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HomeMy WebLinkAbout5703_MaconCoMSW_5YrCAPEvaluation_DIN27586_20170217 1 February 17, 2017 Ms. Elizabeth Werner North Carolina Department of Environmental Quality 217 West Jones Street Raleigh, North Carolina 27603 RE: Five Year Groundwater Contaminant Trend Evaluation Macon County MSW Landfill, Permit No. 57-03, Macon County, North Carolina Ms. Werner; REI Consultants, Inc., on behalf of Macon County, has performed an evaluation of groundwater monitoring data collected from wells in the area where corrective action activities were conducted at Macon County’s MSW Landfill, Permit No. 57-03. The evaluation was conducted in order to evaluate the effectiveness of the corrective action remedies implemented at the facility. This letter and attachments present the findings and conclusions of the evaluation. INTRODUCTION Detections of several Appendix I volatile organic compounds (VOCs) in monitoring wells MW-1A and MW-1B northwest of the facility’s Phase 1/Phase 2 cell overlap triggered development of an assessment monitoring plan in 2007 (Bunnell-Lammons Engineering (BLE), Groundwater Contamination Assessment Plan, BLE Project Number J07-1101-03, September 13, 2007). Assessment monitoring included the addition of wells MW-1D, MW-5D, and MW-23 to the monitoring network. Well MW-1D was installed in the vicinity of wells MW-1A and MW-1B in order to monitor vertical migration of VOCs. Well MW-23 was placed between wells MW- 1A/MW-1B and the Little Tennessee River to monitor horizontal migration of VOCs toward the surface water body. Well MW-5D was installed in order to replace well MW-5, which lies to the south of wells MW-1A/MW-1B and had been dry since 2000. These three wells have been monitored for Appendix I parameters semiannually since the 2nd semiannual 2007 monitoring event. Assessment monitoring also included analysis of samples collected from wells MW-1A and MW-1B for all Appendix II parameters during the 2nd semiannual 2007 monitoring event. No additional parameters beyond the Appendix I list were detected in either well. A map with well locations is provided in Attachment A. Due to continued detections of Appendix I VOCs, some of which exceeded North Carolina groundwater standards promulgated under 15A NCAC 02L .0202 (NC 2L), Macon County developed a corrective action plan in 2010 (BLE, Limited Elements of a Corrective Action Plan, BLE Project Number J10-1101-05, August 23, 2010). Corrective action remedies were implemented in 2011 and consisted of grading of the Phase I cell surface to reduce impoundment/infiltration of 2 storm water and to promote positive runoff from the cell; and installation of a landfill gas cut-off trench containing passive landfill gas vents along the northwest edge of the Phase I area. A map prepared by McGill Associates, indicating the grading and trench locations, is included as Attachment B. The corrective action plan stipulated that an evaluation of the effectiveness of the remedies be conducted every five years after implementation of the corrective action activities. The first of these evaluations is this report. SUMMARY OF MONITORING RESULTS Detections of Appendix I VOCs have been limited to eight parameters, as discussed individually below, in wells located west and northwest of the Phase 1/Phase 2 cell overlap area of the landfill. These wells include MW-1A, MW-1B, MW-1D, MW-5D, and MW-23. VOCs have not been detected in wells south (MW-3A), southwest (MW-2), or north (MW-22, MW-22A) of the corrective action area, or in any other monitoring wells or surface water sample locations at the facility. A summary of VOC results is included as Attachment C. A discussion of the VOC detections, relative to current Solid Waste Section Limits (SWSLs) and current NC 2L groundwater standards, is as follows: Benzene (SWSL = 1 microgram per liter (µg/L), NC 2L = 1 µg/L) Benzene was detected above the SWSL and groundwater standard in wells MW-1A and MW-1B from 2001-2002 through 2009, but hasn’t been detected above the SWSL in either well since 2010. Benzene was detected above the SWSL and groundwater standard in well MW-1D from 2008 to 2010 and in 2012-2013, but hasn’t been detected above the SWSL since the 1st semiannual 2013 monitoring event. Benzene has not been detected above the SWSL in wells MW-5D or MW-23. Chlorobenzene (SWSL = 3 µg/L, NC 2L = 50 µg/L) Chlorobenzene was intermittently detected above the SWSL in wells MW-1A and MW-1B from 2003 to 2013, and in well MW-1D intermittently from 2009 to 2013. Chlorobenzene was never detected above the groundwater standard, and has not been detected above the SWSL in any well since 2013. 1,4-Dichlorobenzene (SWSL = 1 µg/L, NC 2L = 6 µg/L) This parameter was first detected above the SWSL in wells MW-1A and MW-1B in 2002, and has continued to be detected since that time in these wells and in well MW-1D, where it has been detected since its installation in 2007. In addition, 1,4-dichlorobenzene was detected above the SWSL in well MW-23 from 2008 to 2010. However, the parameter was detected at concentrations above the current groundwater standard only intermittently in wells MW-1A and MW-1B from 2003 3 to 2008, and has not been detected above the groundwater standard in wells MW-1D or MW-23. The parameter has not been detected above the SWSL in well MW-5D. 1,1-Dichloroethane (SWSL = 5 µg/L, NC 2L = 6 µg/L) This parameter was detected above the SWSL in wells MW-1A and MW-1B consistently from 2003 through 2006, and in well MW-1D in 2008 and 2009. However, 1,1-dichloroethane has not been detected above the SWSL in wells MW-1A and MW-1B since 2006 or in well MW-1D since 2009. Several of the detections in wells MW-1A and MW-1B exceeded the groundwater standard. None of the MW-1D detections exceeded the groundwater standard. The parameter has not been detected above the SWSL in wells MW-5D or MW-23. Ethylbenzene (SWSL = 1 µg/L, NC 2L = 600 µg/L) Ethylbenzene was detected above the SWSL in wells MW-1A and MW-1B in 2001 and 2002 at concentrations well below the groundwater standard. Ethylbenzene has not been detected above the SWSL in wells MW-1D, MW-5D, or MW-23. Methylene Chloride (SWSL = 1 µg/L, NC 2L = 5 µg/L) Methylene chloride was detected above the SWSL once in well MW-1A and once in well MW-1B in 2003. Both concentrations were above the groundwater protection standard. In addition, the parameter was detected above the SWSL but below the groundwater standard in well MW-5D from the time of its installation in 2007 through 2010. Methylene chloride has not been detected above the SWSL in wells MW-1D or MW-23. Vinyl Chloride (SWSL = 1 µg/L, NC 2L = 0.03 µg/L) Vinyl chloride was detected above the SWSL and above the groundwater standard in wells MW-1A and MW-1B from 2001 to 2010. Vinyl chloride has not been detected above the SWSL in either of these wells since 2010. Vinyl chloride has not been detected above the SWSL in wells MW-1D, MW-5D, or MW-23. Xylenes (SWSL = 5 µg/L, NC 2L = 500 µg/L) Xylenes were detected above the SWSL in well MW-1A from 2000 to 2002 and in well MW-1B from 2001 to 2003. These detections were all below the groundwater protection standard. Xylenes were detected above the SWSL but below the groundwater standard in well MW-5D in 2007 and 2008. Xylenes have not been detected above the SWSL in wells MW-1D or MW-23. 4 TREND EVALUATION As indicated in the discussion above, only 1,4-dichlorobenzene continues to be detected above its SWSL, in wells MW-1A, MW-1B, and MW-1D. All recent detections have been below the groundwater standard. However, due to the continuing detections, an analysis was conducted in order to identify potential trends in concentrations of 1,4-dichlorobenzene in wells MW-1A, MW- 1B, and MW-1D. An initial trend analysis was conducted qualitatively by plotting 1,4-dichlorobenzene data in each well, starting from when the parameter began being detected consistently, up to the most recent monitoring event. The parameter has been detected consistently since the 2nd semiannual 2005 event in wells MW-1A and MW-1B, and since the 2nd semiannual 2008 event in well MW-1D. The plots are included in Attachment D. As indicated by the plots, concentrations of 1,4-dichlorobenzene appear generally to be decreasing in wells MW-1A and MW-1B, and no apparent trend is discernable in well MW-1D. A more formal, quantitative trend analysis was then conducted using the same data as above. The method utilized for trend analysis was the linear regression technique (United States Environmental Protection Agency Office of Resource Conservation and Recovery, Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance, March 2009). This analysis is included in Attachment E and indicates evidence of statistically significant decreasing trends in 1,4- dichlorobenzene concentrations in wells MW-1A and MW-1B, and no evidence of an increasing or decreasing trend in well MW-1D. CONCLUSIONS All VOCs that have been detected above SWSLs historically in the corrective action area of the Macon County MSW Landfill are presently below NC 2L groundwater standards, and no results have exceeded groundwater standards since the 1st semiannual 2013 monitoring event. Of the eight VOCs detected historically, only 1,4-dichlorobenzene continues to be detected above the SWSL, in wells MW-1A, MW-1B, and MW-1D. However, concentrations of 1,4-dichlorobenzene in wells MW-1A and MW-1B appear to be decreasing, and no significant trend is apparent in well MW-1D. The implemented corrective actions have been effective in reducing concentrations of VOCs to below NC 2L groundwater standards. As such, contingency plan measures as proposed in the Limited Elements of a Corrective Action Plan are not required to be implemented at this time. RECOMMENDATIONS We recommend continued sampling of well MW-1D, since 1,4-dichlorobenzene continues to be detected above the SWSL in the well. 5 We recommend that sampling of well MW-23 be discontinued, since no VOCs have been detected above SWSLs in the well since the 2nd semiannual 2010 monitoring event. The well should be kept in place, maintained, and utilized for water level monitoring, such that sampling could be resumed if future monitoring results in wells MW-1A, MW-1B, and/or MW-1D indicate VOCs greater than groundwater standards. Should you have any questions or need additional information, please feel free to contact me at (304) 255-2500 or mhofe@reiclabs.com. Sincerely, Michael Hofe, PE REI Consultants, Inc. cc: Chris Stahl, Macon County Ervin Lane, North Carolina Department of Environmental Quality Mark Cathey, McGill Associates Andrew Alexander, BLE Attachments (5) ATTACHMENT A Map of Well Locations in the Vicinity of Corrective Action Activities MW-1A MW-1D MW-1B MW-2 MW-23 MONITORING WELL TOPOGRAPHIC CONTOURS SURFACE WATER PROPERTY LINE WASTE CELL LIMITS STRUCTURES ROADS - PAVED ROADS - UNPAVED PHASE I (CLOSED) PHASE II (ACTIVE) N PREPARED BY: REI CONSULTANTS, INC. JANUARY 2017 MW-5 MW-5D MW-3A MW-22A MW-22 MW-21 MW-20 MW-17 MACON COUNTY MSW LANDFILL, PERMIT NO. 57-03 FRANKLIN, NORTH CAROLINA WELLS IN THE VICINITY OF THE CORRECTIVE ACTION AREA OF FACILITY SCALE: 0'100'200' ATTACHMENT B McGill Associates Map of Corrective Action Activities C1 SHEET ATTACHMENT C Summary of VOC Data Attachment C. Summary of VOC Data Macon County MSW Landfill, Permit No. 57-03 Parameter SWSL NC 2L Well MW-1AMW-1BMW-1DMW-5DMW-23MW-1AMW-1BMW-1DMW-5DMW-23MW-1AMW-1BMW-1DMW-5DMW-23MW-1AMW-1BMW-1DMW-5DMW-23 Feb-1995 <1 <1 ---<3 <3 ---<1 <1 ---<5 <5 --- Mar-1995 <1 <1 ---<3 <3 ---<1 <1 ---<5 <5 --- Nov-1995 <1 <1 ---<3 <3 ---<1 <1 ---<5 <5 --- Apr-1996 <1 <1 ---<3 <3 ---<1 <1 ---<5 <5 --- Oct-1996 <1 <1 ---<3 <3 ---<1 <1 ---<5 <5 --- May-1997 <1 <1 ---<3 <3 ---<1 <1 ---<5 <5 --- Oct-1997 <1 <1 ---<3 <3 ---<1 <1 ---<5 <5 --- May-1998 <1 <1 ---<3 <3 ---<1 <1 ---<5 <5 --- Oct-1998 <1 <1 ---<3 <3 ---<1 <1 ---<5 <5 --- Apr-1999 <1 <1 ---<3 <3 ---<1 <1 ---<5 <5 --- Oct-1999 <1 <1 ---<3 <3 ---<1 <1 ---<5 <5 --- Apr-2000 <1 <1 ---<3 <3 ---<1 <1 ---<5 <5 --- Oct-2000 <1 <1 ---<3 <3 ---<1 <1 ---<5 23 --- Apr-2001 <1 <1 ---<3 <3 ---<1 <1 ---<5 <5 --- Oct-2001 1.4 1.0 ---<3 <3 ---<1 <1 ---<5 <5 --- Apr-2002 1.6 1.3 ---<3 <3 ---1 <1 ---<5 <5 --- Oct-2002 2.4 1.7 ---<3 <3 ---2.2 1.2 ---<5 <5 --- Apr-2003 <1 <1 ---<3 <3 ---<1 <1 ---7.6 5.3 --- Oct-2003 <1 5.2 ---<3 6.3 ---<1 6.4 ---8.8 12 --- Apr-2004 <1 <1 ---5.2 <3 ---<1 <1 ---6.9 6.5 --- Dec-2004 4.2 3.1 ---5.3 <3 ---6.0 <1 ---7.6 5.8 --- Apr-2005 3.5 3.2 ---<3 <3 ---<1 <1 ---6.1 5.8 --- Oct-2005 3.8 3.6 ---5.6 5.0 ---6.7 5.7 ---7.1 6.7 --- Apr-2006 2.5 2.8 ---<3 <3 ---5.8 5.3 ---5.6 5.3 --- Oct-2006 2.1 3.0 ---5.3 5.1 ---6.5 6.0 ---6.4 6.4 --- Apr-2007 2.3 2.2 ---4.6 4.0 ---5.4 4.9 ---<5 <5 --- Oct-2007 2.2 2.3 <1 <1 <1 5.1 5.0 <3 <3 <3 5.9 5.7 1.3 <1 <1 <5 <5 <5 <5 <5 Apr-2008 1.8 1.9 2.6 <1 <1 3.5 3.6 <3 <3 <3 4.2 4.4 <1 <1 1.3 <5 <5 5.7 <5 <5 Oct-2008 1.4 1.5 1.5 <1 <1 4.9 3.9 <3 <3 <3 6.3 5.0 2.2 <1 1.1 <5 <5 <5 <5 <5 Apr-2009 1.1 1.2 2.6 <1 <1 <3 <3 3.0 <3 <3 3.2 3.6 2.6 <1 1.2 <5 <5 5.3 <5 <5 Oct-2009 <1 <1 2.7 <1 <1 3.2 <3 3.7 <3 <3 4.6 4.1 4.4 <1 1.3 <5 <5 5.8 <5 <5 Apr-2010 <1 <1 1.4 <1 <1 <3 <3 3.1 <3 <3 3.6 3.0 3.9 <1 1.1 <5 <5 <5 <5 <5 Oct-2010 <1 <1 <1 <1 <1 4.0 3.1 <3 <3 <3 5.2 4.2 3.4 <1 1.0 <5 <5 <5 <5 <5 Apr-2011 <1 <1 <1 <1 <1 <3 <3 <3 <3 <3 3.2 2.7 3.4 <1 <1 <5 <5 <5 <5 <5 Oct-2011 <1 <1 <1 <1 <1 3.5 <3 <3 <3 <3 4.3 4.0 3.3 <1 <1 <5 <5 <5 <5 <5 Apr-2012 <1 <1 <1 <1 <1 <3 <3 <3 <3 <3 3.0 2.7 3.4 <1 <1 <5 <5 <5 <5 <5 Oct-2012 <1 <1 1.4 <1 <1 4.0 <3 3.3 <3 <3 4.2 2.9 3.5 <1 <1 <5 <5 <5 <5 <5 Apr-2013 <1 <1 1.1 <1 <1 <3 <3 3.4 <3 <3 1.5 1.1 3.1 <1 <1 <5 <5 <5 <5 <5 Oct-2013 <1 <1 <1 <1 <1 3.2 <3 <3 <3 <3 3.7 2.8 3.5 <1 <1 <5 <5 <5 <5 <5 Apr-2014 <1 <1 <1 <1 <1 <3 <3 <3 <3 <3 1.9 1.6 3.5 <1 <1 <5 <5 <5 <5 <5 Oct-2014 <1 <1 <1 <1 <1 <3 <3 <3 <3 <3 2.0 2.0 3.4 <1 <1 <5 <5 <5 <5 <5 Apr-2015 <1 <1 <1 <1 <1 <3 <3 <3 <3 <3 2.6 1.9 3.3 <1 <1 <5 <5 <5 <5 <5 Oct-2015 <1 <1 <1 <1 <1 <3 <3 <3 <3 <3 2.6 1.5 2.0 <1 <1 <5 <5 <5 <5 <5 Apr-2016 <1 <1 <1 <1 <1 <3 <3 <3 <3 <3 1.8 1.4 3.1 <1 <1 <5 <5 <5 <5 <5 Oct-2016 <1 <1 <1 <1 <1 <3 <3 <3 <3 <3 2.7 1.5 3.7 <1 <1 <5 <5 <5 <5 <5 All data in micrograms per liter SWSL - North Carolina Solid Waste Section Limit NC 2L - current 15A NCAC 2L .0202 groundwater standard Data presented relative to current SWSLs and NC 2L groundwater standards Detections above SWSLs in BOLD; detections greater than NC 2L in RED 1,4-DichlorobenzeneBenzeneChlorobenzene 5 6 1,1-Dichloroethane 6150 113 REI Consultants, Inc. ** PO Box 286 ** Beaver, WV 25813 Attachment C. Summary of VOC Data Macon County MSW Landfill, Permit No. 57-03 Parameter SWSL NC 2L Well Feb-1995 Mar-1995 Nov-1995 Apr-1996 Oct-1996 May-1997 Oct-1997 May-1998 Oct-1998 Apr-1999 Oct-1999 Apr-2000 Oct-2000 Apr-2001 Oct-2001 Apr-2002 Oct-2002 Apr-2003 Oct-2003 Apr-2004 Dec-2004 Apr-2005 Oct-2005 Apr-2006 Oct-2006 Apr-2007 Oct-2007 Apr-2008 Oct-2008 Apr-2009 Oct-2009 Apr-2010 Oct-2010 Apr-2011 Oct-2011 Apr-2012 Oct-2012 Apr-2013 Oct-2013 Apr-2014 Oct-2014 Apr-2015 Oct-2015 Apr-2016 Oct-2016 MW-1AMW-1BMW-1DMW-5DMW-23MW-1AMW-1BMW-1DMW-5DMW-23MW-1AMW-1BMW-1DMW-5DMW-23MW-1AMW-1BMW-1DMW-5DMW-23 <1 <1 ---<1 <1 ---<1 <1 ---<5 <5 --- <1 <1 ---<1 <1 ---<1 <1 ---<5 <5 --- <1 <1 ---<1 <1 ---<1 <1 ---<5 <5 --- <1 <1 ---<1 <1 ---<1 <1 ---<5 <5 --- <1 <1 ---<1 <1 ---<1 <1 ---<5 <5 --- <1 <1 ---<1 <1 ---<1 <1 ---<5 <5 --- <1 <1 ---<1 <1 ---<1 <1 ---<5 <5 --- <1 <1 ---<1 <1 ---<1 <1 ---<5 <5 --- <1 <1 ---<1 <1 ---<1 <1 ---<5 <5 --- <1 <1 ---<1 <1 ---<1 <1 ---<5 <5 --- <1 <1 ---<1 <1 ---<1 <1 ---<5 <5 --- <1 <1 ---<1 <1 ---<1 <1 ---<5 <5 --- <1 <1 ---<1 <1 ---<1 <1 ---6.3 <5 --- 6.4 <1 ---<1 <1 ---1.1 <1 ---8.2 <5 --- 5.8 3.7 ---<1 <1 ---1.7 1.0 ---13 8.9 --- <1 <1 ---<1 <1 ---1.8 1.4 ---12 6.2 --- <1 1.2 ---<1 <1 ---2.9 1.8 ---9.2 5.3 --- <1 <1 ---5.8 <1 ---<1 <1 ---<5 6 --- <1 <1 ---<1 6.1 ---<1 5.5 ---<5 8.4 --- <1 <1 ---<1 <1 ---<1 <1 ---<5 <5 --- <1 <1 ---<1 <1 ---3.9 2.7 ---<5 <5 --- <1 <1 ---<1 <1 ---3.0 3.0 ---<5 <5 --- <1 <1 ---<1 <1 ---4.6 3.9 ---<5 <5 --- <1 <1 ---<1 <1 ---2.8 2.9 ---<5 <5 --- <1 <1 ---<1 <1 ---2.7 3.0 ---<5 <5 --- <1 <1 ---<1 <1 ---2.9 2.7 ---<5 <5 --- <1 <1 <1 <1 <1 <1 <1 <1 1.2 <1 2.2 2.3 <1 <1 <1 <5 <5 <5 5.8 <5 <1 <1 <1 <1 <1 <1 <1 <1 1.7 <1 1.8 1.8 <1 <1 <1 <5 <5 <5 <5 <5 <1 <1 <1 <1 <1 <1 <1 <1 1.7 <1 1.8 1.6 <1 <1 <1 <5 <5 <5 6.1 <5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 1.3 1.3 <1 <1 <1 <5 <5 <5 <5 <5 <1 <1 <1 <1 <1 <1 <1 <1 1.2 <1 1.3 1.3 <1 <1 <1 <5 <5 <5 <5 <5 <1 <1 <1 <1 <1 <1 <1 <1 1.3 <1 1.2 1.1 <1 <1 <1 <5 <5 <5 <5 <5 <1 <1 <1 <1 <1 <1 <1 <1 1.5 <1 <1 <1 <1 <1 <1 <5 <5 <5 <5 <5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5 <5 <5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5 <5 <5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5 <5 <5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5 <5 <5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5 <5 <5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5 <5 <5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5 <5 <5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5 <5 <5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5 <5 <5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5 <5 <5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5 <5 <5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5 <5 <5 All data in micrograms per liter SWSL - North Carolina Solid Waste Section Limit NC 2L - current 15A NCAC 2L .0202 groundwater standard Data presented relative to current SWSLs and NC 2L groundwater standards Detections above SWSLs in BOLD; detections greater than NC 2L in RED Ethylbenzene 1 Methylene Chloride Vinyl Chloride Xylenes, Total 1 1 5 600 5 0.03 500 REI Consultants, Inc. ** PO Box 286 ** Beaver, WV 25813 ATTACHMENT D Time Series Plots Attachment D. Time Series Plots of 1,4-Dichlorobenzene Macon County MSW Landfill, Permit No. 57-03 0 1 2 3 4 5 6 7 20 05 20 06 20 07 20 08 20 09 20 10 20 11 20 12 20 13 20 14 20 15 20 16 20 17 u g /L 1,4-Dichlorobenzene, Well MW-1B 0 1 2 3 4 5 6 7 20 05 20 06 20 07 20 08 20 09 20 10 20 11 20 12 20 13 20 14 20 15 20 16 20 17 u g /L 1,4-Dichlorobenzene, Well MW-1A 0 1 2 3 4 5 6 7 2 0 05 2 0 06 2 0 07 2 0 08 2 0 09 2 0 10 2 0 11 2 0 12 2 0 13 2 0 14 2 0 15 2 0 16 2 0 17 u g /L 1,4-Dichlorobenzene, Well MW-1D REI Consultants, Inc. ** PO Box 286 ** Beaver, WV 25813 ATTACHMENT E Trend Calculations Attachment E. Trend Calculations Macon County MSW Landfill, Permit No. 57-03 Well MW-1A Linear Regression Residuals Normality Test ti xi bi x͆i ri ri2 (t-t̅)2 xi xn-i+1 xn-i+1-xi an-i+1 bi Oct-2005 6.7 -0.000400182 6.2 0.5 0.25 4052519 -1.6 1.3 2.921 0.4542 1.3266 Apr-2006 5.8 -0.00031373 6.0 -0.2 0.03 3323646 -1.6 1.0 2.603 0.3126 0.8138 Oct-2006 6.5 -0.000316301 5.8 0.7 0.52 2689885 -1.0 1.0 1.965 0.2563 0.5036 Apr-2007 5.4 -0.000233773 5.6 -0.2 0.03 2128935 -0.9 0.9 1.740 0.2139 0.3722 Oct-2007 5.9 -0.000223734 5.4 0.5 0.27 1633506 -0.8 0.8 1.511 0.1787 0.2701 Apr-2008 4.2 -0.000136464 5.2 -1.0 0.95 1199215 -0.8 0.7 1.470 0.1480 0.2175 Oct-2008 6.3 -0.000170676 5.0 1.3 1.77 833728 -0.5 0.6 1.088 0.1201 0.1306 Apr-2009 3.2 -6.87481E-05 4.8 -1.6 2.43 524302 -0.5 0.5 1.053 0.0941 0.0991 Oct-2009 4.6 -7.49409E-05 4.6 0.0 0.00 301496 -0.2 0.5 0.688 0.0696 0.0479 Apr-2010 3.6 -3.92095E-05 4.4 -0.8 0.58 134753 -0.2 0.5 0.664 0.0459 0.0305 Oct-2010 5.2 -2.84018E-05 4.2 1.0 1.09 33888 -0.1 0.2 0.361 0.0228 0.0082 Apr-2011 3.2 -1.98145E-07 4.0 -0.8 0.56 4 0.0 0.0 0.000 0.0000 0.0000 Oct-2011 4.3 2.2826E-05 3.7 0.6 0.30 32010 0.2 -0.1 -0.361 Apr-2012 3.0 3.28371E-05 3.5 -0.5 0.29 136097 0.5 -0.2 -0.664 b=3.8201 Oct-2012 4.2 6.85273E-05 3.3 0.9 0.75 302404 0.5 -0.2 -0.688 Apr-2013 1.5 3.34883E-05 3.1 -1.6 2.53 537162 0.5 -0.5 -1.053 Oct-2013 3.7 9.97867E-05 2.9 0.8 0.57 835237 0.6 -0.5 -1.088 Apr-2014 1.9 6.01545E-05 2.7 -0.9 0.76 1201025 0.7 -0.8 -1.470 Oct-2014 2.0 7.55117E-05 2.5 -0.5 0.28 1635619 0.8 -0.8 -1.511 Apr-2015 2.6 0.000111169 2.3 0.2 0.06 2125510 0.9 -0.9 -1.740 Oct-2015 2.6 0.000126584 2.1 0.5 0.23 2692596 1.0 -1.0 -1.965 Apr-2016 1.8 9.74085E-05 1.9 -0.1 0.01 3326659 1.0 -1.6 -2.603 Oct-2016 2.7 0.000160693 1.7 1.0 0.98 4023687 1.3 -1.6 -2.921 b͆ =-0.001117372 sum ri2 sum (t-t̅)2 sx =0.83 15.26 33703884 W =0.956 greater than 0.881 t̅ =40649 normal assumption not rejected s2t =1531994.719 x̅ =3.9 s2e =0.726760765 se(b͆) =0.000146844 tb =-7.609255425 tcp =2.518 tb < -tcp ==> assume a significant decreasing trend Reference: USEPA Unified Guidance, 17.3.1 REI Consultants, Inc. ** PO Box 285 ** Beaver, WV 25813 Attachment E. Trend Calculations Macon County MSW Landfill, Permit No. 57-03 Well MW-1B Linear Regression Residuals Normality Test ti xi bi x͆i ri ri2 (t-t̅)2 xi xn-i+1 xn-i+1-xi an-i+1 bi Oct-2005 5.7 -0.000340453 5.8 -0.1 0.00 4052519 -1.4 0.8 2.217 0.4542 1.0069 Apr-2006 5.3 -0.000286684 5.5 -0.2 0.06 3323646 -0.8 0.8 1.626 0.3126 0.5083 Oct-2006 6.0 -0.00029197 5.3 0.7 0.46 2689885 -0.7 0.7 1.369 0.2563 0.3508 Apr-2007 4.9 -0.000212128 5.1 -0.2 0.04 2128935 -0.6 0.6 1.237 0.2139 0.2645 Oct-2007 5.7 -0.00021615 4.9 0.8 0.64 1633506 -0.5 0.5 1.021 0.1787 0.1825 Apr-2008 4.4 -0.000142962 4.7 -0.3 0.08 1199215 -0.3 0.5 0.756 0.1480 0.1119 Oct-2008 5.0 -0.000135457 4.5 0.5 0.28 833728 -0.3 0.5 0.713 0.1201 0.0856 Apr-2009 3.6 -7.73416E-05 4.2 -0.6 0.42 524302 -0.2 0.2 0.478 0.0941 0.0450 Oct-2009 4.1 -6.67952E-05 4.0 0.1 0.00 301496 -0.2 0.2 0.371 0.0696 0.0258 Apr-2010 3.0 -3.26746E-05 3.8 -0.8 0.68 134753 -0.1 0.2 0.222 0.0459 0.0102 Oct-2010 4.2 -2.29399E-05 3.6 0.6 0.35 33888 0.1 0.1 0.022 0.0228 0.0005 Apr-2011 2.7 -1.67185E-07 3.4 -0.7 0.48 4 0.1 0.1 0.000 0.0000 0.0000 Oct-2011 4.0 2.12335E-05 3.2 0.8 0.67 32010 0.1 0.1 -0.022 Apr-2012 2.7 2.95534E-05 3.0 -0.3 0.07 136097 0.2 -0.1 -0.222 b=2.5920 Oct-2012 2.9 4.73164E-05 2.7 0.2 0.02 302404 0.2 -0.2 -0.371 Apr-2013 1.1 2.45726E-05 2.5 -1.4 1.95 537162 0.2 -0.2 -0.478 Oct-2013 2.8 7.51112E-05 2.3 0.5 0.21 835237 0.5 -0.3 -0.713 Apr-2014 1.6 5.23506E-05 2.1 -0.5 0.24 1201025 0.5 -0.3 -0.756 Oct-2014 2.0 7.39939E-05 1.9 0.1 0.00 1635619 0.5 -0.5 -1.021 Apr-2015 1.9 8.262E-05 1.7 0.2 0.06 2125510 0.6 -0.6 -1.237 Oct-2015 1.5 7.49767E-05 1.5 0.1 0.01 2692596 0.7 -0.7 -1.369 Apr-2016 1.4 7.57621E-05 1.2 0.2 0.03 3326659 0.8 -0.8 -1.626 Oct-2016 1.5 8.92737E-05 1.0 0.5 0.22 4023687 0.8 -1.4 -2.217 b͆ =-0.001178959 sum ri2 sum (t-t̅)2 sx =0.56 6.98 33703884 W =0.963 greater than 0.881 t̅ =40649 normal assumption not rejected s2t =1531994.719 x̅ =3.4 s2e =0.332287653 se(b͆) =9.92927E-05 tb =-11.87357295 tcp =2.518 tb < -tcp ==> assume a significant decreasing trend Reference: USEPA Unified Guidance, 17.3.1 REI Consultants, Inc. ** PO Box 285 ** Beaver, WV 25813 Attachment E. Trend Calculations Macon County MSW Landfill, Permit No. 57-03 Well MW-1D Linear Regression Residuals Normality Test ti xi bi x͆i ri ri2 (t-t̅)2 xi xn-i+1 xn-i+1-xi an-i+1 bi Oct-2008 2.2 -0.000236643 3.3 -1.1 1.22 2133490 -1.2 1.1 2.327 0.4968 1.1562 Apr-2009 2.6 -0.000243481 3.3 -0.7 0.49 1617086 -1.1 0.6 1.711 0.3273 0.5599 Oct-2009 4.4 -0.000355341 3.3 1.1 1.21 1202635 -0.7 0.5 1.153 0.2540 0.2930 Apr-2010 3.9 -0.00026269 3.3 0.6 0.37 836579 -0.2 0.2 0.396 0.1988 0.0787 Oct-2010 3.4 -0.000183192 3.3 0.1 0.01 535307 -0.1 0.2 0.356 0.1524 0.0543 Apr-2011 3.4 -0.000137622 3.3 0.1 0.01 302112 0.0 0.2 0.174 0.1109 0.0193 Oct-2011 3.3 -8.95881E-05 3.3 0.0 0.00 135901 0.1 0.1 0.059 0.0725 0.0043 Apr-2012 3.4 -4.47302E-05 3.3 0.1 0.01 31915 0.1 0.1 0.025 0.0359 0.0009 Oct-2012 3.5 6.06464E-07 3.3 0.2 0.05 6 0.1 0.1 0.000 Apr-2013 3.1 4.28603E-05 3.3 -0.1 0.02 34356 0.1 0.1 -0.025 b=2.1665 Oct-2013 3.5 9.33473E-05 3.3 0.2 0.04 134214 0.1 0.1 -0.059 Apr-2014 3.5 0.00014174 3.3 0.2 0.06 300691 0.2 0.0 -0.174 Oct-2014 3.4 0.000180425 3.3 0.1 0.01 534877 0.2 -0.1 -0.356 Apr-2015 3.3 0.000222574 3.3 0.1 0.00 828742 0.2 -0.2 -0.396 Oct-2015 2.0 0.000163449 3.3 -1.2 1.50 1195421 0.5 -0.7 -1.153 Apr-2016 3.1 0.000291379 3.3 -0.2 0.02 1629077 0.6 -1.1 -1.711 Oct-2016 3.7 0.000397365 3.2 0.5 0.20 2126793 1.1 -1.2 -2.327 b͆ =-1.95415E-05 sum ri2 sum (t-t̅)2 sx =0.57 5.24 13579202 W =0.896 greater than 0.851 t̅ =41197 normal assumption not rejected s2t =848700.1176 x̅ =3.3 s2e =0.349131164 se(b͆) =0.000160346 tb =-0.121870944 tcp =2.602 tcp > tb > -tcp ==> insufficient evidence of trend Reference: USEPA Unified Guidance, 17.3.1 REI Consultants, Inc. ** PO Box 286 ** Beaver, WV 25813