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HomeMy WebLinkAbout9606_wayneCounty_GWMReport_DIN26412_20150821Wayne County Subtitle D Lined MSWLF Dudley, North Carolina August, 2015 MESCO Project Number: G15016.0 Semi-Annual Water Quality Monitoring Report Prepared for Municipal Engineering Services Company, P.A. Garner and Boone, North Carolina P.O. Box 97 Garner, NC 27529 License No. C-0281 Permit Number: 96-06 TABLE OF CONTENTS SECTION Introduction Page 1 Background Page 1 Sampling Procedures Page 2 Field Parameter Data Page 2 Laboratory Results Page 2 Quality Control Samples Page 2 Groundwater Samples Above Standards Page 2 Surface Water Samples Above Standards Page 3 Leachate Samples Page 3 Groundwater and Surface Water Characterization Page 3 Findings Page 3 Closing Page 3 FIGURES Topographic Map with Site Location Figure 1 Potentiometric Map of Uppermost Aquifer Figure 2 TABLES Groundwater Monitoring Well Construction Table Table 1 Field Observations of Monitoring Locations Table 2 Field Parameter Data Summary Table 3 Sampling and Analysis Summary Table 4 Detections Above SWSL, GWP, 2L, or 2B (Appendix 1) Table 5 Detections in Leachate Samples above SWSL, GWP or 2L Table 6 Hydrologic Properties at Monitoring Well Locations Table 7 APPENDICIES Laboratory Analysis Report and Chains of Custody Appendix A Field Sampling Parameter Data Sheet(s) Appendix B April 12, 2016 Ms. Jaclynne Drummond Solid Waste Section (SWS) Division of Waste Management North Carolina Department of Environmental Quality 2090 US 70 Highway Swannanoa, NC 28778 Re: Semi-Annual Water Quality Monitoring Report Wayne County Subtitle D Lined MSWLF Permit No. 96-06 MESCO Project No. G15016.0 Event Date(s): August 20-21, 2015 Introduction On behalf of Wayne County, Municipal Engineering Services Company, P.A. (MESCO) is pleased to present this Semi-Annual Water Quality Report for the summer 2015 event performed at the Wayne County Subtitle D Lined Municipal Solid Waste Landfill (MSWLF). NCDENR Solid Waste Rules 15A NCAC 13B.1632 require that Wayne County provide this report to the NC SWS on a semi-annual basis. This report documents the quality of the ground, surface waters and leachate during this monitoring event performed on August 20-21, 2015. During this event total cadmium was detected in most of the groundwater samples with four above 2L Groundwater Standards. Total cadmium was also detected in downstream surface water SW-4 above 2B Surface Water Standards. The preliminary source of the detected metals is not believed to be anthropogenic. Benzene was detected in unprecedented levels above the 2L Standard in sample MW-13. The preliminary source of benzene is likely anthropogenic. Background The Wayne County Subtitle D lined MSWLF, permit #96-06 (Phases 1-3), is located at 460-B South Landfill Road, Dudley, Wayne County, North Carolina. The lined MSWLF is comprised of contiguous Phases 1, 2 & 3 which are treated as a single unit in this report. Phase 3 was granted a Permit to Operate (PTO) on June 11, 2013 and at the time of this event waste had been placed upon most of the liner encompassing both the east and west sumps. The lined landfill is located west and beyond a perennial local discharge feature from a C&D landfill operating upon an unlined landfill which is monitored separately under Permit #96-01. The site location topographic map is depicted in the attached Figure 1. Water quality at this facility has been monitored at least semi-annually including several pre-operation baseline events with complete historical data available since prior to operation of Phase 1 in 1997. This event was performed in accordance with the NC SWS rules/regulations as promulgated in 15A NCAC 13B and as a condition of the permit to operate. As specified within 15A NCAC 13B.1632(j), the SWS Environmental Monitoring Report Form and a recent SWS memorandum this report contains sampling procedures, field and laboratory results, groundwater and surface water characterization. Well construction summary table, field observations table, field parameter data table, sampling and analysis summary table, detections compared to Standards tables, a groundwater flow directions/rates table, potentiometric map, quality assurance/quality control data, and laboratory analytical data results are enclosed herein. Sampling Procedure Samples were collected in accordance with the Ground and Surface Water Sampling & Analysis Plan (SAP) [DIN 13717] dated April 25, 2011 and approved by the SWS on May 19, 2011 [DIN 13957]. The site specific SAP includes water sample collection and analysis from twelve downgradient monitoring wells (MW-2 through MW- 16R), one background well (MW-1), four surface water locations (SW-2, SW-3, SW-4 and SW-5) and a leachate sample (LE-1). Surface water point SW-1, located downstream of SW-3, monitors the unnamed tributary of Edward's Branch as part of the separate SAP for the adjacent Active C&D and Closed MSWLF. Results of SW-1 are also presented in this report due to the shared discharge features. Quality control measures, which included analysis of equipment blank samples (EB), field blank samples (FB), and trip blank samples (TB) were also reported. Monitoring locations are depicted on the potentiometric map of the uppermost aquifer, Figure 2. A summary detailing the construction of the water monitoring wells is presented on Table 1. The function and integrity of all monitoring locations were visually evaluated and no deficiencies identified as documented on Table 2. The depth to water in each well was electronically gaged prior to purging to quantify the static water level elevation. Low-flow pumping methodology or bailing was used to adequately purge the wells to a minimum of three times the volume of standing water in the well or until dry. Surface water samples were dipped from the surface at previously designated locations. During well purging and surface water sample collection the required field parameters were recorded. The samples were then placed into laboratory-prepared, pre-preserved containers via a new disposable polyethylene bailer. Samples were collected, kept on ice, and transported to a NC-certified laboratory under proper chain of custody (C-O-C) protocols and analyzed within the proper hold-times. Field Parameter Data Stabilized field parameters were recorded during purging which included pH, specific conductance, temperature, total dissolved solids (TDS) and visual turbidity. A summary of the field parameter data is presented in Table 3 and the field sampling data sheet is enclosed in Appendix B. Laboratory Results Pace Analytical Laboratories (PACE) of Huntersville and Asheville, NC performed the laboratory analysis. Groundwater, surface water and quality control blank samples were analyzed for the constituents listed in 40 CFR 258 Appendix I including volatile organic compounds (VOCs) by EPA Test Method 8260 and total unfiltered metals by EPA Test Method series 6000/7000. Leachate samples (LE-1) were analyzed for a leachate specific list that includes Appendix I parameters, nitrate, phosphorus, chemical oxygen demand (COD), biological oxygen demand (BOD), sulfate, and pH. A sampling and analysis table summarizing the locations, constituents, and methods is presented on Table 4. Water samples were analyzed to the laboratory-established Method Detection Limits (MDL), which are at or below the current Solid Waste Section Limit (SWSL). Table 5 summarizes constituents detected in groundwater and surface water samples that attain or were above the current SWSL, Groundwater Protection Standards (GWP), North Carolina Groundwater Standards (2L), the applicable North Carolina Surface Water Standards (2B) for a class C waterbody, and Maximum Contaminant Levels (MCL) also known as “Federal Primary Drinking Water Standards”. Laboratory results and C-O-Cs are presented in Appendix A. Quality Control Samples Methylene chloride was detected in non-quantifiable (“j-qualified”) levels in all blanks (EB, FB, TB). Since methylene chloride, a common laboratory contaminant since used in the extraction process, was not detected in any compliance water samples above regulatory Standards, any potential lab induced artifact contamination is non- consequential. 2 Groundwater Samples Above Standards Total cadmium was detected in samples MW-2 (6.6 µg/L), MW-11 (4.1 µg/L), MW-12 (3.3 µg/L) and MW-16R (2.7 µg/L) above the 2L Standard (2.0 µg/L). Benzene was detected in sample MW-13 (1.1 µg/L) slightly above the 2L Standard (1.0 µg/L). Surface Water Samples Above Standards Surface water sample SW-4, located downstream from the facility, contained total cadmium (2.4 µg/L) which is slightly above the 2B Standard (2.0 µg/L). Leachate Samples Leachate sample LE-1 contained quantifiable concentrations of three metals and four VOCs, however, neither cadmium nor benzene were detected as presented in Table 6. Contaminant levels are low in raw leachate samples which is consistent with historical results. Groundwater and Surface Water Characterization MESCO prepared a potentiometric map using groundwater elevation data from the uppermost aquifer measured during this event (Figure 2). Groundwater velocity rates and directions were calculated and are included on Table 7. Consistent with historical observations groundwater flows from the southwest towards Edward's Branch, which serves as the local discharge feature. Groundwater velocity rates ranged from 2 feet/year (MW-15) to 99 feet/year (MW-13) averaging approximately 26 feet/year. Off-site vegetation has been cleared on the west bank of Edward's Branch in recent years. The off-site western adjoining property should be investigated if evidence of degradation of Edward's Branch is discovered in the future. Streams located within the facility boundaries were visually observed at low seasonal flow, low volume and low turbidity. Findings Total cadmium was detected in 56% of the groundwater samples and downstream SW-4. Cadmium levels were unprecedented at MW-2, MW-11 and MW-16R. Total cadmium is naturally inherent in the ground and surface waters at the facility as evidenced by detections in upgradient background wells MW-1 (lined), MW-1/MW-1R (closed) and upstream surface water point SW-5. Total cadmium has never been detected in any of the 64 leachate samples collected at least semi-annually since the landfill was constructed almost 16 years ago. The preliminary source of total cadmium is likely not anthropogenic. Benzene was detected in excess of the 2L Standard in sample MW-13 for the first time. MW-13 is located cross- gradient and within the lined Phase 2 relevant compliance boundary. Landfill gas (LFG) has been detected in the vadose near MW-13. The preliminary source of benzene detected in MW-13 is likely anthropogenic with a transport mechanism of leachate and or LFG. 3 Figures Topographic Map with Site Location 01 1 MILE FIGURE 1 Wayne County Landfill North Carolina (Dudley) CLOSED MSW FACILITY SUBTITLE D MSW LANDFILL FACILITY 460 B South Landfill Rd Dudley, NC 28333 Lat:35-17-19.1338 Long:-78-04-17.2971 Northing:561283.19 Easting:2277068.62 N Tables Wayne County Subtitle D Lined MSWLF Page 1 of 1 Table 1 Groundwater Monitoring Well Construction Table August 20-21, 2015 Latitude Longitude (inches)(ft) MW-1 12/5/97 2 22.50 7.50 15 soil 164.51 161.95 149.19 15.32 35.2980417 78.0666750 MW-2 12/5/97 2 20.00 5.00 15 soil 147.27 144.63 137.18 10.09 35.2946417 78.0699806 MW-3 12/4/97 2 20.00 5.00 15 soil 141.13 136.40 132.73 8.40 35.2940694 78.0725889 MW-4 12/3/97 2 25.00 10.00 15 soil 139.80 137.80 123.24 16.56 35.2934694 78.0756444 MW-5 12/3/97 2 23.00 8.00 15 soil 140.15 137.35 124.16 15.99 35.2941972 78.0757333 MW-6 12/3/97 2 25.00 10.00 15 soil 146.58 144.42 129.43 17.15 35.2946000 78.0741306 MW-7 12/4/97 2 20.00 5.00 15 soil 135.89 133.57 129.50 6.39 35.2878278 78.0740694 MW-8 12/18/97 2 20.00 5.00 15 soil 135.25 132.79 127.57 7.68 35.2973056 78.0733889 MW-9 12/4/97 2 23.00 8.00 15 soil 141.31 139.13 128.96 12.35 35.2939444 78.0739453 MW-10 12/4/97 2 23.00 8.00 15 soil 141.43 139.19 127.89 13.54 35.2937472 78.0747222 MW-11 4/15/04 2 15.49 5.49 10 soil 134.76 131.76 131.04 3.72 35.2980861 78.0729639 MW-12 4/15/04 2 16.45 6.45 10 soil 135.19 132.19 130.74 4.45 35.2991889 78.0727111 MW-13 4/15/04 2 15.85 5.85 10 soil 149.89 146.89 141.10 8.79 35.2952722 78.0687417 MW-14 9/21/06 2 21.24 6.24 15 soil 137.51 134.68 130.88 6.63 35.2998500 78.0728806 MW-15 9/26/06 2 16.17 6.17 10 soil 131.74 129.01 128.73 3.01 35.3006028 78.0727778 MW-16R 6/4/13 2 22.00 7.00 15 Soil sand 160.39 157.39 145.20 15.19 35.2962278 78.0673861 P-5 1/11/96 2 19.00 11.00 8 soil 159.42 156.25 150.50 8.92 35.3002167 78.0688833 P3-15S 9/21/06 2 16.53 6.53 10 soil 152.23 149.14 144.56 7.67 35.3005639 78.0700639 Na = not available Monitoring Well Date Installed Well Diameter Total Well Depth Top of Screen Depth Screen Length Geology of Screened Interval Top of Casing Elevation Ground Elevation Groundwater Elevation Depth to Water (ft bgs)(ft bgs)(ft amsl)(ft amsl)(ft amsl)(ft btoc) bgs = below ground surface amsl= above mean sea level btoc = below top of PVC well casing Wayne County Subtitle D Lined MSWLF Page 1 of 1 Table 2 Field Observations of Monitoring Locations August 20-21, 2015 Locked Comments MW-1 Yes Yes Yes Yes Yes Yes MW-2 Yes Yes Yes Yes Yes Yes MW-3 Yes Yes Yes Yes Yes Yes See comments below MW-4 Yes Yes Yes Yes Yes Yes MW-5 Yes Yes Yes Yes Yes Yes MW-6 Yes Yes Yes Yes Yes Yes MW-7 Yes Yes Yes Yes Yes Yes Not re-painted yet MW-8 Yes Yes Yes Yes Yes Yes MW-9 Yes Yes Yes Yes Yes Yes MW-10 Yes Yes Yes Yes Yes Yes MW-11 Yes Yes Yes Yes Yes Yes MW-12 Yes Yes Yes Yes Yes Yes MW-13 Yes Yes Yes Yes Yes Yes MW-14 Yes Yes Yes Yes Yes Yes Ph 3 well MW-15 Yes Yes Yes Yes Yes Yes Ph 3 well MW-16R Yes Yes Yes Yes Yes Yes Ph 3 well. Methane gas venting from PVC LE-1 Yes -----Leachate lagoon sample SW-1 Yes -----Shared Downstream of SW-3 SW-2 Yes -----Shared nearest lined MW-2 SW-3 Yes -----Shared downstream of SW-2 SW-3 No -----Shared Upstream furthest east Dry SW-4 Yes -----Downstream of Ph 1 on Edward's Branch SW-5 Yes -----Upstream of facility Any unusual field conditions, observations, or events: Phase 3 now in operation. Waste placed only on the east side of divide. Potential for leachate to migrate towards the west is unlikely. Sample Location Viable Monitoring Location Lack of Any Evidence of Tampering Hinge/Hasp Operational Tagged or Labeled Concrete Surface Pad Assumed Effective Adjoiner west of Edwards Branch across from Ph 2 & 3 has cleared forest since 9/12. Adjoiner may potentially impact wetlands. County replaced pad and case around MW-3 in August 2013. Riser extended 2.63' so top of casing now 141.13 ft amsl. Wayne County Subtitle D Lined MSWLF Page 1 of 1 Table 3 Field Parameter Data Summary August 20-21, 2015 Parameter Temp.ORP DO pH TDS Turbidity Units C mg/L SU visual %/vol MW-1 15.32 149.19 164.51 16.5 NR NR 5.80 30 10 Slight NR MW-2 10.09 137.18 147.27 18.1 NR NR 6.53 510 250 Slight NR MW-3 8.40 132.73 141.13 18.4 NR NR 6.17 310 250 Slight NR MW-4 16.56 123.24 139.80 18.6 NR NR 6.13 320 260 Slight NR MW-5 15.99 124.16 140.15 16.5 NR NR 5.11 10 0 Clear NR MW-6 17.15 129.43 146.58 17.5 NR NR 5.03 0 0 Clear NR MW-7 6.39 129.50 135.89 18.9 NR NR 5.81 210 100 Very NR MW-8 7.68 127.57 135.25 18.5 NR NR 5.53 20 0 Slight NR MW-9 12.35 128.96 141.31 18.9 NR NR 5.21 30 10 Slight NR MW-10 13.54 127.89 141.43 18.1 NR NR 5.81 10 0 Slight NR MW-11 3.72 131.04 134.76 18.2 NR NR 5.35 0 0 Slight NR MW-12 4.45 130.74 135.19 18.3 NR NR 5.38 90 40 Clear NR MW-13 8.79 141.10 149.89 18.1 NR NR 5.13 90 40 Clear NR MW-14 6.63 130.88 137.51 19.9 NR NR 5.13 10 0 Clear NR MW-15 3.01 128.73 131.74 18.3 NR NR 6.23 10 0 Clear NR MW-16R 15.19 145.20 160.39 18.1 NR NR 5.35 10 0 Clear Exists Minimum 3.01 123.24 131.74 16.5 NR NR 5.03 0 0 Clear NR Average 10.33 132.35 142.68 18.2 NR NR 5.61 104 60 Slight NR Maximum 17.15 149.19 164.51 19.9 NR NR 6.53 510 260 Very Exists SW-1 ---20.5 NR NR 7.07 430 210 Clear NR SW-2 ---20.3 NR NR 7.01 370 160 Clear NR SW-3 ---20.1 NR NR 7.01 400 190 Clear NR SW-4 ---20.1 NR NR 7.02 60 20 Clear NR SW-5 ---20.2 NR NR 7.02 80 30 Clear NR Minimum ---20.1 NR NR 7.01 60 20 Clear NR Average ---20.2 NR NR 7.03 268 122 Clear NR Maximum ---20.5 NR NR 7.07 430 210 Clear NR NR = No Reading Attempted and not required Exist = Visually observed LFG vapors (waves) from MW-16R Depth to Water Water Elevation TOC Elevation Specific Conductance Methane Gas in Well Headspace ft (btoc)ft (amsl)ft (amsl)mV цs/cm ppb Wayne County Subtitle D Lined MSWLF Page 1 of 1 Table 4 Sampling and Analysis Summary August 20-21, 2015 Field Parameter Leachate To t a l M e t a l s Te m p e r a t u r e Co n d u c t i v i t y To t a l D i s s o l v e d S o l i d s ( T D S ) pH Tu r b i d i t y Su l f a t e pH Ph o s p h o r u s BO D , 5 d a y CO D Ni t r a t e La b E P A 8 2 6 0 B L a b E P A 6 0 0 0 / 7 0 0 0 Fi e l d M e t e r Fi e l d M e t e r Fi e l d M e t e r Fi e l d M e t e r Fi e l d V i s u a l La b E P A 3 0 0 . 0 La b E P A 9 0 4 0 La b E P A 3 6 5 . 1 La b S M 5 2 1 0 B La b S M 5 2 2 0 D La b E P A 3 5 3 . 2 MW-1 x x x x x x x MW-2 x x x x x x x MW-3 x x x x x x x MW-4 x x x x x x x MW-5 x x x x x x x MW-6 x x x x x x x MW-7 x x x x x x x MW-8 x x x x x x x MW-9 x x x x x x x MW-10 x x x x x x x MW-11 x x x x x x x MW-12 x x x x x x x MW-13 x x x x x x x MW-14 x x x x x x x MW-15 x x x x x x x MW-16R x x x x x x x SW-1 x x x x x x x SW-2 x x x x x x x SW-3 Not Sampled since dry which is typical SW-3 x x x x x x x SW-4 x x x x x x x SW-5 x x x x x x x LE-1 x x x x x x x x EB x x FB x x TB x Appendix I = List from current 40 CFR 258 App. I VO C s Wayne County Subtitle D MSWLF, Phases 1-3 Page 1 of 2 Table 5 Detections in Water Samples above SWSL, GWP, 2L or 2B (Appendix I) August 20-21, 2015 Result Unit MW-1 Vanadium, total 8/20/15 15.7J 2.5 25 NE 3.5 NE MW-1 Zinc, total 8/20/15 12.6 5 10 1000 5000 MW-2 Cadmium, total 8/20/15 6.6 0.5 1 2 5 N MW-2 Copper, total 8/20/15 15.6 2.5 10 1000 1300 MW-2 Selenium, total 8/20/15 14.6 5 10 50 50 MW-3 Cadmium, total 8/20/15 1.3 0.5 1 2 5 MW-4 Cadmium, total 8/20/15 1.8 0.5 1 2 5 MW-8 Cadmium, total 8/20/15 1.3 0.5 1 2 5 MW-11 Cadmium, total 8/20/15 4.1 0.5 1 2 5 N MW-12 Cadmium, total 8/20/15 3.3 0.5 1 2 5 N MW-13 Benzene 8/20/15 1.1 0.25 1 1 5 L &/or LFG MW-14 Cadmium, total 8/20/15 1.5 0.5 1 2 5 MW-15 Cadmium, total 8/20/15 2 0.5 1 2 5 MW-16R Cadmium, total 8/20/15 2.7 0.5 1 2 5 N MW-16R Vanadium, total 8/20/15 3.9J 2.5 25 NE 3.5 NE SW-2 Zinc, total 8/21/15 13 5 10 50 5000 SW-2 Vanadium, total 8/21/15 4.2J 2.5 25 NE NE SW-4 Cadmium, total 8/20/15 2.4 0.5 1 2 5 N SW-4 Zinc, total 8/20/15 10.4 5 10 50 5000 SW-4 Barium, total 8/20/15 223 2.5 100 200000 1300 SW-4 Toluene 8/20/15 3.6 0.26 1 11 1000 SW-5 Barium, total 8/20/15 317 2.5 100 200000 1300 Sample ID Parameter Name 1 Sample Date MDL 2 SWSL 3 2L 4 2B 5 GWP 6 MCL 7 Preliminary Cause 8 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L Wayne County Subtitle D MSWLF, Phases 1-3 Page 2 of 2 Result UnitSample ID Parameter Name 1 Sample Date MDL 2 SWSL 3 2L 4 2B 5 GWP 6 MCL 7 Preliminary Cause 8 EB Methylene Chloride 8/21/15 1.1 0.97 1 4.6 5 FB Methylene Chloride 8/21/15 1.3 0.97 1 4.6 5 TB Methylene Chloride 8/21/15 2.4 0.97 1 4.6 5 A definitive source of the detection was not determined as part of this report. Preliminary cause only listed pursuant to instructions J=The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable N = Natural originating from erosion of natural deposits. Source not anthropogenic. BOLD = Concentration > 2L, 2B, GWP or MCL Standard ug/L ug/L ug/L 1 Table contains constituents detected at or above SWSL, GWP, 2L, 2B or MCL 2 MDL = Method Detection Limit 3 SWSL = Solid Waste Section Reporting Limit 4 2L = North Carolina 15A NCAC 2L Groundwater Quality Standard 5 2B = North Carolina 15 NCAC 2B Surface Water Quality Standard for this Specific Stream Classification 6 GWP = Groundwater Protection Standard 7 MCL = Maximum Contaminant Level aka Primary Drinking Water Standard (not currently applicable for regulatory comparisons) 8 Preliminary Cause = Refers to a preliminary analysis of the cause and/or source of a detection over the respective 2L/2B Standard. Wayne County Subtitle D MSWLF Page 1 of 1 Table 6 Detections in Leachate Sample Above SWSL, GWP, 2L or MCL August 20, 2015 Result Unit LE-1 8/20/15 0.97J 0.24 1 0.4 5 1841 LE-1 Methylene Chloride 8/20/15 1.7 0.97 1 4.6 5 5352 LE-1 Acetone 8/20/15 157 10 100 6000 NE 2163 LE-1 Toluene 8/20/15 59.4 0.26 1 600 1000 1016 LE-1 Antimony, total 8/20/15 13.1 3.8 6 NE 1.4 6 4520 LE-1 Chromium, total 8/20/15 40 2.5 10 10 100 175.4 LE-1 Barium, total 8/20/15 154 2.5 100 700 1300 850 LE-1 Vanadium, total 8/20/15 6.9J 2.5 25 NE 3.5 NE 179 LE-1 Zinc, total 8/20/15 508 5 10 1000 5000 8320 LE-1 Sulfate 8/20/15 28900J 10000 2500000 250000 NE 244000 LE-1 BOD, 5 day 8/20/15 329000 2000 2000 NE NE 3837000 LE-1 COD 8/20/15 956000 12500 25000 NE NE 4773000 LE-1 Phosphorus 8/20/15 1760 25 50 NE NE 7820 adjusted for actual sample preparation data and moisture content, where applicable. NE = Not Established BOLD = Concentration > 2L, GWP, MCL or “Average Leachate” Sample ID Parameter Name 1 Sample Date MDL 2 SWSL 3 2L 4 GWP 5 MCL 6 “Average Leachate” 7 1,2-Dichloroethane ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 1 Table contains only constituents detected at or above SWSL, GWP, 2L, or MCL 2 MDL = Method Detection Limit 3 SWSL = Solid Waste Section Reporting Limit (Current as of Sampling Event) 4 2L = North Carolina 15A NCAC 2L Groundwater Quality Standard (Current as of Sampling Event) 5 GWP = Groundwater Protection Standard (Current as of Sampling Event) 6 MCL = Primary Drinking Water Standard (not currently applicable for regulatory comparisons) 7 Average concentration of leachate from a comparable “Dry Tomb” Landfill published in 1988 by EPA document Summary of Data on MSWLF Leachate Characteristics J =The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), Wayne County Subtitle D Lined MSWLF Page 1 of 1 Table 7 August 20, 2015 Flow Rate (cm/sec)(%)(ft/ft)(ft/yr) MW-1 3.21E-04 31 0.0063 7 S06E 15.32 149.19 MW-2 1.37E-03 31 0.0092 42 S66W 10.09 137.18 MW-3 9.72E-04 31 0.0123 40 S53W 8.40 130.10 MW-4 2.33E-04 9 0.0152 41 S61W 16.56 123.24 MW-5 1.45E-04 9 0.0116 19 N83W 15.99 124.16 MW-6 8.38E-05 31 0.0106 3 N84W 17.15 129.43 MW-7 6.84E-05 9 0.0119 9 N81W 6.39 129.50 MW-8 1.68E-04 9 0.0148 29 S65W 7.68 127.57 MW-9 6.37E-04 31 0.0087 19 S68W 12.35 128.96 MW-10 4.74E-04 31 0.0021 3 S63W 13.54 127.89 MW-11 1.46E-04 22 0.0289 20 S79W 3.72 131.04 MW-12 1.63E-04 22 0.0242 19 N87W 4.45 130.74 MW-13 2.14E-03 22 0.0098 99 S50W 8.79 141.10 MW-14 2.63E-04 22 0.0314 39 N77W 6.63 130.88 MW-15 1.82E-05 22 0.0218 2 N68W 3.01 128.73 MW-16R 22 0.0087 S42W 15.19 145.20 Minimum 1.82E-05 9 0.0021 2 -3.01 123.24 Average 4.80E-04 22 0.0142 26 -10.33 132.18 Maximum 2.14E-03 31 0.0314 99 -17.15 149.19 NOTE: Hydraulic Conductivity values from slug tests performed on each monitoring well. where Hydrologic Properties at Monitoring Well Locations Monitoring Well Hydraulic Conductivity Effective Porosity Hydraulic Gradient Flow Direction Depth to Groundwater Groundwater Potentiometric Elevation (ft btoc)(ft amsl) na na Effective porosity values from Design Hydrogeologic Studies for Wayne County. Hydrologic gradient calculated from groundwater elevations recorded on August 20, 2015. Average Linear Velocity rate (Q) is defined by modified Darcy's equation: K= hydraulic conductivity ne= effective porosity dh= head difference dl= horizontal distance Q=−K ne ⋅dh dl Appendix A Laboratory Analysis Reports Chains of Custody #=CL# September 03, 2015 LIMS USE: FR - JONATHAN PFOHL LIMS OBJECT ID: 92264552 92264552 Project: Pace Project No.: RE: Mr. Jonathan Pfohl Municipal Engineering Services PO Box 97 Garner, NC 27529 WAYNE LINED MSWLF Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on August 21, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Godwin kevin.godwin@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 65 #=CP# CERTIFICATIONS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84 West Virginia Certification #: 357Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 65 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Lab ID Sample ID Matrix Date Collected Date Received 92264552001 MW-1 Water 08/20/15 09:10 08/21/15 15:25 92264552002 MW-2 Water 08/20/15 15:00 08/21/15 15:25 92264552003 MW-3 Water 08/20/15 14:35 08/21/15 15:25 92264552004 MW-4 Water 08/20/15 14:20 08/21/15 15:25 92264552005 MW-5 Water 08/20/15 12:10 08/21/15 15:25 92264552006 MW-6 Water 08/20/15 13:50 08/21/15 15:25 92264552007 MW-7 Water 08/20/15 13:30 08/21/15 15:25 92264552008 MW-8 Water 08/20/15 09:30 08/21/15 15:25 92264552009 MW-9 Water 08/20/15 11:40 08/21/15 15:25 92264552010 MW-10 Water 08/20/15 11:20 08/21/15 15:25 92264552011 MW-11 Water 08/20/15 11:00 08/21/15 15:25 92264552012 MW-12 Water 08/20/15 10:30 08/21/15 15:25 92264552013 MW-13 Water 08/20/15 12:00 08/21/15 15:25 92264552014 MW-14 Water 08/20/15 10:15 08/21/15 15:25 92264552015 MW-15 Water 08/20/15 09:50 08/21/15 15:25 92264552016 MW-16R Water 08/20/15 15:35 08/21/15 15:25 92264552017 SW-4 Water 08/20/15 12:25 08/21/15 15:25 92264552018 SW-5 Water 08/20/15 09:55 08/21/15 15:25 92264552019 LE-1 Water 08/20/15 17:30 08/21/15 15:25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 65 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92264552001 MW-1 EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264552002 MW-2 EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264552003 MW-3 EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264552004 MW-4 EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264552005 MW-5 EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264552006 MW-6 EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264552007 MW-7 EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264552008 MW-8 EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264552009 MW-9 EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264552010 MW-10 EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264552011 MW-11 EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264552012 MW-12 EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264552013 MW-13 EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264552014 MW-14 EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264552015 MW-15 EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264552016 MW-16R EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264552017 SW-4 EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264552018 SW-5 EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264552019 LE-1 EPA 6010 15 PASI-AJDA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 65 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts EPA 8260 51 PASI-CGAW SM 5210B 1 PASI-ABRJ EPA 9040 1 PASI-ASAM EPA 300.0 1 PASI-AMDW EPA 353.2 1 PASI-ASER EPA 365.1 1 PASI-AAES2 SM 5220D 1 PASI-AEWS REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-1 Lab ID:92264552001 Collected:08/20/15 09:10 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/30/15 21:07 7440-36-008/25/15 18:306.0 3.8 1 Arsenic ND ug/L 08/30/15 21:07 7440-38-208/25/15 18:3010.0 2.5 1 Barium 21.2J ug/L 08/30/15 21:07 7440-39-308/25/15 18:301002.5 1 Beryllium ND ug/L 08/30/15 21:07 7440-41-708/25/15 18:301.0 0.50 1 Cadmium 0.63J ug/L 08/30/15 21:07 7440-43-908/25/15 18:301.0 0.50 1 Chromium 5.7J ug/L 08/30/15 21:07 7440-47-308/25/15 18:3010.0 2.5 1 Cobalt ND ug/L 08/30/15 21:07 7440-48-408/25/15 18:3010.0 2.5 1 Copper 4.5J ug/L 08/30/15 21:07 7440-50-808/25/15 18:3010.0 2.5 1 Lead 5.2J ug/L 08/30/15 21:07 7439-92-108/25/15 18:3010.0 2.5 1 Nickel ND ug/L 08/30/15 21:07 7440-02-008/25/15 18:3050.0 2.5 1 Selenium ND ug/L 08/30/15 21:07 7782-49-208/25/15 18:3010.0 5.0 1 Silver ND ug/L 08/30/15 21:07 7440-22-408/25/15 18:3010.0 2.5 1 Thallium ND ug/L 08/30/15 21:07 7440-28-008/25/15 18:305.5 5.0 1 Vanadium 15.7J ug/L 08/30/15 21:07 7440-62-208/25/15 18:3025.0 2.5 1 Zinc 12.6 ug/L 08/30/15 21:07 7440-66-608/25/15 18:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 01:40 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 01:40 107-13-12001.9 1 Benzene ND ug/L 09/01/15 01:40 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 01:40 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 01:40 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 01:40 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 01:40 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 01:40 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 01:40 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 01:40 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 01:40 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 01:40 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 01:40 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 01:40 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 01:40 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 01:40 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 01:40 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 01:40 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 01:40 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 01:40 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 01:40 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 01:40 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 01:40 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 01:40 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 01:40 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 01:40 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 01:40 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 01:40 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 01:40 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-1 Lab ID:92264552001 Collected:08/20/15 09:10 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 01:40 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 01:40 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 01:40 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 01:40 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 09/01/15 01:40 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 01:40 108-10-11000.33 1 Styrene ND ug/L 09/01/15 01:40 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 01:40 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 01:40 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 01:40 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 01:40 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 01:40 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 01:40 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 01:40 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 01:40 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 01:40 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 01:40 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 01:40 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 01:40 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)101 %09/01/15 01:40 460-00-470-130 1 1,2-Dichloroethane-d4 (S)113 %09/01/15 01:40 17060-07-070-130 1 Toluene-d8 (S)102 %09/01/15 01:40 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-2 Lab ID:92264552002 Collected:08/20/15 15:00 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/30/15 21:19 7440-36-008/25/15 18:306.0 3.8 1 Arsenic ND ug/L 08/30/15 21:19 7440-38-208/25/15 18:3010.0 2.5 1 Barium 20.2J ug/L 08/30/15 21:19 7440-39-308/25/15 18:301002.5 1 Beryllium ND ug/L 08/30/15 21:19 7440-41-708/25/15 18:301.0 0.50 1 Cadmium 6.6 ug/L 08/30/15 21:19 7440-43-908/25/15 18:301.0 0.50 1 Chromium ND ug/L 08/30/15 21:19 7440-47-308/25/15 18:3010.0 2.5 1 Cobalt ND ug/L 08/30/15 21:19 7440-48-408/25/15 18:3010.0 2.5 1 Copper 15.6 ug/L 08/30/15 21:19 7440-50-808/25/15 18:3010.0 2.5 1 Lead 7.8J ug/L 08/30/15 21:19 7439-92-108/25/15 18:3010.0 2.5 1 Nickel ND ug/L 08/30/15 21:19 7440-02-008/25/15 18:3050.0 2.5 1 Selenium 14.6 ug/L 08/30/15 21:19 7782-49-208/25/15 18:3010.0 5.0 1 Silver ND ug/L 08/30/15 21:19 7440-22-408/25/15 18:3010.0 2.5 1 Thallium ND ug/L 08/30/15 21:19 7440-28-008/25/15 18:305.5 5.0 1 Vanadium 3.4J ug/L 08/30/15 21:19 7440-62-208/25/15 18:3025.0 2.5 1 Zinc ND ug/L 08/30/15 21:19 7440-66-608/25/15 18:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 01:57 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 01:57 107-13-12001.9 1 Benzene ND ug/L 09/01/15 01:57 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 01:57 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 01:57 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 01:57 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 01:57 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 01:57 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 01:57 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 01:57 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 01:57 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 01:57 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 01:57 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 01:57 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 01:57 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 01:57 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 01:57 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 01:57 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 01:57 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 01:57 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 01:57 110-57-61001.0 1 1,1-Dichloroethane 0.35J ug/L 09/01/15 01:57 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 01:57 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 01:57 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 01:57 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 01:57 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 01:57 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 01:57 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 01:57 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-2 Lab ID:92264552002 Collected:08/20/15 15:00 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 01:57 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 01:57 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 01:57 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 01:57 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 09/01/15 01:57 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 01:57 108-10-11000.33 1 Styrene ND ug/L 09/01/15 01:57 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 01:57 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 01:57 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 01:57 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 01:57 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 01:57 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 01:57 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 01:57 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 01:57 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 01:57 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 01:57 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 01:57 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 01:57 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %09/01/15 01:57 460-00-470-130 1 1,2-Dichloroethane-d4 (S)114 %09/01/15 01:57 17060-07-070-130 1 Toluene-d8 (S)103 %09/01/15 01:57 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-3 Lab ID:92264552003 Collected:08/20/15 14:35 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/30/15 21:22 7440-36-008/25/15 18:306.0 3.8 1 Arsenic 3.8J ug/L 08/30/15 21:22 7440-38-208/25/15 18:3010.0 2.5 1 Barium 30.9J ug/L 08/30/15 21:22 7440-39-308/25/15 18:301002.5 1 Beryllium ND ug/L 08/30/15 21:22 7440-41-708/25/15 18:301.0 0.50 1 Cadmium 1.3 ug/L 08/30/15 21:22 7440-43-908/25/15 18:301.0 0.50 1 Chromium ND ug/L 08/30/15 21:22 7440-47-308/25/15 18:3010.0 2.5 1 Cobalt ND ug/L 08/30/15 21:22 7440-48-408/25/15 18:3010.0 2.5 1 Copper 7.3J ug/L 08/30/15 21:22 7440-50-808/25/15 18:3010.0 2.5 1 Lead 3.7J ug/L 08/30/15 21:22 7439-92-108/25/15 18:3010.0 2.5 1 Nickel ND ug/L 08/30/15 21:22 7440-02-008/25/15 18:3050.0 2.5 1 Selenium 7.3J ug/L 08/30/15 21:22 7782-49-208/25/15 18:3010.0 5.0 1 Silver ND ug/L 08/30/15 21:22 7440-22-408/25/15 18:3010.0 2.5 1 Thallium ND ug/L 08/30/15 21:22 7440-28-008/25/15 18:305.5 5.0 1 Vanadium ND ug/L 08/30/15 21:22 7440-62-208/25/15 18:3025.0 2.5 1 Zinc ND ug/L 08/30/15 21:22 7440-66-608/25/15 18:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 02:14 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 02:14 107-13-12001.9 1 Benzene ND ug/L 09/01/15 02:14 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 02:14 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 02:14 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 02:14 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 02:14 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 02:14 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 02:14 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 02:14 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 02:14 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 02:14 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 02:14 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 02:14 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 02:14 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 02:14 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 02:14 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 02:14 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 02:14 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 02:14 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 02:14 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 02:14 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 02:14 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 02:14 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 02:14 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 02:14 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 02:14 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 02:14 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 02:14 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-3 Lab ID:92264552003 Collected:08/20/15 14:35 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 02:14 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 02:14 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 02:14 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 02:14 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 09/01/15 02:14 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 02:14 108-10-11000.33 1 Styrene ND ug/L 09/01/15 02:14 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 02:14 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 02:14 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 02:14 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 02:14 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 02:14 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 02:14 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 02:14 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 02:14 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 02:14 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 02:14 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 02:14 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 02:14 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)102 %09/01/15 02:14 460-00-470-130 1 1,2-Dichloroethane-d4 (S)117 %09/01/15 02:14 17060-07-070-130 1 Toluene-d8 (S)102 %09/01/15 02:14 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-4 Lab ID:92264552004 Collected:08/20/15 14:20 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/30/15 21:25 7440-36-008/25/15 18:306.0 3.8 1 Arsenic ND ug/L 08/30/15 21:25 7440-38-208/25/15 18:3010.0 2.5 1 Barium 33.8J ug/L 08/30/15 21:25 7440-39-308/25/15 18:301002.5 1 Beryllium ND ug/L 08/30/15 21:25 7440-41-708/25/15 18:301.0 0.50 1 Cadmium 1.8 ug/L 08/30/15 21:25 7440-43-908/25/15 18:301.0 0.50 1 Chromium ND ug/L 08/30/15 21:25 7440-47-308/25/15 18:3010.0 2.5 1 Cobalt ND ug/L 08/30/15 21:25 7440-48-408/25/15 18:3010.0 2.5 1 Copper ND ug/L 08/30/15 21:25 7440-50-808/25/15 18:3010.0 2.5 1 Lead ND ug/L 08/30/15 21:25 7439-92-108/25/15 18:3010.0 2.5 1 Nickel ND ug/L 08/30/15 21:25 7440-02-008/25/15 18:3050.0 2.5 1 Selenium ND ug/L 08/30/15 21:25 7782-49-208/25/15 18:3010.0 5.0 1 Silver ND ug/L 08/30/15 21:25 7440-22-408/25/15 18:3010.0 2.5 1 Thallium ND ug/L 08/30/15 21:25 7440-28-008/25/15 18:305.5 5.0 1 Vanadium ND ug/L 08/30/15 21:25 7440-62-208/25/15 18:3025.0 2.5 1 Zinc ND ug/L 08/30/15 21:25 7440-66-608/25/15 18:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 02:31 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 02:31 107-13-12001.9 1 Benzene ND ug/L 09/01/15 02:31 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 02:31 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 02:31 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 02:31 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 02:31 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 02:31 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 02:31 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 02:31 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 02:31 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 02:31 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 02:31 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 02:31 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 02:31 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 02:31 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 02:31 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 02:31 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 02:31 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 02:31 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 02:31 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 02:31 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 02:31 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 02:31 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 02:31 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 02:31 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 02:31 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 02:31 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 02:31 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-4 Lab ID:92264552004 Collected:08/20/15 14:20 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 02:31 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 02:31 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 02:31 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 02:31 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 09/01/15 02:31 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 02:31 108-10-11000.33 1 Styrene ND ug/L 09/01/15 02:31 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 02:31 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 02:31 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 02:31 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 02:31 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 02:31 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 02:31 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 02:31 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 02:31 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 02:31 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 02:31 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 02:31 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 02:31 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %09/01/15 02:31 460-00-470-130 1 1,2-Dichloroethane-d4 (S)115 %09/01/15 02:31 17060-07-070-130 1 Toluene-d8 (S)101 %09/01/15 02:31 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-5 Lab ID:92264552005 Collected:08/20/15 12:10 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/30/15 21:28 7440-36-008/25/15 18:306.0 3.8 1 Arsenic ND ug/L 08/30/15 21:28 7440-38-208/25/15 18:3010.0 2.5 1 Barium 76.7J ug/L 08/30/15 21:28 7440-39-308/25/15 18:301002.5 1 Beryllium ND ug/L 08/30/15 21:28 7440-41-708/25/15 18:301.0 0.50 1 Cadmium ND ug/L 08/30/15 21:28 7440-43-908/25/15 18:301.0 0.50 1 Chromium ND ug/L 08/30/15 21:28 7440-47-308/25/15 18:3010.0 2.5 1 Cobalt ND ug/L 08/30/15 21:28 7440-48-408/25/15 18:3010.0 2.5 1 Copper ND ug/L 08/30/15 21:28 7440-50-808/25/15 18:3010.0 2.5 1 Lead ND ug/L 08/30/15 21:28 7439-92-108/25/15 18:3010.0 2.5 1 Nickel ND ug/L 08/30/15 21:28 7440-02-008/25/15 18:3050.0 2.5 1 Selenium ND ug/L 08/30/15 21:28 7782-49-208/25/15 18:3010.0 5.0 1 Silver ND ug/L 08/30/15 21:28 7440-22-408/25/15 18:3010.0 2.5 1 Thallium ND ug/L 08/30/15 21:28 7440-28-008/25/15 18:305.5 5.0 1 Vanadium ND ug/L 08/30/15 21:28 7440-62-208/25/15 18:3025.0 2.5 1 Zinc ND ug/L 08/30/15 21:28 7440-66-608/25/15 18:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 02:48 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 02:48 107-13-12001.9 1 Benzene ND ug/L 09/01/15 02:48 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 02:48 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 02:48 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 02:48 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 02:48 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 02:48 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 02:48 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 02:48 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 02:48 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 02:48 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 02:48 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 02:48 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 02:48 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 02:48 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 02:48 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 02:48 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 02:48 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 02:48 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 02:48 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 02:48 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 02:48 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 02:48 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 02:48 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 02:48 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 02:48 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 02:48 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 02:48 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-5 Lab ID:92264552005 Collected:08/20/15 12:10 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 02:48 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 02:48 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 02:48 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 02:48 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 09/01/15 02:48 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 02:48 108-10-11000.33 1 Styrene ND ug/L 09/01/15 02:48 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 02:48 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 02:48 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 02:48 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 02:48 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 02:48 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 02:48 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 02:48 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 02:48 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 02:48 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 02:48 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 02:48 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 02:48 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %09/01/15 02:48 460-00-470-130 1 1,2-Dichloroethane-d4 (S)117 %09/01/15 02:48 17060-07-070-130 1 Toluene-d8 (S)99 %09/01/15 02:48 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-6 Lab ID:92264552006 Collected:08/20/15 13:50 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/30/15 21:31 7440-36-008/25/15 18:306.0 3.8 1 Arsenic ND ug/L 08/30/15 21:31 7440-38-208/25/15 18:3010.0 2.5 1 Barium 49.6J ug/L 08/30/15 21:31 7440-39-308/25/15 18:301002.5 1 Beryllium ND ug/L 08/30/15 21:31 7440-41-708/25/15 18:301.0 0.50 1 Cadmium 0.63J ug/L 08/30/15 21:31 7440-43-908/25/15 18:301.0 0.50 1 Chromium ND ug/L 08/30/15 21:31 7440-47-308/25/15 18:3010.0 2.5 1 Cobalt ND ug/L 08/30/15 21:31 7440-48-408/25/15 18:3010.0 2.5 1 Copper ND ug/L 08/30/15 21:31 7440-50-808/25/15 18:3010.0 2.5 1 Lead ND ug/L 08/30/15 21:31 7439-92-108/25/15 18:3010.0 2.5 1 Nickel ND ug/L 08/30/15 21:31 7440-02-008/25/15 18:3050.0 2.5 1 Selenium ND ug/L 08/30/15 21:31 7782-49-208/25/15 18:3010.0 5.0 1 Silver ND ug/L 08/30/15 21:31 7440-22-408/25/15 18:3010.0 2.5 1 Thallium ND ug/L 08/30/15 21:31 7440-28-008/25/15 18:305.5 5.0 1 Vanadium ND ug/L 08/30/15 21:31 7440-62-208/25/15 18:3025.0 2.5 1 Zinc ND ug/L 08/30/15 21:31 7440-66-608/25/15 18:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 03:05 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 03:05 107-13-12001.9 1 Benzene ND ug/L 09/01/15 03:05 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 03:05 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 03:05 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 03:05 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 03:05 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 03:05 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 03:05 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 03:05 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 03:05 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 03:05 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 03:05 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 03:05 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 03:05 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 03:05 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 03:05 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 03:05 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 03:05 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 03:05 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 03:05 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 03:05 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 03:05 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 03:05 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 03:05 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 03:05 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 03:05 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 03:05 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 03:05 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-6 Lab ID:92264552006 Collected:08/20/15 13:50 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 03:05 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 03:05 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 03:05 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 03:05 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 09/01/15 03:05 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 03:05 108-10-11000.33 1 Styrene ND ug/L 09/01/15 03:05 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 03:05 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 03:05 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 03:05 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 03:05 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 03:05 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 03:05 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 03:05 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 03:05 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 03:05 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 03:05 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 03:05 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 03:05 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)102 %09/01/15 03:05 460-00-470-130 1 1,2-Dichloroethane-d4 (S)115 %09/01/15 03:05 17060-07-070-130 1 Toluene-d8 (S)101 %09/01/15 03:05 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-7 Lab ID:92264552007 Collected:08/20/15 13:30 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/30/15 21:34 7440-36-008/25/15 18:306.0 3.8 1 Arsenic ND ug/L 08/30/15 21:34 7440-38-208/25/15 18:3010.0 2.5 1 Barium 23.7J ug/L 08/30/15 21:34 7440-39-308/25/15 18:301002.5 1 Beryllium ND ug/L 08/30/15 21:34 7440-41-708/25/15 18:301.0 0.50 1 Cadmium ND ug/L 08/30/15 21:34 7440-43-908/25/15 18:301.0 0.50 1 Chromium ND ug/L 08/30/15 21:34 7440-47-308/25/15 18:3010.0 2.5 1 Cobalt ND ug/L 08/30/15 21:34 7440-48-408/25/15 18:3010.0 2.5 1 Copper 3.1J ug/L 08/30/15 21:34 7440-50-808/25/15 18:3010.0 2.5 1 Lead ND ug/L 08/30/15 21:34 7439-92-108/25/15 18:3010.0 2.5 1 Nickel ND ug/L 08/30/15 21:34 7440-02-008/25/15 18:3050.0 2.5 1 Selenium ND ug/L 08/30/15 21:34 7782-49-208/25/15 18:3010.0 5.0 1 Silver ND ug/L 08/30/15 21:34 7440-22-408/25/15 18:3010.0 2.5 1 Thallium ND ug/L 08/30/15 21:34 7440-28-008/25/15 18:305.5 5.0 1 Vanadium ND ug/L 08/30/15 21:34 7440-62-208/25/15 18:3025.0 2.5 1 Zinc ND ug/L 08/30/15 21:34 7440-66-608/25/15 18:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone 14.4J ug/L 09/01/15 03:22 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 03:22 107-13-12001.9 1 Benzene ND ug/L 09/01/15 03:22 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 03:22 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 03:22 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 03:22 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 03:22 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 03:22 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 03:22 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 03:22 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 03:22 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 03:22 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 03:22 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 03:22 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 03:22 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 03:22 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 03:22 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 03:22 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 03:22 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 03:22 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 03:22 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 03:22 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 03:22 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 03:22 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 03:22 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 03:22 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 03:22 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 03:22 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 03:22 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-7 Lab ID:92264552007 Collected:08/20/15 13:30 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 03:22 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 03:22 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 03:22 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 03:22 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 09/01/15 03:22 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 03:22 108-10-11000.33 1 Styrene ND ug/L 09/01/15 03:22 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 03:22 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 03:22 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 03:22 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 03:22 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 03:22 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 03:22 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 03:22 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 03:22 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 03:22 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 03:22 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 03:22 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 03:22 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)104 %09/01/15 03:22 460-00-470-130 1 1,2-Dichloroethane-d4 (S)118 %09/01/15 03:22 17060-07-070-130 1 Toluene-d8 (S)102 %09/01/15 03:22 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-8 Lab ID:92264552008 Collected:08/20/15 09:30 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/30/15 21:38 7440-36-008/25/15 18:306.0 3.8 1 Arsenic ND ug/L 08/30/15 21:38 7440-38-208/25/15 18:3010.0 2.5 1 Barium 17.7J ug/L 08/30/15 21:38 7440-39-308/25/15 18:301002.5 1 Beryllium ND ug/L 08/30/15 21:38 7440-41-708/25/15 18:301.0 0.50 1 Cadmium 1.3 ug/L 08/30/15 21:38 7440-43-908/25/15 18:301.0 0.50 1 Chromium ND ug/L 08/30/15 21:38 7440-47-308/25/15 18:3010.0 2.5 1 Cobalt ND ug/L 08/30/15 21:38 7440-48-408/25/15 18:3010.0 2.5 1 Copper ND ug/L 08/30/15 21:38 7440-50-808/25/15 18:3010.0 2.5 1 Lead ND ug/L 08/30/15 21:38 7439-92-108/25/15 18:3010.0 2.5 1 Nickel ND ug/L 08/30/15 21:38 7440-02-008/25/15 18:3050.0 2.5 1 Selenium ND ug/L 08/30/15 21:38 7782-49-208/25/15 18:3010.0 5.0 1 Silver ND ug/L 08/30/15 21:38 7440-22-408/25/15 18:3010.0 2.5 1 Thallium ND ug/L 08/30/15 21:38 7440-28-008/25/15 18:305.5 5.0 1 Vanadium ND ug/L 08/30/15 21:38 7440-62-208/25/15 18:3025.0 2.5 1 Zinc ND ug/L 08/30/15 21:38 7440-66-608/25/15 18:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 03:39 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 03:39 107-13-12001.9 1 Benzene ND ug/L 09/01/15 03:39 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 03:39 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 03:39 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 03:39 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 03:39 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 03:39 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 03:39 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 03:39 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 03:39 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 03:39 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 03:39 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 03:39 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 03:39 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 03:39 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 03:39 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 03:39 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 03:39 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 03:39 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 03:39 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 03:39 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 03:39 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 03:39 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 03:39 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 03:39 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 03:39 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 03:39 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 03:39 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-8 Lab ID:92264552008 Collected:08/20/15 09:30 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 03:39 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 03:39 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 03:39 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 03:39 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 09/01/15 03:39 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 03:39 108-10-11000.33 1 Styrene ND ug/L 09/01/15 03:39 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 03:39 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 03:39 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 03:39 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 03:39 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 03:39 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 03:39 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 03:39 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 03:39 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 03:39 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 03:39 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 03:39 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 03:39 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)103 %09/01/15 03:39 460-00-470-130 1 1,2-Dichloroethane-d4 (S)117 %09/01/15 03:39 17060-07-070-130 1 Toluene-d8 (S)101 %09/01/15 03:39 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-9 Lab ID:92264552009 Collected:08/20/15 11:40 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/30/15 21:41 7440-36-008/25/15 18:306.0 3.8 1 Arsenic ND ug/L 08/30/15 21:41 7440-38-208/25/15 18:3010.0 2.5 1 Barium 84.7J ug/L 08/30/15 21:41 7440-39-308/25/15 18:301002.5 1 Beryllium ND ug/L 08/30/15 21:41 7440-41-708/25/15 18:301.0 0.50 1 Cadmium ND ug/L 08/30/15 21:41 7440-43-908/25/15 18:301.0 0.50 1 Chromium ND ug/L 08/30/15 21:41 7440-47-308/25/15 18:3010.0 2.5 1 Cobalt ND ug/L 08/30/15 21:41 7440-48-408/25/15 18:3010.0 2.5 1 Copper ND ug/L 08/30/15 21:41 7440-50-808/25/15 18:3010.0 2.5 1 Lead 2.6J ug/L 08/30/15 21:41 7439-92-108/25/15 18:3010.0 2.5 1 Nickel ND ug/L 08/30/15 21:41 7440-02-008/25/15 18:3050.0 2.5 1 Selenium ND ug/L 08/30/15 21:41 7782-49-208/25/15 18:3010.0 5.0 1 Silver ND ug/L 08/30/15 21:41 7440-22-408/25/15 18:3010.0 2.5 1 Thallium ND ug/L 08/30/15 21:41 7440-28-008/25/15 18:305.5 5.0 1 Vanadium ND ug/L 08/30/15 21:41 7440-62-208/25/15 18:3025.0 2.5 1 Zinc ND ug/L 08/30/15 21:41 7440-66-608/25/15 18:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 03:56 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 03:56 107-13-12001.9 1 Benzene ND ug/L 09/01/15 03:56 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 03:56 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 03:56 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 03:56 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 03:56 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 03:56 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 03:56 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 03:56 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 03:56 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 03:56 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 03:56 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 03:56 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 03:56 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 03:56 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 03:56 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 03:56 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 03:56 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 03:56 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 03:56 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 03:56 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 03:56 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 03:56 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 03:56 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 03:56 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 03:56 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 03:56 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 03:56 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-9 Lab ID:92264552009 Collected:08/20/15 11:40 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 03:56 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 03:56 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 03:56 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 03:56 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 09/01/15 03:56 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 03:56 108-10-11000.33 1 Styrene ND ug/L 09/01/15 03:56 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 03:56 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 03:56 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 03:56 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 03:56 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 03:56 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 03:56 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 03:56 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 03:56 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 03:56 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 03:56 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 03:56 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 03:56 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)101 %09/01/15 03:56 460-00-470-130 1 1,2-Dichloroethane-d4 (S)117 %09/01/15 03:56 17060-07-070-130 1 Toluene-d8 (S)102 %09/01/15 03:56 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-10 Lab ID:92264552010 Collected:08/20/15 11:20 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/30/15 21:44 7440-36-008/25/15 18:306.0 3.8 1 Arsenic ND ug/L 08/30/15 21:44 7440-38-208/25/15 18:3010.0 2.5 1 Barium 39.7J ug/L 08/30/15 21:44 7440-39-308/25/15 18:301002.5 1 Beryllium ND ug/L 08/30/15 21:44 7440-41-708/25/15 18:301.0 0.50 1 Cadmium ND ug/L 08/30/15 21:44 7440-43-908/25/15 18:301.0 0.50 1 Chromium ND ug/L 08/30/15 21:44 7440-47-308/25/15 18:3010.0 2.5 1 Cobalt ND ug/L 08/30/15 21:44 7440-48-408/25/15 18:3010.0 2.5 1 Copper ND ug/L 08/30/15 21:44 7440-50-808/25/15 18:3010.0 2.5 1 Lead ND ug/L 08/30/15 21:44 7439-92-108/25/15 18:3010.0 2.5 1 Nickel ND ug/L 08/30/15 21:44 7440-02-008/25/15 18:3050.0 2.5 1 Selenium ND ug/L 08/30/15 21:44 7782-49-208/25/15 18:3010.0 5.0 1 Silver ND ug/L 08/30/15 21:44 7440-22-408/25/15 18:3010.0 2.5 1 Thallium ND ug/L 08/30/15 21:44 7440-28-008/25/15 18:305.5 5.0 1 Vanadium ND ug/L 08/30/15 21:44 7440-62-208/25/15 18:3025.0 2.5 1 Zinc 5.2J ug/L 08/30/15 21:44 7440-66-608/25/15 18:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 04:13 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 04:13 107-13-12001.9 1 Benzene ND ug/L 09/01/15 04:13 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 04:13 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 04:13 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 04:13 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 04:13 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 04:13 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 04:13 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 04:13 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 04:13 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 04:13 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 04:13 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 04:13 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 04:13 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 04:13 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 04:13 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 04:13 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 04:13 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 04:13 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 04:13 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 04:13 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 04:13 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 04:13 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 04:13 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 04:13 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 04:13 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 04:13 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 04:13 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-10 Lab ID:92264552010 Collected:08/20/15 11:20 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 04:13 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 04:13 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 04:13 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 04:13 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 09/01/15 04:13 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 04:13 108-10-11000.33 1 Styrene ND ug/L 09/01/15 04:13 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 04:13 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 04:13 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 04:13 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 04:13 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 04:13 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 04:13 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 04:13 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 04:13 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 04:13 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 04:13 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 04:13 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 04:13 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)101 %09/01/15 04:13 460-00-470-130 1 1,2-Dichloroethane-d4 (S)117 %09/01/15 04:13 17060-07-070-130 1 Toluene-d8 (S)100 %09/01/15 04:13 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-11 Lab ID:92264552011 Collected:08/20/15 11:00 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/30/15 21:47 7440-36-008/25/15 18:306.0 3.8 1 Arsenic ND ug/L 08/30/15 21:47 7440-38-208/25/15 18:3010.0 2.5 1 Barium 25.6J ug/L 08/30/15 21:47 7440-39-308/25/15 18:301002.5 1 Beryllium ND ug/L 08/30/15 21:47 7440-41-708/25/15 18:301.0 0.50 1 Cadmium 4.1 ug/L 08/30/15 21:47 7440-43-908/25/15 18:301.0 0.50 1 Chromium ND ug/L 08/30/15 21:47 7440-47-308/25/15 18:3010.0 2.5 1 Cobalt ND ug/L 08/30/15 21:47 7440-48-408/25/15 18:3010.0 2.5 1 Copper 2.6J ug/L 08/30/15 21:47 7440-50-808/25/15 18:3010.0 2.5 1 Lead ND ug/L 08/30/15 21:47 7439-92-108/25/15 18:3010.0 2.5 1 Nickel ND ug/L 08/30/15 21:47 7440-02-008/25/15 18:3050.0 2.5 1 Selenium ND ug/L 08/30/15 21:47 7782-49-208/25/15 18:3010.0 5.0 1 Silver ND ug/L 08/30/15 21:47 7440-22-408/25/15 18:3010.0 2.5 1 Thallium ND ug/L 08/30/15 21:47 7440-28-008/25/15 18:305.5 5.0 1 Vanadium ND ug/L 08/30/15 21:47 7440-62-208/25/15 18:3025.0 2.5 1 Zinc ND ug/L 08/30/15 21:47 7440-66-608/25/15 18:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 04:30 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 04:30 107-13-12001.9 1 Benzene ND ug/L 09/01/15 04:30 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 04:30 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 04:30 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 04:30 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 04:30 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 04:30 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 04:30 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 04:30 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 04:30 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 04:30 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 04:30 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 04:30 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 04:30 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 04:30 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 04:30 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 04:30 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 04:30 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 04:30 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 04:30 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 04:30 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 04:30 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 04:30 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 04:30 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 04:30 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 04:30 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 04:30 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 04:30 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-11 Lab ID:92264552011 Collected:08/20/15 11:00 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 04:30 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 04:30 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 04:30 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 04:30 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 09/01/15 04:30 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 04:30 108-10-11000.33 1 Styrene ND ug/L 09/01/15 04:30 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 04:30 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 04:30 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 04:30 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 04:30 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 04:30 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 04:30 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 04:30 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 04:30 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 04:30 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 04:30 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 04:30 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 04:30 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)99 %09/01/15 04:30 460-00-470-130 1 1,2-Dichloroethane-d4 (S)118 %09/01/15 04:30 17060-07-070-130 1 Toluene-d8 (S)103 %09/01/15 04:30 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-12 Lab ID:92264552012 Collected:08/20/15 10:30 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/30/15 21:59 7440-36-008/25/15 18:306.0 3.8 1 Arsenic ND ug/L 08/30/15 21:59 7440-38-208/25/15 18:3010.0 2.5 1 Barium 28.1J ug/L 08/30/15 21:59 7440-39-308/25/15 18:301002.5 1 Beryllium ND ug/L 08/30/15 21:59 7440-41-708/25/15 18:301.0 0.50 1 Cadmium 3.3 ug/L 08/30/15 21:59 7440-43-908/25/15 18:301.0 0.50 1 Chromium ND ug/L 08/30/15 21:59 7440-47-308/25/15 18:3010.0 2.5 1 Cobalt 8.6J ug/L 08/30/15 21:59 7440-48-408/25/15 18:3010.0 2.5 1 Copper ND ug/L 08/30/15 21:59 7440-50-808/25/15 18:3010.0 2.5 1 Lead ND ug/L 08/30/15 21:59 7439-92-108/25/15 18:3010.0 2.5 1 Nickel ND ug/L 08/30/15 21:59 7440-02-008/25/15 18:3050.0 2.5 1 Selenium ND ug/L 08/30/15 21:59 7782-49-208/25/15 18:3010.0 5.0 1 Silver ND ug/L 08/30/15 21:59 7440-22-408/25/15 18:3010.0 2.5 1 Thallium ND ug/L 08/30/15 21:59 7440-28-008/25/15 18:305.5 5.0 1 Vanadium ND ug/L 08/30/15 21:59 7440-62-208/25/15 18:3025.0 2.5 1 Zinc 8.7J ug/L 08/30/15 21:59 7440-66-608/25/15 18:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 04:47 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 04:47 107-13-12001.9 1 Benzene ND ug/L 09/01/15 04:47 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 04:47 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 04:47 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 04:47 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 04:47 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 04:47 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 04:47 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 04:47 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 04:47 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 04:47 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 04:47 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 04:47 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 04:47 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 04:47 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 04:47 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 04:47 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 04:47 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 04:47 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 04:47 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 04:47 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 04:47 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 04:47 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 04:47 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 04:47 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 04:47 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 04:47 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 04:47 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-12 Lab ID:92264552012 Collected:08/20/15 10:30 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 04:47 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 04:47 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 04:47 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 04:47 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 09/01/15 04:47 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 04:47 108-10-11000.33 1 Styrene ND ug/L 09/01/15 04:47 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 04:47 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 04:47 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 04:47 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 04:47 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 04:47 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 04:47 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 04:47 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 04:47 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 04:47 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 04:47 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 04:47 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 04:47 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)102 %09/01/15 04:47 460-00-470-130 1 1,2-Dichloroethane-d4 (S)118 %09/01/15 04:47 17060-07-070-130 1 Toluene-d8 (S)100 %09/01/15 04:47 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-13 Lab ID:92264552013 Collected:08/20/15 12:00 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/30/15 22:02 7440-36-008/25/15 18:306.0 3.8 1 Arsenic ND ug/L 08/30/15 22:02 7440-38-208/25/15 18:3010.0 2.5 1 Barium 32.5J ug/L 08/30/15 22:02 7440-39-308/25/15 18:301002.5 1 Beryllium ND ug/L 08/30/15 22:02 7440-41-708/25/15 18:301.0 0.50 1 Cadmium ND ug/L 08/30/15 22:02 7440-43-908/25/15 18:301.0 0.50 1 Chromium ND ug/L 08/30/15 22:02 7440-47-308/25/15 18:3010.0 2.5 1 Cobalt ND ug/L 08/30/15 22:02 7440-48-408/25/15 18:3010.0 2.5 1 Copper ND ug/L 08/30/15 22:02 7440-50-808/25/15 18:3010.0 2.5 1 Lead ND ug/L 08/30/15 22:02 7439-92-108/25/15 18:3010.0 2.5 1 Nickel ND ug/L 08/30/15 22:02 7440-02-008/25/15 18:3050.0 2.5 1 Selenium ND ug/L 08/30/15 22:02 7782-49-208/25/15 18:3010.0 5.0 1 Silver ND ug/L 08/30/15 22:02 7440-22-408/25/15 18:3010.0 2.5 1 Thallium ND ug/L 08/30/15 22:02 7440-28-008/25/15 18:305.5 5.0 1 Vanadium ND ug/L 08/30/15 22:02 7440-62-208/25/15 18:3025.0 2.5 1 Zinc ND ug/L 08/30/15 22:02 7440-66-608/25/15 18:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 05:04 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 05:04 107-13-12001.9 1 Benzene 1.1 ug/L 09/01/15 05:04 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 05:04 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 05:04 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 05:04 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 05:04 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 05:04 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 05:04 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 05:04 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 05:04 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 05:04 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 05:04 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 05:04 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 05:04 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 05:04 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 05:04 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 05:04 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 05:04 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 05:04 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 05:04 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 05:04 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 05:04 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 05:04 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 05:04 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 05:04 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 05:04 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 05:04 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 05:04 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-13 Lab ID:92264552013 Collected:08/20/15 12:00 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 05:04 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 05:04 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 05:04 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 05:04 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 09/01/15 05:04 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 05:04 108-10-11000.33 1 Styrene ND ug/L 09/01/15 05:04 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 05:04 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 05:04 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 05:04 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 05:04 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 05:04 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 05:04 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 05:04 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 05:04 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 05:04 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 05:04 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 05:04 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 05:04 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)102 %09/01/15 05:04 460-00-470-130 1 1,2-Dichloroethane-d4 (S)116 %09/01/15 05:04 17060-07-070-130 1 Toluene-d8 (S)102 %09/01/15 05:04 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-14 Lab ID:92264552014 Collected:08/20/15 10:15 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/30/15 22:05 7440-36-008/25/15 18:306.0 3.8 1 Arsenic ND ug/L 08/30/15 22:05 7440-38-208/25/15 18:3010.0 2.5 1 Barium 27.6J ug/L 08/30/15 22:05 7440-39-308/25/15 18:301002.5 1 Beryllium ND ug/L 08/30/15 22:05 7440-41-708/25/15 18:301.0 0.50 1 Cadmium 1.5 ug/L 08/30/15 22:05 7440-43-908/25/15 18:301.0 0.50 1 Chromium ND ug/L 08/30/15 22:05 7440-47-308/25/15 18:3010.0 2.5 1 Cobalt ND ug/L 08/30/15 22:05 7440-48-408/25/15 18:3010.0 2.5 1 Copper ND ug/L 08/30/15 22:05 7440-50-808/25/15 18:3010.0 2.5 1 Lead ND ug/L 08/30/15 22:05 7439-92-108/25/15 18:3010.0 2.5 1 Nickel ND ug/L 08/30/15 22:05 7440-02-008/25/15 18:3050.0 2.5 1 Selenium ND ug/L 08/30/15 22:05 7782-49-208/25/15 18:3010.0 5.0 1 Silver ND ug/L 08/30/15 22:05 7440-22-408/25/15 18:3010.0 2.5 1 Thallium ND ug/L 08/30/15 22:05 7440-28-008/25/15 18:305.5 5.0 1 Vanadium ND ug/L 08/30/15 22:05 7440-62-208/25/15 18:3025.0 2.5 1 Zinc ND ug/L 08/30/15 22:05 7440-66-608/25/15 18:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 05:20 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 05:20 107-13-12001.9 1 Benzene ND ug/L 09/01/15 05:20 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 05:20 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 05:20 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 05:20 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 05:20 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 05:20 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 05:20 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 05:20 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 05:20 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 05:20 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 05:20 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 05:20 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 05:20 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 05:20 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 05:20 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 05:20 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 05:20 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 05:20 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 05:20 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 05:20 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 05:20 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 05:20 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 05:20 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 05:20 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 05:20 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 05:20 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 05:20 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-14 Lab ID:92264552014 Collected:08/20/15 10:15 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 05:20 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 05:20 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 05:20 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 05:20 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 09/01/15 05:20 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 05:20 108-10-11000.33 1 Styrene ND ug/L 09/01/15 05:20 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 05:20 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 05:20 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 05:20 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 05:20 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 05:20 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 05:20 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 05:20 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 05:20 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 05:20 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 05:20 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 05:20 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 05:20 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)102 %09/01/15 05:20 460-00-470-130 1 1,2-Dichloroethane-d4 (S)118 %09/01/15 05:20 17060-07-070-130 1 Toluene-d8 (S)102 %09/01/15 05:20 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-15 Lab ID:92264552015 Collected:08/20/15 09:50 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/30/15 22:08 7440-36-008/25/15 18:306.0 3.8 1 Arsenic ND ug/L 08/30/15 22:08 7440-38-208/25/15 18:3010.0 2.5 1 Barium 3.6J ug/L 08/30/15 22:08 7440-39-308/25/15 18:301002.5 1 Beryllium ND ug/L 08/30/15 22:08 7440-41-708/25/15 18:301.0 0.50 1 Cadmium 2.0 ug/L 08/30/15 22:08 7440-43-908/25/15 18:301.0 0.50 1 Chromium ND ug/L 08/30/15 22:08 7440-47-308/25/15 18:3010.0 2.5 1 Cobalt ND ug/L 08/30/15 22:08 7440-48-408/25/15 18:3010.0 2.5 1 Copper ND ug/L 08/30/15 22:08 7440-50-808/25/15 18:3010.0 2.5 1 Lead ND ug/L 08/30/15 22:08 7439-92-108/25/15 18:3010.0 2.5 1 Nickel ND ug/L 08/30/15 22:08 7440-02-008/25/15 18:3050.0 2.5 1 Selenium ND ug/L 08/30/15 22:08 7782-49-208/25/15 18:3010.0 5.0 1 Silver ND ug/L 08/30/15 22:08 7440-22-408/25/15 18:3010.0 2.5 1 Thallium ND ug/L 08/30/15 22:08 7440-28-008/25/15 18:305.5 5.0 1 Vanadium ND ug/L 08/30/15 22:08 7440-62-208/25/15 18:3025.0 2.5 1 Zinc ND ug/L 08/30/15 22:08 7440-66-608/25/15 18:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 05:37 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 05:37 107-13-12001.9 1 Benzene ND ug/L 09/01/15 05:37 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 05:37 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 05:37 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 05:37 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 05:37 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 05:37 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 05:37 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 05:37 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 05:37 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 05:37 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 05:37 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 05:37 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 05:37 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 05:37 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 05:37 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 05:37 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 05:37 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 05:37 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 05:37 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 05:37 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 05:37 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 05:37 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 05:37 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 05:37 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 05:37 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 05:37 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 05:37 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-15 Lab ID:92264552015 Collected:08/20/15 09:50 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 05:37 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 05:37 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 05:37 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 05:37 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 09/01/15 05:37 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 05:37 108-10-11000.33 1 Styrene ND ug/L 09/01/15 05:37 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 05:37 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 05:37 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 05:37 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 05:37 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 05:37 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 05:37 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 05:37 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 05:37 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 05:37 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 05:37 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 05:37 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 05:37 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)102 %09/01/15 05:37 460-00-470-130 1 1,2-Dichloroethane-d4 (S)117 %09/01/15 05:37 17060-07-070-130 1 Toluene-d8 (S)102 %09/01/15 05:37 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-16R Lab ID:92264552016 Collected:08/20/15 15:35 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/30/15 22:11 7440-36-008/25/15 18:306.0 3.8 1 Arsenic ND ug/L 08/30/15 22:11 7440-38-208/25/15 18:3010.0 2.5 1 Barium 43.2J ug/L 08/30/15 22:11 7440-39-308/25/15 18:301002.5 1 Beryllium ND ug/L 08/30/15 22:11 7440-41-708/25/15 18:301.0 0.50 1 Cadmium 2.7 ug/L 08/30/15 22:11 7440-43-908/25/15 18:301.0 0.50 1 Chromium ND ug/L 08/30/15 22:11 7440-47-308/25/15 18:3010.0 2.5 1 Cobalt ND ug/L 08/30/15 22:11 7440-48-408/25/15 18:3010.0 2.5 1 Copper ND ug/L 08/30/15 22:11 7440-50-808/25/15 18:3010.0 2.5 1 Lead ND ug/L 08/30/15 22:11 7439-92-108/25/15 18:3010.0 2.5 1 Nickel ND ug/L 08/30/15 22:11 7440-02-008/25/15 18:3050.0 2.5 1 Selenium ND ug/L 08/30/15 22:11 7782-49-208/25/15 18:3010.0 5.0 1 Silver ND ug/L 08/30/15 22:11 7440-22-408/25/15 18:3010.0 2.5 1 Thallium ND ug/L 08/30/15 22:11 7440-28-008/25/15 18:305.5 5.0 1 Vanadium 3.9J ug/L 08/30/15 22:11 7440-62-208/25/15 18:3025.0 2.5 1 Zinc ND ug/L 08/30/15 22:11 7440-66-608/25/15 18:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 05:54 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 05:54 107-13-12001.9 1 Benzene ND ug/L 09/01/15 05:54 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 05:54 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 05:54 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 05:54 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 05:54 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 05:54 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 05:54 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 05:54 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 05:54 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 05:54 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 05:54 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 05:54 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 05:54 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 05:54 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 05:54 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 05:54 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 05:54 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 05:54 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 05:54 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 05:54 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 05:54 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 05:54 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 05:54 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 05:54 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 05:54 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 05:54 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 05:54 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:MW-16R Lab ID:92264552016 Collected:08/20/15 15:35 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 05:54 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 05:54 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 05:54 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 05:54 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 09/01/15 05:54 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 05:54 108-10-11000.33 1 Styrene ND ug/L 09/01/15 05:54 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 05:54 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 05:54 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 05:54 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 05:54 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 05:54 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 05:54 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 05:54 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 05:54 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 05:54 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 05:54 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 05:54 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 05:54 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)102 %09/01/15 05:54 460-00-470-130 1 1,2-Dichloroethane-d4 (S)118 %09/01/15 05:54 17060-07-070-130 1 Toluene-d8 (S)102 %09/01/15 05:54 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:SW-4 Lab ID:92264552017 Collected:08/20/15 12:25 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/30/15 22:14 7440-36-008/25/15 18:306.0 3.8 1 Arsenic ND ug/L 08/30/15 22:14 7440-38-208/25/15 18:3010.0 2.5 1 Barium 223 ug/L 08/30/15 22:14 7440-39-308/25/15 18:301002.5 1 Beryllium ND ug/L 08/30/15 22:14 7440-41-708/25/15 18:301.0 0.50 1 Cadmium 2.4 ug/L 08/30/15 22:14 7440-43-908/25/15 18:301.0 0.50 1 Chromium ND ug/L 08/30/15 22:14 7440-47-308/25/15 18:3010.0 2.5 1 Cobalt ND ug/L 08/30/15 22:14 7440-48-408/25/15 18:3010.0 2.5 1 Copper 4.2J ug/L 08/30/15 22:14 7440-50-808/25/15 18:3010.0 2.5 1 Lead ND ug/L 08/30/15 22:14 7439-92-108/25/15 18:3010.0 2.5 1 Nickel ND ug/L 08/30/15 22:14 7440-02-008/25/15 18:3050.0 2.5 1 Selenium ND ug/L 08/30/15 22:14 7782-49-208/25/15 18:3010.0 5.0 1 Silver ND ug/L 08/30/15 22:14 7440-22-408/25/15 18:3010.0 2.5 1 Thallium ND ug/L 08/30/15 22:14 7440-28-008/25/15 18:305.5 5.0 1 Vanadium ND ug/L 08/30/15 22:14 7440-62-208/25/15 18:3025.0 2.5 1 Zinc 10.4 ug/L 08/30/15 22:14 7440-66-608/25/15 18:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone 10.7J ug/L 09/01/15 06:11 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 06:11 107-13-12001.9 1 Benzene ND ug/L 09/01/15 06:11 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 06:11 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 06:11 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 06:11 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 06:11 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 06:11 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 06:11 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 06:11 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 06:11 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 06:11 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 06:11 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 06:11 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 06:11 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 06:11 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 06:11 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 06:11 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 06:11 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 06:11 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 06:11 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 06:11 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 06:11 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 06:11 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 06:11 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 06:11 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 06:11 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 06:11 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 06:11 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 38 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:SW-4 Lab ID:92264552017 Collected:08/20/15 12:25 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 06:11 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 06:11 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 06:11 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 06:11 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 09/01/15 06:11 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 06:11 108-10-11000.33 1 Styrene ND ug/L 09/01/15 06:11 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 06:11 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 06:11 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 06:11 127-18-41.0 0.46 1 Toluene 3.6 ug/L 09/01/15 06:11 108-88-3 D61.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 06:11 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 06:11 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 06:11 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 06:11 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 06:11 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 06:11 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 06:11 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 06:11 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %09/01/15 06:11 460-00-470-130 1 1,2-Dichloroethane-d4 (S)118 %09/01/15 06:11 17060-07-070-130 1 Toluene-d8 (S)100 %09/01/15 06:11 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 39 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:SW-5 Lab ID:92264552018 Collected:08/20/15 09:55 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/30/15 22:17 7440-36-008/25/15 18:306.0 3.8 1 Arsenic ND ug/L 08/30/15 22:17 7440-38-208/25/15 18:3010.0 2.5 1 Barium 317 ug/L 08/30/15 22:17 7440-39-308/25/15 18:301002.5 1 Beryllium ND ug/L 08/30/15 22:17 7440-41-708/25/15 18:301.0 0.50 1 Cadmium ND ug/L 08/30/15 22:17 7440-43-908/25/15 18:301.0 0.50 1 Chromium ND ug/L 08/30/15 22:17 7440-47-308/25/15 18:3010.0 2.5 1 Cobalt ND ug/L 08/30/15 22:17 7440-48-408/25/15 18:3010.0 2.5 1 Copper ND ug/L 08/30/15 22:17 7440-50-808/25/15 18:3010.0 2.5 1 Lead ND ug/L 08/30/15 22:17 7439-92-108/25/15 18:3010.0 2.5 1 Nickel ND ug/L 08/30/15 22:17 7440-02-008/25/15 18:3050.0 2.5 1 Selenium ND ug/L 08/30/15 22:17 7782-49-208/25/15 18:3010.0 5.0 1 Silver ND ug/L 08/30/15 22:17 7440-22-408/25/15 18:3010.0 2.5 1 Thallium ND ug/L 08/30/15 22:17 7440-28-008/25/15 18:305.5 5.0 1 Vanadium ND ug/L 08/30/15 22:17 7440-62-208/25/15 18:3025.0 2.5 1 Zinc 7.7J ug/L 08/30/15 22:17 7440-66-608/25/15 18:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 06:28 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 06:28 107-13-12001.9 1 Benzene ND ug/L 09/01/15 06:28 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 06:28 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 06:28 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 06:28 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 06:28 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 06:28 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 06:28 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 06:28 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 06:28 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 06:28 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 06:28 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 06:28 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 06:28 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 06:28 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 06:28 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 06:28 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 06:28 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 06:28 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 06:28 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 06:28 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 06:28 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 06:28 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 06:28 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 06:28 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 06:28 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 06:28 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 06:28 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 40 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:SW-5 Lab ID:92264552018 Collected:08/20/15 09:55 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 06:28 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 06:28 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 06:28 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 06:28 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 09/01/15 06:28 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 06:28 108-10-11000.33 1 Styrene ND ug/L 09/01/15 06:28 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 06:28 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 06:28 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 06:28 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 06:28 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 06:28 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 06:28 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 06:28 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 06:28 75-69-4 M11.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 06:28 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 06:28 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 06:28 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 06:28 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)102 %09/01/15 06:28 460-00-470-130 1 1,2-Dichloroethane-d4 (S)118 %09/01/15 06:28 17060-07-070-130 1 Toluene-d8 (S)102 %09/01/15 06:28 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 41 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:LE-1 Lab ID:92264552019 Collected:08/20/15 17:30 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony 13.1 ug/L 08/30/15 22:21 7440-36-008/25/15 18:306.0 3.8 1 Arsenic 8.6J ug/L 08/30/15 22:21 7440-38-208/25/15 18:3010.0 2.5 1 Barium 154 ug/L 08/30/15 22:21 7440-39-308/25/15 18:301002.5 1 Beryllium ND ug/L 08/30/15 22:21 7440-41-708/25/15 18:301.0 0.50 1 Cadmium ND ug/L 08/30/15 22:21 7440-43-908/25/15 18:301.0 0.50 1 Chromium 40.0 ug/L 08/30/15 22:21 7440-47-308/25/15 18:3010.0 2.5 1 Cobalt 3.2J ug/L 08/30/15 22:21 7440-48-408/25/15 18:3010.0 2.5 1 Copper 3.3J ug/L 08/30/15 22:21 7440-50-808/25/15 18:3010.0 2.5 1 Lead 2.7J ug/L 08/30/15 22:21 7439-92-108/25/15 18:3010.0 2.5 1 Nickel 48.5J ug/L 08/30/15 22:21 7440-02-008/25/15 18:3050.0 2.5 1 Selenium ND ug/L 08/30/15 22:21 7782-49-208/25/15 18:3010.0 5.0 1 Silver ND ug/L 08/30/15 22:21 7440-22-408/25/15 18:3010.0 2.5 1 Thallium ND ug/L 08/30/15 22:21 7440-28-008/25/15 18:305.5 5.0 1 Vanadium 6.9J ug/L 08/30/15 22:21 7440-62-208/25/15 18:3025.0 2.5 1 Zinc 508 ug/L 08/30/15 22:21 7440-66-608/25/15 18:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone 157 ug/L 09/01/15 13:23 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 13:23 107-13-12001.9 1 Benzene 0.80J ug/L 09/01/15 13:23 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 13:23 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 13:23 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 13:23 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 13:23 74-83-910.0 0.29 1 2-Butanone (MEK)362J ug/L 09/02/15 11:31 78-93-310009.6 10 Carbon disulfide 1.9J ug/L 09/01/15 13:23 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 13:23 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 13:23 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 13:23 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 13:23 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 13:23 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 13:23 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 13:23 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 13:23 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 13:23 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 13:23 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 13:23 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 13:23 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 13:23 75-34-35.0 0.32 1 1,2-Dichloroethane 0.97J ug/L 09/01/15 13:23 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 13:23 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 13:23 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 13:23 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 13:23 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 13:23 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 13:23 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 42 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Sample:LE-1 Lab ID:92264552019 Collected:08/20/15 17:30 Received:08/21/15 15:25 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 13:23 10061-02-61.0 0.26 1 Ethylbenzene 0.37J ug/L 09/01/15 13:23 100-41-41.0 0.30 1 2-Hexanone 1.4J ug/L 09/01/15 13:23 591-78-650.0 0.46 1 Iodomethane 0.69J ug/L 09/01/15 13:23 74-88-4 B,C910.0 0.32 1 Methylene Chloride 1.7 ug/L 09/01/15 13:23 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)6.6J ug/L 09/01/15 13:23 108-10-11000.33 1 Styrene ND ug/L 09/01/15 13:23 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 13:23 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 13:23 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 13:23 127-18-41.0 0.46 1 Toluene 59.4 ug/L 09/01/15 13:23 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 13:23 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 13:23 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 13:23 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 13:23 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 13:23 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 13:23 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 13:23 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 13:23 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)101 %09/01/15 13:23 460-00-470-130 1 1,2-Dichloroethane-d4 (S)93 %09/01/15 13:23 17060-07-070-130 1 Toluene-d8 (S)101 %09/01/15 13:23 2037-26-570-130 1 Analytical Method: SM 5210B5210B BOD, 5 day BOD, 5 day 329000 ug/L 08/27/15 03:2808/22/15 00:52200020001 Analytical Method: EPA 90409040 pH pH 7.2 Std. Units 08/23/15 12:25 H60.10 0.10 1 Analytical Method: EPA 300.0300.0 IC Anions 28 Days Sulfate 28900J ug/L 09/01/15 09:50 14808-79-825000001000010 Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate ND ug/L 08/22/15 02:171000010.0 1 Analytical Method: EPA 365.1365.1 Phosphorus, Total Phosphorus 1760 ug/L 08/28/15 12:46 7723-14-050.0 25.0 1 Analytical Method: SM 5220D5220D COD Chemical Oxygen Demand 956000 ug/L 08/26/15 15:1525000125001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 43 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/19333 EPA 3010 EPA 6010 6010 MET NC Groundwater Associated Lab Samples:92264552001, 92264552002, 92264552003, 92264552004, 92264552005, 92264552006, 92264552007, 92264552008, 92264552009, 92264552010, 92264552011, 92264552012, 92264552013, 92264552014, 92264552015, 92264552016, 92264552017, 92264552018, 92264552019 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1540919 Associated Lab Samples:92264552001, 92264552002, 92264552003, 92264552004, 92264552005, 92264552006, 92264552007, 92264552008, 92264552009, 92264552010, 92264552011, 92264552012, 92264552013, 92264552014, 92264552015, 92264552016, 92264552017, 92264552018, 92264552019 Matrix:Water Analyzed Antimony ug/L ND 6.0 08/30/15 20:52 Arsenic ug/L ND 10.0 08/30/15 20:52 Barium ug/L ND 100 08/30/15 20:52 Beryllium ug/L ND 1.0 08/30/15 20:52 Cadmium ug/L ND 1.0 08/30/15 20:52 Chromium ug/L ND 10.0 08/30/15 20:52 Cobalt ug/L ND 10.0 08/30/15 20:52 Copper ug/L ND 10.0 08/30/15 20:52 Lead ug/L ND 10.0 08/30/15 20:52 Nickel ug/L ND 50.0 08/30/15 20:52 Selenium ug/L ND 10.0 08/30/15 20:52 Silver ug/L ND 10.0 08/30/15 20:52 Thallium ug/L ND 5.5 08/30/15 20:52 Vanadium ug/L ND 25.0 08/30/15 20:52 Zinc ug/L ND 10.0 08/30/15 20:52 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1540920LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 424417 102 80-120 Arsenic ug/L 410417 98 80-120 Barium ug/L 422417 101 80-120 Beryllium ug/L 422417 101 80-120 Cadmium ug/L 410417 98 80-120 Chromium ug/L 413417 99 80-120 Cobalt ug/L 418417 100 80-120 Copper ug/L 425417 102 80-120 Lead ug/L 413417 99 80-120 Nickel ug/L 407417 98 80-120 Selenium ug/L 406417 98 80-120 Silver ug/L 209208 100 80-120 Thallium ug/L 422417 101 80-120 Vanadium ug/L 420417 101 80-120 Zinc ug/L 407417 98 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 44 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1540921MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92263765018 1540922 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony ug/L 417 91 75-12595 4 25417ND384398 Arsenic ug/L 417 89 75-12593 4 254173.1J 376 390 Barium ug/L 417 89 75-12591 1 25417209581589 Beryllium ug/L 417 91 75-12594 3 25417ND378391 Cadmium ug/L 417 88 75-12591 4 25417ND365379 Chromium ug/L 417 87 75-12590 4 25417ND361375 Cobalt ug/L 417 87 75-12590 4 25417ND362376 Copper ug/L 417 91 75-12594 3 25417ND380392 Lead ug/L 417 85 75-12589 4 254173.4J 358 373 Nickel ug/L 417 84 75-12587 4 254173.6J 352 365 Selenium ug/L 417 87 75-12590 4 25417ND365378 Silver ug/L 208 89 75-12593 4 25208ND187194 Thallium ug/L 417 87 75-12591 5 25417ND364381 Vanadium ug/L 417 90 75-12594 4 25417ND376391 Zinc ug/L 417 85 75-12588 4 25417ND355370 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 45 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MSV/33196 EPA 8260 EPA 8260 8260 MSV Low Level Landfill Associated Lab Samples:92264552001, 92264552002, 92264552003, 92264552004, 92264552005, 92264552006, 92264552007, 92264552008, 92264552009, 92264552010, 92264552011, 92264552012, 92264552013, 92264552014, 92264552015, 92264552016, 92264552017, 92264552018 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1545465 Associated Lab Samples:92264552001, 92264552002, 92264552003, 92264552004, 92264552005, 92264552006, 92264552007, 92264552008, 92264552009, 92264552010, 92264552011, 92264552012, 92264552013, 92264552014, 92264552015, 92264552016, 92264552017, 92264552018 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 09/01/15 01:06 1,1,1-Trichloroethane ug/L ND 1.0 09/01/15 01:06 1,1,2,2-Tetrachloroethane ug/L ND 3.0 09/01/15 01:06 1,1,2-Trichloroethane ug/L ND 1.0 09/01/15 01:06 1,1-Dichloroethane ug/L ND 5.0 09/01/15 01:06 1,1-Dichloroethene ug/L ND 5.0 09/01/15 01:06 1,2,3-Trichloropropane ug/L ND 1.0 09/01/15 01:06 1,2-Dibromo-3-chloropropane ug/L ND 13.0 09/01/15 01:06 1,2-Dibromoethane (EDB)ug/L ND 1.0 09/01/15 01:06 1,2-Dichlorobenzene ug/L ND 5.0 09/01/15 01:06 1,2-Dichloroethane ug/L ND 1.0 09/01/15 01:06 1,2-Dichloropropane ug/L ND 1.0 09/01/15 01:06 1,3-Dichloropropane ug/L ND 1.0 09/01/15 01:06 1,4-Dichlorobenzene ug/L ND 1.0 09/01/15 01:06 2-Butanone (MEK)ug/L ND 100 09/01/15 01:06 2-Hexanone ug/L ND 50.0 09/01/15 01:06 4-Methyl-2-pentanone (MIBK)ug/L ND 100 09/01/15 01:06 Acetone ug/L ND 100 09/01/15 01:06 Acrylonitrile ug/L ND 200 09/01/15 01:06 Benzene ug/L ND 1.0 09/01/15 01:06 Bromochloromethane ug/L ND 3.0 09/01/15 01:06 Bromodichloromethane ug/L ND 1.0 09/01/15 01:06 Bromoform ug/L ND 3.0 09/01/15 01:06 Bromomethane ug/L ND 10.0 09/01/15 01:06 Carbon disulfide ug/L ND 100 09/01/15 01:06 Carbon tetrachloride ug/L ND 1.0 09/01/15 01:06 Chlorobenzene ug/L ND 3.0 09/01/15 01:06 Chloroethane ug/L ND 10.0 09/01/15 01:06 Chloroform ug/L ND 5.0 09/01/15 01:06 Chloromethane ug/L ND 1.0 09/01/15 01:06 cis-1,2-Dichloroethene ug/L ND 5.0 09/01/15 01:06 cis-1,3-Dichloropropene ug/L ND 1.0 09/01/15 01:06 Dibromochloromethane ug/L ND 3.0 09/01/15 01:06 Dibromomethane ug/L ND 10.0 09/01/15 01:06 Ethylbenzene ug/L ND 1.0 09/01/15 01:06 Iodomethane ug/L ND 10.0 09/01/15 01:06 Methylene Chloride ug/L ND 1.0 09/01/15 01:06 Styrene ug/L ND 1.0 09/01/15 01:06 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 46 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1545465 Associated Lab Samples:92264552001, 92264552002, 92264552003, 92264552004, 92264552005, 92264552006, 92264552007, 92264552008, 92264552009, 92264552010, 92264552011, 92264552012, 92264552013, 92264552014, 92264552015, 92264552016, 92264552017, 92264552018 Matrix:Water Analyzed Tetrachloroethene ug/L ND 1.0 09/01/15 01:06 Toluene ug/L ND 1.0 09/01/15 01:06 trans-1,2-Dichloroethene ug/L ND 5.0 09/01/15 01:06 trans-1,3-Dichloropropene ug/L ND 1.0 09/01/15 01:06 trans-1,4-Dichloro-2-butene ug/L ND 100 09/01/15 01:06 Trichloroethene ug/L ND 1.0 09/01/15 01:06 Trichlorofluoromethane ug/L ND 1.0 09/01/15 01:06 Vinyl acetate ug/L ND 50.0 09/01/15 01:06 Vinyl chloride ug/L ND 1.0 09/01/15 01:06 Xylene (Total)ug/L ND 5.0 09/01/15 01:06 1,2-Dichloroethane-d4 (S)%116 70-130 09/01/15 01:06 4-Bromofluorobenzene (S)%102 70-130 09/01/15 01:06 Toluene-d8 (S)%103 70-130 09/01/15 01:06 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1545466LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 45.050 90 80-125 1,1,1-Trichloroethane ug/L 54.450 109 71-129 1,1,2,2-Tetrachloroethane ug/L 46.350 93 79-124 1,1,2-Trichloroethane ug/L 48.550 97 85-125 1,1-Dichloroethane ug/L 47.850 96 73-126 1,1-Dichloroethene ug/L 57.450 115 66-135 1,2,3-Trichloropropane ug/L 50.550 101 75-130 1,2-Dibromo-3-chloropropane ug/L 49.850 100 71-133 1,2-Dibromoethane (EDB)ug/L 50.650 101 83-124 1,2-Dichlorobenzene ug/L 47.150 94 80-133 1,2-Dichloroethane ug/L 49.050 98 67-128 1,2-Dichloropropane ug/L 44.650 89 75-132 1,3-Dichloropropane ug/L 45.450 91 76-131 1,4-Dichlorobenzene ug/L 46.950 94 78-130 2-Butanone (MEK)ug/L 98.8J100 99 61-144 2-Hexanone ug/L 102100 102 68-143 4-Methyl-2-pentanone (MIBK)ug/L 102100 102 72-135 Acetone ug/L 105100 105 48-146 Acrylonitrile ug/L 267250 107 40-160 Benzene ug/L 47.550 95 80-125 Bromochloromethane ug/L 50.950 102 71-125 Bromodichloromethane ug/L 52.350 105 78-124 Bromoform ug/L 38.950 78 71-128 Bromomethane ug/L 35.750 71 40-160 Carbon disulfide ug/L 43.1J50 86 50-160 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 47 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1545466LABORATORY CONTROL SAMPLE: LCSSpike Carbon tetrachloride ug/L 49.950 100 69-131 Chlorobenzene ug/L 46.250 92 81-122 Chloroethane ug/L 46.050 92 39-148 Chloroform ug/L 51.950 104 73-127 Chloromethane ug/L 38.250 76 44-146 cis-1,2-Dichloroethene ug/L 50.750 101 74-124 cis-1,3-Dichloropropene ug/L 48.650 97 72-132 Dibromochloromethane ug/L 44.950 90 78-125 Dibromomethane ug/L 49.350 99 82-120 Ethylbenzene ug/L 45.850 92 79-121 Iodomethane ug/L 81.0100 81 39-154 Methylene Chloride ug/L 49.750 99 64-133 Styrene ug/L 49.350 99 84-126 Tetrachloroethene ug/L 45.350 91 78-122 Toluene ug/L 46.450 93 80-121 trans-1,2-Dichloroethene ug/L 51.650 103 71-127 trans-1,3-Dichloropropene ug/L 51.650 103 69-141 trans-1,4-Dichloro-2-butene ug/L 52.2J50 104 40-160 Trichloroethene ug/L 45.750 91 78-122 Trichlorofluoromethane ug/L 51.650 103 53-137 Vinyl acetate ug/L 103100 103 40-160 Vinyl chloride ug/L 43.950 88 58-137 Xylene (Total)ug/L 142150 95 81-126 1,2-Dichloroethane-d4 (S)%112 70-130 4-Bromofluorobenzene (S)%106 70-130 Toluene-d8 (S)%100 70-130 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1545468MATRIX SPIKE SAMPLE: MSSpike Result 92264552018 1,1,1,2-Tetrachloroethane ug/L 21.720 109 70-130ND 1,1,1-Trichloroethane ug/L 26.120 130 70-130ND 1,1,2,2-Tetrachloroethane ug/L 21.420 107 70-130ND 1,1,2-Trichloroethane ug/L 22.520 113 70-130ND 1,1-Dichloroethane ug/L 22.420 112 70-130ND 1,1-Dichloroethene ug/L 28.520 143 70-166ND 1,2,3-Trichloropropane ug/L 24.120 121 70-130ND 1,2-Dibromo-3-chloropropane ug/L 22.120 110 70-130ND 1,2-Dibromoethane (EDB)ug/L 23.420 117 70-130ND 1,2-Dichlorobenzene ug/L 22.520 112 70-130ND 1,2-Dichloroethane ug/L 22.420 111 70-130ND 1,2-Dichloropropane ug/L 21.020 105 70-130ND 1,3-Dichloropropane ug/L 21.120 105 70-130ND 1,4-Dichlorobenzene ug/L 22.320 112 70-130ND 2-Butanone (MEK)ug/L 44.9J40 112 70-130ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 48 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1545468MATRIX SPIKE SAMPLE: MSSpike Result 92264552018 2-Hexanone ug/L 48.5J40 121 70-130ND 4-Methyl-2-pentanone (MIBK)ug/L 47.3J40 118 70-130ND Acetone ug/L 49.0J40 107 70-130ND Acrylonitrile ug/L 117J100 117 70-130ND Benzene ug/L 22.020 110 70-148ND Bromochloromethane ug/L 22.520 112 70-130ND Bromodichloromethane ug/L 24.020 120 70-130ND Bromoform ug/L 19.020 95 70-130ND Bromomethane ug/L 22.220 111 70-130ND Carbon disulfide ug/L 21.1J20 106 70-130ND Carbon tetrachloride ug/L 24.720 123 70-130ND Chlorobenzene ug/L 22.820 114 70-146ND Chloroethane ug/L 22.620 113 70-130ND Chloroform ug/L 23.920 119 70-130ND Chloromethane ug/L 18.320 91 70-130ND cis-1,2-Dichloroethene ug/L 23.520 118 70-130ND cis-1,3-Dichloropropene ug/L 21.620 108 70-130ND Dibromochloromethane ug/L 21.620 108 70-130ND Dibromomethane ug/L 22.520 112 70-130ND Ethylbenzene ug/L 23.020 115 70-130ND Iodomethane ug/L 35.340 88 70-130ND Methylene Chloride ug/L 21.820 109 70-130ND Styrene ug/L 22.820 114 70-130ND Tetrachloroethene ug/L 23.120 115 70-130ND Toluene ug/L 22.220 111 70-155ND trans-1,2-Dichloroethene ug/L 24.320 122 70-130ND trans-1,3-Dichloropropene ug/L 22.720 114 70-130ND trans-1,4-Dichloro-2-butene ug/L 22.9J20 115 70-130ND Trichloroethene ug/L 22.020 110 69-151ND Trichlorofluoromethane ug/L 26.5 M12013270-130ND Vinyl acetate ug/L 44.0J40 110 70-130ND Vinyl chloride ug/L 21.220 106 70-130ND 1,2-Dichloroethane-d4 (S)%110 70-130 4-Bromofluorobenzene (S)%108 70-130 Toluene-d8 (S)%100 70-130 Parameter Units Dup Result Max RPD QualifiersRPDResult 92264552017 1545467SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/L ND 30ND 1,1,1-Trichloroethane ug/L ND 30ND 1,1,2,2-Tetrachloroethane ug/L ND 30ND 1,1,2-Trichloroethane ug/L ND 30ND 1,1-Dichloroethane ug/L ND 30ND 1,1-Dichloroethene ug/L ND 30ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 49 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 92264552017 1545467SAMPLE DUPLICATE: 1,2,3-Trichloropropane ug/L ND 30ND 1,2-Dibromo-3-chloropropane ug/L ND 30ND 1,2-Dibromoethane (EDB)ug/L ND 30ND 1,2-Dichlorobenzene ug/L ND 30ND 1,2-Dichloroethane ug/L ND 30ND 1,2-Dichloropropane ug/L ND 30ND 1,3-Dichloropropane ug/L ND 30ND 1,4-Dichlorobenzene ug/L ND 30ND 2-Butanone (MEK)ug/L ND 30ND 2-Hexanone ug/L ND 30ND 4-Methyl-2-pentanone (MIBK)ug/L ND 30ND Acetone ug/L ND 3010.7J Acrylonitrile ug/L ND 30ND Benzene ug/L ND 30ND Bromochloromethane ug/L ND 30ND Bromodichloromethane ug/L ND 30ND Bromoform ug/L ND 30ND Bromomethane ug/L ND 30ND Carbon disulfide ug/L ND 30ND Carbon tetrachloride ug/L ND 30ND Chlorobenzene ug/L ND 30ND Chloroethane ug/L ND 30ND Chloroform ug/L ND 30ND Chloromethane ug/L ND 30ND cis-1,2-Dichloroethene ug/L ND 30ND cis-1,3-Dichloropropene ug/L ND 30ND Dibromochloromethane ug/L ND 30ND Dibromomethane ug/L ND 30ND Ethylbenzene ug/L ND 30ND Iodomethane ug/L ND 30ND Methylene Chloride ug/L ND 30ND Styrene ug/L ND 30ND Tetrachloroethene ug/L ND 30ND Toluene ug/L 2.6 D631303.6 trans-1,2-Dichloroethene ug/L ND 30ND trans-1,3-Dichloropropene ug/L ND 30ND trans-1,4-Dichloro-2-butene ug/L ND 30ND Trichloroethene ug/L ND 30ND Trichlorofluoromethane ug/L ND 30ND Vinyl acetate ug/L ND 30ND Vinyl chloride ug/L ND 30ND Xylene (Total)ug/L ND 30ND 1,2-Dichloroethane-d4 (S)%117 1118 4-Bromofluorobenzene (S)%103 3100 Toluene-d8 (S)%102 2100 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 50 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MSV/33199 EPA 8260 EPA 8260 8260 MSV Low Level Landfill Associated Lab Samples:92264552019 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1545743 Associated Lab Samples:92264552019 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 09/01/15 12:49 1,1,1-Trichloroethane ug/L ND 1.0 09/01/15 12:49 1,1,2,2-Tetrachloroethane ug/L ND 3.0 09/01/15 12:49 1,1,2-Trichloroethane ug/L ND 1.0 09/01/15 12:49 1,1-Dichloroethane ug/L ND 5.0 09/01/15 12:49 1,1-Dichloroethene ug/L ND 5.0 09/01/15 12:49 1,2,3-Trichloropropane ug/L ND 1.0 09/01/15 12:49 1,2-Dibromo-3-chloropropane ug/L ND 13.0 09/01/15 12:49 1,2-Dibromoethane (EDB)ug/L ND 1.0 09/01/15 12:49 1,2-Dichlorobenzene ug/L ND 5.0 09/01/15 12:49 1,2-Dichloroethane ug/L ND 1.0 09/01/15 12:49 1,2-Dichloropropane ug/L ND 1.0 09/01/15 12:49 1,3-Dichloropropane ug/L ND 1.0 09/01/15 12:49 1,4-Dichlorobenzene ug/L ND 1.0 09/01/15 12:49 2-Butanone (MEK)ug/L ND 100 09/01/15 12:49 2-Hexanone ug/L ND 50.0 09/01/15 12:49 4-Methyl-2-pentanone (MIBK)ug/L ND 100 09/01/15 12:49 Acetone ug/L ND 100 09/01/15 12:49 Acrylonitrile ug/L ND 200 09/01/15 12:49 Benzene ug/L ND 1.0 09/01/15 12:49 Bromochloromethane ug/L ND 3.0 09/01/15 12:49 Bromodichloromethane ug/L ND 1.0 09/01/15 12:49 Bromoform ug/L ND 3.0 09/01/15 12:49 Bromomethane ug/L ND 10.0 09/01/15 12:49 Carbon disulfide ug/L ND 100 09/01/15 12:49 Carbon tetrachloride ug/L ND 1.0 09/01/15 12:49 Chlorobenzene ug/L ND 3.0 09/01/15 12:49 Chloroethane ug/L ND 10.0 09/01/15 12:49 Chloroform ug/L ND 5.0 09/01/15 12:49 Chloromethane ug/L ND 1.0 09/01/15 12:49 cis-1,2-Dichloroethene ug/L ND 5.0 09/01/15 12:49 cis-1,3-Dichloropropene ug/L ND 1.0 09/01/15 12:49 Dibromochloromethane ug/L ND 3.0 09/01/15 12:49 Dibromomethane ug/L ND 10.0 09/01/15 12:49 Ethylbenzene ug/L ND 1.0 09/01/15 12:49 Iodomethane ug/L 0.49J 10.0 C909/01/15 12:49 Methylene Chloride ug/L ND 1.0 09/01/15 12:49 Styrene ug/L ND 1.0 09/01/15 12:49 Tetrachloroethene ug/L ND 1.0 09/01/15 12:49 Toluene ug/L ND 1.0 09/01/15 12:49 trans-1,2-Dichloroethene ug/L ND 5.0 09/01/15 12:49 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 51 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1545743 Associated Lab Samples:92264552019 Matrix:Water Analyzed trans-1,3-Dichloropropene ug/L ND 1.0 09/01/15 12:49 trans-1,4-Dichloro-2-butene ug/L ND 100 09/01/15 12:49 Trichloroethene ug/L ND 1.0 09/01/15 12:49 Trichlorofluoromethane ug/L ND 1.0 09/01/15 12:49 Vinyl acetate ug/L ND 50.0 09/01/15 12:49 Vinyl chloride ug/L ND 1.0 09/01/15 12:49 Xylene (Total)ug/L ND 5.0 09/01/15 12:49 1,2-Dichloroethane-d4 (S)%95 70-130 09/01/15 12:49 4-Bromofluorobenzene (S)%99 70-130 09/01/15 12:49 Toluene-d8 (S)%101 70-130 09/01/15 12:49 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1545744LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 52.450 105 80-125 1,1,1-Trichloroethane ug/L 44.050 88 71-129 1,1,2,2-Tetrachloroethane ug/L 51.050 102 79-124 1,1,2-Trichloroethane ug/L 48.150 96 85-125 1,1-Dichloroethane ug/L 42.350 85 73-126 1,1-Dichloroethene ug/L 49.750 99 66-135 1,2,3-Trichloropropane ug/L 49.650 99 75-130 1,2-Dibromo-3-chloropropane ug/L 54.950 110 71-133 1,2-Dibromoethane (EDB)ug/L 51.750 103 83-124 1,2-Dichlorobenzene ug/L 52.650 105 80-133 1,2-Dichloroethane ug/L 39.650 79 67-128 1,2-Dichloropropane ug/L 47.250 94 75-132 1,3-Dichloropropane ug/L 49.050 98 76-131 1,4-Dichlorobenzene ug/L 52.350 105 78-130 2-Butanone (MEK)ug/L 98.7J100 99 61-144 2-Hexanone ug/L 110100 110 68-143 4-Methyl-2-pentanone (MIBK)ug/L 102100 102 72-135 Acetone ug/L 86.1J100 86 48-146 Acrylonitrile ug/L 225250 90 40-160 Benzene ug/L 48.450 97 80-125 Bromochloromethane ug/L 45.050 90 71-125 Bromodichloromethane ug/L 48.150 96 78-124 Bromoform ug/L 42.250 84 71-128 Bromomethane ug/L 31.050 62 40-160 Carbon disulfide ug/L 41.4J50 83 50-160 Carbon tetrachloride ug/L 45.850 92 69-131 Chlorobenzene ug/L 49.750 99 81-122 Chloroethane ug/L 31.650 63 39-148 Chloroform ug/L 44.550 89 73-127 Chloromethane ug/L 36.250 72 44-146 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 52 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1545744LABORATORY CONTROL SAMPLE: LCSSpike cis-1,2-Dichloroethene ug/L 43.350 87 74-124 cis-1,3-Dichloropropene ug/L 50.650 101 72-132 Dibromochloromethane ug/L 46.750 93 78-125 Dibromomethane ug/L 46.650 93 82-120 Ethylbenzene ug/L 47.850 96 79-121 Iodomethane ug/L 79.0100 79 39-154 Methylene Chloride ug/L 41.850 84 64-133 Styrene ug/L 50.650 101 84-126 Tetrachloroethene ug/L 47.550 95 78-122 Toluene ug/L 46.450 93 80-121 trans-1,2-Dichloroethene ug/L 43.750 87 71-127 trans-1,3-Dichloropropene ug/L 50.150 100 69-141 trans-1,4-Dichloro-2-butene ug/L 56.0J50 112 40-160 Trichloroethene ug/L 47.350 95 78-122 Trichlorofluoromethane ug/L 36.550 73 53-137 Vinyl acetate ug/L 93.2100 93 40-160 Vinyl chloride ug/L 38.150 76 58-137 Xylene (Total)ug/L 145150 97 81-126 1,2-Dichloroethane-d4 (S)%92 70-130 4-Bromofluorobenzene (S)%97 70-130 Toluene-d8 (S)%97 70-130 Parameter Units MS Result % Rec Limits Qual% RecConc. 1545745MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92263765020 1545746 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 20 104 70-130111 7 3020ND20.8 22.2 1,1,1-Trichloroethane ug/L 20 98 70-130104 6 3020ND20.1 21.3 1,1,2,2-Tetrachloroethane ug/L 20 105 70-130110 4 3020ND21.0 22.0 1,1,2-Trichloroethane ug/L 20 101 70-130107 6 3020ND20.1 21.3 1,1-Dichloroethane ug/L 20 97 70-13099 2 30200.84J 20.3 20.6 1,1-Dichloroethene ug/L 20 107 70-166106 1 30200.95J 22.4 22.2 1,2,3-Trichloropropane ug/L 20 105 70-130107 2 3020ND21.0 21.4 1,2-Dibromo-3- chloropropane ug/L 20 102 70-130106 4 3020ND20.4 21.2 1,2-Dibromoethane (EDB)ug/L 20 107 70-130113 6 3020ND21.4 22.7 1,2-Dichlorobenzene ug/L 20 113 70-130117 4 3020ND22.5 23.5 1,2-Dichloroethane ug/L 20 86 70-13088 2 3020ND17.4 17.8 1,2-Dichloropropane ug/L 20 101 70-130106 5 3020ND20.2 21.3 1,3-Dichloropropane ug/L 20 103 70-130108 5 3020ND20.6 21.7 1,4-Dichlorobenzene ug/L 20 113 70-130116 3 3020ND22.5 23.3 2-Butanone (MEK)ug/L 40 95 70-13098 3 3040ND37.9J 39.0J 2-Hexanone ug/L 40 114 70-130118 3 3040ND45.7J 47.3J 4-Methyl-2-pentanone (MIBK)ug/L 40 102 70-130107 5 3040ND40.7J 42.6J Acetone ug/L 40 86 70-13088 2 3040ND35.8J 36.6J REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 53 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1545745MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92263765020 1545746 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Acrylonitrile ug/L 100 97 70-130104 7 30100ND97.3J 104J Benzene ug/L 20 106 70-148111 5 3020ND21.2 22.3 Bromochloromethane ug/L 20 108 70-130107 1 3020ND21.6 21.4 Bromodichloromethane ug/L 20 101 70-130112 11 3020ND20.1 22.4 Bromoform ug/L 20 82 70-13093 13 3020ND16.3 18.5 Bromomethane ug/L 20 79 70-13083 6 3020ND15.9 16.8 Carbon disulfide ug/L 20 100 70-130100 0 3020ND20.0J 20.0J Carbon tetrachloride ug/L 20 101 70-130108 7 3020ND20.1 21.5 Chlorobenzene ug/L 20 108 70-146114 5 3020ND21.6 22.8 Chloroethane ug/L 20 81 70-13082 1 3020ND16.2 16.4 Chloroform ug/L 20 101 70-130101 0 3020ND20.1 20.1 Chloromethane ug/L 20 75 70-13077 2 3020ND15.0 15.3 cis-1,2-Dichloroethene ug/L 20 109 70-13072 8 302069.3 91.0 83.7 cis-1,3-Dichloropropene ug/L 20 101 70-130110 8 3020ND20.2 21.9 Dibromochloromethane ug/L 20 92 70-130104 12 3020ND18.4 20.8 Dibromomethane ug/L 20 99 70-130104 5 3020ND19.8 20.9 Ethylbenzene ug/L 20 107 70-130111 4 3020ND21.4 22.3 Iodomethane ug/L 40 84 70-13084 0 30400.48J 33.9 33.9 Methylene Chloride ug/L 20 90 70-13089 1 3020ND17.9 17.8 Styrene ug/L 20 109 70-130114 5 3020ND21.8 22.8 Tetrachloroethene ug/L 20 106 70-130110 4 3020ND21.1 22.1 Toluene ug/L 20 102 70-155106 4 3020ND20.3 21.2 trans-1,2-Dichloroethene ug/L 20 102 70-130102 0 3020ND20.5 20.6 trans-1,3-Dichloropropene ug/L 20 101 70-130108 7 3020ND20.3 21.7 trans-1,4-Dichloro-2-butene ug/L 20 122 70-130122 0 3020ND24.5J 24.5J Trichloroethene ug/L 20 114 69-151124 2 302066.2 88.9 91.0 Trichlorofluoromethane ug/L 20 92 70-13095 3 3020ND18.5 19.0 Vinyl acetate ug/L 40 91 70-13093 2 3040ND36.5J 37.4J Vinyl chloride ug/L 20 93 70-13095 2 3020ND19.1 19.4 1,2-Dichloroethane-d4 (S)%94 70-13092 4-Bromofluorobenzene (S)%99 70-13098 Toluene-d8 (S)%97 70-13098 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 54 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/39629 SM 5210B SM 5210B 5210B BOD, 5 day Associated Lab Samples:92264552019 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1539760 Associated Lab Samples:92264552019 Matrix:Water Analyzed BOD, 5 day ug/L ND 2000 08/27/15 03:28 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1539761LABORATORY CONTROL SAMPLE: LCSSpike BOD, 5 day ug/L 174000198000 88 84.6-115.4 Parameter Units Dup Result Max RPD QualifiersRPDResult 92264552019 1539762SAMPLE DUPLICATE: BOD, 5 day ug/L 304000 8 10329000 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 55 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/39640 EPA 9040 EPA 9040 9040 pH Associated Lab Samples:92264552019 Parameter Units Dup Result Max RPD QualifiersRPDResult 92264137001 1539803SAMPLE DUPLICATE: pH Std. Units 6.4 H6096.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 56 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/24312 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples:92264552019 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1544897 Associated Lab Samples:92264552019 Matrix:Water Analyzed Sulfate ug/L ND 250000 08/31/15 20:58 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1544898LABORATORY CONTROL SAMPLE: LCSSpike Sulfate ug/L 19700J20000 99 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1544899MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92263765020 1544900 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate ug/L 20000 109 90-110110 0 102000016.9 mg/L 38700J 38900J Parameter Units MS Result % Rec Limits Qual% RecConc. 1544901MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92265308001 1544902 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate ug/L 20000 104 90-110104 0 102000012.0 mg/L 32800J 32800J REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 57 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/24210 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92264552019 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1539766 Associated Lab Samples:92264552019 Matrix:Water Analyzed Nitrogen, Nitrate ug/L ND 20.0 08/22/15 02:08 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1539767LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate ug/L 24402500 98 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1539768MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92264495001 1539769 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate ug/L 2500 102 90-110102 0 102500ND25602560 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 58 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/24276 EPA 365.1 EPA 365.1 365.1 Phosphorus, Total Associated Lab Samples:92264552019 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1542772 Associated Lab Samples:92264552019 Matrix:Water Analyzed Phosphorus ug/L ND 50.0 08/28/15 12:26 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1542773LABORATORY CONTROL SAMPLE: LCSSpike Phosphorus ug/L 26102500 104 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1542774MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92263940005 1542775 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Phosphorus ug/L M62500104090-1101110 7 1025002.0 mg/L 27900 29700 Parameter Units MS Result % Rec Limits Qual% RecConc. 1542776MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92264381001 1542777 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Phosphorus ug/L 2500 104 90-110107 2 1025000.30 mg/L 2910 2970 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 59 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/24253 SM 5220D SM 5220D 5220D COD Associated Lab Samples:92264552019 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1541567 Associated Lab Samples:92264552019 Matrix:Water Analyzed Chemical Oxygen Demand ug/L ND 25000 08/26/15 15:15 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1541568LABORATORY CONTROL SAMPLE: LCSSpike Chemical Oxygen Demand ug/L 766000750000 102 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1541569MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92263724001 1541570 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chemical Oxygen Demand ug/L 750000 91 90-11091 0 3750000ND684000684000 Parameter Units MS Result % Rec Limits Qual% RecConc. 1541571MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92264468003 1541572 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chemical Oxygen Demand ug/L M17500008990-11089 0 3750000426 mg/L 1100000 1100000 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 60 of 65 #=QL# QUALIFIERS Pace Project No.: Project: 92264552 WAYNE LINED MSWLF DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C ANALYTE QUALIFIERS Analyte was detected in the associated method blank.B Common Laboratory Contaminant.C9 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6 Analysis initiated outside of the 15 minute EPA recommended holding time.H6 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 61 of 65 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92264552 WAYNE LINED MSWLF Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92264552001 MPRP/19333 ICP/17380MW-1 EPA 3010 EPA 6010 92264552002 MPRP/19333 ICP/17380MW-2 EPA 3010 EPA 6010 92264552003 MPRP/19333 ICP/17380MW-3 EPA 3010 EPA 6010 92264552004 MPRP/19333 ICP/17380MW-4 EPA 3010 EPA 6010 92264552005 MPRP/19333 ICP/17380MW-5 EPA 3010 EPA 6010 92264552006 MPRP/19333 ICP/17380MW-6 EPA 3010 EPA 6010 92264552007 MPRP/19333 ICP/17380MW-7 EPA 3010 EPA 6010 92264552008 MPRP/19333 ICP/17380MW-8 EPA 3010 EPA 6010 92264552009 MPRP/19333 ICP/17380MW-9 EPA 3010 EPA 6010 92264552010 MPRP/19333 ICP/17380MW-10 EPA 3010 EPA 6010 92264552011 MPRP/19333 ICP/17380MW-11 EPA 3010 EPA 6010 92264552012 MPRP/19333 ICP/17380MW-12 EPA 3010 EPA 6010 92264552013 MPRP/19333 ICP/17380MW-13 EPA 3010 EPA 6010 92264552014 MPRP/19333 ICP/17380MW-14 EPA 3010 EPA 6010 92264552015 MPRP/19333 ICP/17380MW-15 EPA 3010 EPA 6010 92264552016 MPRP/19333 ICP/17380MW-16R EPA 3010 EPA 6010 92264552017 MPRP/19333 ICP/17380SW-4 EPA 3010 EPA 6010 92264552018 MPRP/19333 ICP/17380SW-5 EPA 3010 EPA 6010 92264552019 MPRP/19333 ICP/17380LE-1 EPA 3010 EPA 6010 92264552001 MSV/33196MW-1 EPA 8260 92264552002 MSV/33196MW-2 EPA 8260 92264552003 MSV/33196MW-3 EPA 8260 92264552004 MSV/33196MW-4 EPA 8260 92264552005 MSV/33196MW-5 EPA 8260 92264552006 MSV/33196MW-6 EPA 8260 92264552007 MSV/33196MW-7 EPA 8260 92264552008 MSV/33196MW-8 EPA 8260 92264552009 MSV/33196MW-9 EPA 8260 92264552010 MSV/33196MW-10 EPA 8260 92264552011 MSV/33196MW-11 EPA 8260 92264552012 MSV/33196MW-12 EPA 8260 92264552013 MSV/33196MW-13 EPA 8260 92264552014 MSV/33196MW-14 EPA 8260 92264552015 MSV/33196MW-15 EPA 8260 92264552016 MSV/33196MW-16R EPA 8260 92264552017 MSV/33196SW-4 EPA 8260 92264552018 MSV/33196SW-5 EPA 8260 92264552019 MSV/33199LE-1 EPA 8260 92264552019 WET/39629 WET/39631LE-1 SM 5210B SM 5210B 92264552019 WET/39640LE-1 EPA 9040 92264552019 WETA/24312LE-1 EPA 300.0 92264552019 WETA/24210LE-1 EPA 353.2 92264552019 WETA/24276LE-1 EPA 365.1 92264552019 WETA/24253LE-1 SM 5220D REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 62 of 65 Page 63 of 65 Page 64 of 65 Page 65 of 65 #=CL# September 04, 2015 LIMS USE: FR - JONATHAN PFOHL LIMS OBJECT ID: 92264878 92264878 Project: Pace Project No.: RE: Mr. Jonathan Pfohl Municipal Engineering Services PO Box 97 Garner, NC 27529 WAYNE MSWLF-SWS Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on August 25, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Godwin kevin.godwin@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 21 #=CP# CERTIFICATIONS Pace Project No.: Project: 92264878 WAYNE MSWLF-SWS Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84 West Virginia Certification #: 357Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 21 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92264878 WAYNE MSWLF-SWS Lab ID Sample ID Matrix Date Collected Date Received 92264878001 SW-2 Water 08/21/15 15:50 08/25/15 15:26 92264878002 SW-3 Water 08/21/15 14:00 08/25/15 15:26 92264878003 SW-1 Water 08/21/15 14:15 08/25/15 15:26 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 21 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92264878 WAYNE MSWLF-SWS Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92264878001 SW-2 EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264878002 SW-3 EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264878003 SW-1 EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 21 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264878 WAYNE MSWLF-SWS Sample:SW-2 Lab ID:92264878001 Collected:08/21/15 15:50 Received:08/25/15 15:26 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/31/15 02:10 7440-36-008/27/15 20:006.0 3.8 1 Arsenic ND ug/L 08/31/15 02:10 7440-38-208/27/15 20:0010.0 2.5 1 Barium 57.7J ug/L 08/31/15 02:10 7440-39-308/27/15 20:001002.5 1 Beryllium ND ug/L 08/31/15 02:10 7440-41-708/27/15 20:001.0 0.50 1 Cadmium ND ug/L 08/31/15 02:10 7440-43-908/27/15 20:001.0 0.50 1 Chromium ND ug/L 08/31/15 02:10 7440-47-308/27/15 20:0010.0 2.5 1 Cobalt ND ug/L 08/31/15 02:10 7440-48-408/27/15 20:0010.0 2.5 1 Copper ND ug/L 08/31/15 02:10 7440-50-808/27/15 20:0010.0 2.5 1 Lead ND ug/L 08/31/15 02:10 7439-92-108/27/15 20:0010.0 2.5 1 Nickel ND ug/L 08/31/15 02:10 7440-02-008/27/15 20:0050.0 2.5 1 Selenium ND ug/L 08/31/15 02:10 7782-49-208/27/15 20:0010.0 5.0 1 Silver ND ug/L 08/31/15 02:10 7440-22-408/27/15 20:0010.0 2.5 1 Thallium ND ug/L 08/31/15 02:10 7440-28-008/27/15 20:005.5 5.0 1 Vanadium 4.2J ug/L 08/31/15 02:10 7440-62-208/27/15 20:0025.0 2.5 1 Zinc 13.0 ug/L 08/31/15 02:10 7440-66-608/27/15 20:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 17:34 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 17:34 107-13-12001.9 1 Benzene ND ug/L 09/01/15 17:34 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 17:34 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 17:34 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 17:34 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 17:34 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 17:34 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 17:34 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 17:34 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 17:34 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 17:34 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 17:34 67-66-35.0 0.14 1 Chloromethane 0.33J ug/L 09/01/15 17:34 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 17:34 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 17:34 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 17:34 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 17:34 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 17:34 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 17:34 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 17:34 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 17:34 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 17:34 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 17:34 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 17:34 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 17:34 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 17:34 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 17:34 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 17:34 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 21 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264878 WAYNE MSWLF-SWS Sample:SW-2 Lab ID:92264878001 Collected:08/21/15 15:50 Received:08/25/15 15:26 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 17:34 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 17:34 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 17:34 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 17:34 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 09/01/15 17:34 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 17:34 108-10-11000.33 1 Styrene ND ug/L 09/01/15 17:34 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 17:34 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 17:34 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 17:34 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 17:34 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 17:34 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 17:34 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 17:34 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 17:34 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 17:34 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 17:34 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 17:34 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 17:34 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)104 %09/01/15 17:34 460-00-470-130 1 1,2-Dichloroethane-d4 (S)118 %09/01/15 17:34 17060-07-070-130 1 Toluene-d8 (S)102 %09/01/15 17:34 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 21 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264878 WAYNE MSWLF-SWS Sample:SW-3 Lab ID:92264878002 Collected:08/21/15 14:00 Received:08/25/15 15:26 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/31/15 02:13 7440-36-008/27/15 20:006.0 3.8 1 Arsenic ND ug/L 08/31/15 02:13 7440-38-208/27/15 20:0010.0 2.5 1 Barium 67.7J ug/L 08/31/15 02:13 7440-39-308/27/15 20:001002.5 1 Beryllium ND ug/L 08/31/15 02:13 7440-41-708/27/15 20:001.0 0.50 1 Cadmium ND ug/L 08/31/15 02:13 7440-43-908/27/15 20:001.0 0.50 1 Chromium ND ug/L 08/31/15 02:13 7440-47-308/27/15 20:0010.0 2.5 1 Cobalt ND ug/L 08/31/15 02:13 7440-48-408/27/15 20:0010.0 2.5 1 Copper ND ug/L 08/31/15 02:13 7440-50-808/27/15 20:0010.0 2.5 1 Lead ND ug/L 08/31/15 02:13 7439-92-108/27/15 20:0010.0 2.5 1 Nickel ND ug/L 08/31/15 02:13 7440-02-008/27/15 20:0050.0 2.5 1 Selenium ND ug/L 08/31/15 02:13 7782-49-208/27/15 20:0010.0 5.0 1 Silver ND ug/L 08/31/15 02:13 7440-22-408/27/15 20:0010.0 2.5 1 Thallium ND ug/L 08/31/15 02:13 7440-28-008/27/15 20:005.5 5.0 1 Vanadium ND ug/L 08/31/15 02:13 7440-62-208/27/15 20:0025.0 2.5 1 Zinc 6.1J ug/L 08/31/15 02:13 7440-66-608/27/15 20:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 17:51 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 17:51 107-13-12001.9 1 Benzene ND ug/L 09/01/15 17:51 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 17:51 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 17:51 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 17:51 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 17:51 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 17:51 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 17:51 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 17:51 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 17:51 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 17:51 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 17:51 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 17:51 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 17:51 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 17:51 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 17:51 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 17:51 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 17:51 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 17:51 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 17:51 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 17:51 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 17:51 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 17:51 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 17:51 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 17:51 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 17:51 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 17:51 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 17:51 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 21 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264878 WAYNE MSWLF-SWS Sample:SW-3 Lab ID:92264878002 Collected:08/21/15 14:00 Received:08/25/15 15:26 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 17:51 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 17:51 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 17:51 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 17:51 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 09/01/15 17:51 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 17:51 108-10-11000.33 1 Styrene ND ug/L 09/01/15 17:51 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 17:51 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 17:51 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 17:51 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 17:51 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 17:51 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 17:51 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 17:51 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 17:51 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 17:51 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 17:51 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 17:51 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 17:51 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %09/01/15 17:51 460-00-470-130 1 1,2-Dichloroethane-d4 (S)120 %09/01/15 17:51 17060-07-070-130 1 Toluene-d8 (S)102 %09/01/15 17:51 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 21 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264878 WAYNE MSWLF-SWS Sample:SW-1 Lab ID:92264878003 Collected:08/21/15 14:15 Received:08/25/15 15:26 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/31/15 02:16 7440-36-008/27/15 20:006.0 3.8 1 Arsenic ND ug/L 08/31/15 02:16 7440-38-208/27/15 20:0010.0 2.5 1 Barium 64.4J ug/L 08/31/15 02:16 7440-39-308/27/15 20:001002.5 1 Beryllium ND ug/L 08/31/15 02:16 7440-41-708/27/15 20:001.0 0.50 1 Cadmium 0.56J ug/L 08/31/15 02:16 7440-43-908/27/15 20:001.0 0.50 1 Chromium ND ug/L 08/31/15 02:16 7440-47-308/27/15 20:0010.0 2.5 1 Cobalt ND ug/L 08/31/15 02:16 7440-48-408/27/15 20:0010.0 2.5 1 Copper ND ug/L 08/31/15 02:16 7440-50-808/27/15 20:0010.0 2.5 1 Lead ND ug/L 08/31/15 02:16 7439-92-108/27/15 20:0010.0 2.5 1 Nickel ND ug/L 08/31/15 02:16 7440-02-008/27/15 20:0050.0 2.5 1 Selenium ND ug/L 08/31/15 02:16 7782-49-208/27/15 20:0010.0 5.0 1 Silver ND ug/L 08/31/15 02:16 7440-22-408/27/15 20:0010.0 2.5 1 Thallium ND ug/L 08/31/15 02:16 7440-28-008/27/15 20:005.5 5.0 1 Vanadium ND ug/L 08/31/15 02:16 7440-62-208/27/15 20:0025.0 2.5 1 Zinc ND ug/L 08/31/15 02:16 7440-66-608/27/15 20:0010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 18:08 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 18:08 107-13-12001.9 1 Benzene ND ug/L 09/01/15 18:08 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 18:08 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 18:08 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 18:08 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 18:08 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 18:08 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 18:08 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 18:08 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 18:08 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 18:08 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 18:08 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 18:08 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 18:08 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 18:08 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 18:08 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 18:08 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 18:08 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 18:08 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 18:08 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 18:08 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 18:08 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 18:08 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 18:08 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 18:08 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 18:08 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 18:08 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 18:08 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 21 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264878 WAYNE MSWLF-SWS Sample:SW-1 Lab ID:92264878003 Collected:08/21/15 14:15 Received:08/25/15 15:26 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 18:08 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 18:08 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 18:08 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 18:08 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 09/01/15 18:08 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 18:08 108-10-11000.33 1 Styrene ND ug/L 09/01/15 18:08 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 18:08 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 18:08 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 18:08 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 18:08 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 18:08 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 18:08 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 18:08 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 18:08 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 18:08 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 18:08 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 18:08 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 18:08 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)103 %09/01/15 18:08 460-00-470-130 1 1,2-Dichloroethane-d4 (S)120 %09/01/15 18:08 17060-07-070-130 1 Toluene-d8 (S)101 %09/01/15 18:08 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264878 WAYNE MSWLF-SWS Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/19358 EPA 3010 EPA 6010 6010 MET NC Groundwater Associated Lab Samples:92264878001, 92264878002, 92264878003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1543211 Associated Lab Samples:92264878001, 92264878002, 92264878003 Matrix:Water Analyzed Antimony ug/L ND 6.0 08/31/15 01:33 Arsenic ug/L ND 10.0 08/31/15 01:33 Barium ug/L ND 100 08/31/15 01:33 Beryllium ug/L ND 1.0 08/31/15 01:33 Cadmium ug/L ND 1.0 08/31/15 01:33 Chromium ug/L ND 10.0 08/31/15 01:33 Cobalt ug/L ND 10.0 08/31/15 01:33 Copper ug/L ND 10.0 08/31/15 01:33 Lead ug/L ND 10.0 08/31/15 01:33 Nickel ug/L ND 50.0 08/31/15 01:33 Selenium ug/L ND 10.0 08/31/15 01:33 Silver ug/L ND 10.0 08/31/15 01:33 Thallium ug/L ND 5.5 08/31/15 01:33 Vanadium ug/L ND 25.0 08/31/15 01:33 Zinc ug/L ND 10.0 08/31/15 01:33 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1543212LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 469500 94 80-120 Arsenic ug/L 458500 92 80-120 Barium ug/L 470500 94 80-120 Beryllium ug/L 469500 94 80-120 Cadmium ug/L 453500 91 80-120 Chromium ug/L 456500 91 80-120 Cobalt ug/L 464500 93 80-120 Copper ug/L 473500 95 80-120 Lead ug/L 458500 92 80-120 Nickel ug/L 450500 90 80-120 Selenium ug/L 451500 90 80-120 Silver ug/L 232250 93 80-120 Thallium ug/L 472500 94 80-120 Vanadium ug/L 467500 93 80-120 Zinc ug/L 453500 91 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264878 WAYNE MSWLF-SWS Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1543213MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92264558007 1543214 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony ug/L 500 104 75-12592 12 25500ND521462 Arsenic ug/L 500 102 75-12591 11 25500ND508454 Barium ug/L 500 105 75-12594 11 255008.6J 535 480 Beryllium ug/L 500 105 75-12594 11 25500ND525471 Cadmium ug/L 500 101 75-12590 11 25500ND503449 Chromium ug/L 500 102 75-12592 10 25500ND511462 Cobalt ug/L 500 103 75-12592 11 25500ND516461 Copper ug/L 500 105 75-12595 11 25500ND528474 Lead ug/L 500 101 75-12590 11 25500ND507454 Nickel ug/L 500 100 75-12589 11 25500ND499447 Selenium ug/L 500 100 75-12589 11 25500ND503448 Silver ug/L 250 103 75-12592 11 25250ND258230 Thallium ug/L 500 105 75-12594 11 25500ND525470 Vanadium ug/L 500 104 75-12594 10 25500ND523472 Zinc ug/L 500 101 75-12590 11 25500ND504453 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264878 WAYNE MSWLF-SWS Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MSV/33203 EPA 8260 EPA 8260 8260 MSV Low Level Landfill Associated Lab Samples:92264878001, 92264878002, 92264878003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1545863 Associated Lab Samples:92264878001, 92264878002, 92264878003 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 09/01/15 15:02 1,1,1-Trichloroethane ug/L ND 1.0 09/01/15 15:02 1,1,2,2-Tetrachloroethane ug/L ND 3.0 09/01/15 15:02 1,1,2-Trichloroethane ug/L ND 1.0 09/01/15 15:02 1,1-Dichloroethane ug/L ND 5.0 09/01/15 15:02 1,1-Dichloroethene ug/L ND 5.0 09/01/15 15:02 1,2,3-Trichloropropane ug/L ND 1.0 09/01/15 15:02 1,2-Dibromo-3-chloropropane ug/L ND 13.0 09/01/15 15:02 1,2-Dibromoethane (EDB)ug/L ND 1.0 09/01/15 15:02 1,2-Dichlorobenzene ug/L ND 5.0 09/01/15 15:02 1,2-Dichloroethane ug/L ND 1.0 09/01/15 15:02 1,2-Dichloropropane ug/L ND 1.0 09/01/15 15:02 1,3-Dichloropropane ug/L ND 1.0 09/01/15 15:02 1,4-Dichlorobenzene ug/L ND 1.0 09/01/15 15:02 2-Butanone (MEK)ug/L ND 100 09/01/15 15:02 2-Hexanone ug/L ND 50.0 09/01/15 15:02 4-Methyl-2-pentanone (MIBK)ug/L ND 100 09/01/15 15:02 Acetone ug/L ND 100 09/01/15 15:02 Acrylonitrile ug/L ND 200 09/01/15 15:02 Benzene ug/L ND 1.0 09/01/15 15:02 Bromochloromethane ug/L ND 3.0 09/01/15 15:02 Bromodichloromethane ug/L ND 1.0 09/01/15 15:02 Bromoform ug/L ND 3.0 09/01/15 15:02 Bromomethane ug/L ND 10.0 09/01/15 15:02 Carbon disulfide ug/L ND 100 09/01/15 15:02 Carbon tetrachloride ug/L ND 1.0 09/01/15 15:02 Chlorobenzene ug/L ND 3.0 09/01/15 15:02 Chloroethane ug/L ND 10.0 09/01/15 15:02 Chloroform ug/L ND 5.0 09/01/15 15:02 Chloromethane ug/L ND 1.0 09/01/15 15:02 cis-1,2-Dichloroethene ug/L ND 5.0 09/01/15 15:02 cis-1,3-Dichloropropene ug/L ND 1.0 09/01/15 15:02 Dibromochloromethane ug/L ND 3.0 09/01/15 15:02 Dibromomethane ug/L ND 10.0 09/01/15 15:02 Ethylbenzene ug/L ND 1.0 09/01/15 15:02 Iodomethane ug/L ND 10.0 09/01/15 15:02 Methylene Chloride ug/L ND 1.0 09/01/15 15:02 Styrene ug/L ND 1.0 09/01/15 15:02 Tetrachloroethene ug/L ND 1.0 09/01/15 15:02 Toluene ug/L ND 1.0 09/01/15 15:02 trans-1,2-Dichloroethene ug/L ND 5.0 09/01/15 15:02 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264878 WAYNE MSWLF-SWS Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1545863 Associated Lab Samples:92264878001, 92264878002, 92264878003 Matrix:Water Analyzed trans-1,3-Dichloropropene ug/L ND 1.0 09/01/15 15:02 trans-1,4-Dichloro-2-butene ug/L ND 100 09/01/15 15:02 Trichloroethene ug/L ND 1.0 09/01/15 15:02 Trichlorofluoromethane ug/L ND 1.0 09/01/15 15:02 Vinyl acetate ug/L ND 50.0 09/01/15 15:02 Vinyl chloride ug/L ND 1.0 09/01/15 15:02 Xylene (Total)ug/L ND 5.0 09/01/15 15:02 1,2-Dichloroethane-d4 (S)%117 70-130 09/01/15 15:02 4-Bromofluorobenzene (S)%105 70-130 09/01/15 15:02 Toluene-d8 (S)%102 70-130 09/01/15 15:02 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1545864LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 49.850 100 80-125 1,1,1-Trichloroethane ug/L 58.850 118 71-129 1,1,2,2-Tetrachloroethane ug/L 52.250 104 79-124 1,1,2-Trichloroethane ug/L 49.950 100 85-125 1,1-Dichloroethane ug/L 50.150 100 73-126 1,1-Dichloroethene ug/L 61.350 123 66-135 1,2,3-Trichloropropane ug/L 57.750 115 75-130 1,2-Dibromo-3-chloropropane ug/L 62.050 124 71-133 1,2-Dibromoethane (EDB)ug/L 53.250 106 83-124 1,2-Dichlorobenzene ug/L 50.650 101 80-133 1,2-Dichloroethane ug/L 51.050 102 67-128 1,2-Dichloropropane ug/L 46.050 92 75-132 1,3-Dichloropropane ug/L 48.650 97 76-131 1,4-Dichlorobenzene ug/L 50.950 102 78-130 2-Butanone (MEK)ug/L 125100 125 61-144 2-Hexanone ug/L 128100 128 68-143 4-Methyl-2-pentanone (MIBK)ug/L 121100 121 72-135 Acetone ug/L 129100 129 48-146 Acrylonitrile ug/L 323250 129 40-160 Benzene ug/L 47.650 95 80-125 Bromochloromethane ug/L 52.350 105 71-125 Bromodichloromethane ug/L 55.250 110 78-124 Bromoform ug/L 44.350 89 71-128 Bromomethane ug/L 39.850 80 40-160 Carbon disulfide ug/L 45.6J50 91 50-160 Carbon tetrachloride ug/L 53.450 107 69-131 Chlorobenzene ug/L 49.350 99 81-122 Chloroethane ug/L 46.450 93 39-148 Chloroform ug/L 55.050 110 73-127 Chloromethane ug/L 40.550 81 44-146 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264878 WAYNE MSWLF-SWS Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1545864LABORATORY CONTROL SAMPLE: LCSSpike cis-1,2-Dichloroethene ug/L 52.450 105 74-124 cis-1,3-Dichloropropene ug/L 50.950 102 72-132 Dibromochloromethane ug/L 47.550 95 78-125 Dibromomethane ug/L 50.650 101 82-120 Ethylbenzene ug/L 49.950 100 79-121 Iodomethane ug/L 79.0100 79 39-154 Methylene Chloride ug/L 50.550 101 64-133 Styrene ug/L 52.350 105 84-126 Tetrachloroethene ug/L 50.450 101 78-122 Toluene ug/L 48.150 96 80-121 trans-1,2-Dichloroethene ug/L 53.850 108 71-127 trans-1,3-Dichloropropene ug/L 54.250 108 69-141 trans-1,4-Dichloro-2-butene ug/L 68.9J50 138 40-160 Trichloroethene ug/L 48.250 96 78-122 Trichlorofluoromethane ug/L 55.550 111 53-137 Vinyl acetate ug/L 111100 111 40-160 Vinyl chloride ug/L 45.350 91 58-137 Xylene (Total)ug/L 154150 102 81-126 1,2-Dichloroethane-d4 (S)%114 70-130 4-Bromofluorobenzene (S)%106 70-130 Toluene-d8 (S)%99 70-130 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1545865MATRIX SPIKE SAMPLE: MSSpike Result 92264558007 1,1,1,2-Tetrachloroethane ug/L 21.520 108 70-130ND 1,1,1-Trichloroethane ug/L 23.220 116 70-130ND 1,1,2,2-Tetrachloroethane ug/L 20.220 101 70-130ND 1,1,2-Trichloroethane ug/L 21.020 105 70-130ND 1,1-Dichloroethane ug/L 22.020 110 70-130ND 1,1-Dichloroethene ug/L 25.220 126 70-166ND 1,2,3-Trichloropropane ug/L 20.120 100 70-130ND 1,2-Dibromo-3-chloropropane ug/L 19.920 99 70-130ND 1,2-Dibromoethane (EDB)ug/L 22.520 113 70-130ND 1,2-Dichlorobenzene ug/L 22.420 112 70-130ND 1,2-Dichloroethane ug/L 20.020 99 70-130ND 1,2-Dichloropropane ug/L 21.620 108 70-130ND 1,3-Dichloropropane ug/L 22.120 111 70-130ND 1,4-Dichlorobenzene ug/L 22.020 110 70-130ND 2-Butanone (MEK)ug/L 39.3J40 98 70-130ND 2-Hexanone ug/L 41.7J40 104 70-130ND 4-Methyl-2-pentanone (MIBK)ug/L 40.3J40 101 70-130ND Acetone ug/L 40.9J40 94 70-130ND Acrylonitrile ug/L 108J100 108 70-130ND Benzene ug/L 23.520 118 70-148ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264878 WAYNE MSWLF-SWS Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1545865MATRIX SPIKE SAMPLE: MSSpike Result 92264558007 Bromochloromethane ug/L 23.720 118 70-130ND Bromodichloromethane ug/L 21.720 108 70-130ND Bromoform ug/L 18.320 91 70-130ND Bromomethane ug/L 28.3 M12014170-130ND Carbon disulfide ug/L 24.1J20 121 70-130ND Carbon tetrachloride ug/L 23.320 116 70-130ND Chlorobenzene ug/L 22.720 113 70-146ND Chloroethane ug/L 22.420 112 70-130ND Chloroform ug/L 24.120 118 70-1300.55J Chloromethane ug/L 20.020 100 70-130ND cis-1,2-Dichloroethene ug/L 23.020 115 70-130ND cis-1,3-Dichloropropene ug/L 21.820 109 70-130ND Dibromochloromethane ug/L 19.820 99 70-130ND Dibromomethane ug/L 21.620 108 70-130ND Ethylbenzene ug/L 22.520 112 70-130ND Iodomethane ug/L 36.840 92 70-130ND Methylene Chloride ug/L 20.320 102 70-130ND Styrene ug/L 22.220 111 70-130ND Tetrachloroethene ug/L 22.820 114 70-130ND Toluene ug/L 22.420 112 70-155ND trans-1,2-Dichloroethene ug/L 24.320 122 70-130ND trans-1,3-Dichloropropene ug/L 20.520 102 70-130ND trans-1,4-Dichloro-2-butene ug/L 14.6J20 73 70-130ND Trichloroethene ug/L 21.320 106 69-151ND Trichlorofluoromethane ug/L 23.620 118 70-130ND Vinyl acetate ug/L 41.0J40 103 70-130ND Vinyl chloride ug/L 25.520 127 70-130ND 1,2-Dichloroethane-d4 (S)%98 70-130 4-Bromofluorobenzene (S)%101 70-130 Toluene-d8 (S)%99 70-130 Parameter Units Dup Result Max RPD QualifiersRPDResult 92264558008 1545866SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/L ND 30ND 1,1,1-Trichloroethane ug/L ND 30ND 1,1,2,2-Tetrachloroethane ug/L ND 30ND 1,1,2-Trichloroethane ug/L ND 30ND 1,1-Dichloroethane ug/L ND 30ND 1,1-Dichloroethene ug/L ND 30ND 1,2,3-Trichloropropane ug/L ND 30ND 1,2-Dibromo-3-chloropropane ug/L ND 30ND 1,2-Dibromoethane (EDB)ug/L ND 30ND 1,2-Dichlorobenzene ug/L 0.36J 300.32J 1,2-Dichloroethane ug/L ND 30ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264878 WAYNE MSWLF-SWS Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 92264558008 1545866SAMPLE DUPLICATE: 1,2-Dichloropropane ug/L ND 30ND 1,3-Dichloropropane ug/L ND 30ND 1,4-Dichlorobenzene ug/L 2.6 15 302.3 2-Butanone (MEK)ug/L ND 30ND 2-Hexanone ug/L ND 30ND 4-Methyl-2-pentanone (MIBK)ug/L ND 30ND Acetone ug/L ND 30ND Acrylonitrile ug/L ND 30ND Benzene ug/L 1.2 300.99J Bromochloromethane ug/L ND 30ND Bromodichloromethane ug/L ND 30ND Bromoform ug/L ND 30ND Bromomethane ug/L ND 30ND Carbon disulfide ug/L ND 30ND Carbon tetrachloride ug/L ND 30ND Chlorobenzene ug/L 13.6 9 3012.4 Chloroethane ug/L ND 30ND Chloroform ug/L ND 30ND Chloromethane ug/L ND 30ND cis-1,2-Dichloroethene ug/L ND 30ND cis-1,3-Dichloropropene ug/L ND 30ND Dibromochloromethane ug/L ND 30ND Dibromomethane ug/L ND 30ND Ethylbenzene ug/L ND 30ND Iodomethane ug/L ND 30ND Methylene Chloride ug/L ND 30ND Styrene ug/L ND 30ND Tetrachloroethene ug/L ND 30ND Toluene ug/L ND 30ND trans-1,2-Dichloroethene ug/L ND 30ND trans-1,3-Dichloropropene ug/L ND 30ND trans-1,4-Dichloro-2-butene ug/L ND 30ND Trichloroethene ug/L ND 30ND Trichlorofluoromethane ug/L ND 30ND Vinyl acetate ug/L ND 30ND Vinyl chloride ug/L ND 30ND Xylene (Total)ug/L ND 30ND 1,2-Dichloroethane-d4 (S)%99 17117 4-Bromofluorobenzene (S)%99 4103 Toluene-d8 (S)%101 2103 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 21 #=QL# QUALIFIERS Pace Project No.: Project: 92264878 WAYNE MSWLF-SWS DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C ANALYTE QUALIFIERS Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 21 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92264878 WAYNE MSWLF-SWS Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92264878001 MPRP/19358 ICP/17401SW-2 EPA 3010 EPA 6010 92264878002 MPRP/19358 ICP/17401SW-3 EPA 3010 EPA 6010 92264878003 MPRP/19358 ICP/17401SW-1 EPA 3010 EPA 6010 92264878001 MSV/33203SW-2 EPA 8260 92264878002 MSV/33203SW-3 EPA 8260 92264878003 MSV/33203SW-1 EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 21 Page 20 of 21 Page 21 of 21 #=CL# September 04, 2015 LIMS USE: FR - JONATHAN PFOHL LIMS OBJECT ID: 92264881 92264881 Project: Pace Project No.: RE: Mr. Jonathan Pfohl Municipal Engineering Services PO Box 97 Garner, NC 27529 WAYNE MSWLF BLANKS Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on August 25, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Godwin kevin.godwin@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 21 #=CP# CERTIFICATIONS Pace Project No.: Project: 92264881 WAYNE MSWLF BLANKS Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84 West Virginia Certification #: 357Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 21 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92264881 WAYNE MSWLF BLANKS Lab ID Sample ID Matrix Date Collected Date Received 92264881001 EB Water 08/21/15 15:00 08/25/15 15:26 92264881002 FB Water 08/21/15 15:10 08/25/15 15:26 92264881003 TB Water 08/21/15 00:00 08/25/15 15:26 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 21 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92264881 WAYNE MSWLF BLANKS Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92264881001 EB EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264881002 FB EPA 6010 15 PASI-AJDA EPA 8260 51 PASI-CNB 92264881003 TB EPA 8260 51 PASI-CNB REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 21 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264881 WAYNE MSWLF BLANKS Sample:EB Lab ID:92264881001 Collected:08/21/15 15:00 Received:08/25/15 15:26 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/31/15 00:22 7440-36-008/26/15 18:306.0 3.8 1 Arsenic ND ug/L 08/31/15 00:22 7440-38-208/26/15 18:3010.0 2.5 1 Barium 7.4J ug/L 08/31/15 00:22 7440-39-308/26/15 18:301002.5 1 Beryllium ND ug/L 08/31/15 00:22 7440-41-708/26/15 18:301.0 0.50 1 Cadmium ND ug/L 08/31/15 00:22 7440-43-908/26/15 18:301.0 0.50 1 Chromium ND ug/L 08/31/15 00:22 7440-47-308/26/15 18:3010.0 2.5 1 Cobalt ND ug/L 08/31/15 00:22 7440-48-408/26/15 18:3010.0 2.5 1 Copper ND ug/L 08/31/15 00:22 7440-50-808/26/15 18:3010.0 2.5 1 Lead ND ug/L 08/31/15 00:22 7439-92-108/26/15 18:3010.0 2.5 1 Nickel ND ug/L 08/31/15 00:22 7440-02-008/26/15 18:3050.0 2.5 1 Selenium ND ug/L 08/31/15 00:22 7782-49-208/26/15 18:3010.0 5.0 1 Silver ND ug/L 08/31/15 00:22 7440-22-408/26/15 18:3010.0 2.5 1 Thallium ND ug/L 08/31/15 00:22 7440-28-008/26/15 18:305.5 5.0 1 Vanadium ND ug/L 08/31/15 00:22 7440-62-208/26/15 18:3025.0 2.5 1 Zinc ND ug/L 08/31/15 00:22 7440-66-608/26/15 18:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 18:42 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 18:42 107-13-12001.9 1 Benzene ND ug/L 09/01/15 18:42 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 18:42 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 18:42 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 18:42 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 18:42 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 18:42 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 18:42 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 18:42 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 18:42 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 18:42 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 18:42 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 18:42 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 18:42 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 18:42 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 18:42 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 18:42 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 18:42 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 18:42 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 18:42 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 18:42 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 18:42 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 18:42 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 18:42 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 18:42 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 18:42 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 18:42 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 18:42 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 21 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264881 WAYNE MSWLF BLANKS Sample:EB Lab ID:92264881001 Collected:08/21/15 15:00 Received:08/25/15 15:26 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 18:42 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 18:42 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 18:42 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 18:42 74-88-410.0 0.32 1 Methylene Chloride 1.1 ug/L 09/01/15 18:42 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 18:42 108-10-11000.33 1 Styrene ND ug/L 09/01/15 18:42 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 18:42 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 18:42 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 18:42 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 18:42 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 18:42 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 18:42 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 18:42 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 18:42 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 18:42 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 18:42 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 18:42 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 18:42 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)104 %09/01/15 18:42 460-00-470-130 1 1,2-Dichloroethane-d4 (S)119 %09/01/15 18:42 17060-07-070-130 1 Toluene-d8 (S)103 %09/01/15 18:42 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 21 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264881 WAYNE MSWLF BLANKS Sample:FB Lab ID:92264881002 Collected:08/21/15 15:10 Received:08/25/15 15:26 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater Antimony ND ug/L 08/31/15 00:25 7440-36-008/26/15 18:306.0 3.8 1 Arsenic ND ug/L 08/31/15 00:25 7440-38-208/26/15 18:3010.0 2.5 1 Barium 7.8J ug/L 08/31/15 00:25 7440-39-308/26/15 18:301002.5 1 Beryllium ND ug/L 08/31/15 00:25 7440-41-708/26/15 18:301.0 0.50 1 Cadmium ND ug/L 08/31/15 00:25 7440-43-908/26/15 18:301.0 0.50 1 Chromium ND ug/L 08/31/15 00:25 7440-47-308/26/15 18:3010.0 2.5 1 Cobalt ND ug/L 08/31/15 00:25 7440-48-408/26/15 18:3010.0 2.5 1 Copper ND ug/L 08/31/15 00:25 7440-50-808/26/15 18:3010.0 2.5 1 Lead ND ug/L 08/31/15 00:25 7439-92-108/26/15 18:3010.0 2.5 1 Nickel ND ug/L 08/31/15 00:25 7440-02-008/26/15 18:3050.0 2.5 1 Selenium ND ug/L 08/31/15 00:25 7782-49-208/26/15 18:3010.0 5.0 1 Silver ND ug/L 08/31/15 00:25 7440-22-408/26/15 18:3010.0 2.5 1 Thallium ND ug/L 08/31/15 00:25 7440-28-008/26/15 18:305.5 5.0 1 Vanadium ND ug/L 08/31/15 00:25 7440-62-208/26/15 18:3025.0 2.5 1 Zinc ND ug/L 08/31/15 00:25 7440-66-608/26/15 18:3010.0 5.0 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 18:59 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 18:59 107-13-12001.9 1 Benzene ND ug/L 09/01/15 18:59 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 18:59 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 18:59 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 18:59 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 18:59 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 18:59 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 18:59 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 18:59 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 18:59 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 18:59 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 18:59 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 18:59 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 18:59 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 18:59 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 18:59 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 18:59 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 18:59 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 18:59 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 18:59 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 18:59 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 18:59 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 18:59 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 18:59 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 18:59 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 18:59 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 18:59 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 18:59 10061-01-51.0 0.13 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 21 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264881 WAYNE MSWLF BLANKS Sample:FB Lab ID:92264881002 Collected:08/21/15 15:10 Received:08/25/15 15:26 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill trans-1,3-Dichloropropene ND ug/L 09/01/15 18:59 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 18:59 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 18:59 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 18:59 74-88-410.0 0.32 1 Methylene Chloride 1.3 ug/L 09/01/15 18:59 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 18:59 108-10-11000.33 1 Styrene ND ug/L 09/01/15 18:59 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 18:59 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 18:59 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 18:59 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 18:59 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 18:59 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 18:59 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 18:59 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 18:59 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 18:59 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 18:59 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 09/01/15 18:59 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 18:59 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)101 %09/01/15 18:59 460-00-470-130 1 1,2-Dichloroethane-d4 (S)120 %09/01/15 18:59 17060-07-070-130 1 Toluene-d8 (S)102 %09/01/15 18:59 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 21 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264881 WAYNE MSWLF BLANKS Sample:TB Lab ID:92264881003 Collected:08/21/15 00:00 Received:08/25/15 15:26 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 09/01/15 19:16 67-64-110010.0 1 Acrylonitrile ND ug/L 09/01/15 19:16 107-13-12001.9 1 Benzene ND ug/L 09/01/15 19:16 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 09/01/15 19:16 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 09/01/15 19:16 75-27-41.0 0.18 1 Bromoform ND ug/L 09/01/15 19:16 75-25-23.0 0.26 1 Bromomethane ND ug/L 09/01/15 19:16 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 09/01/15 19:16 78-93-31000.96 1 Carbon disulfide ND ug/L 09/01/15 19:16 75-15-01001.2 1 Carbon tetrachloride ND ug/L 09/01/15 19:16 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 09/01/15 19:16 108-90-73.0 0.23 1 Chloroethane ND ug/L 09/01/15 19:16 75-00-310.0 0.54 1 Chloroform ND ug/L 09/01/15 19:16 67-66-35.0 0.14 1 Chloromethane ND ug/L 09/01/15 19:16 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 09/01/15 19:16 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 09/01/15 19:16 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 09/01/15 19:16 106-93-41.0 0.27 1 Dibromomethane ND ug/L 09/01/15 19:16 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 09/01/15 19:16 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 09/01/15 19:16 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 09/01/15 19:16 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 09/01/15 19:16 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 09/01/15 19:16 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 09/01/15 19:16 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 09/01/15 19:16 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 09/01/15 19:16 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 09/01/15 19:16 78-87-51.0 0.27 1 1,3-Dichloropropane ND ug/L 09/01/15 19:16 142-28-91.0 0.28 1 cis-1,3-Dichloropropene ND ug/L 09/01/15 19:16 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 09/01/15 19:16 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 09/01/15 19:16 100-41-41.0 0.30 1 2-Hexanone ND ug/L 09/01/15 19:16 591-78-650.0 0.46 1 Iodomethane ND ug/L 09/01/15 19:16 74-88-410.0 0.32 1 Methylene Chloride 2.4 ug/L 09/01/15 19:16 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 09/01/15 19:16 108-10-11000.33 1 Styrene ND ug/L 09/01/15 19:16 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 09/01/15 19:16 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 09/01/15 19:16 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 09/01/15 19:16 127-18-41.0 0.46 1 Toluene ND ug/L 09/01/15 19:16 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 09/01/15 19:16 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 09/01/15 19:16 79-00-51.0 0.29 1 Trichloroethene ND ug/L 09/01/15 19:16 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 09/01/15 19:16 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 09/01/15 19:16 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 09/01/15 19:16 108-05-450.0 0.35 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 21 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92264881 WAYNE MSWLF BLANKS Sample:TB Lab ID:92264881003 Collected:08/21/15 00:00 Received:08/25/15 15:26 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Vinyl chloride ND ug/L 09/01/15 19:16 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 09/01/15 19:16 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)104 %09/01/15 19:16 460-00-470-130 1 1,2-Dichloroethane-d4 (S)119 %09/01/15 19:16 17060-07-070-130 1 Toluene-d8 (S)101 %09/01/15 19:16 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264881 WAYNE MSWLF BLANKS Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/19347 EPA 3010 EPA 6010 6010 MET NC Groundwater Associated Lab Samples:92264881001, 92264881002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1542455 Associated Lab Samples:92264881001, 92264881002 Matrix:Water Analyzed Antimony ug/L ND 6.0 08/31/15 00:04 Arsenic ug/L ND 10.0 08/31/15 00:04 Barium ug/L ND 100 08/31/15 00:04 Beryllium ug/L ND 1.0 08/31/15 00:04 Cadmium ug/L ND 1.0 08/31/15 00:04 Chromium ug/L ND 10.0 09/02/15 20:47 Cobalt ug/L ND 10.0 08/31/15 00:04 Copper ug/L ND 10.0 08/31/15 00:04 Lead ug/L ND 10.0 08/31/15 00:04 Nickel ug/L ND 50.0 09/02/15 20:47 Selenium ug/L ND 10.0 08/31/15 00:04 Silver ug/L ND 10.0 08/31/15 00:04 Thallium ug/L ND 5.5 08/31/15 00:04 Vanadium ug/L ND 25.0 08/31/15 00:04 Zinc ug/L ND 10.0 08/31/15 00:04 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1542456LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 387417 93 80-120 Arsenic ug/L 374417 90 80-120 Barium ug/L 388417 93 80-120 Beryllium ug/L 387417 93 80-120 Cadmium ug/L 373417 89 80-120 Chromium ug/L 449417 108 80-120 Cobalt ug/L 381417 92 80-120 Copper ug/L 391417 94 80-120 Lead ug/L 377417 91 80-120 Nickel ug/L 467417 112 80-120 Selenium ug/L 371417 89 80-120 Silver ug/L 190208 91 80-120 Thallium ug/L 387417 93 80-120 Vanadium ug/L 383417 92 80-120 Zinc ug/L 374417 90 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264881 WAYNE MSWLF BLANKS Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1542457MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92264856001 1542458 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony ug/L 417 106 75-12593 13 254178.8 451 397 Arsenic ug/L 417 104 75-12591 13 25417ND431379 Barium ug/L 417 105 75-12590 7 25417454890831 Beryllium ug/L 417 103 75-12591 13 25417ND430378 Cadmium ug/L 417 101 75-12588 13 25417ND421368 Chromium ug/L 417 97 75-12585 13 25417ND405356 Cobalt ug/L 417 97 75-12585 13 25417ND404356 Copper ug/L 417 107 75-12593 13 254174.6J 448 392 Lead ug/L 417 94 75-12583 12 25417ND394348 Nickel ug/L 417 93 75-12581 11 2541786.6 473 424 Selenium ug/L 417 100 75-12589 12 25417ND418370 Silver ug/L 208 103 75-12590 13 25208ND214188 Thallium ug/L 417 97 75-12585 13 25417ND402353 Vanadium ug/L 417 102 75-12589 13 254176.5J 431 378 Zinc ug/L 417 94 75-12583 13 25417ND394346 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264881 WAYNE MSWLF BLANKS Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MSV/33203 EPA 8260 EPA 8260 8260 MSV Low Level Landfill Associated Lab Samples:92264881001, 92264881002, 92264881003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1545863 Associated Lab Samples:92264881001, 92264881002, 92264881003 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 09/01/15 15:02 1,1,1-Trichloroethane ug/L ND 1.0 09/01/15 15:02 1,1,2,2-Tetrachloroethane ug/L ND 3.0 09/01/15 15:02 1,1,2-Trichloroethane ug/L ND 1.0 09/01/15 15:02 1,1-Dichloroethane ug/L ND 5.0 09/01/15 15:02 1,1-Dichloroethene ug/L ND 5.0 09/01/15 15:02 1,2,3-Trichloropropane ug/L ND 1.0 09/01/15 15:02 1,2-Dibromo-3-chloropropane ug/L ND 13.0 09/01/15 15:02 1,2-Dibromoethane (EDB)ug/L ND 1.0 09/01/15 15:02 1,2-Dichlorobenzene ug/L ND 5.0 09/01/15 15:02 1,2-Dichloroethane ug/L ND 1.0 09/01/15 15:02 1,2-Dichloropropane ug/L ND 1.0 09/01/15 15:02 1,3-Dichloropropane ug/L ND 1.0 09/01/15 15:02 1,4-Dichlorobenzene ug/L ND 1.0 09/01/15 15:02 2-Butanone (MEK)ug/L ND 100 09/01/15 15:02 2-Hexanone ug/L ND 50.0 09/01/15 15:02 4-Methyl-2-pentanone (MIBK)ug/L ND 100 09/01/15 15:02 Acetone ug/L ND 100 09/01/15 15:02 Acrylonitrile ug/L ND 200 09/01/15 15:02 Benzene ug/L ND 1.0 09/01/15 15:02 Bromochloromethane ug/L ND 3.0 09/01/15 15:02 Bromodichloromethane ug/L ND 1.0 09/01/15 15:02 Bromoform ug/L ND 3.0 09/01/15 15:02 Bromomethane ug/L ND 10.0 09/01/15 15:02 Carbon disulfide ug/L ND 100 09/01/15 15:02 Carbon tetrachloride ug/L ND 1.0 09/01/15 15:02 Chlorobenzene ug/L ND 3.0 09/01/15 15:02 Chloroethane ug/L ND 10.0 09/01/15 15:02 Chloroform ug/L ND 5.0 09/01/15 15:02 Chloromethane ug/L ND 1.0 09/01/15 15:02 cis-1,2-Dichloroethene ug/L ND 5.0 09/01/15 15:02 cis-1,3-Dichloropropene ug/L ND 1.0 09/01/15 15:02 Dibromochloromethane ug/L ND 3.0 09/01/15 15:02 Dibromomethane ug/L ND 10.0 09/01/15 15:02 Ethylbenzene ug/L ND 1.0 09/01/15 15:02 Iodomethane ug/L ND 10.0 09/01/15 15:02 Methylene Chloride ug/L ND 1.0 09/01/15 15:02 Styrene ug/L ND 1.0 09/01/15 15:02 Tetrachloroethene ug/L ND 1.0 09/01/15 15:02 Toluene ug/L ND 1.0 09/01/15 15:02 trans-1,2-Dichloroethene ug/L ND 5.0 09/01/15 15:02 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264881 WAYNE MSWLF BLANKS Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1545863 Associated Lab Samples:92264881001, 92264881002, 92264881003 Matrix:Water Analyzed trans-1,3-Dichloropropene ug/L ND 1.0 09/01/15 15:02 trans-1,4-Dichloro-2-butene ug/L ND 100 09/01/15 15:02 Trichloroethene ug/L ND 1.0 09/01/15 15:02 Trichlorofluoromethane ug/L ND 1.0 09/01/15 15:02 Vinyl acetate ug/L ND 50.0 09/01/15 15:02 Vinyl chloride ug/L ND 1.0 09/01/15 15:02 Xylene (Total)ug/L ND 5.0 09/01/15 15:02 1,2-Dichloroethane-d4 (S)%117 70-130 09/01/15 15:02 4-Bromofluorobenzene (S)%105 70-130 09/01/15 15:02 Toluene-d8 (S)%102 70-130 09/01/15 15:02 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1545864LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 49.850 100 80-125 1,1,1-Trichloroethane ug/L 58.850 118 71-129 1,1,2,2-Tetrachloroethane ug/L 52.250 104 79-124 1,1,2-Trichloroethane ug/L 49.950 100 85-125 1,1-Dichloroethane ug/L 50.150 100 73-126 1,1-Dichloroethene ug/L 61.350 123 66-135 1,2,3-Trichloropropane ug/L 57.750 115 75-130 1,2-Dibromo-3-chloropropane ug/L 62.050 124 71-133 1,2-Dibromoethane (EDB)ug/L 53.250 106 83-124 1,2-Dichlorobenzene ug/L 50.650 101 80-133 1,2-Dichloroethane ug/L 51.050 102 67-128 1,2-Dichloropropane ug/L 46.050 92 75-132 1,3-Dichloropropane ug/L 48.650 97 76-131 1,4-Dichlorobenzene ug/L 50.950 102 78-130 2-Butanone (MEK)ug/L 125100 125 61-144 2-Hexanone ug/L 128100 128 68-143 4-Methyl-2-pentanone (MIBK)ug/L 121100 121 72-135 Acetone ug/L 129100 129 48-146 Acrylonitrile ug/L 323250 129 40-160 Benzene ug/L 47.650 95 80-125 Bromochloromethane ug/L 52.350 105 71-125 Bromodichloromethane ug/L 55.250 110 78-124 Bromoform ug/L 44.350 89 71-128 Bromomethane ug/L 39.850 80 40-160 Carbon disulfide ug/L 45.6J50 91 50-160 Carbon tetrachloride ug/L 53.450 107 69-131 Chlorobenzene ug/L 49.350 99 81-122 Chloroethane ug/L 46.450 93 39-148 Chloroform ug/L 55.050 110 73-127 Chloromethane ug/L 40.550 81 44-146 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264881 WAYNE MSWLF BLANKS Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1545864LABORATORY CONTROL SAMPLE: LCSSpike cis-1,2-Dichloroethene ug/L 52.450 105 74-124 cis-1,3-Dichloropropene ug/L 50.950 102 72-132 Dibromochloromethane ug/L 47.550 95 78-125 Dibromomethane ug/L 50.650 101 82-120 Ethylbenzene ug/L 49.950 100 79-121 Iodomethane ug/L 79.0100 79 39-154 Methylene Chloride ug/L 50.550 101 64-133 Styrene ug/L 52.350 105 84-126 Tetrachloroethene ug/L 50.450 101 78-122 Toluene ug/L 48.150 96 80-121 trans-1,2-Dichloroethene ug/L 53.850 108 71-127 trans-1,3-Dichloropropene ug/L 54.250 108 69-141 trans-1,4-Dichloro-2-butene ug/L 68.9J50 138 40-160 Trichloroethene ug/L 48.250 96 78-122 Trichlorofluoromethane ug/L 55.550 111 53-137 Vinyl acetate ug/L 111100 111 40-160 Vinyl chloride ug/L 45.350 91 58-137 Xylene (Total)ug/L 154150 102 81-126 1,2-Dichloroethane-d4 (S)%114 70-130 4-Bromofluorobenzene (S)%106 70-130 Toluene-d8 (S)%99 70-130 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1545865MATRIX SPIKE SAMPLE: MSSpike Result 92264558007 1,1,1,2-Tetrachloroethane ug/L 21.520 108 70-130ND 1,1,1-Trichloroethane ug/L 23.220 116 70-130ND 1,1,2,2-Tetrachloroethane ug/L 20.220 101 70-130ND 1,1,2-Trichloroethane ug/L 21.020 105 70-130ND 1,1-Dichloroethane ug/L 22.020 110 70-130ND 1,1-Dichloroethene ug/L 25.220 126 70-166ND 1,2,3-Trichloropropane ug/L 20.120 100 70-130ND 1,2-Dibromo-3-chloropropane ug/L 19.920 99 70-130ND 1,2-Dibromoethane (EDB)ug/L 22.520 113 70-130ND 1,2-Dichlorobenzene ug/L 22.420 112 70-130ND 1,2-Dichloroethane ug/L 20.020 99 70-130ND 1,2-Dichloropropane ug/L 21.620 108 70-130ND 1,3-Dichloropropane ug/L 22.120 111 70-130ND 1,4-Dichlorobenzene ug/L 22.020 110 70-130ND 2-Butanone (MEK)ug/L 39.3J40 98 70-130ND 2-Hexanone ug/L 41.7J40 104 70-130ND 4-Methyl-2-pentanone (MIBK)ug/L 40.3J40 101 70-130ND Acetone ug/L 40.9J40 94 70-130ND Acrylonitrile ug/L 108J100 108 70-130ND Benzene ug/L 23.520 118 70-148ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264881 WAYNE MSWLF BLANKS Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1545865MATRIX SPIKE SAMPLE: MSSpike Result 92264558007 Bromochloromethane ug/L 23.720 118 70-130ND Bromodichloromethane ug/L 21.720 108 70-130ND Bromoform ug/L 18.320 91 70-130ND Bromomethane ug/L 28.3 M12014170-130ND Carbon disulfide ug/L 24.1J20 121 70-130ND Carbon tetrachloride ug/L 23.320 116 70-130ND Chlorobenzene ug/L 22.720 113 70-146ND Chloroethane ug/L 22.420 112 70-130ND Chloroform ug/L 24.120 118 70-1300.55J Chloromethane ug/L 20.020 100 70-130ND cis-1,2-Dichloroethene ug/L 23.020 115 70-130ND cis-1,3-Dichloropropene ug/L 21.820 109 70-130ND Dibromochloromethane ug/L 19.820 99 70-130ND Dibromomethane ug/L 21.620 108 70-130ND Ethylbenzene ug/L 22.520 112 70-130ND Iodomethane ug/L 36.840 92 70-130ND Methylene Chloride ug/L 20.320 102 70-130ND Styrene ug/L 22.220 111 70-130ND Tetrachloroethene ug/L 22.820 114 70-130ND Toluene ug/L 22.420 112 70-155ND trans-1,2-Dichloroethene ug/L 24.320 122 70-130ND trans-1,3-Dichloropropene ug/L 20.520 102 70-130ND trans-1,4-Dichloro-2-butene ug/L 14.6J20 73 70-130ND Trichloroethene ug/L 21.320 106 69-151ND Trichlorofluoromethane ug/L 23.620 118 70-130ND Vinyl acetate ug/L 41.0J40 103 70-130ND Vinyl chloride ug/L 25.520 127 70-130ND 1,2-Dichloroethane-d4 (S)%98 70-130 4-Bromofluorobenzene (S)%101 70-130 Toluene-d8 (S)%99 70-130 Parameter Units Dup Result Max RPD QualifiersRPDResult 92264558008 1545866SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/L ND 30ND 1,1,1-Trichloroethane ug/L ND 30ND 1,1,2,2-Tetrachloroethane ug/L ND 30ND 1,1,2-Trichloroethane ug/L ND 30ND 1,1-Dichloroethane ug/L ND 30ND 1,1-Dichloroethene ug/L ND 30ND 1,2,3-Trichloropropane ug/L ND 30ND 1,2-Dibromo-3-chloropropane ug/L ND 30ND 1,2-Dibromoethane (EDB)ug/L ND 30ND 1,2-Dichlorobenzene ug/L 0.36J 300.32J 1,2-Dichloroethane ug/L ND 30ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92264881 WAYNE MSWLF BLANKS Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 92264558008 1545866SAMPLE DUPLICATE: 1,2-Dichloropropane ug/L ND 30ND 1,3-Dichloropropane ug/L ND 30ND 1,4-Dichlorobenzene ug/L 2.6 15 302.3 2-Butanone (MEK)ug/L ND 30ND 2-Hexanone ug/L ND 30ND 4-Methyl-2-pentanone (MIBK)ug/L ND 30ND Acetone ug/L ND 30ND Acrylonitrile ug/L ND 30ND Benzene ug/L 1.2 300.99J Bromochloromethane ug/L ND 30ND Bromodichloromethane ug/L ND 30ND Bromoform ug/L ND 30ND Bromomethane ug/L ND 30ND Carbon disulfide ug/L ND 30ND Carbon tetrachloride ug/L ND 30ND Chlorobenzene ug/L 13.6 9 3012.4 Chloroethane ug/L ND 30ND Chloroform ug/L ND 30ND Chloromethane ug/L ND 30ND cis-1,2-Dichloroethene ug/L ND 30ND cis-1,3-Dichloropropene ug/L ND 30ND Dibromochloromethane ug/L ND 30ND Dibromomethane ug/L ND 30ND Ethylbenzene ug/L ND 30ND Iodomethane ug/L ND 30ND Methylene Chloride ug/L ND 30ND Styrene ug/L ND 30ND Tetrachloroethene ug/L ND 30ND Toluene ug/L ND 30ND trans-1,2-Dichloroethene ug/L ND 30ND trans-1,3-Dichloropropene ug/L ND 30ND trans-1,4-Dichloro-2-butene ug/L ND 30ND Trichloroethene ug/L ND 30ND Trichlorofluoromethane ug/L ND 30ND Vinyl acetate ug/L ND 30ND Vinyl chloride ug/L ND 30ND Xylene (Total)ug/L ND 30ND 1,2-Dichloroethane-d4 (S)%99 17117 4-Bromofluorobenzene (S)%99 4103 Toluene-d8 (S)%101 2103 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 21 #=QL# QUALIFIERS Pace Project No.: Project: 92264881 WAYNE MSWLF BLANKS DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C ANALYTE QUALIFIERS Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 21 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92264881 WAYNE MSWLF BLANKS Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92264881001 MPRP/19347 ICP/17392EBEPA 3010 EPA 6010 92264881002 MPRP/19347 ICP/17392FBEPA 3010 EPA 6010 92264881001 MSV/33203EBEPA 8260 92264881002 MSV/33203FBEPA 8260 92264881003 MSV/33203TBEPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/04/2015 03:37 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 21 Page 20 of 21 Page 21 of 21 Appendix B Field Sampling Parameter Data Sheet(s)