9809_WilsonCountyWestsideCDLF_GWMR_26301_20160511

May 12, 2016

Mr. Ervin Lane, Hydrogeologist
NC Division of Waste Management
Solid Waste Section
Mail Service Center 1646
Raleigh, NC 27699-1646

Re: 2016 First Semi-Annual Water Quality Monitoring Results
Westside C&D Facility
Wilson, North Carolina
Permit #98-09

Dear Ervin:

Babb & Associates, P.A. has completed the 2016 first semi-annual sampling event at the Westside C&D
facility in Wilson, NC. On April 20, 2016, four groundwater monitoring wells were sampled and analyzed
for volatile organic compounds (VOCs) by EPA Method 8260 and Appendix I inorganic compounds.

A site map is provided with this report which shows the groundwater sample locations and shallow
potentiometric surface. Additional attachments to this report include tables summarizing the groundwater
analytical results and field parameters (Table 1), well construction information (Table 2), and groundwater
flow rates (Table 3). The laboratory analytical report, in pdf and EDD formats, is included as Appendix A.

If there are any questions regarding the attached information, please contact the undersigned at (919) 325-
0696.

Respectfully,

Babb & Associates, P.A.

Gary D. Babb, P.G.
President

Enclosures

cc: Mr. Andy Davis, Director
Wilson County Solid Waste

Water Quality Monitoring Report

Westside Construction and Demolition Landfill
4537 Landfill Road
Wilson, North Carolina
Permit No. 98-09

Prepared for:

Wilson County Solid Waste
P.O. Box 1728
Wilson, North Carolina 27894

Prepared by:

Babb & Associates, P.A.
P.O. Box 37697
Raleigh, North Carolina 27627

April 2016

___________________________________
Gary D. Babb, Licensed Geologist

Table of Contents

1.0 Introduction 1
1.1 Site Information
1.2 Site Geology
1.3 Site Hydrogeology

2.0 Water Quality Monitoring Program 5
2.1 Groundwater Monitoring Network
2.2 Surface Water Monitoring Network

3.0 Water Quality Sample Collection 6
3.1 Field Sample Procedures
3.2 Field Quality Assurance
3.3 Sample Delivery/Chain-of-Custody

4.0 Laboratory Analysis 8

5.0 Hydrogeological Conditions 9

6.0 Laboratory Analytical Results 10
6.1 Groundwater Analytical Results
6.2 Surface Water Analytical Results
6.3 Quality Control Sample

7.0 Conclusions 12

Figure 1 Water Quality Monitoring Sample Locations/Potentiometric Map

Table 1 Groundwater Analytical Results/Field Parameters
Table 2 Well Construction Information/Elevations
Table 3 Groundwater Flow Rates

Appendix A ENCO Laboratory Analytical Report

Westside C&D Facility Water Quality Monitoring Report
April 2016 Page 1

1.0 Introduction

1.1 Site Information

The Westside Construction and Demolition (C&D) facility is located approximately 3.5
miles east of downtown Wilson, NC at the intersection of NC 42 and Tucker Court. The
Westside C&D facility is located on property that was previously used as a borrow site
for the closed landfill site which is located approximately 350 feet to the east of the
Westside C&D property boundary. The western boundary of the site is established by the
center-line run of Buck Branch. The adjoining properties on the west and east are owned
by Wilson County. To the west, Wilson County has purchased the 76 acre property
identified as the Mohesky Farm which provides additional off-site borrow resources for
Wilson County Landfill projects. The closed Wilson County Landfill site is located due
east of the Westside C&D site. Property further south of the Westside C&D facility is
wooded and contains wetlands associated with the Toisnot Swamp. Prior to construction
of the Westside C&D facility, agriculture was the primary land use in this area of Wilson
County.

Surrounding properties within 1,500 feet of the site are currently being used for farming,
residential, or solid waste management purposes. Land south of the site is mostly
wooded land with wetlands associated with the Toisnot Swamp. Land immediately west
of the site is owned by Wilson County and used for recycling/reclaimation and other solid
waste management activities. Land north of the Site is mostly used for farmland with
wooded areas. Land east of the Site is occupied by the closed Wilson County Landfill.

1.2 Site Geology

The Westside C&D facility is located in the western portion of the Carolina Coastal Plain
near the Fall Line. The Fall Line is the province boundary between the Piedmont and the

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April 2016 Page 2

Coastal Plain provinces. It represents a significant change in lithology, which also
reflects a change in stream gradients. Lithology of the Piedmont province is primarily
igneous and metamorphic while the Coastal Plain province is primarily sedimentary. In
general, rivers and streams in the Piedmont Province have higher flow rates with well
defined channels while Coastal Plain rivers and streams are meandering with lesser
defined channels resulting in swamps and bays. These streams, swamps, and bays are the
major discharge point of the uppermost aquifer.

The Carolina Coastal Plain is underlain by flat-lying to very gently eastward dipping
sedimentary strata which overlay a foundation of crystalline rocks. These sediments
were deposited during repeated marine transgressive and regressive cycles due to
fluctuations in sea level caused by expansion and recession of glacial ice caps during the
Pliocene and early Pleistocene epochs (approximately 2 to 5 million years ago).

Sediments in the area of the Westside C&D facility are classified as being in the
Yorktown Formation. Information gathered from the Geologic Map of North Carolina,
1985 and The Geology of the Carolina, 1991, cites that sediments of the Yorktown
Formation are fossiliferous clay with varying amounts of fine-grained sand, silty sand,
sandy silt, silty clay, and bluish gray shell material. These types of deposits are found
mainly north of the Neuse River and are commonly concentrated in lenses and vary in
vertical and horizontal dimensions. The topography of the Coastal Plain is characterized
by flat to gently undulating relief.

1.3 Site Hydrogeology

The subsurface conditions observed at the site reflects the regional Coastal Plain
characteristics. The depositional environment is influenced by Buck Branch and Toisnot

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April 2016 Page 3

Swamp where the fluvial sediments are mixed with marine sediments in an estuarine
setting. Where these streams once flowed into the Atlantic Ocean, a much broader river
was likely present. Swift currents during flood conditions may have deposited lenticular
beds of sand and other sediments. Incoming tidal currents rework the stream sediments,
creating alternating layers of fluvial and marine sediments.

The local stratigraphy is characterized by relatively thin layers of fluvial and marine silt,
sand, and clay in varying textures and colors. Typically, the color of fluvial sediments
are tan, brown, light grey or orange. With the unconformities expected in the
depositional environment, the typical profile includes a lean clay overlying poorly graded
sands, interbedded with thin clay and clayey sand lenses. The water bearing zone is
present in coarse and well graded sand layers, typically beneath surficial clay. Below the
fluvial sediments, a marine clay layer is consistently encountered. This marine clay unit
is typically dark grey, fat, and laminated with microlenses of fine sand. Below the
marine clay, a dark greenish grey silty clayey sand overlies the residual, fully weathered
bedrock. The bedrock was encountered approximately 30-35 feet below the disturbed
land surface, at an elevation of 60 to 64 feet mean sea level.

Aquifer testing was conducted on six wells at the Westside C&D Landfill site. The
aquifer testing was performed on February 12-13, 2003 and consisted of rising and falling
head tests (slug tests) on wells P-103, P-104, P-105, P-106, P-108, and P-109. The
purpose of the tests were to assess the values of horizontal hydraulic conductivity (K) at
various locations within the water table aquifer. The results of the aquifer tests are
provided below:

Westside C&D Facility Water Quality Monitoring Report
April 2016 Page 4

Well Number Test Type K (centimeters/second)
P-103 (GMW-3) Falling 5.54 x 10-4
P-104 Falling 7.02 x 10-2
P-104 Rising 1.05 x 10-1
P-105 Falling 1.03 x 10-2
P-105 Rising 1.50 x 10-2
P-106 Falling 3.23 x 10-4
P-108 Falling 2.25 x 10-3
P-108 Rising 1.84 x 10-3
P-109 Falling 4.01 x 10-4

The aquifer testing performed for the site indicates that the upper water table aquifer
provides hydraulic conductivity values which are directly related to presence of low
permeability clays. The average hydraulic conductivity value for wells completed in
primarily sandy material (P-104, P-105, P-108) is 4.09 x 10-2. The average hydraulic
conductivity for wells completed in primarily clayey material (P-103, P-106, P-109) is
3.29 x 10-4. Based on the heterogeneity of the subsurface materials encountered during
installation of the wells, the hydraulic conductivity is expected to vary based on the
presence/absence of clayey soil.

Westside C&D Facility Water Quality Monitoring Report
April 2016 Page 5

2.0 Water Quality Monitoring Program

The water quality monitoring network at the Westside C&D facility is evaluated on a semi-
annual basis. The location of the groundwater samples collected during the semi-annual
monitoring events is shown on the attached Figure 1.

2.1 Groundwater Monitoring Network

There are four groundwater monitoring wells located at the facility that comprise the
existing groundwater monitoring system (Figure 1). Monitoring well GMW-1 is located
on the northeast corner of the landfill area and serves as the upgradient groundwater
monitoring well providing background water quality. Monitoring well GMW-2 is located
on the southwest side of the landfill and monitors hydraulically downgradient
groundwater quality. Monitoring well GMW-3 is located on the western side of the
landfill and monitors hydraulically downgradient groundwater quality. Monitoring well
GMW-4 is located on the northwest side of the landfill and monitors hydraulically
downgradient groundwater quality. Table 2 provides monitoring well construction
information including installation date, well depth/screened interval, survey elevations,
and lat/long for each well location. Table 3 provides the estimated hydraulic conductivity
values for select monitoring wells based on falling/rising head slug tests.

Westside C&D Facility Water Quality Monitoring Report
April 2016 Page 6

3.0 Water Quality Sample Collection

Samples of groundwater were collected in accordance with the approved Westside C&D 2010
Water Quality Monitoring Plan and the 2008 NC Solid Waste Section Guidelines for
Groundwater, Soil, and Surface Water Sampling Guidance Document. A brief description of the
sample collection procedure is provided below.

3.1 Field Sample Procedures

Prior to groundwater sampling, water levels were obtained from each well using an
electric water level meter capable of measuring the depth to water to the nearest 0.01 feet.
This information was later used to determine the elevation of the water table in each
monitoring well relative to surveyed datum (Table 2). The depth to water in each well
was also used to determine the volume of standing water in the well casing. This
information allowed for the purging of a minimum of three casing volumes from each
well prior to sample collection to assure a fresh groundwater sample was collected. New
disposable laboratory gloves were worn by sampling personnel and each well was purged
and sampled with a new disposable bailer which was discarded after use.

After the monitoring wells had been allowed to recover from purging, samples were
collected in the following order:

 Volatile organic compounds
 Inorganic compounds
 Field Parameters (pH, Conductivity, Temperature)

The samples are collected directly in the laboratory-supplied containers which are pre-
filled with the appropriate preservative. No filtering of the samples is performed prior to
collection. After collection, the samples are placed in a cooler on ice for overnight
shipment to the analytical laboratory.

Westside C&D Facility Water Quality Monitoring Report
April 2016 Page 7

3.2 Field Quality Assurance

One trip blank sample was prepared by the analytical laboratory and accompanied the
sample shipment until receipt back at the laboratory. The trip blank sample is analyzed
for volatile organic compounds only. Temperature blanks are also provided with the
sample shipments to assure the proper temperature is maintained until delivery to the
analytical laboratory.

3.3 Sample Delivery/Chain of Custody

All groundwater samples are stored in coolers on ice immediately after collection.
Individual sample containers for each well or surface water sample are placed in zip lock
plastic bags to reduce the potential for cross contamination. Chain-of-Custody control
documents are prepared and shipped with each cooler. Custody seals are also used for
each cooler to maintain sample integrity until delivery to the analytical laboratory. The
sample coolers are shipped via Federal Express for next morning delivery to the
analytical laboratory.

Westside C&D Facility Water Quality Monitoring Report
April 2016 Page 8

4.0 Laboratory Analysis

The samples were analyzed for parameters specified by the Solid Waste Section for Detection
Monitoring at permitted solid waste facilities. The standard Detection Monitoring Program for
groundwater and surface water samples consists of the Appendix I parameters. The Appendix I
analysis consists of volatile organic compounds by EPA Method 8260B and inorganic
compounds by EPA Methods 6010C/6020A. The compound tetrahydrofuran is included with
the volatile organic analyses.

The laboratory performing the water quality analysis is Environmental Conservation
Laboratories, Inc. (ENCO) of Cary, North Carolina, which is a NC Certified Laboratory.
Internal quality control samples, including matrix spikes/matrix spike duplicates, are performed
by ENCO for each set of samples. The ENCO laboratory report, including internal quality
control samples, is provided with this report in Appendix A.

Westside C&D Facility Water Quality Monitoring Report
April 2016 Page 9

5.0 Hydrogeological Conditions

The depth to groundwater was measured in the four compliance monitoring wells during the
April 19-20, 2016 monitoring event. The groundwater elevations were calculated relative to the
surveyed measuring point (top of casing) for each monitoring well. The groundwater elevations
are summarized on Table 2 and the potentiometric surface of the shallow water table is shown on
Figure 1.

The general direction of groundwater flow, based on the water level information collected during
this monitoring event, is also shown on Figure 1. Groundwater flow direction is generally to the
west-southwest, toward the Toisnot Swamp Canal.

Based on the results of prior hydrologic tests conducted at the site, the groundwater flow rate in
the shallow saprolite ranges from 0.916 ft/day to 297.64 ft/day. The average hydraulic
conductivity and transmissivity values for the site are provided on Table 3.

Westside C&D Facility Water Quality Monitoring Report
April 2016 Page 10

6.0 Laboratory Analytical Results

Final laboratory analytical results for the samples collected on April 20, 2016 were received
from the analytical laboratory on May 3, 2016. A summary of the analytical results are provided
on Table 1 (groundwater), Table 2 (surface water), and Table 3 (field parameters).

6.1 Groundwater Analytical Results

During this monitoring event, only one volatile organic compound (VOCs) was detected
at concentrations exceeding the Solid Waste Section Limits (SWSLs). The compound
1,2-dichloropropane was reported in monitoring well GMW-3 at a concentration of 2.3
ug/l. The established 2L Groundwater Standard for 1,2-dichloropropane is 0.6 ug/l. No
other VOCs were reported in any of the monitoring wells above the laboratory detection
limits, SWSLs, or 2L Groundwater Standards.

The laboratory analyses did not report any concentrations of inorganic compounds above
the 2L Groundwater Standards. The inorganic compound barium was reported above the
laboratory detection limit and SWSL in monitoring wells GMW-1, GMW-3, and GMW-
4; however, the concentrations did not exceed the established 2L Groundwater Standard.
Monitoring well GMW-3 reported a detectable concentration of beryllium; however,
there is no established 2L Groundwater Standard for this compound. Monitoring wells
GMW-2 and GMW-3 reported detectable concentrations of cobalt; however, there is no
established 2L Groundwater Standard for this compound. Monitoring wells GMW-1,
GMW-2, and GMW-3 reported detectable concentrations of zinc; however, the reported
concentrations were well below the established 2L Groundwater Standard. A summary
of the groundwater laboratory analytical results is provided on Table 1.

Westside C&D Facility Water Quality Monitoring Report
April 2016 Page 11

6.2 Quality Control Sample

The laboratory supplied trip blank was broken during field sampling activities and as
such could not be analyzed. The trip blank for the samples collected during the same
monitoring event at the closed Wilson County Landfill did not detect any VOCs at a
concentration equaling or exceeding laboratory quantitation limits.

Westside C&D Facility Water Quality Monitoring Report
April 2016 Page 12

7.0 Conclusions

The results of this monitoring event report only minor variants from the established NC 2L
Groundwater Standards. Based on the results of this water quality monitoring event, the
Westside C&D facility will remain in Detection Monitoring in accordance with Title 15A NACA
13B .1600. The 2016 fall semi-annual water quality monitoring event is tentatively scheduled
for October 2016.

Attachments to this report include tables summarizing the groundwater analytical results and
field parameters (Tables 1), well construction information (Table 2), and hydrologic test results
(Table 3). A copy of the laboratory analytical report in pdf and EDD formats is also included
with this report in Appendix A.

SITE MAP

TABLES

TABLE 1
April 2016 Groundwater Analytical Results
Westside CDLF Facility
Wilson County, North Carolina
Permit No. 98-09
Parameter GMW-1 GMW-2 GMW-3 GMW-4 2L Standard
pH 6.1 5.4 4.8 5.4 6.5 - 8.5
Conductivity 185 361 260 152 NE
Temperature 15.8 15.1 16.0 16.1 NE
Inorganics (ug/l)
Antimony BQL 0.282 J BQL BQL 10
Barium 104 78.4 J 155 72.7 700
Beryllium 0.986 J 0.218 J 2.02 BQL NE
Cadmium BQL 0.402 J BQL BQL 2
Cobalt 8.31 J 63.6 11.2 BQL NE
Copper 1.96 J BQL BQL BQL 1000
Nickel 10.8 J 14.8 J 16.7 J 2.49 J 100
Thallium 0.125 J 0.154 J BQL BQL NE
Zinc 18.6 28.6 54.8 7.73 J 1000
8260 volatiles (ug/l)
1,2-Dichloropropane BQL BQL 2.3 BQL 0.6
Notes:
Samples collected on April 20, 2016
BQL - Below laboratory quantitation limits
J - Between MDL and RL
NE - Not established
Bold concentrations equal or exceed established standards
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LAB REPORT

102-A Woodwinds Industrial Court
Cary NC, 27511
919.467.3090 919.467.3515Phone:FAX:www.encolabs.com
Environmental Conservation Laboratories, Inc.
ENCO Workorder(s): CZ05054
Raleigh, NC 27606
Unless otherwise noted in an attached project narrative, all samples were received in
acceptable condition and processed in accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained in this report are in compliance with NELAC standards, except
as noted in the project narrative. This report shall not be reproduced except in full, without
the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further information, please do not hesitate to contact me.
Sincerely,
Enclosure(s)
Project Number: [none], Project Name/Desc: Wilson C&D Landfill
Attn: Gary Babb
Babb & Associates (BA024)
3605 Country Cove Lane
Bill Scott
Project Manager
Tuesday, May 3, 2016
RE: Laboratory Results for
Dear Gary Babb,
Enclosed is a copy of your laboratory report for test samples received by our laboratory on
Thursday, April 21, 2016.
The total number of pages in this report, including this page is 22.
www.encolabs.com
SAMPLE SUMMARY/LABORATORY CHRONICLE
9809-GMW1 CZ05054-01 Sampled:04/20/16 08:00 Received:04/21/16 10:30Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 6010D 10/17/16 04/26/16 10:39 4/27/2016 12:25
EPA 6020B 10/17/16 04/26/16 10:50 4/28/2016 12:23
EPA 8260B 05/04/16 05/02/16 12:38 5/3/2016 08:16
9809-GMW2 CZ05054-02 Sampled:04/20/16 08:08 Received:04/21/16 10:30Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 6010D 10/17/16 04/26/16 10:39 4/27/2016 12:47
EPA 6020B 10/17/16 04/26/16 10:50 4/28/2016 12:52
EPA 8260B 05/04/16 05/02/16 12:38 5/3/2016 08:45
9809-GMW3 CZ05054-03 Sampled:04/20/16 08:16 Received:04/21/16 10:30Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 6010D 10/17/16 04/26/16 10:39 4/27/2016 12:50
EPA 6020B 10/17/16 04/26/16 10:50 4/28/2016 12:56
EPA 8260B 05/04/16 05/02/16 12:38 5/3/2016 09:14
9809-GMW4 CZ05054-04 Sampled:04/20/16 08:22 Received:04/21/16 10:30Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 6010D 10/17/16 04/26/16 10:39 4/27/2016 12:53
EPA 6020B 10/17/16 04/26/16 10:50 4/28/2016 12:59
EPA 8260B 05/04/16 05/02/16 12:38 5/3/2016 09:43
Page 2 of 22
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NORTH CAROLINA SWS SAMPLE DETECTION SUMMARY
Analyte MethodUnitsResults
Lab ID:Client ID:9809-GMW1 CZ05054-01
Flag NotesMDLNC SWSLMRLDF
104 ug/L EPA 6010D 10010.01.001Barium - Total
0.986 ug/L EPA 6010DJ 11.000.1001Beryllium - Total
8.31 ug/L EPA 6010DJ 1010.01.101Cobalt - Total
1.96 ug/L EPA 6010DJ 1010.01.601Copper - Total
10.8 ug/L EPA 6010DJ 5010.02.201Nickel - Total
0.125 ug/L EPA 6020BJ 5.51.000.1101Thallium - Total
18.6 ug/L EPA 6010D 1010.04.401Zinc - Total
Analyte MethodUnitsResults
Lab ID:Client ID:9809-GMW2 CZ05054-02
Flag NotesMDLNC SWSLMRLDF
0.282 ug/L EPA 6020BJ 62.000.2201Antimony - Total
78.4 ug/L EPA 6010DJ 10010.01.001Barium - Total
0.218 ug/L EPA 6010DJ 11.000.1001Beryllium - Total
0.402 ug/L EPA 6010DJ 11.000.3601Cadmium - Total
63.6 ug/L EPA 6010D 1010.01.101Cobalt - Total
14.8 ug/L EPA 6010DJ 5010.02.201Nickel - Total
0.154 ug/L EPA 6020BJ 5.51.000.1101Thallium - Total
28.6 ug/L EPA 6010D 1010.04.401Zinc - Total
Analyte MethodUnitsResults
Lab ID:Client ID:9809-GMW3 CZ05054-03
Flag NotesMDLNC SWSLMRLDF
2.3 ug/L EPA 8260B 11.00.1011,2-Dichloropropane
155 ug/L EPA 6010D 10010.01.001Barium - Total
2.02 ug/L EPA 6010D 11.000.1001Beryllium - Total
11.2 ug/L EPA 6010D 1010.01.101Cobalt - Total
16.7 ug/L EPA 6010DJ 5010.02.201Nickel - Total
54.8 ug/L EPA 6010D 1010.04.401Zinc - Total
Analyte MethodUnitsResults
Lab ID:Client ID:9809-GMW4 CZ05054-04
Flag NotesMDLNC SWSLMRLDF
72.7 ug/L EPA 6010DJ 10010.01.001Barium - Total
2.49 ug/L EPA 6010DJ 5010.02.201Nickel - Total
1.56 ug/L EPA 6010DJ 2510.01.401Vanadium - Total
7.73 ug/L EPA 6010DJ 1010.04.401Zinc - Total
Page 3 of 22
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ANALYTICAL RESULTS
9809-GMW1Description:Lab Sample ID:CZ05054-01 04/21/16 10:30Received:
Matrix:Water Sampled:04/20/16 08:00 Work Order:CZ05054
Wilson C&D LandfillProject:Sampled By:ROBERT WELDY
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL
ug/L EPA 8260B 05/03/16 08:161,1,1,2-Tetrachloroethane [630-20-6] ^0.17 MSZ1.00.17 U 51
ug/L EPA 8260B 05/03/16 08:161,1,1-Trichloroethane [71-55-6] ^0.12 MSZ1.00.12 U 11
ug/L EPA 8260B 05/03/16 08:161,1,2,2-Tetrachloroethane [79-34-5] ^0.28 MSZ1.00.28 U 31
ug/L EPA 8260B 05/03/16 08:161,1,2-Trichloroethane [79-00-5] ^0.14 MSZ1.00.14 U 11
ug/L EPA 8260B 05/03/16 08:161,1-Dichloroethane [75-34-3] ^0.13 MSZ1.00.13 U 51
ug/L EPA 8260B 05/03/16 08:161,1-Dichloroethene [75-35-4] ^0.21 MSZ1.00.21 U 51
ug/L EPA 8260B 05/03/16 08:161,2,3-Trichloropropane [96-18-4] ^0.23 MSZ1.00.23 U 11
ug/L EPA 8260B 05/03/16 08:161,2-Dibromo-3-chloropropane [96-12-8] ^0.48 MSZ1.00.48 U 131
ug/L EPA 8260B 05/03/16 08:161,2-Dibromoethane [106-93-4] ^0.66 MSZ1.00.66 U 11
ug/L EPA 8260B 05/03/16 08:161,2-Dichlorobenzene [95-50-1] ^0.19 MSZ1.00.19 U 51
ug/L EPA 8260B 05/03/16 08:161,2-Dichloroethane [107-06-2] ^0.21 MSZ1.00.21 U 11
ug/L EPA 8260B 05/03/16 08:161,2-Dichloropropane [78-87-5] ^0.10 MSZ1.00.10 U 11
ug/L EPA 8260B 05/03/16 08:161,4-Dichlorobenzene [106-46-7] ^0.19 MSZ1.00.19 U 11
ug/L EPA 8260B 05/03/16 08:162-Butanone [78-93-3] ^1.3 MSZ5.01.3 U 1001
ug/L EPA 8260B 05/03/16 08:162-Hexanone [591-78-6] ^0.88 MSZ5.00.88 U 501
ug/L EPA 8260B 05/03/16 08:164-Methyl-2-pentanone [108-10-1] ^1.1 MSZ5.01.1 U 1001
ug/L EPA 8260B 05/03/16 08:16Acetone [67-64-1] ^1.2 MSZ5.01.2 U 1001
ug/L EPA 8260B 05/03/16 08:16Acrylonitrile [107-13-1] ^3.5 MSZ103.5 U 2001
ug/L EPA 8260B 05/03/16 08:16Benzene [71-43-2] ^0.15 MSZ1.00.15 U 11
ug/L EPA 8260B 05/03/16 08:16Bromochloromethane [74-97-5] ^0.48 MSZ1.00.48 U 31
ug/L EPA 8260B 05/03/16 08:16Bromodichloromethane [75-27-4] ^0.17 MSZ1.00.17 U 11
ug/L EPA 8260B 05/03/16 08:16Bromoform [75-25-2] ^0.22 MSZ1.00.22 U 31
ug/L EPA 8260B 05/03/16 08:16Bromomethane [74-83-9] ^0.14 MSZ1.00.14 U 101
ug/L EPA 8260B 05/03/16 08:16Carbon disulfide [75-15-0] ^1.5 MSZ5.01.5 U 1001
ug/L EPA 8260B 05/03/16 08:16Carbon tetrachloride [56-23-5] ^0.17 MSZ1.00.17 U 11
ug/L EPA 8260B 05/03/16 08:16Chlorobenzene [108-90-7] ^0.17 MSZ1.00.17 U 31
ug/L EPA 8260B 05/03/16 08:16Chloroethane [75-00-3] ^0.23 MSZ1.00.23 U 101
ug/L EPA 8260B 05/03/16 08:16Chloroform [67-66-3] ^0.18 MSZ1.00.18 U 51
ug/L EPA 8260B 05/03/16 08:16Chloromethane [74-87-3] ^0.13 MSZ1.00.13 U 11
ug/L EPA 8260B 05/03/16 08:16cis-1,2-Dichloroethene [156-59-2] ^0.15 MSZ1.00.15 U 51
ug/L EPA 8260B 05/03/16 08:16cis-1,3-Dichloropropene [10061-01-5] ^0.20 MSZ1.00.20 U 11
ug/L EPA 8260B 05/03/16 08:16Dibromochloromethane [124-48-1] ^0.17 MSZ1.00.17 U 31
ug/L EPA 8260B 05/03/16 08:16Dibromomethane [74-95-3] ^0.27 MSZ1.00.27 U 101
ug/L EPA 8260B 05/03/16 08:16Ethylbenzene [100-41-4] ^0.13 MSZ1.00.13 U 11
ug/L EPA 8260B 05/03/16 08:16Iodomethane [74-88-4] ^1.7 MSZ5.01.7 U 101
ug/L EPA 8260B 05/03/16 08:16m,p-Xylenes [108-38-3/106-42-3] ^0.17 MSZ2.00.17 U NE1
ug/L EPA 8260B 05/03/16 08:16Methylene chloride [75-09-2] ^0.23 MSZ1.00.23 U 11
ug/L EPA 8260B 05/03/16 08:16o-Xylene [95-47-6] ^0.065 MSZ1.00.065 U NE1
ug/L EPA 8260B 05/03/16 08:16Styrene [100-42-5] ^0.11 MSZ1.00.11 U 11
ug/L EPA 8260B 05/03/16 08:16Tetrachloroethene [127-18-4] ^0.17 MSZ1.00.17 U 11
ug/L EPA 8260B 05/03/16 08:16Tetrahydrofuran [109-99-9] ^0.80 MSZ1.00.80 U 1
ug/L EPA 8260B 05/03/16 08:16Toluene [108-88-3] ^0.14 MSZ1.00.14 U 11
ug/L EPA 8260B 05/03/16 08:16trans-1,2-Dichloroethene [156-60-5] ^0.21 MSZ1.00.21 U 51
ug/L EPA 8260B 05/03/16 08:16trans-1,3-Dichloropropene [10061-02-6] ^0.15 MSZ1.00.15 U 11
ug/L EPA 8260B 05/03/16 08:16trans-1,4-Dichloro-2-butene [110-57-6] ^0.70 MSZ1.00.70 U 1001
ug/L EPA 8260B 05/03/16 08:16Trichloroethene [79-01-6] ^0.15 MSZ1.00.15 U 11
ug/L EPA 8260B 05/03/16 08:16Trichlorofluoromethane [75-69-4] ^0.24 MSZ1.00.24 U 11
ug/L EPA 8260B 05/03/16 08:16Vinyl acetate [108-05-4] ^0.95 MSZ5.00.95 U 501
Page 4 of 22
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9809-GMW1Description:Lab Sample ID:CZ05054-01 04/21/16 10:30Received:
Matrix:Water Sampled:04/20/16 08:00 Work Order:CZ05054
Wilson C&D LandfillProject:Sampled By:ROBERT WELDY
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL
ug/L EPA 8260B 05/03/16 08:16Vinyl chloride [75-01-4] ^0.32 MSZ1.00.32 U 11
ug/L EPA 8260B 05/03/16 08:16Xylenes (Total) [1330-20-7] ^0.45 MSZ3.00.45 U 51
Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF
4-Bromofluorobenzene 53-13689 %MSZEPA 8260B 05/03/16 08:166E020284450.0 1
Dibromofluoromethane 67-12990 %MSZEPA 8260B 05/03/16 08:166E020284550.0 1
Toluene-d8 59-134100 %MSZEPA 8260B 05/03/16 08:166E020285050.0 1
Page 5 of 22
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9809-GMW1Description:Lab Sample ID:CZ05054-01 04/21/16 10:30Received:
Matrix:Water Sampled:04/20/16 08:00 Work Order:CZ05054
Wilson C&D LandfillProject:Sampled By:ROBERT WELDY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL
ug/L EPA 6020B 04/28/16 12:23Antimony [7440-36-0] ^0.220 VLO2.000.220 U 61
ug/L EPA 6010D 04/27/16 12:25Arsenic [7440-38-2] ^6.80 JDH10.06.80 U 101
ug/L EPA 6010D 04/27/16 12:25Barium [7440-39-3] ^1.00 JDH10.0104 1001
ug/L EPA 6010D 04/27/16 12:25Beryllium [7440-41-7] ^0.100 JDH1.000.986 J 11
ug/L EPA 6010D 04/27/16 12:25Cadmium [7440-43-9] ^0.360 JDH1.000.360 U 11
ug/L EPA 6010D 04/27/16 12:25Chromium [7440-47-3] ^1.40 JDH10.01.40 U 101
ug/L EPA 6010D 04/27/16 12:25Cobalt [7440-48-4] ^1.10 JDH10.08.31 J 101
ug/L EPA 6010D 04/27/16 12:25Copper [7440-50-8] ^1.60 JDH10.01.96 J 101
ug/L EPA 6010D 04/27/16 12:25Lead [7439-92-1] ^3.10 JDH10.03.10 U 101
ug/L EPA 6010D 04/27/16 12:25Nickel [7440-02-0] ^2.20 JDH10.010.8 J 501
ug/L EPA 6020B 04/28/16 12:23Selenium [7782-49-2] ^0.910 VLO3.000.910 U 101
ug/L EPA 6010D 04/27/16 12:25Silver [7440-22-4] ^1.90 JDH10.01.90 U 101
ug/L EPA 6020B 04/28/16 12:23Thallium [7440-28-0] ^0.110 VLO1.000.125 J 5.51
ug/L EPA 6010D 04/27/16 12:25Vanadium [7440-62-2] ^1.40 JDH10.01.40 U 251
ug/L EPA 6010D 04/27/16 12:25Zinc [7440-66-6] ^4.40 JDH10.018.6 101
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.
Page 6 of 22
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9809-GMW2Description:Lab Sample ID:CZ05054-02 04/21/16 10:30Received:
Matrix:Water Sampled:04/20/16 08:08 Work Order:CZ05054
Wilson C&D LandfillProject:Sampled By:ROBERT WELDY
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL
ug/L EPA 8260B 05/03/16 08:451,1,1,2-Tetrachloroethane [630-20-6] ^0.17 MSZ1.00.17 U 51
ug/L EPA 8260B 05/03/16 08:451,1,1-Trichloroethane [71-55-6] ^0.12 MSZ1.00.12 U 11
ug/L EPA 8260B 05/03/16 08:451,1,2,2-Tetrachloroethane [79-34-5] ^0.28 MSZ1.00.28 U 31
ug/L EPA 8260B 05/03/16 08:451,1,2-Trichloroethane [79-00-5] ^0.14 MSZ1.00.14 U 11
ug/L EPA 8260B 05/03/16 08:451,1-Dichloroethane [75-34-3] ^0.13 MSZ1.00.13 U 51
ug/L EPA 8260B 05/03/16 08:451,1-Dichloroethene [75-35-4] ^0.21 MSZ1.00.21 U 51
ug/L EPA 8260B 05/03/16 08:451,2,3-Trichloropropane [96-18-4] ^0.23 MSZ1.00.23 U 11
ug/L EPA 8260B 05/03/16 08:451,2-Dibromo-3-chloropropane [96-12-8] ^0.48 MSZ1.00.48 U 131
ug/L EPA 8260B 05/03/16 08:451,2-Dibromoethane [106-93-4] ^0.66 MSZ1.00.66 U 11
ug/L EPA 8260B 05/03/16 08:451,2-Dichlorobenzene [95-50-1] ^0.19 MSZ1.00.19 U 51
ug/L EPA 8260B 05/03/16 08:451,2-Dichloroethane [107-06-2] ^0.21 MSZ1.00.21 U 11
ug/L EPA 8260B 05/03/16 08:451,2-Dichloropropane [78-87-5] ^0.10 MSZ1.00.10 U 11
ug/L EPA 8260B 05/03/16 08:451,4-Dichlorobenzene [106-46-7] ^0.19 MSZ1.00.19 U 11
ug/L EPA 8260B 05/03/16 08:452-Butanone [78-93-3] ^1.3 MSZ5.01.3 U 1001
ug/L EPA 8260B 05/03/16 08:452-Hexanone [591-78-6] ^0.88 MSZ5.00.88 U 501
ug/L EPA 8260B 05/03/16 08:454-Methyl-2-pentanone [108-10-1] ^1.1 MSZ5.01.1 U 1001
ug/L EPA 8260B 05/03/16 08:45Acetone [67-64-1] ^1.2 MSZ5.01.2 U 1001
ug/L EPA 8260B 05/03/16 08:45Acrylonitrile [107-13-1] ^3.5 MSZ103.5 U 2001
ug/L EPA 8260B 05/03/16 08:45Benzene [71-43-2] ^0.15 MSZ1.00.15 U 11
ug/L EPA 8260B 05/03/16 08:45Bromochloromethane [74-97-5] ^0.48 MSZ1.00.48 U 31
ug/L EPA 8260B 05/03/16 08:45Bromodichloromethane [75-27-4] ^0.17 MSZ1.00.17 U 11
ug/L EPA 8260B 05/03/16 08:45Bromoform [75-25-2] ^0.22 MSZ1.00.22 U 31
ug/L EPA 8260B 05/03/16 08:45Bromomethane [74-83-9] ^0.14 MSZ1.00.14 U 101
ug/L EPA 8260B 05/03/16 08:45Carbon disulfide [75-15-0] ^1.5 MSZ5.01.5 U 1001
ug/L EPA 8260B 05/03/16 08:45Carbon tetrachloride [56-23-5] ^0.17 MSZ1.00.17 U 11
ug/L EPA 8260B 05/03/16 08:45Chlorobenzene [108-90-7] ^0.17 MSZ1.00.17 U 31
ug/L EPA 8260B 05/03/16 08:45Chloroethane [75-00-3] ^0.23 MSZ1.00.23 U 101
ug/L EPA 8260B 05/03/16 08:45Chloroform [67-66-3] ^0.18 MSZ1.00.18 U 51
ug/L EPA 8260B 05/03/16 08:45Chloromethane [74-87-3] ^0.13 MSZ1.00.13 U 11
ug/L EPA 8260B 05/03/16 08:45cis-1,2-Dichloroethene [156-59-2] ^0.15 MSZ1.00.15 U 51
ug/L EPA 8260B 05/03/16 08:45cis-1,3-Dichloropropene [10061-01-5] ^0.20 MSZ1.00.20 U 11
ug/L EPA 8260B 05/03/16 08:45Dibromochloromethane [124-48-1] ^0.17 MSZ1.00.17 U 31
ug/L EPA 8260B 05/03/16 08:45Dibromomethane [74-95-3] ^0.27 MSZ1.00.27 U 101
ug/L EPA 8260B 05/03/16 08:45Ethylbenzene [100-41-4] ^0.13 MSZ1.00.13 U 11
ug/L EPA 8260B 05/03/16 08:45Iodomethane [74-88-4] ^1.7 MSZ5.01.7 U 101
ug/L EPA 8260B 05/03/16 08:45m,p-Xylenes [108-38-3/106-42-3] ^0.17 MSZ2.00.17 U NE1
ug/L EPA 8260B 05/03/16 08:45Methylene chloride [75-09-2] ^0.23 MSZ1.00.23 U 11
ug/L EPA 8260B 05/03/16 08:45o-Xylene [95-47-6] ^0.065 MSZ1.00.065 U NE1
ug/L EPA 8260B 05/03/16 08:45Styrene [100-42-5] ^0.11 MSZ1.00.11 U 11
ug/L EPA 8260B 05/03/16 08:45Tetrachloroethene [127-18-4] ^0.17 MSZ1.00.17 U 11
ug/L EPA 8260B 05/03/16 08:45Tetrahydrofuran [109-99-9] ^0.80 MSZ1.00.80 U 1
ug/L EPA 8260B 05/03/16 08:45Toluene [108-88-3] ^0.14 MSZ1.00.14 U 11
ug/L EPA 8260B 05/03/16 08:45trans-1,2-Dichloroethene [156-60-5] ^0.21 MSZ1.00.21 U 51
ug/L EPA 8260B 05/03/16 08:45trans-1,3-Dichloropropene [10061-02-6] ^0.15 MSZ1.00.15 U 11
ug/L EPA 8260B 05/03/16 08:45trans-1,4-Dichloro-2-butene [110-57-6] ^0.70 MSZ1.00.70 U 1001
ug/L EPA 8260B 05/03/16 08:45Trichloroethene [79-01-6] ^0.15 MSZ1.00.15 U 11
ug/L EPA 8260B 05/03/16 08:45Trichlorofluoromethane [75-69-4] ^0.24 MSZ1.00.24 U 11
ug/L EPA 8260B 05/03/16 08:45Vinyl acetate [108-05-4] ^0.95 MSZ5.00.95 U 501
ug/L EPA 8260B 05/03/16 08:45Vinyl chloride [75-01-4] ^0.32 MSZ1.00.32 U 11
ug/L EPA 8260B 05/03/16 08:45Xylenes (Total) [1330-20-7] ^0.45 MSZ3.00.45 U 51
Page 7 of 22
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9809-GMW2Description:Lab Sample ID:CZ05054-02 04/21/16 10:30Received:
Matrix:Water Sampled:04/20/16 08:08 Work Order:CZ05054
Wilson C&D LandfillProject:Sampled By:ROBERT WELDY
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL
Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF
4-Bromofluorobenzene 53-13680 %MSZEPA 8260B 05/03/16 08:456E020284050.0 1
Dibromofluoromethane 67-12993 %MSZEPA 8260B 05/03/16 08:456E020284750.0 1
Toluene-d8 59-13494 %MSZEPA 8260B 05/03/16 08:456E020284750.0 1
Page 8 of 22
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9809-GMW2Description:Lab Sample ID:CZ05054-02 04/21/16 10:30Received:
Matrix:Water Sampled:04/20/16 08:08 Work Order:CZ05054
Wilson C&D LandfillProject:Sampled By:ROBERT WELDY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL
ug/L EPA 6020B 04/28/16 12:52Antimony [7440-36-0] ^0.220 VLO2.000.282 J 61
ug/L EPA 6010D 04/27/16 12:47Arsenic [7440-38-2] ^6.80 JDH10.06.80 U 101
ug/L EPA 6010D 04/27/16 12:47Barium [7440-39-3] ^1.00 JDH10.078.4 J 1001
ug/L EPA 6010D 04/27/16 12:47Beryllium [7440-41-7] ^0.100 JDH1.000.218 J 11
ug/L EPA 6010D 04/27/16 12:47Cadmium [7440-43-9] ^0.360 JDH1.000.402 J 11
ug/L EPA 6010D 04/27/16 12:47Chromium [7440-47-3] ^1.40 JDH10.01.40 U 101
ug/L EPA 6010D 04/27/16 12:47Cobalt [7440-48-4] ^1.10 JDH10.063.6 101
ug/L EPA 6010D 04/27/16 12:47Copper [7440-50-8] ^1.60 JDH10.01.60 U 101
ug/L EPA 6010D 04/27/16 12:47Lead [7439-92-1] ^3.10 JDH10.03.10 U 101
ug/L EPA 6010D 04/27/16 12:47Nickel [7440-02-0] ^2.20 JDH10.014.8 J 501
ug/L EPA 6020B 04/28/16 12:52Selenium [7782-49-2] ^0.910 VLO3.000.910 U 101
ug/L EPA 6010D 04/27/16 12:47Silver [7440-22-4] ^1.90 JDH10.01.90 U 101
ug/L EPA 6020B 04/28/16 12:52Thallium [7440-28-0] ^0.110 VLO1.000.154 J 5.51
ug/L EPA 6010D 04/27/16 12:47Vanadium [7440-62-2] ^1.40 JDH10.01.40 U 251
ug/L EPA 6010D 04/27/16 12:47Zinc [7440-66-6] ^4.40 JDH10.028.6 101
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.
Page 9 of 22
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9809-GMW3Description:Lab Sample ID:CZ05054-03 04/21/16 10:30Received:
Matrix:Water Sampled:04/20/16 08:16 Work Order:CZ05054
Wilson C&D LandfillProject:Sampled By:ROBERT WELDY
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL
ug/L EPA 8260B 05/03/16 09:141,1,1,2-Tetrachloroethane [630-20-6] ^0.17 MSZ1.00.17 U 51
ug/L EPA 8260B 05/03/16 09:141,1,1-Trichloroethane [71-55-6] ^0.12 MSZ1.00.12 U 11
ug/L EPA 8260B 05/03/16 09:141,1,2,2-Tetrachloroethane [79-34-5] ^0.28 MSZ1.00.28 U 31
ug/L EPA 8260B 05/03/16 09:141,1,2-Trichloroethane [79-00-5] ^0.14 MSZ1.00.14 U 11
ug/L EPA 8260B 05/03/16 09:141,1-Dichloroethane [75-34-3] ^0.13 MSZ1.00.13 U 51
ug/L EPA 8260B 05/03/16 09:141,1-Dichloroethene [75-35-4] ^0.21 MSZ1.00.21 U 51
ug/L EPA 8260B 05/03/16 09:141,2,3-Trichloropropane [96-18-4] ^0.23 MSZ1.00.23 U 11
ug/L EPA 8260B 05/03/16 09:141,2-Dibromo-3-chloropropane [96-12-8] ^0.48 MSZ1.00.48 U 131
ug/L EPA 8260B 05/03/16 09:141,2-Dibromoethane [106-93-4] ^0.66 MSZ1.00.66 U 11
ug/L EPA 8260B 05/03/16 09:141,2-Dichlorobenzene [95-50-1] ^0.19 MSZ1.00.19 U 51
ug/L EPA 8260B 05/03/16 09:141,2-Dichloroethane [107-06-2] ^0.21 MSZ1.00.21 U 11
ug/L EPA 8260B 05/03/16 09:141,2-Dichloropropane [78-87-5] ^0.10 MSZ1.02.3 11
ug/L EPA 8260B 05/03/16 09:141,4-Dichlorobenzene [106-46-7] ^0.19 MSZ1.00.19 U 11
ug/L EPA 8260B 05/03/16 09:142-Butanone [78-93-3] ^1.3 MSZ5.01.3 U 1001
ug/L EPA 8260B 05/03/16 09:142-Hexanone [591-78-6] ^0.88 MSZ5.00.88 U 501
ug/L EPA 8260B 05/03/16 09:144-Methyl-2-pentanone [108-10-1] ^1.1 MSZ5.01.1 U 1001
ug/L EPA 8260B 05/03/16 09:14Acetone [67-64-1] ^1.2 MSZ5.01.2 U 1001
ug/L EPA 8260B 05/03/16 09:14Acrylonitrile [107-13-1] ^3.5 MSZ103.5 U 2001
ug/L EPA 8260B 05/03/16 09:14Benzene [71-43-2] ^0.15 MSZ1.00.15 U 11
ug/L EPA 8260B 05/03/16 09:14Bromochloromethane [74-97-5] ^0.48 MSZ1.00.48 U 31
ug/L EPA 8260B 05/03/16 09:14Bromodichloromethane [75-27-4] ^0.17 MSZ1.00.17 U 11
ug/L EPA 8260B 05/03/16 09:14Bromoform [75-25-2] ^0.22 MSZ1.00.22 U 31
ug/L EPA 8260B 05/03/16 09:14Bromomethane [74-83-9] ^0.14 MSZ1.00.14 U 101
ug/L EPA 8260B 05/03/16 09:14Carbon disulfide [75-15-0] ^1.5 MSZ5.01.5 U 1001
ug/L EPA 8260B 05/03/16 09:14Carbon tetrachloride [56-23-5] ^0.17 MSZ1.00.17 U 11
ug/L EPA 8260B 05/03/16 09:14Chlorobenzene [108-90-7] ^0.17 MSZ1.00.17 U 31
ug/L EPA 8260B 05/03/16 09:14Chloroethane [75-00-3] ^0.23 MSZ1.00.23 U 101
ug/L EPA 8260B 05/03/16 09:14Chloroform [67-66-3] ^0.18 MSZ1.00.18 U 51
ug/L EPA 8260B 05/03/16 09:14Chloromethane [74-87-3] ^0.13 MSZ1.00.13 U 11
ug/L EPA 8260B 05/03/16 09:14cis-1,2-Dichloroethene [156-59-2] ^0.15 MSZ1.00.15 U 51
ug/L EPA 8260B 05/03/16 09:14cis-1,3-Dichloropropene [10061-01-5] ^0.20 MSZ1.00.20 U 11
ug/L EPA 8260B 05/03/16 09:14Dibromochloromethane [124-48-1] ^0.17 MSZ1.00.17 U 31
ug/L EPA 8260B 05/03/16 09:14Dibromomethane [74-95-3] ^0.27 MSZ1.00.27 U 101
ug/L EPA 8260B 05/03/16 09:14Ethylbenzene [100-41-4] ^0.13 MSZ1.00.13 U 11
ug/L EPA 8260B 05/03/16 09:14Iodomethane [74-88-4] ^1.7 MSZ5.01.7 U 101
ug/L EPA 8260B 05/03/16 09:14m,p-Xylenes [108-38-3/106-42-3] ^0.17 MSZ2.00.17 U NE1
ug/L EPA 8260B 05/03/16 09:14Methylene chloride [75-09-2] ^0.23 MSZ1.00.23 U 11
ug/L EPA 8260B 05/03/16 09:14o-Xylene [95-47-6] ^0.065 MSZ1.00.065 U NE1
ug/L EPA 8260B 05/03/16 09:14Styrene [100-42-5] ^0.11 MSZ1.00.11 U 11
ug/L EPA 8260B 05/03/16 09:14Tetrachloroethene [127-18-4] ^0.17 MSZ1.00.17 U 11
ug/L EPA 8260B 05/03/16 09:14Tetrahydrofuran [109-99-9] ^0.80 MSZ1.00.80 U 1
ug/L EPA 8260B 05/03/16 09:14Toluene [108-88-3] ^0.14 MSZ1.00.14 U 11
ug/L EPA 8260B 05/03/16 09:14trans-1,2-Dichloroethene [156-60-5] ^0.21 MSZ1.00.21 U 51
ug/L EPA 8260B 05/03/16 09:14trans-1,3-Dichloropropene [10061-02-6] ^0.15 MSZ1.00.15 U 11
ug/L EPA 8260B 05/03/16 09:14trans-1,4-Dichloro-2-butene [110-57-6] ^0.70 MSZ1.00.70 U 1001
ug/L EPA 8260B 05/03/16 09:14Trichloroethene [79-01-6] ^0.15 MSZ1.00.15 U 11
ug/L EPA 8260B 05/03/16 09:14Trichlorofluoromethane [75-69-4] ^0.24 MSZ1.00.24 U 11
ug/L EPA 8260B 05/03/16 09:14Vinyl acetate [108-05-4] ^0.95 MSZ5.00.95 U 501
ug/L EPA 8260B 05/03/16 09:14Vinyl chloride [75-01-4] ^0.32 MSZ1.00.32 U 11
ug/L EPA 8260B 05/03/16 09:14Xylenes (Total) [1330-20-7] ^0.45 MSZ3.00.45 U 51
Page 10 of 22
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9809-GMW3Description:Lab Sample ID:CZ05054-03 04/21/16 10:30Received:
Matrix:Water Sampled:04/20/16 08:16 Work Order:CZ05054
Wilson C&D LandfillProject:Sampled By:ROBERT WELDY
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL
Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF
4-Bromofluorobenzene 53-13685 %MSZEPA 8260B 05/03/16 09:146E020284350.0 1
Dibromofluoromethane 67-12993 %MSZEPA 8260B 05/03/16 09:146E020284650.0 1
Toluene-d8 59-13493 %MSZEPA 8260B 05/03/16 09:146E020284650.0 1
Page 11 of 22
www.encolabs.com
9809-GMW3Description:Lab Sample ID:CZ05054-03 04/21/16 10:30Received:
Matrix:Water Sampled:04/20/16 08:16 Work Order:CZ05054
Wilson C&D LandfillProject:Sampled By:ROBERT WELDY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL
ug/L EPA 6020B 04/28/16 12:56Antimony [7440-36-0] ^0.220 VLO2.000.220 U 61
ug/L EPA 6010D 04/27/16 12:50Arsenic [7440-38-2] ^6.80 JDH10.06.80 U 101
ug/L EPA 6010D 04/27/16 12:50Barium [7440-39-3] ^1.00 JDH10.0155 1001
ug/L EPA 6010D 04/27/16 12:50Beryllium [7440-41-7] ^0.100 JDH1.002.02 11
ug/L EPA 6010D 04/27/16 12:50Cadmium [7440-43-9] ^0.360 JDH1.000.360 U 11
ug/L EPA 6010D 04/27/16 12:50Chromium [7440-47-3] ^1.40 JDH10.01.40 U 101
ug/L EPA 6010D 04/27/16 12:50Cobalt [7440-48-4] ^1.10 JDH10.011.2 101
ug/L EPA 6010D 04/27/16 12:50Copper [7440-50-8] ^1.60 JDH10.01.60 U 101
ug/L EPA 6010D 04/27/16 12:50Lead [7439-92-1] ^3.10 JDH10.03.10 U 101
ug/L EPA 6010D 04/27/16 12:50Nickel [7440-02-0] ^2.20 JDH10.016.7 J 501
ug/L EPA 6020B 04/28/16 12:56Selenium [7782-49-2] ^0.910 VLO3.000.910 U 101
ug/L EPA 6010D 04/27/16 12:50Silver [7440-22-4] ^1.90 JDH10.01.90 U 101
ug/L EPA 6020B 04/28/16 12:56Thallium [7440-28-0] ^0.110 VLO1.000.110 U 5.51
ug/L EPA 6010D 04/27/16 12:50Vanadium [7440-62-2] ^1.40 JDH10.01.40 U 251
ug/L EPA 6010D 04/27/16 12:50Zinc [7440-66-6] ^4.40 JDH10.054.8 101
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.
Page 12 of 22
www.encolabs.com
9809-GMW4Description:Lab Sample ID:CZ05054-04 04/21/16 10:30Received:
Matrix:Water Sampled:04/20/16 08:22 Work Order:CZ05054
Wilson C&D LandfillProject:Sampled By:ROBERT WELDY
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL
ug/L EPA 8260B 05/03/16 09:431,1,1,2-Tetrachloroethane [630-20-6] ^0.17 MSZ1.00.17 U 51
ug/L EPA 8260B 05/03/16 09:431,1,1-Trichloroethane [71-55-6] ^0.12 MSZ1.00.12 U 11
ug/L EPA 8260B 05/03/16 09:431,1,2,2-Tetrachloroethane [79-34-5] ^0.28 MSZ1.00.28 U 31
ug/L EPA 8260B 05/03/16 09:431,1,2-Trichloroethane [79-00-5] ^0.14 MSZ1.00.14 U 11
ug/L EPA 8260B 05/03/16 09:431,1-Dichloroethane [75-34-3] ^0.13 MSZ1.00.13 U 51
ug/L EPA 8260B 05/03/16 09:431,1-Dichloroethene [75-35-4] ^0.21 MSZ1.00.21 U 51
ug/L EPA 8260B 05/03/16 09:431,2,3-Trichloropropane [96-18-4] ^0.23 MSZ1.00.23 U 11
ug/L EPA 8260B 05/03/16 09:431,2-Dibromo-3-chloropropane [96-12-8] ^0.48 MSZ1.00.48 U 131
ug/L EPA 8260B 05/03/16 09:431,2-Dibromoethane [106-93-4] ^0.66 MSZ1.00.66 U 11
ug/L EPA 8260B 05/03/16 09:431,2-Dichlorobenzene [95-50-1] ^0.19 MSZ1.00.19 U 51
ug/L EPA 8260B 05/03/16 09:431,2-Dichloroethane [107-06-2] ^0.21 MSZ1.00.21 U 11
ug/L EPA 8260B 05/03/16 09:431,2-Dichloropropane [78-87-5] ^0.10 MSZ1.00.10 U 11
ug/L EPA 8260B 05/03/16 09:431,4-Dichlorobenzene [106-46-7] ^0.19 MSZ1.00.19 U 11
ug/L EPA 8260B 05/03/16 09:432-Butanone [78-93-3] ^1.3 MSZ5.01.3 U 1001
ug/L EPA 8260B 05/03/16 09:432-Hexanone [591-78-6] ^0.88 MSZ5.00.88 U 501
ug/L EPA 8260B 05/03/16 09:434-Methyl-2-pentanone [108-10-1] ^1.1 MSZ5.01.1 U 1001
ug/L EPA 8260B 05/03/16 09:43Acetone [67-64-1] ^1.2 MSZ5.01.2 U 1001
ug/L EPA 8260B 05/03/16 09:43Acrylonitrile [107-13-1] ^3.5 MSZ103.5 U 2001
ug/L EPA 8260B 05/03/16 09:43Benzene [71-43-2] ^0.15 MSZ1.00.15 U 11
ug/L EPA 8260B 05/03/16 09:43Bromochloromethane [74-97-5] ^0.48 MSZ1.00.48 U 31
ug/L EPA 8260B 05/03/16 09:43Bromodichloromethane [75-27-4] ^0.17 MSZ1.00.17 U 11
ug/L EPA 8260B 05/03/16 09:43Bromoform [75-25-2] ^0.22 MSZ1.00.22 U 31
ug/L EPA 8260B 05/03/16 09:43Bromomethane [74-83-9] ^0.14 MSZ1.00.14 U 101
ug/L EPA 8260B 05/03/16 09:43Carbon disulfide [75-15-0] ^1.5 MSZ5.01.5 U 1001
ug/L EPA 8260B 05/03/16 09:43Carbon tetrachloride [56-23-5] ^0.17 MSZ1.00.17 U 11
ug/L EPA 8260B 05/03/16 09:43Chlorobenzene [108-90-7] ^0.17 MSZ1.00.17 U 31
ug/L EPA 8260B 05/03/16 09:43Chloroethane [75-00-3] ^0.23 MSZ1.00.23 U 101
ug/L EPA 8260B 05/03/16 09:43Chloroform [67-66-3] ^0.18 MSZ1.00.18 U 51
ug/L EPA 8260B 05/03/16 09:43Chloromethane [74-87-3] ^0.13 MSZ1.00.13 U 11
ug/L EPA 8260B 05/03/16 09:43cis-1,2-Dichloroethene [156-59-2] ^0.15 MSZ1.00.15 U 51
ug/L EPA 8260B 05/03/16 09:43cis-1,3-Dichloropropene [10061-01-5] ^0.20 MSZ1.00.20 U 11
ug/L EPA 8260B 05/03/16 09:43Dibromochloromethane [124-48-1] ^0.17 MSZ1.00.17 U 31
ug/L EPA 8260B 05/03/16 09:43Dibromomethane [74-95-3] ^0.27 MSZ1.00.27 U 101
ug/L EPA 8260B 05/03/16 09:43Ethylbenzene [100-41-4] ^0.13 MSZ1.00.13 U 11
ug/L EPA 8260B 05/03/16 09:43Iodomethane [74-88-4] ^1.7 MSZ5.01.7 U 101
ug/L EPA 8260B 05/03/16 09:43m,p-Xylenes [108-38-3/106-42-3] ^0.17 MSZ2.00.17 U NE1
ug/L EPA 8260B 05/03/16 09:43Methylene chloride [75-09-2] ^0.23 MSZ1.00.23 U 11
ug/L EPA 8260B 05/03/16 09:43o-Xylene [95-47-6] ^0.065 MSZ1.00.065 U NE1
ug/L EPA 8260B 05/03/16 09:43Styrene [100-42-5] ^0.11 MSZ1.00.11 U 11
ug/L EPA 8260B 05/03/16 09:43Tetrachloroethene [127-18-4] ^0.17 MSZ1.00.17 U 11
ug/L EPA 8260B 05/03/16 09:43Tetrahydrofuran [109-99-9] ^0.80 MSZ1.00.80 U 1
ug/L EPA 8260B 05/03/16 09:43Toluene [108-88-3] ^0.14 MSZ1.00.14 U 11
ug/L EPA 8260B 05/03/16 09:43trans-1,2-Dichloroethene [156-60-5] ^0.21 MSZ1.00.21 U 51
ug/L EPA 8260B 05/03/16 09:43trans-1,3-Dichloropropene [10061-02-6] ^0.15 MSZ1.00.15 U 11
ug/L EPA 8260B 05/03/16 09:43trans-1,4-Dichloro-2-butene [110-57-6] ^0.70 MSZ1.00.70 U 1001
ug/L EPA 8260B 05/03/16 09:43Trichloroethene [79-01-6] ^0.15 MSZ1.00.15 U 11
ug/L EPA 8260B 05/03/16 09:43Trichlorofluoromethane [75-69-4] ^0.24 MSZ1.00.24 U 11
ug/L EPA 8260B 05/03/16 09:43Vinyl acetate [108-05-4] ^0.95 MSZ5.00.95 U 501
ug/L EPA 8260B 05/03/16 09:43Vinyl chloride [75-01-4] ^0.32 MSZ1.00.32 U 11
ug/L EPA 8260B 05/03/16 09:43Xylenes (Total) [1330-20-7] ^0.45 MSZ3.00.45 U 51
Page 13 of 22
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9809-GMW4Description:Lab Sample ID:CZ05054-04 04/21/16 10:30Received:
Matrix:Water Sampled:04/20/16 08:22 Work Order:CZ05054
Wilson C&D LandfillProject:Sampled By:ROBERT WELDY
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL
Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF
4-Bromofluorobenzene 53-13685 %MSZEPA 8260B 05/03/16 09:436E020284250.0 1
Dibromofluoromethane 67-12995 %MSZEPA 8260B 05/03/16 09:436E020284850.0 1
Toluene-d8 59-13494 %MSZEPA 8260B 05/03/16 09:436E020284750.0 1
Page 14 of 22
www.encolabs.com
9809-GMW4Description:Lab Sample ID:CZ05054-04 04/21/16 10:30Received:
Matrix:Water Sampled:04/20/16 08:22 Work Order:CZ05054
Wilson C&D LandfillProject:Sampled By:ROBERT WELDY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByMRLFlag NotesNC SWSL
ug/L EPA 6020B 04/28/16 12:59Antimony [7440-36-0] ^0.220 VLO2.000.220 U 61
ug/L EPA 6010D 04/27/16 12:53Arsenic [7440-38-2] ^6.80 JDH10.06.80 U 101
ug/L EPA 6010D 04/27/16 12:53Barium [7440-39-3] ^1.00 JDH10.072.7 J 1001
ug/L EPA 6010D 04/27/16 12:53Beryllium [7440-41-7] ^0.100 JDH1.000.100 U 11
ug/L EPA 6010D 04/27/16 12:53Cadmium [7440-43-9] ^0.360 JDH1.000.360 U 11
ug/L EPA 6010D 04/27/16 12:53Chromium [7440-47-3] ^1.40 JDH10.01.40 U 101
ug/L EPA 6010D 04/27/16 12:53Cobalt [7440-48-4] ^1.10 JDH10.01.10 U 101
ug/L EPA 6010D 04/27/16 12:53Copper [7440-50-8] ^1.60 JDH10.01.60 U 101
ug/L EPA 6010D 04/27/16 12:53Lead [7439-92-1] ^3.10 JDH10.03.10 U 101
ug/L EPA 6010D 04/27/16 12:53Nickel [7440-02-0] ^2.20 JDH10.02.49 J 501
ug/L EPA 6020B 04/28/16 12:59Selenium [7782-49-2] ^0.910 VLO3.000.910 U 101
ug/L EPA 6010D 04/27/16 12:53Silver [7440-22-4] ^1.90 JDH10.01.90 U 101
ug/L EPA 6020B 04/28/16 12:59Thallium [7440-28-0] ^0.110 VLO1.000.110 U 5.51
ug/L EPA 6010D 04/27/16 12:53Vanadium [7440-62-2] ^1.40 JDH10.01.56 J 251
ug/L EPA 6010D 04/27/16 12:53Zinc [7440-66-6] ^4.40 JDH10.07.73 J 101
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.
Page 15 of 22
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QUALITY CONTROL
Volatile Organic Compounds by GCMS - Quality Control
Batch 6E02028 - EPA 5030B_MS
Prepared: 05/02/2016 12:38 Analyzed: 05/03/2016 00:47Blank (6E02028-BLK1)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L1.00.17 U 1,1,1,2-Tetrachloroethane
ug/L1.00.12 U 1,1,1-Trichloroethane
ug/L1.00.28 U 1,1,2,2-Tetrachloroethane
ug/L1.00.14 U 1,1,2-Trichloroethane
ug/L1.00.13 U 1,1-Dichloroethane
ug/L1.00.21 U 1,1-Dichloroethene
ug/L1.00.23 U 1,2,3-Trichloropropane
ug/L1.00.48 U 1,2-Dibromo-3-chloropropane
ug/L1.00.66 U 1,2-Dibromoethane
ug/L1.00.19 U 1,2-Dichlorobenzene
ug/L1.00.21 U 1,2-Dichloroethane
ug/L1.00.10 U 1,2-Dichloropropane
ug/L1.00.19 U 1,4-Dichlorobenzene
ug/L5.01.3 U 2-Butanone
ug/L5.00.88 U 2-Hexanone
ug/L5.01.1 U 4-Methyl-2-pentanone
ug/L5.01.2 U Acetone
ug/L103.5 U Acrylonitrile
ug/L1.00.15 U Benzene
ug/L1.00.48 U Bromochloromethane
ug/L1.00.17 U Bromodichloromethane
ug/L1.00.22 U Bromoform
ug/L1.00.14 U Bromomethane
ug/L5.01.5 U Carbon disulfide
ug/L1.00.17 U Carbon tetrachloride
ug/L1.00.17 U Chlorobenzene
ug/L1.00.23 U Chloroethane
ug/L1.00.18 U Chloroform
ug/L1.00.13 U Chloromethane
ug/L1.00.15 U cis-1,2-Dichloroethene
ug/L1.00.20 U cis-1,3-Dichloropropene
ug/L1.00.17 U Dibromochloromethane
ug/L1.00.27 U Dibromomethane
ug/L1.00.13 U Ethylbenzene
ug/L5.01.7 U Iodomethane
ug/L2.00.17 U m,p-Xylenes
ug/L1.00.23 U Methylene chloride
ug/L1.00.065 U o-Xylene
ug/L1.00.11 U Styrene
ug/L1.00.17 U Tetrachloroethene
ug/L1.00.80 U Tetrahydrofuran
ug/L1.00.14 U Toluene
ug/L1.00.21 U trans-1,2-Dichloroethene
ug/L1.00.15 U trans-1,3-Dichloropropene
ug/L1.00.70 U trans-1,4-Dichloro-2-butene
ug/L1.00.15 U Trichloroethene
ug/L1.00.24 U Trichlorofluoromethane
ug/L5.00.95 U Vinyl acetate
ug/L1.00.32 U Vinyl chloride
Page 16 of 22
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QUALITY CONTROL
Volatile Organic Compounds by GCMS - Quality Control
Batch 6E02028 - EPA 5030B_MS
Prepared: 05/02/2016 12:38 Analyzed: 05/03/2016 00:47Blank (6E02028-BLK1) Continued
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L3.00.45 U Xylenes (Total)
ug/L 50.0 53-136Surrogate: 4-Bromofluorobenzene 8744
ug/L 50.0 67-129Surrogate: Dibromofluoromethane 9045
ug/L 50.0 59-134Surrogate: Toluene-d8 9849
Prepared: 05/02/2016 12:38 Analyzed: 05/03/2016 01:16LCS (6E02028-BS1)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L1.0 20.0 75-1337816 1,1-Dichloroethene
ug/L1.0 20.0 81-1349118 Benzene
ug/L1.0 20.0 83-11710120 Chlorobenzene
ug/L1.0 20.0 0-2007916 Tetrahydrofuran
ug/L1.0 20.0 71-1189118 Toluene
ug/L1.0 20.0 74-11910421 Trichloroethene
ug/L 50.0 53-136Surrogate: 4-Bromofluorobenzene 8944
ug/L 50.0 67-129Surrogate: Dibromofluoromethane 8743
ug/L 50.0 59-134Surrogate: Toluene-d8 9146
Prepared: 05/02/2016 12:38 Analyzed: 05/03/2016 01:45Matrix Spike (6E02028-MS1)
Source: CZ05877-05
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L1.0 20.0 75-133830.21 U17 1,1-Dichloroethene
ug/L1.0 20.0 81-134980.15 U20 Benzene
ug/L1.0 20.0 83-1171010.17 U20 Chlorobenzene
ug/L1.0 20.0 0-200830.80 U17 Tetrahydrofuran
ug/L1.0 20.0 71-118920.14 U18 Toluene
ug/L1.0 20.0 74-1191080.15 U22 Trichloroethene
ug/L 50.0 53-136Surrogate: 4-Bromofluorobenzene 8844
ug/L 50.0 67-129Surrogate: Dibromofluoromethane 9347
ug/L 50.0 59-134Surrogate: Toluene-d8 9950
Prepared: 05/02/2016 12:38 Analyzed: 05/03/2016 02:14Matrix Spike Dup (6E02028-MSD1)
Source: CZ05877-05
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L1.0 20.0 2075-13381 20.21 U16 1,1-Dichloroethene
ug/L1.0 20.0 1781-13494 50.15 U19 Benzene
ug/L1.0 20.0 1683-117100 0.40.17 U20 Chlorobenzene
ug/L1.0 20.0 500-20080 30.80 U16 Tetrahydrofuran
ug/L1.0 20.0 1771-11893 20.14 U19 Toluene
ug/L1.0 20.0 2274-119107 0.80.15 U21 Trichloroethene
ug/L 50.0 53-136Surrogate: 4-Bromofluorobenzene 9145
ug/L 50.0 67-129Surrogate: Dibromofluoromethane 9347
ug/L 50.0 59-134Surrogate: Toluene-d8 9950
Page 17 of 22
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QUALITY CONTROL
Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control
Batch 6D26020 - EPA 3005A
Prepared: 04/26/2016 10:39 Analyzed: 04/27/2016 12:18Blank (6D26020-BLK1)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L10.06.80 U Arsenic
ug/L10.01.00 U Barium
ug/L1.000.100 U Beryllium
ug/L1.000.360 U Cadmium
ug/L10.01.40 U Chromium
ug/L10.01.10 U Cobalt
ug/L10.01.60 U Copper
ug/L10.03.10 U Lead
ug/L10.02.20 U Nickel
ug/L10.01.90 U Silver
ug/L10.01.40 U Vanadium
ug/L10.04.40 U Zinc
Prepared: 04/26/2016 10:39 Analyzed: 04/27/2016 12:22LCS (6D26020-BS1)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L10.0 200 80-120107214 Arsenic
ug/L10.0 200 80-120104208 Barium
ug/L1.00 20.0 80-12010420.7 Beryllium
ug/L1.00 20.0 80-12010521.0 Cadmium
ug/L10.0 200 80-120104207 Chromium
ug/L10.0 200 80-120104208 Cobalt
ug/L10.0 200 80-120101203 Copper
ug/L10.0 200 80-120102205 Lead
ug/L10.0 200 80-120107214 Nickel
ug/L10.0 200 80-120107214 Silver
ug/L10.0 200 80-120105211 Vanadium
ug/L10.0 200 80-120105210 Zinc
Prepared: 04/26/2016 10:39 Analyzed: 04/27/2016 12:29Matrix Spike (6D26020-MS1)
Source: CZ05054-01
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L10.0 200 75-1251096.80 U217 Arsenic
ug/L10.0 200 75-125103104309 Barium
ug/L1.00 20.0 75-1251060.98622.2 Beryllium
ug/L1.00 20.0 75-1251080.360 U21.6 Cadmium
ug/L10.0 200 75-1251061.40 U212 Chromium
ug/L10.0 200 75-1251078.31222 Cobalt
ug/L10.0 200 75-1251031.96207 Copper
ug/L10.0 200 75-1251053.10 U210 Lead
ug/L10.0 200 75-12510610.8223 Nickel
ug/L10.0 200 75-1251081.90 U216 Silver
ug/L10.0 200 75-1251081.40 U216 Vanadium
ug/L10.0 200 75-12510618.6231 Zinc
Prepared: 04/26/2016 10:39 Analyzed: 04/27/2016 12:39Matrix Spike Dup (6D26020-MSD1)
Source: CZ05054-01
Page 18 of 22
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QUALITY CONTROL
Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control
Batch 6D26020 - EPA 3005A
Prepared: 04/26/2016 10:39 Analyzed: 04/27/2016 12:39Matrix Spike Dup (6D26020-MSD1) Continued
Source: CZ05054-01
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L10.0 200 2075-125108 0.86.80 U215 Arsenic
ug/L10.0 200 2075-125103 0.006104309 Barium
ug/L1.00 20.0 2075-125107 0.40.98622.3 Beryllium
ug/L1.00 20.0 2075-125107 0.80.360 U21.4 Cadmium
ug/L10.0 200 2075-125106 0.51.40 U213 Chromium
ug/L10.0 200 2075-125107 0.098.31221 Cobalt
ug/L10.0 200 2075-125102 0.11.96207 Copper
ug/L10.0 200 2075-125102 23.10 U205 Lead
ug/L10.0 200 2075-125106 0.0510.8223 Nickel
ug/L10.0 200 2075-125108 0.31.90 U217 Silver
ug/L10.0 200 2075-125108 0.31.40 U217 Vanadium
ug/L10.0 200 2075-125106 0.218.6231 Zinc
Prepared: 04/26/2016 10:39 Analyzed: 04/27/2016 12:42Post Spike (6D26020-PS1)
Source: CZ05054-01
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
mg/L0.0100 0.200 80-1201030.00680 U0.207 Arsenic
mg/L0.0100 0.200 80-120970.00100 U0.297 Barium
mg/L0.00100 0.0200 80-1201010.000100 U0.0212 Beryllium
mg/L0.00100 0.0200 80-1201010.000360 U0.0203 Cadmium
mg/L0.0100 0.200 80-1201000.00140 U0.201 Chromium
mg/L0.0100 0.200 80-1201000.00110 U0.209 Cobalt
mg/L0.0100 0.200 80-120970.00160 U0.196 Copper
mg/L0.0100 0.200 80-120980.00310 U0.196 Lead
mg/L0.0100 0.200 80-1201010.00220 U0.212 Nickel
mg/L0.0100 0.200 80-1201020.00190 U0.204 Silver
mg/L0.0100 0.200 80-1201020.00140 U0.205 Vanadium
mg/L0.0100 0.200 80-1201030.00440 U0.224 Zinc
Batch 6D26022 - EPA 3005A
Prepared: 04/26/2016 10:50 Analyzed: 04/28/2016 10:50Blank (6D26022-BLK1)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L2.000.220 U Antimony
ug/L3.000.910 U Selenium
ug/L1.000.110 U Thallium
Prepared: 04/26/2016 10:50 Analyzed: 04/28/2016 10:57LCS (6D26022-BS1)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L2.00 200 80-120104208 Antimony
ug/L3.00 200 80-120110221 Selenium
ug/L1.00 200 80-120106212 Thallium
Page 19 of 22
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QUALITY CONTROL
Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control
Batch 6D26022 - EPA 3005A
Prepared: 04/26/2016 10:50 Analyzed: 04/28/2016 11:01Matrix Spike (6D26022-MS1)
Source: CZ04340-01
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L2.00 200 75-1251120.220 U224 Antimony
ug/L3.00 200 75-1251130.910 U226 Selenium
ug/L1.00 200 75-1251030.110 U207 Thallium
Prepared: 04/26/2016 10:50 Analyzed: 04/28/2016 11:05Matrix Spike Dup (6D26022-MSD1)
Source: CZ04340-01
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L2.00 200 2075-125109 30.220 U218 Antimony
ug/L3.00 200 2075-125112 10.910 U223 Selenium
ug/L1.00 200 2075-125102 10.110 U204 Thallium
Prepared: 04/26/2016 10:50 Analyzed: 04/28/2016 11:08Post Spike (6D26022-PS1)
Source: CZ04340-01
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
ug/L2.00 200 80-1201090.220 U218 Antimony
ug/L3.00 200 80-1201130.910 U226 Selenium
ug/L1.00 200 80-1201050.110 U209 Thallium
Page 20 of 22
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FLAGS/NOTES AND DEFINITIONS
B The analyte was detected in the associated method blank.
D The sample was analyzed at dilution.
J The reported value is between the laboratory method detection limit (MDL) and the laboratory method
reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable.
U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation
data and moisture content, where applicable.
E
MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is
based on the low point of the calibration curve, when applicable, sample preparation factor, dilution
factor, and, in the case of soil samples, moisture content.
The concentration indicated for this analyte is an estimated value above the calibration range of the
instrument. This value is considered an estimate.
Page 21 of 22