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HomeMy WebLinkAbout2803-CDLF-1995_DareCountyCDLF_GWMReport_DIN26489_20160229D a r e C o u n t y C & D L a n d f i l l F a c i l i t y P e r m i t N o . 2 8 - 0 3 S e m i - A n n u a l S a m p l i n g R e p o r t ( F e b r u a r y 2 0 1 6 S a m p l i n g E v e n t ) 5400 Glenwood Avenue, Suite 400 Raleigh, North Carolina 27612 tel: 919 325-3500 fax: 919 781-5730 April 27, 2016 Ms. Jaclynne Drummond North Carolina Department of Environmental Quality Division of Waste Management Solid Waste Section 2090 U.S. 70 Highway Swannanoa, North Carolina 28778 Subject: February 2016 Semi-Annual Groundwater Sampling Report Dare County C&D Landfill Dare County, North Carolina Facility Permit No. 28-03 Dear Ms. Drummond: CDM Smith Inc., on behalf of Dare County, is submitting an electronic copy of the February 2016 semi-annual groundwater sampling event report. This letter report presents the results of the most recent semi-annual sampling event that was completed at the Dare County C&D Landfill and constitutes the first semi-annual sampling event for 2016. The approved groundwater monitoring network consists of 13 wells (i.e. MW-1, -2, -3, -8, -9, -10, -11, -12, -13, -14, -15, -16, and -17) and three surface water sampling locations (i.e. SW-1, -2, and -3). Field activities and sampling results are discussed below. Field Activities Groundwater and surface water samples from the Dare County C&D Landfill were collected on February 29, 2016, by Environment One, Inc. (Environment One). Monitoring wells and surface water sample locations are shown on Figure 1. Well construction details for the monitoring wells are provided in Table 1. Groundwater elevations were measured at each well prior to sampling using an electronic water level indicator with an accuracy of 0.01 feet. These groundwater elevations as presented in Table 2 were used to construct a potentiometric surface map for this sampling event. The potentiometric contours are presented on Figure 1. Each monitoring well was measured for pH, conductivity, temperature, turbidity, dissolved oxygen, and oxidation-reduction potential (ORP) prior to sampling. The same water quality parameters were Ms. Jaclynne Drummond April 27, 2016 Page 2 measured at the surface water sample locations with the exception of ORP. The water quality parameters at the time samples were collected are presented in Table 2. Sampling Results Environment One located in Greenville, North Carolina, analyzed the groundwater and surface water samples for North Carolina Appendix I volatile organic compounds by U.S. Environmental Protection Agency (EPA) Method 8260B, metals by EPA Methods 200.7, 200.8, and Standard Method (SM) 3113B, mercury by EPA Method 245.1, alkalinity by SM 2320B, chloride and sulfate by SM 4500, and total dissolved solids (TDS) by SM 2540C. In accordance with Solid Waste Section guidelines, the analytical results were reported to the laboratory specific method detection limit (MDL) and are quantifiable at or below Solid Waste Section Limits (SWSLs). All monitoring wells and surface water sample locations for the C&D Landfill had detections of analytes above the MDL but below SWSLs. These detections were qualified with “J” flags, which indicate an estimated concentration. The following list presents the analytes detected above the MDL at each sample location. No “J” flag detections are provided. Underlined analytes exceeded the 15A NCAC 02L .0202 (NC 2L) Groundwater Quality Standard, Groundwater Protection Standard, or the 15A NCAC 02B Surface Water Quality Standard for Class C Waters. A complete summary of all detected and estimated concentrations for the February 2016 sampling event is presented in Table 3. Analytical results for TDS are provided in Table 2. The laboratory analytical report is provided in Appendix A. MW-1 Inorganics: Alkalinity, Chloride Metals: Iron, Manganese Volatile Organic Compounds: None Detected MW-2 Inorganics: Alkalinity, Chloride Metals: Iron, Manganese Volatile Organic Compounds: None Detected MW-3 Inorganics: Alkalinity, Chloride Metals: Iron, Manganese Volatile Organic Compounds: None Detected Ms. Jaclynne Drummond April 27, 2016 Page 3 MW-8 Inorganics: Alkalinity, Chloride Metals: Barium, Iron, Manganese, Zinc Volatile Organic Compounds: None Detected MW-9 Inorganics: Alkalinity, Chloride Metals: Arsenic, Iron, Vanadium, Zinc Volatile Organic Compounds: None Detected MW-10 Inorganics: Alkalinity, Chloride Metals: Arsenic, Iron, Manganese Volatile Organic Compounds: None Detected MW-11 Inorganics: Alkalinity, Chloride Metals: Iron, Manganese Volatile Organic Compounds: None Detected MW-12 Inorganics: Alkalinity, Chloride Metals: Iron Volatile Organic Compounds: None Detected MW-13 Inorganics: Alkalinity, Chloride Metals: Iron, Manganese Volatile Organic Compounds: None Detected MW-14 Inorganics: Alkalinity, Chloride Metals: Arsenic, Iron, Manganese Volatile Organic Compounds: None Detected MW-15 Inorganics: Alkalinity, Chloride Metals: Arsenic, Iron, Manganese, Zinc Volatile Organic Compounds: None Detected Ms. Jaclynne Drummond April 27, 2016 Page 4 MW-16 Inorganics: Alkalinity, Chloride Metals: Barium, Iron, Manganese Volatile Organic Compounds: None Detected MW-17 Inorganics: Alkalinity, Chloride Metals: Iron, Zinc Volatile Organic Compounds: None Detected SW-1 Inorganics: Alkalinity, Chloride Metals: Iron, Lead Volatile Organic Compounds: None Detected SW-2 Inorganics: Alkalinity, Chloride Metals: Iron, Lead, Manganese Volatile Organic Compounds: None Detected SW-3 Inorganics: Alkalinity, Chloride Metals: Iron, Lead, Manganese Volatile Organic Compounds: None Detected “J” flags were not included in the previous list, but several locations had “J” flag detections that exceeded the standards. The “J” flag constituents above the standards along with their locations are listed below. Cobalt: MW-9, -11, and -17 Vanadium: MW-1, -2, -3, -8, -10, -11, -12, -13, -14, -15, -16, and -17 No analytes were detected in the trip blank. The equipment blank had “J” flag detections of beryllium, chromium, iron, and nickel below their respective NC 2L Standard. Duplicate samples collected from MW-12 had analytes detected at similar concentrations to the parent samples. The semi-annual groundwater monitoring program will be continued by Dare County. The second semi-annual sampling event for 2016 is tentatively scheduled for August. Ms. Jaclynne Drummond April 27, 2016 Page 5 If you have any questions or require further explanation, do not hesitate to call me at (919) 325-3569. Very truly yours, Mathew F. Colone, P.G. CDM Smith Inc. Attachments cc: Edward Mann, Dare County Ta b l e 1 Mo n i t o r i n g W e l l C o n s t r u c t i o n S u m m a r y Da r e C o u n t y C & D L a n d f i l l To p o f G r o u n d T o p T o p Ca s i n g S u r f a c e B o r e h o l e S c r e e n o f o f C a s i n g El e v a t i o n E l e v a t i o n D e p t h I n t e r v a l F i l t e r P a c k S e a l D i a m e ter (f e e t m s l ) ( f e e t m s l ) ( f e e t b g s ) ( f e e t b g s ) ( f e e t b g s ) ( feet bgs) ( i n c h e s ) 28 - 0 3 GW - 1 1 1 / 2 8 / 1 9 9 4 H S A 7 7 5 4 5 9 . 4 6 2 9 4 3 4 2 3 . 1 7 S u r f i c i a l 3 . 1 3 1 . 58 1 0 . 0 1 0 . 0 - 2 0 . 0 8 . 0 7 . 0 2 . 0 28 - 0 3 GW - 2 1 1 / 2 9 / 1 9 9 4 H S A 7 7 4 8 1 2 . 6 3 2 9 4 3 4 7 6 . 2 1 S u r f i c i a l 3 . 1 7 1 . 4 2 0 . 0 1 0 . 0 - 2 0 . 0 8 . 0 7 . 0 2 . 0 28 - 0 3 GW - 3 1 1 / 2 9 / 1 9 9 4 H S A 7 7 4 2 4 6 . 5 0 2 9 4 3 5 4 4 . 2 9 S u r f i c i a l 4 . 1 8 1 . 82 2 0 . 0 1 0 . 0 - 2 0 . 0 8 . 0 7 . 0 2 . 0 28 - 0 3 GW - 8 1 1 / 2 8 / 1 9 9 4 H S A 7 7 5 2 7 6 . 9 6 2 9 4 2 7 6 5 . 2 1 S u r f i c i a l 4 . 5 5 2 . 90 2 0 . 0 1 0 . 0 - 2 0 . 0 8 . 0 7 . 0 2 . 0 28 - 0 3 GW - 9 8 / 1 4 / 2 0 0 2 H S A 7 7 2 5 7 8 . 0 1 2 9 4 2 6 1 5 . 3 6 S u r f i c i a l 3 . 5 9 0 . 9 0 2 0 . 0 2 . 0 - 2 0 . 0 1 . 5 1 . 0 2 . 0 28 - 0 3 GW - 1 0 8 / 1 3 / 2 0 0 2 H S A 7 7 2 8 7 3 . 7 8 2 9 4 3 1 8 8 . 4 8 S u r f i c i a l 6 . 0 2 2 . 70 2 0 . 0 2 . 0 - 2 0 . 0 2 . 0 1 . 0 2 . 0 28 - 0 3 GW - 1 1 8 / 1 2 / 2 0 0 2 H S A 7 7 3 0 2 7 . 1 5 2 9 4 3 4 6 4 . 8 5 S u r f i c i a l 6 . 4 1 2 . 74 2 0 . 0 2 . 0 - 2 0 . 0 2 . 0 1 . 0 2 . 0 28 - 0 3 GW - 1 2 8 / 1 3 / 2 0 0 2 H S A 7 7 3 4 9 5 . 4 9 2 9 4 3 6 5 6 . 6 5 S u r f i c i a l 2 . 8 0 . 3 3 2 0 . 0 3 . 0 - 2 0 . 0 1 . 5 1 . 0 2 . 0 28 - 0 3 GW - 1 3 1 / 2 4 / 2 0 0 6 M u d R o t a r y 7 7 4 0 1 9 . 5 6 2 9 4 2 1 6 3 . 2 8 S u r f i c i a l 3 . 0 9 0 . 7 2 0 . 0 5 . 0 - 2 0 . 0 3 . 0 1 . 0 2 . 0 28 - 0 3 GW - 1 4 1 / 2 4 / 2 0 0 6 M u d R o t a r y 7 7 3 5 7 7 . 8 0 2 9 4 2 2 2 4 . 9 0 S u r f i c i a l 3 . 0 6 0 . 5 2 2 0 . 0 5 . 0 - 2 0 . 0 3 . 0 1 . 0 2 . 0 28 - 0 3 GW - 1 5 1 / 2 4 / 2 0 0 6 M u d R o t a r y 7 7 2 9 2 2 . 3 7 2 9 4 2 2 8 9 . 7 6 S u r f i c i a l 3 . 2 4 0 . 8 5 2 0 . 0 5 . 0 - 2 0 . 0 3 . 0 1 . 0 2 . 0 28 - 0 3 GW - 1 6 9 / 1 / 2 0 1 0 H S A 7 7 5 1 2 9 . 9 8 2 9 4 2 4 6 4 . 1 1 S u r f i c i a l 5 . 5 6 3 . 5 20 . 0 5 . 0 - 2 0 . 0 3 . 0 1 . 0 2 . 0 28 - 0 3 GW - 1 7 9 / 1 / 2 0 1 0 H S A 7 7 2 7 2 2 . 1 0 2 9 4 2 8 7 3 . 1 8 S u r f i c i a l 2 . 8 5 0 . 8 20 . 0 5 . 0 - 2 0 . 0 3 . 0 1 . 0 2 . 0 No t e s : 1. H S A - H o l l o w - s t e m a u g e r 2. b g s - b e l o w g r o u n d s u r f a c e 3. m s l - m e a n s e a l e v e l 4. H o r i z o n t a l C o n t r o l - N o r t h A m e r i c a n D a t u m 1 9 8 3 S ta t e P l a n e F e e t N o r t h C a r o l i n a Fa c i l i t y P e r m i t Nu m b e r Mo n i t o r i n g We l l C o d e Aq u i f e r Mo n i t o r i n g In t e r v a l Dr i l l i n g Me t h o d Co m p l e t i o n Da t e No r t h i n g E a s t i n g Pa g e 1 o f 1 April 2016 Ta b l e 2 Wa t e r Q u a l i t y M e a s u r e m e n t s a n d T o t a l D i s s o l v e d S o l i d s Fe b r u a r y 2 0 1 6 S e m i - A n n u a l S a m p l i n g E v e n t Da r e C o u n t y C & D L a n d f i l l Fa c i l i t y P e r m i t Nu m b e r Mo n i t o r i n g W e l l Co d e pH (S . U . ) Co n d u c t i v i t y (µ S / c m ) Te m p e r a t u r e (d e g r e e s Ce l s i u s ) Tu r b i d i t y (N T U s ) Di s s o l v e d Ox y g e n (m g / L ) Ox i d a t i o n - R e d u c t i o n Po t e n t i a l (m V s ) TD S (m g / L ) TO C E l e v a t i o n (f e e t A M S L ) Depth to Groundwater (feet)Groundwater Elevation (feet AMSL) 28 - 0 3 M W - 1 6 . 9 1 , 5 3 5 1 5 8 3 6 . 8 1 1 7 2 , 4 8 0 1 . 6 1 1 . 6 1 0 . 0 0 28 - 0 3 M W - 2 6 . 9 6 6 8 1 5 4 2 1 . 6 4 - 6 0 5 4 2 1 . 5 5 2 . 2 3 - 0 . 6 8 28 - 0 3 M W - 3 6 . 8 7 5 7 1 4 2 2 9 1 . 6 7 - 1 9 4 9 4 1 . 7 4 3 . 8 9 - 2 . 1 5 28 - 0 3 M W - 8 6 . 2 4 , 4 3 0 1 7 1 5 3 2 . 0 2 3 2 3 , 8 4 0 2 . 9 0 2 . 1 2 0 . 7 8 28 - 0 3 M W - 9 5 . 3 1 7 4 1 8 2 6 1 . 7 2 7 7 1 3 6 4 . 9 9 5 . 3 0 - 0 . 3 1 28 - 0 3 M W - 1 0 6 . 2 5 2 3 1 6 2 9 0 . 5 0 4 6 4 1 8 2 . 8 7 5 . 4 0 - 2 . 5 3 28 - 0 3 M W - 1 1 6 . 2 3 3 0 1 6 6 7 1 . 6 0 4 5 1 7 4 3 . 5 6 5 . 0 0 - 1 . 4 4 28 - 0 3 M W - 1 2 5 . 1 9 7 1 5 9 1 . 0 9 8 2 8 5 2 . 8 0 4 . 4 0 - 1 . 6 0 28 - 0 3 M W - 1 3 6 . 8 7 7 2 1 4 1 5 5 1 . 7 0 - 3 3 5 6 3 2 . 9 6 3 . 9 2 - 0 . 9 6 28 - 0 3 M W - 1 4 6 . 2 6 2 7 1 4 2 5 2 1 . 1 0 - 1 3 7 3 2 . 9 6 4 . 0 0 - 1 . 0 4 28 - 0 3 M W - 1 5 6 . 3 3 2 0 1 4 7 4 1 . 8 5 1 5 2 2 4 3 . 1 7 4 . 3 2 - 1 . 1 5 28 - 0 3 M W - 1 6 6 . 1 1 , 9 0 3 1 5 1 1 . 8 1 - 9 2 , 4 1 0 5 . 5 6 5 . 0 2 0 . 5 4 28 - 0 3 M W - 1 7 5 . 0 1 8 5 1 6 1 1 0 . 5 2 9 6 1 4 2 2 . 8 5 4 . 0 0 - 1 . 1 5 28 - 0 3 S W - 1 4 . 9 3 4 9 1 7 8 8 . 5 2 - - 2 8 5 28 - 0 3 S W - 2 7 . 3 5 6 2 1 6 3 7 9 . 4 0 - - 4 0 8 28 - 0 3 S W - 3 6 . 7 5 6 7 1 4 3 7 8 . 4 6 - - 4 2 1 No t e s : 1. m g / L - m i l l i g r a m s p e r l i t e r 2. µ S / c m - M i c r o s i e m e n s p e r c e n t i m e t e r 3. T D S - T o t a l D i s s o l v e d S o l i d s 4. A M S L - A b o v e M e a n S e a L e v e l 5. T O C - T o p o f C a s i n g 6. S . U . - S t a n d a r d U n i t 7. m V s - M i l l i v o l t s 8. N T U s - N e p h e l o m e t r i c T u r b i d i t y U n i t s 9. - - N o t m e a s u r e d Wa t e r Q u a l i t y P a r a m e t e r s Su r f a c e W a t e r S a m p l e L o c a t i o n s Gr o u n d w a t e r E l e v a t i o n s - 2 / 2 9 / 1 6 Pa g e 1 o f 1 April 2016 Ta b l e 3 a De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s , V o l a t i l e O r g a n i c C o m p o u n d s , a n d G e n e r a l C h e m i s t r y Fe b r u a r y 2 0 1 6 S e m i - A n n u a l S a m p l i n g E v e n t Da r e C o u n t y C & D L a n d f i l l Fa c i l i t y Pe r m i t Nu m b e r Mo n i t o r i n g We l l C o d e Sa m p l e Da t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r I r o n L e a d M a n g a n e s e M e r c u r y N i c k e l S e l e n i u m S i l v e r T h a l l i u m V a n a d i u m Z i n c A c e t o n e B e n z e n e C a r b o n D i s u l f i d e C h l o r o b e n z e n e C h l o r o m e t h a n e Toluene Alkalinity Chloride Sulfate 1* 1 0 7 0 0 4 * 2 1 0 1 * 1 , 0 0 0 3 0 0 1 5 5 0 1 1 0 0 2 0 2 0 0 . 2 * 0 . 3 * 1 , 0 0 0 6 , 0 0 0 1 7 0 0 5 0 3 6 0 0 N S 2 5 0 2 5 0 6 1 0 1 0 0 1 1 1 0 1 0 1 0 3 0 0 1 0 5 0 0 . 2 5 0 1 0 1 0 5 . 5 2 5 1 0 1 0 0 1 1 0 0 3 1 1 N E N E 2 5 0 28 - 0 3 M W - 1 2 2 - A u g - 1 1 2 . 7 J 4 8 . 1 J 0 . 1 0 J 1 . 6 J 0 . 5 7 J 2 . 5 J 46 , 0 5 0 0. 6 0 J 55 2 2.5 J 7 . 3 J 3J 3.9 J 239 1,070 58.8J 28 - 0 3 M W - 1 1 6 - F e b - 1 2 2 . 2 J 4 2 . 2 J 0 . 0 9 J 1 . 6 J 0 . 3 9 J 1 . 9 J 49 , 4 0 0 0. 4 7 J 57 8 2J 6 . 7 J 2.3 J 1.8 J 296 1,000 45.2J 28 - 0 3 M W - 1 1 4 - A u g - 1 2 1 . 5 J 4 2 . 9 J 0 . 1 3 J 0 . 8 5 J 0 . 2 0 J 1 . 9 J 46 , 5 5 0 4 7 3 2J 5 . 5 J 1J 15 273 906 64.5J 28 - 0 3 M W - 1 2 8 - F e b - 1 3 0 . 1 5 J 3 . 3 J 7 6 . 9 J 0 . 7 1 J 3 . 4 J 0 . 8 1 J 3 J 99 , 7 0 0 1.5 J 52 6 3.2 J 7 . 5 J 6J 6.6 J 254 975 61.5J 28 - 0 3 M W - 1 3 0 - S e p - 1 3 0 . 1 1 J 2 . 4 J 3 4 . 1 J 0 . 0 6 J 0 . 1 6 J 1 . 7 J 20 , 5 4 0 0. 0 3 J 34 1 0.0 4 J 2 . 2 J 7 . 1 J 3J 2J 276 950 27.3J 28 - 0 3 M W - 1 1 7 - F e b - 1 4 0 . 0 4 J 3 . 9 J 1 8 . 8 J 0 . 4 3 J 0 . 2 5 J 2 . 6 J 8,8 5 0 0. 1 2 J 24 7 6.3 J 1 5 0 . 0 3 J 0 . 2 6 J 1 . 6 J 199 860 39.1J 28 - 0 3 M W - 1 2 6 - A u g - 1 4 2 . 3 J 4 2 . 8 J 0 . 0 6 J 1 . 2 J 0 . 1 8 J 2 . 0 J 28 , 1 2 5 5 2 8 2.2 J 1 1 0. 6 9 J 1.6 J 250 324 38.9J 28 - 0 3 M W - 1 2 7 - F e b - 1 5 3 . 0 J 2 8 . 6 J 0 . 0 4 J 0 . 4 3 J 0 . 1 6 J 2 . 5 J 12 , 8 7 0 0. 1 8 J 10 9 2.4 J 9 . 2 J 1.0 J 2.8 J 186 968 37.7J 28 - 0 3 M W - 1 2 6 - O c t - 1 5 0 . 0 8 J 4 . 2 J 3 5 . 3 J 0 . 0 6 J 0 . 2 6 J 0 . 2 7 J 2 . 4 J 7,7 6 0 0. 1 8 J 68 4.2 J 1 9 0 . 0 1 J 0 . 0 3 J 0. 5 0 J 2.2 J 174 1,060 34.4J 28 - 0 3 M W - 1 2 9 - F e b - 1 6 0 . 1 4 J 3 . 3 J 3 3 . 7 J 0 . 1 0 J 0 . 1 9 J 2 . 7 J 15 , 5 7 1 0. 0 9 J 11 7 3.8 J 0. 3 6 J 174 1,220 37.1J 28 - 0 3 M W - 2 2 2 - A u g - 1 1 0 . 2 1 J 7 . 8 J 0 . 1 4 J 0 . 7 2 J 16 , 1 6 0 0. 0 6 J 28 2 1.2 J 0 . 2 6 J 1.4 J 2J 388 3 9 28 - 0 3 M W - 2 1 6 - F e b - 1 2 0 . 3 2 J 1 2 . 9 J 0 . 0 6 J 0 . 9 4 J 0 . 1 8 J 1 . 5 J 45 , 4 0 0 0. 4 3 J 34 4 0. 8 8 J 0 . 2 6 J 1.9 J 2.8 J 393 3 7 28 - 0 3 M W - 2 1 4 - A u g - 1 2 8 . 7 J 0 . 0 5 J 0 . 1 2 J 1 . 0 J 23 , 4 8 0 2 6 2 1.2 J 0. 3 9 J 11 378 3 8 1 0 . 9 J 28 - 0 3 M W - 2 2 8 - F e b - 1 3 0 . 3 1 J 0 . 5 9 J 4 5 . 8 J 0 . 2 0 J 0 . 1 4 J 1 . 4 J 0 . 1 5 J 1 0 20 4 , 1 0 0 3.1 J 39 9 1.5 J 0 . 5 1 J 3.9 J 46 353 4 6 1 2 . 6 J 28 - 0 3 M W - 2 3 0 - S e p - 1 3 0 . 0 5 J 0 . 2 2 J 8 . 3 J 0 . 0 3 J 0 . 1 3 J 0 . 4 0 J 21 , 1 5 0 0. 0 3 J 21 9 0.0 4 J 1 . 4 J 0 . 5 3 J 3.3 J 1.8 J 404 4 3 1 6 . 4 J 28 - 0 3 M W - 2 1 7 - F e b - 1 4 0 . 1 0 J 8 . 7 J 0 . 1 4 J 0 . 1 8 J 0 . 7 7 J 14 , 9 0 0 0. 0 8 J 35 4 4.4 J 1 . 3 J 0 . 0 4 J 0. 5 0 J 2.0 J 379 4 6 1 0 . 4 J 28 - 0 3 M W - 2 2 6 - A u g - 1 4 8 . 0 J 0 . 4 2 J 0 . 1 4 J 0 . 4 4 J 12 , 8 7 5 3 1 1 1.2 J 0. 6 8 J 1.3 J 368 4 5 1 0 . 4 J 28 - 0 3 M W - 2 2 7 - F e b - 1 5 0 . 5 6 J 0 . 2 4 J 1 0 . 1 J 0 . 9 7 J 13 , 1 3 0 0. 2 2 J 32 4 1.3 J 0 . 6 3 J 0. 8 6 J 6.6 J 333 5 7 28 - 0 3 M W - 2 2 6 - O c t - 1 5 0 . 0 6 J 8 . 0 J 0 . 0 3 J 0 . 0 5 J 0 . 1 7 J 1 . 7 J 11 , 3 4 9 0. 3 0 J 19 9 2.0 J 1 . 1 J 0 . 0 1 J 0. 6 5 J 3.3 J 312 4 8 28 - 0 3 M W - 2 2 9 - F e b - 1 6 1 2 . 3 J 0 . 0 5 J 0 . 1 3 J 0 . 6 3 J 26 , 5 2 2 0. 0 7 J 36 4 1.8 J 0 . 9 7 J 0. 7 1 J 2.2 J 312 6 0 28 - 0 3 M W - 3 2 2 - A u g - 1 1 0 . 1 8 J 1 3 . 0 J 0 . 1 1 J 0 . 0 4 J 0 . 1 8 J 0 . 7 2 J 25 , 4 0 0 0. 0 8 J 35 5 1.2 J 1.1 J 3.6 J 391 3 5 1 2 . 1 J 28 - 0 3 M W - 3 1 6 - F e b - 1 2 1 0 . 7 J 0 . 1 1 J 0 . 0 4 J 0 . 2 2 J 0 . 1 5 J 0 . 2 8 J 25 , 2 7 5 0. 0 7 J 39 8 0. 7 7 J 0. 7 1 J 408 3 4 28 - 0 3 M W - 3 1 4 - A u g - 1 2 1 3 . 8 J 0 . 1 0 J 0 . 0 4 J 0 . 2 8 J 0 . 1 6 J 0 . 6 4 J 25 , 3 2 5 2 4 4 1.6 J 0 . 1 3 J 6 . 9 J 416 3 8 1 8 . 2 J 28 - 0 3 M W - 3 2 8 - F e b - 1 3 0 . 0 4 J 0 . 4 8 J 3 1 . 1 J 0 . 3 2 J 0 . 0 9 J 1 . 0 J 0 . 2 0 J 0 . 2 4 J 81 , 8 5 0 0. 1 2 J 55 3 1.9 J 0 . 6 7 J 1.5 J 2.1 J 473 5 6 1 0 8 J 28 - 0 3 M W - 3 3 0 - S e p - 1 3 0 . 0 4 J 0 . 4 9 J 1 5 . 4 J 0 . 1 1 J 0 . 1 5 J 0 . 4 0 J 30 , 0 9 0 3 7 3 0.0 4 J 1 . 7 J 0 . 6 3 J 3.1 J 1.6 J 478 5 0 5 6 . 4 J 28 - 0 3 M W - 3 1 7 - F e b - 1 4 0 . 4 4 J 2 0 . 5 J 0 . 1 8 J 1 . 2 J 0 . 2 5 J 0 . 4 8 J 53 , 8 7 5 0. 0 4 J 61 4 6.3 J 2 . 0 J 0. 7 6 J 1.9 J 448 5 8 1 0 0 J 28 - 0 3 M W - 3 2 6 - A u g - 1 4 0 . 2 7 J 1 8 . 4 J 0 . 1 1 J 1 . 2 J 0 . 1 7 J 0 . 2 3 J 20 , 7 0 0 5 2 3 1.5 J 1 . 0 J 0. 3 8 J 0. 8 5 J 443 2 9 7 7 . 0 J 28 - 0 3 M W - 3 2 7 - F e b - 1 5 0 . 1 8 J 0 . 7 2 J 4 2 . 8 J 0 . 2 6 J 0 . 0 4 J 0 . 9 0 J 0 . 1 8 J 0 . 3 8 J 49 , 1 2 5 6 2 5 1.8 J 1 . 4 J 1.1 J 1.9 J 379 7 5 1 2 4 J 28 - 0 3 M W - 3 2 6 - O c t - 1 5 0 . 0 6 J 0 . 3 8 J 1 9 . 1 J 0 . 1 2 J 0 . 0 6 J 0 . 9 1 J 0 . 2 5 J 0 . 6 1 J 12 , 6 2 9 0. 1 7 J 38 1 3.0 J 2 . 2 J 0 . 0 1 J 0. 5 9 J 2.3 J 400 6 7 9 8 . 5 J 28 - 0 3 M W - 3 2 9 - F e b - 1 6 4 4 . 8 J 0 . 3 9 J 0 . 3 3 J 0 . 1 7 J 0 . 5 2 J 85 , 5 5 0 0. 0 6 J 55 2 2.0 J 0 . 9 0 J 0. 9 2 J 344 5 5 3 2 . 1 J 28 - 0 3 M W - 8 2 2 - A u g - 1 1 4 . 2 J 2 5 3 0 . 7 4 J 4 . 5 J 0 . 1 2 J 7 . 7 J 31 , 1 2 5 0. 1 1 J 10 1 1.3 J 0 . 0 5 J 8.4 J 3.1 J 128 2,724 213J 28 - 0 3 M W - 8 1 6 - F e b - 1 2 3 . 3 J 2 3 7 0 . 5 J 3 . 6 J 0 . 2 4 J 6 . 0 J 24 , 1 5 0 0. 1 6 J 16 6 1.8 J 1 4 5.4 J 2.7 J 179 2,699 166J 28 - 0 3 M W - 8 1 4 - A u g - 1 2 0 . 0 4 J 4 . 1 J 1 9 2 0 . 9 6 J 5 . 4 J 0 . 1 5 J 5 . 1 J 35 , 1 5 0 0. 1 7 J 95 1.6 J 1 6 11 . 1 J 5.2 J 157 2,693 191J 28 - 0 3 M W - 8 2 8 - F e b - 1 3 9 J 1 9 7 0 . 4 7 J 3 . 6 J 0 . 2 8 J 8 . 0 J 20 , 9 5 0 1 3 0 1.8 J 6.3 J 2.4 J 177 3,049 191J 28 - 0 3 M W - 8 3 0 - S e p - 1 3 0 . 0 5 J 5 . 2 J 2 1 5 0 . 3 2 J 2 . 8 J 0 . 1 5 J 4 . 9 J 41 , 4 8 0 0. 0 4 J 72 0.0 4 J 1 . 6 J 1 9 4.1 J 3.6 J 173 2,724 171J 28 - 0 3 M W - 8 1 7 - F e b - 1 4 0 . 1 2 J 2 1 3 0 . 2 4 J 2 . 2 J 0 . 1 8 J 1 0 7,5 2 5 0. 3 1 J 17 9 3.8 J 2.2 J 7.6 J 129 2,700 187J 28 - 0 3 M W - 8 2 6 - A u g - 1 4 5 . 2 J 2 3 9 0 . 2 7 J 3 . 5 J 0 . 1 4 J 1 1 34 , 1 5 0 1 9 2 2.1 J 25 1 . 7 J 6.6 J 144 2,360 140J 28 - 0 3 M W - 8 2 7 - F e b - 1 5 7 J 3 2 1 0 . 5 2 J 2 . 7 J 0 . 1 5 J 8 . 8 J 20 , 4 7 5 0. 4 3 J 20 6 1.9 J 7.0 J 10 74 2,620 180J 28 - 0 3 M W - 8 2 6 - O c t - 1 5 0 . 1 2 J 8 J 2 3 . 1 J 0 . 2 3 J 2 . 1 J 0 . 2 0 J 8 . 0 J 35 , 8 8 3 0. 2 7 J 23 6 2.6 J 0 . 0 3 J 0 . 0 5 J 1.8 J 7.8 J 73 5 3 1 1 9 J 28 - 0 3 M W - 8 2 9 - F e b - 1 6 2 6 3 0 . 3 5 J 2 . 4 J 0 . 1 7 J 8 . 6 J 23 , 1 4 5 0. 3 9 J 26 1 0.0 6 J 2 . 2 J 2.5 J 11 129 2,800 133J Vo l a t i l e O r g a n i c C o m p o u n d s No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d So l i d W a s t e S e c t i o n L i m i t Me t a l s General Chemistry Pa g e 1 o f 5 April 2016 Ta b l e 3 a De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s , V o l a t i l e O r g a n i c C o m p o u n d s , a n d G e n e r a l C h e m i s t r y Fe b r u a r y 2 0 1 6 S e m i - A n n u a l S a m p l i n g E v e n t Da r e C o u n t y C & D L a n d f i l l Fa c i l i t y Pe r m i t Nu m b e r Mo n i t o r i n g We l l C o d e Sa m p l e Da t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r I r o n L e a d M a n g a n e s e M e r c u r y N i c k e l S e l e n i u m S i l v e r T h a l l i u m V a n a d i u m Z i n c A c e t o n e B e n z e n e C a r b o n D i s u l f i d e C h l o r o b e n z e n e C h l o r o m e t h a n e Toluene Alkalinity Chloride Sulfate 1* 1 0 7 0 0 4 * 2 1 0 1 * 1 , 0 0 0 3 0 0 1 5 5 0 1 1 0 0 2 0 2 0 0 . 2 * 0 . 3 * 1 , 0 0 0 6 , 0 0 0 1 7 0 0 5 0 3 6 0 0 N S 2 5 0 2 5 0 6 1 0 1 0 0 1 1 1 0 1 0 1 0 3 0 0 1 0 5 0 0 . 2 5 0 1 0 1 0 5 . 5 2 5 1 0 1 0 0 1 1 0 0 3 1 1 N E N E 2 5 0 Vo l a t i l e O r g a n i c C o m p o u n d s No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d So l i d W a s t e S e c t i o n L i m i t Me t a l s General Chemistry 28 - 0 3 M W - 9 2 2 - A u g - 1 1 21 35 . 8 J 0 . 1 8 J 0 . 1 6 J 6 . 1 J 5.6 J 2. 8 J 19 4 , 7 5 0 2.6 J 16 2 7.1 J 1 . 0 J 0 . 1 2 J 9.4 J 47 38 1 2 1 9 4 J 28 - 0 3 M W - 9 1 6 - F e b - 1 2 0 . 2 1 J 24 9 47 . 4 J 0 . 4 5 J 0 . 1 8 J 14 3 . 2 J 5. 1 J 68 , 0 7 5 8.1 J 69 3.6 J 1 . 5 J 0 . 0 7 J 0 . 0 8 J 31 21 11 1 6 1 2 0 J 28 - 0 3 M W - 9 1 4 - A u g - 1 2 0 . 1 2 J 36 25 . 3 J 0 . 2 6 J 0 . 2 0 J 6 . 4 J 3.6 J 3. 3 J 9,7 2 5 3.5 J 3 7 J 0 . 0 2 J 4 . 1 J 0 . 7 2 J 0.2 1 J 1 1 . 5 J 22 21 1 6 7 4 . 6 J 28 - 0 3 M W - 9 2 8 - F e b - 1 3 22 27 . 3 J 0 . 1 8 J 0 . 0 8 J 7 . 6 J 1.9 J 3. 3 J 14 , 4 7 0 5.2 J 2 7 J 3 . 3 J 0 . 9 1 J 0 . 1 0 J 13 . 9 J 10 76 7 3 5 . 8 J 28 - 0 3 M W - 9 3 0 - S e p - 1 3 0 . 1 2 J 28 21 . 8 J 0 . 1 8 J 0 . 1 7 J 4 . 2 J 1.9 J 2. 9 J 24 , 6 5 0 2.2 J 2 7 J 0 . 0 3 J 3 . 5 J 1 . 4 J 0 . 0 7 J 11 . 9 J 11 57 1 2 6 2 . 1 J 28 - 0 3 M W - 9 1 7 - F e b - 1 4 0 . 0 4 J 10 23 . 3 J 0 . 1 7 J 0 . 1 3 J 6 . 2 J 1.8 J 2. 6 J 6,1 1 5 3.4 J 3 6 J 3 . 3 J 1 . 7 J 0 . 0 5 J 9.1 J 7.0 J 31 7 3 7 . 6 J 28 - 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0 3 M W - 1 2 2 6 - A u g - 1 4 0 . 1 4 J 1 . 6 J 4 2 . 2 J 0 . 1 4 J 0 . 0 7 J 1 . 9 J 1 . 0 J 1 . 4 J 4,2 1 0 1.5 J 88 4.8 J 0 . 5 2 J 3.5 J 8.5 J 4 2 4 2 1 . 5 J 28 - 0 3 M W - 1 2 2 7 - F e b - 1 5 0 . 8 5 J 3 6 . 0 J 0 . 1 1 J 0 . 0 6 J 1 . 2 J 0 . 3 9 J 1 . 3 J 56 8 0. 9 2 J 3 9 J 1 . 7 J 0 . 4 1 J 2.4 J 5.7 J 7 1 1 1 1 . 3 J 28 - 0 3 M W - 1 2 2 6 - O c t - 1 5 0 . 1 7 J 1 . 5 J 3 0 . 9 J 0 . 1 2 J 0 . 1 2 J 1 . 9 J 0 . 8 1 J 1 . 3 J 4,4 6 8 1.2 J 4 1 J 3 . 0 J 0 . 7 5 J 0 . 0 3 J 0 . 0 4 J 3.2 J 7.1 J 23 28 - 0 3 M W - 1 2 2 9 - F e b - 1 6 0 . 0 6 J 0 . 7 7 J 2 3 . 1 J 0 . 1 0 J 1 . 4 J 0 . 5 5 J 0 . 8 6 J 3,3 4 1 0. 6 8 J 3 7 J 2 . 6 J 0 . 0 8 J 2.0 J 3.5 J 4 1 9 5 . 3 J Pa g e 2 o f 5 April 2016 Ta b l e 3 a De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s , V o l a t i l e O r g a n i c C o m p o u n d s , a n d G e n e r a l C h e m i s t r y Fe b r u a r y 2 0 1 6 S e m i - A n n u a l S a m p l i n g E v e n t Da r e C o u n t y C & D L a n d f i l l Fa c i l i t y Pe r m i t Nu m b e r Mo n i t o r i n g We l l C o d e Sa m p l e Da t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r I r o n L e a d M a n g a n e s e M e r c u r y N i c k e l S e l e n i u m S i l v e r T h a l l i u m V a n a d i u m Z i n c A c e t o n e B e n z e n e C a r b o n D i s u l f i d e C h l o r o b e n z e n e C h l o r o m e t h a n e Toluene Alkalinity Chloride Sulfate 1* 1 0 7 0 0 4 * 2 1 0 1 * 1 , 0 0 0 3 0 0 1 5 5 0 1 1 0 0 2 0 2 0 0 . 2 * 0 . 3 * 1 , 0 0 0 6 , 0 0 0 1 7 0 0 5 0 3 6 0 0 N S 2 5 0 2 5 0 6 1 0 1 0 0 1 1 1 0 1 0 1 0 3 0 0 1 0 5 0 0 . 2 5 0 1 0 1 0 5 . 5 2 5 1 0 1 0 0 1 1 0 0 3 1 1 N E N E 2 5 0 Vo l a t i l e O r g a n i c C o m p o u n d s No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d So l i d W a s t e S e c t i o n L i m i t Me t a l s General Chemistry 28 - 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0 3 M W - 1 6 2 7 - F e b - 1 5 0 . 1 7 J 3 . 1 J 2 1 9 0 . 1 7 J 2 . 5 J 0 . 4 4 J 2 . 8 J 23 , 9 0 0 3 9 6 3.7 J 8 . 3 J 3.9 J 2.9 J 529 792 196J 28 - 0 3 M W - 1 6 2 7 - O c t - 1 5 0 . 1 0 J 4 . 3 J 2 4 4 0 . 2 2 J 3 . 0 J 0 . 3 2 J 2 . 8 J 58 , 3 2 5 0. 1 6 J 28 3 0.0 6 J 3 . 5 J 0 . 0 3 J 3.6 J 4.2 J 75 1,380 96.5J 28 - 0 3 M W - 1 6 2 9 - F e b - 1 6 0 . 0 8 J 4 . 9 J 2 8 4 0 . 6 2 J 2 . 1 J 0 . 2 4 J 4 . 9 J 57 , 9 1 7 2 6 5 2.6 J 2.8 J 2.1 J 163 1,360 84.2J Pa g e 3 o f 5 April 2016 Ta b l e 3 a De t e c t e d G r o u n d w a t e r C o n s t i t u e n t s - M e t a l s , V o l a t i l e O r g a n i c C o m p o u n d s , a n d G e n e r a l C h e m i s t r y Fe b r u a r y 2 0 1 6 S e m i - A n n u a l S a m p l i n g E v e n t Da r e C o u n t y C & D L a n d f i l l Fa c i l i t y Pe r m i t Nu m b e r Mo n i t o r i n g We l l C o d e Sa m p l e Da t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r I r o n L e a d M a n g a n e s e M e r c u r y N i c k e l S e l e n i u m S i l v e r T h a l l i u m V a n a d i u m Z i n c A c e t o n e B e n z e n e C a r b o n D i s u l f i d e C h l o r o b e n z e n e C h l o r o m e t h a n e Toluene Alkalinity Chloride Sulfate 1* 1 0 7 0 0 4 * 2 1 0 1 * 1 , 0 0 0 3 0 0 1 5 5 0 1 1 0 0 2 0 2 0 0 . 2 * 0 . 3 * 1 , 0 0 0 6 , 0 0 0 1 7 0 0 5 0 3 6 0 0 N S 2 5 0 2 5 0 6 1 0 1 0 0 1 1 1 0 1 0 1 0 3 0 0 1 0 5 0 0 . 2 5 0 1 0 1 0 5 . 5 2 5 1 0 1 0 0 1 1 0 0 3 1 1 N E N E 2 5 0 Vo l a t i l e O r g a n i c C o m p o u n d s No r t h C a r o l i n a 2 L o r G r o u n d w a t e r Pr o t e c t i o n S t a n d a r d So l i d W a s t e S e c t i o n L i m i t Me t a l s General Chemistry 28 - 0 3 M W - 1 7 1 8 - O c t - 1 1 30 63 . 5 J 1 0 . 3 3 J 2 . 9 J 3.7 J 1. 4 J 47 , 8 7 5 1.8 J 19 4 7.9 J 0 . 9 1 J 0 . 0 3 J 8.3 J 95 7 19 287 28 - 0 3 M W - 1 7 1 6 - F e b - 1 2 4 . 1 J 3 6 . 8 J 0 . 9 J 0 . 2 1 J 1 . 8 J 3.1 J 1. 1 J 7,7 4 8 1.4 J 98 6.3 J 0 . 5 1 J 2.1 J 38 2 22 372 28 - 0 3 M W - 1 7 1 4 - A u g - 1 2 11 43 . 5 J 0 . 8 0 J 0 . 1 9 J 2 . 5 J 2.9 J 1. 1 J 30 , 8 0 0 1.5 J 89 7.8 J 0 . 6 9 J 6.1 J 20 1 4 2 3 2 2 5 J 28 - 0 3 M W - 1 7 2 8 - F e b - 1 3 0 . 0 4 J 1 . 3 J 3 1 . 1 J 0 . 3 6 J 0 . 1 0 J 1 . 1 J 3.8 J 1. 6 J 8,4 8 0 1.1 J 53 5.9 J 0 . 6 0 J 0 . 0 8 J 1.9 J 10 3 1 1 5 1 4 0 J 28 - 0 3 M W - 1 7 3 0 - S e p - 1 3 0 . 0 9 J 6 J 1 7 . 3 J 0 . 1 1 J 0 . 0 5 J 1 . 6 J 0 . 3 1 J 1 . 2 J 28 , 4 5 0 0. 3 1 J 93 0.0 5 J 2 . 3 J 1 . 3 J 0 . 0 3 J 3.6 J 33 61 1 7 1 2 1 J 28 - 0 3 M W - 1 7 1 7 - F e b - 1 4 0 . 5 4 J 2 9 . 0 J 0 . 1 8 J 0 . 1 5 J 1 . 5 J 1.3 J 2. 3 J 73 8 0. 5 2 J 4 3 J 3 . 3 J 0 . 7 3 J 1.2 J 88 13 1 1 4 J 28 - 0 3 M W - 1 7 2 6 - A u g - 1 4 5 . 8 J 4 2 . 6 J 0 . 1 4 J 0 . 0 4 J 2 . 2 J 1.5 J 1. 1 J 16 , 0 2 5 1.3 J 51 4.1 J 0 . 6 9 J 5.8 J 40 13 1 1 1 0 1 J 28 - 0 3 M W - 1 7 2 7 - F e b - 1 5 1 . 2 J 3 1 . 5 J 0 . 1 5 J 0 . 1 0 J 1 . 2 J 0 . 8 8 J 1 . 5 J 1,7 0 6 1.1 J 2 8 J 2 . 2 J 0 . 4 0 J 2.8 J 26 4 7 1 9 . 4 J 28 - 0 3 M W - 1 7 2 7 - O c t - 1 5 1. 1 J 2.4 J 3 8 . 8 J 0 . 2 2 J 0 . 1 1 J 2 . 3 J 0 . 7 6 J 1 . 4 J 8,4 4 5 2.2 J 3 8 J 0 . 0 5 J 1 . 7 J 0 . 8 0 J 0 . 0 6 J 0 . 0 6 J 4.7 J 57 2 8 5 9 . 5 J 28 - 0 3 M W - 1 7 2 9 - F e b - 1 6 0 . 0 9 J 2 . 8 J 4 4 . 2 J 0 . 2 2 J 0 . 0 6 J 2 . 1 J 1.1 J 2. 5 J 10 , 3 3 1 3.8 J 3 5 J 2 . 5 J 0 . 8 2 J 7.1 J 45 8 1 9 7 5 . 4 J No t e s : 1. M e t a l a n d v o l a t i l e o r g a n i c c o m p o u n d u n i t s a r e i n m i c r o g r a m s p e r l i t e r ( p a r t s p e r b i l l i o n ) . 2. G e n e r a l c h e m i s t r y u n i t s a r e i n m i l l i g r a m s p e r l i t e r ( p a r t s p e r m i l l i o n ) . 3. * - G r o u n d w a t e r P r o t e c t i o n S t a n d a r d 4. N E = N o t E s t a b l i s h e d 5. N S = N o S t a n d a r d 6. J - I n d i c a t e s t h e a n a l y t i c a l r e s u l t i s a n e s t i m a t e d c o n c e n t r a t i o n b e t w e e n t h e m e t h o d d e t e c t i o n l i m i t a n d t h e S o l i d W a s t e S e c t i o n R e p o r t i n g L i m i t . - B l a n k c e l l i n d i c a t e s t h e a n a l y t e w a s n o t d e t e c t e d - C o n c e n t r a t i o n e x c e e d s t h e 1 5 A N C A C 0 2 L . 0 2 0 2 ( N o r t h C a r o l i n a 2 L ) o r G r o u n d w a t e r P r o t e c t i o n S t a n d a r d Pa g e 4 o f 5 April 2016 Ta b l e 3 b De t e c t e d S u r f a c e W a t e r C o n s t i t u e n t s - M e t a l s , V o l a t i l e O r g a n i c C o m p o u n d s , a n d G e n e r a l C h e m i s t r y Fe b r u a r y 2 0 1 6 S e m i - A n n u a l S a m p l i n g E v e n t Da r e C o u n t y C & D L a n d f i l l Fa c i l i t y Pe r m i t Nu m b e r Su r f a c e Wa t e r C o d e Sa m p l e Da t e A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m C a d m i u m C h r o m i u m C o b a l t C o p p e r I r o n L e a d M a n g a n e s e M e r c u r y N i c k e l S e l e n i u m S i l v e r T h a l l i u m V a n a d i u m Z i n c A c e t o n e B e n z e n e C h l o r o b e n z e n e C h l o r o m e t h a n e 1,4-DichlorobenzeneTolueneAlkalinityChloride Sulfate 64 0 * 1 0 2 0 0 , 0 0 0 * 6 . 5 0 . 1 5 2 4 4 * 2 . 7 N S 0 . 5 4 N S 0 . 0 1 2 1 6 5 0 . 0 6 0 . 4 7 * N S 3 6 2 , 0 0 0 51 * 14 0 96 * 100 1 1 N S 230 **NS 10 1 0 1 0 0 1 1 1 0 1 0 1 0 3 0 0 1 0 5 0 0 . 2 5 0 1 0 1 0 5 . 5 2 5 1 0 1 0 0 1 3 1 1 1 1 N E 2 5 0 28 - 0 3 SW - 1 22 - A u g - 1 1 2. 8 J 23 . 7 J 0.1 7 J 0. 5 4 J 1.4 J 27 4 J 0.1 9 J 63 5 2.5 J 2.0 J 2. 9 J 2.4 J 214 392 76.3J 28 - 0 3 SW - 1 16 - F e b - 1 2 2. 1 J 93 J 0.1 9 J 1.0 J 2.1 J 40 3 0.1 7 J 20 1 3.9 J 7. 2 J 0. 7 2 J 0. 9 2 J 158 935 170J 28 - 0 3 SW - 1 14 - A u g - 1 2 2. 3 J 65 . 1 J 0. 6 4 J 2.2 J 65 1 0.3 8 J 22 5 3.4 J 5. 9 J 0. 5 9 J 4.7 J 143 717 158J 28 - 0 3 SW - 1 28 - F e b - 1 3 1.7 J 1. 8 J 13 . 5 J 0.8 5 J 0. 2 8 J 1.7 J 4, 2 2 0 35 14 J 0. 8 2 J 0.8 2 J 2. 2 J 4.8 J 5 145 28 - 0 3 SW - 1 30 - S e p - 1 3 0. 0 9 J 2. 5 J 31 . 8 J 0.0 9 J 0.7 7 J 0. 3 1 J 1.7 J 83 2 0.3 1 J 20 1 0. 0 3 J 2.8 J 3.1 J 2. 8 J 2J 224 304 30.2J 28 - 0 3 SW - 1 17 - F e b - 1 4 0. 4 1 J 2. 1 J 25 . 5 J 0.0 7 J 3. 0 J 0. 6 6 J 2.0 J 3, 5 8 0 8. 7 J 14 5 3.4 J 3.3 J 2. 3 J 4.4 J 92 208 38.8J 28 - 0 3 SW - 1 26 - A u g - 1 4 0. 1 4 J 2. 7 J 25 . 7 J 0.0 7 J 1. 2 J 0. 3 6 J 1.5 J 2, 4 2 6 8. 6 J 10 1 2.5 J 3.5 J 3. 3 J 2.9 J 177 294 39.1J 28 - 0 3 SW - 1 27 - F e b - 1 5 0. 4 4 J 2. 1 J 32 . 5 J 0.2 7 J 0. 0 5 J 3. 9 J 1.4 J 3.3 J 5, 8 8 5 6. 9 J 19 7 3.3 J 1.3 J 7. 7 J 12 129 165 61.6J 28 - 0 3 SW - 1 27 - O c t - 1 5 0. 1 8 J 2. 4 J 26 . 6 J 0.1 7 J 1. 5 J 0. 4 4 J 1.3 J 3, 2 7 7 2. 4 J 19 2 2.3 J 1.8 J 4. 3 J 2.6 J 152 175 49.4J 28 - 0 3 SW - 1 29 - F e b - 1 6 0. 2 7 J 0.7 0 J 24 . 2 J 0.0 8 J 1. 2 J 0. 2 2 J 1.7 J 2, 9 1 4 21 25 J 0. 8 8 J 1.6 J 1. 0 J 5.1 J 12 153 8.9J 28 - 0 3 SW - 2 18 - O c t - 1 1 0. 2 1 J 3. 5 J 53 . 3 J 0.7 0 J 0. 7 4 J 3.3 J 2, 3 9 6 13 15 3 2.7 J 7. 4 J 0. 9 4 J 9.4 J 91 1,170 127J 28 - 0 3 SW - 2 16 - F e b - 1 2 2. 9 J 97 . 3 J 0.9 5 J 1.4 J 2.9 J 2, 9 6 8 4. 9 J 27 4 4.4 J 6. 5 J 1. 2 J 7.6 J 143 935 165J 28 - 0 3 SW - 2 14 - A u g - 1 2 0. 1 4 J 3. 0 J 56 . 0 J 0.9 3 J 0. 6 2 J 2.0 J 2, 3 8 9 4. 3 J 11 6 3.0 J 4.2 J 0. 8 0 J 5.4 J 128 549 150J 28 - 0 3 SW - 2 28 - F e b - 1 3 0. 4 9 J 2. 3 J 35 . 4 J 0.1 1 J 2. 0 J 1.1 J 3.2 J 5, 1 5 5 7. 8 J 16 9 3.1 J 2.6 J 3. 2 J 15 96 276 53.5J 28 - 0 3 SW - 2 30 - S e p - 1 3 0. 0 8 J 2. 1 J 33 . 8 J 0.0 7 J 0.7 0 J 0. 2 8 J 1.9 J 1, 3 5 8 0. 7 3 J 94 0. 0 3 J 2.6 J 3.3 J 1. 8 J 2.1 J 203 372 22.3J 28 - 0 3 SW - 2 17 - F e b - 1 4 0. 3 3 J 1. 4 J 23 . 1 J 0.0 4 J 3. 1 J 0. 5 0 J 2.6 J 4, 0 8 0 5. 6 J 13 3 3.0 J 2.6 J 2. 0 J 5.8 J 93 192 56.1J 28 - 0 3 SW - 2 26 - A u g - 1 4 0. 1 7 J 2. 3 J 26 . 7 J 0.0 5 J 1. 1 J 0. 2 7 J 1.5 J 1, 2 9 3 2. 4 J 36 J 2.7 J 3.7 J 2. 2 J 3.3 J 175 292 20.7J 28 - 0 3 SW - 2 27 - F e b - 1 5 0. 6 8 J 3. 6 J 32 . 1 J 0.2 1 J 0. 0 5 J 4. 6 J 1.1 J 4.0 J 4, 1 9 5 6. 4 J 16 1 3.2 J 1.3 J 5. 8 J 16 132 145 57.6J 28 - 0 3 SW - 2 27 - O c t - 1 5 0. 2 0 J 2. 5 J 29 . 4 J 0.1 6 J 1. 8 J 0. 3 5 J 1.6 J 3, 5 4 3 5. 5 J 81 2.3 J 2.4 J 3. 5 J 3.5 J 146 195 52.5J 28 - 0 3 SW - 2 29 - F e b - 1 6 0. 3 0 J 1. 4 J 21 . 1 J 0.2 9 J 3. 2 J 0. 7 5 J 1.9 J 4, 0 2 1 13 93 2.9 J 1.8 J 3. 7 J 4.6 J 103 94 23.3J 28 - 0 3 SW - 3 22 - A u g - 1 1 4. 5 J 44 . 1 J 0.5 3 J 0. 9 3 J 3.3 J 1, 1 4 2 2. 8 J 10 6 3.2 J 6. 3 J 3. 2 J 5.2 J 178 965 117J 28 - 0 3 SW - 3 16 - F e b - 1 2 2. 7 J 94 . 4 J 0.6 4 J 0.9 J 2.2 J 92 4 2. 1 J 24 9 3.8 J 8. 1 J 0. 7 2 J 2.9 J 159 910 153J 28 - 0 3 SW - 3 14 - A u g - 1 2 0. 1 7 J 2. 9 J 55 . 4 J 0.8 6 J 0. 6 0 J 1.9 J 2, 2 7 4 3. 6 J 11 7 2.9 J 4.6 J 0. 6 0 J 4.8 J 116 567 144J 28 - 0 3 SW - 3 28 - F e b - 1 3 0. 4 8 J 2. 2 J 36 . 4 J 0.1 2 J 0. 0 4 J 2. 5 J 1.0 J 4.1 J 5, 6 5 0 8. 4 J 16 2 3.1 J 2.2 J 4. 0 J 10 99 270 43.0J 28 - 0 3 SW - 3 30 - S e p - 1 3 0. 1 0 J 4. 3 J 48 . 7 J 0.1 6 J 1. 8 J 0. 9 7 J 3.2 J 9, 6 4 0 6. 8 J 39 8 0. 0 4 J 3.4 J 3.2 J 4. 9 J 11 202 342 22.1J 28 - 0 3 SW - 3 17 - F e b - 1 4 0. 1 1 J 2. 1 J 21 . 1 J 0.0 3 J 2. 0 J 0. 4 3 J 2.9 J 2, 1 9 8 2. 2 J 89 2.7 J 4.7 J 1. 2 J 4.0 J 129 318 29.6J 28 - 0 3 SW - 3 26 - A u g - 1 4 0. 2 1 J 2. 7 J 27 . 3 J 0.0 7 J 1. 3 J 0. 3 1 J 1.7 J 1, 8 8 3 4. 2 J 43 J 0. 4 5 2.3 J 3.7 J 2. 1 J 4.0 J 173 290 39.9J 28 - 0 3 SW - 3 27 - F e b - 1 5 0. 6 8 J 3. 7 J 31 . 5 J 0.2 2 J 0. 0 6 J 4. 6 J 1.1 J 4.0 J 4, 0 6 0 6. 4 J 15 6 3.1 J 1.4 J 5. 9 J 19 121 140 69.5J 28 - 0 3 SW - 3 27 - O c t - 1 5 0. 2 3 J 2. 2 J 28 . 3 J 0.1 1 J 1. 6 J 0. 3 6 J 1.7 J 3, 8 7 9 5. 7 J 74 2.2 J 1.8 J 3. 8 J 4.5 J 142 199 24.8J 28 - 0 3 SW - 3 29 - F e b - 1 6 0. 3 0 J 2. 0 J 22 . 7 J 0.3 6 J 0. 0 5 J 4. 1 J 0. 8 6 J 2.0 J 4, 7 7 3 15 11 9 3.2 J 2.2 J 4. 2 J 5.5 J 110 92 33.1J No t e s : 1. M e t a l a n d v o l a t i l e o r g a n i c c o m p o u n d c o n c e n t r a t i o n s a r e i n m i c r o g r a m s p e r l i t e r ( p a r t s p e r b i l l i o n ) . 2. G e n e r a l c h e m i s t r y c o n c e n t r a t i o n s a r e i n m i l l i g r a m s p e r l i t e r ( p a r t s p e r m i l l i o n ) . 3. S t a n d a r d s o b t a i n e d f r o m 1 5 A N C A C 0 2 B ( N o r t h C a r o l i n a 2 B ) S u r f a c e W a t e r S t a n d a r d s f o r C l a s s C W a t e r s o r a r e N a t i o n a l C r i t e r i a p e r t h e U . S . E n v i r o n m e n t a l P r o t e c t i o n A g e n c y ( M a r c h 2 0 1 6 ) . 4. * - H u m a n H e a l t h S t a n d a r d 6. N S = N o S t a n d a r d N E = N o t E s t a b l i s h e d 7. J - I n d i c a t e s t h e a n a l y t i c a l r e s u l t i s a n e s t i m a t e d c o n c e n t r a t i o n b e t w e e n t h e m e t h o d d e t e c t i o n l i m i t a n d t h e S o l i d W a s t e S e c t i o n R e p o r t i n g L i m i t . - B l a n k c e l l i n d i c a t e s t h e a n a l y t e w a s n o t d e t e c t e d - C o n c e n t r a t i o n e x c e e d s t h e N o r t h C a r o l i n a 2 B F r e s h w a t e r A q u a t i c L i f e o r H u m a n H e a l t h S t a n d a r d f o r C l a s s C W a t e r s No r t h C a r o l i n a 2 B F r e s h w a t e r Aq u a t i c L i f e o r H u m a n H e a l t h St a n d a r d Vo l a t i l e O r g a n i c C o m p o u n d s So l i d W a s t e S e c t i o n L i m i t Me t a l s General Chemistry Pa g e 5 o f 5 April 2016 Appendix A c d m s m i t h . c o m