2201_ClayCounty_GWMReport_DIN26401_20151215

Prepared for
Clay County, North Carolina
Project Number 2367.01

Prepared by
Altamont Environmental, Inc.
231 Haywood Street
Asheville, NC 28801
828.281.3350

December 2015
Water Quality Monitoring Report
Clay County Closed
Municipal Solid Waste Landfill
Clay County, North Carolina
Permit #22-01
March 25, 2016

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Table of Contents
1.0 Introduction .................................................................................................................... 1
2.0 Methods ......................................................................................................................... 2
2.1 Groundwater and Surface Water Sampling ...................................................................2
2.1.1 Groundwater Purging and Sampling Methods ..................................................2
2.1.2 Surface Water Sampling Methods ....................................................................2
2.2 Sample Handling, Documentation, and Analysis...........................................................2
3.0 Analytical Results ........................................................................................................... 4
3.1 Groundwater ..................................................................................................................4
3.1.1 Appendix I Metals (EPA Methods 6010 and 7470) ..........................................4
3.1.2 Appendix I VOCs (EPA Method 8260) ...............................................................5
3.1.3 Field Parameters ...............................................................................................5
3.2 Surface Water ................................................................................................................5
3.2.1 Appendix I Metals (EPA Methods 6010 and 7470) ..........................................5
3.2.2 Appendix I VOCs (EPA Method 8260) ...............................................................5
3.2.3 Field Parameters ...............................................................................................5
4.0 Summary and Discussion............................................................................................... 6
4.1 Groundwater Quality ......................................................................................................6
4.2 Surface Water Quality ....................................................................................................6
4.3 Future Activities .............................................................................................................6

Figures
1. Site Location Map
2. Site Layout Map
3. Posted Groundwater Elevation Map
Tables
1. Summary of Groundwater Elevation Data
2. Summary of Laboratory Analyses Performed on Samples
3. Summary of Detected Compounds
4. Solid Waste Section Limits Exceedances Notification
5. Water Quality Standards Exceedances Notification

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Appendices
A. Field Sheet and Certificate of Analysis
B. Reports of Laboratory Analysis and Chain-of-Custody Documentation
C. Environmental Monitoring Reporting Form and Electronic Submittal of Environmental Monitoring
Data 2201Dec2015 (Electronic Submittal Only)

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1.0 Introduction
The Clay County Solid Waste Department maintains a solid waste facility located at 1160 Hinton Center
Road (State Road 1148) in Hayesville, Clay County, North Carolina (Figure 1). The facility accepts solid waste
from Clay County, and includes the following permitted components:
 A closed municipal solid waste (MSW) Landfill (closed landfill; Permit 22-01)
 An active transfer station (Permit 22-02T)
According to the Landfill Gas Monitoring Plan prepared by McGill Associates dated November 2010, the
landfill was officially closed per the letter to the North Carolina Department of Environment and Natural
Resources (DENR), now known as the Department of Environmental Quality (DEQ), dated December 21,
1995. The permit for the landfill requires annual monitoring of groundwater and surface water quality. This
report describes a groundwater and surface water quality sampling event conducted in December 2015.
This report is being submitted in accordance with monitoring requirements for closed landfills as stipulated
in the DEQ Division of Waste Management (DWM) Permit No. 22-01 and its amendments dated April 19,
1990, issued to the Clay County Solid Waste Department, as well as requirements stipulated in the DEQ
Solid Waste Management Rules Title 15A, Subchapter 13B, Section .1600, of the North Carolina
Administrative Code (15A NCAC 13B.1600).
This report presents analytical results and provides an evaluation of groundwater and surface water quality
for the closed landfill.

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2.0 Methods
2.1 Groundwater and Surface Water Sampling
The groundwater monitoring network consists of an upgradient, background monitoring well (MW-1), and five
downgradient monitoring wells (MW-2, MW-3, MW-4, MW-5, and MW-6). MW-1 is located in the northern
portion of the landfill, north of a closed MSW disposal cell and Clay County’s wood waste treatment and
processing area. MW-2 is located in the southeast corner of the facility property on the north side of S.R.
1148, south of a closed MSW landfill cell. MW-3 and MW-4 are located along or near the southernmost
property line of the landfill downgradient of a closed MSW landfill cell. MW-5 and MW-6 are located along the
southwestern property line of the facility downgradient of a closed MSW landfill cell. A map depicting the
location of the monitoring wells is included as Figure 2.
In October 2011, Samuel L. Sprinkle & Associates, P.A., a professional surveying firm certified in the state of
North Carolina, surveyed the horizontal and vertical locations of the monitoring wells associated with the
Clay County Landfill. The certified survey data were presented in a previous monitoring report (Altamont
2012).
Monitoring wells associated with the closed landfill (MW-1, MW-2, MW-3, MW-4, MW-5, and MW-6) and
surface water sample locations (UPSTREAM and DOWNSTREAM) were sampled by Environmental, Inc., of
Sylva, North Carolina, on December 15, 2015. Approximate sample locations are depicted on Figure 2.
Prior to collecting groundwater samples from the monitoring wells, the static water level and total depth at
each of the wells was measured and recorded. These data are presented in Table 1 and shown on Figure 3.
Groundwater flow direction is interpreted to be generally to the southwest toward the Hiwassee River.
2.1.1 Groundwater Purging and Sampling Methods
Prior to sample collection at each monitoring well, field parameters consisting of temperature, pH, specific
conductivity, and turbidity were measured and recorded. A field data sheet and certificate of analysis
provided by Environmental, Inc. are presented in Appendix A. Groundwater monitoring wells were purged
with a new disposable polyethylene bailer before samples were collected.
2.1.2 Surface Water Sampling Methods
Surface water samples UPSTREAM and DOWNSTREAM were collected at designated locations along a minor
unnamed tributary and the Hiwassee River, respectively. These surface water bodies flow adjacent to the
western and southern Site boundary in a south-to-north direction as shown on Figure 2. The surface water
sample collected at the UPSTREAM location is assumed to represent surface water quality upstream of the
closed landfill, while the surface water sample collected at the DOWNSTREAM location is assumed to
represent surface water quality downstream of the closed landfill. One set of field parameters, including
temperature and pH, was measured and recorded at each surface water sampling location prior to sample
collection (Appendix A). Specific conductivity and turbidity were analyzed by Environmental Inc.’s certified, in-
house laboratory.
2.2 Sample Handling, Documentation, and Analysis
Field parameters and additional observations pertaining to the closed landfill sampling locations are
recorded on the certificate of analysis included in Appendix A. Following sample collection, groundwater and
surface water samples were transported to Pace Analytical Services, Inc. (Pace), a laboratory certified in
North Carolina, located in Asheville. Environmental, Inc. submitted the water samples collected from the
monitoring wells and the surface water sampling locations to Pace for analysis as follows:
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 Appendix I volatile organic compounds (VOCs) using US Environmental Protection Agency (EPA)
Approved Method 8260B
 Appendix I metals using EPA Approved Methods 6010A and 7470A
An equipment blank and trip blank, provided by the laboratory, were placed in the sample coolers and
analyzed for Appendix I VOCs and/or metals. Proper chain-of-custody documentation procedures were
followed during collection and transport of each sample. The laboratory analytical reports and chain-of-
custody documentation are included as Appendix B. Laboratory analyses performed on the samples are
summarized in Table 2.
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3.0 Analytical Results
The laboratory analytical results for groundwater, surface water, equipment blank, and trip blank samples
collected at the closed landfill are provided in the laboratory reports of analysis issued by Pace (Appendix B).
In addition, all the laboratory analytical results and measured field parameters are summarized in the
Electronic Data Deliverable (EDD) format (Appendix C) specified by the DEQ DWM Solid Waste Section (SWS).
As stipulated by the SWS, non-detections were reported at their method detection limits (MDL), and all
concentrations exceeding the laboratory-specific MDLs were reported and appropriately qualified (Tables 3,
4, and 5). The MDL is the minimum concentration of a substance that can be measured and reported by a
laboratory with 99 percent confidence that the analyte concentration is greater than zero. The method
reporting limit (MRL) is the minimum concentration of a target analyte that can be accurately determined by
the referenced method. All detections were compared to analyte-specific Solid Waste Section Limits (SWSLs)
established by the SWS. The SWSL is the lowest concentration, determined by the SWS, of an analyte in a
sample that can be quantitatively determined with suitable precision and accuracy. A “J” qualifier is used by
the laboratory for a parameter that is detected at an estimated concentration greater than the MDL but less
than the laboratory’s MRL. If the reported concentration is greater than the laboratory’s MRL and less than
the SWSL, the analytical result is qualified as estimated by Altamont per SWS requirements, and is flagged
with a “J” qualifier (italicized J-flag). Detected concentrations of constituents below the applicable SWSLs are
summarized in Table 3, but are not reported in the text of this report, unless they exceed their applicable
North Carolina water quality standards.
Detected concentrations of analytes in groundwater samples were compared to current groundwater quality
standards specified in 15A NCAC 2L.0202, which are referred to as 2L standards. Detected concentrations
of analytes in groundwater with no established 2L standards were compared either to the interim maximum
allowable concentrations (IMACs) for Class GA and GSA groundwater (in accordance with 15A NCAC 2L
.0202 [c]) or Groundwater Protection Standards (GWPSs), pursuant to 15A NCAC 13B.1634. Detections of
analytes in surface water samples were compared to 15A NCAC 2B surface-water quality standards (2B
standards).
Table 3 presents the summary of laboratory analytical results for detected constituents only. Table 4
presents all analytical results that were above the applicable SWSLs. Table 5 presents only the
concentrations of analytes detected in groundwater and/or surface water samples that exceeded their
respective 2L standards (including IMACs, if applicable), GWPSs, or 2B standards.
In the EDD (Appendix C), the identification of a well (“WELL ID” on the table) consists of the name of the well
prefaced by the un-hyphenated permit number for the facility. For example, the groundwater sample from
monitoring well “MW-2” is identified in the EDD as 2201-MW2. However, in the tables and figures of this
report, the identification of a well consists of the name of the well without the permit number associated
with the facility.
3.1 Groundwater
Analytical results for groundwater samples collected from monitoring wells are discussed below and are
summarized in Tables 3, 4, and 5 and in the EDD as Appendix C. The laboratory analytical reports are
included in Appendix B.
3.1.1 Appendix I Metals (EPA Methods 6010 and 7470)
Eleven metals were detected in one or more of the groundwater samples collected from the monitoring wells
at the landfill (Table 3). Eight of the detected metals (barium, cadmium, chromium, cobalt, copper, lead,
mercury, and zinc) were found at concentrations above their respective SWSLs in one or more of the
groundwater samples collected from the monitoring wells (Table 4). Thallium and zinc were detected in the
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equipment blank sample at concentrations of 6.4 µg/L and 5.8J µg/L, respectively. In addition, four metals
(cadmium, chromium, cobalt, and vanadium) had concentrations that exceeded either their respective 2L
standard or IMAC standard (Table 5) in one or more of the groundwater samples collected from the
monitoring wells. As noted on Table 5, with the exception of cadmium, detected metals could be naturally
occurring, as the three metals that met or exceeded applicable 2L standards or IMACs also exceeded these
standards in monitoring well MW-1, the background well.
3.1.2 Appendix I VOCs (EPA Method 8260)
Eight VOCs were detected in one or more of the groundwater samples collected from the monitoring wells
(Table 3). Two of the detected VOCs (1,4-dichlorobenzene and methylene chloride) were found at
concentrations above their SWSLs in one or more groundwater samples (Table 4). Methylene chloride was
detected above its 2L groundwater standard in monitoring well MW-5. The laboratory reported methylene
chloride detections with a “C9” qualifier, indicating that this constituent is a common laboratory contaminant
(Table 5). Methylene chloride was detected at the highest concentration in the equipment blank. Toluene
and trans-1,2-dichloroethene were also detected in the equipment blank, and methylene chloride was also
detected in the trip blank (Table 3).
3.1.3 Field Parameters
The pH readings obtained from all six monitoring wells were outside the acceptable range of 6.5 to 8.5
Standard Units (SU) specified in 15A NCAC 02L .0202[c] (Tables 3 and 5). Although the results were outside
the acceptable range, they generally appear to be consistent with the naturally occurring range of pH in the
region. This conclusion is based on the pH reading from background monitoring well MW-1, which was
recorded as 6.0 SU.
Turbidity values of the groundwater samples ranged from 4.6 nephelometric turbidity units (NTUs) to 151
NTUs (Table 3).
3.2 Surface Water
Analytical results for surface water samples collected from the Hiwassee River and its tributary are
discussed below and are summarized in Table 3 and in the EDD of Appendix C. Laboratory analytical reports
are included in Appendix B.
3.2.1 Appendix I Metals (EPA Methods 6010 and 7470)
Barium was detected in both surface water samples (Table 3) below its SWSL and 2B surface water
standard.
3.2.2 Appendix I VOCs (EPA Method 8260)
Methylene chloride was detected in the UPSTREAM surface water sample at a concentration of 1.1 µg/L
(Table 3), and was flagged with a C9 qualifier. Methylene chloride was detected at the highest concentration
in the equipment blank and was also detected in the trip blank.
3.2.3 Field Parameters
Turbidity and pH readings were obtained on December 15, 2015 for the surface water samples. The pH
readings measured in both samples were within the 2B standard range established at 6.0 SU to 9.0 SU. The
turbidity for the DOWNSTREAM and UPSTREAM surface water samples was recorded at 1.4 NTU and 1.2
NTU, respectively. These turbidity measurements are well below the 2B surface water standard of 50 NTUs.
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4.0 Summary and Discussion
The following discussion summarizes the results of the December 2015 water quality monitoring event.
4.1 Groundwater Quality
Analysis of data collected during the annual water quality monitoring event conducted on December 15,
2015 at the Clay County closed landfill indicates that eight metals were detected in the groundwater
samples at concentrations above their respective SWSLs. The concentrations of four of these metals
(cadmium, chromium, cobalt, and vanadium) exceeded their respective 2L standards or IMACs in one or
more of the groundwater samples. This sampling event is the first time cadmium has exceeded 2L standards
in any monitoring well on-Site, according to historical data. Chromium has been detected consistently in
monitoring wells MW-01, MW-02, and MW-03 historically, with occasional exceedances of 2L standards in
MW-01, the background well. Historical data shows consistent exceedances of cobalt in all monitoring wells,
with the exception of monitoring well MW-02 which has had no detections of cobalt historically. Vanadium
exceedances have been historically consistent in monitoring wells MW-01, MW-03, and MW-06.
The turbidity values measured from several of the monitoring well samples indicate that the samples
contained solid particles from the surrounding formation in which the wells are screened. The highest
turbidity recorded during this event was in monitoring well MW-01, at a reading of 151 NTUs. Naturally
occurring metals tend to adsorb to the surfaces of these solid particles. The concentrations of metals
detected in these groundwater samples may represent both the dissolved metals in the groundwater and the
metals that were adsorbed to the solid particles, potentially resulting in false positive results and/or higher
concentrations.
Two VOCs were detected at concentrations above their SWSL in one or more groundwater samples. 1,4-
dichlorobenzene was detected above its SWSL in monitoring wells MW-4 and MW-5. Methylene chloride was
detected above its SWSL in monitoring wells MW-2 and MW-5. One VOC (methylene chloride) was detected
at concentrations above established groundwater quality standards in one well at the closed landfill (MW-5).
Methylene chloride is a common laboratory contaminant and was also detected in the trip blank and
equipment blank; therefore, the detections of methylene chloride are not considered to be representative of
groundwater quality.
The pH readings obtained for the monitoring wells were outside the 2L standard acceptable pH range.
However, as discussed in Section 3.1.3, the pH readings appear to be generally consistent with the naturally
occurring range of pH in the region and correlate with background monitoring well MW-1.
4.2 Surface Water Quality
No metals were detected above SWSLs or applicable surface water quality standards in the UPSTREAM or
DOWNSTREAM samples. One VOC (methylene chloride, flagged with a C9 qualifier) was detected above its
SWSL in the UPSTREAM surface water sample. As previously discussed in Section 4.1, this is believed to be
due to laboratory contamination.
4.3 Future Activities
Environmental, Inc. will continue to collect groundwater and surface water samples on an annual basis at
the Clay County Closed Municipal Solid Waste Landfill. Altamont will continue to report the analytical results.
The next sampling event is scheduled for November 2016.

FIGURES





1





¦Legend
Subject Parcel
Data Sources:USGS Topgraphic Maps - Hayesville Quadrangle 1987Parcels - Clay County GIS


Subject Site
#
#
!A
!A
!A
!A
!A
!A
Upstream
Downstream
MW-1
MW-2
MW-3
MW-4
MW-5
MW-6
Ut
Hiw
a
s
s
e
e

R
i
v
e
r
Ut
Hiwa
s
s
e
e

R
i
v
e
r
1840
1
8
2
0
1
8
6
0
1880
1
9
2
0
194
0
1
9
6
0
1
9
8
0
2
0
2
0
1860
1840
1880
1860




2





¦





Legend
!A Monitoring Well
#Surface Water Location
Hydrology
Elevation Contour (20 ft)
Subject ParcelData Sources:Hydrology - NC OneMap 2001Basemap - USDA National AgriculturalImaging Program (October 2014)Parcels - Clay County GISElevation Contours - Clay County 2007


#
#
!A
!A
!A
!A
!A
!A
(1,809.27)
(1,807.46)
(1,811.63)
(1,830.75)
(1,846.60)
(1,949.43)
Upstream
Downstream
MW-1
MW-2
MW-3
MW-4
MW-5
MW-6
1840
1
8
2
0
1
8
6
0
1880
1
9
2
0
194
0
1
9
6
0
1
9
8
0
2
0
2
0
1860
1860
1840
1880
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
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Legend
!A Monitoring Well
#Surface Water Location
Hydrology
Subject Parcel
Elevation Contour (20 ft)
Data Sources:Hydrology - NC OneMap 2001Basemap - USDA National AgriculturalImaging Program (October 2014)Parcels - Clay County GISElevation Contours - Clay County 2007


(1,945.43) Groundwater Elevation
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

TABLES

Table 1
Summary of Groundwater Elevation Data
Clay County Municipal Solid Waste Landfill, Hayesville, Clay County, North Carolina
DEPTH TO
WATER
GROUNDWATER
ELEVATION
(feet NAVD 1988)(feet NAVD 1988) (feet TOC)(feet NAVD 1988)
MW-1 1992.05 1,993.10 43.67 1,949.43
MW-2 1868.94 1,869.77 23.17 1,846.60
MW-3 1835.67 1,837.75 7.00 1,830.75
MW-4 1819.19 1,821.30 9.67 1,811.63
MW-5 1840.53 1,841.63 34.17 1,807.46
MW-6 1825.64 1,826.52 17.25 1,809.27
Notes:
1. TOC = top of casing.
2. NAVD = North American Vertical Datum 1988.
3. All monitoring wells were surveyed on October 18, 2011 by Samuel L. Sprinkle & Associates, P.A..
4. Depth to water for all monitoring wells was measured on December 15, 2015.
WELL ID
TOP OF CASING
(TOC) ELEVATION
GROUND
ELEVATION
2015
P:\Environmental Inc\Clay County\Analytical & Data\Water\2015\Tables\2201Dec2015 T1 GW Elevation Data Page 1 of 1
Table 2
Summary of Laboratory Analyses Performed on Samples
Clay County Municipal Solid Waste Landfill, Hayesville, Clay County, North Carolina
Metals VOCs
EPA 6010
EPA 7470 EPA 8260
MW-1 12/15/2015 X X
MW-2 12/15/2015 X X
MW-3 12/15/2015 X X
MW-4 12/15/2015 X X
MW-6 12/15/2015 X X
MW-6 12/15/2015 X X
EQUIPMENT BLANK 12/15/2015 X X
TRIP BLANK 12/15/2015 X
Metals VOCs
EPA 6010
EPA 7470 EPA 8260
UPSTREAM 12/15/2015 X X
DOWNSTREAM 12/15/2015 X X
2. VOCs and metals analysis include Appendix I constituents per 40 CFR Part 258.
Notes:
1. VOCs = volatile organic compounds.
Groundwater Samples
Sample Name Date Collected
Surface Water Samples
Sample Name Date Collected
P:\Environmental Inc\Clay County\Analytical & Data\Water\2015\Tables\2201Dec2015 Tables 2,3,4,5 Page 1 of 1
Table 3
Summary of Detected Compounds
Clay County Municipal Solid Waste Landfill, Hayesville, Clay County, North Carolina
Metals
Lab Certification 40
Lab Method EPA 6010 and EPA 7470 (Mercury)
Parameter Barium Cadmium Chromium Cobalt Copper Lead Mercury Nickel Silver Thallium Vanadium Zinc
CAS Number 7440-39-3 7440-43-9 7440-47-3 7440-48-4 7440-50-8 7439-92-1 7439-97-6 7440-02-0 7440-22-4 7440-28-0 7440-62-2 7440-66-6
SWS ID 15 34 51 53 54 131 132 152 184 194 209 213
Units μg/L μg/L μg/L μg/L μg/L μg/L μg/L μg/L μg/L μg/L μg/L μg/L
Sample ID Collect Date Result Result Result Result Result Result Result Result Result Result Result Result
MW-1 12/15/2015 133 0.50 U 12.8 9.1 J 15.7 12.3 0.10 U 7.2 J 2.5 U 5.0 U 21.4 J 23.0
MW-2 12/15/2015 101 3.4 6.3 J 2.5 U 8.4 J 2.5 U 0.17 J 2.6 J 8.5 J 5.0 U 3.5 J 30.9
MW-3 12/15/2015 145 0.50 U 6.2 J 7.9 J 11.0 13.8 0.10 U 2.5 U 2.5 U 5.0 U 10.2 J 44.5
MW-4 12/15/2015 231 0.50 U 2.5 U 11.5 6.2 J 2.5 U 0.20 2.5 U 2.5 U 5.0 U 5.0 J 19.5
MW-5 12/15/2015 110 0.50 U 2.5 U 18.9 7.8 J 2.5 U 0.32 2.5 U 2.5 U 5.0 U 2.9 J 13.9
MW-6 12/15/2015 222 0.50 U 2.5 U 13.4 2.5 U 2.5 U 0.10 U 7.3 J 2.5 U 5.0 U 2.5 U 11.4
DOWNSTREAM 12/15/2015 8.8 J 0.50 U 2.5 U 2.5 U 2.5 U 2.5 U 0.10 U 2.5 U 2.5 U 5.0 U 2.5 U 5.0 U
UPSTREAM 12/15/2015 27.6 J 0.50 U 2.5 U 2.5 U 2.5 U 2.5 U 0.10 U 2.5 U 2.5 U 5.0 U 2.5 U 5.0 U
EQUIPMENT BLANK 12/15/2015 2.5 U 0.50 U 2.5 U 2.5 U 2.5 U 2.5 U 0.10 U 2.5 U 2.5 U 6.4 2.5 U 5.8 J
MDL 2.5 0.50 2.5 2.5 2.5 2.5 0.10 2.5 2.5 5.0 2.5 5.0
MRL 5.0 1.0 5.0 5.0 5.0 5.0 0.20 5.0 5.0 5.4 5.0 10.0
SWSL 100 1 10 10 10 10 0.20 50 10 5.5 25 10
2L 700 2 10 NE 1,000 15 1.0 100 20 NE NE 1,000
IMAC NE NE NE 1 NE NE NE NE NE 0.2 0.3 NE
2B 200,000 2 11 270 7 25 0.012 88 0.06 0.47 NE 50
Appendix I VOCs
Lab Certification 12 5090 37754
Lab Method EPA 8260 SM4500HB SM 2130B
Parameter
1,1-
Dichloro-
ethane
1,4-Dichloro-
benzene 2-Hexanone Benzene Chloro-
benzene
cis-1,2-
Dichloro-
ethene
Methylene
Chloride o-Xylene Toluene
Trans-1,2-
Dichloro-
ethene
pH Turbidity
CAS Number 75-34-3 106-46-7 591-78-6 71-43-2 108-90-7 156-59-2 75-09-2 95-47-6 108-88-3 156-60-5 SW320 SW330
SWS ID 75 71 124 16 39 78 140 408 196 79 320 330
Units μg/L μg/L μg/L μg/L μg/L μg/L μg/L μg/L μg/L μg/L SU NTU
Sample ID Collect Date Result Result Result Result Result Result Result Result Result Result Result Result
MW-1 12/15/2015 0.32 U 0.33 U 27.9 J 0.25 U 0.23 U 0.19 U 0.97 U 0.23 U 0.26 U 0.49 U 6.0 151
MW-2 12/15/2015 1.3 J 0.63 J 0.46 U 0.74 J 0.23 U 1.3 J 4.2 C9 0.58 J 0.26 U 0.49 U 5.7 10.3
MW-3 12/15/2015 0.32 U 0.33 U 20.4 J 0.25 U 0.23 U 0.19 U 0.97 U 0.23 U 0.26 U 0.49 U 6.1 40.7
MW-4 12/15/2015 0.97 J 1.6 0.46 U 0.25 U 0.36 J 2.4 J 0.97 U 0.23 U 0.26 U 0.49 U 5.7 4.6
MW-5 12/15/2015 0.32 U 1.2 2.6 J 0.25 U 0.78 J 3.3 J 9.2 0.23 U 0.26 U 0.49 U 5.6 9.7
MW-6 12/15/2015 0.32 U 0.64 J 0.46 U 0.25 U 0.23 U 3.4 J 0.97 U 0.26 J 0.26 U 0.49 U 6.1 9.8
DOWNSTREAM 12/15/2015 0.32 U 0.33 U 0.46 U 0.25 U 0.23 U 0.19 U 0.97 U 0.23 U 0.26 U 0.49 U 7.0 1.4
UPSTREAM 12/15/2015 0.32 U 0.33 U 0.46 U 0.25 U 0.23 U 0.19 U 1.1 C9 0.23 U 0.26 U 0.49 U 7.0 1.2
EQUIPMENT BLANK 12/15/2015 0.32 U 0.33 U 0.46 U 0.25 U 0.23 U 0.19 U 75.9 0.23 U 0.45 J 0.59 J NA NA
TRIP BLANK 12/15/2015 0.32 U 0.33 U 0.46 U 0.25 U 0.23 U 0.19 U 1.6 C9 0.23 U 0.26 U 0.49 U NA NA
MDL 0.32 0.33 0.46 0.25 0.23 0.19 0.97 0.23 0.26 0.49 NA NA
MRL 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 NA NA
SWSL 5 1 50 1 3 5 1 NE 1 5 NE NE
2L 6 6 NE 1 50 70 5 500 600 100 6.5-8.5 NE
IMAC NE NE 40 NE NE NE NE NE NE NE NE NE
2B 20,000 100 NE 51 140 4,900 590 800 11 10,000 6.0-9.0 50
Notes:
1.Only detected constituents are listed on this table. Please refer to Pace Laboratory Reports of Analysis (Appendix B) for further details.
2."Lab Method" is the analytical method used to analyze the constituents.
3."CAS Number" is a unique number assigned by the Chemical Abstracts Service (CAS) to all identified parameters.
4."SWS ID" is the Solid Waste Section Identification Number.
5."Units" are micrograms per liter (µg/L) for analytical results, Standard Units (SU) for pH, and nephelometric turbidity units (NTU) for turbidity.
6."Collect Date" is the date on which the sample was collected in the field.
7."Result" is analytical data reported by the laboratory or field data collected by Altamont.
8."MDL" is the method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero.
9."MRL" is the method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the referenced method.
10."SWSL" is the Solid Waste Section Limit. This limit (identified by DENR) is the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy.
11."U" is a laboratory data qualifier used for parameters not detected at concentrations above MDL.
12."J" is a laboratory data qualifier used for parameters detected at estimated concentrations above MDL but below MRL and SWSL.
An italicized "J" qualifier is assigned by Altamont to reflect a detected concentration that is greater than MRL and MDL but less than the SWSL.
13."2L" and "IMAC" (Interim Maximum Allowable Concentration) are groundwater standards from "North Carolina Administrative Code, Title 15A: Department of Environment and Natural Resources,
Subchapter 2L - Groundwater Classifications and Standards," DENR (Last Amended on April 1, 2013).
14."2B" indicates surface water standard per "North Carolina Administrative Code, Title 15A: Department of Environment and Natural Resources, Subchapter 2B - Surface Water and Wetland Standards,"
(last amended on May 1, 2007) or standard obtained from National Criteria per EPA table (current as of May 15, 2013).
15."NE" means Not Established. "NA" means Not Applicable.
16.Bold numbers indicate a detection. Grayed cells indicate result in exceedance of the 2L, IMAC, or 2B standard.
17."C9" indicates the detected constituent is a common laboratory contaminant.
18.Due to the high concentration of methylene chloride in the equipment blank, along with the detection in the trip blank, the reported methylene chloride concentrations
are not likely representative of groundwater quality.
Field Parameters
P:\Environmental Inc\Clay County\Analytical & Data\Water\2015\Tables\2201Dec2015 Tables 2,3,4,5 Page 1 of 1
Table 4
Solid Waste Section Limits Exceedances Notification
Clay County Municipal Solid Waste Landfill, Hayesville, Clay County, North Carolina
FACILITY
PERMIT WELL ID CAS
NUMBER SWS ID PARAMETER RESULT UNITS METHOD MDL MRL SWSL COLLECT DATE
22-01 MW-1 7440-39-3 15 Barium 133 µg/L EPA 6010 2.5 5.0 100 12/15/2015
22-01 MW-1 7440-47-3 51 Chromium 12.8 µg/L EPA 6010 2.5 5.0 10 12/15/2015
22-01 MW-1 7440-50-8 54 Copper 15.7 µg/L EPA 6010 2.5 5.0 10 12/15/2015
22-01 MW-1 7439-92-1 131 Lead 12.3 µg/L EPA 6010 2.5 5.0 10 12/15/2015
22-01 MW-1 7440-66-6 213 Zinc 23.0 µg/L EPA 6010 5.0 10.0 10 12/15/2015
22-01 MW-2 7440-39-3 15 Barium 101 µg/L EPA 6010 2.5 5.0 100 12/15/2015
22-01 MW-2 7440-43-9 34 Cadmium 3.4 µg/L EPA 6010 0.5 1.0 1 12/15/2015
22-01 MW-2 7440-66-6 213 Zinc 30.9 µg/L EPA 6010 5.0 10.0 10 12/15/2015
22-01 MW-2 75-09-2 140 Methylene Chloride 4.2 C9 µg/L EPA 8260 0.97 1.0 1 12/15/2015
22-01 MW-3 7440-39-3 15 Barium 145 µg/L EPA 6010 2.5 5.0 100 12/15/2015
22-01 MW-3 7440-50-8 54 Copper 11.0 µg/L EPA 6010 2.5 5.0 10 12/15/2015
22-01 MW-3 7439-92-1 131 Lead 13.8 µg/L EPA 6010 2.5 5.0 10 12/15/2015
22-01 MW-3 7440-66-6 213 Zinc 44.5 µg/L EPA 6010 5 10.0 10 12/15/2015
22-01 MW-4 7440-39-3 15 Barium 231 µg/L EPA 6010 2.5 5.0 100 12/15/2015
22-01 MW-4 7440-48-4 53 Cobalt 11.5 µg/L EPA 6010 2.5 5.0 10 12/15/2015
22-01 MW-4 7439-97-6 132 Mercury 0.20 µg/L EPA 7470 0.10 0.2 0.2 12/15/2015
22-01 MW-4 7440-66-6 213 Zinc 19.5 µg/L EPA 6010 5.0 10.0 10 12/15/2015
22-01 MW-4 106-46-7 71 1,4-Dichlorobenzene 1.6 µg/L EPA 8260 0.33 1.0 1 12/15/2015
22-01 MW-5 7440-39-3 15 Barium 110 µg/L EPA 6010 2.5 5.0 100 12/15/2015
22-01 MW-5 7440-48-4 53 Cobalt 18.9 µg/L EPA 6010 2.5 5.0 10 12/15/2015
22-01 MW-5 7439-97-6 132 Mercury 0.32 µg/L EPA 6010 0.10 0.20 0.2 12/15/2015
22-01 MW-5 7440-66-6 213 Zinc 13.9 µg/L EPA 6010 5.0 10.0 10 12/15/2015
22-01 MW-5 106-46-7 71 1,4-Dichlorobenzene 1.2 µg/L EPA 8260 0.33 1.0 1 12/15/2015
22-01 MW-5 75-09-2 140 Methylene Chloride 9.2 µg/L EPA 8260 0.97 1.0 1 12/15/2015
22-01 MW-6 7440-39-3 15 Barium 222 µg/L EPA 6010 2.5 5.0 100 12/15/2015
22-01 MW-6 7440-48-4 53 Cobalt 13.4 µg/L EPA 6010 2.5 5.0 10 12/15/2015
22-01 MW-6 7440-66-6 213 Zinc 11.4 µg/L EPA 6010 5.0 10.0 10 12/15/2015
22-01 UPSTREAM 75-09-2 140 Methylene Chloride 1.1 C9 µg/L EPA 8260 0.97 1.0 1 12/15/2015
22-01 EQUIPMENT BLANK 7440-28-0 194 Thallium 6.4 µg/L EPA 6010 5.0 5.4 5.5 12/15/2015
22-01 EQUIPMENT BLANK 75-09-2 140 Methylene Chloride 75.9 µg/L EPA 8260 0.97 1.0 1 12/15/2015
22-01 TRIP BLANK 75-09-2 140 Methylene Chloride 1.6 C9 µg/L EPA 8260 0.97 1.0 1 12/15/2015
Notes:
1."CAS NUMBER" is a unique number assigned by the Chemical Abstracts Service (CAS) to all identified parameters.
2."SWS ID" is the Solid Waste Section Identification Number.
3."RESULT" is the analytical data reported by the laboratory.
4."µg/L" indicates unit of micrograms per liter for analytical results.
5."METHOD" is the analytical method used to analyze the constituents.
6."MDL" is the method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99% confidence
that the analyte concentration is greater than zero.
7."MRL" is the method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the referenced method.
8."SWSL" is the Solid Waste Section Limit. This limit (identified by DENR) is the lowest amount of analyte in a sample that can be quantitatively
determined with suitable precision and accuracy.
9."COLLECT DATE" is the date on which the sample was collected in the field.
10.Bold numbers indicate a result equal to or in exceedance of the 2L standard.
11."C9" indicates the detected constituent is a common laboratory contaminant.
12.Due to the high concentration of methylene chloride in the equipment blank, along with the detection in the trip blank, the reported methylene chloride
concentrations are not likely representative of groundwater quality.
P:\Environmental Inc\Clay County\Analytical & Data\Water\2015\Tables\2201Dec2015 Tables 2,3,4,5 Page 1 of 1
Table 5
Water Quality Standards Exceedances Notification
Clay County Municipal Solid Waste Landfill, Hayesville, Clay County, North Carolina
FACILITY
PERMIT WELL ID CAS
NUMBER SWS ID PARAMETER RESULT UNITS QUALIFIER METHOD MDL MRL SWSL
GROUNDWATER
QUALITY
STANDARD
COLLECT
DATE CAUSE AND SIGNIFICANCE
22-01 MW-1 7440-47-3 51 Chromium 12.8 µg/L EPA 6010 2.5 5.0 10 10 12/15/2015
22-01 MW-1 7440-48-4 53 Cobalt 9.1 µg/L J EPA 6010 2.5 5.0 10 1 12/15/2015
22-01 MW-1 7440-62-2 209 Vanadium 21.4 µg/L J EPA 6010 2.5 5.0 25 0.3 12/15/2015
22-01 MW-1 SW320 320 pH 6.0 SU SM4500HB NE NE NE 6.5 - 8.5 12/15/2015 Consistent with historic readings.
22-01 MW-2 7440-43-9 34 Cadmium 3.4 µg/L EPA 6010 0.5 1.0 1 2 12/15/2015 Anthropogenic
22-01 MW-2 7440-62-2 209 Vanadium 3.5 µg/L J EPA 6010 2.5 5.0 25 0.3 12/15/2015 Possibly naturally occurring.
22-01 MW-2 SW320 320 pH 5.7 SU SM4500HB NE NE NE 6.5 - 8.5 12/15/2015 Consistent with historic readings.
22-01 MW-3 7440-48-4 53 Cobalt 7.9 µg/L J EPA 6010 2.5 5.0 10 1 12/15/2015
22-01 MW-3 7440-62-2 209 Vanadium 10.2 µg/L J EPA 6010 2.5 5.0 25 0.3 12/15/2015
22-01 MW-3 SW320 320 pH 6.1 SU SM4500HB NE NE NE 6.5 - 8.5 12/15/2015 Consistent with historic readings.
22-01 MW-4 7440-48-4 53 Cobalt 11.5 µg/L EPA 6010 2.5 5.0 10 1 12/15/2015
22-01 MW-4 7440-62-2 209 Vanadium 5.0 µg/L J EPA 6010 2.5 5.0 25 0.3 12/15/2015
22-01 MW-4 SW320 320 pH 5.7 SU SM4500HB NE NE NE 6.5 - 8.5 12/15/2015 Consistent with historic readings.
22-01 MW-5 7440-48-4 53 Cobalt 18.9 µg/L EPA 6010 2.5 5.0 10 1 12/15/2015
22-01 MW-5 7440-62-2 209 Vanadium 2.9 µg/L J EPA 6010 2.5 5.0 25 0.3 12/15/2015
22-01 MW-5 75-09-2 140 Methylene Chloride 9.2 µg/L EPA 8260 0.97 1.0 1 5 12/15/2015 Possibly due to laboratory contamination
22-01 MW-5 SW320 320 pH 5.6 SU SM4500HB NE NE NE 6.5 - 8.5 12/15/2015 Consistent with historic readings.
22-01 MW-6 7440-48-4 53 Cobalt 13.4 µg/L EPA 6010 2.5 5.0 10 1 12/15/2015 Possibly naturally occurring.
22-01 MW-6 SW320 320 pH 6.1 µg/L SM4500HB NE NE NE 6.5 - 8.5 12/15/2015 Consistent with historic readings.
Notes:
1."CAS NUMBER" is a unique number assigned by the Chemical Abstracts Service (CAS) to all identified parameters.
2."SWS ID" is the Solid Waste Section Identification Number.
3."RESULT" is analytical data reported by the laboratory or field data collected by Environmental, Inc.
4."UNITS" are micrograms per liter (µg/L) for analytical results and Standard Units (SU) for pH.
5."QUALIFIER" is a data qualifier or "flag". A blank cell indicates that there is no qualifier associated with the reported result.
6."METHOD" is the analytical method used to analyze the constituents.
7."MDL" is the method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero.
8."MRL" is the method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the referenced method.
9."SWSL" is the Solid Waste Section Limit. This limit (identified by DENR) is the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy.
10."GROUNDWATER QUALITY STANDARD" refers to the 2L standard or Interim Maximum Allowable Concentration (IMAC) for groundwater.
11."COLLECT DATE" is the date on which the sample was collected in the field.
12.2L standard and IMAC are from "North Carolina Administrative Code, Title 15A: Department of Environment and Natural Resources, Subchapter 2L - Groundwater
Classifications and Standards," DENR (Last Amended April 1, 2013).
13.Due to the high concentration of methylene chloride in the equipment blank, along with the detection in the trip blank, the reported methylene chloride concentrations
are not likely representative of groundwater quality.
Possibly naturally occurring.
Possibly naturally occurring.
Possibly naturally occurring. Turbidity of
sample is 151 NTU.
Possibly naturally occurring.
P:\Environmental Inc\Clay County\Analytical & Data\Water\2015\Tables\2201Dec2015 Tables 2,3,4,5 Page 1 of 1

APPENDICES

APPENDIX A

Field Sheet and
Certificate of Analysis

APPENDIX B

Reports of Laboratory Analysis
and Chain-of-Custody Documentation

#=CL#
January 12, 2016
LIMS USE: FR - MARK TEAGUE
LIMS OBJECT ID: 92280048
92280048
Project:
Pace Project No.:
RE:
Mr. Mark Teague
Environmental, Inc.
PO Box 954
Cullowhee, NC 28723
Clay Co. MW #1
Dear Mr. Teague:
Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
A revised laboratory report is being submitted on January 12, 2016, to report MDLs, per client
request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 16
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92280048
Clay Co. MW #1
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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[phone]
Page 2 of 16
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92280048
Clay Co. MW #1
Lab ID Sample ID Matrix Date Collected Date Received
92280048001 MW #1 Water 12/15/15 09:57 12/16/15 11:33
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 3 of 16
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92280048
Clay Co. MW #1
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92280048001 MW #1 EPA 6010 15 PASI-ACDF, JMW
EPA 7470 1 PASI-ASH1
EPA 8260 52 PASI-CGAW
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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[phone]
Page 4 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92280048
Clay Co. MW #1
Sample: MW #1 Lab ID: 92280048001 Collected: 12/15/15 09:57 Received: 12/16/15 11:33 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/19/15 05:56 7440-36-012/17/15 19:005.0 3.8 1
Arsenic ND ug/L 12/19/15 05:56 7440-38-212/17/15 19:0010.0 2.5 1
Barium 133 ug/L 12/19/15 05:56 7440-39-312/17/15 19:005.0 2.5 1
Beryllium ND ug/L 12/19/15 05:56 7440-41-712/17/15 19:001.0 0.50 1
Cadmium ND ug/L 12/19/15 05:56 7440-43-912/17/15 19:001.0 0.50 1
Chromium 12.8 ug/L 12/19/15 05:56 7440-47-312/17/15 19:005.0 2.5 1
Cobalt 9.1 ug/L 12/19/15 05:56 7440-48-412/17/15 19:005.0 2.5 1
Copper 15.7 ug/L 12/19/15 05:56 7440-50-812/17/15 19:005.0 2.5 1
Lead 12.3 ug/L 12/19/15 05:56 7439-92-112/17/15 19:005.0 2.5 1
Nickel 7.2 ug/L 12/19/15 05:56 7440-02-012/17/15 19:005.0 2.5 1
Selenium ND ug/L 12/19/15 05:56 7782-49-212/17/15 19:0010.0 5.0 1
Silver ND ug/L 12/19/15 05:56 7440-22-412/17/15 19:005.0 2.5 1
Thallium ND ug/L 12/22/15 18:09 7440-28-012/17/15 19:005.4 5.0 1
Vanadium 21.4 ug/L 12/19/15 05:56 7440-62-212/17/15 19:005.0 2.5 1
Zinc 23.0 ug/L 12/19/15 05:56 7440-66-612/17/15 19:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/21/15 12:28 7439-97-612/19/15 18:300.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/29/15 14:18 67-64-125.0 10.0 1
Acrylonitrile ND ug/L 12/29/15 14:18 107-13-110.0 1.9 1
Benzene ND ug/L 12/29/15 14:18 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/29/15 14:18 74-97-51.0 0.17 1
Bromodichloromethane ND ug/L 12/29/15 14:18 75-27-41.0 0.18 1
Bromoform ND ug/L 12/29/15 14:18 75-25-21.0 0.26 1
Bromomethane ND ug/L 12/29/15 14:18 74-83-92.0 0.29 1
2-Butanone (MEK)ND ug/L 12/29/15 14:18 78-93-35.0 0.96 1
Carbon disulfide ND ug/L 12/29/15 14:18 75-15-02.0 1.2 1
Carbon tetrachloride ND ug/L 12/29/15 14:18 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/29/15 14:18 108-90-71.0 0.23 1
Chloroethane ND ug/L 12/29/15 14:18 75-00-31.0 0.54 1
Chloroform ND ug/L 12/29/15 14:18 67-66-31.0 0.14 1
Chloromethane ND ug/L 12/29/15 14:18 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/29/15 14:18 96-12-82.0 2.0 1
Dibromochloromethane ND ug/L 12/29/15 14:18 124-48-11.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/29/15 14:18 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/29/15 14:18 74-95-31.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/29/15 14:18 95-50-11.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/29/15 14:18 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/29/15 14:18 110-57-61.0 1.0 1
1,1-Dichloroethane ND ug/L 12/29/15 14:18 75-34-31.0 0.32 1
1,2-Dichloroethane ND ug/L 12/29/15 14:18 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/29/15 14:18 75-35-41.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/29/15 14:18 156-59-21.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/29/15 14:18 156-60-51.0 0.49 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:21 AM
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Page 5 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92280048
Clay Co. MW #1
Sample: MW #1 Lab ID: 92280048001 Collected: 12/15/15 09:57 Received: 12/16/15 11:33 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/29/15 14:18 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/29/15 14:18 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/29/15 14:18 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/29/15 14:18 100-41-41.0 0.30 1
2-Hexanone 27.9 ug/L 12/29/15 14:18 591-78-65.0 0.46 1
Iodomethane ND ug/L 12/29/15 14:18 74-88-45.0 0.32 1
Methylene Chloride ND ug/L 12/29/15 14:18 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/29/15 14:18 108-10-15.0 0.33 1
Styrene ND ug/L 12/29/15 14:18 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/29/15 14:18 630-20-61.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/29/15 14:18 79-34-51.0 0.40 1
Tetrachloroethene ND ug/L 12/29/15 14:18 127-18-41.0 0.46 1
Toluene ND ug/L 12/29/15 14:18 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/29/15 14:18 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/29/15 14:18 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/29/15 14:18 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/29/15 14:18 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/29/15 14:18 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/29/15 14:18 108-05-42.0 0.35 1
Vinyl chloride ND ug/L 12/29/15 14:18 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/29/15 14:18 1330-20-72.0 0.66 1
m&p-Xylene ND ug/L 12/29/15 14:18 179601-23-12.0 0.66 1
o-Xylene ND ug/L 12/29/15 14:18 95-47-61.0 0.23 1
Surrogates
4-Bromofluorobenzene (S)106 %12/29/15 14:18 460-00-470-130 1
1,2-Dichloroethane-d4 (S)88 %12/29/15 14:18 17060-07-070-130 1
Toluene-d8 (S)108 %12/29/15 14:18 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:21 AM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 6 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280048
Clay Co. MW #1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8799
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92280048001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1632840
Associated Lab Samples:92280048001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/21/15 11:410.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1632841LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.12.5 84 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1632842MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279477001
1632844
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 92 75-12575 20 252.5ND 2.4 1.9
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:21 AM
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Page 7 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280048
Clay Co. MW #1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20312
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92280048001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1631789
Associated Lab Samples:92280048001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 12/19/15 05:133.8
Arsenic ug/L ND 10.0 12/19/15 05:132.5
Barium ug/L ND 5.0 12/19/15 05:132.5
Beryllium ug/L ND 1.0 12/19/15 05:130.50
Cadmium ug/L ND 1.0 12/19/15 05:130.50
Chromium ug/L ND 5.0 12/19/15 05:132.5
Cobalt ug/L ND 5.0 12/19/15 05:132.5
Copper ug/L ND 5.0 12/19/15 05:132.5
Lead ug/L ND 5.0 12/19/15 05:132.5
Nickel ug/L ND 5.0 12/19/15 05:132.5
Selenium ug/L ND 10.0 12/19/15 05:135.0
Silver ug/L ND 5.0 12/19/15 05:132.5
Thallium ug/L ND 5.4 12/22/15 17:355.0
Vanadium ug/L ND 5.0 12/19/15 05:132.5
Zinc ug/L ND 10.0 12/19/15 05:135.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1631790LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 489500 98 80-120
Arsenic ug/L 526500 105 80-120
Barium ug/L 496500 99 80-120
Beryllium ug/L 502500 100 80-120
Cadmium ug/L 519500 104 80-120
Chromium ug/L 529500 106 80-120
Cobalt ug/L 530500 106 80-120
Copper ug/L 515500 103 80-120
Lead ug/L 524500 105 80-120
Nickel ug/L 524500 105 80-120
Selenium ug/L 520500 104 80-120
Silver ug/L 233250 93 80-120
Thallium ug/L 522500 104 80-120
Vanadium ug/L 518500 104 80-120
Zinc ug/L 554500 111 80-120
REPORT OF LABORATORY ANALYSIS
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Page 8 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280048
Clay Co. MW #1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1631791MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279775001
1631792
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 99 75-12597 2 25500ND495 483
Arsenic ug/L 500 107 75-125104 3 25500ND537 519
Barium ug/L 500 101 75-12598 3 25500108614 597
Beryllium ug/L 500 103 75-125100 3 25500ND515 499
Cadmium ug/L 500 105 75-125102 3 25500ND526 510
Chromium ug/L 500 107 75-125105 3 25500ND538 524
Cobalt ug/L 500 107 75-125104 3 2550010.9 546 528
Copper ug/L 500 105 75-125101 3 25500ND524 508
Lead ug/L 500 105 75-125102 3 25500ND526 510
Nickel ug/L 500 105 75-125102 3 255006.7 534 517
Selenium ug/L 500 104 75-125101 2 25500ND520 508
Silver ug/L 250 95 75-12592 4 25250ND238 230
Thallium ug/L 500 98 75-12597 1 25500ND488 483
Vanadium ug/L 500 106 75-125103 3 255002.9J 534 517
Zinc ug/L 500 112 75-125109 2 2550020.2 581 567
REPORT OF LABORATORY ANALYSIS
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Page 9 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280048
Clay Co. MW #1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34968
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92280048001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1638140
Associated Lab Samples:92280048001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/29/15 06:110.33
1,1,1-Trichloroethane ug/L ND 1.0 12/29/15 06:110.48
1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/29/15 06:110.40
1,1,2-Trichloroethane ug/L ND 1.0 12/29/15 06:110.29
1,1-Dichloroethane ug/L ND 1.0 12/29/15 06:110.32
1,1-Dichloroethene ug/L ND 1.0 12/29/15 06:110.56
1,2,3-Trichloropropane ug/L ND 1.0 12/29/15 06:110.41
1,2-Dibromo-3-chloropropane ug/L ND 2.0 12/29/15 06:112.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/29/15 06:110.27
1,2-Dichlorobenzene ug/L ND 1.0 12/29/15 06:110.30
1,2-Dichloroethane ug/L ND 1.0 12/29/15 06:110.24
1,2-Dichloropropane ug/L ND 1.0 12/29/15 06:110.27
1,4-Dichlorobenzene ug/L ND 1.0 12/29/15 06:110.33
2-Butanone (MEK)ug/L ND 5.0 12/29/15 06:110.96
2-Hexanone ug/L ND 5.0 12/29/15 06:110.46
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/29/15 06:110.33
Acetone ug/L ND 25.0 12/29/15 06:1110.0
Acrylonitrile ug/L ND 10.0 12/29/15 06:111.9
Benzene ug/L ND 1.0 12/29/15 06:110.25
Bromochloromethane ug/L ND 1.0 12/29/15 06:110.17
Bromodichloromethane ug/L ND 1.0 12/29/15 06:110.18
Bromoform ug/L ND 1.0 12/29/15 06:110.26
Bromomethane ug/L ND 2.0 12/29/15 06:110.29
Carbon disulfide ug/L ND 2.0 12/29/15 06:111.2
Carbon tetrachloride ug/L ND 1.0 12/29/15 06:110.25
Chlorobenzene ug/L ND 1.0 12/29/15 06:110.23
Chloroethane ug/L ND 1.0 12/29/15 06:110.54
Chloroform ug/L ND 1.0 12/29/15 06:110.14
Chloromethane ug/L ND 1.0 12/29/15 06:110.11
cis-1,2-Dichloroethene ug/L ND 1.0 12/29/15 06:110.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/29/15 06:110.13
Dibromochloromethane ug/L ND 1.0 12/29/15 06:110.21
Dibromomethane ug/L ND 1.0 12/29/15 06:110.21
Ethylbenzene ug/L ND 1.0 12/29/15 06:110.30
Iodomethane ug/L ND 5.0 12/29/15 06:110.32
m&p-Xylene ug/L ND 2.0 12/29/15 06:110.66
Methylene Chloride ug/L ND 1.0 12/29/15 06:110.97
o-Xylene ug/L ND 1.0 12/29/15 06:110.23
Styrene ug/L ND 1.0 12/29/15 06:110.26
Tetrachloroethene ug/L ND 1.0 12/29/15 06:110.46
Toluene ug/L ND 1.0 12/29/15 06:110.26
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:21 AM
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Page 10 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280048
Clay Co. MW #1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1638140
Associated Lab Samples:92280048001
Matrix: Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 1.0 12/29/15 06:110.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/29/15 06:110.26
trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/29/15 06:111.0
Trichloroethene ug/L ND 1.0 12/29/15 06:110.47
Trichlorofluoromethane ug/L ND 1.0 12/29/15 06:110.20
Vinyl acetate ug/L ND 2.0 12/29/15 06:110.35
Vinyl chloride ug/L ND 1.0 12/29/15 06:110.62
Xylene (Total)ug/L ND 2.0 12/29/15 06:110.66
1,2-Dichloroethane-d4 (S)%91 70-130 12/29/15 06:11
4-Bromofluorobenzene (S)%102 70-130 12/29/15 06:11
Toluene-d8 (S)%109 70-130 12/29/15 06:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1638141LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.650 101 80-125
1,1,1-Trichloroethane ug/L 48.050 96 71-129
1,1,2,2-Tetrachloroethane ug/L 50.650 101 79-124
1,1,2-Trichloroethane ug/L 50.950 102 85-125
1,1-Dichloroethane ug/L 45.250 90 73-126
1,1-Dichloroethene ug/L 43.650 87 66-135
1,2,3-Trichloropropane ug/L 51.250 102 75-130
1,2-Dibromo-3-chloropropane ug/L 47.850 96 71-133
1,2-Dibromoethane (EDB)ug/L 53.450 107 83-124
1,2-Dichlorobenzene ug/L 49.150 98 80-133
1,2-Dichloroethane ug/L 45.650 91 67-128
1,2-Dichloropropane ug/L 46.850 94 75-132
1,4-Dichlorobenzene ug/L 49.250 98 78-130
2-Butanone (MEK)ug/L 113100 113 61-144
2-Hexanone ug/L 108100 108 68-143
4-Methyl-2-pentanone (MIBK)ug/L 107100 107 72-135
Acetone ug/L 105100 105 48-146
Acrylonitrile ug/L 255250 102 40-160
Benzene ug/L 49.050 98 80-125
Bromochloromethane ug/L 53.750 107 71-125
Bromodichloromethane ug/L 48.150 96 78-124
Bromoform ug/L 43.750 87 71-128
Bromomethane ug/L 40.450 81 40-160
Carbon disulfide ug/L 41.050 82 50-160
Carbon tetrachloride ug/L 49.150 98 69-131
Chlorobenzene ug/L 49.950 100 81-122
Chloroethane ug/L 33.950 68 39-148
Chloroform ug/L 47.650 95 73-127
Chloromethane ug/L 53.750 107 44-146
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280048
Clay Co. MW #1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1638141LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 44.950 90 74-124
cis-1,3-Dichloropropene ug/L 50.850 102 72-132
Dibromochloromethane ug/L 52.850 106 78-125
Dibromomethane ug/L 52.250 104 82-120
Ethylbenzene ug/L 46.550 93 79-121
Iodomethane ug/L 85.5100 86 39-154
m&p-Xylene ug/L 91.9100 92 81-124
Methylene Chloride ug/L 57.250 114 64-133
o-Xylene ug/L 44.950 90 79-131
Styrene ug/L 48.050 96 84-126
Tetrachloroethene ug/L 49.350 99 78-122
Toluene ug/L 45.050 90 80-121
trans-1,2-Dichloroethene ug/L 47.850 96 71-127
trans-1,3-Dichloropropene ug/L 45.450 91 69-141
trans-1,4-Dichloro-2-butene ug/L 54.350 109 40-160
Trichloroethene ug/L 52.550 105 78-122
Trichlorofluoromethane ug/L 43.350 87 53-137
Vinyl acetate ug/L 99.6100 100 40-160
Vinyl chloride ug/L 46.150 92 58-137
Xylene (Total)ug/L 137150 91 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%94 70-130
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92280048
Clay Co. MW #1
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
REPORT OF LABORATORY ANALYSIS
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92280048
Clay Co. MW #1
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92280048001 MPRP/20312 ICP/18330MW #1 EPA 3010A EPA 6010
92280048001 MERP/8799 MERC/8455MW #1 EPA 7470 EPA 7470
92280048001 MSV/34968MW #1 EPA 8260
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Page 15 of 16
Page 16 of 16
#=CL#
January 12, 2016
LIMS USE: FR - MARK TEAGUE
LIMS OBJECT ID: 92280045
92280045
Project:
Pace Project No.:
RE:
Mr. Mark Teague
Environmental, Inc.
PO Box 954
Cullowhee, NC 28723
CLAY CO MW#2
Dear Mr. Teague:
Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
A revised laboratory report is being submitted on January 12, 2016, to report MDLs, per client
request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
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#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92280045
CLAY CO MW#2
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92280045
CLAY CO MW#2
Lab ID Sample ID Matrix Date Collected Date Received
92280045001 MW#2 Water 12/15/15 10:31 12/16/15 11:35
REPORT OF LABORATORY ANALYSIS
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92280045
CLAY CO MW#2
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92280045001 MW#2 EPA 6010 15 PASI-ACDF, JMW
EPA 7470 1 PASI-ASH1
EPA 8260 52 PASI-CGAW
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92280045
CLAY CO MW#2
Sample: MW#2 Lab ID: 92280045001 Collected: 12/15/15 10:31 Received: 12/16/15 11:35 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/19/15 05:53 7440-36-012/17/15 19:005.0 3.8 1
Arsenic ND ug/L 12/19/15 05:53 7440-38-212/17/15 19:0010.0 2.5 1
Barium 101 ug/L 12/19/15 05:53 7440-39-312/17/15 19:005.0 2.5 1
Beryllium ND ug/L 12/19/15 05:53 7440-41-712/17/15 19:001.0 0.50 1
Cadmium 3.4 ug/L 12/19/15 05:53 7440-43-912/17/15 19:001.0 0.50 1
Chromium 6.3 ug/L 12/19/15 05:53 7440-47-312/17/15 19:005.0 2.5 1
Cobalt ND ug/L 12/19/15 05:53 7440-48-412/17/15 19:005.0 2.5 1
Copper 8.4 ug/L 12/19/15 05:53 7440-50-812/17/15 19:005.0 2.5 1
Lead ND ug/L 12/19/15 05:53 7439-92-112/17/15 19:005.0 2.5 1
Nickel 2.6J ug/L 12/19/15 05:53 7440-02-012/17/15 19:005.0 2.5 1
Selenium ND ug/L 12/19/15 05:53 7782-49-212/17/15 19:0010.0 5.0 1
Silver 8.5 ug/L 12/19/15 05:53 7440-22-412/17/15 19:005.0 2.5 1
Thallium ND ug/L 12/22/15 18:06 7440-28-012/17/15 19:005.4 5.0 1
Vanadium 3.5J ug/L 12/19/15 05:53 7440-62-212/17/15 19:005.0 2.5 1
Zinc 30.9 ug/L 12/19/15 05:53 7440-66-612/17/15 19:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury 0.17J ug/L 12/21/15 12:25 7439-97-612/19/15 18:300.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/29/15 14:01 67-64-125.0 10.0 1
Acrylonitrile ND ug/L 12/29/15 14:01 107-13-110.0 1.9 1
Benzene 0.74J ug/L 12/29/15 14:01 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/29/15 14:01 74-97-51.0 0.17 1
Bromodichloromethane ND ug/L 12/29/15 14:01 75-27-41.0 0.18 1
Bromoform ND ug/L 12/29/15 14:01 75-25-21.0 0.26 1
Bromomethane ND ug/L 12/29/15 14:01 74-83-92.0 0.29 1
2-Butanone (MEK)ND ug/L 12/29/15 14:01 78-93-35.0 0.96 1
Carbon disulfide ND ug/L 12/29/15 14:01 75-15-02.0 1.2 1
Carbon tetrachloride ND ug/L 12/29/15 14:01 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/29/15 14:01 108-90-71.0 0.23 1
Chloroethane ND ug/L 12/29/15 14:01 75-00-31.0 0.54 1
Chloroform ND ug/L 12/29/15 14:01 67-66-31.0 0.14 1
Chloromethane ND ug/L 12/29/15 14:01 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/29/15 14:01 96-12-82.0 2.0 1
Dibromochloromethane ND ug/L 12/29/15 14:01 124-48-11.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/29/15 14:01 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/29/15 14:01 74-95-31.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/29/15 14:01 95-50-11.0 0.30 1
1,4-Dichlorobenzene 0.63J ug/L 12/29/15 14:01 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/29/15 14:01 110-57-61.0 1.0 1
1,1-Dichloroethane 1.3 ug/L 12/29/15 14:01 75-34-31.0 0.32 1
1,2-Dichloroethane ND ug/L 12/29/15 14:01 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/29/15 14:01 75-35-41.0 0.56 1
cis-1,2-Dichloroethene 1.3 ug/L 12/29/15 14:01 156-59-21.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/29/15 14:01 156-60-51.0 0.49 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92280045
CLAY CO MW#2
Sample: MW#2 Lab ID: 92280045001 Collected: 12/15/15 10:31 Received: 12/16/15 11:35 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/29/15 14:01 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/29/15 14:01 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/29/15 14:01 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/29/15 14:01 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/29/15 14:01 591-78-65.0 0.46 1
Iodomethane ND ug/L 12/29/15 14:01 74-88-45.0 0.32 1
Methylene Chloride 4.2 ug/L 12/29/15 14:01 75-09-2 C91.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/29/15 14:01 108-10-15.0 0.33 1
Styrene ND ug/L 12/29/15 14:01 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/29/15 14:01 630-20-61.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/29/15 14:01 79-34-51.0 0.40 1
Tetrachloroethene ND ug/L 12/29/15 14:01 127-18-41.0 0.46 1
Toluene ND ug/L 12/29/15 14:01 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/29/15 14:01 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/29/15 14:01 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/29/15 14:01 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/29/15 14:01 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/29/15 14:01 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/29/15 14:01 108-05-42.0 0.35 1
Vinyl chloride ND ug/L 12/29/15 14:01 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/29/15 14:01 1330-20-72.0 0.66 1
m&p-Xylene ND ug/L 12/29/15 14:01 179601-23-12.0 0.66 1
o-Xylene 0.58J ug/L 12/29/15 14:01 95-47-61.0 0.23 1
Surrogates
4-Bromofluorobenzene (S)108 %12/29/15 14:01 460-00-470-130 1
1,2-Dichloroethane-d4 (S)93 %12/29/15 14:01 17060-07-070-130 1
Toluene-d8 (S)106 %12/29/15 14:01 2037-26-570-130 1
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280045
CLAY CO MW#2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8799
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92280045001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1632840
Associated Lab Samples:92280045001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/21/15 11:410.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1632841LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.12.5 84 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1632842MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279477001
1632844
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 92 75-12575 20 252.5ND 2.4 1.9
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280045
CLAY CO MW#2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20312
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92280045001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1631789
Associated Lab Samples:92280045001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 12/19/15 05:133.8
Arsenic ug/L ND 10.0 12/19/15 05:132.5
Barium ug/L ND 5.0 12/19/15 05:132.5
Beryllium ug/L ND 1.0 12/19/15 05:130.50
Cadmium ug/L ND 1.0 12/19/15 05:130.50
Chromium ug/L ND 5.0 12/19/15 05:132.5
Cobalt ug/L ND 5.0 12/19/15 05:132.5
Copper ug/L ND 5.0 12/19/15 05:132.5
Lead ug/L ND 5.0 12/19/15 05:132.5
Nickel ug/L ND 5.0 12/19/15 05:132.5
Selenium ug/L ND 10.0 12/19/15 05:135.0
Silver ug/L ND 5.0 12/19/15 05:132.5
Thallium ug/L ND 5.4 12/22/15 17:355.0
Vanadium ug/L ND 5.0 12/19/15 05:132.5
Zinc ug/L ND 10.0 12/19/15 05:135.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1631790LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 489500 98 80-120
Arsenic ug/L 526500 105 80-120
Barium ug/L 496500 99 80-120
Beryllium ug/L 502500 100 80-120
Cadmium ug/L 519500 104 80-120
Chromium ug/L 529500 106 80-120
Cobalt ug/L 530500 106 80-120
Copper ug/L 515500 103 80-120
Lead ug/L 524500 105 80-120
Nickel ug/L 524500 105 80-120
Selenium ug/L 520500 104 80-120
Silver ug/L 233250 93 80-120
Thallium ug/L 522500 104 80-120
Vanadium ug/L 518500 104 80-120
Zinc ug/L 554500 111 80-120
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280045
CLAY CO MW#2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1631791MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279775001
1631792
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 99 75-12597 2 25500ND495 483
Arsenic ug/L 500 107 75-125104 3 25500ND537 519
Barium ug/L 500 101 75-12598 3 25500108614 597
Beryllium ug/L 500 103 75-125100 3 25500ND515 499
Cadmium ug/L 500 105 75-125102 3 25500ND526 510
Chromium ug/L 500 107 75-125105 3 25500ND538 524
Cobalt ug/L 500 107 75-125104 3 2550010.9 546 528
Copper ug/L 500 105 75-125101 3 25500ND524 508
Lead ug/L 500 105 75-125102 3 25500ND526 510
Nickel ug/L 500 105 75-125102 3 255006.7 534 517
Selenium ug/L 500 104 75-125101 2 25500ND520 508
Silver ug/L 250 95 75-12592 4 25250ND238 230
Thallium ug/L 500 98 75-12597 1 25500ND488 483
Vanadium ug/L 500 106 75-125103 3 255002.9J 534 517
Zinc ug/L 500 112 75-125109 2 2550020.2 581 567
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280045
CLAY CO MW#2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34968
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92280045001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1638140
Associated Lab Samples:92280045001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/29/15 06:110.33
1,1,1-Trichloroethane ug/L ND 1.0 12/29/15 06:110.48
1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/29/15 06:110.40
1,1,2-Trichloroethane ug/L ND 1.0 12/29/15 06:110.29
1,1-Dichloroethane ug/L ND 1.0 12/29/15 06:110.32
1,1-Dichloroethene ug/L ND 1.0 12/29/15 06:110.56
1,2,3-Trichloropropane ug/L ND 1.0 12/29/15 06:110.41
1,2-Dibromo-3-chloropropane ug/L ND 2.0 12/29/15 06:112.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/29/15 06:110.27
1,2-Dichlorobenzene ug/L ND 1.0 12/29/15 06:110.30
1,2-Dichloroethane ug/L ND 1.0 12/29/15 06:110.24
1,2-Dichloropropane ug/L ND 1.0 12/29/15 06:110.27
1,4-Dichlorobenzene ug/L ND 1.0 12/29/15 06:110.33
2-Butanone (MEK)ug/L ND 5.0 12/29/15 06:110.96
2-Hexanone ug/L ND 5.0 12/29/15 06:110.46
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/29/15 06:110.33
Acetone ug/L ND 25.0 12/29/15 06:1110.0
Acrylonitrile ug/L ND 10.0 12/29/15 06:111.9
Benzene ug/L ND 1.0 12/29/15 06:110.25
Bromochloromethane ug/L ND 1.0 12/29/15 06:110.17
Bromodichloromethane ug/L ND 1.0 12/29/15 06:110.18
Bromoform ug/L ND 1.0 12/29/15 06:110.26
Bromomethane ug/L ND 2.0 12/29/15 06:110.29
Carbon disulfide ug/L ND 2.0 12/29/15 06:111.2
Carbon tetrachloride ug/L ND 1.0 12/29/15 06:110.25
Chlorobenzene ug/L ND 1.0 12/29/15 06:110.23
Chloroethane ug/L ND 1.0 12/29/15 06:110.54
Chloroform ug/L ND 1.0 12/29/15 06:110.14
Chloromethane ug/L ND 1.0 12/29/15 06:110.11
cis-1,2-Dichloroethene ug/L ND 1.0 12/29/15 06:110.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/29/15 06:110.13
Dibromochloromethane ug/L ND 1.0 12/29/15 06:110.21
Dibromomethane ug/L ND 1.0 12/29/15 06:110.21
Ethylbenzene ug/L ND 1.0 12/29/15 06:110.30
Iodomethane ug/L ND 5.0 12/29/15 06:110.32
m&p-Xylene ug/L ND 2.0 12/29/15 06:110.66
Methylene Chloride ug/L ND 1.0 12/29/15 06:110.97
o-Xylene ug/L ND 1.0 12/29/15 06:110.23
Styrene ug/L ND 1.0 12/29/15 06:110.26
Tetrachloroethene ug/L ND 1.0 12/29/15 06:110.46
Toluene ug/L ND 1.0 12/29/15 06:110.26
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280045
CLAY CO MW#2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1638140
Associated Lab Samples:92280045001
Matrix: Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 1.0 12/29/15 06:110.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/29/15 06:110.26
trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/29/15 06:111.0
Trichloroethene ug/L ND 1.0 12/29/15 06:110.47
Trichlorofluoromethane ug/L ND 1.0 12/29/15 06:110.20
Vinyl acetate ug/L ND 2.0 12/29/15 06:110.35
Vinyl chloride ug/L ND 1.0 12/29/15 06:110.62
Xylene (Total)ug/L ND 2.0 12/29/15 06:110.66
1,2-Dichloroethane-d4 (S)%91 70-130 12/29/15 06:11
4-Bromofluorobenzene (S)%102 70-130 12/29/15 06:11
Toluene-d8 (S)%109 70-130 12/29/15 06:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1638141LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.650 101 80-125
1,1,1-Trichloroethane ug/L 48.050 96 71-129
1,1,2,2-Tetrachloroethane ug/L 50.650 101 79-124
1,1,2-Trichloroethane ug/L 50.950 102 85-125
1,1-Dichloroethane ug/L 45.250 90 73-126
1,1-Dichloroethene ug/L 43.650 87 66-135
1,2,3-Trichloropropane ug/L 51.250 102 75-130
1,2-Dibromo-3-chloropropane ug/L 47.850 96 71-133
1,2-Dibromoethane (EDB)ug/L 53.450 107 83-124
1,2-Dichlorobenzene ug/L 49.150 98 80-133
1,2-Dichloroethane ug/L 45.650 91 67-128
1,2-Dichloropropane ug/L 46.850 94 75-132
1,4-Dichlorobenzene ug/L 49.250 98 78-130
2-Butanone (MEK)ug/L 113100 113 61-144
2-Hexanone ug/L 108100 108 68-143
4-Methyl-2-pentanone (MIBK)ug/L 107100 107 72-135
Acetone ug/L 105100 105 48-146
Acrylonitrile ug/L 255250 102 40-160
Benzene ug/L 49.050 98 80-125
Bromochloromethane ug/L 53.750 107 71-125
Bromodichloromethane ug/L 48.150 96 78-124
Bromoform ug/L 43.750 87 71-128
Bromomethane ug/L 40.450 81 40-160
Carbon disulfide ug/L 41.050 82 50-160
Carbon tetrachloride ug/L 49.150 98 69-131
Chlorobenzene ug/L 49.950 100 81-122
Chloroethane ug/L 33.950 68 39-148
Chloroform ug/L 47.650 95 73-127
Chloromethane ug/L 53.750 107 44-146
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280045
CLAY CO MW#2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1638141LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 44.950 90 74-124
cis-1,3-Dichloropropene ug/L 50.850 102 72-132
Dibromochloromethane ug/L 52.850 106 78-125
Dibromomethane ug/L 52.250 104 82-120
Ethylbenzene ug/L 46.550 93 79-121
Iodomethane ug/L 85.5100 86 39-154
m&p-Xylene ug/L 91.9100 92 81-124
Methylene Chloride ug/L 57.250 114 64-133
o-Xylene ug/L 44.950 90 79-131
Styrene ug/L 48.050 96 84-126
Tetrachloroethene ug/L 49.350 99 78-122
Toluene ug/L 45.050 90 80-121
trans-1,2-Dichloroethene ug/L 47.850 96 71-127
trans-1,3-Dichloropropene ug/L 45.450 91 69-141
trans-1,4-Dichloro-2-butene ug/L 54.350 109 40-160
Trichloroethene ug/L 52.550 105 78-122
Trichlorofluoromethane ug/L 43.350 87 53-137
Vinyl acetate ug/L 99.6100 100 40-160
Vinyl chloride ug/L 46.150 92 58-137
Xylene (Total)ug/L 137150 91 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%94 70-130
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92280045
CLAY CO MW#2
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Common Laboratory Contaminant.C9
REPORT OF LABORATORY ANALYSIS
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92280045
CLAY CO MW#2
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92280045001 MPRP/20312 ICP/18330MW#2 EPA 3010A EPA 6010
92280045001 MERP/8799 MERC/8455MW#2 EPA 7470 EPA 7470
92280045001 MSV/34968MW#2 EPA 8260
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Page 15 of 16
Page 16 of 16
#=CL#
January 12, 2016
LIMS USE: FR - MARK TEAGUE
LIMS OBJECT ID: 92280033
92280033
Project:
Pace Project No.:
RE:
Mr. Mark Teague
Environmental, Inc.
PO Box 954
Cullowhee, NC 28723
Clay Co MW #3
Dear Mr. Teague:
Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
A revised laboratory report is being submitted on January 12, 2016, to report MDLs, per client
request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
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#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92280033
Clay Co MW #3
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92280033
Clay Co MW #3
Lab ID Sample ID Matrix Date Collected Date Received
92280033001 MW #3 Water 12/15/15 10:41 12/16/15 11:33
REPORT OF LABORATORY ANALYSIS
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92280033
Clay Co MW #3
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92280033001 MW #3 EPA 6010 15 PASI-ACDF, JMW
EPA 7470 1 PASI-ASH1
EPA 8260 52 PASI-CGAW
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92280033
Clay Co MW #3
Sample: MW #3 Lab ID: 92280033001 Collected: 12/15/15 10:41 Received: 12/16/15 11:33 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/19/15 05:50 7440-36-012/17/15 19:005.0 3.8 1
Arsenic ND ug/L 12/19/15 05:50 7440-38-212/17/15 19:0010.0 2.5 1
Barium 145 ug/L 12/19/15 05:50 7440-39-312/17/15 19:005.0 2.5 1
Beryllium ND ug/L 12/19/15 05:50 7440-41-712/17/15 19:001.0 0.50 1
Cadmium ND ug/L 12/19/15 05:50 7440-43-912/17/15 19:001.0 0.50 1
Chromium 6.2 ug/L 12/19/15 05:50 7440-47-312/17/15 19:005.0 2.5 1
Cobalt 7.9 ug/L 12/19/15 05:50 7440-48-412/17/15 19:005.0 2.5 1
Copper 11.0 ug/L 12/19/15 05:50 7440-50-812/17/15 19:005.0 2.5 1
Lead 13.8 ug/L 12/19/15 05:50 7439-92-112/17/15 19:005.0 2.5 1
Nickel ND ug/L 12/19/15 05:50 7440-02-012/17/15 19:005.0 2.5 1
Selenium ND ug/L 12/19/15 05:50 7782-49-212/17/15 19:0010.0 5.0 1
Silver ND ug/L 12/19/15 05:50 7440-22-412/17/15 19:005.0 2.5 1
Thallium ND ug/L 12/22/15 17:54 7440-28-012/17/15 19:005.4 5.0 1
Vanadium 10.2 ug/L 12/19/15 05:50 7440-62-212/17/15 19:005.0 2.5 1
Zinc 44.5 ug/L 12/19/15 05:50 7440-66-612/17/15 19:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/21/15 12:23 7439-97-612/19/15 18:300.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/29/15 13:44 67-64-125.0 10.0 1
Acrylonitrile ND ug/L 12/29/15 13:44 107-13-110.0 1.9 1
Benzene ND ug/L 12/29/15 13:44 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/29/15 13:44 74-97-51.0 0.17 1
Bromodichloromethane ND ug/L 12/29/15 13:44 75-27-41.0 0.18 1
Bromoform ND ug/L 12/29/15 13:44 75-25-21.0 0.26 1
Bromomethane ND ug/L 12/29/15 13:44 74-83-92.0 0.29 1
2-Butanone (MEK)ND ug/L 12/29/15 13:44 78-93-35.0 0.96 1
Carbon disulfide ND ug/L 12/29/15 13:44 75-15-02.0 1.2 1
Carbon tetrachloride ND ug/L 12/29/15 13:44 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/29/15 13:44 108-90-71.0 0.23 1
Chloroethane ND ug/L 12/29/15 13:44 75-00-31.0 0.54 1
Chloroform ND ug/L 12/29/15 13:44 67-66-31.0 0.14 1
Chloromethane ND ug/L 12/29/15 13:44 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/29/15 13:44 96-12-82.0 2.0 1
Dibromochloromethane ND ug/L 12/29/15 13:44 124-48-11.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/29/15 13:44 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/29/15 13:44 74-95-31.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/29/15 13:44 95-50-11.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/29/15 13:44 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/29/15 13:44 110-57-61.0 1.0 1
1,1-Dichloroethane ND ug/L 12/29/15 13:44 75-34-31.0 0.32 1
1,2-Dichloroethane ND ug/L 12/29/15 13:44 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/29/15 13:44 75-35-41.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/29/15 13:44 156-59-21.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/29/15 13:44 156-60-51.0 0.49 1
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92280033
Clay Co MW #3
Sample: MW #3 Lab ID: 92280033001 Collected: 12/15/15 10:41 Received: 12/16/15 11:33 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/29/15 13:44 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/29/15 13:44 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/29/15 13:44 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/29/15 13:44 100-41-41.0 0.30 1
2-Hexanone 20.4 ug/L 12/29/15 13:44 591-78-65.0 0.46 1
Iodomethane ND ug/L 12/29/15 13:44 74-88-45.0 0.32 1
Methylene Chloride ND ug/L 12/29/15 13:44 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/29/15 13:44 108-10-15.0 0.33 1
Styrene ND ug/L 12/29/15 13:44 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/29/15 13:44 630-20-61.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/29/15 13:44 79-34-51.0 0.40 1
Tetrachloroethene ND ug/L 12/29/15 13:44 127-18-41.0 0.46 1
Toluene ND ug/L 12/29/15 13:44 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/29/15 13:44 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/29/15 13:44 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/29/15 13:44 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/29/15 13:44 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/29/15 13:44 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/29/15 13:44 108-05-42.0 0.35 1
Vinyl chloride ND ug/L 12/29/15 13:44 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/29/15 13:44 1330-20-72.0 0.66 1
m&p-Xylene ND ug/L 12/29/15 13:44 179601-23-12.0 0.66 1
o-Xylene ND ug/L 12/29/15 13:44 95-47-61.0 0.23 1
Surrogates
4-Bromofluorobenzene (S)104 %12/29/15 13:44 460-00-470-130 1
1,2-Dichloroethane-d4 (S)95 %12/29/15 13:44 17060-07-070-130 1
Toluene-d8 (S)108 %12/29/15 13:44 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280033
Clay Co MW #3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8799
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92280033001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1632840
Associated Lab Samples:92280033001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/21/15 11:410.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1632841LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.12.5 84 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1632842MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279477001
1632844
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 92 75-12575 20 252.5ND 2.4 1.9
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280033
Clay Co MW #3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20312
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92280033001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1631789
Associated Lab Samples:92280033001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 12/19/15 05:133.8
Arsenic ug/L ND 10.0 12/19/15 05:132.5
Barium ug/L ND 5.0 12/19/15 05:132.5
Beryllium ug/L ND 1.0 12/19/15 05:130.50
Cadmium ug/L ND 1.0 12/19/15 05:130.50
Chromium ug/L ND 5.0 12/19/15 05:132.5
Cobalt ug/L ND 5.0 12/19/15 05:132.5
Copper ug/L ND 5.0 12/19/15 05:132.5
Lead ug/L ND 5.0 12/19/15 05:132.5
Nickel ug/L ND 5.0 12/19/15 05:132.5
Selenium ug/L ND 10.0 12/19/15 05:135.0
Silver ug/L ND 5.0 12/19/15 05:132.5
Thallium ug/L ND 5.4 12/22/15 17:355.0
Vanadium ug/L ND 5.0 12/19/15 05:132.5
Zinc ug/L ND 10.0 12/19/15 05:135.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1631790LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 489500 98 80-120
Arsenic ug/L 526500 105 80-120
Barium ug/L 496500 99 80-120
Beryllium ug/L 502500 100 80-120
Cadmium ug/L 519500 104 80-120
Chromium ug/L 529500 106 80-120
Cobalt ug/L 530500 106 80-120
Copper ug/L 515500 103 80-120
Lead ug/L 524500 105 80-120
Nickel ug/L 524500 105 80-120
Selenium ug/L 520500 104 80-120
Silver ug/L 233250 93 80-120
Thallium ug/L 522500 104 80-120
Vanadium ug/L 518500 104 80-120
Zinc ug/L 554500 111 80-120
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280033
Clay Co MW #3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1631791MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279775001
1631792
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 99 75-12597 2 25500ND495 483
Arsenic ug/L 500 107 75-125104 3 25500ND537 519
Barium ug/L 500 101 75-12598 3 25500108614 597
Beryllium ug/L 500 103 75-125100 3 25500ND515 499
Cadmium ug/L 500 105 75-125102 3 25500ND526 510
Chromium ug/L 500 107 75-125105 3 25500ND538 524
Cobalt ug/L 500 107 75-125104 3 2550010.9 546 528
Copper ug/L 500 105 75-125101 3 25500ND524 508
Lead ug/L 500 105 75-125102 3 25500ND526 510
Nickel ug/L 500 105 75-125102 3 255006.7 534 517
Selenium ug/L 500 104 75-125101 2 25500ND520 508
Silver ug/L 250 95 75-12592 4 25250ND238 230
Thallium ug/L 500 98 75-12597 1 25500ND488 483
Vanadium ug/L 500 106 75-125103 3 255002.9J 534 517
Zinc ug/L 500 112 75-125109 2 2550020.2 581 567
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280033
Clay Co MW #3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34968
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92280033001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1638140
Associated Lab Samples:92280033001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/29/15 06:110.33
1,1,1-Trichloroethane ug/L ND 1.0 12/29/15 06:110.48
1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/29/15 06:110.40
1,1,2-Trichloroethane ug/L ND 1.0 12/29/15 06:110.29
1,1-Dichloroethane ug/L ND 1.0 12/29/15 06:110.32
1,1-Dichloroethene ug/L ND 1.0 12/29/15 06:110.56
1,2,3-Trichloropropane ug/L ND 1.0 12/29/15 06:110.41
1,2-Dibromo-3-chloropropane ug/L ND 2.0 12/29/15 06:112.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/29/15 06:110.27
1,2-Dichlorobenzene ug/L ND 1.0 12/29/15 06:110.30
1,2-Dichloroethane ug/L ND 1.0 12/29/15 06:110.24
1,2-Dichloropropane ug/L ND 1.0 12/29/15 06:110.27
1,4-Dichlorobenzene ug/L ND 1.0 12/29/15 06:110.33
2-Butanone (MEK)ug/L ND 5.0 12/29/15 06:110.96
2-Hexanone ug/L ND 5.0 12/29/15 06:110.46
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/29/15 06:110.33
Acetone ug/L ND 25.0 12/29/15 06:1110.0
Acrylonitrile ug/L ND 10.0 12/29/15 06:111.9
Benzene ug/L ND 1.0 12/29/15 06:110.25
Bromochloromethane ug/L ND 1.0 12/29/15 06:110.17
Bromodichloromethane ug/L ND 1.0 12/29/15 06:110.18
Bromoform ug/L ND 1.0 12/29/15 06:110.26
Bromomethane ug/L ND 2.0 12/29/15 06:110.29
Carbon disulfide ug/L ND 2.0 12/29/15 06:111.2
Carbon tetrachloride ug/L ND 1.0 12/29/15 06:110.25
Chlorobenzene ug/L ND 1.0 12/29/15 06:110.23
Chloroethane ug/L ND 1.0 12/29/15 06:110.54
Chloroform ug/L ND 1.0 12/29/15 06:110.14
Chloromethane ug/L ND 1.0 12/29/15 06:110.11
cis-1,2-Dichloroethene ug/L ND 1.0 12/29/15 06:110.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/29/15 06:110.13
Dibromochloromethane ug/L ND 1.0 12/29/15 06:110.21
Dibromomethane ug/L ND 1.0 12/29/15 06:110.21
Ethylbenzene ug/L ND 1.0 12/29/15 06:110.30
Iodomethane ug/L ND 5.0 12/29/15 06:110.32
m&p-Xylene ug/L ND 2.0 12/29/15 06:110.66
Methylene Chloride ug/L ND 1.0 12/29/15 06:110.97
o-Xylene ug/L ND 1.0 12/29/15 06:110.23
Styrene ug/L ND 1.0 12/29/15 06:110.26
Tetrachloroethene ug/L ND 1.0 12/29/15 06:110.46
Toluene ug/L ND 1.0 12/29/15 06:110.26
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280033
Clay Co MW #3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1638140
Associated Lab Samples:92280033001
Matrix: Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 1.0 12/29/15 06:110.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/29/15 06:110.26
trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/29/15 06:111.0
Trichloroethene ug/L ND 1.0 12/29/15 06:110.47
Trichlorofluoromethane ug/L ND 1.0 12/29/15 06:110.20
Vinyl acetate ug/L ND 2.0 12/29/15 06:110.35
Vinyl chloride ug/L ND 1.0 12/29/15 06:110.62
Xylene (Total)ug/L ND 2.0 12/29/15 06:110.66
1,2-Dichloroethane-d4 (S)%91 70-130 12/29/15 06:11
4-Bromofluorobenzene (S)%102 70-130 12/29/15 06:11
Toluene-d8 (S)%109 70-130 12/29/15 06:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1638141LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.650 101 80-125
1,1,1-Trichloroethane ug/L 48.050 96 71-129
1,1,2,2-Tetrachloroethane ug/L 50.650 101 79-124
1,1,2-Trichloroethane ug/L 50.950 102 85-125
1,1-Dichloroethane ug/L 45.250 90 73-126
1,1-Dichloroethene ug/L 43.650 87 66-135
1,2,3-Trichloropropane ug/L 51.250 102 75-130
1,2-Dibromo-3-chloropropane ug/L 47.850 96 71-133
1,2-Dibromoethane (EDB)ug/L 53.450 107 83-124
1,2-Dichlorobenzene ug/L 49.150 98 80-133
1,2-Dichloroethane ug/L 45.650 91 67-128
1,2-Dichloropropane ug/L 46.850 94 75-132
1,4-Dichlorobenzene ug/L 49.250 98 78-130
2-Butanone (MEK)ug/L 113100 113 61-144
2-Hexanone ug/L 108100 108 68-143
4-Methyl-2-pentanone (MIBK)ug/L 107100 107 72-135
Acetone ug/L 105100 105 48-146
Acrylonitrile ug/L 255250 102 40-160
Benzene ug/L 49.050 98 80-125
Bromochloromethane ug/L 53.750 107 71-125
Bromodichloromethane ug/L 48.150 96 78-124
Bromoform ug/L 43.750 87 71-128
Bromomethane ug/L 40.450 81 40-160
Carbon disulfide ug/L 41.050 82 50-160
Carbon tetrachloride ug/L 49.150 98 69-131
Chlorobenzene ug/L 49.950 100 81-122
Chloroethane ug/L 33.950 68 39-148
Chloroform ug/L 47.650 95 73-127
Chloromethane ug/L 53.750 107 44-146
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280033
Clay Co MW #3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1638141LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 44.950 90 74-124
cis-1,3-Dichloropropene ug/L 50.850 102 72-132
Dibromochloromethane ug/L 52.850 106 78-125
Dibromomethane ug/L 52.250 104 82-120
Ethylbenzene ug/L 46.550 93 79-121
Iodomethane ug/L 85.5100 86 39-154
m&p-Xylene ug/L 91.9100 92 81-124
Methylene Chloride ug/L 57.250 114 64-133
o-Xylene ug/L 44.950 90 79-131
Styrene ug/L 48.050 96 84-126
Tetrachloroethene ug/L 49.350 99 78-122
Toluene ug/L 45.050 90 80-121
trans-1,2-Dichloroethene ug/L 47.850 96 71-127
trans-1,3-Dichloropropene ug/L 45.450 91 69-141
trans-1,4-Dichloro-2-butene ug/L 54.350 109 40-160
Trichloroethene ug/L 52.550 105 78-122
Trichlorofluoromethane ug/L 43.350 87 53-137
Vinyl acetate ug/L 99.6100 100 40-160
Vinyl chloride ug/L 46.150 92 58-137
Xylene (Total)ug/L 137150 91 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%94 70-130
REPORT OF LABORATORY ANALYSIS
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92280033
Clay Co MW #3
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
REPORT OF LABORATORY ANALYSIS
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92280033
Clay Co MW #3
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92280033001 MPRP/20312 ICP/18330MW #3 EPA 3010A EPA 6010
92280033001 MERP/8799 MERC/8455MW #3 EPA 7470 EPA 7470
92280033001 MSV/34968MW #3 EPA 8260
REPORT OF LABORATORY ANALYSIS
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Page 15 of 16
Page 16 of 16
#=CL#
January 12, 2016
LIMS USE: FR - MARK TEAGUE
LIMS OBJECT ID: 92280031
92280031
Project:
Pace Project No.:
RE:
Mr. Mark Teague
Environmental, Inc.
PO Box 954
Cullowhee, NC 28723
Clay Co MW #4
Dear Mr. Teague:
Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
A revised laboratory report is being submitted on January 12, 2016, to report MDLs, per client
request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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Page 1 of 16
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92280031
Clay Co MW #4
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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Page 2 of 16
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92280031
Clay Co MW #4
Lab ID Sample ID Matrix Date Collected Date Received
92280031001 MW #4 Water 12/15/15 11:50 12/16/15 11:33
REPORT OF LABORATORY ANALYSIS
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92280031
Clay Co MW #4
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92280031001 MW #4 EPA 6010 15 PASI-ACDF, JMW
EPA 7470 1 PASI-ASH1
EPA 8260 52 PASI-CGAW
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92280031
Clay Co MW #4
Sample: MW #4 Lab ID: 92280031001 Collected: 12/15/15 11:50 Received: 12/16/15 11:33 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/19/15 05:47 7440-36-012/17/15 19:005.0 3.8 1
Arsenic ND ug/L 12/19/15 05:47 7440-38-212/17/15 19:0010.0 2.5 1
Barium 231 ug/L 12/19/15 05:47 7440-39-312/17/15 19:005.0 2.5 1
Beryllium ND ug/L 12/19/15 05:47 7440-41-712/17/15 19:001.0 0.50 1
Cadmium ND ug/L 12/19/15 05:47 7440-43-912/17/15 19:001.0 0.50 1
Chromium ND ug/L 12/19/15 05:47 7440-47-312/17/15 19:005.0 2.5 1
Cobalt 11.5 ug/L 12/19/15 05:47 7440-48-412/17/15 19:005.0 2.5 1
Copper 6.2 ug/L 12/19/15 05:47 7440-50-812/17/15 19:005.0 2.5 1
Lead ND ug/L 12/19/15 05:47 7439-92-112/17/15 19:005.0 2.5 1
Nickel ND ug/L 12/19/15 05:47 7440-02-012/17/15 19:005.0 2.5 1
Selenium ND ug/L 12/19/15 05:47 7782-49-212/17/15 19:0010.0 5.0 1
Silver ND ug/L 12/19/15 05:47 7440-22-412/17/15 19:005.0 2.5 1
Thallium ND ug/L 12/22/15 17:51 7440-28-012/17/15 19:005.4 5.0 1
Vanadium 5.0 ug/L 12/19/15 05:47 7440-62-212/17/15 19:005.0 2.5 1
Zinc 19.5 ug/L 12/19/15 05:47 7440-66-612/17/15 19:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury 0.20 ug/L 12/21/15 12:20 7439-97-612/19/15 18:300.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/29/15 13:27 67-64-125.0 10.0 1
Acrylonitrile ND ug/L 12/29/15 13:27 107-13-110.0 1.9 1
Benzene ND ug/L 12/29/15 13:27 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/29/15 13:27 74-97-51.0 0.17 1
Bromodichloromethane ND ug/L 12/29/15 13:27 75-27-41.0 0.18 1
Bromoform ND ug/L 12/29/15 13:27 75-25-21.0 0.26 1
Bromomethane ND ug/L 12/29/15 13:27 74-83-92.0 0.29 1
2-Butanone (MEK)ND ug/L 12/29/15 13:27 78-93-35.0 0.96 1
Carbon disulfide ND ug/L 12/29/15 13:27 75-15-02.0 1.2 1
Carbon tetrachloride ND ug/L 12/29/15 13:27 56-23-51.0 0.25 1
Chlorobenzene 0.36J ug/L 12/29/15 13:27 108-90-71.0 0.23 1
Chloroethane ND ug/L 12/29/15 13:27 75-00-31.0 0.54 1
Chloroform ND ug/L 12/29/15 13:27 67-66-31.0 0.14 1
Chloromethane ND ug/L 12/29/15 13:27 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/29/15 13:27 96-12-82.0 2.0 1
Dibromochloromethane ND ug/L 12/29/15 13:27 124-48-11.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/29/15 13:27 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/29/15 13:27 74-95-31.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/29/15 13:27 95-50-11.0 0.30 1
1,4-Dichlorobenzene 1.6 ug/L 12/29/15 13:27 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/29/15 13:27 110-57-61.0 1.0 1
1,1-Dichloroethane 0.97J ug/L 12/29/15 13:27 75-34-31.0 0.32 1
1,2-Dichloroethane ND ug/L 12/29/15 13:27 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/29/15 13:27 75-35-41.0 0.56 1
cis-1,2-Dichloroethene 2.4 ug/L 12/29/15 13:27 156-59-21.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/29/15 13:27 156-60-51.0 0.49 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92280031
Clay Co MW #4
Sample: MW #4 Lab ID: 92280031001 Collected: 12/15/15 11:50 Received: 12/16/15 11:33 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/29/15 13:27 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/29/15 13:27 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/29/15 13:27 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/29/15 13:27 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/29/15 13:27 591-78-65.0 0.46 1
Iodomethane ND ug/L 12/29/15 13:27 74-88-45.0 0.32 1
Methylene Chloride ND ug/L 12/29/15 13:27 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/29/15 13:27 108-10-15.0 0.33 1
Styrene ND ug/L 12/29/15 13:27 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/29/15 13:27 630-20-61.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/29/15 13:27 79-34-51.0 0.40 1
Tetrachloroethene ND ug/L 12/29/15 13:27 127-18-41.0 0.46 1
Toluene ND ug/L 12/29/15 13:27 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/29/15 13:27 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/29/15 13:27 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/29/15 13:27 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/29/15 13:27 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/29/15 13:27 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/29/15 13:27 108-05-42.0 0.35 1
Vinyl chloride ND ug/L 12/29/15 13:27 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/29/15 13:27 1330-20-72.0 0.66 1
m&p-Xylene ND ug/L 12/29/15 13:27 179601-23-12.0 0.66 1
o-Xylene ND ug/L 12/29/15 13:27 95-47-61.0 0.23 1
Surrogates
4-Bromofluorobenzene (S)105 %12/29/15 13:27 460-00-470-130 1
1,2-Dichloroethane-d4 (S)97 %12/29/15 13:27 17060-07-070-130 1
Toluene-d8 (S)102 %12/29/15 13:27 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280031
Clay Co MW #4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8799
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92280031001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1632840
Associated Lab Samples:92280031001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/21/15 11:410.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1632841LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.12.5 84 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1632842MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279477001
1632844
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 92 75-12575 20 252.5ND 2.4 1.9
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280031
Clay Co MW #4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20312
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92280031001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1631789
Associated Lab Samples:92280031001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 12/19/15 05:133.8
Arsenic ug/L ND 10.0 12/19/15 05:132.5
Barium ug/L ND 5.0 12/19/15 05:132.5
Beryllium ug/L ND 1.0 12/19/15 05:130.50
Cadmium ug/L ND 1.0 12/19/15 05:130.50
Chromium ug/L ND 5.0 12/19/15 05:132.5
Cobalt ug/L ND 5.0 12/19/15 05:132.5
Copper ug/L ND 5.0 12/19/15 05:132.5
Lead ug/L ND 5.0 12/19/15 05:132.5
Nickel ug/L ND 5.0 12/19/15 05:132.5
Selenium ug/L ND 10.0 12/19/15 05:135.0
Silver ug/L ND 5.0 12/19/15 05:132.5
Thallium ug/L ND 5.4 12/22/15 17:355.0
Vanadium ug/L ND 5.0 12/19/15 05:132.5
Zinc ug/L ND 10.0 12/19/15 05:135.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1631790LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 489500 98 80-120
Arsenic ug/L 526500 105 80-120
Barium ug/L 496500 99 80-120
Beryllium ug/L 502500 100 80-120
Cadmium ug/L 519500 104 80-120
Chromium ug/L 529500 106 80-120
Cobalt ug/L 530500 106 80-120
Copper ug/L 515500 103 80-120
Lead ug/L 524500 105 80-120
Nickel ug/L 524500 105 80-120
Selenium ug/L 520500 104 80-120
Silver ug/L 233250 93 80-120
Thallium ug/L 522500 104 80-120
Vanadium ug/L 518500 104 80-120
Zinc ug/L 554500 111 80-120
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280031
Clay Co MW #4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1631791MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279775001
1631792
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 99 75-12597 2 25500ND495 483
Arsenic ug/L 500 107 75-125104 3 25500ND537 519
Barium ug/L 500 101 75-12598 3 25500108614 597
Beryllium ug/L 500 103 75-125100 3 25500ND515 499
Cadmium ug/L 500 105 75-125102 3 25500ND526 510
Chromium ug/L 500 107 75-125105 3 25500ND538 524
Cobalt ug/L 500 107 75-125104 3 2550010.9 546 528
Copper ug/L 500 105 75-125101 3 25500ND524 508
Lead ug/L 500 105 75-125102 3 25500ND526 510
Nickel ug/L 500 105 75-125102 3 255006.7 534 517
Selenium ug/L 500 104 75-125101 2 25500ND520 508
Silver ug/L 250 95 75-12592 4 25250ND238 230
Thallium ug/L 500 98 75-12597 1 25500ND488 483
Vanadium ug/L 500 106 75-125103 3 255002.9J 534 517
Zinc ug/L 500 112 75-125109 2 2550020.2 581 567
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280031
Clay Co MW #4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34968
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92280031001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1638140
Associated Lab Samples:92280031001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/29/15 06:110.33
1,1,1-Trichloroethane ug/L ND 1.0 12/29/15 06:110.48
1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/29/15 06:110.40
1,1,2-Trichloroethane ug/L ND 1.0 12/29/15 06:110.29
1,1-Dichloroethane ug/L ND 1.0 12/29/15 06:110.32
1,1-Dichloroethene ug/L ND 1.0 12/29/15 06:110.56
1,2,3-Trichloropropane ug/L ND 1.0 12/29/15 06:110.41
1,2-Dibromo-3-chloropropane ug/L ND 2.0 12/29/15 06:112.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/29/15 06:110.27
1,2-Dichlorobenzene ug/L ND 1.0 12/29/15 06:110.30
1,2-Dichloroethane ug/L ND 1.0 12/29/15 06:110.24
1,2-Dichloropropane ug/L ND 1.0 12/29/15 06:110.27
1,4-Dichlorobenzene ug/L ND 1.0 12/29/15 06:110.33
2-Butanone (MEK)ug/L ND 5.0 12/29/15 06:110.96
2-Hexanone ug/L ND 5.0 12/29/15 06:110.46
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/29/15 06:110.33
Acetone ug/L ND 25.0 12/29/15 06:1110.0
Acrylonitrile ug/L ND 10.0 12/29/15 06:111.9
Benzene ug/L ND 1.0 12/29/15 06:110.25
Bromochloromethane ug/L ND 1.0 12/29/15 06:110.17
Bromodichloromethane ug/L ND 1.0 12/29/15 06:110.18
Bromoform ug/L ND 1.0 12/29/15 06:110.26
Bromomethane ug/L ND 2.0 12/29/15 06:110.29
Carbon disulfide ug/L ND 2.0 12/29/15 06:111.2
Carbon tetrachloride ug/L ND 1.0 12/29/15 06:110.25
Chlorobenzene ug/L ND 1.0 12/29/15 06:110.23
Chloroethane ug/L ND 1.0 12/29/15 06:110.54
Chloroform ug/L ND 1.0 12/29/15 06:110.14
Chloromethane ug/L ND 1.0 12/29/15 06:110.11
cis-1,2-Dichloroethene ug/L ND 1.0 12/29/15 06:110.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/29/15 06:110.13
Dibromochloromethane ug/L ND 1.0 12/29/15 06:110.21
Dibromomethane ug/L ND 1.0 12/29/15 06:110.21
Ethylbenzene ug/L ND 1.0 12/29/15 06:110.30
Iodomethane ug/L ND 5.0 12/29/15 06:110.32
m&p-Xylene ug/L ND 2.0 12/29/15 06:110.66
Methylene Chloride ug/L ND 1.0 12/29/15 06:110.97
o-Xylene ug/L ND 1.0 12/29/15 06:110.23
Styrene ug/L ND 1.0 12/29/15 06:110.26
Tetrachloroethene ug/L ND 1.0 12/29/15 06:110.46
Toluene ug/L ND 1.0 12/29/15 06:110.26
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280031
Clay Co MW #4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1638140
Associated Lab Samples:92280031001
Matrix: Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 1.0 12/29/15 06:110.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/29/15 06:110.26
trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/29/15 06:111.0
Trichloroethene ug/L ND 1.0 12/29/15 06:110.47
Trichlorofluoromethane ug/L ND 1.0 12/29/15 06:110.20
Vinyl acetate ug/L ND 2.0 12/29/15 06:110.35
Vinyl chloride ug/L ND 1.0 12/29/15 06:110.62
Xylene (Total)ug/L ND 2.0 12/29/15 06:110.66
1,2-Dichloroethane-d4 (S)%91 70-130 12/29/15 06:11
4-Bromofluorobenzene (S)%102 70-130 12/29/15 06:11
Toluene-d8 (S)%109 70-130 12/29/15 06:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1638141LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.650 101 80-125
1,1,1-Trichloroethane ug/L 48.050 96 71-129
1,1,2,2-Tetrachloroethane ug/L 50.650 101 79-124
1,1,2-Trichloroethane ug/L 50.950 102 85-125
1,1-Dichloroethane ug/L 45.250 90 73-126
1,1-Dichloroethene ug/L 43.650 87 66-135
1,2,3-Trichloropropane ug/L 51.250 102 75-130
1,2-Dibromo-3-chloropropane ug/L 47.850 96 71-133
1,2-Dibromoethane (EDB)ug/L 53.450 107 83-124
1,2-Dichlorobenzene ug/L 49.150 98 80-133
1,2-Dichloroethane ug/L 45.650 91 67-128
1,2-Dichloropropane ug/L 46.850 94 75-132
1,4-Dichlorobenzene ug/L 49.250 98 78-130
2-Butanone (MEK)ug/L 113100 113 61-144
2-Hexanone ug/L 108100 108 68-143
4-Methyl-2-pentanone (MIBK)ug/L 107100 107 72-135
Acetone ug/L 105100 105 48-146
Acrylonitrile ug/L 255250 102 40-160
Benzene ug/L 49.050 98 80-125
Bromochloromethane ug/L 53.750 107 71-125
Bromodichloromethane ug/L 48.150 96 78-124
Bromoform ug/L 43.750 87 71-128
Bromomethane ug/L 40.450 81 40-160
Carbon disulfide ug/L 41.050 82 50-160
Carbon tetrachloride ug/L 49.150 98 69-131
Chlorobenzene ug/L 49.950 100 81-122
Chloroethane ug/L 33.950 68 39-148
Chloroform ug/L 47.650 95 73-127
Chloromethane ug/L 53.750 107 44-146
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280031
Clay Co MW #4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1638141LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 44.950 90 74-124
cis-1,3-Dichloropropene ug/L 50.850 102 72-132
Dibromochloromethane ug/L 52.850 106 78-125
Dibromomethane ug/L 52.250 104 82-120
Ethylbenzene ug/L 46.550 93 79-121
Iodomethane ug/L 85.5100 86 39-154
m&p-Xylene ug/L 91.9100 92 81-124
Methylene Chloride ug/L 57.250 114 64-133
o-Xylene ug/L 44.950 90 79-131
Styrene ug/L 48.050 96 84-126
Tetrachloroethene ug/L 49.350 99 78-122
Toluene ug/L 45.050 90 80-121
trans-1,2-Dichloroethene ug/L 47.850 96 71-127
trans-1,3-Dichloropropene ug/L 45.450 91 69-141
trans-1,4-Dichloro-2-butene ug/L 54.350 109 40-160
Trichloroethene ug/L 52.550 105 78-122
Trichlorofluoromethane ug/L 43.350 87 53-137
Vinyl acetate ug/L 99.6100 100 40-160
Vinyl chloride ug/L 46.150 92 58-137
Xylene (Total)ug/L 137150 91 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%94 70-130
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92280031
Clay Co MW #4
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92280031
Clay Co MW #4
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92280031001 MPRP/20312 ICP/18330MW #4 EPA 3010A EPA 6010
92280031001 MERP/8799 MERC/8455MW #4 EPA 7470 EPA 7470
92280031001 MSV/34968MW #4 EPA 8260
REPORT OF LABORATORY ANALYSIS
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Page 15 of 16
Page 16 of 16
#=CL#
January 12, 2016
LIMS USE: FR - MARK TEAGUE
LIMS OBJECT ID: 92280027
92280027
Project:
Pace Project No.:
RE:
Mr. Mark Teague
Environmental, Inc.
PO Box 954
Cullowhee, NC 28723
Clay Co MW-5
Dear Mr. Teague:
Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
A revised laboratory report is being submitted on January 12, 2016, to report MDLs, per client
request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
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Page 1 of 16
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92280027
Clay Co MW-5
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92280027
Clay Co MW-5
Lab ID Sample ID Matrix Date Collected Date Received
92280027001 MW-5 Water 12/15/15 11:25 12/16/15 11:33
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92280027
Clay Co MW-5
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92280027001 MW-5 EPA 6010 15 PASI-ACDF, JMW
EPA 7470 1 PASI-ASH1
EPA 8260 52 PASI-CGAW
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92280027
Clay Co MW-5
Sample: MW-5 Lab ID: 92280027001 Collected: 12/15/15 11:25 Received: 12/16/15 11:33 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/19/15 05:44 7440-36-012/17/15 19:005.0 3.8 1
Arsenic ND ug/L 12/19/15 05:44 7440-38-212/17/15 19:0010.0 2.5 1
Barium 110 ug/L 12/19/15 05:44 7440-39-312/17/15 19:005.0 2.5 1
Beryllium ND ug/L 12/19/15 05:44 7440-41-712/17/15 19:001.0 0.50 1
Cadmium ND ug/L 12/19/15 05:44 7440-43-912/17/15 19:001.0 0.50 1
Chromium ND ug/L 12/19/15 05:44 7440-47-312/17/15 19:005.0 2.5 1
Cobalt 18.9 ug/L 12/19/15 05:44 7440-48-412/17/15 19:005.0 2.5 1
Copper 7.8 ug/L 12/19/15 05:44 7440-50-812/17/15 19:005.0 2.5 1
Lead ND ug/L 12/19/15 05:44 7439-92-112/17/15 19:005.0 2.5 1
Nickel ND ug/L 12/19/15 05:44 7440-02-012/17/15 19:005.0 2.5 1
Selenium ND ug/L 12/19/15 05:44 7782-49-212/17/15 19:0010.0 5.0 1
Silver ND ug/L 12/19/15 05:44 7440-22-412/17/15 19:005.0 2.5 1
Thallium ND ug/L 12/22/15 17:48 7440-28-012/17/15 19:005.4 5.0 1
Vanadium 2.9J ug/L 12/19/15 05:44 7440-62-212/17/15 19:005.0 2.5 1
Zinc 13.9 ug/L 12/19/15 05:44 7440-66-612/17/15 19:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury 0.32 ug/L 12/21/15 12:18 7439-97-612/19/15 18:300.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/29/15 13:10 67-64-125.0 10.0 1
Acrylonitrile ND ug/L 12/29/15 13:10 107-13-110.0 1.9 1
Benzene ND ug/L 12/29/15 13:10 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/29/15 13:10 74-97-51.0 0.17 1
Bromodichloromethane ND ug/L 12/29/15 13:10 75-27-41.0 0.18 1
Bromoform ND ug/L 12/29/15 13:10 75-25-21.0 0.26 1
Bromomethane ND ug/L 12/29/15 13:10 74-83-92.0 0.29 1
2-Butanone (MEK)ND ug/L 12/29/15 13:10 78-93-35.0 0.96 1
Carbon disulfide ND ug/L 12/29/15 13:10 75-15-02.0 1.2 1
Carbon tetrachloride ND ug/L 12/29/15 13:10 56-23-51.0 0.25 1
Chlorobenzene 0.78J ug/L 12/29/15 13:10 108-90-71.0 0.23 1
Chloroethane ND ug/L 12/29/15 13:10 75-00-31.0 0.54 1
Chloroform ND ug/L 12/29/15 13:10 67-66-31.0 0.14 1
Chloromethane ND ug/L 12/29/15 13:10 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/29/15 13:10 96-12-82.0 2.0 1
Dibromochloromethane ND ug/L 12/29/15 13:10 124-48-11.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/29/15 13:10 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/29/15 13:10 74-95-31.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/29/15 13:10 95-50-11.0 0.30 1
1,4-Dichlorobenzene 1.2 ug/L 12/29/15 13:10 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/29/15 13:10 110-57-61.0 1.0 1
1,1-Dichloroethane ND ug/L 12/29/15 13:10 75-34-31.0 0.32 1
1,2-Dichloroethane ND ug/L 12/29/15 13:10 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/29/15 13:10 75-35-41.0 0.56 1
cis-1,2-Dichloroethene 3.3 ug/L 12/29/15 13:10 156-59-21.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/29/15 13:10 156-60-51.0 0.49 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92280027
Clay Co MW-5
Sample: MW-5 Lab ID: 92280027001 Collected: 12/15/15 11:25 Received: 12/16/15 11:33 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/29/15 13:10 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/29/15 13:10 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/29/15 13:10 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/29/15 13:10 100-41-41.0 0.30 1
2-Hexanone 2.6J ug/L 12/29/15 13:10 591-78-65.0 0.46 1
Iodomethane ND ug/L 12/29/15 13:10 74-88-45.0 0.32 1
Methylene Chloride 9.2 ug/L 12/29/15 13:10 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/29/15 13:10 108-10-15.0 0.33 1
Styrene ND ug/L 12/29/15 13:10 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/29/15 13:10 630-20-61.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/29/15 13:10 79-34-51.0 0.40 1
Tetrachloroethene ND ug/L 12/29/15 13:10 127-18-41.0 0.46 1
Toluene ND ug/L 12/29/15 13:10 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/29/15 13:10 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/29/15 13:10 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/29/15 13:10 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/29/15 13:10 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/29/15 13:10 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/29/15 13:10 108-05-42.0 0.35 1
Vinyl chloride ND ug/L 12/29/15 13:10 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/29/15 13:10 1330-20-72.0 0.66 1
m&p-Xylene ND ug/L 12/29/15 13:10 179601-23-12.0 0.66 1
o-Xylene ND ug/L 12/29/15 13:10 95-47-61.0 0.23 1
Surrogates
4-Bromofluorobenzene (S)105 %12/29/15 13:10 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %12/29/15 13:10 17060-07-070-130 1
Toluene-d8 (S)112 %12/29/15 13:10 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280027
Clay Co MW-5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8799
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92280027001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1632840
Associated Lab Samples:92280027001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/21/15 11:410.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1632841LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.12.5 84 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1632842MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279477001
1632844
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 92 75-12575 20 252.5ND 2.4 1.9
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280027
Clay Co MW-5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20312
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92280027001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1631789
Associated Lab Samples:92280027001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 12/19/15 05:133.8
Arsenic ug/L ND 10.0 12/19/15 05:132.5
Barium ug/L ND 5.0 12/19/15 05:132.5
Beryllium ug/L ND 1.0 12/19/15 05:130.50
Cadmium ug/L ND 1.0 12/19/15 05:130.50
Chromium ug/L ND 5.0 12/19/15 05:132.5
Cobalt ug/L ND 5.0 12/19/15 05:132.5
Copper ug/L ND 5.0 12/19/15 05:132.5
Lead ug/L ND 5.0 12/19/15 05:132.5
Nickel ug/L ND 5.0 12/19/15 05:132.5
Selenium ug/L ND 10.0 12/19/15 05:135.0
Silver ug/L ND 5.0 12/19/15 05:132.5
Thallium ug/L ND 5.4 12/22/15 17:355.0
Vanadium ug/L ND 5.0 12/19/15 05:132.5
Zinc ug/L ND 10.0 12/19/15 05:135.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1631790LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 489500 98 80-120
Arsenic ug/L 526500 105 80-120
Barium ug/L 496500 99 80-120
Beryllium ug/L 502500 100 80-120
Cadmium ug/L 519500 104 80-120
Chromium ug/L 529500 106 80-120
Cobalt ug/L 530500 106 80-120
Copper ug/L 515500 103 80-120
Lead ug/L 524500 105 80-120
Nickel ug/L 524500 105 80-120
Selenium ug/L 520500 104 80-120
Silver ug/L 233250 93 80-120
Thallium ug/L 522500 104 80-120
Vanadium ug/L 518500 104 80-120
Zinc ug/L 554500 111 80-120
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280027
Clay Co MW-5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1631791MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279775001
1631792
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 99 75-12597 2 25500ND495 483
Arsenic ug/L 500 107 75-125104 3 25500ND537 519
Barium ug/L 500 101 75-12598 3 25500108614 597
Beryllium ug/L 500 103 75-125100 3 25500ND515 499
Cadmium ug/L 500 105 75-125102 3 25500ND526 510
Chromium ug/L 500 107 75-125105 3 25500ND538 524
Cobalt ug/L 500 107 75-125104 3 2550010.9 546 528
Copper ug/L 500 105 75-125101 3 25500ND524 508
Lead ug/L 500 105 75-125102 3 25500ND526 510
Nickel ug/L 500 105 75-125102 3 255006.7 534 517
Selenium ug/L 500 104 75-125101 2 25500ND520 508
Silver ug/L 250 95 75-12592 4 25250ND238 230
Thallium ug/L 500 98 75-12597 1 25500ND488 483
Vanadium ug/L 500 106 75-125103 3 255002.9J 534 517
Zinc ug/L 500 112 75-125109 2 2550020.2 581 567
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280027
Clay Co MW-5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34968
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92280027001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1638140
Associated Lab Samples:92280027001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/29/15 06:110.33
1,1,1-Trichloroethane ug/L ND 1.0 12/29/15 06:110.48
1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/29/15 06:110.40
1,1,2-Trichloroethane ug/L ND 1.0 12/29/15 06:110.29
1,1-Dichloroethane ug/L ND 1.0 12/29/15 06:110.32
1,1-Dichloroethene ug/L ND 1.0 12/29/15 06:110.56
1,2,3-Trichloropropane ug/L ND 1.0 12/29/15 06:110.41
1,2-Dibromo-3-chloropropane ug/L ND 2.0 12/29/15 06:112.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/29/15 06:110.27
1,2-Dichlorobenzene ug/L ND 1.0 12/29/15 06:110.30
1,2-Dichloroethane ug/L ND 1.0 12/29/15 06:110.24
1,2-Dichloropropane ug/L ND 1.0 12/29/15 06:110.27
1,4-Dichlorobenzene ug/L ND 1.0 12/29/15 06:110.33
2-Butanone (MEK)ug/L ND 5.0 12/29/15 06:110.96
2-Hexanone ug/L ND 5.0 12/29/15 06:110.46
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/29/15 06:110.33
Acetone ug/L ND 25.0 12/29/15 06:1110.0
Acrylonitrile ug/L ND 10.0 12/29/15 06:111.9
Benzene ug/L ND 1.0 12/29/15 06:110.25
Bromochloromethane ug/L ND 1.0 12/29/15 06:110.17
Bromodichloromethane ug/L ND 1.0 12/29/15 06:110.18
Bromoform ug/L ND 1.0 12/29/15 06:110.26
Bromomethane ug/L ND 2.0 12/29/15 06:110.29
Carbon disulfide ug/L ND 2.0 12/29/15 06:111.2
Carbon tetrachloride ug/L ND 1.0 12/29/15 06:110.25
Chlorobenzene ug/L ND 1.0 12/29/15 06:110.23
Chloroethane ug/L ND 1.0 12/29/15 06:110.54
Chloroform ug/L ND 1.0 12/29/15 06:110.14
Chloromethane ug/L ND 1.0 12/29/15 06:110.11
cis-1,2-Dichloroethene ug/L ND 1.0 12/29/15 06:110.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/29/15 06:110.13
Dibromochloromethane ug/L ND 1.0 12/29/15 06:110.21
Dibromomethane ug/L ND 1.0 12/29/15 06:110.21
Ethylbenzene ug/L ND 1.0 12/29/15 06:110.30
Iodomethane ug/L ND 5.0 12/29/15 06:110.32
m&p-Xylene ug/L ND 2.0 12/29/15 06:110.66
Methylene Chloride ug/L ND 1.0 12/29/15 06:110.97
o-Xylene ug/L ND 1.0 12/29/15 06:110.23
Styrene ug/L ND 1.0 12/29/15 06:110.26
Tetrachloroethene ug/L ND 1.0 12/29/15 06:110.46
Toluene ug/L ND 1.0 12/29/15 06:110.26
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280027
Clay Co MW-5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1638140
Associated Lab Samples:92280027001
Matrix: Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 1.0 12/29/15 06:110.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/29/15 06:110.26
trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/29/15 06:111.0
Trichloroethene ug/L ND 1.0 12/29/15 06:110.47
Trichlorofluoromethane ug/L ND 1.0 12/29/15 06:110.20
Vinyl acetate ug/L ND 2.0 12/29/15 06:110.35
Vinyl chloride ug/L ND 1.0 12/29/15 06:110.62
Xylene (Total)ug/L ND 2.0 12/29/15 06:110.66
1,2-Dichloroethane-d4 (S)%91 70-130 12/29/15 06:11
4-Bromofluorobenzene (S)%102 70-130 12/29/15 06:11
Toluene-d8 (S)%109 70-130 12/29/15 06:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1638141LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.650 101 80-125
1,1,1-Trichloroethane ug/L 48.050 96 71-129
1,1,2,2-Tetrachloroethane ug/L 50.650 101 79-124
1,1,2-Trichloroethane ug/L 50.950 102 85-125
1,1-Dichloroethane ug/L 45.250 90 73-126
1,1-Dichloroethene ug/L 43.650 87 66-135
1,2,3-Trichloropropane ug/L 51.250 102 75-130
1,2-Dibromo-3-chloropropane ug/L 47.850 96 71-133
1,2-Dibromoethane (EDB)ug/L 53.450 107 83-124
1,2-Dichlorobenzene ug/L 49.150 98 80-133
1,2-Dichloroethane ug/L 45.650 91 67-128
1,2-Dichloropropane ug/L 46.850 94 75-132
1,4-Dichlorobenzene ug/L 49.250 98 78-130
2-Butanone (MEK)ug/L 113100 113 61-144
2-Hexanone ug/L 108100 108 68-143
4-Methyl-2-pentanone (MIBK)ug/L 107100 107 72-135
Acetone ug/L 105100 105 48-146
Acrylonitrile ug/L 255250 102 40-160
Benzene ug/L 49.050 98 80-125
Bromochloromethane ug/L 53.750 107 71-125
Bromodichloromethane ug/L 48.150 96 78-124
Bromoform ug/L 43.750 87 71-128
Bromomethane ug/L 40.450 81 40-160
Carbon disulfide ug/L 41.050 82 50-160
Carbon tetrachloride ug/L 49.150 98 69-131
Chlorobenzene ug/L 49.950 100 81-122
Chloroethane ug/L 33.950 68 39-148
Chloroform ug/L 47.650 95 73-127
Chloromethane ug/L 53.750 107 44-146
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280027
Clay Co MW-5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1638141LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 44.950 90 74-124
cis-1,3-Dichloropropene ug/L 50.850 102 72-132
Dibromochloromethane ug/L 52.850 106 78-125
Dibromomethane ug/L 52.250 104 82-120
Ethylbenzene ug/L 46.550 93 79-121
Iodomethane ug/L 85.5100 86 39-154
m&p-Xylene ug/L 91.9100 92 81-124
Methylene Chloride ug/L 57.250 114 64-133
o-Xylene ug/L 44.950 90 79-131
Styrene ug/L 48.050 96 84-126
Tetrachloroethene ug/L 49.350 99 78-122
Toluene ug/L 45.050 90 80-121
trans-1,2-Dichloroethene ug/L 47.850 96 71-127
trans-1,3-Dichloropropene ug/L 45.450 91 69-141
trans-1,4-Dichloro-2-butene ug/L 54.350 109 40-160
Trichloroethene ug/L 52.550 105 78-122
Trichlorofluoromethane ug/L 43.350 87 53-137
Vinyl acetate ug/L 99.6100 100 40-160
Vinyl chloride ug/L 46.150 92 58-137
Xylene (Total)ug/L 137150 91 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%94 70-130
REPORT OF LABORATORY ANALYSIS
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92280027
Clay Co MW-5
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92280027
Clay Co MW-5
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92280027001 MPRP/20312 ICP/18330MW-5 EPA 3010A EPA 6010
92280027001 MERP/8799 MERC/8455MW-5 EPA 7470 EPA 7470
92280027001 MSV/34968MW-5 EPA 8260
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Page 15 of 16
Page 16 of 16
#=CL#
January 12, 2016
LIMS USE: FR - MARK TEAGUE
LIMS OBJECT ID: 92280025
92280025
Project:
Pace Project No.:
RE:
Mr. Mark Teague
Environmental, Inc.
PO Box 954
Cullowhee, NC 28723
Clay Co MW-6
Dear Mr. Teague:
Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
A revised laboratory report is being submitted on January 12, 2016, to report MDLs, per client
request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
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Page 1 of 16
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92280025
Clay Co MW-6
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92280025
Clay Co MW-6
Lab ID Sample ID Matrix Date Collected Date Received
92280025001 MW-6 Water 12/15/15 12:20 12/16/15 11:33
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92280025
Clay Co MW-6
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92280025001 MW-6 EPA 6010 15 PASI-ACDF, JMW
EPA 7470 1 PASI-ASH1
EPA 8260 52 PASI-CGAW
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Asheville, NC 28804
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Page 4 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92280025
Clay Co MW-6
Sample: MW-6 Lab ID: 92280025001 Collected: 12/15/15 12:20 Received: 12/16/15 11:33 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/19/15 05:41 7440-36-012/17/15 19:005.0 3.8 1
Arsenic ND ug/L 12/19/15 05:41 7440-38-212/17/15 19:0010.0 2.5 1
Barium 222 ug/L 12/19/15 05:41 7440-39-312/17/15 19:005.0 2.5 1
Beryllium ND ug/L 12/19/15 05:41 7440-41-712/17/15 19:001.0 0.50 1
Cadmium ND ug/L 12/19/15 05:41 7440-43-912/17/15 19:001.0 0.50 1
Chromium ND ug/L 12/19/15 05:41 7440-47-312/17/15 19:005.0 2.5 1
Cobalt 13.4 ug/L 12/19/15 05:41 7440-48-412/17/15 19:005.0 2.5 1
Copper ND ug/L 12/19/15 05:41 7440-50-812/17/15 19:005.0 2.5 1
Lead ND ug/L 12/19/15 05:41 7439-92-112/17/15 19:005.0 2.5 1
Nickel 7.3 ug/L 12/19/15 05:41 7440-02-012/17/15 19:005.0 2.5 1
Selenium ND ug/L 12/19/15 05:41 7782-49-212/17/15 19:0010.0 5.0 1
Silver ND ug/L 12/19/15 05:41 7440-22-412/17/15 19:005.0 2.5 1
Thallium ND ug/L 12/22/15 17:44 7440-28-012/17/15 19:005.4 5.0 1
Vanadium ND ug/L 12/19/15 05:41 7440-62-212/17/15 19:005.0 2.5 1
Zinc 11.4 ug/L 12/19/15 05:41 7440-66-612/17/15 19:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/21/15 12:16 7439-97-612/19/15 18:300.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/29/15 12:53 67-64-125.0 10.0 1
Acrylonitrile ND ug/L 12/29/15 12:53 107-13-110.0 1.9 1
Benzene ND ug/L 12/29/15 12:53 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/29/15 12:53 74-97-51.0 0.17 1
Bromodichloromethane ND ug/L 12/29/15 12:53 75-27-41.0 0.18 1
Bromoform ND ug/L 12/29/15 12:53 75-25-21.0 0.26 1
Bromomethane ND ug/L 12/29/15 12:53 74-83-92.0 0.29 1
2-Butanone (MEK)ND ug/L 12/29/15 12:53 78-93-35.0 0.96 1
Carbon disulfide ND ug/L 12/29/15 12:53 75-15-02.0 1.2 1
Carbon tetrachloride ND ug/L 12/29/15 12:53 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/29/15 12:53 108-90-71.0 0.23 1
Chloroethane ND ug/L 12/29/15 12:53 75-00-31.0 0.54 1
Chloroform ND ug/L 12/29/15 12:53 67-66-31.0 0.14 1
Chloromethane ND ug/L 12/29/15 12:53 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/29/15 12:53 96-12-82.0 2.0 1
Dibromochloromethane ND ug/L 12/29/15 12:53 124-48-11.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/29/15 12:53 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/29/15 12:53 74-95-31.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/29/15 12:53 95-50-11.0 0.30 1
1,4-Dichlorobenzene 0.64J ug/L 12/29/15 12:53 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/29/15 12:53 110-57-61.0 1.0 1
1,1-Dichloroethane ND ug/L 12/29/15 12:53 75-34-31.0 0.32 1
1,2-Dichloroethane ND ug/L 12/29/15 12:53 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/29/15 12:53 75-35-41.0 0.56 1
cis-1,2-Dichloroethene 3.4 ug/L 12/29/15 12:53 156-59-21.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/29/15 12:53 156-60-51.0 0.49 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:02 AM
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
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Page 5 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92280025
Clay Co MW-6
Sample: MW-6 Lab ID: 92280025001 Collected: 12/15/15 12:20 Received: 12/16/15 11:33 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/29/15 12:53 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/29/15 12:53 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/29/15 12:53 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/29/15 12:53 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/29/15 12:53 591-78-65.0 0.46 1
Iodomethane ND ug/L 12/29/15 12:53 74-88-45.0 0.32 1
Methylene Chloride ND ug/L 12/29/15 12:53 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/29/15 12:53 108-10-15.0 0.33 1
Styrene ND ug/L 12/29/15 12:53 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/29/15 12:53 630-20-61.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/29/15 12:53 79-34-51.0 0.40 1
Tetrachloroethene ND ug/L 12/29/15 12:53 127-18-41.0 0.46 1
Toluene ND ug/L 12/29/15 12:53 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/29/15 12:53 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/29/15 12:53 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/29/15 12:53 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/29/15 12:53 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/29/15 12:53 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/29/15 12:53 108-05-42.0 0.35 1
Vinyl chloride ND ug/L 12/29/15 12:53 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/29/15 12:53 1330-20-72.0 0.66 1
m&p-Xylene ND ug/L 12/29/15 12:53 179601-23-12.0 0.66 1
o-Xylene 0.26J ug/L 12/29/15 12:53 95-47-61.0 0.23 1
Surrogates
4-Bromofluorobenzene (S)108 %12/29/15 12:53 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %12/29/15 12:53 17060-07-070-130 1
Toluene-d8 (S)121 %12/29/15 12:53 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:02 AM
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 6 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280025
Clay Co MW-6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8799
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92280025001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1632840
Associated Lab Samples:92280025001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/21/15 11:410.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1632841LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.12.5 84 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1632842MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279477001
1632844
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 92 75-12575 20 252.5ND 2.4 1.9
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:02 AM
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 7 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280025
Clay Co MW-6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20312
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92280025001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1631789
Associated Lab Samples:92280025001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 12/19/15 05:133.8
Arsenic ug/L ND 10.0 12/19/15 05:132.5
Barium ug/L ND 5.0 12/19/15 05:132.5
Beryllium ug/L ND 1.0 12/19/15 05:130.50
Cadmium ug/L ND 1.0 12/19/15 05:130.50
Chromium ug/L ND 5.0 12/19/15 05:132.5
Cobalt ug/L ND 5.0 12/19/15 05:132.5
Copper ug/L ND 5.0 12/19/15 05:132.5
Lead ug/L ND 5.0 12/19/15 05:132.5
Nickel ug/L ND 5.0 12/19/15 05:132.5
Selenium ug/L ND 10.0 12/19/15 05:135.0
Silver ug/L ND 5.0 12/19/15 05:132.5
Thallium ug/L ND 5.4 12/22/15 17:355.0
Vanadium ug/L ND 5.0 12/19/15 05:132.5
Zinc ug/L ND 10.0 12/19/15 05:135.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1631790LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 489500 98 80-120
Arsenic ug/L 526500 105 80-120
Barium ug/L 496500 99 80-120
Beryllium ug/L 502500 100 80-120
Cadmium ug/L 519500 104 80-120
Chromium ug/L 529500 106 80-120
Cobalt ug/L 530500 106 80-120
Copper ug/L 515500 103 80-120
Lead ug/L 524500 105 80-120
Nickel ug/L 524500 105 80-120
Selenium ug/L 520500 104 80-120
Silver ug/L 233250 93 80-120
Thallium ug/L 522500 104 80-120
Vanadium ug/L 518500 104 80-120
Zinc ug/L 554500 111 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:02 AM
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 8 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280025
Clay Co MW-6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1631791MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279775001
1631792
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 99 75-12597 2 25500ND495 483
Arsenic ug/L 500 107 75-125104 3 25500ND537 519
Barium ug/L 500 101 75-12598 3 25500108614 597
Beryllium ug/L 500 103 75-125100 3 25500ND515 499
Cadmium ug/L 500 105 75-125102 3 25500ND526 510
Chromium ug/L 500 107 75-125105 3 25500ND538 524
Cobalt ug/L 500 107 75-125104 3 2550010.9 546 528
Copper ug/L 500 105 75-125101 3 25500ND524 508
Lead ug/L 500 105 75-125102 3 25500ND526 510
Nickel ug/L 500 105 75-125102 3 255006.7 534 517
Selenium ug/L 500 104 75-125101 2 25500ND520 508
Silver ug/L 250 95 75-12592 4 25250ND238 230
Thallium ug/L 500 98 75-12597 1 25500ND488 483
Vanadium ug/L 500 106 75-125103 3 255002.9J 534 517
Zinc ug/L 500 112 75-125109 2 2550020.2 581 567
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:02 AM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 9 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280025
Clay Co MW-6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34968
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92280025001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1638140
Associated Lab Samples:92280025001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/29/15 06:110.33
1,1,1-Trichloroethane ug/L ND 1.0 12/29/15 06:110.48
1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/29/15 06:110.40
1,1,2-Trichloroethane ug/L ND 1.0 12/29/15 06:110.29
1,1-Dichloroethane ug/L ND 1.0 12/29/15 06:110.32
1,1-Dichloroethene ug/L ND 1.0 12/29/15 06:110.56
1,2,3-Trichloropropane ug/L ND 1.0 12/29/15 06:110.41
1,2-Dibromo-3-chloropropane ug/L ND 2.0 12/29/15 06:112.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/29/15 06:110.27
1,2-Dichlorobenzene ug/L ND 1.0 12/29/15 06:110.30
1,2-Dichloroethane ug/L ND 1.0 12/29/15 06:110.24
1,2-Dichloropropane ug/L ND 1.0 12/29/15 06:110.27
1,4-Dichlorobenzene ug/L ND 1.0 12/29/15 06:110.33
2-Butanone (MEK)ug/L ND 5.0 12/29/15 06:110.96
2-Hexanone ug/L ND 5.0 12/29/15 06:110.46
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/29/15 06:110.33
Acetone ug/L ND 25.0 12/29/15 06:1110.0
Acrylonitrile ug/L ND 10.0 12/29/15 06:111.9
Benzene ug/L ND 1.0 12/29/15 06:110.25
Bromochloromethane ug/L ND 1.0 12/29/15 06:110.17
Bromodichloromethane ug/L ND 1.0 12/29/15 06:110.18
Bromoform ug/L ND 1.0 12/29/15 06:110.26
Bromomethane ug/L ND 2.0 12/29/15 06:110.29
Carbon disulfide ug/L ND 2.0 12/29/15 06:111.2
Carbon tetrachloride ug/L ND 1.0 12/29/15 06:110.25
Chlorobenzene ug/L ND 1.0 12/29/15 06:110.23
Chloroethane ug/L ND 1.0 12/29/15 06:110.54
Chloroform ug/L ND 1.0 12/29/15 06:110.14
Chloromethane ug/L ND 1.0 12/29/15 06:110.11
cis-1,2-Dichloroethene ug/L ND 1.0 12/29/15 06:110.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/29/15 06:110.13
Dibromochloromethane ug/L ND 1.0 12/29/15 06:110.21
Dibromomethane ug/L ND 1.0 12/29/15 06:110.21
Ethylbenzene ug/L ND 1.0 12/29/15 06:110.30
Iodomethane ug/L ND 5.0 12/29/15 06:110.32
m&p-Xylene ug/L ND 2.0 12/29/15 06:110.66
Methylene Chloride ug/L ND 1.0 12/29/15 06:110.97
o-Xylene ug/L ND 1.0 12/29/15 06:110.23
Styrene ug/L ND 1.0 12/29/15 06:110.26
Tetrachloroethene ug/L ND 1.0 12/29/15 06:110.46
Toluene ug/L ND 1.0 12/29/15 06:110.26
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:02 AM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 10 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280025
Clay Co MW-6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1638140
Associated Lab Samples:92280025001
Matrix: Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 1.0 12/29/15 06:110.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/29/15 06:110.26
trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/29/15 06:111.0
Trichloroethene ug/L ND 1.0 12/29/15 06:110.47
Trichlorofluoromethane ug/L ND 1.0 12/29/15 06:110.20
Vinyl acetate ug/L ND 2.0 12/29/15 06:110.35
Vinyl chloride ug/L ND 1.0 12/29/15 06:110.62
Xylene (Total)ug/L ND 2.0 12/29/15 06:110.66
1,2-Dichloroethane-d4 (S)%91 70-130 12/29/15 06:11
4-Bromofluorobenzene (S)%102 70-130 12/29/15 06:11
Toluene-d8 (S)%109 70-130 12/29/15 06:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1638141LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.650 101 80-125
1,1,1-Trichloroethane ug/L 48.050 96 71-129
1,1,2,2-Tetrachloroethane ug/L 50.650 101 79-124
1,1,2-Trichloroethane ug/L 50.950 102 85-125
1,1-Dichloroethane ug/L 45.250 90 73-126
1,1-Dichloroethene ug/L 43.650 87 66-135
1,2,3-Trichloropropane ug/L 51.250 102 75-130
1,2-Dibromo-3-chloropropane ug/L 47.850 96 71-133
1,2-Dibromoethane (EDB)ug/L 53.450 107 83-124
1,2-Dichlorobenzene ug/L 49.150 98 80-133
1,2-Dichloroethane ug/L 45.650 91 67-128
1,2-Dichloropropane ug/L 46.850 94 75-132
1,4-Dichlorobenzene ug/L 49.250 98 78-130
2-Butanone (MEK)ug/L 113100 113 61-144
2-Hexanone ug/L 108100 108 68-143
4-Methyl-2-pentanone (MIBK)ug/L 107100 107 72-135
Acetone ug/L 105100 105 48-146
Acrylonitrile ug/L 255250 102 40-160
Benzene ug/L 49.050 98 80-125
Bromochloromethane ug/L 53.750 107 71-125
Bromodichloromethane ug/L 48.150 96 78-124
Bromoform ug/L 43.750 87 71-128
Bromomethane ug/L 40.450 81 40-160
Carbon disulfide ug/L 41.050 82 50-160
Carbon tetrachloride ug/L 49.150 98 69-131
Chlorobenzene ug/L 49.950 100 81-122
Chloroethane ug/L 33.950 68 39-148
Chloroform ug/L 47.650 95 73-127
Chloromethane ug/L 53.750 107 44-146
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:02 AM
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 11 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280025
Clay Co MW-6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1638141LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 44.950 90 74-124
cis-1,3-Dichloropropene ug/L 50.850 102 72-132
Dibromochloromethane ug/L 52.850 106 78-125
Dibromomethane ug/L 52.250 104 82-120
Ethylbenzene ug/L 46.550 93 79-121
Iodomethane ug/L 85.5100 86 39-154
m&p-Xylene ug/L 91.9100 92 81-124
Methylene Chloride ug/L 57.250 114 64-133
o-Xylene ug/L 44.950 90 79-131
Styrene ug/L 48.050 96 84-126
Tetrachloroethene ug/L 49.350 99 78-122
Toluene ug/L 45.050 90 80-121
trans-1,2-Dichloroethene ug/L 47.850 96 71-127
trans-1,3-Dichloropropene ug/L 45.450 91 69-141
trans-1,4-Dichloro-2-butene ug/L 54.350 109 40-160
Trichloroethene ug/L 52.550 105 78-122
Trichlorofluoromethane ug/L 43.350 87 53-137
Vinyl acetate ug/L 99.6100 100 40-160
Vinyl chloride ug/L 46.150 92 58-137
Xylene (Total)ug/L 137150 91 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%94 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:02 AM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 12 of 16
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92280025
Clay Co MW-6
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
REPORT OF LABORATORY ANALYSIS
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92280025
Clay Co MW-6
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92280025001 MPRP/20312 ICP/18330MW-6 EPA 3010A EPA 6010
92280025001 MERP/8799 MERC/8455MW-6 EPA 7470 EPA 7470
92280025001 MSV/34968MW-6 EPA 8260
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:02 AM
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Page 15 of 16
Page 16 of 16
#=CL#
January 12, 2016
LIMS USE: FR - MARK TEAGUE
LIMS OBJECT ID: 92280050
92280050
Project:
Pace Project No.:
RE:
Mr. Mark Teague
Environmental, Inc.
PO Box 954
Cullowhee, NC 28723
CLAY CO. UPSTREAM
Dear Mr. Teague:
Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
A revised laboratory report is being submitted on January 12, 2016, to report MDLs, per client
request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 1 of 16
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92280050
CLAY CO. UPSTREAM
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92280050
CLAY CO. UPSTREAM
Lab ID Sample ID Matrix Date Collected Date Received
92280050001 UPSTREAM Water 12/15/15 11:02 12/16/15 11:33
REPORT OF LABORATORY ANALYSIS
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92280050
CLAY CO. UPSTREAM
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92280050001 UPSTREAM EPA 6010 15 PASI-ACDF, JMW
EPA 7470 1 PASI-ASH1
EPA 8260 52 PASI-CGAW
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92280050
CLAY CO. UPSTREAM
Sample: UPSTREAM Lab ID: 92280050001 Collected: 12/15/15 11:02 Received: 12/16/15 11:33 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/19/15 06:12 7440-36-012/17/15 19:005.0 3.8 1
Arsenic ND ug/L 12/19/15 06:12 7440-38-212/17/15 19:0010.0 2.5 1
Barium 27.6 ug/L 12/19/15 06:12 7440-39-312/17/15 19:005.0 2.5 1
Beryllium ND ug/L 12/19/15 06:12 7440-41-712/17/15 19:001.0 0.50 1
Cadmium ND ug/L 12/19/15 06:12 7440-43-912/17/15 19:001.0 0.50 1
Chromium ND ug/L 12/19/15 06:12 7440-47-312/17/15 19:005.0 2.5 1
Cobalt ND ug/L 12/19/15 06:12 7440-48-412/17/15 19:005.0 2.5 1
Copper ND ug/L 12/19/15 06:12 7440-50-812/17/15 19:005.0 2.5 1
Lead ND ug/L 12/19/15 06:12 7439-92-112/17/15 19:005.0 2.5 1
Nickel ND ug/L 12/19/15 06:12 7440-02-012/17/15 19:005.0 2.5 1
Selenium ND ug/L 12/19/15 06:12 7782-49-212/17/15 19:0010.0 5.0 1
Silver ND ug/L 12/19/15 06:12 7440-22-412/17/15 19:005.0 2.5 1
Thallium ND ug/L 12/22/15 18:15 7440-28-012/17/15 19:005.4 5.0 1
Vanadium ND ug/L 12/19/15 06:12 7440-62-212/17/15 19:005.0 2.5 1
Zinc ND ug/L 12/19/15 06:12 7440-66-612/17/15 19:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/21/15 12:32 7439-97-612/19/15 18:300.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/29/15 14:52 67-64-125.0 10.0 1
Acrylonitrile ND ug/L 12/29/15 14:52 107-13-110.0 1.9 1
Benzene ND ug/L 12/29/15 14:52 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/29/15 14:52 74-97-51.0 0.17 1
Bromodichloromethane ND ug/L 12/29/15 14:52 75-27-41.0 0.18 1
Bromoform ND ug/L 12/29/15 14:52 75-25-21.0 0.26 1
Bromomethane ND ug/L 12/29/15 14:52 74-83-92.0 0.29 1
2-Butanone (MEK)ND ug/L 12/29/15 14:52 78-93-35.0 0.96 1
Carbon disulfide ND ug/L 12/29/15 14:52 75-15-02.0 1.2 1
Carbon tetrachloride ND ug/L 12/29/15 14:52 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/29/15 14:52 108-90-71.0 0.23 1
Chloroethane ND ug/L 12/29/15 14:52 75-00-31.0 0.54 1
Chloroform ND ug/L 12/29/15 14:52 67-66-31.0 0.14 1
Chloromethane ND ug/L 12/29/15 14:52 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/29/15 14:52 96-12-82.0 2.0 1
Dibromochloromethane ND ug/L 12/29/15 14:52 124-48-11.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/29/15 14:52 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/29/15 14:52 74-95-31.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/29/15 14:52 95-50-11.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/29/15 14:52 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/29/15 14:52 110-57-61.0 1.0 1
1,1-Dichloroethane ND ug/L 12/29/15 14:52 75-34-31.0 0.32 1
1,2-Dichloroethane ND ug/L 12/29/15 14:52 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/29/15 14:52 75-35-41.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/29/15 14:52 156-59-21.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/29/15 14:52 156-60-51.0 0.49 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92280050
CLAY CO. UPSTREAM
Sample: UPSTREAM Lab ID: 92280050001 Collected: 12/15/15 11:02 Received: 12/16/15 11:33 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/29/15 14:52 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/29/15 14:52 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/29/15 14:52 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/29/15 14:52 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/29/15 14:52 591-78-65.0 0.46 1
Iodomethane ND ug/L 12/29/15 14:52 74-88-45.0 0.32 1
Methylene Chloride 1.1 ug/L 12/29/15 14:52 75-09-2 C91.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/29/15 14:52 108-10-15.0 0.33 1
Styrene ND ug/L 12/29/15 14:52 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/29/15 14:52 630-20-61.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/29/15 14:52 79-34-51.0 0.40 1
Tetrachloroethene ND ug/L 12/29/15 14:52 127-18-41.0 0.46 1
Toluene ND ug/L 12/29/15 14:52 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/29/15 14:52 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/29/15 14:52 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/29/15 14:52 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/29/15 14:52 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/29/15 14:52 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/29/15 14:52 108-05-42.0 0.35 1
Vinyl chloride ND ug/L 12/29/15 14:52 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/29/15 14:52 1330-20-72.0 0.66 1
m&p-Xylene ND ug/L 12/29/15 14:52 179601-23-12.0 0.66 1
o-Xylene ND ug/L 12/29/15 14:52 95-47-61.0 0.23 1
Surrogates
4-Bromofluorobenzene (S)105 %12/29/15 14:52 460-00-470-130 1
1,2-Dichloroethane-d4 (S)93 %12/29/15 14:52 17060-07-070-130 1
Toluene-d8 (S)109 %12/29/15 14:52 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280050
CLAY CO. UPSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8799
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92280050001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1632840
Associated Lab Samples:92280050001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/21/15 11:410.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1632841LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.12.5 84 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1632842MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279477001
1632844
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 92 75-12575 20 252.5ND 2.4 1.9
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280050
CLAY CO. UPSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20312
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92280050001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1631789
Associated Lab Samples:92280050001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 12/19/15 05:133.8
Arsenic ug/L ND 10.0 12/19/15 05:132.5
Barium ug/L ND 5.0 12/19/15 05:132.5
Beryllium ug/L ND 1.0 12/19/15 05:130.50
Cadmium ug/L ND 1.0 12/19/15 05:130.50
Chromium ug/L ND 5.0 12/19/15 05:132.5
Cobalt ug/L ND 5.0 12/19/15 05:132.5
Copper ug/L ND 5.0 12/19/15 05:132.5
Lead ug/L ND 5.0 12/19/15 05:132.5
Nickel ug/L ND 5.0 12/19/15 05:132.5
Selenium ug/L ND 10.0 12/19/15 05:135.0
Silver ug/L ND 5.0 12/19/15 05:132.5
Thallium ug/L ND 5.4 12/22/15 17:355.0
Vanadium ug/L ND 5.0 12/19/15 05:132.5
Zinc ug/L ND 10.0 12/19/15 05:135.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1631790LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 489500 98 80-120
Arsenic ug/L 526500 105 80-120
Barium ug/L 496500 99 80-120
Beryllium ug/L 502500 100 80-120
Cadmium ug/L 519500 104 80-120
Chromium ug/L 529500 106 80-120
Cobalt ug/L 530500 106 80-120
Copper ug/L 515500 103 80-120
Lead ug/L 524500 105 80-120
Nickel ug/L 524500 105 80-120
Selenium ug/L 520500 104 80-120
Silver ug/L 233250 93 80-120
Thallium ug/L 522500 104 80-120
Vanadium ug/L 518500 104 80-120
Zinc ug/L 554500 111 80-120
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280050
CLAY CO. UPSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1631791MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279775001
1631792
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 99 75-12597 2 25500ND495 483
Arsenic ug/L 500 107 75-125104 3 25500ND537 519
Barium ug/L 500 101 75-12598 3 25500108614 597
Beryllium ug/L 500 103 75-125100 3 25500ND515 499
Cadmium ug/L 500 105 75-125102 3 25500ND526 510
Chromium ug/L 500 107 75-125105 3 25500ND538 524
Cobalt ug/L 500 107 75-125104 3 2550010.9 546 528
Copper ug/L 500 105 75-125101 3 25500ND524 508
Lead ug/L 500 105 75-125102 3 25500ND526 510
Nickel ug/L 500 105 75-125102 3 255006.7 534 517
Selenium ug/L 500 104 75-125101 2 25500ND520 508
Silver ug/L 250 95 75-12592 4 25250ND238 230
Thallium ug/L 500 98 75-12597 1 25500ND488 483
Vanadium ug/L 500 106 75-125103 3 255002.9J 534 517
Zinc ug/L 500 112 75-125109 2 2550020.2 581 567
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280050
CLAY CO. UPSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34968
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92280050001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1638140
Associated Lab Samples:92280050001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/29/15 06:110.33
1,1,1-Trichloroethane ug/L ND 1.0 12/29/15 06:110.48
1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/29/15 06:110.40
1,1,2-Trichloroethane ug/L ND 1.0 12/29/15 06:110.29
1,1-Dichloroethane ug/L ND 1.0 12/29/15 06:110.32
1,1-Dichloroethene ug/L ND 1.0 12/29/15 06:110.56
1,2,3-Trichloropropane ug/L ND 1.0 12/29/15 06:110.41
1,2-Dibromo-3-chloropropane ug/L ND 2.0 12/29/15 06:112.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/29/15 06:110.27
1,2-Dichlorobenzene ug/L ND 1.0 12/29/15 06:110.30
1,2-Dichloroethane ug/L ND 1.0 12/29/15 06:110.24
1,2-Dichloropropane ug/L ND 1.0 12/29/15 06:110.27
1,4-Dichlorobenzene ug/L ND 1.0 12/29/15 06:110.33
2-Butanone (MEK)ug/L ND 5.0 12/29/15 06:110.96
2-Hexanone ug/L ND 5.0 12/29/15 06:110.46
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/29/15 06:110.33
Acetone ug/L ND 25.0 12/29/15 06:1110.0
Acrylonitrile ug/L ND 10.0 12/29/15 06:111.9
Benzene ug/L ND 1.0 12/29/15 06:110.25
Bromochloromethane ug/L ND 1.0 12/29/15 06:110.17
Bromodichloromethane ug/L ND 1.0 12/29/15 06:110.18
Bromoform ug/L ND 1.0 12/29/15 06:110.26
Bromomethane ug/L ND 2.0 12/29/15 06:110.29
Carbon disulfide ug/L ND 2.0 12/29/15 06:111.2
Carbon tetrachloride ug/L ND 1.0 12/29/15 06:110.25
Chlorobenzene ug/L ND 1.0 12/29/15 06:110.23
Chloroethane ug/L ND 1.0 12/29/15 06:110.54
Chloroform ug/L ND 1.0 12/29/15 06:110.14
Chloromethane ug/L ND 1.0 12/29/15 06:110.11
cis-1,2-Dichloroethene ug/L ND 1.0 12/29/15 06:110.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/29/15 06:110.13
Dibromochloromethane ug/L ND 1.0 12/29/15 06:110.21
Dibromomethane ug/L ND 1.0 12/29/15 06:110.21
Ethylbenzene ug/L ND 1.0 12/29/15 06:110.30
Iodomethane ug/L ND 5.0 12/29/15 06:110.32
m&p-Xylene ug/L ND 2.0 12/29/15 06:110.66
Methylene Chloride ug/L ND 1.0 12/29/15 06:110.97
o-Xylene ug/L ND 1.0 12/29/15 06:110.23
Styrene ug/L ND 1.0 12/29/15 06:110.26
Tetrachloroethene ug/L ND 1.0 12/29/15 06:110.46
Toluene ug/L ND 1.0 12/29/15 06:110.26
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280050
CLAY CO. UPSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1638140
Associated Lab Samples:92280050001
Matrix: Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 1.0 12/29/15 06:110.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/29/15 06:110.26
trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/29/15 06:111.0
Trichloroethene ug/L ND 1.0 12/29/15 06:110.47
Trichlorofluoromethane ug/L ND 1.0 12/29/15 06:110.20
Vinyl acetate ug/L ND 2.0 12/29/15 06:110.35
Vinyl chloride ug/L ND 1.0 12/29/15 06:110.62
Xylene (Total)ug/L ND 2.0 12/29/15 06:110.66
1,2-Dichloroethane-d4 (S)%91 70-130 12/29/15 06:11
4-Bromofluorobenzene (S)%102 70-130 12/29/15 06:11
Toluene-d8 (S)%109 70-130 12/29/15 06:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1638141LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.650 101 80-125
1,1,1-Trichloroethane ug/L 48.050 96 71-129
1,1,2,2-Tetrachloroethane ug/L 50.650 101 79-124
1,1,2-Trichloroethane ug/L 50.950 102 85-125
1,1-Dichloroethane ug/L 45.250 90 73-126
1,1-Dichloroethene ug/L 43.650 87 66-135
1,2,3-Trichloropropane ug/L 51.250 102 75-130
1,2-Dibromo-3-chloropropane ug/L 47.850 96 71-133
1,2-Dibromoethane (EDB)ug/L 53.450 107 83-124
1,2-Dichlorobenzene ug/L 49.150 98 80-133
1,2-Dichloroethane ug/L 45.650 91 67-128
1,2-Dichloropropane ug/L 46.850 94 75-132
1,4-Dichlorobenzene ug/L 49.250 98 78-130
2-Butanone (MEK)ug/L 113100 113 61-144
2-Hexanone ug/L 108100 108 68-143
4-Methyl-2-pentanone (MIBK)ug/L 107100 107 72-135
Acetone ug/L 105100 105 48-146
Acrylonitrile ug/L 255250 102 40-160
Benzene ug/L 49.050 98 80-125
Bromochloromethane ug/L 53.750 107 71-125
Bromodichloromethane ug/L 48.150 96 78-124
Bromoform ug/L 43.750 87 71-128
Bromomethane ug/L 40.450 81 40-160
Carbon disulfide ug/L 41.050 82 50-160
Carbon tetrachloride ug/L 49.150 98 69-131
Chlorobenzene ug/L 49.950 100 81-122
Chloroethane ug/L 33.950 68 39-148
Chloroform ug/L 47.650 95 73-127
Chloromethane ug/L 53.750 107 44-146
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280050
CLAY CO. UPSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1638141LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 44.950 90 74-124
cis-1,3-Dichloropropene ug/L 50.850 102 72-132
Dibromochloromethane ug/L 52.850 106 78-125
Dibromomethane ug/L 52.250 104 82-120
Ethylbenzene ug/L 46.550 93 79-121
Iodomethane ug/L 85.5100 86 39-154
m&p-Xylene ug/L 91.9100 92 81-124
Methylene Chloride ug/L 57.250 114 64-133
o-Xylene ug/L 44.950 90 79-131
Styrene ug/L 48.050 96 84-126
Tetrachloroethene ug/L 49.350 99 78-122
Toluene ug/L 45.050 90 80-121
trans-1,2-Dichloroethene ug/L 47.850 96 71-127
trans-1,3-Dichloropropene ug/L 45.450 91 69-141
trans-1,4-Dichloro-2-butene ug/L 54.350 109 40-160
Trichloroethene ug/L 52.550 105 78-122
Trichlorofluoromethane ug/L 43.350 87 53-137
Vinyl acetate ug/L 99.6100 100 40-160
Vinyl chloride ug/L 46.150 92 58-137
Xylene (Total)ug/L 137150 91 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%94 70-130
REPORT OF LABORATORY ANALYSIS
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92280050
CLAY CO. UPSTREAM
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Common Laboratory Contaminant.C9
REPORT OF LABORATORY ANALYSIS
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92280050
CLAY CO. UPSTREAM
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92280050001 MPRP/20312 ICP/18330UPSTREAMEPA 3010A EPA 6010
92280050001 MERP/8799 MERC/8455UPSTREAMEPA 7470 EPA 7470
92280050001 MSV/34968UPSTREAMEPA 8260
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Page 15 of 16
Page 16 of 16
#=CL#
January 12, 2016
LIMS USE: FR - MARK TEAGUE
LIMS OBJECT ID: 92280049
92280049
Project:
Pace Project No.:
RE:
Mr. Mark Teague
Environmental, Inc.
PO Box 954
Cullowhee, NC 28723
CLAY CO. DOWNSTREAM
Dear Mr. Teague:
Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
A revised laboratory report is being submitted on January 12, 2016, to report MDLs, per client
request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
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#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92280049
CLAY CO. DOWNSTREAM
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92280049
CLAY CO. DOWNSTREAM
Lab ID Sample ID Matrix Date Collected Date Received
92280049001 DOWNSTREAM Water 12/15/15 12:40 12/16/15 11:33
REPORT OF LABORATORY ANALYSIS
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92280049
CLAY CO. DOWNSTREAM
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92280049001 DOWNSTREAM EPA 6010 15 PASI-ACDF, JMW
EPA 7470 1 PASI-ASH1
EPA 8260 52 PASI-CGAW
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92280049
CLAY CO. DOWNSTREAM
Sample: DOWNSTREAM Lab ID: 92280049001 Collected: 12/15/15 12:40 Received: 12/16/15 11:33 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/19/15 06:09 7440-36-012/17/15 19:005.0 3.8 1
Arsenic ND ug/L 12/19/15 06:09 7440-38-212/17/15 19:0010.0 2.5 1
Barium 8.8 ug/L 12/19/15 06:09 7440-39-312/17/15 19:005.0 2.5 1
Beryllium ND ug/L 12/19/15 06:09 7440-41-712/17/15 19:001.0 0.50 1
Cadmium ND ug/L 12/19/15 06:09 7440-43-912/17/15 19:001.0 0.50 1
Chromium ND ug/L 12/19/15 06:09 7440-47-312/17/15 19:005.0 2.5 1
Cobalt ND ug/L 12/19/15 06:09 7440-48-412/17/15 19:005.0 2.5 1
Copper ND ug/L 12/19/15 06:09 7440-50-812/17/15 19:005.0 2.5 1
Lead ND ug/L 12/19/15 06:09 7439-92-112/17/15 19:005.0 2.5 1
Nickel ND ug/L 12/19/15 06:09 7440-02-012/17/15 19:005.0 2.5 1
Selenium ND ug/L 12/19/15 06:09 7782-49-212/17/15 19:0010.0 5.0 1
Silver ND ug/L 12/19/15 06:09 7440-22-412/17/15 19:005.0 2.5 1
Thallium ND ug/L 12/22/15 18:12 7440-28-012/17/15 19:005.4 5.0 1
Vanadium ND ug/L 12/19/15 06:09 7440-62-212/17/15 19:005.0 2.5 1
Zinc ND ug/L 12/19/15 06:09 7440-66-612/17/15 19:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/21/15 12:30 7439-97-612/19/15 18:300.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/29/15 14:35 67-64-125.0 10.0 1
Acrylonitrile ND ug/L 12/29/15 14:35 107-13-110.0 1.9 1
Benzene ND ug/L 12/29/15 14:35 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/29/15 14:35 74-97-51.0 0.17 1
Bromodichloromethane ND ug/L 12/29/15 14:35 75-27-41.0 0.18 1
Bromoform ND ug/L 12/29/15 14:35 75-25-21.0 0.26 1
Bromomethane ND ug/L 12/29/15 14:35 74-83-92.0 0.29 1
2-Butanone (MEK)ND ug/L 12/29/15 14:35 78-93-35.0 0.96 1
Carbon disulfide ND ug/L 12/29/15 14:35 75-15-02.0 1.2 1
Carbon tetrachloride ND ug/L 12/29/15 14:35 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/29/15 14:35 108-90-71.0 0.23 1
Chloroethane ND ug/L 12/29/15 14:35 75-00-31.0 0.54 1
Chloroform ND ug/L 12/29/15 14:35 67-66-31.0 0.14 1
Chloromethane ND ug/L 12/29/15 14:35 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/29/15 14:35 96-12-82.0 2.0 1
Dibromochloromethane ND ug/L 12/29/15 14:35 124-48-11.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/29/15 14:35 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/29/15 14:35 74-95-31.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/29/15 14:35 95-50-11.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/29/15 14:35 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/29/15 14:35 110-57-61.0 1.0 1
1,1-Dichloroethane ND ug/L 12/29/15 14:35 75-34-31.0 0.32 1
1,2-Dichloroethane ND ug/L 12/29/15 14:35 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/29/15 14:35 75-35-41.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/29/15 14:35 156-59-21.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/29/15 14:35 156-60-51.0 0.49 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92280049
CLAY CO. DOWNSTREAM
Sample: DOWNSTREAM Lab ID: 92280049001 Collected: 12/15/15 12:40 Received: 12/16/15 11:33 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/29/15 14:35 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/29/15 14:35 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/29/15 14:35 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/29/15 14:35 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/29/15 14:35 591-78-65.0 0.46 1
Iodomethane ND ug/L 12/29/15 14:35 74-88-45.0 0.32 1
Methylene Chloride ND ug/L 12/29/15 14:35 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/29/15 14:35 108-10-15.0 0.33 1
Styrene ND ug/L 12/29/15 14:35 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/29/15 14:35 630-20-61.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/29/15 14:35 79-34-51.0 0.40 1
Tetrachloroethene ND ug/L 12/29/15 14:35 127-18-41.0 0.46 1
Toluene ND ug/L 12/29/15 14:35 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/29/15 14:35 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/29/15 14:35 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/29/15 14:35 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/29/15 14:35 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/29/15 14:35 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/29/15 14:35 108-05-42.0 0.35 1
Vinyl chloride ND ug/L 12/29/15 14:35 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/29/15 14:35 1330-20-72.0 0.66 1
m&p-Xylene ND ug/L 12/29/15 14:35 179601-23-12.0 0.66 1
o-Xylene ND ug/L 12/29/15 14:35 95-47-61.0 0.23 1
Surrogates
4-Bromofluorobenzene (S)102 %12/29/15 14:35 460-00-470-130 1
1,2-Dichloroethane-d4 (S)93 %12/29/15 14:35 17060-07-070-130 1
Toluene-d8 (S)116 %12/29/15 14:35 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280049
CLAY CO. DOWNSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8799
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92280049001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1632840
Associated Lab Samples:92280049001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/21/15 11:410.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1632841LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.12.5 84 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1632842MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279477001
1632844
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 92 75-12575 20 252.5ND 2.4 1.9
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280049
CLAY CO. DOWNSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20312
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92280049001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1631789
Associated Lab Samples:92280049001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 12/19/15 05:133.8
Arsenic ug/L ND 10.0 12/19/15 05:132.5
Barium ug/L ND 5.0 12/19/15 05:132.5
Beryllium ug/L ND 1.0 12/19/15 05:130.50
Cadmium ug/L ND 1.0 12/19/15 05:130.50
Chromium ug/L ND 5.0 12/19/15 05:132.5
Cobalt ug/L ND 5.0 12/19/15 05:132.5
Copper ug/L ND 5.0 12/19/15 05:132.5
Lead ug/L ND 5.0 12/19/15 05:132.5
Nickel ug/L ND 5.0 12/19/15 05:132.5
Selenium ug/L ND 10.0 12/19/15 05:135.0
Silver ug/L ND 5.0 12/19/15 05:132.5
Thallium ug/L ND 5.4 12/22/15 17:355.0
Vanadium ug/L ND 5.0 12/19/15 05:132.5
Zinc ug/L ND 10.0 12/19/15 05:135.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1631790LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 489500 98 80-120
Arsenic ug/L 526500 105 80-120
Barium ug/L 496500 99 80-120
Beryllium ug/L 502500 100 80-120
Cadmium ug/L 519500 104 80-120
Chromium ug/L 529500 106 80-120
Cobalt ug/L 530500 106 80-120
Copper ug/L 515500 103 80-120
Lead ug/L 524500 105 80-120
Nickel ug/L 524500 105 80-120
Selenium ug/L 520500 104 80-120
Silver ug/L 233250 93 80-120
Thallium ug/L 522500 104 80-120
Vanadium ug/L 518500 104 80-120
Zinc ug/L 554500 111 80-120
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280049
CLAY CO. DOWNSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1631791MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279775001
1631792
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 99 75-12597 2 25500ND495 483
Arsenic ug/L 500 107 75-125104 3 25500ND537 519
Barium ug/L 500 101 75-12598 3 25500108614 597
Beryllium ug/L 500 103 75-125100 3 25500ND515 499
Cadmium ug/L 500 105 75-125102 3 25500ND526 510
Chromium ug/L 500 107 75-125105 3 25500ND538 524
Cobalt ug/L 500 107 75-125104 3 2550010.9 546 528
Copper ug/L 500 105 75-125101 3 25500ND524 508
Lead ug/L 500 105 75-125102 3 25500ND526 510
Nickel ug/L 500 105 75-125102 3 255006.7 534 517
Selenium ug/L 500 104 75-125101 2 25500ND520 508
Silver ug/L 250 95 75-12592 4 25250ND238 230
Thallium ug/L 500 98 75-12597 1 25500ND488 483
Vanadium ug/L 500 106 75-125103 3 255002.9J 534 517
Zinc ug/L 500 112 75-125109 2 2550020.2 581 567
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280049
CLAY CO. DOWNSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34968
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92280049001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1638140
Associated Lab Samples:92280049001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/29/15 06:110.33
1,1,1-Trichloroethane ug/L ND 1.0 12/29/15 06:110.48
1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/29/15 06:110.40
1,1,2-Trichloroethane ug/L ND 1.0 12/29/15 06:110.29
1,1-Dichloroethane ug/L ND 1.0 12/29/15 06:110.32
1,1-Dichloroethene ug/L ND 1.0 12/29/15 06:110.56
1,2,3-Trichloropropane ug/L ND 1.0 12/29/15 06:110.41
1,2-Dibromo-3-chloropropane ug/L ND 2.0 12/29/15 06:112.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/29/15 06:110.27
1,2-Dichlorobenzene ug/L ND 1.0 12/29/15 06:110.30
1,2-Dichloroethane ug/L ND 1.0 12/29/15 06:110.24
1,2-Dichloropropane ug/L ND 1.0 12/29/15 06:110.27
1,4-Dichlorobenzene ug/L ND 1.0 12/29/15 06:110.33
2-Butanone (MEK)ug/L ND 5.0 12/29/15 06:110.96
2-Hexanone ug/L ND 5.0 12/29/15 06:110.46
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/29/15 06:110.33
Acetone ug/L ND 25.0 12/29/15 06:1110.0
Acrylonitrile ug/L ND 10.0 12/29/15 06:111.9
Benzene ug/L ND 1.0 12/29/15 06:110.25
Bromochloromethane ug/L ND 1.0 12/29/15 06:110.17
Bromodichloromethane ug/L ND 1.0 12/29/15 06:110.18
Bromoform ug/L ND 1.0 12/29/15 06:110.26
Bromomethane ug/L ND 2.0 12/29/15 06:110.29
Carbon disulfide ug/L ND 2.0 12/29/15 06:111.2
Carbon tetrachloride ug/L ND 1.0 12/29/15 06:110.25
Chlorobenzene ug/L ND 1.0 12/29/15 06:110.23
Chloroethane ug/L ND 1.0 12/29/15 06:110.54
Chloroform ug/L ND 1.0 12/29/15 06:110.14
Chloromethane ug/L ND 1.0 12/29/15 06:110.11
cis-1,2-Dichloroethene ug/L ND 1.0 12/29/15 06:110.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/29/15 06:110.13
Dibromochloromethane ug/L ND 1.0 12/29/15 06:110.21
Dibromomethane ug/L ND 1.0 12/29/15 06:110.21
Ethylbenzene ug/L ND 1.0 12/29/15 06:110.30
Iodomethane ug/L ND 5.0 12/29/15 06:110.32
m&p-Xylene ug/L ND 2.0 12/29/15 06:110.66
Methylene Chloride ug/L ND 1.0 12/29/15 06:110.97
o-Xylene ug/L ND 1.0 12/29/15 06:110.23
Styrene ug/L ND 1.0 12/29/15 06:110.26
Tetrachloroethene ug/L ND 1.0 12/29/15 06:110.46
Toluene ug/L ND 1.0 12/29/15 06:110.26
REPORT OF LABORATORY ANALYSIS
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Page 10 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280049
CLAY CO. DOWNSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1638140
Associated Lab Samples:92280049001
Matrix: Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 1.0 12/29/15 06:110.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/29/15 06:110.26
trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/29/15 06:111.0
Trichloroethene ug/L ND 1.0 12/29/15 06:110.47
Trichlorofluoromethane ug/L ND 1.0 12/29/15 06:110.20
Vinyl acetate ug/L ND 2.0 12/29/15 06:110.35
Vinyl chloride ug/L ND 1.0 12/29/15 06:110.62
Xylene (Total)ug/L ND 2.0 12/29/15 06:110.66
1,2-Dichloroethane-d4 (S)%91 70-130 12/29/15 06:11
4-Bromofluorobenzene (S)%102 70-130 12/29/15 06:11
Toluene-d8 (S)%109 70-130 12/29/15 06:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1638141LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.650 101 80-125
1,1,1-Trichloroethane ug/L 48.050 96 71-129
1,1,2,2-Tetrachloroethane ug/L 50.650 101 79-124
1,1,2-Trichloroethane ug/L 50.950 102 85-125
1,1-Dichloroethane ug/L 45.250 90 73-126
1,1-Dichloroethene ug/L 43.650 87 66-135
1,2,3-Trichloropropane ug/L 51.250 102 75-130
1,2-Dibromo-3-chloropropane ug/L 47.850 96 71-133
1,2-Dibromoethane (EDB)ug/L 53.450 107 83-124
1,2-Dichlorobenzene ug/L 49.150 98 80-133
1,2-Dichloroethane ug/L 45.650 91 67-128
1,2-Dichloropropane ug/L 46.850 94 75-132
1,4-Dichlorobenzene ug/L 49.250 98 78-130
2-Butanone (MEK)ug/L 113100 113 61-144
2-Hexanone ug/L 108100 108 68-143
4-Methyl-2-pentanone (MIBK)ug/L 107100 107 72-135
Acetone ug/L 105100 105 48-146
Acrylonitrile ug/L 255250 102 40-160
Benzene ug/L 49.050 98 80-125
Bromochloromethane ug/L 53.750 107 71-125
Bromodichloromethane ug/L 48.150 96 78-124
Bromoform ug/L 43.750 87 71-128
Bromomethane ug/L 40.450 81 40-160
Carbon disulfide ug/L 41.050 82 50-160
Carbon tetrachloride ug/L 49.150 98 69-131
Chlorobenzene ug/L 49.950 100 81-122
Chloroethane ug/L 33.950 68 39-148
Chloroform ug/L 47.650 95 73-127
Chloromethane ug/L 53.750 107 44-146
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280049
CLAY CO. DOWNSTREAM
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1638141LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 44.950 90 74-124
cis-1,3-Dichloropropene ug/L 50.850 102 72-132
Dibromochloromethane ug/L 52.850 106 78-125
Dibromomethane ug/L 52.250 104 82-120
Ethylbenzene ug/L 46.550 93 79-121
Iodomethane ug/L 85.5100 86 39-154
m&p-Xylene ug/L 91.9100 92 81-124
Methylene Chloride ug/L 57.250 114 64-133
o-Xylene ug/L 44.950 90 79-131
Styrene ug/L 48.050 96 84-126
Tetrachloroethene ug/L 49.350 99 78-122
Toluene ug/L 45.050 90 80-121
trans-1,2-Dichloroethene ug/L 47.850 96 71-127
trans-1,3-Dichloropropene ug/L 45.450 91 69-141
trans-1,4-Dichloro-2-butene ug/L 54.350 109 40-160
Trichloroethene ug/L 52.550 105 78-122
Trichlorofluoromethane ug/L 43.350 87 53-137
Vinyl acetate ug/L 99.6100 100 40-160
Vinyl chloride ug/L 46.150 92 58-137
Xylene (Total)ug/L 137150 91 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%94 70-130
REPORT OF LABORATORY ANALYSIS
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92280049
CLAY CO. DOWNSTREAM
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
REPORT OF LABORATORY ANALYSIS
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[phone]
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92280049
CLAY CO. DOWNSTREAM
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92280049001 MPRP/20312 ICP/18330DOWNSTREAMEPA 3010A EPA 6010
92280049001 MERP/8799 MERC/8455DOWNSTREAMEPA 7470 EPA 7470
92280049001 MSV/34968DOWNSTREAMEPA 8260
REPORT OF LABORATORY ANALYSIS
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Page 15 of 16
Page 16 of 16
#=CL#
January 12, 2016
LIMS USE: FR - MARK TEAGUE
LIMS OBJECT ID: 92280023
92280023
Project:
Pace Project No.:
RE:
Mr. Mark Teague
Environmental, Inc.
PO Box 954
Cullowhee, NC 28723
Clay Co. Equipment Blank
Dear Mr. Teague:
Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
A revised laboratory report is being submitted on January 12, 2016, to report MDLs, per client
request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 1 of 18
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92280023
Clay Co. Equipment Blank
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92280023
Clay Co. Equipment Blank
Lab ID Sample ID Matrix Date Collected Date Received
92280023001 EQUIPMENT BLANK Water 12/15/15 13:58 12/16/15 11:33
92280023002 TRIP BLANK Water 12/15/15 13:58 12/16/15 11:33
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 3 of 18
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92280023
Clay Co. Equipment Blank
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92280023001 EQUIPMENT BLANK EPA 6010 15 PASI-ACDF, JMW
EPA 7470 1 PASI-ASH1
EPA 8260 52 PASI-CGAW
92280023002 TRIP BLANK EPA 8260 52 PASI-CGAW
REPORT OF LABORATORY ANALYSIS
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Page 4 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92280023
Clay Co. Equipment Blank
Sample: EQUIPMENT BLANK Lab ID: 92280023001 Collected: 12/15/15 13:58 Received: 12/16/15 11:33 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/19/15 05:38 7440-36-012/17/15 19:005.0 3.8 1
Arsenic ND ug/L 12/19/15 05:38 7440-38-212/17/15 19:0010.0 2.5 1
Barium ND ug/L 12/19/15 05:38 7440-39-312/17/15 19:005.0 2.5 1
Beryllium ND ug/L 12/19/15 05:38 7440-41-712/17/15 19:001.0 0.50 1
Cadmium ND ug/L 12/19/15 05:38 7440-43-912/17/15 19:001.0 0.50 1
Chromium ND ug/L 12/19/15 05:38 7440-47-312/17/15 19:005.0 2.5 1
Cobalt ND ug/L 12/19/15 05:38 7440-48-412/17/15 19:005.0 2.5 1
Copper ND ug/L 12/19/15 05:38 7440-50-812/17/15 19:005.0 2.5 1
Lead ND ug/L 12/19/15 05:38 7439-92-112/17/15 19:005.0 2.5 1
Nickel ND ug/L 12/19/15 05:38 7440-02-012/17/15 19:005.0 2.5 1
Selenium ND ug/L 12/19/15 05:38 7782-49-212/17/15 19:0010.0 5.0 1
Silver ND ug/L 12/19/15 05:38 7440-22-412/17/15 19:005.0 2.5 1
Thallium 6.4 ug/L 12/22/15 17:41 7440-28-012/17/15 19:005.4 5.0 1
Vanadium ND ug/L 12/19/15 05:38 7440-62-212/17/15 19:005.0 2.5 1
Zinc 5.8J ug/L 12/19/15 05:38 7440-66-612/17/15 19:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/21/15 12:13 7439-97-612/19/15 18:300.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/29/15 08:56 67-64-125.0 10.0 1
Acrylonitrile ND ug/L 12/29/15 08:56 107-13-110.0 1.9 1
Benzene ND ug/L 12/29/15 08:56 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/29/15 08:56 74-97-51.0 0.17 1
Bromodichloromethane ND ug/L 12/29/15 08:56 75-27-41.0 0.18 1
Bromoform ND ug/L 12/29/15 08:56 75-25-21.0 0.26 1
Bromomethane ND ug/L 12/29/15 08:56 74-83-92.0 0.29 1
2-Butanone (MEK)ND ug/L 12/29/15 08:56 78-93-35.0 0.96 1
Carbon disulfide ND ug/L 12/29/15 08:56 75-15-02.0 1.2 1
Carbon tetrachloride ND ug/L 12/29/15 08:56 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/29/15 08:56 108-90-71.0 0.23 1
Chloroethane ND ug/L 12/29/15 08:56 75-00-31.0 0.54 1
Chloroform ND ug/L 12/29/15 08:56 67-66-31.0 0.14 1
Chloromethane ND ug/L 12/29/15 08:56 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/29/15 08:56 96-12-82.0 2.0 1
Dibromochloromethane ND ug/L 12/29/15 08:56 124-48-11.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/29/15 08:56 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/29/15 08:56 74-95-31.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/29/15 08:56 95-50-11.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/29/15 08:56 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/29/15 08:56 110-57-61.0 1.0 1
1,1-Dichloroethane ND ug/L 12/29/15 08:56 75-34-31.0 0.32 1
1,2-Dichloroethane ND ug/L 12/29/15 08:56 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/29/15 08:56 75-35-41.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/29/15 08:56 156-59-21.0 0.19 1
trans-1,2-Dichloroethene 0.59J ug/L 12/29/15 08:56 156-60-51.0 0.49 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92280023
Clay Co. Equipment Blank
Sample: EQUIPMENT BLANK Lab ID: 92280023001 Collected: 12/15/15 13:58 Received: 12/16/15 11:33 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloropropane ND ug/L 12/29/15 08:56 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/29/15 08:56 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/29/15 08:56 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/29/15 08:56 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/29/15 08:56 591-78-65.0 0.46 1
Iodomethane ND ug/L 12/29/15 08:56 74-88-45.0 0.32 1
Methylene Chloride 75.9 ug/L 12/29/15 08:56 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/29/15 08:56 108-10-15.0 0.33 1
Styrene ND ug/L 12/29/15 08:56 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/29/15 08:56 630-20-61.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/29/15 08:56 79-34-51.0 0.40 1
Tetrachloroethene ND ug/L 12/29/15 08:56 127-18-41.0 0.46 1
Toluene 0.45J ug/L 12/29/15 08:56 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/29/15 08:56 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/29/15 08:56 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/29/15 08:56 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/29/15 08:56 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/29/15 08:56 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/29/15 08:56 108-05-42.0 0.35 1
Vinyl chloride ND ug/L 12/29/15 08:56 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/29/15 08:56 1330-20-72.0 0.66 1
m&p-Xylene ND ug/L 12/29/15 08:56 179601-23-12.0 0.66 1
o-Xylene ND ug/L 12/29/15 08:56 95-47-61.0 0.23 1
Surrogates
4-Bromofluorobenzene (S)112 %12/29/15 08:56 460-00-470-130 1
1,2-Dichloroethane-d4 (S)92 %12/29/15 08:56 17060-07-070-130 1
Toluene-d8 (S)118 %12/29/15 08:56 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92280023
Clay Co. Equipment Blank
Sample: TRIP BLANK Lab ID: 92280023002 Collected: 12/15/15 13:58 Received: 12/16/15 11:33 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/29/15 12:36 67-64-125.0 10.0 1
Acrylonitrile ND ug/L 12/29/15 12:36 107-13-110.0 1.9 1
Benzene ND ug/L 12/29/15 12:36 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/29/15 12:36 74-97-51.0 0.17 1
Bromodichloromethane ND ug/L 12/29/15 12:36 75-27-41.0 0.18 1
Bromoform ND ug/L 12/29/15 12:36 75-25-21.0 0.26 1
Bromomethane ND ug/L 12/29/15 12:36 74-83-92.0 0.29 1
2-Butanone (MEK)ND ug/L 12/29/15 12:36 78-93-35.0 0.96 1
Carbon disulfide ND ug/L 12/29/15 12:36 75-15-02.0 1.2 1
Carbon tetrachloride ND ug/L 12/29/15 12:36 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/29/15 12:36 108-90-71.0 0.23 1
Chloroethane ND ug/L 12/29/15 12:36 75-00-31.0 0.54 1
Chloroform ND ug/L 12/29/15 12:36 67-66-31.0 0.14 1
Chloromethane ND ug/L 12/29/15 12:36 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/29/15 12:36 96-12-82.0 2.0 1
Dibromochloromethane ND ug/L 12/29/15 12:36 124-48-11.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/29/15 12:36 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/29/15 12:36 74-95-31.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/29/15 12:36 95-50-11.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/29/15 12:36 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/29/15 12:36 110-57-61.0 1.0 1
1,1-Dichloroethane ND ug/L 12/29/15 12:36 75-34-31.0 0.32 1
1,2-Dichloroethane ND ug/L 12/29/15 12:36 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/29/15 12:36 75-35-41.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/29/15 12:36 156-59-21.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/29/15 12:36 156-60-51.0 0.49 1
1,2-Dichloropropane ND ug/L 12/29/15 12:36 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/29/15 12:36 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/29/15 12:36 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/29/15 12:36 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/29/15 12:36 591-78-65.0 0.46 1
Iodomethane ND ug/L 12/29/15 12:36 74-88-45.0 0.32 1
Methylene Chloride 1.6 ug/L 12/29/15 12:36 75-09-2 C91.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/29/15 12:36 108-10-15.0 0.33 1
Styrene ND ug/L 12/29/15 12:36 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/29/15 12:36 630-20-61.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/29/15 12:36 79-34-51.0 0.40 1
Tetrachloroethene ND ug/L 12/29/15 12:36 127-18-41.0 0.46 1
Toluene ND ug/L 12/29/15 12:36 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/29/15 12:36 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/29/15 12:36 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/29/15 12:36 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/29/15 12:36 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/29/15 12:36 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/29/15 12:36 108-05-42.0 0.35 1
Vinyl chloride ND ug/L 12/29/15 12:36 75-01-41.0 0.62 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92280023
Clay Co. Equipment Blank
Sample: TRIP BLANK Lab ID: 92280023002 Collected: 12/15/15 13:58 Received: 12/16/15 11:33 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Xylene (Total)ND ug/L 12/29/15 12:36 1330-20-72.0 0.66 1
m&p-Xylene ND ug/L 12/29/15 12:36 179601-23-12.0 0.66 1
o-Xylene ND ug/L 12/29/15 12:36 95-47-61.0 0.23 1
Surrogates
4-Bromofluorobenzene (S)102 %12/29/15 12:36 460-00-470-130 1
1,2-Dichloroethane-d4 (S)96 %12/29/15 12:36 17060-07-070-130 1
Toluene-d8 (S)104 %12/29/15 12:36 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280023
Clay Co. Equipment Blank
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/8799
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92280023001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1632840
Associated Lab Samples:92280023001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/21/15 11:410.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1632841LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.12.5 84 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1632842MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279477001
1632844
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 92 75-12575 20 252.5ND 2.4 1.9
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:00 AM
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280023
Clay Co. Equipment Blank
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20312
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92280023001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1631789
Associated Lab Samples:92280023001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 12/19/15 05:133.8
Arsenic ug/L ND 10.0 12/19/15 05:132.5
Barium ug/L ND 5.0 12/19/15 05:132.5
Beryllium ug/L ND 1.0 12/19/15 05:130.50
Cadmium ug/L ND 1.0 12/19/15 05:130.50
Chromium ug/L ND 5.0 12/19/15 05:132.5
Cobalt ug/L ND 5.0 12/19/15 05:132.5
Copper ug/L ND 5.0 12/19/15 05:132.5
Lead ug/L ND 5.0 12/19/15 05:132.5
Nickel ug/L ND 5.0 12/19/15 05:132.5
Selenium ug/L ND 10.0 12/19/15 05:135.0
Silver ug/L ND 5.0 12/19/15 05:132.5
Thallium ug/L ND 5.4 12/22/15 17:355.0
Vanadium ug/L ND 5.0 12/19/15 05:132.5
Zinc ug/L ND 10.0 12/19/15 05:135.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1631790LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 489500 98 80-120
Arsenic ug/L 526500 105 80-120
Barium ug/L 496500 99 80-120
Beryllium ug/L 502500 100 80-120
Cadmium ug/L 519500 104 80-120
Chromium ug/L 529500 106 80-120
Cobalt ug/L 530500 106 80-120
Copper ug/L 515500 103 80-120
Lead ug/L 524500 105 80-120
Nickel ug/L 524500 105 80-120
Selenium ug/L 520500 104 80-120
Silver ug/L 233250 93 80-120
Thallium ug/L 522500 104 80-120
Vanadium ug/L 518500 104 80-120
Zinc ug/L 554500 111 80-120
REPORT OF LABORATORY ANALYSIS
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[phone]
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280023
Clay Co. Equipment Blank
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1631791MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279775001
1631792
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 99 75-12597 2 25500ND495 483
Arsenic ug/L 500 107 75-125104 3 25500ND537 519
Barium ug/L 500 101 75-12598 3 25500108614 597
Beryllium ug/L 500 103 75-125100 3 25500ND515 499
Cadmium ug/L 500 105 75-125102 3 25500ND526 510
Chromium ug/L 500 107 75-125105 3 25500ND538 524
Cobalt ug/L 500 107 75-125104 3 2550010.9 546 528
Copper ug/L 500 105 75-125101 3 25500ND524 508
Lead ug/L 500 105 75-125102 3 25500ND526 510
Nickel ug/L 500 105 75-125102 3 255006.7 534 517
Selenium ug/L 500 104 75-125101 2 25500ND520 508
Silver ug/L 250 95 75-12592 4 25250ND238 230
Thallium ug/L 500 98 75-12597 1 25500ND488 483
Vanadium ug/L 500 106 75-125103 3 255002.9J 534 517
Zinc ug/L 500 112 75-125109 2 2550020.2 581 567
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 11 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280023
Clay Co. Equipment Blank
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34968
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92280023001, 92280023002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1638140
Associated Lab Samples:92280023001, 92280023002
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 12/29/15 06:110.33
1,1,1-Trichloroethane ug/L ND 1.0 12/29/15 06:110.48
1,1,2,2-Tetrachloroethane ug/L ND 1.0 12/29/15 06:110.40
1,1,2-Trichloroethane ug/L ND 1.0 12/29/15 06:110.29
1,1-Dichloroethane ug/L ND 1.0 12/29/15 06:110.32
1,1-Dichloroethene ug/L ND 1.0 12/29/15 06:110.56
1,2,3-Trichloropropane ug/L ND 1.0 12/29/15 06:110.41
1,2-Dibromo-3-chloropropane ug/L ND 2.0 12/29/15 06:112.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/29/15 06:110.27
1,2-Dichlorobenzene ug/L ND 1.0 12/29/15 06:110.30
1,2-Dichloroethane ug/L ND 1.0 12/29/15 06:110.24
1,2-Dichloropropane ug/L ND 1.0 12/29/15 06:110.27
1,4-Dichlorobenzene ug/L ND 1.0 12/29/15 06:110.33
2-Butanone (MEK)ug/L ND 5.0 12/29/15 06:110.96
2-Hexanone ug/L ND 5.0 12/29/15 06:110.46
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 12/29/15 06:110.33
Acetone ug/L ND 25.0 12/29/15 06:1110.0
Acrylonitrile ug/L ND 10.0 12/29/15 06:111.9
Benzene ug/L ND 1.0 12/29/15 06:110.25
Bromochloromethane ug/L ND 1.0 12/29/15 06:110.17
Bromodichloromethane ug/L ND 1.0 12/29/15 06:110.18
Bromoform ug/L ND 1.0 12/29/15 06:110.26
Bromomethane ug/L ND 2.0 12/29/15 06:110.29
Carbon disulfide ug/L ND 2.0 12/29/15 06:111.2
Carbon tetrachloride ug/L ND 1.0 12/29/15 06:110.25
Chlorobenzene ug/L ND 1.0 12/29/15 06:110.23
Chloroethane ug/L ND 1.0 12/29/15 06:110.54
Chloroform ug/L ND 1.0 12/29/15 06:110.14
Chloromethane ug/L ND 1.0 12/29/15 06:110.11
cis-1,2-Dichloroethene ug/L ND 1.0 12/29/15 06:110.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/29/15 06:110.13
Dibromochloromethane ug/L ND 1.0 12/29/15 06:110.21
Dibromomethane ug/L ND 1.0 12/29/15 06:110.21
Ethylbenzene ug/L ND 1.0 12/29/15 06:110.30
Iodomethane ug/L ND 5.0 12/29/15 06:110.32
m&p-Xylene ug/L ND 2.0 12/29/15 06:110.66
Methylene Chloride ug/L ND 1.0 12/29/15 06:110.97
o-Xylene ug/L ND 1.0 12/29/15 06:110.23
Styrene ug/L ND 1.0 12/29/15 06:110.26
Tetrachloroethene ug/L ND 1.0 12/29/15 06:110.46
Toluene ug/L ND 1.0 12/29/15 06:110.26
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 12 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280023
Clay Co. Equipment Blank
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1638140
Associated Lab Samples:92280023001, 92280023002
Matrix: Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 1.0 12/29/15 06:110.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/29/15 06:110.26
trans-1,4-Dichloro-2-butene ug/L ND 1.0 12/29/15 06:111.0
Trichloroethene ug/L ND 1.0 12/29/15 06:110.47
Trichlorofluoromethane ug/L ND 1.0 12/29/15 06:110.20
Vinyl acetate ug/L ND 2.0 12/29/15 06:110.35
Vinyl chloride ug/L ND 1.0 12/29/15 06:110.62
Xylene (Total)ug/L ND 2.0 12/29/15 06:110.66
1,2-Dichloroethane-d4 (S)%91 70-130 12/29/15 06:11
4-Bromofluorobenzene (S)%102 70-130 12/29/15 06:11
Toluene-d8 (S)%109 70-130 12/29/15 06:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1638141LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.650 101 80-125
1,1,1-Trichloroethane ug/L 48.050 96 71-129
1,1,2,2-Tetrachloroethane ug/L 50.650 101 79-124
1,1,2-Trichloroethane ug/L 50.950 102 85-125
1,1-Dichloroethane ug/L 45.250 90 73-126
1,1-Dichloroethene ug/L 43.650 87 66-135
1,2,3-Trichloropropane ug/L 51.250 102 75-130
1,2-Dibromo-3-chloropropane ug/L 47.850 96 71-133
1,2-Dibromoethane (EDB)ug/L 53.450 107 83-124
1,2-Dichlorobenzene ug/L 49.150 98 80-133
1,2-Dichloroethane ug/L 45.650 91 67-128
1,2-Dichloropropane ug/L 46.850 94 75-132
1,4-Dichlorobenzene ug/L 49.250 98 78-130
2-Butanone (MEK)ug/L 113100 113 61-144
2-Hexanone ug/L 108100 108 68-143
4-Methyl-2-pentanone (MIBK)ug/L 107100 107 72-135
Acetone ug/L 105100 105 48-146
Acrylonitrile ug/L 255250 102 40-160
Benzene ug/L 49.050 98 80-125
Bromochloromethane ug/L 53.750 107 71-125
Bromodichloromethane ug/L 48.150 96 78-124
Bromoform ug/L 43.750 87 71-128
Bromomethane ug/L 40.450 81 40-160
Carbon disulfide ug/L 41.050 82 50-160
Carbon tetrachloride ug/L 49.150 98 69-131
Chlorobenzene ug/L 49.950 100 81-122
Chloroethane ug/L 33.950 68 39-148
Chloroform ug/L 47.650 95 73-127
Chloromethane ug/L 53.750 107 44-146
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:00 AM
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[phone]
Page 13 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92280023
Clay Co. Equipment Blank
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1638141LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 44.950 90 74-124
cis-1,3-Dichloropropene ug/L 50.850 102 72-132
Dibromochloromethane ug/L 52.850 106 78-125
Dibromomethane ug/L 52.250 104 82-120
Ethylbenzene ug/L 46.550 93 79-121
Iodomethane ug/L 85.5100 86 39-154
m&p-Xylene ug/L 91.9100 92 81-124
Methylene Chloride ug/L 57.250 114 64-133
o-Xylene ug/L 44.950 90 79-131
Styrene ug/L 48.050 96 84-126
Tetrachloroethene ug/L 49.350 99 78-122
Toluene ug/L 45.050 90 80-121
trans-1,2-Dichloroethene ug/L 47.850 96 71-127
trans-1,3-Dichloropropene ug/L 45.450 91 69-141
trans-1,4-Dichloro-2-butene ug/L 54.350 109 40-160
Trichloroethene ug/L 52.550 105 78-122
Trichlorofluoromethane ug/L 43.350 87 53-137
Vinyl acetate ug/L 99.6100 100 40-160
Vinyl chloride ug/L 46.150 92 58-137
Xylene (Total)ug/L 137150 91 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%94 70-130
REPORT OF LABORATORY ANALYSIS
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Page 14 of 18
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92280023
Clay Co. Equipment Blank
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Common Laboratory Contaminant.C9
REPORT OF LABORATORY ANALYSIS
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Page 15 of 18
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92280023
Clay Co. Equipment Blank
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92280023001 MPRP/20312 ICP/18330EQUIPMENT BLANK EPA 3010A EPA 6010
92280023001 MERP/8799 MERC/8455EQUIPMENT BLANK EPA 7470 EPA 7470
92280023001 MSV/34968EQUIPMENT BLANK EPA 8260
92280023002 MSV/34968TRIP BLANK EPA 8260
REPORT OF LABORATORY ANALYSIS
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Page 16 of 18
Page 17 of 18
Page 18 of 18

APPENDIX C

Environmental Monitoring Reporting Form
and Electronic Submittal of
Environmental Monitoring Data
2201Dec2015 (Electronic Submittal Only)