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HomeMy WebLinkAbout3404_TownOfKernersville_GWReportNov2014_DIN23993_20150309.pdf 2211 W. Meadowview Rd., #101 Greensboro, NC 27409 tel: 336/323-0092 fax: 336/323-0093 www.JoyceEngineering.com March 10, 2015 Ms. Jaclynne Drummond Compliance Hydrogeologist NC Department of Environment and Natural Resources Division of Waste Management – Solid Waste Section 2090 US Highway 70 Swannanoa, Nc 28778 RE: Second Semiannual Water Quality Monitoring Report of 2014 Town of Kernersville Landfill, Permit No. 34-04 Forsyth County, North Carolina JOYCE Project No. 00838.1501.12 Task No. 02 Dear Ms. Drummond: On behalf of the Town of Kernersville, Joyce Engineering is submitting the Second Semiannual Water Quality Monitoring Report of 2014 for the closed Town of Kernersville Landfill, Permit No. 34-04. The attached report contains electronic versions of the complete report and all appendices for the November 2014 sampling event. Also attached is the North Carolina Environmental Monitoring Reporting Form for the November 2014 monitoring event. If you wish to have a hard copy of the report, drawings, or appendices, we will be happy to provide it upon your request. Please feel free to contact me or Alex Everhart at (336) 323-0092 if you have any questions regarding this report. Sincerely, JOYCE ENGINEERING Hannu Kemppinen P.G. Senior Project Consultant Attachment C: Thad Buck – Town of Kernersville, Solid Waste Superintendent PREPARED FOR: TOWN OF KERNERSVILLE PUBLIC WORKS DEPARTMENT P.O. BOX 728 KERNERSVILLE, NORTH CAROLINA 27285-0728 TOWN OF KERNERSVILLE LANDFILL PERMIT NO. 34-04 SECOND SEMIANNUAL WATER QUALITY MONITORING REPORT OF 2014 MARCH 2015 PREPARED BY: 2211 WEST MEADOWVIEW ROAD, SUITE 101 GREENSBORO, NORTH CAROLINA 27407 NC LICENSE NUMBER C-0782 PHONE: (336) 323-0092 FAX: (336) 323-0093 JOYCE PROJECT NO. 838.1501.12 ______________________________________________________________________________ Second Semiannual Water Quality Monitoring Report of 2014 Joyce Engineering Town of Kernersville Landfill, Permit No. 34-04 March 2015 i Second Semiannual Water Quality Monitoring Report of 2014 Town of Kernersville Landfill Forsyth County, North Carolina TABLE OF CONTENTS 1.0 INTRODUCTION............................................................................................................. 1 1.1 Site Information .................................................................................................................. 1 1.2 Site Geology and Hydrogeology ......................................................................................... 1 1.3 Regulatory Status ................................................................................................................ 1 2.0 FACILITY MONITORING PROGRAM ...................................................................... 2 2.1 Groundwater Monitoring Program ..................................................................................... 2 2.2 Surface Water Monitoring Program .................................................................................... 3 3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2014 ........................................... 3 3.1 Field Work and Visual Inspection ...................................................................................... 3 3.2 Laboratory Analysis and Quality Control ........................................................................... 4 4.0 DATA ANALYSIS ............................................................................................................ 5 4.1 Groundwater Data Analysis and Comparisons to Standards .............................................. 5 4.2 Surface Water Data Analysis and Comparisons to Standards ............................................ 6 5.0 EVALUATION OF MONITORED NATURAL ATTENUATION (MNA)................ 6 5.1 MNA Parameters and Biodegradation Screening Matrix ................................................... 6 6.0 CONCLUSION ................................................................................................................. 7 7.0 REFERENCES .................................................................................................................. 7 Tables Table 1A Summary of Historical Groundwater Elevations Table 1B Monitoring Well and Boring Completion Summary Table 2 Summary of Estimated Hydraulic Gradient and Linear Velocity Table 3 Summary of Historical Groundwater Constituents Table 4 Summary of Historical Surface Water Constituents Table 5 Summary of MNA Constituents Table 6 MNA Screening Matrix ______________________________________________________________________________ Second Semiannual Water Quality Monitoring Report of 2014 Joyce Engineering Town of Kernersville Landfill, Permit No. 34-04 March 2015 ii Second Semiannual Water Quality Monitoring Report of 2014 Town of Kernersville Landfill Forsyth County, North Carolina TABLE OF CONTENTS (Continued) Figure Figure 1 Site Location Map Drawing Drawing 1 Potentiometric Surface Contour Map Appendices Appendix I Laboratory Analytical Reports and Field Data Logs Appendix II Summary of Detected Constituents Appendix III Summary of Exceedances ______________________________________________________________________________ Second Semiannual Water Quality Monitoring Report of 2014 Joyce Engineering Town of Kernersville Landfill, Permit No. 34-04 March 2015 1 1.0 INTRODUCTION 1.1 Site Information The Town of Kernersville Landfill is a closed, unlined municipal solid waste (MSW) landfill located on approximately 58.2 acres in Forsyth and Guilford Counties, NC, approximately 10 miles north of the City of Kernersville. The waste disposal area comprises approximately 13.8 acres. The property boundary is indicated on an excerpt from the 7.5 minutes USGS topographic map for Belews Creek, North Carolina (Figure 1). The facility was issued a Permit to Operate on May 15, 1985 and a letter of closure was issued on December 10, 1991. The area surrounding the landfill is zoned residential/agricultural and contains open fields and woodlands. The landfill is separated to the North from the Waste Management Piedmont Landfill and Recycling Center Facility by Freeman Road. The landfill is bounded to the south by an unnamed tributary of Belews Creek. 1.2 Site Geology and Hydrogeology The Town of Kernersville Landfill is located in the Piedmont physiographic providence of North Carolina and is underlain by intrusive granitic rocks of Pennsylvanian to Permian age which are part of the Charlotte Belt Geologic Unit. The uppermost aquifer is unconfined and includes both saprolite and uppermost fractured bedrock, which are well connected. The groundwater level measurements taken on November 20, 2014, were used to construct the groundwater surface contours shown in Drawing 1. Historical static water levels are provided in Table 1A. Well construction parameters can be found in Table 1B. Groundwater flow at the site is generally to the southwest. Using the hydraulic gradients along the flow paths shown on Drawing 1, the linear flow velocity (V) was estimated using the modified Darcy equation: V=Ki/n. The hydraulic gradient (i) is 0.04 ft/ft. An effective porosity value (n) of 30 percent was estimated and a hydraulic conductivity (K) 1.73 ft/day was estimated from slug tests completed by JOYCE in November 2013 at the Town of Kernersville Landfill. The calculated groundwater flow rate averages approximately 0.20 ft/day. A summary of the hydraulic gradients and linear flow velocities is provided in Table 2. 1.3 Regulatory Status The Town of Kernersville Landfill is currently monitoring groundwater in accordance with criteria set forth in Title 15A Subchapter 13B .0500 of the North Carolina Solid Waste Management Rules (NCSWMR) for municipal solid waste landfills (MSWLF) closed prior to October 9, 1993. ______________________________________________________________________________ Second Semiannual Water Quality Monitoring Report of 2014 Joyce Engineering Town of Kernersville Landfill, Permit No. 34-04 March 2015 2 Based on the presence of constituents above 2L standards that could potentially be crossing the facility boundary, NCDENR requested that Kernersville submit a Groundwater Assessment Plan to evaluate site conditions as they relate to groundwater quality. The Groundwater Assessment Report was submitted to NCDENR on May 13, 2013. The Groundwater Assessment Report concluded that, based on site hydrogeology, it is very unlikely that the site impacts above 2L standards are crossing the boundary. In a July 16, 2013, response to the Groundwater Assessment Report, NCDENR determined that despite the conclusion of the Assessment Report, the detection of VOCs at concentrations that exceed 2L standards beyond the compliance boundary of the site constitutes a violation of Solid Waste Section regulations. As required by NCDENR JOYCE submitted a Corrective Action Plan (CAP) on behalf of the Town of Kernersville Landfill in July 2014. NCDENR approved the Corrective Action Plan in a letter dated November 4, 2014. 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program The current groundwater compliance monitoring network includes six monitoring wells, including one upgradient well and five downgradient wells. These wells are summarized below, along with their current monitoring program status. Monitoring Well Classification Monitoring Program Total Depth from TOC (ft) MW-1 Former Background Water Levels Only 34.69 MW-2 Compliance/MNA Detection (.0500)/CAP 13.18 MW-3S Compliance/MNA Detection (.0500)/CAP 24.00 MW-3D Compliance/MNA Detection (.0500)/CAP 56.96 MW-4 Compliance/MNA Detection (.0500)/CAP 14.40 MW-5 Compliance Detection (.0500) 11.36 MW-6 Background/MNA Detection (.0500)/CAP 20.46 *TOC = Top of casing. Corrective Action Plan (CAP): Monitored Natural Attenuation (MNA) and Phytoremediation The locations of the monitoring wells are shown on Drawing 1. Existing monitoring well MW-6 serves as the background well for the facility. Monitoring well MW-6 replaced MW-1 as the facility’s background well due to infrequent opportunities to sample the well as a result of low well volumes or the well-being dry. Downgradient monitoring wells MW-2, -3S, -3D, -4, and -5 are monitored as part of the compliance network for the facility. MW-1 is monitored for water levels only, as conditions permit. As a condition of the CAP monitoring wells MW-2, -3S, -3D, -4 and -6 are now monitored for the MNA constituents; nitrate, sulfate, chloride, sulfide, alkalinity, total organic carbon, methane, ethane, ethene, volatile fatty acids, dissolved hydrogen, biological oxygen demand, chemical oxygen demand. ______________________________________________________________________________ Second Semiannual Water Quality Monitoring Report of 2014 Joyce Engineering Town of Kernersville Landfill, Permit No. 34-04 March 2015 3 Groundwater samples are collected semiannually during the second and fourth quarters. Samples are analyzed for all constituents listed in the NCSWMR Appendix I and MNA parameters during both the first and second semiannual events. 2.2 Surface Water Monitoring Program Surface water at the Town of Kernersville Landfill is monitored semiannually in conjunction with the groundwater sampling events. Samples are collected from three surface water monitoring points (SW-1, SW-2, and SW-3). The locations of the surface water monitoring points are shown on Drawing No. 1. Surface water samples are collected and analyzed for the NCSWMR Appendix I list of constituents during both semiannual monitoring events. The results are compared to the 15A NCAC 2B (NC 2B) Surface Water Standards in a value-to-value comparison. These surface water monitoring points are summarized below, along with their current monitoring program status. Surface Point Classification Monitoring Program SW-1 Up Stream/Compliance Surface Water SW-2 Compliance Surface Water SW-3 Compliance Surface Water 3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2014 3.1 Field Work and Visual Inspection In order to detect potential releases of leachate and/or landfill gas migration in a timely manner, a visual inspection program has been implemented at the Town of Kernersville Landfill. This inspection program involves field personnel making the following observations:  Observation of stress induced on the biological community (i.e., dead or dying vegetation),  Indications of leachate impact (i.e., seeps, impacted surface water),  Observations of erosion; and  Negative changes around the waste facility. On November 20, 2014, Joyce Engineering (JOYCE) personnel visited the facility to purge and sample the facility’s monitoring wells MW-2, MW-3S, MW-3D, MW-4 and MW-5. Well MW-6 was dry and was not sampled. Prior to purging, the depth to static water level was measured for all monitoring wells with an electronic water level indicator, accurate to 0.01 foot. MW-1 was measured for a static water level only. ______________________________________________________________________________ Second Semiannual Water Quality Monitoring Report of 2014 Joyce Engineering Town of Kernersville Landfill, Permit No. 34-04 March 2015 4 Monitoring wells were purged and sampled using either disposable bailers or a peristaltic pump. Measurements of temperature, pH, specific conductivity, dissolved oxygen, oxidation reduction potential and turbidity were recorded in the site specific log book prior to purging, after each purge volume, and during sampling. Prior to sampling, laboratory-supplied containers were prepared with the following information:  Monitoring well number (completed by field personnel),  Date and time of sample collection (completed by field personnel),  Initials of sampling personnel (completed by field personnel),  Project name and number (completed by the laboratory),  Chemical preservative (completed by the laboratory); and  Requested chemical analysis (completed by the laboratory). Groundwater samples from each monitoring well were collected directly from the disposable bailers in the provided laboratory containers either immediately after purging or within 24 hours of the final purge volume. Immediately after collection, the samples were placed in a laboratory provided cooler and chilled on ice. Field data logs are provided in the Appendix to this report. Surface water samples were collected directly from stream flow, by lowering the prepared sample containers into the stream flow with the opening facing into the current flow. Care was taken not to overflow the sample containers (which could lead to preservative loss) and avoid sample-induced turbidity. At the time of sampling, surface water was also measured for temperature, pH, specific conductivity, and turbidity. After sample collection, the samples were placed in a laboratory provided cooler and chilled on ice. Field data logs are provided in the Appendix. 3.2 Laboratory Analysis and Quality Control The November 2014 groundwater and surface water samples were submitted to Pace Analytical Services, Inc. of Huntersville, North Carolina under chain-of-custody control for analysis. As presented earlier, the groundwater samples were analyzed for the NCSWMR Appendix I and MNA constituents. JOYCE requested a Level II data report for the final laboratory report. The samples were received by the laboratory on November 21, 2014, in good condition, properly preserved, and within analysis hold times. In addition to samples collected for compliance monitoring at the Town of Kernersville Landfill, a Field Blank was collected by JOYCE personnel as part of the November 2014 sampling event. Also, a Trip Blank was prepared by the laboratory to accompany the volatile sampling containers during shipment to and from the laboratory. The November 2014 Field Blank was analyzed for the NCSWMR Appendix I constituents while the November 2014 Trip Blank was analyzed for the NCSWMR Appendix I volatile organics only. Upon receipt of the laboratory data package, the data was reviewed by JOYCE personnel for the following: ______________________________________________________________________________ Second Semiannual Water Quality Monitoring Report of 2014 Joyce Engineering Town of Kernersville Landfill, Permit No. 34-04 March 2015 5  General typographical errors,  Correct analyses performed and within method specified hold times,  Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate, and Laboratory Control Samples,  Blank qualified data (B-flags),  Detections above the groundwater and surface water standards; and  Detections that are above historical levels. 4.0 DATA ANALYSIS 4.1 Groundwater Data Analysis and Comparisons to Standards Results from the November 2014 sampling event were received December 03, 2014, from Pace and are found in the Appendix. Analytical results from monitoring wells were compared directly to the NC 2L Groundwater Standards (NC 2L) or Groundwater Protection Standards (GWPS). The following inorganic and organic constituents were detected at quantified concentrations in groundwater during the November 2014 sampling event. All concentrations are reported in micrograms per liter (µg/L). Concentrations with a “J” are considered to be estimated. Highlighted concentrations were detected above the NC 2L or GWPS in downgradient wells. Constituent NC2L/ (GWPS) Background Downgradient Blanks MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Barium 700 Dry 301 113 39.5 J 83.3 J 108 ND Cobalt (1) Dry ND 2.5 J ND ND 10.2 ND Zinc 1,000 Dry ND 20.9 ND ND 55.0 ND Benzene 1 Dry 6.2 0.30 J ND 0.32 J ND ND 1,4-Dichlorobenzene 6 Dry 4.7 1.9 3.8 2.6 ND ND 1,1-Dichloroethane 6 Dry 21.5 1.3 J 3.2 J 1.8 J ND ND Cis-1,2-Dichloroethylene 70 Dry 44.9 9.6 55.4 19.3 ND ND 1,2-Dichloropropane 0.6 Dry 4.1 0.56 J 1.2 0.36 J ND ND Tetrachloroethylene 0.7 Dry 1.1 ND ND ND ND ND Trichloroethylene 3 Dry 5.1 ND ND ND ND ND Vinyl Chloride 0.03 Dry 5.2 2.1 5.3 16.2 ND ND *ND = Not Detected above laboratory detection limits *NS= Well was bent and not sampled *J= Estimated In general, the organic and inorganic results are consistent with historical data. Historical groundwater data can be found in Table 3. The results, as reported by the laboratory, the laboratory quality/assurance/quality control information, and the chain-of-custody records are included in the Appendix. ______________________________________________________________________________ Second Semiannual Water Quality Monitoring Report of 2014 Joyce Engineering Town of Kernersville Landfill, Permit No. 34-04 March 2015 6 4.2 Surface Water Data Analysis and Comparisons to Standards There were no constituents detected at quantified concentrations or above the NC 2B standards in the surface waters during the November 2014 sampling event. In general, the results are consistent with historical data. Historical surface water data can be found in Table 4. The results, as reported by the laboratory, the laboratory quality/assurance/quality control information, and the chain-of-custody records are included in the Appendix. 5.0 EVALUATION OF MONITORED NATURAL ATTENUATION (MNA) 5.1 MNA Parameters and Biodegradation Screening Matrix In accordance with the CAP for the facility, MNA baseline sampling was initiated with the November 2014 sampling event. The November 2015 sampling event will be the fourth and final baseline sampling event for MNA. During the November 2014 sampling event the full list of MNA parameters were obtained for the following wells: MW-2, MW-3S, MW-3D, and MW- 4. MW-6 was dry and was not sampled. MNA parameters included field parameters temperature, pH, specific conductance, oxidation reduction potential, turbidity, dissolved oxygen, as well as laboratory parameters dissolved hydrogen, nitrate, sulfate, chloride, alkalinity, sulfide TOC, ethane, ethene, methane and volatile fatty acids Table 5 summarizes the MNA data where available. Laboratory reports and field data forms are included in Appendix A. The MNA parameter data were evaluated in general accordance with the United States Environmental Protection Agency’s (EPA’s) Technical Protocol Manual (EPA, 1998) to determine whether the conditions are conducive to, or whether there is evidence for anaerobic degradation of the chlorinated hydrocarbons. Specifically, the results were evaluated according to the weighted system presented in Table 2.3 of the Technical Protocol Manual, referred to hereafter as the Biodegradation Screening Matrix. According to this manual, a score less than 5 indicates that there is inadequate evidence for anaerobic natural attenuation, a score of 6 to 14 indicates that there is limited evidence for anaerobic natural attenuation, a score of 15 to 19 indicates that there is adequate evidence for anaerobic natural attenuation, and a score of 20 or more indicates that there is strong evidence that anaerobic natural attenuation is occurring. The MNA evaluation was performed based on the results from the November 2014 sampling event for downgradient wells within the contaminant plume, compared where appropriate to the background well (MW-6). The Biodegradation Screening Matrix is presented in Table 6 of this report. aspect of the scoring process is ambiguous with respect to how it should be applied to a landfill site such as this facility, and that is the issue of daughter products. Methane, carbon dioxide (CO2), cis-1,2-dichloroethylene, vinyl chloride, and 1,1-dichlroethane can all be daughter products produced by the biodegradation of higher-order chlorinated ethanes and ethenes, and as such, their presence can be strong indicators that biodegradation is occurring, and are therefore included in the EPA scoring matrix. On the other hand, methane and CO2 are gases produced by the natural metabolization of biomass by microorganisms in a landfill, and cis-1,2- dichloroethylene, vinyl chloride, and 1,1-dichloroethane can be primary contaminants leached ______________________________________________________________________________ Second Semiannual Water Quality Monitoring Report of 2014 Joyce Engineering Town of Kernersville Landfill, Permit No. 34-04 March 2015 7 from waste in landfills. Some of these compounds are present in the groundwater plume; however, it is unclear whether or not they are daughter products indicating natural attenuation. For this reason, the score has been calculated both with and without the points for daughter products. The following table summarizes the scoring results from Table 6 for both options for interpreting the data. The scores ranged from 11 to 23 (adequate evidence of natural attenuation to strong evidence of natural attenuation). In reality, the best score is probably in the middle of this range, indicating limited evidence of natural attenuation. Points Awarded including DP’s Points Awarded excluding DP’s 23 11 DP’s = Points for possible daughter products. 6.0 CONCLUSION Based on historical groundwater data, inorganic and organic constituents detected above their respective NC 2L and GWPS in samples collected during the November 2014 sampling event are consistent with previous events. In addition, there were no constituents detected at the surface water monitoring points above the NC 2B Standards. The Town of Kernersville Landfill will continue to monitor groundwater in accordance with the approved CAP. The next semiannual sampling event is tentatively scheduled for May 2015. 7.0 REFERENCES Brown, Philip M., Chief Geologist, 1985, Geologic Map of North Carolina, The North Carolina Geologic Survey, scale 1:500,000. Fetter, C.W., 2001, Applied Hydrogeology, Fourth Edition: Prentice-Hall, Inc.. Johnson, A.I., 1967, Specific Yield - Compilation of Specific Yields For Various Materials: U.S. Geological Survey Water Supply Paper 1662-D. Joyce Engineering, Inc. 2010. Water Quality Monitoring Plan, Piedmont Landfill & Recycling Center. September 2010. North Carolina Department of Environment and Natural Resources, 1990-2012, Solid Waste Management Regulations. USEPA, 1986, RCRA Ground Water Monitoring Technical Enforcement Guidance Document (TEGD). ______________________________________________________________________________ Second Semiannual Water Quality Monitoring Report of 2014 Joyce Engineering Town of Kernersville Landfill, Permit No. 34-04 March 2015 8 USEPA, 1992, Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance, Chapter 2, July. Tables Table 1A Summary of Historical Groundwater Elevations Table 1B Monitoring Well and Boring Completion Summary Table 2 Summary of Estimated Hydraulic Gradient and Linear Velocity Table 3 Summary of Historical Groundwater Constituents Table 4 Summary of Historical Surface Water Constituents Table 5 Summary of MNA Constituents Table 6 MNA Screening Matrix TABLE 1A SUMMARY OF HISTORICAL GROUNDWATER ELEVATIONS MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 TOC Elevation:806.42 804.87 762.19 764.57 764.56 760.26 773.32 Well Depth:34.69 20.46 13.18 24.00 56.96 14.40 11.36 30-Dec-09 772.45 786.66 759.16 751.54 752.79 754.33 769.21 01-Jun-10 773.45 788.32 758.90 750.76 752.63 753.90 769.69 16-Nov-10 773.55 787.93 759.14 750.98 752.59 753.74 769.81 29-Dec-10 773.29 787.37 758.83 749.82 752.45 753.68 769.56 29-Jun-11 773.10 786.81 758.38 750.54 752.16 753.41 769.73 01-Nov-11 771.92 785.10 758.49 754.73 751.90 753.08 769.63 01-May-12 771.88 785.32 758.54 750.86 752.34 753.55 769.55 07-Nov-12 771.65 DRY 758.20 750.30 751.61 752.87 768.57 09-May-13 769.95 787.56 759.20 752.52 753.24 754.44 - 07-Nov-13 771.46 DRY 758.09 750.12 751.50 752.79 768.13 05-Jun-14 772.22 785.84 758.45 750.67 752.14 753.36 768.57 20-Nov-14 771.73 784.41 758.08 750.24 751.53 752.81 769.23 Notes: TOC = Top of PVC well casing. Elevations in feet above mean sea level. Well depths in feet below TOC. Well ID: DowngradientBackground Town of Kernersville Landfill Permit No. 34-04 Joyce Engineering TABLE 1B MONITORING WELL AND BORING COMPLETION SUMMARY CASING GROUND DIAMETER SURFACE B.G.S.B.T.O.C. inches feet feet from to from to MW-1 2 803.89 806.42 32.16 34.69 24.69 34.96 779.2 768.9 SAPROLITE MW-2 2 760.07 762.19 11.06 13.18 3.18 13.18 756.9 746.9 SAPROLITE MW-3S 2 761.98 764.57 21.41 24.00 14 24 748.0 738.0 SAPROLITE MW-3D 2 762.02 764.56 54.42 56.96 36.96 56.96 725.1 705.1 SAPROLITE MW-4 2 757.00 760.26 11.14 14.40 4.4 14.4 752.6 742.6 SAPROLITE MW-5 2 771.00 773.32 9.04 11.36 6.36 11.36 764.6 759.6 SAPROLITE MW-6 2 801.77 804.87 17.36 20.46 10.46 20.46 791.3 781.3 SAPROLITE NOTES: B.G.S.Below Ground Surface M.S.L.Mean Sea Level B.T.O.C.Below Top of Casing T.O.C.Top of Casing *= Due to limited information this data is assumed based on field conditions TOTAL DEPTH WELL NUMBER LITHOLOGY OF SCREENED INTERVAL*T.O.C. WELL ELEVATIONS feet above M.S.L. SCREENED INTERVAL* DEPTH B.G.S.ELEV. M.S.L. Town of Kernersville Landfill Page 1 of 1 Joyce Engineering TABLE 2 SUMMARY OF ESTIMATED HYDRAULIC GRADIENT AND LINEAR VELOCITY GROUND-HORIZ.HYDRAULIC EFFECTIVE LINEAR WATER GRADIENT,CONDUCTIVITY POROSITY VELOCITY, ELEV.i K n V (feet)(ft/ft) (ft/day)(ft/day) 785 755 Notes: 1. Hydraulic conductivities (“K”) was estimated from slug test completed by JOYCE in April 2013 2. Velocity = Ki/n; assume homogeneous isotropic porous aquifer. 0.20i1SW November 2014 1.730.04 GRADIENT CALCULATION SEGMENT FLOW LINE LENGTH (feet) FLOW DIRECTION 0.30851 Town of Kernersville Landfill Permit No. 34-04 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Inorganic Compounds Antimony 30-Dec-09 1.2 6.0 ---ND 5.4 B ND ND 4.5 B ---1.4 J GWPS = 1.4 µg/L (10/23/07)01-Jun-10 1.2 6.0 ---ND ND ND ND ND ---3.9 J GWPS = 1 µg/L (8/1/10)29-Dec-10 2.6 6.0 ---ND ND ND ND ND ND ND 29-Jun-11 5.0 6.0 ---ND ND ND ND ND ND ND 01-Nov-11 5.0 6.0 ---ND ND ND ND ND ND ND 01-May-12 5.0 6.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.48 6.0 ------ND ND ND ND ---ND 09-May-13 5.0 6.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 6.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 6.0 ---ND ND ND ND ND ND ND 20-Nov-14 3.8 6.0 ------ND ND ND ND ND ND Arsenic 29-Jun-11 5.0 10.0 ---ND ND ND ND ND 6.2 J ND NC 2L = 10 µg/L (1/11/10)01-Nov-11 5.0 10.0 ---ND ND ND ND ND ND ND 01-May-12 5.0 10.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.094 10.0 ------1.43 B 1.42 B 0.87 B 1.04 B ---1.0 J 09-May-13 5.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 10.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 10.0 ---ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 ------ND 2.5 J ND ND 2.7 J ND Barium 30-Dec-09 1.1 100 ---74.1 J 496 178 18.2 J 89.0 J ---3.6 J NC 2L = 700 µg/L (1/11/10)01-Jun-10 1.1 100 ---58.1 J 326 187 22.2 J 94.9 J ---2.0 J 29-Dec-10 0.20 100 ---46.3 B 430 112 38.0 B 92.1 J 72.6 J 11.3 J 29-Jun-11 5.0 100 ---77.7 J 370 128 41.2 J 98.4 J 113 ND 01-Nov-11 5.0 100 ---125 413 132 41.7 J 111 72.1 J ND 01-May-12 5.0 100 ---78.8 J 323 121 40.0 J 99.7 J 66.1 J ND 07-Nov-12 0.39 100 ------369 127 41.0 B 98.7 J ---12.2 J 09-May-13 5.0 100 ---78.6 J 307 112 40.0 J 85.6 J ---ND 07-Nov-13 5.0 100 ------302 113 38.0 J 89.6 J ---ND 05-Jun-14 5.0 100 ---60.3 J 285 117 39.2 J 80.3 J 75.0 J ND 20-Nov-14 2.5 100 ------301 113 39.5 J 83.3 J 108 ND Beryllium 30-Dec-09 0.2 1.0 ---ND 0.5 J ND ND ND ---ND GWPS = 4 µg/L (10/23/07)01-Jun-10 0.2 1.0 ---0.6 J 0.7 J ND ND ND ---ND 29-Dec-10 0.10 1.0 ---ND ND ND ND ND 0.48 J ND 29-Jun-11 1.0 1.0 ---ND ND ND ND ND ND ND 01-Nov-11 1.0 1.0 ---ND ND ND ND ND ND ND 01-May-12 1.0 1.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.049 1.00 ------0.34 J ND ND 0.099 J ---ND 09-May-13 1.0 1.0 ---ND ND ND ND ND ---ND 07-Nov-13 1.0 1.0 ------ND ND ND ND ---ND 05-Jun-14 1.0 1.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.5 1.0 ------ND ND ND ND ND ND Cadmium 30-Dec-09 0.2 1.0 ---ND 0.5 J 5.6 ND ND ---ND NC 2L = 2 µg/L (1/11/10)01-Jun-10 0.2 1.0 ---2.9 1.0 B 5.3 0.4 B 0.4 B ---0.4 J 29-Dec-10 0.50 1.0 ---ND ND ND ND ND ND ND 29-Jun-11 1.0 1.0 ---ND ND ND ND ND ND ND 01-Nov-11 1.0 1.0 ---ND ND ND ND ND ND ND 01-May-12 1.0 1.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.026 1.00 ------0.15 J ND ND 0.043 J ---ND 09-May-13 1.0 1.0 ---ND ND ND ND ND ---ND 07-Nov-13 1.0 1.0 ------ND ND ND ND ---ND 05-Jun-14 1.0 1.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.5 1.0 ------ND ND ND ND ND ND Chromium 30-Dec-09 0.7 10.0 ---ND 2.7 J 9.7 J ND 3.1 J ---ND NC 2L = 10 µg/L (1/11/10)01-Jun-10 0.7 10.0 ---3.5 J 1.6 J 12.4 1.2 J 3.2 J ---ND 29-Dec-10 0.40 10.0 ---0.48 J 1.3 J 0.57 J ND 5.5 J 3.8 J ND 29-Jun-11 5.0 10.0 ---ND ND ND ND ND ND ND 01-Nov-11 5.0 10.0 ---ND ND ND ND 10.3 ND ND 01-May-12 5.0 10.0 ---ND ND ND ND 5.8 J ND ND 07-Nov-12 0.030 10.0 ------0.71 J 0.12 B 0.094 B 7.31 J ---0.099 J 09-May-13 5.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 10.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 10.0 ---ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 ------ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 1 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Cobalt 30-Dec-09 0.7 10.0 ---ND 6.4 J 11.2 ND 1.8 J ---ND GWPS = 70 µg/L (10/23/07)01-Jun-10 0.7 10.0 ---1.8 J 2.5 J 8.5 J ND 1.7 J ---ND GWPS = 1 µg/L (10/1/10)29-Dec-10 0.60 10.0 ---ND 4.9 J 1.7 J ND 1.6 J 10.2 ND 29-Jun-11 5.0 10.0 ---ND ND ND ND ND 9.9 J ND 01-Nov-11 5.0 10.0 ---ND ND ND ND ND 5.2 J ND 01-May-12 5.0 10.0 ---ND ND ND ND ND 13.9 ND 07-Nov-12 0.053 10.0 ------1.98 J 3.89 J 0.43 B 2.02 J ---0.24 J 09-May-13 5.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 10.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 10.0 ---ND ND ND ND ND 12.0 ND 20-Nov-14 2.5 10.0 ------ND 2.5 J ND ND 10.2 ND Copper 30-Dec-09 2.0 10.0 ---ND ND 10.6 ND 1.5 J ---ND NC 2L = 1,000 µg/L (10/23/07)01-Jun-10 2.0 10.0 ---12.2 B 3.3 B 33.2 3.9 B 6.8 B ---4.8 J 29-Dec-10 0.30 10.0 ---ND ND 0.49 J 0.59 J 1.5 J 7.9 J ND 29-Jun-11 5.0 10.0 ---ND ND ND ND ND 16.6 ND 01-Nov-11 5.0 10.0 ---ND ND ND ND 5.4 J ND ND 01-May-12 5.0 10.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.093 10.0 ------3.56 B 0.54 B 0.98 B 1.83 B ---1.23 J 09-May-13 5.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 10.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 10.0 ---ND ND ND ND ND 6.1 J ND 20-Nov-14 2.5 10.0 ------ND ND ND ND 5.3 J ND Lead 30-Dec-09 2.0 10.0 ---ND ND 10.2 ND ND ---ND NC 2L = 15 µg/L (10/23/07)01-Jun-10 2.0 10.0 ---9.1 B 8.2 B 8.7 B 3.0 B 3.9 B ---3.2 J 29-Dec-10 4.0 10.0 ---ND ND ND ND ND 6.5 J ND 29-Jun-11 5.0 10.0 ---ND ND ND ND ND 19.9 ND 01-Nov-11 5.0 10.0 ---5.5 J ND ND ND ND ND ND 01-May-12 5.0 10.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.025 10.0 ------1.00 B 0.091 B 0.066 B 1.12 B ---0.58 J 09-May-13 5.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 10.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 10.0 ---ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 ------ND ND ND ND 4.2 J ND Nickel 30-Dec-09 0.6 50.0 ---ND ND 8.1 J 1.8 J 1.6 J ---ND NC 2L = 100 µg/L (10/23/07)01-Jun-10 0.6 50.0 ---ND ND 6.0 J ND 0.9 J ---ND 29-Dec-10 1.7 50.0 ---ND ND ND ND ND 2.0 B 3.1 J 29-Jun-11 5.0 50.0 ---ND ND ND ND ND ND ND 01-Nov-11 5.0 50.0 ---ND ND ND ND ND ND ND 01-May-12 5.0 50.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.26 50.0 ------0.73 B 1.19 B 0.65 B 5.57 J ---0.84 J 09-May-13 5.0 50.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 50.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 50.0 ---ND ND ND ND ND ND ND 20-Nov-14 2.5 50.0 ------ND ND ND ND ND ND Selenium 30-Dec-09 6.3 10.0 ---ND ND 8.4 J ND ND ---ND NC 2L = 20 µg/L (1/11/10)01-Jun-10 6.3 10.0 ---ND ND 6.3 J ND ND ---ND 29-Dec-10 3.8 10.0 ---ND ND ND ND ND ND ND 29-Jun-11 10.0 10.0 ---ND ND ND ND ND ND ND 01-Nov-11 10.0 10.0 ---ND ND ND ND ND ND ND 01-May-12 10.0 10.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.11 10.0 ------0.16 J 0.38 J 0.20 J 0.25 J ---ND 09-May-13 10.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 10.0 10.0 ------ND ND ND ND ---ND 05-Jun-14 10.0 10.0 ---ND ND ND ND ND ND ND 20-Nov-14 5.0 10.0 ------ND ND ND ND ND ND Silver 30-Dec-09 1.1 10.0 ---ND 1.7 B 2.2 B ND ND ---1.9 J NC 2L = 20 µg/L (1/11/10)01-Jun-10 1.1 10.0 ---ND ND ND ND ND ---ND 29-Dec-10 0.10 10.0 ---ND 1.8 J 0.36 J 0.19 J 0.23 J ND ND 29-Jun-11 5.0 10.0 ---ND ND ND ND ND ND ND 01-Nov-11 5.0 10.0 ---ND ND ND ND ND ND ND 01-May-12 5.0 10.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.017 10.0 ------0.18 J ND ND 0.078 J ---ND 09-May-13 5.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 10.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 10.0 ---ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 ------ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 2 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Thallium 30-Dec-09 2.7 5.5 ---ND ND ND ND ND ---3.7 J GWPS = 0.28 µg/L (10/23/07)01-Jun-10 2.7 5.5 ---ND ND ND ND ND ---ND GWPS = 0.2 µg/L (10/1/10)29-Dec-10 3.0 5.5 ---ND 3.2 J ND ND 4.8 J ND ND 29-Jun-11 5.4 5.5 ---ND ND ND ND ND ND ND 01-Nov-11 5.4 5.5 ---ND ND ND ND ND ND ND 01-May-12 5.4 5.5 ---ND ND ND ND ND ND ND 07-Nov-12 0.060 5.50 ------0.16 J ND ND 0.76 J ---ND 09-May-13 5.4 5.5 ---ND ND ND ND ND ---ND 07-Nov-13 5.4 5.5 ------ND ND ND ND ---ND 05-Jun-14 5.4 5.5 ---ND ND ND ND ND ND ND 20-Nov-14 5.0 5.5 ------ND ND ND ND ND ND Vanadium 30-Dec-09 0.4 25.0 ---ND 1.4 J 37.4 1.5 J 4.3 J ---ND GWPS = 3.5 µg/L (10/23/07)01-Jun-10 0.4 25.0 ---1.2 J 3.4 J 84.2 1.4 J 4.8 J ---ND GWPS = 0.3 µg/L (10/1/10)29-Dec-10 0.20 25.0 ---1.2 B 2.8 J 2.3 J 1.6 J 5.5 J 14.5 J 0.26 J 29-Jun-11 5.0 25.0 ---ND ND ND ND ND 22.0 J ND 01-Nov-11 5.0 25.0 ---7.2 J ND ND ND 12.0 J 7.2 J ND 01-May-12 5.0 25.0 ---ND ND ND ND 7.2 J 7.6 J ND 07-Nov-12 0.085 25.0 ------2.48 J 2.02 J 2.35 J 4.55 J ---ND 09-May-13 5.0 25.0 ---ND ND ND ND ND ---ND 07-Nov-13 5.0 25.0 ------ND ND ND ND ---ND 05-Jun-14 5.0 25.0 ---ND ND 11.4 J ND ND ND ND 20-Nov-14 2.5 25.0 ------ND 3.2 J ND ND 9.4 J ND Zinc 30-Dec-09 2.7 10.0 ---ND 10.1 B 204 15.9 B 24.8 B ---5.8 J NC 2L = 1,000 µg/L (1/11/10)01-Jun-10 2.7 10.0 ---16.2 13.5 415 8.5 J 22.2 ---ND 29-Dec-10 0.40 10.0 ---12.2 B 15.8 B 8.9 B ND 4.6 B 38.1 B 12.5 29-Jun-11 10.0 10.0 ---ND 23.6 B 22.3 B ND 15.5 B 91.2 10.5 01-Nov-11 10.0 10.0 ---16.6 ND 40.0 ND 16.2 31.4 ND 01-May-12 10.0 10.0 ---ND ND 13.5 ND 10.2 12.0 ND 07-Nov-12 1.31 10.0 ------8.61 J 5.20 J 3.98 J 4.65 J ---ND 09-May-13 10.0 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 10.0 10.0 ------13.8 10.4 ND ND ---ND 05-Jun-14 10.0 10.0 ---ND ND 89.0 ND ND 19.4 ND 20-Nov-14 5.0 10.0 ------ND 20.9 ND ND 55.0 ND Organic Compounds Acetone 29-Jun-11 2.2 100 ---ND 2.3 B 2.4 B 3.9 B ND 3.8 B 5.3 J NC 2L = 6,000 µg/L (1/11/10)01-Nov-11 2.2 100 ---ND ND ND ND ND ND 14.6 J 01-May-12 2.2 100 ---ND ND ND ND ND ND ND 07-Nov-12 0.193 100 ------ND ND ND ND ---ND 09-May-13 10.0 100 ---ND ND ND ND ND ---12.0 J 07-Nov-13 10.0 100 ------ND ND ND ND ---ND 05-Jun-14 10.0 100 ---ND ND ND ND ND ND ND 20-Nov-14 10.0 100 ------ND ND ND ND ND ND Benzene 30-Dec-09 0.1 1.0 ---ND 8.4 0.3 J 0.4 J 0.3 J ---ND NC 2L = 1 µg/L (10/23/07)01-Jun-10 0.1 1.0 ---ND 2.9 ND ND ND ---ND 29-Dec-10 0.25 1.0 ---ND 8.1 ND ND ND ND ND 29-Jun-11 0.25 1.0 ---ND 7.2 0.38 J 0.45 J 0.42 J ND ND 01-Nov-11 0.25 1.0 ---ND 8.6 ND ND ND ND ND 01-May-12 0.25 1.0 ---ND 6.7 0.36 J 0.45 J 0.42 J ND ND 07-Nov-12 0.111 1.0 ------8.63 0.430 J 0.504 J 0.478 J ---ND 09-May-13 0.25 1.0 ---ND 5.2 0.27 J 0.32 J 0.30 J ---ND 07-Nov-13 0.25 1.0 ------6.9 0.33 J 0.38 J 0.39 J ---ND 05-Jun-14 0.25 1.0 ---ND 6.0 ND 0.42 J 0.40 J ND ND 20-Nov-14 0.25 1.0 ------6.2 0.30 J ND 0.32 J ND ND Bromoform 09-May-13 0.26 3.0 ---ND ND 0.37 B ND ND ---0.37 J NC 2L = µg/L 4 (10/23/07)07-Nov-13 0.26 3.0 ------ND ND ND ND ---ND 05-Jun-14 0.26 3.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.26 3.0 ------ND ND ND ND ND ND Chlorobenzene 30-Dec-09 0.1 3.0 ---ND 0.5 J 0.6 J ND ND ---ND NC 2L = 50 µg/L (10/23/07)01-Jun-10 0.1 3.0 ---ND ND ND ND ND ---ND 29-Dec-10 0.23 3.0 ---ND 0.61 J ND ND ND ND ND 29-Jun-11 0.23 3.0 ---ND 0.46 J 1.0 J 0.37 J ND ND ND 01-Nov-11 0.23 3.0 ---ND 0.59 J 1.1 J 0.37 J ND ND ND 01-May-12 0.23 3.0 ---ND {0.42}J 0.94 B 0.38 B ND ND 0.30 {ND}J 07-Nov-12 0.083 3.00 ------0.468 J 1.30 J 0.476 J ND ---ND 09-May-13 0.23 3.0 ---ND 0.27 J 0.72 J 0.27 J ND ---ND 07-Nov-13 0.23 3.0 ------0.42 J 0.97 J 0.38 J ND ---ND 05-Jun-14 0.23 3.0 ---ND 0.30 J 0.78 J 0.33 J ND ND ND 20-Nov-14 0.23 3.0 ------0.37 J 0.95 J 0.36 J ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 3 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Chloroethane 30-Dec-09 0.1 10.0 ---ND ND 0.5 J 0.5 J ND ---0.1 J NC 2L = 3,000 µg/L (1/11/10)01-Jun-10 0.1 10.0 ---ND ND 0.4 J ND ND ---ND 29-Dec-10 0.54 10.0 ---ND ND ND ND ND ND ND 29-Jun-11 0.54 10.0 ---ND ND 0.77 J ND 0.57 J ND ND 01-Nov-11 0.54 10.0 ---ND ND 0.79 J ND ND ND ND 01-May-12 0.54 10.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.235 10.0 ------ND ND ND ND ---ND 09-May-13 0.54 10.0 ---ND ND ND ND ND ---ND 07-Nov-13 0.54 10.0 ------ND ND ND ND ---ND 05-Jun-14 0.54 10.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.54 10.0 ------ND ND ND ND ND ND 1,4-Dichlorobenzene 30-Dec-09 0.1 1.0 ---ND 3.8 2.2 2.3 3.1 ---ND NC 2L = 6 µg/L (1/11/10)01-Jun-10 0.1 1.0 ---ND 1.2 0.9 J ND 1.2 ---ND 29-Dec-10 0.33 1.0 ---ND 3.9 1.1 2.3 1.9 ND ND 29-Jun-11 0.33 1.0 ---ND 3.8 2.8 3.6 3.2 ND ND 01-Nov-11 0.33 1.0 ---ND 4.7 4.1 4.1 3.5 ND ND 01-May-12 0.33 1.0 ---ND 4.0 2.7 4.1 3.2 ND ND 07-Nov-12 0.083 1.00 ------5.12 2.93 4.08 3.64 ---ND 09-May-13 0.33 1.0 ---ND 3.6 2.0 3.1 2.3 ---ND 07-Nov-13 0.33 1.0 ------5.4 2.5 4.2 3.2 ---ND 05-Jun-14 0.33 1.0 ---ND 5.0 1.9 4.0 2.7 ND ND 20-Nov-14 0.33 1.0 ------4.7 1.9 3.8 2.6 ND ND 1,1-Dichloroethane 30-Dec-09 0.2 5.0 ---ND 22.8 1.9 J 4.0 J 2.4 J ---ND NC 2L = 6 µg/L (1/11/10)01-Jun-10 0.2 5.0 ---ND 11.0 1.1 J ND 1.2 J ---ND 29-Dec-10 0.32 5.0 ---ND 28.2 2.4 J 4.1 J 2.6 J ND ND 29-Jun-11 0.32 5.0 ---ND 25.0 2.5 J 3.9 J 2.6 J ND ND 01-Nov-11 0.32 5.0 ---ND 27.2 2.3 J 4.0 J 2.3 J ND ND 01-May-12 0.32 5.0 ---ND 22.6 2.0 J 3.8 J 2.0 J ND ND 07-Nov-12 0.208 5.0 ------28.1 2.06 J 4.08 J ND ---ND 09-May-13 0.32 5.0 ---ND 18.7 1.4 J 3.0 J 1.6 J ---ND 07-Nov-13 0.32 5.0 ------26.6 1.7 J 4.2 J 2.2 J ---ND 05-Jun-14 0.32 5.0 ---ND 21.9 1.4 J 3.9 J 1.9 J ND ND 20-Nov-14 0.32 5.0 ------21.5 1.3 J 3.2 J 1.8 J ND ND 1,2-Dichloroethane 30-Dec-09 0.1 1.0 ---ND 1.2 0.7 J 1.2 ND ---ND NC 2L = 0.4 µg/L (1/11/10)01-Jun-10 0.1 1.0 ---ND ND ND ND ND ---ND 29-Dec-10 0.12 1.0 ---ND ND 0.82 J 1.1 ND ND ND 29-Jun-11 0.12 1.0 ---ND 0.76 J 0.86 J 1.3 ND ND ND 01-Nov-11 0.12 1.0 ---ND 0.95 J ND 1.3 ND ND ND 01-May-12 0.12 1.0 ---ND 0.71 J 0.70 J 1.1 ND ND ND 07-Nov-12 0.171 1.00 ------ND ND ND ND ---ND 09-May-13 0.12 1.0 ---ND 0.50 J 0.49 J 0.81 J ND ---ND 07-Nov-13 0.12 1.0 ------0.93 J 0.66 J 1.3 ND ---ND 05-Jun-14 0.12 1.0 ---ND 0.76 J 0.52 J 0.99 J ND ND ND 20-Nov-14 0.12 1.0 ------0.68 J 0.47 J 0.81 J ND ND ND 1,1-Dichloroethylene 30-Dec-09 0.1 5.0 ---ND 0.4 J ND ND ND ---ND NC 2L = 7 µg/L (10/23/07)01-Jun-10 0.1 5.0 ---ND ND ND ND ND ---ND 29-Dec-10 0.56 5.0 ---ND ND ND ND ND ND ND 29-Jun-11 0.56 5.0 ---ND ND ND ND ND ND ND 01-Nov-11 0.56 5.0 ---ND ND ND ND ND ND ND 01-May-12 0.56 5.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.208 5.00 ------ND ND ND ND ---ND NC 2L = 350 µg/L (04/01/2013)09-May-13 0.56 5.0 ---ND ND ND ND ND ---ND 07-Nov-13 0.56 5.0 ------ND ND ND ND ---ND 05-Jun-14 0.56 5.0 ---ND 4.7 J ND ND ND ND ND 20-Nov-14 0.56 5.0 ---ND ND ND ND ND ND ND cis-1,2-Dichloroethene 30-Dec-09 0.1 5.0 ---ND 68.2 11.0 51.0 21.8 ---ND NC 2L = 70 µg/L (10/23/07)01-Jun-10 0.1 5.0 ---ND 23.0 7.6 ND 10.2 ---ND 29-Dec-10 0.19 5.0 ---ND 66.7 16.8 56.7 24.1 ND ND 29-Jun-11 0.19 5.0 ---ND 55.1 16.5 62.7 25.1 ND ND 01-Nov-11 0.19 5.0 ---ND 59.4 15.2 59.3 23.2 ND ND 01-May-12 0.19 5.0 ---ND {48.7}14.2 59.5 22.1 ND 0.21 {ND}J 07-Nov-12 0.103 5.00 ------59.7 13.6 71.3 26.4 ---ND 09-May-13 0.19 5.0 ---ND 39.9 10.9 49.7 17.4 ---ND 07-Nov-13 0.19 5.0 ------53.9 10.7 67.1 21.8 ---ND 05-Jun-14 0.19 5.0 ---ND 47.0 11.2 58.1 20.0 ND ND 20-Nov-14 0.19 5.0 ------44.9 9.6 55.4 19.3 ND ND Town of Kernersville Landfill Permit No. 34-04 Page 4 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks trans-1,2-Dichloroethene 30-Dec-09 0.1 5.0 ---ND 1.4 J ND 0.2 J 0.2 J ---ND NC 2L = 100 µg/L (10/23/07)01-Jun-10 0.1 5.0 ---ND 0.6 J ND ND ND ---ND 29-Dec-10 0.49 5.0 ---ND 1.7 J ND ND ND ND ND 29-Jun-11 0.49 5.0 ---ND 1.5 J ND ND ND ND ND 01-Nov-11 0.49 5.0 ---ND 1.6 J ND ND ND ND ND 01-May-12 0.49 5.0 ---ND 1.4 J ND ND ND ND ND 07-Nov-12 0.077 5.00 ------1.59 J ND ND ND ---ND 09-May-13 0.49 5.0 ---ND 1.1 J ND ND ND ---ND 07-Nov-13 0.49 5.0 ------1.6 J ND ND ND ---ND 05-Jun-14 0.49 5.0 ---ND 1.4 J ND ND ND ND ND 20-Nov-14 0.49 5.0 ------1.4 J ND ND ND ND ND 1,2-Dichloropropane 30-Dec-09 0.1 1.0 ---ND 5.7 0.6 J 1.1 0.7 J ---ND NC 2L = 0.6 µg/L (1/11/10)01-Jun-10 0.1 1.0 ---ND 1.9 ND ND ND ---ND 29-Dec-10 0.27 1.0 ---ND 5.3 ND ND ND ND ND 29-Jun-11 0.27 1.0 ---ND 4.8 0.90 J 1.3 0.73 J ND ND 01-Nov-11 0.27 1.0 ---ND 4.9 0.76 J 1.3 ND ND ND 01-May-12 0.27 1.0 ---ND 4.4 0.76 J 1.4 0.62 J ND ND 07-Nov-12 0.150 1.0 ------4.93 ND 1.66 ND ---ND 09-May-13 0.27 1.0 ---ND 3.3 0.51 J 0.96 J 0.45 J ---ND 07-Nov-13 0.27 1.0 ------4.4 0.63 J 1.3 0.57 J ---ND 05-Jun-14 0.27 1.0 ---ND 4.0 0.51 J ND 0.41 J ND ND 20-Nov-14 0.27 1.0 ------4.1 0.56 J 1.2 0.36 J ND ND Ethylbenzene 30-Dec-09 0.1 1.0 ---ND ND ND 0.4 J ND ---ND NC 2L = 600 µg/L (10/23/07)01-Jun-10 0.1 1.0 ---ND ND ND ND ND ---ND 29-Dec-10 0.30 1.0 ---ND ND ND ND ND ND ND 29-Jun-11 0.30 1.0 ---ND ND ND ND ND ND ND 01-Nov-11 0.30 1.0 ---ND ND ND ND ND ND ND 01-May-12 0.30 1.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.109 1.00 ------ND ND ND ND ---ND 09-May-13 0.30 1.0 ---ND ND ND ND ND ---ND 07-Nov-13 0.30 1.0 ------ND ND ND ND ---ND 05-Jun-14 0.30 1.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.30 1.0 ------ND ND ND ND ND ND Tetrachloroethene 30-Dec-09 0.2 1.0 ---ND 1.2 ND ND ND ---ND NC 2L = 0.7 µg/L (10/23/07)01-Jun-10 0.2 1.0 ---ND 1.4 ND ND ND ---ND 29-Dec-10 0.46 1.0 ---ND 2.8 ND ND ND ND ND 29-Jun-11 0.46 1.0 ---ND 3.6 ND ND ND ND ND 01-Nov-11 0.46 1.0 ---ND 2.9 ND ND ND ND ND 01-May-12 0.46 1.0 ---ND 3.0 ND ND ND ND ND 07-Nov-12 0.193 1.00 ------2.52 ND ND ND ---ND 09-May-13 0.46 1.0 ---ND 1.9 ND ND ND ---ND 07-Nov-13 0.46 1.0 ------1.8 ND ND ND ---ND 05-Jun-14 0.46 1.0 ---ND 2.3 ND ND ND ND ND 20-Nov-14 0.46 1.0 ------1.1 ND ND ND ND ND Toluene 29-Jun-11 0.26 1.0 ---ND ND ND ND ND 0.76 J ND NC 2L = 600 µg/L (1/11/10)01-Nov-11 0.26 1.0 ---ND ND ND ND ND ND ND 01-May-12 0.26 1.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.122 1.00 ------ND ND ND ND ---ND 09-May-13 0.26 1.0 ---ND ND ND ND ND ---ND 07-Nov-13 0.26 1.0 ------ND ND ND ND ---ND 05-Jun-14 0.26 1.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.26 1.0 ------ND ND ND ND ND ND Trichloroethene 30-Dec-09 0.1 1.0 ---ND 8.0 ND ND 0.2 J ---ND NC 2L = 3 µg/L (1/11/10)01-Jun-10 0.1 1.0 ---ND 6.4 ND ND ND ---ND 29-Dec-10 0.47 1.0 ---ND 10.1 ND ND ND ND ND 29-Jun-11 0.47 1.0 ---ND 14.6 ND ND ND ND ND 01-Nov-11 0.47 1.0 ---ND 10.2 ND ND ND ND ND 01-May-12 0.47 1.0 ---ND 11.6 ND ND ND ND ND 07-Nov-12 0.161 1.00 ------9.97 ND ND ND ---ND 09-May-13 0.47 1.0 ---ND 8.4 ND ND ND ---ND 07-Nov-13 0.47 1.0 ------8.0 ND ND ND ---ND 05-Jun-14 0.47 1.0 ---ND 8.9 ND ND ND ND ND 20-Nov-14 0.47 1.0 ------5.1 ND ND ND ND ND Trichlorofluoromethane 29-Jun-11 0.20 1.0 ---ND 0.95 J ND ND ND ND ND NC 2L = 2000 µg/L (1/11/10)01-Nov-11 0.20 1.0 ---ND ND ND ND ND ND ND 01-May-12 0.20 1.0 ---ND ND ND ND ND ND ND 07-Nov-12 0.157 1.00 ------ND ND ND ND ---ND 09-May-13 0.20 1.0 ---ND 0.66 J ND ND ND ---ND 07-Nov-13 0.20 1.0 ------ND ND ND ND ---ND 05-Jun-14 0.20 1.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.20 1.0 ------ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 5 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Vinyl chloride 30-Dec-09 0.1 1.0 ---ND 4.0 2.8 4.1 26.2 ---ND NC 2L = 0.03 µg/L (1/11/10)01-Jun-10 0.1 1.0 ---ND 2.2 3.0 ND 26.7 ---ND 29-Dec-10 0.62 1.0 ---ND 3.5 2.4 4.7 25.6 ND ND 29-Jun-11 0.62 1.0 ---ND 2.8 2.8 4.6 28.7 ND ND 01-Nov-11 0.62 1.0 ---ND 5.1 2.6 6.9 24.0 ND ND 01-May-12 0.62 1.0 ---ND 3.5 2.0 4.8 21.8 ND ND 07-Nov-12 0.127 1.00 ------7.94 2.73 6.99 29.9 ---ND 09-May-13 0.62 1.0 ---ND 2.8 1.9 4.2 18.6 ---ND 07-Nov-13 0.62 1.0 ------6.3 2.1 6.0 21.9 ---ND 05-Jun-14 0.62 1.0 ---ND 7.1 5.6 8.9 21.9 ND ND 20-Nov-14 0.62 1.0 ------5.2 2.1 5.3 16.2 ND ND Xylene (Total)30-Dec-09 0.3 4.0 ---ND ND ND 3.5 J ND ---ND NC 2L = 500 µg/L (1/11/10)01-Jun-10 0.3 4.0 ---ND ND ND ND ND ---ND 29-Dec-10 0.66 2.0 ---ND ND ND ND ND ND ND 29-Jun-11 0.66 2.0 ---ND ND ND ND ND ND ND 01-Nov-11 0.66 2.0 ---ND ND ND ND ND ND ND 01-May-12 0.66 2.0 ---ND 0.89 J ND ND ND ND ND 07-Nov-12 0.179 5.00 ------ND ND ND ND ---ND 09-May-13 0.66 5.0 ---ND ND ND ND ND ---ND 07-Nov-13 0.66 5.0 ------ND ND ND ND ---ND 05-Jun-14 0.66 5.0 ---ND ND ND ND ND ND ND 20-Nov-14 0.66 5.0 ------ND ND ND ND ND ND Notes: 1. RL = Reporting limit (NC SWSL). 2. All concentrations are in micrograms per liter (ug/L). 3. NC 2L Standard is the groundwater quality standard established under 15A NCAC 2L. 4. MW = Monitoring well. 5. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. 6. ND = Not detected at the laboratory's detection limit. 7. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. 8. B = Probable field and/or laboratory contamination since the concentration is within five times the concentration reported in the associated quality control blanks. 9. Bold values are greater than the NC 2L Standard or GWPS. 10. DL = Detection limit. 11. GWPS = Groundwater Protection Standard (GWPS is used when the NC 2L Standard has not been established.) 12. --- = Monitoring well was no sampled. Town of Kernersville Landfill Permit No. 34-04 Page 6 of 6 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Inorganic Compounds Antimony 30-Dec-09 1.2 6.0 1.5 B 6.4 B NS 1.4 J NC 2B = NE µg/L (05/01/07)01-Jun-10 1.2 6.0 6.7 B 2.5 B NS 3.9 J 29-Dec-10 2.6 6.0 ND ND ND ND 29-Jun-11 5.0 6.0 ND ND ND ND 01-Nov-11 5.0 6.0 ND ND ND ND 01-May-12 5.0 6.0 ND ND ND ND 07-Nov-12 0.48 6.0 ND ND ND ND 09-May-13 5.0 6.0 ND ND ND ND 07-Nov-13 5.0 6.0 ND ND ND ND 05-Jun-14 5.0 6.0 ND ND ND ND 20-Nov-14 3.8 6.0 ND ND ND ND Arsenic 07-Nov-12 0.094 10.0 0.17 B 0.26 B 0.24 B 1.0 J NC 2B = 50 µg/L (05/01/07)09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Barium 30-Dec-09 1.1 100 25.1 J 34 J NS 3.4 J NC 2B = NE µg/L (05/01/07)01-Jun-10 1.1 100 28.8 J 31.5 J NS 2.0 J 29-Dec-10 0.20 100 22.3 B 27.8 B 27.9 B 11.3 J 29-Jun-11 5.0 100 40.0 J 39.4 J 39.3 J ND 01-Nov-11 5.0 100 30.1 J 35.2 J 34.3 J ND 01-May-12 5.0 100 66.1 J 35.4 J 33.3 J ND 07-Nov-12 0.39 100 27.6 B 31.5 B 29.9 B 12.2 J 09-May-13 5.0 100 33.6 J 33.8 J 32.6 J ND 07-Nov-13 5.0 100 36.6 J 32.0 J 29.8 J ND 05-Jun-14 5.0 100 31.2 J 35.8 J 33.6 J ND 20-Nov-14 2.5 100 26.6 J 31.2 J 29.4 J ND Cadmium 30-Dec-09 0.2 1.0 ND ND NS ND NC 2B = 2 µg/L (05/01/07)01-Jun-10 0.2 1.0 0.9 B 0.4 B NS 0.4 J 29-Dec-10 0.50 1.0 ND ND ND ND 29-Jun-11 1.0 1.0 ND ND ND ND 01-Nov-11 1.0 1.0 ND ND ND ND 01-May-12 1.0 1.0 ND ND ND ND 07-Nov-12 0.026 1.000 ND ND ND ND 09-May-13 1.0 1.0 ND ND ND ND 07-Nov-13 1.0 1.0 ND ND ND ND 05-Jun-14 1.0 1.0 ND ND ND ND 20-Nov-14 0.5 1.0 ND ND ND ND Chromium 30-Dec-09 0.7 10.0 ND ND NS ND NC 2B = 50 µg/L (05/01/07)01-Jun-10 0.7 10.0 1.7 J 1.2 J NS ND 29-Dec-10 0.40 10.0 0.69 J 0.53 J 0.41 J ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.030 10.0 0.29 B 0.13 B 0.11 B 0.099 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND 2.7 J ND Town of Kernersville Landfill Permit No. 34-04 Page 1 of 3 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Cobalt 30-Dec-09 0.7 10.0 ND ND NS ND NC 2B = NE µg/L (05/01/07)01-Jun-10 0.7 10.0 ND ND NS ND 29-Dec-10 0.60 10.0 ND 1.8 J 1.9 J ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.053 10.0 0.34 B 0.76 B 0.76 B 0.24 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Copper 30-Dec-09 2.0 10.0 ND ND NS ND NC 2B = 7 µg/L (05/01/07)01-Jun-10 2.0 10.0 6.9 B 5.8 B NS 4.8 J 29-Dec-10 0.30 10.0 0.38 J ND ND ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.093 10.0 0.27 B 0.38 B 0.38 B 1.23 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Lead 30-Dec-09 2.0 10.0 ND ND NS ND NC 2B = 25 µg/L (05/01/07)01-Jun-10 2.0 10.0 2.7 B 2.8 B NS 3.2 J 29-Dec-10 4.0 10.0 ND ND ND ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.025 10.0 0.071 B 0.049 B 0.060 B 0.58 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Nickel 07-Nov-12 0.26 50.0 0.46 B 0.39 B 0.35 B 0.84 J NC 2B = 88 µg/L (05/01/07)09-May-13 5.0 50.0 ND ND ND ND 07-Nov-13 5.0 50.0 ND ND ND ND 05-Jun-14 5.0 50.0 ND ND ND ND 20-Nov-14 2.5 50.0 ND ND ND ND Vanadium 30-Dec-09 0.4 25.0 2.0 J 0.8 J NS ND NC 2B = NE µg/L (05/01/07)01-Jun-10 0.4 25.0 2.2 J 2.4 J NS ND 29-Dec-10 0.20 25.0 0.67 B 0.37 B 0.62 B 0.26 J 29-Jun-11 5.0 25.0 ND ND ND ND 01-Nov-11 5.0 25.0 ND ND ND ND 01-May-12 5.0 25.0 ND ND ND ND 07-Nov-12 0.085 25.0 0.63 J 0.44 J 0.52 J ND 09-May-13 5.0 25.0 7.8 J 9.1 J 9.4 J ND 07-Nov-13 5.0 25.0 ND ND ND ND 05-Jun-14 5.0 25.0 ND ND ND ND 20-Nov-14 2.5 25.0 ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 2 of 3 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Zinc 30-Dec-09 2.7 10.0 6.7 B ND NS 4.7 J NC 2B = 50 µg/L (05/01/07)01-Jun-10 2.7 10.0 6.7 J 8.7 J NS ND 29-Dec-10 0.40 10.0 ND 1.2 B 1.2 B 12.5 29-Jun-11 10.0 10.0 ND ND ND 10.5 01-Nov-11 10.0 10.0 ND ND ND ND 01-May-12 10.0 10.0 ND ND ND ND 07-Nov-12 1.31 10.0 ND ND 1.56 J ND 09-May-13 10.0 10.0 ND ND ND ND 07-Nov-13 10.0 10.0 ND ND ND ND 05-Jun-14 10.0 10.0 ND ND ND ND 20-Nov-14 5.0 10.0 ND ND ND ND Organic Compounds Acetone 29-Jun-11 2.2 100 2.8 B 3.3 B 4.4 B 5.3 J NC 2B = NE µg/L (05/01/07)01-Nov-11 2.2 100 ND ND ND 14.6 J 01-May-12 2.2 100 ND ND ND ND 07-Nov-12 0.193 100 ND ND ND ND 09-May-13 10.0 100 ND ND ND 12.0 J 07-Nov-13 10.0 100 ND ND ND ND 05-Jun-14 10.0 100 ND ND ND ND 20-Nov-14 10.0 100 ND ND ND ND cis-1,2-Dichloroethene 30-Dec-09 0.1 5.0 ND ND NS ND NC 2B = NE µg/L (05/01/07)01-Jun-10 0.1 5.0 ND ND NS ND 29-Dec-10 0.19 5.0 ND 0.39 J ND ND 29-Jun-11 0.19 5.0 0.26 J 0.30 J 0.33 J ND 01-Nov-11 0.19 5.0 ND ND ND ND 01-May-12 0.19 5.0 0.31 B ND ND 0.21 (ND)J 07-Nov-12 0.103 5.00 ND ND ND ND 09-May-13 0.19 5.0 ND ND ND ND 07-Nov-13 0.19 5.0 ND 0.38 J ND ND 05-Jun-14 0.19 5.0 ND 0.33 J ND ND 20-Nov-14 0.19 5.0 ND 0.49 J ND ND Notes: 1. RL = Reporting limit (NC SWSL). 2. All concentrations are in micrograms per liter (ug/L). 3. NC 2B Standard is the surface water quality standard. Classification is currently Freshwater Aquatic Life. 4. NS = Not sampled. 5. SMP = Surface water monitoring point. 6. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. 7. ND = Not detected at the laboratory's detection limit. 8. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. 9. B = Blank Qualifed 10. Shaded values are greater than the established NC 2B Surface Water Quality Standards. 11. DL = Detection limit. 12. NE = Not established. Town of Kernersville Landfill Permit No. 34-04 Page 3 of 3 Joyce Engineering TABLE 5 SUMMARY OF MNA CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 Alkalinity, Total as CaCO3 Jun-14 1000.0 5000 ---4600 J 148000 147000 160000 186000 (ug/L)Nov-14 1000.0 5000 ------159000 151000 159000 181000 Sulfate Jun-14 2000 250000 ---6500 J ND ND ND ND (ug/L)Nov-14 1000 250000 ------1760 J 1730 J 1870 J 1560 J Nitrogen, Nitrate Jun-14 20.0 1000 ---72 J 56 J ND ND ND (ug/L)Nov-14 10.0 1000 ------45 J ND ND ND Methane Jun-14 3.3 6.6 ------5530 254 242 515 (ug/L)Nov-14 3.3 6.6 ------4980 159 182 186 Chloride Jun-14 1000 1000 ---2220 11200 25900 16800 15600 (ug/L)Nov-14 500 1000 ------17100 27900 17300 17100 Total Organic Carbon Jun-14 1000 1000 ---3100 10600 8300 1500 8200 (ug/L)Nov-14 500 1000 ------2150 1750 1370 1100 Hydrogen Jun-14 0.13 0.6 ------1.5 1.2 120 3.5 (nM)Nov-14 0.13 0.6 ------2.0 1.1 4.4 1.4 BOD, 5 day Jun-14 2000 2000 ---ND ND ND ND ND (ug/L)Nov-14 2000 2000 ------4900 ND ND ND Chemical Oxygen Demand Jun-14 12500 25000 ---ND ND ND ND ND (ug/L)Nov-14 12500 25000 ------ND ND 431000 ND Notes: MW = Monitoring well. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. ND = Not detected at the laboratory's detection limit. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. B = Probable field and/or laboratory contamination since the concentration is within five times the concentration reported in the associated quality control blanks. DL = Detection limit. QL = Quantitation limit (NC SWSL). --- = Monitoring well was not sampled. Town of Kernersville Landfill Permit No. 34-04 Page 1 of 1 Joyce Engineering TABLE 6: BIODEGRADATION SCREENING MATRIX Parameter Concentration Interpretation Possible Points Awarded Points Awarded in Plume Points with DP points without DP points Oxygen < 0.5 mg/L Tolerated, suppresses the reductive pathway at higher 3 0 0 concentrations > 5 mg/L Not tolerated; however, vinyl chloride may be oxidized -3 0 0 aerobically Nitrate < 1 mg/L At higher concentrations may compete with reductive 2 2 2 pathway Iron II (Ferrous Iron)> 1 mg/L Reductive pathway possible; vinyl chloride may be 3 0 0 oxidized under Fe (III) - reducing conditions Sulfate < 20 mg/L At higher concentrations may compete with reductive 2 2 2 pathway Sulfide > 1 mg/L Reductive pathway possible 3 0 0 Methane < 0.5 mg/L Vinyl chloride oxidizes 0 > 0.5 mg/L Ultimate reductive daughter product, vinyl chloride 3 0 0 accumulates Oxidation Reduction < 50 mV Reductive pathway possible 1 1 1 Potential < -100 mV Reductive pathway likely 2 pH 5 < pH < 9 Optimal range for reductive pathway 0 0 0 5 > pH > 9 Outside optimal range for reductive pathway -2 0 0 TOC > 20 mg/L Carbon and energy source; drives dechlorination; can 2 0 0 be natural or anthropogenic Temperature >20o C At T > 20oC biochemical process is accelerated 1 0 0 Carbon Dioxide > 2x background Ultimate oxidative daughter product 1 0 0 Alkalinity > 2x background Results from interaction between CO2 and 1 1 1 aquifer minerals Chloride > 2x background Daughter product of organic chlorine 2 2 2 Hydrogen > 1 nM Reductive pathway possible 3 3 3 < 1 nM Vinyl chloride oxidizes 0 Volatile Fatty Acids > 0.1 mg/L Intermediates resulting from biodegradation of more 2 0 0 complex compounds; carbon and energy source BTEX > 0.1 mg/L Carbon and energy source; drives dechlorination 2 0 0 Tetrachloroethene (PCE)---Material released 0 0 0 Trichloroethene (TCE)---Material released 0 0 0 ---Daughter product of PCE 2 2 0 Dichloroethenes (DCE)---Material released 0 0 0 Daughter product of TCE 2 2 0 Dichloroethene, cis-1,2,---Material released 0 0 0 ---Daughter product of trichlorethene 2 2 0 Vinyl Chloride (VC)---Material released 0 0 0 ---Daughter product of DCE 2 2 0 1,1,1-Trichloroethane (TCA)---Material released 0 0 0 1,1-Dichloroethane (DCA)---Material released 0 0 0 Daughter product of TCA 2 2 0 Chloroethane ---Daughter product of dichloroethane or vinyl chloride 0 0 0 under reducing conditions 2 2 0 Ethene/Ethane > 0.01 mg/L Daughter products of vinyl chloride/ethene 2 0 0 > 0.1 mg/L 3 0 0 Chloroform ---Material released 0 0 0 ---Daughter product of carbon tetrachloride 2 0 0 Dichloromethane (MC)---Material released 0 0 0 (Methylene Chloride)---Daughter product of chloroform 2 0 0 Based on data collected in November 2014.Total Points Awarded :23 11 mg/L = miligrams per liter mV = millivolts NOTE: Chloroethane, Methane, TCE, DCE, cis-1,2-DCE, MC, VC, DCA, and CO2 are all present in the plume; however, nM = Nanometer it is uncertain whether these are primary leachate constituents or daughter products (DPs); therefore, we C = Celcius have two calculation columns. The first column assumes all of these are daughter products, and the NA = Not Analyzed second column assumes none of them are. The true score is probably between the two. BTEX = Sum of Benzene, Toluene, Ethylbenzene, and Total Xylenes SCORE:Evid. of Nat. Atten. This screening matrix is prepared in general accordance with the United Stated Environmental Protection Agency's < 5 inadequate (EPA's) Table 2.3 Analytical Parameters and Weighted for Preliminary Screening for Anaerobic Biodegradation 6-14 limited Process presented in the EPA's Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents 15-19 adequate in Groundwater , September 1988.> 20 strong Town of Kernersville Joyce Engineering Figure Figure 1 Site Location Map Drawing Drawing 1 Potentiometric Surface Contour Map Appendix I Laboratory Analytical Report and Field Data Logs #=CL# December 03, 2014 LIMS USE: FR - ALEX EVERHART LIMS OBJECT ID: 92226774 92226774 Project: Pace Project No.: RE: Mr. Alex Everhart Joyce Engineering-NC 2211 W. Meadowview Road Suite 101 Greensboro, NC 27407 Town of Kernersville Dear Mr. Everhart: Enclosed are the analytical results for sample(s) received by the laboratory on November 21, 2014. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Godwin kevin.godwin@pacelabs.com Project Manager Enclosures cc:Mr. Van Burbach, Joyce Engineering-NC Alex Everhart, Joyce Engineering-NC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 35 #=CP# CERTIFICATIONS Pace Project No.: Project: 92226774 Town of Kernersville Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84 West Virginia Certification #: 357Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 35 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92226774 Town of Kernersville Lab ID Sample ID Matrix Date Collected Date Received 92226774001 3404-MW2 Water 11/20/14 10:45 11/21/14 14:25 92226774002 3404-MW3S Water 11/20/14 12:40 11/21/14 14:25 92226774003 3404-MW3D Water 11/20/14 13:00 11/21/14 14:25 92226774004 3404-MW4 Water 11/20/14 15:00 11/21/14 14:25 92226774005 3404-MW5 Water 11/20/14 16:10 11/21/14 14:25 92226774006 3404-SW1 Water 11/20/14 11:15 11/21/14 14:25 92226774007 3404-SW2 Water 11/20/14 14:40 11/21/14 14:25 92226774008 3404-SW3 Water 11/20/14 11:30 11/21/14 14:25 92226774009 3404-Field Blank Water 11/20/14 16:20 11/21/14 14:25 92226774010 3404-Trip Blank Water 11/20/14 08:45 11/21/14 14:25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 35 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92226774 Town of Kernersville Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92226774001 3404-MW2 EPA 6010 15 PASI-AJMW EPA 8260 50 PASI-CGAW 92226774002 3404-MW3S EPA 6010 15 PASI-AJMW EPA 8260 50 PASI-CGAW 92226774003 3404-MW3D EPA 6010 15 PASI-AJMW EPA 8260 50 PASI-CGAW 92226774004 3404-MW4 EPA 6010 15 PASI-AJMW EPA 8260 50 PASI-CGAW 92226774005 3404-MW5 EPA 6010 15 PASI-AJMW EPA 8260 50 PASI-CGAW 92226774006 3404-SW1 EPA 6010 15 PASI-AJMW EPA 8260 50 PASI-CGAW 92226774007 3404-SW2 EPA 6010 15 PASI-AJMW EPA 8260 50 PASI-CGAW 92226774008 3404-SW3 EPA 6010 15 PASI-AJMW EPA 8260 50 PASI-CGAW 92226774009 3404-Field Blank EPA 6010 15 PASI-AJMW EPA 8260 50 PASI-CGAW 92226774010 3404-Trip Blank EPA 8260 50 PASI-CGAW REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 35 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226774 Town of Kernersville Sample:3404-MW2 Lab ID:92226774001 Collected:11/20/14 10:45 Received:11/21/14 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/25/14 18:25 7440-36-011/24/14 16:206.0 3.8 1 Arsenic ND ug/L 11/25/14 18:25 7440-38-211/24/14 16:2010.0 2.5 1 Barium 301 ug/L 11/25/14 18:25 7440-39-311/24/14 16:201002.5 1 Beryllium ND ug/L 11/25/14 18:25 7440-41-711/24/14 16:201.0 0.50 1 Cadmium ND ug/L 11/25/14 18:25 7440-43-911/24/14 16:201.0 0.50 1 Chromium ND ug/L 11/25/14 18:25 7440-47-311/24/14 16:2010.0 2.5 1 Cobalt ND ug/L 11/25/14 18:25 7440-48-411/24/14 16:2010.0 2.5 1 Copper ND ug/L 11/25/14 18:25 7440-50-811/24/14 16:2010.0 2.5 1 Lead ND ug/L 11/25/14 18:25 7439-92-111/24/14 16:2010.0 2.5 1 Nickel ND ug/L 11/25/14 18:25 7440-02-011/24/14 16:2050.0 2.5 1 Selenium ND ug/L 11/25/14 18:25 7782-49-211/24/14 16:2010.0 5.0 1 Silver ND ug/L 11/25/14 18:25 7440-22-411/24/14 16:2010.0 2.5 1 Thallium ND ug/L 11/25/14 18:25 7440-28-011/24/14 16:205.5 5.0 1 Vanadium ND ug/L 11/25/14 18:25 7440-62-211/24/14 16:2025.0 2.5 1 Zinc ND ug/L 11/25/14 18:25 7440-66-611/24/14 16:2010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 11/25/14 15:25 67-64-110010.0 1 Acrylonitrile ND ug/L 11/25/14 15:25 107-13-12001.9 1 Benzene 6.2 ug/L 11/25/14 15:25 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 11/25/14 15:25 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 11/25/14 15:25 75-27-41.0 0.18 1 Bromoform ND ug/L 11/25/14 15:25 75-25-23.0 0.26 1 Bromomethane ND ug/L 11/25/14 15:25 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 11/25/14 15:25 78-93-31000.96 1 Carbon disulfide ND ug/L 11/25/14 15:25 75-15-01001.2 1 Carbon tetrachloride ND ug/L 11/25/14 15:25 56-23-51.0 0.25 1 Chlorobenzene 0.37J ug/L 11/25/14 15:25 108-90-73.0 0.23 1 Chloroethane ND ug/L 11/25/14 15:25 75-00-310.0 0.54 1 Chloroform ND ug/L 11/25/14 15:25 67-66-35.0 0.14 1 Chloromethane ND ug/L 11/25/14 15:25 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 11/25/14 15:25 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 11/25/14 15:25 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 11/25/14 15:25 106-93-41.0 0.27 1 Dibromomethane ND ug/L 11/25/14 15:25 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 11/25/14 15:25 95-50-15.0 0.30 1 1,4-Dichlorobenzene 4.7 ug/L 11/25/14 15:25 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 11/25/14 15:25 110-57-61001.0 1 1,1-Dichloroethane 21.5 ug/L 11/25/14 15:25 75-34-35.0 0.32 1 1,2-Dichloroethane 0.68J ug/L 11/25/14 15:25 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 11/25/14 15:25 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 44.9 ug/L 11/25/14 15:25 156-59-25.0 0.19 1 trans-1,2-Dichloroethene 1.4J ug/L 11/25/14 15:25 156-60-55.0 0.49 1 1,2-Dichloropropane 4.1 ug/L 11/25/14 15:25 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 11/25/14 15:25 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 11/25/14 15:25 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 35 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226774 Town of Kernersville Sample:3404-MW2 Lab ID:92226774001 Collected:11/20/14 10:45 Received:11/21/14 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Ethylbenzene ND ug/L 11/25/14 15:25 100-41-41.0 0.30 1 2-Hexanone ND ug/L 11/25/14 15:25 591-78-650.0 0.46 1 Iodomethane ND ug/L 11/25/14 15:25 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 11/25/14 15:25 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 11/25/14 15:25 108-10-11000.33 1 Styrene ND ug/L 11/25/14 15:25 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 11/25/14 15:25 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 11/25/14 15:25 79-34-53.0 0.40 1 Tetrachloroethene 1.1 ug/L 11/25/14 15:25 127-18-41.0 0.46 1 Toluene ND ug/L 11/25/14 15:25 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 11/25/14 15:25 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 11/25/14 15:25 79-00-51.0 0.29 1 Trichloroethene 5.1 ug/L 11/25/14 15:25 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 11/25/14 15:25 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 11/25/14 15:25 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 11/25/14 15:25 108-05-450.0 0.35 1 Vinyl chloride 5.2 ug/L 11/25/14 15:25 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 11/25/14 15:25 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)96 %11/25/14 15:25 460-00-470-130 1 1,2-Dichloroethane-d4 (S)104 %11/25/14 15:25 17060-07-070-130 1 Toluene-d8 (S)102 %11/25/14 15:25 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 35 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226774 Town of Kernersville Sample:3404-MW3S Lab ID:92226774002 Collected:11/20/14 12:40 Received:11/21/14 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/25/14 18:28 7440-36-011/24/14 16:206.0 3.8 1 Arsenic 2.5J ug/L 11/25/14 18:28 7440-38-211/24/14 16:2010.0 2.5 1 Barium 113 ug/L 11/25/14 18:28 7440-39-311/24/14 16:201002.5 1 Beryllium ND ug/L 11/25/14 18:28 7440-41-711/24/14 16:201.0 0.50 1 Cadmium ND ug/L 11/25/14 18:28 7440-43-911/24/14 16:201.0 0.50 1 Chromium ND ug/L 11/25/14 18:28 7440-47-311/24/14 16:2010.0 2.5 1 Cobalt 2.5J ug/L 11/25/14 18:28 7440-48-411/24/14 16:2010.0 2.5 1 Copper ND ug/L 11/25/14 18:28 7440-50-811/24/14 16:2010.0 2.5 1 Lead ND ug/L 11/25/14 18:28 7439-92-111/24/14 16:2010.0 2.5 1 Nickel ND ug/L 11/25/14 18:28 7440-02-011/24/14 16:2050.0 2.5 1 Selenium ND ug/L 11/25/14 18:28 7782-49-211/24/14 16:2010.0 5.0 1 Silver ND ug/L 11/25/14 18:28 7440-22-411/24/14 16:2010.0 2.5 1 Thallium ND ug/L 11/25/14 18:28 7440-28-011/24/14 16:205.5 5.0 1 Vanadium 3.2J ug/L 11/25/14 18:28 7440-62-211/24/14 16:2025.0 2.5 1 Zinc 20.9 ug/L 11/25/14 18:28 7440-66-611/24/14 16:2010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 11/25/14 15:41 67-64-110010.0 1 Acrylonitrile ND ug/L 11/25/14 15:41 107-13-12001.9 1 Benzene 0.30J ug/L 11/25/14 15:41 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 11/25/14 15:41 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 11/25/14 15:41 75-27-41.0 0.18 1 Bromoform ND ug/L 11/25/14 15:41 75-25-23.0 0.26 1 Bromomethane ND ug/L 11/25/14 15:41 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 11/25/14 15:41 78-93-31000.96 1 Carbon disulfide ND ug/L 11/25/14 15:41 75-15-01001.2 1 Carbon tetrachloride ND ug/L 11/25/14 15:41 56-23-51.0 0.25 1 Chlorobenzene 0.95J ug/L 11/25/14 15:41 108-90-73.0 0.23 1 Chloroethane ND ug/L 11/25/14 15:41 75-00-310.0 0.54 1 Chloroform ND ug/L 11/25/14 15:41 67-66-35.0 0.14 1 Chloromethane ND ug/L 11/25/14 15:41 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 11/25/14 15:41 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 11/25/14 15:41 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 11/25/14 15:41 106-93-41.0 0.27 1 Dibromomethane ND ug/L 11/25/14 15:41 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 11/25/14 15:41 95-50-15.0 0.30 1 1,4-Dichlorobenzene 1.9 ug/L 11/25/14 15:41 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 11/25/14 15:41 110-57-61001.0 1 1,1-Dichloroethane 1.3J ug/L 11/25/14 15:41 75-34-35.0 0.32 1 1,2-Dichloroethane 0.47J ug/L 11/25/14 15:41 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 11/25/14 15:41 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 9.6 ug/L 11/25/14 15:41 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 11/25/14 15:41 156-60-55.0 0.49 1 1,2-Dichloropropane 0.56J ug/L 11/25/14 15:41 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 11/25/14 15:41 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 11/25/14 15:41 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 35 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226774 Town of Kernersville Sample:3404-MW3S Lab ID:92226774002 Collected:11/20/14 12:40 Received:11/21/14 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Ethylbenzene ND ug/L 11/25/14 15:41 100-41-41.0 0.30 1 2-Hexanone ND ug/L 11/25/14 15:41 591-78-650.0 0.46 1 Iodomethane ND ug/L 11/25/14 15:41 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 11/25/14 15:41 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 11/25/14 15:41 108-10-11000.33 1 Styrene ND ug/L 11/25/14 15:41 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 11/25/14 15:41 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 11/25/14 15:41 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 11/25/14 15:41 127-18-41.0 0.46 1 Toluene ND ug/L 11/25/14 15:41 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 11/25/14 15:41 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 11/25/14 15:41 79-00-51.0 0.29 1 Trichloroethene ND ug/L 11/25/14 15:41 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 11/25/14 15:41 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 11/25/14 15:41 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 11/25/14 15:41 108-05-450.0 0.35 1 Vinyl chloride 2.1 ug/L 11/25/14 15:41 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 11/25/14 15:41 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)99 %11/25/14 15:41 460-00-470-130 1 1,2-Dichloroethane-d4 (S)106 %11/25/14 15:41 17060-07-070-130 1 Toluene-d8 (S)102 %11/25/14 15:41 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 35 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226774 Town of Kernersville Sample:3404-MW3D Lab ID:92226774003 Collected:11/20/14 13:00 Received:11/21/14 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/25/14 18:41 7440-36-011/24/14 16:206.0 3.8 1 Arsenic ND ug/L 11/25/14 18:41 7440-38-211/24/14 16:2010.0 2.5 1 Barium 39.5J ug/L 11/25/14 18:41 7440-39-311/24/14 16:201002.5 1 Beryllium ND ug/L 11/25/14 18:41 7440-41-711/24/14 16:201.0 0.50 1 Cadmium ND ug/L 11/25/14 18:41 7440-43-911/24/14 16:201.0 0.50 1 Chromium ND ug/L 11/25/14 18:41 7440-47-311/24/14 16:2010.0 2.5 1 Cobalt ND ug/L 11/25/14 18:41 7440-48-411/24/14 16:2010.0 2.5 1 Copper ND ug/L 11/25/14 18:41 7440-50-811/24/14 16:2010.0 2.5 1 Lead ND ug/L 11/25/14 18:41 7439-92-111/24/14 16:2010.0 2.5 1 Nickel ND ug/L 11/25/14 18:41 7440-02-011/24/14 16:2050.0 2.5 1 Selenium ND ug/L 11/25/14 18:41 7782-49-211/24/14 16:2010.0 5.0 1 Silver ND ug/L 11/25/14 18:41 7440-22-411/24/14 16:2010.0 2.5 1 Thallium ND ug/L 11/25/14 18:41 7440-28-011/24/14 16:205.5 5.0 1 Vanadium ND ug/L 11/25/14 18:41 7440-62-211/24/14 16:2025.0 2.5 1 Zinc ND ug/L 11/25/14 18:41 7440-66-611/24/14 16:2010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 11/25/14 16:14 67-64-110010.0 1 Acrylonitrile ND ug/L 11/25/14 16:14 107-13-12001.9 1 Benzene ND ug/L 11/25/14 16:14 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 11/25/14 16:14 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 11/25/14 16:14 75-27-41.0 0.18 1 Bromoform ND ug/L 11/25/14 16:14 75-25-23.0 0.26 1 Bromomethane ND ug/L 11/25/14 16:14 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 11/25/14 16:14 78-93-31000.96 1 Carbon disulfide ND ug/L 11/25/14 16:14 75-15-01001.2 1 Carbon tetrachloride ND ug/L 11/25/14 16:14 56-23-51.0 0.25 1 Chlorobenzene 0.36J ug/L 11/25/14 16:14 108-90-73.0 0.23 1 Chloroethane ND ug/L 11/25/14 16:14 75-00-310.0 0.54 1 Chloroform ND ug/L 11/25/14 16:14 67-66-35.0 0.14 1 Chloromethane ND ug/L 11/25/14 16:14 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 11/25/14 16:14 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 11/25/14 16:14 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 11/25/14 16:14 106-93-41.0 0.27 1 Dibromomethane ND ug/L 11/25/14 16:14 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 11/25/14 16:14 95-50-15.0 0.30 1 1,4-Dichlorobenzene 3.8 ug/L 11/25/14 16:14 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 11/25/14 16:14 110-57-61001.0 1 1,1-Dichloroethane 3.2J ug/L 11/25/14 16:14 75-34-35.0 0.32 1 1,2-Dichloroethane 0.81J ug/L 11/25/14 16:14 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 11/25/14 16:14 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 55.4 ug/L 11/25/14 16:14 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 11/25/14 16:14 156-60-55.0 0.49 1 1,2-Dichloropropane 1.2 ug/L 11/25/14 16:14 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 11/25/14 16:14 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 11/25/14 16:14 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 35 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226774 Town of Kernersville Sample:3404-MW3D Lab ID:92226774003 Collected:11/20/14 13:00 Received:11/21/14 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Ethylbenzene ND ug/L 11/25/14 16:14 100-41-41.0 0.30 1 2-Hexanone ND ug/L 11/25/14 16:14 591-78-650.0 0.46 1 Iodomethane ND ug/L 11/25/14 16:14 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 11/25/14 16:14 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 11/25/14 16:14 108-10-11000.33 1 Styrene ND ug/L 11/25/14 16:14 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 11/25/14 16:14 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 11/25/14 16:14 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 11/25/14 16:14 127-18-41.0 0.46 1 Toluene ND ug/L 11/25/14 16:14 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 11/25/14 16:14 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 11/25/14 16:14 79-00-51.0 0.29 1 Trichloroethene ND ug/L 11/25/14 16:14 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 11/25/14 16:14 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 11/25/14 16:14 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 11/25/14 16:14 108-05-450.0 0.35 1 Vinyl chloride 5.3 ug/L 11/25/14 16:14 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 11/25/14 16:14 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)97 %11/25/14 16:14 460-00-470-130 1 1,2-Dichloroethane-d4 (S)106 %11/25/14 16:14 17060-07-070-130 1 Toluene-d8 (S)103 %11/25/14 16:14 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 35 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226774 Town of Kernersville Sample:3404-MW4 Lab ID:92226774004 Collected:11/20/14 15:00 Received:11/21/14 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/25/14 18:44 7440-36-011/24/14 16:206.0 3.8 1 Arsenic ND ug/L 11/25/14 18:44 7440-38-211/24/14 16:2010.0 2.5 1 Barium 83.3J ug/L 11/25/14 18:44 7440-39-311/24/14 16:201002.5 1 Beryllium ND ug/L 11/25/14 18:44 7440-41-711/24/14 16:201.0 0.50 1 Cadmium ND ug/L 11/25/14 18:44 7440-43-911/24/14 16:201.0 0.50 1 Chromium ND ug/L 11/25/14 18:44 7440-47-311/24/14 16:2010.0 2.5 1 Cobalt ND ug/L 11/25/14 18:44 7440-48-411/24/14 16:2010.0 2.5 1 Copper ND ug/L 11/25/14 18:44 7440-50-811/24/14 16:2010.0 2.5 1 Lead ND ug/L 11/25/14 18:44 7439-92-111/24/14 16:2010.0 2.5 1 Nickel ND ug/L 11/25/14 18:44 7440-02-011/24/14 16:2050.0 2.5 1 Selenium ND ug/L 11/25/14 18:44 7782-49-211/24/14 16:2010.0 5.0 1 Silver ND ug/L 11/25/14 18:44 7440-22-411/24/14 16:2010.0 2.5 1 Thallium ND ug/L 11/25/14 18:44 7440-28-011/24/14 16:205.5 5.0 1 Vanadium ND ug/L 11/25/14 18:44 7440-62-211/24/14 16:2025.0 2.5 1 Zinc ND ug/L 11/25/14 18:44 7440-66-611/24/14 16:2010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 11/25/14 16:30 67-64-110010.0 1 Acrylonitrile ND ug/L 11/25/14 16:30 107-13-12001.9 1 Benzene 0.32J ug/L 11/25/14 16:30 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 11/25/14 16:30 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 11/25/14 16:30 75-27-41.0 0.18 1 Bromoform ND ug/L 11/25/14 16:30 75-25-23.0 0.26 1 Bromomethane ND ug/L 11/25/14 16:30 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 11/25/14 16:30 78-93-31000.96 1 Carbon disulfide ND ug/L 11/25/14 16:30 75-15-01001.2 1 Carbon tetrachloride ND ug/L 11/25/14 16:30 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 11/25/14 16:30 108-90-73.0 0.23 1 Chloroethane ND ug/L 11/25/14 16:30 75-00-310.0 0.54 1 Chloroform ND ug/L 11/25/14 16:30 67-66-35.0 0.14 1 Chloromethane ND ug/L 11/25/14 16:30 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 11/25/14 16:30 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 11/25/14 16:30 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 11/25/14 16:30 106-93-41.0 0.27 1 Dibromomethane ND ug/L 11/25/14 16:30 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 11/25/14 16:30 95-50-15.0 0.30 1 1,4-Dichlorobenzene 2.6 ug/L 11/25/14 16:30 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 11/25/14 16:30 110-57-61001.0 1 1,1-Dichloroethane 1.8J ug/L 11/25/14 16:30 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 11/25/14 16:30 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 11/25/14 16:30 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 19.3 ug/L 11/25/14 16:30 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 11/25/14 16:30 156-60-55.0 0.49 1 1,2-Dichloropropane 0.36J ug/L 11/25/14 16:30 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 11/25/14 16:30 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 11/25/14 16:30 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 35 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226774 Town of Kernersville Sample:3404-MW4 Lab ID:92226774004 Collected:11/20/14 15:00 Received:11/21/14 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Ethylbenzene ND ug/L 11/25/14 16:30 100-41-41.0 0.30 1 2-Hexanone ND ug/L 11/25/14 16:30 591-78-650.0 0.46 1 Iodomethane ND ug/L 11/25/14 16:30 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 11/25/14 16:30 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 11/25/14 16:30 108-10-11000.33 1 Styrene ND ug/L 11/25/14 16:30 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 11/25/14 16:30 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 11/25/14 16:30 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 11/25/14 16:30 127-18-41.0 0.46 1 Toluene ND ug/L 11/25/14 16:30 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 11/25/14 16:30 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 11/25/14 16:30 79-00-51.0 0.29 1 Trichloroethene ND ug/L 11/25/14 16:30 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 11/25/14 16:30 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 11/25/14 16:30 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 11/25/14 16:30 108-05-450.0 0.35 1 Vinyl chloride 16.2 ug/L 11/25/14 16:30 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 11/25/14 16:30 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)96 %11/25/14 16:30 460-00-470-130 1 1,2-Dichloroethane-d4 (S)99 %11/25/14 16:30 17060-07-070-130 1 Toluene-d8 (S)103 %11/25/14 16:30 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 35 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226774 Town of Kernersville Sample:3404-MW5 Lab ID:92226774005 Collected:11/20/14 16:10 Received:11/21/14 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/25/14 18:47 7440-36-011/24/14 16:206.0 3.8 1 Arsenic 2.7J ug/L 11/25/14 18:47 7440-38-211/24/14 16:2010.0 2.5 1 Barium 108 ug/L 11/25/14 18:47 7440-39-311/24/14 16:201002.5 1 Beryllium ND ug/L 11/25/14 18:47 7440-41-711/24/14 16:201.0 0.50 1 Cadmium ND ug/L 11/25/14 18:47 7440-43-911/24/14 16:201.0 0.50 1 Chromium ND ug/L 11/25/14 18:47 7440-47-311/24/14 16:2010.0 2.5 1 Cobalt 10.2 ug/L 11/25/14 18:47 7440-48-411/24/14 16:2010.0 2.5 1 Copper 5.3J ug/L 11/25/14 18:47 7440-50-811/24/14 16:2010.0 2.5 1 Lead 4.2J ug/L 11/25/14 18:47 7439-92-111/24/14 16:2010.0 2.5 1 Nickel ND ug/L 11/25/14 18:47 7440-02-011/24/14 16:2050.0 2.5 1 Selenium ND ug/L 11/25/14 18:47 7782-49-211/24/14 16:2010.0 5.0 1 Silver ND ug/L 11/25/14 18:47 7440-22-411/24/14 16:2010.0 2.5 1 Thallium ND ug/L 11/25/14 18:47 7440-28-011/24/14 16:205.5 5.0 1 Vanadium 9.4J ug/L 11/25/14 18:47 7440-62-211/24/14 16:2025.0 2.5 1 Zinc 55.0 ug/L 11/25/14 18:47 7440-66-611/24/14 16:2010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 11/25/14 16:47 67-64-110010.0 1 Acrylonitrile ND ug/L 11/25/14 16:47 107-13-12001.9 1 Benzene ND ug/L 11/25/14 16:47 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 11/25/14 16:47 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 11/25/14 16:47 75-27-41.0 0.18 1 Bromoform ND ug/L 11/25/14 16:47 75-25-23.0 0.26 1 Bromomethane ND ug/L 11/25/14 16:47 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 11/25/14 16:47 78-93-31000.96 1 Carbon disulfide ND ug/L 11/25/14 16:47 75-15-01001.2 1 Carbon tetrachloride ND ug/L 11/25/14 16:47 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 11/25/14 16:47 108-90-73.0 0.23 1 Chloroethane ND ug/L 11/25/14 16:47 75-00-310.0 0.54 1 Chloroform ND ug/L 11/25/14 16:47 67-66-35.0 0.14 1 Chloromethane ND ug/L 11/25/14 16:47 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 11/25/14 16:47 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 11/25/14 16:47 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 11/25/14 16:47 106-93-41.0 0.27 1 Dibromomethane ND ug/L 11/25/14 16:47 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 11/25/14 16:47 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 11/25/14 16:47 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 11/25/14 16:47 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 11/25/14 16:47 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 11/25/14 16:47 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 11/25/14 16:47 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 11/25/14 16:47 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 11/25/14 16:47 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 11/25/14 16:47 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 11/25/14 16:47 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 11/25/14 16:47 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 35 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226774 Town of Kernersville Sample:3404-MW5 Lab ID:92226774005 Collected:11/20/14 16:10 Received:11/21/14 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Ethylbenzene ND ug/L 11/25/14 16:47 100-41-41.0 0.30 1 2-Hexanone ND ug/L 11/25/14 16:47 591-78-650.0 0.46 1 Iodomethane ND ug/L 11/25/14 16:47 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 11/25/14 16:47 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 11/25/14 16:47 108-10-11000.33 1 Styrene ND ug/L 11/25/14 16:47 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 11/25/14 16:47 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 11/25/14 16:47 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 11/25/14 16:47 127-18-41.0 0.46 1 Toluene ND ug/L 11/25/14 16:47 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 11/25/14 16:47 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 11/25/14 16:47 79-00-51.0 0.29 1 Trichloroethene ND ug/L 11/25/14 16:47 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 11/25/14 16:47 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 11/25/14 16:47 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 11/25/14 16:47 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 11/25/14 16:47 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 11/25/14 16:47 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)96 %11/25/14 16:47 460-00-470-130 1 1,2-Dichloroethane-d4 (S)101 %11/25/14 16:47 17060-07-070-130 1 Toluene-d8 (S)104 %11/25/14 16:47 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 35 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226774 Town of Kernersville Sample:3404-SW1 Lab ID:92226774006 Collected:11/20/14 11:15 Received:11/21/14 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/25/14 18:50 7440-36-011/24/14 16:206.0 3.8 1 Arsenic ND ug/L 11/25/14 18:50 7440-38-211/24/14 16:2010.0 2.5 1 Barium 26.6J ug/L 11/25/14 18:50 7440-39-311/24/14 16:201002.5 1 Beryllium ND ug/L 11/25/14 18:50 7440-41-711/24/14 16:201.0 0.50 1 Cadmium ND ug/L 11/25/14 18:50 7440-43-911/24/14 16:201.0 0.50 1 Chromium ND ug/L 11/25/14 18:50 7440-47-311/24/14 16:2010.0 2.5 1 Cobalt ND ug/L 11/25/14 18:50 7440-48-411/24/14 16:2010.0 2.5 1 Copper ND ug/L 11/25/14 18:50 7440-50-811/24/14 16:2010.0 2.5 1 Lead ND ug/L 11/25/14 18:50 7439-92-111/24/14 16:2010.0 2.5 1 Nickel ND ug/L 11/25/14 18:50 7440-02-011/24/14 16:2050.0 2.5 1 Selenium ND ug/L 11/25/14 18:50 7782-49-211/24/14 16:2010.0 5.0 1 Silver ND ug/L 11/25/14 18:50 7440-22-411/24/14 16:2010.0 2.5 1 Thallium ND ug/L 11/25/14 18:50 7440-28-011/24/14 16:205.5 5.0 1 Vanadium ND ug/L 11/25/14 18:50 7440-62-211/24/14 16:2025.0 2.5 1 Zinc ND ug/L 11/25/14 18:50 7440-66-611/24/14 16:2010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 11/25/14 17:03 67-64-110010.0 1 Acrylonitrile ND ug/L 11/25/14 17:03 107-13-12001.9 1 Benzene ND ug/L 11/25/14 17:03 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 11/25/14 17:03 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 11/25/14 17:03 75-27-41.0 0.18 1 Bromoform ND ug/L 11/25/14 17:03 75-25-23.0 0.26 1 Bromomethane ND ug/L 11/25/14 17:03 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 11/25/14 17:03 78-93-31000.96 1 Carbon disulfide ND ug/L 11/25/14 17:03 75-15-01001.2 1 Carbon tetrachloride ND ug/L 11/25/14 17:03 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 11/25/14 17:03 108-90-73.0 0.23 1 Chloroethane ND ug/L 11/25/14 17:03 75-00-310.0 0.54 1 Chloroform ND ug/L 11/25/14 17:03 67-66-35.0 0.14 1 Chloromethane ND ug/L 11/25/14 17:03 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 11/25/14 17:03 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 11/25/14 17:03 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 11/25/14 17:03 106-93-41.0 0.27 1 Dibromomethane ND ug/L 11/25/14 17:03 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 11/25/14 17:03 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 11/25/14 17:03 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 11/25/14 17:03 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 11/25/14 17:03 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 11/25/14 17:03 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 11/25/14 17:03 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 11/25/14 17:03 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 11/25/14 17:03 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 11/25/14 17:03 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 11/25/14 17:03 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 11/25/14 17:03 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 35 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226774 Town of Kernersville Sample:3404-SW1 Lab ID:92226774006 Collected:11/20/14 11:15 Received:11/21/14 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Ethylbenzene ND ug/L 11/25/14 17:03 100-41-41.0 0.30 1 2-Hexanone ND ug/L 11/25/14 17:03 591-78-650.0 0.46 1 Iodomethane ND ug/L 11/25/14 17:03 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 11/25/14 17:03 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 11/25/14 17:03 108-10-11000.33 1 Styrene ND ug/L 11/25/14 17:03 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 11/25/14 17:03 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 11/25/14 17:03 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 11/25/14 17:03 127-18-41.0 0.46 1 Toluene ND ug/L 11/25/14 17:03 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 11/25/14 17:03 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 11/25/14 17:03 79-00-51.0 0.29 1 Trichloroethene ND ug/L 11/25/14 17:03 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 11/25/14 17:03 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 11/25/14 17:03 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 11/25/14 17:03 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 11/25/14 17:03 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 11/25/14 17:03 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)96 %11/25/14 17:03 460-00-470-130 1 1,2-Dichloroethane-d4 (S)101 %11/25/14 17:03 17060-07-070-130 1 Toluene-d8 (S)102 %11/25/14 17:03 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 35 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226774 Town of Kernersville Sample:3404-SW2 Lab ID:92226774007 Collected:11/20/14 14:40 Received:11/21/14 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/25/14 18:53 7440-36-011/24/14 16:206.0 3.8 1 Arsenic ND ug/L 11/25/14 18:53 7440-38-211/24/14 16:2010.0 2.5 1 Barium 31.2J ug/L 11/25/14 18:53 7440-39-311/24/14 16:201002.5 1 Beryllium ND ug/L 11/25/14 18:53 7440-41-711/24/14 16:201.0 0.50 1 Cadmium ND ug/L 11/25/14 18:53 7440-43-911/24/14 16:201.0 0.50 1 Chromium ND ug/L 11/25/14 18:53 7440-47-311/24/14 16:2010.0 2.5 1 Cobalt ND ug/L 11/25/14 18:53 7440-48-411/24/14 16:2010.0 2.5 1 Copper ND ug/L 11/25/14 18:53 7440-50-811/24/14 16:2010.0 2.5 1 Lead ND ug/L 11/25/14 18:53 7439-92-111/24/14 16:2010.0 2.5 1 Nickel ND ug/L 11/25/14 18:53 7440-02-011/24/14 16:2050.0 2.5 1 Selenium ND ug/L 11/25/14 18:53 7782-49-211/24/14 16:2010.0 5.0 1 Silver ND ug/L 11/25/14 18:53 7440-22-411/24/14 16:2010.0 2.5 1 Thallium ND ug/L 11/25/14 18:53 7440-28-011/24/14 16:205.5 5.0 1 Vanadium ND ug/L 11/25/14 18:53 7440-62-211/24/14 16:2025.0 2.5 1 Zinc ND ug/L 11/25/14 18:53 7440-66-611/24/14 16:2010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 11/25/14 17:20 67-64-110010.0 1 Acrylonitrile ND ug/L 11/25/14 17:20 107-13-12001.9 1 Benzene ND ug/L 11/25/14 17:20 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 11/25/14 17:20 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 11/25/14 17:20 75-27-41.0 0.18 1 Bromoform ND ug/L 11/25/14 17:20 75-25-23.0 0.26 1 Bromomethane ND ug/L 11/25/14 17:20 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 11/25/14 17:20 78-93-31000.96 1 Carbon disulfide ND ug/L 11/25/14 17:20 75-15-01001.2 1 Carbon tetrachloride ND ug/L 11/25/14 17:20 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 11/25/14 17:20 108-90-73.0 0.23 1 Chloroethane ND ug/L 11/25/14 17:20 75-00-310.0 0.54 1 Chloroform ND ug/L 11/25/14 17:20 67-66-35.0 0.14 1 Chloromethane ND ug/L 11/25/14 17:20 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 11/25/14 17:20 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 11/25/14 17:20 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 11/25/14 17:20 106-93-41.0 0.27 1 Dibromomethane ND ug/L 11/25/14 17:20 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 11/25/14 17:20 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 11/25/14 17:20 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 11/25/14 17:20 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 11/25/14 17:20 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 11/25/14 17:20 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 11/25/14 17:20 75-35-45.0 0.56 1 cis-1,2-Dichloroethene 0.49J ug/L 11/25/14 17:20 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 11/25/14 17:20 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 11/25/14 17:20 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 11/25/14 17:20 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 11/25/14 17:20 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 35 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226774 Town of Kernersville Sample:3404-SW2 Lab ID:92226774007 Collected:11/20/14 14:40 Received:11/21/14 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Ethylbenzene ND ug/L 11/25/14 17:20 100-41-41.0 0.30 1 2-Hexanone ND ug/L 11/25/14 17:20 591-78-650.0 0.46 1 Iodomethane ND ug/L 11/25/14 17:20 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 11/25/14 17:20 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 11/25/14 17:20 108-10-11000.33 1 Styrene ND ug/L 11/25/14 17:20 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 11/25/14 17:20 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 11/25/14 17:20 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 11/25/14 17:20 127-18-41.0 0.46 1 Toluene ND ug/L 11/25/14 17:20 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 11/25/14 17:20 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 11/25/14 17:20 79-00-51.0 0.29 1 Trichloroethene ND ug/L 11/25/14 17:20 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 11/25/14 17:20 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 11/25/14 17:20 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 11/25/14 17:20 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 11/25/14 17:20 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 11/25/14 17:20 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)96 %11/25/14 17:20 460-00-470-130 1 1,2-Dichloroethane-d4 (S)103 %11/25/14 17:20 17060-07-070-130 1 Toluene-d8 (S)101 %11/25/14 17:20 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 35 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226774 Town of Kernersville Sample:3404-SW3 Lab ID:92226774008 Collected:11/20/14 11:30 Received:11/21/14 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/25/14 18:56 7440-36-011/24/14 16:206.0 3.8 1 Arsenic ND ug/L 11/25/14 18:56 7440-38-211/24/14 16:2010.0 2.5 1 Barium 29.4J ug/L 11/25/14 18:56 7440-39-311/24/14 16:201002.5 1 Beryllium ND ug/L 11/25/14 18:56 7440-41-711/24/14 16:201.0 0.50 1 Cadmium ND ug/L 11/25/14 18:56 7440-43-911/24/14 16:201.0 0.50 1 Chromium 2.7J ug/L 11/25/14 18:56 7440-47-311/24/14 16:2010.0 2.5 1 Cobalt ND ug/L 11/25/14 18:56 7440-48-411/24/14 16:2010.0 2.5 1 Copper ND ug/L 11/25/14 18:56 7440-50-811/24/14 16:2010.0 2.5 1 Lead ND ug/L 11/25/14 18:56 7439-92-111/24/14 16:2010.0 2.5 1 Nickel ND ug/L 11/25/14 18:56 7440-02-011/24/14 16:2050.0 2.5 1 Selenium ND ug/L 11/25/14 18:56 7782-49-211/24/14 16:2010.0 5.0 1 Silver ND ug/L 11/25/14 18:56 7440-22-411/24/14 16:2010.0 2.5 1 Thallium ND ug/L 11/25/14 18:56 7440-28-011/24/14 16:205.5 5.0 1 Vanadium ND ug/L 11/25/14 18:56 7440-62-211/24/14 16:2025.0 2.5 1 Zinc ND ug/L 11/25/14 18:56 7440-66-611/24/14 16:2010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 11/25/14 17:37 67-64-110010.0 1 Acrylonitrile ND ug/L 11/25/14 17:37 107-13-12001.9 1 Benzene ND ug/L 11/25/14 17:37 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 11/25/14 17:37 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 11/25/14 17:37 75-27-41.0 0.18 1 Bromoform ND ug/L 11/25/14 17:37 75-25-23.0 0.26 1 Bromomethane ND ug/L 11/25/14 17:37 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 11/25/14 17:37 78-93-31000.96 1 Carbon disulfide ND ug/L 11/25/14 17:37 75-15-01001.2 1 Carbon tetrachloride ND ug/L 11/25/14 17:37 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 11/25/14 17:37 108-90-73.0 0.23 1 Chloroethane ND ug/L 11/25/14 17:37 75-00-310.0 0.54 1 Chloroform ND ug/L 11/25/14 17:37 67-66-35.0 0.14 1 Chloromethane ND ug/L 11/25/14 17:37 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 11/25/14 17:37 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 11/25/14 17:37 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 11/25/14 17:37 106-93-41.0 0.27 1 Dibromomethane ND ug/L 11/25/14 17:37 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 11/25/14 17:37 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 11/25/14 17:37 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 11/25/14 17:37 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 11/25/14 17:37 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 11/25/14 17:37 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 11/25/14 17:37 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 11/25/14 17:37 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 11/25/14 17:37 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 11/25/14 17:37 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 11/25/14 17:37 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 11/25/14 17:37 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 35 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226774 Town of Kernersville Sample:3404-SW3 Lab ID:92226774008 Collected:11/20/14 11:30 Received:11/21/14 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Ethylbenzene ND ug/L 11/25/14 17:37 100-41-41.0 0.30 1 2-Hexanone ND ug/L 11/25/14 17:37 591-78-650.0 0.46 1 Iodomethane ND ug/L 11/25/14 17:37 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 11/25/14 17:37 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 11/25/14 17:37 108-10-11000.33 1 Styrene ND ug/L 11/25/14 17:37 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 11/25/14 17:37 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 11/25/14 17:37 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 11/25/14 17:37 127-18-41.0 0.46 1 Toluene ND ug/L 11/25/14 17:37 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 11/25/14 17:37 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 11/25/14 17:37 79-00-51.0 0.29 1 Trichloroethene ND ug/L 11/25/14 17:37 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 11/25/14 17:37 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 11/25/14 17:37 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 11/25/14 17:37 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 11/25/14 17:37 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 11/25/14 17:37 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)97 %11/25/14 17:37 460-00-470-130 1 1,2-Dichloroethane-d4 (S)106 %11/25/14 17:37 17060-07-070-130 1 Toluene-d8 (S)102 %11/25/14 17:37 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 35 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226774 Town of Kernersville Sample:3404-Field Blank Lab ID:92226774009 Collected:11/20/14 16:20 Received:11/21/14 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 11/25/14 18:59 7440-36-011/24/14 16:206.0 3.8 1 Arsenic ND ug/L 11/25/14 18:59 7440-38-211/24/14 16:2010.0 2.5 1 Barium ND ug/L 11/25/14 18:59 7440-39-311/24/14 16:201002.5 1 Beryllium ND ug/L 11/25/14 18:59 7440-41-711/24/14 16:201.0 0.50 1 Cadmium ND ug/L 11/25/14 18:59 7440-43-911/24/14 16:201.0 0.50 1 Chromium ND ug/L 11/25/14 18:59 7440-47-311/24/14 16:2010.0 2.5 1 Cobalt ND ug/L 11/25/14 18:59 7440-48-411/24/14 16:2010.0 2.5 1 Copper ND ug/L 11/25/14 18:59 7440-50-811/24/14 16:2010.0 2.5 1 Lead ND ug/L 11/25/14 18:59 7439-92-111/24/14 16:2010.0 2.5 1 Nickel ND ug/L 11/25/14 18:59 7440-02-011/24/14 16:2050.0 2.5 1 Selenium ND ug/L 11/25/14 18:59 7782-49-211/24/14 16:2010.0 5.0 1 Silver ND ug/L 11/25/14 18:59 7440-22-411/24/14 16:2010.0 2.5 1 Thallium ND ug/L 11/25/14 18:59 7440-28-011/24/14 16:205.5 5.0 1 Vanadium ND ug/L 11/25/14 18:59 7440-62-211/24/14 16:2025.0 2.5 1 Zinc ND ug/L 11/25/14 18:59 7440-66-611/24/14 16:2010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 11/25/14 19:31 67-64-110010.0 1 Acrylonitrile ND ug/L 11/25/14 19:31 107-13-12001.9 1 Benzene ND ug/L 11/25/14 19:31 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 11/25/14 19:31 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 11/25/14 19:31 75-27-41.0 0.18 1 Bromoform ND ug/L 11/25/14 19:31 75-25-23.0 0.26 1 Bromomethane ND ug/L 11/25/14 19:31 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 11/25/14 19:31 78-93-31000.96 1 Carbon disulfide ND ug/L 11/25/14 19:31 75-15-01001.2 1 Carbon tetrachloride ND ug/L 11/25/14 19:31 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 11/25/14 19:31 108-90-73.0 0.23 1 Chloroethane ND ug/L 11/25/14 19:31 75-00-310.0 0.54 1 Chloroform ND ug/L 11/25/14 19:31 67-66-35.0 0.14 1 Chloromethane ND ug/L 11/25/14 19:31 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 11/25/14 19:31 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 11/25/14 19:31 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 11/25/14 19:31 106-93-41.0 0.27 1 Dibromomethane ND ug/L 11/25/14 19:31 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 11/25/14 19:31 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 11/25/14 19:31 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 11/25/14 19:31 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 11/25/14 19:31 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 11/25/14 19:31 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 11/25/14 19:31 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 11/25/14 19:31 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 11/25/14 19:31 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 11/25/14 19:31 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 11/25/14 19:31 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 11/25/14 19:31 10061-02-61.0 0.26 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 35 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226774 Town of Kernersville Sample:3404-Field Blank Lab ID:92226774009 Collected:11/20/14 16:20 Received:11/21/14 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Ethylbenzene ND ug/L 11/25/14 19:31 100-41-41.0 0.30 1 2-Hexanone ND ug/L 11/25/14 19:31 591-78-650.0 0.46 1 Iodomethane ND ug/L 11/25/14 19:31 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 11/25/14 19:31 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 11/25/14 19:31 108-10-11000.33 1 Styrene ND ug/L 11/25/14 19:31 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 11/25/14 19:31 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 11/25/14 19:31 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 11/25/14 19:31 127-18-41.0 0.46 1 Toluene ND ug/L 11/25/14 19:31 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 11/25/14 19:31 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 11/25/14 19:31 79-00-51.0 0.29 1 Trichloroethene ND ug/L 11/25/14 19:31 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 11/25/14 19:31 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 11/25/14 19:31 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 11/25/14 19:31 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 11/25/14 19:31 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 11/25/14 19:31 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)97 %11/25/14 19:31 460-00-470-130 1 1,2-Dichloroethane-d4 (S)100 %11/25/14 19:31 17060-07-070-130 1 Toluene-d8 (S)103 %11/25/14 19:31 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 35 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226774 Town of Kernersville Sample:3404-Trip Blank Lab ID:92226774010 Collected:11/20/14 08:45 Received:11/21/14 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 11/25/14 19:47 67-64-110010.0 1 Acrylonitrile ND ug/L 11/25/14 19:47 107-13-12001.9 1 Benzene ND ug/L 11/25/14 19:47 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 11/25/14 19:47 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 11/25/14 19:47 75-27-41.0 0.18 1 Bromoform ND ug/L 11/25/14 19:47 75-25-23.0 0.26 1 Bromomethane ND ug/L 11/25/14 19:47 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 11/25/14 19:47 78-93-31000.96 1 Carbon disulfide ND ug/L 11/25/14 19:47 75-15-01001.2 1 Carbon tetrachloride ND ug/L 11/25/14 19:47 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 11/25/14 19:47 108-90-73.0 0.23 1 Chloroethane ND ug/L 11/25/14 19:47 75-00-310.0 0.54 1 Chloroform ND ug/L 11/25/14 19:47 67-66-35.0 0.14 1 Chloromethane ND ug/L 11/25/14 19:47 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 11/25/14 19:47 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 11/25/14 19:47 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 11/25/14 19:47 106-93-41.0 0.27 1 Dibromomethane ND ug/L 11/25/14 19:47 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 11/25/14 19:47 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 11/25/14 19:47 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 11/25/14 19:47 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 11/25/14 19:47 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 11/25/14 19:47 107-06-21.0 0.12 1 1,1-Dichloroethene ND ug/L 11/25/14 19:47 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 11/25/14 19:47 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 11/25/14 19:47 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 11/25/14 19:47 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 11/25/14 19:47 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 11/25/14 19:47 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 11/25/14 19:47 100-41-41.0 0.30 1 2-Hexanone ND ug/L 11/25/14 19:47 591-78-650.0 0.46 1 Iodomethane ND ug/L 11/25/14 19:47 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 11/25/14 19:47 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 11/25/14 19:47 108-10-11000.33 1 Styrene ND ug/L 11/25/14 19:47 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 11/25/14 19:47 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 11/25/14 19:47 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 11/25/14 19:47 127-18-41.0 0.46 1 Toluene ND ug/L 11/25/14 19:47 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 11/25/14 19:47 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 11/25/14 19:47 79-00-51.0 0.29 1 Trichloroethene ND ug/L 11/25/14 19:47 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 11/25/14 19:47 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 11/25/14 19:47 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 11/25/14 19:47 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 11/25/14 19:47 75-01-41.0 0.62 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 35 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226774 Town of Kernersville Sample:3404-Trip Blank Lab ID:92226774010 Collected:11/20/14 08:45 Received:11/21/14 14:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Xylene (Total)ND ug/L 11/25/14 19:47 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)95 %11/25/14 19:47 460-00-470-130 1 1,2-Dichloroethane-d4 (S)103 %11/25/14 19:47 17060-07-070-130 1 Toluene-d8 (S)103 %11/25/14 19:47 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 35 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92226774 Town of Kernersville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/17416 EPA 3010 EPA 6010 6010 MET NC Groundwater Associated Lab Samples:92226774001, 92226774002, 92226774003, 92226774004, 92226774005, 92226774006, 92226774007, 92226774008, 92226774009 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1337205 Associated Lab Samples:92226774001, 92226774002, 92226774003, 92226774004, 92226774005, 92226774006, 92226774007, 92226774008, 92226774009 Matrix:Water Analyzed Antimony ug/L ND 6.0 11/25/14 17:35 Arsenic ug/L ND 10.0 11/25/14 17:35 Barium ug/L ND 100 11/25/14 17:35 Beryllium ug/L ND 1.0 11/25/14 17:35 Cadmium ug/L ND 1.0 11/25/14 17:35 Chromium ug/L ND 10.0 11/25/14 17:35 Cobalt ug/L ND 10.0 11/25/14 17:35 Copper ug/L ND 10.0 11/25/14 17:35 Lead ug/L ND 10.0 11/25/14 17:35 Nickel ug/L ND 50.0 11/25/14 17:35 Selenium ug/L ND 10.0 11/25/14 17:35 Silver ug/L ND 10.0 11/25/14 17:35 Thallium ug/L ND 5.5 11/25/14 17:35 Vanadium ug/L ND 25.0 11/25/14 17:35 Zinc ug/L ND 10.0 11/25/14 17:35 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1337206LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 490500 98 80-120 Arsenic ug/L 483500 97 80-120 Barium ug/L 484500 97 80-120 Beryllium ug/L 486500 97 80-120 Cadmium ug/L 489500 98 80-120 Chromium ug/L 481500 96 80-120 Cobalt ug/L 484500 97 80-120 Copper ug/L 492500 98 80-120 Lead ug/L 490500 98 80-120 Nickel ug/L 489500 98 80-120 Selenium ug/L 497500 99 80-120 Silver ug/L 238250 95 80-120 Thallium ug/L 479500 96 80-120 Vanadium ug/L 481500 96 80-120 Zinc ug/L 474500 95 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 35 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92226774 Town of Kernersville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1337207MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92226660007 1337208 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony ug/L 500 94 75-12595 1 25500ND472474 Arsenic ug/L 500 94 75-12594 0 25500ND470471 Barium ug/L 500 94 75-12596 2 25500116586597 Beryllium ug/L 500 96 75-12597 1 25500ND481485 Cadmium ug/L 500 95 75-12595 0 25500ND475477 Chromium ug/L 500 94 75-12595 1 25500ND472476 Cobalt ug/L 500 93 75-12593 0 2550013.5 479 480 Copper ug/L 500 95 75-12596 1 25500ND475480 Lead ug/L 500 93 75-12594 0 25500ND468469 Nickel ug/L 500 94 75-12594 1 255009.0 478 480 Selenium ug/L 500 96 75-12596 1 25500ND479481 Silver ug/L 250 92 75-12593 0 25250ND232232 Thallium ug/L 500 91 75-12592 0 25500ND458460 Vanadium ug/L 500 96 75-12596 0 25500ND480482 Zinc ug/L 500 93 75-12593 0 25500ND466468 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 35 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92226774 Town of Kernersville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MSV/29383 EPA 8260 EPA 8260 8260 MSV Low Level Landfill Associated Lab Samples:92226774001, 92226774002, 92226774003, 92226774004, 92226774005, 92226774006, 92226774007, 92226774008, 92226774009, 92226774010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1337960 Associated Lab Samples:92226774001, 92226774002, 92226774003, 92226774004, 92226774005, 92226774006, 92226774007, 92226774008, 92226774009, 92226774010 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 11/25/14 12:10 1,1,1-Trichloroethane ug/L ND 1.0 11/25/14 12:10 1,1,2,2-Tetrachloroethane ug/L ND 3.0 11/25/14 12:10 1,1,2-Trichloroethane ug/L ND 1.0 11/25/14 12:10 1,1-Dichloroethane ug/L ND 5.0 11/25/14 12:10 1,1-Dichloroethene ug/L ND 5.0 11/25/14 12:10 1,2,3-Trichloropropane ug/L ND 1.0 11/25/14 12:10 1,2-Dibromo-3-chloropropane ug/L ND 13.0 11/25/14 12:10 1,2-Dibromoethane (EDB)ug/L ND 1.0 11/25/14 12:10 1,2-Dichlorobenzene ug/L ND 5.0 11/25/14 12:10 1,2-Dichloroethane ug/L ND 1.0 11/25/14 12:10 1,2-Dichloropropane ug/L ND 1.0 11/25/14 12:10 1,4-Dichlorobenzene ug/L ND 1.0 11/25/14 12:10 2-Butanone (MEK)ug/L ND 100 11/25/14 12:10 2-Hexanone ug/L ND 50.0 11/25/14 12:10 4-Methyl-2-pentanone (MIBK)ug/L ND 100 11/25/14 12:10 Acetone ug/L ND 100 11/25/14 12:10 Acrylonitrile ug/L ND 200 11/25/14 12:10 Benzene ug/L ND 1.0 11/25/14 12:10 Bromochloromethane ug/L ND 3.0 11/25/14 12:10 Bromodichloromethane ug/L ND 1.0 11/25/14 12:10 Bromoform ug/L ND 3.0 11/25/14 12:10 Bromomethane ug/L ND 10.0 11/25/14 12:10 Carbon disulfide ug/L ND 100 11/25/14 12:10 Carbon tetrachloride ug/L ND 1.0 11/25/14 12:10 Chlorobenzene ug/L ND 3.0 11/25/14 12:10 Chloroethane ug/L ND 10.0 11/25/14 12:10 Chloroform ug/L ND 5.0 11/25/14 12:10 Chloromethane ug/L ND 1.0 11/25/14 12:10 cis-1,2-Dichloroethene ug/L ND 5.0 11/25/14 12:10 cis-1,3-Dichloropropene ug/L ND 1.0 11/25/14 12:10 Dibromochloromethane ug/L ND 3.0 11/25/14 12:10 Dibromomethane ug/L ND 10.0 11/25/14 12:10 Ethylbenzene ug/L ND 1.0 11/25/14 12:10 Iodomethane ug/L ND 10.0 11/25/14 12:10 Methylene Chloride ug/L ND 1.0 11/25/14 12:10 Styrene ug/L ND 1.0 11/25/14 12:10 Tetrachloroethene ug/L ND 1.0 11/25/14 12:10 Toluene ug/L ND 1.0 11/25/14 12:10 trans-1,2-Dichloroethene ug/L ND 5.0 11/25/14 12:10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 35 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92226774 Town of Kernersville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1337960 Associated Lab Samples:92226774001, 92226774002, 92226774003, 92226774004, 92226774005, 92226774006, 92226774007, 92226774008, 92226774009, 92226774010 Matrix:Water Analyzed trans-1,3-Dichloropropene ug/L ND 1.0 11/25/14 12:10 trans-1,4-Dichloro-2-butene ug/L ND 100 11/25/14 12:10 Trichloroethene ug/L ND 1.0 11/25/14 12:10 Trichlorofluoromethane ug/L ND 1.0 11/25/14 12:10 Vinyl acetate ug/L ND 50.0 11/25/14 12:10 Vinyl chloride ug/L ND 1.0 11/25/14 12:10 Xylene (Total)ug/L ND 5.0 11/25/14 12:10 1,2-Dichloroethane-d4 (S)%102 70-130 11/25/14 12:10 4-Bromofluorobenzene (S)%97 70-130 11/25/14 12:10 Toluene-d8 (S)%103 70-130 11/25/14 12:10 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1337961LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 51.550 103 80-125 1,1,1-Trichloroethane ug/L 51.250 102 71-129 1,1,2,2-Tetrachloroethane ug/L 50.250 100 79-124 1,1,2-Trichloroethane ug/L 50.450 101 85-125 1,1-Dichloroethane ug/L 54.450 109 73-126 1,1-Dichloroethene ug/L 53.550 107 66-135 1,2,3-Trichloropropane ug/L 48.950 98 75-130 1,2-Dibromo-3-chloropropane ug/L 52.550 105 71-133 1,2-Dibromoethane (EDB)ug/L 54.850 110 83-124 1,2-Dichlorobenzene ug/L 49.050 98 80-133 1,2-Dichloroethane ug/L 46.950 94 67-128 1,2-Dichloropropane ug/L 55.050 110 75-132 1,4-Dichlorobenzene ug/L 49.750 99 78-130 2-Butanone (MEK)ug/L 109100 109 61-144 2-Hexanone ug/L 106100 106 68-143 4-Methyl-2-pentanone (MIBK)ug/L 106100 106 72-135 Acetone ug/L 97.4J100 97 48-146 Acrylonitrile ug/L 276250 111 40-160 Benzene ug/L 52.450 105 80-125 Bromochloromethane ug/L 63.4 L05012771-125 Bromodichloromethane ug/L 48.050 96 78-124 Bromoform ug/L 42.950 86 71-128 Bromomethane ug/L 46.750 93 40-160 Carbon disulfide ug/L 58.5J50 117 50-160 Carbon tetrachloride ug/L 52.350 105 69-131 Chlorobenzene ug/L 50.750 101 81-122 Chloroethane ug/L 40.150 80 39-148 Chloroform ug/L 48.050 96 73-127 Chloromethane ug/L 51.650 103 44-146 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 35 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92226774 Town of Kernersville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1337961LABORATORY CONTROL SAMPLE: LCSSpike cis-1,2-Dichloroethene ug/L 55.150 110 74-124 cis-1,3-Dichloropropene ug/L 54.250 108 72-132 Dibromochloromethane ug/L 45.850 92 78-125 Dibromomethane ug/L 51.350 103 82-120 Ethylbenzene ug/L 50.550 101 79-121 Iodomethane ug/L 118100 118 39-154 Methylene Chloride ug/L 60.350 121 64-133 Styrene ug/L 52.350 105 84-126 Tetrachloroethene ug/L 47.750 95 78-122 Toluene ug/L 49.850 100 80-121 trans-1,2-Dichloroethene ug/L 53.450 107 71-127 trans-1,3-Dichloropropene ug/L 53.550 107 69-141 trans-1,4-Dichloro-2-butene ug/L 48.0J50 96 40-160 Trichloroethene ug/L 45.550 91 78-122 Trichlorofluoromethane ug/L 43.750 87 53-137 Vinyl acetate ug/L 108100 108 40-160 Vinyl chloride ug/L 50.850 102 58-137 Xylene (Total)ug/L 148150 99 81-126 1,2-Dichloroethane-d4 (S)%103 70-130 4-Bromofluorobenzene (S)%96 70-130 Toluene-d8 (S)%102 70-130 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1337962MATRIX SPIKE SAMPLE: MSSpike Result 92226774001 1,1,1,2-Tetrachloroethane ug/L 20.220 101 70-130ND 1,1,1-Trichloroethane ug/L 23.220 116 70-130ND 1,1,2,2-Tetrachloroethane ug/L 18.520 92 70-130ND 1,1,2-Trichloroethane ug/L 20.320 102 70-130ND 1,1-Dichloroethane ug/L 44.820 116 70-13021.5 1,1-Dichloroethene ug/L 23.320 115 70-166ND 1,2,3-Trichloropropane ug/L 19.420 97 70-130ND 1,2-Dibromo-3-chloropropane ug/L 17.820 89 70-130ND 1,2-Dibromoethane (EDB)ug/L 20.720 103 70-130ND 1,2-Dichlorobenzene ug/L 19.320 96 70-130ND 1,2-Dichloroethane ug/L 20.320 98 70-1300.68J 1,2-Dichloropropane ug/L 27.320 116 70-1304.1 1,4-Dichlorobenzene ug/L 24.720 100 70-1304.7 2-Butanone (MEK)ug/L 38.8J40 97 70-130ND 2-Hexanone ug/L 40.1J40 100 70-130ND 4-Methyl-2-pentanone (MIBK)ug/L 39.4J40 99 70-130ND Acetone ug/L 39.0J40 92 70-130ND Acrylonitrile ug/L 104J100 104 70-130ND Benzene ug/L 29.220 115 70-1486.2 Bromochloromethane ug/L 23.220 116 70-130ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 35 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92226774 Town of Kernersville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1337962MATRIX SPIKE SAMPLE: MSSpike Result 92226774001 Bromodichloromethane ug/L 19.220 96 70-130ND Bromoform ug/L 17.120 86 70-130ND Bromomethane ug/L 11.8 M0205970-130ND Carbon disulfide ug/L 21.9J20 110 70-130ND Carbon tetrachloride ug/L 24.620 123 70-130ND Chlorobenzene ug/L 21.620 106 70-1460.37J Chloroethane ug/L 15.220 75 70-130ND Chloroform ug/L 20.720 104 70-130ND Chloromethane ug/L 19.620 98 70-130ND cis-1,2-Dichloroethene ug/L 69.420 122 70-13044.9 cis-1,3-Dichloropropene ug/L 20.320 102 70-130ND Dibromochloromethane ug/L 16.420 82 70-130ND Dibromomethane ug/L 20.720 104 70-130ND Ethylbenzene ug/L 21.420 107 70-130ND Iodomethane ug/L 41.040 103 70-130ND Methylene Chloride ug/L 25.020 125 70-130ND Styrene ug/L 20.920 105 70-130ND Tetrachloroethene ug/L 21.620 102 70-1301.1 Toluene ug/L 21.920 110 70-155ND trans-1,2-Dichloroethene ug/L 24.520 116 70-1301.4J trans-1,3-Dichloropropene ug/L 18.420 92 70-130ND trans-1,4-Dichloro-2-butene ug/L 16.6J20 83 70-130ND Trichloroethene ug/L 25.620 103 69-1515.1 Trichlorofluoromethane ug/L 23.020 115 70-130ND Vinyl acetate ug/L 35.0J40 87 70-130ND Vinyl chloride ug/L 24.920 99 70-1305.2 1,2-Dichloroethane-d4 (S)%100 70-130 4-Bromofluorobenzene (S)%98 70-130 Toluene-d8 (S)%105 70-130 Parameter Units Dup Result Max RPD QualifiersRPDResult 92226774002 1337963SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/L NDND 1,1,1-Trichloroethane ug/L NDND 1,1,2,2-Tetrachloroethane ug/L NDND 1,1,2-Trichloroethane ug/L NDND 1,1-Dichloroethane ug/L 1.3J 11.3J 1,1-Dichloroethene ug/L NDND 1,2,3-Trichloropropane ug/L NDND 1,2-Dibromo-3-chloropropane ug/L NDND 1,2-Dibromoethane (EDB)ug/L NDND 1,2-Dichlorobenzene ug/L NDND 1,2-Dichloroethane ug/L 0.45J0.47J 1,2-Dichloropropane ug/L ND0.56J REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 35 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92226774 Town of Kernersville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 92226774002 1337963SAMPLE DUPLICATE: 1,4-Dichlorobenzene ug/L 1.8 61.9 2-Butanone (MEK)ug/L NDND 2-Hexanone ug/L NDND 4-Methyl-2-pentanone (MIBK)ug/L NDND Acetone ug/L NDND Acrylonitrile ug/L NDND Benzene ug/L 0.33J0.30J Bromochloromethane ug/L NDND Bromodichloromethane ug/L NDND Bromoform ug/L NDND Bromomethane ug/L NDND Carbon disulfide ug/L NDND Carbon tetrachloride ug/L NDND Chlorobenzene ug/L 0.93J0.95J Chloroethane ug/L NDND Chloroform ug/L NDND Chloromethane ug/L NDND cis-1,2-Dichloroethene ug/L 9.4 29.6 cis-1,3-Dichloropropene ug/L NDND Dibromochloromethane ug/L NDND Dibromomethane ug/L NDND Ethylbenzene ug/L NDND Iodomethane ug/L NDND Methylene Chloride ug/L NDND Styrene ug/L NDND Tetrachloroethene ug/L NDND Toluene ug/L NDND trans-1,2-Dichloroethene ug/L NDND trans-1,3-Dichloropropene ug/L NDND trans-1,4-Dichloro-2-butene ug/L NDND Trichloroethene ug/L NDND Trichlorofluoromethane ug/L NDND Vinyl acetate ug/L NDND Vinyl chloride ug/L 2.1 12.1 Xylene (Total)ug/L NDND 1,2-Dichloroethane-d4 (S)%102 4106 4-Bromofluorobenzene (S)%99 099 Toluene-d8 (S)%103 1102 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 35 #=QL# QUALIFIERS Pace Project No.: Project: 92226774 Town of Kernersville DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C ANALYTE QUALIFIERS Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0 Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 35 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92226774 Town of Kernersville Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92226774001 MPRP/17416 ICP/156963404-MW2 EPA 3010 EPA 6010 92226774002 MPRP/17416 ICP/156963404-MW3S EPA 3010 EPA 6010 92226774003 MPRP/17416 ICP/156963404-MW3D EPA 3010 EPA 6010 92226774004 MPRP/17416 ICP/156963404-MW4 EPA 3010 EPA 6010 92226774005 MPRP/17416 ICP/156963404-MW5 EPA 3010 EPA 6010 92226774006 MPRP/17416 ICP/156963404-SW1 EPA 3010 EPA 6010 92226774007 MPRP/17416 ICP/156963404-SW2 EPA 3010 EPA 6010 92226774008 MPRP/17416 ICP/156963404-SW3 EPA 3010 EPA 6010 92226774009 MPRP/17416 ICP/156963404-Field Blank EPA 3010 EPA 6010 92226774001 MSV/293833404-MW2 EPA 8260 92226774002 MSV/293833404-MW3S EPA 8260 92226774003 MSV/293833404-MW3D EPA 8260 92226774004 MSV/293833404-MW4 EPA 8260 92226774005 MSV/293833404-MW5 EPA 8260 92226774006 MSV/293833404-SW1 EPA 8260 92226774007 MSV/293833404-SW2 EPA 8260 92226774008 MSV/293833404-SW3 EPA 8260 92226774009 MSV/293833404-Field Blank EPA 8260 92226774010 MSV/293833404-Trip Blank EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/03/2014 06:18 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 35 Page 34 of 35 Page 35 of 35 #=CL# December 12, 2014 LIMS USE: FR - ALEX EVERHART LIMS OBJECT ID: 92226725 92226725 Project: Pace Project No.: RE: Mr. Alex Everhart Joyce Engineering-NC 2211 W. Meadowview Road Suite 101 Greensboro, NC 27407 Town of Kernersville MNA Dear Mr. Everhart: Enclosed are the analytical results for sample(s) received by the laboratory on November 21, 2014. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. This report was revised to include ethane and ethene, which were not included on the original report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Godwin kevin.godwin@pacelabs.com Project Manager REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 42 #=CL# December 12, 2014 Page 2 LIMS USE: FR - ALEX EVERHART LIMS OBJECT ID: 92226725 Enclosures cc:Mr. Van Burbach, Joyce Engineering-NC Alex Everhart, Joyce Engineering-NC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 42 #=CP# CERTIFICATIONS Pace Project No.: Project: 92226725 Town of Kernersville MNA Minnesota Certification IDs1700 Elm Street SE Suite 200, Minneapolis, MN 55414A2LA Certification #: 2926.01 Alaska Certification #: UST-078Alaska Certification #MN00064Alabama Certification #40770Arizona Certification #: AZ-0014Arkansas Certification #: 88-0680 California Certification #: 01155CAColorado Certification #PaceConnecticut Certification #: PH-0256EPA Region 8 Certification #: 8TMS-LFlorida/NELAP Certification #: E87605 Guam Certification #:14-008rGeorgia Certification #: 959Georgia EPD #: PaceIdaho Certification #: MN00064Hawaii Certification #MN00064 Illinois Certification #: 200011Indiana Certification#C-MN-01Iowa Certification #: 368Kansas Certification #: E-10167Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062Louisiana DEQ Certification #: 3086Louisiana DHH #: LA140001Maine Certification #: 2013011Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Minnesota Certification #: 027-053-137Mississippi Certification #: Pace Montana Certification #: MT0092Nevada Certification #: MN_00064Nebraska Certification #: PaceNew Jersey Certification #: MN-002New York Certification #: 11647 North Carolina Certification #: 530North Carolina State Public Health #: 27700North Dakota Certification #: R-036Ohio EPA #: 4150Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507Oregon Certification #: MN200001Oregon Certification #: MN300001Pennsylvania Certification #: 68-00563Puerto Rico Certification Saipan (CNMI) #:MP0003South Carolina #:74003001Texas Certification #: T104704192Tennessee Certification #: 02818Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251Virginia/VELAP Certification #: PaceWashington Certification #: C486West Virginia Certification #: 382West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 42 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92226725 Town of Kernersville MNA Lab ID Sample ID Matrix Date Collected Date Received 92226725001 3404-MW2 Water 11/20/14 10:45 11/21/14 11:25 92226725002 3404-MW3S Water 11/20/14 12:40 11/21/14 11:25 92226725003 3404-MW3D Water 11/20/14 13:00 11/21/14 11:25 92226725004 3404-MW4 Water 11/20/14 15:00 11/21/14 11:25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 42 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92226725 Town of Kernersville MNA Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92226725001 3404-MW2 RSK 175 3 PASI-MJRB SM 2320B 1 PASI-AMAB SM 4500-S2D 1 PASI-AJTJ SM 5210B 1 PASI-AAC1 EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER SM 5220D 1 PASI-AJTJ SM 5310B 1 PASI-AAES2 92226725002 3404-MW3S RSK 175 3 PASI-MJRB SM 2320B 1 PASI-AMAB SM 4500-S2D 1 PASI-AJTJ SM 5210B 1 PASI-AAC1 EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER SM 5220D 1 PASI-AJTJ SM 5310B 1 PASI-AAES2 92226725003 3404-MW3D RSK 175 3 PASI-MJRB SM 2320B 1 PASI-AMAB SM 4500-S2D 1 PASI-AJTJ SM 5210B 1 PASI-AAC1 EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER SM 5220D 1 PASI-AJTJ SM 5310B 1 PASI-AAES2 92226725004 3404-MW4 RSK 175 3 PASI-MJRB SM 2320B 1 PASI-AMAB SM 4500-S2D 1 PASI-AJTJ SM 5210B 1 PASI-AAC1 EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER SM 5220D 1 PASI-AJTJ SM 5310B 1 PASI-AAES2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 42 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92226725 Town of Kernersville MNA Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92226725001 3404-MW2 Methane 4980 ug/L 11/25/14 22:016.6RSK 175 Alkalinity, Total as CaCO3 159000 ug/L 12/03/14 12:375000SM 2320B BOD, 5 day 4900 ug/L 11/26/14 12:03 D62000SM 5210B Sulfate 1760J ug/L 12/05/14 11:05250000EPA 300.0 Nitrogen, Nitrate 0.045J mg/L 11/21/14 21:1610.0EPA 353.2 Chloride 17100 ug/L 12/03/14 03:491000SM 4500-Cl-E Total Organic Carbon 2150 ug/L 12/04/14 01:041000SM 5310B 92226725002 3404-MW3S Methane 159 ug/L 11/25/14 22:106.6RSK 175 Alkalinity, Total as CaCO3 151000 ug/L 12/03/14 12:50 M15000SM 2320B Sulfate 1730J ug/L 12/05/14 11:18250000EPA 300.0 Chloride 27900 ug/L 12/03/14 03:541000SM 4500-Cl-E Total Organic Carbon 1750 ug/L 12/04/14 01:151000SM 5310B 92226725003 3404-MW3D Methane 182 ug/L 11/25/14 22:186.6RSK 175 Alkalinity, Total as CaCO3 159000 ug/L 12/03/14 13:305000SM 2320B Sulfate 1870J ug/L 12/05/14 11:32250000EPA 300.0 Chloride 17300 ug/L 12/03/14 03:551000SM 4500-Cl-E Chemical Oxygen Demand 431000 ug/L 11/25/14 16:0025000SM 5220D Total Organic Carbon 1370 ug/L 12/04/14 01:251000SM 5310B 92226725004 3404-MW4 Methane 186 ug/L 11/25/14 22:266.6RSK 175 Alkalinity, Total as CaCO3 181000 ug/L 12/03/14 18:015000SM 2320B Sulfate 1560J ug/L 12/05/14 12:13250000EPA 300.0 Chloride 17100 ug/L 12/03/14 03:551000SM 4500-Cl-E Total Organic Carbon 1100 ug/L 12/04/14 01:361000SM 5310B REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226725 Town of Kernersville MNA Sample:3404-MW2 Lab ID:92226725001 Collected:11/20/14 10:45 Received:11/21/14 11:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: RSK 175RSK 175 AIR Headspace Ethane ND ug/L 11/25/14 22:01 74-84-06.2 3.1 1 Ethene ND ug/L 11/25/14 22:01 74-85-16.2 3.1 1 Methane 4980 ug/L 11/25/14 22:01 74-82-86.6 3.3 1 Analytical Method: SM 2320B2320B Alkalinity Alkalinity, Total as CaCO3 159000 ug/L 12/03/14 12:37500010001 Analytical Method: SM 4500-S2D4500S2D Sulfide Water Sulfide ND ug/L 11/24/14 14:00 18496-25-810001001 Analytical Method: SM 5210B5210B BOD, 5 day BOD, 5 day 4900 ug/L 11/26/14 12:03 D611/21/14 15:06200020001 Analytical Method: EPA 300.0300.0 IC Anions 28 Days Sulfate 1760J ug/L 12/05/14 11:05 14808-79-825000010001 Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate 0.045J mg/L 11/21/14 21:1610.0 0.010 1 Analytical Method: SM 4500-Cl-E4500 Chloride Chloride 17100 ug/L 12/03/14 03:49 16887-00-610005001 Analytical Method: SM 5220D5220D COD Chemical Oxygen Demand ND ug/L 11/25/14 16:0025000125001 Analytical Method: SM 5310B5310B TOC Total Organic Carbon 2150 ug/L 12/04/14 01:04 7440-44-010005001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/12/2014 05:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226725 Town of Kernersville MNA Sample:3404-MW3S Lab ID:92226725002 Collected:11/20/14 12:40 Received:11/21/14 11:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: RSK 175RSK 175 AIR Headspace Ethane ND ug/L 11/25/14 22:10 74-84-06.2 3.1 1 Ethene ND ug/L 11/25/14 22:10 74-85-16.2 3.1 1 Methane 159 ug/L 11/25/14 22:10 74-82-86.6 3.3 1 Analytical Method: SM 2320B2320B Alkalinity Alkalinity, Total as CaCO3 151000 ug/L 12/03/14 12:50 M1500010001 Analytical Method: SM 4500-S2D4500S2D Sulfide Water Sulfide ND ug/L 11/24/14 14:00 18496-25-810001001 Analytical Method: SM 5210B5210B BOD, 5 day BOD, 5 day ND ug/L 11/26/14 12:0311/21/14 15:06200020001 Analytical Method: EPA 300.0300.0 IC Anions 28 Days Sulfate 1730J ug/L 12/05/14 11:18 14808-79-825000010001 Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate ND mg/L 11/21/14 21:2410.0 0.010 1 Analytical Method: SM 4500-Cl-E4500 Chloride Chloride 27900 ug/L 12/03/14 03:54 16887-00-610005001 Analytical Method: SM 5220D5220D COD Chemical Oxygen Demand ND ug/L 11/25/14 16:0025000125001 Analytical Method: SM 5310B5310B TOC Total Organic Carbon 1750 ug/L 12/04/14 01:15 7440-44-010005001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/12/2014 05:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226725 Town of Kernersville MNA Sample:3404-MW3D Lab ID:92226725003 Collected:11/20/14 13:00 Received:11/21/14 11:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: RSK 175RSK 175 AIR Headspace Ethane ND ug/L 11/25/14 22:18 74-84-06.2 3.1 1 Ethene ND ug/L 11/25/14 22:18 74-85-16.2 3.1 1 Methane 182 ug/L 11/25/14 22:18 74-82-86.6 3.3 1 Analytical Method: SM 2320B2320B Alkalinity Alkalinity, Total as CaCO3 159000 ug/L 12/03/14 13:30500010001 Analytical Method: SM 4500-S2D4500S2D Sulfide Water Sulfide ND ug/L 11/24/14 14:00 18496-25-810001001 Analytical Method: SM 5210B5210B BOD, 5 day BOD, 5 day ND ug/L 11/26/14 12:0311/21/14 15:06200020001 Analytical Method: EPA 300.0300.0 IC Anions 28 Days Sulfate 1870J ug/L 12/05/14 11:32 14808-79-825000010001 Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate ND mg/L 11/21/14 21:2710.0 0.010 1 Analytical Method: SM 4500-Cl-E4500 Chloride Chloride 17300 ug/L 12/03/14 03:55 16887-00-610005001 Analytical Method: SM 5220D5220D COD Chemical Oxygen Demand 431000 ug/L 11/25/14 16:0025000125001 Analytical Method: SM 5310B5310B TOC Total Organic Carbon 1370 ug/L 12/04/14 01:25 7440-44-010005001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/12/2014 05:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92226725 Town of Kernersville MNA Sample:3404-MW4 Lab ID:92226725004 Collected:11/20/14 15:00 Received:11/21/14 11:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: RSK 175RSK 175 AIR Headspace Ethane ND ug/L 11/25/14 22:26 74-84-06.2 3.1 1 Ethene ND ug/L 11/25/14 22:26 74-85-16.2 3.1 1 Methane 186 ug/L 11/25/14 22:26 74-82-86.6 3.3 1 Analytical Method: SM 2320B2320B Alkalinity Alkalinity, Total as CaCO3 181000 ug/L 12/03/14 18:01500010001 Analytical Method: SM 4500-S2D4500S2D Sulfide Water Sulfide ND ug/L 11/24/14 16:30 18496-25-810001001 Analytical Method: SM 5210B5210B BOD, 5 day BOD, 5 day ND ug/L 11/26/14 12:0311/21/14 15:06200020001 Analytical Method: EPA 300.0300.0 IC Anions 28 Days Sulfate 1560J ug/L 12/05/14 12:13 14808-79-825000010001 Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate ND mg/L 11/21/14 21:4710.0 0.010 1 Analytical Method: SM 4500-Cl-E4500 Chloride Chloride 17100 ug/L 12/03/14 03:55 16887-00-610005001 Analytical Method: SM 5220D5220D COD Chemical Oxygen Demand ND ug/L 11/25/14 16:0025000125001 Analytical Method: SM 5310B5310B TOC Total Organic Carbon 1100 ug/L 12/04/14 01:36 7440-44-010005001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/12/2014 05:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92226725 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: AIR/21922 RSK 175 RSK 175 RSK 175 AIR HEADSPACE Associated Lab Samples:92226725001, 92226725002, 92226725003, 92226725004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1853100 Associated Lab Samples:92226725001, 92226725002, 92226725003, 92226725004 Matrix:Water Analyzed Ethane ug/L ND 6.2 11/25/14 21:11 Ethene ug/L ND 6.2 11/25/14 21:11 Methane ug/L ND 6.6 11/25/14 21:11 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1853101LABORATORY CONTROL SAMPLE & LCSD: LCSSpike LCSD % Rec RPD Max RPD LCSD Result 1853102 Ethane ug/L 117114 103 85-115104118 1 20 Ethene ug/L 109106 103 85-115104110 1 20 Methane ug/L 60.060.7 99 85-11510060.5 1 20 Parameter Units Dup Result Max RPD QualifiersRPDResult 2012600005 1853105SAMPLE DUPLICATE: Ethane ug/L ND 20ND Ethene ug/L ND 20ND Methane ug/L ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/12/2014 05:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92226725 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/34562 SM 2320B SM 2320B 2320B Alkalinity Associated Lab Samples:92226725001, 92226725002, 92226725003, 92226725004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1341775 Associated Lab Samples:92226725001, 92226725002, 92226725003, 92226725004 Matrix:Water Analyzed Alkalinity, Total as CaCO3 ug/L ND 5000 12/03/14 11:31 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1341776LABORATORY CONTROL SAMPLE: LCSSpike Alkalinity, Total as CaCO3 ug/L 4830050000 97 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1341777MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92226725002 1341778 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Alkalinity, Total as CaCO3 ug/L M1500008890-11081 2 450000151000195000191000 Parameter Units MS Result % Rec Limits Qual% RecConc. 1341779MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92227529001 1341780 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Alkalinity, Total as CaCO3 ug/L 50000 93 90-11094 1 45000022.9 mg/L 69600 70000 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/12/2014 05:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92226725 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/34421 SM 4500-S2D SM 4500-S2D 4500S2D Sulfide Water Associated Lab Samples:92226725001, 92226725002, 92226725003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1336896 Associated Lab Samples:92226725001, 92226725002, 92226725003 Matrix:Water Analyzed Sulfide ug/L ND 1000 11/24/14 14:00 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1336897LABORATORY CONTROL SAMPLE: LCSSpike Sulfide ug/L 521J500 104 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1336898MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92226152002 1336899 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfide ug/L 500 97 90-11097 0 105000.15 mg/L 639J 639J Parameter Units MS Result % Rec Limits Qual% RecConc. 1336900MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92226660007 1336901 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfide ug/L 500 97 90-11097 0 10500ND521J523J REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/12/2014 05:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92226725 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/34429 SM 4500-S2D SM 4500-S2D 4500S2D Sulfide Water Associated Lab Samples:92226725004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1337167 Associated Lab Samples:92226725004 Matrix:Water Analyzed Sulfide ug/L ND 1000 11/24/14 16:30 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1337168LABORATORY CONTROL SAMPLE: LCSSpike Sulfide ug/L 514J500 103 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1337169MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92226725004 1337170 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfide ug/L 500 95 90-11095 0 10500ND508J510J Parameter Units MS Result % Rec Limits Qual% RecConc. 1337171MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92226449005 1337172 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfide ug/L 500 95 90-11095 0 10500ND480J480J REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/12/2014 05:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92226725 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/34401 SM 5210B SM 5210B 5210B BOD, 5 day Associated Lab Samples:92226725001, 92226725002, 92226725003, 92226725004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1336011 Associated Lab Samples:92226725001, 92226725002, 92226725003, 92226725004 Matrix:Water Analyzed BOD, 5 day ug/L ND 2000 11/26/14 12:03 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1336012LABORATORY CONTROL SAMPLE: LCSSpike BOD, 5 day ug/L 209000198000 106 84.5-115.4 Parameter Units Dup Result Max RPD QualifiersRPDResult 92226725001 1336013SAMPLE DUPLICATE: BOD, 5 day ug/L 5860 D618104900 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/12/2014 05:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92226725 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/21135 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples:92226725001, 92226725002, 92226725003, 92226725004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1343354 Associated Lab Samples:92226725001, 92226725002, 92226725003, 92226725004 Matrix:Water Analyzed Sulfate ug/L ND 250000 12/04/14 20:05 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1343355LABORATORY CONTROL SAMPLE: LCSSpike Sulfate ug/L 19100J20000 95 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1343356MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92226451005 1343357 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate ug/L 20000 92 90-11092 1 10200003.1 mg/L 21600J 21400J Parameter Units MS Result % Rec Limits Qual% RecConc. 1343358MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92226611006 1343359 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate ug/L 20000 100 90-110100 0 102000014.8 mg/L 34700J 34700J REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/12/2014 05:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92226725 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/21018 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92226725001, 92226725002, 92226725003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1336531 Associated Lab Samples:92226725001, 92226725002, 92226725003 Matrix:Water Analyzed Nitrogen, Nitrate mg/L ND 10.0 11/21/14 20:55 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1336532LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate mg/L 2.4J2.5 95 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1336533MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92226648007 1336534 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L 2.5 96 90-11096 0 102.51.0 3.4J 3.4J Parameter Units MS Result % Rec Limits Qual% RecConc. 1336535MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92226713001 1336536 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L 2.5 96 90-11095 0 102.50.065 2.5J 2.4J REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/12/2014 05:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92226725 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/21019 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92226725004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1336537 Associated Lab Samples:92226725004 Matrix:Water Analyzed Nitrogen, Nitrate mg/L ND 10.0 11/21/14 21:39 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1336538LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate mg/L 2.4J2.5 95 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1336539MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92226648004 1336540 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L M12.5 88 90-11088 0 102.52.6 4.8J 4.8J REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/12/2014 05:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92226725 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/21097 SM 4500-Cl-E SM 4500-Cl-E 4500 Chloride Associated Lab Samples:92226725001, 92226725002, 92226725003, 92226725004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1340780 Associated Lab Samples:92226725001, 92226725002, 92226725003, 92226725004 Matrix:Water Analyzed Chloride ug/L ND 1000 12/03/14 03:37 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1340781LABORATORY CONTROL SAMPLE: LCSSpike Chloride ug/L 2060020000 103 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1340782MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92226122013 1340783 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride ug/L 20000 102 90-110102 0 102000082402870028600 Parameter Units MS Result % Rec Limits Qual% RecConc. 1340784MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92226725001 1340785 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride ug/L 20000 94 90-11094 0 1020000171003580035800 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/12/2014 05:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92226725 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/21046 SM 5220D SM 5220D 5220D COD Associated Lab Samples:92226725001, 92226725002, 92226725003, 92226725004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1337785 Associated Lab Samples:92226725001, 92226725002, 92226725003, 92226725004 Matrix:Water Analyzed Chemical Oxygen Demand ug/L ND 25000 11/25/14 16:00 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1337786LABORATORY CONTROL SAMPLE: LCSSpike Chemical Oxygen Demand ug/L 746000750000 99 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1337787MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92226597001 1337788 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chemical Oxygen Demand ug/L 750000 104 90-110104 0 375000064.0 mg/L 843000 841000 Parameter Units MS Result % Rec Limits Qual% RecConc. 1337789MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92226920001 1337790 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chemical Oxygen Demand ug/L 750000 104 90-110104 0 3750000122 mg/L 899000 899000 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/12/2014 05:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92226725 Town of Kernersville MNA Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/21113 SM 5310B SM 5310B 5310B TOC Associated Lab Samples:92226725001, 92226725002, 92226725003, 92226725004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1341819 Associated Lab Samples:92226725001, 92226725002, 92226725003, 92226725004 Matrix:Water Analyzed Total Organic Carbon ug/L ND 1000 12/03/14 22:31 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1341820LABORATORY CONTROL SAMPLE: LCSSpike Total Organic Carbon ug/L 2380025000 95 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1341821MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92226611002 1341822 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Total Organic Carbon ug/L M12500015990-110155 2 5250002.4 mg/L 42000 41200 Parameter Units MS Result % Rec Limits Qual% RecConc. 1341823MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92226731002 1341824 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Total Organic Carbon ug/L M12500012190-110118 2 5250001.4 mg/L 31700 31000 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/12/2014 05:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 42 #=QL# QUALIFIERS Pace Project No.: Project: 92226725 Town of Kernersville MNA DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - MinneapolisPASI-M ANALYTE QUALIFIERS The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/12/2014 05:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 42 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92226725 Town of Kernersville MNA Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92226725001 AIR/219223404-MW2 RSK 175 92226725002 AIR/219223404-MW3S RSK 175 92226725003 AIR/219223404-MW3D RSK 175 92226725004 AIR/219223404-MW4 RSK 175 92226725001 WET/345623404-MW2 SM 2320B 92226725002 WET/345623404-MW3S SM 2320B 92226725003 WET/345623404-MW3D SM 2320B 92226725004 WET/345623404-MW4 SM 2320B 92226725001 WET/344213404-MW2 SM 4500-S2D 92226725002 WET/344213404-MW3S SM 4500-S2D 92226725003 WET/344213404-MW3D SM 4500-S2D 92226725004 WET/344293404-MW4 SM 4500-S2D 92226725001 WET/34401 WET/344023404-MW2 SM 5210B SM 5210B 92226725002 WET/34401 WET/344023404-MW3S SM 5210B SM 5210B 92226725003 WET/34401 WET/344023404-MW3D SM 5210B SM 5210B 92226725004 WET/34401 WET/344023404-MW4 SM 5210B SM 5210B 92226725001 WETA/211353404-MW2 EPA 300.0 92226725002 WETA/211353404-MW3S EPA 300.0 92226725003 WETA/211353404-MW3D EPA 300.0 92226725004 WETA/211353404-MW4 EPA 300.0 92226725001 WETA/210183404-MW2 EPA 353.2 92226725002 WETA/210183404-MW3S EPA 353.2 92226725003 WETA/210183404-MW3D EPA 353.2 92226725004 WETA/210193404-MW4 EPA 353.2 92226725001 WETA/210973404-MW2 SM 4500-Cl-E 92226725002 WETA/210973404-MW3S SM 4500-Cl-E 92226725003 WETA/210973404-MW3D SM 4500-Cl-E 92226725004 WETA/210973404-MW4 SM 4500-Cl-E 92226725001 WETA/210463404-MW2 SM 5220D 92226725002 WETA/210463404-MW3S SM 5220D 92226725003 WETA/210463404-MW3D SM 5220D 92226725004 WETA/210463404-MW4 SM 5220D 92226725001 WETA/211133404-MW2 SM 5310B 92226725002 WETA/211133404-MW3S SM 5310B 92226725003 WETA/211133404-MW3D SM 5310B 92226725004 WETA/211133404-MW4 SM 5310B REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/12/2014 05:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 42 Page 24 of 42 Page 25 of 42 Page 26 of 42 Page 27 of 42 Page 28 of 42 Page 29 of 42 Page 30 of 42 Page 31 of 42 Page 32 of 42 Page 33 of 42 Page 34 of 42 Page 35 of 42 Page 36 of 42 Page 37 of 42 Page 38 of 42 Page 39 of 42 Page 40 of 42 Page 41 of 42 Page 42 of 42 Appendix II Summary of Detections Appendix II Summary of Detections WELL ID PARAMETER RESULT UNITS METHOD MDL SWSL COLLECT DATE 3404-MW2 Hydrogen 2 nM AM20GAX 0.13 NE 11/20/2014 3404-MW2 Barium 301 ug/L EPA 6010 2.5 100 11/20/2014 3404-MW2 1,1-Dichloroethane 21.5 ug/L EPA 8260 0.32 5 11/20/2014 3404-MW2 1,2-Dichloropropane 4.1 ug/L EPA 8260 0.27 1 11/20/2014 3404-MW2 1,4-Dichlorobenzene 4.7 ug/L EPA 8260 0.33 1 11/20/2014 3404-MW2 Benzene 6.2 ug/L EPA 8260 0.25 1 11/20/2014 3404-MW2 cis-1,2-Dichloroethene 44.9 ug/L EPA 8260 0.19 5 11/20/2014 3404-MW2 Tetrachloroethene 1.1 ug/L EPA 8260 0.46 1 11/20/2014 3404-MW2 Trichloroethene 5.1 ug/L EPA 8260 0.47 1 11/20/2014 3404-MW2 Vinyl chloride 5.2 ug/L EPA 8260 0.62 1 11/20/2014 3404-MW2 Methane 4980 ug/L RSK 175 3.3 NE 11/20/2014 3404-MW2 Alkalinity, Total as CaCO3 159000 ug/L SM 2320B 1000 NE 11/20/2014 3404-MW2 Chloride 17100 ug/L SM 4500-Cl-E 500 NE 11/20/2014 3404-MW2 BOD, 5 day 4900 ug/L SM 5210B 2000 NE 11/20/2014 3404-MW2 Total Organic Carbon 2150 ug/L SM 5310B 500 NE 11/20/2014 3404-MW3D Hydrogen 4.4 nM AM20GAX 0.13 NE 11/20/2014 3404-MW3D 1,2-Dichloropropane 1.2 ug/L EPA 8260 0.27 1 11/20/2014 3404-MW3D 1,4-Dichlorobenzene 3.8 ug/L EPA 8260 0.33 1 11/20/2014 3404-MW3D cis-1,2-Dichloroethene 55.4 ug/L EPA 8260 0.19 5 11/20/2014 3404-MW3D Vinyl chloride 5.3 ug/L EPA 8260 0.62 1 11/20/2014 3404-MW3D Methane 182 ug/L RSK 175 3.3 NE 11/20/2014 3404-MW3D Alkalinity, Total as CaCO3 159000 ug/L SM 2320B 1000 NE 11/20/2014 3404-MW3D Chloride 17300 ug/L SM 4500-Cl-E 500 NE 11/20/2014 3404-MW3D Chemical Oxygen Demand 431000 ug/L SM 5220D 12500 NE 11/20/2014 3404-MW3D Total Organic Carbon 1370 ug/L SM 5310B 500 NE 11/20/2014 3404-MW3S Hydrogen 1.1 nM AM20GAX 0.13 NE 11/20/2014 3404-MW3S Barium 113 ug/L EPA 6010 2.5 100 11/20/2014 3404-MW3S Zinc 20.9 ug/L EPA 6010 5 10 11/20/2014 3404-MW3S 1,4-Dichlorobenzene 1.9 ug/L EPA 8260 0.33 1 11/20/2014 3404-MW3S cis-1,2-Dichloroethene 9.6 ug/L EPA 8260 0.19 5 11/20/2014 3404-MW3S Vinyl chloride 2.1 ug/L EPA 8260 0.62 1 11/20/2014 3404-MW3S Methane 159 ug/L RSK 175 3.3 NE 11/20/2014 3404-MW3S Alkalinity, Total as CaCO3 151000 ug/L SM 2320B 1000 NE 11/20/2014 3404-MW3S Chloride 27900 ug/L SM 4500-Cl-E 500 NE 11/20/2014 3404-MW3S Total Organic Carbon 1750 ug/L SM 5310B 500 NE 11/20/2014 3404-MW4 Hydrogen 1.4 nM AM20GAX 0.13 NE 11/20/2014 3404-MW4 1,4-Dichlorobenzene 2.6 ug/L EPA 8260 0.33 1 11/20/2014 3404-MW4 cis-1,2-Dichloroethene 19.3 ug/L EPA 8260 0.19 5 11/20/2014 3404-MW4 Vinyl chloride 16.2 ug/L EPA 8260 0.62 1 11/20/2014 3404-MW4 Methane 186 ug/L RSK 175 3.3 NE 11/20/2014 3404-MW4 Alkalinity, Total as CaCO3 181000 ug/L SM 2320B 1000 NE 11/20/2014 3404-MW4 Chloride 17100 ug/L SM 4500-Cl-E 500 NE 11/20/2014 3404-MW4 Total Organic Carbon 1100 ug/L SM 5310B 500 NE 11/20/2014 3404-MW5 Barium 108 ug/L EPA 6010 2.5 100 11/20/2014 3404-MW5 Cobalt 10.2 ug/L EPA 6010 2.5 10 11/20/2014 3404-MW5 Zinc 55 ug/L EPA 6010 5 10 11/20/2014 Town of Kernersville Landfill Joyce Engineering Appendix III Summary of Exceedances Appendix III Summary of Exceedances WELL ID PARAMETER RESULT UNITS METHOD MDL NC2L or GWPS COLLECT DATE 3404-MW2 1,1-Dichloroethane 21.5 ug/L EPA 8260 0.32 6 11/20/2014 3404-MW2 1,2-Dichloropropane 4.1 ug/L EPA 8260 0.27 0.6 11/20/2014 3404-MW2 Benzene 6.2 ug/L EPA 8260 0.25 1 11/20/2014 3404-MW2 Tetrachloroethene 1.1 ug/L EPA 8260 0.46 0.7 11/20/2014 3404-MW2 Trichloroethene 5.1 ug/L EPA 8260 0.47 3 11/20/2014 3404-MW2 Vinyl chloride 5.2 ug/L EPA 8260 0.62 0.03 11/20/2014 3404-MW3D 1,2-Dichloropropane 1.2 ug/L EPA 8260 0.27 0.6 11/20/2014 3404-MW3D Vinyl chloride 5.3 ug/L EPA 8260 0.62 0.03 11/20/2014 3404-MW3S Vinyl chloride 2.1 ug/L EPA 8260 0.62 0.03 11/20/2014 3404-MW4 Vinyl chloride 16.2 ug/L EPA 8260 0.62 0.03 11/20/2014 3404-MW5 Cobalt 10.2 ug/L EPA 6010 2.5 1 11/20/2014 Town of Kernersville Landfill Joyce Engineering