41B-DEMO_WileyDavisRdLF_DIN26638_20151231

WATERS EDGE ENVIRONMENTAL, LLC
4901 WATERS EDGE DRIVE, SUITE 201  RALEIGH, NC 27606  PHONE [phone]  FAX [phone]

North Carolina Groundwater/Surface Water Exceedance Notification
(December 31st, 2015)

Well Parameter Concentration (mg/L) NCGS (mg/L)

WD-1 Chromium 0.014 0.010

WD-2 Benzene 0.0013 0.001
WD-2 THF 0.100 0.0046*

WD-2D THF 0.068 0.0046*

WD-3 Barium 0.8 0.7
WD-3 THF 0.023 0.0046*

WD-4 Barium 0.79 0.7
WD-4 THF 0.015 0.0046*

WD-7 Chromium 0.02 0.01

WD-8 Barium 0.84 0.7
WD-8 Chromium 0.013 0.01

WD-9 Cadmium 0.028 0.002

December 2015 Groundwater and Surface Water Sampling Report
Former Wiley Davis Landfill
Wiley Davis Road
Greensboro, North Carolina
Permit #41-B
January 20, 2016

Prepared For Submittal To

Griffin Industrial Services, LLC
Greensboro, North Carolina 27407

Prepared By

Waters Edge Environmental, LLC
Raleigh, North Carolina
WATERS EDGE ENVIRONMENTAL, LLC
4901 WATERS EDGE DRIVE, SUITE 201  RALEIGH, NC 27606  PHONE [phone]  FAX [phone]

January 20, 2016

Mr. David Griffin, Jr.
Griffin Industrial Services, LLC
4700 Hilltop Road
Greensboro, North Carolina 27407

Reference: December 2015 Groundwater and Surface Water Sampling Report
Former Wiley David Landfill
Wiley Davis Road
Greensboro, North Carolina
Permit #41-B
Waters Edge Job No. R5-34

Dear Mr. Griffin:

Waters Edge Environmental has completed the December 2015 groundwater and surface
water sampling event at the above mentioned facility.

If you have any questions regarding the information contained herein, please do not
hesitate to contact our office at 919.859.9987.

Sincerely,

WATERS EDGE ENVIRONMENTAL, LLC

Phillip L Rahn, P.G.
President

cc: Ms. Christine Ritter- NCDENR

16-008/PLR/aht

ii
Table of Contents

1 Introduction 1
2 Groundwater Sampling Activities 1
2.1 Monitor Well Sampling 1
2.2 Surface Water Sampling 1
3 Assessment Results 2
3.1 Groundwater Conditions 2
3.2 Groundwater Laboratory Analytical Results 2
3.3 Surface Water Laboratory Analytical Results 3
4 Conclusions and Recommendations 3

Figures

Figure No. Title

1 Site Location Map
2 Aerial Photograph Map
3 Groundwater Potentiometric Surface (December 2015)

Tables

Table No. Title

1 Groundwater Elevation Data
2 Hydraulic Gradient Data
3 Groundwater / Surface Water Analytical Results

Appendices

Appendix Title

A Laboratory Analytical Results

Page 1 of 4
December 2015 Ground and Surface Water Sampling Report
Former Wiley Davis Landfill
Wiley Davis Road
Greensboro, North Carolina
Permit #41-B
January 20, 2016

1 Introduction

A groundwater and surface water assessment is ongoing at the former Wiley Davis
Landfill (Permit #41-B) located on Wiley Davis Road in Greensboro, North Carolina (see
Figures 1 and 2). The purpose of this assessment is to determine the presence, extent,
and concentration of contaminants present in groundwater and/or surface water, the
horizontal and vertical extent of contamination which may originate from the landfill, the
direction and rate of migration of the contaminants in the groundwater, and the possible
source(s) of contamination detected in the groundwater and/or surface water.

This assessment is being performed in accordance with the Water Quality Monitoring
Plan (Babb & Associates, P.A. and EcoLogic Associates, P.C. - Revised August 1999)
and the Groundwater Assessment Plan (Babb & Associates, P.A. and EcoLogic
Associates, P.C. - Revised August 1999). Since 2005 the sampling responsibilities have
been contracted with Waters Edge Environmental, LLC (Waters Edge).

Herein contains an account of the field sampling, laboratory analytical results and our
conclusions and recommendations for the site.

2 Groundwater Sampling Activities

2.1 Monitoring Well Sampling

On December 31st, 2015, a Waters Edge environmental technician was mobilized to the
site for the groundwater sampling activities. Prior to the sampling event, depth-to-
groundwater measurements were made to the nearest 0.01 foot at each monitoring well
using an electric water level indicator (see Tables 1 and 2).

Groundwater samples were collected from wells WD-1, WD-2, WD-2D, WD-3, WD-3D,
WD-4, WD-4D, WD-7, WD-8, and WD-9. Groundwater samples were analyzed for
volatile organic compounds (VOCs) and tetrahydrofuran (THF) according to EPA Method
8260B and total RCRA metals (EPA Method 6010 and 7470- see summary of analytical
results in Table 3 and documentation in Appendix A).

2.3 Surface Water Sampling

On December 31st, 2015, both upgradient (SW-1 see Figure 2) and downgradient (SW-2 see
Figure 2) surface water samples were collected and analyzed for VOCs and THF according
December 2015 Ground & Surface Water Sampling Report
Wiley Davis Landfill
Greensboro, North Carolina
January 20, 2016
16-008

Page 2 of 4
to EPA Method 8260B and total RCRA metals (EPA Method 6010 and 7470- see summary
of analytical results in Table 3 and documentation in Appendix A).

3 Assessment Results

3.1 Groundwater Conditions

On December 31st, 2015 water level measurements collected from the shallow wells
indicate the shallow water table elevations range from 816.99 feet (WD-7) to 787.07 feet
(WD-3) above mean sea level (msl). We would add that WD-2, WD-2D, WD-8 and
WD-9 have not been surveyed to add as a data point. The groundwater elevations
continue to indicate an overall southwesterly flow direction for shallow groundwater.
The horizontal hydraulic gradient of the shallow water table has an average gradient of
0.0162 ft/ft (see Figure 3)

The vertical gradient was calculated to be 0.0532 ft/ft downward between wells WD-3
and WD-3D and -0.0931 upward between wells WD-4 and WD-4D. We would also note
that WD-2/WD-2D have not been surveyed.

3.2 Groundwater Laboratory Analytical Results

Laboratory analysis of groundwater samples collected had the following exceedances of
North Carolina Groundwater Standards (NCGS):

WD-1 This well had the following NCGS exceedances:
 Chromium at 0.014 mg/L versus a NCGS at 0.01 mg/L
WD-2 This well had the following NCGS exceedances:
 Benzene at 0.0013 mg/L versus a NCGS at 0.001 mg/L
 THF at 0.1 mg/L versus a North Carolina Occupational and
Environmental Epidemiology Branch Recommended 2L Standard of
0.0046 mg/L (there is no codified NCGS)
WD-2D This well had the following NCGS exceedances:
 THF at 0.068 mg/L versus a North Carolina Occupational and
Environmental Epidemiology Branch Recommended 2L Standard of
0.0046 mg/L (there is no codified NCGS)
WD-3 This well had the following NCGS exceedances:
 Barium at 0.8 mg/L versus a NCGS at 0.7 mg/L
December 2015 Ground & Surface Water Sampling Report
Wiley Davis Landfill
Greensboro, North Carolina
January 20, 2016
16-008

Page 3 of 4
 THF at 0.023 mg/L versus a North Carolina Occupational and
Environmental Epidemiology Branch Recommended 2L Standard of
0.0046 mg/L (there is no codified NCGS)
WD-4 This well had the following NCGS exceedances:
 Barium at 0.79 mg/L versus a NCGS at 0.7 mg/L
 THF at 0.015 mg/L versus a North Carolina Occupational and
Environmental Epidemiology Branch Recommended 2L Standard of
0.0046 mg/L (there is no codified NCGS)
WD-7 This well had the following NCGS exceedances:
 Chromium at 0.072 mg/L versus a NCGS at 0.01 mg/L
WD-8 This well had the following NCGS exceedances:
 Barium at 0.84 mg/L versus a NCGS at 0.7 mg/L
 Chromium at 0.013 mg/L versus a NCGS at 0.01 mg/L
WD-9 This well had the following NCGS exceedances:
 Cadmium at 0.0028 mg/L versus a NCGS at 0.002 mg/L

3.3 Surface Water Laboratory Analytical Results

Low levels of one inorganic constituent was detected in upstream sampling point SW-1
(barium at 0.15 mg/L), and the downstream sampling point SW-2 had one inorganic
(barium at 0.13 mg/L); however, no applicable Class C surface water standards were
exceeded (15A NCAC 2B .0211).

4 Conclusions and Recommendations

Information gathered during groundwater assessment activities to date indicates the
general shallow and deep groundwater flow direction (horizontal gradient) beneath the
site to be to the southwest. Using a horizontal hydraulic gradient of 0.0162 ft/ft and
assuming an average hydraulic conductivity in saprolite of 1E-5 cm/sec and an effective
porosity of 0.25, the rate of horizontal groundwater migration would be on the order of
0.612 ft/year.

Now that the landfill is no longer active and has been graded to shed runoff and covered,
the infiltration of rainfall should be significantly reduced. It follows that the driving head
inside the landfill will gradually decline and both the quantity and rate of leachate
December 2015 Ground & Surface Water Sampling Report
Wiley Davis Landfill
Greensboro, North Carolina
January 20, 2016
16-008

Page 4 of 4
production and release should decrease proportionately. Leachate strength should also
continue to decline as the waste stabilizes, with no further introduction of potential
contaminants. Based on these recent results, we would conclude that a continued positive
trend in groundwater quality downgradient of the landfill has occurred.

There were several low level NCGS exceedances for arsenic, barium, cadmium,
chromium and selenium. THF was also detected at low concentrations in four of the
wells sampled ranging from 0.015 mg/L (WD-4) to 0.1 mg/L (WD-2) which is above the
interim NCGS at 4.6 g/L. Based upon our research into THF uses, it appears one major
use is for PVC pipe cement which could have been mistakenly used in the older
monitoring wells. The newer monitoring wells were ND for THF during this sampling
round. The levels in the remaining wells appear to be either stable or decreasing to below
NCGS with respect to time.

There were also several inorganic constituents detected in the newly emplaced
monitoring wells WD-8 and WD-9. Based on the total absence of VOCs, we would still
conclude that these are potentially due to sediment causing false positive readings. We
believe that with continued development and sampling that the inorganic constituents will
decrease. We would conclude that the plume is adequately defined horizontally.

Only one RCRA metal was detected in surface water samples (barium) at concentrations
well below the 2B standards. As such, we conclude that no measurable impacts to
surface water by VOCs or metals have been identified during this assessment.

Given the aforementioned conclusions, it is our recommendation to Wiley Davis Landfill,
Inc. that monitoring of the current system be continued on a semiannual schedule and
once the offsite monitoring wells reduce to below NCGS, be reduced to an annual
schedule. This next sampling event would be conducted in November 2016. We would
also recommend that WD-2, WD-2D, WD-8, and WD-9 be surveyed for both horizontal
and vertical control.

Figures
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Tables
Table 1
Monitoring Well Reference Points and Groundwater Elevaltions
Wiley Davis Landfill,
Greensboro, North Carolina
Well ID Reference Point
Elevation
Water Level
Measurement
(12.31.15)
Water Level Elevation
WD-1 836.65 31.93 804.72
WD-3 791.35 4.28 787.07
WD-3D 793.79 8.74 785.05
WD-4 793.28 4.72 788.56
WD-4D 799.11 6.22 792.89
WD-7 828.08 11.04 817.04
Table 1 GW Elevations
Table 2
Hydraulic Gradient Information
Wiley Davis Landfill
Greensboro, North Carolina
Water Level Elevation
Well I.D. 12.31.15 Gradient
(ft.) (ft.)
WD-1 804.72
0.0181
WD-3 787.07
WD-1 804.72
0.0169
WD-4 788.56
WD-7 817.04
0.0189
WD-1 804.72
WD-7 817.04
0.0218
WD-4 788.56
WD-4D 792.89
0.0176
WD-3D 785.05
WD-3 787.07
0.0532
WD-3D 785.05
WD-4 788.56
-0.0931
WD-4D 792.89
A Negative Hydraulic Gradient Indicates Greater Hydraulic Head in the Deeper Well or Upward Flow.
Waters Edge Job No. R5-34 Wiley Davis Groundwater Table.xlsx.xls, Table 2 Hydraulic Grad
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.
.
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
1
0
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
1
5

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

1
2

1
6
00
0
0
0
0
0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
2.
0

0
.
3
8
0
No
t

S
a
m
p
l
e
d
0.
5
8
0

0
.
3
1
4

N
A

0
.
4
5
0

0
.
3
0
0

0
.
2
7
0

0
.
2
9
1

0
.
3
2
0

0
.
2
0
0
Ca
d
m
i
u
m
mg
/
l
0.
0
0
5

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
0.
0
0
6
..
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
0.
1
6
0
No
t

S
a
m
p
l
e
d
0.
3
6
0
0.
0
5
0

N
A
0.
0
7
0
0.
0
4
0

.
0.
1
1
0

0
.
0
7
1

0
.
0
8
4
Le
a
d
mg
/
l
0.
0
1
5

.
No
t

S
a
m
p
l
e
d
0.
0
0
6

.

N
A
..
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
1

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
5

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
1
8

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
1
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

M
a
r
-
0
0

S
e
p
-
0
0

M
a
y
-
0
1

D
e
c
-
0
1

J
u
l
-
0
2

J
a
n
-
0
3

M
a
y
-
0
5

M
a
r
-
0
6

M
a
y
-
0
6

N
o
v
-
0
6

J
u
n
-
0
7
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
.
.
.
.
.
.
bi
s
-
(
2
-
e
t
h
y
l
h
e
x
y
l
)

p
h
t
h
a
l
a
t
e
ug
/
L
3.0
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,
8
0
0
..
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
m
e
t
h
a
n
e
ug
/
L
3.
.
.
.
.
.
.
.
.
.
2
.
5
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
di
-
n
-
b
u
t
y
l

p
h
t
h
a
l
a
t
e
ug
/
L
700
.
.
.
.
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
700
.
.
.
.
.
.
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l

I
o
d
i
d
e
ug
/
L
NS
.
.
.
.
.
2
.
0
N
A
N
A
N
A
N
A
N
A
4-
(
o
-
c
r
e
s
o
l
)

M
e
t
h
y
l
p
h
e
n
o
l
ug
/
L
3.5
.
.
.
.
.
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
21
.
.
.
.
.
.
.
.
.
.
.
N-
N
i
t
r
o
s
o
d
i
p
h
e
n
y
l
a
m
i
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
..
.
.
.
.
.
.
.
.
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
1
0
0
..
.
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
1
5
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-
00
0
0
0
2
.
0
0
0
0
0
2
.
5
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5
..
.
.
.
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
2.
0

.

.

0
.
2
9
4

.

0
.
2
8
1

0
.
2
9
0

0
.
3
5

0
.
3
7

0
.
3
7

0
.
4
7

0
.
4
7
Ca
d
m
i
u
m
mg
/
l
0.
0
0
5

.

0
.
0
0
1
3

0
.
0
0
1
4
..
.
.
.
.
0.
0
0
2
0
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
..
.
.
.
.
0.
0
1
4

.

.
0.
1
1
0.
0
4
1
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
1
..
.
.
.
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
5

.

.

0
.
0
1
0
5
..
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
1
8
..
.
.
.
.
.
.
.
0.
0
0
7
5

.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
1
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

N
o
v
-
0
7

M
a
y
-
0
8

N
o
v
-
0
8

M
a
y
-
0
9

N
o
v
-
0
9

J
u
n
-
1
0

N
o
v
-
1
0

M
a
y
-
1
1

N
o
v
-
1
1

M
a
y
-
1
2

D
e
c
-
1
2
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0
..
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
m
e
t
h
a
n
e
ug
/
L
3.
.
.
.
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20
.
.
.
.
.
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
..
.
.
.
.
.
.
.
.
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0
..
.
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-
00
0
0
0
0
0
0
0
0
0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1
..
.
.
.
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
0.
7

0
.
4
7

0
.
4
6

0
.
4
0

0
.
4
1

0
.
4
8

0
.
4
0

0
.
4
6

0
.
4
3

0
.
4
7

0
.
4
4

0
.
4
6
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2

.

0
.
0
0
1
2
..
.
.
.
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1
0.
0
5
2

0
.
0
9
6

0
.
0
4
4

0
.
0
2
5

0
.
0
4
0

0
.
0
2
5

0
.
0
6
1

0
.
0
2
7

0
.
0
4
1

0
.
0
2
0

0
.
0
1
4
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
..
.
.
.
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
.
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
2

.

0
.
0
0
7
4
..
.
.
0.
0
0
5
8
..
.
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
1
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

J
u
n
-
1
3

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5

D
e
c
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0
..
.
.
.
Ch
l
o
r
o
m
e
t
h
a
n
e
ug
/
L
3.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
..
.
.
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0
..
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-
00
0
0
0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1
..
.
.
.
Ba
r
i
u
m
mg
/
l
0.
7

0
.
5
0

0
.
5
2

0
.
4
8

0
.
4
4

0
.
5
2
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1
0.
0
2
4

0
.
0
3
3

0
.
0
1
2
0.
0
1
0
0.
0
1
4
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
..
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
2
..
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
2
s
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

A
u
g
-
9
0

M
a
r
-
9
1

A
p
r
-
9
1

M
a
y
-
9
3

O
c
t
-
9
3

A
p
r
-
9
4

F
e
b
-
9
6

A
u
g
-
9
6

A
p
r
-
9
7

N
o
v
-
9
7

O
c
t
-
9
8
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
2.
2
4
..
bi
s
-
(
2
-
e
t
h
y
l
h
e
x
y
l
)

p
h
t
h
a
l
a
t
e
ug
/
L
3.
0

6

J
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
se
c
-
b
u
t
y
l
b
e
n
z
e
n
e
ug
/
L
70

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
35
0
No
t

S
a
m
p
l
e
d
23
0

1
4
0
.
15
0

6
2

8
9

1
1
0

1
1
0

7
8
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,
8
0
0

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
di
-
n
-
b
u
t
y
l

p
h
t
h
a
l
a
t
e
ug
/
L
70
0

2
5
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
62
No
t

S
a
m
p
l
e
d
39

1
2

.

1
3

.

.

5
.
0

.

.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
5
J
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
25
No
t

S
a
m
p
l
e
d
12.
.
5
.
0
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
70
0

.
No
t

S
a
m
p
l
e
d
20

5
.
9

.

5
.
0

.

.

1
.
1
9

.

.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
Et
h
y
l
b
e
n
z
e
n
e
ug
/
L
55
0

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e
ug
/
L
70

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
p-
I
s
o
p
r
o
p
y
l
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.
0

.
No
t

S
a
m
p
l
e
d
6.
0
..
.
.
.
.
.
.
Me
t
h
y
l
-
t
e
r
t

b
u
t
y
l

e
t
h
e
r
ug
/
L
20
0
.
0

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
4-
(
o
-
c
r
e
s
o
l
)

M
e
t
h
y
l
p
h
e
n
o
l
ug
/
L
3.
5

.
No
t

S
a
m
p
l
e
d
47
.

.

N
A

N
A

N
A

N
A

N
A

N
A
Na
p
h
t
h
a
l
e
n
e
ug
/
L
21

.
No
t

S
a
m
p
l
e
d
10 J
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
To
l
u
e
n
e
ug
/
L
1,
0
0
0

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
ug
/
L
35
0

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
1,
3
,
5
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
ug
/
L
35
0

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
1
5

.
No
t

S
a
m
p
l
e
d
16
..
.
.
.
.
.
.
Xy
l
e
n
e
s
ug
/
L
53
0

.
No
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

4
7
3

3
8
0

1
5
7
.
9

0

1
7
3

6
2

8
9

1
1
8
.
4
3

1
1
0

7
8
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
2.
0

0
.
8
0
0
No
t

S
a
m
p
l
e
d
1.
7
0
0

1
.
3
0
0

N
A
2.
2
0
0
1.
9
0
0
2.
4
0
0

2
.
1
2
7

2
.
4
0
0

2
.
4
0
0
Ca
d
m
i
u
m
mg
/
l
0.
0
0
5

.
No
t

S
a
m
p
l
e
d
NA

.

N
A

.

.

.

0
.
0
0
3

.

.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5

.
No
t

S
a
m
p
l
e
d
.

.

N
A

.

.

.

0
.
0
0
5

.

.
Le
a
d
mg
/
l
0.
0
1
5

.
No
t

S
a
m
p
l
e
d
.

.

N
A

.

.

.

0
.
0
0
5

.

.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
1

.
No
t

S
a
m
p
l
e
d
..
N
A
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
5

.
No
t

S
a
m
p
l
e
d
..
N
A
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
1
8

.
No
t

S
a
m
p
l
e
d
..
N
A
.
.
.
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
2
s
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

M
a
r
-
0
0

N
o
v
-
0
6

J
u
n
-
0
7

N
o
v
-
0
7

M
a
y
-
0
8

N
o
v
-
0
8

M
a
y
-
0
9

N
o
v
-
0
9

J
u
n
-
1
0

N
o
v
-
1
0

M
a
y
-
1
1
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0

.
1.
9

1
.
7

1
.
8

1
.
8

1
.
6

1
.
5

1
.
9

1
.
9

1
.
2

1
.
8
se
c
-
b
u
t
y
l
b
e
n
z
e
n
e
ug
/
L
70
.
0
..
.
.
2
.
0
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
94
7.3
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0
..
.
.
.
.
.
.
.
.
1
Ch
l
o
r
o
m
e
t
h
a
n
e
ug
/
L
3.
1
.
6
.
.
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
205
.
0
1
.
8
.
.
.
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
.
.
.
.
.
.
Di
c
h
l
o
r
o
d
i
f
l
u
o
r
o
m
e
t
h
a
n
e

(f
r
e
o
n
)

u
g
/
L
1,
0
0
0

.
1.
9
..
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6

.

.

1
.
5

3
.
6

1
.
6

2
.
0

.

3
.
9

.

.

.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
.
.
.
.
Et
h
y
l
b
e
n
z
e
n
e
ug
/
L
60
0

.

.

1
.
2

1
.
4

1
.
0

1
.
7

1
.
5

1
.
7

.

.

.
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e (
C
u
m
e
n
e
)

u
g
/
L
70

.

.

1
.
8

2
.
3

2
.
0

1
.
7

2
.
1

2
.
3

2
.
6

2
.
1

2
.
8
p-
I
s
o
p
r
o
p
y
l
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.1.
8
1
.
1
.
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
-
t
e
r
t

b
u
t
y
l

e
t
h
e
r
ug
/
L
20
.
.
1
.
2
1
.
2
.
.
1
.
1
.
.
.
.
4-
(
o
-
c
r
e
s
o
l
)

M
e
t
h
y
l
p
h
e
n
o
l
ug
/
L
40
.
.
.
.
.
N
A
N
A
N
A
N
A
N
A
N
A
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6

.

3
.
3

4
.
1

5
.
3

6
.
5

3
.
1

1
.
6

6
.
4

2
.
0

.

2
.
1
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
54

1
1
0

1
8
0

1
9
0

1
1
0

1
7

1
1

1
6
0

1
5
0

9
1

8
9
To
l
u
e
n
e
ug
/
L
60
0
.
.

2
.
1

1
.
5

1
.
1

.

.

1
.
2

.

.

.
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
ug
/
L
40
0
.
.

3
.
3

3
.
3

.

2
.
4

2
.
0

1
.
7

.

.

1
.
2
1,
3
,
5
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
ug
/
L
40
0
.
.1.
1
1
.
1
1
.
1
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
.
.
.
.
.
.
.
Xy
l
e
n
e
s
ug
/
L
50
0

.

.

5
.
6

5
.
3

4
.
8

3
.
9

4
.
1

4
.
0

2
.
3

.

2
.
9
To
t
a
l

V
O
C
s

u
g
/
L

-
-

1
5
3

1
2
9
.
6

2
0
4
.
7

2
1
6
.
8

1
3
1
.
9

3
3
.
4

2
4
.
9

1
8
3
.
1

1
5
8
.
8

9
4
.
3

1
0
0
.
8
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1

.

.
0.
0
1
4
0.
0
0
7
4

0
.
0
0
6
7

.
0.
0
1
9
0.
0
0
9
7
0.
0
2
4

0
.
0
1
5
.
Ba
r
i
u
m
mg
/
l
0.
7
2.
2
4
0.
3
4

0
.
3
6

0
.
4
7

0
.
5
3

0
.
3
1

0
.
5
2

0
.
3
7
0.
7
2
0.
4
1

0
.
3
9
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2

0
.
0
0
3
3
..
.
.
.
.
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1

.

0
.
0
0
9
2

0
.
0
0
8
8
0.
0
2
2

0
.
0
1
2
0.
0
0
9
8

0
.
0
0
8
5

0
.
0
1
0
0.
0
3
8
0.
0
1
0

0
.
0
0
9
1
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
.
.
.
0.
0
0
8
8

.

.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
..
.
.
.
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
.
.
0.
0
1
2
..
.
.
Si
l
v
e
r
mg
/
l
0.
0
2

.

0
.
0
0
5
0
..
.
.
0.
0
0
5
0

0
.
0
0
5
4

0
.
0
0
5
4

.

.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
2
s
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

N
o
v
-
1
1

M
a
y
-
1
2

D
e
c
-
1
2

J
u
n
-
1
3

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5

D
e
c
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0
2.
2

1
.
3

1
.
4

1
.
6

1
.
5

2
.
1

1
.
7

1
.
3
se
c
-
b
u
t
y
l
b
e
n
z
e
n
e
ug
/
L
70
.
0
..
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0
..
.
.
.
.
.
.
Ch
l
o
r
o
m
e
t
h
a
n
e
ug
/
L
3.
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20
.
.
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
.
.
.
Di
c
h
l
o
r
o
d
i
f
l
u
o
r
o
m
e
t
h
a
n
e

(f
r
e
o
n
)

u
g
/
L
1,
0
0
0
..
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
.
Et
h
y
l
b
e
n
z
e
n
e
ug
/
L
600
.
.
.
.
.
.
.
.
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e (
C
u
m
e
n
e
)

u
g
/
L
70

3
.
0

2
.
7

2
.
4

2
.
1

2
.
9

4
.
5

2
.
7

1
.
4
p-
I
s
o
p
r
o
p
y
l
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
Me
t
h
y
l
-
t
e
r
t

b
u
t
y
l

e
t
h
e
r
ug
/
L
20
.
.
.
.
.
.
.
.
4-
(
o
-
c
r
e
s
o
l
)

M
e
t
h
y
l
p
h
e
n
o
l
ug
/
L
40
.
.
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6

1
.
9

.

.

1
.
3

1
.
0

.

.

1
.
6
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
13
0

8
5

1
9
0

9
2

1
5
0

1
4
0

1
0
0

1
0
0
To
l
u
e
n
e
ug
/
L
600
.
.
.
.
.
.
.
.
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
ug
/
L
400
.
.
.
.
.
.
.
.
1,
3
,
5
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
ug
/
L
400
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
.
.
.
.
Xy
l
e
n
e
s
ug
/
L
500
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

1
3
7
.
1

8
9
.
0

1
9
3
.
8

9
7
.
0

1
5
5
.
4

1
4
6
.
6

1
0
4
.
4

1
0
4
.
3
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1

0
.
0
0
7
3

0
.
0
0
8
2
..
.
.
.
.
Ba
r
i
u
m
mg
/
l
0.
7
0.
7
1
0.
6
8
0.
8
2

0
.
7
5

0
.
8
0

0
.
7
2

0
.
8
2
0.
5
9
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1
0.
0
1
4

0
.
0
1
1

0
.
0
1
4

0
.
0
1
2

0
.
0
1
3

0
.
0
1
2

0
.
0
1
1
0.
0
0
7
9
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
.
0.
0
0
5

0
.
0
0
5
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
..
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
.
.
0.
0
2
9
.
Si
l
v
e
r
mg
/
l
0.
0
2

.

.

0
.
0
0
5
1
..
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
2
d
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

A
u
g
-
9
0

M
a
r
-
9
1

A
p
r
-
9
1

M
a
y
-
9
3

O
c
t
-
9
3

A
p
r
-
9
4

F
e
b
-
9
6

A
u
g
-
9
6

A
p
r
-
9
7

N
o
v
-
9
7

O
c
t
-
9
8
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
1.
7
9
..
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

4
7
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
10
0
.
11
0

1
0
0

9
3

9
4

1
1
0

5
7
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,
8
0
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Ch
l
o
r
o
m
e
t
h
a
n
e
ug
/
L
3.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
26

.

3
4

1
2

2
2

1
5

6
.
6

1
0
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
7
.
2
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
70
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
6.
3

.

5
.
0

.

.

1
.
8
1

.

.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
4-
(
o
-
c
r
e
s
o
l
)

M
e
t
h
y
l
p
h
e
n
o
l
ug
/
L
3.
5

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
.

.

N
A

N
A

N
A

N
A

N
A

N
A
Na
p
h
t
h
a
l
e
n
e
ug
/
L
21

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
1
0
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
1
5

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

4
7

1
3
2
.
3

0

1
4
9

1
1
2

1
2
2
.
2

1
1
2
.
6
0

1
1
6
.
6

6
7
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5

.

N
A

N
A
..
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
2.
0

0
.
2
0
0

N
A

0
.
3
1
0

0
.
1
1
2

N
A

0
.
2
3
0

0
.
1
0
0

0
.
2
5
0

0
.
1
5
8

0
.
1
9
0

0
.
1
8
0
Ca
d
m
i
u
m
mg
/
l
0.
0
0
5

.

N
A

N
A

.

N
A

.
0.
0
0
6
..
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5

.

N
A

0
.
0
3
0

.

N
A

.

0
.
0
1
5

.

.

.
Le
a
d
mg
/
l
0.
0
1
5
0.
4
4
0
.

.

0
.
0
1
5

N
A

.

.

0
.
0
0
5

.

.

.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
1

.

N
A

N
A

.

N
A
..
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
5

.

N
A

N
A

.

N
A
..
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
1
8

.

N
A

N
A

.

N
A
..
.
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
2
d
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

M
a
r
-
0
0

N
o
v
-
0
6

J
u
n
-
0
7

N
o
v
-
0
8

M
a
y
-
0
8

N
o
v
-
0
8

M
a
y
-
0
9

N
o
v
-
0
9

J
u
n
-
1
0

N
o
v
-
1
0

M
a
y
-
1
1
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0

.
1.
6

2
.
4

2
.
0

2
.
3

1
.
3

1
.
2
..
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
68
.

7
.
8

8
.
8

9
.
4

4
.
6

5
.
8

5
.
5

2
.
5

4
.
5

3
.
5
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0

.

4
.
6
..
.
.
.
.
.
.
.
Ch
l
o
r
o
m
e
t
h
a
n
e
ug
/
L
3.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20

1
0

.

1
.
3

1
.
6

1
.
9

.

1
.
2

1
.
4

1
.
0

1
.
2

1
.
2
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
1
.
9
.
.
.
.
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
.
.
.
.
Di
c
h
l
o
r
o
d
i
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
1,
0
0
0

.

.

1
.
9

.

1
.
1
..
.
.
.
.
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e

(c
u
m
e
n
e
)

u
g
/
L
70

.

2
.
1

1
.
8

3
.
6

3
.
1

1
.
2

1
.
6

1
.
5

1
.
5

.

1
.
0
p-
I
s
o
p
r
o
p
y
l
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.3.
9
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
2
.
3
.
.
.
.
.
Me
t
h
y
l
-
t
e
r
t

b
u
t
y
l

e
t
h
e
r
ug
/
L
20
.
0

.

1
.
3
..
.
.
.
.
.
.
.
4-
(
o
-
c
r
e
s
o
l
)

M
e
t
h
y
l
p
h
e
n
o
l
ug
/
L
40
.
.
.
.
.
N
A
N
A
N
A
N
A
N
A
N
A
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
8
.
9
1
.
2
1
.
1
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
51

1
8
0

1
7
0

1
1
0

1
3
0

1
3

1
1

1
2
0

5
1

6
2

5
5
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0
..
.
.
.
.
.
.
.
.
.
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
ug
/
L
400
.
2
.
5
.
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
.
.
.
.
.
.
.
Xy
l
e
n
e
s

(t
o
t
a
l
)

u
g
/
L
500
.
4
.
3
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

1
2
9

2
1
1
.
1

1
8
6
.
4

1
2
7
.
1

1
4
7
.
8

2
2
.
4

2
0
.
8

1
2
8
.
4

5
6
.
0

6
7
.
7

6
0
.
7
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1

0
.
0
1
0
8

.

0
.
0
0
5
9

.

0
.
0
0
6
8

0
.
0
0
9
2

0
.
0
0
7
6

0
.
0
0
8
4

0
.
0
0
6
8

.

.
Ba
r
i
u
m
mg
/
l
0.
7

.

0
.
4
5

0
.
2
1

0
.
1
9

0
.
1
9

0
.
2
6

0
.
1
5

0
.
1
9
2.
2
0.
1
3

0
.
2
3
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2

0
.
0
0
2
0

0
.
0
0
1
6

.

.

0
.
0
0
1
9

.

.

.
0.
0
2
4
..
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1

.
0.
0
1
6

0
.
0
1
7
0.
0
0
8

0
.
0
2
1
0.
0
1
5

0
.
0
1
2

0
.
0
1
1

0
.
2
0.
0
0
5
8
0.
0
1
8
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
.
.
.
0.
0
6
9
..
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
..
.
.
.
0.
0
0
0
2
1
..
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
.
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
2
..
.
.
.
.
.
.
0.
0
0
5
7

.

.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
2
d
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

N
o
v
-
1
1

M
a
y
-
1
2

D
e
c
-
1
2

J
u
n
-
1
3

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5

D
e
c
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

4
.
4

3
.
1

3
.
5

4
.
2

4
.
8

3
.
7

4
.
7

5
.
3
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0
..
.
.
.
.
.
.
Ch
l
o
r
o
m
e
t
h
a
n
e
ug
/
L
3.
.
.
1
.
0
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20

1
.
1

.

.

1
.
1

1
.
1

1
.
1

1
.
4

1
.
2
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
.
Di
c
h
l
o
r
o
d
i
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
1,
0
0
0
..
.
.
.
.
.
.
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e

(c
u
m
e
n
e
)

u
g
/
L
701
.
2
.
.
.
.
.
.
.
p-
I
s
o
p
r
o
p
y
l
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
Me
t
h
y
l
-
t
e
r
t

b
u
t
y
l

e
t
h
e
r
ug
/
L
20
.
0
..
.
.
.
.
.
.
4-
(
o
-
c
r
e
s
o
l
)

M
e
t
h
y
l
p
h
e
n
o
l
ug
/
L
40
.
.
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
64

4
2

3
9

5
5

3
7

3
4

5
0

6
8
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0
..
.
.
.
.
.
.
1,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
ug
/
L
400
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
.
.
.
.
Xy
l
e
n
e
s

(t
o
t
a
l
)

u
g
/
L
500
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

7
0
.
7

4
5
.
1

4
2
.
5

6
1
.
3

4
2
.
9

3
8
.
8

5
6
.
1

7
4
.
5
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1
..
.
.
.
0.
0
1
4
..
Ba
r
i
u
m
mg
/
l
0.
7

0
.
0
6
5

0
.
2
0

0
.
2
7

0
.
4
5

0
.
4
2

0
.
5
7

0
.
2
7

0
.
2
7
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1

.

0
.
0
0
9
7
0.
0
1
2

0
.
0
1
7

0
.
0
1
2

0
.
0
3
1
..
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
0.
0
1
7
..
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
..
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
.
.
0.
0
1
2

.
Si
l
v
e
r
mg
/
l
0.
0
2
..
.
.
.
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
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o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
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c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
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d

d
e
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e
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t
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o
n

l
i
m
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t
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Da
t
a

t
h
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u

1
.
1
5
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2
0
0
3

c
o
m
p
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l
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d

f
r
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m

p
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v
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r
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t
a
b
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.
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l
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y

D
a
v
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s

G
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a
b
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l
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x
l
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b
l
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3
.

G
r
o
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d
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a
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r

L
a
b
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y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
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y

D
a
v
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s

L
a
n
d
f
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l
l
,

G
r
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e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
3
Pa
r
a
m
e
t
e
r
Un
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t
s

2
L

S
t
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n
d
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r
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A
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g
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9
0

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a
r
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9
1

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p
r
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1

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a
y
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9
3

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c
t
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3

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p
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9
4

F
e
b
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9
6

A
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g
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6

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p
r
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9
7

N
o
v
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9
7

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c
t
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9
8
Vo
l
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t
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l
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O
r
g
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c

C
o
m
p
o
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s
Be
n
z
e
n
e
ug
/
L
1.0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
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e
d
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s
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)

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h
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l
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/
L
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.

N
o
t

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a
m
p
l
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d

N
o
t

S
a
m
p
l
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d
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.
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.
Ch
l
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/
L
50

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
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d
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.
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l
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/
L
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0

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No
t

S
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m
p
l
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d

N
o
t

S
a
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d
..
.
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l
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/
L
No

S
t
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n
d
a
r
d
.
No
t

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a
m
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l
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d

N
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b
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L
70
0

8

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No
t

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d

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d
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D
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e

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-
D
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c
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o
)

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/
L
No

S
t
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d
a
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d
.
No
t

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d

N
o
t

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/
L
No

S
t
a
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d
a
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d
.
No
t

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d

N
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t

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e

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-
D
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c
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o
)

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L
No

S
t
a
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d
a
r
d
.
No
t

S
a
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l
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d

N
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d
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ug
/
L
70
0

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No
t

S
a
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d

N
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t

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1
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/
L
70

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No
t

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a
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d

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t

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d
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t
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C
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/
L
5.0

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No
t

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d

N
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t

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/
L
No

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t
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d
a
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d
.
No
t

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d

N
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(
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L
3.5

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t

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d

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t

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d
.

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/
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21

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d

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/
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No

S
t
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d
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No
t

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/
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4.
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*

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t

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d

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t

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/
L
2,1
0
0

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No
t

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a
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p
l
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d

N
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t

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5

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t

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d

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t
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l
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0
5

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d
NA

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A

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0
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0
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4

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1
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5
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d
1.
4
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0

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6
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9

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7
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8

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4
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4
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d
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mg
/
l
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5

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t

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d
NA.
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A
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0.
0
0
6
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r
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m
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m
mg
/
l
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0
5

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t

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d
0.
0
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0

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8
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a
d
mg
/
l
0.0
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5

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t

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d
0.
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5

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A

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5

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0
0
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1

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No
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S
a
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d
NA

.

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A

.

.

0
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0
0
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0
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8

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1
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0
5

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No
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d
NA.
N
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.
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l
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/
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8

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No
t

S
a
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d
NA.
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A
.
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.
NA

-

c
o
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d

n
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a
n
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e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
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r
i
m

M
a
x
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u
m

A
l
l
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w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
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t

d
e
t
e
c
t
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d

a
t

t
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e

m
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t
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d

d
e
t
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c
t
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o
n

l
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m
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t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
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l
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d

f
r
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m

p
r
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v
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s

r
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p
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r
t

t
a
b
l
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s
.
Wil
e
y

D
a
v
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s

G
r
o
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n
d
w
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t
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r

T
a
b
l
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.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
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y

D
a
v
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s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
3
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

M
a
r
-
0
0

S
e
p
-
0
0

M
a
y
-
0
1

D
e
c
-
0
1

J
u
l
-
0
2

J
a
n
-
0
3

M
a
y
-
0
5

M
a
r
-
0
6

M
a
y
-
0
6

N
o
v
-
0
6

J
u
n
-
0
7
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
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d
s
Be
n
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n
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ug
/
L
1.0
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.
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.
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.
bi
s
-
(
2
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e
t
h
y
l
h
e
x
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l
)

p
h
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l
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t
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/
L
3.0
.
.
.
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.
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.
.
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l
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o
b
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n
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/
L
50
.
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.
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.
Ch
l
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h
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/
L
2,8
0
0
..
.
.
.
.
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Ch
l
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f
l
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m
e
t
h
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ug
/
L
No

S
t
a
n
d
a
r
d
..
.
2
.
0
.
.
.
.
.
.
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2
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c
h
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b
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n
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n
e

(o
-
D
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c
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l
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r
o
)

u
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/
L
No

S
t
a
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d
a
r
d
..
.
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1,
3
-
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c
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/
L
No

S
t
a
n
d
a
r
d
..
.
.
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.
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4
-
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n
e

(p
-
D
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c
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o
)

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g
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No

S
t
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d
a
r
d
..
.
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.
.
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1
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c
h
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t
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n
e

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/
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700
.
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2
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c
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l
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e
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h
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n
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ug
/
L
70
.
.
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.
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.
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Me
t
h
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l
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e

C
h
l
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r
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d
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ug
/
L
5.0
.
.
.
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.
.
.
.
.
.
.
Na
p
h
t
h
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l
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n
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ug
/
L
21
.
.
.
.
.
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.
.
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.
.
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t
r
a
h
y
d
r
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f
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r
a
n
ug
/
L
4.
6
*

.
10
..
15

2
4

1
5

5
9

1
5

2
2

1
8
Tr
i
c
h
l
o
r
o
f
l
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o
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m
e
t
h
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n
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ug
/
L
2,1
0
0
..
.
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
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d
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ug
/
L
0.0
1
5
..
.
.
.
.
.
.
.
.
.
To
t
a
l

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O
C
s

u
g
/
L

-
-

0

1
0

0

2
.
0

1
5

2
4

1
5

5
9

1
5

2
2

1
8
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5

0
.
0
1
1
7
..
.
.
.
0.0
0
7
5

.

.

0
.
0
0
5
2

.
Ba
r
i
u
m
mg
/
l
2.0

0
.
6
0
2

.

0
.
3
2
5

.

0
.
2
9
7

0
.
5
0
5

1
.
5
0

0
.
9
6

0
.
2
7

0
.
8
8

0
.
8
3
Ca
d
m
i
u
m
mg
/
l
0.0
0
5

0
.
0
0
4
1

0
.
0
0
1
5

0
.
0
0
1
3
..
.
.
.
.
0.0
0
4
3

0
.
0
0
3
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
..
.
.
.
.
0.0
0
7
3

.

0
.
0
0
2
3

0
.
0
1
7

0
.
0
0
7
9
Le
a
d
mg
/
l
0.0
1
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
1
..
.
.
.
.
.
.
.
.
0.
0
0
0
4
Se
l
e
n
i
u
m
mg
/
l
0.
0
5
..
.
.
.
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.0
1
8
..
.
.
.
.
.
.
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wil
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
3
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

N
o
v
-
0
7

M
a
y
-
0
8

N
o
v
-
0
8

M
a
y
-
0
9

J
u
n
-
1
0

N
o
v
-
1
0

M
a
y
-
1
1

N
o
v
-
1
1

M
a
y
-
1
2

D
e
c
-
1
2

J
u
n
-
1
3
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,0
0
0
..
.
.
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20
.
.
.
.
.
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
cis
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
27

3
4

2
8

1
7

1
1

3
1

2
3

2
1

2
3

1
2

2
0
To
l
u
e
n
e
ug
/
L
600
.
.
.
.
.
2
3
0
.
.
.
.
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,0
0
0
..
.
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

2
7

3
4

2
8

1
7

1
1

2
6
1

2
3

2
1

2
3

1
2

2
0
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1

.

0
.
0
0
7
6

0
.
0
0
6
7
0.0
1
2

0
.
0
1
3

0
.
0
1
5
.

.

0
.
0
0
6
7

.

.
Ba
r
i
u
m
mg
/
l
0.7
1.1

0
.
8
4

0
.
8
2

1
.
2

0
.
7
5

0
.
9
2

0
.
8
4

0
.
7
9
0.6
8
0.
9
0

0
.
9
5
Ca
d
m
i
u
m
mg
/
l
0.0
0
2

.
0.
0
0
5
.

.

.

0
.
0
0
3
9

.

.

0
.
0
0
1
5

.

.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1

0
.
0
0
8
9
0.
0
2
5
.

0
.
0
0
9
3

0
.
0
0
8
0.
0
2
5
0.0
0
7
9
0.0
1
2
..
.
Le
a
d
mg
/
l
0.0
1
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.0
0
1

0
.
0
0
0
2

.

.

0
.
0
0
0
3

.

0
.
0
0
0
3
3
..
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2

0
.
0
1
3

.

0
.
0
1
6
..
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
2
..
.
.
.
.
.
.
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wil
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
3
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5

D
e
c
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,0
0
0
..
.
.
Ch
l
o
r
o
m
e
t
h
a
n
e
ug
/
L
3.
.
.
1
.
5
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
cis
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
14

2
3

2
2

2
3
To
l
u
e
n
e
ug
/
L
600
.
.
.
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,0
0
0
..
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

1
4

2
3

2
2

2
4
.
5
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1
..
.
.
Ba
r
i
u
m
mg
/
l
0.7

0
.
5
6
0.9
6

0
.
8
2

0
.
8
0
Ca
d
m
i
u
m
mg
/
l
0.0
0
2

.
..
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1

.

0
.
0
0
6
7

0
.
0
0
6
0

.
Le
a
d
mg
/
l
0.0
1
5
..
.
.
Me
r
c
u
r
y
mg
/
l
0.0
0
1
..
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2

.

.

0
.
0
1
3

.
Si
l
v
e
r
mg
/
l
0.
0
2
..
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wil
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
3
D
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

M
a
r
-
0
0

S
e
p
-
0
0

M
a
y
-
0
1

D
e
c
-
0
1

J
u
l
-
0
2

J
a
n
-
0
3

M
a
y
-
0
5

M
a
r
-
0
6

M
a
y
-
0
6

N
o
v
-
0
6

J
u
n
-
0
7
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
3
.
0
.
.
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,
8
0
0
..
.
.
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.

.

.

5
.
0

3
.
0

3
.
0

1
.
8

.

1
.
0

1
.
2

1
.
2
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
700
.
.
.
.
.
.
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
21
.
.
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

9
.
0
27
..
35

1
9
.
54
..
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
1
0
0
..
.
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
1
5
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

9
.
0

2
7

0

8
.
0

3
8

2
2

1
.
8

5
4

1
.
0

1
.
2

1
.
2
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5
..
.
.
.
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
2.
0

.

.

0
.
3
4
1

.

.

.

0
.
9
2

0
.
0
7
1

0
.
0
4
2

0
.
1
3

0
.
0
8
4
Ca
d
m
i
u
m
mg
/
l
0.
0
0
5

0
.
0
0
1
7

.

0
.
0
0
1
1
..
.
.
.
.
0.
0
0
1
1

.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
..
.
.
.
.
.
0.
0
0
3
4

0
.
0
0
2
8

0
.
0
1
0

0
.
0
0
6
7
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
1
..
.
.
.
.
.
.
.
.
0.
0
0
0
2
6
Se
l
e
n
i
u
m
mg
/
l
0.
0
5

.

.

0
.
0
1
0
2

.

.

.

0
.
0
0
6
9
..
.
.
Si
l
v
e
r
mg
/
l
0.
0
1
8
..
.
.
.
.
.
.
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
3
D

(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

N
o
v
-
0
7

M
a
y
-
0
8

N
o
v
-
0
8

M
a
y
-
0
9

N
o
v
-
0
9

J
u
n
-
1
0

N
o
v
-
1
0

M
a
y
-
1
1

N
o
v
-
1
1

M
a
y
-
1
2

D
e
c
-
1
2
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

2
.
9

1
.
4

1
.
1

.

1
.
1

.

.

.

1
.
1

.

.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0
..
.
.
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20

2
.
7

1
.
7

1
.
3

1
.
3

1
.
3

1
.
1

1
.
2

1
.
4

1
.
1

1
.
1

1
.
1
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
20

1
6
..
10

.

1
0
1
1
1
1
..
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0
..
.
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

2
5
.
6

1
9
.
1

2
.
4

1
.
3

1
2
.
4

1
.
1

1
1
.
2

1
2
.
4

1
3
.
2

1
.
1

1
.
1
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1

.

.

.

0
.
0
0
5
4

.

0
.
0
0
5
6

.

0
.
0
0
5
2

.

.

.
Ba
r
i
u
m
mg
/
l
0.
7

0

0
.
0
6
8

0
.
1
1

0
.
1
4

0
.
1
4

0
.
0
8

0
.
1
5

0
.
1
2

0
.
1
4

0
.
1
3

0
.
1
6
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
.
.
.
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1

.

0
.
0
0
5
6

0
.
0
0
7
2

0
.
0
0
9
6
0.
0
1
1
0.
0
0
9
0.
0
1
4

0
.
0
1
4

0
.
0
1
7

0
.
0
1
2

0
.
0
1
5
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
..
.
.
.
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
.
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
2
..
.
.
.
.
.
.
.
.
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
3
D

(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

J
u
n
-
1
3

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5

D
e
c
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0
..
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
..
.
.
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0
..
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

0
.
0

0
.
0

0
.
0

0
.
0

0
.
0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1
..
.
.
.
Ba
r
i
u
m
mg
/
l
0.
7

0
.
1
4

0
.
1
4

0
.
1
0

0
.
1
4

0
.
0
6
8
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1
0.
0
1
5

0
.
0
1
1

0
.
0
1
1
0.
0
0
7
9

0
.
0
0
6
3
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
..
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
2
..
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
4
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

A
u
g
-
9
0

M
a
r
-
9
1

A
p
r
-
9
1

M
a
y
-
9
3

O
c
t
-
9
3

A
p
r
-
9
4

F
e
b
-
9
6

A
u
g
-
9
6

A
p
r
-
9
7

N
o
v
-
9
7

O
c
t
-
9
8
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
2.0
9

.

.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,8
0
0

9

J
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
70
0

8
.
0
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
cis
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
21

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,1
0
0

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.0
1
5

.
No
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

1
7
.
0
00
0
0
0
2.0
9

0

0
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
2.
0

1
.
3
0
0
No
t

S
a
m
p
l
e
d
1.4
0
0

0
.
7
0
4

N
A

.

0
.
7
0
0

1
.
0
0
0

0
.
7
0
6

0
.
8
4
0

0
.
8
3
0
Ca
d
m
i
u
m
mg
/
l
0.0
0
5

.
No
t

S
a
m
p
l
e
d
NA

.

N
A
1.
0
.

.

0
.
0
0
2

.

.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5

0
.
1
1
0
No
t

S
a
m
p
l
e
d
0.1
1
0

.

N
A
..
.
.
.
.
Le
a
d
mg
/
l
0.0
1
5

0
.
0
1
0
No
t

S
a
m
p
l
e
d
0.0
0
6

0
.
0
1
8

N
A
..
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
1

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
5

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.0
1
8

.
No
t

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
4
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

M
a
r
-
0
0

S
e
p
-
0
0

M
a
y
-
0
1

D
e
c
-
0
1

J
u
l
-
0
2

J
a
n
-
0
3

M
a
y
-
0
5

M
a
r
-
0
6

M
a
y
-
0
6

N
o
v
-
0
6

J
u
n
-
0
7
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
1
.
0
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

.

.

.

1
.
0

1
.
0

2
.
0

.

1
.
1

1
.
3

1
.
5

1
.
4
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,8
0
0

.

.

.

2
.
0

1
.
0
..
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
N
A
N
A
N
A
N
A
N
A
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
2
.
0
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
700
.
.
.
.
.
.
.
.
.
.
.
cis
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
21
.
.
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

.
16
..
24

2
0

1
8

6
0

1
6

1
7
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,1
0
0
..
.
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.0
1
5
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

0

1
6

0

3
.
0

2
6

2
5

1
8

6
1
.
1

1
7
.
3

1
8
.
5

1
.
4
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5
..
.
.
.
.
0.0
0
6
0
..
.
.
Ba
r
i
u
m
mg
/
l
2.
0

0
.
7
6
1

0
.
7
5
2

0
.
6
8
5

0
.
7
9
7

0
.
7
7
0

0
.
7
4
1

0
.
0
7
9

0
.
8
4

0
.
7
1

0
.
7
6

0
.
7
0
Ca
d
m
i
u
m
mg
/
l
0.0
0
5

0
.
0
0
2
1

0
.
0
0
1
5

0
.
0
0
1
7
..
.
.
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
..
.
.
.
.
.
.
.
0.0
1
1

.
Le
a
d
mg
/
l
0.0
1
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
1
..
.
.
.
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
5
..
.
.
.
.
.
0.
0
0
7
4

0
.
0
0
6
1

.

.
Si
l
v
e
r
mg
/
l
0.0
1
8

.

.

0
.
0
1
3
4
..
.
.
.
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
4
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

N
o
v
-
0
7

M
a
y
-
0
8

N
o
v
-
0
8

M
a
y
-
0
9

J
u
n
-
1
0

N
o
v
-
1
0

M
a
y
-
1
1

N
o
v
-
1
1

M
a
y
-
1
2

D
e
c
-
1
2

J
u
n
-
1
3
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

.

1
.
5

1
.
2

1
.
4

1
.
3

1
.
5

1
.
5

1
.
9

.

1
.
5

1
.
5
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,0
0
0
..
.
.
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20
.
.
.
.
.
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
61.
0
.
.
.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
cis
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
18

2
2

2
0

1
7

1
6

1
7

1
9

2
1
..
20
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,0
0
0
..
.
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

1
9

2
3
.
5

2
1
.
2

1
8
.
4

1
7
.
3

1
8
.
5

2
0
.
5

2
2
.
9

0
.
0

1
.
5

2
1
.
5
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1

.

.

.

0
.
0
0
9
0

0
.
0
1
3

0
.
0
0
5
3
..
.
.
.
Ba
r
i
u
m
mg
/
l
0.
7
0.
7
7

0
.
7
8
0.
6
6
0.7
8

0
.
9
5

0
.
8
3

0
.
7
5

0
.
8
2

0
.
7
2

0
.
8
6

0
.
8
1
Ca
d
m
i
u
m
mg
/
l
0.0
0
2
..
.
.
0.0
0
1
3
..
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1

0
.
0
2
0.
0
1
6
0.
0
0
5
9

.
0.0
1
6
0.
0
0
5
4

0
.
0
0
6
1

0
.
0
0
7
7

0
.
0
0
5
6

0
.
0
0
7
7

0
.
0
0
6
8
Le
a
d
mg
/
l
0.0
1
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.0
0
1
..
.
.
.
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
.
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
2
..
.
.
.
.
.
0.
0
0
5
0

.

.

.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
4
(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5

D
e
c
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

1
.
5

1
.
6

1
.
6

1
.
5
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,0
0
0
..
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
cis
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
25

1
4

1
6

1
5
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,0
0
0
..
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

2
7

1
5
.
6

1
7
.
6

1
6
.
5
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1
..
.
.
Ba
r
i
u
m
mg
/
l
0.
7
0.
8
2

0
.
8
4

0
.
7
9

0
.
7
9
Ca
d
m
i
u
m
mg
/
l
0.0
0
2
..
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1

0
.
0
0
6
4
0.
0
1
1
.

0
.
0
0
7
2
Le
a
d
mg
/
l
0.0
1
5
..
.
.
Me
r
c
u
r
y
mg
/
l
0.0
0
1
..
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2

.

.

0
.
0
1
8

.
Si
l
v
e
r
mg
/
l
0.
0
2
..
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
4
D
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

M
a
r
-
0
0

S
e
p
-
0
0

M
a
y
-
0
1

D
e
c
-
0
1

J
u
l
-
0
2

J
a
n
-
0
3

M
a
y
-
0
5

M
a
r
-
0
6

M
a
y
-
0
6

N
o
v
-
0
6

J
u
n
-
0
7
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
.
.
.
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,
8
0
0
..
.
.
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
700
.
.
.
.
.
1
.
0
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
1
.
0
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
-
t
e
r
t
-
b
u
t
y
l

e
t
h
e
r
ug
/
L
200
.
.
.
.
.
.
1
.
0
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
21
.
.
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

7
.
0
20
..
33

2
3

1
3

6
1
.
13
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
1
0
0
..
.
.
2
.
0
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
1
5
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

7
.
0

2
0

0

0

3
5

2
5

1
4

6
1

0

1
3

0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5
..
.
.
.
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
2.0
.
.
.
.
.
.
0.
0
6
6

0
.
0
4
8

0
.
0
3
5

0
.
0
2
6

0
.
0
2
0
Ca
d
m
i
u
m
mg
/
l
0.
0
0
5

0
.
0
0
1
5

0
.
0
0
1
1
..
.
.
.
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
..
.
.
.
.
0.
0
1
5
..
.
.
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
1
..
.
.
.
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
5

.

.

0
.
0
1
1
9
..
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
1
8
..
.
.
.
.
.
.
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
4
D

(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

N
o
v
-
0
7

M
a
y
-
0
8

N
o
v
-
0
8

M
a
y
-
0
9

N
o
v
-
0
9

J
u
n
-
1
0

N
o
v
-
1
0

M
a
y
-
1
1

N
o
v
-
1
1

M
a
y
-
1
2

D
e
c
-
1
2
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
.
.
.
.
.
.
Br
o
m
o
m
e
t
h
a
n
e
ug
/
L
NSE
.
.
.
.
.
.
3
.
1
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
.
.
.
.
.
.
1
.
4
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0
..
.
.
.
.
.
.
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20
.
.
.
.
.
.
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
.
.
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
1
.
0
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
.
.
.
.
.
.
Me
t
h
y
l
-
t
e
r
t
-
b
u
t
y
l

e
t
h
e
r
ug
/
L
20
.
.
.
.
.
.
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

.
15
..
.
.
.
.
.
17

.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0
..
.
.
.
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

0

1
6
00
0
0
3
.
1
0
0
18
.
4

0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1

.

.

.

0
.
0
0
5
4
..
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
0.
7

0
.
0
4
6

0
.
0
3
8

0
.
0
3
1

0
.
0
4
2

0
.
0
4
1

0
.
0
3
7

0
.
0
3
8

0
.
0
3
3

0
.
0
5
7

0
.
0
2
9

0
.
0
3
2
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
.
.
.
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1
..
.
.
.
.
.
.
.
.
.
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
..
.
.
.
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
.
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
2
..
.
.
.
.
.
.
.
.
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
4
D

(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

J
u
n
-
1
3

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5

D
e
c
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0
.
.
.
.
.
Br
o
m
o
m
e
t
h
a
n
e
ug
/
L
NSE
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0
..
.
.
.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20
.
.
.
.
.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
200
.
.
.
.
.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0
.
.
.
.
.
Me
t
h
y
l
-
t
e
r
t
-
b
u
t
y
l

e
t
h
e
r
ug
/
L
20
.
.
.
.
.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*
..
.
.
.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0
..
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3
..
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-
00
0
0
0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1
..
.
.
.
Ba
r
i
u
m
mg
/
l
0.
7

0
.
0
3
5

0
.
0
3
1

0
.
0
3
0

0
.
0
2
9

0
.
0
2
5
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1
..
.
.
.
Le
a
d
mg
/
l
0.
0
1
5
..
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
..
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2
..
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
2
..
.
.
.
NS
E
-

N
o

S
t
a
n
d
a
r
d

E
x
i
s
t
s
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
5
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

A
u
g
-
9
0

M
a
r
-
9
1

A
p
r
-
9
1

M
a
y
-
9
3

O
c
t
-
9
3

A
p
r
-
9
4

F
e
b
-
9
6

A
u
g
-
9
6

A
p
r
-
9
7

N
o
v
-
9
7

O
c
t
-
9
8
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.0

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
bis
-
(
2
-
e
t
h
y
l
h
e
x
y
l
)

p
h
t
h
a
l
a
t
e
ug
/
L
3.0
.

N
o
t

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
3,
0
0
0

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
di-
n
-
b
u
t
y
l

p
h
t
h
a
l
a
t
e
ug
/
L
70
0

6

J
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
1,1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
70
0

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
cis
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.0

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Me
t
h
y
l

I
o
d
i
d
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
4-
(
o
-
c
r
e
s
o
l
)

M
e
t
h
y
l
p
h
e
n
o
l
ug
/
L
3.5

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
.

.

N
A

N
A

N
A

N
A

N
A

N
A
Na
p
h
t
h
a
l
e
n
e
ug
/
L
21

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
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N
i
t
r
o
s
o
d
i
p
h
e
n
y
l
a
m
i
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.6
*

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Tri
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
1
0
0

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
1
5

.
Not

S
a
m
p
l
e
d

N
o
t

S
a
m
p
l
e
d
..
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

6
.
0
00
0
0
0
0
0
0
Me
t
a
l
s

(to
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.0
1

.
Not

S
a
m
p
l
e
d
NA.
.
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
0.7

0
.
4
6
0
Not

S
a
m
p
l
e
d
0.4
9
0

0
.
1
2
8

N
A

.

0
.
3
0
0

0
.
0
5
6

0
.
1
9
1

1
.
0

1
.
1
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2

.
Not

S
a
m
p
l
e
d
NA

0
.
0
3
6

N
A

.

.

.

0
.
0
0
2

.

.
Ch
r
o
m
i
u
m
mg
/
l
0.0
1

0
.
0
5
0
Not

S
a
m
p
l
e
d
0.0
9
0
.

N
A

.

0
.
0
2
0

.

0
.
0
2
1
0.1
8
0

0
.
1
9
0
Le
a
d
mg
/
l
0.
0
1
5

0
.
0
0
9
Not

S
a
m
p
l
e
d
0.0
1
1
0.0
1
7
NA

.

.

.

0
.
0
0
4
0.0
3
9

0
.
0
3
5
Me
r
c
u
r
y
mg
/
l
0.
0
0
1

.
Not

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.0
2

.
Not

S
a
m
p
l
e
d
NA.
N
A
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.0
2

.
Not

S
a
m
p
l
e
d
NA

0
.
0
0
6

N
A

.

.

.

0
.
0
0
4

.

.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
* -

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bla
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wil
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
7
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

M
a
r
-
9
1

A
p
r
-
9
1

M
a
r
-
0
0

S
e
p
-
0
0

M
a
y
-
0
1

D
e
c
-
0
1

J
u
l
-
0
2

J
a
n
-
0
3

M
a
y
-
0
5

M
a
r
-
0
6

M
a
y
-
0
6
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0

N
A

N
A

.

.

.

.

.

.

.

.

.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

.

N
A

.

.

.

.

.

.

.

.

.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,
8
0
0

.

N
A

.

.

.

.

.

.

.

.

.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.N
A
.

.

.

.

.

.

.

.

.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
.N
A
.

.

.

.

.

.

.

.

.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
No

S
t
a
n
d
a
r
d
.N
A
.

.

.

.

.

.

.

.

.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
70
0

.

N
A

.

.

.

.

.

.

.

.

.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70

.

N
A

.

.

.

.

.

.

.

.

.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.
0

.

N
A

.

.

.

.

.

.

.

.

.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
21

N
A

N
A

.

.

.

.

.

.

.

.

.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

.

N
A

.

.

.

.

.

.

.

.

.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
1
0
0

.

N
A

.

.

.

.

.

.

.

.

.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
1
5

N
A

N
A

.

.

.

.

.

.

.

.

.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

0

0

0

0

0

0

0

0

0

0
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5

N
A

N
A

.

.

.

.

.

.

.

.

.
Ba
r
i
u
m
mg
/
l
2.
0

.

0
.
1
2
0

.

.

.

.

.

.

0
.
0
4
5

0
.
0
8
1

0
.
0
5
4
Ca
d
m
i
u
m
mg
/
l
0.
0
0
5

N
A

N
A

.

.

0
.
0
0
1

.

.

.

.

.

.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5

.

.

.

.

0
.
0
1
5
3

0
.
0
1
9

.

.

.

0
.
0
1
9

0
.
0
1
2
Le
a
d
mg
/
l
0.
0
1
5

.

.

.

.

.

.

.

.

.

.

.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1
1

N
A

N
A

.

.

.

.

.

.

.

.

.
Se
l
e
n
i
u
m
mg
/
l
0.
0
5

N
A

N
A

.

.

.

.

.

.

.

.

.
Si
l
v
e
r
mg
/
l
0.
0
1
8

N
A

N
A

.

.

.

.

.

.

.

.

.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
7

(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

N
o
v
-
0
6

J
u
n
-
0
7

N
o
v
-
0
7

M
a
y
-
0
8

N
o
v
-
0
8

M
a
y
-
0
9

N
o
v
-
0
9

J
u
n
-
1
0

N
o
v
-
1
0

M
a
y
-
1
1

N
o
v
-
1
1
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0

.

.

.

.

.

.

.

.

.

.

.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

.

.

.

.

.

.

.

.

.

.

.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,
8
0
0

.

.

.

.

.

.

.

.

.

.

.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20

.

.

.

.

.

.

.

.

.

.

.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
20
0

.

.

.

.

.

.

.

.

.

.

.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70

.

.

.

.

.

.

.

.

.

.

.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.
0

.

.

.

.

.

.

.

.

.

.

.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

.

.

.

.

.

.

.

.

.

.

.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0

.

.

.

.

.

.

.

.

.

.

.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3

.

.

.

.

.

.

.

.

.

.

.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

0

0

0

0

0

0

0

0

0

0

0
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1

.

.

.

.

.

.

.

.

.

.

.
Ba
r
i
u
m
mg
/
l
0.
7

0
.
1
4

0
.
1
2

0
.
2
9

0
.
3
3

0
.
2
0

0
.
2
2

0
.
3
6

0
.
2
3

0
.
2
4

0
.
1
5
0.
9
2
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2

.

.

.

0
.
0
0
1
2

.

.

.

.

.

.

.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1
0.
0
5
6
0.
0
4
3
0.
2
1

0
.
2
5

0
.
0
7
5

0
.
1
3

0
.
1
7

0
.
1
5

0
.
1
4

0
.
0
9
2

0
.
5
7
Le
a
d
mg
/
l
0.
0
1
5

.

.

.

.

.

.

.

.

.

.

.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1

.

.

.

.

.

.

.

.

.

.

.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2

.

.

.

.

.

.

.

.

.

.

0
.
0
1
4
Si
l
v
e
r
mg
/
l
0.
0
2

.

.

.

.

.

.

.

.

.

.

.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

WD
-
7

(
c
o
n
t
i
n
u
e
d
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
L

S
t
a
n
d
a
r
d

M
a
y
-
1
2

D
e
c
-
1
2

J
u
n
-
1
3

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5

D
e
c
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Be
n
z
e
n
e
ug
/
L
1.
0

.

.

.

.

.

.

.
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
50

.

.

.

.

.

.

.
Ch
l
o
r
o
e
t
h
a
n
e
ug
/
L
2,
8
0
0

.

.

.

.

.

.

.
1,
2
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(o
-
D
i
c
h
l
o
r
o
)

u
g
/
L
20

.

.

.

.

.

.

.
1,
3
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
20
0

.

.

.

.

.

.

.
1,
4
-
D
i
c
h
l
o
r
o
b
e
n
z
e
n
e

(p
-
D
i
c
h
l
o
r
o
)

u
g
/
L
6.
.
.
.
.
.
.
1,
1
-
D
i
c
h
l
o
l
o
e
t
h
a
n
e

ug
/
L
6.
.
.
.
.
.
.
ci
s
-
1
,
2
-
D
i
c
h
l
o
r
o
e
t
h
e
n
e
ug
/
L
70

.

.

.

.

.

.

.
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
ug
/
L
5.
0

.

.

.

.

.

.

.
Na
p
h
t
h
a
l
e
n
e
ug
/
L
6.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
6
*

.

.

.

.

.

.

.
Tr
i
c
h
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
2,
0
0
0

.

.

.

.

.

.

.
Vi
n
y
l

C
h
l
o
r
i
d
e
ug
/
L
0.
0
3

.

.

.

.

.

.

.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

0

0

0

0

0

0

0
Me
t
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
1

.

.

.

.

.

.

.
Ba
r
i
u
m
mg
/
l
0.
7

0
.
4
2

0
.
6
1

0
.
5
6

0
.
5
8

0
.
8
6

0
.
2
9

0
.
1
6
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2

0
.
0
0
1
3

.

.

.

.

.

.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
1
0.
2
3

0
.
2
2

0
.
3
7

0
.
2
1

0
.
5
7

0
.
0
7
2

0
.
0
2
0
Le
a
d
mg
/
l
0.
0
1
5

.

.

.

.

0
.
0
1
3

.

.
Me
r
c
u
r
y
mg
/
l
0.
0
0
1

.

.

.

.

.

.

.
Se
l
e
n
i
u
m
mg
/
l
0.
0
2

.

.

.

.

.

.

.
Si
l
v
e
r
mg
/
l
0.
0
2

.

.

.

.

.

.

.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

1
.

G
r
o
u
n
d
w
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
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5
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Me
r
c
u
r
y
mg
/
l
0.
0
0
0
0
1
2
..
.
.
.
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
0
5
..
.
.
.
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
0
0
0
6
..
.
.
.
.
.
.
.
.
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

S
u
r
f
a
c
e

W
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

SW
-
1

(
u
p
s
t
r
e
a
m

c
o
n
t
.
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
B

S
t
a
n
d
a
r
d

J
u
n
-
1
3

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5

D
e
c
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
488
.
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
4
9
0
3
*
..
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-
00
0
0
0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5
..
.
.
.
Ba
r
i
u
m
mg
/
l
1.
0

0
.
1
1

0
.
1
4

0
.
0
5
9

0
.
1

0
.
1
5
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
..
.
.
.
Le
a
d
mg
/
l
0.
0
2
5
..
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
0
0
1
2
..
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
0
5
..
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
0
0
0
6
..
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
2B

-

S
t
a
n
d
a
r
d

f
o
r

C
l
a
s
s

C

S
u
r
f
a
c
e

W
a
t
e
r
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

S
u
r
f
a
c
e

W
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

SW
-
2

(
d
o
w
n
g
r
a
d
i
e
n
t
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
B

S
t
a
n
d
a
r
d

M
a
r
-
0
0

S
e
p
-
0
0

M
a
y
-
0
1

D
e
c
-
0
1

J
u
l
-
0
2

J
a
n
-
0
3

M
a
y
-
0
5

M
a
r
-
0
6

M
a
y
-
0
6

N
o
v
-
0
6

J
u
n
-
0
7
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
488
.
.
.
1
.
0
d
r
y
2
.
0
.
.
.
.
1
.
3
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
1
.
0
d
r
y
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
4
9
0
3
*

.
6.
0
.

.

d
r
y
8.
0
..
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

0

6
.
0

0

2
.
0

1
0
00
0
0
1
.
3
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5
..
.
.
d
r
y
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
1.
0

.

.

0
.
1
5
0

.

d
r
y

0
.
1
1
6

0
.
0
7
7

0
.
3
3

0
.
1
0

0
.
1
1

0
.
3
0
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
d
r
y
.
.
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
..
.
.
d
r
y
.
0.
0
0
2
6
..
.
.
Le
a
d
mg
/
l
0.
0
2
5
..
.
.
d
r
y
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
0
0
1
2
..
.
.
d
r
y
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
0
5

.

.
0.
0
1
4
8
.dr
y
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
0
0
0
6
..
.
.
d
r
y
.
0.
0
0
2
6
..
.
.
SW
-
2

(
d
o
w
n
g
r
a
d
i
e
n
t

c
o
n
t
.
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
B

S
t
a
n
d
a
r
d

N
o
v
-
0
7

M
a
y
-
0
8

N
o
v
-
0
8

M
a
y
-
0
9

N
o
v
-
0
9

J
u
n
-
1
0

N
o
v
-
1
0

M
a
y
-
1
1

N
o
v
-
1
1

M
a
y
-
1
2

D
e
c
-
1
2
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
488
.
.
1
.
1
.
.
.
.
.
.
.
.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
.
.
.
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
4
9
0
3
*
..
.
.
.
.
.
.
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-

0

0

1
.
1
00
0
0
0
0
0
0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5
..
.
.
.
.
.
.
.
.
.
Ba
r
i
u
m
mg
/
l
1.
0

0
.
1
0

0
.
1
2

0
.
1
5

0
.
1
2

0
.
1
6

0
.
1
1

0
.
0
9
5

0
.
0
9
6

0
.
1
8

0
.
0
7
9

0
.
1
2
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
.
.
.
.
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
..
.
.
.
.
.
.
.
.
.
Le
a
d
mg
/
l
0.
0
2
5
..
.
.
.
.
.
.
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
0
0
1
2
..
.
.
.
.
.
.
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
0
5
..
.
.
.
.
.
.
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
0
0
0
6
..
.
.
.
.
.
.
.
.
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s
Ta
b
l
e

3
.

S
u
r
f
a
c
e

W
a
t
e
r

L
a
b
o
r
a
t
o
r
y

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
,

W
i
l
e
y

D
a
v
i
s

L
a
n
d
f
i
l
l
,

G
r
e
e
n
s
b
o
r
o
,

N
o
r
t
h

C
a
r
o
l
i
n
a

SW
-
2

(
d
o
w
n
g
r
a
d
i
e
n
t

c
o
n
t
.
)
Pa
r
a
m
e
t
e
r
Un
i
t
s

2
B

S
t
a
n
d
a
r
d

J
u
n
-
1
3

D
e
c
-
1
3

D
e
c
-
1
4

J
u
n
-
1
5

D
e
c
-
1
5
Vo
l
a
t
i
l
e

O
r
g
a
n
i
c

C
o
m
p
o
u
n
d
s
Ch
l
o
r
o
b
e
n
z
e
n
e
ug
/
L
48
8

.

.

1
.
0

.

.
Ch
l
o
r
o
f
l
u
o
r
o
m
e
t
h
a
n
e
ug
/
L
No

S
t
a
n
d
a
r
d
..
.
.
.
Te
t
r
a
h
y
d
r
o
f
u
r
a
n
ug
/
L
4.
4
9
0
3
*
..
.
.
.
To
t
a
l

V
O
C
s

u
g
/
L

-
-
00
1
0
0
M et
a
l
s

(t
o
t
a
l
)
Ar
s
e
n
i
c
mg
/
l
0.
0
5
..
.
.
.
Ba
r
i
u
m
mg
/
l
1.
0

0
.
1
6

0
.
0
9
9

0
.
1
5

0
.
1
1

0
.
1
3
Ca
d
m
i
u
m
mg
/
l
0.
0
0
2
..
.
.
.
Ch
r
o
m
i
u
m
mg
/
l
0.
0
5
..
.
.
.
Le
a
d
mg
/
l
0.
0
2
5
..
.
.
.
Me
r
c
u
r
y
mg
/
l
0.
0
0
0
0
1
2
..
.
.
.
Se
l
e
n
i
u
m
mg
/
l
0.
0
0
5
..
.
.
.
Si
l
v
e
r
mg
/
l
0.
0
0
0
0
6
..
.
.
.
NA

-

c
o
m
p
o
u
n
d

n
o
t

a
n
a
l
y
z
e
d
2B

-

S
t
a
n
d
a
r
d

f
o
r

C
l
a
s
s

C

S
u
r
f
a
c
e

W
a
t
e
r
*
-

R
e
c
o
m
m
e
n
d
e
d

I
n
t
e
r
i
m

M
a
x
i
u
m

A
l
l
o
w
a
b
l
e

C
o
n
c
e
n
t
r
a
t
i
o
n

(
I
M
A
C
)
Bl
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

c
o
m
p
o
u
n
d

n
o
t

d
e
t
e
c
t
e
d

a
t

t
h
e

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.
Da
t
a

t
h
r
u

1
.
1
5
.
2
0
0
3

c
o
m
p
i
l
e
d

f
r
o
m

p
r
e
v
i
o
u
s

r
e
p
o
r
t

t
a
b
l
e
s
.
Wi
l
e
y

D
a
v
i
s

G
r
o
u
n
d
w
a
t
e
r

T
a
b
l
e
.
x
l
s
x
.
x
l
s

Appendix A
#=CL#
January 14, 2016
LIMS USE: FR - PHIL RAHN
LIMS OBJECT ID: 92281698
92281698
Project:
Pace Project No.:
RE:
Mr. Phil Rahn
Waters Edge Environmental
4901 Water's Edge Drive
Suite 201
Raleigh, NC 27606
WILEY DAVIS LANDFILL
Dear Mr. Rahn:
Enclosed are the analytical results for sample(s) received by the laboratory on January 04, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Brittany Gibson
[e-mail]
Project Coordinator
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 1 of 42
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 2 of 42
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Lab ID Sample ID Matrix Date Collected Date Received
92281698001 WD-1 Water 12/31/15 16:30 01/04/16 15:40
92281698002 WD-2 Water 12/31/15 14:45 01/04/16 15:40
92281698003 WD-2d Water 12/31/15 14:30 01/04/16 15:40
92281698004 WD-3 Water 12/31/15 13:30 01/04/16 15:40
92281698005 WD-3d Water 12/31/15 13:00 01/04/16 15:40
92281698006 WD-4 Water 12/31/15 11:30 01/04/16 15:40
92281698007 WD-4d Water 12/31/15 11:15 01/04/16 15:40
92281698008 WD-7 Water 12/31/15 10:45 01/04/16 15:40
92281698009 WD-8 Water 12/31/15 15:30 01/04/16 15:40
92281698010 WD-9 Water 12/31/15 16:00 01/04/16 15:40
92281698012 UPGRADIENT Water 12/31/15 12:00 01/04/16 15:40
92281698013 SS- DOWNGRADIENT Water 12/31/15 15:00 01/04/16 15:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 3 of 42
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92281698001 WD-1 EPA 6010 7 PASI-ACDF
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CNB
92281698002 WD-2 EPA 6010 7 PASI-ACDF
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CNB
92281698003 WD-2d EPA 6010 7 PASI-ACDF
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CNB
92281698004 WD-3 EPA 6010 7 PASI-ACDF
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CNB
92281698005 WD-3d EPA 6010 7 PASI-ACDF
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CNB
92281698006 WD-4 EPA 6010 7 PASI-ACDF
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CNB
92281698007 WD-4d EPA 6010 7 PASI-ACDF
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CNB
92281698008 WD-7 EPA 6010 7 PASI-ACDF
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CNB
92281698009 WD-8 EPA 6010 7 PASI-ACDF
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CNB
92281698010 WD-9 EPA 6010 7 PASI-ACDF
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CNB
92281698012 UPGRADIENT EPA 6010 7 PASI-ACDF
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CNB
92281698013 SS- DOWNGRADIENT EPA 6010 7 PASI-ACDF
EPA 7470 1 PASI-ASH1
EPA 8260 65 PASI-CNB
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 4 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:WD-1 Lab ID:92281698001 Collected:12/31/15 16:30 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Arsenic ND mg/L 01/07/16 18:28 7440-38-201/06/16 13:550.010 0.0050 1
Barium 0.52 mg/L 01/07/16 18:28 7440-39-301/06/16 13:550.0050 0.0025 1
Cadmium ND mg/L 01/07/16 18:28 7440-43-901/06/16 13:550.0010 0.00050 1
Chromium 0.014 mg/L 01/07/16 18:28 7440-47-301/06/16 13:550.0050 0.0025 1
Lead ND mg/L 01/07/16 18:28 7439-92-101/06/16 13:550.0050 0.0025 1
Selenium ND mg/L 01/07/16 18:28 7782-49-201/06/16 13:550.010 0.0050 1
Silver ND mg/L 01/07/16 18:28 7440-22-401/06/16 13:550.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 01/11/16 16:35 7439-97-601/08/16 18:000.00020 0.00010 1
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 01/06/16 16:00 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 01/06/16 16:00 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 01/06/16 16:00 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 01/06/16 16:00 75-27-40.0010 0.00018 1
Bromoform ND mg/L 01/06/16 16:00 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 01/06/16 16:00 74-83-9 M10.0020 0.00029 1
n-Butylbenzene ND mg/L 01/06/16 16:00 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 01/06/16 16:00 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 01/06/16 16:00 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 01/06/16 16:00 56-23-50.0010 0.00025 1
Chlorobenzene ND mg/L 01/06/16 16:00 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 01/06/16 16:00 75-00-30.0010 0.00054 1
Chloroform ND mg/L 01/06/16 16:00 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 01/06/16 16:00 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 01/06/16 16:00 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 01/06/16 16:00 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 01/06/16 16:00 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 01/06/16 16:00 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 01/06/16 16:00 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 01/06/16 16:00 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 01/06/16 16:00 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 01/06/16 16:00 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 01/06/16 16:00 75-71-80.0010 0.00021 1
1,1-Dichloroethane ND mg/L 01/06/16 16:00 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 01/06/16 16:00 107-06-20.0010 0.00024 1
1,2-Dichloroethene (Total)ND mg/L 01/06/16 16:00 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 01/06/16 16:00 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 01/06/16 16:00 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 01/06/16 16:00 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 01/06/16 16:00 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 01/06/16 16:00 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 01/06/16 16:00 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 01/06/16 16:00 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 01/06/16 16:00 108-20-30.0010 0.00012 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 5 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:WD-1 Lab ID:92281698001 Collected:12/31/15 16:30 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Ethylbenzene ND mg/L 01/06/16 16:00 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 01/06/16 16:00 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 01/06/16 16:00 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 01/06/16 16:00 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 01/06/16 16:00 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 01/06/16 16:00 1634-04-40.0010 0.00021 1
Naphthalene ND mg/L 01/06/16 16:00 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 01/06/16 16:00 103-65-10.0010 0.00042 1
Styrene ND mg/L 01/06/16 16:00 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 01/06/16 16:00 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 01/06/16 16:00 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 01/06/16 16:00 127-18-40.0010 0.00046 1
Tetrahydrofuran ND mg/L 01/06/16 16:00 109-99-90.010 0.0031 1
Toluene ND mg/L 01/06/16 16:00 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 01/06/16 16:00 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 01/06/16 16:00 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 01/06/16 16:00 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 01/06/16 16:00 79-00-50.0010 0.00029 1
Trichloroethene ND mg/L 01/06/16 16:00 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 01/06/16 16:00 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 01/06/16 16:00 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 01/06/16 16:00 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 01/06/16 16:00 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 01/06/16 16:00 108-05-40.0020 0.00035 1
Vinyl chloride ND mg/L 01/06/16 16:00 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 01/06/16 16:00 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 01/06/16 16:00 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 01/06/16 16:00 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)112 %01/06/16 16:00 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %01/06/16 16:00 17060-07-070-130 1
Toluene-d8 (S)100 %01/06/16 16:00 2037-26-570-130 1
Sample:WD-2 Lab ID:92281698002 Collected:12/31/15 14:45 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Arsenic ND mg/L 01/07/16 18:31 7440-38-201/06/16 13:550.010 0.0050 1
Barium 0.59 mg/L 01/07/16 18:31 7440-39-301/06/16 13:550.0050 0.0025 1
Cadmium ND mg/L 01/07/16 18:31 7440-43-901/06/16 13:550.0010 0.00050 1
Chromium 0.0079 mg/L 01/07/16 18:31 7440-47-301/06/16 13:550.0050 0.0025 1
Lead ND mg/L 01/07/16 18:31 7439-92-101/06/16 13:550.0050 0.0025 1
Selenium ND mg/L 01/07/16 18:31 7782-49-201/06/16 13:550.010 0.0050 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 6 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:WD-2 Lab ID:92281698002 Collected:12/31/15 14:45 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Silver ND mg/L 01/07/16 18:31 7440-22-401/06/16 13:550.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 01/11/16 16:37 7439-97-601/08/16 18:000.00020 0.00010 1
Analytical Method: EPA 82608260 MSV Low Level
Benzene 0.0013 mg/L 01/06/16 16:17 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 01/06/16 16:17 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 01/06/16 16:17 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 01/06/16 16:17 75-27-40.0010 0.00018 1
Bromoform ND mg/L 01/06/16 16:17 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 01/06/16 16:17 74-83-90.0020 0.00029 1
n-Butylbenzene ND mg/L 01/06/16 16:17 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 01/06/16 16:17 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 01/06/16 16:17 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 01/06/16 16:17 56-23-50.0010 0.00025 1
Chlorobenzene ND mg/L 01/06/16 16:17 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 01/06/16 16:17 75-00-30.0010 0.00054 1
Chloroform ND mg/L 01/06/16 16:17 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 01/06/16 16:17 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 01/06/16 16:17 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 01/06/16 16:17 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 01/06/16 16:17 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 01/06/16 16:17 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 01/06/16 16:17 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 01/06/16 16:17 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 01/06/16 16:17 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 01/06/16 16:17 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 01/06/16 16:17 75-71-80.0010 0.00021 1
1,1-Dichloroethane ND mg/L 01/06/16 16:17 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 01/06/16 16:17 107-06-20.0010 0.00024 1
1,2-Dichloroethene (Total)ND mg/L 01/06/16 16:17 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 01/06/16 16:17 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 01/06/16 16:17 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 01/06/16 16:17 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 01/06/16 16:17 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 01/06/16 16:17 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 01/06/16 16:17 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 01/06/16 16:17 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 01/06/16 16:17 108-20-30.0010 0.00012 1
Ethylbenzene ND mg/L 01/06/16 16:17 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 01/06/16 16:17 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)0.0014 mg/L 01/06/16 16:17 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 01/06/16 16:17 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 01/06/16 16:17 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 01/06/16 16:17 1634-04-40.0010 0.00021 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 7 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:WD-2 Lab ID:92281698002 Collected:12/31/15 14:45 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Naphthalene 0.0016 mg/L 01/06/16 16:17 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 01/06/16 16:17 103-65-10.0010 0.00042 1
Styrene ND mg/L 01/06/16 16:17 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 01/06/16 16:17 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 01/06/16 16:17 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 01/06/16 16:17 127-18-40.0010 0.00046 1
Tetrahydrofuran 0.10 mg/L 01/06/16 16:17 109-99-90.010 0.0031 1
Toluene ND mg/L 01/06/16 16:17 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 01/06/16 16:17 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 01/06/16 16:17 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 01/06/16 16:17 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 01/06/16 16:17 79-00-50.0010 0.00029 1
Trichloroethene ND mg/L 01/06/16 16:17 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 01/06/16 16:17 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 01/06/16 16:17 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 01/06/16 16:17 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 01/06/16 16:17 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 01/06/16 16:17 108-05-40.0020 0.00035 1
Vinyl chloride ND mg/L 01/06/16 16:17 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 01/06/16 16:17 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 01/06/16 16:17 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 01/06/16 16:17 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)110 %01/06/16 16:17 460-00-470-130 1
1,2-Dichloroethane-d4 (S)103 %01/06/16 16:17 17060-07-070-130 1
Toluene-d8 (S)101 %01/06/16 16:17 2037-26-570-130 1
Sample:WD-2d Lab ID:92281698003 Collected:12/31/15 14:30 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Arsenic ND mg/L 01/07/16 18:34 7440-38-201/06/16 13:550.010 0.0050 1
Barium 0.27 mg/L 01/07/16 18:34 7440-39-301/06/16 13:550.0050 0.0025 1
Cadmium ND mg/L 01/07/16 18:34 7440-43-901/06/16 13:550.0010 0.00050 1
Chromium ND mg/L 01/07/16 18:34 7440-47-301/06/16 13:550.0050 0.0025 1
Lead ND mg/L 01/07/16 18:34 7439-92-101/06/16 13:550.0050 0.0025 1
Selenium ND mg/L 01/07/16 18:34 7782-49-201/06/16 13:550.010 0.0050 1
Silver ND mg/L 01/07/16 18:34 7440-22-401/06/16 13:550.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 01/11/16 16:39 7439-97-601/08/16 18:000.00020 0.00010 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 8 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:WD-2d Lab ID:92281698003 Collected:12/31/15 14:30 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 01/06/16 16:51 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 01/06/16 16:51 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 01/06/16 16:51 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 01/06/16 16:51 75-27-40.0010 0.00018 1
Bromoform ND mg/L 01/06/16 16:51 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 01/06/16 16:51 74-83-90.0020 0.00029 1
n-Butylbenzene ND mg/L 01/06/16 16:51 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 01/06/16 16:51 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 01/06/16 16:51 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 01/06/16 16:51 56-23-50.0010 0.00025 1
Chlorobenzene 0.0053 mg/L 01/06/16 16:51 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 01/06/16 16:51 75-00-30.0010 0.00054 1
Chloroform ND mg/L 01/06/16 16:51 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 01/06/16 16:51 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 01/06/16 16:51 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 01/06/16 16:51 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 01/06/16 16:51 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 01/06/16 16:51 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 01/06/16 16:51 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene 0.0012 mg/L 01/06/16 16:51 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 01/06/16 16:51 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 01/06/16 16:51 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 01/06/16 16:51 75-71-80.0010 0.00021 1
1,1-Dichloroethane ND mg/L 01/06/16 16:51 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 01/06/16 16:51 107-06-20.0010 0.00024 1
1,2-Dichloroethene (Total)ND mg/L 01/06/16 16:51 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 01/06/16 16:51 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 01/06/16 16:51 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 01/06/16 16:51 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 01/06/16 16:51 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 01/06/16 16:51 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 01/06/16 16:51 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 01/06/16 16:51 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 01/06/16 16:51 108-20-30.0010 0.00012 1
Ethylbenzene ND mg/L 01/06/16 16:51 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 01/06/16 16:51 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 01/06/16 16:51 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 01/06/16 16:51 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 01/06/16 16:51 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 01/06/16 16:51 1634-04-40.0010 0.00021 1
Naphthalene ND mg/L 01/06/16 16:51 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 01/06/16 16:51 103-65-10.0010 0.00042 1
Styrene ND mg/L 01/06/16 16:51 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 01/06/16 16:51 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 01/06/16 16:51 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 01/06/16 16:51 127-18-40.0010 0.00046 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 9 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:WD-2d Lab ID:92281698003 Collected:12/31/15 14:30 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Tetrahydrofuran 0.068 mg/L 01/06/16 16:51 109-99-90.010 0.0031 1
Toluene ND mg/L 01/06/16 16:51 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 01/06/16 16:51 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 01/06/16 16:51 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 01/06/16 16:51 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 01/06/16 16:51 79-00-50.0010 0.00029 1
Trichloroethene ND mg/L 01/06/16 16:51 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 01/06/16 16:51 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 01/06/16 16:51 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 01/06/16 16:51 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 01/06/16 16:51 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 01/06/16 16:51 108-05-40.0020 0.00035 1
Vinyl chloride ND mg/L 01/06/16 16:51 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 01/06/16 16:51 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 01/06/16 16:51 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 01/06/16 16:51 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)109 %01/06/16 16:51 460-00-470-130 1
1,2-Dichloroethane-d4 (S)103 %01/06/16 16:51 17060-07-070-130 1
Toluene-d8 (S)100 %01/06/16 16:51 2037-26-570-130 1
Sample:WD-3 Lab ID:92281698004 Collected:12/31/15 13:30 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Arsenic ND mg/L 01/07/16 18:38 7440-38-201/06/16 13:550.010 0.0050 1
Barium 0.80 mg/L 01/07/16 18:38 7440-39-301/06/16 13:550.0050 0.0025 1
Cadmium ND mg/L 01/07/16 18:38 7440-43-901/06/16 13:550.0010 0.00050 1
Chromium ND mg/L 01/07/16 18:38 7440-47-301/06/16 13:550.0050 0.0025 1
Lead ND mg/L 01/07/16 18:38 7439-92-101/06/16 13:550.0050 0.0025 1
Selenium ND mg/L 01/07/16 18:38 7782-49-201/06/16 13:550.010 0.0050 1
Silver ND mg/L 01/07/16 18:38 7440-22-401/06/16 13:550.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 01/11/16 16:42 7439-97-601/08/16 18:000.00020 0.00010 1
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 01/06/16 17:08 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 01/06/16 17:08 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 01/06/16 17:08 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 01/06/16 17:08 75-27-40.0010 0.00018 1
Bromoform ND mg/L 01/06/16 17:08 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 01/06/16 17:08 74-83-90.0020 0.00029 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 10 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:WD-3 Lab ID:92281698004 Collected:12/31/15 13:30 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
n-Butylbenzene ND mg/L 01/06/16 17:08 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 01/06/16 17:08 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 01/06/16 17:08 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 01/06/16 17:08 56-23-50.0010 0.00025 1
Chlorobenzene ND mg/L 01/06/16 17:08 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 01/06/16 17:08 75-00-30.0010 0.00054 1
Chloroform ND mg/L 01/06/16 17:08 67-66-30.0010 0.00014 1
Chloromethane 0.0015 mg/L 01/06/16 17:08 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 01/06/16 17:08 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 01/06/16 17:08 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 01/06/16 17:08 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 01/06/16 17:08 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 01/06/16 17:08 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 01/06/16 17:08 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 01/06/16 17:08 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 01/06/16 17:08 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 01/06/16 17:08 75-71-80.0010 0.00021 1
1,1-Dichloroethane ND mg/L 01/06/16 17:08 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 01/06/16 17:08 107-06-20.0010 0.00024 1
1,2-Dichloroethene (Total)ND mg/L 01/06/16 17:08 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 01/06/16 17:08 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 01/06/16 17:08 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 01/06/16 17:08 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 01/06/16 17:08 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 01/06/16 17:08 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 01/06/16 17:08 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 01/06/16 17:08 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 01/06/16 17:08 108-20-30.0010 0.00012 1
Ethylbenzene ND mg/L 01/06/16 17:08 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 01/06/16 17:08 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 01/06/16 17:08 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 01/06/16 17:08 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 01/06/16 17:08 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 01/06/16 17:08 1634-04-40.0010 0.00021 1
Naphthalene ND mg/L 01/06/16 17:08 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 01/06/16 17:08 103-65-10.0010 0.00042 1
Styrene ND mg/L 01/06/16 17:08 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 01/06/16 17:08 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 01/06/16 17:08 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 01/06/16 17:08 127-18-40.0010 0.00046 1
Tetrahydrofuran 0.023 mg/L 01/06/16 17:08 109-99-90.010 0.0031 1
Toluene ND mg/L 01/06/16 17:08 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 01/06/16 17:08 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 01/06/16 17:08 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 01/06/16 17:08 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 01/06/16 17:08 79-00-50.0010 0.00029 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 11 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:WD-3 Lab ID:92281698004 Collected:12/31/15 13:30 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Trichloroethene ND mg/L 01/06/16 17:08 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 01/06/16 17:08 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 01/06/16 17:08 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 01/06/16 17:08 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 01/06/16 17:08 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 01/06/16 17:08 108-05-40.0020 0.00035 1
Vinyl chloride ND mg/L 01/06/16 17:08 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 01/06/16 17:08 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 01/06/16 17:08 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 01/06/16 17:08 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)112 %01/06/16 17:08 460-00-470-130 1
1,2-Dichloroethane-d4 (S)103 %01/06/16 17:08 17060-07-070-130 1
Toluene-d8 (S)101 %01/06/16 17:08 2037-26-570-130 1
Sample:WD-3d Lab ID:92281698005 Collected:12/31/15 13:00 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Arsenic ND mg/L 01/07/16 18:41 7440-38-201/06/16 13:550.010 0.0050 1
Barium 0.068 mg/L 01/07/16 18:41 7440-39-301/06/16 13:550.0050 0.0025 1
Cadmium ND mg/L 01/07/16 18:41 7440-43-901/06/16 13:550.0010 0.00050 1
Chromium 0.0063 mg/L 01/07/16 18:41 7440-47-301/06/16 13:550.0050 0.0025 1
Lead ND mg/L 01/07/16 18:41 7439-92-101/06/16 13:550.0050 0.0025 1
Selenium ND mg/L 01/07/16 18:41 7782-49-201/06/16 13:550.010 0.0050 1
Silver ND mg/L 01/07/16 18:41 7440-22-401/06/16 13:550.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 01/11/16 16:44 7439-97-601/08/16 18:000.00020 0.00010 1
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 01/06/16 17:25 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 01/06/16 17:25 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 01/06/16 17:25 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 01/06/16 17:25 75-27-40.0010 0.00018 1
Bromoform ND mg/L 01/06/16 17:25 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 01/06/16 17:25 74-83-90.0020 0.00029 1
n-Butylbenzene ND mg/L 01/06/16 17:25 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 01/06/16 17:25 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 01/06/16 17:25 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 01/06/16 17:25 56-23-50.0010 0.00025 1
Chlorobenzene ND mg/L 01/06/16 17:25 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 01/06/16 17:25 75-00-30.0010 0.00054 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 12 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:WD-3d Lab ID:92281698005 Collected:12/31/15 13:00 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Chloroform ND mg/L 01/06/16 17:25 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 01/06/16 17:25 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 01/06/16 17:25 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 01/06/16 17:25 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 01/06/16 17:25 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 01/06/16 17:25 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 01/06/16 17:25 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 01/06/16 17:25 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 01/06/16 17:25 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 01/06/16 17:25 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 01/06/16 17:25 75-71-80.0010 0.00021 1
1,1-Dichloroethane ND mg/L 01/06/16 17:25 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 01/06/16 17:25 107-06-20.0010 0.00024 1
1,2-Dichloroethene (Total)ND mg/L 01/06/16 17:25 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 01/06/16 17:25 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 01/06/16 17:25 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 01/06/16 17:25 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 01/06/16 17:25 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 01/06/16 17:25 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 01/06/16 17:25 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 01/06/16 17:25 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 01/06/16 17:25 108-20-30.0010 0.00012 1
Ethylbenzene ND mg/L 01/06/16 17:25 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 01/06/16 17:25 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 01/06/16 17:25 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 01/06/16 17:25 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 01/06/16 17:25 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 01/06/16 17:25 1634-04-40.0010 0.00021 1
Naphthalene ND mg/L 01/06/16 17:25 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 01/06/16 17:25 103-65-10.0010 0.00042 1
Styrene ND mg/L 01/06/16 17:25 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 01/06/16 17:25 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 01/06/16 17:25 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 01/06/16 17:25 127-18-40.0010 0.00046 1
Tetrahydrofuran ND mg/L 01/06/16 17:25 109-99-90.010 0.0031 1
Toluene ND mg/L 01/06/16 17:25 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 01/06/16 17:25 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 01/06/16 17:25 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 01/06/16 17:25 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 01/06/16 17:25 79-00-50.0010 0.00029 1
Trichloroethene ND mg/L 01/06/16 17:25 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 01/06/16 17:25 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 01/06/16 17:25 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 01/06/16 17:25 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 01/06/16 17:25 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 01/06/16 17:25 108-05-40.0020 0.00035 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 13 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:WD-3d Lab ID:92281698005 Collected:12/31/15 13:00 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Vinyl chloride ND mg/L 01/06/16 17:25 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 01/06/16 17:25 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 01/06/16 17:25 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 01/06/16 17:25 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)113 %01/06/16 17:25 460-00-470-130 1
1,2-Dichloroethane-d4 (S)103 %01/06/16 17:25 17060-07-070-130 1
Toluene-d8 (S)101 %01/06/16 17:25 2037-26-570-130 1
Sample:WD-4 Lab ID:92281698006 Collected:12/31/15 11:30 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Arsenic ND mg/L 01/07/16 18:53 7440-38-201/06/16 13:550.010 0.0050 1
Barium 0.79 mg/L 01/07/16 18:53 7440-39-301/06/16 13:550.0050 0.0025 1
Cadmium ND mg/L 01/07/16 18:53 7440-43-901/06/16 13:550.0010 0.00050 1
Chromium 0.0072 mg/L 01/07/16 18:53 7440-47-301/06/16 13:550.0050 0.0025 1
Lead ND mg/L 01/07/16 18:53 7439-92-101/06/16 13:550.0050 0.0025 1
Selenium ND mg/L 01/07/16 18:53 7782-49-201/06/16 13:550.010 0.0050 1
Silver ND mg/L 01/07/16 18:53 7440-22-401/06/16 13:550.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 01/11/16 16:46 7439-97-601/08/16 18:000.00020 0.00010 1
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 01/06/16 17:42 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 01/06/16 17:42 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 01/06/16 17:42 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 01/06/16 17:42 75-27-40.0010 0.00018 1
Bromoform ND mg/L 01/06/16 17:42 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 01/06/16 17:42 74-83-90.0020 0.00029 1
n-Butylbenzene ND mg/L 01/06/16 17:42 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 01/06/16 17:42 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 01/06/16 17:42 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 01/06/16 17:42 56-23-50.0010 0.00025 1
Chlorobenzene 0.0015 mg/L 01/06/16 17:42 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 01/06/16 17:42 75-00-30.0010 0.00054 1
Chloroform ND mg/L 01/06/16 17:42 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 01/06/16 17:42 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 01/06/16 17:42 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 01/06/16 17:42 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 01/06/16 17:42 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 01/06/16 17:42 106-93-40.0010 0.00027 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 14 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:WD-4 Lab ID:92281698006 Collected:12/31/15 11:30 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Dibromomethane ND mg/L 01/06/16 17:42 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 01/06/16 17:42 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 01/06/16 17:42 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 01/06/16 17:42 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 01/06/16 17:42 75-71-80.0010 0.00021 1
1,1-Dichloroethane ND mg/L 01/06/16 17:42 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 01/06/16 17:42 107-06-20.0010 0.00024 1
1,2-Dichloroethene (Total)ND mg/L 01/06/16 17:42 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 01/06/16 17:42 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 01/06/16 17:42 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 01/06/16 17:42 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 01/06/16 17:42 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 01/06/16 17:42 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 01/06/16 17:42 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 01/06/16 17:42 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 01/06/16 17:42 108-20-30.0010 0.00012 1
Ethylbenzene ND mg/L 01/06/16 17:42 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 01/06/16 17:42 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 01/06/16 17:42 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 01/06/16 17:42 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 01/06/16 17:42 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 01/06/16 17:42 1634-04-40.0010 0.00021 1
Naphthalene ND mg/L 01/06/16 17:42 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 01/06/16 17:42 103-65-10.0010 0.00042 1
Styrene ND mg/L 01/06/16 17:42 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 01/06/16 17:42 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 01/06/16 17:42 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 01/06/16 17:42 127-18-40.0010 0.00046 1
Tetrahydrofuran 0.015 mg/L 01/06/16 17:42 109-99-90.010 0.0031 1
Toluene ND mg/L 01/06/16 17:42 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 01/06/16 17:42 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 01/06/16 17:42 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 01/06/16 17:42 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 01/06/16 17:42 79-00-50.0010 0.00029 1
Trichloroethene ND mg/L 01/06/16 17:42 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 01/06/16 17:42 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 01/06/16 17:42 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 01/06/16 17:42 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 01/06/16 17:42 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 01/06/16 17:42 108-05-40.0020 0.00035 1
Vinyl chloride ND mg/L 01/06/16 17:42 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 01/06/16 17:42 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 01/06/16 17:42 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 01/06/16 17:42 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)110 %01/06/16 17:42 460-00-470-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 15 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:WD-4 Lab ID:92281698006 Collected:12/31/15 11:30 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Surrogates
1,2-Dichloroethane-d4 (S)104 %01/06/16 17:42 17060-07-070-130 1
Toluene-d8 (S)100 %01/06/16 17:42 2037-26-570-130 1
Sample:WD-4d Lab ID:92281698007 Collected:12/31/15 11:15 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Arsenic ND mg/L 01/07/16 18:57 7440-38-201/06/16 13:550.010 0.0050 1
Barium 0.025 mg/L 01/07/16 18:57 7440-39-301/06/16 13:550.0050 0.0025 1
Cadmium ND mg/L 01/07/16 18:57 7440-43-901/06/16 13:550.0010 0.00050 1
Chromium ND mg/L 01/07/16 18:57 7440-47-301/06/16 13:550.0050 0.0025 1
Lead ND mg/L 01/07/16 18:57 7439-92-101/06/16 13:550.0050 0.0025 1
Selenium ND mg/L 01/07/16 18:57 7782-49-201/06/16 13:550.010 0.0050 1
Silver ND mg/L 01/07/16 18:57 7440-22-401/06/16 13:550.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 01/14/16 11:15 7439-97-601/08/16 21:300.00020 0.00010 1
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 01/06/16 17:59 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 01/06/16 17:59 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 01/06/16 17:59 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 01/06/16 17:59 75-27-40.0010 0.00018 1
Bromoform ND mg/L 01/06/16 17:59 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 01/06/16 17:59 74-83-90.0020 0.00029 1
n-Butylbenzene ND mg/L 01/06/16 17:59 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 01/06/16 17:59 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 01/06/16 17:59 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 01/06/16 17:59 56-23-50.0010 0.00025 1
Chlorobenzene ND mg/L 01/06/16 17:59 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 01/06/16 17:59 75-00-30.0010 0.00054 1
Chloroform ND mg/L 01/06/16 17:59 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 01/06/16 17:59 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 01/06/16 17:59 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 01/06/16 17:59 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 01/06/16 17:59 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 01/06/16 17:59 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 01/06/16 17:59 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 01/06/16 17:59 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 01/06/16 17:59 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 01/06/16 17:59 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 01/06/16 17:59 75-71-80.0010 0.00021 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 16 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:WD-4d Lab ID:92281698007 Collected:12/31/15 11:15 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
1,1-Dichloroethane ND mg/L 01/06/16 17:59 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 01/06/16 17:59 107-06-20.0010 0.00024 1
1,2-Dichloroethene (Total)ND mg/L 01/06/16 17:59 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 01/06/16 17:59 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 01/06/16 17:59 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 01/06/16 17:59 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 01/06/16 17:59 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 01/06/16 17:59 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 01/06/16 17:59 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 01/06/16 17:59 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 01/06/16 17:59 108-20-30.0010 0.00012 1
Ethylbenzene ND mg/L 01/06/16 17:59 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 01/06/16 17:59 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 01/06/16 17:59 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 01/06/16 17:59 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 01/06/16 17:59 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 01/06/16 17:59 1634-04-40.0010 0.00021 1
Naphthalene ND mg/L 01/06/16 17:59 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 01/06/16 17:59 103-65-10.0010 0.00042 1
Styrene ND mg/L 01/06/16 17:59 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 01/06/16 17:59 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 01/06/16 17:59 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 01/06/16 17:59 127-18-40.0010 0.00046 1
Tetrahydrofuran ND mg/L 01/06/16 17:59 109-99-90.010 0.0031 1
Toluene ND mg/L 01/06/16 17:59 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 01/06/16 17:59 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 01/06/16 17:59 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 01/06/16 17:59 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 01/06/16 17:59 79-00-50.0010 0.00029 1
Trichloroethene ND mg/L 01/06/16 17:59 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 01/06/16 17:59 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 01/06/16 17:59 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 01/06/16 17:59 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 01/06/16 17:59 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 01/06/16 17:59 108-05-40.0020 0.00035 1
Vinyl chloride ND mg/L 01/06/16 17:59 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 01/06/16 17:59 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 01/06/16 17:59 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 01/06/16 17:59 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)112 %01/06/16 17:59 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %01/06/16 17:59 17060-07-070-130 1
Toluene-d8 (S)103 %01/06/16 17:59 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 17 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:WD-7 Lab ID:92281698008 Collected:12/31/15 10:45 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Arsenic ND mg/L 01/07/16 19:00 7440-38-201/06/16 13:550.010 0.0050 1
Barium 0.16 mg/L 01/07/16 19:00 7440-39-301/06/16 13:550.0050 0.0025 1
Cadmium ND mg/L 01/07/16 19:00 7440-43-901/06/16 13:550.0010 0.00050 1
Chromium 0.020 mg/L 01/07/16 19:00 7440-47-301/06/16 13:550.0050 0.0025 1
Lead ND mg/L 01/07/16 19:00 7439-92-101/06/16 13:550.0050 0.0025 1
Selenium ND mg/L 01/07/16 19:00 7782-49-201/06/16 13:550.010 0.0050 1
Silver ND mg/L 01/07/16 19:00 7440-22-401/06/16 13:550.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 01/14/16 11:22 7439-97-601/08/16 21:300.00020 0.00010 1
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 01/06/16 18:16 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 01/06/16 18:16 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 01/06/16 18:16 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 01/06/16 18:16 75-27-40.0010 0.00018 1
Bromoform ND mg/L 01/06/16 18:16 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 01/06/16 18:16 74-83-90.0020 0.00029 1
n-Butylbenzene ND mg/L 01/06/16 18:16 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 01/06/16 18:16 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 01/06/16 18:16 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 01/06/16 18:16 56-23-50.0010 0.00025 1
Chlorobenzene ND mg/L 01/06/16 18:16 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 01/06/16 18:16 75-00-30.0010 0.00054 1
Chloroform ND mg/L 01/06/16 18:16 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 01/06/16 18:16 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 01/06/16 18:16 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 01/06/16 18:16 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 01/06/16 18:16 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 01/06/16 18:16 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 01/06/16 18:16 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 01/06/16 18:16 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 01/06/16 18:16 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 01/06/16 18:16 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 01/06/16 18:16 75-71-80.0010 0.00021 1
1,1-Dichloroethane ND mg/L 01/06/16 18:16 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 01/06/16 18:16 107-06-20.0010 0.00024 1
1,2-Dichloroethene (Total)ND mg/L 01/06/16 18:16 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 01/06/16 18:16 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 01/06/16 18:16 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 01/06/16 18:16 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 01/06/16 18:16 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 01/06/16 18:16 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 01/06/16 18:16 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 01/06/16 18:16 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 01/06/16 18:16 108-20-30.0010 0.00012 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 18 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:WD-7 Lab ID:92281698008 Collected:12/31/15 10:45 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Ethylbenzene ND mg/L 01/06/16 18:16 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 01/06/16 18:16 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 01/06/16 18:16 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 01/06/16 18:16 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 01/06/16 18:16 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 01/06/16 18:16 1634-04-40.0010 0.00021 1
Naphthalene ND mg/L 01/06/16 18:16 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 01/06/16 18:16 103-65-10.0010 0.00042 1
Styrene ND mg/L 01/06/16 18:16 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 01/06/16 18:16 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 01/06/16 18:16 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 01/06/16 18:16 127-18-40.0010 0.00046 1
Tetrahydrofuran ND mg/L 01/06/16 18:16 109-99-90.010 0.0031 1
Toluene ND mg/L 01/06/16 18:16 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 01/06/16 18:16 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 01/06/16 18:16 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 01/06/16 18:16 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 01/06/16 18:16 79-00-50.0010 0.00029 1
Trichloroethene ND mg/L 01/06/16 18:16 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 01/06/16 18:16 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 01/06/16 18:16 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 01/06/16 18:16 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 01/06/16 18:16 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 01/06/16 18:16 108-05-40.0020 0.00035 1
Vinyl chloride ND mg/L 01/06/16 18:16 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 01/06/16 18:16 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 01/06/16 18:16 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 01/06/16 18:16 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)107 %01/06/16 18:16 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %01/06/16 18:16 17060-07-070-130 1
Toluene-d8 (S)101 %01/06/16 18:16 2037-26-570-130 1
Sample:WD-8 Lab ID:92281698009 Collected:12/31/15 15:30 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Arsenic ND mg/L 01/07/16 19:03 7440-38-201/06/16 13:550.010 0.0050 1
Barium 0.84 mg/L 01/07/16 19:03 7440-39-301/06/16 13:550.0050 0.0025 1
Cadmium ND mg/L 01/07/16 19:03 7440-43-901/06/16 13:550.0010 0.00050 1
Chromium 0.013 mg/L 01/07/16 19:03 7440-47-301/06/16 13:550.0050 0.0025 1
Lead ND mg/L 01/07/16 19:03 7439-92-101/06/16 13:550.0050 0.0025 1
Selenium ND mg/L 01/07/16 19:03 7782-49-201/06/16 13:550.010 0.0050 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 19 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:WD-8 Lab ID:92281698009 Collected:12/31/15 15:30 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Silver ND mg/L 01/07/16 19:03 7440-22-401/06/16 13:550.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury 0.00029 mg/L 01/14/16 11:24 7439-97-601/08/16 21:300.00020 0.00010 1
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 01/06/16 18:34 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 01/06/16 18:34 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 01/06/16 18:34 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 01/06/16 18:34 75-27-40.0010 0.00018 1
Bromoform ND mg/L 01/06/16 18:34 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 01/06/16 18:34 74-83-90.0020 0.00029 1
n-Butylbenzene ND mg/L 01/06/16 18:34 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 01/06/16 18:34 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 01/06/16 18:34 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 01/06/16 18:34 56-23-50.0010 0.00025 1
Chlorobenzene ND mg/L 01/06/16 18:34 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 01/06/16 18:34 75-00-30.0010 0.00054 1
Chloroform ND mg/L 01/06/16 18:34 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 01/06/16 18:34 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 01/06/16 18:34 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 01/06/16 18:34 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 01/06/16 18:34 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 01/06/16 18:34 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 01/06/16 18:34 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 01/06/16 18:34 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 01/06/16 18:34 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 01/06/16 18:34 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 01/06/16 18:34 75-71-80.0010 0.00021 1
1,1-Dichloroethane ND mg/L 01/06/16 18:34 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 01/06/16 18:34 107-06-20.0010 0.00024 1
1,2-Dichloroethene (Total)ND mg/L 01/06/16 18:34 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 01/06/16 18:34 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 01/06/16 18:34 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 01/06/16 18:34 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 01/06/16 18:34 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 01/06/16 18:34 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 01/06/16 18:34 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 01/06/16 18:34 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 01/06/16 18:34 108-20-30.0010 0.00012 1
Ethylbenzene ND mg/L 01/06/16 18:34 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 01/06/16 18:34 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 01/06/16 18:34 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 01/06/16 18:34 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 01/06/16 18:34 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 01/06/16 18:34 1634-04-40.0010 0.00021 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 20 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:WD-8 Lab ID:92281698009 Collected:12/31/15 15:30 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Naphthalene ND mg/L 01/06/16 18:34 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 01/06/16 18:34 103-65-10.0010 0.00042 1
Styrene ND mg/L 01/06/16 18:34 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 01/06/16 18:34 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 01/06/16 18:34 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 01/06/16 18:34 127-18-40.0010 0.00046 1
Tetrahydrofuran ND mg/L 01/06/16 18:34 109-99-90.010 0.0031 1
Toluene ND mg/L 01/06/16 18:34 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 01/06/16 18:34 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 01/06/16 18:34 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 01/06/16 18:34 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 01/06/16 18:34 79-00-50.0010 0.00029 1
Trichloroethene ND mg/L 01/06/16 18:34 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 01/06/16 18:34 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 01/06/16 18:34 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 01/06/16 18:34 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 01/06/16 18:34 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 01/06/16 18:34 108-05-40.0020 0.00035 1
Vinyl chloride ND mg/L 01/06/16 18:34 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 01/06/16 18:34 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 01/06/16 18:34 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 01/06/16 18:34 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)109 %01/06/16 18:34 460-00-470-130 1
1,2-Dichloroethane-d4 (S)103 %01/06/16 18:34 17060-07-070-130 1
Toluene-d8 (S)102 %01/06/16 18:34 2037-26-570-130 1
Sample:WD-9 Lab ID:92281698010 Collected:12/31/15 16:00 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Arsenic ND mg/L 01/07/16 19:06 7440-38-201/06/16 13:550.010 0.0050 1
Barium 0.26 mg/L 01/07/16 19:06 7440-39-301/06/16 13:550.0050 0.0025 1
Cadmium 0.0028 mg/L 01/07/16 19:06 7440-43-901/06/16 13:550.0010 0.00050 1
Chromium 0.0066 mg/L 01/07/16 19:06 7440-47-301/06/16 13:550.0050 0.0025 1
Lead ND mg/L 01/07/16 19:06 7439-92-101/06/16 13:550.0050 0.0025 1
Selenium ND mg/L 01/07/16 19:06 7782-49-201/06/16 13:550.010 0.0050 1
Silver ND mg/L 01/07/16 19:06 7440-22-401/06/16 13:550.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 01/14/16 11:27 7439-97-601/08/16 21:300.00020 0.00010 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 21 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:WD-9 Lab ID:92281698010 Collected:12/31/15 16:00 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 01/06/16 18:51 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 01/06/16 18:51 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 01/06/16 18:51 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 01/06/16 18:51 75-27-40.0010 0.00018 1
Bromoform ND mg/L 01/06/16 18:51 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 01/06/16 18:51 74-83-90.0020 0.00029 1
n-Butylbenzene ND mg/L 01/06/16 18:51 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 01/06/16 18:51 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 01/06/16 18:51 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 01/06/16 18:51 56-23-50.0010 0.00025 1
Chlorobenzene ND mg/L 01/06/16 18:51 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 01/06/16 18:51 75-00-30.0010 0.00054 1
Chloroform ND mg/L 01/06/16 18:51 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 01/06/16 18:51 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 01/06/16 18:51 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 01/06/16 18:51 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 01/06/16 18:51 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 01/06/16 18:51 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 01/06/16 18:51 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 01/06/16 18:51 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 01/06/16 18:51 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 01/06/16 18:51 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 01/06/16 18:51 75-71-80.0010 0.00021 1
1,1-Dichloroethane ND mg/L 01/06/16 18:51 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 01/06/16 18:51 107-06-20.0010 0.00024 1
1,2-Dichloroethene (Total)ND mg/L 01/06/16 18:51 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 01/06/16 18:51 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 01/06/16 18:51 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 01/06/16 18:51 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 01/06/16 18:51 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 01/06/16 18:51 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 01/06/16 18:51 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 01/06/16 18:51 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 01/06/16 18:51 108-20-30.0010 0.00012 1
Ethylbenzene ND mg/L 01/06/16 18:51 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 01/06/16 18:51 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 01/06/16 18:51 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 01/06/16 18:51 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 01/06/16 18:51 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 01/06/16 18:51 1634-04-40.0010 0.00021 1
Naphthalene ND mg/L 01/06/16 18:51 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 01/06/16 18:51 103-65-10.0010 0.00042 1
Styrene ND mg/L 01/06/16 18:51 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 01/06/16 18:51 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 01/06/16 18:51 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 01/06/16 18:51 127-18-40.0010 0.00046 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 22 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:WD-9 Lab ID:92281698010 Collected:12/31/15 16:00 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Tetrahydrofuran ND mg/L 01/06/16 18:51 109-99-90.010 0.0031 1
Toluene ND mg/L 01/06/16 18:51 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 01/06/16 18:51 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 01/06/16 18:51 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 01/06/16 18:51 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 01/06/16 18:51 79-00-50.0010 0.00029 1
Trichloroethene ND mg/L 01/06/16 18:51 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 01/06/16 18:51 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 01/06/16 18:51 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 01/06/16 18:51 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 01/06/16 18:51 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 01/06/16 18:51 108-05-40.0020 0.00035 1
Vinyl chloride ND mg/L 01/06/16 18:51 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 01/06/16 18:51 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 01/06/16 18:51 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 01/06/16 18:51 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)112 %01/06/16 18:51 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %01/06/16 18:51 17060-07-070-130 1
Toluene-d8 (S)103 %01/06/16 18:51 2037-26-570-130 1
Sample:UPGRADIENT Lab ID:92281698012 Collected:12/31/15 12:00 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Arsenic ND mg/L 01/07/16 19:09 7440-38-201/06/16 13:550.010 0.0050 1
Barium 0.15 mg/L 01/07/16 19:09 7440-39-301/06/16 13:550.0050 0.0025 1
Cadmium ND mg/L 01/07/16 19:09 7440-43-901/06/16 13:550.0010 0.00050 1
Chromium ND mg/L 01/07/16 19:09 7440-47-301/06/16 13:550.0050 0.0025 1
Lead ND mg/L 01/07/16 19:09 7439-92-101/06/16 13:550.0050 0.0025 1
Selenium ND mg/L 01/07/16 19:09 7782-49-201/06/16 13:550.010 0.0050 1
Silver ND mg/L 01/07/16 19:09 7440-22-401/06/16 13:550.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 01/14/16 11:29 7439-97-601/08/16 21:300.00020 0.00010 1
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 01/06/16 19:08 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 01/06/16 19:08 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 01/06/16 19:08 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 01/06/16 19:08 75-27-40.0010 0.00018 1
Bromoform ND mg/L 01/06/16 19:08 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 01/06/16 19:08 74-83-90.0020 0.00029 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 23 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:UPGRADIENT Lab ID:92281698012 Collected:12/31/15 12:00 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
n-Butylbenzene ND mg/L 01/06/16 19:08 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 01/06/16 19:08 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 01/06/16 19:08 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 01/06/16 19:08 56-23-50.0010 0.00025 1
Chlorobenzene ND mg/L 01/06/16 19:08 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 01/06/16 19:08 75-00-30.0010 0.00054 1
Chloroform ND mg/L 01/06/16 19:08 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 01/06/16 19:08 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 01/06/16 19:08 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 01/06/16 19:08 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 01/06/16 19:08 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 01/06/16 19:08 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 01/06/16 19:08 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 01/06/16 19:08 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 01/06/16 19:08 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 01/06/16 19:08 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 01/06/16 19:08 75-71-80.0010 0.00021 1
1,1-Dichloroethane ND mg/L 01/06/16 19:08 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 01/06/16 19:08 107-06-20.0010 0.00024 1
1,2-Dichloroethene (Total)ND mg/L 01/06/16 19:08 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 01/06/16 19:08 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 01/06/16 19:08 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 01/06/16 19:08 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 01/06/16 19:08 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 01/06/16 19:08 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 01/06/16 19:08 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 01/06/16 19:08 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 01/06/16 19:08 108-20-30.0010 0.00012 1
Ethylbenzene ND mg/L 01/06/16 19:08 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 01/06/16 19:08 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 01/06/16 19:08 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 01/06/16 19:08 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 01/06/16 19:08 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 01/06/16 19:08 1634-04-40.0010 0.00021 1
Naphthalene ND mg/L 01/06/16 19:08 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 01/06/16 19:08 103-65-10.0010 0.00042 1
Styrene ND mg/L 01/06/16 19:08 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 01/06/16 19:08 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 01/06/16 19:08 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 01/06/16 19:08 127-18-40.0010 0.00046 1
Tetrahydrofuran ND mg/L 01/06/16 19:08 109-99-90.010 0.0031 1
Toluene ND mg/L 01/06/16 19:08 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 01/06/16 19:08 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 01/06/16 19:08 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 01/06/16 19:08 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 01/06/16 19:08 79-00-50.0010 0.00029 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 24 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:UPGRADIENT Lab ID:92281698012 Collected:12/31/15 12:00 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Trichloroethene ND mg/L 01/06/16 19:08 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 01/06/16 19:08 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 01/06/16 19:08 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 01/06/16 19:08 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 01/06/16 19:08 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 01/06/16 19:08 108-05-40.0020 0.00035 1
Vinyl chloride ND mg/L 01/06/16 19:08 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 01/06/16 19:08 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 01/06/16 19:08 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 01/06/16 19:08 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)110 %01/06/16 19:08 460-00-470-130 1
1,2-Dichloroethane-d4 (S)105 %01/06/16 19:08 17060-07-070-130 1
Toluene-d8 (S)100 %01/06/16 19:08 2037-26-570-130 1
Sample:SS- DOWNGRADIENT Lab ID:92281698013 Collected:12/31/15 15:00 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Arsenic ND mg/L 01/07/16 19:12 7440-38-201/06/16 13:550.010 0.0050 1
Barium 0.13 mg/L 01/07/16 19:12 7440-39-301/06/16 13:550.0050 0.0025 1
Cadmium ND mg/L 01/07/16 19:12 7440-43-901/06/16 13:550.0010 0.00050 1
Chromium ND mg/L 01/07/16 19:12 7440-47-301/06/16 13:550.0050 0.0025 1
Lead ND mg/L 01/07/16 19:12 7439-92-101/06/16 13:550.0050 0.0025 1
Selenium ND mg/L 01/07/16 19:12 7782-49-201/06/16 13:550.010 0.0050 1
Silver ND mg/L 01/07/16 19:12 7440-22-401/06/16 13:550.0050 0.0025 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND mg/L 01/14/16 11:31 7439-97-601/08/16 21:300.00020 0.00010 1
Analytical Method: EPA 82608260 MSV Low Level
Benzene ND mg/L 01/06/16 19:25 71-43-20.0010 0.00025 1
Bromobenzene ND mg/L 01/06/16 19:25 108-86-10.0010 0.00030 1
Bromochloromethane ND mg/L 01/06/16 19:25 74-97-50.0010 0.00017 1
Bromodichloromethane ND mg/L 01/06/16 19:25 75-27-40.0010 0.00018 1
Bromoform ND mg/L 01/06/16 19:25 75-25-20.0010 0.00026 1
Bromomethane ND mg/L 01/06/16 19:25 74-83-90.0020 0.00029 1
n-Butylbenzene ND mg/L 01/06/16 19:25 104-51-80.0010 0.00041 1
sec-Butylbenzene ND mg/L 01/06/16 19:25 135-98-80.0010 0.00038 1
tert-Butylbenzene ND mg/L 01/06/16 19:25 98-06-60.0010 0.00040 1
Carbon tetrachloride ND mg/L 01/06/16 19:25 56-23-50.0010 0.00025 1
Chlorobenzene ND mg/L 01/06/16 19:25 108-90-70.0010 0.00023 1
Chloroethane ND mg/L 01/06/16 19:25 75-00-30.0010 0.00054 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 25 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:SS- DOWNGRADIENT Lab ID:92281698013 Collected:12/31/15 15:00 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Chloroform ND mg/L 01/06/16 19:25 67-66-30.0010 0.00014 1
Chloromethane ND mg/L 01/06/16 19:25 74-87-30.0010 0.00011 1
2-Chlorotoluene ND mg/L 01/06/16 19:25 95-49-80.0010 0.00035 1
4-Chlorotoluene ND mg/L 01/06/16 19:25 106-43-40.0010 0.00031 1
Dibromochloromethane ND mg/L 01/06/16 19:25 124-48-10.0010 0.00021 1
1,2-Dibromoethane (EDB)ND mg/L 01/06/16 19:25 106-93-40.0010 0.00027 1
Dibromomethane ND mg/L 01/06/16 19:25 74-95-30.0010 0.00021 1
1,2-Dichlorobenzene ND mg/L 01/06/16 19:25 95-50-10.0010 0.00030 1
1,3-Dichlorobenzene ND mg/L 01/06/16 19:25 541-73-10.0010 0.00024 1
1,4-Dichlorobenzene ND mg/L 01/06/16 19:25 106-46-70.0010 0.00033 1
Dichlorodifluoromethane ND mg/L 01/06/16 19:25 75-71-80.0010 0.00021 1
1,1-Dichloroethane ND mg/L 01/06/16 19:25 75-34-30.0010 0.00032 1
1,2-Dichloroethane ND mg/L 01/06/16 19:25 107-06-20.0010 0.00024 1
1,2-Dichloroethene (Total)ND mg/L 01/06/16 19:25 540-59-00.0010 0.00049 1
1,1-Dichloroethene ND mg/L 01/06/16 19:25 75-35-40.0010 0.00056 1
cis-1,2-Dichloroethene ND mg/L 01/06/16 19:25 156-59-20.0010 0.00019 1
trans-1,2-Dichloroethene ND mg/L 01/06/16 19:25 156-60-50.0010 0.00049 1
1,2-Dichloropropane ND mg/L 01/06/16 19:25 78-87-50.0010 0.00027 1
1,3-Dichloropropane ND mg/L 01/06/16 19:25 142-28-90.0010 0.00028 1
2,2-Dichloropropane ND mg/L 01/06/16 19:25 594-20-70.0010 0.00013 1
1,1-Dichloropropene ND mg/L 01/06/16 19:25 563-58-60.0010 0.00049 1
Diisopropyl ether ND mg/L 01/06/16 19:25 108-20-30.0010 0.00012 1
Ethylbenzene ND mg/L 01/06/16 19:25 100-41-40.0010 0.00030 1
Hexachloro-1,3-butadiene ND mg/L 01/06/16 19:25 87-68-30.0010 0.00071 1
Isopropylbenzene (Cumene)ND mg/L 01/06/16 19:25 98-82-80.0010 0.00040 1
p-Isopropyltoluene ND mg/L 01/06/16 19:25 99-87-60.0010 0.00031 1
Methylene Chloride ND mg/L 01/06/16 19:25 75-09-20.0020 0.00097 1
Methyl-tert-butyl ether ND mg/L 01/06/16 19:25 1634-04-40.0010 0.00021 1
Naphthalene ND mg/L 01/06/16 19:25 91-20-30.0010 0.00024 1
n-Propylbenzene ND mg/L 01/06/16 19:25 103-65-10.0010 0.00042 1
Styrene ND mg/L 01/06/16 19:25 100-42-50.0010 0.00026 1
1,1,1,2-Tetrachloroethane ND mg/L 01/06/16 19:25 630-20-60.0010 0.00033 1
1,1,2,2-Tetrachloroethane ND mg/L 01/06/16 19:25 79-34-50.0010 0.00040 1
Tetrachloroethene ND mg/L 01/06/16 19:25 127-18-40.0010 0.00046 1
Tetrahydrofuran ND mg/L 01/06/16 19:25 109-99-90.010 0.0031 1
Toluene ND mg/L 01/06/16 19:25 108-88-30.0010 0.00026 1
1,2,3-Trichlorobenzene ND mg/L 01/06/16 19:25 87-61-60.0010 0.00033 1
1,2,4-Trichlorobenzene ND mg/L 01/06/16 19:25 120-82-10.0010 0.00035 1
1,1,1-Trichloroethane ND mg/L 01/06/16 19:25 71-55-60.0010 0.00048 1
1,1,2-Trichloroethane ND mg/L 01/06/16 19:25 79-00-50.0010 0.00029 1
Trichloroethene ND mg/L 01/06/16 19:25 79-01-60.0010 0.00047 1
Trichlorofluoromethane ND mg/L 01/06/16 19:25 75-69-40.0010 0.00020 1
1,2,3-Trichloropropane ND mg/L 01/06/16 19:25 96-18-40.0010 0.00041 1
1,2,4-Trimethylbenzene ND mg/L 01/06/16 19:25 95-63-60.0010 0.00031 1
1,3,5-Trimethylbenzene ND mg/L 01/06/16 19:25 108-67-80.0010 0.00036 1
Vinyl acetate ND mg/L 01/06/16 19:25 108-05-40.0020 0.00035 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 26 of 42
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Sample:SS- DOWNGRADIENT Lab ID:92281698013 Collected:12/31/15 15:00 Received:01/04/16 15:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level
Vinyl chloride ND mg/L 01/06/16 19:25 75-01-40.0010 0.00062 1
Xylene (Total)ND mg/L 01/06/16 19:25 1330-20-70.0020 0.00066 1
m&p-Xylene ND mg/L 01/06/16 19:25 179601-23-10.0020 0.00066 1
o-Xylene ND mg/L 01/06/16 19:25 95-47-60.0010 0.00023 1
Surrogates
4-Bromofluorobenzene (S)110 %01/06/16 19:25 460-00-470-130 1
1,2-Dichloroethane-d4 (S)103 %01/06/16 19:25 17060-07-070-130 1
Toluene-d8 (S)101 %01/06/16 19:25 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 27 of 42
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8849
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92281698001, 92281698002, 92281698003, 92281698004, 92281698005, 92281698006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1643385
Associated Lab Samples:92281698001, 92281698002, 92281698003, 92281698004, 92281698005, 92281698006
Matrix:Water
AnalyzedMDL
Mercury mg/L ND 0.00020 01/11/16 15:400.00010
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1643386LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury mg/L 0.0025.0025 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1643387MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92281799001
1643388
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury mg/L .0025 97 75-12594 3 25.0025ND 0.0025 0.0024
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 28 of 42
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8850
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92281698007, 92281698008, 92281698009, 92281698010, 92281698012, 92281698013
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1643395
Associated Lab Samples:92281698007, 92281698008, 92281698009, 92281698010, 92281698012, 92281698013
Matrix:Water
AnalyzedMDL
Mercury mg/L ND 0.00020 01/14/16 11:100.00010
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1643396LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury mg/L 0.0026.0025 105 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1643397MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92281698007
1643398
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury mg/L .0025 92 75-12593 1 25.0025ND 0.0024 0.0024
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 29 of 42
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20425
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples:92281698001, 92281698002, 92281698003, 92281698004, 92281698005, 92281698006, 92281698007,
92281698008, 92281698009, 92281698010, 92281698012, 92281698013
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1641736
Associated Lab Samples:92281698001, 92281698002, 92281698003, 92281698004, 92281698005, 92281698006, 92281698007,
92281698008, 92281698009, 92281698010, 92281698012, 92281698013
Matrix:Water
AnalyzedMDL
Arsenic mg/L ND 0.010 01/07/16 17:540.0050
Barium mg/L ND 0.0050 01/07/16 17:540.0025
Cadmium mg/L ND 0.0010 01/07/16 17:540.00050
Chromium mg/L ND 0.0050 01/07/16 17:540.0025
Lead mg/L ND 0.0050 01/07/16 17:540.0025
Selenium mg/L ND 0.010 01/07/16 17:540.0050
Silver mg/L ND 0.0050 01/07/16 17:540.0025
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1641737LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic mg/L 0.47.5 95 80-120
Barium mg/L 0.51.5 102 80-120
Cadmium mg/L 0.50.5 99 80-120
Chromium mg/L 0.50.5 100 80-120
Lead mg/L 0.49.5 97 80-120
Selenium mg/L 0.48.5 96 80-120
Silver mg/L 0.24.25 98 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1641738MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92281716001
1641739
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic mg/L .5 88 75-12589 0 20.5ND 0.44 0.44
Barium mg/L .5 92 75-12590 2 20.5ND 0.46 0.45
Cadmium mg/L .5 91 75-12589 2 20.5ND 0.46 0.45
Chromium mg/L .5 90 75-12588 2 20.517.9 ug/L 0.47 0.46
Lead mg/L .5 78 75-12577 2 20.5ND 0.39 0.39
Selenium mg/L .5 88 75-12587 1 20.5ND 0.44 0.44
Silver mg/L .25 93 75-12591 3 20.25ND 0.23 0.23
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 30 of 42
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/35064
EPA 8260
EPA 8260
8260 MSV Low Level
Associated Lab Samples:92281698001, 92281698002, 92281698003, 92281698004, 92281698005, 92281698006, 92281698007,
92281698008, 92281698009, 92281698010, 92281698012, 92281698013
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1641483
Associated Lab Samples:92281698001, 92281698002, 92281698003, 92281698004, 92281698005, 92281698006, 92281698007,
92281698008, 92281698009, 92281698010, 92281698012, 92281698013
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane mg/L ND 0.0010 01/06/16 12:020.00033
1,1,1-Trichloroethane mg/L ND 0.0010 01/06/16 12:020.00048
1,1,2,2-Tetrachloroethane mg/L ND 0.0010 01/06/16 12:020.00040
1,1,2-Trichloroethane mg/L ND 0.0010 01/06/16 12:020.00029
1,1-Dichloroethane mg/L ND 0.0010 01/06/16 12:020.00032
1,1-Dichloroethene mg/L ND 0.0010 01/06/16 12:020.00056
1,1-Dichloropropene mg/L ND 0.0010 01/06/16 12:020.00049
1,2,3-Trichlorobenzene mg/L ND 0.0010 01/06/16 12:020.00033
1,2,3-Trichloropropane mg/L ND 0.0010 01/06/16 12:020.00041
1,2,4-Trichlorobenzene mg/L ND 0.0010 01/06/16 12:020.00035
1,2,4-Trimethylbenzene mg/L ND 0.0010 01/06/16 12:020.00031
1,2-Dibromoethane (EDB)mg/L ND 0.0010 01/06/16 12:020.00027
1,2-Dichlorobenzene mg/L ND 0.0010 01/06/16 12:020.00030
1,2-Dichloroethane mg/L ND 0.0010 01/06/16 12:020.00024
1,2-Dichloroethene (Total)mg/L ND 0.0010 01/06/16 12:020.00049
1,2-Dichloropropane mg/L ND 0.0010 01/06/16 12:020.00027
1,3,5-Trimethylbenzene mg/L ND 0.0010 01/06/16 12:020.00036
1,3-Dichlorobenzene mg/L ND 0.0010 01/06/16 12:020.00024
1,3-Dichloropropane mg/L ND 0.0010 01/06/16 12:020.00028
1,4-Dichlorobenzene mg/L ND 0.0010 01/06/16 12:020.00033
2,2-Dichloropropane mg/L ND 0.0010 01/06/16 12:020.00013
2-Chlorotoluene mg/L ND 0.0010 01/06/16 12:020.00035
4-Chlorotoluene mg/L ND 0.0010 01/06/16 12:020.00031
Benzene mg/L ND 0.0010 01/06/16 12:020.00025
Bromobenzene mg/L ND 0.0010 01/06/16 12:020.00030
Bromochloromethane mg/L ND 0.0010 01/06/16 12:020.00017
Bromodichloromethane mg/L ND 0.0010 01/06/16 12:020.00018
Bromoform mg/L ND 0.0010 01/06/16 12:020.00026
Bromomethane mg/L ND 0.0020 01/06/16 12:020.00029
Carbon tetrachloride mg/L ND 0.0010 01/06/16 12:020.00025
Chlorobenzene mg/L ND 0.0010 01/06/16 12:020.00023
Chloroethane mg/L ND 0.0010 01/06/16 12:020.00054
Chloroform mg/L ND 0.0010 01/06/16 12:020.00014
Chloromethane mg/L ND 0.0010 01/06/16 12:020.00011
cis-1,2-Dichloroethene mg/L ND 0.0010 01/06/16 12:020.00019
Dibromochloromethane mg/L ND 0.0010 01/06/16 12:020.00021
Dibromomethane mg/L ND 0.0010 01/06/16 12:020.00021
Dichlorodifluoromethane mg/L ND 0.0010 01/06/16 12:020.00021
Diisopropyl ether mg/L ND 0.0010 01/06/16 12:020.00012
Ethylbenzene mg/L ND 0.0010 01/06/16 12:020.00030
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 31 of 42
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1641483
Associated Lab Samples:92281698001, 92281698002, 92281698003, 92281698004, 92281698005, 92281698006, 92281698007,
92281698008, 92281698009, 92281698010, 92281698012, 92281698013
Matrix:Water
AnalyzedMDL
Hexachloro-1,3-butadiene mg/L ND 0.0010 01/06/16 12:020.00071
Isopropylbenzene (Cumene)mg/L ND 0.0010 01/06/16 12:020.00040
m&p-Xylene mg/L ND 0.0020 01/06/16 12:020.00066
Methyl-tert-butyl ether mg/L ND 0.0010 01/06/16 12:020.00021
Methylene Chloride mg/L ND 0.0020 01/06/16 12:020.00097
n-Butylbenzene mg/L ND 0.0010 01/06/16 12:020.00041
n-Propylbenzene mg/L ND 0.0010 01/06/16 12:020.00042
Naphthalene mg/L ND 0.0010 01/06/16 12:020.00024
o-Xylene mg/L ND 0.0010 01/06/16 12:020.00023
p-Isopropyltoluene mg/L ND 0.0010 01/06/16 12:020.00031
sec-Butylbenzene mg/L ND 0.0010 01/06/16 12:020.00038
Styrene mg/L ND 0.0010 01/06/16 12:020.00026
tert-Butylbenzene mg/L ND 0.0010 01/06/16 12:020.00040
Tetrachloroethene mg/L ND 0.0010 01/06/16 12:020.00046
Tetrahydrofuran mg/L ND 0.010 01/06/16 12:020.0031
Toluene mg/L ND 0.0010 01/06/16 12:020.00026
trans-1,2-Dichloroethene mg/L ND 0.0010 01/06/16 12:020.00049
Trichloroethene mg/L ND 0.0010 01/06/16 12:020.00047
Trichlorofluoromethane mg/L ND 0.0010 01/06/16 12:020.00020
Vinyl acetate mg/L ND 0.0020 01/06/16 12:020.00035
Vinyl chloride mg/L ND 0.0010 01/06/16 12:020.00062
Xylene (Total)mg/L ND 0.0020 01/06/16 12:020.00066
1,2-Dichloroethane-d4 (S)%100 70-130 01/06/16 12:02
4-Bromofluorobenzene (S)%112 70-130 01/06/16 12:02
Toluene-d8 (S)%102 70-130 01/06/16 12:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1641484LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane mg/L 0.048.05 96 70-130
1,1,1-Trichloroethane mg/L 0.048.05 95 70-130
1,1,2,2-Tetrachloroethane mg/L 0.045.05 90 70-130
1,1,2-Trichloroethane mg/L 0.044.05 88 70-130
1,1-Dichloroethane mg/L 0.043.05 86 70-130
1,1-Dichloroethene mg/L 0.045.05 91 70-132
1,1-Dichloropropene mg/L 0.046.05 93 70-130
1,2,3-Trichlorobenzene mg/L 0.045.05 91 70-135
1,2,3-Trichloropropane mg/L 0.045.05 90 70-130
1,2,4-Trichlorobenzene mg/L 0.048.05 96 70-134
1,2,4-Trimethylbenzene mg/L 0.046.05 92 70-130
1,2-Dibromoethane (EDB)mg/L 0.045.05 90 70-130
1,2-Dichlorobenzene mg/L 0.044.05 88 70-130
1,2-Dichloroethane mg/L 0.044.05 88 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 32 of 42
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1641484LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichloroethene (Total)mg/L 0.090.1 90 70-130
1,2-Dichloropropane mg/L 0.044.05 87 70-130
1,3,5-Trimethylbenzene mg/L 0.047.05 95 70-130
1,3-Dichlorobenzene mg/L 0.047.05 95 70-130
1,3-Dichloropropane mg/L 0.043.05 86 70-130
1,4-Dichlorobenzene mg/L 0.048.05 95 70-130
2,2-Dichloropropane mg/L 0.051.05 101 58-145
2-Chlorotoluene mg/L 0.047.05 94 70-130
4-Chlorotoluene mg/L 0.045.05 90 70-130
Benzene mg/L 0.044.05 89 70-130
Bromobenzene mg/L 0.046.05 92 70-130
Bromochloromethane mg/L 0.047.05 95 70-130
Bromodichloromethane mg/L 0.050.05 100 70-130
Bromoform mg/L 0.050.05 100 70-130
Bromomethane mg/L 0.059.05 118 54-130
Carbon tetrachloride mg/L 0.050.05 101 70-132
Chlorobenzene mg/L 0.046.05 92 70-130
Chloroethane mg/L 0.048.05 96 64-134
Chloroform mg/L 0.047.05 93 70-130
Chloromethane mg/L 0.043.05 86 64-130
cis-1,2-Dichloroethene mg/L 0.044.05 89 70-131
Dibromochloromethane mg/L 0.049.05 98 70-130
Dibromomethane mg/L 0.049.05 99 70-131
Dichlorodifluoromethane mg/L 0.039.05 78 56-130
Diisopropyl ether mg/L 0.045.05 90 70-130
Ethylbenzene mg/L 0.045.05 90 70-130
Hexachloro-1,3-butadiene mg/L 0.061.05 123 70-130
Isopropylbenzene (Cumene)mg/L 0.049.05 98 70-130
m&p-Xylene mg/L 0.091.1 91 70-130
Methyl-tert-butyl ether mg/L 0.047.05 94 70-130
Methylene Chloride mg/L 0.044.05 88 63-130
n-Butylbenzene mg/L 0.047.05 94 70-130
n-Propylbenzene mg/L 0.045.05 90 70-130
Naphthalene mg/L 0.044.05 87 70-138
o-Xylene mg/L 0.046.05 91 70-130
p-Isopropyltoluene mg/L 0.046.05 91 70-130
sec-Butylbenzene mg/L 0.048.05 96 70-130
Styrene mg/L 0.045.05 91 70-130
tert-Butylbenzene mg/L 0.038.05 75 70-130
Tetrachloroethene mg/L 0.046.05 91 70-130
Tetrahydrofuran mg/L 0.43.5 86 70-130
Toluene mg/L 0.046.05 93 70-130
trans-1,2-Dichloroethene mg/L 0.045.05 91 70-130
Trichloroethene mg/L 0.047.05 94 70-130
Trichlorofluoromethane mg/L 0.049.05 97 62-133
Vinyl acetate mg/L 0.092.1 92 66-157
Vinyl chloride mg/L 0.046.05 91 50-150
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 33 of 42
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1641484LABORATORY CONTROL SAMPLE:
LCSSpike
Xylene (Total)mg/L 0.14.15 91 70-130
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%110 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1641485MATRIX SPIKE SAMPLE:
MSSpike
Result
92281698001
1,1,1,2-Tetrachloroethane mg/L 0.022.02 109 70-130ND
1,1,1-Trichloroethane mg/L 0.022.02 111 70-130ND
1,1,2,2-Tetrachloroethane mg/L 0.020.02 98 70-130ND
1,1,2-Trichloroethane mg/L 0.019.02 96 70-130ND
1,1-Dichloroethane mg/L 0.020.02 101 70-130ND
1,1-Dichloroethene mg/L 0.021.02 104 70-166ND
1,1-Dichloropropene mg/L 0.021.02 105 70-130ND
1,2,3-Trichlorobenzene mg/L 0.017.02 86 70-130ND
1,2,3-Trichloropropane mg/L 0.020.02 100 70-130ND
1,2,4-Trichlorobenzene mg/L 0.019.02 93 70-130ND
1,2,4-Trimethylbenzene mg/L 0.020.02 100 70-130ND
1,2-Dibromoethane (EDB)mg/L 0.019.02 97 70-130ND
1,2-Dichlorobenzene mg/L 0.020.02 99 70-130ND
1,2-Dichloroethane mg/L 0.021.02 103 70-130ND
1,2-Dichloropropane mg/L 0.018.02 92 70-130ND
1,3,5-Trimethylbenzene mg/L 0.021.02 103 70-130ND
1,3-Dichlorobenzene mg/L 0.021.02 103 70-130ND
1,3-Dichloropropane mg/L 0.019.02 94 70-130ND
1,4-Dichlorobenzene mg/L 0.021.02 105 70-130ND
2,2-Dichloropropane mg/L 0.021.02 104 70-130ND
2-Chlorotoluene mg/L 0.020.02 98 70-130ND
4-Chlorotoluene mg/L 0.020.02 102 70-130ND
Benzene mg/L 0.020.02 100 70-148ND
Bromobenzene mg/L 0.020.02 98 70-130ND
Bromochloromethane mg/L 0.021.02 106 70-130ND
Bromodichloromethane mg/L 0.022.02 109 70-130ND
Bromoform mg/L 0.019.02 95 70-130ND
Bromomethane mg/L 0.012 M1.02 59 70-130ND
Carbon tetrachloride mg/L 0.023.02 115 70-130ND
Chlorobenzene mg/L 0.021.02 106 70-146ND
Chloroethane mg/L 0.019.02 94 70-130ND
Chloroform mg/L 0.021.02 104 70-130ND
Chloromethane mg/L 0.018.02 88 70-130ND
cis-1,2-Dichloroethene mg/L 0.020.02 102 70-130ND
Dibromochloromethane mg/L 0.021.02 103 70-130ND
Dibromomethane mg/L 0.022.02 109 70-130ND
Dichlorodifluoromethane mg/L 0.018.02 90 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 34 of 42
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1641485MATRIX SPIKE SAMPLE:
MSSpike
Result
92281698001
Diisopropyl ether mg/L 0.020.02 101 70-130ND
Ethylbenzene mg/L 0.021.02 104 70-130ND
Hexachloro-1,3-butadiene mg/L 0.026.02 130 70-130ND
Isopropylbenzene (Cumene)mg/L 0.022.02 110 70-130ND
m&p-Xylene mg/L 0.041.04 104 70-130ND
Methyl-tert-butyl ether mg/L 0.021.02 104 70-130ND
Methylene Chloride mg/L 0.020.02 98 70-130ND
n-Butylbenzene mg/L 0.020.02 99 70-130ND
n-Propylbenzene mg/L 0.020.02 99 70-130ND
Naphthalene mg/L 0.017.02 84 70-130ND
o-Xylene mg/L 0.020.02 101 70-130ND
p-Isopropyltoluene mg/L 0.019.02 96 70-130ND
sec-Butylbenzene mg/L 0.020.02 101 70-130ND
Styrene mg/L 0.021.02 103 70-130ND
tert-Butylbenzene mg/L 0.017.02 83 70-130ND
Tetrachloroethene mg/L 0.021.02 107 70-130ND
Tetrahydrofuran mg/L 0.19.2 96 70-130ND
Toluene mg/L 0.021.02 103 70-155ND
trans-1,2-Dichloroethene mg/L 0.021.02 105 70-130ND
Trichloroethene mg/L 0.022.02 109 69-151ND
Trichlorofluoromethane mg/L 0.023.02 114 70-130ND
Vinyl acetate mg/L 0.038.04 95 70-130ND
Vinyl chloride mg/L 0.021.02 103 70-130ND
1,2-Dichloroethane-d4 (S)%101 70-130
4-Bromofluorobenzene (S)%116 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92281698002
1641486SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane mg/L ND 30ND
1,1,1-Trichloroethane mg/L ND 30ND
1,1,2,2-Tetrachloroethane mg/L ND 30ND
1,1,2-Trichloroethane mg/L ND 30ND
1,1-Dichloroethane mg/L ND 30ND
1,1-Dichloroethene mg/L ND 30ND
1,1-Dichloropropene mg/L ND 30ND
1,2,3-Trichlorobenzene mg/L ND 30ND
1,2,3-Trichloropropane mg/L ND 30ND
1,2,4-Trichlorobenzene mg/L ND 30ND
1,2,4-Trimethylbenzene mg/L .00044J 30ND
1,2-Dibromoethane (EDB)mg/L ND 30ND
1,2-Dichlorobenzene mg/L ND 30ND
1,2-Dichloroethane mg/L ND 30ND
1,2-Dichloroethene (Total)mg/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 35 of 42
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92281698002
1641486SAMPLE DUPLICATE:
1,2-Dichloropropane mg/L ND 30ND
1,3,5-Trimethylbenzene mg/L ND 30ND
1,3-Dichlorobenzene mg/L ND 30ND
1,3-Dichloropropane mg/L ND 30ND
1,4-Dichlorobenzene mg/L ND 30ND
2,2-Dichloropropane mg/L ND 30ND
2-Chlorotoluene mg/L ND 30ND
4-Chlorotoluene mg/L ND 30ND
Benzene mg/L 0.0013 3 300.0013
Bromobenzene mg/L ND 30ND
Bromochloromethane mg/L ND 30ND
Bromodichloromethane mg/L ND 30ND
Bromoform mg/L ND 30ND
Bromomethane mg/L ND 30ND
Carbon tetrachloride mg/L ND 30ND
Chlorobenzene mg/L ND 30ND
Chloroethane mg/L ND 30ND
Chloroform mg/L ND 30ND
Chloromethane mg/L ND 30ND
cis-1,2-Dichloroethene mg/L ND 30ND
Dibromochloromethane mg/L ND 30ND
Dibromomethane mg/L ND 30ND
Dichlorodifluoromethane mg/L ND 30ND
Diisopropyl ether mg/L ND 30ND
Ethylbenzene mg/L ND 30ND
Hexachloro-1,3-butadiene mg/L ND 30ND
Isopropylbenzene (Cumene)mg/L 0.0015 5 300.0014
m&p-Xylene mg/L .00069J 30ND
Methyl-tert-butyl ether mg/L .00061J 30ND
Methylene Chloride mg/L ND 30ND
n-Butylbenzene mg/L ND 30ND
n-Propylbenzene mg/L ND 30ND
Naphthalene mg/L 0.0017 8 300.0016
o-Xylene mg/L .00062J 30ND
p-Isopropyltoluene mg/L ND 30ND
sec-Butylbenzene mg/L ND 30ND
Styrene mg/L ND 30ND
tert-Butylbenzene mg/L ND 30ND
Tetrachloroethene mg/L ND 30ND
Tetrahydrofuran mg/L 0.10 1 300.10
Toluene mg/L ND 30ND
trans-1,2-Dichloroethene mg/L ND 30ND
Trichloroethene mg/L ND 30ND
Trichlorofluoromethane mg/L ND 30ND
Vinyl acetate mg/L ND 30ND
Vinyl chloride mg/L ND 30ND
Xylene (Total)mg/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 36 of 42
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92281698002
1641486SAMPLE DUPLICATE:
1,2-Dichloroethane-d4 (S)%102 1103
4-Bromofluorobenzene (S)%106 3110
Toluene-d8 (S)%101 0101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 37 of 42
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 38 of 42
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92281698
WILEY DAVIS LANDFILL
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92281698001 MPRP/20425 ICP/18425WD-1 EPA 3010A EPA 6010
92281698002 MPRP/20425 ICP/18425WD-2 EPA 3010A EPA 6010
92281698003 MPRP/20425 ICP/18425WD-2d EPA 3010A EPA 6010
92281698004 MPRP/20425 ICP/18425WD-3 EPA 3010A EPA 6010
92281698005 MPRP/20425 ICP/18425WD-3d EPA 3010A EPA 6010
92281698006 MPRP/20425 ICP/18425WD-4 EPA 3010A EPA 6010
92281698007 MPRP/20425 ICP/18425WD-4d EPA 3010A EPA 6010
92281698008 MPRP/20425 ICP/18425WD-7 EPA 3010A EPA 6010
92281698009 MPRP/20425 ICP/18425WD-8 EPA 3010A EPA 6010
92281698010 MPRP/20425 ICP/18425WD-9 EPA 3010A EPA 6010
92281698012 MPRP/20425 ICP/18425UPGRADIENTEPA 3010A EPA 6010
92281698013 MPRP/20425 ICP/18425SS- DOWNGRADIENT EPA 3010A EPA 6010
92281698001 MERP/8849 MERC/8501WD-1 EPA 7470 EPA 7470
92281698002 MERP/8849 MERC/8501WD-2 EPA 7470 EPA 7470
92281698003 MERP/8849 MERC/8501WD-2d EPA 7470 EPA 7470
92281698004 MERP/8849 MERC/8501WD-3 EPA 7470 EPA 7470
92281698005 MERP/8849 MERC/8501WD-3d EPA 7470 EPA 7470
92281698006 MERP/8849 MERC/8501WD-4 EPA 7470 EPA 7470
92281698007 MERP/8850 MERC/8499WD-4d EPA 7470 EPA 7470
92281698008 MERP/8850 MERC/8499WD-7 EPA 7470 EPA 7470
92281698009 MERP/8850 MERC/8499WD-8 EPA 7470 EPA 7470
92281698010 MERP/8850 MERC/8499WD-9 EPA 7470 EPA 7470
92281698012 MERP/8850 MERC/8499UPGRADIENTEPA 7470 EPA 7470
92281698013 MERP/8850 MERC/8499SS- DOWNGRADIENT EPA 7470 EPA 7470
92281698001 MSV/35064WD-1 EPA 8260
92281698002 MSV/35064WD-2 EPA 8260
92281698003 MSV/35064WD-2d EPA 8260
92281698004 MSV/35064WD-3 EPA 8260
92281698005 MSV/35064WD-3d EPA 8260
92281698006 MSV/35064WD-4 EPA 8260
92281698007 MSV/35064WD-4d EPA 8260
92281698008 MSV/35064WD-7 EPA 8260
92281698009 MSV/35064WD-8 EPA 8260
92281698010 MSV/35064WD-9 EPA 8260
92281698012 MSV/35064UPGRADIENTEPA 8260
92281698013 MSV/35064SS- DOWNGRADIENT EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 04:17 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 39 of 42
Page 40 of 42
Page 41 of 42
Page 42 of 42