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HomeMy WebLinkAbout6004_DukeMcGuireLF1_July2015_2ndSemiAnnual_DIN26333_20151006 McGuire Nuclear Station – Landfill #1 (Unlined) Permit No. 6004 Semiannual Groundwater Monitoring Report July 2015 Sampling Event October 6, 2015 Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring ReportMcGuire Nuclear Station – Landfill #1 (Unlined) Permit No. 6004 July 2015 Sampling EventCONTENTS ii Contents Page Report Verification ......................................................................................................................... i Contents ........................................................................................................................................ ii Section 1 - Background ................................................................................................................. 1 Section 2 - Methods ...................................................................................................................... 3 2.1 Sampling and Analysis Methods .................................................................................... 3 2.2 Statement of Work .......................................................................................................... 3 Section 3 - Results ........................................................................................................................ 5 3.1 Site Groundwater Flow ................................................................................................... 5 3.2 Analytical Results ........................................................................................................... 5 FIGURES 1. Site Location Map 2. Sample Locations 3. Generalized Groundwater Surface Contours – July 2015 TABLES 1. Well Construction Information 2. Groundwater Flow Velocities – July 2015 3. Field Data Parameters 4. Groundwater Field and Analytical Results 5. Field and Analytical Results that Equal or Exceed 15A NCAC 2L Groundwater Quality Standards 6. Surface Water Field and Analytical Results 7. Radiological Analytical Results APPENDICES A. Field Sampling Forms B. Laboratory Report and Chain-of-Custody Forms Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring ReportMcGuire Nuclear Station – Landfill #1 (Unlined) Permit No. 6004 July 2015 Sampling EventSECTION 1 - BACKGROUND 1 Section 1 - Background The McGuire Nuclear Station Landfill #1 (Unlined)1 is located at the Duke Energy Carolinas, LLC (Duke Energy) McGuire Nuclear Station in Mecklenburg County, North Carolina. The landfill is closed and no longer accepts waste. The landfill and nearby area are depicted on Figure 1. The approximate limit of waste is shown on Figure 2. The landfill is located south of NC Highway 73, east of the Catawba River, and to the west of Cashion Road. Cashion Road runs along a topographic divide with topography sloping away from Cashion Road to the northwest and to the southeast. Surface water to the northwest of Cashion Road drains towards the Catawba River. There are two surface water drainage features adjacent to the landfill. The surface water drainage feature located to the north of the landfill contains an unnamed perennial stream that drains to the northwest towards another perennial unnamed stream that flows to the Catawba River. The surface water drainage feature located to the south and west of the landfill also drains to an unnamed stream that flows to the Catawba River. As described in the Sampling and Analysis Plan2 (SAP), the monitoring system at the landfill consists of the following: Monitoring Wells:MW-1MW-1D MW-2A MW-2D MW-3 MW-3D MW-4 MW-4D MW-11 MW-11D MW-12 MW-12D MW-4R MW-4DR Surface Water Sample Locations:SW-1 The monitoring wells and the surface water sample location are shown on Figure 2. The wells were installed as well pairs with one shallow well and one deeper well adjacent to each other. The well with the “D” designation is the deeper well in each well pair. The shallow wells are 1 In response to the North Carolina Division of Public Health, Radiation Protection Section, November 17, 2006, letter to Duke Energy, LLC, Duke Energy offered to indicate the McGuire Nuclear Station Landfill #1 as (Unlined) in reports. 2 McGuire Nuclear Station Landfill #1, Permit Number 60-04, Ground-Water Monitoring Program Sampling and Analysis Plan (SAP), September 14, 1996, Revised, November 24, 1997, March 9, 2001. Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring ReportMcGuire Nuclear Station – Landfill #1 (Unlined) Permit No. 6004 July 2015 Sampling EventSECTION 1 - BACKGROUND 2 screened to intercept the water table. The deep wells are constructed so that the bottom of the screen is located in residual material just above auger refusal. Monitoring wells MW-1 and MW-1D are located upgradient of the landfill. Monitoring wells MW-4R and MW-4DR are not included in the SAP. These wells were installed in December 2013 as replacement wells for MW-4 and MW-4D, respectively. Monitoring wells MW-4 and MW-4D are approximately 15 feet outside of the waste boundary. The replacement wells were installed in the vicinity of MW-4 and MW-4D and are located near the review boundary. Replacement monitoring well MW-4R was installed with the well screen from 43 feet to 28 feet below ground surface to intercept the water table. Monitoring well MW-4DR was installed with the well screen from 87.6 feet to 72.6 feet below ground surface. Table 1 presents well construction information for the landfill monitoring wells. Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring ReportMcGuire Nuclear Station – Landfill #1 (Unlined) Permit No. 6004 July 2015 Sampling EventSECTION 2 - METHODS 3 Section 2 - Methods 2.1 Sampling and Analysis Methods The collection of samples and documentation of sampling was performed by Duke Energy personnel (Field Certification #5193) according to the North Carolina Solid Waste Management Guidelines. Copies of the field sampling forms are included in Appendix A. The parameters and constituents reported were selected by Duke Energy and the North Carolina Department of Environmental Quality (NCDEQ) Division of Solid Waste and were analyzed by TestAmerica Laboratories, Inc. (North Carolina Laboratory Certification #358) and the Duke Energy Analytical Laboratory (North Carolina Laboratory Certification #248). The groundwater and surface water samples were analyzed for the following constituents in accordance with the SAP:  Barium, chromium, and silver using US Environmental Protection Agency (EPA) Method 200.7  Arsenic, cadmium, lead, and selenium using Solid Waste (SW) Method 6020A  Mercury using EPA Method 245.1  Sulfate using EPA Method 300.0  Volatile organic compounds (VOCs) using SW846 Method 8260B In addition, the following analyses were performed in accordance with the requirements of the Radioactive Materials License No. 060-0379-7 issued by the North Carolina Department of Health and Human Services Radiation Protection Section:  Gross alpha radioactivity using EPA Method 900  Gross beta radioactivity using EPA Method 900  Tritium using EPA Method 906.0 Modified  Gamma radioactivity for select isotopes 2.2 Statement of Work HDR completed the following tasks:  Received field sampling information provided by Duke Energy (performed by Duke Energy personnel) for monitoring wells MW-1, MW-1D, MW-2A, MW-2D, MW-3, MW-3D, MW-4, MW-4R, MW-4D, MW-4DR, MW-11, MW-11D, and MW-12D. There was insufficient volume in monitoring well MW-12 to collect a groundwater sample. Data was also received for surface water sample location SW-1. The samples were collected on Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring ReportMcGuire Nuclear Station – Landfill #1 (Unlined) Permit No. 6004 July 2015 Sampling EventSECTION 2 - METHODS 4 July 30, 2015, and HDR received the data on August 26 and 28, 2015. The field sampling forms are included in Appendix A.  Reviewed the laboratory analytical results for the samples. The Electronic Data Deliverable (EDD) provided by Duke Energy was adapted to conform to the format requirements of the NCDEQ EDD template. HDR added an italicized J data qualifier (J) to indicate a measured concentration that is equal to or greater than the laboratory’s method reporting limit (MRL) but is less than the Solid Waste Section Limit3 (SWSL). A copy of the original EDD is retained in HDR’s files.  Developed a generalized groundwater surface contour map using map data and groundwater elevation data supplied by Duke Energy. Calculated groundwater flow velocities based on groundwater surface contours.  Prepared and submitted this Semiannual Groundwater Monitoring Report to Duke Energy. 3 The Solid Waste Section Limit (SWSL) is defined by NCDEQ as the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy. The SWSL is the concentration below which reported results must be qualified as estimated. NCDEQ Division of Waste Management Memorandum dated February 23, 2007. Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring ReportMcGuire Nuclear Station – Landfill #1 (Unlined) Permit No. 6004 July 2015 Sampling EventSECTION 3 - RESULTS 5 Section 3 - Results 3.1 Site Groundwater Flow Generalized groundwater surface contours and groundwater flow direction arrows for the site are shown on Figure 3. These contours were developed using groundwater elevations measured at the shallow wells on the date of sampling. Calculated flow velocities are presented in Table 2. Groundwater flow in the area of the landfill is generally from the southeast near MW-1/MW-1D and Cashion Road, toward the northwest, toward MW-3/MW-3D, MW-4/MW-4D, and MW-4R/MW-4DR. 3.2 Analytical Results A summary of the field data is presented in Table 3. The field and analytical results of groundwater samples collected from the monitoring wells are summarized in Table 4. The analytical results for these samples are compared to the groundwater standards found in Title 15A NCAC 02L .0202 (g) (2L Standards). Concentrations with values that attain or exceed the 2L Standards are noted on Table 4 by bold font. A summary of the field and analytical results that attain or exceed the 2L Standards and a preliminary analysis of the cause and significance of the exceedances are presented in Table 5. Surface water sample location SW-1 is located on an unnamed stream. The unnamed stream is a tributary to the Catawba River which is classified by the NCDEQ Division of Water Quality as Class WS-IV water at its confluence with the unnamed stream. As a result, the field and analytical results from this location are compared to Title 15A, North Carolina Administrative Code (NCAC), Subchapter 2B Standards (2B Standards) for Class WS-IV water. The field and analytical results of surface water sampling are summarized in Table 6. The MDL was greater than the respective 2L Standard for the following constituents:  1,2,3-Trichloropropane  1,2-Dibromo-3-chloropropane  1,2-Dibromoethane (EDB)  Vinyl chloride The MDL was greater than the respective 2B Standard for the following constituents:  Silver, dissolved Duke Energy Carolinas, LLC | Semiannual Groundwater Monitoring ReportMcGuire Nuclear Station – Landfill #1 (Unlined) Permit No. 6004 July 2015 Sampling EventSECTION 3 - RESULTS 6 The MDLs for the listed constituents were all below their corresponding SWSLs as required by the February 23, 2007, NCDEQ memo4. With the exception of the vinyl chloride concentration in the sample collected from monitoring well MW-4D, these constituents were not detected above the MDL in the analyzed samples and are not considered to exceed their respective 2L or 2B Standards. Analytical results with values that equal or are greater than the SWSLs are noted in Table 4 by gray cells. The results of the radiological analysis are presented in Table 7. A copy of this report has been submitted to the North Carolina Department of Health and Human Services Radiation Protection Section for reference. HDR did not evaluate this data. Select samples were diluted, as is normal laboratory practice, to bring samples within the calibrated range of the analysis. Specifics regarding the samples that were diluted, including the dilution amount, are reported in the EDD. The laboratory reports and chain-of-custody forms can be found in Appendix B. 4 The Solid Waste Section Limit (SWSL) is defined by NCDEQ as the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy. The SWSL is the concentration below which reported results must be qualified as estimated. NCDEQ Division of Waste Management Memorandum dated February 23, 2007. Figures Tables Ta b l e 1 - W e l l C o n s t r u c t i o n I n f o r m a t i o n Du k e E n e r g y C a r o l i n a s , L L C / M c G u i r e N u c l e a r S t a t i o n La n d f i l l # 1 ( U n l i n e d ) - P e r m i t N o . 6 0 0 4 La t i t u d e L o n g i t u d e MW - 1 7 / 1 8 / 1 9 8 9 3 5 . 4 1 1 4 5 5 7 - 8 0 . 9 4 7 6 0 7 8 7 3 0 . 2 3 7 2 9 . 5 8 0 . 6 5 7 0 0 . 0 4 3 0 . 1 9 6 8 . 5 5 5 8 . 5 5 5 8 . 5 5 - 6 8 . 5 5 S a p r o l i t e 2 P V C MW - 1 D 7 / 2 0 / 1 9 8 9 3 5 . 4 1 1 4 7 3 7 - 8 0 . 9 4 7 6 0 4 7 7 3 0 . 6 1 7 2 9 . 7 5 0 . 8 6 6 9 9 . 5 1 3 1 . 1 0 8 8 . 2 2 7 8 . 2 2 7 8 . 2 2 - 8 8 . 2 2 S a p r o l i t e 2 P V C MW - 2 A 7 / 2 1 / 1 9 8 9 3 5 . 4 1 3 0 6 3 9 - 8 0 . 9 4 9 0 5 1 7 7 3 9 . 6 7 7 3 6 . 9 6 2 . 7 1 6 8 6 . 3 8 5 3 . 2 9 7 7 . 5 7 6 7 . 5 7 6 7 . 5 7 - 7 7 . 5 7 S a p r o l i t e 2 P V C MW - 2 D 7 / 2 0 / 1 9 8 9 3 5 . 4 1 3 0 8 0 8 - 8 0 . 9 4 9 0 9 2 0 7 4 0 . 7 7 7 3 7 . 4 1 3 . 3 6 6 8 5 . 5 0 5 5 . 2 7 1 0 8 . 8 2 9 8 . 8 2 9 8 . 8 2 - 1 0 8 . 8 2 S a p r o l i t e 2 P V C MW - 3 7 / 1 0 / 1 9 8 9 3 5 . 4 1 4 0 7 0 5 - 8 0 . 9 5 0 4 8 6 8 7 2 8 . 4 3 7 2 4 . 9 8 3 . 4 5 6 7 0 . 2 7 5 8 . 1 6 7 3 . 6 4 6 3 . 6 4 6 3 . 6 4 - 7 3 . 6 4 S a p r o l i t e 2 P V C MW - 3 D 7 / 1 0 / 1 9 8 9 3 5 . 4 1 4 0 6 8 1 - 8 0 . 9 5 0 5 0 3 8 7 2 8 . 3 9 7 2 4 . 9 8 3 . 4 1 6 7 0 . 2 7 5 8 . 1 2 9 0 . 1 9 8 0 . 1 9 8 0 . 1 9 - 9 0 . 1 9 S a p r o l i t e 2 P V C MW - 4 7 / 6 / 1 9 8 9 3 5 . 4 1 3 4 8 8 9 - 8 0 . 9 5 1 1 5 3 3 7 4 1 . 1 3 7 3 8 . 4 0 2 . 7 3 6 7 5 . 4 5 6 5 . 6 8 7 4 . 1 5 6 4 . 1 5 6 4 . 1 5 - 7 4 . 1 5 S a p r o l i t e 2 P V C MW - 4 D 7 / 6 / 1 9 8 9 3 5 . 4 1 3 4 7 9 1 - 8 0 . 9 5 1 1 6 6 5 7 4 0 . 5 8 7 3 8 . 2 5 2 . 3 3 6 7 4 . 3 8 6 6 . 2 0 1 0 2 . 2 4 9 2 . 2 4 9 2 . 2 4 - 1 0 2 . 2 4 S a p r o l i t e 2 P V C MW - 1 1 1 2 / 1 5 / 2 0 0 4 3 5 . 4 1 1 3 8 2 9 - 8 0 . 9 5 0 4 9 7 9 7 2 2 . 6 0 7 2 0 . 1 0 2 . 5 0 6 8 8 . 8 3 3 3 . 7 7 3 8 . 4 5 2 3 . 4 5 2 3 . 4 5 - 3 8 . 4 5 S a p r o l i t e 2 P V C MW - 1 1 D 1 2 / 1 5 / 2 0 0 4 3 5 . 4 1 1 3 8 8 5 - 8 0 . 9 5 0 4 7 2 5 7 2 3 . 1 4 7 2 0 . 8 4 2 . 3 0 6 8 8 . 7 5 3 4 . 3 9 1 0 1 . 5 5 9 1 . 5 5 9 1 . 5 5 - 1 0 1 . 5 5 S a p r o l i t e 2 P V C MW - 1 2 1 2 / 1 5 / 2 0 0 4 3 5 . 4 1 1 0 0 4 7 - 8 0 . 9 4 9 1 7 2 3 7 2 4 . 8 1 7 2 2 . 2 1 2 . 6 0 6 9 6 . 6 9 2 8 . 1 2 2 9 . 4 9 1 4 . 4 9 1 4 . 4 9 - 2 9 . 4 9 S a p r o l i t e 2 P V C MW - 1 2 D 1 2 / 1 5 / 2 0 0 4 3 5 . 4 1 1 0 1 4 7 - 8 0 . 9 4 9 2 0 9 3 7 2 4 . 7 7 7 2 2 . 2 1 2 . 5 6 6 9 5 . 7 9 2 8 . 9 8 6 8 . 4 2 5 8 . 4 2 5 8 . 4 2 - 6 8 . 4 2 P W R 2 P V C MW - 4 R 1 2 / 4 / 2 0 1 3 3 5 . 4 1 3 4 1 2 3 - 8 0 . 9 5 1 6 1 0 5 7 1 3 . 8 7 7 1 1 . 1 5 2 . 7 2 6 7 3 . 6 0 4 0 . 2 7 4 5 . 7 3 3 0 . 7 2 3 0 . 7 2 - 4 5 . 7 3 S a p r o l i t e 2 P V C MW - 4 D R 1 2 / 4 / 2 0 1 3 3 5 . 4 1 3 3 9 6 9 - 8 0 . 9 5 1 6 2 0 5 7 1 3 . 7 5 7 1 1 . 1 5 2 . 6 0 6 7 2 . 9 9 4 0 . 7 6 9 0 . 4 0 7 5 . 2 0 7 5 . 2 0 - 9 0 . 4 0 S a p r o l i t e 2 P V C No t e s : 1 . T O C i n d i c a t e s t o p o f c a s i n g . 2 . f t . i n d i c a t e s f e e t . 3 . i n . i n d i c a t e s i n c h e s n o m i n a l d i a m e t e r . 4 . P V C i n d i c a t e s p o l y v i n y l c h l o r i d e . 5 . P W R i n d i c a t e s p a r t i a l l y w e a t h e r e d r o c k . 6 . H o r i z o n t a l d a t u m N A D 8 3 . 7 . V e r t i c a l d a t u m i s N A V D 8 8 . 8 . D e p t h t o g r o u n d w a t e r g a u g e d o n J u l y 3 0 , 2 0 1 5 . 9 . I n f o r m a t i o n p r o v i d e d b y D u k e E n e r g y . 10 . T o t a l w e l l d e p t h s f r o m 2 0 1 5 w e l l d e p t h c o n f i r m a t i o n . 11 . T o p o f C a s i n g a n d G r o u n d S u r f a c e E l e v e t i o n s f r o m J a n u a r y 2 0 1 5 r e - s u r v e y b y P r o v i d e n c e L a n d G r o u p . 12 . O t h e r i n f o r m a t i o n p r o v i d e d b y D u k e E n e r g y o n A u g u s t 2 6 , 2 0 1 5 Sc r e e n e d I n t e r v a l be l o w T O C (f t . ) Casing TypeWell Diameter (in.)Geology of Screened Interval We l l S t i c k - u p He i g h t A b o v e Gr o u n d S u r f a c e (f t . ) Gr o u n d w a t e r Ele v a t i o n (ft . ) De p t h t o W a t e r be l o w T O C (ft . ) To t a l W e l l De p t h b e l o w TO C (f t . ) De p t h t o T o p o f Sc r e e n f r o m T O C (ft . ) Co o r d i n a t e s We l l I D We l l In s t a l l a t i o n Da t e W e l l T O C Ele v a t i o n ( f t . ) Gr o u n d S u r f a c e Ele v a t i o n (f t . ) Page  1  of  1 Ta b l e 2 - G r o u n d w a t e r F l o w V e l o c i t i e s Du k e E n e r g y C a r o l i n a s , L L C / M c G u i r e N u c l e a r S t a t i o n La n d f i l l # 1 ( U n l i n e d ) - P e r m i t N o . 6 0 0 4 MW - 1 70 0 69 8 63 0 . 0 3 0 . 4 1 0. 2 5 9 0.05 MW - 1 D 70 0 69 8 63 0 . 0 2 0 . 4 1 0. 2 5 9 0.04 MW - 2 A 68 6 68 4 78 0 . 0 3 0 . 4 1 0. 2 5 9 0.04 MW - 2 D 68 6 68 4 78 0 . 0 3 0 . 4 1 0. 2 5 9 0.04 MW - 3 67 2 67 0 69 0 . 0 2 0 . 4 1 0. 2 5 9 0.04 MW - 3 D 67 2 67 0 69 0 . 0 2 0 . 4 1 0. 2 5 9 0.04 MW - 4 67 6 67 4 72 0 . 0 3 0 . 4 1 0. 2 5 9 0.04 MW - 4 D 67 6 67 4 72 0 . 0 3 0 . 4 1 0. 2 5 9 0.04 MW - 1 1 69 0 68 8 86 0 . 0 2 0 . 4 1 0. 2 5 9 0.04 MW - 1 1 D 69 0 68 8 86 0 . 0 2 0 . 4 1 0. 2 5 9 0.04 MW - 1 2 69 8 69 6 10 0 0 . 0 2 0 . 4 1 0. 2 5 9 0.03 MW - 1 2 D 69 8 69 6 10 0 0 . 0 2 0 . 3 1 0. 0 0 5 1.24 MW - 4 R 67 6 67 4 12 2 0 . 0 2 0 . 4 1 0. 2 5 9 0.03 MW - 4 D R 67 6 67 3 12 2 0 . 0 2 0 . 4 1 0. 2 5 9 0.04 No t e s : 1 . L i n e a r d i s t a n c e m e a s u r e d t h r o u g h m o n i t o r i n g w e l l s i s g e n e r a l l y p e r p e n d i c u l a r t o g r o u n d w a t e r c o n t o u r s . 2 . A t m o n i t o r i n g w e l l l o c a t i o n s w h e r e d o w n g r a d i e n t c o n t o u r s a r e n o t p r e s e n t , t h e g r o u n d w a t e r e l e v a t i o n a t t h e m o n i t o r i n g w e l l i s u s e d a s t h e d o w n g r a d i e n t g r o u n d w a t e r e l e v a t i o n . 3 . A t m o n i t o r i n g w e l l l o c a t i o n s w h e r e u p g r a d i e n t c o n t o u r s a r e n o t p r e s e n t , t h e g r o u n d w a t e r e l e v a t i o n a t t h e m o n i t o r i n g w e l l i s u s e d a s t h e u p g r a d i e n t g r o u n d w a t e r e l e v a t i o n . 4 . M o n i t o r i n g w e l l s a r e n o t l i s t e d w h e r e i n s u f f i c i e n t g r o u n d w a t e r c o n t o u r i n f o r m a t i o n i s a v a i l a b l e t o c a l c u l a t e v e l o c i t y . 5 . H y d r a u l i c g r a d i e n t s a n d g r o u n d w a t e r v e l o c i t i e s a r e a p p r o x i m a t e . 6 . H y d r a u l i c c o n d u c t i v i t y p r e s e n t e d i s t h e g e o m e t r i c m e a n o f t h e c o n d u c t i v i t y d a t a f o r t h e a l l u v i u m / s o i l / s a p r o l i t e a n d P W R h y d r o s t r a t i g r a p h i c l a y e r i n t h e H D R C o n d u c t i v i t y D a t a b a s e ( u n p u b l i s h e d d a t a f r o m P i e d m o n t C a r o l i n a s i t e s w i t h f o l i a t e d / l a y e r e d b e d r o c k ) . 7 . E f f e c t i v e p o r o s i t y p r e s e n t e d i s t h e m e a n v a l u e o f t h e a l l u v i u m / s o i l / s a p r o l i t e a n d P W R h y d r o s t r a t i g r a p h i c l a y e r e s t i m a t e d f r o m s o i l t e s t i n g u s i n g F e t t e r / B e a r D i a g r a m s . 8 . H y d r a u l i c g r a d i e n t a n d g r o u n d w a t e r v e l o c i t i e s a r e b a s e d o n J u l y 2 0 1 5 m e a s u r e d w a t e r e l e v a t i o n s . Ef f e c t i v e Po r o s i t y (% / 1 0 0 ) Gr o u n d w a t e r Ve l o c i t y (f t / d a y ) We l l I D U p g r a d i e n t Gr o u n d w a t e r Co n t o u r El e v a t i o n (f t ) D o w n g r a d i e n t Gr o u n d w a t e r Co n t o u r E l e v a t i o n (f t ) Li n e a r Dis t a n c e Be t w e e n Co n t o u r s th r o u g h W e l l (f t ) Hy d r a u l i c Gr a d i e n t (f t / f t ) Hy d r a u l i c Co n d u c t i v i t y (f t / d a y ) Page 1 of 1 Ta b l e 3 - F i e l d D a t a P a r a m e t e r s Du k e E n e r g y C a r o l i n a s , L L C / M c G u i r e N u c l e a r S t a t i o n La n d f i l l # 1 ( U n l i n e d ) - P e r m i t N o . 6 0 0 4 7/ 3 0 / 2 0 1 5 M W - 1 6 8 . 5 5 3 0 . 1 9 7 0 0 . 0 4 N o r m a l N o n e C P N / A 6 . 2 6 3 2 . 5 0 N O 1 6 . 3 3 1 0 8 6. 1 1 0 . 0 2 3 1 0 . 4 3 7/ 3 0 / 2 0 1 5 M W - 1 D 8 8 . 2 2 3 1 . 1 0 6 9 9 . 5 1 N o r m a l N o n e C P N / A 9 . 3 2 2 8 . 5 0 N O 1 6 . 2 5 9 7 6. 1 2 . 0 2 3 4 0 . 1 6 7/ 3 0 / 2 0 1 5 M W - 2 A 7 7 . 5 7 5 3 . 2 9 6 8 6 . 3 8 N o r m a l N o n e C P N / A 3 . 9 6 1 2 . 0 0 N O 1 7 . 0 7 9 6 6. 5 1 . 4 3 6 6 5 . 6 6 7/ 3 0 / 2 0 1 5 M W - 2 D 1 0 8 . 8 2 5 5 . 2 7 6 8 5 . 5 0 N o r m a l N o n e C P N / A 8 . 7 3 2 7 . 0 0 N O 1 6 . 9 0 6 2 6. 9 2 . 1 3 3 5 9 . 1 5 7/ 3 0 / 2 0 1 5 M W - 3 7 3 . 6 4 5 8 . 1 6 6 7 0 . 2 7 N o r m a l N o n e C P N / A 2 . 5 2 1 1 . 2 5 N O 1 5 . 5 9 7 5 6. 3 1 . 3 4 1 0 5 . 7 2 7/ 3 0 / 2 0 1 5 M W - 3 D 9 0 . 1 9 5 8 . 1 2 6 7 0 . 2 7 N o r m a l N o n e C P N / A 5 . 2 3 2 1 . 0 0 N O 1 5 . 7 6 1 1 4 6. 5 1 . 6 3 5 7 3 . 0 8 7/ 3 0 / 2 0 1 5 M W - 4 7 4 . 1 5 6 5 . 6 8 6 7 5 . 4 5 N o r m a l N o n e E O P N / A 1 . 3 8 0 . 5 5 N / A 1 6 . 4 1 1 5 2 5. 6 4 . 1 4 5 1 1 . 0 9 7/ 3 0 / 2 0 1 5 M W - 4 D 1 0 2 . 2 4 6 6 . 2 0 6 7 4 . 3 8 N o r m a l N o n e C P N / A 5 . 8 8 2 4 . 0 0 N O 1 6 . 0 6 1 7 4 6. 3 1 . 4 2 3 8 0 . 2 6 7/ 3 0 / 2 0 1 5 M W - 1 1 3 8 . 4 5 3 3 . 7 7 6 8 8 . 8 3 N o r m a l N o n e C P N / A 0 . 7 6 2 . 0 0 N O 1 8 . 6 3 2 0 5. 1 8 . 1 4 3 3 5 . 3 0 7/ 3 0 / 2 0 1 5 M W - 1 1 D 1 0 1 . 5 5 3 4 . 3 9 6 8 8 . 7 5 N o r m a l N o n e C P N / A 1 0 . 9 5 2 4 . 2 5 N O 1 5 . 4 9 3 3 5. 8 5 . 3 4 0 7 6 . 5 3 7/ 3 0 / 2 0 1 5 M W - 1 2 2 9 . 4 9 2 8 . 1 2 6 9 6 . 6 9 N S N S N S N S 0 . 2 2 N S N S N S NS NS N S N S N S 7/ 3 0 / 2 0 1 5 M W - 1 2 D 6 8 . 4 2 2 8 . 9 8 6 9 5 . 7 9 N o r m a l N o n e C P N / A 6 . 4 3 1 5 . 0 0 N O 1 5 . 2 4 7 7 6. 3 7 . 1 3 7 4 7 . 6 9 7/ 3 0 / 2 0 1 5 S W - 1 N / A N / A N / A N o r m a l N o n e N / A N / A N / A N / A N / A 2 5 . 8 7 1 2 4 7. 5 1 9 . 6 1 7 1 6 . 9 7 7/ 3 0 / 2 0 1 5 M W - 4 R 4 5 . 7 3 4 0 . 2 7 6 7 3 . 6 0 N o r m a l N o n e C P N / A 0 . 8 9 3 . 0 0 N O 1 6 . 5 8 1 1 7 6. 0 8 . 9 3 6 9 5 . 1 8 7/ 3 0 / 2 0 1 5 M W - 4 D R 9 0 . 4 0 4 0 . 7 6 6 7 2 . 9 9 N o r m a l N o n e C P N / A 8 . 1 0 2 0 . 0 0 N O 1 5 . 5 8 1 2 9 6. 8 3 . 2 3 5 1 4 . 9 4 No t e s : 1 . P u r g e M e t h o d s ; L F = L o w F l o w , C P = C o n v e n t i o n a l P u r g e ( 3 - 5 w e l l v o l u m e s ) , N P = N o P u r g e ( H y d r a S l e e v e ) , E O P = E q u i p m e n t O n l y P u r g e . P u m p r a t e a p p l i c a b l e t o L F p u r g i n g o n l y . 2 . F i e l d s a m p l i n g p e r f o r m e d b y D u k e E n e r g y C a r o l i n a s , L L C p e r s o n n e l . 3 . E V A C i n d i c a t e s w h e t h e r t h e w a t e r l e v e l i n t h e w e l l w a s d r a w n d o w n t o t h e l e v e l o f t h e p u m p d u r i n g p u r g i n g . 4 . µ Լ /c m i n d i c a t e s m i c r o m h o s p e r c e n t i m e t e r . 5 . S U i n d i c a t e s S t a n d a r d U n i t s . 6 . N T U i n d i c a t e s N e p h e l o m e t r i c T u r b i d i t y U n i t s . 7 . m V - N H E i n d i c a t e s m i l l i v o l t s - N o r m a l H y d r o g e n E l e c t r o d e . 8 . m g / L i n d i c a t e s m i l l i g r a m s p e r l i t e r . 9 . N / A i n d i c a t e s n o t a p p l i c a b l e . 10 . N S i n d i c a t e s n o s a m p l e w a s c o l l e c t e d . T h e r e w a s i n s u f f i c i e n t v o l u m e i n M W - 1 2 t o c o l l e c t a g r o u n d w a t e r s a m p l e . 11 . I n f o r m a t i o n p r o v i d e d b y T i m H u n s u c k e r o f D u k e E n e r g y C a r o l i n a s , L L C o n A u g u s t 2 6 , 2 0 1 5 . DO (mg/L) OD O R PU R G E ME T H O D PU M P RA T E (m L / m i n ) WE L L VO L U M E (g a l ) EV A C VO L U M E (g a l ) EV A C (y e s / n o ) TE M P (d e g C ) SP E C I F I C CO N D U C T A N C E (µ Լ /c m ) pH (S U ) TURBIDITY (NTU)ORP (mV-NHE) AP P E A R A N C E DA T E S A M P L E I D WE L L DE P T H (f e e t ) DE P T H T O WA T E R (f e e t ) WA T E R EL E V . (f e e t ) Page 1 of 1 Ta b l e 4 - G r o u n d w a t e r F i e l d a n d A n a l y t i c a l R e s u l t s Du k e E n e r g y C a r o l i n a s , L L C / M c G u i r e N u c l e a r S t a t i o n La n d f i l l # 1 ( U n l i n e d ) - P e r m i t N o . 6 0 0 4 Fie l d p H 32 0 S U 5 1 9 3 - N E 6 . 5 - 8 . 5 6 . 5 - 8 . 5 * Sp e c i f i c C o n d u c t a n c e 3 2 3 µ Լ /cm 5 1 9 3 -N E N E N E Te m p e r a t u r e 3 2 5 ° C 5 1 9 3 -N E N E N E To p o f C a s i n g 32 8 f e e t - -N E N E N E De p t h t o W a t e r 3 1 8 f e e t - -N E N E N E Wa t e r E l e v a t i o n 4 2 7 f e e t - -N E N E N E We l l D e p t h 4 1 1 f e e t - -N E N E N E Ar s e n i c 1 4 µg/ L 24 8 0 . 2 4 2 J 0.1 6 7 J 0.1 1 4 J 0. 0 7 8 U 0 . 1 0 1 J 0. 0 7 8 1 0 10 10 Ba r i u m 15 µg/ L 24 8 22 3 99 . 4 J' 27 . 3 J' 14 . 4 J' 41 J' 0.1 1 0 0 7 0 0 2,000 Ca d m i u m 34 µg/ L 24 8 0. 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 1 2 5 Ch r o m i u m 51 µg/ L 24 8 0.5 U 0. 5 U 0 . 7 1 4 J 0. 5 U 0. 5 U 0 . 5 1 0 10 100 Le a d 13 1 µg/ L 24 8 0 . 0 9 6 7 J 0.0 6 5 U 0 . 3 8 8 J 0. 0 6 5 U 1. 6 J' 0. 0 6 5 1 0 15 15 Me r c u r y 1 3 2 µg/ L 24 8 0. 0 0 6 U 0 . 0 0 6 U 0 . 0 0 6 U 0 . 0 0 6 U 0 . 0 0 6 U 0 . 0 0 6 0 . 2 1 2 Se l e n i u m 18 3 µg/ L 24 8 0. 0 9 2 U 0 . 0 9 2 U 0 . 0 9 2 U 0 . 0 9 2 U 0 . 0 9 2 U 0 . 0 9 2 1 0 20 50 Si l v e r 18 4 µg/ L 24 8 0.7 U 0. 7 U 0.7 U 0. 7 U 0. 7 U 0 . 7 1 0 20 100* Su l f a t e 31 5 µg/ L 24 8 27 3 J' 30 7 J' 59 7 J' 32 0 J' 42 1 J' 18 2 5 0 , 0 0 0 2 5 0 , 0 0 0 2 5 0 , 0 0 0 * 1,1 - D i c h l o r o e t h a n e 7 5 µg/ L 3 5 8 0.2 4 U 0 . 2 4 U 0 . 2 4 U 0 . 2 4 U 0 . 2 4 U 0 . 2 4 5 6 NE Be n z e n e 16 µg/ L 3 5 8 0.2 U 0. 2 U 0.2 U 0. 2 U 0. 2 U 0 . 2 1 1 5 cis - 1 , 2 - D i c h l o r o e t h y l e n e 1 3 7 µg/ L 3 5 8 0.2 1 U 0 . 2 1 U 0 . 2 1 U 0 . 2 1 U 0 . 2 1 U 0 . 2 1 5 70 70 Me t h y l e n e c h l o r i d e 1 4 0 µg/ L 3 5 8 0.2 2 U 0 . 2 2 U 0 . 2 2 U 0 . 2 2 U 0 . 2 2 U 0 . 2 2 1 5 NE Te t r a c h l o r o e t h y l e n e 1 9 6 µg/ L 3 5 8 0.1 4 U 0 . 1 4 U 0 . 1 4 U 0 . 1 4 U 0 . 1 4 U 0 . 1 4 1 0.7 5 To l u e n e 79 µg/ L 3 5 8 0.1 7 U 0 . 1 7 U 0 . 1 7 U 0 . 1 7 U 0 . 1 7 U 0 . 1 7 1 60 0 1,000 tr a n s - 1 , 2 - D i c h l o r o e t h y l e n e 2 1 1 µg/ L 3 5 8 0.2 3 U 0 . 2 3 U 0 . 2 3 U 0 . 2 3 U 0 . 2 3 U 0 . 2 3 5 10 0 100 Tr i c h l o r o e t h y l e n e 1 9 2 µg/ L 3 5 8 0.2 U 0. 2 U 0.2 U 0. 2 U 0.2 U 0 . 2 1 3 5 Tr i c h l o r o f l u o r o m e t h a n e 2 0 3 µg/ L 35 8 0.2 1 U 0 . 2 1 U 0 . 2 1 U 0 . 2 1 U 0 . 9 5 8 J 0. 2 1 1 2,0 0 0 NE Vin y l c h l o r i d e 20 1 µg/ L 3 5 8 0.1 8 U 0 . 1 8 U 0 . 1 8 U 0 . 1 8 U 0 . 1 8 U 0 . 1 8 1 0. 0 3 2 Xy l e n e ( t o t a l ) 34 6 µ g / L 3 5 8 0.5 8 U 0 . 5 8 U 0 . 5 8 U 0 . 5 8 U 0 . 5 8 U 0 . 5 8 5 50 0 10,000 No t e s : 1 . C o n c e n t r a t i o n s p r e s e n t e d i n m i c r o g r a m s p e r l i t e r ( µ g / L ) . 2 . S U i n d i c a t e s S t a n d a r d U n i t s . 3 . µ Լ /c m i n d i c a t e s m i c r o m h o s p e r c e n t i m e t e r . 4 . S W S I D i s t h e S o l i d W a s t e S e c t i o n I d e n t i f i c a t i o n N u m b e r . 5 . M D L i s t h e l a b o r a t o r y m e t h o d d e t e c t i o n l i m i t . T h e M D L v a l u e s p r e s e n t e d a r e f o r s a m p l e s n o t d i l u t e d b y t h e l a b o r a t o r y d u r i n g a n a l y s i s . 6 . S W S L i s t h e S o l i d W a s t e S e c t i o n L i m i t . N C D E Q d e f i n e s t h e S W S L a s t h e l o w e s t a m o u n t o f a n a l y t e i n a s a m p l e t h a t c a n b e q u a n t i t a t i v e l y d e t e r m i n e d w i t h s u i t a b l e p r e c i s i o n a n d a c c u r a c y . 7 . 1 5 A N C A C 2 L S t a n d a r d r e f e r s t o C l a s s G A S t a n d a r d s a s f o u n d i n 1 5 A N C A C 0 2 L . 0 2 0 2 G r o u n d w a t e r Q u a l i t y S t a n d a r d s , l a s t a m e n d e d o n A p r i l 1 , 2 0 1 3 . 8 . M C L i s t h e F e d e r a l M a x i m u m C o n t a m i n a n t L e v e l a s f o u n d i n 4 0 C F R , S u b p a r t G , § 1 4 1 . 6 2 . 9 . * C o n c e n t r a t i o n l i s t e d i s a s e c o n d a r y m a x i m u m c o n t a m i n a n t l e v e l ( S M C L ) . S M C L s a r e e s t a b l i s h e d b y E P A i n t h e N a t i o n a l S e c o n d a r y D r i n k i n g W a t e r R e g u l a t i o n s a s f o u n d i n 4 0 C F R § 1 4 3 . 3 . 10 . N E i n d i c a t e s n o t e s t a b l i s h e d . N A i n d i c a t e s n o t a n a l y z e d . N S i n d i c a t e s n o s a m p l e w a s c o l l e c t e d . B l a n k c e l l s i n d i c a t e t h a t t h e r e i s n o i n f o r m a t i o n r e l e v a n t t o t h e r e s p e c t i v e r o w . 11 . G r a y e d v a l u e s i n d i c a t e v a l u e s t h a t e q u a l o r a r e g r e a t e r t h a n t h e S W S L . 12 . B o l d v a l u e s i n d i c a t e v a l u e s t h a t a t t a i n o r e x c e e d t h e 1 5 A N C A C 2 L S t a n d a r d . 13 . Q u a l i f i e r s i n n o n - i t a l i c i z e d t e x t a r e l a b o r a t o r y d a t a q u a l i f i e r s o r " f l a g s " . " U " i s u s e d t o i d e n t i f y r e s u l t s n o t d e t e c t e d a t c o n c e n t r a t i o n s w h i c h e q u a l t h e l a b o r a t o r y ' s M D L . " J " i s u s e d t o i d e n t i f y e s t i m a t e d c o n c e n t r a t i o n s w h i c h e q u a l o r a r e g r e a t e r t h a n t h e M D L b u t a r e l e s s t h a n t h e l a b o r a t o r y ' s m e t h o d r e p o r t i n g l i m i t ( M R L ) . A n i t a l i c i z e d J'-fl a g i s a d a t a q u a l i f i e r , a d d e d b y H D R t o i n d i c a t e c o n c e n t r a t i o n s w h i c h e q u a l o r a r e g r e a t e r t h a n t h e l a b o r a t o r y ' s M R L b u t a r e l e s s t h a n t h e S W S L . 14 . C o n s t i t u e n t s l i s t e d b e l o w t h e b o l d l i n e a r e E P A M e t h o d 8 2 6 0 v o l a t i l e o r g a n i c c o m p o u n d s ( V O C s ) m e a s u r e d a t c o n c e n t r a t i o n s w h i c h e q u a l o r a r e g r e a t e r t h a n t h e i r M D L i n o n e o r m o r e s a m p l e s . R e s u l t s f o r a l l o t h e r E P A M e t h o d 8 2 6 0 c o n s t i t u e n t s w e r e l e s s t h a n t h e i r M D L s . 15 . A n a l y t i c a l r e s u l t s o b t a i n e d f r o m E l e c t r o n i c D a t a D e l i v e r a b l e ( E D D ) p r o v i d e d b y T i m H u n s u c k e r o f D u k e E n e r g y C a r o l i n a s o n A u g u s t 2 6 , 2 0 1 5 . 73 . 6 4 30 . 1 9 70 0 . 0 4 68 . 5 5 8 8 . 2 2 69 9 . 5 1 31 . 1 0 5 3 . 2 9 68 6 . 3 8 77 . 5 7 1 0 8 . 8 2 68 5 . 5 0 55 . 2 7 6.3 75 15 . 5 9 58 . 1 6 67 0 . 2 7 74 0 . 7 7 73 0 . 6 1 73 0 . 2 3 7 3 9 . 6 7 7 2 8 . 4 3 La b o r a t o r y C e r t i f i c a t e C o d e s : Du k e E n e r g y C a r o l i n a s F i e l d # 5 1 9 3 Du k e E n e r g y A n a l y t i c a l L a b o r a t o r y # 2 4 8 Te s t A m e r i c a L a b o r a t o r i e s , I n c . # 3 5 8 Federal MCL 15 A N C A C 2 L St a n d a r d SW S L Sa m p l e D a t e : J u l y 3 0 , 2 0 1 5 Fie l d S a m p l i n g p e r f o r m e d b y D u k e E n e r g y C a r o l i n a s , L L C Pa r a m e t e r SW S I D U n i t s Ce r t i f i c a t e Co d e 6 0 0 4 M W - 1 6 0 0 4 M W - 1 D 6 0 0 4 M W - 2 A 6 0 0 4 M W - 2 D 6 0 0 4 M W - 3 Mo n i t o r i n g W e l l s MD L 16 . 2 5 976.1 6. 1 10 8 16 . 3 3 1 6 . 9 0 626.9 6. 5 96 17 . 0 7 Page 1 of 3 Ta b l e 4 - G r o u n d w a t e r F i e l d a n d A n a l y t i c a l R e s u l t s Du k e E n e r g y C a r o l i n a s , L L C / M c G u i r e N u c l e a r S t a t i o n La n d f i l l # 1 ( U n l i n e d ) - P e r m i t N o . 6 0 0 4 Fi e l d p H 32 0 S U 5 1 9 3 - NE 6.5-8.5 6 . 5 - 8 . 5 * Sp e c i f i c C o n d u c t a n c e 3 2 3 µ Լ /c m 5 1 9 3 - NE N E N E Te m p e r a t u r e 3 2 5 ° C 5 1 9 3 - NE N E N E To p o f C a s i n g 3 2 8 f e e t - - NE N E N E De p t h t o W a t e r 3 1 8 f e e t - - NE N E N E Wa t e r E l e v a t i o n 4 2 7 f e e t - - NE N E N E We l l D e p t h 4 1 1 f e e t - - NE N E N E Ars e n i c 1 4 µg/ L 2 4 8 0 . 1 0 5 J 0 . 0 7 8 U 0 . 1 2 3 J 0 . 1 2 5 J 0 . 1 0 1 J 0 . 0 7 8 1 0 1 0 1 0 Ba r i u m 1 5 µg/ L 2 4 8 2 7 . 4 J' 69 . 9 J' 14 . 5 J' 43 . 6 J' 13 . 7 J' 0. 1 1 0 0 7 0 0 2 , 0 0 0 Ca d m i u m 3 4 µg/ L 2 4 8 0 . 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 U 0 . 1 0 1 1 2 5 Ch r o m i u m 5 1 µg/ L 2 4 8 0 . 5 U 0 . 5 U 0 . 5 U 0 . 5 U 0 . 5 2 7 J 0 . 5 1 0 1 0 1 0 0 Le a d 1 3 1 µg/ L 2 4 8 0 . 0 6 5 U 0 . 0 6 5 U 0 . 1 2 J 0 . 0 6 5 U 0 . 0 6 5 U 0 . 0 6 5 1 0 1 5 1 5 Me r c u r y 1 3 2 µg/ L 2 4 8 0 . 0 0 6 U 0 . 0 0 6 U 0 . 0 0 6 U 0 . 0 0 6 U 0 . 0 0 6 U 0 . 0 0 6 0 . 2 1 2 Se l e n i u m 1 8 3 µg/ L 2 4 8 0 . 0 9 2 U 0 . 0 9 2 U 0 . 0 9 2 U 0 . 0 9 2 U 0 . 0 9 2 U 0 . 0 9 2 1 0 2 0 5 0 Sil v e r 1 8 4 µg/ L 2 4 8 0 . 7 U 0 . 7 U 0 . 7 U 0 . 7 U 0 . 7 U 0 . 7 1 0 2 0 1 0 0 * Su l f a t e 3 1 5 µg/ L 2 4 8 7 8 5 J' 95 2 J' 39 2 J' 25 5 J' 11 9 0 J' 18 2 5 0 , 0 0 0 2 5 0 , 0 0 0 2 5 0 , 0 0 0 * 1, 1 - D i c h l o r o e t h a n e 7 5 µg/ L 3 5 8 0 . 2 4 U 0 . 2 4 U 0 . 2 4 U 0 . 3 6 5 J 0 . 2 4 U 0 . 2 4 5 6 N E Be n z e n e 1 6 µg/ L 3 5 8 0 . 2 U 0 . 2 U 0 . 2 U 0 . 9 2 7 J 0 . 2 U 0 . 2 1 1 5 ci s - 1 , 2 - D i c h l o r o e t h y l e n e 1 3 7 µg/ L 3 5 8 0 . 7 3 4 J 2 . 4 8 J' 0. 2 1 U 1 3 . 1 0 . 2 1 U 0 . 2 1 5 7 0 7 0 Me t h y l e n e c h l o r i d e 1 4 0 µg/ L 3 5 8 0 . 5 2 J 1 . 0 9 0 . 2 2 U 7.5 0.2 2 U 0 . 2 2 1 5 N E Te t r a c h l o r o e t h y l e n e 1 9 6 µg/ L 3 5 8 0 . 3 7 3 J 2. 2 8 0.5 8 2 J 1.7 3 0. 2 5 9 J 0 . 1 4 1 0 . 7 5 To l u e n e 7 9 µg/ L 3 5 8 0 . 1 7 U 0 . 1 7 U 0 . 1 7 U 0 . 2 4 J 0 . 1 7 U 0 . 1 7 1 6 0 0 1 , 0 0 0 tr a n s - 1 , 2 - D i c h l o r o e t h y l e n e 2 1 1 µg/ L 3 5 8 0 . 2 3 U 0 . 2 3 U 0 . 2 3 U 0 . 7 0 8 J 0 . 2 3 U 0 . 2 3 5 1 0 0 1 0 0 Tr i c h l o r o e t h y l e n e 1 9 2 µg/ L 3 5 8 0. 5 6 3 J 1.7 9 0.2 U 5.2 0. 2 0 4 J 0 . 2 1 3 5 Tr i c h l o r o f l u o r o m e t h a n e 20 3 µg/ L 35 8 1.0 3 0.2 1 0. 2 1 0. 2 1 0.2 1 0. 2 1 1 2,000 NE Vi n y l c h l o r i d e 20 1 µg/ L 3 5 8 0. 1 8 U 0 . 1 8 U 0 . 1 8 U 0. 5 0 3 J 0.1 8 U 0 . 1 8 1 0.03 2 Xy l e n e ( t o t a l ) 34 6 µ g / L 3 5 8 4. 0 2 J' 0.5 8 U 0 . 5 8 U 37 0.5 8 U 0 . 5 8 5 500 1 0 , 0 0 0 No t e s : 1 . C o n c e n t r a t i o n s p r e s e n t e d i n m i c r o g r a m s p e r l i t e r ( µ g / L ) . 2 . S U i n d i c a t e s S t a n d a r d U n i t s . 3 . µ Լ /c m i n d i c a t e s m i c r o m h o s p e r c e n t i m e t e r . 4 . S W S I D i s t h e S o l i d W a s t e S e c t i o n I d e n t i f i c a t i o n N u m b e r . 5 . M D L i s t h e l a b o r a t o r y m e t h o d d e t e c t i o n l i m i t . T h e M D L v a l u e s p r e s e n t e d a r e f o r s a m p l e s n o t d i l u t e d b y t h e l a b o r a t o r y d u r i n g a n a l y s i s . 6 . S W S L i s t h e S o l i d W a s t e S e c t i o n L i m i t . N C D E Q d e f i n e s t h e S W S L a s t h e l o w e s t a m o u n t o f a n a l y t e i n a s a m p l e t h a t c a n b e q u a n t i t a t i v e l y d e t e r m i n e d w i t h s u i t a b l e p r e c i s i o n a n d a c c u r a c y . 7 . 1 5 A N C A C 2 L S t a n d a r d r e f e r s t o C l a s s G A S t a n d a r d s a s f o u n d i n 1 5 A N C A C 0 2 L . 0 2 0 2 G r o u n d w a t e r Q u a l i t y S t a n d a r d s , l a s t a m e n d e d o n A p r i l 1 , 2 0 1 3 . 8 . M C L i s t h e F e d e r a l M a x i m u m C o n t a m i n a n t L e v e l a s f o u n d i n 4 0 C F R , S u b p a r t G , § 1 4 1 . 6 2 . 9 . * C o n c e n t r a t i o n l i s t e d i s a s e c o n d a r y m a x i m u m c o n t a m i n a n t l e v e l ( S M C L ) . S M C L s a r e e s t a b l i s h e d b y E P A i n t h e N a t i o n a l S e c o n d a r y D r i n k i n g W a t e r R e g u l a t i o n s a s f o u n d i n 4 0 C F R § 1 4 3 . 3 . 10 . N E i n d i c a t e s n o t e s t a b l i s h e d . N A i n d i c a t e s n o t a n a l y z e d . N S i n d i c a t e s n o s a m p l e w a s c o l l e c t e d . B l a n k c e l l s i n d i c a t e t h a t t h e r e i s n o i n f o r m a t i o n r e l e v a n t t o t h e r e s p e c t i v e r o w . 11 . G r a y e d v a l u e s i n d i c a t e v a l u e s t h a t e q u a l o r a r e g r e a t e r t h a n t h e S W S L . 12 . B o l d v a l u e s i n d i c a t e v a l u e s t h a t a t t a i n o r e x c e e d t h e 1 5 A N C A C 2 L S t a n d a r d . 13 . Q u a l i f i e r s i n n o n - i t a l i c i z e d t e x t a r e l a b o r a t o r y d a t a q u a l i f i e r s o r " f l a g s " . " U " i s u s e d t o i d e n t i f y r e s u l t s n o t d e t e c t e d a t c o n c e n t r a t i o n s w h i c h e q u a l t h e l a b o r a t o r y ' s M D L . " J " i s u s e d t o i d e n t i f y e s t i m a t e d c o n c e n t r a t i o n s w h i c h e q u a l o r a r e g r e a t e r t h a n t h e M D L b u t a r e l e s s t h a n t h e l a b o r a t o r y ' s m e t h o d r e p o r t i n g l i m i t ( M R L ) . A n i t a l i c i z e d J' -fl a g i s a d a t a q u a l i f i e r , a d d e d b y H D R t o i n d i c a t e c o n c e n t r a t i o n s w h i c h e q u a l o r a r e g r e a t e r t h a n t h e l a b o r a t o r y ' s M R L b u t a r e l e s s t h a n t h e S W S L . 14 . C o n s t i t u e n t s l i s t e d b e l o w t h e b o l d l i n e a r e E P A M e t h o d 8 2 6 0 v o l a t i l e o r g a n i c c o m p o u n d s ( V O C s ) m e a s u r e d a t c o n c e n t r a t i o n s w h i c h e q u a l o r a r e g r e a t e r t h a n t h e i r M D L i n o n e o r m o r e s a m p l e s . R e s u l t s f o r a l l o t h e r E P A M e t h o d 8 2 6 0 c o n s t i t u e n t s w e r e l e s s t h a n t h e i r M D L s . 15 . A n a l y t i c a l r e s u l t s o b t a i n e d f r o m E l e c t r o n i c D a t a D e l i v e r a b l e ( E D D ) p r o v i d e d b y T i m H u n s u c k e r o f D u k e E n e r g y C a r o l i n a s o n A u g u s t 2 6 , 2 0 1 5 . 90 . 4 0 72 8 . 3 9 7 1 3 . 8 7 74 1 . 1 3 7 4 0 . 5 8 67 2 . 9 9 65 . 6 8 67 5 . 4 5 74 . 1 5 90 . 1 9 67 0 . 2 7 58 . 1 2 71 3 . 7 5 45 . 7 3 1 0 2 . 2 4 67 4 . 3 8 16 . 0 6 17 4 6. 3 66 . 2 0 6. 0 11 7 16 . 5 8 40 . 2 7 15 . 7 6 11 4 6. 5 5 . 6 15 2 16 . 4 1 MD L 6.8 12 9 15 . 5 8 40 . 7 6 67 3 . 6 0 Sa m p l e D a t e : J u l y 3 0 , 2 0 1 5 Fi e l d S a m p l i n g p e r f o r m e d b y D u k e E n e r g y C a r o l i n a s , L L C Laboratory Certificate Codes: Du k e E n e r g y C a r o l i n a s F i e l d # 5 1 9 3 Du k e E n e r g y A n a l y t i c a l L a b o r a t o r y # 2 4 8 Te s t A m e r i c a L a b o r a t o r i e s , I n c . # 3 5 8 Pa r a m e t e r S W S I D U n i t s Ce r t i f i c a t e Co d e SW S L Federal MCL 60 0 4 M W - 3 D 6 0 0 4 M W - 4 6 0 0 4 M W - 4 R 6 0 0 4 M W - 4 D 6 0 0 4 M W - 4 D R Mo n i t o r i n g W e l l s 15A NCAC 2L Standard Page 2 of 3 Ta b l e 4 - G r o u n d w a t e r F i e l d a n d A n a l y t i c a l R e s u l t s Du k e E n e r g y C a r o l i n a s , L L C / M c G u i r e N u c l e a r S t a t i o n La n d f i l l # 1 ( U n l i n e d ) - P e r m i t N o . 6 0 0 4 Fie l d p H 32 0 S U 5 1 9 3 - NE 6.5-8.5 6 . 5 - 8 . 5 * Sp e c i f i c C o n d u c t a n c e 3 2 3 µ Լ /cm 5 1 9 3 -N E N E N E Te m p e r a t u r e 3 2 5 ° C 5 1 9 3 -N E N E N E To p o f C a s i n g 32 8 f e e t - -N E N E N E De p t h t o W a t e r 31 8 f e e t - -N E N E N E Wa t e r E l e v a t i o n 42 7 f e e t - -N E N E N E We l l D e p t h 41 1 f e e t - -N E N E N E Ar s e n i c 14 µg/ L 24 8 0. 0 7 8 U 0 . 0 7 8 U 0. 0 7 8 U 0.0 7 8 U 0 . 0 7 8 1 0 10 10 Ba r i u m 15 µg/ L 24 8 7.5 1 J ' 12 . 2 J ' 10 . 5 J ' 0.1 3 8 J 0. 1 1 0 0 700 2 , 0 0 0 Ca d m i u m 34 µg/ L 24 8 0. 1 0 1 U 0 . 1 0 1 U 0. 1 0 1 U 0.1 0 1 U 0 . 1 0 1 1 2 5 Ch r o m i u m 51 µg/ L 24 8 0. 5 U 0. 5 U 0. 5 U 0.5 U 0 . 5 1 0 10 100 Le a d 13 1 µg/ L 24 8 0.0 6 7 4 J 0.0 6 5 U 0. 0 6 5 U 0.0 6 5 U 0 . 0 6 5 1 0 15 15 Me r c u r y 1 3 2 µg/ L 24 8 0. 0 0 6 U 0 . 0 0 6 U 0. 0 0 6 U 0.0 0 6 U 0 . 0 0 6 0 . 2 1 2 Se l e n i u m 18 3 µg/ L 24 8 0. 0 9 2 U 0 . 0 9 2 U 0. 0 9 2 U 0.0 9 2 U 0 . 0 9 2 1 0 20 50 Sil v e r 18 4 µg/ L 24 8 0. 7 U 0. 7 U 0. 7 U 0.7 U 0 . 7 1 0 20 100* Su l f a t e 31 5 µg/ L 24 8 29 7 J ' 78 8 J ' 45 . 6 J 18 U 1 8 2 5 0 , 0 0 0 2 5 0 , 0 0 0 2 5 0 , 0 0 0 * 1,1 - D i c h l o r o e t h a n e 7 5 µg/ L 3 5 8 0 . 2 4 U 0 . 2 4 U 0 . 2 4 U 0 . 2 4 U 0 . 2 4 U 0 . 2 4 5 6 N E Be n z e n e 1 6 µg/ L 3 5 8 0. 2 U 0 . 2 U 0 . 2 U 0 . 2 U 0 . 2 U 0. 2 1 1 5 cis - 1 , 2 - D i c h l o r o e t h y l e n e 1 3 7 µg/ L 3 5 8 0.2 1 U 0 . 2 1 U 0 . 2 1 U 0 . 2 1 U 0 . 2 1 U 0. 2 1 5 7 0 7 0 Me t h y l e n e c h l o r i d e 1 4 0 µg/ L 3 5 8 0.2 2 U 0 . 2 2 U 0 . 2 2 U 0 . 2 2 U 0 . 2 2 U 0. 2 2 1 5 N E Te t r a c h l o r o e t h y l e n e 1 9 6 µg/ L 3 5 8 0.1 4 U 0 . 1 4 U 0 . 1 4 U 0 . 1 4 U 0 . 1 4 U 0. 1 4 1 0 . 7 5 To l u e n e 7 9 µg/ L 3 5 8 0.1 7 U 0 . 1 7 U 0 . 1 7 U 0 . 1 7 U 0 . 1 7 U 0. 1 7 1 6 0 0 1 , 0 0 0 tr a n s - 1 , 2 - D i c h l o r o e t h y l e n e 2 1 1 µg/ L 3 5 8 0.2 3 U 0 . 2 3 U 0 . 2 3 U 0 . 2 3 U 0 . 2 3 U 0. 2 3 5 1 0 0 1 0 0 Tr i c h l o r o e t h y l e n e 1 9 2 µg/ L 3 5 8 0. 2 U 0 . 2 U 0 . 2 U 0 . 2 U 0 . 2 U 0. 2 1 3 5 Tr i c h l o r o f l u o r o m e t h a n e 2 0 3 µg/ L 35 8 0 . 2 1 U 0 . 2 1 U 0 . 2 1 U 0 . 2 1 U 0 . 2 1 U 0 . 2 1 1 2 , 0 0 0 N E Vin y l c h l o r i d e 2 0 1 µg/ L 3 5 8 0.1 8 U 0 . 1 8 U 0 . 1 8 U 0 . 1 8 U 0 . 1 8 U 0. 1 8 1 0 . 0 3 2 Xy l e n e ( t o t a l ) 3 4 6 µ g / L 3 5 8 0.5 8 U 0 . 5 8 U 0 . 5 8 U 0 . 5 8 U 0 . 5 8 U 0. 5 8 5 5 0 0 1 0 , 0 0 0 No t e s : 1 . C o n c e n t r a t i o n s p r e s e n t e d i n m i c r o g r a m s p e r l i t e r ( µ g / L ) . 2 . S U i n d i c a t e s S t a n d a r d U n i t s . 3 . µ Լ /c m i n d i c a t e s m i c r o m h o s p e r c e n t i m e t e r . 4 . S W S I D i s t h e S o l i d W a s t e S e c t i o n I d e n t i f i c a t i o n N u m b e r . 5 . M D L i s t h e l a b o r a t o r y m e t h o d d e t e c t i o n l i m i t . T h e M D L v a l u e s p r e s e n t e d a r e f o r s a m p l e s n o t d i l u t e d b y t h e l a b o r a t o r y d u r i ng a n a l y s i s . 6 . S W S L i s t h e S o l i d W a s t e S e c t i o n L i m i t . N C D E Q d e f i n e s t h e S W S L a s t h e l o w e s t a m o u n t o f a n a l y t e i n a s a m p l e t h a t c a n b e q u a n tit a t i v e l y d e t e r m i n e d w i t h s u i t a b l e p r e c i s i o n a n d a c c u r a c y . 7 . 1 5 A N C A C 2 L S t a n d a r d r e f e r s t o C l a s s G A S t a n d a r d s a s f o u n d i n 1 5 A N C A C 0 2 L . 0 2 0 2 G r o u n d w a t e r Q u a l i t y S t a n d a r d s , l a s t a m e n de d o n A p r i l 1 , 2 0 1 3 . 8 . M C L i s t h e F e d e r a l M a x i m u m C o n t a m i n a n t L e v e l a s f o u n d i n 4 0 C F R , S u b p a r t G , § 1 4 1 . 6 2 . 9 . * C o n c e n t r a t i o n l i s t e d i s a s e c o n d a r y m a x i m u m c o n t a m i n a n t l e v e l ( S M C L ) . S M C L s a r e e s t a b l i s h e d b y E P A i n t h e N a t i o n a l S e c o nd a r y D r i n k i n g W a t e r R e g u l a t i o n s a s f o u n d i n 4 0 C F R § 1 4 3 . 3 . 10 . N E i n d i c a t e s n o t e s t a b l i s h e d . N A i n d i c a t e s n o t a n a l y z e d . N S i n d i c a t e s n o s a m p l e w a s c o l l e c t e d . B l a n k c e l l s i n d i c a t e t h a t th e r e i s n o i n f o r m a t i o n r e l e v a n t t o t h e r e s p e c t i v e r o w . 11 . G r a y e d v a l u e s i n d i c a t e v a l u e s t h a t e q u a l o r a r e g r e a t e r t h a n t h e S W S L . 12 . B o l d v a l u e s i n d i c a t e v a l u e s t h a t a t t a i n o r e x c e e d t h e 1 5 A N C A C 2 L S t a n d a r d . 13 . Q u a l i f i e r s i n n o n - i t a l i c i z e d t e x t a r e l a b o r a t o r y d a t a q u a l i f i e rs o r " f l a g s " . " U " i s u s e d t o i d e n t i f y r e s u l t s n o t d e t e c t e d a t c o n c e n t r a t i o n s w h i c h e q u a l t h e l a b o r a t o r y ' s M D L . " J " i s u s e d t o i d e n t i f y e s t i m a t e d c o n c e n t r a t i o n s w h i c h e q u a l o r a r e g r e a t e r t h a n t h e M D L b u t a r e l e s s t h a n t h e l a b o r a t o r y's m e t h o d r e p o r t i n g l i m i t ( M R L ) . A n i t a l i c i z e d J' -fl a g i s a d a t a q u a l i f i e r , a d d e d b y H D R t o i n d i c a t e c o n c e n t r a t i o n s w h i c h e q u a l o r a r e g r e a t e r t h a n t h e l a b o r a t o r y ' s M R L b u t a r e le s s t h a n t h e S W S L . 14 . C o n s t i t u e n t s l i s t e d b e l o w t h e b o l d l i n e a r e E P A M e t h o d 8 2 6 0 v o la t i l e o r g a n i c c o m p o u n d s ( V O C s ) m e a s u r e d a t c o n c e n t r a t i o n s w h ic h e q u a l o r a r e g r e a t e r t h a n t h e i r M D L i n o n e o r m o r e s a m p l e s . R e s u l t s f o r a l l o t h e r E P A M e t h o d 8 2 6 0 c o n s t i t u e n t s w e r e l e s s t h a n t h e i r M D L s . 15 . A n a l y t i c a l r e s u l t s o b t a i n e d f r o m E l e c t r o n i c D a t a D e l i v e r a b l e ( E D D ) p r o v i d e d b y T i m H u n s u c k e r o f D u k e E n e r g y C a r o l i n a s o n A u gu s t 2 6 , 2 0 1 5 . 38 . 4 5 33 . 7 7 10 1 . 5 5 NS NSNSNS --- NS NSNSNSNS -- NANANANANANANANANA 18 . 6 3 1 5 . 4 9 68 8 . 8 3 72 4 . 7 7 72 4 . 8 1 15 . 2 4 69 5 . 7 9 72 2 . 6 0 7 2 3 . 1 4 NS Laboratory Certificate Codes:Duke Energy Carolinas Field #5193 Du k e E n e r g y A n a l y t i c a l L a b o r a t o r y # 2 4 8 TestAmerica Laboratories, Inc. #358 Federal MCL Sa m p l e D a t e : J u l y 3 0 , 2 0 1 5 Fi e l d S a m p l i n g p e r f o r m e d b y D u k e E n e r g y C a r o l i n a s , L L C 15A NCAC 2L Standard 5.1 Pa r a m e t e r S W S I D U n i t s Ce r t i f i c a t e Co d e SW S L 60 0 4 M W - 1 2 6 0 0 4 M W - 1 2 D Tr i p Bla n k Fie l d Bl a n k 60 0 4 M W - 1 1 D Mo n i t o r i n g W e l l s 20 3 3 -- 6.3 77 - NS NS 60 0 4 M W - 1 1 MD L 5. 8 - 68 . 4 2 68 8 . 7 5 34 . 3 9 2 8 . 1 2 69 6 . 6 9 29 . 4 9 28 . 9 8 - - --- NSNSNSNSNSNS NSNSNSNSNS Page 3 of 3 Ta b l e 5 - F i e l d a n d A n a l y t i c a l R e s u l t s t h a t E q u a l o r E x c e e d 15 A N C A C 2 L G r o u n d w a t e r Q u a l i t y S t a n d a r d s Du k e E n e r g y C a r o l i n a s , L L C / M c G u i r e N u c l e a r S t a t i o n La n d f i l l # 1 ( U n l i n e d ) - P e r m i t N o . 6 0 0 4 Pa r a m e t e r S a m p l e I D Un i t s 15 A N C A C 2L S t a n d a r d His t o r i c a l C o n c e n t r a t i o n s Ca u s e a n d S i g n i f i c a n c e MW - 1 5. 9 - 7 . 0 pH i s c o n s i s t e n t w i t h h i s t o r i c a l r e a d i n g s a t M W - 1 . MW - 1 D 5. 9 - 7 . 0 pH i s c o n s i s t e n t w i t h h i s t o r i c a l r e a d i n g s a t M W - 1 D . MW - 2 A 5. 7 - 7 . 4 pH i s c o n s i s t e n t w i t h h i s t o r i c a l r e a d i n g s a t M W - 2 A . MW - 3 5. 7 - 7 . 5 pH i s c o n s i s t e n t w i t h h i s t o r i c a l r e a d i n g s a t M W - 3 . MW - 3 D 6. 1 - 7 . 1 pH i s c o n s i s t e n t w i t h h i s t o r i c a l r e a d i n g s a t M W - 3 D . MW - 4 5. 3 - 8 . 1 pH i s c o n s i s t e n t w i t h h i s t o r i c a l r e a d i n g s a t M W - 4 . MW - 4 R 5. 9 - 6 . 3 pH i s c o n s i s t e n t w i t h h i s t o r i c a l r e a d i n g s a t M W - 4 R . T h i s i s t h e fo u r t h s a m p l i n g e v e n t a t m o n i t o r i n g w e l l M W - 4 R . MW - 4 D 6. 0 - 7 . 1 pH i s c o n s i s t e n t w i t h h i s t o r i c a l r e a d i n g a t M W - 4 D . MW - 1 1 4. 3 - 5 . 3 pH i s c o n s i s t e n t w i t h h i s t o r i c a l r e a d i n g s a t M W - 1 1 . MW - 1 1 D 5. 3 - 6 . 2 pH i s c o n s i s t e n t w i t h h i s t o r i c a l r e a d i n g s a t M W - 1 1 D . MW - 1 2 D 6. 1 - 7 . 4 pH i s c o n s i s t e n t w i t h h i s t o r i c a l r e a d i n g s a t M W - 1 2 D . Me t h y l e n e C h l o r i d e M W - 4 D µg / L 5 0.5 3 - 6 . 9 3 Me t h y l e n e c h l o r i d e c o n c e n t r a t i o n i n M W - 4 D i s h i g h e r t h a n t h e h i s t o r i c a l r a n g e . M W - 4 D i s l o c a t e d a p p r o x i m a t e l y 15 f e e t o u t s i d e t h e w a s t e b o u n d a r y a n d a p p r o x i m a t e l y 1 1 0 f e e t w i t h i n t h e l a n d f i l l r e v i e w b o u n d a r y . MW - 4 0. 8 8 - 2 . 3 MW - 4 i s l o c a t e d a p p r o x i m a t e l y 1 5 f e e t o u t s i d e t h e w a s t e b o u n d a r y a n d a p p r o x i m a t e l y 1 1 0 f e e t w i t h i n t h e l a n d f i l l re v i e w b o u n d a r y . MW - 4 D 0.5 2 - 1 . 3 9 Te t r a c h l o r o e t h y l e n e c o n c e n t r a t i o n i n M W - 4 D i s h i g h e r t h a n t h e h i s t o r i c a l r a n g e . M W - 4 D i s l o c a t e d a p p r o x i m a t e l y 15 f e e t o u t s i d e t h e w a s t e b o u n d a r y a n d a p p r o x i m a t e l y 1 1 0 f e e t w i t h i n t h e l a n d f i l l r e v i e w b o u n d a r y . Tr i c h l o r o e t h y l e n e M W - 4 D µg / L 3 0.5 8 - 4 . 4 6 Tr i c h l o r o e t h y l e n e c o n c e n t r a t i o n i n M W - 4 D i s h i g h e r t h a n t h e h i s t o r i c a l r a n g e . M W - 4 D i s l o c a t e d a p p r o x i m a t e l y 1 5 fe e t o u t s i d e t h e w a s t e b o u n d a r y a n d a p p r o x i m a t e l y 1 1 0 f e e t w i t h i n t h e l a n d f i l l r e v i e w b o u n d a r y . Vin y l c h l o r i d e M W - 4 D µg / L 0.0 3 <1 MW - 4 D i s l o c a t e d a p p r o x i m a t e l y 1 5 f e e t o u t s i d e t h e w a s t e b o u n d a r y a n d a p p r o x i m a t e l y 1 1 0 f e e t w i t h i n t h e la n d f i l l r e v i e w b o u n d a r y . No t e s : 1 . 1 5 A N C A C 2 L S t a n d a r d r e f e r s t o C l a s s G A S t a n d a r d s a s f o u n d i n 1 5 A N C A C 0 2 L . 0 2 0 2 G r o u n d w a t e r Q u a l i t y S t a n d a r d s , l a s t a m e n d e d o n A p r i l 1 , 2 0 1 3 . 2 . µ g / L i n d i c a t e s m i c r o g r a m s p e r l i t e r . 3 . S U i n d i c a t e s S t a n d a r d U n i t s . 4 . " B " i n d i c a t e s t h a t t h e p a r a m e t e r w a s d e t e c t e d i n t h e m e t h o d b l a n k a t a c o n c e n t r a t i o n t h a t w a s g r e a t e r t h a n t h e M D L b u t b e l o w t h e M R L . T h e s e v a l u e s s h o u l d b e c o n s i d e r e d e s t i m a t e d . 5 . H i s t o r i c a l c o n c e n t r a t i o n s b a s e d o n d a t a i n D u k e E n e r g y C a r o l i n a s , L L C a n a l y t i c a l r e s u l t s d a t a b a s e . 6 . H i s t o r i c a l c o n c e n t r a t i o n s n o t m e a s u r e d a t c o n c e n t r a t i o n s w h i c h e q u a l o r a r e g r e a t e r t h a n t h e l a b o r a t o r y m e t h o d r e p o r t i n g l i m i t a r e p r e s e n t e d a s < M R L . 7 . A n a l y t i c a l r e s u l t s o b t a i n e d f r o m E l e c t r o n i c D a t a D e l i v e r a b l e ( E D D ) p r o v i d e d b y T i m H u n s u c k e r o f D u k e E n e r g y C a r o l i n a s , L L C o n A u g u s t 2 6 , 2 0 1 5 . Sa m p l e D a t e : J u l y 3 0 , 2 0 1 5 Fi e l d s a m p l i n g p e r f o r m e d b y D u k e E n e r g y C a r o l i n a s , L L C pH Re s u l t 6. 1 6. 1 6. 3 5. 6 6. 3 5. 1 5. 8 SU 6 . 5 - 8 . 5 6. 5 6. 0 6. 3 6. 5 0. 5 0 3 7. 5 B 0. 7 Te t r a c h l o r o e t h y l e n e 5. 2 2. 2 8 µg / L 1. 7 3 Page 1 of 1 Ta b l e 6 - S u r f a c e W a t e r F i e l d a n d A n a l y t i c a l R e s u l t s Du k e E n e r g y C a r o l i n a s , L L C / M c G u i r e N u c l e a r S t a t i o n La n d f i l l # 1 ( U n l i n e d ) - P e r m i t N o . 6 0 0 4 Fie l d p H 32 0 S U 5 1 9 3 NE N E 6.0 - 9 . 0 6 . 5 - 8 . 5 * Sp e c i f i c C o n d u c t a n c e 3 2 3 µ Լ /c m 5 1 9 3 NE N E NE NE Te m p e r a t u r e 32 5 ° C 5 1 9 3 NE N E NE NE Ar s e n i c 14 µg/ L 24 8 0. 3 6 4 J 0 . 0 7 8 1 0 10 10 Ar s e n i c , d i s s o l v e d 14 µg/ L 24 8 0. 1 8 0 . 0 7 8 1 0 15 0 NE Ba r i u m 15 µg/ L 24 8 31 . 4 J' 0.1 1 0 0 NE 2, 0 0 0 Ba r i u m , d i s s o l v e d 15 µg/ L 24 8 26 . 5 J' 0.1 1 0 0 NE NE Ca d m i u m 34 µg/ L 24 8 0. 1 0 1 U 0 . 1 0 1 1 NE 5 Ca d m i u m , d i s s o l v e d ( h ) 34 µg/ L 24 8 0. 1 0 1 U 0 . 1 0 1 1 0.1 5 NE Ch r o m i u m 51 µg/ L 24 8 0.5 U 0 . 5 1 0 NE 10 0 Ch r o m i u m , d i s s o l v e d † 51 µg/ L 24 8 0.5 U 0 . 5 1 0 11 NE Le a d 13 1 µg/ L 24 8 0. 1 7 7 J 0 . 0 6 5 1 0 NE 15 Le a d , d i s s o l v e d ( h ) 13 1 µg/ L 24 8 0. 0 6 5 U 0 . 0 6 5 1 0 0.5 4 NE Me r c u r y 1 3 2 µg/ L 24 8 0. 0 0 6 U 0 . 0 0 6 0 . 2 0. 0 1 2 2 Se l e n i u m 18 3 µg/ L 24 8 0. 0 9 2 U 0 . 0 9 5 1 0 5 50 Sil v e r 18 4 µg/ L 24 8 0.7 U 0 . 7 1 0 NE 10 0 * Sil v e r , d i s s o l v e d 18 4 µg/ L 24 8 0.7 U 0 . 7 1 0 0.0 6 NE Su l f a t e 31 5 µg/ L 24 8 1, 2 7 0 J' 18 2 5 0 , 0 0 0 NE 2 5 0 , 0 0 0 * EP A 8 2 6 0 B ( V O C s ) No t e s : 1 . C o n c e n t r a t i o n s p r e s e n t e d i n m i c r o g r a m s p e r l i t e r ( µ g / L ) . 2 . S U i n d i c a t e s S t a n d a r d U n i t s . 3 . µ Լ /c m i n d i c a t e s m i c r o m h o s p e r c e n t i m e t e r . 4 . S W S I D i s t h e S o l i d W a s t e S e c t i o n I d e n t i f i c a t i o n N u m b e r . 5 . M D L i s t h e l a b o r a t o r y m e t h o d d e t e c t i o n l i m i t . T h e M D L v a l u e s p r e s e n t e d a r e f o r s a m p l e s n o t d i l u t e d b y t h e l a b o r a t o r y d u r i n g a n a l y s i s . 6 . S W S L i s t h e S o l i d W a s t e S e c t i o n L i m i t . N C D E Q d e f i n e s t h e S W S L a s t h e l o w e s t a m o u n t o f a n a l y t e i n a s a m p l e t h a t c a n b e q u a n t i t a t i v e l y d e t e r m i n e d w i t h s u i t a b l e p r e c i s i o n a n d a c c u r a c y . 7 . 1 5 A N C A C 2 B S t a n d a r d i s f r o m " N o r t h C a r o l i n a A d m i n i s t r a t i v e C o d e , T i t l e 1 5 A : D e p a r m e n t o f E n v i r o n m e n t a l Q u a l i t y , S u b c h a p t e r 2 B - S u r f a c e W a t e r a n d W e t l a n d S t a n d a r d s , " ( l a s t a m e n d e d o n J a n u a r y 1 , 2 0 1 5 ) f o r C l a s s W S - I V w a t e r s . 8 . M C L i s t h e F e d e r a l M a x i m u m C o n t a m i n a n t L e v e l a s f o u n d i n 4 0 C F R , S u b p a r t G , § 1 4 1 . 6 2 . 9 . * C o n c e n t r a t i o n l i s t e d i s a s e c o n d a r y m a x i m u m c o n t a m i n a n t l e v e l ( S M C L ) . S M C L s a r e e s t a b l i s h e d b y E P A i n t h e N a t i o n a l S e c o n d a r y D r i n k i n g W a t e r R e g u l a t i o n s a s f o u n d i n 4 0 C F R § 1 4 3 . 3 . 10 . N E i n d i c a t e s n o t e s t a b l i s h e d . 11 . G r a y e d v a l u e s i n d i c a t e v a l u e s t h a t e q u a l o r a r e g r e a t e r t h a n t h e S W S L . 12 . B o l d v a l u e s i n d i c a t e v a l u e s t h a t a t t a i n o r e x c e e d t h e 1 5 A N C A C 2 B S t a n d a r d . 13 . Q u a l i f i e r s i n n o n - i t a l i c i z e d t e x t a r e l a b o r a t o r y d a t a q u a l i f i e r s o r " f l a g s " . " U " i s u s e d t o i d e n t i f y r e s u l t s n o t d e t e c t e d a t c o n c e n t r a t i o n s w h i c h e q u a l t h e l a b o r a t o r y ' s M D L . " J " i s u s e d t o i d e n t i f y e s t i m a t e d c o n c e n t r a t i o n s w h i c h e q u a l o r a r e g r e a t e r t h a n t h e M D L b u t a r e l e s s t h a n t h e l a b o r a t o r y ' s m e t h o d r e p o r t i n g l i m i t ( M R L ) . A n i t a l i c i z e d J' -f l a g i s a d a t a q u a l i f i e r , a d d e d b y H D R t o i n d i c a t e c o n c e n t r a t i o n s w h i c h e q u a l o r a r e g r e a t e r t h a n t h e l a b o r a t o r y ' s M R L b u t a r e l e s s t h a n t h e S W S L . 14 . † S t a n d a r d l i s t e d i s m o s t s t r i n g e n t o f C r ( I I I ) a n d C r ( V I ) . 15 . ( h ) S t a n d a r d i s h a r d n e s s d e p e n d e n t ; s t a n d a r d i s d i s p l a y e d a s s u m i n g a h a r d n e s s o f ≤ 2 5 m g / L . 16 . R e s u l t s f o r a l l E P A M e t h o d 8 2 6 0 c o n s t i t u e n t s w e r e l e s s t h a n t h e i r M D L s . 17 . A n a l y t i c a l r e s u l t s o b t a i n e d f r o m E l e c t r o n i c D a t a D e l i v e r a b l e ( E D D ) p r o v i d e d b y T i m H u n s u c k e r o f D u k e E n e r g y C a r o l i n a s o n A u g u s t 2 6 , 2 0 1 5 . La b o r a t o r y C e r t i f i c a t e C o d e s : Du k e E n e r g y C a r o l i n a s F i e l d # 5 1 9 3 Du k e E n e r g y A n a l y t i c a l L a b o r a t o r y # 2 4 8 Te s t A m e r i c a L a b o r a t o r i e s , I n c . # 3 5 8 Sa m p l e D a t e : J u l y 3 0 , 2 0 1 5 Fie l d S a m p l i n g p e r f o r m e d b y D u k e E n e r g y C a r o l i n a s , L L C SW S L Pa r a m e t e r S W S I D U n i t s Ce r t i f i c a t e Co d e S W - 1 SE E N O T E 1 6 15 A N C A C 2 B St a n d a r d F e d e r a l MC L MD L 25 . 8 7 12 4 7. 5 Page 1 of 1 Ta b l e 7 - R a d i o l o g i c a l A n a l y t i c a l R e s u l t s Du k e E n e r g y C a r o l i n a s , L L C / M c G u i r e N u c l e a r S t a t i o n La n d f i l l # 1 ( U n l i n e d ) - P e r m i t N o . 6 0 0 4 MW - 1 M W - 1 D M W - 2 A M W - 2 D M W - 3 M W - 3 D M W - 4 M W - 4 R M W - 4 D M W - 4 D R M W - 1 1 M W - 1 1 D M W - 1 2 M W - 1 2 D Alp h a p C i / L 24 8 <-0 . 5 2 < - 0 . 3 6 < - 0 . 0 4 8 < - 0 . 1 9 < - 0 . 2 5 < - 0 . 5 6 < - 0 . 0 5 6 < - 0 . 2 7 < - 0 . 7 < - 0 . 3 9 < - 0 . 1 9 < - 0 . 0 3 3 N S <-0.19 < - 0 . 5 1 Ba L a - 1 4 0 p C i / L 24 8 <8 . 3 3 < 5 . 7 7 < 7 . 8 3 < 7 . 3 3 < 7 . 8 3 < 8 . 8 2 < 7 . 4 < 6 . 4 < 5 . 7 < 9 . 4 8 < 6 . 7 4 < 8 . 6 N S <5.51 < 6 . 5 6 Be - 7 p C i / L 24 8 <3 9 . 4 < 5 8 . 5 < 3 3 . 6 < 4 1 . 8 < 4 4 . 7 < 4 2 . 4 < 5 2 < 4 9 . 8 < 3 7 . 3 < 5 4 < 4 1 . 3 < 5 1 . 9 N S 6.06 < 4 7 . 8 Be t a p C i / L 24 8 <-0 . 6 6 < - 0 . 5 7 < - 0 . 8 5 < - 1 . 7 < - 0 . 9 5 < - 0 . 4 6 <-1 < - 1 . 4 <- 1 < - 1 . 3 < - 1 . 4 < - 1 . 7 N S <-1.7 < - 0 . 8 7 Co - 5 8 p C i / L 24 8 <5 . 7 3 < 7 . 0 3 < 4 . 7 6 < 4 . 4 2 < 5 . 3 8 < 5 . 6 4 < 5 . 2 8 < 5 . 3 7 < 5 . 3 4 < 4 . 0 3 < 6 . 2 1 < 6 . 0 3 N S <6.08 < 5 . 7 3 Co - 6 0 p C i / L 24 8 <6 . 7 < 7 . 9 3 < 5 . 6 7 < 5 . 3 9 < 5 . 2 7 < 5 . 0 6 < 5 . 3 7 < 4 . 3 3 < 3 . 8 2 < 5 . 2 7 < 5 . 9 4 < 3 . 8 N S <6.03 < 4 . 9 3 Cs - 1 3 4 p C i / L 24 8 <6 . 1 5 < 8 . 2 9 < 5 . 5 < 6 . 5 5 < 6 . 5 6 < 7 . 0 7 < 6 . 2 7 < 4 . 7 4 < 6 . 5 5 < 5 . 7 4 < 4 . 9 8 < 6 . 0 6 N S <3.79 < 3 . 9 1 Cs - 1 3 7 p C i / L 24 8 <7 . 1 3 < 6 . 7 7 < 5 . 8 5 < 3 . 7 1 < 5 . 3 6 < 5 . 6 1 < 5 . 9 5 < 5 . 6 9 < 4 . 4 9 < 5 . 3 6 < 5 . 9 7 < 6 . 4 1 N S <4.98 < 4 . 9 3 Fe - 5 9 p C i / L 24 8 <1 2 . 3 < 1 0 . 3 < 1 0 . 4 < 1 0 . 1 < 9 . 2 1 < 9 . 6 5 < 1 0 < 7 . 8 4 < 9 . 4 5 < 9 . 2 1 < 1 1 . 4 < 1 1 . 1 N S <8.55 < 1 1 . 7 H3 G W p C i / L 24 8 <- 7 6 < - 3 6 < 2 7 . 6 < - 2 9 < - 5 3 < - 7 0 < - 1 9 < - 2 4 < - 6 1 < - 1 6 0 < 1 5 . 4 < - 2 5 N S <-7.7 < 4 8 I- 1 3 1 p C i / L 24 8 <7 . 9 < 8 . 4 5 < 6 . 6 5 < 6 . 4 2 < 6 . 6 5 < 7 . 0 2 < 6 . 9 9 < 4 . 8 < 6 . 6 2 < 6 . 5 3 < 7 . 0 5 < 6 . 4 9 N S <6.32 < 6 . 2 5 K-4 0 p C i / L 24 8 <1 0 3 1 2 6 6 3 . 1 3 8 . 9 91 1 3 6 < 8 5 . 2 4 9 . 9 < 9 8 . 9 6 0 . 2 < 9 9 . 3 9 4 . 2 N S 91.5 6 1 . 1 Mn - 5 4 p C i / L 24 8 <6 . 4 8 < 5 . 9 5 < 5 . 4 9 < 5 . 8 4 < 4 . 4 8 < 5 . 5 7 < 4 . 7 9 < 5 . 4 9 < 3 . 8 < 5 . 6 8 < 4 . 6 9 < 5 . 2 1 N S <6.01 < 4 . 3 6 Nb - 9 5 p C i / L 24 8 <6 . 7 9 < 7 . 2 7 < 6 . 6 7 < 4 . 8 7 < 6 . 0 5 < 6 . 1 6 <6 < 5 . 3 3 < 6 . 7 3 < 6 . 0 5 < 6 . 8 4 < 6 . 4 7 N S <5.51 < 5 . 0 9 Zn - 6 5 p C i / L 24 8 <1 2 . 3 < 1 4 . 9 < 1 1 . 8 < 1 3 . 2 < 1 0 . 6 < 1 1 . 8 < 1 1 . 4 < 1 1 . 8 < 8 . 7 2 < 1 1 . 2 < 9 . 7 3 < 1 1 . 4 N S <9.28 < 1 1 . 5 Zr - 9 5 p C i / L 24 8 <1 0 . 9 < 1 1 . 1 < 9 . 6 9 < 9 . 2 9 < 9 . 0 3 < 8 . 2 7 < 9 . 2 < 9 . 9 9 < 7 . 2 3 < 1 0 . 6 < 9 . 4 6 < 9 . 1 8 N S <10.3 < 8 . 1 3 No t e s : 1 . C o n c e n t r a t i o n s p r e s e n t e d i n p i c o c u r i e s p e r l i t e r ( p C i / L ) . 2 . N S i n d i c a t e s n o s a m p l e w a s c o l l e c t e d . 3 . A n a l y t i c a l r e s u l t s o b t a i n e d f r o m E n R a d L a b o r a t o r y R e p o r t J o b : M N S _ 9 J U N 2 0 1 5 _ A M c G u i r e L a n d f i l l 1 G r o u n d w a t e r s p r o v i d e d b y T i m H u n s u c k e r o f D u k e E n e r g y C a r o l i n a s o n A u g u s t 2 8 , 2 0 1 5 . Sa m p l e D a t e : J u l y 3 0 , 2 0 1 5 Fi e l d S a m p l i n g P e r f o r m e d b y D u k e E n e r g y C a r o l i n a s , L L C Laboratory Certification Code Duke Energy Analytical Laboratory #248 Pa r a m e t e r U n i t s Ce r t i f i c a t e Co d e SW-1 Mo n i t o r i n g W e l l s Page 1 of 1 A Appendix A Field Sampling Forms ANALYZER SERIAL #: WEATHER CONDITIONS: DATE:TIME:DATE:TIME: Calibation Instrument Standard Instrument Standard Standard Value Value Value Value SS 0.0 ▬/▬►0.0 0.0 ▬/▬►0.0 SS 233.3 ▬▬►227 220.1 ▬/▬►227 SS 74.5 ▬/▬►75 73.1 ▬/▬►75 SS ▬/▬►▬/▬► B (7.00)7.01 ▬▬►7.02 7.02 ▬/▬►7.02 B (4.00)4.00 ▬▬►4.00 3.97 ▬/▬►4.00 B (10.00)10.08 ▬/▬►10.04 10.06 ▬/▬►10.04 20.83 20.68 pH Check B (7.00)▬▬► Time: SS (7.00)289 ▬▬►294 292 ▬/▬►294 SS (4.00)N/A ▬/▬►469 N/A ▬/▬►469 20.64 20.54 W 7.90 8.00 W 8.00 8.10 AW 7.98 ▬▬►7.95 8.11 ▬/▬►8.05 SS 53.4 ▬/▬►53.3 53.0 ▬/▬►53.3 NIST N/A ▬/▬►N/A N/A ▬/▬►N/A KEY: NOTES: SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To (mmHg) B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable Replaced DO electrolyte See Notes Field Barometric Pressure Beginning BP 740.6 (mmHg)Ending BP 741.2 Tested - OK See Notes Tested - OK See Notes Dissolved Oxygen Subsystem Replaced Teflon Membrane Cleaned Electrode Tested - OK See Notes Oxidation Reduction Subsystem Temperature Subsystem Cleaned Electrode Cleaned Electrode Tested - OK Replaced ref Electrode KCL See Notes Replaced Ref. Electrode Tip INSTRUMENT MAINTENANCE DATE / TIME Conductance Subsystem pH Subsystem Cleaned Electrodes Cleaned Electrodes Temp Cert Device # TEMP (deg C)Adjustment Not Available Adjustment Not Available ORP Temp.ORP Temp. Calibration Pass TURB (ntu)Calibration Accepted Calibration Accepted DO (mg/L)Calibration Accepted Buffer Temp. Calibration Accepted Calibration Pass pH (units) Calibration Accepted Calibration Pass Calibration Accepted Calibration Pass Calibration Accepted Calibration Pass Buffer Temp.Buffer Temp. Specifc conductance checkpoint (used if sampled well is outside of initial calibration range). SPEC. COND. CHECK (uS/cm) SPEC. COND. (uS/cm) Instrument Zeroed Zero Pass Calibration Accepted Calibration Pass Calibration Accepted Calibration Pass Calibration Date / Time 30-Jul-15 4:50 31-Jul-15 6:45 741.7 741.9 Parameter Calibration Results Calibration Results CALIBRATION BP (mmHg)CALIBRATION BP (mmHg) COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:3858 ANALYZER MODEL#:MS5 66121 PROCEDURE #:HYDROLAB 3210.5 VALIDATED BY: FIELD SAMPLING CALIBRATION FORM STUDY:McGUIRE NUCLEAR STATION - LANDFILL 1 GROUNDWATER MONITORING DATE (s):July 30, 2015 SURFACE UNIT READER:LDC OTHER EQUIPMENT:TURBIDIMETER NO.2 - 3260-GW Mostly sunny, calm, 75 to 90 deg F ANALYZER SERIAL #: WEATHER CONDITIONS: DATE:TIME:DATE:TIME: Calibation Instrument Standard Instrument Standard Standard Value Value Value Value SS 0.0 ▬/▬►0.0 0.0 ▬/▬►0.0 SS 229.6 ▬▬►227 223.5 ▬/▬►227 SS 75.3 ▬/▬►75 71.9 ▬/▬►75 SS ▬/▬►▬/▬► B (7.00)6.95 ▬▬►7.02 7.04 ▬/▬►7.02 B (4.00)4.05 ▬▬►4.00 3.98 ▬/▬►4.00 B (10.00)10.05 ▬/▬►10.04 10.11 ▬/▬►10.04 20.84 20.68 pH Check B (7.00)▬▬► Time: SS (7.00)288 ▬▬►294 292 ▬/▬►294 SS (4.00)N/A ▬/▬►469 N/A ▬/▬►469 20.63 20.54 W 7.90 8.00 W 8.00 8.10 AW 7.91 ▬▬►7.95 8.08 ▬/▬►8.05 SS 52.3 ▬/▬►52.9 52.7 ▬/▬►52.9 NIST N/A ▬/▬►N/A N/A ▬/▬►N/A KEY: NOTES: SS = Standard solution AW = Average Winkler ▬/▬►= Not Adjusted To (mmHg) B = Buffer W = Winkler ▬▬► = Adjusted To N/A = Not Applicable Replaced DO electrolyte See Notes Field Barometric Pressure Beginning BP 740.6 (mmHg)Ending BP 741.2 Tested - OK See Notes Tested - OK See Notes Dissolved Oxygen Subsystem Replaced Teflon Membrane Cleaned Electrode Tested - OK See Notes Oxidation Reduction Subsystem Temperature Subsystem Cleaned Electrode Cleaned Electrode Tested - OK Replaced ref Electrode KCL See Notes Replaced Ref. Electrode Tip INSTRUMENT MAINTENANCE DATE / TIME Conductance Subsystem pH Subsystem Cleaned Electrodes Cleaned Electrodes Temp Cert Device # TEMP (deg C)Adjustment Not Available Adjustment Not Available ORP Temp.ORP Temp. Calibration Pass TURB (ntu)Calibration Accepted Calibration Accepted DO (mg/L)Calibration Accepted Buffer Temp. Calibration Accepted Calibration Pass pH (units) Calibration Accepted Calibration Pass Calibration Accepted Calibration Pass Calibration Accepted Calibration Pass Buffer Temp.Buffer Temp. Specifc conductance checkpoint (used if sampled well is outside of initial calibration range). SPEC. COND. CHECK (uS/cm) SPEC. COND. (uS/cm) Instrument Zeroed Zero Pass Calibration Accepted Calibration Pass Calibration Accepted Calibration Pass Calibration Date / Time 30-Jul-15 4:40 31-Jul-15 6:40 CALIBRATION BP (mmHg)741.7 741.9 Parameter Calibration Results Calibration Results CALIBRATION BP (mmHg) COLLECTORS:LDC, PSP SURFACE UNIT SERIAL #:S05042 ANALYZER MODEL#:MS5 66120 PROCEDURE #:HYDROLAB 3210.5 VALIDATED BY: FIELD SAMPLING CALIBRATION FORM STUDY:McGUIRE NUCLEAR STATION - LANDFILL 1 GROUNDWATER MONITORING DATE (s):July 30, 2015 SURFACE UNIT READER:PSP OTHER EQUIPMENT:TURBIDIMETER NO.1 - 3260-GW Mostly sunny, calm, 75 to 90 deg F 58.55 68.55 35 (psi)9 (sec)(sec) (gal) 6.26 (gal) @ QC By:< 2.0 DATE TIME DISSOLVED OXYGEN 25.0 231 0.42 0.50234 7/30/2015 1110 Sample preservation verified to pH (units) ORP (ft)(YES/NO) 6.50 NO 16.18 108 6.08 16.21 VOLUME EVACUATION COND. PURGE METHOD Conventional DISCHARGERECHARGEPRESSURE 6 PUMP CONTROLLER SETTINGS 0.1631CONVERSION FACTOR Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) 6.26WELL VOLUME (gal) FIELD CREW LDC, PSP MONITORING WELL INFORMATION 2 N/A PROCEDURE NO 3175.2DUKE ENERGY GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING SITE NAME McGUIRE NUCLEAR STATION PERMIT #60-04 SITE ID PROJECT NAME LANDFILL 1 GROUNDWATER MONITORING SAMPLING DATE(s)30-Jul-2015 63.55 68.05PUMP INTAKE DEPTH (ft TOC)68.55 TOC ELEV (ft msl) GS ELEV (ft msl) 730.23 729.58 WELL/LOCATION NAME MW-1 SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 WELL DEPTH (ft TOC) WELL DIAMETER (in)MIDDLE OF WETTED SCREEN (ft toc) WELL VOL SCREEN INTERVAL (ft TOC)TO SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC)30.19 WATER COLUMN (ft)38.36 EQUIPMENT INFORMATION LEVEL METER SERIAL#26054 SAMPLING EQUIPMENT TUBING DIAMETER (in)1/2 OD QED T1200 PURGE COMPLETE TEMP SPECIFIC pH TURBIDITY WATER ELEVATION (ft msl)700.04 APPEARANCE DETECTED ODOR None Normal WATER LEVEL AFTER PURGE *(recalculates on current water level)(deg C)(umho/cm)(SU)(NTU)(mV-NHE)(mg/L) 187.0 239 0.62 6.50 NO 6.50 NO 16.26 108 6.10 6.50 NO 16.31 109 6.08 25.5 231 0.44 108 6.09 34.8 COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY 6.50 NO 16.33 108 6.11 10.0 231 0.43 LDC 0 TOTAL PURGE VOLUME 32.50 * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column WELL CASING WELL CONDITION PROTECTIVE CASING WELL PAD WELL TAG Good Condition Good Condition Good Condition SAMPLING NOTES QC for rad collected. ADDITIONAL WELL CONDITION NOTES Good Tag 78.22 88.22 42 (psi)5 (sec)(sec) (gal) 9.32 (gal) @ QC By: SAMPLING NOTES PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 28.50 LDC 7/30/2015 1050 0 9.50 NO 16.25 97 6.12 2.0 234 0.16 9.50 NO 16.30 96 6.13 4.0 233 0.18 OXYGEN (recalculates on current water level)(mV-NHE)(mg/L) 9.50 NO 16.14 95 6.14 6.6 238 (ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU) 0.23 PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND. (gal) DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC)31.10 WATER COLUMN (ft)57.12 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)699.51 WELL VOLUME 9.32 PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 10 26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional MONITORING WELL INFORMATION WELL DIAMETER (in)2 TOC ELEV (ft msl)730.61 MIDDLE OF WETTED SCREEN (ft toc)83.22 SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC)88.22 GS ELEV (ft msl)729.75 PUMP INTAKE DEPTH (ft TOC)87.72 PROJECT NAME LANDFILL 1 GROUNDWATER MONITORING FIELD CREW LDC, PSP SAMPLING DATE(s)30-Jul-2015 WELL/LOCATION NAME MW-1D SITE NAME McGUIRE NUCLEAR STATION PERMIT #60-04 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.2 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING 67.57 77.57 48 (psi)14 (sec)(sec) (gal) 3.96 (gal) @ QC By: SITE NAME McGUIRE NUCLEAR STATION PERMIT #60-04 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.2 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING PROJECT NAME LANDFILL 1 GROUNDWATER MONITORING FIELD CREW LDC, PSP SAMPLING DATE(s)30-Jul-2015 WELL/LOCATION NAME MW-2A MONITORING WELL INFORMATION WELL DIAMETER (in)2 TOC ELEV (ft msl)739.67 MIDDLE OF WETTED SCREEN (ft toc)72.57 SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC)77.57 GS ELEV (ft msl)736.96 PUMP INTAKE DEPTH (ft TOC)77.07 PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 6 26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC)53.29 WATER COLUMN (ft)24.28 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)686.38 WELL VOLUME 3.96 (gal) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND.OXYGEN (recalculates on current water level)(mV-NHE)(mg/L) 4.00 NO 16.58 93 6.62 3.1 393 (ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU) 6.24 4.00 NO 17.07 96 6.51 1.4 366 5.66 4.00 NO 17.03 96 6.53 1.6 377 5.24 CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 12.00 LDC 7/30/2015 0745 0 TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag SAMPLING NOTES 98.82 108.82 50 (psi)8 (sec)(sec) (gal) 8.73 (gal) @ QC By: SITE NAME McGUIRE NUCLEAR STATION PERMIT #60-04 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.2 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING PROJECT NAME LANDFILL 1 GROUNDWATER MONITORING FIELD CREW LDC, PSP SAMPLING DATE(s)30-Jul-2015 WELL/LOCATION NAME MW-2D MONITORING WELL INFORMATION WELL DIAMETER (in)2 TOC ELEV (ft msl)740.77 MIDDLE OF WETTED SCREEN (ft toc)103.82 SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC)108.82 GS ELEV (ft msl)737.41 PUMP INTAKE DEPTH (ft TOC)108.32 PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 7 26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC)55.27 WATER COLUMN (ft)53.55 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)685.50 WELL VOLUME 8.73 (gal) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND.OXYGEN (recalculates on current water level)(mV-NHE)(mg/L) 9.00 NO 16.71 62 6.95 4.7 358 (ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU) 10.61 9.00 NO 16.90 62 6.88 2.1 335 9.15 9.00 NO 16.81 62 6.89 1.4 343 8.91 CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 27.00 LDC 7/30/2015 0835 0 TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag SAMPLING NOTES 63.64 73.64 38 (psi)10 (sec)(sec) (gal) 2.52 (gal) @ QC By: SITE NAME McGUIRE NUCLEAR STATION PERMIT #60-04 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.2 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING PROJECT NAME LANDFILL 1 GROUNDWATER MONITORING FIELD CREW LDC, PSP SAMPLING DATE(s)30-Jul-2015 WELL/LOCATION NAME MW-3 MONITORING WELL INFORMATION WELL DIAMETER (in)2 TOC ELEV (ft msl)728.43 MIDDLE OF WETTED SCREEN (ft toc)68.64 SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC)73.64 GS ELEV (ft msl)724.98 PUMP INTAKE DEPTH (ft TOC)73.14 PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 10 26055 SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC)58.16 WATER COLUMN (ft)15.48 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)670.27 WELL VOLUME 2.52 (gal) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND.OXYGEN (recalculates on current water level)(mV-NHE)(mg/L) 3.00 NO 15.52 65 6.15 5.6 416 (ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU) 4.41 2.75 NO 15.58 73 6.28 1.7 406 5.51 2.75 NO 15.54 71 6.24 2.6 415 5.18 2.75 NO 15.59 75 6.30 1.3 410 5.72 CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 11.25 PSP 7/30/2015 0935 0 TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Wasps Lid is bent so wasps can get inside, well pad is loose. WELL PAD Undermined / Washed-out WELL CASING Good Condition WELL TAG Good Tag SAMPLING NOTES 80.19 90.19 48 (psi)14 (sec)(sec) (gal) 5.23 (gal) @ QC By: SITE NAME McGUIRE NUCLEAR STATION PERMIT #60-04 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.2 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING PROJECT NAME LANDFILL 1 GROUNDWATER MONITORING FIELD CREW LDC, PSP SAMPLING DATE(s)30-Jul-2015 WELL/LOCATION NAME MW-3D MONITORING WELL INFORMATION WELL DIAMETER (in)2 TOC ELEV (ft msl)728.39 MIDDLE OF WETTED SCREEN (ft toc)85.19 SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC)90.19 GS ELEV (ft msl)724.98 PUMP INTAKE DEPTH (ft TOC)89.69 PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 6 26055 SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC)58.12 WATER COLUMN (ft)32.07 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)670.27 WELL VOLUME 5.23 (gal) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND.OXYGEN (recalculates on current water level)(mV-NHE)(mg/L) 5.25 NO 15.94 105 6.51 0.8 362 (ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU) 2.78 5.25 NO 15.97 113 6.52 2.1 356 3.06 5.25 NO 15.89 114 6.52 0.9 360 2.58 5.25 NO 15.76 114 6.52 1.6 357 3.08 CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 21.00 PSP 7/30/2015 1040 0 TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Wasps Lid is bent so wasps can get in. Well pad is Loose WELL PAD Minor Cracks WELL CASING Good Condition WELL TAG Good Tag SAMPLING NOTES 64.15 74.15 45 (psi)45 (sec)(sec) (gal) 1600 (ml) 495 (ml) 2095 (ml)=0.55 (gal)@ QC By: SITE NAME McGUIRE NUCLEAR STATION PERMIT #60-04 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.2 GROUNDWATER MONITORING DATA SHEET FOR EQUIPMENT PURGE ONLY SAMPLING PROJECT NAME LANDFILL 1 GROUNDWATER MONITORING FIELD CREW LDC, PSP SAMPLING DATE(s)30-Jul-2015 WELL/LOCATION NAME MW-4 MONITORING WELL INFORMATION WELL DIAMETER (in)2 TOC ELEV (ft msl)741.13 MIDDLE OF WETTED SCREEN (ft toc)69.92 SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC)74.15 GS ELEV (ft msl)738.40 PUMP INTAKE DEPTH (ft TOC)73.65 PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 15 26055 SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Equip. Only Purge DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC)65.68 WATER COLUMN (ft)8.47 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)675.45 WELL VOLUME 1.38 INITIAL FLOW FINAL TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED (ft)(ml/min)(ft)(deg C)(umho/cm)(SU)(NTU)(mV-NHE)(mg/L) WATER LEVEL RATE WATER LEVEL COND.OXYGEN 4.1 451 1.09 N/A Tubing Volume Purged 0.75 Gallons EQUIPMENT PURGE ONLY SAMPLE CHLORINE (mg/l)Pump (Bladder) Volume 65.68 N/A 70.08 16.41 152 5.58 0 WELL CONDITION ADDITIONAL WELL CONDITION NOTES SAMPLE COLLECTED BY DATE TIME Total Purge Volume PSP 7/30/2015 0655 Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Damaged / Repair Required Hinge broken WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag SAMPLING NOTES 92.24 102.24 60 (psi)10 (sec)(sec) (gal) 5.88 (gal) @ QC By: SITE NAME McGUIRE NUCLEAR STATION PERMIT #60-04 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.2 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING PROJECT NAME LANDFILL 1 GROUNDWATER MONITORING FIELD CREW LDC, PSP SAMPLING DATE(s)30-Jul-2015 WELL/LOCATION NAME MW-4D MONITORING WELL INFORMATION WELL DIAMETER (in)2 TOC ELEV (ft msl)740.58 MIDDLE OF WETTED SCREEN (ft toc)97.24 SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC)102.24 GS ELEV (ft msl)738.25 PUMP INTAKE DEPTH (ft TOC)101.74 PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 10 26055 SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC)66.20 WATER COLUMN (ft)36.04 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)674.38 WELL VOLUME 5.88 (gal) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND.OXYGEN (recalculates on current water level)(mV-NHE)(mg/L) 6.00 NO 16.04 162 6.27 27.5 282 (ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU) 0.64 6.00 NO 16.07 173 6.32 2.5 243 0.26 6.00 NO 16.10 175 6.31 3.9 252 0.28 6.00 NO 16.06 174 6.34 1.4 238 0.26 CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 24.00 PSP 7/30/2015 0800 0 TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag SAMPLING NOTES 28.00 43.00 30 (psi)13 (sec)(sec) (gal) 0.89 (gal) @ QC By: SITE NAME McGUIRE NUCLEAR STATION PERMIT #60-04 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.2 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING PROJECT NAME LANDFILL 1 GROUNDWATER MONITORING FIELD CREW LDC, PSP SAMPLING DATE(s)30-Jul-2015 WELL/LOCATION NAME MW-4R MONITORING WELL INFORMATION WELL DIAMETER (in)2 TOC ELEV (ft msl)713.87 MIDDLE OF WETTED SCREEN (ft toc)43.00 SCREEN LENGTH (ft)15.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC)45.73 GS ELEV (ft msl)711.15 PUMP INTAKE DEPTH (ft TOC)45.23 PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 7 26055 SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional 0.89 DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC)40.27 WATER COLUMN (ft)5.46 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)673.60 WELL VOLUME (gal) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND.OXYGEN (recalculates on current water level)(mV -NEH)(mg/L) 1.00 NO 15.67 114 6.01 107.0 307 (ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU) 5.36 1.00 NO 16.58 117 6.00 8.9 369 5.18 1.00 NO 16.05 112 5.99 54.0 358 5.29 CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 3.00 PSP 7/30/2015 1135 0 TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag SAMPLING NOTES 72.60 87.60 60 (psi)10 (sec)(sec) (gal) 8.10 (gal) @ QC By: SITE NAME McGUIRE NUCLEAR STATION PERMIT #60-04 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.2 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING PROJECT NAME LANDFILL 1 GROUNDWATER MONITORING FIELD CREW LDC, PSP SAMPLING DATE(s)30-Jul-2015 WELL/LOCATION NAME MW-4DR MONITORING WELL INFORMATION WELL DIAMETER (in)2 TOC ELEV (ft msl)713.75 MIDDLE OF WETTED SCREEN (ft toc)82.90 SCREEN LENGTH (ft)15.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC)90.40 GS ELEV (ft msl)711.15 PUMP INTAKE DEPTH (ft TOC)89.90 PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 5 26055 SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional 8.10 DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC)40.76 WATER COLUMN (ft)49.64 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)672.99 WELL VOLUME (gal) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND.OXYGEN (recalculates on current water level)(mV -NEH)(mg/L) 9.00 56.90 NO 15.57 123 6.80 5.0 344 (ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU) 4.92 5.46 5.50 NO 15.58 129 6.81 3.2 351 4.94 5.50 NO 15.59 127 6.81 3.8 349 4.89 CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 20.00 PSP 7/30/2015 1210 0 TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag SAMPLING NOTES 23.45 38.45 25 (psi)13 (sec)(sec) (gal) 0.76 (gal) @ QC By: SITE NAME McGUIRE NUCLEAR STATION PERMIT #60-04 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.2 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING PROJECT NAME LANDFILL 1 GROUNDWATER MONITORING FIELD CREW LDC, PSP SAMPLING DATE(s)30-Jul-2015 WELL/LOCATION NAME MW-11 MONITORING WELL INFORMATION WELL DIAMETER (in)2 TOC ELEV (ft msl)722.60 MIDDLE OF WETTED SCREEN (ft toc)36.11 SCREEN LENGTH (ft)15.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC)38.45 GS ELEV (ft msl)720.10 PUMP INTAKE DEPTH (ft TOC)37.95 PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 7 26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC)33.77 WATER COLUMN (ft)4.68 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)688.83 WELL VOLUME 0.76 (gal) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND.OXYGEN (recalculates on current water level)(mV-NHE)(mg/L) 1.00 35.67 NO 17.71 20 5.10 12.5 425 (ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU) 5.16 0.45 0.50 NO 18.63 20 5.10 8.1 433 5.30 0.50 NO 18.49 19 5.09 8.3 431 5.32 CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 2.00 LDC 7/30/2015 1215 0 TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag SAMPLING NOTES 91.55 101.55 50 (psi)8 (sec)(sec) (gal) 10.95 (gal) @ QC By: SITE NAME McGUIRE NUCLEAR STATION PERMIT #60-04 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.2 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING PROJECT NAME LANDFILL 1 GROUNDWATER MONITORING FIELD CREW LDC, PSP SAMPLING DATE(s)30-Jul-2015 WELL/LOCATION NAME MW-11D MONITORING WELL INFORMATION WELL DIAMETER (in)2 TOC ELEV (ft msl)723.14 MIDDLE OF WETTED SCREEN (ft toc)96.55 SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC)101.55 GS ELEV (ft msl)720.84 PUMP INTAKE DEPTH (ft TOC)101.05 See note below PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 7 26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC)34.39 WATER COLUMN (ft)67.16 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)688.75 WELL VOLUME 10.95 (gal) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND.OXYGEN (recalculates on current water level)(mV-NHE)(mg/L) 11.00 60.27 NO 15.63 31 5.75 16.5 403 (ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU) 6.42 6.73 6.01 6.25 NO 15.49 33 5.80 5.3 407 6.53 7.00 64.71 NO 15.54 32 5.79 7.0 401 6.52 CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 24.25 LDC 7/30/2015 1310 0 TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag SAMPLING NOTES After initial well volume is removed - WL drops to 65 ft - recalculate well volume and use for subsequent readings. 14.49 29.49 18 (psi)14 (sec)(sec) (gal) 0.22 (gal) @ QC By: SITE NAME McGUIRE NUCLEAR STATION PERMIT #60-04 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.2 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING PROJECT NAME LANDFILL 1 GROUNDWATER MONITORING FIELD CREW LDC, PSP SAMPLING DATE(s)30-Jul-2015 WELL/LOCATION NAME MW-12 MONITORING WELL INFORMATION WELL DIAMETER (in)2 TOC ELEV (ft msl)724.81 MIDDLE OF WETTED SCREEN (ft toc)28.81 SCREEN LENGTH (ft)15.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC)29.49 GS ELEV (ft msl)722.21 PUMP INTAKE DEPTH (ft TOC)28.99 No sample - insufficient volume / recharge PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 6 26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional DETECTED ODOR CONVERSION FACTOR 0.1631 APPEARANCE SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC)28.12 WATER COLUMN (ft)1.37 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)696.69 WELL VOLUME 0.22 (gal) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND.OXYGEN (recalculates on current water level)(mV-NHE)(mg/L) N/A (ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU) N/A CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 0.00 LDC 7/30/2015 1340 TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units) PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag SAMPLING NOTES No sample - insufficient volume / recharge - would not pump. 58.42 68.42 35 (psi)10 (sec)(sec) (gal) 6.43 (gal) @ QC By: SITE NAME McGUIRE NUCLEAR STATION PERMIT #60-04 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.2 GROUNDWATER MONITORING DATA SHEET FOR CONVENTIONAL SAMPLING PROJECT NAME LANDFILL 1 GROUNDWATER MONITORING FIELD CREW LDC, PSP SAMPLING DATE(s)30-Jul-2015 WELL/LOCATION NAME MW-12D MONITORING WELL INFORMATION WELL DIAMETER (in)2 TOC ELEV (ft msl)724.77 MIDDLE OF WETTED SCREEN (ft toc)63.42 SCREEN LENGTH (ft)10.00 ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC)68.42 GS ELEV (ft msl)722.21 PUMP INTAKE DEPTH (ft TOC)67.92 PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE 10 26054 SAMPLING EQUIPMENT QED T1200 PURGE METHOD TUBING DIAMETER (in)1/2 OD Conventional 6.43 DETECTED ODOR None CONVERSION FACTOR 0.1631 APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC)28.98 WATER COLUMN (ft)39.44 Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)695.79 WELL VOLUME (gal) PURGE WATER LEVEL AFTER PURGE * COMPLETE TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED WELL VOL VOLUME EVACUATION COND.OXYGEN (recalculates on current water level)(mV-NHE)(mg/L) 6.50 42.38 NO 15.21 76 6.35 10.0 371 (ft)(YES/NO)(deg C)(umho/cm)(SU)(NTU) 7.76 4.25 4.25 NO 15.24 77 6.33 7.1 374 7.69 4.25 NO 15.23 76 6.36 9.1 373 7.71 CHLORINE (mg/l)SAMPLE COLLECTED BY DATE TIME 15.00 LDC 7/30/2015 1430 0 TOTAL PURGE VOLUME * Optional measurement to recalculate well volume when purging results in substantial drawdown of water column COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING Good Condition WELL PAD Good Condition WELL CASING Good Condition WELL TAG Good Tag SAMPLING NOTES 0.00 0.00 N/A (psi)N/A (sec)(sec) (gal) (ft)=(in)@ QC By: SITE NAME McGUIRE NUCLEAR STATION PERMIT #60-04 SITE ID N/A DUKE ENERGY PROCEDURE NO 3175.2 GROUNDWATER MONITORING DATA SHEET FOR NO PURGE SAMPLING PROJECT NAME LANDFILL 1 GROUNDWATER MONITORING FIELD CREW LDC, PSP SAMPLING DATE(s)30-Jul-2015 WELL/LOCATION NAME SW-1 MONITORING WELL INFORMATION WELL DIAMETER (in)TOC ELEV (ft msl)N/A MIDDLE OF WETTED SCREEN (ft toc) SCREEN LENGTH (ft)ELEV REF NAVD 88 SCREEN INTERVAL (ft TOC)TO EQUIPMENT INFORMATION LEVEL METER SERIAL# WELL DEPTH (ft TOC)GS ELEV (ft msl)PUMP INTAKE DEPTH (ft TOC)N/A PUMP CONTROLLER SETTINGS PRESSURE RECHARGE DISCHARGE N/A N/A SAMPLING EQUIPMENT PERISTALTIC PUMP PURGE METHOD TUBING DIAMETER (in)3/8 OD No Purge DETECTED ODOR None CONVERSION FACTOR APPEARANCE Normal SAMPLING INFORMATION INITIAL DEPTH TO WATER (ft TOC)N/A WATER COLUMN (ft)Well Volume = water column X conversion factor (Conversion factor dependent on well diameter and selected well volume units) WATER ELEVATION (ft msl)WELL VOLUME TEMP SPECIFIC pH TURBIDITY ORP DISSOLVED TIME PSP 7/30/2015 LENGTH DEPTH (top)DEPLOYED COND.OXYGEN (inches)(ft TOC)(deg C)(umho/cm)(SU) HYDRASLEEVE DEPLOYED DATE (NTU)(mV-NHE)(mg/L) N/A N/A N/A 25.87 124 7.48 19.6 1250 171 6.97 0 N/A Deployed Water Column In Screen Above Top Of Hydrasleeve NO PURGE SAMPLE CHLORINE (mg/l)Top Weight SAMPLE COLLECTED BY DATE WELL CONDITION ADDITIONAL WELL CONDITION NOTES Sample preservation verified to pH (units)< 2.0 PROTECTIVE CASING WELL PAD WELL CASING WELL TAG SAMPLING NOTES PERMIT # MW-1 MW-1D MW-2 MW-2D MW-3 MW-3D MW-4 MW-4D MW-11 MW-11D MW-12 MW-12D SW-1 MW-4R MW-4PR YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES N/A YES YES YES YES YES YES YES YES YES YES YES YES YES YES N/A YES YES YES YES YES YES YES YES YES YES YES YES YES YES N/A YES YES YES YES YES YES SEE NOTE SEE NOTE YES YES YES YES YES YES N/A YES YES YES YES YES YES YES YES SEE NOTE SEE NOTE SEE NOTE YES YES YES YES YES N/A YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES N/A YES YES YES YES YES YES YES YES YES YES YES YES YES YES N/A YES YES YES YES YES YES YES YES YES YES YES YES YES YES N/A YES YES Lacks required information - Total well depth Lacks required information - Depth to screen Lacks required information - Non potable tag NOTE:MW-3 and MW-3D have bent lids on protective casing allowing wasps inside (active nests), and both concrete pads were loose. MW-3D concrete pad has minor cracks. MW-4 has a broken hinge on protective casing lid. Lacks required information - Completion date FLUSH MOUNT WELLS Vault in good condition Water inside vault Vault bolt holes broken or stripped Bolts stripped Vault lid cracked or broken WELL ID TAGS Well tag in good condition Well tag missing Well tag damaged / illegible Lacks required information - Driller Reg # Replaced damaged well cap Fire ants around concrete pad WELL PROTECTIVE CASINGS Casing in good condition Damaged casing / still functional Damaged casing / repair required Broken hinge on protective lid Wasp nest inside protective casing Ants inside protective casing WELL CAPS Well cap in good conditon Damaged / needs replacement Undermined / washing out Lock in good condition Lock rusted, difficult to open / needs replacing Replaced damaged lock WELL CASINGS Casing in good condition Damaged casing / still functional Damaged casing / repair required CONCRETE PADS Pad in good condition Minor cracks Major cracks / broken / repair required WELL LOCK CONDITION PAGE 1 OF 1 ACCESS TO WELLS Access cleared into well Access cleared around well Tall grass or weeds - needs mowing Road washing out / muddy / needs grading Fallen tree blocking access WELL SECURITY Well found locked Well found unlocked SITE CONTACT John Williamson, Bill Spencer FIELD CREW LDC, PSP WEATHER Mostly sunny, calm, 75 to 90 deg F. NORTH CAROLINA GROUNDWATER SAMPLING SITE CHECKLIST LOCATION / SITE McGUIRE NUCLEAR STATION - LANDFILL #1 GROUNDWATER MONITORING 60-04 SAMPLE DATE July 30, 2015 WELL DEPTH TO WATER Purge AVG *WELL EVAC SPECIFIC WELL DEPTH WATER ELEV.Method PMP RATE VOL VOL EVAC TEMP CONDUCTANCE pH TURBIDITY ORP DODATENO.(feet-toc)(feet-toc)(feet)APPEARANCE ODOR (ml/min)(gal)(gal)(yes/no)(deg C)(umho/cm)(units)(NTU)(mV-NHE)(mg/l) 7/30/2015 MW-1 68.55 30.19 700.04 Normal None C N/A 6.26 32.50 NO 16.33 108 6.1 10.0 231 0.437/30/2015 MW-1D 88.22 31.10 699.51 Normal None C N/A 9.32 28.50 NO 16.25 97 6.1 2.0 234 0.167/30/2015 MW-2A 77.57 53.29 686.38 Normal None C N/A 3.96 12.00 NO 17.07 96 6.5 1.4 366 5.66 7/30/2015 MW-2D 108.82 55.27 685.50 Normal None C N/A 8.73 27.00 NO 16.90 62 6.9 2.1 335 9.157/30/2015 MW-3 73.64 58.16 670.27 Normal None C N/A 2.52 11.25 NO 15.59 75 6.3 1.3 410 5.727/30/2015 MW-3D 90.19 58.12 670.27 Normal None C N/A 5.23 21.00 NO 15.76 114 6.5 1.6 357 3.08 7/30/2015 MW-4 74.15 65.68 675.45 Normal None EOP N/A 1.38 0.55 N/A 16.41 152 5.6 4.1 451 1.09 7/30/2015 MW-4D 102.24 66.20 674.38 Normal None C N/A 5.88 24.00 NO 16.06 174 6.3 1.4 238 0.267/30/2015 MW-11 38.45 33.77 688.83 Normal None C N/A 0.76 2.00 NO 18.63 20 5.1 8.1 433 5.307/30/2015 MW-11D 101.55 34.39 688.75 Normal None C N/A 10.95 24.25 NO 15.49 33 5.8 5.3 407 6.53 7/30/2015 MW-12 29.49 28.12 696.69 0 0 C N/A 0.22 0.00 0.00 0 0.0 0.0 N/A N/A7/30/2015 MW-12D 68.42 28.98 695.79 Normal None C N/A 6.43 15.00 NO 15.24 77 6.3 7.1 374 7.697/30/2015 SW-1 N/A N/A N/A Normal None NP N/A N/A N/A N/A 25.87 124 7.5 19.6 171 6.97 7/30/2015 MW-4R 45.73 40.27 673.60 Normal None C N/A 0.89 3.00 NO 16.58 117 6.0 8.9 369 5.18 7/30/2015 MW-4DR 90.40 40.76 672.99 Normal None C N/A 8.10 20.00 NO 15.58 129 6.8 3.2 351 4.94 Purge Methods LF = Low FlowLF(M) = Low Flow (Mod.)C = Connventional NP = No Purge EOP = Equip. Only PurgeLO = Level Only * = Applicable to LF & LF(M) Purging Only McGUIRE NUCLEAR STATION LANDFILL 1 GROUNDWATER MONITORING GROUNDWATER MONITORING FIELD DATA PERMIT #60-04 B Appendix B Laboratory Report and Chain-of-Custody Forms 13339 Hagers Ferry RoadHuntersville, NC 28078-7929McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J15060650 Project Name:MCGUIRE - GW LF1 Lab Contact: Jason C Perkins Date:8/20/2015 Customer Address:13225 Hagers Ferry Rd Customer Name(s):TIM HUNSUCKER, C Campbell Mail Code: MG01CH Huntersville, NC 28078-8985 Phone: 980-875-5348 Report Authorized By:(Signature) Program Comments: Please contact the Program Manager (Jason C Perkins) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Jason C Perkins Page 1 of 77 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015020145 MCGUIRE 30-Jul-15 5:25 AM SC TRIP BLANK 2015020146 MCGUIRE 30-Jul-15 11:10 AM SC MW-1 2015020147 MCGUIRE 30-Jul-15 10:50 AM SC MW-1D 2015020148 MCGUIRE 30-Jul-15 7:45 AM SC MW-2A 2015020149 MCGUIRE 30-Jul-15 8:35 AM SC MW-2D 2015020150 MCGUIRE 30-Jul-15 9:35 AM PSP MW-3 2015020151 MCGUIRE 30-Jul-15 10:40 AM PSP MW-3D 2015020152 MCGUIRE 30-Jul-15 6:55 AM PSP MW-4 2015020153 MCGUIRE 30-Jul-15 8:00 AM PSP MW-4D 2015020154 MCGUIRE 30-Jul-15 12:15 PM SC MW-11 2015020155 MCGUIRE 30-Jul-15 1:10 PM SC MW-11D 2015020157 MCGUIRE 30-Jul-15 2:30 PM MW-12D 2015020158 MCGUIRE 30-Jul-15 12:50 PM PSP SW-1 2015020159 MCGUIRE 30-Jul-15 11:35 AM PSP MW-4R 2015020160 MCGUIRE 30-Jul-15 12:10 PM PSP MW-4DR 2015020161 MCGUIRE 30-Jul-15 2:35 PM PSP FIELD BLANK 16 Total Samples Page 2 of 77 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:DBA Account Date:8/20/2015 Electronic Data Deliverable (EDD) Sent Separately Page 3 of 77 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060650 2015020145 Collection Date:30-Jul-15 5:25 AM Site:TRIP BLANK Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF VOLATILES - (Analysis Performed by Test America) Benzene Complete Vendor Method V_T. America Page 4 of 77 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060650 2015020146 Collection Date:30-Jul-15 11:10 AM Site:MW-1 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)53 mg/L (CaCO3)SM2320B 08/03/2015 14:59 TJA7067201 INORGANIC IONS BY IC Chloride 1.7 mg/L EPA 300.0 08/03/2015 12:28 BGN90340.1 1 Sulfate 0.27 mg/L EPA 300.0 08/03/2015 12:28 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 08/03/2015 14:24 ACPAYNE0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.223 mg/L EPA 200.7 08/03/2015 12:27 FCJORDA0.005 1 Calcium (Ca)6.98 mg/L EPA 200.7 08/03/2015 12:27 FCJORDA0.01 1 Chromium (Cr)< 0.005 mg/L EPA 200.7 08/03/2015 12:27 FCJORDA0.005 1 Magnesium (Mg)3.23 mg/L EPA 200.7 08/03/2015 12:27 FCJORDA0.005 1 Potassium (K)1.10 mg/L EPA 200.7 08/03/2015 12:27 FCJORDA0.1 1 Silver (Ag)< 0.005 mg/L EPA 200.7 08/03/2015 12:27 FCJORDA0.005 1 Sodium (Na)6.12 mg/L EPA 200.7 08/03/2015 12:27 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020A 08/03/2015 17:01 JAHERMA11 Cadmium (Cd)< 1 ug/L SW 6020A 08/03/2015 17:01 JAHERMA11 Lead (Pb)< 1 ug/L SW 6020A 08/03/2015 17:01 JAHERMA11 Selenium (Se)< 1 ug/L SW 6020A 08/03/2015 17:01 JAHERMA11 VOLATILES - (Analysis Performed by Test America) Benzene Complete Vendor Method V_T. America Page 5 of 77 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060650 2015020147 Collection Date:30-Jul-15 10:50 AM Site:MW-1D Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)47 mg/L (CaCO3)SM2320B 08/03/2015 14:59 TJA7067201 INORGANIC IONS BY IC Chloride 1.5 mg/L EPA 300.0 08/03/2015 13:22 BGN90340.1 1 Sulfate 0.31 mg/L EPA 300.0 08/03/2015 13:22 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 08/03/2015 14:31 ACPAYNE0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.099 mg/L EPA 200.7 08/03/2015 12:39 FCJORDA0.005 1 Calcium (Ca)7.10 mg/L EPA 200.7 08/03/2015 12:39 FCJORDA0.01 1 Chromium (Cr)< 0.005 mg/L EPA 200.7 08/03/2015 12:39 FCJORDA0.005 1 Magnesium (Mg)2.44 mg/L EPA 200.7 08/03/2015 12:39 FCJORDA0.005 1 Potassium (K)1.05 mg/L EPA 200.7 08/03/2015 12:39 FCJORDA0.1 1 Silver (Ag)< 0.005 mg/L EPA 200.7 08/03/2015 12:39 FCJORDA0.005 1 Sodium (Na)6.76 mg/L EPA 200.7 08/03/2015 12:39 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020A 08/03/2015 16:40 JAHERMA11 Cadmium (Cd)< 1 ug/L SW 6020A 08/03/2015 16:40 JAHERMA11 Lead (Pb)< 1 ug/L SW 6020A 08/03/2015 16:40 JAHERMA11 Selenium (Se)< 1 ug/L SW 6020A 08/03/2015 16:40 JAHERMA11 VOLATILES - (Analysis Performed by Test America) Benzene Complete Vendor Method V_T. America Page 6 of 77 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060650 2015020148 Collection Date:30-Jul-15 7:45 AM Site:MW-2A Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)42 mg/L (CaCO3)SM2320B 08/03/2015 14:59 TJA7067201 INORGANIC IONS BY IC Chloride 1.4 mg/L EPA 300.0 08/03/2015 13:40 BGN90340.1 1 Sulfate 0.60 mg/L EPA 300.0 08/03/2015 13:40 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 08/03/2015 14:33 ACPAYNE0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.027 mg/L EPA 200.7 08/03/2015 12:43 FCJORDA0.005 1 Calcium (Ca)9.51 mg/L EPA 200.7 08/03/2015 12:43 FCJORDA0.01 1 Chromium (Cr)< 0.005 mg/L EPA 200.7 08/03/2015 12:43 FCJORDA0.005 1 Magnesium (Mg)2.58 mg/L EPA 200.7 08/03/2015 12:43 FCJORDA0.005 1 Potassium (K)0.402 mg/L EPA 200.7 08/03/2015 12:43 FCJORDA0.1 1 Silver (Ag)< 0.005 mg/L EPA 200.7 08/03/2015 12:43 FCJORDA0.005 1 Sodium (Na)6.24 mg/L EPA 200.7 08/03/2015 12:43 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020A 08/03/2015 17:08 JAHERMA11 Cadmium (Cd)< 1 ug/L SW 6020A 08/03/2015 17:08 JAHERMA11 Lead (Pb)< 1 ug/L SW 6020A 08/03/2015 17:08 JAHERMA11 Selenium (Se)< 1 ug/L SW 6020A 08/03/2015 17:08 JAHERMA11 VOLATILES - (Analysis Performed by Test America) Benzene Complete Vendor Method V_T. America Page 7 of 77 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060650 2015020149 Collection Date:30-Jul-15 8:35 AM Site:MW-2D Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)25 mg/L (CaCO3)SM 2320B4d 08/06/2015 15:15 TJA706751 INORGANIC IONS BY IC Chloride 1.2 mg/L EPA 300.0 08/03/2015 13:57 BGN90340.1 1 Sulfate 0.32 mg/L EPA 300.0 08/03/2015 13:57 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 08/03/2015 14:36 ACPAYNE0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.014 mg/L EPA 200.7 08/03/2015 12:46 FCJORDA0.005 1 Calcium (Ca)5.22 mg/L EPA 200.7 08/03/2015 12:46 FCJORDA0.01 1 Chromium (Cr)< 0.005 mg/L EPA 200.7 08/03/2015 12:46 FCJORDA0.005 1 Magnesium (Mg)1.54 mg/L EPA 200.7 08/03/2015 12:46 FCJORDA0.005 1 Potassium (K)0.325 mg/L EPA 200.7 08/03/2015 12:46 FCJORDA0.1 1 Silver (Ag)< 0.005 mg/L EPA 200.7 08/03/2015 12:46 FCJORDA0.005 1 Sodium (Na)5.22 mg/L EPA 200.7 08/03/2015 12:46 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020A 08/03/2015 17:15 JAHERMA11 Cadmium (Cd)< 1 ug/L SW 6020A 08/03/2015 17:15 JAHERMA11 Lead (Pb)< 1 ug/L SW 6020A 08/03/2015 17:15 JAHERMA11 Selenium (Se)< 1 ug/L SW 6020A 08/03/2015 17:15 JAHERMA11 VOLATILES - (Analysis Performed by Test America) Benzene Complete Vendor Method V_T. America Page 8 of 77 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060650 2015020150 Collection Date:30-Jul-15 9:35 AM Site:MW-3 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)37 mg/L (CaCO3)SM2320B 08/03/2015 14:59 TJA7067201 INORGANIC IONS BY IC Chloride 1.3 mg/L EPA 300.0 08/03/2015 14:15 BGN90340.1 1 Sulfate 0.42 mg/L EPA 300.0 08/03/2015 14:15 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 08/03/2015 14:38 ACPAYNE0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.041 mg/L EPA 200.7 08/03/2015 12:50 FCJORDA0.005 1 Calcium (Ca)7.09 mg/L EPA 200.7 08/03/2015 12:50 FCJORDA0.01 1 Chromium (Cr)< 0.005 mg/L EPA 200.7 08/03/2015 12:50 FCJORDA0.005 1 Magnesium (Mg)3.01 mg/L EPA 200.7 08/03/2015 12:50 FCJORDA0.005 1 Potassium (K)0.645 mg/L EPA 200.7 08/03/2015 12:50 FCJORDA0.1 1 Silver (Ag)< 0.005 mg/L EPA 200.7 08/03/2015 12:50 FCJORDA0.005 1 Sodium (Na)4.02 mg/L EPA 200.7 08/03/2015 12:50 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020A 08/03/2015 17:22 JAHERMA11 Cadmium (Cd)< 1 ug/L SW 6020A 08/03/2015 17:22 JAHERMA11 Lead (Pb)1.60 ug/L SW 6020A 08/03/2015 17:22 JAHERMA11 Selenium (Se)< 1 ug/L SW 6020A 08/03/2015 17:22 JAHERMA11 VOLATILES - (Analysis Performed by Test America) Benzene Complete Vendor Method V_T. America Page 9 of 77 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060650 2015020151 Collection Date:30-Jul-15 10:40 AM Site:MW-3D Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)58 mg/L (CaCO3)SM2320B 08/03/2015 14:59 TJA7067201 INORGANIC IONS BY IC Chloride 1.4 mg/L EPA 300.0 08/03/2015 14:33 BGN90340.1 1 Sulfate 0.78 mg/L EPA 300.0 08/03/2015 14:33 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 08/03/2015 14:41 ACPAYNE0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.027 mg/L EPA 200.7 08/03/2015 12:54 FCJORDA0.005 1 Calcium (Ca)12.4 mg/L EPA 200.7 08/03/2015 12:54 FCJORDA0.01 1 Chromium (Cr)< 0.005 mg/L EPA 200.7 08/03/2015 12:54 FCJORDA0.005 1 Magnesium (Mg)4.31 mg/L EPA 200.7 08/03/2015 12:54 FCJORDA0.005 1 Potassium (K)0.806 mg/L EPA 200.7 08/03/2015 12:54 FCJORDA0.1 1 Silver (Ag)< 0.005 mg/L EPA 200.7 08/03/2015 12:54 FCJORDA0.005 1 Sodium (Na)5.78 mg/L EPA 200.7 08/03/2015 12:54 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020A 08/03/2015 17:29 JAHERMA11 Cadmium (Cd)< 1 ug/L SW 6020A 08/03/2015 17:29 JAHERMA11 Lead (Pb)< 1 ug/L SW 6020A 08/03/2015 17:29 JAHERMA11 Selenium (Se)< 1 ug/L SW 6020A 08/03/2015 17:29 JAHERMA11 VOLATILES - (Analysis Performed by Test America) Benzene Complete Vendor Method V_T. America Page 10 of 77 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060650 2015020152 Collection Date:30-Jul-15 6:55 AM Site:MW-4 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)88 mg/L (CaCO3)SM2320B 08/03/2015 14:59 TJA7067201 INORGANIC IONS BY IC Chloride 2.2 mg/L EPA 300.0 08/03/2015 14:51 BGN90340.1 1 Sulfate 0.95 mg/L EPA 300.0 08/03/2015 14:51 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 08/03/2015 14:43 ACPAYNE0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.070 mg/L EPA 200.7 08/03/2015 12:58 FCJORDA0.005 1 Calcium (Ca)13.7 mg/L EPA 200.7 08/03/2015 12:58 FCJORDA0.01 1 Chromium (Cr)< 0.005 mg/L EPA 200.7 08/03/2015 12:58 FCJORDA0.005 1 Magnesium (Mg)13.1 mg/L EPA 200.7 08/03/2015 12:58 FCJORDA0.005 1 Potassium (K)0.592 mg/L EPA 200.7 08/03/2015 12:58 FCJORDA0.1 1 Silver (Ag)< 0.005 mg/L EPA 200.7 08/03/2015 12:58 FCJORDA0.005 1 Sodium (Na)2.35 mg/L EPA 200.7 08/03/2015 12:58 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020A 08/03/2015 17:36 JAHERMA11 Cadmium (Cd)< 1 ug/L SW 6020A 08/03/2015 17:36 JAHERMA11 Lead (Pb)< 1 ug/L SW 6020A 08/03/2015 17:36 JAHERMA11 Selenium (Se)< 1 ug/L SW 6020A 08/03/2015 17:36 JAHERMA11 VOLATILES - (Analysis Performed by Test America) Benzene Complete Vendor Method V_T. America Page 11 of 77 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060650 2015020153 Collection Date:30-Jul-15 8:00 AM Site:MW-4D Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)90 mg/L (CaCO3)SM2320B 08/03/2015 14:59 TJA7067201 INORGANIC IONS BY IC Chloride 1.7 mg/L EPA 300.0 08/03/2015 15:09 BGN90340.1 1 Sulfate 0.26 mg/L EPA 300.0 08/03/2015 15:09 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 08/03/2015 14:45 ACPAYNE0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.044 mg/L EPA 200.7 08/03/2015 13:02 FCJORDA0.005 1 Calcium (Ca)18.4 mg/L EPA 200.7 08/03/2015 13:02 FCJORDA0.01 1 Chromium (Cr)< 0.005 mg/L EPA 200.7 08/03/2015 13:02 FCJORDA0.005 1 Magnesium (Mg)8.59 mg/L EPA 200.7 08/03/2015 13:02 FCJORDA0.005 1 Potassium (K)0.620 mg/L EPA 200.7 08/03/2015 13:02 FCJORDA0.1 1 Silver (Ag)< 0.005 mg/L EPA 200.7 08/03/2015 13:02 FCJORDA0.005 1 Sodium (Na)4.06 mg/L EPA 200.7 08/03/2015 13:02 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020A 08/03/2015 17:43 JAHERMA11 Cadmium (Cd)< 1 ug/L SW 6020A 08/03/2015 17:43 JAHERMA11 Lead (Pb)< 1 ug/L SW 6020A 08/03/2015 17:43 JAHERMA11 Selenium (Se)< 1 ug/L SW 6020A 08/03/2015 17:43 JAHERMA11 VOLATILES - (Analysis Performed by Test America) Benzene Complete Vendor Method V_T. America Page 12 of 77 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060650 2015020154 Collection Date:30-Jul-15 12:15 PM Site:MW-11 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)< 5 mg/L (CaCO3)SM 2320B4d 08/06/2015 15:15 TJA706751 INORGANIC IONS BY IC Chloride 1.5 mg/L EPA 300.0 08/03/2015 15:27 BGN90340.1 1 Sulfate 0.30 mg/L EPA 300.0 08/03/2015 15:27 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 08/03/2015 14:48 ACPAYNE0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.008 mg/L EPA 200.7 08/03/2015 13:06 FCJORDA0.005 1 Calcium (Ca)0.730 mg/L EPA 200.7 08/03/2015 13:06 FCJORDA0.01 1 Chromium (Cr)< 0.005 mg/L EPA 200.7 08/03/2015 13:06 FCJORDA0.005 1 Magnesium (Mg)0.644 mg/L EPA 200.7 08/03/2015 13:06 FCJORDA0.005 1 Potassium (K)< 0.1 mg/L EPA 200.7 08/03/2015 13:06 FCJORDA0.1 1 Silver (Ag)< 0.005 mg/L EPA 200.7 08/03/2015 13:06 FCJORDA0.005 1 Sodium (Na)1.03 mg/L EPA 200.7 08/03/2015 13:06 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020A 08/03/2015 17:50 JAHERMA11 Cadmium (Cd)< 1 ug/L SW 6020A 08/03/2015 17:50 JAHERMA11 Lead (Pb)< 1 ug/L SW 6020A 08/03/2015 17:50 JAHERMA11 Selenium (Se)< 1 ug/L SW 6020A 08/03/2015 17:50 JAHERMA11 VOLATILES - (Analysis Performed by Test America) Benzene Complete Vendor Method V_T. America Page 13 of 77 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060650 2015020155 Collection Date:30-Jul-15 1:10 PM Site:MW-11D Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)10 mg/L (CaCO3)SM 2320B4d 08/06/2015 15:15 TJA706751 INORGANIC IONS BY IC Chloride 1.3 mg/L EPA 300.0 08/03/2015 15:45 BGN90340.1 1 Sulfate 0.79 mg/L EPA 300.0 08/03/2015 15:45 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 08/03/2015 14:50 ACPAYNE0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.012 mg/L EPA 200.7 08/03/2015 13:09 FCJORDA0.005 1 Calcium (Ca)1.64 mg/L EPA 200.7 08/03/2015 13:09 FCJORDA0.01 1 Chromium (Cr)< 0.005 mg/L EPA 200.7 08/03/2015 13:09 FCJORDA0.005 1 Magnesium (Mg)0.967 mg/L EPA 200.7 08/03/2015 13:09 FCJORDA0.005 1 Potassium (K)0.156 mg/L EPA 200.7 08/03/2015 13:09 FCJORDA0.1 1 Silver (Ag)< 0.005 mg/L EPA 200.7 08/03/2015 13:09 FCJORDA0.005 1 Sodium (Na)3.58 mg/L EPA 200.7 08/03/2015 13:09 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020A 08/03/2015 17:57 JAHERMA11 Cadmium (Cd)< 1 ug/L SW 6020A 08/03/2015 17:57 JAHERMA11 Lead (Pb)< 1 ug/L SW 6020A 08/03/2015 17:57 JAHERMA11 Selenium (Se)< 1 ug/L SW 6020A 08/03/2015 17:57 JAHERMA11 VOLATILES - (Analysis Performed by Test America) Benzene Complete Vendor Method V_T. America Page 14 of 77 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060650 2015020157 Collection Date:30-Jul-15 2:30 PM Site:MW-12D Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)35 mg/L (CaCO3)SM2320B 08/03/2015 14:59 TJA7067201 INORGANIC IONS BY IC Chloride 2.6 mg/L EPA 300.0 08/03/2015 16:57 BGN90340.1 1 Sulfate < 0.1 mg/L EPA 300.0 08/03/2015 16:57 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 08/03/2015 14:57 ACPAYNE0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.011 mg/L EPA 200.7 08/03/2015 13:21 FCJORDA0.005 1 Calcium (Ca)7.95 mg/L EPA 200.7 08/03/2015 13:21 FCJORDA0.01 1 Chromium (Cr)< 0.005 mg/L EPA 200.7 08/03/2015 13:21 FCJORDA0.005 1 Magnesium (Mg)1.26 mg/L EPA 200.7 08/03/2015 13:21 FCJORDA0.005 1 Potassium (K)0.267 mg/L EPA 200.7 08/03/2015 13:21 FCJORDA0.1 1 Silver (Ag)< 0.005 mg/L EPA 200.7 08/03/2015 13:21 FCJORDA0.005 1 Sodium (Na)7.11 mg/L EPA 200.7 08/03/2015 13:21 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020A 08/03/2015 18:32 JAHERMA11 Cadmium (Cd)< 1 ug/L SW 6020A 08/03/2015 18:32 JAHERMA11 Lead (Pb)< 1 ug/L SW 6020A 08/03/2015 18:32 JAHERMA11 Selenium (Se)< 1 ug/L SW 6020A 08/03/2015 18:32 JAHERMA11 VOLATILES - (Analysis Performed by Test America) Benzene Complete Vendor Method V_T. America Page 15 of 77 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060650 2015020158 Collection Date:30-Jul-15 12:50 PM Site:SW-1 Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)58 mg/L (CaCO3)SM2320B 08/03/2015 14:59 TJA7067201 INORGANIC IONS BY IC Chloride 2.4 mg/L EPA 300.0 08/03/2015 17:50 BGN90340.1 1 Sulfate 1.3 mg/L EPA 300.0 08/03/2015 17:50 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 08/03/2015 15:04 ACPAYNE0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.031 mg/L EPA 200.7 08/03/2015 13:25 FCJORDA0.005 1 Calcium (Ca)12.2 mg/L EPA 200.7 08/03/2015 13:25 FCJORDA0.01 1 Chromium (Cr)< 0.005 mg/L EPA 200.7 08/03/2015 13:25 FCJORDA0.005 1 Magnesium (Mg)4.87 mg/L EPA 200.7 08/03/2015 13:25 FCJORDA0.005 1 Potassium (K)1.66 mg/L EPA 200.7 08/03/2015 13:25 FCJORDA0.1 1 Silver (Ag)< 0.005 mg/L EPA 200.7 08/03/2015 13:25 FCJORDA0.005 1 Sodium (Na)5.83 mg/L EPA 200.7 08/03/2015 13:25 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020A 08/03/2015 18:39 JAHERMA11 Cadmium (Cd)< 1 ug/L SW 6020A 08/03/2015 18:39 JAHERMA11 Lead (Pb)< 1 ug/L SW 6020A 08/03/2015 18:39 JAHERMA11 Selenium (Se)< 1 ug/L SW 6020A 08/03/2015 18:39 JAHERMA11 VOLATILES - (Analysis Performed by Test America) Benzene Complete Vendor Method V_T. America Page 16 of 77 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060650 2015020159 Collection Date:30-Jul-15 11:35 AM Site:MW-4R Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)57 mg/L (CaCO3)SM2320B 08/03/2015 14:59 TJA7067201 INORGANIC IONS BY IC Chloride 3.0 mg/L EPA 300.0 08/03/2015 18:08 BGN90340.1 1 Sulfate 0.39 mg/L EPA 300.0 08/03/2015 18:08 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 08/03/2015 15:06 ACPAYNE0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.014 mg/L EPA 200.7 08/03/2015 13:28 FCJORDA0.005 1 Calcium (Ca)10.0 mg/L EPA 200.7 08/03/2015 13:28 FCJORDA0.01 1 Chromium (Cr)< 0.005 mg/L EPA 200.7 08/03/2015 13:28 FCJORDA0.005 1 Magnesium (Mg)8.11 mg/L EPA 200.7 08/03/2015 13:28 FCJORDA0.005 1 Potassium (K)0.325 mg/L EPA 200.7 08/03/2015 13:28 FCJORDA0.1 1 Silver (Ag)< 0.005 mg/L EPA 200.7 08/03/2015 13:28 FCJORDA0.005 1 Sodium (Na)2.35 mg/L EPA 200.7 08/03/2015 13:28 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020A 08/03/2015 18:46 JAHERMA11 Cadmium (Cd)< 1 ug/L SW 6020A 08/03/2015 18:46 JAHERMA11 Lead (Pb)< 1 ug/L SW 6020A 08/03/2015 18:46 JAHERMA11 Selenium (Se)< 1 ug/L SW 6020A 08/03/2015 18:46 JAHERMA11 VOLATILES - (Analysis Performed by Test America) Benzene Complete Vendor Method V_T. America Page 17 of 77 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060650 2015020160 Collection Date:30-Jul-15 12:10 PM Site:MW-4DR Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY (FIXED END POINT 4.5) Alkalinity (mg/L CaCO3)66 mg/L (CaCO3)SM2320B 08/03/2015 14:59 TJA7067201 INORGANIC IONS BY IC Chloride 1.7 mg/L EPA 300.0 08/03/2015 18:26 BGN90340.1 1 Sulfate 1.2 mg/L EPA 300.0 08/03/2015 18:26 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 08/03/2015 15:09 ACPAYNE0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)0.014 mg/L EPA 200.7 08/03/2015 13:32 FCJORDA0.005 1 Calcium (Ca)14.6 mg/L EPA 200.7 08/03/2015 13:32 FCJORDA0.01 1 Chromium (Cr)< 0.005 mg/L EPA 200.7 08/03/2015 13:32 FCJORDA0.005 1 Magnesium (Mg)4.58 mg/L EPA 200.7 08/03/2015 13:32 FCJORDA0.005 1 Potassium (K)0.843 mg/L EPA 200.7 08/03/2015 13:32 FCJORDA0.1 1 Silver (Ag)< 0.005 mg/L EPA 200.7 08/03/2015 13:32 FCJORDA0.005 1 Sodium (Na)6.82 mg/L EPA 200.7 08/03/2015 13:32 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020A 08/03/2015 18:53 JAHERMA11 Cadmium (Cd)< 1 ug/L SW 6020A 08/03/2015 18:53 JAHERMA11 Lead (Pb)< 1 ug/L SW 6020A 08/03/2015 18:53 JAHERMA11 Selenium (Se)< 1 ug/L SW 6020A 08/03/2015 18:53 JAHERMA11 VOLATILES - (Analysis Performed by Test America) Benzene Complete Vendor Method V_T. America Page 18 of 77 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060650 2015020161 Collection Date:30-Jul-15 2:35 PM Site:FIELD BLANK Matrix:GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF LOW LEVEL ALKALINITY (FIXED END POINT) Alkalinity (mg/L CaCO3)< 5 mg/L (CaCO3)SM 2320B4d 08/06/2015 15:15 TJA706751 INORGANIC IONS BY IC Chloride < 0.1 mg/L EPA 300.0 08/03/2015 18:44 BGN90340.1 1 Sulfate < 0.1 mg/L EPA 300.0 08/03/2015 18:44 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 08/03/2015 15:11 ACPAYNE0.05 1 TOTAL RECOVERABLE METALS BY ICP Barium (Ba)< 0.005 mg/L EPA 200.7 08/03/2015 13:36 FCJORDA0.005 1 Calcium (Ca)0.017 mg/L EPA 200.7 08/03/2015 13:36 FCJORDA0.01 1 Chromium (Cr)< 0.005 mg/L EPA 200.7 08/03/2015 13:36 FCJORDA0.005 1 Magnesium (Mg)< 0.005 mg/L EPA 200.7 08/03/2015 13:36 FCJORDA0.005 1 Potassium (K)< 0.1 mg/L EPA 200.7 08/03/2015 13:36 FCJORDA0.1 1 Silver (Ag)< 0.005 mg/L EPA 200.7 08/03/2015 13:36 FCJORDA0.005 1 Sodium (Na)< 0.05 mg/L EPA 200.7 08/03/2015 13:36 FCJORDA0.05 1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As)< 1 ug/L SW 6020A 08/03/2015 19:00 JAHERMA11 Cadmium (Cd)< 1 ug/L SW 6020A 08/03/2015 19:00 JAHERMA11 Lead (Pb)< 1 ug/L SW 6020A 08/03/2015 19:00 JAHERMA11 Selenium (Se)< 1 ug/L SW 6020A 08/03/2015 19:00 JAHERMA11 VOLATILES - (Analysis Performed by Test America) Benzene Complete Vendor Method V_T. America Page 19 of 77 ANALYTICAL REPORT TestAmerica Laboratories, Inc. TestAmerica Nashville 2960 Foster Creighton Drive Nashville, TN 37204 Tel:(615)726-0177 TestAmerica Job ID: 490-84166-1 Client Project/Site: MNS Landfill #1 J15060650 For: Duke Energy Corporation 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Attn: Lab Customer Authorized for release by: 8/14/2015 3:26:18 PM Shali Brown, Project Manager II (615)301-5031 shali.brown@testamericainc.com The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited parameters, exceptions are noted in this report. This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature. Results relate only to the items tested and the sample(s) as received by the laboratory. 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 20 of 77 Table of Contents Client: Duke Energy Corporation Project/Site: MNS Landfill #1 J15060650 TestAmerica Job ID: 490-84166-1 Page 2 of 55 TestAmerica Nashville8/14/2015 Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1 Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2 Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3 Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4 Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6 Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7 QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .39 QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .45 Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .46 Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .49 Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .50 Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .51 Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .55 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 21 of 77         !    " # $% &'% ( )* + ,,      -" .('/0 1$2$, 3, $$, , 3 &00 1$2$,  $$, , 2 &00 1$2$, , $$, , &030 1$2$, 1, $$, , ,&030 1$2$, 2, $$, , &02 0 1$2$, 2, $$, , 1 &020 1$2$,  $$, , &00 1$2$, ,, $$, , &00 1$2$,  $$, , &00 1$2$, 3, $$, , &00 1$2$, 2 $$, , 3 &030 1$2$, 2 $$, , 2 %00 1$2$, 3, $$, , &0-0 1$2$, 2, $$, , ,&0-0 1$2$, 3 $$, , 4( .('/0 1$2$, 2, $$, ,  ' 56 Page 3 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 22 of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age 4 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 23 of 77           !! " #$%&'%()*+  ,!!, 3 $ $%,4     3 $ $%,4 0<  >.  0@ ). .0@ * ). ) .*). 2   ..* (%  <D $,3.1 )...(%)(%  1 )).)=. * 0. ).2  )3 &.)BC<!@.  22 ).  2))1.*.&.)<! 4 )3.*11 2)  2)1..) . )?"@('AB !! 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' . . $( $$, /, 2 1 ' . .- $( $$, /, -9:   ' . ., $( $$, /,  ) 2  ' . .-- $( $$, /, &2  2 ) ' . . $( $$, /, &2 -!   5&067 ' . .- $( $$, /, %  ' . ., $( $$, /, 888- 2  2  ' 3 . . $( $$, /, 88-8- 2  2  ' . . $( $$, /,  2  2 ' . ./ $( $$, /,   ' ,. . $( $$, /,  8 2  - ' . .-4 $( $$, /,  8- 2  2 ' . ./ $( $$, /,  84 2  ! ! ' . . $( $$, /, 88 2  2  ' 3 . . $( $$, /, 88- 2  2  ' . .- $( $$, /,  2  2 ' . .- $( $$, /,  2  *  2  ' . .-4 $( $$, /, 8-84 2  ! !  ' . ./ $( $$, /, ;    ' . . $( $$, /, ;  2 ) ' 4. ., $( $$, /, < 8    '  ' 2= Page 7 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 26 of 77            !    " # $% &'% ( )* + ,,      ! "#$ " %&'()*)+,+   &-'))++                     !"#  $   % $    ' 2= Page 8 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 27 of 77            !    " # $% &'% ( )* + ,,   , !$ ! "#$ " %&'()*)+   &-'))++ !.%',/% 0"1 &% %' 23)!4  !    ' -,. -. $( $$, /,   56 & 57'" "'8    9 :" . ., $( $$, /,     ' . .- $( $$, /, 01 ' . ., $( $$, /, 0  2  2  ' . ./ $( $$, /, 0  ) 2  2  ' 3 . .- $( $$, /, 0  *  ' 3 . .4, $( $$, /, 0  2  ' ,. -. $( $$, /, -0   5&67 ' . .-- $( $$, /,    )*) ' . . $( $$, /,     2 ) ' . . $( $$, /, 2  1 ' . .-, $( $$, /, 2  )  2  ' 3 . .4 $( $$, /, 2  2  ' . .-4 $( $$, /, 2  *  ' . .4 $( $$, /, 2  2  ' . .- $( $$, /,  8- 2  2 ' . ./ $( $$, /,  84 2  ! ! ' . . $( $$, /, 8-  42  ! !  ' 3 . .- $( $$, /, 8-  2  507 ' . ., $( $$, /,   2  ' . . $( $$, /, 8- 2  1 ' . ./ $( $$, /, 8 2  1 ' . .- $( $$, /, 8 2  2  ' . .- $( $$, /, 8- 2  2  ' . .-, $( $$, /, 8 2  2 ' . .-, $( $$, /, 8- 2  ! !  ' . . $( $$, /, 2 1 ' . .- $( $$, /, -9:   ' . ., $( $$, /,  ) 2  ' . .-- $( $$, /, &2  2 ) ' . . $( $$, /, &2 -!   5&067 ' . .- $( $$, /, %  ' . ., $( $$, /, 888- 2  2  ' 3 . . $( $$, /, 88-8- 2  2  ' . . $( $$, /,  2  2 ' . ./ $( $$, /,   ' ,. . $( $$, /,  8 2  - ' . .-4 $( $$, /,  8- 2  2 ' . ./ $( $$, /,  84 2  ! ! ' . . $( $$, /, 88 2  2  ' 3 . . $( $$, /, 88- 2  2  ' . .- $( $$, /,  2  2 ' . .- $( $$, /,  2  *  2  ' . .-4 $( $$, /, 8-84 2  ! !  ' . ./ $( $$, /, ;    ' . . $( $$, /, ;  2 ) ' 4. ., $( $$, /, < 8    '  ' 2= Page 9 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 28 of 77            !    " # $% &'% ( )* + ,,   , !$ ! "#$ " %&'()*)+   &-'))++                     !"#  $   % $    ' 2= Page 10 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 29 of 77            !    " # $% &'% ( )* + ,,   * !$ ! "#$ " %&'()*)++   &-'))++ !.%',/% 0"1 &% %' 23)!4  !    ' -,. -. $( $$, -   56 & 57'" "'8    9 :" . ., $( $$, -     ' . .- $( $$, - 01 ' . ., $( $$, - 0  2  2  ' . ./ $( $$, - 0  ) 2  2  ' 3 . .- $( $$, - 0  *  ' 3 . .4, $( $$, - 0  2  ' ,. -. $( $$, - -0   5&67 ' . .-- $( $$, -    )*) ' . . $( $$, -     2 ) ' . . $( $$, - 2  1 ' . .-, $( $$, - 2  )  2  ' 3 . .4 $( $$, - 2  2  ' . .-4 $( $$, - 2  *  ' . .4 $( $$, - 2  2  ' . .- $( $$, -  8- 2  2 ' . ./ $( $$, -  84 2  ! ! ' . . $( $$, - 8-  42  ! !  ' 3 . .- $( $$, - 8-  2  507 ' . ., $( $$, -   2  ' . . $( $$, - 8- 2  1 ' . ./ $( $$, - 8 2  1 ' . .- $( $$, - 8 2  2  ' . .- $( $$, - 8- 2  2  ' . .-, $( $$, - 8 2  2 ' . .-, $( $$, - 8- 2  ! !  ' . . $( $$, - 2 1 ' . .- $( $$, - -9:   ' . ., $( $$, -  ) 2  ' . .-- $( $$, - &2  2 ) ' . . $( $$, - &2 -!   5&067 ' . .- $( $$, - %  ' . ., $( $$, - 888- 2  2  ' 3 . . $( $$, - 88-8- 2  2  ' . . $( $$, -  2  2 ' . ./ $( $$, -   ' ,. . $( $$, -  8 2  - ' . .-4 $( $$, -  8- 2  2 ' . ./ $( $$, -  84 2  ! ! ' . . $( $$, - 88 2  2  ' 3 . . $( $$, - 88- 2  2  ' . .- $( $$, -  2  2 ' . .- $( $$, -  2  *  2  ' . .-4 $( $$, - 8-84 2  ! !  ' . ./ $( $$, - ;    ' . . $( $$, - ;  2 ) ' 4. ., $( $$, - < 8    '  ' 2= Page 11 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 30 of 77            !    " # $% &'% ( )* + ,,   * !$ ! "#$ " %&'()*)++   &-'))++    "               "  !"#  $ "  % $ "   ' 2= Page 12 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 31 of 77            !    " # $% &'% ( )* + ,,    !$, ! "#$ " %&'()*)+(+   &-'))++ !.%',/% 0"1 &% %' 23)!4  !    ' -,. -. $( $$, ,   56 & 57'" "'8    9 :" . ., $( $$, ,     ' . .- $( $$, , 01 ' . ., $( $$, , 0  2  2  ' . ./ $( $$, , 0  ) 2  2  ' 3 . .- $( $$, , 0  *  ' 3 . .4, $( $$, , 0  2  ' ,. -. $( $$, , -0   5&67 ' . .-- $( $$, ,    )*) ' . . $( $$, ,     2 ) ' . . $( $$, , 2  1 ' . .-, $( $$, , 2  )  2  ' 3 . .4 $( $$, , 2  2  ' . .-4 $( $$, , 2  *  ' . .4 $( $$, , 2  2  ' . .- $( $$, ,  8- 2  2 ' . ./ $( $$, ,  84 2  ! ! ' . . $( $$, , 8-  42  ! !  ' 3 . .- $( $$, , 8-  2  507 ' . ., $( $$, ,   2  ' . . $( $$, , 8- 2  1 ' . ./ $( $$, , 8 2  1 ' . .- $( $$, , 8 2  2  ' . .- $( $$, , 8- 2  2  ' . .-, $( $$, , 8 2  2 ' . .-, $( $$, , 8- 2  ! !  ' . . $( $$, , 2 1 ' . .- $( $$, , -9:   ' . ., $( $$, ,  ) 2  ' . .-- $( $$, , &2  2 ) ' . . $( $$, , &2 -!   5&067 ' . .- $( $$, , %  ' . ., $( $$, , 888- 2  2  ' 3 . . $( $$, , 88-8- 2  2  ' . . $( $$, ,  2  2 ' . ./ $( $$, ,   ' ,. . $( $$, ,  8 2  - ' . .-4 $( $$, ,  8- 2  2 ' . ./ $( $$, ,  84 2  ! ! ' . . $( $$, , 88 2  2  ' 3 . . $( $$, , 88- 2  2  ' . .- $( $$, ,  2  2 ' . .- $( $$, ,  2  *  2  ' . .-4 $( $$, , 8-84 2  ! !  ' . ./ $( $$, , ;    ' . . $( $$, , ;  2 ) ' 4. ., $( $$, , < 8    '  ' 2= Page 13 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 32 of 77            !    " # $% &'% ( )* + ,,    !$, ! "#$ " %&'()*)+(+   &-'))++                   "  !"#  $   % $ "   ' 2= Page 14 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 33 of 77            !    " # $% &'% ( )* + ,,   + !$, ! "#$ " %&'()*)+*+   &-'))++ !.%',/% 0"1 &% %' 23)!4  !    ' -,. -. $( $$, -   56 & 57'" "'8    9 :" . ., $( $$, -     ' . .- $( $$, - 01 ' . ., $( $$, - 0  2  2  ' . ./ $( $$, - 0  ) 2  2  ' 3 . .- $( $$, - 0  *  ' 3 . .4, $( $$, - 0  2  ' ,. -. $( $$, - -0   5&67 ' . .-- $( $$, -    )*) ' . . $( $$, -     2 ) ' . . $( $$, - 2  1 ' . .-, $( $$, - 2  )  2  ' 3 . .4 $( $$, - 2  2  ' . .-4 $( $$, - 2  *  ' . .4 $( $$, - 2  2  ' . .- $( $$, -  8- 2  2 ' . ./ $( $$, -  84 2  ! ! ' . . $( $$, - 8-  42  ! !  ' 3 . .- $( $$, - 8-  2  507 ' . ., $( $$, -   2  ' . . $( $$, - 8- 2  1 ' . ./ $( $$, - 8 2  1 ' . .- $( $$, - 8 2  2  ' . .- $( $$, - 8- 2  2  ' . .-, $( $$, - 8 2  2 ' . .-, $( $$, - 8- 2  ! !  ' . . $( $$, - 2 1 ' . .- $( $$, - -9:   ' . ., $( $$, -  ) 2  ' . .-- $( $$, - &2  2 ) ' . . $( $$, - &2 -!   5&067 ' . .- $( $$, - %  ' . ., $( $$, - 888- 2  2  ' 3 . . $( $$, - 88-8- 2  2  ' . . $( $$, -  2  2 ' . ./ $( $$, -   ' ,. . $( $$, -  8 2  - ' . .-4 $( $$, -  8- 2  2 ' . ./ $( $$, -  84 2  ! ! ' . . $( $$, - 88 2  2  ' 3 . . $( $$, - 88- 2  2  ' . .- $( $$, -  2  2 ' . .- $( $$, -  2  *  2  ' . .-4 $( $$, - 8-84 2  ! !  ' . ./ $( $$, - ;    ' . . $( $$, - ;  2 ) ' 4. ., $( $$, - < 8    '  ' 2= Page 15 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 34 of 77            !    " # $% &'% ( )* + ,,   + !$, ! "#$ " %&'()*)+*+   &-'))++    "               "  !"#  $ "  % $ "   ' 2= Page 16 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 35 of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age 17 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 36 of 77            !    " # $% &'% ( )* + ,,    !$* ! "#$ " %&'()*)+*+   &-'))++                     !"#  $   % $ "   ' 2= Page 18 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 37 of 77            !    " # $% &'% ( )* + ,,   ( !$* ! "#$ " %&'()*)+   &-'))++ !.%',/% 0"1 &% %' 23)!4  !    ' -,. -. $( $$, -,   56 & 57'" "'8    9 :" . ., $( $$, -,     ' . .- $( $$, -, 01 ' . ., $( $$, -, 0  2  2  ' . ./ $( $$, -, 0  ) 2  2  ' 3 . .- $( $$, -, 0  *  ' 3 . .4, $( $$, -, 0  2  ' ,. -. $( $$, -, -0   5&67 ' . .-- $( $$, -,    )*) ' . . $( $$, -,     2 ) ' . . $( $$, -, 2  1 ' . .-, $( $$, -, 2  )  2  ' 3 . .4 $( $$, -, 2  2  ' . .-4 $( $$, -, 2  *  ' . .4 $( $$, -, 2  2  ' . .- $( $$, -, & =,&.%"%.;(* < . ./ $($$, -,  84 2  ! !' . . $($$, -, 8-  42  ! ! ' 3 . .- $($$, -, 8-  2  507 ' . ., $($$, -,   2 ' . . $($$, -, 8- 2  1' . ./ $($$, -, 8 2  1' . .- $($$, -, 8 2  2 ' . .- $($$, -, 8- 2  2 ' . .-, $($$, -, 8 2  2' . .-, $($$, -, 8- 2  ! ! ' . . $($$, -, 2 1' . .- $($$, -, -9:  ' . ., $($$, -,  ) 2 ' . .-- $($$, -, !.5.%"';+, < . . $($$, -, &2 -!   5&067 ' . .- $($$, -, % ' . ., $($$, -, 888- 2  2 ' 3 . . $($$, -, 88-8- 2  2 ' . . $($$, -, " &.%"%.;*(* < . ./ $($$, -,  ' ,. . $($$, -,  8 2  -' . .-4 $($$, -,  8- 2  2' . ./ $($$, -,  84 2  ! !' . . $($$, -, 88 2  2 ' 3 . . $($$, -, 88- 2  2 ' . .- $($$, -, "&.%"%.;+* < . .- $($$, -, "&.%"%:%"% . ;* . .-4 $($$, -, 8-84 2  ! ! ' . ./ $($$, -, ;   ' . . $($$, -, ;  2 )' 4. ., $($$, -, >5 =% ;,  ' 2= Page 19 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 38 of 77            !    " # $% &'% ( )* + ,,   ( !$* ! "#$ " %&'()*)+   &-'))++    "               "  !"#  $ "  % $ "   ' 2= Page 20 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 39 of 77            !    " # $% &'% ( )* + ,,    !$ ! "#$ " %&'()*)+++   &-'))++ !.%',/% 0"1 &% %' 23)!4  !    ' -,. -. $( $$, --   56 & 57'" "'8    9 :" . ., $( $$, --     ' . .- $( $$, -- 01 ' . ., $( $$, -- 0  2  2  ' . ./ $( $$, -- 0  ) 2  2  ' 3 . .- $( $$, -- 0  *  ' 3 . .4, $( $$, -- 0  2  ' ,. -. $( $$, -- -0   5&67 ' . .-- $( $$, --    )*) ' . . $( $$, --     2 ) ' . . $( $$, -- 2  1 ' . .-, $( $$, -- 2  )  2  ' 3 . .4 $( $$, -- 2  2  ' . .-4 $( $$, -- 2  *  ' . .4 $( $$, -- 2  2  ' . .- $( $$, -- & =,&.%"%.,; . ./ $($$, --  84 2  ! !' . . $($$, -- 8-  42  ! ! ' 3 . .- $($$, -- 8-  2  507 ' . ., $($$, --   2 ' . . $($$, -- 8- 2  1' . ./ $($$, -- 8 2  1' . .- $($$, -- 8 2  2 ' . .- $($$, -- 8- 2  2 ' . .-, $($$, -- 8 2  2' . .-, $($$, -- 8- 2  ! ! ' . . $($$, -- 2 1' . .- $($$, -- -9:  ' . ., $($$, --  ) 2 ' . .-- $($$, -- !.5.%"';  . . $($$, -- &2 -!   5&067 ' . .- $($$, -- % ' . ., $($$, -- 888- 2  2 ' 3 . . $($$, -- 88-8- 2  2 ' . . $($$, -- " &.%"%.,;, . ./ $($$, --  ' ,. . $($$, --  8 2  -' . .-4 $($$, --  8- 2  2' . ./ $($$, --  84 2  ! !' . . $($$, -- 88 2  2 ' 3 . . $($$, -- 88- 2  2 ' . .- $($$, -- "&.%"%.;( . .- $($$, --  2  *  2 ' . .-4 $($$, -- 8-84 2  ! ! ' . ./ $($$, -- ;   ' . . $($$, -- ;  2 )' 4. ., $($$, -- < 8   '  ' 2= Page 21 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 40 of 77            !    " # $% &'% ( )* + ,,    !$ ! "#$ " %&'()*)+++   &-'))++    ""               ""  !"#  $ ""  % $ ""   ' 2= Page 22 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 41 of 77            !    " # $% &'% ( )* + ,,    !$ ! "#$ " %&'()*)+   &-'))++ !.%',/% 0"1 &% %' 23)!4  !    ' -,. -. $( $$, -   56 & 57'" "'8    9 :" . ., $( $$, -     ' . .- $( $$, - 7;,( < . ., $($$, - 0  2  2 ' . ./ $($$, - 0  ) 2  2 ' 3 . .- $($$, - 0  * ' 3 . .4, $($$, - 0  2 ' ,. -. $($$, - -0   5&67 ' . .-- $($$, -    )*)' . . $($$, -     2 )' . . $($$, - 2  1' . .-, $($$, - 2  )  2 ' 3 . .4 $($$, - 2  2 ' . .-4 $($$, - 2  * ' . .4 $($$, - 2  2 ' . .- $($$, - & =,&.%"%.*; . ./ $($$, -  84 2  ! !' . . $($$, - 8-  42  ! ! ' 3 . .- $($$, - 8-  2  507 ' . ., $($$, -   2 ' . . $($$, - 8- 2  1' . ./ $($$, - 8 2  1' . .- $($$, - =&.%"%. ;*+ < . .- $($$, - 8- 2  2 ' . .-, $($$, - 8 2  2' . .-, $($$, - 8- 2  ! ! ' . . $($$, - 2 1' . .- $($$, - -9:  ' . ., $($$, -  ) 2 ' . .-- $($$, - !.5.%"'(;+  . . $($$, - &2 -!   5&067 ' . .- $($$, - % ' . ., $($$, - 888- 2  2 ' 3 . . $($$, - 88-8- 2  2 ' . . $($$, - " &.%"%.;(* . ./ $($$, - %;, < ,. . $($$, -  8 2  -' . .-4 $($$, - "  =,&.%"%.;( < . ./ $($$, -  84 2  ! !' . . $($$, - 88 2  2 ' 3 . . $($$, - 88- 2  2 ' . .- $($$, - "&.%"%.+;, . .- $($$, -  2  *  2 ' . .-4 $($$, - 8-84 2  ! ! ' . ./ $($$, - ;   ' . . $($$, - /5&.%"';+* < 4. ., $($$, - >5 =% *(;  ' 2= Page 23 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 42 of 77            !    " # $% &'% ( )* + ,,    !$ ! "#$ " %&'()*)+   &-'))++    "               "  !"#  $ "  % $ "   ' 2= Page 24 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 43 of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age 25 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 44 of 77            !    " # $% &'% ( )* + ,,    !$ ! "#$ " %&'()*)+,+   &-'))++    "               ""  !"#  $ "  % $ ""   ' 2= Page 26 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 45 of 77            !    " # $% &'% ( )* + ,,    !$ ! "#$ " %&'()*)+*   &-'))++ !.%',/% 0"1 &% %' 23)!4  !    ' -,. -. $( $$, --4   56 & 57'" "'8    9 :" . ., $( $$, --4     ' . .- $( $$, --4 01 ' . ., $( $$, --4 0  2  2  ' . ./ $( $$, --4 0  ) 2  2  ' 3 . .- $( $$, --4 0  *  ' 3 . .4, $( $$, --4 0  2  ' ,. -. $( $$, --4 -0   5&67 ' . .-- $( $$, --4    )*) ' . . $( $$, --4     2 ) ' . . $( $$, --4 2  1 ' . .-, $( $$, --4 2  )  2  ' 3 . .4 $( $$, --4 2  2  ' . .-4 $( $$, --4 2  *  ' . .4 $( $$, --4 2  2  ' . .- $( $$, --4  8- 2  2 ' . ./ $( $$, --4  84 2  ! ! ' . . $( $$, --4 8-  42  ! !  ' 3 . .- $( $$, --4 8-  2  507 ' . ., $( $$, --4   2  ' . . $( $$, --4 8- 2  1 ' . ./ $( $$, --4 8 2  1 ' . .- $( $$, --4 8 2  2  ' . .- $( $$, --4 8- 2  2  ' . .-, $( $$, --4 8 2  2 ' . .-, $( $$, --4 8- 2  ! !  ' . . $( $$, --4 2 1 ' . .- $( $$, --4 -9:   ' . ., $( $$, --4  ) 2  ' . .-- $( $$, --4 &2  2 ) ' . . $( $$, --4 &2 -!   5&067 ' . .- $( $$, --4 %  ' . ., $( $$, --4 888- 2  2  ' 3 . . $( $$, --4 88-8- 2  2  ' . . $( $$, --4  2  2 ' . ./ $( $$, --4   ' ,. . $( $$, --4  8 2  - ' . .-4 $( $$, --4  8- 2  2 ' . ./ $( $$, --4  84 2  ! ! ' . . $( $$, --4 88 2  2  ' 3 . . $( $$, --4 88- 2  2  ' . .- $( $$, --4  2  2 ' . .- $( $$, --4  2  *  2  ' . .-4 $( $$, --4 8-84 2  ! !  ' . ./ $( $$, --4 ;    ' . . $( $$, --4 ;  2 ) ' 4. ., $( $$, --4 < 8    '  ' 2= Page 27 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 46 of 77            !    " # $% &'% ( )* + ,,    !$ ! "#$ " %&'()*)+*   &-'))++    ""               ""  !"#  $ ""  % $ ""   ' 2= Page 28 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 47 of 77            !    " # $% &'% ( )* + ,,   , !$, ! "#$ " %&'()*)+*   &-'))++ !.%',/% 0"1 &% %' 23)!4  !    ' -,. -. $( $$, --4   56 & 57'" "'8    9 :" . ., $( $$, --4     ' . .- $( $$, --4 01 ' . ., $( $$, --4 0  2  2  ' . ./ $( $$, --4 0  ) 2  2  ' 3 . .- $( $$, --4 0  *  ' 3 . .4, $( $$, --4 0  2  ' ,. -. $( $$, --4 -0   5&67 ' . .-- $( $$, --4    )*) ' . . $( $$, --4     2 ) ' . . $( $$, --4 2  1 ' . .-, $( $$, --4 2  )  2  ' 3 . .4 $( $$, --4 2  2  ' . .-4 $( $$, --4 2  *  ' . .4 $( $$, --4 2  2  ' . .- $( $$, --4  8- 2  2 ' . ./ $( $$, --4  84 2  ! ! ' . . $( $$, --4 8-  42  ! !  ' 3 . .- $( $$, --4 8-  2  507 ' . ., $( $$, --4   2  ' . . $( $$, --4 8- 2  1 ' . ./ $( $$, --4 8 2  1 ' . .- $( $$, --4 8 2  2  ' . .- $( $$, --4 8- 2  2  ' . .-, $( $$, --4 8 2  2 ' . .-, $( $$, --4 8- 2  ! !  ' . . $( $$, --4 2 1 ' . .- $( $$, --4 -9:   ' . ., $( $$, --4  ) 2  ' . .-- $( $$, --4 &2  2 ) ' . . $( $$, --4 &2 -!   5&067 ' . .- $( $$, --4 %  ' . ., $( $$, --4 888- 2  2  ' 3 . . $( $$, --4 88-8- 2  2  ' . . $( $$, --4  2  2 ' . ./ $( $$, --4   ' ,. . $( $$, --4  8 2  - ' . .-4 $( $$, --4  8- 2  2 ' . ./ $( $$, --4  84 2  ! ! ' . . $( $$, --4 88 2  2  ' 3 . . $( $$, --4 88- 2  2  ' . .- $( $$, --4  2  2 ' . .- $( $$, --4  2  *  2  ' . .-4 $( $$, --4 8-84 2  ! !  ' . ./ $( $$, --4 ;    ' . . $( $$, --4 ;  2 ) ' 4. ., $( $$, --4 < 8    '  ' 2= Page 29 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 48 of 77            !    " # $% &'% ( )* + ,,   , !$, ! "#$ " %&'()*)+*   &-'))++    ""               ""  !"#  $ ""  % $ ""   ' 2= Page 30 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 49 of 77            !    " # $% &'% ( )* + ,,   * $ ! "#$ " %&'()*)+,+   &-'))++ !.%',/% 0"1 &% %' 23)!4  !    ' -,. -. $( $$, --,/   56 & 57'" "'8    9 :" . ., $( $$, --,/     ' . .- $( $$, --,/ 01 ' . ., $( $$, --,/ 0  2  2  ' . ./ $( $$, --,/ 0  ) 2  2  ' 3 . .- $( $$, --,/ 0  *  ' 3 . .4, $( $$, --,/ 0  2  ' ,. -. $( $$, --,/ -0   5&67 ' . .-- $( $$, --,/    )*) ' . . $( $$, --,/     2 ) ' . . $( $$, --,/ 2  1 ' . .-, $( $$, --,/ 2  )  2  ' 3 . .4 $( $$, --,/ 2  2  ' . .-4 $( $$, --,/ 2  *  ' . .4 $( $$, --,/ 2  2  ' . .- $( $$, --,/  8- 2  2 ' . ./ $( $$, --,/  84 2  ! ! ' . . $( $$, --,/ 8-  42  ! !  ' 3 . .- $( $$, --,/ 8-  2  507 ' . ., $( $$, --,/   2  ' . . $( $$, --,/ 8- 2  1 ' . ./ $( $$, --,/ 8 2  1 ' . .- $( $$, --,/ 8 2  2  ' . .- $( $$, --,/ 8- 2  2  ' . .-, $( $$, --,/ 8 2  2 ' . .-, $( $$, --,/ 8- 2  ! !  ' . . $( $$, --,/ 2 1 ' . .- $( $$, --,/ -9:   ' . ., $( $$, --,/  ) 2  ' . .-- $( $$, --,/ &2  2 ) ' . . $( $$, --,/ &2 -!   5&067 ' . .- $( $$, --,/ %  ' . ., $( $$, --,/ 888- 2  2  ' 3 . . $( $$, --,/ 88-8- 2  2  ' . . $( $$, --,/  2  2 ' . ./ $( $$, --,/   ' ,. . $( $$, --,/  8 2  - ' . .-4 $( $$, --,/  8- 2  2 ' . ./ $( $$, --,/  84 2  ! ! ' . . $( $$, --,/ 88 2  2  ' 3 . . $( $$, --,/ 88- 2  2  ' . .- $( $$, --,/  2  2 ' . .- $( $$, --,/  2  *  2  ' . .-4 $( $$, --,/ 8-84 2  ! !  ' . ./ $( $$, --,/ ;    ' . . $( $$, --,/ ;  2 ) ' 4. ., $( $$, --,/ < 8    '  ' 2= Page 31 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 50 of 77            !    " # $% &'% ( )* + ,,   * $ ! "#$ " %&'()*)+,+   &-'))++    ""               ""  !"#  $ ""  % $ ""   ' 2= Page 32 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 51 of 77            !    " # $% &'% ( )* + ,,    !$ ! "#$ " %&'()*)+*+   &-'))++ !.%',/% 0"1 &% %' 23)!4  !    ' -,. -. $( $$, -4-,   56 & 57'" "'8    9 :" . ., $( $$, -4-,     ' . .- $( $$, -4-, 01 ' . ., $( $$, -4-, 0  2  2  ' . ./ $( $$, -4-, 0  ) 2  2  ' 3 . .- $( $$, -4-, 0  *  ' 3 . .4, $( $$, -4-, 0  2  ' ,. -. $( $$, -4-, -0   5&67 ' . .-- $( $$, -4-,    )*) ' . . $( $$, -4-,     2 ) ' . . $( $$, -4-, 2  1 ' . .-, $( $$, -4-, 2  )  2  ' 3 . .4 $( $$, -4-, 2  2  ' . .-4 $( $$, -4-, 2  *  ' . .4 $( $$, -4-, 2  2  ' . .- $( $$, -4-,  8- 2  2 ' . ./ $( $$, -4-,  84 2  ! ! ' . . $( $$, -4-, 8-  42  ! !  ' 3 . .- $( $$, -4-, 8-  2  507 ' . ., $( $$, -4-,   2  ' . . $( $$, -4-, 8- 2  1 ' . ./ $( $$, -4-, 8 2  1 ' . .- $( $$, -4-, 8 2  2  ' . .- $( $$, -4-, 8- 2  2  ' . .-, $( $$, -4-, 8 2  2 ' . .-, $( $$, -4-, 8- 2  ! !  ' . . $( $$, -4-, 2 1 ' . .- $( $$, -4-, -9:   ' . ., $( $$, -4-,  ) 2  ' . .-- $( $$, -4-, &2  2 ) ' . . $( $$, -4-, &2 -!   5&067 ' . .- $( $$, -4-, %  ' . ., $( $$, -4-, 888- 2  2  ' 3 . . $( $$, -4-, 88-8- 2  2  ' . . $( $$, -4-, " &.%"%.;+, < . ./ $($$, -4-,  ' ,. . $($$, -4-,  8 2  -' . .-4 $($$, -4-,  8- 2  2' . ./ $($$, -4-,  84 2  ! !' . . $($$, -4-, 88 2  2 ' 3 . . $($$, -4-, 88- 2  2 ' . .- $($$, -4-,  2  2' . .- $($$, -4-,  2  *  2 ' . .-4 $($$, -4-, 8-84 2  ! ! ' . ./ $($$, -4-, ;   ' . . $($$, -4-, ;  2 )' 4. ., $($$, -4-, < 8   '  ' 2= Page 33 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 52 of 77            !    " # $% &'% ( )* + ,,    !$ ! "#$ " %&'()*)+*+   &-'))++    ""               ""  !"#  $ """  % $ ""   ' 2= Page 34 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 53 of 77            !    " # $% &'% ( )* + ,,   + !$ ! "#$ " %&'()*)+,   &-'))++ !.%',/% 0"1 &% %' 23)!4  !    ' -,. -. $( $$, -4,-   56 & 57'" "'8    9 :" . ., $( $$, -4,-     ' . .- $( $$, -4,- 01 ' . ., $( $$, -4,- 0  2  2  ' . ./ $( $$, -4,- 0  ) 2  2  ' 3 . .- $( $$, -4,- 0  *  ' 3 . .4, $( $$, -4,- 0  2  ' ,. -. $( $$, -4,- -0   5&67 ' . .-- $( $$, -4,-    )*) ' . . $( $$, -4,-     2 ) ' . . $( $$, -4,- 2  1 ' . .-, $( $$, -4,- 2  )  2  ' 3 . .4 $( $$, -4,- 2  2  ' . .-4 $( $$, -4,- 2  *  ' . .4 $( $$, -4,- 2  2  ' . .- $( $$, -4,-  8- 2  2 ' . ./ $( $$, -4,-  84 2  ! ! ' . . $( $$, -4,- 8-  42  ! !  ' 3 . .- $( $$, -4,- 8-  2  507 ' . ., $( $$, -4,-   2  ' . . $( $$, -4,- 8- 2  1 ' . ./ $( $$, -4,- 8 2  1 ' . .- $( $$, -4,- 8 2  2  ' . .- $( $$, -4,- 8- 2  2  ' . .-, $( $$, -4,- 8 2  2 ' . .-, $( $$, -4,- 8- 2  ! !  ' . . $( $$, -4,- 2 1 ' . .- $( $$, -4,- -9:   ' . ., $( $$, -4,-  ) 2  ' . .-- $( $$, -4,- &2  2 ) ' . . $( $$, -4,- &2 -!   5&067 ' . .- $( $$, -4,- %  ' . ., $( $$, -4,- 888- 2  2  ' 3 . . $( $$, -4,- 88-8- 2  2  ' . . $( $$, -4,- " &.%"%.;,+ < . ./ $($$, -4,-  ' ,. . $($$, -4,-  8 2  -' . .-4 $($$, -4,-  8- 2  2' . ./ $($$, -4,-  84 2  ! !' . . $($$, -4,- 88 2  2 ' 3 . . $($$, -4,- 88- 2  2 ' . .- $($$, -4,- "&.%"%.;, < . .- $($$, -4,-  2  *  2 ' . .-4 $($$, -4,- 8-84 2  ! ! ' . ./ $($$, -4,- ;   ' . . $($$, -4,- ;  2 )' 4. ., $($$, -4,- < 8   '  ' 2= Page 35 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 54 of 77            !    " # $% &'% ( )* + ,,   + !$ ! "#$ " %&'()*)+,   &-'))++    ""               ""  !"#  $ ""  % $ ""   ' 2= Page 36 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 55 of 77            !    " # $% &'% ( )* + ,,    6? ! "#$ " %&'()*)+*+   &-'))++ !.%',/% 0"1 &% %' 23)!4  !    ' -,. -. $( $$, /4-   56 & 57'" "'8    9 :" . ., $( $$, /4-     ' . .- $( $$, /4- 01 ' . ., $( $$, /4- 0  2  2  ' . ./ $( $$, /4- 0  ) 2  2  ' 3 . .- $( $$, /4- 0  *  ' 3 . .4, $( $$, /4- 0  2  ' ,. -. $( $$, /4- -0   5&67 ' . .-- $( $$, /4-    )*) ' . . $( $$, /4-     2 ) ' . . $( $$, /4- 2  1 ' . .-, $( $$, /4- 2  )  2  ' 3 . .4 $( $$, /4- 2  2  ' . .-4 $( $$, /4- 2  *  ' . .4 $( $$, /4- 2  2  ' . .- $( $$, /4-  8- 2  2 ' . ./ $( $$, /4-  84 2  ! ! ' . . $( $$, /4- 8-  42  ! !  ' 3 . .- $( $$, /4- 8-  2  507 ' . ., $( $$, /4-   2  ' . . $( $$, /4- 8- 2  1 ' . ./ $( $$, /4- 8 2  1 ' . .- $( $$, /4- 8 2  2  ' . .- $( $$, /4- 8- 2  2  ' . .-, $( $$, /4- 8 2  2 ' . .-, $( $$, /4- 8- 2  ! !  ' . . $( $$, /4- 2 1 ' . .- $( $$, /4- -9:   ' . ., $( $$, /4-  ) 2  ' . .-- $( $$, /4- &2  2 ) ' . . $( $$, /4- &2 -!   5&067 ' . .- $( $$, /4- %  ' . ., $( $$, /4- 888- 2  2  ' 3 . . $( $$, /4- 88-8- 2  2  ' . . $( $$, /4-  2  2 ' . ./ $( $$, /4-   ' ,. . $( $$, /4-  8 2  - ' . .-4 $( $$, /4-  8- 2  2 ' . ./ $( $$, /4-  84 2  ! ! ' . . $( $$, /4- 88 2  2  ' 3 . . $( $$, /4- 88- 2  2  ' . .- $( $$, /4-  2  2 ' . .- $( $$, /4-  2  *  2  ' . .-4 $( $$, /4- 8-84 2  ! !  ' . ./ $( $$, /4- ;    ' . . $( $$, /4- ;  2 ) ' 4. ., $( $$, /4- < 8    '  ' 2= Page 37 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 56 of 77            !    " # $% &'% ( )* + ,,    6? ! "#$ " %&'()*)+*+   &-'))++    "               "  !"#  $ "  % $ "   ' 2= Page 38 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 57 of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' - 011$%12 34%"   53  ,  '-6 Page 50 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 69 of 77 Page 51 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 70 of 77 Page 52 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 71 of 77 Page 53 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 72 of 77 Page 54 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 73 of 77                           !" #   $  %      !"#$%!&!   $'()!    $$   $ " *  &! %$! $ $+, $+$!* (-.! $ $$+, $+ !*  &!  $$  &"! $     #&*  .$#  !" !*     $!!*     $ !  * /*0  1$ $*  1$,    *  1$,  #& , *  2$&3 . %$ $14  &   $! !$#&! $ !"  &1*  .$  !" #&5 *  .! $&"$*   $     *  .!! ($  "  *  -  $! $  $ *  .$ !, * (-.6 $ "7 , *  & $$ ,,!"*,  8 $ $$+!* 8 $  9.(9. $   $ 8  : & $!&"& $!  $ ';(<=*  9 &$!$$  $*  .$  8  $ !$* (-$ & &!  * $  % Page 55 of 55 8/14/2015 1 2 3 4 5 6 7 8 9 10 11 12 13 Page 74 of 77 Pa g e 7 5 o f 7 7 Pa g e 7 6 o f 7 7 Page 77 of 77 13339 Hagers Ferry RoadHuntersville, NC 28078-7929McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15070293 Project Name:MCGUIRE - Lab Contact:Jason C Perkins Date:8/14/2015 Customer Address:13225 Hagers Ferry Rd Customer Name(s):TIM HUNSUCKER, C Campbell Mail Code: MG01CH Huntersville, NC 28078-8985 Phone: 980-875-5348 Report Authorized By:(Signature) Program Comments: Please contact the Program Manager (Jason C Perkins) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method qualitysystem or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that havebeen qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Jason C Perkins 1 of 5 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015022837 MCGUIRE 30-Jul-15 12:50 PM PSP SW-1 1 Total Samples 2 of 5 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:Jason C Perkins Date:8/14/2015 Electronic Data Deliverable (EDD) Sent Separately 3 of 5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15070293 2015022837 Collection Date: 30-Jul-15 12:50 PM Site: SW-1 Matrix: GW_RCRA Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP Barium (Ba)0.026 mg/L EPA 200.7 07/31/2015 11:58 FCJORDA0.005 1 Chromium (Cr)< 0.005 mg/L EPA 200.7 07/31/2015 11:58 FCJORDA0.005 1 Silver (Ag)< 0.005 mg/L EPA 200.7 07/31/2015 11:58 FCJORDA0.005 1 DISSOLVED METALS BY ICP-MS Arsenic (As)< 1 ug/L EPA 200.8 08/03/2015 20:10 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 08/03/2015 20:10 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 08/03/2015 20:10 JAHERMA11 4 of 5 5 o f 5 Radiological Data for MCGUIRE 380953Sample #:Station:MCGUIRE Collection End: 7/30/2015 11:10:00 Collection Start:7/30/2015 11:10:00Location:MW-1_ML1 [ MNS Landfill 1 / MW-1 ( LANDFILL ) ] Ground Water MNS_9JUN2015_AJob: GW ALPHABETA Gross Alpha / Beta Analysis Waters Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Alpha <-5.2E-01 0.00E+00 1.12E+00 Beta <-6.6E-01 0.00E+00 1.49E+00 LLD OK<4 GAMMAGW Gamma Spectroscopy Ground Water Analysis Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Mn-54 <6.48E+00 0.00E+00 6.48E+00 <1000 LLD OK<15 Co-58 <5.73E+00 0.00E+00 5.73E+00 <1000 LLD OK<15 Fe-59 <1.23E+01 0.00E+00 1.23E+01 <400 LLD OK<30 Co-60 <6.70E+00 0.00E+00 6.70E+00 <300 LLD OK<15 Zn-65 <1.23E+01 0.00E+00 1.23E+01 <300 LLD OK<30 Zr-95 <1.09E+01 0.00E+00 1.09E+01 <400 LLD OK<15 Nb-95 <6.79E+00 0.00E+00 6.79E+00 <400 LLD OK<15 I-131 <7.90E+00 0.00E+00 7.90E+00 LLD OK<15 Cs-134 <6.15E+00 0.00E+00 6.15E+00 <30 LLD OK<15 Cs-137 <7.13E+00 0.00E+00 7.13E+00 <50 LLD OK<18 BaLa-140 <8.33E+00 0.00E+00 8.33E+00 <200 LLD OK<15 Be-7 <3.94E+01 0.00E+00 3.94E+01 K-40 <1.03E+02 0.00E+00 1.03E+02 H3 Tritium Analysis of Water Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL H3GW <-7.6E+01 0.00E+00 1.90E+02 <20000 LLD OK<250 380954Sample #:Station:MCGUIRE Collection End: 7/30/2015 10:50:00 Collection Start:7/30/2015 10:50:00Location:MW-1D_ML1 [ MNS Landfill 1 / MW-1D ( LANDFILL ) ] Ground Water MNS_9JUN2015_AJob: GW ALPHABETA Gross Alpha / Beta Analysis Waters Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Alpha <-3.6E-01 0.00E+00 1.11E+00 Beta <-5.7E-01 0.00E+00 1.49E+00 LLD OK<4 GAMMAGW Gamma Spectroscopy Ground Water Analysis Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Mn-54 <5.95E+00 0.00E+00 5.95E+00 <1000 LLD OK<15 Co-58 <7.03E+00 0.00E+00 7.03E+00 <1000 LLD OK<15 Fe-59 <1.03E+01 0.00E+00 1.03E+01 <400 LLD OK<30 Page 1 of 11Report Generated @ 8/27/2015 16:44:39 job_report_grouped_by_media EnRad Laboratory MNS Building 7405 (MG03A2) 13339 Hagers Ferry RoadHuntersville, NC 28078 (980)875-5371 EnRad Laboratory Page 1 of 12 08.27.2015 Radiological Data for MCGUIRE 380954Sample #:Station:MCGUIRE Collection End: 7/30/2015 10:50:00 Collection Start:7/30/2015 10:50:00Location:MW-1D_ML1 [ MNS Landfill 1 / MW-1D ( LANDFILL ) ] Ground Water MNS_9JUN2015_AJob: GW GAMMAGW Gamma Spectroscopy Ground Water Analysis Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Co-60 <7.93E+00 0.00E+00 7.93E+00 <300 LLD OK<15 Zn-65 <1.49E+01 0.00E+00 1.49E+01 <300 LLD OK<30 Zr-95 <1.11E+01 0.00E+00 1.11E+01 <400 LLD OK<15 Nb-95 <7.27E+00 0.00E+00 7.27E+00 <400 LLD OK<15 I-131 <8.45E+00 0.00E+00 8.45E+00 LLD OK<15 Cs-134 <8.29E+00 0.00E+00 8.29E+00 <30 LLD OK<15 Cs-137 <6.77E+00 0.00E+00 6.77E+00 <50 LLD OK<18 BaLa-140 <5.77E+00 0.00E+00 5.77E+00 <200 LLD OK<15 Be-7 <5.85E+01 0.00E+00 5.85E+01 K-40 1.26E+02 5.33E+01 5.19E+01 H3 Tritium Analysis of Water Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL H3GW <-3.6E+01 0.00E+00 1.93E+02 <20000 LLD OK<250 380955Sample #:Station:MCGUIRE Collection End: 7/30/2015 07:45:00 Collection Start:7/30/2015 07:45:00Location:MW-2A_ML1 [ MNS Landfill 1 / MW-2A ( LANDFILL ) ] Ground Water MNS_9JUN2015_AJob: GW ALPHABETA Gross Alpha / Beta Analysis Waters Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Alpha <-4.8E-02 0.00E+00 1.11E+00 Beta <-8.5E-01 0.00E+00 1.49E+00 LLD OK<4 GAMMAGW Gamma Spectroscopy Ground Water Analysis Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Mn-54 <5.49E+00 0.00E+00 5.49E+00 <1000 LLD OK<15 Co-58 <4.76E+00 0.00E+00 4.76E+00 <1000 LLD OK<15 Fe-59 <1.04E+01 0.00E+00 1.04E+01 <400 LLD OK<30 Co-60 <5.67E+00 0.00E+00 5.67E+00 <300 LLD OK<15 Zn-65 <1.18E+01 0.00E+00 1.18E+01 <300 LLD OK<30 Zr-95 <9.69E+00 0.00E+00 9.69E+00 <400 LLD OK<15 Nb-95 <6.67E+00 0.00E+00 6.67E+00 <400 LLD OK<15 I-131 <6.65E+00 0.00E+00 6.65E+00 LLD OK<15 Cs-134 <5.50E+00 0.00E+00 5.50E+00 <30 LLD OK<15 Cs-137 <5.85E+00 0.00E+00 5.85E+00 <50 LLD OK<18 BaLa-140 <7.83E+00 0.00E+00 7.83E+00 <200 LLD OK<15 Page 2 of 11Report Generated @ 8/27/2015 16:44:39 job_report_grouped_by_media EnRad Laboratory MNS Building 7405 (MG03A2) 13339 Hagers Ferry RoadHuntersville, NC 28078 (980)875-5371 EnRad Laboratory Page 2 of 12 08.27.2015 Radiological Data for MCGUIRE 380955Sample #:Station:MCGUIRE Collection End: 7/30/2015 07:45:00 Collection Start:7/30/2015 07:45:00Location:MW-2A_ML1 [ MNS Landfill 1 / MW-2A ( LANDFILL ) ] Ground Water MNS_9JUN2015_AJob: GW GAMMAGW Gamma Spectroscopy Ground Water Analysis Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Be-7 <3.36E+01 0.00E+00 3.36E+01 K-40 6.31E+01 5.35E+01 8.11E+01 H3 Tritium Analysis of Water Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL H3GW <2.76E+01 0.00E+00 1.93E+02 <20000 LLD OK<250 380956Sample #:Station:MCGUIRE Collection End: 7/30/2015 08:35:00 Collection Start:7/30/2015 08:35:00Location:MW-2D_ML1 [ MNS Landfill 1 / MW-2D ( LANDFILL ) ] Ground Water MNS_9JUN2015_AJob: GW ALPHABETA Gross Alpha / Beta Analysis Waters Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Alpha <-1.9E-01 0.00E+00 1.03E+00 Beta <-1.7E+00 0.00E+00 1.47E+00 LLD OK<4 GAMMAGW Gamma Spectroscopy Ground Water Analysis Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Mn-54 <5.84E+00 0.00E+00 5.84E+00 <1000 LLD OK<15 Co-58 <4.42E+00 0.00E+00 4.42E+00 <1000 LLD OK<15 Fe-59 <1.01E+01 0.00E+00 1.01E+01 <400 LLD OK<30 Co-60 <5.39E+00 0.00E+00 5.39E+00 <300 LLD OK<15 Zn-65 <1.32E+01 0.00E+00 1.32E+01 <300 LLD OK<30 Zr-95 <9.29E+00 0.00E+00 9.29E+00 <400 LLD OK<15 Nb-95 <4.87E+00 0.00E+00 4.87E+00 <400 LLD OK<15 I-131 <6.42E+00 0.00E+00 6.42E+00 LLD OK<15 Cs-134 <6.55E+00 0.00E+00 6.55E+00 <30 LLD OK<15 Cs-137 <3.71E+00 0.00E+00 3.71E+00 <50 LLD OK<18 BaLa-140 <7.33E+00 0.00E+00 7.33E+00 <200 LLD OK<15 Be-7 <4.18E+01 0.00E+00 4.18E+01 K-40 3.89E+01 3.43E+01 4.91E+01 H3 Tritium Analysis of Water Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL H3GW <-2.9E+01 0.00E+00 1.92E+02 <20000 LLD OK<250 Page 3 of 11Report Generated @ 8/27/2015 16:44:39 job_report_grouped_by_media EnRad Laboratory MNS Building 7405 (MG03A2) 13339 Hagers Ferry RoadHuntersville, NC 28078 (980)875-5371 EnRad Laboratory Page 3 of 12 08.27.2015 Radiological Data for MCGUIRE 380957Sample #:Station:MCGUIRE Collection End: 7/30/2015 09:35:00 Collection Start:7/30/2015 09:35:00Location:MW-3_ML1 [ MNS Landfill 1 / MW-3 ( LANDFILL ) ] Ground Water MNS_9JUN2015_AJob: GW ALPHABETA Gross Alpha / Beta Analysis Waters Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Alpha <-2.5E-01 0.00E+00 1.07E+00 Beta <-9.5E-01 0.00E+00 1.48E+00 LLD OK<4 GAMMAGW Gamma Spectroscopy Ground Water Analysis Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Mn-54 <4.48E+00 0.00E+00 4.48E+00 <1000 LLD OK<15 Co-58 <5.38E+00 0.00E+00 5.38E+00 <1000 LLD OK<15 Fe-59 <9.21E+00 0.00E+00 9.21E+00 <400 LLD OK<30 Co-60 <5.27E+00 0.00E+00 5.27E+00 <300 LLD OK<15 Zn-65 <1.06E+01 0.00E+00 1.06E+01 <300 LLD OK<30 Zr-95 <9.03E+00 0.00E+00 9.03E+00 <400 LLD OK<15 Nb-95 <6.05E+00 0.00E+00 6.05E+00 <400 LLD OK<15 I-131 <6.65E+00 0.00E+00 6.65E+00 LLD OK<15 Cs-134 <6.56E+00 0.00E+00 6.56E+00 <30 LLD OK<15 Cs-137 <5.36E+00 0.00E+00 5.36E+00 <50 LLD OK<18 BaLa-140 <7.83E+00 0.00E+00 7.83E+00 <200 LLD OK<15 Be-7 <4.47E+01 0.00E+00 4.47E+01 K-40 9.10E+01 5.11E+01 6.54E+01 H3 Tritium Analysis of Water Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL H3GW <-5.3E+01 0.00E+00 1.92E+02 <20000 LLD OK<250 380958Sample #:Station:MCGUIRE Collection End: 7/30/2015 10:40:00 Collection Start:7/30/2015 10:40:00Location:MW-3D_ML1 [ MNS Landfill 1 / MW-3D ( LANDFILL ) ] Ground Water MNS_9JUN2015_AJob: GW ALPHABETA Gross Alpha / Beta Analysis Waters Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Alpha <-5.6E-01 0.00E+00 1.19E+00 Beta <-4.6E-01 0.00E+00 1.52E+00 LLD OK<4 GAMMAGW Gamma Spectroscopy Ground Water Analysis Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Mn-54 <5.57E+00 0.00E+00 5.57E+00 <1000 LLD OK<15 Co-58 <5.64E+00 0.00E+00 5.64E+00 <1000 LLD OK<15 Fe-59 <9.65E+00 0.00E+00 9.65E+00 <400 LLD OK<30 Page 4 of 11Report Generated @ 8/27/2015 16:44:39 job_report_grouped_by_media EnRad Laboratory MNS Building 7405 (MG03A2) 13339 Hagers Ferry RoadHuntersville, NC 28078 (980)875-5371 EnRad Laboratory Page 4 of 12 08.27.2015 Radiological Data for MCGUIRE 380958Sample #:Station:MCGUIRE Collection End: 7/30/2015 10:40:00 Collection Start:7/30/2015 10:40:00Location:MW-3D_ML1 [ MNS Landfill 1 / MW-3D ( LANDFILL ) ] Ground Water MNS_9JUN2015_AJob: GW GAMMAGW Gamma Spectroscopy Ground Water Analysis Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Co-60 <5.06E+00 0.00E+00 5.06E+00 <300 LLD OK<15 Zn-65 <1.18E+01 0.00E+00 1.18E+01 <300 LLD OK<30 Zr-95 <8.27E+00 0.00E+00 8.27E+00 <400 LLD OK<15 Nb-95 <6.16E+00 0.00E+00 6.16E+00 <400 LLD OK<15 I-131 <7.02E+00 0.00E+00 7.02E+00 LLD OK<15 Cs-134 <7.07E+00 0.00E+00 7.07E+00 <30 LLD OK<15 Cs-137 <5.61E+00 0.00E+00 5.61E+00 <50 LLD OK<18 BaLa-140 <8.82E+00 0.00E+00 8.82E+00 <200 LLD OK<15 Be-7 <4.24E+01 0.00E+00 4.24E+01 K-40 1.36E+02 6.01E+01 6.82E+01 H3 Tritium Analysis of Water Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL H3GW <-7.0E+01 0.00E+00 1.90E+02 <20000 LLD OK<250 380959Sample #:Station:MCGUIRE Collection End: 7/30/2015 06:55:00 Collection Start:7/30/2015 06:55:00Location:MW-4_ML1 [ MNS Landfill 1 / MW-4 ( LANDFILL ) ] Ground Water MNS_9JUN2015_AJob: GW ALPHABETA Gross Alpha / Beta Analysis Waters Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Alpha <-5.6E-02 0.00E+00 1.32E+00 Beta <-1.0E+00 0.00E+00 1.58E+00 LLD OK<4 GAMMAGW Gamma Spectroscopy Ground Water Analysis Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Mn-54 <4.79E+00 0.00E+00 4.79E+00 <1000 LLD OK<15 Co-58 <5.28E+00 0.00E+00 5.28E+00 <1000 LLD OK<15 Fe-59 <1.00E+01 0.00E+00 1.00E+01 <400 LLD OK<30 Co-60 <5.37E+00 0.00E+00 5.37E+00 <300 LLD OK<15 Zn-65 <1.14E+01 0.00E+00 1.14E+01 <300 LLD OK<30 Zr-95 <9.20E+00 0.00E+00 9.20E+00 <400 LLD OK<15 Nb-95 <6.00E+00 0.00E+00 6.00E+00 <400 LLD OK<15 I-131 <6.99E+00 0.00E+00 6.99E+00 LLD OK<15 Cs-134 <6.27E+00 0.00E+00 6.27E+00 <30 LLD OK<15 Cs-137 <5.95E+00 0.00E+00 5.95E+00 <50 LLD OK<18 BaLa-140 <7.40E+00 0.00E+00 7.40E+00 <200 LLD OK<15 Page 5 of 11Report Generated @ 8/27/2015 16:44:39 job_report_grouped_by_media EnRad Laboratory MNS Building 7405 (MG03A2) 13339 Hagers Ferry RoadHuntersville, NC 28078 (980)875-5371 EnRad Laboratory Page 5 of 12 08.27.2015 Radiological Data for MCGUIRE 380959Sample #:Station:MCGUIRE Collection End: 7/30/2015 06:55:00 Collection Start:7/30/2015 06:55:00Location:MW-4_ML1 [ MNS Landfill 1 / MW-4 ( LANDFILL ) ] Ground Water MNS_9JUN2015_AJob: GW GAMMAGW Gamma Spectroscopy Ground Water Analysis Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Be-7 <5.20E+01 0.00E+00 5.20E+01 K-40 <8.52E+01 0.00E+00 8.52E+01 H3 Tritium Analysis of Water Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL H3GW <-1.9E+01 0.00E+00 1.88E+02 <20000 LLD OK<250 380960Sample #:Station:MCGUIRE Collection End: 7/30/2015 11:35:00 Collection Start:7/30/2015 11:35:00Location:MW-4R_ML1 [ MNS Landfill 1 / MW-4R ( LANDFILL ) ] Ground Water MNS_9JUN2015_AJob: GW ALPHABETA Gross Alpha / Beta Analysis Waters Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Alpha <-2.7E-01 0.00E+00 1.20E+00 Beta <-1.4E+00 0.00E+00 1.52E+00 LLD OK<4 GAMMAGW Gamma Spectroscopy Ground Water Analysis Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Mn-54 <5.49E+00 0.00E+00 5.49E+00 <1000 LLD OK<15 Co-58 <5.37E+00 0.00E+00 5.37E+00 <1000 LLD OK<15 Fe-59 <7.84E+00 0.00E+00 7.84E+00 <400 LLD OK<30 Co-60 <4.33E+00 0.00E+00 4.33E+00 <300 LLD OK<15 Zn-65 <1.18E+01 0.00E+00 1.18E+01 <300 LLD OK<30 Zr-95 <9.99E+00 0.00E+00 9.99E+00 <400 LLD OK<15 Nb-95 <5.33E+00 0.00E+00 5.33E+00 <400 LLD OK<15 I-131 <4.80E+00 0.00E+00 4.80E+00 LLD OK<15 Cs-134 <4.74E+00 0.00E+00 4.74E+00 <30 LLD OK<15 Cs-137 <5.69E+00 0.00E+00 5.69E+00 <50 LLD OK<18 BaLa-140 <6.40E+00 0.00E+00 6.40E+00 <200 LLD OK<15 Be-7 <4.98E+01 0.00E+00 4.98E+01 K-40 4.99E+01 4.40E+01 6.61E+01 H3 Tritium Analysis of Water Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL H3GW <-2.4E+01 0.00E+00 1.90E+02 <20000 LLD OK<250 Page 6 of 11Report Generated @ 8/27/2015 16:44:39 job_report_grouped_by_media EnRad Laboratory MNS Building 7405 (MG03A2) 13339 Hagers Ferry RoadHuntersville, NC 28078 (980)875-5371 EnRad Laboratory Page 6 of 12 08.27.2015 Radiological Data for MCGUIRE 380961Sample #:Station:MCGUIRE Collection End: 7/30/2015 08:00:00 Collection Start:7/30/2015 08:00:00Location:MW-4D_ML1 [ MNS Landfill 1 / MW-4D ( LANDFILL ) ] Ground Water MNS_9JUN2015_AJob: GW ALPHABETA Gross Alpha / Beta Analysis Waters Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Alpha <-7.0E-01 0.00E+00 1.36E+00 Beta <-1.0E+00 0.00E+00 1.60E+00 LLD OK<4 GAMMAGW Gamma Spectroscopy Ground Water Analysis Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Mn-54 <3.80E+00 0.00E+00 3.80E+00 <1000 LLD OK<15 Co-58 <5.34E+00 0.00E+00 5.34E+00 <1000 LLD OK<15 Fe-59 <9.45E+00 0.00E+00 9.45E+00 <400 LLD OK<30 Co-60 <3.82E+00 0.00E+00 3.82E+00 <300 LLD OK<15 Zn-65 <8.72E+00 0.00E+00 8.72E+00 <300 LLD OK<30 Zr-95 <7.23E+00 0.00E+00 7.23E+00 <400 LLD OK<15 Nb-95 <6.73E+00 0.00E+00 6.73E+00 <400 LLD OK<15 I-131 <6.62E+00 0.00E+00 6.62E+00 LLD OK<15 Cs-134 <6.55E+00 0.00E+00 6.55E+00 <30 LLD OK<15 Cs-137 <4.49E+00 0.00E+00 4.49E+00 <50 LLD OK<18 BaLa-140 <5.70E+00 0.00E+00 5.70E+00 <200 LLD OK<15 Be-7 <3.73E+01 0.00E+00 3.73E+01 K-40 <9.89E+01 0.00E+00 9.89E+01 H3 Tritium Analysis of Water Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL H3GW <-6.1E+01 0.00E+00 1.90E+02 <20000 LLD OK<250 380962Sample #:Station:MCGUIRE Collection End: 7/30/2015 12:10:00 Collection Start:7/30/2015 12:10:00Location:MW-4DR_ML1 [ MNS Landfill 1 / MW-4DR ( LANDFILL ) ] Ground Water MNS_9JUN2015_AJob: GW ALPHABETA Gross Alpha / Beta Analysis Waters Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Alpha <-3.9E-01 0.00E+00 1.22E+00 Beta <-1.3E+00 0.00E+00 1.53E+00 LLD OK<4 GAMMAGW Gamma Spectroscopy Ground Water Analysis Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Mn-54 <5.68E+00 0.00E+00 5.68E+00 <1000 LLD OK<15 Co-58 <4.03E+00 0.00E+00 4.03E+00 <1000 LLD OK<15 Fe-59 <9.21E+00 0.00E+00 9.21E+00 <400 LLD OK<30 Page 7 of 11Report Generated @ 8/27/2015 16:44:39 job_report_grouped_by_media EnRad Laboratory MNS Building 7405 (MG03A2) 13339 Hagers Ferry RoadHuntersville, NC 28078 (980)875-5371 EnRad Laboratory Page 7 of 12 08.27.2015 Radiological Data for MCGUIRE 380962Sample #:Station:MCGUIRE Collection End: 7/30/2015 12:10:00 Collection Start:7/30/2015 12:10:00Location:MW-4DR_ML1 [ MNS Landfill 1 / MW-4DR ( LANDFILL ) ] Ground Water MNS_9JUN2015_AJob: GW GAMMAGW Gamma Spectroscopy Ground Water Analysis Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Co-60 <5.27E+00 0.00E+00 5.27E+00 <300 LLD OK<15 Zn-65 <1.12E+01 0.00E+00 1.12E+01 <300 LLD OK<30 Zr-95 <1.06E+01 0.00E+00 1.06E+01 <400 LLD OK<15 Nb-95 <6.05E+00 0.00E+00 6.05E+00 <400 LLD OK<15 I-131 <6.53E+00 0.00E+00 6.53E+00 LLD OK<15 Cs-134 <5.74E+00 0.00E+00 5.74E+00 <30 LLD OK<15 Cs-137 <5.36E+00 0.00E+00 5.36E+00 <50 LLD OK<18 BaLa-140 <9.48E+00 0.00E+00 9.48E+00 <200 LLD OK<15 Be-7 <5.40E+01 0.00E+00 5.40E+01 K-40 6.02E+01 4.90E+01 7.27E+01 H3 Tritium Analysis of Water Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL H3GW <-1.6E+02 0.00E+00 1.90E+02 <20000 LLD OK<250 380963Sample #:Station:MCGUIRE Collection End: 7/30/2015 12:15:00 Collection Start:7/30/2015 12:15:00Location:MW-11_ML1 [ MNS Landfill 1 / MW-11 ( LANDFILL ) ] Ground Water MNS_9JUN2015_AJob: GW ALPHABETA Gross Alpha / Beta Analysis Waters Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Alpha <-1.9E-01 0.00E+00 8.50E-01 Beta <-1.4E+00 0.00E+00 1.44E+00 LLD OK<4 GAMMAGW Gamma Spectroscopy Ground Water Analysis Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Mn-54 <4.69E+00 0.00E+00 4.69E+00 <1000 LLD OK<15 Co-58 <6.21E+00 0.00E+00 6.21E+00 <1000 LLD OK<15 Fe-59 <1.14E+01 0.00E+00 1.14E+01 <400 LLD OK<30 Co-60 <5.94E+00 0.00E+00 5.94E+00 <300 LLD OK<15 Zn-65 <9.73E+00 0.00E+00 9.73E+00 <300 LLD OK<30 Zr-95 <9.46E+00 0.00E+00 9.46E+00 <400 LLD OK<15 Nb-95 <6.84E+00 0.00E+00 6.84E+00 <400 LLD OK<15 I-131 <7.05E+00 0.00E+00 7.05E+00 LLD OK<15 Cs-134 <4.98E+00 0.00E+00 4.98E+00 <30 LLD OK<15 Cs-137 <5.97E+00 0.00E+00 5.97E+00 <50 LLD OK<18 BaLa-140 <6.74E+00 0.00E+00 6.74E+00 <200 LLD OK<15 Page 8 of 11Report Generated @ 8/27/2015 16:44:39 job_report_grouped_by_media EnRad Laboratory MNS Building 7405 (MG03A2) 13339 Hagers Ferry RoadHuntersville, NC 28078 (980)875-5371 EnRad Laboratory Page 8 of 12 08.27.2015 Radiological Data for MCGUIRE 380963Sample #:Station:MCGUIRE Collection End: 7/30/2015 12:15:00 Collection Start:7/30/2015 12:15:00Location:MW-11_ML1 [ MNS Landfill 1 / MW-11 ( LANDFILL ) ] Ground Water MNS_9JUN2015_AJob: GW GAMMAGW Gamma Spectroscopy Ground Water Analysis Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Be-7 <4.13E+01 0.00E+00 4.13E+01 K-40 <9.93E+01 0.00E+00 9.93E+01 H3 Tritium Analysis of Water Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL H3GW <1.54E+01 0.00E+00 1.88E+02 <20000 LLD OK<250 380964Sample #:Station:MCGUIRE Collection End: 7/30/2015 13:10:00 Collection Start:7/30/2015 13:10:00Location:MW-11D_ML1 [ MNS Landfill 1 / MW-11D ( LANDFILL ) ] Ground Water MNS_9JUN2015_AJob: GW ALPHABETA Gross Alpha / Beta Analysis Waters Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Alpha <-3.3E-02 0.00E+00 8.84E-01 Beta <-1.7E+00 0.00E+00 1.44E+00 LLD OK<4 GAMMAGW Gamma Spectroscopy Ground Water Analysis Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Mn-54 <5.21E+00 0.00E+00 5.21E+00 <1000 LLD OK<15 Co-58 <6.03E+00 0.00E+00 6.03E+00 <1000 LLD OK<15 Fe-59 <1.11E+01 0.00E+00 1.11E+01 <400 LLD OK<30 Co-60 <3.80E+00 0.00E+00 3.80E+00 <300 LLD OK<15 Zn-65 <1.14E+01 0.00E+00 1.14E+01 <300 LLD OK<30 Zr-95 <9.18E+00 0.00E+00 9.18E+00 <400 LLD OK<15 Nb-95 <6.47E+00 0.00E+00 6.47E+00 <400 LLD OK<15 I-131 <6.49E+00 0.00E+00 6.49E+00 LLD OK<15 Cs-134 <6.06E+00 0.00E+00 6.06E+00 <30 LLD OK<15 Cs-137 <6.41E+00 0.00E+00 6.41E+00 <50 LLD OK<18 BaLa-140 <8.60E+00 0.00E+00 8.60E+00 <200 LLD OK<15 Be-7 <5.19E+01 0.00E+00 5.19E+01 K-40 9.42E+01 5.82E+01 8.07E+01 H3 Tritium Analysis of Water Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL H3GW <-2.5E+01 0.00E+00 1.91E+02 <20000 LLD OK<250 Page 9 of 11Report Generated @ 8/27/2015 16:44:39 job_report_grouped_by_media EnRad Laboratory MNS Building 7405 (MG03A2) 13339 Hagers Ferry RoadHuntersville, NC 28078 (980)875-5371 EnRad Laboratory Page 9 of 12 08.27.2015 Radiological Data for MCGUIRE 380966Sample #:Station:MCGUIRE Collection End: 7/30/2015 14:30:00 Collection Start:7/30/2015 14:30:00Location:MW-12D_ML1 [ MNS Landfill 1 / MW-12D ( LANDFILL ) ] Ground Water MNS_9JUN2015_AJob: GW ALPHABETA Gross Alpha / Beta Analysis Waters Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Alpha <-1.9E-01 0.00E+00 1.06E+00 Beta <-1.7E+00 0.00E+00 1.47E+00 LLD OK<4 GAMMAGW Gamma Spectroscopy Ground Water Analysis Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Mn-54 <6.01E+00 0.00E+00 6.01E+00 <1000 LLD OK<15 Co-58 <6.08E+00 0.00E+00 6.08E+00 <1000 LLD OK<15 Fe-59 <8.55E+00 0.00E+00 8.55E+00 <400 LLD OK<30 Co-60 <6.03E+00 0.00E+00 6.03E+00 <300 LLD OK<15 Zn-65 <9.28E+00 0.00E+00 9.28E+00 <300 LLD OK<30 Zr-95 <1.03E+01 0.00E+00 1.03E+01 <400 LLD OK<15 Nb-95 <5.51E+00 0.00E+00 5.51E+00 <400 LLD OK<15 I-131 <6.32E+00 0.00E+00 6.32E+00 LLD OK<15 Cs-134 <3.79E+00 0.00E+00 3.79E+00 <30 LLD OK<15 Cs-137 <4.98E+00 0.00E+00 4.98E+00 <50 LLD OK<18 BaLa-140 <5.51E+00 0.00E+00 5.51E+00 <200 LLD OK<15 Be-7 6.06E+00 2.47E+01 4.41E+01 K-40 9.15E+01 5.66E+01 7.83E+01 H3 Tritium Analysis of Water Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL H3GW <-7.7E+00 0.00E+00 1.89E+02 <20000 LLD OK<250 380967Sample #:Station:MCGUIRE Collection End: 7/30/2015 12:50:00 Collection Start:7/30/2015 12:50:00Location:SW-1_ML1 [ MNS Landfill 1 / SW-1 ( LANDFILL ) ] Ground Water MNS_9JUN2015_AJob: GW ALPHABETA Gross Alpha / Beta Analysis Waters Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Alpha <-5.1E-01 0.00E+00 1.22E+00 Beta <-8.7E-01 0.00E+00 1.53E+00 LLD OK<4 GAMMAGW Gamma Spectroscopy Ground Water Analysis Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Mn-54 <4.36E+00 0.00E+00 4.36E+00 <1000 LLD OK<15 Co-58 <5.73E+00 0.00E+00 5.73E+00 <1000 LLD OK<15 Fe-59 <1.17E+01 0.00E+00 1.17E+01 <400 LLD OK<30 Page 10 of 11Report Generated @ 8/27/2015 16:44:39 job_report_grouped_by_media EnRad Laboratory MNS Building 7405 (MG03A2) 13339 Hagers Ferry RoadHuntersville, NC 28078 (980)875-5371 EnRad Laboratory Page 10 of 12 08.27.2015 Radiological Data for MCGUIRE 380967Sample #:Station:MCGUIRE Collection End: 7/30/2015 12:50:00 Collection Start:7/30/2015 12:50:00Location:SW-1_ML1 [ MNS Landfill 1 / SW-1 ( LANDFILL ) ] Ground Water MNS_9JUN2015_AJob: GW GAMMAGW Gamma Spectroscopy Ground Water Analysis Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL Co-60 <4.93E+00 0.00E+00 4.93E+00 <300 LLD OK<15 Zn-65 <1.15E+01 0.00E+00 1.15E+01 <300 LLD OK<30 Zr-95 <8.13E+00 0.00E+00 8.13E+00 <400 LLD OK<15 Nb-95 <5.09E+00 0.00E+00 5.09E+00 <400 LLD OK<15 I-131 <6.25E+00 0.00E+00 6.25E+00 LLD OK<15 Cs-134 <3.91E+00 0.00E+00 3.91E+00 <30 LLD OK<15 Cs-137 <4.93E+00 0.00E+00 4.93E+00 <50 LLD OK<18 BaLa-140 <6.56E+00 0.00E+00 6.56E+00 <200 LLD OK<15 Be-7 <4.78E+01 0.00E+00 4.78E+01 K-40 6.11E+01 4.60E+01 6.56E+01 H3 Tritium Analysis of Water Units:pCi/l Calculated MDA 2 Sigma Error Activity SLC/ODCM LLD Fraction SLC/ODCM RPT LVL H3GW <4.80E+01 0.00E+00 1.87E+02 <20000 LLD OK<250 Page 11 of 11Report Generated @ 8/27/2015 16:44:39 job_report_grouped_by_media EnRad Laboratory MNS Building 7405 (MG03A2) 13339 Hagers Ferry RoadHuntersville, NC 28078 (980)875-5371 EnRad Laboratory Page 11 of 12 08.27.2015 E n R a d L a b o r a t o r y P a g e 1 2 o f 1 2 0 8 . 2 7 . 2 0 1 5