 2 12 5 Laboratory Certification Codes:Duke Energy Carolinas Field #5193 Duke Energy Analytical Laboratory #248 CR W ‐8R C R W ‐9C R W ‐10 C R W ‐11 C R W ‐12 Du k e En e r g y Ca r o l i n a s , LL C Ja n u a r y 30 an d 31 , 20 1 7 5.5 54 SW S L is th e So l i d Wa s t e Se c t i o n Li m i t . NC D E Q de f i n e s th e SW S L as th e lo w e s t am o u n t of an a l y t e in a sa m p l e th a t ca n be qu a n t i t a t i v e l y de t e r m i n e d wi t h su i t a b l e pr e c i s i o n and accuracy SU in d i c a t e s st a n d a r d un i t s µԼ /c m in d i c a t e s mi c r o m h o s pe r ce n t i m e t e r SW S ID is th e So l i d Wa s t e Se c t i o n Id e n t i f i c a t i o n Nu m b e r °C in d i c a t e s de g r e e s ce l s i u s 15 A NC A C 2L St a n d a r d re f e r s to Cl a s s GA St a n d a r d s as fo u n d in 15 A NC A C 02 L .0 2 0 2 Gr o u n d w a t e r Qu a l i t y St a n d a r d s , la s t am e n d e d on Ap r i l 1, 20 1 3 MC L is th e Fe d e r a l Ma x i m u m Co n t a m i n a n t Le v e l as fo u n d in 40 CF R , Su b p a r t G, §1 4 1 . 6 2 * Co n c e n t r a t i o n li s t e d is a se c o n d a r y ma x i m u m co n t a m i n a n t le v e l (S M C L ) ; SM C L s ar e es t a b l i s h e d by EP A in th e Na t i o n a l Se c o n d a r y Dr i n k i n g Wa t e r Re g u l a t i o n s as fo u n d in 40 CFR §143.3 by th e la b o r a t o r y fo r th e an a l y s e s co m p l e t e d ; th e r e f o r e , th e SW S L an d 2L St a n d a r d li s t e d ar e fo r th e ch l o r i d e wi t h CA S nu m b e r SW 3 0 1 as sp e c i f i e d on th e Co n s t i t u e n t Look ‐up webpage (last updated June 13, 2011) NE in d i c a t e s no t es t a b l i s h e d ; NA in d i c a t e s no t an a l y z e d ; bl a n k ce l l s in d i c a t e th a t th e r e is no in f o r m a t i o n re l e v a n t to th e re s p e c t i v e ro w 13.42 28 . 5 2 2 7 . 1 6 3 1 . 1 0 3 6 . 5 2 837.93 77 6 . 3 9 7 6 9 . 6 7 505. 8 5. 7 92 81 6 . 1 2 6. 3 5. 6 19 5 801.41 µg / L in d i c a t e s mi c r o g r a m s pe r li t e r 15 . 5 2 77 7 . 2 3 Gr a y e d va l u e s in d i c a t e va l u e s th a t eq u a l or ar e gr e a t e r th a n th e SW S L 13 . 7 0 1 4 . 0 6 14 . 4 3 40 . 1 8 23 . 7 4 75 3 . 4 9 30 . 1 6 39 . 6 2 Ac c o r d i n g to th e Co n s t i t u e n t Lo o k ‐up we b p a g e on th e NC D E Q Di v i s i o n of Wa s t e Ma n a g e m e n t we b p a g e , th e r e is no SW S L or 2L St a n d a r d fo r ch o r i d e as s o c i a t e d wi t h CAS number 16887 ‐08 ‐6, which is the CAS reported 74 7 . 8 7 7 4 2 . 5 1 Bo l d va l u e s in d i c a t e va l u e s th a t at t a i n or ex c e e d th e 15 A NC A C 2L St a n d a r d MD L is th e la b o r a t o r y me t h o d de t e c t i o n li m i t . Th e MD L va l u e s pr e s e n t e d ar e fo r sa m p l e s no t di l u t e d by th e la b o r a t o r y du r i n g an a l y s i s Qu a l i f i e r s in no n ‐it a l i c i z e d te x t ar e la b o r a t o r y da t a qu a l i f i e r s or "f l a g s " , "U " is us e d to id e n t i f y re s u l t s no t de t e c t e d at co n c e n t r a t i o n s wh i c h eq u a l th e la b o r a t o r y ' s MD L , "J " is us e d to id e n t i f y es t i m a t e d co n c e n t r a t i o n s wh i c h eq u a l or ar e gr e a t e r th a n th e MD L bu t ar e le s s th a n th e la b o r a t o r y ' s me t h o d re p o r t i n g li m i t (M R L ) , an d an it a l i c i z e d J' ‐fl a g is a da t a qu a l i f i e r , ad d e d by HD R to in d i c a t e co n c e n t r a t i o n s wh i c h eq u a l or ar e gr e a t e r th a n th e la b o r a t o r y ' s MR L bu t ar e le s s th a n th e SW S L An a l y t i c a l re s u l t s ob t a i n e d fr o m El e c t r o n i c Da t a De l i v e r a b l e (E D D ) pr o v i d e d by Br y a n Mo e l l e r of Du k e En e r g y Ca r o l i n a s , LL C on Fe b r u a r y 23 , 20 1 7 Ta b l e 4C ‐ Gr o u n d w a t e r Fi e l d an d An a l y t i c a l Re s u l t s Du k e En e r g y Ca r o l i n a s , LL C / B e l e w s Cr e e k St e a m St a t i o n Cr a i g Ro a d As h La n d f i l l Ph a s e 1 an d 2 ‐ Pe r m i t No . 85 0 4 Sa m p l e Da t e : Fi e l d Sa m p l i n g Pe r f o r m e d By : Pa r a m e t e r S W S ID U n i t s Ce r t i f i c a t i o n Co d e MDL S W S L 15A NCAC 2L Standard Federal MCL Fi e l d pH 3 2 0 S U 5 1 9 3 ‐‐NE 6 . 5 ‐8.5 6 . 5 ‐8.5* Sp e c i f i c Co n d u c t a n c e 3 2 3 µ Լ /c m 5 1 9 3 ‐‐NE N E N E Te m p e r a t u r e 3 2 5 ° C 5 1 9 3 ‐‐NE N E N E To p of Ca s i n g 3 2 8 f e e t ‐ ‐‐NE N E N E De p t h to Wa t e r 3 1 8 f e e t ‐ ‐‐NE N E N E Wa t e r El e v a t i o n 4 2 7 f e e t ‐ ‐‐NE N E N E We l l De p t h 4 1 1 f e e t ‐ ‐‐NE N E N E Ar s e n i c 1 4 µ g / L 2 4 8 0. 0 7 8 U 0 . 2 8 9 J 0 . 0 7 8 U 0 . 0 7 8 U 0 . 4 9 1 J 0.078 1 0 1 0 1 0 Ba r i u m 1 5 µ g / L 2 4 8 18 . 6 J' 38 . 1 J' 9. 8 6 J' 27 . 1 J' 50.7 J'0.1 1 0 0 7 0 0 2 , 0 0 0 Bo r o n 4 2 8 µ g / L 2 4 8 3. 3 U 5 . 7 8 J 6 . 4 J 3 . 3 U 2 9 . 7 J 3.3 N E 7 0 0 N E Ca d m i u m 3 4 µ g / L 2 4 8 0. 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 U 0.101 1 2 5 Ch l o r i d e 4 5 5 µ g / L 2 4 8 15 , 5 0 0 2 9 , 0 0 0 1 0 , 0 0 0 4 , 9 1 0 2 , 1 2 0 22 N E 2 5 0 , 0 0 0 2 5 0 , 0 0 0 * Ch r o m i u m 5 1 µ g / L 2 4 8 2. 9 6 J 0 . 5 U 0 . 6 2 2 J 2 J 1 . 6 1 J 0.5 1 0 1 0 1 0 0 Co p p e r 5 4 µ g / L 2 4 8 1U 1 . 6 9 J 1 . 0 8 J 1 U 1 U 1 1 0 1 , 0 0 0 1 , 0 0 0 * Fl u o r i d e 3 1 2 µ g / L 2 4 8 54 J 2 2 7 J' 51 . 1 J 1 7 U 4 3 . 7 J 17 2 , 0 0 0 2 , 0 0 0 2 , 0 0 0 * Ir o n 3 4 0 µ g / L 2 4 8 32 6 18 7 J' 48 . 3 J' 36 9 4 0 4 1.3 3 0 0 3 0 0 3 0 0 * Le a d 1 3 1 µ g / L 2 4 8 0. 0 7 9 J 0 . 0 6 6 J 0 . 0 6 5 U 0 . 2 3 3 J 0 . 2 1 2 J 0.065 1 0 1 5 1 5 Ma n g a n e s e 3 4 2 µ g / L 2 4 8 7. 5 J' 15 . 8 J' 6. 9 2 J' 11 . 2 J' 10.3 J'0.2 5 0 5 0 5 0 * Me r c u r y 1 3 2 µ g / L 2 4 8 0. 0 3 3 4 U 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0.0334 0 . 2 1 2 Ni c k e l 1 5 2 µ g / L 2 4 8 0. 5 U 2 . 2 5 J 1 . 7 2 J 0 . 7 3 J 0 . 5 1 5 J 0.5 5 0 1 0 0 N E Ni t r a t e (a s Ni t r o g e n ) 3 0 3 µ g / L 2 4 8 1, 9 2 0 J' 4, 3 4 0 J' 90 . 6 J' 81 . 5 J' 30.6 J'5.4 1 0 , 0 0 0 1 0 , 0 0 0 1 0 , 0 0 0 Se l e n i u m 18 3 µ g / L 2 4 8 0. 0 9 2 U 0 . 2 7 5 J 0 . 1 4 6 J 0 . 0 9 2 U 0 . 0 9 2 U 0.092 1 0 2 0 5 0 Si l v e r 1 8 4 µ g / L 2 4 8 0. 0 5 1 U 0 . 1 7 4 J 0 . 1 6 J 0 . 0 5 1 U 0 . 0 5 1 U 0.051 1 0 2 0 1 0 0 * Su l f a t e 3 1 5 µ g / L 2 4 8 1, 0 5 0 J' 22 , 7 0 0 J' 2, 9 0 0 J' 1, 2 9 0 J' 249 J'18 2 5 0 , 0 0 0 2 5 0 , 0 0 0 2 5 0 , 0 0 0 * To t a l Di s s o l v e d So l i d s 3 1 1 µ g / L 2 4 8 10 8 , 0 0 0 1 8 6 , 0 0 0 7 1 , 0 0 0 6 5 , 0 0 0 5 2 , 0 0 0 16,700 N E 5 0 0 , 0 0 0 5 0 0 , 0 0 0 * Zi n c 2 1 3 µ g / L 2 4 8 2. 6 U 5 . 4 2 J' 12 . 1 2 . 6 U 4 . 0 8 J 2.6 1 0 1 , 0 0 0 5 , 0 0 0 * No t e s : 1.2.3.4.5.6.7.8.9. 10 . 11 . 12 . 13 . 14 . 15 . 16 . An a l y t i c a l re s u l t s ob t a i n e d fr o m El e c t r o n i c Da t a De l i v e r a b l e (E D D ) pr o v i d e d by Br y a n Mo e l l e r of Du k e En e r g y Ca r o l i n a s , LL C on Fe b r u a r y 23 , 20 1 7 Gr a y e d va l u e s in d i c a t e va l u e s th a t eq u a l or ar e gr e a t e r th a n th e SW S L Bo l d va l u e s in d i c a t e va l u e s th a t at t a i n or ex c e e d th e 15 A NC A C 2L St a n d a r d MD L is th e la b o r a t o r y me t h o d de t e c t i o n li m i t . Th e MD L va l u e s pr e s e n t e d ar e fo r sa m p l e s no t di l u t e d by th e la b o r a t o r y du r i n g an a l y s i s Qu a l i f i e r s in no n ‐it a l i c i z e d te x t ar e la b o r a t o r y da t a qu a l i f i e r s or "f l a g s " , "U " is us e d to id e n t i f y re s u l t s no t de t e c t e d at co n c e n t r a t i o n s wh i c h eq u a l th e la b o r a t o r y ' s MD L , "J " is us e d to id e n t i f y es t i m a t e d co n c e n t r a t i o n s wh i c h eq u a l or ar e gr e a t e r th a n th e MD L bu t ar e le s s th a n th e la b o r a t o r y ' s me t h o d re p o r t i n g li m i t (M R L ) , an d an it a l i c i z e d J' ‐fl a g is a da t a qu a l i f i e r , ad d e d by HD R to in d i c a t e co n c e n t r a t i o n s wh i c h eq u a l or ar e gr e a t e r th a n th e la b o r a t o r y ' s MR L bu t ar e le s s th a n th e SW S L NE in d i c a t e s no t es t a b l i s h e d ; NA in d i c a t e s no t an a l y z e d ; bl a n k ce l l s in d i c a t e th a t th e r e is no in f o r m a t i o n re l e v a n t to th e re s p e c t i v e ro w µg / L in d i c a t e s mi c r o g r a m s pe r li t e r °C in d i c a t e s de g r e e s ce l s i u s SU in d i c a t e s st a n d a r d un i t s µԼ /c m in d i c a t e s mi c r o m h o s pe r ce n t i m e t e r SW S ID is th e So l i d Wa s t e Se c t i o n Id e n t i f i c a t i o n Nu m b e r SW S L is th e So l i d Wa s t e Se c t i o n Li m i t . NC D E Q de f i n e s th e SW S L as th e lo w e s t am o u n t of an a l y t e in a sa m p l e th a t ca n be qu a n t i t a t i v e l y de t e r m i n e d wi t h su i t a b l e pr e c i s i o n and accuracy 15 A NC A C 2L St a n d a r d re f e r s to Cl a s s GA St a n d a r d s as fo u n d in 15 A NC A C 02 L .0 2 0 2 Gr o u n d w a t e r Qu a l i t y St a n d a r d s , la s t am e n d e d on Ap r i l 1, 20 1 3 MC L is th e Fe d e r a l Ma x i m u m Co n t a m i n a n t Le v e l as fo u n d in 40 CF R , Su b p a r t G, §1 4 1 . 6 2 * Co n c e n t r a t i o n li s t e d is a se c o n d a r y ma x i m u m co n t a m i n a n t le v e l (S M C L ) ; SM C L s ar e es t a b l i s h e d by EP A in th e Na t i o n a l Se c o n d a r y Dr i n k i n g Wa t e r Re g u l a t i o n s as fo u n d in 40 CFR §143.3 Ac c o r d i n g to th e Co n s t i t u e n t Lo o k ‐up we b p a g e on th e NC D E Q Di v i s i o n of Wa s t e Ma n a g e m e n t we b p a g e , th e r e is no SW S L or 2L St a n d a r d fo r ch o r i d e as s o c i a t e d wi t h CAS number 16887 ‐08 ‐6, which is the CAS reported by th e la b o r a t o r y fo r th e an a l y s e s co m p l e t e d ; th e r e f o r e , th e SW S L an d 2L St a n d a r d li s t e d ar e fo r th e ch l o r i d e wi t h CA S nu m b e r SW 3 0 1 as sp e c i f i e d on th e Co n s t i t u e n t Look ‐up webpage (last updated June 13, 2011) 78 8 . 4 1 7 7 1 . 3 1 7 3 2 . 2 3 7 3 0 . 2 6 7 9 9 . 0 5 39 . 2 8 4 1 . 4 4 3 8 . 8 2 5 0 . 6 6 4 1 . 7 0 82 2 . 4 9 7 9 4 . 8 7 7 6 8 . 4 3 7 7 3 . 5 9 8 3 4 . 5 6 34 . 0 8 2 3 . 5 6 3 6 . 2 0 4 3 . 3 3 3 5 . 5 1 15 1 2 6 6 9 4 7 0 7 0 12 . 8 8 1 4 . 8 6 1 3 . 4 8 1 1 . 8 0 1 4 . 8 0 Ja n u a r y 30 an d 31 , 20 1 7 Laboratory Certification Codes: Du k e En e r g y Ca r o l i n a s , LL C Duke Energy Carolinas Field #5193 Duke Energy Analytical Laboratory #248 6. 0 6 . 0 5 . 8 5 . 7 5 . 8 CR W ‐13 C R W ‐14 C R W ‐15 C R W ‐16 C R W ‐17 Ta b l e 4D ‐ Gr o u n d w a t e r Fi e l d an d An a l y t i c a l Re s u l t s Du k e En e r g y Ca r o l i n a s , LL C / B e l e w s Cr e e k St e a m St a t i o n Cr a i g Ro a d As h La n d f i l l Ph a s e 1 an d 2 ‐ Pe r m i t No . 85 0 4 Sa m p l e Da t e : Fi e l d Sa m p l i n g Pe r f o r m e d By : Pa r a m e t e r S W S ID U n i t s Ce r t i f i c a t i o n Co d e MDL S W S L 15A NCAC 2L Standard Federal MCL Fi e l d pH 3 2 0 S U 5 1 9 3 ‐‐NE 6 . 5 ‐8.5 6 . 5 ‐8.5* Sp e c i f i c Co n d u c t a n c e 3 2 3 µ Լ /c m 5 1 9 3 ‐‐NE N E N E Te m p e r a t u r e 3 2 5 ° C 5 1 9 3 ‐‐NE N E N E To p of Ca s i n g 3 2 8 f e e t ‐ ‐‐NE N E N E De p t h to Wa t e r 3 1 8 f e e t ‐ ‐‐NE N E N E Wa t e r El e v a t i o n 4 2 7 f e e t ‐ ‐‐NE N E N E We l l De p t h 4 1 1 f e e t ‐ ‐‐NE N E N E Ar s e n i c 1 4 µ g / L 2 4 8 0. 0 9 9 J 0 . 3 6 1 J 0 . 0 7 8 U 0.078 1 0 1 0 1 0 Ba r i u m 1 5 µ g / L 2 4 8 14 . 1 J' 36 . 2 J' 0. 1 U 0.1 1 0 0 7 0 0 2 , 0 0 0 Bo r o n 4 2 8 µ g / L 2 4 8 69 . 5 1 0 . 4 J 3 . 3 U 3.3 N E 7 0 0 N E Ca d m i u m 3 4 µ g / L 2 4 8 0. 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 U 0.101 1 2 5 Ch l o r i d e 4 5 5 µ g / L 2 4 8 5, 3 6 0 4 , 1 5 0 2 2 U 22 N E 2 5 0 , 0 0 0 2 5 0 , 0 0 0 * Ch r o m i u m 5 1 µ g / L 2 4 8 2. 1 2 J 0 . 9 3 7 J 0 . 5 U 0.5 1 0 1 0 1 0 0 Co p p e r 5 4 µ g / L 2 4 8 1U 1 U 1 U 1 1 0 1 , 0 0 0 1 , 0 0 0 * Fl u o r i d e 3 1 2 µ g / L 2 4 8 50 . 2 J 4 6 . 4 J 1 7 U 17 2 , 0 0 0 2 , 0 0 0 2 , 0 0 0 * Ir o n 3 4 0 µ g / L 2 4 8 57 8 5 , 8 7 0 2. 0 6 J 1.3 3 0 0 3 0 0 3 0 0 * Le a d 1 3 1 µ g / L 2 4 8 0. 2 0 5 J 0 . 5 5 2 J 0 . 0 6 5 U 0.065 1 0 1 5 1 5 Ma n g a n e s e 3 4 2 µ g / L 2 4 8 38 . 2 J' 26 4 0. 2 U 0.2 5 0 5 0 5 0 * Me r c u r y 1 3 2 µ g / L 2 4 8 0. 0 3 3 4 U 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0.0334 0 . 2 1 2 Ni c k e l 1 5 2 µ g / L 2 4 8 0. 5 U 0 . 9 9 7 J 0 . 5 U 0.5 5 0 1 0 0 N E Ni t r a t e (a s Ni t r o g e n ) 3 0 3 µ g / L 2 4 8 45 2 J' 17 . 1 J 5 . 4 U 5.4 1 0 , 0 0 0 1 0 , 0 0 0 1 0 , 0 0 0 Se l e n i u m 18 3 µ g / L 2 4 8 0. 1 4 J 0 . 0 9 2 U 0 . 0 9 2 U 0.092 1 0 2 0 5 0 Si l v e r 1 8 4 µ g / L 2 4 8 0. 0 5 1 U 0 . 0 5 1 U 0 . 0 5 1 U 0.051 1 0 2 0 1 0 0 * Su l f a t e 3 1 5 µ g / L 2 4 8 17 , 1 0 0 J' 10 , 4 0 0 J' 18 U 18 2 5 0 , 0 0 0 2 5 0 , 0 0 0 2 5 0 , 0 0 0 * To t a l Di s s o l v e d So l i d s 3 1 1 µ g / L 2 4 8 95 , 0 0 0 5 7 , 0 0 0 16,700 N E 5 0 0 , 0 0 0 5 0 0 , 0 0 0 * Zi n c 2 1 3 µ g / L 2 4 8 7. 4 1 J' 12 . 8 2 . 6 U 2.6 1 0 1 , 0 0 0 5 , 0 0 0 * No t e s : 1.2.3.4.5.6.7.8.9. 10 . 11 . 12 . 13 . 14 . 15 . 16 . on th e Co n s t i t u e n t Lo o k ‐up we b p a g e (l a s t up d a t e d Ju n e 13 , 20 1 1 ) to in d i c a t e co n c e n t r a t i o n s wh i c h eq u a l or ar e gr e a t e r th a n th e la b o r a t o r y ' s MR L bu t ar e le s s th a n th e SW S L 15 A NC A C 2L St a n d a r d re f e r s to Cl a s s GA St a n d a r d s as fo u n d in 15 A NC A C 02 L .0 2 0 2 Gr o u n d w a t e r Qu a l i t y St a n d a r d s , la s t am e n d e d on Ap r i l 1, 20 1 3 MC L is th e Fe d e r a l Ma x i m u m Co n t a m i n a n t Le v e l as fo u n d in 40 CF R , Su b p a r t G, §1 4 1 . 6 2 * Co n c e n t r a t i o n li s t e d is a se c o n d a r y ma x i m u m co n t a m i n a n t le v e l (S M C L ) ; SM C L s ar e es t a b l i s h e d by EP A in th e Na t i o n a l Se c o n d a r y Dr i n k i n g Wa t e r Regulations as found in 40 CFR §143.3 Ac c o r d i n g to th e Co n s t i t u e n t Lo o k ‐up we b p a g e on th e NC D E Q Di v i s i o n of Wa s t e Ma n a g e m e n t we b p a g e , th e r e is no SW S L or 2L St a n d a r d fo r ch o r i d e associated with CAS numbe r 16 8 8 7 ‐08 ‐6, wh i c h is th e CA S re p o r t e d by th e la b o r a t o r y fo r th e an a l y s e s co m p l e t e d ; th e r e f o r e , th e SW S L an d 2L St a n d a r d li s t e d ar e fo r th e ch l o r i d e with CAS number SW301 as specified NE in d i c a t e s no t es t a b l i s h e d ; NA in d i c a t e s no t an a l y z e d ; bl a n k ce l l s in d i c a t e th a t th e r e is no in f o r m a t i o n re l e v a n t to th e re s p e c t i v e ro w An a l y t i c a l re s u l t s ob t a i n e d fr o m El e c t r o n i c Da t a De l i v e r a b l e (E D D ) pr o v i d e d by Br y a n Mo e l l e r of Du k e En e r g y Ca r o l i n a s , LL C on Fe b r u a r y 23 , 20 1 7 Gr a y e d va l u e s in d i c a t e va l u e s th a t eq u a l or ar e gr e a t e r th a n th e SW S L Bo l d va l u e s in d i c a t e va l u e s th a t at t a i n or ex c e e d th e 15 A NC A C 2L St a n d a r d MD L is th e la b o r a t o r y me t h o d de t e c t i o n li m i t . Th e MD L va l u e s pr e s e n t e d ar e fo r sa m p l e s no t di l u t e d by th e la b o r a t o r y du r i n g an a l y s i s Qu a l i f i e r s in no n ‐it a l i c i z e d te x t ar e la b o r a t o r y da t a qu a l i f i e r s or "f l a g s " , "U " is us e d to id e n t i f y re s u l t s no t de t e c t e d at co n c e n t r a t i o n s wh i c h eq u a l th e laboratory's MDL, "J" is used to identify es t i m a t e d co n c e n t r a t i o n s wh i c h eq u a l or ar e gr e a t e r th a n th e MD L bu t ar e le s s th a n th e la b o r a t o r y ' s me t h o d re p o r t i n g li m i t (M R L ) , an d an it a l i c i z e d J'‐flag is a data qualifier, added by HDR SW S L is th e So l i d Wa s t e Se c t i o n Li m i t . NC D E Q de f i n e s th e SW S L as th e lo w e s t am o u n t of an a l y t e in a sa m p l e th a t ca n be qu a n t i t a t i v e l y de t e r m i n e d with suitable precision and accurac y ‐‐ ‐‐ ‐‐ ‐‐ µg / L in d i c a t e s mi c r o g r a m s pe r li t e r °C in d i c a t e s de g r e e s ce l s i u s SU in d i c a t e s st a n d a r d un i t s µԼ /c m in d i c a t e s mi c r o m h o s pe r ce n t i m e t e r SW S ID is th e So l i d Wa s t e Se c t i o n Id e n t i f i c a t i o n Nu m b e r ‐‐‐‐ ‐‐ ‐‐ ‐‐ 10 7 ‐‐ 11 . 9 0 ‐‐ ‐‐ 5. 8 ‐‐ Ja n u a r y 30 an d 31 , 20 1 7 ‐‐ ‐‐ 5. 7 80 10 . 9 4 ‐‐ Laboratory Certification Codes: Du k e En e r g y Ca r o l i n a s , LL C Duke Energy Carolinas Field #5193 Duke Energy Analytical Laboratory #248 CR S ‐4 F i e l d Bl a n k CR S ‐5 Ta b l e 5A ‐ Fi e l d an d An a l y t i c a l Re s u l t s th a t Eq u a l or Ex c e e d NC A C 2L Gr o u n d w a t e r Qu a l i t y St a n d a r d s Du k e En e r g y Ca r o l i n a s , LL C / B e l e w s Cr e e k St e a m St a t i o n Cr a i g Ro a d As h La n d f i l l Ph a s e 1 an d 2 ‐ Pe r m i t No . 85 0 4 Sa m p l e Da t e : Pa r a m e t e r S a m p l e ID R e s u l t U n i t s 15 A NC A C 2L St a n d a r d Hi s t o r i c a l Co n c e n t r a t i o n s C a u s e and Significance CR W ‐2 5 . 7 5 . 2 ‐ 6. 0 p H is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at CR W ‐2 CR W ‐3 5 . 6 5 . 2 ‐ 5. 9 p H is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at CR W ‐3 CR W ‐4 6 . 3 5 . 8 ‐ 6. 4 p H is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at CR W ‐4 CR W ‐5 5 . 8 5 . 6 ‐ 6. 1 p H is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at CR W ‐5 CR W ‐6 5 . 1 4 . 5 ‐ 5. 7 p H is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at CR W ‐6 CR W ‐8R 5 . 7 5 . 2 ‐ 5. 8 p H is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at CR W ‐8R CR W ‐9 5 . 8 5 . 6 ‐ 8. 5 p H is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at CR W ‐9 CR W ‐10 5 . 6 5 . 3 ‐ 6. 3 p H is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at CR W ‐10 CR W ‐11 6 . 3 5 . 8 ‐ 6. 3 p H is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at CR W ‐11 CR W ‐12 5 . 5 5 . 1 ‐ 5. 6 p H is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at CR W ‐12 CR W ‐13 6 . 0 5 . 7 ‐ 6. 0 p H is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at CR W ‐13 CR W ‐14 6 . 0 5 . 6 ‐ 6. 1 p H is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at CR W ‐14 CR W ‐15 5 . 8 5 . 3 ‐ 5. 7 p H is gr e a t e r th a n th e hi s t o r i c a l re a d i n g s at CR W ‐15 CR W ‐16 5 . 7 5 . 4 ‐ 5. 8 p H is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at CR W ‐16 CR W ‐17 5 . 8 5 . 1 ‐ 5. 4 p H is gr e a t e r th a n th e hi s t o r i c a l re a d i n g s at CR W ‐17 CR S ‐4 5 . 8 5 . 5 ‐ 6. 5 p H is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at CR S ‐4 CR S ‐5 5 . 7 5 . 5 ‐ 6. 8 p H is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at CR S ‐5 No t e s : 1.2.3.4.5. NT U in d i c a t e s Ne p h e l o m e t r i c Tu r b i d i t y Un i t s Hi s t o r i c a l co n c e n t r a t i o n s ba s e d on da t a in Du k e En e r g y Ca r o l i n a s , LL C (D u k e En e r g y ) an a l y t i c a l re s u l t s da t a b a s e An a l y t i c a l re s u l t s ob t a i n e d fr o m El e c t r o n i c Da t a De l i v e r a b l e (E D D ) pr o v i d e d by Br y a n Mo e l l e r of Du k e En e r g y Ca r o l i n a s , LL C on Fe b r u a r y 23, 2017 15 A NC A C 2L St a n d a r d re f e r s to Cl a s s GA St a n d a r d s as fo u n d in 15 A NC A C 02 L .0 2 0 2 Gr o u n d w a t e r Qu a l i t y St a n d a r d s , la s t am e n d e d on April 1, 2013 Ja n u a r y 30 an d 31 , 20 1 7 SU in d i c a t e s St a n d a r d Un i t s pH S U 6 . 5 ‐ 8. 5 Ta b l e 5B ‐ Fi e l d an d An a l y t i c a l Re s u l t s th a t Eq u a l or Ex c e e d NC A C 2L Gr o u n d w a t e r Qu a l i t y St a n d a r d s Du k e En e r g y Ca r o l i n a s , LL C / B e l e w s Cr e e k St e a m St a t i o n Cr a i g Ro a d As h La n d f i l l Ph a s e 1 an d 2 ‐ Pe r m i t No . 85 0 4 Sa m p l e Da t e : Pa r a m e t e r S a m p l e ID R e s u l t U n i t s 15 A NC A C 2L St a n d a r d Hi s t o r i c a l Co n c e n t r a t i o n s C a u s e and Significance CR W ‐2 1 , 1 1 0 5 1 9 ‐ 28 , 7 7 5 I r o n in CR W ‐2 is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at well; turbidity measured at 16.8 NTU CR W ‐3 3 , 1 7 0 2 4 4 ‐ 14 , 9 0 0 I r o n in CR W ‐3 is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at well; turbidity measured at 62.6 NTU CR W ‐4 7 2 0 7 2 . 7 ‐ 1, 7 7 8 I r o n in CR W ‐4 is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at well; turbidity measured at 11.8 NTU CR W ‐5 6 , 9 5 0 5 , 4 4 0 ‐ 18 , 2 6 0 I r o n in CR W ‐5 is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at well CR W ‐6 2 , 8 9 0 2 3 9 ‐ 12 , 5 8 5 I r o n in CR W ‐6 is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at well; turbidity measured at 34.5 NTU CR W ‐8R 6 5 1 4 4 6 ‐ 7, 0 7 0 I r o n in CR W ‐8R is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at well; turbidity measured at 17.5 NTU CR W ‐9 7 9 3 1 5 7 ‐ 31 , 6 0 0 I r o n in CR W ‐9 is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at well; turbidity measured at 15.6 NTU CR W ‐10 3 5 6 1 0 3 ‐ 11 , 4 0 7 I r o n in CR W ‐10 is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at well CR W ‐12 3 5 8 1 4 1 ‐ 47 , 0 0 0 I r o n in CR W ‐12 is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at well CR W ‐13 3 2 6 4 0 5 ‐ 8, 7 1 0 I r o n in CR W ‐13 is lo w e r th a n hi s t o r i c a l re a d i n g s at we l l CR W ‐16 3 6 9 7 6 . 4 ‐ 2, 5 6 0 I r o n in CR W ‐16 is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at well; turbidity measured at 10.7 NTU CR W ‐17 4 0 4 4 9 6 ‐ 35 , 4 2 3 I r o n in CR W ‐17 is lo w e r th a n hi s t o r i c a l re a d i n g s at we l l CR S ‐4 5 7 8 2 0 3 ‐ 7, 8 3 0 I r o n in CR S ‐4 is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at location CR S ‐5 5 , 8 7 0 2 , 6 8 0 ‐ 31 , 7 0 0 I r o n in CR S ‐5 is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at location; turbidity measrued at 26.5 NTU CR W ‐3 5 8 . 7 2 7 . 6 ‐ 51 6 M a n g a n e s e in CR W ‐3 is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at well; turbidity measured at 62.6 NTU CR W ‐5 9 8 . 3 8 2 . 1 ‐ 18 0 M a n g a n e s e in CR W ‐5 is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at well CR W ‐6 1 1 8 7 6 . 4 ‐ 68 1 M a n g a n e s e in CR W ‐6 is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at well; turbidity measured at 34.5 NTU CR S ‐5 2 6 4 1 7 7 ‐ 1, 5 9 3 M a n g a n e s e in CR S ‐5 is co n s i s t e n t wi t h hi s t o r i c a l re a d i n g s at location; turbidity measrued at 26.5 NTU No t e s : 1.2.3.4.5. Ja n u a r y 30 an d 31 , 20 1 7 Ir o n µ g / L 3 0 0 µg / L in d i c a t e s mi c r o g r a m s pe r li t e r NT U in d i c a t e s Ne p h e l o m e t r i c Tu r b i d i t y Un i t s 15 A NC A C 2L St a n d a r d re f e r s to Cl a s s GA St a n d a r d s as fo u n d in 15 A NC A C 02 L .0 2 0 2 Gr o u n d w a t e r Qu a l i t y St a n d a r d s , la s t am e n d e d on April 1, 2013 Hi s t o r i c a l co n c e n t r a t i o n s ba s e d on da t a in Du k e En e r g y Ca r o l i n a s , LL C (D u k e En e r g y ) an a l y t i c a l re s u l t s da t a b a s e An a l y t i c a l re s u l t s ob t a i n e d fr o m El e c t r o n i c Da t a De l i v e r a b l e (E D D ) pr o v i d e d by Br y a n Mo e l l e r of Du k e En e r g y Ca r o l i n a s , LL C on Fe b r u a r y 23, 2017 Ma n g a n e s e µ g / L 5 0 Table 6 ‐ Surface Water Field and Analytical Results Duke Energy Carolinas, LLC/Belews Creek Steam Station Craig Road Ash Landfill Phase 1 and 2 ‐ Permit No. 8504 Sample Date: Field Sampling Performed By: Parameter SWS ID Units Certification Code MDL SWSL 15A NCAC 2B Standard Federal MCL Field pH 320 SU 5193 ‐‐NE 6.0‐9.0 6.5‐8.5* Field Specific Conductivity 323 µԼ/cm 5193 ‐‐NE NE NE Temperature 325 °C 5193 ‐‐NE NE NE Arsenic 14 µg/L 248 0.114 J 0.158 J 0.124 J 0.078 10 10 10 Arsenic, dissolved 14 µg/L 248 0.078 U 0.078 U 0.078 U 0.078 10 150 NE Barium 15 µg/L 248 26.4 J'22.3 J'34.1 J'0.1 100 NE 2,000 Barium, dissolved 15 µg/L 248 25.2 J'24.1 J'31.3 J'0.1 100 NE NE Boron 428 µg/L 248 4.58 J 5.61 J 4.35 J 3.3 NE NE NE Boron, dissolved 428 µg/L 248 3.3 U 3.3 U 3.3 U 3.3 NE NE NE Cadmium 34 µg/L 248 0.101 U 0.101 U 0.101 U 0.101 1 NE 5 Cadmium, dissolved (h) 34 µg/L 248 0.101 U 0.101 U 0.101 U 0.101 1 0.15 NE Chloride 455 µg/L 248 8,370 8,370 6,570 22 NE 230,000 250,000* Chromium 51 µg/L 248 0.561 J 0.5 U 1.22 J 0.5 10 NE 100 Chromium, dissolved †51µg/L 248 0.761 J 0.809 J 0.5 U 0.5 10 11 NE Copper 54 µg/L 248 1 U 1 U 1.82 J 1 10 NE 1,000* Copper, dissolved (h) 54 µg/L 248 1 U 1 U 1 U 110 3 NE Fluoride 312 µg/L 248 50.6 J 50.7 J 61 J 17 2,000 1,800 2,000* Iron 340 µg/L 248 281 J'834 644 1.3 300 NE 300* Iron, dissolved 340 µg/L 248 83.7 J'714 10.5 J'1.3 300 NE NE Lead 131 µg/L 248 0.0899 J 0.065 U 0.306 J 0.065 10 NE 15 Lead, dissolved (h) 131 µg/L 248 0.065 U 0.065 U 0.065 U 0.065 10 0.54 NE Manganese 342 µg/L 248 33.7 J'92.3 364 0.2 50 NE 50* Manganese, dissolved 342 µg/L 248 31.9 J'103 325 0.2 50 NE NE Mercury 132 µg/L 248 0.0334 U 0.0334 U 0.0334 U 0.0334 0.2 0.012 2 Nickel 152 µg/L 248 0.5 U 0.5 U 2 J 0.5 50 NE NE Nickel, dissolved (h) 152 µg/L 248 0.5 U 0.5 U 1.08 J 0.5 50 16.000 NE Nitrate (as Nitrogen) 303 µg/L 248 135 J'60.9 J'419 J'5.4 10,000 NE 10,000 Selenium 183 µg/L 248 0.092 U 0.092 U 0.092 U 0.092 10 5 50 Silver 184 µg/L 248 0.051 U 0.051 U 0.051 U 0.051 10 NE 100* Silver, dissolved 184 µg/L 248 0.051 U 0.051 U 0.051 U 0.051 10 0.06 NE Sulfate 315 µg/L 248 8,950 J'15,600 J'5,660 J'18 250,000 NE 250,000* Total Dissolved Solids 311 µg/L 248 92,000 88,000 64,000 16,700 NE NE 500,000* Zinc 213 µg/L 248 2.6 U 2.6 U 3.35 J 2.6 10 NE 5,000* Zinc, dissolved (h) 213 µg/L 248 2.6 U 2.6 U 2.6 U 2.6 10 36 NE Notes: 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 14.94 98 SWS ID is the Solid Waste Section Identification Number 107 116 4.89 4.84 NS NS NS NS NS NS NS NS NS Analytical results obtained from Electronic Data Deliverable (EDD) provided by Bryan Moeller of Duke Energy Carolinas, LLC on February 23, 2017 µg/L indicates micrograms per liter Reference 15A NCAC 2B .0200 Classifications and Water Quality Standards Applicable to Surface Waters and Wetlands of N.C. Amended Effective: May 1, 2007 The perennial tributaries to Belews Lake are classified as Class C waters. Regulation 15A NCAC 02B .0211 provides water quality standards for Class C waters Standards for Class C waters assume the most stringent of Freshwater and Human Health standard 2B ‐ Surface Water and Wetland Standards," (including '07‐'14 Triennial Review standards pending EPA review) for Class WS‐IV waters 15A NCAC 2B Standard is from "North Carolina Administrative Code, Title 15A: Deparment of Environment and Natural Resources, Subchapter determined with suitable precision and accuracy SWSL is the Solid Waste Section Limit. NCDEQ defines the SWSL as the lowest amount of analyte in a sample that can be quantitatively µԼ/cm indicates micromhos per centimeter SU indicates standard units °C indicates degrees celsius MDL is the laboratory method detection limit. The MDL values presented are for samples not diluted by the laboratory during analysis (h) Standard is hardness dependent; standard is displayed assuming a hardness of ≤ 25 mg/L NS NS NS NS CRS‐3 NS NS NS NS NS CRS‐6 NS 5.9 CRS‐1 CRS‐2 6.5 6.5 Laboratory Certification Codes: Duke Energy Carolinas Field #5193 January 30 and 31, 2017 Duke Energy Carolinas, LLC Duke Energy Analytical Laboratory #248 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS No sample was collected from CRS‐3 due to lack of water † Standard listed is most stringent of Cr(III) and Cr(VI) Bold values indicate values that attain or exceed the 15A NCAC 2B Standard greater than the laboratory's MRL but are less than the SWSL laboratory's method reporting limit (MRL); an italicized J'‐flag is a data qualifier, added by HDR to indicate concentrations which equal or are Drinking Water Regulations Grayed values indicate values that equal or are greater than the SWSL * Concentration listed is a secondary maximum contaminant level (SMCL). SMCLs are established by EPA in the National Secondary MCL is the Federal Maximum Contaminant Level as found in 40 CFR, Subpart G, §141.62 NE indicates not established; NA indicates not analyzed; NS indicates no sample collected; blank cells indicate that there is no information relevant According to the Constituent Look‐up webpage on the NCDEQ Division of Waste Management webpage, there is no SWSL or 2L Standard for choride associated with CAS number 16887‐08‐6, which is the CAS reported by the laboratory for the analyses completed; therefore, the SWSL and 2L Standard listed are for the chloride with CAS number SW301 as specified on the Constituent Look‐up webpage (last updated June 13, 2011) equal the laboratory's MDL; "J" is used to identify estimated concentrations which equal or are greater than the MDL but are less than the to the respective row Qualifiers in non‐italicized text are laboratory data qualifiers or "flags"; "U" is used to identify results not detected at concentrations which Ta b l e 7 ‐ Fi e l d an d An a l y t i c a l Re s u l t s th a t Eq u a l or Ex c e e d NC A C 2B Su r f a c e Wa t e r Qu a l i t y St a n d a r d s Du k e En e r g y Ca r o l i n a s , LL C / B e l e w s Cr e e k St e a m St a t i o n Cr a i g Ro a d As h La n d f i l l Ph a s e 1 an d 2 ‐ Pe r m i t No . 85 0 4 Sa m p l e Da t e : Pa r a m e t e r S a m p l e ID R e s u l t U n i t s 15 A NC A C 2L St a n d a r d Hi s t o r i c a l Co n c e n t r a t i o n s C a u s e and Significance pH C R S ‐6 5 . 9 S U 6 . 0 ‐ 9. 0 6 . 3 ‐ 7. 0 p H is le s s th a n th e hi s t o r i c a l re a d i n g s at CR S ‐6 No t e s : 1.2.3.4.5.6. An a l y t i c a l re s u l t s ob t a i n e d fr o m El e c t r o n i c Da t a De l i v e r a b l e (E D D ) pr o v i d e d by Br y a n Mo e l l e r of Du k e En e r g y Ca r o l i n a s , LL C on Fe b r u a r y 23, 2017 Hi s t o r i c a l co n c e n t r a t i o n s ba s e d on da t a in Du k e En e r g y Ca r o l i n a s , LL C (D u k e En e r g y ) an a l y t i c a l re s u l t s da t a b a s e Ja n u a r y 30 an d 31 , 20 1 7 SU in d i c a t e s St a n d a r d Un i t s 15 A NC A C 2B St a n d a r d is fr o m "N o r t h Ca r o l i n a Ad m i n i s t r a t i v e Co d e , Ti t l e 15 A : De p a r m e n t of En v i r o n m e n t an d Na t u r a l Re s o u r c e s , Subchapter 2B ‐ Su r f a c e Wa t e r an d We t l a n d St a n d a r d s , " (i n c l u d i n g '0 7 ‐'1 4 Tr i e n n i a l Re v i e w st a n d a r d s pe n d i n g EP A re v i e w ) fo r Cl a s s WS ‐IV wa t e r s St a n d a r d s fo r Cl a s s C wa t e r s as s u m e th e mo s t st r i n g e n t of Fr e s h w a t e r an d Hu m a n He a l t h st a n d a r d Th e pe r e n n i a l tr i b u t a r i e s to Be l e w s La k e ar e cl a s s i f i e d as Cl a s s C wa t e r s . Re g u l a t i o n 15 A NC A C 02 B .0 2 1 1 pr o v i d e s wa t e r qu a l i t y st a n d a r d s for Class C waters Re f e r e n c e 15 A NC A C 2B .0 2 0 0 Cl a s s i f i c a t i o n s an d Wa t e r Qu a l i t y St a n d a r d s Ap p l i c a b l e to Su r f a c e Wa t e r s an d We t l a n d s of N. C . Am e n d e d Effective: May 1, 2007 Ta b l e 8 ‐ Le a c h a t e Fi e l d an d An a l y t i c a l Re s u l t s Du k e En e r g y Ca r o l i n a s , LL C / B e l e w s Cr e e k St e a m St a t i o n Cr a i g Ro a d As h La n d f i l l Ph a s e 1 an d 2 ‐ Pe r m i t No . 85 0 4 Sa m p l e Da t e : Fi e l d Sa m p l i n g Pe r f o r m e d By : Pa r a m e t e r S W S ID U n i t s Ce r t i f i c a t i o n Co d e MDL S W S L Fi e l d pH 3 2 0 S U 5 1 9 3 ‐‐ ‐ ‐ Fi e l d Sp e c i f i c Co n d u c t i v i t y 3 2 3 µ Լ /c m 5 1 9 3 ‐‐ ‐ ‐ Te m p e r a t u r e 3 2 5 ° C 5 1 9 3 ‐‐ ‐ ‐ Ar s e n i c 1 4 µg / L 2 4 8 2 9 . 4 4 0 . 5 0.078 1 0 Ba r i u m 1 5 µg / L 2 4 8 2 9 . 3 J' 25 J' 0.1 1 0 0 Bo r o n 4 2 8 µg / L 2 4 8 3 8 , 1 0 0 7 3 , 1 0 0 3.3 N E Ca d m i u m 3 4 µg / L 2 4 8 3 . 7 9 7 . 2 5 0.101 1 Ch l o r i d e 4 5 5 µg / L 2 4 8 4 2 9 , 0 0 0 3 1 9 , 0 0 0 22 N E Ch r o m i u m 5 1 µg / L 2 4 8 0 . 5 U 0 . 5 U 0.5 1 0 Co p p e r 5 4 µg / L 2 4 8 1 U 6 . 2 9 J' 110 Fl u o r i d e 3 1 2 µg / L 2 4 8 1 , 6 2 0 J 2 , 9 4 0 J 17 2 , 0 0 0 Ir o n 3 4 0 µg / L 2 4 8 1 4 . 5 J' 42 J' 1.3 3 0 0 Le a d 1 3 1 µg / L 2 4 8 5 . 7 1 J' 11 . 1 0.065 1 0 Ma n g a n e s e 3 4 2 µg / L 2 4 8 1 9 , 0 0 0 1 9 , 2 0 0 0.2 5 0 Me r c u r y 1 3 2 µg / L 2 4 8 0 . 0 3 3 4 U 0 . 0 3 3 4 U 0.0334 0 . 2 Ni c k e l 1 5 2 µg / L 2 4 8 1 0 6 2 4 0 0.5 5 0 Ni t r a t e (a s Ni t r o g e n ) 3 0 3 µg / L 2 4 8 2 6 , 7 0 0 3 7 , 5 0 0 5.4 1 0 , 0 0 0 Se l e n i u m 18 3 µg / L 2 4 8 1 0 4 1 9 1 0.092 1 0 Si l v e r 1 8 4 µg / L 2 4 8 0 . 0 5 1 U 0 . 0 5 1 U 0.051 1 0 Su l f a t e 3 1 5 µg / L 2 4 8 2 , 2 1 0 , 0 0 0 4 , 2 1 0 , 0 0 0 18 2 5 0 , 0 0 0 To t a l Di s s o l v e d So l i d s 3 1 1 µg / L 2 4 8 3 , 1 0 0 , 0 0 0 3 , 8 2 0 , 0 0 0 16,700 N E Zi n c 2 1 3 µg / L 2 4 8 2 4 2 5 5 5 2.6 1 0 No t e s : 1.2.3.4.5.6.7.8.9. 10 . 11 . 14 . 15 . Gr a y e d va l u e s in d i c a t e va l u e s th a t eq u a l or ar e gr e a t e r th a n th e SW S L MD L is th e la b o r a t o r y me t h o d de t e c t i o n li m i t as s o c i a t e d wi t h CA S nu m b e r 16 8 8 7 ‐08 ‐6, wh i c h is th e CA S re p o r t e d by th e la b o r a t o r y fo r th e an a l y s e s co m p l e t e d ; th e r e f o r e , th e SWSL µg / L in d i c a t e s mi c r o g r a m s pe r li t e r NE in d i c a t e s no t es t a b l i s h e d ; NA in d i c a t e s no t an a l y z e d ; NS in d i c a t e s no sa m p l e co l l e c t d ; bl a n k ce l l s in d i c a t e th a t th e r e is no in f o r m a t i o n re l e v a n t to th e re s p e c t i v e ro w No Sa m p l e wa s co l l e c t e d fr o m CW B ‐3 as th e r e wa s in s u f f i c i e n t wa t e r An a l y t i c a l re s u l t s ob t a i n e d fr o m El e c t r o n i c Da t a De l i v e r a b l e (E D D ) pr o v i d e d by Br y a n Mo e l l e r of Du k e En e r g y Ca r o l i n a s , LL C on February 23, 2017 Qu a l i f i e r s in no n ‐it a l i c i z e d te x t ar e la b o r a t o r y da t a qu a l i f i e r s or "f l a g s " , "U " is us e d to id e n t i f y re s u l t s no t de t e c t e d at co n c e n t r a t i o n s HD R to in d i c a t e co n c e n t r a t i o n s wh i c h eq u a l or ar e gr e a t e r th a n th e la b o r a t o r y ' s MR L bu t ar e le s s th a n th e SW S L wh i c h eq u a l th e la b o r a t o r y ' s me t h o d de t e c t i o n li m i t (M D L ) , "J " is us e d to id e n t i f y es t i m a t e d co n c e n t r a t i o n s wh i c h eq u a l or ar e gr e a t e r th a n th e MD L bu t ar e le s s th a n th e la b o r a t o r y ' s me t h o d re p o r t i n g li m i t (M R L ) , an it a l i c i z e d J' ‐fl a g is a da t a qu a l i f i e r , ad d e d by NS SW S L is th e So l i d Wa s t e Se c t i o n Li m i t ; NC D E Q de f i n e s th e SW S L as th e lo w e s t am o u n t of an a l y t e in a sa m p l e th a t ca n be qu a n t i t a t i v e l y NS NS NS NS °C in d i c a t e s de g r e e s ce l s i u s NSNSNSNS SU in d i c a t e s st a n d a r d un i t s li s t e d is fo r th e ch l o r i d e wi t h CA S nu m b e r SW 3 0 1 as sp e c i f i e d on th e Co n s t i t u e n t Lo o k ‐up we b p a g e µԼ /c m in d i c a t e s mi c r o m h o s pe r ce n t i m e t e r SW S ID is th e So l i d Wa s t e Se c t i o n Id e n t i f i c a t i o n Nu m b e r Ac c o r d i n g to th e Co n s t i t u e n t Lo o k ‐up we b p a g e on th e NC D E Q Di v i s i o n of Wa s t e Ma n a g e m e n t we b p a g e , th e r e is no SW S L fo r ch o r i d e de t e r m i n e d wi t h su i t a b l e pr e c i s i o n an d ac c u r a c y NS NSLa b o r a t o r y Certification Codes: Du k e En e r g y Carolinas Field #5193 NS NS NS NS NS CW B ‐3 NS NS NS Ja n u a r y 30 an d 31 , 20 1 7 Du k e En e r g y Ca r o l i n a s , LL C Du k e En e r g y An a l y t i c a l Laboratory #248 NS NSNS CW B ‐1 C W B ‐2 4. 7 3 . 8 4, 3 4 4 6 , 3 8 9 14 . 4 0 1 6 . 0 5 A Appendix A Field Sampling Forms STUDY: ANALYZER SERIAL #: DATE: TIME: DATE: TIME: Calibation Instrument Standard Instrument Standard Standard Value Value Value Value SS 0.0 ŷŷŹ 0.0 0.0 ŷŷŹ 0.0 SS 220.4 ŷŷŹ 227 227.0 ŷŷŹ 227 SS 73.4 ŷŷŹ 75 73.1 ŷŷŹ 75 SS ŷŷŹ 1410 ŷŷŹ 1410 SS B (7.00)7.08 ŷŷŹ 7.02 7.03 ŷŷŹ 7.02 B (4.00)4.03 ŷŷŹ 4.00 4.03 ŷŷŹ 4.00 B (10.00)10.00 ŷŷŹ 10.06 9.99 ŷŷŹ 10.06 20.26 20.31 pH Check B (7.00)ŷŷŹ 7.13 Time:0.00 440 ŷŷŹ 440 438 ŷŷŹ 440 N/A ŷŷŹ N/A N/A ŷŷŹ N/A Zobell's 20.22 20.39 TEMP(CO) BP (mmHg) COND 100 % mg/L 8.81 ŷŷŹ 8.92 8.95 ŷŷŹ 8.95 After Cal 8.92 100.00 9.01 100.63 LCS 8.97 100.56 8.93 99.74 LCSD 8.96 -0.11 8.94 0.11 SS 54.6 ŷŷŹ 53.4 54.9 ŷŷŹ 53.4 NIST N/A ŷŷŹ N/A N/A ŷŷŹ N/A KEY: FIELD SAMPLING CALIBRATION FORM DATE (s): January 30 - 31, 2017 SURFACE UNIT READER: BELEWS CREEK STEAM STATION - CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW WEATHER CONDITIONS:Clouds then clear, breezy, 32 - 45 deg F LDC COLLECTORS: LDC, PSP SURFACE UNIT SERIAL #: 0730 ANALYZER MODEL#: HL4 400692 3210.6 VALIDATED BY: Calibration Date / Time 30-Jan-17 400 31-Jan-17 340 HYDROLAB PROCEDURE #: CALIBRATION BP (mmHg)738.46 CALIBRATION BP (mmHg)742.17 Parameter Calibration Results Calibration Results Specifc conductance checkpoint (used if sampled well is outside of initial calibration range). SPEC. COND. CHECK (uS/cm) SPEC. COND. (uS/cm) INSTRUMENT ZEROED INSTRUMENT ZEROED CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED Buffer Temp. ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED pH (units) CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED Buffer Temp. Buffer Temp. 84.70 84.90 ORP Temp. ORP Temp. DO (mg/L) 19.47 19.54 738.46 CALIBRATION ACCEPTED CALIBRATION ACCEPTED After Cal % SAT After Cal % SAT CALIBRATION PASS CALIBRATION PASS 742.17 CALIBRATION PASS CALIBRATION PASS TURB (ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED Temp Cert Device # TEMP (deg C)Adjustment Not Available Adjustment Not Available Tested - OK Replaced ref Electrode KCL See Notes Replaced Ref. Electrode Tip INSTRUMENT MAINTENANCE DATE / TIME Conductance Subsystem pH Subsystem Cleaned Electrodes Cleaned Electrodes Tested - OK See Notes Tested - OK See Notes Dissolved Oxygen Subsystem Replaced Teflon Membrane Cleaned Electrode Tested - OK See Notes Oxidation Reduction Subsystem Temperature Subsystem Cleaned Electrode Cleaned Electrode Replaced DO electrolyte See Notes Field Barometric Pressure Beginning BP 740.98 (mmHg)Ending BP 740.98 N/A = Not Applicable W = WinklerBP = Barometric Pressure AW = Average Winkler NOTES: (mmHg) B = Buffer LCS = Lab Control Standard ŷŷŹ $GMXVWHG7R SS = Standard solution LCSD = Lab Control Standard Duplicate ŷŷŹ 1RW$GMXVWHG7R de ORP TUR (ntu STUDY: ANALYZER SERIAL #: DATE: TIME: DATE: TIME: Calibation Instrument Standard Instrument Standard Standard Value Value Value Value SS 0.0 ŷŷŹ 0.0 0.0 ŷŷŹ 0.0 SS 227.0 ŷŷŹ 227 226.6 ŷŷŹ 227 SS 73.1 ŷŷŹ 75 73.2 ŷŷŹ 75 SS ŷŷŹ 1410 ŷŷŹ 1410 SS B (7.00)7.03 ŷŷŹ 7.02 7.01 ŷŷŹ 7.02 B (4.00)4.03 ŷŷŹ 4.00 3.94 ŷŷŹ 4.00 B (10.00)9.99 ŷŷŹ 10.06 10.07 ŷŷŹ 10.04 20.31 20.54 pH Check B (7.00)ŷŷŹ 7.13 Time:0.00 438 ŷŷŹ 440 441 ŷŷŹ 440 N/A ŷŷŹ N/A N/A ŷŷŹ N/A Zobell's 20.39 20.36 TEMP(CO) BP (mmHg) COND 100 % mg/L 8.95 ŷŷŹ 8.95 8.82 ŷŷŹ 8.86 After Cal 9.01 100.63 8.84 99.80 LCS 8.93 99.74 8.85 99.91 LCSD 8.94 0.11 8.88 0.34 SS 54.9 ŷŷŹ 53.4 54.6 ŷŷŹ 53.4 NIST N/A ŷŷŹ N/A N/A ŷŷŹ N/A KEY: FIELD SAMPLING CALIBRATION FORM DATE (s): January 30 - 31, 2017 SURFACE UNIT READER: BELEWS CREEK STEAM STATION - CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW WEATHER CONDITIONS:Clear, slight breeze, 25 to 45 deg F LDC COLLECTORS: LDC, PSP SURFACE UNIT SERIAL #: 0722 ANALYZER MODEL#: HL4 400692 3210.6 VALIDATED BY: Calibration Date / Time 31-Jan-17 340 1-Feb-17 605 HYDROLAB PROCEDURE #: CALIBRATION BP (mmHg)742.17 CALIBRATION BP (mmHg)741.92 Parameter Calibration Results Calibration Results Specifc conductance checkpoint (used if sampled well is outside of initial calibration range). SPEC. COND. CHECK (uS/cm) SPEC. COND. (uS/cm) INSTRUMENT ZEROED INSTRUMENT ZEROED CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED Buffer Temp. ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED pH (units) CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED Buffer Temp. Buffer Temp. 84.90 86.30 ORP Temp. ORP Temp. DO (mg/L) 19.54 20.06 742.17 CALIBRATION ACCEPTED CALIBRATION ACCEPTED After Cal % SAT After Cal % SAT CALIBRATION PASS CALIBRATION PASS 741.92 CALIBRATION PASS CALIBRATION PASS TURB (ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED Temp Cert Device # TEMP (deg C)Adjustment Not Available Adjustment Not Available Tested - OK Replaced ref Electrode KCL See Notes Replaced Ref. Electrode Tip INSTRUMENT MAINTENANCE DATE / TIME Conductance Subsystem pH Subsystem Cleaned Electrodes Cleaned Electrodes Tested - OK See Notes Tested - OK See Notes Dissolved Oxygen Subsystem Replaced Teflon Membrane Cleaned Electrode Tested - OK See Notes Oxidation Reduction Subsystem Temperature Subsystem Cleaned Electrode Cleaned Electrode Replaced DO electrolyte See Notes Field Barometric Pressure Beginning BP 741.47 (mmHg)Ending BP 739.99 N/A = Not Applicable W = WinklerBP = Barometric Pressure AW = Average Winkler NOTES: (mmHg) B = Buffer LCS = Lab Control Standard ŷŷŹ $GMXVWHG7R SS = Standard solution LCSD = Lab Control Standard Duplicate ŷŷŹ 1RW$GMXVWHG7R de ORP TUR (ntu STUDY: ANALYZER SERIAL #: DATE: TIME: DATE: TIME: Calibation Instrument Standard Instrument Standard Standard Value Value Value Value SS 0.0 ŷŷŹ 0.0 0.0 ŷŷŹ 0.0 SS 220.6 ŷŷŹ 227 224.1 ŷŷŹ 227 SS 75.4 ŷŷŹ 75 74.9 ŷŷŹ 75 SS ŷŷŹ 1410 ŷŷŹ 1410 SS B (7.00)6.98 ŷŷŹ 7.02 6.99 ŷŷŹ 7.02 B (4.00)3.97 ŷŷŹ 4.00 3.98 ŷŷŹ 4.00 B (10.00)10.03 ŷŷŹ 10.06 10.01 ŷŷŹ 10.06 20.36 19.81 pH Check B (7.00)ŷŷŹ 7.13 Time:0.00 443 ŷŷŹ 440 438 ŷŷŹ 441 N/A ŷŷŹ N/A N/A ŷŷŹ N/A Zobell's 20.33 20.17 TEMP(CO) BP (mmHg) COND 100 % mg/L 8.85 ŷŷŹ 8.93 8.91 ŷŷŹ 8.97 After Cal 8.94 100.10 8.98 100.13 LCS 8.98 100.55 8.98 100.13 LCSD 8.96 -0.22 9.00 0.22 SS 52.7 ŷŷŹ 53.0 54.0 ŷŷŹ 53.0 NIST N/A ŷŷŹ N/A N/A ŷŷŹ N/A KEY: CALIBRATION ACCEPTED CALIBRATION ACCEPTED Beginning BP DATE (s): January 30 - 31, 2017 SURFACE UNIT READER: PSP SPEC. COND. (uS/cm) INSTRUMENT ZEROED INSTRUMENT ZEROED COLLECTORS: LDC, PSP SURFACE UNIT SERIAL #: 0662 ANALYZER MODEL#: HL4 400440 HYDROLAB PROCEDURE #:3210.6 VALIDATED BY: Parameter OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW Clouds then clear, breezy, 32 - 45 deg F CALIBRATION BP (mmHg)738.46 CALIBRATION BP (mmHg)742.17 Calibration Date / Time 30-Jan-17 340 31-Jan-17 500 Calibration Results Calibration Results CALIBRATION ACCEPTED CALIBRATION ACCEPTED Specifc conductance checkpoint (used if sampled well is outside of initial calibration range). Buffer Temp. SPEC. COND. CHECK (uS/cm) CALIBRATION ACCEPTED 740.98 SS = Standard solution TURB (ntu) pH (units) CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED (mmHg) ORP CALIBRATION ACCEPTED Field Barometric Pressure CALIBRATION ACCEPTED Buffer Temp. 84.20 After Cal % SAT After Cal % SAT CALIBRATION PASS Replaced DO electrolyte See Notes Buffer Temp. See Notes Dissolved Oxygen Subsystem Replaced Teflon Membrane Cleaned Electrode Tested - OK See Notes Oxidation Reduction Subsystem Temperature Subsystem Cleaned Electrode Cleaned Electrode Tested - OK See Notes ORP Temp. ORP Temp. 86.60 CALIBRATION ACCEPTED CALIBRATION ACCEPTED Cleaned Electrodes INSTRUMENT MAINTENANCE DATE / TIME DO (mg/L) 19.41 19.46 738.46 742.17 CALIBRATION PASS CALIBRATION PASS CALIBRATION PASS CALIBRATION ACCEPTED CALIBRATION ACCEPTED Replaced ref Electrode KCL LCSD = Lab Control Standard Duplicate W = Winkler Replaced Ref. Electrode Tip pH Subsystem Cleaned Electrodes Conductance Subsystem Temp Cert Device # TEMP (deg C)Adjustment Not Available Adjustment Not Available Tested - OK See Notes Tested - OK (mmHg) B = Buffer ŷŷŹ $GMXVWHG7R N/A = Not Applicable LCS = Lab Control Standard Ending BP 740.98 ŷŷŹ 1RW$GMXVWHG7R BP = Barometric Pressure NOTES: AW = Average Winkler BELEWS CREEK STEAM STATION - CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD SAMPLING CALIBRATION FORM WEATHER CONDITIONS: de ORP TUR (ntu STUDY: ANALYZER SERIAL #: DATE: TIME: DATE: TIME: Calibation Instrument Standard Instrument Standard Standard Value Value Value Value SS 0.0 ŷŷŹ 0.0 0.0 ŷŷŹ 0.0 SS 224.1 ŷŷŹ 227 229.8 ŷŷŹ 227 SS 74.9 ŷŷŹ 75 75.2 ŷŷŹ 75 SS ŷŷŹ 1410 ŷŷŹ 1410 SS B (7.00)6.99 ŷŷŹ 7.02 6.95 ŷŷŹ 7.02 B (4.00)3.98 ŷŷŹ 4.00 3.95 ŷŷŹ 4.00 B (10.00)10.01 ŷŷŹ 10.06 10.01 ŷŷŹ 10.04 19.81 20.68 pH Check B (7.00)ŷŷŹ 7.13 Time:0.00 438 ŷŷŹ 441 444 ŷŷŹ 440 N/A ŷŷŹ N/A N/A ŷŷŹ N/A Zobell's 20.17 20.44 TEMP(CO) BP (mmHg) COND 100 % mg/L 8.91 ŷŷŹ 8.97 8.87 ŷŷŹ 8.86 After Cal 8.98 100.13 8.89 100.32 LCS 8.98 100.13 8.92 100.66 LCSD 9.00 0.22 8.94 0.22 SS 54.0 ŷŷŹ 53.0 52.4 ŷŷŹ 53.0 NIST N/A ŷŷŹ N/A N/A ŷŷŹ N/A KEY: FIELD SAMPLING CALIBRATION FORM DATE (s): January 30 - 31, 2017 SURFACE UNIT READER: BELEWS CREEK STEAM STATION - CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW WEATHER CONDITIONS:Clear, slight breeze, 25 to 45 deg F PSP COLLECTORS: LDC, PSP SURFACE UNIT SERIAL #: 0970 ANALYZER MODEL#: HL4 400440 3210.6 VALIDATED BY: Calibration Date / Time 31-Jan-17 500 1-Feb-17 540 HYDROLAB PROCEDURE #: CALIBRATION BP (mmHg)742.17 CALIBRATION BP (mmHg)741.92 Parameter Calibration Results Calibration Results Specifc conductance checkpoint (used if sampled well is outside of initial calibration range). SPEC. COND. CHECK (uS/cm) SPEC. COND. (uS/cm) INSTRUMENT ZEROED INSTRUMENT ZEROED CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED Buffer Temp. ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED pH (units) CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED CALIBRATION ACCEPTED Buffer Temp. Buffer Temp. 86.60 87.50 ORP Temp. ORP Temp. DO (mg/L) 19.46 20.04 742.17 CALIBRATION ACCEPTED CALIBRATION ACCEPTED After Cal % SAT After Cal % SAT CALIBRATION PASS CALIBRATION PASS 741.92 CALIBRATION PASS CALIBRATION PASS TURB (ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED Temp Cert Device # TEMP (deg C)Adjustment Not Available Adjustment Not Available Tested - OK Replaced ref Electrode KCL See Notes Replaced Ref. Electrode Tip INSTRUMENT MAINTENANCE DATE / TIME Conductance Subsystem pH Subsystem Cleaned Electrodes Cleaned Electrodes Tested - OK See Notes Tested - OK See Notes Dissolved Oxygen Subsystem Replaced Teflon Membrane Cleaned Electrode Tested - OK See Notes Oxidation Reduction Subsystem Temperature Subsystem Cleaned Electrode Cleaned Electrode Replaced DO electrolyte See Notes Field Barometric Pressure Beginning BP 741.47 (mmHg)Ending BP 739.99 N/A = Not Applicable W = WinklerBP = Barometric Pressure AW = Average Winkler NOTES: (mmHg) B = Buffer LCS = Lab Control Standard ŷŷŹ $GMXVWHG7R SS = Standard solution LCSD = Lab Control Standard Duplicate ŷŷŹ 1RW$GMXVWHG7R de ORP TUR (ntu N/A 28.24 38.24 15 (psi)6 (sec) (sec) (gal) @ QC By: SAMPLING PROCEDURE NO. 3175.4 CRW-2 NO WELL CONDITION ADDITIONAL WELL CONDITION NOTES SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED PROTECTIVE CASING WELL PAD WELL CASING WELL TAG ACCESS TO WELLS WELL CAPS FLUSH MOUNT WELLS < 2.0Sample preservation verified to pH (units) CHLORINE (mg/l) INITIAL PURGE VOLUME 1.75 (gal)SAMPLE COLLECTED BY DATE TIME TOTAL PURGE VOLUME 4.15 (gal)PSP 1/30/2017 1055 N/A N/A 10:50 26.03 200 14.40 40 5.71 16.8 568 7.49 N/A 10:45 26.03 200 14.42 40 5.71 17.4 567 7.47 N/A 10:40 26.03 200 14.39 40 5.71 20.2 566 7.47 N/A 10:35 26.03 200 14.32 39 5.70 26.3 565 7.47 N/A 10:30 26.03 200 14.42 39 5.69 30.0 564 7.39 N/A 10:25 26.03 200 14.35 39 5.69 52.5 562 7.43 N/A 10:20 26.03 200 14.57 37 5.69 52.8 561 7.34 N/A 10:15 26.03 200 14.47 37 5.68 50.3 560 7.29 N/A 10:10 26.03 200 14.46 36 5.67 43.3 559 7.25 N/A 10:05 26.03 200 14.58 35 5.67 38.5 557 7.36 PURGE METHOD Low Flow WELL TYPE WELL INFORMATION MONITORING WELL SEE NOTE BELOW COND. OXYGEN 14.11 WATER ELEVATION (ft msl) 737.33 WELL VOLUME ODOR STRENGTH None WELL/SAMPLING INFORMATION (gal) NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC) 38.24 GS ELEV (ft msl) 0.00 PUMP INTAKE DEPTH (ft TOC) 37.00 28651 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD ELEV REF RECHARGE DISCHARGE 6 SITE NAME GROUNDWATER MONITORING DATA SHEET FOR LOW FLOW SAMPLING PROJECT NAME SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME DUKE ENERGY MONITORING WELL INFORMATION WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 761.46 MIDDLE OF WETTED SCREEN (ft toc)33.24 SCREEN LENGTH (ft) 10 WELL USE FOSSIL LANDFILL NPDES PUMP CONTROLLER SETTINGS PRESSURE 2.30 DETECTED ODOR None APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 24.13 WATER COLUMN (ft) ORP DISSOLVED WELL VOL STICK UP WELL (recalculates on current water level)(hh:mm) (ft) (ml/min) (deg C) (umho/cm) (mg/L) LEVEL COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY (SU) (NTU)(mV-NHE) Good Condition Casing in good condition Well Impacted By Silting: DRAW-DOWN 1.90 (ft) Lock in good conditionWELL LOCK CONDITION Good Condition LDC, PSP SITE ID 85-04PERMIT #BELEWS CREEK STEAM STATION FIELD CREWCRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM SAMPLING NOTES LIFT WELL CAP ONE FOOT UP FROM PVC WELL CASING AND PUMP AT 480 mL/min. Access cleared around wellACCESS AROUND WELL Well cap in good conditon Well tag in good condition Access cleared into well Well found lockedWELL SECURITY 30 31 T SP DISS WETU GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A 8.84 18.84 15 (psi)7 (sec) (sec) (gal) 1.69 (gal) @ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY GROUNDWATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR CONVENTIONAL SAMPLING WELL DEPTH (ft TOC) 18.84 GS ELEV (ft msl) 0.00 PUMP INTAKE DEPTH (ft TOC) 18.50 CRW-3 MONITORING WELL INFORMATION WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 746.39 MIDDLE OF WETTED SCREEN (ft toc)13.84 SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME EQUIPMENT INFORMATION SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional PUMP CONTROLLER SETTINGS SEE NOTE BELOW PRESSURE RECHARGE DISCHARGE 3 LEVEL METER SERIAL# 28651 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD DETECTED ODOR None ODOR STRENGTH None APPEARANCE Turbid WATER ELEVATION (ft msl) 737.91 WELL VOLUME 1.69 SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 8.48 WATER COLUMN (ft) 10.36 (gal) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED (mV -NHE)(mg/L) 2.75 NO 14.21 60 5.76 >1000 550 (ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU) WELL VOL VOLUME EVACUATION COND. OXYGEN (recalculates on current water level) 5.73 1.75 NO 14.43 62 5.74 418.0 520 3.92 1.75 NO 14.02 60 5.71 395.0 501 5.26 4.00 NO 14.02 62 5.60 62.6 531 4.75 1.75 NO 14.18 62 5.66 549.0 533 N/A N/A N/A Sampled:N/A N/A N/A N/A 6.22 If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water Level To The Right Before Sampling to Determine Recharge. DATE: TIME: WATER LEVEL: WELL VOL: Evacuated:N/A 1245 N/A TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 12.00 PSP 1/30/2017 Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Casing in good condition FLUSH MOUNT WELLS WELL CAPS Well cap in good conditon WELL CASING Good Condition ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Good Condition Well Impacted By Silting:NO SAMPLING NOTES LIFT WELL CAP ONE FOOT UP FROM PVC WELL CASING AND PUMP AT 528 mL/min. WELL SECURITY Well found locked WELL LOCK CONDITION Lock in good condition WELL TAG Well tag in good condition ACCESS AROUND WELL Access cleared around well 30 31 T SP DISS WTU GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A 20.19 30.19 18 (psi)9 (sec) (sec) (gal) 1.31 (gal) @ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY GROUNDWATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR CONVENTIONAL SAMPLING WELL DEPTH (ft TOC) 30.19 GS ELEV (ft msl) 0.00 PUMP INTAKE DEPTH (ft TOC) 29.00 CRW-4 MONITORING WELL INFORMATION WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 773.53 MIDDLE OF WETTED SCREEN (ft toc)26.19 SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME EQUIPMENT INFORMATION SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 6 LEVEL METER SERIAL# 28651 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD DETECTED ODOR None ODOR STRENGTH None APPEARANCE Normal WATER ELEVATION (ft msl) 751.35 WELL VOLUME 1.31 SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 22.18 WATER COLUMN (ft) 8.01 (gal) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED (mV -NHE)(mg/L) 1.50 NO 15.90 65 6.27 44.9 543 (ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU) WELL VOL VOLUME EVACUATION COND. OXYGEN (recalculates on current water level) 8.34 1.50 NO 15.88 64 6.27 15.9 550 8.43 1.50 NO 15.89 65 6.26 22.3 548 8.31 1.50 NO 15.90 64 6.25 11.8 556 8.31 1.50 NO 15.88 64 6.26 12.5 554 N/A N/A N/A Sampled:N/A N/A N/A N/A 8.34 If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water Level To The Right Before Sampling to Determine Recharge. DATE: TIME: WATER LEVEL: WELL VOL: Evacuated:N/A 1330 N/A TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 7.50 PSP 1/30/2017 Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Casing in good condition FLUSH MOUNT WELLS WELL CAPS Well cap in good conditon WELL CASING Good Condition ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Good Condition Well Impacted By Silting:NO SAMPLING NOTES WELL SECURITY Well found locked WELL LOCK CONDITION Lock in good condition WELL TAG Well tag in good condition ACCESS AROUND WELL Access cleared around well 30 31 T SP DISS WTU GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A 13.16 23.16 18 (psi)10 (sec) (sec) (gal) 1.00 (gal) @ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY GROUNDWATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR CONVENTIONAL SAMPLING WELL DEPTH (ft TOC) 23.16 GS ELEV (ft msl) 0.00 PUMP INTAKE DEPTH (ft TOC) 22.50 CRW-5 MONITORING WELL INFORMATION WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 764.74 MIDDLE OF WETTED SCREEN (ft toc)20.11 SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME EQUIPMENT INFORMATION SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 10 LEVEL METER SERIAL# 28651 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD DETECTED ODOR None ODOR STRENGTH None APPEARANCE Normal WATER ELEVATION (ft msl) 747.69 WELL VOLUME 1.00 SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 17.05 WATER COLUMN (ft) 6.11 (gal) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED (mV -NHE)(mg/L) 1.00 NO 15.39 93 5.92 49.8 264 (ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU) WELL VOL VOLUME EVACUATION COND. OXYGEN (recalculates on current water level) 0.00 1.00 NO 14.98 91 5.84 3.9 266 0.00 1.00 NO 15.06 91 5.87 17.1 265 0.00 N/A N/A N/A Sampled:N/A N/A N/A N/A If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water Level To The Right Before Sampling to Determine Recharge. DATE: TIME: WATER LEVEL: WELL VOL: Evacuated:N/A 0825 N/A TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 3.00 PSP 1/31/2017 Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Casing in good condition FLUSH MOUNT WELLS WELL CAPS Well cap in good conditon WELL CASING Good Condition ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Good Condition Well Impacted By Silting:NO SAMPLING NOTES WELL SECURITY Well found locked WELL LOCK CONDITION Lock in good condition WELL TAG Well tag in good condition ACCESS AROUND WELL Access cleared around well 30 31 T SP DISS WTU GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A 20.20 30.20 18 (psi)9 (sec) (sec) (gal) 0.92 (gal) @ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY GROUNDWATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR CONVENTIONAL SAMPLING WELL DEPTH (ft TOC) 30.20 GS ELEV (ft msl) 0.00 PUMP INTAKE DEPTH (ft TOC) 29.00 CRW-6 MONITORING WELL INFORMATION WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 783.10 MIDDLE OF WETTED SCREEN (ft toc)27.38 SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME EQUIPMENT INFORMATION SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 6 LEVEL METER SERIAL# 28651 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD DETECTED ODOR None ODOR STRENGTH None APPEARANCE Normal WATER ELEVATION (ft msl) 758.54 WELL VOLUME 0.92 SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 24.56 WATER COLUMN (ft) 5.64 (gal) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED (mV -NHE)(mg/L) 1.00 YES 16.92 65 5.09 34.5 543 (ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU) WELL VOL VOLUME EVACUATION COND. OXYGEN (recalculates on current water level) 0.00 1415 BELOW PUMP N/A Sampled:1/31/2017 1100 24.56 0.92 If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water Level To The Right Before Sampling to Determine Recharge. DATE: TIME: WATER LEVEL: WELL VOL: Evacuated:1/30/2017 1100 N/A TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 1.00 PSP 1/30/2017 Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Casing in good condition FLUSH MOUNT WELLS WELL CAPS Well cap in good conditon WELL CASING Good Condition ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Good Condition Well Impacted By Silting:NO SAMPLING NOTES WELL SECURITY Well found locked WELL LOCK CONDITION Lock in good condition WELL TAG Well tag in good condition ACCESS AROUND WELL Access cleared around well 30 31 T SP DISS WTU GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A 19.90 29.90 18 (psi)5 (sec) (sec) (gal) 0.39 (gal) @ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY GROUNDWATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR CONVENTIONAL SAMPLING WELL DEPTH (ft TOC) 29.90 GS ELEV (ft msl) 0.00 PUMP INTAKE DEPTH (ft TOC) 29.00 CRW-7 MONITORING WELL INFORMATION WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 785.08 MIDDLE OF WETTED SCREEN (ft toc)28.70 SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME EQUIPMENT INFORMATION SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 5 LEVEL METER SERIAL# 28651 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD DETECTED ODOR None ODOR STRENGTH None No sample - insufficient volume / could not get dischargeAPPEARANCE WATER ELEVATION (ft msl) 757.58 WELL VOLUME 0.39 SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 27.50 WATER COLUMN (ft) 2.40 (gal) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED (mV -NHE)(mg/L)(ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU) WELL VOL VOLUME EVACUATION COND. OXYGEN (recalculates on current water level) N/A N/A Sampled: If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water Level To The Right Before Sampling to Determine Recharge. DATE: TIME: WATER LEVEL: WELL VOL: Evacuated: N/A TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 0.00 PSP 1/30/2017 Sample preservation verified to pH (units)N/A PROTECTIVE CASING Casing in good condition FLUSH MOUNT WELLS WELL CAPS Well cap in good conditon WELL CASING Good Condition ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Good Condition Well Impacted By Silting:NO SAMPLING NOTES WELL SECURITY Well found locked WELL LOCK CONDITION Lock in good condition WELL TAG Well tag in good condition ACCESS AROUND WELL Access cleared around well 30 31 T SP DISS WTU GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A 30.18 40.18 18 (psi)10 (sec) (sec) (gal) @ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY GROUNDWATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR LOW FLOW SAMPLING WELL DEPTH (ft TOC) 40.18 GS ELEV (ft msl) 773.68 PUMP INTAKE DEPTH (ft TOC) 39.68 CRW-8R MONITORING WELL INFORMATION WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 776.39 MIDDLE OF WETTED SCREEN (ft toc)35.18 SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME EQUIPMENT INFORMATION SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Low Flow PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 10 LEVEL METER SERIAL# 28651 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD DETECTED ODOR None ODOR STRENGTH None APPEARANCE Normal WATER ELEVATION (ft msl) 747.87 WELL VOLUME 1.90 SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 28.52 WATER COLUMN (ft) 11.66 ORP DISSOLVED WELL VOL LEVEL COND. (gal) TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY (mV-NHE)(mg/L) 9:15 29.15 270 14.61 100 5.50 23.0 524 OXYGEN (recalculates on current water level)(hh:mm) (ft) (ml/min) (deg C) (umho/cm) (SU) (NTU) 8.34 N/A 9:25 29.15 270 14.52 94 5.57 18.4 534 8.34 N/A 9:20 29.15 270 14.72 97 5.54 27.0 530 8.45 N/A 9:35 29.15 270 14.43 92 5.65 17.5 539 8.29 N/A 9:30 29.15 270 14.52 93 5.64 18.3 536 8.44 N/A DRAW-DOWN 0.63 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l) INITIAL PURGE VOLUME 1.50 (gal) N/A SAMPLE COLLECTED BY DATE TIME TOTAL PURGE VOLUME 2.95 (gal)PSP 1/31/2017 0940 Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Casing in good condition FLUSH MOUNT WELLS WELL CAPS Well cap in good conditon WELL CASING Good Condition ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Good Condition Well Impacted By Silting:NO SAMPLING NOTES Lift well cap up one foot from PVC well casing, pump at 330 mL/min with settings indicated above and remove 2 gallons prior to recording low flow parameters. WELL SECURITY Well found locked WELL LOCK CONDITION Lock in good condition WELL TAG Well tag in good condition ACCESS AROUND WELL Access cleared around well 30 31 T SP DISS WETU GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A 29.62 39.62 18 (psi)10 (sec) (sec) (gal) @ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY GROUNDWATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR LOW FLOW SAMPLING WELL DEPTH (ft TOC) 39.62 GS ELEV (ft msl) 0.00 PUMP INTAKE DEPTH (ft TOC) 38.50 CRW-9 MONITORING WELL INFORMATION WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 769.67 MIDDLE OF WETTED SCREEN (ft toc)34.62 SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME EQUIPMENT INFORMATION SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Low Flow PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 10 LEVEL METER SERIAL# 28651 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD DETECTED ODOR None ODOR STRENGTH None APPEARANCE Normal WATER ELEVATION (ft msl) 742.51 WELL VOLUME 2.03 SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 27.16 WATER COLUMN (ft) 12.46 ORP DISSOLVED WELL VOL LEVEL COND. (gal) TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY (mV-NHE)(mg/L) 10:05 28.57 300 15.38 52 5.77 18.7 535 OXYGEN (recalculates on current water level)(hh:mm) (ft) (ml/min) (deg C) (umho/cm) (SU) (NTU) 6.87 N/A 10:15 28.57 300 15.52 50 5.76 15.6 548 6.72 N/A 10:10 28.57 300 15.51 49 5.74 17.5 542 6.88 N/A DRAW-DOWN 1.41 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l) INITIAL PURGE VOLUME 0.75 (gal) N/A SAMPLE COLLECTED BY DATE TIME TOTAL PURGE VOLUME 1.55 (gal)PSP 1/31/2017 1020 Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Casing in good condition FLUSH MOUNT WELLS WELL CAPS Well cap in good conditon WELL CASING Good Condition ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Good Condition Well Impacted By Silting:NO SAMPLING NOTES WELL SECURITY Well found locked WELL LOCK CONDITION Lock in good condition WELL TAG Well tag in good condition ACCESS AROUND WELL Access cleared around well 30 31 T SP DISS WETU GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A 20.16 30.16 18 (psi)14 (sec) (sec) (gal) 1.05 (gal) @ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY GROUNDWATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR CONVENTIONAL SAMPLING WELL DEPTH (ft TOC) 30.16 GS ELEV (ft msl) 0.00 PUMP INTAKE DEPTH (ft TOC) 29.00 CRW-10 MONITORING WELL INFORMATION WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 777.23 MIDDLE OF WETTED SCREEN (ft toc)26.95 SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME EQUIPMENT INFORMATION SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 6 LEVEL METER SERIAL# 28650 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD DETECTED ODOR None ODOR STRENGTH None APPEARANCE Normal WATER ELEVATION (ft msl) 753.49 WELL VOLUME 1.05 SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 23.74 WATER COLUMN (ft) 6.42 (gal) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED (mV -NHE)(mg/L) 1.25 24.92 NO 14.10 226 5.62 67.1 632 (ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU) WELL VOL VOLUME EVACUATION COND. OXYGEN (recalculates on current water level) 1.66 0.70 0.75 26.98 NO 13.88 199 5.60 64.7 558 1.55 0.85 1.00 25.88 NO 14.30 210 5.58 43.3 575 3.62 0.75 NO 13.70 195 5.57 5.4 542 2.55 0.52 0.75 NO 13.67 196 5.58 10.0 545 N/A N/A Sampled: 3.57 If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water Level To The Right Before Sampling to Determine Recharge. DATE: TIME: WATER LEVEL: WELL VOL: Evacuated: 0850 N/A TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 4.50 LDC 1/31/2017 Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Casing in good condition FLUSH MOUNT WELLS WELL CAPS Well cap in good conditon WELL CASING Good Condition ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Good Condition Well Impacted By Silting:NO SAMPLING NOTES Had to thaw discharge line. WELL SECURITY Well found locked WELL LOCK CONDITION Lock in good condition WELL TAG Well tag in good condition ACCESS AROUND WELL Access cleared around well 30 31 T SP DISS WTU GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A 28.52 38.52 15 (psi)10 (sec) (sec) (gal) 815 (ml) 495 (ml) 1310 (ml)=0.35 (gal)@ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY GROUNDWATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR EQUIPMENT PURGE ONLY SAMPLING WELL DEPTH (ft TOC) 38.52 GS ELEV (ft msl) 813.38 PUMP INTAKE DEPTH (ft TOC) 37.52 CRW-11 MONITORING WELL INFORMATION WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 816.12 MIDDLE OF WETTED SCREEN (ft toc)34.81 SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME EQUIPMENT INFORMATION SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Equip. Only Purge PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 5 LEVEL METER SERIAL# 28650 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD DETECTED ODOR None ODOR STRENGTH None APPEARANCE Normal WATER ELEVATION (ft msl) 785.02 WELL VOLUME 1.21 SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 31.10 WATER COLUMN (ft) 7.42 OXYGEN (ft) (ml/min) (ft) (deg C) (umho/cm) (SU) TURBIDITY ORP DISSOLVED WATER LEVEL RATE WATER LEVEL COND. INITIAL FLOW FINAL TEMP SPECIFIC pH 477 8.48 N/A If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water Level To The Right Before Sampling to Determine Recharge. DATE: TIME: WATER LEVEL: Well Vol.: Evacuated: (NTU)(mV -NEH)(mg/L) 31.10 160 31.76 14.06 125 6.34 9.3 Tubing Volume INITIAL PURGE VOL.EQUIPMENT PURGE ONLY SAMPLE CHLORINE (mg/l)Pump (Bladder) Volume 0.50 SAMPLE COLLECTED BY DATE TIME N/A N/A Sample: Total Purge Volume LDC 1/31/2017 0945 N/A Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Casing in good condition FLUSH MOUNT WELLS WELL CAPS Well cap in good conditon WELL CASING Good Condition ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Good Condition Well Impacted By Silting:NO SAMPLING NOTES WELL SECURITY Well found locked WELL LOCK CONDITION Lock in good condition WELL TAG Well tag in good condition ACCESS AROUND WELL Access cleared around well 30 31 GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A 34.65 44.65 20 (psi)10 (sec) (sec) (gal) @ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY GROUNDWATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR LOW FLOW SAMPLING WELL DEPTH (ft TOC) 44.65 GS ELEV (ft msl) 835.00 PUMP INTAKE DEPTH (ft TOC) 44.15 CRW-12 MONITORING WELL INFORMATION WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 837.93 MIDDLE OF WETTED SCREEN (ft toc)40.59 SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME EQUIPMENT INFORMATION SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Low Flow PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 10 LEVEL METER SERIAL# 28650 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD DETECTED ODOR None ODOR STRENGTH None APPEARANCE Normal WATER ELEVATION (ft msl) 801.41 WELL VOLUME 1.33 SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 36.52 WATER COLUMN (ft) 8.13 ORP DISSOLVED WELL VOL LEVEL COND. (gal) TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY (mV-NHE)(mg/L) 8:15 37.13 150 12.74 53 5.56 16.2 560 OXYGEN (recalculates on current water level)(hh:mm) (ft) (ml/min) (deg C) (umho/cm) (SU) (NTU) 7.78 N/A 8:25 37.13 150 13.42 54 5.53 9.4 557 7.93 N/A 8:20 37.13 150 13.17 53 5.53 10.7 558 7.75 N/A DRAW-DOWN 0.61 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l) INITIAL PURGE VOLUME 0.50 (gal) N/A SAMPLE COLLECTED BY DATE TIME TOTAL PURGE VOLUME 0.90 (gal)LDC 1/30/2017 0830 Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Casing in good condition FLUSH MOUNT WELLS WELL CAPS Well cap in good conditon WELL CASING Good Condition ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Good Condition Well Impacted By Silting:NO SAMPLING NOTES Lift well cap 3 feet up from top of well casing. WELL SECURITY Well found locked WELL LOCK CONDITION Lock in good condition WELL TAG Well tag in good condition ACCESS AROUND WELL Access cleared around well 30 31 T SP DISS WETU GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A 29.28 39.28 19 (psi)10 (sec) (sec) (gal) 0.85 (gal) @ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY GROUNDWATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR CONVENTIONAL SAMPLING WELL DEPTH (ft TOC) 39.28 GS ELEV (ft msl)819.44 PUMP INTAKE DEPTH (ft TOC) 38.78 CRW-13 MONITORING WELL INFORMATION WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 822.49 MIDDLE OF WETTED SCREEN (ft toc)36.68 SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME EQUIPMENT INFORMATION SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Conventional PUMP CONTROLLER SETTINGS SEE NOTE BELOW PRESSURE RECHARGE DISCHARGE 10 LEVEL METER SERIAL# 28650 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD DETECTED ODOR None ODOR STRENGTH None APPEARANCE Normal WATER ELEVATION (ft msl) 788.41 WELL VOLUME 0.85 SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 34.08 WATER COLUMN (ft) 5.20 (gal) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED (mV -NHE)(mg/L) 1.00 NO 13.17 141 6.02 13.7 529 (ft) (YES/NO) (deg C) (umho/cm) (SU) (NTU) WELL VOL VOLUME EVACUATION COND. OXYGEN (recalculates on current water level) 7.97 1.00 NO 12.34 150 6.03 10.5 509 8.03 1.00 NO 12.53 147 6.02 11.1 518 7.99 8.10 1.00 NO 12.88 151 6.03 6.8 503 N/A N/A Sampled: If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water Level To The Right Before Sampling to Determine Recharge. DATE: TIME: WATER LEVEL: WELL VOL: Evacuated: 0955 N/A TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 4.00 LDC 1/30/2017 Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Casing in good condition FLUSH MOUNT WELLS WELL CAPS Well cap in good conditon WELL CASING Good Condition ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Good Condition Well Impacted By Silting:NO SAMPLING NOTES Pump at 230 mL/min. WELL SECURITY Well found locked WELL LOCK CONDITION Lock in good condition WELL TAG Well tag in good condition ACCESS AROUND WELL Access cleared around well 30 31 T SP DISS WTU GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A 26.44 41.44 20 (psi)5 (sec) (sec) (gal) @ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY GROUNDWATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR LOW FLOW SAMPLING WELL DEPTH (ft TOC) 41.44 GS ELEV (ft msl) 792.23 PUMP INTAKE DEPTH (ft TOC) 40.44 CRW-14 MONITORING WELL INFORMATION WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 794.87 MIDDLE OF WETTED SCREEN (ft toc)33.94 SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME EQUIPMENT INFORMATION SCREEN LENGTH (ft) 15 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Low Flow PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 10 LEVEL METER SERIAL# 28650 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD DETECTED ODOR None ODOR STRENGTH None APPEARANCE Normal WATER ELEVATION (ft msl) 771.31 WELL VOLUME 2.92 SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 23.56 WATER COLUMN (ft) 17.88 ORP DISSOLVED WELL VOL LEVEL COND. (gal) TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY (mV-NHE)(mg/L) 10:25 23.79 400 14.45 401 6.55 7.1 486 OXYGEN (recalculates on current water level)(hh:mm) (ft) (ml/min) (deg C) (umho/cm) (SU) (NTU) 2.39 N/A 10:35 23.79 400 14.75 345 6.33 4.0 488 1.97 N/A 10:30 23.79 400 14.73 377 6.46 5.0 485 4.96 N/A 10:45 23.79 400 14.85 283 6.09 2.9 499 3.53 N/A 10:40 23.79 400 14.80 302 6.17 3.0 494 5.96 N/A 10:55 23.79 400 14.83 266 5.97 5.4 505 5.54 N/A 10:50 23.79 400 14.90 270 6.03 3.9 502 6.46 N/A 6.29 N/A 11:00 23.79 400 14.86 266 5.95 5.4 508 DRAW-DOWN 0.23 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l) INITIAL PURGE VOLUME 0.50 (gal) N/A SAMPLE COLLECTED BY DATE TIME TOTAL PURGE VOLUME 4.20 (gal)LDC 1/30/2017 1105 Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Casing in good condition FLUSH MOUNT WELLS WELL CAPS Well cap in good conditon WELL CASING Good Condition ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Good Condition Well Impacted By Silting:NO SAMPLING NOTES WELL SECURITY Well found locked WELL LOCK CONDITION Lock in good condition WELL TAG Well tag in good condition ACCESS AROUND WELL Access cleared around well 30 31 T SP DISS WETU GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A 28.82 38.82 25 (psi)11 (sec) (sec) (gal) 832 (ml) 495 (ml) 1327 (ml)=0.35 (gal)@ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY GROUNDWATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR EQUIPMENT PURGE ONLY SAMPLING WELL DEPTH (ft TOC) 38.82 GS ELEV (ft msl) 765.69 PUMP INTAKE DEPTH (ft TOC) 38.32 CRW-15 MONITORING WELL INFORMATION WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 768.43 MIDDLE OF WETTED SCREEN (ft toc)37.51 SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME EQUIPMENT INFORMATION SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Equip. Only Purge PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 9 LEVEL METER SERIAL# 28650 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD DETECTED ODOR None ODOR STRENGTH None APPEARANCE Normal WATER ELEVATION (ft msl) 732.23 WELL VOLUME 0.43 SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 36.20 WATER COLUMN (ft) 2.62 OXYGEN (ft) (ml/min) (ft) (deg C) (umho/cm) (SU) TURBIDITY ORP DISSOLVED WATER LEVEL RATE WATER LEVEL COND. INITIAL FLOW FINAL TEMP SPECIFIC pH 504 8.22 N/A If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water Level To The Right Before Sampling to Determine Recharge. DATE: TIME: WATER LEVEL: Well Vol.: Evacuated: (NTU)(mV -NEH)(mg/L) 36.20 114 Below pump 13.48 94 5.76 2.1 Tubing Volume INITIAL PURGE VOL.EQUIPMENT PURGE ONLY SAMPLE CHLORINE (mg/l)Pump (Bladder) Volume 0.50 SAMPLE COLLECTED BY DATE TIME N/A N/A Sampled: Total Purge Volume LDC 1/30/2017 1145 N/A Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Casing in good condition FLUSH MOUNT WELLS WELL CAPS Well cap in good conditon WELL CASING Good Condition ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Good Condition Well Impacted By Silting:NO SAMPLING NOTES Pump needs top check valve. WELL SECURITY Well found locked WELL LOCK CONDITION Lock in good condition WELL TAG Well tag in good condition ACCESS AROUND WELL Access cleared around well 30 31 GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A 40.66 50.66 20 (psi)10 (sec) (sec) (gal) @ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY GROUNDWATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR LOW FLOW SAMPLING WELL DEPTH (ft TOC) 50.66 GS ELEV (ft msl) 770.58 PUMP INTAKE DEPTH (ft TOC) 47.66 CRW-16 MONITORING WELL INFORMATION WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 773.59 MIDDLE OF WETTED SCREEN (ft toc)47.00 SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME EQUIPMENT INFORMATION SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Low Flow PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 10 LEVEL METER SERIAL# 28651 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD DETECTED ODOR None ODOR STRENGTH None APPEARANCE Normal WATER ELEVATION (ft msl) 730.26 WELL VOLUME 1.20 SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 43.33 WATER COLUMN (ft) 7.33 ORP DISSOLVED WELL VOL LEVEL COND. (gal) TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY (mV-NHE)(mg/L) 8:35 43.91 192 12.46 68 5.68 218.0 576 OXYGEN (recalculates on current water level)(hh:mm) (ft) (ml/min) (deg C) (umho/cm) (SU) (NTU) 3.24 N/A 8:45 43.91 192 12.36 70 5.69 58.7 567 3.30 N/A 8:40 43.91 192 12.37 69 5.69 117.0 572 3.19 N/A 8:55 43.91 192 11.96 70 5.68 28.0 562 3.20 N/A 8:50 43.91 192 12.30 70 5.69 36.0 565 3.19 N/A 9:05 43.91 192 12.06 70 5.68 13.6 557 3.19 N/A 9:00 43.91 192 12.12 71 5.68 15.0 559 3.26 N/A 3.21 N/A 9:10 43.91 192 11.80 70 5.68 10.7 556 DRAW-DOWN 0.58 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l) INITIAL PURGE VOLUME 1.50 (gal) N/A SAMPLE COLLECTED BY DATE TIME TOTAL PURGE VOLUME 3.30 (gal)PSP 1/30/2017 0915 Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Casing in good condition FLUSH MOUNT WELLS WELL CAPS Well cap in good conditon WELL CASING Good Condition ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Debris covering well pad Well Impacted By Silting:NO SAMPLING NOTES LIFT WELL CAP FIVE FOOT UP FROM PVC WELL CASING AND PUMP AT 150 mL/min. WELL SECURITY Well found locked WELL LOCK CONDITION Lock in good condition WELL TAG Well tag in good condition ACCESS AROUND WELL Access cleared around well 30 31 T SP DISS WETU GAMMA A H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A 31.70 41.70 15 (psi)10 (sec) (sec) (gal) 884 (ml) 495 (ml) 1379 (ml)=0.36 (gal)@ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY GROUNDWATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR EQUIPMENT PURGE ONLY SAMPLING WELL DEPTH (ft TOC) 41.70 GS ELEV (ft msl) 831.62 PUMP INTAKE DEPTH (ft TOC) 40.70 CRW-17 MONITORING WELL INFORMATION WELL DIAMETER (in) 2.00 TOC ELEV (ft msl) 834.56 MIDDLE OF WETTED SCREEN (ft toc)38.61 SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME EQUIPMENT INFORMATION SCREEN LENGTH (ft) 10 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD STICK UP WELL MONITORING WELL FOSSIL LANDFILL NPDES Equip. Only Purge PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 5 LEVEL METER SERIAL# 28650 SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in)1/2 OD DETECTED ODOR None ODOR STRENGTH None APPEARANCE Normal WATER ELEVATION (ft msl) 799.05 WELL VOLUME 1.01 SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC) 35.51 WATER COLUMN (ft) 6.19 OXYGEN (ft) (ml/min) (ft) (deg C) (umho/cm) (SU) TURBIDITY ORP DISSOLVED WATER LEVEL RATE WATER LEVEL COND. INITIAL FLOW FINAL TEMP SPECIFIC pH 497 6.38 N/A If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water Level To The Right Before Sampling to Determine Recharge. DATE: TIME: WATER LEVEL: Well Vol.: Evacuated: (NTU)(mV -NEH)(mg/L) 35.51 110 35.78 14.80 70 5.81 3.4 Tubing Volume INITIAL PURGE VOL.EQUIPMENT PURGE ONLY SAMPLE CHLORINE (mg/l)Pump (Bladder) Volume 0.50 SAMPLE COLLECTED BY DATE TIME N/A N/A Sample: Total Purge Volume LDC 1/31/2017 1030 N/A Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Casing in good condition FLUSH MOUNT WELLS WELL CAPS Well cap in good conditon WELL CASING Good Condition ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Good Condition Well Impacted By Silting:NO SAMPLING NOTES WELL SECURITY Well found locked WELL LOCK CONDITION Lock in good condition WELL TAG Well tag in good condition ACCESS AROUND WELL Access cleared around well 30 31 GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A @ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY SURFACE WATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR SURFACE WATER SAMPLING CRS-1SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME SAMPLING METHOD: GRAB LOCATION ENVIRONMENT: WOODED SURFACE WATER LOCATION INFORMATION LOCATION TYPE: STREAM WAS WATER PRESENT: YES WAS THERE A NOTICABLE FLOW: YES WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD FOSSIL LANDFILL NPDES Surface Water Sample DETECTED ODOR None ODOR STRENGTH None APPEARANCE Normal SAMPLING INFORMATION DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED (METERS)(deg C) (umho/cm) (SU) (NTU)(mV -NEH)(mg/L) INTAKE COND. OXYGEN TIME LDC 1/31/2017 0910 N/A Sample preservation verified to pH (units)< 2.0 4.4 407 10.36 N/A FLOW CONDITIONS: SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE N/A 4.89 107 6.51 PROTECTIVE CASING FLUSH MOUNT WELLS WELL CAPS WELL CASING ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Well Impacted By Silting:N/A SAMPLING NOTES Filtered metal collected at 0925 hrs WELL SECURITY WELL LOCK CONDITION WELL TAG ACCESS AROUND WELL Access cleared around well 30 31 T SP DISSTU GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A @ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY SURFACE WATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR SURFACE WATER SAMPLING CRS-2SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME SAMPLING METHOD: GRAB LOCATION ENVIRONMENT: WOODED SURFACE WATER LOCATION INFORMATION LOCATION TYPE: STREAM WAS WATER PRESENT: YES WAS THERE A NOTICABLE FLOW: YES WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD FOSSIL LANDFILL NPDES Surface Water Sample DETECTED ODOR None ODOR STRENGTH None APPEARANCE Normal SAMPLING INFORMATION DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED (METERS)(deg C) (umho/cm) (SU) (NTU)(mV -NEH)(mg/L) INTAKE COND. OXYGEN TIME PSP 1/31/2017 1040 N/A Sample preservation verified to pH (units)< 2.0 3.4 296 11.69 N/A FLOW CONDITIONS: SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE N/A 4.84 116 6.51 PROTECTIVE CASING FLUSH MOUNT WELLS WELL CAPS WELL CASING ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Well Impacted By Silting:N/A SAMPLING NOTES WELL SECURITY WELL LOCK CONDITION WELL TAG ACCESS AROUND WELL Access cleared around well 30 31 T SP DISSTU GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A @ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY SURFACE WATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR SURFACE WATER SAMPLING CRS-3SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME SAMPLING METHOD: GRAB LOCATION ENVIRONMENT: WOODED LOCATION DRY SURFACE WATER LOCATION INFORMATION LOCATION TYPE: STREAM WAS WATER PRESENT: NO WAS THERE A NOTICABLE FLOW: NO WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD FOSSIL LANDFILL NPDES Surface Water Sample DETECTED ODOR None ODOR STRENGTH None NO SAMPLE - LOCATION WAS DRYAPPEARANCE Normal SAMPLING INFORMATION DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED (METERS)(deg C) (umho/cm) (SU) (NTU)(mV -NEH)(mg/L) INTAKE COND. OXYGEN TIME PSP 1/30/2017 0940 N/A Sample preservation verified to pH (units)< 2.0 N/A FLOW CONDITIONS: SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE PROTECTIVE CASING FLUSH MOUNT WELLS WELL CAPS WELL CASING ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Well Impacted By Silting:N/A SAMPLING NOTES WELL SECURITY WELL LOCK CONDITION WELL TAG ACCESS AROUND WELL Access cleared around well 30 31 T SP DISSTU GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A @ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY SURFACE WATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR SURFACE WATER SAMPLING CRS-4SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME SAMPLING METHOD: GRAB LOCATION ENVIRONMENT: WOODED SURFACE WATER LOCATION INFORMATION LOCATION TYPE: STREAM WAS WATER PRESENT: YES WAS THERE A NOTICABLE FLOW: YES WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD FOSSIL LANDFILL NPDES Surface Water Sample DETECTED ODOR None ODOR STRENGTH None APPEARANCE Normal SAMPLING INFORMATION DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED (METERS)(deg C) (umho/cm) (SU) (NTU)(mV -NEH)(mg/L) INTAKE COND. OXYGEN TIME PSP 1/30/2017 1145 N/A Sample preservation verified to pH (units)< 2.0 5.2 416 4.57 N/A FLOW CONDITIONS: SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE N/A 11.90 107 5.83 PROTECTIVE CASING FLUSH MOUNT WELLS WELL CAPS WELL CASING ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Well Impacted By Silting:N/A SAMPLING NOTES WELL SECURITY WELL LOCK CONDITION WELL TAG ACCESS AROUND WELL Access cleared around well 30 31 T SP DISSTU GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A @ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY SURFACE WATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR SURFACE WATER SAMPLING CRS-5SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME SAMPLING METHOD: PERISTALTIC PUMP LOCATION ENVIRONMENT: WOODED SURFACE WATER LOCATION INFORMATION LOCATION TYPE: STREAM WAS WATER PRESENT: YES WAS THERE A NOTICABLE FLOW: YES WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD FOSSIL LANDFILL NPDES Surface Water Sample DETECTED ODOR None ODOR STRENGTH None APPEARANCE Oil/Sheen SAMPLING INFORMATION DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED (METERS)(deg C) (umho/cm) (SU) (NTU)(mV -NEH)(mg/L) INTAKE COND. OXYGEN TIME PSP 1/31/2017 0850 N/A Sample preservation verified to pH (units)< 2.0 26.5 329 6.01 N/A FLOW CONDITIONS: SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE 0.10 10.94 80 5.70 PROTECTIVE CASING FLUSH MOUNT WELLS WELL CAPS WELL CASING ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Well Impacted By Silting:N/A SAMPLING NOTES WELL SECURITY WELL LOCK CONDITION WELL TAG ACCESS AROUND WELL Access cleared around well 30 31 T SP DISSTU GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A @ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY SURFACE WATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR SURFACE WATER SAMPLING CRS-6SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME SAMPLING METHOD: PERISTALTIC PUMP LOCATION ENVIRONMENT: WOODED SURFACE WATER LOCATION INFORMATION LOCATION TYPE: STREAM WAS WATER PRESENT: YES WAS THERE A NOTICABLE FLOW: YES WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD FOSSIL LANDFILL NPDES Surface Water Sample DETECTED ODOR None ODOR STRENGTH None APPEARANCE Normal SAMPLING INFORMATION DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED (METERS)(deg C) (umho/cm) (SU) (NTU)(mV -NEH)(mg/L) INTAKE COND. OXYGEN TIME LDC 1/31/2017 1115 N/A Sample preservation verified to pH (units)< 2.0 12.7 492 8.19 N/A FLOW CONDITIONS: SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE 0.10 14.94 98 5.86 PROTECTIVE CASING FLUSH MOUNT WELLS WELL CAPS WELL CASING ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Well Impacted By Silting:N/A SAMPLING NOTES Filtered metal collected at 1130 hrs WELL SECURITY WELL LOCK CONDITION WELL TAG ACCESS AROUND WELL Access cleared around well 30 31 T SP DISSTU GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A @ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY SURFACE WATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR SURFACE WATER SAMPLING CWB-1SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME SAMPLING METHOD: GRAB LOCATION ENVIRONMENT: PIPE SURFACE WATER LOCATION INFORMATION LOCATION TYPE: LEACHATE/DRAINAGE WAS WATER PRESENT: YES WAS THERE A NOTICABLE FLOW: YES WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD FOSSIL LANDFILL NPDES Surface Water Sample DETECTED ODOR None ODOR STRENGTH None APPEARANCE Normal SAMPLING INFORMATION DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED (METERS)(deg C) (umho/cm) (SU) (NTU)(mV -NEH)(mg/L) INTAKE COND. OXYGEN TIME LDC 1/30/2017 1250 N/A Sample preservation verified to pH (units)< 2.0 1.4 555 9.32 N/A FLOW CONDITIONS: SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE 0.10 14.40 4344 4.69 PROTECTIVE CASING FLUSH MOUNT WELLS WELL CAPS Location formerly known as E-WWB-Leachate WELL CASING ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Well Impacted By Silting:N/A SAMPLING NOTES WELL SECURITY WELL LOCK CONDITION WELL TAG ACCESS AROUND WELL Access cleared around well 30 31 T SP DISSTU GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A @ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY SURFACE WATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR SURFACE WATER SAMPLING CWB-2SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME SAMPLING METHOD: GRAB LOCATION ENVIRONMENT: PIPE SURFACE WATER LOCATION INFORMATION LOCATION TYPE: LEACHATE/DRAINAGE WAS WATER PRESENT: YES WAS THERE A NOTICABLE FLOW: YES WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD FOSSIL LANDFILL NPDES Surface Water Sample DETECTED ODOR None ODOR STRENGTH None APPEARANCE Normal SAMPLING INFORMATION DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED (METERS)(deg C) (umho/cm) (SU) (NTU)(mV -NEH)(mg/L) INTAKE COND. OXYGEN TIME LDC 1/30/2017 1220 N/A Sample preservation verified to pH (units)< 2.0 1.3 596 8.50 N/A FLOW CONDITIONS: SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE 0.10 16.05 6389 3.81 PROTECTIVE CASING FLUSH MOUNT WELLS WELL CAPS Location formerly known as W-WWB-Leachate WELL CASING ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Well Impacted By Silting:N/A SAMPLING NOTES 0 WELL SECURITY WELL LOCK CONDITION WELL TAG ACCESS AROUND WELL Access cleared around well 30 31 T SP DISSTU GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC N/A @ QC By: SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-04 SITE ID PROJECT NAME CRAIG ROAD LANDFILL GROUNDWATER MONITORING PROGRAM FIELD CREW LDC, PSP DUKE ENERGY SURFACE WATER MONITORING DATA SHEET SAMPLING PROCEDURE NO. 3175.4 FOR SURFACE WATER SAMPLING CWB-3SAMPLING DATE(s)30-Jan-2017 31-Jan-2017 WELL/LOCATION NAME SAMPLING METHOD: GRAB LOCATION ENVIRONMENT: PIPE LOCATION DRY SURFACE WATER LOCATION INFORMATION LOCATION TYPE: LEACHATE/DRAINAGE WAS WATER PRESENT: NO WAS THERE A NOTICABLE FLOW: NO WELL/SAMPLING INFORMATION WELL TYPE WELL INFORMATION WELL USE PURGE METHOD FOSSIL LANDFILL NPDES Surface Water Sample DETECTED ODOR None ODOR STRENGTH None NO SAMPLE - LOCATION WAS DRYAPPEARANCE Normal SAMPLING INFORMATION DEPTH OF TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED (METERS)(deg C) (umho/cm) (SU) (NTU)(mV -NEH)(mg/L) INTAKE COND. OXYGEN TIME PSP 1/30/2017 0930 N/A Sample preservation verified to pH (units)< 2.0 N/A FLOW CONDITIONS: SURFACE WATER SAMPLE CHLORINE (mg/l)SAMPLE COLLECTED BY DATE PROTECTIVE CASING FLUSH MOUNT WELLS WELL CAPS WELL CASING ACCESS TO WELLS Access cleared into well SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED WELL CONDITION ADDITIONAL WELL CONDITION NOTES WELL PAD Well Impacted By Silting:N/A SAMPLING NOTES 0 WELL SECURITY WELL LOCK CONDITION WELL TAG ACCESS AROUND WELL Access cleared around well 30 31 T SP DISSTU GAMMA AA H3 SO4,CL SR 89/90 0 GROSS ALPH/BETA Fe 55 Ni 63 IODINE 131 BORON METALS NO3-N, CL, SO4 F_ALK TDS/TSS RADIUM 226/228 METALS F_ALK K CO2 VOC's RSK 175 TPH-DRO METALS NO3-N, CL, F, SO4, F_ALK TDS ALPHA SPEC CR W - 2 C R W - 3 C R W - 4 C R W - 5 C R W - 6 C R W - 7 C R W - 8 R C R W - 9 C R W - 1 0 C R W - 1 1 C R W - 1 2 C R W - 1 3 C R W - 1 4 C R W - 1 5 C R W - 1 6 C R W - 1 7 YE S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S YE S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S NO N O N O N O N O N O N O N O N O N O N O N O N O N O N O N O YE S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S YE S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S YE S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S YE S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S YE S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S YE S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S N/ A N / A N / A N / A N / A N / A N / A N / A N / A N / A N / A N / A N / A N / A N / A N / A YE S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S WE A T H E R Cle a r , s l i g h t b r e e z e , 2 5 t o 4 5 d e g F 1/ 3 1 / 2 0 1 7 Cl o u d s t h e n c l e a r , b r e e z y , 3 2 - 4 5 d e g F 1/ 3 0 / 2 0 1 7 We l l i m p a c t e d b y s i l t i n g PA G E 1 O F 2 Re p l a c e d d a m a g e d w e l l c a p Ma j o r c r a c k s / b r o k e n / r e p a i r r e q u i r e d An t s i n s i d e p r o t e c t i v e c a s i n g Da m a g e d c a s i n g / s t i l l f u n c t i o n a l Da m a g e d c a s i n g / r e p a i r r e q u i r e d Br o k e n h i n g e o n p r o t e c t i v e l i d Wa s p n e s t i n s i d e p r o t e c t i v e c a s i n g La c k s r e q u i r e d i n f o - C a s i n g d e p t h / d i a m . La c k s r e q u i r e d i n f o r m a t i o n - S c r e e n i n t e r v a l La c k s r e q u i r e d i n f o r m a t i o n - N o n p o t a b l e t a g La c k s r e q u i r e d i n f o r m a t i o n - D e p t h t o s c r e e n Wa t e r i n s i d e v a u l t Va u l t b o l t h o l e s b r o k e n o r s t r i p p e d Bo l t s s t r i p p e d Va u l t l i d c r a c k e d o r b r o k e n WE L L I D T A G S We l l t a g i n g o o d c o n d i t i o n We l l t a g m i s s i n g WE L L C A P S We l l c a p i n g o o d c o n d i t o n Da m a g e d / n e e d s r e p l a c e m e n t NO T E : Da m a g e d c a s i n g / r e p a i r r e q u i r e d Pa d i n g o o d c o n d i t i o n Min o r c r a c k s We l l t a g d a m a g e d / i l l e g i b l e La c k s r e q u i r e d i n f o r m a t i o n - S t a t i c W L / d a t e Un d e r m i n e d / w a s h i n g o u t Fi r e a n t s a r o u n d c o n c r e t e p a d La c k s r e q u i r e d i n f o r m a t i o n - D r i l l e r R e g # La c k s r e q u i r e d i n f o r m a t i o n - C o m p l e t i o n d a t e La c k s r e q u i r e d i n f o r m a t i o n - T o t a l w e l l d e p t h Va u l t i n g o o d c o n d i t i o n Ca s i n g i n g o o d c o n d i t i o n Ac c e s s c l e a r e d a r o u n d w e l l Ta l l g r a s s o r w e e d s - n e e d s m o w i n g Ro a d w a s h i n g o u t / m u d d y / n e e d s g r a d i n g FL U S H M O U N T W E L L S WE L L P R O T E C T I V E C A S I N G S CO N C R E T E P A D S WE L L S E C U R I T Y We l l f o u n d l o c k e d We l l f o u n d u n l o c k e d WE L L L O C K C O N D I T I O N Lo c k i n g o o d c o n d i t i o n Lo c k r u s t e d , d i f f i c u l t t o o p e n / n e e d s r e p l a c i n g Re p l a c e d d a m a g e d l o c k WE L L C A S I N G S Ca s i n g i n g o o d c o n d i t i o n Da m a g e d c a s i n g / s t i l l f u n c t i o n a l Fa l l e n t r e e b l o c k i n g a c c e s s WE L L D E P T H NO R T H C A R O L I N A G R O U N D W A T E R S A M P L I N G S I T E C H E C K L I S T SI T E : SA M P L E D A T E January 30 - 31, 2017 SI T E C O N T A C T FI E L D C R E W LDC, PSP PR O J E C T : Ke e l e y M c C o r m i c k , K i m b e r l y W i t t , M e l o n i e M a r t i n BE L E W S C R E E K S T E A M S T A T I O N CR A I G R O A D L A N D F I L L G R O U N D W A T E R M O N I T O R I N G P R O G R A M AC C E S S T O W E L L S Ac c e s s c l e a r e d i n t o w e l l CR S - 1 C R S - 2 C R S - 3 C R S - 4 C R S - 5 C R S - 6 C W B - 1 C W B - 2 C W B - 3 YE S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S YE S Y E S Y E S Y E S Y E S Y E S Y E S Y E S Y E S N/ A N / A N / A N / A N / A N / A N / A N / A N / A N/ A N / A N / A N / A N / A N / A N / A N / A N / A N/ A N / A N / A N / A N / A N / A N / A N / A N / A N/ A N / A N / A N / A N / A N / A N / A N / A N / A N/ A N / A N / A N / A N / A N / A N / A N / A N / A N/ A N / A N / A N / A N / A N / A N / A N / A N / A N/ A N / A N / A N / A N / A N / A N / A N / A N / A N/ A N / A N / A N / A N / A N / A N / A N / A N / A N/ A N / A N / A N / A N / A N / A N / A N / A N / A PR O J E C T : CR A I G R O A D L A N D F I L L G R O U N D W A T E R M O N I T O R I N G P R O G R A M FI E L D C R E W LDC, PSP NO R T H C A R O L I N A G R O U N D W A T E R S A M P L I N G S I T E C H E C K L I S T SI T E : BE L E W S C R E E K S T E A M S T A T I O N SA M P L E D A T E January 30 - 31, 2017 AC C E S S T O W E L L S SI T E C O N T A C T Ke e l e y M c C o r m i c k , K i m b e r l y W i t t , M e l o n i e M a r t i n WE A T H E R 1/ 3 0 / 2 0 1 7 C l o u d s t h e n c l e a r , b r e e z y , 3 2 - 4 5 d e g F 1/ 3 1 / 2 0 1 7 C l e a r , s l i g h t b r e e z e , 2 5 t o 4 5 d e g F PA G E 2 O F 2 We l l f o u n d u n l o c k e d Ac c e s s c l e a r e d i n t o w e l l Ac c e s s c l e a r e d a r o u n d w e l l Ta l l g r a s s o r w e e d s - n e e d s m o w i n g Ro a d w a s h i n g o u t / m u d d y / n e e d s g r a d i n g Fa l l e n t r e e b l o c k i n g a c c e s s WE L L D E P T H We l l i m p a c t e d b y s i l t i n g WE L L S E C U R I T Y We l l f o u n d l o c k e d CO N C R E T E P A D S WE L L L O C K C O N D I T I O N Lo c k i n g o o d c o n d i t i o n Lo c k r u s t e d , d i f f i c u l t t o o p e n / n e e d s r e p l a c i n g Re p l a c e d d a m a g e d l o c k WE L L C A S I N G S Ca s i n g i n g o o d c o n d i t i o n Da m a g e d c a s i n g / s t i l l f u n c t i o n a l Da m a g e d c a s i n g / r e p a i r r e q u i r e d Wa s p n e s t i n s i d e p r o t e c t i v e c a s i n g Pa d i n g o o d c o n d i t i o n Min o r c r a c k s Ma j o r c r a c k s / b r o k e n / r e p a i r r e q u i r e d Un d e r m i n e d / w a s h i n g o u t Fi r e a n t s a r o u n d c o n c r e t e p a d WE L L P R O T E C T I V E C A S I N G S Ca s i n g i n g o o d c o n d i t i o n Da m a g e d c a s i n g / s t i l l f u n c t i o n a l Da m a g e d c a s i n g / r e p a i r r e q u i r e d Br o k e n h i n g e o n p r o t e c t i v e l i d Bo l t s s t r i p p e d An t s i n s i d e p r o t e c t i v e c a s i n g WE L L C A P S We l l c a p i n g o o d c o n d i t o n Da m a g e d / n e e d s r e p l a c e m e n t Re p l a c e d d a m a g e d w e l l c a p FL U S H M O U N T W E L L S Va u l t i n g o o d c o n d i t i o n Wa t e r i n s i d e v a u l t Va u l t b o l t h o l e s b r o k e n o r s t r i p p e d La c k s r e q u i r e d i n f o r m a t i o n - S c r e e n i n t e r v a l Va u l t l i d c r a c k e d o r b r o k e n WE L L I D T A G S We l l t a g i n g o o d c o n d i t i o n We l l t a g m i s s i n g We l l t a g d a m a g e d / i l l e g i b l e La c k s r e q u i r e d i n f o r m a t i o n - D r i l l e r R e g # La c k s r e q u i r e d i n f o r m a t i o n - C o m p l e t i o n d a t e La c k s r e q u i r e d i n f o r m a t i o n - T o t a l w e l l d e p t h La c k s r e q u i r e d i n f o r m a t i o n - D e p t h t o s c r e e n La c k s r e q u i r e d i n f o - C a s i n g d e p t h / d i a m . La c k s r e q u i r e d i n f o r m a t i o n - S t a t i c W L / d a t e La c k s r e q u i r e d i n f o r m a t i o n - N o n p o t a b l e t a g NO T E : DA T E WE L L NO WE L L DE P T H (f t - T O C ) DE P T H T O WA T E R (f t - T O C ) WA T E R EL E V . (f t ) AP P E A R A N C E O D O R PU R G E ME T H O D PU M P RA T E (m l / m i n ) WE L L VO L . (g a l ) EV A C VO L . (g a l ) EV A C (Y E S / N O ) TE M P . (d e g . C ) SP E C I F I C CO N D U C T A N C E (u m h o / c m ) pH (units)TURBIDITY (NTU's)ORP (mV-NHE)DO (mg/L) 1/ 3 0 / 2 0 1 7 C R W - 2 3 8 . 2 4 2 4 . 1 3 7 3 7 . 3 3 N o r m a l N o n e L F 2 0 0 . 0 0 2 . 3 0 4 . 1 5 N / A 1 4 . 4 0 4 0 5 . 7 1 1 6 . 8 5 6 8 7 . 4 9 1/ 3 0 / 2 0 1 7 C R W - 3 1 8 . 8 4 8 . 4 8 7 3 7 . 9 1 T u r b i d N o n e C N / A 1 . 6 9 1 2 . 0 0 N O 1 4 . 0 2 6 2 5 . 6 0 6 2 . 6 5 3 1 6 . 2 2 1/ 3 0 / 2 0 1 7 C R W - 4 3 0 . 1 9 2 2 . 1 8 7 5 1 . 3 5 N o r m a l N o n e C N / A 1 . 3 1 7 . 5 0 N O 1 5 . 9 0 6 4 6 . 2 5 1 1 . 8 5 5 6 8 . 3 4 1/ 3 1 / 2 0 1 7 C R W - 5 2 3 . 1 6 1 7 . 0 5 7 4 7 . 6 9 N o r m a l N o n e C N / A 1 . 0 0 3 . 0 0 N O 1 4 . 9 8 9 1 5 . 8 4 3 . 9 2 6 6 0 . 0 0 1/ 3 0 / 2 0 1 7 C R W - 6 3 0 . 2 0 2 4 . 5 6 7 5 8 . 5 4 N o r m a l N o n e C N / A 0 . 9 2 1 . 0 0 Y E S 1 6 . 9 2 6 5 5 . 0 9 3 4 . 5 5 4 3 0 . 0 0 1/ 3 0 / 2 0 1 7 C R W - 7 2 9 . 9 0 2 7 . 5 0 7 5 7 . 5 8 1 / 0 / 1 9 0 0 N o n e C N / A 0 . 3 9 0 . 0 0 0 . 0 0 0 0 . 0 0 0 . 0 0 0 . 0 0 1/ 3 1 / 2 0 1 7 C R W - 8 R 4 0 . 1 8 2 8 . 5 2 7 4 7 . 8 7 N o r m a l N o n e L F 2 7 0 . 0 0 1 . 9 0 2 . 9 5 N / A 1 4 . 4 3 9 2 5 . 6 5 1 7 . 5 5 3 9 8 . 4 4 1/ 3 1 / 2 0 1 7 C R W - 9 3 9 . 6 2 2 7 . 1 6 7 4 2 . 5 1 N o r m a l N o n e L F 3 0 0 . 0 0 2 . 0 3 1 . 5 5 N / A 1 5 . 5 2 5 0 5 . 7 6 1 5 . 6 5 4 8 6 . 8 8 1/ 3 1 / 2 0 1 7 C R W - 1 0 3 0 . 1 6 2 3 . 7 4 7 5 3 . 4 9 N o r m a l N o n e C N / A 1 . 0 5 4 . 5 0 N O 1 3 . 7 0 1 9 5 5 . 5 7 5 . 4 5 4 2 3 . 5 7 1/ 3 1 / 2 0 1 7 C R W - 1 1 3 8 . 5 2 3 1 . 1 0 7 8 5 . 0 2 N o r m a l N o n e E O P N / A 1 . 2 1 0 . 5 0 N / A 1 4 . 0 6 1 2 5 6 . 3 4 9 . 3 4 7 7 8 . 4 8 1/ 3 0 / 2 0 1 7 C R W - 1 2 4 4 . 6 5 3 6 . 5 2 8 0 1 . 4 1 N o r m a l N o n e L F 1 5 0 . 0 0 1 . 3 3 0 . 9 0 N / A 1 3 . 4 2 5 4 5 . 5 3 9 . 4 5 5 7 7 . 7 5 1/ 3 0 / 2 0 1 7 C R W - 1 3 3 9 . 2 8 3 4 . 0 8 7 8 8 . 4 1 N o r m a l N o n e C N / A 0 . 8 5 4 . 0 0 N O 1 2 . 8 8 1 5 1 6 . 0 3 6 . 8 5 0 3 7 . 9 9 1/ 3 0 / 2 0 1 7 C R W - 1 3 3 9 . 2 8 3 4 . 0 8 7 8 8 . 4 1 N o r m a l N o n e C N / A 0 . 8 5 4 . 0 0 N O 1 2 . 8 8 1 5 1 6 . 0 3 6 . 8 5 0 3 7 . 9 9 1/ 3 0 / 2 0 1 7 C R W - 1 4 4 1 . 4 4 2 3 . 5 6 7 7 1 . 3 1 N o r m a l N o n e L F 4 0 0 . 0 0 2 . 9 2 4 . 2 0 N / A 1 4 . 8 6 2 6 6 5 . 9 5 5 . 4 5 0 8 6 . 4 6 1/ 3 0 / 2 0 1 7 C R W - 1 5 3 8 . 8 2 3 6 . 2 0 7 3 2 . 2 3 N o r m a l N o n e E O P N / A 0 . 4 3 0 . 5 0 N / A 1 3 . 4 8 9 4 5 . 7 6 2 . 1 5 0 4 8 . 2 2 1/ 3 0 / 2 0 1 7 C R W - 1 6 5 0 . 6 6 4 3 . 3 3 7 3 0 . 2 6 N o r m a l N o n e L F 1 9 2 . 0 0 1 . 2 0 3 . 3 0 N / A 1 1 . 8 0 7 0 5 . 6 8 1 0 . 7 5 5 6 3 . 2 6 1/ 3 1 / 2 0 1 7 C R W - 1 7 4 1 . 7 0 3 5 . 5 1 7 9 9 . 0 5 N o r m a l N o n e E O P N / A 1 . 0 1 0 . 5 0 N / A 1 4 . 8 0 7 0 5 . 8 1 3 . 4 4 9 7 6 . 3 8 1/ 3 1 / 2 0 1 7 C R S - 1 0 . 0 0 N o r m a l N o n e S W S N / A N / A N / A 4 . 8 9 1 0 7 6 . 5 1 4 . 4 4 0 7 1 0 . 3 6 1/ 3 1 / 2 0 1 7 C R S - 2 0 . 0 0 N o r m a l N o n e S W S N / A N / A N / A 4 . 8 4 1 1 6 6 . 5 1 3 . 4 2 9 6 1 1 . 6 9 1/ 3 0 / 2 0 1 7 C R S - 3 0 . 0 0 N o r m a l N o n e S W S N / A N / A N / A 0 . 0 0 0 0 . 0 0 0 . 0 0 0 . 0 0 1/ 3 0 / 2 0 1 7 C R S - 4 0 . 0 0 N o r m a l N o n e S W S N / A N / A N / A 1 1 . 9 0 1 0 7 5 . 8 3 5 . 2 4 1 6 4 . 5 7 1/ 3 1 / 2 0 1 7 C R S - 5 0 . 0 0 O i l / S h e e n N o n e S W S N / A N / A N / A 1 0 . 9 4 8 0 5 . 7 0 2 6 . 5 3 2 9 6 . 0 1 1/ 3 1 / 2 0 1 7 C R S - 6 0 . 0 0 N o r m a l N o n e S W S N / A N / A N / A 1 4 . 9 4 9 8 5 . 8 6 1 2 . 7 4 9 2 8 . 1 9 1/ 3 0 / 2 0 1 7 C W B - 1 0 . 0 0 N o r m a l N o n e S W S N / A N / A N / A 1 4 . 4 0 4 3 4 4 4 . 6 9 1 . 4 5 5 5 9 . 3 2 1/ 3 0 / 2 0 1 7 C W B - 2 0 . 0 0 N o r m a l N o n e S W S N / A N / A N / A 1 6 . 0 5 6 3 8 9 3 . 8 1 1 . 3 5 9 6 8 . 5 0 1/ 3 0 / 2 0 1 7 C W B - 3 0 . 0 0 N o r m a l N o n e S W S N / A N / A N / A 0 . 0 0 0 0 . 0 0 0 . 0 0 0 . 0 0 Pu r g e M e t h o d s LF = L o w F l o w NP = N o P u r g e EO P = E q u i p . O n l y P u r g e L O = L e v e l O n l y L F ( M ) = L o w F l o w ( M o d . ) * = A p p l i c a b l e t o L F & L F ( M ) P u r g i n g O n l y C = C o n n v e n t i o n a l BE L E W S C R E E K S T E A M S T A T I O N CR A I G R O A D L A N D F I L L G R O U N D W A T ER M O N I T O R I N G P R O G R A M GR O U N D W A T E R M O N I T O R I N G F I E L D D A T A PE R M I T # 8 5 - 0 4 B Appendix B Laboratory Report and Chain-of-Custody Forms 13339 Hagers Ferry RoadHuntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J16120415 Project Name:BELEWS - GW CRAIG ROAD LF Lab Contact: Anne Pridgeon Date:2/10/2017 Customer Address:3195 Pine Hall Rd Customer Name(s):Chuck Campbell, T. Hunsucker, Ed Sullivan Mailcode: Belews Steam Station Belews Creek, NC 28012 Phone: 980-875-6610 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Anne Pridgeon) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Anne Pridgeon Page 1 of 41 Reason: I have reviewed this document. Date: 2017.02.14 16:21:47 -05'00' Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2016040257 BELEWS 30-Jan-17 10:55 AM PSP CRW-2 2016040258 BELEWS 30-Jan-17 12:45 PM PSP CRW-3 2016040259 BELEWS 30-Jan-17 1:30 PM PSP CRW-4 2016040260 BELEWS 31-Jan-17 8:25 AM PSP CRW-5 2016040261 BELEWS 31-Jan-17 11:00 AM PSP CRW-6 2016040263 BELEWS 31-Jan-17 9:40 AM PSP CRW-8R 2016040264 BELEWS 31-Jan-17 10:20 AM PSP CRW-9 2016040265 BELEWS 31-Jan-17 8:50 AM LDC CRW-10 2016040266 BELEWS 31-Jan-17 9:45 AM LDC CRW-11 2016040267 BELEWS 30-Jan-17 8:30 AM LDC CRW-12 2016040268 BELEWS 30-Jan-17 9:55 AM LDC CRW-13 2016040269 BELEWS 30-Jan-17 11:05 AM LDC CRW-14 2016040270 BELEWS 30-Jan-17 11:45 AM LDC CRW-15 2016040271 BELEWS 30-Jan-17 9:15 AM PSP CRW-16 2016040272 BELEWS 31-Jan-17 10:30 AM LDC CRW-17 2016040273 BELEWS 30-Jan-17 12:50 PM LDC CWB-1 2016040274 BELEWS 30-Jan-17 12:20 PM LDC CWB-2 2016040276 BELEWS 31-Jan-17 9:10 AM LDC CRS-1 2016040277 BELEWS 31-Jan-17 10:40 AM PSP CRS-2 2016040279 BELEWS 30-Jan-17 11:45 AM PSP CRS-4 2016040280 BELEWS 31-Jan-17 8:50 AM PSP CRS-5 2016040281 BELEWS 31-Jan-17 11:15 AM LDC CRS-6 2016040284 BELEWS 31-Jan-17 11:30 AM PSP FIELD BLANK 23 Total Samples Page 2 of 41 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:DBA Account Date:2/10/2017 Electronic Data Deliverable (EDD) Sent Separatel Page 3 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040257 Collection Date:30-Jan-17 10:55 AM Site:CRW-2 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)14 mg/L (CaCO3) SM 2320B 02/01/2017 14:49 CJELLIO51 INORGANIC IONS BY IC Chloride 1.8 mg/L EPA 9056A 01/31/2017 08:37 BGN90340.2 2 Fluoride < 0.1 mg/L EPA 9056A 01/31/2017 08:37 BGN90340.1 1 Nitrate 0.32 mg/L EPA 9056A 01/31/2017 08:37 BGN90340.1 1 Nitrate as N 0.07 mg-N/L EPA 9056A 01/31/2017 08:37 BGN90340.023 1 Sulfate 0.34 mg/L EPA 9056A 01/31/2017 08:37 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/02/2017 14:45 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.049 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.05 1 Calcium (Ca)2.33 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.01 1 Chromium (Cr)0.007 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.005 1 Iron (Fe)1.11 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.01 1 Magnesium (Mg)1.26 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.005 1 Manganese (Mn)0.015 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.005 1 Potassium (K)2.64 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.1 1 Sodium (Na)3.16 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.05 1 Zinc (Zn)0.008 mg/L SW 6010D 02/01/2017 13:55 JJMACKE0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/02/2017 19:24 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 02/02/2017 19:24 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 02/02/2017 19:24 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 02/02/2017 19:24 CWSPEN311 Silver (Ag)< 1 ug/L SW 6020B 02/02/2017 19:24 CWSPEN311 TOTAL DISSOLVED SOLIDS TDS 54 mg/L SM2540C 02/02/2017 14:30 MGIGANT251 Page 4 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040258 Collection Date:30-Jan-17 12:45 PM Site:CRW-3 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)16 mg/L (CaCO3) SM 2320B 02/01/2017 14:49 CJELLIO51 INORGANIC IONS BY IC Chloride 3.8 mg/L EPA 9056A 01/31/2017 09:27 BGN90340.2 2 Fluoride < 0.1 mg/L EPA 9056A 01/31/2017 09:27 BGN90340.1 1 Nitrate 0.66 mg/L EPA 9056A 01/31/2017 09:27 BGN90340.1 1 Nitrate as N 0.15 mg-N/L EPA 9056A 01/31/2017 09:27 BGN90340.023 1 Sulfate 5.3 mg/L EPA 9056A 01/31/2017 09:27 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/02/2017 14:53 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.029 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.05 1 Calcium (Ca)3.82 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.01 1 Chromium (Cr)0.008 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.005 1 Iron (Fe)3.17 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.01 1 Magnesium (Mg)2.72 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.005 1 Manganese (Mn)0.059 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.005 1 Potassium (K)2.58 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.1 1 Sodium (Na)4.03 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.05 1 Zinc (Zn)0.012 mg/L SW 6010D 02/01/2017 14:06 JJMACKE0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/02/2017 19:03 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 02/02/2017 19:03 CWSPEN311 Lead (Pb)1.44 ug/L SW 6020B 02/02/2017 19:03 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 02/02/2017 19:03 CWSPEN311 Silver (Ag)< 1 ug/L SW 6020B 02/02/2017 19:03 CWSPEN311 TOTAL DISSOLVED SOLIDS TDS 89 mg/L SM2540C 02/02/2017 14:30 MGIGANT251 Page 5 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040259 Collection Date:30-Jan-17 1:30 PM Site:CRW-4 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)22 mg/L (CaCO3) SM 2320B 02/01/2017 08:49 CJELLIO201 INORGANIC IONS BY IC Chloride 2.4 mg/L EPA 9056A 01/31/2017 09:44 BGN90340.2 2 Fluoride < 0.1 mg/L EPA 9056A 01/31/2017 09:44 BGN90340.1 1 Nitrate 4.2 mg/L EPA 9056A 01/31/2017 09:44 BGN90340.1 1 Nitrate as N 0.95 mg-N/L EPA 9056A 01/31/2017 09:44 BGN90340.023 1 Sulfate 2.1 mg/L EPA 9056A 01/31/2017 09:44 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/02/2017 14:55 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.006 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.05 1 Calcium (Ca)4.69 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.01 1 Chromium (Cr)< 0.005 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.005 1 Iron (Fe)0.720 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.01 1 Magnesium (Mg)1.58 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.005 1 Manganese (Mn)0.011 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.005 1 Potassium (K)1.90 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.1 1 Sodium (Na)5.22 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.05 1 Zinc (Zn)< 0.005 mg/L SW 6010D 02/01/2017 14:10 JJMACKE0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/02/2017 19:32 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 02/02/2017 19:32 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 02/02/2017 19:32 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 02/02/2017 19:32 CWSPEN311 Silver (Ag)< 1 ug/L SW 6020B 02/02/2017 19:32 CWSPEN311 TOTAL DISSOLVED SOLIDS TDS 73 mg/L SM2540C 02/02/2017 14:30 MGIGANT251 Page 6 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040260 Collection Date:31-Jan-17 8:25 AM Site:CRW-5 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)27 mg/L (CaCO3) SM 2320B 02/01/2017 08:49 CJELLIO201 INORGANIC IONS BY IC Chloride 2.4 mg/L EPA 9056A 02/01/2017 12:24 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 12:24 BGN90340.1 1 Nitrate < 0.1 mg/L EPA 9056A 02/01/2017 12:24 BGN90340.1 1 Nitrate as N < 0.023 mg-N/L EPA 9056A 02/01/2017 12:24 BGN90340.023 1 Sulfate 13 mg/L EPA 9056A 02/01/2017 12:24 BGN90340.5 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/02/2017 14:58 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.014 mg/L SW 6010D 02/07/2017 10:48 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 10:48 MHH71310.05 1 Calcium (Ca)3.39 mg/L SW 6010D 02/07/2017 10:48 MHH71310.01 1 Chromium (Cr)< 0.005 mg/L SW 6010D 02/07/2017 10:48 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 10:48 MHH71310.005 1 Iron (Fe)6.95 mg/L SW 6010D 02/07/2017 10:48 MHH71310.01 1 Magnesium (Mg)2.80 mg/L SW 6010D 02/07/2017 10:48 MHH71310.005 1 Manganese (Mn)0.098 mg/L SW 6010D 02/07/2017 10:48 MHH71310.005 1 Nickel (Ni)0.012 mg/L SW 6010D 02/07/2017 10:48 MHH71310.005 1 Potassium (K)1.49 mg/L SW 6010D 02/07/2017 10:48 MHH71310.1 1 Sodium (Na)4.34 mg/L SW 6010D 02/07/2017 10:48 MHH71310.05 1 Zinc (Zn)0.017 mg/L SW 6010D 02/07/2017 10:48 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 20:35 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 20:35 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 20:35 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 20:35 PARMSTR11 Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 20:35 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 78 mg/L SM2540C 02/02/2017 14:30 MGIGANT251 Page 7 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040261 Collection Date:31-Jan-17 11:00 AM Site:CRW-6 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)< 5 mg/L (CaCO3) SM 2320B 02/01/2017 14:49 CJELLIO51 INORGANIC IONS BY IC Chloride 1.2 mg/L EPA 9056A 02/01/2017 12:41 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 12:41 BGN90340.1 1 Nitrate < 0.1 mg/L EPA 9056A 02/01/2017 12:41 BGN90340.1 1 Nitrate as N < 0.023 mg-N/L EPA 9056A 02/01/2017 12:41 BGN90340.023 1 Sulfate 22 mg/L EPA 9056A 02/01/2017 12:41 BGN90340.5 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/02/2017 15:00 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.035 mg/L SW 6010D 02/07/2017 11:00 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:00 MHH71310.05 1 Calcium (Ca)3.22 mg/L SW 6010D 02/07/2017 11:00 MHH71310.01 1 Chromium (Cr)0.005 mg/L SW 6010D 02/07/2017 11:00 MHH71310.005 1 Copper (Cu)0.005 mg/L SW 6010D 02/07/2017 11:00 MHH71310.005 1 Iron (Fe)2.89 mg/L SW 6010D 02/07/2017 11:00 MHH71310.01 1 Magnesium (Mg)2.87 mg/L SW 6010D 02/07/2017 11:00 MHH71310.005 1 Manganese (Mn)0.118 mg/L SW 6010D 02/07/2017 11:00 MHH71310.005 1 Nickel (Ni)0.020 mg/L SW 6010D 02/07/2017 11:00 MHH71310.005 1 Potassium (K)2.47 mg/L SW 6010D 02/07/2017 11:00 MHH71310.1 1 Sodium (Na)3.89 mg/L SW 6010D 02/07/2017 11:00 MHH71310.05 1 Zinc (Zn)0.022 mg/L SW 6010D 02/07/2017 11:00 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 19:41 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 19:41 PARMSTR11 Lead (Pb)1.63 ug/L SW 6020B 02/03/2017 19:41 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 19:41 PARMSTR11 Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 19:41 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 76 mg/L SM2540C 02/02/2017 14:30 MGIGANT251 Page 8 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040263 Collection Date:31-Jan-17 9:40 AM Site:CRW-8R Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)18 mg/L (CaCO3) SM 2320B 02/01/2017 14:49 CJELLIO51 INORGANIC IONS BY IC Chloride 4.4 mg/L EPA 9056A 02/01/2017 10:09 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 10:09 BGN90340.1 1 Nitrate 14 mg/L EPA 9056A 02/01/2017 10:09 BGN90340.5 5 Nitrate as N 3.1 mg-N/L EPA 9056A 02/01/2017 10:09 BGN90340.023 1 Sulfate 1.4 mg/L EPA 9056A 02/01/2017 10:09 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/02/2017 15:03 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.066 mg/L SW 6010D 02/07/2017 11:04 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:04 MHH71310.05 1 Calcium (Ca)6.91 mg/L SW 6010D 02/07/2017 11:04 MHH71310.01 1 Chromium (Cr)< 0.005 mg/L SW 6010D 02/07/2017 11:04 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 11:04 MHH71310.005 1 Iron (Fe)0.651 mg/L SW 6010D 02/07/2017 11:04 MHH71310.01 1 Magnesium (Mg)2.62 mg/L SW 6010D 02/07/2017 11:04 MHH71310.005 1 Manganese (Mn)0.011 mg/L SW 6010D 02/07/2017 11:04 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/07/2017 11:04 MHH71310.005 1 Potassium (K)2.61 mg/L SW 6010D 02/07/2017 11:04 MHH71310.1 1 Sodium (Na)4.82 mg/L SW 6010D 02/07/2017 11:04 MHH71310.05 1 Zinc (Zn)< 0.005 mg/L SW 6010D 02/07/2017 11:04 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 20:43 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 20:43 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 20:43 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 20:43 PARMSTR11 Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 20:43 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 90 mg/L SM2540C 02/02/2017 14:30 MGIGANT251 Page 9 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040264 Collection Date:31-Jan-17 10:20 AM Site:CRW-9 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)15 mg/L (CaCO3) SM 2320B 02/01/2017 14:49 CJELLIO51 INORGANIC IONS BY IC Chloride 2.3 mg/L EPA 9056A 02/01/2017 10:26 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 10:26 BGN90340.1 1 Nitrate 2.6 mg/L EPA 9056A 02/01/2017 10:26 BGN90340.1 1 Nitrate as N 0.60 mg-N/L EPA 9056A 02/01/2017 10:26 BGN90340.023 1 Sulfate 1.7 mg/L EPA 9056A 02/01/2017 10:26 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/02/2017 15:05 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.017 mg/L SW 6010D 02/07/2017 11:08 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:08 MHH71310.05 1 Calcium (Ca)4.00 mg/L SW 6010D 02/07/2017 11:08 MHH71310.01 1 Chromium (Cr)0.005 mg/L SW 6010D 02/07/2017 11:08 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 11:08 MHH71310.005 1 Iron (Fe)0.793 mg/L SW 6010D 02/07/2017 11:08 MHH71310.01 1 Magnesium (Mg)1.03 mg/L SW 6010D 02/07/2017 11:08 MHH71310.005 1 Manganese (Mn)0.011 mg/L SW 6010D 02/07/2017 11:08 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/07/2017 11:08 MHH71310.005 1 Potassium (K)2.16 mg/L SW 6010D 02/07/2017 11:08 MHH71310.1 1 Sodium (Na)3.40 mg/L SW 6010D 02/07/2017 11:08 MHH71310.05 1 Zinc (Zn)< 0.005 mg/L SW 6010D 02/07/2017 11:08 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 20:51 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 20:51 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 20:51 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 20:51 PARMSTR11 Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 20:51 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 55 mg/L SM2540C 02/02/2017 14:30 MGIGANT251 Page 10 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040265 Collection Date:31-Jan-17 8:50 AM Site:CRW-10 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)15 mg/L (CaCO3) SM 2320B 02/01/2017 14:49 CJELLIO51 INORGANIC IONS BY IC Chloride 14 mg/L EPA 9056A 02/01/2017 12:58 BGN9034110 Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 12:58 BGN90340.1 1 Nitrate 2.0 mg/L EPA 9056A 02/01/2017 12:58 BGN90340.1 1 Nitrate as N 0.45 mg-N/L EPA 9056A 02/01/2017 12:58 BGN90340.023 1 Sulfate 49 mg/L EPA 9056A 02/01/2017 12:58 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/02/2017 15:07 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.011 mg/L SW 6010D 02/07/2017 11:12 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:12 MHH71310.05 1 Calcium (Ca)16.9 mg/L SW 6010D 02/07/2017 11:12 MHH71310.01 1 Chromium (Cr)< 0.005 mg/L SW 6010D 02/07/2017 11:12 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 11:12 MHH71310.005 1 Iron (Fe)0.356 mg/L SW 6010D 02/07/2017 11:12 MHH71310.01 1 Magnesium (Mg)5.94 mg/L SW 6010D 02/07/2017 11:12 MHH71310.005 1 Manganese (Mn)0.029 mg/L SW 6010D 02/07/2017 11:12 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/07/2017 11:12 MHH71310.005 1 Potassium (K)3.49 mg/L SW 6010D 02/07/2017 11:12 MHH71310.1 1 Sodium (Na)7.22 mg/L SW 6010D 02/07/2017 11:12 MHH71310.05 1 Zinc (Zn)< 0.005 mg/L SW 6010D 02/07/2017 11:12 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 20:58 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 20:58 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 20:58 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 20:58 PARMSTR11 Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 20:58 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 140 mg/L SM2540C 02/02/2017 14:30 MGIGANT251 Page 11 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040266 Collection Date:31-Jan-17 9:45 AM Site:CRW-11 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)39 mg/L (CaCO3) SM 2320B 02/01/2017 08:49 CJELLIO201 INORGANIC IONS BY IC Chloride 4.6 mg/L EPA 9056A 02/01/2017 13:15 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 13:15 BGN90340.1 1 Nitrate 12 mg/L EPA 9056A 02/01/2017 13:15 BGN90340.5 5 Nitrate as N 2.8 mg-N/L EPA 9056A 02/01/2017 13:15 BGN90340.023 1 Sulfate 0.63 mg/L EPA 9056A 02/01/2017 13:15 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/02/2017 15:10 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.022 mg/L SW 6010D 02/07/2017 11:16 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:16 MHH71310.05 1 Calcium (Ca)10.9 mg/L SW 6010D 02/07/2017 11:16 MHH71310.01 1 Chromium (Cr)< 0.005 mg/L SW 6010D 02/07/2017 11:16 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 11:16 MHH71310.005 1 Iron (Fe)0.191 mg/L SW 6010D 02/07/2017 11:16 MHH71310.01 1 Magnesium (Mg)5.14 mg/L SW 6010D 02/07/2017 11:16 MHH71310.005 1 Manganese (Mn)< 0.005 mg/L SW 6010D 02/07/2017 11:16 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/07/2017 11:16 MHH71310.005 1 Potassium (K)1.48 mg/L SW 6010D 02/07/2017 11:16 MHH71310.1 1 Sodium (Na)4.82 mg/L SW 6010D 02/07/2017 11:16 MHH71310.05 1 Zinc (Zn)< 0.005 mg/L SW 6010D 02/07/2017 11:16 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 21:06 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 21:06 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 21:06 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 21:06 PARMSTR11 Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 21:06 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 94 mg/L SM2540C 02/02/2017 14:30 MGIGANT251 Page 12 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040267 Collection Date:30-Jan-17 8:30 AM Site:CRW-12 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)21 mg/L (CaCO3) SM 2320B 02/01/2017 08:49 CJELLIO201 INORGANIC IONS BY IC Chloride 2.0 mg/L EPA 9056A 01/31/2017 10:01 BGN90340.2 2 Fluoride < 0.1 mg/L EPA 9056A 01/31/2017 10:01 BGN90340.1 1 Nitrate 1.2 mg/L EPA 9056A 01/31/2017 10:01 BGN90340.1 1 Nitrate as N 0.27 mg-N/L EPA 9056A 01/31/2017 10:01 BGN90340.023 1 Sulfate 0.16 mg/L EPA 9056A 01/31/2017 10:01 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/02/2017 15:12 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.022 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.05 1 Calcium (Ca)3.88 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.01 1 Chromium (Cr)< 0.005 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.005 1 Iron (Fe)0.358 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.01 1 Magnesium (Mg)1.39 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.005 1 Manganese (Mn)0.010 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.005 1 Potassium (K)2.08 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.1 1 Sodium (Na)4.73 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.05 1 Zinc (Zn)< 0.005 mg/L SW 6010D 02/01/2017 14:14 JJMACKE0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 17:30 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 17:30 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 17:30 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 17:30 CWSPEN311 Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 17:30 CWSPEN311 TOTAL DISSOLVED SOLIDS TDS 60 mg/L SM2540C 02/02/2017 14:30 MGIGANT251 Page 13 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040268 Collection Date:30-Jan-17 9:55 AM Site:CRW-13 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)38 mg/L (CaCO3) SM 2320B 02/01/2017 08:49 CJELLIO201 INORGANIC IONS BY IC Chloride 15 mg/L EPA 9056A 01/31/2017 12:00 BGN90340.5 5 Fluoride < 0.1 mg/L EPA 9056A 01/31/2017 12:00 BGN90340.1 1 Nitrate 8.5 mg/L EPA 9056A 01/31/2017 12:00 BGN90340.1 1 Nitrate as N 1.9 mg-N/L EPA 9056A 01/31/2017 12:00 BGN90340.023 1 Sulfate 1.1 mg/L EPA 9056A 01/31/2017 12:00 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 13:13 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.019 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.05 1 Calcium (Ca)12.9 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.01 1 Chromium (Cr)< 0.005 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.005 1 Iron (Fe)0.326 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.01 1 Magnesium (Mg)6.92 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.005 1 Manganese (Mn)0.007 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.005 1 Potassium (K)1.70 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.1 1 Sodium (Na)5.42 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.05 1 Zinc (Zn)< 0.005 mg/L SW 6010D 02/01/2017 14:18 JJMACKE0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 17:37 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 17:37 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 17:37 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 17:37 CWSPEN311 Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 17:37 CWSPEN311 TOTAL DISSOLVED SOLIDS TDS 110 mg/L SM2540C 02/02/2017 14:30 MGIGANT251 Page 14 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040269 Collection Date:30-Jan-17 11:05 AM Site:CRW-14 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)38 mg/L (CaCO3) SM 2320B 02/01/2017 08:49 CJELLIO201 INORGANIC IONS BY IC Chloride 29 mg/L EPA 9056A 01/31/2017 12:16 BGN90340.5 5 Fluoride 0.23 mg/L EPA 9056A 01/31/2017 12:16 BGN90340.1 1 Nitrate 19 mg/L EPA 9056A 01/31/2017 12:16 BGN90340.5 5 Nitrate as N 4.3 mg-N/L EPA 9056A 01/31/2017 12:16 BGN90340.023 1 Sulfate 23 mg/L EPA 9056A 01/31/2017 12:16 BGN90340.5 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 13:20 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.038 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.05 1 Calcium (Ca)18.9 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.01 1 Chromium (Cr)< 0.005 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.005 1 Iron (Fe)0.187 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.01 1 Magnesium (Mg)6.43 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.005 1 Manganese (Mn)0.016 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.005 1 Potassium (K)3.71 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.1 1 Sodium (Na)21.2 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.05 1 Zinc (Zn)0.005 mg/L SW 6010D 02/01/2017 14:21 JJMACKE0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 17:44 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 17:44 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 17:44 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 17:44 CWSPEN311 Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 17:44 CWSPEN311 TOTAL DISSOLVED SOLIDS TDS 190 mg/L SM2540C 02/02/2017 14:30 MGIGANT251 Page 15 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040270 Collection Date:30-Jan-17 11:45 AM Site:CRW-15 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)22 mg/L (CaCO3) SM 2320B 02/01/2017 08:49 CJELLIO201 INORGANIC IONS BY IC Chloride 10 mg/L EPA 9056A 01/31/2017 12:33 BGN90340.5 5 Fluoride < 0.1 mg/L EPA 9056A 01/31/2017 12:33 BGN90340.1 1 Nitrate 0.40 mg/L EPA 9056A 01/31/2017 12:33 BGN90340.1 1 Nitrate as N 0.09 mg-N/L EPA 9056A 01/31/2017 12:33 BGN90340.023 1 Sulfate 2.9 mg/L EPA 9056A 01/31/2017 12:33 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 13:23 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.010 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.05 1 Calcium (Ca)6.24 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.01 1 Chromium (Cr)< 0.005 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.005 1 Iron (Fe)0.048 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.01 1 Magnesium (Mg)2.90 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.005 1 Manganese (Mn)0.007 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.005 1 Potassium (K)2.87 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.1 1 Sodium (Na)5.66 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.05 1 Zinc (Zn)0.012 mg/L SW 6010D 02/01/2017 14:37 JJMACKE0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 17:52 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 17:52 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 17:52 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 17:52 CWSPEN311 Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 17:52 CWSPEN311 TOTAL DISSOLVED SOLIDS TDS 71 mg/L SM2540C 02/02/2017 14:30 MGIGANT251 Page 16 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040271 Collection Date:30-Jan-17 9:15 AM Site:CRW-16 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)24 mg/L (CaCO3) SM 2320B 02/01/2017 08:49 CJELLIO201 INORGANIC IONS BY IC Chloride 4.9 mg/L EPA 9056A 01/31/2017 11:09 BGN90340.2 2 Fluoride < 0.1 mg/L EPA 9056A 01/31/2017 11:09 BGN90340.1 1 Nitrate 0.36 mg/L EPA 9056A 01/31/2017 11:09 BGN90340.1 1 Nitrate as N 0.08 mg-N/L EPA 9056A 01/31/2017 11:09 BGN90340.023 1 Sulfate 1.3 mg/L EPA 9056A 01/31/2017 11:09 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 13:25 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.027 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.05 1 Calcium (Ca)5.25 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.01 1 Chromium (Cr)< 0.005 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.005 1 Iron (Fe)0.369 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.01 1 Magnesium (Mg)1.45 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.005 1 Manganese (Mn)0.011 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.005 1 Potassium (K)2.01 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.1 1 Sodium (Na)6.27 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.05 1 Zinc (Zn)< 0.005 mg/L SW 6010D 02/01/2017 14:40 JJMACKE0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 17:59 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 17:59 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 17:59 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 17:59 CWSPEN311 Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 17:59 CWSPEN311 TOTAL DISSOLVED SOLIDS TDS 65 mg/L SM2540C 02/02/2017 14:30 MGIGANT251 Page 17 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040272 Collection Date:31-Jan-17 10:30 AM Site:CRW-17 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)19 mg/L (CaCO3) SM 2320B 02/01/2017 14:49 CJELLIO51 INORGANIC IONS BY IC Chloride 2.1 mg/L EPA 9056A 02/01/2017 11:17 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 11:17 BGN90340.1 1 Nitrate 0.14 mg/L EPA 9056A 02/01/2017 11:17 BGN90340.1 1 Nitrate as N 0.03 mg-N/L EPA 9056A 02/01/2017 11:17 BGN90340.023 1 Sulfate 0.25 mg/L EPA 9056A 02/01/2017 11:17 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 13:28 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.051 mg/L SW 6010D 02/07/2017 11:20 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:20 MHH71310.05 1 Calcium (Ca)1.26 mg/L SW 6010D 02/07/2017 11:20 MHH71310.01 1 Chromium (Cr)< 0.005 mg/L SW 6010D 02/07/2017 11:20 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 11:20 MHH71310.005 1 Iron (Fe)0.404 mg/L SW 6010D 02/07/2017 11:20 MHH71310.01 1 Magnesium (Mg)0.576 mg/L SW 6010D 02/07/2017 11:20 MHH71310.005 1 Manganese (Mn)0.010 mg/L SW 6010D 02/07/2017 11:20 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/07/2017 11:20 MHH71310.005 1 Potassium (K)2.12 mg/L SW 6010D 02/07/2017 11:20 MHH71310.1 1 Sodium (Na)16.7 mg/L SW 6010D 02/07/2017 11:20 MHH71310.05 1 Zinc (Zn)< 0.005 mg/L SW 6010D 02/07/2017 11:20 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 21:14 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 21:14 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 21:14 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 21:14 PARMSTR11 Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 21:14 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 52 mg/L SM2540C 02/02/2017 14:30 MGIGANT251 Page 18 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040273 Collection Date:30-Jan-17 12:50 PM Site:CWB-1 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)< 5 mg/L (CaCO3) SM 2320B 02/01/2017 14:49 CJELLIO51 INORGANIC IONS BY IC Chloride 430 mg/L EPA 9056A 01/31/2017 12:50 BGN9034550 Fluoride < 5 mg/L EPA 9056A 01/31/2017 12:50 BGN9034550 Nitrate 120 mg/L EPA 9056A 01/31/2017 12:50 BGN9034550 Nitrate as N 27 mg-N/L EPA 9056A 01/31/2017 12:50 BGN90340.023 1 Sulfate 2200 mg/L EPA 9056A 01/31/2017 12:50 BGN903450500 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 13:30 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.029 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.005 1 Boron (B)38.1 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.5 10 Calcium (Ca)524 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.1 10 Chromium (Cr)< 0.005 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.005 1 Iron (Fe)0.014 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.01 1 Magnesium (Mg)149 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.05 10 Manganese (Mn)19.0 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.005 1 Nickel (Ni)0.106 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.005 1 Potassium (K)82.5 mg/L SW 6010D 02/01/2017 14:57 JJMACKE110 Sodium (Na)189 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.5 10 Zinc (Zn)0.242 mg/L SW 6010D 02/01/2017 14:57 JJMACKE0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)29.4 ug/L SW 6020B 02/03/2017 18:06 CWSPEN311 Cadmium (Cd)3.79 ug/L SW 6020B 02/03/2017 18:06 CWSPEN311 Lead (Pb)5.71 ug/L SW 6020B 02/03/2017 18:06 CWSPEN311 Selenium (Se)104 ug/L SW 6020B 02/03/2017 18:06 CWSPEN311 Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 18:06 CWSPEN311 TOTAL DISSOLVED SOLIDS TDS 3100 mg/L SM2540C 02/02/2017 14:30 MGIGANT5001 Page 19 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040274 Collection Date:30-Jan-17 12:20 PM Site:CWB-2 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)< 20 mg/L (CaCO3) SM 2320B 02/01/2017 08:49 CJELLIO201 INORGANIC IONS BY IC Chloride 320 mg/L EPA 9056A 01/31/2017 13:07 BGN903410100 Fluoride < 10 mg/L EPA 9056A 01/31/2017 13:07 BGN903410100 Nitrate 170 mg/L EPA 9056A 01/31/2017 13:07 BGN903410100 Nitrate as N 37 mg-N/L EPA 9056A 01/31/2017 13:07 BGN90340.023 1 Sulfate 4200 mg/L EPA 9056A 01/31/2017 13:07 BGN90341001000 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 13:32 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.025 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.005 1 Boron (B)73.1 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.5 10 Calcium (Ca)421 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.1 10 Chromium (Cr)< 0.005 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.005 1 Copper (Cu)0.006 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.005 1 Iron (Fe)0.042 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.01 1 Magnesium (Mg)359 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.5 100 Manganese (Mn)19.2 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.005 1 Nickel (Ni)0.240 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.005 1 Potassium (K)189 mg/L SW 6010D 02/01/2017 15:13 JJMACKE110 Sodium (Na)298 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.5 10 Zinc (Zn)0.555 mg/L SW 6010D 02/01/2017 15:13 JJMACKE0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)40.5 ug/L SW 6020B 02/03/2017 18:13 CWSPEN311 Cadmium (Cd)7.25 ug/L SW 6020B 02/03/2017 18:13 CWSPEN311 Lead (Pb)11.1 ug/L SW 6020B 02/03/2017 18:13 CWSPEN311 Selenium (Se)191 ug/L SW 6020B 02/03/2017 18:13 CWSPEN311 Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 18:13 CWSPEN311 TOTAL DISSOLVED SOLIDS TDS 3800 mg/L SM2540C 02/02/2017 14:30 MGIGANT5001 Page 20 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040276 Collection Date:31-Jan-17 9:10 AM Site:CRS-1 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)26 mg/L (CaCO3) SM 2320B 02/01/2017 08:49 CJELLIO201 INORGANIC IONS BY IC Chloride 8.4 mg/L EPA 9056A 02/01/2017 11:34 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 11:34 BGN90340.1 1 Nitrate 0.60 mg/L EPA 9056A 02/01/2017 11:34 BGN90340.1 1 Nitrate as N 0.14 mg-N/L EPA 9056A 02/01/2017 11:34 BGN90340.023 1 Sulfate 9.0 mg/L EPA 9056A 02/01/2017 11:34 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 13:35 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.026 mg/L SW 6010D 02/07/2017 11:24 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:24 MHH71310.05 1 Calcium (Ca)8.63 mg/L SW 6010D 02/07/2017 11:24 MHH71310.01 1 Chromium (Cr)< 0.005 mg/L SW 6010D 02/07/2017 11:24 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 11:24 MHH71310.005 1 Iron (Fe)0.281 mg/L SW 6010D 02/07/2017 11:24 MHH71310.01 1 Magnesium (Mg)3.76 mg/L SW 6010D 02/07/2017 11:24 MHH71310.005 1 Manganese (Mn)0.034 mg/L SW 6010D 02/07/2017 11:24 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/07/2017 11:24 MHH71310.005 1 Potassium (K)1.88 mg/L SW 6010D 02/07/2017 11:24 MHH71310.1 1 Sodium (Na)5.66 mg/L SW 6010D 02/07/2017 11:24 MHH71310.05 1 Zinc (Zn)< 0.005 mg/L SW 6010D 02/07/2017 11:24 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 21:22 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 21:22 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 21:22 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 21:22 PARMSTR11 Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 21:22 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 92 mg/L SM2540C 02/02/2017 14:30 MGIGANT251 Page 21 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040277 Collection Date:31-Jan-17 10:40 AM Site:CRS-2 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)22 mg/L (CaCO3) SM 2320B 02/01/2017 08:49 CJELLIO201 INORGANIC IONS BY IC Chloride 8.4 mg/L EPA 9056A 02/01/2017 13:31 BGN90340.5 5 Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 13:31 BGN90340.1 1 Nitrate 0.27 mg/L EPA 9056A 02/01/2017 13:31 BGN90340.1 1 Nitrate as N 0.06 mg-N/L EPA 9056A 02/01/2017 13:31 BGN90340.023 1 Sulfate 16 mg/L EPA 9056A 02/01/2017 13:31 BGN90340.5 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 13:37 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.022 mg/L SW 6010D 02/07/2017 11:29 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:29 MHH71310.05 1 Calcium (Ca)9.18 mg/L SW 6010D 02/07/2017 11:29 MHH71310.01 1 Chromium (Cr)< 0.005 mg/L SW 6010D 02/07/2017 11:29 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 11:29 MHH71310.005 1 Iron (Fe)0.834 mg/L SW 6010D 02/07/2017 11:29 MHH71310.01 1 Magnesium (Mg)3.56 mg/L SW 6010D 02/07/2017 11:29 MHH71310.005 1 Manganese (Mn)0.092 mg/L SW 6010D 02/07/2017 11:29 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/07/2017 11:29 MHH71310.005 1 Potassium (K)1.97 mg/L SW 6010D 02/07/2017 11:29 MHH71310.1 1 Sodium (Na)5.44 mg/L SW 6010D 02/07/2017 11:29 MHH71310.05 1 Zinc (Zn)< 0.005 mg/L SW 6010D 02/07/2017 11:29 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 21:29 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 21:29 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 21:29 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 21:29 PARMSTR11 Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 21:29 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 88 mg/L SM2540C 02/02/2017 14:30 MGIGANT251 Page 22 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040279 Collection Date:30-Jan-17 11:45 AM Site:CRS-4 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)20 mg/L (CaCO3) SM 2320B 02/01/2017 14:49 CJELLIO51 INORGANIC IONS BY IC Chloride 5.4 mg/L EPA 9056A 01/31/2017 16:30 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 01/31/2017 16:30 BGN90340.1 1 Nitrate 2.0 mg/L EPA 9056A 01/31/2017 16:30 BGN90340.1 1 Nitrate as N 0.45 mg-N/L EPA 9056A 01/31/2017 16:30 BGN90340.023 1 Sulfate 17 mg/L EPA 9056A 01/31/2017 16:30 BGN90340.5 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 13:40 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.014 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.005 1 Boron (B)0.070 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.05 1 Calcium (Ca)8.78 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.01 1 Chromium (Cr)< 0.005 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.005 1 Iron (Fe)0.578 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.01 1 Magnesium (Mg)3.20 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.005 1 Manganese (Mn)0.038 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.005 1 Potassium (K)2.46 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.1 1 Sodium (Na)5.60 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.05 1 Zinc (Zn)0.007 mg/L SW 6010D 02/01/2017 14:52 JJMACKE0.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 18:42 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 18:42 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 18:42 CWSPEN311 Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 18:42 CWSPEN311 Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 18:42 CWSPEN311 TOTAL DISSOLVED SOLIDS TDS 95 mg/L SM2540C 02/02/2017 14:30 MGIGANT251 Page 23 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040280 Collection Date:31-Jan-17 8:50 AM Site:CRS-5 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)17 mg/L (CaCO3) SM 2320B 02/01/2017 14:49 CJELLIO51 INORGANIC IONS BY IC Chloride 4.2 mg/L EPA 9056A 02/01/2017 12:07 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 12:07 BGN90340.1 1 Nitrate < 0.1 mg/L EPA 9056A 02/01/2017 12:07 BGN90340.1 1 Nitrate as N < 0.023 mg-N/L EPA 9056A 02/01/2017 12:07 BGN90340.023 1 Sulfate 10 mg/L EPA 9056A 02/01/2017 12:07 BGN90340.5 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 14:59 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.036 mg/L SW 6010D 02/07/2017 11:33 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:33 MHH71310.05 1 Calcium (Ca)3.91 mg/L SW 6010D 02/07/2017 11:33 MHH71310.01 1 Chromium (Cr)< 0.005 mg/L SW 6010D 02/07/2017 11:33 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 11:33 MHH71310.005 1 Iron (Fe)5.87 mg/L SW 6010D 02/07/2017 11:33 MHH71310.01 1 Magnesium (Mg)2.46 mg/L SW 6010D 02/07/2017 11:33 MHH71310.005 1 Manganese (Mn)0.264 mg/L SW 6010D 02/07/2017 11:33 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/07/2017 11:33 MHH71310.005 1 Potassium (K)2.05 mg/L SW 6010D 02/07/2017 11:33 MHH71310.1 1 Sodium (Na)3.91 mg/L SW 6010D 02/07/2017 11:33 MHH71310.05 1 Zinc (Zn)0.013 mg/L SW 6010D 02/07/2017 11:33 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 21:37 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 21:37 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 21:37 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 21:37 PARMSTR11 Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 21:37 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 57 mg/L SM2540C 02/02/2017 14:30 MGIGANT251 Page 24 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040281 Collection Date:31-Jan-17 11:15 AM Site:CRS-6 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)28 mg/L (CaCO3) SM 2320B 02/01/2017 08:49 CJELLIO201 INORGANIC IONS BY IC Chloride 6.6 mg/L EPA 9056A 02/01/2017 15:31 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 15:31 BGN90340.1 1 Nitrate 1.9 mg/L EPA 9056A 02/01/2017 15:31 BGN90340.1 1 Nitrate as N 0.42 mg-N/L EPA 9056A 02/01/2017 15:31 BGN90340.023 1 Sulfate 5.7 mg/L EPA 9056A 02/01/2017 15:31 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 15:02 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.034 mg/L SW 6010D 02/07/2017 11:49 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:49 MHH71310.05 1 Calcium (Ca)7.10 mg/L SW 6010D 02/07/2017 11:49 MHH71310.01 1 Chromium (Cr)< 0.005 mg/L SW 6010D 02/07/2017 11:49 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 11:49 MHH71310.005 1 Iron (Fe)0.644 mg/L SW 6010D 02/07/2017 11:49 MHH71310.01 1 Magnesium (Mg)3.66 mg/L SW 6010D 02/07/2017 11:49 MHH71310.005 1 Manganese (Mn)0.364 mg/L SW 6010D 02/07/2017 11:49 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/07/2017 11:49 MHH71310.005 1 Potassium (K)1.67 mg/L SW 6010D 02/07/2017 11:49 MHH71310.1 1 Sodium (Na)5.01 mg/L SW 6010D 02/07/2017 11:49 MHH71310.05 1 Zinc (Zn)< 0.005 mg/L SW 6010D 02/07/2017 11:49 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 22:08 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 22:08 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 22:08 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 22:08 PARMSTR11 Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 22:08 PARMSTR11 TOTAL DISSOLVED SOLIDS TDS 64 mg/L SM2540C 02/02/2017 14:30 MGIGANT251 Page 25 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 2016040284 Collection Date:31-Jan-17 11:30 AM Site:FIELD BLANK Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)< 20 mg/L (CaCO3) SM 2320B 02/01/2017 08:49 CJELLIO201 INORGANIC IONS BY IC Chloride < 0.1 mg/L EPA 9056A 02/01/2017 15:48 BGN90340.1 1 Fluoride < 0.1 mg/L EPA 9056A 02/01/2017 15:48 BGN90340.1 1 Nitrate < 0.1 mg/L EPA 9056A 02/01/2017 15:48 BGN90340.1 1 Nitrate as N < 0.023 mg-N/L EPA 9056A 02/01/2017 15:48 BGN90340.023 1 Sulfate < 0.1 mg/L EPA 9056A 02/01/2017 15:48 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 7470A 02/07/2017 15:04 DMFRANC0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)< 0.005 mg/L SW 6010D 02/07/2017 11:53 MHH71310.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/07/2017 11:53 MHH71310.05 1 Calcium (Ca)< 0.01 mg/L SW 6010D 02/07/2017 11:53 MHH71310.01 1 Chromium (Cr)< 0.005 mg/L SW 6010D 02/07/2017 11:53 MHH71310.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/07/2017 11:53 MHH71310.005 1 Iron (Fe)< 0.01 mg/L SW 6010D 02/07/2017 11:53 MHH71310.01 1 Magnesium (Mg)< 0.005 mg/L SW 6010D 02/07/2017 11:53 MHH71310.005 1 Manganese (Mn)< 0.005 mg/L SW 6010D 02/07/2017 11:53 MHH71310.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/07/2017 11:53 MHH71310.005 1 Potassium (K)< 0.1 mg/L SW 6010D 02/07/2017 11:53 MHH71310.1 1 Sodium (Na)< 0.05 mg/L SW 6010D 02/07/2017 11:53 MHH71310.05 1 Zinc (Zn)< 0.005 mg/L SW 6010D 02/07/2017 11:53 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/03/2017 22:15 PARMSTR11 Cadmium (Cd)< 1 ug/L SW 6020B 02/03/2017 22:15 PARMSTR11 Lead (Pb)< 1 ug/L SW 6020B 02/03/2017 22:15 PARMSTR11 Selenium (Se)< 1 ug/L SW 6020B 02/03/2017 22:15 PARMSTR11 Silver (Ag)< 1 ug/L SW 6020B 02/03/2017 22:15 PARMSTR11 Page 26 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 Q17020024 ALK_FIX4.5 ALKALINITY (FIXED END POINT 4.5) Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Duplicate # 1 RPD Parent Sample: J16120415 -- 2016040259 Alkalinity (mg/L CaCO3)5.52mg/L (CaCO3)-120.7 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Alkalinity (mg/L CaCO3) 52.5 88.3mg/L (CaCO3)-12080146.4 Page 27 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 Q17020036 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT) Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Duplicate # 1 RPD Parent Sample: J16120415 -- 2016040257 Alkalinity (mg/L CaCO3)5.86mg/L (CaCO3)-115.3 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Alkalinity (mg/L CaCO3) 26.25 85.9mg/L (CaCO3)-12080122.6 Page 28 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 Q17010649 Dionex INORGANIC IONS BY IC Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Chloride 0.032 mg/L -10.032 0.1 < 1/2 RDL Fluoride 0.0142 mg/L -10.0142 0.1 < 1/2 RDL Nitrate 0.0366 mg/L -10.0366 0.1 < 1/2 RDL Sulfate -0.0233 mg/L -1-0.0233 0.1 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter IS # 1 % Recovery LCL UCLSpike Chloride 6.24 10 107mg/L -12080212.5 Fluoride 4.74 10 94.2mg/L -1208029.48 Nitrate 5.37 10 104mg/L -12080210.7 Sulfate 5.41 10 105mg/L -12080210.8 Final QualifierDilMeasuredUnits:Parameter ISD # 1 RPD% Recovery LCL UCLSpike Chloride 6.25 10 107 0.243mg/L -12080212.5 Fluoride 4.76 10 94.5 3.41mg/L -1208029.51 Nitrate 5.4 10 104 0.559mg/L -12080210.8 Sulfate 5.41 10 105 0.133mg/L -12080210.8 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Chloride 4.93 5 98.6mg/L -1208014.93 Fluoride 5.21 5 104mg/L -1208015.21 Nitrate 4.87 5 97.4mg/L -1208014.87 Sulfate 4.88 5 97.7mg/L -1208014.88 Page 29 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 Q17020003 Dionex INORGANIC IONS BY IC Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Chloride 0.0259 mg/L -10.0259 0.1 < 1/2 RDL Fluoride 0.0121 mg/L -10.0121 0.1 < 1/2 RDL Nitrate 0.04 mg/L -10.04 0.1 < 1/2 RDL Sulfate -0.016 mg/L -1-0.016 0.1 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter IS # 1 % Recovery LCL UCLSpike Chloride 5.45 25 99.1mg/L -12080527.3 Fluoride 4.9 25 97.6mg/L -12080524.5 Nitrate 4.82 25 95.6mg/L -12080524.1 Sulfate 7.38 25 95.2mg/L -12080536.9 Final QualifierDilMeasuredUnits:Parameter ISD # 1 RPD% Recovery LCL UCLSpike Chloride 5.48 25 99.6 0.493mg/L -12080527.4 Fluoride 4.91 25 97.8 0.196mg/L -12080524.6 Nitrate 4.84 25 96.1 0.53mg/L -12080524.2 Sulfate 7.39 25 95.5 0.264mg/L -12080537 Final QualifierDilMeasuredUnits:Parameter IS # 2 % Recovery LCL UCLSpike Chloride 8.82 50 108mg/L -120801088.2 Fluoride 4.85 50 96.7mg/L -120801048.5 Nitrate 50mg/L -120801Not Tested Sulfate 5.14 50 99.7mg/L -120801051.4 Final QualifierDilMeasuredUnits:Parameter ISD # 2 RPD% Recovery LCL UCLSpike Chloride 8.78 50 107 0.72mg/L -120801087.8 Fluoride 4.96 50 98.9 2.24mg/L -120801049.6 Nitrate 50mg/L -120801Not Tested Sulfate 5.16 50 100 0.311mg/L -120801051.6 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Chloride 4.86 5 97.2mg/L -1109014.86 Fluoride 5.04 5 101mg/L -1109015.04 Nitrate 4.83 5 96.6mg/L -1109014.83 Sulfate 4.82 5 96.3mg/L -1109014.82 Page 30 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 Q17020098 HG 7470 MERCURY (COLD VAPOR) IN WATER Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Mercury (Hg) -0.004 ug/L -1-0.004 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 2 RDL Relative Concentration Mercury (Hg) 0.002 ug/L -10.002 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Mercury (Hg) 2 2 100ug/L -1158512 Final QualifierDilMeasuredUnits:Parameter LCS # 2 % Recovery LCL UCLSpike Mercury (Hg) 2 2 100ug/L -1158512 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J17010464 -- 2017002045 Mercury (Hg) 0.938 1 93.1ug/L -1257510.938 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J17010464 -- 2017002045 Mercury (Hg) 0.941 1 93.4 0.322ug/L -1257510.941 Final QualifierDilMeasuredUnits:Parameter MS # 2 % Recovery LCL UCLSpike Parent Sample: J16120415 -- 2016040257 Mercury (Hg) 1.01 1 100ug/L -1257511.01 Final QualifierDilMeasuredUnits:Parameter MSD # 2 RPD% Recovery LCL UCLSpike Parent Sample: J16120415 -- 2016040257 Mercury (Hg) 1.01 1 100 0.0999ug/L -1257511.01 Page 31 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 Q17020187 HG 7470 MERCURY (COLD VAPOR) IN WATER Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Mercury (Hg) 0.01 ug/L -10.01 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 2 RDL Relative Concentration Mercury (Hg) 0.022 ug/L -10.022 0.05 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Mercury (Hg) 2.02 2 101ug/L -1158512.02 Final QualifierDilMeasuredUnits:Parameter LCS # 2 % Recovery LCL UCLSpike Mercury (Hg) 1.93 2 96.6ug/L -1158511.93 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J16120415 -- 2016040268 Mercury (Hg) 1.02 1 102ug/L -1257511.02 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J16120415 -- 2016040268 Mercury (Hg) 1 1 99.6 2.48ug/L -1257511 Final QualifierDilMeasuredUnits:Parameter MS # 2 % Recovery LCL UCLSpike Parent Sample: J17020101 -- 2017003805 Mercury (Hg) 1 1 95.2ug/L -1257511 Final QualifierDilMeasuredUnits:Parameter MSD # 2 RPD% Recovery LCL UCLSpike Parent Sample: J17020101 -- 2017003805 Mercury (Hg) 1.02 1 97.1 1.98ug/L -1257511.02 Page 32 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 Q17010658 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Barium (Ba) 0.000166 mg/L -10.000166 0.005 < 1/2 RDL Boron (B) -0.00162 mg/L -1-0.00162 0.05 < 1/2 RDL Calcium (Ca) 0.00175 mg/L -10.00175 0.01 < 1/2 RDL Chromium (Cr) 0.000615 mg/L -10.000615 0.005 < 1/2 RDL Copper (Cu) -0.000461 mg/L -1-0.000461 0.005 < 1/2 RDL Iron (Fe) 0.000682 mg/L -10.000682 0.01 < 1/2 RDL Magnesium (Mg) 0.00173 mg/L -10.00173 0.005 < 1/2 RDL Manganese (Mn) 0.00031 mg/L -10.00031 0.005 < 1/2 RDL Nickel (Ni) -0.000288 mg/L -1-0.000288 0.005 < 1/2 RDL Potassium (K) 0.00382 mg/L -10.00382 0.1 < 1/2 RDL Sodium (Na) -0.0085 mg/L -1-0.0085 0.05 < 1/2 RDL Zinc (Zn) 0.000345 mg/L -10.000345 0.005 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Barium (Ba) 5.24 5 105mg/L -1208015.24 Boron (B) 5.03 5 101mg/L -1208015.03 Calcium (Ca) 4.93 5 98.6mg/L -1208014.93 Chromium (Cr) 5.1 5 102mg/L -1208015.1 Copper (Cu) 5.07 5 101mg/L -1208015.07 Iron (Fe) 5.03 5 101mg/L -1208015.03 Magnesium (Mg) 5.17 5 103mg/L -1208015.17 Manganese (Mn) 5.29 5 106mg/L -1208015.29 Nickel (Ni) 5 5 100mg/L -1208015 Potassium (K) 5.09 5 102mg/L -1208015.09 Sodium (Na) 4.99 5 99.8mg/L -1208014.99 Zinc (Zn) 5.16 5 103mg/L -1208015.16 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J16120415 -- 2016040257 Barium (Ba) 5.74 5 114mg/L -1257515.74 Boron (B) 5.41 5 108mg/L -1257515.41 Calcium (Ca) 7.92 5 112mg/L -1257517.92 Chromium (Cr) 5.48 5 110mg/L -1257515.48 Copper (Cu) 5.44 5 109mg/L -1257515.44 Iron (Fe) 6.64 5 111mg/L -1257516.64 Magnesium (Mg) 7.03 5 115mg/L -1257517.03 Manganese (Mn) 5.7 5 114mg/L -1257515.7 Nickel (Ni) 5.4 5 108mg/L -1257515.4 Potassium (K) 8.31 5 113mg/L -1257518.31 Page 33 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 Q17010658 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J16120415 -- 2016040257 Sodium (Na) 8.87 5 114mg/L -1257518.87 Zinc (Zn) 5.53 5 111mg/L -1257515.53 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J16120415 -- 2016040257 Barium (Ba) 5.32 5 105 7.83mg/L -1257515.32 Boron (B) 5.04 5 101 6.97mg/L -1257515.04 Calcium (Ca) 7.42 5 102 9.45mg/L -1257517.42 Chromium (Cr) 5.13 5 102 6.66mg/L -1257515.13 Copper (Cu) 5.08 5 102 6.82mg/L -1257515.08 Iron (Fe) 6.2 5 102 8.23mg/L -1257516.2 Magnesium (Mg) 6.51 5 105 9.26mg/L -1257516.51 Manganese (Mn) 5.34 5 106 6.67mg/L -1257515.34 Nickel (Ni) 5.04 5 101 6.84mg/L -1257515.04 Potassium (K) 7.77 5 103 10mg/L -1257517.77 Sodium (Na) 8.29 5 103 10.6mg/L -1257518.29 Zinc (Zn) 5.19 5 104 6.39mg/L -1257515.19 Page 34 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 Q17020043 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Barium (Ba) -0.000134 mg/L -1-0.000134 0.005 < 1/2 RDL Boron (B) 0.00132 mg/L -10.00132 0.05 < 1/2 RDL Calcium (Ca) 0.00181 mg/L -10.00181 0.01 < 1/2 RDL Chromium (Cr) 0.000114 mg/L -10.000114 0.005 < 1/2 RDL Copper (Cu) -0.000396 mg/L -1-0.000396 0.005 < 1/2 RDL Iron (Fe) 0.000913 mg/L -10.000913 0.01 < 1/2 RDL Magnesium (Mg) 0.000959 mg/L -10.000959 0.005 < 1/2 RDL Manganese (Mn) -0.000009 mg/L -1-0.000009 0.005 < 1/2 RDL Nickel (Ni) -0.000075 mg/L -1-0.000075 0.005 < 1/2 RDL Potassium (K) 0.000568 mg/L -10.000568 0.1 < 1/2 RDL Sodium (Na) -0.00168 mg/L -1-0.00168 0.05 < 1/2 RDL Zinc (Zn) 0.00053 mg/L -10.00053 0.005 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Barium (Ba) 4.87 5 97.5mg/L -1208014.87 Boron (B) 4.81 5 96.3mg/L -1208014.81 Calcium (Ca) 4.94 5 98.8mg/L -1208014.94 Chromium (Cr) 4.9 5 98mg/L -1208014.9 Copper (Cu) 4.88 5 97.6mg/L -1208014.88 Iron (Fe) 4.89 5 97.7mg/L -1208014.89 Magnesium (Mg) 4.92 5 98.4mg/L -1208014.92 Manganese (Mn) 4.9 5 98.1mg/L -1208014.9 Nickel (Ni) 4.99 5 99.7mg/L -1208014.99 Potassium (K) 4.85 5 97mg/L -1208014.85 Sodium (Na) 4.75 5 95mg/L -1208014.75 Zinc (Zn) 4.91 5 98.2mg/L -1208014.91 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J16120415 -- 2016040260 Barium (Ba) 4.91 5 97.9mg/L -1257514.91 Boron (B) 4.83 5 96.5mg/L -1257514.83 Calcium (Ca) 8.27 5 97.6mg/L -1257518.27 Chromium (Cr) 4.91 5 98.2mg/L -1257514.91 Copper (Cu) 4.9 5 97.9mg/L -1257514.9 Iron (Fe) 11.8 5 96.9mg/L -12575111.8 Magnesium (Mg) 7.62 5 96.3mg/L -1257517.62 Manganese (Mn) 5.02 5 98.5mg/L -1257515.02 Nickel (Ni) 5 5 99.7mg/L -1257515 Potassium (K) 6.37 5 97.7mg/L -1257516.37 Page 35 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 Q17020043 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J16120415 -- 2016040260 Sodium (Na) 9.18 5 96.7mg/L -1257519.18 Zinc (Zn) 4.92 5 98mg/L -1257514.92 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J16120415 -- 2016040260 Barium (Ba) 4.92 5 98.2 0.245mg/L -1257514.92 Boron (B) 4.86 5 97 0.537mg/L -1257514.86 Calcium (Ca) 8.29 5 98 0.47mg/L -1257518.29 Chromium (Cr) 4.92 5 98.4 0.203mg/L -1257514.92 Copper (Cu) 4.91 5 98.1 0.204mg/L -1257514.91 Iron (Fe) 11.8 5 97.7 0.822mg/L -12575111.8 Magnesium (Mg) 7.63 5 96.6 0.249mg/L -1257517.63 Manganese (Mn) 5.04 5 98.8 0.243mg/L -1257515.04 Nickel (Ni) 5 5 99.8 0.12mg/L -1257515 Potassium (K) 6.37 5 97.6 0.0615mg/L -1257516.37 Sodium (Na) 9.2 5 97.1 0.433mg/L -1257519.2 Zinc (Zn) 4.92 5 98.1 0.0816mg/L -1257514.92 Page 36 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 Q17010669 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Arsenic (As) 0.002 ug/L -10.002 1 < 1/2 RDL Cadmium (Cd) 0.005 ug/L -10.005 1 < 1/2 RDL Lead (Pb) 0.001 ug/L -10.001 1 < 1/2 RDL Selenium (Se) -0.028 ug/L -1-0.028 1 < 1/2 RDL Silver (Ag) 0.004 ug/L -10.004 1 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Arsenic (As) 50.9 50 102ug/L -12080150.9 Cadmium (Cd) 50.7 50 101ug/L -12080150.7 Lead (Pb) 51.3 50 103ug/L -12080151.3 Selenium (Se) 45.5 50 90.9ug/L -12080145.5 Silver (Ag) 53 50 106ug/L -12080153 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J16120415 -- 2016040258 Arsenic (As) 48.8 50 97ug/L -12575148.8 Cadmium (Cd) 49.4 50 98.7ug/L -12575149.4 Lead (Pb) 51.2 50 99.5ug/L -12575151.2 Selenium (Se) 44 50 87.9ug/L -12575144 Silver (Ag) 51.2 50 102ug/L -12575151.2 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J16120415 -- 2016040258 Arsenic (As) 48.6 50 96.6 0.446ug/L -12575148.6 Cadmium (Cd) 49.6 50 99.1 0.419ug/L -12575149.6 Lead (Pb) 51.5 50 100 0.587ug/L -12575151.5 Selenium (Se) 44 50 87.9 0.0319ug/L -12575144 Silver (Ag) 50.9 50 102 0.686ug/L -12575150.9 Page 37 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 Q17020054 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Arsenic (As) 0.101 ug/L -10.101 1 < 1/2 RDL Cadmium (Cd) 0.0016 ug/L -10.0016 1 < 1/2 RDL Lead (Pb) -0.0015 ug/L -1-0.0015 1 < 1/2 RDL Selenium (Se) -0.0116 ug/L -1-0.0116 1 < 1/2 RDL Silver (Ag) 0.0005 ug/L -10.0005 1 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Arsenic (As) 49.8 50 99.5ug/L -12080149.8 Cadmium (Cd) 49.7 50 99.3ug/L -12080149.7 Lead (Pb) 49.2 50 98.3ug/L -12080149.2 Selenium (Se) 47.1 50 94.2ug/L -12080147.1 Silver (Ag) 53.1 50 106ug/L -12080153.1 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J16120415 -- 2016040261 Arsenic (As) 49.9 50 98.9ug/L -12575149.9 Cadmium (Cd) 51.1 50 102ug/L -12575151.1 Lead (Pb) 51.4 50 99.4ug/L -12575151.4 Selenium (Se) 48.3 50 96.5ug/L -12575148.3 Silver (Ag) 53.8 50 107ug/L -12575153.8 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J16120415 -- 2016040261 Arsenic (As) 50.2 50 99.6 0.645ug/L -12575150.2 Cadmium (Cd) 51.4 50 103 0.606ug/L -12575151.4 Lead (Pb) 51.5 50 99.8 0.323ug/L -12575151.5 Selenium (Se) 46.7 50 93.3 3.31ug/L -12575146.7 Silver (Ag) 54.1 50 108 0.559ug/L -12575154.1 Page 38 of 41 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120415 Q17020042 TDS TOTAL DISSOLVED SOLIDS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration TDS 0 mg/L -10 25 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Blank # 2 RDL Relative Concentration TDS 0 mg/L -10 25 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter Duplicate # 1 RPD Parent Sample: J16120415 -- 2016040257 TDS 60 10.5mg/L -160 Final QualifierDilMeasuredUnits:Parameter Duplicate # 2 RPD Parent Sample: J16120415 -- 2016040258 TDS 87 2.27mg/L -187 Final QualifierDilMeasuredUnits:Parameter Duplicate # 3 RPD Parent Sample: J16120415 -- 2016040259 TDS 71 2.78mg/L -171 Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike TDS 107 100 107mg/L -110901107 Page 39 of 41 Page 40 of 41 Page 41 of 41 13339 Hagers Ferry RoadHuntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J16120417 Project Name:BELEWS - GW CRAIG ROAD LF Lab Contact: Anne Pridgeon Date:2/17/2017 Customer Address:3195 Pine Hall Rd Customer Name(s):Chuck Campbell, T. Hunsucker, Ed Sullivan Mailcode: Belews Steam Station Belews Creek, NC 28012 Phone: 980-875-6610 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Anne Pridgeon) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Anne Pridgeon Page 1 of 10 Reason: I have reviewed this document. Date: 2017.02.17 10:39:20 -05'00' Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2016040285 BELEWS 31-Jan-17 9:25 AM LDC CRS-1 2016040286 BELEWS 31-Jan-17 10:40 AM PSP CRS-2 2016040288 BELEWS 31-Jan-17 11:30 AM LDC CRS-6 3 Total Samples Page 2 of 10 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:DBA Account Date:2/17/2017 Electronic Data Deliverable (EDD) Sent Separatel Page 3 of 10 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120417 2016040285 Collection Date:31-Jan-17 9:25 AM Site:CRS-1 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP Barium (Ba)0.025 mg/L SW 6010D 02/14/2017 12:43 JJMACKE0.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/14/2017 12:43 JJMACKE0.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 02/14/2017 12:43 JJMACKE0.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/14/2017 12:43 JJMACKE0.005 1 Iron (Fe)0.084 mg/L SW 6010D 02/14/2017 12:43 JJMACKE0.01 1 Manganese (Mn)0.032 mg/L SW 6010D 02/14/2017 12:43 JJMACKE0.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/14/2017 12:43 JJMACKE0.005 1 Zinc (Zn)< 0.005 mg/L SW 6010D 02/14/2017 12:43 JJMACKE0.005 1 DISSOLVED METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/14/2017 16:55 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 02/14/2017 16:55 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 02/14/2017 16:55 CWSPEN311 Silver (Ag)< 1 ug/L SW 6020B 02/14/2017 16:55 CWSPEN311 Page 4 of 10 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120417 2016040286 Collection Date:31-Jan-17 10:40 AM Site:CRS-2 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP Barium (Ba)0.024 mg/L SW 6010D 02/14/2017 12:54 JJMACKE0.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/14/2017 12:54 JJMACKE0.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 02/14/2017 12:54 JJMACKE0.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/14/2017 12:54 JJMACKE0.005 1 Iron (Fe)0.714 mg/L SW 6010D 02/14/2017 12:54 JJMACKE0.01 1 Manganese (Mn)0.103 mg/L SW 6010D 02/14/2017 12:54 JJMACKE0.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/14/2017 12:54 JJMACKE0.005 1 Zinc (Zn)< 0.005 mg/L SW 6010D 02/14/2017 12:54 JJMACKE0.005 1 DISSOLVED METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/14/2017 17:16 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 02/14/2017 17:16 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 02/14/2017 17:16 CWSPEN311 Silver (Ag)< 1 ug/L SW 6020B 02/14/2017 17:16 CWSPEN311 Page 5 of 10 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120417 2016040288 Collection Date:31-Jan-17 11:30 AM Site:CRS-6 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP Barium (Ba)0.031 mg/L SW 6010D 02/14/2017 12:58 JJMACKE0.005 1 Boron (B)< 0.05 mg/L SW 6010D 02/14/2017 12:58 JJMACKE0.05 1 Chromium (Cr)< 0.005 mg/L SW 6010D 02/14/2017 12:58 JJMACKE0.005 1 Copper (Cu)< 0.005 mg/L SW 6010D 02/14/2017 12:58 JJMACKE0.005 1 Iron (Fe)0.011 mg/L SW 6010D 02/14/2017 12:58 JJMACKE0.01 1 Manganese (Mn)0.325 mg/L SW 6010D 02/14/2017 12:58 JJMACKE0.005 1 Nickel (Ni)< 0.005 mg/L SW 6010D 02/14/2017 12:58 JJMACKE0.005 1 Zinc (Zn)< 0.005 mg/L SW 6010D 02/14/2017 12:58 JJMACKE0.005 1 DISSOLVED METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020B 02/14/2017 17:23 CWSPEN311 Cadmium (Cd)< 1 ug/L SW 6020B 02/14/2017 17:23 CWSPEN311 Lead (Pb)< 1 ug/L SW 6020B 02/14/2017 17:23 CWSPEN311 Silver (Ag)< 1 ug/L SW 6020B 02/14/2017 17:23 CWSPEN311 Page 6 of 10 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120417 Q17020372 ICP Dissolved DISSOLVED METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Barium (Ba) -0.0001 mg/L -1-0.0001 0.005 < 1/2 RDL Boron (B) -0.0046 mg/L -1-0.0046 0.05 < 1/2 RDL Chromium (Cr) 0.000139 mg/L -10.000139 0.005 < 1/2 RDL Copper (Cu) -0.00183 mg/L -1-0.00183 0.005 < 1/2 RDL Iron (Fe) -0.000052 mg/L -1-0.000052 0.01 < 1/2 RDL Manganese (Mn) -0.0001 mg/L -1-0.0001 0.005 < 1/2 RDL Nickel (Ni) -0.000901 mg/L -1-0.000901 0.005 < 1/2 RDL Zinc (Zn) -0.000916 mg/L -1-0.000916 0.005 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Barium (Ba) 0.988 1 98.8mg/L -1158510.988 Boron (B) 2 2 100mg/L -1158512 Chromium (Cr) 1.01 1 101mg/L -1158511.01 Copper (Cu) 1.95 2 97.3mg/L -1158511.95 Iron (Fe) 2.03 2 102mg/L -1158512.03 Manganese (Mn) 0.983 1 98.3mg/L -1158510.983 Nickel (Ni) 2 2 99.8mg/L -1158512 Zinc (Zn) 1.03 1 103mg/L -1158511.03 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J16120417 -- 2016040285 Barium (Ba) 5.78 5 115mg/L -1307015.78 Boron (B) 5.25 5 105mg/L -1307015.25 Chromium (Cr) 5.54 5 111mg/L -1307015.54 Copper (Cu) 5.53 5 111mg/L -1307015.53 Iron (Fe) 5.52 5 109mg/L -1307015.52 Manganese (Mn) 5.83 5 116mg/L -1307015.83 Nickel (Ni) 5.4 5 108mg/L -1307015.4 Zinc (Zn) 5.72 5 114mg/L -1307015.72 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J16120417 -- 2016040285 Barium (Ba) 5.77 5 115 0.104mg/L -1307015.77 Boron (B) 5.22 5 104 0.478mg/L -1307015.22 Chromium (Cr) 5.57 5 111 0.486mg/L -1307015.57 Copper (Cu) 5.54 5 111 0.325mg/L -1307015.54 Iron (Fe) 5.55 5 109 0.532mg/L -1307015.55 Manganese (Mn) 5.87 5 117 0.585mg/L -1307015.87 Nickel (Ni) 5.39 5 108 0.111mg/L -1307015.39 Page 7 of 10 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120417 Q17020372 ICP Dissolved DISSOLVED METALS BY ICP Level II QC Summary Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J16120417 -- 2016040285 Zinc (Zn) 5.76 5 115 0.697mg/L -1307015.76 Page 8 of 10 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16120417 Q17020383 IMS Dissolved DISSOLVED METALS BY ICP-MS Level II QC Summary Final QualifierDilMeasuredUnits:Parameter Blank # 1 RDL Relative Concentration Arsenic (As) -0.015 ug/L -1-0.015 1 < 1/2 RDL Cadmium (Cd) 0.001 ug/L -10.001 1 < 1/2 RDL Lead (Pb) 0.005 ug/L -10.005 1 < 1/2 RDL Silver (Ag) 0.002 ug/L -10.002 1 < 1/2 RDL Final QualifierDilMeasuredUnits:Parameter LCS # 1 % Recovery LCL UCLSpike Arsenic (As) 81.1 80 101ug/L -12080181.1 Cadmium (Cd) 8.3 8 104ug/L -1208018.3 Lead (Pb) 82.3 80 103ug/L -12080182.3 Silver (Ag) 40.4 40 101ug/L -12080140.4 Final QualifierDilMeasuredUnits:Parameter MS # 1 % Recovery LCL UCLSpike Parent Sample: J16120417 -- 2016040285 Arsenic (As) 48.9 50 97.8ug/L -12575148.9 Cadmium (Cd) 49.2 50 98.5ug/L -12575149.2 Lead (Pb) 49.4 50 98.7ug/L -12575149.4 Silver (Ag) 48.1 50 96.1ug/L -12575148.1 Final QualifierDilMeasuredUnits:Parameter MSD # 1 RPD% Recovery LCL UCLSpike Parent Sample: J16120417 -- 2016040285 Arsenic (As) 48.9 50 97.7 0.141ug/L -13070148.9 Cadmium (Cd) 49.3 50 98.5 0.0305ug/L -13070149.3 Lead (Pb) 49.4 50 98.7 0.0263ug/L -13070149.4 Silver (Ag) 48.4 50 96.8 0.645ug/L -13070148.4 Page 9 of 10 Page 10 of 10