9602_WayneCounty_GWMReport_DIN26413_20151024

Northern Wayne County Closed Unlined MSWLF - Pikeville
Pikeville, North Carolina
October 2015
MESCO Project Number: G15016.0
Annual Water Quality Monitoring Report
Prepared for
Municipal Engineering Services Company, P.A.Garner, Boone and Morehead City, North Carolina
Permit Number: 96-02-MSWLF-1981
Tables
Wayne County Closed Landfill, Pikeville Page 1 of 1
Table 1
Groundwater Monitoring Well Construction Table
October 24, 2015
Latitude Longitude
(inches)(ft)
MW-2 1.25 24.85 soil 6.35 35.483875 -78.004758
MW-3 1.25 25.20 soil 0.00 35.481458 -78.000765
MW-4 1.25 20.50 soil 8.90 35.476471 -78.002436
MW-5 1.25 21.95 soil 19.99 35.481289 -78.003996
Monitoring
Well
Date
Installed
Well
Diameter
Total
Well Depth
Top of Screen
Depth
Screen
Length Geology of Screened
Interval
Top of
Casing Elevation
Ground
Elevation
Groundwater
Elevation
Depth to
Water
(ft btoc)(ft bgs)(ft amsl)(ft amsl)(ft amsl)(ft btoc)
na na na na na na
na na na na na na
na na na na na na
na na na na na na
na = not available
bgs = below ground surface
amsl= above mean sea level
btoc = below top of PVC well casing
Wayne County Closed Landfill, Pikeville Page 1 of 1
Table 2
Field Observations of Monitoring Locations
October 24, 2015
Locked Comments
MW-2 Yes Yes Yes Yes No Yes
MW-3 Yes Yes Yes Yes No Yes Lock is poor
MW-4 Yes Yes Yes Yes No Yes
MW-5 Yes Yes Yes Yes No Yes
SW-1 No -----Dry
Any unusual field conditions, observations, or events:
All wells locked but not labeled very well.
All wells 1.25” nominal PVC
Sample
Location
Viable
Monitoring
Location
Lack of Any
Evidence of
Tampering
Hinge/Hasp
Operational
Tagged
or
Labeled
Concrete
Surface Pad
Assumed
Effective
Wayne County Subtitle D Lined MSWLF Page 1 of 1
Table 3
Field Parameter Data Summary
October 24, 2015
Parameter Temp.ORP DO pH TDS Turbidity
Units C mg/L SU visual %/vol
MW-2 6.35 16.3 NR NR 5.90 80 30 Clear NR
MW-3 0.00 17.3 NR NR 6.91 100 80 Clear NR
MW-4 8.90 14.9 NR NR 5.38 20 10 Moderate NR
MW-5 19.99 16.1 NR NR 4.86 10 0 Moderate NR
Minimum 0.00 14.9 NR NR 4.86 10 0 Clear NR
Average 8.81 16.2 NR NR 5.76 53 30 Slight NR
Maximum 19.99 17.3 NR NR 6.91 100 80 Moderate NR
NR = No Reading Attempted and not required
Depth to
Water
Water
Elevation
TOC
Elevation
Specific
Conductance
Methane Gas
in Well
Headspace
ft (btoc)ft (amsl)ft (amsl)mV цs/cm ppb
na na
na na
na na
na na
na na
na na
na na
Wayne County Closed MSWLF (Pikeville)Page 1 of 1
Table 4
Detections in Water Samples above Established SWSL, GWP, 2L or MCL (Appendix I)
October 24, 2015
Result Unit
MW-2 10/24/15 2.1 0.11 1 3 NE
MW-2 Cadmium, total 10/24/15 1.9 0.5 1 2 5
MW-3 Cadmium, total 10/24/15 2 0.5 1 2 5
MW-3 Copper, total 10/24/15 3 j (B)2.5 10 1000 NE
MW-4 Cadmium, total 10/24/15 3 0.5 1 2 5 N & S
MW-4 Cadmium, Dissolved 10/24/15 1.8 0.5 1 2 5
MW-4 Zinc, total 10/24/15 22.2 5 10 1000 5000
MW-4 Thallium, total 10/24/15 ND<5 5 10 NE 0.28 2
MW-4 Thallium, Dissolved 10/24/15 6.2 j 5 10 NE 0.28 2 A
MW-4 Zinc, Dissolved 10/24/15 7.2 j 2.5 10 1000 5000
MW-4 Copper, total 10/24/15 4.3 j (B)2.5 10 1000 NE
MW-4 Nickel, Dissolved 10/24/15 2.5 j 2.5 5 100 NE
MW-4 Beryllium, Dissolved 10/24/15 0.27 j (B)0.05 1 NE 4 NE
MW-4 Barium, total 10/24/15 ND<2.5 2.5 5 700 1300
MW-4 Barium, Dissolved 10/24/15 126 2.5 5 700 1300
MW-5 Cadmium, total 10/24/15 2.8 0.5 1 2 5 N & S
MW-5 Cadmium, Dissolved 10/24/15 1.4 0.5 1 2 5
MW-5 Thallium, total 10/24/15 ND<5 5 10 NE 0.28 2
MW-5 Thallium, Dissolved 10/24/15 6.9 j 5 10 NE 0.28 2 A
MW-5 Zinc, total 10/24/15 16.6 5 10 1000 5000
MW-5 Zinc, Dissolved 10/24/15 7.8 j 2.5 10 1000 5000
MW-5 Barium, total 10/24/15 212 2.5 100 700 1300
MW-5 Barium, Dissolved 10/24/15 111 2.5 5 700 1300
A definitive source of the detection was not determined as part of this report. Preliminary cause only listed pursuant to instructions
j =The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL),
adjusted for actual sample preparation data and moisture content, where applicable
N = Natural originating from erosion of natural deposits. Source not anthropogenic.
S = Sediment entrained in sample. As evidenced by results of dissolved samples
Concentration > 2L, 2B, GWP or MCL Standard
Sample
ID Parameter Name 1 Sample
Date MDL 2 SWSL 3 2L 4 GWP 5 MCL 6 Preliminary Cause 7
Chloromethane ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
1 Table contains constituents detected at or above SWSL, GWP, 2L, or MCL
2 MDL = Method Detection Limit
3 SWSL = Solid Waste Section Reporting Limit
4 2L = North Carolina 15A NCAC 2L Groundwater Quality Standard
5 GWP = Groundwater Protection Standard
6 MCL = Primary Drinking Water Standard (not currently applicable for regulatory comparisons)
7 Preliminary Cause = Refers to a preliminary analysis of the cause and/or source of a detection over the respective 2L/2B Standard.
(B) = Analyte also detected in the associated method blank so qualified by laboratory as such
A = Artifact Contamination originating from laboratory. Detected in dissolved lab filtered sample but not in total unfiltered. Thallium likely introduced by the lab filtration process.
BOLD =
Appendix A
Laboratory Analysis Reports
Chains of Custody
#=CL#
November 05, 2015
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92273348
92273348
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
PO Box 97
Garner, NC 27529
WAYNE CLOSED MSWLF (PIKEVILLE)
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on October 26, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 30
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 30
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Lab ID Sample ID Matrix Date Collected Date Received
92273348001 MW-2 Water 10/24/15 10:20 10/26/15 12:15
92273348002 MW-3 Water 10/24/15 11:20 10/26/15 12:15
92273348003 MW-4 Water 10/24/15 12:20 10/26/15 12:15
92273348004 MW-5 Water 10/24/15 13:35 10/26/15 12:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 30
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92273348001 MW-2 EPA 6010 15 PASI-AJMW
EPA 8260 51 PASI-CCAH
92273348002 MW-3 EPA 6010 15 PASI-ACDF
EPA 8260 51 PASI-CCAH
92273348003 MW-4 EPA 6010 15 PASI-ACDF
EPA 8260 51 PASI-CCAH
92273348004 MW-5 EPA 6010 15 PASI-AJMW
EPA 8260 51 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Sample:MW-2 Lab ID:92273348001 Collected:10/24/15 10:20 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 10/30/15 23:44 7440-36-010/28/15 20:006.0 3.8 1
Arsenic ND ug/L 10/30/15 23:44 7440-38-210/28/15 20:0010.0 2.5 1
Barium 35.4J ug/L 10/30/15 23:44 7440-39-310/28/15 20:001002.5 1
Beryllium ND ug/L 10/30/15 23:44 7440-41-710/28/15 20:001.0 0.50 1
Cadmium 1.9 ug/L 10/30/15 23:44 7440-43-910/28/15 20:001.0 0.50 1
Chromium ND ug/L 10/30/15 23:44 7440-47-310/28/15 20:0010.0 2.5 1
Cobalt ND ug/L 10/30/15 23:44 7440-48-410/28/15 20:0010.0 2.5 1
Copper 3.1J ug/L 10/30/15 23:44 7440-50-810/28/15 20:0010.0 2.5 1
Lead ND ug/L 10/30/15 23:44 7439-92-110/28/15 20:0010.0 2.5 1
Nickel ND ug/L 10/30/15 23:44 7440-02-010/28/15 20:0050.0 2.5 1
Selenium ND ug/L 10/30/15 23:44 7782-49-210/28/15 20:0010.0 5.0 1
Silver ND ug/L 10/30/15 23:44 7440-22-410/28/15 20:0010.0 2.5 1
Thallium ND ug/L 10/30/15 23:44 7440-28-010/28/15 20:005.5 5.0 1
Vanadium ND ug/L 10/30/15 23:44 7440-62-210/28/15 20:0025.0 2.5 1
Zinc 5.1J ug/L 10/30/15 23:44 7440-66-610/28/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 11/01/15 05:21 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 05:21 107-13-12001.9 1
Benzene ND ug/L 11/01/15 05:21 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 05:21 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 05:21 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 05:21 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 05:21 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 05:21 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 05:21 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 05:21 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 11/01/15 05:21 108-90-73.0 0.23 1
Chloroethane ND ug/L 11/01/15 05:21 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 05:21 67-66-35.0 0.14 1
Chloromethane 2.1 ug/L 11/01/15 05:21 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 05:21 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 05:21 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 05:21 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 05:21 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 05:21 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 11/01/15 05:21 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 05:21 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 11/01/15 05:21 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 11/01/15 05:21 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 05:21 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 11/01/15 05:21 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 05:21 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 11/01/15 05:21 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 05:21 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 05:21 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Sample:MW-2 Lab ID:92273348001 Collected:10/24/15 10:20 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 11/01/15 05:21 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 05:21 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 05:21 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 05:21 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 05:21 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 05:21 108-10-11000.33 1
Styrene ND ug/L 11/01/15 05:21 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 05:21 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 05:21 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 05:21 127-18-41.0 0.46 1
Toluene ND ug/L 11/01/15 05:21 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 05:21 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 05:21 79-00-51.0 0.29 1
Trichloroethene ND ug/L 11/01/15 05:21 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 05:21 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 05:21 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 05:21 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 11/01/15 05:21 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 11/01/15 05:21 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %11/01/15 05:21 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %11/01/15 05:21 17060-07-070-130 1
Toluene-d8 (S)100 %11/01/15 05:21 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Sample:MW-3 Lab ID:92273348002 Collected:10/24/15 11:20 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 11/04/15 19:53 7440-36-010/28/15 19:006.0 3.8 1
Arsenic ND ug/L 11/04/15 19:53 7440-38-210/28/15 19:0010.0 2.5 1
Barium 34.0J ug/L 11/04/15 19:53 7440-39-310/28/15 19:001002.5 1
Beryllium ND ug/L 11/04/15 19:53 7440-41-710/28/15 19:001.0 0.50 1
Cadmium 2.0 ug/L 11/04/15 19:53 7440-43-910/28/15 19:001.0 0.50 1
Chromium ND ug/L 11/04/15 19:53 7440-47-310/28/15 19:0010.0 2.5 1
Cobalt ND ug/L 11/04/15 19:53 7440-48-410/28/15 19:0010.0 2.5 1
Copper 3.0J ug/L 11/04/15 19:53 7440-50-8 B10/28/15 19:0010.0 2.5 1
Lead ND ug/L 11/04/15 19:53 7439-92-110/28/15 19:0010.0 2.5 1
Nickel ND ug/L 11/04/15 19:53 7440-02-010/28/15 19:0050.0 2.5 1
Selenium ND ug/L 11/04/15 19:53 7782-49-210/28/15 19:0010.0 5.0 1
Silver ND ug/L 11/04/15 19:53 7440-22-410/28/15 19:0010.0 2.5 1
Thallium ND ug/L 11/04/15 19:53 7440-28-010/28/15 19:005.5 5.0 1
Vanadium ND ug/L 11/04/15 19:53 7440-62-210/28/15 19:0025.0 2.5 1
Zinc 8.9J ug/L 11/04/15 19:53 7440-66-610/28/15 19:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 11/01/15 05:38 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 05:38 107-13-12001.9 1
Benzene ND ug/L 11/01/15 05:38 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 05:38 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 05:38 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 05:38 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 05:38 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 05:38 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 05:38 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 05:38 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 11/01/15 05:38 108-90-73.0 0.23 1
Chloroethane ND ug/L 11/01/15 05:38 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 05:38 67-66-35.0 0.14 1
Chloromethane ND ug/L 11/01/15 05:38 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 05:38 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 05:38 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 05:38 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 05:38 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 05:38 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 11/01/15 05:38 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 05:38 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 11/01/15 05:38 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 11/01/15 05:38 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 05:38 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 11/01/15 05:38 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 05:38 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 11/01/15 05:38 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 05:38 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 05:38 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Sample:MW-3 Lab ID:92273348002 Collected:10/24/15 11:20 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 11/01/15 05:38 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 05:38 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 05:38 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 05:38 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 05:38 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 05:38 108-10-11000.33 1
Styrene ND ug/L 11/01/15 05:38 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 05:38 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 05:38 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 05:38 127-18-41.0 0.46 1
Toluene ND ug/L 11/01/15 05:38 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 05:38 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 05:38 79-00-51.0 0.29 1
Trichloroethene ND ug/L 11/01/15 05:38 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 05:38 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 05:38 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 05:38 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 11/01/15 05:38 75-01-4 M11.0 0.62 1
Xylene (Total)ND ug/L 11/01/15 05:38 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %11/01/15 05:38 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %11/01/15 05:38 17060-07-070-130 1
Toluene-d8 (S)99 %11/01/15 05:38 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Sample:MW-4 Lab ID:92273348003 Collected:10/24/15 12:20 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 11/04/15 19:56 7440-36-010/28/15 19:006.0 3.8 1
Arsenic ND ug/L 11/04/15 19:56 7440-38-210/28/15 19:0010.0 2.5 1
Barium 76.1J ug/L 11/04/15 19:56 7440-39-310/28/15 19:001002.5 1
Beryllium ND ug/L 11/04/15 19:56 7440-41-710/28/15 19:001.0 0.50 1
Cadmium 3.0 ug/L 11/04/15 19:56 7440-43-910/28/15 19:001.0 0.50 1
Chromium ND ug/L 11/04/15 19:56 7440-47-310/28/15 19:0010.0 2.5 1
Cobalt ND ug/L 11/04/15 19:56 7440-48-410/28/15 19:0010.0 2.5 1
Copper 4.3J ug/L 11/04/15 19:56 7440-50-8 B10/28/15 19:0010.0 2.5 1
Lead 2.9J ug/L 11/04/15 19:56 7439-92-110/28/15 19:0010.0 2.5 1
Nickel ND ug/L 11/04/15 19:56 7440-02-010/28/15 19:0050.0 2.5 1
Selenium ND ug/L 11/04/15 19:56 7782-49-210/28/15 19:0010.0 5.0 1
Silver ND ug/L 11/04/15 19:56 7440-22-410/28/15 19:0010.0 2.5 1
Thallium ND ug/L 11/04/15 19:56 7440-28-010/28/15 19:005.5 5.0 1
Vanadium ND ug/L 11/04/15 19:56 7440-62-210/28/15 19:0025.0 2.5 1
Zinc 22.2 ug/L 11/04/15 19:56 7440-66-610/28/15 19:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 11/01/15 05:55 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 05:55 107-13-12001.9 1
Benzene ND ug/L 11/01/15 05:55 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 05:55 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 05:55 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 05:55 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 05:55 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 05:55 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 05:55 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 05:55 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 11/01/15 05:55 108-90-73.0 0.23 1
Chloroethane ND ug/L 11/01/15 05:55 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 05:55 67-66-35.0 0.14 1
Chloromethane ND ug/L 11/01/15 05:55 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 05:55 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 05:55 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 05:55 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 05:55 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 05:55 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 11/01/15 05:55 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 05:55 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 11/01/15 05:55 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 11/01/15 05:55 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 05:55 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 11/01/15 05:55 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 05:55 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 11/01/15 05:55 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 05:55 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 05:55 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Sample:MW-4 Lab ID:92273348003 Collected:10/24/15 12:20 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 11/01/15 05:55 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 05:55 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 05:55 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 05:55 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 05:55 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 05:55 108-10-11000.33 1
Styrene ND ug/L 11/01/15 05:55 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 05:55 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 05:55 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 05:55 127-18-41.0 0.46 1
Toluene ND ug/L 11/01/15 05:55 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 05:55 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 05:55 79-00-51.0 0.29 1
Trichloroethene ND ug/L 11/01/15 05:55 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 05:55 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 05:55 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 05:55 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 11/01/15 05:55 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 11/01/15 05:55 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %11/01/15 05:55 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %11/01/15 05:55 17060-07-070-130 1
Toluene-d8 (S)100 %11/01/15 05:55 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Sample:MW-5 Lab ID:92273348004 Collected:10/24/15 13:35 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 10/30/15 23:47 7440-36-010/28/15 20:006.0 3.8 1
Arsenic 4.1J ug/L 10/30/15 23:47 7440-38-210/28/15 20:0010.0 2.5 1
Barium 212 ug/L 10/30/15 23:47 7440-39-310/28/15 20:001002.5 1
Beryllium 0.54J ug/L 10/30/15 23:47 7440-41-710/28/15 20:001.0 0.50 1
Cadmium 2.8 ug/L 10/30/15 23:47 7440-43-910/28/15 20:001.0 0.50 1
Chromium 4.1J ug/L 10/30/15 23:47 7440-47-310/28/15 20:0010.0 2.5 1
Cobalt 4.3J ug/L 10/30/15 23:47 7440-48-410/28/15 20:0010.0 2.5 1
Copper 2.8J ug/L 10/30/15 23:47 7440-50-810/28/15 20:0010.0 2.5 1
Lead 5.2J ug/L 10/30/15 23:47 7439-92-110/28/15 20:0010.0 2.5 1
Nickel 5.7J ug/L 10/30/15 23:47 7440-02-010/28/15 20:0050.0 2.5 1
Selenium ND ug/L 10/30/15 23:47 7782-49-210/28/15 20:0010.0 5.0 1
Silver ND ug/L 10/30/15 23:47 7440-22-410/28/15 20:0010.0 2.5 1
Thallium ND ug/L 10/30/15 23:47 7440-28-010/28/15 20:005.5 5.0 1
Vanadium 2.8J ug/L 10/30/15 23:47 7440-62-210/28/15 20:0025.0 2.5 1
Zinc 16.6 ug/L 10/30/15 23:47 7440-66-610/28/15 20:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 11/01/15 06:28 67-64-110010.0 1
Acrylonitrile ND ug/L 11/01/15 06:28 107-13-12001.9 1
Benzene ND ug/L 11/01/15 06:28 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 11/01/15 06:28 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 11/01/15 06:28 75-27-41.0 0.18 1
Bromoform ND ug/L 11/01/15 06:28 75-25-23.0 0.26 1
Bromomethane ND ug/L 11/01/15 06:28 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 11/01/15 06:28 78-93-31000.96 1
Carbon disulfide ND ug/L 11/01/15 06:28 75-15-01001.2 1
Carbon tetrachloride ND ug/L 11/01/15 06:28 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 11/01/15 06:28 108-90-73.0 0.23 1
Chloroethane ND ug/L 11/01/15 06:28 75-00-310.0 0.54 1
Chloroform ND ug/L 11/01/15 06:28 67-66-35.0 0.14 1
Chloromethane ND ug/L 11/01/15 06:28 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 11/01/15 06:28 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 11/01/15 06:28 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 11/01/15 06:28 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/01/15 06:28 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 11/01/15 06:28 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 11/01/15 06:28 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 11/01/15 06:28 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 11/01/15 06:28 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 11/01/15 06:28 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 11/01/15 06:28 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 11/01/15 06:28 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 11/01/15 06:28 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 11/01/15 06:28 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 11/01/15 06:28 142-28-91.0 0.28 1
cis-1,3-Dichloropropene ND ug/L 11/01/15 06:28 10061-01-51.0 0.13 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Sample:MW-5 Lab ID:92273348004 Collected:10/24/15 13:35 Received:10/26/15 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
trans-1,3-Dichloropropene ND ug/L 11/01/15 06:28 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 11/01/15 06:28 100-41-41.0 0.30 1
2-Hexanone ND ug/L 11/01/15 06:28 591-78-650.0 0.46 1
Iodomethane ND ug/L 11/01/15 06:28 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 11/01/15 06:28 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/01/15 06:28 108-10-11000.33 1
Styrene ND ug/L 11/01/15 06:28 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 11/01/15 06:28 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 11/01/15 06:28 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 11/01/15 06:28 127-18-41.0 0.46 1
Toluene ND ug/L 11/01/15 06:28 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 11/01/15 06:28 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 11/01/15 06:28 79-00-51.0 0.29 1
Trichloroethene ND ug/L 11/01/15 06:28 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 11/01/15 06:28 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 11/01/15 06:28 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 11/01/15 06:28 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 11/01/15 06:28 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 11/01/15 06:28 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %11/01/15 06:28 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %11/01/15 06:28 17060-07-070-130 1
Toluene-d8 (S)100 %11/01/15 06:28 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/19905
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92273348001, 92273348004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1593024
Associated Lab Samples:92273348001, 92273348004
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 10/30/15 22:423.8
Arsenic ug/L ND 10.0 10/30/15 22:422.5
Barium ug/L ND 100 10/30/15 22:422.5
Beryllium ug/L ND 1.0 10/30/15 22:420.50
Cadmium ug/L ND 1.0 10/30/15 22:420.50
Chromium ug/L ND 10.0 10/30/15 22:422.5
Cobalt ug/L ND 10.0 10/30/15 22:422.5
Copper ug/L ND 10.0 10/30/15 22:422.5
Lead ug/L ND 10.0 10/30/15 22:422.5
Nickel ug/L ND 50.0 10/30/15 22:422.5
Selenium ug/L ND 10.0 10/30/15 22:425.0
Silver ug/L ND 10.0 10/30/15 22:422.5
Thallium ug/L ND 5.5 10/30/15 22:425.0
Vanadium ug/L ND 25.0 10/30/15 22:422.5
Zinc ug/L ND 10.0 10/30/15 22:425.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1593025LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 491500 98 80-120
Arsenic ug/L 464500 93 80-120
Barium ug/L 479500 96 80-120
Beryllium ug/L 487500 97 80-120
Cadmium ug/L 482500 96 80-120
Chromium ug/L 474500 95 80-120
Cobalt ug/L 467500 93 80-120
Copper ug/L 494500 99 80-120
Lead ug/L 471500 94 80-120
Nickel ug/L 469500 94 80-120
Selenium ug/L 466500 93 80-120
Silver ug/L 237250 95 80-120
Thallium ug/L 465500 93 80-120
Vanadium ug/L 481500 96 80-120
Zinc ug/L 445500 89 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1593026MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273337001
1593027
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 106 75-12592 13 25500ND530464
Arsenic ug/L 500 101 75-12588 13 25500ND504441
Barium ug/L 500 107 75-12593 12 2550074.1J 607 539
Beryllium ug/L 500 109 75-12595 13 25500ND543475
Cadmium ug/L 500 105 75-12592 13 25500ND527461
Chromium ug/L 500 105 75-12593 13 25500ND528465
Cobalt ug/L 500 103 75-12591 13 25500ND517453
Copper ug/L 500 109 75-12594 15 25500ND544469
Lead ug/L 500 104 75-12590 13 25500ND518452
Nickel ug/L 500 104 75-12591 13 25500ND522457
Selenium ug/L 500 101 75-12588 14 25500ND505441
Silver ug/L 250 105 75-12591 14 25250ND262228
Thallium ug/L 500 102 75-12589 13 25500ND509446
Vanadium ug/L 500 108 75-12595 13 25500ND538473
Zinc ug/L 500 101 75-12588 13 25500ND506443
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/19918
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92273348002, 92273348003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1594175
Associated Lab Samples:92273348002, 92273348003
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 11/04/15 19:093.8
Arsenic ug/L ND 10.0 11/04/15 19:092.5
Barium ug/L ND 100 11/04/15 19:092.5
Beryllium ug/L ND 1.0 11/04/15 19:090.50
Cadmium ug/L ND 1.0 11/04/15 19:090.50
Chromium ug/L 2.7J 10.0 11/04/15 19:092.5
Cobalt ug/L ND 10.0 11/04/15 19:092.5
Copper ug/L 3.3J 10.0 11/04/15 19:092.5
Lead ug/L ND 10.0 11/04/15 19:092.5
Nickel ug/L ND 50.0 11/04/15 19:092.5
Selenium ug/L ND 10.0 11/04/15 19:095.0
Silver ug/L ND 10.0 11/04/15 19:092.5
Thallium ug/L ND 5.5 11/04/15 19:095.0
Vanadium ug/L ND 25.0 11/04/15 19:092.5
Zinc ug/L ND 10.0 11/04/15 19:095.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1594176LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 452500 90 80-120
Arsenic ug/L 485500 97 80-120
Barium ug/L 471500 94 80-120
Beryllium ug/L 455500 91 80-120
Cadmium ug/L 469500 94 80-120
Chromium ug/L 478500 96 80-120
Cobalt ug/L 487500 97 80-120
Copper ug/L 493500 99 80-120
Lead ug/L 485500 97 80-120
Nickel ug/L 471500 94 80-120
Selenium ug/L 475500 95 80-120
Silver ug/L 218250 87 80-120
Thallium ug/L 445500 89 80-120
Vanadium ug/L 461500 92 80-120
Zinc ug/L 501500 100 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1594177MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92273330003
1594178
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 91 75-125105 14 25500ND459530
Arsenic ug/L 500 98 75-125115 15 25500ND493573
Barium ug/L 500 97 75-125116 7 2550083713201420
Beryllium ug/L 500 92 75-125108 15 25500ND461538
Cadmium ug/L 500 95 75-125109 14 25500ND474547
Chromium ug/L 500 94 75-125110 16 255003.4J 473 555
Cobalt ug/L 500 93 75-125108 15 2550011.7 477 553
Copper ug/L 500 99 75-125114 14 25500ND496572
Lead ug/L 500 92 75-125107 15 25500ND463537
Nickel ug/L 500 90 75-125104 15 255008.4J 458 531
Selenium ug/L 500 96 75-125110 14 25500ND479551
Silver ug/L 250 88 75-125101 15 25250ND220255
Thallium ug/L 500 82 75-12595 16 25500ND408477
Vanadium ug/L 500 93 75-125109 16 255005.9J 470 549
Zinc ug/L 500 95 75-125112 16 25500ND478562
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
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Page 16 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34086
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92273348001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596340
Associated Lab Samples:92273348001
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 11/01/15 00:130.33
1,1,1-Trichloroethane ug/L ND 1.0 11/01/15 00:130.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 11/01/15 00:130.40
1,1,2-Trichloroethane ug/L ND 1.0 11/01/15 00:130.29
1,1-Dichloroethane ug/L ND 5.0 11/01/15 00:130.32
1,1-Dichloroethene ug/L ND 5.0 11/01/15 00:130.56
1,2,3-Trichloropropane ug/L ND 1.0 11/01/15 00:130.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 11/01/15 00:132.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 11/01/15 00:130.27
1,2-Dichlorobenzene ug/L ND 5.0 11/01/15 00:130.30
1,2-Dichloroethane ug/L ND 1.0 11/01/15 00:130.24
1,2-Dichloropropane ug/L ND 1.0 11/01/15 00:130.27
1,3-Dichloropropane ug/L ND 1.0 11/01/15 00:130.28
1,4-Dichlorobenzene ug/L ND 1.0 11/01/15 00:130.33
2-Butanone (MEK)ug/L ND 100 11/01/15 00:130.96
2-Hexanone ug/L ND 50.0 11/01/15 00:130.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 11/01/15 00:130.33
Acetone ug/L ND 100 11/01/15 00:1310.0
Acrylonitrile ug/L ND 200 11/01/15 00:131.9
Benzene ug/L ND 1.0 11/01/15 00:130.25
Bromochloromethane ug/L ND 3.0 11/01/15 00:130.17
Bromodichloromethane ug/L ND 1.0 11/01/15 00:130.18
Bromoform ug/L ND 3.0 11/01/15 00:130.26
Bromomethane ug/L ND 10.0 11/01/15 00:130.29
Carbon disulfide ug/L ND 100 11/01/15 00:131.2
Carbon tetrachloride ug/L ND 1.0 11/01/15 00:130.25
Chlorobenzene ug/L ND 3.0 11/01/15 00:130.23
Chloroethane ug/L ND 10.0 11/01/15 00:130.54
Chloroform ug/L ND 5.0 11/01/15 00:130.14
Chloromethane ug/L ND 1.0 11/01/15 00:130.11
cis-1,2-Dichloroethene ug/L ND 5.0 11/01/15 00:130.19
cis-1,3-Dichloropropene ug/L ND 1.0 11/01/15 00:130.13
Dibromochloromethane ug/L ND 3.0 11/01/15 00:130.21
Dibromomethane ug/L ND 10.0 11/01/15 00:130.21
Ethylbenzene ug/L ND 1.0 11/01/15 00:130.30
Iodomethane ug/L ND 10.0 11/01/15 00:130.32
Methylene Chloride ug/L ND 1.0 11/01/15 00:130.97
Styrene ug/L ND 1.0 11/01/15 00:130.26
Tetrachloroethene ug/L ND 1.0 11/01/15 00:130.46
Toluene ug/L ND 1.0 11/01/15 00:130.26
trans-1,2-Dichloroethene ug/L ND 5.0 11/01/15 00:130.49
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
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Page 17 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596340
Associated Lab Samples:92273348001
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 11/01/15 00:130.26
trans-1,4-Dichloro-2-butene ug/L ND 100 11/01/15 00:131.0
Trichloroethene ug/L ND 1.0 11/01/15 00:130.47
Trichlorofluoromethane ug/L ND 1.0 11/01/15 00:130.20
Vinyl acetate ug/L ND 50.0 11/01/15 00:130.35
Vinyl chloride ug/L ND 1.0 11/01/15 00:130.62
Xylene (Total)ug/L ND 5.0 11/01/15 00:130.66
1,2-Dichloroethane-d4 (S)%102 70-130 11/01/15 00:13
4-Bromofluorobenzene (S)%101 70-130 11/01/15 00:13
Toluene-d8 (S)%100 70-130 11/01/15 00:13
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596341LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 51.750 103 80-125
1,1,1-Trichloroethane ug/L 53.950 108 71-129
1,1,2,2-Tetrachloroethane ug/L 51.550 103 79-124
1,1,2-Trichloroethane ug/L 49.350 99 85-125
1,1-Dichloroethane ug/L 53.350 107 73-126
1,1-Dichloroethene ug/L 56.250 112 66-135
1,2,3-Trichloropropane ug/L 49.150 98 75-130
1,2-Dibromo-3-chloropropane ug/L 50.650 101 71-133
1,2-Dibromoethane (EDB)ug/L 51.050 102 83-124
1,2-Dichlorobenzene ug/L 51.150 102 80-133
1,2-Dichloroethane ug/L 46.750 93 67-128
1,2-Dichloropropane ug/L 50.550 101 75-132
1,3-Dichloropropane ug/L 51.350 103 76-131
1,4-Dichlorobenzene ug/L 50.350 101 78-130
2-Butanone (MEK)ug/L 98.2J100 98 61-144
2-Hexanone ug/L 102100 102 68-143
4-Methyl-2-pentanone (MIBK)ug/L 102100 102 72-135
Acetone ug/L 98.4J100 98 48-146
Acrylonitrile ug/L 253250 101 40-160
Benzene ug/L 52.550 105 80-125
Bromochloromethane ug/L 53.750 107 71-125
Bromodichloromethane ug/L 53.150 106 78-124
Bromoform ug/L 50.750 101 71-128
Bromomethane ug/L 50.150 100 40-160
Carbon disulfide ug/L 54.4J50 109 50-160
Carbon tetrachloride ug/L 55.450 111 69-131
Chlorobenzene ug/L 50.550 101 81-122
Chloroethane ug/L 50.650 101 39-148
Chloroform ug/L 52.250 104 73-127
Chloromethane ug/L 50.150 100 44-146
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
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Page 18 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596341LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 51.250 102 74-124
cis-1,3-Dichloropropene ug/L 51.150 102 72-132
Dibromochloromethane ug/L 53.150 106 78-125
Dibromomethane ug/L 50.150 100 82-120
Ethylbenzene ug/L 51.950 104 79-121
Iodomethane ug/L 102100 102 39-154
Methylene Chloride ug/L 55.850 112 64-133
Styrene ug/L 52.150 104 84-126
Tetrachloroethene ug/L 51.850 104 78-122
Toluene ug/L 51.550 103 80-121
trans-1,2-Dichloroethene ug/L 52.950 106 71-127
trans-1,3-Dichloropropene ug/L 50.850 102 69-141
trans-1,4-Dichloro-2-butene ug/L 59.8J50 120 40-160
Trichloroethene ug/L 49.450 99 78-122
Trichlorofluoromethane ug/L 53.850 108 53-137
Vinyl acetate ug/L 105100 105 40-160
Vinyl chloride ug/L 59.150 118 58-137
Xylene (Total)ug/L 155150 103 81-126
1,2-Dichloroethane-d4 (S)%97 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596342MATRIX SPIKE SAMPLE:
MSSpike
Result
92273330003
1,1,1,2-Tetrachloroethane ug/L 21.620 108 70-130ND
1,1,1-Trichloroethane ug/L 24.420 122 70-130ND
1,1,2,2-Tetrachloroethane ug/L 21.420 107 70-130ND
1,1,2-Trichloroethane ug/L 21.220 106 70-130ND
1,1-Dichloroethane ug/L 34.220 123 70-1309.6
1,1-Dichloroethene ug/L 26.020 130 70-166ND
1,2,3-Trichloropropane ug/L 20.720 103 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.720 98 70-130ND
1,2-Dibromoethane (EDB)ug/L 21.820 109 70-130ND
1,2-Dichlorobenzene ug/L 22.120 109 70-1300.37J
1,2-Dichloroethane ug/L 20.420 100 70-1300.35J
1,2-Dichloropropane ug/L 22.220 111 70-130ND
1,3-Dichloropropane ug/L 21.920 110 70-130ND
1,4-Dichlorobenzene ug/L 25.720 110 70-1303.8
2-Butanone (MEK)ug/L 40.9J40 101 70-130ND
2-Hexanone ug/L 41.5J40 104 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 42.8J40 107 70-130ND
Acetone ug/L 45.9J40 103 70-130ND
Acrylonitrile ug/L 109J100 109 70-130ND
Benzene ug/L 27.720 117 70-1484.2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
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[phone]
Page 19 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596342MATRIX SPIKE SAMPLE:
MSSpike
Result
92273330003
Bromochloromethane ug/L 24.320 122 70-130ND
Bromodichloromethane ug/L 22.020 110 70-130ND
Bromoform ug/L 18.720 94 70-130ND
Bromomethane ug/L 17.420 87 70-130ND
Carbon disulfide ug/L 23.9J20 120 70-130ND
Carbon tetrachloride ug/L 24.320 121 70-130ND
Chlorobenzene ug/L 23.420 111 70-1461.1J
Chloroethane ug/L 44.720 123 70-13020.1
Chloroform ug/L 23.420 117 70-130ND
Chloromethane ug/L 25.120 126 70-130ND
cis-1,2-Dichloroethene ug/L 23.420 115 70-1300.44J
cis-1,3-Dichloropropene ug/L 20.420 102 70-130ND
Dibromochloromethane ug/L 21.020 105 70-130ND
Dibromomethane ug/L 21.120 106 70-130ND
Ethylbenzene ug/L 22.720 112 70-130ND
Iodomethane ug/L 34.840 87 70-130ND
Methylene Chloride ug/L 24.620 123 70-130ND
Styrene ug/L 21.720 109 70-130ND
Tetrachloroethene ug/L 22.720 114 70-130ND
Toluene ug/L 23.320 113 70-1550.65J
trans-1,2-Dichloroethene ug/L 24.420 121 70-130ND
trans-1,3-Dichloropropene ug/L 20.420 102 70-130ND
trans-1,4-Dichloro-2-butene ug/L 16.1J20 81 70-130ND
Trichloroethene ug/L 22.320 112 69-151ND
Trichlorofluoromethane ug/L 25.820 129 70-130ND
Vinyl acetate ug/L 34.8J40 87 70-130ND
Vinyl chloride ug/L 27.9 M12013870-130ND
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273335001
1596343SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 62.2 4 3060.1
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L 0.42J 300.42J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
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[phone]
Page 20 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273335001
1596343SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 2.7 6 302.6
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L 6.9 3 306.7
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 0.23J 30ND
Chloroethane ug/L 1.1J 300.89J
Chloroform ug/L ND 30ND
Chloromethane ug/L 2.2 1 302.1
cis-1,2-Dichloroethene ug/L 55.7 4 3053.4
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L 1.2 7 301.1
Trichlorofluoromethane ug/L ND 300.21J
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L 2.9 5 302.8
Xylene (Total)ug/L 1.2J 301.1J
1,2-Dichloroethane-d4 (S)%101 1100
4-Bromofluorobenzene (S)%99 099
Toluene-d8 (S)%101 1100
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
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Huntersville, NC 28078
[phone]
Page 21 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34087
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92273348002, 92273348003, 92273348004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596344
Associated Lab Samples:92273348002, 92273348003, 92273348004
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 11/01/15 00:300.33
1,1,1-Trichloroethane ug/L ND 1.0 11/01/15 00:300.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 11/01/15 00:300.40
1,1,2-Trichloroethane ug/L ND 1.0 11/01/15 00:300.29
1,1-Dichloroethane ug/L ND 5.0 11/01/15 00:300.32
1,1-Dichloroethene ug/L ND 5.0 11/01/15 00:300.56
1,2,3-Trichloropropane ug/L ND 1.0 11/01/15 00:300.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 11/01/15 00:302.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 11/01/15 00:300.27
1,2-Dichlorobenzene ug/L ND 5.0 11/01/15 00:300.30
1,2-Dichloroethane ug/L ND 1.0 11/01/15 00:300.24
1,2-Dichloropropane ug/L ND 1.0 11/01/15 00:300.27
1,3-Dichloropropane ug/L ND 1.0 11/01/15 00:300.28
1,4-Dichlorobenzene ug/L ND 1.0 11/01/15 00:300.33
2-Butanone (MEK)ug/L ND 100 11/01/15 00:300.96
2-Hexanone ug/L ND 50.0 11/01/15 00:300.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 11/01/15 00:300.33
Acetone ug/L ND 100 11/01/15 00:3010.0
Acrylonitrile ug/L ND 200 11/01/15 00:301.9
Benzene ug/L ND 1.0 11/01/15 00:300.25
Bromochloromethane ug/L ND 3.0 11/01/15 00:300.17
Bromodichloromethane ug/L ND 1.0 11/01/15 00:300.18
Bromoform ug/L ND 3.0 11/01/15 00:300.26
Bromomethane ug/L ND 10.0 11/01/15 00:300.29
Carbon disulfide ug/L ND 100 11/01/15 00:301.2
Carbon tetrachloride ug/L ND 1.0 11/01/15 00:300.25
Chlorobenzene ug/L ND 3.0 11/01/15 00:300.23
Chloroethane ug/L ND 10.0 11/01/15 00:300.54
Chloroform ug/L ND 5.0 11/01/15 00:300.14
Chloromethane ug/L ND 1.0 11/01/15 00:300.11
cis-1,2-Dichloroethene ug/L ND 5.0 11/01/15 00:300.19
cis-1,3-Dichloropropene ug/L ND 1.0 11/01/15 00:300.13
Dibromochloromethane ug/L ND 3.0 11/01/15 00:300.21
Dibromomethane ug/L ND 10.0 11/01/15 00:300.21
Ethylbenzene ug/L ND 1.0 11/01/15 00:300.30
Iodomethane ug/L ND 10.0 11/01/15 00:300.32
Methylene Chloride ug/L ND 1.0 11/01/15 00:300.97
Styrene ug/L ND 1.0 11/01/15 00:300.26
Tetrachloroethene ug/L ND 1.0 11/01/15 00:300.46
Toluene ug/L ND 1.0 11/01/15 00:300.26
trans-1,2-Dichloroethene ug/L ND 5.0 11/01/15 00:300.49
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 11/05/2015 03:08 PM
Pace Analytical Services, Inc.
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[phone]
Page 22 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596344
Associated Lab Samples:92273348002, 92273348003, 92273348004
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 11/01/15 00:300.26
trans-1,4-Dichloro-2-butene ug/L ND 100 11/01/15 00:301.0
Trichloroethene ug/L ND 1.0 11/01/15 00:300.47
Trichlorofluoromethane ug/L ND 1.0 11/01/15 00:300.20
Vinyl acetate ug/L ND 50.0 11/01/15 00:300.35
Vinyl chloride ug/L ND 1.0 11/01/15 00:300.62
Xylene (Total)ug/L ND 5.0 11/01/15 00:300.66
1,2-Dichloroethane-d4 (S)%101 70-130 11/01/15 00:30
4-Bromofluorobenzene (S)%100 70-130 11/01/15 00:30
Toluene-d8 (S)%101 70-130 11/01/15 00:30
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596345LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.050 100 80-125
1,1,1-Trichloroethane ug/L 53.250 106 71-129
1,1,2,2-Tetrachloroethane ug/L 50.950 102 79-124
1,1,2-Trichloroethane ug/L 48.250 96 85-125
1,1-Dichloroethane ug/L 52.350 105 73-126
1,1-Dichloroethene ug/L 55.250 110 66-135
1,2,3-Trichloropropane ug/L 49.150 98 75-130
1,2-Dibromo-3-chloropropane ug/L 50.450 101 71-133
1,2-Dibromoethane (EDB)ug/L 50.750 101 83-124
1,2-Dichlorobenzene ug/L 50.750 101 80-133
1,2-Dichloroethane ug/L 45.950 92 67-128
1,2-Dichloropropane ug/L 49.850 100 75-132
1,3-Dichloropropane ug/L 50.350 101 76-131
1,4-Dichlorobenzene ug/L 49.550 99 78-130
2-Butanone (MEK)ug/L 98.6J100 99 61-144
2-Hexanone ug/L 101100 101 68-143
4-Methyl-2-pentanone (MIBK)ug/L 101100 101 72-135
Acetone ug/L 97.6J100 98 48-146
Acrylonitrile ug/L 253250 101 40-160
Benzene ug/L 51.350 103 80-125
Bromochloromethane ug/L 53.050 106 71-125
Bromodichloromethane ug/L 52.650 105 78-124
Bromoform ug/L 50.250 100 71-128
Bromomethane ug/L 48.950 98 40-160
Carbon disulfide ug/L 53.4J50 107 50-160
Carbon tetrachloride ug/L 54.150 108 69-131
Chlorobenzene ug/L 49.150 98 81-122
Chloroethane ug/L 48.650 97 39-148
Chloroform ug/L 51.750 103 73-127
Chloromethane ug/L 50.650 101 44-146
REPORT OF LABORATORY ANALYSIS
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Page 23 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596345LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 50.150 100 74-124
cis-1,3-Dichloropropene ug/L 50.650 101 72-132
Dibromochloromethane ug/L 51.850 104 78-125
Dibromomethane ug/L 49.950 100 82-120
Ethylbenzene ug/L 50.350 101 79-121
Iodomethane ug/L 102100 102 39-154
Methylene Chloride ug/L 54.550 109 64-133
Styrene ug/L 51.050 102 84-126
Tetrachloroethene ug/L 50.550 101 78-122
Toluene ug/L 50.650 101 80-121
trans-1,2-Dichloroethene ug/L 52.050 104 71-127
trans-1,3-Dichloropropene ug/L 50.450 101 69-141
trans-1,4-Dichloro-2-butene ug/L 61.0J50 122 40-160
Trichloroethene ug/L 48.650 97 78-122
Trichlorofluoromethane ug/L 52.850 106 53-137
Vinyl acetate ug/L 104100 104 40-160
Vinyl chloride ug/L 59.450 119 58-137
Xylene (Total)ug/L 151150 101 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596346MATRIX SPIKE SAMPLE:
MSSpike
Result
92273348002
1,1,1,2-Tetrachloroethane ug/L 21.020 105 70-130ND
1,1,1-Trichloroethane ug/L 24.320 121 70-130ND
1,1,2,2-Tetrachloroethane ug/L 21.720 108 70-130ND
1,1,2-Trichloroethane ug/L 20.620 103 70-130ND
1,1-Dichloroethane ug/L 23.620 118 70-130ND
1,1-Dichloroethene ug/L 25.720 128 70-166ND
1,2,3-Trichloropropane ug/L 20.720 104 70-130ND
1,2-Dibromo-3-chloropropane ug/L 20.520 103 70-130ND
1,2-Dibromoethane (EDB)ug/L 21.320 107 70-130ND
1,2-Dichlorobenzene ug/L 21.920 109 70-130ND
1,2-Dichloroethane ug/L 20.020 99 70-130ND
1,2-Dichloropropane ug/L 21.620 108 70-130ND
1,3-Dichloropropane ug/L 21.520 107 70-130ND
1,4-Dichlorobenzene ug/L 21.820 109 70-130ND
2-Butanone (MEK)ug/L 43.4J40 108 70-130ND
2-Hexanone ug/L 44.3J40 111 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 43.6J40 109 70-130ND
Acetone ug/L 48.6J40 115 70-130ND
Acrylonitrile ug/L 109J100 109 70-130ND
Benzene ug/L 22.620 113 70-148ND
REPORT OF LABORATORY ANALYSIS
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Page 24 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1596346MATRIX SPIKE SAMPLE:
MSSpike
Result
92273348002
Bromochloromethane ug/L 23.620 118 70-130ND
Bromodichloromethane ug/L 21.720 109 70-130ND
Bromoform ug/L 18.920 95 70-130ND
Bromomethane ug/L 19.920 99 70-130ND
Carbon disulfide ug/L 23.8J20 119 70-130ND
Carbon tetrachloride ug/L 23.920 119 70-130ND
Chlorobenzene ug/L 21.920 109 70-146ND
Chloroethane ug/L 23.520 118 70-130ND
Chloroform ug/L 23.020 115 70-130ND
Chloromethane ug/L 24.220 121 70-130ND
cis-1,2-Dichloroethene ug/L 22.520 112 70-130ND
cis-1,3-Dichloropropene ug/L 20.220 101 70-130ND
Dibromochloromethane ug/L 20.720 103 70-130ND
Dibromomethane ug/L 21.120 106 70-130ND
Ethylbenzene ug/L 22.320 112 70-130ND
Iodomethane ug/L 41.140 103 70-130ND
Methylene Chloride ug/L 23.120 115 70-130ND
Styrene ug/L 20.420 102 70-130ND
Tetrachloroethene ug/L 22.820 114 70-130ND
Toluene ug/L 21.920 110 70-155ND
trans-1,2-Dichloroethene ug/L 23.620 118 70-130ND
trans-1,3-Dichloropropene ug/L 19.720 99 70-130ND
trans-1,4-Dichloro-2-butene ug/L 16.9J20 85 70-130ND
Trichloroethene ug/L 21.520 107 69-151ND
Trichlorofluoromethane ug/L 25.320 126 70-130ND
Vinyl acetate ug/L 37.5J40 94 70-130ND
Vinyl chloride ug/L 27.4 M12013770-130ND
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273348003
1596347SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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Page 25 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92273348003
1596347SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%100 1101
4-Bromofluorobenzene (S)%98 199
Toluene-d8 (S)%99 1100
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Page 26 of 30
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Analyte was detected in the associated method blank.B
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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Page 27 of 30
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92273348
WAYNE CLOSED MSWLF (PIKEVILLE)
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92273348001 MPRP/19905 ICP/17945MW-2 EPA 3010 EPA 6010
92273348002 MPRP/19918 ICP/17958MW-3 EPA 3010 EPA 6010
92273348003 MPRP/19918 ICP/17958MW-4 EPA 3010 EPA 6010
92273348004 MPRP/19905 ICP/17945MW-5 EPA 3010 EPA 6010
92273348001 MSV/34086MW-2 EPA 8260
92273348002 MSV/34087MW-3 EPA 8260
92273348003 MSV/34087MW-4 EPA 8260
92273348004 MSV/34087MW-5 EPA 8260
REPORT OF LABORATORY ANALYSIS
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Page 28 of 30
Page 29 of 30
Page 30 of 30
#=CL#
December 17, 2015
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92279139
92279139
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
PO Box 97
Garner, NC 27529
WAYNE CLOSED MSWLF (PIKEVILLE)
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on December 09, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
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Page 1 of 12
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92279139
WAYNE CLOSED MSWLF (PIKEVILLE)
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001
West Virginia Certification #: 356Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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Page 2 of 12
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92279139
WAYNE CLOSED MSWLF (PIKEVILLE)
Lab ID Sample ID Matrix Date Collected Date Received
92279139001 MW-4 Water 10/24/15 12:20 12/09/15 09:40
92279139002 MW-5 Water 10/24/15 13:35 12/09/15 09:40
REPORT OF LABORATORY ANALYSIS
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Page 3 of 12
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92279139
WAYNE CLOSED MSWLF (PIKEVILLE)
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92279139001 MW-4 EPA 6010 15 PASI-ACDF
92279139002 MW-5 EPA 6010 15 PASI-ACDF
REPORT OF LABORATORY ANALYSIS
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Page 4 of 12
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279139
WAYNE CLOSED MSWLF (PIKEVILLE)
Sample:MW-4 Lab ID:92279139001 Collected:10/24/15 12:20 Received:12/09/15 09:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP, Dissolved
Antimony, Dissolved ND ug/L 12/17/15 00:16 7440-36-012/11/15 22:325.0 3.8 1
Arsenic, Dissolved ND ug/L 12/17/15 00:16 7440-38-212/11/15 22:3210.0 5.0 1
Barium, Dissolved 126 ug/L 12/17/15 00:16 7440-39-312/11/15 22:325.0 2.5 1
Beryllium, Dissolved 0.27J ug/L 12/17/15 00:16 7440-41-7 B12/11/15 22:321.0 0.050 1
Cadmium, Dissolved 1.8 ug/L 12/17/15 00:16 7440-43-912/11/15 22:321.0 0.50 1
Chromium, Dissolved ND ug/L 12/17/15 00:16 7440-47-312/11/15 22:325.0 2.5 1
Cobalt, Dissolved ND ug/L 12/17/15 00:16 7440-48-412/11/15 22:325.0 2.5 1
Copper, Dissolved ND ug/L 12/17/15 00:16 7440-50-812/11/15 22:325.0 2.5 1
Lead, Dissolved ND ug/L 12/17/15 00:16 7439-92-112/11/15 22:325.0 2.5 1
Nickel, Dissolved 2.5J ug/L 12/17/15 00:16 7440-02-012/11/15 22:325.0 2.5 1
Selenium, Dissolved ND ug/L 12/17/15 00:16 7782-49-212/11/15 22:3210.0 5.0 1
Silver, Dissolved ND ug/L 12/17/15 00:16 7440-22-412/11/15 22:325.0 2.5 1
Thallium, Dissolved 6.2J ug/L 12/17/15 00:16 7440-28-012/11/15 22:3210.0 5.0 1
Vanadium, Dissolved ND ug/L 12/17/15 00:16 7440-62-212/11/15 22:325.0 2.5 1
Zinc, Dissolved 7.2J ug/L 12/17/15 00:16 7440-66-612/11/15 22:3210.0 2.5 1
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92279139
WAYNE CLOSED MSWLF (PIKEVILLE)
Sample:MW-5 Lab ID:92279139002 Collected:10/24/15 13:35 Received:12/09/15 09:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP, Dissolved
Antimony, Dissolved ND ug/L 12/17/15 00:25 7440-36-012/11/15 22:325.0 3.8 1
Arsenic, Dissolved ND ug/L 12/17/15 00:25 7440-38-212/11/15 22:3210.0 5.0 1
Barium, Dissolved 111 ug/L 12/17/15 00:25 7440-39-312/11/15 22:325.0 2.5 1
Beryllium, Dissolved 0.38J ug/L 12/17/15 00:25 7440-41-7 B12/11/15 22:321.0 0.050 1
Cadmium, Dissolved 1.4 ug/L 12/17/15 00:25 7440-43-912/11/15 22:321.0 0.50 1
Chromium, Dissolved ND ug/L 12/17/15 00:25 7440-47-312/11/15 22:325.0 2.5 1
Cobalt, Dissolved ND ug/L 12/17/15 00:25 7440-48-412/11/15 22:325.0 2.5 1
Copper, Dissolved ND ug/L 12/17/15 00:25 7440-50-812/11/15 22:325.0 2.5 1
Lead, Dissolved ND ug/L 12/17/15 00:25 7439-92-112/11/15 22:325.0 2.5 1
Nickel, Dissolved ND ug/L 12/17/15 00:25 7440-02-012/11/15 22:325.0 2.5 1
Selenium, Dissolved ND ug/L 12/17/15 00:25 7782-49-212/11/15 22:3210.0 5.0 1
Silver, Dissolved ND ug/L 12/17/15 00:25 7440-22-412/11/15 22:325.0 2.5 1
Thallium, Dissolved 6.9J ug/L 12/17/15 00:25 7440-28-012/11/15 22:3210.0 5.0 1
Vanadium, Dissolved ND ug/L 12/17/15 00:25 7440-62-212/11/15 22:325.0 2.5 1
Zinc, Dissolved 7.8J ug/L 12/17/15 00:25 7440-66-612/11/15 22:3210.0 2.5 1
REPORT OF LABORATORY ANALYSIS
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Page 6 of 12
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279139
WAYNE CLOSED MSWLF (PIKEVILLE)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/20264
EPA 3010
EPA 6010
6010 MET Filtered Diss.
Associated Lab Samples:92279139001, 92279139002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1627278
Associated Lab Samples:92279139001, 92279139002
Matrix:Water
AnalyzedMDL
Antimony, Dissolved ug/L ND 5.0 12/17/15 00:103.8
Arsenic, Dissolved ug/L ND 10.0 12/17/15 00:105.0
Barium, Dissolved ug/L ND 5.0 12/17/15 00:102.5
Beryllium, Dissolved ug/L 0.052J 1.0 12/17/15 00:100.050
Cadmium, Dissolved ug/L ND 1.0 12/17/15 00:100.50
Chromium, Dissolved ug/L ND 5.0 12/17/15 00:102.5
Cobalt, Dissolved ug/L ND 5.0 12/17/15 00:102.5
Copper, Dissolved ug/L ND 5.0 12/17/15 00:102.5
Lead, Dissolved ug/L ND 5.0 12/17/15 00:102.5
Nickel, Dissolved ug/L ND 5.0 12/17/15 00:102.5
Selenium, Dissolved ug/L ND 10.0 12/17/15 00:105.0
Silver, Dissolved ug/L ND 5.0 12/17/15 00:102.5
Thallium, Dissolved ug/L ND 10.0 12/17/15 00:105.0
Vanadium, Dissolved ug/L ND 5.0 12/17/15 00:102.5
Zinc, Dissolved ug/L ND 10.0 12/17/15 00:102.5
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1627279LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony, Dissolved ug/L 538500 108 80-120
Arsenic, Dissolved ug/L 478500 96 80-120
Barium, Dissolved ug/L 476500 95 80-120
Beryllium, Dissolved ug/L 470500 94 80-120
Cadmium, Dissolved ug/L 492500 98 80-120
Chromium, Dissolved ug/L 462500 92 80-120
Cobalt, Dissolved ug/L 498500 100 80-120
Copper, Dissolved ug/L 479500 96 80-120
Lead, Dissolved ug/L 496500 99 80-120
Nickel, Dissolved ug/L 492500 98 80-120
Selenium, Dissolved ug/L 497500 99 80-120
Silver, Dissolved ug/L 251250 101 80-120
Thallium, Dissolved ug/L 472500 94 80-120
Vanadium, Dissolved ug/L 518500 104 80-120
Zinc, Dissolved ug/L 507500 101 80-120
REPORT OF LABORATORY ANALYSIS
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Page 7 of 12
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92279139
WAYNE CLOSED MSWLF (PIKEVILLE)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1627280MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92279139001
1627281
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony, Dissolved ug/L 500 92 75-12599 8 20500ND463500
Arsenic, Dissolved ug/L 500 83 75-12589 7 20500ND416447
Barium, Dissolved ug/L 500 81 75-12588 6 20500126534566
Beryllium, Dissolved ug/L 500 81 75-12588 8 205000.27J 405 439
Cadmium, Dissolved ug/L 500 85 75-12592 7 205001.8 427 459
Chromium, Dissolved ug/L 500 78 75-12586 9 20500ND392429
Cobalt, Dissolved ug/L 500 85 75-12592 8 20500ND425462
Copper, Dissolved ug/L 500 82 75-12587 7 20500ND408437
Lead, Dissolved ug/L 500 85 75-12592 7 20500ND426459
Nickel, Dissolved ug/L 500 84 75-12591 8 205002.5J 421 458
Selenium, Dissolved ug/L 500 87 75-12592 7 20500ND433462
Silver, Dissolved ug/L 250 89 75-12595 6 20250ND223238
Thallium, Dissolved ug/L 500 80 75-12588 9 205006.2J 405 446
Vanadium, Dissolved ug/L 500 89 75-12596 8 20500ND444483
Zinc, Dissolved ug/L 500 87 75-12596 10 205007.2J 440 487
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/17/2015 04:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 12
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92279139
WAYNE CLOSED MSWLF (PIKEVILLE)
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
ANALYTE QUALIFIERS
Analyte was detected in the associated method blank.B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/17/2015 04:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 12
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92279139
WAYNE CLOSED MSWLF (PIKEVILLE)
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92279139001 MPRP/20264 ICP/18285MW-4 EPA 3010 EPA 6010
92279139002 MPRP/20264 ICP/18285MW-5 EPA 3010 EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/17/2015 04:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 12
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