8505_DukeBelewsCreekFGD_Nov2015_2ndSemiAnnual_DIN26344_20160202

FGD Residue Landfill Permit No. 8505
Semiannual Groundwater Monitoring Report
November 2015 Sampling Event
Belews Creek Steam Station
February 2, 2016

Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
November 2015 Sampling EventCONTENTS

1
Contents
Page
Report Verification i
Contents 1
Section 1 – Background 2
Section 2 – Methods 4
2.1 Sampling and Analysis Methods 4
2.2 Statement of Work 4
Section 3 – Results 6
3.1 Site Groundwater Flow 6
3.2 Analytical Results 6

FIGURES
1. Site Location Map
2. Sample Locations
3. Generalized Groundwater Surface Contours – November 4, 2015
TABLES
1. Well Construction Information
2. Groundwater Flow Velocities – November 4, 2015
3. Field Data Parameters
4. Field and Analytical Results
5. Analytical Results that Equal or Exceed 15A NCAC 2L Groundwater Quality Standards
6. Leachate Field and Analytical Results
APPENDICES
A. Field Sampling Forms

B. Laboratory Report and Chain-of-Custody Forms

Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
November 2015 Sampling EventSECTION 1 – BACKGROUND

2
Section 1 – Background
The flue gas desulfurization (FGD) residue landfill is located at the Duke Energy Carolinas, LLC
(Duke Energy) Belews Creek Steam Station, in Stokes County, North Carolina. The FGD
residue landfill is permitted to receive FGD residue (gypsum) from Belews Creek Steam Station
operations. The landfill is permitted under the North Carolina Department of Environmental
Quality (NCDEQ) Solid Waste Permit No. 8505.
The FGD residue landfill is located south of the Belews Creek plant, on land between two arms
of the Belews Lake. The West Belews Creek arm of the lake is located west of the landfill site
and the East Belews Creek arm of the lake is located east of the site. Craig Road is located to
the west of the landfill. The FGD residue landfill and nearby surrounding area are depicted on
Figure 1.
The landfill consists of four cells contained in an area of approximately 24 acres. The adjacent
stormwater basin occupies an area of approximately 2.4 acres and is used to manage leachate
and stormwater collected from the landfill. The landfill has an engineered liner system consisting
of a leachate collection system, underlain by a high-density polyethylene (HDPE) geomembrane
liner, underlain by a geo-synthetic clay liner.
The subsurface conditions in the landfill area consist of residual soils, saprolite, partially
weathered rock, and bedrock, as described in the Water Quality Monitoring Plan.1
As is typical for groundwater systems located in the Piedmont region, groundwater at the landfill
site occurs within the residuum, saprolite, partially weathered rock, and shallow fractured
bedrock under unconfined aquifer conditions. The groundwater flow in the area of the landfill is
generally from areas of higher topography, located to the east of the landfill, to the west and to
the northwest of the landfill, towards Belews Lake.

1 Water Quality Monitoring Plan FGD Scrubber Residue Landfill Belews Creek Steam Station, December 07, 2007.
Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
November 2015 Sampling EventSECTION 1 – BACKGROUND

3
The monitoring system for the landfill consists of the following:
Monitoring Wells2:BC-20
BC-21 BC-22
BC-23A
BC-25 BC-26
BC-27
BC-28 BC-29
BC-30 BC-31 BC-323
Observation Well: BC-7
Surface Water: SW-1
Leachate Sample: Leachate

The monitoring system for the landfill is shown on Figure 2. A summary of monitoring well
construction information is presented in Table 1. Monitoring wells BC-23A and BC-28 are
considered to represent background groundwater quality, according to the Water Quality
Monitoring Plan. The groundwater monitoring locations are sampled on a semi-annual basis and
the results compared to groundwater quality standards found in 15A NCAC .02L .0202(g) (2L
Standards).
Observation well BC-7 is used for water level measurements only. Monitoring wells are used to
monitor groundwater quality and to measure groundwater levels.
SW-1 is a groundwater seep located to the east of well BC-28. When water is present, it
emanates from the ground just above the sampling location. SW-1 analytical results are
compared to 2L Standards. This surface water feature drains to Belews Lake.

2 BC-25 and BC-27 were recently (as of June 2015) converted to stick-up wells in an effort to reduce TDS
and obtain better samples. 3 Monitoring well BC-32 was installed in August 2013, as part of a groundwater assessment being
conducted at the landfill. The monitoring well is not included in the Water Quality Monitoring Plan, but the analytical results from the well are included in this landfill groundwater monitoring report.
Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
November 2015 Sampling EventSECTION 2 – METHODS

4
Section 2 – Methods
2.1 Sampling and Analysis Methods
Groundwater sampling and documentation of sampling activities were performed by Duke
Energy personnel (Duke Energy Carolinas Field Certification #5193) in accordance with the
North Carolina Solid Waste Management Guidelines. Copies of the field sampling forms are
included in Appendix A. The parameters and constituents sampled were selected by Duke
Energy and the NCDEQ Division of Solid Waste and were analyzed by the Duke Energy
Analytical Laboratory (North Carolina Laboratory Certification #248) and provided to HDR by
Duke Energy. The laboratory report and chain-of-custody forms are included in Appendix B.
The groundwater samples were analyzed using the following analytical methods:
 Barium, boron, chromium, copper, iron, manganese, nickel, silver, and zinc using U.S.
Environmental Protection Agency (EPA) Method 200.7
 Arsenic, cadmium, lead, and selenium by EPA Method 200.8
 Chloride, fluoride, nitrate as nitrogen, and sulfate using EPA Method 300.0
 Mercury using EPA Method 245.1
 Total Dissolved Solids using Standard Method (SM) 2540C
2.2 Statement of Work
HDR completed the following tasks:
 Received field sampling information provided by Duke Energy (performed by Duke
Energy personnel) for monitoring wells BC-20, BC-21, BC-22, BC-23A, BC-25, BC-26,
BC-27, BC-28, BC-29, BC-30, BC-31, BC-32, surface water sampling location SW-1,
and the leachate sampling location. The samples were collected on November 4, 2015
and HDR received the data on November 23, 2015.

 Reviewed the laboratory analytical results for the samples noted above. The Electronic
Data Deliverable (EDD), provided by Duke Energy, was adapted to conform to the
format requirements of the NCDEQ EDD template. HDR added an italicized J data
qualifier (J’) to indicate a detected concentration that equals or is greater than the
laboratory’s method reporting limit (MRL), but less than the Solid Waste Section Limit4
(SWSL), and retained the laboratory-supplied qualifier J to indicate values that equal or
are greater than the laboratory’s method detection limit (MDL) but are less than the
MRL. A copy of the original EDD is retained in HDR’s files.

4 The Solid Waste Section Limit (SWSL) is defined by NCDEQ as the lowest amount of analyte in a
sample that can be quantitatively determined with suitable precision and accuracy. The SWSL is the
concentration below which reported results must be qualified as estimated. NCDEQ Division of Waste
Management Memorandum dated February 23, 2007.
Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
November 2015 Sampling EventSECTION 2 – METHODS

5
 Developed a generalized groundwater surface contour map using map data and
groundwater elevation data supplied by Duke Energy.

 Prepared and submitted this Semiannual Groundwater Monitoring Report to Duke
Energy.
Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
November 2015 Sampling EventSECTION 3 – RESULTS

6
Section 3 – Results
3.1 Site Groundwater Flow
Generalized groundwater surface contours and groundwater flow direction arrows for the site
are shown on Figure 3. These contours were developed using groundwater elevations
measured at the wells on the date of sampling. Calculated groundwater flow velocities are
presented on Table 2.
Based on the groundwater elevations measured at the wells on the date of sampling,
groundwater flow in the area of the landfill is generally from areas of higher topography, located
to the east of the landfill, to the west and to the northwest of the landfill, towards Belews Lake.
3.2 Analytical Results
A summary of the field data is presented in Table 3.
The field and analytical results of groundwater and surface water sampling are summarized in
Table 4. The analysis results for these locations are compared to the 2L Standards.
Concentrations with values that attain or exceed the 2L Standards are noted on Table 4 by bold
font. A summary of the analytical results that attain or exceed the 2L Standards and a
preliminary analysis of the cause and significance of the exceedances are presented in Table 5.
The field and analytical results of leachate sampling are summarized in Table 6.
Concentrations with values that equal or are greater than the SWSLs are noted on Tables 4 and
6 by gray-shaded cells.
Selected samples were diluted as is normal laboratory practice to bring samples to the
calibrated range of the analysis. Specifics regarding the samples that were diluted, including the
dilution amount, are reported in the EDD and the laboratory report.
HDR previously prepared and submitted an assessment to NCDEQ for exceedances of 2L
Standards at this landfill (Groundwater Assessment Belews Creek Steam Station FGD Residue
Landfill, Permit No. 8505. October 5, 2012).
The report assessed the exceedances of the 2L Standards at wells BC-20, BC-21, BC-23A, BC-
26, BC-27, BC-29, and BC-31 and at surface water sampling location SW-1. The assessment
report concluded for the period of analytical results reviewed that:
 the source of iron exceedances reported in BC-20, BC-21, BC-23A, BC-26, BC-27, BC-
29, and BC-31 appear to be related to turbidity introduced from naturally occurring
sources,
 the source of manganese exceedances reported in BC-27 appear to be related to
turbidity introduced from naturally occurring sources,
 the manganese results at BC-21 do not appear to be related to turbidity, and
Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
November 2015 Sampling EventSECTION 3 – RESULTS

7
 the iron and manganese exceedances at surface water sampling location SW-1 are from
naturally occurring sources and are not related to impacts from the landfill.
The report assessed 2L Standard exceedances for iron, sulfate, and total dissolved solids (TDS)
at monitoring well BC-25. HDR recommended installing an additional monitoring well at the
review boundary between BC-25 and the landfill to further delineate the sulfate and TDS
concentrations in this area and improve the understanding of groundwater flow and quality near
BC-25. HDR further recommended that BC-20 and BC-21 be re-sampled when the new
monitoring well was sampled.
In a letter dated November 28, 20125 to Mr. Ed Sullivan, P.E., of Duke Energy, the NCDEQ
Solid Waste Section approved the recommendations presented in the groundwater assessment
report dated October 5, 2012.
Monitoring well BC-32 was installed in August 2013, and HDR prepared and submitted a
supplemental groundwater assessment to NCDEQ (Supplemental Groundwater Assessment
Belews Creek Steam Station FGD Residue Landfill, Permit No. 8505. June 4, 2014).
The supplemental groundwater assessment report concluded:
 although it is not possible to eliminate leakage through the liner system as a cause for
2L Standard exceedances, leakage through the liner system is not the likely source of 2L
Standard exceedances, and
 increases in precipitation runoff received by non-contact stormwater basins SB-6 and
SB-7, due to the process of filling Cell 1, may have caused deposited FGD residue to be
subjected to increased infiltration into the groundwater at these basins. It appears that
an increase in surface runoff and infiltration of gypsum into the groundwater in this area
may be the source of exceedances of sulfate, TDS, and selenium.
As part of the supplemental groundwater assessment report HDR recommended:
 monitoring well BC-32 should continue to be sampled as part of the groundwater
monitoring program for the FGD Residue Landfill,
 if concentrations of sulfate and TDS decrease to below the 2L Standard in monitoring
wells BC-25 and BC-32 and remain below the 2L Standard for a minimum of two
sampling events, discontinue groundwater monitoring at BC-25 and incorporate
monitoring well BC-32 into the groundwater monitoring program for the FGD Residue
Landfill, and
 if the concentrations of sulfate and TDS remain above the 2L Standards in monitoring
wells BC-25 and BC-32 for the next three sampling events, an additional assessment
should be conducted to identify the sources of the exceedances.
5 North Carolina Department of Environment and Natural Resources, Division of Waste Management.
November 28, 2012, Groundwater Assessment Report Response. Duke Energy – Belews Creek FGD Landfill, DOC ID 17761.
Duke Energy Carolinas, LLC | Belews Creek Steam Station
FGD Residue Landfill Semiannual Groundwater Monitoring Report
November 2015 Sampling EventSECTION 3 – RESULTS

8
This is the third groundwater monitoring event since the completion of the supplemental
groundwater assessment (November 2014, May 2015, and November 2015).
The sulfate and TDS concentrations in monitoring wells BC-25 and BC-32 have been greater
than the 2L Standards during last three sampling events, with the concentrations of these
parameters generally increasing in both of the monitoring wells.
The sulfate concentration measured in monitoring well BC-20 was less than the 2L Standard
during the November 2014 event. When measured in May of 2015, the sulfate concentration in
monitoring well BC-20 increased to a concentration greater than the 2L Standard where it has
remained during the November 2015 sampling event.
The selenium concentration in BC-21 was measured above the 2L standard in August 2013 but
below the standard in all events before and after that event.
Selenium has been measured at concentrations greater than the 2L standard during both May
and November 2015 sampling events (at 20.3 µg/L and 21.9 µg/L, respectively).
The sulfate concentration measured in monitoring well BC-21 has been greater than the 2L
Standard during the last four sampling events.
Based on the results of the sampling events conducted since the June 2014 Supplemental
Groundwater Assessment, HDR recommend that Duke Energy contact DEQ and provide a plan
for further assessment of the groundwater exceedances at the landfill.

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c
a
t
e
s

i
n
c
h
e
s

n
o
m
i
n
a
l

d
i
a
m
e
t
e
r
.
4
.

P
V
C

i
n
d
i
c
a
t
e
s

p
o
l
y
v
i
n
y
l

c
h
l
o
r
i
d
e
.
5
.

P
W
R

i
n
d
i
c
a
t
e
s

p
a
r
t
i
a
l
l
y

w
e
a
t
h
e
r
e
d

r
o
c
k
.
6
.

B
R

i
n
d
i
c
a
t
e
s

b
e
d
r
o
c
k
.
7
.

H
o
r
i
z
o
n
t
a
l

d
a
t
u
m

a
s
s
u
m
e
d

t
o

b
e

N
A
D
8
3
.
8
.

E
l
e
v
a
t
i
o
n
s

b
a
s
e
d

o
n

N
V
G
D

2
9

v
e
r
t
i
c
a
l

d
a
t
u
m
.
9
.

M
o
n
i
t
o
r
i
n
g

w
e
l
l
s

B
C
-
2
5

a
n
d

B
C
-
2
7

a
r
e

f
l
u
s
h
-
m
o
u
n
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l
s
.
10
.

B
C
-
3
2

w
a
s

o
r
i
g
i
n
a
l
l
y

s
u
r
v
e
y
e
d

i
n

N
A
V
D

8
8

v
e
r
t
i
c
a
l

d
a
t
u
m
.

E
l
e
v
a
t
i
o
n

p
r
e
s
e
n
t
e
d

i
n

t
a
b
l
e

w
a
s

c
o
n
v
e
r
t
e
d

t
o

N
V
G
D

2
9

v
e
r
t
i
c
a
l

d
at
u
m
.
11
.

D
e
p
t
h

t
o

g
r
o
u
n
d
w
a
t
e
r

w
a
s

m
e
a
s
u
r
e
d

o
n

N
o
v
e
m
b
e
r

4
,

2
0
1
5
.
12
.

I
n
f
o
r
m
a
t
i
o
n

p
r
o
v
i
d
e
d

b
y

D
u
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s
,

L
L
C

o
n

N
o
v
e
m
b
e
r

2
3
,

2
0
1
5
.
We
l
l

S
t
i
c
k
-
u
p

He
i
g
h
t

A
b
o
v
e

Gr
o
u
n
d

S
u
r
f
a
c
e

(ft
.
)
We
l
l

I
D
We
l
l

In
s
t
a
l
l
a
t
i
o
n

Da
t
e
Co
o
r
d
i
n
a
t
e
s
TO
C

El
e
v
a
t
i
o
n

(
f
t
.
)
Gr
o
u
n
d

S
u
r
f
a
c
e

El
e
v
a
t
i
o
n
(f
t
.
)
Gr
o
u
n
d
w
a
t
e
r

Ele
v
a
t
i
o
n
(f
t
.
)
De
p
t
h

t
o

W
a
t
e
r

be
l
o
w

T
O
C
(ft
.
)
To
t
a
l

W
e
l
l

De
p
t
h

b
e
l
o
w

TO
C
(f
t
.
)
De
p
t
h

t
o

T
o
p

o
f

Sc
r
e
e
n

f
r
o
m

T
O
C
(f
t
.
)
Casing TypeWell Diameter (in.)Geology of Screened Interval
Sc
r
e
e
n
e
d

I
n
t
e
r
v
a
l

be
l
o
w

T
O
C
(f
t
.
)
Page  1  of  1
Ta
b
l
e

2

-

G
r
o
u
n
d
w
a
t
e
r

F
l
o
w

V
e
l
o
c
i
t
i
e
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s

L
L
C
/
B
e
l
e
w
s

C
r
e
e
k

S
t
e
a
m

S
t
a
t
i
o
n
FG
D

R
e
s
i
d
u
e

L
a
n
d
f
i
l
l
,

P
e
r
m
i
t

N
o
.

8
5
0
5
BC
-
7
74
0
73
9
28

0
.
0
2
8

0
.
3
1
0

0
.
0
0
5

1
.
7
6
BC
-
2
0
75
0
74
5
24
6

0
.
0
2
0

0
.
4
1
1

0
.
2
5
9

0
.
0
3
BC
-
2
1
75
0
74
5
76

0
.
0
6
0

0
.
4
1
1

0
.
2
5
9

0
.
0
9
BC
-
2
3
A

7
8
3
78
0
16
7

0
.
0
2
1

0
.
3
1
0

0
.
0
0
5

1
.
2
9
BC
-
2
5
73
5
73
4
23

0
.
0
2
9

0
.
4
1
1

0
.
2
5
9

0
.
0
5
BC
-
2
6
73
5
73
2
69

0
.
0
4
8

0
.
4
1
1

0
.
2
5
9

0
.
0
8
BC
-
2
7
73
5
72
9
90

0
.
0
6
3

0
.
4
1
1

0
.
2
5
9

0
.
1
0
BC
-
2
8
76
6
76
5
21

0
.
0
4
0

0
.
4
1
1

0
.
2
5
9

0
.
0
6
BC
-
2
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73
6
70

0
.
0
5
2

0
.
4
1
1

0
.
2
5
9

0
.
0
8
BC
-
3
0
75
0
74
5
13
9

0
.
0
3
6

0
.
4
1
1

0
.
2
5
9

0
.
0
6
BC
-
3
1
75
5
75
0
45
1

0
.
0
1
1

0
.
3
1
0

0
.
0
0
5

0
.
7
1
BC
-
3
2
74
5
74
0
21
7

0
.
0
2
3

0
.
4
1
1

0
.
2
5
9

0
.
0
4
No
t
e
s
:
1
.

L
i
n
e
a
r

d
i
s
t
a
n
c
e

m
e
a
s
u
r
e
d

t
h
r
o
u
g
h

m
o
n
i
t
o
r
i
n
g

w
e
l
l
s

i
s

a
p
p
r
o
x
i
m
a
t
e
l
y

p
e
r
p
e
n
d
i
c
u
l
a
r

t
o

g
r
o
u
n
d
w
a
t
e
r

c
o
n
t
o
u
r
s
.
2
.

A
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l

l
o
c
a
t
i
o
n
s

w
h
e
r
e

d
o
w
n
g
r
a
d
i
e
n
t

c
o
n
t
o
u
r
s

a
r
e

n
o
t

p
r
e
s
e
n
t
,

t
h
e

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

a
t

t
h
e

m
o
n
i
t
o
r
i
n
g

w
e
l
l

i
s

u
s
e
d

a
s

t
h
e

d
o
w
n
g
r
a
d
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n
.
3
.

A
t

m
o
n
i
t
o
r
i
n
g

w
e
l
l

l
o
c
a
t
i
o
n
s

w
h
e
r
e

u
p
g
r
a
d
i
e
n
t

c
o
n
t
o
u
r
s

a
r
e

n
o
t

p
r
e
s
e
n
t
,

t
h
e

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n

a
t

t
h
e

m
o
n
i
t
o
r
i
n
g

w
e
l
l

i
s

u
s
e
d

a
s

t
h
e

u
p
g
r
a
d
i
e
n
t

g
r
o
u
n
d
w
a
t
e
r

e
l
e
v
a
t
i
o
n
.
4
.

M
o
n
i
t
o
r
i
n
g

w
e
l
l
s

a
r
e

n
o
t

l
i
s
t
e
d

w
h
e
r
e

i
n
s
u
f
f
i
c
i
e
n
t

i
n
f
o
r
m
a
t
i
o
n

i
s

a
v
a
i
l
a
b
l
e

t
o

c
a
l
c
u
l
a
t
e

v
e
l
o
c
i
t
y
.
5
.

H
y
d
r
a
u
l
i
c

g
r
a
d
i
e
n
t
s

a
n
d

g
r
o
u
n
d
w
a
t
e
r

v
e
l
o
c
i
t
i
e
s

a
r
e

a
p
p
r
o
x
i
m
a
t
e
.
6
.

H
y
d
r
a
u
l
i
c

c
o
n
d
u
c
t
i
v
i
t
y

p
r
e
s
e
n
t
e
d

f
o
r

t
h
e

a
l
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e

h
y
d
r
o
s
t
r
a
t
i
g
r
a
p
h
i
c

l
a
y
e
r

i
s

t
h
e

g
e
o
m
e
t
r
i
c

m
e
a
n

o
f

t
h
e

c
o
n
d
u
c
t
i
v
i
t
y

d
a
t
a

i
n

t
h
e

H
D
R

C
o
n
d
u
c
t
i
v
i
t
y

D
a
t
a
b
a
s
e

(
u
n
p
u
b
l
i
s
h
e
d

d
a
t
a

f
r
o
m

P
i
e
d
m
o
n
t

C
a
r
o
l
i
n
a

s
i
t
e
s

w
i
t
h

f
o
l
i
a
t
e
d
/
l
a
y
e
r
e
d

b
e
d
r
o
c
k
)
.
7
.

H
y
d
r
a
u
l
i
c

c
o
n
d
u
c
t
i
v
i
t
y

p
r
e
s
e
n
t
e
d

f
o
r

t
h
e

b
e
d
r
o
c
k

l
a
y
e
r

i
s

t
h
e

g
e
o
m
e
t
r
i
c

m
e
a
n

o
f

t
h
e

c
o
n
d
u
c
t
i
v
i
t
y

d
a
t
a

i
n

t
h
e

H
D
R

C
o
n
d
u
c
t
i
v
i
t
y

D
a
t
a
b
a
s
e

(
u
n
p
u
b
l
i
s
h
e
d

d
a
t
a

f
r
o
m

P
i
e
d
m
o
n
t

C
a
r
o
l
i
n
a

s
i
t
e
s

w
i
t
h

f
o
l
i
a
t
e
d
/
l
a
y
e
r
e
d

b
e
d
r
o
c
k
)
.
8
.

E
f
f
e
c
t
i
v
e

p
o
r
o
s
i
t
y

p
r
e
s
e
n
t
e
d

f
o
r

t
h
e

a
l
l
u
v
i
u
m
/
s
o
i
l
/
s
a
p
r
o
l
i
t
e

h
y
d
r
o
s
t
r
a
t
i
g
r
a
p
h
i
c

l
a
y
e
r

i
s

t
h
e

m
e
a
n

v
a
l
u
e

e
s
t
i
m
a
t
e
d

f
r
o
m

g
r
a
i
n

s
i
z
e

d
a
t
a

u
s
i
n
g

F
e
t
t
e
r
/
B
e
a
r

D
i
a
g
r
a
m
s
.

9
.

E
f
f
e
c
t
i
v
e

p
o
r
o
s
i
t
y

f
o
r

t
h
e

b
e
d
r
o
c
k

l
a
y
e
r

i
s

b
a
s
e
d

o
n

p
u
b
l
i
s
h
e
d

v
a
l
u
e
s

.

10
.

H
y
d
r
a
u
l
i
c

g
r
a
d
i
e
n
t

a
n
d

g
r
o
u
n
d
w
a
t
e
r

v
e
l
o
c
i
t
i
e
s

c
a
l
c
u
l
a
t
e
d

b
a
s
e
d

o
n

g
r
o
u
n
d
w
a
t
e
r

d
e
p
t
h

m
e
a
s
u
r
e
d

o
n

N
o
v
e
m
b
e
r

4
,

2
0
1
5
.
Ef
f
e
c
t
i
v
e

Po
r
o
s
i
t
y

(%
/
1
0
0
)
Gr
o
u
n
d
w
a
t
e
r

Ve
l
o
c
i
t
y

(f
t
/
d
a
y
)
We
l
l

I
D

U
p
g
r
a
d
i
e
n
t

Gr
o
u
n
d
w
a
t
e
r

Co
n
t
o
u
r

El
e
v
a
t
i
o
n
(f
t
)
D
o
w
n
g
r
a
d
i
e
n
t

Gr
o
u
n
d
w
a
t
e
r

Co
n
t
o
u
r

El
e
v
a
t
i
o
n
(f
t
)
Li
n
e
a
r

Di
s
t
a
n
c
e

Be
t
w
e
e
n

Co
n
t
o
u
r
s

th
r
o
u
g
h

W
e
l
l
(f
t
)
Hy
d
r
a
u
l
i
c

Gr
a
d
i
e
n
t

(f
t
/
f
t
)
Hy
d
r
a
u
l
i
c

Co
n
d
u
c
t
i
v
i
t
y

(f
t
/
d
a
y
)
Page 1 of 1
Ta
b
l
e

3

-

F
i
e
l
d

D
a
t
a

P
a
r
a
m
e
t
e
r
s
Du
k
e

E
n
e
r
g
y

C
a
r
o
l
i
n
a
s

L
L
C
/
B
e
l
e
w
s

C
r
e
e
k

S
t
e
a
m

S
t
a
t
i
o
n
FG
D

R
e
s
i
d
u
e

L
a
n
d
f
i
l
l
,

P
e
r
m
i
t

N
o
.

8
5
0
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11
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4
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0
1
5

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-
7

5
2
.
3
0

3
8
.
5
9

7
3
9
.
2
1

N
/
A

N
/
A

L
O

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A

N
/
A
11
/
4
/
2
0
1
5

B
C
-
2
0

2
4
.
2
2

1
1
.
6
3

7
4
5
.
5
9

N
o
r
m
a
l

N
o
n
e

L
F

2
1
0

2
.
0
5

1
.
3
5

N
/
A

1
8
.
5
8

9
3
4

5
.
3

3
3
.
8

4
1
6

8
.
2
4
11
/
4
/
2
0
1
5

B
C
-
2
1

1
6
.
7
7

1
1
.
2
2

7
4
5
.
4
7

N
o
r
m
a
l

N
o
n
e

L
F

2
1
0

0
.
9
1

0
.
8
5

N
/
A

1
8
.
3
0

9
2
1

5
.
1

1
.
8

4
3
9

7
.
4
9
11
/
4
/
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0
1
5

B
C
-
2
2

1
3
.
0
0

3
.
4
3

7
6
2
.
4
8

N
o
r
m
a
l

N
o
n
e

C
P

N
/
A

1
.
5
6

7
.
0
0

N
O

1
6
.
7
8

1
2
5

5
.
6

2
.
8

4
0
9

5
.
5
1
11
/
4
/
2
0
1
5

B
C
-
2
3
A

1
0
1
.
2
1

8
0
.
3
2

7
8
3
.
4
7

N
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r
m
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l

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n
e

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P

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3
.
4
1

7
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0
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3
4

4
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4
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3

4
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4

8
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1
8
11
/
4
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0
1
5

B
C
-
2
5

2
6
.
1
5

1
4
.
1
0

7
3
4
.
3
3

N
o
r
m
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l

N
o
n
e

L
F

2
0
0

1
.
9
7

1
.
3
0

N
/
A

1
9
.
0
7

2
,
0
9
0

5
.
3

1
8
.
7

3
4
6

5
.
9
3
11
/
4
/
2
0
1
5

B
C
-
2
6

2
3
.
2
6

1
7
.
6
0

7
3
1
.
7
2

N
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r
m
a
l

N
o
n
e

L
F

2
7
0

0
.
9
2

5
.
1
5

N
/
A

1
6
.
0
1

1
4
7

4
.
8

9
.
5

3
5
6

3
.
8
2
11
/
4
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0
1
5

B
C
-
2
7

3
8
.
3
3

3
5
.
4
0

7
2
9
.
3
8

N
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r
m
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l

N
o
n
e

L
F

1
2
0

0
.
4
8

1
.
0
5

N
/
A

1
6
.
8
6

7
5

5
.
1

3
.
7

2
2
3

0
.
7
0
11
/
4
/
2
0
1
5

B
C
-
2
8

6
0
.
2
0

5
2
.
2
4

7
6
5
.
8
5

N
o
r
m
a
l

N
o
n
e

L
F

1
5
0

1
.
3
0

0
.
6
5

N
/
A

1
5
.
7
5

6
0

5
.
8

2
.
8

3
8
2

6
.
7
3
11
/
4
/
2
0
1
5

B
C
-
2
9

2
5
.
3
2

1
9
.
8
3

7
3
6
.
3
7

N
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r
m
a
l

N
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n
e

L
F

2
1
0

0
.
9
0

1
.
3
5

N
/
A

1
6
.
3
1

5
5

5
.
1

8
.
2

4
5
1

2
.
1
8
11
/
4
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2
0
1
5

B
C
-
3
0

3
4
.
1
0

2
9
.
2
7

7
4
6
.
4
5

N
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r
m
a
l

N
o
n
e

L
F

1
8
0

0
.
7
9

2
.
0
0

N
/
A

1
4
.
8
4

7
5

5
.
5

8
.
1

4
0
3

7
.
5
4
11
/
4
/
2
0
1
5

B
C
-
3
1

8
3
.
3
0

6
1
.
2
6

7
5
5
.
1
4

N
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r
m
a
l

N
o
n
e

L
F

1
3
0

3
.
5
9

1
.
3
0

N
/
A

1
6
.
0
3

1
0
6

6
.
1

7
.
1

3
2
5

5
.
0
7
11
/
4
/
2
0
1
5

B
C
-
3
2

3
3
.
0
1

1
5
.
3
7

7
4
1
.
1
9

N
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r
m
a
l

N
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n
e

L
F

2
6
0

2
.
8
8

1
.
2
0

N
/
A

1
6
.
8
3

1
,
4
8
4

5
.
4

2
.
0

4
0
2

6
.
2
8
11
/
4
/
2
0
1
5

B
C
-
S
W
1

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
o
n
e

N
/
A

N
/
A

N
/
A

N
/
A

N
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A

1
5
.
8
4

3
4
4

6
.
3

2
0
.
1

2
7
2

7
.
9
9
11
/
4
/
2
0
1
5

B
C
-
L
E
A
C
H
A
T
E

N
/
A

N
/
A

N
/
A

N
o
r
m
a
l

N
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N
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A

N
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N
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6
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7
7

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,
7
9
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4

1
.
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3
6
6

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3
3
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s
:
1
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P
u
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g
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M
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v
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n
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n
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P
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r
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(
3
-
5

w
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v
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m
e
s
)
,

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P
=
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o

P
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(
H
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d
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a
S
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v
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,

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O
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l
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.

P
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p

r
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p
p
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a
b
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t
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p
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o
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s
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b
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L
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p
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3
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n
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w
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w
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l
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v
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n

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w
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l
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w
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d
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w
n

d
o
w
n

t
o

t
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l
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v
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t
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p
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d
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p
u
r
g
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n
g
.
4
.

µ
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m

i
n
d
i
c
a
t
e
s

m
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m
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s

p
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t
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5
.

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.

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y
d
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8
.

m
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m
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d
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a
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m
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l
l
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l
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r
s

p
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m
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t
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9
.

m
g
/
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m
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p
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l
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.
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d
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n
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a
p
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a
b
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7

w
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g
a
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d

f
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d
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t
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w
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r

o
n
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.
12
.

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n
f
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t
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p
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b
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E
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l
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s
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d
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(µ
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m
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pH (SU)TURBIDITY (NTU)ORP (mV-NHE)Page 1 of 1
Ta
b
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4

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a
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Page 1 of 2
Ta
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Page 1 of 1
Ta
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Page 1 of 1

A
Appendix A
Field Sampling Forms

ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬/▬►0.0 0.0 ▬/▬►0.0
SS 718.4 ▬▬►720 719.5 ▬/▬►720
SS 228.0 ▬/▬►227 230.4 ▬/▬►227
SS ▬/▬►▬/▬►
B (7.00)7.02 ▬▬►7.02 7.02 ▬/▬►7.02
B (4.00)3.98 ▬▬►4.00 4.01 ▬/▬►4.00
B (10.00)10.12 ▬/▬►10.06 10.07 ▬/▬►10.06
20.36 20.20
pH Check B (7.00)▬▬►
Time:
SS (7.00)290 ▬▬►294 289 ▬/▬►295
SS (4.00)N/A ▬/▬►469 N/A ▬/▬►470
20.35 20.21
W 8.70 8.70
W 8.70 8.60
AW 8.62 ▬▬►8.70 8.76 ▬/▬►8.65
SS 52.5 ▬/▬►53.5 52.5 ▬/▬►53.5
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 750.1 (mmHg)Ending BP 750.1
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
ORP Temp.ORP Temp.
Calibration Pass
TURB
(ntu)Calibration Accepted Calibration Accepted
DO
(mg/L)Calibration Accepted
Buffer Temp.
Calibration Accepted Calibration Pass
pH
(units)
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Buffer Temp.Buffer Temp.
Parameter Calibration Results Calibration Results
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)
Instrument Zeroed Zero Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Calibration Date / Time 4-Nov-15 4:25 5-Nov-15 500
CALIBRATION BP (mmHg)748.5 CALIBRATION BP (mmHg)748.8
COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:3858
ANALYZER MODEL#:MS5 66121
PROCEDURE #:HYDROLAB 3210.5 VALIDATED BY:
FIELD SAMPLING CALIBRATION FORM
STUDY:BELEWS CREEK STEAM STATION - FGD LANDFILL GROUNDWATER MONITORING
DATE (s):November 4, 2015 SURFACE UNIT READER:LDC
OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW Cloudy, slight breeze, 55 to 65 deg F
ANALYZER SERIAL #:
WEATHER CONDITIONS:
DATE:TIME:DATE:TIME:
Calibation Instrument Standard Instrument Standard
Standard Value Value Value Value
SS 0.0 ▬/▬►0.0 0.0 ▬/▬►0.0
SS 719.7 ▬▬►720 719.8 ▬/▬►720
SS 227.1 ▬/▬►227 230.8 ▬/▬►227
SS ▬/▬►▬/▬►
B (7.00)7.02 ▬▬►7.02 7.00 ▬/▬►7.02
B (4.00)4.00 ▬▬►4.00 4.01 ▬/▬►4.00
B (10.00)10.08 ▬/▬►10.06 10.04 ▬/▬►10.06
20.32 20.17
pH Check B (7.00)▬▬►
Time:
SS (7.00)290 ▬▬►294 291 ▬/▬►295
SS (4.00)N/A ▬/▬►470 N/A ▬/▬►470
20.30 20.19
W 8.70 8.70
W 8.70 8.60
AW 8.55 ▬▬►8.70 8.83 ▬/▬►8.65
SS 53.2 ▬/▬►54.5 54.1 ▬/▬►54.5
NIST N/A ▬/▬►N/A N/A ▬/▬►N/A
KEY:
NOTES:
SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To
(mmHg)
B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable
Replaced DO electrolyte See Notes
Field Barometric Pressure
Beginning BP 750.1 (mmHg)Ending BP 750.1
Tested - OK See Notes Tested - OK See Notes
Dissolved Oxygen Subsystem
Replaced Teflon Membrane Cleaned Electrode
Tested - OK See Notes
Oxidation Reduction Subsystem Temperature Subsystem
Cleaned Electrode Cleaned Electrode
Tested - OK Replaced ref Electrode KCL
See Notes Replaced Ref. Electrode Tip
INSTRUMENT MAINTENANCE DATE / TIME
Conductance Subsystem pH Subsystem
Cleaned Electrodes Cleaned Electrodes
Temp Cert Device #
TEMP
(deg C)Adjustment Not Available Adjustment Not Available
ORP Temp.ORP Temp.
Calibration Pass
TURB
(ntu)Calibration Accepted Calibration Accepted
DO
(mg/L)Calibration Accepted
Buffer Temp.
Calibration Accepted Calibration Pass
pH
(units)
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Buffer Temp.Buffer Temp.
Parameter Calibration Results Calibration Results
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
CHECK (uS/cm)
SPEC. COND.
(uS/cm)
Instrument Zeroed Zero Pass
Calibration Accepted Calibration Pass
Calibration Accepted Calibration Pass
Calibration Date / Time 4-Nov-15 4:10 5-Nov-15 530
CALIBRATION BP (mmHg)748.5 CALIBRATION BP (mmHg)748.8
COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:S05042
ANALYZER MODEL#:MS5 66120
PROCEDURE #:HYDROLAB 3210.5 VALIDATED BY:
FIELD SAMPLING CALIBRATION FORM
STUDY:BELEWS CREEK STEAM STATION - FGD LANDFILL GROUNDWATER MONITORING
DATE (s):November 4, 2015 SURFACE UNIT READER:PSP
OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW Cloudy, slight breeze, 55 to 65 deg F
37.30 52.30
N/A (psi)N/A (sec)(sec)
(gal)
2.24 (gal)
@
QC By:Sample preservation verified to pH
(units)< 2.0
SAMPLING NOTES
ADDITIONAL WELL CONDITION NOTESWELL CONDITION
PROTECTIVE CASING
WELL PAD
WELL TAG
Good Condition
Good Condition
Good Condition
Good Tag
WELL CASING
PSP N/A
TOTAL PURGE
VOLUME
0.00
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
CHLORINE (mg/l)SAMPLE COLLECTED BY
(recalculates on
current water
level)(deg C)(umho/cm)(SU)(NTU)(mV-NHE)(mg/L)
N/A N/A N/A
SAMPLING EQUIPMENT
TUBING DIAMETER (in)
LEVEL ONLY
PURGE COMPLETE TEMP SPECIFIC pH TURBIDITY
WATER ELEVATION (ft msl)739.21
APPEARANCE
DETECTED ODOR None
WATER LEVEL
AFTER PURGE *
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29
WELL DEPTH (ft TOC)
WELL DIAMETER (in)MIDDLE OF WETTED SCREEN (ft toc)
WELL VOL
SCREEN INTERVAL (ft TOC)TO
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)38.59 WATER COLUMN (ft)13.71
EQUIPMENT INFORMATION
LEVEL METER SERIAL#28651
N/APUMP INTAKE DEPTH (ft TOC)52.30
TOC ELEV (ft msl)
GS ELEV (ft msl)
777.80
775.78
WELL/LOCATION NAME BC-7
FIELD CREW LDC, PSP
MONITORING WELL INFORMATION
2
N/A
PROCEDURE NO 3175.2DUKE ENERGY
GROUNDWATER MONITORING DATA SHEET
FOR LEVEL ONLY
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID
PROJECT NAME FGD LANDFILL GROUNDWATER
SAMPLING DATE(s)4-Nov-2015
45.45
PURGE METHOD
Level Only
DISCHARGERECHARGEPRESSURE N/A
PUMP CONTROLLER SETTINGS
0.1631CONVERSION FACTOR
Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
2.24WELL VOLUME
ORP
(ft)(YES/NO)
N/A N/A N/A N/A N/A
VOLUME EVACUATION COND.
11/4/2015
WATER LEVEL ONLY
DATE TIME
DISSOLVED
OXYGEN
14.22 24.22
12 (psi)10 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)4-Nov-2015 WELL/LOCATION NAME BC-20
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)757.22 MIDDLE OF WETTED SCREEN (ft toc)19.22
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)24.22 GS ELEV (ft msl)754.58 PUMP INTAKE DEPTH (ft TOC)23.22
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
Target 200 mL/min.
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)11.63 WATER COLUMN (ft)12.59 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)745.59 WELL VOLUME 2.05
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
10:50 12.69 210 18.51 927 5.33 28.9 413 8.32 N/A
10:45 12.69 210 18.52 939 5.32 6.7 410 8.33
N/A10:55 12.69 210 18.58 934 5.33 33.8 416 8.24
DRAW-DOWN 1.06 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.75 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 1.35 (gal)LDC 11/4/2015 1100 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
6.77 16.77
10 (psi)10 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 0.85 (gal)LDC 11/4/2015 1235 NA
DRAW-DOWN 0.26 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.25 (gal)SAMPLE COLLECTED BY DATE TIME
N/A12:30 11.48 210 18.30 921 5.11 1.8 439 7.49
N/A
12:25 11.48 210 18.33 942 5.11 1.7 437 7.57 N/A
12:20 11.48 210 18.39 962 5.11 1.7 433 7.59
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)11.22 WATER COLUMN (ft)5.55 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)745.47 WELL VOLUME 0.91
Target 210 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 7
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)756.69 MIDDLE OF WETTED SCREEN (ft toc)14.00
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)16.77 GS ELEV (ft msl)753.42 PUMP INTAKE DEPTH (ft TOC)16.27
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)4-Nov-2015 WELL/LOCATION NAME BC-21
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
3.00 13.00
8 (psi)5 (sec)(sec)
(gal)
1.56 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
7.00 LDC 11/4/2015 1155 N/A
1.75 NO 16.78 125 5.59 2.8 409 5.51
1.75 NO 16.78 125 5.59 3.5 408 5.48
1.75 NO 16.77 127 5.61 4.3 405 5.40
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
1.75 NO 16.75 135 5.59 8.8 401
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
5.09
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)3.43 WATER COLUMN (ft)9.57 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)762.48 WELL VOLUME 1.56
Target 500 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)765.91 MIDDLE OF WETTED SCREEN (ft toc)8.22
SCREEN LENGTH (ft)10.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)13.00 GS ELEV (ft msl)763.72 PUMP INTAKE DEPTH (ft TOC)11.50
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)4-Nov-2015 WELL/LOCATION NAME BC-22
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
76.21 101.21
60 (psi)15 (sec)(sec)
(gal)
3.41 (gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE
VOLUME
* Optional measurement to recalculate well
volume when purging results in substantial
drawdown of water column
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME
7.00 LDC 11/4/2015 0755 N/A
1.75 NO 15.34 46 5.86 14.3 424 8.18
1.75 NO 15.29 46 5.88 23.7 420 8.24
OXYGEN (recalculates on
current water
level)(mV-NHE)(mg/L)
3.50 91.53 NO 15.21 46 5.84 25.8 417
(ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU)
8.16 1.58
PURGE WATER LEVEL
AFTER PURGE *
COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
VOLUME EVACUATION COND.
(gal)
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)80.32 WATER COLUMN (ft)20.89 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)783.47 WELL VOLUME 3.41
Target 200 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 6
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Conventional
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)863.79 MIDDLE OF WETTED SCREEN (ft toc)90.77
SCREEN LENGTH (ft)25.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)101.21 GS ELEV (ft msl)862.56 PUMP INTAKE DEPTH (ft TOC)98.71
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)4-Nov-2015 WELL/LOCATION NAME BC-23A
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR CONVENTIONAL SAMPLING
11.15 26.15
8 (psi)10 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
If well is pumped with no energy discharge (8 to 10 psi) turbidity will decrease below 10 ntu.
PROTECTIVE CASING Good Condition Originally a flush mount well, it was converted to a stick-up well by adding a riser to
the well casing during June 2015. The original well depth from TOC was 23.15 ft. June
29, 2015 the dedicated pumps were re-set by adding new tubing. Well depth from TOC
was re-measured at 26.15 ft. and updated on this blankform.
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 1.30 (gal)PSP 11/4/2015 1355 NA
DRAW-DOWN 0.33 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.75 (gal)SAMPLE COLLECTED BY DATE TIME
N/A13:50 14.43 200 19.07 2090 5.26 18.7 346 5.93
N/A
13:45 14.43 200 19.10 2100 5.24 16.5 346 5.95 N/A
13:40 14.43 200 19.14 2100 5.25 16.3 346 5.89
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)14.10 WATER COLUMN (ft)12.05 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)734.33 WELL VOLUME 1.97
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 5
28651 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)748.43 MIDDLE OF WETTED SCREEN (ft toc)20.13
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)26.15 GS ELEV (ft msl)745.97 PUMP INTAKE DEPTH (ft TOC)25.65
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)4-Nov-2015 WELL/LOCATION NAME BC-25
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
8.26 23.26
13 (psi)10 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 5.15 (gal)PSP 11/4/2015 1255 NA
DRAW-DOWN 1.61 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 3.00 (gal)SAMPLE COLLECTED BY DATE TIME
N/A12:50 19.21 270 16.01 147 4.83 9.5 356 3.82
N/A
12:45 19.21 270 16.00 147 4.82 11.1 353 3.86 N/A
12:40 19.21 270 16.00 148 4.83 14.0 350 3.93
N/A
12:35 19.21 270 16.01 150 4.81 22.0 347 3.98 N/A
12:30 19.21 270 16.01 150 4.83 23.8 343 4.06
N/A
12:25 19.21 270 16.02 151 4.84 32.9 340 4.12 N/A
12:20 19.21 270 16.03 152 4.83 42.9 337 4.16
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)17.60 WATER COLUMN (ft)5.66 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)731.72 WELL VOLUME 0.92
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
28651 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)749.32 MIDDLE OF WETTED SCREEN (ft toc)20.43
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)23.26 GS ELEV (ft msl)747.21 PUMP INTAKE DEPTH (ft TOC)22.26
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)4-Nov-2015 WELL/LOCATION NAME BC-26
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
23.33 38.33
17 (psi)10 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition Originally a flush mount well, it was converted to a stick-up well by adding a riser to
the well casing during June 2015. The original well depth from TOC was 34.95 ft. June
29, 2015 the dedicated pumps were re-set by adding new tubing. Well depth from TOC
was re-measured at 38.33 ft. and updated on this blankform.
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 1.05 (gal)PSP 11/4/2015 1120 NA
DRAW-DOWN 0.42 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.25 (gal)SAMPLE COLLECTED BY DATE TIME
N/A
11:15 35.82 120 16.86 75 5.12 3.7 223 0.70 N/A
11:10 35.82 120 16.89 76 5.12 6.0 229 0.71
N/A
11:05 35.82 120 16.93 76 5.13 9.7 235 0.71 N/A
11:00 35.82 120 16.92 77 5.17 28.0 247 0.65
N/A
10:55 35.82 120 16.91 78 5.15 50.9 262 0.64 N/A
10:50 35.82 120 16.99 89 5.22 >1000 298 0.73
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)35.40 WATER COLUMN (ft)2.93 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)729.38 WELL VOLUME 0.48
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
28651 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)764.78 MIDDLE OF WETTED SCREEN (ft toc)36.87
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)38.33 GS ELEV (ft msl)762.44 PUMP INTAKE DEPTH (ft TOC)37.83
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)4-Nov-2015 WELL/LOCATION NAME BC-27
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
45.20 60.20
30 (psi)10 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Minor Cracks
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 0.65 (gal)LDC 11/4/2015 0935 NA
DRAW-DOWN 1.49 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.25 (gal)SAMPLE COLLECTED BY DATE TIME
N/A9:30 53.73 150 15.75 60 5.80 2.8 382 6.73
N/A
9:25 53.73 150 15.74 60 5.79 3.5 379 6.80 N/A
9:20 53.73 150 15.84 61 5.80 7.8 373 7.12
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)52.24 WATER COLUMN (ft)7.96 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)765.85 WELL VOLUME 1.30
Target 150 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)818.09 MIDDLE OF WETTED SCREEN (ft toc)56.22
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)60.20 GS ELEV (ft msl)816.02 PUMP INTAKE DEPTH (ft TOC)59.20
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)4-Nov-2015 WELL/LOCATION NAME BC-28
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
10.32 25.32
12 (psi)10 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
Well casing was extended 3.02 feet higher than previous sampling. Pump intake for this event was estimated to be 4.02 feet off the well bottom (originally 1 foot off the bottom
plus the additional 3.02 feet since the well casing was extended). The well depth should be remeasured and pump intake should be reset to 1 foot from the well bottom.
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 1.35 (gal)PSP 11/4/2015 0930 NA
DRAW-DOWN 0.24 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.75 (gal)SAMPLE COLLECTED BY DATE TIME
N/A9:25 20.07 210 16.31 55 5.10 8.2 451 2.18
N/A
9:20 20.07 210 16.28 55 5.10 19.4 452 2.12 N/A
9:15 20.07 210 16.29 56 5.12 34.9 454 2.09
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)19.83 WATER COLUMN (ft)5.49 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)736.37 WELL VOLUME 0.90
Target 200 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
28651 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)756.20 MIDDLE OF WETTED SCREEN (ft toc)22.58
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)25.32 GS ELEV (ft msl)752.28 PUMP INTAKE DEPTH (ft TOC)SEE NOTE
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)4-Nov-2015 WELL/LOCATION NAME BC-29
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
19.10 34.10
17 (psi)13 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
Well located in middle of field.
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 2.00 (gal)PSP 11/4/2015 0800 NA
DRAW-DOWN 1.07 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 1.50 (gal)SAMPLE COLLECTED BY DATE TIME
N/A7:55 30.34 180 14.84 75 5.52 8.1 403 7.54
N/A
7:50 30.34 180 14.81 75 5.48 6.9 401 7.50 N/A
7:45 30.34 180 14.79 75 5.47 8.0 400 7.47
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)29.27 WATER COLUMN (ft)4.83 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)746.45 WELL VOLUME 0.79
Target 200 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 7
28651 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)775.72 MIDDLE OF WETTED SCREEN (ft toc)31.69
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)34.10 GS ELEV (ft msl)773.91 PUMP INTAKE DEPTH (ft TOC)33.60
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)4-Nov-2015 WELL/LOCATION NAME BC-30
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
63.30 83.30
30 (psi)10 (sec)(sec)
(gal)
@
QC By:
SAMPLING NOTES
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
TOTAL PURGE VOLUME 1.30 (gal)LDC 11/4/2015 0855 NA
DRAW-DOWN 2.90 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.25 (gal)SAMPLE COLLECTED BY DATE TIME
N/A8:50 64.16 130 16.03 106 6.08 7.1 325 5.07
N/A
8:45 64.16 130 16.04 107 6.08 2.8 320 4.93 N/A
8:40 64.16 130 15.98 108 6.08 2.6 314 4.81
N/A
8:35 64.16 130 15.89 110 6.07 2.5 302 4.08 N/A
8:30 64.16 130 15.88 112 6.08 3.6 285 3.84
N/A
8:25 64.16 130 15.93 124 6.09 4.5 266 3.27 N/A
8:20 64.16 130 16.10 121 5.98 4.7 315 3.73
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)61.26 WATER COLUMN (ft)22.04 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)755.14 WELL VOLUME 3.59
Target 140 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 10
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)816.40 MIDDLE OF WETTED SCREEN (ft toc)73.30
SCREEN LENGTH (ft)20.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)83.30 GS ELEV (ft msl)813.43 PUMP INTAKE DEPTH (ft TOC)82.00
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)4-Nov-2015 WELL/LOCATION NAME BC-31
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
18.01 33.01
15 (psi)7 (sec)(sec)
(gal)
@
QC By:
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR LOW FLOW SAMPLING
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)4-Nov-2015 WELL/LOCATION NAME BC-32
MONITORING WELL INFORMATION
WELL DIAMETER (in)2 TOC ELEV (ft msl)756.56 MIDDLE OF WETTED SCREEN (ft toc)25.51
SCREEN LENGTH (ft)15.00 ELEV REF NAVD 29 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)33.01 GS ELEV (ft msl)753.62 PUMP INTAKE DEPTH (ft TOC)32.01
Target 240 mL/min.PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE 8
26056 SAMPLING EQUIPMENT QED T1200 PURGE METHOD
TUBING DIAMETER (in)1/2 OD Low Flow
2.88
DETECTED ODOR None CONVERSION FACTOR 0.1631
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)15.37 WATER COLUMN (ft)17.64 Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)741.19 WELL VOLUME
(gal)
TIME WATER FLOWRATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL
(recalculates on
current water
level)(hh:mm)(ft)(ml/min)(deg C)(umho/cm)(SU)(NTU)(mV -NEH)(mg/L)
LEVEL COND.OXYGEN
N/A
10:10 17.02 260 16.81 1507 5.43 2.1 401 6.38 N/A
10:05 17.02 260 16.75 1523 5.41 2.3 403 6.34
N/A10:15 17.02 260 16.83 1484 5.43 2.0 402 6.28
DRAW-DOWN 1.65 (ft)COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE
(mg/l)INITIAL PURGE VOLUME 0.50 (gal)SAMPLE COLLECTED BY DATE TIME
TOTAL PURGE VOLUME 1.20 (gal)LDC 11/4/2015 1020 NA
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
PROTECTIVE CASING Good Condition
WELL PAD Good Condition
WELL CASING Good Condition
WELL TAG Good Tag
SAMPLING NOTES
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SAMPLING NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
1430
272 7.99
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 15.84 344 6.34 20.1
TIME
PSP 11/4/2015
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
DETECTED ODOR CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
Surface Water Location PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT GRAB PURGE METHOD
TUBING DIAMETER (in)No Purge
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)4-Nov-2015 WELL/LOCATION NAME BC-SW1
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
0.00 0.00
N/A (psi)N/A (sec)(sec)
(gal)
(ft)=(in)@
QC By:
SAMPLING NOTES
PROTECTIVE CASING
WELL PAD
WELL CASING
WELL TAG
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
Sample preservation verified to pH
(units)< 2.0
1020
366 6.33
N/A
N/A
Deployed Water Column In Screen
Above Top Of Hydrasleeve
NO PURGE SAMPLE CHLORINE
(mg/l)Top Weight SAMPLE COLLECTED BY DATE
(NTU)(mV-NHE)(mg/L)
N/A N/A N/A 16.77 2799 6.43 1.1
TIME
PSP 11/4/2015
LENGTH DEPTH (top)DEPLOYED COND.OXYGEN
(inches)(ft TOC)(deg C)(umho/cm)(SU)
HYDRASLEEVE DEPLOYED DATE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED
DETECTED ODOR CONVERSION FACTOR
APPEARANCE Normal
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor
(Conversion factor dependent on well diameter
and selected well volume units)
WATER ELEVATION (ft msl)WELL VOLUME
PUMP CONTROLLER SETTINGS
PRESSURE RECHARGE DISCHARGE N/A
N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD
TUBING DIAMETER (in)3/8 OD No Purge
MONITORING WELL INFORMATION
WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc)
SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A
PROJECT NAME FGD LANDFILL GROUNDWATER FIELD CREW LDC, PSP
SAMPLING DATE(s)4-Nov-2015 WELL/LOCATION NAME BC-LEACHATE
SITE NAME BELEWS CREEK STEAM STATION PERMIT #85-05 SITE ID N/A
DUKE ENERGY PROCEDURE NO 3175.2
GROUNDWATER MONITORING DATA SHEET
FOR NO PURGE SAMPLING
PERMIT #
BC-7 BC-20 BC-21 BC-22 BC-23A BC-25 BC-26 BC-27 BC-28 BC-29 BC-30 BC-31 BC-32 BC-SW1
YES YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES YES
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A
YES YES YES YES YES YES YES YES YES YES YES YES N/A
SEE NOTE
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A
N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
YES YES YES YES YES YES YES YES YES YES YES YES YES N/A
NORTH CAROLINA GROUNDWATER SAMPLING SITE CHECKLIST
LOCATION / SITE BELEWS CREEK STEAM STATION - FGD LANDFILL GROUNDWATER MONITORING 85-05 SAMPLE DATE November 4, 2015
SITE CONTACT Melonie Martin, Kim Hutchinson FIELD CREW LDC, PSP
WEATHER Cloudy, slight breeze, 55 to 65 deg F.
WELL LOCK CONDITION
PAGE 1 OF 1
ACCESS TO WELLS
Access cleared into well
Access cleared around well
Tall grass or weeds - needs mowing
Road washing out / muddy / needs grading
Fallen tree blocking access
WELL SECURITY
Well found locked
Well found unlocked
Undermined / washing out
Lock in good condition
Lock rusted, difficult to open / needs replacing
Replaced damaged lock
WELL CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
CONCRETE PADS
Pad in good condition
Minor cracks
Major cracks / broken / repair required
Replaced damaged well cap
Fire ants around concrete pad
WELL PROTECTIVE CASINGS
Casing in good condition
Damaged casing / still functional
Damaged casing / repair required
Broken hinge on protective lid
Wasp nest inside protective casing
Ants inside protective casing
WELL CAPS
Well cap in good conditon
Damaged / needs replacement
Lacks required information - Completion date
FLUSH MOUNT WELLS
Vault in good condition
Water inside vault
Vault bolt holes broken or stripped
Bolts stripped
Vault lid cracked or broken
WELL ID TAGS
Well tag in good condition
Well tag missing
Well tag damaged / illegible
Lacks required information - Driller Reg #
Lacks required information - Total well depth
Lacks required information - Depth to screen
Lacks required information - Non potable tag
NOTE:BC-28 has a minor crack in the well pad.
WELL DEPTH TO WATER Purge AVG *WELL EVAC SPECIFIC
WELL DEPTH WATER ELEV.Method PMP RATE VOL VOL EVAC TEMP CONDUCTANCE pH TURBIDITY ORP DO
DATE NO.(feet-toc)(feet-toc)(feet)APPEARANCE ODOR (ml/min)(gal)(gal)(yes/no)(deg C)(umho/cm)(units)(NTU)(mV-NHE)(mg/l)
11/4/2015 BC-7 52.30 38.59 739.21 N/A N/A LO N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
11/4/2015 BC-20 24.22 11.63 745.59 Normal None LF 210 2.05 1.35 N/A 18.58 934 5.3 33.8 416 8.24
11/4/2015 BC-21 16.77 11.22 745.47 Normal None LF 210 0.91 0.85 N/A 18.30 921 5.1 1.8 439 7.49
11/4/2015 BC-22 13.00 3.43 762.48 Normal None C N/A 1.56 7.00 NO 16.78 125 5.6 2.8 409 5.51
11/4/2015 BC-23A 101.21 80.32 783.47 Normal None C N/A 3.41 7.00 NO 15.34 46 5.9 14.3 424 8.18
11/4/2015 BC-25 26.15 14.10 734.33 Normal None LF 200 1.97 1.30 N/A 19.07 2090 5.3 18.7 346 5.93
11/4/2015 BC-26 23.26 17.60 731.72 Normal None LF 270 0.92 5.15 N/A 16.01 147 4.8 9.5 356 3.82
11/4/2015 BC-27 38.33 35.40 729.38 Normal None LF 120 0.48 1.05 N/A 16.86 75 5.1 3.7 223 0.70
11/4/2015 BC-28 60.20 52.24 765.85 Normal None LF 150 1.30 0.65 N/A 15.75 60 5.8 2.8 382 6.73
11/4/2015 BC-29 25.32 19.83 736.37 Normal None LF 210 0.90 1.35 N/A 16.31 55 5.1 8.2 451 2.18
11/4/2015 BC-30 34.10 29.27 746.45 Normal None LF 180 0.79 2.00 N/A 14.84 75 5.5 8.1 403 7.54
11/4/2015 BC-31 83.30 61.26 755.14 Normal None LF 130 3.59 1.30 N/A 16.03 106 6.1 7.1 325 5.07
11/4/2015 BC-32 33.01 15.37 741.19 Normal None LF 260 2.88 1.20 N/A 16.83 1484 5.4 2.0 402 6.28
11/4/2015 BC-SW1 0.00 N/A N/A Normal None NP N/A N/A N/A N/A 15.84 344 6.3 20.1 272 7.99
11/4/2015 BC-LEACHATE 0.00 N/A N/A Normal None NP N/A N/A N/A N/A 16.77 2799 6.4 1.1 366 6.33
Purge Methods
LF = Low Flow
LF(M) = Low Flow (Mod.)
C = Connventional
NP = No Purge
EOP = Equip. Only Purge
LO = Level Only
* = Applicable to LF & LF(M) Purging Only
BELEWS CREEK STEAM STATION
FGD LANDFILL GROUNDWATER
GROUNDWATER MONITORING FIELD DATA
PERMIT #85-05

B
Appendix B
Laboratory Report and
Chain-of-Custody Forms

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J15100577
Project Name:BELEWS - GW FGD LF
Lab Contact:Peggy Kendall
Date:11/19/2015
Customer Address:3195 Pine Hall Rd
Customer Name(s):Chuck Campbell, T. Hunsucker, Ed Sullivan
Mailcode: Belews Steam Station
Belews Creek, NC 28012
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Peggy Kendall
Page 1 of 28
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015034575 BELEWS 04-Nov-15 11:00 AM LDC BC-20
2015034576 BELEWS 04-Nov-15 12:35 PM LDC BC-21
2015034577 BELEWS 04-Nov-15 11:55 AM LDC BC-22
2015034578 BELEWS 04-Nov-15 7:55 AM LDC BC-23A
2015034579 BELEWS 04-Nov-15 1:55 PM PSP BC-25
2015034580 BELEWS 04-Nov-15 12:55 PM PSP BC-26
2015034581 BELEWS 04-Nov-15 11:20 AM PSP BC-27
2015034582 BELEWS 04-Nov-15 9:35 AM LDC BC-28
2015034583 BELEWS 04-Nov-15 9:30 AM PSP BC-29
2015034584 BELEWS 04-Nov-15 8:00 AM PSP BC-30
2015034585 BELEWS 04-Nov-15 8:55 AM LDC BC-31
2015034586 BELEWS 04-Nov-15 10:20 AM LDC BC-32
2015034587 BELEWS 04-Nov-15 2:30 PM PSP SW-1
2015034588 BELEWS 04-Nov-15 10:20 AM PSP LEACHATE
2015034589 BELEWS 04-Nov-15 2:50 PM PSP FIELD BLANK
15 Total Samples
Page 2 of 28
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:11/19/2015
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
2015034575
Collection Date:04-Nov-15 11:00 AM
Site:BC-20
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)5.6 mg/L
(CaCO3)
SM 2320B4d 11/07/2015 10:44 GHUTCHI51
INORGANIC IONS BY IC
Chloride 3.3 mg/L EPA 300.0 11/05/2015 14:32 BGN90340.5 5
Fluoride < 0.5 mg/L EPA 300.0 11/05/2015 14:32 BGN90340.5 5
Nitrate 9.3 mg/L EPA 300.0 11/05/2015 14:32 BGN90340.5 5
Nitrate as N 2.1 mg-N/L EPA 300.0 11/05/2015 14:32 BGN90340.023 1
Sulfate 490 mg/L EPA 300.0 11/05/2015 14:32 BGN903410100
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/10/2015 16:54 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.054 mg/L EPA 200.7 11/06/2015 09:23 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/06/2015 09:23 MHH71310.05 1
Calcium (Ca)112 mg/L EPA 200.7 11/06/2015 09:23M4 MHH71310.1 10
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/06/2015 09:23 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/06/2015 09:23 MHH71310.005 1
Iron (Fe)0.725 mg/L EPA 200.7 11/06/2015 09:23 MHH71310.01 1
Magnesium (Mg)45.4 mg/L EPA 200.7 11/06/2015 09:23 MHH71310.005 1
Manganese (Mn)0.020 mg/L EPA 200.7 11/06/2015 09:23 MHH71310.005 1
Nickel (Ni)0.016 mg/L EPA 200.7 11/06/2015 09:23 MHH71310.005 1
Potassium (K)6.11 mg/L EPA 200.7 11/06/2015 09:23 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/06/2015 09:23 MHH71310.005 1
Sodium (Na)23.7 mg/L EPA 200.7 11/06/2015 09:23 MHH71310.05 1
Zinc (Zn)0.019 mg/L EPA 200.7 11/06/2015 09:23 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/05/2015 18:35 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/05/2015 18:35 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/05/2015 18:35 MHALL311
Selenium (Se)2.24 ug/L EPA 200.8 11/05/2015 18:35 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 780 mg/L SM2540C 11/05/2015 14:15 CJELLIO251
Page 4 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
2015034576
Collection Date:04-Nov-15 12:35 PM
Site:BC-21
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B4d 11/07/2015 10:44 GHUTCHI51
INORGANIC IONS BY IC
Chloride 5.5 mg/L EPA 300.0 11/05/2015 14:50 BGN90340.5 5
Fluoride < 0.5 mg/L EPA 300.0 11/05/2015 14:50 BGN90340.5 5
Nitrate 15 mg/L EPA 300.0 11/05/2015 14:50 BGN90340.5 5
Nitrate as N 3.3 mg-N/L EPA 300.0 11/05/2015 14:50 BGN90340.023 1
Sulfate 450 mg/L EPA 300.0 11/05/2015 14:50 BGN903410100
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/10/2015 16:57 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.020 mg/L EPA 200.7 11/06/2015 09:35 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/06/2015 09:35 MHH71310.05 1
Calcium (Ca)63.1 mg/L EPA 200.7 11/06/2015 09:35B2 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/06/2015 09:35 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/06/2015 09:35 MHH71310.005 1
Iron (Fe)0.012 mg/L EPA 200.7 11/06/2015 09:35 MHH71310.01 1
Magnesium (Mg)70.0 mg/L EPA 200.7 11/06/2015 09:35 MHH71310.005 1
Manganese (Mn)0.089 mg/L EPA 200.7 11/06/2015 09:35 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/06/2015 09:35 MHH71310.005 1
Potassium (K)3.93 mg/L EPA 200.7 11/06/2015 09:35 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/06/2015 09:35 MHH71310.005 1
Sodium (Na)23.8 mg/L EPA 200.7 11/06/2015 09:35 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/06/2015 09:35 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)1.64 ug/L EPA 200.8 11/05/2015 18:14 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/05/2015 18:14 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/05/2015 18:14 MHALL311
Selenium (Se)1.77 ug/L EPA 200.8 11/05/2015 18:14 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 720 mg/L SM2540C 11/05/2015 14:15 CJELLIO251
Page 5 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
2015034577
Collection Date:04-Nov-15 11:55 AM
Site:BC-22
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)18 mg/L
(CaCO3)
SM 2320B4d 11/07/2015 10:44 GHUTCHI51
INORGANIC IONS BY IC
Chloride 4.3 mg/L EPA 300.0 11/05/2015 13:57 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 11/05/2015 13:57 BGN90340.1 1
Nitrate 5.0 mg/L EPA 300.0 11/05/2015 13:57 BGN90340.1 1
Nitrate as N 1.1 mg-N/L EPA 300.0 11/05/2015 13:57 BGN90340.023 1
Sulfate 25 mg/L EPA 300.0 11/05/2015 13:57 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/10/2015 16:59 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.086 mg/L EPA 200.7 11/06/2015 09:39 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/06/2015 09:39 MHH71310.05 1
Calcium (Ca)9.06 mg/L EPA 200.7 11/06/2015 09:39B2 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/06/2015 09:39 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/06/2015 09:39 MHH71310.005 1
Iron (Fe)0.203 mg/L EPA 200.7 11/06/2015 09:39 MHH71310.01 1
Magnesium (Mg)3.46 mg/L EPA 200.7 11/06/2015 09:39 MHH71310.005 1
Manganese (Mn)0.060 mg/L EPA 200.7 11/06/2015 09:39 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/06/2015 09:39 MHH71310.005 1
Potassium (K)2.10 mg/L EPA 200.7 11/06/2015 09:39 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/06/2015 09:39 MHH71310.005 1
Sodium (Na)7.44 mg/L EPA 200.7 11/06/2015 09:39 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/06/2015 09:39 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/05/2015 18:42 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/05/2015 18:42 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/05/2015 18:42 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 11/05/2015 18:42 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 100 mg/L SM2540C 11/05/2015 14:15 CJELLIO251
Page 6 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
2015034578
Collection Date:04-Nov-15 7:55 AM
Site:BC-23A
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)17 mg/L
(CaCO3)
SM 2320B4d 11/07/2015 10:44 GHUTCHI51
INORGANIC IONS BY IC
Chloride 2.3 mg/L EPA 300.0 11/05/2015 10:23 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 11/05/2015 10:23 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 11/05/2015 10:23 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 11/05/2015 10:23 BGN90340.023 1
Sulfate 0.23 mg/L EPA 300.0 11/05/2015 10:23 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/10/2015 17:01 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.035 mg/L EPA 200.7 11/06/2015 09:44 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/06/2015 09:44 MHH71310.05 1
Calcium (Ca)1.54 mg/L EPA 200.7 11/06/2015 09:44B2 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/06/2015 09:44 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/06/2015 09:44 MHH71310.005 1
Iron (Fe)0.445 mg/L EPA 200.7 11/06/2015 09:44 MHH71310.01 1
Magnesium (Mg)0.850 mg/L EPA 200.7 11/06/2015 09:44 MHH71310.005 1
Manganese (Mn)0.008 mg/L EPA 200.7 11/06/2015 09:44 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/06/2015 09:44 MHH71310.005 1
Potassium (K)1.56 mg/L EPA 200.7 11/06/2015 09:44 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/06/2015 09:44 MHH71310.005 1
Sodium (Na)5.96 mg/L EPA 200.7 11/06/2015 09:44 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/06/2015 09:44 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/05/2015 18:49 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/05/2015 18:49 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/05/2015 18:49 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 11/05/2015 18:49 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 64 mg/L SM2540C 11/05/2015 14:15 CJELLIO251
Page 7 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
2015034579
Collection Date:04-Nov-15 1:55 PM
Site:BC-25
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)13 mg/L
(CaCO3)
SM 2320B4d 11/07/2015 10:44 GHUTCHI51
INORGANIC IONS BY IC
Chloride 48 mg/L EPA 300.0 11/05/2015 15:08 BGN9034110
Fluoride < 1 mg/L EPA 300.0 11/05/2015 15:08 BGN9034110
Nitrate 7.7 mg/L EPA 300.0 11/05/2015 15:08 BGN9034110
Nitrate as N 1.7 mg-N/L EPA 300.0 11/05/2015 15:08 BGN90340.023 1
Sulfate 1100 mg/L EPA 300.0 11/05/2015 15:08 BGN903420200
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/10/2015 17:04 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.070 mg/L EPA 200.7 11/06/2015 09:48 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/06/2015 09:48 MHH71310.05 1
Calcium (Ca)269 mg/L EPA 200.7 11/06/2015 09:48B2 MHH71310.1 10
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/06/2015 09:48 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/06/2015 09:48 MHH71310.005 1
Iron (Fe)1.25 mg/L EPA 200.7 11/06/2015 09:48 MHH71310.01 1
Magnesium (Mg)137 mg/L EPA 200.7 11/06/2015 09:48 MHH71310.05 10
Manganese (Mn)0.099 mg/L EPA 200.7 11/06/2015 09:48 MHH71310.005 1
Nickel (Ni)0.047 mg/L EPA 200.7 11/06/2015 09:48 MHH71310.005 1
Potassium (K)10.3 mg/L EPA 200.7 11/06/2015 09:48 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/06/2015 09:48 MHH71310.005 1
Sodium (Na)38.0 mg/L EPA 200.7 11/06/2015 09:48 MHH71310.05 1
Zinc (Zn)0.014 mg/L EPA 200.7 11/06/2015 09:48 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/05/2015 18:56 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/05/2015 18:56 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/05/2015 18:56 MHALL311
Selenium (Se)21.9 ug/L EPA 200.8 11/05/2015 18:56 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 1800 mg/L SM2540C 11/05/2015 14:15 CJELLIO251
Page 8 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
2015034580
Collection Date:04-Nov-15 12:55 PM
Site:BC-26
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)< 5 mg/L
(CaCO3)
SM 2320B4d 11/07/2015 10:44 GHUTCHI51
INORGANIC IONS BY IC
Chloride 15 mg/L EPA 300.0 11/05/2015 14:15 BGN90340.5 5
Fluoride < 0.1 mg/L EPA 300.0 11/05/2015 14:15 BGN90340.1 1
Nitrate 24 mg/L EPA 300.0 11/05/2015 14:15 BGN90340.5 5
Nitrate as N 5.4 mg-N/L EPA 300.0 11/05/2015 14:15 BGN90340.023 1
Sulfate 13 mg/L EPA 300.0 11/05/2015 14:15 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/10/2015 17:11 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.287 mg/L EPA 200.7 11/06/2015 09:52 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/06/2015 09:52 MHH71310.05 1
Calcium (Ca)2.04 mg/L EPA 200.7 11/06/2015 09:52B2 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/06/2015 09:52 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/06/2015 09:52 MHH71310.005 1
Iron (Fe)0.313 mg/L EPA 200.7 11/06/2015 09:52 MHH71310.01 1
Magnesium (Mg)6.39 mg/L EPA 200.7 11/06/2015 09:52 MHH71310.005 1
Manganese (Mn)0.028 mg/L EPA 200.7 11/06/2015 09:52 MHH71310.005 1
Nickel (Ni)0.007 mg/L EPA 200.7 11/06/2015 09:52 MHH71310.005 1
Potassium (K)4.22 mg/L EPA 200.7 11/06/2015 09:52 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/06/2015 09:52 MHH71310.005 1
Sodium (Na)10.3 mg/L EPA 200.7 11/06/2015 09:52 MHH71310.05 1
Zinc (Zn)0.052 mg/L EPA 200.7 11/06/2015 09:52 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/05/2015 19:03 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/05/2015 19:03 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/05/2015 19:03 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 11/05/2015 19:03 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 110 mg/L SM2540C 11/05/2015 14:15 CJELLIO251
Page 9 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
2015034581
Collection Date:04-Nov-15 11:20 AM
Site:BC-27
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)17 mg/L
(CaCO3)
SM 2320B4d 11/07/2015 10:44 GHUTCHI51
INORGANIC IONS BY IC
Chloride 9.8 mg/L EPA 300.0 11/05/2015 11:17 BGN90340.2 2
Fluoride < 0.1 mg/L EPA 300.0 11/05/2015 11:17 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 11/05/2015 11:17 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 11/05/2015 11:17 BGN90340.023 1
Sulfate 0.13 mg/L EPA 300.0 11/05/2015 11:17 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/10/2015 17:18 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.034 mg/L EPA 200.7 11/06/2015 10:05 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/06/2015 10:05 MHH71310.05 1
Calcium (Ca)0.370 mg/L EPA 200.7 11/06/2015 10:05B2 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/06/2015 10:05 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/06/2015 10:05 MHH71310.005 1
Iron (Fe)3.17 mg/L EPA 200.7 11/06/2015 10:05 MHH71310.01 1
Magnesium (Mg)1.65 mg/L EPA 200.7 11/06/2015 10:05 MHH71310.005 1
Manganese (Mn)0.268 mg/L EPA 200.7 11/06/2015 10:05 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/06/2015 10:05 MHH71310.005 1
Potassium (K)2.54 mg/L EPA 200.7 11/06/2015 10:05 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/06/2015 10:05 MHH71310.005 1
Sodium (Na)7.60 mg/L EPA 200.7 11/06/2015 10:05 MHH71310.05 1
Zinc (Zn)0.006 mg/L EPA 200.7 11/06/2015 10:05 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/05/2015 19:10 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/05/2015 19:10 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/05/2015 19:10 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 11/05/2015 19:10 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 72 mg/L SM2540C 11/05/2015 14:15 CJELLIO251
Page 10 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
2015034582
Collection Date:04-Nov-15 9:35 AM
Site:BC-28
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)21 mg/L
(CaCO3)
SM2320B 11/06/2015 12:33 GHUTCHI201
INORGANIC IONS BY IC
Chloride 1.7 mg/L EPA 300.0 11/05/2015 11:34 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 11/05/2015 11:34 BGN90340.1 1
Nitrate 4.3 mg/L EPA 300.0 11/05/2015 11:34 BGN90340.1 1
Nitrate as N 0.98 mg-N/L EPA 300.0 11/05/2015 11:34 BGN90340.023 1
Sulfate 0.34 mg/L EPA 300.0 11/05/2015 11:34 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/10/2015 17:20 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.029 mg/L EPA 200.7 11/06/2015 10:09 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/06/2015 10:09 MHH71310.05 1
Calcium (Ca)3.95 mg/L EPA 200.7 11/06/2015 10:09B2 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/06/2015 10:09 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/06/2015 10:09 MHH71310.005 1
Iron (Fe)0.051 mg/L EPA 200.7 11/06/2015 10:09 MHH71310.01 1
Magnesium (Mg)1.27 mg/L EPA 200.7 11/06/2015 10:09 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 11/06/2015 10:09 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/06/2015 10:09 MHH71310.005 1
Potassium (K)2.09 mg/L EPA 200.7 11/06/2015 10:09 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/06/2015 10:09 MHH71310.005 1
Sodium (Na)4.97 mg/L EPA 200.7 11/06/2015 10:09 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/06/2015 10:09 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/05/2015 19:17 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/05/2015 19:17 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/05/2015 19:17 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 11/05/2015 19:17 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 73 mg/L SM2540C 11/05/2015 14:15 CJELLIO251
Page 11 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
2015034583
Collection Date:04-Nov-15 9:30 AM
Site:BC-29
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)14 mg/L
(CaCO3)
SM 2320B4d 11/07/2015 10:44 GHUTCHI51
INORGANIC IONS BY IC
Chloride 5.0 mg/L EPA 300.0 11/05/2015 11:52 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 11/05/2015 11:52 BGN90340.1 1
Nitrate 1.4 mg/L EPA 300.0 11/05/2015 11:52 BGN90340.1 1
Nitrate as N 0.32 mg-N/L EPA 300.0 11/05/2015 11:52 BGN90340.023 1
Sulfate 1.4 mg/L EPA 300.0 11/05/2015 11:52 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/10/2015 17:23 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.130 mg/L EPA 200.7 11/06/2015 10:14 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/06/2015 10:14 MHH71310.05 1
Calcium (Ca)0.985 mg/L EPA 200.7 11/06/2015 10:14B2 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/06/2015 10:14 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/06/2015 10:14 MHH71310.005 1
Iron (Fe)0.328 mg/L EPA 200.7 11/06/2015 10:14 MHH71310.01 1
Magnesium (Mg)1.90 mg/L EPA 200.7 11/06/2015 10:14 MHH71310.005 1
Manganese (Mn)0.010 mg/L EPA 200.7 11/06/2015 10:14 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/06/2015 10:14 MHH71310.005 1
Potassium (K)1.66 mg/L EPA 200.7 11/06/2015 10:14 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/06/2015 10:14 MHH71310.005 1
Sodium (Na)5.99 mg/L EPA 200.7 11/06/2015 10:14 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/06/2015 10:14 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/05/2015 19:24 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/05/2015 19:24 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/05/2015 19:24 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 11/05/2015 19:24 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 62 mg/L SM2540C 11/05/2015 14:15 CJELLIO251
Page 12 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
2015034584
Collection Date:04-Nov-15 8:00 AM
Site:BC-30
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)28 mg/L
(CaCO3)
SM2320B 11/06/2015 12:33 GHUTCHI201
INORGANIC IONS BY IC
Chloride 3.9 mg/L EPA 300.0 11/05/2015 12:10 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 11/05/2015 12:10 BGN90340.1 1
Nitrate 2.4 mg/L EPA 300.0 11/05/2015 12:10 BGN90340.1 1
Nitrate as N 0.54 mg-N/L EPA 300.0 11/05/2015 12:10 BGN90340.023 1
Sulfate 0.68 mg/L EPA 300.0 11/05/2015 12:10 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/10/2015 17:25 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.021 mg/L EPA 200.7 11/06/2015 10:18 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/06/2015 10:18 MHH71310.05 1
Calcium (Ca)5.71 mg/L EPA 200.7 11/06/2015 10:18B2 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/06/2015 10:18 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/06/2015 10:18 MHH71310.005 1
Iron (Fe)0.573 mg/L EPA 200.7 11/06/2015 10:18 MHH71310.01 1
Magnesium (Mg)2.14 mg/L EPA 200.7 11/06/2015 10:18 MHH71310.005 1
Manganese (Mn)0.009 mg/L EPA 200.7 11/06/2015 10:18 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/06/2015 10:18 MHH71310.005 1
Potassium (K)1.62 mg/L EPA 200.7 11/06/2015 10:18 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/06/2015 10:18 MHH71310.005 1
Sodium (Na)5.59 mg/L EPA 200.7 11/06/2015 10:18 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/06/2015 10:18 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/05/2015 19:31 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/05/2015 19:31 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/05/2015 19:31 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 11/05/2015 19:31 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 85 mg/L SM2540C 11/05/2015 14:15 CJELLIO251
Page 13 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
2015034585
Collection Date:04-Nov-15 8:55 AM
Site:BC-31
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)46 mg/L
(CaCO3)
SM2320B 11/06/2015 12:33 GHUTCHI201
INORGANIC IONS BY IC
Chloride 1.9 mg/L EPA 300.0 11/05/2015 17:13 BGN90340.1 1
Fluoride 0.13 mg/L EPA 300.0 11/05/2015 17:13 BGN90340.1 1
Nitrate 3.7 mg/L EPA 300.0 11/05/2015 17:13 BGN90340.1 1
Nitrate as N 0.83 mg-N/L EPA 300.0 11/05/2015 17:13 BGN90340.023 1
Sulfate 1.2 mg/L EPA 300.0 11/05/2015 17:13 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/10/2015 17:27 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.024 mg/L EPA 200.7 11/06/2015 10:30 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/06/2015 10:30 MHH71310.05 1
Calcium (Ca)7.53 mg/L EPA 200.7 11/06/2015 10:30B2 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/06/2015 10:30 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/06/2015 10:30 MHH71310.005 1
Iron (Fe)0.509 mg/L EPA 200.7 11/06/2015 10:30 MHH71310.01 1
Magnesium (Mg)3.73 mg/L EPA 200.7 11/06/2015 10:30 MHH71310.005 1
Manganese (Mn)0.015 mg/L EPA 200.7 11/06/2015 10:30 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/06/2015 10:30 MHH71310.005 1
Potassium (K)1.65 mg/L EPA 200.7 11/06/2015 10:30 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/06/2015 10:30 MHH71310.005 1
Sodium (Na)7.79 mg/L EPA 200.7 11/06/2015 10:30 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/06/2015 10:30 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/05/2015 19:59 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/05/2015 19:59 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/05/2015 19:59 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 11/05/2015 19:59 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 97 mg/L SM2540C 11/05/2015 14:15 CJELLIO251
Page 14 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
2015034586
Collection Date:04-Nov-15 10:20 AM
Site:BC-32
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
LOW LEVEL ALKALINITY (FIXED END POINT)
Alkalinity (mg/L CaCO3)14 mg/L
(CaCO3)
SM 2320B4d 11/07/2015 10:44 GHUTCHI51
INORGANIC IONS BY IC
Chloride 2.2 mg/L EPA 300.0 11/05/2015 21:06 BGN90340.2 2
Fluoride < 0.2 mg/L EPA 300.0 11/05/2015 21:06 BGN90340.2 2
Nitrate 3.6 mg/L EPA 300.0 11/05/2015 21:06 BGN90340.2 2
Nitrate as N 0.82 mg-N/L EPA 300.0 11/05/2015 21:06 BGN90340.023 1
Sulfate 850 mg/L EPA 300.0 11/05/2015 21:06 BGN903420200
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/10/2015 17:29 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.058 mg/L EPA 200.7 11/06/2015 10:34 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/06/2015 10:34 MHH71310.05 1
Calcium (Ca)159 mg/L EPA 200.7 11/06/2015 10:34B2 MHH71310.1 10
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/06/2015 10:34 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/06/2015 10:34 MHH71310.005 1
Iron (Fe)0.033 mg/L EPA 200.7 11/06/2015 10:34 MHH71310.01 1
Magnesium (Mg)109 mg/L EPA 200.7 11/06/2015 10:34 MHH71310.05 10
Manganese (Mn)0.013 mg/L EPA 200.7 11/06/2015 10:34 MHH71310.005 1
Nickel (Ni)0.021 mg/L EPA 200.7 11/06/2015 10:34 MHH71310.005 1
Potassium (K)6.58 mg/L EPA 200.7 11/06/2015 10:34 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/06/2015 10:34 MHH71310.005 1
Sodium (Na)28.9 mg/L EPA 200.7 11/06/2015 10:34 MHH71310.05 1
Zinc (Zn)0.014 mg/L EPA 200.7 11/06/2015 10:34 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/05/2015 20:06 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/05/2015 20:06 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/05/2015 20:06 MHALL311
Selenium (Se)5.98 ug/L EPA 200.8 11/05/2015 20:06 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 1300 mg/L SM2540C 11/05/2015 14:15 CJELLIO251
Page 15 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
2015034587
Collection Date:04-Nov-15 2:30 PM
Site:SW-1
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)26 mg/L
(CaCO3)
SM2320B 11/06/2015 12:33 GHUTCHI201
INORGANIC IONS BY IC
Chloride 3.6 mg/L EPA 300.0 11/05/2015 19:01 BGN90340.2 2
Fluoride < 0.2 mg/L EPA 300.0 11/05/2015 19:01 BGN90340.2 2
Nitrate 0.45 mg/L EPA 300.0 11/05/2015 19:01 BGN90340.2 2
Nitrate as N 0.10 mg-N/L EPA 300.0 11/05/2015 19:01 BGN90340.023 1
Sulfate 130 mg/L EPA 300.0 11/05/2015 19:01 BGN9034550
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/10/2015 17:32 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.060 mg/L EPA 200.7 11/06/2015 10:38 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/06/2015 10:38 MHH71310.05 1
Calcium (Ca)49.9 mg/L EPA 200.7 11/06/2015 10:38B2 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/06/2015 10:38 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/06/2015 10:38 MHH71310.005 1
Iron (Fe)1.86 mg/L EPA 200.7 11/06/2015 10:38 MHH71310.01 1
Magnesium (Mg)4.86 mg/L EPA 200.7 11/06/2015 10:38 MHH71310.005 1
Manganese (Mn)0.235 mg/L EPA 200.7 11/06/2015 10:38 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/06/2015 10:38 MHH71310.005 1
Potassium (K)6.13 mg/L EPA 200.7 11/06/2015 10:38 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/06/2015 10:38 MHH71310.005 1
Sodium (Na)3.05 mg/L EPA 200.7 11/06/2015 10:38 MHH71310.05 1
Zinc (Zn)0.043 mg/L EPA 200.7 11/06/2015 10:38 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/05/2015 20:13 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/05/2015 20:13 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/05/2015 20:13 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 11/05/2015 20:13 MHALL311
TOTAL DISSOLVED SOLIDS
TDS 240 mg/L SM2540C 11/05/2015 14:15 CJELLIO251
Page 16 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
2015034588
Collection Date:04-Nov-15 10:20 AM
Site:LEACHATE
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)220 mg/L
(CaCO3)
SM2320B 11/06/2015 12:33 GHUTCHI201
INORGANIC IONS BY IC
Chloride 90 mg/L EPA 300.0 11/05/2015 21:24 BGN90342.5 25
Fluoride < 2.5 mg/L EPA 300.0 11/05/2015 21:24 BGN90342.5 25
Nitrate 8.9 mg/L EPA 300.0 11/05/2015 21:24 BGN90342.5 25
Nitrate as N 2.0 mg-N/L EPA 300.0 11/05/2015 21:24 BGN90340.023 1
Sulfate 1600 mg/L EPA 300.0 11/05/2015 21:24 BGN903450500
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/10/2015 17:34 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)0.016 mg/L EPA 200.7 11/06/2015 10:46 MHH71310.005 1
Boron (B)6.57 mg/L EPA 200.7 11/06/2015 10:46 MHH71310.05 1
Calcium (Ca)643 mg/L EPA 200.7 11/06/2015 10:46B2 MHH71310.1 10
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/06/2015 10:46 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/06/2015 10:46 MHH71310.005 1
Iron (Fe)0.047 mg/L EPA 200.7 11/06/2015 10:46 MHH71310.01 1
Magnesium (Mg)82.4 mg/L EPA 200.7 11/06/2015 10:46 MHH71310.005 1
Manganese (Mn)9.01 mg/L EPA 200.7 11/06/2015 10:46 MHH71310.005 1
Nickel (Ni)0.010 mg/L EPA 200.7 11/06/2015 10:46 MHH71310.005 1
Potassium (K)6.79 mg/L EPA 200.7 11/06/2015 10:46 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/06/2015 10:46 MHH71310.005 1
Sodium (Na)6.40 mg/L EPA 200.7 11/06/2015 10:46 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/06/2015 10:46 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)1.19 ug/L EPA 200.8 11/05/2015 20:20 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/05/2015 20:20 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/05/2015 20:20 MHALL311
Selenium (Se)2160 ug/L EPA 200.8 11/05/2015 20:20 MHALL31010
TOTAL DISSOLVED SOLIDS
TDS 120 mg/L SM2540C 11/05/2015 14:15 CJELLIO251
Page 17 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
2015034589
Collection Date:04-Nov-15 2:50 PM
Site:FIELD BLANK
Matrix:GW_RCRA
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY (FIXED END POINT 4.5)
Alkalinity (mg/L CaCO3)< 20 mg/L
(CaCO3)
SM2320B 11/06/2015 12:33 GHUTCHI201
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 11/05/2015 16:37 BGN90340.1 1
Fluoride < 0.1 mg/L EPA 300.0 11/05/2015 16:37 BGN90340.1 1
Nitrate < 0.1 mg/L EPA 300.0 11/05/2015 16:37 BGN90340.1 1
Nitrate as N < 0.023 mg-N/L EPA 300.0 11/05/2015 16:37 BGN90340.023 1
Sulfate < 0.1 mg/L EPA 300.0 11/05/2015 16:37 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 11/10/2015 17:37 ACPAYNE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Barium (Ba)< 0.005 mg/L EPA 200.7 11/06/2015 10:42 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 11/06/2015 10:42 MHH71310.05 1
Calcium (Ca)0.017 mg/L EPA 200.7 11/06/2015 10:42B2 MHH71310.01 1
Chromium (Cr)< 0.005 mg/L EPA 200.7 11/06/2015 10:42 MHH71310.005 1
Copper (Cu)< 0.005 mg/L EPA 200.7 11/06/2015 10:42 MHH71310.005 1
Iron (Fe)< 0.01 mg/L EPA 200.7 11/06/2015 10:42 MHH71310.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 11/06/2015 10:42 MHH71310.005 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 11/06/2015 10:42 MHH71310.005 1
Nickel (Ni)< 0.005 mg/L EPA 200.7 11/06/2015 10:42 MHH71310.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 11/06/2015 10:42 MHH71310.1 1
Silver (Ag)< 0.005 mg/L EPA 200.7 11/06/2015 10:42 MHH71310.005 1
Sodium (Na)< 0.05 mg/L EPA 200.7 11/06/2015 10:42 MHH71310.05 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 11/06/2015 10:42 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Arsenic (As)< 1 ug/L EPA 200.8 11/05/2015 20:27 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 11/05/2015 20:27 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 11/05/2015 20:27 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 11/05/2015 20:27 MHALL311
Qualifiers:
B2 Target analyte was detected in blank(s) at a concentration greater than ½ the reporting limit but less than the
reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate
to the spike level. The associated Laboratory Control Spike recovery was acceptable.
Page 18 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
Q15110126 ALK_FIX4.5 ALKALINITY (FIXED END POINT 4.5)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J15100577 -- 2015034587
Alkalinity (mg/L CaCO3)0.194mg/L
(CaCO3)
-125.8
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3)81.6 97.1mg/L
(CaCO3)
-12080179.2
Page 19 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
Q15110149 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J15100577 -- 2015034575
Alkalinity (mg/L CaCO3)0.183mg/L
(CaCO3)
-15.58
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J15100577 -- 2015034586
Alkalinity (mg/L CaCO3)0.334mg/L
(CaCO3)
-113.6
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3)8.16 93.2mg/L
(CaCO3)
-1208017.61
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Alkalinity (mg/L CaCO3)8.16 83.2mg/L
(CaCO3)
-1208016.79
Page 20 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
Q15110093 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0241 mg/L -10.0241 0.1 < 1/2 RDL
Fluoride 0.0453 mg/L -10.0453 0.1 < 1/2 RDL
Nitrate 0.0056 mg/L -10.0056 0.1 < 1/2 RDL
Sulfate 0.0122 mg/L -10.0122 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 7.31 5 99.9mg/L -1208017.31
Fluoride 5.28 5 104mg/L -1208015.28
Nitrate 4.89 5 97.4mg/L -1208014.89
Sulfate 5.16 5 98.6mg/L -1208015.16
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 7.3 5 99.6 0.351mg/L -1208017.3
Fluoride 5.28 5 104 0.025mg/L -1208015.28
Nitrate 4.88 5 97.3 0.0431mg/L -1208014.88
Sulfate 5.16 5 98.8 0.128mg/L -1208015.16
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 7.11 5 104mg/L -1208017.11
Fluoride 5.48 5 107mg/L -1208015.48
Nitrate 8.69 5 101mg/L -1208018.69
Sulfate 6.32 5 102mg/L -1208016.32
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 7.11 5 104 0.0695mg/L -1208017.11
Fluoride 5.48 5 107 0.0317mg/L -1208015.48
Nitrate 8.7 5 101 0.0378mg/L -1208018.7
Sulfate 6.3 5 102 0.238mg/L -1208016.3
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.2 5 104mg/L -1208015.2
Fluoride 5.15 5 103mg/L -1208015.15
Nitrate 5.01 5 100mg/L -1208015.01
Sulfate 5.12 5 102mg/L -1208015.12
Page 21 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
Q15110197 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) -0.002 ug/L -1-0.002 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) -0.02 ug/L -1-0.02 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Mercury (Hg) -0.029 ug/L -1-0.029 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 4
RDL Relative Concentration
Mercury (Hg) -0.024 ug/L -1-0.024 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.96 2 98ug/L -1158511.96
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.91 2 95.6ug/L -1158511.91
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Mercury (Hg) 1.89 2 94.3ug/L -1158511.89
Final QualifierDilMeasuredUnits:Parameter
LCS # 4
% Recovery LCL UCLSpike
Mercury (Hg) 1.9 2 94.8ug/L -1158511.9
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J15100405 -- 2015033922
Mercury (Hg) 0.995 1 101ug/L -1307010.995
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15100405 -- 2015033922
Mercury (Hg) 1 1 102 0.787ug/L -1307011
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J15100406 -- 2015033939
Mercury (Hg) 0.172 1 19.2ug/L -1307010.172
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J15100406 -- 2015033939
Mercury (Hg) 0.167 1 18.7 2.64ug/L -1307010.167
Page 22 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
Q15110197 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J15100543 -- 2015034418
Mercury (Hg) 0.945 1 96.1ug/L -1307010.945
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J15100543 -- 2015034418
Mercury (Hg) 0.995 1 101 5.07ug/L -1307010.995
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J15100544 -- 2015034429
Mercury (Hg) 0.985 1 100ug/L -1307010.985
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J15100544 -- 2015034429
Mercury (Hg) 0.975 1 99 1.01ug/L -1307010.975
Final QualifierDilMeasuredUnits:Parameter
MS # 5
% Recovery LCL UCLSpike
Parent Sample: J15100544 -- 2015034438
Mercury (Hg) 0.968 1 98.5ug/L -1307010.968
Final QualifierDilMeasuredUnits:Parameter
MSD # 5
RPD% Recovery LCL UCLSpike
Parent Sample: J15100544 -- 2015034438
Mercury (Hg) 0.938 1 95.5 3.09ug/L -1307010.938
Final QualifierDilMeasuredUnits:Parameter
MS # 6
% Recovery LCL UCLSpike
Parent Sample: J15100577 -- 2015034580
Mercury (Hg) 0.973 1 98.9ug/L -1307010.973
Final QualifierDilMeasuredUnits:Parameter
MSD # 6
RPD% Recovery LCL UCLSpike
Parent Sample: J15100577 -- 2015034580
Mercury (Hg) 0.953 1 96.9 2.04ug/L -1307010.953
Final QualifierDilMeasuredUnits:Parameter
MS # 7
% Recovery LCL UCLSpike
Parent Sample: J15100536 -- 2015034383
Mercury (Hg) 0.914 1 93.1ug/L -1307010.914
Final QualifierDilMeasuredUnits:Parameter
MSD # 7
RPD% Recovery LCL UCLSpike
Parent Sample: J15100536 -- 2015034383
Mercury (Hg) 0.947 1 96.4 3.48ug/L -1307010.947
Page 23 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
Q15110083 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Barium (Ba) 0.00005 mg/L -10.00005 0.005 < 1/2 RDL
Boron (B) 0.000089 mg/L -10.000089 0.05 < 1/2 RDL
Calcium (Ca) 0.00643 mg/L -10.00643 0.01 > 1/2 RDL
Chromium (Cr) 0.000302 mg/L -10.000302 0.005 < 1/2 RDL
Copper (Cu) 0.000466 mg/L -10.000466 0.005 < 1/2 RDL
Iron (Fe) 0.00073 mg/L -10.00073 0.01 < 1/2 RDL
Magnesium (Mg) -0.000126 mg/L -1-0.000126 0.005 < 1/2 RDL
Manganese (Mn) 0.000002 mg/L -10.000002 0.005 < 1/2 RDL
Nickel (Ni) -0.000065 mg/L -1-0.000065 0.005 < 1/2 RDL
Potassium (K) -0.00435 mg/L -1-0.00435 0.1 < 1/2 RDL
Silver (Ag) -0.00029 mg/L -1-0.00029 0.005 < 1/2 RDL
Sodium (Na) 0.00206 mg/L -10.00206 0.05 < 1/2 RDL
Zinc (Zn) -0.000076 mg/L -1-0.000076 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Barium (Ba) 5.14 5 103mg/L -1208015.14
Boron (B) 5.06 5 101mg/L -1208015.06
Calcium (Ca) 5.07 5 101mg/L -1208015.07
Chromium (Cr) 5.06 5 101mg/L -1208015.06
Copper (Cu) 5.07 5 101mg/L -1208015.07
Iron (Fe) 5 5 99.9mg/L -1208015
Magnesium (Mg) 5.02 5 100mg/L -1208015.02
Manganese (Mn) 5.05 5 101mg/L -1208015.05
Nickel (Ni) 5.09 5 102mg/L -1208015.09
Potassium (K) 5.02 5 100mg/L -1208015.02
Silver (Ag) 0.497 0.5 99.3mg/L -1208010.497
Sodium (Na) 5.06 5 101mg/L -1208015.06
Zinc (Zn) 5.06 5 101mg/L -1208015.06
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J15100577 -- 2015034575
Barium (Ba) 5.11 5 101mg/L -1257515.11
Boron (B) 5.09 5 101mg/L -1257515.09
Calcium (Ca) 113 5 0mg/L -125751#Error
Chromium (Cr) 4.94 5 98.8mg/L -1257514.94
Copper (Cu) 5.02 5 100mg/L -1257515.02
Iron (Fe) 5.66 5 98.7mg/L -1257515.66
Magnesium (Mg) 50.8 5 109mg/L -12575150.8
Manganese (Mn) 4.95 5 98.5mg/L -1257514.95
Page 24 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
Q15110083 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J15100577 -- 2015034575
Nickel (Ni) 4.89 5 97.4mg/L -1257514.89
Potassium (K) 11.3 5 104mg/L -12575111.3
Silver (Ag) 0.491 0.5 98.2mg/L -1257510.491
Sodium (Na) 29.1 5 108mg/L -12575129.1
Zinc (Zn) 4.87 5 97mg/L -1257514.87
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15100577 -- 2015034575
Barium (Ba) 5.1 5 101 0.218mg/L -1257515.1
Boron (B) 5.1 5 101 0.217mg/L -1257515.1
Calcium (Ca) 113 5 0 0mg/L -125751#Error
Chromium (Cr) 4.97 5 99.4 0.626mg/L -1257514.97
Copper (Cu) 5.01 5 100 0.0598mg/L -1257515.01
Iron (Fe) 5.69 5 99.3 0.586mg/L -1257515.69
Magnesium (Mg) 50.9 5 112 2.78mg/L -12575150.9
Manganese (Mn) 4.97 5 99 0.486mg/L -1257514.97
Nickel (Ni) 4.91 5 97.9 0.471mg/L -1257514.91
Potassium (K) 11.3 5 104 0.386mg/L -12575111.3
Silver (Ag) 0.491 0.5 98.4 0.193mg/L -1257510.491
Sodium (Na) 28.9 5 105 2.57mg/L -12575128.9
Zinc (Zn) 4.92 5 97.9 0.923mg/L -1257514.92
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
Q15110088 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Arsenic (As) 0.0736 ug/L -10.0736 1 < 1/2 RDL
Cadmium (Cd) -0.0027 ug/L -1-0.0027 1 < 1/2 RDL
Lead (Pb) -0.0028 ug/L -1-0.0028 1 < 1/2 RDL
Selenium (Se) 0.0145 ug/L -10.0145 1 < 1/2 RDL
Silver (Ag) -0.0012 ug/L -1-0.0012 1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Arsenic (As) 52.1 50 104ug/L -12080152.1
Cadmium (Cd) 50.3 50 101ug/L -12080150.3
Lead (Pb) 50.8 50 102ug/L -12080150.8
Selenium (Se) 51.4 50 103ug/L -12080151.4
Silver (Ag) 49 50 97.9ug/L -12080149
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J15100577 -- 2015034576
Arsenic (As) 54.9 50 107ug/L -12080154.9
Cadmium (Cd) 50.8 50 101ug/L -12080150.8
Lead (Pb) 51 50 102ug/L -12080151
Selenium (Se) 51.8 50 100ug/L -12080151.8
Silver (Ag) 49.1 50 98.2ug/L -12080149.1
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J15100577 -- 2015034576
Arsenic (As) 54.1 50 105 1.59ug/L -12080154.1
Cadmium (Cd) 49.9 50 98.8 1.99ug/L -12080149.9
Lead (Pb) 51.3 50 102 0.489ug/L -12080151.3
Selenium (Se) 51.6 50 99.7 0.42ug/L -12080151.6
Silver (Ag) 48.3 50 96.6 1.66ug/L -12080148.3
Page 26 of 28
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15100577
Q15110084 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -10 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J15100404 -- 2015033911
TDS 2.84mg/L -1214
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J15100404 -- 2015033912
TDS 0.887mg/L -1449
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 99mg/L -11090199
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