0501_AsheCoMSWLF_May2015LeachateMR_DIN27417_20160308

Ashe County Subtitle D Lined MSWLF
Crumpler, North Carolina
October 12, 2014 through May 13, 2015
MESCO Project Number: G15005.0
Semi-Annual Leachate Recirculation Report
Prepared for
Municipal Engineering Services Company, P.A.Garner and Boone, North Carolina
Permit Number: 05-01
P.O. Box 97
Garner, NC 27529
License Number: C-0281
March 7, 2016
Mr. Ervin Lane
Solid Waste Section
Division of Waste Management
North Carolina Department of Environment and Natural Resources
401 Oberlin Road, Suite 150
Raleigh, NC 27605
Re: Semi-Annual Leachate Recirculation Report
Ashe County Subtitle D Lined MSWLF
Permit No. 05-01
MESCO Project No. G14005.0
Reporting Period: October 12, 2014-May 13, 2015
Dear Mr. Lane:
The Ashe County Subtitle D Lined MSWLF located near Crumpler NC, currently operating under permit #05-01 is
permitted to recirculate leachate onto existing MSWLF Phases. During the period between October 12, 2014
through May 13, 2015 leachate was reported to be recirculated into the Phase 4 lined landfill and disposed of at
Waste Water Treatment Plants (WWTP).
In accordance with the permit requirements the volume of leachate recirculated, the amount of precipitation
reported, the analytical results of leachate sampling and the amount of leachate disposed of off site are included
here and in the attachments. This leachate recirculation report is submitted semi-annually with the dates
corresponding to the facility's established routine semi-annual water quality detection monitoring program. The
pertinent information for this semi-annual event is found below:
●Leachate recirculated into Lined Landfill: 324,000 gallons
●Leachate disposed of at WWTPs: 922,892 gallons
●Amount of precipitation: 19.17 inches
●Leachate analytical sampling date: May 13, 2015
The next semi-annual sampling event was performed in October 2015 and the report will be submitted upon
completion. If you have any questions or comments regarding this report, please contact us by phone at (919) 772-
5393 or by email at [e-mail].
Sincerely,
MUNICIPAL ENGINEERING SERVICES CO., P.A.
Jonathan Pfohl
Environmental Specialist
Enclosures
cc: Mr. Scott Hurley
Ashe County

Tables
Table 1
Daily Precipitation & Leachate Recirculation Data as Recorded at Facility
October 12, 2014 through May 13, 2015
10/12/14 0.00 0 0 12/2/14 0.50 9,091 0 1/22/15 0.00 0 0 3/14/15 0.10 0 0 5/4/15 0.00 0 0
10/13/14 0.75 0 0 12/3/14 0.10 12,084 0 1/23/15 0.20 0 9,000 3/15/15 0.00 0 0 5/5/15 0.00 0 0
10/14/14 0.14 0 0 12/4/14 0.10 9,091 0 1/24/15 0.00 0 0 3/16/15 0.00 23,099 0 5/6/15 0.10 0 0
10/15/14 2.25 16,665 0 12/5/14 0.00 5,796 0 1/25/15 0.00 0 0 3/17/15 0.00 0 0 5/7/15 0.00 0 0
10/16/14 0.40 0 0 12/6/14 0.25 0 0 1/26/15 0.10 0 0 3/18/15 0.00 17,355 0 5/8/15 0.10 0 0
10/17/14 0.00 5,781 0 12/7/14 0.00 0 0 1/27/15 0.00 11,929 0 3/19/15 0.10 9,051 0 5/9/15 0.00 0 0
10/18/14 0.00 0 0 12/8/14 0.00 22,870 0 1/28/15 0.00 8,993 42,000 3/20/15 0.00 11,553 0 5/10/15 0.00 0 0
10/19/14 0.00 0 0 12/9/14 0.00 17,279 0 1/29/15 0.00 0 0 3/21/15 0.00 0 0 5/11/15 0.00 0 15,000
10/20/14 0.00 17,301 0 12/10/14 0.00 35,115 0 1/30/15 0.00 5,946 0 3/22/15 0.00 0 0 5/12/15 0.10 0 0
10/21/14 0.00 0 0 12/11/14 0.00 11,816 12,000 1/31/15 0.00 0 0 3/23/15 0.10 0 0 5/13/15 0.00 2,966 15,000
10/22/14 0.00 0 0 12/12/14 0.00 6,035 18,000 2/1/15 0.00 0 0 3/24/15 0.00 17,275 0 SubTotal 922,892 324,000
10/23/14 0.00 0 0 12/13/14 0.00 0 0 2/2/15 0.10 17,119 0 3/25/15 0.00 0 0 TOTAL 19.17
10/24/14 0.00 11,493 0 12/14/14 0.00 0 0 2/3/15 0.00 0 0 3/26/15 0.10 5,776 0
10/25/14 0.00 0 0 12/15/14 0.00 12,180 0 2/4/15 0.00 0 0 3/27/15 0.00 0 0
10/26/14 0.00 0 0 12/16/14 0.10 3,040 18,000 2/5/15 0.00 0 0 3/28/15 0.00 0 0
10/27/14 0.00 17,365 0 12/17/14 0.00 0 0 2/6/15 0.00 0 0 3/29/15 0.00 0 0
10/28/14 0.00 17,351 0 12/18/14 0.00 0 0 2/7/15 0.00 0 0 3/30/15 0.00 0 0
10/29/14 0.10 0 0 12/19/14 0.00 0 0 2/8/15 0.00 0 0 3/31/15 0.00 0 0
10/30/14 0.00 5,784 0 12/20/14 0.00 0 0 2/9/15 0.00 0 12,000 4/1/15 0.00 0 0
10/31/14 0.28 0 6,000 12/21/14 0.00 0 0 2/10/15 0.10 0 0 4/2/15 0.00 0 0
11/1/14 0.00 0 0 12/22/14 0.00 0 0 2/11/15 0.10 0 0 4/3/15 0.10 0 0
11/2/14 0.00 0 0 12/23/14 0.30 0 0 2/12/15 0.00 0 0 4/4/15 0.00 0 0
11/3/14 0.30 0 0 12/24/14 1.00 11,536 0 2/13/15 0.20 0 0 4/5/15 0.00 0 0
11/4/14 0.00 0 0 12/25/14 0.00 0 0 2/14/15 0.00 0 0 4/6/15 0.00 0 0
11/5/14 0.00 0 9,000 12/26/14 0.00 5,784 18,000 2/15/15 0.00 0 0 4/7/15 0.10 0 0
11/6/14 0.30 0 0 12/27/14 0.00 0 0 2/16/15 0.20 0 0 4/8/15 0.40 0 0
11/7/14 0.00 28,895 0 12/28/14 0.00 0 0 2/17/15 0.40 0 0 4/9/15 0.00 0 0
11/8/14 0.00 0 0 12/29/14 0.10 0 0 2/18/15 0.00 0 0 4/10/15 1.00 17,322 18,000
11/9/14 0.00 0 0 12/30/14 0.00 9,385 0 2/19/15 0.00 0 0 4/11/15 0.00 0 0
11/10/14 0.00 0 3,000 12/31/14 0.00 9,411 0 2/20/15 0.10 0 0 4/12/15 0.00 0 0
11/11/14 0.00 0 0 1/1/15 0.00 0 0 2/21/15 0.30 0 0 4/13/15 0.10 23,206 0
11/12/14 0.00 0 0 1/2/15 0.00 0 0 2/22/15 0.00 0 0 4/14/15 0.00 32,400 9,000
11/13/14 0.00 0 0 1/3/15 0.00 0 0 2/23/15 0.00 0 0 4/15/15 0.40 26,095 6,000
11/14/14 0.00 0 0 1/4/15 0.00 0 0 2/24/15 0.40 0 0 4/16/15 0.25 17,305 0
11/15/14 0.00 0 0 1/5/15 0.20 0 0 2/25/15 0.10 0 0 4/17/15 0.00 3,007 0
11/16/14 0.00 0 0 1/6/15 0.10 12,206 0 2/26/15 0.40 0 0 4/18/15 0.00 0 0
11/17/14 0.30 0 0 1/7/15 0.00 0 0 2/27/15 0.00 0 0 4/19/15 0.00 0 0
11/18/14 0.00 0 0 1/8/15 0.00 0 0 2/28/15 0.00 0 0 4/20/15 2.55 23,153 0
11/19/14 0.00 0 0 1/9/15 0.00 0 0 3/1/15 0.00 0 0 4/21/15 0.35 27,955 0
11/20/14 0.00 11,599 0 1/10/15 0.00 0 0 3/2/15 0.00 0 0 4/22/15 0.00 17,425 0
11/21/14 0.00 12,223 0 1/11/15 0.00 0 0 3/3/15 0.00 0 0 4/23/15 0.00 23,206 0
11/22/14 0.00 0 0 1/12/15 0.10 22,770 0 3/4/15 0.10 0 0 4/24/15 0.00 11,544 0
11/23/14 0.00 0 0 1/13/15 0.00 9,296 9,000 3/5/15 0.40 0 12,000 4/25/15 0.00 0 0
11/24/14 1.25 0 0 1/14/15 0.00 24,092 0 3/6/15 0.00 0 0 4/26/15 0.00 0 0
11/25/14 0.00 0 0 1/15/15 0.00 29,752 0 3/7/15 0.00 0 0 4/27/15 0.30 9,047 0
11/26/14 0.20 0 0 1/16/15 0.00 3,141 0 3/8/15 0.00 0 0 4/28/15 0.00 0 0
11/27/14 0.00 0 0 1/17/15 0.00 0 0 3/9/15 0.00 11,577 0 4/29/15 0.00 9,039 0
11/28/14 0.00 0 0 1/18/15 0.10 0 0 3/10/15 0.00 32,731 27,000 4/30/15 0.00 0 0
11/29/14 0.00 0 0 1/19/15 0.00 3,143 21,000 3/11/15 0.10 29,240 18,000 5/1/15 0.20 6,080 15,000
11/30/14 0.00 0 0 1/20/15 0.00 12,672 0 3/12/15 0.00 0 12,000 5/2/15 0.10 0 0
12/1/14 0.00 12,103 0 1/21/15 0.00 0 0 3/13/15 0.10 17,353 0 5/3/15 0.00 0 0
Recirculated into Landfill (gal)WWTPs (gal)
Recirculated into Landfill (gal)
1,246,892
Date Rainfall (In) WWTPs (gal)
Recirculated into Landfill (gal)Date Rainfall (In)Rainfall (In)WWTPs (gal)Date Rainfall (In)WWTPs (gal)WWTPs (gal)
Recirculated into Landfill (gal)Date
Recirculated into Landfill (gal)Date Rainfall (In)
Ashe County Subtitle D Lined Landfill Page 1 of 1
Ashe County Subtitle D Lined MSWLF Page 1 of 1
Table 2
Detections in Leachate Samples above SWSL
May 13, 2015
Result Unit
LAGOON Toluene 5/13/15 1.5 0.26 1 600 1000
LAGOON Naphthalene 5/13/15 3.5J 0.24 10 21 NE
LAGOON Benzene 5/13/15 8.4 0.25 1 1 5
LAGOON 5/13/15 11.7 0.3 1 550 700
LAGOON 5/13/15 3 0.33 1 6 75
LAGOON Xylene (Total)5/13/15 19.1 0.66 5 530 10000
LAGOON Barium, total 5/13/15 206 2.5 100 700 1300
LAGOON Vanadium, total 5/13/15 17.5J 2.5 25 NE 3.5 NE
LAGOON Thallium, total 5/13/15 7 5 5.5 NE 0.28 2
LAGOON Phosphorus 5/13/15 281 25 50 NE NE
LAGOON BOD, 5 day 5/13/15 93000 2000 2000 NE NE
LAGOON COD 5/13/15 176000 25000 50000 NE NE
6 MCL = Primary Drinking Water Standard (not currently applicable for regulatory comparisons)
BOLD = Concentration > 2L, 2B or MCL Standard
Sample
ID Parameter Name 1 Sample
Date MDL 2 SWSL 3 2L 4 GWP 5 MCL 6
ug/L
ug/L
ug/L
Ethylbenzene ug/L
1,4-Dichlorobenzene ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1 Table contains constituents detected at or above SWSL, GWP, 2L, or 2B
2 MDL = Method Detection Limit
3 SWSL = Solid Waste Section Reporting Limit
4 2L = North Carolina 15A NCAC 2L Groundwater Quality Standard
5 GWP = Groundwater Protection Standard
Appendix A
Laboratory Analysis Reports
Chains of Custody
#=CL#
May 28, 2015
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92249931
92249931
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
PO Box 97
Garner, NC 27529
ASHE CO LINED MSWLF LAGOON
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on May 14, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 26
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 26
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Lab ID Sample ID Matrix Date Collected Date Received
92249931001 LAGOON Water 05/13/15 16:00 05/14/15 13:35
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 26
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92249931001 LAGOON EPA 6010 16 PASI-AJMW
EPA 7470 1 PASI-AHVK
EPA 8260 67 PASI-CCCL
SM 5210B 1 PASI-AERK
EPA 300.0 1 PASI-AAES2
EPA 353.2 1 PASI-AEWS
EPA 365.1 1 PASI-AJDA
SM 5220D 1 PASI-AMAB
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Sample:LAGOON Lab ID:92249931001 Collected:05/13/15 16:00 Received:05/14/15 13:35 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 05/20/15 02:13 7440-36-005/18/15 13:506.0 3.8 1
Arsenic ND ug/L 05/20/15 02:13 7440-38-205/18/15 13:5010.0 2.5 1
Barium 206 ug/L 05/20/15 02:13 7440-39-305/18/15 13:501002.5 1
Beryllium ND ug/L 05/20/15 02:13 7440-41-705/18/15 13:501.0 0.50 1
Cadmium ND ug/L 05/20/15 02:13 7440-43-905/18/15 13:501.0 0.50 1
Chromium 3.0J ug/L 05/20/15 02:13 7440-47-305/18/15 13:5010.0 2.5 1
Cobalt 2.6J ug/L 05/20/15 02:13 7440-48-405/18/15 13:5010.0 2.5 1
Copper ND ug/L 05/20/15 02:13 7440-50-805/18/15 13:5010.0 2.5 1
Lead 3.2J ug/L 05/20/15 02:13 7439-92-105/18/15 13:5010.0 2.5 1
Nickel 4.3J ug/L 05/20/15 02:13 7440-02-005/18/15 13:5050.0 2.5 1
Selenium ND ug/L 05/20/15 02:13 7782-49-205/18/15 13:5010.0 5.0 1
Silver 2.9J ug/L 05/20/15 02:13 7440-22-405/18/15 13:5010.0 2.5 1
Thallium 7.0 ug/L 05/20/15 02:13 7440-28-005/18/15 13:505.5 5.0 1
Tin ND ug/L 05/20/15 02:13 7440-31-505/18/15 13:501002.5 1
Vanadium 17.5J ug/L 05/20/15 02:13 7440-62-205/18/15 13:5025.0 2.5 1
Zinc ND ug/L 05/20/15 02:13 7440-66-605/18/15 13:5010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 05/22/15 14:30 7439-97-605/20/15 12:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 05/26/15 15:41 67-64-110010.0 1
Acetonitrile ND ug/L 05/26/15 15:41 75-05-855.0 2.2 1
Acrolein ND ug/L 05/26/15 15:41 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 05/26/15 15:41 107-13-12001.9 1
Allyl chloride ND ug/L 05/26/15 15:41 107-05-110.0 1.5 1
Benzene 8.4 ug/L 05/26/15 15:41 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 05/26/15 15:41 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 05/26/15 15:41 75-27-41.0 0.18 1
Bromoform ND ug/L 05/26/15 15:41 75-25-23.0 0.26 1
Bromomethane ND ug/L 05/26/15 15:41 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 05/26/15 15:41 78-93-31000.96 1
Carbon disulfide ND ug/L 05/26/15 15:41 75-15-01001.2 1
Carbon tetrachloride ND ug/L 05/26/15 15:41 56-23-51.0 0.25 1
Chlorobenzene 1.2J ug/L 05/26/15 15:41 108-90-73.0 0.23 1
Chloroethane ND ug/L 05/26/15 15:41 75-00-310.0 0.54 1
Chloroform ND ug/L 05/26/15 15:41 67-66-35.0 0.14 1
Chloromethane 0.18J ug/L 05/26/15 15:41 74-87-31.0 0.11 1
Chloroprene ND ug/L 05/26/15 15:41 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 05/26/15 15:41 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 05/26/15 15:41 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 05/26/15 15:41 106-93-41.0 0.27 1
Dibromomethane ND ug/L 05/26/15 15:41 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 05/26/15 15:41 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 05/26/15 15:41 541-73-15.0 0.24 1
1,4-Dichlorobenzene 3.0 ug/L 05/26/15 15:41 106-46-71.0 0.33 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/28/2015 03:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Sample:LAGOON Lab ID:92249931001 Collected:05/13/15 16:00 Received:05/14/15 13:35 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,4-Dichloro-2-butene ND ug/L 05/26/15 15:41 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 05/26/15 15:41 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 05/26/15 15:41 75-34-35.0 0.32 1
1,2-Dichloroethane 0.19J ug/L 05/26/15 15:41 107-06-21.0 0.12 1
1,1-Dichloroethene ND ug/L 05/26/15 15:41 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 0.91J ug/L 05/26/15 15:41 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 05/26/15 15:41 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 05/26/15 15:41 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 05/26/15 15:41 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 05/26/15 15:41 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 05/26/15 15:41 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 05/26/15 15:41 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 05/26/15 15:41 10061-02-61.0 0.26 1
Ethylbenzene 11.7 ug/L 05/26/15 15:41 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 05/26/15 15:41 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 05/26/15 15:41 87-68-310.0 0.71 1
2-Hexanone ND ug/L 05/26/15 15:41 591-78-650.0 0.46 1
Iodomethane ND ug/L 05/26/15 15:41 74-88-410.0 0.32 1
Isobutanol ND ug/L 05/26/15 15:41 78-83-110035.0 1
Methacrylonitrile ND ug/L 05/26/15 15:41 126-98-71000.93 1
Methylene Chloride ND ug/L 05/26/15 15:41 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 05/26/15 15:41 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 05/26/15 15:41 108-10-11000.33 1
Naphthalene 3.5J ug/L 05/26/15 15:41 91-20-310.0 0.24 1
Propionitrile ND ug/L 05/26/15 15:41 107-12-01503.6 1
Styrene ND ug/L 05/26/15 15:41 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 05/26/15 15:41 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 05/26/15 15:41 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 05/26/15 15:41 127-18-41.0 0.46 1
Toluene 1.5 ug/L 05/26/15 15:41 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 05/26/15 15:41 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 05/26/15 15:41 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 05/26/15 15:41 79-00-51.0 0.29 1
Trichloroethene ND ug/L 05/26/15 15:41 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 05/26/15 15:41 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 05/26/15 15:41 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 05/26/15 15:41 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 05/26/15 15:41 75-01-41.0 0.62 1
Xylene (Total)19.1 ug/L 05/26/15 15:41 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)101 %05/26/15 15:41 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %05/26/15 15:41 17060-07-070-130 1
Toluene-d8 (S)101 %05/26/15 15:41 2037-26-570-130 1
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day 93000 ug/L 05/19/15 22:20 B205/15/15 03:20200020001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/28/2015 03:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Sample:LAGOON Lab ID:92249931001 Collected:05/13/15 16:00 Received:05/14/15 13:35 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 4110J ug/L 05/28/15 00:00 14808-79-825000010001
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate ND ug/L 05/15/15 14:551000010.0 1
Analytical Method: EPA 365.1365.1 Phosphorus, Total
Phosphorus 281 ug/L 05/26/15 14:29 7723-14-050.0 25.0 1
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand 176000 ug/L 05/20/15 16:3550000250002
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/28/2015 03:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/7837
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92249931001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1462214
Associated Lab Samples:92249931001
Matrix:Water
Analyzed
Mercury ug/L ND 0.20 05/22/15 13:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1462215LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.62.5 104 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1462216MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92249822006
1462217
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 78 75-12580 2 252.5ND 2.0 2.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/28/2015 03:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/18501
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92249931001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1461460
Associated Lab Samples:92249931001
Matrix:Water
Analyzed
Antimony ug/L ND 6.0 05/20/15 00:37
Arsenic ug/L ND 10.0 05/20/15 00:37
Barium ug/L ND 100 05/20/15 00:37
Beryllium ug/L ND 1.0 05/20/15 00:37
Cadmium ug/L ND 1.0 05/20/15 00:37
Chromium ug/L ND 10.0 05/20/15 00:37
Cobalt ug/L ND 10.0 05/20/15 00:37
Copper ug/L ND 10.0 05/20/15 00:37
Lead ug/L ND 10.0 05/20/15 00:37
Nickel ug/L ND 50.0 05/20/15 00:37
Selenium ug/L ND 10.0 05/20/15 00:37
Silver ug/L ND 10.0 05/20/15 00:37
Thallium ug/L ND 5.5 05/20/15 00:37
Tin ug/L ND 100 05/20/15 00:37
Vanadium ug/L ND 25.0 05/20/15 00:37
Zinc ug/L ND 10.0 05/20/15 00:37
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1461461LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 524500 105 80-120
Arsenic ug/L 520500 104 80-120
Barium ug/L 510500 102 80-120
Beryllium ug/L 515500 103 80-120
Cadmium ug/L 521500 104 80-120
Chromium ug/L 506500 101 80-120
Cobalt ug/L 513500 103 80-120
Copper ug/L 501500 100 80-120
Lead ug/L 509500 102 80-120
Nickel ug/L 511500 102 80-120
Selenium ug/L 532500 106 80-120
Silver ug/L 229250 92 80-120
Thallium ug/L 477500 95 80-120
Tin ug/L 498500 100 80-120
Vanadium ug/L 494500 99 80-120
Zinc ug/L 524500 105 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/28/2015 03:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1461462MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92249918001
1461463
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 96 75-12582 17 25500ND482408
Arsenic ug/L 500 96 75-12582 16 25500ND481409
Barium ug/L 500 94 75-12579 12 25500201669594
Beryllium ug/L 500 96 75-12581 17 25500ND482405
Cadmium ug/L 500 96 75-12582 17 25500ND482408
Chromium ug/L 500 94 75-12579 17 25500ND471397
Cobalt ug/L 500 94 75-12579 17 25500ND469396
Copper ug/L 500 93 75-12579 17 25500ND467394
Lead ug/L 500 93 75-12579 17 25500ND464393
Nickel ug/L 500 93 75-12579 17 255003.2J 468 396
Selenium ug/L 500 97 75-12583 16 25500ND486416
Silver ug/L M12508475-12571 17 25250ND209176
Thallium ug/L M15008775-12573 17 25500ND436368
Tin ug/L 500 92 75-12578 17 25500ND460388
Vanadium ug/L 500 92 75-12578 17 25500ND462391
Zinc ug/L 500 96 75-12581 17 255005.7J 484 409
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/28/2015 03:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/31816
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92249931001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1466642
Associated Lab Samples:92249931001
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 5.0 05/26/15 13:34
1,1,1-Trichloroethane ug/L ND 1.0 05/26/15 13:34
1,1,2,2-Tetrachloroethane ug/L ND 3.0 05/26/15 13:34
1,1,2-Trichloroethane ug/L ND 1.0 05/26/15 13:34
1,1-Dichloroethane ug/L ND 5.0 05/26/15 13:34
1,1-Dichloroethene ug/L ND 5.0 05/26/15 13:34
1,1-Dichloropropene ug/L ND 5.0 05/26/15 13:34
1,2,3-Trichloropropane ug/L ND 1.0 05/26/15 13:34
1,2,4-Trichlorobenzene ug/L ND 10.0 05/26/15 13:34
1,2-Dibromo-3-chloropropane ug/L ND 13.0 05/26/15 13:34
1,2-Dibromoethane (EDB)ug/L ND 1.0 05/26/15 13:34
1,2-Dichlorobenzene ug/L ND 5.0 05/26/15 13:34
1,2-Dichloroethane ug/L ND 1.0 05/26/15 13:34
1,2-Dichloropropane ug/L ND 1.0 05/26/15 13:34
1,3-Dichlorobenzene ug/L ND 5.0 05/26/15 13:34
1,3-Dichloropropane ug/L ND 1.0 05/26/15 13:34
1,4-Dichlorobenzene ug/L ND 1.0 05/26/15 13:34
2,2-Dichloropropane ug/L ND 15.0 05/26/15 13:34
2-Butanone (MEK)ug/L ND 100 05/26/15 13:34
2-Hexanone ug/L ND 50.0 05/26/15 13:34
4-Methyl-2-pentanone (MIBK)ug/L ND 100 05/26/15 13:34
Acetone ug/L ND 100 05/26/15 13:34
Acetonitrile ug/L ND 55.0 05/26/15 13:34
Acrolein ug/L ND 53.0 05/26/15 13:34
Acrylonitrile ug/L ND 200 05/26/15 13:34
Allyl chloride ug/L ND 10.0 05/26/15 13:34
Benzene ug/L ND 1.0 05/26/15 13:34
Bromochloromethane ug/L ND 3.0 05/26/15 13:34
Bromodichloromethane ug/L ND 1.0 05/26/15 13:34
Bromoform ug/L ND 3.0 05/26/15 13:34
Bromomethane ug/L ND 10.0 05/26/15 13:34
Carbon disulfide ug/L ND 100 05/26/15 13:34
Carbon tetrachloride ug/L ND 1.0 05/26/15 13:34
Chlorobenzene ug/L ND 3.0 05/26/15 13:34
Chloroethane ug/L ND 10.0 05/26/15 13:34
Chloroform ug/L ND 5.0 05/26/15 13:34
Chloromethane ug/L ND 1.0 05/26/15 13:34
Chloroprene ug/L ND 20.0 05/26/15 13:34
cis-1,2-Dichloroethene ug/L ND 5.0 05/26/15 13:34
cis-1,3-Dichloropropene ug/L ND 1.0 05/26/15 13:34
Dibromochloromethane ug/L ND 3.0 05/26/15 13:34
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/28/2015 03:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1466642
Associated Lab Samples:92249931001
Matrix:Water
Analyzed
Dibromomethane ug/L ND 10.0 05/26/15 13:34
Dichlorodifluoromethane ug/L ND 5.0 05/26/15 13:34
Ethyl methacrylate ug/L ND 10.0 05/26/15 13:34
Ethylbenzene ug/L ND 1.0 05/26/15 13:34
Hexachloro-1,3-butadiene ug/L ND 10.0 05/26/15 13:34
Iodomethane ug/L ND 10.0 05/26/15 13:34
Isobutanol ug/L ND 100 05/26/15 13:34
Methacrylonitrile ug/L ND 100 05/26/15 13:34
Methyl methacrylate ug/L ND 30.0 05/26/15 13:34
Methylene Chloride ug/L ND 1.0 05/26/15 13:34
Naphthalene ug/L ND 10.0 05/26/15 13:34
Propionitrile ug/L ND 150 05/26/15 13:34
Styrene ug/L ND 1.0 05/26/15 13:34
Tetrachloroethene ug/L ND 1.0 05/26/15 13:34
Toluene ug/L ND 1.0 05/26/15 13:34
trans-1,2-Dichloroethene ug/L ND 5.0 05/26/15 13:34
trans-1,3-Dichloropropene ug/L ND 1.0 05/26/15 13:34
trans-1,4-Dichloro-2-butene ug/L ND 100 05/26/15 13:34
Trichloroethene ug/L ND 1.0 05/26/15 13:34
Trichlorofluoromethane ug/L ND 1.0 05/26/15 13:34
Vinyl acetate ug/L ND 50.0 05/26/15 13:34
Vinyl chloride ug/L ND 1.0 05/26/15 13:34
Xylene (Total)ug/L ND 5.0 05/26/15 13:34
1,2-Dichloroethane-d4 (S)%101 70-130 05/26/15 13:34
4-Bromofluorobenzene (S)%98 70-130 05/26/15 13:34
Toluene-d8 (S)%99 70-130 05/26/15 13:34
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1466643LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.250 100 80-125
1,1,1-Trichloroethane ug/L 49.250 98 71-129
1,1,2,2-Tetrachloroethane ug/L 43.550 87 79-124
1,1,2-Trichloroethane ug/L 45.250 90 85-125
1,1-Dichloroethane ug/L 44.450 89 73-126
1,1-Dichloroethene ug/L 47.850 96 66-135
1,1-Dichloropropene ug/L 47.850 96 74-135
1,2,3-Trichloropropane ug/L 42.850 86 75-130
1,2,4-Trichlorobenzene ug/L 47.150 94 75-134
1,2-Dibromo-3-chloropropane ug/L 43.850 88 71-133
1,2-Dibromoethane (EDB)ug/L 48.050 96 83-124
1,2-Dichlorobenzene ug/L 45.650 91 80-133
1,2-Dichloroethane ug/L 42.950 86 67-128
1,2-Dichloropropane ug/L 43.450 87 75-132
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/28/2015 03:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1466643LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 47.650 95 77-130
1,3-Dichloropropane ug/L 43.550 87 76-131
1,4-Dichlorobenzene ug/L 46.350 93 78-130
2,2-Dichloropropane ug/L 46.550 93 40-160
2-Butanone (MEK)ug/L 90.8J100 91 61-144
2-Hexanone ug/L 92.1100 92 68-143
4-Methyl-2-pentanone (MIBK)ug/L 90.1J100 90 72-135
Acetone ug/L 92.0J100 92 48-146
Acetonitrile ug/L 422500 84 62-150
Acrolein ug/L 252250 101 24-160
Acrylonitrile ug/L 212250 85 40-160
Allyl chloride ug/L 43.550 87 66-137
Benzene ug/L 47.050 94 80-125
Bromochloromethane ug/L 45.950 92 71-125
Bromodichloromethane ug/L 45.650 91 78-124
Bromoform ug/L 40.250 80 71-128
Bromomethane ug/L 52.050 104 40-160
Carbon disulfide ug/L 48.0J50 96 50-160
Carbon tetrachloride ug/L 53.850 108 69-131
Chlorobenzene ug/L 44.450 89 81-122
Chloroethane ug/L 43.750 87 39-148
Chloroform ug/L 45.250 90 73-127
Chloromethane ug/L 42.450 85 44-146
Chloroprene ug/L 50.950 102 75-145
cis-1,2-Dichloroethene ug/L 44.450 89 74-124
cis-1,3-Dichloropropene ug/L 47.350 95 72-132
Dibromochloromethane ug/L 43.850 88 78-125
Dibromomethane ug/L 45.550 91 82-120
Dichlorodifluoromethane ug/L 41.350 83 34-157
Ethyl methacrylate ug/L 49.050 98 82-121
Ethylbenzene ug/L 46.850 94 79-121
Hexachloro-1,3-butadiene ug/L 50.850 102 72-131
Iodomethane ug/L 71.6100 72 39-154
Isobutanol ug/L 9981000 100 34-160
Methacrylonitrile ug/L 449500 90 74-134
Methyl methacrylate ug/L 52.050 104 84-124
Methylene Chloride ug/L 45.550 91 64-133
Naphthalene ug/L 48.750 97 73-133
Propionitrile ug/L 457500 91 73-140
Styrene ug/L 45.850 92 84-126
Tetrachloroethene ug/L 48.950 98 78-122
Toluene ug/L 46.850 94 80-121
trans-1,2-Dichloroethene ug/L 45.650 91 71-127
trans-1,3-Dichloropropene ug/L 47.250 94 69-141
trans-1,4-Dichloro-2-butene ug/L 78.8J50 158 40-160
Trichloroethene ug/L 46.650 93 78-122
Trichlorofluoromethane ug/L 42.250 84 53-137
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/28/2015 03:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1466643LABORATORY CONTROL SAMPLE:
LCSSpike
Vinyl acetate ug/L 106100 106 40-160
Vinyl chloride ug/L 44.350 89 58-137
Xylene (Total)ug/L 141150 94 81-126
1,2-Dichloroethane-d4 (S)%93 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1466644MATRIX SPIKE SAMPLE:
MSSpike
Result
92249927009
1,1,1,2-Tetrachloroethane ug/L 18.420 92 70-130ND
1,1,1-Trichloroethane ug/L 22.520 112 70-130ND
1,1,2,2-Tetrachloroethane ug/L 17.720 88 70-130ND
1,1,2-Trichloroethane ug/L 18.720 93 70-130ND
1,1-Dichloroethane ug/L 19.720 99 70-130ND
1,1-Dichloroethene ug/L 21.920 109 70-166ND
1,1-Dichloropropene ug/L 22.020 110 70-130ND
1,2,3-Trichloropropane ug/L 17.520 87 70-130ND
1,2,4-Trichlorobenzene ug/L 18.520 93 70-130ND
1,2-Dibromo-3-chloropropane ug/L 17.020 85 70-130ND
1,2-Dibromoethane (EDB)ug/L 19.820 99 70-130ND
1,2-Dichlorobenzene ug/L 18.420 92 70-130ND
1,2-Dichloroethane ug/L 18.520 92 70-130ND
1,2-Dichloropropane ug/L 19.220 96 70-130ND
1,3-Dichlorobenzene ug/L 19.520 98 70-130ND
1,3-Dichloropropane ug/L 18.520 93 70-130ND
1,4-Dichlorobenzene ug/L 20.320 97 70-1300.91J
2,2-Dichloropropane ug/L 20.620 103 70-130ND
2-Butanone (MEK)ug/L 37.9J40 95 70-130ND
2-Hexanone ug/L 36.2J40 90 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 37.3J40 93 70-130ND
Acetone ug/L 38.2J40 96 70-130ND
Acetonitrile ug/L 194200 97 70-130ND
Acrolein ug/L 90.0100 90 70-130ND
Acrylonitrile ug/L 93.1J100 93 70-130ND
Allyl chloride ug/L 18.520 92 70-130ND
Benzene ug/L 20.720 100 70-1480.61J
Bromochloromethane ug/L 21.120 106 70-130ND
Bromodichloromethane ug/L 19.420 97 70-130ND
Bromoform ug/L 16.020 80 70-130ND
Bromomethane ug/L 15.220 76 70-130ND
Carbon disulfide ug/L 21.5J20 107 70-130ND
Carbon tetrachloride ug/L 22.420 112 70-130ND
Chlorobenzene ug/L 19.620 98 70-146ND
Chloroethane ug/L 20.220 101 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/28/2015 03:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1466644MATRIX SPIKE SAMPLE:
MSSpike
Result
92249927009
Chloroform ug/L 19.920 100 70-130ND
Chloromethane ug/L 18.720 94 70-130ND
Chloroprene ug/L 22.920 115 70-130ND
cis-1,2-Dichloroethene ug/L 20.720 101 70-1300.46J
cis-1,3-Dichloropropene ug/L 19.620 98 70-130ND
Dibromochloromethane ug/L 17.620 88 70-130ND
Dibromomethane ug/L 19.620 98 70-130ND
Dichlorodifluoromethane ug/L 20.220 96 70-1301.0J
Ethyl methacrylate ug/L 19.020 95 70-130ND
Ethylbenzene ug/L 20.620 103 70-130ND
Hexachloro-1,3-butadiene ug/L 19.820 99 70-130ND
Iodomethane ug/L 27.5 M1406970-130ND
Isobutanol ug/L 759 M140019070-130ND
Methacrylonitrile ug/L 197200 98 70-130ND
Methyl methacrylate ug/L 20.6J20 103 70-130ND
Methylene Chloride ug/L 22.920 114 70-130ND
Naphthalene ug/L 18.020 90 70-130ND
Propionitrile ug/L 192200 96 70-130ND
Styrene ug/L 20.120 101 70-130ND
Tetrachloroethene ug/L 21.020 104 70-130ND
Toluene ug/L 20.520 102 70-155ND
trans-1,2-Dichloroethene ug/L 21.020 105 70-130ND
trans-1,3-Dichloropropene ug/L 18.420 92 70-130ND
trans-1,4-Dichloro-2-butene ug/L 17.2J20 86 70-130ND
Trichloroethene ug/L 21.520 106 69-151ND
Trichlorofluoromethane ug/L 20.620 103 70-130ND
Vinyl acetate ug/L 39.7J40 99 70-130ND
Vinyl chloride ug/L 20.620 101 70-130ND
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92249927011
1466645SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,1-Dichloropropene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2,4-Trichlorobenzene ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/28/2015 03:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92249927011
1466645SAMPLE DUPLICATE:
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichlorobenzene ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2,2-Dichloropropane ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acetonitrile ug/L ND 30ND
Acrolein ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Allyl chloride ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
Chloroprene ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Ethyl methacrylate ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Hexachloro-1,3-butadiene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Isobutanol ug/L ND 30ND
Methacrylonitrile ug/L ND 30ND
Methyl methacrylate ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Naphthalene ug/L ND 30ND
Propionitrile ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/28/2015 03:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92249927011
1466645SAMPLE DUPLICATE:
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%102 399
4-Bromofluorobenzene (S)%101 1100
Toluene-d8 (S)%100 0100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/28/2015 03:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/37482
SM 5210B
SM 5210B
5210B BOD, 5 day
Associated Lab Samples:92249931001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1460046
Associated Lab Samples:92249931001
Matrix:Water
Analyzed
BOD, 5 day ug/L ND 2000 05/19/15 22:20
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1460047LABORATORY CONTROL SAMPLE:
LCSSpike
BOD, 5 day ug/L 202000198000 102 84.6-115.4
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92249594001
1460048SAMPLE DUPLICATE:
BOD, 5 day ug/L 14100 9 1015.5 mg/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/28/2015 03:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/23066
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples:92249931001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1469165
Associated Lab Samples:92249931001
Matrix:Water
Analyzed
Sulfate ug/L ND 250000 05/27/15 20:50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1469166LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 19100J20000 96 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1469167MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92249822005
1469168
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 98 90-11094 1 102000076.2 mg/L 95800J 95000J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1469169MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92250431002
1469170
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L M6200002090-110-32 1 10200001880 mg/L 1890000
J
1880000
J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/28/2015 03:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/22952
EPA 353.2
EPA 353.2
353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples:92249931001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1460631
Associated Lab Samples:92249931001
Matrix:Water
Analyzed
Nitrogen, Nitrate ug/L ND 20.0 05/15/15 14:52
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1460632LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Nitrate ug/L 25302500 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1460633MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92249931001
1460634
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Nitrate ug/L 2500 105 90-110105 0 102500ND26202620
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/28/2015 03:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/23053
EPA 365.1
EPA 365.1
365.1 Phosphorus, Total
Associated Lab Samples:92249931001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1467409
Associated Lab Samples:92249931001
Matrix:Water
Analyzed
Phosphorus ug/L ND 50.0 05/26/15 14:04
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1467410LABORATORY CONTROL SAMPLE:
LCSSpike
Phosphorus ug/L 26502500 106 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1467411MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92250558001
1467412
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Phosphorus ug/L 2500 107 90-110102 2 1025002.9 mg/L 5550 5440
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1467413MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92250815001
1467414
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Phosphorus ug/L 2500 105 90-110107 2 1025000.61 mg/L 3230 3280
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/28/2015 03:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/22977
SM 5220D
SM 5220D
5220D COD
Associated Lab Samples:92249931001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1462324
Associated Lab Samples:92249931001
Matrix:Water
Analyzed
Chemical Oxygen Demand ug/L ND 25000 05/20/15 16:35
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1462325LABORATORY CONTROL SAMPLE:
LCSSpike
Chemical Oxygen Demand ug/L 781000750000 104 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1462326MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92249550004
1462327
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chemical Oxygen Demand ug/L 750000 105 90-110105 0 3750000ND791000791000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1462328MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92250331006
1462329
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chemical Oxygen Demand ug/L 15000000 103 90-110103 0 3150000007760 mg/L 2320000
0
2320000
0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/28/2015 03:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 26
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated
for the dilution using the most amount of sample.B2
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/28/2015 03:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 26
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92249931
ASHE CO LINED MSWLF LAGOON
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92249931001 MPRP/18501 ICP/16604LAGOONEPA 3010 EPA 6010
92249931001 MERP/7837 MERC/7524LAGOONEPA 7470 EPA 7470
92249931001 MSV/31816LAGOONEPA 8260
92249931001 WET/37482 WET/37483LAGOONSM 5210B SM 5210B
92249931001 WETA/23066LAGOONEPA 300.0
92249931001 WETA/22952LAGOONEPA 353.2
92249931001 WETA/23053LAGOONEPA 365.1
92249931001 WETA/22977LAGOONSM 5220D
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/28/2015 03:58 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 26
Page 25 of 26
Page 26 of 26