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9230 Greenway Waste Solutions of Apex LF Jan 2025 Semi-Annual WQM Report
5940 Old Smithfield Rd CD Unit Permit 9230-CDLF-2014 Doc/Event #: Data - Email ' 'NC DENR ' ' Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: • Prepare one form for each individually monitored unit. • Please type or print legibly. • Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). • Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. • Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Greenway Waste Solutions of Apex, LLC Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Brandt Kayser, P.G. E-mail: brandt(aD_griffinbros.com Phone:914-844-7048 NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) reenway Waste Solutions of Apex 5940 Old Smithfield Rd, Apex, NC 27539 2-30 0500 October 21-22, December 4, S&D Landfill 2024 Environmental Status: (Check all that apply) Initial/Background Monitoring ® Detection Monitoring Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data El water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? ® No. No groundwater or surface water standards were exceeded. Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. EJ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Brandt Kayser, P.G. Environmental Compliance Officer 914-844-7048 Facility Representative Npme (PJij� _ Title (Area Code) Telephone Number 1 /10/2025 Signature % / Date 19505 Liverpool Pkwy, Huntersville, NC 28031 Facility Representative Address NA Affix NC Licensed/ Prroo(V&sional Geologist Seal y` 11141 i% v`I.,rp ei 4t NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 Fall 2024 Semi -Annual Water Quality Monitoring Report Greenway Waste Solutions of Apex, LLC 5940 Old Smithfield Road Apex, North Carolina Solid Waste Facility Permit Number 92-30 R Griffin Brothers Co. I I I � 4)01(I11011S Greenway Waste Solutions of Apex, LLC 19109 W. Catawba Avenue Cornelius, North Carolina 28031-5611 January 10, 2025 c /"(o/0tF Fall 2024 Semi -Annual Water Quality Monitoring Report Greenway Waste Solutions of Apex, LLC Apex, North Carolina January 10, 2025 Table of Contents Section Page No. 1.0 Introduction............................................................................................................................1 1.1 Site Description & Background............................................................................................1 2.0 Sampling & Analysis Conducted...........................................................................................2 2.1 Water Level Measurements...................................................................................................2 2.2 Groundwater Sampling Methods..........................................................................................2 2.3 Surface Water Sampling Methods........................................................................................3 2.4 Sample Handling and Analyses............................................................................................3 3.0 Findings...................................................................................................................................5 3.1 Groundwater Flow................................................................................................................ 5 3.2 Groundwater Analytical Results...........................................................................................7 3.3 Surface Water Results........................................................................................................... 9 4.0 Conclusions & Recommendations.......................................................................................10 4.1 Conclusions.........................................................................................................................10 4.2 Recommendations...............................................................................................................11 List of Figures Figure 1 Site Location Map Figure 2 Well Location Map Figure 3 Fall 2024 Potentiometric Contour Map List of Tables Table A Estimation of Groundwater Flow Velocity Table 1 Summary of Groundwater Elevation Data Table 2 Summary of Recent Groundwater Sample Analytical Detections 1 P &dAo HrNAvS Lr 6reenr�o [UustE Solutions Table 3 Summary of Recent Surface Water Analytical Data Table 4 Summary of Historical Groundwater Analytical Detections Table 5 Summary of Historical Surface Water Analytical Detections List of Appendices Appendix A Groundwater Sampling Forms Appendix B Laboratory Analytical Reports 11 a mnaamw: r. 6reenr�fl [Uns�E solurrons Fall 2024 Semi -Annual Water Quality Monitoring Report Greenway Waste Solutions of Apex, LLC Apex, North Carolina January 10, 2025 1.0 Introduction This Semi -Annual Water Quality Monitoring Report has been prepared to document the methods and results of the semi-annual groundwater monitoring event conducted in Fall 2024 at the Greenway Waste Solutions of Apex, LLC (GWSA) C&D Landfill (Site). This report details well gauging and field sampling activities, summarizes the site groundwater conditions and analytical data, and provides conclusions and recommendations for future monitoring events. 1.1 Site Description & Background The subject landfill facility is owned and operated by GWSA under Solid Waste Facility Permit Number 92-30. The Site, formerly known as the Highway 55 C&D Landfill, is located at 5940 Old Smithfield Road, Apex, North Carolina. A site location map is provided as Figure 1. The Site is bounded by the Triangle Expressway (Interstate 540) to the north, Highway 55 to the east, the South Wake Landfill to the south, and privately -owned property to the west. Tributary streams to Little Branch occupy the southern and western property boundaries. Site layout and monitoring well locations are depicted in Figure 2. The facility was originally permitted on August 20, 2002 under North Carolina Department of Environmental Quality Solid Waste Section (NCDEQ SWS) permit number 92-30. The Phase 1 and Phase 2 landfilling area footprints contain approximately 32.6 acres, and the currently active Phase 3 expansion contains approximately 11.2 acres. 1 P &dAo HrNAvS Lr 6reenr�o [UustE Solutions 2.0 Sampling & Analysis Conducted Groundwater monitoring activities for the Fall 2024 sampling event were conducted in accordance with the North Carolina Department of Environmental Quality Solid Waste Section (SWS)-approved Updated Water Quality Monitoring Plan prepared by Civil & Environmental Consultants, Inc. (CEC) dated February 13, 2020. Groundwater sampling activities were conducted on October 21 and 22, 2024 by GWSA personnel. GWSA returned to the site on December 4, 2024 to resample MW-9 to confirm a detection of benzene. Project oversight was provided by an NC -licensed geologist. Sampling activities included water level measurements, static water purging, and groundwater sample collection from fourteen monitoring wells: MW-1, MW-2 MW-3, MW-4, MW-5, MW-6, MW-7, MW-8, MW-9, MW-10, MW-11R, MW-12, MW- 13R and MW-14. Samples were also collected from four surface water locations: SW-1, SW-2, SW-3R, and SW-4, as well as the leachate storage tanks. The approximate locations of these monitoring wells and surface water sampling locations are depicted on Figure 2. 2.1 Water Level Measurements Prior to monitoring well purging, depth -to -water was measured in each of the site monitoring wells on October 21, 2024. Depth -to -water measurements were collected from the top of casing utilizing a decontaminated electronic water level indicator. Water level measurements and calculated groundwater elevations are summarized in Table 1. 2.2 Groundwater Sampling Methods The shallow wells were purged using low flow methods in general accordance with the Solid Waste Section Guidelines for Groundwater, Soil, and Surface Water Sampling Revision 4-08. A peristaltic pump with polyethylene tubing was used to purge and sample each shallow well using low flow purging and sampling techniques. The pump tubing was positioned in the approximate mid -portion of the screened interval of each well. Water levels were monitored during the purging process to ensure the purging rate did not cause significant drawdown of the water column. Samples were collected following stabilization of field parameters and when turbidity readings were below 10 nephelometric turbidity units (NTUs). Field measurements of pH, 2 a rn�werys 6reerrr�o [UustE Solutions temperature, specific conductivity, oxygen reduction potential (ORP), and dissolved oxygen (DO) were measured using a YSI Pro Plus water quality meter equipped with a flow -through cell. Turbidity was measured using an HF Scientific MicroTPW turbidity meter. Copies of the groundwater sampling field forms are provided in Appendix A. 2.3 Surface Water Sampling Methods Surface water samples were collected from two unnamed tributaries of Little Branch in general accordance with Solid Waste Section Guidelines for Groundwater, Soil, and Surface Water Sampling Revision 4-08. Surface water samples SW-1 and SW-2 were collected from the tributary along the southern property boundary, and SW-3R and SW-4 were collected from the tributary located west of the landfill (Figure 2). Surface water sampling was conducted starting downstream and working upstream. 2.4 Sample Handling and Analyses Following the well purging procedures described above, samples for laboratory analysis were placed directly into dedicated laboratory -supplied sample bottles, labeled, and placed on ice in an insulated cooler. A chain -of -custody record was completed and included sample identification, analyses required, matrix, and date and time of sample collection. The samples were transported on ice, under standard chain -of -custody protocol, to Eurofins TestAmerica's (ETA) Charlotte office for shipment to ETA's laboratory in Chicago, I1. The laboratory analytical reports and chain -of -custody records are provided in Appendix B. Groundwater samples collected from each sample location were analyzed by ETA for the constituents listed in 40 CRF 258 Appendix I, in accordance with 15A NCAC 13B 0544(b)(1)(D): Volatile Organic Compounds (VOCs) plus Tetrahydrofuran (THF) by EPA 8260D 1,4-dioxane by modified EPA 8260D Metals by EPA 6020B Mercury by EPA 7470A 3 P &dAo H NA v5 Lr 6reenr�o [UustE Solutions Samples were also collected from all facility monitoring wells for analysis for leachate indicator parameters including the following: Chloride and Sulfate by EPA 9056A Alkalinity by SM 2320B Total Dissolved Solids (TDS) by SM 2540C Four surface water samples and a quality control trip blank were analyzed for Appendix I VOCs plus THE and 1,4-dioxane via EPA Method 8260B. GWSA also submitted a blind duplicate sample, collected from MW-8, to TA for analysis of Appendix I VOCs plus THE and 1,4- dioxane for quality control purposes. Additionally, GWSA submitted one split sample, collected from MW-8, to Pace Analytical Services, LLC (Pace) for analysis of Appendix I VOCs plus THE and 1,4-dioxane only. 4 P &dAo H NA v5 Lr 6reenr�o [UustE Solutions 3.0 Findings 3.1 Groundwater Flow A summary of monitoring well gauging and water level elevation data is provided in Table 1. Utilizing water table elevation data derived from well gauging measurements, GWSA created a generalized potentiometric map depicting shallow groundwater flow beneath the active landfill area (Figure 3). Shallow groundwater in the northeastern portion of the Site generally flows southwest towards an unnamed tributary of Little Branch. Shallow groundwater movement beneath the eastern portion of the landfill is semi -radial, such that shallow groundwater in the northwestern portion of the Site generally flows to the northwest toward a tributary of Little Branch located to the northwest of the landfilling area, and shallow groundwater in the central portion of the Site generally flows west toward another tributary of Little Branch. Shallow groundwater in the southern portion of the site generally flows southwest toward the tributary of Little Branch which forms the southern property boundary. Horizontal Shallow Groundwater Gradient The horizontal hydraulic gradient (i) used in the flow velocity calculation below was estimated between the upgradient well MW-1 and downgradient well MW-5, which are separated by a horizontal distance of approximately 2,700 feet. Based on the calculated groundwater elevations for the October 2024 event, the hydraulic head difference between MW-1 (348.81 ft) and MW-5 (277. ft) is 71.32 feet. The horizontal hydraulic gradient, which is calculated by dividing the difference in hydraulic head (68.28 ft) by the horizontal well separation distance (2,700 ft), is 0.026 (unitless). Horizontal Shallow Groundwater Hydraulic Conductivity and Flow Velocity In order to estimate the horizontal hydraulic conductivity of the shallow water bearing zone, slug tests were conducted in MW-6 during August 2013 by Elite Techniques, Inc. The mean K calculated from the slug test data is 4.54 x 10-5 cm/sec (= 0.13 ft/day, or 47.45 ft/year). As described in the Well Installation Report — Phase III Expansion dated March 10, 2020, additional slug testing was performed in January 2020 by GWSA personnel in MW-12, MW-13R, and MW-14 following the installation of these wells in accordance with the facility Permit to Operate 6reenr�o [UustE Solutions (PTO). Determined K values for MW-12 (3.84 x 10-6 cm/sec), MW-13R (1.15 x 10-6 cm/sec), and MW-14 (1.05 x 10-5 cm/sec), are generally consistent with the value determined for MW-6. Based on the known typical absence of significant fracturing within the massive conglomerate beneath the landfill footprint, the K values derived from slug testing appear to be higher than typical values for unfractured rock from the scientific literature (10-8 cm/s, or 10-2 ft/year). Monitoring well gauging data from the October 2024 monitoring event, and determined aquifer properties described above, were used to estimate groundwater seepage velocity and specific discharge (Table A). An average effective porosity of 0.6% (0.006) was utilized based on calculated values for MW-12, MW-13R, and MW-14. An average K of 0.043 ft/day (1.52 x 10-5 cm/sec) was utilized based on K values derived from slug testing of MW-6, MW-12, MW-13R, and MW-14. The groundwater seepage velocity was estimated with the following equation: Where: V = Kx i Tie V = groundwater flow velocity (ft/sec) K = horizontal hydraulic conductivity (ft/sec) i = horizontal hydraulic gradient (dh/dl, unitless) dh = difference in hydraulic head between wells (ft) d1= distance between wells (ft) Ile = effective porosity (%) The specific discharge of the surficial aquifer was estimated with the following equation: Where: q=Kxi q = specific discharge (ft/sec) K = horizontal hydraulic conductivity (ft/sec) i = horizontal hydraulic gradient (dh/dl, unitless) dh = difference in hydraulic head between wells (ft) d1= distance between wells (ft) 6 P &dAo H NA v5 Lr 6reenr�o [UustE Solutions Table A — Estimation of Groundwater Flow Velocity Parameter K (ft/day) I (ft) qe (%) V (ft/day) V (ft/year) MW-lA to MW-5 Seepage Velocity 0.043 0.026 0.6 0.189 69.10 Specific 0.043 0.026 NA 0.001 0.415 Discharge 3.2 Groundwater Analytical Results A summary of Appendix I VOCs, metals, and inorganic analytes detected in the groundwater samples at concentrations above their respective laboratory reporting limits is provided in Table 2. The laboratory analytical data reports are provided in Appendix B. Historical analytical detections above their respective laboratory reporting limits are provided in Table 4. VOCs The analytical data for the Fall 2024 monitoring event indicates that 1,4-dioxane was detected at concentrations which exceed the North Carolina Administrative Code Title 15A Subchapter 2L Groundwater Classifications and Standards (2L Standards) of 3 µg/L in MW-8 (3.1 µg/L) and MW-9 (11.0 µg/L). The detection in MW-8 was confirmed by the Pace split sample. The analytical report indicates that benzene was detected at a concentration of 1.3 µg/L in MW- 9, which slightly exceeds the 2L Standard of 1.0 µg/L. The analytical report for the December 4 confirmation sample from MW-9 indicates benzene was detected at a concentration of 1.3 jig/L. No other VOCs were detected at concentrations which exceed their respective 2L Standard. Inor ag nics The analytical report indicates that detected total dissolved solids (TDS) levels exceeded the 2L Standard of 500,000 µg/L in MW-1, MW-2, MW-3, MW-8, MW-9, MW-10, MW-11R, MW-12, MW-13R, and MW-14. Chloride was detected at concentrations which exceed the 2L Standard of 250,000 µg/L in MW-1, MW-2, MW-9, MW-10, MW-12, MW-13R, and MW-14. It is 7 P &dAo H NA v5 Lr 6reenr�o [UustE Solutions important note that the highest concentration of TDS (3,900,000 µg/L) was detected in upgradient monitoring well MW-1. According the analytical report, barium was detected at concentrations which exceed the 2L Standard of 700 µg/L in MW-1 (1,100 µg/L), MW-9 (1,100 µg/L), MW-10 (1,900 µg/L), MW- 13R (910 µg/L), and MW-14 (1,800 µg/L). The fact that barium was detected at an elevated concentration in upgradient monitoring well MW-1, and was detected above laboratory reporting limits in all sampled monitoring wells at the Site, suggests that these concentrations reflect naturally occurring groundwater conditions at the facility. The analytical report indicates that chromium was detected in cross -gradient well MW-13R at a concentration of 13.0 µg/L, which exceeds the 2L standard of 10 µg/L. The analytical results indicate that cobalt was detected at concentrations which exceed the 2L Standard of 1.0 µg/L in MW-3 (15.0 µg/L), MW-5 (5.0 µg/L), MW-6 (1.6 µg/L), MW-7 (1.3 µg/L), MW-8 (2.0 µg/L), MW-9 (5.6 µg/L), MW-11 R (16.0 µg/L), and MW-12 (1.2 µg/L). The consistency of these detections with historical detections suggests that they are representative of naturally occurring cobalt concentrations. Iron and manganese were detected at concentrations which exceed their respective 2L Standards in the majority of the samples collected from Site monitoring wells. Detected concentrations of both iron and manganese were above their 2L Standards of 300 µg/L and 50 µg/L, respectively, in MW-2, MW-3, MW-4, MW-5, MW-6, MW-7, MW-8, MW-9, MW-11R, and MW-12. Manganese was also detected at a concentration in excess of the 2L Standard in MW-10 and MW-14. According to the analytical report, mercury was detected in eleven of the fourteen perimeter monitoring wells, with one of the highest detected concentrations being in upgradient monitoring well MW-1. Mercury was detected at concentrations which exceed the 2L standard of 1.0 µg/L in upgradient monitoring well MW-1 (1.6 µg/L), cross -gradient monitoring well MW-13R (2.1 µg/L), and upgradient monitoring well MW-14 (1.2 µg/L), however mercury was not detected 8 A &UA. &&Am a 6reerriuQ lUos�E s'nlutrons above laboratory reporting limits in the Leachate sample. The concentration of mercury detected in MW-1 during the Fall 2024 sampling event is consistent with historical detections in this well, which suggests that mercury may be locally naturally occurring. The analytical data indicates that vanadium was detected in cross -gradient monitoring well MW- 14 at a concentration of 8.4 µg/L, which exceeds the 2L Standard of 7 jig/L. Vanadium was also detected at a concentration of 7.0 µg/L in nearby upgradient well MW-1. Per the NCDEQ SWS-approved Alternative Source Demonstration Addendum, dated April 20, 2018 and prepared by CEC, an alternative source demonstration is being performed to address 2L Standard and IMAC exceedances for chromium, cobalt, iron, manganese, thallium, and vanadium. CEC will submit an addendum alternative demonstration report to NCDEQ SWS upon the completion of statistical data analysis, in which an alternative concentration will be proposed for metals listed above. 3.3 Surface Water Results A summary of the analytical results for the surface water samples is provided in Table 3. The laboratory analytical data reports are provided in Appendix B. Historical analytical results are provided in Table 5. Analytical data for surface water is compared to the North Carolina 15A NCAC 02B Water Quality Standards for Surface Waters (213 Standards) for Aquatic Life & Secondary Recreation (ALSR), Fish Consumption (FC), and In -Stream Target Values (ISTV) for Class C streams. Surface water samples were collected from four locations from Little Branch along the western property boundary (SW-1 and SW-2) and the tributary to Little Branch which forms the southern property boundary (SW-3R and SW-4). The approximate surface water sampling locations are depicted on Figure 2. Surface water samples were analyzed for Appendix I VOCs plus THE and 1,4-dioxane via EPA Method 8260. The analytical results indicate that no VOCs were detected at concentrations above laboratory reporting limits. 9 P &dAo H NA v5 Lr 6reerrrllo [UustE Solutions 4.0 Conclusions & Recommendations Groundwater samples were collected from thirteen Site monitoring wells at the Greenway Waste Solutions of Apex, LLC C&D Landfill by GWSA personnel on October 21 and 22, as well as December 4, 2024. In addition, four surface water samples were collected from tributary creeks of Little Branch along the southern and western property boundaries. 4.1 Conclusions Historically, dissolved VOC/SVOC constituents in groundwater at this site have been generally below NCDEQ 2L standards since the development of Phase I of our C&D Landfill. Analytical data from the Fall 2024 sampling event indicates that 1,4-dioxane, which is one of the most prevalent VOCs in C&D Landfills across the state due to its relatively high solubility in groundwater, was detected at a low-level exceedance of the 2L Standard in MW-8 and MW-9. The only other VOC detected slightly above the 2L Standard is benzene in MW-9. Based on industry experiences with VOC detections in groundwater resulting from landfill gas (LFG) integrating at the groundwater interface, GWSA has elected to preemptively install an active LFG extraction system to limit LFG contact with groundwater. Continuous operation of this LFG extraction system is expected to lead to a decrease in detected concentrations of VOCs such as 1,4-dioxane and benzene over time. Metals barium, cobalt, iron, and manganese were detected at concentrations which exceed their respective 2L Standard in the majority of samples collected from Site monitoring wells. An addendum alternative source demonstration report will be submitted by CEC to propose alterative standard concentrations based on naturally occurring metals concentrations at the Site. Chromium was detected in cross -gradient monitoring well MW-13R at a concentration of 13.0 µg/L, which exceeds the 2L Standard of 10 jig/L. MW-13R is located upgradient of the current extent of landfilled waste, and this concentration is generally consistent with the historical range of detections for chromium in MW-13R, which may suggest that the detected concentration reflects naturally occurring groundwater conditions. 10 P &dAo HrNAvS Lr 6reenr�o [UustE Solutions Vanadium was detected in cross -gradient monitoring well MW-14 at a concentration of 8.4 µg/L, which exceeds the 2L Standard of 7 µg/L. Vanadium was also detected in nearby upgradient monitoring well MW-1 at a concentration of 7.0 µg/L, which suggests that these detections may be naturally occurring. Mercury was detected at a concentration of 1.6 µg/L in upgradient monitoring well MW-I, which slightly exceeds the 2L Standard for of 1.0 µg/L. Mercury was also detected in excess of the 2L Standard in cross -gradient monitoring wells MW-13R (2.1 µg/L) and MW-14 (1.2 µg/L), both of which are currently located upgradient of landfilled waste. The consistency of these upgradient and cross -gradient mercury detections with historical detections in these wells, and the fact that mercury was not detected in the leachate sample, suggests that they may be representative of naturally occurring groundwater conditions at the facility. The analytical data indicates that TDS and chloride were detected at concentrations which exceed their respective 2L Standards in samples collected from both upgradient and downgradient monitoring wells. Consistent with historical analytical results, the highest concentration of TDS was detected in upgradient monitoring well MW-1. An upgradient source for the elevated concentrations of TDS and chloride has not been identified. 4.2 Recommendations Additional evaluation is required to determine the source of the elevated concentrations of TDS and chloride which were detected in MW-1, MW-2, MW-3, MW-8, MW-9, MW-10, MW-11R, MW-12, MW-13R, and MW-14. GWSA will closely monitor concentrations of mercury in MW-13R and MW-14 as construction and demolition waste is landfilled upgradient to these wells in the future, and additional well purging will be conducted during sampling activities to minimize turbidity prior to collecting samples. 1 1 P &dAo HrNAvS Lr 6reenr�o [UustE Solutions TINGEN RD / NORTH kr -�p ,HOODS t i t IRONGATE DR 0 55 pEPp O O/ V I N- _ • BOBS/TT RD 2 4 �Q• -rf v c8 pVr o ��p STRAYWy/TEAV E 350 SIT OZD SM/T —l- F/E(p R0 - 350 Feltonviile� D,e 3 -� :. O 3✓ Cam$ �� w HYANNIS DR ` , 7 55 350 Fitt/( !f/, 9poA C�EEKHAVEN co 3C}j A j� O L \ ( I O eNEHOR CREEK WAY 150. l REFERENCE U.S.G.S. 7.5' TOPOGRAPHIC MAP, APEX QUADRANGLE, NC DATED: 2016. //AN AV AV Civil & Environmental Consultants, Inc. 3701 Arco Corporate Drive - Suite 400 - Charlotte, NC 28273 Ph: 980.237.0373 - Fax: 980.237.0372 www.cecinc.com CX c 1 -X ki SCALE IN FEET 0 2000 4000 HIGHWAY 55 C&D LANDFILL GREENWAY WASTE SOLUTIONS OF APEX, LLC SITE LOCATION MAP DRAWN BY: PAB LCHECKED BY: MBG I APPROVED BY: DMC FIGURE NO.: DATE: JANUARY 2025 1 DWG SCALE: 1 "=2000 PROJECT NO: 1 1 1-370.003 1 O 0 a� .c c 4 O O N J 0 ti m 0 v 0 �. �i a 3 7 N of 0 Table 1 (Page 1 of 1) Summary of Groundwater Elevation Data Greenway Waste Solutions of Apex, LLC Apex, North Carolina October 17, 2018 April 17, 2019 October 24, 2019 April 2, 2020 October 27, 2020 April 12, 2021 October 27, 2021 April 4, 2022 October 25, 2022 April 18, 2023 October 9, 2023 April 16, 2024 October 21, 2024 Well ID TOC Elevation (ft mal) Depth to Groundwater ft below TOC Groundwater Elevation feet mal Depth to Groundwater ft below TOC Groundwater Elevation feet anal Depth to Groundwater ft below TOC Groundwater Elevation feet mal Depth to Groundwater ft below TOC Groundwater Elevation feet mal Depth to Groundwater ft below TOC Groundwater Elevation feet mailft Depth to Groundwater below TOC Groundwater Elevation feet msl Depth to Groundwater ft below TOC Groundwater Elevation feet -1 Depth to Groundwater ft below TOC Groundwater Elevation feet msl Depth to Groundwater ft below TOC Groundwater Elevation feet mal Depth to Groundwater ft below TOC Groundwater Elevation feet msl Depth to Groundwater ft below TOC Groundwater Elevation feet -1 Depth to Groundwater ft below TOC Groundwater Elevation feet mal Depth to Groundwater ft below TOC Groundwater Elevation feet mal MW-1 364.51 16.82 347.69 15.64 348.87 16.23 348.28 17.59 346.92 16.01 348.50 15.62 348.89 15.57 348.94 17.41 347.10 16.84 347.67 15.96 348.55 16.00 348.51 17.68 346.83 15.70 348.81 MW-2 294.84 7.45 287.39 7.45 287.39 10.95 283.89 7.96 286.88 8.80 286.04 8.55 286.29 10.79 284.05 8.45 286.39 11.72 283.12 7.30 287.54 11.37 283.47 9.12 285.72 9.90 284.94 MW3 288.57 5.26 283.31 4.73 283.84 8.58 279.99 4.94 283.63 5.85 282.72 5.24 283.33 7.05 281.52 4.60 283.97 8.58 279.99 4.41 284.16 8.12 280A5 5.90 282.67 6.90 281.67 MW4 286.25 6.08 280.17 4.72 281.53 8.12 278.13 5.18 281.07 6.60 279.65 5.95 280.30 7.52 278.73 4.88 281.37 8.63 277.62 4.71 281.54 8.38 277.87 6.20 280.05 6.83 279.42 MW5 284.76 6.28 278.48 4.29 280.47 8A2 276.34 4.80 279.96 6.54 278.22 5.76 279.00 7.67 277.09 7.58 277.18 8.95 275.81 4.52 280.24 8.75 276.01 6.21 278.55 7.27 277.49 MW6 287.07 5.63 281.44 5.01 282.06 9.48 277.59 5.19 281.88 6.33 280.74 5.91 281 A6 8.47 278.60 4.81 282.26 10.09 276.98 4.84 282.23 9.38 277.69 6.23 280.84 7.50 279.57 MW-7 1 297.58 7.28 290.30 1 7.34 290.24 12.22 285.36 6.85 290.73 8.27 1 289.31 7.53 1 290.05 10.83 1 286.75 6.78 1 290.80 12.27 285.31 6.74 290.84 12.12 285.46 1 7.29 290.29 9.96 1 287.62 MW-8 315.24 20.42 294.82 19.39 295.85 20.20 295.04 20.19 295.05 20.77 1 294.47 19.77 295.47 21.57 293.67 19.79 1 295.45 22.21 293.03 19.68 295.56 21.84 293.40 1 20.51 294.73 21.16 1 294.08 MW-9 314.89 6.58 308.31 6.73 308.16 9.17 305.72 6.09 30880 6.96 307.93 622 308.67 8.97 305.92 6.26 308.63 9.65 305.24 5.50 309.39 8.96 305.93 6.68 308.21 7.43 307.46 304.49 14.03 290.46 13.82 290.67 15.28 28.21 9MW-10 14.28 290.21 15.45 289.04 14.28 290.21 14.86 289.63 13.60 290.89 15.57 288.92 13.38 291.11 14.98 289.51 14.82 289.67 14.8 289.69 MINA 1R 339.91 8.78 331.13 7.72 332.19 . 083 329.08 10.33 329.58 10.66 329.25 10.38 329.53 10.93 328.98 10.93 328.98 13.09 326.82 10.23 329.68 11.87 328.04 11.57 328.34 10.98 328.93 MWA2 319.74 NI NI NI 14.6 13.25 306.49 14.18 305.56 13.88 305.86 14.48 305.26 14.87 304.87 13.71 306.03 13.59 306.15 14.19 305.55 12.89 306.85 MW-13R 324.46 Ni NI NI 7.47 06 7.62 316.84 Z51 316.95 NM 629 318.17 6,29 318.17 5A9 319.27 8.55 315.91 6.65 317.81 6.6 317.86 MW-14 330.61 NM NM 10,46 320.15 9.77 11.29 31932 10.5 320.11 12.6 318.01 1 14.68 315.93 10.09 320.52 13.28 317.33 11.44 319.17 11.87 318.74 Notes: NM = Not measured; NI =Not Installed TOC= Surveyed well top -of -casing elevation MW-11 was abandoned on June 16, 2017 and was relocated and replaced by MW-IIR on November 22, 2017. Table 1 (Page 1 of 1) Greenway Waste Solutions of Apex, LLC Table 2 (Page 1 of 1) Summary of Recent Groundwater Sample Analytical Detections Greenway Waste Solutions of Apex, LLC Highway 55 C&D Landfill Apex, North Carolina Sample ID CAS Number Screening Criteria W- M1 NIW-2 MW-3 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11R MW-12 M W-13R MW-14 Leachate Date 10/22/24 10/21/24 10/21/24 10/21/24 10/21/24 10/21/24 10/22/24 10/22/24 10/22/24 10/22/24 10/22/24 12/5/24 10/21/24 10/21/24 10/22/24 10/22/24 10/22/24 10/22/24 Analytical Laboratory 2L Standard(') IMAC (2) TA TA TA TA TA TA TA TA TA Du P split TA TA TA TA TA TA TA TA Appendix I VOCs by EPA 8260E (pg/L) 75-34-3 6 <1.0 <1.0 <1.0 <1.0 <1.0 0.62 J <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,1-Dichloroethane 1,4-Dioxane 123-91-1 3 - <0.40 1.5 0.59 0.77 0.37 J 0.92 0.65 3.1 2.8 5.1 11.0 NS <0.40 <0.40 <0.40 <0.40 <0.40 30.0 2-Butanone (MEK) 78-93-3 4,000 - <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 1 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 4-Methyl-2-pentanone (MIBK) 108-10-1 NS <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Acetone 67-64-1 6,000 <10 <10 <10 <10 <10 <10 <10 <1 < <10 <25.0 <10 <10 <10 <10 <10 <10 <10 17.0 Benzene 71-43-2 1 - <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.93 0.84 <1.0 1.3 1.3 <0.50 <0.50 <0.50 <0.50 <0.50 0.81 Bromodichrloromethane 75-274 0.6 - <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 I <1.0 <1.0 Carbon Disulfide 75-15-0 700 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 1.5 J Chloroform 67-66-3 70 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <1.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Dibromochloromethane 12448-1 0.4 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Tetrahydrofuran 109-99-9 NE 2,000 <10 "- <10 "- <10 "- <10 "- <10 '- <10 '- <10 '- <10 '- <10 `- <10 <10 '- 11.0 <10 "- <10 "- <10 "- <10 "- <10 '- 700 Toluene 108-88-3 600 - <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <1.0 0.29 J <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 1.1 Vinyl chloride 75-01-4 0.03 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Appendix I Metals by EPA 6020B/7470At3I fua/L1 Antimony 7440-36-0 1 - <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 NS NS <3.0 NS <3.0 <3.0 <3.0 <3.0 <3.0 3.2 Arsenic 7440-38-2 10 0.70 J 2.2 0.69 J 3.8 3.1 2.2 1.7 3.0 NS NS 8.1 NS 0.93 J 3.2 1.8 0.31 J 0.55 J 100 Barium 7440-39-3 700 1, 000 240 110 120 59.0 120 77.0 150 NS NS 1,100 NS 1,900 230 400 910 1,800 380 Beryllium 7440-41-7 4 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NS NS <1.0 NS <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Cadmium 7440-43-9 2 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NS NS <0.50 NS <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Calcium 7440-70-2 NE NE 370,000 190,000 1 77,000 33,000 21,000 29,000 55,000 120,000 NS NS 130,000 NS 380,000 81,000 130,000 310,000 240,000 420,000 Chromium 7440-47-3 10 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 2.2 J NS NS 3.5 J NS <5.0 <5.0 <5.0 13.0 <5.0 44.0 Cobalt 744048-4 1 <1.0 0.46 J 15.0 0.68 J 5.0 1.6 1.3 2.0 NS NS 5.6 NS <1.0 16.0 1.2 <1.0 <1.0 2.2 Copper 7440-50-8 1,000 <2.0 <2.0 1.0 J <2.0 0.68 J <2.0 <2.0 <2.0 NS NS 0.75 J NS 0.53 J 1.1 J 0.57 J 1.0 J 0.78 J 0.50 J Iron 7439-89-6 300 - <100 960 22800 2 000 8�00 350 1 500 2 800 NS NS 9,300 NS 170 4 000 1�00 <100 180 610 Lead 7439-92-1 15 - <0.50 <0.50 0.45 J 0.43 J 0.41 J <0.50 <0.50 <0.50 NS NS <0.50 NS <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Manganese 7439-96-5 50 9.3 840 1,300 1,700 1.200 480 500 600 NS NS 5.200 NS 1.700 2.600 1,500 6.0 230 510 Mercury 7439-97-6 1 1.6 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 NS NS <0.20 NS <0.20 <0.20 <0.20 2.1 1.2 <0.20 Nickel 7440-02-0 100 - 2.0 18.0 2.2 1.2 J 0.74 J 0.98 J 4.1 8.8 NS NS 15.0 NS <2.0 5.9 3.3 <2.0 '.0 3.7 Selenium 7782-49-2 20 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 NS NS 1.2 J NS <2.5 1.1 J <2.5 1.3 J <2.5 3.7 Silver 7440-22-4 20 0.22 J <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NS NS <0.50 NS <0.50 <0.50 <0.50 0.17 J 0.31 J <0.50 Thallium 7440-28-0 2 - <2.0 <2.0 <2.0 1 <2.0 <2.0 <2.0 1 <2.0 <2.0 NS NS <2.0 NS <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Vanadium 7440-62-2 7 - 7.0 <5.0 3.0 J <5.0 3.2 J <5.0 <5.0 <5.0 NS NS <5.0 NS <5.0 <5.0 <5.0 <5.0 8.4 21.0 Zinc 7440-66-6 1,000 - <10 <10 <10 <10 <10 <10 <10 <10 NS NS <10 NS =10 <10 <10 <10 <10 <10 Inorganic Indicator Parameters (mg/1-) Total Dissolved Solids SW311 500,000 3,900,000 1,200,000 830,000 380,000 150,000 210,000 360,000 880,000 NS NS 2,100,000 NS 3,800,000 1,000,000 1,200,000 2,400,000 2,900,000 2,800,000 Total Alkalinity as CaCO3 by SM 2320 SW337 NE NE 470,000 230,000 200,000 82,000 100,000 140,000 510,000 NS NS 730,000 NS 250,000 500,000 380,000 520,000 470,000 1,700,000 Chloride b SM 4500 SW301 250,000 [1150,000 000 000 290 000 190,000 63,000 7,500 26,000 42,000 98,000 NS NS 640 000 NS 1 500 000 150,000 340,000 1 700 000 1,200,000 97,000 Sulfate b EPA 300.0 14808-79-8 250,000 14,000 52,000 110,000 18,000 15,000 28,000 67,000 66,000 NS NS 90,000 NS 11,000 68,000 110,000 9,100 13,000 450,000 Notes: 1) 2L = North Carolina Department of Environmental Quality (NCDEQ) 15A NCAC 02L .0202 GW Standards (Eff. 2013) Levels (April 11, 2022). 2) IMAC = Interim Maximum Allowable Concentration (Eff. 2013) 3) Mercury analyzed by EPA Method 7470A P = Pace, TA = Eurofins TestAmerica NA = Not Analyzed; NS = Not Sampled; NE = Not Established J = Analyte detected at a level less than the RL and greater than or equal to the MDL. = LCS and/or LCSD is outside acceptance limits, low biased. Bold and Underlined indicates result or reporting level exceeded the 2L Standard Bold indicates exceedance of IMAC when no 2L Standard is specified Grey and Underlined indicates laboratory RL exceeded the PQL pg/L = micrograms per liter; mg/L = milligrams per liter Table 2 (Page 1 of 1) Greenway Waste Solutions of Apex, LLC Table 3 (Page 1 of 1) Summary of Recent Surface Water Sample Analytical Data Greenway Waste Solutions of Apex, LLC Highway 55 C&D Landfill Apex, North Carolina CAS Number Screening Criteria(l) Date Aquatic Life & Secondary Recreation Fish Consumption In -Stream Target Values 10/22/24 10/22/24 10/22/24 10/22/24 Sample ID SW-1 SW-2 SW-3R SW-4 Appendix I VOCs by EPA 8260B (ug/L) 1,1-Dichloroethane 75-34-3 - - -- <1.0 <1.0 <1.0 <1.0 1,1-Dichloroethene 75-35-4 - - -- <1.0 <1.0 <1.0 <1.0 1,1,1-Trichloroethane 71-55-6 - - 2,500 <1.0 <1.0 <1.0 <1.0 1 ,1 ,2-Trichloroethane 79-00-5 - - 2,300 <1.0 <1.0 <1.0 <1.0 1,1,1,2-Tetrachloroethane 630-20-6 - - -- <1.0 <1.0 <1.0 <1.0 1 ,1,2,2-Tetrachloroethane 79-34-5 - 4 1,000 <1.0 <1.0 <1.0 <1.0 1,4-Dioxane 123-91-1 - - -- <0.40 <0.40 <0.40 0.21 J 2-Butanone (MEK) 78-93-3 - - 26,000 <5.0 <5.0 <5.0 <5.0 1,2-Dichlorobenzene 95-50-1 - - 470 <1.0 <1.0 <1.0 <1.0 1,2-Dichloroethane 107-06-2 - - -- <1.0 <1.0 <1.0 <1.0 1,4-Dichlorobenzene 106-46-7 - - -- <1.0 <1.0 <1.0 <1.0 4-Methyl-2-pentanone (MIBK) 108-10-1 - - 26,000 <5.0 <5.0 <5.0 <5.0 Acrylonitrile 107-13-1 - - 420 <20 <20 <20 <20 Benzene 71-43-2 - 51 -- <0.50 <0.50 <0.50 <0.50 Bromochrloromethane 74-97-5 - - -- <1.0 <1.0 <1.0 <1.0 Bromodichrloromethane 75-27-4 - - -- <1.0 <1.0 <1.0 <1.0 Bromoform 75-25-2 - - -- <1.0 <1.0 <1.0 <1.0 Bromomethane 74-83-9 - - 0.04 <3.0 <3.0 <3.0 <3.0 Carbon Disulfide 75-15-0 - - 100 <2.0 <2.0 <2.0 <2.0 Carbon Tetrachloride 56-23-5 - 1.6 560 <1.0 <1.0 <1.0 <1.0 Chlorobenzene 108-90-7 - - 140 <1.0 <1.0 <1.0 <1.0 Chloroethane 75-00-3 - - -- <5.0 <5.0 <5.0 <5.0 Chloroform 67-66-3 - - <2.0 <2.0 <2.0 <2.0 Chloromethane 74-87-3 - - <5.0 <5.0 <5.0 <5.0 Dibromochloromethane 124-48-1 - - <1.0 <1.0 <1.0 <1.0 Dibromomethane 74-95-3 - - <1.0 <1.0 <1.0 <1.0 cis-1,3-Dichloropropene 10061-01-5 - - <1.0 <1.0 <1.0 <1.0 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 - - -- <5.0 <5.0 <5.0 <5.0 1,2-Dibromoethane; Ethylene dibromide (EDB) 106-93-4 - - -- <1.0 <1.0 <1.0 <1.0 Ethylbenzene 100-41-4 - - 97 <0.50 <0.50 <0.50 <0.50 Styrene 100-42-5 - - -- <1.0 <1.0 <1.0 <1.0 Tetrachloroethene 127-18-4 - 3.3 120 <1.0 <1.0 <1.0 <1.0 Toluene 108-88-3 11 - -- <0.50 0.21 J <0.50 <0.50 trans-1.2-Dichloroethene 156-60-5 - - -- <1.0 <1.0 <1.0 <1.0 trans-1,3-Dichloropropene 10061-02-6 - - -- <1.0 <1.0 <1.0 <1.0 Trchloroethene 79-01-6 - 30 -- <0.50 <0.50 <0.50 <0.50 Trichlorofluoromethane 75-69-4 - - -- <1.0 <1.0 <1.0 <1.0 Vinyl acetate 108-05-4 - - -- <2.0 <2.0 <2.0 <2.0 Vinyl chloride 75-01-4 - 2.4 -- <1.0 <1.0 <1.0 <1.0 X lenes Total 1330-20-7 - 11 -- 670 <1.0 <1.0 <1.0 <1.0 Notes: 1) North Carolina Department of Environmental Quality (NCDEQ) 15A NCAC 02B Water Quality Standards for Surface Waters (Eff. June 10, 2019) - = Not Established J = Analyte detected at a level less than the RL and greater than or equal to the MDL. Concentrations in this range are estimated. Bold and Underlined indicates result exceeded the 2B Standard for Aquatic Life & Secondary Recreation Bold indicates exceedance of the 2B Standard for Fish Consumption Underlined indicates exceedance of the In -Stream Target Value pg/L = micrograms per liter; mg/L = milligrams per liter Table 3 (Page 1 of 1) Greenway Waste Solutions of Apex, LLC Table 4 (Page 1 of 14) Summary of Historical Groundwater Analytical Detections Greenway Waste Solutions of Apex, LLC Highway 55 C&D Landfill Apex, North Carolina Sample ID CAS Number Screening Criteria MW-1 Date 11/4/13 4/2/14 10/21/14 4/23/15 10/12/15 4/25/16 10/31/16 4/19/17 10/16/17 4/18/18 4/18/18 6/19/18 10/17/18 4/17/19 10/24/19 4/2/20 10/28/20 4/12/21 10/28/21 4/5/22 10/26/22 4/19/23 10/10/23 4/17/24 10/22/24 Analytical Laboratory 2L Standard"' IMAC 121 S S S S S S S TA P P P D P P P TA TA TA TA TA TA TA TA TA TA TA Appendix I VOCs by EPA 8260B (ualL) 75-343 6 <1 <1 <1 <0.13 <0.19 <0.19 <0.4 <1 <1 <1 NS NS <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,1-Dichloroethane 1,4-Dioxane 123-91A 3 NS NS NS NS NS NS NS NS NS NS NS NS <2 <2 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.40 2-Butanone (MEK) 78-93-3 4,000 <10 <70 <10 <2 <1.8 <1.8 12 15 <5 <5 NS NS <5 <5 <5 <5 <5.0 <5.0 <5.0 <10 <10 <5.0 <5.0 <5.0 <5.0 4-Methyl-2-pentenone (MIBK) 108-10-1 NS <10 <10 <10 <0.23 <0.23 <0.29 <2 <5 <5 <5 NS NS <5 <5 <5 <5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Acetone 67-64A 6,000 <20 <20 1 <20 <6.7 <1.6 1 <1.6 <2 <5 <25 1 <25 NS NS <25 1 <25 <10 <10 <10 I <10 <10 <10 <10 1 5.7 JB <10 1.8 J <10 Benzene 71-43-2 1 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <0.5 <1 <1 NS NS <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Bromodichdoromelhane 75-27-4 0.6 <1 <1 <1 <0.21 <0.21 <0.23 <0.4 <1 <1 <1 NS NS <1 <1 <7 <7 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Carbon Disulfide 75-15-0 700 <1 <1 <1 <0.097 <0.45 <0.45 <0.4 <2 <2 <2 NS NS <2 <2 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Chloroform 67-66-3 70 <1 <1 <1 <0.21 0.28 J 0.41 J 0.65 J <2 <1 <1 NS NS <1 <1 <1 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Dibromochloromethane 124-08-1 0.4 <1 <1 <1 <0.21 <0.21 <0.23 <0.4 <1 <1 <1 NS NS <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Telmhydrofumn 109-99-9 NE 2,000 <5 <5 <5 <2 <0.57 <0.57 <1 <10 <10 <10 NS NS <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 *- Toluene 10"83 600 <1 <1 <l <0.33 <0.24 <0.24 <0.4 <0.5 <1 <1 NS NS <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Vinyl chloride 75-01-4 0.03 <1 <1 <1 <0.054 <0.5 <0.5 <0.4 <0.5 <1 <1 NS NS <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Appendix I Metals by EPA 6020BI7470AIsl fpgl Antimony 7, 4036-0 1 <10 <10 <10 <6.6 <6.6 <6.6 <6.6 <3 <5 5.2 <5 <1 13.7 <5 <3 <3 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 Arsenic 7440-38-2 10 <70 <70 <10 <2.2 3.5 J 7.3 J 2.5 J 0.90 J <10 <10 <10 <1 <10 <70 3.3 2.3 1.6 0.95 J 2.0 <1.0 2.1 2.1 1.9 0.63 J 0.70 J Barium 7440393 700 890 850 760 860 850 940 870 1i00 1i00 1i70 997 375 1,120 1,250 1,500 1i00 1000 1000 1i00 960 1000 1000 1�00 1,100 11100 Beryllium 7440-01-7 4 <4 <4 <4 <0.22 <0.22 0.34 J 0.22 J <4 <4 <1 <1 <0.1 <1 <1 <1 <1 <1.0 <1.0 <1.0 ^1+ <1.0 <1.0 <1.0 <1.0 "+ <1.0 <1.0 Cadmium 7440-03-9 2 <2 <2 <2 <0.54 <0.54 <0.54 <0.54 <2 <1 <1 I <1 <0.1 <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Calcium 7440-70-2 NE NE NS NS NS NS NS NS NS NS 452,000 NS NS NS 369,000 458,000 490,000 470,000 470,000 380,000 430,000 340,000 400,000 340,000 370,000 360,000 370,000 Chromium 7440-473 10 <5 <5 <5 <0.72 1.3 J <0.72 <0.72 15 <5 <5 <5 <1 <5 <5 <5 15 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Cobalt 8-4 1 <25 <25 <25 <1.3 <1.3 <1.3 <1.3 0.28 J <5 <5 <5 <4 <5 <5 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Copper 0-8 1,000 <5 <5 <5 <1.8 2.7 J <1.8 <1.8 1.1 J <5 9.8 16.1 1.4 <5 <5 3.1 0.86 J 0.69 J 0.71 J 1.1 J <2.0 <2.0 1.3 J <2.0 <2.0 <2.0 Iron -89-6 300 NS NS NS NS NS NS NS NS <50 <50 <50 36.5 <50 <50 50.0 <100 55J 891 <100 <100 <100 <100 <100 <100 <100 Lead -92-1 15 <10 <10 <10 <4.7 <4.7 <4.7 <4.7 <10 <5 <5 <5 <1 <5 <5 0.24 BJ <0.5 <0.50 <0.50 "1+ <0.50 <0.50 <0.50 0.22 JB <0.50 <0.50 <0.50 Manganese -96-5 50 NS NS NS NS NS NS NS NS 8.6 9.2 <5 7.9 6.3 29.4 25.0 11.0 9.7 26.0 8.8 7.9 8.9 8.9 7.3 10.0 9.3 Mercury 97-6 1 1.1 2.6 1.4 1.2 0.63 1.5 2.4 B 1.2 0.56 1.1 <0.2 1.7 It 0.59 0.21 0.48 1.6 1.4 F7 1.7 2.1 0.21 1.5 1.5 1.2 1.6 Nickel -02-0 100 <40 <40 <40 <2.8 <2.8 <2.8 <2.8 <40 <5 <5 15 <1 <5 <5 0.81 J 0.92 J 0.77 J <2.0 0.87 J <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Selenium -49-2 I 20 <10 <10 <10 <8.5 <8.5 <8.5 <8.5 <2.5 <10 <10 <10 <1 16.7 <10 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 1.1 J <2.5 <2.5 <2.5 Silver -224 20 <5 <5 <5 <2.1 <2.1 <2.1 <2.1 3.3 <5 <5 <5 0.40 <5 <5 0.37 J 0.48 J 0.64 0.25 J 0.23 J <0.50 <0.50 0.19 J 0.36 J 0.19 J 0.22 J Thallium -28-0 2 NS NS NS NS NS NS NS NS NS <0.5 <0.5 <2 <0.1 <0.1 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Vanadium -62-2 7 <50 <50 <50 <2.6 5.1 J 5.9 J 5.4 J 4.9 J 5.5 15 <5 5.3 <5 7.2 8.7 6.7 7.3 5.6 LA 6.2 6.4 7.0 7.1 6.2 7.0 Zinc -66-6 1,000 20.0 <20 <20 <2.2 27.0 9.7 BJ 11 J <20 <10 <10 <10 <5 <10 <70 15.0 <10 <10 <10 <10 <15 <15 <10 <10 <10 <10 Inorganic Indicator Parameters (ualL) Total Dissolved Solids b Sly 2540C 2222 500,000 NS NS NS NS NS NS NS 5,600,000 5 460 000 4 440 000 NS NS 3,840,000 4,630,000 4,900,000 4,200,000 4,100,000 3,800,000 3,900,000 3,900,000 4,800,000 3,800,000 3 700 000 3 700 000 3 900 000 Total Alkalinity as CaCO3 b SM 2320 0192 NE NE NS NS NS NS NS NS NS 410,000 433,000 437,000 NS NS 460,000 457,000 550,000 440,000 420,000 470,000 500,000 480,000 490,000 *- 510,000 520,000 520,000 150,000 Chloride b EPA 9056A -00-6 250,000 NS NS NS NS NS NS NS 2 700 000 2 670 000 2 680 000 NS NS 1 930 000 2 250 000 2 800 000 2 500 000 2 500 000 2 100 000 2 000 000 1 800 000 2 100 000 1 800 000 2.300.000 1,700,000 1,000,000 Sulfate b EPA 9056A 14808-79-8 250,000 NS NS NS NS NS NS NS 3,800 2,800 3,400 NS NS 5,200 7,200 4,300 5,700 5,200 8,600 6,600 6,400 <20,000 *+ 7,400 9,000 8,800 J 14,000 Notes: 1) 2L = North Carolina Department of Environmental Quality (NCDEQ) 15A NCAC 02L .0202 GW Standards (Eff. 2013) Levels (April 11, 2022). 2) IMAC = Intedm Maximum Allowable Concentration (Eff. 2013) 3) Mercury analyzed by EPA Method 7470A S = Shealy, P = Pace, TA = Eurofins TestAmerica NA = Not Analyzed; NS = Not Sampled; NE = Not Established J = Analyte detected at a level less than the RL and greater than or equal to the MDL. in this range am estimated. B = the analyte was detected in the associted blank H = Sample was prepped or analyzed beyond the specified holding time. -= LCS and/or LCSD is outside acceptance limits, low biased. ^1+= Initial Calibration Verification (ICV) is outside acceptance limits, high biased. F1 = MS and/or MSD recovery exceeds control limits Bold and Underlined indicates result or reporting level exceeded the 2L Standard Bold indicates exceedance of IMAC when no 2L Standard is specified pg/L = micrograms per liter; mg/L = milligrams per liter Table 4 (Page 1 of 14) Greenway Waste Solutions of Apex, LLC Table 4 (Page 2 of 14) Summary of Historical Groundwater Analytical Detections Greenway Waste Solutions of Apex, LLC Highway 55 C&D Landfill Apex, North Carolina Sample ID CAS Number Screening Criteria n9N-2 Date 11/4/13 4/2/14 10/21/14 4/23/15 10/12/15 4/25/16 10/31/16 4/20/17 10/16/17 4/18/18 10/17/18 4/17/19 10/24/19 4/12/21 10/27/21 4/4/22 10/26/22 4/18/23 10/10/23 4/16/24 10/21/24 Analytical Laboratory2L Standard"' IMAC a' S S S S S S S TA P P P P TA TA TA TA TA TA TA TA TA TA Appendix I VOCs by EPA 8260B fuall- 75-34-3 6 <1 <1 <1 <0.13 <0.19 <0.19 <0.4 <1 NS <1 <1 <1 <1 112'2110/28/20 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,1-Dichloroethane 1,4-Dioxane 123-91-1 3 NS NS NS NS NS NS NS NS NS NS <2 <2 <1 <1.0 <1.0 <1.0 <1.0 <1.0 1.3 1.6 1.4 1.5 2-Butanone (MEK) 78-93-3 4,000 <70 <10 <10 <2 <1.8 <1.8 12 <5 NS 15 <5 <5 <5 <5.0 <5.0 <5.0 <10 <10 <5.0 <5.0 <5.0 <5.0 4-Methyl-2-pentanone (MIBK) 108-10-1 NS <10 <10 <10 <0.23 <0.23 <0.29 <2 <5 NS <5 <5 <5 <5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Acetone 67-64-1 6,000 <20 <20 <20 <6.7 <1.6 <1.6 <2 <5 NS <25 <25 <25 <10 . <10 <10 4.3 J <10 <10 <10 <10 <10 <10 Benzene 71-03-2 1 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <0.5 NS <1 <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Bromodichdoromethane 75-27-4 0.6 <1 <1 <7 <0.21 <0.21 <0.23 <0.4 <1 NS <1 <1 <1 <1 <7 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Carbon Disulfide 75-15-0 700 <1 <1 <7 <0.097 <0.45 <0.45 <0.4 <2 NS <2 <2 <2 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Chloroform 67-66-3 70 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <2 NS <1 <1 <1 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 0.91 JB <2.0 Dibromochloromethane 124-08-1 0.4 <1 <1 <1 <0.21 <0.21 <0.23 <0.4 <1 NS <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 *+ <1.0 <1.0 <1.0 Tetrahydrofumn 109-99-9 NE 2,000 <5 <5 <5 <2 <0.57 <0.57 <1 <10 NS <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 2.9 JB <10 *- Toluene 108-88-3 600 <1 <l <7 <0.33 <0.24 <0.24 <0.4 <0.5 NS <1 <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.18 J <0.50 <0.50 Vinyl chloride 75-01-4 0.03 <1 <1 <t <0.054 <0.5 <0.5 0.63 J <0.5 NS <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Appendix I Metals by EPA 6020131747001 101W Antimony 744036-0 1 <10 <10 <10 <6.6 <6.6 <6.6 <6.6 <3 NS <5 <5 <5 <3 <3 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 Arsenic 7440-38-2 10 <70 <10 <10 <2.2 4.6 J 3.5 J 3.6 J 1.2 NS <10 <10 <10 2.7 2.5 2.0 0.94 J 1.7 2.3 2.6 3.2 1.8 B 1.1 2.2 Barium 7440-393 700 250 130 120 30.0 330 37.0 160 74.0 NS 57.0 178 46.6 160 110 150 53.0 180 190 230 210 310 57.0 240 Beryllium 7440-01-7 4 <4 1 <4 <4 1 <0.22 <0.22 1 0.24 J <0.22 1 <1 NS <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 A1+ <1.0 <1.0 <1.0 <1.0 A+ <1.0 <1.0 Cadmium 7440-03-9 2 <2 <2 <2 <0.54 <0.54 <0.54 <0.54 <0.5 NS <1 <1 <1 <0.5 <0.5 <0.50 <0.50 1 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Calcium 7440-70-2 NE NE NS NS NS NS NS NS NS NS NS NS 131,000 28,400 110,000 90,000 88,000 33,000 110,000 140,000 150,000 160,000 140,000 B 34,000 190,000 Chromium 7440-473 10 6.2 <5 <5 <0.72 4.4 J <0.72 <0.72 <5 NS <5 <5 <5 <5 <5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 1.5 J <5.0 <5.0 Cobalt 7440-48-4 1 <25 <25 <25 <1.3 3 J <1.3 1.9 J 0.59 J NS <5 <5 <5 0.86 J <1 1.3 0.61 J 0.85 J <1.0 0.56 J 0.44 J <1.0 <1.0 0.46 J Copper 7440-50-8 1,000 12.0 <5 <5 <1.8 4.5 J 8.4 J 2.9 J 0.79 J NS <5 <5 <5 0.52 J <2 0.65 J 0.80 J 0.65 J <2.0 <2.0 <2.0 <2.0 0.86 J <2.0 Iron 7439-89-0 300 NS NS NS NS NS NS NS NS NS 637 1�30 214 1�00 1.100 1.300 460 880 1�00 830 1�00 3�00 370 260 Lead 7439-92-1 15 11.0 <10 <10 <4.7 <4.7 <4.7 <4.7 0.51 NS <5 <5 <5 0.56 B 0.21 J 0.22 J 0.32 J A7+ 0.22 J <0.50 <0.50 0.24 JB <0.50 0.23 J <0.50 Manganese 7439-96-5 50 NS NS NS NS NS NS NS NS NS 189 695 97.8 540 410 550 210 490 810 540 990 1�00 170 840 Mercury 7439-97-6 1 <0.1 <0.1 <0.1 <0.028 <0.028 <0.028 0.055 BJ <0.2 NS <0.2 <0.2 <0.2 <0.2 <0.2 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 0.43 <0.20 Nickel 7440-02-0 100 <40 <40 <40 <2.8 8.1 J <2.8 5.6 J 2.8 NS <5 8.9 <5 8.2 5.7 8.5 2.9 12.0 12.0 15.0 15.0 15.0 3.4 18.0 Selenium 7782-49-2 20 <70 <10 <10 <8.5 c8.5 <8.5 <8.5 <2.5 NS <10 <10 <10 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 Silver 7440-22-4 20 <5 <5 <5 <2.1 <2.1 <2.1 <2.1 <0.5 NS <5 <5 <5 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Thallium 7440-28-0 2 NS NS NS NS NS NS NS NS NS <0.5 <0.1 <0.1 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Vanadium 7440-62-2 7 <50 <50 <50 <2.6 9.2 J <2.6 <2.6 2.5 J NS <5 <5 <5 4.9 J <5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Zinc 7440-66-6 1,000 43.0 <20 <20 <2.2 69.0 87 B 32.0 <20 NS <10 <10 <10 8.3 J <10 E220,OOO <10 <10 <15 <15 <10 <10 <10 <10 Inorganic Indicator Parameters (ug/L) Total Dissolved Solids b SM 2540C E1642222 500,000 NS NS NS NS NS NS NS 530 000 NS 323,000 896 000 267,000 760 000 630 000 200,000 770,000 810,000 970,000 910,000 920,000 310,000 1,200.000 Total Alkalinityas CaCO3 b SM 2320 E1640192 NE NE NS NS NS NS NS NS NS 160,000 NS 71,300 329,000 88,600 400,000 220,000 130,000 360,000 350,000 430,000 390,000 440,000 280,000 470,000 Chloride b EPA 9056A 16887-00-6 250,000 NS NS NS NS NS NS NS 130,000 NS 58,300 238,000 25,100 220,000 140,000 230,000 51,000 200,000 250,000 290 000 280 000 320 000 170,000 290,000 Sulfate b EPA 9056A 14808-79-8 250,000 NS NS NS NS NS NS NS 87,000 NS 73,300 76,200 65,800 63,000 88,000 90,000 80,000 52,000 58,000 45,000 55,000 14,000 54,000 52,000 Notes: 1) 2L = North Carolina Department of Environmental Quality (NCDEQ) 15A NCAC 02L .0202 GV Levels (April 11, 2022). 2) IMAC = Interim Maximum Allowable Concentration (Eff. 2013) 3) Mercury analyzed by EPA Method 7470A S = Shealy, P = Pace, TA = Eurofins TestAmerm NA = Not Analyzed; NS = Not Sampled; NE = Not Established J = Analyte detected at a level less than the RL and greater than or equal to the MDL. in this range are estimated. B = the analyte was detected in the assoc0ed blank H = Sample was prepped or analyzed beyond the specified holding time. -= LCS and/or LCSD is outside acceptance limits, low biased. Al+= Initial Calibration Verification (ICV) is outside acceptance limits, high biased. F1 = MS and/or MSD recovery exceeds control limits Bold and Underlined indicates result or reporting level exceeded the 2L Standard Bold indicates exceedance of IMAC when no 2L Standard is specified pg/L = micrograms per liter, mg/L = milligrams per liter Table 4 (Page 2 of 14) Greenway Waste Solutions of Apex, LLC Table 4 (Page 3 of 14) Summary of Historical Groundwater Analytical Detections Greenway Waste Solutions of Apex, LLC Highway 55 C&D Landfill Apex, North Carolina Sample ID CAS Number Screening Criteria n41V-3 Date 11/4/13 4/2/14 10/21/14 4/23/15 10/12/15 4/25/16 10/31/16 4/20/17 10/16/17 4/18/18 10/17/18 4/17/19 10/24/19 4/2/20 10/28/20 4/12/21 10/27/21 4/18/23 10/10/23 4/16/24 10/21/24 Analytical Laboratory2L Standard"' IMAC a' S S S S S S S TA P P P P TA TA TA TA TA TA TA TA TA Appendix I VOCs by EPA 8260B fuall- 75-34-3 6 <1 <1 <1 <0.13 <0.19 <0.19 <0.4 <1 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 ;142;101222 <1.0 <1.0 <1.0 <1.0 1,1-Dichloroethane 1,4-Dioxane 123-91-1 3 NS NS NS NS NS NS NS NS NS NS <2 <2 1.3 <1 <1.0 <1.0 <1.0 1.2 1.2 0.64 J 0.59 2-Butanone (MEK) 78-93-3 4,000 <70 <10 <10 <2 <1.8 <1.8 <2 <5 <5 <5 <5 <5 <5 <5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 4-Methyl-2-pentanone (MIBK) 108-10-1 NS <10 <10 <10 <0.23 <0.23 <0.29 <2 <5 <5 <5 <5 <5 <5 <5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Acetone 67-64-1 6,000 <20 <20 <20 <6.7 <1.6 <1.6 <2 <5 <25 <25 <25 <25 <10 5.8 J <10 <10 5.4 J <10 . <10 <10 <10 Benzene 71-03-2 1 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <0.5 <1 <1 <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Bromodichdoromethane 75-27-4 0.6 <1 <1 <7 <0.21 <0.21 <0.21 <0.4 <1 <1 <1 <1 <1 <1 <7 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Carbon Disulfide 75-15-0 700 1.0 <1 <7 <0.097 <0.45 <0.45 <0.4 <2 <2 <2 <2 <2 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0'+ <2.0 M<2.O <2.0 <2.0 Chloroform 67-66-3 70 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <2 <1 <1 <1 <1 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 0.98 JB <2.0 Dibromochloromethane 124-08-1 0.4 <1 <1 <1 <0.21 <0.21 <0.23 <0.4 <1 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0'+<1.0 <1.0 Tetrahydrofumn 109-99-9 NE 2,000 <5 <5 <5 <2 <0.57 <0.57 <1 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 2.1 JB <10 *- Toluene 108-88-3 600 <1 <1 <7 <0.33 <0.24 <0.24 <0.4 <0.5 <1 <1 <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Vinyl chloride 75-01-4 0.03 <1 <1 <1 <0.054 <0.5 <0.5 <0.4 <0.5 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 '+ <1.0 <1.0 <1.0 <1.0 Appendix I Metals by EPA 6020131747001 101W Antimony 744036-0 1 <10 <10 <10 <6.6 <6.6 <6.6 <6.6 <3 <5 <5 <5 <5 <3 <3 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 Arsenic 7440-38-2 10 <70 <10 <10 <2.2 3.6 J 5.4 J <2.2 1.6 <10 <10 <10 <10 1.5 1.7 0.74 J 0.65 J 1.3 1.0 1.7 1.7 1.2 B 0.63 J 0.69 J Barium 7440-393 700 330 310 310 240 200 330 170 230 263 260 88.4 311 290 300 280 280 250 100 210 140 250 95.0 110 Beryllium 7440-01-7 4 <4 <4 <4 <0.22 <0.22 0.24 J <0.22 <1 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 A1+ 0.20 J <1.0 <1.0 <1.0 A+ <1.0 <1.0 Cadmium 7440-03-9 2 <2 1 <2 <2 <0.54 <0.54 <0.54 <0.54 <0.5 <1 <1 <1 I <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 0.50 <0.50 <0.50 <0.50 <0.50 Calcium 7440-70-2 NE NE NS I NS NS NS NS NS NS NS 136,000 NS 36,500 181,000 150,000 180,000 160,000 160,000 130,000 110,000 110,000 110,000 140,000 B 99,000 77,000 Chromium 7440-473 10 <5 <5 <5 <0.72 <0.72 < 32 <0.72 <5 <5 <5 <5 <5 <5 <5 <5.0 <5.0 <5.0 <5.0 <5.0 1.3 J <5.0 <5.0 <5.0 Cobalt 7440-48-4 1 <25 <25 <25 <1.3 <1.3 <1.3 <1.3 21.0 <5 4.0 15.6 <5 <1 <1 1.1 9.8 2.4 79.0 51 56.0 5.6 42.0 15.0 Copper 7440-50-8 1,000 7.1 <5 <5 <1.8 <1.8 <1.8 <1.8 0.81 J <5 <5 <5 <5 0.88 J <2 0.85 J <2.0 0.86 J <2.0 1.3 J 0.91 J 0.76 J 0.82 J 1.0 J Iron 7439-89-6 300 NS NS NS NS NS NS NS NS 1�10 5�30 2.040 1�50 1�00 640 660 1�00 1�00 2�00 870 2y_00 1�00 1�00 2�00 Lead 7439-92-1 15 <70 <10 <10 <4.7 <4.7 <4.7 <4.7 0.55 <5 <5 <5 <5 0.43 BJ <0.5 <0.50 <0.50 A1+ 0.37 J <0.50 0.41 J 0.57 B 0.48 J 0.27 J 0.45 J Manganese 7439-96-5 50 NS NS NS NS NS NS NS NS 403 364 920 288 450 200 120 880 160 4�00 200 2�00 790 2�00 1�00 Mercury 7439-97-6 1 <0.1 <0.1 <0.1 <0.028 <0.028 <0.028 0.054 BJ <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 0.23 <0.20 Nickel 7440-02-0 100 <40 <40 <40 <2.8 <2.8 <2.8 <2.8 2.1 <5 <5 <5 <5 <2 2.1 2.2 2.4 2.3 4.5 2.8 4.0 2.7 3.6 2.2 Selenium 7782-49-2 20 <70 <10 <10 <8.5 <8.5 <8.5 <8.5 <2.5 <10 <10 <10 <10 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 Silver 7440-22-4 20 <5 <5 <5 <2.1 <2.1 <2.1 <2.1 <0.5 <5 <5 <5 <5 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Thallium 7440-28-0 2 NS NS NS NS NS NS NS NS NS <0.5"93,20021,400 0.1 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Vanadium 7440-62-2 7 <50 <50 <50 <2.6 <2.6 <2.6 <2.6 <5 <5 <5 6.0 2.9 J -5.0 <5.0 2.9 J 1.8 J 3.4 J 3.5 J 3.1 J <5.0 3.0 J Zinc 7440-66-6 1,000 21.0 <20 <20 <2.2 5.2 J 5.7 BJ 16 J <20 <10 10 7 J <10 <10 <10 <10 <15 <15 <10 <10 <10 <10 Inorganic Indicator Parameters fun/Ll t1.460.000 Total Dissolved Solids b SM 2540C E1642222 500,000 NS NS NS NS NS NS NS 1,600,000 2,250,000 0 000 1 400 000 1 500 000 1 200 000 1 400 000 1 200 000 1 1 00 000 1 1 00 000 1 200 000 1 400 000 1 000 000 830 000 Total Alkalinit as CaCO3 b SM 2320 E1640192 NE NE NS NS NS NS NS NS NS 470,000 705,000 ,000 770,000 700,000 650,000 570,000 570,000 170,000550,000290,000 660,000 210,000 230,000 Chloride b EPA 9056A 16887-00-6 250,000 NS NS NS NS NS NS NS 530000 476 000 000 420 000 460,000 500,000 230,000 370,000 340,000 320,000 3KQME2c+ 390,000 280 000 190,000 Sulfate b EPA 9056A 14808-79-8 250,000 NS NS NS NS NS NS NS 140,000 8,400 34,900,400 17,000 20,000 42,000 100,000 67,000 280 000 54,000 210,00o FZ Fr 52,000 220,000 110,000 Notes: 1) 2L = North Carolina Department of Environmental Quality (NCDEQ) 15A NCAC 02L .0202 GV Levels (April 11, 2022). 2) IMAC = Intedm Maximum Allowable Concentration (Eff. 2013) 3) Mercury analyzed by EPA Method 7470A S = Shealy, P = Pace, TA = Eurofins TestAmerm NA = Not Analyzed; NS = Not Sampled; NE = Not Established J = Analyte detected at a level less than the RL and greater than or equal to the MDL. in this range are estimated. B = the analyte was detected in the assoc0ed blank H = Sample was prepped or analyzed beyond the specified holding time. -= LCS and/or LCSD is outside acceptance limits, low biased. Al+= Initial Calibration Verification (ICV) is outside acceptance limits, high biased. F1 = MS and/or MSD recovery exceeds control limits Bold and Underlined indicates result or reporting level exceeded the 2L Standard Bold indicates exceedance of IMAC when no 2L Standard is specified pg/L = micrograms per liter, mg/L = milligrams per liter Table 4 (Page 3 of 14) Greenway Waste Solutions of Apex, LLC Table 4 (Page 4 of 14) Summary of Historical Groundwater Analytical Detections Greenway Waste Solutions of Apex, LLC Highway 55 C&D Landfill Apex, North Carolina Sample ID CAS Number Screening Criteria n41V-4 Date 11/4/13 4/2/14 10/21/14 4/23/15 10/12/15 4/25/16 10/31/16 4/19/17 10/16/17 4/18/18 10/17/18 4/17/19 10/24/19 4/2/20 10/28/20 4/12/21 10/27/21 4/4/22 10/25/22 4/18/23 10/10/23 4/16/24 10/21/24 Analytical Laboratory 2L Standard"' IMAC a' S S S S S S S TA P P P P TA TA TA TA TA TA TA TA TA TA TA Appendix I VOCs by EPA 8260B fuall- 75-34-3 6 <1 <1 <1 <0.13 <0.19 <0.19 <0.4 <1 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,1-Dichloroethane 1,4-Dioxane 123-91-1 3 NS NS NS NS NS NS NS NS NS NS 3.1 4.9 3.7 2.1 0.63 J 2.3 <1.a 2.9 0.73 J 4.0 1.8 2.0 0.77 2-Butanone (MEK) 78-93-3 4,000 <70 <10 <10 <2 <1.8 <1.8 12 <5 <5 15 <5 <5 <5 <5 <5.0 <5.0 <5.0 <10 <10 <5.0 <5.0 <5.0 <5.0 4-Methyl-2-pentanone (MIBK) 108-10-1 NS <10 <10 <10 <0.29 <0.29 <0.29 <2 <5 <5 <5 <5 <5 <5 <5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Acetone 67-64-1 6,000 <20 <20 <20 <6.7 3.1 J <1.6 3.8 J 5.9 <25 <25 <25 <25 <10 15.0 <10 <10 6.6 J <10 <10 <10 <10 2.2 J <10 Benzene 71-03-2 1 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <0.5 <1 <1 <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Bromodichdoromethane 75-27-4 0.6 <1 <1 <7 <0.23 <0.23 <0.23 <0.4 <1 <1 <1 <1 <1 <1 <7 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Carbon Disulfide 75-15-0 700 <1 <1 <7 <0.097 <0.45 <0.45 <0.4 <2 <2 <2 <2 <2 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0'+ c2.0 <2.0 <2.0 <2.0 Chloroform 67-66-3 70 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <2 <1 <1 <1 <1 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 0.86 JB <2.0 Dibromochloromethane 124-08-1 0.4 <1 <1 <1 <0.23 <0.23 <0.23 <0.4 <1 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0'+ <1.0 <1.0 <1.0 Tetrahydrofumn 109-99-9 NE 2,000 <5 <5 <5 <2 <0.57 5.6 2.7 J 6.5 J <10 <10 <10 <10 <10 <10 <10 <10 <10 2.8 J <10 <10 <10 2.3 JB <10 *- Toluene 108-88-3 600 <1 <l <7 <0.33 <0.24 <0.24 <0.4 <0.5 <1 <1 <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.30 J <0.50 <0.50 Vinyl chloride 75-01-4 0.03 <1 <1 <1 <0.054 <0.5 <0.5 <0.4 <0.5 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 '+ <1.0 <1.0 <1.0 <1.0 Appendix I Metals by EPA 6020&7470A01 101W Antimony 744036-0 1 <10 <10 <10 <6.6 <6.6 <6.6 <6.6 <3 <5 <5 <5 <5 <3 <3 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 "+ <3.0 <3.0 Arsenic 7440-38-2 10 <70 <10 <10 <2.2 8.6 J 5.1 J 6.1 J 4.4 <10 <10 <10 <10 6.3 1.6 7.4 0.82 J 6.4 0.94 J 5.7 2.1 8.6 B 2.2 3.8 Barium 7440-393 700 180 70.0 150 76.0 220 151 67.0 130 291 66.6 167 92.4 170 110 150 130 140 58.0 130 72.0 140 100 120 Beryllium 7440-01-7 4 <4 <4 <4 <0.22 <0.22 0.27 J <0.22 <1 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 ^1+ <1.0 <1.0 <1.0 <1.0 "+ <1.0 <1.0 Cadmium 7440-03-9 2 <2 <2 <2 <0.54 <0.54 <0.54 <0.54 <0.5 <1 <1 <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Calcium 7440-70-2 NE NE NS NS NS NS NS NS NS NS 90,800 NS 45,200 57,200 51,000 66,000 44,000 80,000 39,000 37,000 41,000 42,000 39,000 45,000 33,000 Chromium 7440-473 10 <5 <5 <5 <0.72 19.0 3.6 J 2.9 J 6.6 6.2 <5 <5 <5 1.2 J 2.2 J 1.5 J 2.3 J <5.0 <5.0 <5.0 2.5 J <5.0 1.7 J <5.0 Cobalt 7440-0Sd 1 <25 <25 <25 <1.3 12 J 3.2 J <1.3 10.0 8.7 8.6 <5 6.4 2.5 5.2 3.3 2.2 2.9 1 3.9 3.8 1.9 0.68 J Copper 7440-50-8 1,000 39.0 <5 <5 <1.8 <1.8 <1.8 <1.8 <2 <5 <5 <5 <5 0.6 J <2 1.7 J <2.0 0.62 J .0 1.7 J 0.72 J 0.69 J <2.0 Iron 7439-89-6 300 NS NS NS NS NS NS NS NS 8520 5560 2530 3500 1500 22.700 250 33500 1500 0 4500 2500 4500 2500 Lead 7439-92-1 15 <70 <10 <10 <4.7 <4.7 <4.7 c4.7 0.17 J <5 <5 <5 <5 0.38 BJ 0.31 J 0.87 0.20 J ^7+ 0.23 J J M<2.5<2250 1.0 B 0.53 0.39 J 0.43 J Manganese 7439-96-5 50 NS NS NS NS NS NS NS NS 9500 1560 3 550 6550 33.700 33 900 2�800 12�000 2500 0 1500 2500 2500 1500 Mercury 7439-97-6 1 <0.1 0.22 <0.1 <0.028 <0.028 0.052 J 0.055 BJ <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.20 <0.20 <0.20 0 <0.20 <0.20 <0.20 <0.20 Nickel 7440-02-0 100 <40 140 <40 <2.8 12 J 8.2 J <2.8 8.0 10.8 <5 5.1 <5 3.7 5.8 5.3 5.6 2.1 4.8 1.7 J 4.6 1.2 J Selenium 7782-49-2 20 <10 <10 <10 <8.5 <8.5 <8.5 <8.5 <2.5 <10 <10 <10 <10 <2.5 <2.5 <2.5 <2.5 <2.5 .5 <2.5 <2.5 1.0 J <2.5 Silver 7440-22-4 20 <5 <5 <5 <2.1 4.9 J <2.1 <2.1 <0.5 <5 <5 <5 <5 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Thallium 7440-28-0 2 NS NS NS NS NS NS NS NS NS <0.5 <0.1 <0.1 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Vanadium 7440-62-2 7 <50 <50 <50 <2.6 5.1 J <2.6 3.8 J <5 12.8 <5 <5 <5 <5 2.6 J 2.5 J <5.0 <5.0 <5.0 <5.0 4.6 J <5.0 <5.0 <5.0 Zinc 7440-6" 1,000 55.0 21.0 <20 <2.2 11 J 5.7 BJ 4.4 J <20 <10 <10 <10 <10 14.0 <10 <10 <10 <10 <15 <15 <10 <10 <10 Inorganic Indicator Parameters fug/LI Total Dissolved Solids by SM 2540C E1642222 500,000 NS NS 1 NS NS NS NS NS 1 100 000 960 000 592,000 538,000 814 000 540 000 880,000 440.000 770.000 390,000 610,000 450,000 660,000 400,000 700,000 380,000 Total Alkalinityas CaCO3 b SM 2320 E1640192 NE NE NS NS NS NS NS NS NS 690,000 651!000 204,000 329,000 375,000 320,000 380,000 250,000 ±70,000 270,000 180,000 290,000 290,000 240,000 260,000 200,000 Chloride b EPA 9056A 16887-00-6 250,000 NS NS NS NS NS NS NS 100,000 98,800 90,300 75,600 102,000 90,000 120,000 100,000 94,000 82,000 96,000 78,000 76,000 89,000 120,000 63,000 Sulfate b EPA 9056A 14808-79-8 250,000 NS NS NS NS NS NS NS 75,000 46,600 106,000 34,100 133,000 35,000 160,000 31,000 76,000 24,000 180,000 26,000 88,000 23,000 140,000 18,000 Notes: 1) 2L = North Carolina Department of Environmental Quality (NCDEQ) 15A NCAC 02L .0202 GV Levels (April 11, 2022). 2) IMAC = Intedm Maximum Allowable Concentration (Eff. 2013) 3) Mercury analyzed by EPA Method 7470A S = Shealy, P = Pace, TA = Eurofins TestAmerm NA = Not Analyzed; NS = Not Sampled; NE = Not Established J = Analyte detected at a level less than the RL and greater than or equal to the MDL. in this range are estimated. B = the analyte was detected in the assoc0ed blank H = Sample was prepped or analyzed beyond the specified holding time. -= LCS and/or LCSD is outside acceptance limits, low biased. "1+= Initial Calibration Verification (ICV) is outside acceptance lim0s, high biased. F1 = MS and/or MSD recovery exceeds control limits Bold and Underlined indicates result or reporting level exceeded the 2L Standard Bold indicates exceedance of IMAC when no 2L Standard is specified pg/L = micrograms per liter, mg/L = milligrams per liter Table 4 (Page 4 of 14) Greenway Waste Solutions of Apex, LLC Table 4 (Page 5 of 14) Summary of Historical Groundwater Analytical Detections Greenway Waste Solutions of Apex, LLC Highway 55 C&D Landfill Apex, North Carolina Sample ID CAS Number Screening Criteria n41V-5 Date 11/4/13 4/2/14 10/21/14 4/23/15 10/12/15 4/25/16 10/31/16 4/19/17 10/16/17 4/18/18 10/17/18 4/17/19 10/24/19 4/2/20 10/27/20 4/12/21 10/28/21 4/5/22 10/25/22 4/18/23 10/10/23 4/16/24 10/21/24 Analytical Laboratory 2L Standard"' IMAC a' S S S S S S S TA P P P P TA TA TA TA TA TA TA TA TA TA TA Appendix I VOCs by EPA 8260B fuall- 75-34-3 6 <1 <1 <1 <0.13 <0.19 <0.19 <0.4 <1 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,1-Dichloroethane 1,4-Dioxane 123-91-1 3 NS NS NS NS NS NS NS NS NS NS <2 <2 9.4 4.2 5.0 5.8 2.9 1.3 1.0 <1.0 <1.0 <1.0 0.37 J 2-Butanone (MEK) 78-93-3 4,000 <70 <10 <10 <2 <1.8 <1.8 12 <5 <5 15 <5 <5 <5 <5 <5.0 <5.0 <5.0 <10 <10 <5.0 <5.0 <5.0 <5.0 4-Methyl-2-pentanone (MIBK) 108-10-1 NS <10 <10 <10 <0.29 <0.29 <0.29 <2 <5 <5 <5 <5 <5 <5 <5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Acetone 67-64-1 6,000 <20 <20 <20 <6.7 <1.6 <1.6 <2 <5 <25 <25 <25 <25 3.6 J <10 <10 3.8 J 3.3 J <10 <10 <10 <10 <10 <10 Benzene 71-03-2 1 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <0.5 <1 <1 <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Bromodichdoromethane 75-27-4 0.6 <1 <1 <7 <0.23 <0.23 <0.23 <0.4 <1 <1 <1 <1 <1 <1 <7 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Carbon Disulfide 75-15-0 700 <1 <1 <7 <0.097 <0.45 <0.45 <0.4 <2 <2 <2 <2 <2 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0'+ <2.0 <2.0 <2.0 <2.0 Chloroform 67-66-3 70 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <2 <1 <1 <1 <1 0.86 J <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 0.86 JB <2.0 Dibromochloromethane 124-08-1 0.4 <1 <1 <1 <0.23 <0.23 <0.23 <0.4 <1 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0'+ <1.0 <1.0 <1.0 Tetrahydrofumn 109-99-9 NE 2,000 <5 <5 <5 <2 <0.57 <0.57 <1 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 *- Toluene 108-88-3 600 <1 <l <7 <0.33 <0.24 <0.24 <0.4 <0.5 <1 <1 <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Vinyl chloride 75-01-4 0.03 <1 <1 <1 <0.054 <0.5 <0.5 <0.4 <0.5 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 '+ <1.0 <1.0 <1.0 <1.0 Appendix I Metals by EPA 6020131747001 101W Antimony 744036-0 1 <10 <10 <10 <6.6 <6.6 <6.6 <6.6 <3 <5 <5 <5 <5 <3 <3 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 A+ <3.0 <3.0 Arsenic 7440-38-2 10 <70 <10 <10 <2.2 <2.2 3.3 J <2.2 0.30 J <10 <10 <10 <70 1.9 1.5 2.7 2.1 2.0 1.3 3.5 1.4 2.7 B 0.90 J 3.1 Barium 7440-393 700 140 65.0 130 56.0 50.0 50.0 41.0 82.0 121 51.4 40.9 96.2 140 200 180 200 130 84.0 110 53.0 78.0 48.0 59.0 Beryllium 7440-01-7 4 <4 <4 <4 <0.22 <0.22 <0.22 <0.22 <1 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 At+ <1.0 <1.0 <1.0 <1.0 A+ <1.0 <1.0 Cadmium 7440-03-9 2 <2 1 <2 <2 1 <0.54 <0.54 1 <0.54 <0.54 1 <0.5 <1 I <1 <1 <1 <0.5 <0.5 1 <0.50 <0.50 <0.50 <0.50 0.29 J <0.50 1 <0.50 <0.50 1 <0.50 Calcium 7440-70-2 NE NE NS NSJ6.7 NS NS NS NS NS 25,200 NS 7,350 26,200 42,000 50,000 60,000 67,000 42,000 47,000 32,000 14,000 14,000 B 28,000 21,000 Chromium 7440-473 10 5.3 <5 <0.72 1.1 J < 32 <0.72 <5 <5 <5 <5 <5 <5 <5 <5.0 <5.0 <5.0 <5.0 <5.0 2.7 J 1.7 J 1.1 J <5.0 Cobalt 7440-48-4 1 <25 <25 <1.3 1.3 J <1.3 <1.3 10.0 5.4 1.6 <5 12.4 17.0 8.0 22.0 20.0 20.0 13.0 7.0 4.3 2.8 2.3 5.0 Copper 7440-50-8 1,000 13.0 <5 <1.8 <1.8 <1.8 <1.8 <2 <5 <5 <5 <5 <2 <2 0.53 J <2.0 0.73 J <2.0 0.91 J 1.5 J 2.1 0.72 J 0.68 J Iron 7439-89-6 300 NS NS NS NS NS NS NS 10y00 1�60 2�70 6�80 14y00 15y00 28y00 26y00 26,000 15,000 8�00 5�00 7�00 3�00 8�00Lead 7439-92-1 15 <70 <10 <4.7 <4.7 <4.7 <4.7 <0.5 <5 <5 <5 <5 0.24 BJ <0.5 <0.50 <0.50 ^1+ 0.19 J <0.50 0.85 1.8 B 2.0 0.63 0.41 J Manganese 7439-96b 50 NS NS NS NS NS NS NS 1�00 321 501 2.540 5.000 3�700 7,400 7�00 2�00 4�00 2�00710 760 730 1�00Mercury 7439-97-6 1 <0.1 <0.1 <0.028 <0.028 <0.028 0.054 BJ <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.20 <0.20 <0.20 0.083 J <0.20 <0.20 <0.20 <0.20 <0.20 Nickel 7440-02-0 100 <40 <40 <40 <2.8 <2.8 <2.8 <2.8 1.3 J <5 <5 <5 <5 2.3 0.96 J 2.8 2.4 2.1 <2.0 1.8 J 1.3 J 1.4 J 0.73 J 0.74 J Selenium 7782-49-2 20 <70 <10 <10 <8.5 <8.5 <8.5 <8.5 <2.5 <10 <10 <10 <10 2.5 <2.5 <2.5 <2.5 <2.5 <2.5 1.3 J <2.5 <2.5 <2.5 <2.5 Silver 7440-22-4 20 <5 <5 <5 <2.1 <2.1 <2.1 <2.1 <0.5 <5 <5 <5 <5 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Thallium 7440-28-0 2 NS NS NS NS NS NS NS NS NS <0.5 <0.1 <0.1 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Vanadium 7440-62-2 7 <50 <50 <50 <2.6 <2.6 <2.6 <2.6 <5 <5 <5 <5 <5 5.0 <5 <5.0 <5.0 <5.0 <5.0 5.8 8.6 10.0 4.3 J 3.2 J Zinc 7440-66-6 1,000 10.0 <20 43.0 <2.2 8.4 J 3.1 BJ 6 J <20 <10 <10 <10 <10 11.0 <10 <10 <10 <10 <15 <15 7.0 J 9.9 J <10 Inorganic Indicator Parameters fun/1-1 Total Dissolved Solids by SM 2540C E1642222 500,000 NS NS NS NS NS NSaNSE200,000 218,000 100,000 105,000 216,000 420,000 360,000 530 000 500,000 400,000 290,000 260,000 250,000 190,000 170,000 150,000 Total Alkalinit as CaCO3 b SM 2320 E1640192 NE NE NSNS NSNS NS NS9,000 104,000 28,900 26,200 91,800 270,000 160,000 230,000 240,000 170,000 160,000 110,000 60,000 73,000 99,000 82,000 Chloride b EPA 9056A 16887-00-6 250,000 NS NS NS NS NS NS6,000 31,800 12,900 9,700 17,100 44,000 32,000 63,000 47000 43000 17,000 19,000 11,000 9,500 12,000 7,500 Sulfate b EPA 9056A 14808-79-8 250,000 NS NS NS NS NS NS4,000 33,400 18,300 17,400 25,600 97,000 57,000 130,000 160,000 100,000 69,000 58,000 25,000 27,000 25,000 15,000 Notes: 1) 2L = North Carolina Department of Environmental Quality (NCDEQ) 15A NCAC 02L .0202 GV Levels (April 11, 2022). 2) IMAC = Intedm Maximum Allowable Concentration (Eff. 2013) 3) Mercury analyzed by EPA Method 7470A S = Shealy, P = Pace, TA = Eurofins TestAmerm NA = Not Analyzed; NS = Not Sampled; NE = Not Established J = Analyte detected at a level less than the RL and greater than or equal to the MDL. in this range are estimated. B = the analyte was detected in the assoc0ed blank H = Sample was prepped or analyzed beyond the specified holding time. -= LCS and/or LCSD is outside acceptance limits, low biased. Al+= Initial Calibration Verification (ICV) is outside acceptance limits, high biased. F1 = MS and/or MSD recovery exceeds control limits Bold and Underlined indicates result or reporting level exceeded the 2L Standard Bold indicates exceedance of IMAC when no 2L Standard is specified pg/L = micrograms per liter, mg/L = milligrams per liter Table 4 (Page 5 of 14) Greenway Waste Solutions of Apex, LLC Table 4 (Page 6 of 14) Summary of Historical Groundwater Analytical Detections Greenway Waste Solutions of Apex, LLC Highway 55 C&D Landfill Apex, North Carolina Sample ID CAS Number Screening Criteria NIW-6 Date 11/4/13 4/2/14 10/21/14 4/23/15 10/12/15 4/25/16 10/31/16 4/19/17 10/16/17 4/18/18 10/17/18 4/17/18 10/24/19 4/2/20 10/27/20 4/12/21 10/28/21 4/5/22 10/25/22 4/19/23 10/10/23 4/16/24 5/23/24 10/21/24 Analytical Laboratory 2L Standard"' IMAC (�1 S S S S S S S TA P P P P TA TA TA TA TA TA TA TA TA TA TA TA Appendix I VOCs by EPA 8260B (uc/LI 75343 6 <1 <1 <1 <0.13 0.97 J <0.19 <0.4 <1 1.4 <1 <1 <1 1.9 <1 <1.0 <1.0 <1.0 <1.0 3.6 <1.0 4.3 <1.0 NS 0.62 J 1,1-Dichloroethane 1,4-Dioxane 123-91-1 3 NS NS NS NS NS NS NS NS NS NS <2 <2 1.2 <1 <1.0 <1.0 0.86 J <1.0 1.4 <1.0 3.2 <1.0 NS 0.92 2-Butanone (MEK) 78-93-3 4,000 <10 <10 <10 <2 <1.8 <1.8 <2 <5 <5 <5 <5 <5 <5 <5 <5.0 <5.0 <5.0 <10 <10 <5.0 <5.0 <5.0 NS <5.0 4-Methyl-2-pentanone (MIBK) 108-10-1 NS <10 <10 <10 <0.29 <0.29 <0.29 <2 <5 <5 <5 15 <5 <5 <5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NS <5.0 Acetone 67-64-1 6,000 <20 <20 <20 <6.7 <1.6 <1.6 <2 <5 <25 <25 <25 <25 1 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 NS <10 Benzene 71-03-2 1 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <0.5 <1 1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NS <0.50 Bromodichdoromethane 75-274 0.6 <1 <1 <1 <0.23 <0.23 <0.23 <0.4 <1 <7 7 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NS <1.0 Carbon Disu0ide 75-15-0 700 <1 <1 <1 <0.097 <0.45 2.7 <0.4 <2 <2 <2 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0" <2.0 <2.0 <2.0 NS <2.0 Chloroform 67-663 70 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <2 <1 t <1 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 0.96 JB NS <2.0 Dibromochloromethane 124-08-1 0.4 <1 <1 <1 <0.23 <0.23 <0.23 <0.4 <1 <1 H<212 1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 -+ <1.0 <1.0 NS <1.0 Tetmhydrofumn 109-99-9 NE 2,000 <5 <5 <5 <2 <0.57 <0.57 <1 <10 <10 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 NS <10'- Toluene 108-88-3 600 <1 <1 <1 <0.33 <0.24 <0.24 <0.4 <0.5 <l 1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.30 J <0.50 NS <0.50 Vin lhloride 75-01d 0.03 <1 <1 <1 <0.054 <0.5 <0.5 <0.4 <0.5 <1 1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 '+ <1.0 <1.0 <1.0 NS <1.0 Appendix I Metals by EPA 6020B/7470Ap1 fuolLl Antimony 7440-36-0 1 <10 <10 <10 <6.6 <6.6 <6.6 <6.6 <3 <5 <5 <5 <5 <3 <3 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 ^+ <3.0 NS <3.0 Arsenic 7440-38-2 10 <10 <10 <10 <2.2 3.5 J <2.2 3 J 9.7 <10 <10 <10 <10 3.9 0.64 J 0.48 J <1.0 1.9 <1.0 2.5 0.44 J 1.8 0.67 J NS 2.2 Barium 7440-39-3 700 62.0 75.0 36.0 <1.9 60.0 17 J 33.0 270 105 31.6 16.7 23.5 130 29.0 32.0 34.0 80.0 33.0 160 43.0 190 53.0 NS 120 Beryllium 7440-41-7 4 <4 <4 <4 <0.22 <0.22 0.24 J <0.22 0.58 J <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 ^1+ <1.0 <1.0 <1.0 <1.0 ^+ <1.0 NS <1.0 Cadmium 7440-43-9 2 <2 <2 <2 <0.54 <0.54 <0.54 <0.54 0.36 J <1 11 <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NS <0.50 Calcium 7440-70-2 NE NE NS NS NS NS NS NS NS NS 21,100 NS 3,650 5,120 30,000 7,800 8,600 F1 F2 9,000 19,000 9,000 44,000 11,000 48,000 12,000 NS 29,000 Chromium 7440-47-3 10 <5 <5 <5 <0.72 0.74 J <0.72 <0.72 3.8 J <5 <5 <5 <5 <5 <5 1.8 J <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NS <5.0 Cobalt 7440-48-4 1 <25 <25 <25 <1.3 <1.3 2.2 J 1.5 J 4.2 <5 0.43 <5 <5 18 15 0.42 J 0.86 J 0.83 J <1.0 0.40 J 0.97 J 0.41 J 0.73 J NS 1.6 Copper 7440-503 1,000 <5 <5 <5 <1.8 <1.8 <1.8 <1.8 8.9 <5 <5 <5 <5 0.69 J <2 0.76 J <2.0 0.66 J 1.6 J <2.0 0.68 J <2.0 6.1 NS <2.0 Iron 7439-89-6 300 NS NS NS NS NS NS NS NS 22.330 837 578 625 '1�00 340 420 360 800 78J 390 160 200 190 NS 350 Lead 7439-92-1 15 <10 <10 <10 <4.7 <4.7 <4.7 <4.7 21.0 <5 <5 <5 <5 0.63 B 0.2 J 0.32 J 0.22 J ^1+ 0.34 J <0.50 <0.50 0.50 B <0.50 <0.50 NS <0.50 Manganese 7439-96-5 50 NS NS NS NS NS NS NS NS 656 93.3 109 178 910 150 83.0 100 400 30.0 340 80.0 370 240 NS 480 Mercury 7439-97-6 1 <0.1 <0.1 <0.1 <0.028 <0.028 0.077 J 0.065 BJ <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 1.1 F1 <0.20 <0.20 Nickel 7440-02-0 100 <40 <40 <40 <2.8 <2.8 <2.8 <2.8 4.7 <5 <5 <5 <5 1.8 J 0.68 J 1.4 J <2.0 0.94 J <2.0 <2.0 0.89 J 0.96 J 0.67 J NS 0.98 J Selenium 7782-49-2 20 <10 <10 <10 <8.5 <8.5 <8.5 <8.5 <2.5 <10 <10 <10 <10 <2.5 <2.5 <2.5 <2.5 <2.5 < S <2.5 <2.5 <2.5 1 <2.5 NS <2.5 Silver 7440-22-4 20 <5 <5 <5 <2.1 <2.1 <2.1 <2.1 0.099 J <5 <5 <5 <5 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NS <0.50 Thallium 7440-28-0 2 NS NS NS NS NS NS NS NS NS <0.5 <0.1 <0.1 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 NS <2.0 Vanadium 7440-62-2 7 <50 <50 <50 <2.6 <2.6 <2.6 3.4 J 14.0 <5 <5 <5 15 15 15 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NS <5.0 Zinc 7440-66-6 1,000 <20 <20 <20 <2.2 4.1 J 6 BJ 191 38 B <10 <10 <10 <10 10.0 <10 <10 <10 <10 <15 <15 <10 <10 7.7 J NS <10 Inorganic Indicator Parameters (ua/L) Total Dissolved Solids b SM 2540C E1642222 500,000 NS NS NS NS NS NS NS 130,000 206,000 92,000 87,000 101,000 230,000 92,000 99,000 64,000 180,000 110,000 250,000 120,000 250,000 100,000 NS 210,000 Total Alkalinity as CaCO3 b SM 2320 E1640192 NE NE NS NS NS NS NS NS NS 11,000 108,000 <5,000 6,600 9,300 93,000 11,000 11,000 9,300 110,000 12,000 180,000 10,000 180,000 30,000 NS 100,000 Chloride b EPA 9056A 16887-00-6 250,000 NS NS NS NS NS NS NS 36,000 31,000 29,800 12,300 12,300 25,000 15,000 16,0110 45,000 26,000 19,000 32,000 16,000 41,000 20,000 NS 26,000 Sulfate b EPA 9056A 14808-79-8 250,000 NS NS NS NS NS NS NS 17,000 15,500 16,300 22,900 22,900 56,000 32,000 40,000 26,000 22,000 38,000 11,000 33,000 10,000 45,000 NS 28,000 Notes: 1) 2L = North Carolina Department of Environmental Quality (NCDEQ) 15A NCAC 02L .0202 GV Levels (April 11, 2022). 2) IMAC = Interim Maximum Allowable Concentration (Eff. 2013) 3) Mercury analyzed by EPA Method 7470A S = Shealy, P = Pace, TA = Eurofins TestAmerica NA = Not Analyzed; NS = Not Sampled; NE = Not Established J = Analyte detected at a level less than the RL and greater than or equal to the MDL. in this range are estimated. B = the analyte was detected in the associted blank H = Sample was prepped or analyzed beyond the specified holding time. - = LCS and/or LCSD is outside acceptance limits, low biased. ^1+= Initial Calibration Verification (ICV) is outside acceptance limits, high biased. F1 = MS and/or MSD recovery exceeds control limits Bold and Underlined indicates result or reporting level exceeded the 2L Standard Bold indicates exceedance of IMAC when no 2L Standard is specified pg/L = micrograms per liter, mg/L = milligrams per liter Table 4 (Page 6 of 14) Greenway Waste Solutions of Apex, LLC Table 4 (Page 7 of 14) Summary of Historical Groundwater Analytical Detections Greenway Waste Solutions of Apex, LLC Highway 55 C&D Landfill Apex, North Carolina Sample ID CAS Number Screening Criteria n41V-7 Date 11/4/13 4/2/14 10/21/14 4/23/15 10/12/15 4/25/16 10/31/16 4/19/17 10/16/17 4/18/18 10/17/18 4/17/19 10/24/19 4/2/20 4/12/21 10/28/21 4/5/22 10/25/22 4/19/23 10/9/23 4/16/24 10/22/24 Analytical Laboratory2L Standard') IMAC a) S S S S S S S TA P P P P TA TA TA TA TA TA TA TA TA TA Appendix I VOCs by EPA 8260B fuall- 75-34-3 6 <1 <1 <1 <0.13 <0.19 <0.19 <0.4 <1 <1 <1 <1 <1 1.9 <1 ;4.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,1-Dichloroethane 1,4-Dioxane 123-91-1 3 NS NS NS NS NS NS NS NS NS NS <2 <2 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 0.65 2-Butanone (MEK) 78-93-3 4,000 <70 <10 <10 <2 11.8 <1.8 12 <5 <5 15 <5 <5 <5 <5 <5.0 <5.0 <10 <10 <5.0 <5.0 <5.0 <5.0 4-Methyl-2-pentanone (MIBK) 108-10-1 NS <10 <10 <10 <0.29 <0.29 <0.29 <2 <5 <5 <5 <5 <5 <5 <5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Acetone 67-64-1 6,000 <20 <20 <20 <63 <1.6 <1.6 <2 <5 <25 <25 <25 <25 <10 <10 <10 6.5 J <10 <10 <10 <10 <10 Benzene 71-03-2 1 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <0.5 <1 <1 <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Bromodichdoromethane 75-27-4 0.6 <1 <1 <7 <0.23 <0.23 <0.23 <0.4 <1 <1 <1 <1 <1 <1 <7 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Carbon Disulfide 75-15-0 700 1.2 <1 <7 <0.097 <0.45 <0.45 <0.4 <2 <2 <2 <2 <2 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0'+ <2.0 M<2.O <2.0 <2.0 Chloroform 67-66-3 70 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <2 <1 <1 <1 <1 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 0.84 JB <2.0 Dibromochloromethane 124-08-1 0.4 <1 <1 <1 <0.23 <0.23 <0.23 <0.4 <1 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0'+<1.0 <1.0 Tetrahydrofumn 109-99-9 NE 2,000 <5 <5 <5 <2 <0.57 <0.57 <1 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 2.0 JB <10 *- Toluene 108-88-3 600 <1 <l <7 <0.33 <0.24 <0.24 <0.4 <0.5 <1 <1 <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.15 J <0.50 <0.50 Vinyl chloride 75-01-4 0.03 <1 <1 <1 <0.054 <0.5 <0.5 <0.4 <0.5 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 '+ <1.0 <1.0 <1.0 <1.0 Appendix I Metals by EPA 6020131747001 101W Antimony 744036-0 1 <10 <10 <10 <6.6 <6.6 <6.6 16.6 <3 <5 <5 <5 <5 <3 <3 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 A+ <3.0 <3.0 Arsenic 7440-38-2 10 11.0 <10 <10 19.0 81 6.6 J 4.6 J 3.6 <10 <10 <10 <10 2.1 3.5 1.2 0.91 J 1.0 5.9 4.3 3.2 4.1 0.95 J 1.7 Barium 7440-393 700 180 60.0 40.0 80.0 98.0 62.0 94.0 61.0 78.5 51.8 54.8 49.8 81.0 48.0 120 62.0 100 39.0 81.0 40.0 61.0 34.0 77.0 Beryllium 7440-01-7 4 <4 <4 14 <0.22 <0.22 <0.22 <0.22 <1 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 A1+ <1.0 <1.0 <1.0 <1.0 A+ <1.0 <1.0 Cadmium 7440-03-9 2 <2 1 <2 1 <2 <0.54 <0.54 <0.54 <0.54 <0.5 <1 <1 <1 I <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 1 <0.50 <0.50 1 <0.50 <0.50 <0.50 Calcium 7440-70-2 NE NE NS NS NS NS NS NS NS NS 96,500 NS 44,000 46,100 110,000 55,000 66,000 57,000 110,000 32,000 95,000 33,000 78,000 18,000 55,000 Chromium 7440-473 10 11.0 <5 <5 <0.72 2.8 J <0.72 <0.72 <5 <5 <5 <5 <5 <5 <5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Cobalt 7440-48-4 1 <25 <25 <25 <1.3 1.5 J <1.3 <1.3 1.3 <5 1.2 <5 <5 <1 0.99 J 2.3 <1.0 0.50 J 1.4 <1.0 1.3 <1.0 1.3 1.3 Copper 7440-50-8 1,000 35.0 <5 5.2 <1.8 5.2 <1.8 8.7 J 1.0 J <5 <5 <5 <5 <2 <2 <2.0 <2.0 1.3 J <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Iron 7439-89-6 300 NS NS NS NS NS NS NS NS 1�80 1�30 1�80 1�20 950 1�00 22.100 1�00 1�00 4�00 1�00 2�00 1�00 1�00 1�00 Lead 7439-92-1 15 28.0 <10 <10 <4.7 <4.7 <4.7 <4.7 0.41 J <5 <5 <5 <5 0.44 BJ <0.5 <0.50 <0.50 A1+ <0.50 <0.50 <0.50 0.26 JB <0.50 <0.50 <0.50 Manganese 7439-96-5 50 NS NS NS NS NS NS NS NS 450 272 237 340 710 440 1,400 580 1�00 330 880 280 650 130 500 Mercury 7439-97-6 1 <0.1 <0.1 <0.1 <0.028 <0.028 <0.028 0.059 BJ <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 0.25 <0.20 Nickel 7440-02-0 100 <40 <40 <40 <2.8 <2.8 <2.8 <2.8 1.2 J 15 <5 <5 <5 0.68 J 1 J 3.7 <2.0 1.1 J 1.8 J <2.0 1.9 J <2.0 1.5 J 4.1 Selenium 7782-49-2 20 <70 <10 <10 <8.5 <8.5 <8.5 <8.5 NS <10 <10 <10 <10 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 Silver 7440-22-4 20 <5 <5 <5 <2.1 <2.1 <2.1 <2.1 NS <5 <5 <5 <5 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Thallium 7440-28-0 2 NS NS NS NS NS NS NS NS NS <0.5 <0.1 <0.1 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Vanadium 7440-62-2 7 <50 <50 <50 <2.6 4.4 J <2.6 5 J <5 <5 <5 <5 <5 <5 <5 -5.0 <5.0 <5.0 3.1 J <5.0 <5.0 <5.0 <5.0 <5.0 Zinc 7440-66-6 1,000 92.0 <20 670 <2.2 17 J 7.2 BJ 34.0 <20 <10 <10 <10 <10 8.6 J <10 <10 <10 <10 <15 <15 <111 <10 <10 Inorganic Indicator Parameters fug/LI Total Dissolved Solids by SM 2540C E1642222 500,000 NS NS NS NS NS NS NS 390,000 474,000 332,000 289,000 264,000 470,000k8E[ 530 000 190,000 440,000 190,000 500,000 300,000 330,000 170,000 360,000 Total Alkalinityas CaCO3 b SM 2320 E1640192 NE NE NS NS NS NS NS NS NS 170,000 249,000 145,000 129,000 129,000 270,000 190,000 140,000 180,000 71,000 230,000 97,000 220,000 38,000 140,000 Chloride by EPA 9056A 16887-00-6 250,000 NS NS NS NS NS NS NS 42,000 63,100 42,300 21,900 14,600 88,000 22,000 96,000 28,000 43,000 18,000 55,000 13,000 34,000 12,000 42,000 Sulfate b EPA 9056A 14808-79-8 250,000 NS NS NS NS NS NS NS 74,000 73,300 66,300 39,900 57,300 42,000 36,000 130,000 62.000 180,000 64,000 140,000 50,000 40,000 65,000 67,000 Notes: 1) 2L = North Carolina Department of Environmental Quality (NCDEQ) 15A NCAC 02L .0202 GV Levels (April 11, 2022). 2) IMAC = Intedm Maximum Allowable Concentration (Eff. 2013) 3) Mercury analyzed by EPA Method 7470A S = Shealy, P = Pace, TA = Eurofins TestAmerm NA = Not Analyzed; NS = Not Sampled; NE = Not Established J = Analyte detected at a level less than the RL and greater than or equal to the MDL. in this range are estimated. B = the analyte was detected in the assoc0ed blank H = Sample was prepped or analyzed beyond the specified holding time. -= LCS and/or LCSD is outside acceptance limits, low biased. Al+= Initial Calibration Verification (ICV) is outside acceptance limits, high biased. F1 = MS and/or MSD recovery exceeds control limits Bold and Underlined indicates result or reporting level exceeded the 2L Standard Bold indicates exceedance of IMAC when no 2L Standard is specified pg/L = micrograms per liter, mg/L = milligrams per liter Table 4 (Page 7 of 14) Greenway Waste Solutions of Apex, LLC Table 4 (Page 8 of 14) Summary of Historical Groundwater Analytical Detections Greenway Waste Solutions of Apex, LLC Highway 55 C&D Landfill Apex, North Carolina Sample ID CAS Number Screening Criteria NIW 8 Date 11/4/13 4/2/14 10/21/14 4/23/15 10/12/15 4/25/16 10/31/16 10/31/16 4/20/17 6/15/17 10/16/17 10/16/17 4/18/18 4/18/18 10/17/18 10/17/18 10/17/18 4/17/19 4/17/19 4/17/19 10/24/19 10/24/19 10/24/19 4/3/20 4/3/20 4/3/20 Analytical Laboratory 2L Standard(' IMAC t2' S S S S S S S S TA TA P TA split P P (DUP) P P (DUP) TA split P P (DUP) TA split TA TA Du P split TA TA Du P split Appendix I VOCs by EPA 8260B (po/L) 75343 6 <1 <1 <1 <0.13 <0.19 <0.19 <0.4 <0.4 <t <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <t <1 <1 <1 <1 <1 <1.0 1,1-Dichloroethane 1,4-Dioxane 123-91-1 3 NS NS NS NS NS NS NS NS NS NS NS NS NS NS <2 <2 1.5 <2 <2 11 2.4 2.8 <2 1.9 2.2 <2.0 2-Butanone (MEK) 78-93-3 4,000 <10 <10 <10 12 <1.8 <1.8 <2 <2 <5 <5 <5 <5 15 15 15 <5 15 <5 <5 <5 <5 <5 <5 15 15 <5.0 4-Methyl-2-pentanone (MIBK) 108-10-1 NS <10 <10 <10 <0.29 <0.29 <0.29 <2 <2 <5 <5 <5 1 15 <5 1 <5 <5 <5 <5 <5 <5 <5 <5 1 <5 <5 1 <5 <5 <5.0 Acetone 67-64-1 6,000 <20 <20 <20 <6.7 <1.6 <1.6 <2 <2 <5 <5 <25 <5 <25 <25 <25 <25 3.5 J <25 <25 13.0 <10 <10 <25 2.4 J 1.9 J <25 Benzene 7143-2 1 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <0.4 <0.5 <0.5 <1 <0.5 <1 <1 <1 <1 0.19 J <1 <1 0.27 J 0.27 J <0.5 <1 0.24 J 0.26 J <1.0 Bromodichdoromethane 75-274 0.6 <1 <1 <1 <0.23 <0.23 <0.23 <0.4 <0.4 <1 <7 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <7 <7 <7 <1 <1.0 Carbon Disuffide 75-15-0 700 <1 <1 <1 <0.097 <0.45 <0.45 <0.4 <0.4 <2 12 <2 12 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2.0 Chloroform 67-663 70 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <0.4 12 <2 <1 <2 <1 <1 <1 <1 <2 <1 <1 <2 <2 <2 <5 <2 <2 <5.0 Dibromochloromethane 12448-1 0.4 <1 <1 <1 <0.23 <0.23 <0.23 <0.4 <0.4 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1.0 Tetmhydrofumn 109-99-9 NE 2,000 <5 15 15 <2 <0.57 <0.57 <1 <1 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 4.4 J 3.9 J <10 4 J 3.7 J <10 Toluene 108-88-3 600 <1 <1 <1 <0.33 <0.24 <0.24 <0.4 <0.4 <0.5 <0.5 <1 <0.5 <1 <1 <1 <1 <0.5 -1 <1 <0.5 <0.5 <0.5 <1 <0.5 <0.5 <1.0 Vinyl chloride 75-014 0.03 4.1 <1 5.3 <0.054 <0.5 <0.5 2.8 2.8 4.2 <0.5 <1 <0.5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1.0 Appendix I Metals by EPA 60206/7470A01 Ipa/L1 Antimony 744036-0 1 <10 <10 <10 <6.6 <6.6 <6.6 <6.6 <6.6 <3 NS <5 NS <5 NS <5 NS NS <5 NS NS <3 NS NS <3 NS NS Arsenic 7440-38-2 10 21.0 <10 <10 <2.2 8.4 J 3 J <2.2 <2.2 1.8 NS <10 NS <10 NS <10 NS NS <10 NS NS 1.2 NS NS 2.8 NS NS Barium 7440-39-3 700 550 48.0 <25 29.0 160 43.0 20 J 20 J 70.0 NS 91.1 NS 70.2 NS 76.0 NS NS 84.1 NS NS 77.0 NS NS 83.0 NS NS Beryllium 744041-7 4 <4 <4 <4 <0.22 0.26 J <0.22 <0.22 <0.22 <1 NS <1 NS <1 NS <1 NS NS <1 NS NS <1 NS NS <1 NS NS Cadmium 744043-9 2 <2 <2 <2 <0.54 <0.54 1 <0.54 <0.54 <0.54 <0.5 NS <1 NS <1 NS <1 NS NS <1 NS NS 0.50 NS NS <0.5 NS NS Calcium 7440-70-2 NE NE NS NS NS NS NS NS NS NS NS NS 46,400 NS NS NS 47,300 NS NS 60,200 NS NS 61,000 NS NS 67,000 NS NS Chromium 744047-3 10 <5 <5 <5 <0.72 8.1 <0.72 <0.72 <0.72 <5 NS <5 NS <5 NS <5 NS NS <5 NS NS <5 NS NS <5 NS NS Cobalt 7440484 1 <25 <25 <25 <1.3 6.9 J 2.2 J <1.3 <1.3 1.8 NS <5 NS US NS <5 NS NS <5 NS NS <1.2 NS NS Li NS NS Copper 744050-8 1,000 15.0 6.0 <5 <1.8 11.0ENS <1.8 <1.8 1.3 J NS <5 NS <5 NS <5 NS NS <5 NS NS 0.65 J NS NS <2 NS NS Iron 7439-89-6 300 NS NS NS NS NS NS NS NS NS 8 230NS 1�10 NS 2�20 NS NS 3�90 NS NS 390 NS NS 2�00 NS NS Lead 7439-92-1 15 <10 <10 <10 <4.7 7.6 J <4.7 <4.7 0.54 NS <5 NS <5 NS <5 NS NS --NS NS 0.2 BJ NS NS <0.5 NS NS Manganese 7439-965 50 NS NS NS NS NS NS NS NS NS 967 NS 533 NS 670 NS NS 504 NS NS 230 NS NS 250 NS NS Mercury 7439-97-6 1 <0.1 <0.1 <0.1 <0.028 <0.0280.067 BJ 0.067 BJ <0.2 NS <0.2 NS <0.2 NS <0.2 NS NS <0.2 NS NS <0.2 NS NS <0.2 NS NS Nickel 7440-02-0 100 <40 <40 <40 <2.8 7.3 J <2.8 <2.8 3.2 NS 5.5 NS <5 NS <5 NS NS <5 NS NS 3.5 NS NS 3.8 NS NS Selenium 778249-2 20 <10 <10 <10 <8.5 <8.5 <8.5 <8.5 NS NS <10 NS <10 NS <10 NS NS <10 NS NS <2.5 NS NS <2.5 NS NS Silver 7440-224 20 <5 <5 <5 <2.1 <2.1 . <2.1 <2.1 NS NS <5 NS <5 NS <5 NS NS <5 NS NS <0.5 NS NS <0.5 NS NS Thallium 7440-28-0 2 NS NS NS NS NS NS NS NS NS NS NS NS <0.5 NS <0.1 NS NS <0.1 NS NS <2 NS NS <2 NS NS Vanadium 7440-62-2 7 -50 <50 <50 <2.6 23 J <2.6 <2.6 <2.6 2.0 J NS 8.3 NS 15 NS 15 NS NS <5 NS NS <5 NS NS 3.3 J NS NS Zinc 7440-665 1,000 28.0 37.0 <20 <2.2 38.0 7.8 BJ <2.2 <2.2 <20 NS 15.0 NS <10 NS <10 NS NS <10 NS NS 31.0 NS NS <10 NS NS Inorganic Indicator Parameters (uall- Total Dissolved Solids by SM 2540C E1642222 500,000 IN NS NS NS NS NS NS NS 470,000 NS 472,000 NS 430,000 NS 428,000 IN NS 475,000 NS NS 540,000 NS NS 630 000 NS NS Total Alkalinityas CaCO3 b SM 2320 E1640192 NE NE NS NS NS NS NS NS NS NS 250,000 NS 265,000 NS 273,000 NS 244,0002 NS NS 295,W0 NS NS 430,000 NS NS 330,000 NS NS Chloride b EPA 9056A 16887-00-6 250,000 NS NS NS NS NS NS NS NS 93,000 NS 89,000 NS 104,000 NS 78,700 NS NS 86,700 NS NS 96,000 NS NS 88,000 NS NS ,Sulfate by EPA 9056A 14808-793 250,000 NS NS NS NS NS NS NS NS 26,000 NS 21,800 NS 21,300 NS 23,800 NS NS 24,300 NS NS 34,000 NS NS 38,000 NS NS Notes: 1) 2L = North Carolina Department of Environmental Quality (NCDEQ) 15A NCAC 02L .0202 GV Levels (April 11, 2022). 2) IMAC = Interim Maximum Allowable Concentration (Eff. 2013) 3) Mercury analyzed by EPA Method 7470A S = Shealy, P = Pace, TA = Eurofins TestAmerica NA = Not Analyzed; NS = Not Sampled; NE = Not Established J = Analyte detected at a level less than the RL and greater than or equal to the MDL. in this range are estimated. B = the analyte was detected in the associted blank H = Sample was prepped or analyzed beyond the specified holding time. - = LCS and/or LCSD is outside acceptance limits, low biased. "1+= Initial Calibration Verification (ICV) is outside acceptance limits, high biased. F1 = MS and/or MSD recovery exceeds control limits Bold and Underlined indicates result or reporting level exceeded the 2L Standard Bold indicates exceedance of IMAC when no 2L Standard is specified pg/L = micrograms per liter, mg/L = milligrams per liter Table 4 (Page 8 of 14) Greenway Waste Solutions of Apex, LLC Table 4 (Page 9 of 14) Summary of Historical Groundwater Analytical Detections Greenway Waste Solutions of Apex, LLC Highway 55 C&D Landfill Apex, North Carolina Sample ID CAS Number Screening Criteria MW-8 (cont.) Date 10/27/20 10/27/20 10/27/20 4/12/21 4/12/21 4/12/21 10/28/21 10/28/21 10/28/21 4/5/22 4/5/22 4/5/22 10/26/22 10/26/22 10/26/22 4/19/23 4/19/23 4/19/23 10/9/23 10/9/23 10/9/23 4/16/24 4/16/24 4/16/24 10/22/24 10/22/24 10/22/24 Analytical Laboratory 2L Standard" IMAC 121 TA TA Du P split TA TA Du P split TA TA Du P split TA TA Du P split TA TA Du P split TA TA Du P split TA TA Du P split TA TA Du P split TA TA Du P split Appendix I VOCs by EPA 8260B fug/LI 75-343 6 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,1-Dichloroethane 1,4-Dioxane 123-91-1 3 1.0 0.99 J 2.3 2.6 2.5 3.8 - 2.3 <1.0 3.9 - <1.0 1.3 3.9 - 3.1 - 3.6 - 4.4 - 4.0 - 4.0 - 3.0 4.7 - 5.6 - 6.1 - 2.8 3.7 - 5.3 - 3.1 - 2.8 5.1 - 2-Bulanone (MEK) 78-933 4,000 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <10 <10 <5.0 <10 <10 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 4-Methyl-2-pentenone (MIBK) 108-10-1 NS <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Acetone 67-64-1 6,000 3.7 J <10 <25 20.0 9.9 J <25.0 4.9 J 9.0 J <25.0 <10 <10 <25.0 <10 <10 <25.0 <10 6.4 JB <25.0 2.1 J 3.9 J <25.0 <10 1.7 J <25.0 <10 <10 1 <25.0 Benzene 7143-2 1 0.37 J 0.44 J <1.0 0.50 0.51 <1.0 <0.50 <0.50 <1.0 0.67 0.56 1 <1.0 0.38 J 0.42 J <1.0 0.77 0.68 <1.0 0.37 J 0.36 J <1.0 0.73 0.97 <1.0 0.93 0.84 <1.0 Bromodichdoromethane 75-274 0.6 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Carbon Disulfide 75-15-0 700 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Chloroform 67-663 70 <2.0 <2.0 <5.0 <2.0 <2.0 <5.0 <2.0 <2.0 <5.0 <2.0 <2.0 <1.0 <2.0 <2.0 <1.0 0.82 J <2.0 <1.0 <2.0 <2.0 <1.0 0.74 JB 0.85 JB <1.0 <2.0 <2.0 <1.0 Dibromochloromethane 12448-1 0.4 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 *+ <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Tetrahydrofuran 109-99-9 NE 2,000 7.0 J 7.2 J <10 8.2 J 8.5 J <10.0 16.0 15.0 <10.0 13.0 11.0 <10.0 8.2 J 8.7 J 11.5 <10 4.6 J <10.0 <10 <10 <10 4.1 JB 5.4 JB <10 <10 *- <10 *- <10 Toluene 108-883 600 <0.50 <0.50 <1.0 <0.50 <0.50 <1.0 <0.50 <0.50 <1.0 <0.50 <0.50 <1.0 <0.50 <0.50 <1.0 <0.50 <0.50 <1.0 0.25 J 0.25 J <1.0 <0.50 <0.50 <1.0 <0.50 <0.50 <1.0 Vinyl chloride 75-014 0.03 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Appendix I Metals by EPA 6020B17470A1a1 /L Antimony 744036-0 1 <3.0 NS NS <3.0 NS NS <3.0 NS NS <3.0 NS NS <3.0 NS NS <3.0 NS NS <3.0 A. NS NS <3.0 NS NS <3.0 NS NS Arsenic 7440-38-2 10 2.7 NS NS 1.8 NS NS 2.6 NS NS 2.1 NS NS 1.6 NS NS 3.0 NS NS 2.8 B NS NS 2.5 NS NS 3.0 NS NS Barium 744039-3 700 110 NS NS 110 NS NS 120 NS NS 130 NS NS 110 NS NS 120 NS NS 140 NS NS 140 NS NS 150 NS NS Beryllium 744041-7 4 <1.0 NS NS <1.0 NS NS <1.0 -1 NS NS <1.0 NS NS <1.0 NS NS <1.0 NS NS <1.0 A+ NS NS <1.0 NS NS <1.0 NS NS Cadmium 744043-9 2 <0.50 NS NS <0.50 NS NS <0.50 NS NS <0.50 NS NS <0.50 NS NS <0.50 NS NS <0.50 NS NS <0.50 NS NS <0.50 NS NS Calcium 7440-70-2 NE NE 79,000 NS NS 84,000 NS NS 93,000 NS NS 100,000 NS NS 100,000 NS NS 92,000 NS NS 110,000 B NS NS 110,000 NS NS 120,000 NS NS Chromium 744047-3 10 1.4 J NS NS 1.9 J NS NS 2.0 J NS NS <5.0 NS NS <5.0 NS NS 2.1 J NS NS 2.0 J NS NS 2.4 J NS NS 2.2 J NS NS Cobalt 7440484 1 1.9 NS NS 1.6 NS NS 1.9 NS NS 1.7 NS NS 1.8 NS NS 2.1 NS NS 1.8 NS NS 2.1 NS NS 2.0 NS NS Copper 744050-8 1,000 1.2 J NS NS 1.0 J NS NS <2.0 NS NS <2.0 NS NS <2.0 NS NS 0.59 J NS NS <2.0 NS NS 0.66 J NS NS <2.0 NS NS Iron 7439-89-6 300 3�00 NS NS 22.000 NS NS 3�00 NS NS 1�00 NS NS 600 NS NS 33.000 NS NS 1�00 NS NS 2�00 NS NS 2�00 NS NS Lead 7439-92-1 15 <0.50 NS NS 0.27 J "1+ NS NS <0.50 NS NS <0.50 NS NS <0.50 NS NS 0.51 B NS NS <0.50 NS NS <0.50 NS NS <0.50 NS NS Manganese 7439-96-5 50 380 NS NS 330 NS NS 390 NS NS 420 NS NS 430 NS NS 500 NS NS 560 NS NS 580 NS NS 600 NS NS Mercury 7439-97-6 1 <0.20 NS NS <0.20 NS NS <0.20 NS NS <0.20 NS NS <0.20 NS NS <0.20 NS NS <0.20 NS NS 0.078 J NS NS <0.20 NS NS Nickel 7440-02-0 100 4.8 NS NS 5.3 NS NS 6.6 NS NS 7.3 NS NS 7.5 NS NS 6.8 NS NS 8.6 NS NS 8.2 NS NS 8.8 NS NS Selenium 778249-2 20 <2.5 NS NS <2.5 NS NS <2.5 NS NS <2.5 NS NS <2.5 NS NS <2.5 NS NS <2.5 NS NS <2.5 NS NS <2.5 NS NS Silver 7440-224 20 <0.50 NS NS <0.50 NS NS <0.50 NS NS <0.50 NS NS <0.50 NS NS <0.50 NS NS <0.50 NS NS <0.50 NS NS <0.50 NS NS Thallium 7440-28-0 2 <2.0 NS NS <2.0 NS NS <2.0 NS NS <2.0 NS NS <2.0 NS NS <2.0 NS NS <2.0 NS NS <2.0 NS NS <2.0 NS NS Vanadium 7440-62-2 7 <5.0 NS NS <5.0 NS NS <5.0 NS NS <5.0 NS NS <5.0 NS NS <5.0 NS NS <5.0 NS NS <5.0 NS NS <5.0 NS NS Zinc 7440-66-6 1,000 <10 NS NS <10 NS NS <10 NS NS <15 NS NS <15 NS NS 11.0 NS NS <10 NS NS <10 NS NS <10 NS NS Inorganic Indicator Parameters (ug/Li Total Dissolved Solids by SM 2540C 1 E1642222 500,000 620,000 NS NS 1,500,000 NS NS 730 000 NS NS 750,000 NS NS 780 000 NS NS 660 000 NS NS 880,000 NS NS 830,000 NS NS 880 000 NS NS Total Alkalinity as CaCO3 by SM 2320 E1640192 NE NE 360,000 NS NS 400,000 NS NS 470,000 NS NS 450,002 NS NS 490,000 *- NS NS 400,000 NS NS 510,000 NS NS 510,000 NS NS 510,000 NS NS Chloride b EPA 9056A 16887-00-6 250,000 120,000 NS NS 100,000 NS NS 95,000 NS NS 100,000 NS NS 97,000 NS NS 79,000 NS NS 130,000 NS NS 100,000 NS NS 98,000 NS NS Sulfate b EPA 9056A 14808-79-8 250,000 59,000 NS NS 67,000 NS NS 72,000 NS NS 72,000 NS NS 73,000 NS NS 53,000 NS NS 83,000 NS NS 73,000 NS NS 66,000 NS NS Notes: 1) 21 = North Carolina Department of Environmental Quality (NCDEQ) 15A NCAC 02L .0202 GV Levels (April 11, 2022). 2) IMAC = Interim Maximum Allowable Concentration (Eff. 2013) 3) Mercury analyzed by EPA Method 7470A S = Shealy, P = Pace, TA = Eurofins TestAmerica NA = Not Analyzed; NS = Not Sampled; NE = Not Established J = Analyte detected at a level less than the RL and greater than or equal to the MDL. in this range are estimated. B = the analyte was detected in the associted blank H = Sample was prepped or analyzed beyond the specified holding time. -= LCS and/or LCSD is outside acceptance limits, low biased. Al+= Initial Calibration Verification (ICV) is outside acceptance limits, high biased. F1 = MS and/or MSD recovery exceeds control limits Bold and Underlined indicates result or reporting level exceeded the 2L Standard Bold indicates exceedance of IMAC when no 2L Standard is specified pg/L = micrograms per liter; mg/L = milligrams per liter Table 4 (Page 9 of 14) Greenway Waste Solutions of Apex, LLC Table 4 (Page 10 of 14) Summary of Historical Groundwater Analytical Detections Greenway Waste Solutions of Apex, LLC Highway 55 C&D Landfill Apex, North Carolina Sample ID CAS Number Screening Criteria MN-9 Date 11/4/13 4/2/14 10/21/14 4/23/15 10/12/15 4/25/16 10/31/16 4/19/17 10/16/17 4/18/18 4/18/18 6/19/18 10/17/18 4/17/19 10/24/19 4/3/20 10/27/20 4/13/21 10/28/21 4/5/22 10/26/22 12/8/22 4/19/23 6/8/23 10/9/23 12/14/23 4/17/24 5/30/24 10/22/24 12/5/24 Analytical Laboratory 2L Standard"' IMAC i�1 S S S S S S S TA P P P (1)ND P P P TA TA TA TA TA TA TA TA TA TA TA TA TA TA TA TA Appendix I VOCs by EPA 8260B (ug/L) 75-34-3 6 <1 <1 <1 <0.13 <0.19 <0.19 <0.4 <1 <1 <1 NS NS <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,1-Dichloroethane 1,4-0ioxane 123-91-1 3 NS NS NS NS NS NS NS NS NS NS NS NS 3.5 6.1 3.8 3.3 3.4 5.8 4.8 <1.0 *3 6.8 11.0 13.0 NA 12.0 NS 12.0 NS 11.0 NS 2-Butanone (MEK) 78-93-3 4,000 <10 <10 <10 <2 <1.8 <1.8 <2 <5 <5 <5 NS NS <5 <5 <5 <5 <5.0 <5.0 <5.0 <10 <10 <10 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 4-Methyl-2-pentanone (MIBK) 108-10-1 NS <10 <10 <10 <0.29 <0.29 <0.29 <2 <5 <5 <5 NS NS <5 15 <5 <5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Acetone 67-64-1 6,000 <20 <20 1 <20 <6.7 <1.6 <1.6 <2 <5 <25 <25 NS NS <25 <25 1 7.1 J <10 <10 <10 5.0 J <10 <10 <10 <10 4.9 J 1.9 J 9.2 JB 2.9 J <10 <10 <10 Benzene 71-03-2 1 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <0.5 <1 <1 NS NS <1 <1 0.43 J 0.44 J 0.63 0.69 0.69 1.1 1.1 1.1 1.5 1.2 1.4 1.8 1.5 1.4 1.3 1.3 Bromodichdoromethane 75-27-4 0.6 <1 <7 <1 <0.23 <0.23 <0.23 <0.4 <1 <1 <1 NS NS <1 <7 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Carbon Disulfide 75-15-0 700 <1 <7 <1 <0.097 <0.45 <0.45 <0.4 <2 <2 <2 NS NS <2 12 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Chloroform 67-66-3 70 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <2 <1 <1 NS NS <1 <1 0.85 J <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 0.45 JB 0.79 JB <2.0 <2.0 <2.0 Dibromochloromethane 124-08A 0.4 <1 <1 <1 <0.23 <0.23 <0.23 <0.4 <1 <1 <1 NS NS <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 *+ <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Tetrahydrofuran 109-99-9 NE 2,000 <5 <5 15 12 <0.57 <0.57 <1 <10 <10 <10 NS NS <10 <10 2.6 J <10 <10 <10 <10 3.5 J 2.9 J 6.0 J <10 14.0 4.1 J 5.4 J 7.4 JB 13.0 <10 *- 11.0 Toluene 108-88-3 600 <1 <l <1 <0.33 <0.24 <0.24 <0.4 <0.5 <1 <1 NS NS <1 <1 0.36 J 0.22 J 0.43 J <0.50 0.24 J <0.50 <0.50 <0.50 <0.50 0.19 J 0.35 J 0.37 J 0.33 J 0.23 J 0.29 J <0.50 Vinyl chloride 75-01-4 0.03 <1 <t <1 <0.054 <0.5 <0.5 <0.4 <0.5 <1 <t NS NS <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Appendix I Metals by EPA 6020B/7470AI31 (up/L1 Antimony 744036-0 1 <10 <10 <10 <6.6 <6.6 <6.6 <6.6 <3 <5 <5 <5 <1 <5 <5 <3 <3 <3.0 <3.0 <3.0 <3.0 <3.0 NS <3.0 NS <3.0 ^+ NS <3.0 NS <3.0 NS Arsenic 7440-38-2 10 10.0 <10 <10 <2.2 3.4 J 3.1 J <2.2 2.3 <10 <10 <10 2.6 <10 <10 6.1 7.2 6.3 5.7 6.1 7.4 8.6 NS 9.2 NS 7.7 NS 8.3 NS 8.1 NS Barium 7440-393 700 310 180 400 210 310 170 320 360 601 414 267 214 906 922 830 960 980 1000 940 1 000 910 NS 1,100 NS 1,100 NS 1000 NS 1i00 NS Beryllium 7440-01-7 4 <4 <4 <4 <0.22 <0.22 0.22 J <0.22 <1 <1 <1 <1 <0.1 <1 <1 <1 <1 <1.0 <1.0 <1.0 Al, <1.0 <1.0 NS <1.0 NS <1 .0 A+ NS <1.0 NS <1.0 NS Cadmium 7440-03-9 2 <2 <2 <2 <0.54 <0.54 <0.54 <0.54 <0.5 <1 <1 <1 <0.1 <1 <1 <0.5 <0.5 1 <0.50 <0.50 <0.50 <0.50 <0.50 NS <0.50 NS <0.50 NS <0.50 NS <0.50 NS Calcium 7440-70-2 NE NE NS NS NS NS NS NS NS NS 75,600 NS NS NS 95,000 104,000 100,000 110,000 100,000 100,000 99,000 110,000 100,000 NS 110,000 NS 110,000 NS 120,000 NS 130,000 NS Chromium 7440-47-3 10 9.7 15 10.0 <0.72 4.1 J <0.72 1.2 J <5 <5 <5 <5 <7 <5 <5 <5 1.9 J <5.0 <5.0 <5.0 <5.0 2.9 J NS 3.4 J NS 2.4 J NS 3.9 J NS 3.5 J NS Cobalt 7440-48-4 1 <25 <25 <25 <1.3 2.3 J 1.3 J 1.3 J 0.77 J <5 1.5 <5 <4 <5 <5 2.2 4.5 3.9 5.2 3.8 5.4 5.1 NS 6.7 NS 4.3 NS 6.3 NS 5.6 NS Copper 7440-50-8 1,000 7.4 <5 9.1 <1.8 2.9 J <1.8 <1.8 0.72 J <5 <5 <5 <1 <5 <5 4.0 <2 0.75 J <2.0 3.7 <2.0 <2.0 NS 0.52 J NS <2.0 NS <2.0 NS 0.75 J NS Iron 7439-89-6 300 NS NS NS NS NS NS NS NS 2�20 1�70 <50 22.170 33.190 4�70 7000 5�00 5�00 6�00 5�00 7�00 7�00 NS 9�00 NS 66.700 NS 9�00 NS 9�00 NS Lead 7439-92-1 15 <10 <10 <10 <4.7 <4.7 <4.7 <4.7 0.23 J <5 <5 <5 <1 <5 <5 0.38 BJ <0.5 <0.50 <0.50 -1+ 0.22 J <0.50 <0.50 NS 0.33 JB NS <0.50 NS <0.50 NS <0.50 NS Manganese 7439-965 50 NS NS NS NS NS NS NS NS 1�00 714 <5 363 1,700 1030 2000 2000 2200 2000 3�00 4000 4000 NS 4,600 NS 4,300 NS 5�00 NS 5�00 NS Memory 7439-97-6 1 <0.1 <0.1 0.12 <0.028 <0.028 0.036 J 0.069 BJ <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 F1 <0.2 <0.20 <0.20 <0.20 <0.20 <0.20 NS <0.20 NS <0.20 NS <0.20 NS <0.20 NS Nickel 7440-02-0 100 <40 <40 -40 <2.8 <2.8 <2.8 <2.8 2.0 <5 <5 <5 2.8 7.7 6.4 5.7 7.6 8.0 7.3 7.9 14.0 12.0 NS 16.0 NS 11.0 NS 16.0 NS 15.0 NS Selenium 7782-49-2 20 <10 <10 <10 <8.5 <8.5 <8.5 <8.5 NS I <10 <10 <10 <7 <10 <10 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 NS 1.4 J NS <2.5 NS <2.5 NS 1.2 J NS Silver 7440-22-4 20 <5 <5 <5 <2.1 <2.1 <2.1 <2.1 NS <5 <5 <5 <0.1 <5 <5 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50E690.000 NS <0.50 NS <0.50 NS <0.50 NS <0.50 NS Thallium 7440-28-0 2 NS NS NS NS NS NS NS NS NS <0.5 <0.5 <2 <0.1 <0.1 <2 <2 <2.0 <2.0 <2.0 <2.0 NS <2.0 NS <2.0 NS <2.0 NS <2.0 NS Vanadium 7440-62-2 7 <50 <50 <50 <2.6 9.7 J <2.6 3.2 J 2.0 J <5 <5 <5 2.5 <5 <5 2.9 J 6.2 3.1 J <5.0 <5.0 <5.0 NS <5.0 NS <5.0 NS <5.0 NS <5.0 NS Zinc 7440-66-6 1,000 57.0 <20 62.0 <2.2 19.0 4.1 BJ 7.1 J <20 <10 <10 <10 <5 <10 <10 27.0 <10 <10 <10 <10 <15 NS <10 NS <10 NS <10 NS <10 NS Inorganic Indicator Parameters IupIL) Total Dissolved Solids b SM 2540C E1642222 500,000 NS NS NS NS NS NS NS 210,000 1,510,000 1,020,000 NS NS 2,150,000 1 920 000 1 800 000 2 000 000 1,700,000 2,000,000 1,800,000 1,800,000 NS 2,300,000 NS 2,000,000 NS 2200000 NS 2 100 000 NS Total Alkalinityas CaCO3 b SM 2320 E1640192 NE NE NS NS NS NS NS NS NS 250,000 313,000 200,000 NS NS 408,000 472,000 410,000 490,000 490,000 520,000 530,000 620,000 NS 700,000 NS 640,000 NS 760,000 NS 730,000 NS Chlodde b EPA 9056A 16887-00-6 250,000 NS NS NS NS NS NS NS 500,000 630,000 517,000 NS NS 805,000 790,000 820,000 800 000 920 000 70 0000 70 0000 730,000 NS 850 000 NS 300 000 NS 620 000 B NS 640 000 NS Sulfate b EPA 9056A 14808-79-8 250,000 NS NS NS NS NS NS NS 43,000 28,500 31,600 NS NS 36,500 44,000 43,000 58,000 78,000 56,000 67,000 100,000 80,000 NS 110,000 NS 96,000 NS 110,000 NS 90,000 NS Notes, 1) 2L = North Carolina Department of Environmental Quality (NCDEQ) 15A NCAC 02L .0202 GV Levels (April 11, 2022). 2) IMAC = Interim Maximum Allowable Concentration (Eff. 2013) 3) Mercury analyzed by EPA Method 7470A S = Shealy, P = Pace, TA = Eurofins TestAmenca NA = Not Analyzed; NS = Not Sampled; NE = Not Established J = Analyte detected at a level less than the RL and greater than or equal to the MDL. in this range are estimated. B = the analyte was detected in the associted blank H = Sample was prepped or analyzed beyond the specified holding time. -= LCS and/or LCSD is outside acceptance limits, low biased. Al+= Initial Calibration Verification (ICV) is outside acceptance limits, high biased. F1 = MS and/or MSD recovery exceeds control limits Bold and Underlined indicates result or reporting level exceeded the 2L Standard Bold indicates exceedance of IMAC when no 2L Standard is specified pg/L = micrograms per liter, mg/L = milligrams per liter Table 4 (Page 10 of 14) Greenway Waste Solutions of Apex, LLC Table 4 (Page 11 of 14) Summary of Historical Groundwater Analytical Detections Greenway Waste Solutions of Apex, LLC Highway 55 C&D Landfill Apex, North Carolina Sample ID CAS Number Screening Criteria MW-10 Date 11/4/13 4/2/14 10/21/14 4/23/15 10/12/15 4/25/16 10/31/16 4/19/17 10/16/17 4/18/18 10/17/18 4/17/19 10/24/19 4/2/20 10/27/20 4/12/21 10/27/21 4/18/23 10/10/23 4/16/24 10/21/24 Analytical Laboratory2L Standard"' IMAC al S S S S S S S TA P P P P TA TA TA TA TA TA TA TA TA TA Appendix I VOCs by EPA 8260B fuoll- 75-34-3 6 <1 <1 <1 <0.13 <0.19 <0.19 <0.4 <1 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 ;/210/25/22 <1.0 <1.0 <1.0 <1.0 <1.0 1,1-Dichloroethane 1,4-Dioxane 123-91-1 3 NS NS NS NS NS NS NS NS NS NS <2 <2 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.40 2-Butanone (MEK) 78-93-3 4,000 <70 <10 <10 <2 <1.8 <1.8 <2 <5 <5 <5 <5 <5 <5 <5 <5.0 <5.0 <5.0 <10 <5.0 <5.0 <5.0 <5.0 4-Methyl-2-pentanone (MIBK) 108-10-1 NS <10 <10 <10 <0.29 <0.29 <0.29 <2 <5 <5 <5 <5 <5 <5 <5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Acetone 67-64-1 6,000 <20 <20 <20 <6.7 2.1 J <1.6 <2 <5 36.8 <25 <25 <25 <10 11.0 <10 <10 2.9 J <10 <10 <10 <10 <10 <10 Benzene 71-03-2 1 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <0.5 <1 <1 <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 1 <0.50 <0.50 <0.50 Bromodichdoromethane 75-27-4 0.6 <1 <1 <7 <0.23 <0.23 <0.23 <0.4 <1 <1 <1 <1 <1 <1 <7 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Carbon Disulfide 75-15-0 700 <1 <1 <7 <0.097 <0.45 <0.45 <0.4 <2 <2 <2 <2 <2 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0'+ <2.0 <2.0 <2.0 <2.0 Chloroform 67-66-3 70 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <2 <1 <1 <1 <1 <1 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 0.83 JB <2.0 Dibromochloromethane 124-08-1 0.4 <1 <1 <1 <0.23 <0.23 <0.23 <0.4 <1 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0'+ <1.0 <1.0 <1.0 Tetmhydrofumn 109-99-9 NE 2,000 <5 <5 <5 <2 <0.57 <0.57 <1 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 2.3 JB <10 *- Toluene 108-88-3 600 <1 <l <7 <0.33 <0.24 <0.24 <0.4 <0.5 <1 <1 <1 <1 <0.5 0.17 J <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.34 J <0.50 <0.50 Vinyl chloride 75-01-4 0.03 <1 <1 <1 <0.054 <0.5 <0.5 <0.4 <0.5 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 '+ <1.0 <1.0 <1.0 <1.0 Appendix I Metals by EPA 6020131747001 101W Antimony 744036-0 1 <10 <10 <10 <6.6 <6.6 <6.6 <6.6 <3 5.2 5.9 12.5 <5 <3 <3 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 Arsenic 7440-38-2 10 <70 <10 <10 <2,2 3.8 J 7.4 J 5.1 J 1.5 <10 <10 <10 <70 5.2 3.5 3.2 1.3 2.2 <1.0 1.6 2.0 2.3 1.1 0.93 J Barium 7440-393 700 1,400 1300 1i00 1 500 1 500 1 300 1i00 1i00 1800 2 000 1 880 1,770 2,100 2000 2i00 1 800 2000 1900 1900 1 800 2i00 1 900 11 000 Beryllium 7440-01-7 4 <4 <4 <4 <0.22 <0.22 0.3 J 0.27 J <1 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 A1+ <1.0 <1.0 <1.0 <1.0 A+ <1.0 <1.0 Cadmium 7440-03-9 2 <2 1 <2 <2 1 <0.54 <0.54 1 <0.54 <0.54 1 <0.5 <1 I <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Calcium 7440-70-2 NE NE NS NS NS NS NS NS NS NS 428,000 NS 442,000 460,000 440,000 460,000 440,000 450,000 400,000 400,000 400,000 400,000 380,000 380,000 Chromium 7440-473 10 <5 <5 <5 <0.72 1.4 J <0.72 <0.72 <5 <5 <5 <5 <5 <5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Cobalt 7440-48-4 1 <25 <25 <25 <1.3 <1.3 1.5 J <1.3 <1 <5 0.73 <5 0.97 J 0.65 J 0.53 J <1.0 <1.0 <1.0 0.29 J <1.0 <1.0 <1.0 <1.0 Copper 7440-50-8 1,000 <5 <5 13.0 <1.8 <1.8 <1.8 <1.8 0.90 J <5 5.6 K719770 <5 0.66 J 1 J 1.1 J 0.67 J 0.71 J <2.0 <2.0 0.60 J <2.0 <2.0 0.53 J Iron 7439-89-6 300 NS NS NS NS NS NS NS NS 573 2�50 702 1900 820 2300 270 460 180 210 86 J 520 320 170 Lead 7439-92-1 15 <70 <10 <10 <4.7 <4.7 <4.7 <4.7 <0.5 <5 <5 <5 0.58 B <0.5 <0.50 <0.50 A1+ <0.50 <0.50 <0.50 0.22 JB <0.50 <0.50 <0.50 Manganese 7439-96b 50 NS NS NS NS NS NS NS NS 1�70 1940 406 2800 2�100 2�100 40.0 1I 2000 2�00 150 1800 1300 1�00 Mercury 7439-97-6 1 <0.1 <0.1 <0.1 <0.028 <0.028 <0.028 0.068 BJ <0.2 <0.2 <0.2 <0.2 <0.2 0.20 <0.2 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 0.53 <0.20 Nickel 7440-02-0 100 <40 <40 <40 <2.8 <2.8 <2.8 <2.8 <2 <5 <5 <5 <5 1.3 J 1.2 J 0.85 J <2.0 1.2 J <2.0 <2.0 0.78 J <2.0 <2.0 <2.0 Selenium 7782-49-2 20 <70 <10 <10 <8.5 <8.5 <8.5 <8.5 NS <10 <10 16.0 <10 <2.5 <2.5 <2.5 <2.5 1.1 J <2.5 <2.5 1.2 J <2.5 <2.5 <2.5 Silver 7440-22-4 20 <5 <5 <5 <2.1 <2.1 <2.1 <2.1 NS <5 <5 <5 <5 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Thallium 7440-28-0 2 NS NS NS NS NS NS NS NS NS <0.5 <0.1 <0.1 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Vanadium 7440-62-2 7 <50 <50 <50 <2.6 <2.6 <2.6 <2.6 <5 <5 <5 <5 <5 2.7 J 2.7 J <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Zinc 7440-66-6 1,000 <20 <20 62.0 <2.2 24.0 20 B 34.0 <20 42.2 <10 <10 <10 15.0 <10 <10 <10 <10 <15 <15 <10 <10 <10 <10 Inorganic Indicator Parameters fug/Ll Total Dissolved Solids by SM 2540C E1642222 500,000 NS NS NS NS NS NS NS 4 9000 4 620 000 3,790,000 3 760 000 3 350 000 3 50 0000 3 300 000 3,500,000 3,200,000 3,200,000 3,400,000 3,800,000 3,200,000 3,000,000 2,900,000 3,800,000 Total Alkalinityas CaCO3 b SM 2320 E1640192 NE NE NS NS NS NS NS NS NS 160001100 735,000 563,000 459,000 430,000 400,000 370,000 330,000 330,000 370,000 310,000 310,000 280,000 280,000 260,000 250,000 Chloride by EPA 9056A 16887-00-6 250,000 NS NS NS NS NS NS NS 2,300,000 1 850 000 2,130,000 1,670,000 1,580,000 1 900 000 1,800,000 1,700,000 1,800,000 1 7 00 000 1 700 000 1 700 000 1,000,000 2,100, 000 1 500,000 1,500,000 Sulfate b EPA 9056A 14808-79-8 250,000 NS NS NS NS NS NS NS 23,000 F1 10,200 13,800 13,300 17,000 18,000 16,000 19,000 17,000 15.000 14,000 <50,000 *+ 13,000 15,000 14,000 11,000 Notes: 1) 2L = North Carolina Department of Environmental Quality (NCDEQ) 15A NCAC 02L .0202 GV Levels (April 11, 2022). 2) IMAC = Intedm Maximum Allowable Concentration (Eff. 2013) 3) Mercury analyzed by EPA Method 7470A S = Shealy, P = Pace, TA = Eurofins TestAmenca NA = Not Analyzed; NS = Not Sampled; NE = Not Established J = Analyte detected at a level less than the RL and greater than or equal to the MDL. in this range are estimated. B = the analyte was detected in the assoc0ed blank H = Sample was prepped or analyzed beyond the specified holding time. -= LCS and/or LCSD is outside acceptance limits, low biased. Al+= Initial Calibration Verification (ICV) is outside acceptance limits, high biased. F1 = MS and/or MSD recovery exceeds control limits Bold and Underlined indicates result or reporting level exceeded the 2L Standard Bold indicates exceedance of IMAC when no 2L Standard is specified pg/L = micrograms per liter, mg/L = milligrams per liter Table 4 (Page 11 of 14) Greenway Waste Solutions of Apex, LLC Table 4 (Page 12 of 14) Summary of Historical Groundwater Analytical Detections Greenway Waste Solutions of Apex, LLC Highway 55 C&D Landfill Apex, North Carolina Sample ID CAS Number Screening Criteria MW-11 MW-11R Date 11/4/13 4/2/14 10/21/14 4/23/15 10/12/15 4/25/16 10/31/16 4/19/17 10/16/17 4/18/18 10/17/18 4/17/19 10/24/19 4/2/20 10/28/20 4/12/21 10/27/21 4/4/22 10/25/22 4/18/23 10/10/23 4/16/24 10/21/24 Analytical Laboratory 2L Standard"' IMAC al S S S S S S S TA P p P P TA TA TA TA TA TA TA TA TA TA TA Appendix I VOCs by EPA 8260B fuoll- 75-34-3 6 <1 <1 <1 <0.13 <0.19 <0.19 <0.4 <1 NS <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,1-Dichloroethane 1,4-Dioxane 123-91-1 3 NS NS NS NS NS NS NS NS NS NS <2 <2 <1 <1 <1.0 <1.0 <1.a <1.0 <1.0 <1.0 <1.0 <1.0 <0.40 2-Butanone (MEK) 78-93-3 4,000 <70 <10 <10 <2 <1.8 <1.8 12 <5 NS 15 <5 <5 <5 <5 22.0 <5.0 <5.0 <10 <10 <5.0 <5.0 <5.0 <5.0 4-Methyl-2-pentanone (MIBK) 108-10-1 NS <10 <10 <10 <0.29 <0.29 <0.29 <2 <5 NS <5 <5 <5 <5 <5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Acetone 67-64-1 6,000 <20 <20 <20 <6.7 2.6 J <1.6 <2 <5 NS <25 <25 <25 7.9 J 4.4 J 2.6 J <10 5.3 J <10 <10 <10 2.7 J 2.6 J <10 Benzene 71-03-2 1 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <0.5 NS <1 <1 <1 <0.5 <0.5 <0.50 <0.50 1 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Bromodichdoromethane 75-27-4 0.6 <1 <1 <7 <0.23 <0.23 <0.23 <0.4 <1 NS <1 <1 <1 <1 <7 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Carbon Disulfide 75-15-0 700 <1 <1 <7 <0.097 <0.45 <0.45 <0.4 <2 NS <2 <2 <2 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0'+ <2.0 <2.0 <2.0 <2.0 Chloroform 67-66-3 70 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <2 NS <1 <1 <1 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 0.91 JB <2.0 Dibromochloromethane 124-08-1 0.4 <1 <1 <1 <0.23 <0.23 <0.23 <0.4 <1 NS <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0'+ <1.0 <1.0 <1.0 Tetmhydrofumn 109-99-9 NE 2,000 <5 <5 <5 <2 <0.57 <0.57 <1 <10 NS <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 2.6 JB <10 *- Toluene 108-88-3 600 <1 <l <7 <0.33 <0.24 <0.24 <0.4 <0.5 NS <1 <1 <1 <0.5 <0.5 0.30 J 0.21 J <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Vinyl chloride 75-01-4 0.03 <1 <1 <1 <0.054 <0.5 <0.5 <0.4 <0.5 NS <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 '+ <1.0 <1.0 <1.0 <1.0 Appendix I Metals by EPA 6020131747001 101W Antimony 744036-0 1 <10 <10 <10 <6.6 <6.6 <6.6 <6.6 <3 NS <5 <5 <5 <3 <3 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 Arsenic 7440-38-2 10 <70 <10 <10 <2.2 <2.2 4.3 J 61 1.4 NS <10 <10 <10 7.3 2.8 9.0 6.3 6.6 3.4 6.1 2.6 6.2 1.6 3.2 Barium 7440-393 700 120 11400 190 210 250 300 1i00 420 NS 148 145 171 260 190 220 210 320 260 200 240 280 240 F1 230 Beryllium 7440-01-7 4 <4 <4 <4 <0.22 0.52 J 0.54 J 0.3 J 0.78 J NS <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 11+ <1.0 <1.0 <1.0 <1.0 A+ <1.0 <1.0 Cadmium 7440-03-9 2 <2 1 <2 <2 1 <0.54 <0.54 1 <0.54 <0.54 1 0.72 NS I <1 <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Calcium 7440-70-2 NE NE NS NS NS NS NS NS NS NS NS NS 65,800 88,200 95,000 100,000 83,000 91,000 97,000 100,000 84,000 92,000 89,000 94,000 F1 81,000 Chromium 7440-473 10 <5 <5 <5 <0.72 1.6 J <0.72 <0.72 <5 NS <5 <5 <5 <5 <5 1.4 J <5.0 1.2 J <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Cobalt 7440-48-4 1 <25 <25 <25 <1.3 7.5 J 9.8 J 1.3 J 11.0 NS 1.8 18.0 15.9 13.0 11.0 18.0 3.4 4.7 5.0 10.0 11.0 13.0 8.8 16.0 Copper 7440-50-8 1,000 <5 <5 <5 <1.8 <1.8 <1.8 <1.8 0.72 J NS <5 <5 <5 0.78 J <2 <2.0 0.68 J 1.0 J <2.0 <2.0 0.77 J 1.0 J 0.61 J 1.1 J Iron 7439-89-6 300 NS NS NS NS NS NS NS NS NS 3�60 7�50 2�50 13y00 22.800 19y00 9�00 7�00 4�00 12y00 2�00 6�00 1,400 F1 4�00 Lead 7439-92-1 15 <70 <10 <10 <4.7 <4.7 <4.7 <4.7 1.9 NS <5 <5 <5 0.4 BJ <0.5 <0.50 0.20 J A7+ <0.50 <0.50 <0.50 0.37 JB <0.50 <0.50 <0.50 Manganese 7439-96b 50 NS NS NS NS NS NS NS NS NS 2�20 2�80 33.020 22.800 33 100 221700 2�00 2�00 3�00 3�00 2�00 2�00 2,800 F1 2�00 Mercury 7439-97-6 1 <0.1 <0.1 <0.1 <0.028 <0.028 0.073 J 0.052 BJ <0.2 NS <0.2 <0.2 <0.2 <0.2 <0.2 F1 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 0.11 J <0.20 Nickel 7440-02-0 100 <40 <40 <40 <2.8 <2.8 <2.8 <2.8 2.6 NS <5 9.8 5.8 8.0 6.3 8.6 2.3 2.4 2.2 3.3 3.6 5.7 3.6 5.9 Selenium 7782-49-2 20 <10 <10 <10 <8.5 <8.5 <8.5 <8.5 NS NS <10 <10 <10 2.5 <2.5 <2.5 1.0 J 1.3 J <2.5 1.4 J 1.4 J <2.5 <2.5 1.1 J Silver 7440-22-4 20 <5 <5 <5 <2.1 <2.1 <2.1 <2.1 NS NS <5 <5 <5 0.50 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Thallium 7440-28-0 2 NS NS NS NS NS NS NS NS NS <0.5 <0.1 <0.1 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Vanadium 7440-62-2 7 <50 <50 <50 <2.6 <2.6 <2.6 <2.6 <5 NS 15 <5 <5 3.2 J 31 3.3 J <5.0 <5.0 <5.0 1.8 J <5.0 <5.0 <5.0 <5.0 Zinc 7440-66-6 1,000 <20 <20 <20 4,900 340 75 B 14 J 12 J NS <10 25.1 <10 13.0 <10 <10 <10 <10 <15 <15 <10 <10 <10 <10 Inorganic Indicator Parameters fug/Ll Total Dissolved Solids by SM 2540C E1642222 500,000 NS NS NS NS NS NS NS 690 000 NS 1 170 000 914 000 1 110 000 1 100 000 1 100 000 920 000 1,100,000 1,100,000 1,200,000 470,000 1,300,000 1,100,000 1,200,000 1,000,000 Total Alkalinityas CaCO3 b SM 2320 E1640192 NE NE NS NS NS NS NS NS NS 14,000 NS 698,000 358,000 593,000 530,000 590,000 470,000 640,000 690,000 710,000 570,000 680,000 570,000 680,000 500,000 Chloride b EPA 9056A 16887-00-6 250,000 NS NS NS NS NS NS NS 170,000 NS 248,000 173,000 185,000 190,000 200,000 190,000 210,000 190,000 200,000 180,000 180,000 230,000 180,000 150,000 Sulfate b EPA 9056A 14808-79-8 250,000 NS NS NS NS NS NS NS 26,000 F1 NS 79,000 120,000 98,900 120,000 110,000 100,000 82,000 71,000 69,000 73,000'1 66,000 76,000 64,000 68,000 Notes: 1) 2L = North Carolina Department of Environmental Quality (NCDEQ) 15A NCAC 02L .0202 GV Levels (April 11, 2022). 2) IMAC = Intedm Maximum Allowable Concentration (Eff. 2013) 3) Mercury analyzed by EPA Method 7470A S = Shealy, P = Pace, TA = Eurofins TestAmenca NA = Not Analyzed; NS = Not Sampled; NE = Not Established J = Analyte detected at a level less than the RL and greater than or equal to the MDL. in this range are estimated. B = the analyte was detected in the associted blank H = Sample was prepped or analyzed beyond the specified holding time. -= LCS and/or LCSD is outside acceptance limits, low biased. Al+= Initial Calibration Verification (ICV) is outside acceptance limits, high biased. F1 = MS and/or MSD recovery exceeds control limits Bold and Underlined indicates result or reporting level exceeded the 2L Standard Bold indicates exceedance of IMAC when no 2L Standard is specified pg/L = micrograms per liter, mg/L = milligrams per liter Table 4 (Page 12 of 14) Greenway Waste Solutions of Apex, LLC Table 4 (Page 13 of 14) Summary of Historical Groundwater Analytical Detections Greenway Waste Solutions of Apex, LLC Highway 55 C&D Landfill Apex, North Carolina Sample ID CAS Number Screening Criteria MW-12 MW-13R Date 4/3/20 10/27/20 4/13/21 10/28/21 4/5/22 10/26/22 4/19/23 10/9/23 4/17/24 10/22/24 4/3/20 10/27/20 4/13/21 10/28/21 4722 10/25/22 4/19/23 10/9/23 12/14/23 4/17/24 5/23/24 10/22/24 Analytical Laboratory 21. Standard"' IMAC 1s1 TA TA TA TA TA TA TA TA TA TA TA TA TA TA TA TA TA TA TA TA TA TA Appendix I VOCs by EPA 8260E (uc/LI 75343 6 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 <1.0 <1.0 NS <1.0 <1.0 <1.0 <1.0 NS <1.0 NS <1.0 1,1-Dichloroethane 1,4-Dioxane 123-91A 3 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.40 <1 <1.0 0.32J NS <1.0 <1.0 <1.0 <1.0 NS <1.0 NS <0.40 2-Butanone (MEK) 78-93-3 4,000 15 <5.0 <5.0 <5.0 <70 <70 <5.0 <5.0 <5.0 <5.0 15 <5.0 <5.0 NS <10 <10 <5.0 <5.0 NS <5.0 NS <5.0 4-Methyl-2-pentanone (MIBK) 108-10-1 NS <5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5 <5.0 <5.0 NS <5.0 <5.0 <5.0 <5.0 NS <5.0 NS <5.0 Acetone 67-64-1 6,000 <10 <10 <10 <10 <10 <10 6.7 JB <10 <10 <10 <10 <10 <10 NS <10 <10 5.5 JB <10 F2 NS <10 NS <10 Benzene 71-03-2 1 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.5 <0.50 <0.50 NS <0.50 <0.50 <0.50 <0.50 NS <0.50 NS <0.50 Bromodichdoromethane 75-274 0.6 <1 <1.0 <7.0 <7.0 <7.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 <1.0 <1.0 NS <7.0 <7.0 <7.0 <1.0 NS <1.0 NS <1.0 Carbon Disulfide 75-15-0 700 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2 <2.0 <2.0 NS <2.0 <2.0" <2.0 <2.0 NS <2.0 NS <2.0 Chloroform 67-663 70 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2 <2.0 <2.0 NS <2.0 <2.0 <2.0 <2.0 NS <2.0 NS <2.0 Dibromcchloromethane 124-08A 0.4 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 <1.0 <1.0 NS <1.0 <1.0 <1.0 <1.0 NS <1.0 NS <1.0 Tetmhydrofumn 109-99-9 NE 2,000 <10 <10 <10 <10 <70 <70 <10 <10 <10 <10'- <10 <10 <10 NS <10 <10 <70 <10 NS <10 NS <10'- Toluene 108-88-3 600 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.5 <0.50 <0.50 NS <0.50 <0.50 <0.50 0.25 J NS <0.50 NS <0.50 Vinyl chloride 75-014 0.03 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 <1.0 <1.0 NS <1.0 <1.0 '+ <1.0 <1.0 NS <1.0 NS <1.0 Appendix I Metals by EPA 602013/747001 fua/L1 Antimony 7440-36-0 1 <3 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 ^+ <3.0 <3.0 <3 <3.0 <3.0 NS <3.0 <3.0 <3.0 <3.0 ^+ NS <3.0 NS <3.0 Arsenic 7440-38-2 10 0.99 J 0.36 J 0.35 J 0.51 J <1.0 <1.0 1.0 1.5 B 0.33 J 1.8 1.2 0.53 J 0.44 J NS <7.0 <1.0 0.82 J 0.71 JIB NS 0.28 J NS 0.31 J Barium 7440-39-3 700 420 350 210 280 180 130 170 210 220 400 390 450 440 NS 200 400 470 900 NS 750 NS 910 Beryllium 7440-41-7 4 <1 <1.0 <1.0 <1.0 At+ <1.0 <1.0 <1.0 <1.0 ^+ <1.0 <1.0 <1 <1.0 <1.0 NS <1.0 <1.0 <1.0 <1.0 ^+ NS <1.0 NS <1.0 Cadmium 7440-03-9 2 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.5 <0.50 <0.50 NS <0.50 <0.50 <0.50 <0.50 NS <0.50 NS I <0.50 Calcium 7440-70-2 NE NE 140,000 100,000 64,000 76,000 55,000 45,000 51,000 89,000 B 70,000 130,000 160,000 160,000 150,000 NS 91,000 140,000 150,000 270,000 B NS 260,000 NS 310,000 Chromium 7440-47-3 10 <5 <5.0 <5.0 <5.0 <5.0 <5.0 1.1 J <5.0 <5.0 <5.0 <5 <5.0 <5.0 NS 12.0 <5.0 <5.0 2.8 J NS 9.7 NS 13.0 Cobalt 7440-48-4 1 <1 <1.0 <1.0 <1.0 <1.0 0.81 J 0.47 J 0.86 J <1.0 L2 <1 <1.0 <1.0 NS <1.0 <1.0 <1.0 <1.0 NS <1.0 NS <1.0 Copper 7440-50-8 1,000 <2 0.63 J <2.0 <2.0 2.4 2.0 1.2 J 2.2 1.1 J 0.57 J <2 0.83 J 0.63 J NS 1.3 J <2.0 0.59 J 0.76 J NS <2.0 NS 1.0 J Iron 7439-89-6 300 <100 110 <100 <100 26 J 2�00 1�00 520 320 1�00 <100 <100 <100 NS 98 J <100 <100 73 J NS <100 NS <100 Lead 7439-92-1 15 <0.5 <0.50 <0.50 A1+ <0.50 <0.50 1.1 0.76 B 0.31 J <0.50 <0.50 <0.5 <0.50 <0.50 -1+ NS <0.50 <0.50 0.27 JIB <0.50 NS <0.50 NS <0.50 Manganese 7439-96-5 50 18.0 37.0 11.0 160 18.0 220 230 510 52.0 1�00 410 45.0 44.0 NS 8.2 4.3 1.4 J 29.0 NS 3.7 NS 6.0 Mercury 7439-97-6 1 <0.2 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 0.079 J <0.20 <0.2 <0.20 <0.20 NS <0.20 <0.20 <0.20 4.5 1.2 1.4 2.1 2.1 Nickel 7440-02-0 100 12 <2.0 <2.0 0.64 J <2.0 <2.0 1.1 J 2.0 0.74 J 3.3 0.7 J <2.0 <2.0 NS 3.8 <2.0 <2.0 <2.0 NS <2.0 NS <2.0 Selenium 7782-49-2 20 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 NS <2.5 <2.5 <2.5 <2.5 NS <2.5 NS 1.3 J Silver 7440-22-4 20 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.5 <0.50 <0.50 NS <0.50 <0.50 <0.50 0.36 J NS 0.16 J NS 0.17 J Thallium 7440-28-0 2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2 <2.0 <2.0 NS <2.0 <2.0 <2.0 <2.0 NS <2.0 NS <2.0 Vanadium 7440-62-2 7 3.4 J 3.2 J 3.6 J 3.0 J 4.0 J 7.6 6.5 2.3 J 5.5 <5.0 3.5 J 2.3 J <5.0 NS <5.0 <5.0 <5.0 2.3 J NS <5.0 NS <5.0 Zinc 7440-66-6 1,000 <10 <10 <10 <10 <15 <15 <10 <10 <10 <10 <10 <10 <10 NS <15 <15 <10 <10 NS <10 NS <10 Inorganic Indicator Parameters (ualL) Total Dissolved Solids b SM 2540C E1642222 500,000 1 600 000 1 300 000 860 000 1 000 000 790 000 640 000 770 000 890 000 900,000 1,200,000 1,300,000 1,300,000 1 200 000�N� 1 500 000 1 300 000 1 900 000 NS 1 900 000 NS 2 400000 Total Alkalinit as CaCO3 b SM 2320 E1640192 NE NE 130,000 130,000 120,000 160,000 140,000 99,000 *- l 190,000 220,000 190,000 380,000 150,000 150,000 150,000 61,000 68,000 160,000 NS 130,000 NS 520,000 Chloride b EPA 9056A 16887-00-6 250,000 910000 840000 580000 510000 410 000 270000 310000 150,000 350 000 B 340 000 640000 780 000 7710 000 700 000 810 000 NS 960 000 B NS 1 700 000 Sulfate b EPA 9056A 14808-793 250,000 5,900 6,800 5,200 5,000 42006,900 J"+12,000 72000 36,000 110,000 16,000 18,000 18,0005,400 J 13,000 12,000 NS 16,000 NS 9,100 Notes: 1) 2L = North Carolina Department of Environmental Quality (NCDEQ) 15A NCAC 02L .0202 GV Levels (April 11, 2022). 2) IMAC = Interim Maximum Allowable Concentration (Eff. 2013) 3) Mercury analyzed by EPA Method 7470A S = Shealy, P = Pace, TA = Eurofins TestAmerica NA = Not Analyzed; NS = Not Sampled; NE = Not Established J = Analyte detected at a level less than the RL and greater than or equal to the MDL. in this range are estimated. B = the analyte was detected in the associted blank H = Sample was propped or analyzed beyond the specified holding time. - = LCS and/or LCSD is outside acceptance limits, low biased. At+ = Initial Calibration Verification (ICV) is outside acceptance limits, high biased. F1 = MS and/or MSD recovery exceeds control limits Bold and Underlined indicates result or reporting level exceeded the 21- Standard Bold indicates exceedance of IMAC when no 21 Standard is specified pg/L = micrograms per liter; mg/L = milligrams per liter Table 4 (Page 13 of 14) Greenway Waste Solutions of Apex, LLC Table 4 (Page 14 of 14) Summary of Historical Groundwater Analytical Detections Greenway Waste Solutions of Apex, LLC Highway 55 C&D Landfill Apex, North Carolina Sample ID CAS Number Screening Criteria MW-14 Leachate Date 10/24/19 4/3/20 10/28/20 4/13/21 10/28/21 4/5/22 10/26/22 4/19/23 10/10/23 4/17/24 10/22/24 4/19/23 10/10/23 4/30/24 10/22/24 Analytical Laboratory 21 Standard"' IMAC hl TA TA TA TA TA TA TA TA TA TA TA TA TA TA TA Appendix I VOCs by EPA 8260E (uall-) 75343 6 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,1-Dichlomethane 1,4-Dioxane 123-91-1 3 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.40 14.0 41.0 16.0 30.0 2-Butanone (MEK) 78-93-3 4,000 15 <5 <5.0 <5.0 <5.0 <10 <10 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 4-Methyl-2-pentanone (MIBK) 108-10-1 NS <5 15 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 3.8 J <5.0 <5.0 Acetone 67-64-1 6,000 <10 3.2 J <10 <10 <10 <10 <10 <10 <10 2.1 J <10 10.0 34.0 1.9 J 17.0 Benzene 71A3-2 1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 1.4 4.8 <0.50 0.81 Bromodichdoromethane 75-27-4 0.6 <1 <1 <1.0 <1.0 <1.0 <7.0 <7.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Carbon Disuffide 75-15-0 700 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 1.0 J 8.7 <2.0 1.5 J Chloroform 67-663 70 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 0.63 J <2.0 Dibromochloromethane 124-08-1 0.4 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 *+ <1.0 <1.0 <1.0 <1.0 *+ <1.0 <1.0 <1.0 Tetmhydrofumn 109-99-9 NE 2,000 <10 <10 <10 <10 <10 <10 <10 <70 <10 <10 <10 *- 270 2,400 19.0 700 Toluene 108-88-3 600 <0.5 <0.5 <0.50 10.50 <0.50 <0.50 <0.50 <0.50 0.15 J <0.50 <0.50 0.55 7.9 <0.50 1.1 Vinyl chloride 75-01-4 0.03 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Appendix I Metals by EPA 602013/747001 fua/L1 Antimony 7440-36-0 1 <3 <3 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 3.8 1.5 J 3.2 Arsenic 7440-38-2 10 1.8 2.1 1.2 0.76 J 1.4 <11.0 1.3 1.4 1.5 0.48 J 0.55 J 69.0 140 B 65.0 100 Barium 7440-39-3 700 1 000 1 800 1600 1i00 1i00 1�00 1 600 1,700 1 900 1,700 1800 2 00 200 310 380 Beryllium 7440-41-7 4 <1 <1 <1.0 <1.0 <1.0 11+ <1.0 <1.0 <1.0 <1.0 "+ <1.0 <1.0 <1.0 <1.0 ^+ <1.0 <1.0 Cadmium 7440-43-9 2 0.50 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.56 1 <0.50 <0.50 Calcium 7440-70-2 NE NE 230,000 280,000 210,000 270,000 290,000 230,000 240,000 240,000 230,000 240,000 240,000 440,000 310,000 B 430,000 420,000 Chromium 7440-47-3 10 <5 1.8 J 1.8 J <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 38.0 48.0 45.0 44.0 Cobalt 7440-48-4 1 <1 0.57 J 19 <1.0 <1.0 <1.0 0.32 J <1.0 <1.0 <1.0 <1.0 1.8 L4 2.9 2.2 Copper 744050-8 1,000 1.6 J 0.5 J 2.1 <2.0 1.3 J <2.0 <2.0 0.53 J 0.71 J <2.0 0.78 J 0.63 J 0.68 J 3.5 0.50 J Iron 7439-89-6 300 54.0 1i00 31300 390 310 110 790 100 420 <100 180 3800 4800 5800 610 Lead 7439-92-1 15 0.19 BJ 0.21 J 0.61 <0.50 -1+ <0.50 <0.50 <0.50 0.23 JB 0.19 J <0.50 <0.50 0.32 JB <0.50 0.33 J <0.50 Manganese 7439-965 50 14.0 140 1900 83.0 96.0 92.0 180 120 260 150 230 620 270 860 590 Mercury 7439-97-6 1 0.61 1.6 0.95 0.88 0.55 1.6 0.11 J 0.92 0.90 0.72 1.2 <0.20 <0.20 <0.20 <0.20 Nickel 7440-02-0 100 12 1.3 J 2.6 <2.0 0.80 J <2.0 <2.0 0.80 J <2.0 <2.0 <2.0 2.4 4.3 3.8 3.7 Selenium 7782-49-2 20 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 1.8 J 1.9 J 5.1 3.7 Silver 7440-22-4 20 0.26 J 0.23 J 0.22 J 0.13 J <0.50 <0.50 <0.50 0.14 J 0.45 J <0.50 0.31 J <0.50 <0.50 <0.50 <0.50 Thallium 7440-28-0 2 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Vanadium 7440-62-2 7 8.9 8.3 11.0 4.9 J 6.5 5.3 7.9 6.3 6.9 4.2 J 8.4 16.0 25.0 24.0 21.0 Zinc 7440-66-6 1,000 T6 J <10 15.0 8.9 J <10 <15 <75 <70 <10 <10 <10 6.9 J <10 <10 <10 Inoraanic Indicator Parameters (ua/L) Total Dissolved Solids by SM 2540C E1642222 500,000 2,600,000 3,100,000 2,400,000 2,800,000 2,900,000 2,900,000 2,800,000 3,000,000 2,600,000 2,600,000 2.900.000 2.800.000 2,800,000 3,000,000 2,800,000 Total Alkalinity as CaCO3 by SM 2320 E1640192 NE NE 390'000 380,000 410,000 430,000 460,000 420,000 470,000 *- 480,000 500,000 460,000 470,000 1,502,000 2,000,000 1,700,000 1,700,000 Chloride b EPA 9056A 16887-005 250,000 1 300 000 1 500 000 1 300 000 1 300 000 1 400 000 1 300 000 1 400 000 850 000 1,600,000 1,200,000 1,200,000 19,000 180,000 97,000 97,000 Sulfate b EPA 9056A 14808-793 250,000 10,000 10.000 13,000 35,000 9,400 11,000 <20,000 , 11,000 12,000 14,000 13,000 160,000 180,000 580 000 450 000 Notes: 1) 2L = North Carolina Department of Environmental Quality (NCDEQ) 15A NCAC 02L .0202 GV Levels (April 11, 2022). 2) IMAC = Interim Maximum Allowable Concentration (Eff. 2013) 3) Mercury analyzed by EPA Method 7470A S = Shealy, P = Pace, TA = Eurofins TestAmerica NA = Not Analyzed; NS = Not Sampled; NE = Not Established J = Analyte detected at a level less than the RL and greater than or equal to the MDL. in this range are estimated. B = the analyte was detected in the associted blank H = Sample was prepped or analyzed beyond the specified holding time. - = LCS and/or LCSD is outside acceptance limits, low biased. "1+= Initial Calibration Verification (ICV) is outside acceptance limits, high biased. F1 = MS and/or MSD recovery exceeds control limits Bold and Underlined indicates result or reporting level exceeded the 21- Standard Bold indicates exceedance of IMAC when no 21 Standard is specified pg/L = micrograms per liter, mg/L = milligrams per liter Table 4 (Page 14 of 14) Greenway Waste Solutions of Apex, LLC Table 5 (Page 1 of 4) Summary of Historical Surface Water Analytical Detections Greenway Waste Solutions of Apex, LLC Highway 55 C&D Landfill Apex, North Carolina Sample ID Sceenina Criteria (1) SW-1 Date CAS Number Aquatic Life & Secondary Recreation Fish Consumption In -Stream Target Values 11/4/13 4/2/14 10/21/14 4/23/15 10/12/15 4/25/16 10/31/16 4/20/17 10/16/17 4/18/18 10/17/18 4/17/19 10/24/19 4/2/20 10/27/20 4/13/21 10/28/21 4/5/22 10/26/22 4/18/23 10/10/23 4/17/24 10/22/24 Analytical Laboratory S S S S S S S TA P P P P TA TA TA TA TA TA TA TA TA TA TA Appendix I VOCs by EPA 8260B (ug/L) 75-34-3 <1 <1 <1 <0.13 <0.19 <0.19 <0.4 <1 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,1-Dichloroethane 1,4-Dioxane 123-91-1 NS NS NS NS NS NS NS NS NS NS <2 <2 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.40 2-Butanone (MEK) 78-93-3 26000 <10 63.0 <10 1 <2 <1.8 1 <1.8 7.8 J 1 <5 <5 <5 1 <5 <5 1 <5 <5 1 <5.0 <5.0 1 <5.0 <10 <10 <5.0 <5.0 1 <5.0 <5.0 1,2-Dichlorobenzene 9550-1 470 NA NA NA NA NA NA NA NA NA NA NA NA NA <1 <1.0 <1.0 <1.0 <1.0 <1.0 I <1.0 <1.0 <1.0 <1.0 1,2-Dichloroethane 107-06-2 NA NA NA NA NA NA NA NA NA NA NA NA NA <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,2-Dichloropropane 78-87-5 NA NA NA NA NA NA NA NA NA NA NA NA NA <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,4-Dichlorobenzene 10646-7 NA NA NA NA NA NA NA NA NA NA NA NA NA <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 4-Methyl-2-pentanone (MIBK) 108-10-1 26000 <10 <10 <10 <0.29 <0.29 <0.29 <2 <5 <5 <5 <5 <5 <5 <5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Acetone 67-64-1 2000 <20 <20 <20 <6.7 <1.6 <1.6 47.0 <5 <25 <25 <25 <25 <10 <10 <10 <10 <10 <10 <10 <10 <10 F2 2.7 J <10 Acrylonitrile 107-13-1 420 NA NA NA NA NA NA NA NA NA NA NA NA <20 <20 <20 <20 <20 <20 <20 <20 <4.5 F1 <20 Benzene 7143-2 51 <1 <1 <1 <0.21 <0.21 <0.21 0.65 J <0.5 <1 <1 <1 1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Bromodichdoromethane 75-274 <1 <1 <1 <0.23 <0.23 <0.23 <0.4 <1 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Carbon Disulfide 75-15-0 100 <1 <1 <1 <0.097 <0.45 <0.45 <0.4 <2 <2 <2 <2 <2 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Chlorobenzene 108-90-7 140 NA NA NA NA NA NA NA NA NA NA NA NA NA <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 *+ <1.0 Chloroform 67-66-3 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <2 <1 <1 <1 <1 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Dibromochloromethane 12448-1 <1 <1 <1 <0.23 <0.23 <0.23 <0.4 <1 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 *+ <1.0 <1.0 <1.0 Methylene Chloride (Dichloromethane) 75-09-2 11000 NA NA NA NA NA NA NA NA NA NA NA NA NA <5 <5.0 6.0 B <5.0 <5.0 <5.0 2.2 J 3.2 JB <5.0 3.7 JB Toluene 108-88-3 11 <1 <1 <1 <0.33 <0.24 <0.24 <0.4 0.95 <1 <1 <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Tdchloroethene 79-01-6 30 NA NA NA NA NA NA NA NA NA NA NA NA NA <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Vinyl chloride 75-014 2.4 <1 <1 <1 <0.054 <0.5 <0.5 <0.4 <0.5 <1 <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 X lene Total 1330-20-7 670 NA NA NA NA NA NA NA NA NA NA NA NA NA <1 NA <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Appendix I Metals by EPA 6020B/7470A(" (pg/L) 7440-36-0 5300 <10 <10 <10 <6.6 <6.6 - <1 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Antimony Arsenic 7440-38-2 340 10 <10 <10 <10 <2.2 <2.2 2.5 J 15.0 0.61 J NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Barium 7440-39-3 21000 69.0 480 110 82.0 110 64.0 520 48.0 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Beryllium 744041-7 65 <4 <4 <4 <0.22 <0.22 <0.22 <0.22 <1 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Cadmium 744043-9 4.13 <2 <2 <2 <0.54 <0.54 <0.54 <0.54 <0.5 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Chromium 744047-3 837.28 <5 16.0 <5 <0.72 1.1 J 1.4 J 0.98 J <5 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Cobalt 7440484 16 <25 <25 <25 <1.3 <1.3 <1.3 5.2 J 0.58 J NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Copper 7440-50-8 20.93 <5 19.0 <5 <1.8 <1.8 <1.8 <1.8 0.95 J NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Lead 7439-92-1 107.31 <10 16.0 <10 <4,7 <4.7 <4.7 <4.7 0.38 J NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Mercury 7439-97-6 0.12 <0.1 <0.1 <0.1 <0.028 <0.028 <0.028 0.071 BJ <0.2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Nickel 7440-02-0 696.87 <40 <40 <40 <2.8 <2.8 <2.8 5.3 J <2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Selenium 778249-2 5 <10 <10 <10 <8.5 <8.5 <8.5 <8.5 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Silver 7440-224 7.22 <5 <5 <5 <2.1 <2.1 <2.1 <2.1 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Thallium 7440-28-0 - - 2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Vanadium 7440-62-2 10 5 1 <50 68.0 <50 <2.6 <2.6 5.4 J 16 J <5 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Zinc 7440-66-6 174.5 <20 150 <20 <2.2 5.2 J 9.6 BJ 13 J <20 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Inorganic Indicator Parameters WWI-) SW311 NS NS NS NS NS NS NS 84,000 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Total Dissolved Solids by SM 2540C Total Alkalinity as CaCO3 by SM 2320 SW337 NS NS NS NS NS NS NS 27,000 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Chloride by EPA 9056A SW301 230,000 NS NS NS NS NS NS NS 28,000 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Sulfate by EPA 9056A 14808-79-8 NS NS NS NS NS NS NS 4,000 NS NS NS NS NS NS NS NS NS NS NS I NS NS NS NS Notes: 1) North Carolina Department of Environmental Quality (NCDEQ) 15A NCAC 02B Water Quality Standards for Surface Waters (Eff. June 10, 2019) 2) Mercury analyzed by EPA Method 7470A 3) In -stream hardness value of 160 mg/L based on sample collected on April 13, 2021 P = Pace, TA = Eurofins TestAmerica NA = Not Analyzed; NS = Not Sampled; - = Not Established J = Analyte detected at a level less than the RL and greater than or equal to the MDL. Concentrations B = the analyte was detected in the associted blank Bold and Underlined indicates result exceeded the 2B Standard for Aquatic Life & Secondary Recreation Bold indicates exceedance of the 2B Standard for Fish Consumption Underlined indicates exceedance of the In -Stream Target Value pg/L = micrograms per liter,, mg/L = milligrams per liter Table 5 (Page 1 of 4) Greenway Waste Solutions of Apex, LLC Table 5 (Page 2 of 4) Summary of Historical Surface Water Analytical Detections Greenway Waste Solutions of Apex, LLC Highway 55 C&D Landfill Apex, North Carolina Sample ID Sceenina Criteria (1) SW-2 Date CAS Number Aquatic Life & Secondary Recreation Fish Consumption In -Stream Target Values 11/4/13 4/2/14 10/21/14 4/23/15 10/12/15 4/25/16 10/31/16 4/20/17 10/16/17 4/18/18 10/17/18 4/17/19 10/24/19 4/2/20 10/27/20 4/13/21 10/28/21 4/5/22 10/26/22 4/18/23 10/10/23 4/17/24 10/22/24 Analytical Laboratory S S S S S S S TA P P P P TA TA TA TA TA TA TA TA TA TA TA Appendix I VOCs by EPA 8260B (ug/L) 75-34-3 <1 <1 <1 <0.13 <0.19 <0.19 <0.4 <1 NS <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,1-Dichloroethane 1,4-Dioxane 123-91-1 NS NS NS NS NS NS NS NS NS NS <2 <2 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.40 2-Butanone (MEK) 78-93-3 26000 <10 I <10 <10 1 <2 <1.8 1 <1.8 <2 1 <5 NS <5 1 <5 <5 1 <5 <5 1 <5.0 <5.0 1 <5.0 <10 <10 <5.0 <5.0 1 <5.0 <5.0 1,2-Dichlorobenzene 9550-1 470 NA NA NA NA NA NA NA NA NA NA NA NA NA <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,2-Dichloroethane 107-06-2 NA NA NA NA NA NA NA NA NA NA NA NA NA <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,2-Dichloropropane 78-87-5 NA NA NA NA NA NA NA NA NA NA NA NA NA <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,4-Dichlorobenzene 10646-7 NA NA NA NA NA NA NA NA NA NA NA NA NA <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 4-Methyl-2-pentanone (MIBK) 108-10-1 26000 <10 <10 <10 <0.29 <0.29 <0.29 <2 <5 NS <5 <5 <5 <5 <5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Acetone 67-64-1 2000 <20 <20 <20 <6.7 1.6 J <1.6 <2 <5 NS <25 <25 <25 <10 <10 <10 <10 <10 <10 <10 <10 <10 2.5 J <10 Acrylonitrile 107-13-1 420 NA NA NA NA NA NA NA NA NA NA NA NA <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 Benzene 7143-2 51 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <0.5 NS <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Bromodichdoromethane 75-274 <1 <1 <1 <0.23 <0.23 <0.23 <0.4 <1 NS <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Carbon Disulfide 75-15-0 100 <1 <1 <1 <0.097 <0.45 <0.45 <0.4 <2 NS <2 <2 <2 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Chlorobenzene 108-90-7 140 NA NA NA NA NA NA NA NA NA NA NA NA NA <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0.+ <1.0 Chloroform 67-66-3 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <2 NS <1 <1 <1 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Dibromochloromethane 12448-1 <1 <1 <1 <0.23 <0.23 <0.23 <0.4 <1 NS <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0'+ <1.0 <1.0 <1.0 Methylene Chloride (Dichloromethane) 75-09-2 11000 NA NA NA NA NA NA NA NA NA NA NA NA NA <5 <5.0 5.4 B <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 3.9 JB Toluene 108-88-3 11 <1 <1 <1 <0.33 <0.24 <0.24 <0.4 <0.5 NS <1 <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 10.0 <0.50 0.21 J Tdchloroethene 79-01-6 30 NA NA NA NA NA NA NA NA NA NA NA NA NA <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Vinyl chloride 75-014 2.4 <1 <1 <1 <0.054 <0.5 <0.5 <0.4 <0.5 NS <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 X lene Total 1330-20-7 670 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Appendix I Metals by EPA 6020B/7470A(" (pg/L) 7440-36-0 5300 <10 <10 <10 <6.6 <6.6 <6.6 <6.6 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Antimony Arsenic 7440-38-2 340 10 <10 <10 <10 <2.2 2.2 J <2.2 7.2 J NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Barium 7440-39-3 21000 130 49.0 40.0 120 41.0 45.0 290 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Beryllium 744041-7 65 <4 <4 <4 <0.22 <0.22 <0.22 <0.22 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Cadmium 744043-9 4.13 <2 <2 <2 <0.54 <0.54 <0.54 <0.54 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Chromium 744047-3 837.28 <5 <5 <5 5.9 0.91 J 2.8 J 15.0 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Cobalt 7440484 16 <25 <25 <25 <1.3 <1.3 <1.3 13 J NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Copper 7440-50-8 20.93 5.0 <5 <5 <1.8 <1.8 <1.8 15.0 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Lead 7439-92-1 107.31 <10 <10 <10 <4,7 <4.7 <4.7 14.0 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Mercury 7439-97-6 0.12 <0.1 <0.1 <0.1 <0.028 <0.028 <0.028 0.076 BJ NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Nickel 7440-02-0 696.87 <40 <40 <40 <2.8 <2.8 <2.8 7.3 J NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Selenium 778249-2 5 <10 <10 <10 <8.5 <8.5 <8.5 <8.5 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Silver 7440-224 7.22 <5 <5 <5 <2.1 <2.1 <2.1 <2.1 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Thallium 7440-28-0 - - 2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Vanadium 7440-62-2 10 5 1 <50 <50 <50 <2.6 <2.6 <2.6 50.0 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Zinc 7440-66-6 174.5 <20 <20 <20 29.0 6 J 5.4 BJ 80.0 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Inorganic Indicator Parameters WWI-) SW311 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Total Dissolved Solids by SM 2540C Total Alkalinity as CaCO3 by SM 2320 SW337 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Chloride b EPA 9056A SW301 230,000 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Sulfate by EPA 9056A 14808-79-8 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Notes: 1) North Carolina Department of Environmental Quality (NCDEQ) 15A NCAC 02B Water Quality Standards for Surf Waters (Eff. June 10, 2019) 2) Mercury analyzed by EPA Method 7470A 3) In -stream hardness value of 160 mg/L based on sample collected on April 13, 2021 P = Pace, TA = Eurofins TestAmerica NA = Not Analyzed; NS = Not Sampled; - = Not Established J = Analyte detected at a level less than the RL and greater than or equal to the MDL. Concentrations B = the analyte was detected in the associted blank Bold and Underlined indicates result exceeded the 2B Standard for Aquatic Life & Secondary Recreation Bold indicates exceedance of the 2B Standard for Fish Consumption Underlined indicates exceedance of the In -Stream Target Value pg/L = micrograms per Ifter, mg/L = milligrams per liter Table 5 (Page 2 of 4) Greenway Waste Solutions of Apex, LLC Table 5 (Page 3 of 4) Summary of Historical Surface Water Analytical Detections Greenway Waste Solutions of Apex, LLC Highway 55 C&D Landfill Apex, North Carolina Sample ID Sceenina Criteriat1I SW-3 SW-3R Date CAS Number Aquatic Life & Secondary Recreation Fish Consumption In -Stream Target Values 11/4/13 4/2/14 10/21/14 4/23/15 10/12/15 4/25/16 10/31/16 4/20/17 10/16/17 4/18/18 10/17/18 4/17/19 10/24/19 4/2/20 10/27/20 4/13/21 10/28/21 4/5/22 10/26/22 4/18/23 10/10/23 4/17/24 10/22/24 Analytical Laboratory S S S S S S S TA P P P P TA TA TA TA TA TA TA TA TA TA TA Appendix I VOCs by EPA 8260B (ug/L) 75-34-3 <1 <1 <1 <0.13 <0.19 <0.19 <0.4 <1 NS <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,1-Dichloroethane 1,4-Dioxane 123-91-1 NS NS NS NS NS NS NS NS NS NS <2 <2 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.40 2-Butanone (MEK) 78-93-3 26000 <10 I <10 <10 1 <2 <1.8 1 1.8 <2 1 <5 NS <5 1 <5 <5 1 <5 <5 <5.0 <5.0 <5.0 <10 <10 <5.0 <5.0 1 <5.0 <5.0 1,2-Dichlorobenzene 9550-1 470 NA NA NA NA NA NA NA NA NA NA NA NA NA <1 <1.0 <1.0 I <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,2-Dichloroethane 107-06-2 NA NA NA NA NA NA NA NA NA NA NA NA NA <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,2-Dichloropropane 78-87-5 NA NA NA NA NA NA NA NA NA NA NA NA NA <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,4-Dichlorobenzene 10646-7 NA NA NA NA NA NA NA NA NA NA NA NA NA <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 4-Methyl-2-pentanone (MIBK) 108-10-1 26000 <10 <10 <10 <0.29 <0.29 2.0 J <2 <5 NS <5 <5 <5 <5 <5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Acetone 67-64-1 2000 <20 <20 <20 <6.7 <1.6 4 J <2 <5 NS <25 <25 <25 <10 <10 21.0 6.3 J <10 <10 <10 <10 2.8 J 2.7 J <10 Acrylonitrile 107-13-1 420 NA NA NA NA NA NA NA NA NA NA NA NA <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 Benzene 7143-2 51 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <0.5 NS <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Bromodichdoromethane 75-274 <1 <1 <1 <0.23 <0.23 0.54 J <0.4 <1 NS <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Carbon Disulfide 75-15-0 100 <1 <1 <1 <0.097 <0.45 <0.45 <0.4 <2 NS <2 <2 <2 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Chlorobenzene 108-90-7 140 NA NA NA NA NA NA NA NA NA NA NA NA NA <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0.+ <1.0 Chloroform 67-66-3 <1 <1 <1 <0.21 <0.21 0.59 J <0.4 <2 NS <1 <1 <1 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Dibromochloromethane 12448-1 <1 <1 <1 <0.23 <0.23 0.38 J <0.4 <1 NS <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0'+ <1.0 1 <1.0 <1.0 Methylene Chloride (Dichloromethane) 75-09-2 11000 NA NA NA NA NA NA NA NA NA NA NA NA NA <5 <5.0 5.4 B <5.0 <5.0 <5.0 1 <5.0 2.9 JB <5.0 3.7 JB Toluene 108-88-3 11 <1 <1 <1 <0.33 <0.24 <0.24 <0.4 <0.5 NS <1 <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Tdchloroethene 79-01-6 30 NA NA NA NA NA NA NA NA NA NA NA NA NA <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Vinyl chloride 75-014 2.4 <1 <1 <1 <0.054 <0.5 <0.5 <0.4 <0.5 NS <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 X lene Total 1330-20-7 670 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Appendix I Metals by EPA 6020B/7470A(" (pg/L) 7440-36-0 5300 <10 <10 <10 <6.6 <6.6 <6.6 <1 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Antimony Arsenic 7440-38-2 340 10 <10 <10 <10 <2.2 2.2 J 3.7 J <2.2 1.6 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Barium 7440-39-3 21000 45.0 48.0 120 120 41.0 100 41.0 240 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Beryllium 744041-7 65 <4 <4 <4 <0.22 <0.22 <0.22 <0.22 <1 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Cadmium 744043-9 4.13 <2 <2 <2 <0.54 <0.54 <0.54 <0.54 <0.5 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Chromium 744047-3 837.28 <5 <5 <5 <0.72 <0.72 7.6 J <0.72 <5 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Cobalt 7440484 16 <25 <25 <25 <1.3 <1.3 3 J <1.3 4.4 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Copper 7440-50-8 20.93 <5 <5 <5 <1.8 1.9 J 11.0 <1.8 5.8 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Lead 7439-92-1 107.31 <10 <10 <10 <4,7 <4.7 9.3 J <4.7 1.2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Mercury 7439-97-6 0.12 <0.1 <0.1 <0.1 <0.028 <0.028 <0.028 0.06 BJ <0.2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Nickel 7440-02-0 696.87 <40 <40 <40 <2.8 <2.8 4.6 J <2.8 1.9 J NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Selenium 778249-2 5 <10 <10 <10 <8.5 <8.5 <8.5 <8.5 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Silver 7440-224 7.22 <5 <5 <5 <2.1 <2.1 <2.1 <2.1 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Thallium 7440-28-0 - - 2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Vanadium 7440-62-2 10 5 1 <50 <50 <50 <2.6 <2.6 20 J <2.6 2.7 J NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Zinc 7440-66-6 174.5 <20 <20 <20 <2.2 3.9 J 55 B <2.2 140 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Inorganic Indicator Parameters WWI-) SW311 NS NS NS NS NS NS NS 370,000 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Total Dissolved Solids by SM 2540C Total Alkalinity as CaCO3 by SM 2320 SW337 NS NS NS NS NS NS NS 97,000 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Chloride by EPA 9056A SW301 230,000 NS NS NS NS NS NS NS 56,000 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Sulfate b EPA 9056A 14808-79-8 NS NS NS NS NS NS NS 51,000 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Notes: 1) North Carolina Department of Environmental Quality (NCDEQ) 15A NCAC 02B Water Quality Standards for Surf Waters (Eff. June 10, 2019) 2) Mercury analyzed by EPA Method 7470A 3) In -stream hardness value of 160 mg/L based on sample collected on April 13, 2021 P = Pace, TA = Eurofins TestAmerica NA = Not Analyzed; NS = Not Sampled; - = Not Established J = Analyte detected at a level less than the RL and greater than or equal to the MDL. Concentrations B = the analyte was detected in the associted blank Bold and Underlined indicates result exceeded the 2B Standard for Aquatic Life & Secondary Recreation Bold indicates exceedance of the 2B Standard for Fish Consumption Underlined indicates exceedance of the In -Stream Target Value pg/L = micrograms per liter,, mg/L = milligrams per liter Table 5 (Page 3 of 4) Greenway Waste Solutions of Apex, LLC Table 5 (Page 4 of 4) Summary of Historical Surface Water Analytical Detections Greenway Waste Solutions of Apex, LLC Highway 55 C&D Landfill Apex, North Carolina Sample ID Sceenina Criteria (1) SW-4 Date CAS Number Aquatic Life & Secondary Recreation Fish Consumption In -Stream Target Values 11/4/13 4/2/14 10/21/14 4/23/15 10/12/15 4/25/16 10/31/16 4/20/17 10/16/17 4/18/18 10/17/18 4/17/19 10/24/19 4/2/20 10/27/20 4/13/21 10/28/21 4/5/22 10/26/22 4/18/23 10/10/23 4/17/24 10/22/24 Analytical Laboratory S S S S S S S TA P P P P TA TA TA TA TA TA TA TA TA TA TA Appendix I VOCs by EPA 8260B (ug/L) 75-34-3 <1 <1 <1 <0.13 <0.19 <0.19 <0.4 <1 NS <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,1-Dichloroethane 1,4-Dioxane 123-91-1 NS NS NS NS NS NS NS NS NS NS <2 <2 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 0.73 J <1.0 <1.0 0.21 J 2-Butanone (MEK) 78-93-3 26000 <10 <10 I <10 <2 1 8.6 J <1.8 <2 1 <5 NS 1 <5 <5 <5 <5 1 <5 <5.0 <5.0 1 <5.0 <10 I <10 <5.0 <5.0 <5.0 <5.0 1,2-Dichlorobenzene 9550-1 470 NA NA NA NA NA NA NA NA NA NA NA NA NA <1 <1.0 <1.0 <1.0 <1.0 <1.0 I <1.0 <1.0 <1.0 <1.0 1,2-Dichloroethane 107-06-2 NA NA NA NA NA NA NA NA NA NA NA NA NA <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,2-Dichloropropane 78-87-5 NA NA NA NA NA NA NA NA NA NA NA NA NA <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,4-Dichlorobenzene 10646-7 NA NA NA NA NA NA NA NA NA NA NA NA NA <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 4-Methyl-2-pentanone (MIBK) 108-10-1 26000 <10 <10 <10 <0.29 <0.29 <0.29 <2 <5 NS <5 <5 <5 <5 <5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Acetone 67-64-1 2000 <20 <20 <20 <6.7 2.6 J <1.6 <2 <5 NS <25 <25 <25 <10 <10 23.0 4.8 J 18.0 <10 <10 <10 <10 2.4 J <10 Acrylonitrile 107-13-1 420 NA NA NA NA NA NA NA NA NA NA NA NA <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 Benzene 7143-2 51 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <0.5 NS <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Bromodichdoromethane 75-274 <1 <1 <1 <0.23 <0.23 <0.23 <0.4 <1 NS <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Carbon Disulfide 75-15-0 100 <1 <1 <1 <0.097 <0.45 <0.45 <0.4 <2 NS <2 <2 <2 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Chlorobenzene 108-90-7 140 NA NA NA NA NA NA NA NA NA NA NA NA NA <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 *+ <1.0 Chloroform 67-66-3 <1 <1 <1 <0.21 <0.21 <0.21 <0.4 <2 NS <1 <1 <1 <2 <2 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Dibromochloromethane 12448-1 <1 <1 <1 <0.23 1 <0.23 <0.23 <0.4 <1 I NS <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 *+ <1.0 <1.0 <1.0 Methylene Chloride (Dichloromethane) 75-09-2 11000 NA NA NA NA NA NA NA NA NA NA NA NA NA <5 <5.0 5.1 B <5.0 <5.0 <5.0 2.3 J <5.0 <5.0 <5.0 Toluene 108-88-3 11 <1 <1 <1 <0.33 <0.24 <0.24 <0.4 <0.5 NS <1 <1 <1 <0.5 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Tdchloroethene 79-01-6 30 NA NA NA NA NA NA NA NA NA NA NA NA NA <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Vinyl chloride 75-014 2.4 <1 <1 <1 <0.054 <0.5 <0.5 <0.4 <0.5 NS <1 <1 <1 <1 <1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 X lene Total 1330-20-7 670 NA NA NA NA NA NA NA NA NA NA NA NA NA NA <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Appendix I Metals by EPA 6020B/7470A(" (pg/L) 7440-36-0 5300 <10 <10 <10 <6.6 <6.6 <6.6 <6.6 <1 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Antimony Arsenic 7440-38-2 340 10 <10 <10 <10 <2.2 <2.2 <2.2 13 J 1.8 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Barium 7440-39-3 21000 46.0 95.0 39.0 100 75.0 45.0 320 73.0 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Beryllium 744041-7 65 <4 <4 <4 <0.22 <0.22 <0.22 <0.22 <1 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Cadmium 744043-9 4.13 <2 <2 <2 <0.54 <0.54 <0.54 <0.54 <0.5 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Chromium 744047-3 837.28 <5 <5 <5 <0.72 2.6 J <0.72 1.1 J <5 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Cobalt 7440484 16 <25 <25 <25 <1.3 <1.3 <1.3 5.5 J 1.1 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Copper 7440-50-8 20.93 <5 <5 <5 <1.8 2.6 J <1.8 <1.8 16.0 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Lead 7439-92-1 107.31 <10 <10 <10 <4,7 <4.7 <4.7 <4.7 0.21 J NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Mercury 7439-97-6 0.12 <0.1 <0.1 <0.1 <0.028 0.079 J <0.028 0.065 BJ <0.2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Nickel 7440-02-0 696.87 <40 <40 <40 <2.8 <2.8 <2.8 5.6 J <2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Selenium 778249-2 5 <10 <10 <10 <8.5 <8.5 <8.5 <8.5 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Silver 7440-224 7.22 <5 <5 <5 <2.1 <2.1 <2.1 <2.1 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Thallium 7440-28-0 - - 2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Vanadium 7440-62-2 10 5 1 <50 <50 <50 <2.6 4.8 J <2.6 14 J <5 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Zinc 7440-66-6 174.5 <20 <20 <20 28.0 91 13 BJ 8.4 J <20 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Inorganic Indicator Parameters WWI-) SW311 NS NS NS NS NS NS NS 280,000 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Total Dissolved Solids by SM 2540C Total Alkalinity as CaCO3 by SM 2320 SW337 NS NS NS NS NS NS NS 120,000 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Chloride b EPA 9056A SW301 230,000 NS NS NS NS NS NS NS 44,000 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Sulfate by EPA 9056A 14808-79-8 NS NS NS NS NS NS NS 20,000 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS Notes: 1) North Carolina Department of Environmental Quality (NCDEQ) 15A NCAC 02B Water Quality Standards for Surf Waters (Eff. June 10, 2019) 2) Mercury analyzed by EPA Method 7470A 3) In -stream hardness value of 160 mg/L based on sample collected on April 13, 2021 P = Pace, TA = Eurofins TestAmerica NA = Not Analyzed; NS = Not Sampled; - = Not Established J = Analyte detected at a level less than the RL and greater than or equal to the MDL. Concentrations B = the analyte was detected in the associted blank Bold and Underlined indicates result exceeded the 2B Standard for Aquatic Life & Secondary Recreation Bold indicates exceedance of the 2B Standard for Fish Consumption Underlined indicates exceedance of the In -Stream Target Value pg/L = micrograms per liter,, mg/L = milligrams per liter Table 5 (Page 4 of 4) Greenway Waste Solutions of Apex, LLC Appendix A Groundwater Sampling Forms �G�n „ [[jl Solutions R Gnfirn Btafheis Co Greenwau Waste Solutions GROUNDWATER SAMPLING RECORD Depth to Water (ft btoc): IS, 7e Type of Pump: Stabilization Criteria Temperature +/- 0.2 IC ph+/-0.2starderdUnks Facility: GWS Apex - Highway 55 C&D Landfill UroxtivRy +/- 5% Tutny <10 ntu Well ID: MW- / DO +/- 0.2 mWL Date: 10/44/24 Sampling Personnel: Brandt Kayser, P.G. Peristaltic Casing Material: PVC Total Depth (ft btoc): 3 4. c( Tubing Material: Polyethylene Decontamination Method Alconox & DI bath Pump/Tubing set at: 3„1. ft Weather Conditions: r� r4 ram, ( 7o Notes: Water Volume Time Level (ft btoc) Pumped (ml) (go r, (1` 91 toco (4ro ( cryo (u(r (.lac Axy ( quo ( J .qr Arep (w-r (J'-17 1&M Other Sample Parameters: Well Diameter (in): 2 Begin Purging at 1311— GROUNDWATER SAMPLING PARAMETERS Pumping Temp. DO S. Cond. pH ORP Turbidity Rate (ml/min) u (ma/I) S/cm (SU) (MV) (NTU) (v 0 �� ALL )}. C o r)L 0,3) (i ro(cot G"Ggg 6.--_4—_74- 9.S ( 19'-f r- Ocf y_ .M 7 (H 01Y7. 7 (F rr--- V •Oci V-d(.4— ��_� 0-.k C 4of GCf3 (qp,1— 11,u2 iI. P G,qsc (C9L �? Sampled at: (C4330 Parameters taken with: YSI Pro Plus & HF Scientific MicroTPW Field Filtration: ( ) Yes ( X ) No If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives): Appendix I VOCs + THE (3 40ml VOAs - HCI), 1,4-Dioxane (3 40ml VOAs - HCI), Appendix I metals (1 250ml plastic - HNO3), alkalinity, sulfate, TDS, chloride (1 1 L plastic - unpreserved), PFAS Compounds (2 1 L HDPE - unpreserved) N Griffin Brothers Co Greenwau Waste Solutions GROUNDWATER SAMPLING RECORD Depth to Water (ft btoc): -( -9,0 Type of Pump: Stabilization Criteria Temperature +J- 0.2 "C pn+/-0.2stesdedUnits Facility: GWS Apex - Highway 55 C&D Landfill Ca mWi0y +l- 5% Turbily -10 nlu Well ID: MW- DO +/- 0.2 mglL Date: 10161( /24 Sampling Personnel: Brandt Kayser, P.G. Peristaltic Casing Material: PVC Total Depth (ft btoc): *V.3T' Tubing Material: Polyethylene Well Diameter (in): 2 Decontamination Method: Alconox & DI bath Pump/Tubing set at: if ft. Begin Purging at t3CT— Weather Conditions: C 6ww-" 6!!±S�.1,r�6 Cad Notes: GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping Temp. DO S. Cond. pH ORP Turbidity Time Level (ft btoc) Pumaed (ml) Rate (ml/min) °C (m4/11 S/cm � LV) (NTU) c 3(0 to, 3? 5``� f C7r7 ©.Cf (' -Q17f — SICF.� t A Ao (3(j- co . (Cbo _ , 3 r ( r1764 rA P1 lq BAR (TOO Other Sample Parameters: Sampled at: 3.1jr Parameters taken with: YSI Pro Plus & HF Scientific MicroTPW Field Filtration: ( ) Yes ( X ) No If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives): Appendix I VOCs + THE (3 40ml VOAs - HCI), 1,4-Dioxane (3 40ml VOAs - HCI), Appendix I metals (1 250ml plastic - HNO3), alkalinity, sulfate, TDS, chloride (1 1 L plastic - unpreserved), PFAS Compounds (2 1 L HDPE - unpreserved) R Griffin Brothers Co G_ reep Waste Solutions Stabilization Criteria _ Te Wature +/- 0.2 "C -_�� p,+/-0.2ste,aedWts Facility: GWS Apex - Highway 55 C&D Landfill Canductivky +/- 5% GROUNDWATER SAMPLING RECORD Tufty -10 ntu DO+/-0.2mg/L Well ID: MW-) Date: 10/A(/24 Sampling Personnel: Brandt Kayser, P.G. Depth to Water (ft btoc): Type of Pump: Peristaltic Casing Material: PVC Total Depth (ft btoc): Qa .0'1' Tubing Material: Polyethylene Well Diameter (in): 2 Decontamination Method: Alconox & DI bath Pump/Tubing set at: ft. Begin Purging at Weather Conditions: 6v+e2m. C.'�4 CA.r 7cJ rr Notes: GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping Temp. DO S. Cond. pH ORP Turbidity Time Level (ft btoc) Pumped (ml) Rate (ml/min) j°c) im9m S/cm (SU) (MV) NTU 03,0 7 01 (`cc; (oc t q. f 0, 31- (. 70,f G, d -?A •q aa, $ 13 B, 7,6 7 ( aco 64: r 0"'14 (.6do 6,3( 74. dS 73 1900 (ice iq. S' 01 U (u0r -of, At'di (CRO o tXi CCI. S` O. OQ (' 3 Q0 -Ma _ � (4(r 0-d- (.dam .{r4.t -31j. C� - 14, 2a` ( qW& For- S— it uw Mr 0.(3 (E 3 &4 � 4� - S'y'`' S' 9,70 Other Sample Parameters: Sampled at: ( q-.Lj— Field Filtration: ( ) Yes ( X ) No Parameters taken with: YSI Pro Plus & HF Scientific MicroTPW If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives): Appendix I VOCs + THE (3 40ml VOAs - HCI), 1,4-Dioxane (3 40ml VOAs - HCI), Appendix I metals (1 250ml plastic - HNO3), alkalinity, sulfate, TDS, chloride (1 1 L plastic - unpreserved), PFAS Compounds (2 1 L HDPE - unpreserved) A Cnffin Of others Co Greentuo Waste Solutions Stabilization Criteria Temperature +/- 0.2 °C ph+/-0.2starxWdunas Facility: GWS Apex - Highway 55 C&D Landfill CmdWivity +/- 5% Tufty <10 ntu Well ID: MW- FGROUNDWATER SAMPLING RECORD Do+/-0.2mW� Date: 10/.t(/24 Sampling Personnel: Brandt Kayser, P.G. Depth to Water (ft btoc): Type of Pump: Peristaltic Casing Material: PVC Total Depth (ft btoc): aZ/, Tubing Material: Polyethylene Well Diameter (in): 2 Decontamination Method: Alconox & DI bath Pump/Tubing set at: (y ft. Begin Purging at (yam Weather Conditions: cO. ,r Ca, 70 r Notes: GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping Temp. DO S. Cond. pH ORP Turbidity Time Level (ft btoc) Pumped (ml) Rate (ml/min) 111 (mg/I)(PS/cm) (SU) mV N( TU) 7� ( roy (A9i"' f 7� (,PAPcoy- r, l ak 0133 f', 6 � 7Z-(.ttr� _ 1� 2 (no aq,r 0,30 Gases -(a?,o (rtat 1), Other Sample Parameters: Sampled at: MS o Parameters taken with: YSI Pro Plus & HF Scientific MicroTPW Field Filtration: ( ) Yes (X ) No If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives): Appendix I VOCs + THE (3 40ml VOAs - HCI), 1,4-Dioxane (3 40m1 VOAs - HCI), Appendix I metals (1 250ml plastic - HNO3), alkalinity, sulfate, TDS, chloride (1 1 L plastic - unpreserved), PFAS Compounds (2 1 L HDPE - unpreserved) R Griffin Brothers Co 'J'reencuJwaste Solutions Stabilization Criteria Temperature +/_ 0.2 °C ah+/-0.2Standard Unks Facility: GWS Apex - Highway 55 C&D Landfill Caductivoy +/- $% Turbity 00 ntu Well ID: MW- GROUNDWATER SAMPLING RECORD DO+/-0.2 mWL Date: 10/Al /24 Depth to Water (ft btoc): Total Depth (ft btoc): Decontamination Method: Weather Conditions. C °`r 71 X7 Type of Pump: 2a, [r— Tubing Material: Alconox & DI bath Pump/Tubing set at: ( "zO S Sampling Personnel: Peristaltic Polyethylene / ft. Notes: Brandt Kayser, P.G. Casing Material: PVC Well Diameter (in): 2 Begin Purging at GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping Temp. DO S. Cond. pH ORP Turbidity Time Level (ft btoc) Pumped (ml) Rate (mVmin) CC) (mo/I) S/cm (SU) (mV) (NTU) tr" 7, S9 J,-rT 027 �Dv oo W'7 O 1: 1W •? rp'-Ox ( 7, ?a t> j;T- .2�' 5et r- �P'y ('& 00 7.R A tr,W 9- Ir �J&o (q. d Two(q'0 © c. q -1ro I .,??— -( .F.Cie- 3�*c -t!?y6— aj" M r 8 .qa1 G600 (FT 013 Aq3 5.YCA 010 ( (6 J-0 70or) r p•d 0.(0 Zit .7 Other Sample Parameters: Sampled at: (a xt�- Parameters taken with: YSI Pro Plus & HF Scientific MicroTPW Field Filtration: ( ) Yes ( X ) No If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives): Appendix I VOCs + THE (3 40ml VOAs - HCI), 1,4-Dioxane (3 40ml VOAs - HCI), Appendix I metals (1 250ml plastic - HNO3), alkalinity, sulfate, TDS, chloride (1 1 L plastic - unpreserved), PFAS Compounds (2 1 L HDPE - unpreserved) R Cnff+n Biolheis Co Greenqo Waste Solutions Stabilization Criteria ph+/-0.2 staxWd Uhks Facility: GWS Apex - Highway 55 C&D Landfill Conductidy +/- $% Turbity-10ntu Well ID: MW- (o' FGROUNDWATER SAMPLING RECORD DO+/-0.2mgtL Date: 10Q( /24 Sampling Personnel: Brandt Kayser, P.G. Depth to Water (ft btoc): 7, J"O Type of Pump: Peristaltic Casing Material: PVC Total Depth (ft btoc): da. ld Tubing Material: Polyethylene Well Diameter (in): 2 Decontamination Method: Alconox & DI bath Pump/Tubing set at: 0 ft. Begin Purging at X §2 Weather Conditions: Cam{ r C�+.. 7D Is, Notes: GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping Temp. DO S. Cond. pH ORP Turbidity Time Level (ft btoc) Pumped (ml) Rate (ml/min) °C m /I S/cm (SU) (MV) NTU CC L Other Sample Parameters: Sampled at: ROO Parameters taken with: YSI Pro Plus & HF Scientific MicroTPW Field Filtration: ( ) Yes ( X ) No If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives): Appendix I VOCs + THE (3 40ml VOAs - HCI), 1,4-Dioxane (3 40ml VOAs - HCI), Appendix I metals (1 250ml plastic - HNO3), alkalinity, sulfate, TDS, chloride (1 1 L plastic - unpreserved), PFAS Compounds (2 1 L HDPE - unpreserved) /t Griffin Brothers Co Greener CUaste Solutions stabilization Criteria Tanpemtum +r- 0,2 T ph+/-0.2stardwdum5 Facility: GWS Apex- Highway 55 C&D Landfill Conductivity +/- 5% GROUNDWATER SAMPLING RECORD Turdty -10 ntu DO+/-0.2mg1L Well ID: MW- % Date: 10/4424 Sampling Personnel: Brandt Kayser, P.G. Depth to Water (ft btoc): Type of Pump: Peristaltic Casing Material: PVC Total Depth (ft btoc): o�(��?� Tubing Material: Polyethylene Well Diameter (in): 2 Decontamination Method: Alconox & DI bath Pump/Tubing set at: U ft. Begin Purging at 4197pf— WeatherConditions: �.(.._�,(,�y� C8,,, 902' Notes: GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping Temp. DO S. Cond. pH ORP Turbidity Time Level (ft btoc) Pumped (ml) Rate (ml/min) °f Q (mo/Il S/cm (SOU N( TU) D E1 (©.ter (©cv too o.T.t G(( "•-ar• c ONO (0-70 (rab (6.o 0,31 60l ,60 C. o e - (03? ACM? (&. o 0-t's, GOV 411715 Other Sample Parameters: Sampled at: 0)7oL.- Field Filtration: ( ) Yes ( X ) No Parameters taken with: If yes, which sample parameters were field filtered: YSI Pro Plus & HF Scientific MicroTPW Sample Parameter Containers (Types, Number of Containers, Preservatives): Appendix I VOCs + THE (3 40ml VOAs - HCI), 1,4-Dioxane (3 40ml VOAs - HCI), Appendix I metals (1 250ml plastic - HNO3), alkalinity, sulfate, TDS, chloride (1 1 L plastic - unpreserved), PFAS Compounds (2 1 L HDPE - unpreserved) n Griffin 6folhefs Co GrOORWIM CUaste Solutions GROUNDWATER SAMPLING RECORD Stabilization Criteria Tempemkwe +/- 0.2'c ph+/- 0.2 standard !hats Facility: GWS Apex - Highway 55 C&D Landfill caxwivxy +/- s% m TudMy <10 ntu Well ID: MW- O DO +/- 0.2 mWL Date: 1W /24 Sampling Personnel: Brandt Kayser, P.G. Depth to Water (ft btoc): a(.(r, Type of Pump: Peristaltic Total Depth (ft btoc): Tubing Material: Polyethylene Decontamination Method: Alconox & DI bath Pump/Tubing set at: ft. Weather Conditions: r"6h.—E a 'r" Co., jV iA GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping Temp. DO S. Cond. Time Level (ft btoc) Pumped (ml) Rate (ml/min) f11 (mg/I)(US/cm) moo k.aU 5&0 cow aLl a(w�(��cq oaco Oc.'>a (ivy eg a? 0-C1 04i1-19 a3j Other Sample Parameters: Sampled at: 0q,�_jr, Field Filtration: ( ) Yes (X ) No Casing Material: PVC Well Diameter (in): 2 Begin Purging at pH ORP Turbidity (SU) (MV) (NTU) Gloss _� f t t-7g 6 Parameters taken with: YSI Pro Plus & HF Scientific MicroTPW If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives): Appendix I VOCs + THE (3 40ml VOAs - HCI), 1,4-Dioxane (3 40ml VOAs - HCI), Appendix I metals (1 250ml plastic - HNO3), alkalinity, sulfate, TDS, chloride (1 1 L plastic - unpreserved), PFAS Compounds (2 1 L HDPE - unpreserved) N Griffin Brothers Co Greenwail Waste Solutions GROUNDWATER SAMPLING RECORD Stabilization Criteria Temperature +/- 0.2 "C pn+/-0.2stardardUMs Facility: GWS Apex - Highway 55 C&D Landfill C rd xtWy +/- 5% TurWy -10 ntu Well ID: MW- DO +/- 0.2 mg1L Date: 10/,UJ24 Sampling Personnel: Brandt Kayser, P.G. Depth to Water (ft btoc): %, 5�3 Type of Pump: Peristaltic Casing Material: PVC Total Depth (ft btoc): 4„77 Tubing Material: Polyethylene Well Diameter (in): 2 Decontamination Method: Alconox & DI bath Pump/Tubing set at: (�' ft. Begin Purging at (01- Weather Conditions: rf Notes: T GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping Temp. DO S. Cond. pH ORP Turbidity Time Level (ft btoc) Pumped (ml) Rate (ml/min) fO�C (m4/I)(US/cm (SU) (NTU) toot& 7 74" Coe) l 7 f o 173 _ 0.11— ( c rx (030 (?�_ 01 33 G.jt/ - 64e, (D35" 7<<ti dt I i / ©-J-Y 3" 0o 0,4 P .k2 Other Sample Parameters: Sampled at: (0C/o Field Filtration: ( ) Yes ( X ) No Parameters taken with: YSI Pro Plus & HF Scientific MicroTPW If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives): Appendix I VOCs + THE (3 40ml VOAs - HCI), 1,4-Dioxane (3 40ml VOAs - HCI), Appendix I metals (1 250ml plastic - HNO3), alkalinity, sulfate, TDS, chloride (1 1 L plastic - unpreserved), PFAS Compounds (2 1 L HDPE - unpreserved) A Griffin Brothers Co Greenw9li waste Solutions GROUNDWATER SAMPLING RECORD Stabilization Criteria Temperature +/- 0.2'C pn+/-0.2stardudtma5 Facility: GWS Apex - Highway 55 C&D Landfill Canductivhy +/- 5% Turbky 00 ntu Well ID: MW-10 DO +/- 0.2 mg1L Date: 10/al /24 Sampling Personnel: Brandt Kayser, P.G. Depth to Water (ft btoc): Mpo Type of Pump: Total Depth (ft btoc): D"y 7 Tubing Material: Decontamination Method: Alconox & DI bath Pump/Tubing set at Peristaltic Polyethylene Qb ft. Casing Material: PVC Well Diameter (in): 2 Begin Purging at t2oe� Weather Conditions: C [,,,,, �� . Cow C4 rJ' Notes: GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping Temp. DO S. Cond. pH ORP Turbidity Time Level (ft btoc) Pumped (ml) Rate (ml/min) °LC,) (ma/I) S/cm (SU) (MV) (NTU) Wo reo dr-1 1 (hF' ((Ad �6,24— f7y Imo!" 16"Fo JW v dl.o 0,1xr r d4 ro"m 1CC? G 7G Other Sample Parameters: Sampled at: tdOr Field Filtration: ( ) Yes ( X ) No Parameters taken with: If yes, which sample parameters were field filtered: YSI Pro Plus & HF Scientific MicroTPW Sample Parameter Containers (Types, Number of Containers, Preservatives): Appendix I VOCs + THE (3 40ml VOAs - HCI), 1,4-Dioxane (3 40ml VOAs - HCI), Appendix I metals (1 250ml plastic - HNO3), alkalinity, sulfate, TDS, chloride (1 1 L plastic - unpreserved), PFAS Compounds (2 1 L HDPE - unpreserved) R Griffin Brothers Co Greentua Waste Solutions Stabilization Criteria Temperature +/- 0.2 °C pn+/-0.2Standard Units Facility: GWS Apex - Highway 55 C&D Landfill C ndwtWy +/- 5% T"yc10ntu Well ID: MW- jiZ GROUNDWATER SAMPLING RECORD DO+/-0.2 mgfL Date: 1041 /24 Sampling Personnel: Brandt Kayser, P.G. Depth to Water (ft btoc): Wg Type of Pump: Peristaltic Casing Material: PVC Total Depth (ft btoc): } G (r Tubing Material: Polyethylene Well Diameter (in): 2 Decontamination Method: Alconox & DI bath Pump/Tubing set at: 090 ft. Begin Purging at Weather Conditions: car.- 6,•�, j tk-[�A Jib 9% Notes: GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping Temp. DO S. Cond. pH ORP Turbidity Time Level (ft btoc) Pumped (ml) Rate (ml/min) f—C) fm m S/cm (SU) jm�V N( TU) l(l>� Lpt,g4 (off-2 (06 K ( © (xi cJ 3 r (cr (T 20 G 3 �,o � -'7 Other Sample Parameters: Sampled at: (V� Parameters taken with: YSI Pro Plus & HF Scientific MicroTPW Field Filtration: ( ) Yes ( X ) No If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives): Appendix I VOCs + THE (3 40ml VOAs - HCI), 1,4-Dioxane (3 40ml VOAs - HCI), Appendix I metals (1 250ml plastic - HNO3), alkalinity, sulfate, TDS, chloride (1 1 L plastic - unpreserved), PFAS Compounds (2 1 L HDPE - unpreserved) R Griffin Brothers Co _Greenwau Uluste Solutions GROUNDWATER SAMPLING RECORD Stabilization Criteria Tenpmture +/- 0.2 T p,+/-0.2stendedUnks Facility: GWS Apex - Highway 55 C&D Landfill canductivKy +/- 5% TurWy<10 ntu Well ID: MW- (,t DO +/- 0.2 mg1L Date: 10/,ZX24 Sampling Personnel: Brandt Kayser, P.G. Depth to Water (ft btoc): (a-Y✓7 Type of Pump: Total Depth (ft btoc): 31 ', J, Tubing Material: Peristaltic Polyethylene Decontamination Method: Alconox & DI bath Pump/Tubing set at: � t: ft. Weather Conditions: Notes: Casing Material: PVC Well Diameter (in): 2 Begin Purging at lion, GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping Temp. DO S. Cond. pH ORP Turbidity Time Level (ft btoc) Pumped (ml) Rate (ml/min) CC) (mg/I) S/cm (SU) (MV) NTU Wo ().)2 too rf-C 1•`� a,Eq r' 4'9-/nY_r_ �qiT (rcrr' I)-6 7 f (Z o fl_l` 3 at Q4�Q ?,C?6_ - r. r Jrg t 3_R r r,(2�o 0.76 4 aJrr _ 7 o f -1l6, jl�_ rd ((.r (V. (rj )LOWA D_dt 2 6Y3 , 03 -10..t —('00 0. (4 •2, 07 se= 7.o( -( N. sue _ Other Sample Parameters: Sampled at: (( r Parameters taken with: YSI Pro Plus & HF Scientific MicroTPW Field Filtration: ( ) Yes ( X ) No If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives): Appendix I VOCs + THE (3 40ml VOAs - HCI), 1,4-Dioxane (3 40ml VOAs - HCI), Appendix I metals (1 250ml plastic - HNO3), alkalinity, sulfate, TDS, chloride (1 1 L plastic - unpreserved), PFAS Compounds (2 1 L HDPE - unpreserved) R Griffin Brothers Co Greenwou Waste Solutions Stabilization Criteria Temperature +1- 0.2 °C p,+/-0.2starKhdLWs Facility: GWS Apex - Highway 55 C&D Landfill Conductivity +/- 5% Tubity00ntu Well ID: MW-/ R GROUNDWATER SAMPLING RECORD DO+/-0.2 mg1L Date: 10/,U/24 Sampling Personnel: Brandt Kayser, P.G. Depth to Water (ft btoc): CA 4pp Type of Pump: Peristaltic Casing Material: PVC Total Depth (ft btoc): 38 q3 Tubing Material: Polyethylene Well Diameter (in): 2 Decontamination Method: Alconox & DI bath Pump/Tubing set at: Begin Purging at (o2(D Weather Conditions: r^Cav�gfr (i,,., 6104, Notes: GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping Temp. DO S. Cond. pH ORP Turbidity Time Level (ft btoc) Pumped (ml) Rate (ml/min) L2 imam 61S1crn (SU) (MV) (NTU) (eLd o Flog, 'A I C15, 3 ' , 93G COU Mg 1�5 3, q14 : a Other Sample Parameters: Sampled at: (OBT Parameters taken with: YSI Pro Plus & HF Scientific MicroTPW Field Filtration: ( ) Yes ( X ) No If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives): Appendix I VOCs + THE (3 40ml VOAs - HCI), 1,4-Dioxane (3 40ml VOAs - HCI), Appendix I metals (1 250ml plastic - HNO3), alkalinity, sulfate, TDS, chloride (1 1 L plastic - unpreserved), PFAS Compounds (2 1 L HDPE - unpreserved) R Griffin Brothers Co Greenqm mast_ Solutions GROUNDWATER SAMPLING RECORD Stabilization Criteria Temperature +/_ 0.2 "C pn+/-0.2Standard Units Facility: GWS Apex - Highway 55 C&D Landfill Canductivky +/- 5% T"y<10ntu Well ID: MW- (9- DO +/_ 0.2 mWL Date: 10LJ-/24 Sampling Personnel: Brandt Kayser, P.G. Depth to Water (ft btoc): t (11? Type of Pump: Peristaltic Total Depth (ft btoc): Ar4a. Tubing Material: Polyethylene Decontamination Method: Alconox & DI bath Pump/Tubing set at: d1CA- ft. Weather Conditions: CC-, ew k _ C'c a 4 ce ri Notes: Water Time Level (ft btoc) Or- U _Y3 Other Sample Parameters: Sampled at: Mo Field Filtration: ( ) Yes ( X ) No Casing Material: PVC Well Diameter (in): 2 Begin Purging at /AQO GROUNDWATER SAMPLING PARAMETERS Volume Pumping Temp. DO S. Cond. pH ORP Turbidity Pumped (ml) Rate (mUmin) f11 fmo/I) S/cm (SU) N( TU) (016 t fly 0,6cf- C4 860 A7ce) ,sue c�:a. o,c� �c - �2. q-(.d 4, IF Parameters taken with: YSI Pro Plus & HF Scientific MicroTPW If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives): Appendix I VOCs + THE (3 40ml VOAs - HCI), 1,4-Dioxane (3 40ml VOAs - HCI), Appendix I metals (1 250ml plastic - HNO3), alkalinity, sulfate, TDS, chloride (1 1 L plastic - unpreserved), PFAS Compounds (2 1 L HDPE - unpreserved) Appendix B Laboratory Analytical Reports �G�n „ [[jl Solutions %, eurofins Environment Testing I ANALYTICAL REPORT C PREPARED FOR Attn: Brandt Kayser Greenway Waste Solutions LLC 19109 W Catawba Ave C Suite 110 Cornelius, North Carolina 28031 I Generated 11/12/2024 1:47:31 PM JOB DESCRIPTION NC Apex Landfil JOB NUMBER 500-258888-1 This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written approval of the laboratory. All questions should be directed to the Eurofins Chicago Project Manager. k64�� � / Generated / � 11 /12/2024 1:47:31 PM Authorized for release by Robin Kintz, Project Manager II Robin. Kintz(a).et.eurofinsus.com (708)534-5200 F Eurofins Chicago is a laboratory within Eurofins Environment Testing North Central, LLC, a company within Eurofins Environment Testing Group of Companies Page 2 of 99 11 /12/2024 Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Table of Contents Laboratory Job ID: 500-258888-1 Cover Page .............................................. 1 Table of Contents ......................................... 3 Case Narrative ........................................... 4 L Detection Summary ........................................ 5 Method Summary ......................................... 13 Sample Summary ......................................... 14 Client Sample Results ...................................... 15 E: Definitions ............................................... 58 QC Association ........................................... 59 F Surrogate Summary ....................................... 65 QC Sample Results ........................................ 67 Chronicle................................................ 83 Certification Summary ...................................... 90 Chain of Custody .......................................... 91 E: Receipt Checklists ......................................... 98 Eurofins Chicago Page 3 of 99 11/12/2024 Case Narrative Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project: NC Apex Landfill Job ID: 500-258888-1 Eurofins Chicago Job Narrative 500-258888-1 Receipt The samples were received on 10/23/24 09:40. Unless otherwise noted below, the samples arrived in good condition, and where required, properly preserved and on ice. The temperatures of the 3 coolers at receipt time were 0.91 C, 1.21 C and 3.21 C. Receipt Exceptions Received 1 VOA vial empty for sample 16. GC/MS VOA Method 8260D SIM 14D: The following sample(s) was collected in a properly preserved vial; however, the pH was outside the required criteria when verified by the laboratory. The sample was analyzed outside the 7-day holding time specified for unpreserved samples but within the 14-day holding time specified for preserved samples: Leachate (500-258888-15). Method 8260D: The continuing calibration verification (CCV) analyzed in batch 500-792556 was outside the method criteria for the following analyte(s): 1,2-Dichloroethane, 2-Butanone (MEK), Acetone, Acrylonitrile, Bromomethane, Tetrahydrofuran, trans-1,4- Dichloro-2-butene and Vinyl acetate. A CCV standard at or below the reporting limit (RL) was analyzed with the affected samples and found to be acceptable. As indicated in the reference method, sample analysis may proceed; however, any detection for the affected analyte(s) is considered estimated. Method 8260D: Methylene chloride was detected in the following items: MW-11 R (500-258888-1), MW-0 (500-258888-2), MW-2 (500-258888-3), MW-3 (500-258888-4), MW-4 (500-258888-5), MW-5 (500-258888-6), MW-6 (500-258888-7), MW-7 (500-258888-8), MW-8 (500-258888-9), MW-9 (500-258888-10), MW-13R (500-258888-12), MW-1 (500-258888-14), Leachate (500-258888-15), SW-2 (500-258888-16), SW-1 (500-258888-18), SW-3R (500-258888-19), DUP-1 (500-258888-20) and (MB 500-792556/6). Methylene chloride is a known lab contaminant; therefore all low level detects for this compound could be suspected as lab contamination. Method 8260D: The following analyte(s) recovered outside control limits for the LCS associated with analytical batch 500-792556: Tetrahydrofuran. This is not indicative of a systematic control problem because these were random marginal exceedances. Qualified results have been reported. Method 8260D: The following sample was collected in a properly preserved vial; however, the pH was outside the required criteria when verified by the laboratory. The sample was analyzed outside the 7-day holding time specified for unpreserved samples but within the 14-day holding time specified for preserved samples: Leachate (500-258888-15). Method 8260D: The continuing calibration verification (CCV) analyzed in batch 500-792782 was outside the method criteria for the following analyte(s): 1,1,2,2-Tetrachloroethane, 1,1,2-Trichloroethane, Bromomethane, cis- 1,3-Dichloropropene and lodomethane. A CCV standard at or below the reporting limit (RL) was analyzed with the affected samples and found to be acceptable. As indicated in the reference method, sample analysis may proceed; however, any detection for the affected analyte(s) is considered estimated. Method 8260D: Methylene Chloride was detected in the following items: Trip Blank (500-258888-21). Methylene Chloride is a known lab contaminant; therefore all low level detects for this compound could be suspected as lab contamination. Method 8260D: The following sample was collected in a properly preserved vial; however, the pH was outside the required criteria when verified by the laboratory. The sample was analyzed within the 7-day holding time specified for unpreserved samples: Leachate (500-258888-15). No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page. Metals No analytical or quality issues were noted, other than those described in the Definitions/Glossary page. General Chemistry Method SM 2540C: The TDS matrix duplicate (DU) % RPD precision was outside of control limits for the following sample in analytical batch 500-792683: (500-258888-1-12 DU). The laboratory control standard (LCS) recovery met acceptance criteria No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page. VOA Prep No analytical or quality issues were noted, other than those described in the Definitions/Glossary page. Eurofins Chicago Page 4 of 99 11 /12/2024 Detection Summary Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Client Sample ID: MW-11 R Analyte Result Qualifier RL MDL Unit Methylene Chloride 3.9 J B 5.0 3.6 ug/L Arsenic 3.2 1.0 0.23 ug/L Barium 230 2.5 0.73 ug/L Calcium 81000 200 44 ug/L Cobalt 16 1.0 0.40 ug/L Copper 1.1 J 2.0 0.50 ug/L Iron 4000 100 47 ug/L Manganese 2600 2.5 0.79 ug/L Nickel 5.9 2.0 0.63 ug/L Selenium 1.1 J 2.5 0.98 ug/L Chloride 150000 5000 580 ug/L Sulfate 68000 5000 1000 ug/L Alkalinity 500000 5000 3700 ug/L Total Dissolved Solids 1000000 10000 4300 ug/L Client Sample ID: MW-0 Analyte Result Qualifier RL MDL Unit Methylene Chloride 4.0 J B 5.0 3.6 ug/L Arsenic 0.93 J 1.0 0.23 ug/L Barium 1900 2.5 0.73 ug/L Calcium 380000 200 44 ug/L Copper 0.53 J 2.0 0.50 ug/L Iron 170 100 47 ug/L Manganese 1700 2.5 0.79 ug/L Chloride 1500000 50000 5800 ug/L Sulfate 11000 5000 1000 ug/L Alkalinity 250000 5000 3700 ug/L Total Dissolved Solids 3800000 17000 7200 ug/L Client Sample ID: MW-2 Analyte Result Qualifier RL MDL Unit 1,4-Dioxane 1.5 0.40 0.17 ug/L Methylene Chloride 3.6 J B 5.0 3.6 ug/L Arsenic 2.2 1.0 0.23 ug/L Barium 240 2.5 0.73 ug/L Calcium 190000 200 44 ug/L This Detection Summary does not include radiochemical test results. F Job ID: 500-258888-1 Lab Sample ID: 500-258888-1 DII Fac D Method Prep Type 1 8260D Total/NA 1 60206 Total Recoverable 1 6020B Total Recoverable 1 6020B Total Recoverable 1 6020B Total Recoverable 1 60206 Total Recoverable 1 60206 Total Recoverable 1 6020B Total Recoverable 1 6020B Total Recoverable 1 6020B Total Recoverable 5 9056A Total/NA 5 9056A Total/NA 1 SM 2320B Total/NA 1 SM 2540C Total/NA Lab Sample ID: 500-258888-2 Dil Fac D Method Prep Type 1 8260D Total/NA 1 6020B Total Recoverable 1 6020B Total Recoverable 1 6020B Total Recoverable 1 6020B Total Recoverable 1 6020B Total Recoverable 1 6020B Total Recoverable 50 9056A Total/NA 5 9056A Total/NA 1 SM 2320B Total/NA 1 SM 2540C Total/NA Lab Sample ID: 500-258888-3 Dil Fac D Method Prep Type 1 8260D SIM 14D Total/NA 1 8260D Total/NA 1 6020B Total Recoverable 1 6020B Total Recoverable 1 6020B Total Recoverable Page 5 of 99 Eurofins Chicago 11 /12/2024 Detection Summary Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-2 (Continued) Lab Sample ID: 500-258888-3 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type Cobalt 0.46 J 1.0 0.40 ug/L 1 6020B Total Recoverable Iron 960 100 47 ug/L 1 60206 Total Recoverable Manganese 840 2.5 0.79 ug/L 1 6020B Total Recoverable Nickel 18 2.0 0.63 ug/L 1 6020B Total Recoverable Chloride 290000 10000 1200 ug/L 10 9056A Total/NA Sulfate 52000 5000 1000 ug/L 5 9056A Total/NA Alkalinity 470000 5000 3700 ug/L 1 SM 2320B Total/NA Total Dissolved Solids 1200000 10000 4300 ug/L 1 SM 2540C Total/NA Client Sample ID: MW-3 Lab Sample ID: 500-258888-4 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 0.59 0.40 0.17 ug/L 1 8260D SIM 14D Total/NA Methylene Chloride 3.7 J B 5.0 3.6 ug/L 1 8260D Total/NA Arsenic 0.69 J 1.0 0.23 ug/L 1 6020B Total Recoverable Barium 110 2.5 0.73 ug/L 1 6020B Total Recoverable Calcium 77000 200 44 ug/L 1 6020E Total Recoverable Cobalt 15 1.0 0.40 ug/L 1 6020B Total Recoverable Copper 1.0 J 2.0 0.50 ug/L 1 6020B Total Recoverable Iron 2300 100 47 ug/L 1 6020B Total Recoverable Lead 0.45 J 0.50 0.19 ug/L 1 6020B Total Recoverable Manganese 1300 2.5 0.79 ug/L 1 6020B Total Recoverable Nickel 2.2 2.0 0.63 ug/L 1 6020B Total Recoverable Vanadium 3.0 J 5.0 2.2 ug/L 1 6020B Total Recoverable Chloride 190000 10000 1200 ug/L 10 9056A Total/NA Sulfate 110000 10000 2100 ug/L 10 9056A Total/NA Alkalinity 230000 5000 3700 ug/L 1 SM 2320B Total/NA LTotal Dissolved Solids 830000 10000 4300 ug/L 1 SM 2540C Total/NA Client Sample ID: MW-4 Lab Sample ID: 500-258888-5 FAnalyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 0.77 0.40 0.17 ug/L 1 8260D SIM 14D Total/NA Methylene Chloride 4.0 J B 5.0 3.6 ug/L 1 8260D Total/NA Arsenic 3.8 1.0 0.23 ug/L 1 6020B Total Recoverable Barium 120 2.5 0.73 ug/L 1 6020B Total Recoverable Calcium 33000 200 44 ug/L 1 6020B Total Recoverable Cobalt 0.68 J 1.0 0.40 ug/L 1 6020B Total Recoverable This Detection Summary does not include radiochemical test results. Page 6 of 99 Eurofins Chicago 11 /12/2024 Detection Summary Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-4 (Continued) Lab Sample ID: 500-258888-5 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type Iron 2000 100 47 ug/L 1 6020E Total Recoverable Lead 0.43 J 0.50 0.19 ug/L 1 60206 Total Recoverable Manganese 1700 2.5 0.79 ug/L 1 6020B Total Recoverable Nickel 1.2 J 2.0 0.63 ug/L 1 6020B Total Recoverable Chloride 63000 10000 1200 ug/L 10 9056A Total/NA Sulfate 18000 10000 2100 ug/L 10 9056A Total/NA Alkalinity 200000 5000 3700 ug/L 1 SM 2320B Total/NA Total Dissolved Solids 380000 10000 4300 ug/L 1 SM 2540C Total/NA Client Sample ID: MW-5 Lab Sample ID: 500-258888-6 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 0.37 J 0.40 0.17 ug/L 1 8260D SIM 14D Total/NA Methylene Chloride 3.8 J B 5.0 3.6 ug/L 1 8260D Total/NA Arsenic 3.1 1.0 0.23 ug/L 1 6020B Total Recoverable Barium 59 2.5 0.73 ug/L 1 6020B Total Recoverable Calcium 21000 200 44 ug/L 1 6020E Total Recoverable Cobalt 5.0 1.0 0.40 ug/L 1 6020B Total Recoverable Copper 0.68 J 2.0 0.50 ug/L 1 6020B Total Recoverable Iron 8700 100 47 ug/L 1 6020B Total Recoverable Lead 0.41 J 0.50 0.19 ug/L 1 6020B Total Recoverable Manganese 1200 2.5 0.79 ug/L 1 6020B Total Recoverable Nickel 0.74 J 2.0 0.63 ug/L 1 6020B Total Recoverable Vanadium 3.2 J 5.0 2.2 ug/L 1 6020B Total Recoverable Chloride 7500 5000 580 ug/L 5 9056A Total/NA Sulfate 15000 5000 1000 ug/L 5 9056A Total/NA Alkalinity 82000 5000 3700 ug/L 1 SM 2320B Total/NA LTotal Dissolved Solids 150000 10000 4300 ug/L 1 SM 2540C Total/NA Client Sample ID: MW-6 Lab Sample ID: 500-258888-7 FAnalyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 0.92 0.40 0.17 ug/L 1 8260D SIM 14D Total/NA 1,1-Dichloroethane 0.62 J 1.0 0.36 ug/L 1 8260D Total/NA Methylene Chloride 3.6 J B 5.0 3.6 ug/L 1 8260D Total/NA Arsenic 2.2 1.0 0.23 ug/L 1 6020B Total Recoverable Barium 120 2.5 0.73 ug/L 1 6020B Total Recoverable Calcium 29000 200 44 ug/L 1 6020B Total Recoverable This Detection Summary does not include radiochemical test results. Page 7 of 99 Eurofins Chicago 11 /12/2024 Detection Summary Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Client Sample ID: MW-6 (Continued) Analyte Result Qualifier Cobalt 1.6 Iron 350 Manganese 480 Nickel 0.98 J Chloride 26000 Sulfate 28000 Alkalinity 100000 Total Dissolved Solids 210000 Client Sample ID: MW-7 Analyte Result Qualifier 1,4-Dioxane 0.65 Methylene Chloride 3.6 J B Arsenic 1.7 Barium 77 Calcium 55000 Cobalt 1.3 Iron 1500 Manganese 500 Nickel 4.1 Chloride 42000 Sulfate 67000 Alkalinity 140000 Total Dissolved Solids 360000 F Job ID: 500-258888-1 Lab Sample ID: 500-258888-7 RL MDL Unit Dil Fac D Method Prep Type 1.0 0.40 ug/L 1 6020B Total Recoverable 100 47 ug/L 1 6020B Total Recoverable 2.5 0.79 ug/L 1 6020B Total Recoverable 2.0 0.63 ug/L 1 6020B Total Recoverable 1000 120 ug/L 1 9056A Total/NA 1000 210 ug/L 1 9056A Total/NA 5000 3700 ug/L 1 SM 2320B Total/NA 10000 4300 ug/L 1 SM 2540C Total/NA Lab Sample ID: 500-258888-8 RL MDL Unit Dil Fac D Method Prep Type 0.40 0.17 ug/L 1 8260D SIM 14D Total/NA 5.0 3.6 ug/L 1 8260D Total/NA 1.0 0.23 ug/L 1 6020B Total Recoverable 2.5 0.73 ug/L 1 6020B Total Recoverable 200 44 ug/L 1 6020B Total Recoverable 1.0 0.40 ug/L 1 6020B Total Recoverable 100 47 ug/L 1 6020B Total Recoverable 2.5 0.79 ug/L 1 6020B Total Recoverable 2.0 0.63 ug/L 1 6020B Total Recoverable 5000 580 ug/L 5 9056A Total/NA 5000 1000 ug/L 5 9056A Total/NA 5000 3700 ug/L 1 SM 2320B Total/NA 10000 4300 ug/L 1 SM 2540C Total/NA Client Sample ID: MW-8 Lab Sample ID: 500-258888-9 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 3.1 0.40 0.17 ug/L 1 8260D SIM 14D Total/NA Benzene 0.93 0.50 0.18 ug/L 1 8260D Total/NA Methylene Chloride 3.7 J B 5.0 3.6 ug/L 1 8260D Total/NA Arsenic 3.0 1.0 0.23 ug/L 1 6020B Total Recoverable Barium 150 2.5 0.73 ug/L 1 6020B Total Recoverable Calcium 120000 200 44 ug/L 1 6020B Total Recoverable Chromium 2.2 J 5.0 1.1 ug/L 1 6020B Total Recoverable Cobalt 2.0 1.0 0.40 ug/L 1 6020B Total Recoverable Iron 2800 100 47 ug/L 1 6020B Total Recoverable This Detection Summary does not include radiochemical test results. Eurofins Chicago Page 8 of 99 11/12/2024 Detection Summary Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-8 (Continued) Lab Sample ID: 500-258888-9 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type Manganese 600 2.5 0.79 ug/L 1 6020B Total Recoverable Nickel 8.8 2.0 0.63 ug/L 1 60206 Total Recoverable Chloride 98000 5000 580 ug/L 5 9056A Total/NA Sulfate 66000 5000 1000 ug/L 5 9056A Total/NA Alkalinity 510000 5000 3700 ug/L 1 SM 2320B Total/NA Total Dissolved Solids 880000 10000 4300 ug/L 1 SM 2540C Total/NA Client Sample ID: MW-9 Lab Sample ID: 500-258888-10 C Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 11 2.0 0.85 ug/L 5 8260D SIM 14D Total/NA Benzene 1.3 0.50 0.18 ug/L 1 8260D Total/NA Methylene Chloride 4.6 J B 5.0 3.6 ug/L 1 8260D Total/NA Toluene 0.29 J 0.50 0.21 ug/L 1 8260D Total/NA Xylenes, Total 0.55 J 1.0 0.30 ug/L 1 8260D Total/NA Arsenic 8.1 1.0 0.23 ug/L 1 6020B Total Recoverable Barium 1100 2.5 0.73 ug/L 1 6020B Total Recoverable Calcium 130000 200 44 ug/L 1 6020B Total Recoverable Chromium 3.5 J 5.0 1.1 ug/L 1 6020B Total Recoverable Cobalt 5.6 1.0 0.40 ug/L 1 6020B Total Recoverable Copper 0.75 J 2.0 0.50 ug/L 1 6020B Total Recoverable Iron 9300 100 47 ug/L 1 6020B Total Recoverable Manganese 5200 2.5 0.79 ug/L 1 6020B Total Recoverable Nickel 15 2.0 0.63 ug/L 1 6020B Total Recoverable Selenium 1.2 J 2.5 0.98 ug/L 1 6020B Total Recoverable Chloride 640000 20000 2300 ug/L 20 9056A Total/NA Sulfate 90000 20000 4100 ug/L 20 9056A Total/NA Alkalinity 730000 5000 3700 ug/L 1 SM 2320B Total/NA Total Dissolved Solids 2100000 13000 5400 ug/L 1 SM 2540C Total/NA Client Sample ID: MW-12 Lab Sample ID: 500-258888-11 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type Arsenic 1.8 1.0 0.23 ug/L 1 6020B Total Recoverable Barium 400 2.5 0.73 ug/L 1 6020B Total Recoverable Calcium 130000 200 44 ug/L 1 6020B Total Recoverable Cobalt 1.2 1.0 0.40 ug/L 1 6020B Total Recoverable Copper 0.57 J 2.0 0.50 ug/L 1 6020B Total Recoverable This Detection Summary does not include radiochemical test results. Page 9 of 99 Eurofins Chicago 11 /12/2024 Detection Summary Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-12 (Continued) Lab Sample ID: 500-258888-11 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type Iron 1400 100 47 ug/L 1 6020E Total Recoverable Manganese 1500 2.5 0.79 ug/L 1 60206 Total Recoverable Nickel 3.3 2.0 0.63 ug/L 1 6020B Total Recoverable Chloride 340000 10000 1200 ug/L 10 9056A Total/NA Sulfate 110000 10000 2100 ug/L 10 9056A Total/NA Alkalinity 380000 5000 3700 ug/L 1 SM 2320B Total/NA Total Dissolved Solids 1200000 10000 4300 ug/L 1 SM 2540C Total/NA Client Sample ID: MW-13R Lab Sample ID: 500-258888-12 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type Methylene Chloride 3.9 J B 5.0 3.6 ug/L 1 8260D Total/NA Arsenic 0.31 J 1.0 0.23 ug/L 1 6020B Total Recoverable Barium 910 2.5 0.73 ug/L 1 6020B Total Recoverable Calcium 310000 200 44 ug/L 1 6020E Total Recoverable Chromium 13 5.0 1.1 ug/L 1 60206 Total Recoverable Copper 1.0 J 2.0 0.50 ug/L 1 6020B Total Recoverable Manganese 6.0 2.5 0.79 ug/L 1 6020B Total Recoverable Selenium 1.3 J 2.5 0.98 ug/L 1 6020B Total Recoverable Silver 0.17 J 0.50 0.12 ug/L 1 6020B Total Recoverable Mercury 2.1 0.20 0.076 ug/L 1 7470A Total/NA Chloride 1700000 50000 5800 ug/L 50 9056A Total/NA Sulfate 9100 1000 210 ug/L 1 9056A Total/NA Alkalinity 520000 5000 3700 ug/L 1 SM 2320B Total/NA Total Dissolved Solids 2400000 13000 5400 ug/L 1 SM 2540C Total/NA Client Sample ID: MW-14 Lab Sample ID: 500-258888-13 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type Methylene Chloride 3.6 J B 5.0 3.6 ug/L 1 8260D Total/NA Arsenic 0.55 J 1.0 0.23 ug/L 1 6020B Total Recoverable Barium 1800 2.5 0.73 ug/L 1 6020B Total Recoverable Calcium 240000 200 44 ug/L 1 6020E Total Recoverable Copper 0.78 J 2.0 0.50 ug/L 1 6020B Total Recoverable Iron 180 100 47 ug/L 1 6020E Total Recoverable Manganese 230 2.5 0.79 ug/L 1 6020B Total Recoverable Silver 0.31 J 0.50 0.12 ug/L 1 6020B Total Recoverable Vanadium 8.4 5.0 2.2 ug/L 1 6020B Total Recoverable This Detection Summary does not include radiochemical test results. Eurofins Chicago Page 10 of 99 11/12/2024 Detection Summary Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-14 (Continued) Lab Sample ID: 500-258888-13 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type Mercury 1.2 0.20 0.076 ug/L 1 7470A Total/NA ' Chloride 1200000 100000 12000 ug/L 100 9056A Total/NA Sulfate 13000 1000 210 ug/L 1 9056A Total/NA Alkalinity 470000 5000 3700 ug/L 1 SM 2320B Total/NA Total Dissolved Solids 2900000 17000 7200 ug/L 1 SM 2540C Total/NA Client Sample ID: MW-1 Lab Sample ID: 500-258888-14 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type Methylene Chloride 3.7 J B 5.0 3.6 ug/L 1 8260D Total/NA Arsenic 0.70 J 1.0 0.23 ug/L 1 6020B Total Recoverable Barium 1100 2.5 0.73 ug/L 1 6020B Total Recoverable Calcium 370000 200 44 ug/L 1 6020E Total Recoverable Manganese 9.3 2.5 0.79 ug/L 1 6020B Total Recoverable Silver 0.22 J 0.50 0.12 ug/L 1 6020B Total Recoverable Vanadium 7.0 5.0 2.2 ug/L 1 6020E Total Recoverable Mercury 1.6 0.20 0.076 ug/L 1 7470A Total/NA Chloride 1000000 100000 12000 ug/L 100 9056A Total/NA Sulfate 14000 1000 210 ug/L 1 9056A Total/NA Alkalinity 150000 5000 3700 ug/L 1 SM 2320B Total/NA Total Dissolved Solids 3900000 25000 11000 ug/L 1 SM 2540C Total/NA Client Sample ID: Leachate Lab Sample ID: 500-258888-15 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 30 8.0 3.4 ug/L 20 8260D SIM 14D Total/NA Acetone 17 10 4.3 ug/L 1 8260D Total/NA Benzene 0.81 0.50 0.18 ug/L 1 8260D Total/NA Carbon disulfide 1.5 J 2.0 1.1 ug/L 1 8260D Total/NA Ethylbenzene 1.2 0.50 0.20 ug/L 1 8260D Total/NA Methylene Chloride 3.6 J B 5.0 3.6 ug/L 1 8260D Total/NA Toluene 1.1 0.50 0.21 ug/L 1 8260D Total/NA Xylenes, Total 2.1 1.0 0.30 ug/L 1 8260D Total/NA Tetrahydrofuran - DL 700 100 39 ug/L 10 8260D Total/NA Antimony 3.2 3.0 1.3 ug/L 1 6020B Total Recoverable Arsenic 100 1.0 0.23 ug/L 1 6020B Total Recoverable Barium 380 2.5 0.73 ug/L 1 6020B Total Recoverable Calcium 420000 200 44 ug/L 1 6020B Total Recoverable Chromium 44 5.0 1.1 ug/L 1 6020E Total Recoverable Cobalt 2.2 1.0 0.40 ug/L 1 6020B Total Recoverable Copper 0.50 J 2.0 0.50 ug/L 1 6020B Total Recoverable This Detection Summary does not include radiochemical test results. Page 11 of 99 Eurofins Chicago 11 /12/2024 Detection Summary Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Client Sample ID: Leachate (Continued) Job ID: 500-258888-1 Lab Sample ID: 500-258888-15 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type Iron 610 100 47 ug/L 1 6020B Total Recoverable Manganese 510 2.5 0.79 ug/L 1 60206 Total Recoverable Nickel 3.7 2.0 0.63 ug/L 1 6020B Total Recoverable Selenium 3.7 2.5 0.98 ug/L 1 6020B Total Recoverable Vanadium 21 5.0 2.2 ug/L 1 6020B Total Recoverable Chloride 97000 20000 2300 ug/L 20 9056A Total/NA Sulfate 450000 20000 4100 ug/L 20 9056A Total/NA Alkalinity 1700000 5000 3700 ug/L 1 SM 2320B Total/NA Total Dissolved Solids 2800000 13000 5400 ug/L 1 SM 2540C Total/NA Client Sample ID: SW-2 Lab Sample ID: 500-258888-16 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type Methylene Chloride Toluene Client Sample ID: SW-4 3.9 0.21 J B J 5.0 0.50 3.6 0.21 ug/L ug/L 1 8260D Total/NA 1 8260D Total/NA Lab Sample ID: 500-258888-17 C Analyte 1,4-Dioxane Result 0.21 Qualifier J RL 0.40 MDL 0.17 Unit ug/L Dil Fac D Method Prep Type 1 8260D SIM 14D Total/NA Client Sample ID: SW-1 Lab Sample ID: 500-258888-18 CAnalyte Methylene Chloride Result 3.7 Qualifier J B RL 5.0 MDL 3.6 Unit ug/L Dil Fac D Method Prep Type 1 8260D Total/NA Client Sample ID: SW-3R Lab Sample ID: 500-258888-19 CAnalyte Methylene Chloride Result 3.7 Qualifier J B RL 5.0 MDL 3.6 Unit ug/L Dil Fac D Method Prep Type 1 8260D Total/NA Client Sample ID: DUP-1 Lab Sample ID: 500-258888-20 Analyte 1,4-Dioxane Benzene Methylene Chloride Client Sample ID: Trip Blank Analyte LMethylene Chloride Result Qualifier 2.8 0.84 3.6 J B Result Qualifier 10 B This Detection Summary does not include radiochemical test results. RL MDL Unit Dil Fac D Method Prep Type 0.40 0.17 ug/L 1 8260D SIM 14D Total/NA 0.50 0.18 ug/L 1 8260D Total/NA 5.0 3.6 ug/L 1 8260D Total/NA Lab Sample ID: 500-258888-21 RL MDL Unit Dil Fac D Method Prep Type 5.0 3.6 ug/L 1 8260D Total/NA Eurofins Chicago Page 12 of 99 11/12/2024 Method Summary Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Job ID: 500-258888-1 Method Method Description Protocol Laboratory 8260D Volatile Organic Compounds by GC/MS SW846 EET CHI 8260D SIM 14D Volatile Organic Compounds (GC/MS) SW846 ELLE 6020B Metals (ICP/MS) SW846 EET CHI 7470A Mercury (CVAA) SW846 EET CHI 9056A Anions, Ion Chromatography SW846 EET CHI SM 2320B Alkalinity SM EET CHI SM 2540C Solids, Total Dissolved (TDS) SM EET CHI 3005A Preparation, Total Recoverable or Dissolved Metals SW846 EET CHI 5030B Purge and Trap SW846 EET CHI 5030C Purge and Trap SW846 ELLE 7470A Preparation, Mercury SW846 EET CHI Protocol References: SM = "Standard Methods For The Examination Of Water And Wastewater" SW846 ='Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. Laboratory References: EET CHI = Eurofins Chicago, 2417 Bond Street, University Park, IL 60484, TEL (708)534-5200 ELLE = Eurofins Lancaster Laboratories Environment Testing, LLC, 2425 New Holland Pike, Lancaster, PA 17601, TEL (717)656-2300 Eurofins Chicago Page 13 of 99 11/12/2024 Sample Summary Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Lab Sample ID Client Sample ID Matrix Collected Received 500-258888-1 MW-11R Water 10/21/2411:25 10/23/24 09:40 500-258888-2 MW-0 Water 10/21/24 12:35 10/23/24 09:40 500-258888-3 MW-2 Water 10/21/24 13:25 10/23/24 09:40 500-258888-4 MW-3 Water 10/21/24 14:25 10/23/24 09:40 500-258888-5 MW-4 Water 10/21/24 15:20 10/23/24 09:40 500-258888-6 MW-5 Water 10/21/24 16:25 10/23/24 09:40 500-258888-7 MW-6 Water 10/21/24 17:00 10/23/24 09:40 500-258888-8 MW-7 Water 10/22/24 08:25 10/23/24 09:40 500-258888-9 MW-8 Water 10/22/24 09:25 10/23/24 09:40 500-258888-10 MW-9 Water 10/22/24 10:40 10/23/24 09:40 500-258888-11 MW-12 Water 10/22/24 11:35 10/23/24 09:40 500-258888-12 MW-13R Water 10/22/24 12:35 10/23/24 09:40 500-258888-13 MW-14 Water 10/22/24 13:30 10/23/24 09:40 500-258888-14 MW-1 Water 10/22/24 14:30 10/23/24 09:40 500-258888-15 Leachate Water 10/22/24 15:45 10/23/24 09:40 500-258888-16 SW-2 Water 10/22/24 15:10 10/23/24 09:40 500-258888-17 SW-4 Water 10/22/24 15:15 10/23/24 09:40 500-258888-18 SW-1 Water 10/22/24 15:20 10/23/24 09:40 500-258888-19 SW-3R Water 10/22/24 16:15 10/23/24 09:40 500-258888-20 DUP-1 Water 10/22/24 00:00 10/23/24 09:40 500-258888-21 Trip Blank Water 10/21/24 00:00 10/23/24 09:40 Job ID: 500-258888-1 C 0 Eurofins Chicago Page 14 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Job ID: 500-258888-1 Client Sample ID: MW-11 R Lab Sample ID: 500-258888-1 Date Collected: 10/21/24 11:25 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit 1,4-Dioxane <0.40 0.40 0.17 ug/L Surrogate Toluene-d8 (Surr) %Recovery Qualifier Limits 95 80-120 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL 1,1,1,2-Tetrachloroethane <1.0 1.0 1,1,1-Trichloroethane <1.0 1.0 1,1,2,2-Tetrachloroethane <1.0 1.0 1,1,2-Trichloroethane <1.0 1.0 1,1-Dichloroethane <1.0 1.0 1,1-Dichloroethene <1.0 1.0 1,2,3-Trichloropropane <2.0 2.0 1,2-Dibromo-3-Chloropropane <5.0 5.0 1,2-Dibromoethane <1.0 1.0 1,2-Dichlorobenzene <1.0 1.0 1,2-Dichloroethane <1.0 1.0 1,2-Dichloropropane <1.0 1.0 1,4-Dichlorobenzene <1.0 1.0 2-Butanone (MEK) <5.0 5.0 2-Hexanone <5.0 5.0 4-Methyl-2-pentanone (MIBK) <5.0 5.0 Acetone <10 10 Acrylonitrile <20 20 Benzene <0.50 0.50 Bromochloromethane <1.0 1.0 Bromodichloromethane <1.0 1.0 Bromoform <1.0 1.0 Bromomethane <3.0 3.0 Carbon disulfide <2.0 2.0 Carbon tetrachloride <1.0 1.0 Chlorobenzene <1.0 1.0 Chloroethane <5.0 5.0 Chloroform <2.0 2.0 Chloromethane <5.0 5.0 cis-1,2-Dichloroethene <1.0 1.0 cis-1,3-Dichloropropene <1.0 1.0 Dibromochloromethane <1.0 1.0 Dibromomethane <1.0 1.0 Ethylbenzene <0.50 0.50 lodomethane <3.0 3.0 Methylene Chloride 3.9 J B 5.0 Styrene <1.0 1.0 Tetrachloroethene <1.0 1.0 Tetrahydrofuran <10 *- 10 Toluene <0.50 0.50 trans- 1,2-Dichloroethene <1.0 1.0 trans- 1,3-Dichloropropene <1.0 1.0 trans- 1,4-Dichloro-2-butene <5.0 5.0 D Prepared Analyzed Dil Fac C 10/29/24 12:40 1 Prepared Analyzed Dil Fac 10129124 12:40 1 MDL Unit D Prepared Analyzed Dil Fac 0.67 ug/L 10/28/2410:43 1 0.45 ug/L 10/28/2410:43 1 0.65 ug/L 10/28/2410:43 1 0.73 ug/L 10/28/2410:43 1 0.36 ug/L 10/28/2410:43 1 0.48 ug/L 10/28/2410:43 1 1.5 ug/L 10/28/2410:43 1 3.9 ug/L 10/28/2410:43 1 0.56 ug/L 10/28/2410:43 1 0.48 ug/L 10/28/2410:43 1 0.58 ug/L 10/28/2410:43 1 0.37 ug/L 10/28/2410:43 1 0.45 ug/L 10/28/2410:43 1 2.3 ug/L 10/28/2410:43 1 2.2 ug/L 10/28/2410:43 1 2.0 ug/L 10/28/2410:43 1 4.3 ug/L 10/28/2410:43 1 6.0 ug/L 10/28/2410:43 1 0.18 ug/L 10/28/2410:43 1 0.50 ug/L 10/28/2410:43 1 0.57 ug/L 10/28/2410:43 1 0.96 ug/L 10/28/2410:43 1 1.8 ug/L 10/28/2410:43 1 1.1 ug/L 10/28/2410:43 1 0.41 ug/L 10/28/2410:43 1 0.41 ug/L 10/28/2410:43 1 0.47 ug/L 10/28/2410:43 1 0.92 ug/L 10/28/2410:43 1 0.79 ug/L 10/28/2410:43 1 0.42 ug/L 10/28/2410:43 1 0.52 ug/L 10/28/2410:43 1 0.83 ug/L 10/28/2410:43 1 0.58 ug/L 10/28/2410:43 1 0.20 ug/L 10/28/2410:43 1 0.68 ug/L 10/28/2410:43 1 3.6 ug/L 10/28/2410:43 1 0.31 ug/L 10/28/2410:43 1 0.39 ug/L 10/28/2410:43 1 3.9 ug/L 10/28/2410:43 1 0.21 ug/L 10/28/2410:43 1 0.44 ug/L 10/28/2410:43 1 0.63 ug/L 10/28/2410:43 1 3.4 ug/L 10/28/2410:43 1 Eurofins Chicago Page 15 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-11 R Lab Sample ID: 500-258888-1 Date Collected: 10/21/24 11:25 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichloroethene <0.50 0.50 0.15 ug/L 10/28/24 10:43 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/28/24 10:43 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/28/24 10:43 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/28/24 10:43 1 Xylenes, Total <1.0 1.0 0.30 ug/L 10/28/24 10:43 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 89 75- 126 10128124 10:43 1 4-Bromofluorobenzene (Surr) 91 72 - 124 10128124 10:43 1 Dibromofluoromethane 99 75 - 120 10128124 10:43 1 Toluene-d8 (Surr) 102 75 - 120 10/28/24 10:43 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <3.0 3.0 1.3 ug/L 11/01/24 08:39 11/04/24 17:06 1 Arsenic 3.2 1.0 0.23 ug/L 11/01/24 08:39 11/04/24 17:06 1 Barium 230 2.5 0.73 ug/L 11/01/24 08:39 11/04/24 17:06 1 Beryllium <1.0 1.0 0.53 ug/L 11/01/24 08:39 11/04/24 17:06 1 Cadmium <0.50 0.50 0.17 ug/L 11/01/24 08:39 11/04/24 17:06 1 Calcium 81000 200 44 ug/L 11/01/24 08:39 11/04/24 17:06 1 Chromium <5.0 5.0 1.1 ug/L 11/01/24 08:39 11/04/24 17:06 1 Cobalt 16 1.0 0.40 ug/L 11/01/24 08:39 11/04/24 17:06 1 Copper 1.1 J 2.0 0.50 ug/L 11/01/24 08:39 11/04/24 17:06 1 Iron 4000 100 47 ug/L 11/01/24 08:39 11/04/24 17:06 1 Lead <0.50 0.50 0.19 ug/L 11/01/24 08:39 11/04/24 17:06 1 Manganese 2600 2.5 0.79 ug/L 11/01/24 08:39 11/04/24 17:06 1 Nickel 5.9 2.0 0.63 ug/L 11/01/24 08:39 11/04/24 17:06 1 Selenium 1.1 J 2.5 0.98 ug/L 11/01/24 08:39 11/04/24 17:06 1 Silver <0.50 0.50 0.12 ug/L 11/01/24 08:39 11/04/24 17:06 1 Thallium <2.0 2.0 0.57 ug/L 11/01/24 08:39 11/04/24 17:06 1 Vanadium <5.0 5.0 2.2 ug/L 11/01/24 08:39 11/04/24 17:06 1 Zinc <10 10 6.9 ug/L 11/01/24 08:39 11/04/24 17:06 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury <0.20 0.20 0.076 ug/L 10/31/24 10:20 11/01/24 07:55 1 General Chemistry Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chloride (SW846 9056A) 150000 5000 580 ug/L 11/09/24 02:09 5 Sulfate (SW846 9056A) 68000 5000 1000 ug/L 11/09/24 02:09 5 Alkalinity (SM 2320B) 500000 5000 3700 ug/L 10/31/24 21:55 1 Total Dissolved Solids (SM 2540C) 1000000 10000 4300 ug/L 10/28/24 10:30 1 Eurofins Chicago Page 16 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-0 Lab Sample ID: 500-258888-2 Date Collected: 10/21/24 12:35 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane <0.40 0.40 0.17 ug/L 10/29/2413:00 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Toluene-d8 (Surr) 94 80 - 120 10129124 13:00 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed 1,1,1,2-Tetrachloroethane <1.0 1.0 0.67 ug/L 10/28/24 11:08 1,1,1-Trichloroethane <1.0 1.0 0.45 ug/L 10/28/24 11:08 1,1,2,2-Tetrachloroethane <1.0 1.0 0.65 ug/L 10/28/24 11:08 1,1,2-Trichloroethane <1.0 1.0 0.73 ug/L 10/28/24 11:08 1,1-Dichloroethane <1.0 1.0 0.36 ug/L 10/28/24 11:08 1,1-Dichloroethene <1.0 1.0 0.48 ug/L 10/28/24 11:08 1,2,3-Trichloropropane <2.0 2.0 1.5 ug/L 10/28/24 11:08 1,2-Dibromo-3-Chloropropane <5.0 5.0 3.9 ug/L 10/28/24 11:08 1,2-Dibromoethane <1.0 1.0 0.56 ug/L 10/28/24 11:08 1,2-Dichlorobenzene <1.0 1.0 0.48 ug/L 10/28/24 11:08 1,2-Dichloroethane <1.0 1.0 0.58 ug/L 10/28/24 11:08 1,2-Dichloropropane <1.0 1.0 0.37 ug/L 10/28/24 11:08 1,4-Dichlorobenzene <1.0 1.0 0.45 ug/L 10/28/24 11:08 2-Butanone (MEK) <5.0 5.0 2.3 ug/L 10/28/24 11:08 2-Hexanone <5.0 5.0 2.2 ug/L 10/28/24 11:08 4-Methyl-2-pentanone (MIBK) <5.0 5.0 2.0 ug/L 10/28/24 11:08 Acetone <10 10 4.3 ug/L 10/28/24 11:08 Acrylonitrile <20 20 6.0 ug/L 10/28/24 11:08 Benzene <0.50 0.50 0.18 ug/L 10/28/24 11:08 Bromochloromethane <1.0 1.0 0.50 ug/L 10/28/24 11:08 Bromodichloromethane <1.0 1.0 0.57 ug/L 10/28/24 11:08 Bromoform <1.0 1.0 0.96 ug/L 10/28/24 11:08 Bromomethane <3.0 3.0 1.8 ug/L 10/28/24 11:08 Carbon disulfide <2.0 2.0 1.1 ug/L 10/28/24 11:08 Carbon tetrachloride <1.0 1.0 0.41 ug/L 10/28/24 11:08 Chlorobenzene <1.0 1.0 0.41 ug/L 10/28/24 11:08 Chloroethane <5.0 5.0 0.47 ug/L 10/28/24 11:08 Chloroform <2.0 2.0 0.92 ug/L 10/28/24 11:08 Chloromethane <5.0 5.0 0.79 ug/L 10/28/24 11:08 cis-1,2-Dichloroethene <1.0 1.0 0.42 ug/L 10/28/24 11:08 cis-1,3-Dichloropropene <1.0 1.0 0.52 ug/L 10/28/24 11:08 Dibromochloromethane <1.0 1.0 0.83 ug/L 10/28/24 11:08 Dibromomethane <1.0 1.0 0.58 ug/L 10/28/24 11:08 Ethylbenzene <0.50 0.50 0.20 ug/L 10/28/24 11:08 lodomethane <3.0 3.0 0.68 ug/L 10/28/24 11:08 Methylene Chloride 4.0 J B 5.0 3.6 ug/L 10/28/24 11:08 Styrene <1.0 1.0 0.31 ug/L 10/28/24 11:08 Tetrachloroethene <1.0 1.0 0.39 ug/L 10/28/24 11:08 Tetrahydrofuran <10 *- 10 3.9 ug/L 10/28/24 11:08 Toluene <0.50 0.50 0.21 ug/L 10/28/24 11:08 trans- 1,2-Dichloroethene <1.0 1.0 0.44 ug/L 10/28/24 11:08 trans- 1,3-Dichloropropene <1.0 1.0 0.63 ug/L 10/28/24 11:08 trans- 1,4-Dichloro-2-butene <5.0 5.0 3.4 ug/L 10/28/24 11:08 Eurofins Chicago Page 17 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-0 Lab Sample ID: 500-258888-2 Date Collected: 10/21/24 12:35 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichloroethene <0.50 0.50 0.15 ug/L 10/28/24 11:08 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/28/24 11:08 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/28/24 11:08 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/28/24 11:08 1 Xylenes, Total <1.0 1.0 0.30 ug/L 10/28/24 11:08 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 89 75- 126 10128124 11:08 1 4-Bromofluorobenzene (Surr) 92 72 - 124 10128124 11:08 1 Dibromofluoromethane 100 75 - 120 10128124 11:08 1 Toluene-d8 (Surr) 101 75 - 120 10128124 11:08 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <3.0 3.0 1.3 ug/L 11/01/24 08:39 11/04/24 17:22 1 Arsenic 0.93 J 1.0 0.23 ug/L 11/01/24 08:39 11/04/24 17:22 1 Barium 1900 2.5 0.73 ug/L 11/01/24 08:39 11/04/24 17:22 1 Beryllium <1.0 1.0 0.53 ug/L 11/01/24 08:39 11/04/24 17:22 1 Cadmium <0.50 0.50 0.17 ug/L 11/01/24 08:39 11/04/24 17:22 1 Calcium 380000 200 44 ug/L 11/01/24 08:39 11/04/24 17:22 1 Chromium <5.0 5.0 1.1 ug/L 11/01/24 08:39 11/04/24 17:22 1 Cobalt <1.0 1.0 0.40 ug/L 11/01/24 08:39 11/04/24 17:22 1 Copper 0.53 J 2.0 0.50 ug/L 11/01/24 08:39 11/04/24 17:22 1 Iron 170 100 47 ug/L 11/01/24 08:39 11/04/24 17:22 1 Lead <0.50 0.50 0.19 ug/L 11/01/24 08:39 11/04/24 17:22 1 Manganese 1700 2.5 0.79 ug/L 11/01/24 08:39 11/04/24 17:22 1 Nickel <2.0 2.0 0.63 ug/L 11/01/24 08:39 11/04/24 17:22 1 Selenium <2.5 2.5 0.98 ug/L 11/01/24 08:39 11/04/24 17:22 1 Silver <0.50 0.50 0.12 ug/L 11/01/24 08:39 11/04/24 17:22 1 Thallium <2.0 2.0 0.57 ug/L 11/01/24 08:39 11/04/24 17:22 1 Vanadium <5.0 5.0 2.2 ug/L 11/01/24 08:39 11/04/24 17:22 1 Zinc <10 10 6.9 ug/L 11/01/24 08:39 11/04/24 17:22 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury <0.20 0.20 0.076 ug/L 10/31/24 10:20 11/01/24 07:57 1 General Chemistry Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chloride (SW846 9056A) 1500000 50000 5800 ug/L 11/11/24 15:03 50 Sulfate (SW846 9056A) 11000 5000 1000 ug/L 11/09/24 02:25 5 Alkalinity (SM 2320B) 250000 5000 3700 ug/L 10/31/24 22:08 1 Total Dissolved Solids (SM 2540C) 3800000 17000 7200 ug/L 10/28/24 10:33 1 Eurofins Chicago Page 18 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Job ID: 500-258888-1 Client Sample ID: MW-2 Lab Sample ID: 500-258888-3 Date Collected: 10/21/24 13:25 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed 1,4-Dioxane 1.5 0.40 0.17 ug/L 10/29/2414:41 Surrogate %Recovery Qualifier Limits Toluene-d8 (Surr) 95 80 - 120 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit Prepared Analyzed 10129124 14:41 D Prepared Analyzed 1,1,1,2-Tetrachloroethane <1.0 1.0 0.67 ug/L 10/28/24 11:31 1,1,1-Trichloroethane <1.0 1.0 0.45 ug/L 10/28/24 11:31 1,1,2,2-Tetrachloroethane <1.0 1.0 0.65 ug/L 10/28/24 11:31 1,1,2-Trichloroethane <1.0 1.0 0.73 ug/L 10/28/24 11:31 1,1-Dichloroethane <1.0 1.0 0.36 ug/L 10/28/24 11:31 1,1-Dichloroethene <1.0 1.0 0.48 ug/L 10/28/24 11:31 1,2,3-Trichloropropane <2.0 2.0 1.5 ug/L 10/28/24 11:31 1,2-Dibromo-3-Chloropropane <5.0 5.0 3.9 ug/L 10/28/24 11:31 1,2-Dibromoethane <1.0 1.0 0.56 ug/L 10/28/24 11:31 1,2-Dichlorobenzene <1.0 1.0 0.48 ug/L 10/28/24 11:31 1,2-Dichloroethane <1.0 1.0 0.58 ug/L 10/28/24 11:31 1,2-Dichloropropane <1.0 1.0 0.37 ug/L 10/28/24 11:31 1,4-Dichlorobenzene <1.0 1.0 0.45 ug/L 10/28/24 11:31 2-Butanone (MEK) <5.0 5.0 2.3 ug/L 10/28/24 11:31 2-Hexanone <5.0 5.0 2.2 ug/L 10/28/24 11:31 4-Methyl-2-pentanone (MIBK) <5.0 5.0 2.0 ug/L 10/28/24 11:31 Acetone <10 10 4.3 ug/L 10/28/24 11:31 Acrylonitrile <20 20 6.0 ug/L 10/28/24 11:31 Benzene <0.50 0.50 0.18 ug/L 10/28/24 11:31 Bromochloromethane <1.0 1.0 0.50 ug/L 10/28/24 11:31 Bromodichloromethane <1.0 1.0 0.57 ug/L 10/28/24 11:31 Bromoform <1.0 1.0 0.96 ug/L 10/28/24 11:31 Bromomethane <3.0 3.0 1.8 ug/L 10/28/24 11:31 Carbon disulfide <2.0 2.0 1.1 ug/L 10/28/24 11:31 Carbon tetrachloride <1.0 1.0 0.41 ug/L 10/28/24 11:31 Chlorobenzene <1.0 1.0 0.41 ug/L 10/28/24 11:31 Chloroethane <5.0 5.0 0.47 ug/L 10/28/24 11:31 Chloroform <2.0 2.0 0.92 ug/L 10/28/24 11:31 Chloromethane <5.0 5.0 0.79 ug/L 10/28/24 11:31 cis-1,2-Dichloroethene <1.0 1.0 0.42 ug/L 10/28/24 11:31 cis-1,3-Dichloropropene <1.0 1.0 0.52 ug/L 10/28/24 11:31 Dibromochloromethane <1.0 1.0 0.83 ug/L 10/28/24 11:31 Dibromomethane <1.0 1.0 0.58 ug/L 10/28/24 11:31 Ethylbenzene <0.50 0.50 0.20 ug/L 10/28/24 11:31 lodomethane <3.0 3.0 0.68 ug/L 10/28/24 11:31 Methylene Chloride 3.6 J B 5.0 3.6 ug/L 10/28/24 11:31 Styrene <1.0 1.0 0.31 ug/L 10/28/24 11:31 Tetrachloroethene <1.0 1.0 0.39 ug/L 10/28/24 11:31 Tetrahydrofuran <10 *- 10 3.9 ug/L 10/28/24 11:31 Toluene <0.50 0.50 0.21 ug/L 10/28/24 11:31 trans- 1,2-Dichloroethene <1.0 1.0 0.44 ug/L 10/28/24 11:31 trans- 1,3-Dichloropropene <1.0 1.0 0.63 ug/L 10/28/24 11:31 trans- 1,4-Dichloro-2-butene <5.0 5.0 3.4 ug/L 10/28/24 11:31 Eurofins Chicago Page 19 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-2 Lab Sample ID: 500-258888-3 Date Collected: 10/21/24 13:25 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichloroethene <0.50 0.50 0.15 ug/L 10/28/24 11:31 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/28/24 11:31 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/28/24 11:31 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/28/24 11:31 1 Xylenes, Total <1.0 1.0 0.30 ug/L 10/28/24 11:31 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 87 75- 126 10128124 11:31 1 4-Bromofluorobenzene (Surr) 98 72 - 124 10128124 11:31 1 Dibromofluoromethane 99 75 - 120 10128124 11:31 1 Toluene-d8 (Surr) 102 75 - 120 10128124 11:31 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <3.0 3.0 1.3 ug/L 11/01/24 08:39 11/04/24 17:24 1 Arsenic 2.2 1.0 0.23 ug/L 11/01/24 08:39 11/04/24 17:24 1 Barium 240 2.5 0.73 ug/L 11/01/24 08:39 11/04/24 17:24 1 Beryllium <1.0 1.0 0.53 ug/L 11/01/24 08:39 11/04/24 17:24 1 Cadmium <0.50 0.50 0.17 ug/L 11/01/24 08:39 11/04/24 17:24 1 Calcium 190000 200 44 ug/L 11/01/24 08:39 11/04/24 17:24 1 Chromium <5.0 5.0 1.1 ug/L 11/01/24 08:39 11/04/24 17:24 1 Cobalt 0.46 J 1.0 0.40 ug/L 11/01/24 08:39 11/04/24 17:24 1 Copper <2.0 2.0 0.50 ug/L 11/01/24 08:39 11/04/24 17:24 1 Iron 960 100 47 ug/L 11/01/24 08:39 11/04/24 17:24 1 Lead <0.50 0.50 0.19 ug/L 11/01/24 08:39 11/04/24 17:24 1 Manganese 840 2.5 0.79 ug/L 11/01/24 08:39 11/04/24 17:24 1 Nickel 18 2.0 0.63 ug/L 11/01/24 08:39 11/04/24 17:24 1 Selenium <2.5 2.5 0.98 ug/L 11/01/24 08:39 11/04/24 17:24 1 Silver <0.50 0.50 0.12 ug/L 11/01/24 08:39 11/04/24 17:24 1 Thallium <2.0 2.0 0.57 ug/L 11/01/24 08:39 11/04/24 17:24 1 Vanadium <5.0 5.0 2.2 ug/L 11/01/24 08:39 11/04/24 17:24 1 Zinc <10 10 6.9 ug/L 11/01/24 08:39 11/04/24 17:24 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury <0.20 0.20 0.076 ug/L 10/31/24 10:20 11/01/24 07:59 1 General Chemistry Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chloride (SW846 9056A) 290000 10000 1200 ug/L 11/11/24 15:19 10 Sulfate (SW846 9056A) 52000 5000 1000 ug/L 11/09/24 02:40 5 Alkalinity (SM 2320B) 470000 5000 3700 ug/L 10/31/24 22:27 1 Total Dissolved Solids (SM 2540C) 1200000 10000 4300 ug/L 10/28/24 10:35 1 Eurofins Chicago Page 20 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Job ID: 500-258888-1 Client Sample ID: MW-3 Lab Sample ID: 500-258888-4 Date Collected: 10/21/24 14:25 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed 1,4-Dioxane 0.59 0.40 0.17 ug/L 10/29/2415:01 Surrogate %Recovery Qualifier Limits Toluene-d8 (Surr) 95 80 - 120 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit Prepared Analyzed 10129124 15:01 D Prepared Analyzed 1,1,1,2-Tetrachloroethane <1.0 1.0 0.67 ug/L 10/28/24 11:56 1,1,1-Trichloroethane <1.0 1.0 0.45 ug/L 10/28/24 11:56 1,1,2,2-Tetrachloroethane <1.0 1.0 0.65 ug/L 10/28/24 11:56 1,1,2-Trichloroethane <1.0 1.0 0.73 ug/L 10/28/24 11:56 1,1-Dichloroethane <1.0 1.0 0.36 ug/L 10/28/24 11:56 1,1-Dichloroethene <1.0 1.0 0.48 ug/L 10/28/24 11:56 1,2,3-Trichloropropane <2.0 2.0 1.5 ug/L 10/28/24 11:56 1,2-Dibromo-3-Chloropropane <5.0 5.0 3.9 ug/L 10/28/24 11:56 1,2-Dibromoethane <1.0 1.0 0.56 ug/L 10/28/24 11:56 1,2-Dichlorobenzene <1.0 1.0 0.48 ug/L 10/28/24 11:56 1,2-Dichloroethane <1.0 1.0 0.58 ug/L 10/28/24 11:56 1,2-Dichloropropane <1.0 1.0 0.37 ug/L 10/28/24 11:56 1,4-Dichlorobenzene <1.0 1.0 0.45 ug/L 10/28/24 11:56 2-Butanone (MEK) <5.0 5.0 2.3 ug/L 10/28/24 11:56 2-Hexanone <5.0 5.0 2.2 ug/L 10/28/24 11:56 4-Methyl-2-pentanone (MIBK) <5.0 5.0 2.0 ug/L 10/28/24 11:56 Acetone <10 10 4.3 ug/L 10/28/24 11:56 Acrylonitrile <20 20 6.0 ug/L 10/28/24 11:56 Benzene <0.50 0.50 0.18 ug/L 10/28/24 11:56 Bromochloromethane <1.0 1.0 0.50 ug/L 10/28/24 11:56 Bromodichloromethane <1.0 1.0 0.57 ug/L 10/28/24 11:56 Bromoform <1.0 1.0 0.96 ug/L 10/28/24 11:56 Bromomethane <3.0 3.0 1.8 ug/L 10/28/24 11:56 Carbon disulfide <2.0 2.0 1.1 ug/L 10/28/24 11:56 Carbon tetrachloride <1.0 1.0 0.41 ug/L 10/28/24 11:56 Chlorobenzene <1.0 1.0 0.41 ug/L 10/28/24 11:56 Chloroethane <5.0 5.0 0.47 ug/L 10/28/24 11:56 Chloroform <2.0 2.0 0.92 ug/L 10/28/24 11:56 Chloromethane <5.0 5.0 0.79 ug/L 10/28/24 11:56 cis-1,2-Dichloroethene <1.0 1.0 0.42 ug/L 10/28/24 11:56 cis-1,3-Dichloropropene <1.0 1.0 0.52 ug/L 10/28/24 11:56 Dibromochloromethane <1.0 1.0 0.83 ug/L 10/28/24 11:56 Dibromomethane <1.0 1.0 0.58 ug/L 10/28/24 11:56 Ethylbenzene <0.50 0.50 0.20 ug/L 10/28/24 11:56 lodomethane <3.0 3.0 0.68 ug/L 10/28/24 11:56 Methylene Chloride 3.7 J B 5.0 3.6 ug/L 10/28/24 11:56 Styrene <1.0 1.0 0.31 ug/L 10/28/24 11:56 Tetrachloroethene <1.0 1.0 0.39 ug/L 10/28/24 11:56 Tetrahydrofuran <10 *- 10 3.9 ug/L 10/28/24 11:56 Toluene <0.50 0.50 0.21 ug/L 10/28/24 11:56 trans- 1,2-Dichloroethene <1.0 1.0 0.44 ug/L 10/28/24 11:56 trans- 1,3-Dichloropropene <1.0 1.0 0.63 ug/L 10/28/24 11:56 trans- 1,4-Dichloro-2-butene <5.0 5.0 3.4 ug/L 10/28/24 11:56 Eurofins Chicago Page 21 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-3 Lab Sample ID: 500-258888-4 Date Collected: 10/21/24 14:25 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichloroethene <0.50 0.50 0.15 ug/L 10/28/24 11:56 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/28/24 11:56 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/28/24 11:56 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/28/24 11:56 1 Xylenes, Total <1.0 1.0 0.30 ug/L 10/28/24 11:56 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 86 75- 126 10128124 11:56 1 4-Bromofluorobenzene (Surr) 94 72 - 124 10128124 11:56 1 Dibromofluoromethane 98 75 - 120 10128124 11:56 1 Toluene-d8 (Surr) 99 75 - 120 10128124 11:56 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <3.0 3.0 1.3 ug/L 11/01/24 08:39 11/04/24 17:26 1 Arsenic 0.69 J 1.0 0.23 ug/L 11/01/24 08:39 11/04/24 17:26 1 Barium 110 2.5 0.73 ug/L 11/01/24 08:39 11/04/24 17:26 1 Beryllium <1.0 1.0 0.53 ug/L 11/01/24 08:39 11/04/24 17:26 1 Cadmium <0.50 0.50 0.17 ug/L 11/01/24 08:39 11/04/24 17:26 1 Calcium 77000 200 44 ug/L 11/01/24 08:39 11/04/24 17:26 1 Chromium <5.0 5.0 1.1 ug/L 11/01/24 08:39 11/04/24 17:26 1 Cobalt 15 1.0 0.40 ug/L 11/01/24 08:39 11/04/24 17:26 1 Copper 1.0 J 2.0 0.50 ug/L 11/01/24 08:39 11/04/24 17:26 1 Iron 2300 100 47 ug/L 11/01/24 08:39 11/04/24 17:26 1 Lead 0.45 J 0.50 0.19 ug/L 11/01/24 08:39 11/04/24 17:26 1 Manganese 1300 2.5 0.79 ug/L 11/01/24 08:39 11/04/24 17:26 1 Nickel 2.2 2.0 0.63 ug/L 11/01/24 08:39 11/04/24 17:26 1 Selenium <2.5 2.5 0.98 ug/L 11/01/24 08:39 11/04/24 17:26 1 Silver <0.50 0.50 0.12 ug/L 11/01/24 08:39 11/04/24 17:26 1 Thallium <2.0 2.0 0.57 ug/L 11/01/24 08:39 11/04/24 17:26 1 Vanadium 3.0 J 5.0 2.2 ug/L 11/01/24 08:39 11/04/24 17:26 1 Zinc <10 10 6.9 ug/L 11/01/24 08:39 11/04/24 17:26 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury <0.20 0.20 0.076 ug/L 10/31/24 10:20 11/01/24 08:01 1 General Chemistry Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chloride (SW846 9056A) 190000 10000 1200 ug/L 11/09/24 02:56 10 Sulfate (SW846 9056A) 110000 10000 2100 ug/L 11/09/24 02:56 10 Alkalinity (SM 2320B) 230000 5000 3700 ug/L 10/31/24 22:38 1 Total Dissolved Solids (SM 2540C) 830000 10000 4300 ug/L 10/28/24 10:38 1 Eurofins Chicago Page 22 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Job ID: 500-258888-1 Client Sample ID: MW-4 Lab Sample ID: 500-258888-5 Date Collected: 10/21/24 15:20 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed 1,4-Dioxane 0.77 0.40 0.17 ug/L 10/25/24 02:31 Surrogate %Recovery Qualifier Limits Toluene-d8 (Surr) 99 80 - 120 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit Prepared Analyzed 10125124 02:31 D Prepared Analyzed 1,1,1,2-Tetrachloroethane <1.0 1.0 0.67 ug/L 10/28/24 12:21 1,1,1-Trichloroethane <1.0 1.0 0.45 ug/L 10/28/24 12:21 1,1,2,2-Tetrachloroethane <1.0 1.0 0.65 ug/L 10/28/24 12:21 1,1,2-Trichloroethane <1.0 1.0 0.73 ug/L 10/28/24 12:21 1,1-Dichloroethane <1.0 1.0 0.36 ug/L 10/28/24 12:21 1,1-Dichloroethene <1.0 1.0 0.48 ug/L 10/28/24 12:21 1,2,3-Trichloropropane <2.0 2.0 1.5 ug/L 10/28/24 12:21 1,2-Dibromo-3-Chloropropane <5.0 5.0 3.9 ug/L 10/28/24 12:21 1,2-Dibromoethane <1.0 1.0 0.56 ug/L 10/28/24 12:21 1,2-Dichlorobenzene <1.0 1.0 0.48 ug/L 10/28/24 12:21 1,2-Dichloroethane <1.0 1.0 0.58 ug/L 10/28/24 12:21 1,2-Dichloropropane <1.0 1.0 0.37 ug/L 10/28/24 12:21 1,4-Dichlorobenzene <1.0 1.0 0.45 ug/L 10/28/24 12:21 2-Butanone (MEK) <5.0 5.0 2.3 ug/L 10/28/24 12:21 2-Hexanone <5.0 5.0 2.2 ug/L 10/28/24 12:21 4-Methyl-2-pentanone (MIBK) <5.0 5.0 2.0 ug/L 10/28/24 12:21 Acetone <10 10 4.3 ug/L 10/28/24 12:21 Acrylonitrile <20 20 6.0 ug/L 10/28/24 12:21 Benzene <0.50 0.50 0.18 ug/L 10/28/24 12:21 Bromochloromethane <1.0 1.0 0.50 ug/L 10/28/24 12:21 Bromodichloromethane <1.0 1.0 0.57 ug/L 10/28/24 12:21 Bromoform <1.0 1.0 0.96 ug/L 10/28/24 12:21 Bromomethane <3.0 3.0 1.8 ug/L 10/28/24 12:21 Carbon disulfide <2.0 2.0 1.1 ug/L 10/28/24 12:21 Carbon tetrachloride <1.0 1.0 0.41 ug/L 10/28/24 12:21 Chlorobenzene <1.0 1.0 0.41 ug/L 10/28/24 12:21 Chloroethane <5.0 5.0 0.47 ug/L 10/28/24 12:21 Chloroform <2.0 2.0 0.92 ug/L 10/28/24 12:21 Chloromethane <5.0 5.0 0.79 ug/L 10/28/24 12:21 cis-1,2-Dichloroethene <1.0 1.0 0.42 ug/L 10/28/24 12:21 cis-1,3-Dichloropropene <1.0 1.0 0.52 ug/L 10/28/24 12:21 Dibromochloromethane <1.0 1.0 0.83 ug/L 10/28/24 12:21 Dibromomethane <1.0 1.0 0.58 ug/L 10/28/24 12:21 Ethylbenzene <0.50 0.50 0.20 ug/L 10/28/24 12:21 lodomethane <3.0 3.0 0.68 ug/L 10/28/24 12:21 Methylene Chloride 4.0 J B 5.0 3.6 ug/L 10/28/24 12:21 Styrene <1.0 1.0 0.31 ug/L 10/28/24 12:21 Tetrachloroethene <1.0 1.0 0.39 ug/L 10/28/24 12:21 Tetrahydrofuran <10 *- 10 3.9 ug/L 10/28/24 12:21 Toluene <0.50 0.50 0.21 ug/L 10/28/24 12:21 trans- 1,2-Dichloroethene <1.0 1.0 0.44 ug/L 10/28/24 12:21 trans- 1,3-Dichloropropene <1.0 1.0 0.63 ug/L 10/28/24 12:21 trans- 1,4-Dichloro-2-butene <5.0 5.0 3.4 ug/L 10/28/24 12:21 Eurofins Chicago Page 23 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-4 Lab Sample ID: 500-258888-5 Date Collected: 10/21/24 15:20 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichloroethene <0.50 0.50 0.15 ug/L 10/28/24 12:21 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/28/24 12:21 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/28/24 12:21 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/28/24 12:21 1 Xylenes, Total <1.0 1.0 0.30 ug/L 10/28/24 12:21 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 88 75- 126 10128124 12:21 1 4-Bromofluorobenzene (Surr) 95 72 - 124 10128124 12:21 1 Dibromofluoromethane 100 75 - 120 10128124 12:21 1 Toluene-d8 (Surr) 102 75 - 120 10/28/24 12:21 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <3.0 3.0 1.3 ug/L 11/01/24 08:39 11/04/24 17:29 1 Arsenic 3.8 1.0 0.23 ug/L 11/01/24 08:39 11/04/24 17:29 1 Barium 120 2.5 0.73 ug/L 11/01/24 08:39 11/04/24 17:29 1 Beryllium <1.0 1.0 0.53 ug/L 11/01/24 08:39 11/04/24 17:29 1 Cadmium <0.50 0.50 0.17 ug/L 11/01/24 08:39 11/04/24 17:29 1 Calcium 33000 200 44 ug/L 11/01/24 08:39 11/04/24 17:29 1 Chromium <5.0 5.0 1.1 ug/L 11/01/24 08:39 11/04/24 17:29 1 Cobalt 0.68 J 1.0 0.40 ug/L 11/01/24 08:39 11/04/24 17:29 1 Copper <2.0 2.0 0.50 ug/L 11/01/24 08:39 11/04/24 17:29 1 Iron 2000 100 47 ug/L 11/01/24 08:39 11/04/24 17:29 1 Lead 0.43 J 0.50 0.19 ug/L 11/01/24 08:39 11/04/24 17:29 1 Manganese 1700 2.5 0.79 ug/L 11/01/24 08:39 11/04/24 17:29 1 Nickel 1.2 J 2.0 0.63 ug/L 11/01/24 08:39 11/04/24 17:29 1 Selenium <2.5 2.5 0.98 ug/L 11/01/24 08:39 11/04/24 17:29 1 Silver <0.50 0.50 0.12 ug/L 11/01/24 08:39 11/04/24 17:29 1 Thallium <2.0 2.0 0.57 ug/L 11/01/24 08:39 11/04/24 17:29 1 Vanadium <5.0 5.0 2.2 ug/L 11/01/24 08:39 11/04/24 17:29 1 Zinc <10 10 6.9 ug/L 11/01/24 08:39 11/04/24 17:29 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury <0.20 0.20 0.076 ug/L 10/31/24 10:20 11/01/24 08:03 1 General Chemistry Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chloride (SW846 9056A) 63000 10000 1200 ug/L 11/09/24 03:12 10 Sulfate (SW846 9056A) 18000 10000 2100 ug/L 11/09/24 03:12 10 Alkalinity (SM 2320B) 200000 5000 3700 ug/L 10/31/24 22:47 1 Total Dissolved Solids (SM 2540C) 380000 10000 4300 ug/L 10/28/24 10:41 1 Eurofins Chicago Page 24 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Job ID: 500-258888-1 Client Sample ID: MW-5 Lab Sample ID: 500-258888-6 Date Collected: 10/21/24 16:25 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit 1,4-Dioxane 0.37 J 0.40 0.17 ug/L Surrogate Toluene-d8 (Surr) %Recovery Qualifier Limits 96 80-120 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL 1,1,1,2-Tetrachloroethane <1.0 1.0 1,1,1-Trichloroethane <1.0 1.0 1,1,2,2-Tetrachloroethane <1.0 1.0 1,1,2-Trichloroethane <1.0 1.0 1,1-Dichloroethane <1.0 1.0 1,1-Dichloroethene <1.0 1.0 1,2,3-Trichloropropane <2.0 2.0 1,2-Dibromo-3-Chloropropane <5.0 5.0 1,2-Dibromoethane <1.0 1.0 1,2-Dichlorobenzene <1.0 1.0 1,2-Dichloroethane <1.0 1.0 1,2-Dichloropropane <1.0 1.0 1,4-Dichlorobenzene <1.0 1.0 2-Butanone (MEK) <5.0 5.0 2-Hexanone <5.0 5.0 4-Methyl-2-pentanone (MIBK) <5.0 5.0 Acetone <10 10 Acrylonitrile <20 20 Benzene <0.50 0.50 Bromochloromethane <1.0 1.0 Bromodichloromethane <1.0 1.0 Bromoform <1.0 1.0 Bromomethane <3.0 3.0 Carbon disulfide <2.0 2.0 Carbon tetrachloride <1.0 1.0 Chlorobenzene <1.0 1.0 Chloroethane <5.0 5.0 Chloroform <2.0 2.0 Chloromethane <5.0 5.0 cis-1,2-Dichloroethene <1.0 1.0 cis-1,3-Dichloropropene <1.0 1.0 Dibromochloromethane <1.0 1.0 Dibromomethane <1.0 1.0 Ethylbenzene <0.50 0.50 lodomethane <3.0 3.0 Methylene Chloride 3.8 J B 5.0 Styrene <1.0 1.0 Tetrachloroethene <1.0 1.0 Tetrahydrofuran <10 *- 10 Toluene <0.50 0.50 trans- 1,2-Dichloroethene <1.0 1.0 trans- 1,3-Dichloropropene <1.0 1.0 trans- 1,4-Dichloro-2-butene <5.0 5.0 D Prepared Analyzed Dil Fac C 10/25/24 00:12 1 Prepared Analyzed Dil Fac 10125124 00:12 1 MDL Unit D Prepared Analyzed Dil Fac 0.67 ug/L 10/28/2412:46 1 0.45 ug/L 10/28/2412:46 1 0.65 ug/L 10/28/2412:46 1 0.73 ug/L 10/28/2412:46 1 0.36 ug/L 10/28/2412:46 1 0.48 ug/L 10/28/2412:46 1 1.5 ug/L 10/28/2412:46 1 3.9 ug/L 10/28/2412:46 1 0.56 ug/L 10/28/2412:46 1 0.48 ug/L 10/28/2412:46 1 0.58 ug/L 10/28/2412:46 1 0.37 ug/L 10/28/2412:46 1 0.45 ug/L 10/28/2412:46 1 2.3 ug/L 10/28/2412:46 1 2.2 ug/L 10/28/2412:46 1 2.0 ug/L 10/28/2412:46 1 4.3 ug/L 10/28/2412:46 1 6.0 ug/L 10/28/2412:46 1 0.18 ug/L 10/28/2412:46 1 0.50 ug/L 10/28/2412:46 1 0.57 ug/L 10/28/2412:46 1 0.96 ug/L 10/28/2412:46 1 1.8 ug/L 10/28/2412:46 1 1.1 ug/L 10/28/2412:46 1 0.41 ug/L 10/28/2412:46 1 0.41 ug/L 10/28/2412:46 1 0.47 ug/L 10/28/2412:46 1 0.92 ug/L 10/28/2412:46 1 0.79 ug/L 10/28/2412:46 1 0.42 ug/L 10/28/2412:46 1 0.52 ug/L 10/28/2412:46 1 0.83 ug/L 10/28/2412:46 1 0.58 ug/L 10/28/2412:46 1 0.20 ug/L 10/28/2412:46 1 0.68 ug/L 10/28/2412:46 1 3.6 ug/L 10/28/2412:46 1 0.31 ug/L 10/28/2412:46 1 0.39 ug/L 10/28/2412:46 1 3.9 ug/L 10/28/2412:46 1 0.21 ug/L 10/28/2412:46 1 0.44 ug/L 10/28/2412:46 1 0.63 ug/L 10/28/2412:46 1 3.4 ug/L 10/28/2412:46 1 Eurofins Chicago Page 25 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-5 Lab Sample ID: 500-258888-6 Date Collected: 10/21/24 16:25 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichloroethene <0.50 0.50 0.15 ug/L 10/28/24 12:46 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/28/24 12:46 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/28/24 12:46 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/28/24 12:46 1 Xylenes, Total <1.0 1.0 0.30 ug/L 10/28/24 12:46 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 88 75- 126 10128124 12:46 1 4-Bromofluorobenzene (Surr) 89 72 - 124 10128124 12:46 1 Dibromofluoromethane 103 75 - 120 10128124 12:46 1 Toluene-d8 (Surr) 102 75 - 120 10/28/24 12:46 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <3.0 3.0 1.3 ug/L 11/01/24 08:39 11/04/24 17:31 1 Arsenic 3.1 1.0 0.23 ug/L 11/01/24 08:39 11/04/24 17:31 1 Barium 59 2.5 0.73 ug/L 11/01/24 08:39 11/04/24 17:31 1 Beryllium <1.0 1.0 0.53 ug/L 11/01/24 08:39 11/04/24 17:31 1 Cadmium <0.50 0.50 0.17 ug/L 11/01/24 08:39 11/04/24 17:31 1 Calcium 21000 200 44 ug/L 11/01/24 08:39 11/04/24 17:31 1 Chromium <5.0 5.0 1.1 ug/L 11/01/24 08:39 11/04/24 17:31 1 Cobalt 5.0 1.0 0.40 ug/L 11/01/24 08:39 11/04/24 17:31 1 Copper 0.68 J 2.0 0.50 ug/L 11/01/24 08:39 11/04/24 17:31 1 Iron 8700 100 47 ug/L 11/01/24 08:39 11/04/24 17:31 1 Lead 0.41 J 0.50 0.19 ug/L 11/01/24 08:39 11/04/24 17:31 1 Manganese 1200 2.5 0.79 ug/L 11/01/24 08:39 11/04/24 17:31 1 Nickel 0.74 J 2.0 0.63 ug/L 11/01/24 08:39 11/04/24 17:31 1 Selenium <2.5 2.5 0.98 ug/L 11/01/24 08:39 11/04/24 17:31 1 Silver <0.50 0.50 0.12 ug/L 11/01/24 08:39 11/04/24 17:31 1 Thallium <2.0 2.0 0.57 ug/L 11/01/24 08:39 11/04/24 17:31 1 Vanadium 3.2 J 5.0 2.2 ug/L 11/01/24 08:39 11/04/24 17:31 1 Zinc <10 10 6.9 ug/L 11/01/24 08:39 11/04/24 17:31 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury <0.20 0.20 0.076 ug/L 10/31/24 10:20 11/01/24 08:10 1 General Chemistry Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chloride (SW846 9056A) 7500 5000 580 ug/L 11/09/24 03:27 5 Sulfate (SW846 9056A) 15000 5000 1000 ug/L 11/09/24 03:27 5 Alkalinity (SM 2320B) 82000 5000 3700 ug/L 10/31/24 22:56 1 Total Dissolved Solids (SM 2540C) 150000 10000 4300 ug/L 10/28/24 10:43 1 Eurofins Chicago Page 26 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Job ID: 500-258888-1 Client Sample ID: MW-6 Lab Sample ID: 500-258888-7 Date Collected: 10/21/24 17:00 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit 1,4-Dioxane 0.92 0.40 0.17 ug/L Surrogate Toluene-d8 (Surr) %Recovery Qualifier Limits 97 80-120 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL 1,1,1,2-Tetrachloroethane <1.0 1.0 1,1,1-Trichloroethane <1.0 1.0 1,1,2,2-Tetrachloroethane <1.0 1.0 1,1,2-Trichloroethane <1.0 1.0 1,1-Dichloroethane 0.62 J 1.0 1,1-Dichloroethene <1.0 1.0 1,2,3-Trichloropropane <2.0 2.0 1,2-Dibromo-3-Chloropropane <5.0 5.0 1,2-Dibromoethane <1.0 1.0 1,2-Dichlorobenzene <1.0 1.0 1,2-Dichloroethane <1.0 1.0 1,2-Dichloropropane <1.0 1.0 1,4-Dichlorobenzene <1.0 1.0 2-Butanone (MEK) <5.0 5.0 2-Hexanone <5.0 5.0 4-Methyl-2-pentanone (MIBK) <5.0 5.0 Acetone <10 10 Acrylonitrile <20 20 Benzene <0.50 0.50 Bromochloromethane <1.0 1.0 Bromodichloromethane <1.0 1.0 Bromoform <1.0 1.0 Bromomethane <3.0 3.0 Carbon disulfide <2.0 2.0 Carbon tetrachloride <1.0 1.0 Chlorobenzene <1.0 1.0 Chloroethane <5.0 5.0 Chloroform <2.0 2.0 Chloromethane <5.0 5.0 cis-1,2-Dichloroethene <1.0 1.0 cis-1,3-Dichloropropene <1.0 1.0 Dibromochloromethane <1.0 1.0 Dibromomethane <1.0 1.0 Ethylbenzene <0.50 0.50 lodomethane <3.0 3.0 Methylene Chloride 3.6 J B 5.0 Styrene <1.0 1.0 Tetrachloroethene <1.0 1.0 Tetrahydrofuran <10 *- 10 Toluene <0.50 0.50 trans- 1,2-Dichloroethene <1.0 1.0 trans- 1,3-Dichloropropene <1.0 1.0 trans- 1,4-Dichloro-2-butene <5.0 5.0 D Prepared Analyzed Dil Fac C 10/25/24 02:51 1 Prepared Analyzed Dil Fac 10125124 02:51 1 MDL Unit D Prepared Analyzed Dil Fac 0.67 ug/L 10/28/2413:10 1 0.45 ug/L 10/28/2413:10 1 0.65 ug/L 10/28/2413:10 1 0.73 ug/L 10/28/2413:10 1 0.36 ug/L 10/28/2413:10 1 0.48 ug/L 10/28/2413:10 1 1.5 ug/L 10/28/2413:10 1 3.9 ug/L 10/28/2413:10 1 0.56 ug/L 10/28/2413:10 1 0.48 ug/L 10/28/2413:10 1 0.58 ug/L 10/28/2413:10 1 0.37 ug/L 10/28/2413:10 1 0.45 ug/L 10/28/2413:10 1 2.3 ug/L 10/28/2413:10 1 2.2 ug/L 10/28/2413:10 1 2.0 ug/L 10/28/2413:10 1 4.3 ug/L 10/28/2413:10 1 6.0 ug/L 10/28/2413:10 1 0.18 ug/L 10/28/2413:10 1 0.50 ug/L 10/28/2413:10 1 0.57 ug/L 10/28/2413:10 1 0.96 ug/L 10/28/2413:10 1 1.8 ug/L 10/28/2413:10 1 1.1 ug/L 10/28/2413:10 1 0.41 ug/L 10/28/2413:10 1 0.41 ug/L 10/28/2413:10 1 0.47 ug/L 10/28/2413:10 1 0.92 ug/L 10/28/2413:10 1 0.79 ug/L 10/28/2413:10 1 0.42 ug/L 10/28/2413:10 1 0.52 ug/L 10/28/2413:10 1 0.83 ug/L 10/28/2413:10 1 0.58 ug/L 10/28/2413:10 1 0.20 ug/L 10/28/2413:10 1 0.68 ug/L 10/28/2413:10 1 3.6 ug/L 10/28/2413:10 1 0.31 ug/L 10/28/2413:10 1 0.39 ug/L 10/28/2413:10 1 3.9 ug/L 10/28/2413:10 1 0.21 ug/L 10/28/2413:10 1 0.44 ug/L 10/28/2413:10 1 0.63 ug/L 10/28/2413:10 1 3.4 ug/L 10/28/2413:10 1 Eurofins Chicago Page 27 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-6 Lab Sample ID: 500-258888-7 Date Collected: 10/21/24 17:00 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichloroethene <0.50 0.50 0.15 ug/L 10/28/24 13:10 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/28/24 13:10 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/28/24 13:10 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/28/24 13:10 1 Xylenes, Total <1.0 1.0 0.30 ug/L 10/28/24 13:10 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 90 75- 126 10128124 13:10 1 4-Bromofluorobenzene (Surr) 90 72 - 124 10128124 13:10 1 Dibromofluoromethane 103 75 - 120 10128124 13:10 1 Toluene-d8 (Surr) 99 75 - 120 10/28/24 13:10 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <3.0 3.0 1.3 ug/L 11/01/24 08:39 11/04/24 17:33 1 Arsenic 2.2 1.0 0.23 ug/L 11/01/24 08:39 11/04/24 17:33 1 Barium 120 2.5 0.73 ug/L 11/01/24 08:39 11/04/24 17:33 1 Beryllium <1.0 1.0 0.53 ug/L 11/01/24 08:39 11/04/24 17:33 1 Cadmium <0.50 0.50 0.17 ug/L 11/01/24 08:39 11/04/24 17:33 1 Calcium 29000 200 44 ug/L 11/01/24 08:39 11/04/24 17:33 1 Chromium <5.0 5.0 1.1 ug/L 11/01/24 08:39 11/04/24 17:33 1 Cobalt 1.6 1.0 0.40 ug/L 11/01/24 08:39 11/04/24 17:33 1 Copper <2.0 2.0 0.50 ug/L 11/01/24 08:39 11/04/24 17:33 1 Iron 350 100 47 ug/L 11/01/24 08:39 11/04/24 17:33 1 Lead <0.50 0.50 0.19 ug/L 11/01/24 08:39 11/04/24 17:33 1 Manganese 480 2.5 0.79 ug/L 11/01/24 08:39 11/04/24 17:33 1 Nickel 0.98 J 2.0 0.63 ug/L 11/01/24 08:39 11/04/24 17:33 1 Selenium <2.5 2.5 0.98 ug/L 11/01/24 08:39 11/04/24 17:33 1 Silver <0.50 0.50 0.12 ug/L 11/01/24 08:39 11/04/24 17:33 1 Thallium <2.0 2.0 0.57 ug/L 11/01/24 08:39 11/04/24 17:33 1 Vanadium <5.0 5.0 2.2 ug/L 11/01/24 08:39 11/04/24 17:33 1 Zinc <10 10 6.9 ug/L 11/01/24 08:39 11/04/24 17:33 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury <0.20 0.20 0.076 ug/L 10/31/24 10:20 11/01/24 08:12 1 General Chemistry Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chloride (SW846 9056A) 26000 1000 120 ug/L 11/07/24 17:02 1 Sulfate (SW846 9056A) 28000 1000 210 ug/L 11/07/24 17:02 1 Alkalinity (SM 2320B) 100000 5000 3700 ug/L 10/31/24 23:04 1 Total Dissolved Solids (SM 2540C) 210000 10000 4300 ug/L 10/28/24 10:46 1 Eurofins Chicago Page 28 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-7 Lab Sample ID: 500-258888-8 Date Collected: 10/22/24 08:25 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane 0.65 0.40 0.17 ug/L 10/25/24 00:32 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Toluene-d8 (Surr) 93 80 - 120 10125124 00:32 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed 1,1,1,2-Tetrachloroethane <1.0 1.0 0.67 ug/L 10/28/24 13:35 1,1,1-Trichloroethane <1.0 1.0 0.45 ug/L 10/28/24 13:35 1,1,2,2-Tetrachloroethane <1.0 1.0 0.65 ug/L 10/28/24 13:35 1,1,2-Trichloroethane <1.0 1.0 0.73 ug/L 10/28/24 13:35 1,1-Dichloroethane <1.0 1.0 0.36 ug/L 10/28/24 13:35 1,1-Dichloroethene <1.0 1.0 0.48 ug/L 10/28/24 13:35 1,2,3-Trichloropropane <2.0 2.0 1.5 ug/L 10/28/24 13:35 1,2-Dibromo-3-Chloropropane <5.0 5.0 3.9 ug/L 10/28/24 13:35 1,2-Dibromoethane <1.0 1.0 0.56 ug/L 10/28/24 13:35 1,2-Dichlorobenzene <1.0 1.0 0.48 ug/L 10/28/24 13:35 1,2-Dichloroethane <1.0 1.0 0.58 ug/L 10/28/24 13:35 1,2-Dichloropropane <1.0 1.0 0.37 ug/L 10/28/24 13:35 1,4-Dichlorobenzene <1.0 1.0 0.45 ug/L 10/28/24 13:35 2-Butanone (MEK) <5.0 5.0 2.3 ug/L 10/28/24 13:35 2-Hexanone <5.0 5.0 2.2 ug/L 10/28/24 13:35 4-Methyl-2-pentanone (MIBK) <5.0 5.0 2.0 ug/L 10/28/24 13:35 Acetone <10 10 4.3 ug/L 10/28/24 13:35 Acrylonitrile <20 20 6.0 ug/L 10/28/24 13:35 Benzene <0.50 0.50 0.18 ug/L 10/28/24 13:35 Bromochloromethane <1.0 1.0 0.50 ug/L 10/28/24 13:35 Bromodichloromethane <1.0 1.0 0.57 ug/L 10/28/24 13:35 Bromoform <1.0 1.0 0.96 ug/L 10/28/24 13:35 Bromomethane <3.0 3.0 1.8 ug/L 10/28/24 13:35 Carbon disulfide <2.0 2.0 1.1 ug/L 10/28/24 13:35 Carbon tetrachloride <1.0 1.0 0.41 ug/L 10/28/24 13:35 Chlorobenzene <1.0 1.0 0.41 ug/L 10/28/24 13:35 Chloroethane <5.0 5.0 0.47 ug/L 10/28/24 13:35 Chloroform <2.0 2.0 0.92 ug/L 10/28/24 13:35 Chloromethane <5.0 5.0 0.79 ug/L 10/28/24 13:35 cis-1,2-Dichloroethene <1.0 1.0 0.42 ug/L 10/28/24 13:35 cis-1,3-Dichloropropene <1.0 1.0 0.52 ug/L 10/28/24 13:35 Dibromochloromethane <1.0 1.0 0.83 ug/L 10/28/24 13:35 Dibromomethane <1.0 1.0 0.58 ug/L 10/28/24 13:35 Ethylbenzene <0.50 0.50 0.20 ug/L 10/28/24 13:35 lodomethane <3.0 3.0 0.68 ug/L 10/28/24 13:35 Methylene Chloride 3.6 J B 5.0 3.6 ug/L 10/28/24 13:35 Styrene <1.0 1.0 0.31 ug/L 10/28/24 13:35 Tetrachloroethene <1.0 1.0 0.39 ug/L 10/28/24 13:35 Tetrahydrofuran <10 *- 10 3.9 ug/L 10/28/24 13:35 Toluene <0.50 0.50 0.21 ug/L 10/28/24 13:35 trans- 1,2-Dichloroethene <1.0 1.0 0.44 ug/L 10/28/24 13:35 trans- 1,3-Dichloropropene <1.0 1.0 0.63 ug/L 10/28/24 13:35 trans- 1,4-Dichloro-2-butene <5.0 5.0 3.4 ug/L 10/28/24 13:35 Eurofins Chicago Page 29 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-7 Lab Sample ID: 500-258888-8 Date Collected: 10/22/24 08:25 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichloroethene <0.50 0.50 0.15 ug/L 10/28/24 13:35 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/28/24 13:35 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/28/24 13:35 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/28/24 13:35 1 Xylenes, Total <1.0 1.0 0.30 ug/L 10/28/24 13:35 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 87 75- 126 10128124 13:35 1 4-Bromofluorobenzene (Surr) 92 72 - 124 10128124 13:35 1 Dibromofluoromethane 100 75 - 120 10128124 13:35 1 Toluene-d8 (Surr) 101 75 - 120 10/28/24 13:35 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <3.0 3.0 1.3 ug/L 11/01/24 08:39 11/04/24 17:35 1 Arsenic 1.7 1.0 0.23 ug/L 11/01/24 08:39 11/04/24 17:35 1 Barium 77 2.5 0.73 ug/L 11/01/24 08:39 11/04/24 17:35 1 Beryllium <1.0 1.0 0.53 ug/L 11/01/24 08:39 11/04/24 17:35 1 Cadmium <0.50 0.50 0.17 ug/L 11/01/24 08:39 11/04/24 17:35 1 Calcium 55000 200 44 ug/L 11/01/24 08:39 11/04/24 17:35 1 Chromium <5.0 5.0 1.1 ug/L 11/01/24 08:39 11/04/24 17:35 1 Cobalt 1.3 1.0 0.40 ug/L 11/01/24 08:39 11/04/24 17:35 1 Copper <2.0 2.0 0.50 ug/L 11/01/24 08:39 11/04/24 17:35 1 Iron 1500 100 47 ug/L 11/01/24 08:39 11/04/24 17:35 1 Lead <0.50 0.50 0.19 ug/L 11/01/24 08:39 11/04/24 17:35 1 Manganese 500 2.5 0.79 ug/L 11/01/24 08:39 11/04/24 17:35 1 Nickel 4.1 2.0 0.63 ug/L 11/01/24 08:39 11/04/24 17:35 1 Selenium <2.5 2.5 0.98 ug/L 11/01/24 08:39 11/04/24 17:35 1 Silver <0.50 0.50 0.12 ug/L 11/01/24 08:39 11/04/24 17:35 1 Thallium <2.0 2.0 0.57 ug/L 11/01/24 08:39 11/04/24 17:35 1 Vanadium <5.0 5.0 2.2 ug/L 11/01/24 08:39 11/04/24 17:35 1 Zinc <10 10 6.9 ug/L 11/01/24 08:39 11/04/24 17:35 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury <0.20 0.20 0.076 ug/L 10/31/24 10:20 11/01/24 08:14 1 General Chemistry Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chloride (SW846 9056A) 42000 5000 580 ug/L 11/07/24 17:18 5 Sulfate (SW846 9056A) 67000 5000 1000 ug/L 11/07/24 17:18 5 Alkalinity (SM 2320B) 140000 5000 3700 ug/L 11/01/24 13:57 1 Total Dissolved Solids (SM 2540C) 360000 10000 4300 ug/L 10/28/24 14:03 1 Eurofins Chicago Page 30 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-8 Lab Sample ID: 500-258888-9 Date Collected: 10/22/24 09:25 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane 3.1 0.40 0.17 ug/L 10/29/2416:40 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Toluene-d8 (Surr) 95 80 - 120 10129124 16:40 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed 1,1,1,2-Tetrachloroethane <1.0 1.0 0.67 ug/L 10/28/24 14:00 1,1,1-Trichloroethane <1.0 1.0 0.45 ug/L 10/28/24 14:00 1,1,2,2-Tetrachloroethane <1.0 1.0 0.65 ug/L 10/28/24 14:00 1,1,2-Trichloroethane <1.0 1.0 0.73 ug/L 10/28/24 14:00 1,1-Dichloroethane <1.0 1.0 0.36 ug/L 10/28/24 14:00 1,1-Dichloroethene <1.0 1.0 0.48 ug/L 10/28/24 14:00 1,2,3-Trichloropropane <2.0 2.0 1.5 ug/L 10/28/24 14:00 1,2-Dibromo-3-Chloropropane <5.0 5.0 3.9 ug/L 10/28/24 14:00 1,2-Dibromoethane <1.0 1.0 0.56 ug/L 10/28/24 14:00 1,2-Dichlorobenzene <1.0 1.0 0.48 ug/L 10/28/24 14:00 1,2-Dichloroethane <1.0 1.0 0.58 ug/L 10/28/24 14:00 1,2-Dichloropropane <1.0 1.0 0.37 ug/L 10/28/24 14:00 1,4-Dichlorobenzene <1.0 1.0 0.45 ug/L 10/28/24 14:00 2-Butanone (MEK) <5.0 5.0 2.3 ug/L 10/28/24 14:00 2-Hexanone <5.0 5.0 2.2 ug/L 10/28/24 14:00 4-Methyl-2-pentanone (MIBK) <5.0 5.0 2.0 ug/L 10/28/24 14:00 Acetone <10 10 4.3 ug/L 10/28/24 14:00 Acrylonitrile <20 20 6.0 ug/L 10/28/24 14:00 Benzene 0.93 0.50 0.18 ug/L 10/28/24 14:00 Bromochloromethane <1.0 1.0 0.50 ug/L 10/28/24 14:00 Bromodichloromethane <1.0 1.0 0.57 ug/L 10/28/24 14:00 Bromoform <1.0 1.0 0.96 ug/L 10/28/24 14:00 Bromomethane <3.0 3.0 1.8 ug/L 10/28/24 14:00 Carbon disulfide <2.0 2.0 1.1 ug/L 10/28/24 14:00 Carbon tetrachloride <1.0 1.0 0.41 ug/L 10/28/24 14:00 Chlorobenzene <1.0 1.0 0.41 ug/L 10/28/24 14:00 Chloroethane <5.0 5.0 0.47 ug/L 10/28/24 14:00 Chloroform <2.0 2.0 0.92 ug/L 10/28/24 14:00 Chloromethane <5.0 5.0 0.79 ug/L 10/28/24 14:00 cis-1,2-Dichloroethene <1.0 1.0 0.42 ug/L 10/28/24 14:00 cis-1,3-Dichloropropene <1.0 1.0 0.52 ug/L 10/28/24 14:00 Dibromochloromethane <1.0 1.0 0.83 ug/L 10/28/24 14:00 Dibromomethane <1.0 1.0 0.58 ug/L 10/28/24 14:00 Ethylbenzene <0.50 0.50 0.20 ug/L 10/28/24 14:00 lodomethane <3.0 3.0 0.68 ug/L 10/28/24 14:00 Methylene Chloride 3.7 J B 5.0 3.6 ug/L 10/28/24 14:00 Styrene <1.0 1.0 0.31 ug/L 10/28/24 14:00 Tetrachloroethene <1.0 1.0 0.39 ug/L 10/28/24 14:00 Tetrahydrofuran <10 *- 10 3.9 ug/L 10/28/24 14:00 Toluene <0.50 0.50 0.21 ug/L 10/28/24 14:00 trans- 1,2-Dichloroethene <1.0 1.0 0.44 ug/L 10/28/24 14:00 trans- 1,3-Dichloropropene <1.0 1.0 0.63 ug/L 10/28/24 14:00 trans- 1,4-Dichloro-2-butene <5.0 5.0 3.4 ug/L 10/28/24 14:00 Eurofins Chicago Page 31 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-8 Lab Sample ID: 500-258888-9 Date Collected: 10/22/24 09:25 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichloroethene <0.50 0.50 0.15 ug/L 10/28/24 14:00 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/28/24 14:00 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/28/24 14:00 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/28/24 14:00 1 Xylenes, Total <1.0 1.0 0.30 ug/L 10/28/24 14:00 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 91 75- 126 10128124 14:00 1 4-Bromofluorobenzene (Surr) 91 72 - 124 10128124 14:00 1 Dibromofluoromethane 100 75 - 120 10128124 14:00 1 Toluene-d8 (Surr) 102 75 - 120 10/28/24 14:00 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <3.0 3.0 1.3 ug/L 11/01/24 08:39 11/04/24 17:38 1 Arsenic 3.0 1.0 0.23 ug/L 11/01/24 08:39 11/04/24 17:38 1 Barium 150 2.5 0.73 ug/L 11/01/24 08:39 11/04/24 17:38 1 Beryllium <1.0 1.0 0.53 ug/L 11/01/24 08:39 11/04/24 17:38 1 Cadmium <0.50 0.50 0.17 ug/L 11/01/24 08:39 11/04/24 17:38 1 Calcium 120000 200 44 ug/L 11/01/24 08:39 11/04/24 17:38 1 Chromium 2.2 J 5.0 1.1 ug/L 11/01/24 08:39 11/04/24 17:38 1 Cobalt 2.0 1.0 0.40 ug/L 11/01/24 08:39 11/04/24 17:38 1 Copper <2.0 2.0 0.50 ug/L 11/01/24 08:39 11/04/24 17:38 1 Iron 2800 100 47 ug/L 11/01/24 08:39 11/04/24 17:38 1 Lead <0.50 0.50 0.19 ug/L 11/01/24 08:39 11/04/24 17:38 1 Manganese 600 2.5 0.79 ug/L 11/01/24 08:39 11/04/24 17:38 1 Nickel 8.8 2.0 0.63 ug/L 11/01/24 08:39 11/04/24 17:38 1 Selenium <2.5 2.5 0.98 ug/L 11/01/24 08:39 11/04/24 17:38 1 Silver <0.50 0.50 0.12 ug/L 11/01/24 08:39 11/04/24 17:38 1 Thallium <2.0 2.0 0.57 ug/L 11/01/24 08:39 11/04/24 17:38 1 Vanadium <5.0 5.0 2.2 ug/L 11/01/24 08:39 11/04/24 17:38 1 Zinc <10 10 6.9 ug/L 11/01/24 08:39 11/04/24 17:38 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury <0.20 0.20 0.076 ug/L 10/31/24 10:20 11/01/24 08:23 1 General Chemistry Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chloride (SW846 9056A) 98000 5000 580 ug/L 11/07/24 18:05 5 Sulfate (SW846 9056A) 66000 5000 1000 ug/L 11/07/24 18:05 5 Alkalinity (SM 2320B) 510000 5000 3700 ug/L 11/01/24 14:05 1 Total Dissolved Solids (SM 2540C) 880000 10000 4300 ug/L 10/28/24 14:25 1 Eurofins Chicago Page 32 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-9 Lab Sample ID: 500-258888-10 Date Collected: 10/22/24 10:40 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane 11 2.0 0.85 ug/L 10/25/24 03:11 5 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Toluene-d8 (Surr) 113 80 - 120 10125124 03:11 5 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane <1.0 1.0 0.67 ug/L 10/28/24 14:25 1 1,1,1-Trichloroethane <1.0 1.0 0.45 ug/L 10/28/24 14:25 1 1,1,2,2-Tetrachloroethane <1.0 1.0 0.65 ug/L 10/28/24 14:25 1 1,1,2-Trichloroethane <1.0 1.0 0.73 ug/L 10/28/24 14:25 1 1,1-Dichloroethane <1.0 1.0 0.36 ug/L 10/28/24 14:25 1 1,1-Dichloroethene <1.0 1.0 0.48 ug/L 10/28/24 14:25 1 1,2,3-Trichloropropane <2.0 2.0 1.5 ug/L 10/28/24 14:25 1 1,2-Dibromo-3-Chloropropane <5.0 5.0 3.9 ug/L 10/28/24 14:25 1 1,2-Dibromoethane <1.0 1.0 0.56 ug/L 10/28/24 14:25 1 1,2-Dichlorobenzene <1.0 1.0 0.48 ug/L 10/28/24 14:25 1 1,2-Dichloroethane <1.0 1.0 0.58 ug/L 10/28/24 14:25 1 1,2-Dichloropropane <1.0 1.0 0.37 ug/L 10/28/24 14:25 1 1,4-Dichlorobenzene <1.0 1.0 0.45 ug/L 10/28/24 14:25 1 2-Butanone (MEK) <5.0 5.0 2.3 ug/L 10/28/24 14:25 1 2-Hexanone <5.0 5.0 2.2 ug/L 10/28/24 14:25 1 4-Methyl-2-pentanone (MIBK) <5.0 5.0 2.0 ug/L 10/28/24 14:25 1 Acetone <10 10 4.3 ug/L 10/28/24 14:25 1 Acrylonitrile <20 20 6.0 ug/L 10/28/24 14:25 1 Benzene 1.3 0.50 0.18 ug/L 10/28/24 14:25 1 Bromochloromethane <1.0 1.0 0.50 ug/L 10/28/24 14:25 1 Bromodichloromethane <1.0 1.0 0.57 ug/L 10/28/24 14:25 1 Bromoform <1.0 1.0 0.96 ug/L 10/28/24 14:25 1 Bromomethane <3.0 3.0 1.8 ug/L 10/28/24 14:25 1 Carbon disulfide <2.0 2.0 1.1 ug/L 10/28/24 14:25 1 Carbon tetrachloride <1.0 1.0 0.41 ug/L 10/28/24 14:25 1 Chlorobenzene <1.0 1.0 0.41 ug/L 10/28/24 14:25 1 Chloroethane <5.0 5.0 0.47 ug/L 10/28/24 14:25 1 Chloroform <2.0 2.0 0.92 ug/L 10/28/24 14:25 1 Chloromethane <5.0 5.0 0.79 ug/L 10/28/24 14:25 1 cis-1,2-Dichloroethene <1.0 1.0 0.42 ug/L 10/28/24 14:25 1 cis-1,3-Dichloropropene <1.0 1.0 0.52 ug/L 10/28/24 14:25 1 Dibromochloromethane <1.0 1.0 0.83 ug/L 10/28/24 14:25 1 Dibromomethane <1.0 1.0 0.58 ug/L 10/28/24 14:25 1 Ethylbenzene <0.50 0.50 0.20 ug/L 10/28/24 14:25 1 lodomethane <3.0 3.0 0.68 ug/L 10/28/24 14:25 1 Methylene Chloride 4.6 J B 5.0 3.6 ug/L 10/28/24 14:25 1 Styrene <1.0 1.0 0.31 ug/L 10/28/24 14:25 1 Tetrachloroethene <1.0 1.0 0.39 ug/L 10/28/24 14:25 1 Tetrahydrofuran <10 *- 10 3.9 ug/L 10/28/24 14:25 1 Toluene 0.29 J 0.50 0.21 ug/L 10/28/24 14:25 1 trans- 1,2-Dichloroethene <1.0 1.0 0.44 ug/L 10/28/24 14:25 1 trans- 1,3-Dichloropropene <1.0 1.0 0.63 ug/L 10/28/24 14:25 1 trans- 1,4-Dichloro-2-butene <5.0 5.0 3.4 ug/L 10/28/24 14:25 1 Eurofins Chicago Page 33 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-9 Lab Sample ID: 500-258888-10 Date Collected: 10/22/24 10:40 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichloroethene <0.50 0.50 0.15 ug/L 10/28/24 14:25 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/28/24 14:25 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/28/24 14:25 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/28/24 14:25 1 Xylenes, Total 0.55 J 1.0 0.30 ug/L 10/28/24 14:25 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 89 75- 126 10128124 14:25 1 4-Bromofluorobenzene (Surr) 94 72 - 124 10128124 14:25 1 Dibromofluoromethane 103 75 - 120 10128124 14:25 1 Toluene-d8 (Surr) 98 75 - 120 10/28/24 14:25 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <3.0 3.0 1.3 ug/L 11/01/24 08:39 11/04/24 17:40 1 Arsenic 8.1 1.0 0.23 ug/L 11/01/24 08:39 11/04/24 17:40 1 Barium 1100 2.5 0.73 ug/L 11/01/24 08:39 11/04/24 17:40 1 Beryllium <1.0 1.0 0.53 ug/L 11/01/24 08:39 11/04/24 17:40 1 Cadmium <0.50 0.50 0.17 ug/L 11/01/24 08:39 11/04/24 17:40 1 Calcium 130000 200 44 ug/L 11/01/24 08:39 11/04/24 17:40 1 Chromium 3.5 J 5.0 1.1 ug/L 11/01/24 08:39 11/04/24 17:40 1 Cobalt 5.6 1.0 0.40 ug/L 11/01/24 08:39 11/04/24 17:40 1 Copper 0.75 J 2.0 0.50 ug/L 11/01/24 08:39 11/04/24 17:40 1 Iron 9300 100 47 ug/L 11/01/24 08:39 11/04/24 17:40 1 Lead <0.50 0.50 0.19 ug/L 11/01/24 08:39 11/04/24 17:40 1 Manganese 5200 2.5 0.79 ug/L 11/01/24 08:39 11/04/24 17:40 1 Nickel 15 2.0 0.63 ug/L 11/01/24 08:39 11/04/24 17:40 1 Selenium 1.2 J 2.5 0.98 ug/L 11/01/24 08:39 11/04/24 17:40 1 Silver <0.50 0.50 0.12 ug/L 11/01/24 08:39 11/04/24 17:40 1 Thallium <2.0 2.0 0.57 ug/L 11/01/24 08:39 11/04/24 17:40 1 Vanadium <5.0 5.0 2.2 ug/L 11/01/24 08:39 11/04/24 17:40 1 Zinc <10 10 6.9 ug/L 11/01/24 08:39 11/04/24 17:40 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury <0.20 0.20 0.076 ug/L 10/31/24 10:20 11/01/24 08:25 1 General Chemistry Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chloride (SW846 9056A) 640000 20000 2300 ug/L 11/07/24 18:20 20 Sulfate (SW846 9056A) 90000 20000 4100 ug/L 11/07/24 18:20 20 Alkalinity (SM 2320B) 730000 5000 3700 ug/L 11/01/24 14:15 1 Total Dissolved Solids (SM 2540C) 2100000 13000 5400 ug/L 10/28/24 14:33 1 Eurofins Chicago Page 34 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-12 Lab Sample ID: 500-258888-11 Date Collected: 10/22/24 11:35 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane <0.40 0.40 0.17 ug/L 10/29/2413:20 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Toluene-d8 (Surr) 92 80 - 120 10129124 13:20 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed 1,1,1,2-Tetrachloroethane <1.0 1.0 0.67 ug/L 10/28/24 14:50 1,1,1-Trichloroethane <1.0 1.0 0.45 ug/L 10/28/24 14:50 1,1,2,2-Tetrachloroethane <1.0 1.0 0.65 ug/L 10/28/24 14:50 1,1,2-Trichloroethane <1.0 1.0 0.73 ug/L 10/28/24 14:50 1,1-Dichloroethane <1.0 1.0 0.36 ug/L 10/28/24 14:50 1,1-Dichloroethene <1.0 1.0 0.48 ug/L 10/28/24 14:50 1,2,3-Trichloropropane <2.0 2.0 1.5 ug/L 10/28/24 14:50 1,2-Dibromo-3-Chloropropane <5.0 5.0 3.9 ug/L 10/28/24 14:50 1,2-Dibromoethane <1.0 1.0 0.56 ug/L 10/28/24 14:50 1,2-Dichlorobenzene <1.0 1.0 0.48 ug/L 10/28/24 14:50 1,2-Dichloroethane <1.0 1.0 0.58 ug/L 10/28/24 14:50 1,2-Dichloropropane <1.0 1.0 0.37 ug/L 10/28/24 14:50 1,4-Dichlorobenzene <1.0 1.0 0.45 ug/L 10/28/24 14:50 2-Butanone (MEK) <5.0 5.0 2.3 ug/L 10/28/24 14:50 2-Hexanone <5.0 5.0 2.2 ug/L 10/28/24 14:50 4-Methyl-2-pentanone (MIBK) <5.0 5.0 2.0 ug/L 10/28/24 14:50 Acetone <10 10 4.3 ug/L 10/28/24 14:50 Acrylonitrile <20 20 6.0 ug/L 10/28/24 14:50 Benzene <0.50 0.50 0.18 ug/L 10/28/24 14:50 Bromochloromethane <1.0 1.0 0.50 ug/L 10/28/24 14:50 Bromodichloromethane <1.0 1.0 0.57 ug/L 10/28/24 14:50 Bromoform <1.0 1.0 0.96 ug/L 10/28/24 14:50 Bromomethane <3.0 3.0 1.8 ug/L 10/28/24 14:50 Carbon disulfide <2.0 2.0 1.1 ug/L 10/28/24 14:50 Carbon tetrachloride <1.0 1.0 0.41 ug/L 10/28/24 14:50 Chlorobenzene <1.0 1.0 0.41 ug/L 10/28/24 14:50 Chloroethane <5.0 5.0 0.47 ug/L 10/28/24 14:50 Chloroform <2.0 2.0 0.92 ug/L 10/28/24 14:50 Chloromethane <5.0 5.0 0.79 ug/L 10/28/24 14:50 cis-1,2-Dichloroethene <1.0 1.0 0.42 ug/L 10/28/24 14:50 cis-1,3-Dichloropropene <1.0 1.0 0.52 ug/L 10/28/24 14:50 Dibromochloromethane <1.0 1.0 0.83 ug/L 10/28/24 14:50 Dibromomethane <1.0 1.0 0.58 ug/L 10/28/24 14:50 Ethylbenzene <0.50 0.50 0.20 ug/L 10/28/24 14:50 lodomethane <3.0 3.0 0.68 ug/L 10/28/24 14:50 Methylene Chloride <5.0 5.0 3.6 ug/L 10/28/24 14:50 Styrene <1.0 1.0 0.31 ug/L 10/28/24 14:50 Tetrachloroethene <1.0 1.0 0.39 ug/L 10/28/24 14:50 Tetrahydrofuran <10 *- 10 3.9 ug/L 10/28/24 14:50 Toluene <0.50 0.50 0.21 ug/L 10/28/24 14:50 trans- 1,2-Dichloroethene <1.0 1.0 0.44 ug/L 10/28/24 14:50 trans- 1,3-Dichloropropene <1.0 1.0 0.63 ug/L 10/28/24 14:50 trans- 1,4-Dichloro-2-butene <5.0 5.0 3.4 ug/L 10/28/24 14:50 Eurofins Chicago Page 35 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-12 Lab Sample ID: 500-258888-11 Date Collected: 10/22/24 11:35 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichloroethene <0.50 0.50 0.15 ug/L 10/28/24 14:50 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/28/24 14:50 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/28/24 14:50 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/28/24 14:50 1 Xylenes, Total <1.0 1.0 0.30 ug/L 10/28/24 14:50 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 88 75- 126 10128124 14:50 1 4-Bromofluorobenzene (Surr) 92 72 - 124 10128124 14:50 1 Dibromofluoromethane 99 75 - 120 10128124 14:50 1 Toluene-d8 (Surr) 102 75 - 120 10/28/24 14:50 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <3.0 3.0 1.3 ug/L 11/01/24 08:39 11/04/24 17:47 1 Arsenic 1.8 1.0 0.23 ug/L 11/01/24 08:39 11/04/24 17:47 1 Barium 400 2.5 0.73 ug/L 11/01/24 08:39 11/04/24 17:47 1 Beryllium <1.0 1.0 0.53 ug/L 11/01/24 08:39 11/04/24 17:47 1 Cadmium <0.50 0.50 0.17 ug/L 11/01/24 08:39 11/04/24 17:47 1 Calcium 130000 200 44 ug/L 11/01/24 08:39 11/04/24 17:47 1 Chromium <5.0 5.0 1.1 ug/L 11/01/24 08:39 11/04/24 17:47 1 Cobalt 1.2 1.0 0.40 ug/L 11/01/24 08:39 11/04/24 17:47 1 Copper 0.57 J 2.0 0.50 ug/L 11/01/24 08:39 11/04/24 17:47 1 Iron 1400 100 47 ug/L 11/01/24 08:39 11/04/24 17:47 1 Lead <0.50 0.50 0.19 ug/L 11/01/24 08:39 11/04/24 17:47 1 Manganese 1500 2.5 0.79 ug/L 11/01/24 08:39 11/04/24 17:47 1 Nickel 3.3 2.0 0.63 ug/L 11/01/24 08:39 11/04/24 17:47 1 Selenium <2.5 2.5 0.98 ug/L 11/01/24 08:39 11/04/24 17:47 1 Silver <0.50 0.50 0.12 ug/L 11/01/24 08:39 11/04/24 17:47 1 Thallium <2.0 2.0 0.57 ug/L 11/01/24 08:39 11/04/24 17:47 1 Vanadium <5.0 5.0 2.2 ug/L 11/01/24 08:39 11/04/24 17:47 1 Zinc <10 10 6.9 ug/L 11/01/24 08:39 11/04/24 17:47 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury <0.20 0.20 0.076 ug/L 10/31/24 10:20 11/01/24 08:27 1 General Chemistry Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chloride (SW846 9056A) 340000 10000 1200 ug/L 11/09/24 14:24 10 Sulfate (SW846 9056A) 110000 10000 2100 ug/L 11/09/24 14:24 10 Alkalinity (SM 2320B) 380000 5000 3700 ug/L 11/01/24 14:26 1 Total Dissolved Solids (SM 2540C) 1200000 10000 4300 ug/L 10/28/24 14:40 1 Eurofins Chicago Page 36 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Job ID: 500-258888-1 Client Sample ID: MW-13R Lab Sample ID: 500-258888-12 Date Collected: 10/22/24 12:35 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit 1,4-Dioxane <0.40 0.40 0.17 ug/L Surrogate Toluene-d8 (Surr) %Recovery Qualifier Limits 95 80-120 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL 1,1,1,2-Tetrachloroethane <1.0 1.0 1,1,1-Trichloroethane <1.0 1.0 1,1,2,2-Tetrachloroethane <1.0 1.0 1,1,2-Trichloroethane <1.0 1.0 1,1-Dichloroethane <1.0 1.0 1,1-Dichloroethene <1.0 1.0 1,2,3-Trichloropropane <2.0 2.0 1,2-Dibromo-3-Chloropropane <5.0 5.0 1,2-Dibromoethane <1.0 1.0 1,2-Dichlorobenzene <1.0 1.0 1,2-Dichloroethane <1.0 1.0 1,2-Dichloropropane <1.0 1.0 1,4-Dichlorobenzene <1.0 1.0 2-Butanone (MEK) <5.0 5.0 2-Hexanone <5.0 5.0 4-Methyl-2-pentanone (MIBK) <5.0 5.0 Acetone <10 10 Acrylonitrile <20 20 Benzene <0.50 0.50 Bromochloromethane <1.0 1.0 Bromodichloromethane <1.0 1.0 Bromoform <1.0 1.0 Bromomethane <3.0 3.0 Carbon disulfide <2.0 2.0 Carbon tetrachloride <1.0 1.0 Chlorobenzene <1.0 1.0 Chloroethane <5.0 5.0 Chloroform <2.0 2.0 Chloromethane <5.0 5.0 cis-1,2-Dichloroethene <1.0 1.0 cis-1,3-Dichloropropene <1.0 1.0 Dibromochloromethane <1.0 1.0 Dibromomethane <1.0 1.0 Ethylbenzene <0.50 0.50 lodomethane <3.0 3.0 Methylene Chloride 3.9 J B 5.0 Styrene <1.0 1.0 Tetrachloroethene <1.0 1.0 Tetrahydrofuran <10 *- 10 Toluene <0.50 0.50 trans- 1,2-Dichloroethene <1.0 1.0 trans- 1,3-Dichloropropene <1.0 1.0 trans- 1,4-Dichloro-2-butene <5.0 5.0 D Prepared Analyzed Dil Fac C 10/29/24 13:40 1 Prepared Analyzed Dil Fac 10129124 13:40 1 MDL Unit D Prepared Analyzed Dil Fac 0.67 ug/L 10/28/2415:15 1 0.45 ug/L 10/28/2415:15 1 0.65 ug/L 10/28/2415:15 1 0.73 ug/L 10/28/2415:15 1 0.36 ug/L 10/28/2415:15 1 0.48 ug/L 10/28/2415:15 1 1.5 ug/L 10/28/2415:15 1 3.9 ug/L 10/28/2415:15 1 0.56 ug/L 10/28/2415:15 1 0.48 ug/L 10/28/2415:15 1 0.58 ug/L 10/28/2415:15 1 0.37 ug/L 10/28/2415:15 1 0.45 ug/L 10/28/2415:15 1 2.3 ug/L 10/28/2415:15 1 2.2 ug/L 10/28/2415:15 1 2.0 ug/L 10/28/2415:15 1 4.3 ug/L 10/28/2415:15 1 6.0 ug/L 10/28/2415:15 1 0.18 ug/L 10/28/2415:15 1 0.50 ug/L 10/28/2415:15 1 0.57 ug/L 10/28/2415:15 1 0.96 ug/L 10/28/2415:15 1 1.8 ug/L 10/28/2415:15 1 1.1 ug/L 10/28/2415:15 1 0.41 ug/L 10/28/2415:15 1 0.41 ug/L 10/28/2415:15 1 0.47 ug/L 10/28/2415:15 1 0.92 ug/L 10/28/2415:15 1 0.79 ug/L 10/28/2415:15 1 0.42 ug/L 10/28/2415:15 1 0.52 ug/L 10/28/2415:15 1 0.83 ug/L 10/28/2415:15 1 0.58 ug/L 10/28/2415:15 1 0.20 ug/L 10/28/2415:15 1 0.68 ug/L 10/28/2415:15 1 3.6 ug/L 10/28/2415:15 1 0.31 ug/L 10/28/2415:15 1 0.39 ug/L 10/28/2415:15 1 3.9 ug/L 10/28/2415:15 1 0.21 ug/L 10/28/2415:15 1 0.44 ug/L 10/28/2415:15 1 0.63 ug/L 10/28/2415:15 1 3.4 ug/L 10/28/2415:15 1 Eurofins Chicago Page 37 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-13R Lab Sample ID: 500-258888-12 Date Collected: 10/22/24 12:35 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichloroethene <0.50 0.50 0.15 ug/L 10/28/24 15:15 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/28/24 15:15 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/28/24 15:15 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/28/24 15:15 1 Xylenes, Total <1.0 1.0 0.30 ug/L 10/28/24 15:15 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 91 75- 126 10128124 15:15 1 4-Bromofluorobenzene (Surr) 87 72 - 124 10128124 15:15 1 Dibromofluoromethane 100 75 - 120 10128124 15:15 1 Toluene-d8 (Surr) 103 75 - 120 10/28/24 15:15 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <3.0 3.0 1.3 ug/L 11/01/24 08:39 11/04/24 17:49 1 Arsenic 0.31 J 1.0 0.23 ug/L 11/01/24 08:39 11/04/24 17:49 1 Barium 910 2.5 0.73 ug/L 11/01/24 08:39 11/04/24 17:49 1 Beryllium <1.0 1.0 0.53 ug/L 11/01/24 08:39 11/04/24 17:49 1 Cadmium <0.50 0.50 0.17 ug/L 11/01/24 08:39 11/04/24 17:49 1 Calcium 310000 200 44 ug/L 11/01/24 08:39 11/04/24 17:49 1 Chromium 13 5.0 1.1 ug/L 11/01/24 08:39 11/04/24 17:49 1 Cobalt <1.0 1.0 0.40 ug/L 11/01/24 08:39 11/04/24 17:49 1 Copper 1.0 J 2.0 0.50 ug/L 11/01/24 08:39 11/04/24 17:49 1 Iron <100 100 47 ug/L 11/01/24 08:39 11/04/24 17:49 1 Lead <0.50 0.50 0.19 ug/L 11/01/24 08:39 11/04/24 17:49 1 Manganese 6.0 2.5 0.79 ug/L 11/01/24 08:39 11/04/24 17:49 1 Nickel <2.0 2.0 0.63 ug/L 11/01/24 08:39 11/04/24 17:49 1 Selenium 1.3 J 2.5 0.98 ug/L 11/01/24 08:39 11/04/24 17:49 1 Silver 0.17 J 0.50 0.12 ug/L 11/01/24 08:39 11/04/24 17:49 1 Thallium <2.0 2.0 0.57 ug/L 11/01/24 08:39 11/04/24 17:49 1 Vanadium <5.0 5.0 2.2 ug/L 11/01/24 08:39 11/04/24 17:49 1 Zinc <10 10 6.9 ug/L 11/01/24 08:39 11/04/24 17:49 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury 2.1 0.20 0.076 ug/L 10/31/24 10:20 11/01/24 08:29 1 General Chemistry Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chloride (SW846 9056A) 1700000 50000 5800 ug/L 11/06/24 16:01 50 Sulfate (SW846 9056A) 9100 1000 210 ug/L 11/10/24 19:18 1 Alkalinity (SM 2320B) 520000 5000 3700 ug/L 11/01/24 14:37 1 Total Dissolved Solids (SM 2540C) 2400000 13000 5400 ug/L 10/28/24 14:48 1 Eurofins Chicago Page 38 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-14 Lab Sample ID: 500-258888-13 Date Collected: 10/22/24 13:30 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane <0.40 0.40 0.17 ug/L 10/29/2414:00 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Toluene-d8 (Surr) 94 80 - 120 10129124 14:00 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed 1,1,1,2-Tetrachloroethane <1.0 1.0 0.67 ug/L 10/28/24 15:39 1,1,1-Trichloroethane <1.0 1.0 0.45 ug/L 10/28/24 15:39 1,1,2,2-Tetrachloroethane <1.0 1.0 0.65 ug/L 10/28/24 15:39 1,1,2-Trichloroethane <1.0 1.0 0.73 ug/L 10/28/24 15:39 1,1-Dichloroethane <1.0 1.0 0.36 ug/L 10/28/24 15:39 1,1-Dichloroethene <1.0 1.0 0.48 ug/L 10/28/24 15:39 1,2,3-Trichloropropane <2.0 2.0 1.5 ug/L 10/28/24 15:39 1,2-Dibromo-3-Chloropropane <5.0 5.0 3.9 ug/L 10/28/24 15:39 1,2-Dibromoethane <1.0 1.0 0.56 ug/L 10/28/24 15:39 1,2-Dichlorobenzene <1.0 1.0 0.48 ug/L 10/28/24 15:39 1,2-Dichloroethane <1.0 1.0 0.58 ug/L 10/28/24 15:39 1,2-Dichloropropane <1.0 1.0 0.37 ug/L 10/28/24 15:39 1,4-Dichlorobenzene <1.0 1.0 0.45 ug/L 10/28/24 15:39 2-Butanone (MEK) <5.0 5.0 2.3 ug/L 10/28/24 15:39 2-Hexanone <5.0 5.0 2.2 ug/L 10/28/24 15:39 4-Methyl-2-pentanone (MIBK) <5.0 5.0 2.0 ug/L 10/28/24 15:39 Acetone <10 10 4.3 ug/L 10/28/24 15:39 Acrylonitrile <20 20 6.0 ug/L 10/28/24 15:39 Benzene <0.50 0.50 0.18 ug/L 10/28/24 15:39 Bromochloromethane <1.0 1.0 0.50 ug/L 10/28/24 15:39 Bromodichloromethane <1.0 1.0 0.57 ug/L 10/28/24 15:39 Bromoform <1.0 1.0 0.96 ug/L 10/28/24 15:39 Bromomethane <3.0 3.0 1.8 ug/L 10/28/24 15:39 Carbon disulfide <2.0 2.0 1.1 ug/L 10/28/24 15:39 Carbon tetrachloride <1.0 1.0 0.41 ug/L 10/28/24 15:39 Chlorobenzene <1.0 1.0 0.41 ug/L 10/28/24 15:39 Chloroethane <5.0 5.0 0.47 ug/L 10/28/24 15:39 Chloroform <2.0 2.0 0.92 ug/L 10/28/24 15:39 Chloromethane <5.0 5.0 0.79 ug/L 10/28/24 15:39 cis-1,2-Dichloroethene <1.0 1.0 0.42 ug/L 10/28/24 15:39 cis-1,3-Dichloropropene <1.0 1.0 0.52 ug/L 10/28/24 15:39 Dibromochloromethane <1.0 1.0 0.83 ug/L 10/28/24 15:39 Dibromomethane <1.0 1.0 0.58 ug/L 10/28/24 15:39 Ethylbenzene <0.50 0.50 0.20 ug/L 10/28/24 15:39 lodomethane <3.0 3.0 0.68 ug/L 10/28/24 15:39 Methylene Chloride 3.6 J B 5.0 3.6 ug/L 10/28/24 15:39 Styrene <1.0 1.0 0.31 ug/L 10/28/24 15:39 Tetrachloroethene <1.0 1.0 0.39 ug/L 10/28/24 15:39 Tetrahydrofuran <10 *- 10 3.9 ug/L 10/28/24 15:39 Toluene <0.50 0.50 0.21 ug/L 10/28/24 15:39 trans- 1,2-Dichloroethene <1.0 1.0 0.44 ug/L 10/28/24 15:39 trans- 1,3-Dichloropropene <1.0 1.0 0.63 ug/L 10/28/24 15:39 trans- 1,4-Dichloro-2-butene <5.0 5.0 3.4 ug/L 10/28/24 15:39 Eurofins Chicago Page 39 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-14 Lab Sample ID: 500-258888-13 Date Collected: 10/22/24 13:30 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichloroethene <0.50 0.50 0.15 ug/L 10/28/24 15:39 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/28/24 15:39 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/28/24 15:39 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/28/24 15:39 1 Xylenes, Total <1.0 1.0 0.30 ug/L 10/28/24 15:39 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 90 75- 126 10128124 15:39 1 4-Bromofluorobenzene (Surr) 92 72 - 124 10128124 15:39 1 Dibromofluoromethane 102 75 - 120 10128124 15:39 1 Toluene-d8 (Surr) 101 75 - 120 10/28/24 15:39 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <3.0 3.0 1.3 ug/L 11/01/24 08:39 11/04/24 17:51 1 Arsenic 0.55 J 1.0 0.23 ug/L 11/01/24 08:39 11/04/24 17:51 1 Barium 1800 2.5 0.73 ug/L 11/01/24 08:39 11/04/24 17:51 1 Beryllium <1.0 1.0 0.53 ug/L 11/01/24 08:39 11/04/24 17:51 1 Cadmium <0.50 0.50 0.17 ug/L 11/01/24 08:39 11/04/24 17:51 1 Calcium 240000 200 44 ug/L 11/01/24 08:39 11/04/24 17:51 1 Chromium <5.0 5.0 1.1 ug/L 11/01/24 08:39 11/04/24 17:51 1 Cobalt <1.0 1.0 0.40 ug/L 11/01/24 08:39 11/04/24 17:51 1 Copper 0.78 J 2.0 0.50 ug/L 11/01/24 08:39 11/04/24 17:51 1 Iron 180 100 47 ug/L 11/01/24 08:39 11/04/24 17:51 1 Lead <0.50 0.50 0.19 ug/L 11/01/24 08:39 11/04/24 17:51 1 Manganese 230 2.5 0.79 ug/L 11/01/24 08:39 11/04/24 17:51 1 Nickel <2.0 2.0 0.63 ug/L 11/01/24 08:39 11/04/24 17:51 1 Selenium <2.5 2.5 0.98 ug/L 11/01/24 08:39 11/04/24 17:51 1 Silver 0.31 J 0.50 0.12 ug/L 11/01/24 08:39 11/04/24 17:51 1 Thallium <2.0 2.0 0.57 ug/L 11/01/24 08:39 11/04/24 17:51 1 Vanadium 8.4 5.0 2.2 ug/L 11/01/24 08:39 11/04/24 17:51 1 Zinc <10 10 6.9 ug/L 11/01/24 08:39 11/04/24 17:51 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury 1.2 0.20 0.076 ug/L 10/31/24 10:20 11/01/24 08:35 1 General Chemistry Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chloride (SW846 9056A) 1200000 100000 12000 ug/L 11/06/24 16:17 100 Sulfate (SW846 9056A) 13000 1000 210 ug/L 11/09/24 14:55 1 Alkalinity (SM 2320B) 470000 5000 3700 ug/L 11/01/24 14:47 1 Total Dissolved Solids (SM 2540C) 2900000 17000 7200 ug/L 10/28/24 15:03 1 Eurofins Chicago Page 40 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-1 Lab Sample ID: 500-258888-14 Date Collected: 10/22/24 14:30 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane <0.40 0.40 0.17 ug/L 10/25/2400:52 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Toluene-d8 (Surr) 101 80 - 120 10125124 00:52 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed 1,1,1,2-Tetrachloroethane <1.0 1.0 0.67 ug/L 10/28/24 16:04 1,1,1-Trichloroethane <1.0 1.0 0.45 ug/L 10/28/24 16:04 1,1,2,2-Tetrachloroethane <1.0 1.0 0.65 ug/L 10/28/24 16:04 1,1,2-Trichloroethane <1.0 1.0 0.73 ug/L 10/28/24 16:04 1,1-Dichloroethane <1.0 1.0 0.36 ug/L 10/28/24 16:04 1,1-Dichloroethene <1.0 1.0 0.48 ug/L 10/28/24 16:04 1,2,3-Trichloropropane <2.0 2.0 1.5 ug/L 10/28/24 16:04 1,2-Dibromo-3-Chloropropane <5.0 5.0 3.9 ug/L 10/28/24 16:04 1,2-Dibromoethane <1.0 1.0 0.56 ug/L 10/28/24 16:04 1,2-Dichlorobenzene <1.0 1.0 0.48 ug/L 10/28/24 16:04 1,2-Dichloroethane <1.0 1.0 0.58 ug/L 10/28/24 16:04 1,2-Dichloropropane <1.0 1.0 0.37 ug/L 10/28/24 16:04 1,4-Dichlorobenzene <1.0 1.0 0.45 ug/L 10/28/24 16:04 2-Butanone (MEK) <5.0 5.0 2.3 ug/L 10/28/24 16:04 2-Hexanone <5.0 5.0 2.2 ug/L 10/28/24 16:04 4-Methyl-2-pentanone (MIBK) <5.0 5.0 2.0 ug/L 10/28/24 16:04 Acetone <10 10 4.3 ug/L 10/28/24 16:04 Acrylonitrile <20 20 6.0 ug/L 10/28/24 16:04 Benzene <0.50 0.50 0.18 ug/L 10/28/24 16:04 Bromochloromethane <1.0 1.0 0.50 ug/L 10/28/24 16:04 Bromodichloromethane <1.0 1.0 0.57 ug/L 10/28/24 16:04 Bromoform <1.0 1.0 0.96 ug/L 10/28/24 16:04 Bromomethane <3.0 3.0 1.8 ug/L 10/28/24 16:04 Carbon disulfide <2.0 2.0 1.1 ug/L 10/28/24 16:04 Carbon tetrachloride <1.0 1.0 0.41 ug/L 10/28/24 16:04 Chlorobenzene <1.0 1.0 0.41 ug/L 10/28/24 16:04 Chloroethane <5.0 5.0 0.47 ug/L 10/28/24 16:04 Chloroform <2.0 2.0 0.92 ug/L 10/28/24 16:04 Chloromethane <5.0 5.0 0.79 ug/L 10/28/24 16:04 cis-1,2-Dichloroethene <1.0 1.0 0.42 ug/L 10/28/24 16:04 cis-1,3-Dichloropropene <1.0 1.0 0.52 ug/L 10/28/24 16:04 Dibromochloromethane <1.0 1.0 0.83 ug/L 10/28/24 16:04 Dibromomethane <1.0 1.0 0.58 ug/L 10/28/24 16:04 Ethylbenzene <0.50 0.50 0.20 ug/L 10/28/24 16:04 lodomethane <3.0 3.0 0.68 ug/L 10/28/24 16:04 Methylene Chloride 3.7 J B 5.0 3.6 ug/L 10/28/24 16:04 Styrene <1.0 1.0 0.31 ug/L 10/28/24 16:04 Tetrachloroethene <1.0 1.0 0.39 ug/L 10/28/24 16:04 Tetrahydrofuran <10 *- 10 3.9 ug/L 10/28/24 16:04 Toluene <0.50 0.50 0.21 ug/L 10/28/24 16:04 trans- 1,2-Dichloroethene <1.0 1.0 0.44 ug/L 10/28/24 16:04 trans- 1,3-Dichloropropene <1.0 1.0 0.63 ug/L 10/28/24 16:04 trans- 1,4-Dichloro-2-butene <5.0 5.0 3.4 ug/L 10/28/24 16:04 Eurofins Chicago Page 41 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-1 Lab Sample ID: 500-258888-14 Date Collected: 10/22/24 14:30 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichloroethene <0.50 0.50 0.15 ug/L 10/28/24 16:04 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/28/24 16:04 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/28/24 16:04 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/28/24 16:04 1 Xylenes, Total <1.0 1.0 0.30 ug/L 10/28/24 16:04 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 92 75- 126 10128124 16:04 1 4-Bromofluorobenzene (Surr) 91 72 - 124 10128124 16:04 1 Dibromofluoromethane 101 75 - 120 10128124 16:04 1 Toluene-d8 (Surr) 100 75 - 120 10/28/24 16:04 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <3.0 3.0 1.3 ug/L 11/01/24 08:39 11/04/24 17:54 1 Arsenic 0.70 J 1.0 0.23 ug/L 11/01/24 08:39 11/04/24 17:54 1 Barium 1100 2.5 0.73 ug/L 11/01/24 08:39 11/04/24 17:54 1 Beryllium <1.0 1.0 0.53 ug/L 11/01/24 08:39 11/04/24 17:54 1 Cadmium <0.50 0.50 0.17 ug/L 11/01/24 08:39 11/04/24 17:54 1 Calcium 370000 200 44 ug/L 11/01/24 08:39 11/04/24 17:54 1 Chromium <5.0 5.0 1.1 ug/L 11/01/24 08:39 11/04/24 17:54 1 Cobalt <1.0 1.0 0.40 ug/L 11/01/24 08:39 11/04/24 17:54 1 Copper <2.0 2.0 0.50 ug/L 11/01/24 08:39 11/04/24 17:54 1 Iron <100 100 47 ug/L 11/01/24 08:39 11/04/24 17:54 1 Lead <0.50 0.50 0.19 ug/L 11/01/24 08:39 11/04/24 17:54 1 Manganese 9.3 2.5 0.79 ug/L 11/01/24 08:39 11/04/24 17:54 1 Nickel <2.0 2.0 0.63 ug/L 11/01/24 08:39 11/04/24 17:54 1 Selenium <2.5 2.5 0.98 ug/L 11/01/24 08:39 11/04/24 17:54 1 Silver 0.22 J 0.50 0.12 ug/L 11/01/24 08:39 11/04/24 17:54 1 Thallium <2.0 2.0 0.57 ug/L 11/01/24 08:39 11/04/24 17:54 1 Vanadium 7.0 5.0 2.2 ug/L 11/01/24 08:39 11/04/24 17:54 1 Zinc <10 10 6.9 ug/L 11/01/24 08:39 11/04/24 17:54 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury 1.6 0.20 0.076 ug/L 10/31/24 10:20 11/01/24 08:37 1 General Chemistry Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chloride (SW846 9056A) 1000000 100000 12000 ug/L 11/06/24 16:32 100 Sulfate (SW846 9056A) 14000 1000 210 ug/L 11/09/24 15:11 1 Alkalinity (SM 2320B) 150000 5000 3700 ug/L 11/01/24 14:58 1 Total Dissolved Solids (SM 2540C) 3900000 25000 11000 ug/L 10/28/24 15:10 1 Eurofins Chicago Page 42 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Job ID: 500-258888-1 Client Sample ID: Leachate Lab Sample ID: 500-258888-15 Date Collected: 10/22/24 15:45 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit 1,4-Dioxane 30 8.0 3.4 ug/L Surrogate Toluene-d8 (Surr) %Recovery Qualifier Limits 95 80-120 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL 1,1,1,2-Tetrachloroethane <1.0 1.0 1,1,1-Trichloroethane <1.0 1.0 1,1,2,2-Tetrachloroethane <1.0 1.0 1,1,2-Trichloroethane <1.0 1.0 1,1-Dichloroethane <1.0 1.0 1,1-Dichloroethene <1.0 1.0 1,2,3-Trichloropropane <2.0 2.0 1,2-Dibromo-3-Chloropropane <5.0 5.0 1,2-Dibromoethane <1.0 1.0 1,2-Dichlorobenzene <1.0 1.0 1,2-Dichloroethane <1.0 1.0 1,2-Dichloropropane <1.0 1.0 1,4-Dichlorobenzene <1.0 1.0 2-Butanone (MEK) <5.0 5.0 2-Hexanone <5.0 5.0 4-Methyl-2-pentanone (MIBK) <5.0 5.0 Acetone 17 10 Acrylonitrile <20 20 Benzene 0.81 0.50 Bromochloromethane <1.0 1.0 Bromodichloromethane <1.0 1.0 Bromoform <1.0 1.0 Bromomethane <3.0 3.0 Carbon disulfide 1.5 J 2.0 Carbon tetrachloride <1.0 1.0 Chlorobenzene <1.0 1.0 Chloroethane <5.0 5.0 Chloroform <2.0 2.0 Chloromethane <5.0 5.0 cis-1,2-Dichloroethene <1.0 1.0 cis-1,3-Dichloropropene <1.0 1.0 Dibromochloromethane <1.0 1.0 Dibromomethane <1.0 1.0 Ethylbenzene 1.2 0.50 lodomethane <3.0 3.0 Methylene Chloride 3.6 J B 5.0 Styrene <1.0 1.0 Tetrachloroethene <1.0 1.0 Toluene 1.1 0.50 trans- 1,2-Dichloroethene <1.0 1.0 trans- 1,3-Dichloropropene <1.0 1.0 trans- 1,4-Dichloro-2-butene <5.0 5.0 Trichloroethene <0.50 0.50 D Prepared Analyzed Dil Fac C 10/29/2417:00 20 Prepared Analyzed Dil Fac 10129124 17:00 20 MDL Unit D Prepared Analyzed Dil Fac 0.67 ug/L 10/28/2416:29 1 0.45 ug/L 10/28/2416:29 1 0.65 ug/L 10/28/2416:29 1 0.73 ug/L 10/28/2416:29 1 0.36 ug/L 10/28/2416:29 1 0.48 ug/L 10/28/2416:29 1 1.5 ug/L 10/28/2416:29 1 3.9 ug/L 10/28/2416:29 1 0.56 ug/L 10/28/2416:29 1 0.48 ug/L 10/28/2416:29 1 0.58 ug/L 10/28/2416:29 1 0.37 ug/L 10/28/2416:29 1 0.45 ug/L 10/28/2416:29 1 2.3 ug/L 10/28/2416:29 1 2.2 ug/L 10/28/2416:29 1 2.0 ug/L 10/28/2416:29 1 4.3 ug/L 10/28/2416:29 1 6.0 ug/L 10/28/2416:29 1 0.18 ug/L 10/28/2416:29 1 0.50 ug/L 10/28/2416:29 1 0.57 ug/L 10/28/2416:29 1 0.96 ug/L 10/28/2416:29 1 1.8 ug/L 10/28/2416:29 1 1.1 ug/L 10/28/2416:29 1 0.41 ug/L 10/28/2416:29 1 0.41 ug/L 10/28/2416:29 1 0.47 ug/L 10/28/2416:29 1 0.92 ug/L 10/28/2416:29 1 0.79 ug/L 10/28/2416:29 1 0.42 ug/L 10/28/2416:29 1 0.52 ug/L 10/28/2416:29 1 0.83 ug/L 10/28/2416:29 1 0.58 ug/L 10/28/2416:29 1 0.20 ug/L 10/28/2416:29 1 0.68 ug/L 10/28/2416:29 1 3.6 ug/L 10/28/2416:29 1 0.31 ug/L 10/28/2416:29 1 0.39 ug/L 10/28/2416:29 1 0.21 ug/L 10/28/2416:29 1 0.44 ug/L 10/28/2416:29 1 0.63 ug/L 10/28/2416:29 1 3.4 ug/L 10/28/2416:29 1 0.15 ug/L 10/28/2416:29 1 Eurofins Chicago Page 43 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: Leachate Lab Sample ID: 500-258888-15 Date Collected: 10/22/24 15:45 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/28/24 16:29 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/28/24 16:29 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/28/24 16:29 1 Xylenes, Total 2.1 1.0 0.30 ug/L 10/28/24 16:29 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 89 75- 126 10128124 16729 1 4-Bromofluorobenzene (Surr) 92 72 - 124 10/28/24 16:29 1 Dibromofluoromethane 101 75 - 120 10/28/24 16:29 1 Toluene-d8 (Surr) 102 75 - 120 10/28/24 16:29 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS - DL Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Tetrahydrofuran 700 100 39 ug/L 10/29/2418:59 10 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 116 75- 126 10129124 18:59 10 4-Bromofluorobenzene (Surr) 105 72 - 124 10129124 18:59 10 Dibromofluoromethane 107 75 - 120 10129124 18:59 10 Toluene-d8 (Surr) 102 75 - 120 10/29/24 18:59 10 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony 3.2 3.0 1.3 ug/L 11/01/24 08:39 11/04/24 17:56 1 Arsenic 100 1.0 0.23 ug/L 11/01/24 08:39 11/04/24 17:56 1 Barium 380 2.5 0.73 ug/L 11/01/24 08:39 11/04/24 17:56 1 Beryllium <1.0 1.0 0.53 ug/L 11/01/24 08:39 11/04/24 17:56 1 Cadmium <0.50 0.50 0.17 ug/L 11/01/24 08:39 11/04/24 17:56 1 Calcium 420000 200 44 ug/L 11/01/24 08:39 11/04/24 17:56 1 Chromium 44 5.0 1.1 ug/L 11/01/24 08:39 11/04/24 17:56 1 Cobalt 2.2 1.0 0.40 ug/L 11/01/24 08:39 11/04/24 17:56 1 Copper 0.50 J 2.0 0.50 ug/L 11/01/24 08:39 11/04/24 17:56 1 Iron 610 100 47 ug/L 11/01/24 08:39 11/04/24 17:56 1 Lead <0.50 0.50 0.19 ug/L 11/01/24 08:39 11/04/24 17:56 1 Manganese 510 2.5 0.79 ug/L 11/01/24 08:39 11/04/24 17:56 1 Nickel 3.7 2.0 0.63 ug/L 11/01/24 08:39 11/04/24 17:56 1 Selenium 3.7 2.5 0.98 ug/L 11/01/24 08:39 11/04/24 17:56 1 Silver <0.50 0.50 0.12 ug/L 11/01/24 08:39 11/04/24 17:56 1 Thallium <2.0 2.0 0.57 ug/L 11/01/24 08:39 11/04/24 17:56 1 Vanadium 21 5.0 2.2 ug/L 11/01/24 08:39 11/04/24 17:56 1 Zinc <10 10 6.9 ug/L 11/01/24 08:39 11/04/24 17:56 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury <0.20 0.20 0.076 ug/L 10/31/24 10:20 11/01/24 08:40 1 General Chemistry Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chloride (SW846 9056A) 97000 20000 2300 ug/L 11/06/24 16:48 20 Sulfate (SW846 9056A) 450000 20000 4100 ug/L 11/06/24 16:48 20 Alkalinity (SM 2320B) 1700000 5000 3700 ug/L 11/01/24 15:09 1 Eurofins Chicago Page 44 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill client Sample IU: Leacnate Date Collected: 10/22/24 15:45 Date Received: 10/23/24 09:40 F Job ID: 500-258888-1 Lab Sample ID: 500-258888-15 Matrix: Water General Chemistry (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Total Dissolved Solids (SM 2540C) 2800000 13000 5400 ug/L 10/28/24 15:17 1 Eurofins Chicago Page 45 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: SW-2 Lab Sample ID: 500-258888-16 Date Collected: 10/22/24 15:10 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane <0.40 0.40 0.17 ug/L 10/25/2401:12 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Toluene-d8 (Surr) 102 80 - 120 10125124 01:12 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed 1,1,1,2-Tetrachloroethane <1.0 1.0 0.67 ug/L 10/28/24 16:54 1,1,1-Trichloroethane <1.0 1.0 0.45 ug/L 10/28/24 16:54 1,1,2,2-Tetrachloroethane <1.0 1.0 0.65 ug/L 10/28/24 16:54 1,1,2-Trichloroethane <1.0 1.0 0.73 ug/L 10/28/24 16:54 1,1-Dichloroethane <1.0 1.0 0.36 ug/L 10/28/24 16:54 1,1-Dichloroethene <1.0 1.0 0.48 ug/L 10/28/24 16:54 1,2,3-Trichloropropane <2.0 2.0 1.5 ug/L 10/28/24 16:54 1,2-Dibromo-3-Chloropropane <5.0 5.0 3.9 ug/L 10/28/24 16:54 1,2-Dibromoethane <1.0 1.0 0.56 ug/L 10/28/24 16:54 1,2-Dichlorobenzene <1.0 1.0 0.48 ug/L 10/28/24 16:54 1,2-Dichloroethane <1.0 1.0 0.58 ug/L 10/28/24 16:54 1,2-Dichloropropane <1.0 1.0 0.37 ug/L 10/28/24 16:54 1,4-Dichlorobenzene <1.0 1.0 0.45 ug/L 10/28/24 16:54 2-Butanone (MEK) <5.0 5.0 2.3 ug/L 10/28/24 16:54 2-Hexanone <5.0 5.0 2.2 ug/L 10/28/24 16:54 4-Methyl-2-pentanone (MIBK) <5.0 5.0 2.0 ug/L 10/28/24 16:54 Acetone <10 10 4.3 ug/L 10/28/24 16:54 Acrylonitrile <20 20 6.0 ug/L 10/28/24 16:54 Benzene <0.50 0.50 0.18 ug/L 10/28/24 16:54 Bromochloromethane <1.0 1.0 0.50 ug/L 10/28/24 16:54 Bromodichloromethane <1.0 1.0 0.57 ug/L 10/28/24 16:54 Bromoform <1.0 1.0 0.96 ug/L 10/28/24 16:54 Bromomethane <3.0 3.0 1.8 ug/L 10/28/24 16:54 Carbon disulfide <2.0 2.0 1.1 ug/L 10/28/24 16:54 Carbon tetrachloride <1.0 1.0 0.41 ug/L 10/28/24 16:54 Chlorobenzene <1.0 1.0 0.41 ug/L 10/28/24 16:54 Chloroethane <5.0 5.0 0.47 ug/L 10/28/24 16:54 Chloroform <2.0 2.0 0.92 ug/L 10/28/24 16:54 Chloromethane <5.0 5.0 0.79 ug/L 10/28/24 16:54 cis-1,2-Dichloroethene <1.0 1.0 0.42 ug/L 10/28/24 16:54 cis-1,3-Dichloropropene <1.0 1.0 0.52 ug/L 10/28/24 16:54 Dibromochloromethane <1.0 1.0 0.83 ug/L 10/28/24 16:54 Dibromomethane <1.0 1.0 0.58 ug/L 10/28/24 16:54 Ethylbenzene <0.50 0.50 0.20 ug/L 10/28/24 16:54 lodomethane <3.0 3.0 0.68 ug/L 10/28/24 16:54 Methylene Chloride 3.9 J B 5.0 3.6 ug/L 10/28/24 16:54 Styrene <1.0 1.0 0.31 ug/L 10/28/24 16:54 Tetrachloroethene <1.0 1.0 0.39 ug/L 10/28/24 16:54 Tetrahydrofuran <10 *- 10 3.9 ug/L 10/28/24 16:54 Toluene 0.21 J 0.50 0.21 ug/L 10/28/24 16:54 trans- 1,2-Dichloroethene <1.0 1.0 0.44 ug/L 10/28/24 16:54 trans- 1,3-Dichloropropene <1.0 1.0 0.63 ug/L 10/28/24 16:54 trans- 1,4-Dichloro-2-butene <5.0 5.0 3.4 ug/L 10/28/24 16:54 Eurofins Chicago Page 46 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: SW-2 Lab Sample ID: 500-258888-16 Date Collected: 10/22/24 15:10 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichloroethene <0.50 0.50 0.15 ug/L 10/28/24 16:54 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/28/24 16:54 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/28/24 16:54 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/28/24 16:54 1 Xylenes, Total <1.0 1.0 0.30 ug/L 10/28/24 16:54 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 88 75- 126 10128124 16:54 1 4-Bromofluorobenzene (Surr) 93 72 - 124 10128124 16:54 1 Dibromofluoromethane 104 75 - 120 10128124 16:54 1 Toluene-d8 (Surr) 101 75 - 120 10/28/24 16:54 1 Eurofins Chicago Page 47 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: SW-4 Lab Sample ID: 500-258888-17 Date Collected: 10/22/24 15:15 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane 0.21 J 0.40 0.17 ug/L 10/25/24 01:31 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Toluene-d8 (Surr) 85 80 - 120 10125124 01:31 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane <1.0 1.0 0.67 ug/L 10/28/24 17:19 1 1,1,1-Trichloroethane <1.0 1.0 0.45 ug/L 10/28/24 17:19 1 1,1,2,2-Tetrachloroethane <1.0 1.0 0.65 ug/L 10/28/24 17:19 1 1,1,2-Trichloroethane <1.0 1.0 0.73 ug/L 10/28/24 17:19 1 1,1-Dichloroethane <1.0 1.0 0.36 ug/L 10/28/24 17:19 1 1,1-Dichloroethene <1.0 1.0 0.48 ug/L 10/28/24 17:19 1 1,2,3-Trichloropropane <2.0 2.0 1.5 ug/L 10/28/24 17:19 1 1,2-Dibromo-3-Chloropropane <5.0 5.0 3.9 ug/L 10/28/24 17:19 1 1,2-Dibromoethane <1.0 1.0 0.56 ug/L 10/28/24 17:19 1 1,2-Dichlorobenzene <1.0 1.0 0.48 ug/L 10/28/24 17:19 1 1,2-Dichloroethane <1.0 1.0 0.58 ug/L 10/28/24 17:19 1 1,2-Dichloropropane <1.0 1.0 0.37 ug/L 10/28/24 17:19 1 1,4-Dichlorobenzene <1.0 1.0 0.45 ug/L 10/28/24 17:19 1 2-Butanone (MEK) <5.0 5.0 2.3 ug/L 10/28/24 17:19 1 2-Hexanone <5.0 5.0 2.2 ug/L 10/28/24 17:19 1 4-Methyl-2-pentanone (MIBK) <5.0 5.0 2.0 ug/L 10/28/24 17:19 1 Acetone <10 10 4.3 ug/L 10/28/24 17:19 1 Acrylonitrile <20 20 6.0 ug/L 10/28/24 17:19 1 Benzene <0.50 0.50 0.18 ug/L 10/28/24 17:19 1 Bromochloromethane <1.0 1.0 0.50 ug/L 10/28/24 17:19 1 Bromodichloromethane <1.0 1.0 0.57 ug/L 10/28/24 17:19 1 Bromoform <1.0 1.0 0.96 ug/L 10/28/24 17:19 1 Bromomethane <3.0 3.0 1.8 ug/L 10/28/24 17:19 1 Carbon disulfide <2.0 2.0 1.1 ug/L 10/28/24 17:19 1 Carbon tetrachloride <1.0 1.0 0.41 ug/L 10/28/24 17:19 1 Chlorobenzene <1.0 1.0 0.41 ug/L 10/28/24 17:19 1 Chloroethane <5.0 5.0 0.47 ug/L 10/28/24 17:19 1 Chloroform <2.0 2.0 0.92 ug/L 10/28/24 17:19 1 Chloromethane <5.0 5.0 0.79 ug/L 10/28/24 17:19 1 cis-1,2-Dichloroethene <1.0 1.0 0.42 ug/L 10/28/24 17:19 1 cis-1,3-Dichloropropene <1.0 1.0 0.52 ug/L 10/28/24 17:19 1 Dibromochloromethane <1.0 1.0 0.83 ug/L 10/28/24 17:19 1 Dibromomethane <1.0 1.0 0.58 ug/L 10/28/24 17:19 1 Ethylbenzene <0.50 0.50 0.20 ug/L 10/28/24 17:19 1 lodomethane <3.0 3.0 0.68 ug/L 10/28/24 17:19 1 Methylene Chloride <5.0 5.0 3.6 ug/L 10/28/24 17:19 1 Styrene <1.0 1.0 0.31 ug/L 10/28/24 17:19 1 Tetrachloroethene <1.0 1.0 0.39 ug/L 10/28/24 17:19 1 Tetrahydrofuran <10 *- 10 3.9 ug/L 10/28/24 17:19 1 Toluene <0.50 0.50 0.21 ug/L 10/28/24 17:19 1 trans- 1,2-Dichloroethene <1.0 1.0 0.44 ug/L 10/28/24 17:19 1 trans- 1,3-Dichloropropene <1.0 1.0 0.63 ug/L 10/28/24 17:19 1 trans- 1,4-Dichloro-2-butene <5.0 5.0 3.4 ug/L 10/28/24 17:19 1 Eurofins Chicago Page 48 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: SW-4 Lab Sample ID: 500-258888-17 Date Collected: 10/22/24 15:15 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichloroethene <0.50 0.50 0.15 ug/L 10/28/24 17:19 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/28/24 17:19 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/28/24 17:19 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/28/24 17:19 1 Xylenes, Total <1.0 1.0 0.30 ug/L 10/28/24 17:19 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 90 75- 126 10128124 17:19 1 4-Bromofluorobenzene (Surr) 94 72 - 124 10128124 17:19 1 Dibromofluoromethane 100 75 - 120 10128124 17:19 1 Toluene-d8 (Surr) 103 75 - 120 10/28/24 17:19 1 Eurofins Chicago Page 49 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Job ID: 500-258888-1 Client Sample ID: SW-1 Lab Sample ID: 500-258888-18 Date Collected: 10/22/24 15:20 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit 1,4-Dioxane <0.40 0.40 0.17 ug/L Surrogate Toluene-d8 (Surr) %Recovery Qualifier Limits 97 80-120 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL 1,1,1,2-Tetrachloroethane <1.0 1.0 1,1,1-Trichloroethane <1.0 1.0 1,1,2,2-Tetrachloroethane <1.0 1.0 1,1,2-Trichloroethane <1.0 1.0 1,1-Dichloroethane <1.0 1.0 1,1-Dichloroethene <1.0 1.0 1,2,3-Trichloropropane <2.0 2.0 1,2-Dibromo-3-Chloropropane <5.0 5.0 1,2-Dibromoethane <1.0 1.0 1,2-Dichlorobenzene <1.0 1.0 1,2-Dichloroethane <1.0 1.0 1,2-Dichloropropane <1.0 1.0 1,4-Dichlorobenzene <1.0 1.0 2-Butanone (MEK) <5.0 5.0 2-Hexanone <5.0 5.0 4-Methyl-2-pentanone (MIBK) <5.0 5.0 Acetone <10 10 Acrylonitrile <20 20 Benzene <0.50 0.50 Bromochloromethane <1.0 1.0 Bromodichloromethane <1.0 1.0 Bromoform <1.0 1.0 Bromomethane <3.0 3.0 Carbon disulfide <2.0 2.0 Carbon tetrachloride <1.0 1.0 Chlorobenzene <1.0 1.0 Chloroethane <5.0 5.0 Chloroform <2.0 2.0 Chloromethane <5.0 5.0 cis-1,2-Dichloroethene <1.0 1.0 cis-1,3-Dichloropropene <1.0 1.0 Dibromochloromethane <1.0 1.0 Dibromomethane <1.0 1.0 Ethylbenzene <0.50 0.50 lodomethane <3.0 3.0 Methylene Chloride 3.7 J B 5.0 Styrene <1.0 1.0 Tetrachloroethene <1.0 1.0 Tetrahydrofuran <10 *- 10 Toluene <0.50 0.50 trans- 1,2-Dichloroethene <1.0 1.0 trans- 1,3-Dichloropropene <1.0 1.0 trans- 1,4-Dichloro-2-butene <5.0 5.0 D Prepared Analyzed Dil Fac C 10/25/24 01:51 1 Prepared Analyzed Dil Fac 10125124 01:51 1 MDL Unit D Prepared Analyzed Dil Fac 0.67 ug/L 10/28/2417:43 1 0.45 ug/L 10/28/2417:43 1 0.65 ug/L 10/28/2417:43 1 0.73 ug/L 10/28/2417:43 1 0.36 ug/L 10/28/2417:43 1 0.48 ug/L 10/28/2417:43 1 1.5 ug/L 10/28/2417:43 1 3.9 ug/L 10/28/2417:43 1 0.56 ug/L 10/28/2417:43 1 0.48 ug/L 10/28/2417:43 1 0.58 ug/L 10/28/2417:43 1 0.37 ug/L 10/28/2417:43 1 0.45 ug/L 10/28/2417:43 1 2.3 ug/L 10/28/2417:43 1 2.2 ug/L 10/28/2417:43 1 2.0 ug/L 10/28/2417:43 1 4.3 ug/L 10/28/2417:43 1 6.0 ug/L 10/28/2417:43 1 0.18 ug/L 10/28/2417:43 1 0.50 ug/L 10/28/2417:43 1 0.57 ug/L 10/28/2417:43 1 0.96 ug/L 10/28/2417:43 1 1.8 ug/L 10/28/2417:43 1 1.1 ug/L 10/28/2417:43 1 0.41 ug/L 10/28/2417:43 1 0.41 ug/L 10/28/2417:43 1 0.47 ug/L 10/28/2417:43 1 0.92 ug/L 10/28/2417:43 1 0.79 ug/L 10/28/2417:43 1 0.42 ug/L 10/28/2417:43 1 0.52 ug/L 10/28/2417:43 1 0.83 ug/L 10/28/2417:43 1 0.58 ug/L 10/28/2417:43 1 0.20 ug/L 10/28/2417:43 1 0.68 ug/L 10/28/2417:43 1 3.6 ug/L 10/28/2417:43 1 0.31 ug/L 10/28/2417:43 1 0.39 ug/L 10/28/2417:43 1 3.9 ug/L 10/28/2417:43 1 0.21 ug/L 10/28/2417:43 1 0.44 ug/L 10/28/2417:43 1 0.63 ug/L 10/28/2417:43 1 3.4 ug/L 10/28/2417:43 1 Eurofins Chicago Page 50 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: SW-1 Lab Sample ID: 500-258888-18 Date Collected: 10/22/24 15:20 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichloroethene <0.50 0.50 0.15 ug/L 10/28/24 17:43 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/28/24 17:43 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/28/24 17:43 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/28/24 17:43 1 Xylenes, Total <1.0 1.0 0.30 ug/L 10/28/24 17:43 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 86 75- 126 10128124 17:43 1 4-Bromofluorobenzene (Surr) 92 72 - 124 10128124 17:43 1 Dibromofluoromethane 98 75 - 120 10128124 17:43 1 Toluene-d8 (Surr) 100 75 - 120 10/28/24 17:43 1 Eurofins Chicago Page 51 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: SW-3R Lab Sample ID: 500-258888-19 Date Collected: 10/22/24 16:15 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane <0.40 0.40 0.17 ug/L 10/29/2414:22 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Toluene-d8 (Surr) 95 80 - 120 10129124 14:22 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed 1,1,1,2-Tetrachloroethane <1.0 1.0 0.67 ug/L 10/28/24 18:08 1,1,1-Trichloroethane <1.0 1.0 0.45 ug/L 10/28/24 18:08 1,1,2,2-Tetrachloroethane <1.0 1.0 0.65 ug/L 10/28/24 18:08 1,1,2-Trichloroethane <1.0 1.0 0.73 ug/L 10/28/24 18:08 1,1-Dichloroethane <1.0 1.0 0.36 ug/L 10/28/24 18:08 1,1-Dichloroethene <1.0 1.0 0.48 ug/L 10/28/24 18:08 1,2,3-Trichloropropane <2.0 2.0 1.5 ug/L 10/28/24 18:08 1,2-Dibromo-3-Chloropropane <5.0 5.0 3.9 ug/L 10/28/24 18:08 1,2-Dibromoethane <1.0 1.0 0.56 ug/L 10/28/24 18:08 1,2-Dichlorobenzene <1.0 1.0 0.48 ug/L 10/28/24 18:08 1,2-Dichloroethane <1.0 1.0 0.58 ug/L 10/28/24 18:08 1,2-Dichloropropane <1.0 1.0 0.37 ug/L 10/28/24 18:08 1,4-Dichlorobenzene <1.0 1.0 0.45 ug/L 10/28/24 18:08 2-Butanone (MEK) <5.0 5.0 2.3 ug/L 10/28/24 18:08 2-Hexanone <5.0 5.0 2.2 ug/L 10/28/24 18:08 4-Methyl-2-pentanone (MIBK) <5.0 5.0 2.0 ug/L 10/28/24 18:08 Acetone <10 10 4.3 ug/L 10/28/24 18:08 Acrylonitrile <20 20 6.0 ug/L 10/28/24 18:08 Benzene <0.50 0.50 0.18 ug/L 10/28/24 18:08 Bromochloromethane <1.0 1.0 0.50 ug/L 10/28/24 18:08 Bromodichloromethane <1.0 1.0 0.57 ug/L 10/28/24 18:08 Bromoform <1.0 1.0 0.96 ug/L 10/28/24 18:08 Bromomethane <3.0 3.0 1.8 ug/L 10/28/24 18:08 Carbon disulfide <2.0 2.0 1.1 ug/L 10/28/24 18:08 Carbon tetrachloride <1.0 1.0 0.41 ug/L 10/28/24 18:08 Chlorobenzene <1.0 1.0 0.41 ug/L 10/28/24 18:08 Chloroethane <5.0 5.0 0.47 ug/L 10/28/24 18:08 Chloroform <2.0 2.0 0.92 ug/L 10/28/24 18:08 Chloromethane <5.0 5.0 0.79 ug/L 10/28/24 18:08 cis-1,2-Dichloroethene <1.0 1.0 0.42 ug/L 10/28/24 18:08 cis-1,3-Dichloropropene <1.0 1.0 0.52 ug/L 10/28/24 18:08 Dibromochloromethane <1.0 1.0 0.83 ug/L 10/28/24 18:08 Dibromomethane <1.0 1.0 0.58 ug/L 10/28/24 18:08 Ethylbenzene <0.50 0.50 0.20 ug/L 10/28/24 18:08 lodomethane <3.0 3.0 0.68 ug/L 10/28/24 18:08 Methylene Chloride 3.7 J B 5.0 3.6 ug/L 10/28/24 18:08 Styrene <1.0 1.0 0.31 ug/L 10/28/24 18:08 Tetrachloroethene <1.0 1.0 0.39 ug/L 10/28/24 18:08 Tetrahydrofuran <10 *- 10 3.9 ug/L 10/28/24 18:08 Toluene <0.50 0.50 0.21 ug/L 10/28/24 18:08 trans- 1,2-Dichloroethene <1.0 1.0 0.44 ug/L 10/28/24 18:08 trans- 1,3-Dichloropropene <1.0 1.0 0.63 ug/L 10/28/24 18:08 trans- 1,4-Dichloro-2-butene <5.0 5.0 3.4 ug/L 10/28/24 18:08 Eurofins Chicago Page 52 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: SW-3R Lab Sample ID: 500-258888-19 Date Collected: 10/22/24 16:15 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichloroethene <0.50 0.50 0.15 ug/L 10/28/24 18:08 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/28/24 18:08 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/28/24 18:08 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/28/24 18:08 1 Xylenes, Total <1.0 1.0 0.30 ug/L 10/28/24 18:08 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 89 75- 126 10128124 18:08 1 4-Bromofluorobenzene (Surr) 93 72 - 124 10128124 18:08 1 Dibromofluoromethane 101 75 - 120 10128124 18:08 1 Toluene-d8 (Surr) 101 75 - 120 10/28/24 18:08 1 Eurofins Chicago Page 53 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Job ID: 500-258888-1 Client Sample ID: DUP-1 Lab Sample ID: 500-258888-20 Date Collected: 10/22/24 00:00 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit 1,4-Dioxane 2.8 0.40 0.17 ug/L Surrogate Toluene-d8 (Surr) %Recovery Qualifier Limits 95 80-120 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL 1,1,1,2-Tetrachloroethane <1.0 1.0 1,1,1-Trichloroethane <1.0 1.0 1,1,2,2-Tetrachloroethane <1.0 1.0 1,1,2-Trichloroethane <1.0 1.0 1,1-Dichloroethane <1.0 1.0 1,1-Dichloroethene <1.0 1.0 1,2,3-Trichloropropane <2.0 2.0 1,2-Dibromo-3-Chloropropane <5.0 5.0 1,2-Dibromoethane <1.0 1.0 1,2-Dichlorobenzene <1.0 1.0 1,2-Dichloroethane <1.0 1.0 1,2-Dichloropropane <1.0 1.0 1,4-Dichlorobenzene <1.0 1.0 2-Butanone (MEK) <5.0 5.0 2-Hexanone <5.0 5.0 4-Methyl-2-pentanone (MIBK) <5.0 5.0 Acetone <10 10 Acrylonitrile <20 20 Benzene 0.84 0.50 Bromochloromethane <1.0 1.0 Bromodichloromethane <1.0 1.0 Bromoform <1.0 1.0 Bromomethane <3.0 3.0 Carbon disulfide <2.0 2.0 Carbon tetrachloride <1.0 1.0 Chlorobenzene <1.0 1.0 Chloroethane <5.0 5.0 Chloroform <2.0 2.0 Chloromethane <5.0 5.0 cis-1,2-Dichloroethene <1.0 1.0 cis-1,3-Dichloropropene <1.0 1.0 Dibromochloromethane <1.0 1.0 Dibromomethane <1.0 1.0 Ethylbenzene <0.50 0.50 lodomethane <3.0 3.0 Methylene Chloride 3.6 J B 5.0 Styrene <1.0 1.0 Tetrachloroethene <1.0 1.0 Tetrahydrofuran <10 *- 10 Toluene <0.50 0.50 trans- 1,2-Dichloroethene <1.0 1.0 trans- 1,3-Dichloropropene <1.0 1.0 trans- 1,4-Dichloro-2-butene <5.0 5.0 D Prepared Analyzed Dil Fac C 10/29/24 16:20 1 Prepared Analyzed Dil Fac 10129124 16:20 1 MDL Unit D Prepared Analyzed Dil Fac 0.67 ug/L 10/28/2418:33 1 0.45 ug/L 10/28/2418:33 1 0.65 ug/L 10/28/2418:33 1 0.73 ug/L 10/28/2418:33 1 0.36 ug/L 10/28/2418:33 1 0.48 ug/L 10/28/2418:33 1 1.5 ug/L 10/28/2418:33 1 3.9 ug/L 10/28/2418:33 1 0.56 ug/L 10/28/2418:33 1 0.48 ug/L 10/28/2418:33 1 0.58 ug/L 10/28/2418:33 1 0.37 ug/L 10/28/2418:33 1 0.45 ug/L 10/28/2418:33 1 2.3 ug/L 10/28/2418:33 1 2.2 ug/L 10/28/2418:33 1 2.0 ug/L 10/28/2418:33 1 4.3 ug/L 10/28/2418:33 1 6.0 ug/L 10/28/2418:33 1 0.18 ug/L 10/28/2418:33 1 0.50 ug/L 10/28/2418:33 1 0.57 ug/L 10/28/2418:33 1 0.96 ug/L 10/28/2418:33 1 1.8 ug/L 10/28/2418:33 1 1.1 ug/L 10/28/2418:33 1 0.41 ug/L 10/28/2418:33 1 0.41 ug/L 10/28/2418:33 1 0.47 ug/L 10/28/2418:33 1 0.92 ug/L 10/28/2418:33 1 0.79 ug/L 10/28/2418:33 1 0.42 ug/L 10/28/2418:33 1 0.52 ug/L 10/28/2418:33 1 0.83 ug/L 10/28/2418:33 1 0.58 ug/L 10/28/2418:33 1 0.20 ug/L 10/28/2418:33 1 0.68 ug/L 10/28/2418:33 1 3.6 ug/L 10/28/2418:33 1 0.31 ug/L 10/28/2418:33 1 0.39 ug/L 10/28/2418:33 1 3.9 ug/L 10/28/2418:33 1 0.21 ug/L 10/28/2418:33 1 0.44 ug/L 10/28/2418:33 1 0.63 ug/L 10/28/2418:33 1 3.4 ug/L 10/28/2418:33 1 Eurofins Chicago Page 54 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: DUP-1 Lab Sample ID: 500-258888-20 Date Collected: 10/22/24 00:00 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichloroethene <0.50 0.50 0.15 ug/L 10/28/24 18:33 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/28/24 18:33 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/28/24 18:33 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/28/24 18:33 1 Xylenes, Total <1.0 1.0 0.30 ug/L 10/28/24 18:33 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 91 75- 126 10128124 18:33 1 4-Bromofluorobenzene (Surr) 96 72 - 124 10128124 18:33 1 Dibromofluoromethane 104 75 - 120 10128124 18:33 1 Toluene-d8 (Surr) 99 75 - 120 10/28/24 18:33 1 Eurofins Chicago Page 55 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Job ID: 500-258888-1 Client Sample ID: Trip Blank Lab Sample ID: 500-258888-21 Date Collected: 10/21/24 00:00 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit 1,4-Dioxane <0.40 0.40 0.17 ug/L Surrogate Toluene-d8 (Surr) %Recovery Qualifier Limits 95 80-120 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL 1,1,1,2-Tetrachloroethane <1.0 1.0 1,1,1-Trichloroethane <1.0 1.0 1,1,2,2-Tetrachloroethane <1.0 1.0 1,1,2-Trichloroethane <1.0 1.0 1,1-Dichloroethane <1.0 1.0 1,1-Dichloroethene <1.0 1.0 1,2,3-Trichloropropane <2.0 2.0 1,2-Dibromo-3-Chloropropane <5.0 5.0 1,2-Dibromoethane <1.0 1.0 1,2-Dichlorobenzene <1.0 1.0 1,2-Dichloroethane <1.0 1.0 1,2-Dichloropropane <1.0 1.0 1,4-Dichlorobenzene <1.0 1.0 2-Butanone (MEK) <5.0 5.0 2-Hexanone <5.0 5.0 4-Methyl-2-pentanone (MIBK) <5.0 5.0 Acetone <10 10 Acrylonitrile <20 20 Benzene <0.50 0.50 Bromochloromethane <1.0 1.0 Bromodichloromethane <1.0 1.0 Bromoform <1.0 1.0 Bromomethane <3.0 3.0 Carbon disulfide <2.0 2.0 Carbon tetrachloride <1.0 1.0 Chlorobenzene <1.0 1.0 Chloroethane <5.0 5.0 Chloroform <2.0 2.0 Chloromethane <5.0 5.0 cis-1,2-Dichloroethene <1.0 1.0 cis-1,3-Dichloropropene <1.0 1.0 Dibromochloromethane <1.0 1.0 Dibromomethane <1.0 1.0 Ethylbenzene <0.50 0.50 lodomethane <3.0 3.0 Methylene Chloride 10 B 5.0 Styrene <1.0 1.0 Tetrachloroethene <1.0 1.0 Tetrahydrofuran <10 10 Toluene <0.50 0.50 trans- 1,2-Dichloroethene <1.0 1.0 trans- 1,3-Dichloropropene <1.0 1.0 trans- 1,4-Dichloro-2-butene <5.0 5.0 D Prepared Analyzed Dil Fac C 10/29/24 11:21 1 Prepared Analyzed Dil Fac 10/29/24 11:21 1 MDL Unit D Prepared Analyzed Dil Fac 0.67 ug/L 10/29/2418:35 1 0.45 ug/L 10/29/2418:35 1 0.65 ug/L 10/29/2418:35 1 0.73 ug/L 10/29/2418:35 1 0.36 ug/L 10/29/2418:35 1 0.48 ug/L 10/29/2418:35 1 1.5 ug/L 10/29/2418:35 1 3.9 ug/L 10/29/2418:35 1 0.56 ug/L 10/29/2418:35 1 0.48 ug/L 10/29/2418:35 1 0.58 ug/L 10/29/2418:35 1 0.37 ug/L 10/29/2418:35 1 0.45 ug/L 10/29/2418:35 1 2.3 ug/L 10/29/2418:35 1 2.2 ug/L 10/29/2418:35 1 2.0 ug/L 10/29/2418:35 1 4.3 ug/L 10/29/2418:35 1 6.0 ug/L 10/29/2418:35 1 0.18 ug/L 10/29/2418:35 1 0.50 ug/L 10/29/2418:35 1 0.57 ug/L 10/29/2418:35 1 0.96 ug/L 10/29/2418:35 1 1.8 ug/L 10/29/2418:35 1 1.1 ug/L 10/29/2418:35 1 0.41 ug/L 10/29/2418:35 1 0.41 ug/L 10/29/2418:35 1 0.47 ug/L 10/29/2418:35 1 0.92 ug/L 10/29/2418:35 1 0.79 ug/L 10/29/2418:35 1 0.42 ug/L 10/29/2418:35 1 0.52 ug/L 10/29/2418:35 1 0.83 ug/L 10/29/2418:35 1 0.58 ug/L 10/29/2418:35 1 0.20 ug/L 10/29/2418:35 1 0.68 ug/L 10/29/2418:35 1 3.6 ug/L 10/29/2418:35 1 0.31 ug/L 10/29/2418:35 1 0.39 ug/L 10/29/2418:35 1 3.9 ug/L 10/29/2418:35 1 0.21 ug/L 10/29/2418:35 1 0.44 ug/L 10/29/2418:35 1 0.63 ug/L 10/29/2418:35 1 3.4 ug/L 10/29/2418:35 1 Eurofins Chicago Page 56 of 99 11/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: Trip Blank Lab Sample ID: 500-258888-21 Date Collected: 10/21/24 00:00 Matrix: Water Date Received: 10/23/24 09:40 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichloroethene <0.50 0.50 0.15 ug/L 10/29/24 18:35 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/29/24 18:35 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/29/24 18:35 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/29/24 18:35 1 Xylenes, Total <1.0 1.0 0.30 ug/L 10/29/24 18:35 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 117 75- 126 10129124 18:35 1 4-Bromofluorobenzene (Surr) 107 72 - 124 10/29/24 18:35 1 Dibromofluoromethane 110 75 - 120 10/29/24 18:35 1 Toluene-d8 (Surr) 97 75 - 120 10/29/24 18:35 1 Eurofins Chicago Page 57 of 99 11/12/2024 Definitions/Glossary Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Qualifiers GC/MS VOA Qualifier B J Metals Job ID: 500-258888-1 Qualifier Description LCS and/or LCSD is outside acceptance limits, low biased. Compound was found in the blank and sample. L Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value. Qualifier Qualifier Description 4 MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not applicable. J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value. General Chemistry Qualifier Qualifier Description F3 Duplicate RPD exceeds the control limit Glossary Abbreviation These commonly used abbreviations may or may not be present in this report. Listed under the "D" column to designate that the result is reported on a dry weight basis %R Percent Recovery CFL Contains Free Liquid CFU Colony Forming Unit CNF Contains No Free Liquid DER Duplicate Error Ratio (normalized absolute difference) Dil Fac Dilution Factor DL Detection Limit (DoD/DOE) DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample DLC Decision Level Concentration (Radiochemistry) EDL Estimated Detection Limit (Dioxin) LOD Limit of Detection (DoD/DOE) LOQ Limit of Quantitation (DoD/DOE) MCL EPA recommended "Maximum Contaminant Level' MDA Minimum Detectable Activity (Radiochemistry) MDC Minimum Detectable Concentration (Radiochemistry) MDL Method Detection Limit ML Minimum Level (Dioxin) MPN Most Probable Number MQL Method Quantitation Limit NC Not Calculated ND Not Detected at the reporting limit (or MDL or EDL if shown) NEG Negative / Absent POS Positive / Present PQL Practical Quantitation Limit PRIES Presumptive QC Quality Control RER Relative Error Ratio (Radiochemistry) RL Reporting Limit or Requested Limit (Radiochemistry) RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) TNTC Too Numerous To Count Eurofins Chicago Page 58 of 99 11/12/2024 QC Association Summary Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill GC/MS VOA Analysis Batch: 567628 Job ID: 500-258888-1 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 500-258888-5 MW-4 Total/NA Water 8260D SIM 14D 500-258888-6 MW-5 Total/NA Water 8260D SIM 14D 500-258888-7 MW-6 Total/NA Water 8260D SIM 14D 500-258888-8 MW-7 Total/NA Water 8260D SIM 14D 500-258888-10 MW-9 Total/NA Water 8260D SIM 14D 500-258888-14 MW-1 Total/NA Water 8260D SIM 14D 500-258888-16 SW-2 Total/NA Water 8260D SIM 14D 500-258888-17 SW-4 Total/NA Water 8260D SIM 14D 500-258888-18 SW-1 Total/NA Water 8260D SIM 14D MB 410-567628/35 Method Blank Total/NA Water 8260D SIM 14D LCS 410-567628/4 Lab Control Sample Total/NA Water 8260D SIM 14D LCSD 410-567628/5 Lab Control Sample Dup Total/NA Water 8260D SIM 14D Analysis Batch: 568895 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 500-258888-1 MW-11R Total/NA Water 8260DSIM14D 500-258888-2 MW-0 Total/NA Water 8260D SIM 14D 500-258888-3 MW-2 Total/NA Water 8260D SIM 14D 500-258888-4 MW-3 Total/NA Water 8260D SIM 14D 500-258888-9 MW-8 Total/NA Water 8260D SIM 14D 500-258888-11 MW-12 Total/NA Water 8260D SIM 14D 500-258888-12 MW-13R Total/NA Water 8260D SIM 14D 500-258888-13 MW-14 Total/NA Water 8260D SIM 14D 500-258888-15 Leachate Total/NA Water 8260D SIM 14D 500-258888-19 SW-3R Total/NA Water 8260D SIM 14D 500-258888-20 DUP-1 Total/NA Water 8260D SIM 14D 500-258888-21 Trip Blank Total/NA Water 8260D SIM 14D MB 410-568895/7 Method Blank Total/NA Water 8260D SIM 14D LCS 410-568895/4 Lab Control Sample Total/NA Water 8260D SIM 14D LCSD 410-568895/5 Lab Control Sample Dup Total/NA Water 8260D SIM 14D Analysis Batch: 792556 Lab Sample ID 500-258888-1 500-258888-2 500-258888-3 500-258888-4 500-258888-5 500-258888-6 500-258888-7 500-258888-8 500-258888-9 500-258888-10 500-258888-11 500-258888-12 500-258888-13 500-258888-14 500-258888-15 500-258888-16 500-258888-17 500-258888-18 Client Sample ID MW-11 R MW-0 MW-2 MW-3 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9 MW-12 MW-13R MW-14 MW-1 Leachate SW-2 SW-4 SW-1 Prep Type Total/NA Total/NA Total/NA Total/NA Total/NA Total/NA Total/NA Total/NA Total/NA Total/NA Total/NA Total/NA Total/NA Total/NA Total/NA Total/NA Total/NA Total/NA Matrix Water Water Water Water Water Water Water Water Water Water Water Water Water Water Water Water Water Water Method 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D Prep Batch 0 Page 59 of 99 Eurofins Chicago 11 /12/2024 QC Association Summary Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill GC/MS VOA (Continued) Analysis Batch: 792556 (Continued) Lab Sample ID Client Sample ID 500-258888-19 SW-3R 500-258888-20 DUP-1 MB 500-792556/6 Method Blank LCS 500-792556/3 Lab Control Sample 500-258888-10 MS MW-9 500-258888-10 MSD MW-9 Analysis Batch: 792782 Lab Sample ID Client Sample ID 500-258888-15 - DL Leachate Trip Blank [500-258888-21 MB 500-792782/7 Method Blank LCS 500-792782/5 Lab Control Sample Job ID: 500-258888-1 Prep Type Matrix Method Prep Batch Total/NA Water 8260D Total/NA Water 8260D Total/NA Water 8260D Total/NA Water 8260D Total/NA Water 8260D Total/NA Water 8260D Prep Type Matrix Method Prep Batch Total/NA Water 8260D Total/NA Water 8260D Total/NA Water 8260D Total/NA Water 8260D Metals Prep Batch: 793293 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 500-258888-1 MW-11 R Total/NA Water 7470A 500-258888-2 MW-0 Total/NA Water 7470A 500-258888-3 MW-2 Total/NA Water 7470A 500-258888-4 MW-3 Total/NA Water 7470A 500-258888-5 MW-4 Total/NA Water 7470A 500-258888-6 MW-5 Total/NA Water 7470A 500-258888-7 MW-6 Total/NA Water 7470A 500-258888-8 MW-7 Total/NA Water 7470A 500-258888-9 MW-8 Total/NA Water 7470A 500-258888-10 MW-9 Total/NA Water 7470A 500-258888-11 MW-12 Total/NA Water 7470A 500-258888-12 MW-13R Total/NA Water 7470A 500-258888-13 MW-14 Total/NA Water 7470A 500-258888-14 MW-1 Total/NA Water 7470A 500-258888-15 Leachate Total/NA Water 7470A MB 500-793293/12-A Method Blank Total/NA Water 7470A LCS 500-793293/13-A Lab Control Sample Total/NA Water 7470A 500-258888-8 MS MW-7 Total/NA Water 7470A 500-258888-8 MSD MW-7 Total/NA Water 7470A 500-258888-8 DU MW-7 Total/NA Water 7470A Prep Batch: 793427 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 500-258888-1 MW-11 R Total Recoverable Water 3005A 500-258888-2 MW-0 Total Recoverable Water 3005A 500-258888-3 MW-2 Total Recoverable Water 3005A 500-258888-4 MW-3 Total Recoverable Water 3005A 500-258888-5 MW-4 Total Recoverable Water 3005A 500-258888-6 MW-5 Total Recoverable Water 3005A 500-258888-7 MW-6 Total Recoverable Water 3005A 500-258888-8 MW-7 Total Recoverable Water 3005A 500-258888-9 MW-8 Total Recoverable Water 3005A 500-258888-10 MW-9 Total Recoverable Water 3005A Eurofins Chicago Page 60 of 99 11/12/2024 QC Association Summary Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Metals (Continued) Prep Batch: 793427 (Continued) Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 500-258888-11 MW-12 Total Recoverable Water 3005A 500-258888-12 MW-13R Total Recoverable Water 3005A 500-258888-13 MW-14 Total Recoverable Water 3005A 500-258888-14 MW-1 Total Recoverable Water 3005A 500-258888-15 Leachate Total Recoverable Water 3005A MB 500-793427/1-A Method Blank Total Recoverable Water 3005A LCS 500-793427/2-A Lab Control Sample Total Recoverable Water 3005A 500-258888-1 MS MW-11 R Total Recoverable Water 3005A 500-258888-1 MSD MW-11 R Total Recoverable Water 3005A 500-258888-1 DU MW-11 R Total Recoverable Water 3005A Analysis Batch: 793508 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 500-258888-1 MW-11 R Total/NA Water 7470A 793293 500-258888-2 MW-0 Total/NA Water 7470A 793293 500-258888-3 MW-2 Total/NA Water 7470A 793293 500-258888-4 MW-3 Total/NA Water 7470A 793293 500-258888-5 MW-4 Total/NA Water 7470A 793293 500-258888-6 MW-5 Total/NA Water 7470A 793293 500-258888-7 MW-6 Total/NA Water 7470A 793293 500-258888-8 MW-7 Total/NA Water 7470A 793293 500-258888-9 MW-8 Total/NA Water 7470A 793293 500-258888-10 MW-9 Total/NA Water 7470A 793293 500-258888-11 MW-12 Total/NA Water 7470A 793293 500-258888-12 MW-13R Total/NA Water 7470A 793293 500-258888-13 MW-14 Total/NA Water 7470A 793293 500-258888-14 MW-1 Total/NA Water 7470A 793293 500-258888-15 Leachate Total/NA Water 7470A 793293 MB 500-793293/12-A Method Blank Total/NA Water 7470A 793293 LCS 500-793293/13-A Lab Control Sample Total/NA Water 7470A 793293 500-258888-8 MS MW-7 Total/NA Water 7470A 793293 500-258888-8 MSD MW-7 Total/NA Water 7470A 793293 L500-258888-8 DU MW-7 Total/NA Water 7470A 793293 Analysis Batch: 793897 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 500-258888-1 MW-11 R Total Recoverable Water 6020E 793427 500-258888-2 MW-0 Total Recoverable Water 6020E 793427 500-258888-3 MW-2 Total Recoverable Water 6020E 793427 500-258888-4 MW-3 Total Recoverable Water 6020B 793427 500-258888-5 MW-4 Total Recoverable Water 6020B 793427 500-258888-6 MW-5 Total Recoverable Water 6020B 793427 500-258888-7 MW-6 Total Recoverable Water 6020E 793427 500-258888-8 MW-7 Total Recoverable Water 6020E 793427 500-258888-9 MW-8 Total Recoverable Water 6020E 793427 500-258888-10 MW-9 Total Recoverable Water 6020B 793427 500-258888-11 MW-12 Total Recoverable Water 6020B 793427 500-258888-12 MW-13R Total Recoverable Water 6020B 793427 500-258888-13 MW-14 Total Recoverable Water 6020B 793427 500-258888-14 MW-1 Total Recoverable Water 6020B 793427 500-258888-15 Leachate Total Recoverable Water 6020B 793427 E Eurofins Chicago Page 61 of 99 11/12/2024 QC Association Summary Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Metals (Continued) Analysis Batch: 793897 (Continued) Lab Sample ID Client Sample ID MB 500-793427/1-A Method Blank LCS 500-793427/2-A Lab Control Sample 500-258888-1 MS MW-11 R 500-258888-1 MSD MW-11 R 500-258888-1 DU MW-11 R General Chem Analysis Batch: 792634 Lab Sample ID Client Sample ID 500-258888-1 MW-11 R 500-258888-2 MW-0 500-258888-3 MW-2 500-258888-4 MW-3 500-258888-5 MW-4 500-258888-6 MW-5 500-258888-7 MW-6 MB 500-792634/1 Method Blank LCS 500-792634/2 Lab Control Sample 500-258888-7 DU MW-6 Analysis Batch: 792683 Lab Sample ID Client Sample ID 500-258888-8 MW-7 500-258888-9 MW-8 500-258888-10 MW-9 500-258888-11 MW-12 500-258888-12 MW-13R 500-258888-13 MW-14 500-258888-14 MW-1 500-258888-15 Leachate MB 500-792683/1 Method Blank LCS 500-792683/2 Lab Control Sample 500-258888-8 MS MW-7 500-258888-8 DU MW-7 500-258888-12 DU MW-13R Analysis Batch: 793438 Lab Sample ID Client Sample ID 500-258888-1 MW-11 R 500-258888-2 MW-0 500-258888-3 MW-2 500-258888-4 MW-3 500-258888-5 MW-4 500-258888-6 MW-5 500-258888-7 MW-6 MB 500-793438/53 Method Blank LCS 500-793438/54 Lab Control Sample 500-258888-2 DU MW-0 Job ID: 500-258888-1 Prep Type Matrix Method Prep Batch Total Recoverable Water 6020B 793427 Total Recoverable Water 6020B 793427 Total Recoverable Water 6020B 793427 Total Recoverable Water 6020B 793427 Total Recoverable Water 6020B 793427 Prep Type Matrix Method Prep Batch Total/NA Water SM 2540C Total/NA Water SM 2540C Total/NA Water SM 2540C Total/NA Water SM 2540C Total/NA Water SM 2540C Total/NA Water SM 2540C Total/NA Water SM 2540C Total/NA Water SM 2540C Total/NA Water SM 2540C Total/NA Water SM 2540C Prep Type Matrix Method Prep Batch Total/NA Water SM 2540C Total/NA Water SM 2540C Total/NA Water SM 2540C Total/NA Water SM 2540C Total/NA Water SM 2540C Total/NA Water SM 2540C Total/NA Water SM 2540C Total/NA Water SM 2540C Total/NA Water SM 2540C Total/NA Water SM 2540C Total/NA Water SM 2540C Total/NA Water SM 2540C Total/NA Water SM 2540C Prep Type Matrix Method Prep Batch Total/NA Water SM 2320B Total/NA Water SM 2320B Total/NA Water SM 2320B Total/NA Water SM 2320B Total/NA Water SM 2320B Total/NA Water SM 2320B Total/NA Water SM 2320B Total/NA Water SM 2320B Total/NA Water SM 2320B Total/NA Water SM 2320B Page 62 of 99 Eurofins Chicago 11 /12/2024 QC Association Summary Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill General Chemistry Analysis Batch: 793688 Lab Sample ID Client Sample ID 500-258888-8 MW-7 500-258888-9 MW-8 500-258888-10 MW-9 500-258888-11 MW-12 500-258888-12 MW-13R 500-258888-13 MW-14 500-258888-14 MW-1 500-258888-15 Leachate MB 500-793688/3 Method Blank LCS 500-793688/4 Lab Control Sample Analysis Batch: 793982 Lab Sample ID Client Sample ID 500-258888-12 MW-13R 500-258888-13 MW-14 500-258888-14 MW-1 500-258888-15 Leachate MB 500-793982/3 Method Blank LCS 500-793982/4 Lab Control Sample Analysis Batch: 794184 Lab Sample ID Client Sample ID 500-258888-1 MW-11 R 500-258888-2 MW-0 500-258888-3 MW-2 500-258888-4 MW-3 500-258888-5 MW-4 500-258888-6 MW-5 MB 500-794184/3 Method Blank LCS 500-794184/4 Lab Control Sample Analysis Batch: 794207 Lab Sample ID Client Sample ID 500-258888-7 MW-6 500-258888-8 MW-7 500-258888-9 MW-8 500-258888-10 MW-9 MB 500-794207/3 Method Blank LCS 500-794207/4 Lab Control Sample Analysis Batch: 794364 Lab Sample ID Client Sample ID 500-258888-11 MW-12 500-258888-13 MW-14 500-258888-14 MW-1 MB 500-794364/3 Method Blank LCS 500-794364/4 Lab Control Sample Analysis Batch: 794677 Lab Sample ID Client Sample ID 500-258888-12 MW-13R Job ID: 500-258888-1 Prep Type Matrix Method Prep Batch Total/NA Water SM 2320B Total/NA Water SM 2320B Total/NA Water SM 2320B Total/NA Water SM 2320B Total/NA Water SM 2320B Total/NA Water SM 2320B Total/NA Water SM 2320B Total/NA Water SM 2320B Total/NA Water SM 2320B Total/NA Water SM 2320B Prep Type Matrix Method Prep Batch Total/NA Water 9056A Total/NA Water 9056A Total/NA Water 9056A Total/NA Water 9056A Total/NA Water 9056A Total/NA Water 9056A Prep Type Matrix Method Prep Batch Total/NA Water 9056A Total/NA Water 9056A Total/NA Water 9056A Total/NA Water 9056A Total/NA Water 9056A Total/NA Water 9056A Total/NA Water 9056A Total/NA Water 9056A Prep Type Matrix Method Prep Batch Total/NA Water 9056A Total/NA Water 9056A Total/NA Water 9056A Total/NA Water 9056A Total/NA Water 9056A Total/NA Water 9056A Prep Type Matrix Method Prep Batch Total/NA Water 9056A Total/NA Water 9056A Total/NA Water 9056A Total/NA Water 9056A Total/NA Water 9056A Prep Type Matrix Method Prep Batch Total/NA Water 9056A Eurofins Chicago Page 63 of 99 11/12/2024 QC Association Summary Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill General Chemistry (Continued) Analysis Batch: 794677 (Continued) Lab Sample ID Client Sample ID MB 500-794677/3 Method Blank LCS 500-794677/4 Lab Control Sample Analysis Batch: 794781 Lab Sample ID Client Sample ID 500-258888-2 MW-0 500-258888-3 MW-2 MB 500-794781/3 Method Blank LCS 500-794781/4 Lab Control Sample F Job ID: 500-258888-1 Prep Type Matrix Method Prep Batch Total/NA Water 9056A Total/NA Water 9056A Prep Type Matrix Method Prep Batch Total/NA Water 9056A Total/NA Water 9056A Total/NA Water 9056A Total/NA Water 9056A Eurofins Chicago Page 64 of 99 11/12/2024 Surrogate Summary Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Job ID: 500-258888-1 Method: 8260D - Volatile Organic Compounds by GC/MS Matrix: Water PreD TvDe: Total/NA Lab Sample ID 500-258888-1 500-258888-2 500-258888-3 500-258888-4 500-258888-5 500-258888-6 500-258888-7 500-258888-8 500-258888-9 500-258888-10 500-258888-10 MS 500-258888-10 MSD 500-258888-11 500-258888-12 500-258888-13 500-258888-14 500-258888-15 500-258888-15 - DL 500-258888-16 500-258888-17 500-258888-18 500-258888-19 500-258888-20 500-258888-21 LCS 500-792556/3 LCS 500-792782/5 MB 500-792556/6 MB 500-792782/7 Surrogate Legend Client Sample ID MW-11 R MW-0 MW-2 MW-3 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9 MW-9 MW-9 MW-12 MW-13R MW-14 MW-1 Leachate Leachate SW-2 SW-4 SW-1 SW-3R DUP-1 Trip Blank Lab Control Sample Lab Control Sample Method Blank Method Blank DCA= 1,2-Dichloroethane-d4 (Surr) BFB = 4-Bromofluorobenzene (Surr) DBFM = Dibromofluoromethane TOL = Toluene-d8 (Surr) DCA (75-126) Percent Surrogate Recovery (Acceptance Limits) BFB DBFM TOL (72-124) (75-120) (75-120) 89 91 99 102 89 92 100 101 87 98 99 102 86 94 98 99 88 95 100 102 88 89 103 102 90 90 103 99 87 92 100 101 91 91 100 102 89 94 103 98 87 87 97 103 86 91 100 101 88 92 99 102 91 87 100 103 90 92 102 101 92 91 101 100 89 92 101 102 116 105 107 102 88 93 104 101 90 94 100 103 86 92 98 100 89 93 101 101 91 96 104 99 117 107 110 97 84 91 97 105 116 104 107 99 88 91 99 102 117 107 102 98 Method: 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Matrix: Water Prep Type: Total/NA Lab Sample ID 500-258888-1 500-258888-2 500-258888-3 500-258888-4 500-258888-5 500-258888-6 500-258888-7 500-258888-8 500-258888-9 Client Sample ID MW-11 R MW-0 MW-2 MW-3 MW-4 MW-5 MW-6 MW-7 MW-8 Percent Surrogate Recovery (Acceptance Limits) TOL (80-120) 95 94 95 95 99 96 97 93 95 Page 65 of 99 Eurofins Chicago 11 /12/2024 Surrogate Summary Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Method: 8260D SIM 14D - Volatile Organic Compounds (GC/MS) (Continued) Matrix: Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) Lab Sample ID Client Sample ID TOL (80-120) 500-258888-10 MW-9 113 500-258888-11 MW-12 92 500-258888-12 MW-13R 95 500-258888-13 MW-14 94 500-258888-14 MW-1 101 500-258888-15 Leachate 95 500-258888-16 SW-2 102 500-258888-17 SW-4 85 500-258888-18 SW-1 97 500-258888-19 SW-3R 95 500-258888-20 DUP-1 95 m 500-258888-21 Trip Blank 95 LCS 410-567628/4 Lab Control Sample 107 LCS 410-568895/4 Lab Control Sample 95 LCSD 410-567628/5 Lab Control Sample Dup 94 LCSD 410-568895/5 Lab Control Sample Dup 95 MB 410-567628/35 Method Blank 93 E: MB 410-568895/7 Method Blank 95 Surrogate Legend TOL = Toluene-d8 (Surr) Eurofins Chicago Page 66 of 99 11/12/2024 QC Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Method: 8260D - Volatile Organic Compounds by GUMS Lab Sample ID: MB 500-792556/6 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 792556 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane <1.0 1.0 0.67 ug/L 10/28/24 10:19 1 1,1,1-Trichloroethane <1.0 1.0 0.45 ug/L 10/28/24 10:19 1 1,1,2,2-Tetrachloroethane <1.0 1.0 0.65 ug/L 10/28/24 10:19 1 1,1,2-Trichloroethane <1.0 1.0 0.73 ug/L 10/28/24 10:19 1 1,1-Dichloroethane <1.0 1.0 0.36 ug/L 10/28/24 10:19 1 1,1-Dichloroethene <1.0 1.0 0.48 ug/L 10/28/24 10:19 1 1,2,3-Trichloropropane <2.0 2.0 1.5 ug/L 10/28/24 10:19 1 1,2-Dibromo-3-Chloropropane <5.0 5.0 3.9 ug/L 10/28/24 10:19 1 1,2-Dibromoethane <1.0 1.0 0.56 ug/L 10/28/24 10:19 1 1,2-Dichlorobenzene <1.0 1.0 0.48 ug/L 10/28/24 10:19 1 1,2-Dichloroethane <1.0 1.0 0.58 ug/L 10/28/24 10:19 1 1,2-Dichloropropane <1.0 1.0 0.37 ug/L 10/28/24 10:19 1 1,4-Dichlorobenzene <1.0 1.0 0.45 ug/L 10/28/24 10:19 1 2-Butanone (MEK) <5.0 5.0 2.3 ug/L 10/28/24 10:19 1 2-Hexanone <5.0 5.0 2.2 ug/L 10/28/24 10:19 1 4-Methyl-2-pentanone (MIBK) <5.0 5.0 2.0 ug/L 10/28/24 10:19 1 Acetone <10 10 4.3 ug/L 10/28/24 10:19 1 Acrylonitrile <20 20 6.0 ug/L 10/28/24 10:19 1 Benzene <0.50 0.50 0.18 ug/L 10/28/24 10:19 1 Bromochloromethane <1.0 1.0 0.50 ug/L 10/28/24 10:19 1 Bromodichloromethane <1.0 1.0 0.57 ug/L 10/28/24 10:19 1 Bromoform <1.0 1.0 0.96 ug/L 10/28/24 10:19 1 Bromomethane <3.0 3.0 1.8 ug/L 10/28/24 10:19 1 Carbon disulfide <2.0 2.0 1.1 ug/L 10/28/24 10:19 1 Carbon tetrachloride <1.0 1.0 0.41 ug/L 10/28/24 10:19 1 Chlorobenzene <1.0 1.0 0.41 ug/L 10/28/24 10:19 1 Chloroethane <5.0 5.0 0.47 ug/L 10/28/24 10:19 1 Chloroform <2.0 2.0 0.92 ug/L 10/28/24 10:19 1 Chloromethane <5.0 5.0 0.79 ug/L 10/28/24 10:19 1 cis-1,2-Dichloroethene <1.0 1.0 0.42 ug/L 10/28/24 10:19 1 cis-1,3-Dichloropropene <1.0 1.0 0.52 ug/L 10/28/24 10:19 1 Dibromochloromethane <1.0 1.0 0.83 ug/L 10/28/24 10:19 1 Dibromomethane <1.0 1.0 0.58 ug/L 10/28/24 10:19 1 Ethylbenzene <0.50 0.50 0.20 ug/L 10/28/24 10:19 1 lodomethane <3.0 3.0 0.68 ug/L 10/28/24 10:19 1 Methylene Chloride 5.60 5.0 3.6 ug/L 10/28/24 10:19 1 Styrene <1.0 1.0 0.31 ug/L 10/28/24 10:19 1 Tetrachloroethene <1.0 1.0 0.39 ug/L 10/28/24 10:19 1 Tetrahydrofuran <10 10 3.9 ug/L 10/28/24 10:19 1 Toluene <0.50 0.50 0.21 ug/L 10/28/24 10:19 1 trans- 1,2-Dichloroethene <1.0 1.0 0.44 ug/L 10/28/24 10:19 1 trans- 1,3-Dichloropropene <1.0 1.0 0.63 ug/L 10/28/24 10:19 1 trans- 1,4-Dichloro-2-butene <5.0 5.0 3.4 ug/L 10/28/24 10:19 1 Trichloroethene <0.50 0.50 0.15 ug/L 10/28/24 10:19 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/28/24 10:19 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/28/24 10:19 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/28/24 10:19 1 Xylenes, Total <1.0 1.0 0.30 ug/L 10/28/24 10:19 1 Eurofins Chicago Page 67 of 99 11/12/2024 QC Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: MB 500-792556/6 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 792556 MB MB L Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 88 75- 126 10128124 10:19 1 4-Bromofluorobenzene (Surr) 91 72 - 124 10128124 10:19 1 Dibromofluoromethane 99 75 - 120 10128124 10:19 1 Toluene-d8 (Surr) 102 75 - 120 10128124 10:19 1 Lab Sample ID: LCS 500-792556/3 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA E: Analysis Batch: 792556 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,1,1,2-Tetrachloroethane 50.0 51.3 ug/L 103 70-125 1,1,1-Trichloroethane 50.0 45.4 ug/L 91 70-125 m 1,1,2,2-Tetrachloroethane 50.0 48.9 ug/L 98 62-140 1,1,2-Trichloroethane 50.0 48.9 ug/L 98 71-130 1,1-Dichloroethane 50.0 40.9 ug/L 82 70-125 1,1-Dichloroethene 50.0 46.6 ug/L 93 67-122 1,2,3-Trichloropropane 50.0 47.4 ug/L 95 50-133 1,2-Dibromo-3-Chloropropane 50.0 44.7 ug/L 89 56-123 1,2-Dibromoethane 50.0 52.0 ug/L 104 70-125 1,2-Dichlorobenzene 50.0 48.3 ug/L 97 70 -125 1,2-Dichloroethane 50.0 37.5 ug/L 75 68 -127 1,2-Dichloropropane 50.0 45.3 ug/L 91 67 -130 1,4-Dichlorobenzene 50.0 47.8 ug/L 96 70 -120 2-Butanone (MEK) 50.0 36.0 ug/L 72 46 -144 2-Hexanone 50.0 44.3 ug/L 89 54 -146 4-Methyl-2-pentanone (MIBK) 50.0 41.9 ug/L 84 55-139 Acetone 50.0 31.5 ug/L 63 40 -143 Acrylonitrile 500 345 ug/L 69 67 -140 Benzene 50.0 48.3 ug/L 97 70-120 Bromochloromethane 50.0 51.5 ug/L 103 65 -122 Bromodichloromethane 50.0 47.6 ug/L 95 69 -120 Bromoform 50.0 53.9 ug/L 108 56 -132 Bromomethane 50.0 54.1 ug/L 108 40 -152 Carbon disulfide 50.0 43.2 ug/L 86 66 -120 Carbon tetrachloride 50.0 53.9 ug/L 108 59 -133 Chlorobenzene 50.0 52.7 ug/L 105 70 -120 Chloroethane 50.0 43.8 ug/L 88 48 -136 Chloroform 50.0 48.0 ug/L 96 70 -120 Chloromethane 50.0 36.7 ug/L 73 56 -152 cis-1,2-Dichloroethene 50.0 48.8 ug/L 98 70 -125 cis-1,3-Dichloropropene 50.0 50.0 ug/L 100 64 -127 Dibromochloromethane 50.0 55.6 ug/L ill 68 -125 Dibromomethane 50.0 47.1 ug/L 94 70 -120 Ethylbenzene 50.0 52.5 ug/L 105 70 -123 lodomethane 50.0 41.6 ug/L 83 61 -136 Methylene Chloride 50.0 52.9 ug/L 106 69 -125 Styrene 50.0 54.0 ug/L 108 70 -120 Tetrachloroethene 50.0 51.3 ug/L 103 70 -128 Eurofins Chicago Page 68 of 99 11/12/2024 QC Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCS 500-792556/3 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 792556 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Tetrahydrofuran 100 58.4 ug/L 58 59 -139 Toluene 50.0 49.1 ug/L 98 70 -125 trans- 1,2-Dichloroethene 50.0 49.6 ug/L 99 70-125 trans- 1,3-Dichloropropene 50.0 48.1 ug/L 96 62 -128 trans- 1,4-Dichloro-2-butene 50.0 36.1 ug/L 72 60-130 Trichloroethene 50.0 51.1 ug/L 102 70 -125 Trichlorofluoromethane 50.0 46.6 ug/L 93 55 -128 Vinyl acetate 50.0 33.5 ug/L 67 43 -133 Vinyl chloride 50.0 41.7 ug/L 83 64 -126 Xylenes, Total 100 95.0 ug/L 95 70 -125 LCS LCS m Surrogate %Recovery Qualifier Limits 1,2-Dichloroethane-d4 (Surr) 84 75- 126 4-Bromofluorobenzene (Surr) 91 72 - 124 Dibromofluoromethane 97 75 - 120 Toluene-d8 (Surr) 105 75 - 120 Lab Sample ID: 500-258888-10 MS Client Sample ID: MW-9 Matrix: Water Prep Type: Total/NA Analysis Batch: 792556 Sample Sample Spike MS MS %Rec Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits 1,1,1,2-Tetrachloroethane <1.0 50.0 51.3 ug/L 103 70-125 1,1,1-Trichloroethane <1.0 50.0 47.9 ug/L 96 70-125 1,1,2,2-Tetrachloroethane <1.0 50.0 52.6 ug/L 105 62-140 1,1,2-Trichloroethane <1.0 50.0 52.9 ug/L 106 71-130 1,1-Dichloroethane <1.0 50.0 43.0 ug/L 86 70-125 1,1-Dichloroethene <1.0 50.0 46.7 ug/L 93 67-122 1,2,3-Trichloropropane <2.0 50.0 48.2 ug/L 96 50-133 1,2-Dibromo-3-Chloropropane <5.0 50.0 49.6 ug/L 99 56-123 1,2-Dibromoethane <1.0 50.0 53.2 ug/L 106 70-125 1,2-Dichlorobenzene <1.0 50.0 51.3 ug/L 103 70 -125 1,2-Dichloroethane <1.0 50.0 41.5 ug/L 83 68 -127 1,2-Dichloropropane <1.0 50.0 46.5 ug/L 93 67 -130 1,4-Dichlorobenzene <1.0 50.0 50.0 ug/L 100 70 -120 2-Butanone (MEK) <5.0 50.0 38.9 ug/L 78 46 -144 2-Hexanone <5.0 50.0 45.0 ug/L 90 54 -146 4-Methyl-2-pentanone (MIBK) <5.0 50.0 44.3 ug/L 89 55-139 Acetone <10 50.0 27.2 ug/L 54 40 -143 Acrylonitrile <20 500 359 ug/L 72 67 -140 Benzene 1.3 50.0 51.1 ug/L 100 70 -120 Bromochloromethane <1.0 50.0 53.3 ug/L 107 65 -122 Bromodichloromethane <1.0 50.0 50.2 ug/L 100 69 -120 Bromoform <1.0 50.0 54.8 ug/L 110 56 -132 Bromomethane <3.0 50.0 65.7 ug/L 131 40 -152 Carbon disulfide <2.0 50.0 44.5 ug/L 89 66 -120 Carbon tetrachloride <1.0 50.0 54.2 ug/L 108 59 -133 Chlorobenzene <1.0 50.0 53.8 ug/L 108 70 -120 Eurofins Chicago Page 69 of 99 11/12/2024 QC Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: 500-258888-10 MS Client Sample ID: MW-9 Matrix: Water Prep Type: Total/NA Analysis Batch: 792556 Sample Sample Spike MS MS %Rec Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits Chloroethane <5.0 50.0 47.5 ug/L 95 48 -136 Chloroform <2.0 50.0 51.3 ug/L 103 70 -120 Chloromethane <5.0 50.0 36.3 ug/L 73 56 -152 cis-1,2-Dichloroethene <1.0 50.0 51.1 ug/L 102 70 -125 cis-1,3-Dichloropropene <1.0 50.0 52.4 ug/L 105 64 -127 Dibromochloromethane <1.0 50.0 57.3 ug/L 115 68 -125 Dibromomethane <1.0 50.0 48.3 ug/L 97 70 -120 Ethylbenzene <0.50 50.0 54.0 ug/L 108 70 -123 lodomethane <3.0 50.0 38.6 ug/L 77 61 -136 Methylene Chloride 4.6 J B 50.0 53.2 ug/L 97 69 -125 Styrene <1.0 50.0 57.0 ug/L 114 70 -120 Tetrachloroethene <1.0 50.0 51.9 ug/L 104 70 -128 m Tetrahydrofuran <10 100 64.6 ug/L 65 59 -139 Toluene 0.29 J 50.0 50.5 ug/L 100 70 -125 trans- 1,2-Dichloroethene <1.0 50.0 51.3 ug/L 103 70-125 trans- 1,3-Dichloropropene <1.0 50.0 49.4 ug/L 99 62 -128 trans- 1,4-Dichloro-2-butene <5.0 50.0 38.5 ug/L 77 60-130 Trichloroethene <0.50 50.0 49.3 ug/L 99 70 -125 Trichlorofluoromethane <1.0 50.0 50.0 ug/L 100 55 -128 Vinyl acetate <2.0 50.0 37.2 ug/L 74 43 -133 Vinyl chloride <1.0 50.0 44.3 ug/L 89 64 -126 Xylenes, Total 0.55 J 100 101 ug/L 100 70 -125 MS MS Surrogate %Recovery Qualifier Limits 1,2-Dichloroethane-d4 (Surr) 87 75- 126 4-Bromofluorobenzene (Surr) 87 72. 124 Dibromofluoromethane 97 75 - 120 Toluene-d8 (Surr) 103 75 - 120 Lab Sample ID: 500-258888-10 MSD Client Sample ID: MW-9 Matrix: Water Prep Type: Total/NA Analysis Batch: 792556 Sample Sample Spike MSD MSD %Rec RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit 1,1,1,2-Tetrachloroethane <1.0 50.0 50.2 ug/L 100 70-125 2 20 1,1,1-Trichloroethane <1.0 50.0 48.9 ug/L 98 70-125 2 20 1,1,2,2-Tetrachloroethane <1.0 50.0 52.4 ug/L 105 62-140 0 20 1,1,2-Trichloroethane <1.0 50.0 51.8 ug/L 104 71-130 2 20 1,1-Dichloroethane <1.0 50.0 42.4 ug/L 85 70-125 1 20 1,1-Dichloroethene <1.0 50.0 47.2 ug/L 94 67-122 1 20 1,2,3-Trichloropropane <2.0 50.0 51.4 ug/L 103 50-133 6 20 1,2-Dibromo-3-Chloropropane <5.0 50.0 48.8 ug/L 98 56-123 2 20 1,2-Dibromoethane <1.0 50.0 53.2 ug/L 106 70-125 0 20 1,2-Dichlorobenzene <1.0 50.0 53.0 ug/L 106 70 -125 3 20 1,2-Dichloroethane <1.0 50.0 42.1 ug/L 84 68 -127 1 20 1,2-Dichloropropane <1.0 50.0 47.2 ug/L 94 67.130 2 20 1,4-Dichlorobenzene <1.0 50.0 50.4 ug/L 101 70 -120 1 20 2-Butanone (MEK) <5.0 50.0 36.6 ug/L 73 46 -144 6 20 Eurofins Chicago Page 70 of 99 11/12/2024 QC Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Job ID: 500-258888-1 Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: 500-258888-10 MSD Client Sample ID: MW-9 Matrix: Water Prep Type: Total/NA Analysis Batch: 792556 Sample Sample Spike MSD MSD %Rec RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit 2-Hexanone <5.0 50.0 44.3 ug/L 89 54 -146 2 20 4-Methyl-2-pentanone (MIBK) <5.0 50.0 43.7 ug/L 87 55-139 1 20 Acetone <10 50.0 26.0 ug/L 52 40-143 4 20 Acrylonitrile <20 500 369 ug/L 74 67 -140 3 20 Benzene 1.3 50.0 50.9 ug/L 99 70-120 0 20 F- Bromochloromethane <1.0 50.0 56.3 ug/L 113 65 -122 5 20 Bromodichloromethane <1.0 50.0 50.7 ug/L 101 69 -120 1 20 Bromoform <1.0 50.0 55.5 ug/L 111 56 -132 1 20 Bromomethane <3.0 50.0 59.1 ug/L 118 40 -152 11 20 Carbon disulfide <2.0 50.0 43.6 ug/L 87 66 -120 2 20 Carbon tetrachloride <1.0 50.0 55.4 ug/L ill 59-133 2 20 Chlorobenzene <1.0 50.0 54.6 ug/L 109 70-120 2 20 IM Chloroethane <5.0 50.0 46.4 ug/L 93 48 -136 2 20 Chloroform <2.0 50.0 49.5 ug/L 99 70 -120 3 20 Chloromethane <5.0 50.0 36.9 ug/L 74 56 -152 1 20 cis-1,2-Dichloroethene <1.0 50.0 51.4 ug/L 103 70 -125 0 20 cis-1,3-Dichloropropene <1.0 50.0 50.6 ug/L 101 64 -127 3 20 Dibromochloromethane <1.0 50.0 56.4 ug/L 113 68 -125 1 20 Dibromomethane <1.0 50.0 50.6 ug/L 101 70 -120 5 20 Ethylbenzene <0.50 50.0 53.3 ug/L 107 70 -123 1 20 lodomethane <3.0 50.0 46.6 ug/L 93 61-136 19 20 Methylene Chloride 4.6 J B 50.0 54.4 ug/L 100 69 -125 2 20 Styrene <1.0 50.0 54.9 ug/L 110 70 -120 4 20 Tetrachloroethene <1.0 50.0 52.3 ug/L 105 70 -128 1 20 Tetrahydrofuran <10 "- 100 64.8 ug/L 65 59 -139 0 20 Toluene 0.29 J 50.0 50.0 ug/L 99 70 -125 1 20 trans- 1,2-Dichloroethene <1.0 50.0 51.5 ug/L 103 70-125 0 20 trans- 1,3-Dichloropropene <1.0 50.0 48.6 ug/L 97 62 -128 2 20 trans- 1,4-Dichloro-2-butene <5.0 50.0 40.0 ug/L 80 60-130 4 20 Trichloroethene <0.50 50.0 51.3 ug/L 103 70 -125 4 20 Trichlorofluoromethane <1.0 50.0 46.3 ug/L 93 55 -128 8 20 Vinyl acetate <2.0 50.0 36.9 ug/L 74 43 -133 1 20 Vinyl chloride <1.0 50.0 42.8 ug/L 86 64 -126 4 20 Xylenes, Total 0.55 J 100 98.6 ug/L 98 70 -125 2 20 MSD MSD Surrogate %Recovery Qualifier Limits 1,2-Dichloroethane-d4 (Surr) 86 75- 126 4-Bromofluorobenzene (Surr) 91 72 - 124 Dibromofluoromethane 100 75- 120 Toluene-d8 (Surr) 101 75 - 120 Lab Sample ID: MB 500-792782/7 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 792782 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane <1.0 1.0 0.67 ug/L 10/29/2410:42 1 1,1,1-Trichloroethane <1.0 1.0 0.45 ug/L 10/29/2410:42 1 Eurofins Chicago Page 71 of 99 11/12/2024 QC Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Job ID: 500-258888-1 Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: MB 500-792782/7 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 792782 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,2,2-Tetrachloroethane <1.0 1.0 0.65 ug/L 10/29/24 10:42 1 1,1,2-Trichloroethane <1.0 1.0 0.73 ug/L 10/29/24 10:42 1 1,1-Dichloroethane <1.0 1.0 0.36 ug/L 10/29/24 10:42 1 1,1-Dichloroethene <1.0 1.0 0.48 ug/L 10/29/24 10:42 1 1,2,3-Trichloropropane <2.0 2.0 1.5 ug/L 10/29/24 10:42 1 1,2-Dibromo-3-Chloropropane <5.0 5.0 3.9 ug/L 10/29/24 10:42 1 1,2-Dibromoethane <1.0 1.0 0.56 ug/L 10/29/24 10:42 1 1,2-Dichlorobenzene <1.0 1.0 0.48 ug/L 10/29/24 10:42 1 1,2-Dichloroethane <1.0 1.0 0.58 ug/L 10/29/24 10:42 1 1,2-Dichloropropane <1.0 1.0 0.37 ug/L 10/29/24 10:42 1 1,4-Dichlorobenzene <1.0 1.0 0.45 ug/L 10/29/24 10:42 1 2-Butanone (MEK) <5.0 5.0 2.3 ug/L 10/29/24 10:42 1 2-Hexanone <5.0 5.0 2.2 ug/L 10/29/24 10:42 1 4-Methyl-2-pentanone (MIBK) <5.0 5.0 2.0 ug/L 10/29/24 10:42 1 Acetone <10 10 4.3 ug/L 10/29/24 10:42 1 Acrylonitrile <20 20 6.0 ug/L 10/29/24 10:42 1 Benzene <0.50 0.50 0.18 ug/L 10/29/24 10:42 1 Bromochloromethane <1.0 1.0 0.50 ug/L 10/29/24 10:42 1 Bromodichloromethane <1.0 1.0 0.57 ug/L 10/29/24 10:42 1 Bromoform <1.0 1.0 0.96 ug/L 10/29/24 10:42 1 Bromomethane <3.0 3.0 1.8 ug/L 10/29/24 10:42 1 Carbon disulfide <2.0 2.0 1.1 ug/L 10/29/24 10:42 1 Carbon tetrachloride <1.0 1.0 0.41 ug/L 10/29/24 10:42 1 Chlorobenzene <1.0 1.0 0.41 ug/L 10/29/24 10:42 1 Chloroethane <5.0 5.0 0.47 ug/L 10/29/24 10:42 1 Chloroform <2.0 2.0 0.92 ug/L 10/29/24 10:42 1 Chloromethane <5.0 5.0 0.79 ug/L 10/29/24 10:42 1 cis-1,2-Dichloroethene <1.0 1.0 0.42 ug/L 10/29/24 10:42 1 cis-1,3-Dichloropropene <1.0 1.0 0.52 ug/L 10/29/24 10:42 1 Dibromochloromethane <1.0 1.0 0.83 ug/L 10/29/24 10:42 1 Dibromomethane <1.0 1.0 0.58 ug/L 10/29/24 10:42 1 Ethylbenzene <0.50 0.50 0.20 ug/L 10/29/24 10:42 1 lodomethane <3.0 3.0 0.68 ug/L 10/29/24 10:42 1 Methylene Chloride 8.80 5.0 3.6 ug/L 10/29/24 10:42 1 Styrene <1.0 1.0 0.31 ug/L 10/29/24 10:42 1 Tetrachloroethene <1.0 1.0 0.39 ug/L 10/29/24 10:42 1 Tetrahydrofuran <10 10 3.9 ug/L 10/29/24 10:42 1 Toluene <0.50 0.50 0.21 ug/L 10/29/24 10:42 1 trans- 1,2-Dichloroethene <1.0 1.0 0.44 ug/L 10/29/24 10:42 1 trans- 1,3-Dichloropropene <1.0 1.0 0.63 ug/L 10/29/24 10:42 1 trans- 1,4-Dichloro-2-butene <5.0 5.0 3.4 ug/L 10/29/24 10:42 1 Trichloroethene <0.50 0.50 0.15 ug/L 10/29/24 10:42 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 10/29/24 10:42 1 Vinyl acetate <2.0 2.0 0.78 ug/L 10/29/24 10:42 1 Vinyl chloride <1.0 1.0 0.47 ug/L 10/29/24 10:42 1 Xylenes, Total <1.0 1.0 0.30 ug/L 10/29/24 10:42 1 Ill Eurofins Chicago Page 72 of 99 11/12/2024 QC Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: MB 500-792782/7 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 792782 MB MB L Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 117 75- 126 10129124 10:42 1 4-Bromofluorobenzene (Surr) 107 72 - 124 10129124 10:42 1 Dibromofluoromethane 102 75 - 120 10129124 10:42 1 Toluene-d8 (Surr) 98 75 - 120 10129124 10:42 1 Lab Sample ID: LCS 500-792782/5 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA E: Analysis Batch: 792782 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,1,1,2-Tetrachloroethane 50.0 44.3 ug/L 89 70-125 1,1,1-Trichloroethane 50.0 53.8 ug/L 108 70-125 m 1,1,2,2-Tetrachloroethane 50.0 41.5 ug/L 83 62-140 1,1,2-Trichloroethane 50.0 40.3 ug/L 81 71-130 1,1-Dichloroethane 50.0 46.7 ug/L 93 70-125 1,1-Dichloroethene 50.0 48.9 ug/L 98 67-122 1,2,3-Trichloropropane 50.0 43.1 ug/L 86 50-133 1,2-Dibromo-3-Chloropropane 50.0 46.6 ug/L 93 56-123 1,2-Dibromoethane 50.0 42.3 ug/L 85 70-125 1,2-Dichlorobenzene 50.0 40.1 ug/L 80 70 -125 1,2-Dichloroethane 50.0 47.0 ug/L 94 68 -127 1,2-Dichloropropane 50.0 40.1 ug/L 80 67 -130 1,4-Dichlorobenzene 50.0 41.0 ug/L 82 70 -120 2-Butanone (MEK) 50.0 56.4 ug/L 113 46 -144 2-Hexanone 50.0 48.4 ug/L 97 54 -146 4-Methyl-2-pentanone (MIBK) 50.0 48.2 ug/L 96 55-139 Acetone 50.0 60.2 ug/L 120 40 -143 Acrylonitrile 500 519 ug/L 104 67 -140 Benzene 50.0 42.7 ug/L 85 70-120 Bromochloromethane 50.0 43.9 ug/L 88 65 -122 Bromodichloromethane 50.0 43.4 ug/L 87 69 -120 Bromoform 50.0 42.4 ug/L 85 56 -132 Bromomethane 50.0 40.0 ug/L 80 40 -152 Carbon disulfide 50.0 45.3 ug/L 91 66 -120 Carbon tetrachloride 50.0 57.2 ug/L 114 59 -133 Chlorobenzene 50.0 40.9 ug/L 82 70 -120 Chloroethane 50.0 51.5 ug/L 103 48 -136 Chloroform 50.0 44.1 ug/L 88 70 -120 Chloromethane 50.0 47.4 ug/L 95 56 -152 cis-1,2-Dichloroethene 50.0 42.0 ug/L 84 70 -125 cis-1,3-Dichloropropene 50.0 41.5 ug/L 83 64 -127 Dibromochloromethane 50.0 43.1 ug/L 86 68 -125 Dibromomethane 50.0 44.2 ug/L 88 70 -120 Ethylbenzene 50.0 44.1 ug/L 88 70 -123 lodomethane 50.0 32.2 ug/L 64 61 -136 Methylene Chloride 50.0 51.0 ug/L 102 69 -125 Styrene 50.0 41.2 ug/L 82 70 -120 Tetrachloroethene 50.0 44.6 ug/L 89 70 -128 Eurofins Chicago Page 73 of 99 11/12/2024 QC Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill F Job ID: 500-258888-1 Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Lab Sample ID: LCS 500-792782/5 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 792782 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Tetrahydrofuran 100 99.6 ug/L 100 59 -139 Toluene 50.0 41.7 ug/L 83 70 -125 trans- 1,2-Dichloroethene 50.0 46.6 ug/L 93 70-125 trans- 1,3-Dichloropropene 50.0 42.4 ug/L 85 62 -128 trans- 1,4-Dichloro-2-butene 50.0 48.2 ug/L 96 60-130 Trichloroethene 50.0 46.5 ug/L 93 70 -125 Trichlorofluoromethane 50.0 58.3 ug/L 117 55 -128 Vinyl acetate 50.0 53.4 ug/L 107 43 -133 Vinyl chloride 50.0 52.1 ug/L 104 64 -126 Xylenes, Total 100 87.6 ug/L 88 70 -125 LCS LCS Surrogate %Recovery Qualifier Limits 1,2-Dichloroethane-d4 (Surr) 116 75- 126 4-Bromofluorobenzene (Surr) 104 72 - 124 Dibromofluoromethane 107 75 - 120 Toluene-d8 (Surr) 99 75 - 120 Method: 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Lab Sample ID: MB 410-567628/35 Matrix: Water Analysis Batch: 567628 MB MB Analyte Result Qualifier 1,4-Dioxane <0.40 MB MB Surrogate %Recovery Qualifier Toluene-d8 (Surr) 93 Lab Sample ID: LCS 410-567628/4 Matrix: Water Analysis Batch: 567628 Analyte 1,4-Dioxane LCS LCS Surrogate %Recovery Qualifier Toluene-d8 (Surr) 107 Lab Sample ID: LCSD 410-567628/5 Matrix: Water Analysis Batch: 567628 Analyte 1,4-Dioxane LCSD LCSD Surrogate %Recovery Qualifier Toluene-d8 (Surr) 94 Client Sample ID: Method Blank Prep Type: Total/NA RL MDL Unit D Prepared Analyzed Dil Fac 0.40 0.17 ug/L 10/24/24 23:13 1 Limits Prepared Analyzed Dil Fac 80 - 120 10124124 23:13 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS %Rec Added Result Qualifier Unit D %Rec Limits 4.99 5.31 ug/L 106 74-133 Limits 80 - 120 Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA Spike LCSD LCSD %Rec RPD Added Result Qualifier Unit D %Rec Limits RPD Limit 4.99 4.94 ug/L 99 74-133 7 20 Limits 80-120 Page 74 of 99 Eurofins Chicago 11 /12/2024 QC Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Method: 8260D SIM 14D - Volatile Organic Compounds (GC/MS) Lab Sample ID: MB 410-568895/7 Matrix: Water Analysis Batch: 568895 MB MB Analyte Result Qualifier RL MDL Unit 1,4-Dioxane <0.40 0.40 0.17 ug/L F Job ID: 500-258888-1 Client Sample ID: Method Blank Prep Type: Total/NA L D Prepared Analyzed Dil Fac 10/29/24 10:41 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Toluene-d8 (Surr) 95 80 - 120 10129124 10:41 1 Lab Sample ID: LCS 410-568895/4 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 568895 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,4-Dioxane 4.99 5.34 ug/L 107 74-133 m LCS LCS Surrogate %Recovery Qualifier Limits Toluene-d8 (Surr) 95 80 - 120 Lab Sample ID: LCSD 410-56889515 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 568895 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit 1,4-Dioxane 4.99 4.46 ug/L 89 74 -133 18 20 LCSD LCSD Surrogate %Recovery Qualifier Limits Toluene-d8 (Surr) 95 80 - 120 Method: 6020B - Metals (ICP/MS) Lab Sample ID: MB 500-793427/1-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total Recoverable Analysis Batch: 793897 Prep Batch: 793427 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <3.0 3.0 1.3 ug/L 11/01/24 08:39 11/04/24 17:01 1 Arsenic <1.0 1.0 0.23 ug/L 11/01/24 08:39 11/04/24 17:01 1 Barium <2.5 2.5 0.73 ug/L 11/01/24 08:39 11/04/24 17:01 1 Beryllium <1.0 1.0 0.53 ug/L 11/01/24 08:39 11/04/24 17:01 1 Cadmium <0.50 0.50 0.17 ug/L 11/01/24 08:39 11/04/24 17:01 1 Calcium <200 200 44 ug/L 11/01/24 08:39 11/04/24 17:01 1 Chromium <5.0 5.0 1.1 ug/L 11/01/24 08:39 11/04/24 17:01 1 Cobalt <1.0 1.0 0.40 ug/L 11/01/24 08:39 11/04/24 17:01 1 Copper <2.0 2.0 0.50 ug/L 11/01/24 08:39 11/04/24 17:01 1 Iron <100 100 47 ug/L 11/01/24 08:39 11/04/24 17:01 1 Lead <0.50 0.50 0.19 ug/L 11/01/24 08:39 11/04/24 17:01 1 Manganese <2.5 2.5 0.79 ug/L 11/01/24 08:39 11/04/24 17:01 1 Nickel <2.0 2.0 0.63 ug/L 11/01/24 08:39 11/04/24 17:01 1 Selenium <2.5 2.5 0.98 ug/L 11/01/24 08:39 11/04/24 17:01 1 Silver <0.50 0.50 0.12 ug/L 11/01/24 08:39 11/04/24 17:01 1 Thallium <2.0 2.0 0.57 ug/L 11/01/24 08:39 11/04/24 17:01 1 Eurofins Chicago Page 75 of 99 11/12/2024 QC Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Method: 6020B - Metals (ICP/MS) (Continued) Lab Sample ID: MB 500-793427/1-A Matrix: Water Analysis Batch: 793897 Analyte MB MB Result Qualifier Vanadium <5.0 Zinc <10 Lab Sample ID: LCS 500-793427/2-A Matrix: Water Analysis Batch: 793897 Spike Analyte Added Antimony 500 Arsenic 100 Barium 500 Beryllium 50.0 Cadmium 50.0 Calcium 10000 Chromium 200 Cobalt 500 Copper 250 Iron 1000 Lead 100 Manganese 500 Nickel 500 Selenium 100 Silver 50.0 Thallium 100 Vanadium 500 Zinc 500 Lab Sample ID: 500-258888-1 MS Matrix: Water Analysis Batch: 793897 Job ID: 500-258888-1 Client Sample ID: Method Blank Prep Type: Total Recoverable Prep Batch: 793427 RL MDL Unit D Prepared Analyzed Dil Fac 5.0 2.2 ug/L 11/01/24 08:39 11/04/24 17:01 1 10 6.9 ug/L 11/01/24 08:39 11/04/24 17:01 1 Client Sample ID: Lab Control Sample Prep Type: Total Recoverable Prep Batch: 793427 LCS LCS %Rec Result Qualifier Unit D %Rec Limits 536 ug/L — 107 80-120 105 ug/L 105 80-120 536 ug/L 107 80-120 52.8 ug/L 106 80 -120 m 52.3 ug/L 105 80 -120 8810 ug/L 88 80-120 213 ug/L 107 80-120 559 ug/L 112 80-120 263 ug/L 105 80-120 1100 ug/L 110 80-120 102 ug/L 102 80-120 536 ug/L 107 80-120 532 ug/L 106 80-120 109 ug/L 109 80-120 53.0 ug/L 106 80 -120 104 ug/L 104 80-120 532 ug/L 106 80-120 533 ug/L 107 80-120 Analyte Sample Result Sample Qualifier Spike Added MS Result MS Qualifier Unit Antimony <3.0 500 560 ug/L Arsenic 3.2 100 110 ug/L Barium 230 500 762 ug/L Beryllium <1.0 50.0 50.9 ug/L Cadmium <0.50 50.0 53.1 ug/L Calcium 81000 10000 89800 4 ug/L Chromium <5.0 200 207 ug/L Cobalt 16 500 552 ug/L Copper 1.1 J 250 269 ug/L Iron 4000 1000 4920 ug/L Lead <0.50 100 103 ug/L Manganese 2600 500 3070 4 ug/L Nickel 5.9 500 538 ug/L Selenium 1.1 J 100 108 ug/L Silver <0.50 50.0 52.6 ug/L Thallium <2.0 100 104 ug/L Vanadium <5.0 500 528 ug/L Client Sample ID: MW-11 R Prep Type: Total Recoverable Prep Batch: 793427 %Rec D %Rec Limits 112 75-125 107 75-125 106 75-125 102 75-125 106 75-125 83 75-125 104 75-125 107 75-125 107 75-125 95 75-125 103 75-125 89 75-125 106 75-125 107 75-125 105 75-125 104 75-125 106 75-125 Eurofins Chicago Page 76 of 99 11/12/2024 QC Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Method: 6020B - Metals (ICP/MS) (Continued) Lab Sample ID: 500-258888-1 MS Matrix: Water Analysis Batch: 793897 Sample Sample Analyte Result Qualifier Zinc <10 Lab Sample ID: 500-258888-1 MSD Matrix: Water Analysis Batch: 793897 Sample Sample Analyte Result Qualifier Antimony <3.0 Arsenic 3.2 Barium 230 Beryllium <1.0 Cadmium <0.50 Calcium 81000 Chromium <5.0 Cobalt 16 Copper 1.1 J Iron 4000 Lead <0.50 Manganese 2600 Nickel 5.9 Selenium 1.1 J Silver <0.50 Thallium <2.0 Vanadium <5.0 Zinc <10 Lab Sample ID: 500-258888-1 DU Matrix: Water Analysis Batch: 793897 Analyte Sample Result Sample Qualifier Antimony <3.0 Arsenic 3.2 Barium 230 Beryllium <1.0 Cadmium <0.50 Calcium 81000 Chromium <5.0 Cobalt 16 Copper 1.1 J Iron 4000 Lead <0.50 Manganese 2600 Nickel 5.9 Selenium 1.1 J Silver <0.50 Thallium <2.0 Vanadium <5.0 Zinc <10 Spike Added 500 Spike Added 500 100 500 50.0 50.0 10000 200 500 250 1000 100 500 500 100 50.0 100 500 500 Job ID: 500-258888-1 Client Sample ID: MW-11 R Prep Type: Total Recoverable Prep Batch: 793427 MS MS %Rec Result Qualifier Unit D %Rec Limits 544 ug/L 109 75-125 MSD MSD Result Qualifier Unit 540 ug/L 107 ug/L 745 ug/L 49.0 ug/L 51.2 ug/L 89300 4 ug/L 199 ug/L 539 ug/L 262 ug/L 4880 ug/L 99.6 ug/L 3060 4 ug/L 508 ug/L 106 ug/L 50.9 ug/L 99.3 ug/L 511 ug/L 527 ug/L DU DU Result Qualifier Unit <3.0 ug/L 3.13 ug/L 230 ug/L <1.0 ug/L <0.50 ug/L 80800 ug/L <5.0 ug/L 16.1 ug/L 1.15 J ug/L 3930 ug/L <0.50 ug/L 2590 ug/L 5.78 ug/L 1.19 J ug/L <0.50 ug/L <2.0 ug/L <5.0 ug/L <10 ug/L Client Sample ID: MW-11 R Prep Type: Total Recoverable Prep Batch: 793427 %Rec RPD D %Rec Limits RPD Limit 108 75-125 4 20 104 75-125 2 20 102 75-125 2 20 98 75-125 4 20 102 75-125 4 20 78 75-125 1 20 100 75-125 4 20 104 75-125 2 20 104 75-125 3 20 91 75-125 1 20 100 75-125 3 20 86 75-125 1 20 100 75-125 6 20 105 75-125 2 20 102 75-125 3 20 99 75-125 5 20 102 75-125 3 20 105 75-125 3 20 Client Sample ID: MW-11 R Prep Type: Total Recoverable Prep Batch: 793427 RPD D RPD Limit NC 20 2 20 1 20 NC 20 NC 20 0.8 20 NC 20 0.7 20 4 20 1 20 NC 20 2 20 1 20 10 20 NC 20 NC 20 NC 20 NC 20 Page 77 of 99 Eurofins Chicago 11 /12/2024 QC Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Method: 7470A - Mercury (CVAA) Lab Sample ID: MB 500-793293/12-A Matrix: Water Analysis Batch: 793508 Analyte Mercury MB MB Result Qualifier <0.20 Lab Sample ID: LCS 500-793293/13-A Matrix: Water Analysis Batch: 793508 Analyte Mercury Lab Sample ID: 500-258888-8 MS Matrix: Water Analysis Batch: 793508 Sample Sample Analyte Result Qualifier Mercury <0.20 Lab Sample ID: 500-258888-8 MSD Matrix: Water Analysis Batch: 793508 Sample Sample Analyte Result Qualifier Mercury <0.20 FLab Sample ID: 500-258888-8 DU Matrix: Water Analysis Batch: 793508 Sample Sample Analyte Result Qualifier Mercury <0.20 Job ID: 500-258888-1 Client Sample ID: Method Blank Prep Type: Total/NA Prep Batch: 793293 RL MDL Unit D Prepared Analyzed Dil Fac 0.20 0.076 ug/L 10/31/24 10:20 11/01/24 07:51 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Prep Batch: 793293 Spike LCS LCS %Rec Added Result Qualifier Unit D %Rec Limits 2.00 2.01 ug/L 101 80 -120 Client Sample ID: MW-7 Prep Type: Total/NA Prep Batch: 793293 Spike MS MS %Rec Added Result Qualifier Unit D %Rec Limits 0.999 0.929 ug/L 93 75 -125 Client Sample ID: MW-7 Prep Type: Total/NA Prep Batch: 793293 Spike MSD MSD %Rec RPD Added Result Qualifier Unit D %Rec Limits RPD Limit L- 0.999 0.901 ug/L 90 75 -125 3 20 Client Sample ID: MW-7 Prep Type: Total/NA Prep Batch: 793293 DU DU RPD Result Qualifier Unit D RPD Limit <0.20 ug/L NC 20 Method: 9056A - Anions, Ion Chromatography Lab Sample ID: MB 500-793982/3 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 793982 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chloride <1000 1000 120 ug/L 11/06/24 09:15 1 Sulfate <1000 1000 210 ug/L 11/06/24 09:15 1 Lab Sample ID: LCS 500-793982/4 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 793982 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Chloride 20000 18800 ug/L 94 80-120 Sulfate 20000 21400 ug/L 107 80-120 Page 78 of 99 Eurofins Chicago 11 /12/2024 QC Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Method: 9056A - Anions, Ion Chromatography (Continued) Lab Sample ID: MB 500-794184/3 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 794184 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chloride <1000 1000 120 ug/L 11/08/24 22:46 1 Sulfate <1000 1000 210 ug/L 11/08/24 22:46 1 Lab Sample ID: LCS 500-794184/4 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA E: Analysis Batch: 794184 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Chloride 20000 18800 ug/L 94 80 -120 Sulfate 20000 21300 ug/L 106 80 -120 Lab Sample ID: MB 500-794207/3 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 794207 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chloride <1000 1000 120 ug/L 11/07/2414:57 1 Sulfate <1000 1000 210 ug/L 11/07/2414:57 1 Lab Sample ID: LCS 500-794207/4 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 794207 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Chloride 20000 18800 ug/L 94 80 -120 Sulfate 20000 21000 ug/L 105 80 -120 Lab Sample ID: MB 500-794364/3 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 794364 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chloride <1000 1000 120 ug/L 11/09/24 07:37 1 Sulfate <1000 1000 210 ug/L 11/09/24 07:37 1 Lab Sample ID: LCS 500-794364/4 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 794364 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Chloride 20000 18800 ug/L 94 80 -120 Sulfate 20000 21200 ug/L 106 80 -120 Lab Sample ID: MB 500-794677/3 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 794677 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Sulfate <1000 1000 210 ug/L 11/10/2414:37 1 Eurofins Chicago Page 79 of 99 11/12/2024 QC Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Method: 9056A - Anions, Ion Chromatography (Continued) Lab Sample ID: LCS 500-794677/4 Matrix: Water Analysis Batch: 794677 F Job ID: 500-258888-1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS %Rec C Analyte Added Result Qualifier Unit D %Rec Limits Sulfate 20000 20300 ug/L 102 80 - 120 Lab Sample ID: MB 500-794781/3 Matrix: Water Analysis Batch: 794781 MB MB Analyte Result Qualifier RL MDL Unit Chloride <1000 1000 120 ug/L Lab Sample ID: LCS 500-794781/4 Matrix: Water Analysis Batch: 794781 Client Sample ID: Method Blank Prep Type: Total/NA F D Prepared Analyzed Dil Fac 11/11/2411:10 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Im Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Chloride 20000 19500 ug/L 98 80-120 Method: SM 2320B - Alkalinity Lab Sample ID: MB 500-793438/53 Matrix: Water Analysis Batch: 793438 MB MB Analyte Result Qualifier Alkalinity <5000 Lab Sample ID: LCS 500-793438/54 Matrix: Water Analysis Batch: 793438 Spike Analyte Added Alkalinity 100000 Lab Sample ID: 500-258888-2 DU Matrix: Water Analysis Batch: 793438 Sample Sample Analyte Result Qualifier Alkalinity 250000 Lab Sample ID: MB 500-793688/3 Matrix: Water Analysis Batch: 793688 MB MB Analyte Result Qualifier Alkalinity <5000 Client Sample ID: Method Blank Prep Type: Total/NA RL MDL Unit D Prepared Analyzed Dil Fac 5000 3700 ug/L 10/31/24 21:31 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA RL 5000 LCS LCS %Rec Result Qualifier Unit D %Rec Limits 99200 ug/L 99 95-121 Client Sample ID: MW-0 Prep Type: Total/NA DU DU RPD Result Qualifier Unit D RPD Limit 251000 ug/L 1 20 Client Sample ID: Method Blank Prep Type: Total/NA MDL Unit D Prepared Analyzed Dil Fac 3700 ug/L 11/01/24 11:42 1 Eurofins Chicago Page 80 of 99 11/12/2024 QC Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Method: SM 2320B - Alkalinity (Continued) Lab Sample ID: LCS 500-793688/4 Matrix: Water Analysis Batch: 793688 Analyte Alkalinity F Job ID: 500-258888-1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS %Rec L Added Result Qualifier Unit D %Rec Limits 100000 98900 ug/L 99 95-121 Method: SM 2540C - Solids, Total Dissolved (TDS) Lab Sample ID: MB 500-792634/1 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 792634 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Total Dissolved Solids <10000 10000 4300 ug/L 10/28/24 10:25 1 Lab Sample ID: LCS 500-792634/2 Client Sample ID: Lab Control Sample m Matrix: Water Prep Type: Total/NA Analysis Batch: 792634 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Total Dissolved Solids 250000 254000 ug/L 102 80 -120 FLab Sample ID: 500-258888-7 DU Client Sample ID: MW-6 Matrix: Water Prep Type: Total/NA Analysis Batch: 792634 Sample Sample DU DU RPD Analyte Result Qualifier Result Qualifier Unit D RPD Limit Total Dissolved Solids 210000 202000 ug/L 2 5 Lab Sample ID: MB 500-792683/1 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 792683 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Total Dissolved Solids <10000 10000 4300 ug/L 10/28/24 13:41 1 Lab Sample ID: LCS 500-792683/2 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 792683 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Total Dissolved Solids 250000 262000 ug/L 105 80 -120 Lab Sample ID: 500-258888-8 MS Client Sample ID: MW-7 Matrix: Water Prep Type: Total/NA Analysis Batch: 792683 Sample Sample Spike MS MS %Rec Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits Total Dissolved Solids 360000 250000 632000 ug/L 110 75 -125 Page 81 of 99 Eurofins Chicago 11 /12/2024 QC Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Method: SM 2540C - Solids, Total Dissolved (TDS) (Continued) Job ID: 500-258888-1 Lab Sample ID: 500-258888-8 DU Client Sample ID: MW-7 Matrix: Water Prep Type: Total/NA Analysis Batch: 792683 Sample Sample DU DU RPD Analyte Result Qualifier Result Qualifier Unit D RPD Limit Total Dissolved Solids 360000 364000 ug/L 2 5 FLab Sample ID: 500-258888-12 DU Client Sample ID: MW-13R Matrix: Water Prep Type: Total/NA Analysis Batch: 792683 Sample Sample DU DU RPD Analyte Result Qualifier Result Qualifier Unit D RPD Limit Total Dissolved Solids 2400000 2790000 F3 ug/L 14 5 Eurofins Chicago Page 82 of 99 11/12/2024 Lab Chronicle Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-11 R Lab Sample ID: 500-258888-1 Date Collected: 10/21/24 11:25 Matrix: Water Date Received: 10/23/24 09:40 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 792556 MM EET CHI 10/28/24 10:43 Total/NA Analysis 8260D SIM 14D 1 568895 UJML ELLE 10/29/24 12:40 Total Recoverable Prep 3005A 793427 BDE EET CHI 11/01/24 08:39 - 11/01/24 14:39' Total Recoverable Analysis 6020B 1 793897 RN EET CHI 11/04/24 17:06 Total/NA Prep 7470A 793293 MJG EET CHI 10/31/24 10:20 - 10/31/24 12:20' Total/NA Analysis 7470A 1 793508 MJG EET CHI 11/01/24 07:55 Total/NA Analysis 9056A 5 794184 MM EET CHI 11/09/24 02:09 Total/NA Analysis SM 2320B 1 793438 SO EET CHI 10/31/24 21:55 Total/NA Analysis SM 2540C 1 792634 SO EET CHI 10/28/24 10:30 Client Sample ID: MW-0 Lab Sample ID: 500-258888-2 Date Collected: 10/21/24 12:35 Matrix: Water Date Received: 10/23/24 09:40 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 792556 MM EET CHI 10/28/24 11:08 Total/NA Analysis 8260D SIM 14D 1 568895 UJML ELLE 10/29/24 13:00 Total Recoverable Prep 3005A 793427 BDE EET CHI 11/01/24 08:39 - 11/01/24 14:39' Total Recoverable Analysis 6020B 1 793897 RN EET CHI 11/04/24 17:22 Total/NA Prep 7470A 793293 MJG EET CHI 10/31/24 10:20 - 10/31/24 12:20' Total/NA Analysis 7470A 1 793508 MJG EET CHI 11/01/24 07:57 Total/NA Analysis 9056A 50 794781 MM EET CHI 11/11/24 15:03 Total/NA Analysis 9056A 5 794184 MM EET CHI 11/09/24 02:25 Total/NA Analysis SM 2320B 1 793438 SO EET CHI 10/31/24 22:08 Total/NA Analysis SM 2540C 1 792634 SO EET CHI 10/28/24 10:33 Client Sample ID: MW-2 Lab Sample ID: 500-258888-3 Date Collected: 10/21/24 13:25 Matrix: Water Date Received: 10/23/24 09:40 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 792556 MM EET CHI 10/28/24 11:31 Total/NA Analysis 8260D SIM 14D 1 568895 UJML ELLE 10/29/24 14:41 Total Recoverable Prep 3005A 793427 BDE EET CHI 11/01/24 08:39 - 11/01/24 14:39' Total Recoverable Analysis 6020B 1 793897 RN EET CHI 11/04/24 17:24 Total/NA Prep 7470A 793293 MJG EET CHI 10/31/24 10:20 - 10/31/24 12:20' Total/NA Analysis 7470A 1 793508 MJG EET CHI 11/01/24 07:59 Total/NA Analysis 9056A 10 794781 MM EET CHI 11/11/24 15:19 Total/NA Analysis 9056A 5 794184 MM EET CHI 11/09/24 02:40 Total/NA Analysis SM 2320B 1 793438 SO EET CHI 10/31/24 22:27 Total/NA Analysis SM 2540C 1 792634 SO EET CHI 10/28/24 10:35 Eurofins Chicago Page 83 of 99 11/12/2024 Lab Chronicle Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill F Job ID: 500-258888-1 Client Sample ID: MW-3 Lab Sample ID: 500-258888-4 Date Collected: 10/21/24 14:25 Matrix: Water Date Received: 10/23/24 09:40 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 792556 MM EET CHI 10/28/24 11:56 Total/NA Analysis 8260D SIM 14D 1 568895 UJML ELLE 10/29/24 15:01 Total Recoverable Prep 3005A 793427 BDE EET CHI 11/01/24 08:39 - 11/01/24 14:39' Total Recoverable Analysis 6020B 1 793897 RN EET CHI 11/04/24 17:26 Total/NA Prep 7470A 793293 MJG EET CHI 10/31/24 10:20 - 10/31/24 12:20' Total/NA Analysis 7470A 1 793508 MJG EET CHI 11/01/24 08:01 Total/NA Analysis 9056A 10 794184 MM EET CHI 11/09/24 02:56 Total/NA Analysis SM 2320B 1 793438 SO EET CHI 10/31/24 22:38 Total/NA Analysis SM 2540C 1 792634 SO EET CHI 10/28/24 10:38 Client Sample ID: MW-4 Lab Sample ID: 500-258888-5 Date Collected: 10/21/24 15:20 Matrix: Water Date Received: 10/23/24 09:40 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 792556 MM EET CHI 10/28/24 12:21 Total/NA Analysis 8260D SIM 14D 1 567628 UKAD ELLE 10/25/24 02:31 Total Recoverable Prep 3005A 793427 BDE EET CHI 11/01/24 08:39 - 11/01/24 14:39' Total Recoverable Analysis 6020B 1 793897 RN EET CHI 11/04/24 17:29 Total/NA Prep 7470A 793293 MJG EET CHI 10/31/24 10:20 - 10/31/24 12:20' Total/NA Analysis 7470A 1 793508 MJG EET CHI 11/01/24 08:03 Total/NA Analysis 9056A 10 794184 MM EET CHI 11/09/24 03:12 Total/NA Analysis SM 2320B 1 793438 SO EET CHI 10/31/24 22:47 Total/NA Analysis SM 2540C 1 792634 SO EET CHI 10/28/24 10:41 Client Sample ID: MW-5 Lab Sample ID: 500-258888-6 Date Collected: 10/21/24 16:25 Matrix: Water Date Received: 10/23/24 09:40 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 792556 MM EET CHI 10/28/24 12:46 Total/NA Analysis 8260D SIM 14D 1 567628 UKAD ELLE 10/25/24 00:12 Total Recoverable Prep 3005A 793427 BDE EET CHI 11/01/24 08:39 - 11/01/24 14:39' Total Recoverable Analysis 6020B 1 793897 RN EET CHI 11/04/24 17:31 Total/NA Prep 7470A 793293 MJG EET CHI 10/31/24 10:20 - 10/31/24 12:20' Total/NA Analysis 7470A 1 793508 MJG EET CHI 11/01/24 08:10 Total/NA Analysis 9056A 5 794184 MM EET CHI 11/09/24 03:27 Total/NA Analysis SM 2320B 1 793438 SO EET CHI 10/31/24 22:56 Total/NA Analysis SM 2540C 1 792634 SO EET CHI 10/28/24 10:43 Page 84 of 99 Eurofins Chicago 11 /12/2024 Lab Chronicle Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill F Job ID: 500-258888-1 Client Sample ID: MW-6 Lab Sample ID: 500-258888-7 Date Collected: 10/21/24 17:00 Matrix: Water Date Received: 10/23/24 09:40 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 792556 MM EET CHI 10/28/24 13:10 Total/NA Analysis 8260D SIM 14D 1 567628 UKAD ELLE 10/25/24 02:51 Total Recoverable Prep 3005A 793427 BDE EET CHI 11/01/24 08:39 - 11/01/24 14:39' Total Recoverable Analysis 6020B 1 793897 RN EET CHI 11/04/24 17:33 Total/NA Prep 7470A 793293 MJG EET CHI 10/31/24 10:20 - 10/31/24 12:20' Total/NA Analysis 7470A 1 793508 MJG EET CHI 11/01/24 08:12 Total/NA Analysis 9056A 1 794207 MM EET CHI 11/07/24 17:02 Total/NA Analysis SM 2320B 1 793438 SO EET CHI 10/31/24 23:04 Total/NA Analysis SM 2540C 1 792634 SO EET CHI 10/28/24 10:46 Client Sample ID: MW-7 Lab Sample ID: 500-258888-8 Date Collected: 10/22/24 08:25 Matrix: Water Date Received: 10/23/24 09:40 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 792556 MM EET CHI 10/28/24 13:35 Total/NA Analysis 8260D SIM 14D 1 567628 UKAD ELLE 10/25/24 00:32 Total Recoverable Prep 3005A 793427 BDE EET CHI 11/01/24 08:39 - 11/01/24 14:39' Total Recoverable Analysis 6020B 1 793897 RN EET CHI 11/04/24 17:35 Total/NA Prep 7470A 793293 MJG EET CHI 10/31/24 10:20 - 10/31/24 12:20' Total/NA Analysis 7470A 1 793508 MJG EET CHI 11/01/24 08:14 Total/NA Analysis 9056A 5 794207 MM EET CHI 11/07/24 17:18 Total/NA Analysis SM 2320B 1 793688 SO EET CHI 11/01/24 13:57 Total/NA Analysis SM 2540C 1 792683 SO EET CHI 10/28/24 14:03 Client Sample ID: MW-8 Lab Sample ID: 500-258888-9 Date Collected: 10/22/24 09:25 Matrix: Water Date Received: 10/23/24 09:40 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 792556 MM EET CHI 10/28/24 14:00 Total/NA Analysis 8260D SIM 14D 1 568895 UJML ELLE 10/29/24 16:40 Total Recoverable Prep 3005A 793427 BDE EET CHI 11/01/24 08:39 - 11/01/24 14:39' Total Recoverable Analysis 6020B 1 793897 RN EET CHI 11/04/24 17:38 Total/NA Prep 7470A 793293 MJG EET CHI 10/31/24 10:20 - 10/31/24 12:20' Total/NA Analysis 7470A 1 793508 MJG EET CHI 11/01/24 08:23 Total/NA Analysis 9056A 5 794207 MM EET CHI 11/07/24 18:05 Total/NA Analysis SM 2320B 1 793688 SO EET CHI 11/01/24 14:05 Total/NA Analysis SM 2540C 1 792683 SO EET CHI 10/28/24 14:25 Page 85 of 99 Eurofins Chicago 11 /12/2024 Lab Chronicle Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-9 Lab Sample ID: 500-258888-10 Date Collected: 10/22/24 10:40 Matrix: Water Date Received: 10/23/24 09:40 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 792556 MM EET CHI 10/28/24 14:25 Total/NA Analysis 8260D SIM 14D 5 567628 UKAD ELLE 10/25/24 03:11 Total Recoverable Prep 3005A 793427 BDE EET CHI 11/01/24 08:39 - 11/01/24 14:39' Total Recoverable Analysis 6020B 1 793897 RN EET CHI 11/04/24 17:40 Total/NA Prep 7470A 793293 MJG EET CHI 10/31/24 10:20 - 10/31/24 12:20' Total/NA Analysis 7470A 1 793508 MJG EET CHI 11/01/24 08:25 Total/NA Analysis 9056A 20 794207 MM EET CHI 11/07/24 18:20 Total/NA Analysis SM 2320B 1 793688 SO EET CHI 11/01/24 14:15 Total/NA Analysis SM 2540C 1 792683 SO EET CHI 10/28/24 14:33 Client Sample ID: MW-12 Lab Sample ID: 500-258888-11 Date Collected: 10/22/24 11:35 Matrix: Water Date Received: 10/23/24 09:40 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 792556 MM EET CHI 10/28/24 14:50 Total/NA Analysis 8260D SIM 14D 1 568895 UJML ELLE 10/29/24 13:20 Total Recoverable Prep 3005A 793427 BDE EET CHI 11/01/24 08:39 - 11/01/24 14:39' Total Recoverable Analysis 6020B 1 793897 RN EET CHI 11/04/24 17:47 Total/NA Prep 7470A 793293 MJG EET CHI 10/31/24 10:20 - 10/31/24 12:20' Total/NA Analysis 7470A 1 793508 MJG EET CHI 11/01/24 08:27 Total/NA Analysis 9056A 10 794364 MM EET CHI 11/09/24 14:24 Total/NA Analysis SM 2320B 1 793688 SO EET CHI 11/01/24 14:26 Total/NA Analysis SM 2540C 1 792683 SO EET CHI 10/28/24 14:40 Client Sample ID: MW-13R Lab Sample ID: 500-258888-12 Date Collected: 10/22/24 12:35 Matrix: Water Date Received: 10/23/24 09:40 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 792556 MM EET CHI 10/28/24 15:15 Total/NA Analysis 8260D SIM 14D 1 568895 UJML ELLE 10/29/24 13:40 Total Recoverable Prep 3005A 793427 BDE EET CHI 11/01/24 08:39 - 11/01/24 14:39' Total Recoverable Analysis 6020B 1 793897 RN EET CHI 11/04/24 17:49 Total/NA Prep 7470A 793293 MJG EET CHI 10/31/24 10:20 - 10/31/24 12:20' Total/NA Analysis 7470A 1 793508 MJG EET CHI 11/01/24 08:29 Total/NA Analysis 9056A 1 794677 MM EET CHI 11/10/24 19:18 Total/NA Analysis 9056A 50 793982 MM EET CHI 11/06/24 16:01 Total/NA Analysis SM 2320B 1 793688 SO EET CHI 11/01/24 14:37 Total/NA Analysis SM 2540C 1 792683 SO EET CHI 10/28/24 14:48 Eurofins Chicago Page 86 of 99 11/12/2024 Lab Chronicle Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: MW-14 Lab Sample ID: 500-258888-13 Date Collected: 10/22/24 13:30 Matrix: Water Date Received: 10/23/24 09:40 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 792556 MM EET CHI 10/28/24 15:39 Total/NA Analysis 8260D SIM 14D 1 568895 UJML ELLE 10/29/24 14:00 Total Recoverable Prep 3005A 793427 BDE EET CHI 11/01/24 08:39 - 11/01/24 14:39' Total Recoverable Analysis 6020B 1 793897 RN EET CHI 11/04/24 17:51 Total/NA Prep 7470A 793293 MJG EET CHI 10/31/24 10:20 - 10/31/24 12:20' Total/NA Analysis 7470A 1 793508 MJG EET CHI 11/01/24 08:35 Total/NA Analysis 9056A 100 793982 MM EET CHI 11/06/24 16:17 Total/NA Analysis 9056A 1 794364 MM EET CHI 11/09/24 14:55 Total/NA Analysis SM 2320B 1 793688 SO EET CHI 11/01/24 14:47 Total/NA Analysis SM 2540C 1 792683 SO EET CHI 10/28/24 15:03 Client Sample ID: MW-1 Lab Sample ID: 500-258888-14 Date Collected: 10/22/24 14:30 Matrix: Water Date Received: 10/23/24 09:40 Batch Batch Dilution Batch Prepared C Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 792556 MM EET CHI 10/28/24 16:04 Total/NA Analysis 8260D SIM 14D 1 567628 UKAD ELLE 10/25/24 00:52 Total Recoverable Prep 3005A 793427 BDE EET CHI 11/01/24 08:39 - 11/01/24 14:39' Total Recoverable Analysis 6020B 1 793897 RN EET CHI 11/04/24 17:54 Total/NA Prep 7470A 793293 MJG EET CHI 10/31/24 10:20 - 10/31/24 12:20' Total/NA Analysis 7470A 1 793508 MJG EET CHI 11/01/24 08:37 Total/NA Analysis 9056A 100 793982 MM EET CHI 11/06/24 16:32 Total/NA Analysis 9056A 1 794364 MM EET CHI 11/09/24 15:11 Total/NA Analysis SM 2320B 1 793688 SO EET CHI 11/01/24 14:58 Total/NA Analysis SM 2540C 1 792683 SO EET CHI 10/28/24 15:10 Client Sample ID: Leachate Lab Sample ID: 500-258888-15 Date Collected: 10/22/24 15:45 Matrix: Water Date Received: 10/23/24 09:40 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 792556 MM EET CHI 10/28/24 16:29 Total/NA Analysis 8260D DL 10 792782 SW1 EET CHI 10/29/24 18:59 Total/NA Analysis 8260D SIM 14D 20 568895 UJML ELLE 10/29/24 17:00 Total Recoverable Prep 3005A 793427 BDE EET CHI 11/01/24 08:39 - 11/01/24 14:39' Total Recoverable Analysis 6020E 1 793897 RN EET CHI 11/04/24 17:56 Total/NA Prep 7470A 793293 MJG EET CHI 10/31/24 10:20 - 10/31/24 12:20' Total/NA Analysis 7470A 1 793508 MJG EET CHI 11/01/24 08:40 Total/NA Analysis 9056A 20 793982 MM EET CHI 11/06/24 16:48 Total/NA Analysis SM 2320B 1 793688 SO EET CHI 11/01/24 15:09 Total/NA Analysis SM 2540C 1 792683 SO EET CHI 10/28/24 15:17 Eurofins Chicago Page 87 of 99 11/12/2024 Lab Chronicle Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Client Sample ID: SW-2 Lab Sample ID: 500-258888-16 Date Collected: 10/22/24 15:10 Matrix: Water Date Received: 10/23/24 09:40 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 792556 MM EET CHI 10/28/24 16:54 Total/NA Analysis 8260D SIM 14D 1 567628 UKAD ELLE 10/25/24 01:12 Client Sample ID: SW-4 Lab Sample ID: 500-258888-17 Date Collected: 10/22/24 15:15 Matrix: Water Date Received: 10/23/24 09:40 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 792556 MM EET CHI 10/28/24 17:19 Total/NA Analysis 8260D SIM 14D 1 567628 UKAD ELLE 10/25/24 01:31 Client Sample ID: SW-1 Lab Sample ID: 500-258888-18 Date Collected: 10/22/24 15:20 Matrix: Water Date Received: 10/23/24 09:40 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 792556 MM EET CHI 10/28/24 17:43 Total/NA Analysis 8260D SIM 14D 1 567628 UKAD ELLE 10/25/24 01:51 Client Sample ID: SW-3R Lab Sample ID: 500-258888-19 Date Collected: 10/22/24 16:15 Matrix: Water Date Received: 10/23/24 09:40 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 792556 MM EET CHI 10/28/24 18:08 Total/NA Analysis 8260D SIM 14D 1 568895 UJML ELLE 10/29/24 14:22 Client Sample ID: DUP-1 Lab Sample ID: 500-258888-20 Date Collected: 10/22/24 00:00 Matrix: Water Date Received: 10/23/24 09:40 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 792556 MM EET CHI 10/28/24 18:33 Total/NA Analysis 8260D SIM 14D 1 568895 UJML ELLE 10/29/24 16:20 Client Sample ID: Trip Blank Lab Sample ID: 500-258888-21 Date Collected: 10/21/24 00:00 Matrix: Water Date Received: 10/23/24 09:40 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 792782 SW1 EET CHI 10/29/24 18:35 Total/NA Analysis 8260D SIM 14D 1 568895 UJML ELLE 10/29/24 11:21 ' This procedure uses a method stipulated length of time for the process. Both start and end times are displayed Eurofins Chicago Page 88 of 99 11/12/2024 Lab Chronicle Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Laboratory References: Job ID: 500-258888-1 EET CHI = Eurofins Chicago, 2417 Bond Street, University Park, IL 60484, TEL (708)534-5200 ELLE = Eurofins Lancaster Laboratories Environment Testing, LLC, 2425 New Holland Pike, Lancaster, PA 17601, TEL (717)656-2300 Eurofins Chicago Page 89 of 99 11/12/2024 Accreditation/Certification Summary C Client: Greenway Waste Solutions LLC Job ID: 500-258888-1 Project/Site: NC Apex Landfill Laboratory: Eurofins Chicago The accreditations/certifications listed below are applicable to this report. Authority Program Identification Number Expiration Date North Carolina (WW/SW) State 291 12-31-24 Laboratory: Eurofins Lancaster Laboratories Environment Testing, LLC The accreditations/certifications listed below are applicable to this report. Authority Program Identification Number Expiration Date North Carolina (WW/SW) State 521 12-31-25 Eurofins Chicago Page 90 of 99 11/12/2024 Eurofins Chicago 2417 Bond Street University Park, IL 60484 Phone 708-534-5200 Fax:708-534-5211 Chain of Custody Record ti-- eurofins Environment Testing Client Information Sampgl r &,,,->-,,+ ��@zz '.�',r Lab PM Kintz, Robin M Carrier Tracking Nu(s) COC No. 500-128733A7806 1 Client Contact. Brandt Kayseri Phone �j o S J yr 7G S E-Mall Robin Kintz@et eurofinsus com State of Or In Page Page 1 off' �wrk Company PWSID Jo w pZ Greenway Waste Solutions LLC Analysis Requested Address Due Dale Requested Preservation Codes: 19109 W Catawba Ave Suite 110 .. D HNO3N City- lt,• • •, Cornelius ; None A HCL TAT Requested (days) Zip' Stale NC, 28031 Compliance Project a A No PO #. Phone 914-844-7048(Tel) 500-258888 Coe GWSA o �„ + WO# Email ? o y Brandt@griffinbros coo o - Q us ) e o v a o Project Name Project #' NC Apex Landfill 50013281 < n r16c o Lo Other, Site SSOWN � u t q F *' Sample Matrix o a tQQ o Type (Wwv.l.r, p� N 1VI .4 O tlll Z Sample (C=comp, 9=eo{Id, o-,,,.r.ms, g o N M Sample Identification Sam le Date Time G= rab er=Ti•.e.,A=Air N m :9 t2 o o '' Special InstructionslNote: �,i tpp c17�1 cam' X IN IN , , GJ' �t't' 2 tv ( Poss' le Hazard Identification Sample Disposal (A fee may�/be aasssed if samples are retained longer than 1 month) Non -Hazard I--]Flammable� Skin Irritant Poison B Unknown Radiological = Return To Client " Dis osal By Lab Archive For Months Deliverable Requested I, II, III, IV, Other (specify) Special Instructions/QC Requirements Empty Kit Relinquished by Date Time Method of shipment: Relinquished by Date/Time, Company rr Received b . Date i Com y Relinquished by Dale tme Company Rece d by Dale ime Company Relinquished by DatelTime Company Received by Daleffime Company Custody Seals Intact. Custody Seal No Cooler Temperature(AC d er ar y Q A Yes A No ✓! r Ver 05"" Page 91 of 99 /12/2024 Eurofins Chicago 2417 Bond Street University Park, IL 60484 Phone 708-534-5200 Fax 708-534-5211 Chain of Custody Record tiff eurof ins Environment Testing Sam tar Lab PM Carrier Tracking No(s). CDC No Client Information e-We(ayt Kintz, Robin M 500-128733-47806 2 Client Contact. Brandt Kayser Phone. � y9 '�,w 7'"� �/' 7oq- rY E-Mall. Robin Kintz@et eurofnsus com Stale of Origin. Page Page 2 ort r�r� Company PWSID Job Greenway Waste Solutions LLC Analysis Requested Address Due Dale Requested Preservation Codes 19109 W Catawba Ave Suite 110 D HNO3 : N None A HCL City- TAT Requested (day Cornelius 777 Slate, Zip: Compliance Project. as A No NC, 28031 a = 1 Phone PON 914-844-7048(Tei) GWSA o Z = ; 0 + + Email WO H Brandt@grifrinbros com I Q ' Project Name Project N NC Apex Landfill 50013281 v A .� 12 o a Other Site SSOW#: # 0 c o N N U Sample Matrix (w o o `o o Type Sample (C=comp, a=soled, o w.a mn, ? ? Sam le Identification Sam le Date Time G=grab ET=Tlasue,A-Alr) U spacial Instructions/Note: 0 IN Cbc X1 X Ix 'X 13� t� - - P 3_) o ic' - IllSk1 Ur`!Ce.yc� Poss a Hazard identification Sample Disposal (A fee may(beassessed if samples are retained longer than 1 monfh) Non -Hazard =Flammable =Skin Irritant Poison B � Unknown 0 Radiotogical =Return To Client E] Disposal By Lab Archive For Months Deliverable Requested I, II, III, IV, Other (specify) Special Instructions/QC Requirements Empty Kit Relinquished by Date Time Method of Shipment: Retinqulshed by Days Ime / Company Received by D telri Co TU Relinquished by DatelT me Company ReceiveAYN DatefT me I Cot-Fparly Relinquished by Dalerrlme Company Received by Date/Time Company Custody Seals Intact Custody Seal No Cools r Temperature(s) °C and Other Remarks. A Yes A No Ver 05/06/20?1 / 12/2024 Page 92 of 99 BRANDT KAYSER ACTWGT: 20.00 LS MAN 12717 CALDWELL RD CAD: 0675905/CAFE3804 b CHARLOTTE. NC 28213 UNITED STATES US T© SHIPPING DEPT 2 — EUROFINS CHICAGO 2417 BOND ST s UNIVERSITY PARK IL 60484 FedEx TRKN 70517817 9431 o22t NX JOTA �. 1 v 500.255888 W mW FedEx Express 0 N 0 WED • 23 OCT 1010A PRIORITY OVERNIGHT 60484 IL -US ORD BRANDT KAYSER ACTWGT; 20.U0 LB MAN CAD: 0675905/CAFE3804 12717 CALDWELL RD CHARLOTTE, SATU To SHIPPING DEPT 2 ` EUROFINS CHICAGO 2417 BOND ST 0 UNIVERSITY PA IL 60484',. (7008j 634-5200 REFi 1 _ OEPT� RMk: III HII III — FedEx Express � l o FedEx a WEAK 3 23 OCT i ak 1 z2, 05f � 74/19429 � PR ORItY OVERt� f ° Xa m 6f ;Y NX JOTA IL -US 090 z I � Page 93 of 99 11 /12/2024 8RANOT KAYSER ACTWST% 20.00 LB nAM CAD: 0675905/CAFESS04 12717 CALDWELL RD CHARLOTTE, NC 28213 UNITED STATES US TO SHIPPING DEPT 2 EUROFINS CHICAGO 2417 BOND ST UNIVERSITY PARK IL 60484 HOB) 534-VID REN P07 DEPT RMA: III IIIIIII r FedEX LEI FedEx *ED .23 OCT 110:30A TRK# 70517817 9442 R,BtQRITY OVERNIGHT 0221 60484 NX JOTA tL.US ORE) Page 94 of 99 11 /12/2024 Eurofins Chicago 2417 Bond Street University Park, IL 60484 Phone.708-534-5200 Fax 708.534.5211 Chain of Custody Record N : i ;?= eurofins Environment Testing Sampler Lab PM- Carrier Tracking No(s) COC No. Client Information Sub Contract Lab NIA Kintz. Robin M NIA- _- _ 500 194288.1 Client Contact. Phone E-Me State of Origin. Page: Shipping/Receiving N/A Robin.Kintz@et.eurofinsus.com North Carolina Page 1 of 3 Company Accreddations Required (See note): Job # Eurofins Lancaster Laboratories Environm State - North Carolina (WWISW): State Program - North C . 500-258888-1 Address. Due Date Requested: Preservation Codes: 2425 New Holland Pike, 11/5/2024 Analysis Requested City: TAT Requested (days): Lancaster N/A State, Zip. PA, 17601 Phone: PO # 717-656-2300(Tel) N/A o 2 m Email WO # N/A N/A to = 4 C m c Project Name. Project INC Apex Landfill 50013281 m n E m g c u Other: Site: SSOW# NIA NIA `° V/ N o `p WA Sample Matrix m In xi E Type (w•..,.r, LL € nl z Sample (C=Comp, s•.one. o•w..,.r.11, u t 5 Sample Identification -Client ID Lab ID Sam le Date Time G= rab BT•Ti.....A•Alr ti as Special Instructions/Note: Preservation Code: MW-11R 500-258888-1 10/21/24 11.25 G Water X 31 MW-0 (500-258888-2) 10/21124 12'35 G Water X 3 Eastern MW-2 (500-258888-3) 10/2124 1 stern G Water X 3 MW-3 (500-258888-4) 1012124 a425n G Water X 3 1 MW 4 (500-258888-5) 10121/24 15:20 G Water X 3 a rn MW-5 (500-258888-6) 10/21/24 16:25n EasterMW-6 G Water X 3 (500-258888-7) 1021/24 17.00 G Water X 3 Eastern MW-7 (500-258888-8) 10/22/24 a825n G Water X 3 MW-8 (500-25BB88-9) 10/2224 1 0g.25 Eas ern G Water X 3 Note Since laboratory accreditations are subject to change, Eurofns Chicago places the ownership of method, analyte & accreditation compliance upon our subcontract laboratories. This sample shipment is forwarded under chain -of -custody. ❑ the laboratory does not currently maintain accreditation in the State of Origin listed above for analysis/testslmalnx being analyzed, the samples must be shipped back to the Eurofins Chicago laboratory or other instructions will be provided. Any changes to accreditation status should be brought to Eurofins Chicago attention immediately. If all requested accreditations are current to date, return the signed Chain of Custody attesting to said compliance to Eurofins Chicago Possible Hazard Identification Sample Disposal ( A fee may be assessed /f samples are retained longer than 1 month) Unconfirmed = Return To Client = Disposal By Lab Archive For Months Deliverable Requested: 1, 11, III, IV, Other (specify) Primary Deliverable Rank: 2 Special Instructions/QC Requirements' Empty Kit Relinquish d by Date: 1,Time Method of Shipment Relinquished by Q Dalerr Company by: DatefTime: ny00A4( Relinquished by Daterrime Company!]Received Recved by: Date/Time: Company Relinquished y' Daten-lme: CompanyReceived by /,(rs/'c., Daterriimme �/ Compar/��—' 6T- Cuslaieals Intact: Custody Seal No. Cooler Temperature(s) °C and Other R marks. Yel A No [14 .gyp ver. 10n012024 t9 Page 95 of 99 11/12/2024 Eurofins Chicago Ll 2417 Bond Street Chain of CustodyRecord ti:= eurofins University Park, IL 60484 Environment Testing o,....,... 7110 cq?1-5010 Fax 708_574-5211 Sampler Lab PM. Carrier Tracking No(s) - COC No: Client information Sub Contract Lab N/A _ Kintz, Robin M N/A 500-194288 2 Client Contact. Phone E-Mail State of Origin Page: Shipping/Receiving N/A Robin.Kintz@et eurofinsus com North Carolina Page 2 of 3 Company Accreditabons Required (See note) Job # Eurofins Lancaster Laboratories Environm State - North Carolina (WW/SW), State Program - North C . 500-258888-1 Atldress. Due Date Requested: Preservation Codes: 2425 New Holland Pike, 11/5/2024 Analysis Requested City TAT Requested (days): Lancaster N/A Stale, Zip: PA, 17601 Phone: PO # 717-656-2300(Tel) NIA o _ all WO #: NIA N/A m } = p .2 c Project Name Project #: NC Apex Landfill 50013281 E v c u `o Other: Sde SSOWtt N/A N/A y N O a N/A Sample Matrix f E Type (w.w..r. - _ u. € ur I o = Sample (C=comp, alloaa, d_.w.u, y t 3 Sample Identification -Client ID Lab ID Sam le Date Time G= rob er..h....-.0 ti a Special Instructions/Note: Preservation Code: MW-9 500-258888-10) 10/22/24 10 40 G Water X 3 MW-12 (500-258888-11) 10/22/24 Eastern G Water X 3 MW-13R (500-258888-12) 10/22/24 12:35n EasterMW-14 G Water X 3 (500-258888.13) 10/22/24 13:30 Eastern G Water X 3 MW-1 (500-258888-14) 10/22/24 14 3 m G Water X 3 Leachate (500-258886-15) 10/22/24 15 45n Easter G Water X 3 SW-2 (500-258888-16) 10122/24 15.10n G Water X 3 SW-4 (500-258888-17) 10/22/24 1a5:15 stern G Water X 3 SW-1 (500-258888-18) 10l22124 15:20 as ern G Water X 3 Note: Since laboratory accreditation are subject to change, Eurofins Chicago places the ownership of method, analytic 8 accreditation compliance upon our subcontract laboratories. This sample shipment is forwarded under chain -of -custody. If the laboratory does not currently maintain accreditation in the State of Origin listed above for analysisllastsfmatrix being analyzed, the samples must be shipped back to the Eurofins Chicago laboratory or other instructions will be provided. Any changes to accreditation status should be brought to Eurofins Chicago attention immediately. If all requested accreditations are current to date, return the signed Chain of Custody attesting to said compliance to Eurofins Chicago. Possible Hazard Identification Sample Disposal (A fee may be assessed If samples are retained longer than 1 month) Unconfirmed I1 Return To Clienf = Disposal By Lab Archive For _ Months I Deliverable Requested: I, II, III, IV, Other (specify) Primary Deliverable Rank. 2 Special Instructions/QC Requirements. Empty Kit Relinquished by: Dale Time Method of shipment Relinquished by ` -MMRelinquished Dalerrime: , Company Received by. Dalerl-ime Company by Daterrimil. f Uompany Received by Company Datarfime: Relingm Company Received by. DataAime/� Z� `_ -� C (�Ct Compa� Custodeals Intact: Custody Seal No Cooler Tempe ature(s) °C and Other Remarks [14 -A Page 96 of 99 11/12/2024 Eurofins Chicago 2417 Bond Street University Park, IL 60484 Phone 708.534-5200 Fax 708-534-5211 Chain of Custody Record eurofins Environment Testing Client- Information Sub Contract Lab)- — Sampler NIA Lab PM. Kintz, Robin M _ _ Carrier Tracking Nots1 NIA COG No 500-194288 3 Client Contact Shipping/Receiving Phone NIA E-Mail Robin Kintz@et eurofinsus com State of Origin' North Carolina Page Page 3 of 3 Company' Eurofins Lancaster Laboratories Environm Accred,ta;ons Required (See note) State - North Carolina (WWISW): State Program - North C Job a 5DO-258888-1 Address 2425 New Holland Pike, Due Data Requested: 11/512024 Analysis Requested Preservation Codes: City Lancaster TAT Requested (days): N/A o Z m i �•, `o m d E > N y f m in ff €31 M d • a V + c o n $ C c c u `o 2 $ Other: 1 Slate, 7 p PA, 17601 Phone 717-656-2300(Tel) PO is N/A Email NIA woo N/A Project Name NC Apex Landfill Project a 50013281 Site N/A SSOWa N/A Sample Identification - Client ID Lab ID Sam le Date Sample Time Sample Type (C=comp, G= rab)eT•Tb�u�,A•Av Matrix (W—". o. ' Special Instructions/Note: Preservation Code: SW-3R 500-258888-19) DUP-1 (500-258888-20) 10122/24 16:er G Water X 3 10122/24 Eastern G Water X 3 Trip Blank (500-258888-21) 10/21/24 Eastern G Water X 2 Note: Since laboratory accreditation are subject to change, Eurofins Chicago places the ownership of method, anslyte d accreditation compliance upon our subcontract laboratories. This sample shipment is forwarded under chain-cf-custody If the laboratory does not currently maintain accreditation in the Stale of Origin listed above for anslysisAestalmatrix being analyzed, the samples must be shipped back to the Eurofins Chicago laboratory brother Instructions will be provided. Any ranges to accreditation status should be brought to Eurofins Chicago attention immediately If all requested accreditation are current to date, return the signed Chain of Custody attesting to said compliance to Eurofins Chicago Possible Hazard Identification Unconfirmed Sample Disposal (A fee may be assessed if samples are retained longer than 1 month) 0 Retum To Client Cl Disposal By Lab Archive For Months Deliverable Requested I, II, III, IV, Other (specify) Primary Deliverable Rank: 2 Special Instructions/QC Requirements. Empty Kit Relinquished , Date: Time Method of Shipment Relinquished by D7�irfi 1-9 <TZA Company Received by jDaterTime. Relinquished by (Date me pany Received by. jDalerrime Company Relinquished Date/Time Company Received byDaterTi e Z S / oy Compan+ G Custo,00eals Intact Ye No Custody Seal No Co er Temperature(s) °C and Other Remarks —10•(0— C— /-1% Ver. 10i10/2024 Page 97 of 99 11/12/2024 Client: Greenway Waste Solutions LLC Login Number: 258888 List Number: 1 Creator: Scott, Sherri L Question Login Sample Receipt Checklist Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey True meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. False Sample Preservation Verified. True There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. N/A 0.9,3.2,1.2 Job Number: 500-258888-1 List Source: Eurofins Chicago Eurofins Chicago Page 98 of 99 11/12/2024 Login Sample Receipt Checklist Client: Greenway Waste Solutions LLC Job Number: 500-258888-1 Login Number: 258888 List Source: Eurofins Lancaster Laboratories Environment Testing, LLC List Number: 2 List Creation: 10/24/24 10:26 AM Creator: Ballard, Megan Question Answer Comment The cooler's custody seal is intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True C Cooler Temperature acceptable,where thermal pres is required(</=6C, not True frozen). Cooler Temperature is recorded. True WV:Container Temp acceptable,where thermal pres is required (</=6C, not N/A frozen). WV: Container Temperature is recorded. N/A COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True There are no discrepancies between the containers received and the COC. True Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True There is sufficient vol. for all requested analyses. True Is the Field Sampler's name present on COC? False Received project as a subcontract. Sample custody seals are intact. True VOA sample vials do not have headspace >6mm in diameter (none, if from N/A WV)? Eurofins Chicago Page 99 of 99 11/12/2024 %, eurofins Environment Testing I ANALYTICAL REPORT C PREPARED FOR Attn: Brandt Kayser Greenway Waste Solutions LLC 19109 W Catawba Ave C Suite 110 Cornelius, North Carolina 28031 I Generated 12/12/2024 4:29:18 PM JOB DESCRIPTION NC Apex Landfil JOB NUMBER 500-261190-1 This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written approval of the laboratory. All questions should be directed to the Eurofins Chicago Project Manager. k64�� � / Generated /� 12/12/2024 4:29:18 PM Authorized for release by Robin Kintz, Project Manager II Robin. Kintz(a).et.eurofinsus.com (708)534-5200 F Eurofins Chicago is a laboratory within Eurofins Environment Testing North Central, LLC, a company within Eurofins Environment Testing Group of Companies Page 2 of 22 12/12/2024 Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Table of Contents Laboratory Job ID: 500-261190-1 Cover Page .............................................. 1 Table of Contents ......................................... 3 Case Narrative ........................................... 4 L Detection Summary ........................................ 5 Method Summary ......................................... 6 Sample Summary ......................................... 7 Client Sample Results ...................................... 8 E: Definitions............................................... 10 QC Association ........................................... 11 F Surrogate Summary ....................................... 12 QC Sample Results ........................................ 13 Chronicle................................................ 17 Certification Summary ...................................... 18 Chain of Custody .......................................... 19 E: Receipt Checklists ......................................... 22 Eurofins Chicago Page 3 of 22 12/12/2024 Case Narrative Client: Greenway Waste Solutions LLC Job ID: 500-261190-1 Project: NC Apex Landfill Job ID: 500-261190-1 Eurofins Chicago Job Narrative 500-261190-1 Receipt The sample was received on 12/7/2024 9:50 AM. Unless otherwise noted below, the sample arrived in good condition, and where required, properly preserved and on ice. The temperature of the cooler at receipt was 3.70 C. GC/MS VOA Method 8260D: The RPD of the laboratory control sample (LCS) and laboratory control sample duplicate (LCSD) for analytical batch 500-798701 recovered outside control limits for the following analytes: 1,1-Dichloroethene and Vinyl acetate. Method 8260D: The continuing calibration verification (CCV) analyzed in batch 500-798701 was outside the method criteria for the following analyte(s): Vinyl acetate. A CCV standard at or below the reporting limit (RL) was analyzed with the affected samples and found to be acceptable. As indicated in the reference method, sample analysis may proceed; however, any detection for the affected analyte(s) is considered estimated. Method 8260D: The laboratory control sample (LCS) and / or laboratory control sample duplicate (LCSD) for analytical batch 500-798701 recovered outside control limits for the following analytes: Vinyl acetate. These analytes were biased high in the LCS and were not detected in the associated samples; therefore, the data have been reported. Method 8260D: The method blank for analytical batch 500-798701 contained lodomethane above the method detection limit. This target analyte concentration was less than the reporting limit (RL) in the method blank; therefore, re -extraction and/or re -analysis of samples was not performed. No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page. Page 4 of 22 Eurofins Chicago 12/12/2024 Detection Summary Client: Greenway Waste Solutions LLC Job ID: 500-261190-1 Project/Site: NC Apex Landfill Client Sample ID: MW-9 Lab Sample ID: 500-261190-1 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type Benzene 1.3 0.50 0.18 ug/L 1 8260D Total/NA ' Tetrahydrofuran 11 10 3.9 ug/L 1 8260D Total/NA Xylenes, Total 0.58 J 1.0 0.30 ug/L 1 8260D Total/NA This Detection Summary does not include radiochemical test results. Eurofins Chicago Page 5 of 22 12/12/2024 Method Summary Client: Greenway Waste Solutions LLC Job ID: 500-261190-1 Project/Site: NC Apex Landfill Method Method Description Protocol Laboratory 8260D Volatile Organic Compounds by GC/MS SW846 EET CHI 5030B Purge and Trap SW846 EET CHI Protocol References: SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. Laboratory References: EET CHI = Eurofins Chicago, 2417 Bond Street, University Park, IL 60484, TEL (708)534-5200 Eurofins Chicago Page 6 of 22 12/12/2024 Sample Summary Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Lab Sample ID Client Sample ID 500-261190-1 MW-9 Matrix Water Collected Received 12/05/24 14:10 12/07/24 09:50 Job ID: 500-261190-1 C 0 Page 7 of 22 Eurofins Chicago 12/12/20g4 Client Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Job ID: 500-261190-1 Client Sample ID: MW-9 Lab Sample ID: 500-261190-1 Date Collected: 12/05/24 14:10 Matrix: Water Date Received: 12/07/24 09:50 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL Acetone <10 10 Acrylonitrile <20 20 Benzene 1.3 0.50 Bromochloromethane <1.0 1.0 Bromodichloromethane <1.0 1.0 Bromoform <1.0 1.0 Bromomethane <3.0 3.0 2-Butanone (MEK) <5.0 5.0 Carbon disulfide <2.0 2.0 Carbon tetrachloride <1.0 1.0 Chlorobenzene <1.0 1.0 Chloroethane <5.0 5.0 Chloroform <2.0 2.0 Chloromethane <5.0 5.0 cis-1,2-Dichloroethene <1.0 1.0 cis-1,3-Dichloropropene <1.0 1.0 Dibromochloromethane <1.0 1.0 1,2-Dibromo-3-Chloropropane <5.0 5.0 1,2-Dibromoethane <1.0 1.0 Dibromomethane <1.0 1.0 1,2-Dichlorobenzene <1.0 1.0 1,4-Dichlorobenzene <1.0 1.0 1,1-Dichloroethane <1.0 1.0 1,2-Dichloroethane <1.0 1.0 1,1-Dichloroethene <1.0 *1 1.0 1,2-Dichloropropene <1.0 1.0 Ethylbenzene <0.50 0.50 2-Hexanone <5.0 5.0 lodomethane <3.0 3.0 Methylene Chloride <5.0 5.0 4-Methyl-2-pentanone (MIBK) <5.0 5.0 Styrene <1.0 1.0 1,1,1,2-Tetrachloroethane <1.0 1.0 1,1,2,2-Tetrachloroethane <1.0 1.0 Tetrachloroethene <1.0 1.0 Tetrahydrofuran 11 10 Toluene <0.50 0.50 trans- 1,4-Dichloro-2-butene <5.0 5.0 trans- 1,2-Dichloroethene <1.0 1.0 trans- 1,3-Dichloropropene <1.0 1.0 1,1,1-Trichloroethane <1.0 1.0 1,1,2-Trichloroethane <1.0 1.0 Trichloroethene <0.50 0.50 Trichlorofluoromethane <1.0 1.0 1,2,3-Trichloropropane <2.0 2.0 Vinyl acetate <2.0 `+ "1 2.0 Vinyl chloride <1.0 1.0 Xylenes, Total 0.58 J 1.0 MDL Unit D Prepared Analyzed Dil Fac 4.3 ug/L 12/10/2418:52 1 6.0 ug/L 12/10/2418:52 1 0.18 ug/L 12/10/2418:52 1 0.50 ug/L 12/10/2418:52 1 0.57 ug/L 12/10/2418:52 1 0.96 ug/L 12/10/2418:52 1 1.8 ug/L 12/10/2418:52 1 2.3 ug/L 12/10/2418:52 1 1.1 ug/L 12/10/2418:52 1 0.41 ug/L 12/10/2418:52 1 0.41 ug/L 12/10/2418:52 1 0.47 ug/L 12/10/2418:52 1 0.92 ug/L 12/10/2418:52 1 0.79 ug/L 12/10/2418:52 1 0.42 ug/L 12/10/2418:52 1 0.52 ug/L 12/10/2418:52 1 0.83 ug/L 12/10/2418:52 1 3.9 ug/L 12/10/2418:52 1 0.56 ug/L 12/10/2418:52 1 0.58 ug/L 12/10/2418:52 1 0.48 ug/L 12/10/2418:52 1 0.45 ug/L 12/10/2418:52 1 0.36 ug/L 12/10/2418:52 1 0.58 ug/L 12/10/2418:52 1 0.48 ug/L 12/10/2418:52 1 0.37 ug/L 12/10/2418:52 1 0.20 ug/L 12/10/2418:52 1 2.2 ug/L 12/10/2418:52 1 0.68 ug/L 12/10/2418:52 1 3.6 ug/L 12/10/2418:52 1 2.0 ug/L 12/10/2418:52 1 0.31 ug/L 12/10/2418:52 1 0.67 ug/L 12/10/2418:52 1 0.65 ug/L 12/10/2418:52 1 0.39 ug/L 12/10/2418:52 1 3.9 ug/L 12/10/2418:52 1 0.21 ug/L 12/10/2418:52 1 3.4 ug/L 12/10/2418:52 1 0.44 ug/L 12/10/2418:52 1 0.63 ug/L 12/10/2418:52 1 0.45 ug/L 12/10/2418:52 1 0.73 ug/L 12/10/2418:52 1 0.15 ug/L 12/10/2418:52 1 0.44 ug/L 12/10/2418:52 1 1.5 ug/L 12/10/2418:52 1 0.78 ug/L 12/10/2418:52 1 0.47 ug/L 12/10/2418:52 1 0.30 ug/L 12/10/2418:52 1 Eurofins Chicago Page 8 of 22 12/12/2024 Client Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-261190-1 Project/Site: NC Apex Landfill Client Sample ID: MW-9 Lab Sample ID: 500-261190-1 Date Collected: 12/05/24 14:10 Matrix: Water Date Received: 12/07/24 09:50 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 99 72 - 124 12110124 18:52 1 Dibromofluoromethane 104 75 - 120 12110124 18:52 1 1,2-Dichloroethane-d4 (Surr) 103 75- 126 12110124 18:52 1 Toluene-d8 (Surr) 99 75 - 120 12110124 18:52 1 F F Eurofins Chicago Page 9 of 22 12/12/2024 Definitions/Glossary Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Qualifiers GUMS VOA Qualifier *1 E J Job ID: 500-261190-1 Qualifier Description LCS and/or LCSD is outside acceptance limits, high biased. LCS/LCSD RPD exceeds control limits. L Result exceeded calibration range. Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value. Glossary Abbreviation These commonly used abbreviations may or may not be present in this report. Listed under the "Y column to designate that the result is reported on a dry weight basis %R Percent Recovery CFL Contains Free Liquid CFU Colony Forming Unit CNF Contains No Free Liquid DER Duplicate Error Ratio (normalized absolute difference) Dil Fac Dilution Factor DL Detection Limit (DoD/DOE) DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample DLC Decision Level Concentration (Radiochemistry) EDL Estimated Detection Limit (Dioxin) LOD Limit of Detection (DoD/DOE) LOQ Limit of Quantitation (DoD/DOE) MCL EPA recommended "Maximum Contaminant Level' MDA Minimum Detectable Activity (Radiochemistry) MDC Minimum Detectable Concentration (Radiochemistry) MDL Method Detection Limit ML Minimum Level (Dioxin) MPN Most Probable Number MQL Method Quantitation Limit NC Not Calculated ND Not Detected at the reporting limit (or MDL or EDL if shown) NEG Negative / Absent POS Positive / Present IDOL Practical Quantitation Limit PRES Presumptive QC Quality Control RER Relative Error Ratio (Radiochemistry) RL Reporting Limit or Requested Limit (Radiochemistry) RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) TNTC Too Numerous To Count 0 Eurofins Chicago Page 10 of 22 12/12/2024 QC Association Summary Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill GC/MS VOA Analysis Batch: 798701 Lab Sample ID Client Sample ID 500-261190-1 MW-9 MB 500-798701/6 Method Blank LCS 500-798701/3 Lab Control Sample LCSD 500-798701/4 Lab Control Sample Dup Job ID: 500-261190-1 Prep Type Matrix Method Prep Batch Total/NA Water 8260D Total/NA Water 8260D Total/NA Water 8260D Total/NA Water 8260D 0 Eurofins Chicago Page 11 of 22 12/12/2024 Surrogate Summary Client: Greenway Waste Solutions LLC Job ID: 500-261190-1 Project/Site: NC Apex Landfill Method: 8260D - Volatile Organic Compounds by GC/MS Matrix: Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) BFB DBFM DCA TOL Lab Sample ID Client Sample ID (72-124) (75-120) (75-126) (75-120) 500-261190-1 MW-9 99 104 103 99 LCS 500-798701/3 Lab Control Sample 102 102 102 98 LCSD 500-798701/4 Lab Control Sample Dup 101 102 100 99 MB 500-798701/6 Method Blank 99 104 103 98 Surrogate Legend BFB = 4-Bromofluorobenzene (Surr) DBFM = Dibromofluoromethane DCA= 1,2-Dichloroethane-d4 (Surr) TOL = Toluene-d8 (Surr) 1 m Eurofins Chicago Page 12 of 22 12/12/2024 QC Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-261190-1 Project/Site: NC Apex Landfill Method: 8260D - Volatile Organic Compounds by GUMS Lab Sample ID: MB 500-798701/6 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 798701 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Acetone <10 10 4.3 ug/L 12/10/24 12:44 1 Acrylonitrile <20 20 6.0 ug/L 12/10/24 12:44 1 Benzene <0.50 0.50 0.18 ug/L 12/10/24 12:44 1 Bromochloromethane <1.0 1.0 0.50 ug/L 12/10/24 12:44 1 Bromodichloromethane <1.0 1.0 0.57 ug/L 12/10/24 12:44 1 Bromoform <1.0 1.0 0.96 ug/L 12/10/24 12:44 1 Bromomethane <3.0 3.0 1.8 ug/L 12/10/24 12:44 1 2-Butanone (MEK) <5.0 5.0 2.3 ug/L 12/10/24 12:44 1 Carbon disulfide <2.0 2.0 1.1 ug/L 12/10/24 12:44 1 Carbon tetrachloride <1.0 1.0 0.41 ug/L 12/10/24 12:44 1 Chlorobenzene <1.0 1.0 0.41 ug/L 12/10/24 12:44 1 Chloroethane <5.0 5.0 0.47 ug/L 12/10/24 12:44 1 Chloroform <2.0 2.0 0.92 ug/L 12/10/24 12:44 1 Chloromethane <5.0 5.0 0.79 ug/L 12/10/24 12:44 1 cis-1,2-Dichloroethene <1.0 1.0 0.42 ug/L 12/10/24 12:44 1 cis-1,3-Dichloropropene <1.0 1.0 0.52 ug/L 12/10/24 12:44 1 Dibromochloromethane <1.0 1.0 0.83 ug/L 12/10/24 12:44 1 1,2-Dibromo-3-Chloropropane <5.0 5.0 3.9 ug/L 12/10/24 12:44 1 1,2-Dibromoethane <1.0 1.0 0.56 ug/L 12/10/24 12:44 1 Dibromomethane <1.0 1.0 0.58 ug/L 12/10/24 12:44 1 1,2-Dichlorobenzene <1.0 1.0 0.48 ug/L 12/10/24 12:44 1 1,4-Dichlorobenzene <1.0 1.0 0.45 ug/L 12/10/24 12:44 1 1,1-Dichloroethane <1.0 1.0 0.36 ug/L 12/10/24 12:44 1 1,2-Dichloroethane <1.0 1.0 0.58 ug/L 12/10/24 12:44 1 1,1-Dichloroethene <1.0 1.0 0.48 ug/L 12/10/24 12:44 1 1,2-Dichloropropane <1.0 1.0 0.37 ug/L 12/10/24 12:44 1 Ethylbenzene <0.50 0.50 0.20 ug/L 12/10/24 12:44 1 2-Hexanone <5.0 5.0 2.2 ug/L 12/10/24 12:44 1 lodomethane 0.807 J 3.0 0.68 ug/L 12/10/24 12:44 1 Methylene Chloride <5.0 5.0 3.6 ug/L 12/10/24 12:44 1 4-Methyl-2-pentanone (MIBK) <5.0 5.0 2.0 ug/L 12/10/24 12:44 1 Styrene <1.0 1.0 0.31 ug/L 12/10/24 12:44 1 1,1,1,2-Tetrachloroethane <1.0 1.0 0.67 ug/L 12/10/24 12:44 1 1,1,2,2-Tetrachloroethane <1.0 1.0 0.65 ug/L 12/10/24 12:44 1 Tetrachloroethene <1.0 1.0 0.39 ug/L 12/10/24 12:44 1 Tetrahydrofuran <10 10 3.9 ug/L 12/10/24 12:44 1 Toluene <0.50 0.50 0.21 ug/L 12/10/24 12:44 1 trans- 1,4-Dichloro-2-butene <5.0 5.0 3.4 ug/L 12/10/24 12:44 1 trans- 1,2-Dichloroethene <1.0 1.0 0.44 ug/L 12/10/24 12:44 1 trans- 1,3-Dichloropropene <1.0 1.0 0.63 ug/L 12/10/24 12:44 1 1,1,1-Trichloroethane <1.0 1.0 0.45 ug/L 12/10/24 12:44 1 1,1,2-Trichloroethane <1.0 1.0 0.73 ug/L 12/10/24 12:44 1 Trichloroethene <0.50 0.50 0.15 ug/L 12/10/24 12:44 1 Trichlorofluoromethane <1.0 1.0 0.44 ug/L 12/10/24 12:44 1 1,2,3-Trichloropropane <2.0 2.0 1.5 ug/L 12/10/24 12:44 1 Vinyl acetate <2.0 2.0 0.78 ug/L 12/10/24 12:44 1 Vinyl chloride <1.0 1.0 0.47 ug/L 12/10/24 12:44 1 Xylenes, Total <1.0 1.0 0.30 ug/L 12/10/24 12:44 1 Eurofins Chicago Page 13 of 22 12/12/2024 QC Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-261190-1 Project/Site: NC Apex Landfill Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: MB 500-798701/6 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 798701 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 99 72 - 124 12110124 12:44 1 Dibromofluoromethane 104 75 - 120 12110124 12:44 1 1,2-Dichloroethane-d4 (Surr) 103 75- 126 12110124 12:44 1 Toluene-d8 (Surr) 98 75 - 120 12110124 12:44 1 Lab Sample ID: LCS 500-798701/3 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 798701 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Acetone 50.0 44.8 ug/L 90 40 -143 Acrylonitrile 500 537 ug/L 107 67 -140 m Benzene 50.0 43.9 ug/L 88 70-120 Bromochloromethane 50.0 48.8 ug/L 98 65 -122 Bromodichloromethane 50.0 48.1 ug/L 96 69 -120 Bromoform 50.0 53.2 ug/L 106 56 -132 Bromomethane 50.0 39.2 ug/L 78 40 -152 2-Butanone (MEK) 50.0 53.5 ug/L 107 46 -144 Carbon disulfide 50.0 45.1 ug/L 90 66 -120 Carbon tetrachloride 50.0 47.8 ug/L 96 59 -133 Chlorobenzene 50.0 46.3 ug/L 93 70 -120 Chloroethane 50.0 49.1 ug/L 98 48 -136 Chloroform 50.0 46.0 ug/L 92 70 -120 Chloromethane 50.0 43.6 ug/L 87 56 -152 cis-1,2-Dichloroethene 50.0 46.9 ug/L 94 70 -125 cis-1,3-Dichloropropene 50.0 48.2 ug/L 96 64 -127 Dibromochloromethane 50.0 51.2 ug/L 102 68 -125 1,2-Dibromo-3-Chloropropane 50.0 53.8 ug/L 108 56-123 1,2-Dibromoethane 50.0 50.8 ug/L 102 70-125 Dibromomethane 50.0 49.8 ug/L 100 70 -120 1,2-Dichlorobenzene 50.0 46.4 ug/L 93 70 -125 1,4-Dichlorobenzene 50.0 46.5 ug/L 93 70 -120 1,1-Dichloroethane 50.0 47.0 ug/L 94 70-125 1,2-Dichloroethane 50.0 46.9 ug/L 94 68 -127 1,1-Dichloroethene 50.0 45.5 ug/L 91 67-122 1,2-Dichloropropane 50.0 46.9 ug/L 94 67 -130 Ethylbenzene 50.0 43.3 ug/L 87 70 -123 2-Hexanone 50.0 52.8 ug/L 106 54 -146 lodomethane 50.0 46.7 ug/L 93 61 -136 Methylene Chloride 50.0 44.3 ug/L 89 69 -125 4-Methyl-2-pentanone (MIBK) 50.0 51.4 ug/L 103 55-139 Styrene 50.0 47.9 ug/L 96 70 -120 1,1,1,2-Tetrachloroethane 50.0 49.1 ug/L 98 70-125 1,1,2,2-Tetrachloroethane 50.0 57.8 ug/L 116 62-140 Tetrachloroethene 50.0 44.0 ug/L 88 70 -128 Tetrahydrofuran 100 101 ug/L 101 59 -139 Toluene 50.0 43.1 ug/L 86 70 -125 trans- 1,4-Dichloro-2-butene 50.0 55.7 ug/L 111 60-130 Eurofins Chicago Page 14 of 22 12/12/2024 QC Sample Results Client: Greenway Waste Solutions LLC Job ID: 500-261190-1 Project/Site: NC Apex Landfill Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCS 500-798701/3 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 798701 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits trans- 1,2-Dichloroethene 50.0 45.6 ug/L 91 70-125 trans- 1,3-Dichloropropene 50.0 49.5 ug/L 99 62 -128 1,1,1-Trichloroethane 50.0 47.0 ug/L 94 70-125 1,1,2-Trichloroethane 50.0 48.5 ug/L 97 71-130 Trichloroethene 50.0 42.7 ug/L 85 70 -125 Trichlorofluoromethane 50.0 49.3 ug/L 99 55 -128 1,2,3-Trichloropropane 50.0 52.6 ug/L 105 50-133 Vinyl acetate 50.0 197 .+ ug/L 395 43 -133 Vinyl chloride 50.0 44.0 ug/L 88 64 -126 Xylenes, Total 100 84.2 ug/L 84 70 -125 LCS LCS m Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 102 72 - 124 Dibromofluoromethane 102 75 - 120 1,2-Dichloroethane-d4 (Surr) 102 75- 126 Toluene-d8 (Surr) 98 75 - 120 Lab Sample ID: LCSD 500-798701/4 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 798701 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit Acetone 50.0 50.7 ug/L 101 40 -143 13 20 Acrylonitrile 500 606 ug/L 121 67 -140 12 20 Benzene 50.0 51.1 ug/L 102 70 -120 15 20 Bromochloromethane 50.0 55.1 ug/L 110 65 -122 12 20 Bromodichloromethane 50.0 54.8 ug/L 110 69 -120 13 20 Bromoform 50.0 59.7 ug/L 119 56 -132 12 20 Bromomethane 50.0 45.4 ug/L 91 40 -152 15 20 2-Butanone (MEK) 50.0 57.3 ug/L 115 46 -144 7 20 Carbon disulfide 50.0 54.7 ug/L 109 66 -120 19 20 Carbon tetrachloride 50.0 58.5 ug/L 117 59 -133 20 20 Chlorobenzene 50.0 53.5 ug/L 107 70 -120 14 20 Chloroethane 50.0 52.8 ug/L 106 48 -136 7 20 Chloroform 50.0 52.9 ug/L 106 70 -120 14 20 Chloromethane 50.0 45.8 ug/L 92 56 -152 5 20 cis-1,2-Dichloroethene 50.0 53.8 ug/L 108 70 -125 14 20 cis-1,3-Dichloropropene 50.0 55.4 ug/L 111 64 -127 14 20 Dibromochloromethane 50.0 58.3 ug/L 117 68 -125 13 20 1,2-Dibromo-3-Chloropropane 50.0 59.8 ug/L 120 56-123 11 20 1,2-Dibromoethane 50.0 57.5 ug/L 115 70-125 12 20 Dibromomethane 50.0 56.8 ug/L 114 70 -120 13 20 1,2-Dichlorobenzene 50.0 53.1 ug/L 106 70 -125 13 20 1,4-Dichlorobenzene 50.0 52.7 ug/L 105 70 -120 12 20 1,1-Dichloroethane 50.0 54.8 ug/L 110 70-125 15 20 1,2-Dichloroethane 50.0 53.8 ug/L 108 68 -127 14 20 1,1-Dichloroethene 50.0 56.0 '1 ug/L 112 67-122 21 20 1,2-Dichloropropane 50.0 53.5 ug/L 107 67 -130 13 20 Eurofins Chicago Page 15 of 22 12/12/2024 QC Sample Results Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill Job ID: 500-261190-1 Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCSD 500-798701/4 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 798701 RPD Limit Analyte Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene trans- 1,4-Dichloro-2-butene trans- 1,2-Dichloroethene trans- 1,3-Dichloropropene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylenes, Total Surrogate 4-Bromofluorobenzene (Surr) Dibromofluoromethane 1,2-Dichloroethane-d4 (Surr) Toluene-d8 (Surr) Spike LCSD LCSD %Rec Added Result Qualifier Unit D %Rec Limits RPD 50.0 51.5 ug- / -L 103 70 -123 17 50.0 58.4 ug/L 117 54 -146 10 50.0 56.6 ug/L 113 61-136 19 50.0 50.5 ug/L 101 69 -125 13 50.0 57.2 ug/L 114 55 -139 11 50.0 54.8 ug/L 110 70 -120 13 50.0 56.2 ug/L 112 70 -125 13 50.0 64.9 ug/L 130 62-140 11 50.0 53.1 ug/L 106 70 -128 19 100 114 ug/L 114 59-139 12 50.0 49.9 ug/L 100 70 -125 15 50.0 63.2 ug/L 126 60 -130 13 50.0 54.4 ug/L 109 70 -125 18 50.0 55.8 ug/L 112 62 -128 12 50.0 56.8 ug/L 114 70 -125 19 50.0 54.8 ug/L 110 71-130 12 50.0 51.3 ug/L 103 70 -125 18 50.0 51.3 ug/L 103 55 -128 4 50.0 59.6 ug/L 119 50 -133 13 50.0 255 .+ E "1 ug/L 510 43 -133 25 50.0 46.2 ug/L 92 64 -126 5 100 98.5 ug/L 99 70 -125 16 LCSD LCSD %Recovery Qualifier Limits 101 72-124 102 75-120 100 75-126 99 75-120 20 20 20 20 20 F- 20 20 20 20 20 20 IM20 20 20 20 20 F 20 20 20 20 20 20 Eurofins Chicago Page 16 of 22 12/12/2024 Lab Chronicle Client: Greenway Waste Solutions LLC Project/Site: NC Apex Landfill F Job ID: 500-261190-1 Client Sample ID: MW-9 Lab Sample ID: 500-261190-1 Date Collected: 12/05/24 14:10 Matrix: Water Date Received: 12/07/24 09:50 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 798701 MM EET CHI 12/10/24 18:52 Laboratory References: EET CHI = Eurofins Chicago, 2417 Bond Street, University Park, IL 60484, TEL (708)534-5200 Page 17 of 22 Eurofins Chicago 12/12/2024 Accreditation/Certification Summary Client: Greenway Waste Solutions LLC Job ID: 500-261190-1 Project/Site: NC Apex Landfill Laboratory: Eurofins Chicago The accreditations/certifications listed below are applicable to this report. Authority Program Identification Number Expiration Date North Carolina (WW/SW) State 291 12-31-24 Eurofins Chicago Page 18 of 22 12/12/2024 Address Regulatory Program: ❑DW 1NPDES ❑RCRA ❑Other Environment Testing TestAmerica TAL•8210 Client Contact Project Manager , ( s Site Contact Date tLo COC No Company Name Gr Gcl't ;,v4 , Tel/Email ttz,tvG ' gw �J.fi1 ,XjrLab Contact Ak ' A;k Carrier �_ of � COCs Address [tl C., Cif let 3; o Analysis Tu naround Time } E rn ro LL } " 0 E a tL p Sampler City/State/Zip �' (iGIL' rGC. ; j R(. C NDAR DAYS ❑ WORKING DAYS For Lab Use Only: Walk in Client Lab Sampling Phone q1 t f - b y F TAT if different from Below z weeks ❑ I week ❑ 2 days ❑ I day Fax Project Name 6-v(y ! L.11. kt Site P O # k: 500-26119000C Sample Identificatioi,/Date Job / SDG No '- Sample Sample Time Sample Type =Co �mp, G=Grab) Matrix coot Sample Specific Notes � - ei�L � � i�-t(✓ � Cu 3 Pre erarafion Uses#;:_, t = tce, 2= HCl; 3= 1-12S94 '_ fj Q ° 5a=NaOH; 6= Other _ .. Possible Hazard Identification: Are any samples from a listed EPA Hazardous Waste? Please List any EPA Waste Codes for the sample in the Comments Section if the lab is to dispose of the sample Sample Disposal ( A fee may be assessed if samples are retained longer than 1 month) [f Return to Client Fc �y Lab r_ Archive for Months [l{erFHazard ❑ Flammable ❑ Skin Irritant ❑ Poison 6 L Unknown Special Instructions/QC Requirements & Comments: Custody Seals Intact ❑ Yes ❑ No Custody Seal No jCoolerTemp (C) Obs'd Corr'd Therm ID No Relinquished by Company ,P, 4 Date/Time I� wj"?, Received by Company Date/Time Relinquished b Company Date/Time Received by Company Date/Time Relinquished by Company Date/Time Received �boratory y Comp y. a-1 . . ... .... Djatte�im' �J � 14 Page 19 of 22 12/12/2024 ORIGIN iD PNVA (704) 392-'1 154 SHIP DATE CANDACE BONHAM ACTWGf 15 TESTAMERICA CAD 5096M. 283E-B QUEEN CITY DRIVE CHARLOTTE, NC 28208 BILL RECIPIENT UNITED STATES US -- TO SAMPLE REC. EUROFINS 24V BOND STREET .0 NIVERSITY PARK IL 60484 57081'. �34-5201 1� I')v PC, III IIIIIIIIlllllllilil'l l !I!I ICI I IIIIIi 11 11 lII I{ I li 11 llll l lil I I ill O M = 'q o 00 00 c Lu O H � fi R O) 00 (0 O cv) W Nr O mmmm) ti r� w Y N m L. i ' 500-261190 Waybi F Lu RT1 Fx Page 20 of 22 12/12/2024 Page 21 of 22 12/12/2024 Client: Greenway Waste Solutions LLC Login Number: 261190 List Number: 1 Creator: Scott, Sherri L Question Login Sample Receipt Checklist Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey True meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. True There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. N/A 3.7 Job Number: 500-261190-1 List Source: Eurofins Chicago Eurofins Chicago Page 22 of 22 12/12/2024