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HomeMy WebLinkAbout5502_LincolnCountyOwlsDen_GWMReport_DIN26397_20151009October 2015 Semi-Annual Monitoring Report Owl’s Den Landfill Lincolnton, North Carolina S&ME Project No. 1356-07-006 Prepared for: Lincoln County 5291 Crouse Road Crouse, North Carolina 28033 Prepared by: S&ME, Inc. 9751 Southern Pine Boulevard Charlotte, NC 28273 December 8, 2015 S&ME, Inc. | 9751 Southern Pine Boulevard | Charlotte, NC 28273 | p 704.523.4726 | f 704.525.3953 | www.smeinc.com December 8, 2015 Lincoln County 5291 Crouse Road Crouse, North Carolina 28033 Attention: Mr. Mark Bivins Reference: October 2015 Semi-Annual Monitoring Report Owl’s Den Landfill Lincolnton, North Carolina S&ME Project No. 1356-07-006 Dear Mr. Bivins: S&ME Inc. (S&ME) has completed the October 2015 Semi-Annual Monitoring and Reporting for the Owl’s Den Landfill. This report presents the results of the second monitoring event of the year for the facility. S&ME appreciates the continued opportunity to provide services to you and Lincoln County. If you have any questions or need additional information regarding this report, please contact us at (704) 523-4726. Sincerely, S&ME, Inc. Jasmine Tayouga, E.I. Julie P. Robertson, P.G. Staff Professional Project Manager/Senior Geologist NC Registration No. 1995 Cc: Jaclynne Drummond, NCDENR – Solid Waste Section October 2015 Semi-Annual Monitoring Report Owl’s Den Landfill Lincolnton, North Carolina S&ME Project No. 1356-07-006 December 8, 2015 ii Table of Contents 1.0 Introduction ............................................................................................................ 1 2.0 Groundwater Levels and Flow............................................................................ 1 3.0 Analytical Data ...................................................................................................... 2 3.1 Monitoring Well Sampling .............................................................................................. 2 3.1.1.Volatile Organic Compounds (VOCs) ........................................................................... 2 3.1.2.Inorganic Constituents (Metals) ..................................................................................... 3 3.2.Surface Water Sampling .................................................................................................. 3 3.2.1.Volatile Organic Compounds (VOCs) ........................................................................... 3 3.2.2.Inorganic Constituents (Metals) ..................................................................................... 3 3.3.Private Supply Well Sampling ........................................................................................ 4 4.Methane Readings ................................................................................................. 4 Appendices Appendix I – Drawings Appendix II –Tables Appendix III – Well Sampling Logs and Laboratory Reports October 2015 Semi-Annual Monitoring Report Owl’s Den Landfill Lincolnton, North Carolina S&ME Project No. 1356-07-006 December 8, 2015 1 1.0 Introduction S&ME, Inc. (S&ME) was contracted by Lincoln County to provide groundwater, surface water, and water supply well monitoring services at the Owl’s Den Landfill (the Site) located off Owl’s Den Road in Lincolnton, North Carolina. This semi-annual monitoring event was conducted on October 8th and 9th, 2015. This report presents the results of the second semi-annual sampling event for the year 2015 at the facility, which included the sampling of one (1) background well (MW-1), ten (10) compliance wells (MW-2, MW- 4, MW-5, MW-6, MW-6A, MW-7, MW-7A, MW-8, MW-9, and MW-10), three (3) surface water locations (SW-1, SW-2 and SW-3), and four (4) private supply wells (PSW-1, PSW-3, PSW-6, and PSW-16). Surface water location SW-1 represents the background surface water sample for the Site. Please note that compliance well MW-3 has been removed from the Site’s monitoring plan due to expansion of the property boundary currently monitored by compliance wells MW-8 and MW-9. Compliance monitoring well MW-3 remains on-site for water level measurement purposes. Lincoln County personnel collect monthly landfill gas readings at seven (7) methane monitoring wells (MMW-2, MMW-4, MMW-5, MMW-6, MMW-7, MMW-8, and MMW-9). Please note that methane monitoring wells MMW-1 and MMW-3 have been removed from the Site’s monitoring plan. MMW-1 was replaced with MMW-7, and MMW-3 was replaced with MMW-5 and MMW-6. This report includes the results (both current and historical) of the Site’s landfill gas monitoring. The next sampling event is scheduled for April 2016. 2.0 Groundwater Levels and Flow The water table elevations and our interpretation of the groundwater surface expressed as a potentiometric map along with groundwater flow direction are shown in Appendix I. Based upon the groundwater elevations in the vicinity of the landfill, groundwater in this area is projected to flow north- northwest toward the drainage features bordering the site on the west, north and east of the property. Groundwater levels obtained during the October 2015 monitoring event, as well as monitoring well construction data, are presented in Appendix II. The hydraulic gradient (i) in the vicinity of each well was determined by calculating the vertical difference between the groundwater elevation at each well and one or more nearby contour lines from the Groundwater Elevation Map. This value was then divided by the distance measured from the well to the selected groundwater elevation contour line. Groundwater velocity was calculated by multiplying the gradient (i) by the hydraulic conductivity (k) and dividing by the estimated effective porosity (ne) of the aquifer. Table 2 summarizes the groundwater flow velocities for the monitoring wells. October 2015 Semi-Annual Monitoring Report Owl’s Den Landfill Lincolnton, North Carolina S&ME Project No. 1356-07-006 December 8, 2015 2 3.0 Analytical Data Analytical results for the landfill monitoring wells and surface water locations are summarized in Tables 4 and 5. Field measurements of pH, conductivity, and temperature are summarized in Table 3. Well sampling logs containing field measurements of pH, conductivity, temperature, and water levels are included in Appendix III. The monitoring wells, surface water locations, and private supply wells were sampled for volatile organics by EPA Method 8260B and for RCRA metals. 3.1 Monitoring Well Sampling 3.1.1.Volatile Organic Compounds (VOCs) No volatile organic compounds (VOCs) were detected in the background monitoring well, MW-1, or monitoring wells MW-5 and MW-10. Nine (9) VOCs were detected in monitoring well MW-2, none of which were detected at a level at or above their respective NCAC 2L .0202 Groundwater Quality Standard (2L Standard) and/or respective North Carolina Department of Environment and Natural Resources - Solid Waste Section - Groundwater Protection Standard (SW GWP Standard). Ten (10) VOCs were detected in monitoring well MW-4, three (3) of which were detected at levels at or above their respective 2L Standard and/or respective SW GWP Standard (1,2-Dichloroethane, 1,4- Dichlorobenzene, and Benzene). Five (5) VOCs were detected in monitoring well MW-6, none of which were detected at or above their respective 2L Standard and/or respective SW GWP Standard. Seven (7) VOCs were detected in monitoring well MW-6A, one (1) of which was detected at or above its respective 2L Standard and/or respective SW GWP Standard (1,4-Dichlorobenzene). Eight (8) VOCs were detected in monitoring well MW-7, none of which were detected at or above their respective 2L Standard and/or respective SW GWP Standard. Nine (9) VOCs were detected in monitoring well MW-7A, none of which were detected at or above their respective 2L Standard and/or respective SW GWP Standard. One (1) VOC was detected in monitoring well MW-8 and was below its respective 2L Standard and/or respective SW GWP Standard. One (1) VOC was detected in monitoring well MW-9 at a concentration at/or above its respective 2L Standard and/or respective SW GWP Standard (Tetrachloroethene). October 2015 Semi-Annual Monitoring Report Owl’s Den Landfill Lincolnton, North Carolina S&ME Project No. 1356-07-006 December 8, 2015 3 3.1.2.Inorganic Constituents (Metals) Barium was detected in all eleven monitoring wells, including the background monitoring well MW-1. Barium was detected at concentrations of 784 and 724 micrograms per liter (µg/L) in monitoring wells MW-6A and MW-7A, respectively, which is above its 2L Standard of 700 µg/L. Cadmium was detected in monitoring wells MW-2, MW-6, MW-7A, and MW-8. Cadmium was detected above its 2L Standard of 2 µg/L in monitoring wells MW-2 and MW-7A at concentrations of 2.13 and 3.00 µg/L, respectively. Chromium was detected in monitoring wells MW-2, MW-6, MW-7A, and MW-10. Chromium was detected above its 2L Standard of 10 µg/L in monitoring well MW-7A at a concentration of 10.5 µg/L. Mercury was detected in monitoring well MW-9 at a concentration of 5.18 µg/L, which is above its 2L Standard of 1 µg/L. Silver was detected in monitoring wells MW-2, MW-4, MW-6, MW-6A and MW-7A at concentrations ranging from 2.22 J to 4.39 J µg/L, which is below its 2L Standard of 20 µg/L. Please note that the concentrations of metals in the monitoring wells fluctuate with time and may be due to suspended solids rather than actual dissolved metals. No other metals were detected in the monitoring wells. 3.2.Surface Water Sampling 3.2.1.Volatile Organic Compounds (VOCs) The volatile organic compound 1,4-Dichloroethane was detected at surface water sampling location SW-3 at a concentration of 1.2 µg/L. The NCAC 2B Freshwater Standard for 1,4-Dichoroethane is 100 µg/L. The volatile organic compound cis-1,2-Dichloroethene was detected at surface water sampling location SW-2 at a concentration of 0.62 J μg/L. The NCAC 2B Freshwater Standard for cis-1,2-Dichloroethene is 4,900 µg/L. The volatile organic compound Chlorobenzene was detected at surface water sampling location SW-3 at a concentration of 0.70 J µg/L. The NCAC 2B Freshwater Standard for Chlorobenzene is 140 µg/L. 3.2.2.Inorganic Constituents (Metals) Barium was detected at surface water sampling locations SW-1, SW-2 and SW-3 at concentrations of 221, 226, and 321 μg/L, respectively. The NCAC 2B Freshwater Standard established for Barium is 200,000 μg/L. Chromium was detected at surface water sampling location SW-1 at a concentration of 4.12 J μg/L. The NCAC 2B Freshwater Standard for Chromium is 50 μg/L. October 2015 Semi-Annual Monitoring Report Owl’s Den Landfill Lincolnton, North Carolina S&ME Project No. 1356-07-006 December 8, 2015 4 No other metals were detected in the surface water samples. 3.3.Private Supply Well Sampling During the October 2015 sampling event, four (4) private water supply wells (PSW-1, PSW-3, PSW-6, and PSW-16) located on properties adjacent to the landfill, were sampled for EPA method 8260B volatile organics and RCRA metals. The locations of the four (4) private well locations are shown on the attached Figure 1. Laboratory analytical results for the private supply wells are summarized in Table 6 and also included in Appendix III. No volatile organic compounds were detected in any of the private supply wells sampled during the October 2015 monitoring event. Each of the four (4) private supply wells had detections of barium ranging from 42.3 to 111 µg/L. The 2L Standard for Barium is 700 µg/L. No other metals were detected in the private supply wells during the October 2015 sampling event. 4.Methane Readings Methane readings from the seven (7) methane monitoring wells on site (MMW-2, MMW-4, MMW-5, MMW-6, MMW-7, MMW-8, and MMW-9) are measured monthly by Lincoln County personnel using a GEM 2000 gas meter. Table 7 and its corresponding charts summarize the current and historical data collected. Appendices Appendix I - Drawings (# (# (# (# kj kj #A#A #A #A (# (# (#kj !W !W !W !W (##A #A(# #A (##A #A MW-8 MW-9 MMW-9 MMW-8MW-10 MMW-7 MMW-5 MMW-6 SW-3MW-5 SW-2 SW-1 MW-3 MW-4 MW-1 MW-2 MMW-4 MMW-2 MMW-3 MMW-1 MW-7/7A MW-6/6A PSW-1 PSW-3 PSW-6 PSW-16 815 810 805 820 795 825 830 800 Source: Esri, DigitalGlobe, GeoEye, i-cubed, USDA, USGS, AEX, Getmapping, Aerogrid, IGN, IGP, swisstopo, and the GIS User Community G R O U N D W A T E R E L E V A T I O N M A P O C T O B E R , 2 0 1 5 O W L S D E N L A N D F I L L L I N C O L N T O N , N O R T H C A R O L I N A 1 1 3 5 6 -0 7 -0 0 6 1 " = 3 0 0 ' S J T 1 2 /0 3 /2 0 1 5 FIGURE NO. S C A L E : P R O J E C T N O : D A T E : D R A W N B Y : C H E C K E D B Y : W W W .S M E I N C .C O M ! 0 300 600150Feet J P R O W L S D E N R O A D 791.64 792.94 811.38 801.56 796.44 822.85 828.43832.99 830.09832.00 PARCEL AND TOPOGRAPHIC GIS DATA AND 2014 AERIAL PHOTOGRAPHY WERE OBTAINED FROM THE WORLD IMAGERY ESRI MAPPING SERVICE. EXISTING AND PROPOSED WELL LOCATIONS, SURFACE WATER SAMPLE LOCATIONS, GROUND WATER SURFACE DATA, AND SURFACE WATER FEATURES WERE GENERATED BY S&ME, INC. PLEASE NOTE THIS DATA IS FOR INFORMATIONAL PURPOSES ONLY. IT IS NOT MEANT FOR DESIGN, LEGAL, OR ANY OTHER USES. THERE ARE NO GUARANTEES ABOUT ITS ACCURACY. S&ME, INC. ASSUMES NO RESPONSIBILITY FOR ANY DECISION MADE OR ANY ACTIONS TAKEN BY THE USER BASED UPON INFORMATION OBTAINED FROM THE ABOVE DATA. REFERENCE: Q :\1 3 5 6 \L I N C O L N C O U N T Y \O w l 's D e n \G W E l e v a t i o n s a n d G I S \O w l s D e n G r o u n d w a t e r E l e v a t i o n O c t o b e r 2 0 1 5 1 1 x 1 7 .m x d GROUNDWATER SURFACE ELEVATION (FT-MSL) Legend GROUNDWATER SURFACE (10/2015) PROPERTY BOUNDARYExisting Wells (#GROUNDWATER MONITORING WELLS #AMETHANE MONITORING WELLS kj SURFACE WATER SAMPLING LOCATION SURFACE WATER FEATURES PARCEL BOUNDARIES PRIVATE SUPPLY WELLS GROUNDWATER SURFACE ELEVATION (FT-MSL)828.43 !W Appendix II - Tables Latitude Longitude Ground TOC DTW - TOC GW ELEV (MM/DD/YY)(ft)(ft - MSL) MW-1 09/28/00 35.4845710°-081.3075490°863.20 865.69 0.0 to 30.0 30.0 to 45.0 0.0 to 26.0 26.0 to 28.0 Bentonite 28.0 to 45.0 SAP 37.26 828.43 MW-2 10/03/00 35.4874879°-081.3094713°822.50 824.96 0.0 to 23.0 23.0 to 38.0 0.0 to 19.0 19.0 to 21.0 Bentonite 21.0 to 38.0 PWR 23.40 801.56 MW-3 09/26/00 35.4846148°-081.3089804°870.20 872.60 0.0 to 33.0 33.0 to 48.0 0.0 to 28.5 28.5 to 30.5 Bentonite 30.5 to 48.0 PWR 42.51 830.09 MW-4 10/02/00 35.4874987°-081.3125120°831.80 833.90 0.0 to 40.0 40.0 to 55.0 0.0 to 36.0 36.0 to 38.0 Bentonite 38.0 to 55.0 PWR 40.96 792.94 MW-5 08/05/01 35.4857775°-081.3140465°835.90 839.10 0.0 to 15.0 15.0 to 30.0 0.0 to 10.5 10.5 to 13.0 Bentonite 13.0 to 30.0 SAP 27.72 811.38 MW-6 07/24/01 35.4877917°-081.3128338°805.44 808.55 0.0 to 6.0 6.0 to 21.0 0.0 to 3.0 3.0 to 5.0 Bentonite 5.0 to 21.0 PWR 16.91 791.64 MW-6A*07/18/01 35.4877917°-081.3128338°805.17 808.61 0.0 to 44.5 45.0 to 55.0 0.0 to 41.5 41.5 to 45.0 Bentonite and K-Packer ROCK 18.60 790.01 MW-7 07/24/01 35.4876205°-081.3095665°815.47 818.44 0.0 to 10.0 10.0 to 25.0 0.0 to 6.0 6.0 to 8.0 Bentonite 8.0 to 25.0 PWR 22.00 796.44 MW-7A**07/24/01 35.4876205°-081.3095665°814.68 817.48 0.0 to 41.0 41.5 to 51.5 0.0 to 39.0 39.0 to 41.5 Bentonite and K-Packer ROCK 25.85 791.63 MW-8 07/14/08 35.4843606°-081.3094687°878.23 881.21 3.0 to 39.0 39.0 to 54.0 0.0 to 34.5 34.5 to 36.5 Bentonite 36.5 to 54.0 SAP 49.21 832.00 MW-9 07/08/08 35.4841556°-081.3084430°882.19 884.94 2.8 to 45.0 45.0 to 60.0 0.0 to 36.0 36.0 to 39.5 Bentonite 39.5 to 60.0 SAP 51.95 832.99 MW-10 07/10/08 35.4853675°-081.3073758°864.33 867.11 2.8 to 33.0 33.0 to 48.0 0.0 to 29.0 29.0 to 31.3 Bentonite 31.3 to 48.0 SAP 44.26 822.85 Notes: (ft-MSL)Feet Mean Sea Level (ft-bls)Feet Below Land Surface TOC Top of Casing Ground Ground Surface DRY No water in well at time of sampling NS Well was not sampled N/A Not Applicable DTW Depth to Water GW ELEV.Groundwater Elevation #2 Filter Sand Medium to Fine Grained Silica Sand Bentonite Bentonite Pellets Sch. 40 Schedule 40 Pipe 0.010 Slot 0.010-Inch Machine-Slotted Pipe Neat Cement Cement Mixture without Bentonite SAP Saprolite PWR Partially Weathered Rock ROCK Bedrock - - -Not Available October 2015Geology in Screen Interval Filter Pack Interval (ft-bls) 2-inch, SCH. 40, PVC Screen Interval Grout Interval 2-inch, 0.010 Slot, PVC Neatr Cement (decimal degrees)(ft-MSL)(ft-bls) BentoniteInstall Date GPS Coordinates Survey Elevations Casing Interval (ft-bls)(ft-bls) None None Table 1 Well Construction Summary and Water Level Data Owl's Den Landfill S&ME Project No: 1356-07-006 Well ID Seal Interval (ft-bls) K n I v Well Hydraulic Cond. Eff. Porosity Gradient Flow Velocity ID (ft/day)(ne)(ft/ft)(ft/yr) MW-1 4.3E+02 0.20 0.02 47 MW-2 2.6E+03 0.28 0.08 735 MW-3 9.8E+02 0.33 0.01 15 MW-4 1.3E+03 0.30 0.04 166 MW-5 6.2E+02 0.27 0.01 27 MW-6 4.2E+02 0.29 0.02 25 MW-7 2.1E+02 0.30 0.02 16 MW-8 5.6E+02 0.28 0.02 47 MW-9 1.3E+03 0.31 0.02 80 MW-10 9.5E+02 0.31 0.09 275 Notes: (1) Hydraulic Conductivity was calculated from slug tests performed after well construction. (2) Effective porosity was estimated from soils collected within the saturated portion of screen interval during well construction. (3) Hydraulic gradient calculated by measuring linear feet between selected contour intervals. (4) Seepage velocity v = (K*i)/ne - - -Not Available Table 2 Groundwater Flow Data Owl's Den Landfill S&ME Project No: 1356-07-006 October 2015 Well ID DTW TOC (ft-bls)pH Temp (°C)Conductance (μS) MW-1 37.26 5.37 16.4 28 MW-2 23.40 6.64 17.1 558 MW-3 42.51 MW-4 40.96 6.88 17.3 1447 MW-5 27.72 6.15 14.7 66 MW-6 16.91 6.76 15.9 832 MW-6A 18.60 7.19 15.8 877 MW-7 22.00 7.11 17.0 411 MW-7A 25.85 6.46 17.3 606 MW-8 49.21 5.68 14.5 48 MW-9 51.95 6.13 16.8 122 MW-10 44.26 5.88 16.2 30 Notes: °C degrees celcius μS micro siemems Table 3 October 2015 - Field Parameters in Monitoring Wells Lincoln County Owl's Den Landfill S&ME Project No. 1356-07-006 NOT RECORDED EPA Volatile Organic Compounds Method 8260B (ug/L) NCDENR SWSL 15A NCAC 2L Soild Waste GWP ST MW-1 MW-2 MW-3 MW-4 MW-5 MW-6 MW- 6A MW-7 MW- 7A MW-8 MW-9 MW-10 1,1- Dichloroethane 5 6 NE 0.41 J 1.1 1.6 0.57 J 1.2 1,2-Dichlorobenzene 5 20 NE 0.60 J 4.3 1.1 3.0 0.42 J 0.60 J 1,2-Dichloroethane 1 0.4 NE 0.83 J 1,2-Dichloropropane 1 0.6 NE 0.42 J 0.41 J 0.43 J 1,3-Dichlorobenzene 5 200 NE 0.46 J 1.1 0.46 J 1,4-Dichlorobenzene 1 6 NE 5.4 14 5.9 10 4.4 5.4 2-Chlorotoluene NE 100 NE 0.91 J 1.2 0.84 J 1.4 Acetone 100 6000 NE 7.2 Benzene 1 1 NE 0.71 1.4 0.93 J 0.50 J 0.44 J 0.55 J Chlorobenzene 3 50 NE 3.7 13 16 14 3.2 5 Chloroethane 10 3,000 NE 2.7 0.94 J cis-1,2-Dichloroethene 5 70 NE 0.62 J 2.0 1.4 Methyl-tert-Butyl Ether NE 20 NE 0.41 J 0.86 J Tetrachloroethene 1 0.7 NE 0.88 J Trichloroethene 1 3 NE 0.78 J EPA RCRA Metals Method 6010B (ug/L) NCDENR SWSL 15A NCAC 2L Soild Waste GWP ST MW-1 MW-2 MW-3 MW-4 MW-5 MW-6 MW- 6A MW-7 MW- 7A MW-8 MW-9 MW-10 Barium 100 700 NE 138 579 656 69.6 288 784 398 724 192 245 101 Cadmium 1 2 NE 3.00 0.816 J 2.13 0.484 J Chromium 10 10 NE 7.32 J 1.66 J 10.5 1.85 J Mercury 0.2 1 NE 5.18 Silver 10 20 NE 3.72 J 2.62 J 2.22 J 3.37 J 4.39 J Notes: (1) ug/L = micrograms per liter (parts per billion) (2) mg/L = milligrams per liter (parts per million) (3) μS = microSiemens (4) 15A NCAC 2L = North Carolina Groundwater Quality Standards (5) 15A NCAC 2B = North Carolina Surface Water Quality Standards S&ME Project No. 1356-07-006 October 2015 - Detected Analytes in Groundwater Monitoring Wells Table 4 Lincoln County Owl's Den Landfill Lincolnton, North Carolina O M I T T E D F R O M G R O U N D W A T E R M O N I T O R I N G P L A N I N 2 0 0 8 EPA Volatile Organic Compounds Method 8260B (ug/L) 15A NCAC 2B SW-1 SW-2 SW-3 1,1- Dichloroethane 20,000 1,4 - Dichlorobenzene 100 1.2 Chlorobenzene 140 0.70 J cis-1,2-Dichloroethene 4,900 0.62 J EPA RCRA Metals Method 6010B (ug/L) Barium 200,000 221 226 321 Chromium 50 4.12 J Notes: (1) ug/L = micrograms per liter (parts per billion) (2) 15A NCAC 2B = North Carolina Surface Water Quality Standards for Freshwater (3) NE = No established standard (4) Bold indicates above 15A NCAC 2B (5) J = Analyte was detected between the method detection limit (MDL) and the method reporting limit (MRL) (6) Target analytes not shown were reported as below detection limits Table 5 October 2015 - Detected Analytes in Surface Water Samples Lincoln County Owl's Den Landfill Lincolnton, North Carolina S&ME Project No. 1356-07-006 EPA Volatile Organic Compounds Method 8260B (ug/L) 15A NCAC 2L Soild Waste GWP ST PSW-1 PSW-3 PSW-6 PSW-16 EPA RCRA Metals Method 6010B (ug/L) Barium 700 NE 46.9 111 74.2 42.3 Notes: NE = No established standard Table 6 October 2015 - Detected Analytes in Private Supply Wells Lincoln County Owl's Den Landfill Lincolnton, North Carolina S&ME Project No. 1356-07-006 No VOCs were detected in private supply wells during the October 2015 event Table 7 - Methane Gas Measurements Data Tracking Owl's Den Landfill (Permit #55-02) MMW-1 MMW-2 MMW-3 MMW-4 MMW-5 MMW-6 MMW-7 MMW-8 MMW-9 Apr-03 0 35 0 62 N/A N/A N/A N/A N/A Oct-03 63 38 31 56 N/A N/A N/A N/A N/A Apr-04 0 10 0 0 N/A N/A N/A N/A N/A Oct-04 0 8 10 38 N/A N/A N/A N/A N/A Apr-05 5 30 44 68 N/A N/A N/A N/A N/A Oct-05 36 30 18 58 N/A N/A N/A N/A N/A Apr-06 30 36 0 0 N/A N/A N/A N/A N/A Oct-06 38 38 0 58 N/A N/A N/A N/A N/A Apr-07 100 100 20 100 N/A N/A N/A N/A N/A Oct-07 6 12 20 55 N/A N/A N/A N/A N/A Apr-08 0.8 20 0 0 N/A N/A N/A N/A N/A Jul-08 14.4 42 73 0.2 10.6 0 0 0 0 Oct-08 0 15.4 36 12.6 6.2 3.1 0 0 0 Apr-09 8.5 20.6 46 0 6.6 0.2 0 0 0 Oct-09 16.5 17.7 59.3 61.3 4.2 0 0 0 0 Apr-10 N/A 27 N/A 0.2 8.5 0 0 0 0 Jun-10 N/A 27.6 N/A 68.4 9.9 1.5 0 0 0 Jul-10 N/A 19.6 N/A 66.9 9.4 1.7 0 0 0 Aug-10 N/A 13.8 N/A 48.4 6 0 0 0 0 Sep-10 N/A 13 N/A 0 5.3 0 0 0 0 Oct-10 N/A 10.7 N/A 58.5 4.3 0 0 0 0 Nov-10 N/A 10 N/A 6.8 4.1 0 0 0 0 Dec-10 N/A 4.6 N/A 0.1 3.7 0 0 0 0 Jan-11 N/A 12.6 N/A 41.2 3.4 0.2 0 0 0 Feb-11 N/A 13.9 N/A 36.7 4.4 0.2 0 0 0 Mar-11 N/A 15.3 N/A 11.1 4.8 0 0 0 0 Apr-11 N/A 13.1 N/A 0.2 6.2 0 0 0 0 May-11 N/A 15.2 N/A 9.6 3.4 0 0 0 0 Jun-11 N/A 15.1 N/A 48.7 6.3 0 0 0 0 Jul-11 N/A 17.2 N/A 42 9 0 0 0 0 Aug-11 N/A 18.2 N/A 0 5.2 0 0 0 0 Sep-11 N/A 15.5 N/A 66.5 3.7 0 0 0 0 Oct-11 N/A 10.7 N/A 6.4 3.6 0 0 0 0 Nov-11 N/A 4.3 N/A 59.3 3.4 0 0 0 0 Dec-11 N/A 17.9 N/A 60.2 3.8 0.1 0 0 0 Jan-12 N/A 21.4 N/A 36.2 5.4 0 0 0 0 Feb-12 N/A 22.6 N/A 0 5.9 0 0 0 0 Mar-12 N/A 21.6 N/A 36.3 5.9 0 0 0 0 Apr-12 N/A 24.9 N/A 19.7 6.1 0 0 0 0 May-12 N/A 26.2 N/A 70.5 5.2 0.2 0 0 0 Jun-12 N/A 23.4 N/A 70.9 4.5 0 0 0 0 Jul-12 N/A 20.9 N/A 0 3.9 0 0 0 0 Aug-12 N/A 14.2 N/A 8.3 2.4 0 0 0 0 Percent Methane Gas by Date Well IdentificationDate Page 1 of 2 Table 7 - Methane Gas Measurements Data Tracking Owl's Den Landfill (Permit #55-02) MMW-1 MMW-2 MMW-3 MMW-4 MMW-5 MMW-6 MMW-7 MMW-8 MMW-9 Percent Methane Gas by Date Well IdentificationDate Sep-12 N/A 13.2 N/A 0.4 1.3 0 0 0 0 Oct-12 N/A 15.5 N/A 61.7 1.3 0 0 0 0 Nov-12 N/A 10.8 N/A 1.2 0.7 0 0 0 0 Dec-12 N/A 9.8 N/A 0 0.3 0 0 0 0.8 Jan-13 N/A 18.1 N/A 14.8 0.4 0 0 0 0 Feb-13 N/A 22.9 N/A 29.4 0.7 0 0 0 0 Mar-13 N/A 24.2 N/A 68.5 1 0 0 0 0 Apr-13 N/A 26.1 N/A 70.8 1.5 0 0 0 0 May-13 N/A 27.3 N/A 39.3 1.5 0 0 0 0 Jun-13 N/A 28.6 N/A 46.1 1.6 0 0 0 0 Jul-13 N/A 34.4 N/A 55.9 1.8 0 0 0 0 Aug-13 N/A 33.4 N/A 72.0 2.2 0 0 0 0 Sep-13 N/A 26.9 N/A 40.4 2.3 0 0 0 0 Oct-13 N/A 19.2 N/A 62.6 1.7 0 0 0 0 Nov-13 N/A 13 N/A 44.6 0.5 0 0 0 0 Dec-13 N/A 18.9 N/A 16.6 0.8 0 0 0 0 Jan-14 N/A 24.5 N/A 67.4 1.7 0 0 0 0 Feb-14 N/A 23.4 N/A 35.8 1.5 0 0 0 0 Mar-14 N/A 27.6 N/A 63.1 2.1 0 0 0 0 Apr-14 N/A 28.2 N/A 0 2.8 0 0 0 0 May-14 N/A 31.7 N/A 0.9 2.8 0 0 0 0 Jun-14 N/A 25.1 N/A 31.7 1.7 0 0 0 0 Jul-14 N/A 18.9 N/A 70.2 0.8 0 0 0 0 Aug-14 N/A 17.4 N/A 7.1 0.4 0 0 0 0 Sep-14 N/A 20.2 N/A 70.0 0.5 0 0 0 0 Oct-14 N/A 20.6 N/A 66.6 0.5 0 0 0 0 Nov-14 N/A 14.7 N/A 0 0.3 0 0 0 0 Dec-14 N/A 16.1 N/A 4.4 0.1 0 0 0 0 Jan-15 N/A 19.4 N/A 66.2 0.4 0 0 0 0 Feb-15 N/A 20.2 N/A 62.1 0.7 0 0 0 0 Mar-15 N/A 22.7 N/A 62.4 1.2 0 0 0 0 Apr-15 N/A 23.6 N/A 0 1.1 0 0 0 0 May-15 N/A 26.3 N/A 60 0.5 0 0 0 0 Jun-15 N/A 26.2 N/A 18.4 0.4 0 0 0 0 Jul-15 N/A 18.1 N/A 65.7 0.1 0 0 0 0 Aug-15 N/A 13.9 N/A 59.2 0.0 0 0 0 0 Sep-15 N/A 10.7 N/A 14.6 0.0 0 0 0 0 Oct-15 N/A 10.0 N/A 10.9 0.0 0 0 0 0 Notes: (1) Recorded measurements are in percent methane. (2) Methane monitoring wells 5 through 9 were installed during the 2008 assessment activities. (3) Methane monitoring wells 1 and 3 were removed from the monitoring plan following the 2008 assessment activities due to their close proximity to the edge of waste. (4) Highlighted data are above 100 percent of the lower explosive limit. (5) Lower explosive limit for methane is 5 percent. (6) Upper explosive limit for methane is 15 percent. (7) N/A = Not Available Page 2 of 2 Appendix III – Well Sampling Logs and Laboratory Reports Project Name: Owl's Den Landfill Project Location: Lincoln County, North Carolina Project Number: 1356-07-006 Well ID MW-1 Sampling Personnel J. Tayouga, N. Shuff Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location TOC Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/8/2015 Purging Equipment Total Voume (Gal)Time pH Temp (ºC)Conductance (µS) Initial 0 9:40 5.57 16.2 1.7 9:45 5.42 16.2 2.4 9:50 5.32 16.7 Final 4.1 9:55 5.37 16.4 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Method 8260 (3) 40 ml glass vials HCL RCRA Metals (1) 250 ml plastic bottles HNO3 Comments Lab 50 34 Disposable Teflon Bailer 10.24 31 28 Electronic Water Level Probe Approx. 70°F, sunny. 1.7 37.26 47.50 ENCO 8:55 Clear Disposable Teflon Bailer 10/9/2015 Project Name: Owl's Den Landfill Project Location: Lincoln County, North Carolina Project Number: 1356-07-006 Well ID MW-2 Sampling Personnel J. Tayouga, N. Shuff Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location TOC Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/8/2015 Purging Equipment Total Voume (Gal)Time pH Temp (ºC)Conductance (µS) Initial 0 11:46 6.56 17.3 2.8 11:47 6.64 17.1 5.6 11:50 Final 8.4 11:51 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Method 8260 (3) 40 ml glass vials HCL RCRA Metals (1) 250 ml plastic bottles HNO3 Comments Lab ENCO 9:50 Clear Disposable Teflon Bailer 17.10 Electric Water Level Probe Field Clean Typhoon Pump 10/9/2015 571 558 DRY @ 5 gallons Approx. 70°F, sunny. 23.40 2.8 40.50 Project Name: Owl's Den Landfill Project Location: Lincoln County, North Carolina Project Number: 1356-07-006 Well ID MW-3 Sampling Personnel J. Tayouga, N. Shuff Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location TOC Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)50.4 (well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 4/16/2015 Purging Equipment Total Voume (Gal)Time pH Temp (ºC)Conductance (µS) Initial 0 Final Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Comments Lab Electric Water Level Probe Approx. 70°F, sunny. 42.51 Project Name: Owl's Den Landfill Project Location: Lincoln County, North Carolina Project Number: 1356-07-006 Well ID MW-4 Sampling Personnel J. Tayouga, N. Shuff Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location TOC Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/8/2015 Purging Equipment Total Voume (Gal)Time pH Temp (ºC)Conductance (µS) Initial 0 13:18 6.71 20.2 2.6 13:20 6.75 17.5 5.2 13:23 6.68 17.2 Final 7.8 13:25 6.88 17.3 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Method 8260 (3) 40 ml glass vials HCL RCRA Metals (1) 250 ml plastic bottles HNO3 Comments Lab Field Cleaned Typhoon Pump 1447 Approx. 70°F, sunny. 2.6 40.96 16.14 57.10 Electric Water Level Probe 1461 1508 1416 ENCO 10:30 Clear Disposable Teflon Bailer 10/9/2015 Project Name: Owl's Den Landfill Project Location: Lincoln County, North Carolina Project Number: 1356-07-006 Well ID MW-5 Sampling Personnel J. Tayouga, N. Shuff Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location TOC Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/8/2015 Purging Equipment Total Voume (Gal)Time pH Temp (ºC)Conductance (µS) Initial 0 14:22 7.08 16.0 0.9 14:23 6.44 15.2 1.8 14:24 6.30 14.8 Final 2.7 14:25 6.15 14.7 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Method 8260 (3) 40 ml glass vials HCL RCRA Metals (1) 250 ml plastic bottles HNO3 Comments Lab Disposable Teflon Bailer 66 Approx. 70°F, sunny. 0.9 27.72 5.48 33.20 Electric Water Level Probe 67 71 71 ENCO 10:55 Disposable Teflon Bailer Clear 10/9/2015 Project Name: Owl's Den Landfill Project Location: Lincoln County, North Carolina Project Number: 1356-07-006 Well ID MW-6 Sampling Personnel J. Tayouga, N. Shuff Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location TOC Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/8/2015 Purging Equipment Total Voume (Gal)Time pH Temp (ºC)Conductance (µS) Initial 0 13:40 6.94 16.3 1.2 13:43 6.80 16.2 2.4 13:46 6.75 15.9 Final 3.6 13:49 6.76 15.9 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Method 8260 (3) 40 ml glass vials HCL RCRA Metals (1) 250 ml plastic bottles HNO3 Comments Lab Disposable Teflon Bailer 832 Approx. 70°F, sunny. 1.2 16.91 7.20 24.11 Electric Water Level Probe 1041 799 822 ENCO 10:40 Disposable Teflon Bailer Clear 10/9/2015 Project Name: Owl's Den Landfill Project Location: Lincoln County, North Carolina Project Number: 1356-07-006 Well ID MW-6A Sampling Personnel J. Tayouga, N. Shuff Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location TOC Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/8/2015 Purging Equipment Total Voume (Gal)Time pH Temp (ºC)Conductance (µS) Initial 0 13:50 7.22 16.1 6.5 13:54 7.45 15.7 13.0 13:57 7.40 16.1 Final 19.5 14:00 7.19 15.8 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Method 8260 (3) 40 ml glass vials HCL RCRA Metals (1) 250 ml plastic bottles HNO3 Comments Lab Field Cleaned Whale Pump 877 Approx. 70°F, sunny. 6.5 18.60 39.84 58.44 Electric Water Level Probe 654 576 725 ENCO 10:45 Clear Disposable Teflon Bailer 10/9/2015 Project Name: Owl's Den Landfill Project Location: Lincoln County, North Carolina Project Number: 1356-07-006 Well ID MW-7 Sampling Personnel J. Tayouga, N. Shuff Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location TOC Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/8/2015 Purging Equipment Total Voume (Gal)Time pH Temp (ºC)Conductance (µS) Initial 0 11:40 6.69 17.5 1.0 11:43 7.09 17.3 2.0 11:46 6.90 17.2 Final 3.0 11:48 7.11 17.0 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Method 8260 (3) 40 ml glass vials HCL RCRA Metals (1) 250 ml plastic bottles HNO3 Comments Lab Disposable Teflon Bailer 411 Approx. 70°F, sunny. 1.0 22 5.97 27.97 Electric Water Level Probe 420 411 414 ENCO Broken hinge 9:45 Disposable Teflon Bailer Clear 10/9/2015 Project Name: Owl's Den Landfill Project Location: Lincoln County, North Carolina Project Number: 1356-07-006 Well ID MW-7A Sampling Personnel J. Tayouga, N. Shuff Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location TOC Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/8/2015 Purging Equipment Total Voume (Gal)Time pH Temp (ºC)Conductance (µS) Initial 0 12:00 6.48 17.7 4.7 12:05 6.00 17.2 9.4 12:11 6.40 17.3 Final 14.1 12:16 6.46 17.3 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Method 8260 (3) 40 ml glass vials HCL RCRA Metals (1) 250 ml plastic bottles HNO3 Comments Lab Approx. 70°F, sunny. 633 576 606 4.7 25.85 54.30 28.45 Electric Water Level Probe Field Cleaned Typhoon Pump 606 ENCO 9:40 Disposable Teflon Bailer Slightly turbid 10/9/2015 Project Name: Owl's Den Landfill Assessment Project Location: Lincoln County, North Carolina Project Number: 1356-07-006 Well ID MW-8 Sampling Personnel J. Tayouga, N. Shuff Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location TOC Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/8/2015 Purging Equipment Total Voume (Gal)Time pH Temp (ºC)Conductance (µS) Initial 0 10:35 5.65 15.4 1.2 10:38 5.69 14.9 2.4 10:41 5.69 14.7 Final 3.6 10:46 5.68 14.5 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Method 8260 (3) 40 ml glass vials HCL RCRA Metals (1) 250 ml plastic bottles HNO3 Comments Lab 51 Approx. 70°F, sunny. 1.2 49.21 Electronic Water Level Probe 56.80 7.59 Disposable Teflon Bailer 48 47 48 ENCO 9:20 Clear, some floating solids present Disposable Teflon Bailer 10/9/2015 Project Name: Owl's Den Landfill Assessment Project Location: Lincoln County, North Carolina Project Number: 1356-07-006 Well ID MW-9 Sampling Personnel J. Tayouga, N. Shuff Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location TOC Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/8/2015 Purging Equipment Total Voume (Gal)Time pH Temp (ºC)Conductance (µS) Initial 0 10:55 6.02 17.5 2.0 11:02 6.00 16.5 4.0 11:08 6.08 16.3 Final 6.0 11:14 6.13 16.8 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Method 8260 (3) 40 ml glass vials HCL RCRA Metals (1) 250 ml plastic bottles HNO3 Comments Lab Clear Disposable Teflon Bailer Approx. 70°F, sunny. ENCO 129 118 125 2.0 64.28 122 9:25 Electronic Water Level Probe Disposable Teflon Bailer 10/9/2015 51.95 12.33 Project Name: Owl's Den Landfill Assessment Project Location: Lincoln County, North Carolina Project Number: 1356-07-006 Well ID MW-10 Sampling Personnel J. Tayouga, N. Shuff Weather Conditions Unusual Site Conditions Water Level Data Measuring Point Location TOC Well Casing Volume Depth to Water (ft) Depth to Base of Well (ft)(well casing volume = water column*0.164) Water Column (ft) Equipment Used to Measure Depths Well Purging Data Date 10/8/2015 Purging Equipment Total Voume (Gal)Time pH Temp (ºC)Conductance (µS) Initial 0 10:08 5.80 16.5 1.1 10:11 5.83 16.2 2.2 10:14 5.86 16.3 Final 3.3 10:17 5.88 16.2 Well Sampling Data Sampling Date Sampling Time Sampling Equipment Sample Observations Analytical Data Method Container Type and No.Preservation Method 8260 (3) 40 ml glass vials HCL RCRA Metals (1) 250 ml plastic bottles HNO3 Comments Lab 32 Approx. 70°F, sunny. 1.1 44.26 Electronic Water Level Probe 50.96 6.70 Disposable Teflon Bailer 30 30 30 ENCO 9:10 Clear Disposable Teflon Bailer 10/9/2015