Loading...
HomeMy WebLinkAbout9209_NorthWakeLinedMSWLF_ASD_DIN27392_20161107N o r t h W a k e S u b t i t l e D L a n d f i l l F a c i l i t y P e r m i t N o . 9 2 0 9 - 1 9 9 7 - M S W W a k e C o u n t y A l t e r n a t e S o u r c e D e m o n s t r a t i o n P r e p a r e d N o v e m b e r 2 0 1 6 5400 Glenwood Avenue, Suite 400 Raleigh, North Carolina 27612 tel: 919 325-3500 fax: 919 781-5730 November 7, 2016 Ms. Jaclynne Drummond North Carolina Department of Environmental Quality Division of Waste Management Solid Waste Section 2090 U.S. 70 Highway Swannanoa, North Carolina 28778 Subject: North Wake Lined Landfill Alternate Source Demonstration Facility Permit # 9209-MSWLF-1996 Dear Ms. Drummond: CDM Smith Inc (CDM Smith), on behalf of Wake County, is pleased to provide this Alternate Source Demonstration (ASD) for the North Wake Lined Landfill. This ASD has been prepared in accordance with Solid Waste rule .1633(c)(3), to demonstrate that select metals exceeding the North Carolina 2L Groundwater Standards (NC2L) detected in monitoring wells at the site are naturally occurring and not related to a release from the facility. Site Background The North Wake Lined Landfill is located off of Durant Road in Raleigh, Wake County, North Carolina. A site map is provided on Figure 1. The site is located in the Raleigh belt of the Piedmont Physiographic Province. The Piedmont Physiographic Province in North Carolina is characterized by gentle to steep, hilly terrain with small quantities of alluvium. Saprolite, a clay-rich residual material that is the product of in-place chemical weathering and leaching of bedrock, is commonly found in the Piedmont Province. Beneath the saprolite is a transition zone of weathered bedrock. The thickness of regolith above unweathered bedrock averages about 50 feet. The transition zone below the saprolite is generally the zone in which most of the lateral groundwater flow takes place. The porosity within the transition zone decreases with depth, as the degree of weathering decreases. The North Wake Lined Landfill is situated over the Raleigh gneiss. West of the site and corresponding with the highest elevations in the vicinity, is the Falls Leucogneiss. Both of these rock occurrences demonstrate a southwest to northeast trend in outcrop. Immediately east of the site is the Gresham Lake pluton. The Raleigh gneiss was observed to consist primarily of biotite gneiss and to a lesser degree hornblende gneiss. The gneiss demonstrates strong flow banding of compositional layers consisting of Ms. Jaclynne Drummond November 7, 2016 Page 2 9209-1997-MSWLF_ASD Report_11072016.docx white, feldspar rich layers and quartz biotite layers. Granitoid orthogneiss was also observed within the north and south stream channels west of the site. Relatively small diabase dikes, several feet wide, were identified at the site during construction of the North Wake Lined landfill. These dikes have been mapped and generally trend from south to north. Also noted during previous site reconnaissance was an extremely quartz rich gneiss in both the north and south streams. This rock appeared to be resistant to erosion/weathering relative to the surrounding rock and formed the creek channels into a series of small waterfalls for distances of approximately 75 feet. These two outcrops may potentially represent a continuous, resistant rock layer that forms a subsurface bedrock ridge aligned with the regional structure. The occurrence and movement of groundwater in the weathered bedrock is generally restricted to fractures and other discontinuities. The fractures are generally most numerous and have the largest openings near the top of the unweathered bedrock. The amount and location of groundwater in the unweathered bedrock varies greatly dependent on the depth, openness, and degree of connection between fractures. Upgradient (background) and downgradient (compliance) groundwater monitoring wells have been installed surrounding the closed lined landfill. There are two background wells at the site, MW-11 and MW-11d. MW-11 serves as the shallow background well for the site and monitors the surficial aquifer. MW-11d is the deep background well for the site and monitors the shallow fractured bedrock aquifer. The shallow site wells are generally completed to depths corresponding with the top of rock and are considered representative of the saprolite/transition zone. The deep wells at the site are generally completed in the shallow fractured bedrock and are considered representative of the bedrock aquifer. Groundwater elevations are collected from the site monitoring wells during the semi-annual groundwater sampling events. Groundwater contours from the Fall 2016 semi-annual sampling event were used to construct potentiometric contours presented on Figure 1. The groundwater contours indicate a generally north-easterly groundwater flow direction. Groundwater flow direction and discharge is largely controlled by topography and the Neuse River to the east. In situ horizontal hydraulic conductivity (slug) tests performed on monitoring wells at the site during previous site investigations estimate the average horizontal hydraulic conductivity to be approximately 2 feet/day across the entire site. Site History There are 3 separate landfill units at the North Wake Landfill facility: The closed Lined Landfill, the closed C&D landfill, and the closed Unlined Landfill. The C&D landfill is located west of the Lined Landfill and was closed in 2004. The Unlined Landfill is located north of the Lined Landfill and was closed in 1996. Lined and C&D Landfill units are shown on Figure 1. Ms. Jaclynne Drummond November 7, 2016 Page 3 9209-1997-MSWLF_ASD Report_11072016.docx The Lined Landfill began receiving waste in early 1996. Groundwater samples for Appendix I volatile and inorganic compounds were first collected in October 1995 and have been collected semi-annually since. In May 2008, Wake County discontinued disposal of municipal solid waste in the Lined landfill. Final closure of the Lined Landfill was completed in May 2009. The site is now used as the North Wake Landfill District Park, which opened in 2010. Alternate Source Demonstration During the most recent semi-annual sampling event conducted in September 2016, samples were collected from all of the site wells and analyzed for the North Carolina Solid Waste Section Appendix I volatile organic compounds (VOC) and metals. The analytical results were reported to the laboratory specific method detection limit (MDL) and were quantifiable at or below Solid Waste Section Limits (SWSLs). Detections of analytes above the laboratory MDL but below the SWSL were qualified as estimated or “J” flags. During the most recent event, no VOCs were detected in any of the samples. Several metals were detected in all wells, however, select metals, particularly chromium, cobalt, thallium, and vanadium were detected in both the upgradient and downgradient wells at concentrations above their respective NC2L. Several metals have been detected in both upgradient and downgradient monitoring wells at levels above their respective North Carolina 2L standards (NC2L) since initial sampling in 1995. A summary of the analytical results for this and previous sampling events are provided in Appendix A. Historically, there have been very few reported detections of VOC in any of the wells associated with the North Wake Lined Landfill and when detected, VOC concentrations tend to be non-repeatable and very low. Metals have routinely been detected in all of the site wells. CDM Smith reviewed the site data for metals and identified the several metals that have routinely exceeded the North Carolina 2L Standards at each monitoring well at the North Wake Lined Landfill. Metals routinely exceeding the 2L or Groundwater protection standards for each well are shown on Table 1. For the purpose of this ASD, based on the data presented above, the following metals in groundwater are the constituents of concern (COC) for the North Wake Lined Landfill site: Antimony, Arsenic, Chromium, Cobalt, Lead, Thallium, and Vanadium. Based on the following discussions, CDM Smith believes that the routine detections of these and other metals in the site monitoring wells are related to naturally occurring background conditions at the site. Ms. Jaclynne Drummond November 7, 2016 Page 4 9209-1997-MSWLF_ASD Report_11072016.docx Concentrations are further impaired by suspended particles in the samples and are not related to a release from the landfill. Due to the variable amounts of clays and weathered mica at the site, turbidity in some wells is an issue. As wells are purged, accumulated suspended solids are removed from the wells, and over time concentrations have decreased. Data from the downgradient compliance wells were compared statistically to data from the background well using an ANOVA comparison to determine if there was a statistically significant variation in background to downgradient well concentrations. While using the ANOVA comparison, in instances where results were below detection limits, a value less than or equal to the Solid Waste Section Limit was substituted. The ANOVA comparisons for each well are provided in Appendix B. Based on a review of the ANOVA comparisons, all reported detections of the COCs in the downgradient wells were not found to be statistically significant above the corresponding background well with the exception of the following: Chromium MW-13, MW-14, MW-15, MW-17, MW-18, MW-20, MW-25d Cobalt MW-18, MW-16 Vanadium MW-12, MW-15, MW-18 For the wells with one or more statistically significant COC, further data evaluation was conducted. A review of historic sampling data indicated that wells with statistically significant COCs tended to be more turbid than wells without. As shown on Table 1, CDM Smith evaluated maximum and average reported concentrations for each statistically significant COC. In most instances, both maximum and average reported concentrations for the COC in a given well were similar to the maximum and average concentration in the corresponding background well. Again, in wells where the maximum and average detections were not in correlation with the background wells, turbidity tended to be higher. In order to determine if turbidity was a contributing factor to total reported metals, CDM Smith collected filtered samples during the September 2016 sampling event and had them analyzed for dissolved metals. As shown on Table 1, total detected concentrations during the September 2016 sampling event were often an order of magnitude higher than the dissolved (filtered) concentrations in the same well. CDM Smith then compared dissolved concentrations of the statistically significant COCs in the downgradient wells to the corresponding dissolved concentrations in the applicable background well. In all cases, the dissolved concentrations were less than or similar for both wells. Figure 1: Potentiometric Surface Map Ma p D a t a S o u r c e : A u g u s t 2 0 1 0 A e r i a l P h o t o g r a p h , W a k e C o u n t y , T e r r a S e r v e r GW E l e v . 30 1 . 59 GW E l e v . 3 0 1 . 0 2 GW E l e v . 28 1. 7 0 GW E l e v . 28 2. 4 8 GW E l e v . 28 6. 3 8 GW E l e v . 28 0 . 0 1 . GW E l e v . 27 5. 4 8 GW E l e v . 2 7 8. 60 GW E l e v . 2 69 .8 3 GW E l e v . 26 4. 9 0 GW E l e v . 26 0. 4 0 GW E l e v . 24 5. 6 0 GW E l e v . 24 5. 9 9 GW E l e v . 24 3 .9 7 GW Elev.24 4 .51GW Elev.228.73GW Elev.22 0.51 GW Elev.22 1.91 GW Elev.23 3.12 GW Elev.243.07 GW Elev. 242.19 GW Elev.26 3.94 LEGEND Groundwater Monitoring Well Potentiometric Contour (dashed where inferred) No t e s : 1. G r o u n d w a t e r e l e v a t i o n s w e r e m e a s u r e d o n September 1 , 2016. 2. P o t e n t i o m e t r i c c o n t o u r s a r e d e r i v e d f r o m p r e v i o u s investigations.Surface Water Sample Location Li n e d L a n d f i l l C& D La n d f i l l 3 0 0 3 0 0 295 2 9 5 29 0 2 9 0 285 280 275 270 265 260 2 55 25 0 2 4 5240235230225220 2 2 0 2 2 5 2 3 0 2 3 5 2 4 0 2 4 5 2 5 0 2 5 5 2 6 0 2 6 5 2 7 0 2 7 5 2 8 0 2 8 5 2 7 0 Contour Interval - 5 Feet Sc a l e i n F e e t SW - 2 0 3 0 0 6 0 0 9 0 0 Ta b l e 1 Da t a E v a l u a t i o n Al t e r n a t e S o u r c e D e m o n s t r a t i o n No r t h W a k e L i n e d L a n d f i l l Wa k e C o u n t y , N o r t h C a r o l i n a Pe r m i t N o . 9 2 0 9 Do w n g r a d i e n t W e l l A n t i m o n y A r s e n i c C h r o m i u m C o b a l t L e a d T h a l l i u m V a n a d i u m St a t i s t i c a l l y Si g n i f i c a n t CO C Ma x i m i u m De t e c t e d Co n c e n t r a t i o n in W e l l Av e r a g e De t e c t e d Co n c e n t r a t i o n in W e l l Ma x i m i u m De t e c t e d Co n c e n t r a t i o n in B a c k g r o u n d We l l Av e r a g e De t e c t e d Co n c e n t r a t i o n in B a c k g r o u n d We l l Total (unfiltered sample)Dissolved (filtered sample)Background Well Dissolved MW - 1 2 X X X X V a n a d i u m 0 . 1 8 1 0 . 0 4 8 0 . 1 1 7 0 . 0 2 2 0.100 0.001J 0.002J MW - 1 2 D X X X X N o n e MW - 1 3 X X X X C h r o m i u m 0 . 2 1 0 . 0 3 0 . 0 2 4 0 . 0 0 5 0.032 0.0011J 0 . 0 0 1 1 J MW - 1 4 X X X C h r o m i u m 0 . 0 3 4 0 . 0 0 9 0 . 0 2 4 0 . 0 0 5 0 . 0 0 6 9 J 0 . 0 0 1 3 J 0 . 0 0 1 1 J X X X X C h r o m i u m 0 . 1 9 6 0 . 0 2 5 0 . 0 2 4 0 . 0 0 5 0 . 0 0 6 9 J N D 0 . 0 0 1 1 J Va n a d i u m 0 . 4 1 0 . 0 6 6 0 . 1 1 7 0 . 0 2 2 0.019J ND 0.002J MW - 1 5 D X X X N o n e MW - 1 6 X X X X X N o n e MW - 1 7 X X X C h r o m i u m 0 . 0 3 6 6 0 . 0 1 3 0 . 0 2 4 0 . 0 0 5 0 . 0 0 1 5 J N D 0 . 0 0 1 1 J MW - 1 7 D X X N o n e X X X X C h r o m i u m 0 . 2 9 9 0 . 0 5 1 0 . 0 2 4 0 . 0 0 5 0.01 ND 0 . 0 0 1 1 J Co b a l t 0 . 1 2 7 0 . 0 2 5 0 . 0 7 1 0 . 0 1 1 0.0036J ND N D Va n a d i u m 0 . 2 0 7 0 . 0 5 6 0 . 1 1 4 0 . 0 2 2 0.01J 0.0022J 0.002J MW - 1 9 X N o n e MW - 2 0 X X X X X C h r o m i u m 0 . 0 2 7 4 0 . 0 1 0 . 0 2 4 0 . 0 0 5 0.014 0.0017J 0 . 0 0 1 1 J MW - 2 1 X X X N o n e MW - 2 5 X X X N o n e MW - 2 5 D X X X C h r o m i u m 0 . 0 5 4 0 . 0 1 1 0 . 0 1 5 0 . 0 0 3 0 . 0 0 3 9 J 0 . 0 0 1 7 J 0 . 0 0 0 7 J MW - 2 6 X X X Co b a l t 0. 0 3 0. 0 1 5 0. 0 7 1 0. 0 1 1 0.014 0.0078J ND No t e s : - S i t e b a c k g r o u n d w e l l s a r e M W - 1 1 a n d M W - 1 1 d . - C o n s t i t u e n t o f C o n c e r n i s b a s e d o n N C 2 L o r G W P S e x c e e d a n c e s . - A N O V A u s e d f o r s t a t i s t i c a l c o m p a r i s o n . - A l l u n i t s s h o w n i n m g / L ( p p m ) - B o l d c o n c e n t r a t i o n s e x c e e d r e l a v e n t S t a n d a r d . September 2016 Sampling Event Co n s t i t u e n t o f C o n c e r n ( C O C ) MW - 1 5 MW - 1 8 Appendix A Analytical Data - Metals Ap p e n d i x A De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s Al t e r n a t e S o u r c e D e m o n s t r a t i o n No r t h W a k e L i n e d L a n d f i l l Pe r m i t N o . 9 2 0 9 M o n i t o r i n g W e l l C o d e S a m p l e D a t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r L e a d M e r c u r y N i c k e l S e l e n i u m S i l v e r Thallium VanadiumZinc 0. 0 0 1 * 0 . 0 1 0 . 7 0 . 0 0 4 * 0 . 0 0 2 0 . 0 1 0 . 0 0 1 * 1 0 . 0 1 5 0 . 0 0 1 0 . 1 0 . 0 2 0 . 0 2 0 . 0 0 0 2 * 0 . 0 0 0 3 * 1 0. 0 0 6 0 . 0 1 0 0 . 1 0 . 0 0 1 0 . 0 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 0 0 2 0 . 0 5 0 . 0 1 0 . 0 1 0 . 0 0 5 5 0 . 0 2 5 0 . 0 1 MW - 1 1 3 1 - O c t - 9 5 0. 0 1 1 0 . 8 4 2 0 . 0 0 8 0 . 0 2 4 0 . 0 7 1 0.3 3 1 0.0 2 6 0. 0 8 7 0.117 0.314 MW - 1 1 1 9 - D e c - 9 5 MW - 1 1 2 6 - F e b - 9 6 0. 0 1 1 0 . 0 2 2 0.106 MW - 1 1 2 9 - A p r - 9 6 0.106 MW - 1 1 2 7 - N o v - 9 6 0 . 0 3 5 MW - 1 1 2 2 - A p r - 9 7 0.13 MW - 1 1 3 1 - O c t - 9 7 0.066 MW - 1 1 1 1 - M a y - 9 8 MW - 1 1 8 - D e c - 9 8 0. 0 0 2 1 MW - 1 1 1 4 - A p r - 9 9 MW - 1 1 3 0 - N o v - 9 9 MW - 1 1 5 - A p r - 0 0 0.0 0 1 2 MW - 1 1 1 8 - D e c - 0 0 MW - 1 1 1 8 - A p r - 0 1 MW - 1 1 2 7 - N o v - 0 1 0 . 3 1 1 0. 0 1 6 5 0.0297 MW - 1 1 5 - A p r - 0 2 MW - 1 1 5 - N o v - 0 2 MW - 1 1 1 5 - A p r - 0 3 MW - 1 1 2 9 - O c t - 0 3 MW - 1 1 2 1 - A p r - 0 4 MW - 1 1 1 8 - N o v - 0 4 MW - 1 1 2 1 - A p r - 0 5 MW - 1 1 1 1 - N o v - 0 5 0.083 MW - 1 1 1 3 - A p r - 0 6 MW - 1 1 8 - N o v - 0 6 0.082 MW - 1 1 2 0 - A p r - 0 7 0.021 MW - 1 1 7 - N o v - 0 7 0 . 3 3 2 0 . 0 0 2 1 0.0 1 2 0.058 0.113 MW - 1 1 1 5 - M a y - 0 8 0 . 0 7 7 8 J 0 . 0 0 5 4 J 0 . 0 1 0 5 0 . 0 0 3 9 2 J 0. 0 0 4 4 8 J 0.00563 0.00290J 0 . 0 1 6 1 MW - 1 1 1 0 - N o v - 0 8 0 . 0 5 3 1 J 0 . 0 0 3 0 3 0 . 0 0 0 3 5 J B 0 . 0 0 2 7 3 J B 0 . 0 0 5 9 4 J B 0 . 0 0 9 7 8 J B 0.0 0 4 0 2 J B 0 . 0 0 1 1 4 J 0 . 0 0 8 1 8 J MW - 1 1 1 1 - M a r - 0 9 0 . 0 9 9 1 J B 0.0 0 6 2 9 0.0 0 0 2 4 J 0 . 0 0 4 3 9 J B 0.0 0 6 5 1 J B 0. 0 1 3 6 B 0 . 0 0 5 8 4 J B 0.0 0 6 3 4 J B 0.0203JB 0.0207 MW - 1 1 3 - D e c - 0 9 0 . 4 1 2 0 . 0 0 2 3 6 0 . 0 0 0 2 2 J 0. 0 1 4 9 0 . 0 2 5 4 0.1 0 2 B 0. 0 1 9 2 0.0 1 4 5 J 0 . 0 1 0 7 0.099B 0.12B MW - 1 1 1 2 - M a y - 1 0 0 . 0 6 2 1 J 0 . 0 0 1 4 5 J 0 . 0 0 1 9 2 J 0.00267J 0 . 0 1 2 6 MW - 1 1 2 6 - O c t - 1 0 0 . 1 4 3 0 . 0 0 3 5 0 J 0. 0 0 5 4 7 J 0. 0 2 5 8 0 . 0 0 5 6 9 J 0.023J 0.0427 MW - 1 1 1 7 - M a r - 1 1 0 . 0 7 6 7 J 0 . 0 0 1 6 J 0 . 0 0 3 8 8 J 0.000265J 0 . 0 0 3 5 1 J 0.0243 MW - 1 1 1 - N o v - 1 1 0 . 0 8 0 7 J 0 . 0 0 1 9 J 0 . 0 0 6 3 3 J B 0 . 0 0 2 1 4 J B 0.00361J 0.0196 MW - 1 1 2 5 - A p r - 1 2 0 . 0 6 5 3 J 0.0 0 2 3 7 J 0.00323J 0.0121 MW - 1 1 2 3 - O c t - 1 2 0 . 0 8 0 6 J 0. 0 0 1 4 2 J 0.0 0 3 6 6 J 0.00532J 0.0197 MW - 1 1 1 7 - A p r - 1 3 0 . 0 9 J 0 . 0 0 0 2 J 0 . 0 0 2 J 0. 0 0 2 J 0.0 0 8 J 0 . 0 0 1 J 0 . 0 0 1 J 0.009J 0.02B MW - 1 1 1 6 - O c t - 1 3 0 . 1 0 . 0 0 0 1 J 0 . 0 0 0 2 J 0 . 0 0 2 J 0. 0 0 1 J 0.0 0 4 J 0 . 0 0 0 5 J 0 . 0 0 0 9 J 0.005J 0.015B MW - 1 1 1 7 - A p r - 1 4 0 . 1 7 0 . 0 0 0 5 J 0 . 0 0 0 2 J 0 . 0 0 4 J 0. 0 0 6 J 0.0 1 8 0 . 0 0 3 J 0 . 0 0 3 J 0 . 0 0 0 0 8 J 0.04 0.050B MW - 1 1 1 3 - N o v - 1 4 0 . 0 9 0 J 0 . 0 0 0 2 J 0 . 0 0 0 2 J 0 . 0 0 2 J 0. 0 0 2 J 0.0 0 8 J 0 . 0 0 1 J 0 . 0 0 1 J 0 . 0 0 0 0 5 J 0.007J 0.024 MW - 1 1 30 - A p r - 1 5 0. 1 0 0 0. 0 0 0 2 J 0. 0 0 2 J 0. 0 0 3 J 0.0 1 0 J 0.0 0 1 J 0. 0 0 2 J 0.00006J 0.012J 0.027 MW - 1 1 15 - O c t - 1 5 0.1 1 0. 0 0 0 3 J 0.0 0 0 1 J 0. 0 0 3 J 0. 0 0 3 J 0.0 1 1 0.0 0 1 J 0. 0 0 0 0 4 J 0. 0 0 2 J 0.00005J 0.013JB 0.027 MW - 1 1 21 - A p r - 1 6 0.0 0 0 5 J 0. 1 3 0 0. 0 0 0 3 J 0. 0 0 3 J 0. 0 0 4 J 0.0 1 6 0.0 0 2 J 0. 0 0 2 J 0.0001JB 0.018J 0.032 MW - 1 1 1- S e p - 1 6 0. 0 9 0 J 0.0 0 0 2 8 J 0.0 0 0 5 4 J 0.0 0 2 4 J 0.0 0 2 6 J 0. 0 0 8 3 J 0. 0 0 1 3 J 0.0 0 1 6 J 0.011J 0.020 MW - 1 1 ( d i s s o l v e d ) 1- S e p - 1 6 0. 0 4 8 J 0 . 0 0 1 1 J 0 . 0 0 0 2 8 B J 0.002J 0.0069J So l i d W a s t e S e c t i o n L i m i t No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d Pa g e 1 o f 1 8 October 2016 Ap p e n d i x A De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s Al t e r n a t e S o u r c e D e m o n s t r a t i o n No r t h W a k e L i n e d L a n d f i l l Pe r m i t N o . 9 2 0 9 M o n i t o r i n g W e l l C o d e S a m p l e D a t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r L e a d M e r c u r y N i c k e l S e l e n i u m S i l v e r Thallium VanadiumZinc 0. 0 0 1 * 0 . 0 1 0 . 7 0 . 0 0 4 * 0 . 0 0 2 0 . 0 1 0 . 0 0 1 * 1 0 . 0 1 5 0 . 0 0 1 0 . 1 0 . 0 2 0 . 0 2 0 . 0 0 0 2 * 0 . 0 0 0 3 * 1 0. 0 0 6 0 . 0 1 0 0 . 1 0 . 0 0 1 0 . 0 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 0 0 2 0 . 0 5 0 . 0 1 0 . 0 1 0 . 0 0 5 5 0 . 0 2 5 0 . 0 1 So l i d W a s t e S e c t i o n L i m i t No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d MW - 1 1 D 31 - O c t - 9 5 0.0 0 2 MW - 1 1 D 1 9 - D e c - 9 5 MW - 1 1 D 2 6 - F e b - 9 6 0.0 0 1 MW - 1 1 D 2 9 - A p r - 9 6 MW - 1 1 D ( d u p ) 2 9 - A p r - 9 6 MW - 1 1 D 2 7 - N o v - 9 6 0 . 0 2 6 MW - 1 1 D 2 2 - A p r - 9 7 0.054 MW - 1 1 D 3 1 - O c t - 9 7 0.026 MW - 1 1 D 1 1 - M a y - 9 8 0. 0 1 2 0.069 MW - 1 1 D 8 - D e c - 9 8 0. 0 0 1 9 MW - 1 1 D 1 4 - A p r - 9 9 MW - 1 1 D 3 0 - N o v - 9 9 MW - 1 1 D 5 - A p r - 0 0 MW - 1 1 D 1 8 - D e c - 0 0 MW - 1 1 D 1 8 - A p r - 0 1 MW - 1 1 D 2 7 - N o v - 0 1 MW - 1 1 D 5 - A p r - 0 2 MW - 1 1 D 5 - N o v - 0 2 MW - 1 1 D 1 5 - A p r - 0 3 MW - 1 1 D 2 9 - O c t - 0 3 MW - 1 1 D 2 1 - A p r - 0 4 MW - 1 1 D 1 8 - N o v - 0 4 MW - 1 1 D 2 1 - A p r - 0 5 MW - 1 1 D 1 1 - N o v - 0 5 MW - 1 1 D 1 3 - A p r - 0 6 MW - 1 1 D 8 - N o v - 0 6 MW - 1 1 D 2 0 - A p r - 0 7 MW - 1 1 D 7 - N o v - 0 7 0.016 MW - 1 1 D 1 5 - M a y - 0 8 0 . 0 5 9 7 J 0 . 0 0 3 0 7 0 . 0 0 6 4 1 J 0 . 0 0 8 2 1 J 0 . 0 0 4 5 9 J 0. 0 0 3 9 8 J 0.00691 0.000970J 0 . 0 0 9 8 2 J MW - 1 1 D 1 0 - N o v - 0 8 0 . 0 3 7 6 J 0 . 0 0 0 3 6 J B 0 . 0 0 1 9 4 J B 0 . 0 0 5 8 J B 0 . 0 0 8 5 J B 0.0 0 4 3 7 J B 0.00409J 0.00414J MW - 1 1 D 1 6 - M a r - 0 9 0 . 0 0 4 1 1 J 0 . 0 8 7 7 J B 0.0 0 6 1 1 B 0.0 0 0 4 1 J 0 . 0 0 7 1 4 J B 0 . 0 1 5 3 B 0 . 0 0 6 9 4 J B 0.0 0 1 2 2 J B 0.0201JB 0.0219 MW - 1 1 D 4 - D e c - 0 9 0 . 0 6 1 4 J B 0 . 0 0 5 4 1 J B 0 . 0 0 8 2 J B 0.0 0 3 1 6 J B 0.00728JB 0.00885JB MW - 1 1 D 1 3 - M a y - 1 0 0. 0 0 1 0 1 J 0. 0 4 7 8 J 0 . 0 0 5 1 0 J 0 . 0 0 3 1 J 0.00550J 0.0123 MW - 1 1 D 2 7 - O c t - 1 0 0. 0 0 1 7 3 J 0. 0 4 1 3 J 0 . 0 0 3 5 6 J 0 . 0 0 2 7 9 J 0.00382J 0.0973J MW - 1 1 D 1 8 - M a r - 1 1 0 . 0 0 0 8 5 2 J 0 . 0 5 1 2 J 0 . 0 0 3 4 3 J 0 . 0 0 4 4 1 J 0.00373J 0.00804J MW - 1 1 D 2 - N o v - 1 1 0 . 0 4 5 5 J 0 . 0 0 2 1 8 J 0 . 0 0 4 1 4 J B 0.00245J 0.00586J MW - 1 1 D 2 6 - A p r - 1 2 0 . 0 0 0 2 4 7 J 0 . 0 4 4 2 J 0 . 0 0 3 0 4 J 0 . 0 0 9 6 8 J B 0 . 0 0 3 3 1 J 0.00205J 0.00462J MW - 1 1 D 2 4 - O c t - 1 2 0 . 0 4 3 7 J 0 . 0 0 0 3 7 5 J 0 . 0 0 2 4 0 J 0.00253J 0.00510J MW - 1 1 D 1 8 - A p r - 1 3 0 . 0 0 0 4 J 0 . 0 5 0 J 0 . 0 0 0 1 J 0 . 0 0 2 J B 0 . 0 0 0 2 J 0 . 0 0 1 J 0 . 0 0 0 6 J 0.004JB MW - 1 1 D 1 7 - O c t - 1 3 0 . 0 0 0 6 J 0 . 0 0 0 6 J 0 . 0 5 0 J 0 . 0 0 0 3 J 0 . 0 0 1 J 0 . 0 0 0 2 J 0 . 0 0 1 J 0 . 0 0 0 0 2 J 0 . 0 0 0 6 J 0.002J 0.002JB MW - 1 1 D 1 7 - A p r - 1 4 0 . 3 0 . 0 0 2 1 0 . 0 0 0 2 J 0 . 0 1 5 0 . 0 1 3 0 . 0 5 6 0 . 0 1 1 0 . 0 0 9 J 0.0002J 0 . 0 9 9 0.088 MW - 1 1 D 1 3 - N o v - 1 4 0 . 1 5 0 . 0 0 0 7 J 0 . 0 0 0 1 J 0 . 0 0 5 J 0. 0 0 4 J 0.0 1 8 0 . 0 0 4 J 0 . 0 0 3 J 0.00007J 0 . 0 3 7 0.035 MW - 1 1 D 29 - A p r - 1 5 0.0 0 0 6 J 0.0 0 0 5 J 0. 0 6 0 J 0. 0 0 0 1 J 0.0 0 0 1 J 0. 0 0 2 J 0.0 0 0 6 J 0.0 0 3 J 0. 0 0 0 3 J 0.0 0 0 9 J 0.005J 0.008J MW - 1 1 D 15 - O c t - 1 5 0.0 0 0 4 J 0. 0 9 0 J 0. 0 0 0 3 J 0.0 0 0 1 J 0. 0 0 3 J 0. 0 0 2 J 0.0 0 9 J 0.0 0 2 J 0. 0 0 0 0 5 J 0. 0 0 2 J 0.014JB 0.016 MW - 1 1 D 21 - A p r - 1 6 0.0 0 0 3 J 0. 0 6 0 J 0. 0 0 2 J 0. 0 0 0 3 J B 0.0 0 4 J 0. 0 0 0 5 J 0. 0 0 2 J 0.012 MW - 1 1 D 1- S e p - 1 6 0.0 0 0 4 3 B J 0. 0 4 5 J 0.0 0 0 0 7 6 J 0.0 0 1 2 J 0. 0 0 2 1 J 0.0 0 0 2 5 J 0. 0 0 0 7 5 J 0.0027J 0.0092BJ MW - 1 1 D ( d i s s o l v e d ) 1- S e p - 1 6 0. 0 4 1 J 0 . 0 0 0 0 4 5 J 0 . 0 0 0 7 J 0 . 0 0 0 7 3 J 0 . 0 0 0 7 2 J 0.0017J 0.0062BJ Pa g e 2 o f 1 8 October 2016 Ap p e n d i x A De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s Al t e r n a t e S o u r c e D e m o n s t r a t i o n No r t h W a k e L i n e d L a n d f i l l Pe r m i t N o . 9 2 0 9 M o n i t o r i n g W e l l C o d e S a m p l e D a t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r L e a d M e r c u r y N i c k e l S e l e n i u m S i l v e r Thallium VanadiumZinc 0. 0 0 1 * 0 . 0 1 0 . 7 0 . 0 0 4 * 0 . 0 0 2 0 . 0 1 0 . 0 0 1 * 1 0 . 0 1 5 0 . 0 0 1 0 . 1 0 . 0 2 0 . 0 2 0 . 0 0 0 2 * 0 . 0 0 0 3 * 1 0. 0 0 6 0 . 0 1 0 0 . 1 0 . 0 0 1 0 . 0 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 0 0 2 0 . 0 5 0 . 0 1 0 . 0 1 0 . 0 0 5 5 0 . 0 2 5 0 . 0 1 So l i d W a s t e S e c t i o n L i m i t No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d MW - 1 2 31 - O c t - 9 5 MW - 1 2 1 9 - D e c - 9 5 MW - 1 2 ( d u p ) 1 9 - D e c - 9 5 MW - 1 2 2 6 - F e b - 9 6 ` MW - 1 2 2 9 - A p r - 9 6 MW - 1 2 2 7 - N o v - 9 6 0 . 2 0. 0 0 5 0. 0 1 0 . 0 0 6 0.014 0.028 MW - 1 2 2 4 - A p r - 9 7 0. 0 1 2 0.11 MW - 1 2 3 - N o v - 9 7 0 . 5 5 0 . 0 0 2 9 0 . 0 0 1 3 0. 0 2 1 0 . 0 2 3 0 . 0 1 8 0.12 0.31 MW - 1 2 2 3 - N o v - 9 8 MW - 1 2 1 4 - A p r - 9 9 MW - 1 2 1 - D e c - 9 9 MW - 1 2 5 - A p r - 0 0 MW - 1 2 1 8 - D e c - 0 0 MW - 1 2 1 7 - A p r - 0 1 MW - 1 2 2 8 - N o v - 0 1 MW - 1 2 3 - A p r - 0 2 MW - 1 2 5 - N o v - 0 2 0.0 0 1 3 MW - 1 2 1 5 - A p r - 0 3 MW - 1 2 3 0 - O c t - 0 3 MW - 1 2 7 - A p r - 0 4 MW - 1 2 1 8 - N o v - 0 4 0. 0 1 9 0 . 0 1 8 0.065 0.05 MW - 1 2 2 1 - A p r - 0 5 MW - 1 2 1 1 - N o v - 0 5 MW - 1 2 1 3 - A p r - 0 6 MW - 1 2 8 - N o v - 0 6 MW - 1 2 2 0 - A p r - 0 7 0 . 2 6 0 . 0 0 1 0.0 3 7 0.05 0.061 MW - 1 2 7 - N o v - 0 7 0 . 2 6 6 0 . 0 0 1 4 0.0 3 1 0.038 0.068 MW - 1 2 1 4 - M a y - 0 8 0 . 2 8 7 0 . 0 0 0 6 8 J 0. 0 1 8 1 0 . 0 0 9 9 2 J 0. 0 6 5 6 0. 0 2 0 6 0. 0 1 0 1 0.0578 0.0592 MW - 1 2 5 - N o v - 0 8 0 . 0 5 6 7 J 0 . 0 0 2 4 4 0 . 0 0 0 1 7 J 0 . 0 0 3 5 3 J 0 . 0 0 6 8 4 J 0. 0 0 1 5 J B 0.00585J 0.0105 MW - 1 2 1 8 - M a r - 0 9 0 . 0 5 6 3 J 0 . 0 0 0 1 4 J 0 . 0 0 2 6 5 J 0 . 0 1 5 1 B 0.0 0 1 4 9 J B 0.0201JB 0.00909J MW - 1 2 2 0 - O c t - 0 9 0 . 0 5 7 3 J B 0 . 0 0 0 3 4 J 0 . 0 0 5 1 J B 0 . 0 1 4 1 B 0 . 0 0 3 7 9 J 0.0101J 0.00912JB MW - 1 2 7 - M a y - 1 0 0 . 1 9 0 . 0 0 0 5 4 9 J 0 . 0 0 8 3 5 J 0. 0 0 8 3 1 J 0. 0 3 9 2 0 . 0 0 4 9 3 J 0 . 0 0 2 7 2 J 0 . 0 0 0 9 2 9 J 0 . 0 0 0 1 7 6 J 0.0396 0.0505 MW - 1 2 1 9 - O c t - 1 0 0 . 0 0 9 2 8 J 0. 8 3 7 0 . 0 3 4 2 0 . 0 3 5 3 0. 1 8 0. 0 2 1 4 0.0 1 6 4 J 0 . 0 0 2 3 4 J 0.00113J 0 . 1 8 1 0.163 MW - 1 2 1 5 - M a r - 1 1 0 . 3 1 1 0 . 0 0 1 1 9 0 . 0 0 0 6 2 5 J 0. 0 1 5 2 0 . 0 1 0 2 0. 0 6 8 2 0. 0 1 7 7 0. 0 0 6 9 5 J 0.000389J 0 . 0 8 2 4 0.0708 MW - 1 2 2 0 - O c t - 1 1 0 . 1 6 7 0 . 0 0 7 6 4 J 0. 0 0 4 7 9 J 0. 0 3 1 4 0 . 0 0 6 6 2 J 0 . 0 0 3 5 7 J 0.0344 0.0574 MW - 1 2 1 1 - A p r - 1 2 0 . 0 0 0 5 3 5 J 0 . 1 8 5 0 . 0 0 0 2 7 1 J 0 . 0 0 7 9 2 J 0. 0 0 6 1 9 J 0. 0 3 7 4 0 . 0 0 7 9 8 J 0 . 0 0 3 7 2 J 0 . 0 0 2 J 0 . 0 0 0 1 9 5 J 0.0364 0.0383 MW - 1 2 2 6 - O c t - 1 2 0 . 2 2 6 0 . 0 0 9 4 1 J 0. 0 0 5 6 2 J 0. 0 4 2 2 0 . 0 0 7 7 9 J 0 . 0 0 4 2 4 J 0 . 0 0 1 0 9 J 0 . 0 0 0 1 6 0 J 0.0474 0.0498 MW - 1 2 1 1 - A p r - 1 3 0 . 4 4 0 . 0 0 1 9 0 . 0 0 0 2 J 0. 0 2 0 . 0 1 3 0.0 6 7 0 . 0 1 1 0 . 0 1 J 0.0005J 0 . 0 7 7 0.077 MW - 1 2 2 - O c t - 1 3 0 . 2 1 0 0 . 0 0 0 8 J 0 . 0 0 0 3 J 0 . 0 0 6 J 0. 0 0 5 J 0.0 2 5 0 . 0 0 4 J 0 . 0 0 4 J 0.0002J 0 . 0 3 0 0.037B MW - 1 2 4 - A p r - 1 4 0 . 2 8 0 0 . 0 0 0 8 J 0 . 0 0 0 2 J 0 . 0 0 8 J 0. 0 0 9 J 0.0 3 6 0 . 0 0 5 J 0 . 0 0 5 J 0.0002J 0 . 0 5 9 0.058B MW - 1 2 1 2 - N o v - 1 4 0 . 0 8 0 J 0 . 0 0 0 2 J 0 . 0 0 2 J 0. 0 0 3 J 0.0 0 9 J 0 . 0 0 1 J 0 . 0 0 2 J 0 . 0 0 0 0 8 J 0.007J 0.014 MW - 1 2 8 - A p r - 1 5 0 . 0 8 0 J 0 . 0 0 0 3 J 0 . 0 0 3 J 0. 0 0 3 J 0.0 1 2 0 . 0 0 2 J 0 . 0 0 2 J 0 . 0 0 0 0 6 J 0.011J 0.019JB MW - 1 2 7 - O c t - 1 5 0 . 0 8 0 J 0 . 0 0 0 2 J 0 . 0 0 0 1 J 0 . 0 0 2 J 0. 0 0 3 J 0.0 1 1 0 . 0 0 1 J 0 . 0 0 2 J 0 . 0 0 0 0 7 J 0.004J 0.020 MW - 1 2 2 5 - M a r - 1 6 0 . 1 4 2 0 . 0 0 0 4 9 J 0 . 0 0 5 7 J 0.0 0 4 3 J 0. 0 2 2 5 0 . 0 0 2 9 9 J 0 . 0 0 3 4 J 0 . 0 0 0 1 5 J 0.014J 0.0347 MW - 1 2 1 - S e p - 1 6 0 . 0 0 0 2 5 J 0 . 5 2 0 0 . 0 0 2 1 0 . 0 0 2 2 J D 0. 0 1 8 D 0.0 8 4 B 0 . 0 1 2 0 . 0 1 2 J D 0 . 0 0 1 5 J 0 . 0 0 0 1 8 J 0.00062J 0 . 1 0 0 D 0.100 MW - 1 2 ( d i s s o l v e d ) 1 - S e p - 1 6 0 . 0 0 0 2 4 J 0 . 0 3 0 J 0 . 0 0 0 0 6 8 J 0.0 0 4 2 J 0.0 0 0 6 2 B J 0 . 0 1 7 J 0.001J 0.005J Pa g e 3 o f 1 8 October 2016 Ap p e n d i x A De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s Al t e r n a t e S o u r c e D e m o n s t r a t i o n No r t h W a k e L i n e d L a n d f i l l Pe r m i t N o . 9 2 0 9 M o n i t o r i n g W e l l C o d e S a m p l e D a t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r L e a d M e r c u r y N i c k e l S e l e n i u m S i l v e r Thallium VanadiumZinc 0. 0 0 1 * 0 . 0 1 0 . 7 0 . 0 0 4 * 0 . 0 0 2 0 . 0 1 0 . 0 0 1 * 1 0 . 0 1 5 0 . 0 0 1 0 . 1 0 . 0 2 0 . 0 2 0 . 0 0 0 2 * 0 . 0 0 0 3 * 1 0. 0 0 6 0 . 0 1 0 0 . 1 0 . 0 0 1 0 . 0 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 0 0 2 0 . 0 5 0 . 0 1 0 . 0 1 0 . 0 0 5 5 0 . 0 2 5 0 . 0 1 So l i d W a s t e S e c t i o n L i m i t No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d MW - 1 2 D 31 - O c t - 9 5 MW - 1 2 D 1 9 - D e c - 9 5 MW - 1 2 D 2 6 - F e b - 9 6 MW - 1 2 D 2 9 - A p r - 9 6 MW - 1 2 D 2 7 - N o v - 9 6 0 . 0 1 3 MW - 1 2 D 2 4 - A p r - 9 7 MW - 1 2 D 3 - N o v - 9 7 MW - 1 2 D 2 3 - N o v - 9 8 MW - 1 2 D 1 4 - A p r - 9 9 MW - 1 2 D 1 - D e c - 9 9 MW - 1 2 D 5 - A p r - 0 0 MW - 1 2 D 1 8 - D e c - 0 0 MW - 1 2 D ( d u p ) 1 8 - D e c - 0 0 0.0 0 1 1 MW - 1 2 D 1 7 - A p r - 0 1 MW - 1 2 D 2 8 - N o v - 0 1 MW - 1 2 D 3 - A p r - 0 2 MW - 1 2 D 5 - N o v - 0 2 MW - 1 2 D 1 5 - A p r - 0 3 MW - 1 2 D 3 0 - O c t - 0 3 MW - 1 2 D 7 - A p r - 0 4 MW - 1 2 D 1 8 - N o v - 0 4 MW - 1 2 D 2 1 - A p r - 0 5 MW - 1 2 D 1 1 - N o v - 0 5 MW - 1 2 D 1 3 - A p r - 0 6 MW - 1 2 D 8 - N o v - 0 6 MW - 1 2 D 2 0 - A p r - 0 7 MW - 1 2 D 7 - N o v - 0 7 MW - 1 2 D 1 4 - M a y - 0 8 0 . 0 2 2 8 J 0 . 0 0 3 4 5 J 0 . 0 1 3 1 0 . 0 0 9 4 7 J MW - 1 2 D 5 - N o v - 0 8 0 . 0 1 6 4 J 0.0 0 4 7 4 0.0 0 0 1 4 J 0 . 0 1 0 2 0 . 0 0 4 0 9 J 0.0 0 1 2 4 J B MW - 1 2 D 1 8 - M a r - 0 9 0 . 0 0 7 3 1 J 0 . 0 0 0 2 7 J 0. 0 1 3 2 B 0.0 0 1 3 4 J B 0.00773 0 . 0 1 0 1 J B MW - 1 2 D 2 0 - O c t - 0 9 0 . 0 2 5 6 J B 0 . 0 0 0 2 2 J 0 . 0 0 4 1 6 J B 0 . 0 2 1 B 0.00527J 0.00272JB MW - 1 2 D 6 - M a y - 1 0 0 . 0 1 9 7 J 0.0 0 8 6 2 J 0.00258J MW - 1 2 D 2 9 - O c t - 1 0 0 . 0 2 1 2 J 0. 0 1 0 4 0.000502J 0 . 0 0 2 5 3 J MW - 1 2 D 6 - M a y - 1 0 0 . 0 1 9 7 J 0.0 0 8 6 2 J 0.00258J MW - 1 2 D 2 9 - O c t - 1 0 0 . 0 2 1 2 J 0. 0 1 0 4 0.000502J 0 . 0 0 2 5 3 J MW - 1 2 D 1 5 - M a r - 1 1 0 . 0 2 5 4 J 0. 0 1 1 7 0.000156J 0.00201J MW - 1 2 D 2 0 - O c t - 1 1 0 . 0 2 6 4 J 0.0 0 9 4 5 J 0.00179J MW - 1 2 D 1 1 - A p r - 1 2 0 . 0 0 0 7 2 J 0 . 0 2 4 9 J 0. 0 1 4 9 0.00146J MW - 1 2 D 2 6 - O c t - 1 2 0. 0 0 1 2 6 J 0. 0 2 7 4 J 0 . 0 0 2 7 3 J 0 . 0 0 9 7 9 J 0.00245J 0.00914J MW - 1 2 D 1 1 - A p r - 1 3 0 . 0 0 0 5 J 0 . 0 3 J 0 . 0 0 0 5 J B 0 . 0 0 0 2 J B 0 . 0 1 7 0 . 0 0 0 9 J B MW - 1 2 D ( d u p ) 1 1 - A p r - 1 3 0 . 0 0 0 7 J 0 . 0 3 J 0 . 0 0 0 2 J 0 . 0 0 0 6 J B 0 . 0 0 0 2 J B 0 . 0 1 4 0 . 0 0 0 2 J 0 . 0 0 0 9 J B 0.005J MW - 1 2 D 2 - O c t - 1 3 0 . 0 3 J B 0 . 0 0 0 0 6 J B 0. 0 0 1 J 0.0 1 2 0 . 0 0 0 9 J MW - 1 2 D 4 - A p r - 1 4 0 . 0 0 0 4 J 0 . 0 2 0 J 0 . 0 0 0 3 J 0 . 0 0 0 1 J 0 . 0 0 6 J 0.002J 0 . 0 0 7 J B MW - 1 2 D 1 3 - N o v - 1 4 0.0 0 1 5 J 0. 0 4 0 J 0 . 0 0 0 0 6 J 0 . 0 0 1 0 J 0. 0 8 5 0 . 0 0 2 J 0.0 3 2 0 . 0 0 1 J 0 . 0 4 1 J 0 . 0 0 0 0 6 J 0.007J 0.017 MW - 1 2 D 8 - A p r - 1 5 0 . 0 0 0 4 J B 0 . 0 2 0 J 0 . 0 0 0 2 J 0. 0 2 9 0.0 0 0 5 J 0 . 0 1 5 0 . 0 0 0 3 J 0 . 0 1 4 J 0.006JB MW - 1 2 D 7 - O c t - 1 5 0 . 0 0 0 6 J 0 . 0 2 0 J 0 . 0 0 0 6 J 0 . 0 0 1 J 0 . 0 0 0 2 J 0 . 0 0 9 J 0 . 0 0 1 J 0.010 MW - 1 2 D 2 5 - M a r - 1 6 0 . 0 0 0 3 J 0 . 0 1 7 0 . 0 0 1 0 J B 0 . 0 0 0 2 J 0 . 0 0 5 3 J 0 . 0 0 0 7 J 0.0018J MW - 1 2 D 1 - S e p - 1 6 0 . 0 2 5 J 0 . 0 0 0 0 5 4 J 0 . 0 0 0 5 2 J 0 . 0 0 8 2 B J 0.0023J 0.0035J MW - 1 2 D ( d i s s o l v e d ) 1 - S e p - 1 6 0 . 0 2 6 J 0 . 0 0 0 0 7 J 0. 0 0 1 J 0.0 0 0 8 1 B J 0 . 0 0 0 9 4 J 0.0025J 0.0032J Pa g e 4 o f 1 8 October 2016 Ap p e n d i x A De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s Al t e r n a t e S o u r c e D e m o n s t r a t i o n No r t h W a k e L i n e d L a n d f i l l Pe r m i t N o . 9 2 0 9 M o n i t o r i n g W e l l C o d e S a m p l e D a t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r L e a d M e r c u r y N i c k e l S e l e n i u m S i l v e r Thallium VanadiumZinc 0. 0 0 1 * 0 . 0 1 0 . 7 0 . 0 0 4 * 0 . 0 0 2 0 . 0 1 0 . 0 0 1 * 1 0 . 0 1 5 0 . 0 0 1 0 . 1 0 . 0 2 0 . 0 2 0 . 0 0 0 2 * 0 . 0 0 0 3 * 1 0. 0 0 6 0 . 0 1 0 0 . 1 0 . 0 0 1 0 . 0 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 0 0 2 0 . 0 5 0 . 0 1 0 . 0 1 0 . 0 0 5 5 0 . 0 2 5 0 . 0 1 So l i d W a s t e S e c t i o n L i m i t No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d MW - 1 3 31 - O c t - 9 5 0.0 0 2 0. 0 2 2 0. 0 6 3 0.044 0.069 MW - 1 3 1 9 - D e c - 9 5 MW - 1 3 2 6 - F e b - 9 6 MW - 1 3 2 9 - A p r - 9 6 MW - 1 3 2 7 - N o v - 9 6 0 . 0 1 8 MW - 1 3 2 4 - A p r - 9 7 MW - 1 3 7 - M a y - 9 8 0. 0 2 1 MW - 1 3 2 3 - N o v - 9 8 0. 0 0 6 8 0 . 0 5 9 0 . 0 1 9 0.081 0.12 MW - 1 3 1 4 - A p r - 9 9 MW - 1 3 1 - D e c - 9 9 MW - 1 3 6 - A p r - 0 0 MW - 1 3 1 8 - D e c - 0 0 0.0 0 1 1 0. 0 1 0 2 MW - 1 3 1 7 - A p r - 0 1 MW - 1 3 2 8 - N o v - 0 1 N S N S N S N S N S N S N S N S N S N S N S N S N S N S N S MW - 1 3 3 - A p r - 0 2 MW - 1 3 6 - N o v - 0 2 MW - 1 3 1 5 - A p r - 0 3 MW - 1 3 ( d u p ) 1 5 - A p r - 0 3 MW - 1 3 3 0 - O c t - 0 3 MW - 1 3 8 - A p r - 0 4 0. 0 2 2 2 MW - 1 3 ( d u p ) 8 - A p r - 0 4 MW - 1 3 1 8 - N o v - 0 4 0. 0 8 6 0 . 0 3 3 0.099 0.1 MW - 1 3 2 1 - A p r - 0 5 MW - 1 3 1 1 - N o v - 0 5 0 . 5 7 8 0. 0 1 5 8 0. 1 0 9 0.217 0.272 MW - 1 3 1 3 - A p r - 0 6 0. 0 1 2 MW - 1 3 8 - N o v - 0 6 0. 0 1 7 MW - 1 3 2 0 - A p r - 0 7 0.012 MW - 1 3 7 - N o v - 0 7 0 . 1 5 7 0. 0 2 4 0.03 0.062 MW - 1 3 1 3 - M a y - 0 8 0 . 0 4 4 6 J 0 . 0 0 7 4 8 J 0 . 0 0 4 6 6 J 0 . 0 0 8 8 1 J 0.00589J 0.00845J MW - 1 3 4 - N o v - 0 8 0 . 0 6 8 6 J 0. 0 1 4 4 0.0 0 1 6 9 J 0 . 0 0 4 1 J 0. 0 0 1 4 J B 0.0165J 0.0199 MW - 1 3 1 8 - M a r - 0 9 0 . 0 5 6 6 J 0. 0 1 1 1 0.0 0 4 8 6 J B 0.0 0 1 5 6 J B 0.0061 0 . 0 2 3 1 J B 0.0131 MW - 1 3 2 1 - O c t - 0 9 0 . 0 7 9 1 J B 0.0 1 7 8 B 0 . 0 0 4 1 J 0.0 0 9 1 5 J B 0 . 0 0 7 2 8 J 0.0269 0.0228B MW - 1 3 7 - M a y - 1 0 0 . 0 0 4 1 J 0. 8 3 8 0.0 0 1 2 6 0. 2 1 0 . 0 8 1 4 0. 0 1 6 4 0. 0 2 2 7 0 . 1 0 7 0 . 0 0 0 7 0 7 J 0 . 2 7 4 0.339 MW - 1 3 2 9 - O c t - 1 0 0 . 1 2 7 0. 0 2 8 7 0 . 0 0 9 2 4 J 0.0 0 2 8 6 J 0 . 0 0 4 4 4 J 0 . 0 1 4 3 J 0.000487J 0 . 0 4 0 4 0.0457 MW - 1 3 1 5 - M a r - 1 1 0 . 0 7 9 3 J 0 . 0 0 0 1 5 9 J 0. 0 1 4 7 0 . 0 0 3 8 8 J 0.0 0 2 3 3 J 0 . 0 0 3 4 3 J 0 . 0 0 5 6 6 J 0 . 0 0 0 1 3 5 J 0.0185J 0.0293 MW - 1 3 2 0 - O c t - 1 1 0 . 1 5 3 0. 0 3 0 5 0 . 0 0 9 9 5 J 0.0 0 2 2 6 J 0 . 0 0 5 3 3 J 0 . 0 1 5 6 J 0 . 0 0 2 0 9 J 0.0403 0.0617 MW - 1 3 1 1 - A p r - 1 2 0 . 0 0 0 9 2 9 J 0 . 1 9 6 0. 0 4 5 8 0 . 0 1 3 6 0.0 0 2 3 4 J 0 . 0 0 8 6 2 J 0 . 0 2 2 3 J 0 . 0 0 2 3 4 J 0.000336J 0 . 0 5 6 4 0.0702 MW - 1 3 2 6 - O c t - 1 2 0 . 0 0 5 4 0 J 0 . 2 9 7 0. 0 7 3 1 0 . 0 2 2 3 0.0 0 4 6 2 J 0 . 0 1 4 6 0 . 0 3 8 8 J 0.000212J 0 . 0 9 4 9 0.126 MW - 1 3 1 1 - A p r - 1 3 0 . 1 1 0 . 0 0 0 5 J 0. 0 2 4 0 . 0 0 7 J 0.0 0 2 J 0 . 0 0 3 J 0 . 0 1 2 J 0.0002J 0 . 0 2 7 0.031 MW - 1 3 2 - O c t - 1 3 0 . 0 7 0 J 0 . 0 0 0 3 J B 0. 0 1 4 0 . 0 0 4 J 0.0 0 1 J 0 . 0 0 1 J 0 . 0 0 7 J 0 . 0 0 0 1 J 0.019J 0.015B MW - 1 3 4 - A p r - 1 4 0 . 0 7 0 J 0 . 0 0 0 2 J 0. 0 1 0 J 0 . 0 0 3 J 0. 0 0 0 9 J 0 . 0 0 1 J 0 . 0 0 5 J 0 . 0 0 0 0 7 J 0.016J 0.018B MW - 1 3 1 2 - N o v - 1 4 0 . 0 4 0 J 0 . 0 0 0 0 6 J 0 . 0 0 5 J 0.0 0 0 9 J 0. 0 0 0 3 J 0 . 0 0 0 3 J 0 . 0 0 2 J 0.006J 0.005J MW - 1 3 8 - A p r - 1 5 0 . 0 5 0 J 0 . 0 0 0 1 J 0 . 0 0 7 J 0. 0 0 2 J 0.0 0 1 J 0 . 0 0 0 7 J 0 . 0 0 3 J 0.009J 0.013B MW - 1 3 7 - O c t - 1 5 0 . 0 6 0 J 0 . 0 0 0 2 J 0. 0 1 2 0 . 0 0 3 J 0. 0 0 0 9 J 0 . 0 0 1 J 0 . 0 0 5 J 0 . 0 0 0 0 7 J 0.010J 0.018 MW - 1 3 2 5 - M a r - 1 6 0 . 0 3 5 J 0 . 0 0 0 1 2 J 0 . 0 0 6 6 J 0.0 0 1 6 J 0. 0 0 0 5 J 0 . 0 0 0 6 4 J 0 . 0 0 2 9 J 0.0095J MW - 1 3 1 - S e p - 1 6 0 . 0 0 0 2 J 0 . 1 7 0 . 0 0 0 6 6 J 0 . 0 0 0 0 5 9 J 0 . 0 3 2 0.0 1 0. 0 0 2 9 B J 0 . 0 0 4 1 J 0 . 0 1 5 J 0 . 0 0 0 1 7 J 0.00028J 0 . 0 4 2 0.054 MW - 1 3 ( d i s s o l v e d ) 1 - S e p - 1 6 0 . 0 2 3 J 0 . 0 0 1 1 J 0 . 0 0 0 3 0 B J 0 . 0 0 0 8 0 J 0.0042J 0.0034J Pa g e 5 o f 1 8 October 2016 Ap p e n d i x A De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s Al t e r n a t e S o u r c e D e m o n s t r a t i o n No r t h W a k e L i n e d L a n d f i l l Pe r m i t N o . 9 2 0 9 M o n i t o r i n g W e l l C o d e S a m p l e D a t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r L e a d M e r c u r y N i c k e l S e l e n i u m S i l v e r Thallium VanadiumZinc 0. 0 0 1 * 0 . 0 1 0 . 7 0 . 0 0 4 * 0 . 0 0 2 0 . 0 1 0 . 0 0 1 * 1 0 . 0 1 5 0 . 0 0 1 0 . 1 0 . 0 2 0 . 0 2 0 . 0 0 0 2 * 0 . 0 0 0 3 * 1 0. 0 0 6 0 . 0 1 0 0 . 1 0 . 0 0 1 0 . 0 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 0 0 2 0 . 0 5 0 . 0 1 0 . 0 1 0 . 0 0 5 5 0 . 0 2 5 0 . 0 1 So l i d W a s t e S e c t i o n L i m i t No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d MW - 1 4 31 - O c t - 9 5 0. 0 5 2 MW - 1 4 1 9 - D e c - 9 5 MW - 1 4 2 6 - F e b - 9 6 0.0 2 1 MW - 1 4 2 9 - A p r - 9 6 0. 0 1 3 0. 0 1 2 MW - 1 4 2 7 - N o v - 9 6 0 . 0 1 1 MW - 1 4 2 4 - A p r - 9 7 0.098 MW - 1 4 1 - N o v - 9 7 0.098 MW - 1 4 7 - M a y - 9 8 0. 0 3 4 0. 0 8 8 0.064 MW - 1 4 2 3 - N o v - 9 8 MW - 1 4 ( d u p ) 2 3 - N o v - 9 8 MW - 1 4 1 4 - A p r - 9 9 MW - 1 4 1 - D e c - 9 9 0.0 0 1 MW - 1 4 6 - A p r - 0 0 MW - 1 4 ( d u p ) 6 - A p r - 0 0 MW - 1 4 1 8 - D e c - 0 0 MW - 1 4 1 7 - A p r - 0 1 MW - 1 4 2 8 - N o v - 0 1 MW - 1 4 3 - A p r - 0 2 MW - 1 4 5 - N o v - 0 2 MW - 1 4 1 5 - A p r - 0 3 0.0 0 1 7 MW - 1 4 2 9 - O c t - 0 3 MW - 1 4 8 - A p r - 0 4 MW - 1 4 1 8 - N o v - 0 4 MW - 1 4 2 1 - A p r - 0 5 MW - 1 4 1 1 - N o v - 0 5 MW - 1 4 1 3 - A p r - 0 6 MW - 1 4 8 - N o v - 0 6 MW - 1 4 2 0 - A p r - 0 7 MW - 1 4 7 - N o v - 0 7 0.0 1 3 0.025 MW - 1 4 1 3 - M a y - 0 8 0 . 0 3 3 8 J 0 . 0 0 5 5 4 J 0 . 0 0 6 4 2 J 0 . 0 0 7 8 7 J MW - 1 4 4 - N o v - 0 8 0 . 0 2 5 8 J 0 . 0 0 0 3 7 J 0 . 0 0 3 2 8 J 0 . 0 0 3 3 3 J 0 . 0 0 3 7 5 J 0.0 0 1 1 6 J B 0.00083J 0.00508J MW - 1 4 1 8 - M a r - 0 9 0 . 0 2 5 7 J 0 . 0 0 2 6 5 J 0 . 0 0 8 2 5 J B 0. 0 0 1 3 J B 0.0124JB MW - 1 4 2 1 - O c t - 0 9 0 . 0 0 5 3 2 J 0 . 0 3 2 5 J B 0 . 0 0 6 2 3 J B 0 . 0 0 9 6 1 J B 0.00875J 0.00574JB MW - 1 4 7 - M a y - 1 0 0 . 0 2 4 8 J 0 . 0 0 2 1 J 0.00486J 0.00484J MW - 1 4 2 8 - O c t - 1 0 0 . 0 4 0 6 J 0 . 0 0 6 7 3 J 0.0 0 1 7 J 0.0 0 6 3 2 J 0 . 0 0 3 0 5 J 0.000289J 0 . 0 1 2 6 J 0.0136 MW - 1 4 1 5 - M a r - 1 1 0 . 0 2 6 1 J 0 . 0 0 2 5 6 J 0.00484J 0.00465J MW - 1 4 2 0 - O c t - 1 1 0 . 0 4 0 2 J 0 . 0 0 4 2 3 J 0. 0 0 2 7 1 J 0.0 0 4 4 9 J 0 . 0 0 3 2 3 J 0.0103J 0.0142 MW - 1 4 1 1 - A p r - 1 2 0 . 0 7 1 5 J 0 . 0 0 0 1 4 6 J 0 . 0 0 8 1 3 J 0. 0 0 5 8 4 J 0. 0 1 5 6 0 . 0 0 4 8 3 J 0 . 0 0 6 8 2 J 0.0217J 0.0186 MW - 1 4 2 6 - O c t - 1 2 0 . 0 0 3 3 8 J 0 . 1 0 9 0. 0 1 7 5 0 . 0 0 8 7 4 J 0. 0 2 1 6 0 . 0 0 6 4 4 J 0 . 0 1 3 7 J 0.0281 0.0356 MW - 1 4 1 1 - A p r - 1 3 0 . 1 1 0 0 . 0 0 0 5 J 0. 0 1 4 0 . 0 0 9 J 0.0 2 3 0 . 0 0 5 J 0 . 0 1 5 J 0 . 0 0 0 1 J 0.036 0.029 MW - 1 4 2 - O c t - 1 3 0 . 1 1 0 0 . 0 0 0 6 J 0 . 0 0 0 1 J 0. 0 1 2 0 . 0 0 7 J 0.0 2 2 0 . 0 0 4 J 0 . 0 1 2 J 0 . 0 0 0 1 J 0.034 0.033B MW - 1 4 4 - A p r - 1 4 0 . 0 8 0 J 0 . 0 0 0 2 J 0. 0 0 6 J 0 . 0 0 4 J 0.0 1 0 J 0 . 0 0 2 J 0 . 0 0 5 J 0.026 0.023B MW - 1 4 1 3 - N o v - 1 4 0 . 0 0 3 J 0 . 0 0 0 0 5 J 0 . 0 0 0 2 J 0. 0 2 2 0 . 0 0 1 J 0.0 0 3 J 0 . 0 0 0 3 J 0 . 0 1 1 J 0.005J 0.004J MW - 1 4 8 - A p r - 1 5 0 . 0 3 0 J 0 . 0 0 0 0 9 J 0 . 0 0 4 J 0. 0 0 1 J 0.0 0 4 J 0 . 0 0 0 7 J 0 . 0 0 2 J 0.006J 0.008JB MW - 1 4 8 - O c t - 1 5 0 . 0 5 0 J 0 . 0 0 0 2 J 0 . 0 0 7 J 0. 0 0 4 J 0.0 1 1 0 . 0 0 2 J 0 . 0 0 6 J 0.013J 0.019 MW - 1 4 2 5 - M a r - 1 6 0 . 0 5 7 J 0 . 0 0 0 1 7 J 0 . 0 0 6 5 J 0.0 0 3 7 J 0. 0 0 8 6 J 0 . 0 0 1 7 1 J 0 . 0 0 5 7 J 0 . 0 0 0 0 7 J 0.012J 0.0138 MW - 1 4 1 - S e p - 1 6 0 . 0 6 0 J 0 . 0 0 0 2 8 J 0 . 0 0 0 0 4 5 J 0 . 0 0 6 9 J 0.0 0 4 8 J 0.0 1 1 B 0 . 0 0 2 5 J 0 . 0 0 6 4 J 0 . 0 0 0 2 1 J 0 . 0 0 0 0 7 5 J 0.018J 0.017 MW - 1 4 ( d i s s o l v e d ) 1 - S e p - 1 6 0 . 0 1 6 J 0 . 0 0 1 3 J 0 . 0 0 0 3 0 B J 0 . 0 0 0 9 1 J 0.005J 0.0031J Pa g e 6 o f 1 8 October 2016 Ap p e n d i x A De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s Al t e r n a t e S o u r c e D e m o n s t r a t i o n No r t h W a k e L i n e d L a n d f i l l Pe r m i t N o . 9 2 0 9 M o n i t o r i n g W e l l C o d e S a m p l e D a t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r L e a d M e r c u r y N i c k e l S e l e n i u m S i l v e r Thallium VanadiumZinc 0. 0 0 1 * 0 . 0 1 0 . 7 0 . 0 0 4 * 0 . 0 0 2 0 . 0 1 0 . 0 0 1 * 1 0 . 0 1 5 0 . 0 0 1 0 . 1 0 . 0 2 0 . 0 2 0 . 0 0 0 2 * 0 . 0 0 0 3 * 1 0. 0 0 6 0 . 0 1 0 0 . 1 0 . 0 0 1 0 . 0 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 0 0 2 0 . 0 5 0 . 0 1 0 . 0 1 0 . 0 0 5 5 0 . 0 2 5 0 . 0 1 So l i d W a s t e S e c t i o n L i m i t No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d MW - 1 5 31 - O c t - 9 5 0. 0 1 2 0. 0 6 4 MW - 1 5 1 9 - D e c - 9 5 MW - 1 5 2 6 - F e b - 9 6 0. 0 3 6 0 . 0 1 2 0.143 MW - 1 5 2 9 - A p r - 9 6 0.0 0 5 0 . 1 9 6 0 . 0 5 2 0.5 0 3 0.0 3 4 0. 0 9 4 0.410 0.240 MW - 1 5 2 7 - N o v - 9 6 0 . 1 5 0 . 0 0 3 0. 0 0 7 0.0 1 7 0.051 0.046 MW - 1 5 ( d u p ) 2 7 - N o v - 9 6 0 . 2 0 . 0 0 4 0. 0 0 7 0.0 2 1 0.072 0.046 MW - 1 5 2 4 - A p r - 9 7 0.078 MW - 1 5 ( d u p ) 2 4 - A p r - 9 7 MW - 1 5 3 1 - O c t - 9 7 0.078 MW - 1 5 7 - M a y - 9 8 0.012 MW - 1 5 2 3 - N o v - 9 8 0. 0 0 2 5 0. 0 1 0.040 0.12 MW - 1 5 1 4 - A p r - 9 9 0.0 0 1 1 0.0159 MW - 1 5 1 - D e c - 9 9 MW - 1 5 6 - A p r - 0 0 0.0 0 1 5 MW - 1 5 1 8 - D e c - 0 0 0.0 0 1 4 0.0 1 0 2 0.0941 0.475 MW - 1 5 1 7 - A p r - 0 1 MW - 1 5 ( d u p ) 1 7 - A p r - 0 1 MW - 1 5 2 8 - N o v - 0 1 0.0 0 1 1 0.0669 0.165 MW - 1 5 3 - A p r - 0 2 MW - 1 5 6 - N o v - 0 2 MW - 1 5 1 5 - A p r - 0 3 0.0 0 1 9 0. 0 1 9 5 0 . 0 1 6 9 0.0617 MW - 1 5 2 9 - O c t - 0 3 MW - 1 5 8 - A p r - 0 4 MW - 1 5 1 8 - N o v - 0 4 0. 0 6 0 . 0 2 5 0. 0 5 2 0.142 0.09 MW - 1 5 2 1 - A p r - 0 5 MW - 1 5 1 1 - N o v - 0 5 MW - 1 5 1 3 - A p r - 0 6 MW - 1 5 8 - N o v - 0 6 0. 0 1 1 0.061 MW - 1 5 2 0 - A p r - 0 7 MW - 1 5 7 - N o v - 0 7 0.0 1 5 0.027 0.077 MW - 1 5 1 3 - M a y - 0 8 0 . 0 8 9 6 J 0. 0 1 2 1 0 . 0 0 5 2 6 J 0. 0 1 9 7 0 . 0 0 5 1 5 J 0 . 0 1 3 9 0.0191J 0.0134 MW - 1 5 3 - N o v - 0 8 0 . 0 6 6 5 J 0 . 0 0 0 3 J 0 . 0 0 4 4 9 J 0 . 0 0 6 6 2 J 0 . 0 0 9 6 J 0 . 0 0 2 0 1 J B 0.00504J 0.00882J MW - 1 5 1 8 - M a r - 0 9 0 . 0 7 7 4 J 0 . 0 0 0 1 8 J 0 . 0 0 6 9 2 J 0. 0 0 3 4 7 J 0. 0 1 6 2 B 0.0 0 1 9 3 J B 0.0064 0 . 0 2 7 7 B 0.00954J MW - 1 5 2 1 - O c t - 0 9 0 . 0 5 1 3 J 0 . 0 0 3 0 8 J 0 . 0 0 6 6 9 J B 0 . 0 0 8 0 6 J 0 . 0 0 2 8 6 J 0.0213JB 0.00773JB MW - 1 5 7 - M a y - 1 0 0 . 1 4 1 0 . 0 0 7 8 7 J 0. 0 0 7 9 1 J 0. 0 1 3 8 0 . 0 0 3 0 2 J 0 . 0 0 3 1 5 J 0.0239J 0.0228 MW - 1 5 2 8 - O c t - 1 0 0 . 0 6 2 3 J 0 . 0 0 4 8 9 J 0. 0 0 2 1 7 J 0.0 0 8 8 1 J 0 . 0 0 8 2 2 J 0.000251J 0 . 0 2 0 1 J 0.0251 MW - 1 5 1 4 - M a r - 1 1 0 . 0 7 9 5 J 0 . 0 0 4 7 8 J 0. 0 0 3 0 4 J 0.0 0 9 3 1 J 0 . 0 0 2 0 3 J 0 . 0 1 0 4 J 0.0318 0.0223 MW - 1 5 2 0 - O c t - 1 1 0 . 2 4 9 0 . 0 0 0 6 6 J 0. 0 5 7 7 0 . 0 1 9 4 0. 0 9 0 8 0 . 0 0 8 6 7 J 0 . 0 3 3 J 0 . 0 0 1 2 7 J 0 . 0 0 4 1 6 J 0.000489J 0 . 1 4 4 0.0716 MW - 1 5 1 1 - A p r - 1 2 0 . 2 0 0 0. 0 3 8 9 0 . 0 1 3 2 0. 0 6 2 3 0 . 0 0 7 9 6 J 0 . 0 2 1 9 J 0 . 0 0 1 8 7 J 0.000251J 0 . 0 9 3 8 0.0512 MW - 1 5 2 6 - O c t - 1 2 0 . 0 0 3 0 5 J 0 . 2 6 9 0. 0 5 0 7 0 . 0 1 9 4 0. 0 9 3 8 0 . 0 0 9 6 8 J 0 . 0 3 4 6 J 0 . 0 0 1 6 7 J 0 . 0 0 2 9 8 J 0.000276J 0 . 1 5 3 0.0834 MW - 1 5 1 1 - A p r - 1 3 0 . 1 8 0 0 . 0 0 0 3 J 0 . 0 0 0 4 J 0. 0 3 1 0 . 0 1 J 0.0 4 6 0 . 0 0 3 J 0 . 0 1 8 J 0.0002J 0 . 0 6 9 0.032 MW - 1 5 2 - O c t - 1 3 0 . 2 2 0 0 . 0 0 0 3 J B 0 . 0 0 0 6 J 0. 0 3 1 0 . 0 1 J 0.0 5 5 0 . 0 0 3 J 0 . 0 1 7 J 0.0002J 0 . 0 9 3 0.035B MW - 1 5 4 - A p r - 1 4 0 . 1 2 0 0 . 0 0 0 0 7 J 0 . 0 0 0 1 J 0 . 0 0 3 J 0. 0 0 4 J 0.0 0 7 J 0 . 0 0 0 7 J 0 . 0 0 2 J 0.018J 0.011B MW - 1 5 1 3 - N o v - 1 4 0 . 0 7 0 J 0 . 0 0 0 2 J 0 . 0 0 1 J 0. 0 0 4 J 0.0 0 3 J 0 . 0 0 2 J 0.004J 0.008J MW - 1 5 9 - A p r - 1 5 0 . 0 9 0 J 0 . 0 0 0 1 J 0 . 0 0 2 J 0. 0 0 4 J 0.0 0 3 J 0 . 0 0 0 3 J 0 . 0 0 1 J 0.003J 0.005JB MW - 1 5 8 - O c t - 1 5 0 . 0 8 0 J 0 . 0 0 0 1 J 0 . 0 0 7 J 0. 0 0 8 J 0.0 1 0 0 . 0 0 0 5 J 0 . 0 1 0 J 0 . 0 0 0 0 6 J 0.006J 0.017 MW - 1 5 2 5 - M a r - 1 6 0 . 1 0 7 0 . 0 0 0 1 1 J 0 . 0 0 0 1 2 J 0. 0 1 0 8 0 . 0 0 3 2 J 0. 0 1 5 1 0 . 0 0 1 2 8 J 0 . 0 0 4 4 J 0 . 0 0 0 1 J 0.019J 0.0167 MW - 1 5 ( d u p ) 2 5 - M a r - 1 6 0 . 0 0 0 7 J 0 . 1 2 8 0 . 0 0 0 1 0 J 0 . 0 0 0 2 3 J 0. 0 1 3 6 0 . 0 0 4 4 J 0. 0 1 9 4 0 . 0 0 1 3 7 J 0 . 0 0 6 2 J 0 . 0 0 1 J 0 . 0 0 0 1 3 J 0.025 0.0245 MW - 1 5 1 - S e p - 1 6 0 . 0 7 7 J 0 . 0 0 0 1 1 J 0 . 0 0 6 9 J 0.0 0 3 8 J 0.0 1 2 B 0 . 0 0 0 8 9 J 0 . 0 0 4 2 J 0.019J 0.013 MW - 1 5 ( d i s s o l v e d ) 1 - S e p - 1 6 0 . 0 4 1 J 0.0 0 1 5 J 0.0 0 0 4 4 B J 0 . 0 0 5 9 J 0.0088J Pa g e 7 o f 1 8 October 2016 Ap p e n d i x A De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s Al t e r n a t e S o u r c e D e m o n s t r a t i o n No r t h W a k e L i n e d L a n d f i l l Pe r m i t N o . 9 2 0 9 M o n i t o r i n g W e l l C o d e S a m p l e D a t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r L e a d M e r c u r y N i c k e l S e l e n i u m S i l v e r Thallium VanadiumZinc 0. 0 0 1 * 0 . 0 1 0 . 7 0 . 0 0 4 * 0 . 0 0 2 0 . 0 1 0 . 0 0 1 * 1 0 . 0 1 5 0 . 0 0 1 0 . 1 0 . 0 2 0 . 0 2 0 . 0 0 0 2 * 0 . 0 0 0 3 * 1 0. 0 0 6 0 . 0 1 0 0 . 1 0 . 0 0 1 0 . 0 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 0 0 2 0 . 0 5 0 . 0 1 0 . 0 1 0 . 0 0 5 5 0 . 0 2 5 0 . 0 1 So l i d W a s t e S e c t i o n L i m i t No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d MW - 1 5 D 31 - O c t - 9 5 MW - 1 5 D 1 9 - D e c - 9 5 MW - 1 5 D 2 6 - F e b - 9 6 MW - 1 5 D 2 9 - A p r - 9 6 MW - 1 5 D 2 7 - N o v - 9 6 0 . 0 5 0 . 0 0 3 0.005 MW - 1 5 D 2 4 - A p r - 9 7 0.05 MW - 1 5 D 3 1 - O c t - 9 7 0.0 1 3 0.05 MW - 1 5 D 7 - M a y - 9 8 0. 0 1 3 0.011 MW - 1 5 D 2 3 - N o v - 9 8 MW - 1 5 D 1 4 - A p r - 9 9 MW - 1 5 D 1 - D e c - 9 9 MW - 1 5 D 6 - A p r - 0 0 MW - 1 5 D 1 8 - D e c - 0 0 MW - 1 5 D 1 7 - A p r - 0 1 MW - 1 5 D 2 8 - N o v - 0 1 MW - 1 5 D 3 - A p r - 0 2 MW - 1 5 D 6 - N o v - 0 2 MW - 1 5 D 1 5 - A p r - 0 3 MW - 1 5 D 2 9 - O c t - 0 3 MW - 1 5 D 8 - A p r - 0 4 MW - 1 5 D 1 8 - N o v - 0 4 MW - 1 5 D 2 1 - A p r - 0 5 MW - 1 5 D 1 1 - N o v - 0 5 MW - 1 5 D 1 3 - A p r - 0 6 MW - 1 5 D 8 - N o v - 0 6 MW - 1 5 D 2 0 - A p r - 0 7 MW - 1 5 D 7 - N o v - 0 7 MW - 1 5 D 1 3 - M a y - 0 8 0 . 0 6 0 1 J 0 . 0 0 5 0 6 J 0 . 0 0 5 2 2 J 0 . 0 0 7 8 8 J 0.00536J MW - 1 5 D 5 - N o v - 0 8 0 . 0 6 3 6 J 0 . 0 0 2 8 2 J 0 . 0 0 3 9 4 J 0.0 0 1 1 1 J B MW - 1 5 D ( d u p ) 5 - N o v - 0 8 0 . 0 6 3 6 J 0 . 0 0 3 7 7 J 0.0 0 0 8 8 J B 0.00708J MW - 1 5 D 1 7 - M a r - 0 9 0 . 0 4 1 2 J 0 . 0 0 0 3 1 J 0 . 0 0 4 5 2 J 0 . 0 0 2 3 4 J 0 . 0 0 5 6 0 J 0.0 0 1 8 7 J B 0.0108JB 0.00755J MW - 1 5 D 2 0 - O c t - 0 9 0. 0 0 1 3 7 J 0. 0 0 5 3 4 J 0 . 0 6 8 5 J B 0 . 0 0 1 4 2 0 . 0 0 9 7 J B 0 . 0 1 4 B 0 . 0 0 9 4 7 J 0.00596J 0.0157B MW - 1 5 D ( d u p ) 2 0 - O c t - 0 9 0. 0 0 1 5 8 J 0. 0 6 9 8 J B 0 . 0 0 1 5 3 0 . 0 0 8 9 5 J B 0 . 0 1 3 8 B 0.0108J 0.0144B MW - 1 5 D 6 - M a y - 1 0 0 . 0 0 0 5 2 6 J 0 . 0 6 1 3 J 0 . 0 0 0 3 6 4 J 0 . 0 0 4 0 3 J 0.00430J 0.00436J MW - 1 5 D 2 7 - O c t - 1 0 0 . 0 0 0 5 6 3 J 0 . 0 5 3 1 J 0 . 0 0 0 8 2 7 J 0 . 0 0 3 6 7 J 0.000363J 0 . 0 0 4 0 9 J 0.00585J MW - 1 5 D 1 4 - M a r - 1 1 0 . 0 0 0 3 6 1 J 0 . 0 6 3 5 J 0 . 0 0 0 5 3 9 J 0 . 0 0 4 4 5 J 0 . 0 0 1 9 6 J 0 . 0 0 2 2 8 J 0.00432J 0.00414J MW - 1 5 D 1 9 - O c t - 1 1 0 . 0 0 0 7 1 3 J 0 . 0 7 1 5 J 0 . 0 0 0 4 2 3 J 0 . 0 0 5 J 0.00377J 0.00632J MW - 1 5 D 1 0 - A p r - 1 2 0. 0 0 1 0 3 J 0. 0 8 1 J 0 . 0 0 0 6 7 7 J 0 . 0 0 5 7 7 J 0 . 0 6 9 7 0 . 0 0 2 8 6 J 0.00415J 0.0156 MW - 1 5 D 2 5 - O c t - 1 2 0 . 0 7 9 6 J 0 . 0 0 0 7 2 7 J 0 . 0 0 3 6 4 J 0 . 0 1 8 6 0.00345J 0.0105 MW - 1 5 D 1 0 - A p r - 1 3 0.0 0 2 1 J 0. 0 8 0 J 0 . 0 0 0 4 J 0 . 0 0 3 J 0 . 0 0 0 0 9 J B 0 . 0 1 J 0 . 0 0 0 3 J 0 . 0 0 1 J 0.006J MW - 1 5 D 2 - O c t - 1 3 0 . 0 0 0 3 J 0 . 0 8 0 J 0 . 0 0 0 0 5 J B 0 . 0 0 1 J 0 . 0 0 0 1 J 0 . 0 0 2 J 0 . 0 0 0 9 J 0.002J MW - 1 5 D 4 - A p r - 1 4 0 . 0 0 0 5 J 0 . 0 7 0 J 0 . 0 0 0 3 J 0 . 0 0 1 J 0 . 0 0 0 0 6 J 0 . 0 0 3 J 0 . 0 0 1 0 J 0.005J 0.005JB MW - 1 5 D 1 3 - N o v - 1 4 0 . 0 0 0 6 J 0 . 0 7 0 J 0 . 0 0 0 2 J 0 . 0 0 1 J 0 . 0 0 0 1 J 0 . 0 0 2 J 0 . 0 0 0 8 J 0.005J MW - 1 5 D ( d u p ) 1 3 - N o v - 1 4 0 . 0 0 1 0 J 0 . 0 7 0 J 0 . 0 0 0 3 J 0 . 0 0 1 J 0 . 0 0 0 1 J 0 . 0 0 3 J 0 . 0 0 0 7 J 0.011 MW - 1 5 D 9 - A p r - 1 5 0 . 0 7 0 J 0 . 0 0 0 2 J 0 . 0 0 0 8 J 0 . 0 0 0 0 8 J 0 . 0 0 3 J 0 . 0 0 0 6 J 0.003JB MW - 1 5 D 8 - O c t - 1 5 0 . 0 7 0 J 0 . 0 0 0 6 J 0 . 0 0 1 J 0 . 0 0 0 0 9 J 0 . 0 0 2 J 0 . 0 0 2 J 0.010 MW - 1 5 D 2 5 - M a r - 1 6 0 . 0 0 0 3 J 0 . 0 7 1 J 0 . 0 0 0 3 2 J 0 . 0 0 1 3 J B 0 . 0 0 0 1 J 0 . 0 0 1 5 J 0 . 0 0 0 1 3 J 0 . 0 0 0 9 J 0.0060J MW - 1 5 D 1 - S e p - 1 6 0 . 0 0 0 2 7 J 0 . 0 6 6 J 0 . 0 0 0 0 6 1 J 0 . 0 0 1 2 B J 0 . 0 0 0 1 6 J 0 . 0 0 1 1 J 0.0036J 0.0059J MW - 1 5 D ( d i s s o l v e d ) 1 - S e p - 1 6 0. 0 7 2 J 0.0 0 1 B J 0.0 0 1 9 J 0.0039J 0.01 Pa g e 8 o f 1 8 October 2016 Ap p e n d i x A De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s Al t e r n a t e S o u r c e D e m o n s t r a t i o n No r t h W a k e L i n e d L a n d f i l l Pe r m i t N o . 9 2 0 9 M o n i t o r i n g W e l l C o d e S a m p l e D a t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r L e a d M e r c u r y N i c k e l S e l e n i u m S i l v e r Thallium VanadiumZinc 0. 0 0 1 * 0 . 0 1 0 . 7 0 . 0 0 4 * 0 . 0 0 2 0 . 0 1 0 . 0 0 1 * 1 0 . 0 1 5 0 . 0 0 1 0 . 1 0 . 0 2 0 . 0 2 0 . 0 0 0 2 * 0 . 0 0 0 3 * 1 0. 0 0 6 0 . 0 1 0 0 . 1 0 . 0 0 1 0 . 0 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 0 0 2 0 . 0 5 0 . 0 1 0 . 0 1 0 . 0 0 5 5 0 . 0 2 5 0 . 0 1 So l i d W a s t e S e c t i o n L i m i t No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d MW - 1 6 31 - O c t - 9 5 0. 5 9 0 0. 0 7 3 MW - 1 6 1 9 - D e c - 9 5 0 . 7 2 J 0. 2 0 4 MW - 1 6 2 6 - F e b - 9 6 0. 0 8 6 MW - 1 6 ( d u p ) 2 6 - F e b - 9 6 0. 0 2 0 MW - 1 6 2 9 - A p r - 9 6 0 . 0 0 3 0. 0 4 0 0 . 0 1 7 0 . 0 3 7 0.065 0.051 MW - 1 6 2 7 - N o v - 9 6 0 . 1 5 0. 0 0 2 MW - 1 6 2 4 - A p r - 9 7 0 . 0 1 B J 0. 0 1 2 0.0 1 1 0.14 MW - 1 6 3 1 - O c t - 9 7 0.0 1 0.045 MW - 1 6 ( d u p ) 3 1 - O c t - 9 7 0 . 0 1 9 J 0. 0 1 2 0 . 0 1 3 0.0 1 2 0.031 MW - 1 6 7 - M a y - 9 8 0. 0 1 2 0.015 MW - 1 6 2 3 - N o v - 9 8 0.0 0 1 5 MW - 1 6 1 4 - A p r - 9 9 0.0 0 1 3 MW - 1 6 1 - D e c - 9 9 0 . 0 3 9 J 0.0 0 1 3 MW - 1 6 6 - A p r - 0 0 0 . 1 0.0 1 3 3 MW - 1 6 1 8 - D e c - 0 0 MW - 1 6 1 7 - A p r - 0 1 MW - 1 6 2 8 - N o v - 0 1 0.0 1 3 3 MW - 1 6 3 - A p r - 0 2 MW - 1 6 6 - N o v - 0 2 MW - 1 6 1 5 - A p r - 0 3 MW - 1 6 2 9 - O c t - 0 3 MW - 1 6 ( d u p ) 2 9 - O c t - 0 3 MW - 1 6 8 - A p r - 0 4 0.0 1 5 1 0.0 1 2 4 MW - 1 6 1 8 - N o v - 0 4 d r y d r y d r y d r y d r y d r y d r y d r y d r y d r y d r y d r y d r y d r y d r y MW - 1 6 2 1 - A p r - 0 5 MW - 1 6 1 1 - N o v - 0 5 MW - 1 6 1 3 - A p r - 0 6 MW - 1 6 8 - N o v - 0 6 0. 0 1 2 0. 0 1 2 0 . 0 1 2 MW - 1 6 2 0 - A p r - 0 7 0 . 1 1 2 0.0 1 1 0.029 MW - 1 6 7 - N o v - 0 7 0 . 1 6 7 0.0 1 2 0.023 MW - 1 6 1 3 - M a y - 0 8 0 . 1 4 4 0 . 0 0 0 2 7 J 0. 0 1 5 2 0 . 0 0 7 5 2 J 0. 0 2 9 5 0 . 0 1 2 0 . 0 1 2 0 . 0 0 0 9 4 J 0.0307J 0.129 MW - 1 6 5 - N o v - 0 8 0 . 0 0 2 1 6 J 0 . 2 0 2 0 . 0 0 0 4 5 J 0. 0 1 0 5 0 . 0 1 3 3 0. 0 1 7 9 0 . 0 1 0 6 0 . 0 0 5 8 6 J 0 . 0 0 1 5 9 J B 0.0294 0.136 MW - 1 6 1 7 - M a r - 0 9 0 . 0 8 0 J 0 . 0 0 0 5 7 J 0 . 0 0 2 2 3 J 0 . 0 1 0 3 0 . 0 0 4 1 8 J 0.0 0 1 7 2 J B 0.0203JB 0.0226 MW - 1 6 2 0 - O c t - 0 9 0. 0 0 1 4 1 J 0.0 0 5 1 J 0 . 1 6 9 B 0 . 0 0 4 2 5 J B 0. 0 0 2 8 3 J 0. 0 1 2 9 B 0 . 0 0 2 7 1 J 0.0113J 0.0261B MW - 1 6 7 - M a y - 1 0 0 . 0 0 0 3 2 9 J 0 . 1 2 4 0 . 0 0 1 7 7 J 0.0 0 3 1 J 0.0 0 8 4 1 J 0 . 0 0 2 6 8 J 0.0049J 0.0304 MW - 1 6 2 8 - O c t - 1 0 0 . 0 0 0 7 2 6 J 0 . 1 1 1 0.0 0 5 1 7 J 0 . 0 0 2 1 J 0.000625J 0 . 0 0 4 5 3 J 0.0105 MW - 1 6 1 5 - M a r - 1 1 0 . 0 0 0 5 5 1 J 0 . 1 3 4 0 . 0 0 1 0 5 J 0.0 0 2 5 J 0.0 0 6 1 3 J 0 . 0 0 3 0 7 J 0.00391J 0.0147 MW - 1 6 2 0 - O c t - 1 1 0 . 0 0 0 2 6 2 J 0 . 1 5 4 0 . 0 0 1 3 5 J 0. 0 0 2 4 8 J 0.0 0 6 7 8 J 0 . 0 0 3 3 9 J 0.00449J 0.016 MW - 1 6 1 1 - A p r - 1 2 0 . 0 0 0 7 2 9 J 0 . 1 4 2 0 . 0 0 2 3 5 J 0. 0 0 4 0 9 J 0. 0 1 0 3 0 . 0 0 2 7 3 J 0.00695J 0.0184 MW - 1 6 2 6 - O c t - 1 2 0 . 1 7 6 0 . 0 0 6 4 1 J 0. 0 0 6 5 2 J 0. 0 2 2 9 0 . 0 0 3 6 3 J 0 . 0 0 6 6 2 J 0 . 0 0 0 1 4 3 J 0.013J 0.0481 MW - 1 6 1 1 - A p r - 1 3 0 . 0 0 0 3 J 0 . 0 0 0 8 J 0 . 1 3 0 0 . 0 0 0 3 J 0 . 0 0 1 J 0. 0 0 3 J 0.0 0 7 J 0 . 0 0 0 6 J 0 . 0 0 4 J 0 . 0 0 0 0 7 J 0 . 0 1 1 MW - 1 6 2 - O c t - 1 3 0 . 0 0 0 8 J 0 . 0 0 0 6 J 0 . 1 4 0 0 . 0 0 0 0 8 J B 0 . 0 0 0 2 J 0 . 0 0 0 7 J 0. 0 0 2 J 0.0 0 9 J 0 . 0 0 0 7 J 0 . 0 0 3 J 0 . 0 0 0 1 J 0.004J 0.015B MW - 1 6 4 - A p r - 1 4 0 . 0 0 0 3 J 0 . 0 0 1 J 0 . 1 2 0 0 . 0 0 0 1 J 0 . 0 0 0 3 J 0 . 0 0 2 J 0. 0 0 4 J 0. 0 2 0 . 0 0 3 J 0 . 0 0 4 J 0 . 0 0 0 0 9 J 0.012J 0.029B MW - 1 6 1 3 - N o v - 1 4 0 . 0 0 0 2 J 0 . 0 0 0 6 J 0 . 1 3 0 0 . 0 0 0 1 J 0 . 0 0 0 2 J 0 . 0 0 5 J 0. 0 0 3 J 0.0 1 3 0 . 0 0 2 J 0 . 0 0 4 J 0.011J 0.026 MW - 1 6 9 - A p r - 1 5 0 . 0 0 0 4 J B 0 . 0 0 0 9 J 0 . 1 1 0 0 . 0 0 0 1 J 0 . 0 0 0 5 J 0. 0 0 2 J 0.0 0 5 J 0 . 0 0 0 2 J 0 . 0 0 2 J 0 . 0 0 0 0 9 J 0 . 0 0 8 J B MW - 1 6 8 - O c t - 1 5 0 . 1 2 0 0 . 0 0 0 2 J 0 . 0 0 0 4 J 0. 0 0 2 J 0.0 0 6 J 0 . 0 0 2 J 0 . 0 0 0 1 J 0 . 0 3 2 MW - 1 6 2 5 - M a r - 1 6 0 . 0 0 0 3 J 0 . 1 1 9 0 . 0 0 0 1 4 J 0 . 0 0 0 5 J B 0.0 0 2 0 J 0. 0 0 5 2 J 0 . 0 0 0 1 9 J 0 . 0 0 2 6 J 0 . 0 0 0 0 8 J 0 . 0 5 7 3 MW - 1 6 1 - S e p - 1 6 0 . 0 0 0 2 J 0 . 0 0 0 2 8 J 0 . 0 9 9 J 0 . 0 0 0 1 3 J 0 . 0 0 1 5 J 0.0 0 3 3 J 0.0 0 7 1 B J 0 . 0 0 1 J 0 . 0 0 3 7 J 0 . 0 0 0 0 8 2 J 0.0049J 0.023 MW - 1 6 ( d i s s o l v e d ) 1 - S e p - 1 6 0 . 0 0 0 1 8 J 0 . 0 9 3 J 0 . 0 0 0 0 6 3 J 0.0 0 2 5 J 0.0 0 1 8 B J 0 . 0 0 3 3 J 0.0013J 0.029 Pa g e 9 o f 1 8 October 2016 Ap p e n d i x A De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s Al t e r n a t e S o u r c e D e m o n s t r a t i o n No r t h W a k e L i n e d L a n d f i l l Pe r m i t N o . 9 2 0 9 M o n i t o r i n g W e l l C o d e S a m p l e D a t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r L e a d M e r c u r y N i c k e l S e l e n i u m S i l v e r Thallium VanadiumZinc 0. 0 0 1 * 0 . 0 1 0 . 7 0 . 0 0 4 * 0 . 0 0 2 0 . 0 1 0 . 0 0 1 * 1 0 . 0 1 5 0 . 0 0 1 0 . 1 0 . 0 2 0 . 0 2 0 . 0 0 0 2 * 0 . 0 0 0 3 * 1 0. 0 0 6 0 . 0 1 0 0 . 1 0 . 0 0 1 0 . 0 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 0 0 2 0 . 0 5 0 . 0 1 0 . 0 1 0 . 0 0 5 5 0 . 0 2 5 0 . 0 1 So l i d W a s t e S e c t i o n L i m i t No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d MW - 1 7 31 - O c t - 9 5 MW - 1 7 1 9 - D e c - 9 5 0. 0 1 2 MW - 1 7 2 6 - F e b - 9 6 0.0 0 3 0. 0 3 6 0 . 0 1 1 0 . 0 1 6 0.104 0.052 MW - 1 7 2 9 - A p r - 9 6 0. 0 1 4 MW - 1 7 2 7 - N o v - 9 6 0 . 0 2 3 0. 0 0 3 MW - 1 7 2 4 - A p r - 9 7 0. 0 2 0.056 MW - 1 7 3 1 - O c t - 9 7 0. 0 1 3 0. 0 1 0.035 MW - 1 7 1 1 - M a y - 9 8 0. 0 1 1 0.13 MW - 1 7 2 3 - N o v - 9 8 MW - 1 7 1 4 - A p r - 9 9 MW - 1 7 1 - D e c - 9 9 MW - 1 7 6 - A p r - 0 0 MW - 1 7 1 8 - D e c - 0 0 MW - 1 7 1 7 - A p r - 0 1 MW - 1 7 2 9 - N o v - 0 1 MW - 1 7 3 - A p r - 0 2 MW - 1 7 ( d u p ) 3 - A p r - 0 2 MW - 1 7 6 - N o v - 0 2 MW - 1 7 1 5 - A p r - 0 3 MW - 1 7 2 9 - O c t - 0 3 MW - 1 7 8 - A p r - 0 4 MW - 1 7 1 8 - N o v - 0 4 MW - 1 7 2 1 - A p r - 0 5 MW - 1 7 1 1 - N o v - 0 5 0. 0 1 4 MW - 1 7 1 3 - A p r - 0 6 MW - 1 7 8 - N o v - 0 6 0.0 0 3 0. 0 2 0 . 0 1 7 0.042 MW - 1 7 2 0 - A p r - 0 7 MW - 1 7 7 - N o v - 0 7 0 . 1 0 7 0 . 0 0 3 0. 0 1 9 0.0 1 1 0.0 1 5 0.041 0.029 MW - 1 7 1 3 - M a y - 0 8 0 . 0 4 1 7 J 0. 0 1 1 2 0.0 0 8 0 8 J 0 . 0 0 8 4 4 J 0.0 0 1 5 J 0.0113J 0.00722J MW - 1 7 3 - N o v - 0 8 0 . 0 2 1 5 J 0.0 0 6 1 3 0.0 0 0 1 6 J 0 . 0 0 5 5 7 J 0 . 0 0 2 5 J 0. 0 0 1 4 4 J MW - 1 7 1 8 - M a r - 0 9 0 . 0 0 8 4 3 J 0.0 0 3 5 6 J B 0.0 0 1 1 5 J B 0.00763JB MW - 1 7 2 1 - O c t - 0 9 0 . 0 0 5 7 7 J 0 . 0 2 4 5 J B 0 . 0 0 4 5 3 J B 0 . 0 0 7 7 5 J B 0.00344 0.00259JB MW - 1 7 7 - M a y - 1 0 0 . 0 3 8 1 J 0 . 0 0 0 2 2 J 0. 0 1 0 6 0 . 0 0 2 4 3 J 0.0 0 4 9 3 J 0 . 0 0 4 5 3 J 0.0202J 0.028 MW - 1 7 2 9 - O c t - 1 0 0 . 0 3 5 2 J 0 . 0 0 7 2 8 J 0. 0 0 1 9 5 J 0.0 0 3 4 4 J 0 . 0 0 3 8 9 J 0 . 0 0 2 0 6 J 0.00111J 0 . 0 1 4 5 J 0.0147 MW - 1 7 1 5 - M a r - 1 1 0 . 0 2 2 6 J 0 . 0 0 1 5 7 J 0.00226J 0.00551J MW - 1 7 2 0 - O c t - 1 1 0 . 0 3 4 3 J 0 . 0 0 0 3 0 5 J 0 . 0 0 7 4 3 J 0. 0 0 1 4 9 J 0.0 0 2 5 2 J 0 . 0 0 2 0 8 J 0.0118J 0.00988J MW - 1 7 1 1 - A p r - 1 2 0 . 0 7 9 5 J 0 . 0 0 1 4 0. 0 2 6 6 0 . 0 0 6 5 9 J 0.0 1 3 0 . 0 1 2 0 . 0 0 6 3 5 J 0 . 0 0 0 1 1 5 J 0.0489 0.0243 MW - 1 7 2 6 - O c t - 1 2 0 . 0 8 1 7 J 0 . 0 0 0 6 1 6 J 0. 0 3 6 6 0 . 0 0 6 1 0 J 0. 0 2 0 4 0 . 0 1 3 3 0 . 0 0 7 3 4 J 0.0671 0.0293 MW - 1 7 1 1 - A p r - 1 3 0 . 0 5 J 0 . 0 0 1 1 J 0 . 0 0 0 1 J 0. 0 1 7 0 . 0 0 3 J 0.0 0 9 J 0 . 0 0 6 J 0 . 0 0 4 J 0.032 0.01 MW - 1 7 2 - O c t - 1 3 0 . 0 3 0 J 0 . 0 0 0 5 J 0 . 0 0 0 3 J 0 . 0 0 6 J 0. 0 0 2 J 0.0 0 3 J 0 . 0 0 2 J 0 . 0 0 2 J 0.012J 0.004JB MW - 1 7 4 - A p r - 1 4 0 . 0 5 0 J 0 . 0 0 1 2 0 . 0 0 0 2 J 0 . 0 1 9 0. 0 0 3 J 0.0 1 1 0 . 0 0 8 J 0 . 0 0 4 J 0 . 0 0 0 0 7 J 0.035 0.018B MW - 1 7 1 3 - N o v - 1 4 0 . 0 6 0 J 0 . 0 0 1 0 . 0 0 1 1 0 . 0 1 9 0. 0 0 4 J 0.0 0 9 J 0 . 0 0 7 J 0 . 0 0 5 J 0 . 0 0 0 0 7 J 0.034 0.015 MW - 1 7 9 - A p r - 1 5 0 . 0 0 0 6 J B 0 . 0 4 0 J 0 . 0 0 0 6 J 0 . 0 0 0 2 J 0. 0 1 0 . 0 0 2 J 0.0 0 5 J 0 . 0 0 4 J 0 . 0 0 2 J 0.016J 0.005JB MW - 1 7 8 - O c t - 1 5 0 . 0 3 0 J 0 . 0 0 0 5 J 0 . 0 0 0 3 J 0 . 0 0 9 J 0. 0 0 2 J 0.0 0 4 J 0 . 0 0 3 J 0 . 0 0 2 J 0.012J 0.015 MW - 1 7 2 5 - M a r - 1 6 0 . 0 2 1 J 0 . 0 0 0 1 2 J 0 . 0 0 0 1 5 J 0 . 0 0 1 3 J B 0 . 0 0 0 1 J 0 . 0 0 0 5 J 0 . 0 0 0 1 6 J 0.0035J MW - 1 7 1 - S e p - 1 6 0 . 0 0 0 1 8 J 0 . 0 1 8 J 0 . 0 0 0 1 8 J 0 . 0 0 0 1 1 J 0 . 0 0 1 5 J 0 . 0 0 0 3 4 J 0 . 0 0 0 8 3 B J 0 . 0 0 0 4 7 J 0 . 0 0 0 7 3 J 0.0033J 0.0035J MW - 1 7 ( d i s s o l v e d ) 1 - S e p - 1 6 0 . 0 1 7 J 0 . 0 0 0 0 6 7 J 0 . 0 0 0 5 3 B J 0 . 0 0 1 2 J 0.0014J 0.0041J Pa g e 1 0 o f 1 8 October 2016 Ap p e n d i x A De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s Al t e r n a t e S o u r c e D e m o n s t r a t i o n No r t h W a k e L i n e d L a n d f i l l Pe r m i t N o . 9 2 0 9 M o n i t o r i n g W e l l C o d e S a m p l e D a t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r L e a d M e r c u r y N i c k e l S e l e n i u m S i l v e r Thallium VanadiumZinc 0. 0 0 1 * 0 . 0 1 0 . 7 0 . 0 0 4 * 0 . 0 0 2 0 . 0 1 0 . 0 0 1 * 1 0 . 0 1 5 0 . 0 0 1 0 . 1 0 . 0 2 0 . 0 2 0 . 0 0 0 2 * 0 . 0 0 0 3 * 1 0. 0 0 6 0 . 0 1 0 0 . 1 0 . 0 0 1 0 . 0 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 0 0 2 0 . 0 5 0 . 0 1 0 . 0 1 0 . 0 0 5 5 0 . 0 2 5 0 . 0 1 So l i d W a s t e S e c t i o n L i m i t No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d MW - 1 7 D 31 - O c t - 9 5 MW - 1 7 D 1 9 - D e c - 9 5 MW - 1 7 D 2 6 - F e b - 9 6 MW - 1 7 D 2 9 - A p r - 9 6 MW - 1 7 D 2 7 - N o v - 9 6 0 . 0 2 6 0 . 0 0 5 MW - 1 7 D 2 4 - A p r - 9 7 MW - 1 7 D 3 1 - O c t - 9 7 MW - 1 7 D 1 1 - M a y - 9 8 0.058 MW - 1 7 D 2 3 - N o v - 9 8 MW - 1 7 D 1 4 - A p r - 9 9 MW - 1 7 D 1 - D e c - 9 9 MW - 1 7 D 6 - A p r - 0 0 MW - 1 7 D 1 8 - D e c - 0 0 MW - 1 7 D 1 7 - A p r - 0 1 MW - 1 7 D 2 9 - N o v - 0 1 MW - 1 7 D 3 - A p r - 0 2 MW - 1 7 D 6 - N o v - 0 2 0.539 MW - 1 7 D 1 5 - A p r - 0 3 MW - 1 7 D 2 9 - O c t - 0 3 MW - 1 7 D 8 - A p r - 0 4 MW - 1 7 D 1 8 - N o v - 0 4 MW - 1 7 D 2 1 - A p r - 0 5 0.0 0 2 MW - 1 7 D 1 1 - N o v - 0 5 MW - 1 7 D 1 3 - A p r - 0 6 MW - 1 7 D 8 - N o v - 0 6 MW - 1 7 D 2 0 - A p r - 0 7 0. 0 2 1 MW - 1 7 D 7 - N o v - 0 7 MW - 1 7 D 1 3 - M a y - 0 8 0 . 0 3 8 2 J 0 . 0 0 3 4 5 J 0 . 0 0 4 4 6 J 0 . 0 0 8 5 3 J 0.0 0 1 3 J 0.0063J MW - 1 7 D 5 - N o v - 0 8 0 . 0 4 3 8 J 0 . 0 0 1 6 1 0 . 0 0 5 5 7 J 0 . 0 0 2 1 6 J 0.0 0 1 3 2 J B MW - 1 7 D 1 7 - M a r - 0 9 0 . 0 1 3 0 J 0 . 0 0 0 5 3 0 J 0.0 0 6 4 0 J 0.0 0 1 6 8 J B 0.0115JB 0.0177 MW - 1 7 D ( d u p ) 1 7 - M a r - 0 9 0 . 0 1 1 5 J 0 . 0 0 0 4 0 J 0.0 0 1 7 8 J B 0.00884JB 0.00717J MW - 1 7 D 2 0 - O c t - 0 9 0 . 0 0 0 5 6 J 0 . 0 3 8 3 J B 0 . 0 0 0 2 9 J 0 . 0 0 5 1 J B 0 . 0 1 2 5 B 0.00662J 0.0121B MW - 1 7 D 6 - M a y - 1 0 0. 0 0 2 1 7 J 0. 0 3 1 3 J 0 . 0 0 0 9 4 6 J 0 . 0 0 2 2 5 J 0 . 0 0 3 6 9 J 0.00495J 0.0175 MW - 1 7 D ( d u p ) 6 - M a y - 1 0 0. 0 0 1 8 8 J 0. 0 3 2 J 0 . 0 0 0 8 2 5 J 0 . 0 0 2 5 1 J 0 . 0 0 3 5 7 J 0.00452J 0.0118 MW - 1 7 D 2 8 - O c t - 1 0 0. 0 0 1 0 5 J 0. 0 3 5 J 0 . 0 0 0 7 5 3 J 0 . 0 0 2 2 2 J 0 . 0 6 5 7 0.000431J 0 . 0 0 4 8 3 J 0.00818J MW - 1 7 D 1 4 - M a r - 1 1 0 . 0 0 0 8 7 1 J 0 . 0 3 8 1 J 0 . 0 0 1 1 8 0 . 0 0 1 9 3 J 0 . 0 1 9 6 0.00452J 0.00717J MW - 1 7 D 1 9 - O c t - 1 1 0 . 0 0 0 6 9 2 J 0 . 0 4 0 8 J 0 . 0 0 0 7 7 3 J 0 . 0 0 2 1 9 J 0 . 0 0 6 3 3 J 0.0042J 0.00787J MW - 1 7 D ( d u p ) 1 9 - O c t - 1 1 0 . 0 0 0 7 7 3 J 0 . 0 4 0 5 J 0 . 0 0 0 8 4 6 J 0 . 0 0 2 1 4 J 0 . 0 0 6 5 4 J 0.00439J 0.00819J MW - 1 7 D 1 0 - A p r - 1 2 0 . 0 0 0 6 6 9 J 0 . 0 0 3 5 1 J B 0 . 0 4 5 5 J 0 . 0 0 0 6 0 9 J 0 . 0 0 2 2 8 J 0 . 0 1 4 0 . 0 0 3 0 4 J 0.00423J 0.00644J MW - 1 7 D 2 5 - O c t - 1 2 0 . 0 4 6 6 J 0 . 0 0 0 4 6 5 J 0 . 0 0 2 7 3 J 0 . 0 0 1 9 8 J 0.00436J 0.00568J MW - 1 7 D 1 0 - A p r - 1 3 0.0 0 3 1 J 0. 0 4 0 J 0 . 0 0 0 6 J 0 . 0 0 2 J 0 . 0 0 0 3 J B 0 . 0 0 4 J 0 . 0 0 0 5 J 0 . 0 0 1 J 0.008J MW - 1 7 D 1 - O c t - 1 3 0.0 0 1 7 J 0. 0 4 0 J 0 . 0 0 0 1 J B 0 . 0 0 0 2 J 0 . 0 0 2 J 0 . 0 0 0 3 J B 0 . 0 0 4 J 0 . 0 0 0 8 J 0 . 0 0 1 J 0.003J 0.004JB MW - 1 7 D 4 - A p r - 1 4 0.0 0 0 3 J 0. 0 5 0 J 0 . 0 0 0 1 J 0 . 0 0 2 J 0 . 0 0 0 5 J 0 . 0 1 1 0 . 0 0 2 J 0 . 0 0 1 J 0.007J 0.009JB MW - 1 7 D 1 3 - N o v - 1 4 0 . 0 0 0 5 J 0 . 0 0 6 0 J 0 . 0 0 0 2 J 0 . 0 0 0 1 J 0 . 0 0 3 J 0 . 0 0 0 7 J 0 . 0 0 2 J 0 . 0 0 4 J 0 . 0 0 2 J 0.005J 0.007J MW - 1 7 D 9 - A p r - 1 5 0 . 0 0 0 4 J B 0 . 0 0 0 5 J 0 . 0 4 0 J 0 . 0 0 1 0 J 0 . 0 0 2 J 0 . 0 0 0 2 J 0 . 0 0 7 J 0 . 0 0 0 5 J 0 . 0 0 0 9 J 0.004JB MW - 1 7 D 8 - O c t - 1 5 0 . 0 0 0 4 J 0 . 0 4 0 J 0 . 0 0 0 1 J 0 . 0 0 3 J 0 . 0 0 0 1 J 0 . 0 0 2 J 0 . 0 0 0 3 J 0 . 0 0 2 J 0.006J MW - 1 7 D ( d u p ) 8 - O c t - 1 5 0 . 0 0 0 5 J 0 . 0 4 0 J 0 . 0 0 0 2 J 0 . 0 0 3 J 0 . 0 0 0 1 J 0 . 0 0 2 J 0 . 0 0 0 3 J 0 . 0 0 3 J 0.007J MW - 1 7 D 2 5 - M a r - 1 6 0 . 0 0 0 3 J 0 . 0 3 9 J 0 . 0 0 2 5 J 0 . 0 0 0 1 J 0 . 0 0 1 7 J 0 . 0 0 0 3 8 J 0 . 0 0 1 3 J 0.0044J MW - 1 7 D 1 - S e p - 1 6 0 . 0 0 0 3 9 J 0 . 0 3 4 J 0 . 0 0 0 0 8 4 J 0 . 0 0 1 5 J 0 . 0 0 1 9 B J 0 . 0 0 0 3 1 J 0 . 0 0 1 1 J 0.0042J 0.0079J MW - 1 7 D ( d i s s o l v e d ) 1 - S e p - 1 6 0 . 0 0 0 4 7 J 0 . 0 1 5 J 0 . 0 0 0 1 5 J 0 . 0 0 0 8 5 J 0 . 0 0 1 7 B J 0 . 0 0 1 4 J 0.0036J 0.012 MW - 1 7 D ( d u p ) 1 - S e p - 1 6 0 . 0 0 0 4 6 J 0 . 0 3 6 J 0 . 0 0 0 0 5 6 J 0 . 0 0 1 8 J 0 . 0 0 1 7 J 0 . 0 0 0 3 7 J 0 . 0 0 0 9 3 J 0.0043J 0.0077J MW - 1 7 D ( d u p , d i s s o l v e d ) 1 - S e p - 1 6 0 . 0 0 0 5 2 J 0 . 0 1 4 J 0 . 0 0 0 1 5 J 0 . 0 0 1 J 0 . 0 0 1 7 J 0 . 0 0 0 9 1 J 0.0038J 0.0071J Pa g e 1 1 o f 1 8 October 2016 Ap p e n d i x A De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s Al t e r n a t e S o u r c e D e m o n s t r a t i o n No r t h W a k e L i n e d L a n d f i l l Pe r m i t N o . 9 2 0 9 M o n i t o r i n g W e l l C o d e S a m p l e D a t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r L e a d M e r c u r y N i c k e l S e l e n i u m S i l v e r Thallium VanadiumZinc 0. 0 0 1 * 0 . 0 1 0 . 7 0 . 0 0 4 * 0 . 0 0 2 0 . 0 1 0 . 0 0 1 * 1 0 . 0 1 5 0 . 0 0 1 0 . 1 0 . 0 2 0 . 0 2 0 . 0 0 0 2 * 0 . 0 0 0 3 * 1 0. 0 0 6 0 . 0 1 0 0 . 1 0 . 0 0 1 0 . 0 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 0 0 2 0 . 0 5 0 . 0 1 0 . 0 1 0 . 0 0 5 5 0 . 0 2 5 0 . 0 1 So l i d W a s t e S e c t i o n L i m i t No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d MW - 1 8 31 - O c t - 9 5 0. 8 5 7 0.0 0 4 0. 2 7 1 0. 0 9 2 0.0 1 8 0. 2 6 4 0.207 0.428 MW - 1 8 ( d u p ) 3 1 - O c t - 9 5 1. 3 4 7 0 . 0 0 9 0 . 5 0 5 0 . 1 4 5 0 . 0 2 7 0 . 4 5 8 0.307 0.875 MW - 1 8 1 9 - D e c - 9 5 MW - 1 8 2 6 - F e b - 9 6 0. 0 6 7 0 . 0 3 8 0.0 1 2 0.107 0.150 MW - 1 8 2 9 - A p r - 9 6 0.0 0 5 0 . 2 9 9 0 . 1 2 7 0.6 2 0 0.0 2 3 0 . 2 1 8 0.165 0.606 MW - 1 8 2 7 - N o v - 9 6 0 . 0 1 8 MW - 1 8 2 4 - A p r - 9 7 0.0 0 1 0. 0 4 5 0. 0 6 6 0.11 0.26 MW - 1 8 3 1 - O c t - 9 7 0. 0 6 4 0 . 0 2 6 0.062 0.11 MW - 1 8 7 - M a y - 9 8 0. 0 1 4 MW - 1 8 2 3 - N o v - 9 8 0.0 0 1 2 0. 0 1 3 MW - 1 8 1 4 - A p r - 9 9 0. 0 0 1 8 MW - 1 8 1 - D e c - 9 9 0. 0 1 2 3 MW - 1 8 6 - A p r - 0 0 MW - 1 8 1 8 - D e c - 0 0 MW - 1 8 1 7 - A p r - 0 1 MW - 1 8 2 9 - N o v - 0 1 0. 0 2 3 1 0 . 0 1 6 5 0.0676 MW - 1 8 5 - A p r - 0 2 MW - 1 8 6 - N o v - 0 2 0. 0 1 4 6 0 . 0 1 0 6 MW - 1 8 1 5 - A p r - 0 3 0.0 0 1 0 0. 0 2 3 5 0 . 0 1 3 3 MW - 1 8 2 9 - O c t - 0 3 0. 0 2 7 5 0 . 0 1 3 4 MW - 1 8 8 - A p r - 0 4 0. 0 2 5 1 0 . 0 1 1 9 MW - 1 8 1 8 - N o v - 0 4 MW - 1 8 2 1 - A p r - 0 5 MW - 1 8 1 1 - N o v - 0 5 MW - 1 8 1 3 - A p r - 0 6 0. 0 2 3 0.051 MW - 1 8 8 - N o v - 0 6 0 . 5 9 8 0 . 0 0 3 0. 0 4 7 0 . 0 1 9 0 . 0 1 7 0.056 0.244 MW - 1 8 2 0 - A p r - 0 7 0 . 1 0 6 0.0 2 6 0.025 0.043 MW - 1 8 7 - N o v - 0 7 0 . 2 8 1 0 . 0 0 1 0. 0 3 5 0 . 0 1 3 0.0 4 3 0.044 0.107 MW - 1 8 1 3 - M a y - 0 8 0 . 0 7 2 6 J 0. 0 2 2 0 . 0 0 5 4 4 J 0. 0 2 8 6 0 . 0 1 2 8 0 . 0 0 6 0 8 J 0 . 0 0 9 1 J 0.0178J 0.0223 MW - 1 8 3 - N o v - 0 8 0 . 0 2 0 7 J 0 . 0 0 3 7 6 0 . 0 0 0 1 6 J 0 . 0 0 4 9 8 J 0 . 0 0 5 6 5 J 0. 0 0 1 1 5 J 0.0014J 0.00495J MW - 1 8 1 8 - M a r - 0 9 0 . 0 3 4 3 J 0 . 0 0 0 4 5 J 0. 0 1 1 7 0. 0 2 1 6 B 0.0 0 1 4 3 J B 0.0218JB 0.00942J MW - 1 8 2 1 - O c t - 0 9 0 . 0 4 9 6 J B 0.0 1 6 4 B 0 . 0 0 3 2 1 J 0. 0 2 2 6 B 0 . 0 0 5 0 9 J 0.0138J 0.0132B MW - 1 8 7 - M a y - 1 0 0 . 2 5 3 0 . 0 0 0 6 2 4 J 0. 0 9 0 1 0 . 0 3 6 9 0.1 1 7 0 . 0 0 6 2 7 J 0 . 0 3 8 8 J 0 . 0 0 0 1 2 8 J 0.0814 0.103 MW - 1 8 28 - O c t - 1 0 0. 0 1 4 1 J 0. 0 0 1 9 2 J 0.000356J 0.00329J 0.00527J MW - 1 8 15 - M a r - 1 1 0. 0 3 6 2 J 0. 0 0 9 5 9 J 0. 0 0 3 0 6 J 0. 0 1 0 4 0. 0 0 3 4 9 J 0.00828J 0.01 MW - 1 8 20 - O c t - 1 1 0. 0 9 6 7 J 0. 0 3 2 6 0.0 1 1 6 0. 0 3 7 6 0.0 0 2 3 4 J 0.0 1 4 1 J 0.0282 0.0341 MW - 1 8 11 - A p r - 1 2 0.0 0 0 3 9 9 J 0. 3 5 2 0. 0 0 0 4 5 1 J 0. 1 2 6 0.0 4 8 4 0.1 4 8 0.0 1 3 0. 0 5 8 0. 0 0 3 7 3 J 0.000194J 0.116 0.135 MW - 1 8 26 - O c t - 1 2 0. 0 0 5 7 6 J 0. 3 1 1 0. 0 8 5 5 0.0 3 6 1 0.1 1 4 0.0 0 8 1 8 J 0.0 5 0 7 0.0732 0.134 MW - 1 8 11 - A p r - 1 3 0. 1 2 0 0. 0 0 0 4 J 0. 0 4 0 0. 0 1 5 0.0 4 6 0.0 0 2 J 0. 0 2 0 J 0.0009J 0.033 0.038 MW - 1 8 2- O c t - 1 3 0. 1 4 0 0. 0 0 0 5 J 0. 0 4 3 0. 0 1 5 0.0 5 9 0.0 0 3 J 0. 0 2 1 J 0.0001J 0.037 0.039B MW - 1 8 4- A p r - 1 4 0. 2 4 0 0. 0 0 0 6 J 0.0 0 0 1 J 0. 0 7 0 0. 0 2 6 0.0 8 1 0.0 0 4 J 0. 0 3 5 J 0.0002J 0.067 0.084 MW - 1 8 13 - N o v - 1 4 0. 2 9 0 0. 0 0 0 7 J 0.0 0 0 1 J 0. 0 8 8 0. 0 3 4 0.0 9 9 0.0 0 5 J 0. 0 4 2 J 0.0002J 0.081 0.112 MW - 1 8 9- A p r - 1 5 0. 1 3 0 0. 0 0 0 5 J 0.0 0 0 2 J 0. 0 6 0 0. 0 2 3 0.0 7 4 0.0 0 4 J 0. 0 3 1 J 0.0001J 0.031 0.048 MW - 1 8 8- O c t - 1 5 0. 0 2 0 J 0. 0 0 5 J 0. 0 0 1 J 0.0 0 4 J 0. 0 0 0 2 J 0. 0 0 2 J 0.001J 0.008J MW - 1 8 25 - M a r - 1 6 0. 0 2 4 J 0.0 0 0 0 5 J 0.0 0 8 3 J 0.0 0 2 8 J 0. 0 0 9 0 J 0.0 0 0 4 7 J 0.0 0 4 2 J 0.0101 MW - 1 8 1- S e p - 1 6 0. 0 3 9 J 0.0 0 0 1 3 J 0. 0 1 0.0 0 3 6 J 0.0 1 1 B 0.0 0 0 6 4 J 0.0 0 5 1 J 0.01J 0.013 MW - 1 8 ( d i s s o l v e d ) 1- S e p - 1 6 0. 0 1 4 J 0.0 0 0 2 4 B J 0.0 0 0 8 3 J 0. 0 0 0 9 6 J 0.0022J 0.0025J Pa g e 1 2 o f 1 8 October 2016 Ap p e n d i x A De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s Al t e r n a t e S o u r c e D e m o n s t r a t i o n No r t h W a k e L i n e d L a n d f i l l Pe r m i t N o . 9 2 0 9 M o n i t o r i n g W e l l C o d e S a m p l e D a t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r L e a d M e r c u r y N i c k e l S e l e n i u m S i l v e r Thallium VanadiumZinc 0. 0 0 1 * 0 . 0 1 0 . 7 0 . 0 0 4 * 0 . 0 0 2 0 . 0 1 0 . 0 0 1 * 1 0 . 0 1 5 0 . 0 0 1 0 . 1 0 . 0 2 0 . 0 2 0 . 0 0 0 2 * 0 . 0 0 0 3 * 1 0. 0 0 6 0 . 0 1 0 0 . 1 0 . 0 0 1 0 . 0 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 0 0 2 0 . 0 5 0 . 0 1 0 . 0 1 0 . 0 0 5 5 0 . 0 2 5 0 . 0 1 So l i d W a s t e S e c t i o n L i m i t No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d MW - 1 9 8-M a r - 9 9 0.0 0 3 0. 1 2 4 0.0 2 8 5 0. 0 1 2 4 0. 0 5 6 0.0826 0.0573 MW - 1 9 1 5 - A p r - 9 9 MW - 1 9 2 7 - M a y - 9 9 MW - 1 9 2 0 - J u l - 9 9 MW - 1 9 4 - A u g - 9 9 MW - 1 9 ( d u p ) 4 - A u g - 9 9 MW - 1 9 1 - D e c - 9 9 MW - 1 9 5 - A p r - 0 0 MW - 1 9 1 8 - D e c - 0 0 MW - 1 9 1 8 - A p r - 0 1 MW - 1 9 2 8 - N o v - 0 1 MW - 1 9 4 - A p r - 0 2 MW - 1 9 5 - N o v - 0 2 0. 0 1 7 8 MW - 1 9 1 6 - A p r - 0 3 0. 0 2 9 4 MW - 1 9 3 0 - O c t - 0 3 MW - 1 9 7 - A p r - 0 4 MW - 1 9 1 8 - N o v - 0 4 0. 0 1 8 MW - 1 9 2 1 - A p r - 0 5 MW - 1 9 1 1 - N o v - 0 5 MW - 1 9 1 3 - A p r - 0 6 MW - 1 9 8 - N o v - 0 6 MW - 1 9 2 0 - A p r - 0 7 MW - 1 9 7 - N o v - 0 7 0. 0 1 7 0.0 2 9 0.012 MW - 1 9 1 4 - M a y - 0 8 0 . 0 3 3 J 0. 0 1 0 6 0.0 1 2 0.00437J MW - 1 9 5 - N o v - 0 8 0 . 0 1 2 4 J 0 . 0 0 1 5 4 B 0 . 0 0 0 1 4 J 0 . 0 0 3 8 9 J 0 . 0 0 2 9 4 J 0.0 0 1 5 5 J B MW - 1 9 1 8 - M a r - 0 9 0.0 0 0 2 3 J 0 . 0 0 2 8 5 J 0 . 0 0 5 5 1 J B 0.0 0 1 4 6 J B 0.00773JB MW - 1 9 2 1 - O c t - 0 9 0 . 0 2 J B 0 . 0 0 5 5 7 J B 0 . 0 0 8 6 7 J B 0.00462J 0.00349JB MW - 1 9 7 - M a y - 1 0 0 . 0 2 2 2 J 0 . 0 0 0 4 4 6 J 0 . 0 0 7 8 1 J 0. 0 0 1 3 0 J 0.0 0 7 8 5 J 0 . 0 0 2 4 7 J 0.00474J 0.022 MW - 1 9 1 5 - M a r - 1 1 0 . 0 1 5 5 J 0 . 0 0 2 9 1 J 0 . 0 0 1 6 8 J 0 . 0 0 1 9 5 J 0.00269J 0.0191 MW - 1 9 ( d u p ) 1 5 - M a r - 1 1 0 . 0 1 5 1 J 0 . 0 0 2 8 8 J 0.000115J 0.00259J 0.00756 MW - 1 9 2 0 - O c t - 1 1 0 . 0 1 4 5 J 0 . 0 0 2 7 6 J 0.00232J 0.00958J MW - 1 9 1 0 - A p r - 1 2 0 . 0 1 9 8 J 0 . 0 0 6 0 7 J 0 . 0 0 5 6 7 J 0 . 0 0 1 9 4 J 0.00379J MW - 1 9 2 6 - O c t - 1 2 0 . 0 1 5 3 J 0 . 0 0 3 1 8 J 0 . 0 0 2 1 2 J 0.00252J 0.00594J MW - 1 9 1 1 - A p r - 1 3 0 . 0 2 J 0 . 0 0 0 1 J 0 . 0 0 3 J 0 . 0 0 0 1 J B 0 . 0 0 2 J 0 . 0 0 1 J 0.003J MW - 1 9 2 - O c t - 1 3 0 . 0 2 0 J B 0 . 0 0 0 0 8 J B 0 . 0 0 2 J 0 . 0 0 0 1 J B 0 . 0 0 2 J 0 . 0 0 1 J 0.003JB MW - 1 9 4 - A p r - 1 4 0 . 0 2 0 J 0 . 0 0 0 2 J 0 . 0 0 4 J 0 . 0 0 0 4 J 0 . 0 0 3 J 0 . 0 0 2 J 0.004J 0.007JB MW - 1 9 ( d u p ) 4 - A p r - 1 4 0 . 0 2 0 J 0 . 0 0 0 1 J 0 . 0 0 4 J 0 . 0 0 0 6 J 0 . 0 0 4 J 0 . 0 0 2 J 0.004J 0.006JB MW - 1 9 1 3 - N o v - 1 4 0 . 0 1 0 J 0 . 0 0 3 J 0 . 0 0 0 2 J 0 . 0 0 1 J 0 . 0 0 1 J 0.004J MW - 1 9 8 - A p r - 1 5 0 . 0 1 0 J 0 . 0 0 0 2 J 0 . 0 0 3 J 0 . 0 0 0 1 J 0 . 0 0 2 J 0 . 0 0 1 J 0.005JB MW - 1 9 7 - O c t - 1 5 0 . 0 2 0 J 0 . 0 0 4 J 0 . 0 0 0 2 J 0 . 0 0 3 J 0 . 0 0 1 J 0.003J MW - 1 9 2 5 - M a r - 1 6 0 . 0 2 1 J 0 . 0 0 0 3 1 J 0 . 0 0 5 2 J 0 . 0 0 0 3 J B 0 . 0 0 5 1 J 0 . 0 0 0 2 7 J 0 . 0 0 1 7 J 0.0034J MW - 1 9 1- S e p - 1 6 0. 0 0 0 3 7 J 0. 0 1 3 J 0.0 0 0 1 4 J 0.0 0 2 9 J 0. 0 0 1 1 J 0.0 0 1 3 J 0.003J 0.0058J MW - 1 9 ( d i s s o l v e d ) 1 - S e p - 1 6 0. 0 0 0 1 8 J 0. 0 1 3 J 0.0 0 0 1 1 J 0.0 0 2 7 J 0.0 0 0 4 7 J 0.0 0 1 6 J 0.0028J 0.0049J Pa g e 1 3 o f 1 8 October 2016 Ap p e n d i x A De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s Al t e r n a t e S o u r c e D e m o n s t r a t i o n No r t h W a k e L i n e d L a n d f i l l Pe r m i t N o . 9 2 0 9 M o n i t o r i n g W e l l C o d e S a m p l e D a t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r L e a d M e r c u r y N i c k e l S e l e n i u m S i l v e r Thallium VanadiumZinc 0. 0 0 1 * 0 . 0 1 0 . 7 0 . 0 0 4 * 0 . 0 0 2 0 . 0 1 0 . 0 0 1 * 1 0 . 0 1 5 0 . 0 0 1 0 . 1 0 . 0 2 0 . 0 2 0 . 0 0 0 2 * 0 . 0 0 0 3 * 1 0. 0 0 6 0 . 0 1 0 0 . 1 0 . 0 0 1 0 . 0 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 0 0 2 0 . 0 5 0 . 0 1 0 . 0 1 0 . 0 0 5 5 0 . 0 2 5 0 . 0 1 So l i d W a s t e S e c t i o n L i m i t No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d MW - 2 0 15 - A p r - 9 9 0.0 0 0 1 2 0. 0 1 1 8 0. 0 3 6 0.098 MW - 2 0 2 7 - M a y - 9 9 MW - 2 0 ( d u p ) 2 7 - M a y - 9 9 MW - 2 0 2 0 - J u l - 9 9 MW - 2 0 4 - A u g - 9 9 MW - 2 0 1 - D e c - 9 9 MW - 2 0 5 - A p r - 0 0 MW - 2 0 1 8 - D e c - 0 0 MW - 2 0 1 8 - A p r - 0 1 MW - 2 0 2 7 - N o v - 0 1 0 . 1 7 9 0.0 2 7 9 0.1 2 2 0.0827 MW - 2 0 4 - A p r - 0 2 0. 0 1 1 MW - 2 0 6 - N o v - 0 2 MW - 2 0 1 6 - A p r - 0 3 0.0 0 1 3 0. 0 1 0 1 0 . 0 1 9 1 0.0601 MW - 2 0 3 0 - O c t - 0 3 MW - 2 0 7 - A p r - 0 4 MW - 2 0 1 8 - N o v - 0 4 0.0 1 MW - 2 0 2 1 - A p r - 0 5 MW - 2 0 1 1 - N o v - 0 5 MW - 2 0 1 3 - A p r - 0 6 MW - 2 0 8 - N o v - 0 6 MW - 2 0 2 0 - A p r - 0 7 0.0 1 9 0.015 MW - 2 0 7 - N o v - 0 7 0 . 1 4 7 0. 0 1 2 0.0 7 5 0.0 1 9 0.029 0.079 MW - 2 0 1 4 - M a y - 0 8 0 . 0 0 2 3 1 J 0 . 0 3 6 4 J 0 . 0 0 4 7 4 J 0 . 0 2 7 2 0 . 0 1 1 3 0.0107J 0.0126 MW - 2 0 5 - N o v - 0 8 0 . 0 2 5 8 J 0 . 0 0 0 6 3 J 0 . 0 0 0 1 4 J 0 . 0 0 3 1 7 J 0 . 0 1 7 6 0. 0 0 1 0 5 J 0.00654J 0.00757J MW - 2 0 1 8 - M a r - 0 9 0 . 0 2 7 4 J 0 . 0 0 2 8 4 J 0 . 0 3 7 3 B 0 . 0 0 4 9 1 J 0 . 0 0 1 2 6 J B 0.0115 0 . 0 2 9 0 B 0.011 MW - 2 0 2 1 - O c t - 0 9 0 . 0 2 9 3 J B 0 . 0 0 5 0 9 J B 0 . 0 1 4 5 B 0 . 0 0 7 8 8 J 0.0122J 0.00577JB MW - 2 0 7 - M a y - 1 0 0 . 1 6 5 0 . 0 0 0 6 5 6 J 0. 0 1 7 2 0 . 0 2 7 8 0. 1 9 0 . 0 1 2 2 0 . 0 2 5 9 J 0 . 0 0 0 1 2 9 J 0.0538 0.0925 MW - 2 0 2 9 - O c t - 1 0 0 . 0 1 8 4 J 0 . 0 0 1 6 5 J 0 . 0 0 8 1 J 0 . 0 0 2 1 8 J 0.0002J 0 . 0 0 9 8 1 J 0.00687J MW - 2 0 1 5 - M a r - 1 1 0 . 0 2 2 9 J 0 . 0 0 1 5 2 J 0 . 0 0 6 9 8 J 0 . 0 0 2 7 3 J 0.00998J 0.0101 MW - 2 0 2 0 - O c t - 1 1 0 . 0 3 1 1 J 0 . 0 0 2 8 2 J 0. 0 0 2 6 4 J 0. 0 1 6 7 0 . 0 0 3 4 J 0.0126J 0.0158 MW - 2 0 1 1 - A p r - 1 2 0 . 1 0 5 0. 0 1 0 3 0 . 0 1 5 7 0.1 0 7 0 . 0 0 8 3 1 J 0 . 0 1 7 1 J 0.0341 0.066 MW - 2 0 ( d u p ) 1 1 - A p r - 1 2 0 . 0 4 4 J 0 . 0 0 3 6 8 J 0. 0 0 4 5 8 J 0. 0 2 7 6 0 . 0 0 4 9 5 J 0 . 0 0 5 0 6 J 0.0154J 0.0198 MW - 2 0 2 6 - O c t - 1 2 0 . 0 0 3 1 4 J 0 . 1 2 0. 0 1 3 8 0 . 0 1 7 5 0.1 2 0 0 . 0 1 1 7 0 . 0 2 3 J 0.0426 0.0746 MW - 2 0 1 1 - A p r - 1 3 0 . 1 3 0 . 0 0 0 4 J 0. 0 1 2 0 . 0 1 9 0.1 2 9 0 . 0 0 9 J 0 . 0 2 3 J 0.0002J 0 . 0 4 2 0.064 MW - 2 0 2 - O c t - 1 3 0 . 3 1 0 0 . 0 0 0 9 J 0 . 0 0 0 1 J 0. 0 2 6 0 . 0 3 2 0.3 2 9 0.0 2 6 0. 0 4 1 J 0.0003J 0 . 1 1 0 0.168 MW - 2 0 4 - A p r - 1 4 0 . 0 8 0 J 0 . 0 0 0 2 J 0. 0 0 7 J 0 . 0 1 0 J 0.0 6 8 0.0 0 5 J 0. 0 1 3 J 0.00008J 0 . 0 3 4 0.041B MW - 2 0 1 2 - N o v - 1 4 0 . 2 1 0 0 . 0 0 0 5 J 0. 0 2 5 0 . 0 3 2 0.2 1 7 0.0 1 9 0. 0 3 6 J 0.0003J 0 . 0 7 4 0.120 MW - 2 0 8 - A p r - 1 5 0 . 1 1 0 0 . 0 0 0 3 J 0 . 0 0 0 1 J 0 . 0 0 9 J 0. 0 1 3 0.0 9 3 0 . 0 0 7 J 0 . 0 1 5 J 0 . 0 0 0 1 J 0.039 0.062 MW - 2 0 ( d u p ) 8 - A p r - 1 5 0 . 1 2 0 0 . 0 0 0 3 J 0 . 0 0 0 1 J 0. 0 1 3 0 . 0 1 7 0.1 3 1 0 . 0 0 9 J 0 . 0 2 1 J 0 . 0 0 0 1 J 0.041 0.067 MW - 2 0 8 - O c t - 1 5 0 . 0 4 0 J 0 . 0 0 0 0 5 J 0 . 0 0 4 J 0. 0 0 4 J 0.0 2 7 0 . 0 0 2 J 0 . 0 0 6 J 0.007J 0.017 MW - 2 0 2 5 - M a r - 1 6 0 . 3 6 7 0 . 0 0 0 8 2 J 0 . 0 0 0 1 8 J 0. 0 2 7 4 0 . 0 3 8 1 0. 0 2 8 3 0. 0 2 3 1 0.0 4 4 7 J 0.00032J 0 . 1 2 7 0.142 MW - 2 0 1 - S e p - 1 6 0 . 0 0 0 1 8 J 0 . 1 3 0 . 0 0 0 3 3 J 0 . 0 0 0 0 7 8 J 0. 0 1 4 0 . 0 1 8 0. 1 3 0 . 0 0 9 7 J 0 . 0 2 J 0 . 0 0 0 1 6 J 0.041 0.068 MW - 2 0 ( d i s s o l v e d ) 1 - S e p - 1 6 0 . 0 0 0 2 6 J 0 . 0 1 5 J 0 . 0 0 0 0 6 1 J 0 . 0 0 1 7 J 0 . 0 0 0 5 8 J 0 . 0 0 1 1 J 0.0073J 0.0032J Pa g e 1 4 o f 1 8 October 2016 Ap p e n d i x A De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s Al t e r n a t e S o u r c e D e m o n s t r a t i o n No r t h W a k e L i n e d L a n d f i l l Pe r m i t N o . 9 2 0 9 M o n i t o r i n g W e l l C o d e S a m p l e D a t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r L e a d M e r c u r y N i c k e l S e l e n i u m S i l v e r Thallium VanadiumZinc 0. 0 0 1 * 0 . 0 1 0 . 7 0 . 0 0 4 * 0 . 0 0 2 0 . 0 1 0 . 0 0 1 * 1 0 . 0 1 5 0 . 0 0 1 0 . 1 0 . 0 2 0 . 0 2 0 . 0 0 0 2 * 0 . 0 0 0 3 * 1 0. 0 0 6 0 . 0 1 0 0 . 1 0 . 0 0 1 0 . 0 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 0 0 2 0 . 0 5 0 . 0 1 0 . 0 1 0 . 0 0 5 5 0 . 0 2 5 0 . 0 1 So l i d W a s t e S e c t i o n L i m i t No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d MW - 2 1 15 - A p r - 9 9 0.0 0 4 0.0 6 3 2 0.3 6 2 0. 0 1 4 7 0.0 5 2 7 0.0565 0.347 MW - 2 1 2 7 - M a y - 9 9 MW - 2 1 2 0 - J u l - 9 9 MW - 2 1 4 - A u g - 9 9 MW - 2 1 3 0 - N o v - 9 9 MW - 2 1 5 - A p r - 0 0 MW - 2 1 1 8 - D e c - 0 0 MW - 2 1 1 8 - A p r - 0 1 MW - 2 1 2 7 - N o v - 0 1 MW - 2 1 4 - A p r - 0 2 MW - 2 1 5 - N o v - 0 2 MW - 2 1 1 6 - A p r - 0 3 MW - 2 1 3 0 - O c t - 0 3 MW - 2 1 7 - A p r - 0 4 MW - 2 1 1 8 - N o v - 0 4 0. 0 1 6 0.049 MW - 2 1 2 1 - A p r - 0 5 MW - 2 1 1 1 - N o v - 0 5 MW - 2 1 1 3 - A p r - 0 6 MW - 2 1 8 - N o v - 0 6 MW - 2 1 2 0 - A p r - 0 7 MW - 2 1 7 - N o v - 0 7 0.011 MW - 2 1 1 4 - M a y - 0 8 0 . 0 8 5 J 0 . 0 0 4 2 5 J 0 . 0 1 9 2 0 . 0 0 6 4 5 J 0.00538J 0.0109 MW - 2 1 ( d u p ) 1 4 - M a y - 0 8 0 . 0 9 1 4 J 0 . 0 0 4 7 6 J 0 . 0 2 0 5 0 . 0 0 5 4 2 J 0. 0 0 4 4 6 J 0.00692 0 . 0 1 2 J 0.0168 MW - 2 1 5 - N o v - 0 8 0 . 0 0 1 8 5 J 0 . 0 5 8 1 J 0 . 0 0 1 1 2 0 . 0 0 1 9 7 J 0 . 0 0 9 2 8 J 0.0 0 1 2 6 J B 0.00504J MW - 2 1 1 8 - M a r - 0 9 0 . 0 5 8 4 J 0 . 0 0 1 3 6 J 0 . 0 1 7 0 B 0.0 0 1 3 7 J B 0.00816 0 . 0 1 9 5 J B 0.00654J MW - 2 1 2 1 - O c t - 0 9 0 . 0 5 0 8 J 0 . 0 0 5 2 8 J B 0 . 0 1 2 3 B 0.00725J 0.00438JB MW - 2 1 7 - M a y - 1 0 0 . 1 2 4 0 . 0 0 3 2 3 J 0. 0 0 4 6 1 J 0. 0 2 4 9 0.0192J 0.0249 MW - 2 1 2 9 - O c t - 1 0 0 . 0 5 1 1 J 0 . 0 0 1 4 6 J 0 . 0 0 6 2 4 J 0.000148J 0.00693J 0.0177 MW - 2 1 1 5 - M a r - 1 1 0 . 0 4 5 2 J 0 . 0 0 1 6 6 J 0 . 0 0 2 7 3 J 0 . 0 0 2 0 1 J 0.00483J 0.00619J MW - 2 1 2 0 - O c t - 1 1 0 . 0 6 1 6 J 0 . 0 0 2 0 6 J 0. 0 0 1 2 5 J 0.0 0 6 6 4 J 0.00675J 0.0111 MW - 2 1 1 0 - A p r - 1 2 0 . 2 0 8 0 . 0 0 0 1 7 1 J 0 . 0 0 6 4 2 J 0. 0 0 8 0 4 J 0. 0 4 6 9 0 . 0 0 3 4 9 J 0 . 0 0 2 4 6 J 0 . 0 0 0 1 2 2 J 0.0315 0.0353 MW - 2 1 2 6 - O c t - 1 2 0 . 2 0 9 0 . 0 0 7 3 1 J 0. 0 0 7 2 5 J 0. 0 5 6 2 0 . 0 0 4 6 4 J 0 . 0 0 3 4 3 J 0.0357 0.0407 MW - 2 1 1 1 - A p r - 1 3 0 . 1 0 . 0 0 0 2 J 0 . 0 0 0 1 J 0 . 0 0 4 J 0. 0 0 3 J 0.0 1 9 0 . 0 0 1 J 0 . 0 0 2 J 0.011J 0.012 MW - 2 1 2 - O c t - 1 3 0 . 1 1 0 0 . 0 0 0 3 J B 0 . 0 0 0 2 J 0 . 0 0 3 J 0. 0 0 3 J 0.0 2 2 0 . 0 0 1 J 0 . 0 0 2 J 0 . 0 0 0 0 5 J 0.015J 0.012B MW - 2 1 ( d u p ) 2 - O c t - 1 3 0 . 1 3 0 0 . 0 0 0 3 J B 0 . 0 0 4 J 0. 0 0 4 J 0.0 2 9 0 . 0 0 1 J 0 . 0 0 2 J 0 . 0 0 0 0 7 J 0.018J 0.015B MW - 2 1 4 - A p r - 1 4 0 . 0 9 0 J 0 . 0 0 0 1 J 0 . 0 0 3 J 0. 0 0 2 J 0.0 1 4 0 . 0 0 0 8 J 0 . 0 0 2 J 0.012J 0.013B MW - 2 1 1 2 - N o v - 1 4 0 . 1 3 0 0 . 0 0 0 2 J 0 . 0 0 5 J 0. 0 0 4 J 0.0 2 5 0 . 0 0 1 J 0 . 0 0 2 J 0 . 0 0 0 0 6 J 0.017J 0.019 MW - 2 1 8 - A p r - 1 5 0 . 1 1 0 0 . 0 0 0 2 J 0 . 0 0 0 1 J 0 . 0 0 9 J 0. 0 0 3 J 0.0 1 7 0 . 0 0 1 J 0 . 0 0 2 J 0 . 0 0 0 0 6 J 0.015J 0.019B MW - 2 1 8 - O c t - 1 5 0 . 2 8 0 0 . 0 0 0 5 J 0 . 0 0 7 J 0. 0 1 0 0.0 5 5 0 . 0 0 3 J 0 . 0 0 4 J 0 . 0 0 0 1 J 0.019J 0.039 MW - 2 1 2 5 - M a r - 1 6 0 . 0 7 6 J 0 . 0 0 0 0 5 J 0 . 0 0 2 8 J 0.0 0 1 4 J 0. 0 0 7 2 J 0 . 0 0 0 4 7 J 0 . 0 0 0 7 J 0.006J 0.0075J MW - 2 1 1- S e p - 1 6 0.0 0 0 2 J 0.3 1 0. 0 0 0 6 J 0.0 0 0 1 1 J 0.0 0 7 2 J 0. 0 1 2 0.0 6 8 0. 0 0 3 8 J 0.0 0 4 7 J 0.00022J 0.045 0.058 MW - 2 1 ( d i s s o l v e d ) 1 - S e p - 1 6 0. 0 3 4 J 0.0 0 1 2 J 0.0 0 0 2 8 J 0.0 0 2 4 J 0.0035J 0.0046J Pa g e 1 5 o f 1 8 October 2016 Ap p e n d i x A De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s Al t e r n a t e S o u r c e D e m o n s t r a t i o n No r t h W a k e L i n e d L a n d f i l l Pe r m i t N o . 9 2 0 9 M o n i t o r i n g W e l l C o d e S a m p l e D a t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r L e a d M e r c u r y N i c k e l S e l e n i u m S i l v e r Thallium VanadiumZinc 0. 0 0 1 * 0 . 0 1 0 . 7 0 . 0 0 4 * 0 . 0 0 2 0 . 0 1 0 . 0 0 1 * 1 0 . 0 1 5 0 . 0 0 1 0 . 1 0 . 0 2 0 . 0 2 0 . 0 0 0 2 * 0 . 0 0 0 3 * 1 0. 0 0 6 0 . 0 1 0 0 . 1 0 . 0 0 1 0 . 0 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 0 0 2 0 . 0 5 0 . 0 1 0 . 0 1 0 . 0 0 5 5 0 . 0 2 5 0 . 0 1 So l i d W a s t e S e c t i o n L i m i t No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d MW - 2 5 15 - A p r - 9 9 MW - 2 5 2 7 - M a y - 9 9 MW - 2 5 2 0 - J u l - 9 9 MW - 2 5 ( d u p ) 2 0 - J u l - 9 9 MW - 2 5 4 - A u g - 9 9 MW - 2 5 1 - D e c - 9 9 MW - 2 5 5 - A p r - 0 0 MW - 2 5 1 8 - D e c - 0 0 0.0 0 1 1 MW - 2 5 1 8 - A p r - 0 1 MW - 2 5 2 7 - N o v - 0 1 MW - 2 5 4 - A p r - 0 2 MW - 2 5 5 - N o v - 0 2 MW - 2 5 1 6 - A p r - 0 3 MW - 2 5 3 0 - O c t - 0 3 MW - 2 5 7 - A p r - 0 4 MW - 2 5 1 8 - N o v - 0 4 MW - 2 5 2 1 - A p r - 0 5 MW - 2 5 1 1 - N o v - 0 5 MW - 2 5 1 3 - A p r - 0 6 MW - 2 5 8 - N o v - 0 6 MW - 2 5 2 0 - A p r - 0 7 0.01 MW - 2 5 7 - N o v - 0 7 0 . 1 2 6 0. 0 1 5 0.028 MW - 2 5 1 4 - M a y - 0 8 0 . 0 5 2 8 J 0 . 0 0 4 4 1 J 0 . 0 0 4 7 2 J 0 . 0 0 3 9 7 J MW - 2 5 5 - N o v - 0 8 0 . 0 7 0 4 J 0 . 0 0 7 0 2 J 0 . 0 0 4 0 3 J 0.0 0 1 4 8 J B 0.00516J MW - 2 5 1 7 - M a r - 0 9 0 . 0 4 2 1 J 0 . 0 0 1 1 5 0 . 0 0 0 1 7 J 0.0 0 4 5 7 J 0.0 0 1 7 7 J B 0.00813JB MW - 2 5 2 1 - O c t - 0 9 0 . 0 5 5 5 J B 0 . 0 0 3 5 1 J B 0 . 0 0 7 7 6 J B 0.00151J 0.00288JB MW - 2 5 6 - M a y - 1 0 0 . 1 1 8 0. 0 1 5 4 0 . 0 0 5 2 7 J 0.0 0 6 3 7 J 0 . 0 0 2 9 3 J 0 . 0 0 7 2 4 J 0.0150J 0.0213 MW - 2 5 2 8 - O c t - 1 0 0 . 0 9 0 5 J 0 . 0 0 6 7 8 J 0. 0 0 2 1 2 J 0.0 0 2 8 9 J 0 . 0 0 3 8 5 J 0.000262J 0 . 0 0 5 6 5 J 0.0136 MW - 2 5 1 4 - M a r - 1 1 0 . 0 7 8 2 J 0 . 0 0 2 5 3 J 0. 0 0 1 8 7 J 0.0 0 2 3 7 J 0 . 0 0 4 9 7 J 0.000224J 0 . 0 0 3 4 4 J 0.0062J MW - 2 5 1 9 - O c t - 1 1 0 . 0 9 6 J 0 . 0 0 7 3 4 J 0. 0 0 2 8 2 J 0.0 0 2 1 3 J 0 . 0 0 3 8 4 J 0.00554J 0.0139 MW - 2 5 1 1 - A p r - 1 2 0 . 0 9 1 6 J 0 . 0 0 1 3 4 J 0.00159J 0.00408J MW - 2 5 2 6 - O c t - 1 2 0 . 0 8 0 5 J 0 . 0 0 5 5 3 J 0. 0 0 1 4 1 J 0.0 0 1 9 2 J 0 . 0 0 5 0 3 J 0.00393J 0.0135 MW - 2 5 1 0 - A p r - 1 3 0 . 0 8 0 J 0 . 0 0 0 1 J 0 . 0 0 3 J 0. 0 0 2 J 0.0 0 1 J 0 . 0 0 0 4 J 0 . 0 0 6 J 0.004J MW - 2 5 2 - O c t - 1 3 0 . 0 8 0 J 0 . 0 0 0 1 J B 0 . 0 0 3 J 0. 0 0 3 J 0.0 0 2 J 0 . 0 0 0 3 J 0 . 0 0 3 J 0.004J 0.012B MW - 2 5 4 - A p r - 1 4 0 . 0 7 0 J 0 . 0 0 2 J 0. 0 0 3 J 0. 0 0 1 0 J 0 . 0 0 0 2 J 0 . 0 0 5 J 0.004J 0.009JB MW - 2 5 1 2 - N o v - 1 4 0 . 0 6 0 J 0 . 0 0 0 8 J 0 . 0 0 0 7 J 0 . 0 0 0 3 J 0 . 0 0 4 J 0.003J MW - 2 5 9 - A p r - 1 5 0 . 0 6 0 J 0. 0 0 2 J 0. 0 0 2 J 0.003JB MW - 2 5 7 - O c t - 1 5 0 . 0 8 0 J 0 . 0 0 0 0 6 J 0 . 0 0 4 J 0. 0 0 2 J 0.0 0 1 J 0 . 0 0 0 3 J 0 . 0 0 6 J 0.006J MW - 2 5 2 5 - M a r - 1 6 0 . 0 7 1 J 0 . 0 0 1 0 J B 0.0 0 2 2 J 0. 0 0 0 4 J 0 . 0 0 3 1 J 0.0041J MW - 2 5 1- S e p - 1 6 0. 0 0 0 3 2 J 0. 0 8 7 J 0.0 0 0 1 6 J 0.0 0 0 0 8 9 J 0.0 0 5 1 J 0.0 0 3 4 J 0. 0 0 2 3 J 0.0 0 0 6 4 J 0.0 0 3 2 J 0.0054J 0.011 MW - 2 5 ( d i s s o l v e d ) 1 - S e p - 1 6 0. 0 5 7 J 0. 0 0 0 6 9 J 0.0 0 0 3 1 J 0.0 0 2 8 J 0.001J 0.0043J Pa g e 1 6 o f 1 8 October 2016 Ap p e n d i x A De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s Al t e r n a t e S o u r c e D e m o n s t r a t i o n No r t h W a k e L i n e d L a n d f i l l Pe r m i t N o . 9 2 0 9 M o n i t o r i n g W e l l C o d e S a m p l e D a t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r L e a d M e r c u r y N i c k e l S e l e n i u m S i l v e r Thallium VanadiumZinc 0. 0 0 1 * 0 . 0 1 0 . 7 0 . 0 0 4 * 0 . 0 0 2 0 . 0 1 0 . 0 0 1 * 1 0 . 0 1 5 0 . 0 0 1 0 . 1 0 . 0 2 0 . 0 2 0 . 0 0 0 2 * 0 . 0 0 0 3 * 1 0. 0 0 6 0 . 0 1 0 0 . 1 0 . 0 0 1 0 . 0 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 0 0 2 0 . 0 5 0 . 0 1 0 . 0 1 0 . 0 0 5 5 0 . 0 2 5 0 . 0 1 So l i d W a s t e S e c t i o n L i m i t No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d MW - 2 5 D 15 - A p r - 9 9 MW - 2 5 D 2 7 - M a y - 9 9 MW - 2 5 D 2 0 - J u l - 9 9 MW - 2 5 D 4 - A u g - 9 9 MW - 2 5 D 1 - D e c - 9 9 MW - 2 5 D 5 - A p r - 0 0 MW - 2 5 D 1 8 - D e c - 0 0 MW - 2 5 D 1 8 - A p r - 0 1 0. 0 0 3 9 MW - 2 5 D 2 7 - N o v - 0 1 0. 0 1 0 9 MW - 2 5 D 4 - A p r - 0 2 MW - 2 5 D 5 - N o v - 0 2 MW - 2 5 D 1 6 - A p r - 0 3 0. 0 0 3 3 0 . 0 1 7 2 0 . 0 2 1 2 MW - 2 5 D 3 0 - O c t - 0 3 MW - 2 5 D 7 - A p r - 0 4 MW - 2 5 D 1 8 - N o v - 0 4 MW - 2 5 D 2 1 - A p r - 0 5 MW - 2 5 D 1 1 - N o v - 0 5 MW - 2 5 D 1 3 - A p r - 0 6 MW - 2 5 D 8 - N o v - 0 6 0. 0 1 MW - 2 5 D 2 0 - A p r - 0 7 MW - 2 5 D 7 - N o v - 0 7 0. 0 1 0.0 2 9 0.029 MW - 2 5 D 1 4 - M a y - 0 8 0 . 0 7 6 6 J 0. 0 1 2 1 0 . 0 0 4 1 8 J 0. 0 3 5 6 0 . 0 0 8 4 4 J 0.013J 0.0204 MW - 2 5 D 5 - N o v - 0 8 0 . 0 6 9 9 J 0 . 0 0 0 6 3 J 0. 0 5 4 0 . 0 0 3 1 5 J 0. 0 1 9 1 0 . 0 0 6 6 8 J 0 . 0 3 0 2 J 0 . 0 0 1 6 7 J B 0.00444J 0.02 MW - 2 5 D 1 7 - M a r - 0 9 0 . 1 7 6 0 . 0 0 1 5 6 0. 0 1 9 2 0 . 0 1 1 7 0. 0 2 6 2 0 . 0 0 3 9 9 J 0 . 0 4 2 3 J 0 . 0 0 2 8 4 J B 0.017JB 0.0555 MW - 2 5 D 2 1 - O c t - 0 9 0 . 0 0 4 9 1 J 0 . 0 4 4 6 J B 0 . 0 0 7 1 6 J B 0 . 0 1 2 1 B 0.00621J 0.00547JB MW - 2 5 D 7 - M a y - 1 0 0 . 1 1 2 0 . 0 0 0 4 3 J 0. 0 1 6 4 0 . 0 1 0 9 0. 0 6 1 3 0 . 0 0 2 9 0 J 0 . 0 1 4 4 J 0.0327 0.0443 MW - 2 5 D 2 8 - O c t - 1 0 0 . 0 0 3 0 1 J 0 . 1 8 7 0. 0 3 3 0 . 0 2 3 9 0.1 4 6 0 . 0 0 5 5 4 J 0 . 0 3 2 6 0.000322J 0 . 0 7 4 6 0.0931 MW - 2 5 D 1 4 - M a r - 1 1 0 . 0 6 2 3 J 0 . 0 0 0 1 0 6 J 0 . 0 0 6 9 3 J 0. 0 0 3 1 5 J 0. 0 1 7 6 0 . 0 0 5 8 7 J 0 . 0 0 0 1 3 4 J 0.0109J 0.0133 MW - 2 5 D 1 9 - O c t - 1 1 0 . 0 7 J 0 . 0 0 8 5 9 J 0. 0 0 5 0 6 J 0. 0 2 2 8 0 . 0 0 7 2 5 J 0.0138J 0.0173 MW - 2 5 D 1 1 - A p r - 1 2 0 . 0 4 8 5 J 0 . 0 0 4 2 7 J 0. 0 0 1 4 4 J 0.0 0 9 0 5 J 0.00575J 0.00449J MW - 2 5 D 2 6 - O c t - 1 2 0 . 0 4 8 5 J 0 . 0 0 5 0 6 J 0. 0 0 1 6 4 J 0.0 0 9 7 4 J 0 . 0 3 0 0 J 0.00711J 0.011 MW - 2 5 D 1 1 - A p r - 1 3 0 . 0 6 J 0 . 0 0 0 1 J 0 . 0 0 6 J 0. 0 0 3 J 0.0 1 5 0 . 0 0 0 6 J 0 . 0 0 5 J 0.007J 0.007J MW - 2 5 D 2 - O c t - 1 3 0 . 0 5 0 J 0 . 0 0 0 1 J B 0 . 0 0 5 J 0. 0 0 2 J 0.0 1 1 0 . 0 0 0 4 J 0 . 0 0 3 J 0.008J 0.004JB MW - 2 5 D 4 - A p r - 1 4 0 . 0 5 0 J 0 . 0 0 0 1 J 0 . 0 0 6 J 0. 0 0 3 J 0.0 1 8 0 . 0 0 0 6 J 0 . 0 0 5 J 0.010J 0.011B MW - 2 5 D 1 2 - N o v - 1 4 0 . 0 0 0 4 J 0 . 0 6 0 J 0 . 0 0 0 1 J 0 . 0 0 7 J 0. 0 0 3 J 0. 0 2 0 . 0 0 0 7 J 0 . 0 0 6 J 0.012J 0.015 MW - 2 5 D 9 - A p r - 1 5 0 . 0 5 0 J 0 . 0 0 0 0 5 J 0 . 0 0 4 J 0. 0 0 2 J 0.0 1 2 0 . 0 0 0 5 J 0 . 0 0 3 J 0.007J 0.007JB MW - 2 5 D 8 - O c t - 1 5 0 . 0 0 0 5 J 0 . 0 6 0 J 0 . 0 0 0 0 9 J 0 . 0 0 0 2 J 0 . 0 0 6 J 0. 0 0 3 J 0.0 2 0 0 . 0 0 0 5 J 0 . 0 0 6 J 0.007J 0.015 MW - 2 5 D 2 4 - M a r - 1 6 0 . 0 5 8 J 0 . 0 0 0 0 6 J 0 . 0 0 0 1 4 J 0 . 0 0 4 2 J 0.0 0 2 1 J 0. 0 1 0 6 0 . 0 0 0 3 7 J 0 . 0 0 4 0 J 0.006J 0.0215 MW - 2 5 D 3 1 - A u g - 1 6 0 . 0 0 0 2 2 J 0 . 0 4 5 J 0 . 0 0 0 1 3 J 0 . 0 0 0 0 9 8 J 0 . 0 0 3 9 J 0.0 0 1 9 J 0. 0 1 0 . 0 0 0 3 7 J 0 . 0 0 3 5 J 0.0076J 0.0097J MW - 2 5 D ( d i s s o l v e d ) 3 1 - A u g - 1 6 0 . 0 3 1 J 0 . 0 0 1 7 J 0 . 0 0 2 1 J 0 . 0 0 1 5 J 0.0038J 0.0093J Pa g e 1 7 o f 1 8 October 2016 Ap p e n d i x A De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s Al t e r n a t e S o u r c e D e m o n s t r a t i o n No r t h W a k e L i n e d L a n d f i l l Pe r m i t N o . 9 2 0 9 M o n i t o r i n g W e l l C o d e S a m p l e D a t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r L e a d M e r c u r y N i c k e l S e l e n i u m S i l v e r Thallium VanadiumZinc 0. 0 0 1 * 0 . 0 1 0 . 7 0 . 0 0 4 * 0 . 0 0 2 0 . 0 1 0 . 0 0 1 * 1 0 . 0 1 5 0 . 0 0 1 0 . 1 0 . 0 2 0 . 0 2 0 . 0 0 0 2 * 0 . 0 0 0 3 * 1 0. 0 0 6 0 . 0 1 0 0 . 1 0 . 0 0 1 0 . 0 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 1 0 . 0 0 0 2 0 . 0 5 0 . 0 1 0 . 0 1 0 . 0 0 5 5 0 . 0 2 5 0 . 0 1 So l i d W a s t e S e c t i o n L i m i t No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d MW - 2 6 27 - M a y - 9 9 0.0 0 1 4 0.0 3 0 6 MW - 2 6 2 0 - J u l - 9 9 0.0 1 0 2 MW - 2 6 4 - A u g - 9 9 0.0 1 MW - 2 6 ( d u p ) 4 - A u g - 9 9 0.0 1 0 2 MW - 2 6 3 0 - N o v - 9 9 MW - 2 6 ( d u p ) 3 0 - N o v - 9 9 MW - 2 6 5 - A p r - 0 0 0.0 0 1 7 0.0 1 4 6 MW - 2 6 1 5 - D e c - 0 0 0.0 0 1 8 0.0 2 MW - 2 6 1 8 - A p r - 0 1 0.0 1 0 9 MW - 2 6 2 7 - N o v - 0 1 0.0 1 2 6 MW - 2 6 4 - A p r - 0 2 0.0 1 1 1 MW - 2 6 5 - N o v - 0 2 0.0 0 1 6 0.0 1 5 2 MW - 2 6 ( d u p ) 5 - N o v - 0 2 0.0 0 1 8 0.0 1 5 4 MW - 2 6 1 6 - A p r - 0 3 0.0 0 1 2 0.0 1 6 5 MW - 2 6 3 0 - O c t - 0 3 0.0 0 1 1 0.0 2 7 8 0.0405 MW - 2 6 7 - A p r - 0 4 0.0 1 1 7 MW - 2 6 1 8 - N o v - 0 4 0. 0 1 1 0 . 0 2 3 MW - 2 6 2 1 - A p r - 0 5 MW - 2 6 1 1 - N o v - 0 5 MW - 2 6 1 3 - A p r - 0 6 MW - 2 6 8 - N o v - 0 6 MW - 2 6 2 0 - A p r - 0 7 0 . 3 8 7 0 . 0 0 1 0.0 0 2 0 . 0 1 6 0 . 0 2 6 0.3 5 6 0.059 0.165 MW - 2 6 7 - N o v - 0 7 0.0 1 2 MW - 2 6 1 4 - M a y - 0 8 0 . 0 6 3 3 J 0. 0 1 0 2 0 . 0 1 2 9 0. 0 5 7 3 0 . 0 1 3 7 0 . 0 1 1 8 J 0 . 0 2 0 3 0.0155J 0.0141 MW - 2 6 5 - N o v - 0 8 0 . 0 1 9 3 J 0.0 0 4 3 2 0. 0 0 1 3 6 J 0.0 0 4 6 J 0.0 0 6 7 9 J 0.0 0 1 2 1 J B MW - 2 6 1 8 - M a r - 0 8 0 . 0 0 7 5 3 J 0. 0 0 7 7 2 J 0.0 0 5 7 1 J B 0.0 0 1 7 5 J B 0.00581JB MW - 2 6 2 1 - O c t - 0 9 0 . 0 2 5 3 J B 0 . 0 0 3 3 2 J B 0. 0 0 7 2 1 J 0.0 0 9 7 6 J B 0 . 0 0 4 5 J 0.00232J 0 . 0 0 1 3 1 J B MW - 2 6 7 - M a y - 1 0 0 . 0 3 9 7 J 0 . 0 0 2 5 8 J 0.0 1 1 4 0. 0 2 4 7 0 . 0 0 7 1 1 J 0.00992J 0.0215 MW - 2 6 2 9 - O c t - 1 0 0 . 0 6 9 5 J 0 . 0 0 7 2 9 J 0.0 1 4 5 0. 0 7 6 7 0 . 0 0 2 2 4 J 0 . 0 1 6 1 J 0.0197J 0.0345 MW - 2 6 ( d u p ) 2 9 - O c t - 1 0 0 . 0 9 6 4 J 0. 0 1 1 6 0 . 0 1 9 7 0.1 1 5 0 . 0 0 2 3 0 J 0 . 0 2 2 3 J 0.000266J 0 . 0 3 0 3 0.0554 MW - 2 6 1 5 - M a r - 1 1 0 . 0 5 3 3 J 0 . 0 0 0 1 1 6 J 0 . 0 0 5 1 9 J 0.0 1 4 5 0. 0 4 6 5 0 . 0 0 5 2 6 J 0 . 0 1 1 3 J 0 . 0 0 0 1 2 3 J 0.013J 0.0176 MW - 2 6 2 0 - O c t - 1 1 0 . 0 6 7 J 0 . 0 0 6 2 1 J 0.0 1 4 8 0. 0 4 3 9 0 . 0 1 2 1 J 0.0152J 0.0295 MW - 2 6 1 1 - A p r - 1 2 0 . 0 4 2 3 J 0 . 0 0 2 8 3 J 0.0 1 1 7 0. 0 2 0 . 0 0 3 9 1 J 0 . 0 0 7 2 3 J 0.00675J 0.00682J MW - 2 6 2 5 - O c t - 1 2 0 . 1 2 3 0 . 0 0 0 6 2 6 J 0. 0 1 4 8 0 . 0 2 4 0.1 1 9 0 . 0 0 1 9 3 J 0 . 0 2 9 3 J 0 . 0 0 2 0 8 J 0.0365 0.0368 MW - 2 6 ( d u p ) 2 5 - O c t - 1 2 0 . 1 5 4 0 . 0 0 0 9 3 3 J 0. 0 2 1 0 . 0 3 0 2 0.1 5 7 0 . 0 0 5 4 5 J 0 . 0 3 9 3 J 0 . 0 0 2 0 8 J 0.0504 0.0555 MW - 2 6 1 1 - A p r - 1 3 0 . 1 1 0 . 0 0 0 3 J 0 . 0 0 0 6 J 0. 0 1 3 0 . 0 2 2 0. 0 9 0 . 0 0 2 J 0 . 0 2 5 J 0 . 0 0 0 0 6 J 0.029 0.026 MW - 2 6 2 - O c t - 1 3 0 . 1 3 0 0 . 0 0 0 5 J 0 . 0 0 0 5 J 0. 0 1 5 0 . 0 2 4 0.1 0 6 0 . 0 0 1 J 0 . 0 3 0 J 0 . 0 0 0 0 7 J 0.039 0.030B MW - 2 6 4 - A p r - 1 4 0 . 0 6 0 J 0 . 0 0 0 1 J 0 . 0 0 0 1 J 0 . 0 0 4 J 0. 0 1 4 0.0 2 8 0 . 0 0 0 5 J 0 . 0 1 1 J 0.014J 0.014B MW - 2 6 1 2 - N o v - 1 4 0 . 0 4 0 J 0 . 0 0 2 J 0. 0 1 1 0.0 1 1 0 . 0 0 7 J 0.002J 0.005J MW - 2 6 8 - A p r - 1 5 0 . 0 3 0 J 0 . 0 0 1 J 0. 0 1 1 0.0 0 6 J 0 . 0 0 6 J 0.003JB MW - 2 6 8 - O c t - 1 5 0 . 0 7 0 J 0 . 0 0 0 1 J 0 . 0 0 0 1 J 0 . 0 0 7 J 0. 0 1 6 0.0 3 3 0 . 0 0 0 5 J 0 . 0 1 5 J 0.008J 0.022 MW - 2 6 2 5 - M a r - 1 6 0 . 0 0 0 9 J 0 . 0 2 5 J 0 . 0 0 0 5 J B 0.0 0 9 1 J 0. 0 0 0 9 J 0 . 0 0 3 4 J MW - 2 6 1 - S e p - 1 6 0 . 0 7 4 J 0 . 0 0 0 1 8 J 0 . 0 0 0 2 1 J 0 . 0 0 6 J 0. 0 1 4 0.0 5 1 0 . 0 0 0 9 5 J 0 . 0 1 3 J 0.018J 0.018 MW - 2 6 ( d i s s o l v e d ) 1 - S e p - 1 6 0 . 0 3 1 J 0.0 0 7 8 J 0. 0 0 0 5 J 0 . 0 0 3 8 J 0 . 0 0 6 3 J No t e s : 1. A l l u n i t s a r e i n m i l l i g r a m s p e r l i t e r ( p a r t s p e r m i l l i o n ) . 2. * - G r o u n d w a t e r P r o t e c t i o n S t a n d a r d 3. d u p - D u p l i c a t e S a m p l e - C o n c e n t r a t i o n e x c e e d s t h e 1 5 A N C A C 0 2 L . 0 2 0 2 o r G r o u n d w a t e r P r o t e c t i o n S t a n d a r d . - I n d i c a t e s t h e r e s u l t i s b e l o w t h e d e t e c t i o n l i m i t . 4. M e r c u r y i s a n A p p e n d i x I I c o n s t i t u e n t t h a t i s o n l y r e p o r t e d f o r b a c k g r o u n d m o n i t o r i n g w e l l s M W - 1 1 a n d - 1 1 D . 5. J - I n d i c a t e s t h e a n a l y t i c a l r e s u l t i s a n e s t i m a t e d c o n c e n t r a t i o n b e t w e e n t h e m e t h o d d e t e c t i o n l i m i t a n d t h e S o l i d W a s t e S e c t i o n R e p o r t i n g L i m i t . 6. B - T h e a n a l y t e c o n c e n t r a t i o n d e t e c t e d i n t h e m e t h o d b l a n k w a s g r e a t e r t h a n t h e m e t h o d d e t e c t i o n l i m i t . Pa g e 1 8 o f 1 8 October 2016 Appendix B Statistical Evaluations Chromium Background MW-12 0.024 0.001 Anova: Single Factor 0.001 0.001 0.011 0.001 SUMMARY 0.001 0.001 Groups Count Sum Average Variance 0.001 0.001 Background 45 0.11827 0.002628 1.74E-05 0.001 0.001 MW-12 45 0.237 0.005267 5.29E-05 0.001 0.012 0.001 0.021 0.001 0.001 ANOVA 0.001 0.001 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 0.000157 1 0.000157 4.451163 0.037717 5.200226 0.001 0.001 Within Groups 0.003097 88 3.52E-05 0.001 0.001 0.001 0.001 Total 0.003253 89 0.001 0.001 NOT SIGNIFICANT 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.019 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.0054 0.0181 0.00273 0.00353 0.00439 0.00265 0.0149 0.0051 0.00145 0.00835 0.0035 0.0342 0.0016 0.0152 0.0019 0.00764 0.001 0.00792 0.001 0.00941 0.002 0.02 0.002 0.006 0.004 0.008 0.002 0.002 0.002 0.003 0.003 0.002 0.0030 0.0057 0.0024 0.0022 Cobalt Background MW-12 0.071 0.001 Anova: Single Factor 0.001 0.001 0.022 0.001 SUMMARY 0.001 0.001 Groups Count Sum Average Variance 0.001 0.001 0.071 44 0.1154 0.002623 2.37E-05 0.001 0.005 0.001 44 0.21063 0.004787 5E-05 0.001 0.001 0.001 0.023 0.001 0.001 ANOVA 0.001 0.001 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 0.000103 1 0.000103 2.79737 0.098053 5.204434 0.001 0.001 Within Groups 0.003168 86 3.68E-05 0.001 0.001 0.001 0.001 Total 0.003271 87 0.001 0.001 NOT SIGNIFICANT 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.018 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.00992 0.001 0.001 0.00651 0.001 0.0254 0.001 0.001 0.00831 0.00547 0.0353 0.001 0.0102 0.001 0.00479 0.001 0.00619 0.00142 0.00562 0.002 0.013 0.001 0.005 0.006 0.009 0.002 0.003 0.003 0.003 0.003 0.003 0.0040 0.0043 0.0026 0.018 Thallium Background MW-12 0.00005 0.00005 Anova: Single Factor 0.00005 0.00005 0.00005 0.00005 SUMMARY 0.00005 0.00005 Groups Count Sum Average Variance 0.00005 0.00005 0.00005 43 0.008035 0.000187 7.23E-07 0.00005 0.00005 0.00005 43 0.00543 0.000126 3.96E-08 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 ANOVA 0.00005 0.00005 Source of Variation SS df MS F P-value F crit 0.00005 0.00005 Between Groups 7.89E-08 1 7.89E-08 0.206843 0.650426 5.208847 0.00005 0.00005 Within Groups 3.2E-05 84 3.81E-07 0.00005 0.00005 0.00005 0.00005 Total 3.21E-05 85 0.00005 0.00005 NOT SIGNIFICANT 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.00563 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.00005 0.000176 0.00005 0.00113 0.000265 0.000389 0.00005 0.000195 0.00005 0.00016 0.00005 0.0005 0.00005 0.0002 0.00005 0.0002 0.00008 0.00008 0.00005 0.00006 0.00006 0.00007 0.00005 0.00015 0.0001 0.00062 Vanadium Background MW-12 0.117 0.001 Anova: Single Factor 0.001 0.001 0.001 0.001 SUMMARY 0.001 0.001 Groups Count Sum Average Variance 0.001 0.001 0.117 44 0.36268 0.008243 0.000319 0.001 0.014 0.001 44 1.12505 0.025569 0.001499 0.001 0.001 0.001 0.12 0.001 0.001 ANOVA 0.001 0.001 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 0.006605 1 0.006605 7.263238 0.008464 5.204434 0.001 0.001 Within Groups 0.078202 86 0.000909 0.001 0.001 0.001 0.001 Total 0.084807 87 0.001 0.001 SIGNIFICANT 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.065 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.05 0.058 0.038 0.0029 0.0578 0.00114 0.00585 0.0203 0.0201 0.099 0.0101 0.00267 0.0396 0.023 0.181 0.00351 0.0824 0.00361 0.0344 0.00323 0.0364 0.00532 0.0474 0.009 0.077 0.005 0.030 0.04 0.059 0.007 0.007 0.012 0.011 0.013 0.004 0.018 0.014 0.011 0.1 Antimony Background MW-12D Anova: Single Factor 0.00010 0.00010 0.00010 0.00010 SUMMARY 0.00010 0.00010 Groups Count Sum Average Variance 0.00010 0.00010 Background 46 0.010169 0.000221065 9.39289E-08 0.00010 0.00010 MW-12D 46 0.00948 0.000206087 8.44955E-08 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 ANOVA 0.00010 0.00010 Source of Variation SS df MS F P-value F crit 0.00010 0.00010 Between Groups 5.16001E-09 1 5.16001E-09 0.057839756 0.81049 5.19621 0.00010 0.00010 Within Groups 8.0291E-06 90 8.92122E-08 0.00010 0.00010 0.00010 0.00010 Total 8.03426E-06 91 0.00010 0.00010 NOT SIGNIFICANT 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00101 0.00010 0.00173 0.00010 0.00085 0.00010 0.00010 0.00010 0.00025 0.0007 0.00010 0.0013 0.00040 0.0005 0.00060 0.00010 0.00010 0.0004 0.00010 0.0015 0.00060 0.0004 0.00040 0.0006 0.00030 0.0003 0.00043 0.00010 Chromium Background MW-12D Anova: Single Factor 0.001 0.001 0.001 0.001 SUMMARY 0.001 0.001 Groups Count Sum Average Variance 0.001 0.001 Background 46 0.09981 0.002169783 6.22613E-06 0.001 0.001 MW-12D 46 0.16484 0.003583478 0.000167827 0.001 0.001 0.001 0.001 0.001 0.001 ANOVA 0.001 0.001 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 4.59663E-05 1 4.59663E-05 0.528187463 0.469256 5.19621 0.001 0.001 Within Groups 0.007832386 90 8.70265E-05 0.001 0.001 0.001 0.001 Total 0.007878353 91 0.001 0.001 NOT SIGNIFICANT 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.00345 0.001 0.001 0.00641 0.001 0.00194 0.00416 0.00714 0.001 0.00541 0.001 0.0051 0.001 0.00356 0.001 0.00343 0.001 0.00218 0.001 0.00304 0.001 0.0024 0.00273 0.002 0.0005 0.001 0.001 0.015 0.001 0.005 0.085 0.002 0.029 0.003 0.001 0.002 0.001 0.0012 0.001 Thallium Background MW-12D Anova: Single Factor 0.0001 0.0001 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 46 0.01148 0.000249565 1.00796E-06 0.0001 0.0001 MW-12D 46 0.01305 0.000283696 1.2665E-06 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 2.67924E-08 1 2.67924E-08 0.023559364 0.878355 5.19621 0.0001 0.0001 Within Groups 0.000102351 90 1.13723E-06 0.0001 0.0001 0.0001 0.0001 Total 0.000102377 91 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.00773 0.00691 0.0001 0.0001 0.0001 0.0001 0.000502 0.0001 0.0001 0.0001 0.000502 0.0001 0.000156 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0002 0.0001 0.00007 0.00006 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 Vanadium Background MW-12D Anova: Single Factor 0.0001 0.0001 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 46 0.21522 0.004678696 0.000243237 0.0001 0.0001 MW-12D 46 0.0479 0.001041304 4.00038E-06 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 0.000304304 1 0.000304304 2.4616322 0.120167 5.19621 0.0001 0.0001 Within Groups 0.011125697 90 0.000123619 0.0001 0.0001 0.0001 0.0001 Total 0.011430001 91 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0101 0.00097 0.00527 0.00409 0.00258 0.0201 0.00253 0.00728 0.00258 0.0055 0.00253 0.00382 0.00201 0.00373 0.00179 0.00245 0.00146 0.00205 0.00245 0.00253 0.0001 0.0001 0.0001 0.002 0.0001 0.099 0.002 0.037 0.007 0.005 0.0001 0.014 0.0001 0.0001 0.0001 0.0027 0.0023 Chromium Background MW-13 Anova: Single Factor 0.024 0.022 0.001 0.001 SUMMARY 0.011 0.001 Groups Count Sum Average Variance 0.001 0.001 Background 45 0.11827 0.002628222 1.74395E-05 0.001 0.001 MW-13 44 0.86938 0.019758636 0.001229487 0.001 0.001 0.001 0.021 0.001 0.059 ANOVA 0.001 0.001 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 0.006528462 1 0.006528462 10.58959838 0.00162 5.202305 0.001 0.001 Within Groups 0.053635295 87 0.000616498 0.001 0.0102 0.001 0.001 Total 0.060163757 88 0.001 0.001 SIGNIFICANT 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.0222 0.001 0.001 0.001 0.086 0.001 0.001 0.001 0.0158 0.001 0.012 0.001 0.017 0.001 0.001 0.001 0.024 0.001 0.00748 0.0054 0.0144 0.00273 0.0111 0.00439 0.0178 0.0149 0.21 0.00145 0.0287 0.0035 0.0147 0.0016 0.0305 0.0019 0.0458 0.001 0.0731 0.001 0.024 0.002 0.014 0.002 0.01 0.004 0.005 0.002 0.007 0.002 0.012 0.003 0.0066 0.0030 0.032 0.0024 Cobalt Background MW-13 Anova: Single Factor 0.071 0.001 0.001 0.001 SUMMARY 0.022 0.001 Groups Count Sum Average Variance 0.001 0.001 Background 45 0.1864 0.004142222 0.000127026 0.001 0.001 MW-13 43 0.25397 0.005906279 0.000183114 0.001 0.001 0.001 0.001 0.001 0.019 ANOVA 0.001 0.001 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 6.84264E-05 1 6.84264E-05 0.443124727 0.5074 5.204434 0.001 0.001 Within Groups 0.013279934 86 0.000154418 0.001 0.001 0.001 0.001 Total 0.01334836 87 0.001 0.001 NOT SIGNIFICANT 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.033 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.0041 0.00651 0.0814 0.0254 0.00924 0.001 0.00388 0.00547 0.00995 0.001 0.0136 0.001 0.0223 0.001 0.007 0.00142 0.004 0.002 0.003 0.001 0.0009 0.006 0.002 0.002 0.003 0.003 0.0016 0.003 0.01 0.0040 0.0026 Thallium Background MW-13 Anova: Single Factor 0.0001 0.0001 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 45 0.010035 0.000223 6.80325E-07 0.0001 0.0001 MW-13 43 0.011897 0.000276674 8.40231E-07 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 6.3348E-08 1 6.3348E-08 0.083526439 0.77327 5.204434 0.0001 0.0001 Within Groups 6.5224E-05 86 7.58419E-07 0.0001 0.0001 0.0001 0.0001 Total 6.52874E-05 87 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.00563 0.0061 0.0001 0.0001 0.0001 0.000707 0.0001 0.000487 0.0001 0.000135 0.0001 0.0001 0.000265 0.000336 0.0001 0.000212 0.0001 0.0002 0.0001 0.0001 0.0001 0.00007 0.0001 0.0001 0.00008 0.0001 0.00005 0.00007 0.00006 0.0001 0.00005 0.00028 0.0001 0.0001 Vanadium Background MW-13 Anova: Single Factor 0.117 0.044 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 45 0.45718 0.010159556 0.000585103 0.0001 0.0001 MW-13 43 1.19899 0.027883488 0.003062091 0.0001 0.0001 0.0001 0.0001 0.0001 0.081 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 0.006907462 1 0.006907462 3.848608409 0.053022 5.204434 0.0001 0.0001 Within Groups 0.154352339 86 0.001794795 0.0001 0.0001 0.0001 0.0001 Total 0.1612598 87 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.099 0.0001 0.0001 0.0001 0.217 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.03 0.0001 0.00589 0.058 0.0165 0.0029 0.0231 0.00114 0.0269 0.0203 0.274 0.099 0.0404 0.00267 0.0185 0.023 0.0403 0.00351 0.0564 0.00361 0.0949 0.00323 0.027 0.00532 0.019 0.009 0.016 0.005 0.006 0.04 0.009 0.007 0.01 0.012 0.0001 0.013 0.042 0.018 0.011 Chromium Background MW-14 0.024 0.001 Anova: Single Factor 0.001 0.001 0.011 0.001 SUMMARY 0.001 0.013 Groups Count Sum Average Variance 0.001 0.001 0.024 44 0.09427 0.002143 6.98149E-06 0.001 0.001 0.001 44 0.20835 0.004735 4.44432E-05 0.001 0.001 0.001 0.034 0.001 0.001 ANOVA 0.001 0.001 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 0.000148 1 0.000148 5.751680768 0.018635 5.204434 0.001 0.001 Within Groups 0.002211 86 2.57E-05 0.001 0.001 0.001 0.001 Total 0.002359 87 0.001 0.001 SIGNIFICANT 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.0054 0.00554 0.00273 0.00328 0.00439 0.00265 0.0149 0.00623 0.00145 0.0021 0.0035 0.00673 0.0016 0.00256 0.0019 0.00423 0.001 0.00813 0.001 0.0175 0.002 0.014 0.002 0.012 0.004 0.006 0.002 0.022 0.002 0.004 0.003 0.007 0.0030 0.0065 0.0024 0.0069 Cobalt Background MW-14 Anova: Single Factor 0.071 0.001 0.001 0.001 SUMMARY 0.022 0.001 Groups Count Sum Average Variance 0.001 0.012 Background 45 0.1864 0.004142 0.000127026 0.001 0.001 MW-14 45 0.09749 0.002166 6.5057E-06 0.001 0.001 0.001 0.001 0.001 0.001 ANOVA 0.001 0.001 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 8.78E-05 1 8.78E-05 1.315544625 0.254502 5.200226 0.001 0.001 Within Groups 0.005875 88 6.68E-05 0.001 0.001 0.001 0.001 Total 0.005963 89 0.001 0.001 NOT SIGNIFICANT 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.00651 0.001 0.0254 0.001 0.001 0.001 0.00547 0.0017 0.001 0.001 0.001 0.00271 0.001 0.00584 0.00142 0.00874 0.002 0.009 0.001 0.007 0.006 0.004 0.002 0.001 0.003 0.001 0.003 0.004 0.0040 0.0037 0.0026 0.0048 Vanadium Background MW-14 Anova: Single Factor 0.117 0.0001 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 45 0.45718 0.01016 0.000585103 0.0001 0.0001 MW-14 45 0.25718 0.005715 9.45426E-05 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 0.000444 1 0.000444 1.307871685 0.255882 5.200226 0.0001 0.0001 Within Groups 0.029904 88 0.00034 0.0001 0.0001 0.0001 0.0001 Total 0.030349 89 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.058 0.0001 0.0029 0.0001 0.00114 0.00083 0.0203 0.0124 0.099 0.00875 0.00267 0.00486 0.023 0.0126 0.00351 0.00484 0.00361 0.0103 0.00323 0.0217 0.00532 0.0281 0.009 0.036 0.005 0.034 0.04 0.026 0.007 0.005 0.012 0.006 0.013 0.013 0.018 0.012 0.011 0.018 Chromium Background MW-15 Anova: Single Factor 0.024 0.012 0.001 0.001 SUMMARY 0.011 0.036 Groups Count Sum Average Variance 0.001 0.196 Background 45 0.11827 0.002628 1.74E-05 0.001 0.003 MW-15 45 0.65063 0.014458 0.001013 0.001 0.001 0.001 0.001 0.001 0.01 ANOVA 0.001 0.001 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 0.003149 1 0.003149 6.111755 0.015352 5.200226 0.001 0.001 Within Groups 0.04534 88 0.000515 0.001 0.001 0.001 0.001 Total 0.048489 89 0.001 0.001 SIGNIFICANT 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.0195 0.001 0.001 0.001 0.001 0.001 0.06 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.011 0.001 0.001 0.001 0.001 0.0054 0.0121 0.00273 0.00449 0.00439 0.00692 0.0149 0.00308 0.00145 0.00787 0.0035 0.00489 0.0016 0.00478 0.0019 0.0577 0.001 0.0389 0.001 0.0507 0.002 0.031 0.002 0.031 0.004 0.003 0.002 0.001 0.002 0.002 0.003 0.007 0.0030 0.0108 0.0024 0.0069 Cobalt Background MW-15 Anova: Single Factor 0.071 0.001 0.001 0.001 SUMMARY 0.022 0.012 Groups Count Sum Average Variance 0.001 0.052 Background 45 0.1864 0.004142 0.000127 0.001 0.007 MW-15 45 0.26695 0.005932 8.48E-05 0.001 0.001 0.001 0.001 0.001 0.001 ANOVA 0.001 0.001 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 7.21E-05 1 7.21E-05 0.680697 0.411578 5.200226 0.001 0.001 Within Groups 0.00932 88 0.000106 0.001 0.0102 0.001 0.001 Total 0.009392 89 0.001 0.001 NOT SIGNIFICANT 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.0169 0.001 0.001 0.001 0.001 0.001 0.025 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.00526 0.001 0.001 0.00651 0.00347 0.0254 0.001 0.001 0.00791 0.00547 0.00217 0.001 0.00304 0.001 0.0194 0.001 0.0132 0.00142 0.0194 0.002 0.01 0.001 0.01 0.006 0.004 0.002 0.004 0.003 0.004 0.003 0.008 0.0040 0.0032 0.0026 0.0038 Thallium Background MW-15 Anova: Single Factor 0.0001 0.0001 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 45 0.010035 0.000223 6.8E-07 0.0001 0.0001 MW-15 45 0.023727 0.000527 3.94E-06 0.0001 0.0001 0.0001 0.012 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 2.08E-06 1 2.08E-06 0.901786 0.344904 5.200226 0.0001 0.0001 Within Groups 0.000203 88 2.31E-06 0.0001 0.0001 0.0001 0.0001 Total 0.000205 89 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.00563 0.0001 0.0001 0.0001 0.0001 0.0064 0.0001 0.0001 0.0001 0.0001 0.0001 0.000251 0.000265 0.0001 0.0001 0.000489 0.0001 0.000251 0.0001 0.000276 0.0001 0.0002 0.0001 0.0002 0.00008 0.0001 0.00005 0.0001 0.00006 0.0001 0.00005 0.00006 0.0001 0.0001 0.0001 0.0001 Vanadium Background MW-15 Anova: Single Factor 0.117 0.0001 0.0001 0.0001 SUMMARY 0.0001 0.143 Groups Count Sum Average Variance 0.0001 0.410 Background 45 0.45718 0.01016 0.000585 0.0001 0.051 MW-15 45 1.80824 0.040183 0.005209 0.0001 0.0001 0.0001 0.0001 0.0001 0.040 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 0.020282 1 0.020282 7.001345 0.009648 5.200226 0.0001 0.0001 Within Groups 0.254922 88 0.002897 0.0001 0.0941 0.0001 0.0001 Total 0.275204 89 0.0001 0.0001 SIGNIFICANT 0.0001 0.0669 0.0001 0.0001 0.0001 0.0001 0.0001 0.0617 0.0001 0.0001 0.0001 0.0001 0.0001 0.142 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.058 0.027 0.0029 0.0191 0.00114 0.00504 0.0203 0.0277 0.099 0.0213 0.00267 0.0239 0.023 0.0201 0.00351 0.0318 0.00361 0.144 0.00323 0.0938 0.00532 0.153 0.009 0.069 0.005 0.093 0.04 0.018 0.007 0.004 0.012 0.003 0.013 0.006 0.018 0.019 0.011 0.019 Antimony Background MW-15D Anova: Single Factor 0.00010 0.00010 0.00010 0.00010 SUMMARY 0.00010 0.00010 Groups Count Sum Average Variance 0.00010 0.00010 Background 46 0.010169 0.000221 9.39E-08 0.00010 0.00010 MW-15D 45 0.011933 0.000265 1.5E-07 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 ANOVA 0.00010 0.00010 Source of Variation SS df MS F P-value F crit 0.00010 0.00010 Between Groups 4.43E-08 1 4.43E-08 0.363576 0.54806 5.198195 0.00010 0.00010 Within Groups 1.08E-05 89 1.22E-07 0.00010 0.00010 0.00010 0.00010 Total 1.09E-05 90 0.00010 0.00010 NOT SIGNIFICANT 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00137 0.00010 0.00053 0.00101 0.00056 0.00173 0.00036 0.00085 0.00071 0.00010 0.00103 0.00025 0.00010 0.00010 0.00210 0.00040 0.00030 0.00060 0.00050 0.00010 0.00060 0.00010 0.00010 0.00060 0.00010 0.00040 0.00030 0.00030 0.00027 0.00043 Thallium Background MW-15D Anova: Single Factor 0.0001 0.0001 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 46 0.01148 0.00025 1.01E-06 0.0001 0.0001 MW-15D 45 0.015663 0.000348 2.64E-06 0.0001 0.0001 0.0001 0.0001 0.0001 0.011 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 2.21E-07 1 2.21E-07 0.121652 0.728074 5.198195 0.0001 0.0001 Within Groups 0.000161 89 1.81E-06 0.0001 0.0001 0.0001 0.0001 Total 0.000162 90 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.00691 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.000363 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0002 0.0001 0.00007 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 Vanadium Background MW-15D Anova: Single Factor 0.0001 0.0001 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 46 0.21522 0.004679 0.000243 0.0001 0.0001 MW-15D 46 0.0479 0.001041 4E-06 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 0.000304 1 0.000304 2.461632 0.120167 5.19621 0.0001 0.0001 Within Groups 0.011126 90 0.000124 0.0001 0.0001 0.0001 0.0001 Total 0.01143 91 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0101 0.00097 0.00527 0.00409 0.00258 0.0201 0.00253 0.00728 0.00258 0.0055 0.00253 0.00382 0.00201 0.00373 0.00179 0.00245 0.00146 0.00205 0.00245 0.00253 0.0001 0.0001 0.0001 0.002 0.0001 0.099 0.002 0.037 0.007 0.005 0.0001 0.014 0.0001 0.0001 0.0001 0.0027 0.0023 Arsenic Background MW-16 Anova: Single Factor 0.0110 0.0001 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 45 0.0158 0.000351111 2.63937E-06 0.0001 0.0001 MW-16 44 0.05514 0.001253182 1.19547E-05 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 1.81032E-05 1 1.81032E-05 2.499233575 0.117531 5.202305 0.0001 0.0001 Within Groups 0.000630186 87 7.24352E-06 0.0001 0.0001 0.0001 0.0001 Total 0.000648289 88 0.0001 0.0133 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0151 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0120 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0022 0.0001 0.0001 0.0001 0.0051 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0008 0.0001 0.0006 0.0001 0.0010 0.0001 0.0006 0.0001 0.0009 0.0001 0.0001 0.0001 0.0001 0.0005 0.00028 0.0001 Chromium Background MW-16 Anova: Single Factor 0.024 0.590 0.001 0.204 SUMMARY 0.011 0.086 Groups Count Sum Average Variance 0.001 0.040 Background 45 0.11827 0.002628222 1.74395E-05 0.001 0.001 MW-16 44 1.03271 0.023470682 0.008729674 0.001 0.012 0.001 0.001 0.001 0.012 ANOVA 0.001 0.001 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 0.00966436 1 0.00966436 2.235316454 0.138508 5.202305 0.001 0.001 Within Groups 0.376143324 87 0.004323486 0.001 0.001 0.001 0.001 Total 0.385807684 88 0.001 0.001 NOT SIGNIFICANT 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.012 0.001 0.001 0.001 0.001 0.001 0.0152 0.0054 0.0105 0.00273 0.00223 0.00439 0.00425 0.0149 0.00177 0.00145 0.001 0.0035 0.00105 0.0016 0.00135 0.0019 0.00235 0.001 0.00641 0.001 0.001 0.002 0.0007 0.002 0.002 0.004 0.005 0.002 0.0005 0.002 0.0004 0.003 0.0005 0.0030 0.0015 0.0024 Cobalt Background MW-16 Anova: Single Factor 0.071 0.001 0.001 0.001 SUMMARY 0.022 0.001 Groups Count Sum Average Variance 0.001 0.001 Background 45 0.1864 0.004142222 0.000127026 0.001 0.017 MW-16 44 0.15234 0.003462273 1.73441E-05 0.001 0.002 0.001 0.001 0.001 0.01 ANOVA 0.001 0.001 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 1.02856E-05 1 1.02856E-05 0.141255844 0.707951 5.202305 0.001 0.001 Within Groups 0.006334923 87 7.28152E-05 0.001 0.001 0.001 0.0133 Total 0.006345208 88 0.001 0.001 NOT SIGNIFICANT 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.0124 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.012 0.001 0.001 0.001 0.001 0.001 0.00752 0.001 0.0133 0.001 0.001 0.00651 0.00283 0.0254 0.0031 0.001 0.001 0.00547 0.0025 0.001 0.00248 0.001 0.00409 0.001 0.00652 0.00142 0.003 0.002 0.002 0.001 0.004 0.006 0.003 0.002 0.002 0.003 0.002 0.003 0.002 0.0040 0.0033 0.0026 Thallium Background MW-16 Anova: Single Factor 0.0001 0.0001 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 45 0.010035 0.000223 6.80325E-07 0.0001 0.0001 MW-16 44 0.01978 0.000449545 5.0445E-06 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.015 Between Groups 1.14179E-06 1 1.14179E-06 0.402416906 0.527508 5.202305 0.0001 0.0001 Within Groups 0.000246848 87 2.83733E-06 0.0001 0.0001 0.0001 0.0001 Total 0.000247989 88 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.00563 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.000625 0.0001 0.0001 0.000265 0.0001 0.0001 0.0001 0.0001 0.000143 0.0001 0.00007 0.0001 0.0001 0.0001 0.00009 0.00008 0.0001 0.00005 0.00009 0.00006 0.0001 0.00005 0.00008 0.0001 0.000082 0.0001 Vanadium Background MW-16 Anova: Single Factor 0.117 0.0001 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 45 0.45718 0.010159556 0.000585103 0.0001 0.065 MW-16 44 0.22928 0.005210909 0.000139057 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 0.000544814 1 0.000544814 1.49410011 0.224883 5.202305 0.0001 0.0001 Within Groups 0.031723975 87 0.000364643 0.0001 0.0001 0.0001 0.0001 Total 0.032268788 88 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.058 0.0307 0.0029 0.0294 0.00114 0.0203 0.0203 0.0113 0.099 0.0049 0.00267 0.00453 0.023 0.00391 0.00351 0.00449 0.00361 0.00695 0.00323 0.013 0.00532 0.0001 0.009 0.004 0.005 0.012 0.04 0.011 0.007 0.0001 0.012 0.0001 0.013 0.0001 0.018 0.0049 0.011 Chromium Background MW-17 Anova: Single Factor 0.024 0.001 0.001 0.012 SUMMARY 0.011 0.036 Groups Count Sum Average Variance 0.001 0.014 Background 45 0.11827 0.002628222 1.74395E-05 0.001 0.003 MW-17 45 0.37418 0.008315111 8.81301E-05 0.001 0.02 0.001 0.013 0.001 0.011 ANOVA 0.001 0.001 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 0.000728 1 0.000727666 13.78551617 0.000359 5.200226 0.001 0.001 Within Groups 0.004645 88 5.27848E-05 0.001 0.001 0.001 0.001 Total 0.005373 89 0.001 0.001 SIGNIFICANT 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.014 0.001 0.001 0.001 0.02 0.001 0.001 0.001 0.019 0.0054 0.0112 0.00273 0.00557 0.00439 0.001 0.0149 0.00453 0.00145 0.0106 0.0035 0.00728 0.0016 0.00157 0.0019 0.00743 0.001 0.0266 0.001 0.0366 0.002 0.017 0.002 0.006 0.004 0.019 0.002 0.019 0.002 0.01 0.003 0.009 0.0030 0.0013 0.0024 0.0015 Cobalt Background MW-17 Anova: Single Factor 0.071 0.001 0.001 0.001 SUMMARY 0.022 0.011 Groups Count Sum Average Variance 0.001 0.001 Background 45 0.1864 0.004142222 0.000127026 0.001 0.001 MW-17 45 0.077 0.001711111 3.61217E-06 0.001 0.001 0.001 0.001 0.001 0.001 ANOVA 0.001 0.001 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 0.000133 1 0.000132982 2.035885272 0.157163 5.200226 0.001 0.001 Within Groups 0.005748 88 6.53189E-05 0.001 0.001 0.001 0.001 Total 0.005881 89 0.001 0.001 NOT SIGNIFICANT 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.00651 0.001 0.0254 0.001 0.001 0.00243 0.00547 0.00195 0.001 0.001 0.001 0.00149 0.001 0.00659 0.00142 0.0061 0.002 0.003 0.001 0.002 0.006 0.003 0.002 0.004 0.003 0.002 0.003 0.002 0.0040 0.0001 0.0026 0.00034 Vanadium Background MW-17 Anova: Single Factor 0.117 0.0001 0.0001 0.0001 SUMMARY 0.0001 0.104 Groups Count Sum Average Variance 0.0001 0.0001 Background 45 0.45718 0.010159556 0.000585103 0.0001 0.0001 MW-17 45 0.52103 0.011578444 0.00045551 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 4.53E-05 1 4.5298E-05 0.087060315 0.768643 5.200226 0.0001 0.0001 Within Groups 0.045787 88 0.000520306 0.0001 0.0001 0.0001 0.0001 Total 0.045832 89 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.042 0.0001 0.0001 0.058 0.041 0.0029 0.0113 0.00114 0.0001 0.0203 0.00763 0.099 0.00344 0.00267 0.0202 0.023 0.0145 0.00351 0.00226 0.00361 0.0118 0.00323 0.0489 0.00532 0.0671 0.009 0.032 0.005 0.012 0.04 0.035 0.007 0.034 0.012 0.016 0.013 0.012 0.018 0.0001 0.011 0.0033 Antimony Background MW-17D Anova: Single Factor 0.00010 0.00010 0.00010 0.00010 SUMMARY 0.00010 0.00010 Groups Count Sum Average Variance 0.00010 0.00010 Background 46 0.010169 0.000221 9.39289E-08 0.00010 0.00010 MW-17D 45 0.015802 0.000351 3.57573E-07 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 ANOVA 0.00010 0.00010 Source of Variation SS df MS F P-value F crit 0.00010 0.00010 Between Groups 3.85E-07 1 3.85E-07 1.716518 0.193513 5.198195 0.00010 0.00010 Within Groups 2E-05 89 2.24E-07 0.00010 0.00010 0.00010 0.00010 Total 2.03E-05 90 0.00010 0.00010 NOT SIGNIFICANT 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00010 0.00056 0.00010 0.00217 0.00101 0.00105 0.00173 0.00087 0.00085 0.00069 0.00010 0.00067 0.00025 0.00010 0.00010 0.00310 0.00040 0.00170 0.00060 0.00030 0.00010 0.00010 0.00010 0.00040 0.00060 0.00040 0.00040 0.00030 0.00030 0.00039 0.00043 Vanadium Background MW-17D Anova: Single Factor 0.0001 0.0001 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 46 0.21522 0.004679 0.000243237 0.0001 0.0001 MW-17D 45 0.06771 0.001505 6.77199E-06 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 0.000229 1 0.000229 1.813984273 0.181451 5.198195 0.0001 0.0001 Within Groups 0.011244 89 0.000126 0.0001 0.0001 0.0001 0.0001 Total 0.011473 90 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.00097 0.0001 0.00409 0.0115 0.0201 0.00662 0.00728 0.00495 0.0055 0.00483 0.00382 0.00452 0.00373 0.0042 0.00245 0.00423 0.00205 0.00436 0.00253 0.0001 0.0001 0.003 0.002 0.007 0.099 0.005 0.037 0.0001 0.005 0.0001 0.014 0.0001 0.0001 0.0042 0.0027 Chromium Background MW-18 Anova: Single Factor 0.024 0.271 0.001 0.001 SUMMARY 0.011 0.067 Groups Count Sum Average Variance 0.001 0.299 Background 45 0.11827 0.002628222 1.74395E-05 0.001 0.001 MW-18 45 1.69619 0.037693111 0.003816662 0.001 0.001 0.001 0.064 0.001 0.014 ANOVA 0.001 0.013 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 0.027664795 1 0.027664795 14.43091597 0.000267 5.200226 0.001 0.0123 Within Groups 0.168700444 88 0.001917051 0.001 0.001 0.001 0.001 Total 0.196365239 89 0.001 0.001 SIGNIFICANT 0.001 0.0231 0.001 0.001 0.001 0.0146 0.001 0.0235 0.001 0.0275 0.001 0.0251 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.023 0.001 0.047 0.001 0.001 0.001 0.035 0.0054 0.022 0.00273 0.00498 0.00439 0.0117 0.0149 0.0164 0.00145 0.0901 0.0035 0.00192 0.0016 0.00959 0.0019 0.0326 0.001 0.126 0.001 0.0855 0.002 0.040 0.002 0.043 0.004 0.070 0.002 0.088 0.002 0.060 0.003 0.005 0.0030 0.008 0.0024 0.01 Cobalt Background MW-18 Anova: Single Factor 0.071 0.092 0.001 0.001 SUMMARY 0.022 0.038 Groups Count Sum Average Variance 0.001 0.127 Background 45 0.1864 0.004142222 0.000127026 0.001 0.001 MW-18 45 0.70881 0.015751333 0.000614272 0.001 0.045 0.001 0.026 0.001 0.001 ANOVA 0.001 0.001 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 0.003032358 1 0.003032358 8.181215556 0.005286 5.200226 0.001 0.001 Within Groups 0.032617096 88 0.000370649 0.001 0.001 0.001 0.001 Total 0.035649454 89 0.001 0.001 SIGNIFICANT 0.001 0.0165 0.001 0.001 0.001 0.0106 0.001 0.0133 0.001 0.0134 0.001 0.0119 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.019 0.001 0.001 0.001 0.013 0.001 0.00544 0.001 0.001 0.00651 0.001 0.0254 0.00321 0.001 0.0369 0.00547 0.001 0.001 0.00306 0.001 0.0116 0.001 0.0484 0.00142 0.0361 0.002 0.015 0.001 0.015 0.006 0.026 0.002 0.034 0.003 0.023 0.003 0.001 0.0040 0.0028 0.0026 0.0036 Thallium Background MW-18 Anova: Single Factor 0.0001 0.0001 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 45 0.010035 0.000223 6.80325E-07 0.0001 0.0001 MW-18 45 0.005878 0.000130622 1.57491E-08 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 1.92007E-07 1 1.92007E-07 0.551685797 0.459608 5.200226 0.0001 0.0001 Within Groups 3.06273E-05 88 3.48037E-07 0.0001 0.0001 0.0001 0.0001 Total 3.08193E-05 89 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.00563 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.000128 0.0001 0.000356 0.000265 0.0001 0.0001 0.0001 0.0001 0.000194 0.0001 0.0001 0.0001 0.0009 0.0001 0.0001 0.00008 0.0002 0.00005 0.0002 0.00006 0.0001 0.00005 0.0001 0.0001 0.0001 0.0001 0.0001 Vanadium Background MW-18 Anova: Single Factor 0.117 0.207 0.0001 0.0001 SUMMARY 0.0001 0.107 Groups Count Sum Average Variance 0.0001 0.165 Background 45 0.45718 0.010159556 0.000585103 0.0001 0.0001 MW-18 45 1.40317 0.031181556 0.002301829 0.0001 0.11 0.0001 0.062 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 0.009943301 1 0.009943301 6.888490307 0.010228 5.200226 0.0001 0.0001 Within Groups 0.127025 88 0.001443466 0.0001 0.0001 0.0001 0.0001 Total 0.1369683 89 0.0001 0.0001 SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.056 0.0001 0.025 0.058 0.044 0.0029 0.0178 0.00114 0.0014 0.0203 0.0218 0.099 0.0138 0.00267 0.0814 0.023 0.00329 0.00351 0.00828 0.00361 0.0282 0.00323 0.116 0.00532 0.0732 0.009 0.033 0.005 0.037 0.04 0.067 0.007 0.081 0.012 0.031 0.013 0.001 0.018 0.0001 0.011 0.01 Vanadium Background MW-19 Anova: Single Factor 0.117 0.0826 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 45 0.45718 0.01016 0.000585 0.0001 0.0001 MW-19 39 0.12091 0.0031 0.000174 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 0.001041 1 0.001041 2.638752 0.108123 5.213481 0.0001 0.0001 Within Groups 0.032355 82 0.000395 0.0001 0.0001 0.0001 0.0001 Total 0.033396 83 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.00773 0.0001 0.00462 0.058 0.00474 0.0029 0.00269 0.00114 0.00232 0.0203 0.00379 0.099 0.00252 0.00267 0.0001 0.023 0.0001 0.00351 0.004 0.00361 0.0001 0.00323 0.0001 0.00532 0.0001 0.009 0.0001 0.005 0.003 0.04 0.007 0.012 0.013 0.018 0.011 Chromium Background MW-20 Anova: Single Factor 0.024 0.0118 0.001 0.001 SUMMARY 0.011 0.001 Groups Count Sum Average Variance 0.001 0.001 Background 45 0.11827 0.002628222 1.74395E-05 0.001 0.001 MW-20 39 0.22843 0.005857179 5.61026E-05 0.001 0.001 0.001 0.001 0.001 0.001 ANOVA 0.001 0.001 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 0.000218 1 0.000217832 6.161017835 0.015101 5.213481 0.001 0.001 Within Groups 0.002899 82 3.53566E-05 0.001 0.0101 0.001 0.001 Total 0.003117 83 0.001 0.001 SIGNIFICANT 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.00474 0.001 0.00317 0.001 0.00284 0.001 0.00509 0.001 0.0172 0.001 0.00165 0.0054 0.00152 0.00273 0.00282 0.00439 0.0103 0.0149 0.0138 0.00145 0.012 0.0035 0.026 0.0016 0.007 0.0019 0.025 0.001 0.009 0.001 0.004 0.002 0.0274 0.002 0.014 0.004 0.002 0.002 0.003 0.0030 0.0024 Cobalt Background MW-20 Anova: Single Factor 0.071 0.036 0.001 0.001 SUMMARY 0.022 0.001 Groups Count Sum Average Variance 0.001 0.001 Background 45 0.1864 0.004142222 0.000127026 0.001 0.001 MW-20 39 0.36674 0.00940359 0.000136282 0.001 0.001 0.001 0.001 0.001 0.001 ANOVA 0.001 0.0279 Source of Variation SS df MS F P-value F crit 0.001 0.011 Between Groups 0.000578 1 0.000578356 4.404337624 0.038924 5.213481 0.001 0.001 Within Groups 0.010768 82 0.000131315 0.001 0.0191 0.001 0.001 Total 0.011346 83 0.001 0.001 NOT SIGNIFICANT 0.001 0.01 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.012 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.0278 0.001 0.001 0.001 0.001 0.001 0.00264 0.00651 0.0157 0.0254 0.0175 0.001 0.019 0.00547 0.032 0.001 0.01 0.001 0.032 0.001 0.013 0.00142 0.004 0.002 0.0381 0.001 0.018 0.006 0.002 0.003 0.003 0.0040 0.0026 Lead Background MW-20 Anova: Single Factor 0.026 0.0005 0.0005 0.0005 SUMMARY 0.0005 0.0005 Groups Count Sum Average Variance 0.0005 0.0005 Background 45 0.10823 0.002405111 2.57334E-05 0.0005 0.0005 MW-20 39 0.18592 0.004767179 4.88529E-05 0.0005 0.0005 0.0005 0.0005 0.0005 0.0005 ANOVA 0.0005 0.0005 Source of Variation SS df MS F P-value F crit 0.0005 0.0005 Between Groups 0.000117 1 0.000116569 3.198284523 0.077409 5.213481 0.0005 0.0005 Within Groups 0.002989 82 3.64473E-05 0.0005 0.0005 0.0005 0.0005 Total 0.003105 83 0.0005 0.0005 NOT SIGNIFICANT 0.0005 0.0005 0.0005 0.0005 0.0005 0.0005 0.0005 0.0005 0.0005 0.0005 0.0005 0.0005 0.0005 0.019 0.0005 0.0113 0.0005 0.0005 0.0005 0.0005 0.0005 0.00788 0.0005 0.0122 0.012 0.0005 0.00392 0.00273 0.00978 0.0005 0.00584 0.00831 0.0192 0.0117 0.0005 0.009 0.00569 0.026 0.0005 0.005 0.0005 0.019 0.0005 0.007 0.0005 0.002 0.001 0.0231 0.0005 0.0097 0.003 0.001 0.001 0.001 0.002 0.0013 Thallium Background MW-20 Anova: Single Factor 0.0001 0.0001 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 45 0.010035 0.000223 6.80325E-07 0.0001 0.0001 MW-20 39 0.016189 0.000415103 3.32213E-06 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 7.71E-07 1 7.71017E-07 0.404823539 0.526381 5.213481 0.0001 0.0001 Within Groups 0.000156 82 1.90458E-06 0.0001 0.0001 0.0001 0.0001 Total 0.000157 83 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0115 0.0001 0.0001 0.0001 0.000129 0.0001 0.0002 0.00563 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0002 0.0001 0.0003 0.000265 0.00008 0.0001 0.0003 0.0001 0.0001 0.0001 0.0001 0.0001 0.00032 0.0001 0.00016 0.00008 0.00005 0.00006 0.00005 0.0001 0.0001 Vanadium Background MW-20 Anova: Single Factor 0.117 0.0001 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 45 0.45718 0.010159556 0.000585103 0.0001 0.0001 MW-20 39 0.72633 0.018623846 0.000909575 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 0.001497 1 0.001496852 2.035238103 0.157487 5.213481 0.0001 0.0001 Within Groups 0.060308 82 0.000735468 0.0001 0.0001 0.0001 0.0001 Total 0.061805 83 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.029 0.0001 0.0107 0.0001 0.00654 0.0001 0.029 0.0001 0.0122 0.0001 0.0538 0.058 0.00981 0.0029 0.00998 0.00114 0.0126 0.0203 0.0341 0.099 0.0426 0.00267 0.042 0.023 0.110 0.00351 0.034 0.00361 0.074 0.00323 0.039 0.00532 0.007 0.009 0.127 0.005 0.041 0.04 0.007 0.012 0.013 0.018 0.011 Cobalt Background MW-21 Anova: Single Factor 0.071 0.0632 0.001 0.001 SUMMARY 0.022 0.001 Groups Count Sum Average Variance 0.001 0.001 Background 45 0.1864 0.004142 0.000127 0.001 0.001 MW-21 41 0.16875 0.004116 0.000101 0.001 0.001 0.001 0.001 0.001 0.001 ANOVA 0.001 0.001 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 1.49E-08 1 1.49E-08 0.00013 0.990921 5.208847 0.001 0.001 Within Groups 0.00962 84 0.000115 0.001 0.001 0.001 0.001 Total 0.00962 85 0.001 0.001 NOT SIGNIFICANT 0.001 0.016 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.00461 0.001 0.001 0.001 0.001 0.00651 0.00125 0.0254 0.00804 0.001 0.00725 0.00547 0.003 0.001 0.003 0.001 0.004 0.001 0.002 0.00142 0.004 0.002 0.003 0.001 0.010 0.006 0.001 0.002 0.012 0.003 0.003 0.0040 0.0026 Thallium Background MW-21 Anova: Single Factor 0.0001 0.0001 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 45 0.010035 0.000223 6.8E-07 0.0001 0.0001 MW-21 39 0.01202 0.000308 1.67E-06 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 1.52E-07 1 1.52E-07 0.133409 0.715863 5.213481 0.0001 0.0001 Within Groups 9.32E-05 82 1.14E-06 0.0001 0.0001 0.0001 0.0001 Total 9.34E-05 83 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.00816 0.0001 0.0001 0.0001 0.0001 0.0001 0.000148 0.00563 0.0001 0.0001 0.0001 0.0001 0.000122 0.0001 0.0001 0.0001 0.0001 0.0001 0.00005 0.000265 0.0001 0.0001 0.00006 0.0001 0.00006 0.0001 0.0001 0.0001 0.0001 0.0001 0.00022 0.00008 0.00005 0.00006 0.00005 0.0001 0.0001 Vanadium Background MW-21 Anova: Single Factor 0.117 0.0565 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 45 0.45718 0.01016 0.000585 0.0001 0.0001 MW-21 39 0.38454 0.00986 0.000222 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 1.87E-06 1 1.87E-06 0.004497 0.946698 5.213481 0.0001 0.0001 Within Groups 0.034186 82 0.000417 0.0001 0.0001 0.0001 0.0001 Total 0.034188 83 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.049 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.00538 0.0001 0.0001 0.0001 0.0195 0.0001 0.00725 0.0001 0.0192 0.058 0.00693 0.0029 0.00483 0.00114 0.00675 0.0203 0.0315 0.099 0.0357 0.00267 0.011 0.023 0.015 0.00351 0.012 0.00361 0.017 0.00323 0.015 0.00532 0.019 0.009 0.006 0.005 0.045 0.04 0.007 0.012 0.013 0.018 0.011 Cobalt Background MW-25 Anova: Single Factor 0.071 0.001 0.001 0.001 SUMMARY 0.022 0.001 Groups Count Sum Average Variance 0.001 0.001 Background 45 0.1864 0.004142 0.000127026 0.001 0.001 MW-25 39 0.05779 0.001482 8.67415E-07 0.001 0.001 0.001 0.001 0.001 0.001 ANOVA 0.001 0.001 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 0.000148 1 0.000148 2.156834304 0.145763 5.213481 0.001 0.001 Within Groups 0.005622 82 6.86E-05 0.001 0.001 0.001 0.001 Total 0.00577 83 0.001 0.001 NOT SIGNIFICANT 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.00527 0.001 0.00212 0.001 0.00187 0.001 0.00282 0.00651 0.001 0.0254 0.00141 0.001 0.002 0.00547 0.003 0.001 0.003 0.001 0.0007 0.001 0.002 0.00142 0.002 0.002 0.0022 0.001 0.0034 0.006 0.002 0.003 0.003 0.0040 0.0026 Thallium Background MW-25 Anova: Single Factor 0.0001 0.0001 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 45 0.010035 0.000223 6.80325E-07 0.0001 0.0001 MW-25 39 0.004186 0.000107 1.04007E-09 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 2.8E-07 1 2.8E-07 0.764690516 0.384419 5.213481 0.0001 0.0001 Within Groups 3E-05 82 3.66E-07 0.0001 0.0001 0.0001 0.0001 Total 3.03E-05 83 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.000262 0.00563 0.000224 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.000265 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.00008 0.00005 0.00006 0.00005 0.0001 0.0001 Vanadium Background MW-25 Anova: Single Factor 0.117 0.0001 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 45 0.45718 0.01016 0.000585103 0.0001 0.0001 MW-25 39 0.06099 0.001564 9.25944E-06 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 0.001544 1 0.001544 4.850593535 0.030444 5.213481 0.0001 0.0001 Within Groups 0.026096 82 0.000318 0.0001 0.0001 0.0001 0.0001 Total 0.02764 83 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.00813 0.0001 0.00151 0.0001 0.015 0.058 0.00565 0.0029 0.00344 0.00114 0.00554 0.0203 0.00159 0.099 0.00393 0.00267 0.0001 0.023 0.004 0.00351 0.004 0.00361 0.0001 0.00323 0.0001 0.00532 0.0001 0.009 0.0001 0.005 0.0054 0.04 0.007 0.012 0.013 0.018 0.011 Chromium Background MW-25D Anova: Single Factor 0.001 0.001 0.001 0.001 SUMMARY 0.001 0.001 Groups Count Sum Average Variance 0.001 0.001 Background 46 0.09981 0.002169783 6.23E-06 0.001 0.001 MW-25D 39 0.26401 0.006769487 0.000104 0.001 0.001 0.001 0.001 0.001 0.001 ANOVA 0.001 0.001 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 0.000446543 1 0.000446543 8.73392 0.004064 5.211135 0.001 0.001 Within Groups 0.004243579 83 5.11275E-05 0.001 0.0172 0.001 0.001 Total 0.004690122 84 0.001 0.001 SIGNIFICANT 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.01 0.001 0.001 0.001 0.01 0.001 0.0121 0.001 0.054 0.001 0.0192 0.001 0.00716 0.001 0.0164 0.001 0.033 0.001 0.00693 0.00641 0.00859 0.00194 0.00427 0.00714 0.00506 0.00541 0.006 0.0051 0.005 0.00356 0.006 0.00343 0.007 0.00218 0.004 0.00304 0.006 0.0024 0.0042 0.002 0.0039 0.001 0.015 0.005 0.002 0.003 0.002 0.0012 Cobalt Background MW-25D Anova: Single Factor 0.071 0.001 0.001 0.001 SUMMARY 0.022 0.001 Groups Count Sum Average Variance 0.001 0.001 Background 45 0.1864 0.004142222 0.000127 0.001 0.001 MW-25D 39 0.12732 0.003264615 2.64E-05 0.001 0.001 0.001 0.001 0.001 0.001 ANOVA 0.001 0.001 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 1.60915E-05 1 1.60915E-05 0.200213 0.655729 5.213481 0.001 0.001 Within Groups 0.006590531 82 8.03723E-05 0.001 0.0212 0.001 0.001 Total 0.006606622 83 0.001 0.001 NOT SIGNIFICANT 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.00418 0.001 0.00315 0.001 0.0117 0.001 0.001 0.001 0.0109 0.001 0.0239 0.001 0.00315 0.001 0.00506 0.00651 0.00144 0.0254 0.00164 0.001 0.003 0.00547 0.002 0.001 0.003 0.001 0.003 0.001 0.002 0.00142 0.003 0.002 0.0021 0.001 0.0019 0.006 0.002 0.003 0.003 0.0040 0.0026 Vanadium Background MW-25D Anova: Single Factor 0.0001 0.0001 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 46 0.21522 0.004678696 0.000243 0.0001 0.0001 MW-25D 39 0.25221 0.006466923 0.00017 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 6.74915E-05 1 6.74915E-05 0.321809 0.572054 5.211135 0.0001 0.0001 Within Groups 0.017407219 83 0.000209726 0.0001 0.0001 0.0001 0.0001 Total 0.017474711 84 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.013 0.0001 0.00444 0.0001 0.017 0.0001 0.00621 0.0001 0.0327 0.0001 0.0746 0.0001 0.0109 0.00097 0.0138 0.00409 0.00575 0.0201 0.00711 0.00728 0.007 0.0055 0.008 0.00382 0.01 0.00373 0.012 0.00245 0.007 0.00205 0.007 0.00253 0.006 0.0001 0.0076 0.002 0.099 0.037 0.005 0.014 0.0001 0.0027 Chromium Background MW-26 Anova: Single Factor 0.024 0.001 0.001 0.001 SUMMARY 0.011 0.001 Groups Count Sum Average Variance 0.001 0.001 Background 45 0.11827 0.002628 1.74E-05 0.001 0.001 MW-26 38 0.14828 0.003902 2.13E-05 0.001 0.001 0.001 0.001 0.001 0.001 ANOVA 0.001 0.001 Source of Variation SS df MS F P-value F crit 0.001 0.001 Between Groups 3.34E-05 1 3.34E-05 1.742379 0.190556 5.215887 0.001 0.001 Within Groups 0.001554 81 1.92E-05 0.001 0.001 0.001 0.001 Total 0.001588 82 0.001 0.011 NOT SIGNIFICANT 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.016 0.001 0.001 0.001 0.0102 0.001 0.00136 0.001 0.001 0.001 0.00332 0.001 0.00258 0.001 0.00729 0.001 0.00519 0.0054 0.00621 0.00273 0.00283 0.00439 0.0148 0.0149 0.013 0.00145 0.015 0.0035 0.004 0.0016 0.002 0.0019 0.001 0.001 0.007 0.001 0.0005 0.002 0.006 0.002 0.004 0.002 0.002 0.003 0.0030 0.0024 Cobalt Background MW-26 Anova: Single Factor 0.071 0.0306 0.001 0.0102 SUMMARY 0.022 0.01 Groups Count Sum Average Variance 0.001 0.001 Background 45 0.1864 0.004142 0.000127 0.001 0.0146 MW-26 38 0.49063 0.012911 6.1E-05 0.001 0.02 0.001 0.0109 0.001 0.0126 ANOVA 0.001 0.0111 Source of Variation SS df MS F P-value F crit 0.001 0.0152 Between Groups 0.001584 1 0.001584 16.35309 0.000119 5.215887 0.001 0.0165 Within Groups 0.007847 81 9.69E-05 0.001 0.0278 0.001 0.0117 Total 0.009431 82 0.001 0.023 SIGNIFICANT 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.026 0.001 0.001 0.001 0.0129 0.001 0.0046 0.001 0.00772 0.001 0.00721 0.001 0.0114 0.001 0.0145 0.001 0.0145 0.001 0.0148 0.001 0.0117 0.00651 0.024 0.0254 0.022 0.001 0.024 0.00547 0.014 0.001 0.011 0.001 0.011 0.001 0.016 0.00142 0.0091 0.002 0.014 0.001 0.006 0.002 0.003 0.003 0.0040 0.0026 Vanadium Background MW-26 Anova: Single Factor 0.117 0.0001 0.0001 0.0001 SUMMARY 0.0001 0.0001 Groups Count Sum Average Variance 0.0001 0.0001 Background 45 0.45718 0.01016 0.000585 0.0001 0.0001 MW-26 38 0.3363 0.00885 0.000206 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 ANOVA 0.0001 0.0001 Source of Variation SS df MS F P-value F crit 0.0001 0.0001 Between Groups 3.53E-05 1 3.53E-05 0.085727 0.77043 5.215887 0.0001 0.0001 Within Groups 0.033383 81 0.000412 0.0001 0.0405 0.0001 0.0001 Total 0.033419 82 0.0001 0.0001 NOT SIGNIFICANT 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.059 0.0001 0.0001 0.0001 0.0155 0.0001 0.0001 0.0001 0.00581 0.0001 0.00232 0.0001 0.00992 0.0001 0.0197 0.058 0.013 0.0029 0.0152 0.00114 0.00675 0.0203 0.0365 0.099 0.029 0.00267 0.039 0.023 0.014 0.00351 0.002 0.00361 0.0001 0.00323 0.008 0.00532 0.0001 0.009 0.018 0.005 0.04 0.007 0.012 0.013 0.018 0.011