8505_DukeBelewsCreekFGD_Nov2016_2ndSemiAnnual_DIN27307_20170124

FGD Residue Landfill Permit No. 8505
Semiannual Groundwater
Monitoring Report
November 2016 Sampling Event
Belews Creek Steam Station
January 25, 2017

Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
November 2016 Sampling Event
CONTENTS

ii
Contents
Page
Report Verification ....................................................................................................................... i
Contents ..................................................................................................................................... ii
Section 1 – Background ............................................................................................................. 1
Section 2 – Methods .................................................................................................................. 3
2.1 Sampling and Analysis Methods .................................................................................. 3
2.2 Statement of Work ....................................................................................................... 3
Section 3 – Results .................................................................................................................... 5
3.1 Site Groundwater Flow ................................................................................................ 5
3.2 Analytical Results......................................................................................................... 5

FIGURES
1. Site Location Map
2. Sample Locations
3. Generalized Groundwater Surface Contours
TABLES
1. Well Construction Information
2. Groundwater Flow Velocities
3. Field Data Parameters
4. Field and Analytical Results
5. Analytical Results that Equal or Exceed 15A NCAC 2L Groundwater Quality Standards
6. Leachate Field and Analytical Results
APPENDICES
A. Field Sampling Forms

B. Laboratory Report and Chain-of-Custody Forms
Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
November 2016 Sampling Event
SECTION 1 – BACKGROUND

1
Section 1 – Background
The flue gas desulfurization (FGD) residue landfill is located at the Duke Energy Carolinas, LLC
(Duke Energy) Belews Creek Steam Station in Stokes County, North Carolina. The FGD residue
landfill is permitted to receive FGD residue (gypsum) from Belews Creek Steam Station
operations. The landfill is permitted under the North Carolina Department of Environmental
Quality (NCDEQ) Solid Waste Permit No. 8505.
The FGD residue landfill is located south of the Belews Creek plant on land between two arms
of the Belews Lake. The West Belews Creek arm of the lake is located west of the landfill site
and the East Belews Creek arm of the lake is located east of the site. Craig Road is located to
the west of the landfill. The FGD residue landfill and nearby surrounding area are depicted on
Figure 1.
The landfill consists of four cells contained in an area of approximately 24 acres. The adjacent
stormwater basin occupies an area of approximately 2.4 acres and is used to manage leachate
and stormwater collected from the landfill. The landfill has an engineered liner system consisting
of a leachate collection system, underlain by a high-density polyethylene (HDPE) geomembrane
liner, underlain by a geo-synthetic clay liner.
The subsurface conditions in the landfill area consist of residual soils, saprolite, partially
weathered rock, and bedrock, as described in the Water Quality Monitoring Plan.1
As is typical for groundwater systems located in the Piedmont region, groundwater at the landfill
site occurs within the saprolite, partially weathered rock, and shallow fractured bedrock under
unconfined aquifer conditions. The groundwater flow in the area of the landfill is generally from
areas of higher topography, located to the east of the landfill, to the west and to the northwest of
the landfill, towards Belews Lake.

1 Water Quality Monitoring Plan FGD Scrubber Residue Landfill Belews Creek Steam Station, December 07, 2007.
Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
November 2016 Sampling Event
SECTION 1 – BACKGROUND

2
The monitoring system for the landfill consists of the following:
Monitoring Wells2: BC-20
BC-21 BC-22
BC-23A BC-25 BC-26
BC-27
BC-28 BC-29
BC-30 BC-31 BC-323
Observation Well: BC-7
Surface Water: SW-1
Leachate Sample: Leachate

The monitoring system for the landfill is shown on Figure 2. A summary of monitoring well
construction information is presented in Table 1. Monitoring wells BC-23A and BC-28 are
considered to represent background groundwater quality according to the Water Quality
Monitoring Plan. The groundwater monitoring locations are sampled on a semi-annual basis and
the results compared to groundwater quality standards found in 15A NCAC .02L .0202 (g) (2L
Standards).
Observation well BC-7 is used for water level measurements only. Monitoring wells are used to
monitor groundwater quality and to measure groundwater levels.
SW-1 is a groundwater seep located to the east of well BC-28. When water is present, it
emanates from the ground just above the sampling location. SW-1 analytical results are
compared to 2L Standards. This surface water feature drains to Belews Lake.

2 BC-25 and BC-27 were converted (June 2015) to stick-up wells in an effort to reduce TDS and obtain
better samples. 3 Monitoring well BC-32 was installed in August 2013 as part of a groundwater assessment being
conducted at the landfill. The monitoring well is not included in the Water Quality Monitoring Plan, but the analytical results from the well are included in this landfill groundwater monitoring report.
Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
November 2016 Sampling Event
SECTION 2 – METHODS

3
Section 2 – Methods
2.1 Sampling and Analysis Methods
Groundwater sampling and documentation of sampling activities were performed by Duke
Energy personnel (Duke Energy Carolinas Field Certification #5193) in accordance with the
North Carolina Solid Waste Management Guidelines. Copies of the field sampling forms are
included in Appendix A. The parameters and constituents sampled were selected by Duke
Energy and the NCDEQ Division of Solid Waste and were analyzed by the Duke Energy
Analytical Laboratory (North Carolina Laboratory Certification #248) and provided to HDR by
Duke Energy. The laboratory report and chain-of-custody forms are included in Appendix B.
The groundwater samples were analyzed using the following analytical methods:
 Barium, boron, chromium, copper, iron, manganese, nickel, silver, and zinc using
Environmental Protection Agency (EPA) Solid Waste (SW)-8464 - Method 6010D
 Arsenic, cadmium, lead, and selenium by EPA SW-846 - Method 6020B
 Chloride, fluoride, nitrate as nitrogen, and sulfate using EPA SW-846 - Method 9056A
 Mercury using EPA SW-846 - Method 7470A
 Total Dissolved Solids using Standard Method (SM) 2540C
2.2 Statement of Work
HDR completed the following tasks:
 Received field sampling information provided by Duke Energy (performed by Duke
Energy personnel) for monitoring wells BC-20, BC-21, BC-22, BC-23A, BC-25, BC-26,
BC-27, BC-28, BC-29, BC-30, BC-31, BC-32, surface water sampling location SW-1,
and the leachate sampling location. Groundwater elevation measurements were not
gauged at BC-27 and BC-29 as the water level in these wells was below their pumps.
The samplers were did not remove the pumps as to avoid contaminating the
groundwater samples. The samples were collected on November 3, 2016, and HDR
received the data on November 21, 2016.
 Reviewed the laboratory analytical results for the samples noted above. The Electronic
Data Deliverable (EDD) provided by Duke Energy was adapted to conform to the format
requirements of the NCDEQ EDD template. HDR added an italicized J data qualifier (J)
to indicate a detected concentration that equals or is greater than the laboratory’s
method reporting limit (MRL), but less than the Solid Waste Section Limit5 (SWSL), and
4 EPA Hazardous Waste Test Methods (SW-846); available online at https://www.epa.gov/hw-sw846
(Accessed July 1, 2016)
5 The Solid Waste Section Limit (SWSL) is defined by NCDEQ as the lowest amount of analyte in a
sample that can be quantitatively determined with suitable precision and accuracy. The SWSL is the
Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
November 2016 Sampling Event
SECTION 2 – METHODS

4
retained the laboratory-supplied qualifier J to indicate values that equal or are greater
than the laboratory’s method detection limit (MDL) but are less than the MRL. A copy of
the original EDD is retained in HDR’s files.
 Developed a generalized groundwater surface contour map using map data and
groundwater elevation data supplied by Duke Energy.
 Prepared and submitted this Semiannual Groundwater Monitoring Report to Duke
Energy.
concentration below which reported results must be qualified as estimated. NCDEQ Division of Waste
Management Memorandum dated February 23, 2007.
Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
November 2016 Sampling Event
SECTION 3 – RESULTS

5
Section 3 – Results
3.1 Site Groundwater Flow
Generalized groundwater surface contours and groundwater flow direction arrows for the site
are shown on Figure 3. These contours were developed using groundwater elevations
measured at the wells on the date of sampling. Calculated groundwater flow velocities are
presented in Table 2.
Based on the groundwater elevations measured at the wells on the date of sampling,
groundwater flow in the area of the landfill is generally from areas of higher topography, located
to the east of the landfill, to the west and to the northwest of the landfill, towards Belews Lake.
3.2 Analytical Results
A summary of the field data is presented in Table 3.
The field and analytical results of groundwater and surface water sampling are summarized in
Table 4. The analysis results for these locations are compared to the 2L Standards.
Concentrations with values that attain or exceed the 2L Standards are noted on Table 4 by bold
font. A summary of the analytical results that attain or exceed the 2L Standards and a
preliminary analysis of the cause and significance of the exceedances are presented in Table 5.
The field and analytical results of leachate sampling are summarized in Table 6.
Concentrations with values that equal or are greater than the SWSLs are noted in Tables 4 and
6 by gray-shaded cells.
Selected samples were diluted as is normal laboratory practice to bring samples to the
calibrated range of the analysis. Specifics regarding the samples that were diluted, including the
dilution amount, are reported in the EDD and the laboratory report.
HDR previously prepared and submitted an assessment to NCDEQ for exceedances of 2L
Standards at this landfill (Groundwater Assessment Belews Creek Steam Station FGD Residue
Landfill, Permit No. 8505. October 5, 2012).
The report assessed the exceedances of the 2L Standards at wells BC-20, BC-21, BC-23A,
BC-26, BC-27, BC-29, and BC-31, and at surface water sampling location SW-1. For the period
of analytical results, the assessment report concluded the following:
 The source of iron exceedances reported in BC-20, BC-21, BC-23A, BC-26, BC-27,
BC-29, and BC-31 appear to be related to turbidity introduced from naturally occurring
sources.
 The source of manganese exceedances reported in BC-27 appears to be related to
turbidity introduced from naturally occurring sources.
 The manganese results at BC-21 do not appear to be related to turbidity.
Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
November 2016 Sampling Event
SECTION 3 – RESULTS

6
 The iron and manganese exceedances at surface water sampling location SW-1 are
from naturally occurring sources and are not related to impacts from the landfill.
The report assessed 2L Standard exceedances for iron, sulfate, and total dissolved solids (TDS)
at monitoring well BC-25. HDR recommended installing an additional monitoring well at the
review boundary between BC-25 and the landfill to further delineate the sulfate and TDS
concentrations in this area and improve the understanding of groundwater flow and quality near
BC-25. HDR further recommended that BC-20 and BC-21 be re-sampled when the new
monitoring well was sampled.
In a letter dated November 28, 2012,6 to Mr. Ed Sullivan, P.E., of Duke Energy, the NCDEQ
Solid Waste Section approved the recommendations presented in the groundwater assessment
report dated October 5, 2012.
Monitoring well BC-32 was installed in August 2013, and HDR prepared and submitted a
supplemental groundwater assessment to NCDEQ (Supplemental Groundwater Assessment
Belews Creek Steam Station FGD Residue Landfill, Permit No. 8505. June 4, 2014).
The supplemental groundwater assessment report indicated:
 Although it is not possible to eliminate leakage through the liner system as a cause for
2L Standard exceedances, leakage through the liner system is not the likely source of 2L
Standard exceedances.
 Increases in precipitation runoff received by non-contact stormwater basins SB-6 and
SB-7, due to the process of filling Cell 1, may have caused deposited FGD residue to be
subjected to increased infiltration into the groundwater at these basins. It appears that
an increase in surface runoff and infiltration of gypsum into the groundwater in this area
may be the source of exceedances of sulfate, TDS, and selenium.
As part of the supplemental groundwater assessment report HDR recommended:
 Monitoring well BC-32 should continue to be sampled as part of the groundwater
monitoring program for the FGD Residue Landfill.
 If concentrations of sulfate and TDS decrease to below the 2L Standard in monitoring
wells BC-25 and BC-32 and remain below the 2L Standard for a minimum of two
sampling events, discontinue groundwater monitoring at BC-25 and incorporate
monitoring well BC-32 into the groundwater monitoring program for the FGD Residue
Landfill.
 If the concentrations of sulfate and TDS remain above the 2L Standards in monitoring
wells BC-25 and BC-32 for the next three sampling events, an additional assessment
should be conducted to identify the sources of the exceedances.
6 North Carolina Department of Environment and Natural Resources, Division of Waste Management.
November 28, 2012, Groundwater Assessment Report Response. Duke Energy – Belews Creek FGD Landfill, DOC ID 17761.
Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
November 2016 Sampling Event
SECTION 3 – RESULTS

7
This is the fifth groundwater monitoring event since the completion of the supplemental
groundwater assessment (November 2014, May 2015, November 2015, May 2016, and
November 2016).
The sulfate and TDS concentrations in monitoring wells BC-25 and BC-32 have been greater
than the 2L Standards since the supplemental groundwater assessment. The concentrations of
these parameters have been decreasing in BC-25 from highs of 1,190,000 µg/L (sulfate) and
1,810,000 µg/L (TDS) in November 2015 and May 2016, respectively. In BC-32, sulfate has
slightly increased from the prior sampling event in May 2016 (949,000 µg/L to 954,000 µg/L)
and TDS has decreased from the May 2016 sampling event from 1,380,000 µg/L to 1,330,000
µg/L.
Since the supplemental assessment, sulfate concentrations in BC-20 have been above the 2L
standard of 250 mg/L.
The selenium concentration in BC-21 was measured above the 2L standard in August 2013 but
below the standard in all events before and after that event.
The sulfate concentration measured in monitoring well BC-21 has been greater than the 2L
Standard in all sampling events since the supplemental assessment.
Selenium in BC-25 has been measured at concentrations greater than the 2L standard of 20
µg/L during both May and November 2015 sampling events (at 20.3 µg/L and 21.9 µg/L,
respectively). However, in both sampling events since May 2016, the selenium concentration
has remained below 2L at 12.4 and 9.7 µg/L, respectively.
Duke Energy submitted an additional assessment workplan7 which was subsequently approved
by DEQ on September 7, 2016. Assessment activities are currently underway in accordance
with the approved work plan.
7 Additional Assessment of Groundwater Exceedances, BCSS FGD Residue Landfill, Permit No. 8505.

Figures

#UJ$CUKP
ASH LANDFILL
PERMIT NO.
8503
FGD
LANDFILL
PERMIT NO.
8505
%TCKI4QCF
CRAIG ROAD
LANDFILL
PERMIT NO.
8504
'CUV$GNGYU
%TGGM#TO

$GNGYU.CMG
9GUV$GNGYU
%TGGM#TO

$GNGYU.CMG
$GNGYU%TGGM5VGCO5VCVKQP
.CPFHKNN$QWPFCT[
1000 2000
5%#.'
(''6
0 1000
0QVGU
5QWTEG75)56QRQITCRJKE/CRÄ$GNGYU.CMG
3WCFTCPING%TGCVGF4GXKUGF
6QRQITCRJKEOCRFQGUPQVTGHNGEVTGCNKIPOGPVQH%TCKI
4QCF
DATE
FIGURE
SITE LOCATION MAP
BELEWS CREEK STEAM STATION
FGD RESIDUE LANDFILL
PERMIT NO. 8505
JANUARY 2017
1
HDR Engineering Inc.
440 S. Church St. Suite 1000
Charlotte, NC 28202-2075
704.338.6700
of the Carolinas
5
%
#
.
'


(
'
'
6

1
0
0
0
1
0
0
2
0
0
0QVG$CUG/CR2TQXKFGFD[&WMG'PGTI[%CTQNKPCU..%&CVGF/C[
S
A
M
P
L
E

L
O
C
A
T
I
O
N
S
B
E
L
E
W
S

C
R
E
E
K

S
T
E
A
M

S
T
A
T
I
O
N
F
G
D

R
E
S
I
D
U
E

L
A
N
D
F
I
L
L
P
E
R
M
I
T

N
O
.

8
5
0
5
J
A
N
U
A
R
Y

2
0
1
7
2
H
D
R

E
n
g
i
n
e
e
r
i
n
g

I
n
c
.
4
4
0

S
.

C
h
u
r
c
h

S
t
.

S
u
i
t
e

1
0
0
0
C
h
a
r
l
o
t
t
e
,

N
C

2
8
2
0
2
-
2
0
7
5
7
0
4
.
3
3
8
.
6
7
0
0
o
f

t
h
e

C
a
r
o
l
i
n
a
s
D
A
T
E
F
I
G
U
R
E
5
%
#
.
'


(
'
'
6

1
0
0
0
1
0
0
2
0
0
G
E
N
E
R
A
L
I
Z
E
D

G
R
O
U
N
D
W
A
T
E
R

S
U
R
F
A
C
E
C
O
N
T
O
U
R
S

-

N
O
V
E
M
B
E
R

2
0
1
6
B
E
L
E
W
S

C
R
E
E
K

S
T
E
A
M

S
T
A
T
I
O
N
P
E
R
M
I
T

N
O
.

8
5
0
5
J
A
N
U
A
R
Y

2
0
1
7
3
H
D
R

E
n
g
i
n
e
e
r
i
n
g

I
n
c
.
4
4
0

S
.

C
h
u
r
c
h

S
t
.

S
u
i
t
e

1
0
0
0
C
h
a
r
l
o
t
t
e
,

N
C

2
8
2
0
2
-
2
0
7
5
7
0
4
.
3
3
8
.
6
7
0
0
o
f

t
h
e

C
a
r
o
l
i
n
a
s
D
A
T
E
F
I
G
U
R
E
F
G
D

R
E
S
I
D
U
E

L
A
N
D
F
I
L
L
0QVGU$CUG/CR2TQXKFGFD[&WMG'PGTI[%CTQNKPCU..%&CVGF/C[)TQWPFYCVGT'NGXCVKQPU/GCUWTGFQP0QXGODGT

Tables

Ta
b
l
e

1

-

W
e
l
l

C
o
n
s
t
r
u
c
t
i
o
n

I
n
f
o
r
m
a
t
i
o
n
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s

L
L
C
/
B
e
l
e
w
s

C
r
e
e
k

S
t
e
a
m

S
t
a
t
i
o
n
FG
D

R
e
s
i
d
u
e

L
a
n
d
f
i
l
l
,

P
e
r
m
i
t

N
o
.

8
5
0
5
La
t
i
t
u
d
e

L
o
n
g
i
t
u
d
e
BC
-
7

1
1
/
2
1
/
2
0
0
2

3
6
.
2
7
3
0
7
8
7

-
8
0
.
0
5
8
8
0
0
1

7
7
7
.
8
0

7
7
5
.
7
8

2
.
0
2

7
3
9
.
9
0

3
7
.
9
0

5
2
.
3
0

3
7
.
3
0

3
7
.
3
0

-

5
2
.
3
0

B
e
d
r
o
c
k

2

P
V
C
BC
-
2
0

8
/
3
1
/
2
0
0
4

3
6
.
2
7
5
9
4
6
7

-
8
0
.
0
5
7
9
8
5
2

7
5
7
.
2
2

7
5
4
.
5
8

2
.
6
4

7
4
0
.
0
8

1
7
.
1
4

2
4
.
2
2

1
4
.
2
2

1
4
.
2
2

-

2
4
.
2
2

S
a
p
r
o
l
i
t
e
/
P
W
R

2

P
V
C
BC
-
2
1

9
/
1
/
.
2
0
0
4

3
6
.
2
7
6
2
6
6
1

-
8
0
.
0
5
6
3
0
6
8

7
5
6
.
6
9

7
5
3
.
4
2

3
.
2
7

7
4
3
.
8
7

1
2
.
8
2

1
6
.
7
7

6
.
7
7

6
.
7
7

-

1
6
.
7
7

S
a
p
r
o
l
i
t
e

2

P
V
C
BC
-
2
2

9
/
2
/
2
0
0
4

3
6
.
2
7
6
1
2
5
8

-
8
0
.
0
5
4
6
2
5
5

7
6
5
.
9
1

7
6
3
.
7
2

2
.
1
9

7
6
0
.
8
5

5
.
0
6

1
3
.
0
0

3
.
0
0

3
.
0
0

-

1
3
.
0
0

S
a
p
r
o
l
i
t
e

2

P
V
C
BC
-
2
3
A

9
/
2
/
2
0
0
4

3
6
.
2
7
4
7
3
2
6

-
8
0
.
0
5
3
8
3
7
3

8
6
3
.
7
9

8
6
2
.
5
6

1
.
2
3

7
8
5
.
2
3

7
8
.
5
6

1
0
1
.
2
1

7
6
.
2
1

7
6
.
2
1

-

1
0
1
.
2
1

P
W
R
/
B
e
d
r
o
c
k 2

P
V
C
BC
-
2
5

2
/
2
1
/
2
0
0
6

3
6
.
2
7
6
0
9
1
1

-
8
0
.
0
5
9
0
9
1
0

7
4
8
.
4
3

7
4
5
.
9
8

2
.
4
5

7
3
1
.
2
9

1
7
.
1
4

2
3
.
1
5

8
.
1
5

8
.
1
5

-

2
3
.
1
5

S
a
p
r
o
l
i
t
e
/
P
W
R

2

P
V
C
BC
-
2
6

2
/
1
7
/
2
0
0
6

3
6
.
2
7
5
1
0
2
2

-
8
0
.
0
5
9
5
3
6
1

7
4
9
.
3
2

7
4
7
.
2
1

2
.
1
1

7
3
1
.
8
1

1
7
.
5
1

2
3
.
2
6

8
.
2
6

8
.
2
6

-

2
3
.
2
6

S
a
p
r
o
l
i
t
e

2

P
V
C
BC
-
2
7

2
/
2
0
/
2
0
0
6

3
6
.
2
7
4
2
8
1
6

-
8
0
.
0
5
9
5
7
0
6

7
6
4
.
7
8

7
6
1
.
9
6

2
.
8
2

S
E
E

N
O
T
E

1
2

S
E
E

N
O
T
E

1
2

3
4
.
9
5

1
9
.
9
5

1
9
.
9
5

-

3
4
.
9
5

S
a
p
r
o
l
i
t
e

2

P
V
C
BC
-
2
8

2
/
1
5
/
2
0
0
6

3
6
.
2
7
2
5
9
1
6

-
8
0
.
0
5
5
8
4
3
9

8
1
8
.
0
9

8
1
6
.
0
2

2
.
0
7

7
6
8
.
9
0

4
9
.
1
9

6
0
.
2
0

4
5
.
2
0

4
5
.
2
0

-

6
0
.
2
0

S
a
p
r
o
l
i
t
e
/
P
W
R
/
B
R

2

P
V
C
BC
-
2
9

1
0
/
2
9
/
2
0
0
7

3
6
.
2
7
3
7
8
3
6

-
8
0
.
0
5
8
9
6
2
5

7
5
3
.
1
8

7
5
1
.
4
1

1
.
7
7

S
E
E

N
O
T
E

1
2

S
E
E

N
O
T
E

1
2

2
2
.
3
0

7
.
3
0

7
.
3
0

-

2
2
.
3
0

S
a
p
r
o
l
i
t
e

2

P
V
C
BC
-
3
0

1
0
/
2
9
/
2
0
0
7

3
6
.
2
7
2
9
6
1
2

-
8
0
.
0
5
7
9
1
3
4

7
7
5
.
7
2

7
7
3
.
9
1

1
.
8
1

7
4
7
.
9
1

2
7
.
8
1

3
4
.
1
0

1
9
.
1
0

1
9
.
1
0

-

3
4
.
1
0

S
a
p
r
o
l
i
t
e
/
P
W
R

2

P
V
C
BC
-
3
1

1
0
/
3
0
/
2
0
0
7

3
6
.
2
7
3
4
8
5
0

-
8
0
.
0
5
5
2
5
7
3

8
1
6
.
4
0

8
1
3
.
4
3

2
.
9
7

7
5
7
.
6
8

5
8
.
7
2

8
3
.
3
0

6
3
.
3
0

6
3
.
3
0

-

8
3
.
3
0

P
W
R
/
B
e
d
r
o
c
k 2

P
V
C
BC
-
3
2

8
/
1
2
/
2
0
1
3

3
6
.
2
7
5
6
7
5
7

-
8
0
.
0
5
8
9
0
4
1

7
5
6
.
5
6

7
5
3
.
6
2

2
.
9
4

7
3
9
.
0
2

1
7
.
5
4

3
3
.
0
1

1
8
.
0
1

1
8
.
0
1

-

3
3
.
0
1

S
a
p
r
o
l
i
t
e
/
P
W
R

2

P
V
C
No
t
e
s
:
1
.

T
O
C

i
n
d
i
c
a
t
e
s

t
o
p

o
f

c
a
s
i
n
g
.
2
.

f
t
.

i
n
d
i
c
a
t
e
s

f
e
e
t
.
3
.

i
n
.

i
n
d
i
c
a
t
e
s

i
n
c
h
e
s

n
o
m
i
n
a
l

d
i
a
m
e
t
e
r
.
4
.

P
V
C

i
n
d
i
c
a
t
e
s

p
o
l
y
v
i
n
y
l

c
h
l
o
r
i
d
e
.
5
.

P
W
R

i
n
d
i
c
a
t
e
s

p
a
r
t
i
a
l
l
y

w
e
a
t
h
e
r
e
d

r
o
c
k
.
6
.

B
R

i
n
d
i
c
a
t
e
s

b
e
d
r
o
c
k
.
7
.

H
o
r
i
z
o
n
t
a
l

d
a
t
u
m

a
s
s
u
m
e
d

t
o

b
e

N
A
D
8
3
.
8
.

E
l
e
v
a
t
i
o
n
s

b
a
s
e
d

o
n

N
V
G
D

2
9

v
e
r
t
i
c
a
l

d
a
t
u
m
.
9
.

M
o
n
i
t
o
r
i
n
g

w
e
l
l
s

B
C
-
2
5

a
n
d

B
C
-
2
7

w
e
r
e

o
r
i
g
i
n
a
l
l
y

f
l
u
s
h
-
m
o
u
n
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l
s
,

b
u
t

w
e
r
e

c
o
n
v
e
r
t
e
d

t
o

s
t
i
c
k
-
u
p

w
e
l
l
s

i
n

J
u
n
e 2
0
1
5
.
10
.

B
C
-
3
2

w
a
s

o
r
i
g
i
n
a
l
l
y

s
u
r
v
e
y
e
d

i
n

N
A
V
D

8
8

v
e
r
t
i
c
a
l

d
a
t
u
m
.

E
l
e
v
a
t
i
o
n

p
r
e
s
e
n
t
e
d

i
n

t
a
b
l
e

w
a
s

c
o
n
v
e
r
t
e
d

t
o

N
V
G
D

2
9

v
e
r
t
i
c
a
l

d
at
u
m
.
11
.

D
e
p
t
h

t
o

g
r
o
u
n
d
w
a
t
e
r

w
a
s

m
e
a
s
u
r
e
d

o
n

N
o
v
e
m
b
e
r

3
,

2
0
1
6
.
12
.

G
r
o
u
n
d
w
a
t
e
r

a
t

B
C
-
2
7

a
n
d

B
C
-
2
9

c
o
u
l
d

n
o
t

b
e

m
e
a
s
u
r
e
d

a
s

t
h
e

i
n
i
t
i
a
l

w
a
t
e
r

l
e
v
e
l

w
a
s

b
e
l
o
w

t
o
p

o
f

p
u
m
p
.
13
.

I
n
f
o
r
m
a
t
i
o
n

p
r
o
v
i
d
e
d

b
y

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

o
n

N
o
v
e
m
b
e
r

2
9
,

2
0
1
6
.
We
l
l

S
t
i
c
k
-
u
p

He
i
g
h
t

A
b
o
v
e

Gr
o
u
n
d

S
u
r
f
a
c
e

(ft
.
)
We
l
l

I
D
We
l
l

In
s
t
a
l
l
a
t
i
o
n

Da
t
e
Co
o
r
d
i
n
a
t
e
s
TO
C

El
e
v
a
t
i
o
n

(
f
t
.
)
Gr
o
u
n
d

S
u
r
f
a
c
e

El
e
v
a
t
i
o
n
(f
t
.
)
Gr
o
u
n
d
w
a
t
e
r

Ele
v
a
t
i
o
n
(f
t
.
)
De
p
t
h

t
o

W
a
t
e
r

be
l
o
w

T
O
C
(ft
.
)
To
t
a
l

W
e
l
l

De
p
t
h

b
e
l
o
w

TO
C
(f
t
.
)
De
p
t
h

t
o

T
o
p

o
f

Sc
r
e
e
n

f
r
o
m

T
O
C
(f
t
.
)
Casing TypeWell Diameter (in.)Geology of Screened Interval
Sc
r
e
e
n
e
d

I
n
t
e
r
v
a
l

be
l
o
w

T
O
C
(f
t
.
)
Page  1  of  1
Ta
b
l
e

2

-

G
r
o
u
n
d
w
a
t
e
r

F
l
o
w

V
e
l
o
c
i
t
i
e
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s

L
L
C
/
B
e
l
e
w
s

C
r
e
e
k

S
t
e
a
m

S
t
a
t
i
o
n
FG
D

R
e
s
i
d
u
e

L
a
n
d
f
i
l
l
,

P
e
r
m
i
t

N
o
.

8
5
0
5
BC
-
7

7
4
0
.
0
0

7
3
9
.
9
0

3
5

0
.
0
0
3

0
.
3
1
0

0
.
0
0
5

0
.
1
8
BC
-
2
0

7
4
5
.
0
0

7
4
0
.
0
0

1
6
9

0
.
0
3
0

0
.
4
1
1

0
.
2
5
9

0
.
0
5
BC
-
2
1

7
4
5
.
0
0

7
4
3
.
8
7

3
7

0
.
0
3
1

0
.
4
1
1

0
.
2
5
9

0
.
0
5
BC
-
2
2

7
6
5
.
0
0

7
6
0
.
0
0

9
5

0
.
0
5
3

0
.
4
1
1

0
.
2
5
9

0
.
0
8
BC
-
2
3
A

7
8
5
.
2
3

7
8
5
.
0
0

1
3

0
.
0
1
8

0
.
3
1
0

0
.
0
0
5

1
.
1
2
BC
-
2
5

7
3
5
.
0
0

7
3
1
.
2
9

4
8

0
.
0
7
7

0
.
4
1
1

0
.
2
5
9

0
.
1
2
BC
-
2
6

7
3
5
.
0
0

7
3
1
.
8
1

6
1

0
.
0
5
2

0
.
4
1
1

0
.
2
5
9

0
.
0
8
BC
-
2
7

S
E
E

N
O
T
E

1
0

S
E
E

N
O
T
E

1
0

S
E
E

N
O
T
E

1
0

S
E
E

N
O
T
E

1
0

0
.
4
1
1

0
.
2
5
9

S
E
E

N
O
T
E

1
0
BC
-
2
8

7
6
8
.
9
0

7
6
5
.
0
0

5
1

0
.
0
7
6

0
.
4
1
1

0
.
2
5
9

0
.
1
2
BC
-
2
9

S
E
E

N
O
T
E

1
0

S
E
E

N
O
T
E

1
0

S
E
E

N
O
T
E

1
0

S
E
E

N
O
T
E

1
0

0
.
4
1
1

0
.
2
5
9

S
E
E

N
O
T
E

1
0
BC
-
3
0

7
5
0
.
0
0

7
4
5
.
0
0

2
1
8

0
.
0
2
3

0
.
4
1
1

0
.
2
5
9

0
.
0
4
BC
-
3
1

7
5
7
.
6
8

7
5
5
.
0
0

1
0
2

0
.
0
2
6

0
.
3
1
0

0
.
0
0
5

1
.
6
3
BC
-
3
2

7
4
0
.
0
0

7
3
5
.
0
0

1
0
4

0
.
0
4
8

0
.
4
1
1

0
.
2
5
9

0
.
0
8
No
t
e
s
:
1
.

L
i
n
e
a
r

d
i
s
t
a
n
c
e

m
e
a
s
u
r
e
d

t
h
r
o
u
g
h

m
o
n
i
t
o
r
i
n
g

w
e
l
l
s
is

a
p
p
r
o
x
i
m
a
t
e
l
y

p
e
r
p
e
n
d
i
c
u
l
a
r

t
o

g
r
o
u
n
d
w
a
t
e
r

c
o
n
t
o
u
r
s
.
2
.

A
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l

l
o
c
a
t
i
o
n
s

w
h
e
r
e

d
o
w
n
g
r
a
d
i
e
n
t

c
o
n
t
o
u
r
s

a
r
e

n
o
t

p
r
e
s
e
n
t
,

t
h
e

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

a
t

t
h
e

m
o
n
i
t
o
r
i
n
g

w
e
l
l

i
s

u
s
e
d

a
s

t
h
e

d
o
w
n
g
r
a
d
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n
.
3
.

A
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l

l
o
c
a
t
i
o
n
s

w
h
e
r
e

u
p
g
r
a
d
i
e
n
t

c
o
n
t
o
u
r
s

a
r
e

n
o
t

p
r
e
s
e
n
t
,

t
h
e

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

a
t

t
h
e

m
o
n
i
t
o
r
i
n
g

w
e
l
l

i
s

u
s
e
d

a
s

t
h
e

u
p
g
r
a
d
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n
.
4
.

M
o
n
i
t
o
r
i
n
g

w
e
l
l
s

a
r
e

n
o
t

l
i
s
t
e
d

w
h
e
r
e

i
n
s
u
f
f
i
c
i
e
n
t

i
n
f
o
r
m
a
t
i
o
n

i
s

a
v
a
i
l
a
b
l
e

t
o

c
a
l
c
u
l
a
t
e

v
e
l
o
c
i
t
y
.
5
.

H
y
d
r
a
u
l
i
c

g
r
a
d
i
e
n
t
s

a
n
d

g
r
o
u
n
d
w
a
t
e
r

v
e
l
o
c
i
t
i
e
s

a
r
e

a
p
p
r
o
x
i
m
a
t
e
.
6
.

H
y
d
r
a
u
l
i
c

c
o
n
d
u
c
t
i
v
i
t
y

p
r
e
s
e
n
t
e
d

f
o
r

t
h
e

a
l
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e

h
y
d
r
o
s
t
r
a
t
i
g
r
a
p
h
i
c

l
a
y
e
r

i
s

t
h
e

g
e
o
m
e
t
r
i
c

m
e
a
n

o
f

t
h
e

c
o
n
du
c
t
i
v
i
t
y

d
a
t
a

i
n

t
h
e

H
D
R

C
o
n
d
u
c
t
i
v
i
t
y

D
a
t
a
b
a
s
e

(
u
n
p
u
b
l
i
s
h
e
d

d
a
t
a

f
r
o
m

P
i
e
d
m
o
n
t

C
a
r
o
l
i
n
a

s
i
t
e
s

w
i
t
h

f
o
l
i
a
t
e
d
/
l
a
y
e
r
e
d

b
e
d
r
o
c
k
)
.
7
.

H
y
d
r
a
u
l
i
c

c
o
n
d
u
c
t
i
v
i
t
y

p
r
e
s
e
n
t
e
d

f
o
r

t
h
e

b
e
d
r
o
c
k

l
a
y
e
r

i
s

t
h
e

g
e
o
m
e
t
r
i
c

m
e
a
n

o
f

t
h
e

c
o
n
d
u
c
t
i
v
i
t
y

d
a
t
a

i
n

t
h
e

H
D
R

C
o
n
d
u
c
t
i
v
i
t
y

D
a
t
a
b
a
s
e

(
u
n
p
u
b
l
i
s
h
e
d

d
a
t
a

f
r
o
m

P
i
e
d
m
o
n
t

C
a
r
o
l
i
n
a

s
i
t
e
s

w
i
t
h

f
o
l
i
a
t
e
d
/
l
a
y
e
r
e
d

b
e
d
r
o
c
k
)
.
8
.

E
f
f
e
c
t
i
v
e

p
o
r
o
s
i
t
y

p
r
e
s
e
n
t
e
d

f
o
r

t
h
e

a
l
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e

h
y
d
r
o
s
t
r
a
t
i
g
r
a
p
h
i
c

l
a
y
e
r

i
s

t
h
e

m
e
a
n

v
a
l
u
e

e
s
t
i
m
a
t
e
d

f
r
o
m

g
r
ai
n

s
i
z
e

d
a
t
a

u
s
i
n
g

F
e
t
t
e
r
/
B
e
a
r

D
i
a
g
r
a
m
s
.

9
.

E
f
f
e
c
t
i
v
e

p
o
r
o
s
i
t
y

f
o
r

t
h
e

b
e
d
r
o
c
k

l
a
y
e
r

i
s

b
a
s
e
d

o
n

p
u
b
l
i
s
h
e
d

v
a
l
u
e
s
.

10
.

G
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n
s

a
t

B
C
-
2
7

a
n
d

B
C
-
2
9

c
o
u
l
d

n
o
t

b
e

m
e
a
s
u
r
e
d

a
s

t
h
e

g
r
o
u
n
d
w
a
t
e
r

w
a
s

b
e
l
o
w

t
h
e

t
o
p

o
f

t
h
e

i
n
s
t
a
l
l
e
d

b
l
a
d
d
er

p
u
m
p
s
.
11
.

H
y
d
r
a
u
l
i
c

g
r
a
d
i
e
n
t

a
n
d

g
r
o
u
n
d
w
a
t
e
r

v
e
l
o
c
i
t
i
e
s

c
a
l
c
u
l
a
t
e
d

b
a
s
e
d

o
n

g
r
o
u
n
d
w
a
t
e
r

d
e
p
t
h

m
e
a
s
u
r
e
d

o
n

N
o
v
e
m
b
e
r

3
,

2
0
1
6
.
Ef
f
e
c
t
i
v
e

Po
r
o
s
i
t
y

(%
/
1
0
0
)
Gr
o
u
n
d
w
a
t
e
r

Ve
l
o
c
i
t
y

(f
t
/
d
a
y
)
We
l
l

I
D
U
p
g
r
a
d
i
e
n
t

Gr
o
u
n
d
w
a
t
e
r

Co
n
t
o
u
r

El
e
v
a
t
i
o
n
(f
t
)
D
o
w
n
g
r
a
d
i
e
n
t

Gr
o
u
n
d
w
a
t
e
r

Co
n
t
o
u
r

El
e
v
a
t
i
o
n
(f
t
)
Li
n
e
a
r

Dis
t
a
n
c
e

Be
t
w
e
e
n

Co
n
t
o
u
r
s

th
r
o
u
g
h

W
e
l
l
(f
t
)
Hy
d
r
a
u
l
i
c

Gr
a
d
i
e
n
t

(f
t
/
f
t
)
Hy
d
r
a
u
l
i
c

Co
n
d
u
c
t
i
v
i
t
y

(f
t
/
d
a
y
)
Page 1 of 1
Ta
b
l
e

3

-

F
i
e
l
d

D
a
t
a

P
a
r
a
m
e
t
e
r
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s

L
L
C
/
B
e
l
e
w
s

C
r
e
e
k

S
t
e
a
m

S
t
a
t
i
o
n
FG
D

R
e
s
i
d
u
e

L
a
n
d
f
i
l
l
,

P
e
r
m
i
t

N
o
.

8
5
0
5
11
/
3
/
2
0
1
6

B
C
-
7

5
2
.
3
0

3
7
.
9

7
3
9
.
9
0

N
/
A

N
/
A

L
O

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A
11
/
3
/
2
0
1
6

B
C
-
2
0

2
4
.
2
2

1
7
.
1
4

7
4
0
.
0
8

N
o
r
m
a
l

N
o
n
e

L
F
21
0

1
.
1
5

1
.
1

N
/
A

1
9
.
7
9

1
,
0
1
5

5
.
3

1
4

3
7
8

8
.
0
5
11
/
3
/
2
0
1
6

B
C
-
2
1

1
6
.
7
7

1
2
.
8
2

7
4
3
.
8
7

N
o
r
m
a
l

N
o
n
e

E
O
P

N
/
A

0
.
6
4

0
.
2
2

N
/
A

1
9
.
9
9

8
5
3

5
.
1

1
8
.
1

4
0
9

6
.
0
6
11
/
3
/
2
0
1
6

B
C
-
2
2

1
3
.
0
0

5
.
0
6

7
6
0
.
8
5

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
3
0

4
.
5
0

N
O

1
7
.
4
6

2
3
5

5
.
5

2
.
3

3
8
7

5
.
1
0
11
/
3
/
2
0
1
6

B
C
-
2
3
A

1
0
1
.
2
1

7
8
.
5
6

7
8
5
.
2
3

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

3
.
6
9

8
.
2
5

N
O

1
5
.
4
3

4
4

5
.
8

1
5
.
1

3
8
2

7
.
9
6
11
/
3
/
2
0
1
6

B
C
-
2
5

2
6
.
1
5

1
7
.
1
4

7
3
1
.
2
9

N
o
r
m
a
l

N
o
n
e

L
F
20
0

1
.
4
7

1
.
3
0

N
/
A

2
0
.
5
5

1
,
5
5
9

5
.
3

1
2
.
2

3
3
3

3
.
1
4
11
/
3
/
2
0
1
6

B
C
-
2
6

2
3
.
2
6

1
7
.
5
1

7
3
1
.
8
1

N
o
r
m
a
l

N
o
n
e

L
F
27
0

0
.
9
4

2
.
5

N
/
A

1
6
.
6
5

1
8
6

4
.
8

1
2
.
2

3
7
6

3
.
8
3
11
/
3
/
2
0
1
6

B
C
-
2
7

3
8
.
3
3

S
E
E

N
O
T
E

1
2

S
E
E

N
O
T
E

1
2

N
o
r
m
a
l

N
o
n
e

L
F
12
0

S
E
E

N
O
T
E

1
2

0
.
7
5

N
/
A

1
9
.
6
5

1
1
6

5
.
2

4
.
8

2
6
4

1
.
6
9
11
/
3
/
2
0
1
6

B
C
-
2
8

6
0
.
2
0

4
9
.
1
9

7
6
8
.
9
0

N
o
r
m
a
l

N
o
n
e

L
F
15
0

1
.
8
0

0
.
9

N
/
A

1
6
.
4
1

5
5

5
.
6

1
2
.
2

3
6
1

7
.
5
7
11
/
3
/
2
0
1
6

B
C
-
2
9

2
5
.
3
2

S
E
E

N
O
T
E

1
2

S
E
E

N
O
T
E

1
2

N
o
r
m
a
l

N
o
n
e

L
F
18
0

S
E
E

N
O
T
E

1
2

1
.
2
5

N
/
A

1
6
.
7
3

7
0

5
.
2

5
.
8

3
7
5

2
.
4
6
11
/
3
/
2
0
1
6

B
C
-
3
0

3
4
.
1
0

2
7
.
8
1

7
4
7
.
9
1

N
o
r
m
a
l

N
o
n
e

L
F
18
0

1
.
0
3

2
.
0
0

N
/
A

1
4
.
8

6
8

5
.
7

3
.
7

3
5
6

7
.
5
6
11
/
3
/
2
0
1
6

B
C
-
3
1

8
3
.
3
0

5
8
.
7
2

7
5
7
.
6
8

N
o
r
m
a
l

N
o
n
e

L
F
14
0

4
.
0
1

1
.
6
5

N
/
A

1
7
.
2
4

1
1
7

6
.
0

1
.
7

2
8
5

5
.
2
5
11
/
3
/
2
0
1
6

B
C
-
3
2

3
3
.
0
1

1
7
.
5
4

7
3
9
.
0
2

N
o
r
m
a
l

N
o
n
e

L
F
24
0

2
.
5
2

1
.
1
5

N
/
A

1
7
.
5

1
,
5
6
9

5
.
3

2
.
2

3
9
2

5
.
7
4
11
/
3
/
2
0
1
6

B
C
-
S
W
1

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

1
5
.
9

1
4
6

7
.
5

6
.
6

2
0
4

9
.
1
9
11
/
3
/
2
0
1
6

B
C
-
L
E
A
C
H
A
T
E

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

1
7
.
3
4

2
,
8
6
7

6
.
4

0
.
9

3
5
0

6
.
5
1
No
t
e
s
:
1
.

P
u
r
g
e

M
e
t
h
o
d
s
;

L
F
=
L
o
w

F
l
o
w
,

C
P
=
C
o
n
v
e
n
t
i
o
n
a
l

P
u
r
g
e

(
3
-
5

w
e
l
l

v
o
l
u
m
e
s
)
,

N
P
=
N
o

P
u
r
g
e

(
H
y
d
r
a
S
l
e
e
v
e
)
,

L
O
=
L
e
v
e
l

O
n
l
y
.

P
u
m
p

r
a
t
e a
p
p
l
i
c
a
b
l
e

t
o

L
F

p
u
r
g
i
n
g

o
n
l
y
.
2
.

F
i
e
l
d

s
a
m
p
l
i
n
g

p
e
r
f
o
r
m
e
d

b
y

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

p
e
r
s
o
n
n
e
l
.
3
.

E
V
A
C

i
n
d
i
c
a
t
e
s

w
h
e
t
h
e
r

t
h
e

w
a
t
e
r

l
e
v
e
l

i
n

t
h
e

w
e
l
l

w
a
s

d
r
a
w
n

d
o
w
n

t
o

t
h
e

l
e
v
e
l

o
f

t
h
e

p
u
m
p

d
u
r
i
n
g

p
u
r
g
i
n
g
.
4
.

µ
Լ /c
m

i
n
d
i
c
a
t
e
s

m
i
c
r
o
m
h
o
s

p
e
r

c
e
n
t
i
m
e
t
e
r
.
5
.

S
U

i
n
d
i
c
a
t
e
s

S
t
a
n
d
a
r
d

U
n
i
t
s
.
6
.

N
T
U

i
n
d
i
c
a
t
e
s

N
e
p
h
e
l
o
m
e
t
r
i
c

T
u
r
b
i
d
i
t
y

U
n
i
t
s
.
7
.

m
V
-
N
H
E

i
n
d
i
c
a
t
e
s

m
i
l
l
i
v
o
l
t
s
-
N
o
r
m
a
l

H
y
d
r
o
g
e
n

E
l
e
c
t
r
o
d
e
.
8
.

m
L
/
m
i
n

i
n
d
i
c
a
t
e
s

m
i
l
l
i
l
i
t
e
r
s

p
e
r

m
i
n
u
t
e
.
9
.

m
g
/
L

i
n
d
i
c
a
t
e
s

m
i
l
l
i
g
r
a
m
s

p
e
r

l
i
t
e
r
.
10
.

N
/
A

i
n
d
i
c
a
t
e
s

n
o
t

a
p
p
l
i
c
a
b
l
e
.
11
.

O
b
s
e
r
v
a
t
i
o
n

w
e
l
l

B
C
-
7

w
a
s

g
a
u
g
e
d

f
o
r

d
e
p
t
h

t
o

w
a
t
e
r

o
n
l
y
.
12
.

G
r
o
u
n
d
w
a
t
e
r

a
t

B
C
-
2
7

a
n
d

B
C
-
2
9

c
o
u
l
d

n
o
t

b
e

m
e
a
s
u
r
e
d

a
s

t
h
e

i
n
i
t
i
a
l

w
a
t
e
r

l
e
v
e
l

w
a
s

b
e
l
o
w

t
o
p

o
f

p
u
m
p
.
13
.

I
n
f
o
r
m
a
t
i
o
n

p
r
o
v
i
d
e
d

b
y

T
i
m

H
u
n
s
u
c
k
e
r

o
f

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

o
n

N
o
v
e
m
b
e
r

2
9
,

2
0
1
6
.
AP
P
E
A
R
A
N
C
E
DO (mg/L)
OD
O
R
PU
R
G
E
ME
T
H
O
D

PU
M
P

R
A
T
E
(m
L
/
m
i
n
)
WE
L
L
VO
L
U
M
E
(g
a
l
)
EV
A
C
VO
L
U
M
E
(g
a
l
)
EV
A
C
(Y
E
S
/
N
O
)
TE
M
P
(d
e
g

C
)
SP
E
C
I
F
I
C
Co
n
d
u
c
t
a
n
c
e
(µ
Լ /c
m
)
pH (SU)TURBIDITY (NTU)ORP (mV-NHE)
DA
T
E

S
A
M
P
L
E

I
D
WE
L
L
DE
P
T
H
(f
e
e
t
)
DE
P
T
H

T
O
WA
T
E
R
(f
e
e
t
)
WA
T
E
R
EL
E
V
.
(f
e
e
t
)
Page 1 of 1
Ta
b
l
e

4

-

F
i
e
l
d

a
n
d

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s

L
L
C
/
B
e
l
e
w
s

C
r
e
e
k

S
t
e
a
m

S
t
a
t
i
o
n
FG
D

R
e
s
i
d
u
e

L
a
n
d
f
i
l
l
,

P
e
r
m
i
t

N
o
.

8
5
0
5
Fie
l
d

p
H

3
2
0

S
U

5
1
9
3
-

N
E

6
.
5
-
8
.
5

6
.
5
-
8
.
5
*
Fie
l
d

S
p
e
c
i
f
i
c

C
o
n
d
u
c
t
a
n
c
e

3
2
3

µ
Լ /cm

5
1
9
3
-NE

N
E

N
E
Te
m
p
e
r
a
t
u
r
e

3
2
5

°
C

5
1
9
3
-NE

N
E

N
E
To
p

o
f

C
a
s
i
n
g
32
8

f
e
e
t

-
-NE

N
E

N
E
De
p
t
h

t
o

W
a
t
e
r

3
1
8

f
e
e
t

-
-NE

N
E

N
E
Wa
t
e
r

E
l
e
v
a
t
i
o
n

3
1
9

f
e
e
t

-
-NE

N
E

N
E
We
l
l

D
e
p
t
h

4
1
1

f
e
e
t

-
-NE

N
E

N
E
Ar
s
e
n
i
c

1
4
µg/
L
24
8

0
.
0
7
8

U

1
.
0
3
J'
0.0
7
8

U

0
.
1
3
2
J
0.1
2
7

J

0
.
0
7
8

U

0
.
7
7
5
J
0.0
7
8

1
0

1
0

1
0
Ba
r
i
u
m

1
5
µg/
L
24
8

1
0
7

4
0
.
8
J'
11
6

3
5
.
5
J'
60
.
9
J'
31
1

4
4
.
4
J'
0.1

1
0
0

7
0
0

2
,
0
0
0
Bo
r
o
n

4
2
8
µg/
L
24
8

1
3
.
7
J
6.7
5
J
6.
8
2
J
11
0

2
7
.
8

J

5
.
5
1
J
3.
3

U

3
.
3

N
E

7
0
0

N
E
Ca
d
m
i
u
m

3
4
µg/
L
24
8

0
.
7
2
3
J
0.3
4
2
J
0.2
0
4
J
0.
1
0
1

U

0
.
1
0
1

U

0
.
4
2
5
J
0.
1
0
1

U

0
.
1
0
1

1

2

5
Ch
l
o
r
i
d
e

3
0
1
µg/
L
24
8

4
,
0
7
0

2
3
,
0
0
0

4
,
7
9
0

2
,
1
3
0

2
6
,
9
0
0

2
1
,
3
0
0

1
7
,
6
0
0

2
2

N
E

2
5
0
,
0
0
0

2
5
0
,
0
0
0
*
Ch
r
o
m
i
u
m

5
1
µg/
L
24
8

1
.
8
9
J
0.7
8
4
J
0.6
0
6
J
1.4
6
J
0.9
3

J

0
.
7
4
3
J
0.
5

U

0
.
5

1
0

1
0

1
0
0
Co
p
p
e
r

5
4
µg/
L
24
8

1

U

1

U

1

U

1

U

1

U

1

U

1

U

1

1
0

1
,
0
0
0

1
,
3
0
0
Flu
o
r
i
d
e

3
1
2
µg/
L
24
8

8
5

U

8
5

U

8
5

U

5
5
J
17
0

U

5
4
.
3
J
38
.
6
J
17

2
,
0
0
0

2
,
0
0
0

4
,
0
0
0
Ir
o
n

3
4
0
µg/
L
24
8
1,0
3
0

3
2
9

4
2
7

4
6
4

7
2
8

1
,
0
2
0

8
,
1
1
0
1.3

3
0
0

3
0
0

3
0
0
*
Le
a
d

1
3
1
µg/
L
24
8

0
.
1
7
4
J
0.2
1
3
J
0.2
0
8
J
0.
4
1
9
J
0.1
6

J

0
.
3
4
5
J
0.
0
8
9
J
0.0
6
5

1
0

1
5

1
5
Ma
n
g
a
n
e
s
e

3
4
2
µg/
L
24
8

2
1
J'
51
.
1

7
2
.
6
10
.
2
J'
52
.
6
39
.
8
J'
83
8
0.2

5
0

5
0

5
0
*
Me
r
c
u
r
y

1
3
2
µg/
L
24
8

0
.
0
3
3
4

U

0
.
0
3
3
4

U

0
.
0
3
3
4

U

0
.
0
3
3
4

U

0
.
0
3
3
4

U

0
.
0
3
3
4

U

0
.
0
3
3
4

U

0
.
0
3
3
4

0
.
2

1

2
Nic
k
e
l

1
5
2
µg/
L
24
8

1
5
.
4
J'
0.8
7
2
J
0.6
6
8
J
0.
5

U

3
5
.
7
J'
9.
7
7
J'
0.
5

U

0
.
5

5
0

1
0
0

N
E
Nit
r
a
t
e

(
a
s

N
i
t
r
o
g
e
n
)

3
0
3
µg/
L
24
8

2
,
6
1
0
J'
15
,
1
0
0
2,6
0
0
J'
7.6
7
J
2,5
0
0
J'
5,9
7
0
J'
5.
4

U

5
.
4

1
0
,
0
0
0

1
0
,
0
0
0

1
0
,
0
0
0
Se
l
e
n
i
u
m

1
8
3
µg/
L
24
8

3
.
8
5
J'
0.9
6
8
J
1.
0
5
J'
0.
0
9
2

U

9
.
7
J'
0.1
3
7
J
0.
1
8
7
J
0.0
9
2

1
0

2
0

5
0
Si
l
v
e
r

1
8
4
µg/
L
24
8

0
.
7

U

0
.
7

U

0
.
7

U

0
.
7

U

0
.
7

U

0
.
7

U

0
.
7

U

0
.
7

1
0

2
0

1
0
0
*
Su
l
f
a
t
e

3
1
5
µg/
L
24
8
53
7
,
0
0
0

3
6
4
,
0
0
0
77
,
1
0
0
J'
18
4
J'
96
7
,
0
0
0
26
,
0
0
0
J'
22
6
J'
18

2
5
0
,
0
0
0

2
5
0
,
0
0
0

2
5
0
,
0
0
0
*
To
t
a
l

D
i
s
s
o
l
v
e
d

S
o
l
i
d
s

3
1
1
µg/
L
24
8
81
2
,
0
0
0

5
4
4
,
0
0
0
16
6
,
0
0
0

5
4
,
0
0
0
1,3
2
0
,
0
0
0
12
2
,
0
0
0

7
3
,
0
0
0

1
6
,
7
0
0

N
E

5
0
0
,
0
0
0

5
0
0
,
0
0
0
*
Zin
c

2
1
3
µg/
L
24
8

1
6
.
3

1
1
.
9

6
.
0
8
J'
8.0
3
J'
50
.
6

7
4
.
2

9
.
7
6
J'
2.6

1
0

1
,
0
0
0

5
,
0
0
0
*
No
t
e
s
:

1
.

C
o
n
c
e
n
t
r
a
t
i
o
n
s

p
r
e
s
e
n
t
e
d

i
n

m
i
c
r
o
g
r
a
m
s

p
e
r

l
i
t
e
r

(
µ
g
/
L
)
.

2
.

S
W
S

I
D

i
s

t
h
e

S
o
l
i
d

W
a
s
t
e

S
e
c
t
i
o
n

I
d
e
n
t
i
f
i
c
a
t
i
o
n

N
u
m
b
e
r
.

3
.

M
D
L

i
s

t
h
e

l
a
b
o
r
a
t
o
r
y

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.

T
h
e

M
D
L

v
a
l
u
e
s

p
r
e
s
e
n
t
e
d

a
r
e

f
o
r

s
a
m
p
l
e
s

n
o
t

d
i
l
u
t
e
d

b
y

t
h
e

l
a
b
o
r
a
t
o
r
y

d
u
r
in
g

a
n
a
l
y
s
i
s
.

4
.

S
W
S
L

i
s

t
h
e

S
o
l
i
d

W
a
s
t
e

S
e
c
t
i
o
n

L
i
m
i
t
.

N
C
D
E
Q

d
e
f
i
n
e
s

t
h
e

S
W
S
L

a
s

t
h
e

l
o
w
e
s
t

a
m
o
u
n
t

o
f

a
n
a
l
y
t
e

i
n

a

s
a
m
p
l
e

t
h
a
t

c
a
n

b
e

q
u
an
t
i
t
a
t
i
v
e
l
y

d
e
t
e
r
m
i
n
e
d

w
i
t
h

s
u
i
t
a
b
l
e

p
r
e
c
i
s
i
o
n

a
n
d

a
c
c
u
r
a
c
y
.

5
.

1
5
A

N
C
A
C

2
L

S
t
a
n
d
a
r
d

r
e
f
e
r
s

t
o

C
l
a
s
s

G
A

S
t
a
n
d
a
r
d
s

a
s

f
o
u
n
d

i
n

1
5
A

N
C
A
C

0
2
L
.

0
2
0
2

G
r
o
u
n
d
w
a
t
e
r

Q
u
a
l
i
t
y

S
t
a
n
d
a
r
d
s
,

l
a
s
t

a
m
e
n
de
d

o
n

A
p
r
i
l

1
,

2
0
1
3
.

6
.

M
C
L

i
s

t
h
e

F
e
d
e
r
a
l

M
a
x
i
m
u
m

C
o
n
t
a
m
i
n
a
n
t

L
e
v
e
l

a
s

f
o
u
n
d

i
n

4
0

C
F
R
,

S
u
b
p
a
r
t

G
,

§
1
4
1
.
6
2
.

7
.

*

C
o
n
c
e
n
t
r
a
t
i
o
n

l
i
s
t
e
d

i
s

a

s
e
c
o
n
d
a
r
y

m
a
x
i
m
u
m

c
o
n
t
a
m
i
n
a
n
t

l
e
v
e
l

(
S
M
C
L
)
.

S
M
C
L
s

a
r
e

e
s
t
a
b
l
i
s
h
e
d

b
y

E
P
A

i
n

t
h
e

N
a
t
i
o
n
a
l

S
e
c
on
d
a
r
y

D
r
i
n
k
i
n
g

W
a
t
e
r

R
e
g
u
l
a
t
i
o
n
s

a
s

f
o
u
n
d

i
n

4
0

C
F
R

§
1
4
3
.
3
.

8
.

N
E

i
n
d
i
c
a
t
e
s

n
o
t

e
s
t
a
b
l
i
s
h
e
d
.

N
A

i
n
d
i
c
a
t
e
s

n
o
t

a
n
a
l
y
z
e
d
.

B
l
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

t
h
a
t

t
h
e
r
e

i
s

n
o

i
n
f
o
r
m
a
t
i
o
n

r
e
l
e
v
a
n
t

t
o

th
e

r
e
s
p
e
c
t
i
v
e

r
o
w
.

9
.

G
r
a
y
e
d

v
a
l
u
e
s

i
n
d
i
c
a
t
e

v
a
l
u
e
s

t
h
a
t

e
q
u
a
l

o
r

a
r
e

g
r
e
a
t
e
r

t
h
a
n

t
h
e

S
W
S
L
.
10
.

B
o
l
d

v
a
l
u
e
s

i
n
d
i
c
a
t
e

v
a
l
u
e
s

t
h
a
t

a
t
t
a
i
n

o
r

e
x
c
e
e
d

t
h
e

1
5
A

N
C
A
C

2
L

S
t
a
n
d
a
r
d
.
11
.

Q
u
a
l
i
f
i
e
r
s

i
n

n
o
n
-
i
t
a
l
i
c
i
z
e
d

t
e
x
t

a
r
e

l
a
b
o
r
a
t
o
r
y

d
a
t
a

q
u
a
l
i
f
i
e
r
s

o
r

"
f
l
a
g
s
"
.

"
U
"

i
s

u
s
e
d

t
o

i
d
e
n
t
i
f
y

r
e
s
u
l
t
s

n
o
t

d
e
t
e
c
t
e
d

a
t c
o
n
c
e
n
t
r
a
t
i
o
n
s

w
h
i
c
h

e
q
u
a
l

t
h
e

l
a
b
o
r
a
t
o
r
y
'
s

M
D
L
.

"
J
"

i
s

u
s
e
d

t
o

i
d
e
n
t
i
f
y

e
s
t
i
m
a
t
e
d

c
o
n
c
e
n
t
r
a
t
i
o
n
s

w
h
i
c
h

e
q
u
a
l

o
r

a
r
e

g
r
e
a
t
e
r

t
h
a
n

t
h
e

M
D
L

b
u
t

a
r
e

l
e
s
s

t
h
a
n

t
h
e

l
a
b
o
r
a
t
o
r
y's

m
e
t
h
o
d

r
e
p
o
r
t
i
n
g

l
i
m
i
t

(
M
R
L
)
.

A
n

i
t
a
l
i
c
i
z
e
d

J'
-fl
a
g

i
s

a

d
a
t
a

q
u
a
l
i
f
i
e
r
,

a
d
d
e
d

b
y

H
D
R

t
o

i
n
d
i
c
a
t
e

c
o
n
c
e
n
t
r
a
t
i
o
n
s

w
h
i
c
h

e
q
u
a
l

o
r

a
r
e

g
r
e
a
t
e
r

t
h
a
n

t
h
e

l
a
b
o
r
a
t
o
r
y
'
s

M
R
L

b
u
t

a
r
e
le
s
s

t
h
a
n

t
h
e

S
W
S
L
.

12
.

S
U

i
n
d
i
c
a
t
e
s

S
t
a
n
d
a
r
d

U
n
i
t
s
.
13
.

µ
Լ /c
m

i
n
d
i
c
a
t
e
s

m
i
c
r
o
m
h
o
s

p
e
r

c
e
n
t
i
m
e
t
e
r
.
14
.

A
c
c
o
r
d
i
n
g

t
o

t
h
e

C
o
n
s
t
i
t
u
e
n
t

L
o
o
k
-
u
p

w
e
b
p
a
g
e

o
n

t
h
e

N
C
D
E
Q

D
i
v
i
s
i
o
n

o
f

W
a
s
t
e

M
a
n
a
g
e
m
e
n
t

w
e
b
p
a
g
e
,

t
h
e
r
e

i
s

n
o

S
W
S
L

o
r

2
L

S
t
a
n
da
r
d

f
o
r

c
h
l
o
r
i
d
e

a
s
s
o
c
i
a
t
e
d

w
i
t
h

C
A
S

n
u
m
b
e
r

1
6
8
8
7
-
0
0
-
6
,

w
h
i
c
h

i
s

t
h
e

C
A
S

r
e
p
o
r
t
e
d

b
y

t
h
e

l
a
b
o
r
a
t
o
r
y

f
o
r

t
h
e

a
n
a
l
y
s
e
s

c
o
m
p
l
e
t
e
d
.

T
h
e
r
e
f
o
r
e
,

t
h
e

S
W
S
L

a
n
d

2
L

S
t
a
n
d
a
r
d

l
i
s
t
e
d

a
r
e

f
o
r

t
h
e

c
h
l
o
r
i
d
e

w
i
t
h

C
A
S

n
u
m
b
e
r

S
W
3
0
1

a
s

s
p
ec
i
f
i
e
d

o
n

t
h
e

C
o
n
s
t
i
t
u
e
n
t

L
o
o
k
-
u
p

w
e
b
p
a
g
e

(
l
a
s
t

u
p
d
a
t
e
d

J
u
n
e

1
3
,

2
0
1
1
)
.
15
.

G
r
o
u
n
d
w
a
t
e
r

a
t

B
C
-
2
7

a
n
d

B
C
-
2
9

c
o
u
l
d

n
o
t

b
e

m
e
a
s
u
r
e
d

a
s

t
h
e

i
n
i
t
i
a
l

w
a
t
e
r

l
e
v
e
l

w
a
s

b
e
l
o
w

t
o
p

o
f

p
u
m
p
.
16
.

A
n
a
l
y
t
i
c
a
l

r
e
s
u
l
t
s

o
b
t
a
i
n
e
d

f
r
o
m

E
l
e
c
t
r
o
n
i
c

D
a
t
a

D
e
l
i
v
e
r
a
b
l
e

(
E
D
D
)

p
r
o
v
i
d
e
d

b
y

T
i
m

H
u
n
s
u
c
k
e
r

o
f

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

on

N
o
v
e
m
b
e
r

2
9
,

2
0
1
6
.
26
.
1
5
73
1
.
2
9
17
.
1
4
78
.
5
6
78
5
.
2
3
10
1
.
2
1

3
8
.
3
3
SE
E

N
O
T
E

1
5
SE
E

N
O
T
E

1
5
17
.
5
1
73
1
.
8
1
23
.
2
6
5.
5
5.
1
85
3
19
.
9
9
19
.
7
9
1,
0
1
5
5.3
Laboratory Certificate Codes:Duke Energy Carolinas Field #5193 Duke Energy Analytical Laboratory #248
Mo
n
i
t
o
r
i
n
g

W
e
l
l
s
85
0
5

B
C
-
2
7
Sa
m
p
l
e

D
a
t
e
:

N
o
v
e
m
b
e
r

3
,

2
0
1
6

Fie
l
d

S
a
m
p
l
i
n
g

p
e
r
f
o
r
m
e
d

b
y

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

Pa
r
a
m
e
t
e
r

S
W
S

I
D

U
n
i
t
s
Ce
r
t
i
f
i
c
a
t
e
Co
d
e

8
5
0
5

B
C
-
2
0

8
5
0
5

B
C
-
2
1

8
5
0
5

B
C
-
2
2
15A NCAC 2L Standard
MD
L
Federal MCL
85
0
5

B
C
-
2
5

S
W
S
L
75
7
.
2
2

7
6
5
.
9
1
85
0
5

B
C
-
2
3
A

8
5
0
5

B
C
-
2
6
74
9
.
3
2
74
8
.
4
3
75
6
.
6
9
16
.
6
5
20
.
5
5
1,5
5
9
5.3
5.8 44
15
.
4
3
17
.
4
6
23
5
76
4
.
7
8
86
3
.
7
9
19
.
6
5
11
6
5.2
4.
8
18
6
24
.
2
2
74
0
.
0
8
17
.
1
4
76
0
.
8
5
5.0
6
12
.
8
2
74
3
.
8
7
16
.
7
7

1
3
.
0
0
Page 1 of 2
Ta
b
l
e

4

-

F
i
e
l
d

a
n
d

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s

L
L
C
/
B
e
l
e
w
s

C
r
e
e
k

S
t
e
a
m

S
t
a
t
i
o
n
FG
D

R
e
s
i
d
u
e

L
a
n
d
f
i
l
l
,

P
e
r
m
i
t

N
o
.

8
5
0
5
Fi
e
l
d

p
H

3
2
0

S
U

5
1
9
3
-

N
E

6
.
5
-
8
.
5

6
.
5
-
8
.
5
*
Fie
l
d

S
p
e
c
i
f
i
c

C
o
n
d
u
c
t
a
n
c
e

3
2
3

µ
Լ /c
m

5
1
9
3
-NE

N
E

N
E
Te
m
p
e
r
a
t
u
r
e

3
2
5

°
C

5
1
9
3
-NE

N
E

N
E
To
p

o
f

C
a
s
i
n
g

3
2
8

f
e
e
t

-
-NE

N
E

N
E
De
p
t
h

t
o

W
a
t
e
r

3
1
8

f
e
e
t

-
-NE

N
E

N
E
Wa
t
e
r

E
l
e
v
a
t
i
o
n

3
1
9

f
e
e
t

-
-NE

N
E

N
E
We
l
l

D
e
p
t
h

4
1
1

f
e
e
t

-
-NE

N
E

N
E
Ar
s
e
n
i
c

1
4
µg/
L

2
4
8
0.0
7
8

U

0
.
0
7
8

U

0
.
0
7
8

U

0
.
0
7
8

U

0
.
1
8
2

J

0
.
4
8
5
J
0.0
7
8

U

0
.
0
7
8
10

1
0

1
0
Ba
r
i
u
m

1
5
µg/
L

2
4
8
31
.
4
J'
12
6

1
6
.
7
J'
16
.
5
J'
41
.
6
J'
28
.
2
J'
0.1

U

0
.
1
100

7
0
0

2
,
0
0
0
Bo
r
o
n

4
2
8
µg/
L

2
4
8
3.7
3
J
5.
3
7
J
3.
3

U

1
8
J
11
.
6

J

3
.
5
J
3.
7
3
J
3.
3
NE

7
0
0

N
E
Ca
d
m
i
u
m

3
4
µg/
L

2
4
8
0.1
0
1

U

0
.
1
0
1

U

0
.
1
0
1

U

0
.
1
0
1

U

0
.
2
7
6

J

0
.
1
0
1

U

0
.
1
0
1

U

0
.
1
0
1
125
Ch
l
o
r
i
d
e

3
0
1
µg/
L

2
4
8
2,0
3
0

4
,
0
3
0

3
,
1
8
0

1
,
7
9
0

2
,
2
7
0

4
,
0
3
0

2
2

U

2
2
NE

2
5
0
,
0
0
0

2
5
0
,
0
0
0
*
Ch
r
o
m
i
u
m

5
1
µg/
L

2
4
8
1.0
2
J
0.5

U

0
.
5
1
9
J
0.5

U

0
.
5

U

0
.
5

U

0
.
5

U

0
.
5
10

1
0

1
0
0
Co
p
p
e
r

5
4
µg/
L

2
4
8
1U

1
U

1
U

1
U

1
U

1
U

1
U

1
10

1
,
0
0
0

1
,
3
0
0
Flu
o
r
i
d
e

3
1
2
µg/
L

2
4
8
52
J
50
.
5
J
64
.
6
J
99
J
34
0

U

1
1
4
J'
17

U

1
7
2,000

2
,
0
0
0

4
,
0
0
0
Ir
o
n

3
4
0
µg/
L

2
4
8
69
0
20
0
J'
89
.
2
J'
95
.
6
J'
58
.
6
J'
2,8
6
0
1.3

U

1
.
3
300

3
0
0

3
0
0
*
Le
a
d

1
3
1
µg/
L

2
4
8
0.6
1
4
J
0.0
6
5

U

0
.
0
6
5

U

0
.
0
6
5

U

0
.
0
6
5

U

0
.
0
6
5

U

0
.
0
6
5

U

0
.
0
6
5
10

1
5

1
5
Ma
n
g
a
n
e
s
e

3
4
2
µg/
L

2
4
8
11
.
9
J'
71
.
8
2.8
5
J
17
.
9
J'
18
J'
32
7
1.
0
7
J
0.
2
50

5
0

5
0
*
Me
r
c
u
r
y

1
3
2
µg/
L

2
4
8
0.
0
3
3
4

U

0
.
0
3
3
4

U

0
.
0
3
3
4

U

0
.
0
3
3
4

U

0
.
0
3
3
4

U

0
.
0
3
3
4

U

0
.
0
3
3
4

U

0
.
0
3
3
4
0.2

1

2
Nic
k
e
l

1
5
2
µg/
L

2
4
8
0.
5

U

0
.
7
6
4
J
0.
5

U

0
.
5

U

1
5
.
2
J'
0.
5

U

0
.
5

U

0
.
5
50

1
0
0

N
E
Nit
r
a
t
e

(
a
s

N
i
t
r
o
g
e
n
)

3
0
3
µg/
L

2
4
8
91
8
J'
38
6
J'
57
7
J'
80
0
J'
51
8
J'
8.0
6
J
5.4

U

5
.
4
10,000

1
0
,
0
0
0

1
0
,
0
0
0
Se
l
e
n
i
u
m

1
8
3
µg/
L

2
4
8
0.0
9
2

U

0
.
2
3
8
J
0.
0
9
2

U

0
.
0
9
2

U

4
.
2
1
J'
0.
0
9
2

U

0
.
0
9
2

U

0
.
0
9
2
10

2
0

5
0
Sil
v
e
r

1
8
4
µg/
L

2
4
8
0.
7

U

0
.
7

U

0
.
7

U

0
.
7

U

0
.
7

U

0
.
7

U

0
.
7

U

0
.
7
10

2
0

1
0
0
*
Su
l
f
a
t
e

3
1
5
µg/
L

2
4
8
27
1
J'
11
,
7
0
0
J'
62
3
J'
1,0
2
0
J'
95
4
,
0
0
0
14
,
2
0
0
J'
18

U

1
8
250,000

2
5
0
,
0
0
0

2
5
0
,
0
0
0
*
To
t
a
l

D
i
s
s
o
l
v
e
d

S
o
l
i
d
s

3
1
1
µg/
L

2
4
8
55
,
0
0
0

4
9
,
0
0
0

7
0
,
0
0
0

8
7
,
0
0
0
1,
3
3
0
,
0
0
0
88
,
0
0
0

1
6
,
7
0
0
NE

5
0
0
,
0
0
0

5
0
0
,
0
0
0
*
Zi
n
c

2
1
3
µg/
L

2
4
8
14

7
.
0
7
J'
2.
6

U

2
.
6

U

2
2

3
6
.
6
2.6

U
2.
6
10

1
,
0
0
0

5
,
0
0
0
*
No
t
e
s
:
1
.

C
o
n
c
e
n
t
r
a
t
i
o
n
s

p
r
e
s
e
n
t
e
d

i
n

m
i
c
r
o
g
r
a
m
s

p
e
r

l
i
t
e
r

(
µ
g
/
L
)
.
2
.

S
W
S

I
D

i
s

t
h
e

S
o
l
i
d

W
a
s
t
e

S
e
c
t
i
o
n

I
d
e
n
t
i
f
i
c
a
t
i
o
n

N
u
m
b
e
r
.
3
.

M
D
L

i
s

t
h
e

l
a
b
o
r
a
t
o
r
y

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.

T
h
e

M
D
L

v
a
l
u
e
s

p
r
e
s
e
n
t
e
d

a
r
e

f
o
r

s
a
m
p
l
e
s

n
o
t

d
i
l
u
t
e
d

b
y

t
h
e

l
a
b
o
r
a
t
o
r
y

d
u
r
in
g

a
n
a
l
y
s
i
s
.

4
.

S
W
S
L

i
s

t
h
e

S
o
l
i
d

W
a
s
t
e

S
e
c
t
i
o
n

L
i
m
i
t
.

N
C
D
E
Q

d
e
f
i
n
e
s

t
h
e

S
W
S
L

a
s

t
h
e

l
o
w
e
s
t

a
m
o
u
n
t

o
f

a
n
a
l
y
t
e

i
n

a

s
a
m
p
l
e

t
h
a
t

c
a
n

b
e

q
u
an
t
i
t
a
t
i
v
e
l
y

d
e
t
e
r
m
i
n
e
d

w
i
t
h

s
u
i
t
a
b
l
e

p
r
e
c
i
s
i
o
n

a
n
d

a
c
c
u
r
a
c
y
.

5
.

1
5
A

N
C
A
C

2
L

S
t
a
n
d
a
r
d

r
e
f
e
r
s

t
o

C
l
a
s
s

G
A

S
t
a
n
d
a
r
d
s

a
s

f
o
u
n
d

i
n

1
5
A

N
C
A
C

0
2
L
.

0
2
0
2

G
r
o
u
n
d
w
a
t
e
r

Q
u
a
l
i
t
y

S
t
a
n
d
a
r
d
s
,

l
a
s
t

a
m
e
n
de
d

o
n

A
p
r
i
l

1
,

2
0
1
3
.

6
.

M
C
L

i
s

t
h
e

F
e
d
e
r
a
l

M
a
x
i
m
u
m

C
o
n
t
a
m
i
n
a
n
t

L
e
v
e
l

a
s

f
o
u
n
d

i
n

4
0

C
F
R
,

S
u
b
p
a
r
t

G
,

§
1
4
1
.
6
2
.
7
.

*

C
o
n
c
e
n
t
r
a
t
i
o
n

l
i
s
t
e
d

i
s

a

s
e
c
o
n
d
a
r
y

m
a
x
i
m
u
m

c
o
n
t
a
m
i
n
a
n
t

l
e
v
e
l

(
S
M
C
L
)
.

S
M
C
L
s

a
r
e

e
s
t
a
b
l
i
s
h
e
d

b
y

E
P
A

i
n

t
h
e

N
a
t
i
o
n
a
l

S
e
c
on
d
a
r
y

D
r
i
n
k
i
n
g

W
a
t
e
r

R
e
g
u
l
a
t
i
o
n
s

a
s

f
o
u
n
d

i
n

4
0

C
F
R

§
1
4
3
.
3
.
8
.

N
E

i
n
d
i
c
a
t
e
s

n
o
t

e
s
t
a
b
l
i
s
h
e
d
.

N
A

i
n
d
i
c
a
t
e
s

n
o
t

a
n
a
l
y
z
e
d
.

B
l
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

t
h
a
t

t
h
e
r
e

i
s

n
o

i
n
f
o
r
m
a
t
i
o
n

r
e
l
e
v
a
n
t

t
o

th
e

r
e
s
p
e
c
t
i
v
e

r
o
w
.

9
.

G
r
a
y
e
d

v
a
l
u
e
s

i
n
d
i
c
a
t
e

v
a
l
u
e
s

t
h
a
t

e
q
u
a
l

o
r

a
r
e

g
r
e
a
t
e
r

t
h
a
n

t
h
e

S
W
S
L
.
10
.

B
o
l
d

v
a
l
u
e
s

i
n
d
i
c
a
t
e

v
a
l
u
e
s

t
h
a
t

a
t
t
a
i
n

o
r

e
x
c
e
e
d

t
h
e

1
5
A

N
C
A
C

2
L

S
t
a
n
d
a
r
d
.
11
.

Q
u
a
l
i
f
i
e
r
s

i
n

n
o
n
-
i
t
a
l
i
c
i
z
e
d

t
e
x
t

a
r
e

l
a
b
o
r
a
t
o
r
y

d
a
t
a

q
u
a
l
i
f
i
e
r
s

o
r

"
f
l
a
g
s
"
.

"
U
"

i
s

u
s
e
d

t
o

i
d
e
n
t
i
f
y

r
e
s
u
l
t
s

n
o
t

d
e
t
e
c
t
e
d

a
t c
o
n
c
e
n
t
r
a
t
i
o
n
s

w
h
i
c
h

e
q
u
a
l

t
h
e

l
a
b
o
r
a
t
o
r
y
'
s

M
D
L
.

"
J
"

i
s

u
s
e
d

t
o

i
d
e
n
t
i
f
y

e
s
t
i
m
a
t
e
d

c
o
n
c
e
n
t
r
a
t
i
o
n
s

w
h
i
c
h

e
q
u
a
l

o
r

a
r
e

g
r
e
a
t
e
r

t
h
a
n

t
h
e

M
D
L

b
u
t

a
r
e

l
e
s
s

t
h
a
n

t
h
e

l
a
b
o
r
a
t
o
r
y's

m
e
t
h
o
d

r
e
p
o
r
t
i
n
g

l
i
m
i
t

(
M
R
L
)
.

A
n

i
t
a
l
i
c
i
z
e
d

J'
-fl
a
g

i
s

a

d
a
t
a

q
u
a
l
i
f
i
e
r
,

a
d
d
e
d

b
y

H
D
R

t
o

i
n
d
i
c
a
t
e

c
o
n
c
e
n
t
r
a
t
i
o
n
s

w
h
i
c
h

e
q
u
a
l

o
r

a
r
e

g
r
e
a
t
e
r

t
h
a
n

t
h
e

l
a
b
o
r
a
t
o
r
y
'
s

M
R
L

b
u
t

a
r
e
le
s
s

t
h
a
n

t
h
e

S
W
S
L
.

12
.

S
U

i
n
d
i
c
a
t
e
s

S
t
a
n
d
a
r
d

U
n
i
t
s
.
13
.

µ
Լ /c
m

i
n
d
i
c
a
t
e
s

m
i
c
r
o
m
h
o
s

p
e
r

c
e
n
t
i
m
e
t
e
r
.
14
.

A
c
c
o
r
d
i
n
g

t
o

t
h
e

C
o
n
s
t
i
t
u
e
n
t

L
o
o
k
-
u
p

w
e
b
p
a
g
e

o
n

t
h
e

N
C
D
E
Q

D
i
v
i
s
i
o
n

o
f

W
a
s
t
e

M
a
n
a
g
e
m
e
n
t

w
e
b
p
a
g
e
,

t
h
e
r
e

i
s

n
o

S
W
S
L

o
r

2
L

S
t
a
n
da
r
d

f
o
r

c
h
l
o
r
i
d
e

a
s
s
o
c
i
a
t
e
d

w
i
t
h

C
A
S

n
u
m
b
e
r

1
6
8
8
7
-
0
0
-
6
,

w
h
i
c
h

i
s

t
h
e

C
A
S

r
e
p
o
r
t
e
d

b
y

t
h
e

l
a
b
o
r
a
t
o
r
y

f
o
r

t
h
e

a
n
a
l
y
s
e
s

c
o
m
p
l
e
t
e
d
.

T
h
e
r
e
f
o
r
e
,

t
h
e

S
W
S
L

a
n
d

2
L

S
t
a
n
d
a
r
d

l
i
s
t
e
d

a
r
e

f
o
r

t
h
e

c
h
l
o
r
i
d
e

w
i
t
h

C
A
S

n
u
m
b
e
r

S
W
3
0
1

a
s

s
p
ec
i
f
i
e
d

o
n

t
h
e

C
o
n
s
t
i
t
u
e
n
t

L
o
o
k
-
u
p

w
e
b
p
a
g
e

(
l
a
s
t

u
p
d
a
t
e
d

J
u
n
e

1
3
,

2
0
1
1
)
.
15
.

G
r
o
u
n
d
w
a
t
e
r

a
t

B
C
-
2
7

a
n
d

B
C
-
2
9

c
o
u
l
d

n
o
t

b
e

m
e
a
s
u
r
e
d

a
s

t
h
e

i
n
i
t
i
a
l

w
a
t
e
r

l
e
v
e
l

w
a
s

b
e
l
o
w

t
o
p

o
f

p
u
m
p
.
16
.

A
n
a
l
y
t
i
c
a
l

r
e
s
u
l
t
s

o
b
t
a
i
n
e
d

f
r
o
m

E
l
e
c
t
r
o
n
i
c

D
a
t
a

D
e
l
i
v
e
r
a
b
l
e

(
E
D
D
)

p
r
o
v
i
d
e
d

b
y

T
i
m

H
u
n
s
u
c
k
e
r

o
f

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

on

N
o
v
e
m
b
e
r

2
9
,

2
0
1
6
.
NA
25
.
3
2
SE
E

N
O
T
E

1
5
SE
E

N
O
T
E

1
5
49
.
1
9
76
8
.
9
0
60
.
2
0

8
3
.
3
0
75
7
.
6
8
58
.
7
2
27
.
8
1
74
7
.
9
1
34
.
1
0
--
17
.
5
4
33
.
0
1
5.
2
5.6 55
16
.
4
1
77
5
.
7
2
17
.
2
4
11
7
6.0
5.7 68
14
.
8
16
.
7
3
70
-
Laboratory Certificate Codes:Duke Energy Carolinas Field #5193 Duke Energy Analytical Laboratory #248 Federal MCL15A NCAC 2L Standard
75
6
.
5
6
-
SWSL
MD
L
15
.
9
14
6
7.5
5.
3
1,
5
6
9
17
.
5
-
73
9
.
0
2
85
0
5

B
C
-
2
9
85
0
5

B
C
-
2
8
Fie
l
d

B
l
a
n
k
85
0
5

S
W
-
1
85
0
5

B
C
-
3
2
Mo
n
i
t
o
r
i
n
g

W
e
l
l
s
-
75
3
.
1
8
81
8
.
0
9
Sa
m
p
l
e

D
a
t
e
:

N
o
v
e
m
b
e
r

3
,

2
0
1
6

Fi
e
l
d

S
a
m
p
l
i
n
g

p
e
r
f
o
r
m
e
d

b
y

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

81
6
.
4
0
85
0
5

B
C
-
3
1
-----
Pa
r
a
m
e
t
e
r

S
W
S

I
D

U
n
i
t
s
Ce
r
t
i
f
i
c
a
t
e
Co
d
e

8
5
0
5

B
C
-
3
0
Page 2 of 2
Ta
b
l
e

5

-

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s

t
h
a
t

E
q
u
a
l

o
r

E
x
c
e
e
d
15
A

N
C
A
C

2
L

G
r
o
u
n
d
w
a
t
e
r

Q
u
a
l
i
t
y

S
t
a
n
d
a
r
d
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s

L
L
C
/
B
e
l
e
w
s

C
r
e
e
k

S
t
e
a
m

S
t
a
t
i
o
n
FG
D

R
e
s
i
d
u
e

L
a
n
d
f
i
l
l
,

P
e
r
m
i
t

N
o
.

8
5
0
5
Pa
r
a
m
e
t
e
r

S
a
m
p
l
e

I
D

R
e
s
u
l
t

U
n
i
t
s
15
A

N
C
A
C
2L

S
t
a
n
d
a
r
d
Hi
s
t
o
r
i
c
a
l

C
o
n
c
e
n
t
r
a
t
i
o
n
s

C
a
u
s
e

a
n
d

S
i
g
n
i
f
i
c
a
n
c
e
BC
-
2
0

5
.
3

5
.
1

-

5
.
9

p
H

i
n

B
C
-
2
0

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.
BC
-
2
1

5
.
1

4
.
7

-

5
.
8

p
H

i
n

B
C
-
2
1

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.
BC
-
2
2

5
.
5

5
.
3

-

5
.
9

p
H

i
n

B
C
-
2
2

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.
BC
-
2
3
A

5
.
8

5
.
4

-

6
.
1

p
H

i
n

B
C
-
2
3
A

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.
BC
-
2
5

5
.
3

5
.
0

-

5
.
8

p
H

i
n

B
C
-
2
5

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.
BC
-
2
6

4
.
8

4
.
7

-

5
.
2

p
H

i
n

B
C
-
2
6

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.
BC
-
2
7

5
.
2

4
.
8

-

5
.
7

p
H

i
n

B
C
-
2
7

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.
BC
-
2
8

5
.
6

5
.
4

-

6
.
1

p
H

i
n

B
C
-
2
8

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.
BC
-
2
9

5
.
2

4
.
8

-

5
.
5

p
H

i
n

B
C
-
2
9

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.
BC
-
3
0

5
.
7

4
.
5

-

5
.
9

p
H

i
n

B
C
-
3
0

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.
BC
-
3
1

6
.
0

5
.
5

-

6
.
6

p
H

i
n

B
C
-
3
1

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.
BC
-
3
2

5
.
3

5
.
3

-

5
.
5

p
H

i
n

B
C
-
3
2

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

t
h
e

l
o
w
e
s
t

h
i
s
t
o
r
i
c
a
l

r
e
a
d
i
n
g

a
t

w
e
l
l
.
BC
-
2
0

1
,
0
3
0

5
9

-

1
4
8
,
0
0
0

I
r
o
n

c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
2
0

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.

T
u
r
b
i
d
i
t
y

i
n

B
C
-
2
0

w
a
s

m
e
a
s
u
r
e
d
a
t

1
4

N
T
U
.
BC
-
2
1

3
2
9

1
2
.
3

-

1
,
0
7
0

I
r
o
n

c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
2
1

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.

T
u
r
b
i
d
i
t
y

i
n

B
C
-
2
1

w
a
s

m
e
a
s
u
r
e
d

at

1
8
.
1

N
T
U
.
BC
-
2
2

4
2
7

2
1
.
5

-

1
,
3
3
0

I
r
o
n

c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
2
2

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.

BC
-
2
3
A

4
6
4

1
5
7

-

8
,
7
3
3

I
r
o
n

c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
2
3
A

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.

T
u
r
b
i
d
i
t
y

i
n

B
C
-
2
3
A

w
a
s

m
e
a
s
u
r
e
d a
t

1
5
.
1

N
T
U
.
BC
-
2
5

7
2
8

3
7
4

-

2
8
8
,
0
0
0

I
r
o
n

c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
2
5

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.

T
u
r
b
i
d
i
t
y

i
n

B
C
-
2
5

w
a
s

m
e
a
s
u
r
e
d
a
t

1
2
.
2

N
T
U
.
BC
-
2
6

1
,
0
2
0

8
5
.
5

-

6
,
0
5
0

I
r
o
n

c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
2
6

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.

T
u
r
b
i
d
i
t
y

i
n

B
C
-
2
6

w
a
s

m
e
a
s
u
r
e
d
a
t

1
2
.
2

N
T
U
.
BC
-
2
7

8
,
1
1
0

2
,
4
0
0

-

3
4
,
5
0
0

I
r
o
n

c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
2
7

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.

BC
-
2
8

6
9
0

3
3
.
3

-

3
,
4
9
1

I
r
o
n

c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
2
8

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.

T
u
r
b
i
d
i
t
y

i
n

B
C
-
2
8

w
a
s

m
e
a
s
u
r
e
d

at

1
2
.
2

N
T
U
.
SW
-
1

2
,
8
6
0

6
9
6

-

7
,
6
2
5

I
r
o
n

c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

S
W
-
1

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

l
o
c
a
t
i
o
n
.

BC
-
2
1

5
1
.
1

4
.
7

-

3
1
5

M
a
n
g
a
n
e
s
e

c
o
c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
2
1

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.

T
u
r
b
i
d
i
t
y

i
n

B
C
-
2
1

w
a
s

m
e
a
s
ured at 18.1 NTU.
BC
-
2
2

7
2
.
6

7
.
2

-

2
2
5

M
a
n
g
a
n
e
s
e

c
o
c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
2
2

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.

BC
-
2
5

5
2
.
6

5
.
6

-

9
4
2

M
a
n
g
a
n
e
s
e

c
o
c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
2
5

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.

T
u
r
b
i
d
i
t
y

i
n

B
C
-
2
5

w
a
s

m
e
a
s
ured at 12.2 NTU.
BC
-
2
7

8
3
8

1
1
3

-

1
,
2
0
0

M
a
n
g
a
n
e
s
e

c
o
c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
2
7

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.
BC
-
2
9

7
1
.
8

7
.
1

-

5
8
4

M
a
n
g
a
n
e
s
e

c
o
c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
2
9

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.

SW
-
1

3
2
7

2
2
2

-

3
,
5
7
0

M
a
n
g
a
n
e
s
e

c
o
c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

S
W
-
1

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

l
o
c
a
t
i
o
n
.
Nit
r
a
t
e

a
s

N

B
C
-
2
1

1
5
,
1
0
0

µ
g
/
L

1
0
,
0
0
0

1
7
0

-

5
,
1
3
0

N
i
t
r
a
t
e

a
s

N

c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
2
1

i
s

h
i
g
h
e
r

t
h
a
n

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.

T
u
r
b
id
i
t
y

a
t

B
C
-
2
1

w
a
s

m
e
a
s
u
r
e
d

a
t

1
8

N
T
U
.
BC
-
2
0

5
3
7
,
0
0
0

2
1
,
9
5
0

-

5
5
4
,
0
0
0

S
u
l
f
a
t
e

c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
2
0

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.

BC
-
2
1

3
6
4
,
0
0
0

1
1
,
6
9
0

-

7
0
1
,
0
0
0

S
u
l
f
a
t
e

c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
2
1

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.

BC
-
2
5

9
6
7
,
0
0
0

1
4
,
3
2
0

-

1
,
1
9
0
,
0
0
0

S
u
l
f
a
t
e

c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
2
5

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.

BC
-
3
2

9
5
4
,
0
0
0

4
9
0
,
0
0
0

-

9
4
9
,
0
0
0

S
u
l
f
a
t
e

c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
3
2

i
s

h
i
g
h
e
r

t
h
a
n

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.

BC
-
2
0

8
1
2
,
0
0
0

1
0
8
,
0
0
0

-

8
3
8
,
0
0
0

T
D
S

c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
2
0

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.

BC
-
2
1

5
4
4
,
0
0
0

8
8
,
0
0
0

-

1
,
0
2
0
,
0
0
0

T
D
S

c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
2
1

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.

BC
-
2
5

1
,
3
2
0
,
0
0
0

7
4
,
0
0
0

-

1
,
8
1
0
,
0
0
0

T
D
S

c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
2
5

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.

BC
-
3
2

1
,
3
3
0
,
0
0
0

7
8
9
,
0
0
0

-

1
,
3
8
0
,
0
0
0

T
D
S

c
o
n
c
e
n
t
r
a
t
i
o
n

i
n

B
C
-
3
2

i
s

c
o
n
s
i
s
t
e
n
t

w
i
t
h

h
i
s
t
o
r
i
c
a
l

r
e
s
u
l
t
s

a
t

w
e
l
l
.

No
t
e
s
:
1
.

1
5
A

N
C
A
C

2
L

S
t
a
n
d
a
r
d

r
e
f
e
r
s

t
o

C
l
a
s
s

G
A

S
t
a
n
d
a
r
d
s

a
s

f
o
u
n
d

i
n

1
5
A

N
C
A
C

0
2
L

.
0
2
0
2

G
r
o
u
n
d
w
a
t
e
r

S
t
a
n
d
a
r
d
s
,

l
a
s
t

a
m
e
n
d
e
d

o
n

A
p
ril

1
,

2
0
1
3
.
2
.

µ
g
/
L

i
n
d
i
c
a
t
e
s

m
i
c
r
o
g
r
a
m
s

p
e
r

l
i
t
e
r
.
3
.

S
U

i
n
d
i
c
a
t
e
s

S
t
a
n
d
a
r
d

U
n
i
t
s
.
4
.

N
T
U

i
n
d
i
c
a
t
e
s

N
e
p
h
e
l
o
m
e
t
r
i
c

T
u
r
b
i
d
i
t
y

U
n
i
t
s
.
5
.

H
i
s
t
o
r
i
c
a
l

c
o
n
c
e
n
t
r
a
t
i
o
n
s

b
a
s
e
d

o
n

d
a
t
a

i
n

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

a
n
a
l
y
t
i
c
a
l

r
e
s
u
l
t
s

d
a
t
a
b
a
s
e
.
Sa
m
p
l
e

D
a
t
e
:

N
o
v
e
m
b
e
r

3
,

2
0
1
6

pH

6
.
5

-

8
.
5
Ir
o
n
SU
30
0
µg
/
L
To
t
a
l

D
i
s
s
o
l
v
e
d

So
l
i
d
s
50
0
,
0
0
0
µg
/
L
50
Ma
n
g
a
n
e
s
e

µ
g
/
L
25
0
,
0
0
0
Su
l
f
a
t
e

µ
g
/
L
.
Page 1 of 1
Ta
b
l
e

6

-

L
e
a
c
h
a
t
e

F
i
e
l
d

a
n
d

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s

L
L
C
/
B
e
l
e
w
s

C
r
e
e
k

S
t
e
a
m

S
t
a
t
i
o
n
FG
D

R
e
s
i
d
u
e

L
a
n
d
f
i
l
l
,

P
e
r
m
i
t

N
o
.

8
5
0
5
Fie
l
d

p
H

3
2
0

S
U

5
1
9
3

-

N
E
Fi
e
l
d

S
p
e
c
i
f
i
c

C
o
n
d
u
c
t
a
n
c
e

3
2
3

µ
Լ /c
m

5
1
9
3

-

N
E
Te
m
p
e
r
a
t
u
r
e

3
2
5
ºC
51
9
3

-

N
E
Ar
s
e
n
i
c

1
4
µg/
L
24
8

0
.
5
2
1
J
0.
0
7
8

1
0
Ba
r
i
u
m

1
5
µg/
L
24
8

1
6
.
4
J '
0.
1

1
0
0
Bo
r
o
n

4
2
8
µg/
L
24
8

7
,
1
6
0

3
.
3

N
E
Ca
d
m
i
u
m

3
4
µg/
L
24
8

0
.
1
0
1

U

0
.
1
0
1

1
Ch
l
o
r
i
d
e

3
0
1
µg/
L
24
8

1
0
3
,
0
0
0

5
5
0

N
E
Ch
r
o
m
i
u
m

5
1
µg/
L
24
8

0
.
5

U

0
.
5

1
0
Co
p
p
e
r

5
4
µg/
L
24
8

1

U

1

1
0
Flu
o
r
i
d
e

3
1
2
µg/
L
24
8

1
,
7
7
0
J
42
5

2
,
0
0
0
Ir
o
n

3
4
0
µg/
L
24
8

2
9
.
4
J '
1.
3

3
0
0
Le
a
d

1
3
1
µg/
L
24
8

0
.
0
6
5

U

0
.
0
6
5

1
0
Ma
n
g
a
n
e
s
e

3
4
2
µg/
L
24
8

6
,
7
4
0

0
.
2

5
0
Me
r
c
u
r
y
13
2
µg/
L
24
8

0
.
0
3
3
4

U

0
.
0
3
3
4

0
.
2
Nic
k
e
l

1
5
2
µg/
L
24
8

3
.
4
5
J
0.
5

5
0
Nit
r
a
t
e

(
a
s

N
i
t
r
o
g
e
n
)

3
0
3
µg/
L
24
8

8
2
0
J '
5.
4

1
0
,
0
0
0
Se
l
e
n
i
u
m

1
8
3
µg/
L
24
8

1
,
9
7
0

0
.
0
9
2

1
0
Si
l
v
e
r

1
8
4
µg/
L
24
8

0
.
7

U

0
.
7

1
0
Su
l
f
a
t
e

3
1
5
µg/
L
24
8

1
,
7
3
0
,
0
0
0

9
,
0
0
0

2
5
0
,
0
0
0
To
t
a
l

D
i
s
s
o
l
v
e
d

S
o
l
i
d
s

3
1
1
µg/
L
24
8

2
3
3
,
0
0
0

1
6
,
7
0
0

N
E
Zin
c

2
1
3
µg/
L
24
8

3
.
4
7
J
2.
6

1
0
No
t
e
s
:

1
.

C
o
n
c
e
n
t
r
a
t
i
o
n
s

p
r
e
s
e
n
t
e
d

i
n

m
i
c
r
o
g
r
a
m
s

p
e
r

l
i
t
e
r

(
µ
g
/
L
)
.

2
.

S
W
S

I
D

i
s

t
h
e

S
o
l
i
d

W
a
s
t
e

S
e
c
t
i
o
n

I
d
e
n
t
i
f
i
c
a
t
i
o
n

N
u
m
b
e
r
.

3
.

M
D
L

i
s

t
h
e

l
a
b
o
r
a
t
o
r
y

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.

4
.

S
W
S
L

i
s

t
h
e

S
o
l
i
d

W
a
s
t
e

S
e
c
t
i
o
n

L
i
m
i
t
.

N
C
D
E
Q

d
e
f
i
n
e
s

t
h
e

S
W
S
L

a
s

t
h
e

l
o
w
e
s
t

a
m
o
u
n
t

o
f

a
n
a
l
y
t
e

i
n

a

s
a
m
p
l
e

t
h
a
t

c
a
n

b
e

q
u
an
t
i
t
a
t
i
v
e
l
y

d
e
t
e
r
m
i
n
e
d

w
i
t
h

s
u
i
t
a
b
l
e

p
r
e
c
i
s
i
o
n

a
n
d

a
c
c
u
r
a
c
y
.

5
.

G
r
a
y
e
d

v
a
l
u
e
s

i
n
d
i
c
a
t
e

v
a
l
u
e
s

t
h
a
t

e
q
u
a
l

o
r

a
r
e

g
r
e
a
t
e
r

t
h
a
n

t
h
e

S
W
S
L
.

6
.

Q
u
a
l
i
f
i
e
r
s

i
n

n
o
n
-
i
t
a
l
i
c
i
z
e
d

t
e
x
t

a
r
e

l
a
b
o
r
a
t
o
r
y

d
a
t
a

q
u
a
l
i
f
i
e
r
s

o
r

"
f
l
a
g
s
"
.

"
U
"

i
s

u
s
e
d

t
o

i
d
e
n
t
i
f
y

r
e
s
u
l
t
s

n
o
t

d
e
t
e
c
t
e
d
a
t

c
o
n
c
e
n
t
r
a
t
i
o
n
s

w
h
i
c
h

e
q
u
a
l

t
h
e

l
a
b
o
r
a
t
o
r
y
'
s

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t

(
M
D
L
)
.

"
J
"

i
s

u
s
e
d

t
o

i
d
e
n
t
i
f
y

e
s
t
i
m
a
t
e
d

c
o
n
c
e
n
t
r
a
t
i
o
n
s

w
h
i
c
h

e
q
u
a
l

o
r

a
r
e

g
r
e
a
t
e
r

t
h
a
n

t
h
e

M
D
L

b
u
t

a
r
e

l
e
s
s

t
h
a
n

t
h
e

l
a
b
o
r
a
t
o
r
y's

m
e
t
h
o
d

r
e
p
o
r
t
i
n
g

l
i
m
i
t

(
M
R
L
)
.

A
n

i
t
a
l
i
c
i
z
e
d

J'
-f
l
a
g

i
s

a

d
a
t
a

q
u
a
l
i
f
i
e
r
,

a
d
d
e
d

b
y

H
D
R

t
o

i
n
d
i
c
a
t
e

c
o
n
c
e
n
t
r
a
t
i
o
n
s

w
h
i
c
h

e
q
u
a
l

o
r

a
r
e

g
r
e
a
t
e
r

t
h
a
n

t
h
e

l
a
b
o
r
a
t
o
r
y
'
s

M
R
L

b
u
t

a
r
e
l
e
s
s

t
h
a
n

t
h
e

S
W
S
L
.

7
.

S
U

i
n
d
i
c
a
t
e
s

S
t
a
n
d
a
r
d

U
n
i
t
s
.

8
.

µ
Լ /c
m

i
n
d
i
c
a
t
e
s

m
i
c
r
o
m
h
o
s

p
e
r

c
e
n
t
i
m
e
t
e
r
.

9
.

N
E

i
n
d
i
c
a
t
e
s

n
o
t

e
s
t
a
b
l
i
s
h
e
d
.
10
.

A
c
c
o
r
d
i
n
g

t
o

t
h
e

C
o
n
s
t
i
t
u
e
n
t

L
o
o
k
-
u
p

w
e
b
p
a
g
e

o
n

t
h
e

N
C
D
E
Q

D
i
v
i
s
i
o
n

o
f

W
a
s
t
e

M
a
n
a
g
e
m
e
n
t

w
e
b
p
a
g
e
,

t
h
e
r
e

i
s

n
o

S
W
S
L

o
r

2
L

S
t
a
nd
a
r
d

f
o
r

c
h
l
o
r
i
d
e

a
s
s
o
c
i
a
t
e
d

w
i
t
h

C
A
S

n
u
m
b
e
r

1
6
8
8
7
-
0
0
-
6
,

w
h
i
c
h

i
s

t
h
e

C
A
S

r
e
p
o
r
t
e
d

b
y

t
h
e

l
a
b
o
r
a
t
o
r
y

f
o
r

t
h
e

a
n
a
l
y
s
e
s

c
o
m
p
l
e
t
e
d
.

T
h
e
r
e
f
o
r
e
,

t
h
e

S
W
S
L

a
n
d

2
L

S
t
a
n
d
a
r
d

l
i
s
t
e
d

a
r
e

f
o
r

t
h
e

c
h
l
o
r
i
d
e

w
i
t
h

C
A
S
n
u
m
b
e
r

S
W
3
0
1

a
s

s
p
e
c
i
f
i
e
d

o
n

t
h
e

C
o
n
s
t
i
t
u
e
n
t

L
o
o
k
-
u
p

w
e
b
p
a
g
e

(
l
a
s
t

u
p
d
a
t
e
d

J
u
n
e

1
3
,

2
0
1
1
)
.
11
.

A
n
a
l
y
t
i
c
a
l

r
e
s
u
l
t
s

o
b
t
a
i
n
e
d

f
r
o
m

E
l
e
c
t
r
o
n
i
c

D
a
t
a

D
e
l
i
v
e
r
a
b
l
e

(
E
D
D
)

p
r
o
v
i
d
e
d

b
y

T
i
m

H
u
n
s
u
c
k
e
r

o
f

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C
o
n

N
o
v
e
m
b
e
r

2
9
,

2
0
1
6
.
Sa
m
p
l
e

D
a
t
e
:

N
o
v
e
m
b
e
r

3
,

2
0
1
6

Fi
e
l
d

S
a
m
p
l
i
n
g

p
e
r
f
o
r
m
e
d

b
y

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

Pa
r
a
m
e
t
e
r

S
W
S

I
D

U
n
i
t
s
Ce
r
t
i
f
i
c
a
t
e
Co
d
e
La
b
o
r
a
t
o
r
y

C
e
r
t
i
f
i
c
a
t
e

C
o
d
e
s
:
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s

F
i
e
l
d

#
5
1
9
3
Du
k
e

E
n
e
r
g
y

A
n
a
l
y
t
i
c
a
l

L
a
b
o
r
a
t
o
r
y

#
2
4
8
85
0
5

L
e
a
c
h
a
t
e

S
W
S
L
MD
L
17
.
3
4
6.
4
2,
8
6
7
Page 1 of 1

A
Appendix A
Field Sampling Forms

ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬/▬►0.0
SS 721.7 ▬▬►720 719.7 ▬/▬►720
SS 349.8 ▬/▬►350 351.1 ▬/▬►350
SS ▬/▬►1410 ▬/▬►1410
B (7.00)7.03 ▬▬►7.02 6.99 ▬/▬►7.02
B (4.00)3.99 ▬▬►4.00 3.96 ▬/▬►4.00
B (10.00)10.07 ▬/▬►10.06 10.06 ▬/▬►10.06
19.86 20.02
pH Check B (7.00)▬▬►7.13
Time:0.00
440 ▬▬►442 440 ▬/▬►441
N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 19.77 19.89
TEMP (CO)
BP (mmHg)
COND
100 % mg/L 9.10 ▬▬►9.07 9.05 ▬/▬►9.01
After Cal 9.06 99.88 9.05 100.42
LCS 9.08 100.10 9.05 100.42
LCSD 9.05 -0.33 9.00 -0.56
SS 54.0 ▬/▬►53.6 54.0 ▬/▬►53.6
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 746.4 (mmHg)Ending BP 745.4
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION PASS CALIBRATION PASS
DO
(mg/L)
19.28 19.30
747.85 743.40
95.2
CALIBRATION PASS CALIBRATION PASS
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
96.4
ORP Temp.ORP Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.Buffer Temp.
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Parameter Calibration Results Calibration Results
CALIBRATION BP (mmHg)747.85 CALIBRATION BP (mmHg)743.40
Calibration Date / Time 3-Nov-16 445 4-Nov-16 640
PROCEDURE #:HYDROLAB 3210.6 VALIDATED BY:
FIELD SAMPLING CALIBRATION FORM
STUDY:BELEWS CREEK STEAM STATION - FGD LANDFILL GROUNDWATER MONITORING
DATE (s):November 3, 2016 SURFACE UNIT READER:LDC
OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW Mostly clear, slight breeze, 60 to 75 deg F
COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:S06479
ANALYZER MODEL#:MS5 66120
A-1
ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬/▬►0.0
SS 717.6 ▬▬►720 724.3 ▬/▬►720
SS 347.5 ▬/▬►350 346.0 ▬/▬►350
SS ▬/▬►1410 ▬/▬►1410
B (7.00)7.01 ▬▬►7.02 6.95 ▬/▬►7.02
B (4.00)3.98 ▬▬►4.00 3.94 ▬/▬►4.00
B (10.00)10.08 ▬/▬►10.06 10.14 ▬/▬►10.06
19.93 20.02
pH Check B (7.00)▬▬►7.13
Time:0.00
441 ▬▬►441 443 ▬/▬►442
N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 19.90 19.79
TEMP (CO)
BP (mmHg)
COND
100 % mg/L 9.09 ▬▬►9.07 9.02 ▬/▬►9.02
After Cal 9.06 99.94 8.97 99.39
LCS 9.09 100.27 9.00 99.73
LCSD 9.08 -0.11 9.00 0.00
SS 52.6 ▬/▬►53.2 54.4 ▬/▬►53.2
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 746.4 (mmHg)Ending BP 745.4
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION PASS CALIBRATION PASS
DO
(mg/L)
19.31 19.23
747.85 743.40
89.4
CALIBRATION PASS CALIBRATION PASS
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
90.7
ORP Temp.ORP Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.Buffer Temp.
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Parameter Calibration Results Calibration Results
CALIBRATION BP (mmHg)747.85 CALIBRATION BP (mmHg)743.40
Calibration Date / Time 3-Nov-16 410 4-Nov-16 615
PROCEDURE #:HYDROLAB 3210.6 VALIDATED BY:
FIELD SAMPLING CALIBRATION FORM
STUDY:BELEWS CREEK STEAM STATION - FGD LANDFILL GROUNDWATER MONITORING
DATE (s):November 3, 2016 SURFACE UNIT READER:PSP
OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW Mostly clear, slight breeze, 60 to 75 deg F
COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:0722
ANALYZER MODEL#:HL4 400440
A-2
37.30 52.30
(psi)(sec)(sec)
(gal)
2.35 (gal)
@
QC By:
WATER LEVEL ONLY
DATE TIME
DISSOLVED
OXYGEN
11/3/2016 0845
ORP
(ft)(YES/NO)
N/A N/A N/A N/A N/A
VOLUME EVACUATION COND.
PURGE METHOD
Level Only
DISCHARGERECHARGEPRESSURE
PUMP CONTROLLER SETTINGS
0.1631CONVERSION FACTOR
Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
2.35WELL VOLUME
FIELD CREW LDC, PSP
MONITORING WELL INFORMATION
2
N/A
PROCEDURE NO 3175.4DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
FOR LEVEL ONLY
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID
PROJECT NAME FGD LANDFILL GROUNDWATER
SAMPLING DATE(s)3-Nov-2016
45.10
N/APUMP INTAKE DEPTH (ft TOC)52.30
TOC ELEV (ft msl)
GS ELEV (ft msl)
777.80
775.78
WELL/LOCATION NAME BC-7
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29
WELL DEPTH (ft TOC)
WELL DIAMETER (in)MIDDLE OF WETTED SCREEN (ft toc)
WELL VOL
SCREEN INTERVAL (ft TOC)TO
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)37.90 WATER COLUMN (ft)14.40
EQUIPMENT INFORMATION
LEVEL METER SERIAL#3320-T SAMPLING EQUIPMENT
TUBING DIAMETER (in)
LEVEL ONLY
PURGE COMPLETE TEMP SPECIFIC pH TURBIDITY
WATER ELEVATION (ft msl)739.90
APPEARANCE
DETECTED ODOR None
WATER LEVEL
AFTER PURGE *(recalculates on
current water
level)(deg C)(umho/cm)(SU)(NTU)(mV-NHE)(mg/L)
N/A N/A N/A
CHLORINE (mg/l)SAMPLE COLLECTED BY
PSP N/A
TOTAL PURGE
VOLUME
0.00
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
Good Condition
Good Tag
WELL CASING
WELL CONDITION
PROTECTIVE CASING
WELL PAD
WELL TAG
Good Condition
Good Condition
Sample preservation verified to pH
(units)N/A
SAMPLING NOTES
Well pad covered with grass
ADDITIONAL WELL CONDITION NOTES
A-3
14.22 24.22
12 (psi)10 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 1.10 (gal)LDC 11/3/2016 1255 NA
DRAW-DOWN 0.75 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.50 (gal)SAMPLE COLLECTED BY DATE TIME
N/A12:50 17.89 210 19.79 1015 5.26 14.0 378 8.05
N/A
12:45 17.89 210 19.62 1000 5.27 9.7 375 8.11 N/A
12:40 17.89 210 19.39 1007 5.29 2.7 369 8.10
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)17.14 WATER COLUMN (ft)7.08 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)740.08 WELL VOLUME 1.15
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
3310-t SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
Target 200 mL/min.
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)757.22 MIDDLE OF WETTED SCREEN (ft toc)20.68
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)24.22 GS ELEV (ft msl)754.58 PUMP INTAKE DEPTH (ft TOC)23.22
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)3-Nov-2016 WELL/LOCATION NAME BC-20
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
A-4
6.77 16.77
10 (psi)10 (sec)(sec)
(gal)
353 (ml)
495 (ml)
848 (ml)=0.22 (gal)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR EQUIPMENT PURGE ONLY SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)3-Nov-2016 WELL/LOCATION NAME BC-21
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)756.69 MIDDLE OF WETTED SCREEN (ft toc)14.80
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)16.77 GS ELEV (ft msl)753.42 PUMP INTAKE DEPTH (ft TOC)16.27
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 7
3310-T SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Equip. Only Purge
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)12.82 WATER COLUMN (ft)3.95 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)743.87 WELL VOLUME 0.64
(ft)(ml/min)(ft)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
WATER LEVEL RATE WATER LEVEL TEMP COND.pH TURBIDITY ORP OXYGEN
18.1 409 6.06 N/A
Tubing Volume Removed 0.25 gal EQUIPMENT PURGE ONLY SAMPLE CHLORINE
(mg/l)Pump (Bladder) Volume
12.82 210 Below pump 19.99 853 5.06
NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
SAMPLE COLLECTED BY DATE TIME
Total Purge Volume LDC 11/3/2016 1215
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
The water level was very near the top of the pump. Probably would not have been able to measure draw down in the well for low flow sampling. Since WL was within the
screened interval, an equipment purge sampling was the protocol used.
A-5
3.00 13.00
8 (psi)8 (sec)(sec)
(gal)
1.30 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)3-Nov-2016 WELL/LOCATION NAME BC-22
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)765.91 MIDDLE OF WETTED SCREEN (ft toc)9.03
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)13.00 GS ELEV (ft msl)763.72 PUMP INTAKE DEPTH (ft TOC)11.50
Target 500 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 7
3310-T SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)5.06 WATER COLUMN (ft)7.94 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)760.85 WELL VOLUME 1.30
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.50 NO 17.43 228 5.45 6.2 383
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
5.16
1.50 NO 17.46 235 5.45 2.3 387 5.10
1.50 NO 17.42 231 5.45 3.5 385 5.13
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
4.50 LDC 11/3/2016 1150 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition Could not inspect well pad due to weeds surrounding well
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
A-6
76.21 101.21
60 (psi)15 (sec)(sec)
(gal)
3.69 (gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)3-Nov-2016 WELL/LOCATION NAME BC-23A
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)863.79 MIDDLE OF WETTED SCREEN (ft toc)89.89
SCREEN LENGTH (ft)25.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)101.21 GS ELEV (ft msl)862.56 PUMP INTAKE DEPTH (ft TOC)98.71
Target 200 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
3310-T SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)78.56 WATER COLUMN (ft)22.65 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)785.23 WELL VOLUME 3.69
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
3.75 87.77 NO 15.37 42 5.67 54.0 376
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
7.95 2.19
2.25 NO 15.43 44 5.78 15.1 382 7.96
2.25 NO 15.48 44 5.76 26.7 380 7.99
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
8.25 LDC 11/3/2016 0845 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition Needed mowing around well - high grass / weeds
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
A-7
11.15 26.15
8 (psi)10 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)3-Nov-2016 WELL/LOCATION NAME BC-25
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)748.43 MIDDLE OF WETTED SCREEN (ft toc)21.65
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)26.15 GS ELEV (ft msl)745.97 PUMP INTAKE DEPTH (ft TOC)25.65
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
3320-T SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)17.14 WATER COLUMN (ft)9.01 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)731.29 WELL VOLUME 1.47
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
12:45 17.53 200 20.27 1572 5.26 12.0 329 2.94 N/A
12:40 17.53 200 20.26 1620 5.25 16.7 321 3.07
N/A12:50 17.52 200 20.55 1559 5.28 12.2 333 3.14
DRAW-DOWN 0.38 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.75 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 1.30 (gal)PSP 11/3/2016 1255 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition Originally a flush mount well, it was converted to a stick-up well by adding a riser to
the well casing during June 2015. The original well depth from TOC was 23.15 ft. June
29, 2015 the dedicated pumps were re-set by adding new tubing. Well depth from TOC
was re-measured at 26.15 ft. and updated on this blankform.
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
If well is pumped with no energy discharge (8 to 10 psi) turbidity will decrease below 10 ntu.
A-8
8.26 23.26
13 (psi)10 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)3-Nov-2016 WELL/LOCATION NAME BC-26
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)749.32 MIDDLE OF WETTED SCREEN (ft toc)20.39
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)23.26 GS ELEV (ft msl)747.21 PUMP INTAKE DEPTH (ft TOC)22.26
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
3320-T SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)17.51 WATER COLUMN (ft)5.75 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)731.81 WELL VOLUME 0.94
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
11:55 18.61 270 16.73 188 4.79 8.4 375 4.00 N/A
11:50 18.61 270 16.77 190 4.83 9.3 374 3.95
N/A12:00 18.61 270 16.65 186 4.78 12.2 376 3.83
DRAW-DOWN 1.10 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 1.75 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 2.50 (gal)PSP 11/3/2016 1205 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
A-9
23.33 38.33
17 (psi)10 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)3-Nov-2016 WELL/LOCATION NAME BC-27
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)764.78 MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)38.33 GS ELEV (ft msl)762.44 PUMP INTAKE DEPTH (ft TOC)37.83
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
3320-T SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)SEE NOTE WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
10:50 ????120 18.99 115 5.30 12.5 271 1.81 N/A
10:45 ????120 18.88 114 5.37 16.7 274 1.35
N/A
11:00 ????120 19.65 116 5.21 4.8 264 1.69 N/A
10:55 ????120 19.35 115 5.24 9.5 268 1.61
DRAW-DOWN 0.00 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.25 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 0.75 (gal)PSP 11/3/2016 1105 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition Originally a flush mount well, it was converted to a stick-up well by adding a riser to
the well casing during June 2015. The original well depth from TOC was 34.95 ft. June
29, 2015 the dedicated pumps were re-set by adding new tubing. Well depth from TOC
was re-measured at 38.33 ft. and updated on this blankform.
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Initial water level was below top of pump, could not get water level probe past pump to measure. Could not remove pump to measure, and get an accurate water level while
maintaining quality sample.
A-10
45.20 60.20
30 (psi)10 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)3-Nov-2016 WELL/LOCATION NAME BC-28
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)818.09 MIDDLE OF WETTED SCREEN (ft toc)54.70
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)60.20 GS ELEV (ft msl)816.02 PUMP INTAKE DEPTH (ft TOC)59.20
Target 150 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
3310-T SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)49.19 WATER COLUMN (ft)11.01 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)768.90 WELL VOLUME 1.80
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
10:30 51.33 150 16.41 55 5.64 5.9 354 7.63 N/A
10:25 51.33 150 16.62 56 5.66 2.1 345 7.76
N/A10:35 51.33 150 16.41 55 5.60 12.2 361 7.57
DRAW-DOWN 2.14 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.50 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 0.90 (gal)LDC 11/3/2016 1040 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition Hinge on protective casing lid is broken
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
A-11
10.32 25.32
12 (psi)10 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)3-Nov-2016 WELL/LOCATION NAME BC-29
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)756.20 MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)25.32 GS ELEV (ft msl)752.28 PUMP INTAKE DEPTH (ft TOC)18.28
Target 200 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
3320-T SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)SEE NOTE WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
9:15 ????180 16.67 72 5.16 17.5 376 2.42 N/A
9:10 ????180 16.64 76 5.17 36.1 378 2.35
N/A
9:25 ????180 16.73 70 5.15 5.8 375 2.46 N/A
9:20 ????180 16.68 70 5.17 7.9 375 2.42
DRAW-DOWN 0.00 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.50 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 1.25 (gal)PSP 11/3/2016 0930 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Initial water level was below top of pump, could not get water level probe past pump to measure. Could not remove pump to measure, and get an accurate water level while
maintaining quality samples.
A-12
19.10 34.10
17 (psi)13 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)3-Nov-2016 WELL/LOCATION NAME BC-30
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)775.72 MIDDLE OF WETTED SCREEN (ft toc)30.96
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)34.10 GS ELEV (ft msl)773.91 PUMP INTAKE DEPTH (ft TOC)33.60
Target 200 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 7
3320-T SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)27.81 WATER COLUMN (ft)6.29 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)747.91 WELL VOLUME 1.03
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
8:15 28.71 180 14.79 68 5.73 3.1 354 7.54 N/A
8:10 28.71 180 14.76 68 5.75 3.3 352 7.59
N/A8:20 28.71 180 14.80 68 5.73 3.7 356 7.56
DRAW-DOWN 0.90 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 1.50 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 2.00 (gal)PSP 11/3/2016 0825 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition Well pad covered with grass.
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Well located in middle of field.
A-13
63.30 83.30
30 (psi)10 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)3-Nov-2016 WELL/LOCATION NAME BC-31
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)816.40 MIDDLE OF WETTED SCREEN (ft toc)73.30
SCREEN LENGTH (ft)20.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)83.30 GS ELEV (ft msl)813.43 PUMP INTAKE DEPTH (ft TOC)82.00
Target 140 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
3310-T SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)58.72 WATER COLUMN (ft)24.58 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)757.68 WELL VOLUME 4.01
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
9:15 61.71 140 16.27 134 6.03 5.2 241 3.20 N/A
9:10 61.71 140 16.58 131 5.94 3.5 283 3.92
N/A
9:25 61.71 140 16.39 120 6.03 3.7 264 4.17 N/A
9:20 61.71 140 16.29 124 6.03 4.8 251 3.81
N/A
9:35 61.71 140 16.67 117 6.04 2.1 281 4.97 N/A
9:30 61.71 140 16.57 118 6.03 2.4 273 4.76
N/A9:40 61.71 140 17.24 117 6.04 1.7 285 5.25
DRAW-DOWN 2.99 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.50 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 1.65 (gal)LDC 11/3/2016 0945 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition Tall weeds around well - could not inspect well pad.
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
A-14
18.01 33.01
15 (psi)7 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 1.15 (gal)LDC 11/3/2016 1115 NA
DRAW-DOWN 1.08 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.50 (gal)SAMPLE COLLECTED BY DATE TIME
N/A11:10 18.62 240 17.50 1569 5.33 2.2 392 5.74
N/A
11:05 18.62 240 17.43 1572 5.33 3.0 392 5.75 N/A
11:00 18.62 240 17.92 1586 5.32 2.5 391 5.46
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
2.52
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)17.54 WATER COLUMN (ft)15.47 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)739.02 WELL VOLUME
Target 240 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 8
3310-T SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)756.56 MIDDLE OF WETTED SCREEN (ft toc)25.51
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)33.01 GS ELEV (ft msl)753.62 PUMP INTAKE DEPTH (ft TOC)32.01
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)3-Nov-2016 WELL/LOCATION NAME BC-32
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
A-15
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)3-Nov-2016 WELL/LOCATION NAME BC-SW1
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
Surface Water Location PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT GRAB PURGE METHOD
TUBING DIAMETER (in)No Purge
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
PSP 11/3/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 15.90 146 7.49 6.6
1320
204 9.19
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
A-16
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)3-Nov-2016 WELL/LOCATION NAME BC-LEACHATE
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)No Purge
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
PSP 11/3/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 17.34 2867 6.41 0.9
1010
350 6.51
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
A-17
PERMIT #
BC-7 BC-20 BC-21 BC-22 BC-23A BC-25 BC-26 BC-27 BC-28 BC-29 BC-30 BC-31 BC-32 BC-SW1
YES YES YES YES SEE NOTE YES YES YES YES YES YES YES YES YES
YES YES YES YES SEE NOTE YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A
YES YES YES SEE NOTE YES YES YES YES YES YES SEE NOTE SEE NOTE YES N/A
YES YES YES YES YES YES YES YES YES YES YES YES N/A
YES
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A
N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A
Lacks required information - Total well depth
Lacks required information - Depth to screen
Lacks required information - Non potable tag
NOTE:Due to tall grass and weeds surrounding the wells the concrete pads could not be inspected for cracks at BC-22, BC-30, and BC-31. The grass and weeds around and leading into BC-23A needed mowing. The hinge on the protective casing lid
for BC-28 is broken.
Lacks required information - Completion date
FLUSH MOUNT WELLS
Vault in good condition
Water inside vault
Vault bolt holes broken or stripped
Bolts stripped
Vault lid cracked or broken
WELL ID TAGS
Well tag in good condition
Well tag missing
Well tag damaged / illegible
Lacks required information - Driller Reg #
Replaced damaged well cap
Fire ants around concrete pad
WELL PROTECTIVE CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
Broken hinge on protective lid
Wasp nest inside protective casing
Ants inside protective casing
WELL CAPS
Well cap in good conditon
Damaged / needs replacement
Undermined / washing out
Lock in good condition
Lock rusted, difficult to open / needs replacing
Replaced damaged lock
WELL CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
CONCRETE PADS
Pad in good condition
Minor cracks
Major cracks / broken / repair required
WELL LOCK CONDITION
PAGE 1 OF 1
ACCESS TO WELLS
Access cleared into well
Access cleared around well
Tall grass or weeds - needs mowing
Road washing out / muddy / needs grading
Fallen tree blocking access
WELL SECURITY
Well found locked
Well found unlocked
SITE CONTACT Melonie Martin, Kimberly Witt, Will Harrison, Keeley McCormick FIELD CREW LDC, PSP
WEATHER Mostly clear, slight breeze, 60 to 75 deg F
NORTH CAROLINA GROUNDWATER SAMPLING SITE CHECKLIST
LOCATION / SITE BELEWS CREEK STEAM STATION - FGD LANDFILL GROUNDWATER MONITORING 85-05 SAMPLE DATE November 3, 2016
A-18
WELL DEPTH TO WATER Purge AVG *WELL EVAC SPECIFIC
WELL DEPTH WATER ELEV.Method PMP RATE VOL VOL EVAC TEMP CONDUCTANCE pH TURBIDITY ORP DO
DATE NO.(feet-toc)(feet-toc)(feet)APPEARANCE ODOR (ml/min)(gal)(gal)(yes/no)(deg C)(umho/cm)(units)(NTU)(mV-NHE)(mg/l)
11/3/2016 BC-7 52.30 37.90 739.90 N/A N/A LO N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
11/3/2016 BC-20 24.22 17.14 740.08 Normal None LF 210 1.15 1.10 N/A 19.79 1015 5.3 14.0 378 8.05
11/3/2016 BC-21 16.77 12.82 743.87 Normal None EOP N/A 0.64 0.22 N/A 19.99 853 5.1 18.1 409 6.06
11/3/2016 BC-22 13.00 5.06 760.85 Normal None C N/A 1.30 4.50 NO 17.46 235 5.5 2.3 387 5.10
11/3/2016 BC-23A 101.21 78.56 785.23 Normal None C N/A 3.69 8.25 NO 15.43 44 5.8 15.1 382 7.96
11/3/2016 BC-25 26.15 17.14 731.29 Normal None LF 200 1.47 1.30 N/A 20.55 1559 5.3 12.2 333 3.14
11/3/2016 BC-26 23.26 17.51 731.81 Normal None LF 270 0.94 2.50 N/A 16.65 186 4.8 12.2 376 3.83
11/3/2016 BC-27 38.33 SEE NOTE Normal None LF 120 ---0.75 N/A 19.65 116 5.2 4.8 264 1.69
11/3/2016 BC-28 60.20 49.19 768.90 Normal None LF 150 1.80 0.90 N/A 16.41 55 5.6 12.2 361 7.57
11/3/2016 BC-29 25.32 SEE NOTE Normal None LF 180 ---1.25 N/A 16.73 70 5.2 5.8 375 2.46
11/3/2016 BC-30 34.10 27.81 747.91 Normal None LF 180 1.03 2.00 N/A 14.80 68 5.7 3.7 356 7.56
11/3/2016 BC-31 83.30 58.72 757.68 Normal None LF 140 4.01 1.65 N/A 17.24 117 6.0 1.7 285 5.25
11/3/2016 BC-32 33.01 17.54 739.02 Normal None LF 240 2.52 1.15 N/A 17.50 1569 5.3 2.2 392 5.74
11/3/2016 BC-SW1 0.00 N/A N/A Normal None NP N/A N/A N/A N/A 15.90 146 7.5 6.6 204 9.19
11/3/2016 BC-LEACHATE 0.00 N/A N/A Normal None NP N/A N/A N/A N/A 17.34 2867 6.4 0.9 350 6.51
Purge Methods
LF = Low Flow
LF(M) = Low Flow (Mod.)
C = Connventional
NP = No Purge
EOP = Equip. Only Purge
LO = Level Only
Note Initial water level was below top of pump, could not get water level probe past pump to measure. Could not remove pump to measure, and get an accurate water level while maintaining quality samples.
* = Applicable to LF & LF(M) Purging Only
BELEWS CREEK STEAM STATION
FGD LANDFILL GROUNDWATER
GROUNDWATER MONITORING FIELD DATA
PERMIT #85-05
A-19

B
Appendix B
Laboratory Report and
Chain-of-Custody Forms

13339 Hagers Ferry RoadHuntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16100617
Project Name:BELEWS - GW FGD LF
Lab Contact: Anne Pridgeon
Date:11/18/2016
Customer Address:3195 Pine Hall Rd
Customer Name(s):Chuck Campbell, T. Hunsucker, Ed Sullivan
Mailcode: Belews Steam Station
Belews Creek, NC 28012
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Method 2540C: The current reported result for total dissolved solids is well below historical limits for the leachate sample in this
data set. Upon inspection of sample however, matrix appeared clean and void of any color or turbidity. Since leachates often exhibit erratic results, the current reported value was not confirmed and data has been reported accordingly.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 29
Reason: I have reviewed
this document.
Date: 2016.11.18 09:32:13
-05'00'
B-1
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection Date and Time Collected By Sample Description
2016034439 BELEWS 03-Nov-16 12:55 PM LDC BC-20
2016034440 BELEWS 03-Nov-16 12:15 PM LDC BC-21
2016034441 BELEWS 03-Nov-16 11:50 AM LDC BC-22
2016034442 BELEWS 03-Nov-16 8:45 AM LDC BC-23A
2016034443 BELEWS 03-Nov-16 12:55 PM PSP BC-25
2016034444 BELEWS 03-Nov-16 12:05 PM PSP BC-26
2016034445 BELEWS 03-Nov-16 11:05 AM PSP BC-27
2016034446 BELEWS 03-Nov-16 10:40 AM LDC BC-28
2016034447 BELEWS 03-Nov-16 9:30 AM PSP BC-29
2016034448 BELEWS 03-Nov-16 8:25 AM PSP BC-30
2016034449 BELEWS 03-Nov-16 9:45 AM LDC BC-31
2016034450 BELEWS 03-Nov-16 11:15 AM LDC BC-32
2016034451 BELEWS 03-Nov-16 1:20 PM PSP SW-1
2016034452 BELEWS 03-Nov-16 10:10 AM PSP LEACHATE
2016034453 BELEWS 03-Nov-16 1:35 PM PSP FIELD BLANK
15 Total Samples
Duke Energy Analytical Lab
Page 2 of 29
B-2
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:11/16/2016
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab
Page 3 of 29
B-3
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
2016034439
Collection Date:03-Nov-16 12:55 PM
Site:BC-20
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)5.9 mg/L
(CaCO3)
SM 2320B 11/07/2016 14:44 CJELLIO51
INORGANIC IONS BY IC
Chloride 4.1 mg/L EPA 9056A 11/04/2016 13:36 BGN90340.5 5
Fluoride < 0.5 mg/L EPA 9056A 11/04/2016 13:36 BGN90340.5 5
Nitrate 12 mg/L EPA 9056A 11/04/2016 13:36 BGN90340.5 5
Nitrate as N 2.6 mg-N/L EPA 9056A 11/04/2016 13:36 BGN90340.023 1
Sulfate 540 mg/L EPA 9056A 11/04/2016 13:36 BGN903410100
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/04/2016 14:37 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.107 mg/L SW 6010D 11/13/2016 20:32 MHALL30.005 1
Boron (B)< 0.05 mg/L SW 6010D 11/13/2016 20:32 MHALL30.05 1
Calcium (Ca)116 mg/L SW 6010D 11/13/2016 20:32M4 MHALL30.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 20:32 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 20:32 MHALL30.005 1
Iron (Fe)1.03 mg/L SW 6010D 11/13/2016 20:32 MHALL30.01 1
Magnesium (Mg)48.4 mg/L SW 6010D 11/13/2016 20:32M4 MHALL30.05 10
Manganese (Mn)0.021 mg/L SW 6010D 11/13/2016 20:32 MHALL30.005 1
Nickel (Ni)0.015 mg/L SW 6010D 11/13/2016 20:32 MHALL30.005 1
Potassium (K)6.53 mg/L SW 6010D 11/13/2016 20:32 MHALL30.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 20:32 MHALL30.005 1
Sodium (Na)27.1 mg/L SW 6010D 11/13/2016 20:32 MHALL30.05 1
Zinc (Zn)0.016 mg/L SW 6010D 11/13/2016 20:32 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/07/2016 23:34 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/07/2016 23:34 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/07/2016 23:34 CWSPEN311
Selenium (Se)3.85 ug/L SW 6020B 11/07/2016 23:34 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 810 mg/L SM2540C 11/09/2016 17:15 CJELLIO251
Duke Energy Analytical Lab
Page 4 of 29
B-4
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
2016034440
Collection Date:03-Nov-16 12:15 PM
Site:BC-21
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 11/07/2016 14:44 CJELLIO51
INORGANIC IONS BY IC
Chloride 23 mg/L EPA 9056A 11/05/2016 10:47 BGN90340.5 5
Fluoride < 0.5 mg/L EPA 9056A 11/05/2016 10:47 BGN90340.5 5
Nitrate 67 mg/L EPA 9056A 11/05/2016 10:47 BGN9034220
Nitrate as N 15 mg-N/L EPA 9056A 11/05/2016 10:47 BGN90340.023 1
Sulfate 360 mg/L EPA 9056A 11/05/2016 10:47 BGN903410100
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/04/2016 14:40 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.041 mg/L SW 6010D 11/13/2016 20:44 MHALL30.005 1
Boron (B)< 0.05 mg/L SW 6010D 11/13/2016 20:44 MHALL30.05 1
Calcium (Ca)61.9 mg/L SW 6010D 11/13/2016 20:44 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 20:44 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 20:44 MHALL30.005 1
Iron (Fe)0.329 mg/L SW 6010D 11/13/2016 20:44 MHALL30.01 1
Magnesium (Mg)48.5 mg/L SW 6010D 11/13/2016 20:44 MHALL30.05 10
Manganese (Mn)0.051 mg/L SW 6010D 11/13/2016 20:44 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 11/13/2016 20:44 MHALL30.005 1
Potassium (K)3.48 mg/L SW 6010D 11/13/2016 20:44 MHALL30.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 20:44 MHALL30.005 1
Sodium (Na)11.8 mg/L SW 6010D 11/13/2016 20:44 MHALL30.05 1
Zinc (Zn)0.012 mg/L SW 6010D 11/13/2016 20:44 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)1.03 ug/L SW 6020B 11/07/2016 23:41 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/07/2016 23:41 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/07/2016 23:41 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 11/07/2016 23:41 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 540 mg/L SM2540C 11/09/2016 17:15 CJELLIO251
Duke Energy Analytical Lab
Page 5 of 29
B-5
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
2016034441
Collection Date:03-Nov-16 11:50 AM
Site:BC-22
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)19 mg/L
(CaCO3)
SM 2320B 11/07/2016 14:44 CJELLIO51
INORGANIC IONS BY IC
Chloride 4.8 mg/L EPA 9056A 11/04/2016 14:09 BGN90340.5 5
Fluoride < 0.5 mg/L EPA 9056A 11/04/2016 14:09 BGN90340.5 5
Nitrate 12 mg/L EPA 9056A 11/04/2016 14:09 BGN90340.5 5
Nitrate as N 2.6 mg-N/L EPA 9056A 11/04/2016 14:09 BGN90340.023 1
Sulfate 77 mg/L EPA 9056A 11/04/2016 14:09 BGN90342.5 25
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/15/2016 13:16 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.116 mg/L SW 6010D 11/13/2016 20:48 MHALL30.005 1
Boron (B)< 0.05 mg/L SW 6010D 11/13/2016 20:48 MHALL30.05 1
Calcium (Ca)19.5 mg/L SW 6010D 11/13/2016 20:48 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 20:48 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 20:48 MHALL30.005 1
Iron (Fe)0.427 mg/L SW 6010D 11/13/2016 20:48 MHALL30.01 1
Magnesium (Mg)8.31 mg/L SW 6010D 11/13/2016 20:48 MHALL30.005 1
Manganese (Mn)0.073 mg/L SW 6010D 11/13/2016 20:48 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 11/13/2016 20:48 MHALL30.005 1
Potassium (K)2.70 mg/L SW 6010D 11/13/2016 20:48 MHALL30.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 20:48 MHALL30.005 1
Sodium (Na)10.2 mg/L SW 6010D 11/13/2016 20:48 MHALL30.05 1
Zinc (Zn)0.006 mg/L SW 6010D 11/13/2016 20:48 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/07/2016 23:48 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/07/2016 23:48 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/07/2016 23:48 CWSPEN311
Selenium (Se)1.04 ug/L SW 6020B 11/07/2016 23:48 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 170 mg/L SM2540C 11/09/2016 17:15 CJELLIO251
Duke Energy Analytical Lab
Page 6 of 29
B-6
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
2016034442
Collection Date:03-Nov-16 8:45 AM
Site:BC-23A
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)18 mg/L
(CaCO3)
SM 2320B 11/07/2016 14:44 CJELLIO51
INORGANIC IONS BY IC
Chloride 2.1 mg/L EPA 9056A 11/04/2016 11:11 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 11/04/2016 11:11 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 11/04/2016 11:11 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 11/04/2016 11:11 BGN90340.023 1
Sulfate 0.18 mg/L EPA 9056A 11/04/2016 11:11 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/15/2016 13:18 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.036 mg/L SW 6010D 11/13/2016 20:52 MHALL30.005 1
Boron (B)0.110 mg/L SW 6010D 11/13/2016 20:52 MHALL30.05 1
Calcium (Ca)3.32 mg/L SW 6010D 11/13/2016 20:52 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 20:52 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 20:52 MHALL30.005 1
Iron (Fe)0.464 mg/L SW 6010D 11/13/2016 20:52 MHALL30.01 1
Magnesium (Mg)1.13 mg/L SW 6010D 11/13/2016 20:52 MHALL30.005 1
Manganese (Mn)0.010 mg/L SW 6010D 11/13/2016 20:52 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 11/13/2016 20:52 MHALL30.005 1
Potassium (K)1.57 mg/L SW 6010D 11/13/2016 20:52 MHALL30.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 20:52 MHALL30.005 1
Sodium (Na)5.82 mg/L SW 6010D 11/13/2016 20:52 MHALL30.05 1
Zinc (Zn)0.008 mg/L SW 6010D 11/13/2016 20:52 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/07/2016 23:55 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/07/2016 23:55 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/07/2016 23:55 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 11/07/2016 23:55 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 54 mg/L SM2540C 11/09/2016 17:15 CJELLIO251
Duke Energy Analytical Lab
Page 7 of 29
B-7
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
2016034443
Collection Date:03-Nov-16 12:55 PM
Site:BC-25
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)14 mg/L
(CaCO3)
SM 2320B 11/07/2016 14:44 CJELLIO51
INORGANIC IONS BY IC
Chloride 27 mg/L EPA 9056A 11/04/2016 14:26 BGN9034110
Fluoride < 1 mg/L EPA 9056A 11/04/2016 14:26 BGN9034110
Nitrate 11 mg/L EPA 9056A 11/04/2016 14:26 BGN9034110
Nitrate as N 2.5 mg-N/L EPA 9056A 11/04/2016 14:26 BGN90340.023 1
Sulfate 970 mg/L EPA 9056A 11/04/2016 14:26 BGN903420200
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/15/2016 13:21 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.061 mg/L SW 6010D 11/13/2016 20:56 MHALL30.005 1
Boron (B)< 0.05 mg/L SW 6010D 11/13/2016 20:56 MHALL30.05 1
Calcium (Ca)186 mg/L SW 6010D 11/13/2016 20:56 MHALL30.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 20:56 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 20:56 MHALL30.005 1
Iron (Fe)0.728 mg/L SW 6010D 11/13/2016 20:56 MHALL30.01 1
Magnesium (Mg)94.6 mg/L SW 6010D 11/13/2016 20:56 MHALL30.05 10
Manganese (Mn)0.053 mg/L SW 6010D 11/13/2016 20:56 MHALL30.005 1
Nickel (Ni)0.036 mg/L SW 6010D 11/13/2016 20:56 MHALL30.005 1
Potassium (K)9.10 mg/L SW 6010D 11/13/2016 20:56 MHALL30.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 20:56 MHALL30.005 1
Sodium (Na)30.0 mg/L SW 6010D 11/13/2016 20:56 MHALL30.05 1
Zinc (Zn)0.051 mg/L SW 6010D 11/13/2016 20:56 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/08/2016 00:02 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/08/2016 00:02 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/08/2016 00:02 CWSPEN311
Selenium (Se)9.70 ug/L SW 6020B 11/08/2016 00:02 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 1300 mg/L SM2540C 11/09/2016 17:15 CJELLIO251
Duke Energy Analytical Lab
Page 8 of 29
B-8
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
2016034444
Collection Date:03-Nov-16 12:05 PM
Site:BC-26
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 11/07/2016 14:44 CJELLIO51
INORGANIC IONS BY IC
Chloride 21 mg/L EPA 9056A 11/04/2016 13:02 BGN90340.5 5
Fluoride < 0.1 mg/L EPA 9056A 11/04/2016 13:02 BGN90340.1 1
Nitrate 26 mg/L EPA 9056A 11/04/2016 13:02 BGN90340.5 5
Nitrate as N 6.0 mg-N/L EPA 9056A 11/04/2016 13:02 BGN90340.023 1
Sulfate 26 mg/L EPA 9056A 11/04/2016 13:02 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/15/2016 13:23 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.311 mg/L SW 6010D 11/13/2016 21:00 MHALL30.005 1
Boron (B)< 0.05 mg/L SW 6010D 11/13/2016 21:00 MHALL30.05 1
Calcium (Ca)3.02 mg/L SW 6010D 11/13/2016 21:00 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 21:00 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 21:00 MHALL30.005 1
Iron (Fe)1.02 mg/L SW 6010D 11/13/2016 21:00 MHALL30.01 1
Magnesium (Mg)9.00 mg/L SW 6010D 11/13/2016 21:00 MHALL30.005 1
Manganese (Mn)0.040 mg/L SW 6010D 11/13/2016 21:00 MHALL30.005 1
Nickel (Ni)0.010 mg/L SW 6010D 11/13/2016 21:00 MHALL30.005 1
Potassium (K)5.07 mg/L SW 6010D 11/13/2016 21:00 MHALL30.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 21:00 MHALL30.005 1
Sodium (Na)12.0 mg/L SW 6010D 11/13/2016 21:00 MHALL30.05 1
Zinc (Zn)0.074 mg/L SW 6010D 11/13/2016 21:00 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/08/2016 00:09 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/08/2016 00:09 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/08/2016 00:09 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 11/08/2016 00:09 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 120 mg/L SM2540C 11/09/2016 17:15 CJELLIO251
Duke Energy Analytical Lab
Page 9 of 29
B-9
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
2016034445
Collection Date:03-Nov-16 11:05 AM
Site:BC-27
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)21 mg/L
(CaCO3)
SM 2320B 11/07/2016 13:18 CJELLIO201
INORGANIC IONS BY IC
Chloride 18 mg/L EPA 9056A 11/04/2016 12:46 BGN90340.2 2
Fluoride < 0.1 mg/L EPA 9056A 11/04/2016 12:46 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 11/04/2016 12:46 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 11/04/2016 12:46 BGN90340.023 1
Sulfate 0.23 mg/L EPA 9056A 11/04/2016 12:46 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/15/2016 13:26 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.044 mg/L SW 6010D 11/13/2016 21:04 MHALL30.005 1
Boron (B)< 0.05 mg/L SW 6010D 11/13/2016 21:04 MHALL30.05 1
Calcium (Ca)0.334 mg/L SW 6010D 11/13/2016 21:04 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 21:04 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 21:04 MHALL30.005 1
Iron (Fe)8.11 mg/L SW 6010D 11/13/2016 21:04 MHALL30.01 1
Magnesium (Mg)3.59 mg/L SW 6010D 11/13/2016 21:04 MHALL30.005 1
Manganese (Mn)0.838 mg/L SW 6010D 11/13/2016 21:04 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 11/13/2016 21:04 MHALL30.005 1
Potassium (K)2.69 mg/L SW 6010D 11/13/2016 21:04 MHALL30.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 21:04 MHALL30.005 1
Sodium (Na)8.93 mg/L SW 6010D 11/13/2016 21:04 MHALL30.05 1
Zinc (Zn)0.010 mg/L SW 6010D 11/13/2016 21:04 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/08/2016 00:16 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/08/2016 00:16 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/08/2016 00:16 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 11/08/2016 00:16 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 73 mg/L SM2540C 11/09/2016 17:15 CJELLIO251
Duke Energy Analytical Lab
Page 10 of 29
B-10
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
2016034446
Collection Date:03-Nov-16 10:40 AM
Site:BC-28
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)18 mg/L
(CaCO3)
SM 2320B 11/07/2016 14:44 CJELLIO51
INORGANIC IONS BY IC
Chloride 2.0 mg/L EPA 9056A 11/04/2016 12:14 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 11/04/2016 12:14 BGN90340.1 1
Nitrate 4.1 mg/L EPA 9056A 11/04/2016 12:14 BGN90340.1 1
Nitrate as N 0.92 mg-N/L EPA 9056A 11/04/2016 12:14 BGN90340.023 1
Sulfate 0.27 mg/L EPA 9056A 11/04/2016 12:14 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/15/2016 13:28 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.031 mg/L SW 6010D 11/13/2016 21:08 MHALL30.005 1
Boron (B)< 0.05 mg/L SW 6010D 11/13/2016 21:08 MHALL30.05 1
Calcium (Ca)3.84 mg/L SW 6010D 11/13/2016 21:08 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 21:08 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 21:08 MHALL30.005 1
Iron (Fe)0.690 mg/L SW 6010D 11/13/2016 21:08 MHALL30.01 1
Magnesium (Mg)1.32 mg/L SW 6010D 11/13/2016 21:08 MHALL30.005 1
Manganese (Mn)0.012 mg/L SW 6010D 11/13/2016 21:08 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 11/13/2016 21:08 MHALL30.005 1
Potassium (K)2.23 mg/L SW 6010D 11/13/2016 21:08 MHALL30.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 21:08 MHALL30.005 1
Sodium (Na)4.59 mg/L SW 6010D 11/13/2016 21:08 MHALL30.05 1
Zinc (Zn)0.014 mg/L SW 6010D 11/13/2016 21:08 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/08/2016 00:23 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/08/2016 00:23 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/08/2016 00:23 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 11/08/2016 00:23 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 55 mg/L SM2540C 11/09/2016 17:15 CJELLIO251
Duke Energy Analytical Lab
Page 11 of 29
B-11
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
2016034447
Collection Date:03-Nov-16 9:30 AM
Site:BC-29
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)11 mg/L
(CaCO3)
SM 2320B 11/07/2016 14:44 CJELLIO51
INORGANIC IONS BY IC
Chloride 4.0 mg/L EPA 9056A 11/05/2016 11:19 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 11/05/2016 11:19 BGN90340.1 1
Nitrate 1.7 mg/L EPA 9056A 11/05/2016 11:19 BGN90340.1 1
Nitrate as N 0.39 mg-N/L EPA 9056A 11/05/2016 11:19 BGN90340.023 1
Sulfate 12 mg/L EPA 9056A 11/05/2016 11:19 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/15/2016 13:30 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.126 mg/L SW 6010D 11/13/2016 21:12 MHALL30.005 1
Boron (B)< 0.05 mg/L SW 6010D 11/13/2016 21:12 MHALL30.05 1
Calcium (Ca)1.30 mg/L SW 6010D 11/13/2016 21:12 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 21:12 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 21:12 MHALL30.005 1
Iron (Fe)0.200 mg/L SW 6010D 11/13/2016 21:12 MHALL30.01 1
Magnesium (Mg)3.53 mg/L SW 6010D 11/13/2016 21:12 MHALL30.005 1
Manganese (Mn)0.072 mg/L SW 6010D 11/13/2016 21:12 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 11/13/2016 21:12 MHALL30.005 1
Potassium (K)1.61 mg/L SW 6010D 11/13/2016 21:12 MHALL30.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 21:12 MHALL30.005 1
Sodium (Na)4.97 mg/L SW 6010D 11/13/2016 21:12 MHALL30.05 1
Zinc (Zn)0.007 mg/L SW 6010D 11/13/2016 21:12 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/08/2016 00:51 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/08/2016 00:51 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/08/2016 00:51 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 11/08/2016 00:51 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 49 mg/L SM2540C 11/09/2016 17:15 CJELLIO251
Duke Energy Analytical Lab
Page 12 of 29
B-12
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
2016034448
Collection Date:03-Nov-16 8:25 AM
Site:BC-30
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)25 mg/L
(CaCO3)
SM 2320B 11/07/2016 13:18 CJELLIO201
INORGANIC IONS BY IC
Chloride 3.2 mg/L EPA 9056A 11/04/2016 16:18 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 11/04/2016 16:18 BGN90340.1 1
Nitrate 2.6 mg/L EPA 9056A 11/04/2016 16:18 BGN90340.1 1
Nitrate as N 0.58 mg-N/L EPA 9056A 11/04/2016 16:18 BGN90340.023 1
Sulfate 0.62 mg/L EPA 9056A 11/04/2016 16:18 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/15/2016 13:33 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.017 mg/L SW 6010D 11/13/2016 21:28 MHALL30.005 1
Boron (B)< 0.05 mg/L SW 6010D 11/13/2016 21:28 MHALL30.05 1
Calcium (Ca)5.07 mg/L SW 6010D 11/13/2016 21:28 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 21:28 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 21:28 MHALL30.005 1
Iron (Fe)0.089 mg/L SW 6010D 11/13/2016 21:28 MHALL30.01 1
Magnesium (Mg)1.88 mg/L SW 6010D 11/13/2016 21:28 MHALL30.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 11/13/2016 21:28 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 11/13/2016 21:28 MHALL30.005 1
Potassium (K)1.39 mg/L SW 6010D 11/13/2016 21:28 MHALL30.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 21:28 MHALL30.005 1
Sodium (Na)5.52 mg/L SW 6010D 11/13/2016 21:28 MHALL30.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 11/13/2016 21:28 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/08/2016 00:58 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/08/2016 00:58 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/08/2016 00:58 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 11/08/2016 00:58 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 70 mg/L SM2540C 11/09/2016 17:15 CJELLIO251
Duke Energy Analytical Lab
Page 13 of 29
B-13
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
2016034449
Collection Date:03-Nov-16 9:45 AM
Site:BC-31
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)50 mg/L
(CaCO3)
SM 2320B 11/07/2016 13:18 CJELLIO201
INORGANIC IONS BY IC
Chloride 1.8 mg/L EPA 9056A 11/04/2016 15:31 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 11/04/2016 15:31 BGN90340.1 1
Nitrate 3.5 mg/L EPA 9056A 11/04/2016 15:31 BGN90340.1 1
Nitrate as N 0.80 mg-N/L EPA 9056A 11/04/2016 15:31 BGN90340.023 1
Sulfate 1.0 mg/L EPA 9056A 11/04/2016 15:31 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/15/2016 13:43 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.016 mg/L SW 6010D 11/13/2016 21:32 MHALL30.005 1
Boron (B)< 0.05 mg/L SW 6010D 11/13/2016 21:32 MHALL30.05 1
Calcium (Ca)9.30 mg/L SW 6010D 11/13/2016 21:32 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 21:32 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 21:32 MHALL30.005 1
Iron (Fe)0.096 mg/L SW 6010D 11/13/2016 21:32 MHALL30.01 1
Magnesium (Mg)4.45 mg/L SW 6010D 11/13/2016 21:32 MHALL30.005 1
Manganese (Mn)0.018 mg/L SW 6010D 11/13/2016 21:32 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 11/13/2016 21:32 MHALL30.005 1
Potassium (K)1.73 mg/L SW 6010D 11/13/2016 21:32 MHALL30.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 21:32 MHALL30.005 1
Sodium (Na)8.02 mg/L SW 6010D 11/13/2016 21:32 MHALL30.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 11/13/2016 21:32 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/08/2016 01:05 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/08/2016 01:05 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/08/2016 01:05 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 11/08/2016 01:05 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 87 mg/L SM2540C 11/09/2016 17:15 CJELLIO251
Duke Energy Analytical Lab
Page 14 of 29
B-14
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
2016034450
Collection Date:03-Nov-16 11:15 AM
Site:BC-32
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)15 mg/L
(CaCO3)
SM 2320B 11/07/2016 14:44 CJELLIO51
INORGANIC IONS BY IC
Chloride 2.3 mg/L EPA 9056A 11/04/2016 18:26 BGN9034220
Fluoride < 2 mg/L EPA 9056A 11/04/2016 18:26 BGN9034220
Nitrate 2.3 mg/L EPA 9056A 11/04/2016 18:26 BGN9034220
Nitrate as N 0.52 mg-N/L EPA 9056A 11/04/2016 18:26 BGN90340.023 1
Sulfate 950 mg/L EPA 9056A 11/04/2016 18:26 BGN903420200
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/15/2016 13:50 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.042 mg/L SW 6010D 11/13/2016 21:36 MHALL30.005 1
Boron (B)< 0.05 mg/L SW 6010D 11/13/2016 21:36 MHALL30.05 1
Calcium (Ca)167 mg/L SW 6010D 11/13/2016 21:36 MHALL30.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 21:36 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 21:36 MHALL30.005 1
Iron (Fe)0.059 mg/L SW 6010D 11/13/2016 21:36 MHALL30.01 1
Magnesium (Mg)111 mg/L SW 6010D 11/13/2016 21:36 MHALL30.05 10
Manganese (Mn)0.018 mg/L SW 6010D 11/13/2016 21:36 MHALL30.005 1
Nickel (Ni)0.015 mg/L SW 6010D 11/13/2016 21:36 MHALL30.005 1
Potassium (K)6.88 mg/L SW 6010D 11/13/2016 21:36 MHALL30.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 21:36 MHALL30.005 1
Sodium (Na)27.6 mg/L SW 6010D 11/13/2016 21:36 MHALL30.05 1
Zinc (Zn)0.022 mg/L SW 6010D 11/13/2016 21:36 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/08/2016 01:13 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/08/2016 01:13 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/08/2016 01:13 CWSPEN311
Selenium (Se)4.21 ug/L SW 6020B 11/08/2016 01:13 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 1300 mg/L SM2540C 11/09/2016 17:15 CJELLIO251
Duke Energy Analytical Lab
Page 15 of 29
B-15
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
2016034451
Collection Date:03-Nov-16 1:20 PM
Site:SW-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)44 mg/L
(CaCO3)
SM 2320B 11/07/2016 13:18 CJELLIO201
INORGANIC IONS BY IC
Chloride 4.0 mg/L EPA 9056A 11/05/2016 11:35 BGN90340.1 1
Fluoride 0.11 mg/L EPA 9056A 11/05/2016 11:35 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 11/05/2016 11:35 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 11/05/2016 11:35 BGN90340.023 1
Sulfate 14 mg/L EPA 9056A 11/05/2016 11:35 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/15/2016 13:52 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.028 mg/L SW 6010D 11/13/2016 21:40 MHALL30.005 1
Boron (B)< 0.05 mg/L SW 6010D 11/13/2016 21:40 MHALL30.05 1
Calcium (Ca)14.1 mg/L SW 6010D 11/13/2016 21:40 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 21:40 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 21:40 MHALL30.005 1
Iron (Fe)2.86 mg/L SW 6010D 11/13/2016 21:40 MHALL30.01 1
Magnesium (Mg)4.22 mg/L SW 6010D 11/13/2016 21:40 MHALL30.005 1
Manganese (Mn)0.327 mg/L SW 6010D 11/13/2016 21:40 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 11/13/2016 21:40 MHALL30.005 1
Potassium (K)2.39 mg/L SW 6010D 11/13/2016 21:40 MHALL30.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 21:40 MHALL30.005 1
Sodium (Na)5.95 mg/L SW 6010D 11/13/2016 21:40 MHALL30.05 1
Zinc (Zn)0.037 mg/L SW 6010D 11/13/2016 21:40 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/08/2016 01:20 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/08/2016 01:20 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/08/2016 01:20 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 11/08/2016 01:20 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 88 mg/L SM2540C 11/09/2016 17:15 CJELLIO251
Duke Energy Analytical Lab
Page 16 of 29
B-16
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
2016034452
Collection Date:03-Nov-16 10:10 AM
Site:LEACHATE
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)230 mg/L
(CaCO3)
SM 2320B 11/07/2016 13:18 CJELLIO201
INORGANIC IONS BY IC
Chloride 100 mg/L EPA 9056A 11/04/2016 18:58 BGN90342.5 25
Fluoride < 2.5 mg/L EPA 9056A 11/04/2016 18:58 BGN90342.5 25
Nitrate 3.6 mg/L EPA 9056A 11/04/2016 18:58 BGN90342.5 25
Nitrate as N 0.82 mg-N/L EPA 9056A 11/04/2016 18:58 BGN90340.023 1
Sulfate 1700 mg/L EPA 9056A 11/04/2016 18:58 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/15/2016 13:55 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.016 mg/L SW 6010D 11/13/2016 21:44 MHALL30.005 1
Boron (B)7.16 mg/L SW 6010D 11/13/2016 21:44 MHALL30.05 1
Calcium (Ca)651 mg/L SW 6010D 11/13/2016 21:44 MHALL30.1 10
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 21:44 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 21:44 MHALL30.005 1
Iron (Fe)0.029 mg/L SW 6010D 11/13/2016 21:44 MHALL30.01 1
Magnesium (Mg)78.0 mg/L SW 6010D 11/13/2016 21:44 MHALL30.05 10
Manganese (Mn)6.74 mg/L SW 6010D 11/13/2016 21:44 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 11/13/2016 21:44 MHALL30.005 1
Potassium (K)8.27 mg/L SW 6010D 11/13/2016 21:44 MHALL30.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 21:44 MHALL30.005 1
Sodium (Na)6.37 mg/L SW 6010D 11/13/2016 21:44 MHALL30.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 11/13/2016 21:44 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/08/2016 01:27 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/08/2016 01:27 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/08/2016 01:27 CWSPEN311
Selenium (Se)1970 ug/L SW 6020B 11/08/2016 01:27 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 230 mg/L SM2540C 11/09/2016 17:15 CJELLIO251
Duke Energy Analytical Lab
Page 17 of 29
B-17
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
2016034453
Collection Date:03-Nov-16 1:35 PM
Site:FIELD BLANK
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)< 20 mg/L
(CaCO3)
SM 2320B 11/07/2016 13:18 CJELLIO201
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 9056A 11/04/2016 09:35 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 11/04/2016 09:35 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 11/04/2016 09:35 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 11/04/2016 09:35 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 11/04/2016 09:35 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 11/15/2016 13:57 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 11/13/2016 21:48 MHALL30.005 1
Boron (B)< 0.05 mg/L SW 6010D 11/13/2016 21:48 MHALL30.05 1
Calcium (Ca)0.014 mg/L SW 6010D 11/13/2016 21:48 MHALL30.01 1
Chromium (Cr)< 0.005 mg/L SW 6010D 11/13/2016 21:48 MHALL30.005 1
Copper (Cu)< 0.005 mg/L SW 6010D 11/13/2016 21:48 MHALL30.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 11/13/2016 21:48 MHALL30.01 1
Magnesium (Mg)< 0.005 mg/L SW 6010D 11/13/2016 21:48 MHALL30.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 11/13/2016 21:48 MHALL30.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 11/13/2016 21:48 MHALL30.005 1
Potassium (K)< 0.1 mg/L SW 6010D 11/13/2016 21:48 MHALL30.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 11/13/2016 21:48 MHALL30.005 1
Sodium (Na)< 0.05 mg/L SW 6010D 11/13/2016 21:48 MHALL30.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 11/13/2016 21:48 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 11/08/2016 01:34 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 11/08/2016 01:34 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 11/08/2016 01:34 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 11/08/2016 01:34 CWSPEN311
Qualifiers:
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate to the spike level. The associated Laboratory Control Spike recovery was acceptable.
Duke Energy Analytical Lab
Page 18 of 29
B-18
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
Q16110248 ALK_FIX4.5 ALKALINITY (FIXED END POINT 4.5)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3)75.7 94.5mg/L (CaCO3)-12080171.6
Duke Energy Analytical Lab
Page 19 of 29
B-19
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
Q16110249 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16100617 -- 2016034439
Alkalinity (mg/L CaCO3)2.91mg/L (CaCO3)-16.04
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3)7.57 95.2mg/L (CaCO3)-1208017.21
Duke Energy Analytical Lab
Page 20 of 29
B-20
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
Q16110145 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0278 mg/L -10.0278 0.1 < 1/2 RDL
Fluoride 0.028 mg/L -10.028 0.1 < 1/2 RDL
Nitrate 0.0194 mg/L -10.0194 0.1 < 1/2 RDL
Sulfate -0.0371 mg/L -1-0.0371 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 5.35 5 102mg/L -1208015.35
Fluoride 5.14 5 102mg/L -1208015.14
Nitrate 5.73 5 102mg/L -1208015.73
Sulfate 7.8 5 83.2mg/L -1208017.8
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 5.36 5 103 0.191mg/L -1208015.36
Fluoride 5.13 5 102 0.196mg/L -1208015.13
Nitrate 5.75 5 102 0.304mg/L -1208015.75
Sulfate 7.8 5 83.2 0.0264mg/L -1208017.8
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 6.58 5 95.9mg/L -1208016.58
Fluoride 4.93 5 96.5mg/L -1208014.93
Nitrate 8.74 5 104mg/L -1208018.74
Sulfate 6.21 5 104mg/L -1208016.21
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 6.63 5 96.8 0.905mg/L -1208016.63
Fluoride 4.9 5 95.9 0.648mg/L -1208014.9
Nitrate 8.74 5 104 0.0289mg/L -1208018.74
Sulfate 6.21 5 104 0.0617mg/L -1208016.21
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.02 5 100mg/L -1208015.02
Fluoride 5.22 5 104mg/L -1208015.22
Nitrate 5.01 5 100mg/L -1208015.01
Sulfate 5 5 100mg/L -1208015
Duke Energy Analytical Lab
Page 21 of 29
B-21
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
Q16110169 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.007 ug/L -10.007 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.007 ug/L -10.007 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Mercury (Hg) 0.009 ug/L -10.009 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 4
RDL Relative Concentration
Mercury (Hg) 0.009 ug/L -10.009 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.02 1 101ug/L -1257511.02
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 1.02 1 101 0.595ug/L -1257511.02
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 0.923 100 91.3ug/L -1257510092.3
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.922 100 91.2 0.11ug/L -1257510092.3
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.06 2 103ug/L -1158512.06
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.99 2 99.3ug/L -1158511.99
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16100522 -- 2016033963
Mercury (Hg) 0.977 1 96.8ug/L -1257510.977
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16100522 -- 2016033963
Mercury (Hg) 0.967 1 95.8 1.04ug/L -1257510.967
Duke Energy Analytical Lab
Page 22 of 29
B-22
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
Q16110169 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16100537 -- 2016034013
Mercury (Hg) 0.975 1 96.1ug/L -1257510.975
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16100537 -- 2016034013
Mercury (Hg) 0.978 1 96.4 0.312ug/L -1257510.978
Duke Energy Analytical Lab
Page 23 of 29
B-23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
Q16110467 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) -0.014 ug/L -1-0.014 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) -0.016 ug/L -1-0.016 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.08 1 103ug/L -1257511.08
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 1.04 1 99.7 3.55ug/L -1257511.04
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.05 2 103ug/L -1158512.05
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16100617 -- 2016034449
Mercury (Hg) 0.974 1 98.9ug/L -1257510.974
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16100617 -- 2016034449
Mercury (Hg) 0.977 1 99.2 0.303ug/L -1257510.977
Duke Energy Analytical Lab
Page 24 of 29
B-24
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
Q16110147 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) -0.000366 mg/L -1-0.000366 0.005 < 1/2 RDL
Boron (B) -0.000427 mg/L -1-0.000427 0.05 < 1/2 RDL
Calcium (Ca) 0.000017 mg/L -10.000017 0.01 < 1/2 RDL
Chromium (Cr) -0.000271 mg/L -1-0.000271 0.005 < 1/2 RDL
Copper (Cu) -0.00173 mg/L -1-0.00173 0.005 < 1/2 RDL
Iron (Fe) 0.000471 mg/L -10.000471 0.01 < 1/2 RDL
Magnesium (Mg) -0.000197 mg/L -1-0.000197 0.005 < 1/2 RDL
Manganese (Mn) -0.000063 mg/L -1-0.000063 0.005 < 1/2 RDL
Nickel (Ni) -0.000359 mg/L -1-0.000359 0.005 < 1/2 RDL
Potassium (K) 0.00206 mg/L -10.00206 0.1 < 1/2 RDL
Silver (Ag) -0.000531 mg/L -1-0.000531 0.005 < 1/2 RDL
Sodium (Na) 0.00177 mg/L -10.00177 0.05 < 1/2 RDL
Zinc (Zn) 0.000752 mg/L -10.000752 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 5.15 5 103mg/L -1208015.15
Boron (B) 5.21 5 104mg/L -1208015.21
Calcium (Ca) 5.27 5 105mg/L -1208015.27
Chromium (Cr) 5.14 5 103mg/L -1208015.14
Copper (Cu) 5.23 5 105mg/L -1208015.23
Iron (Fe) 5.37 5 107mg/L -1208015.37
Magnesium (Mg) 5.28 5 106mg/L -1208015.28
Manganese (Mn) 5.26 5 105mg/L -1208015.26
Nickel (Ni) 5.25 5 105mg/L -1208015.25
Potassium (K) 5.15 5 103mg/L -1208015.15
Silver (Ag) 0.514 0.5 103mg/L -1208010.514
Sodium (Na) 5 5 99.9mg/L -1208015
Zinc (Zn) 5.18 5 104mg/L -1208015.18
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16100617 -- 2016034439
Barium (Ba) 5.22 5 102mg/L -1257515.22
Boron (B) 5.18 5 103mg/L -1257515.18
Calcium (Ca) 117 5 15.1mg/L -125751117
Chromium (Cr) 4.99 5 99.7mg/L -1257514.99
Copper (Cu) 5.09 5 102mg/L -1257515.09
Iron (Fe) 6.17 5 103mg/L -1257516.17
Magnesium (Mg) 21 5 0mg/L -12575121
Manganese (Mn) 5.11 5 102mg/L -1257515.11
Duke Energy Analytical Lab
Page 25 of 29
B-25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
Q16110147 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16100617 -- 2016034439
Nickel (Ni) 4.98 5 99.2mg/L -1257514.98
Potassium (K) 11.7 5 104mg/L -12575111.7
Silver (Ag) 0.497 0.5 99.4mg/L -1257510.497
Sodium (Na) 32.1 5 101mg/L -12575132.1
Zinc (Zn) 4.92 5 98.2mg/L -1257514.92
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16100617 -- 2016034439
Barium (Ba) 5.24 5 103 0.527mg/L -1257515.24
Boron (B) 5.18 5 103 0mg/L -1257515.18
Calcium (Ca) 115 5 18 17.4mg/L -125751115
Chromium (Cr) 4.98 5 99.5 0.181mg/L -1257514.98
Copper (Cu) 5.11 5 102 0.235mg/L -1257515.11
Iron (Fe) 6.21 5 104 0.736mg/L -1257516.21
Magnesium (Mg) 20.9 5 551 200mg/L -12575120.9
Manganese (Mn) 5.14 5 102 0.568mg/L -1257515.14
Nickel (Ni) 4.99 5 99.4 0.222mg/L -1257514.99
Potassium (K) 11.6 5 102 1.8mg/L -12575111.6
Silver (Ag) 0.498 0.5 99.7 0.331mg/L -1257510.498
Sodium (Na) 31.8 5 94.2 6.53mg/L -12575131.8
Zinc (Zn) 4.91 5 97.9 0.245mg/L -1257514.91
Duke Energy Analytical Lab
Page 26 of 29
B-26
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
Q16110158 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) -0.026 ug/L -1-0.026 1 < 1/2 RDL
Cadmium (Cd) -0.001 ug/L -1-0.001 1 < 1/2 RDL
Lead (Pb) -0.016 ug/L -1-0.016 1 < 1/2 RDL
Selenium (Se) 0.011 ug/L -10.011 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 51.3 50 103ug/L -12080151.3
Cadmium (Cd) 51.8 50 104ug/L -12080151.8
Lead (Pb) 51.3 50 103ug/L -12080151.3
Selenium (Se) 49.6 50 99.1ug/L -12080149.6
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16110110 -- 2016035520
Arsenic (As) 50.1 50 100ug/L -12575150.1
Cadmium (Cd) 51.1 50 102ug/L -12575151.1
Lead (Pb) 50.5 50 101ug/L -12575150.5
Selenium (Se) 46.9 50 93.5ug/L -12575146.9
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16110110 -- 2016035520
Arsenic (As) 49 50 97.9 2.16ug/L -12575149
Cadmium (Cd) 50.8 50 102 0.586ug/L -12575150.8
Lead (Pb) 49.7 50 99.4 1.49ug/L -12575149.7
Selenium (Se) 48.9 50 97.5 4.17ug/L -12575148.9
Duke Energy Analytical Lab
Page 27 of 29
B-27
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100617
Q16110287 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16100586 -- 2016034278
TDS 0mg/L -157
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16100586 -- 2016034279
TDS 2.82mg/L -170
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16100586 -- 2016034280
TDS 5.22mg/L -156
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 4
RPD
Parent Sample: J16100586 -- 2016034283
TDS 5.41mg/L -157
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 94mg/L -11090194
Duke Energy Analytical Lab
Page 28 of 29
B-28
Duke Energy Analytical Lab Page 29 of 29 B-29