8106_DukeRogers_Oct2015_2ndSemiAnnual_DIN26432_20160125

573 Duke Power Road Mooresboro, NC
28114
Coal Combustion Products (CCP) Landfill
Permit No. 8106
Semiannual Groundwater Monitoring Report
October 2015 Sampling Event
Cliffside Steam Station
January 25, 2016
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Cliffside Steam Station, CCP Landfill, Phase I, Permit No.8106 October 2015 Sampling Event Contents

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Contents
Page
Section 1 – Background ................................................................................................................ 1
Section 2 – Methods ..................................................................................................................... 3
2.1 Sampling and Analysis Methods .................................................................................... 3
2.2 Statement of Work .......................................................................................................... 3
Section 3 - Results ........................................................................................................................ 5
3.1 Site Groundwater Flow ................................................................................................... 5
3.2 Analytical Results ........................................................................................................... 5

Figures
1. Site Location Map
2. Sample Locations
3. Generalized Groundwater Surface Contours – October 27, 2015
Tables
1. Well Construction Information
2. Groundwater Flow Velocities – October 27, 2015
3. Field Data Parameters
4. Groundwater Field and Analytical Results
5. Field and Analytical Results that Equal or Exceed 15A NCAC 2L Groundwater Quality
Standards
6. Surface Water Field and Analytical Results
7. Leachate Field and Analytical Results
Appendices
Appendix A – Field Sampling Forms
Appendix B – Laboratory Report and Chain-of-Custody Forms
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Cliffside Steam Station, CCP Landfill, Phase I, Permit No.8106 October 2015 Sampling Event Section 1 – Background

1
Section 1 – Background
Cliffside Steam Station is located in Rutherford and Cleveland Counties near Cliffside, North
Carolina. The station is owned and operated by Duke Energy Carolinas, LLC (Duke Energy)
and generates electricity by combustion of coal. The Coal Combustion Products (CCP) Landfill,
Phase I, was constructed with an engineered liner system and permitted to receive fly ash,
bottom ash, boiler slag, mill rejects, flue gas desulfurization sludge, gypsum, leachate basin
sludge, non-hazardous sandblast material, limestone, ball mill rejects, coal, carbon, sulfur
pellets, cation and anion resins, sediment from sumps, and cooling tower sludge under North
Carolina Department of Environmental Quality (NCDEQ) Solid Waste Permit No. 8106. Waste
was first placed into the landfill on October 24, 2010.
The CCP landfill is located southwest of the Cliffside Steam Station on Duke Energy property
and is situated completely within Rutherford County. The CCP landfill is northeast of the
intersection of Old U.S. Highway 221A and Ballenger Road (Figure 1). Phase I of the CCP
landfill has a footprint of approximately 23 acres. A Permit to Construct has been issued for
Phase II of the CCP landfill, and construction commenced in February 2015. Phase II will have
a footprint of approximately 15 acres and will be north of Phase I.
The monitoring system at the landfill consists of nine groundwater monitoring wells, two surface
water sample locations, and one leachate sampling location as listed below.

Monitoring Wells: CCPMW-1S CCPMW-1D
CCPMW-2S
CCPMW-2D CCPMW-3S
CCPMW-3D
CCPTW-1S CCPTW-1D
CCPTW-2
Surface Water: CCPSW-1
CCPSW-2
Leachate Sample: CCPLeachate

The groundwater monitoring wells, surface water sample locations, and leachate sample
locations are shown on Figure 2. Wells with a “D” designation (e.g., CCPMW-1D) are deep wells
that were installed with the well screen below auger refusal. Wells with an “S” designation or no
designation (e.g., CCPTW-2) are shallow wells that were installed with the well screen above
auger refusal. Well construction information is presented in Table 1. The leachate sample is
collected at the inlet to the leachate basin instead of the sampling port next to the landfill. The
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Cliffside Steam Station, CCP Landfill, Phase I, Permit No.8106 October 2015 Sampling Event Section 1 – Background

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sample port at the edge of the landfill was getting clogged with silt between sampling events.
There is not a good location to flush the sampling port out so it was decided to collect a sample
where the leachate enters the leachate basin. The inlet to the leachate basin is high on the bank
so the sample represents the leachate entering the concrete basin. The leachate basin is
located on the southeast side of the landfill.

As is typical in the Piedmont region, groundwater at the landfill site occurs within the residuum,
saprolite, partially weathered rock, and fractured bedrock. Groundwater generally flows from
regions of higher topography to regions of lower topography. The highest topographic area at
the landfill site is along the western edge of the landfill. Monitoring wells CCPMW-1S and
CCPMW-1D are considered by the Water Quality Monitoring Plan as background wells for the
landfill.1

Two drainage features are located in close proximity to the CCP landfill: one to the northwest
and one to the southeast. Based on the generalized groundwater surface contours developed
using the groundwater elevations measured in the shallow wells (Figure 3), the expected
groundwater discharge area for the landfill is to Suck Creek, located southeast of the landfill.
Suck Creek flows to the north, to the Broad River.

1 Duke Energy Cliffside CCP Landfill Water Quality Monitoring Plan, December 2011.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Cliffside Steam Station, CCP Landfill, Phase I, Permit No.8106 October 2015 Sampling Event Section 2 – Methods

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Section 2 – Methods
2.1 Sampling and Analysis Methods
Groundwater, surface water, and leachate sampling, as well as documentation of sampling
activities were performed by Duke Energy personnel (Duke Energy Carolinas Field Certification
#5193). Copies of the field sampling forms are included in Appendix A. The parameters and
constituents reported were analyzed by Duke Energy Analytical Laboratory (North Carolina
Laboratory Certification #248).
Samples were analyzed for the following constituents:2
 Barium, boron, copper, iron, manganese, silver, and zinc using U.S. Environmental
Protection Agency (EPA) Method 200.7
 Arsenic, cadmium, chromium, lead, nickel, and selenium using EPA Method 200.8
 Mercury using EPA Method 245.1
 Chloride, fluoride, nitrate as nitrogen, and sulfate using EPA Method 300.0
 Total dissolved solids using Standard Method (SM) 2540C
Surface water sample locations CCPSW-1 and CCPSW-2 were also field filtered using a 0.45
micron in-line filter and dissolved analysis performed for the following constituents:
 Barium, boron, chromium, copper, iron, manganese, nickel, and zinc using U.S.
Environmental Protection Agency (EPA) Method 200.7

 Arsenic, cadmium, lead, and silver using EPA Method 200.8
2.2 Statement of Work
HDR completed the following tasks:
 Received field sampling information provided by Duke Energy (performed by Duke
Energy personnel) for monitoring wells CCPMW-1S, CCPMW-1D, CCPMW-2S,
CCPMW-2D, CCPMW-3D, CCPTW-1S, CCPTW-1D, and CCPTW-2. A sample was not
collected from monitoring well CCPMW-3S due to insufficient water volume in the well.
Data were also received for surface water sample locations CCPSW-1 and CCPSW-2
and for leachate sampling location CCP-Leachate. The samples were collected on
October 27, 2015, and HDR received the data on November 11, 2015.
2 Samples were analyzed for constituents listed in Table 4.2 of the Water Quality Monitoring Plan
submitted for the Permit to Construct Application for Phase II of the Landfill. Duke Energy, Cliffside Steam Station, CCP Landfill-Phase II Permit to Construct Permit Application, CDM August 27, 2012.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Cliffside Steam Station, CCP Landfill, Phase I, Permit No.8106 October 2015 Sampling Event Section 2 – Methods

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 Reviewed the laboratory analytical results for samples. The Electronic Data Deliverable
(EDDs) provided by Duke Energy were adapted to conform to the format requirements of
the NCDEQ EDD template. In the EDDs, HDR added an italicized J data qualifier (J’) to
indicate a detected concentration that equals or is greater than the laboratory’s method
reporting limit (MRL), but less than the Solid Waste Section Limit3 (SWSL), and retained
the laboratory-supplied qualifier J to indicate values that equal or are greater than the
laboratory’s method detection limit (MDL) but are less than the MRL. A copy of the
original EDDs are retained in HDR’s files.
 Developed a generalized groundwater surface contour map using map data and
groundwater elevation data supplied by Duke Energy. Calculated groundwater flow
velocities are based on groundwater surface contours.
 Prepared and submitted this Semiannual Groundwater Monitoring Report to Duke
Energy.

3 The Solid Waste Section Limit (SWSL) is defined by NCDEQ as the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy. The SWSL is the
concentration below which reported results must be qualified as estimated. NCDEQ Division of Waste Management Memorandum dated February 23, 2007.
Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring Report Cliffside Steam Station, CCP Landfill, Phase I, Permit No.8106 October 2015 Sampling Event Section 3 - Results

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Section 3 - Results
3.1 Site Groundwater Flow
Generalized groundwater surface contours and groundwater flow direction arrows for the site
are shown on Figure 3. These contours were developed using the measured groundwater
elevations in the shallow wells on the date of sampling. Calculated groundwater flow velocities
are presented on Table 2.
Groundwater at the site generally flows from the northwest near CCPMW-1S to the southeast
toward Suck Creek.
3.2 Analytical Results
A summary of the field data is presented in Table 3.
The groundwater sampling field and analytical results are summarized in Table 4. The
groundwater analytical results for the semiannual constituents are compared to the groundwater
standards found in Title 15A NCAC 02L .0202 (g) (2L Standards). Concentrations with values
that attain or exceed the 2L Standards are noted in Table 4 by bold font. A summary of the
groundwater analytical results that attain or exceed the 2L Standards and a preliminary analysis
of the cause and significance of the exceedances are presented in Table 5.
Surface water sample locations CCPSW-1 and CCPSW-2 are located on Suck Creek. As a
result, the field and analytical results for these two locations are compared to Title 15A NCAC
Subchapter 2B Standards (2B Standards) for Class WS-IV surface water. The field and
analytical results for surface water sampling are summarized in Table 6.
The MDL was greater than the respective 2B Standard for silver. The MDL for silver was below
the corresponding SWSL as required in the February 23, 2007, NCDEQ memo. This constituent
was not detected above the MDL in the analyzed samples and is not considered to exceed the
2B Standard.
The field and analytical results for leachate sampling are summarized in Table 7.
Concentrations with values that equal or are greater than the SWSLs are noted in Tables 4, 6,
and 7 by gray-shaded cells.
Select samples were diluted, as is normal laboratory practice, to bring samples within the
calibrated range of the analysis. Specifics regarding the samples that were diluted, including the
dilution factor, are reported in the EDD.
The laboratory report and chain-of-custody forms can be found in Appendix B.

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-
2
S

8
0
5
80
4
53
.
3

0
.
0
2
5
7
2

0
.
4
1
1

0
.
2
5
9

0
.
0
4
0
8
1
CC
P
M
W
-
3
S

8
0
0
79
8
37
.
7

0
.
0
6
0
2
8

0
.
4
1
1

0
.
2
5
9

0
.
0
9
5
6
6
CC
P
T
W
-
1
S

8
1
5
81
0
81
2
.
0

0
.
0
0
6
1
6

0
.
4
1
1

0
.
2
5
9

0
.
0
0
9
7
7
CC
P
T
W
-
2

8
0
5
80
0
30
3
.
8

0
.
0
1
6
4
6

0
.
4
1
1

0
.
2
5
9

0
.
0
2
6
1
2
No
t
e
s
:
1
.

L
i
n
e
a
r

d
i
s
t
a
n
c
e

m
e
a
s
u
r
e
d

t
h
r
o
u
g
h

m
o
n
i
t
o
r
i
n
g

w
e
l
l
s

i
s

g
e
n
e
r
a
l
l
y

p
e
r
p
e
n
d
i
c
u
l
a
r

t
o

g
r
o
u
n
d
w
a
t
e
r

c
o
n
t
o
u
r
s
.
2
.

A
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l

l
o
c
a
t
i
o
n
s

w
h
e
r
e

d
o
w
n
g
r
a
d
i
e
n
t

c
o
n
t
o
u
r
s

a
r
e

n
o
t

p
r
e
s
e
n
t
,

t
h
e

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

a
t

t
h
e

m
o
n
i
t
o
r
i
n
g

w
e
l
l

i
s

u
s
e
d

a
s

t
h
e

d
o
w
n
g
r
a
d
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n
.
3
.

A
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l

l
o
c
a
t
i
o
n
s

w
h
e
r
e

u
p
g
r
a
d
i
e
n
t

c
o
n
t
o
u
r
s

a
r
e

n
o
t

p
r
e
s
e
n
t
,

t
h
e

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

a
t

t
h
e

m
o
n
i
t
o
r
i
n
g

w
e
l
l

i
s

u
s
e
d

a
s

t
h
e

u
p
g
r
a
d
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n
.
4
.

M
o
n
i
t
o
r
i
n
g

w
e
l
l
s

a
r
e

n
o
t

l
i
s
t
e
d

w
h
e
r
e

i
n
s
u
f
f
i
c
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

c
o
n
t
o
u
r

i
n
f
o
r
m
a
t
i
o
n

i
s

a
v
a
i
l
a
b
l
e

t
o

c
a
l
c
u
l
a
t
e

v
e
l
o
c
i
t
y
.
5
.

H
y
d
r
a
u
l
i
c

g
r
a
d
i
e
n
t

i
s

a
p
p
r
o
x
i
m
a
t
e
.
6
.

H
y
d
r
a
u
l
i
c

c
o
n
d
u
c
t
i
v
i
t
y

p
r
e
s
e
n
t
e
d

i
s

t
h
e

g
e
o
m
e
t
r
i
c

m
e
a
n

o
f

t
h
e

c
o
n
d
u
c
t
i
v
i
t
y

d
a
t
a

f
o
r

t
h
e

a
l
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e

h
y
d
r
o
s
t
r
a
t
i
g
r
a
p
h
i
c

l
a
y
e
r

i
n

t
h
e

H
D
R

C
o
n
d
u
c
t
i
v
i
t
y

D
a
t
a
b
a
s
e

(
u
n
p
u
b
l
i
s
h
e
d

d
a
t
a

f
r
o
m

C
a
r
o
l
i
n
a

s
i
t
e
s

w
i
t
h

f
o
l
i
a
t
e
d
/
l
a
y
e
r
e
d

b
e
d
r
o
c
k
)
.
7
.

E
f
f
e
c
t
i
v
e

p
o
r
o
s
i
t
y

p
r
e
s
e
n
t
e
d

i
s

t
h
e

m
e
a
n

v
a
l
u
e

o
f

t
h
e

a
l
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e

h
y
d
r
o
s
t
r
a
t
i
g
r
a
p
h
i
c

l
a
y
e
r

e
s
t
i
m
a
t
e
d

f
r
o
m

s
o
i
l

t
e
s
t
i
n
g

u
s
i
n
g

F
e
t
t
e
r
/
B
e
a
r

D
i
a
g
r
a
m
s
.

8
.

H
y
d
r
a
u
l
i
c

g
r
a
d
i
e
n
t
s

a
n
d

g
r
o
u
n
d
w
a
t
e
r

v
e
l
o
c
i
t
i
e
s

c
a
l
c
u
l
a
t
e
d

u
s
i
n
g

g
r
o
u
n
d
w
a
t
e
r

d
e
p
t
h

m
e
a
s
u
r
e
d

o
n

O
c
t
o
b
e
r

2
7
,

2
0
1
5
.
Ef
f
e
c
t
i
v
e

Po
r
o
s
i
t
y

(%
/
1
0
0
)
Groundwater Velocity (ft/day)
We
l
l

I
D

U
p
g
r
a
d
i
e
n
t

Gr
o
u
n
d
w
a
t
e
r

Co
n
t
o
u
r

El
e
v
a
t
i
o
n
(f
t
)
D
o
w
n
g
r
a
d
i
e
n
t

Gr
o
u
n
d
w
a
t
e
r

Co
n
t
o
u
r

El
e
v
a
t
i
o
n
(f
t
)
Li
n
e
a
r

Di
s
t
a
n
c
e

Be
t
w
e
e
n

Co
n
t
o
u
r
s

th
r
o
u
g
h

W
e
l
l
(f
t
)
Hy
d
r
a
u
l
i
c

Gr
a
d
i
e
n
t

(f
t
/
f
t
)
Hy
d
r
a
u
l
i
c

Co
n
d
u
c
t
i
v
i
t
y

(f
t
/
d
a
y
)
Page 1 of 1
Ta
b
l
e

3

-
-

F
i
e
l
d

D
a
t
a

P
a
r
a
m
e
t
e
r
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C
/
C
l
i
f
f
s
i
d
e

S
t
e
a
m

S
t
a
t
i
o
n
C
C
P

L
a
n
d
f
i
l
l
,

P
h
a
s
e

I

-
-

P
e
r
m
i
t

N
o
.

8
1
0
6
10
/
2
7
/
2
0
1
5

C
C
P
M
W
-
1
S

4
2
.
2
4

3
8
.
0
1

8
3
7
.
5
7

N
o
r
m
a
l

N
o
n
e

E
O
P

N
/
A
0.
6
9

0
.
3
7

N
/
A
14
.
9
6

2
3
5.3

1
9
.
1

3
8
6

9
.
1
8
10
/
2
7
/
2
0
1
5

C
C
P
M
W
-
1
D

5
6
.
7
0

3
9
.
2
7

8
3
6
.
6
2

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A
2.
8
4

9
.
0
0

N
O

1
5
.
2
6

5
5
5.6

2
.
1

3
9
7

7
.
4
0
10
/
2
7
/
2
0
1
5

C
C
P
M
W
-
2
S

4
4
.
0
7

3
8
.
6
1

8
0
3
.
6
3

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A
0.
8
9

3
.
0
0

N
O

1
5
.
1
3

3
6
5.2

4
.
3

4
1
9

8
.
0
2
10
/
2
7
/
2
0
1
5

C
C
P
M
W
-
2
D

7
2
.
4
7

4
0
.
2
7

8
0
2
.
1
1

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A
5.
2
5

1
1
.
2
5

N
O

1
5
.
4
7

1
3
2
9.2

1
.
7

2
9
9

3
.
6
5
10
/
2
7
/
2
0
1
5

C
C
P
M
W
-
3
S

1
5
.
0
2

1
3
.
8
3

7
9
7
.
7
3

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A
0.
1
9

N
S

N
S

N
S
NS
NS

N
S

N
S

N
S
10
/
2
7
/
2
0
1
5

C
C
P
M
W
-
3
D

3
5
.
1
9

1
4
.
8
8

7
9
6
.
8
6

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A
3.
3
1

1
0
.
5
0

N
O

1
5
.
8
7

7
3
5.3

1
.
1

4
1
7

5
.
6
5
10
/
2
7
/
2
0
1
5

C
C
P
T
W
-
1
S

3
6
.
7
8

2
6
.
9
5

8
1
1
.
9
7

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A
1.
6
0

5
.
2
5

N
O

1
6
.
7
4

4
7
5.2

1
.
5

4
3
2

5
.
7
5
10
/
2
7
/
2
0
1
5

C
C
P
T
W
-
1
D

6
8
.
2
3

2
8
.
1
7

8
1
0
.
3
6

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A
6.
5
3

8
.
7
5

N
O

1
6
.
4
1

2
6
6
7.5

1
.
7

2
9
4

1
1
.
8
3
10
/
2
7
/
2
0
1
5

C
C
P
T
W
-
2

4
7
.
6
3

4
0
.
8
0

8
0
1
.
3
8

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A
1.
1
1

3
.
7
5

N
O

1
5
.
9
5

4
5
5.1

5
.
0

4
0
5

6
.
8
7
10
/
2
7
/
2
0
1
5

C
C
P
S
W
-
1

N
/
A
N/
A
N/
A
No
r
m
a
l

N
/
A
N/
A
N/
A
N/
A
N/
A
N/
A
12
.
7
1

4
6
6.7

5
.
7

3
4
6

8
.
6
6
10
/
2
7
/
2
0
1
5

C
C
P
S
W
-
2

N
/
A
N/
A
N/
A
No
r
m
a
l

N
/
A
N/
A
N/
A
N/
A
N/
A
N/
A
12
.
7
7

4
4
6.5

1
1
.
3

3
0
9

8
.
5
3
10
/
2
7
/
2
0
1
5

C
C
P
-
L
E
A
C
H
A
T
E

N
/
A
N/
A
N/
A
No
r
m
a
l

N
/
A
N/
A
N/
A
N/
A
N/
A
N/
A
18
.
4
4

2
9
,
3
6
9

4
.
6

3
2
.
2

3
4
3

7
.
3
9
No
t
e
s
:

1
.

P
u
r
g
e

M
e
t
h
o
d
s
;

L
F
=
L
o
w

F
l
o
w
,

C
P
=
C
o
n
v
e
n
t
i
o
n
a
l

P
u
r
g
e

(
3
-
5

w
e
l
l

v
o
l
u
m
e
s
)
,

N
P
=
N
o

P
u
r
g
e

(
H
y
d
r
a
S
l
e
e
v
e
)
,

E
O
P
=
E
q
u
i
p
m
e
n
t

O
n
l
y

P
u
r
g
e
.

A
v
e
r
a
g
e

p
u
m
p

r
a
t
e

a
p
p
l
i
c
a
b
l
e

t
o

L
F

p
u
r
g
i
n
g

o
n
l
y
.

2
.

F
i
e
l
d

s
a
m
p
l
i
n
g

p
e
r
f
o
r
m
e
d

b
y

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

p
e
r
s
o
n
n
e
l
.

3
.

E
V
A
C

i
n
d
i
c
a
t
e
s

w
h
e
t
h
e
r

t
h
e

w
a
t
e
r

l
e
v
e
l

i
n

t
h
e

w
e
l
l

w
a
s

d
r
a
w
n

d
o
w
n

t
o

t
h
e

l
e
v
e
l

o
f

t
h
e

p
u
m
p

d
u
r
i
n
g

p
u
r
g
i
n
g
.

4
.

µ
Լ /c
m

i
n
d
i
c
a
t
e
s

m
i
c
r
o
m
h
o
s

p
e
r

c
e
n
t
i
m
e
t
e
r
.

5
.

S
U

i
n
d
i
c
a
t
e
s

S
t
a
n
d
a
r
d

U
n
i
t
s
.

6
.

N
T
U

i
n
d
i
c
a
t
e
s

N
e
p
h
e
l
o
m
e
t
r
i
c

T
u
r
b
i
d
i
t
y

U
n
i
t
s
.

7
.

m
V
-
N
H
E

i
n
d
i
c
a
t
e
s

m
i
l
l
i
v
o
l
t
s
-
N
o
r
m
a
l

H
y
d
r
o
g
e
n

E
l
e
c
t
r
o
d
e
.

8
.

m
g
/
L

i
n
d
i
c
a
t
e
s

m
i
l
l
i
g
r
a
m
s

p
e
r

l
i
t
e
r
.

9
.

N
/
A

i
n
d
i
c
a
t
e
s

n
o
t

a
p
p
l
i
c
a
b
l
e
.
10
.

N
S

i
n
d
i
c
a
t
e
s

n
o

s
a
m
p
l
e

w
a
s

c
o
l
l
e
c
t
e
d
.

A

s
a
m
p
l
e

c
o
u
l
d

n
o
t

b
e

c
o
l
l
e
c
t
e
d

f
r
o
m

C
C
P
M
W
-
3
S

d
u
e

t
o

i
n
s
u
f
f
i
c
i
e
n
t

w
a
t
e
r

v
o
l
u
m
e

i
n

t
h
e

w
e
l
l
.

11
.

I
n
f
o
r
m
a
t
i
o
n

p
r
o
v
i
d
e
d

b
y

T
i
m

H
u
n
s
u
c
k
e
r

o
f

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

o
n

N
o
v
e
m
b
e
r

1
1
,

2
0
1
5
.
AP
P
E
A
R
A
N
C
E
DA
T
E

S
A
M
P
L
E

I
D
WE
L
L
DE
P
T
H
(fe
e
t
)
DE
P
T
H

T
O
WA
T
E
R
(f
e
e
t
)
WA
T
E
R
EL
E
V
.
(f
e
e
t
)
DO (mg/L)
OD
O
R
PU
R
G
E
ME
T
H
O
D

AV
E
R
A
G
E
PU
M
P

R
A
T
E
(m
L
/
m
i
n
)
WE
L
L
VO
L
U
M
E
(g
a
l
)
EV
A
C
VO
L
U
M
E
(g
a
l
)
EV
A
C
(Y
E
S
/
N
O
)
TE
M
P
(d
e
g

C
)
SP
E
C
I
F
I
C
CO
N
D
U
C
T
A
N
C
E
(µ
Լ /c
m
)
pH
(S
U
)
TURBIDITY (NTU)ORP (mV-NHE) Page 1 of 1
Ta
b
l
e

4

-
-

G
r
o
u
n
d
w
a
t
e
r

F
i
e
l
d

a
n
d

A
n
a
l
y
t
i
c
a
l

R
e
s
u
l
t
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C
/
C
l
i
f
f
s
i
d
e

S
t
e
a
m

S
t
a
t
i
o
n
C
C
P

L
a
n
d
f
i
l
l
,

P
h
a
s
e

I

-
-

P
e
r
m
i
t

N
o
.

8
1
0
6
Fie
l
d

p
H
32
0

S
U

5
1
9
3
-
NE
6.5-8.5

6
.
5
-
8
.
5
*
Fie
l
d

S
p
e
c
i
f
i
c

C
o
n
d
u
c
t
i
v
i
t
y
32
3

µ
Լ /cm

5
1
9
3
-
NE

N
E

N
E
Te
m
p
e
r
a
t
u
r
e

3
2
5

°
C

5
1
9
3
-
NE

N
E

N
E
To
p

o
f

C
a
s
i
n
g
32
8

f
e
e
t
-
-
NE
NE NE
De
p
t
h

t
o

W
a
t
e
r
31
8

f
e
e
t
-
-
NE
NE NE
Wa
t
e
r

E
l
e
v
a
t
i
o
n
31
9

f
e
e
t
-
-
NE
NE NE
We
l
l

D
e
p
t
h
41
1

f
e
e
t
-
-
NE
NE NE
Ar
s
e
n
i
c
14

µ
g
/
L

2
4
8
0.1
9
7
J
0.
0
7
8
4
J
0.
1
1
4
J
0.9
6
7
J
0.0
9
9
4
J
0.0
7
8

1
0
10 10
Ba
r
i
u
m
15

µ
g
/
L

2
4
8
23
.
2
J '
17
.
9
J '
20
.
4
J '
7.6
2
J '
29
.
8
J '
0.
1

1
0
0

7
0
0

2
,
0
0
0
Bo
r
o
n

4
2
8

µ
g
/
L

2
4
8

5
.
6
7
J
6.
4
1
J
3.9
5
J
3.7
7
J
8.
1
J
3.
3

N
E
700 NE
Ca
d
m
i
u
m
34

µ
g
/
L

2
4
8
0.1
0
1

U

0
.
1
0
1

U

0
.
1
0
1

U

0
.
1
0
1

U
0.
1
0
1

U

0
.
1
0
1

1
2 5
Ch
l
o
r
i
d
e
45
5

µ
g
/
L

2
4
8
3,6
9
0
5,9
0
0
4,
7
1
0
4,
6
0
0
4,
9
2
0

2
2

N
E
250,000

2
5
0
,
0
0
0
*
Ch
r
o
m
i
u
m
51

µ
g
/
L

2
4
8
1.
2
7
J '
0.
4
7
J
0.
8
6
8
J
0.5
1
4
J
1.
7
J '
0.0
6
1

1
0

1
0

1
0
0
Co
p
p
e
r
54

µ
g
/
L

2
4
8
1

U
1

U
1

U
1

U
1

U

1
10
1,000

1
,
3
0
0
Flu
o
r
i
d
e
31
2

µ
g
/
L

2
4
8
55
.
3
J
56
.
3
J
71
.
1
J
92
.
2
J
65
.
1
J
17

2
,
0
0
0

2
,
0
0
0

4
,
0
0
0
Ir
o
n

3
4
0

µ
g
/
L

2
4
8
75
5
36
.
7
J '
10
8
J '
20
.
8
J '
4
J
1.
3

3
0
0
300 300*
Le
a
d
13
1

µ
g
/
L

2
4
8
0.5
1
6
J
0.0
6
5

U

0
.
1
0
3
J
0.0
6
5

U
0.
0
6
5

U

0
.
0
6
5

1
0
15 15
Ma
n
g
a
n
e
s
e
34
2

µ
g
/
L

2
4
8
43
J '
13
.
7
J '
10
.
2
J '
0.4
8
3
J
8.
8
J '
0.
2

5
0

5
0

5
0
*
Me
r
c
u
r
y

1
3
2

µ
g
/
L

2
4
8

0
.
0
1
J
0.0
0
7
J
0.0
2
J
0.0
1
J
0.
0
1
1
J
0.0
0
6

0
.
2
1 2
Nic
k
e
l
15
2

µ
g
/
L

2
4
8
0.7
7
2
J
1.2
J '
0.
4
2
7
J
0.1
9
4

U
0.
3
7
4
J
0.1
9
4

5
0
100 NE
Ni
t
r
a
t
e

a
s

N
i
t
r
o
g
e
n

3
0
3

µ
g
/
L

2
4
8
29
.
6
J '
1,7
0
0
J '
50
3
J '
95
6
J '
1,
5
4
0
J '
5.
4

1
0
,
0
0
0

1
0
,
0
0
0

1
0
,
0
0
0
Se
l
e
n
i
u
m

1
8
3

µ
g
/
L

2
4
8

0
.
0
9
2

U

0
.
0
9
2

U

0
.
0
9
2

U

0
.
1
4
7
J
0.
1
8
9
J
0.0
9
2

1
0
20 50
Si
l
v
e
r
18
4

µ
g
/
L

2
4
8
0.
7

U
0.7

U
0.
7

U
0.
7

U
0.
7

U

0
.
7

1
0
20 100*
Su
l
f
a
t
e
31
5

µ
g
/
L

2
4
8
73
8
J '
1,4
9
0
J '
41
4
J '
5,0
4
0
J '
12
,
7
0
0
J '
18

2
5
0
,
0
0
0

2
5
0
,
0
0
0

2
5
0
,
0
0
0
*
To
t
a
l

D
i
s
s
o
l
v
e
d

S
o
l
i
d
s
31
1

µ
g
/
L

2
4
8

2
9
,
0
0
0

3
6
,
0
0
0

3
4
,
0
0
0

9
1
,
0
0
0
47
,
0
0
0

1
6
,
7
0
0

N
E
500,000 500,000*
Zin
c
21
3

µ
g
/
L

2
4
8
3.5
1
J
2.6

U
2.
6

U
2.
6

U
2.
6

U

2
.
6

1
0
1,000 5,000*
No
t
e
s
:
1
.

C
o
n
c
e
n
t
r
a
t
i
o
n
s

p
r
e
s
e
n
t
e
d

i
n

m
i
c
r
o
g
r
a
m
s

p
e
r

l
i
t
e
r

(
µ
g
/
L
)
.
2
.

S
W
S

I
D

i
s

t
h
e

S
o
l
i
d

W
a
s
t
e

S
e
c
t
i
o
n

I
d
e
n
t
i
f
i
c
a
t
i
o
n

N
u
m
b
e
r
.
3
.

M
D
L

i
s

t
h
e

l
a
b
o
r
a
t
o
r
y

m
e
t
h
o
d

d
e
t
e
c
t
i
o
n

l
i
m
i
t
.

T
h
e

M
D
L

v
a
l
u
e
s

p
r
e
s
e
n
t
e
d

a
r
e

f
o
r

s
a
m
p
l
e
s

n
o
t

d
i
l
u
t
e
d

b
y

t
h
e

l
a
b
o
r
a
t
o
r
y

d
u
r
i
n
g

a
n
a
l
y
s
i
s
.

4
.

S
W
S
L

i
s

t
h
e

S
o
l
i
d

W
a
s
t
e

S
e
c
t
i
o
n

L
i
m
i
t
.

N
C
D
E
Q

d
e
f
i
n
e
s

t
h
e

S
W
S
L

a
s

t
h
e

l
o
w
e
s
t

a
m
o
u
n
t

o
f

a
n
a
l
y
t
e

i
n

a

s
a
m
p
l
e

t
h
a
t

c
a
n

b
e

q
u
a
n
t
i
t
a
t
i
v
e
l
y

d
e
t
e
r
m
i
n
e
d

w
i
t
h

s
u
i
t
a
b
l
e

p
r
e
c
i
s
i
o
n

a
n
d

a
c
c
u
r
a
c
y
.

5
.

1
5
A

N
C
A
C

2
L

S
t
a
n
d
a
r
d

r
e
f
e
r
s

t
o

C
l
a
s
s

G
A

S
t
a
n
d
a
r
d
s

a
s

f
o
u
n
d

i
n

1
5
A

N
C
A
C

0
2
L

.
0
2
0
2

G
r
o
u
n
d
w
a
t
e
r

Q
u
a
l
i
t
y

S
t
a
n
d
a
r
d
s
,

l
a
s
t

a
m
e
n
d
e
d

o
n

A
p
r
i
l

1
,

2
0
1
3
.

6
.

M
C
L

i
s

t
h
e

F
e
d
e
r
a
l

M
a
x
i
m
u
m

C
o
n
t
a
m
i
n
a
n
t

L
e
v
e
l

a
s

f
o
u
n
d

i
n

4
0

C
F
R
,

S
u
b
p
a
r
t

G
,

§
1
4
1
.
6
2
.
7
.

*

C
o
n
c
e
n
t
r
a
t
i
o
n

l
i
s
t
e
d

i
s

a

s
e
c
o
n
d
a
r
y

m
a
x
i
m
u
m

c
o
n
t
a
m
i
n
a
n
t

l
e
v
e
l

(
S
M
C
L
)
.

S
M
C
L
s

a
r
e

e
s
t
a
b
l
i
s
h
e
d

b
y

E
P
A

i
n

t
h
e

N
a
t
i
o
n
a
l

S
e
c
o
n
d
a
r
y

D
r
i
n
k
i
n
g

W
a
t
e
r

R
e
g
u
l
a
t
i
o
n
s
.
8
.

N
E

i
n
d
i
c
a
t
e
s

n
o
t

e
s
t
a
b
l
i
s
h
e
d
.

N
A

i
n
d
i
c
a
t
e
s

n
o
t

a
n
a
l
y
z
e
d
.

B
l
a
n
k

c
e
l
l
s

i
n
d
i
c
a
t
e

t
h
a
t

t
h
e
r
e

i
s

n
o

i
n
f
o
r
m
a
t
i
o
n

r
e
l
e
v
a
n
t

t
o

t
h
e

r
e
s
p
e
c
t
i
v
e

r
o
w
.
9
.

N
S

i
n
d
i
c
a
t
e
s

n
o

s
a
m
p
l
e

w
a
s

c
o
l
l
e
c
t
e
d
.

A

s
a
m
p
l
e

c
o
u
l
d

n
o
t

b
e

c
o
l
l
e
c
t
e
d

f
r
o
m

C
C
P
M
W
-
3
S

d
u
e

t
o

i
n
s
u
f
f
i
c
i
e
n
t

w
a
t
e
r

v
o
l
u
m
e

i
n

t
h
e

w
e
l
l
.

10
.

G
r
a
y
e
d

v
a
l
u
e
s

i
n
d
i
c
a
t
e

v
a
l
u
e
s

t
h
a
t

e
q
u
a
l

o
r

a
r
e

g
r
e
a
t
e
r

t
h
a
n

t
h
e

S
W
S
L
.
11
.

B
o
l
d

v
a
l
u
e
s

i
n
d
i
c
a
t
e

v
a
l
u
e
s

t
h
a
t

a
t
t
a
i
n

o
r

e
x
c
e
e
d

t
h
e

1
5
A

N
C
A
C

2
L

S
t
a
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Page 1 of 1

A
Appendix A
Field Sampling Forms

ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬/▬►0.0 0.0 ▬/▬►0.0
SS 349.9 ▬▬►350 357.3 ▬/▬►350
SS 74.3 ▬/▬►75 76.8 ▬/▬►75
SS ▬/▬►▬/▬►
B (7.00)7.10 ▬▬►7.02 7.09 ▬/▬►7.02
B (4.00)4.01 ▬▬►4.00 4.11 ▬/▬►4.00
B (10.00)10.05 ▬/▬►10.06 10.10 ▬/▬►10.06
20.09 20.17
pH Check B (7.00)▬▬►
Time:
SS (7.00)305 ▬▬►295 276 ▬/▬►295
SS (4.00)N/A ▬/▬►470 N/A ▬/▬►470
20.11 20.15
W 8.80 8.50
W 8.80 8.50
AW 8.81 ▬▬►8.80 8.57 ▬/▬►8.50
SS 54.1 ▬/▬►53.5 53.8 ▬/▬►53.5
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
FIELD SAMPLING CALIBRATION FORM
STUDY:CLIFFSIDE STEAM STATION - CCP LANDFILL GROUNDWATER MONITORING
DATE (s):October 27, 2015 SURFACE UNIT READER:LDC
OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW Steady rain, windy, 45 to 50 deg F.
COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:3825
ANALYZER MODEL#:MS5 66121
PROCEDURE #:HYDROLAB 3210.5 VALIDATED BY:
Calibration Date / Time 27-Oct-15 4:30 28-Oct-15 7:20
CALIBRATION BP (mmHg)751.3 CALIBRATION BP (mmHg)739.9
Parameter Calibration Results Calibration Results
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)
Instrument Zeroed Zero Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
pH
(units)
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Buffer Temp.Buffer Temp.
Buffer Temp.
Calibration Accepted Calibration Pass
ORP Temp.ORP Temp.
Calibration Pass
TURB
(ntu)Calibration Accepted Calibration Accepted
DO
(mg/L)Calibration Accepted
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 750.4 (mmHg)Ending BP 750.6
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬/▬►0.0 0.0 ▬/▬►0.0
SS 343.6 ▬▬►350 350.6 ▬/▬►350
SS 72.7 ▬/▬►75 73.3 ▬/▬►75
SS ▬/▬►▬/▬►
B (7.00)7.08 ▬▬►7.02 7.04 ▬/▬►7.02
B (4.00)4.03 ▬▬►4.00 4.05 ▬/▬►4.00
B (10.00)10.10 ▬/▬►10.06 10.10 ▬/▬►10.06
20.16 20.13
pH Check B (7.00)▬▬►
Time:
SS (7.00)290 ▬▬►295 289 ▬/▬►295
SS (4.00)N/A ▬/▬►470 N/A ▬/▬►470
20.06 20.10
W 8.80 8.50
W 8.80 8.50
AW 8.78 ▬▬►8.80 8.63 ▬/▬►8.50
SS 53.9 ▬/▬►54.5 52.9 ▬/▬►54.5
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
FIELD SAMPLING CALIBRATION FORM
STUDY:CLIFFSIDE STEAM STATION - CCP LANDFILL GROUNDWATER MONITORING
DATE (s):October 27, 2015 SURFACE UNIT READER:PSP
OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW Steady rain, windy, 45 to 50 deg F.
COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:S05042
ANALYZER MODEL#:MS5 66120
PROCEDURE #:HYDROLAB 3210.5 VALIDATED BY:
Calibration Date / Time 27-Oct-15 4:00 28-Oct-15 7:30
CALIBRATION BP (mmHg)751.3 CALIBRATION BP (mmHg)739.9
Parameter Calibration Results Calibration Results
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)
Instrument Zeroed Zero Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
pH
(units)
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Buffer Temp.Buffer Temp.
Buffer Temp.
Calibration Accepted Calibration Pass
ORP Temp.ORP Temp.
Calibration Pass
TURB
(ntu)Calibration Accepted Calibration Accepted
DO
(mg/L)Calibration Accepted
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 750.4 (mmHg)Ending BP 750.6
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
32.24 42.24
18 (psi)10 (sec)(sec)
(gal)
896 (ml)
495 (ml)
1391 (ml)=0.37 (gal)@
QC By:
DATE TIME
(mg/L)(NTU)(mV -NEH)
10/27/2015 0920
PURGE METHOD
Equip. Only Purge
DISCHARGERECHARGEPRESSURE 10
PUMP CONTROLLER SETTINGS
0.1631CONVERSION FACTOR
Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
0.69WELL VOLUME
FIELD CREW LDC, PSP
MONITORING WELL INFORMATION
2
N/A
PROCEDURE NO 3175.2DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
FOR EQUIPMENT PURGE ONLY SAMPLING
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID
PROJECT NAME CLIFFSIDE CCP LANDFILL
SAMPLING DATE(s)27-Oct-2015
40.13
41.24PUMP INTAKE DEPTH (ft TOC)42.24
TOC ELEV (ft msl)
GS ELEV (ft msl)
875.58
873.24
WELL/LOCATION NAME CCPMW-1S
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88
WELL DEPTH (ft TOC)
WELL DIAMETER (in)MIDDLE OF WETTED SCREEN (ft toc)
SCREEN INTERVAL (ft TOC)TO
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)38.01 WATER COLUMN (ft)4.23
EQUIPMENT INFORMATION
LEVEL METER SERIAL#26055 SAMPLING EQUIPMENT
TUBING DIAMETER (in)1/2 OD
QED T1200
WATER ELEVATION (ft msl)837.57
APPEARANCE
DETECTED ODOR None
Normal
INITIAL FLOW FINAL TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
14.96 23
(ft)(ml/min)(ft)(deg C)(umho/cm)(SU)
OXYGEN
Good Condition
Good Tag
WELL CASING
Below pump
WATER LEVEL RATE WATER LEVEL COND.
LDC
WELL CONDITION
PROTECTIVE CASING
WELL PAD
WELL TAG
Good Condition
Minor Cracks
5.26 19.1
Sample preservation verified to pH
(units)< 2.0
SAMPLING NOTES
ADDITIONAL WELL CONDITION NOTES
NA
Pump (Bladder) Volume
Tubing Volume
Total Purge Volume
386 9.18 N/A
EQUIPMENT PURGE ONLY SAMPLE CHLORINE
(mg/l)SAMPLE COLLECTED BY
38.01 300
51.70 56.70
22 (psi)14 (sec)(sec)
(gal)
2.84 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
9.00 LDC 10/27/2015 1005 N/A
3.00 NO 15.26 55 5.60 2.1 397 7.40
3.00 NO 15.30 54 5.45 2.5 399 7.35
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
3.00 NO 15.27 55 5.38 4.7 393
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
7.16
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)39.27 WATER COLUMN (ft)17.43 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)836.62 WELL VOLUME 2.84
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 11
26055 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)875.89 MIDDLE OF WETTED SCREEN (ft toc)54.20
SCREEN LENGTH (ft)5.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)56.70 GS ELEV (ft msl)873.33 PUMP INTAKE DEPTH (ft TOC)55.70
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)27-Oct-2015 WELL/LOCATION NAME CCPMW-1D
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
34.07 44.07
20 (psi)10 (sec)(sec)
(gal)
0.89 (gal)
@
QC By:
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)27-Oct-2015 WELL/LOCATION NAME CCPMW-2S
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)842.24 MIDDLE OF WETTED SCREEN (ft toc)41.34
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)44.07 GS ELEV (ft msl)840.26 PUMP INTAKE DEPTH (ft TOC)43.07
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26055 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)38.61 WATER COLUMN (ft)5.46 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)803.63 WELL VOLUME 0.89
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.00 NO 15.12 37 5.22 18.3 419
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
8.02
1.00 NO 15.13 36 5.24 4.3 419 8.02
1.00 NO 15.08 36 5.19 4.8 417 8.04
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
3.00 LDC 10/27/2015 0755 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
67.47 72.47
40 (psi)9 (sec)(sec)
(gal)
5.25 (gal)
@
QC By:
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)27-Oct-2015 WELL/LOCATION NAME CCPMW-2D
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)842.38 MIDDLE OF WETTED SCREEN (ft toc)69.97
SCREEN LENGTH (ft)5.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)72.47 GS ELEV (ft msl)840.17 PUMP INTAKE DEPTH (ft TOC)71.47
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
26055 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)40.27 WATER COLUMN (ft)32.20 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)802.11 WELL VOLUME 5.25
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
5.25 59.08 NO 15.41 154 9.72 1.9 270
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
2.46 2.18
1.80
2.00 62.08 NO 15.45 135 9.37 1.7 295 3.43 1.69
2.25 61.43 NO 15.44 140 9.45 2.0 277 3.57
1.75 NO 15.47 132 9.23 1.7 299 3.65
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
11.25 LDC 10/27/2015 0840 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
10.02 15.02
8 (psi)10 (sec)(sec)
(gal)
0.19 (gal)
@
QC By:
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)27-Oct-2015 WELL/LOCATION NAME CCPMW-3S
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)811.56 MIDDLE OF WETTED SCREEN (ft toc)14.43
SCREEN LENGTH (ft)5.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)15.02 GS ELEV (ft msl)810.56 PUMP INTAKE DEPTH (ft TOC)14.02
No sample - see note PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)13.83 WATER COLUMN (ft)1.19 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)797.73 WELL VOLUME 0.19
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
0.00 PSP 10/27/2015 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
Insufficient volume to sample. Would require 0.21 gallons to purge equipment volume
30.19 35.19
20 (psi)10 (sec)(sec)
(gal)
3.31 (gal)
@
QC By:
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)27-Oct-2015 WELL/LOCATION NAME CCPMW-3D
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)811.74 MIDDLE OF WETTED SCREEN (ft toc)32.69
SCREEN LENGTH (ft)5.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)35.19 GS ELEV (ft msl)810.47 PUMP INTAKE DEPTH (ft TOC)34.18
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)14.88 WATER COLUMN (ft)20.31 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)796.86 WELL VOLUME 3.31
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
3.50 NO 15.89 69 5.32 1.2 403
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
5.51
3.50 NO 15.87 73 5.33 1.1 417 5.65
3.50 NO 15.86 72 5.33 1.2 411 5.61
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
10.50 PSP 10/27/2015 1155 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
26.78 36.78
18 (psi)10 (sec)(sec)
(gal)
1.60 (gal)
@
QC By:
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)27-Oct-2015 WELL/LOCATION NAME CCPTW-1S
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)838.92 MIDDLE OF WETTED SCREEN (ft toc)31.87
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)36.78 GS ELEV (ft msl)836.81 PUMP INTAKE DEPTH (ft TOC)35.78
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)26.95 WATER COLUMN (ft)9.83 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)811.97 WELL VOLUME 1.60
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.75 NO 16.70 46 5.17 4.9 427
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
6.85
1.75 NO 16.74 47 5.21 1.5 432 5.75
1.75 NO 16.75 47 5.23 2.2 432 6.13
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
5.25 PSP 10/27/2015 0905 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
63.23 68.23
35 (psi)10 (sec)(sec)
(gal)
6.53 (gal)
@
QC By:
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)27-Oct-2015 WELL/LOCATION NAME CCPTW-1D
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)838.53 MIDDLE OF WETTED SCREEN (ft toc)65.73
SCREEN LENGTH (ft)5.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)68.23 GS ELEV (ft msl)836.41 PUMP INTAKE DEPTH (ft TOC)67.23
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)28.17 WATER COLUMN (ft)40.06 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)810.36 WELL VOLUME 6.53
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
6.75 65.70 NO 16.61 325 7.69 3.8 295
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
5.84 0.41
0.50 NO 16.27 383 7.56 8.0 289 0.58
0.75 NO 16.37 383 7.55 4.8 297 0.86
0.25 NO 16.41 266 7.52 1.7 294 11.83
0.50 NO 16.32 312 7.58 11.3 288 9.11
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
8.75 PSP 10/27/2015 1010 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
37.63 47.63
22 (psi)10 (sec)(sec)
(gal)
1.11 (gal)
@
QC By:
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)27-Oct-2015 WELL/LOCATION NAME CCPTW-2
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)842.18 MIDDLE OF WETTED SCREEN (ft toc)44.22
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)47.63 GS ELEV (ft msl)839.62 PUMP INTAKE DEPTH (ft TOC)46.63
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 20
26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)40.80 WATER COLUMN (ft)6.83 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)801.38 WELL VOLUME 1.11
(gal)
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.25 NO 15.94 44 4.91 4.6 403
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
7.05
1.25 NO 15.95 45 5.12 5.0 405 6.87
1.25 NO 15.96 44 5.05 4.2 397 7.05
CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
3.75 PSP 10/27/2015 0800 N/A
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
0.00 0.00
(psi)(sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)27-Oct-2015 WELL/LOCATION NAME CCPSW-1
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
Surface water location PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE
N/A SAMPLING EQUIPMENT GRAB PURGE METHOD
TUBING DIAMETER (in)No Purge
DETECTED ODOR CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
LDC 10/27/2015
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 12.71 46 6.67 5.7
1040
346 8.66
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
0.00 0.00
(psi)(sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)27-Oct-2015 WELL/LOCATION NAME CCPSW-2
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
Surface water location PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
DETECTED ODOR CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
PSP 10/27/2015
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 12.77 44 6.53 11.3
1250
309 8.53
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
0.00 0.00
(psi)(sec)(sec)
(gal)
(ft)=(in)@
QC By:
SITE NAME CLIFFSIDE STEAM STATION PERMIT #81-06 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PROJECT NAME CLIFFSIDE CCP LANDFILL FIELD CREW LDC, PSP
SAMPLING DATE(s)27-Oct-2015 WELL/LOCATION NAME CCP-LEACHATE
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE
N/A SAMPLING EQUIPMENT GRAB PURGE METHOD
TUBING DIAMETER (in)No Purge
DETECTED ODOR CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
TIME
LDC 10/27/2015
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 18.44 29369 4.60 32.2
1105
343 7.39
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
SAMPLING NOTES
PERMIT #
CCPMW-1S CCPMW-1D CCPMW-2S CCPMW-2D CCPMW-3S CCPMW-3D CCPTW-1S CCPTW-1D CCPTW-2 CCPSW-1 CCPSW-2 LEACHATE
YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES N/A N/A N/A
YES YES YES YES YES YES YES YES YES N/A N/A N/A
YES YES YES YES YES YES YES YES YES N/A N/A N/A
YES YES YES YES YES YES YES YES N/A N/A N/A
YES
YES YES YES YES YES YES YES YES YES N/A N/A N/A
YES YES YES YES YES YES YES YES YES N/A N/A N/A
N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES YES YES YES YES YES YES YES YES N/A N/A N/A
Lacks required information - Total well depth
Lacks required information - Depth to screen
Lacks required information - Non potable tag
NOTE:
Lacks required information - Completion date
FLUSH MOUNT WELLS
Vault in good condition
Water inside vault
Vault bolt holes broken or stripped
Bolts stripped
Vault lid cracked or broken
WELL ID TAGS
Well tag in good condition
Well tag missing
Well tag damaged / illegible
Lacks required information - Driller Reg #
Replaced damaged well cap
Fire ants around concrete pad
WELL PROTECTIVE CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
Broken hinge on protective lid
Wasp nest inside protective casing
Ants inside protective casing
WELL CAPS
Well cap in good conditon
Damaged / needs replacement
Undermined / washing out
Lock in good condition
Lock rusted, difficult to open / needs replacing
Replaced damaged lock
WELL CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
CONCRETE PADS
Pad in good condition
Minor cracks
Major cracks / broken / repair required
WELL LOCK CONDITION
PAGE 1 OF 1
ACCESS TO WELLS
Access cleared into well
Access cleared around well
Tall grass or weeds - needs mowing
Road washing out / muddy / needs grading
Fallen tree blocking access
WELL SECURITY
Well found locked
Well found unlocked
SITE CONTACT Steve Hodges FIELD CREW LDC, PSP
WEATHER Steady rain, windy, 45 to 50 deg F.
NORTH CAROLINA GROUNDWATER SAMPLING SITE CHECKLIST
LOCATION / SITE CLIFFSIDE STEAM STATION - CCP LANDFILL GROUNDWATER MONITORING 81-06 SAMPLE DATE October 27, 2015
WELL DEPTH TO WATER Purge AVG *WELL EVAC SPECIFIC
WELL DEPTH WATER ELEV.Method PMP RATE VOL VOL EVAC TEMP CONDUCTANCE pH TURBIDITY ORP DO
DATE NO.(feet-toc)(feet-toc)(feet)APPEARANCE ODOR (ml/min)(gal)(gal)(yes/no)(deg C)(umho/cm)(units)(NTU)(mV-NHE)(mg/l)
10/27/2015 CCPMW-1S 42.24 38.01 837.57 Normal None EOP N/A 0.69 0.37 N/A 14.96 23 5.3 19.1 386 9.18
10/27/2015 CCPMW-1D 56.70 39.27 836.62 Normal None C N/A 2.84 9.00 NO 15.26 55 5.6 2.1 397 7.40
10/27/2015 CCPMW-2S 44.07 38.61 803.63 Normal None C N/A 0.89 3.00 NO 15.13 36 5.2 4.3 419 8.02
10/27/2015 CCPMW-2D 72.47 40.27 802.11 Normal None C N/A 5.25 11.25 NO 15.47 132 9.2 1.7 299 3.65
10/27/2015 CCPMW-3S 15.02 13.83 797.73 Normal None C N/A 0.19 NS NS NS NS NS NS NS NS
10/27/2015 CCPMW-3D 35.19 14.88 796.86 Normal None C N/A 3.31 10.50 NO 15.87 73 5.3 1.1 417 5.65
10/27/2015 CCPTW-1S 36.78 26.95 811.97 Normal None C N/A 1.60 5.25 NO 16.74 47 5.2 1.5 432 5.75
10/27/2015 CCPTW-1D 68.23 28.17 810.36 Normal None C N/A 6.53 8.75 NO 16.41 266 7.5 1.7 294 11.83
10/27/2015 CCPTW-2 47.63 40.80 801.38 Normal None C N/A 1.11 3.75 NO 15.95 45 5.1 5.0 405 6.87
10/27/2015 CCPSW-1 N/A N/A N/A Normal N/A NP N/A N/A N/A N/A 12.71 46 6.7 5.7 346 8.66
10/27/2015 CCPSW-2 N/A N/A N/A Normal N/A NP N/A N/A N/A N/A 12.77 44 6.5 11.3 309 8.53
10/27/2015 CCP-LEACHATE N/A N/A N/A Normal N/A NP N/A N/A N/A N/A 18.44 29369 4.6 32.2 343 7.39
Purge Methods
LF = Low Flow
LF(M) = Low Flow (Mod.)
C = Connventional
NP = No Purge
EOP = Equip. Only Purge
LO = Level Only
NS = Not Sampled / Insufficient volume in well
* = Applicable to LF & LF(M) Purging Only
CLIFFSIDE STEAM STATION
CLIFFSIDE CCP LANDFILL
GROUNDWATER MONITORING FIELD DATA
PERMIT #81-06

B
Appendix B
Laboratory Report and
Chain-of-Custody Forms

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J15100247
Project Name:CLIFFSIDE - GW CCP LANDFILL
Lab Contact:Peggy Kendall
Date:11/10/2015
Customer Address:573 Duke Power Rd
Customer Name(s):Chuck Campbell, TSH, SEAN DENEALE
Mail Code: Clliffside Steam Station
Mooresboro, NC 28024
Phone:
Report Authorized By:
(Signature)
Program Comments:
Reviewed history
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Peggy Kendall
Page 1 of 25
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015033202 CLIFFSIDE 27-Oct-15 9:20 AM LDC CCPMW-1S
2015033203 CLIFFSIDE 27-Oct-15 10:05 AM LDC CCPMW-1D
2015033204 CLIFFSIDE 27-Oct-15 7:55 AM LDC CCPMW-2S
2015033205 CLIFFSIDE 27-Oct-15 8:40 AM LDC CCPMW-2D
2015033207 CLIFFSIDE 27-Oct-15 11:55 AM PSP CCPMW-3D
2015033208 CLIFFSIDE 27-Oct-15 9:05 AM PSP CCPTW-1S
2015033209 CLIFFSIDE 27-Oct-15 10:10 AM PSP CCPTW-1D
2015033210 CLIFFSIDE 27-Oct-15 8:00 AM PSP CCPTW-2
2015033211 CLIFFSIDE 27-Oct-15 10:40 AM LDC CCPSW-1
2015033212 CLIFFSIDE 27-Oct-15 12:50 PM PSP CCPSW-2
2015033213 CLIFFSIDE 27-Oct-15 11:05 AM LDC CCP Leachate
2015033214 CLIFFSIDE 27-Oct-15 1:15 PM PSP FIELD BLANK
12 Total Samples
Page 2 of 25
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By: Date:11/9/2015
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100247
2015033202
Collection Date:27-Oct-15 9:20 AM
Site:CCPMW-1S
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B4d 10/28/2015 13:39 GHUTCHI51
INORGANIC IONS BY IC
Chloride 3.7 mg/L EPA 300.0 10/28/2015 09:24 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 10/28/2015 09:24 BGN90340.1 1
Nitrate 0.13 mg/L EPA 300.0 10/28/2015 09:24 BGN90340.1 1
Nitrate as N 0.03 mg-N/L EPA 300.0 10/28/2015 09:24 BGN90340.023 1
Sulfate 0.74 mg/L EPA 300.0 10/28/2015 09:24 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 10:29 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.023 mg/L EPA 200.7 10/29/2015 09:39 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 10/29/2015 09:39 MHH71310.05 1
Calcium (Ca)0.171 mg/L EPA 200.7 10/29/2015 09:39B2 MHH71310.01 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/29/2015 09:39 MHH71310.005 1
Iron (Fe)0.755 mg/L EPA 200.7 10/29/2015 09:39 MHH71310.01 1
Magnesium (Mg)0.709 mg/L EPA 200.7 10/29/2015 09:39 MHH71310.005 1
Manganese (Mn)0.043 mg/L EPA 200.7 10/29/2015 09:39 MHH71310.005 1
Potassium (K)0.880 mg/L EPA 200.7 10/29/2015 09:39 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/29/2015 09:39 MHH71310.005 1
Sodium (Na)1.29 mg/L EPA 200.7 10/29/2015 09:39 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 10/29/2015 09:39 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 10/29/2015 15:16 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 10/29/2015 15:16 JAHERMA11
Chromium (Cr)1.27 ug/L EPA 200.8 10/29/2015 15:16 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 10/29/2015 15:16 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 10/29/2015 15:16 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 10/29/2015 15:16 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 29 mg/L SM2540C 10/29/2015 15:25 CJELLIO251
Page 4 of 25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100247
2015033203
Collection Date:27-Oct-15 10:05 AM
Site:CCPMW-1D
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)6.1 mg/L
(CaCO3)
SM 2320B4d 10/28/2015 13:39 GHUTCHI51
INORGANIC IONS BY IC
Chloride 5.9 mg/L EPA 300.0 10/28/2015 12:41 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 10/28/2015 12:41 BGN90340.1 1
Nitrate 7.5 mg/L EPA 300.0 10/28/2015 12:41 BGN90340.1 1
Nitrate as N 1.7 mg-N/L EPA 300.0 10/28/2015 12:41 BGN90340.023 1
Sulfate 1.5 mg/L EPA 300.0 10/28/2015 12:41 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 10:31 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.018 mg/L EPA 200.7 10/29/2015 09:51 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 10/29/2015 09:51 MHH71310.05 1
Calcium (Ca)3.28 mg/L EPA 200.7 10/29/2015 09:51B2 MHH71310.01 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/29/2015 09:51 MHH71310.005 1
Iron (Fe)0.037 mg/L EPA 200.7 10/29/2015 09:51 MHH71310.01 1
Magnesium (Mg)1.67 mg/L EPA 200.7 10/29/2015 09:51 MHH71310.005 1
Manganese (Mn)0.014 mg/L EPA 200.7 10/29/2015 09:51 MHH71310.005 1
Potassium (K)1.29 mg/L EPA 200.7 10/29/2015 09:51 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/29/2015 09:51 MHH71310.005 1
Sodium (Na)2.73 mg/L EPA 200.7 10/29/2015 09:51 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 10/29/2015 09:51 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 10/29/2015 14:54 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 10/29/2015 14:54 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 10/29/2015 14:54 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 10/29/2015 14:54 JAHERMA11
Nickel (Ni)1.20 ug/L EPA 200.8 10/29/2015 14:54 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 10/29/2015 14:54 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 36 mg/L SM2540C 10/29/2015 15:25 CJELLIO251
Page 5 of 25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100247
2015033204
Collection Date:27-Oct-15 7:55 AM
Site:CCPMW-2S
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B4d 10/28/2015 13:39 GHUTCHI51
INORGANIC IONS BY IC
Chloride 4.7 mg/L EPA 300.0 10/28/2015 10:17 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 10/28/2015 10:17 BGN90340.1 1
Nitrate 2.2 mg/L EPA 300.0 10/28/2015 10:17 BGN90340.1 1
Nitrate as N 0.50 mg-N/L EPA 300.0 10/28/2015 10:17 BGN90340.023 1
Sulfate 0.41 mg/L EPA 300.0 10/28/2015 10:17 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 10:33 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.020 mg/L EPA 200.7 10/29/2015 09:55 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 10/29/2015 09:55 MHH71310.05 1
Calcium (Ca)1.87 mg/L EPA 200.7 10/29/2015 09:55B2 MHH71310.01 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/29/2015 09:55 MHH71310.005 1
Iron (Fe)0.108 mg/L EPA 200.7 10/29/2015 09:55 MHH71310.01 1
Magnesium (Mg)0.849 mg/L EPA 200.7 10/29/2015 09:55 MHH71310.005 1
Manganese (Mn)0.010 mg/L EPA 200.7 10/29/2015 09:55 MHH71310.005 1
Potassium (K)1.56 mg/L EPA 200.7 10/29/2015 09:55 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/29/2015 09:55 MHH71310.005 1
Sodium (Na)1.86 mg/L EPA 200.7 10/29/2015 09:55 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 10/29/2015 09:55 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 10/29/2015 15:23 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 10/29/2015 15:23 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 10/29/2015 15:23 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 10/29/2015 15:23 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 10/29/2015 15:23 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 10/29/2015 15:23 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 34 mg/L SM2540C 10/29/2015 15:25 CJELLIO251
Page 6 of 25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100247
2015033205
Collection Date:27-Oct-15 8:40 AM
Site:CCPMW-2D
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)45 mg/L
(CaCO3)
SM2320B 10/28/2015 11:17 TJA7067201
INORGANIC IONS BY IC
Chloride 4.6 mg/L EPA 300.0 10/28/2015 10:35 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 10/28/2015 10:35 BGN90340.1 1
Nitrate 4.2 mg/L EPA 300.0 10/28/2015 10:35 BGN90340.1 1
Nitrate as N 0.96 mg-N/L EPA 300.0 10/28/2015 10:35 BGN90340.023 1
Sulfate 5.0 mg/L EPA 300.0 10/28/2015 10:35 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 10:35 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.008 mg/L EPA 200.7 10/29/2015 09:59 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 10/29/2015 09:59 MHH71310.05 1
Calcium (Ca)16.5 mg/L EPA 200.7 10/29/2015 09:59B2 MHH71310.01 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/29/2015 09:59 MHH71310.005 1
Iron (Fe)0.021 mg/L EPA 200.7 10/29/2015 09:59 MHH71310.01 1
Magnesium (Mg)0.518 mg/L EPA 200.7 10/29/2015 09:59 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 10/29/2015 09:59 MHH71310.005 1
Potassium (K)2.48 mg/L EPA 200.7 10/29/2015 09:59 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/29/2015 09:59 MHH71310.005 1
Sodium (Na)5.17 mg/L EPA 200.7 10/29/2015 09:59 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 10/29/2015 09:59 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 10/29/2015 15:30 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 10/29/2015 15:30 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 10/29/2015 15:30 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 10/29/2015 15:30 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 10/29/2015 15:30 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 10/29/2015 15:30 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 91 mg/L SM2540C 10/29/2015 15:25 CJELLIO251
Page 7 of 25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100247
2015033207
Collection Date:27-Oct-15 11:55 AM
Site:CCPMW-3D
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B4d 10/28/2015 13:39 GHUTCHI51
INORGANIC IONS BY IC
Chloride 4.9 mg/L EPA 300.0 10/28/2015 13:16 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 10/28/2015 13:16 BGN90340.1 1
Nitrate 6.8 mg/L EPA 300.0 10/28/2015 13:16 BGN90340.1 1
Nitrate as N 1.5 mg-N/L EPA 300.0 10/28/2015 13:16 BGN90340.023 1
Sulfate 13 mg/L EPA 300.0 10/28/2015 13:16 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 10:38 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.030 mg/L EPA 200.7 10/29/2015 10:03 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 10/29/2015 10:03 MHH71310.05 1
Calcium (Ca)5.71 mg/L EPA 200.7 10/29/2015 10:03B2 MHH71310.01 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/29/2015 10:03 MHH71310.005 1
Iron (Fe)< 0.01 mg/L EPA 200.7 10/29/2015 10:03 MHH71310.01 1
Magnesium (Mg)2.24 mg/L EPA 200.7 10/29/2015 10:03 MHH71310.005 1
Manganese (Mn)0.009 mg/L EPA 200.7 10/29/2015 10:03 MHH71310.005 1
Potassium (K)1.49 mg/L EPA 200.7 10/29/2015 10:03 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/29/2015 10:03 MHH71310.005 1
Sodium (Na)2.17 mg/L EPA 200.7 10/29/2015 10:03 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 10/29/2015 10:03 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 10/29/2015 15:37 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 10/29/2015 15:37 JAHERMA11
Chromium (Cr)1.70 ug/L EPA 200.8 10/29/2015 15:37 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 10/29/2015 15:37 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 10/29/2015 15:37 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 10/29/2015 15:37 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 47 mg/L SM2540C 10/29/2015 15:25 CJELLIO251
Page 8 of 25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100247
2015033208
Collection Date:27-Oct-15 9:05 AM
Site:CCPTW-1S
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B4d 10/28/2015 13:39 GHUTCHI51
INORGANIC IONS BY IC
Chloride 4.4 mg/L EPA 300.0 10/28/2015 12:59 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 10/28/2015 12:59 BGN90340.1 1
Nitrate 9.2 mg/L EPA 300.0 10/28/2015 12:59 BGN90340.1 1
Nitrate as N 2.1 mg-N/L EPA 300.0 10/28/2015 12:59 BGN90340.023 1
Sulfate 0.64 mg/L EPA 300.0 10/28/2015 12:59 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 10:50 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.028 mg/L EPA 200.7 10/29/2015 10:07 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 10/29/2015 10:07 MHH71310.05 1
Calcium (Ca)2.16 mg/L EPA 200.7 10/29/2015 10:07B2 MHH71310.01 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/29/2015 10:07 MHH71310.005 1
Iron (Fe)0.039 mg/L EPA 200.7 10/29/2015 10:07 MHH71310.01 1
Magnesium (Mg)1.77 mg/L EPA 200.7 10/29/2015 10:07 MHH71310.005 1
Manganese (Mn)0.007 mg/L EPA 200.7 10/29/2015 10:07 MHH71310.005 1
Potassium (K)1.29 mg/L EPA 200.7 10/29/2015 10:07 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/29/2015 10:07 MHH71310.005 1
Sodium (Na)2.57 mg/L EPA 200.7 10/29/2015 10:07 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 10/29/2015 10:07 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 10/29/2015 15:44 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 10/29/2015 15:44 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 10/29/2015 15:44 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 10/29/2015 15:44 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 10/29/2015 15:44 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 10/29/2015 15:44 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 39 mg/L SM2540C 10/29/2015 15:25 CJELLIO251
Page 9 of 25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100247
2015033209
Collection Date:27-Oct-15 10:10 AM
Site:CCPTW-1D
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)79 mg/L
(CaCO3)
SM2320B 10/28/2015 11:17 TJA7067201
INORGANIC IONS BY IC
Chloride 2.9 mg/L EPA 300.0 10/29/2015 08:56 BGN90340.1 1
Fluoride 0.23 mg/L EPA 300.0 10/29/2015 08:56 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 10/29/2015 08:56 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 10/29/2015 08:56 BGN90340.023 1
Sulfate 43 mg/L EPA 300.0 10/29/2015 08:56 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 10:57 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.028 mg/L EPA 200.7 10/29/2015 10:11 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 10/29/2015 10:11 MHH71310.05 1
Calcium (Ca)32.0 mg/L EPA 200.7 10/29/2015 10:11B2 MHH71310.01 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/29/2015 10:11 MHH71310.005 1
Iron (Fe)0.040 mg/L EPA 200.7 10/29/2015 10:11 MHH71310.01 1
Magnesium (Mg)2.99 mg/L EPA 200.7 10/29/2015 10:11 MHH71310.005 1
Manganese (Mn)0.031 mg/L EPA 200.7 10/29/2015 10:11 MHH71310.005 1
Potassium (K)2.76 mg/L EPA 200.7 10/29/2015 10:11 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/29/2015 10:11 MHH71310.005 1
Sodium (Na)14.5 mg/L EPA 200.7 10/29/2015 10:11 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 10/29/2015 10:11 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 10/29/2015 15:51 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 10/29/2015 15:51 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 10/29/2015 15:51 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 10/29/2015 15:51 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 10/29/2015 15:51 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 10/29/2015 15:51 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 160 mg/L SM2540C 10/29/2015 15:25 CJELLIO251
Page 10 of 25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100247
2015033210
Collection Date:27-Oct-15 8:00 AM
Site:CCPTW-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B4d 10/28/2015 13:39 GHUTCHI51
INORGANIC IONS BY IC
Chloride 4.3 mg/L EPA 300.0 10/28/2015 10:53 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 10/28/2015 10:53 BGN90340.1 1
Nitrate 7.6 mg/L EPA 300.0 10/28/2015 10:53 BGN90340.1 1
Nitrate as N 1.7 mg-N/L EPA 300.0 10/28/2015 10:53 BGN90340.023 1
Sulfate 2.5 mg/L EPA 300.0 10/28/2015 10:53 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 10:59 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.026 mg/L EPA 200.7 10/29/2015 10:15 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 10/29/2015 10:15 MHH71310.05 1
Calcium (Ca)2.26 mg/L EPA 200.7 10/29/2015 10:15B2 MHH71310.01 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/29/2015 10:15 MHH71310.005 1
Iron (Fe)0.283 mg/L EPA 200.7 10/29/2015 10:15 MHH71310.01 1
Magnesium (Mg)1.74 mg/L EPA 200.7 10/29/2015 10:15 MHH71310.005 1
Manganese (Mn)0.010 mg/L EPA 200.7 10/29/2015 10:15 MHH71310.005 1
Potassium (K)1.44 mg/L EPA 200.7 10/29/2015 10:15 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/29/2015 10:15 MHH71310.005 1
Sodium (Na)1.85 mg/L EPA 200.7 10/29/2015 10:15 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 10/29/2015 10:15 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 10/29/2015 15:58 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 10/29/2015 15:58 JAHERMA11
Chromium (Cr)1.16 ug/L EPA 200.8 10/29/2015 15:58 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 10/29/2015 15:58 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 10/29/2015 15:58 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 10/29/2015 15:58 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 37 mg/L SM2540C 10/29/2015 15:25 CJELLIO251
Page 11 of 25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100247
2015033211
Collection Date:27-Oct-15 10:40 AM
Site:CCPSW-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)11 mg/L
(CaCO3)
SM 2320B4d 10/28/2015 13:39 GHUTCHI51
INORGANIC IONS BY IC
Chloride 3.9 mg/L EPA 300.0 10/28/2015 11:11 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 10/28/2015 11:11 BGN90340.1 1
Nitrate 1.5 mg/L EPA 300.0 10/28/2015 11:11 BGN90340.1 1
Nitrate as N 0.34 mg-N/L EPA 300.0 10/28/2015 11:11 BGN90340.023 1
Sulfate 1.5 mg/L EPA 300.0 10/28/2015 11:11 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 11:02 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.022 mg/L EPA 200.7 10/29/2015 10:19 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 10/29/2015 10:19 MHH71310.05 1
Calcium (Ca)2.58 mg/L EPA 200.7 10/29/2015 10:19B2 MHH71310.01 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/29/2015 10:19 MHH71310.005 1
Iron (Fe)1.25 mg/L EPA 200.7 10/29/2015 10:19 MHH71310.01 1
Magnesium (Mg)1.32 mg/L EPA 200.7 10/29/2015 10:19 MHH71310.005 1
Manganese (Mn)0.038 mg/L EPA 200.7 10/29/2015 10:19 MHH71310.005 1
Potassium (K)2.19 mg/L EPA 200.7 10/29/2015 10:19 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/29/2015 10:19 MHH71310.005 1
Sodium (Na)2.60 mg/L EPA 200.7 10/29/2015 10:19 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 10/29/2015 10:19 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 10/29/2015 16:05 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 10/29/2015 16:05 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 10/29/2015 16:05 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 10/29/2015 16:05 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 10/29/2015 16:05 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 10/29/2015 16:05 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 43 mg/L SM2540C 10/29/2015 15:25 CJELLIO251
Page 12 of 25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100247
2015033212
Collection Date:27-Oct-15 12:50 PM
Site:CCPSW-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)11 mg/L
(CaCO3)
SM 2320B4d 10/28/2015 13:39 GHUTCHI51
INORGANIC IONS BY IC
Chloride 3.9 mg/L EPA 300.0 10/28/2015 14:46 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 10/28/2015 14:46 BGN90340.1 1
Nitrate 1.3 mg/L EPA 300.0 10/28/2015 14:46 BGN90340.1 1
Nitrate as N 0.29 mg-N/L EPA 300.0 10/28/2015 14:46 BGN90340.023 1
Sulfate 1.6 mg/L EPA 300.0 10/28/2015 14:46 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 11:04 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.023 mg/L EPA 200.7 10/29/2015 10:24 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 10/29/2015 10:24 MHH71310.05 1
Calcium (Ca)2.64 mg/L EPA 200.7 10/29/2015 10:24B2 MHH71310.01 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/29/2015 10:24 MHH71310.005 1
Iron (Fe)1.30 mg/L EPA 200.7 10/29/2015 10:24 MHH71310.01 1
Magnesium (Mg)1.33 mg/L EPA 200.7 10/29/2015 10:24 MHH71310.005 1
Manganese (Mn)0.041 mg/L EPA 200.7 10/29/2015 10:24 MHH71310.005 1
Potassium (K)2.20 mg/L EPA 200.7 10/29/2015 10:24 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/29/2015 10:24 MHH71310.005 1
Sodium (Na)2.57 mg/L EPA 200.7 10/29/2015 10:24 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 10/29/2015 10:24 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 10/29/2015 16:12 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 10/29/2015 16:12 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 10/29/2015 16:12 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 10/29/2015 16:12 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 10/29/2015 16:12 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 10/29/2015 16:12 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 50 mg/L SM2540C 10/29/2015 15:25 CJELLIO251
Page 13 of 25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100247
2015033213
Collection Date:27-Oct-15 11:05 AM
Site:CCP Leachate
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B4d 10/28/2015 13:39 GHUTCHI51
INORGANIC IONS BY IC
Chloride 11000 mg/L EPA 300.0 10/28/2015 15:58 BGN90342002000
Fluoride < 10 mg/L EPA 300.0 10/28/2015 15:58 BGN903410100
Nitrate 17 mg/L EPA 300.0 10/28/2015 15:58 BGN903410100
Nitrate as N 3.8 mg-N/L EPA 300.0 10/28/2015 15:58 BGN90340.023 1
Sulfate 880 mg/L EPA 300.0 10/28/2015 15:58 BGN903410100
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 11:06 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.627 mg/L EPA 200.7 10/29/2015 10:40 MHH71310.005 1
Boron (B)8.62 mg/L EPA 200.7 10/29/2015 10:40 MHH71310.05 1
Calcium (Ca)5590 mg/L EPA 200.7 10/29/2015 10:40B2 MHH71311100
Copper (Cu)0.056 mg/L EPA 200.7 10/29/2015 10:40 MHH71310.005 1
Iron (Fe)9.69 mg/L EPA 200.7 10/29/2015 10:40 MHH71310.01 1
Magnesium (Mg)60.6 mg/L EPA 200.7 10/29/2015 10:40 MHH71310.005 1
Manganese (Mn)51.5 mg/L EPA 200.7 10/29/2015 10:40 MHH71310.25 50
Potassium (K)442 mg/L EPA 200.7 10/29/2015 10:40 MHH7131550
Silver (Ag)< 0.005 mg/L EPA 200.7 10/29/2015 10:40 MHH71310.005 1
Sodium (Na)293 mg/L EPA 200.7 10/29/2015 10:40 MHH71312.5 50
Zinc (Zn)0.304 mg/L EPA 200.7 10/29/2015 10:40 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)39.0 ug/L EPA 200.8 10/30/2015 12:15 JAHERMA11
Cadmium (Cd)4.10 ug/L EPA 200.8 10/30/2015 12:15 JAHERMA11
Chromium (Cr)5.35 ug/L EPA 200.8 10/30/2015 12:15 JAHERMA11
Lead (Pb)208 ug/L EPA 200.8 10/30/2015 12:15 JAHERMA11
Nickel (Ni)222 ug/L EPA 200.8 10/30/2015 12:15 JAHERMA11
Selenium (Se)249 ug/L EPA 200.8 10/30/2015 12:15 JAHERMA11
TOTAL DISSOLVED SOLIDS
TDS 26000 mg/L SM2540C 10/29/2015 15:25 CJELLIO5001
Page 14 of 25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100247
2015033214
Collection Date:27-Oct-15 1:15 PM
Site:FIELD BLANK
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)< 20 mg/L
(CaCO3)
SM2320B 10/28/2015 11:17 TJA7067201
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 10/28/2015 09:06 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 10/28/2015 09:06 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 10/28/2015 09:06 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 10/28/2015 09:06 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 300.0 10/28/2015 09:06 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 10/30/2015 11:08 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L EPA 200.7 10/29/2015 10:36 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 10/29/2015 10:36 MHH71310.05 1
Calcium (Ca)0.022 mg/L EPA 200.7 10/29/2015 10:36B2 MHH71310.01 1
Copper (Cu)< 0.005 mg/L EPA 200.7 10/29/2015 10:36 MHH71310.005 1
Iron (Fe)< 0.01 mg/L EPA 200.7 10/29/2015 10:36 MHH71310.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 10/29/2015 10:36 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 10/29/2015 10:36 MHH71310.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 10/29/2015 10:36 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 10/29/2015 10:36 MHH71310.005 1
Sodium (Na)< 0.05 mg/L EPA 200.7 10/29/2015 10:36 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 10/29/2015 10:36 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 10/29/2015 16:40 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 10/29/2015 16:40 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 10/29/2015 16:40 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 10/29/2015 16:40 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 10/29/2015 16:40 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 10/29/2015 16:40 JAHERMA11
Qualifiers:
B2 Target analyte was detected in blank(s) at a concentration greater than ½ the reporting limit but less than the
reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
Page 15 of 25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100247
Q15100483 ALK_FIX4.5 ALKALINITY (FIXED END POINT 4.5)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J15100247 -- 2015033209
Alkalinity (mg/L CaCO3)0.194mg/L
(CaCO3)
-179.6
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3)81.6 98.7mg/L
(CaCO3)
-12080180.6
Page 16 of 25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100247
Q15100491 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J15100188 -- 2015032952
Alkalinity (mg/L CaCO3)1.68mg/L
(CaCO3)
-110.5
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3)8.16 87.5mg/L
(CaCO3)
-1208017.14
Page 17 of 25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100247
Q15100459 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0336 mg/L -10.0336 0.1 < 1/2 RDL
Fluoride 0.0399 mg/L -10.0399 0.1 < 1/2 RDL
Nitrate 0.0297 mg/L -10.0297 0.1 < 1/2 RDL
Sulfate 0.0264 mg/L -10.0264 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 9.12 5 109mg/L -1208019.12
Fluoride 5.25 5 104mg/L -1208015.25
Nitrate 5.51 5 108mg/L -1208015.51
Sulfate 5.65 5 98.2mg/L -1208015.65
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 9.1 5 108 0.42mg/L -1208019.1
Fluoride 5.26 5 104 0.0577mg/L -1208015.26
Nitrate 5.51 5 108 0.026mg/L -1208015.51
Sulfate 5.63 5 97.9 0.353mg/L -1208015.63
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 9.11 5 103mg/L -1208019.11
Fluoride 5.03 5 99mg/L -1208015.03
Nitrate 6.44 5 103mg/L -1208016.44
Sulfate 6.71 5 102mg/L -1208016.71
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 9.09 5 103 0.265mg/L -1208019.09
Fluoride 5.04 5 99.1 0.111mg/L -1208015.04
Nitrate 6.43 5 103 0.131mg/L -1208016.43
Sulfate 6.7 5 102 0.0959mg/L -1208016.7
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.1 5 102mg/L -1208015.1
Fluoride 5.43 5 109mg/L -1208015.43
Nitrate 5.09 5 102mg/L -1208015.09
Sulfate 5.07 5 101mg/L -1208015.07
Page 18 of 25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100247
Q15100545 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.009 ug/L -10.009 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.019 ug/L -10.019 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.94 2 97ug/L -1158511.94
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.91 2 95.3ug/L -1158511.91
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J15090311 -- 2015030319
Mercury (Hg) 0.911 20 89.9ug/L -130702018.2
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15090311 -- 2015030319
Mercury (Hg) 0.905 20 89.3 0.726ug/L -130702018.1
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J15100188 -- 2015032958
Mercury (Hg) 1.03 1 102ug/L -1307011.03
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J15100188 -- 2015032958
Mercury (Hg) 1.03 1 103 0.88ug/L -1307011.03
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J15100247 -- 2015033208
Mercury (Hg) 1.01 1 99.1ug/L -1307011.01
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J15100247 -- 2015033208
Mercury (Hg) 1.02 1 99.3 0.202ug/L -1307011.02
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J15100568 -- 2015034550
Mercury (Hg) 1.02 1 101ug/L -1307011.02
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J15100568 -- 2015034550
Mercury (Hg) 1.02 1 101 0ug/L -1307011.02
Page 19 of 25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100247
Q15100468 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) 0.0007 mg/L -10.0007 0.005 < 1/2 RDL
Boron (B) 0.00114 mg/L -10.00114 0.05 < 1/2 RDL
Calcium (Ca) 0.00601 mg/L -10.00601 0.01 > 1/2 RDL
Copper (Cu) 0.000716 mg/L -10.000716 0.005 < 1/2 RDL
Iron (Fe) 0.000647 mg/L -10.000647 0.01 < 1/2 RDL
Magnesium (Mg) 0.000612 mg/L -10.000612 0.005 < 1/2 RDL
Manganese (Mn) 0.000506 mg/L -10.000506 0.005 < 1/2 RDL
Potassium (K) 0.00421 mg/L -10.00421 0.1 < 1/2 RDL
Silver (Ag) -0.000107 mg/L -1-0.000107 0.005 < 1/2 RDL
Sodium (Na) 0.000827 mg/L -10.000827 0.05 < 1/2 RDL
Zinc (Zn) 0.000699 mg/L -10.000699 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 5.08 5 102mg/L -1208015.08
Boron (B) 5.01 5 100mg/L -1208015.01
Calcium (Ca) 5.08 5 102mg/L -1208015.08
Copper (Cu) 5 5 100mg/L -1208015
Iron (Fe) 5.09 5 102mg/L -1208015.09
Magnesium (Mg) 4.96 5 99.1mg/L -1208014.96
Manganese (Mn) 5.09 5 102mg/L -1208015.09
Potassium (K) 4.96 5 99.3mg/L -1208014.96
Silver (Ag) 0.496 0.5 99.2mg/L -1208010.496
Sodium (Na) 4.96 5 99.2mg/L -1208014.96
Zinc (Zn) 5.17 5 103mg/L -1208015.17
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J15100247 -- 2015033202
Barium (Ba) 5.04 5 100mg/L -1257515.04
Boron (B) 4.95 5 98.9mg/L -1257514.95
Calcium (Ca) 5.16 5 99.8mg/L -1257515.16
Copper (Cu) 4.93 5 98.6mg/L -1257514.93
Iron (Fe) 5.72 5 99.3mg/L -1257515.72
Magnesium (Mg) 5.63 5 98.5mg/L -1257515.63
Manganese (Mn) 5.07 5 101mg/L -1257515.07
Potassium (K) 5.81 5 98.5mg/L -1257515.81
Silver (Ag) 0.491 0.5 98.3mg/L -1257510.491
Sodium (Na) 6.19 5 98mg/L -1257516.19
Zinc (Zn) 5.08 5 101mg/L -1257515.08
Page 20 of 25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100247
Q15100468 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15100247 -- 2015033202
Barium (Ba) 5.03 5 100 0.0798mg/L -1257515.03
Boron (B) 4.96 5 99.1 0.182mg/L -1257514.96
Calcium (Ca) 5.17 5 100 0.22mg/L -1257515.17
Copper (Cu) 4.92 5 98.4 0.183mg/L -1257514.92
Iron (Fe) 5.73 5 99.4 0.161mg/L -1257515.73
Magnesium (Mg) 5.63 5 98.3 0.183mg/L -1257515.63
Manganese (Mn) 5.08 5 101 0.179mg/L -1257515.08
Potassium (K) 5.82 5 98.7 0.162mg/L -1257515.82
Silver (Ag) 0.49 0.5 98.1 0.229mg/L -1257510.49
Sodium (Na) 6.2 5 98.1 0.163mg/L -1257516.2
Zinc (Zn) 5.11 5 102 0.668mg/L -1257515.11
Page 21 of 25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100247
Q15100471 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) 0.0409 ug/L -10.0409 1 < 1/2 RDL
Cadmium (Cd) 0.0007 ug/L -10.0007 1 < 1/2 RDL
Chromium (Cr) 0.0057 ug/L -10.0057 1 < 1/2 RDL
Copper (Cu) -0.0466 ug/L -1-0.0466 1 < 1/2 RDL
Lead (Pb) 0.0066 ug/L -10.0066 1 < 1/2 RDL
Nickel (Ni) -0.0001 ug/L -1-0.0001 1 < 1/2 RDL
Selenium (Se) 0.0139 ug/L -10.0139 1 < 1/2 RDL
Silver (Ag) 0.0002 ug/L -10.0002 1 < 1/2 RDL
Zinc (Zn) 0.0182 ug/L -10.0182 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 51.4 50 103ug/L -12080151.4
Cadmium (Cd) 51.4 50 103ug/L -12080151.4
Chromium (Cr) 52.6 50 105ug/L -12080152.6
Copper (Cu) 52.1 50 104ug/L -12080152.1
Lead (Pb) 50.6 50 101ug/L -12080150.6
Nickel (Ni) 51.2 50 102ug/L -12080151.2
Selenium (Se) 50.9 50 102ug/L -12080150.9
Silver (Ag) 50.8 50 102ug/L -12080150.8
Zinc (Zn) 52 50 104ug/L -12080152
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J15100247 -- 2015033203
Arsenic (As) 48.9 50 97.7ug/L -12080148.9
Cadmium (Cd) 49 50 98.1ug/L -12080149
Chromium (Cr) 52.4 50 104ug/L -12080152.4
Copper (Cu) 50.2 50 100ug/L -12080150.2
Lead (Pb) 50.2 50 100ug/L -12080150.2
Nickel (Ni) 49.9 50 97.4ug/L -12080149.9
Selenium (Se) 47.9 50 95.7ug/L -12080147.9
Silver (Ag) 48.7 50 97.4ug/L -12080148.7
Zinc (Zn) 50 50 96.5ug/L -12080150
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15100247 -- 2015033203
Arsenic (As) 48.8 50 97.5 0.246ug/L -12080148.8
Cadmium (Cd) 49.3 50 98.5 0.488ug/L -12080149.3
Chromium (Cr) 52.7 50 104 0.48ug/L -12080152.7
Copper (Cu) 50.4 50 100 0.299ug/L -12080150.4
Page 22 of 25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100247
Q15100471 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15100247 -- 2015033203
Lead (Pb) 50.5 50 101 0.517ug/L -12080150.5
Nickel (Ni) 50.2 50 98.1 0.696ug/L -12080150.2
Selenium (Se) 47.4 50 94.7 1.03ug/L -12080147.4
Silver (Ag) 49.1 50 98.2 0.797ug/L -12080149.1
Zinc (Zn) 50.2 50 97 0.517ug/L -12080150.2
Page 23 of 25
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100247
Q15100501 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J15100247 -- 2015033202
TDS 10.9mg/L -126
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J15100247 -- 2015033203
TDS 5.71mg/L -134
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J15100247 -- 2015033204
TDS 6.06mg/L -132
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 102mg/L -110901102
Page 24 of 25
Page 25 of 25
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J15100249
Project Name:CLIFFSIDE -
Lab Contact:Peggy Kendall
Date:11/10/2015
Customer Address:573 Duke Power Rd
Customer Name(s):Chuck Campbell, TSH, SEAN DENEALE
Mail Code: Clliffside Steam Station
Mooresboro, NC 28024
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Peggy Kendall
Page 1 of 9
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015033223 CLIFFSIDE 27-Oct-15 10:40 AM LDC CCPSW-1
2015033224 CLIFFSIDE 27-Oct-15 12:50 PM PSP CCPSW-2
2 Total Samples
Page 2 of 9
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:11/6/2015
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 9
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100249
2015033223
Collection Date:27-Oct-15 10:40 AM
Site:CCPSW-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
DISSOLVED METALS BY ICP
Barium (Ba)0.020 mg/L EPA 200.7 11/02/2015 11:10 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/02/2015 11:10 FCJORDA0.05 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/02/2015 11:10 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/02/2015 11:10 FCJORDA0.005 1
Iron (Fe)0.399 mg/L EPA 200.7 11/02/2015 11:10 FCJORDA0.01 1
Manganese (Mn)0.037 mg/L EPA 200.7 11/02/2015 11:10 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/02/2015 11:10 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/02/2015 11:10 FCJORDA0.005 1
DISSOLVED METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/04/2015 11:29 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 11/04/2015 11:29 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 11/04/2015 11:29 JAHERMA11
Silver (Ag)< 1 ug/L EPA 200.8 11/04/2015 11:29 JAHERMA11
Page 4 of 9
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100249
2015033224
Collection Date:27-Oct-15 12:50 PM
Site:CCPSW-2
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
DISSOLVED METALS BY ICP
Barium (Ba)0.022 mg/L EPA 200.7 11/02/2015 11:21 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/02/2015 11:21 FCJORDA0.05 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/02/2015 11:21 FCJORDA0.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/02/2015 11:21 FCJORDA0.005 1
Iron (Fe)0.340 mg/L EPA 200.7 11/02/2015 11:21 FCJORDA0.01 1
Manganese (Mn)0.040 mg/L EPA 200.7 11/02/2015 11:21 FCJORDA0.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/02/2015 11:21 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/02/2015 11:21 FCJORDA0.005 1
DISSOLVED METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/04/2015 11:50 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 11/04/2015 11:50 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 11/04/2015 11:50 JAHERMA11
Silver (Ag)< 1 ug/L EPA 200.8 11/04/2015 11:50 JAHERMA11
Page 5 of 9
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100249
Q15110008 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.000262 mg/L -10.000262 0.005 < 1/2 RDL
Barium (Ba) 0.000316 mg/L -10.000316 0.005 < 1/2 RDL
Boron (B) 0.0151 mg/L -10.0151 0.05 < 1/2 RDL
Chromium (Cr) -0.000046 mg/L -1-0.000046 0.005 < 1/2 RDL
Copper (Cu) 0.00185 mg/L -10.00185 0.005 < 1/2 RDL
Iron (Fe) -0.000105 mg/L -1-0.000105 0.01 < 1/2 RDL
Manganese (Mn) 0.000308 mg/L -10.000308 0.005 < 1/2 RDL
Nickel (Ni) 0.000199 mg/L -10.000199 0.005 < 1/2 RDL
Strontium (Sr) 0.000369 mg/L -10.000369 0.005 < 1/2 RDL
Zinc (Zn) -0.000455 mg/L -1-0.000455 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 2.04 2 102mg/L -1158512.04
Barium (Ba) 1.02 1 102mg/L -1158511.02
Boron (B) 2.01 2 100mg/L -1158512.01
Chromium (Cr) 1.04 1 104mg/L -1158511.04
Copper (Cu) 2 2 99.8mg/L -1158512
Iron (Fe) 2.06 2 103mg/L -1158512.06
Manganese (Mn) 1 1 100mg/L -1158511
Nickel (Ni) 2.02 2 101mg/L -1158512.02
Strontium (Sr) 1.97 2 98.5mg/L -1158511.97
Zinc (Zn) 1.05 1 105mg/L -1158511.05
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J15100249 -- 2015033223
Aluminum (Al) 5.53 5 110mg/L -1307015.53
Barium (Ba) 5.63 5 112mg/L -1307015.63
Boron (B) 4.64 5 92.5mg/L -1307014.64
Chromium (Cr) 5.45 5 109mg/L -1307015.45
Copper (Cu) 5.45 5 109mg/L -1307015.45
Iron (Fe) 5.83 5 109mg/L -1307015.83
Manganese (Mn) 5.66 5 112mg/L -1307015.66
Nickel (Ni) 5.52 5 110mg/L -1307015.52
Strontium (Sr) 5.56 5 111mg/L -1307015.56
Zinc (Zn) 5.43 5 108mg/L -1307015.43
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15100249 -- 2015033223
Aluminum (Al) 5.57 5 111 0.597mg/L -1307015.57
Page 6 of 9
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100249
Q15110008 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15100249 -- 2015033223
Barium (Ba) 5.66 5 113 0.498mg/L -1307015.66
Boron (B) 4.67 5 93.2 0.775mg/L -1307014.67
Chromium (Cr) 5.49 5 110 0.749mg/L -1307015.49
Copper (Cu) 5.48 5 110 0.622mg/L -1307015.48
Iron (Fe) 5.86 5 109 0.533mg/L -1307015.86
Manganese (Mn) 5.71 5 113 0.797mg/L -1307015.71
Nickel (Ni) 5.54 5 111 0.362mg/L -1307015.54
Strontium (Sr) 5.54 5 110 0.38mg/L -1307015.54
Zinc (Zn) 5.45 5 109 0.405mg/L -1307015.45
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J15110004 -- 2015035279
Aluminum (Al) 5.62 5 111mg/L -1307015.62
Barium (Ba) 5.79 5 115mg/L -1307015.79
Boron (B) 4.88 5 96.7mg/L -1307014.88
Chromium (Cr) 5.5 5 110mg/L -1307015.5
Copper (Cu) 5.55 5 111mg/L -1307015.55
Iron (Fe) 5.62 5 108mg/L -1307015.62
Manganese (Mn) 5.75 5 114mg/L -1307015.75
Nickel (Ni) 5.55 5 111mg/L -1307015.55
Strontium (Sr) 5.25 5 104mg/L -1307015.25
Zinc (Zn) 5.45 5 109mg/L -1307015.45
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J15110004 -- 2015035279
Aluminum (Al) 5.64 5 111 0.288mg/L -1307015.64
Barium (Ba) 5.79 5 115 0.0693mg/L -1307015.79
Boron (B) 4.88 5 96.8 0.0827mg/L -1307014.88
Chromium (Cr) 5.5 5 110 0.0727mg/L -1307015.5
Copper (Cu) 5.56 5 111 0.144mg/L -1307015.56
Iron (Fe) 5.64 5 109 0.425mg/L -1307015.64
Manganese (Mn) 5.75 5 114 0.0351mg/L -1307015.75
Nickel (Ni) 5.58 5 112 0.539mg/L -1307015.58
Strontium (Sr) 5.23 5 103 0.367mg/L -1307015.23
Zinc (Zn) 5.46 5 109 0.165mg/L -1307015.46
Page 7 of 9
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100249
Q15110070 IMS Dissolved DISSOLVED METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As)ug/L -10.01 1 < 1/2 RDL
Cadmium (Cd)ug/L -10 1 < 1/2 RDL
Lead (Pb)ug/L -1-0.01 1 < 1/2 RDL
Silver (Ag)ug/L -10 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As)80 111ug/L -11585188.4
Cadmium (Cd)8 109ug/L -1158518.75
Lead (Pb)80 108ug/L -11585186.2
Silver (Ag)40 108ug/L -11585143.4
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J15100249 -- 2015033223
Arsenic (As) 51.1 50 102ug/L -13070151.1
Cadmium (Cd) 50.5 50 101ug/L -13070150.5
Lead (Pb) 49.9 50 99.7ug/L -13070149.9
Silver (Ag) 48 50 96ug/L -13070148
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15100249 -- 2015033223
Arsenic (As) 51 50 102 0.314ug/L -13070151
Cadmium (Cd) 50 50 99.9 1.04ug/L -13070150
Lead (Pb) 49.9 50 99.6 0.0401ug/L -13070149.9
Silver (Ag) 47.9 50 95.9 0.188ug/L -13070147.9
Page 8 of 9
Page 9 of 9