1809_DukeMarshallFGD_Sept2016_2ndSemiAnnual_DIN27172_20161220

Marshall Steam Station
Semiannual Groundwater
Monitoring Report
FGD Residue Landfill, Phase 1, Cell 1
Permit No. 1809
September 2016 Sampling Event
December 20, 2016

Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Marshall Steam Station FGD Residue Landfill Phase 1, Cell 1 Permit No. 1809
September 2016 Sampling EventContents

ii
Contents
Page
Report Verification ......................................................................................................................... i
Contents ........................................................................................................................................ ii
Section 1 – Background ................................................................................................................ 1
Section 2 – Methods ..................................................................................................................... 3
2.1 Sampling and Analysis Methods .................................................................................... 3
2.2 Statement of Work .......................................................................................................... 3
Section 3 - Results ........................................................................................................................ 5
3.1 Site Groundwater Flow ................................................................................................... 5
3.2 Analytical Results ........................................................................................................... 5

FIGURES
1. Site Location Map
2. Sample Locations
3. Generalized Groundwater Surface Contours
TABLES
1. Well Construction Information
2. Groundwater Flow Velocities
3. Field Data Parameters
4. Field and Analytical Results
5. Field and Analytical Results that Equal or Exceed NCAC 2L Groundwater Quality
Standards
6. Leachate Field and Analytical Results
APPENDICES
A. Field Sampling Forms
B. Laboratory Report and Chain-of-Custody Forms
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Marshall Steam Station FGD Residue Landfill Phase 1, Cell 1 Permit No. 1809
September 2016 Sampling EventSection 1 – BACKGROUND

1
Section 1 – Background
Marshall Steam Station (Marshall) is owned and operated by Duke Energy Carolinas, LLC
(Duke Energy). The Marshall plant has a generating capacity of 2,090 megawatts of electric
power by the combustion of coal. The plant is located in Catawba County, North Carolina, on
Lake Norman and is in the Piedmont physiographic region.
The flue gas desulfurization (FGD) landfill is located northwest of the power plant and west of
the Marshall ash basin as shown on Figure 1. In general, the topography of the landfill site
slopes from the west-northwest to the east-southeast towards the Marshall ash basin.
The landfill is permitted to receive FGD residue (gypsum), clarifier sludge, fly ash, bottom ash,
construction and demolition (C&D) waste, asbestos waste, mill rejects (pyrites), waste limestone
material, land clearing and inert debris, boiler slag, ball mill rejects, sand blast material, and coal
waste. The clarifier sludge is generated from the FGD wastewater treatment system. Only Cell 1
of the landfill has been constructed and is in operation. Cell 1 is approximately 18 acres in area.
The landfill is constructed with an engineered liner system. Contact stormwater and leachate
are collected in the lined Cell 1 and then piped to the ash basin. The landfill began receiving
waste in 2007.
The subsurface conditions at the site consist of residual soils and partially weathered rock which
have been formed by the in-place weathering of the parent rock. These materials are underlain
by bedrock. The site hydrogeological description and information on the monitoring wells can be
found in the Groundwater Sampling and Analysis Plan.1
The monitoring system for the Marshall FGD Landfill, Phase 1, Cell 1 consists the following:
Monitoring Wells: MS-8
MS-9
MS-10
MS-11
MS-12
MS-13
MS-14
MS-15
MS-16

Surface Water Sample: SW-1

Leachate Sample: C1 Leachate

The locations of the wells, surface water sample location, and the leachate sampling location
are shown on Figure 2. Note that the asbestos landfill footprint shown in Figure 1 is the
permitted extent of the landfill. Table 1 presents well construction information for the landfill
1 Marshall Steam Station Flue Gas Desulfurization (FGD) Residue Landfill Phase 1, Cell 1 Permit No.
1809 Groundwater Sampling and Analysis Plan. Dated August 19, 2011.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Marshall Steam Station FGD Residue Landfill Phase 1, Cell 1 Permit No. 1809
September 2016 Sampling EventSection 1 – BACKGROUND

2
monitoring wells. The leachate sampling requirement was added in the revised Permit to
Operate for the Marshall FGD Landfill2 in September 2011. Due to landfill operations, the
historical leachate collection area is no longer accessible as of the September 2014 sampling
event. A new collection point for leachate sample C1 Leachate has been established northwest
of the landfill at the outlet of the leachate dischargeo pipe.
Well MS-8 is located north of the landfill and, according to the Groundwater Sampling and
Analysis Plan, is the background monitoring well for the site.
Surface water sample location SW-1 is a groundwater seep and the analytical results are
compared to Title 15A, North Carolina Administrative Code (NCAC), Subchapter 2L Standards
(2L Standards) for Class GA groundwater.
2 Attachment 3 – Conditions of Operating Permit, Part I: General Facility Conditions, Monitoring and
Reporting Requirements, #13.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Marshall Steam Station FGD Residue Landfill Phase 1, Cell 1 Permit No. 1809
September 2016 Sampling EventSection 2 – METHODS

3
Section 2 – Methods
2.1 Sampling and Analysis Methods
Groundwater sampling and documentation of sampling activities were performed by Duke
Energy personnel (Field Certification #5193) according to the North Carolina Solid Waste
Management Guidelines. Copies of the field sampling forms are included in Appendix A. The
parameters and constituents reported were selected by Duke Energy and the NCDEQ Division
of Solid Waste and were analyzed by Duke Energy Analytical Laboratory (North Carolina
Laboratory Certification #248).
The samples were analyzed for the following constituents and/or parameters:
 Barium, boron, copper, iron, manganese, nickel, silver, and zinc using Solid Waste
(SW)-8463 Method 6010D
 Arsenic, cadmium, chromium, lead, and selenium using SW-846 Method 6020B
 Mercury using U.S. Environmental Protection Agency (EPA) Method 7470A
 Total dissolved solids using Standard Method (SM) 2540C
 Chloride, fluoride, nitrate as nitrogen, and sulfate using SW-846 Method 9056A
2.2 Statement of Work
HDR completed the following tasks:
 Received field sampling information provided by Duke Energy (performed by Duke
Energy personnel) for monitoring wells MS-8, MS-9, MS-10, MS-11, MS-12, MS-13, MS-
14, MS-15, and MS-16 and leachate sampling location C1 Leachate. Surface water
sample location SW-1 was dry and a sample could not be collected. The samples were
collected on September 28, 2016, and HDR received the data on October 19, 2016. The
field sampling forms are included in Appendix A.
 Reviewed the laboratory analytical results for samples. The EDD provided by Duke
Energy was adapted to conform to the format requirements of the North Carolina
Department of Environmental Quality (NCDEQ) EDD template. HDR added an italicized
J data qualifier (J) to indicate a concentration that is equal to or greater than the
laboratory’s method reporting limit (MRL) but less than the Solid Waste Section Limit4
(SWSL). A copy of the original EDD is retained in HDR’s files.

3 EPA Hazardous Waste Test Methods (SW-846); available online at https://www.epa.gov/hw-sw846
(Accessed August 30, 2016)
4 The Solid Waste Section Limit (SWSL) is defined by NCDEQ as the lowest amount of analyte in a
sample that can be quantitatively determined with suitable precision and accuracy. The SWSL is the
concentration below which reported results must be qualified as estimated. NCDEQ Division of Waste
Management Memorandum dated February 23, 2007.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Marshall Steam Station FGD Residue Landfill Phase 1, Cell 1 Permit No. 1809
September 2016 Sampling EventSection 2 – METHODS

4
 Developed a generalized groundwater surface contour map using map data and
groundwater elevation data supplied by Duke Energy. Calculated groundwater flow
velocities based on groundwater surface contours.
 Prepared and submitted this Semiannual Groundwater Monitoring Report to Duke
Energy.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report
Marshall Steam Station FGD Residue Landfill Phase 1, Cell 1 Permit No. 1809
September 2016 Sampling EventSection 3 - RESULTS

5
Section 3 - Results
3.1 Site Groundwater Flow
Generalized groundwater surface contours for the site are shown on Figure 3. These contours
were developed using groundwater elevations measured in the wells on the date of sampling.
Calculated groundwater flow velocities are presented in Table 2.
Groundwater flow in the area of the landfill is generally from areas of higher topography located
to the north and west of the landfill, toward the Marshall ash basin, located to the east of the
landfill. To a lesser extent, some component of groundwater flow is expected to be toward
surface water sample location SW-1. Note that SW-1 was dry during this sampling event.
3.2 Analytical Results
A summary of the field data is presented in Table 3.
The field and analytical results of the groundwater samples collected at the monitoring wells are
summarized in Table 4. The analysis results for these locations are compared to the 2L
Standards. Concentrations with values that attain or exceed the 2L Standards are noted on
Table 4 by bold font. A summary of the analytical results that attain or exceed the 2L Standards
and a preliminary analysis of the cause and significance of the exceedances is presented in
Table 5.
The field and analytical results for the leachate sampling are summarized in Table 6.
Analytical results with values that equal or are greater than the SWSLs are noted on Tables 4
and 6 by gray cells.
Selected samples were diluted as is normal laboratory practice to bring samples to the
calibrated range of the analysis. Specifics regarding the samples that were diluted, including the
dilution amount, are reported in the EDD.
The laboratory report and chain-of-custody forms are located in Appendix B.
HDR previously prepared and submitted an assessment to NCDEQ on historical exceedances
of 2L Standards at this landfill (Groundwater Assessment Marshall Steam Station FGD Landfill,
Phase 1, Cell 1, July 12, 2012). The report assessed 2L Standard exceedances chromium at
MS-15; iron at MS-8, MS-10, MS-11, MS-16, and SW-1; manganese at MS-16; and pH at MS-8,
MS-10, MS-11, MS-12, MS-13, MS-14, MS-15, MS-16, and SW-1. The assessment report
concluded for the period of analytical results reviewed, that the exceedances of the 2L
Standards at the site were naturally occurring and are not related to impacts from the landfill.

FIGURES
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0
3

8
2
5

5
1

0
.
0
2

0
.
4
1

0
.
2
5
9

0
.
0
3
MS
-
1
0

8
3
2
.
7
5

8
3
0

4
8

0
.
0
6

0
.
4
1

0
.
2
5
9

0
.
0
9
MS
-
1
1

8
2
5

8
2
0

1
3
8

0
.
0
4

0
.
4
1

0
.
2
5
9

0
.
0
6
MS
-
1
2

8
1
5

8
1
0

4
8
9

0
.
0
1

0
.
4
1

0
.
2
5
9

0
.
0
2
MS
-
1
3

8
1
5

8
1
0

4
2
4

0
.
0
1

0
.
4
1

0
.
2
5
9

0
.
0
2
MS
-
1
4

8
1
0

8
0
8
.
0
5

2
8
0

0
.
0
1

0
.
4
1

0
.
2
5
9

0
.
0
1
MS
-
1
5

8
1
5

8
1
0

4
7
5

0
.
0
1

0
.
4
1

0
.
2
5
9

0
.
0
2
MS
-
1
6

8
1
5

8
1
0

1
1
0

0
.
0
5

0
.
4
1

0
.
2
5
9

0
.
0
7
No
t
e
s
:
1
.

L
i
n
e
a
r

d
i
s
t
a
n
c
e

m
e
a
s
u
r
e
d

t
h
r
o
u
g
h

m
o
n
i
t
o
r
i
n
g

w
e
l
l
s

i
s

g
e
n
e
r
a
l
l
y

p
e
r
p
e
n
d
i
c
u
l
a
r

t
o

g
r
o
u
n
d
w
a
t
e
r

c
o
n
t
o
u
r
s
.
2
.

A
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l

l
o
c
a
t
i
o
n
s

w
h
e
r
e

d
o
w
n
g
r
a
d
i
e
n
t

c
o
n
t
o
u
r
s

a
r
e

n
o
t

p
r
e
s
e
n
t
,

t
h
e

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

a
t

t
h
e

m
o
n
i
t
o
r
i
n
g

w
e
l
l

i
s

u
s
e
d

a
s

t
h
e

d
o
w
n
g
r
a
d
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n
.
3
.

A
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l

l
o
c
a
t
i
o
n
s

w
h
e
r
e

u
p
g
r
a
d
i
e
n
t

c
o
n
t
o
u
r
s

a
r
e

n
o
t

p
r
e
s
e
n
t
,

t
h
e

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

a
t

t
h
e

m
o
n
i
t
o
r
i
n
g

w
e
l
l

i
s

u
s
e
d

a
s

t
h
e

u
p
g
r
a
d
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n
.
4
.

M
o
n
i
t
o
r
i
n
g

w
e
l
l
s

a
r
e

n
o
t

l
i
s
t
e
d

w
h
e
r
e

i
n
s
u
f
f
i
c
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

c
o
n
t
o
u
r

i
n
f
o
r
m
a
t
i
o
n

o
r

w
e
l
l

c
o
n
s
t
r
u
c
t
i
o
n

d
a
t
a

i
s

a
v
a
i
l
a
b
l
e

to

c
a
l
c
u
l
a
t
e

v
e
l
o
c
i
t
y
.
5
.

H
y
d
r
a
u
l
i
c

g
r
a
d
i
e
n
t
s

a
n
d

g
r
o
u
n
d
w
a
t
e
r

v
e
l
o
c
i
t
i
e
s

a
r
e

a
p
p
r
o
x
i
m
a
t
e
.
6
.

H
y
d
r
a
u
l
i
c

c
o
n
d
u
c
t
i
v
i
t
y

p
r
e
s
e
n
t
e
d

i
s

t
h
e

g
e
o
m
e
t
r
i
c

m
e
a
n

o
f

t
h
e

c
o
n
d
u
c
t
i
v
i
t
y

d
a
t
a

f
o
r

t
h
e

a
l
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e

a
n
d

P
W
R

h
y
d
r
o
s
t
r
a
t
i
g
r
a
p
h
i
c

l
a
y
e
r

i
n

t
h
e

H
D
R

C
o
n
d
u
c
t
i
v
i
t
y

D
a
t
a
b
a
s
e

(
u
n
p
u
b
l
i
s
h
e
d

d
a
t
a

f
r
o
m

P
i
e
d
m
o
n
t

C
a
r
o
l
i
n
a

s
i
t
e
s

w
i
t
h

f
o
l
i
a
t
e
d
/
l
ay
e
r
e
d

b
e
d
r
o
c
k
)
.

7
.

E
f
f
e
c
t
i
v
e

p
o
r
o
s
i
t
y

p
r
e
s
e
n
t
e
d

i
s

t
h
e

m
e
a
n

v
a
l
u
e

o
f

t
h
e

a
l
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e

a
n
d

P
W
R

h
y
d
r
o
s
t
r
a
t
i
g
r
a
p
h
i
c

l
a
y
e
r

e
s
t
i
m
a
t
e
d

f
r
o
m

s
o
i
l

t
e
s
t
i
n
g

u
s
i
n
g

F
e
t
t
e
r
/
B
e
a
r

D
i
a
g
r
a
m
s
.

8
.

H
y
d
r
a
u
l
i
c

g
r
a
d
i
e
n
t
s

a
n
d

g
r
o
u
n
d
w
a
t
e
r

v
e
l
o
c
i
t
i
e
s

c
a
l
c
u
l
a
t
e
d

u
s
i
n
g

g
r
o
u
n
d
w
a
t
e
r

d
e
p
t
h
s

m
e
a
s
u
r
e
d

o
n

S
e
p
t
e
m
b
e
r

2
8
,

2
0
1
6
.
Ef
f
e
c
t
i
v
e

Po
r
o
s
i
t
y

(%
/
1
0
0
)
Groundwater Velocity (ft/day)
We
l
l

I
D

U
p
g
r
a
d
i
e
n
t

Gr
o
u
n
d
w
a
t
e
r

Co
n
t
o
u
r

El
e
v
a
t
i
o
n
(f
t
)
D
o
w
n
g
r
a
d
i
e
n
t

Gr
o
u
n
d
w
a
t
e
r

Co
n
t
o
u
r

El
e
v
a
t
i
o
n
(f
t
)
Li
n
e
a
r

Di
s
t
a
n
c
e

Be
t
w
e
e
n

Co
n
t
o
u
r
s

th
r
o
u
g
h

W
e
l
l
(f
t
)
Hy
d
r
a
u
l
i
c

Gr
a
d
i
e
n
t

(f
t
/
f
t
)
Hy
d
r
a
u
l
i
c

Co
n
d
u
c
t
i
v
i
t
y

(f
t
/
d
a
y
)
Page 1 of 1
Ta
b
l
e

3

-

F
i
e
l
d

D
a
t
a

P
a
r
a
m
e
t
e
r
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C
/
M
a
r
s
h
a
l
l

S
t
e
a
m

S
t
a
t
i
o
n
FG
D

R
e
s
i
d
u
e

L
a
n
d
f
i
l
l
Ph
a
s
e

1
,

C
e
l
l

1

-

P
e
r
m
i
t

N
o
.

1
8
0
9
9/
2
8
/
2
0
1
6

M
S
-
8

5
1
.
5
8

4
4
.
9
4

8
2
7
.
4
0

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
0
8

3
.
0
0

N
O

1
6
.
7
8

4
2

5
.
9

9
.
7

3
8
7

6
.
5
2
9/
2
8
/
2
0
1
6

M
S
-
9

5
3
.
0
0

4
2
.
0
1

8
2
6
.
0
3

N
o
r
m
a
l

N
o
n
e

L
F

5
4
0

1
.
7
9

4
.
3
5

N
/
A

1
6
.
3
8

7
5

6
.
4

2
.
4

3
6
1

7
.
9
4
9/
2
8
/
2
0
1
6

M
S
-
1
0

2
3
.
3
4

1
8
.
5
4

8
3
2
.
7
5

N
o
r
m
a
l

N
o
n
e

L
F

2
8
0

0
.
7
8

1
.
7
5

N
/
A

1
6
.
9
4

2
0

5
.
0

9
.
8

5
3
5

5
.
2
1
9/
2
8
/
2
0
1
6

M
S
-
1
1

4
2
.
7
2

3
4
.
8
3

8
2
4
.
9
5

N
o
r
m
a
l

N
o
n
e

L
F

3
6
0

1
.
2
9

3
.
0
0

N
/
A

1
5
.
0
5

4
0

5
.
4

2
.
9

3
3
5

7
.
2
9
9/
2
8
/
2
0
1
6

M
S
-
1
2

3
1
.
0
9

2
3
.
5
5

8
1
2
.
1
1

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
2
3

3
.
7
5

N
O

1
4
.
5
9

2
5

4
.
9

8
.
7

3
9
7

8
.
0
7
9/
2
8
/
2
0
1
6

M
S
-
1
3

4
1
.
5
2

3
1
.
0
1

8
1
0
.
8
9

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
7
1

5
.
2
5

N
O

1
4
.
3
6

6
3

5
.
4

2
.
1

3
6
1

4
.
6
1
9/
2
8
/
2
0
1
6

M
S
-
1
4

4
4
.
3
8

3
6
.
0
2

8
0
8
.
0
5

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
3
6

4
.
5
0

N
O

1
5
.
1
5

5
3

5
.
9

3
.
8

5
4
0

6
.
8
7
9/
2
8
/
2
0
1
6

M
S
-
1
5

6
3
.
0
8

5
1
.
3
8

8
1
0
.
0
9

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
9
1

1
0
.
0
0

N
O

1
6
.
4
0

1
4
2

6
.
4

3
.
5

5
3
9

7
.
3
4
9/
2
8
/
2
0
1
6

M
S
-
1
6

3
7
.
4
6

2
6
.
1
8

8
1
0
.
8
0

T
u
r
b
i
d

N
o
n
e

C
P

N
/
A

1
.
8
4

4
.
7
5
Y ES

1
7
.
6
8

1
0
4

6
.
3

8
9
.
3

3
1
4

8
.
5
1
9/
2
8
/
2
0
1
6

S
W
-
1

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

N
S

N
S

N
S

N
S

N
S

N
S
9/
2
8
/
2
0
1
6

C
1
-
L
E
A
C
H
A
T
E

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

1
9
.
1
9

4
,
5
8
9

6
.
0

5
7
.
2

2
5
2

8
.
6
8
No
t
e
s
:
1
.

P
u
r
g
e

M
e
t
h
o
d
s
;

L
F
=
L
o
w

F
l
o
w
,

C
P
=
C
o
n
v
e
n
t
i
o
n
a
l

P
u
r
g
e

(
3
-
5

w
e
l
l

v
o
l
u
m
e
s
)
,

N
P
=
N
o

P
u
r
g
e

(
H
y
d
r
a
S
l
e
e
v
e
)
,

E
O
P
=
E
q
u
i
p
m
e
n
t

O
n
l
y

P
u
r
g
e
.
P
u
m
p

r
a
t
e

a
p
p
l
i
c
a
b
l
e

t
o

L
F

p
u
r
g
i
n
g

o
n
l
y
.
2
.

F
i
e
l
d

s
a
m
p
l
i
n
g

p
e
r
f
o
r
m
e
d

b
y

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

p
e
r
s
o
n
n
e
l
.
3
.

E
V
A
C

i
n
d
i
c
a
t
e
s

w
h
e
t
h
e
r

t
h
e

w
a
t
e
r

l
e
v
e
l

i
n

t
h
e

w
e
l
l

w
a
s

d
r
a
w
n

d
o
w
n

t
o

t
h
e

l
e
v
e
l

o
f

t
h
e

p
u
m
p

d
u
r
i
n
g

p
u
r
g
i
n
g
.
4
.

µ
Լ /c
m

i
n
d
i
c
a
t
e
s

m
i
c
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m
h
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p
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n
t
i
m
e
t
e
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.
5
.

m
L
/
m
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n

i
n
d
i
c
a
t
e
s

m
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l
l
i
l
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t
e
r
s

p
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m
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n
u
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.
6
.

S
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i
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d
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a
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s

S
t
a
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d
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d

U
n
i
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s
.
7
.

N
T
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n
d
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c
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s

N
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p
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T
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U
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8
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m
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E
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N
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n
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a
p
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a
b
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10
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N
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n
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s
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w
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c
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d
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w
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l
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w
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d
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t
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t
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s
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p
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11
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I
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f
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m
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p
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d

b
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T
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s
u
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k
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o
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D
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E
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y

C
a
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L
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DE
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T
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WA
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pH (SU)TURBIDITY (NTU)ORP (mV-NHE)
AP
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A
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OD
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PU
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ME
T
H
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PU
M
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RA
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(m
L
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m
i
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L
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VO
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a
l
l
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s
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C
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(g
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l
l
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s
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C
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n
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C
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C
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Page 1 of 1
Ta
b
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e

4

-

G
r
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u
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d
w
a
t
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r

F
i
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l
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a
n
d

A
n
a
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R
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Du
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E
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C
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a
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L
L
C
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Ph
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N
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µ
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(
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:
1
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C
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c
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r
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t
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n
s

p
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d

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m
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r
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g
r
a
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p
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l
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t
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r

(
µ
g
/
L
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.
2
.

S
U

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d
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d

U
n
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t
s
.
3
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µ
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d
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m
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m
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p
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t
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t
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.
4
.

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t
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N
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.
5
.

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D
L

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t
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l
a
b
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t
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y

m
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d
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t
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l
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m
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.

T
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v
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a
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s
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m
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d
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b
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t
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d
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a
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s
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.

6
.

S
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7
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1
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§
1
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6
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a

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m
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4
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C
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§
1
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3
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3
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10
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.

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s
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1
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n
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t
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p
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pH

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6
.
5

-

8
.
5
Page 1 of 1
Ta
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F
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r

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n

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r

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s
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E
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n
c

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1
3

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g
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8

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6

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0
No
t
e
s
:
1
.

C
o
n
c
e
n
t
r
a
t
i
o
n
s

p
r
e
s
e
n
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d

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n

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c
r
o
g
r
a
m
s

p
e
r

l
i
t
e
r

(
µ
g
/
L
)
.
2
.

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U

i
n
d
i
c
a
t
e
s

S
t
a
n
d
a
r
d

U
n
i
t
s
.
3
.

µ
Լ /c
m

i
n
d
i
c
a
t
e
s

m
i
c
r
o
m
h
o
s

p
e
r

c
e
n
t
i
m
e
t
e
r
.
4
.

S
W
S

I
D

i
s

t
h
e

S
o
l
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d

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a
s
t
e

S
e
c
t
i
o
n

I
d
e
n
t
i
f
i
c
a
t
i
o
n

N
u
m
b
e
r
.
5
.

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D
L

i
s

t
h
e

l
a
b
o
r
a
t
o
r
y

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.

6
.

S
W
S
L

i
s

t
h
e

S
o
l
i
d

W
a
s
t
e

S
e
c
t
i
o
n

L
i
m
i
t
.

N
C
D
E
Q

d
e
f
i
n
e
s

t
h
e

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W
S
L

a
s

t
h
e

l
o
w
e
s
t

a
m
o
u
n
t

o
f

a
n
a
l
y
t
e

i
n

a

s
a
m
p
l
e

t
h
a
t

c
a
n

b
e

q
u
a
n
tit
a
t
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e
l
y

d
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t
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m
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d

w
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t
h

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u
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t
a
b
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p
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c
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s
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n

a
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a
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c
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r
a
c
y
.

7
.

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r
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y
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d

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l
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e
s

i
n
d
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c
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Page 1 of 1

A
Appendix A
Field Sampling Forms

ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬/▬►0.0
SS 227.8 ▬▬►227 226.4 ▬/▬►227
SS 74.3 ▬/▬►75 76.9 ▬/▬►75
SS ▬/▬►1410 ▬/▬►1410
B (7.00)7.03 ▬▬►7.02 7.03 ▬/▬►7.02
B (4.00)3.99 ▬▬►4.00 4.02 ▬/▬►4.00
B (10.00)10.06 ▬/▬►10.06 10.05 ▬/▬►10.06
20.33 20.24
pH Check B (7.00)▬▬►7.13
Time:0.00
438 ▬▬►441 440 ▬/▬►441
N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 20.19 20.17
TEMP (CO)
BP (mmHg)
COND
100 % mg/L 8.95 ▬▬►8.87 8.94 ▬/▬►8.89
After Cal 8.83 99.55 8.96 100.81
LCS 8.90 100.33 8.90 100.13
LCSD 8.89 -0.11 8.91 0.11
SS 53.5 ▬/▬►54.5 53.6 ▬/▬►54.5
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
FIELD SAMPLING CALIBRATION FORM
STUDY:MARSHALL STEAM STATION - FGD LANDFILL GROUNDWATER MONITORING
DATE (s):September 28, 2016 SURFACE UNIT READER:LDC
OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW Cloudy, calm, 70 deg F
COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:3858
ANALYZER MODEL#:MS5 66120
Calibration Date / Time 28-Sep-16 440 28-Sep-16 1240
PROCEDURE #:HYDROLAB 3210.6 VALIDATED BY:
Parameter Calibration Results Calibration Results
CALIBRATION BP (mmHg)740.19 CALIBRATION BP (mmHg)740.93
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.Buffer Temp.
ORP Temp.ORP Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
88.8
CALIBRATION PASS CALIBRATION PASS
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION PASS CALIBRATION PASS
DO
(mg/L)
19.87 19.82
740.19 740.93
88.7
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 739.2 (mmHg)Ending BP 740.4
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬▬►0.0 0.0 ▬/▬►0.0
SS 218.9 ▬▬►227 224.7 ▬/▬►227
SS 74.2 ▬/▬►75 75.9 ▬/▬►75
SS ▬/▬►1410 ▬/▬►1410
B (7.00)7.10 ▬▬►7.02 7.06 ▬/▬►7.02
B (4.00)4.07 ▬▬►4.00 4.08 ▬/▬►4.00
B (10.00)10.01 ▬/▬►10.06 10.05 ▬/▬►10.06
20.29 20.21
pH Check B (7.00)▬▬►7.13
Time:0.00
441 ▬▬►441 438 ▬/▬►441
N/A ▬/▬►N/A N/A ▬/▬►N/A
Zobell's 20.18 20.13
TEMP (CO)
BP (mmHg)
COND
100 % mg/L 8.93 ▬▬►8.87 8.93 ▬/▬►8.91
After Cal 8.87 99.99 8.91 100.00
LCS 8.84 99.66 8.90 99.89
LCSD 8.83 -0.11 8.87 -0.34
SS 53.8 ▬/▬►53.5 53.9 ▬/▬►53.5
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
FIELD SAMPLING CALIBRATION FORM
STUDY:MARSHALL STEAM STATION - FGD LANDFILL GROUNDWATER MONITORING
DATE (s):September 28, 2016 SURFACE UNIT READER:PSP
OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW Cloudy, calm, 70 deg F
COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:0730
ANALYZER MODEL#:HL4 400440
Calibration Date / Time 28-Sep-16 425 28-Sep-16 1225
PROCEDURE #:HYDROLAB 3210.6 VALIDATED BY:
Parameter Calibration Results Calibration Results
CALIBRATION BP (mmHg)740.19 CALIBRATION BP (mmHg)740.93
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
INSTRUMENT ZEROED INSTRUMENT ZEROED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)
pH
(units)
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.Buffer Temp.
ORP Temp.ORP Temp.
ORP CALIBRATION ACCEPTED CALIBRATION ACCEPTED
Buffer Temp.
86.1
CALIBRATION PASS CALIBRATION PASS
CALIBRATION ACCEPTED CALIBRATION ACCEPTED
After Cal % SAT After Cal % SAT
TURB
(ntu)CALIBRATION ACCEPTED CALIBRATION ACCEPTED
CALIBRATION PASS CALIBRATION PASS
DO
(mg/L)
19.87 19.70
740.19 740.93
80.2
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 739.2 (mmHg)Ending BP 740.4
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
41.58 51.58
35 (psi)15 (sec)(sec)
(gal)
1.08 (gal)
@
QC By:
See note below
DATE TIME
DISSOLVED
OXYGEN
19.1 368 6.43
6.32360
9/28/2016 0735
ORP
(ft)(YES/NO)
1.25 48.63 NO 16.27 43 5.79
16.53
VOLUME EVACUATION COND.
(gal)
PURGE METHOD
Conventional
DISCHARGERECHARGEPRESSURE 5
PUMP CONTROLLER SETTINGS
0.1631CONVERSION FACTOR
Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
1.08WELL VOLUME
FIELD CREW LDC, PSP
MONITORING WELL INFORMATION
2
N/A
PROCEDURE NO 3175.4DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID
PROJECT NAME FGD LANDFILL GROUNDWATER
SAMPLING DATE(s)28-Sep-2016
48.26
50.60PUMP INTAKE DEPTH (ft TOC)51.58
TOC ELEV (ft msl)
GS ELEV (ft msl)
872.34
869.35
WELL/LOCATION NAME MS-8
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88
WELL DEPTH (ft TOC)
WELL DIAMETER (in)MIDDLE OF WETTED SCREEN (ft toc)
WELL VOL
SCREEN INTERVAL (ft TOC)TO
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)44.94 WATER COLUMN (ft)6.64
EQUIPMENT INFORMATION
LEVEL METER SERIAL#26056 SAMPLING EQUIPMENT
TUBING DIAMETER (in)1/2 OD
QED T1200
PURGE COMPLETE TEMP SPECIFIC pH TURBIDITY
WATER ELEVATION (ft msl)827.40
APPEARANCE
DETECTED ODOR None
Normal
WATER LEVEL
AFTER PURGE *(recalculates on
current water
level)(deg C)(umho/cm)(SU)(NTU)(mV-NHE)(mg/L)
23.6 357 6.34 0.48
0.75 NO
0.50 NO 16.64 42 5.86
0.50 NO 16.78 42 5.91 9.7 387 6.52
42 5.86 58.6
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY
LDC N/A
TOTAL PURGE
VOLUME
3.00
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
Good Condition
Good Tag
WELL CASING
WELL CONDITION
PROTECTIVE CASING
WELL PAD
WELL TAG
Good Condition
Sample preservation verified to pH
(units)< 2.0
SAMPLING NOTES
Consider checking water level after 1st or 2nd removed well volume to re-calculate the purge volume necessary. This well typically "evacuates" after the 1st well volume.
Well pad loode in ground.
ADDITIONAL WELL CONDITION NOTES
43.00 53.00
25 (psi)8 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 4.35 (gal)LDC 9/28/2016 0825 NA
DRAW-DOWN 1.23 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.75 (gal)SAMPLE COLLECTED BY DATE TIME
N/A
8:20 43.24 540 16.38 75 6.40 2.4 361 7.94 N/A
8:15 43.24 540 16.40 77 6.42 2.4 360 7.92
N/A
8:10 43.24 540 16.41 80 6.47 2.6 352 7.82 N/A
8:05 43.24 540 16.40 84 6.48 2.6 340 7.62
N/A
8:00 43.24 540 16.42 87 6.56 1.8 328 7.16 N/A
7:55 43.24 540 16.45 98 6.71 1.4 304 6.65
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)42.01 WATER COLUMN (ft)10.99 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)826.03 WELL VOLUME 1.79
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 7
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)868.04 MIDDLE OF WETTED SCREEN (ft toc)48.00
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)53.00 GS ELEV (ft msl)865.36 PUMP INTAKE DEPTH (ft TOC)52.00
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)28-Sep-2016 WELL/LOCATION NAME MS-9
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
13.34 23.34
10 (psi)5 (sec)(sec)
(gal)
@
QC By:
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)28-Sep-2016 WELL/LOCATION NAME MS-10
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)851.29 MIDDLE OF WETTED SCREEN (ft toc)20.94
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)23.34 GS ELEV (ft msl)848.29 PUMP INTAKE DEPTH (ft TOC)22.30
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)18.54 WATER COLUMN (ft)4.80 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)832.75 WELL VOLUME 0.78
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
8:55 19.34 280 16.90 20 4.97 50.2 506 5.32 N/A
8:50 19.34 280 16.94 20 4.97 78.6 482 5.63
N/A
9:05 19.34 280 16.95 20 4.96 8.9 529 5.09 N/A
9:00 19.34 280 16.86 20 4.97 14.8 521 5.21
N/A9:10 19.34 280 16.94 20 4.98 9.8 535 5.21
DRAW-DOWN 0.80 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.25 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 1.75 (gal)LDC 9/28/2016 0915 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
32.72 42.72
20 (psi)10 (sec)(sec)
(gal)
@
QC By:
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)28-Sep-2016 WELL/LOCATION NAME MS-11
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)859.78 MIDDLE OF WETTED SCREEN (ft toc)38.78
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)42.72 GS ELEV (ft msl)856.87 PUMP INTAKE DEPTH (ft TOC)41.70
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)34.83 WATER COLUMN (ft)7.89 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)824.95 WELL VOLUME 1.29
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
7:35 35.53 360 15.08 39 5.38 3.4 332 7.30 N/A
7:30 35.53 360 15.07 38 5.40 3.1 329 7.30
N/A7:40 35.53 360 15.05 40 5.38 2.9 335 7.29
DRAW-DOWN 0.70 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 2.00 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 3.00 (gal)PSP 9/28/2016 0745 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
21.09 31.09
15 (psi)10 (sec)(sec)
(gal)
1.23 (gal)
@
QC By:
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)28-Sep-2016 WELL/LOCATION NAME MS-12
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)835.66 MIDDLE OF WETTED SCREEN (ft toc)27.32
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)31.09 GS ELEV (ft msl)832.70 PUMP INTAKE DEPTH (ft TOC)30.10
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)23.55 WATER COLUMN (ft)7.54 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)812.11 WELL VOLUME 1.23
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.25 NO 14.61 26 4.89 23.2 382
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
8.15
1.25 NO 14.59 25 4.91 8.7 397 8.07
1.25 NO 14.59 25 4.90 12.9 390 8.11
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
3.75 PSP 9/28/2016 0820 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
During sampling, it was noticed that samples were cloudy, measured turbidity during sampling and measured 45 NTU's during the filling of the last sample bottle (NO3). Metals
and TDS were collected first and second respectively.
31.52 41.52
23 (psi)10 (sec)(sec)
(gal)
1.71 (gal)
@
QC By:
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)28-Sep-2016 WELL/LOCATION NAME MS-13
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)841.90 MIDDLE OF WETTED SCREEN (ft toc)36.52
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)41.52 GS ELEV (ft msl)839.19 PUMP INTAKE DEPTH (ft TOC)40.50
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)31.01 WATER COLUMN (ft)10.51 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)810.89 WELL VOLUME 1.71
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.75 NO 14.41 63 5.34 3.8 328
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
4.89
1.75 NO 14.36 63 5.39 2.1 361 4.61
1.75 NO 14.37 61 5.30 2.8 347 4.69
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
5.25 PSP 9/28/2016 0915 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
34.38 44.38
25 (psi)10 (sec)(sec)
(gal)
1.36 (gal)
@
QC By:
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)28-Sep-2016 WELL/LOCATION NAME MS-14
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)844.07 MIDDLE OF WETTED SCREEN (ft toc)40.20
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)44.38 GS ELEV (ft msl)841.27 PUMP INTAKE DEPTH (ft TOC)43.40
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)36.02 WATER COLUMN (ft)8.36 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)808.05 WELL VOLUME 1.36
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.50 NO 15.14 57 5.95 3.0 520
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
6.51
1.50 NO 15.15 53 5.87 3.8 540 6.87
1.50 NO 15.11 55 5.92 3.9 528 6.52
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
4.50 LDC 9/28/2016 1055 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
53.08 63.08
30 (psi)12 (sec)(sec)
(gal)
1.91 (gal)
@
QC By:
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)28-Sep-2016 WELL/LOCATION NAME MS-15
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)861.47 MIDDLE OF WETTED SCREEN (ft toc)58.08
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)63.08 GS ELEV (ft msl)858.42 PUMP INTAKE DEPTH (ft TOC)62.10
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 8
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)51.38 WATER COLUMN (ft)11.70 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)810.09 WELL VOLUME 1.91
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
2.00 NO 16.53 159 6.55 2.7 478
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
7.37
2.00 NO 16.41 148 6.62 1.3 496 7.26
2.00 NO 16.43 153 6.81 1.2 473 7.33
2.00 NO 16.40 142 6.41 3.5 539 7.34
2.00 NO 16.44 141 6.43 4.4 520 7.28
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
10.00 LDC 9/28/2016 1025 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
27.46 37.46
18 (psi)10 (sec)(sec)
(gal)
1.84 (gal)
@
QC By:
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)28-Sep-2016 WELL/LOCATION NAME MS-16
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)836.98 MIDDLE OF WETTED SCREEN (ft toc)32.46
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)37.46 GS ELEV (ft msl)834.25 PUMP INTAKE DEPTH (ft TOC)36.50
See note below PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Turbid
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)26.18 WATER COLUMN (ft)11.28 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)810.80 WELL VOLUME 1.84
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
2.00 29.34 NO 16.19 110 6.13 28.6 298
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
6.16 1.32
0.69
0.75 36.10 NO 16.85 108 6.15 45.4 314 6.73 0.22
1.50 33.25 NO 16.18 109 6.09 62.3 312 6.21
0.25 YES 17.68 104 6.27 89.3 314 8.51
0.25 YES 17.32 108 6.25 63.2 312 7.82
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
4.75 PSP 9/28/2016 1050 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Water level drops below top of pump and well is considered evacuated.
N/A
(psi)(sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)28-Sep-2016 WELL/LOCATION NAME SW-1
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)N/A
SCREEN LENGTH (ft)N/A ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)N/A GS ELEV (ft msl)822.26 PUMP INTAKE DEPTH (ft TOC)N/A
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)N/A Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME N/A
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
PSP 9/28/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A
0830 N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
No sample collected surface water location was completely dry.
N/A
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SAMPLING NOTES
Sample untreated leachate from leachate piping at SE corner of landfill
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
0945
252 8.68
N/A
5.00 gal.
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 19.19 4589 5.98 57.2
TIME
PSP 9/28/2016
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
N/A
DETECTED ODOR None CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)N/A Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)N/A
SCREEN LENGTH (ft)N/A ELEV REF SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)N/A GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)28-Sep-2016 WELL/LOCATION NAME C1-LEACHATE
SITE NAME MARSHALL STEAM STATION PERMIT #18-09 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.4
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PERMIT #
MS-8 MS-9 MS-10 MS-11 MS-12 MS-13 MS-14 MS-15 MS-16 SW-1
YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES N/A
YES YES YES YES YES YES YES YES YES N/A
YES YES YES YES YES YES YES YES YES N/A
SEE NOTE YES YES YES YES YES YES YES YES N/A
YES YES YES YES YES YES YES YES YES N/A
YES YES YES YES YES YES YES YES YES N/A
N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES YES YES YES YES YES YES YES YES N/A
Lacks required information - Total well depth
Lacks required information - Depth to screen
Lacks required information - Non potable tag
NOTE:MS-8 well pad is loose in ground.
Lacks required information - Completion date
FLUSH MOUNT WELLS
Vault in good condition
Water inside vault
Vault bolt holes broken or stripped
Bolts stripped
Vault lid cracked or broken
WELL ID TAGS
Well tag in good condition
Well tag missing
Well tag damaged / illegible
Lacks required information - Driller Reg #
Replaced damaged well cap
Fire ants around concrete pad
WELL PROTECTIVE CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
Broken hinge on protective lid
Wasp nest inside protective casing
Ants inside protective casing
WELL CAPS
Well cap in good conditon
Damaged / needs replacement
Undermined / washing out
Lock in good condition
Lock rusted, difficult to open / needs replacing
Replaced damaged lock
WELL CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
CONCRETE PADS
Pad in good condition
Minor cracks
Major cracks / broken / repair required
WELL LOCK CONDITION
PAGE 1 OF 1
ACCESS TO WELLS
Access cleared into well
Access cleared around well
Tall grass or weeds - needs mowing
Road washing out / muddy / needs grading
Fallen tree blocking access
WELL SECURITY
Well found locked
Well found unlocked
SITE CONTACT Scott La Sala, Christopher Randazzo FIELD CREW LDC, PSP
WEATHER Cloudy, calm, 70 deg F
NORTH CAROLINA GROUNDWATER SAMPLING SITE CHECKLIST
LOCATION / SITE MARSHALL STEAM STATION - FGD LANDFILL GROUNDWATER MONITORING 18-09 SAMPLE DATE September 28, 2016
WELL DEPTH TO WATER Purge AVG *WELL EVAC SPECIFIC
WELL DEPTH WATER ELEV.Method PMP RATE VOL VOL EVAC TEMP CONDUCTANCE pH TURBIDITY ORP DO
DATE NO.(feet-toc)(feet-toc)(feet)APPEARANCE ODOR (ml/min)(gal)(gal)(yes/no)(deg C)(umho/cm)(units)(NTU)(mV-NHE)(mg/l)
9/28/2016 MS-8 51.58 44.94 827.40 Normal None C N/A 1.08 3.00 NO 16.78 42 5.9 9.7 387 6.52
9/28/2016 MS-9 53.00 42.01 826.03 Normal None LF 540 1.79 4.35 N/A 16.38 75 6.4 2.4 361 7.94
9/28/2016 MS-10 23.34 18.54 832.75 Normal None LF 280 0.78 1.75 N/A 16.94 20 5.0 9.8 535 5.21
9/28/2016 MS-11 42.72 34.83 824.95 Normal None LF 360 1.29 3.00 N/A 15.05 40 5.4 2.9 335 7.29
9/28/2016 MS-12 31.09 23.55 812.11 Normal None C N/A 1.23 3.75 NO 14.59 25 4.9 8.7 397 8.07
9/28/2016 MS-13 41.52 31.01 810.89 Normal None C N/A 1.71 5.25 NO 14.36 63 5.4 2.1 361 4.61
9/28/2016 MS-14 44.38 36.02 808.05 Normal None C N/A 1.36 4.50 NO 15.15 53 5.9 3.8 540 6.87
9/28/2016 MS-15 63.08 51.38 810.09 Normal None C N/A 1.91 10.00 NO 16.40 142 6.4 3.5 539 7.34
9/28/2016 MS-16 37.46 26.18 810.80 Turbid None C N/A 1.84 4.75 YES 17.68 104 6.3 89.3 314 8.51
9/28/2016 SW-1 N/A N/A N/A Normal None NP N/A N/A N/A N/A NS NS NS NS NS NS
9/28/2016 C1-LEACHATE N/A N/A N/A Normal None NP N/A N/A N/A N/A 19.19 4589 6.0 57.2 252 8.68
Purge Methods
LF = Low Flow
LF(M) = Low Flow (Mod.)
C = Connventional
NP = No Purge
EOP = Equip. Only Purge
LO = Level Only
NS = Not Sampled / Dry
* = Applicable to LF & LF(M) Purging Only
MARSHALL STEAM STATION
FGD LANDFILL GROUNDWATER
GROUNDWATER MONITORING FIELD DATA
PERMIT #18-09

B
Appendix B
Laboratory Report and
Chain-of-Custody Forms

13339 Hagers Ferry RoadHuntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16090068
Project Name:MARSHALL - GW FGD LANDFILL
Lab Contact: Anne Pridgeon
Date:10/13/2016
Customer Address:8320 NC Hwy 150 East
Customer Name(s):Chuck Campbell, Ed Sullivan, Tim Hunsucker
Mail Code: Marshall Steam Station
Terrell, NC 28682
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
As per LDC, location SW-01 was dry and not collected on 9/28/2016.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 23
Reason: I have reviewed
this document.
Date: 2016.10.13
17:56:17 -04'00'
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection Date and Time Collected By Sample Description
2016028360 MARSHALL 28-Sep-16 7:35 AM LDC MS-8
2016028361 MARSHALL 28-Sep-16 8:25 AM LDC MS-9
2016028362 MARSHALL 28-Sep-16 9:15 AM LDC MS-10
2016028363 MARSHALL 28-Sep-16 7:45 AM PSP MS-11
2016028364 MARSHALL 28-Sep-16 8:20 AM PSP MS-12
2016028365 MARSHALL 28-Sep-16 9:15 AM PSP MS-13
2016028366 MARSHALL 28-Sep-16 10:55 AM LDC MS-14
2016028367 MARSHALL 28-Sep-16 10:25 AM LDC MS-15
2016028368 MARSHALL 28-Sep-16 10:50 AM PSP MS-16
2016028370 MARSHALL 28-Sep-16 9:45 AM PSP C1 LEACHATE
2016028371 MARSHALL 28-Sep-16 11:15 AM LDC FIELD BLANK
11 Total Samples
Duke Energy Analytical Lab
Page 2 of 23
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:10/13/2016
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab
Page 3 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090068
2016028360
Collection Date:28-Sep-16 7:35 AM
Site:MS-8
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)18 mg/L
(CaCO3)
SM 2320B 09/29/2016 10:38 CJELLIO51
INORGANIC IONS BY IC
Chloride 1.2 mg/L EPA 9056A 09/28/2016 15:09 BGN90340.1 1
Fluoride 0.15 mg/L EPA 9056A 09/28/2016 15:09 BGN90340.1 1
Nitrate 0.50 mg/L EPA 9056A 09/28/2016 15:09 BGN90340.1 1
Nitrate as N 0.11 mg-N/L EPA 9056A 09/28/2016 15:09 BGN90340.023 1
Sulfate 0.19 mg/L EPA 9056A 09/28/2016 15:09 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/01/2016 11:01 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.038 mg/L SW 6010D 10/03/2016 09:59 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 10/03/2016 09:59 MHH71310.05 1
Calcium (Ca)3.71 mg/L SW 6010D 10/03/2016 09:59B2 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/03/2016 09:59 MHH71310.005 1
Iron (Fe)0.601 mg/L SW 6010D 10/03/2016 09:59 MHH71310.01 1
Magnesium (Mg)1.44 mg/L SW 6010D 10/03/2016 09:59 MHH71310.005 1
Manganese (Mn)0.006 mg/L SW 6010D 10/03/2016 09:59 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/03/2016 09:59 MHH71310.005 1
Potassium (K)1.05 mg/L SW 6010D 10/03/2016 09:59 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/03/2016 09:59 MHH71310.005 1
Sodium (Na)4.12 mg/L SW 6010D 10/03/2016 09:59 MHH71310.05 1
Zinc (Zn)0.090 mg/L SW 6010D 10/03/2016 09:59 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 09/30/2016 19:32 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 09/30/2016 19:32 CWSPEN311
Chromium (Cr)5.64 ug/L SW 6020B 09/30/2016 19:32 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 09/30/2016 19:32 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 09/30/2016 19:32 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 72 mg/L SM2540C 10/03/2016 12:18 HGRUVER251
Duke Energy Analytical Lab
Page 4 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090068
2016028361
Collection Date:28-Sep-16 8:25 AM
Site:MS-9
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)35 mg/L
(CaCO3)
SM 2320B 09/29/2016 08:57 CJELLIO201
INORGANIC IONS BY IC
Chloride 1.1 mg/L EPA 9056A 09/28/2016 15:59 BGN90340.1 1
Fluoride 0.16 mg/L EPA 9056A 09/28/2016 15:59 BGN90340.1 1
Nitrate 0.85 mg/L EPA 9056A 09/28/2016 15:59 BGN90340.1 1
Nitrate as N 0.19 mg-N/L EPA 9056A 09/28/2016 15:59 BGN90340.023 1
Sulfate 0.38 mg/L EPA 9056A 09/28/2016 15:59 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/01/2016 11:08 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.035 mg/L SW 6010D 10/03/2016 10:11 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 10/03/2016 10:11 MHH71310.05 1
Calcium (Ca)10.0 mg/L SW 6010D 10/03/2016 10:11B2 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/03/2016 10:11 MHH71310.005 1
Iron (Fe)0.112 mg/L SW 6010D 10/03/2016 10:11 MHH71310.01 1
Magnesium (Mg)1.05 mg/L SW 6010D 10/03/2016 10:11 MHH71310.005 1
Manganese (Mn)0.006 mg/L SW 6010D 10/03/2016 10:11 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/03/2016 10:11 MHH71310.005 1
Potassium (K)1.22 mg/L SW 6010D 10/03/2016 10:11 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/03/2016 10:11 MHH71310.005 1
Sodium (Na)3.86 mg/L SW 6010D 10/03/2016 10:11 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 10/03/2016 10:11 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 09/30/2016 19:11 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 09/30/2016 19:11 CWSPEN311
Chromium (Cr)1.99 ug/L SW 6020B 09/30/2016 19:11 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 09/30/2016 19:11 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 09/30/2016 19:11 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 82 mg/L SM2540C 10/03/2016 12:18 HGRUVER251
Duke Energy Analytical Lab
Page 5 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090068
2016028362
Collection Date:28-Sep-16 9:15 AM
Site:MS-10
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 09/29/2016 10:38 CJELLIO51
INORGANIC IONS BY IC
Chloride 1.2 mg/L EPA 9056A 09/28/2016 16:16 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 09/28/2016 16:16 BGN90340.1 1
Nitrate 3.9 mg/L EPA 9056A 09/28/2016 16:16 BGN90340.1 1
Nitrate as N 0.88 mg-N/L EPA 9056A 09/28/2016 16:16 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 09/28/2016 16:16 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/01/2016 11:10 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.145 mg/L SW 6010D 10/03/2016 10:15 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 10/03/2016 10:15 MHH71310.05 1
Calcium (Ca)0.264 mg/L SW 6010D 10/03/2016 10:15B2 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/03/2016 10:15 MHH71310.005 1
Iron (Fe)0.430 mg/L SW 6010D 10/03/2016 10:15 MHH71310.01 1
Magnesium (Mg)0.488 mg/L SW 6010D 10/03/2016 10:15 MHH71310.005 1
Manganese (Mn)0.032 mg/L SW 6010D 10/03/2016 10:15 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/03/2016 10:15 MHH71310.005 1
Potassium (K)0.985 mg/L SW 6010D 10/03/2016 10:15 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/03/2016 10:15 MHH71310.005 1
Sodium (Na)1.94 mg/L SW 6010D 10/03/2016 10:15 MHH71310.05 1
Zinc (Zn)0.009 mg/L SW 6010D 10/03/2016 10:15 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 09/30/2016 19:39 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 09/30/2016 19:39 CWSPEN311
Chromium (Cr)< 1 ug/L SW 6020B 09/30/2016 19:39 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 09/30/2016 19:39 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 09/30/2016 19:39 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 29 mg/L SM2540C 10/03/2016 12:18 HGRUVER251
Duke Energy Analytical Lab
Page 6 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090068
2016028363
Collection Date:28-Sep-16 7:45 AM
Site:MS-11
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)11 mg/L
(CaCO3)
SM 2320B 09/29/2016 10:38 CJELLIO51
INORGANIC IONS BY IC
Chloride 3.2 mg/L EPA 9056A 09/28/2016 16:33 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 09/28/2016 16:33 BGN90340.1 1
Nitrate 0.26 mg/L EPA 9056A 09/28/2016 16:33 BGN90340.1 1
Nitrate as N 0.06 mg-N/L EPA 9056A 09/28/2016 16:33 BGN90340.023 1
Sulfate 0.33 mg/L EPA 9056A 09/28/2016 16:33 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/01/2016 11:13 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.070 mg/L SW 6010D 10/03/2016 10:19 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 10/03/2016 10:19 MHH71310.05 1
Calcium (Ca)2.17 mg/L SW 6010D 10/03/2016 10:19B2 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/03/2016 10:19 MHH71310.005 1
Iron (Fe)0.200 mg/L SW 6010D 10/03/2016 10:19 MHH71310.01 1
Magnesium (Mg)1.13 mg/L SW 6010D 10/03/2016 10:19 MHH71310.005 1
Manganese (Mn)0.016 mg/L SW 6010D 10/03/2016 10:19 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/03/2016 10:19 MHH71310.005 1
Potassium (K)2.02 mg/L SW 6010D 10/03/2016 10:19 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/03/2016 10:19 MHH71310.005 1
Sodium (Na)2.72 mg/L SW 6010D 10/03/2016 10:19 MHH71310.05 1
Zinc (Zn)0.009 mg/L SW 6010D 10/03/2016 10:19 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 09/30/2016 19:46 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 09/30/2016 19:46 CWSPEN311
Chromium (Cr)2.49 ug/L SW 6020B 09/30/2016 19:46 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 09/30/2016 19:46 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 09/30/2016 19:46 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 43 mg/L SM2540C 10/03/2016 12:18 HGRUVER251
Duke Energy Analytical Lab
Page 7 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090068
2016028364
Collection Date:28-Sep-16 8:20 AM
Site:MS-12
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 09/29/2016 10:38 CJELLIO51
INORGANIC IONS BY IC
Chloride 2.9 mg/L EPA 9056A 09/28/2016 16:50 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 09/28/2016 16:50 BGN90340.1 1
Nitrate 0.66 mg/L EPA 9056A 09/28/2016 16:50 BGN90340.1 1
Nitrate as N 0.15 mg-N/L EPA 9056A 09/28/2016 16:50 BGN90340.023 1
Sulfate 0.16 mg/L EPA 9056A 09/28/2016 16:50 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/01/2016 11:15 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.091 mg/L SW 6010D 10/03/2016 10:23 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 10/03/2016 10:23 MHH71310.05 1
Calcium (Ca)0.202 mg/L SW 6010D 10/03/2016 10:23B2 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/03/2016 10:23 MHH71310.005 1
Iron (Fe)0.818 mg/L SW 6010D 10/03/2016 10:23 MHH71310.01 1
Magnesium (Mg)0.596 mg/L SW 6010D 10/03/2016 10:23 MHH71310.005 1
Manganese (Mn)0.055 mg/L SW 6010D 10/03/2016 10:23 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/03/2016 10:23 MHH71310.005 1
Potassium (K)2.15 mg/L SW 6010D 10/03/2016 10:23 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/03/2016 10:23 MHH71310.005 1
Sodium (Na)2.00 mg/L SW 6010D 10/03/2016 10:23 MHH71310.05 1
Zinc (Zn)0.007 mg/L SW 6010D 10/03/2016 10:23 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 09/30/2016 19:53 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 09/30/2016 19:53 CWSPEN311
Chromium (Cr)< 1 ug/L SW 6020B 09/30/2016 19:53 CWSPEN311
Lead (Pb)1.31 ug/L SW 6020B 09/30/2016 19:53 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 09/30/2016 19:53 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 36 mg/L SM2540C 10/03/2016 12:18 HGRUVER251
Duke Energy Analytical Lab
Page 8 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090068
2016028365
Collection Date:28-Sep-16 9:15 AM
Site:MS-13
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)18 mg/L
(CaCO3)
SM 2320B 09/29/2016 10:38 CJELLIO51
INORGANIC IONS BY IC
Chloride 2.7 mg/L EPA 9056A 09/28/2016 18:15 BGN90340.1 1
Fluoride 0.12 mg/L EPA 9056A 09/28/2016 18:15 BGN90340.1 1
Nitrate 6.7 mg/L EPA 9056A 09/28/2016 18:15 BGN90340.1 1
Nitrate as N 1.5 mg-N/L EPA 9056A 09/28/2016 18:15 BGN90340.023 1
Sulfate 0.24 mg/L EPA 9056A 09/28/2016 18:15 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/01/2016 11:18 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.088 mg/L SW 6010D 10/03/2016 10:27 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 10/03/2016 10:27 MHH71310.05 1
Calcium (Ca)5.24 mg/L SW 6010D 10/03/2016 10:27B2 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/03/2016 10:27 MHH71310.005 1
Iron (Fe)0.028 mg/L SW 6010D 10/03/2016 10:27 MHH71310.01 1
Magnesium (Mg)1.21 mg/L SW 6010D 10/03/2016 10:27 MHH71310.005 1
Manganese (Mn)0.006 mg/L SW 6010D 10/03/2016 10:27 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/03/2016 10:27 MHH71310.005 1
Potassium (K)2.23 mg/L SW 6010D 10/03/2016 10:27 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/03/2016 10:27 MHH71310.005 1
Sodium (Na)3.91 mg/L SW 6010D 10/03/2016 10:27 MHH71310.05 1
Zinc (Zn)0.005 mg/L SW 6010D 10/03/2016 10:27 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 09/30/2016 20:00 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 09/30/2016 20:00 CWSPEN311
Chromium (Cr)< 1 ug/L SW 6020B 09/30/2016 20:00 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 09/30/2016 20:00 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 09/30/2016 20:00 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 50 mg/L SM2540C 10/03/2016 12:18 HGRUVER251
Duke Energy Analytical Lab
Page 9 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090068
2016028366
Collection Date:28-Sep-16 10:55 AM
Site:MS-14
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)25 mg/L
(CaCO3)
SM 2320B 09/29/2016 08:57 CJELLIO201
INORGANIC IONS BY IC
Chloride 0.88 mg/L EPA 9056A 09/28/2016 17:24 BGN90340.1 1
Fluoride 0.13 mg/L EPA 9056A 09/28/2016 17:24 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 09/28/2016 17:24 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 09/28/2016 17:24 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 09/28/2016 17:24 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/01/2016 11:20 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.044 mg/L SW 6010D 10/03/2016 10:31 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 10/03/2016 10:31 MHH71310.05 1
Calcium (Ca)3.97 mg/L SW 6010D 10/03/2016 10:31B2 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/03/2016 10:31 MHH71310.005 1
Iron (Fe)0.122 mg/L SW 6010D 10/03/2016 10:31 MHH71310.01 1
Magnesium (Mg)0.835 mg/L SW 6010D 10/03/2016 10:31 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 10/03/2016 10:31 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/03/2016 10:31 MHH71310.005 1
Potassium (K)1.54 mg/L SW 6010D 10/03/2016 10:31 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/03/2016 10:31 MHH71310.005 1
Sodium (Na)5.89 mg/L SW 6010D 10/03/2016 10:31 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L SW 6010D 10/03/2016 10:31 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 09/30/2016 20:07 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 09/30/2016 20:07 CWSPEN311
Chromium (Cr)< 1 ug/L SW 6020B 09/30/2016 20:07 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 09/30/2016 20:07 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 09/30/2016 20:07 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 63 mg/L SM2540C 10/03/2016 12:18 HGRUVER251
Duke Energy Analytical Lab
Page 10 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090068
2016028367
Collection Date:28-Sep-16 10:25 AM
Site:MS-15
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)61 mg/L
(CaCO3)
SM 2320B 09/29/2016 08:57 CJELLIO201
INORGANIC IONS BY IC
Chloride 2.8 mg/L EPA 9056A 09/28/2016 17:41 BGN90340.1 1
Fluoride 0.12 mg/L EPA 9056A 09/28/2016 17:41 BGN90340.1 1
Nitrate 0.97 mg/L EPA 9056A 09/28/2016 17:41 BGN90340.1 1
Nitrate as N 0.22 mg-N/L EPA 9056A 09/28/2016 17:41 BGN90340.023 1
Sulfate 1.1 mg/L EPA 9056A 09/28/2016 17:41 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/01/2016 11:22 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.113 mg/L SW 6010D 10/03/2016 10:35 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 10/03/2016 10:35 MHH71310.05 1
Calcium (Ca)17.3 mg/L SW 6010D 10/03/2016 10:35B2 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/03/2016 10:35 MHH71310.005 1
Iron (Fe)0.174 mg/L SW 6010D 10/03/2016 10:35 MHH71310.01 1
Magnesium (Mg)4.77 mg/L SW 6010D 10/03/2016 10:35 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 10/03/2016 10:35 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/03/2016 10:35 MHH71310.005 1
Potassium (K)2.50 mg/L SW 6010D 10/03/2016 10:35 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/03/2016 10:35 MHH71310.005 1
Sodium (Na)4.32 mg/L SW 6010D 10/03/2016 10:35 MHH71310.05 1
Zinc (Zn)0.006 mg/L SW 6010D 10/03/2016 10:35 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 09/30/2016 20:34 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 09/30/2016 20:34 CWSPEN311
Chromium (Cr)20.8 ug/L SW 6020B 09/30/2016 20:34 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 09/30/2016 20:34 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 09/30/2016 20:34 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 110 mg/L SM2540C 10/03/2016 12:18 HGRUVER251
Duke Energy Analytical Lab
Page 11 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090068
2016028368
Collection Date:28-Sep-16 10:50 AM
Site:MS-16
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)48 mg/L
(CaCO3)
SM 2320B 09/29/2016 08:57 CJELLIO201
INORGANIC IONS BY IC
Chloride 1.5 mg/L EPA 9056A 09/28/2016 17:58 BGN90340.1 1
Fluoride 0.23 mg/L EPA 9056A 09/28/2016 17:58 BGN90340.1 1
Nitrate 1.6 mg/L EPA 9056A 09/28/2016 17:58 BGN90340.1 1
Nitrate as N 0.36 mg-N/L EPA 9056A 09/28/2016 17:58 BGN90340.023 1
Sulfate 0.35 mg/L EPA 9056A 09/28/2016 17:58 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/01/2016 11:25 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.122 mg/L SW 6010D 10/03/2016 10:39 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 10/03/2016 10:39 MHH71310.05 1
Calcium (Ca)9.93 mg/L SW 6010D 10/03/2016 10:39B2 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/03/2016 10:39 MHH71310.005 1
Iron (Fe)3.18 mg/L SW 6010D 10/03/2016 10:39 MHH71310.01 1
Magnesium (Mg)4.38 mg/L SW 6010D 10/03/2016 10:39 MHH71310.005 1
Manganese (Mn)0.042 mg/L SW 6010D 10/03/2016 10:39 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/03/2016 10:39 MHH71310.005 1
Potassium (K)2.69 mg/L SW 6010D 10/03/2016 10:39 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/03/2016 10:39 MHH71310.005 1
Sodium (Na)7.13 mg/L SW 6010D 10/03/2016 10:39 MHH71310.05 1
Zinc (Zn)0.145 mg/L SW 6010D 10/03/2016 10:39 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 09/30/2016 20:41 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 09/30/2016 20:41 CWSPEN311
Chromium (Cr)5.32 ug/L SW 6020B 09/30/2016 20:41 CWSPEN311
Lead (Pb)1.51 ug/L SW 6020B 09/30/2016 20:41 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 09/30/2016 20:41 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 120 mg/L SM2540C 10/03/2016 12:18 HGRUVER251
Duke Energy Analytical Lab
Page 12 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090068
2016028370
Collection Date:28-Sep-16 9:45 AM
Site:C1 LEACHATE
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B 09/29/2016 10:38 CJELLIO51
INORGANIC IONS BY IC
Chloride 380 mg/L EPA 9056A 09/28/2016 18:49 BGN9034550
Fluoride 5.3 mg/L EPA 9056A 09/28/2016 18:49 BGN9034550
Nitrate 11 mg/L EPA 9056A 09/28/2016 18:49 BGN9034550
Nitrate as N 2.4 mg-N/L EPA 9056A 09/28/2016 18:49 BGN90340.023 1
Sulfate 2800 mg/L EPA 9056A 09/28/2016 18:49 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/01/2016 11:44 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.05 mg/L SW 6010D 10/03/2016 10:55 MHH71310.05 10
Boron (B)43.0 mg/L SW 6010D 10/03/2016 10:55 MHH71310.5 10
Calcium (Ca)609 mg/L SW 6010D 10/03/2016 10:55B2 MHH71310.1 10
Copper (Cu)< 0.05 mg/L SW 6010D 10/03/2016 10:55 MHH71310.05 10
Iron (Fe)175 mg/L SW 6010D 10/03/2016 10:55 MHH71310.1 10
Magnesium (Mg)201 mg/L SW 6010D 10/03/2016 10:55 MHH71310.05 10
Manganese (Mn)5.11 mg/L SW 6010D 10/03/2016 10:55 MHH71310.05 10
Nickel (Ni)0.145 mg/L SW 6010D 10/03/2016 10:55 MHH71310.05 10
Potassium (K)80.7 mg/L SW 6010D 10/03/2016 10:55 MHH7131110
Silver (Ag)< 0.05 mg/L SW 6010D 10/03/2016 10:55 MHH71310.05 10
Sodium (Na)138 mg/L SW 6010D 10/03/2016 10:55 MHH71310.5 10
Zinc (Zn)0.202 mg/L SW 6010D 10/03/2016 10:55 MHH71310.05 10
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)1.54 ug/L SW 6020B 09/30/2016 20:48 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 09/30/2016 20:48 CWSPEN311
Chromium (Cr)1.57 ug/L SW 6020B 09/30/2016 20:48 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 09/30/2016 20:48 CWSPEN311
Selenium (Se)210 ug/L SW 6020B 09/30/2016 20:48 CWSPEN311
TOTAL DISSOLVED SOLIDS
TDS 3900 mg/L SM2540C 10/03/2016 12:18 HGRUVER621
Duke Energy Analytical Lab
Page 13 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090068
2016028371
Collection Date:28-Sep-16 11:15 AM
Site:FIELD BLANK
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)< 20 mg/L
(CaCO3)
SM 2320B 09/29/2016 08:57 CJELLIO201
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 9056A 09/28/2016 14:52 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 9056A 09/28/2016 14:52 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 9056A 09/28/2016 14:52 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 9056A 09/28/2016 14:52 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 9056A 09/28/2016 14:52 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 7470A 10/01/2016 11:47 DMFRANC0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L SW 6010D 10/03/2016 10:43 MHH71310.005 1
Boron (B)< 0.05 mg/L SW 6010D 10/03/2016 10:43 MHH71310.05 1
Calcium (Ca)1.26 mg/L SW 6010D 10/03/2016 10:43B2 MHH71310.01 1
Copper (Cu)< 0.005 mg/L SW 6010D 10/03/2016 10:43 MHH71310.005 1
Iron (Fe)< 0.01 mg/L SW 6010D 10/03/2016 10:43 MHH71310.01 1
Magnesium (Mg)0.017 mg/L SW 6010D 10/03/2016 10:43 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L SW 6010D 10/03/2016 10:43 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L SW 6010D 10/03/2016 10:43 MHH71310.005 1
Potassium (K)< 0.1 mg/L SW 6010D 10/03/2016 10:43 MHH71310.1 1
Silver (Ag)< 0.005 mg/L SW 6010D 10/03/2016 10:43 MHH71310.005 1
Sodium (Na)< 0.05 mg/L SW 6010D 10/03/2016 10:43 MHH71310.05 1
Zinc (Zn)0.123 mg/L SW 6010D 10/03/2016 10:43 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L SW 6020B 09/30/2016 20:55 CWSPEN311
Cadmium (Cd)< 1 ug/L SW 6020B 09/30/2016 20:55 CWSPEN311
Chromium (Cr)< 1 ug/L SW 6020B 09/30/2016 20:55 CWSPEN311
Lead (Pb)< 1 ug/L SW 6020B 09/30/2016 20:55 CWSPEN311
Selenium (Se)< 1 ug/L SW 6020B 09/30/2016 20:55 CWSPEN311
Qualifiers:
B2 Target analyte was detected in blank(s) at a concentration greater than ½ the reporting limit but less than the reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
Duke Energy Analytical Lab
Page 14 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090068
Q16091033 ALK_FIX4.5 ALKALINITY (FIXED END POINT 4.5)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3) 75.7 96.1mg/L (CaCO3)-12080172.7
Duke Energy Analytical Lab
Page 15 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090068
Q16091051 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16090068 -- 2016028362
Alkalinity (mg/L CaCO3)32.9mg/L (CaCO3)-11.79
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3) 7.57 86.2mg/L (CaCO3)-1208016.52
Duke Energy Analytical Lab
Page 16 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090068
Q16091025 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0357 mg/L -10.0357 0.1 < 1/2 RDL
Fluoride 0 mg/L -10.0231 0.1 < 1/2 RDL
Nitrate 0 mg/L -10.0228 0.1 < 1/2 RDL
Sulfate -0.0107 mg/L -1-0.0107 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 6.31 5 102mg/L -1208016.31
Fluoride 5.26 5 102mg/L -1208015.26
Nitrate 5.75 5 105mg/L -1208015.75
Sulfate 5.45 5 105mg/L -1208015.45
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 6.33 5 103 0.367mg/L -1208016.33
Fluoride 5.27 5 102 0.0606mg/L -1208015.27
Nitrate 5.77 5 105 0.327mg/L -1208015.77
Sulfate 5.47 5 105 0.211mg/L -1208015.47
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.11 5 102mg/L -1208015.11
Fluoride 5.16 5 103mg/L -1208015.16
Nitrate 5.14 5 103mg/L -1208015.14
Sulfate 5.14 5 103mg/L -1208015.14
Duke Energy Analytical Lab
Page 17 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090068
Q16100005 HG 7470 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.014 ug/L -10.014 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.019 ug/L -10.019 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Mercury (Hg) 0.023 ug/L -10.023 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.16 2 108ug/L -1158512.16
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 2.07 2 103ug/L -1158512.07
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16090068 -- 2016028360
Mercury (Hg) 1.15 1 110ug/L -1257511.15
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16090068 -- 2016028360
Mercury (Hg) 1.13 1 109 1.01ug/L -1257511.13
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16090461 -- 2016030325
Mercury (Hg) 1.08 1 107ug/L -1257511.08
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16090461 -- 2016030325
Mercury (Hg) 1.08 1 107 0.0934ug/L -1257511.08
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16090520 -- 2016030617
Mercury (Hg) 1.02 1 99.5ug/L -1257511.02
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16090520 -- 2016030617
Mercury (Hg) 1.02 1 100 0.501ug/L -1257511.02
Duke Energy Analytical Lab
Page 18 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090068
Q16091047 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) -0.000102 mg/L -1-0.000102 0.005 < 1/2 RDL
Boron (B) 0.000299 mg/L -10.000299 0.05 < 1/2 RDL
Calcium (Ca) 0.00683 mg/L -10.00683 0.01 > 1/2 RDL
Copper (Cu) 0.000108 mg/L -10.000108 0.005 < 1/2 RDL
Iron (Fe) 0.000615 mg/L -10.000615 0.01 < 1/2 RDL
Magnesium (Mg) 0.000804 mg/L -10.000804 0.005 < 1/2 RDL
Manganese (Mn) -0.000149 mg/L -1-0.000149 0.005 < 1/2 RDL
Nickel (Ni) -0.000512 mg/L -1-0.000512 0.005 < 1/2 RDL
Potassium (K) -0.0116 mg/L -1-0.0116 0.1 < 1/2 RDL
Silver (Ag) -0.00231 mg/L -1-0.00231 0.005 < 1/2 RDL
Sodium (Na) 0.00793 mg/L -10.00793 0.05 < 1/2 RDL
Zinc (Zn) 0.00227 mg/L -10.00227 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 5.02 5 100mg/L -1208015.02
Boron (B) 4.91 5 98.1mg/L -1208014.91
Calcium (Ca) 5.06 5 101mg/L -1208015.06
Copper (Cu) 4.93 5 98.6mg/L -1208014.93
Iron (Fe) 5.08 5 102mg/L -1208015.08
Magnesium (Mg) 5 5 100mg/L -1208015
Manganese (Mn) 4.99 5 99.7mg/L -1208014.99
Nickel (Ni) 4.99 5 99.8mg/L -1208014.99
Potassium (K) 4.91 5 98.1mg/L -1208014.91
Silver (Ag) 0.476 0.5 95.2mg/L -1208010.476
Sodium (Na) 4.97 5 99.3mg/L -1208014.97
Zinc (Zn) 4.98 5 99.6mg/L -1208014.98
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16090068 -- 2016028360
Barium (Ba) 5.15 5 102mg/L -1257515.15
Boron (B) 4.98 5 99.4mg/L -1257514.98
Calcium (Ca) 8.86 5 103mg/L -1257518.86
Copper (Cu) 5 5 100mg/L -1257515
Iron (Fe) 5.81 5 104mg/L -1257515.81
Magnesium (Mg) 6.5 5 101mg/L -1257516.5
Manganese (Mn) 5.08 5 101mg/L -1257515.08
Nickel (Ni) 5.05 5 101mg/L -1257515.05
Potassium (K) 6.08 5 101mg/L -1257516.08
Silver (Ag) 0.485 0.5 96.9mg/L -1257510.485
Duke Energy Analytical Lab
Page 19 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090068
Q16091047 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16090068 -- 2016028360
Sodium (Na) 9.27 5 103mg/L -1257519.27
Zinc (Zn) 5.11 5 100mg/L -1257515.11
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16090068 -- 2016028360
Barium (Ba) 5.1 5 101 1mg/L -1257515.1
Boron (B) 4.95 5 98.8 0.646mg/L -1257514.95
Calcium (Ca) 8.62 5 98.2 4.79mg/L -1257518.62
Copper (Cu) 4.97 5 99.4 0.542mg/L -1257514.97
Iron (Fe) 5.74 5 103 1.47mg/L -1257515.74
Magnesium (Mg) 6.39 5 99 2.12mg/L -1257516.39
Manganese (Mn) 5.03 5 101 0.852mg/L -1257515.03
Nickel (Ni) 5.02 5 100 0.636mg/L -1257515.02
Potassium (K) 5.99 5 98.8 1.84mg/L -1257515.99
Silver (Ag) 0.48 0.5 96 0.981mg/L -1257510.48
Sodium (Na) 9.01 5 97.9 5.1mg/L -1257519.01
Zinc (Zn) 5.08 5 99.8 0.599mg/L -1257515.08
Duke Energy Analytical Lab
Page 20 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090068
Q16091049 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) 0.089 ug/L -10.089 1 < 1/2 RDL
Cadmium (Cd) 0.002 ug/L -10.002 1 < 1/2 RDL
Chromium (Cr) -0.063 ug/L -1-0.063 1 < 1/2 RDL
Lead (Pb) -0.004 ug/L -1-0.004 1 < 1/2 RDL
Selenium (Se) -0.014 ug/L -1-0.014 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 50 50 100ug/L -12080150
Cadmium (Cd) 51.2 50 102ug/L -12080151.2
Chromium (Cr) 51 50 102ug/L -12080151
Lead (Pb) 50 50 99.9ug/L -12080150
Selenium (Se) 49.5 50 98.9ug/L -12080149.5
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16090068 -- 2016028361
Arsenic (As) 51.5 50 103ug/L -12575151.5
Cadmium (Cd) 52.8 50 106ug/L -12575152.8
Chromium (Cr) 55.2 50 106ug/L -12575155.2
Lead (Pb) 51.4 50 103ug/L -12575151.4
Selenium (Se) 51.3 50 102ug/L -12575151.3
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16090068 -- 2016028361
Arsenic (As) 49.3 50 98.2 4.33ug/L -12575149.3
Cadmium (Cd) 51.3 50 103 2.93ug/L -12575151.3
Chromium (Cr) 53.3 50 103 3.63ug/L -12575153.3
Lead (Pb) 49.8 50 99.5 3.1ug/L -12575149.8
Selenium (Se) 48.8 50 97.4 5.03ug/L -12575148.8
Duke Energy Analytical Lab
Page 21 of 23
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16090068
Q16100007 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16090068 -- 2016028360
TDS 4.26mg/L -169
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16090068 -- 2016028361
TDS 3.73mg/L -179
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 102mg/L -110901102
Duke Energy Analytical Lab
Page 22 of 23
Duke Energy Analytical Lab
Page 23 of 23