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HomeMy WebLinkAbout2601_AnnStPhaseIV_WQMP_25252_20160328 Appendix H Water Quality Monitoring Plan i Table of Contents Section 1 Purpose and Scope ................................................................................................ 1 Section 2 Geology and Hydrogeology ................................................................................... 1 Section 3 Proposed Groundwater Monitoring Network ........................................................ 2 3.1 Monitoring Well Locations .................................................................................................................. 2 3.2 Monitoring Well Installation and Construction................................................................................... 3 3.3 Hydraulic Conductivity Testing ............................................................................................................ 6 3.4 Surface Water Quality Monitoring ...................................................................................................... 6 Section 4 Sampling and Analysis Plan ................................................................................... 6 4.1 Groundwater Sample Collection ......................................................................................................... 6 4.1.1 Static Water Level Measurements .......................................................................................... 6 4.1.2 Detection of Immiscible Layers ............................................................................................... 7 4.1.3 Monitoring Well Evacuation .................................................................................................... 7 4.1.4 Sample Collection .................................................................................................................... 8 4.1.5 Decontamination Procedures ................................................................................................. 9 4.2 Sample Preservation and Shipment .................................................................................................... 9 4.3 Analytical Procedures .......................................................................................................................... 9 4.4 Chain-of-Custody ............................................................................................................................... 10 4.5 Quality Assurance/Quality Control ................................................................................................... 11 4.5.1 Field Duplicates ..................................................................................................................... 11 4.5.2 Equipment Rinsate Blanks ..................................................................................................... 11 4.5.3 Trip Blanks ............................................................................................................................. 11 4.6 Results/Reporting Requirements ...................................................................................................... 11 4.7 Detection of Elevated Constituent Levels ......................................................................................... 12 Section 5 References .......................................................................................................... 12 Figures Figure 1 Typical Monitoring Well .............................................................................................................. 5 Tables Table 1 Monitoring Well Construction Summary ..................................................................................... 4 Sheets Sheet 1 Map Pocket 1 Revised February 2016 Cumberland County Subtitle D Landfill Water Quality Monitoring Plan 1 Purpose and Scope The purpose of this Water Quality Monitoring Plan is to address the requirements in Rule .1623(b)(3)(B), and to present a plan for groundwater and surface water monitoring for the proposed Cumberland County Subtitle D Landfill Cells 9 and 10 Expansion. The Water Quality Monitoring Plan includes information on the expansion of the existing groundwater monitoring network, sampling and analysis requirements, and detection monitoring requirements. The groundwater monitoring network was designed based on information obtained from recent and previous subsurface investigations and a review of literature pertaining to regional geology and groundwater resources. A detailed discussion of the geological and hydrogeological conditions at the Cells 9 and 10 Expansion is presented in both the initial Site Plan Application and the Design Hydrogeologic Report for the Cells 9 and 10 area. The Water Quality Monitoring Plan includes the following elements, in accordance with Rules .1630 through .1637 of the North Carolina Administrative Code: Design and installation of a groundwater monitoring system, based on site-specific information, to yield groundwater samples from the uppermost aquifer that represents the quality of the background groundwater that has not been affected by landfill activities or other man-made activities. Design and installation of groundwater monitoring system, based on site-specific information, to yield groundwater samples from the uppermost aquifer that represent the quality of groundwater passing the relevant point of compliance. Monitor wells designed and constructed in accordance with the applicable North Carolina Well Construction Standards as found in 15A NCAC 2C. A Sampling and Analysis Plan that includes procedures and techniques for sample collection, sample preservation and shipment, analytical procedures, chain-of-custody procedures, and quality assurance/quality control. A certification of effectiveness of the water quality monitoring plan is provided. 2 Geology and Hydrogeology The Cumberland County Subtitle D Landfill site is located in the western flank of the North Carolina Coastal Plain Physiographic Province. Observation of the site conditions and subsurface logs indicate that approximately 8 to 39 feet of shallow surficial soils overly the Cape Fear confining unit. The alluvial or surficial soils consist of fine to coarse grained silty sands with occasional gravel and some interbedded clayey silts and silty clays. The Cape Fear confining unit consists of silts interbedded with major concentrations of impermeable sandy clay. Cumberland County Subtitle D Landfill • Water Quality Monitoring Plan 2 Revised February 2016 At the landfill site, groundwater resides in the shallow, more porous and permeable soils lying above the Cape Fear confining unit. The depth to groundwater generally ranges from about 7 to 17 feet below ground surface with groundwater typically shallower in the northwest and southeast portions of the site. Groundwater flow in the Cells 9 and 10 expansion area is generally convergent from the northwest toward the northeast trending paleo-channel located in the central portion of the site. This paleo-channel is the major control for groundwater flow. Additional information on the geologic and hydrogeologic conditions at the site is provided in the Design Hydrogeologic Report. 3 Proposed Groundwater Monitoring Network This section presents the proposed groundwater monitoring network for the Cells 9 and 10 expansion area. Section 3.1 presents proposed monitoring well locations, Section 3.2 discusses monitoring well installation and construction specifications, Section 3.3 discusses hydraulic conductivity testing of the monitoring wells. No additional surface water sampling locations are proposed for this expansion. 3.1 Monitoring Well Locations The SWS regulations require that upgradient monitoring well(s) be located so that groundwater samples collected from the uppermost aquifer provide an indication of background groundwater quality. Upgradient well MW-E was originally installed to monitor background water quality; however, due to continued detections of offsite contaminants, MW-E was replaced. Monitoring well MW-E rep now serves as the background well for the Subtitle D landfill. No additional background wells are proposed. The downgradient monitoring wells must represent groundwater quality at the relevant point of compliance. The wells must be located in similar geologic units so that upgradient and downgradient groundwater quality data can be compared. The proposed expanded groundwater monitoring system is shown on Sheet 1. This sheet shows the existing Cells 1-8 and proposed Cells 9 and 10 of the Subtitle D landfill and the relationship of the monitoring wells to each of these cells. Because site hydrogeologic conditions are generally very predictable and quite typical of coastal plain conditions throughout North Carolina, no nested monitoring wells are proposed in this plan. Specifically, the surficial, silty-sands which overlie the top of the low permeability clays of the Cape Fear confining unit provide the only available aquifer at this site (excluding any regional aquifers which may be present several hundreds of feet below ground surface beneath the bottom of the Cape Fear Formation). Currently, there are four monitoring wells (MW-E rep, MW-F, MW-I, MW-J) in use at the existing facility. These wells have been sampled on a semi-annual basis since installation. MW-E rep serves as the background well for the facility, and will continue to do so. MW-F is located downgradient of the leachate pond between the pond and the landfill. MW-l and MW-J are located east of Cell 8 and proposed Cell 9 in the northeast trending paleo-channel. Former background well MW-E is used to monitoring water elevations only. The potentiometric contours provided on Sheet 1, show that all groundwater flow within the landfill boundaries is controlled by this feature. In addition to the existing wells, CDM Smith is proposing to install one additional well to the Groundwater Monitoring Network for the Cumberland County Subtitle D Landfill. The current monitoring well network serves to accurately monitor the existing landfill. The groundwater flow pattern indicates that the eastern portion of groundwater flow is toward existing wells MW-I and Cumberland County Subtitle D Landfill • Water Quality Monitoring Plan 3 Revised February 2016 MW-J. Because the surficial aquifer thickness is less than 15 feet in most areas, the aquifer can be monitored with a single well. The paleo-channel acts as a preferential pathway for groundwater flow. Based on the results of the design hydrogeologic investigation, only 1 additional well is recommended for the site. Piezometer P-205 will be abandoned and a new monitoring well with 15 feet of screen will be installed in its place. The following is a brief discussion on the placement, rationale and location for the new monitoring well location: MW-K - This well will be situated downgradient of Cell 10, within the northern portion of the northeast-southwest trending linear feature. Like MW-I and MW-J, this well will be permanent and monitored for the life of the facility. Table 1 provides the screen interval depths for the groundwater monitoring wells currently installed at the proposed site, and estimated screen depths for the new well. Sheet 1 shows the existing wells, proposed well and existing surface water sampling locations for the existing and expanded Subtitle D landfill site. 3.2 Monitor Well Installation and Construction Prior to installation, existing piezometer will be properly abandoned. Monitoring well MW-K will be constructed in accordance with standard industry procedures and will meet the requirements of 15A NCAC 2C. The well design for monitoring well MW-K is shown on Figure 1. The monitoring well will be installed by advancing the borehole through the water table using hollow-stem auger techniques. If running sands present a problem during drilling, mud rotary techniques will be used. Soil lithology will be described in the field by an onsite geologist to develop a borehole log. The monitoring well will be constructed using 2-inch ID PVC well casing with threaded flush joints. The well will be constructed with 15 feet of 0.010-inch slot screen at the end of the casing string placed so that it brackets the water table. The PVC casing string will extend approximately three feet above ground surface. A sand pack will be placed around the screen interval to a maximum of two feet above the top of the screen. A two foot thick bentonite seal consisting of hydrated bentonite pellets will be placed on top of the sand to hydraulically seal the completion interval. The remainder of the annulus will be sealed with a bentonite-Portland cement grout to ground surface. A protective outer casing with a lockable cap will be placed over the PVC casing and into the grout, extending 2.5 to 3 feet below ground surface. Following completion, the monitor well will be developed to remove the residual effects of drilling. The well will be developed using a combination of surging and over-pumping. All drilling and downhole equipment will be decontaminated by steam cleaning prior to use. Well development equipment will be decontaminated by washing in a non-phosphate detergent solution followed by a potable water rinse, then a distilled water rinse, and allowed to air dry. The horizontal location of the new monitor well will be surveyed in State Plane Coordinates by a Registered Land Surveyor to the nearest 0.1 foot. The vertical control or elevation of the top of PVC casing (the well measuring point) will be surveyed to the nearest 0.01 foot accuracy to mean sea level (msl). The height of the well measuring point above ground surface will be measured. Ta b l e  1 Mo n i t o r i n g  We l l  Co n s t r u c t i o n  Su m m a r y Cu m b e r l a n d  Co u n t y  Su b t i t l e  D  La n d f i l l  Ex p a n s i o n  ‐   Ce l l  9  an d  10 Wa t e r  Qu a l i t y  Mo n i t o r i n g  Pl a n Bo r e h o l e   De p t h Sc r e e n   In t e r v a l Sa n d   In t e r v a l Bentonite  Seal MW ‐K TB D T B D T B D T B D T B D 3 9 . 0 2 4 . 0 ‐39 . 0 2 2 . 0 ‐39 . 0 2 0 . 0 ‐22.0 8 2 MW ‐E* 1 1 / 1 7 / 1 9 9 7 8 6 . 5 9 8 3 . 5 0 7 6 . 5 0 6 1 . 5 0 2 2 . 0 7 . 0 ‐22 . 0 5 . 5 ‐22 . 0 3 . 5 ‐5.5 8 2 MW ‐E  (r e p ) 6 / 8 / 2 0 1 0 9 2 . 0 1 8 9 . 1 7 9 . 1 6 9 . 1 2 0 . 0 1 0 . 0 ‐20 . 0 8 . 0 ‐20 . 0 6 . 0 ‐8.0 8 2 MW ‐F 1 1 / 1 7 / 1 9 9 7 9 3 . 4 5 9 3 . 7 0 7 8 . 4 5 6 3 . 4 5 3 0 . 0 1 5 . 0 ‐30 . 0 1 3 . 5 ‐30 . 0 1 1 . 0 ‐13.5 8 2 MW ‐I 1 2 / 1 9 / 2 0 0 0 9 0 . 1 2 8 6 . 9 0 7 2 . 9 0 5 7 . 9 0 2 9 . 0 1 4 . 0 ‐29 . 0 1 2 . 0 ‐29 . 0 1 0 . 0 ‐12.0 6 2 MW ‐J 1 2 / 1 5 / 2 0 0 0 9 0 . 4 8 8 7 . 5 1 7 2 . 5 1 5 7 . 5 1 3 0 . 0 1 5 . 0 ‐30 . 0 1 3 . 0 ‐30 . 0 1 1 . 0 ‐13.0 6 2 TM W ‐1 11 / 1 8 / 1 9 9 7 8 9 . 6 1 8 6 . 6 0 7 5 . 1 0 6 0 . 1 0 2 6 . 5 1 1 . 5 ‐26 . 5 9 . 5 ‐26 . 5 7 . 0 ‐9.5 8 2 No t e s : 1.  AM S L  ‐   Ab o v e  Me a n  Se a  Le v e l 2.  It a l i c s  in d i c a t e s  ab a n d o n e d  mo n i t o r i n g  we l l . 3.  Ve r t i c a l  Co n t r o l  ‐   Na t i o n a l  Ge o d e t i c  Ve r t i c a l  Da t u m  of  19 2 9 4.  Ho r i z o n t a l  Co n t r o l  ‐   No r t h  Am e r i c a n  Da t u m  of  19 8 3 Ce l l  9  an d  10  Ex p a n s i o n  Pr o p o s e d  Mo n i t o r i n g  We l l Ex i s t i n g  Mo n i t o r i n g  We l l  Ne t w o r k Pi e z o m e t e r / M o n i t o r i n g   We l l  I. D . To p  of   Ca s i n g   El e v a t i o n   (a m s l ) Gr o u n d   El e v a t i o n   (a m s l ) Borehole  Diameter  (inches)Casing  Diameter  (inches) In s t a l l a t i o n  Da t e To p  of   Sc r e e n   (f e e t  am s l ) Bo t t o m  of   Sc r e e n   (f e e t  am s l ) De p t h s  (f e e t  be l o w  gr o u n d  su r f a c e ) Table  1 Locking Steel Protective Cover Well Expansion Plug Finished Grade 2'x2'x6" Concrete Pad 8" +/‐ Borehole Diameter 2" Schedule 40 PVC Blank Casing Portland Type I Cement Grout 2' Bentonite Seal #2 Silica Sand Filter Pack 2" Schedule 40 PVC 0.010 inch Slotted Well Screen Notes: Stick‐up will extend between 2.5 and 3 feet above finished grade. Silica sand filter pack will extend at least 2 feet above top of screen elevation. Well depth will vary depending on Cape Fear confining unit elevation. Anticipated construction depth to 39‐feet below land surface with 15 feet of screen. Figure 1 Cumberland County Subtitle D Landfill Typical Monitoring Well Detail Cumberland County Subtitle D Landfill • Water Quality Monitoring Plan 6 Revised February 2016 3.3 Hydraulic Conductivity Testing Following installation and development of the new monitor well, the hydraulic conductivity of the aquifer material surrounding each well will be determined by conducting slug falling head and/or recovery tests on the well. Effective porosity values of the subsurface materials will be estimated based on data collected during the design hydrogeologic investigation. 3.4 Surface Water Quality Monitoring No additional surface water sampling locations are proposed for the site. Existing locations SW-4, SW- 5, and SW-6 are shown on Sheet 1. 4 Sampling and Analysis Plan Rule .1632 (a) specifies that the owner/operator must provide, as part of the groundwater monitoring program, a groundwater and surface water sampling and analysis (S&A) plan. The S&A plan should be designed to provide accurate results of groundwater quality at the upgradient and downgradient sampling locations. The S&A plan will address the following subjects: Groundwater sample collection Sample preservation and shipment Analytical procedures Chain-of-custody Quality assurance/quality control (QA/QC) 4.1 Groundwater Sample Collection Upon completion of well construction, development, and a well stabilization period, the sampling plan will be instituted. The proposed frequency of sampling will include one sample to be collected from the monitoring well prior to the Cell 9 and 10 expansion receiving waste and three additional samples within six months of issuance of the Permit To Operate as required by Rule .1633(b). These samples will comprise the baseline sampling for the well. Groundwater samples from the monitoring well will be sampled on a semi-annual basis, along with the existing wells. 4.1.1 Static Water Level Measurements Static water level elevations will be measured prior to any purging or sampling activities. Static water level data will be used to monitor changes in site hydrogeologic conditions. The following measurements will be recorded in a dedicated field book prior to sample collection: Depth of water in the well from the TOC measuring point (to the nearest 0.01 foot) Total depth of the well Height of the water column in the well casing. An electronic water level indicator will be used to accurately measure water elevations to within 0.01 foot. The well will have a permanent, easily identified reference point from which all water level Cumberland County Subtitle D Landfill • Water Quality Monitoring Plan 7 Revised February 2016 measurements will be taken. The reference point will be marked and the elevation surveyed by a North Carolina Registered Land Surveyor. 4.1.2 Detection of Immiscible Layers USEPA's Technical Manual for Solid Waste Disposal Facility Criteria outlines specifications for groundwater sampling and analysis. One of these specifications outlines the establishment of provisions for detecting immiscible fluids, if applicable. Typically, immiscible fluids are categorized as either, (1) light, non-aqueous phase liquids (L-NAPLs), or (2) dense, non-aqueous phase liquids (D- NAPLs). L-NAPLs are more commonly referred to as "floaters" due to their relatively lighter specific gravity, while D-NAPLs are typically referred to as "sinkers" due to their relatively denser specific gravity. In most instances, the probability of immiscible fluids being present and subsequently detected in groundwater monitoring wells surrounding MSW landfills is somewhat remote because chemical products (such as industrial solvents) are not accepted for storage or disposal at Subtitle D solid waste management facilities. However, for those rare instances where a separate immiscible phase is believed to be present, EPA suggests that provisions for detecting these types of fluids should be developed. The following procedure is proposed to address these concerns in the event that the SWS ever require this test to be performed. In those instances where the monitoring well's screened interval encompasses the water table surface, the ability to detect and sample light non-aqueous phase liquids (LNAPLs) prior to implementation of routine groundwater sampling activities may exist. To accomplish this objective, a transparent teflon bailer will be lowered into the well to just below the water table surface. The bailer will then be removed from the well and the contents examined to identify if any immiscible fluids are present. If any immiscible fluids are determined to be potentially present, an interface probe is proposed to be used. The depth of the light phase immiscible layer, as determined by the interface probe, will then be recorded in a field logbook. The interface probe will continue to be lowered until it intersects the groundwater table surface. The depth of the organic/water interface zone also will be recorded. From these two measurements, the thickness of the light phase immiscible layer can be readily determined. The potential presence of dense phase immiscible layer will be determined by the examination of laboratory analytical results. Analytical results above a percentage of a given chemicals solubility limit can indicate the potential presence of DNAPLs. As mentioned above, monitoring for immsicible phase fluids is not envisioned to be performed during typical sampling events, but is provided here to document how the test will be performed if the SWS require it at a future date. 4.1.3 Monitoring Well Evacuation Following measurement of the static water level in the well, the well will be purged of all stagnant water. The stagnant water, which is not representative of true aquifer conditions, will be removed to ensure that fresh formation water can be sampled. A minimum of three well casing volumes will be removed prior to sampling the well. The well volume for 2-inch diameter wells will be calculated using the following equation: one well volume in gallons equals the height of the water column (in feet) Cumberland County Subtitle D Landfill • Water Quality Monitoring Plan 8 Revised February 2016 times 0.1632 (slightly less than 0.5 gallons per foot water for 3 casing volumes). During the well purging process, field measurements (pH, temperature, dissolved oxygen, oxidation/reduction potential, turbidity and specific conductance) will be collected at regular intervals, and reported in a tabular format. The well will be purged until field measurements stabilize within approximately 10 percent between subsequent readings or until the well is dry. Stabilization of these measurements will indicate that fresh formation water is present in the well. Field measurements will be obtained by using a YSI 600-series Multiparameter Water Quality Meter or equivalent. If the well is purged to dryness, the samples will be collected after a sufficient volume of water has entered the well to allow collection of the sample. Wells will be purged and sampled using a dedicated sampling system (Well Wizard®) which will be installed in the new well. Dedicated pumps are currently used in the existing wells at the facility. Field measurements collected during purging activities will be recorded in the field logbook. 4.1.4 Sample Collection After purging activities are complete, groundwater samples will be collected for laboratory analysis. The well will be sampled using the dedicated bladder pumps installed within each well, following low- flow techniques. All sample contact parts of the dedicated bladder pumps are constructed of either stainless steel or Teflon. Wells will be purged at a rate of less than 1 liter per minute. Actual purging and sampling flow rates will be adjusted to maintain the water level in the well at less than 0.3 ft below the initial static water level. Once water quality parameters have stabilized, groundwater samples will be collected directly from the pump discharge. Sample water will be placed directly into sample bottles provided by the analytical laboratory, using the following methods: 1. Adjust pump rate to 100 ml/minute and slowly transfer sample water to the appropriate sample container. The pump equipment (discharge tubing) should not be allowed to touch the sample container. 2. The sample container for the volatile organic compounds should be filled first, leaving no headspace or air bubbles. The container should then be tightly sealed. The sample container will come with preservative already added by the laboratory. 3. The sample container for the metals should then be filled. This container will also come with preservative added by the laboratory. This container should be filled to the bottle shoulder. Surface water samples will be obtained from areas of minimal turbulence and aeration. The following procedure will be implemented regarding sample of surface waters: 1. Hold the bottle near the bottom with one hand and remove the cap with the other. 2. Push the sample contained slowly into the water and tilt up towards the current to fill. A depth of six inches is satisfactory. Avoid breaching the surface while filling the container. 3. The container should be moved slowly, in a lateral direction, if there is little current movement. Cumberland County Subtitle D Landfill • Water Quality Monitoring Plan 9 Revised February 2016 4. If the stream depths are too shallow to allow submersion of the sample container, a pool may be scooped out of the channel bottom and allowed to clear prior to sampling. 5. Lift the container from the water and place the uncontaminated cap on the container. The individual water samples will be collected and bottled in the order of parameter volatility. The collection order for the samples will be as follows: Volatile organic compounds (VOCs) Total metals. The samples will be transferred from the sampling equipment directly into a prepared sample container provided by the laboratory. Field filtering of samples is not permitted. There will be a specific size and type of container provided for each constituent to be analyzed. For VOC analysis, the containers provided will be 40-ml glass vials. For metals analysis, the samples will be collected in 0.5- liter HDPE bottles. Extra containers will be provided in case of accidental breakage. All field personnel will wear protective latex or nitrile disposable gloves in order to prevent extrinsic contamination from clothing, body oils, dirt, and other various contaminants. Sample documentation requirements to ensure sample integrity, will included sample locations, date and time of sample collection, proper analysis, and preservative (if applicable). 4.1.5 Decontamination Procedures All sampling and purging equipment that will come in contact with the well casing and water will be decontaminated per specifications in the North Carolina Water Quality Guidance Document for Solid Waste Facilities. All sampling equipment will be laboratory cleaned. 4.2 Sample Preservation and Shipment In order to ensure sample integrity, preservation and shipment procedures will be carefully monitored. Generally, ice and chemical additives will be used as sample preservatives, as recommended by the commercial laboratory. For VOC analysis, hydrochloric acid will be used as the preservation method as well as maintaining the samples at a temperature of 4°C. Nitric acid will be used as the preservative for samples needing metals analysis. Samples shall be shipped via a 24-hour delivery service to ensure holding times are not exceeded. Shipment of samples will be coordinated with the laboratory. Proper storage and transport conditions must be maintained in order to preserve the integrity of the sample. Once taken, samples will be placed on ice and cooled to a temperature of 4°C. Samples are to be packed in iced coolers so as to inhibit breakage or accidental spills. Custody seals will be placed on the outside of the cooler, in a manner to detect tampering of the samples. The laboratory shall immediately notify the owner/operator of any samples that arrive with custody seals broken. 4.3 Analytical Procedures The samples taken from the new well and the existing well locations will be analyzed for the constituents listed in 40 CFR Part 258, Appendix 1. The analytical procedures for the indicated parameters will be conducted using the following methods: Cumberland County Subtitle D Landfill • Water Quality Monitoring Plan 10 Revised February 2016 Analysis EPA Method Number Volatile organic compounds 8260 Total metals In accordance with SWS policy at the time of sampling. 4.4 Chain-of-Custody It is imperative that an accurate record of sample collection, transport, analysis, and disposal be maintained and documented. Therefore, chain-of-custody procedures will be instituted and followed throughout the sampling program. It is necessary to establish documentation to trace sample possession from the time of collection until disposal. The chain-of-custody program shall include the following requirements: Samples shall be accompanied by a chain-of-custody record that notes the date and time of collection as well as sampling personnel. All samples shall be properly labeled to prevent misidentification of samples. Field notes shall be included to provide pertinent information about each sample. A sample analysis sheet shall accompany all samples to the laboratory. Sample custody seals shall be used to indicate any tampering of samples. All records pertaining to the shipment of a sample shall be retained (freight bills, post office receipts, and bills of lading). The laboratory shall not accept samples for analysis without a correctly prepared chain-of-custody form. The laboratory shall be responsible for maintaining chain-of-custody of the sample(s) from time of receipt to disposal. The chain-of-custody form shall be signed by each individual who possesses the samples. To prevent sample misidentification, a label will be affixed to each sample container in a manner as to prevent the label from becoming dislodged during transport which will contain the following information: Sample identification number. Name and signature of sample collector. Date and time of collection. Place of collection. Parameters requested. Type of preservative. Cumberland County Subtitle D Landfill • Water Quality Monitoring Plan 11 Revised February 2016 4.5 Quality Assurance/Quality Control The reliability and validity of the field and analytical laboratory data will be monitored as part of the QA/QC program used in the laboratory. Field duplicates and sample blanks will be collected to check sampling protocol and to account for any changes that occur after sampling. The QA/QC program will stipulate the use of standards, laboratory blanks, and duplicates for identification of matrix interferences. The QA/QC program will be used for baseline sampling at the new well and for all semi- annual events. 4.5.1 Field Duplicates Field duplicates provide a measure of field and laboratory precision. Field duplicates will be collected from identical locations using proper sampling procedures. The duplicate samples will be collected at a frequency of one per day per sampling event. 4.5.2 Equipment Rinsate Blanks To evaluate the effectiveness of the product decontamination, equipment rinsate blanks will be collected. The sample will be collected by passing distilled water through the sampling equipment after decontamination has been completed. Equipment blanks will be collected at a minimum of one per day of groundwater sampling activities. 4.5.3 Trip Blanks A trip blank shall be prepared to account for any sample contamination that may occur during transport to and from the site. The sample will be prepared in the laboratory with deionized or distilled water and shall accompany the sample shipping container to the field. The trip blank shall remain unopened until receipt by the lab for analysis. One trip blank per sampling event will be collected. 4.6 Results/Reporting Requirements Following analysis for the analytical data from groundwater and surface water samples, a report shall be submitted to the SWS which includes the following information: Field observations related to the condition of the monitoring wells, Field data, Laboratory data, Sampling methodologies, Quality assurance/quality control data, Information on groundwater flow, Wells with constituents exceeding groundwater standards, Other pertinent information, Solid Waste Section Reporting Form, and, Cumberland County Subtitle D Landfill • Water Quality Monitoring Plan 12 Revised February 2016 Electronic Data Deliverable in the approved SWS format. 4.7 Detection of Elevated Constituent Levels If upon completion of sampling and data analysis, Cumberland County determines that concentrations are elevated above the North Carolina 2L Standard (NC2L) or practical quantification limit (PQL) for any volatile organic compound (VOC) listed in Appendix 1 at any monitoring well or surface water sample at the site's boundary, then: 1. The county will notify the SWS within 14 days of this finding, 2. Place a notice in the operating record within 14 days of this finding indicating which constituent(s) have demonstrated exceeded the applicable limit, 3. Demonstrate successfully to the SWS (through certification by a qualified groundwater scientist) that a source other than the MSWLF unit caused the contamination, or that the exceedence resulted from error in sampling, analysis, statistical evaluation or natural variation in groundwater quality. The actions outlined above are proposed to be implemented if contaminants are detected. Final actions will be mandated by direction of the North Carolina SWS. 5 References Brown, Phillip M., Geologic Map of North Carolina. Department of Natural Resources and Community Development, 1985. Bouwer, Herman. The Bouwer and Rice Slug Test - An Update. Groundwater, May-June, 1989. Camp Dresser & McKee, Ann Street Landfill Subtitle D Expansion Permit to Construct Application (Cells 1-5), January 1995. Camp Dresser & McKee, Ann Street Landfill Subtitle D Expansion Permit to Construct Application (Cells 6-8), September 1999. Heath, Ralph. Basic Elements of Ground-Water Hydrology with References to Conditions in North Carolina. USGS Water Resources Investigation Open-File Report 80-44, 1980. North Carolina Department of Natural Resources and Community Development, Guide to the Location and Development of Groundwater-Lower Cape Fear River Basin. NRCD, Raleigh, North Carolina, 1984. Schipf, R.G. Geology and Groundwater Resources of the Fayetteville Area. Groundwater Bulletin No. 3, North Carolina Department of Water Resources, Raleigh, North Carolina, 1961. Winner, M.D. and R.W. Coble. Hydrogeologic Framework of the North Carolina Coastal Plain Aquifer System. U.S. Geological Survey Open-File Report 87-690, Raleigh, North Carolina, 1989.