5002_JacksonCounty_MSWLF_CDLF_Oct23GW_FID1834043_20240412

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April 2024 ANCHOR
Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 INZ Q E A `'`'"
Fall 2023
Semiannual Water Quality Monitoring Report
Prepared for Jackson County Solid Waste Department

April 2024
Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02
Fall 2023
Semiannual Water Quality Monitoring Report
Prepared for
Jackson County Solid Waste Department
401 Grindstaff Cove Road
Sylva, North Carolina 28779
ason Volker, PE, LSS
Managing Engineer
Prepared by
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
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J MayerS�sica
ff Professional
Project Number: C01480-01.02
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Report_Fa I I_2023.docx

Table of Contents
Table of Contents
Abbreviations
1 Introduction
1
2 Semiannual Monitoring...........................................................................................................3
2.1 Groundwater, Surface Water, Domestic Well, and Leachate Sampling..........................................3
2.1.1 Monitoring Well Purging and Sampling Methods.................................................................3
2.1.2 Surface Water Sampling Methods................................................................................................4
2.1.3 Leachate Sampling Methods..........................................................................................................5
2.1.4 Domestic Well Sampling Methods...............................................................................................5
2.2 Sample Handling, Documentation, and Analysis....................................................................................5
2.2.1 Sampling Schedule.............................................................................................................................5
2.2.2 Fall 2023 Sampling..............................................................................................................................6
3 Findings........................................................................................................................................8
3.1
Groundwater.........................................................................................................................................................8
3.1.1 Field Parameters..................................................................................................................................9
3.1.2 Appendix II Metals (Total)................................................................................................................9
3.1.3 Appendix II VOCs and 1,4-Dioxane...........................................................................................
10
3.2
Surface Water....................................................................................................................................................
11
3.2.1 Field Parameters...............................................................................................................................
11
3.2.2 Appendix II Metals...........................................................................................................................
11
3.2.3 Appendix II VOCs and 1,4-Dioxane...........................................................................................
11
3.3
Leachate...............................................................................................................................................................11
3.4
Domestic Well....................................................................................................................................................
12
3.4.1 Field Parameters...............................................................................................................................
12
3.4.2 VOCs......................................................................................................................................................
12
3.5
Groundwater Flow Directions......................................................................................................................
12
4 Summary....................................................................................................................................14
4.1 Groundwater Quality...................................................................................................................................... 14
4.1.1 Appendix II Metals........................................................................................................................... 14
4.1.2 Appendix II Volatile Organic Compounds and 1,4-Dioxane............................................ 14
4.1.3 Field Parameters and Other Constituents............................................................................... 14
Fall 2023 Semiannual
Water Quality Monitoring Report i April 2024

4.2 Surface Water Quality..................................................................................................................................... 14
4.2.1 Appendix II Metals........................................................................................................................... 14
4.2.2 Appendix II Volatile Organic Compounds and 1,4-Dioxane............................................ 14
4.2.3 Field Parameters and Other Constituents............................................................................... 15
4.3 Leachate Quality............................................................................................................................................... 15
4.4 Domestic Well Water Quality...................................................................................................................... 15
5 Future Activities
6 References
TABLES
Table 1 Summary of Laboratory Analyses Performed on Samples
Table 2 Well Construction Details and Corresponding Elevations
Table 3 Analytical Summary
Table 4 Mass Removal Calculations for VOCs Detected in the Leachate Sample (LT-01)
FIGURES
Figure 1
Site Location Map
Figure 2
Site Layout Map
Figure 3
Generalized Groundwater Flow Direction
Figure 4
Hydrograph and Constituents of Concern Versus Time —
MW-01
Figure 5
Hydrograph and Constituents of Concern Versus Time —
MW-02
Figure 6
Hydrograph and Constituents of Concern Versus Time —
MW-03
Figure 7
Hydrograph and Constituents of Concern Versus Time —
MW-04
Figure 8
Hydrograph and Constituents of Concern Versus Time —
MW-05R
Figure 9
Hydrograph and Constituents of Concern Versus Time —
MW-06
Figure 10
Hydrograph and Constituents of Concern Versus Time —
MW-07
APPENDICES
Appendix A Well Sampling Logs, and Equipment Documentation and Instrument Calibration
Data Sheets
Appendix B Reports of Laboratory Analysis, Chain -of -Custody Documentation,
and Certificates of Analysis
16
17
Fall 2023 Semiannual
Water Quality Monitoring Report ii April 2024

Abbreviations
pg/L
micrograms per liter
pmhos/cm
micromhos per centimeter
2L standard
15A NCAC 2L.0202 Groundwater Standard
CAER
Five -Year Corrective Action Evaluation Report
CAP
Corrective Action Plan
DEQ
North Carolina Department of Environmental Quality
DO
dissolved oxygen
EPA
U.S. Environmental Protection Agency
IMAC
interim maximum allowable concentration
MDL
method detection limit
mg/L
milligrams per liter
MNA
monitored natural attenuation
mV
millivolts
NCAC
North Carolina Administrative Code
NTU
nephelometric turbidity unit
ORP
oxidation reduction potential
PWR
partially weathered rock
SC
specific conductivity
Site
closed Municipal Solid Waste Landfill
SM
Standard Method
SU
standard unit
SVOC
semivolatile organic compound
SWS
Solid Waste Section
TWSA
Tuckasegee Water & Sewer Authority
VOC
volatile organic compound
Fall 2023 Semiannual
Water Quality Monitoring Report iii April 2024

1 Introduction
The Jackson County Solid Waste Department maintains a closed Municipal Solid Waste Landfill (Site)
approximately 0.75 mile west of Dillsboro, North Carolina, on the northeast side of
Old Dillsboro Road (Old U.S. Highway 74; Figure 1). Water quality monitoring at the landfill is
governed by the North Carolina Department of Environmental Quality (DEQ), Division of Waste
Management, Solid Waste Section (SWS), under Permit No. 50-02 issued to Jackson County. The
landfill permit requires semiannual monitoring of groundwater and surface water quality.
Since October 2007, when Anchor QEA of North Carolina, PLLC began performing water quality
monitoring events at the Site, groundwater quality monitoring has indicated persistent low-level
concentrations of constituents that exceeded groundwater quality standards. In response to the
continued exceedances of the analyzed constituents, an Assessment of Corrective Measures was
submitted to the North Carolina Department of Environment and Natural Resources (now DEQ) on
September 7, 2010 (Altamont 2010). A Corrective Action Plan (CAP; Altamont 2011) was implemented
upon approval by the North Carolina Department of Environmental and Natural Resources, as
recorded in the September 1, 2011, letter regarding "Approval of the County's Corrective Action
Plan" (DENR 2011). The implemented remedy includes the extraction of leachate through dedicated
submersible pumps installed within landfill gas extraction wells and disposal of the leachate into the
Tuckasegee Water & Sewer Authority (TWSA) collection system. In addition to the leachate
extraction, groundwater natural attenuation parameters are monitored, and natural attenuation
processes are evaluated. As discussed in the CAP, a corrective action evaluation report is prepared
every 5 years. The evaluation report analyzes the progress of the approved corrective action remedy
based on semiannual water quality monitoring data. The remedy was implemented in a phased
approach, with full implementation occurring on September 6, 2013. The first Five -Year Corrective
Action Evaluation Report (CAER), submitted by Altamont on October 31, 2016 (Altamont 2016),
concluded that the current conditions of the monitored natural attenuation (MNA) parameters and
Site geochemical parameters allow for the slow degradation of the select contaminants identified in
the CAER. The second CAER was submitted by Anchor QEA on January 13, 2022, and concluded that
the leachate extraction system has improved but still does not align with the anticipated
performance as modeled in the CAP.
This report serves as the second semiannual water quality monitoring report for 2023. The report
provides an evaluation of groundwater and surface water quality. The water quality monitoring
network is presented in Figure 2. The generalized groundwater flow direction in the upper parts of
the underlying aquifer system is provided in Figure 3. In addition to groundwater and surface water
monitoring, this report includes analysis of the extracted leachate and two domestic water wells. The
water samples collected from selected monitoring points during the fall sampling event were
analyzed for a range of parameters, as presented in Section 2.2 and Table 1. The fall 2023 sampling
Fall 2023 Semiannual
Water Quality Monitoring Report 1 April 2024

event was performed on October 4, 5, 9, and 11, 2023. These sampling efforts are being reported in
accordance with requirements stipulated in the DEQ Solid Waste Management Rules codified under
Title 15A, Subchapter 13B of the North Carolina Administrative Code (NCAC).
Fall 2023 Semiannual
Water Quality Monitoring Report 2 April 2024

2 Semiannual Monitoring
2.1 Groundwater, Surface Water, Domestic Well, and Leachate
Sampling
The Site monitoring wells (MW-01, MW-02, MW-03, MW-04, MW-05R, MW-06, and MW-07), surface
water sample locations (SW-01, SW-02, and SW-03), leachate sample location (LT-01), and domestic
wells (DW-01 and DW-02) were sampled on October 4, 5, 9, and 11, 2023, by Anchor QEA. Static
groundwater level measurements and field parameter data are included on the sampling logs
presented in Appendix A. Field equipment calibration logs for the YSI Professional Plus
Multiparameter Water Quality Meter and the Hach 2100Q Turbidimeter are also provided in
Appendix A. The full suite of groundwater and surface water laboratory analytical results is presented
in the laboratory analysis reports in Appendix B.
Monitoring wells MW-01 and MW-06 are considered to be the Site's upgradient monitoring wells;
MW-03 and MW-05R are located in the mid -gradient portion of the Site; and MW-02, MW-04, and
MW-07 monitor downgradient portions of the Site. As summarized in Table 2, the total depths of the
monitoring wells range from 40 to 110 feet below ground surface. The geology of the screened
intervals of the monitoring wells is as follows:
• Saprolite': MW-04 and MW-05R
• Partially weathered rock (PWR)z: MW-03
• Bedrock3: MW-01, MW-02, MW-06, and MW-07
The locations of the monitoring wells, surface water samples, leachate, and domestic well sample
locations are shown in Figure 2.
2.1. 7 Monitoring Well Purging and Sampling Methods
Before the monitoring wells were sampled, the static water level was gauged in each well, and an
initial round of field parameters was measured (consisting of pH, specific conductivity [SC], dissolved
oxygen [DO], turbidity, temperature, and oxidation reduction potential [ORP]).
Anchor QEA personnel used either low -flow techniques or disposable bailers to purge the
monitoring wells and collect groundwater samples. The total depth, condition of the casing, and
groundwater recharge rate determined the purging and sample collection method employed at each
monitoring well.
Saprolite is the result of in -place weathering that produces soil -like material that retains relict features of the parent rock.
z PWR is generally found above the bedrock and is softer than bedrock, but not as soft as saprolite.
3 Bedrock is solid competent rock that underlies Saprolite and partially weathered rock.
Fall 2023 Semiannual
Water Quality Monitoring Report 3 April 2024

Four of the monitoring wells (MW-03, MW-04, MW-06, and MW-07) were purged using low -flow
techniques in accordance with the procedures described by the U.S. Environmental Protection
Agency (EPA) in Low -Flow (Minimal Drawdown) Ground -Water Sampling Procedures (EPA 1996).
During purging, the field parameters (pH, SC, DO, ORP, turbidity, and temperature) were measured
and recorded approximately every 3 minutes. Well purging continued until these parameters had
generally stabilized for three consecutive readings. The required stabilization criteria are determined
by the EPA Region 4 Science and Ecosystem Support Division in Operating Procedure: Groundwater
Sampling (EPA 2017) and are summarized as follows:
• pH values within ±0.1 standard unit (SU)
• SC values within ±5%
• Temperature, DO, and turbidity values within ±10%
• ORP values within ±10 millivolts (mV)
Once the parameters had stabilized, a groundwater sample was collected by field personnel wearing
a new pair of nitrile gloves, using laboratory -supplied sample containers.
Because of their slow recharge rates, monitoring wells MW-01, MW-02, and MW-05R were purged
and sampled using disposable bailers. The wells were purged of three successive well volumes or
purged dry during each sampling event. Monitoring well MW-01 was purged and sampled on
October 5, 2023, after the well had sufficient time to recharge. A round of field parameters was
measured and recorded at the start of purging and after each consecutive well volume had been
purged. Monitoring well MW-02 was purged dry on October 4, and sampled on October 5, 2023,
after the well had sufficient time to recharge. Monitoring well MW-05R was purged dry in the
morning on October 9, 2023, and sampled later in the day after the well had sufficient time to
recharge.
Field parameter data are shown in the well sampling logs included in Appendix A.
2.1.2 Surface Water Sampling Methods
Surface water samples SW-01, SW-02, and SW-03 were collected on October 4, 2023, at their
designated locations along the Tuckasegee River, which is adjacent to and southwest of the landfill
(Figure 2). Sampling location SW-01 is represents surface water quality upstream of the landfill,
sampling location SW-02 represents surface water quality downstream of the landfill, and sampling
location SW-03 represents surface water quality midstream of the landfill. One round of field
parameters was measured and recorded at each surface water sampling location immediately prior
to collecting the sample (Appendix A). The surface water samples were collected in
laboratory -provided sample containers by a technician wearing a new pair of nitrile gloves.
Fall 2023 Semiannual
Water Quality Monitoring Report 4 April 2024

2.1.3 Leachate Sampling Methods
Dedicated bottom -loading air -powered pumps, air pressure lines, and a leachate force main
collection system are installed at the landfill. Pumps are installed in landfill gas extraction wells
EW-1 R, EW-2R, EW-3R, EW-4, EW-5, EW-6, EW-7, EW-8, EW-9, and EW-10. The gas extraction well
locations are presented in Figure 2. The leachate is pumped from the wells into a flow equalization
tank, which is connected to the TWSA wastewater collection system.
The flow equalization tank is east of the landfill, adjacent to the existing landfill gas flare. A grab
sample of leachate (LT-01) was acquired on October 4, 2023, by collecting a sample as the leachate
entered the flow equalization tank. One round of field parameters was measured and recorded after
the sample was collected (Appendix A).
2. 7.4 Domestic Well Sampling Methods
The domestic well water samples (DW-01 and DW-02) were collected on October 11, 2022, from an
outside spigot at the residence located at 318 Joe Wilkey Road (DW-01) and 138 Joe Wilkey Road
(DW-02), bordering the northern boundary of the landfill (Figure 2). The wells were purged of
30 gallons prior to sample collection. One round of field parameters was measured and recorded
after the 30 gallons had been purged. The domestic well water samples were collected in
laboratory -provided sample containers by field personnel wearing new nitrile gloves.
2.2 Sample Handling, Documentation, and Analysis
2.2. 7 Sampling Schedule
The sampling schedule for semiannual sampling events at the Jackson County Landfill is presented in
the following table:
Parameter
Groundwater
Surface Water
Leachate
Domestic Well
Groundwater
Appendix I VOCs
Annual Spring
Annual Spring
Annual Spring
Not Applicable
Appendix I Metals
Annual Spring
Annual Spring
Annual Spring
Not Applicable
Appendix II VOC
Annual Fall
Annual Fall
Annual Fall
Not Applicable
Appendix 11 SVOC
Annual Fall
Annual Fall
Annual Fall
Not Applicable
Appendix 11 Metals
Annual Fall
Annual Fall
Annual Fall
Not Applicable
Mercury
Annual Fall
Annual Fall
Annual Fall
Not Applicable
Sulfide
Semiannual
Semiannual
Semiannual
Not Applicable
1,4-Dioxane
Semiannual
Semiannual
Semiannual
Not Applicable
Herbicides and
Pesticides
Biennial — Fall
Even Years
Biennial — Fall
Even Years
Not Applicable
Not Applicable
MNA Parameters
Biennial
Not Applicable
Not Applicable
Not Applicable
Fall 2023 Semiannual
Water Quality Monitoring Report 5 April 2024

Parameter
Groundwater
Surface Water
Leachate
Domestic Well
Groundwater
Spring and Fall
Odd Years
Hardness
Not Applicable
Semiannual
Not Applicable
Not Applicable
VOC by 524.2
Not Applicable
Not Applicable
Not Applicable
Semiannual
2.2.2 Fall 2023 Sampling
Field parameters and additional observations pertaining to the Site sampling locations are provided
in the sampling logs (Appendix A). Following sample collection, each groundwater, surface water,
leachate, and domestic well water sample was immediately placed on ice in a sample cooler for
transport to Pace Analytical, a North Carolina -certified laboratory in Huntersville, North Carolina. The
collected samples were analyzed for the following parameters (Table 1):
• Groundwater
— Appendix II metals, including mercury, using EPA Methods 6020B and 7470A
— Appendix II volatile organic compounds (VC)Cs) using EPA Method 8260D
— Appendix II semivolatile organic compounds (SVOCs) using EPA Method 8270D
— 1,4-Dioxane using EPA Method 8260DSIM
— Monitored Natural Attenuation (MNA) Parameters
— Sulfide
• Surface water
— Appendix II metals, including mercury, using EPA Methods 6020B and 7470A
— Appendix II volatile organic compounds (VC)Cs) using EPA Method 8260D
— Appendix II SVOCs using EPA Method 8270D
— 1,4-Dioxane using EPA Method 8260DSIM
— Hardness
— Sulfide
• Leachate
— Appendix II VOCs, using EPA Method 8260D
— 1,4-dioxane, using EPA Method 8260DSIM
— Appendix II metals using EPA Method 6020B
• Groundwater from domestic wells
— VOCs using EPA Method 524.2
Proper chain -of -custody documentation procedures were followed during collection and
transportation of each sample (Appendix B). Six trip blank samples for quality control/quality
assurance purposes were included in the sample coolers and analyzed for Appendix II VOCs when
Fall 2023 Semiannual
Water Quality Monitoring Report 6 April 2024

applicable. The reports of the laboratory analyses are provided in Appendix B. Laboratory analyses
performed on the samples are summarized in Table 1.
Fall 2023 Semiannual
Water Quality Monitoring Report 7 April 2024

3 Findings
The field parameter data and laboratory analytical results for the groundwater samples (from
monitoring wells MW-01 through MW-07), surface water samples (SW-01 and SW-02), leachate
sample (LT-01), and domestic well samples (DW-01 and DW-02) collected at the landfill are included
in Appendices A and B. The results are also submitted separately to the DEQ Division of Waste
Management SWS in the Electronic Data Deliverable format (DEQ 2020).
The laboratory analytical results were reported and appropriately qualified as follows:
• Non -Detections: Non -detections are values reported by the laboratory as less than the
method detection limits (MDLs). They are tabulated in Table 3 and flagged with a "U" qualifier.
The MDL is the minimum concentration of a substance that can be measured and reported by
a laboratory with 99% confidence that the constituent concentration is greater than zero.
• Estimated or "J" Qualified: A "J" qualifier is used by the laboratory for parameters that are
detected at estimated concentrations greater than the MDL but less than the laboratory's
method reporting limit. The method reporting limit is the minimum concentration of a target
analyte that can be accurately determined by the referenced method.
• Groundwater Quality Standard: Detected concentrations of constituents in groundwater
samples were compared to applicable North Carolina groundwater quality standards. For
most constituents, this standard is defined in the 15A NCAC 2L.0202 Groundwater Standard
15A NCAC 2L.0202 (2L standard). Detected concentrations of analytes in groundwater with no
established 2L standard were compared to the interim maximum allowable concentrations
(IMACs) for Class GA and GSA groundwater (in accordance with 15A NCAC 02L.0202).
• 2B Standard: Detections of analytes in surface water samples were compared to the surface
water quality standards defined in 15A NCAC 2B (213 standards). Hardness -dependent
2B surface water standards were calculated using the average analyzed hardness value
(calculated from the upstream and downstream surface water sampling location results) via
the most stringent hardness -dependent metal calculation.
Table 3 summarizes detected concentrations of analytes that exceeded their respective 2L standard,
IMAC, or 2B standard.
3.1 Groundwater
Measured field parameters and analytical results for groundwater samples collected from the
monitoring wells during the fall 2023 sampling event are discussed in the following sections and
summarized in Table 3.
Fall 2023 Semiannual
Water Quality Monitoring Report 8 April 2024

3.1.7 Field Parameters
Field parameter measurements were obtained from all Site monitoring wells (MW-01, MW-02,
MW-03, MW-04, MW-05R, MW-06, and MW-07). Field parameters are presented in Table 3 and
summarized below:
• pH: The pH readings ranged from 5.2 SU in MW-06 to 7.1 SU in MW-05R. Of these monitoring
wells, the pH values for MW-01, MW-02, MW-03, MW-04, MW-06, and MW-07 were less than
the 2L standard pH range of 6.5 to 8.5 SU.
• Turbidity: Turbidity ranged from 0.28 nephelometric turbidity units (NTUs) in MW-04 to
81.5 NTU in MW-05R. Generally, higher values were measured at the monitoring wells
(MW-01, MW-02, and MW-05R) that were purged and sampled using the bailer method
(Section 2.1.1). The bailers were lowered gently to minimize water column disturbance when
the samples were collected.
• Dissolved Oxygen (DO): DO concentrations at the Site ranged from 0.95 milligram per liter
(mg/L) in monitoring well MW-07 to 2.66 mg/L in monitoring well MW-04. DO readings were
not measured in monitoring wells MW-01, MW-02, and MW-06 due to equipment
malfunction.
• SC: SC concentrations at the Site ranged from 63.1 micromhos per centimeter (pmhos/cm) in
monitoring well MW-06 to 819 pmhos/cm in monitoring well MW-07.
• Oxidation/Reduction Potential: ORP concentrations at the Site ranged from -18.9 mV in
monitoring well MW-05R to 504.3 mV in monitoring well MW-04.
3.1.2 Appendix 11 Metals (Total)
Fifteen metals were detected in one or more of the monitoring well samples. Two of these metals
(cobalt and iron) were detected at concentrations above their respective NC21- and/or IMAC water
quality standards in one or more of the groundwater samples. A summary of the detections is
provided below.
• Cobalt (21- standard of 1 pg/L): Cobalt was detected in MW-01, MW-02, MW-03, MW-04,
MW-05R, MW-06, and MW-07. Cobalt concentrations in these samples ranged from 2.3 pg/L
(MW-07) to 95.4 pg/L (MW-01). As noted in Section 2.1, monitoring well MW-01 is considered
to represent upgradient conditions. The second upgradient well (MW-06) also showed an
exceedance of cobalt (3.3 pg/L). Historically, cobalt has been present at concentrations that
exceeded its applicable water quality standard in groundwater samples from each of the
seven monitoring wells.
• Iron (21- standard of 300 pg/L): Iron was detected in MW-01, MW-02, MW-05R, and
MW-07. Iron concentrations in these samples ranged from 700 pg/L (MW-07) to
23,500 pg/L (MW-05R).
Fall 2023 Semiannual
Water Quality Monitoring Report 9 April 2024

Cobalt has historically been present at concentrations exceeding its water quality standard in
samples collected from multiple groundwater monitoring wells at the Site. However, the elevated
turbidity values measured in monitoring wells MW-01, MW-02, and MW-05R, the three monitoring
wells that are purged and sampled using the bailer method, may have affected the reported iron
concentrations.
3.1.3 Appendix 11 VOCs and 1,4-Dioxane
Nine VOCs were detected in one or more of the monitoring wells (Table 3). Three of these VOCs
(1,4-xane, benzene, and vinyl chloride) were detected at concentrations that exceeded their
respective 2L standards in the groundwater samples collected from one or more monitoring wells.
Concentration -versus -time graphs (trend plots) were created for the monitoring wells that have
historically exhibited the following VOC concentrations in excess of their 2L standards (Figures 4
through 10):
• 1,4-Dioxane (21L standard of 3 pg/L): The detected concentrations of 1,4-dioxane exceeded its
2L standard in MW-03 (6.7 pg/L), MW-04 (13.4 pg/L), MW-05R (7.1 pg/L), and MW-07
(21.2 pg/L). 1,4-Dioxane was not detected in monitoring wells MW-01, MW-02, or MW-06.
Trend plots of 1,4-dioxane concentrations in MW-04 and MW-07 show declining
concentrations from 2018 into 2021; however, in the fall of 2021 and spring of 2022,
respectively, concentrations began to increase (Figure 10). The trend plot for MW-3 shows
1,4-dioxane fluctuating above and below the 2L standard, but generally in a declining trend.
• Benzene (2L standard of 1 pg/L): Benzene was detected at concentrations that exceeded its
2L standard in MW-05R (1.1 pg/L) and MW-07 (1.6 pg/L). Benzene concentrations at MW-5R
have fluctuated consistently since 2012 (Figure 8). Benzene concentrations at MW-07 have
been relatively stable since 2011 (Figure 10).
• Vinyl chloride (21L standard of 0.03 pg/L): The concentration of vinyl chloride in the sample
collected from one monitoring well, MW-05R (0.55 pg/L J), exceeded its 2L standard. A trend
plot for vinyl chloride concentrations in MW-05R shows fluctuating concentrations over time;
however, the fall 2020 event concentrations have been in decline (Figure 8).
A review of historical groundwater data indicates the VOCs (1,4-dioxane; benzene; and vinyl chloride)
exhibiting concentrations that exceeded the 2L standards during the fall 2023 sampling event have
been detected at relatively consistent concentrations for the past several years. As described in
Section 3.2.3, historical surface water samples from the Tuckasegee River, which may receive
discharge from the saprolite groundwater -bearing zone, have consistently shown no detections of
these compounds, or other VOCs.
Fall 2023 Semiannual
Water Quality Monitoring Report 10 April 2024

3.2 Surface Water
The following sections summarize the measured field parameters and analytical results associated
with the three surface water samples collected during the fall 2022 sampling event.
3.2.7 Field Parameters
Field parameters are presented in Table 3 and summarized below:
• pH: The pH readings for the upstream (SW-01), downstream (SW-02), and midstream (SW-03)
surface water samples collected during the fall 2023 sampling event were 8.3, 8.6, and 8.8 SU,
respectively. The pH readings for all surface water samples were within than the 2B standard
range of 6.0 to 9.0 SU.
• Turbidity: The turbidity values measured in SW-01 (1.85 NTU), SW-02 (2.99 NTU), and SW-03
(2.47 NTU) were less than the 2B standard, which is established at less than or equal to
50 NTU for the receiving water in streams not designated as trout waters.
• DO: DO was measured at a concentration of 8.54 mg/L in SW-01, 8.40 mg/L in SW-02, and
8.98 mg/L in SW-03. The 2B standard is established as greater than or equal to 4 mg/L; thus,
each sample is within the acceptable DO range.
• SC: SC concentrations in surface water samples SW-01, SW-02, and SW-03 were recorded at
39.0, 43.8, and 36.8 pmhos/cm, respectively. These concentrations of SC are consistent with
historical data for surface water samples SW-01 and SW-02.
• ORP: ORP values for SW-01, SW-02, and SW-03 were 138.6, 93.2, and 119.4 mV, respectively.
The measured concentrations of ORP in surface water samples SW-01, SW-02, and SW-03 are
consistent with historical data.
3.2.2 Appendix 11 Metals
Five metals were detected in one, both or all surface water sampling locations. Of these metals, none
exceeded the established 2B standards.
3.2.3 Appendix 11 VOCs and 7,4-Dioxane
No VOCs were detected at surface water locations SW-01, SW-02, and SW-03 above the
2B standards.
3.3 Leachate
Table 3 identifies the VOCs, SVOCs, and metals identified in the leachate sample. In general,
13 metals, 11 VOCs, and 2 SVOCs were detected. The number and concentration of the constituents
detected in the leachate varies each sampling event. Table 4 provides the historical concentrations of
VOCs and SVOCs removed by the leachate extraction system and provides a calculation of the total
mass removed.
Fall 2023 Semiannual
Water Quality Monitoring Report 11 April 2024

On September 1, 2012, leachate extraction was initiated following installation of leachate extraction
pumps in the 10 landfill gas extraction wells at the Site (Figure 2). Based on readings taken from the
leachate totalizer during the October 2023 monitoring events, approximately 40,922 gallons of
leachate were discharged through a permanent connection to the TWSA between March 28, 2023,
and October 4, 2023.
In fall 2013, the active portion of the approved corrective action remedy was initiated. Based on the
leachate analytical results for the sample collected on October 4, 2023, Anchor QEA estimates that
approximately 0.019 pounds of VOCs were removed with the extracted leachate between the
March 2023 and October 2023 sampling events. Mass removal calculations through October 2023
are included in Table 4
3.4 Domestic Well
The following sections summarize measured field parameters and analytical results associated with
the domestic well water sample collected during the fall 2023 sampling event.
3.4.7 Field Parameters
The pH reading for the domestic well samples for DW-01 and DW-02 were 6.4 and 6.5 SU,
respectively. The pH reading recorded at DW-01 (6.4 SU) was less than the 2L standard range of 6.5
to 8.5 SU. The pH reading recorded at DW-02 is within the 2L standard range.
Turbidity measured in DW-01 and DW-02 were 1.54 and 1.31 NTU, respectively. DO was measured at
a concentration of 4.50 mg/L in DW-01 and 10.26 mg/L in DW-02. SC measured in DW-01 and
DW-02 was 80.6 and 97.2 pmhos/cm, respectively. ORP measured in DW-01 and DW-02 was
151.9 and 157.3 mV, respectively. These parameters do not have established water quality standards.
3.4.2 VOCs
No VOCs were detected at concentrations that exceeded their respective MDLs in the domestic well
water samples.
3.5 Groundwater Flow Directions
Groundwater levels in the saprolite, PWR, and bedrock are monitored at the Site. Three of the
bedrock monitoring wells (MW-01, MW-02, and MW-06) are located in the northern and
northwestern portions of the Site (Figure 3; Table 2). The fourth bedrock monitoring well (MW-07) is
located southwest of the landfill (Figure 3). PWR monitoring well MW-03 and saprolite monitoring
wells MW-04 and MW-05R (Figure 3) are located in the south-central and southern parts of the
landfill, respectively. The fall 2023 water level data collected from all the Site monitoring wells is
presented in Table 2 and on Figure 3. Generalized groundwater elevation contours are presented in
Fall 2023 Semiannual
Water Quality Monitoring Report 12 April 2024

Figure 3 and indicate that groundwater flow direction in the combined aquifer system (saprolite,
PWR, and bedrock) is generally to the south-southwest, toward the Tuckasegee River (Figure 3).
Fall 2023 Semiannual
Water Quality Monitoring Report 13 April 2024

4 Summary
The second semiannual water quality monitoring event of 2023 for the Site was performed on
October 4, 5, 9 and 11, 2023. Appendices A and B and Table 3 provide detailed analytical results and
field data summarizing the groundwater, surface water, and leachate quality at the landfill.
4.1 Groundwater Quality
4.1. 7 Appendix ll Metals
Two metals (cobalt and iron) were detected at concentrations that exceeded their associated
groundwater quality standards in one or more of the monitoring wells (Table 3). Cobalt
concentrations exceeded the 2L standard in all the collected groundwater samples. Iron
concentrations exceeded 2L standards in monitoring wells MW-01, MW-02, MW-05R, and MW-07.
4. 7.2 Appendix 11 Volatile Organic Compounds and 1,4-Dioxane
Three VOCs (1,4-dioxane, benzene, and vinyl chloride) were detected at concentrations that
exceeded their respective 2L standards (Table 3) in one or more monitoring wells, including
1,4-dioxane and benzene, in the mid -gradient monitoring well MW-05R and the downgradient well
MW-07.
Trend plots for samples from monitoring wells that had VOC concentrations that exceeded their
2L standards (Figures 4 through 10) show relatively consistent trends with time; however, 1,4-dioxane
is generally showing higher concentrations in MW-04 and MW-07.
4.1.3 Field Parameters and Other Constituents
Six of the seven samples collected from the monitoring wells had pH readings outside of the
2L standard range (6.5 to 8.5 SU). These results are consistent with historical data and are
characteristic of the natural groundwater quality of the region. Turbidity readings ranged from
0.28 NTU (MW-04) to 81.5 NTU (MW-05R).
4.2 Surface Water Quality
4.2. 7 Appendix 11 Metals
No metals were detected at concentrations exceeding their associated 2B standards in any of the
sampled surface water locations (Table 3).
4.2.2 Appendix 11 Volatile Organic Compounds and 1,4-Dioxane
No concentrations for VOCs exceeded 2B standards for surface water during this monitoring event.
Fall 2023 Semiannual
Water Quality Monitoring Report 14 April 2024

4.2.3 Field Parameters and Other Constituents
Field parameters measured in both surface water samples, including DO, pH, and turbidity were
within the 2B standards established for these parameters.
Based on the data presented above, the groundwater migrating from the landfill toward the
Tuckasegee River does not appear to be impacting surface water quality with regards to VOCs and
1,4-Dioxane. Metal concentrations can fluctuate from one sampling to the next. Anchor QEA
recommends continued monitoring to determine if a trend is developing.
4.3 Leachate Quality
The leachate sample (LT-01) was collected from the flow equalization tank and analyzed for
Appendix I VOCs and 1,4-dioxane. Eight VOCs were either detected or detected at estimated
concentrations in the leachate sample (Table 3). There are no established water quality standards for
leachate. 1,4-Dioxane was detected at 62.7 pg/L, which is higher than the detected concentrations of
the compound in the monitoring well groundwater samples. Since monitoring of 1,4-dioxane began
in fall of 2020, the 1,4-dioxane concentrations have ranged from 48.8 pg/L in fall 2021 to 106 pg/L in
spring of 2022.
4.4 Domestic Well Water Quality
No VOCs were detected at concentrations that exceeded their respective MDLs in the domestic well
water samples.
Fall 2023 Semiannual
Water Quality Monitoring Report 15 April 2024

5 Future Activities
Anchor QEA will continue to monitor the water quality on a semiannual basis at the Site. During
spring 2024, domestic well owners will be contacted, and groundwater samples will be collected
from domestic wells if permitted by the well owner, and if possible, based on well pump operability.
Domestic well samples will be analyzed for VOCs only. Samples will be collected from the monitoring
wells, surface water monitoring points, and leachate flow equalization tank during spring 2024 and
fall 2024. In addition to the MNA parameters that were added to the monitoring requirements as
part of the CAP, the analytical suites associated with the current and future sampling events are
outlined in the 2011 CAP (Altamont 2011), the first CAER (Altamont 2016), and the second CAER
(Anchor QEA 2022). The upcoming sampling event parameters are as follows:
Sampling Event
Analytical Suite
Appendix I VOCs (including 1,4-dioxane)
Appendix I Metals
Spring 2024
Sulfide
Hardness
Appendix 11 VOCs (including 1,4-dioxane)
Appendix II Metals
Appendix II SVOCs
Fall 2024
Mercury
Herbicides and Pesticides
Hardness
Sulfide
Fall 2023 Semiannual
Water Quality Monitoring Report 16 April 2024

6 References
Altamont (Altamont Environmental, Inc.), 2010. Assessment of Corrective Measures. Prepared for
North Carolina Department of Environment and Natural Resources. September 7, 2010.
Altamont, 2011. Corrective Action Plan. Prepared for North Carolina Department of Environment and
Natural Resources. June 30, 2011.
Altamont, 2016. Five -Year Corrective Action Evaluation Report. Prepared for North Carolina
Department of Environmental Quality. October 31, 2016.
Anchor QEA (Anchor QEA of North Carolina, PLLC), 2020. Spring 2020 Semiannual Water Quality
Monitoring Report. Prepared for Jackson County Solid Waste Department. June 2020.
Anchor QEA, 2022. Five -Year Corrective Action Evaluation Report. Prepared for North Carolina
Department of Environmental Quality. January 13, 2022.
DENR (North Carolina Department of Environmental and Natural Resources), 2011. Letter to:
Altamont Environmental, Inc. Regarding: Approval of the County's Corrective Action Plan.
September 1, 2011.
DEQ, 2018. "Groundwater Protection Compliance Standards — Constituents List." Last modified
October 15, 2018. Available at:
https://edocs.deq.nc.gov/WasteManagement/0/edoc/12571811SWS_EnviroMonitoring_Const
ituents_List.pdf?searchid=13f8efbl -eel l-485a-b03f-718f2287b271.
DEQ, 2020. Memorandum to: Solid Waste Directors, Landfill Owners/Operators, and North Carolina
Certified Laboratories. Regarding: New Electronic Data Deliverable (EDD) Format.
July 20, 2020.
EPA (U.S. Environmental Protection Agency), 1996. Low -Flow (Minimal Drawdown) Ground -Water
Sampling Procedures. Office of Land and Emergency Management, EPA/540/5-95/504.
EPA, 2017. Science and Ecosystem Support Division. Operating Procedure: Groundwater Sampling.
April 26, 2017.
Fall 2023 Semiannual
Water Quality Monitoring Report 17 April 2024

Tables

Table 1
Summary of Laboratory Analyses Performed on Samples
Groundwater Samples
Location ID
Date
Collected
Sample ID
Appendix I
VOCs
1,4-Dioxane
Appendix I
Metals
Mercury
Appendix II
SVOCs
EPA 8260D
EPA 8260D SIM
EPA 6020B
EPA 7470A
EPA 8270D
MW-01
10/05/2023
MW-01-20231005
X
X
X
X
X
MW-02
10/05/2023
MW-02-20231005
X
X
X
X
X
MW-03
10/11/2023
MW-03-20231011
X
X
X
X
X
MW-04
10/09/2023
MW-04-20231009
X
X
X
X
X
MW-05R
10/09/2023
MW-05R-20231009
X
X
X
X
X
MW-06
10/05/2023
MW-06-20231005
X
X
X
X
X
MW-07
10/09/2023
MW-07-20231009
I X
X
X
X
X
DUPLICATE
10/05/2023
DUP-20231005
X
X
X
X
X
Surface Water, Leachate, Domestic Well, and Quality Control Samples
Location ID
Date
Collected
Sample ID
VOCs
Appendix II
VOCs
Appendix II
SVOCs
1,4-Dioxane
Appendix II
Metals
Mercury
Calcium,
Magnesium,
Hardness
PFAS
EPA 524.2
EPA 8260D
EPA 8270D
EPA 8260D SIM
EPA 6020B
EPA 7470A
EPA 200.7
TBD
DW-01
10/11/2023
DW-01-20231011
X
DW-02
10/11/2023
DW-02-20231011
X
LT-01
10/04/2023
LT-01-20231004
X
X
X
X
SW-01
10/04/2023
SW-01-20231004
X
X
X
X
X
X
X
SW-02
10/04/2023
SW-02-20231004
X
X
X
X
X
X
X
SW-03
10/04/2023
SW-03-20231004
X
X
X
X
X
X
X
TRIP BLANK
10/04/2023
TB-20231004
X
X
TRIP BLANK
10/05/2023
TB-20231005
X
X
TRIP BLANK
10/09/2023
TB-20231006
X
X
TRIP BLANK
10/11/2023
TB-20231007
X
X
EQUIPMENT BLANK
10/04/2023
EQUIP-BLANK-01
X
EQUIPMENT BLANK
10/04/2023
EQUIP-BLANK-02
X
EQUIPMENT BLANK
10/05/2023
EQUIP-BLANK-03
X
EQUIPMENT BLANK
10/09/2023
EQUIP-BLANK-04
X
SOURCE WATER BLANK
10/11/2023
SOURCE-WATER-BLANK-01
X
SOURCE WATER BLANK
10/11/2023
SOURCE-WATER-BLANK-02
X
Groundwater and Surface Water Samples: Monitored Natural Attenuation Parameters
Location ID
Date
Collected
Sample ID
COD
BOD
Ferrous Iron
Total Alkalinity
to PH 4.5
Nitrate
as N
Chloride
Sulfate
TOC
Sulfide
Volatile
Fatty
Acids
Carbon
Dioxide
Ethane,
Ethene,
Methane
Dissolved
H drogen
SM 5220D
SM 5210B
SM 3500-Fe D
SM 2320B
EPA 9056A
531OC-2011
SM4500-S2F
AM23G
AM20GAX and RSK 175
MW-01
10/05/2023
MW-01-20231005
X
X
X
X
X
X
X
X
X
X
X
X
X
MW-02
10/05/2023
MW-02-20231005
X
X
X
X
X
X
X
X
X
X
X
X
X
MW-03
10/11/2023
MW-03-20231011
X
X
X
X
X
X
X
X
X
X
X
X
X
MW-04
10/09/2023
MW-04-20231009
X
X
X
X
X
X
X
X
X
X
X
X
X
MW-05R
10/09/2023
MW-05R-20231009
X
X
X
X
X
X
X
X
X
X
X
X
X
MW-06
10/05/2023
MW-06-20231005
X
X
X
X
X
X
X
X
X
X
X
X
X
MW-07
10/09/2023
MW-07-20231009
X
X
X
X
X
X
X
X
X
X
X
X
X
DUPLICATE
10/05/2023
DUP-20231005
X
X
X
X
X
X
X
X
X
X
X
X
X
Notes:
1: An additional sample was collected for a laboratory -filtered dissolved metals analysis.
Appendix II constituents were analyzed per Title 40 Code of Federal Regulations, Part 258.
Blank cell: Analysis was not performed on that sample.
BOD: biochemical oxygen demand
COD: chemical oxygen demand
EPA: U.S. Environmental Protection Agency (method)
PFAS: per -and polyfluoroalkyl substances
SIM: selective ion monitoring
SM: Standard Method
SVOC: semivolatile organic compound
TB: trip blank
TOC: total organic carbon
VOC: volatile organic compound
Fall 2023 Semiannual Water Quality Monitoring Report Page 1 of 1
Jackson County Closed Municipal Solid Waste Landfill April 2024

Table 2
Well Construction Details and Corresponding Elevations
Stick Up
Depth to
Depth to
Top
Elevation of
Ground
(feet
Depth To
Approximate
Approximate
Top of
Bottom of
Elevation of
Bottom of
Surface
TOC
above
Total Well
Water
Depth to
Top of Bedrock
Screened
Screened
Screened
Screened
Source of Well
Facility
Elevation
Elevation
ground
Depth
(feet below
Groundwater
Bedrock
Elevation
Interval
Interval
Interval
Interval
Geology of Screened
Construction
Permit
Well ID
I Date Drilled
(feet)
(feet)
surface)
(feet bgs)
TOC)
Elevation (feet)
(feet bgs)
(feet)
(feet bgs)
(feet bgs)
(feet)
(feet)
Interval
Information
MW-01
04/23/1992
2,169.40
2,171.42
2.0
110.5
105.09
2,066.33
83.0
2,086.40
95.0
110.0
2,074.40
2,059.40
Bedrock
MW-02
04/22/1992
2,013.15
2,015.38
2.3
60.7
43.64
1,971.74
13.0
2,000.15
45.0
60.0
1,968.15
1,953.15
Bedrock
S&ME, Inc.
MW-03
04/21/1992
2,044.16
2,045.53
1.3
65.5
51.43
1,994.10
57.0
1,987.16
48.5
63.5
1,995.66
1,980.66
Partially Weathered Rock
50-02
MW-04
04/21/1992
1,978.68
1,980.77
2.0
43.0
28.44
1,952.33
NA
NA
25.0
40.0
1,953.68
1,938.68
Saprolite
MW-05R
01/26/2012
2,027.98
2,030.95
2.8
54.0
51.47
1,979.48
NA
NA
44.0
54.0
1,983.98
1,973.98
Saprolite
MW-06
03/23/2004
2,136.58
2,139.57
3.0
94.0
85.13
2,054.44
47.6
2,088.98
84.6
94.6
2,051.98
2,041.98
Bedrock
Altamont
Environmental, Inc.
MW-07
07/30/2010
1,978.71
1,981.29
2.6
95.0
32.96
1,948.33
44.0
1,935.00
70.0
95.0
1,908.71
1,883.71
Bedrock
Notes:
Elevations associated with wells MW-01, MW-02, MW-03, MW-04, and MW-06 are measured relative to mean sea level and are based on surveying completed by Davenport & Associates, Inc.
Elevations associated with wells MW-05R and MW-07 are measured relative to horizontal North American Datum 83 and are based on surveying completed by Wes Cole Land Surveying, PA.
Depth to water was measured on October 4, 5, 9, and 11, 2023.
Depth to bedrock and screened interval for MW-01 through MW-04 was taken from S&ME, Inc., boring logs completed April 21 through 23, 1992.
Depth to bedrock and screened interval for MW-06 was taken from an Altamont Environmental, Inc., boring log completed March 23, 2004.
Depth to bedrock and screened interval for MW-07 was taken from an Altamont Environmental, Inc., boring log completed July 30, 2010.
Depth to bedrock and screened interval for MW-05R was taken from an Altamont Environmental, Inc., boring log completed January 26, 2012.
Monitoring well MW-05 was abandoned on January 26, 2012, by NYEG Drilling, LLC. Monitoring well MW-05R was installed by NYEG Drilling, LLC, on January 26, 2012, as a replacement to MW-05.
Monitoring well MW-05R was surveyed by Wes Cole Land Surveying, PA, on September 28, 2012.
bgs: below ground surface
NA: not applicable
TOC: top of casing
Fall 2023 Semiannual Water Quality Monitoring Report Page 1 of 1
Jackson County Closed Municipal Solid Waste Landfill April 2024

Table 3
Analytical Summary
Location ID
Domestic Well Samples
Leachate Sample
Groundwater Samples
DW-01
DW-02
LT-01
MW-01
MW-02
MW-03
MW-04
MW-0511
Sample ID
DW-01-20231011
DW-02-20231011
LT-01-20231004
MW-01-20231005
MW-02-20231005
MW-03-20231011
MW-04-20231009
MW-05R-20231009
Sample Date
10/11/2023
10/11/2023
10/4/2023
10/5/2023
10/5/2023
10/11/2023
10/9/2023
10/9/2023
Sample Type
N
N
N
N
N
N
N
N
Matrix
WG
WG
WG
WG
WG
WG
WG
WG
Method
NC2L
NC2L
IMAC
I NC213
Conventional Parameters
Water level depth (feet) Field
--
--
--
--
--
105.09
43.64
51.43
28.44
51.47
Temperature (°C) Field
--
--
--
15.0
15.3
30.3
16.1
16.9
15.7
15.5
17.0
H (SU) Field
6.5-8.5
--
6.0-9.0
6.4
6.5
7.4
5.7
6.1
5.4
5.7
7.1
Turbidity (NTU) Field
--
--
<50
1.54
1.31
408
14.8
21.1
2.72
0.28
81.5
Dissolved oxygen (m /L) Field
--
--
>_4.0
4.50
10.26
2.05
--
--
2.48
2.66
1.55
Specific conductivity (pmhos/cm) Field
--
--
--
80.6
97.2
5155
185.5
225.1
269.5
727.0
690.0
ORP (mV) Field
--
--
--
151.9
157.3
85.2
38.0
265.0
263.8
504.3
-18.9
Hardness as Ca and M (m /L) SM2340B
--
--
--
--
--
892
--
--
--
--
--
Monitored Natural Attenuation Parameters
Alkalinity, Total (µ /L) SM2320B
--
20000
--
--
--
89.3
43.4
65.9
150
202
Biochemical oxygen demand (m /L) SM5210B
--
--
--
--
--
5.3
2.0 U
2.0 U
2.0 U
75.7
Carbon dioxide (µ /L) EPA RSK-175
--
--
--
227000
64900
200000
124000
6010000
Chemical oxygen demand (m /L) SM5220D
--
--
--
--
--
--
22.5 J
12.5 U
20.9 J
17.7 J
134
Chloride (m /L) SW9056A
250
--
230
--
--
--
0.79 J
21.3
30.6
78.4
67.7
Ferrous iron (p /L) SM3500FEB
--
--
1000
--
--
260 J
68 J
97 J
77 J
4300
Ethane (p /L) RSK175
--
0.0059 U
0.0059 U
--
0.0059 U
0.0059 U
Ethene (p /L) RSK175
--
--
--
--
0.0057 U
0.0057 U
--
0.0057 U
0.0057 U
Hydrogen (nM) AM20GAX
--
--
--
--
--
10
292
--
Iron, ion (Fe 3+) (reactive iron) SM3500FED
--
--
--
--
19200
2300
250 U
250 U
19200
Methane (p /L) RSK175
--
0.366
0.0053 U
--
0.0189
1.87
Nitrate as nitrogen (m /L) SW9056A
10
--
10
--
--
0.060 U
0.19
4.2
1.5
0.060 U
Sulfate (m /L) SW9056A
250
--
250
--
--
1.2
22.7
3.0
79.8
0.50 U
Sulfide (m /L) SM4500S2D
--
--
--
--
--
0.048 J
0.042 J
0.022 U
0.022 U
0.022 U
Total organic carbon (m /L) SM5310B
--
--
--
--
--
2.4
2.7
5.0
2.7
13.8
Appendix II Metals, Total (N /L)
Antimony SW6020B
1
--
5.6
--
1.6 J
0.20 U
0.20 U
0.20 U
0.20 U
0.20 U
Arsenic SW6020B
10
--
10
--
148
0.11 J
0.48 J
0.12 J
0.087 U
0.38 J
Barium SW6020B
700
--
1000
--
13600
101
43.6
131
58.3
232
Beryllium SW6020B
4
--
6.5
--
3.0
0.050 U
0.050 U
0.050 U
0.050 U
0.065 J
Cadmium SW6020B
2
--
0.08*
--
0.46 J
0.74
0.060 U
0.26
0.25
0.094 J
Chromium SW6020B
10
--
11.94*
--
1120
0.50 U
2.1
0.54 J
0.74 J
1.4
Cobalt SW6020B
1
--
1.6
--
68.2
95.4
6.9
15.4
2.4
12.4
Copper SW6020B
1000
--
1.33*
--
155
1.6 J
3.6
1.1 U
1.1 U
15.9
Iron SW6020B
300
--
1000
--
--
19500
2320
86.1
20.9 U
23500
Lead SW6020B
15
--
0.21*
--
--
45.9
0.077 U
0.48 J
0.15 J
0.077 U
0.42 J
Mercury SW7470A
1
--
0.012
--
0.12 U
0.12 U
0.12 U
0.12 U
0.28
0.12 U
Nickel SW6020B
100
--
7.89*
--
171
12.1
2.2
2.8
1.4
2.7
Selenium SW6020B
20
--
5
--
2.0 J
0.072 U
0.15 J
0.072 U
0.30 J
0.093 J
Thallium SW6020B
2
--
2
--
0.69 J
0.82
0.050 U
0.098 J
0.076 J
0.050 U
Tin SW6020B
2000
770
--
26.0
0.43 U
0.43 U
0.43 U
0.43 U
1.1
Vanadium SW6020B
7
--
--
304
0.25 U
2.4
0.25 U
0.25 U
1.2
Appendix II Volatile Organic Compounds (VOCs) and 1,4-Dioxane (p /L)
1,1-Dichloroethane SW8260D 6 -- 1 6 -- 0.37 U 1.2 0.37 U 0.37 U 0.37 U 0.37 U
Fall 2023 Semiannual Water Quality Monitoring Report Page 1 of 5
Jackson County Closed Municipal Solid Waste Landfill April 2024

Table 3
Analytical Summary
Surface Water Samples
Trip Blanks
MW-06
MW-07
DUPLICATE (MW-06)
SW-01
SW-02
SW-03
FieldQC
FieIdQC
FieIdQC
FieIdQC
MW-06-20231005
MW-07-20231009
DUP-20231005
SW-01-20231004
SW-02-20231004
SW-03-20231004
TB-20231004
TB-20231005
TB-20231009
TB-20231011
10/5/2023
10/9/2023
10/5/2023
10/4/2023
10/4/2023
10/4/2023
10/4/2023
10/5/2023
10/9/2023
10/11/2023
N
N
FD
N
N
N
N
N
N
N
WG
WG
WG
WS
WS
WS
WQ
WQ
WQ
WQ
85.13
32.96
--
--
--
--
-
16.1
14.8
--
21.6
24.2
21.7
--
--
--
--
5.2
6.0
--
8.3
8.6
8.8
--
--
--
--
1.98
1.26
--
1.85
2.99
2.47
--
--
--
--
--
0.95
--
8.54
8.40
8.98
--
--
--
--
63.1
819.0
--
39.0
43.8
36.8
--
--
--
--
254.2
-29.5
--
138.6
93.2
119.4
--
--
--
--
--
--
--
11.2
10.7
10.4
--
--
--
--
29.5
263
29.7
--
--
--
--
--
--
--
2.0 U
2.0 U
2.0 U
--
--
--
--
--
--
--
227000
276000
202000
12.5 U
24.8 J
12.5 U
--
--
--
--
--
--
--
0.73 J
83.9
0.93 J
--
--
--
--
--
--
--
75 J
570
54 J
--
--
--
--
--
--
--
0.0059 U
0.0059 U
0.0059 U
--
--
--
--
--
--
--
0.0057 U
0.0057 U
0.0057 U
--
--
--
--
--
--
--
102
3.9
87.9
250 U
250 U
250 U
--
--
--
--
--
--
--
0.0053 U
0.393
0.0053 U
--
--
--
--
--
--
--
0.22
0.060 U
0.25
--
--
--
--
--
--
--
0.80 J
17.6
0.89 J
--
--
--
--
--
--
--
0.022 U
0.022 U
0.022 U
0.022 U
0.022 U
0.022 U
--
--
--
--
0.50 U
2.6
0.50 U
--
--
--
--
--
--
--
0.20 U
0.20 U
0.20 U
0.20 U
0.20 U
0.20 U
--
--
--
--
0.087 U
0.12 J
0.087 U
0.088 J
0.087 U
0.087 U
--
--
--
--
49.5
451
48.2
16.2
12.6
10.7
--
--
--
--
0.056 J
0.050 U
0.078 J
0.050 U
0.050 U
0.050 U
--
--
--
--
0.12 J
0.060 U
0.12 J
0.060 U
0.060 U
0.060 U
--
--
--
--
0.61 J
0.84 J
0.58 J
0.65 J
0.50 U
0.50 U
--
--
--
--
3.3
2.3
3.1
0.12 J
0.13 J
0.094 J
--
--
--
--
1.4 J
1.1 U
1.2 J
1.1 U
1.1 U
1.1 U
--
--
--
--
47.9 J
700
37.6 J
--
--
--
--
--
--
--
0.14 J
0.08 J
0.14 J
0.077 U
0.077 U
0.077 U
--
--
--
--
0.12U
0.12U
0.12U
0.12U
0.12U
0.12U
--
--
--
--
4.0
7.7
3.9
0.42 U
0.42 U
0.42 U
--
--
--
--
0.072 U
0.072 U
0.072 U
0.072 U
0.072 U
0.072 U
--
--
--
--
0.24
0.050 U
0.25
0.050 U
0.050 U
0.050 U
--
--
--
--
0.43 U
1.3
0.43 U
0.43 U
0.43 U
0.43 U
--
--
--
--
0.41 J
0.34 J
0.37 J
0.51 J
0.46 J
0.43 J
--
--
--
--
0.81J 1 0.37U 1 0.76J 1 0.37U 1 0.37U 1 0.37U 1 0.37U 1 0.37U 1 0.37U 1 0.37U
Fall 2023 Semiannual Water Quality Monitoring Report Page 2 of 5
Jackson County Closed Municipal Solid Waste Landfill April 2024

Table 3
Analytical Summary
Location ID
Domestic Well Samples
Leachate Sample
Groundwater Samples
DW-01
DW-02
LT-01
MW-01
MW-02
MW-03
MW-04
MW-0511
Sample ID
DW-01-20231011
DW-02-20231011
LT-01-20231004
MW-01-20231005
MW-02-20231005
MW-03-20231011
MW-04-20231009
MW-05R-20231009
Sample Date
10/11/2023
10/11/2023
10/4/2023
10/5/2023
10/5/2023
10/11/2023
10/9/2023
10/9/2023
Sample Type
N
N
N
N
N
N
N
N
Matrix
WG
WG
WG
WG
WG
WG
WG
WG
Method
NC2L
NUL
IMAC
NC213
1,2-Dichloroethene, cis- SW8260D
70
--
60
--
--
0.38 U
0.98 J
0.38 U
0.77 J
0.76 J
2.4
1,4-Dioxane SW8260DM
3
--
0.35
--
--
62.7
0.86 U
2.3
6.7
13.4
7.1
Benzene SW8260D
1
--
1.19
--
--
0.77 J
0.36 J
0.34 U
0.40 J
0.34 U
1.1
Chlorobenzene SW8260D
50
--
140
--
--
2.2
0.49 J
0.28 U
4.7
1.4
4.9
Eth (benzene SW8260D
600
--
97
--
--
0.32 J
0.30 U
0.30 U
0.30 U
0.30 U
0.30 U
Methyl tert-but I ether (MTBE) SW8260D
20
--
19
--
--
0.42 U
0.42 U
0.42 U
0.49 J
0.42 U
0.42 U
Naphthalene SW8260D
6
--
12
--
--
6.9
0.64 U
0.64 U
0.64 U
0.64 U
0.64 U
o-Xylene SW8260D
500
--
600
--
--
0.73 J
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
Total Xylene SW8260D
500
--
670
--
--
0.73 J
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
Vinyl chloride SW8260D
0.03
--
0.025
--
--
0.39 U
0.39 U
0.39 U
0.39 U
0.39 U
0.551
1,4-Dichlorobenzene SW8260D
6
--
488
--
--
2.3
0.33 U
0.33 U
2.4
0.33 U
5.1
Diethyl phthalate SW8270E
6000
--
600
--
--
2.0 U
1.9 U
3.7 J
2.0 U
2.0 U
1.9 U
Fall 2023 Semiannual Water Quality Monitoring Report Page 3 of 5
Jackson County Closed Municipal Solid Waste Landfill April 2024

Table 3
Analytical Summary
Surface Water Samples
Trip
Blanks
MW-06
MW-07
DUPLICATE (MW-06)
SW-01
SW-02
SW-03
FieldQC
FieIdQC
FieIdQC
FieIdQC
MW-06-20231005
MW-07-20231009
DUP-20231005
SW-01-20231004
SW-02-20231004
SW-03-20231004
TB-20231004
TB-20231005
TB-20231009
TB-20231011
10/5/2023
10/9/2023
10/5/2023
10/4/2023
10/4/2023
10/4/2023
10/4/2023
10/5/2023
10/9/2023
10/11/2023
N
N
FD
N
N
N
N
N
N
N
WG
WG
WG
WS
WS
WS
WQ
WQ
WQ
WQ
0.46J
1.7
0.45J
0.38U
0.38U
0.38U
0.38U
0.38U
0.38U
0.38U
0.86 U
21.2
0.86 U
0.86 U
0.86 U
0.86 U
--
--
--
--
0.34 U
1.6
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.28U
4.1
0.28U
0.28U
0.28U
0.28U
0.28U
0.28U
0.28U
0.28U
0.30U
0.30U
0.30U
0.30U
0.30U
0.30U
0.30U
0.30U
0.30U
0.30U
0.53 J
0.80 J
0.45 J
0.42 U
0.42 U
0.42 U
0.42 U
0.42 U
0.42 U
0.42 U
0.64 U
0.64 U
0.64 U
0.64 U
0.64 U
0.64 U
0.64 U
0.64 U
0.64 U
0.64 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.34 U
0.39 U
0.39 U
0.39 U
0.39 U
0.39 U
0.39 U
0.39 U
0.39 U
0.39 U
0.39 U
0.33 U
4.6
0.33 U
0.33 U
0.33 U
0.33 U
0.33 U
0.33 U
0.33 U
0.33 U
1.9U
2.0U
1.8U
1.9U
2.0U
0.18U
--
--
--
--
Fall 2023 Semiannual Water Quality Monitoring Report Page 4 of 5
Jackson County Closed Municipal Solid Waste Landfill April 2024

Table 3
Analytical Summary
Notes:
indicates the detected concentration is greater than the NC2L (2022) or NC2L IMAC (2022) screening level.
indicates the detected concentration is greater than the NC213 screening level.
Bold indicates a detected result.
Italicized indicates non -detected concentration is above one or more identified screening levels
*: 213 surface water standard calculated using average analyzed hardness value (calculated from the upstream and downstream sampling location results) via the most stringent hardness -dependent metal calculation per North Carolina Administrative Code, Title 15A: Department of
Environmental Quality, Subchapter 2B - Surface Water and Wetland Standards (last amended September 2022).
All nondetect results are reported at the method detection limit.
Horizontal coordinate datum is North American Datum of 1983 State Plane North Carolina FIPS 3200 (US Survey Feet).
--: compound not analyzed for the sample
pg/L: micrograms per liter
213: surface water standard per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 213 — Surface Water and Wetland Standards (last amended in September 2022) or the standard obtained from the U.S. Environmental Protection Agency
Nationally Recommended Water Quality Criteria for Aquatic Life and Human Health
2L: Subchapter 2L — Groundwater Classifications and Standards, Department of Environmental Quality (Amended April 1, 2022); groundwater standard from North Carolina Administrative Code, Title 15A
Appendix I: indicates volatile organic compounds and metals per 40 Code of Federal Regulations Part 258
IMAC: interim maximum allowable concentration (listed in 2L Appendix 1)
J: estimated value between the method detection limit and reporting limit established by the analytical laboratory.
mg/L: milligrams per liter
mv: millivolts
N: normal environmental sample
NTU: nephelometric turbidity unit
PCE: perchloroethylene
SM: Standard Method
SU: standard units
TB: trip blank
U: compound analyzed for but not detected above detection limit
pmhos/cm: microsiemens per centimeter
Fall 2023 Semiannual Water Quality Monitoring Report Page 5 of 5
Jackson County Closed Municipal Solid Waste Landfill April 2024

Table 3
Analytical Summary
Fall 2023 Semiannual Water Quality Monitoring Report Page 5 of 5
Jackson County Closed Municipal Solid Waste Landfill April 2024

Table 4
Mass Removal Calculations for VOCs Detected in the Leachate Sample (LT-01)
Sample Dates
Detected VOCs
Concen-
tration in
LT-01
(mg/L)
Cumulative
Flow at Gauge
(gal)
Differential
Flow (gal)
Mass
Removed
(lb)
Estimated Cumulative
Mass Removed (lb)
Beginning
Ending
9/1/2012
10/25/2012
1,4-dichlorobenzene
0.0034
11,500
J
J
J
J
11,500
0.00033
4-meth I-2 entanone (MIBK)
0.0021
0.00020
Acetone
0.0292
0.00280
Benzene
0.0021
0.00020
Chlorobenzene
0.0029
0.00028
cis- 1,2-dichloroethene
0.00063
0.00006
Dichlorodifluoro-methane
0.00093
0.00009
Eth (benzene
0.0102
0.00098
Naphthalene
0.0069
0.00066
Styrene
0.00033
0.00003
Toluene
0.003
0.00029
Total xylenes
0.0094
0.00090
Total:
0.00681
0.00681
10/26/2012
4/11/2013
1,4-dichlorobenzene
0.006
65,500
J
J
J
J
54,000
0.00270
Acetone
0.012
0.00540
Benzene
0.0011
0.00049
Carbon disulfide
0.0067
0.00301
Chlorobenzene
0.0024
0.00108
cis- 1,2-dichloroethene
0.00058 IJI
0.00026
Eth (benzene
0.0083
0.00373
Toluene
0.00059
0.00027
Total xylenes
0.0078
0.00351
Total:
0.02045
0.02726
4/12/2013
10/8/2013
1,4-dichlorobenzene
0.0055
114,737
J
J
49,237
0.00226
4-methyl -2- pentanone (MIBK)
0.0012
0.00049
Benzene
0.0020
0.00082
Chlorobenzene
0.0039
0.00160
cis- 1,2-dichloroethene
0.00080
0.00033
Eth (benzene
0.0151 1
0.00619
Naphthalene
0.0184
0.00754
Toluene
0.0012
0.00049
Total xylenes
0.0090
0.00369
Total:
0.02341
0.05067
10/9/2013
4/8/2014'
1,4-dichlorobenzene
0.0056
164,437
J
J
49,700
0.00232
Benzene
0.0018
0.00075
Chlorobenzene
0.0051
0.00211
cis-1,2-dichloroethene
0.00049
0.00020
Eth (benzene
0.0047
0.00195
Toluene
10.00041 IJI
0.00017
Total xylenes
0.0021
0.00087
Total:
0.00836
0.05903
4/8/2014
10/23/2014'
1,4-dichlorobenzene
0.0053
200,148
J
J
35,710
0.00158
Benzene
0.0014
0.00042
Chlorobenzene
0.003
0.00089
cis-1,2-dichloroethene
0.00049
0.00015
Eth (benzene
0.0027
0.00080
Toluene
10.00051 IJI
0.00015
Total xylenes
0.0014
0.00042
Total:
0.00440
0.06343
10/23/2014
4/21/2015
1,2,3-trimeth (benzene
0.00062
241,700
J
J
J
41,552
0.00021
1,2,4-trimeth (benzene
0.00076
0.00026
2-chlorotoluene
0.00067
0.00023
1,4-dichlorobenzene
0.0059
0.00204
Acetone
0.00790
0.00 7
Benzene
0.0022
0.00076
Chlorobenzene
0.003
0.00104
Eth (benzene
0.0056
0.00194
Isopropyl benzene
0.0013
0.00045
Methy tert-butyl -ether
0.0013
0.00045
Napthalene
0.024
0.00831
n-propylbenzene
0.00088
0.00030
Tetrah drofuran
0.089
0.03080
Toluene
0.00054
0.00019
Vinyl chloride
0.00038
0.000 3
Total xylenes
0.0030
0.00104
Total:
0.05089
0.11432
4/21/2015
10/13/2015
1,4-dichlorobenzene
0.00600
278,420
J
36,720
0.00183
2-butanone
0.00960
0.00294
Benzene
0.00210
0.00064
Chlorobenzene
0.0040
0.00122
Eth (benzene
0.00710
0.00217
Naphthalene
0.021
0.00642
Tetrah drofuran
062
0.01896
Toluene
005
0.00018
xylenes
.31
000Total
0.00095
Total:
0.03531
0.14963
10/13/2015
4/5/2016
1,4-dichlorobenzene
0.00590
337,398
J
58,978
0.00290
Benzene
0.00170
0.00083
Chlorobenzene
0.0038
0.00187
Eth (benzene
0.00500
0.00246
Toluene
0.00063
0.00031
Total xylenes
10.0025 IJI
0.00123
Total:
0.00959
1 0.15922
Fall 2023 Semiannual Water Quality Monitoring Report Page 1 of 3
Jackson County Closed Municipal Solid Waste Landfill April 2024

Table 4
Mass Removal Calculations for VOCs Detected in the Leachate Sample (LT-01)
Sample Dates
Detected VOCs
Concen-
tration in
LT-01
(mg/L)
Cumulative
Flow at Gauge
(gal)
Differential
Flow (gal)
Mass
Removed
(lb)
Estimated Cumulative
Mass Removed (lb)
Beginning
Ending
4/5/2016
10/11/2016'
No detected compounds
352,745
15,347
0.00000
Total:
0.00000
0.15922
10/11/2016
3/21/2017
1,4-dichlorobenzene
0.0046
355,947
3,202
0.00012
Acetone
0.0094 J
0.00025
Benzene
0.0015
0.00004
Chlorobenzene
0.0043
0.00011
Eth (benzene
0.0014
0.00004
Tetrah drofuran
10.066
0.00176
Total x lenes
10.0015 IJI
0.00004
Total:
0.00237
0.16159
3/21/2017
10/11/2017
1,4-dichlorobenzene
0.0041
386,495
30,548
0.00104
Acetone
0.0067 J
0.00170
Acetonitrile
0.008 J
0.00204
Benzene
0.00061
0.00016
Chlorobenzene
0.0012
0.00031
Eth (benzene
0.00087
0.00022
Naphthalene
0.0012
10.12
0.00031
Tetrah drofuran
0.03053
Total:
0.03630
0.19789
10/12/2017
10/18/20183
1,4-dichlorobenzene
0.0028
398,872
1 12,377
0.00029
Acetone
0.017
1
0.00175
Benzene
0.0012
0.00012
Chlorobenzene
0.0024
0.00025
Eth (benzene
0.0018
0.00019
Methylene chloride
10.00034 J
0.00004
Total x lenes
10.00098 11
0.00010
Total:
0.0027
0.20062
10/18/2018
10/22/20193
1,4-dichlorobenzene
0.0037
407,807
1 8,936
0.00028
Acetone
0.006
0.00045
Benzene
0.0017
0.00013
Chlorobenzene
0.0038
0.00028
Eth (benzene
0.0016
0.00012
Toluene
10.00039 1 J
0.00003
Total x lenes
JO.0017 IJI
0.00013
Total:
0.0014
0.20203
10/22/2019
3/18/20203
1,4-dichlorobenzene
0.0056
539,644
131,836
0.00615
1,4-dioxane
0.06
0.06585
Acetone
0.0064
0.00702
Benzene
0.0013
0.00143
Chlorobenzene
0.0032
0.00351
Eth (benzene
0.0027
0.00296
Methyl isobut I ketone
0.00079 J
0.00087
Toluene
0.00070
0.00077
Total x lenes
0.00209 J
0.00229
Total:
0.0886
0.29058
3/18/2020
10/14/20203
1,2-dichloroethene, cis-
0.00029 J
639,343
99,699
0.00024
1,3-dichlorobenzene
0.00027 J
0.00022
1,4-dichlorobenzene
0.0048
0.00398
1,4-dioxane
0.058
0.04814
Acetone
0.011
0.00913
Acetonitrile (ethanenitrile)
0.0047 IJI
0.00390
Benzene
0.0024
0.00199
Chlorobenzene
0.0044
0.00365
Chloroethane
0.00047 J
0.00039
Eth (benzene
0.0018
0.00149
Naphthalene
0.013
0.01079
Tetrah drofuran
0.094
0.07802
Toluene
0.00079
0.00066
Total x lenes
0.0037
0.00307
Vinyl chloride
0.00022 J
0.00018
Total:
0.1659
0.45645
10/14/2020'
10/20/2021
1,4-dichlorobenzene
0.00385
701,994
62,651
0.00201
1,4-dioxane
0.0488
0.02546
Acetone
0.00814
0.00425
Benzene
0.00245
0.00128
Chlorobenzene
0.00428
0.00223
Eth (benzene
0.000838
0.00044
Naphthalene
0.0136
0.00710
Tetrah drofuran
0.203
0.10592
Total x lenes
0.00281
0.00147
Total:
0.1501
0.60659
10/20/2021
3/7/2022
1,4-dichlorobenzene
0.00168
710,029
8,035
0.00034
1,4-dioxane
0.106
0.02155
Acetone
0.00641
0.00130
Benzene
0.00148
0.00030
Chlorobenzene
0.00418
0.00085
Tetrah drofuran
10.168
0.03415
Total:
0.0585
0.66508
Fall 2023 Semiannual Water Quality Monitoring Report Page 2 of 3
Jackson County Closed Municipal Solid Waste Landfill April 2024

Table 4
Mass Removal Calculations for VOCs Detected in the Leachate Sample (LT-01)
Sample Dates
Detected VOCs
Concen-
tration in
LT-01
(mg/L)
Cumulative
Flow at Gauge
(gal)
Differential
Flow (gal)
Mass
Removed
(lb)
Estimated Cumulative
Mass Removed (lb)
Beginning
Ending
3/7/2022
10/4/2022
1,4-dioxane
0.08
734,436
24,407
0.01626
Benzene
0.000568
6.00012
Chlorobenzene
0.00139
0.00028
Tetra hyd rofu ra n
0.0678
0.01378
4-Methyl-2-pentanone
0.00112
0.00023
Carbon disulfide
0.000683
0.00014
Ethylbenzene
0.000267
0.00005
Methyl ethyl ketone
0.00236
0.00048
Naphthalene
0.00366
0.00074
o-xylene
0.000465
0.00009
Toluene
0.00024
0.00005
Total xylene
10.00046S
0.00009
1,4-dichlorobenzene
10.00182
0.00037
Total:
0.0327
0.69777
10/4/2022
3/28/2023
1,4-dioxane
0.0487
765,240
30,804
0.01249
1,2-Dichloroethene, cis-
0.00216
0.00055
Tetra hyd rofu ra n
0.0957
0.02455
1,4-dichlorobenzene
0.00234
0.00060
Total:
0.0382
0.73597
3/28/2023
10/4/2023
1,4-dioxane
0.0627
806,162
40,922
0.01608
Benzene
0.00077
)
)
0.00020
Ethylbenzene
0.00032
0.00008
Naphthalene
0.0069
0.00177
o-xylene
0.00073
0.00019
Total x lene
10.00073 1.1
0.00019
1,4-dichlorobenzene
10.0023
0.00059
Total:
0.0191
0.75507
Notes:
Total xylenes represent the sum of m,p-xylenes and o-xylenes.
Only detected VOCs in leachate sample LT-01 are included in the mass removal calculation.
Leachate extraction at the landfill was initiated on September 1, 2012. Connection to the TWSA sewer was completed on September 6, 2013. Up until the connection to
the TWSA sewer, leachate was pumped into a temporary collection tank and then hauled off site. Extraction volume measurements for leachate hauled off site were
Anchor QEA bases mass removal calculations on the assumption that the VOCs concentration in one sampling event is representative of leachate quality until the next
sampling event occurs and that the leachate removal system has a 100% removal and treatment efficiency.
Differential flow represents the total flow between the LT-01 sample dates.
Estimated cumulative mass removed and treated is estimated based upon a conversion of milligrams to pounds and liters to gallons and the multiplication of the
concentration by the differential flow for the specified period. Formula: ((concentration[mg/L])*(2.2e-6 Ib)/(0.264 gal))*(differential flow).
1. Totalizer readings were not recorded during the sampling event, and the differential flow was calculated based on an interpolated totalizer reading using monthly
readings taken by TWSA for 3 months before and after the sample date.
2. No VOCs were detected in the leachate sample collected during the October 2016 sampling event.
3. In March 2018, the totalizer at the TWSA connection was replaced. During the March 2018 sampling event, Anchor QEA began reading an incorrect totalizer for the
volume of extracted the leachate. Differential flow was calculated for the sample dates in the same manner as Note 1. This table has been updated to reflect the updated
4. Totalizer buried during March 2021 monitoring event, due to on -Site construction. Therefore a totalizer reading was not obtained.
gal: gallon
J: indicates laboratory estimated concentration is above the adjusted method detection limit and below the adjusted reporting limit
lb: pound
mg/L: milligrams per liter
TWSA: Tuckaseigee Water and Sewer Authority
VOC: volatile organic compound
Fall 2023 Semiannual Water Quality Monitoring Report Page 3 of 3
Jackson County Closed Municipal Solid Waste Landfill April 2024

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4. Data presented are from semiannual sampling events from 2007 to Fall 2023.
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ft: feet
Publish Date: 02/22/2024 10:16 AM I User: SAR-SCOL
File Path: \\Wcl-fs1\asheville\Projects\Jackson County\02-Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py
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Constituent Key with 2L Standards
f Tetrachloroethene (PCE) (0.70 µg/L)
Trichloroethene (TCE) (3 µg/L)
cis-1,2-Dichloroethene (70 µg/L)
f Vinyl Chloride (0.03 µg/L)
f Benzene (1 µg/L)
f 1,4-Dichlorobenzene (6 µg/L)
1,4-Dioxane (3 µg/L)
Groundwater Elevation (ft)
-- Leachate Extraction Start Date
Figure 4
Hydrograph and Constituents of Concern Versus Time - MW-01
Fall 2023 Semiannual Water Quality Monitoring Report
Jackson County Closed Municipal Solid Waste Landifll

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Notes:
1. Dashed horizontal lines represent the 2L groundwater standard.
2. Dashed vertical lines represent the start of leachate extraction.
3. Non -detects are plotted as an open symbol at the method detection limit.
4. Data presented are from semiannual sampling events from 2007 to Fall 2023.
µg/L: micrograms per liter
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Constituent Key with 2L Standards
f Tetrachloroethene (PCE) (0.70 µg/L)
Trichloroethene (TCE) (3 µg/L)
cis-1,2-Dichloroethene (70 µg/L)
f Vinyl Chloride (0.03 µg/L)
f Benzene (1 µg/L)
f 1,4-Dichlorobenzene (6 µg/L)
1,4-Dioxane (3 µg/L)
Groundwater Elevation (ft)
-- Leachate Extraction Start Date
190
188
186
184
182 .O
180 >
LU
178
176
174 0
O
172
170
168
166
Figure 5
Hydrograph and Constituents of Concern Versus Time - MW-02
Fall 2023 Semiannual Water Quality Monitoring Report
Jackson County Closed Municipal Solid Waste Landifll

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Notes:
1. Dashed horizontal lines represent the 2L groundwater standard.
2. Dashed vertical lines represent the start of leachate extraction.
3. Non -detects are plotted as an open symbol at the method detection limit.
4. Data presented are from semiannual sampling events from 2007 to Fall 2023.
µg/L: micrograms per liter
ft: feet
Publish Date: 02/22/2024 10:16 AM I User: SAR-SCOL
File Path: \\Wcl-fs1\asheville\Projects\Jackson County\02-Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py
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2009
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1991
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Date
Constituent Key with 2L Standards
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Trichloroethene (TCE) (3 µg/L)
cis-1,2-Dichloroethene (70 µg/L)
f Vinyl Chloride (0.03 µg/L)
f Benzene (1 µg/L)
f 1,4-Dichlorobenzene (6 µg/L)
1,4-Dioxane (3 µg/L)
Groundwater Elevation (ft)
-- Leachate Extraction Start Date
Figure 6
Hydrograph and Constituents of Concern Versus Time - MW-03
Fall 2023 Semiannual Water Quality Monitoring Report
Jackson County Closed Municipal Solid Waste Landifll

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Date Date Date
Benzene 1,4-Dichlorobenzene 1,4-Dioxane
Notes:
1. Dashed horizontal lines represent the 2L groundwater standard.
2. Dashed vertical lines represent the start of leachate extraction.
3. Non -detects are plotted as an open symbol at the method detection limit.
4. Data presented are from semiannual sampling events from 2007 to Fall 2023.
µg/L: micrograms per liter
ft: feet
Publish Date: 02/22/2024 10:16 AM I User: SAR-SCOL
File Path: \\Wcl-fs1\asheville\Projects\Jackson County\02-Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py
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Constituent Key with 2L Standards
f Tetrachloroethene (PCE) (0.70 µg/L)
Trichloroethene (TCE) (3 µg/L)
cis-1,2-Dichloroethene (70 µg/L)
f Vinyl Chloride (0.03 µg/L)
f Benzene (1 µg/L)
f 1,4-Dichlorobenzene (6 µg/L)
1,4-Dioxane (3 µg/L)
— Groundwater Elevation (ft)
-- Leachate Extraction Start Date
Figure 8
Hydrograph and Constituents of Concern Versus Time - MW-05R
Fall 2023 Semiannual Water Quality Monitoring Report
Jackson County Closed Municipal Solid Waste Landifll

Tetrachloroethene (PCE) Trichloroethene (TCE)
5
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Benzene 1,4-Dichlorobenzene 1,4-Dioxane
Notes:
1. Dashed horizontal lines represent the 2L groundwater standard.
2. Dashed vertical lines represent the start of leachate extraction.
3. Non -detects are plotted as an open symbol at the method detection limit.
4. Data presented are from semiannual sampling events from 2007 to Fall 2023.
µg/L: micrograms per liter
ft: feet
Publish Date: 02/22/2024 10:16 AM I User: SAR-SCOL
File Path: \\Wcl-fs1\asheville\Projects\Jackson County\02-Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py
kZANCHOR
QEA
Vinyl Chloride
1958
1956
C
0
1954
C
0
1952 (D
--------------------
1950
Q�1,3 S\Q- CNN '\102�1O2�2�2�22262I,
Date
Constituent Key with 2L Standards
f Tetrachloroethene (PCE) (0.70 µg/L)
Trichloroethene (TCE) (3 µg/L)
cis-1,2-Dichloroethene (70 µg/L)
f Vinyl Chloride (0.03 µg/L)
f Benzene (1 µg/L)
f 1,4-Dichlorobenzene (6 µg/L)
1,4-Dioxane (3 µg/L)
Groundwater Elevation (ft)
-- Leachate Extraction Start Date
Figure 7
Hydrograph and Constituents of Concern Versus Time - MW-04
Fall 2023 Semiannual Water Quality Monitoring Report
Jackson County Closed Municipal Solid Waste Landifll

5
4
�3
c
O
M
0
14
12
10
c
O 8
M
4
2
0
Tetrachloroethene (PCE)
I
I
I
I
I
I
I
I
1
1
I
1
I
1
I
- ---------------------
I
I
$
Date
Date
Benzene
Notes:
1. Dashed horizontal lines represent the 2L groundwater standard.
2. Dashed vertical lines represent the start of leachate extraction.
3. Non -detects are plotted as an open symbol at the method detection limit.
4. Data presented are from semiannual sampling events from 2007 to Fall 2023.
µg/L: micrograms per liter
ft: feet
2066
WOM
2062
2060
c
0
2058
2056 "'
iv
2054
2052
O
2050 0
2048
2046
Trichloroethene (TCE)
6
I
I
5
J 4
>s
1
0
Date
2066
20.0
2064
17.5
2062
15.0
2060
J
o
12.5
2058
o
2056 w
�
10.0
iv
2054
U
7.5
2052 0
v
2050 �9
5.0
2048
2.5
2046
0.0
Publish Date: 02/22/2024 10:16 AM I User: SAR-SCOL
File Path: \\Wcl-fs1\asheville\Projects\Jackson County\02-Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py
kZANCHOR
QEA
2Q00231I3 \Ik161$�112'31, QR�
Date
1,4-Dichlorobenzene
2066
102
2064
2062
2060
J
101
o
2058 M
0
°—
2056 LU
2054
100
-6
2052 0
V
c
0
2050
2048
10-1
2046
cis-1,2-Dichloroethene
------------------
1
I
1
1
1
I
1
1
1
1
1
1
1
1
1
1
1
1
1
2066
,
2064
20.0
2062
17.5
'
1
2060
15.0
o
2058
a',
c
12.5
2056
10.0
2054 3
1
2052 0
0
7.5
2050
5.0
2048
2.5
-- ---- -
2046
0.0
Date
1,4-Dioxane
2066
101
2064
2062
Y
2060
J
o
2058 >
10°
C
°—
2056 '
2054
2052 0
U
C
v
2050
10-1
2048
2046
64
62
60
58
56
54
52
O
50
48
46
Vinyl Chloride
I
I
I
I
I
I
I
- ---------------------------
I
2Q000 2p'5) 012262I,
Date
Constituent Key with 2L Standards
f Tetrachloroethene (PCE) (0.70 µg/L)
Trichloroethene (TCE) (3 µg/L)
cis-1,2-Dichloroethene (70 µg/L)
f Vinyl Chloride (0.03 µg/L)
f Benzene (1 µg/L)
f 1,4-Dichlorobenzene (6 µg/L)
1,4-Dioxane (3 µg/L)
Groundwater Elevation (ft)
-- Leachate Extraction Start Date
2066
2064
2062
Y
2060
0
2058 0
Q)
2056
2054
2052 0
2050
2048
2046
Figure 9
Hydrograph and Constituents of Concern Versus Time - MW-06
Fall 2023 Semiannual Water Quality Monitoring Report
Jackson County Closed Municipal Solid Waste Landifll

Tetrachloroethene (PCE)
5
4
�3
c
O
M
c
2
c
O
U
1
1954
1952 0
w
1950 C
O
0 1 '" ME"' — µ 1948
$
Date
14
12
10
c
O 8
M
c
6
c
O
U
4
2
0
LD
Trichloroethene (TCE)
6
5
J 4
c
O
3
c
v
o 2
U
1
0
1954
20.0
17.5
15.0
1952
0
.2
0)
12.5
w
o
�
10.0
1950
u
o
7.5
O
U
5.0
2.5
1948
0.0
102
1952 0
1
10
2
w
0
0
1-2
3
100
1950 �
o
O
U
6
10-1
1948
Date
1954
20.0
17.5
1952
0
15.0
>
c
12.5
w
.0
10.0
3
v
1950
0
7.5
O
U
5.0
2.5
1948
0.0
cis-1,2-Dichloroethene
1954
10,
1952 0
>
100
w
C
O
U
1950 c:
u
o
O
U
0
10-1
1� µ 1948
Date
N,0 "00��11) 200 162�1$2�2�2�222�2� 2��$2�1�2�122�1�2�1�2�1�2�2�2�222�2�
Date Date Date
Benzene 1,4-Dichlorobenzene 1,4-Dioxane
Notes:
1. Dashed horizontal lines represent the 2L groundwater standard.
2. Dashed vertical lines represent the start of leachate extraction.
3. Non -detects are plotted as an open symbol at the method detection limit.
4. Data presented are from semiannual sampling events from 2007 to Fall 2023.
µg/L: micrograms per liter
ft: feet
Publish Date: 02/22/2024 10:16 AM I User: SAR-SCOL
File Path: \\Wcl-fs1\asheville\Projects\Jackson County\02-Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py
kZANCHOR
QEA
w
1950 ("
IM
1948
Vinyl Chloride
1954
1952 0
w
1950 C
O
1948
�)162Ci1co,�)xl)
Date
Constituent Key with 2L Standards
f Tetrachloroethene (PCE) (0.70 µg/L)
Trichloroethene (TCE) (3 µg/L)
cis-1,2-Dichloroethene (70 µg/L)
f Vinyl Chloride (0.03 µg/L)
f Benzene (1 µg/L)
f 1,4-Dichlorobenzene (6 µg/L)
1,4-Dioxane (3 µg/L)
Groundwater Elevation (ft)
-- Leachate Extraction Start Date
Figure 10
Hydrograph and Constituents of Concern Versus Time - MW-07
Fall 2023 Semiannual Water Quality Monitoring Report
Jackson County Closed Municipal Solid Waste Landifll

Appendix A
Well Sampling Logs, and Equipment
Documentation and Instrument
Calibration Data Sheets

li,zANCHOR
IDEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Eaui .,ment Documentation and Instrument Calibration Data Sheet
Project Name: -SQc %n n C&&h}e} Cac" kYIY qpJ Wok Analyst Conducting Calibration: orl
Project Number: C%%41b0 ^ O.k Oi _ Date of Calibration: 10141 Z,023
Project Location: ���10 t G Date of Field Measurements: 1 0/q 12,023
Facility ID or Permit # (if applicable):2-
EQUIPMENT DOCUMENTATION
Rental sample analysis equipment or meters used to take measurements:
Equipment Type
Brand
Serial Number
I Date of Use
I Rental Compa
i Orr 10 301:1-4
1 1014 ! 3
Select Turbidimeter.
Hach 2100Q (s/n 1 S1006045207)
Rental Hach 21GDQ (s/n
Instrument Readings
(Hach 2100Q)
Cal Std Information
10 NTU
20 NTU
100 NTU
800 NTU
Lot #..
f -62.y d
ft I z 7.3
q:b
3
Expiration Date:
t i
L
1
Cal (NTU):20
O
Cal (NTU):
Cal (NTU):
Time: D -�Ob
Time:6
Time:
Calibration
Verification•_
*Pre -Analysis
Check (10 NTU):
Result (NTU):
dt • 4i
Time:
01-2101
*Post -Analysis
Check (10 NTU):
Result (NTU):
�O • 0
Time:
7-03
YSI Professional Plus Multiparameter Meter OAP488404804
Instrument Readings
Cal Std Information
Lot #
Date
Opened
Exp. Date
Dissolved Oxygen
(% saturation)
Initial (%):
E 1 s n 2
Cal (%):
l D m
mmHg:
Temperature CQ:
23 .*L
Time:
U i S
DO (Site #2,
ifapplicable)*
Initial (%):
Cal (%):
mmHg:
Temperature CC):
Time:
QC** Check: DO
Time:
0(057-
Result (k :
q•D
Time:
0015123)
Result (%):
Time:
Result (%):
PH 7 S.U.
report to 0.1 S. U.
Initial:
5
pHmV:
— 10 • 5
Cal (S..U.):
-r • Ip I
pHmV:
r
— (� ' 10
Time:
0 -F o l
1
D l x!2.52.
'j,(A�•
10
pH 4 S.U.
re
porttoO.IS.U.
Initial:
L{. 0
pHmV:
L S Ct
Cal (S.U.):
14-(P
pHmV:
0 -c7
Time:
0�0
K
05rZ
�l 2
PH 10 S.U.
report to 0.1 S. U.
Initial:
to . p
pHmV:
^ ti
Cal (S.U.):
t (rA : m k
pHmV:
- l
Time:
l l7
m
-0
651zs
QC** PH 7 S.U.
repoit to 0.1 S. U.
Time: �1
0 �1 �.
Result (S.U.):
Time: r-
Z. o � 10
Result (S.U.): G
• O ; 7
Time:
Result (S.U.):
rr
IN
2
6--Q
-74
Spec. Cord.
1,000 pmhos/cm
Initial:
918
Cal (Nmhos/cm):
4 oo
Time::
0054
3�tv
L®Q
a
fJ J L5
ID317,
% Recove =
QC** Spec Cond.
1,000 mhos/cm
Time:
o-4 Z-
Result (Nmhos/cm):
2..
Time:
7-031
Result (Nmhos/cm):
Time:
Result (umhos/cm):
16ily
1I o 11-3
% Recovery-
2D0
ORP mV
Initial:
j6
Cal:
�7-0©
Temperature CC):
LZ.•
Time:
�1
O' �4-
/[•
44 .
4
Foi��r7
I
0�-1
Analyst Signature:N"Wla,Analyst Name: 5�� (n0.y� Date: V010'QU2,3
Notes:
Revision 8, 1/11122, CAP U
1. Instruments shall be calibrated in accordance with the manufacturers operation manual.
2. Specific Conductivity should be calibrated according to values representative of historic range.
3. Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 10, DO, OAP, QC checks.
4. *When performing DO analyses at multiple sample sites (.e. project/facility locations), the DO probe must be
calibrated at each sample site prior to analysis.
S. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10%of the true value. If QC readings are out
of range, the instrument needs to be recalibrated.
6. " QC check must be performed prior to sampling and following completion of sampling, at a minimum. QC
checks must be performed with calibration standard from a separate lot* as the initial QC.
7. % Recovery = (Value Obtained, pmhos/cm a Tiue Value, pmhos/cm) x 100
8. NC Field Laboratory Certificate Number 544S -
9. Documentation errors are to be crossedout with a single line, so the original text is still legible, followed by
the staff members initials and date
10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity.
11. 1 pmho/cm = 1 pS/cm
Abbreviations:
Method Reference.
pmhos/cm: micromhos per centimeter NTU: nephelomet6c turbidity units
Temperature: SM 2SS0 B-2010
'C degrees Celsius ORP: oxidation reduction potential
Specific conductivity. EPA Method 120.1, Rev. 1982
DO: dissolved oxygen s/n: serial number
DO: SM 4S00 0 G-2016
mg/L: milligrams per liter S.U.: standard units
pH: SM 4500-H' B-2011
mV: millivolt Spec Cond: Specific Conductivity
Turbidity. SM 2130 B-2011
Page 1 of 1

ANCHOR
kA IDEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Equipment Documentation and Instrument Calibration Data Sheet
Project Name: J&f_k4o V1 Ces.tx�'!-N_ <By j 0_hvu4AXl )NM. Analyst Conducting Calibration:
Project Number: G mil' 4t�b —OI • C ♦ Date of Calibration: 0 1 5 t
Project Location: 1\S� �, NC, Date of Field Measurements:
Facility ID or Permit # (if applicable): So - O7-
EQUIPMENT DOCUMENTATION
Rental sample analysis equipment or meters used to take measurements:
E ui ment Type
Brand
I Serial Number
I Date of Use Rental Company
e rnI
I Ix 10.49 44
1 imillL Gnv
Select Turbidlmeter. Hach 2100Q (s/n 151006045207)
Rental Hach 2100Q (s/n _
YSI Professional Plus Multiparameter Meter43Aii469484BG3)-
Cal Std Information
Instrument Readings
Date
Lot #
Opened
Exp. Date
Dissolved Oxygen
Initial (%):
95.5
Cal (%):
1 O
mmHg:
Temperature CQ
22
Time:
t 0ZLf
(% saturation)
o
-I
.
DO (Site #2,
Initial (%):
Cal (%):
mmHg:
Temperature CQ:
Time:
if a livable
QC" Check DO
Time:, r
V
Result I%: ,^
Time:
Result (%):
Time:
Result (%):
PH 7 S.U.
Initial:
pHmV:
Cal (S.U.):
pHmV:
Time:
2(�t
report to 0.1 S.U.
4.0
- It •(c
- • 0
— 1(• 5
0 cj
U7,
0'M5
t02.4
PH 4 S.U.
Initial:
pHmV:
Cal (S.U.):
pHmV:
Time:
f1
report to0.)SU.
of
S '. ,
fl
GE-5
Of I
05 23
t� 3
PH 10 S.U.
Initial:
pHmV:
Ca�ll (SSy.U.):
pHmV:
Time:
2
Jm`
report to0.1S.U.
2
-V- .5
tV •ol
— +3
�"
09123
0-6115
QC" pH 7 S.U.
Time:
W.
Result S.U.):
Time: C
Result (S.U.):
Time:
Result (S.U.):
3 (�
re ortto0.1S.U.
-
'02)1
US113
25
Spec. Cond.
Initial:
Cal (ymhos/cm):
Time:
1,000 umhos/cm
•�
10 0 T
1000
D (0 5 B
12
17-4.
% Recovery=
QC** Spec. Cond.
Time:
Result (pmmhos/cm):
Time:
Result (pmhos/cm):
Time:
Result (pmhos/cm):
'LC%1-S
1,000 mhos/cm
p
V 1
l V S
�(C
L� L �7
OL
% Recovery=
ORP 200 mV
Initial:
Cal:
'2 �%�
Temperature CC):
Time: �' }
b'
.�-
v'ERa
Analyst Signature: tt,L� Analyst Name: �2551C0.1'Vliulv�r� Date: In1rnrl�hs�
Notes: I
Revision B, 1/11122, CAP
1. Instruments shall becalibrated in accordance with the manufacturer's operation manual.
2. Specific Conductivity should be calibrated according to values representative of historic range.
3. Order of Calibration is as follows : Speck Conductivity, pH 7, pH 4, pH 1Q DO, ORP, QC checks.
4. When performing DO analyses at multiple sample sites (.e. project/facility locations), the DO probe must be calibrated at each sample site prior to analysis.
5. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated.
6... QC check must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be performed with calibration standard from a separate lot # as the initial QC.
7. % Recovery = (Value Obtained, pmhos/cm +True Value, pmhos/cm) x 100
B. NC Field Laboratory Certificate Number S44S
9. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity.
11. 1 pmho/cm = 1 pS/cm
Abbreviations: Method Reference:
pmhos/cm: micromhos per centimeter NTU: nephelometric turbidity units Temperature: SM 2SS0 B-2010
•C: degrees Celsius ORP: oxidation reduction potential Specific conductivity. EPA Method 120.1, Rev. 1982
DO: dissolved oxygen s/n: serial number DO: SM 4S00 0 G-2016
mg/L: milligrams per liter S.U.: standard units pH: SM 450D-H` B-2011
mV: millivolt Spec. Cond.: Speck Conductivity Turbidity. SM 2130 B-2011
Page 1 of 1

ZANCHOR
w QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Equipment Documentation and Instrument Calibration Data Sheet
ProjectName:lc_CV,100 (CLIAky- SeMJcLy1VLU,i it(Q Analyst Conducting Calibration: ,
Project Number. C& s fee-0%, 0% 0 Date of Calibration: 10 J(j V ko-43
Project Location: 1C)( \k&tcorC r fit- Date of Field Measurements: � Ot Doi t 1.a7S
Facility ID or Permit # (if applicable): - cn_
EQUIPMENT DOCUMENTATION
Rental sample analysis equipment or meters usea to take measurements:
Equipment T pe Brand Serial Number Date of Use Rental Company
Select Turbidimeter.
Hach 2100Q (s/n 15100604S207)
Rental Hach 2100Q (s/n _
Instrument Readings
(Hach 2100Q)
Cal Std Information
10 NTU
20 NTU
100 NTU
800 NTU
Lot #.-
Ab2.qo
RW
2tft
Expiration Date:
l
[( 4
Cal (NTU): 20
0
Cal (NTU):
Cal (NTU):
Time 0 t
Time:
tv
Time:Time: © Z-6
Calibration
Verification:
'Pre -Analysis
Check (10 NTU):
Result (NTU):
a . -L,+
Time:
V 25
F
1*
Check (101ysis NTU):
Rest�t�TU)O'
LL
Time A10�-
YSI Professional Plus Multiparameter
Meter (s/n 186101802)
Instrument Readings
Cal Std Information
Lot #
Date
Exp. Date
Dissolved Oxygen
(% saturation)
Initial I
01y+•el—
Cal (%):
100
mmHg:
14Pt•
Temperature (°C):
I
Time:
o643
DO (Site #2,
if a livable "
Initial (%):
Cal (%):
mmHg:
Temperature (°C):
Time:
QC** Check DO
Time:
111111
Result (%):
106
Time:
Result (%):
Time:
Result (%):
PH 7 S.U.
report to0.1SU.
Initial:
•
pHmV:
"
Cal (S.U.):
�
pHmV: C
—%-J
Time:
I
?-
ZQ
0 (
)O �f
PH4S.U.
report to 0.1 S.U.
Initial:
4 • OC)
pHmV:
Cal (S.U.):
4 -O
pHmV:
Time:
1 Ct
1tl11�
PH 10 S.U.
report to 0.1 SU.
Initial: � _
/rW
-t • dt
'- ZpHmV•?
Zt • 8
Cal (S.U.):
W) •
pHmV:
- 222 •
Time:n
(9(.g2.q
$�`
mo
0
QC"" pH 7 S.U.
ortto0.1SU.
Time.
�� J�
Result (S.U.):
't l`�
Time: p
l 4t
Result (S.U.):
l�-Q5
Time:
Result (S.U.):
ml4QAft
lCaC-
OR1153
Spec. Cond.
1,000 mhos/cm
Initial:
rr�+
1VO
Cal (Umhos/cm):
1006
Time
ti
Wl
4& C.
{mqW
04ft3
M1
% Recovery=
QC"" Spec. Cond.
1,000 mhos/cm
Time:
t7 `D� y
Result (Umhos/cm):
to 43
Time:
Result (Umhos/cm):
tot,-'
Time:
Result (Umhos/cm):
ZGj'T
ita�D
�5fZ3
t0
% Recove =
ORP z�mv
Initial:
Cal:
ZOC)
Temperature CC):
1 �J
Time:
NO&
ejbts
10,lcii
7_25
I MIZA
Analyst Signature: Analyst Name: Co` Date: 0 0 q
Notes
Revision B, 1/11/22, CAP
1. Instruments shall be calibrated in accordance with the manufacturer's operation manual.
2. Specific Conductivity should be calibrated according to values representative of historic range.
3. Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, PH 10, DO, ORP, QC checks.
4. *When performing DO analyses at multiple sample sites (i.e. project/facility locations), the DO probe must be calibrated at
each sample site prior to analysis.
S. QC Acceptable Ranges: PH +/- 0.1 S.U. and Specific Conductivity 10%of the true value. If QC readings are out of range, the instrument needs to be recalibrated.
6... QC check must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be performed with calibration standard from a separate lot # as the initial QC.
7. % Recovery = (Value Obtained, pmhos/cm - True Value, pmhos/cm) x 100
B. NC Field Laboratory Certificate Number 544S
9. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity.
11. 1 pmho/cm = 1 PS/cm
Abbreviations:
Method Reference:
pmhos/cm: micromhos per centimeter NTU: nephelometric turbidity units
Temperature: SM 2SSO B-2010
'C: degrees Celsius ORP: oxidation reduction potential
Specific conductivity: EPA Method 120.1, Rev. 1982
DO: dissolved oxygen s/m serial number
DO: SM 4S00 O G-2016
mg/L: milligrams per liter S.U.: standard units
pH: SM 4500-H' B-2011
mv: millivolt Spec Cond.: Specific Conductivity
Turbidity. SM 2130 B-2011
Page 1 of 1

kzANCHOR.
QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
q-
n
01
Equipment Diocumentation and Instru nt Calibration Data Sheet
Project Name: � f�44 Analyst Conducting Calibration: 7�
O ,
Project Number: (°3t 4to ^ L-A , O 1 Date of Calibration: / f[
Project Location: 1C�i j tkS%1nyU . MC_ Date of Field Measurements: 10/ ((!
Facility ID or Permit # (if applicable): 1597102
EQUIPMENT DOCUMENTATION
Rental sample analysis equipment or meters used to take measurements:
Equipment Type
Brand
Serial Number Date of Use
Rental Company
i
l
I I
i
Select Turbidimeter.
Hach 21000 (s/n 1S1006045207)
Rental Hach 21000. (S/n
Instrument Readings
(Hach 21000)
Cal Still Information
10 NTU
20 NTU
100 NTU
800 NTU
Lot #:
Wbi-1 t o
W 32Z'�a
� � '�-
ft32+eo
Expiration Date:
Cal (NIU
Cal (NT:
Cal (NTU)' /
TimeO? sue^
JJ
T� , 36
Time: -7r 7
Calibration
Verification:
'Pre -Analysis
Check (10 NTU):
Result (NTU):
, , D
Time'.
6 • ��
-Post-Analysis
Check (10 NTU):
Result (NTU):
��• 10
Time: �/
-7 . ti3
YSI Professional Plus Multiparameter Meter (s/n 188101802)
Instrument Readings
Cal Std Information
Lot #
Date
O coed
Exp. Date
Dissolved Oxygen
(% saturation)
Initial (%):
6(7� • q
Cal (%):
to'I
mmHg:
a e. 1
Temperature (°q:
11. y
Time:
Oct s
DO (Site #2,
if applicable)'
Initial (%):
Cal (%):
mmHg:
Temperature (°C):
Time:
QC.* Check: DO
Tim
Result
Time:
Result (%):
Time:
Result M:
PH 7 S.U.
report to0.1S.U.
Initial:
6.9
pHmV:
Cal (S.U.):
% Q�
pHmV:
f _'L
Time:
71
7 ek-Y
'2A2-
� �-t
,IZ3
10-J38—
pH 4 S.U.
report to0.1S.U,
Initial: 7
.6-A
pHmV:
( .
]
CaIsIS�.U.):
K0�
pHmV:
G
Time:
ll�: �
ICi1 K
61�
I�512_'3
N %3
PH 10 S.U.
report to 0.1 SU.
Ini/ti/a�l:�
! �/ • ©
pHmV:n^
�� #•L /s �
Cal ( U,):
'D�
pHmV: /1�
, 2-2 . `1
Time: �7Q
7, L-(
Qjdl�
m
r '1Z3
b3yop� S
QC** pH 7 S.U.
report to 0.1 S. U.
r, �y
`� ` (
Result Is.
Trig '
Resul (S.0 y
r r
Time:
II =i
Result (S.U.):
3C!%G
9) �
/
081 Z3
0 3L% 5
Spec. Cord.
1.000 mhos/cm
Initial:
la 1l
Cal (pmhos/cm):
� noo
Time:
1317;10
f
5& L
101R
07,Il
6512,4
% Recove -
QC" Spec. Cond.
1,000 mhos/cm
Time:
d-7'
Result (w In s/cm):
/
T'i' e: �%
• ` O
Result (/p'mhh�os/cm):
w
Time:
Result (pmhos/cm):
N'$�
�lcj
OS%[.�
t,�l q
"15
% Recovery-
j
ORP 200 mV
Initial:
I?
Cal:
D
Temperature (°C):
aQ• 0
Time:
07= s
$(�sE
ICA 23
0 17A
/
Analyst Signature: i ..�/C Analyst Name: I r a Date: 10
Notes: U Y r
Revision 6, 1/11122, CAP
1. Instruments shall be calibrated in accordance with the manufacturer's operation manual.
2. Specific Conductivity should be calibrated according to values representative of historic range.
3. Order of Calibration is as follows: Specff c Conductivity, pH 7, pH 4, pH 10, DO, ORP, QC checks.
4. -When performing DO analyses at multiple sample sites (Le. project/facility locations), the DO probe must be calibrated at each sample site prior to analysis.
S. QC Acceptable Ranges: pH +/- 01 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated.
6. •• QC check must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be performed with calibration standard from a separate lot a as the initial QC.
7. %Recovery = (Value Obtained, pmhos/cm + True Value, pmhos/cm) x 100
S. NC Field Laboratory Certificate Number 5445
9. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity.
11. 1 pmho/cm = 1 VS/cm
Abbreviations: Method Reference:
pmhos/cm: micromhos per centimeter NTU: nephelometric turbidity units Temperature: SM 2550 B-2010
-C degrees Celsius ORP: oxidation reduction potential Specific conductivity. EPA Method 120.1, Rev. 1982
DO: dissolved oxygen Vn: serial number DO: SM 4500 O G-2016
mg/L: milligrams per liter S.U.: standard units pH: SM 4500-H• 8-2011
mV: millivolt Spec. Cond.: Specific Conductivity Turbidity. SM 2130 B-2011
Page 1 of 1

ANCHOR
QEA At: 4.w"
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Well Sampling Log
[Me —HIM MU) —©
Project Name: 3ecC-V_.S©L\ �u�n t noaa$ WCV Date: 1p�13 ­ t0lb,5f2l
Project Number. C '� 14'a0 -- W . O1 Weather.
Project Location: D A«S%rol NG Facility ID or Permit # (if applicable): SO-OZ
Sample Collector(s): _ tJ A IM A Sample ID (on CDC): M\,V . Ot- 2.023 IDS
Well Diameter. ' Z in Sample Time: ' 35
Screen Interval: N + ft bgs
Measuring Point: 70C Well Depth (WD): f �, s ft TOC
Well Type: p3tick Up ❑Flush Mount Water Level in Feet (WL): / OS, ft TOC
Comments: an -"'Pe oL1 Wf ejl r2a.CO 4o We f J Length of Water Column (LWQ: 15, r ft; (WD - WL)
/� ����CLI�p j (•� One Casing Volume: _ (� (p gallons; (LWC x WCV)
101O$I Z0Z3 Three Casing Volumes: gallons
il L Si- 1— f �p , 5 1�u��5 Actual Volume Purged: �® �' _gallons
} F `""
Vol. Purged:
Tagged Bottom: ILZ , 8 ft at (time): L33
Well Casing Volumes (WCV)
1" = 0.04 Gal/Ft 2" = 0.16 Gal/Ft 3" = 0.37 Gal/Ft 4" = 0.65 Gal/Ft 6" = 1.47 Gal/Ft 8" = 2.61 Gal/Ft 12" = 5.87 Gal/Ft
Purge Method: Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other.
Sample Method: Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other.
Oxidation
Dissolved
Specific
pH (S.U.)
Reduction
Gallons
Temperature
Oxygen
Conductivity
report to 0.1
Potential
Turbidity
Reading
Time
Purged
VQ
(mg/L)
(pmhos/cm)
S.U.
(m1)
(NTU)
Comments
1
Vi
2
5
3, 5 7
3
%
o
4
3
—
(�3
s •
l��
5
�.
i Z..
Zp
.Ff
6
2
7
8
9
10
Sampling Container Number of Containers Requested Analysis
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 mL Glass
1 L Glass
Other
Protective Casing: Pad:= Lock: Vegetation: J Access: ter'
ampe
Sample Analysts Signature: Analysts ►�,,�
S1�Co M Date: �D� �S�Zt�23
_ Name:
Notes:
1: Stabilization (3 successive readings, 3 mi utes apart): within +/- 70% DO and turbidity,* +/- 3% Conductivity,, +/- 0.7 pH unit +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 544S
Abbreviations:
"C: degrees Celsius
pmhos/cm: micromhos per centimeter
mg/L: milligrams per liter
mV: millivolt
NTU: nephelometric turbidity units
S.U.: standard units
ft: feet
in: inches
bgs: below ground surface
TOC: top of casing
Method Reference:
Temperature: SM 2SS0 B-2010
Specific conductivity: EPA Method 120.1, Rev.1982
DO: SM 4500 O G-2011
pH: SM 4500-H' B-2011
Turbidity: SM 2130 B-2011
K, X I Page 1 of 1

ANCHOR
V, QEA
Well Sampling Log
Well ID: MW
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name:7&Ckfi0V% (MAft\'% SeAniannual W ®
Date:
`01 5[L--:,,
Project Number: C!JV50 . C7I , o 1
Weather.
= 2 C0
Project Location: Q �(�`0�70 r 14C Facility ID
or Permit # (if applicable):
Sample Collector(s): m "rfV\
Sample ID (on COQ:
��� 5 �- 2,07_�j 143O'S
Well Diameter. Z in
Sample Time:
Screen Interval: N ! _ ft bgs
1
Measuring Point: 1 G
Well Depth (WD):
ft TOC
Well Type: Stick Up oFlush Mount
Water Level in Feet (WL):
L43s_ (a ft TOC
Comments: CbYYC� �i �Jj b 14V Vp �pZ ( L XA Length of Water Column (LWC):
1 Ir . O (0 ft; (WD - WL)
V J OAO t�i 11,q5 C nt i (2-a)
One Casing Volume:
2_ =t 3 gallons; (LWC x WCV)
to/ d 5 PLS :
Three Casing Volumes:
_ I gallons
% GIs
Actual Volume Purged:
$ 8 gallons
Vol. Purged: _, (>(
L
Three Eesin�-Vckimes=—�
t3a14a..
10I1��
Tagged Bottom: .0b ft at (time): I C) 13
l o` p4 IZoZ3
3 7� N 5 � ft z �j f .4 S yai
Well Casing Volumes (WCV)
1" = 0.04 Gal/Ft 2" = 0.16 Gal/Ft 3" = 0.37 Gal/Ft 4" = 0.65 Gal/Ft 6" = 1.47 Gal/Ft B" = 2.61 Gal/Ft 12" = 5.87 Gal/Ft
Purge Method:
Sample Method:
Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos
Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos
Other:
Other:
Reading
Time
Gallons
Purged
Temperature
VQ
&" `
Dissolved
Oxygen
(mg/L)
Specific
Conductivity
(pmhos/cm)
pH (S.U.)
report to 0.1
S.U.
Oxidation
Reduction
Potential
Turbidity
(NTU)
Comments
J
ff(m1)
2
3
4
5
6
7
8
9
10
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 mL Glass
1 L Glass
Other
Protective Casing: Pad: Lock: Vegetation:
Access:
Sample Analysts Signature:
Analysts --[(�
Name: plebs\ CA
Date: 10)051.2'e,
Notes: ( -
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity: +/- A Conductivity; +/- a i pH unit' +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 544S
Abbreviations:
Method Reference:
°C: degrees Celsius S.U.: standard units
Temperature: SM 2SS0 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev.1982
mg/L: milligrams per liter in: inches
DO: SM 4S00 0 G-2011
mV: millivolt bgs: below ground surface
pH: SM 4S00-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity: SM 2130 B-2011
Page 1 of 1

ANCHOR
QEA c
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Low -Flow Sampling Log
Well—im mW—
r
Project Name.. 4 sof\ (,Out�tJ►—�Pylr� 0.vt tn.a
Project Number. C�s1�kt30- Ot,b1
Project Location: D, tt5boye i N G
Sample Collector(s): V rl M f T"APf
Well Diameter. 'L
Screen Interval: 1,�1a , a5 w' �3 • 5
Well Depth (as constructed): V [
Depth to Water: 5� -43
Measuring Point: V L
\
Depth of Pump Intake: ��` 5 S
Pump Used (circle): Peristaltic Bladder
Comments: pt�y�., .".. /.� , ((]
� c, 1 to
n t �/l� �Q Date:
Weather. 55"t Sun tit o,.,e cA_qdr
Facility ID or Permit # (if applicable): ` 0-02
Sample ID (on CDC): mW—(3'�, 2.07.,3 10 11
in Arrive at Well: 0" C)
ft bgs StartTime: 1 t o
ft bgs Sample Time:
ft Leave Well:
Well Type: ktick Up ❑Flush Mount
ft Tagged Bottom: ft at (time): 0963
Other (describe): Purge Rate:
iyt:r 1 �Xi � ' tL ICA_ ( (tM p , b i Total Volume Purged:
mtt (OGt W t t tV ti1V�^r 117 Pump Speed: �rJ
Time
DTW (feet)
Temperature ('Q
Dissolved Oxygen
(mg/L)
Specific
Conductivity
(Nmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity (NTU)
Flow Rate (ml./min)
I10
51 •51f
VS
2-Q2
253•L�
5•`-t-
ZOO-B
5•2.
2tv
ttZ
O
ItS•
2• (v
25 •3
t•Ot
If—
t 5
__ p
1 •�-
2.5
2 5-•.
5.3 q
22. .5
e; .44
115
t
5
2.53
I •Z
-40
•o
3.15
1
5
6
(
S--tI
5
.o
d
24
IS
2•
2
5•
25
?
--
!L
3
! .1
2 •q 8
2 . 5
52
f A. 16
1 .-+2
Z.to
Sample Analyst Signature:
Sample Analyst
Name. Cat
Date:
t�l tt
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity, +/- 3%Conductivity, +/- 0.1 pH unit,' +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff nember's initials and date
3. Samples are analyzed immediately upon collection.
A NC Field Laboratory Certificate Number 5445
S. 1 pmho/cm = 1 pS/cm
Abbreviations:
•C: degrees Celsius S.U.: standard units
pmhos/cm: micromhos per centimeter ft feet
mg/L milligrams per liter in: inches
mv: millivolt bgs: below ground surface
NTU: nephelometric turbidity units TOC: top of casing
r'. to F ' 3}
Method Reference:
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev. 1982
DO: SM 4500 O G-2016
pH: SM 4500-H' B-2011
Turbidity: SM 2130 B-2011
Page 1 of 1

ANCHOR
;QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Low -Flow Sampling Log
Well ID:
Project Name:',3ftGKOVCoc�wan n,sA` A� Date: i �^ 7
Project Number. Weather: 1. •,•=a
Project Location: '� t,'c� �p �G Facility ID or Permit # (if applicable):
Sample Collector(s).—Is1R-rn , —Moe Sample ID (on COC): mW _ 04
Well Diameter: 2 in Arrive at Well: t4110
Screen Interval: _ Z 5 ^ 4p ft bgs Start Time: t O�
Well Depth (as constructed): ) ft bgs Sample Time: t S
Depth to Water: -19 -" _ ft Leave Well:
Measuring Point: 1'>c Well Type: 6Qick Up ❑flush Mount
Depth of Pump Intake: _ 235— ft Tagged Bottom: `L , L� ft at (time):
Pump Used (circle): Peristaltic Bladder Other (describe): Purge Rate:
Comments: f��c CNN P (5 o D (- 13 �Q•n�' Fo s}a(•f- Total Volume Purged: z
t'/n� 1 S � Pump Speed:
LJ b
Time
DTW (feet)
Temperature (°C)
Dissolved Oxygen
(mg/L)
Specific
Conductivity
(pmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity (NTU)
Flow Rate (mL/min)
lS a
.551
j, . 2
2,
o 5
S•8
11 I>
ito
t 50 01
s
I
• t
-fi5
411 - (0
(0 -(e (
tL 0
115
21R •5
t5-
t
S. f. 9
14a}•5
0.5
110
(a o
IS-5
5•
o
O
--
1
7- 6, 6a
L S--+
S.(,Q
2• 5
0.2:;-
►ZS
f
S
5-
a---
0.2
(2-
52
a
2.
t • Zo
- S
5Z2 •
•2
—
5Z-+'
2,8 0
:� 2
is')
51-7•1
0•t
25
S
2 o
t S
C5
423.2
--
2 R. to 0
5.5
2-(OR
5•-+2-
1 2
2
L2r5
5
Z
- 5
. (g
2
5. 2
5 o .3
IsI
Z.5
Sample Analyst Signature:
Sample Analyst
Name:
:Scssic&„
Date:
t0jol1202,3
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity, +/- 3% Conductivity, +/- 0.1 pH unit +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff member's initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number S445
S. 1 pmho/cm = 1 pS/cm
Abbreviations:
"C: degrees Celsius
S.U.: standard units
pmhos/cm: micromhos per centimeter
ft feet
mg/L: milligrams per liter
in: inches
mv: millivolt
bgs: below ground surface
NTU: nephelometric turbidity units
TOC: top of casing
Method Reference:
Temperature: SM 2550 B-2010
Specific conductivity. EPA Method 120.1, Rev. 1982
DO: SM 4500 O G-2016
PH: SM 4500-H` B-2011
Turbidity. SM 2130 B-2011
Page 1 of 1

ANCHOR
QEA `
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Well Sampling Log
Well ID:
jj_
-a-,Project
Name: • A[l'r�tnlaA
p�
M" V"W( C, Date:
10 7"�12
i`
Project Number: CIS — 01,01
Weather.
+ l';�lll�h_t r��
Project Location: W �Lra r KG
Facility ID or Permit # (if applicable):
u0 OZ,
Sample Collector(s): -I'Vyy) PC
Sample ID (on COC):
Well Diameter. ''
in Sample Time:
Screen Interval:
ft bgs
Measuring Point: TUC
Well Depth (WD):
'
ft TOC
Well Type: <Stick Up ❑Flush Mount
Water Level in Feet (WL):
5A� �
ft TOC
Comments: S5 1 l no of
Length of Water Column (LWQ:
'Z , �j3
ft; (WD - WL)
One Casing Volume:
LW cj
gallons; (LWC x WCV)
Three Casing Volumes:
_ , , 21
gallons
Actual Volume Purged:
_Z - 23
gallons
Vol. Purged:,y
Three Casing Volumes:
_
gallons
Tagged Bottom: Cr�r_ri ft at (time):
��—
Well Casing Volumes (WCV)
1" = 0.04 Gal/Ft 2" = 0.16 Gal/Ft 3" = 0.37 Gal/Ft 4" = 0.65 Gal/Ft 6" = 1.47 Gal/Ft
8" = 2.61 Gal/Ft 12" = 5.87 Gal/Ft
Purge Method: Bailer-Disp.` . Bailer -Teflon
Dedicated Pump Whale Pump Grundfos
Other.
Sample Method: Bailer-Disp. Bailer -Teflon
Dedicated Pump Whale Pump Grundfos
Other.
Oxidation
Dissolved
Specific
pH (S.U.)
Reduction
Gallons
Temperature
Oxygen
Conductivity
report to 0.1
Potential
Turbidity
Reading
Time
Purged
VQ
(rri
(pmhos/cm)
S.U.
(m1)
(NTU)
Comments
1
�3
2.2
��-O
. 55
a0
. 12_
— ► . `t
S[ • S
2
3
4
5
6
7
8
9
10
Sampling Container
Number of Containers Requested Analysis
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 mL Glass
1 L Glass
Other
Protective Casing: Pad: Lock: Vegetation: Access:
Sample
Sample Analysts Signature:
Analysts
Name: co,,'Date:
IQ�0I
NEW
_-Qss1
Notes: I I
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity; +/- 3% Conductivity; +/- 0.7 pH unit; +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
Abbreviations:
'C: degrees Celsius
pmhos/cm: micromhos per centimeter
mg/L: milligrams per liter
mV: millivolt
NTU: nephelometric turbidity units
Method Reference:
S,U.: standard units Temperature: SM 2550 B-2010
ft: feet Specific conductivity: EPA Method 120.1, Rev. 1982
in: inches DO: SM 4500 0 G-2011
bgs: below ground surface pH: SM 4500-H' B-2011
TOO top of casing Turbidity: SM 2130 B-2011
1► t•
,�r� l� '� Page 1 of 1

Anchor QEA of North Carolina, PLLC
ANCHOR
QEA
231 Haywood Street
Asheville, North Carolina 28801
_ Low -Flow Sampling Log
Well ID: rY1 W — cs"fo
Project Name-
Project Number.
Project Location:
Sample Collector(s):
Well Diameter:
Screen Interval:
Well Depth (as constructed):
Depth to Water:
Measuring Point:
Depth of Pump Intake:
Pump Used (circle):
Comments:
, t$bV\ (MMA7a.N S118 dLy%ytNW Date: `b/0 51 23 i
L%,% 4'8 V � O 1 Weather. 'I �5 11 z 5r.thn`� C la��
Z)%' tX%4gow, Facility ID or Permit # (if applicable): SID — O Z. _
_+(Y) r�'r S Sample ID (on COC):�—b(o ►��( p_p S7
in Arrive at Well: i i Lf S
�jLt. ft bgs Start Time: S 3
Cl i.. f ft bgs Sample Time:
c)�ft Leave Well: (U
_TuCo Well Type: yitick Up ❑Flush Mount
Cl I ft Tagged Bottom: �� _ (/) ft at (time):
Peristaltic Bladder Other (describe): —'-~F- — Purge Rate:
v L.km 9 a Y, Total Volume Purged:
C tQlA3 1 3j Pump Speed: p 2-5
Time
DTW (feet)
Temperature ("C)
Dissolved Oxygen
(mg/L)
Specific
Conductivity
(pmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity (NTU)
Flow Rate (mL/min)
S
a '
1?,-0
S, Lt
6-25
'2- 26. 3
(D-4 3,
1 J
E; 0
D
N
u 1
2- • 2-
{ '. { V
lJ
.1�
Sample Analyst Signature:
Sample Analyst
Name: �e ;
Date:
io 10 s j'Z�l
Notes: r r
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity; +/- 3% Conductivity, +/- 0.1 pH unit +/- 70 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff member's initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445'
S. 1 pmho/cm = 1 pS/cm
Abbreviations: Method Reference:
°C: degrees Celsius S.U.: standard units Temperature: SM 2SSO B-2010
pmhos/cm: micromhos per centimeter ft: feet Specific conductivity: EPA Method 120.1, Rev. 19B2
mg/L: milligrams per liter in: inches DO: SM 4SOO O G-2016
mv: millivolt bgs: below ground surface pH: SM 4S00-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing Turbidity. SM 2130 B-2011
Page 1 of 1

ANCHOR
..�, QEA'
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
`\
Low -Flow Sampling Log
well ID:
Project Name:7ALVS,-r%
(bu
4!A, � Qrih
e�� G1_
Date:
' "-,kd J
Project Number:
CW, M0 - d,
Weather.
L
Project Location:';
rrs� I
Facility ID or Permit # (if applicable):
(� �••
Sample Collector(s):
"vorvV%-q pl(�
Sample ID (on COC):
MW — 0--l- 2-0 7-3 y 3 l0o
Well Diameter:
Z
in
Arrive at Well:
0Cl/ i I ID
Screen Interval:
—ci�c
ft bgs
Start Time:
Well Depth (as constructed):
ft bgs
Sample Time:
(.3
Depth to Water:
? •
it
Leave Well:
Measuring Point:
;
L',
Well Type: uQStick Up
❑Flush Mount
Depth of Pump Intake:
ft
Tagged Bottom:
ri , . l ft
at (time):
c11
t V• �J ,
Pump Used (circle):
_
Peristaltic
ladder
Other (describe):
Purge Rate:
Comments:
.,n f
0
• J
� 11 •(s J [! � tr b4
9J
Total Volume Purged:
Pump Speed:
rU
'D 7 (
^
1 i 5
Specific
Oxidation
Dissolved Oxygen
Conductivity
pH (S.U.)
Reduction
Time
DTW (feet)
Temperature (•C)
(mg/L)
(Nmhos/cm)
report to 0.1 S.U.
Potential (mV)
Turbidity (NTU)
Flow Rate (mL/min)
IL-1 . 1
01. Ott
3
9.00
12 O.
4-
10 q CQ
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. $
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00 • t
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I
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ty �-
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4.10
Sample A Signature:
Name:
��Estrye ri
Date:
1O o`lFZ613.
Notes: I i
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity, +/- 3% Conductivity,, +/- 0.1 pH unit +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures,
April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original
text is still legible, followed by the staff member's initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm = 1 p5/cm
Abbreviations:
Method Reference:
•C: degrees Celsius S.U.: standard units
Temperature: 5M 2550 8-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L milligrams per liter in: inches
DO: SM 4S00 0 G-2016
mV: millivolt bgs: below ground surface
pH: SM 4S00-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity. SM 2130 B-2011
So, ►+� �Le, � I h o-E �i l I.CdI FO r -ham." b i vt �¢.v�,e, Co ' 20 i 1. 7-0)
a4 " .,if
,'L`i
1 of IL

ANCHOR
QEA
Low -Flow Samalina Loa
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Well ID: iY1 W- n
Project Name: 'f0LLI(So _
r•,s-1
��
Date:
tolO9i7"3
Project Number:
CSti+W C)t,0
Weather:
(¢ la , '.".y,t'I
c,j � ( (�'aS
tS
Project Location:
1tStDoro �L
Facility ID or Permit # (if applicable):
50- OZ
Sample Collector(s):
Sample ID (on COQ:
M W _ 0—+- IC>11 p6 ol
Well Diameter.
in
Arrive at Well:
t7 9, Lt5
Screen Interval:
— 5
ft bgs
Start Time:
It (P
Well Depth (as constructed):
9 C,
ft bgs
Sample Time:
t"b
Depth to Water.
•�Z, dt L
ft
Leave Well:
Measuring Point:
"k—bG
Well Type:
a6tick Up
❑Flush Mount
Depth of Pump Intake:
156
ft
Tagged Bottom:
ft
at (time):
Pump Used (circle):
Peristaltic
ladde
Other (describe):
Purge Rate:
Comments:
Total Volume Purged:
Pump Speed:
!�
Specific
Oxidation
Dissolved Oxygen
Conductivity
pH (S.U.)
Reduction
Time
DTW (feet)
Temperature
CQ
(mg/L)
(pmhos/cm)
report to 0.1 S.U.
Potential (m1)
Turbidity (NTU)
12z-1
S
1`i•13
D -cig
Sig
'338
32•
l•2.1
t 7- '+
3Ifs
C
i
5.99
Z. k
1. t1
►7
3• 3
Iy-
d
l 9
5•11
'Z(o•Z
C
14-16
0•qo
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1;
-5-4.
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t 2 aq
31-15.
14
0•92
S 1-0
15 q8
—60- 13
t•5
1 2
3
t
0.90
Q2o
5.9,$
-SZ-4
t -e
4S
33 3�-
14-9
0
Zv
5•'I
- -8
1-0
14.S
o• g 5
$ q 8
i. V6
2
-1,5
IL-t- 8
0• 1
Sig
s•98
-
0
L 5'1
3 '3 -38
140
3
w
1
1,01
m 5
3
t.k•--+
o f
6 LO
S q
-TA-
.q
00
1-,,3. b 3
1
► 4 --+
0- c14
s2o
S aI
`n. S
i• 3
c:a o
33.35
I
A ` -
b , 01 S
161
1 -
- 'L q 5
t -tics
Sample Analyst
Sample Analyst Signature:
Name:
�L�
Date:
Notes: U
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity +/- 3% Conductivity,, +/- 0.1 pH unit +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number S44S
S. 1 pmho/cm = 1 PS/cm
Abbreviations:
Method Reference:
°C: degrees Celsius S.U.: standard units
Temperature: SM 2SS0 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter in: inches
DO: SM 4S00 0 G-2016
mv: millivolt bgs: below ground surface
pH: SM 4S00-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity. SM 2130 B-2011
©q� �� ck�k stoti:<<K. she(s a 1 hV
us
)JO
Ntoi
to,
Ito
Page Zof t

ANCHOR
QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Surface Water Sampling Log
Location ID:.S'w 0 1
Project Name:
S�aMianInUA,X
W C)
Date: 101 pq I ?.023
Project Number:
c%%iug0-pt. 01
Weather: ^oo- suLyn f t i 'U-J"
Project Location:
1C) i11S106b t *4C,
Facility ID or Permit # (if applicable): 5 p -62.
Sample Collector(s):
TA TIMA
Sample ID (on COQ Svc .- p
Comments:
Sample Method (circle
rab Syringe
Pump
Bailer-Disp. Other:
one):
Specific
Oxidation
Temperature
Dissolved
Conductivity
pH (S.U.)
Reduction
Turbidity
Time
VC)
Oxygen (mg/L)
(pmhos/cm)
report to 0.7 S.U.
Potential (mV)
(NTU)
Comments
��.30
21,6
S.,5q
39.0
8026
139a6
�,SS
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 mL Glass
1 L Glass
-T -
—
Other
Vegetation:
Sample Analyst Signature:
Sample Analyst
Name:GSs� r
Access: ��
Date: IL-qe4
1. Documentation errors are to be crossed out with a sinale line. so the oriainal text is still legible, followed by the staff members initials and date
2. Samples are analyzed immediately upon collection.
3. NC Field Laboratory Certificate Number 5445
Abbreviations:
Method Reference:
°C: degrees Celsius
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter
DO: SM 4500 0 G-2011
mv: millivolt
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units
Turbiditv: SM 2130 B-2011
S.U.: standard units
Page 1 of 1

ANCHOR
.-v QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Surface Water Sampling Log
Location ID:
Project Name—Sa(_k$,,, COS c Sew%%aLykk&"4
Date:
Project Number: C%��- a�, of
Weather: W,6vrr<I�- w1:LL0&.,W
Project Location: 1Di11S1�cVo f3G _
Facility ID or Permit # (if applicable): 50'-02
Sample Collector(s): J/j2f "�
Sample ID (on COC):
Comments:
Sample Method (circle
one):gra Syringe
Pump
Bailer-Disp. Other:
Specific
Oxidation
Temperature
Dissolved
Conductivity
pH (S.U.)
Reduction
Turbidity
Time
CC)
Oxygen (mg/L)
(pmhos/cm)
report to 0.1 S.U.
Potential (mV)
(NTU)
Comments
93, a
02.9 9
Sampling Container Number of Containers
Requested Analysis
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 mL Glass
1 L Glass
Other
Vegetation: cN Access:
Sample Analyst
Sample Analyst Signature: Name: '�-eSS1 G0. Date:
1. Documentation errors are to be crossed out with a sinale line, so the orioinal text is still legible, followed by the staff members initials and date
2. Samples are analyzed immediately upon collection.
3. NC Field Laboratory Certificate Number 5445
Abbreviations:
°C: degrees Celsius
pmhos/cm: micromhos per centimeter
mg/L: milligrams per liter
mv: millivolt
NTU: nephelometric turbidity units
S.U.: standard units
Method Reference:
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev. 1982
DO: SM 4500 O G-2011
pH: SM 4500-H' B-2011
Turbiditv: 5M 2130 B-2011
Page 1 of 1

Anchor QEA of North Carolina, PLLC
4-0 ANCHOR
QEA
231 Haywood Street
Asheville, North Carolina 28801
Surface Water Sampling Log
Location ID:
Project Name( y-,, ��
� Q_--�4y�Nun1
Nh _
Date:
ibt Vi
Project Number: C%%Jta() t)(•
0.X
Weather:
5Wnw"
Project Location: Z) I�6h
NC C. _
Facility ID or Permit # (if applicable):
150- C>7
Sample Collector(s): -AIRSample
ID (on COC):
5VQ� (U
Comments:
Sample Method (circle
one)
Syringe
Pump
Bailer-Disp.
Other:
Specific
Oxidation
Temperature
Dissolved
Conductivity
pH (S.U.)
Reduction
Turbidity
Time
VC)
Oxygen (mg/L)
(pmhos/cm)
report to 0.1 S.U.
Potential (mom
(NTU)
Comments
►50
�.�.�
8�9��°�A
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 mL Glass
1 L Glass
Other
Vegetation:
Sample Analyst Signature:
Sample Analyst
Name. �PSSt Ca
Access:
Date: , f oq
1. Documentation errors are to be crossed out with a sinale line, so the oriainal text is still leaible. followed by the staff members initials and date
2. Samples are analyzed immediately upon collection.
3. NC Field Laboratory Certificate Number 5445
Abbreviations:
Method Reference:
°C: degrees Celsius
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter
DO: SM 4500 O G-2011
mv: millivolt
pH: 5M 4500-H' B-2011
NTU: nephelometric turbidity units
Turbidity: SM 2130 B-2011
5.U.: standard units
Page 1 of 1

ANCHOR
V, QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Surface Water Sampling Log
Location ID: I-T- O (
Project Name:--S�',its, Lo il rl+VU'v k--) '*3 Q
Date: Lf [ ZC�3
Project Number:
G314rB0_ DI , 0%
'DZUipo
Weather:
Project Location:
a"
N&T.,
Facility ID or Permit # (if applicable): ro()_yZ
SampleCollector(s):
(I�Yy1 � �(/�/1
Sample ID (on COC): L_-T.-C)r -
Comments:
Sample Method (circle
one):
Syringe
Pump
Bailer-Disp. Other:
Specific
Oxidation
Temperature
Dissolved
Conductivity
pH (S.U.)
Reduction
Turbidity
Time
(IC)
Oxygen (mg/L)
(pmhos/cm)
report to 0.1 S.U.
Potential (mV)
(NTU)
Comments
y52a
303
z. C'S
511s 5
Z
405
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 mL Glass
1 L Glass
Other
Vegetation: ,noYN-� Access:
Sample Analyst Signature:
Sample Analyst
Name:
Date: tolo4lu,22
1. Documentation errors are to be crossed out with a sinole line. so the orioinal text is still leoible, followed by the staff members initials and date
2. Samples are analyzed immediately upon collection.
3. NC Field Laboratory Certificate Number 5445
Abbreviations:
Method Reference:
"C: degrees Celsius
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter
Specific conductivity. EPA Method 120.1, Rev. 1982
mg/L milligrams per liter
DO: SM 4500 0 G-2011
mv: millivolt
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units
Turbiditv: SM 2130 B-2011
S.U.: standard units
Page 1 of 1

ANCHOR
QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Surface Water Sampling Log
Location ID: W— O
Project Name:-1
C'kSn (,,, w m Scmakayii."I
ka C4)
Date: Lai It 123
Project Numbera-6;SQ_ 0` . OS
Weather:Cie cw
OL-Qw
Project Location:
�1 il:�dN �L
Facility ID or Permit # (if applicable): 1>0 02_
Sample Collector(s):
r -h,� F ��
T
Sample ID (on COC): V *'I— O 1 J -y" tp-t J
Comments:
Sample Method (circle
one)
Grab Syringe
Pump
Bailer-Disp. Other:
Specific
Oxidation
Temperature
Dissolved
Conductivity
pH (S.U.)
Reduction
Turbidity
Time
CQ
Oxygen (mg/L)
(pmhos/cm)
reportto 0.7 S.U.
Potential (mV)
(NTU)
Comments
�r.sv
Aso. G
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 mL Glass
1 L Glass
Other
Vegetation:
Access: V2 [, 0'"
Sample Analyst
Sample Analyst Signature: Name: �S Date
_ OIL,
Notes:
I. uocumentation errors are to oe crossea out witn a shale line, so the onainal text Is stin Zeal Die, ronowea Dv the sTaTr memUers Initials ana adte
2. Samples are analyzed immediately upon collection.
3. NC Field Laboratory Certificate Number 5445
Abbreviations:
Method Reference:
'C: degrees Celsius
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter
Specific conductivity. EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter
DO: SM 4500 0 G-2011
mv: millivolt
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units
Turbiditv: SM 2130 B-2011
S.U.: standard units
Page 1 of 1

0.15
ANCHOR
L� QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Surface Water Sampling Log
Location ID: W-02—
Project Name:
CA� QyvuOL>nv►MAk
W Q
Date: 10/1r 10
Project Number:
C31`te)o " 01. 0 1
Weather: (00, owccg�t';S-
Project Location:
D IISip t4G
Facility ID or Permit # (if applicable): 50. 02 _
Sample Collector(s):
OAMr i"�
I i
Sample ID (on COQ PW'OZ - Zo 7-3to 1 f
Comments:
Sample Method (circle
Grab Syringe
Pump
Bailer-Disp. Other:
one)
Specific
Oxidation
Temperature
Dissolved
Conductivity
pH (S.U.)
Reduction
Turbidity
Time
VC)
Oxygen (mg/L)
(pmhos/cm)
report to & I S.U.
Potential (mV)
(NTU)
Comments
3
6'
17- Z
6 T,
.s7.3
t 31
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 mL Glass
3
rr�.
-at . 2-
1 L Glass
Other
Vegetation: N Access: N f ty� 0/.) pd
Sample Analyst
Sample Analyst Signature: Name: Sew Date- ICI �� f zoz3
Notes:
1. Documentation errors are to be crossed out with a sinole line, so the orioinal text is still leoible, followed by the staff members initials and date
2. Samples are analyzed immediately upon collection.
3. NC Field Laboratory Certificate Number 5445
Abbreviations:
Method Reference:
°C: degrees Celsius
Temperature: 5M 2550 B-2010
pmhos/cm: micromhos per centimeter
5pecific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter
DO: SM 4500 O G-2011
mv: millivolt
pH: 5M 4500-H' B-2011
NTU: nephelometric turbidity units
Turbiditv: SM 2130 B-2011
S.U.: standard units
Page 1 of 1

Appendix B
Reports of Laboratory Analysis,
Chain -of -Custody Documentation,
and Certificates of Analysis

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
February 23, 2024
Jessica Mayers
Anchor QEA
231 Haywood Street
Asheville, NC 28801
RE: Project: Jackson County Fall 2023
Pace Project No.: 92691921
Dear Jessica Mayers:
Enclosed are the analytical results for sample(s) received by the laboratory between October 05, 2023 and October 12,
2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable
TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the
report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Ormond Beach
A revised report is being submitted on 2/23/24 to report a revised metals list for 92691921-001.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
W0.''� ,
Angela Baioni
[e-mail]
612-473-6801
Project Manager
Enclosures
cc: Jessica Mayers, Anchor QEA
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 229

�ce
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Alaska DEC- CS/UST/LUST
Alabama Certification #: 41320
California Certification# 3096
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
DoD-ANAB MADE-3199
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maine Certification #: FL01264
Maryland Certification: #346
Massachusetts Certification #: M-FL1264
Michigan Certification #: 9911
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
New Hampshire Certification #: 2958
New Jersey Certification #: FL022
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Ohio DEP 87780
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 229

SAMPLE SUMMARY
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92691921001
LT-01-20231004
Water
10/04/2315:20
10/05/23 09:04
92691921002
SW-01-20231004
Water
10/04/23 18:30
10/05/23 09:04
92691921003
SW-02-20231004
Water
10/04/23 16:25
10/05/23 09:04
92691921004
SW-03-20231004
Water
10/04/23 17:50
10/05/23 09:04
92691921005
TB-20231004
Water
10/04/23 00:00
10/05/23 09:04
92691980001
MW-06-20231005
Water
10/05/2315:42
10/06/23 11:51
92691980002
MW-01-20231005
Water
10/05/2313:56
10/06/23 11:51
92691980003
MW-02-20231005
Water
10/05/2311:55
10/06/23 11:51
92691980004
DUP-20231005
Water
10/05/23 09:36
10/06/23 11:51
92691980005
TB-20231005
Water
10/05/23 00:00
10/06/23 11:51
92692397001
MW-04-20231009
Water
10/09/2315:36
10/10/2311:08
92692397002
MW-05R-20231009
Water
10/09/2317:38
10/10/2311:08
92692397003
MW-07-20231009
Water
10/09/2313:03
10/10/2311:08
92692397004
TB-20231009
Water
10/09/23 00:00
10/10/2311:08
92691921015
MW-03-20231011
Water
10/11/2311:27
10/12/2316:45
92691921016
DW-01-20231011
Water
10/11/2314:10
10/12/2316:45
92691921017
DW-02-20231011
Water
10/11/2314:55
10/12/2316:45
92691921018
TB-20231011
Water
10/11/23 00:00
10/12/23 16:45
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 3 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Jackson County Fall 2023
92691921
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92691921001
LT-01-20231004
EPA6020B
CRW, KRL
16
PASI-A
EPA 7470A
BM
1
PASI-A
EPA 8270E
PKS
111
PASI-C
EPA 8260D
LMB
63
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
92691921002
SW-01-20231004
EPA6020B
CRW
16
PASI-A
EPA 7470A
BM
1
PASI-A
EPA 8270E
PKS
111
PASI-C
EPA 8260D
LMB
63
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
SM 4500-S2D-2011
JP1
1
PASI-A
92691921003
SW-02-20231004
EPA 6020E
CRW
16
PASI-A
EPA 7470A
BM
1
PASI-A
EPA 8270E
PKS
111
PASI-C
EPA 8260D
LMB
63
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
SM 4500-S2D-2011
JP1
1
PASI-A
92691921004
SW-03-20231004
EPA 6020E
CRW
16
PASI-A
EPA 7470A
BM
1
PASI-A
EPA 8270E
PKS
111
PASI-C
EPA 8260D
LMB
63
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
SM 4500-S2D-2011
JP1
1
PASI-A
92691921005
TB-20231004
EPA 8260D
LMB
63
PASI-C
92691980001
MW-06-20231005
RSK 175 Modified
TEG
3
PASI-C
EPA 6020E
CRW, KRL
16
PASI-A
EPA 7470A
BM
1
PASI-A
EPA 8270E
PKS
111
PASI-C
EPA 8260D
TMH
63
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 3500-Fe D#4
KDF1
1
PASI-A
SM 3500-Fe B-2011
JMH1
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
SM 5210B-2011
MDM
1
PASI-A
SM 5220D-2011
JP1
1
PASI-A
SM 5310B-2014
MJP
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Project:
Jackson County Fall 2023
Pace Project No.:
92691921
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
EPA 9056A
CDC
3
PASI-A
92691980002
MW-01-20231005
RSK 175 Modified
TEG
3
PASI-C
EPA 6020E
CRW, KRL
16
PASI-A
EPA 7470A
BM
1
PASI-A
EPA 8270E
PKS
111
PASI-C
EPA 8260D
JJK
63
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 3500-Fe D#4
KDF1
1
PASI-A
SM 3500-Fe B-2011
JMH1
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
SM 5210B-2011
MDM
1
PASI-A
SM 5220D-2011
JP1
1
PASI-A
SM 5310B-2014
MJP
1
PASI-A
EPA 9056A
CDC
3
PASI-A
92691980003
MW-02-20231005
RSK 175 Modified
TEG
3
PASI-C
EPA 6020E
CRW, KRL
16
PASI-A
EPA 7470A
BM
1
PASI-A
EPA 8270E
PKS
111
PASI-C
EPA 8260D
JJK
63
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 3500-Fe D#4
KDF1
1
PASI-A
SM 3500-Fe B-2011
JMH1
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
SM 5210B-2011
MDM
1
PASI-A
SM 5220D-2011
JP1
1
PASI-A
SM 5310B-2014
MJP
1
PASI-A
EPA 9056A
CDC
3
PASI-A
92691980004
DUP-20231005
RSK 175 Modified
TEG
3
PASI-C
EPA 6020E
CRW, KRL
16
PASI-A
EPA 7470A
BM
1
PASI-A
EPA 8270E
PKS
111
PASI-C
EPA 8260D
JJK
63
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 3500-Fe D#4
KDF1
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 229

SAMPLE ANALYTE COUNT
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
SM 3500-Fe B-2011
JMH1
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
SM 521OB-2011
MDM
1
PASI-A
SM 5220D-2011
JP1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
EPA 9056A
CDC
3
PASI-A
92691980005
TB-20231005
EPA 8260D
LMB
63
PASI-C
92692397001
MW-04-20231009
RSK 175 Modified
TEG
3
PASI-C
EPA 6020E
KRL
16
PASI-A
EPA 7470A
BM
1
PASI-A
EPA 8270E
PKS
111
PASI-C
EPA 8260D
TMH
63
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 3500-Fe D#4
KDF1
1
PASI-A
SM 3500-Fe B-2011
JMH1
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
SM 521OB-2011
KO
1
PASI-A
SM 5220D-2011
JP1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
EPA 9056A
JCM
3
PASI-A
92692397002
MW-05R-20231009
RSK 175 Modified
TEG
3
PASI-C
EPA 6020E
CRW, KRL
16
PASI-A
EPA 7470A
BM
1
PASI-A
EPA 8270E
PKS
111
PASI-C
EPA 8260D
TMH
63
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 3500-Fe D#4
KDF1
1
PASI-A
SM 3500-Fe B-2011
JMH1
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
SM 521OB-2011
KO
1
PASI-A
SM 5220D-2011
JP1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
EPA 9056A
JCM
3
PASI-A
92692397003
MW-07-20231009
RSK 175 Modified
TEG
3
PASI-C
EPA 6020E
CRW, KRL
16
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 6 of 229

SAMPLE ANALYTE COUNT
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
EPA 7470A
BM
1
PASI-A
EPA 8270E
PKS
111
PASI-C
EPA 8260D
TMH
63
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 3500-Fe D#4
KDF1
1
PASI-A
SM 3500-Fe B-2011
JMH1
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
SM 521OB-2011
KO
1
PASI-A
SM 5220D-2011
JP1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
EPA 9056A
JCM
3
PASI-A
92692397004
TB-20231009
EPA 8260D
TMH
63
PASI-C
92691921015
MW-03-20231011
EPA 6020E
KRL
16
PASI-A
EPA 7470A
BM
1
PASI-A
EPA 8270E
PKS
111
PASI-C
EPA 8260D
SAS
63
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 3500-Fe D#4
KDF1
1
PASI-A
SM 3500-Fe B-2011
JMH1
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
SM 521OB-2016
MDM
1
PASI-A
SM 5220D-2011
JP1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
EPA 9056A
CDC
3
PASI-A
92691921016
DW-01-20231011
EPA524.2
CLT
24
PASI-O
92691921017
DW-02-20231011
EPA 524.2
CLT
24
PASI-O
92691921018
TB-20231011
EPA 8260D
LMB
63
PASI-C
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-O = Pace Analytical Services - Ormond Beach
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: LT-01-20231004 Lab ID: 92691921001 Collected: 10/04/23 15:20 Received: 10/05/23 09:04 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
1.6J
ug/L
5.0
1.0
5
10/15/23 13:35
10/17/23 04:36
7440-36-0
M1
Arsenic
148
ug/L
5.0
0.43
5
10/15/23 13:35
10/17/23 04:36
7440-38-2
M1
Barium
13600
ug/L
100
21.4
100
10/15/23 13:35
10/17/2314:07
7440-39-3
M1
Beryllium
3.0
ug/L
0.50
0.25
5
10/15/23 13:35
10/17/23 04:36
7440-41-7
Cadmium
0.46J
ug/L
1.0
0.30
5
10/15/23 13:35
10/17/23 04:36
7440-43-9
Chromium
1120
ug/L
10.0
5.0
10
10/15/23 13:35
10/17/2314:02
7440-47-3
M1
Cobalt
68.2
ug/L
5.0
0.25
5
10/15/23 13:35
10/17/23 04:36
7440-48-4
M1
Copper
155
ug/L
10.0
5.7
5
10/15/23 13:35
10/17/23 04:36
7440-50-8
M1
Lead
45.9
ug/L
5.0
0.38
5
10/15/23 13:35
10/17/23 04:36
7439-92-1
M1
Nickel
171
ug/L
5.0
2.1
5
10/15/23 13:35
10/17/23 04:36
7440-02-0
M1
Selenium
2.OJ
ug/L
10.0
0.36
5
10/15/23 13:35
10/17/23 04:36
7782-49-2
Silver
<0.35
ug/L
2.0
0.35
5
10/15/23 13:35
10/17/23 04:36
7440-22-4
D3
Thallium
0.69J
ug/L
1.0
0.25
5
10/15/23 13:35
10/17/23 04:36
7440-28-0
Tin
26.0
ug/L
5.0
2.1
5
10/15/23 13:35
10/17/23 04:36
7440-31-5
M1
Hardness, Total(SM 2340B)
892000
ug/L
27000
27000
50
10/10/23 15:20
10/12/23 01:16
Vanadium
304
ug/L
10.0
2.5
10
10/15/23 13:35
10/17/2314:02
7440-62-2
M1
7470 Mercury
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services
-Asheville
Mercury
<0.12
ug/L
0.20
0.12
1
10/13/2315:08
10/14/2311:27
7439-97-6
8270E APP9 RV
Analytical Method: EPA 8270E Preparation
Method: EPA 3510C
Pace Analytical Services - Charlotte
Acenaphthene
<2.0
ug/L
10.0
2.0
1
10/09/23 06:26
10/09/23 23:15
83-32-9
Acenaphthylene
<2.0
ug/L
10.0
2.0
1
10/09/23 06:26
10/09/23 23:15
208-96-8
Acetophenone
<1.5
ug/L
10.0
1.5
1
10/09/23 06:26
10/09/23 23:15
98-86-2
2-Acetylaminofluorene
<4.1
ug/L
10.0
4.1
1
10/09/23 06:26
10/09/23 23:15
53-96-3
4-Aminobiphenyl
<4.7
ug/L
10.0
4.7
1
10/09/23 06:26
10/09/23 23:15
92-67-1
Anthracene
<2.3
ug/L
10.0
2.3
1
10/09/23 06:26
10/09/23 23:15
120-12-7
Benzo(a)anthracene
<2.7
ug/L
10.0
2.7
1
10/09/23 06:26
10/09/23 23:15
56-55-3
Benzo(a)pyrene
<2.8
ug/L
10.0
2.8
1
10/09/23 06:26
10/09/23 23:15
50-32-8
Benzo(b)fluoranthene
<2.6
ug/L
10.0
2.6
1
10/09/23 06:26
10/09/23 23:15
205-99-2
Benzo(g,h,i)perylene
<2.8
ug/L
10.0
2.8
1
10/09/23 06:26
10/09/23 23:15
191-24-2
Benzo(k)fluoranthene
<2.7
ug/L
10.0
2.7
1
10/09/23 06:26
10/09/23 23:15
207-08-9
Benzyl alcohol
<2.9
ug/L
20.0
2.9
1
10/09/23 06:26
10/09/23 23:15
100-51-6
4-Bromophenylphenyl ether
<1.8
ug/L
10.0
1.8
1
10/09/23 06:26
10/09/23 23:15
101-55-3
Butylbenzylphthalate
<3.1
ug/L
10.0
3.1
1
10/09/23 06:26
10/09/23 23:15
85-68-7
4-Chloro-3-methyl phenol
<3.3
ug/L
10.0
3.3
1
10/09/23 06:26
10/09/23 23:15
59-50-7
4-Chloroaniline
<3.6
ug/L
20.0
3.6
1
10/09/23 06:26
10/09/23 23:15
106-47-8
Chlorobenzilate
<3.8
ug/L
10.0
3.8
1
10/09/23 06:26
10/09/23 23:15
510-15-6
bis(2-Chloroethoxy)methane
<1.8
ug/L
10.0
1.8
1
10/09/23 06:26
10/09/23 23:15
111-91-1
bis(2-Chloroethyl) ether
<1.9
ug/L
10.0
1.9
1
10/09/23 06:26
10/09/23 23:15
111-44-4
2-Chloronaphthalene
<1.7
ug/L
10.0
1.7
1
10/09/23 06:26
10/09/23 23:15
91-58-7
2-Chlorophenol
<1.2
ug/L
10.0
1.2
1
10/09/23 06:26
10/09/23 23:15
95-57-8
4-Chlorophenylphenyl ether
<2.0
ug/L
10.0
2.0
1
10/09/23 06:26
10/09/23 23:15
7005-72-3
REPORT OF
LABORATORY
ANALYSIS
This report shall not be reproduced, except in
full,
Date: 02/23/2024 01:48 PM
without the written consent of Pace Analytical Services, LLC.
Page 8 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: LT-01-20231004 Lab ID: 92691921001 Collected: 10/04/23 15:20 Received: 10/05/23 09:04 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Chrysene
<2.8
ug/L
10.0
2.8
1
10/09/23 06:26
10/09/23 23:15
218-01-9
Diallate
<3.4
ug/L
10.0
3.4
1
10/09/23 06:26
10/09/23 23:15
2303-16-4
Dibenz(a,h)anthracene
<3.0
ug/L
10.0
3.0
1
10/09/23 06:26
10/09/23 23:15
53-70-3
Dibenzofuran
<2.1
ug/L
10.0
2.1
1
10/09/23 06:26
10/09/23 23:15
132-64-9
3,3'-Dichlorobenzidine
<8.1
ug/L
20.0
8.1
1
10/09/23 06:26
10/09/23 23:15
91-94-1
2,4-Dichlorophenol
<1.4
ug/L
10.0
1.4
1
10/09/23 06:26
10/09/23 23:15
120-83-2
2,6-Dichlorophenol
<4.2
ug/L
10.0
4.2
1
10/09/23 06:26
10/09/23 23:15
87-65-0
Diethylphthalate
<2.0
ug/L
10.0
2.0
1
10/09/23 06:26
10/09/23 23:15
84-66-2
Dimethoate
<3.7
ug/L
10.0
3.7
1
10/09/23 06:26
10/09/23 23:15
60-51-5
P-Dimethylaminoazobenzene
<2.4
ug/L
5.0
2.4
1
10/09/23 06:26
10/09/23 23:15
60-11-7
7,12-Dimethylbenz(a)anthracene
<3.0
ug/L
10.0
3.0
1
10/09/23 06:26
10/09/23 23:15
57-97-6
3,3'-Dimethylbenzidine
<31.1
ug/L
50.0
31.1
1
10/09/23 06:26
10/09/23 23:15
119-93-7
2,4-Dimethylphenol
<1.7
ug/L
10.0
1.7
1
10/09/23 06:26
10/09/23 23:15
105-67-9
Dimethylphthalate
<2.1
ug/L
10.0
2.1
1
10/09/23 06:26
10/09/23 23:15
131-11-3
Di-n-butylphthalate
<2.2
ug/L
10.0
2.2
1
10/09/23 06:26
10/09/23 23:15
84-74-2
4,6-Dinitro-2-methyl phenol
<7.8
ug/L
20.0
7.8
1
10/09/23 06:26
10/09/23 23:15
534-52-1
1,3-Dinitrobenzene
<3.8
ug/L
10.0
3.8
1
10/09/23 06:26
10/09/23 23:15
99-65-0
2,4-Dinitrophenol
<26.0
ug/L
50.0
26.0
1
10/09/23 06:26
10/09/23 23:15
51-28-5
2,4-Dinitrotoluene
<1.6
ug/L
10.0
1.6
1
10/09/23 06:26
10/09/23 23:15
121-14-2
2,6-Dinitrotoluene
<1.7
ug/L
10.0
1.7
1
10/09/23 06:26
10/09/23 23:15
606-20-2
Di-n-octylphthalate
<3.9
ug/L
10.0
3.9
1
10/09/23 06:26
10/09/23 23:15
117-84-0
Diphenylamine
<3.0
ug/L
10.0
3.0
1
10/09/23 06:26
10/09/23 23:15
122-39-4
Disulfoton
<4.6
ug/L
10.0
4.6
1
10/09/23 06:26
10/09/23 23:15
298-04-4
bis(2- Ethyl hexyl)phthalate
<3.7
ug/L
6.0
3.7
1
10/09/23 06:26
10/09/23 23:15
117-81-7
Ethyl methanesulfonate
<3.0
ug/L
20.0
3.0
1
10/09/23 06:26
10/09/23 23:15
62-50-0
Famphur
<6.1
ug/L
10.0
6.1
1
10/09/23 06:26
10/09/23 23:15
52-85-7
Fluoranthene
<2.2
ug/L
10.0
2.2
1
10/09/23 06:26
10/09/23 23:15
206-44-0
Fluorene
<2.1
ug/L
10.0
2.1
1
10/09/23 06:26
10/09/23 23:15
86-73-7
Hexachlorobenzene
<2.2
ug/L
10.0
2.2
1
10/09/23 06:26
10/09/23 23:15
118-74-1
Hexachlorocyclopentadiene
<1.6
ug/L
10.0
1.6
1
10/09/23 06:26
10/09/23 23:15
77-47-4
Hexachloroethane
<1.4
ug/L
10.0
1.4
1
10/09/23 06:26
10/09/23 23:15
67-72-1
Hexachloropropene
<2.7
ug/L
10.0
2.7
1
10/09/23 06:26
10/09/23 23:15
1888-71-7
Indeno(1,2,3-cd)pyrene
<2.9
ug/L
10.0
2.9
1
10/09/23 06:26
10/09/23 23:15
193-39-5
Isodrin
<2.8
ug/L
10.0
2.8
1
10/09/23 06:26
10/09/23 23:15
465-73-6
Isophorone
<1.7
ug/L
10.0
1.7
1
10/09/23 06:26
10/09/23 23:15
78-59-1
Isosafrole
<2.5
ug/L
10.0
2.5
1
10/09/23 06:26
10/09/23 23:15
120-58-1
Kepone
<14.1
ug/L
20.0
14.1
1
10/09/23 06:26
10/09/23 23:15
143-50-0
Methapyrilene
<17.0
ug/L
50.0
17.0
1
10/09/23 06:26
10/09/23 23:15
91-80-5
3-Methylcholanthrene
<3.7
ug/L
10.0
3.7
1
10/09/23 06:26
10/09/23 23:15
56-49-5
Methyl methanesulfonate
<3.1
ug/L
5.0
3.1
1
10/09/23 06:26
10/09/23 23:15
66-27-3
2-Methylnaphthalene
<1.9
ug/L
10.0
1.9
1
10/09/23 06:26
10/09/23 23:15
91-57-6
Methyl parathion
<3.7
ug/L
10.0
3.7
1
10/09/23 06:26
10/09/23 23:15
298-00-0
2-Methylphenol(o-Cresol)
<1.9
ug/L
10.0
1.9
1
10/09/23 06:26
10/09/23 23:15
95-48-7
3&4-Methyl phenol (m&p Cresol)
<1.2
ug/L
10.0
1.2
1
10/09/23 06:26
10/09/23 23:15
15831-10-4
1-Naphthalenamine
<6.0
ug/L
10.0
6.0
1
10/09/23 06:26
10/09/23 23:15
134-32-7
REPORT OF LABORATORY ANALYSIS
IL
11.
v1
v1
v1
L2
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: LT-01-20231004 Lab ID: 92691921001 Collected: 10/04/23 15:20 Received: 10/05/23 09:04 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
2-Naphthalenamine
1,4-Naphthoquinone
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
5-Nitro-o-toluidine
N-Nitrosodiethylamine
N-Nitrosodimethylamine
N-Nitroso-di-n-butylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
N-Nitrosomethylethylamine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
O, O,O-Triethyl phosphorothioate
2,2'-Oxybis(1-chloropropane)
Parathion (Ethyl parathion)
Pentachlorobenzene
Pentachloronitrobenzene
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
p-Phenylenediamine
Phorate
Pronamide
Pyrene
Safrole
1,2,4,5-Tetrachlorobenzene
2,3,4,6-Tetrachlorophenol
Thionazin
O-Toluidine
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
1,3,5-Trinitrobenzene
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
<5.4
ug/L
10.0
5.4
1
10/09/23 06:26
10/09/23 23:15
91-59-8
<4.4
ug/L
5.0
4.4
1
10/09/23 06:26
10/09/23 23:15
130-15-4
<3.0
ug/L
20.0
3.0
1
10/09/23 06:26
10/09/23 23:15
88-74-4
<3.8
ug/L
20.0
3.8
1
10/09/23 06:26
10/09/23 23:15
99-09-2
<5.1
ug/L
20.0
5.1
1
10/09/23 06:26
10/09/23 23:15
100-01-6
<1.9
ug/L
10.0
1.9
1
10/09/23 06:26
10/09/23 23:15
98-95-3
<1.4
ug/L
10.0
1.4
1
10/09/23 06:26
10/09/23 23:15
88-75-5
<6.6
ug/L
50.0
6.6
1
10/09/23 06:26
10/09/23 23:15
100-02-7
<3.8
ug/L
10.0
3.8
1
10/09/23 06:26
10/09/23 23:15
99-55-8
<2.3
ug/L
10.0
2.3
1
10/09/23 06:26
10/09/23 23:15
55-18-5
<1.9
ug/L
10.0
1.9
1
10/09/23 06:26
10/09/23 23:15
62-75-9
<2.0
ug/L
10.0
2.0
1
10/09/23 06:26
10/09/23 23:15
924-16-3
<1.3
ug/L
10.0
1.3
1
10/09/23 06:26
10/09/23 23:15
621-64-7
<3.0
ug/L
10.0
3.0
1
10/09/23 06:26
10/09/23 23:15
86-30-6
<7.5
ug/L
10.0
7.5
1
10/09/23 06:26
10/09/23 23:15
10595-95-6
<2.5
ug/L
10.0
2.5
1
10/09/23 06:26
10/09/23 23:15
100-75-4
<3.1
ug/L
10.0
3.1
1
10/09/23 06:26
10/09/23 23:15
930-55-2
<2.6
ug/L
10.0
2.6
1
10/09/23 06:26
10/09/23 23:15
126-68-1
<1.2
ug/L
10.0
1.2
1
10/09/23 06:26
10/09/23 23:15
108-60-1
<3.9
ug/L
10.0
3.9
1
10/09/23 06:26
10/09/23 23:15
56-38-2
<3.4
ug/L
10.0
3.4
1
10/09/23 06:26
10/09/23 23:15
608-93-5
<3.3
ug/L
10.0
3.3
1
10/09/23 06:26
10/09/23 23:15
82-68-8
<3.8
ug/L
20.0
3.8
1
10/09/23 06:26
10/09/23 23:15
87-86-5
<3.6
ug/L
10.0
3.6
1
10/09/23 06:26
10/09/23 23:15
62-44-2
<2.0
ug/L
10.0
2.0
1
10/09/23 06:26
10/09/23 23:15
85-01-8
<1.4
ug/L
10.0
1.4
1
10/09/23 06:26
10/09/23 23:15
108-95-2
<10.0
ug/L
10.0
10.0
1
10/09/23 06:26
10/09/23 23:15
106-50-3
<3.6
ug/L
10.0
3.6
1
10/09/23 06:26
10/09/23 23:15
298-02-2
<3.1
ug/L
10.0
3.1
1
10/09/23 06:26
10/09/23 23:15
23950-58-5
<2.2
ug/L
10.0
2.2
1
10/09/23 06:26
10/09/23 23:15
129-00-0
<2.3
ug/L
10.0
2.3
1
10/09/23 06:26
10/09/23 23:15
94-59-7
<4.5
ug/L
10.0
4.5
1
10/09/23 06:26
10/09/23 23:15
95-94-3
<1.5
ug/L
10.0
1.5
1
10/09/23 06:26
10/09/23 23:15
58-90-2
<2.9
ug/L
10.0
2.9
1
10/09/23 06:26
10/09/23 23:15
297-97-2
<2.6
ug/L
10.0
2.6
1
10/09/23 06:26
10/09/23 23:15
95-53-4
<1.4
ug/L
10.0
1.4
1
10/09/23 06:26
10/09/23 23:15
95-95-4
<1.6
ug/L
10.0
1.6
1
10/09/23 06:26
10/09/23 23:15
88-06-2
<5.5
ug/L
10.0
5.5
1
10/09/23 06:26
10/09/23 23:15
99-35-4
43
%
10-138
1
10/09/23 06:26
10/09/23 23:15
4165-60-0
55
%
10-130
1
10/09/23 06:26
10/09/23 23:15
321-60-8
94
%
19-191
1
10/09/23 06:26
10/09/23 23:15
1718-51-0
41
%
10-130
1
10/09/23 06:26
10/09/23 23:15
13127-88-3
37
%
10-130
1
10/09/23 06:26
10/09/23 23:15
367-12-4
121
%
10-164
1
10/09/23 06:26
10/09/23 23:15
118-79-6
REPORT OF LABORATORY ANALYSIS
v1
v1
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: LT-01-20231004 Lab ID: 92691921001 Collected: 10/04/23 15:20 Received: 10/05/23 09:04 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
<5.1
ug/L
25.0
5.1
1
10/09/2312:45
67-64-1
0.77J
ug/L
1.0
0.34
1
10/09/2312:45
71-43-2
<0.29
ug/L
1.0
0.29
1
10/09/2312:45
108-86-1
<0.47
ug/L
1.0
0.47
1
10/09/2312:45
74-97-5
<0.31
ug/L
1.0
0.31
1
10/09/2312:45
75-27-4
<0.34
ug/L
1.0
0.34
1
10/09/2312:45
75-25-2
<1.7
ug/L
2.0
1.7
1
10/09/2312:45
74-83-9 v2
<4.0
ug/L
5.0
4.0
1
10/09/2312:45
78-93-3
<0.33
ug/L
1.0
0.33
1
10/09/2312:45
56-23-5
2.2
ug/L
1.0
0.28
1
10/09/2312:45
108-90-7
<0.65
ug/L
1.0
0.65
1
10/09/2312:45
75-00-3
<0.43
ug/L
1.0
0.43
1
10/09/2312:45
67-66-3
<0.54
ug/L
1.0
0.54
1
10/09/2312:45
74-87-3
<0.32
ug/L
1.0
0.32
1
10/09/2312:45
95-49-8
<0.32
ug/L
1.0
0.32
1
10/09/2312:45
106-43-4
<0.34
ug/L
2.0
0.34
1
10/09/2312:45
96-12-8
<0.36
ug/L
1.0
0.36
1
10/09/2312:45
124-48-1
<0.27
ug/L
1.0
0.27
1
10/09/2312:45
106-93-4
<0.39
ug/L
1.0
0.39
1
10/09/2312:45
74-95-3
<0.34
ug/L
1.0
0.34
1
10/09/2312:45
95-50-1
<0.34
ug/L
1.0
0.34
1
10/09/2312:45
541-73-1
2.3
ug/L
1.0
0.33
1
10/09/2312:45
106-46-7
<0.35
ug/L
1.0
0.35
1
10/09/2312:45
75-71-8
<0.37
ug/L
1.0
0.37
1
10/09/2312:45
75-34-3
<0.32
ug/L
1.0
0.32
1
10/09/2312:45
107-06-2
<0.35
ug/L
1.0
0.35
1
10/09/2312:45
75-35-4
<0.38
ug/L
1.0
0.38
1
10/09/2312:45
156-59-2
<0.40
ug/L
1.0
0.40
1
10/09/2312:45
156-60-5
<0.36
ug/L
1.0
0.36
1
10/09/2312:45
78-87-5
<0.28
ug/L
1.0
0.28
1
10/09/2312:45
142-28-9
<0.39
ug/L
1.0
0.39
1
10/09/2312:45
594-20-7
<0.43
ug/L
1.0
0.43
1
10/09/2312:45
563-58-6
<0.36
ug/L
1.0
0.36
1
10/09/2312:45
10061-01-5
<0.36
ug/L
1.0
0.36
1
10/09/2312:45
10061-02-6
<0.31
ug/L
1.0
0.31
1
10/09/2312:45
108-20-3
0.32J
ug/L
1.0
0.30
1
10/09/2312:45
100-41-4
<1.5
ug/L
2.0
1.5
1
10/09/2312:45
87-68-3
<0.48
ug/L
5.0
0.48
1
10/09/2312:45
591-78-6
<0.41
ug/L
1.0
0.41
1
10/09/2312:45
99-87-6
<2.0
ug/L
5.0
2.0
1
10/09/2312:45
75-09-2
<2.7
ug/L
5.0
2.7
1
10/09/2312:45
108-10-1
<0.42
ug/L
1.0
0.42
1
10/09/2312:45
1634-04-4
6.9
ug/L
1.0
0.64
1
10/09/2312:45
91-20-3
<0.29
ug/L
1.0
0.29
1
10/09/2312:45
100-42-5
<0.31
ug/L
1.0
0.31
1
10/09/2312:45
630-20-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 229

Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: LT-01-20231004
Parameters
8260D MSV Low Level Landfill
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 02/23/2024 01:48 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Lab ID: 92691921001 Collected: 10/04/23 15:20 Received: 10/05/23 09:04 Matrix: Water
Results Units PQL
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
<0.22
ug/L
1.0
<0.29
ug/L
1.0
<0.24
ug/L
1.0
<0.81
ug/L
1.0
<0.64
ug/L
1.0
<0.33
ug/L
1.0
<0.32
ug/L
1.0
<0.38
ug/L
1.0
<0.30
ug/L
1.0
<0.26
ug/L
1.0
<1.3
ug/L
2.0
<0.39
ug/L
1.0
0.73J
ug/L
1.0
<0.71
ug/L
2.0
0.73J
ug/L
1.0
99
%
70-130
96
%
70-130
99
%
70-130
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
62.7
ug/L
2.0
85
%
67-130
91
%
70-130
MDL DF Prepared Analyzed CAS No. Qual
0.22 1
0.29 1
0.24 1
0.81 1
0.64 1
0.33 1
0.32 1
0.38 1
0.30 1
0.26 1
1.3 1
0.39 1
0.34 1
0.71 1
0.34 1
0.86 1
1
1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
10/09/23 12:45 79-34-5
10/09/23 12:45 127-18-4
10/09/23 12:45 108-88-3
10/09/23 12:45 87-61-6
10/09/23 12:45 120-82-1
10/09/23 12:45 71-55-6
10/09/23 12:45 79-00-5
10/09/23 12:45 79-01-6
10/09/23 12:45 75-69-4
10/09/23 12:45 96-18-4
10/09/23 12:45 108-05-4
10/09/23 12:45 75-01-4
10/09/23 12:45 1330-20-7
10/09/23 12:45 179601-23-1
10/09/23 12:45 95-47-6
10/09/23 12:45 460-00-4
10/09/23 12:45 17060-07-0
10/09/23 12:45 2037-26-5
10/09/23 20:11 123-91-1
10/09/23 20:11 17060-07-0
10/09/23 20:11 2037-26-5
Page 12 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: SW-01-20231004 Lab ID: 92691921002 Collected: 10/04/23 18:30 Received: 10/05/23 09:04 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Arsenic
0.088J
ug/L
1.0
0.087
1
10/10/2315:20
10/11/2314:39
7440-38-2
Beryllium
<0.050
ug/L
0.10
0.050
1
10/10/2315:20
10/11/2314:39
7440-41-7
Barium
16.2
ug/L
1.0
0.21
1
10/10/2315:20
10/11/2314:39
7440-39-3
Cadmium
<0.060
ug/L
0.20
0.060
1
10/10/2315:20
10/11/2314:39
7440-43-9
Cobalt
0.12J
ug/L
1.0
0.050
1
10/10/2315:20
10/11/2314:39
7440-48-4
Chromium
0.65J
ug/L
1.0
0.50
1
10/10/2315:20
10/11/2314:39
7440-47-3
Copper
<1.1
ug/L
2.0
1.1
1
10/10/2315:20
10/11/2314:39
7440-50-8
Nickel
<0.42
ug/L
1.0
0.42
1
10/10/2315:20
10/11/2314:39
7440-02-0
Silver
<0.070
ug/L
0.40
0.070
1
10/10/2315:20
10/11/2314:39
7440-22-4
Lead
<0.077
ug/L
1.0
0.077
1
10/10/2315:20
10/11/2314:39
7439-92-1
Antimony
<0.20
ug/L
1.0
0.20
1
10/10/2315:20
10/11/2314:39
7440-36-0
Selenium
<0.072
ug/L
2.0
0.072
1
10/10/2315:20
10/11/2314:39
7782-49-2
Tin
<0.43
ug/L
1.0
0.43
1
10/10/2315:20
10/11/2314:39
7440-31-5
Thallium
<0.050
ug/L
0.20
0.050
1
10/10/2315:20
10/11/2314:39
7440-28-0
Vanadium
0.511
ug/L
1.0
0.25
1
10/10/2315:20
10/11/2314:39
7440-62-2
Hardness, Total(SM 2340B)
11200
ug/L
541
541
1
10/10/23 15:20
10/11/23 14:39
7470 Mercury
Analytical Method: EPA 7470A Preparation Method:
EPA
7470A
Pace Analytical Services
-Asheville
Mercury
<0.12
ug/L
0.20
0.12
1
10/13/2315:08
10/14/2311:29
7439-97-6
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method:
EPA
3510C
Pace Analytical Services - Charlotte
Acenaphthene
<1.8
ug/L
9.1
1.8
1
10/09/23 06:26
10/09/23 23:41
83-32-9
Acenaphthylene
<1.8
ug/L
9.1
1.8
1
10/09/23 06:26
10/09/23 23:41
208-96-8
Acetophenone
<1.4
ug/L
9.1
1.4
1
10/09/23 06:26
10/09/23 23:41
98-86-2
2-Acetylaminofluorene
<3.7
ug/L
9.1
3.7
1
10/09/23 06:26
10/09/23 23:41
53-96-3
4-Aminobiphenyl
<4.3
ug/L
9.1
4.3
1
10/09/23 06:26
10/09/23 23:41
92-67-1
Anthracene
<2.1
ug/L
9.1
2.1
1
10/09/23 06:26
10/09/23 23:41
120-12-7
Benzo(a)anthracene
<2.4
ug/L
9.1
2.4
1
10/09/23 06:26
10/09/23 23:41
56-55-3
Benzo(a)pyrene
<2.5
ug/L
9.1
2.5
1
10/09/23 06:26
10/09/23 23:41
50-32-8
Benzo(b)fluoranthene
<2.4
ug/L
9.1
2.4
1
10/09/23 06:26
10/09/23 23:41
205-99-2
Benzo(g,h,i)perylene
<2.6
ug/L
9.1
2.6
1
10/09/23 06:26
10/09/23 23:41
191-24-2
Benzo(k)fluoranthene
<2.5
ug/L
9.1
2.5
1
10/09/23 06:26
10/09/23 23:41
207-08-9
Benzyl alcohol
<2.6
ug/L
18.2
2.6
1
10/09/23 06:26
10/09/23 23:41
100-51-6
4-Bromophenylphenyl ether
<1.6
ug/L
9.1
1.6
1
10/09/23 06:26
10/09/23 23:41
101-55-3
Butylbenzylphthalate
<2.9
ug/L
9.1
2.9
1
10/09/23 06:26
10/09/23 23:41
85-68-7
4-Chloro-3-methyl phenol
<3.0
ug/L
9.1
3.0
1
10/09/23 06:26
10/09/23 23:41
59-50-7
4-Chloroaniline
<3.3
ug/L
18.2
3.3
1
10/09/23 06:26
10/09/23 23:41
106-47-8
Chlorobenzilate
<3.4
ug/L
9.1
3.4
1
10/09/23 06:26
10/09/23 23:41
510-15-6
bis(2-Chloroethoxy)methane
<1.7
ug/L
9.1
1.7
1
10/09/23 06:26
10/09/23 23:41
111-91-1
bis(2-Chloroethyl) ether
<1.7
ug/L
9.1
1.7
1
10/09/23 06:26
10/09/23 23:41
111-44-4
2-Chloronaphthalene
<1.6
ug/L
9.1
1.6
1
10/09/23 06:26
10/09/23 23:41
91-58-7
2-Chlorophenol
<1.1
ug/L
9.1
1.1
1
10/09/23 06:26
10/09/23 23:41
95-57-8
4-Chlorophenylphenyl ether
<1.8
ug/L
9.1
1.8
1
10/09/23 06:26
10/09/23 23:41
7005-72-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: SW-01-20231004 Lab ID: 92691921002 Collected: 10/04/23 18:30 Received: 10/05/23 09:04 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Chrysene
<2.5
ug/L
9.1
2.5
1
10/09/23 06:26
10/09/23 23:41
218-01-9
Diallate
<3.1
ug/L
9.1
3.1
1
10/09/23 06:26
10/09/23 23:41
2303-16-4
Dibenz(a,h)anthracene
<2.7
ug/L
9.1
2.7
1
10/09/23 06:26
10/09/23 23:41
53-70-3
Dibenzofuran
<1.9
ug/L
9.1
1.9
1
10/09/23 06:26
10/09/23 23:41
132-64-9
3,3'-Dichlorobenzidine
<7.4
ug/L
18.2
7.4
1
10/09/23 06:26
10/09/23 23:41
91-94-1
2,4-Dichlorophenol
<1.3
ug/L
9.1
1.3
1
10/09/23 06:26
10/09/23 23:41
120-83-2
2,6-Dichlorophenol
<3.8
ug/L
9.1
3.8
1
10/09/23 06:26
10/09/23 23:41
87-65-0
Diethylphthalate
<1.9
ug/L
9.1
1.9
1
10/09/23 06:26
10/09/23 23:41
84-66-2
Dimethoate
<3.3
ug/L
9.1
3.3
1
10/09/23 06:26
10/09/23 23:41
60-51-5
P-Dimethylaminoazobenzene
<2.2
ug/L
4.5
2.2
1
10/09/23 06:26
10/09/23 23:41
60-11-7
7,12-Dimethylbenz(a)anthracene
<2.7
ug/L
9.1
2.7
1
10/09/23 06:26
10/09/23 23:41
57-97-6
3,3'-Dimethylbenzidine
<28.3
ug/L
45.5
28.3
1
10/09/23 06:26
10/09/23 23:41
119-93-7
2,4-Dimethylphenol
<1.5
ug/L
9.1
1.5
1
10/09/23 06:26
10/09/23 23:41
105-67-9
Dimethylphthalate
<1.9
ug/L
9.1
1.9
1
10/09/23 06:26
10/09/23 23:41
131-11-3
Di-n-butylphthalate
<2.0
ug/L
9.1
2.0
1
10/09/23 06:26
10/09/23 23:41
84-74-2
4,6-Dinitro-2-methyl phenol
<7.1
ug/L
18.2
7.1
1
10/09/23 06:26
10/09/23 23:41
534-52-1
1,3-Dinitrobenzene
<3.4
ug/L
9.1
3.4
1
10/09/23 06:26
10/09/23 23:41
99-65-0
2,4-Dinitrophenol
<23.6
ug/L
45.5
23.6
1
10/09/23 06:26
10/09/23 23:41
51-28-5
2,4-Dinitrotoluene
<1.5
ug/L
9.1
1.5
1
10/09/23 06:26
10/09/23 23:41
121-14-2
2,6-Dinitrotoluene
<1.6
ug/L
9.1
1.6
1
10/09/23 06:26
10/09/23 23:41
606-20-2
Di-n-octylphthalate
<3.6
ug/L
9.1
3.6
1
10/09/23 06:26
10/09/23 23:41
117-84-0
Diphenylamine
<2.7
ug/L
9.1
2.7
1
10/09/23 06:26
10/09/23 23:41
122-39-4
Disulfoton
<4.2
ug/L
9.1
4.2
1
10/09/23 06:26
10/09/23 23:41
298-04-4
bis(2- Ethyl hexyl)phthalate
<3.4
ug/L
5.5
3.4
1
10/09/23 06:26
10/09/23 23:41
117-81-7
Ethyl methanesulfonate
<2.7
ug/L
18.2
2.7
1
10/09/23 06:26
10/09/23 23:41
62-50-0
Famphur
<5.6
ug/L
9.1
5.6
1
10/09/23 06:26
10/09/23 23:41
52-85-7
Fluoranthene
<2.0
ug/L
9.1
2.0
1
10/09/23 06:26
10/09/23 23:41
206-44-0
Fluorene
<1.9
ug/L
9.1
1.9
1
10/09/23 06:26
10/09/23 23:41
86-73-7
Hexachlorobenzene
<2.0
ug/L
9.1
2.0
1
10/09/23 06:26
10/09/23 23:41
118-74-1
Hexachlorocyclopentadiene
<1.4
ug/L
9.1
1.4
1
10/09/23 06:26
10/09/23 23:41
77-47-4
Hexachloroethane
<1.3
ug/L
9.1
1.3
1
10/09/23 06:26
10/09/23 23:41
67-72-1
Hexachloropropene
<2.5
ug/L
9.1
2.5
1
10/09/23 06:26
10/09/23 23:41
1888-71-7
Indeno(1,2,3-cd)pyrene
<2.6
ug/L
9.1
2.6
1
10/09/23 06:26
10/09/23 23:41
193-39-5
Isodrin
<2.5
ug/L
9.1
2.5
1
10/09/23 06:26
10/09/23 23:41
465-73-6
Isophorone
<1.5
ug/L
9.1
1.5
1
10/09/23 06:26
10/09/23 23:41
78-59-1
Isosafrole
<2.3
ug/L
9.1
2.3
1
10/09/23 06:26
10/09/23 23:41
120-58-1
Kepone
<12.8
ug/L
18.2
12.8
1
10/09/23 06:26
10/09/23 23:41
143-50-0
Methapyrilene
<15.5
ug/L
45.5
15.5
1
10/09/23 06:26
10/09/23 23:41
91-80-5
3-Methylcholanthrene
<3.4
ug/L
9.1
3.4
1
10/09/23 06:26
10/09/23 23:41
56-49-5
Methyl methanesulfonate
<2.8
ug/L
4.5
2.8
1
10/09/23 06:26
10/09/23 23:41
66-27-3
2-Methylnaphthalene
<1.7
ug/L
9.1
1.7
1
10/09/23 06:26
10/09/23 23:41
91-57-6
Methyl parathion
<3.4
ug/L
9.1
3.4
1
10/09/23 06:26
10/09/23 23:41
298-00-0
2-Methylphenol(o-Cresol)
<1.7
ug/L
9.1
1.7
1
10/09/23 06:26
10/09/23 23:41
95-48-7
3&4-Methyl phenol (m&p Cresol)
<1.1
ug/L
9.1
1.1
1
10/09/23 06:26
10/09/23 23:41
15831-10-4
1-Naphthalenamine
<5.5
ug/L
9.1
5.5
1
10/09/23 06:26
10/09/23 23:41
134-32-7
REPORT OF LABORATORY ANALYSIS
IL
11.
v1
v1
v1
L2
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: SW-01-20231004 Lab ID: 92691921002 Collected: 10/04/23 18:30 Received: 10/05/23 09:04 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
2-Naphthalenamine
1,4-Naphthoquinone
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
5-Nitro-o-toluidine
N-Nitrosodiethylamine
N-Nitrosodimethylamine
N-Nitroso-di-n-butylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
N-Nitrosomethylethylamine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
O, O,O-Triethyl phosphorothioate
2,2'-Oxybis(1-chloropropane)
Parathion (Ethyl parathion)
Pentachlorobenzene
Pentachloronitrobenzene
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
p-Phenylenediamine
Phorate
Pronamide
Pyrene
Safrole
1,2,4,5-Tetrachlorobenzene
2,3,4,6-Tetrachlorophenol
Thionazin
O-Toluidine
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
1,3,5-Trinitrobenzene
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
<5.0
ug/L
9.1
5.0
1
10/09/23 06:26
10/09/23 23:41
91-59-8
<4.0
ug/L
4.5
4.0
1
10/09/23 06:26
10/09/23 23:41
130-15-4
<2.7
ug/L
18.2
2.7
1
10/09/23 06:26
10/09/23 23:41
88-74-4
<3.4
ug/L
18.2
3.4
1
10/09/23 06:26
10/09/23 23:41
99-09-2
<4.6
ug/L
18.2
4.6
1
10/09/23 06:26
10/09/23 23:41
100-01-6
<1.7
ug/L
9.1
1.7
1
10/09/23 06:26
10/09/23 23:41
98-95-3
<1.3
ug/L
9.1
1.3
1
10/09/23 06:26
10/09/23 23:41
88-75-5
<6.0
ug/L
45.5
6.0
1
10/09/23 06:26
10/09/23 23:41
100-02-7
<3.5
ug/L
9.1
3.5
1
10/09/23 06:26
10/09/23 23:41
99-55-8
<2.1
ug/L
9.1
2.1
1
10/09/23 06:26
10/09/23 23:41
55-18-5
<1.7
ug/L
9.1
1.7
1
10/09/23 06:26
10/09/23 23:41
62-75-9
<1.8
ug/L
9.1
1.8
1
10/09/23 06:26
10/09/23 23:41
924-16-3
<1.2
ug/L
9.1
1.2
1
10/09/23 06:26
10/09/23 23:41
621-64-7
<2.7
ug/L
9.1
2.7
1
10/09/23 06:26
10/09/23 23:41
86-30-6
<6.8
ug/L
9.1
6.8
1
10/09/23 06:26
10/09/23 23:41
10595-95-6
<2.3
ug/L
9.1
2.3
1
10/09/23 06:26
10/09/23 23:41
100-75-4
<2.8
ug/L
9.1
2.8
1
10/09/23 06:26
10/09/23 23:41
930-55-2
<2.3
ug/L
9.1
2.3
1
10/09/23 06:26
10/09/23 23:41
126-68-1
<1.0
ug/L
9.1
1.0
1
10/09/23 06:26
10/09/23 23:41
108-60-1
<3.5
ug/L
9.1
3.5
1
10/09/23 06:26
10/09/23 23:41
56-38-2
<3.1
ug/L
9.1
3.1
1
10/09/23 06:26
10/09/23 23:41
608-93-5
<3.0
ug/L
9.1
3.0
1
10/09/23 06:26
10/09/23 23:41
82-68-8
<3.4
ug/L
18.2
3.4
1
10/09/23 06:26
10/09/23 23:41
87-86-5
<3.3
ug/L
9.1
3.3
1
10/09/23 06:26
10/09/23 23:41
62-44-2
<1.8
ug/L
9.1
1.8
1
10/09/23 06:26
10/09/23 23:41
85-01-8
<1.2
ug/L
9.1
1.2
1
10/09/23 06:26
10/09/23 23:41
108-95-2
<9.1
ug/L
9.1
9.1
1
10/09/23 06:26
10/09/23 23:41
106-50-3
<3.2
ug/L
9.1
3.2
1
10/09/23 06:26
10/09/23 23:41
298-02-2
<2.8
ug/L
9.1
2.8
1
10/09/23 06:26
10/09/23 23:41
23950-58-5
<2.0
ug/L
9.1
2.0
1
10/09/23 06:26
10/09/23 23:41
129-00-0
<2.1
ug/L
9.1
2.1
1
10/09/23 06:26
10/09/23 23:41
94-59-7
<4.1
ug/L
9.1
4.1
1
10/09/23 06:26
10/09/23 23:41
95-94-3
<1.4
ug/L
9.1
1.4
1
10/09/23 06:26
10/09/23 23:41
58-90-2
<2.6
ug/L
9.1
2.6
1
10/09/23 06:26
10/09/23 23:41
297-97-2
<2.4
ug/L
9.1
2.4
1
10/09/23 06:26
10/09/23 23:41
95-53-4
<1.3
ug/L
9.1
1.3
1
10/09/23 06:26
10/09/23 23:41
95-95-4
<1.4
ug/L
9.1
1.4
1
10/09/23 06:26
10/09/23 23:41
88-06-2
<5.0
ug/L
9.1
5.0
1
10/09/23 06:26
10/09/23 23:41
99-35-4
48
%
10-138
1
10/09/23 06:26
10/09/23 23:41
4165-60-0
49
%
10-130
1
10/09/23 06:26
10/09/23 23:41
321-60-8
71
%
19-191
1
10/09/23 06:26
10/09/23 23:41
1718-51-0
25
%
10-130
1
10/09/23 06:26
10/09/23 23:41
13127-88-3
33
%
10-130
1
10/09/23 06:26
10/09/23 23:41
367-12-4
71
%
10-164
1
10/09/23 06:26
10/09/23 23:41
118-79-6
REPORT OF LABORATORY ANALYSIS
v1
v1
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: SW-01-20231004 Lab ID: 92691921002 Collected: 10/04/23 18:30 Received: 10/05/23 09:04 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
<5.1
ug/L
25.0
5.1
1
10/09/2313:03
67-64-1
<0.34
ug/L
1.0
0.34
1
10/09/2313:03
71-43-2
<0.29
ug/L
1.0
0.29
1
10/09/2313:03
108-86-1
<0.47
ug/L
1.0
0.47
1
10/09/2313:03
74-97-5
<0.31
ug/L
1.0
0.31
1
10/09/2313:03
75-27-4
<0.34
ug/L
1.0
0.34
1
10/09/2313:03
75-25-2
<1.7
ug/L
2.0
1.7
1
10/09/2313:03
74-83-9 v2
<4.0
ug/L
5.0
4.0
1
10/09/2313:03
78-93-3
<0.33
ug/L
1.0
0.33
1
10/09/2313:03
56-23-5
<0.28
ug/L
1.0
0.28
1
10/09/2313:03
108-90-7
<0.65
ug/L
1.0
0.65
1
10/09/2313:03
75-00-3
<0.43
ug/L
1.0
0.43
1
10/09/2313:03
67-66-3
<0.54
ug/L
1.0
0.54
1
10/09/2313:03
74-87-3
<0.32
ug/L
1.0
0.32
1
10/09/2313:03
95-49-8
<0.32
ug/L
1.0
0.32
1
10/09/2313:03
106-43-4
<0.34
ug/L
2.0
0.34
1
10/09/2313:03
96-12-8
<0.36
ug/L
1.0
0.36
1
10/09/2313:03
124-48-1
<0.27
ug/L
1.0
0.27
1
10/09/2313:03
106-93-4
<0.39
ug/L
1.0
0.39
1
10/09/2313:03
74-95-3
<0.34
ug/L
1.0
0.34
1
10/09/2313:03
95-50-1
<0.34
ug/L
1.0
0.34
1
10/09/2313:03
541-73-1
<0.33
ug/L
1.0
0.33
1
10/09/2313:03
106-46-7
<0.35
ug/L
1.0
0.35
1
10/09/2313:03
75-71-8
<0.37
ug/L
1.0
0.37
1
10/09/2313:03
75-34-3
<0.32
ug/L
1.0
0.32
1
10/09/2313:03
107-06-2
<0.35
ug/L
1.0
0.35
1
10/09/2313:03
75-35-4
<0.38
ug/L
1.0
0.38
1
10/09/2313:03
156-59-2
<0.40
ug/L
1.0
0.40
1
10/09/2313:03
156-60-5
<0.36
ug/L
1.0
0.36
1
10/09/2313:03
78-87-5
<0.28
ug/L
1.0
0.28
1
10/09/2313:03
142-28-9
<0.39
ug/L
1.0
0.39
1
10/09/2313:03
594-20-7
<0.43
ug/L
1.0
0.43
1
10/09/2313:03
563-58-6
<0.36
ug/L
1.0
0.36
1
10/09/2313:03
10061-01-5
<0.36
ug/L
1.0
0.36
1
10/09/2313:03
10061-02-6
<0.31
ug/L
1.0
0.31
1
10/09/2313:03
108-20-3
<0.30
ug/L
1.0
0.30
1
10/09/2313:03
100-41-4
<1.5
ug/L
2.0
1.5
1
10/09/2313:03
87-68-3
<0.48
ug/L
5.0
0.48
1
10/09/2313:03
591-78-6
<0.41
ug/L
1.0
0.41
1
10/09/2313:03
99-87-6
<2.0
ug/L
5.0
2.0
1
10/09/2313:03
75-09-2
<2.7
ug/L
5.0
2.7
1
10/09/2313:03
108-10-1
<0.42
ug/L
1.0
0.42
1
10/09/2313:03
1634-04-4
<0.64
ug/L
1.0
0.64
1
10/09/2313:03
91-20-3
<0.29
ug/L
1.0
0.29
1
10/09/2313:03
100-42-5
<0.31
ug/L
1.0
0.31
1
10/09/2313:03
630-20-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 16 of 229

Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: SW-01-20231004
Parameters
8260D MSV Low Level Landfill
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
Date: 02/23/2024 01:48 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Lab ID: 92691921002 Collected: 10/04/23 18:30 Received: 10/05/23 09:04 Matrix: Water
Results Units PQL
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
<0.22
ug/L
1.0
<0.29
ug/L
1.0
<0.24
ug/L
1.0
<0.81
ug/L
1.0
<0.64
ug/L
1.0
<0.33
ug/L
1.0
<0.32
ug/L
1.0
<0.38
ug/L
1.0
<0.30
ug/L
1.0
<0.26
ug/L
1.0
<1.3
ug/L
2.0
<0.39
ug/L
1.0
<0.34
ug/L
1.0
<0.71
ug/L
2.0
<0.34
ug/L
1.0
97
%
70-130
105
%
70-130
99
%
70-130
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
<0.86
ug/L
2.0
88
%
67-130
93
%
70-130
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services
-Asheville
<0.022
mg/L
0.10
MDL DF Prepared Analyzed CAS No. Qual
0.22
1
10/09/23 13:03
79-34-5
0.29
1
10/09/23 13:03
127-18-4
0.24
1
10/09/23 13:03
108-88-3
0.81
1
10/09/23 13:03
87-61-6
0.64
1
10/09/23 13:03
120-82-1
0.33
1
10/09/23 13:03
71-55-6
0.32
1
10/09/23 13:03
79-00-5
0.38
1
10/09/23 13:03
79-01-6
0.30
1
10/09/23 13:03
75-69-4
0.26
1
10/09/23 13:03
96-18-4
1.3
1
10/09/23 13:03
108-05-4
0.39
1
10/09/23 13:03
75-01-4
0.34
1
10/09/23 13:03
1330-20-7
0.71
1
10/09/23 13:03
179601-23-1
0.34
1
10/09/23 13:03
95-47-6
1
10/09/23 13:03
460-00-4
1
10/09/23 13:03
17060-07-0
1
10/09/23 13:03
2037-26-5
0.86 1
10/09/23 20:33
123-91-1
1
10/09/23 20:33
17060-07-0
1
10/09/23 20:33
2037-26-5
0.022 1
10/11/23 01:16
18496-25-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: SW-02-20231004 Lab ID: 92691921003 Collected: 10/04/23 16:25 Received: 10/05/23 09:04 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
<0.20
ug/L
1.0
0.20
1
10/10/2315:20
10/11/2314:44
7440-36-0
Arsenic
<0.087
ug/L
1.0
0.087
1
10/10/2315:20
10/11/2314:44
7440-38-2
Barium
12.6
ug/L
1.0
0.21
1
10/10/2315:20
10/11/2314:44
7440-39-3
Beryllium
<0.050
ug/L
0.10
0.050
1
10/10/2315:20
10/11/2314:44
7440-41-7
Cadmium
<0.060
ug/L
0.20
0.060
1
10/10/2315:20
10/11/2314:44
7440-43-9
Chromium
<0.50
ug/L
1.0
0.50
1
10/10/2315:20
10/11/2314:44
7440-47-3
Cobalt
0.13J
ug/L
1.0
0.050
1
10/10/2315:20
10/11/2314:44
7440-48-4
Copper
<1.1
ug/L
2.0
1.1
1
10/10/2315:20
10/11/2314:44
7440-50-8
Lead
<0.077
ug/L
1.0
0.077
1
10/10/2315:20
10/11/2314:44
7439-92-1
Nickel
<0.42
ug/L
1.0
0.42
1
10/10/2315:20
10/11/2314:44
7440-02-0
Selenium
<0.072
ug/L
2.0
0.072
1
10/10/2315:20
10/11/2314:44
7782-49-2
Silver
<0.070
ug/L
0.40
0.070
1
10/10/2315:20
10/11/2314:44
7440-22-4
Thallium
<0.050
ug/L
0.20
0.050
1
10/10/2315:20
10/11/2314:44
7440-28-0
Tin
<0.43
ug/L
1.0
0.43
1
10/10/2315:20
10/11/2314:44
7440-31-5
Hardness, Total(SM 2340B)
10700
ug/L
541
541
1
10/10/23 15:20
10/11/23 14:44
Vanadium
0.46J
ug/L
1.0
0.25
1
10/10/2315:20
10/11/2314:44
7440-62-2
7470 Mercury
Analytical Method: EPA 7470A Preparation Method: EPA
7470A
Pace Analytical Services
-Asheville
Mercury
<0.12
ug/L
0.20
0.12
1
10/13/2315:08
10/14/2311:36
7439-97-6
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method:
EPA
3510C
Pace Analytical Services - Charlotte
Acenaphthene
<2.0
ug/L
10.0
2.0
1
10/09/23 06:26
10/09/23 22:24
83-32-9
Acenaphthylene
<2.0
ug/L
10.0
2.0
1
10/09/23 06:26
10/09/23 22:24
208-96-8
Acetophenone
<1.5
ug/L
10.0
1.5
1
10/09/23 06:26
10/09/23 22:24
98-86-2
2-Acetylaminofluorene
<4.1
ug/L
10.0
4.1
1
10/09/23 06:26
10/09/23 22:24
53-96-3
4-Aminobiphenyl
<4.7
ug/L
10.0
4.7
1
10/09/23 06:26
10/09/23 22:24
92-67-1
Anthracene
<2.3
ug/L
10.0
2.3
1
10/09/23 06:26
10/09/23 22:24
120-12-7
Benzo(a)anthracene
<2.7
ug/L
10.0
2.7
1
10/09/23 06:26
10/09/23 22:24
56-55-3
Benzo(a)pyrene
<2.8
ug/L
10.0
2.8
1
10/09/23 06:26
10/09/23 22:24
50-32-8
Benzo(b)fluoranthene
<2.6
ug/L
10.0
2.6
1
10/09/23 06:26
10/09/23 22:24
205-99-2
Benzo(g,h,i)perylene
<2.8
ug/L
10.0
2.8
1
10/09/23 06:26
10/09/23 22:24
191-24-2
Benzo(k)fluoranthene
<2.7
ug/L
10.0
2.7
1
10/09/23 06:26
10/09/23 22:24
207-08-9
Benzyl alcohol
<2.9
ug/L
20.0
2.9
1
10/09/23 06:26
10/09/23 22:24
100-51-6
4-Bromophenylphenyl ether
<1.8
ug/L
10.0
1.8
1
10/09/23 06:26
10/09/23 22:24
101-55-3
Butylbenzylphthalate
<3.1
ug/L
10.0
3.1
1
10/09/23 06:26
10/09/23 22:24
85-68-7
4-Chloro-3-methyl phenol
<3.3
ug/L
10.0
3.3
1
10/09/23 06:26
10/09/23 22:24
59-50-7
4-Chloroaniline
<3.6
ug/L
20.0
3.6
1
10/09/23 06:26
10/09/23 22:24
106-47-8
Chlorobenzilate
<3.8
ug/L
10.0
3.8
1
10/09/23 06:26
10/09/23 22:24
510-15-6
bis(2-Chloroethoxy)methane
<1.8
ug/L
10.0
1.8
1
10/09/23 06:26
10/09/23 22:24
111-91-1
bis(2-Chloroethyl) ether
<1.9
ug/L
10.0
1.9
1
10/09/23 06:26
10/09/23 22:24
111-44-4
2-Chloronaphthalene
<1.7
ug/L
10.0
1.7
1
10/09/23 06:26
10/09/23 22:24
91-58-7
2-Chlorophenol
<1.2
ug/L
10.0
1.2
1
10/09/23 06:26
10/09/23 22:24
95-57-8
4-Chlorophenylphenyl ether
<2.0
ug/L
10.0
2.0
1
10/09/23 06:26
10/09/23 22:24
7005-72-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: SW-02-20231004 Lab ID: 92691921003 Collected: 10/04/23 16:25 Received: 10/05/23 09:04 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Chrysene
<2.8
ug/L
10.0
2.8
1
10/09/23 06:26
10/09/23 22:24
218-01-9
Diallate
<3.4
ug/L
10.0
3.4
1
10/09/23 06:26
10/09/23 22:24
2303-16-4
Dibenz(a,h)anthracene
<3.0
ug/L
10.0
3.0
1
10/09/23 06:26
10/09/23 22:24
53-70-3
Dibenzofuran
<2.1
ug/L
10.0
2.1
1
10/09/23 06:26
10/09/23 22:24
132-64-9
3,3'-Dichlorobenzidine
<8.1
ug/L
20.0
8.1
1
10/09/23 06:26
10/09/23 22:24
91-94-1
2,4-Dichlorophenol
<1.4
ug/L
10.0
1.4
1
10/09/23 06:26
10/09/23 22:24
120-83-2
2,6-Dichlorophenol
<4.2
ug/L
10.0
4.2
1
10/09/23 06:26
10/09/23 22:24
87-65-0
Diethylphthalate
<2.0
ug/L
10.0
2.0
1
10/09/23 06:26
10/09/23 22:24
84-66-2
Dimethoate
<3.7
ug/L
10.0
3.7
1
10/09/23 06:26
10/09/23 22:24
60-51-5
P-Dimethylaminoazobenzene
<2.4
ug/L
5.0
2.4
1
10/09/23 06:26
10/09/23 22:24
60-11-7
7,12-Dimethylbenz(a)anthracene
<3.0
ug/L
10.0
3.0
1
10/09/23 06:26
10/09/23 22:24
57-97-6
3,3'-Dimethylbenzidine
<31.1
ug/L
50.0
31.1
1
10/09/23 06:26
10/09/23 22:24
119-93-7
2,4-Dimethylphenol
<1.7
ug/L
10.0
1.7
1
10/09/23 06:26
10/09/23 22:24
105-67-9
Dimethylphthalate
<2.1
ug/L
10.0
2.1
1
10/09/23 06:26
10/09/23 22:24
131-11-3
Di-n-butylphthalate
<2.2
ug/L
10.0
2.2
1
10/09/23 06:26
10/09/23 22:24
84-74-2
4,6-Dinitro-2-methyl phenol
<7.8
ug/L
20.0
7.8
1
10/09/23 06:26
10/09/23 22:24
534-52-1
1,3-Dinitrobenzene
<3.8
ug/L
10.0
3.8
1
10/09/23 06:26
10/09/23 22:24
99-65-0
2,4-Dinitrophenol
<26.0
ug/L
50.0
26.0
1
10/09/23 06:26
10/09/23 22:24
51-28-5
2,4-Dinitrotoluene
<1.6
ug/L
10.0
1.6
1
10/09/23 06:26
10/09/23 22:24
121-14-2
2,6-Dinitrotoluene
<1.7
ug/L
10.0
1.7
1
10/09/23 06:26
10/09/23 22:24
606-20-2
Di-n-octylphthalate
<3.9
ug/L
10.0
3.9
1
10/09/23 06:26
10/09/23 22:24
117-84-0
Diphenylamine
<3.0
ug/L
10.0
3.0
1
10/09/23 06:26
10/09/23 22:24
122-39-4
Disulfoton
<4.6
ug/L
10.0
4.6
1
10/09/23 06:26
10/09/23 22:24
298-04-4
bis(2- Ethyl hexyl)phthalate
<3.7
ug/L
6.0
3.7
1
10/09/23 06:26
10/09/23 22:24
117-81-7
Ethyl methanesulfonate
<3.0
ug/L
20.0
3.0
1
10/09/23 06:26
10/09/23 22:24
62-50-0
Famphur
<6.1
ug/L
10.0
6.1
1
10/09/23 06:26
10/09/23 22:24
52-85-7
Fluoranthene
<2.2
ug/L
10.0
2.2
1
10/09/23 06:26
10/09/23 22:24
206-44-0
Fluorene
<2.1
ug/L
10.0
2.1
1
10/09/23 06:26
10/09/23 22:24
86-73-7
Hexachlorobenzene
<2.2
ug/L
10.0
2.2
1
10/09/23 06:26
10/09/23 22:24
118-74-1
Hexachlorocyclopentadiene
<1.6
ug/L
10.0
1.6
1
10/09/23 06:26
10/09/23 22:24
77-47-4
Hexachloroethane
<1.4
ug/L
10.0
1.4
1
10/09/23 06:26
10/09/23 22:24
67-72-1
Hexachloropropene
<2.7
ug/L
10.0
2.7
1
10/09/23 06:26
10/09/23 22:24
1888-71-7
Indeno(1,2,3-cd)pyrene
<2.9
ug/L
10.0
2.9
1
10/09/23 06:26
10/09/23 22:24
193-39-5
Isodrin
<2.8
ug/L
10.0
2.8
1
10/09/23 06:26
10/09/23 22:24
465-73-6
Isophorone
<1.7
ug/L
10.0
1.7
1
10/09/23 06:26
10/09/23 22:24
78-59-1
Isosafrole
<2.5
ug/L
10.0
2.5
1
10/09/23 06:26
10/09/23 22:24
120-58-1
Kepone
<14.1
ug/L
20.0
14.1
1
10/09/23 06:26
10/09/23 22:24
143-50-0
Methapyrilene
<17.0
ug/L
50.0
17.0
1
10/09/23 06:26
10/09/23 22:24
91-80-5
3-Methylcholanthrene
<3.7
ug/L
10.0
3.7
1
10/09/23 06:26
10/09/23 22:24
56-49-5
Methyl methanesulfonate
<3.1
ug/L
5.0
3.1
1
10/09/23 06:26
10/09/23 22:24
66-27-3
2-Methylnaphthalene
<1.9
ug/L
10.0
1.9
1
10/09/23 06:26
10/09/23 22:24
91-57-6
Methyl parathion
<3.7
ug/L
10.0
3.7
1
10/09/23 06:26
10/09/23 22:24
298-00-0
2-Methylphenol(o-Cresol)
<1.9
ug/L
10.0
1.9
1
10/09/23 06:26
10/09/23 22:24
95-48-7
3&4-Methyl phenol (m&p Cresol)
<1.2
ug/L
10.0
1.2
1
10/09/23 06:26
10/09/23 22:24
15831-10-4
1-Naphthalenamine
<6.0
ug/L
10.0
6.0
1
10/09/23 06:26
10/09/23 22:24
134-32-7
REPORT OF LABORATORY ANALYSIS
IL
11.
v1
v1
v1
L2
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: SW-02-20231004 Lab ID: 92691921003 Collected: 10/04/23 16:25 Received: 10/05/23 09:04 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
2-Naphthalenamine
1,4-Naphthoquinone
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
5-Nitro-o-toluidine
N-Nitrosodiethylamine
N-Nitrosodimethylamine
N-Nitroso-di-n-butylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
N-Nitrosomethylethylamine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
O, O,O-Triethyl phosphorothioate
2,2'-Oxybis(1-chloropropane)
Parathion (Ethyl parathion)
Pentachlorobenzene
Pentachloronitrobenzene
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
p-Phenylenediamine
Phorate
Pronamide
Pyrene
Safrole
1,2,4,5-Tetrachlorobenzene
2,3,4,6-Tetrachlorophenol
Thionazin
O-Toluidine
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
1,3,5-Trinitrobenzene
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
<5.4
ug/L
10.0
5.4
1
10/09/23 06:26
10/09/23 22:24
91-59-8
<4.4
ug/L
5.0
4.4
1
10/09/23 06:26
10/09/23 22:24
130-15-4
<3.0
ug/L
20.0
3.0
1
10/09/23 06:26
10/09/23 22:24
88-74-4
<3.8
ug/L
20.0
3.8
1
10/09/23 06:26
10/09/23 22:24
99-09-2
<5.1
ug/L
20.0
5.1
1
10/09/23 06:26
10/09/23 22:24
100-01-6
<1.9
ug/L
10.0
1.9
1
10/09/23 06:26
10/09/23 22:24
98-95-3
<1.4
ug/L
10.0
1.4
1
10/09/23 06:26
10/09/23 22:24
88-75-5
<6.6
ug/L
50.0
6.6
1
10/09/23 06:26
10/09/23 22:24
100-02-7
<3.8
ug/L
10.0
3.8
1
10/09/23 06:26
10/09/23 22:24
99-55-8
<2.3
ug/L
10.0
2.3
1
10/09/23 06:26
10/09/23 22:24
55-18-5
<1.9
ug/L
10.0
1.9
1
10/09/23 06:26
10/09/23 22:24
62-75-9
<2.0
ug/L
10.0
2.0
1
10/09/23 06:26
10/09/23 22:24
924-16-3
<1.3
ug/L
10.0
1.3
1
10/09/23 06:26
10/09/23 22:24
621-64-7
<3.0
ug/L
10.0
3.0
1
10/09/23 06:26
10/09/23 22:24
86-30-6
<7.5
ug/L
10.0
7.5
1
10/09/23 06:26
10/09/23 22:24
10595-95-6
<2.5
ug/L
10.0
2.5
1
10/09/23 06:26
10/09/23 22:24
100-75-4
<3.1
ug/L
10.0
3.1
1
10/09/23 06:26
10/09/23 22:24
930-55-2
<2.6
ug/L
10.0
2.6
1
10/09/23 06:26
10/09/23 22:24
126-68-1
<1.2
ug/L
10.0
1.2
1
10/09/23 06:26
10/09/23 22:24
108-60-1
<3.9
ug/L
10.0
3.9
1
10/09/23 06:26
10/09/23 22:24
56-38-2
<3.4
ug/L
10.0
3.4
1
10/09/23 06:26
10/09/23 22:24
608-93-5
<3.3
ug/L
10.0
3.3
1
10/09/23 06:26
10/09/23 22:24
82-68-8
<3.8
ug/L
20.0
3.8
1
10/09/23 06:26
10/09/23 22:24
87-86-5
<3.6
ug/L
10.0
3.6
1
10/09/23 06:26
10/09/23 22:24
62-44-2
<2.0
ug/L
10.0
2.0
1
10/09/23 06:26
10/09/23 22:24
85-01-8
<1.4
ug/L
10.0
1.4
1
10/09/23 06:26
10/09/23 22:24
108-95-2
<10.0
ug/L
10.0
10.0
1
10/09/23 06:26
10/09/23 22:24
106-50-3
<3.6
ug/L
10.0
3.6
1
10/09/23 06:26
10/09/23 22:24
298-02-2
<3.1
ug/L
10.0
3.1
1
10/09/23 06:26
10/09/23 22:24
23950-58-5
<2.2
ug/L
10.0
2.2
1
10/09/23 06:26
10/09/23 22:24
129-00-0
<2.3
ug/L
10.0
2.3
1
10/09/23 06:26
10/09/23 22:24
94-59-7
<4.5
ug/L
10.0
4.5
1
10/09/23 06:26
10/09/23 22:24
95-94-3
<1.5
ug/L
10.0
1.5
1
10/09/23 06:26
10/09/23 22:24
58-90-2
<2.9
ug/L
10.0
2.9
1
10/09/23 06:26
10/09/23 22:24
297-97-2
<2.6
ug/L
10.0
2.6
1
10/09/23 06:26
10/09/23 22:24
95-53-4
<1.4
ug/L
10.0
1.4
1
10/09/23 06:26
10/09/23 22:24
95-95-4
<1.6
ug/L
10.0
1.6
1
10/09/23 06:26
10/09/23 22:24
88-06-2
<5.5
ug/L
10.0
5.5
1
10/09/23 06:26
10/09/23 22:24
99-35-4
72
%
10-138
1
10/09/23 06:26
10/09/23 22:24
4165-60-0
67
%
10-130
1
10/09/23 06:26
10/09/23 22:24
321-60-8
85
%
19-191
1
10/09/23 06:26
10/09/23 22:24
1718-51-0
15
%
10-130
1
10/09/23 06:26
10/09/23 22:24
13127-88-3
6
%
10-130
1
10/09/23 06:26
10/09/23 22:24
367-12-4
16
%
10-164
1
10/09/23 06:26
10/09/23 22:24
118-79-6
REPORT OF LABORATORY ANALYSIS
v1
v1
SO
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: SW-02-20231004 Lab ID: 92691921003 Collected: 10/04/23 16:25 Received: 10/05/23 09:04 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
<5.1
ug/L
25.0
5.1
1
10/09/2313:22
67-64-1
<0.34
ug/L
1.0
0.34
1
10/09/2313:22
71-43-2
<0.29
ug/L
1.0
0.29
1
10/09/2313:22
108-86-1
<0.47
ug/L
1.0
0.47
1
10/09/2313:22
74-97-5
<0.31
ug/L
1.0
0.31
1
10/09/2313:22
75-27-4
<0.34
ug/L
1.0
0.34
1
10/09/2313:22
75-25-2
<1.7
ug/L
2.0
1.7
1
10/09/2313:22
74-83-9 v2
<4.0
ug/L
5.0
4.0
1
10/09/2313:22
78-93-3
<0.33
ug/L
1.0
0.33
1
10/09/2313:22
56-23-5
<0.28
ug/L
1.0
0.28
1
10/09/2313:22
108-90-7
<0.65
ug/L
1.0
0.65
1
10/09/2313:22
75-00-3
<0.43
ug/L
1.0
0.43
1
10/09/2313:22
67-66-3
<0.54
ug/L
1.0
0.54
1
10/09/2313:22
74-87-3
<0.32
ug/L
1.0
0.32
1
10/09/2313:22
95-49-8
<0.32
ug/L
1.0
0.32
1
10/09/2313:22
106-43-4
<0.34
ug/L
2.0
0.34
1
10/09/2313:22
96-12-8
<0.36
ug/L
1.0
0.36
1
10/09/2313:22
124-48-1
<0.27
ug/L
1.0
0.27
1
10/09/2313:22
106-93-4
<0.39
ug/L
1.0
0.39
1
10/09/2313:22
74-95-3
<0.34
ug/L
1.0
0.34
1
10/09/2313:22
95-50-1
<0.34
ug/L
1.0
0.34
1
10/09/2313:22
541-73-1
<0.33
ug/L
1.0
0.33
1
10/09/2313:22
106-46-7
<0.35
ug/L
1.0
0.35
1
10/09/2313:22
75-71-8
<0.37
ug/L
1.0
0.37
1
10/09/2313:22
75-34-3
<0.32
ug/L
1.0
0.32
1
10/09/2313:22
107-06-2
<0.35
ug/L
1.0
0.35
1
10/09/2313:22
75-35-4
<0.38
ug/L
1.0
0.38
1
10/09/2313:22
156-59-2
<0.40
ug/L
1.0
0.40
1
10/09/2313:22
156-60-5
<0.36
ug/L
1.0
0.36
1
10/09/2313:22
78-87-5
<0.28
ug/L
1.0
0.28
1
10/09/2313:22
142-28-9
<0.39
ug/L
1.0
0.39
1
10/09/2313:22
594-20-7
<0.43
ug/L
1.0
0.43
1
10/09/2313:22
563-58-6
<0.36
ug/L
1.0
0.36
1
10/09/2313:22
10061-01-5
<0.36
ug/L
1.0
0.36
1
10/09/2313:22
10061-02-6
<0.31
ug/L
1.0
0.31
1
10/09/2313:22
108-20-3
<0.30
ug/L
1.0
0.30
1
10/09/2313:22
100-41-4
<1.5
ug/L
2.0
1.5
1
10/09/2313:22
87-68-3
<0.48
ug/L
5.0
0.48
1
10/09/2313:22
591-78-6
<0.41
ug/L
1.0
0.41
1
10/09/2313:22
99-87-6
<2.0
ug/L
5.0
2.0
1
10/09/2313:22
75-09-2
<2.7
ug/L
5.0
2.7
1
10/09/2313:22
108-10-1
<0.42
ug/L
1.0
0.42
1
10/09/2313:22
1634-04-4
<0.64
ug/L
1.0
0.64
1
10/09/2313:22
91-20-3
<0.29
ug/L
1.0
0.29
1
10/09/2313:22
100-42-5
<0.31
ug/L
1.0
0.31
1
10/09/2313:22
630-20-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 21 of 229

Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: SW-02-20231004
Parameters
8260D MSV Low Level Landfill
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
Date: 02/23/2024 01:48 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Lab ID: 92691921003 Collected: 10/04/23 16:25 Received: 10/05/23 09:04 Matrix: Water
Results Units PQL
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
<0.22
ug/L
1.0
<0.29
ug/L
1.0
<0.24
ug/L
1.0
<0.81
ug/L
1.0
<0.64
ug/L
1.0
<0.33
ug/L
1.0
<0.32
ug/L
1.0
<0.38
ug/L
1.0
<0.30
ug/L
1.0
<0.26
ug/L
1.0
<1.3
ug/L
2.0
<0.39
ug/L
1.0
<0.34
ug/L
1.0
<0.71
ug/L
2.0
<0.34
ug/L
1.0
98
%
70-130
104
%
70-130
100
%
70-130
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
<0.86
ug/L
2.0
89
%
67-130
93
%
70-130
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services
-Asheville
<0.022
mg/L
0.10
MDL DF Prepared Analyzed CAS No. Qual
0.22
1
10/09/23 13:22
79-34-5
0.29
1
10/09/23 13:22
127-18-4
0.24
1
10/09/23 13:22
108-88-3
0.81
1
10/09/23 13:22
87-61-6
0.64
1
10/09/23 13:22
120-82-1
0.33
1
10/09/23 13:22
71-55-6
0.32
1
10/09/23 13:22
79-00-5
0.38
1
10/09/23 13:22
79-01-6
0.30
1
10/09/23 13:22
75-69-4
0.26
1
10/09/23 13:22
96-18-4
1.3
1
10/09/23 13:22
108-05-4
0.39
1
10/09/23 13:22
75-01-4
0.34
1
10/09/23 13:22
1330-20-7
0.71
1
10/09/23 13:22
179601-23-1
0.34
1
10/09/23 13:22
95-47-6
1
10/09/23 13:22
460-00-4
1
10/09/23 13:22
17060-07-0
1
10/09/23 13:22
2037-26-5
0.86 1
10/09/23 20:54
123-91-1
1
10/09/23 20:54
17060-07-0
1
10/09/23 20:54
2037-26-5
0.022 1
10/11/23 01:16
18496-25-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 22 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: SW-03-20231004 Lab ID: 92691921004 Collected: 10/04/23 17:50 Received: 10/05/23 09:04 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
<0.20
ug/L
1.0
0.20
1
10/10/2315:20
10/11/2314:49
7440-36-0
Arsenic
<0.087
ug/L
1.0
0.087
1
10/10/2315:20
10/11/2314:49
7440-38-2
Barium
10.7
ug/L
1.0
0.21
1
10/10/2315:20
10/11/2314:49
7440-39-3
Beryllium
<0.050
ug/L
0.10
0.050
1
10/10/2315:20
10/11/2314:49
7440-41-7
Cadmium
<0.060
ug/L
0.20
0.060
1
10/10/2315:20
10/11/2314:49
7440-43-9
Chromium
<0.50
ug/L
1.0
0.50
1
10/10/2315:20
10/11/2314:49
7440-47-3
Cobalt
0.094J
ug/L
1.0
0.050
1
10/10/2315:20
10/11/2314:49
7440-48-4
Copper
<1.1
ug/L
2.0
1.1
1
10/10/2315:20
10/11/2314:49
7440-50-8
Lead
<0.077
ug/L
1.0
0.077
1
10/10/2315:20
10/11/2314:49
7439-92-1
Nickel
<0.42
ug/L
1.0
0.42
1
10/10/2315:20
10/11/2314:49
7440-02-0
Selenium
<0.072
ug/L
2.0
0.072
1
10/10/2315:20
10/11/2314:49
7782-49-2
Silver
<0.070
ug/L
0.40
0.070
1
10/10/2315:20
10/11/2314:49
7440-22-4
Thallium
<0.050
ug/L
0.20
0.050
1
10/10/2315:20
10/11/2314:49
7440-28-0
Tin
<0.43
ug/L
1.0
0.43
1
10/10/2315:20
10/11/2314:49
7440-31-5
Hardness, Total(SM 2340B)
10400
ug/L
541
541
1
10/10/23 15:20
10/11/23 14:49
Vanadium
0.43J
ug/L
1.0
0.25
1
10/10/2315:20
10/11/2314:49
7440-62-2
7470 Mercury
Analytical Method: EPA 7470A Preparation Method: EPA
7470A
Pace Analytical Services
-Asheville
Mercury
<0.12
ug/L
0.20
0.12
1
10/13/2315:08
10/14/2311:38
7439-97-6
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method:
EPA
3510C
Pace Analytical Services - Charlotte
Acenaphthene
<0.17
ug/L
0.87
0.17
1
10/11/23 16:36
10/12/23 15:02
83-32-9
Acenaphthylene
<0.17
ug/L
0.87
0.17
1
10/11/23 16:36
10/12/23 15:02
208-96-8
Acetophenone
<0.13
ug/L
0.87
0.13
1
10/11/23 16:36
10/12/23 15:02
98-86-2
2-Acetylaminofluorene
<0.35
ug/L
0.87
0.35
1
10/11/23 16:36
10/12/23 15:02
53-96-3
4-Aminobiphenyl
<0.41
ug/L
0.87
0.41
1
10/11/23 16:36
10/12/23 15:02
92-67-1
Anthracene
<0.20
ug/L
0.87
0.20
1
10/11/23 16:36
10/12/23 15:02
120-12-7
Benzo(a)anthracene
<0.23
ug/L
0.87
0.23
1
10/11/23 16:36
10/12/23 15:02
56-55-3
Benzo(a)pyrene
<0.24
ug/L
0.87
0.24
1
10/11/23 16:36
10/12/23 15:02
50-32-8
Benzo(b)fluoranthene
<0.23
ug/L
0.87
0.23
1
10/11/23 16:36
10/12/23 15:02
205-99-2
Benzo(g,h,i)perylene
<0.25
ug/L
0.87
0.25
1
10/11/23 16:36
10/12/23 15:02
191-24-2
Benzo(k)fluoranthene
<0.24
ug/L
0.87
0.24
1
10/11/23 16:36
10/12/23 15:02
207-08-9
Benzyl alcohol
<0.25
ug/L
1.7
0.25
1
10/11/23 16:36
10/12/23 15:02
100-51-6
4-Bromophenylphenyl ether
<0.15
ug/L
0.87
0.15
1
10/11/23 16:36
10/12/23 15:02
101-55-3
Butylbenzylphthalate
<0.27
ug/L
0.87
0.27
1
10/11/23 16:36
10/12/23 15:02
85-68-7
4-Chloro-3-methyl phenol
<0.29
ug/L
0.87
0.29
1
10/11/23 16:36
10/12/23 15:02
59-50-7
4-Chloroaniline
<0.32
ug/L
1.7
0.32
1
10/11/23 16:36
10/12/23 15:02
106-47-8
Chlorobenzilate
<0.33
ug/L
0.87
0.33
1
10/11/23 16:36
10/12/23 15:02
510-15-6
bis(2-Chloroethoxy)methane
<0.16
ug/L
0.87
0.16
1
10/11/23 16:36
10/12/23 15:02
111-91-1
bis(2-Chloroethyl) ether
<0.17
ug/L
0.87
0.17
1
10/11/23 16:36
10/12/23 15:02
111-44-4
2-Chloronaphthalene
<0.15
ug/L
0.87
0.15
1
10/11/23 16:36
10/12/23 15:02
91-58-7
2-Chlorophenol
<0.10
ug/L
0.87
0.10
1
10/11/23 16:36
10/12/23 15:02
95-57-8
4-Chlorophenylphenyl ether
<0.17
ug/L
0.87
0.17
1
10/11/23 16:36
10/12/23 15:02
7005-72-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: SW-03-20231004 Lab ID: 92691921004 Collected: 10/04/23 17:50 Received: 10/05/23 09:04 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Chrysene
<0.24
ug/L
0.87
0.24
1
10/11/23 16:36
10/12/23 15:02
218-01-9
Diallate
<0.30
ug/L
0.87
0.30
1
10/11/23 16:36
10/12/23 15:02
2303-16-4
Dibenz(a,h)anthracene
<0.26
ug/L
0.87
0.26
1
10/11/23 16:36
10/12/23 15:02
53-70-3
Dibenzofuran
<0.18
ug/L
0.87
0.18
1
10/11/23 16:36
10/12/23 15:02
132-64-9
3,3'-Dichlorobenzidine
<0.71
ug/L
1.7
0.71
1
10/11/23 16:36
10/12/23 15:02
91-94-1
2,4-Dichlorophenol
<0.12
ug/L
0.87
0.12
1
10/11/23 16:36
10/12/23 15:02
120-83-2
2,6-Dichlorophenol
<0.37
ug/L
0.87
0.37
1
10/11/23 16:36
10/12/23 15:02
87-65-0
Diethylphthalate
<0.18
ug/L
0.87
0.18
1
10/11/23 16:36
10/12/23 15:02
84-66-2
Dimethoate
<0.32
ug/L
0.87
0.32
1
10/11/23 16:36
10/12/23 15:02
60-51-5
P-Dimethylaminoazobenzene
<0.21
ug/L
0.43
0.21
1
10/11/23 16:36
10/12/23 15:02
60-11-7
7,12-Dimethylbenz(a)anthracene
<0.26
ug/L
0.87
0.26
1
10/11/23 16:36
10/12/23 15:02
57-97-6
3,3'-Dimethylbenzidine
<2.7
ug/L
4.3
2.7
1
10/11/23 16:36
10/12/23 15:02
119-93-7
2,4-Dimethylphenol
<0.15
ug/L
0.87
0.15
1
10/11/23 16:36
10/12/23 15:02
105-67-9
Dimethylphthalate
<0.19
ug/L
0.87
0.19
1
10/11/23 16:36
10/12/23 15:02
131-11-3
Di-n-butylphthalate
<0.19
ug/L
0.87
0.19
1
10/11/23 16:36
10/12/23 15:02
84-74-2
4,6-Dinitro-2-methyl phenol
<0.68
ug/L
1.7
0.68
1
10/11/23 16:36
10/12/23 15:02
534-52-1
1,3-Dinitrobenzene
<0.33
ug/L
0.87
0.33
1
10/11/23 16:36
10/12/23 15:02
99-65-0
2,4-Dinitrophenol
<2.3
ug/L
4.3
2.3
1
10/11/23 16:36
10/12/23 15:02
51-28-5
2,4-Dinitrotoluene
<0.14
ug/L
0.87
0.14
1
10/11/23 16:36
10/12/23 15:02
121-14-2
2,6-Dinitrotoluene
<0.15
ug/L
0.87
0.15
1
10/11/23 16:36
10/12/23 15:02
606-20-2
Di-n-octylphthalate
<0.34
ug/L
0.87
0.34
1
10/11/23 16:36
10/12/23 15:02
117-84-0
Diphenylamine
<0.26
ug/L
0.87
0.26
1
10/11/23 16:36
10/12/23 15:02
122-39-4
Disulfoton
<0.40
ug/L
0.87
0.40
1
10/11/23 16:36
10/12/23 15:02
298-04-4
bis(2- Ethyl hexyl)phthalate
<0.32
ug/L
0.52
0.32
1
10/11/23 16:36
10/12/23 15:02
117-81-7
Ethyl methanesulfonate
<0.26
ug/L
1.7
0.26
1
10/11/23 16:36
10/12/23 15:02
62-50-0
Famphur
<0.53
ug/L
0.87
0.53
1
10/11/23 16:36
10/12/23 15:02
52-85-7
Fluoranthene
<0.19
ug/L
0.87
0.19
1
10/11/23 16:36
10/12/23 15:02
206-44-0
Fluorene
<0.18
ug/L
0.87
0.18
1
10/11/23 16:36
10/12/23 15:02
86-73-7
Hexachlorobenzene
<0.19
ug/L
0.87
0.19
1
10/11/23 16:36
10/12/23 15:02
118-74-1
Hexachlorocyclopentadiene
<0.14
ug/L
0.87
0.14
1
10/11/23 16:36
10/12/23 15:02
77-47-4
Hexachloroethane
<0.12
ug/L
0.87
0.12
1
10/11/23 16:36
10/12/23 15:02
67-72-1
Hexachloropropene
<0.23
ug/L
0.87
0.23
1
10/11/23 16:36
10/12/23 15:02
1888-71-7
Indeno(1,2,3-cd)pyrene
<0.25
ug/L
0.87
0.25
1
10/11/23 16:36
10/12/23 15:02
193-39-5
Isodrin
<0.24
ug/L
0.87
0.24
1
10/11/23 16:36
10/12/23 15:02
465-73-6
Isophorone
<0.14
ug/L
0.87
0.14
1
10/11/23 16:36
10/12/23 15:02
78-59-1
Isosafrole
<0.22
ug/L
0.87
0.22
1
10/11/23 16:36
10/12/23 15:02
120-58-1
Kepone
<1.2
ug/L
1.7
1.2
1
10/11/23 16:36
10/12/23 15:02
143-50-0
Methapyrilene
<1.5
ug/L
4.3
1.5
1
10/11/23 16:36
10/12/23 15:02
91-80-5
3-Methylcholanthrene
<0.33
ug/L
0.87
0.33
1
10/11/23 16:36
10/12/23 15:02
56-49-5
Methyl methanesulfonate
<0.27
ug/L
0.43
0.27
1
10/11/23 16:36
10/12/23 15:02
66-27-3
2-Methylnaphthalene
<0.16
ug/L
0.87
0.16
1
10/11/23 16:36
10/12/23 15:02
91-57-6
Methyl parathion
<0.32
ug/L
0.87
0.32
1
10/11/23 16:36
10/12/23 15:02
298-00-0
2-Methylphenol(o-Cresol)
<0.16
ug/L
0.87
0.16
1
10/11/23 16:36
10/12/23 15:02
95-48-7
3&4-Methyl phenol (m&p Cresol)
<0.11
ug/L
0.87
0.11
1
10/11/23 16:36
10/12/23 15:02
15831-10-4
1-Naphthalenamine
<0.52
ug/L
0.87
0.52
1
10/11/23 16:36
10/12/23 15:02
134-32-7
REPORT OF LABORATORY ANALYSIS
IL
IH,L2
L1
v1
v1
L2
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: SW-03-20231004 Lab ID: 92691921004 Collected: 10/04/23 17:50 Received: 10/05/23 09:04 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
2-Naphthalenamine
1,4-Naphthoquinone
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
5-Nitro-o-toluidine
N-Nitrosodiethylamine
N-Nitrosodimethylamine
N-Nitroso-di-n-butylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
N-Nitrosomethylethylamine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
O, O,O-Triethyl phosphorothioate
2,2'-Oxybis(1-chloropropane)
Parathion (Ethyl parathion)
Pentachlorobenzene
Pentachloronitrobenzene
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
p-Phenylenediamine
Phorate
Pronamide
Pyrene
Safrole
1,2,4,5-Tetrachlorobenzene
2,3,4,6-Tetrachlorophenol
Thionazin
O-Toluidine
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
1,3,5-Trinitrobenzene
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
<0.47
ug/L
0.87
0.47
1
10/11/2316:36
10/12/2315:02
91-59-8
<0.38
ug/L
0.43
0.38
1
10/11/2316:36
10/12/2315:02
130-15-4
<0.26
ug/L
1.7
0.26
1
10/11/2316:36
10/12/2315:02
88-74-4
<0.33
ug/L
1.7
0.33
1
10/11/2316:36
10/12/2315:02
99-09-2
<0.44
ug/L
1.7
0.44
1
10/11/2316:36
10/12/2315:02
100-01-6
<0.16
ug/L
0.87
0.16
1
10/11/2316:36
10/12/2315:02
98-95-3
<0.12
ug/L
0.87
0.12
1
10/11/2316:36
10/12/2315:02
88-75-5
<0.57
ug/L
4.3
0.57
1
10/11/2316:36
10/12/2315:02
100-02-7
<0.33
ug/L
0.87
0.33
1
10/11/2316:36
10/12/2315:02
99-55-8
<0.20
ug/L
0.87
0.20
1
10/11/2316:36
10/12/2315:02
55-18-5
<0.16
ug/L
0.87
0.16
1
10/11/2316:36
10/12/2315:02
62-75-9
<0.17
ug/L
0.87
0.17
1
10/11/2316:36
10/12/2315:02
924-16-3
<0.12
ug/L
0.87
0.12
1
10/11/2316:36
10/12/2315:02
621-64-7
<0.26
ug/L
0.87
0.26
1
10/11/2316:36
10/12/2315:02
86-30-6
<0.65
ug/L
0.87
0.65
1
10/11/2316:36
10/12/2315:02
10595-95-6
<0.22
ug/L
0.87
0.22
1
10/11/2316:36
10/12/2315:02
100-75-4
<0.27
ug/L
0.87
0.27
1
10/11/2316:36
10/12/2315:02
930-55-2
<0.22
ug/L
0.87
0.22
1
10/11/2316:36
10/12/2315:02
126-68-1
<0.10
ug/L
0.87
0.10
1
10/11/2316:36
10/12/2315:02
108-60-1
<0.34
ug/L
0.87
0.34
1
10/11/2316:36
10/12/2315:02
56-38-2
<0.30
ug/L
0.87
0.30
1
10/11/2316:36
10/12/2315:02
608-93-5
<0.28
ug/L
0.87
0.28
1
10/11/2316:36
10/12/2315:02
82-68-8
<0.33
ug/L
1.7
0.33
1
10/11/2316:36
10/12/2315:02
87-86-5
<0.31
ug/L
0.87
0.31
1
10/11/2316:36
10/12/2315:02
62-44-2
<0.17
ug/L
0.87
0.17
1
10/11/2316:36
10/12/2315:02
85-01-8
<0.12
ug/L
0.87
0.12
1
10/11/2316:36
10/12/2315:02
108-95-2
<0.87
ug/L
0.87
0.87
1
10/11/2316:36
10/12/2315:02
106-50-3
<0.31
ug/L
0.87
0.31
1
10/11/2316:36
10/12/2315:02
298-02-2
<0.27
ug/L
0.87
0.27
1
10/11/2316:36
10/12/2315:02
23950-58-5
<0.19
ug/L
0.87
0.19
1
10/11/2316:36
10/12/2315:02
129-00-0
<0.20
ug/L
0.87
0.20
1
10/11/2316:36
10/12/2315:02
94-59-7
<0.39
ug/L
0.87
0.39
1
10/11/2316:36
10/12/2315:02
95-94-3
<0.13
ug/L
0.87
0.13
1
10/11/2316:36
10/12/2315:02
58-90-2
<0.25
ug/L
0.87
0.25
1
10/11/2316:36
10/12/2315:02
297-97-2
<0.23
ug/L
0.87
0.23
1
10/11/2316:36
10/12/2315:02
95-53-4
<0.12
ug/L
0.87
0.12
1
10/11/2316:36
10/12/2315:02
95-95-4
<0.13
ug/L
0.87
0.13
1
10/11/2316:36
10/12/2315:02
88-06-2
<0.48
ug/L
0.87
0.48
1
10/11/2316:36
10/12/2315:02
99-35-4
95
%
10-138
1
10/11/2316:36
10/12/2315:02
4165-60-0
95
%
10-130
1
10/11/2316:36
10/12/2315:02
321-60-8
120
%
19-191
1
10/11/2316:36
10/12/2315:02
1718-51-0
27
%
10-130
1
10/11/2316:36
10/12/2315:02
13127-88-3
9
%
10-130
1
10/11/2316:36
10/12/2315:02
367-12-4
24
%
10-164
1
10/11/2316:36
10/12/2315:02
118-79-6
REPORT OF LABORATORY ANALYSIS
v1
L1
v2
SO
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: SW-03-20231004 Lab ID: 92691921004 Collected: 10/04/23 17:50 Received: 10/05/23 09:04 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
<5.1
ug/L
25.0
5.1
1
10/09/2318:17
67-64-1
<0.34
ug/L
1.0
0.34
1
10/09/2318:17
71-43-2
<0.29
ug/L
1.0
0.29
1
10/09/2318:17
108-86-1
<0.47
ug/L
1.0
0.47
1
10/09/2318:17
74-97-5
<0.31
ug/L
1.0
0.31
1
10/09/2318:17
75-27-4
<0.34
ug/L
1.0
0.34
1
10/09/2318:17
75-25-2
<1.7
ug/L
2.0
1.7
1
10/09/2318:17
74-83-9 v2
<4.0
ug/L
5.0
4.0
1
10/09/2318:17
78-93-3
<0.33
ug/L
1.0
0.33
1
10/09/2318:17
56-23-5
<0.28
ug/L
1.0
0.28
1
10/09/2318:17
108-90-7
<0.65
ug/L
1.0
0.65
1
10/09/2318:17
75-00-3
<0.43
ug/L
1.0
0.43
1
10/09/2318:17
67-66-3
<0.54
ug/L
1.0
0.54
1
10/09/2318:17
74-87-3
<0.32
ug/L
1.0
0.32
1
10/09/2318:17
95-49-8
<0.32
ug/L
1.0
0.32
1
10/09/2318:17
106-43-4
<0.34
ug/L
2.0
0.34
1
10/09/2318:17
96-12-8
<0.36
ug/L
1.0
0.36
1
10/09/2318:17
124-48-1
<0.27
ug/L
1.0
0.27
1
10/09/2318:17
106-93-4
<0.39
ug/L
1.0
0.39
1
10/09/2318:17
74-95-3
<0.34
ug/L
1.0
0.34
1
10/09/2318:17
95-50-1
<0.34
ug/L
1.0
0.34
1
10/09/2318:17
541-73-1
<0.33
ug/L
1.0
0.33
1
10/09/2318:17
106-46-7
<0.35
ug/L
1.0
0.35
1
10/09/2318:17
75-71-8
<0.37
ug/L
1.0
0.37
1
10/09/2318:17
75-34-3
<0.32
ug/L
1.0
0.32
1
10/09/2318:17
107-06-2
<0.35
ug/L
1.0
0.35
1
10/09/2318:17
75-35-4
<0.38
ug/L
1.0
0.38
1
10/09/2318:17
156-59-2
<0.40
ug/L
1.0
0.40
1
10/09/2318:17
156-60-5
<0.36
ug/L
1.0
0.36
1
10/09/2318:17
78-87-5
<0.28
ug/L
1.0
0.28
1
10/09/2318:17
142-28-9
<0.39
ug/L
1.0
0.39
1
10/09/2318:17
594-20-7
<0.43
ug/L
1.0
0.43
1
10/09/2318:17
563-58-6
<0.36
ug/L
1.0
0.36
1
10/09/2318:17
10061-01-5
<0.36
ug/L
1.0
0.36
1
10/09/2318:17
10061-02-6
<0.31
ug/L
1.0
0.31
1
10/09/2318:17
108-20-3
<0.30
ug/L
1.0
0.30
1
10/09/2318:17
100-41-4
<1.5
ug/L
2.0
1.5
1
10/09/2318:17
87-68-3
<0.48
ug/L
5.0
0.48
1
10/09/2318:17
591-78-6
<0.41
ug/L
1.0
0.41
1
10/09/2318:17
99-87-6
<2.0
ug/L
5.0
2.0
1
10/09/2318:17
75-09-2
<2.7
ug/L
5.0
2.7
1
10/09/2318:17
108-10-1
<0.42
ug/L
1.0
0.42
1
10/09/2318:17
1634-04-4
<0.64
ug/L
1.0
0.64
1
10/09/2318:17
91-20-3
<0.29
ug/L
1.0
0.29
1
10/09/2318:17
100-42-5
<0.31
ug/L
1.0
0.31
1
10/09/2318:17
630-20-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 26 of 229

Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: SW-03-20231004
Parameters
8260D MSV Low Level Landfill
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
Date: 02/23/2024 01:48 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Lab ID: 92691921004 Collected: 10/04/23 17:50 Received: 10/05/23 09:04 Matrix: Water
Results Units PQL
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
<0.22
ug/L
1.0
<0.29
ug/L
1.0
<0.24
ug/L
1.0
<0.81
ug/L
1.0
<0.64
ug/L
1.0
<0.33
ug/L
1.0
<0.32
ug/L
1.0
<0.38
ug/L
1.0
<0.30
ug/L
1.0
<0.26
ug/L
1.0
<1.3
ug/L
2.0
<0.39
ug/L
1.0
<0.34
ug/L
1.0
<0.71
ug/L
2.0
<0.34
ug/L
1.0
97
%
70-130
102
%
70-130
100
%
70-130
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
<0.86
ug/L
2.0
88
%
67-130
93
%
70-130
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services
-Asheville
<0.022
mg/L
0.10
MDL DF Prepared Analyzed CAS No. Qual
0.22
1
10/09/23 18:17
79-34-5
0.29
1
10/09/23 18:17
127-18-4
0.24
1
10/09/23 18:17
108-88-3
0.81
1
10/09/23 18:17
87-61-6
0.64
1
10/09/23 18:17
120-82-1
0.33
1
10/09/23 18:17
71-55-6
0.32
1
10/09/23 18:17
79-00-5
0.38
1
10/09/23 18:17
79-01-6
0.30
1
10/09/23 18:17
75-69-4
0.26
1
10/09/23 18:17
96-18-4
1.3
1
10/09/23 18:17
108-05-4
0.39
1
10/09/23 18:17
75-01-4
0.34
1
10/09/23 18:17
1330-20-7
0.71
1
10/09/23 18:17
179601-23-1
0.34
1
10/09/23 18:17
95-47-6
1
10/09/23 18:17
460-00-4
1
10/09/23 18:17
17060-07-0
1
10/09/23 18:17
2037-26-5
0.86 1
10/09/23 21:15
123-91-1
1
10/09/23 21:15
17060-07-0
1
10/09/23 21:15
2037-26-5
0.022 1
10/11/23 01:17
18496-25-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 27 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: TB-20231004 Lab ID: 92691921005 Collected: 10/04/23 00:00 Received: 10/05/23 09:04 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
<5.1
ug/L
25.0
5.1
1
10/09/2310:35
67-64-1
<0.34
ug/L
1.0
0.34
1
10/09/2310:35
71-43-2
<0.29
ug/L
1.0
0.29
1
10/09/2310:35
108-86-1
<0.47
ug/L
1.0
0.47
1
10/09/2310:35
74-97-5
<0.31
ug/L
1.0
0.31
1
10/09/2310:35
75-27-4
<0.34
ug/L
1.0
0.34
1
10/09/2310:35
75-25-2
<1.7
ug/L
2.0
1.7
1
10/09/2310:35
74-83-9 v2
<4.0
ug/L
5.0
4.0
1
10/09/2310:35
78-93-3
<0.33
ug/L
1.0
0.33
1
10/09/2310:35
56-23-5
<0.28
ug/L
1.0
0.28
1
10/09/2310:35
108-90-7
<0.65
ug/L
1.0
0.65
1
10/09/2310:35
75-00-3
<0.43
ug/L
1.0
0.43
1
10/09/2310:35
67-66-3
<0.54
ug/L
1.0
0.54
1
10/09/2310:35
74-87-3
<0.32
ug/L
1.0
0.32
1
10/09/2310:35
95-49-8
<0.32
ug/L
1.0
0.32
1
10/09/2310:35
106-43-4
<0.34
ug/L
2.0
0.34
1
10/09/2310:35
96-12-8
<0.36
ug/L
1.0
0.36
1
10/09/2310:35
124-48-1
<0.27
ug/L
1.0
0.27
1
10/09/2310:35
106-93-4
<0.39
ug/L
1.0
0.39
1
10/09/2310:35
74-95-3
<0.34
ug/L
1.0
0.34
1
10/09/2310:35
95-50-1
<0.34
ug/L
1.0
0.34
1
10/09/2310:35
541-73-1
<0.33
ug/L
1.0
0.33
1
10/09/2310:35
106-46-7
<0.35
ug/L
1.0
0.35
1
10/09/2310:35
75-71-8
<0.37
ug/L
1.0
0.37
1
10/09/2310:35
75-34-3
<0.32
ug/L
1.0
0.32
1
10/09/2310:35
107-06-2
<0.35
ug/L
1.0
0.35
1
10/09/2310:35
75-35-4
<0.38
ug/L
1.0
0.38
1
10/09/2310:35
156-59-2
<0.40
ug/L
1.0
0.40
1
10/09/2310:35
156-60-5
<0.36
ug/L
1.0
0.36
1
10/09/2310:35
78-87-5
<0.28
ug/L
1.0
0.28
1
10/09/2310:35
142-28-9
<0.39
ug/L
1.0
0.39
1
10/09/2310:35
594-20-7
<0.43
ug/L
1.0
0.43
1
10/09/2310:35
563-58-6
<0.36
ug/L
1.0
0.36
1
10/09/2310:35
10061-01-5
<0.36
ug/L
1.0
0.36
1
10/09/2310:35
10061-02-6
<0.31
ug/L
1.0
0.31
1
10/09/2310:35
108-20-3
<0.30
ug/L
1.0
0.30
1
10/09/2310:35
100-41-4
<1.5
ug/L
2.0
1.5
1
10/09/2310:35
87-68-3
<0.48
ug/L
5.0
0.48
1
10/09/2310:35
591-78-6
<0.41
ug/L
1.0
0.41
1
10/09/2310:35
99-87-6
<2.0
ug/L
5.0
2.0
1
10/09/2310:35
75-09-2
<2.7
ug/L
5.0
2.7
1
10/09/2310:35
108-10-1
<0.42
ug/L
1.0
0.42
1
10/09/2310:35
1634-04-4
<0.64
ug/L
1.0
0.64
1
10/09/2310:35
91-20-3
<0.29
ug/L
1.0
0.29
1
10/09/2310:35
100-42-5
<0.31
ug/L
1.0
0.31
1
10/09/2310:35
630-20-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 28 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: TB-20231004
Lab ID:
92691921005
Collected:
10/04/23
00:00
Received: 10/05/23 09:04 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,2,2-Tetrachloroethane
<0.22
ug/L
1.0
0.22
1
10/09/23 10:35
79-34-5
Tetrachloroethene
<0.29
ug/L
1.0
0.29
1
10/09/23 10:35
127-18-4
Toluene
<0.24
ug/L
1.0
0.24
1
10/09/23 10:35
108-88-3
1,2,3-Trichlorobenzene
<0.81
ug/L
1.0
0.81
1
10/09/23 10:35
87-61-6
1,2,4-Trichlorobenzene
<0.64
ug/L
1.0
0.64
1
10/09/23 10:35
120-82-1
1,1,1-Trichloroethane
<0.33
ug/L
1.0
0.33
1
10/09/23 10:35
71-55-6
1,1,2-Trichloroethane
<0.32
ug/L
1.0
0.32
1
10/09/23 10:35
79-00-5
Trichloroethene
<0.38
ug/L
1.0
0.38
1
10/09/23 10:35
79-01-6
Trichlorofluoromethane
<0.30
ug/L
1.0
0.30
1
10/09/23 10:35
75-69-4
1,2,3-Trichloropropane
<0.26
ug/L
1.0
0.26
1
10/09/23 10:35
96-18-4
Vinyl acetate
<1.3
ug/L
2.0
1.3
1
10/09/23 10:35
108-05-4
Vinyl chloride
<0.39
ug/L
1.0
0.39
1
10/09/23 10:35
75-01-4
Xylene (Total)
<0.34
ug/L
1.0
0.34
1
10/09/23 10:35
1330-20-7
m&p-Xylene
<0.71
ug/L
2.0
0.71
1
10/09/23 10:35
179601-23-1
o-Xylene
<0.34
ug/L
1.0
0.34
1
10/09/23 10:35
95-47-6
Surrogates
4-Bromofluorobenzene (S)
97
%
70-130
1
10/09/23 10:35
460-00-4
1,2-Dichloroethane-d4 (S)
102
%
70-130
1
10/09/23 10:35
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
10/09/23 10:35
2037-26-5
Date: 02/23/2024 01:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 29 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: MW-06-20231005 Lab ID: 92691980001 Collected: 10/05/23 15:42 Received: 10/06/23 11:51 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Ethane
<5.9
ug/L
10.0
5.9
1
10/12/2313:59
74-84-0
Ethene
<5.7
ug/L
10.0
5.7
1
10/12/2313:59
74-85-1
Methane
<5.3
ug/L
10.0
5.3
1
10/12/2313:59
74-82-8
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Antimony
<0.20
ug/L
1.0
0.20
1
10/10/2315:20
10/11/2314:54
7440-36-0
Arsenic
<0.087
ug/L
1.0
0.087
1
10/10/2315:20
10/11/2314:54
7440-38-2
Barium
49.5
ug/L
1.0
0.21
1
10/10/2315:20
10/11/2314:54
7440-39-3
Beryllium
0.056J
ug/L
0.10
0.050
1
10/10/2315:20
10/11/2314:54
7440-41-7
Cadmium
0.12J
ug/L
0.20
0.060
1
10/10/2315:20
10/11/2314:54
7440-43-9
Chromium
0.61J
ug/L
1.0
0.50
1
10/10/2315:20
10/11/2314:54
7440-47-3
Cobalt
3.3
ug/L
1.0
0.050
1
10/10/2315:20
10/11/2314:54
7440-48-4
Copper
1.4J
ug/L
2.0
1.1
1
10/10/2315:20
10/11/2314:54
7440-50-8
Iron
47.9J
ug/L
50.0
20.9
1
10/18/2312:10
10/18/2319:05
7439-89-6
Lead
0.14J
ug/L
1.0
0.077
1
10/10/2315:20
10/11/2314:54
7439-92-1
Nickel
4.0
ug/L
1.0
0.42
1
10/10/2315:20
10/11/2314:54
7440-02-0
Selenium
<0.072
ug/L
2.0
0.072
1
10/10/2315:20
10/11/2314:54
7782-49-2
Silver
<0.070
ug/L
0.40
0.070
1
10/10/2315:20
10/11/2314:54
7440-22-4
Thallium
0.24
ug/L
0.20
0.050
1
10/10/2315:20
10/11/2314:54
7440-28-0
Tin
<0.43
ug/L
1.0
0.43
1
10/10/2315:20
10/11/2314:54
7440-31-5
Vanadium
0.41J
ug/L
1.0
0.25
1
10/10/2315:20
10/11/2314:54
7440-62-2
7470 Mercury
Mercury
8270E APP9 RV
Acenaphthene
Acenaphthylene
Acetophenone
2-Acetylaminofluorene
4-Aminobiphenyl
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Benzyl alcohol
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methyl phenol
4-Chloroaniline
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
<0.12 ug/L 0.20 0.12 1 10/13/2315:08 10/14/2311:40 7439-97-6
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
<1.8
ug/L
9.1
1.8
1
10/09/23 06:26
10/09/23 21:59
83-32-9
<1.8
ug/L
9.1
1.8
1
10/09/23 06:26
10/09/23 21:59
208-96-8
<1.4
ug/L
9.1
1.4
1
10/09/23 06:26
10/09/23 21:59
98-86-2
<3.7
ug/L
9.1
3.7
1
10/09/23 06:26
10/09/23 21:59
53-96-3
<4.3
ug/L
9.1
4.3
1
10/09/23 06:26
10/09/23 21:59
92-67-1
<2.1
ug/L
9.1
2.1
1
10/09/23 06:26
10/09/23 21:59
120-12-7
<2.4
ug/L
9.1
2.4
1
10/09/23 06:26
10/09/23 21:59
56-55-3
<2.5
ug/L
9.1
2.5
1
10/09/23 06:26
10/09/23 21:59
50-32-8
<2.4
ug/L
9.1
2.4
1
10/09/23 06:26
10/09/23 21:59
205-99-2
<2.6
ug/L
9.1
2.6
1
10/09/23 06:26
10/09/23 21:59
191-24-2
<2.5
ug/L
9.1
2.5
1
10/09/23 06:26
10/09/23 21:59
207-08-9
<2.6
ug/L
18.2
2.6
1
10/09/23 06:26
10/09/23 21:59
100-51-6
<1.6
ug/L
9.1
1.6
1
10/09/23 06:26
10/09/23 21:59
101-55-3
<2.9
ug/L
9.1
2.9
1
10/09/23 06:26
10/09/23 21:59
85-68-7
<3.0
ug/L
9.1
3.0
1
10/09/23 06:26
10/09/23 21:59
59-50-7
<3.3
ug/L
18.2
3.3
1
10/09/23 06:26
10/09/23 21:59
106-47-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 30 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-06-20231005 Lab ID: 92691980001 Collected: 10/05/23 15:42 Received: 10/06/23 11:51 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Chlorobenzilate
<3.4
ug/L
9.1
3.4
1
10/09/23 06:26
10/09/23 21:59
510-15-6
bis(2-Chloroethoxy)methane
<1.7
ug/L
9.1
1.7
1
10/09/23 06:26
10/09/23 21:59
111-91-1
bis(2-Chloroethyl) ether
<1.7
ug/L
9.1
1.7
1
10/09/23 06:26
10/09/23 21:59
111-44-4
2-Chloronaphthalene
<1.6
ug/L
9.1
1.6
1
10/09/23 06:26
10/09/23 21:59
91-58-7
2-Chlorophenol
<1.1
ug/L
9.1
1.1
1
10/09/23 06:26
10/09/23 21:59
95-57-8
4-Chlorophenylphenyl ether
<1.8
ug/L
9.1
1.8
1
10/09/23 06:26
10/09/23 21:59
7005-72-3
Chrysene
<2.5
ug/L
9.1
2.5
1
10/09/23 06:26
10/09/23 21:59
218-01-9
Diallate
<3.1
ug/L
9.1
3.1
1
10/09/23 06:26
10/09/23 21:59
2303-16-4
Dibenz(a,h)anthracene
<2.7
ug/L
9.1
2.7
1
10/09/23 06:26
10/09/23 21:59
53-70-3
Dibenzofuran
<1.9
ug/L
9.1
1.9
1
10/09/23 06:26
10/09/23 21:59
132-64-9
3,3'-Dichlorobenzidine
<7.4
ug/L
18.2
7.4
1
10/09/23 06:26
10/09/23 21:59
91-94-1
2,4-Dichlorophenol
<1.3
ug/L
9.1
1.3
1
10/09/23 06:26
10/09/23 21:59
120-83-2
2,6-Dichlorophenol
<3.8
ug/L
9.1
3.8
1
10/09/23 06:26
10/09/23 21:59
87-65-0
Diethylphthalate
<1.9
ug/L
9.1
1.9
1
10/09/23 06:26
10/09/23 21:59
84-66-2
Dimethoate
<3.3
ug/L
9.1
3.3
1
10/09/23 06:26
10/09/23 21:59
60-51-5
P-Dimethylaminoazobenzene
<2.2
ug/L
4.5
2.2
1
10/09/23 06:26
10/09/23 21:59
60-11-7
7,12-Dimethylbenz(a)anthracene
<2.7
ug/L
9.1
2.7
1
10/09/23 06:26
10/09/23 21:59
57-97-6
3,3'-Dimethylbenzidine
<28.3
ug/L
45.5
28.3
1
10/09/23 06:26
10/09/23 21:59
119-93-7
2,4-Dimethylphenol
<1.5
ug/L
9.1
1.5
1
10/09/23 06:26
10/09/23 21:59
105-67-9
Dimethylphthalate
<1.9
ug/L
9.1
1.9
1
10/09/23 06:26
10/09/23 21:59
131-11-3
Di-n-butylphthalate
<2.0
ug/L
9.1
2.0
1
10/09/23 06:26
10/09/23 21:59
84-74-2
4,6-Dinitro-2-methyl phenol
<7.1
ug/L
18.2
7.1
1
10/09/23 06:26
10/09/23 21:59
534-52-1
1,3-Dinitrobenzene
<3.4
ug/L
9.1
3.4
1
10/09/23 06:26
10/09/23 21:59
99-65-0
2,4-Dinitrophenol
<23.6
ug/L
45.5
23.6
1
10/09/23 06:26
10/09/23 21:59
51-28-5
2,4-Dinitrotoluene
<1.5
ug/L
9.1
1.5
1
10/09/23 06:26
10/09/23 21:59
121-14-2
2,6-Dinitrotoluene
<1.6
ug/L
9.1
1.6
1
10/09/23 06:26
10/09/23 21:59
606-20-2
Di-n-octylphthalate
<3.6
ug/L
9.1
3.6
1
10/09/23 06:26
10/09/23 21:59
117-84-0
Diphenylamine
<2.7
ug/L
9.1
2.7
1
10/09/23 06:26
10/09/23 21:59
122-39-4
Disulfoton
<4.2
ug/L
9.1
4.2
1
10/09/23 06:26
10/09/23 21:59
298-04-4
bis(2- Ethyl hexyl)phthalate
<3.4
ug/L
5.5
3.4
1
10/09/23 06:26
10/09/23 21:59
117-81-7
Ethyl methanesulfonate
<2.7
ug/L
18.2
2.7
1
10/09/23 06:26
10/09/23 21:59
62-50-0
Famphur
<5.6
ug/L
9.1
5.6
1
10/09/23 06:26
10/09/23 21:59
52-85-7
Fluoranthene
<2.0
ug/L
9.1
2.0
1
10/09/23 06:26
10/09/23 21:59
206-44-0
Fluorene
<1.9
ug/L
9.1
1.9
1
10/09/23 06:26
10/09/23 21:59
86-73-7
Hexachlorobenzene
<2.0
ug/L
9.1
2.0
1
10/09/23 06:26
10/09/23 21:59
118-74-1
Hexachlorocyclopentadiene
<1.4
ug/L
9.1
1.4
1
10/09/23 06:26
10/09/23 21:59
77-47-4
Hexachloroethane
<1.3
ug/L
9.1
1.3
1
10/09/23 06:26
10/09/23 21:59
67-72-1
Hexachloropropene
<2.5
ug/L
9.1
2.5
1
10/09/23 06:26
10/09/23 21:59
1888-71-7
Indeno(1,2,3-cd)pyrene
<2.6
ug/L
9.1
2.6
1
10/09/23 06:26
10/09/23 21:59
193-39-5
Isodrin
<2.5
ug/L
9.1
2.5
1
10/09/23 06:26
10/09/23 21:59
465-73-6
Isophorone
<1.5
ug/L
9.1
1.5
1
10/09/23 06:26
10/09/23 21:59
78-59-1
Isosafrole
<2.3
ug/L
9.1
2.3
1
10/09/23 06:26
10/09/23 21:59
120-58-1
Kepone
<12.8
ug/L
18.2
12.8
1
10/09/23 06:26
10/09/23 21:59
143-50-0
Methapyrilene
<15.5
ug/L
45.5
15.5
1
10/09/23 06:26
10/09/23 21:59
91-80-5
3-Methylcholanthrene
<3.4
ug/L
9.1
3.4
1
10/09/23 06:26
10/09/23 21:59
56-49-5
REPORT OF LABORATORY ANALYSIS
IL
v1
v1
v1
L2
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-06-20231005 Lab ID: 92691980001 Collected: 10/05/23 15:42 Received: 10/06/23 11:51 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Methyl methanesulfonate
<2.8
ug/L
4.5
2.8
1
10/09/23 06:26
10/09/23 21:59
66-27-3
2-Methylnaphthalene
<1.7
ug/L
9.1
1.7
1
10/09/23 06:26
10/09/23 21:59
91-57-6
Methyl parathion
<3.4
ug/L
9.1
3.4
1
10/09/23 06:26
10/09/23 21:59
298-00-0
2-Methylphenol(o-Cresol)
<1.7
ug/L
9.1
1.7
1
10/09/23 06:26
10/09/23 21:59
95-48-7
3&4-Methyl phenol (m&p Cresol)
<1.1
ug/L
9.1
1.1
1
10/09/23 06:26
10/09/23 21:59
15831-10-4
1-Naphthalenamine
<5.5
ug/L
9.1
5.5
1
10/09/23 06:26
10/09/23 21:59
134-32-7
2-Naphthalenamine
<5.0
ug/L
9.1
5.0
1
10/09/23 06:26
10/09/23 21:59
91-59-8
1,4-Naphthoquinone
<4.0
ug/L
4.5
4.0
1
10/09/23 06:26
10/09/23 21:59
130-15-4
2-Nitroaniline
<2.7
ug/L
18.2
2.7
1
10/09/23 06:26
10/09/23 21:59
88-74-4
3-Nitroaniline
<3.4
ug/L
18.2
3.4
1
10/09/23 06:26
10/09/23 21:59
99-09-2
4-Nitroaniline
<4.6
ug/L
18.2
4.6
1
10/09/23 06:26
10/09/23 21:59
100-01-6
Nitrobenzene
<1.7
ug/L
9.1
1.7
1
10/09/23 06:26
10/09/23 21:59
98-95-3
2-Nitrophenol
<1.3
ug/L
9.1
1.3
1
10/09/23 06:26
10/09/23 21:59
88-75-5
4-Nitrophenol
<6.0
ug/L
45.5
6.0
1
10/09/23 06:26
10/09/23 21:59
100-02-7
5-Nitro-o-toluidine
<3.5
ug/L
9.1
3.5
1
10/09/23 06:26
10/09/23 21:59
99-55-8
N-Nitrosodiethylamine
<2.1
ug/L
9.1
2.1
1
10/09/23 06:26
10/09/23 21:59
55-18-5
N-Nitrosodimethylamine
<1.7
ug/L
9.1
1.7
1
10/09/23 06:26
10/09/23 21:59
62-75-9
N-Nitroso-di-n-butylamine
<1.8
ug/L
9.1
1.8
1
10/09/23 06:26
10/09/23 21:59
924-16-3
N-Nitroso-di-n-propylamine
<1.2
ug/L
9.1
1.2
1
10/09/23 06:26
10/09/23 21:59
621-64-7
N-Nitrosodiphenylamine
<2.7
ug/L
9.1
2.7
1
10/09/23 06:26
10/09/23 21:59
86-30-6
N-Nitrosomethylethylamine
<6.8
ug/L
9.1
6.8
1
10/09/23 06:26
10/09/23 21:59
10595-95-6
N-Nitrosopiperidine
<2.3
ug/L
9.1
2.3
1
10/09/23 06:26
10/09/23 21:59
100-75-4
N-Nitrosopyrrolidine
<2.8
ug/L
9.1
2.8
1
10/09/23 06:26
10/09/23 21:59
930-55-2
O,O,O-Triethylphosphorothioate
<2.3
ug/L
9.1
2.3
1
10/09/23 06:26
10/09/23 21:59
126-68-1
2,2'-Oxybis(1-chloropropane)
<1.0
ug/L
9.1
1.0
1
10/09/23 06:26
10/09/23 21:59
108-60-1
Parathion (Ethyl parathion)
<3.5
ug/L
9.1
3.5
1
10/09/23 06:26
10/09/23 21:59
56-38-2
Pentachlorobenzene
<3.1
ug/L
9.1
3.1
1
10/09/23 06:26
10/09/23 21:59
608-93-5
Pentachloronitrobenzene
<3.0
ug/L
9.1
3.0
1
10/09/23 06:26
10/09/23 21:59
82-68-8
Pentachlorophenol
<3.4
ug/L
18.2
3.4
1
10/09/23 06:26
10/09/23 21:59
87-86-5
Phenacetin
<3.3
ug/L
9.1
3.3
1
10/09/23 06:26
10/09/23 21:59
62-44-2
Phenanthrene
<1.8
ug/L
9.1
1.8
1
10/09/23 06:26
10/09/23 21:59
85-01-8
Phenol
<1.2
ug/L
9.1
1.2
1
10/09/23 06:26
10/09/23 21:59
108-95-2
p-Phenylenediamine
<9.1
ug/L
9.1
9.1
1
10/09/23 06:26
10/09/23 21:59
106-50-3
Phorate
<3.2
ug/L
9.1
3.2
1
10/09/23 06:26
10/09/23 21:59
298-02-2
Pronamide
<2.8
ug/L
9.1
2.8
1
10/09/23 06:26
10/09/23 21:59
23950-58-5
Pyrene
<2.0
ug/L
9.1
2.0
1
10/09/23 06:26
10/09/23 21:59
129-00-0
Safrole
<2.1
ug/L
9.1
2.1
1
10/09/23 06:26
10/09/23 21:59
94-59-7
1,2,4,5-Tetrachlorobenzene
<4.1
ug/L
9.1
4.1
1
10/09/23 06:26
10/09/23 21:59
95-94-3
2,3,4,6-Tetrachlorophenol
<1.4
ug/L
9.1
1.4
1
10/09/23 06:26
10/09/23 21:59
58-90-2
Thionazin
<2.6
ug/L
9.1
2.6
1
10/09/23 06:26
10/09/23 21:59
297-97-2
O-Toluidine
<2.4
ug/L
9.1
2.4
1
10/09/23 06:26
10/09/23 21:59
95-53-4
2,4,5-Trichlorophenol
<1.3
ug/L
9.1
1.3
1
10/09/23 06:26
10/09/23 21:59
95-95-4
2,4,6-Trichlorophenol
<1.4
ug/L
9.1
1.4
1
10/09/23 06:26
10/09/23 21:59
88-06-2
1,3,5-Trinitrobenzene
<5.0
ug/L
9.1
5.0
1
10/09/23 06:26
10/09/23 21:59
99-35-4
REPORT OF LABORATORY ANALYSIS
v1
v1
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-06-20231005 Lab ID: 92691980001 Collected: 10/05/23 15:42 Received: 10/06/23 11:51 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260D MSV Low Level Landfill
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
105
%
10-138
1
10/09/23 06:26
10/09/23 21:59
4165-60-0
92
%
10-130
1
10/09/23 06:26
10/09/23 21:59
321-60-8
113
%
19-191
1
10/09/23 06:26
10/09/23 21:59
1718-51-0
55
%
10-130
1
10/09/23 06:26
10/09/23 21:59
13127-88-3
72
%
10-130
1
10/09/23 06:26
10/09/23 21:59
367-12-4
121
%
10-164
1
10/09/23 06:26
10/09/23 21:59
118-79-6
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
<5.1
ug/L
25.0
5.1
1
10/11/2315:21
67-64-1
<0.34
ug/L
1.0
0.34
1
10/11/2315:21
71-43-2
<0.29
ug/L
1.0
0.29
1
10/11/2315:21
108-86-1
<0.47
ug/L
1.0
0.47
1
10/11/2315:21
74-97-5
<0.31
ug/L
1.0
0.31
1
10/11/2315:21
75-27-4
<0.34
ug/L
1.0
0.34
1
10/11/2315:21
75-25-2
<1.7
ug/L
2.0
1.7
1
10/11/2315:21
74-83-9
<4.0
ug/L
5.0
4.0
1
10/11/2315:21
78-93-3
<0.33
ug/L
1.0
0.33
1
10/11/2315:21
56-23-5
<0.28
ug/L
1.0
0.28
1
10/11/2315:21
108-90-7
<0.65
ug/L
1.0
0.65
1
10/11/2315:21
75-00-3
<0.43
ug/L
1.0
0.43
1
10/11/2315:21
67-66-3
<0.54
ug/L
1.0
0.54
1
10/11/2315:21
74-87-3
<0.32
ug/L
1.0
0.32
1
10/11/2315:21
95-49-8
<0.32
ug/L
1.0
0.32
1
10/11/2315:21
106-43-4
<0.34
ug/L
2.0
0.34
1
10/11/2315:21
96-12-8
<0.36
ug/L
1.0
0.36
1
10/11/2315:21
124-48-1
<0.27
ug/L
1.0
0.27
1
10/11/2315:21
106-93-4
<0.39
ug/L
1.0
0.39
1
10/11/2315:21
74-95-3
<0.34
ug/L
1.0
0.34
1
10/11/2315:21
95-50-1
<0.34
ug/L
1.0
0.34
1
10/11/2315:21
541-73-1
<0.33
ug/L
1.0
0.33
1
10/11/2315:21
106-46-7
<0.35
ug/L
1.0
0.35
1
10/11/2315:21
75-71-8
0.81J
ug/L
1.0
0.37
1
10/11/2315:21
75-34-3
<0.32
ug/L
1.0
0.32
1
10/11/2315:21
107-06-2
<0.35
ug/L
1.0
0.35
1
10/11/2315:21
75-35-4
0.46J
ug/L
1.0
0.38
1
10/11/2315:21
156-59-2
<0.40
ug/L
1.0
0.40
1
10/11/2315:21
156-60-5
<0.36
ug/L
1.0
0.36
1
10/11/2315:21
78-87-5
<0.28
ug/L
1.0
0.28
1
10/11/2315:21
142-28-9
<0.39
ug/L
1.0
0.39
1
10/11/2315:21
594-20-7
<0.43
ug/L
1.0
0.43
1
10/11/2315:21
563-58-6
<0.36
ug/L
1.0
0.36
1
10/11/2315:21
10061-01-5
<0.36
ug/L
1.0
0.36
1
10/11/2315:21
10061-02-6
<0.31
ug/L
1.0
0.31
1
10/11/2315:21
108-20-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 33 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-06-20231005 Lab ID: 92691980001 Collected: 10/05/23 15:42 Received: 10/06/23 11:51 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Iron, Ferric (Calculation)
Iron, Ferric
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
<0.30
ug/L
1.0
<1.5
ug/L
2.0
<0.48
ug/L
5.0
<0.41
ug/L
1.0
<2.0
ug/L
5.0
<2.7
ug/L
5.0
0.53J
ug/L
1.0
<0.64
ug/L
1.0
<0.29
ug/L
1.0
<0.31
ug/L
1.0
<0.22
ug/L
1.0
<0.29
ug/L
1.0
<0.24
ug/L
1.0
<0.81
ug/L
1.0
<0.64
ug/L
1.0
<0.33
ug/L
1.0
<0.32
ug/L
1.0
<0.38
ug/L
1.0
<0.30
ug/L
1.0
<0.26
ug/L
1.0
<1.3
ug/L
2.0
<0.39
ug/L
1.0
<0.34
ug/L
1.0
<0.71
ug/L
2.0
<0.34
ug/L
1.0
101
%
70-130
97
%
70-130
101
%
70-130
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
<0.86
ug/L
2.0
87 % 67-130
93 % 70-130
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
29.5 mg/L 5.0
Analytical Method: SM 3500-Fe D#4
Pace Analytical Services -Asheville
<0.25 mg/L 0.50
0.30
1
10/11 /23 15:21
100-41-4
1.5
1
10/11 /23 15:21
87-68-3
0.48
1
10/11 /23 15:21
591-78-6
0.41
1
10/11 /23 15:21
99-87-6
2.0
1
10/11 /23 15:21
75-09-2
2.7
1
10/11 /23 15:21
108-10-1
0.42
1
10/11 /23 15:21
1634-04-4
0.64
1
10/11 /23 15:21
91-20-3
0.29
1
10/11 /23 15:21
100-42-5
0.31
1
10/11 /23 15:21
630-20-6
0.22
1
10/11 /23 15:21
79-34-5
0.29
1
10/11 /23 15:21
127-18-4
0.24
1
10/11 /23 15:21
108-88-3
0.81
1
10/11 /23 15:21
87-61-6
0.64
1
10/11 /23 15:21
120-82-1
0.33
1
10/11 /23 15:21
71-55-6
0.32
1
10/11 /23 15:21
79-00-5
0.38
1
10/11 /23 15:21
79-01-6
0.30
1
10/11 /23 15:21
75-69-4
0.26
1
10/11 /23 15:21
96-18-4
1.3
1
10/11 /23 15:21
108-05-4
0.39
1
10/11 /23 15:21
75-01-4
0.34
1
10/11 /23 15:21
1330-20-7
0.71
1
10/11 /23 15:21
179601-23-1
0.34
1
10/11 /23 15:21
95-47-6
1 10/11 /23 15:21 460-00-4
1 10/11 /23 15:21 17060-07-0
1 10/11 /23 15:21 2037-26-5
0.86 1 10/09/23 21:37 123-91-1
1 10/09/23 21:37 17060-07-0
1 10/09/23 21:37 2037-26-5
5.0 1 10/13/23 17:55
0.25 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
11/28/23 08:24 20074-52-6 N2
Page 34 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: MW-06-20231005
Lab ID: 92691980001 Collected:
10/05/23
15:42
Received: 10/06/23
11:51 Matrix: Water
Parameters
Results Units PQL
MDL
DF
Prepared
Analyzed
CAS No. Qual
Iron, Ferrous
Analytical Method: SM 3500-Fe B-2011
Pace Analytical Services -Asheville
Iron, Ferrous
0.075J mg/L 0.50
0.040
1
10/17/23 11:34
H3,N2
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
<0.022 mg/L 0.10
0.022
1
10/11/23 01:17
18496-25-8
5210B BOD, 5 day
Analytical Method: SM 521OB-2011
Pace Analytical Services -Asheville
BOD, 5 day
<2.0 mg/L 2.0
2.0
1
10/07/23 07:22
10/12/23 01:42
2g
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
<12.5 mg/L 25.0
12.5
1
10/19/23 03:19
10/19/23 23:55
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
<0.50 mg/L 1.0
0.50
1
10/16/23 18:09
7440-44-0
9056 IC Anions 48hr
Analytical Method: EPA 9056A
Pace Analytical Services -Asheville
Chloride
0.73J mg/L 1.0
0.60
1
10/06/2318:26
16887-00-6
Nitrate as N
0.22 mg/L 0.10
0.060
1
10/06/23 18:26
14797-55-8
Sulfate
0.801 mg/L 1.0
0.50
1
10/06/2318:26
14808-79-8 M1
Date: 02/23/2024 01:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 35 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: MW-01-20231005 Lab ID: 92691980002 Collected: 10/05/23 13:56 Received: 10/06/23 11:51 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Ethane
<5.9
ug/L
10.0
5.9
1
10/12/2314:53
74-84-0
Ethene
<5.7
ug/L
10.0
5.7
1
10/12/2314:53
74-85-1
Methane
366
ug/L
10.0
5.3
1
10/12/2314:53
74-82-8
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Pace Analytical Services
-Asheville
Antimony
<0.20
ug/L
1.0
0.20
1
10/10/2315:20
10/11/2314:59
7440-36-0
Arsenic
0.11J
ug/L
1.0
0.087
1
10/10/2315:20
10/11/2314:59
7440-38-2
Barium
101
ug/L
1.0
0.21
1
10/10/2315:20
10/11/2314:59
7440-39-3
Beryllium
<0.050
ug/L
0.10
0.050
1
10/10/2315:20
10/11/2314:59
7440-41-7
Cadmium
0.74
ug/L
0.20
0.060
1
10/10/2315:20
10/11/2314:59
7440-43-9
Chromium
<0.50
ug/L
1.0
0.50
1
10/10/2315:20
10/11/2314:59
7440-47-3
Cobalt
95.4
ug/L
1.0
0.050
1
10/10/2315:20
10/11/2314:59
7440-48-4
Copper
1.6J
ug/L
2.0
1.1
1
10/10/2315:20
10/11/2314:59
7440-50-8
Iron
19500
ug/L
500
209
10
11/21/23 01:07
11/21/23 14:49
7439-89-6
Lead
<0.077
ug/L
1.0
0.077
1
10/10/2315:20
10/11/2314:59
7439-92-1
Nickel
12.1
ug/L
1.0
0.42
1
10/10/2315:20
10/11/2314:59
7440-02-0
Selenium
<0.072
ug/L
2.0
0.072
1
10/10/2315:20
10/11/2314:59
7782-49-2
Silver
<0.070
ug/L
0.40
0.070
1
10/10/2315:20
10/11/2314:59
7440-22-4
Thallium
0.82
ug/L
0.20
0.050
1
10/10/2315:20
10/11/2314:59
7440-28-0
Tin
<0.43
ug/L
1.0
0.43
1
10/10/2315:20
10/11/2314:59
7440-31-5
Vanadium
<0.25
ug/L
1.0
0.25
1
10/10/2315:20
10/11/2314:59
7440-62-2
7470 Mercury
Mercury
8270E APP9 RV
Acenaphthene
Acenaphthylene
Acetophenone
2-Acetylaminofluorene
4-Aminobiphenyl
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Benzyl alcohol
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methyl phenol
4-Chloroaniline
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
<0.12 ug/L 0.20 0.12 1 10/13/2315:08 10/14/2311:42 7439-97-6
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
<1.8
ug/L
9.1
1.8
1
10/09/23 06:26
10/10/23 01:49
83-32-9
<1.8
ug/L
9.1
1.8
1
10/09/23 06:26
10/10/23 01:49
208-96-8
<1.4
ug/L
9.1
1.4
1
10/09/23 06:26
10/10/23 01:49
98-86-2
<3.7
ug/L
9.1
3.7
1
10/09/23 06:26
10/10/23 01:49
53-96-3
<4.3
ug/L
9.1
4.3
1
10/09/23 06:26
10/10/23 01:49
92-67-1
<2.1
ug/L
9.1
2.1
1
10/09/23 06:26
10/10/23 01:49
120-12-7
<2.4
ug/L
9.1
2.4
1
10/09/23 06:26
10/10/23 01:49
56-55-3
<2.5
ug/L
9.1
2.5
1
10/09/23 06:26
10/10/23 01:49
50-32-8
<2.4
ug/L
9.1
2.4
1
10/09/23 06:26
10/10/23 01:49
205-99-2
<2.6
ug/L
9.1
2.6
1
10/09/23 06:26
10/10/23 01:49
191-24-2
<2.5
ug/L
9.1
2.5
1
10/09/23 06:26
10/10/23 01:49
207-08-9
<2.6
ug/L
18.2
2.6
1
10/09/23 06:26
10/10/23 01:49
100-51-6
<1.6
ug/L
9.1
1.6
1
10/09/23 06:26
10/10/23 01:49
101-55-3
<2.9
ug/L
9.1
2.9
1
10/09/23 06:26
10/10/23 01:49
85-68-7
<3.0
ug/L
9.1
3.0
1
10/09/23 06:26
10/10/23 01:49
59-50-7
<3.3
ug/L
18.2
3.3
1
10/09/23 06:26
10/10/23 01:49
106-47-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 36 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-01-20231005 Lab ID: 92691980002 Collected: 10/05/23 13:56 Received: 10/06/23 11:51 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Chlorobenzilate
<3.4
ug/L
9.1
3.4
1
10/09/23 06:26
10/10/23 01:49
510-15-6
bis(2-Chloroethoxy)methane
<1.7
ug/L
9.1
1.7
1
10/09/23 06:26
10/10/23 01:49
111-91-1
bis(2-Chloroethyl) ether
<1.7
ug/L
9.1
1.7
1
10/09/23 06:26
10/10/23 01:49
111-44-4
2-Chloronaphthalene
<1.6
ug/L
9.1
1.6
1
10/09/23 06:26
10/10/23 01:49
91-58-7
2-Chlorophenol
<1.1
ug/L
9.1
1.1
1
10/09/23 06:26
10/10/23 01:49
95-57-8
4-Chlorophenylphenyl ether
<1.8
ug/L
9.1
1.8
1
10/09/23 06:26
10/10/23 01:49
7005-72-3
Chrysene
<2.5
ug/L
9.1
2.5
1
10/09/23 06:26
10/10/23 01:49
218-01-9
Diallate
<3.1
ug/L
9.1
3.1
1
10/09/23 06:26
10/10/23 01:49
2303-16-4
Dibenz(a,h)anthracene
<2.7
ug/L
9.1
2.7
1
10/09/23 06:26
10/10/23 01:49
53-70-3
Dibenzofuran
<1.9
ug/L
9.1
1.9
1
10/09/23 06:26
10/10/23 01:49
132-64-9
3,3'-Dichlorobenzidine
<7.4
ug/L
18.2
7.4
1
10/09/23 06:26
10/10/23 01:49
91-94-1
2,4-Dichlorophenol
<1.3
ug/L
9.1
1.3
1
10/09/23 06:26
10/10/23 01:49
120-83-2
2,6-Dichlorophenol
<3.8
ug/L
9.1
3.8
1
10/09/23 06:26
10/10/23 01:49
87-65-0
Diethylphthalate
<1.9
ug/L
9.1
1.9
1
10/09/23 06:26
10/10/23 01:49
84-66-2
Dimethoate
<3.3
ug/L
9.1
3.3
1
10/09/23 06:26
10/10/23 01:49
60-51-5
P-Dimethylaminoazobenzene
<2.2
ug/L
4.5
2.2
1
10/09/23 06:26
10/10/23 01:49
60-11-7
7,12-Dimethylbenz(a)anthracene
<2.7
ug/L
9.1
2.7
1
10/09/23 06:26
10/10/23 01:49
57-97-6
3,3'-Dimethylbenzidine
<28.3
ug/L
45.5
28.3
1
10/09/23 06:26
10/10/23 01:49
119-93-7
2,4-Dimethylphenol
<1.5
ug/L
9.1
1.5
1
10/09/23 06:26
10/10/23 01:49
105-67-9
Dimethylphthalate
<1.9
ug/L
9.1
1.9
1
10/09/23 06:26
10/10/23 01:49
131-11-3
Di-n-butylphthalate
<2.0
ug/L
9.1
2.0
1
10/09/23 06:26
10/10/23 01:49
84-74-2
4,6-Dinitro-2-methyl phenol
<7.1
ug/L
18.2
7.1
1
10/09/23 06:26
10/10/23 01:49
534-52-1
1,3-Dinitrobenzene
<3.4
ug/L
9.1
3.4
1
10/09/23 06:26
10/10/23 01:49
99-65-0
2,4-Dinitrophenol
<23.6
ug/L
45.5
23.6
1
10/09/23 06:26
10/10/23 01:49
51-28-5
2,4-Dinitrotoluene
<1.5
ug/L
9.1
1.5
1
10/09/23 06:26
10/10/23 01:49
121-14-2
2,6-Dinitrotoluene
<1.6
ug/L
9.1
1.6
1
10/09/23 06:26
10/10/23 01:49
606-20-2
Di-n-octylphthalate
<3.6
ug/L
9.1
3.6
1
10/09/23 06:26
10/10/23 01:49
117-84-0
Diphenylamine
<2.7
ug/L
9.1
2.7
1
10/09/23 06:26
10/10/23 01:49
122-39-4
Disulfoton
<4.2
ug/L
9.1
4.2
1
10/09/23 06:26
10/10/23 01:49
298-04-4
bis(2- Ethyl hexyl)phthalate
<3.4
ug/L
5.5
3.4
1
10/09/23 06:26
10/10/23 01:49
117-81-7
Ethyl methanesulfonate
<2.7
ug/L
18.2
2.7
1
10/09/23 06:26
10/10/23 01:49
62-50-0
Famphur
<5.6
ug/L
9.1
5.6
1
10/09/23 06:26
10/10/23 01:49
52-85-7
Fluoranthene
<2.0
ug/L
9.1
2.0
1
10/09/23 06:26
10/10/23 01:49
206-44-0
Fluorene
<1.9
ug/L
9.1
1.9
1
10/09/23 06:26
10/10/23 01:49
86-73-7
Hexachlorobenzene
<2.0
ug/L
9.1
2.0
1
10/09/23 06:26
10/10/23 01:49
118-74-1
Hexachlorocyclopentadiene
<1.4
ug/L
9.1
1.4
1
10/09/23 06:26
10/10/23 01:49
77-47-4
Hexachloroethane
<1.3
ug/L
9.1
1.3
1
10/09/23 06:26
10/10/23 01:49
67-72-1
Hexachloropropene
<2.5
ug/L
9.1
2.5
1
10/09/23 06:26
10/10/23 01:49
1888-71-7
Indeno(1,2,3-cd)pyrene
<2.6
ug/L
9.1
2.6
1
10/09/23 06:26
10/10/23 01:49
193-39-5
Isodrin
<2.5
ug/L
9.1
2.5
1
10/09/23 06:26
10/10/23 01:49
465-73-6
Isophorone
<1.5
ug/L
9.1
1.5
1
10/09/23 06:26
10/10/23 01:49
78-59-1
Isosafrole
<2.3
ug/L
9.1
2.3
1
10/09/23 06:26
10/10/23 01:49
120-58-1
Kepone
<12.8
ug/L
18.2
12.8
1
10/09/23 06:26
10/10/23 01:49
143-50-0
Methapyrilene
<15.5
ug/L
45.5
15.5
1
10/09/23 06:26
10/10/23 01:49
91-80-5
3-Methylcholanthrene
<3.4
ug/L
9.1
3.4
1
10/09/23 06:26
10/10/23 01:49
56-49-5
REPORT OF LABORATORY ANALYSIS
IL
v1
v1
v1
L2
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-01-20231005 Lab ID: 92691980002 Collected: 10/05/23 13:56 Received: 10/06/23 11:51 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Methyl methanesulfonate
<2.8
ug/L
4.5
2.8
1
10/09/23 06:26
10/10/23 01:49
66-27-3
2-Methylnaphthalene
<1.7
ug/L
9.1
1.7
1
10/09/23 06:26
10/10/23 01:49
91-57-6
Methyl parathion
<3.4
ug/L
9.1
3.4
1
10/09/23 06:26
10/10/23 01:49
298-00-0
2-Methylphenol(o-Cresol)
<1.7
ug/L
9.1
1.7
1
10/09/23 06:26
10/10/23 01:49
95-48-7
3&4-Methyl phenol (m&p Cresol)
<1.1
ug/L
9.1
1.1
1
10/09/23 06:26
10/10/23 01:49
15831-10-4
1-Naphthalenamine
<5.5
ug/L
9.1
5.5
1
10/09/23 06:26
10/10/23 01:49
134-32-7
2-Naphthalenamine
<5.0
ug/L
9.1
5.0
1
10/09/23 06:26
10/10/23 01:49
91-59-8
1,4-Naphthoquinone
<4.0
ug/L
4.5
4.0
1
10/09/23 06:26
10/10/23 01:49
130-15-4
2-Nitroaniline
<2.7
ug/L
18.2
2.7
1
10/09/23 06:26
10/10/23 01:49
88-74-4
3-Nitroaniline
<3.4
ug/L
18.2
3.4
1
10/09/23 06:26
10/10/23 01:49
99-09-2
4-Nitroaniline
<4.6
ug/L
18.2
4.6
1
10/09/23 06:26
10/10/23 01:49
100-01-6
Nitrobenzene
<1.7
ug/L
9.1
1.7
1
10/09/23 06:26
10/10/23 01:49
98-95-3
2-Nitrophenol
<1.3
ug/L
9.1
1.3
1
10/09/23 06:26
10/10/23 01:49
88-75-5
4-Nitrophenol
<6.0
ug/L
45.5
6.0
1
10/09/23 06:26
10/10/23 01:49
100-02-7
5-Nitro-o-toluidine
<3.5
ug/L
9.1
3.5
1
10/09/23 06:26
10/10/23 01:49
99-55-8
N-Nitrosodiethylamine
<2.1
ug/L
9.1
2.1
1
10/09/23 06:26
10/10/23 01:49
55-18-5
N-Nitrosodimethylamine
<1.7
ug/L
9.1
1.7
1
10/09/23 06:26
10/10/23 01:49
62-75-9
N-Nitroso-di-n-butylamine
<1.8
ug/L
9.1
1.8
1
10/09/23 06:26
10/10/23 01:49
924-16-3
N-Nitroso-di-n-propylamine
<1.2
ug/L
9.1
1.2
1
10/09/23 06:26
10/10/23 01:49
621-64-7
N-Nitrosodiphenylamine
<2.7
ug/L
9.1
2.7
1
10/09/23 06:26
10/10/23 01:49
86-30-6
N-Nitrosomethylethylamine
<6.8
ug/L
9.1
6.8
1
10/09/23 06:26
10/10/23 01:49
10595-95-6
N-Nitrosopiperidine
<2.3
ug/L
9.1
2.3
1
10/09/23 06:26
10/10/23 01:49
100-75-4
N-Nitrosopyrrolidine
<2.8
ug/L
9.1
2.8
1
10/09/23 06:26
10/10/23 01:49
930-55-2
O,O,O-Triethylphosphorothioate
<2.3
ug/L
9.1
2.3
1
10/09/23 06:26
10/10/23 01:49
126-68-1
2,2'-Oxybis(1-chloropropane)
<1.0
ug/L
9.1
1.0
1
10/09/23 06:26
10/10/23 01:49
108-60-1
Parathion (Ethyl parathion)
<3.5
ug/L
9.1
3.5
1
10/09/23 06:26
10/10/23 01:49
56-38-2
Pentachlorobenzene
<3.1
ug/L
9.1
3.1
1
10/09/23 06:26
10/10/23 01:49
608-93-5
Pentachloronitrobenzene
<3.0
ug/L
9.1
3.0
1
10/09/23 06:26
10/10/23 01:49
82-68-8
Pentachlorophenol
<3.4
ug/L
18.2
3.4
1
10/09/23 06:26
10/10/23 01:49
87-86-5
Phenacetin
<3.3
ug/L
9.1
3.3
1
10/09/23 06:26
10/10/23 01:49
62-44-2
Phenanthrene
<1.8
ug/L
9.1
1.8
1
10/09/23 06:26
10/10/23 01:49
85-01-8
Phenol
<1.2
ug/L
9.1
1.2
1
10/09/23 06:26
10/10/23 01:49
108-95-2
p-Phenylenediamine
<9.1
ug/L
9.1
9.1
1
10/09/23 06:26
10/10/23 01:49
106-50-3
Phorate
<3.2
ug/L
9.1
3.2
1
10/09/23 06:26
10/10/23 01:49
298-02-2
Pronamide
<2.8
ug/L
9.1
2.8
1
10/09/23 06:26
10/10/23 01:49
23950-58-5
Pyrene
<2.0
ug/L
9.1
2.0
1
10/09/23 06:26
10/10/23 01:49
129-00-0
Safrole
<2.1
ug/L
9.1
2.1
1
10/09/23 06:26
10/10/23 01:49
94-59-7
1,2,4,5-Tetrachlorobenzene
<4.1
ug/L
9.1
4.1
1
10/09/23 06:26
10/10/23 01:49
95-94-3
2,3,4,6-Tetrachlorophenol
<1.4
ug/L
9.1
1.4
1
10/09/23 06:26
10/10/23 01:49
58-90-2
Thionazin
<2.6
ug/L
9.1
2.6
1
10/09/23 06:26
10/10/23 01:49
297-97-2
O-Toluidine
<2.4
ug/L
9.1
2.4
1
10/09/23 06:26
10/10/23 01:49
95-53-4
2,4,5-Trichlorophenol
<1.3
ug/L
9.1
1.3
1
10/09/23 06:26
10/10/23 01:49
95-95-4
2,4,6-Trichlorophenol
<1.4
ug/L
9.1
1.4
1
10/09/23 06:26
10/10/23 01:49
88-06-2
1,3,5-Trinitrobenzene
<5.0
ug/L
9.1
5.0
1
10/09/23 06:26
10/10/23 01:49
99-35-4
REPORT OF LABORATORY ANALYSIS
v1
v1
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-01-20231005 Lab ID: 92691980002 Collected: 10/05/23 13:56 Received: 10/06/23 11:51 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260D MSV Low Level Landfill
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
44
%
10-138
1
10/09/23 06:26
10/10/23 01:49
4165-60-0
47
%
10-130
1
10/09/23 06:26
10/10/23 01:49
321-60-8
70
%
19-191
1
10/09/23 06:26
10/10/23 01:49
1718-51-0
11
%
10-130
1
10/09/23 06:26
10/10/23 01:49
13127-88-3
5
%
10-130
1
10/09/23 06:26
10/10/23 01:49
367-12-4 SO
16
%
10-164
1
10/09/23 06:26
10/10/23 01:49
118-79-6
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
<5.1
ug/L
25.0
5.1
1
10/11/2315:15
67-64-1
0.36J
ug/L
1.0
0.34
1
10/11/2315:15
71-43-2
<0.29
ug/L
1.0
0.29
1
10/11/2315:15
108-86-1
<0.47
ug/L
1.0
0.47
1
10/11/2315:15
74-97-5
<0.31
ug/L
1.0
0.31
1
10/11/2315:15
75-27-4
<0.34
ug/L
1.0
0.34
1
10/11/2315:15
75-25-2
<1.7
ug/L
2.0
1.7
1
10/11/2315:15
74-83-9 v2
<4.0
ug/L
5.0
4.0
1
10/11/2315:15
78-93-3
<0.33
ug/L
1.0
0.33
1
10/11/2315:15
56-23-5
0.49J
ug/L
1.0
0.28
1
10/11/2315:15
108-90-7
<0.65
ug/L
1.0
0.65
1
10/11/2315:15
75-00-3
<0.43
ug/L
1.0
0.43
1
10/11/2315:15
67-66-3
<0.54
ug/L
1.0
0.54
1
10/11/2315:15
74-87-3
<0.32
ug/L
1.0
0.32
1
10/11/2315:15
95-49-8
<0.32
ug/L
1.0
0.32
1
10/11/2315:15
106-43-4
<0.34
ug/L
2.0
0.34
1
10/11/2315:15
96-12-8
<0.36
ug/L
1.0
0.36
1
10/11/2315:15
124-48-1
<0.27
ug/L
1.0
0.27
1
10/11/2315:15
106-93-4
<0.39
ug/L
1.0
0.39
1
10/11/2315:15
74-95-3
<0.34
ug/L
1.0
0.34
1
10/11/2315:15
95-50-1
<0.34
ug/L
1.0
0.34
1
10/11/2315:15
541-73-1
<0.33
ug/L
1.0
0.33
1
10/11/2315:15
106-46-7
<0.35
ug/L
1.0
0.35
1
10/11/2315:15
75-71-8
1.2
ug/L
1.0
0.37
1
10/11/2315:15
75-34-3
<0.32
ug/L
1.0
0.32
1
10/11/2315:15
107-06-2
<0.35
ug/L
1.0
0.35
1
10/11/2315:15
75-35-4
0.981
ug/L
1.0
0.38
1
10/11/2315:15
156-59-2
<0.40
ug/L
1.0
0.40
1
10/11/2315:15
156-60-5
<0.36
ug/L
1.0
0.36
1
10/11/2315:15
78-87-5
<0.28
ug/L
1.0
0.28
1
10/11/2315:15
142-28-9
<0.39
ug/L
1.0
0.39
1
10/11/2315:15
594-20-7
<0.43
ug/L
1.0
0.43
1
10/11/2315:15
563-58-6
<0.36
ug/L
1.0
0.36
1
10/11/2315:15
10061-01-5
<0.36
ug/L
1.0
0.36
1
10/11/2315:15
10061-02-6
<0.31
ug/L
1.0
0.31
1
10/11/2315:15
108-20-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 39 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-01-20231005 Lab ID: 92691980002 Collected: 10/05/23 13:56 Received: 10/06/23 11:51 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Iron, Ferric (Calculation)
Iron, Ferric
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
<0.30
ug/L
1.0
<1.5
ug/L
2.0
<0.48
ug/L
5.0
<0.41
ug/L
1.0
<2.0
ug/L
5.0
<2.7
ug/L
5.0
<0.42
ug/L
1.0
<0.64
ug/L
1.0
<0.29
ug/L
1.0
<0.31
ug/L
1.0
<0.22
ug/L
1.0
<0.29
ug/L
1.0
<0.24
ug/L
1.0
<0.81
ug/L
1.0
<0.64
ug/L
1.0
<0.33
ug/L
1.0
<0.32
ug/L
1.0
<0.38
ug/L
1.0
<0.30
ug/L
1.0
<0.26
ug/L
1.0
<1.3
ug/L
2.0
<0.39
ug/L
1.0
<0.34
ug/L
1.0
<0.71
ug/L
2.0
<0.34
ug/L
1.0
96
%
70-130
94
%
70-130
107
%
70-130
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
<0.86
ug/L
2.0
91 % 67-130
94 % 70-130
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
89.3 mg/L 5.0
Analytical Method: SM 3500-Fe D#4
Pace Analytical Services -Asheville
19.2 mg/L 0.50
0.30
1
10/11 /23 15:15
100-41-4
1.5
1
10/11/2315:15
87-68-3
0.48
1
10/11 /23 15:15
591-78-6
0.41
1
10/11/2315:15
99-87-6
2.0
1
10/11/2315:15
75-09-2
2.7
1
10/11 /23 15:15
108-10-1
0.42
1
10/11 /23 15:15
1634-04-4
0.64
1
10/11 /23 15:15
91-20-3
0.29
1
10/11 /23 15:15
100-42-5
0.31
1
10/11/2315:15
630-20-6
0.22
1
10/11/2315:15
79-34-5
0.29
1
10/11 /23 15:15
127-18-4
0.24
1
10/11 /23 15:15
108-88-3
0.81
1
10/11 /23 15:15
87-61-6
0.64
1
10/11 /23 15:15
120-82-1
0.33
1
10/11 /23 15:15
71-55-6
0.32
1
10/11/2315:15
79-00-5
0.38
1
10/11 /23 15:15
79-01-6
0.30
1
10/11/2315:15
75-69-4
0.26
1
10/11/2315:15
96-18-4
1.3
1
10/11 /23 15:15
108-05-4
0.39
1
10/11 /23 15:15
75-01-4
0.34
1
10/11 /23 15:15
1330-20-7
0.71
1
10/11 /23 15:15
179601-23-1
0.34
1
10/11/2315:15
95-47-6
1 10/11/2315:15 460-00-4
1 10/11 /23 15:15 17060-07-0
1 10/11/2315:15 2037-26-5
0.86 1 10/09/23 21:58 123-91-1
1 10/09/23 21:58 17060-07-0
1 10/09/23 21:58 2037-26-5
5.0 1 10/13/23 18:11
0.25 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
11/28/23 08:24 20074-52-6 N2
Page 40 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: MW-01-20231005
Lab ID: 92691980002 Collected:
10/05/23
13:56
Received: 10/06/23
11:51 Matrix: Water
Parameters
Results Units PQL
MDL
DF
Prepared
Analyzed
CAS No. Qual
Iron, Ferrous
Analytical Method: SM 3500-Fe B-2011
Pace Analytical Services -Asheville
Iron, Ferrous
0.26J mg/L 0.50
0.040
1
10/17/23 11:32
H3,N2
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
0.048J mg/L 0.10
0.022
1
10/11/23 01:18
18496-25-8
5210B BOD, 5 day
Analytical Method: SM 521OB-2011
Pace Analytical Services -Asheville
BOD, 5 day
5.3 mg/L 2.0
2.0
1
10/07/23 07:22
10/12/23 01:37
2g
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
22.5.11 mg/L 25.0
12.5
1
10/19/23 03:19
10/19/23 23:55
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
2.4 mg/L 1.0
0.50
1
10/16/23 18:31
7440-44-0
9056 IC Anions 48hr
Analytical Method: EPA 9056A
Pace Analytical Services -Asheville
Chloride
0.79J mg/L 1.0
0.60
1
10/06/2318:11
16887-00-6
Nitrate as N
<0.060 mg/L 0.10
0.060
1
10/06/23 18:11
14797-55-8
Sulfate
1.2 mg/L 1.0
0.50
1
10/06/2318:11
14808-79-8
Date: 02/23/2024 01:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 41 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: MW-02-20231005 Lab ID: 92691980003 Collected: 10/05/23 11:55 Received: 10/06/23 11:51 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Ethane
<5.9
ug/L
10.0
5.9
1
10/12/2315:09
74-84-0
Ethene
<5.7
ug/L
10.0
5.7
1
10/12/2315:09
74-85-1
Methane
<5.3
ug/L
10.0
5.3
1
10/12/2315:09
74-82-8
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Antimony
<0.20
ug/L
1.0
0.20
1
10/10/2315:20
10/11/2315:04
7440-36-0
Arsenic
0.48J
ug/L
1.0
0.087
1
10/10/2315:20
10/11/2315:04
7440-38-2
Barium
43.6
ug/L
1.0
0.21
1
10/10/2315:20
10/11/2315:04
7440-39-3
Beryllium
<0.050
ug/L
0.10
0.050
1
10/10/2315:20
10/11/2315:04
7440-41-7
Cadmium
<0.060
ug/L
0.20
0.060
1
10/10/2315:20
10/11/2315:04
7440-43-9
Chromium
2.1
ug/L
1.0
0.50
1
10/10/2315:20
10/11/2315:04
7440-47-3
Cobalt
6.9
ug/L
1.0
0.050
1
10/10/2315:20
10/11/2315:04
7440-48-4
Copper
3.6
ug/L
2.0
1.1
1
10/10/2315:20
10/11/2315:04
7440-50-8
Iron
2320
ug/L
50.0
20.9
1
10/18/2312:10
10/18/2319:16
7439-89-6
Lead
0.48J
ug/L
1.0
0.077
1
10/10/2315:20
10/11/2315:04
7439-92-1
Nickel
2.2
ug/L
1.0
0.42
1
10/10/2315:20
10/11/2315:04
7440-02-0
Selenium
0.15J
ug/L
2.0
0.072
1
10/10/2315:20
10/11/2315:04
7782-49-2
Silver
<0.070
ug/L
0.40
0.070
1
10/10/2315:20
10/11/2315:04
7440-22-4
Thallium
<0.050
ug/L
0.20
0.050
1
10/10/2315:20
10/11/2315:04
7440-28-0
Tin
<0.43
ug/L
1.0
0.43
1
10/10/2315:20
10/11/2315:04
7440-31-5
Vanadium
2.4
ug/L
1.0
0.25
1
10/10/2315:20
10/11/2315:04
7440-62-2
7470 Mercury
Mercury
8270E APP9 RV
Acenaphthene
Acenaphthylene
Acetophenone
2-Acetylaminofluorene
4-Aminobiphenyl
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Benzyl alcohol
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methyl phenol
4-Chloroaniline
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
<0.12 ug/L 0.20 0.12 1 10/13/2315:08 10/14/2311:48 7439-97-6
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
<2.0
ug/L
10.0
2.0
1
10/09/23 06:26
10/09/23 22:50
83-32-9
<2.0
ug/L
10.0
2.0
1
10/09/23 06:26
10/09/23 22:50
208-96-8
<1.5
ug/L
10.0
1.5
1
10/09/23 06:26
10/09/23 22:50
98-86-2
<4.1
ug/L
10.0
4.1
1
10/09/23 06:26
10/09/23 22:50
53-96-3
<4.7
ug/L
10.0
4.7
1
10/09/23 06:26
10/09/23 22:50
92-67-1
<2.3
ug/L
10.0
2.3
1
10/09/23 06:26
10/09/23 22:50
120-12-7
<2.7
ug/L
10.0
2.7
1
10/09/23 06:26
10/09/23 22:50
56-55-3
<2.8
ug/L
10.0
2.8
1
10/09/23 06:26
10/09/23 22:50
50-32-8
<2.6
ug/L
10.0
2.6
1
10/09/23 06:26
10/09/23 22:50
205-99-2
<2.8
ug/L
10.0
2.8
1
10/09/23 06:26
10/09/23 22:50
191-24-2
<2.7
ug/L
10.0
2.7
1
10/09/23 06:26
10/09/23 22:50
207-08-9
<2.9
ug/L
20.0
2.9
1
10/09/23 06:26
10/09/23 22:50
100-51-6
<1.8
ug/L
10.0
1.8
1
10/09/23 06:26
10/09/23 22:50
101-55-3
<3.1
ug/L
10.0
3.1
1
10/09/23 06:26
10/09/23 22:50
85-68-7
<3.3
ug/L
10.0
3.3
1
10/09/23 06:26
10/09/23 22:50
59-50-7
<3.6
ug/L
20.0
3.6
1
10/09/23 06:26
10/09/23 22:50
106-47-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 42 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-02-20231005 Lab ID: 92691980003 Collected: 10/05/23 11:55 Received: 10/06/23 11:51 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Chlorobenzilate
<3.8
ug/L
10.0
3.8
1
10/09/23 06:26
10/09/23 22:50
510-15-6
bis(2-Chloroethoxy)methane
<1.8
ug/L
10.0
1.8
1
10/09/23 06:26
10/09/23 22:50
111-91-1
bis(2-Chloroethyl) ether
<1.9
ug/L
10.0
1.9
1
10/09/23 06:26
10/09/23 22:50
111-44-4
2-Chloronaphthalene
<1.7
ug/L
10.0
1.7
1
10/09/23 06:26
10/09/23 22:50
91-58-7
2-Chlorophenol
<1.2
ug/L
10.0
1.2
1
10/09/23 06:26
10/09/23 22:50
95-57-8
4-Chlorophenylphenyl ether
<2.0
ug/L
10.0
2.0
1
10/09/23 06:26
10/09/23 22:50
7005-72-3
Chrysene
<2.8
ug/L
10.0
2.8
1
10/09/23 06:26
10/09/23 22:50
218-01-9
Diallate
<3.4
ug/L
10.0
3.4
1
10/09/23 06:26
10/09/23 22:50
2303-16-4
Dibenz(a,h)anthracene
<3.0
ug/L
10.0
3.0
1
10/09/23 06:26
10/09/23 22:50
53-70-3
Dibenzofuran
<2.1
ug/L
10.0
2.1
1
10/09/23 06:26
10/09/23 22:50
132-64-9
3,3'-Dichlorobenzidine
<8.1
ug/L
20.0
8.1
1
10/09/23 06:26
10/09/23 22:50
91-94-1
2,4-Dichlorophenol
<1.4
ug/L
10.0
1.4
1
10/09/23 06:26
10/09/23 22:50
120-83-2
2,6-Dichlorophenol
<4.2
ug/L
10.0
4.2
1
10/09/23 06:26
10/09/23 22:50
87-65-0
Diethylphthalate
3.7J
ug/L
10.0
2.0
1
10/09/23 06:26
10/09/23 22:50
84-66-2
Dimethoate
<3.7
ug/L
10.0
3.7
1
10/09/23 06:26
10/09/23 22:50
60-51-5
P-Dimethylaminoazobenzene
<2.4
ug/L
5.0
2.4
1
10/09/23 06:26
10/09/23 22:50
60-11-7
7,12-Dimethylbenz(a)anthracene
<3.0
ug/L
10.0
3.0
1
10/09/23 06:26
10/09/23 22:50
57-97-6
3,3'-Dimethylbenzidine
<31.1
ug/L
50.0
31.1
1
10/09/23 06:26
10/09/23 22:50
119-93-7
2,4-Dimethylphenol
<1.7
ug/L
10.0
1.7
1
10/09/23 06:26
10/09/23 22:50
105-67-9
Dimethylphthalate
<2.1
ug/L
10.0
2.1
1
10/09/23 06:26
10/09/23 22:50
131-11-3
Di-n-butylphthalate
<2.2
ug/L
10.0
2.2
1
10/09/23 06:26
10/09/23 22:50
84-74-2
4,6-Dinitro-2-methyl phenol
<7.8
ug/L
20.0
7.8
1
10/09/23 06:26
10/09/23 22:50
534-52-1
1,3-Dinitrobenzene
<3.8
ug/L
10.0
3.8
1
10/09/23 06:26
10/09/23 22:50
99-65-0
2,4-Dinitrophenol
<26.0
ug/L
50.0
26.0
1
10/09/23 06:26
10/09/23 22:50
51-28-5
2,4-Dinitrotoluene
<1.6
ug/L
10.0
1.6
1
10/09/23 06:26
10/09/23 22:50
121-14-2
2,6-Dinitrotoluene
<1.7
ug/L
10.0
1.7
1
10/09/23 06:26
10/09/23 22:50
606-20-2
Di-n-octylphthalate
<3.9
ug/L
10.0
3.9
1
10/09/23 06:26
10/09/23 22:50
117-84-0
Diphenylamine
<3.0
ug/L
10.0
3.0
1
10/09/23 06:26
10/09/23 22:50
122-39-4
Disulfoton
<4.6
ug/L
10.0
4.6
1
10/09/23 06:26
10/09/23 22:50
298-04-4
bis(2- Ethyl hexyl)phthalate
<3.7
ug/L
6.0
3.7
1
10/09/23 06:26
10/09/23 22:50
117-81-7
Ethyl methanesulfonate
<3.0
ug/L
20.0
3.0
1
10/09/23 06:26
10/09/23 22:50
62-50-0
Famphur
<6.1
ug/L
10.0
6.1
1
10/09/23 06:26
10/09/23 22:50
52-85-7
Fluoranthene
<2.2
ug/L
10.0
2.2
1
10/09/23 06:26
10/09/23 22:50
206-44-0
Fluorene
<2.1
ug/L
10.0
2.1
1
10/09/23 06:26
10/09/23 22:50
86-73-7
Hexachlorobenzene
<2.2
ug/L
10.0
2.2
1
10/09/23 06:26
10/09/23 22:50
118-74-1
Hexachlorocyclopentadiene
<1.6
ug/L
10.0
1.6
1
10/09/23 06:26
10/09/23 22:50
77-47-4
Hexachloroethane
<1.4
ug/L
10.0
1.4
1
10/09/23 06:26
10/09/23 22:50
67-72-1
Hexachloropropene
<2.7
ug/L
10.0
2.7
1
10/09/23 06:26
10/09/23 22:50
1888-71-7
Indeno(1,2,3-cd)pyrene
<2.9
ug/L
10.0
2.9
1
10/09/23 06:26
10/09/23 22:50
193-39-5
Isodrin
<2.8
ug/L
10.0
2.8
1
10/09/23 06:26
10/09/23 22:50
465-73-6
Isophorone
<1.7
ug/L
10.0
1.7
1
10/09/23 06:26
10/09/23 22:50
78-59-1
Isosafrole
<2.5
ug/L
10.0
2.5
1
10/09/23 06:26
10/09/23 22:50
120-58-1
Kepone
<14.1
ug/L
20.0
14.1
1
10/09/23 06:26
10/09/23 22:50
143-50-0
Methapyrilene
<17.0
ug/L
50.0
17.0
1
10/09/23 06:26
10/09/23 22:50
91-80-5
3-Methylcholanthrene
<3.7
ug/L
10.0
3.7
1
10/09/23 06:26
10/09/23 22:50
56-49-5
REPORT OF LABORATORY ANALYSIS
IL
IH
v1
v1
v1
L2
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-02-20231005 Lab ID: 92691980003 Collected: 10/05/23 11:55 Received: 10/06/23 11:51 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Methyl methanesulfonate
<3.1
ug/L
5.0
3.1
1
10/09/23 06:26
10/09/23 22:50
66-27-3
2-Methylnaphthalene
<1.9
ug/L
10.0
1.9
1
10/09/23 06:26
10/09/23 22:50
91-57-6
Methyl parathion
<3.7
ug/L
10.0
3.7
1
10/09/23 06:26
10/09/23 22:50
298-00-0
2-Methylphenol(o-Cresol)
<1.9
ug/L
10.0
1.9
1
10/09/23 06:26
10/09/23 22:50
95-48-7
3&4-Methyl phenol (m&p Cresol)
<1.2
ug/L
10.0
1.2
1
10/09/23 06:26
10/09/23 22:50
15831-10-4
1-Naphthalenamine
<6.0
ug/L
10.0
6.0
1
10/09/23 06:26
10/09/23 22:50
134-32-7
2-Naphthalenamine
<5.4
ug/L
10.0
5.4
1
10/09/23 06:26
10/09/23 22:50
91-59-8
1,4-Naphthoquinone
<4.4
ug/L
5.0
4.4
1
10/09/23 06:26
10/09/23 22:50
130-15-4
2-Nitroaniline
<3.0
ug/L
20.0
3.0
1
10/09/23 06:26
10/09/23 22:50
88-74-4
3-Nitroaniline
<3.8
ug/L
20.0
3.8
1
10/09/23 06:26
10/09/23 22:50
99-09-2
4-Nitroaniline
<5.1
ug/L
20.0
5.1
1
10/09/23 06:26
10/09/23 22:50
100-01-6
Nitrobenzene
<1.9
ug/L
10.0
1.9
1
10/09/23 06:26
10/09/23 22:50
98-95-3
2-Nitrophenol
<1.4
ug/L
10.0
1.4
1
10/09/23 06:26
10/09/23 22:50
88-75-5
4-Nitrophenol
<6.6
ug/L
50.0
6.6
1
10/09/23 06:26
10/09/23 22:50
100-02-7
5-Nitro-o-toluidine
<3.8
ug/L
10.0
3.8
1
10/09/23 06:26
10/09/23 22:50
99-55-8
N-Nitrosodiethylamine
<2.3
ug/L
10.0
2.3
1
10/09/23 06:26
10/09/23 22:50
55-18-5
N-Nitrosodimethylamine
<1.9
ug/L
10.0
1.9
1
10/09/23 06:26
10/09/23 22:50
62-75-9
N-Nitroso-di-n-butylamine
<2.0
ug/L
10.0
2.0
1
10/09/23 06:26
10/09/23 22:50
924-16-3
N-Nitroso-di-n-propylamine
<1.3
ug/L
10.0
1.3
1
10/09/23 06:26
10/09/23 22:50
621-64-7
N-Nitrosodiphenylamine
<3.0
ug/L
10.0
3.0
1
10/09/23 06:26
10/09/23 22:50
86-30-6
N-Nitrosomethylethylamine
<7.5
ug/L
10.0
7.5
1
10/09/23 06:26
10/09/23 22:50
10595-95-6
N-Nitrosopiperidine
<2.5
ug/L
10.0
2.5
1
10/09/23 06:26
10/09/23 22:50
100-75-4
N-Nitrosopyrrolidine
<3.1
ug/L
10.0
3.1
1
10/09/23 06:26
10/09/23 22:50
930-55-2
O,O,O-Triethylphosphorothioate
<2.6
ug/L
10.0
2.6
1
10/09/23 06:26
10/09/23 22:50
126-68-1
2,2'-Oxybis(1-chloropropane)
<1.2
ug/L
10.0
1.2
1
10/09/23 06:26
10/09/23 22:50
108-60-1
Parathion (Ethyl parathion)
<3.9
ug/L
10.0
3.9
1
10/09/23 06:26
10/09/23 22:50
56-38-2
Pentachlorobenzene
<3.4
ug/L
10.0
3.4
1
10/09/23 06:26
10/09/23 22:50
608-93-5
Pentachloronitrobenzene
<3.3
ug/L
10.0
3.3
1
10/09/23 06:26
10/09/23 22:50
82-68-8
Pentachlorophenol
<3.8
ug/L
20.0
3.8
1
10/09/23 06:26
10/09/23 22:50
87-86-5
Phenacetin
<3.6
ug/L
10.0
3.6
1
10/09/23 06:26
10/09/23 22:50
62-44-2
Phenanthrene
<2.0
ug/L
10.0
2.0
1
10/09/23 06:26
10/09/23 22:50
85-01-8
Phenol
<1.4
ug/L
10.0
1.4
1
10/09/23 06:26
10/09/23 22:50
108-95-2
p-Phenylenediamine
<10.0
ug/L
10.0
10.0
1
10/09/23 06:26
10/09/23 22:50
106-50-3
Phorate
<3.6
ug/L
10.0
3.6
1
10/09/23 06:26
10/09/23 22:50
298-02-2
Pronamide
<3.1
ug/L
10.0
3.1
1
10/09/23 06:26
10/09/23 22:50
23950-58-5
Pyrene
<2.2
ug/L
10.0
2.2
1
10/09/23 06:26
10/09/23 22:50
129-00-0
Safrole
<2.3
ug/L
10.0
2.3
1
10/09/23 06:26
10/09/23 22:50
94-59-7
1,2,4,5-Tetrachlorobenzene
<4.5
ug/L
10.0
4.5
1
10/09/23 06:26
10/09/23 22:50
95-94-3
2,3,4,6-Tetrachlorophenol
<1.5
ug/L
10.0
1.5
1
10/09/23 06:26
10/09/23 22:50
58-90-2
Thionazin
<2.9
ug/L
10.0
2.9
1
10/09/23 06:26
10/09/23 22:50
297-97-2
O-Toluidine
<2.6
ug/L
10.0
2.6
1
10/09/23 06:26
10/09/23 22:50
95-53-4
2,4,5-Trichlorophenol
<1.4
ug/L
10.0
1.4
1
10/09/23 06:26
10/09/23 22:50
95-95-4
2,4,6-Trichlorophenol
<1.6
ug/L
10.0
1.6
1
10/09/23 06:26
10/09/23 22:50
88-06-2
1,3,5-Trinitrobenzene
<5.5
ug/L
10.0
5.5
1
10/09/23 06:26
10/09/23 22:50
99-35-4
REPORT OF LABORATORY ANALYSIS
v1
v1
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-02-20231005 Lab ID: 92691980003 Collected: 10/05/23 11:55 Received: 10/06/23 11:51 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260D MSV Low Level Landfill
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
109
%
10-138
1
10/09/23 06:26
10/09/23 22:50
4165-60-0
103
%
10-130
1
10/09/23 06:26
10/09/23 22:50
321-60-8
115
%
19-191
1
10/09/23 06:26
10/09/23 22:50
1718-51-0
42
%
10-130
1
10/09/23 06:26
10/09/23 22:50
13127-88-3
25
%
10-130
1
10/09/23 06:26
10/09/23 22:50
367-12-4
48
%
10-164
1
10/09/23 06:26
10/09/23 22:50
118-79-6
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
<5.1
ug/L
25.0
5.1
1
10/11/23 05:34
67-64-1
<0.34
ug/L
1.0
0.34
1
10/11/23 05:34
71-43-2
<0.29
ug/L
1.0
0.29
1
10/11/23 05:34
108-86-1
<0.47
ug/L
1.0
0.47
1
10/11/23 05:34
74-97-5
<0.31
ug/L
1.0
0.31
1
10/11/23 05:34
75-27-4
<0.34
ug/L
1.0
0.34
1
10/11/23 05:34
75-25-2
<1.7
ug/L
2.0
1.7
1
10/11/23 05:34
74-83-9
<4.0
ug/L
5.0
4.0
1
10/11/23 05:34
78-93-3
<0.33
ug/L
1.0
0.33
1
10/11/23 05:34
56-23-5
<0.28
ug/L
1.0
0.28
1
10/11/23 05:34
108-90-7
<0.65
ug/L
1.0
0.65
1
10/11/23 05:34
75-00-3
<0.43
ug/L
1.0
0.43
1
10/11/23 05:34
67-66-3
<0.54
ug/L
1.0
0.54
1
10/11/23 05:34
74-87-3
<0.32
ug/L
1.0
0.32
1
10/11/23 05:34
95-49-8
<0.32
ug/L
1.0
0.32
1
10/11/23 05:34
106-43-4
<0.34
ug/L
2.0
0.34
1
10/11/23 05:34
96-12-8
<0.36
ug/L
1.0
0.36
1
10/11/23 05:34
124-48-1
<0.27
ug/L
1.0
0.27
1
10/11/23 05:34
106-93-4
<0.39
ug/L
1.0
0.39
1
10/11/23 05:34
74-95-3
<0.34
ug/L
1.0
0.34
1
10/11/23 05:34
95-50-1
<0.34
ug/L
1.0
0.34
1
10/11/23 05:34
541-73-1
<0.33
ug/L
1.0
0.33
1
10/11/23 05:34
106-46-7
<0.35
ug/L
1.0
0.35
1
10/11/23 05:34
75-71-8
<0.37
ug/L
1.0
0.37
1
10/11/23 05:34
75-34-3
<0.32
ug/L
1.0
0.32
1
10/11/23 05:34
107-06-2
<0.35
ug/L
1.0
0.35
1
10/11/23 05:34
75-35-4
<0.38
ug/L
1.0
0.38
1
10/11/23 05:34
156-59-2
<0.40
ug/L
1.0
0.40
1
10/11/23 05:34
156-60-5
<0.36
ug/L
1.0
0.36
1
10/11/23 05:34
78-87-5
<0.28
ug/L
1.0
0.28
1
10/11/23 05:34
142-28-9
<0.39
ug/L
1.0
0.39
1
10/11/23 05:34
594-20-7
<0.43
ug/L
1.0
0.43
1
10/11/23 05:34
563-58-6
<0.36
ug/L
1.0
0.36
1
10/11/23 05:34
10061-01-5
<0.36
ug/L
1.0
0.36
1
10/11/23 05:34
10061-02-6
<0.31
ug/L
1.0
0.31
1
10/11/23 05:34
108-20-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 45 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-02-20231005 Lab ID: 92691980003 Collected: 10/05/23 11:55 Received: 10/06/23 11:51 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Iron, Ferric (Calculation)
Iron, Ferric
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
<0.30
ug/L
1.0
<1.5
ug/L
2.0
<0.48
ug/L
5.0
<0.41
ug/L
1.0
<2.0
ug/L
5.0
<2.7
ug/L
5.0
<0.42
ug/L
1.0
<0.64
ug/L
1.0
<0.29
ug/L
1.0
<0.31
ug/L
1.0
<0.22
ug/L
1.0
<0.29
ug/L
1.0
<0.24
ug/L
1.0
<0.81
ug/L
1.0
<0.64
ug/L
1.0
<0.33
ug/L
1.0
<0.32
ug/L
1.0
<0.38
ug/L
1.0
<0.30
ug/L
1.0
<0.26
ug/L
1.0
<1.3
ug/L
2.0
<0.39
ug/L
1.0
<0.34
ug/L
1.0
<0.71
ug/L
2.0
<0.34
ug/L
1.0
99
%
70-130
95
%
70-130
103
%
70-130
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
2.3
ug/L
2.0
92 % 67-130
95 % 70-130
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
43.4 mg/L 5.0
Analytical Method: SM 3500-Fe D#4
Pace Analytical Services -Asheville
2.3 mg/L 0.50
0.30
1
10/11/23 05:34
100-41-4
1.5
1
10/11/23 05:34
87-68-3
0.48
1
10/11/23 05:34
591-78-6
0.41
1
10/11/23 05:34
99-87-6
2.0
1
10/11/23 05:34
75-09-2
2.7
1
10/11/23 05:34
108-10-1
0.42
1
10/11/23 05:34
1634-04-4
0.64
1
10/11/23 05:34
91-20-3
0.29
1
10/11/23 05:34
100-42-5
0.31
1
10/11/23 05:34
630-20-6
0.22
1
10/11/23 05:34
79-34-5
0.29
1
10/11/23 05:34
127-18-4
0.24
1
10/11/23 05:34
108-88-3
0.81
1
10/11/23 05:34
87-61-6
0.64
1
10/11/23 05:34
120-82-1
0.33
1
10/11/23 05:34
71-55-6
0.32
1
10/11/23 05:34
79-00-5
0.38
1
10/11/23 05:34
79-01-6
0.30
1
10/11/23 05:34
75-69-4
0.26
1
10/11/23 05:34
96-18-4
1.3
1
10/11/23 05:34
108-05-4 v2
0.39
1
10/11/23 05:34
75-01-4
0.34
1
10/11/23 05:34
1330-20-7
0.71
1
10/11/23 05:34
179601-23-1
0.34
1
10/11/23 05:34
95-47-6
1 10/11/23 05:34 460-00-4
1 10/11/23 05:34 17060-07-0
1 10/11/23 05:34 2037-26-5
0.86 1 10/09/23 22:19 123-91-1
1 10/09/23 22:19 17060-07-0
1 10/09/23 22:19 2037-26-5
5.0 1 10/13/23 18:21
0.25 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
11/28/23 08:24 20074-52-6 N2
Page 46 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: MW-02-20231005
Lab ID: 92691980003 Collected:
10/05/23
11:55
Received: 10/06/23
11:51 Matrix: Water
Parameters
Results Units PQL
MDL
DF
Prepared
Analyzed
CAS No. Qual
Iron, Ferrous
Analytical Method: SM 3500-Fe B-2011
Pace Analytical Services -Asheville
Iron, Ferrous
0.068J mg/L 0.50
0.040
1
10/17/23 11:27
H3,N2
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
0.042J mg/L 0.10
0.022
1
10/11/23 01:18
18496-25-8
5210B BOD, 5 day
Analytical Method: SM 521OB-2011
Pace Analytical Services -Asheville
BOD, 5 day
<2.0 mg/L 2.0
2.0
1
10/07/23 07:22
10/12/23 01:29
2g
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
<12.5 mg/L 25.0
12.5
1
10/19/23 03:19
10/19/23 23:55
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
2.7 mg/L 1.0
0.50
1
10/16/23 18:49
7440-44-0
9056 IC Anions 48hr
Analytical Method: EPA 9056A
Pace Analytical Services -Asheville
Chloride
21.3 mg/L 1.0
0.60
1
10/06/2317:57
16887-00-6
Nitrate as N
0.19 mg/L 0.10
0.060
1
10/06/23 17:57
14797-55-8
Sulfate
22.7 mg/L 1.0
0.50
1
10/06/2317:57
14808-79-8
Date: 02/23/2024 01:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 47 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: DUP-20231005 Lab ID: 92691980004 Collected: 10/05/23 09:36 Received: 10/06/23 11:51 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Ethane
<5.9
ug/L
10.0
5.9
1
10/12/2315:25
74-84-0
Ethene
<5.7
ug/L
10.0
5.7
1
10/12/2315:25
74-85-1
Methane
<5.3
ug/L
10.0
5.3
1
10/12/2315:25
74-82-8
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Antimony
<0.20
ug/L
1.0
0.20
1
10/10/2315:20
10/11/2315:39
7440-36-0
Arsenic
<0.087
ug/L
1.0
0.087
1
10/10/2315:20
10/11/2315:39
7440-38-2
Barium
48.2
ug/L
1.0
0.21
1
10/10/2315:20
10/11/2315:39
7440-39-3
Beryllium
0.078J
ug/L
0.10
0.050
1
10/10/2315:20
10/11/2315:39
7440-41-7
Cadmium
0.12J
ug/L
0.20
0.060
1
10/10/2315:20
10/11/2315:39
7440-43-9
Chromium
0.58J
ug/L
1.0
0.50
1
10/10/2315:20
10/11/2315:39
7440-47-3
Cobalt
3.1
ug/L
1.0
0.050
1
10/10/2315:20
10/11/2315:39
7440-48-4
Copper
1.2J
ug/L
2.0
1.1
1
10/10/2315:20
10/11/2315:39
7440-50-8
Iron
37.6J
ug/L
50.0
20.9
1
10/18/2312:10
10/18/2319:21
7439-89-6
Lead
0.14J
ug/L
1.0
0.077
1
10/10/2315:20
10/11/2315:39
7439-92-1
Nickel
3.9
ug/L
1.0
0.42
1
10/10/2315:20
10/11/2315:39
7440-02-0
Selenium
<0.072
ug/L
2.0
0.072
1
10/10/2315:20
10/11/2315:39
7782-49-2
Silver
<0.070
ug/L
0.40
0.070
1
10/10/2315:20
10/11/2315:39
7440-22-4
Thallium
0.25
ug/L
0.20
0.050
1
10/10/2315:20
10/11/2315:39
7440-28-0
Tin
<0.43
ug/L
1.0
0.43
1
10/10/2315:20
10/11/2315:39
7440-31-5
Vanadium
0.37J
ug/L
1.0
0.25
1
10/10/2315:20
10/11/2315:39
7440-62-2
7470 Mercury
Mercury
8270E APP9 RV
Acenaphthene
Acenaphthylene
Acetophenone
2-Acetylaminofluorene
4-Aminobiphenyl
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Benzyl alcohol
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methyl phenol
4-Chloroaniline
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
<0.12 ug/L 0.20 0.12 1 10/13/2315:08 10/14/2311:50 7439-97-6
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
<1.7
ug/L
8.7
1.7
1
10/11/2316:36
10/12/2315:54
83-32-9
<1.7
ug/L
8.7
1.7
1
10/11/2316:36
10/12/2315:54
208-96-8
<1.3
ug/L
8.7
1.3
1
10/11/2316:36
10/12/2315:54
98-86-2
<3.5
ug/L
8.7
3.5
1
10/11/2316:36
10/12/2315:54
53-96-3
<4.1
ug/L
8.7
4.1
1
10/11/2316:36
10/12/2315:54
92-67-1
<2.0
ug/L
8.7
2.0
1
10/11/2316:36
10/12/2315:54
120-12-7
<2.3
ug/L
8.7
2.3
1
10/11/2316:36
10/12/2315:54
56-55-3
<2.4
ug/L
8.7
2.4
1
10/11/2316:36
10/12/2315:54
50-32-8
<2.3
ug/L
8.7
2.3
1
10/11/2316:36
10/12/2315:54
205-99-2
<2.5
ug/L
8.7
2.5
1
10/11/2316:36
10/12/2315:54
191-24-2
<2.4
ug/L
8.7
2.4
1
10/11/2316:36
10/12/2315:54
207-08-9
<2.5
ug/L
17.4
2.5
1
10/11/2316:36
10/12/2315:54
100-51-6
<1.5
ug/L
8.7
1.5
1
10/11/2316:36
10/12/2315:54
101-55-3
<2.7
ug/L
8.7
2.7
1
10/11/2316:36
10/12/2315:54
85-68-7
<2.9
ug/L
8.7
2.9
1
10/11/2316:36
10/12/2315:54
59-50-7
<3.2
ug/L
17.4
3.2
1
10/11/2316:36
10/12/2315:54
106-47-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 48 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: DUP-20231005 Lab ID: 92691980004 Collected: 10/05/23 09:36 Received: 10/06/23 11:51 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Chlorobenzilate
<3.3
ug/L
8.7
3.3
1
10/11/23 16:36
10/12/23 15:54
510-15-6
bis(2-Chloroethoxy)methane
<1.6
ug/L
8.7
1.6
1
10/11/23 16:36
10/12/23 15:54
111-91-1
bis(2-Chloroethyl) ether
<1.7
ug/L
8.7
1.7
1
10/11/23 16:36
10/12/23 15:54
111-44-4
2-Chloronaphthalene
<1.5
ug/L
8.7
1.5
1
10/11/23 16:36
10/12/23 15:54
91-58-7
2-Chlorophenol
<1.0
ug/L
8.7
1.0
1
10/11/23 16:36
10/12/23 15:54
95-57-8
4-Chlorophenylphenyl ether
<1.7
ug/L
8.7
1.7
1
10/11/23 16:36
10/12/23 15:54
7005-72-3
Chrysene
<2.4
ug/L
8.7
2.4
1
10/11/23 16:36
10/12/23 15:54
218-01-9
Diallate
<3.0
ug/L
8.7
3.0
1
10/11/23 16:36
10/12/23 15:54
2303-16-4
Dibenz(a,h)anthracene
<2.6
ug/L
8.7
2.6
1
10/11/23 16:36
10/12/23 15:54
53-70-3
Dibenzofuran
<1.8
ug/L
8.7
1.8
1
10/11/23 16:36
10/12/23 15:54
132-64-9
3,3'-Dichlorobenzidine
<7.1
ug/L
17.4
7.1
1
10/11/23 16:36
10/12/23 15:54
91-94-1
2,4-Dichlorophenol
<1.2
ug/L
8.7
1.2
1
10/11/23 16:36
10/12/23 15:54
120-83-2
2,6-Dichlorophenol
<3.7
ug/L
8.7
3.7
1
10/11/23 16:36
10/12/23 15:54
87-65-0
Diethylphthalate
<1.8
ug/L
8.7
1.8
1
10/11/23 16:36
10/12/23 15:54
84-66-2
Dimethoate
<3.2
ug/L
8.7
3.2
1
10/11/23 16:36
10/12/23 15:54
60-51-5
P-Dimethylaminoazobenzene
<2.1
ug/L
4.3
2.1
1
10/11/23 16:36
10/12/23 15:54
60-11-7
7,12-Dimethylbenz(a)anthracene
<2.6
ug/L
8.7
2.6
1
10/11/23 16:36
10/12/23 15:54
57-97-6
3,3'-Dimethylbenzidine
<27.0
ug/L
43.5
27.0
1
10/11/23 16:36
10/12/23 15:54
119-93-7
2,4-Dimethylphenol
<1.5
ug/L
8.7
1.5
1
10/11/23 16:36
10/12/23 15:54
105-67-9
Dimethylphthalate
<1.9
ug/L
8.7
1.9
1
10/11/23 16:36
10/12/23 15:54
131-11-3
Di-n-butylphthalate
<1.9
ug/L
8.7
1.9
1
10/11/23 16:36
10/12/23 15:54
84-74-2
4,6-Dinitro-2-methyl phenol
<6.8
ug/L
17.4
6.8
1
10/11/23 16:36
10/12/23 15:54
534-52-1
1,3-Dinitrobenzene
<3.3
ug/L
8.7
3.3
1
10/11/23 16:36
10/12/23 15:54
99-65-0
2,4-Dinitrophenol
<22.6
ug/L
43.5
22.6
1
10/11/23 16:36
10/12/23 15:54
51-28-5
2,4-Dinitrotoluene
<1.4
ug/L
8.7
1.4
1
10/11/23 16:36
10/12/23 15:54
121-14-2
2,6-Dinitrotoluene
<1.5
ug/L
8.7
1.5
1
10/11/23 16:36
10/12/23 15:54
606-20-2
Di-n-octylphthalate
<3.4
ug/L
8.7
3.4
1
10/11/23 16:36
10/12/23 15:54
117-84-0
Diphenylamine
<2.6
ug/L
8.7
2.6
1
10/11/23 16:36
10/12/23 15:54
122-39-4
Disulfoton
<4.0
ug/L
8.7
4.0
1
10/11/23 16:36
10/12/23 15:54
298-04-4
bis(2- Ethyl hexyl)phthalate
<3.2
ug/L
5.2
3.2
1
10/11/23 16:36
10/12/23 15:54
117-81-7
Ethyl methanesulfonate
<2.6
ug/L
17.4
2.6
1
10/11/23 16:36
10/12/23 15:54
62-50-0
Famphur
<5.3
ug/L
8.7
5.3
1
10/11/23 16:36
10/12/23 15:54
52-85-7
Fluoranthene
<1.9
ug/L
8.7
1.9
1
10/11/23 16:36
10/12/23 15:54
206-44-0
Fluorene
<1.8
ug/L
8.7
1.8
1
10/11/23 16:36
10/12/23 15:54
86-73-7
Hexachlorobenzene
<1.9
ug/L
8.7
1.9
1
10/11/23 16:36
10/12/23 15:54
118-74-1
Hexachlorocyclopentadiene
<1.4
ug/L
8.7
1.4
1
10/11/23 16:36
10/12/23 15:54
77-47-4
Hexachloroethane
<1.2
ug/L
8.7
1.2
1
10/11/23 16:36
10/12/23 15:54
67-72-1
Hexachloropropene
<2.3
ug/L
8.7
2.3
1
10/11/23 16:36
10/12/23 15:54
1888-71-7
Indeno(1,2,3-cd)pyrene
<2.5
ug/L
8.7
2.5
1
10/11/23 16:36
10/12/23 15:54
193-39-5
Isodrin
<2.4
ug/L
8.7
2.4
1
10/11/23 16:36
10/12/23 15:54
465-73-6
Isophorone
<1.4
ug/L
8.7
1.4
1
10/11/23 16:36
10/12/23 15:54
78-59-1
Isosafrole
<2.2
ug/L
8.7
2.2
1
10/11/23 16:36
10/12/23 15:54
120-58-1
Kepone
<12.3
ug/L
17.4
12.3
1
10/11/23 16:36
10/12/23 15:54
143-50-0
Methapyrilene
<14.8
ug/L
43.5
14.8
1
10/11/23 16:36
10/12/23 15:54
91-80-5
3-Methylcholanthrene
<3.3
ug/L
8.7
3.3
1
10/11/23 16:36
10/12/23 15:54
56-49-5
REPORT OF LABORATORY ANALYSIS
IL
IH,L2
L1
v1
v1
L2
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 49 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: DUP-20231005
Lab ID:
92691980004
Collected:
10/05/23
09:36
Received: 10/06/23 11:51 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared
Analyzed
CAS No. Qual
8270E APP9 RV
Analytical
Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services - Charlotte
Methyl methanesulfonate
<2.7
ug/L
4.3
2.7
1
10/11/23 16:36
10/12/23 15:54
66-27-3
2-Methylnaphthalene
<1.6
ug/L
8.7
1.6
1
10/11/23 16:36
10/12/23 15:54
91-57-6
Methyl parathion
<3.2
ug/L
8.7
3.2
1
10/11/23 16:36
10/12/23 15:54
298-00-0
2-Methylphenol(o-Cresol)
<1.6
ug/L
8.7
1.6
1
10/11/23 16:36
10/12/23 15:54
95-48-7
3&4-Methyl phenol (m&p Cresol)
<1.1
ug/L
8.7
1.1
1
10/11/23 16:36
10/12/23 15:54
15831-10-4
1-Naphthalenamine
<5.2
ug/L
8.7
5.2
1
10/11/23 16:36
10/12/23 15:54
134-32-7
2-Naphthalenamine
<4.7
ug/L
8.7
4.7
1
10/11/23 16:36
10/12/23 15:54
91-59-8
1,4-Naphthoquinone
<3.8
ug/L
4.3
3.8
1
10/11/23 16:36
10/12/23 15:54
130-15-4
2-Nitroaniline
<2.6
ug/L
17.4
2.6
1
10/11/23 16:36
10/12/23 15:54
88-74-4
3-Nitroaniline
<3.3
ug/L
17.4
3.3
1
10/11/23 16:36
10/12/23 15:54
99-09-2
4-Nitroaniline
<4.4
ug/L
17.4
4.4
1
10/11/23 16:36
10/12/23 15:54
100-01-6
Nitrobenzene
<1.6
ug/L
8.7
1.6
1
10/11/23 16:36
10/12/23 15:54
98-95-3
2-Nitrophenol
<1.2
ug/L
8.7
1.2
1
10/11/23 16:36
10/12/23 15:54
88-75-5
4-Nitrophenol
<5.7
ug/L
43.5
5.7
1
10/11/23 16:36
10/12/23 15:54
100-02-7
5-Nitro-o-toluidine
<3.3
ug/L
8.7
3.3
1
10/11/23 16:36
10/12/23 15:54
99-55-8
N-Nitrosodiethylamine
<2.0
ug/L
8.7
2.0
1
10/11/23 16:36
10/12/23 15:54
55-18-5
N-Nitrosodimethylamine
<1.6
ug/L
8.7
1.6
1
10/11/23 16:36
10/12/23 15:54
62-75-9
N-Nitroso-di-n-butylamine
<1.7
ug/L
8.7
1.7
1
10/11/23 16:36
10/12/23 15:54
924-16-3
N-Nitroso-di-n-propylamine
<1.2
ug/L
8.7
1.2
1
10/11/23 16:36
10/12/23 15:54
621-64-7
N-Nitrosodiphenylamine
<2.6
ug/L
8.7
2.6
1
10/11/23 16:36
10/12/23 15:54
86-30-6
N-Nitrosomethylethylamine
<6.5
ug/L
8.7
6.5
1
10/11/23 16:36
10/12/23 15:54
10595-95-6
N-Nitrosopiperidine
<2.2
ug/L
8.7
2.2
1
10/11/23 16:36
10/12/23 15:54
100-75-4
N-Nitrosopyrrolidine
<2.7
ug/L
8.7
2.7
1
10/11/23 16:36
10/12/23 15:54
930-55-2
O,O,O-Triethylphosphorothioate
<2.2
ug/L
8.7
2.2
1
10/11/23 16:36
10/12/23 15:54
126-68-1 v1
2,2'-Oxybis(1-chloropropane)
<1.0
ug/L
8.7
1.0
1
10/11/23 16:36
10/12/23 15:54
108-60-1
Parathion (Ethyl parathion)
<3.4
ug/L
8.7
3.4
1
10/11/23 16:36
10/12/23 15:54
56-38-2
Pentachlorobenzene
<3.0
ug/L
8.7
3.0
1
10/11/23 16:36
10/12/23 15:54
608-93-5
Pentachloronitrobenzene
<2.8
ug/L
8.7
2.8
1
10/11/23 16:36
10/12/23 15:54
82-68-8
Pentachlorophenol
<3.3
ug/L
17.4
3.3
1
10/11/23 16:36
10/12/23 15:54
87-86-5
Phenacetin
<3.1
ug/L
8.7
3.1
1
10/11/23 16:36
10/12/23 15:54
62-44-2
Phenanthrene
<1.7
ug/L
8.7
1.7
1
10/11/23 16:36
10/12/23 15:54
85-01-8
Phenol
<1.2
ug/L
8.7
1.2
1
10/11/23 16:36
10/12/23 15:54
108-95-2
p-Phenylenediamine
<8.7
ug/L
8.7
8.7
1
10/11/23 16:36
10/12/23 15:54
106-50-3
Phorate
<3.1
ug/L
8.7
3.1
1
10/11/23 16:36
10/12/23 15:54
298-02-2
Pronamide
<2.7
ug/L
8.7
2.7
1
10/11/23 16:36
10/12/23 15:54
23950-58-5
Pyrene
<1.9
ug/L
8.7
1.9
1
10/11/23 16:36
10/12/23 15:54
129-00-0
Safrole
<2.0
ug/L
8.7
2.0
1
10/11/23 16:36
10/12/23 15:54
94-59-7
1,2,4,5-Tetrachlorobenzene
<3.9
ug/L
8.7
3.9
1
10/11/23 16:36
10/12/23 15:54
95-94-3
2,3,4,6-Tetrachlorophenol
<1.3
ug/L
8.7
1.3
1
10/11/23 16:36
10/12/23 15:54
58-90-2
Thionazin
<2.5
ug/L
8.7
2.5
1
10/11/23 16:36
10/12/23 15:54
297-97-2
O-Toluidine
<2.3
ug/L
8.7
2.3
1
10/11/23 16:36
10/12/23 15:54
95-53-4
2,4,5-Trichlorophenol
<1.2
ug/L
8.7
1.2
1
10/11/23 16:36
10/12/23 15:54
95-95-4 L1
2,4,6-Trichlorophenol
<1.3
ug/L
8.7
1.3
1
10/11/23 16:36
10/12/23 15:54
88-06-2
1,3,5-Trinitrobenzene
<4.8
ug/L
8.7
4.8
1
10/11/23 16:36
10/12/23 15:54
99-35-4 v2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 50 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: DUP-20231005 Lab ID: 92691980004 Collected: 10/05/23 09:36 Received: 10/06/23 11:51 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260D MSV Low Level Landfill
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
40
%
10-138
1
10/11/2316:36
10/12/2315:54
4165-60-0
40
%
10-130
1
10/11/2316:36
10/12/2315:54
321-60-8
42
%
19-191
1
10/11/2316:36
10/12/2315:54
1718-51-0
22
%
10-130
1
10/11/2316:36
10/12/2315:54
13127-88-3
31
%
10-130
1
10/11/2316:36
10/12/2315:54
367-12-4
44
%
10-164
1
10/11/2316:36
10/12/2315:54
118-79-6
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
<5.1
ug/L
25.0
5.1
1
10/11/23 05:52
67-64-1
<0.34
ug/L
1.0
0.34
1
10/11/23 05:52
71-43-2
<0.29
ug/L
1.0
0.29
1
10/11/23 05:52
108-86-1
<0.47
ug/L
1.0
0.47
1
10/11/23 05:52
74-97-5
<0.31
ug/L
1.0
0.31
1
10/11/23 05:52
75-27-4
<0.34
ug/L
1.0
0.34
1
10/11/23 05:52
75-25-2
<1.7
ug/L
2.0
1.7
1
10/11/23 05:52
74-83-9
<4.0
ug/L
5.0
4.0
1
10/11/23 05:52
78-93-3
<0.33
ug/L
1.0
0.33
1
10/11/23 05:52
56-23-5
<0.28
ug/L
1.0
0.28
1
10/11/23 05:52
108-90-7
<0.65
ug/L
1.0
0.65
1
10/11/23 05:52
75-00-3
<0.43
ug/L
1.0
0.43
1
10/11/23 05:52
67-66-3
<0.54
ug/L
1.0
0.54
1
10/11/23 05:52
74-87-3
<0.32
ug/L
1.0
0.32
1
10/11/23 05:52
95-49-8
<0.32
ug/L
1.0
0.32
1
10/11/23 05:52
106-43-4
<0.34
ug/L
2.0
0.34
1
10/11/23 05:52
96-12-8
<0.36
ug/L
1.0
0.36
1
10/11/23 05:52
124-48-1
<0.27
ug/L
1.0
0.27
1
10/11/23 05:52
106-93-4
<0.39
ug/L
1.0
0.39
1
10/11/23 05:52
74-95-3
<0.34
ug/L
1.0
0.34
1
10/11/23 05:52
95-50-1
<0.34
ug/L
1.0
0.34
1
10/11/23 05:52
541-73-1
<0.33
ug/L
1.0
0.33
1
10/11/23 05:52
106-46-7
<0.35
ug/L
1.0
0.35
1
10/11/23 05:52
75-71-8
0.76J
ug/L
1.0
0.37
1
10/11/23 05:52
75-34-3
<0.32
ug/L
1.0
0.32
1
10/11/23 05:52
107-06-2
<0.35
ug/L
1.0
0.35
1
10/11/23 05:52
75-35-4
0.45J
ug/L
1.0
0.38
1
10/11/23 05:52
156-59-2
<0.40
ug/L
1.0
0.40
1
10/11/23 05:52
156-60-5
<0.36
ug/L
1.0
0.36
1
10/11/23 05:52
78-87-5
<0.28
ug/L
1.0
0.28
1
10/11/23 05:52
142-28-9
<0.39
ug/L
1.0
0.39
1
10/11/23 05:52
594-20-7
<0.43
ug/L
1.0
0.43
1
10/11/23 05:52
563-58-6
<0.36
ug/L
1.0
0.36
1
10/11/23 05:52
10061-01-5
<0.36
ug/L
1.0
0.36
1
10/11/23 05:52
10061-02-6
<0.31
ug/L
1.0
0.31
1
10/11/23 05:52
108-20-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
v2
Page 51 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: DUP-20231005 Lab ID: 92691980004 Collected: 10/05/23 09:36 Received: 10/06/23 11:51 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Iron, Ferric (Calculation)
Iron, Ferric
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
<0.30
ug/L
1.0
<1.5
ug/L
2.0
<0.48
ug/L
5.0
<0.41
ug/L
1.0
<2.0
ug/L
5.0
<2.7
ug/L
5.0
0.45J
ug/L
1.0
<0.64
ug/L
1.0
<0.29
ug/L
1.0
<0.31
ug/L
1.0
<0.22
ug/L
1.0
<0.29
ug/L
1.0
<0.24
ug/L
1.0
<0.81
ug/L
1.0
<0.64
ug/L
1.0
<0.33
ug/L
1.0
<0.32
ug/L
1.0
<0.38
ug/L
1.0
<0.30
ug/L
1.0
<0.26
ug/L
1.0
<1.3
ug/L
2.0
<0.39
ug/L
1.0
<0.34
ug/L
1.0
<0.71
ug/L
2.0
<0.34
ug/L
1.0
98
%
70-130
98
%
70-130
104
%
70-130
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
<0.86
ug/L
2.0
89 % 67-130
94 % 70-130
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
29.7 mg/L 5.0
Analytical Method: SM 3500-Fe D#4
Pace Analytical Services -Asheville
<0.25 mg/L 0.50
0.30
1
10/11/23 05:52
100-41-4
1.5
1
10/11/23 05:52
87-68-3
0.48
1
10/11/23 05:52
591-78-6
0.41
1
10/11/23 05:52
99-87-6
2.0
1
10/11/23 05:52
75-09-2
2.7
1
10/11/23 05:52
108-10-1
0.42
1
10/11/23 05:52
1634-04-4
0.64
1
10/11/23 05:52
91-20-3
0.29
1
10/11/23 05:52
100-42-5
0.31
1
10/11/23 05:52
630-20-6
0.22
1
10/11/23 05:52
79-34-5
0.29
1
10/11/23 05:52
127-18-4
0.24
1
10/11/23 05:52
108-88-3
0.81
1
10/11/23 05:52
87-61-6
0.64
1
10/11/23 05:52
120-82-1
0.33
1
10/11/23 05:52
71-55-6
0.32
1
10/11/23 05:52
79-00-5
0.38
1
10/11/23 05:52
79-01-6
0.30
1
10/11/23 05:52
75-69-4
0.26
1
10/11/23 05:52
96-18-4
1.3
1
10/11/23 05:52
108-05-4 v2
0.39
1
10/11/23 05:52
75-01-4
0.34
1
10/11/23 05:52
1330-20-7
0.71
1
10/11/23 05:52
179601-23-1
0.34
1
10/11/23 05:52
95-47-6
1 10/11/23 05:52 460-00-4
1 10/11/23 05:52 17060-07-0
1 10/11/23 05:52 2037-26-5
0.86 1 10/09/23 22:41 123-91-1
1 10/09/23 22:41 17060-07-0
1 10/09/23 22:41 2037-26-5
5.0 1 10/13/23 18:39
0.25 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
11/28/23 08:24 20074-52-6 N2
Page 52 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: DUP-20231005
Lab ID: 92691980004 Collected:
10/05/23 09:36
Received: 10/06/23 11:51 Matrix: Water
Parameters
Results Units PQL
MDL
DF
Prepared
Analyzed
CAS No. Qual
Iron, Ferrous
Analytical Method: SM 3500-Fe B-2011
Pace Analytical Services -Asheville
Iron, Ferrous
0.054J mg/L 0.50
0.040
1
10/17/23 11:25
H3,N2
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
<0.022 mg/L 0.10
0.022
1
10/11/23 01:19
18496-25-8
5210B BOD, 5 day
Analytical Method: SM 521OB-2011
Pace Analytical Services -Asheville
BOD, 5 day
<2.0 mg/L 2.0
2.0
1
10/07/23 07:22
10/12/23 01:24
2g
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
<12.5 mg/L 25.0
12.5
1
10/19/23 03:19
10/19/23 23:55
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
<0.50 mg/L 1.0
0.50
1
10/16/23 19:51
7440-44-0
9056 IC Anions 48hr
Analytical Method: EPA 9056A
Pace Analytical Services -Asheville
Chloride
0.93J mg/L 1.0
0.60
1
10/06/2317:42
16887-00-6
Nitrate as N
0.25 mg/L 0.10
0.060
1
10/06/23 17:42
14797-55-8
Sulfate
0.891 mg/L 1.0
0.50
1
10/06/2317:42
14808-79-8
Date: 02/23/2024 01:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 53 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: TB-20231005 Lab ID: 92691980005 Collected: 10/05/23 00:00 Received: 10/06/23 11:51 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
<5.1
ug/L
25.0
5.1
1
10/09/23 11:31
67-64-1
<0.34
ug/L
1.0
0.34
1
10/09/23 11:31
71-43-2
<0.29
ug/L
1.0
0.29
1
10/09/23 11:31
108-86-1
<0.47
ug/L
1.0
0.47
1
10/09/23 11:31
74-97-5
<0.31
ug/L
1.0
0.31
1
10/09/23 11:31
75-27-4
<0.34
ug/L
1.0
0.34
1
10/09/23 11:31
75-25-2
<1.7
ug/L
2.0
1.7
1
10/09/23 11:31
74-83-9 v2
<4.0
ug/L
5.0
4.0
1
10/09/23 11:31
78-93-3
<0.33
ug/L
1.0
0.33
1
10/09/23 11:31
56-23-5
<0.28
ug/L
1.0
0.28
1
10/09/23 11:31
108-90-7
<0.65
ug/L
1.0
0.65
1
10/09/23 11:31
75-00-3
<0.43
ug/L
1.0
0.43
1
10/09/23 11:31
67-66-3
<0.54
ug/L
1.0
0.54
1
10/09/23 11:31
74-87-3
<0.32
ug/L
1.0
0.32
1
10/09/23 11:31
95-49-8
<0.32
ug/L
1.0
0.32
1
10/09/23 11:31
106-43-4
<0.34
ug/L
2.0
0.34
1
10/09/23 11:31
96-12-8
<0.36
ug/L
1.0
0.36
1
10/09/23 11:31
124-48-1
<0.27
ug/L
1.0
0.27
1
10/09/23 11:31
106-93-4
<0.39
ug/L
1.0
0.39
1
10/09/23 11:31
74-95-3
<0.34
ug/L
1.0
0.34
1
10/09/23 11:31
95-50-1
<0.34
ug/L
1.0
0.34
1
10/09/23 11:31
541-73-1
<0.33
ug/L
1.0
0.33
1
10/09/23 11:31
106-46-7
<0.35
ug/L
1.0
0.35
1
10/09/23 11:31
75-71-8
<0.37
ug/L
1.0
0.37
1
10/09/23 11:31
75-34-3
<0.32
ug/L
1.0
0.32
1
10/09/23 11:31
107-06-2
<0.35
ug/L
1.0
0.35
1
10/09/23 11:31
75-35-4
<0.38
ug/L
1.0
0.38
1
10/09/23 11:31
156-59-2
<0.40
ug/L
1.0
0.40
1
10/09/23 11:31
156-60-5
<0.36
ug/L
1.0
0.36
1
10/09/23 11:31
78-87-5
<0.28
ug/L
1.0
0.28
1
10/09/23 11:31
142-28-9
<0.39
ug/L
1.0
0.39
1
10/09/23 11:31
594-20-7
<0.43
ug/L
1.0
0.43
1
10/09/23 11:31
563-58-6
<0.36
ug/L
1.0
0.36
1
10/09/23 11:31
10061-01-5
<0.36
ug/L
1.0
0.36
1
10/09/23 11:31
10061-02-6
<0.31
ug/L
1.0
0.31
1
10/09/23 11:31
108-20-3
<0.30
ug/L
1.0
0.30
1
10/09/23 11:31
100-41-4
<1.5
ug/L
2.0
1.5
1
10/09/23 11:31
87-68-3
<0.48
ug/L
5.0
0.48
1
10/09/23 11:31
591-78-6
<0.41
ug/L
1.0
0.41
1
10/09/23 11:31
99-87-6
<2.0
ug/L
5.0
2.0
1
10/09/23 11:31
75-09-2
<2.7
ug/L
5.0
2.7
1
10/09/23 11:31
108-10-1
<0.42
ug/L
1.0
0.42
1
10/09/23 11:31
1634-04-4
<0.64
ug/L
1.0
0.64
1
10/09/23 11:31
91-20-3
<0.29
ug/L
1.0
0.29
1
10/09/23 11:31
100-42-5
<0.31
ug/L
1.0
0.31
1
10/09/23 11:31
630-20-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 54 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: TB-20231005
Lab ID:
92691980005
Collected:
10/05/23
00:00
Received: 10/06/23 11:51 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,2,2-Tetrachloroethane
<0.22
ug/L
1.0
0.22
1
10/09/23 11:31
79-34-5
Tetrachloroethene
<0.29
ug/L
1.0
0.29
1
10/09/23 11:31
127-18-4
Toluene
<0.24
ug/L
1.0
0.24
1
10/09/23 11:31
108-88-3
1,2,3-Trichlorobenzene
<0.81
ug/L
1.0
0.81
1
10/09/23 11:31
87-61-6
1,2,4-Trichlorobenzene
<0.64
ug/L
1.0
0.64
1
10/09/23 11:31
120-82-1
1,1,1-Trichloroethane
<0.33
ug/L
1.0
0.33
1
10/09/23 11:31
71-55-6
1,1,2-Trichloroethane
<0.32
ug/L
1.0
0.32
1
10/09/23 11:31
79-00-5
Trichloroethene
<0.38
ug/L
1.0
0.38
1
10/09/23 11:31
79-01-6
Trichlorofluoromethane
<0.30
ug/L
1.0
0.30
1
10/09/23 11:31
75-69-4
1,2,3-Trichloropropane
<0.26
ug/L
1.0
0.26
1
10/09/23 11:31
96-18-4
Vinyl acetate
<1.3
ug/L
2.0
1.3
1
10/09/23 11:31
108-05-4
Vinyl chloride
<0.39
ug/L
1.0
0.39
1
10/09/23 11:31
75-01-4
Xylene (Total)
<0.34
ug/L
1.0
0.34
1
10/09/23 11:31
1330-20-7
m&p-Xylene
<0.71
ug/L
2.0
0.71
1
10/09/23 11:31
179601-23-1
o-Xylene
<0.34
ug/L
1.0
0.34
1
10/09/23 11:31
95-47-6
Surrogates
4-Bromofluorobenzene (S)
96
%
70-130
1
10/09/23 11:31
460-00-4
1,2-Dichloroethane-d4 (S)
103
%
70-130
1
10/09/23 11:31
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
10/09/23 11:31
2037-26-5
Date: 02/23/2024 01:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 55 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: MW-04-20231009 Lab ID: 92692397001 Collected: 10/09/23 15:36 Received: 10/10/23 11:08 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Ethane
<5.9
ug/L
10.0
5.9
1
10/12/2315:40
74-84-0
Ethene
<5.7
ug/L
10.0
5.7
1
10/12/2315:40
74-85-1
Methane
18.9
ug/L
10.0
5.3
1
10/12/2315:40
74-82-8
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Antimony
<0.20
ug/L
1.0
0.20
1
10/15/23 13:35
10/17/23 05:50
7440-36-0
Arsenic
<0.087
ug/L
1.0
0.087
1
10/15/23 13:35
10/17/23 05:50
7440-38-2
Barium
58.3
ug/L
1.0
0.21
1
10/15/23 13:35
10/17/23 05:50
7440-39-3
Beryllium
<0.050
ug/L
0.10
0.050
1
10/15/23 13:35
10/17/23 05:50
7440-41-7
Cadmium
0.25
ug/L
0.20
0.060
1
10/15/23 13:35
10/17/23 05:50
7440-43-9
Chromium
0.74J
ug/L
1.0
0.50
1
10/15/23 13:35
10/17/23 05:50
7440-47-3
Cobalt
2.4
ug/L
1.0
0.050
1
10/15/23 13:35
10/17/23 05:50
7440-48-4
Copper
<1.1
ug/L
2.0
1.1
1
10/15/23 13:35
10/17/23 05:50
7440-50-8
Iron
<20.9
ug/L
50.0
20.9
1
10/18/2312:10
10/18/2319:26
7439-89-6
Lead
<0.077
ug/L
1.0
0.077
1
10/15/23 13:35
10/17/23 05:50
7439-92-1
Nickel
1.4
ug/L
1.0
0.42
1
10/15/23 13:35
10/17/23 05:50
7440-02-0
Selenium
0.30J
ug/L
2.0
0.072
1
10/15/23 13:35
10/17/23 05:50
7782-49-2
Silver
<0.070
ug/L
0.40
0.070
1
10/15/23 13:35
10/17/23 05:50
7440-22-4
Thallium
0.076J
ug/L
0.20
0.050
1
10/15/23 13:35
10/17/23 05:50
7440-28-0
Tin
<0.43
ug/L
1.0
0.43
1
10/15/23 13:35
10/17/23 05:50
7440-31-5
Vanadium
<0.25
ug/L
1.0
0.25
1
10/15/23 13:35
10/17/23 05:50
7440-62-2
7470 Mercury
Mercury
8270E APP9 RV
Acenaphthene
Acenaphthylene
Acetophenone
2-Acetylaminofluorene
4-Aminobiphenyl
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Benzyl alcohol
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methyl phenol
4-Chloroaniline
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
0.28 ug/L 0.20 0.12 1 10/12/2312:00 10/13/2312:43 7439-97-6
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
<2.0
ug/L
10.0
2.0
1
10/12/2315:31
10/13/2319:39
83-32-9
<2.0
ug/L
10.0
2.0
1
10/12/2315:31
10/13/2319:39
208-96-8
<1.5
ug/L
10.0
1.5
1
10/12/2315:31
10/13/2319:39
98-86-2
<4.1
ug/L
10.0
4.1
1
10/12/2315:31
10/13/2319:39
53-96-3
<4.7
ug/L
10.0
4.7
1
10/12/2315:31
10/13/2319:39
92-67-1
<2.3
ug/L
10.0
2.3
1
10/12/2315:31
10/13/2319:39
120-12-7
<2.7
ug/L
10.0
2.7
1
10/12/2315:31
10/13/2319:39
56-55-3
<2.8
ug/L
10.0
2.8
1
10/12/2315:31
10/13/2319:39
50-32-8
<2.6
ug/L
10.0
2.6
1
10/12/2315:31
10/13/2319:39
205-99-2
<2.8
ug/L
10.0
2.8
1
10/12/2315:31
10/13/2319:39
191-24-2
<2.7
ug/L
10.0
2.7
1
10/12/2315:31
10/13/2319:39
207-08-9
<2.9
ug/L
20.0
2.9
1
10/12/2315:31
10/13/2319:39
100-51-6
<1.8
ug/L
10.0
1.8
1
10/12/2315:31
10/13/2319:39
101-55-3
<3.1
ug/L
10.0
3.1
1
10/12/2315:31
10/13/2319:39
85-68-7
<3.3
ug/L
10.0
3.3
1
10/12/2315:31
10/13/2319:39
59-50-7
<3.6
ug/L
20.0
3.6
1
10/12/2315:31
10/13/2319:39
106-47-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 56 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-04-20231009 Lab ID: 92692397001 Collected: 10/09/23 15:36 Received: 10/10/23 11:08 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Chlorobenzilate
<3.8
ug/L
10.0
3.8
1
10/12/23 15:31
10/13/23 19:39
510-15-6
bis(2-Chloroethoxy)methane
<1.8
ug/L
10.0
1.8
1
10/12/23 15:31
10/13/23 19:39
111-91-1
bis(2-Chloroethyl) ether
<1.9
ug/L
10.0
1.9
1
10/12/23 15:31
10/13/23 19:39
111-44-4
2-Chloronaphthalene
<1.7
ug/L
10.0
1.7
1
10/12/23 15:31
10/13/23 19:39
91-58-7
2-Chlorophenol
<1.2
ug/L
10.0
1.2
1
10/12/23 15:31
10/13/23 19:39
95-57-8
4-Chlorophenylphenyl ether
<2.0
ug/L
10.0
2.0
1
10/12/23 15:31
10/13/23 19:39
7005-72-3
Chrysene
<2.8
ug/L
10.0
2.8
1
10/12/23 15:31
10/13/23 19:39
218-01-9
Diallate
<3.4
ug/L
10.0
3.4
1
10/12/23 15:31
10/13/23 19:39
2303-16-4
Dibenz(a,h)anthracene
<3.0
ug/L
10.0
3.0
1
10/12/23 15:31
10/13/23 19:39
53-70-3
Dibenzofuran
<2.1
ug/L
10.0
2.1
1
10/12/23 15:31
10/13/23 19:39
132-64-9
3,3'-Dichlorobenzidine
<8.1
ug/L
20.0
8.1
1
10/12/23 15:31
10/13/23 19:39
91-94-1
2,4-Dichlorophenol
<1.4
ug/L
10.0
1.4
1
10/12/23 15:31
10/13/23 19:39
120-83-2
2,6-Dichlorophenol
<4.2
ug/L
10.0
4.2
1
10/12/23 15:31
10/13/23 19:39
87-65-0
Diethylphthalate
<2.0
ug/L
10.0
2.0
1
10/12/23 15:31
10/13/23 19:39
84-66-2
Dimethoate
<3.7
ug/L
10.0
3.7
1
10/12/23 15:31
10/13/23 19:39
60-51-5
P-Dimethylaminoazobenzene
<2.4
ug/L
5.0
2.4
1
10/12/23 15:31
10/13/23 19:39
60-11-7
7,12-Dimethylbenz(a)anthracene
<3.0
ug/L
10.0
3.0
1
10/12/23 15:31
10/13/23 19:39
57-97-6
3,3'-Dimethylbenzidine
<31.1
ug/L
50.0
31.1
1
10/12/23 15:31
10/13/23 19:39
119-93-7
2,4-Dimethylphenol
<1.7
ug/L
10.0
1.7
1
10/12/23 15:31
10/13/23 19:39
105-67-9
Dimethylphthalate
<2.1
ug/L
10.0
2.1
1
10/12/23 15:31
10/13/23 19:39
131-11-3
Di-n-butylphthalate
<2.2
ug/L
10.0
2.2
1
10/12/23 15:31
10/13/23 19:39
84-74-2
4,6-Dinitro-2-methyl phenol
<7.8
ug/L
20.0
7.8
1
10/12/23 15:31
10/13/23 19:39
534-52-1
1,3-Dinitrobenzene
<3.8
ug/L
10.0
3.8
1
10/12/23 15:31
10/13/23 19:39
99-65-0
2,4-Dinitrophenol
<26.0
ug/L
50.0
26.0
1
10/12/23 15:31
10/13/23 19:39
51-28-5
2,4-Dinitrotoluene
<1.6
ug/L
10.0
1.6
1
10/12/23 15:31
10/13/23 19:39
121-14-2
2,6-Dinitrotoluene
<1.7
ug/L
10.0
1.7
1
10/12/23 15:31
10/13/23 19:39
606-20-2
Di-n-octylphthalate
<3.9
ug/L
10.0
3.9
1
10/12/23 15:31
10/13/23 19:39
117-84-0
Diphenylamine
<3.0
ug/L
10.0
3.0
1
10/12/23 15:31
10/13/23 19:39
122-39-4
Disulfoton
<4.6
ug/L
10.0
4.6
1
10/12/23 15:31
10/13/23 19:39
298-04-4
bis(2- Ethyl hexyl)phthalate
<3.7
ug/L
6.0
3.7
1
10/12/23 15:31
10/13/23 19:39
117-81-7
Ethyl methanesulfonate
<3.0
ug/L
20.0
3.0
1
10/12/23 15:31
10/13/23 19:39
62-50-0
Famphur
<6.1
ug/L
10.0
6.1
1
10/12/23 15:31
10/13/23 19:39
52-85-7
Fluoranthene
<2.2
ug/L
10.0
2.2
1
10/12/23 15:31
10/13/23 19:39
206-44-0
Fluorene
<2.1
ug/L
10.0
2.1
1
10/12/23 15:31
10/13/23 19:39
86-73-7
Hexachlorobenzene
<2.2
ug/L
10.0
2.2
1
10/12/23 15:31
10/13/23 19:39
118-74-1
Hexachlorocyclopentadiene
<1.6
ug/L
10.0
1.6
1
10/12/23 15:31
10/13/23 19:39
77-47-4
Hexachloroethane
<1.4
ug/L
10.0
1.4
1
10/12/23 15:31
10/13/23 19:39
67-72-1
Hexachloropropene
<2.7
ug/L
10.0
2.7
1
10/12/23 15:31
10/13/23 19:39
1888-71-7
Indeno(1,2,3-cd)pyrene
<2.9
ug/L
10.0
2.9
1
10/12/23 15:31
10/13/23 19:39
193-39-5
Isodrin
<2.8
ug/L
10.0
2.8
1
10/12/23 15:31
10/13/23 19:39
465-73-6
Isophorone
<1.7
ug/L
10.0
1.7
1
10/12/23 15:31
10/13/23 19:39
78-59-1
Isosafrole
<2.5
ug/L
10.0
2.5
1
10/12/23 15:31
10/13/23 19:39
120-58-1
Kepone
<14.1
ug/L
20.0
14.1
1
10/12/23 15:31
10/13/23 19:39
143-50-0
Methapyrilene
<17.0
ug/L
50.0
17.0
1
10/12/23 15:31
10/13/23 19:39
91-80-5
3-Methylcholanthrene
<3.7
ug/L
10.0
3.7
1
10/12/23 15:31
10/13/23 19:39
56-49-5
REPORT OF LABORATORY ANALYSIS
IL
IH
v1
L1,v1
L2
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 57 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: MW-04-20231009
Lab ID:
92692397001
Collected:
10/09/23
15:36
Received: 10/10/23
11:08 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared
Analyzed
CAS No. Qual
8270E APP9 RV
Analytical
Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services - Charlotte
Methyl methanesulfonate
<3.1
ug/L
5.0
3.1
1
10/12/23 15:31
10/13/23 19:39
66-27-3
2-Methylnaphthalene
<1.9
ug/L
10.0
1.9
1
10/12/23 15:31
10/13/23 19:39
91-57-6
Methyl parathion
<3.7
ug/L
10.0
3.7
1
10/12/23 15:31
10/13/23 19:39
298-00-0
2-Methylphenol(o-Cresol)
<1.9
ug/L
10.0
1.9
1
10/12/23 15:31
10/13/23 19:39
95-48-7
3&4-Methyl phenol (m&p Cresol)
<1.2
ug/L
10.0
1.2
1
10/12/23 15:31
10/13/23 19:39
15831-10-4
1-Naphthalenamine
<6.0
ug/L
10.0
6.0
1
10/12/23 15:31
10/13/23 19:39
134-32-7
2-Naphthalenamine
<5.4
ug/L
10.0
5.4
1
10/12/23 15:31
10/13/23 19:39
91-59-8
1,4-Naphthoquinone
<4.4
ug/L
5.0
4.4
1
10/12/23 15:31
10/13/23 19:39
130-15-4
2-Nitroaniline
<3.0
ug/L
20.0
3.0
1
10/12/23 15:31
10/13/23 19:39
88-74-4
3-Nitroaniline
<3.8
ug/L
20.0
3.8
1
10/12/23 15:31
10/13/23 19:39
99-09-2
4-Nitroaniline
<5.1
ug/L
20.0
5.1
1
10/12/23 15:31
10/13/23 19:39
100-01-6
Nitrobenzene
<1.9
ug/L
10.0
1.9
1
10/12/23 15:31
10/13/23 19:39
98-95-3
2-Nitrophenol
<1.4
ug/L
10.0
1.4
1
10/12/23 15:31
10/13/23 19:39
88-75-5
4-Nitrophenol
<6.6
ug/L
50.0
6.6
1
10/12/23 15:31
10/13/23 19:39
100-02-7
5-Nitro-o-toluidine
<3.8
ug/L
10.0
3.8
1
10/12/23 15:31
10/13/23 19:39
99-55-8
N-Nitrosodiethylamine
<2.3
ug/L
10.0
2.3
1
10/12/23 15:31
10/13/23 19:39
55-18-5
N-Nitrosodimethylamine
<1.9
ug/L
10.0
1.9
1
10/12/23 15:31
10/13/23 19:39
62-75-9
N-Nitroso-di-n-butylamine
<2.0
ug/L
10.0
2.0
1
10/12/23 15:31
10/13/23 19:39
924-16-3
N-Nitroso-di-n-propylamine
<1.3
ug/L
10.0
1.3
1
10/12/23 15:31
10/13/23 19:39
621-64-7
N-Nitrosodiphenylamine
<3.0
ug/L
10.0
3.0
1
10/12/23 15:31
10/13/23 19:39
86-30-6
N-Nitrosomethylethylamine
<7.5
ug/L
10.0
7.5
1
10/12/23 15:31
10/13/23 19:39
10595-95-6
N-Nitrosopiperidine
<2.5
ug/L
10.0
2.5
1
10/12/23 15:31
10/13/23 19:39
100-75-4
N-Nitrosopyrrolidine
<3.1
ug/L
10.0
3.1
1
10/12/23 15:31
10/13/23 19:39
930-55-2
O,O,O-Triethylphosphorothioate
<2.6
ug/L
10.0
2.6
1
10/12/23 15:31
10/13/23 19:39
126-68-1 v1
2,2'-Oxybis(1-chloropropane)
<1.2
ug/L
10.0
1.2
1
10/12/23 15:31
10/13/23 19:39
108-60-1
Parathion (Ethyl parathion)
<3.9
ug/L
10.0
3.9
1
10/12/23 15:31
10/13/23 19:39
56-38-2
Pentachlorobenzene
<3.4
ug/L
10.0
3.4
1
10/12/23 15:31
10/13/23 19:39
608-93-5
Pentachloronitrobenzene
<3.3
ug/L
10.0
3.3
1
10/12/23 15:31
10/13/23 19:39
82-68-8 v1
Pentachlorophenol
<3.8
ug/L
20.0
3.8
1
10/12/23 15:31
10/13/23 19:39
87-86-5
Phenacetin
<3.6
ug/L
10.0
3.6
1
10/12/23 15:31
10/13/23 19:39
62-44-2
Phenanthrene
<2.0
ug/L
10.0
2.0
1
10/12/23 15:31
10/13/23 19:39
85-01-8
Phenol
<1.4
ug/L
10.0
1.4
1
10/12/23 15:31
10/13/23 19:39
108-95-2
p-Phenylenediamine
<10.0
ug/L
10.0
10.0
1
10/12/23 15:31
10/13/23 19:39
106-50-3
Phorate
<3.6
ug/L
10.0
3.6
1
10/12/23 15:31
10/13/23 19:39
298-02-2
Pronamide
<3.1
ug/L
10.0
3.1
1
10/12/23 15:31
10/13/23 19:39
23950-58-5
Pyrene
<2.2
ug/L
10.0
2.2
1
10/12/23 15:31
10/13/23 19:39
129-00-0
Safrole
<2.3
ug/L
10.0
2.3
1
10/12/23 15:31
10/13/23 19:39
94-59-7
1,2,4,5-Tetrachlorobenzene
<4.5
ug/L
10.0
4.5
1
10/12/23 15:31
10/13/23 19:39
95-94-3
2,3,4,6-Tetrachlorophenol
<1.5
ug/L
10.0
1.5
1
10/12/23 15:31
10/13/23 19:39
58-90-2
Thionazin
<2.9
ug/L
10.0
2.9
1
10/12/23 15:31
10/13/23 19:39
297-97-2
O-Toluidine
<2.6
ug/L
10.0
2.6
1
10/12/23 15:31
10/13/23 19:39
95-53-4
2,4,5-Trichlorophenol
<1.4
ug/L
10.0
1.4
1
10/12/23 15:31
10/13/23 19:39
95-95-4
2,4,6-Trichlorophenol
<1.6
ug/L
10.0
1.6
1
10/12/23 15:31
10/13/23 19:39
88-06-2
1,3,5-Trinitrobenzene
<5.5
ug/L
10.0
5.5
1
10/12/23 15:31
10/13/23 19:39
99-35-4 v2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 58 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-04-20231009 Lab ID: 92692397001 Collected: 10/09/23 15:36 Received: 10/10/23 11:08 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260D MSV Low Level Landfill
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
18
%
10-133
1
10/12/2315:31
10/13/2319:39
4165-60-0
17
%
10-130
1
10/12/2315:31
10/13/2319:39
321-60-8
51
%
10-193
1
10/12/2315:31
10/13/2319:39
1718-51-0
10
%
10-130
1
10/12/2315:31
10/13/2319:39
13127-88-3
12
%
10-130
1
10/12/2315:31
10/13/2319:39
367-12-4
35
%
10-166
1
10/12/2315:31
10/13/2319:39
118-79-6
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
<5.1
ug/L
25.0
5.1
1
10/11/2317:06
67-64-1
<0.34
ug/L
1.0
0.34
1
10/11/2317:06
71-43-2
<0.29
ug/L
1.0
0.29
1
10/11/2317:06
108-86-1
<0.47
ug/L
1.0
0.47
1
10/11/2317:06
74-97-5
<0.31
ug/L
1.0
0.31
1
10/11/2317:06
75-27-4
<0.34
ug/L
1.0
0.34
1
10/11/2317:06
75-25-2
<1.7
ug/L
2.0
1.7
1
10/11/2317:06
74-83-9
<4.0
ug/L
5.0
4.0
1
10/11/2317:06
78-93-3
<0.33
ug/L
1.0
0.33
1
10/11/2317:06
56-23-5
1.4
ug/L
1.0
0.28
1
10/11/2317:06
108-90-7
<0.65
ug/L
1.0
0.65
1
10/11/2317:06
75-00-3
<0.43
ug/L
1.0
0.43
1
10/11/2317:06
67-66-3
<0.54
ug/L
1.0
0.54
1
10/11/2317:06
74-87-3
<0.32
ug/L
1.0
0.32
1
10/11/2317:06
95-49-8
<0.32
ug/L
1.0
0.32
1
10/11/2317:06
106-43-4
<0.34
ug/L
2.0
0.34
1
10/11/2317:06
96-12-8
<0.36
ug/L
1.0
0.36
1
10/11/2317:06
124-48-1
<0.27
ug/L
1.0
0.27
1
10/11/2317:06
106-93-4
<0.39
ug/L
1.0
0.39
1
10/11/2317:06
74-95-3
<0.34
ug/L
1.0
0.34
1
10/11/2317:06
95-50-1
<0.34
ug/L
1.0
0.34
1
10/11/2317:06
541-73-1
<0.33
ug/L
1.0
0.33
1
10/11/2317:06
106-46-7
<0.35
ug/L
1.0
0.35
1
10/11/2317:06
75-71-8
<0.37
ug/L
1.0
0.37
1
10/11/2317:06
75-34-3
<0.32
ug/L
1.0
0.32
1
10/11/2317:06
107-06-2
<0.35
ug/L
1.0
0.35
1
10/11/2317:06
75-35-4
0.76J
ug/L
1.0
0.38
1
10/11/2317:06
156-59-2
<0.40
ug/L
1.0
0.40
1
10/11/2317:06
156-60-5
<0.36
ug/L
1.0
0.36
1
10/11/2317:06
78-87-5
<0.28
ug/L
1.0
0.28
1
10/11/2317:06
142-28-9
<0.39
ug/L
1.0
0.39
1
10/11/2317:06
594-20-7
<0.43
ug/L
1.0
0.43
1
10/11/2317:06
563-58-6
<0.36
ug/L
1.0
0.36
1
10/11/2317:06
10061-01-5
<0.36
ug/L
1.0
0.36
1
10/11/2317:06
10061-02-6
<0.31
ug/L
1.0
0.31
1
10/11/2317:06
108-20-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 59 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-04-20231009 Lab ID: 92692397001 Collected: 10/09/23 15:36 Received: 10/10/23 11:08 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Iron, Ferric (Calculation)
Iron, Ferric
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
<0.30
ug/L
1.0
<1.5
ug/L
2.0
<0.48
ug/L
5.0
<0.41
ug/L
1.0
<2.0
ug/L
5.0
<2.7
ug/L
5.0
<0.42
ug/L
1.0
<0.64
ug/L
1.0
<0.29
ug/L
1.0
<0.31
ug/L
1.0
<0.22
ug/L
1.0
<0.29
ug/L
1.0
<0.24
ug/L
1.0
<0.81
ug/L
1.0
<0.64
ug/L
1.0
<0.33
ug/L
1.0
<0.32
ug/L
1.0
<0.38
ug/L
1.0
<0.30
ug/L
1.0
<0.26
ug/L
1.0
<1.3
ug/L
2.0
<0.39
ug/L
1.0
<0.34
ug/L
1.0
<0.71
ug/L
2.0
<0.34
ug/L
1.0
99
%
70-130
99
%
70-130
99
%
70-130
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
13.4
ug/L
2.0
89 % 67-130
91 % 70-130
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
150 mg/L 5.0
Analytical Method: SM 3500-Fe D#4
Pace Analytical Services -Asheville
<0.25 mg/L 0.50
0.30
1
10/11 /23 17:06
100-41-4
1.5
1
10/11/2317:06
87-68-3
0.48
1
10/11 /23 17:06
591-78-6
0.41
1
10/11/2317:06
99-87-6
2.0
1
10/11/2317:06
75-09-2
2.7
1
10/11 /23 17:06
108-10-1
0.42
1
10/11 /23 17:06
1634-04-4
0.64
1
10/11 /23 17:06
91-20-3
0.29
1
10/11 /23 17:06
100-42-5
0.31
1
10/11/2317:06
630-20-6
0.22
1
10/11/2317:06
79-34-5
0.29
1
10/11 /23 17:06
127-18-4
0.24
1
10/11 /23 17:06
108-88-3
0.81
1
10/11 /23 17:06
87-61-6
0.64
1
10/11 /23 17:06
120-82-1
0.33
1
10/11 /23 17:06
71-55-6
0.32
1
10/11/2317:06
79-00-5
0.38
1
10/11 /23 17:06
79-01-6
0.30
1
10/11/2317:06
75-69-4
0.26
1
10/11/2317:06
96-18-4
1.3
1
10/11 /23 17:06
108-05-4
0.39
1
10/11 /23 17:06
75-01-4
0.34
1
10/11 /23 17:06
1330-20-7
0.71
1
10/11 /23 17:06
179601-23-1
0.34
1
10/11/2317:06
95-47-6
1 10/11/2317:06 460-00-4
1 10/11 /23 17:06 17060-07-0
1 10/11/2317:06 2037-26-5
0.86 1 10/12/23 18:53 123-91-1
1 10/12/23 18:53 17060-07-0
1 10/12/23 18:53 2037-26-5
5.0 1 10/18/23 17:42
0.25 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
11/28/23 08:24 20074-52-6 N2
Page 60 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: MW-04-20231009
Lab ID: 92692397001 Collected:
10/09/23
15:36
Received: 10/10/23
11:08 Matrix: Water
Parameters
Results Units PQL
MDL
DF
Prepared
Analyzed
CAS No. Qual
Iron, Ferrous
Analytical Method: SM 3500-Fe B-2011
Pace Analytical Services -Asheville
Iron, Ferrous
0.077J mg/L 0.50
0.040
1
10/17/23 11:36
H3,N2
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
<0.022 mg/L 0.10
0.022
1
10/11/23 01:27
18496-25-8
5210B BOD, 5 day
Analytical Method: SM 521OB-2011
Pace Analytical Services -Asheville
BOD, 5 day
<2.0 mg/L 2.0
2.0
1
10/11/23 05:28
10/16/23 09:48
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
17.7.11 mg/L 25.0
12.5
1
10/19/23 03:19
10/20/23 00:00
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
2.7 mg/L 1.0
0.50
1
10/16/23 22:37
7440-44-0
9056 IC Anions 48hr
Analytical Method: EPA 9056A
Pace Analytical Services -Asheville
Chloride
78.4 mg/L 1.0
0.60
1
10/11/23 00:34
16887-00-6
Nitrate as N
1.5 mg/L 0.10
0.060
1
10/11/23 00:34
14797-55-8
Sulfate
79.8 mg/L 1.0
0.50
1
10/11/23 00:34
14808-79-8
Date: 02/23/2024 01:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 61 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: MW-05R-20231009
Lab ID:
92692397002
Collected:
10/09/23
17:38
Received: 10/10/23 11:08 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared
Analyzed
CAS No. Qual
RSK 175 Headspace
Analytical
Method: RSK 175
Modified
Pace Analytical
Services - Charlotte
Ethane
<5.9
ug/L
10.0
5.9
1
10/12/2315:56
74-84-0 M1
Ethene
<5.7
ug/L
10.0
5.7
1
10/12/2315:56
74-85-1 M1
Methane
1870
ug/L
10.0
5.3
1
10/12/2315:56
74-82-8 M1
6020 MET ICPMS
Analytical
Method: EPA 6020E Preparation Method: EPA 3010A
Pace Analytical
Services
-Asheville
Antimony
<0.20
ug/L
1.0
0.20
1
10/15/23 13:35
10/17/23 05:55
7440-36-0
Arsenic
0.38J
ug/L
1.0
0.087
1
10/15/23 13:35
10/17/23 05:55
7440-38-2
Barium
232
ug/L
3.0
0.64
3
10/15/23 13:35
10/17/2315:02
7440-39-3
Beryllium
0.065J
ug/L
0.10
0.050
1
10/15/23 13:35
10/17/23 05:55
7440-41-7
Cadmium
0.094J
ug/L
0.20
0.060
1
10/15/23 13:35
10/17/23 05:55
7440-43-9
Chromium
1.4
ug/L
1.0
0.50
1
10/15/23 13:35
10/17/23 05:55
7440-47-3
Cobalt
12.4
ug/L
1.0
0.050
1
10/15/23 13:35
10/17/23 05:55
7440-48-4
Copper
15.9
ug/L
2.0
1.1
1
10/15/23 13:35
10/17/23 05:55
7440-50-8
Iron
23500
ug/L
500
209
10
11/21/23 01:07
11/21/23 14:54
7439-89-6
Lead
0.42J
ug/L
1.0
0.077
1
10/15/23 13:35
10/17/23 05:55
7439-92-1
Nickel
2.7
ug/L
1.0
0.42
1
10/15/23 13:35
10/17/23 05:55
7440-02-0
Selenium
0.093J
ug/L
2.0
0.072
1
10/15/23 13:35
10/17/23 05:55
7782-49-2
Silver
<0.070
ug/L
0.40
0.070
1
10/15/23 13:35
10/17/23 05:55
7440-22-4
Thallium
<0.050
ug/L
0.20
0.050
1
10/15/23 13:35
10/17/23 05:55
7440-28-0
Tin
1.1
ug/L
1.0
0.43
1
10/15/23 13:35
10/17/23 05:55
7440-31-5
Vanadium
1.2
ug/L
1.0
0.25
1
10/15/23 13:35
10/17/23 05:55
7440-62-2
7470 Mercury
Mercury
8270E APP9 RV
Acenaphthene
Acenaphthylene
Acetophenone
2-Acetylaminofluorene
4-Aminobiphenyl
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Benzyl alcohol
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methyl phenol
4-Chloroaniline
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
<0.12 ug/L 0.20 0.12 1 10/12/2312:00 10/13/2312:45 7439-97-6
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
<1.8
ug/L
9.1
1.8
1
10/16/2316:27
10/17/2314:01
83-32-9
<1.8
ug/L
9.1
1.8
1
10/16/2316:27
10/17/2314:01
208-96-8
<1.4
ug/L
9.1
1.4
1
10/16/2316:27
10/17/2314:01
98-86-2
<3.7
ug/L
9.1
3.7
1
10/16/2316:27
10/17/2314:01
53-96-3
<4.3
ug/L
9.1
4.3
1
10/16/2316:27
10/17/2314:01
92-67-1
<2.1
ug/L
9.1
2.1
1
10/16/2316:27
10/17/2314:01
120-12-7
<2.4
ug/L
9.1
2.4
1
10/16/2316:27
10/17/2314:01
56-55-3
<2.5
ug/L
9.1
2.5
1
10/16/2316:27
10/17/2314:01
50-32-8
<2.4
ug/L
9.1
2.4
1
10/16/2316:27
10/17/2314:01
205-99-2
<2.6
ug/L
9.1
2.6
1
10/16/2316:27
10/17/2314:01
191-24-2
<2.5
ug/L
9.1
2.5
1
10/16/2316:27
10/17/2314:01
207-08-9
<2.6
ug/L
18.2
2.6
1
10/16/2316:27
10/17/2314:01
100-51-6
<1.6
ug/L
9.1
1.6
1
10/16/2316:27
10/17/2314:01
101-55-3
<2.9
ug/L
9.1
2.9
1
10/16/2316:27
10/17/2314:01
85-68-7
<3.0
ug/L
9.1
3.0
1
10/16/2316:27
10/17/2314:01
59-50-7
<3.3
ug/L
18.2
3.3
1
10/16/2316:27
10/17/2314:01
106-47-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 62 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: MW-05R-20231009
Lab ID:
92692397002
Collected:
10/09/23
17:38
Received: 10/10/23 11:08 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared
Analyzed
CAS No.
Qual
8270E APP9 RV
Analytical
Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services - Charlotte
Chlorobenzilate
<3.4
ug/L
9.1
3.4
1
10/16/23 16:27
10/17/23 14:01
510-15-6
bis(2-Chloroethoxy)methane
<1.7
ug/L
9.1
1.7
1
10/16/23 16:27
10/17/23 14:01
111-91-1
bis(2-Chloroethyl) ether
<1.7
ug/L
9.1
1.7
1
10/16/23 16:27
10/17/23 14:01
111-44-4
2-Chloronaphthalene
<1.6
ug/L
9.1
1.6
1
10/16/23 16:27
10/17/23 14:01
91-58-7
2-Chlorophenol
<1.1
ug/L
9.1
1.1
1
10/16/23 16:27
10/17/23 14:01
95-57-8
4-Chlorophenylphenyl ether
<1.8
ug/L
9.1
1.8
1
10/16/23 16:27
10/17/23 14:01
7005-72-3
Chrysene
<2.5
ug/L
9.1
2.5
1
10/16/23 16:27
10/17/23 14:01
218-01-9
Diallate
<3.1
ug/L
9.1
3.1
1
10/16/23 16:27
10/17/23 14:01
2303-16-4
Dibenz(a,h)anthracene
<2.7
ug/L
9.1
2.7
1
10/16/23 16:27
10/17/23 14:01
53-70-3
Dibenzofuran
<1.9
ug/L
9.1
1.9
1
10/16/23 16:27
10/17/23 14:01
132-64-9
3,3'-Dichlorobenzidine
<7.4
ug/L
18.2
7.4
1
10/16/23 16:27
10/17/23 14:01
91-94-1
2,4-Dichlorophenol
<1.3
ug/L
9.1
1.3
1
10/16/23 16:27
10/17/23 14:01
120-83-2
2,6-Dichlorophenol
<3.8
ug/L
9.1
3.8
1
10/16/23 16:27
10/17/23 14:01
87-65-0
Diethylphthalate
<1.9
ug/L
9.1
1.9
1
10/16/23 16:27
10/17/23 14:01
84-66-2
Dimethoate
<3.3
ug/L
9.1
3.3
1
10/16/23 16:27
10/17/23 14:01
60-51-5
P-Dimethylaminoazobenzene
<2.2
ug/L
4.5
2.2
1
10/16/23 16:27
10/17/23 14:01
60-11-7
IL
7,12-Dimethylbenz(a)anthracene
<2.7
ug/L
9.1
2.7
1
10/16/23 16:27
10/17/23 14:01
57-97-6
3,3'-Dimethylbenzidine
<28.3
ug/L
45.5
28.3
1
10/16/23 16:27
10/17/23 14:01
119-93-7
IH,L2,
v1
2,4-Dimethylphenol
<1.5
ug/L
9.1
1.5
1
10/16/23 16:27
10/17/23 14:01
105-67-9
Dimethylphthalate
<1.9
ug/L
9.1
1.9
1
10/16/23 16:27
10/17/23 14:01
131-11-3
Di-n-butylphthalate
<2.0
ug/L
9.1
2.0
1
10/16/23 16:27
10/17/23 14:01
84-74-2
4,6-Dinitro-2-methyl phenol
<7.1
ug/L
18.2
7.1
1
10/16/23 16:27
10/17/23 14:01
534-52-1
1,3-Dinitrobenzene
<3.4
ug/L
9.1
3.4
1
10/16/23 16:27
10/17/23 14:01
99-65-0
2,4-Dinitrophenol
<23.6
ug/L
45.5
23.6
1
10/16/23 16:27
10/17/23 14:01
51-28-5
2,4-Dinitrotoluene
<1.5
ug/L
9.1
1.5
1
10/16/23 16:27
10/17/23 14:01
121-14-2
2,6-Dinitrotoluene
<1.6
ug/L
9.1
1.6
1
10/16/23 16:27
10/17/23 14:01
606-20-2
Di-n-octylphthalate
<3.6
ug/L
9.1
3.6
1
10/16/23 16:27
10/17/23 14:01
117-84-0
Diphenylamine
<2.7
ug/L
9.1
2.7
1
10/16/23 16:27
10/17/23 14:01
122-39-4
Disulfoton
<4.2
ug/L
9.1
4.2
1
10/16/23 16:27
10/17/23 14:01
298-04-4
bis(2- Ethyl hexyl)phthalate
<3.4
ug/L
5.5
3.4
1
10/16/23 16:27
10/17/23 14:01
117-81-7
Ethyl methanesulfonate
<2.7
ug/L
18.2
2.7
1
10/16/23 16:27
10/17/23 14:01
62-50-0
Famphur
<5.6
ug/L
9.1
5.6
1
10/16/23 16:27
10/17/23 14:01
52-85-7
Fluoranthene
<2.0
ug/L
9.1
2.0
1
10/16/23 16:27
10/17/23 14:01
206-44-0
Fluorene
<1.9
ug/L
9.1
1.9
1
10/16/23 16:27
10/17/23 14:01
86-73-7
Hexachlorobenzene
<2.0
ug/L
9.1
2.0
1
10/16/23 16:27
10/17/23 14:01
118-74-1
Hexachlorocyclopentadiene
<1.4
ug/L
9.1
1.4
1
10/16/23 16:27
10/17/23 14:01
77-47-4
v1
Hexachloroethane
<1.3
ug/L
9.1
1.3
1
10/16/23 16:27
10/17/23 14:01
67-72-1
Hexachloropropene
<2.5
ug/L
9.1
2.5
1
10/16/23 16:27
10/17/23 14:01
1888-71-7
v1
Indeno(1,2,3-cd)pyrene
<2.6
ug/L
9.1
2.6
1
10/16/23 16:27
10/17/23 14:01
193-39-5
Isodrin
<2.5
ug/L
9.1
2.5
1
10/16/23 16:27
10/17/23 14:01
465-73-6
Isophorone
<1.5
ug/L
9.1
1.5
1
10/16/23 16:27
10/17/23 14:01
78-59-1
Isosafrole
<2.3
ug/L
9.1
2.3
1
10/16/23 16:27
10/17/23 14:01
120-58-1
Kepone
<12.8
ug/L
18.2
12.8
1
10/16/23 16:27
10/17/23 14:01
143-50-0
L1,v1
Methapyrilene
<15.5
ug/L
45.5
15.5
1
10/16/23 16:27
10/17/23 14:01
91-80-5
L2,v1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 63 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: MW-05R-20231009
Lab ID:
92692397002
Collected:
10/09/23
17:38
Received: 10/10/23 11:08 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared
Analyzed
CAS No.
Qual
8270E APP9 RV
Analytical
Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services - Charlotte
3-Methylcholanthrene
<3.4
ug/L
9.1
3.4
1
10/16/23 16:27
10/17/23 14:01
56-49-5
Methyl methanesulfonate
<2.8
ug/L
4.5
2.8
1
10/16/23 16:27
10/17/23 14:01
66-27-3
2-Methylnaphthalene
<1.7
ug/L
9.1
1.7
1
10/16/23 16:27
10/17/23 14:01
91-57-6
Methyl parathion
<3.4
ug/L
9.1
3.4
1
10/16/23 16:27
10/17/23 14:01
298-00-0
2-Methylphenol(o-Cresol)
<1.7
ug/L
9.1
1.7
1
10/16/23 16:27
10/17/23 14:01
95-48-7
3&4-Methyl phenol (m&p Cresol)
<1.1
ug/L
9.1
1.1
1
10/16/23 16:27
10/17/23 14:01
15831-10-4
1-Naphthalenamine
<5.5
ug/L
9.1
5.5
1
10/16/23 16:27
10/17/23 14:01
134-32-7
2-Naphthalenamine
<5.0
ug/L
9.1
5.0
1
10/16/23 16:27
10/17/23 14:01
91-59-8
1,4-Naphthoquinone
<4.0
ug/L
4.5
4.0
1
10/16/23 16:27
10/17/23 14:01
130-15-4
2-Nitroaniline
<2.7
ug/L
18.2
2.7
1
10/16/23 16:27
10/17/23 14:01
88-74-4
3-Nitroaniline
<3.4
ug/L
18.2
3.4
1
10/16/23 16:27
10/17/23 14:01
99-09-2
4-Nitroaniline
<4.6
ug/L
18.2
4.6
1
10/16/23 16:27
10/17/23 14:01
100-01-6
Nitrobenzene
<1.7
ug/L
9.1
1.7
1
10/16/23 16:27
10/17/23 14:01
98-95-3
2-Nitrophenol
<1.3
ug/L
9.1
1.3
1
10/16/23 16:27
10/17/23 14:01
88-75-5
v1
4-Nitrophenol
<6.0
ug/L
45.5
6.0
1
10/16/23 16:27
10/17/23 14:01
100-02-7
5-Nitro-o-toluidine
<3.5
ug/L
9.1
3.5
1
10/16/23 16:27
10/17/23 14:01
99-55-8
N-Nitrosodiethylamine
<2.1
ug/L
9.1
2.1
1
10/16/23 16:27
10/17/23 14:01
55-18-5
N-Nitrosodimethylamine
<1.7
ug/L
9.1
1.7
1
10/16/23 16:27
10/17/23 14:01
62-75-9
N-Nitroso-di-n-butylamine
<1.8
ug/L
9.1
1.8
1
10/16/23 16:27
10/17/23 14:01
924-16-3
L1
N-Nitroso-di-n-propylamine
<1.2
ug/L
9.1
1.2
1
10/16/23 16:27
10/17/23 14:01
621-64-7
N-Nitrosodiphenylamine
<2.7
ug/L
9.1
2.7
1
10/16/23 16:27
10/17/23 14:01
86-30-6
N-Nitrosomethylethylamine
<6.8
ug/L
9.1
6.8
1
10/16/23 16:27
10/17/23 14:01
10595-95-6
N-Nitrosopiperidine
<2.3
ug/L
9.1
2.3
1
10/16/23 16:27
10/17/23 14:01
100-75-4
N-Nitrosopyrrolidine
<2.8
ug/L
9.1
2.8
1
10/16/23 16:27
10/17/23 14:01
930-55-2
O,O,O-Triethylphosphorothioate
<2.3
ug/L
9.1
2.3
1
10/16/23 16:27
10/17/23 14:01
126-68-1
L1,v1
2,2'-Oxybis(1-chloropropane)
<1.0
ug/L
9.1
1.0
1
10/16/23 16:27
10/17/23 14:01
108-60-1
Parathion (Ethyl parathion)
<3.5
ug/L
9.1
3.5
1
10/16/23 16:27
10/17/23 14:01
56-38-2
Pentachlorobenzene
<3.1
ug/L
9.1
3.1
1
10/16/23 16:27
10/17/23 14:01
608-93-5
v1
Pentachloronitrobenzene
<3.0
ug/L
9.1
3.0
1
10/16/23 16:27
10/17/23 14:01
82-68-8
v1
Pentachlorophenol
<3.4
ug/L
18.2
3.4
1
10/16/23 16:27
10/17/23 14:01
87-86-5
Phenacetin
<3.3
ug/L
9.1
3.3
1
10/16/23 16:27
10/17/23 14:01
62-44-2
Phenanthrene
<1.8
ug/L
9.1
1.8
1
10/16/23 16:27
10/17/23 14:01
85-01-8
Phenol
<1.2
ug/L
9.1
1.2
1
10/16/23 16:27
10/17/23 14:01
108-95-2
p-Phenylenediamine
<9.1
ug/L
9.1
9.1
1
10/16/23 16:27
10/17/23 14:01
106-50-3
Phorate
<3.2
ug/L
9.1
3.2
1
10/16/23 16:27
10/17/23 14:01
298-02-2
Pronamide
<2.8
ug/L
9.1
2.8
1
10/16/23 16:27
10/17/23 14:01
23950-58-5
Pyrene
<2.0
ug/L
9.1
2.0
1
10/16/23 16:27
10/17/23 14:01
129-00-0
Safrole
<2.1
ug/L
9.1
2.1
1
10/16/23 16:27
10/17/23 14:01
94-59-7
v1
1,2,4,5-Tetrachlorobenzene
<4.1
ug/L
9.1
4.1
1
10/16/23 16:27
10/17/23 14:01
95-94-3
2,3,4,6-Tetrachlorophenol
<1.4
ug/L
9.1
1.4
1
10/16/23 16:27
10/17/23 14:01
58-90-2
Thionazin
<2.6
ug/L
9.1
2.6
1
10/16/23 16:27
10/17/23 14:01
297-97-2
O-Toluidine
<2.4
ug/L
9.1
2.4
1
10/16/23 16:27
10/17/23 14:01
95-53-4
2,4,5-Trichlorophenol
<1.3
ug/L
9.1
1.3
1
10/16/23 16:27
10/17/23 14:01
95-95-4
v1
2,4,6-Trichlorophenol
<1.4
ug/L
9.1
1.4
1
10/16/23 16:27
10/17/23 14:01
88-06-2
1,3,5-Trinitrobenzene
<5.0
ug/L
9.1
5.0
1
10/16/23 16:27
10/17/23 14:01
99-35-4
v2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 64 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-05R-20231009 Lab ID: 92692397002 Collected: 10/09/23 17:38 Received: 10/10/23 11:08 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260D MSV Low Level Landfill
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
103
%
10-133
1
10/16/2316:27
10/17/2314:01
4165-60-0
107
%
10-130
1
10/16/2316:27
10/17/2314:01
321-60-8
115
%
10-193
1
10/16/2316:27
10/17/2314:01
1718-51-0
57
%
10-130
1
10/16/2316:27
10/17/2314:01
13127-88-3
77
%
10-130
1
10/16/2316:27
10/17/2314:01
367-12-4
163
%
10-166
1
10/16/2316:27
10/17/2314:01
118-79-6
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
<5.1
ug/L
25.0
5.1
1
10/11/2317:41
67-64-1
1.1
ug/L
1.0
0.34
1
10/11/2317:41
71-43-2
<0.29
ug/L
1.0
0.29
1
10/11/2317:41
108-86-1
<0.47
ug/L
1.0
0.47
1
10/11/2317:41
74-97-5
<0.31
ug/L
1.0
0.31
1
10/11/2317:41
75-27-4
<0.34
ug/L
1.0
0.34
1
10/11/2317:41
75-25-2
<1.7
ug/L
2.0
1.7
1
10/11/2317:41
74-83-9
<4.0
ug/L
5.0
4.0
1
10/11/2317:41
78-93-3
<0.33
ug/L
1.0
0.33
1
10/11/2317:41
56-23-5
4.9
ug/L
1.0
0.28
1
10/11/2317:41
108-90-7
<0.65
ug/L
1.0
0.65
1
10/11/2317:41
75-00-3
<0.43
ug/L
1.0
0.43
1
10/11/2317:41
67-66-3
<0.54
ug/L
1.0
0.54
1
10/11/2317:41
74-87-3
<0.32
ug/L
1.0
0.32
1
10/11/2317:41
95-49-8
<0.32
ug/L
1.0
0.32
1
10/11/2317:41
106-43-4
<0.34
ug/L
2.0
0.34
1
10/11/2317:41
96-12-8
<0.36
ug/L
1.0
0.36
1
10/11/2317:41
124-48-1
<0.27
ug/L
1.0
0.27
1
10/11/2317:41
106-93-4
<0.39
ug/L
1.0
0.39
1
10/11/2317:41
74-95-3
<0.34
ug/L
1.0
0.34
1
10/11/2317:41
95-50-1
<0.34
ug/L
1.0
0.34
1
10/11/2317:41
541-73-1
5.1
ug/L
1.0
0.33
1
10/11/2317:41
106-46-7
<0.35
ug/L
1.0
0.35
1
10/11/2317:41
75-71-8
<0.37
ug/L
1.0
0.37
1
10/11/2317:41
75-34-3
<0.32
ug/L
1.0
0.32
1
10/11/2317:41
107-06-2
<0.35
ug/L
1.0
0.35
1
10/11/2317:41
75-35-4
2.4
ug/L
1.0
0.38
1
10/11/2317:41
156-59-2
<0.40
ug/L
1.0
0.40
1
10/11/2317:41
156-60-5
<0.36
ug/L
1.0
0.36
1
10/11/2317:41
78-87-5
<0.28
ug/L
1.0
0.28
1
10/11/2317:41
142-28-9
<0.39
ug/L
1.0
0.39
1
10/11/2317:41
594-20-7
<0.43
ug/L
1.0
0.43
1
10/11/2317:41
563-58-6
<0.36
ug/L
1.0
0.36
1
10/11/2317:41
10061-01-5
<0.36
ug/L
1.0
0.36
1
10/11/2317:41
10061-02-6
<0.31
ug/L
1.0
0.31
1
10/11/2317:41
108-20-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 65 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-05R-20231009 Lab ID: 92692397002 Collected: 10/09/23 17:38 Received: 10/10/23 11:08 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Iron, Ferric (Calculation)
Iron, Ferric
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
<0.30
ug/L
1.0
<1.5
ug/L
2.0
<0.48
ug/L
5.0
<0.41
ug/L
1.0
<2.0
ug/L
5.0
<2.7
ug/L
5.0
<0.42
ug/L
1.0
<0.64
ug/L
1.0
<0.29
ug/L
1.0
<0.31
ug/L
1.0
<0.22
ug/L
1.0
<0.29
ug/L
1.0
<0.24
ug/L
1.0
<0.81
ug/L
1.0
<0.64
ug/L
1.0
<0.33
ug/L
1.0
<0.32
ug/L
1.0
<0.38
ug/L
1.0
<0.30
ug/L
1.0
<0.26
ug/L
1.0
<1.3
ug/L
2.0
0.55J
ug/L
1.0
<0.34
ug/L
1.0
<0.71
ug/L
2.0
<0.34
ug/L
1.0
100
%
70-130
99
%
70-130
102
%
70-130
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
7.1
ug/L
2.0
92 % 67-130
92 % 70-130
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
202 mg/L 5.0
Analytical Method: SM 3500-Fe D#4
Pace Analytical Services -Asheville
19.2 mg/L 0.50
0.30
1
10/11 /23 17:41
100-41-4
1.5
1
10/11 /23 17:41
87-68-3
0.48
1
10/11 /23 17:41
591-78-6
0.41
1
10/11 /23 17:41
99-87-6
2.0
1
10/11 /23 17:41
75-09-2
2.7
1
10/11 /23 17:41
108-10-1
0.42
1
10/11 /23 17:41
1634-04-4
0.64
1
10/11 /23 17:41
91-20-3
0.29
1
10/11 /23 17:41
100-42-5
0.31
1
10/11 /23 17:41
630-20-6
0.22
1
10/11 /23 17:41
79-34-5
0.29
1
10/11 /23 17:41
127-18-4
0.24
1
10/11 /23 17:41
108-88-3
0.81
1
10/11 /23 17:41
87-61-6
0.64
1
10/11 /23 17:41
120-82-1
0.33
1
10/11 /23 17:41
71-55-6
0.32
1
10/11 /23 17:41
79-00-5
0.38
1
10/11 /23 17:41
79-01-6
0.30
1
10/11 /23 17:41
75-69-4
0.26
1
10/11 /23 17:41
96-18-4
1.3
1
10/11 /23 17:41
108-05-4
0.39
1
10/11 /23 17:41
75-01-4
0.34
1
10/11 /23 17:41
1330-20-7
0.71
1
10/11 /23 17:41
179601-23-1
0.34
1
10/11 /23 17:41
95-47-6
1 10/11 /23 17:41 460-00-4
1 10/11 /23 17:41 17060-07-0
1 10/11 /23 17:41 2037-26-5
0.86 1 10/12/23 19:15 123-91-1
1 10/12/23 19:15 17060-07-0
1 10/12/23 19:15 2037-26-5
5.0 1 10/18/23 17:54
0.25 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
11/28/23 08:24 20074-52-6 N2
Page 66 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: MW-05R-20231009
Lab ID: 92692397002 Collected:
10/09/23
17:38
Received: 10/10/23
11:08 Matrix: Water
Parameters
Results Units PQL
MDL
DF
Prepared
Analyzed
CAS No. Qual
Iron, Ferrous
Analytical Method: SM 3500-Fe B-2011
Pace Analytical Services -Asheville
Iron, Ferrous
4.3 mg/L 1.0
0.080
2
10/17/23 12:14
H3,N2
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
<0.022 mg/L 0.10
0.022
1
10/11/23 01:28
18496-25-8
5210B BOD, 5 day
Analytical Method: SM 521OB-2011
Pace Analytical Services -Asheville
BOD, 5 day
75.7 mg/L 2.0
2.0
1
10/11/23 05:28
10/16/23 09:48
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
134 mg/L 25.0
12.5
1
10/19/23 03:19
10/20/23 00:01
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
13.8 mg/L 1.0
0.50
1
10/16/23 22:55
7440-44-0
9056 IC Anions 48hr
Analytical Method: EPA 9056A
Pace Analytical Services -Asheville
Chloride
67.7 mg/L 1.0
0.60
1
10/11/23 00:48
16887-00-6 M1
Nitrate as N
<0.060 mg/L 0.10
0.060
1
10/11/23 00:48
14797-55-8
Sulfate
<0.50 mg/L 1.0
0.50
1
10/11/23 00:48
14808-79-8
Date: 02/23/2024 01:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 67 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: MW-07-20231009 Lab ID: 92692397003 Collected: 10/09/23 13:03 Received: 10/10/23 11:08 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Ethane
<5.9
ug/L
10.0
5.9
1
10/12/2316:12
74-84-0
Ethene
<5.7
ug/L
10.0
5.7
1
10/12/2316:12
74-85-1
Methane
393
ug/L
10.0
5.3
1
10/12/2316:12
74-82-8
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Antimony
<0.20
ug/L
1.0
0.20
1
10/15/23 13:35
10/17/23 06:00
7440-36-0
Arsenic
0.12J
ug/L
1.0
0.087
1
10/15/23 13:35
10/17/23 06:00
7440-38-2
Barium
451
ug/L
3.0
0.64
3
10/15/23 13:35
10/17/2315:08
7440-39-3
Beryllium
<0.050
ug/L
0.10
0.050
1
10/15/23 13:35
10/17/23 06:00
7440-41-7
Cadmium
<0.060
ug/L
0.20
0.060
1
10/15/23 13:35
10/17/23 06:00
7440-43-9
Chromium
0.84J
ug/L
1.0
0.50
1
10/15/23 13:35
10/17/23 06:00
7440-47-3
Cobalt
2.3
ug/L
1.0
0.050
1
10/15/23 13:35
10/17/23 06:00
7440-48-4
Copper
<1.1
ug/L
2.0
1.1
1
10/15/23 13:35
10/17/23 06:00
7440-50-8
Iron
700
ug/L
50.0
20.9
1
10/18/2312:10
10/18/2319:36
7439-89-6
Lead
0.080J
ug/L
1.0
0.077
1
10/15/23 13:35
10/17/23 06:00
7439-92-1
Nickel
7.7
ug/L
1.0
0.42
1
10/15/23 13:35
10/17/23 06:00
7440-02-0
Selenium
<0.072
ug/L
2.0
0.072
1
10/15/23 13:35
10/17/23 06:00
7782-49-2
Silver
<0.070
ug/L
0.40
0.070
1
10/15/23 13:35
10/17/23 06:00
7440-22-4
Thallium
<0.050
ug/L
0.20
0.050
1
10/15/23 13:35
10/17/23 06:00
7440-28-0
Tin
1.3
ug/L
1.0
0.43
1
10/15/23 13:35
10/17/23 06:00
7440-31-5
Vanadium
0.34J
ug/L
1.0
0.25
1
10/15/23 13:35
10/17/23 06:00
7440-62-2
7470 Mercury
Mercury
8270E APP9 RV
Acenaphthene
Acenaphthylene
Acetophenone
2-Acetylaminofluorene
4-Aminobiphenyl
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Benzyl alcohol
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methyl phenol
4-Chloroaniline
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
<0.12 ug/L 0.20 0.12 1 10/12/2312:00 10/13/2312:47 7439-97-6
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
<2.0
ug/L
10.0
2.0
1
10/12/23 15:31
10/13/23 20:31
83-32-9
<2.0
ug/L
10.0
2.0
1
10/12/23 15:31
10/13/23 20:31
208-96-8
<1.5
ug/L
10.0
1.5
1
10/12/23 15:31
10/13/23 20:31
98-86-2
<4.1
ug/L
10.0
4.1
1
10/12/23 15:31
10/13/23 20:31
53-96-3
<4.7
ug/L
10.0
4.7
1
10/12/23 15:31
10/13/23 20:31
92-67-1
<2.3
ug/L
10.0
2.3
1
10/12/23 15:31
10/13/23 20:31
120-12-7
<2.7
ug/L
10.0
2.7
1
10/12/23 15:31
10/13/23 20:31
56-55-3
<2.8
ug/L
10.0
2.8
1
10/12/23 15:31
10/13/23 20:31
50-32-8
<2.6
ug/L
10.0
2.6
1
10/12/23 15:31
10/13/23 20:31
205-99-2
<2.8
ug/L
10.0
2.8
1
10/12/23 15:31
10/13/23 20:31
191-24-2
<2.7
ug/L
10.0
2.7
1
10/12/23 15:31
10/13/23 20:31
207-08-9
<2.9
ug/L
20.0
2.9
1
10/12/23 15:31
10/13/23 20:31
100-51-6
<1.8
ug/L
10.0
1.8
1
10/12/23 15:31
10/13/23 20:31
101-55-3
<3.1
ug/L
10.0
3.1
1
10/12/23 15:31
10/13/23 20:31
85-68-7
<3.3
ug/L
10.0
3.3
1
10/12/23 15:31
10/13/23 20:31
59-50-7
<3.6
ug/L
20.0
3.6
1
10/12/23 15:31
10/13/23 20:31
106-47-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
R1
Page 68 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-07-20231009 Lab ID: 92692397003 Collected: 10/09/23 13:03 Received: 10/10/23 11:08 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Chlorobenzilate
<3.8
ug/L
10.0
3.8
1
10/12/23 15:31
10/13/23 20:31
510-15-6
bis(2-Chloroethoxy)methane
<1.8
ug/L
10.0
1.8
1
10/12/23 15:31
10/13/23 20:31
111-91-1
bis(2-Chloroethyl) ether
<1.9
ug/L
10.0
1.9
1
10/12/23 15:31
10/13/23 20:31
111-44-4
2-Chloronaphthalene
<1.7
ug/L
10.0
1.7
1
10/12/23 15:31
10/13/23 20:31
91-58-7
2-Chlorophenol
<1.2
ug/L
10.0
1.2
1
10/12/23 15:31
10/13/23 20:31
95-57-8
4-Chlorophenylphenyl ether
<2.0
ug/L
10.0
2.0
1
10/12/23 15:31
10/13/23 20:31
7005-72-3
Chrysene
<2.8
ug/L
10.0
2.8
1
10/12/23 15:31
10/13/23 20:31
218-01-9
Diallate
<3.4
ug/L
10.0
3.4
1
10/12/23 15:31
10/13/23 20:31
2303-16-4
Dibenz(a,h)anthracene
<3.0
ug/L
10.0
3.0
1
10/12/23 15:31
10/13/23 20:31
53-70-3
Dibenzofuran
<2.1
ug/L
10.0
2.1
1
10/12/23 15:31
10/13/23 20:31
132-64-9
3,3'-Dichlorobenzidine
<8.1
ug/L
20.0
8.1
1
10/12/23 15:31
10/13/23 20:31
91-94-1
2,4-Dichlorophenol
<1.4
ug/L
10.0
1.4
1
10/12/23 15:31
10/13/23 20:31
120-83-2
2,6-Dichlorophenol
<4.2
ug/L
10.0
4.2
1
10/12/23 15:31
10/13/23 20:31
87-65-0
Diethylphthalate
<2.0
ug/L
10.0
2.0
1
10/12/23 15:31
10/13/23 20:31
84-66-2
Dimethoate
<3.7
ug/L
10.0
3.7
1
10/12/23 15:31
10/13/23 20:31
60-51-5
P-Dimethylaminoazobenzene
<2.4
ug/L
5.0
2.4
1
10/12/23 15:31
10/13/23 20:31
60-11-7
7,12-Dimethylbenz(a)anthracene
<3.0
ug/L
10.0
3.0
1
10/12/23 15:31
10/13/23 20:31
57-97-6
3,3'-Dimethylbenzidine
<31.1
ug/L
50.0
31.1
1
10/12/23 15:31
10/13/23 20:31
119-93-7
2,4-Dimethylphenol
<1.7
ug/L
10.0
1.7
1
10/12/23 15:31
10/13/23 20:31
105-67-9
Dimethylphthalate
<2.1
ug/L
10.0
2.1
1
10/12/23 15:31
10/13/23 20:31
131-11-3
Di-n-butylphthalate
<2.2
ug/L
10.0
2.2
1
10/12/23 15:31
10/13/23 20:31
84-74-2
4,6-Dinitro-2-methyl phenol
<7.8
ug/L
20.0
7.8
1
10/12/23 15:31
10/13/23 20:31
534-52-1
1,3-Dinitrobenzene
<3.8
ug/L
10.0
3.8
1
10/12/23 15:31
10/13/23 20:31
99-65-0
2,4-Dinitrophenol
<26.0
ug/L
50.0
26.0
1
10/12/23 15:31
10/13/23 20:31
51-28-5
2,4-Dinitrotoluene
<1.6
ug/L
10.0
1.6
1
10/12/23 15:31
10/13/23 20:31
121-14-2
2,6-Dinitrotoluene
<1.7
ug/L
10.0
1.7
1
10/12/23 15:31
10/13/23 20:31
606-20-2
Di-n-octylphthalate
<3.9
ug/L
10.0
3.9
1
10/12/23 15:31
10/13/23 20:31
117-84-0
Diphenylamine
<3.0
ug/L
10.0
3.0
1
10/12/23 15:31
10/13/23 20:31
122-39-4
Disulfoton
<4.6
ug/L
10.0
4.6
1
10/12/23 15:31
10/13/23 20:31
298-04-4
bis(2- Ethyl hexyl)phthalate
<3.7
ug/L
6.0
3.7
1
10/12/23 15:31
10/13/23 20:31
117-81-7
Ethyl methanesulfonate
<3.0
ug/L
20.0
3.0
1
10/12/23 15:31
10/13/23 20:31
62-50-0
Famphur
<6.1
ug/L
10.0
6.1
1
10/12/23 15:31
10/13/23 20:31
52-85-7
Fluoranthene
<2.2
ug/L
10.0
2.2
1
10/12/23 15:31
10/13/23 20:31
206-44-0
Fluorene
<2.1
ug/L
10.0
2.1
1
10/12/23 15:31
10/13/23 20:31
86-73-7
Hexachlorobenzene
<2.2
ug/L
10.0
2.2
1
10/12/23 15:31
10/13/23 20:31
118-74-1
Hexachlorocyclopentadiene
<1.6
ug/L
10.0
1.6
1
10/12/23 15:31
10/13/23 20:31
77-47-4
Hexachloroethane
<1.4
ug/L
10.0
1.4
1
10/12/23 15:31
10/13/23 20:31
67-72-1
Hexachloropropene
<2.7
ug/L
10.0
2.7
1
10/12/23 15:31
10/13/23 20:31
1888-71-7
Indeno(1,2,3-cd)pyrene
<2.9
ug/L
10.0
2.9
1
10/12/23 15:31
10/13/23 20:31
193-39-5
Isodrin
<2.8
ug/L
10.0
2.8
1
10/12/23 15:31
10/13/23 20:31
465-73-6
Isophorone
<1.7
ug/L
10.0
1.7
1
10/12/23 15:31
10/13/23 20:31
78-59-1
Isosafrole
<2.5
ug/L
10.0
2.5
1
10/12/23 15:31
10/13/23 20:31
120-58-1
Kepone
<14.1
ug/L
20.0
14.1
1
10/12/23 15:31
10/13/23 20:31
143-50-0
Methapyrilene
<17.0
ug/L
50.0
17.0
1
10/12/23 15:31
10/13/23 20:31
91-80-5
3-Methylcholanthrene
<3.7
ug/L
10.0
3.7
1
10/12/23 15:31
10/13/23 20:31
56-49-5
REPORT OF LABORATORY ANALYSIS
M1
M1
IL
IH,M1
LTA
v1
L1,v1
L2
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 69 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: MW-07-20231009
Lab ID:
92692397003
Collected:
10/09/23
13:03
Received: 10/10/23
11:08 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared
Analyzed
CAS No.
Qual
8270E APP9 RV
Analytical
Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services - Charlotte
Methyl methanesulfonate
<3.1
ug/L
5.0
3.1
1
10/12/23 15:31
10/13/23 20:31
66-27-3
2-Methylnaphthalene
<1.9
ug/L
10.0
1.9
1
10/12/23 15:31
10/13/23 20:31
91-57-6
Methyl parathion
<3.7
ug/L
10.0
3.7
1
10/12/23 15:31
10/13/23 20:31
298-00-0
2-Methylphenol(o-Cresol)
<1.9
ug/L
10.0
1.9
1
10/12/23 15:31
10/13/23 20:31
95-48-7
3&4-Methyl phenol (m&p Cresol)
<1.2
ug/L
10.0
1.2
1
10/12/23 15:31
10/13/23 20:31
15831-10-4
R1
1-Naphthalenamine
<6.0
ug/L
10.0
6.0
1
10/12/23 15:31
10/13/23 20:31
134-32-7
2-Naphthalenamine
<5.4
ug/L
10.0
5.4
1
10/12/23 15:31
10/13/23 20:31
91-59-8
1,4-Naphthoquinone
<4.4
ug/L
5.0
4.4
1
10/12/23 15:31
10/13/23 20:31
130-15-4
2-Nitroaniline
<3.0
ug/L
20.0
3.0
1
10/12/23 15:31
10/13/23 20:31
88-74-4
3-Nitroaniline
<3.8
ug/L
20.0
3.8
1
10/12/23 15:31
10/13/23 20:31
99-09-2
4-Nitroaniline
<5.1
ug/L
20.0
5.1
1
10/12/23 15:31
10/13/23 20:31
100-01-6
Nitrobenzene
<1.9
ug/L
10.0
1.9
1
10/12/23 15:31
10/13/23 20:31
98-95-3
2-Nitrophenol
<1.4
ug/L
10.0
1.4
1
10/12/23 15:31
10/13/23 20:31
88-75-5
M1
4-Nitrophenol
<6.6
ug/L
50.0
6.6
1
10/12/23 15:31
10/13/23 20:31
100-02-7
M1
5-Nitro-o-toluidine
<3.8
ug/L
10.0
3.8
1
10/12/23 15:31
10/13/23 20:31
99-55-8
N-Nitrosodiethylamine
<2.3
ug/L
10.0
2.3
1
10/12/23 15:31
10/13/23 20:31
55-18-5
N-Nitrosodimethylamine
<1.9
ug/L
10.0
1.9
1
10/12/23 15:31
10/13/23 20:31
62-75-9
N-Nitroso-di-n-butylamine
<2.0
ug/L
10.0
2.0
1
10/12/23 15:31
10/13/23 20:31
924-16-3
N-Nitroso-di-n-propylamine
<1.3
ug/L
10.0
1.3
1
10/12/23 15:31
10/13/23 20:31
621-64-7
N-Nitrosodiphenylamine
<3.0
ug/L
10.0
3.0
1
10/12/23 15:31
10/13/23 20:31
86-30-6
N-Nitrosomethylethylamine
<7.5
ug/L
10.0
7.5
1
10/12/23 15:31
10/13/23 20:31
10595-95-6
N-Nitrosopiperidine
<2.5
ug/L
10.0
2.5
1
10/12/23 15:31
10/13/23 20:31
100-75-4
N-Nitrosopyrrolidine
<3.1
ug/L
10.0
3.1
1
10/12/23 15:31
10/13/23 20:31
930-55-2
O,O,O-Triethylphosphorothioate
<2.6
ug/L
10.0
2.6
1
10/12/23 15:31
10/13/23 20:31
126-68-1
v1
2,2'-Oxybis(1-chloropropane)
<1.2
ug/L
10.0
1.2
1
10/12/23 15:31
10/13/23 20:31
108-60-1
Parathion (Ethyl parathion)
<3.9
ug/L
10.0
3.9
1
10/12/23 15:31
10/13/23 20:31
56-38-2
Pentachlorobenzene
<3.4
ug/L
10.0
3.4
1
10/12/23 15:31
10/13/23 20:31
608-93-5
Pentachloronitrobenzene
<3.3
ug/L
10.0
3.3
1
10/12/23 15:31
10/13/23 20:31
82-68-8
v1
Pentachlorophenol
<3.8
ug/L
20.0
3.8
1
10/12/23 15:31
10/13/23 20:31
87-86-5
M1
Phenacetin
<3.6
ug/L
10.0
3.6
1
10/12/23 15:31
10/13/23 20:31
62-44-2
Phenanthrene
<2.0
ug/L
10.0
2.0
1
10/12/23 15:31
10/13/23 20:31
85-01-8
Phenol
<1.4
ug/L
10.0
1.4
1
10/12/23 15:31
10/13/23 20:31
108-95-2
p-Phenylenediamine
<10.0
ug/L
10.0
10.0
1
10/12/23 15:31
10/13/23 20:31
106-50-3
Phorate
<3.6
ug/L
10.0
3.6
1
10/12/23 15:31
10/13/23 20:31
298-02-2
Pronamide
<3.1
ug/L
10.0
3.1
1
10/12/23 15:31
10/13/23 20:31
23950-58-5
Pyrene
<2.2
ug/L
10.0
2.2
1
10/12/23 15:31
10/13/23 20:31
129-00-0
Safrole
<2.3
ug/L
10.0
2.3
1
10/12/23 15:31
10/13/23 20:31
94-59-7
1,2,4,5-Tetrachlorobenzene
<4.5
ug/L
10.0
4.5
1
10/12/23 15:31
10/13/23 20:31
95-94-3
2,3,4,6-Tetrachlorophenol
<1.5
ug/L
10.0
1.5
1
10/12/23 15:31
10/13/23 20:31
58-90-2
M1
Thionazin
<2.9
ug/L
10.0
2.9
1
10/12/23 15:31
10/13/23 20:31
297-97-2
O-Toluidine
<2.6
ug/L
10.0
2.6
1
10/12/23 15:31
10/13/23 20:31
95-53-4
2,4,5-Trichlorophenol
<1.4
ug/L
10.0
1.4
1
10/12/23 15:31
10/13/23 20:31
95-95-4
M1
2,4,6-Trichlorophenol
<1.6
ug/L
10.0
1.6
1
10/12/23 15:31
10/13/23 20:31
88-06-2
M1
1,3,5-Trinitrobenzene
<5.5
ug/L
10.0
5.5
1
10/12/23 15:31
10/13/23 20:31
99-35-4
v2,v3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 70 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-07-20231009 Lab ID: 92692397003 Collected: 10/09/23 13:03 Received: 10/10/23 11:08 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260D MSV Low Level Landfill
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
85
%
10-133
1
10/12/23 15:31
10/13/23 20:31
4165-60-0
76
%
10-130
1
10/12/23 15:31
10/13/23 20:31
321-60-8
93
%
10-193
1
10/12/23 15:31
10/13/23 20:31
1718-51-0
49
%
10-130
1
10/12/23 15:31
10/13/23 20:31
13127-88-3
59
%
10-130
1
10/12/23 15:31
10/13/23 20:31
367-12-4
100
%
10-166
1
10/12/23 15:31
10/13/23 20:31
118-79-6
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
<5.1
ug/L
25.0
5.1
1
10/11/2318:16
67-64-1
1.6
ug/L
1.0
0.34
1
10/11/2318:16
71-43-2
<0.29
ug/L
1.0
0.29
1
10/11/2318:16
108-86-1
<0.47
ug/L
1.0
0.47
1
10/11/2318:16
74-97-5
<0.31
ug/L
1.0
0.31
1
10/11/2318:16
75-27-4
<0.34
ug/L
1.0
0.34
1
10/11/2318:16
75-25-2
<1.7
ug/L
2.0
1.7
1
10/11/2318:16
74-83-9
<4.0
ug/L
5.0
4.0
1
10/11/2318:16
78-93-3
<0.33
ug/L
1.0
0.33
1
10/11/2318:16
56-23-5
4.1
ug/L
1.0
0.28
1
10/11/2318:16
108-90-7
<0.65
ug/L
1.0
0.65
1
10/11/2318:16
75-00-3
<0.43
ug/L
1.0
0.43
1
10/11/2318:16
67-66-3
<0.54
ug/L
1.0
0.54
1
10/11/2318:16
74-87-3
<0.32
ug/L
1.0
0.32
1
10/11/2318:16
95-49-8
<0.32
ug/L
1.0
0.32
1
10/11/2318:16
106-43-4
<0.34
ug/L
2.0
0.34
1
10/11/2318:16
96-12-8
<0.36
ug/L
1.0
0.36
1
10/11/2318:16
124-48-1
<0.27
ug/L
1.0
0.27
1
10/11/2318:16
106-93-4
<0.39
ug/L
1.0
0.39
1
10/11/2318:16
74-95-3
<0.34
ug/L
1.0
0.34
1
10/11/2318:16
95-50-1
<0.34
ug/L
1.0
0.34
1
10/11/2318:16
541-73-1
4.6
ug/L
1.0
0.33
1
10/11/2318:16
106-46-7
<0.35
ug/L
1.0
0.35
1
10/11/2318:16
75-71-8
<0.37
ug/L
1.0
0.37
1
10/11/2318:16
75-34-3
<0.32
ug/L
1.0
0.32
1
10/11/2318:16
107-06-2
<0.35
ug/L
1.0
0.35
1
10/11/2318:16
75-35-4
1.7
ug/L
1.0
0.38
1
10/11/2318:16
156-59-2
<0.40
ug/L
1.0
0.40
1
10/11/2318:16
156-60-5
<0.36
ug/L
1.0
0.36
1
10/11/2318:16
78-87-5
<0.28
ug/L
1.0
0.28
1
10/11/2318:16
142-28-9
<0.39
ug/L
1.0
0.39
1
10/11/2318:16
594-20-7
<0.43
ug/L
1.0
0.43
1
10/11/2318:16
563-58-6
<0.36
ug/L
1.0
0.36
1
10/11/2318:16
10061-01-5
<0.36
ug/L
1.0
0.36
1
10/11/2318:16
10061-02-6
<0.31
ug/L
1.0
0.31
1
10/11/2318:16
108-20-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 71 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-07-20231009 Lab ID: 92692397003 Collected: 10/09/23 13:03 Received: 10/10/23 11:08 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Iron, Ferric (Calculation)
Iron, Ferric
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
<0.30
ug/L
1.0
<1.5
ug/L
2.0
<0.48
ug/L
5.0
<0.41
ug/L
1.0
<2.0
ug/L
5.0
<2.7
ug/L
5.0
0.80J
ug/L
1.0
<0.64
ug/L
1.0
<0.29
ug/L
1.0
<0.31
ug/L
1.0
<0.22
ug/L
1.0
<0.29
ug/L
1.0
<0.24
ug/L
1.0
<0.81
ug/L
1.0
<0.64
ug/L
1.0
<0.33
ug/L
1.0
<0.32
ug/L
1.0
<0.38
ug/L
1.0
<0.30
ug/L
1.0
<0.26
ug/L
1.0
<1.3
ug/L
2.0
<0.39
ug/L
1.0
<0.34
ug/L
1.0
<0.71
ug/L
2.0
<0.34
ug/L
1.0
102
%
70-130
101
%
70-130
103
%
70-130
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
21.2
ug/L
2.0
91 % 67-130
91 % 70-130
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
263 mg/L 5.0
Analytical Method: SM 3500-Fe D#4
Pace Analytical Services -Asheville
<0.25 mg/L 0.50
0.30
1
10/11 /23 18:16
100-41-4
1.5
1
10/11/2318:16
87-68-3
0.48
1
10/11 /23 18:16
591-78-6
0.41
1
10/11/2318:16
99-87-6
2.0
1
10/11/2318:16
75-09-2
2.7
1
10/11 /23 18:16
108-10-1
0.42
1
10/11 /23 18:16
1634-04-4
0.64
1
10/11 /23 18:16
91-20-3
0.29
1
10/11 /23 18:16
100-42-5
0.31
1
10/11/2318:16
630-20-6
0.22
1
10/11/2318:16
79-34-5
0.29
1
10/11 /23 18:16
127-18-4
0.24
1
10/11 /23 18:16
108-88-3
0.81
1
10/11 /23 18:16
87-61-6
0.64
1
10/11 /23 18:16
120-82-1
0.33
1
10/11 /23 18:16
71-55-6
0.32
1
10/11/2318:16
79-00-5
0.38
1
10/11 /23 18:16
79-01-6
0.30
1
10/11/2318:16
75-69-4
0.26
1
10/11/2318:16
96-18-4
1.3
1
10/11 /23 18:16
108-05-4
0.39
1
10/11 /23 18:16
75-01-4
0.34
1
10/11 /23 18:16
1330-20-7
0.71
1
10/11 /23 18:16
179601-23-1
0.34
1
10/11/2318:16
95-47-6
1 10/11/2318:16 460-00-4
1 10/11 /23 18:16 17060-07-0
1 10/11/2318:16 2037-26-5
0.86 1 10/12/23 19:36 123-91-1
1 10/12/23 19:36 17060-07-0
1 10/12/23 19:36 2037-26-5
5.0 1 10/19/23 10:05
0.25 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
11/28/23 08:24 20074-52-6 N2
Page 72 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: MW-07-20231009
Lab ID: 92692397003 Collected:
10/09/23
13:03
Received: 10/10/23
11:08 Matrix: Water
Parameters
Results Units PQL
MDL
DF
Prepared
Analyzed
CAS No. Qual
Iron, Ferrous
Analytical Method: SM 3500-Fe B-2011
Pace Analytical Services -Asheville
Iron, Ferrous
0.57 mg/L 0.50
0.040
1
10/17/23 11:34
H3,N2
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
<0.022 mg/L 0.10
0.022
1
10/11/23 01:28
18496-25-8
5210B BOD, 5 day
Analytical Method: SM 521OB-2011
Pace Analytical Services -Asheville
BOD, 5 day
<2.0 mg/L 2.0
2.0
1
10/11/23 05:28
10/16/23 09:42
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
24.8J mg/L 25.0
12.5
1
10/19/23 03:19
10/20/23 00:01
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
2.6 mg/L 1.0
0.50
1
10/23/23 11:47
7440-44-0
9056 IC Anions 48hr
Analytical Method: EPA 9056A
Pace Analytical Services -Asheville
Chloride
83.9 mg/L 1.0
0.60
1
10/10/23 23:01
16887-00-6
Nitrate as N
<0.060 mg/L 0.10
0.060
1
10/10/23 23:01
14797-55-8
Sulfate
17.6 mg/L 1.0
0.50
1
10/10/23 23:01
14808-79-8
Date: 02/23/2024 01:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 73 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: TB-20231009 Lab ID: 92692397004 Collected: 10/09/23 00:00 Received: 10/10/23 11:08 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
<5.1
ug/L
25.0
5.1
1
10/11/2315:03
67-64-1
<0.34
ug/L
1.0
0.34
1
10/11/2315:03
71-43-2
<0.29
ug/L
1.0
0.29
1
10/11/2315:03
108-86-1
<0.47
ug/L
1.0
0.47
1
10/11/2315:03
74-97-5
<0.31
ug/L
1.0
0.31
1
10/11/2315:03
75-27-4
<0.34
ug/L
1.0
0.34
1
10/11/2315:03
75-25-2
<1.7
ug/L
2.0
1.7
1
10/11/2315:03
74-83-9
<4.0
ug/L
5.0
4.0
1
10/11/2315:03
78-93-3
<0.33
ug/L
1.0
0.33
1
10/11/2315:03
56-23-5
<0.28
ug/L
1.0
0.28
1
10/11/2315:03
108-90-7
<0.65
ug/L
1.0
0.65
1
10/11/2315:03
75-00-3
<0.43
ug/L
1.0
0.43
1
10/11/2315:03
67-66-3
<0.54
ug/L
1.0
0.54
1
10/11/2315:03
74-87-3
<0.32
ug/L
1.0
0.32
1
10/11/2315:03
95-49-8
<0.32
ug/L
1.0
0.32
1
10/11/2315:03
106-43-4
<0.34
ug/L
2.0
0.34
1
10/11/2315:03
96-12-8
<0.36
ug/L
1.0
0.36
1
10/11/2315:03
124-48-1
<0.27
ug/L
1.0
0.27
1
10/11/2315:03
106-93-4
<0.39
ug/L
1.0
0.39
1
10/11/2315:03
74-95-3
<0.34
ug/L
1.0
0.34
1
10/11/2315:03
95-50-1
<0.34
ug/L
1.0
0.34
1
10/11/2315:03
541-73-1
<0.33
ug/L
1.0
0.33
1
10/11/2315:03
106-46-7
<0.35
ug/L
1.0
0.35
1
10/11/2315:03
75-71-8
<0.37
ug/L
1.0
0.37
1
10/11/2315:03
75-34-3
<0.32
ug/L
1.0
0.32
1
10/11/2315:03
107-06-2
<0.35
ug/L
1.0
0.35
1
10/11/2315:03
75-35-4
<0.38
ug/L
1.0
0.38
1
10/11/2315:03
156-59-2
<0.40
ug/L
1.0
0.40
1
10/11/2315:03
156-60-5
<0.36
ug/L
1.0
0.36
1
10/11/2315:03
78-87-5
<0.28
ug/L
1.0
0.28
1
10/11/2315:03
142-28-9
<0.39
ug/L
1.0
0.39
1
10/11/2315:03
594-20-7
<0.43
ug/L
1.0
0.43
1
10/11/2315:03
563-58-6
<0.36
ug/L
1.0
0.36
1
10/11/2315:03
10061-01-5
<0.36
ug/L
1.0
0.36
1
10/11/2315:03
10061-02-6
<0.31
ug/L
1.0
0.31
1
10/11/2315:03
108-20-3
<0.30
ug/L
1.0
0.30
1
10/11/2315:03
100-41-4
<1.5
ug/L
2.0
1.5
1
10/11/2315:03
87-68-3
<0.48
ug/L
5.0
0.48
1
10/11/2315:03
591-78-6
<0.41
ug/L
1.0
0.41
1
10/11/2315:03
99-87-6
<2.0
ug/L
5.0
2.0
1
10/11/2315:03
75-09-2
<2.7
ug/L
5.0
2.7
1
10/11/2315:03
108-10-1
<0.42
ug/L
1.0
0.42
1
10/11/2315:03
1634-04-4
<0.64
ug/L
1.0
0.64
1
10/11/2315:03
91-20-3
<0.29
ug/L
1.0
0.29
1
10/11/2315:03
100-42-5
<0.31
ug/L
1.0
0.31
1
10/11/2315:03
630-20-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 74 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: TB-20231009
Lab ID:
92692397004
Collected:
10/09/23
00:00
Received: 10/10/23 11:08 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,2,2-Tetrachloroethane
<0.22
ug/L
1.0
0.22
1
10/11/23 15:03
79-34-5
Tetrachloroethene
<0.29
ug/L
1.0
0.29
1
10/11/23 15:03
127-18-4
Toluene
<0.24
ug/L
1.0
0.24
1
10/11/23 15:03
108-88-3
1,2,3-Trichlorobenzene
<0.81
ug/L
1.0
0.81
1
10/11/23 15:03
87-61-6
1,2,4-Trichlorobenzene
<0.64
ug/L
1.0
0.64
1
10/11/23 15:03
120-82-1
1,1,1-Trichloroethane
<0.33
ug/L
1.0
0.33
1
10/11/23 15:03
71-55-6
1,1,2-Trichloroethane
<0.32
ug/L
1.0
0.32
1
10/11/23 15:03
79-00-5
Trichloroethene
<0.38
ug/L
1.0
0.38
1
10/11/23 15:03
79-01-6
Trichlorofluoromethane
<0.30
ug/L
1.0
0.30
1
10/11/23 15:03
75-69-4
1,2,3-Trichloropropane
<0.26
ug/L
1.0
0.26
1
10/11/23 15:03
96-18-4
Vinyl acetate
<1.3
ug/L
2.0
1.3
1
10/11/23 15:03
108-05-4
Vinyl chloride
<0.39
ug/L
1.0
0.39
1
10/11/23 15:03
75-01-4
Xylene (Total)
<0.34
ug/L
1.0
0.34
1
10/11/23 15:03
1330-20-7
m&p-Xylene
<0.71
ug/L
2.0
0.71
1
10/11/23 15:03
179601-23-1
o-Xylene
<0.34
ug/L
1.0
0.34
1
10/11/23 15:03
95-47-6
Surrogates
4-Bromofluorobenzene (S)
102
%
70-130
1
10/11/23 15:03
460-00-4
1,2-Dichloroethane-d4 (S)
100
%
70-130
1
10/11/23 15:03
17060-07-0
Toluene-d8 (S)
101
%
70-130
1
10/11/23 15:03
2037-26-5
Date: 02/23/2024 01:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 75 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: MW-03-20231011 Lab ID: 92691921015 Collected: 10/11/23 11:27 Received: 10/12/23 16:45 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
<0.20
ug/L
1.0
0.20
1
10/19/23 16:00
10/23/23 22:36
7440-36-0
Arsenic
0.12J
ug/L
1.0
0.087
1
10/19/23 16:00
10/23/23 22:36
7440-38-2
Barium
131
ug/L
1.0
0.21
1
10/19/23 16:00
10/23/23 22:36
7440-39-3
Beryllium
<0.050
ug/L
0.10
0.050
1
10/19/23 16:00
10/23/23 22:36
7440-41-7
Cadmium
0.26
ug/L
0.20
0.060
1
10/19/23 16:00
10/23/23 22:36
7440-43-9
Chromium
0.54J
ug/L
1.0
0.50
1
10/19/23 16:00
10/23/23 22:36
7440-47-3
Cobalt
15.4
ug/L
1.0
0.050
1
10/19/23 16:00
10/23/23 22:36
7440-48-4
Copper
<1.1
ug/L
2.0
1.1
1
10/19/23 16:00
10/23/23 22:36
7440-50-8
Iron
86.1
ug/L
50.0
20.9
1
10/19/23 16:00
10/23/23 22:36
7439-89-6
Lead
0.15J
ug/L
1.0
0.077
1
10/19/23 16:00
10/23/23 22:36
7439-92-1
Nickel
2.8
ug/L
1.0
0.42
1
10/19/23 16:00
10/23/23 22:36
7440-02-0
Selenium
<0.072
ug/L
2.0
0.072
1
10/19/23 16:00
10/23/23 22:36
7782-49-2
Silver
<0.070
ug/L
0.40
0.070
1
10/19/23 16:00
10/23/23 22:36
7440-22-4
Thallium
0.0981
ug/L
0.20
0.050
1
10/19/23 16:00
10/23/23 22:36
7440-28-0
Tin
<0.43
ug/L
1.0
0.43
1
10/19/23 16:00
10/23/23 22:36
7440-31-5
Vanadium
<0.25
ug/L
1.0
0.25
1
10/19/23 16:00
10/23/23 22:36
7440-62-2
7470 Mercury
Analytical Method: EPA 7470A Preparation Method: EPA
7470A
Pace Analytical Services
-Asheville
Mercury
<0.12
ug/L
0.20
0.12
1
10/17/2312:27
10/18/2311:53
7439-97-6
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method:
EPA
3510C
Pace Analytical Services - Charlotte
Acenaphthene
<2.0
ug/L
10.0
2.0
1
10/15/23 11:13
10/17/23 13:36
83-32-9
Acenaphthylene
<2.0
ug/L
10.0
2.0
1
10/15/23 11:13
10/17/23 13:36
208-96-8
Acetophenone
<1.5
ug/L
10.0
1.5
1
10/15/23 11:13
10/17/23 13:36
98-86-2
2-Acetylaminofluorene
<4.1
ug/L
10.0
4.1
1
10/15/23 11:13
10/17/23 13:36
53-96-3
4-Aminobiphenyl
<4.7
ug/L
10.0
4.7
1
10/15/23 11:13
10/17/23 13:36
92-67-1
Anthracene
<2.3
ug/L
10.0
2.3
1
10/15/23 11:13
10/17/23 13:36
120-12-7
Benzo(a)anthracene
<2.7
ug/L
10.0
2.7
1
10/15/23 11:13
10/17/23 13:36
56-55-3
Benzo(a)pyrene
<2.8
ug/L
10.0
2.8
1
10/15/23 11:13
10/17/23 13:36
50-32-8
Benzo(b)fluoranthene
<2.6
ug/L
10.0
2.6
1
10/15/23 11:13
10/17/23 13:36
205-99-2
Benzo(g,h,i)perylene
<2.8
ug/L
10.0
2.8
1
10/15/23 11:13
10/17/23 13:36
191-24-2
Benzo(k)fluoranthene
<2.7
ug/L
10.0
2.7
1
10/15/23 11:13
10/17/23 13:36
207-08-9
Benzyl alcohol
<2.9
ug/L
20.0
2.9
1
10/15/23 11:13
10/17/23 13:36
100-51-6
4-Bromophenylphenyl ether
<1.8
ug/L
10.0
1.8
1
10/15/23 11:13
10/17/23 13:36
101-55-3
Butylbenzylphthalate
<3.1
ug/L
10.0
3.1
1
10/15/23 11:13
10/17/23 13:36
85-68-7
4-Chloro-3-methyl phenol
<3.3
ug/L
10.0
3.3
1
10/15/23 11:13
10/17/23 13:36
59-50-7
4-Chloroaniline
<3.6
ug/L
20.0
3.6
1
10/15/23 11:13
10/17/23 13:36
106-47-8
Chlorobenzilate
<3.8
ug/L
10.0
3.8
1
10/15/23 11:13
10/17/23 13:36
510-15-6
bis(2-Chloroethoxy)methane
<1.8
ug/L
10.0
1.8
1
10/15/23 11:13
10/17/23 13:36
111-91-1
bis(2-Chloroethyl) ether
<1.9
ug/L
10.0
1.9
1
10/15/23 11:13
10/17/23 13:36
111-44-4
2-Chloronaphthalene
<1.7
ug/L
10.0
1.7
1
10/15/23 11:13
10/17/23 13:36
91-58-7
2-Chlorophenol
<1.2
ug/L
10.0
1.2
1
10/15/23 11:13
10/17/23 13:36
95-57-8
4-Chlorophenylphenyl ether
<2.0
ug/L
10.0
2.0
1
10/15/23 11:13
10/17/23 13:36
7005-72-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 76 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-03-20231011 Lab ID: 92691921015 Collected: 10/11/23 11:27 Received: 10/12/23 16:45 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Chrysene
<2.8
ug/L
10.0
2.8
1
10/15/23 11:13
10/17/23 13:36
218-01-9
Diallate
<3.4
ug/L
10.0
3.4
1
10/15/23 11:13
10/17/23 13:36
2303-16-4
Dibenz(a,h)anthracene
<3.0
ug/L
10.0
3.0
1
10/15/23 11:13
10/17/23 13:36
53-70-3
Dibenzofuran
<2.1
ug/L
10.0
2.1
1
10/15/23 11:13
10/17/23 13:36
132-64-9
3,3'-Dichlorobenzidine
<8.1
ug/L
20.0
8.1
1
10/15/23 11:13
10/17/23 13:36
91-94-1
2,4-Dichlorophenol
<1.4
ug/L
10.0
1.4
1
10/15/23 11:13
10/17/23 13:36
120-83-2
2,6-Dichlorophenol
<4.2
ug/L
10.0
4.2
1
10/15/23 11:13
10/17/23 13:36
87-65-0
Diethylphthalate
<2.0
ug/L
10.0
2.0
1
10/15/23 11:13
10/17/23 13:36
84-66-2
Dimethoate
<3.7
ug/L
10.0
3.7
1
10/15/23 11:13
10/17/23 13:36
60-51-5
P-Dimethylaminoazobenzene
<2.4
ug/L
5.0
2.4
1
10/15/23 11:13
10/17/23 13:36
60-11-7
7,12-Dimethylbenz(a)anthracene
<3.0
ug/L
10.0
3.0
1
10/15/23 11:13
10/17/23 13:36
57-97-6
3,3'-Dimethylbenzidine
<31.1
ug/L
50.0
31.1
1
10/15/23 11:13
10/17/23 13:36
119-93-7
2,4-Dimethylphenol
<1.7
ug/L
10.0
1.7
1
10/15/23 11:13
10/17/23 13:36
105-67-9
Dimethylphthalate
<2.1
ug/L
10.0
2.1
1
10/15/23 11:13
10/17/23 13:36
131-11-3
Di-n-butylphthalate
<2.2
ug/L
10.0
2.2
1
10/15/23 11:13
10/17/23 13:36
84-74-2
4,6-Dinitro-2-methyl phenol
<7.8
ug/L
20.0
7.8
1
10/15/23 11:13
10/17/23 13:36
534-52-1
1,3-Dinitrobenzene
<3.8
ug/L
10.0
3.8
1
10/15/23 11:13
10/17/23 13:36
99-65-0
2,4-Dinitrophenol
<26.0
ug/L
50.0
26.0
1
10/15/23 11:13
10/17/23 13:36
51-28-5
2,4-Dinitrotoluene
<1.6
ug/L
10.0
1.6
1
10/15/23 11:13
10/17/23 13:36
121-14-2
2,6-Dinitrotoluene
<1.7
ug/L
10.0
1.7
1
10/15/23 11:13
10/17/23 13:36
606-20-2
Di-n-octylphthalate
<3.9
ug/L
10.0
3.9
1
10/15/23 11:13
10/17/23 13:36
117-84-0
Diphenylamine
<3.0
ug/L
10.0
3.0
1
10/15/23 11:13
10/17/23 13:36
122-39-4
Disulfoton
<4.6
ug/L
10.0
4.6
1
10/15/23 11:13
10/17/23 13:36
298-04-4
bis(2- Ethyl hexyl)phthalate
<3.7
ug/L
6.0
3.7
1
10/15/23 11:13
10/17/23 13:36
117-81-7
Ethyl methanesulfonate
<3.0
ug/L
20.0
3.0
1
10/15/23 11:13
10/17/23 13:36
62-50-0
Famphur
<6.1
ug/L
10.0
6.1
1
10/15/23 11:13
10/17/23 13:36
52-85-7
Fluoranthene
<2.2
ug/L
10.0
2.2
1
10/15/23 11:13
10/17/23 13:36
206-44-0
Fluorene
<2.1
ug/L
10.0
2.1
1
10/15/23 11:13
10/17/23 13:36
86-73-7
Hexachlorobenzene
<2.2
ug/L
10.0
2.2
1
10/15/23 11:13
10/17/23 13:36
118-74-1
Hexachlorocyclopentadiene
<1.6
ug/L
10.0
1.6
1
10/15/23 11:13
10/17/23 13:36
77-47-4
Hexachloroethane
<1.4
ug/L
10.0
1.4
1
10/15/23 11:13
10/17/23 13:36
67-72-1
Hexachloropropene
<2.7
ug/L
10.0
2.7
1
10/15/23 11:13
10/17/23 13:36
1888-71-7
Indeno(1,2,3-cd)pyrene
<2.9
ug/L
10.0
2.9
1
10/15/23 11:13
10/17/23 13:36
193-39-5
Isodrin
<2.8
ug/L
10.0
2.8
1
10/15/23 11:13
10/17/23 13:36
465-73-6
Isophorone
<1.7
ug/L
10.0
1.7
1
10/15/23 11:13
10/17/23 13:36
78-59-1
Isosafrole
<2.5
ug/L
10.0
2.5
1
10/15/23 11:13
10/17/23 13:36
120-58-1
Kepone
<14.1
ug/L
20.0
14.1
1
10/15/23 11:13
10/17/23 13:36
143-50-0
Methapyrilene
<17.0
ug/L
50.0
17.0
1
10/15/23 11:13
10/17/23 13:36
91-80-5
3-Methylcholanthrene
<3.7
ug/L
10.0
3.7
1
10/15/23 11:13
10/17/23 13:36
56-49-5
Methyl methanesulfonate
<3.1
ug/L
5.0
3.1
1
10/15/23 11:13
10/17/23 13:36
66-27-3
2-Methylnaphthalene
<1.9
ug/L
10.0
1.9
1
10/15/23 11:13
10/17/23 13:36
91-57-6
Methyl parathion
<3.7
ug/L
10.0
3.7
1
10/15/23 11:13
10/17/23 13:36
298-00-0
2-Methylphenol(o-Cresol)
<1.9
ug/L
10.0
1.9
1
10/15/23 11:13
10/17/23 13:36
95-48-7
3&4-Methyl phenol (m&p Cresol)
<1.2
ug/L
10.0
1.2
1
10/15/23 11:13
10/17/23 13:36
15831-10-4
REPORT OF LABORATORY ANALYSIS
IL
IH,L1,
M0.v1
R1
v1
v1
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 77 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: MW-03-20231011 Lab ID: 92691921015 Collected: 10/11/23 11:27 Received: 10/12/23 16:45 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
1-Naphthalenamine
<6.0
ug/L
10.0
6.0
1
10/15/23 11:13
10/17/23 13:36
134-32-7
2-Naphthalenamine
<5.4
ug/L
10.0
5.4
1
10/15/23 11:13
10/17/23 13:36
91-59-8
1,4-Naphthoquinone
<4.4
ug/L
5.0
4.4
1
10/15/23 11:13
10/17/23 13:36
130-15-4
2-Nitroaniline
<3.0
ug/L
20.0
3.0
1
10/15/23 11:13
10/17/23 13:36
88-74-4
3-Nitroaniline
<3.8
ug/L
20.0
3.8
1
10/15/23 11:13
10/17/23 13:36
99-09-2
4-Nitroaniline
<5.1
ug/L
20.0
5.1
1
10/15/23 11:13
10/17/23 13:36
100-01-6
Nitrobenzene
<1.9
ug/L
10.0
1.9
1
10/15/23 11:13
10/17/23 13:36
98-95-3
2-Nitrophenol
<1.4
ug/L
10.0
1.4
1
10/15/23 11:13
10/17/23 13:36
88-75-5
v1
4-Nitrophenol
<6.6
ug/L
50.0
6.6
1
10/15/23 11:13
10/17/23 13:36
100-02-7
5-Nitro-o-toluidine
<3.8
ug/L
10.0
3.8
1
10/15/23 11:13
10/17/23 13:36
99-55-8
N-Nitrosodiethylamine
<2.3
ug/L
10.0
2.3
1
10/15/23 11:13
10/17/23 13:36
55-18-5
N-Nitrosodimethylamine
<1.9
ug/L
10.0
1.9
1
10/15/23 11:13
10/17/23 13:36
62-75-9
N-Nitroso-di-n-butylamine
<2.0
ug/L
10.0
2.0
1
10/15/23 11:13
10/17/23 13:36
924-16-3
L1
N-Nitroso-di-n-propylamine
<1.3
ug/L
10.0
1.3
1
10/15/23 11:13
10/17/23 13:36
621-64-7
N-Nitrosodiphenylamine
<3.0
ug/L
10.0
3.0
1
10/15/23 11:13
10/17/23 13:36
86-30-6
N-Nitrosomethylethylamine
<7.5
ug/L
10.0
7.5
1
10/15/23 11:13
10/17/23 13:36
10595-95-6
N-Nitrosopiperidine
<2.5
ug/L
10.0
2.5
1
10/15/23 11:13
10/17/23 13:36
100-75-4
N-Nitrosopyrrolidine
<3.1
ug/L
10.0
3.1
1
10/15/23 11:13
10/17/23 13:36
930-55-2
O,O,O-Triethylphosphorothioate
<2.6
ug/L
10.0
2.6
1
10/15/23 11:13
10/17/23 13:36
126-68-1
v1
2,2'-Oxybis(1-chloropropane)
<1.2
ug/L
10.0
1.2
1
10/15/23 11:13
10/17/23 13:36
108-60-1
Parathion (Ethyl parathion)
<3.9
ug/L
10.0
3.9
1
10/15/23 11:13
10/17/23 13:36
56-38-2
Pentachlorobenzene
<3.4
ug/L
10.0
3.4
1
10/15/23 11:13
10/17/23 13:36
608-93-5
L1,v1
Pentachloronitrobenzene
<3.3
ug/L
10.0
3.3
1
10/15/23 11:13
10/17/23 13:36
82-68-8
v1
Pentachlorophenol
<3.8
ug/L
20.0
3.8
1
10/15/23 11:13
10/17/23 13:36
87-86-5
Phenacetin
<3.6
ug/L
10.0
3.6
1
10/15/23 11:13
10/17/23 13:36
62-44-2
Phenanthrene
<2.0
ug/L
10.0
2.0
1
10/15/23 11:13
10/17/23 13:36
85-01-8
Phenol
<1.4
ug/L
10.0
1.4
1
10/15/23 11:13
10/17/23 13:36
108-95-2
p-Phenylenediamine
<10.0
ug/L
10.0
10.0
1
10/15/23 11:13
10/17/23 13:36
106-50-3
Phorate
<3.6
ug/L
10.0
3.6
1
10/15/23 11:13
10/17/23 13:36
298-02-2
Pronamide
<3.1
ug/L
10.0
3.1
1
10/15/23 11:13
10/17/23 13:36
23950-58-5
Pyrene
<2.2
ug/L
10.0
2.2
1
10/15/23 11:13
10/17/23 13:36
129-00-0
Safrole
<2.3
ug/L
10.0
2.3
1
10/15/23 11:13
10/17/23 13:36
94-59-7
v1
1,2,4,5-Tetrachlorobenzene
<4.5
ug/L
10.0
4.5
1
10/15/23 11:13
10/17/23 13:36
95-94-3
2,3,4,6-Tetrachlorophenol
<1.5
ug/L
10.0
1.5
1
10/15/23 11:13
10/17/23 13:36
58-90-2
Thionazin
<2.9
ug/L
10.0
2.9
1
10/15/23 11:13
10/17/23 13:36
297-97-2
O-Toluidine
<2.6
ug/L
10.0
2.6
1
10/15/23 11:13
10/17/23 13:36
95-53-4
2,4,5-Trichlorophenol
<1.4
ug/L
10.0
1.4
1
10/15/23 11:13
10/17/23 13:36
95-95-4
v1
2,4,6-Trichlorophenol
<1.6
ug/L
10.0
1.6
1
10/15/23 11:13
10/17/23 13:36
88-06-2
1,3,5-Trinitrobenzene
<5.5
ug/L
10.0
5.5
1
10/15/23 11:13
10/17/23 13:36
99-35-4
v2,v3
Surrogates
Nitrobenzene-d5 (S)
90
%
10-133
1
10/15/23 11:13
10/17/23 13:36
4165-60-0
P2
2-Fluorobiphenyl (S)
93
%
10-130
1
10/15/23 11:13
10/17/23 13:36
321-60-8
Terphenyl-d14 (S)
108
%
10-193
1
10/15/23 11:13
10/17/23 13:36
1718-51-0
Phenol-d6 (S)
1
%
10-130
1
10/15/23 11:13
10/17/23 13:36
13127-88-3
SO
2-Fluorophenol (S)
9
%
10-130
1
10/15/23 11:13
10/17/23 13:36
367-12-4
SO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 78 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-03-20231011 Lab ID: 92691921015 Collected: 10/11/23 11:27 Received: 10/12/23 16:45 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Surrogates
2,4,6-Tribromophenol (S)
8260D MSV Low Level Landfill
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
97
%
10-166
1
10/15/2311:13 10/17/2313:36
118-79-6
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
<5.1
ug/L
25.0
5.1
1
10/16/2319:17
67-64-1
0.40J
ug/L
1.0
0.34
1
10/16/2319:17
71-43-2
<0.29
ug/L
1.0
0.29
1
10/16/2319:17
108-86-1
<0.47
ug/L
1.0
0.47
1
10/16/2319:17
74-97-5
<0.31
ug/L
1.0
0.31
1
10/16/2319:17
75-27-4
<0.34
ug/L
1.0
0.34
1
10/16/2319:17
75-25-2
<1.7
ug/L
2.0
1.7
1
10/16/2319:17
74-83-9
<4.0
ug/L
5.0
4.0
1
10/16/2319:17
78-93-3
<0.33
ug/L
1.0
0.33
1
10/16/2319:17
56-23-5
4.7
ug/L
1.0
0.28
1
10/16/2319:17
108-90-7
<0.65
ug/L
1.0
0.65
1
10/16/2319:17
75-00-3
<0.43
ug/L
1.0
0.43
1
10/16/2319:17
67-66-3
<0.54
ug/L
1.0
0.54
1
10/16/2319:17
74-87-3
<0.32
ug/L
1.0
0.32
1
10/16/2319:17
95-49-8
<0.32
ug/L
1.0
0.32
1
10/16/2319:17
106-43-4
<0.34
ug/L
2.0
0.34
1
10/16/2319:17
96-12-8
<0.36
ug/L
1.0
0.36
1
10/16/2319:17
124-48-1
<0.27
ug/L
1.0
0.27
1
10/16/2319:17
106-93-4
<0.39
ug/L
1.0
0.39
1
10/16/2319:17
74-95-3
<0.34
ug/L
1.0
0.34
1
10/16/2319:17
95-50-1
<0.34
ug/L
1.0
0.34
1
10/16/2319:17
541-73-1
2.4
ug/L
1.0
0.33
1
10/16/2319:17
106-46-7
<0.35
ug/L
1.0
0.35
1
10/16/2319:17
75-71-8
<0.37
ug/L
1.0
0.37
1
10/16/2319:17
75-34-3
<0.32
ug/L
1.0
0.32
1
10/16/2319:17
107-06-2
<0.35
ug/L
1.0
0.35
1
10/16/2319:17
75-35-4
0.77J
ug/L
1.0
0.38
1
10/16/2319:17
156-59-2
<0.40
ug/L
1.0
0.40
1
10/16/2319:17
156-60-5
<0.36
ug/L
1.0
0.36
1
10/16/2319:17
78-87-5
<0.28
ug/L
1.0
0.28
1
10/16/2319:17
142-28-9
<0.39
ug/L
1.0
0.39
1
10/16/2319:17
594-20-7
<0.43
ug/L
1.0
0.43
1
10/16/2319:17
563-58-6
<0.36
ug/L
1.0
0.36
1
10/16/2319:17
10061-01-5
<0.36
ug/L
1.0
0.36
1
10/16/2319:17
10061-02-6
<0.31
ug/L
1.0
0.31
1
10/16/2319:17
108-20-3
<0.30
ug/L
1.0
0.30
1
10/16/2319:17
100-41-4
<1.5
ug/L
2.0
1.5
1
10/16/2319:17
87-68-3
<0.48
ug/L
5.0
0.48
1
10/16/2319:17
591-78-6
<0.41
ug/L
1.0
0.41
1
10/16/2319:17
99-87-6
<2.0
ug/L
5.0
2.0
1
10/16/2319:17
75-09-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
Page 79 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-03-20231011 Lab ID: 92691921015 Collected: 10/11/23 11:27 Received: 10/12/23 16:45 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Iron, Ferric (Calculation)
Iron, Ferric
Iron, Ferrous
Iron, Ferrous
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
<2.7
ug/L
5.0
0.49J
ug/L
1.0
<0.64
ug/L
1.0
<0.29
ug/L
1.0
<0.31
ug/L
1.0
<0.22
ug/L
1.0
<0.29
ug/L
1.0
<0.24
ug/L
1.0
<0.81
ug/L
1.0
<0.64
ug/L
1.0
<0.33
ug/L
1.0
<0.32
ug/L
1.0
<0.38
ug/L
1.0
<0.30
ug/L
1.0
<0.26
ug/L
1.0
<1.3
ug/L
2.0
<0.39
ug/L
1.0
<0.34
ug/L
1.0
<0.71
ug/L
2.0
<0.34
ug/L
1.0
106
%
70-130
89
%
70-130
106
%
70-130
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
6.7
ug/L
2.0
89
%
67-130
93
%
70-130
Analytical Method: SM 2320B-2011
Pace Analytical Services
-Asheville
65.9
mg/L
5.0
Analytical Method: SM 3500-Fe D#4
Pace Analytical Services
-Asheville
<0.25
mg/L
0.50
Analytical Method: SM 3500-Fe B-2011
Pace Analytical Services
-Asheville
0.097.11
mg/L
0.50
2.7
1
10/16/23 19:17
108-10-1
0.42
1
10/16/23 19:17
1634-04-4
0.64
1
10/16/23 19:17
91-20-3
0.29
1
10/16/23 19:17
100-42-5
0.31
1
10/16/23 19:17
630-20-6
0.22
1
10/16/23 19:17
79-34-5
0.29
1
10/16/23 19:17
127-18-4
0.24
1
10/16/23 19:17
108-88-3
0.81
1
10/16/23 19:17
87-61-6
0.64
1
10/16/23 19:17
120-82-1
0.33
1
10/16/23 19:17
71-55-6
0.32
1
10/16/23 19:17
79-00-5
0.38
1
10/16/23 19:17
79-01-6
0.30
1
10/16/23 19:17
75-69-4
0.26
1
10/16/23 19:17
96-18-4
1.3
1
10/16/23 19:17
108-05-4
0.39
1
10/16/23 19:17
75-01-4
0.34
1
10/16/23 19:17
1330-20-7
0.71
1
10/16/23 19:17
179601-23-1
0.34
1
10/16/23 19:17
95-47-6
1
10/16/23 19:17
460-00-4
1
10/16/23 19:17
17060-07-0
1
10/16/23 19:17
2037-26-5
0.86 1 10/16/23 13:53 123-91-1
1 10/16/2313:53 17060-07-0 P4
1 10/16/2313:53 2037-26-5
5.0 1 10/20/23 13:27
0.25 1
0.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
11/28/23 08:24 20074-52-6 N2
10/17/23 11:39
H3,N2
Page 80 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: MW-03-20231011
Lab ID: 92691921015 Collected:
10/11/23
11:27
Received: 10/12/23
16:45 Matrix: Water
Parameters
Results Units PQL
MDL
DF
Prepared
Analyzed
CAS No. Qual
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
<0.022 mg/L 0.10
0.022
1
10/18/23 03:54
18496-25-8
5210B BOD, 5 day
Analytical Method: SM 521OB-2016
Pace Analytical Services -Asheville
BOD, 5 day
<2.0 mg/L 2.0
2.0
1
10/14/23 05:09
10/19/23 04:10
H2
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
20.9J mg/L 25.0
12.5
1
10/25/23 01:46
10/25/23 04:55
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
5.0 mg/L 1.0
0.50
1
10/24/23 01:15
7440-44-0
9056 IC Anions 48hr
Analytical Method: EPA 9056A
Pace Analytical Services -Asheville
Chloride
30.6 mg/L 1.0
0.60
1
10/13/2319:15
16887-00-6
Nitrate as N
4.2 mg/L 0.10
0.060
1
10/13/23 19:15
14797-55-8 H1,M1
Sulfate
3.0 mg/L 1.0
0.50
1
10/13/2319:15
14808-79-8
Date: 02/23/2024 01:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 81 of 229

Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: DW-01-20231011
Parameters
524.2 MSV
Benzene
Carbon tetrachloride
Chlorobenzene
1,2-Dichlorobenzene
1,4-Dichlorobenzene
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
Ethylbenzene
Methylene Chloride
Styrene
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
Toluene-d8 (S)
1,2-Dichlorobenzene-d4 (S)
Date: 02/23/2024 01:48 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Lab ID: 92691921016 Collected: 10/11/23 14:10 Received: 10/12/23 16:45 Matrix: Water
Results
Units
PQL
MDL
Analytical
Method:
EPA 524.2
Pace Analytical Services
- Ormond
Beach
<0.00040
mg/L
0.00050
0.00040
<0.00028
mg/L
0.00050
0.00028
<0.00026
mg/L
0.00050
0.00026
<0.00026
mg/L
0.00050
0.00026
<0.00030
mg/L
0.00050
0.00030
<0.00030
mg/L
0.00050
0.00030
<0.00029
mg/L
0.00050
0.00029
<0.00033
mg/L
0.00050
0.00033
<0.00027
mg/L
0.00050
0.00027
<0.00044
mg/L
0.00050
0.00044
<0.00023
mg/L
0.00050
0.00023
<0.00044
mg/L
0.0010
0.00044
<0.00025
mg/L
0.00050
0.00025
<0.00026
mg/L
0.00050
0.00026
<0.00028
mg/L
0.00050
0.00028
<0.00035
mg/L
0.00050
0.00035
<0.00027
mg/L
0.00050
0.00027
<0.00028
mg/L
0.00050
0.00028
<0.00026
mg/L
0.00050
0.00026
<0.00019
mg/L
0.00050
0.00019
<0.00011
mg/L
0.0010
0.00011
103
%
70-130
97
%
70-130
102
%
70-130
DF Prepared Analyzed CAS No. Qual
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
10/17/2315:04
71-43-2
10/17/2315:04
56-23-5
10/ 17/23 15:04
108-90-7
10/17/2315:04
95-50-1
10/ 17/23 15:04
106-46-7
10/ 17/23 15:04
107-06-2
10/17/2315:04
75-35-4
10/ 17/23 15:04
156-59-2
10/ 18/23 14:40
156-60-5
10/17/2315:04
78-87-5
10/17/23 15:04
100-41-4
10/17/2315:04
75-09-2
10/ 17/23 15:04
100-42-5
10/ 17/23 15:04
127-18-4
10/ 17/23 15:04
108-88-3
10/ 17/23 15:04
120-82-1
10/17/2315:04
71-55-6
10/17/2315:04
79-00-5
10/17/2315:04
79-01-6
10/17/2315:04
75-01-4
10/ 17/23 15:04
1330-20-7
10/18/2314:40 460-00-4
10/18/2314:40 2037-26-5
10/18/2314:40 2199-69-1
Page 82 of 229

Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: DW-02-20231011
Parameters
524.2 MSV
Benzene
Carbon tetrachloride
Chlorobenzene
1,2-Dichlorobenzene
1,4-Dichlorobenzene
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
Ethylbenzene
Methylene Chloride
Styrene
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
Toluene-d8 (S)
1,2-Dichlorobenzene-d4 (S)
Date: 02/23/2024 01:48 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Lab ID: 92691921017 Collected: 10/11/23 14:55 Received: 10/12/23 16:45 Matrix: Water
Results
Units
PQL
MDL
Analytical
Method:
EPA 524.2
Pace Analytical Services
- Ormond
Beach
<0.00040
mg/L
0.00050
0.00040
<0.00028
mg/L
0.00050
0.00028
<0.00026
mg/L
0.00050
0.00026
<0.00026
mg/L
0.00050
0.00026
<0.00030
mg/L
0.00050
0.00030
<0.00030
mg/L
0.00050
0.00030
<0.00029
mg/L
0.00050
0.00029
<0.00033
mg/L
0.00050
0.00033
<0.00027
mg/L
0.00050
0.00027
<0.00044
mg/L
0.00050
0.00044
<0.00023
mg/L
0.00050
0.00023
<0.00044
mg/L
0.0010
0.00044
<0.00025
mg/L
0.00050
0.00025
<0.00026
mg/L
0.00050
0.00026
<0.00028
mg/L
0.00050
0.00028
<0.00035
mg/L
0.00050
0.00035
<0.00027
mg/L
0.00050
0.00027
<0.00028
mg/L
0.00050
0.00028
<0.00026
mg/L
0.00050
0.00026
<0.00019
mg/L
0.00050
0.00019
<0.00011
mg/L
0.0010
0.00011
99
%
70-130
104
%
70-130
100
%
70-130
DF Prepared Analyzed CAS No. Qual
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
10/17/2315:29
71-43-2
10/17/2315:29
56-23-5
10/ 17/23 15:29
108-90-7
10/17/2315:29
95-50-1
10/ 17/23 15:29
106-46-7
10/ 17/23 15:29
107-06-2
10/17/2315:29
75-35-4
10/ 17/23 15:29
156-59-2
10/ 18/23 15:05
156-60-5
10/17/2315:29
78-87-5
10/17/23 15:29
100-41-4
10/17/2315:29
75-09-2
10/ 17/23 15:29
100-42-5
10/ 17/23 15:29
127-18-4
10/ 17/23 15:29
108-88-3
10/ 17/23 15:29
120-82-1
10/17/2315:29
71-55-6
10/17/2315:29
79-00-5
10/17/2315:29
79-01-6
10/17/2315:29
75-01-4
10/ 17/23 15:29
1330-20-7
10/18/2315:05 460-00-4
10/18/2315:05 2037-26-5
10/18/2315:05 2199-69-1
Page 83 of 229

ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: TB-20231011 Lab ID: 92691921018 Collected: 10/11/23 00:00 Received: 10/12/23 16:45 Matrix: Water
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
Date: 02/23/2024 01:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
<5.1
ug/L
25.0
5.1
1
10/16/2313:22
67-64-1
<0.34
ug/L
1.0
0.34
1
10/16/2313:22
71-43-2
<0.29
ug/L
1.0
0.29
1
10/16/2313:22
108-86-1
<0.47
ug/L
1.0
0.47
1
10/16/2313:22
74-97-5
<0.31
ug/L
1.0
0.31
1
10/16/2313:22
75-27-4
<0.34
ug/L
1.0
0.34
1
10/16/2313:22
75-25-2
<1.7
ug/L
2.0
1.7
1
10/16/2313:22
74-83-9 v2
<4.0
ug/L
5.0
4.0
1
10/16/2313:22
78-93-3
<0.33
ug/L
1.0
0.33
1
10/16/2313:22
56-23-5
<0.28
ug/L
1.0
0.28
1
10/16/2313:22
108-90-7
<0.65
ug/L
1.0
0.65
1
10/16/2313:22
75-00-3
<0.43
ug/L
1.0
0.43
1
10/16/2313:22
67-66-3
<0.54
ug/L
1.0
0.54
1
10/16/2313:22
74-87-3
<0.32
ug/L
1.0
0.32
1
10/16/2313:22
95-49-8
<0.32
ug/L
1.0
0.32
1
10/16/2313:22
106-43-4
<0.34
ug/L
2.0
0.34
1
10/16/2313:22
96-12-8
<0.36
ug/L
1.0
0.36
1
10/16/2313:22
124-48-1
<0.27
ug/L
1.0
0.27
1
10/16/2313:22
106-93-4
<0.39
ug/L
1.0
0.39
1
10/16/2313:22
74-95-3
<0.34
ug/L
1.0
0.34
1
10/16/2313:22
95-50-1
<0.34
ug/L
1.0
0.34
1
10/16/2313:22
541-73-1
<0.33
ug/L
1.0
0.33
1
10/16/2313:22
106-46-7
<0.35
ug/L
1.0
0.35
1
10/16/2313:22
75-71-8
<0.37
ug/L
1.0
0.37
1
10/16/2313:22
75-34-3
<0.32
ug/L
1.0
0.32
1
10/16/2313:22
107-06-2
<0.35
ug/L
1.0
0.35
1
10/16/2313:22
75-35-4
<0.38
ug/L
1.0
0.38
1
10/16/2313:22
156-59-2
<0.40
ug/L
1.0
0.40
1
10/16/2313:22
156-60-5
<0.36
ug/L
1.0
0.36
1
10/16/2313:22
78-87-5
<0.28
ug/L
1.0
0.28
1
10/16/2313:22
142-28-9
<0.39
ug/L
1.0
0.39
1
10/16/2313:22
594-20-7
<0.43
ug/L
1.0
0.43
1
10/16/2313:22
563-58-6
<0.36
ug/L
1.0
0.36
1
10/16/2313:22
10061-01-5
<0.36
ug/L
1.0
0.36
1
10/16/2313:22
10061-02-6
<0.31
ug/L
1.0
0.31
1
10/16/2313:22
108-20-3
<0.30
ug/L
1.0
0.30
1
10/16/2313:22
100-41-4
<1.5
ug/L
2.0
1.5
1
10/16/2313:22
87-68-3
<0.48
ug/L
5.0
0.48
1
10/16/2313:22
591-78-6
<0.41
ug/L
1.0
0.41
1
10/16/2313:22
99-87-6
<2.0
ug/L
5.0
2.0
1
10/16/2313:22
75-09-2
<2.7
ug/L
5.0
2.7
1
10/16/2313:22
108-10-1
<0.42
ug/L
1.0
0.42
1
10/16/2313:22
1634-04-4
<0.64
ug/L
1.0
0.64
1
10/16/2313:22
91-20-3
<0.29
ug/L
1.0
0.29
1
10/16/2313:22
100-42-5
<0.31
ug/L
1.0
0.31
1
10/16/2313:22
630-20-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 84 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Sample: TB-20231011
Lab ID:
92691921018
Collected:
10/11/23
00:00
Received: 10/12/23 16:45 Matrix: Water
Parameters
Results
Units
PQL
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1,2,2-Tetrachloroethane
<0.22
ug/L
1.0
0.22
1
10/16/23 13:22
79-34-5
Tetrachloroethene
<0.29
ug/L
1.0
0.29
1
10/16/23 13:22
127-18-4
Toluene
<0.24
ug/L
1.0
0.24
1
10/16/23 13:22
108-88-3
1,2,3-Trichlorobenzene
<0.81
ug/L
1.0
0.81
1
10/16/23 13:22
87-61-6
1,2,4-Trichlorobenzene
<0.64
ug/L
1.0
0.64
1
10/16/23 13:22
120-82-1
1,1,1-Trichloroethane
<0.33
ug/L
1.0
0.33
1
10/16/23 13:22
71-55-6
1,1,2-Trichloroethane
<0.32
ug/L
1.0
0.32
1
10/16/23 13:22
79-00-5
Trichloroethene
<0.38
ug/L
1.0
0.38
1
10/16/23 13:22
79-01-6
Trichlorofluoromethane
<0.30
ug/L
1.0
0.30
1
10/16/23 13:22
75-69-4
1,2,3-Trichloropropane
<0.26
ug/L
1.0
0.26
1
10/16/23 13:22
96-18-4
Vinyl acetate
<1.3
ug/L
2.0
1.3
1
10/16/23 13:22
108-05-4
Vinyl chloride
<0.39
ug/L
1.0
0.39
1
10/16/23 13:22
75-01-4
Xylene (Total)
<0.34
ug/L
1.0
0.34
1
10/16/23 13:22
1330-20-7
m&p-Xylene
<0.71
ug/L
2.0
0.71
1
10/16/23 13:22
179601-23-1
o-Xylene
<0.34
ug/L
1.0
0.34
1
10/16/23 13:22
95-47-6
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
10/16/23 13:22
460-00-4
1,2-Dichloroethane-d4 (S)
107
%
70-130
1
10/16/23 13:22
17060-07-0
Toluene-d8 (S)
102
%
70-130
1
10/16/23 13:22
2037-26-5
Date: 02/23/2024 01:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 85 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QC Batch: 805861 Analysis Method: RSK 175 Modified
QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92691980001, 92691980002, 92691980003, 92691980004, 92692397001, 92692397002, 92692397003
METHOD BLANK: 4172958
Matrix:
Water
Associated Lab Samples:
92691980001, 92691980002, 92691980003, 92691980004, 92692397001, 92692397002, 92692397003
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
Ethane
ug/L
<5.9
10.0
5.9 10/12/2312:44
Ethene
ug/L
<5.7
10.0
5.7 10/12/2312:44
Methane
ug/L
<5.3
10.0
5.3 10/12/2312:44
LABORATORY CONTROL SAMPLE:
4172959
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits
Qualifiers
Ethane
ug/L
557
544
98
70-130
Ethene
ug/L
520
518
100
70-130
Methane
ug/L
297
259
87
70-130
MATRIX SPIKE SAMPLE:
4172961
92692397002
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Ethane
ug/L
<5.9
557
220
39 70-130 M1
Ethene
ug/L
<5.7
520
207
40 70-130 M1
Methane
ug/L
1870
297
1470
-135
70-130 M1
SAMPLE DUPLICATE: 4172960
92692397001
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Ethane
ug/L
<5.9
<5.9
20
Ethene
ug/L
<5.7
<5.7
20
Methane
ug/L
18.9
8.3J
20
SAMPLE DUPLICATE: 4172962
92692476006
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Ethane
ug/L
<5.9
<5.9
20 H1
Ethene
ug/L
<5.7
<5.7
20 H1
Methane
ug/L
<5.3
<5.3
20 H1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 86 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 805815 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92692397001, 92692397002, 92692397003
METHOD BLANK: 4172762 Matrix: Water
Associated Lab Samples: 92692397001, 92692397002, 92692397003
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Mercury ug/L <0.12 0.20 0.12 10/13/2311:51
LABORATORY CONTROL SAMPLE: 4172763
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 2.5 2.5 102 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4172764 4172765
MS MSD
92691419001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND 2.5 2.5 2.6 2.5 105 99 75-125 6 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 87 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QC Batch: 806184 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92691921001, 92691921002, 92691921003, 92691921004, 92691980001, 92691980002, 92691980003,
92691980004
METHOD BLANK: 4174809 Matrix: Water
Associated Lab Samples: 92691921001, 92691921002, 92691921003, 92691921004, 92691980001, 92691980002, 92691980003,
92691980004
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Mercury ug/L <0.12 0.20 0.12 10/14/2311:23
LABORATORY CONTROL SAMPLE: 4174810
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 2.5 2.6 103 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4174811 4174812
MS MSD
92691921002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L <0.12 2.5 2.5 2.4 2.4 98 98 75-125 0 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 88 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 806808 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92691921015
METHOD BLANK: 4177925
Matrix:
Water
Associated Lab Samples: 92691921015
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Mercury
ug/L
<0.12
0.20
0.12 10/18/2311:48
LABORATORY CONTROL SAMPLE:
4177926
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Mercury
ug/L
2.5
2.6 102
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4177927 4177928
MS MSD
92692277019 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND 2.5 2.5 2.7 2.9 106 115 75-125 8 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 89 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QC Batch: 805306 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92691921001, 92691921002, 92691921003, 92691921004, 92691980001, 92691980002, 92691980003,
92691980004
METHOD BLANK: 4170167 Matrix: Water
Associated Lab Samples: 92691921001, 92691921002, 92691921003, 92691921004, 92691980001, 92691980002, 92691980003,
92691980004
Parameter
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Hardness, Total(SM 2340B)
Lead
Nickel
Selenium
Silver
Thallium
Tin
Vanadium
Blank
Reporting
Units
Result
Limit
MDL
Analyzed Qualifiers
ug/L
<0.20
1.0
0.20
10/11/2313:19
ug/L
<0.087
1.0
0.087
10/11/2313:19
ug/L
<0.21
1.0
0.21
10/11/2313:19
ug/L
<0.050
0.10
0.050
10/11/2313:19
ug/L
<0.060
0.20
0.060
10/11/2313:19
ug/L
<0.50
1.0
0.50
10/11/2313:19
ug/L
<0.050
1.0
0.050
10/11/2313:19
ug/L
<1.1
2.0
1.1
10/11 /23 13:19
ug/L
<541
541
541
10/11 /23 13:19
ug/L
<0.077
1.0
0.077
10/11/2313:19
ug/L
<0.42
1.0
0.42
10/11/2313:19
ug/L
<0.072
2.0
0.072
10/11/2313:19
ug/L
<0.070
0.40
0.070
10/11/2313:19
ug/L
<0.050
0.20
0.050
10/11/2313:19
ug/L
<0.43
1.0
0.43
10/11/2313:19
ug/L
<0.25
1.0
0.25
10/11/2313:19
LABORATORY CONTROL SAMPLE:
Parameter
4170168
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
50
50.5
101
80-120
Arsenic
ug/L
50
49.4
99
80-120
Barium
ug/L
50
50.4
101
80-120
Beryllium
ug/L
50
52.7
105
80-120
Cadmium
ug/L
50
49.4
99
80-120
Chromium
ug/L
50
51.2
102
80-120
Cobalt
ug/L
50
51.3
103
80-120
Copper
ug/L
50
50.9
102
80-120
Hardness, Total(SM 2340B)
ug/L
17500
Lead
ug/L
50
48.1
96
80-120
Nickel
ug/L
50
51.6
103
80-120
Selenium
ug/L
50
50.0
100
80-120
Silver
ug/L
25
26.1
104
80-120
Thallium
ug/L
25
24.4
97
80-120
Tin
ug/L
50
49.9
100
80-120
Vanadium
ug/L
50
51.5
103
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 90 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4170169
4170170
MS
MSD
92691844020
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
50
50
49.7
50.2
99
100
75-125
1
20
Arsenic
ug/L
ND
50
50
49.1
49.4
98
99
75-125
1
20
Barium
ug/L
ND
50
50
50.0
50.6
100
101
75-125
1
20
Beryllium
ug/L
0.055J
50
50
53.1
51.6
106
103
75-125
3
20
Cadmium
ug/L
ND
50
50
49.3
49.5
99
99
75-125
0
20
Chromium
ug/L
ND
50
50
50.6
51.4
100
102
75-125
2
20
Cobalt
ug/L
ND
50
50
50.3
50.6
101
101
75-125
0
20
Copper
ug/L
ND
50
50
50.4
50.8
101
101
75-125
1
20
Hardness, Total(SM 2340B)
ug/L
ND
17400
17200
1
20
Lead
ug/L
ND
50
50
48.3
48.3
96
97
75-125
0
20
Nickel
ug/L
ND
50
50
50.4
51.1
100
102
75-125
1
20
Selenium
ug/L
ND
50
50
50.2
50.0
100
100
75-125
0
20
Silver
ug/L
ND
25
25
26.4
26.3
106
105
75-125
0
20
Thallium
ug/L
ND
25
25
24.7
24.7
99
99
75-125
0
20
Tin
ug/L
ND
50
50
49.7
50.0
99
100
75-125
1
20
Vanadium
ug/L
ND
50
50
51.4
51.1
103
102
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 91 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 806465 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92691921001, 92692397001, 92692397002, 92692397003
METHOD BLANK: 4176168
Matrix:
Water
Associated Lab Samples:
92691921001, 92692397001,
92692397002, 92692397003
Blank
Reporting
Parameter
Units
Result
Limit
Antimony
ug/L
<0.20
1.0
Arsenic
ug/L
<0.087
1.0
Barium
ug/L
<0.21
1.0
Beryllium
ug/L
<0.050
0.10
Cadmium
ug/L
<0.060
0.20
Chromium
ug/L
<0.50
1.0
Cobalt
ug/L
<0.050
1.0
Copper
ug/L
<1.1
2.0
Lead
ug/L
<0.077
1.0
Nickel
ug/L
<0.42
1.0
Selenium
ug/L
<0.072
2.0
Silver
ug/L
<0.070
0.40
Thallium
ug/L
<0.050
0.20
Tin
ug/L
<0.43
1.0
Vanadium
ug/L
<0.25
1.0
MDL Analyzed
0.20 10/17/23 04:00
0.087 10/17/23 04:00
0.21 10/17/23 04:00
0.050 10/17/23 04:00
0.060 10/17/23 04:00
0.50 10/17/23 04:00
0.050 10/17/23 04:00
1.1 10/17/23 04:00
0.077 10/17/23 04:00
0.42 10/17/23 04:00
0.072 10/17/23 04:00
0.070 10/17/23 04:00
0.050 10/17/23 04:00
0.43 10/17/23 04:00
0.25 10/17/23 04:00
LABORATORY CONTROL SAMPLE:
Parameter
4176169
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
50
48.1
96
80-120
Arsenic
ug/L
50
53.4
107
80-120
Barium
ug/L
50
53.4
107
80-120
Beryllium
ug/L
50
59.6
119
80-120
Cadmium
ug/L
50
54.2
108
80-120
Chromium
ug/L
50
56.4
113
80-120
Cobalt
ug/L
50
55.1
110
80-120
Copper
ug/L
50
55.9
112
80-120
Lead
ug/L
50
53.4
107
80-120
Nickel
ug/L
50
55.6
111
80-120
Selenium
ug/L
50
55.6
111
80-120
Silver
ug/L
25
22.8
91
80-120
Thallium
ug/L
25
27.4
110
80-120
Tin
ug/L
50
48.4
97
80-120
Vanadium
ug/L
50
53.7
107
80-120
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 92 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
Jackson County Fall 2023
92691921
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4176170
4176171
MS
MSD
92691921001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
1.6J
50
50
36.3
38.4
69
74
75-125
6
20 M1
Arsenic
ug/L
148
50
50
152
154
8
13
75-125
2
20 M1
Barium
ug/L
13600
50
50
10400
10900
-6280
-5470
75-125
4
20 M1
Beryllium
ug/L
3.0
50
50
57.4
60.5
109
115
75-125
5
20
Cadmium
ug/L
0.46J
50
50
51.6
53.3
102
106
75-125
3
20
Chromium
ug/L
1120
50
50
700
644
-837
-949
75-125
8
20 M1
Cobalt
ug/L
68.2
50
50
103
108
70
79
75-125
4
20 M1
Copper
ug/L
155
50
50
117
116
-74
-78
75-125
1
20 M1
Lead
ug/L
45.9
50
50
78.9
81.0
66
70
75-125
3
20 M1
Nickel
ug/L
171
50
50
185
193
29
44
75-125
4
20 M1
Selenium
ug/L
2.OJ
50
50
42.6
44.1
81
84
75-125
3
20
Silver
ug/L
<0.35
25
25
22.4
23.0
89
91
75-125
3
20
Thallium
ug/L
0.69J
25
25
28.0
28.6
109
112
75-125
2
20
Tin
ug/L
26.0
50
50
55.4
58.9
59
66
75-125
6
20 M1
Vanadium
ug/L
304
50
50
237
222
-133
-163
75-125
7
20 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 93 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 807246 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92691980001, 92691980003, 92691980004, 92692397001, 92692397003
METHOD BLANK: 4179999 Matrix: Water
Associated Lab Samples: 92691921002, 92691980001, 92691980003, 92691980004, 92692397001, 92692397003
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Iron ug/L <20.9 50.0 20.9 10/18/2318:06
LABORATORY CONTROL SAMPLE: 4180000
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Iron ug/L 1250 1300 104 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4180034 4180035
MS MSD
92691921002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Iron ug/L 234 1250 1250 1570 1570 107 107 75-125 0 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 94 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 807639 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92691921015
METHOD BLANK: 4182098
Associated Lab Samples: 92691921015
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Antimony
ug/L
<0.20
1.0
0.20
10/23/23 22:26
Arsenic
ug/L
<0.087
1.0
0.087
10/23/23 22:26
Barium
ug/L
<0.21
1.0
0.21
10/23/23 22:26
Beryllium
ug/L
<0.050
0.10
0.050
10/23/23 22:26
Cadmium
ug/L
<0.060
0.20
0.060
10/23/23 22:26
Chromium
ug/L
<0.50
1.0
0.50
10/23/23 22:26
Cobalt
ug/L
<0.050
1.0
0.050
10/23/23 22:26
Copper
ug/L
<1.1
2.0
1.1
10/23/23 22:26
Iron
ug/L
<20.9
50.0
20.9
10/23/23 22:26
Lead
ug/L
<0.077
1.0
0.077
10/23/23 22:26
Nickel
ug/L
<0.42
1.0
0.42
10/23/23 22:26
Selenium
ug/L
<0.072
2.0
0.072
10/23/23 22:26
Silver
ug/L
<0.070
0.40
0.070
10/23/23 22:26
Thallium
ug/L
<0.050
0.20
0.050
10/23/23 22:26
Tin
ug/L
<0.43
1.0
0.43
10/23/23 22:26
Vanadium
ug/L
<0.25
1.0
0.25
10/23/23 22:26
LABORATORY CONTROL SAMPLE:
Parameter
4182099
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
50
51.1
102
80-120
Arsenic
ug/L
50
52.4
105
80-120
Barium
ug/L
50
52.7
105
80-120
Beryllium
ug/L
50
56.1
112
80-120
Cadmium
ug/L
50
55.1
110
80-120
Chromium
ug/L
50
54.7
109
80-120
Cobalt
ug/L
50
56.8
114
80-120
Copper
ug/L
50
56.5
113
80-120
Iron
ug/L
1250
1340
107
80-120
Lead
ug/L
50
54.0
108
80-120
Nickel
ug/L
50
56.2
112
80-120
Selenium
ug/L
50
53.6
107
80-120
Silver
ug/L
25
23.6
95
80-120
Thallium
ug/L
25
27.7
111
80-120
Tin
ug/L
50
51.8
104
80-120
Vanadium
ug/L
50
55.2
110
80-120
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 95 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
Jackson County Fall 2023
92691921
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4182100
4182101
MS
MSD
92691921015
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
<0.20
50
50
51.3
51.6
103
103
75-125
1
20
Arsenic
ug/L
0.12J
50
50
53.4
53.5
107
107
75-125
0
20
Barium
ug/L
131
50
50
189
186
115
110
75-125
1
20
Beryllium
ug/L
<0.050
50
50
57.1
57.8
114
116
75-125
1
20
Cadmium
ug/L
0.26
50
50
55.9
56.3
111
112
75-125
1
20
Chromium
ug/L
0.54J
50
50
55.9
56.0
111
111
75-125
0
20
Cobalt
ug/L
15.4
50
50
71.4
71.9
112
113
75-125
1
20
Copper
ug/L
<1.1
50
50
56.8
57.5
112
113
75-125
1
20
Iron
ug/L
86.1
1250
1250
1410
1420
106
107
75-125
1
20
Lead
ug/L
0.15J
50
50
54.4
54.1
109
108
75-125
0
20
Nickel
ug/L
2.8
50
50
58.6
59.2
112
113
75-125
1
20
Selenium
ug/L
<0.072
50
50
53.1
53.4
106
107
75-125
1
20
Silver
ug/L
<0.070
25
25
24.1
24.1
96
96
75-125
0
20
Thallium
ug/L
0.098J
25
25
28.2
28.1
112
112
75-125
0
20
Tin
ug/L
<0.43
50
50
51.8
51.9
103
104
75-125
0
20
Vanadium
ug/L
<0.25
50
50
55.4
55.7
111
111
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 96 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 814645 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92691980002, 92692397002
METHOD BLANK: 4217476 Matrix: Water
Associated Lab Samples: 92691980002, 92692397002
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Iron ug/L <20.9 50.0 20.9 11/21/2313:48
LABORATORY CONTROL SAMPLE: 4217477
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Iron ug/L 1250 1240 100 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4217478 4217479
MS MSD
92699569001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Iron ug/L ND 1250 1250 1240 1230 99 98 75-125 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 97 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 958810
Analysis Method:
EPA 524.2
QC Batch Method: EPA 524.2
Analysis Description:
524.2 MSV
Laboratory:
Pace
Analytical Services - Ormond Beach
Associated Lab Samples: 92691921016, 92691921017
METHOD BLANK: 5272746
Matrix: Water
Associated Lab Samples: 92691921016, 92691921017
Blank Reporting
Parameter
Units
Result
Limit
MDL
Analyzed
Qualifiers
1,1,1-Trichloroethane
mg/L
<0.00027
0.00050
0.00027
10/17/23 13:40
1,1,2-Trichloroethane
mg/L
<0.00028
0.00050
0.00028
10/17/23 13:40
1,1-Dichloroethene
mg/L
<0.00029
0.00050
0.00029
10/17/23 13:40
1,2,4-Trichlorobenzene
mg/L
<0.00035
0.00050
0.00035
10/17/23 13:40
1,2-Dichlorobenzene
mg/L
<0.00026
0.00050
0.00026
10/17/23 13:40
1,2-Dichloroethane
mg/L
<0.00030
0.00050
0.00030
10/17/23 13:40
1,2-Dichloropropane
mg/L
<0.00044
0.00050
0.00044
10/17/23 13:40
1,4-Dichlorobenzene
mg/L
<0.00030
0.00050
0.00030
10/17/23 13:40
Benzene
mg/L
<0.00040
0.00050
0.00040
10/17/23 13:40
Carbon tetrachloride
mg/L
<0.00028
0.00050
0.00028
10/17/23 13:40
Chlorobenzene
mg/L
<0.00026
0.00050
0.00026
10/17/23 13:40
cis-1,2-Dichloroethene
mg/L
<0.00033
0.00050
0.00033
10/17/23 13:40
Ethylbenzene
mg/L
<0.00023
0.00050
0.00023
10/17/23 13:40
Methylene Chloride
mg/L
<0.00044
0.0010
0.00044
10/17/23 13:40
Styrene
mg/L
<0.00025
0.00050
0.00025
10/17/23 13:40
Tetrachloroethene
mg/L
<0.00026
0.00050
0.00026
10/17/23 13:40
Toluene
mg/L
<0.00028
0.00050
0.00028
10/17/23 13:40
Trichloroethene
mg/L
<0.00026
0.00050
0.00026
10/17/23 13:40
Vinyl chloride
mg/L
<0.00019
0.00050
0.00019
10/17/23 13:40
Xylene (Total)
mg/L
<0.00011
0.0010
0.00011
10/17/23 13:40
1,2-Dichlorobenzene-d4 (S)
%
101
70-130
10/17/23 13:40
4-Bromofluorobenzene (S)
%
98
70-130
10/17/23 13:40
Toluene-d8 (S)
%
100
70-130
10/17/23 13:40
LABORATORY CONTROL SAMPLE & LCSD:
5272747
5272748
Spike LCS
LCSD
LCS LCSD
% Rec
Max
Parameter
Units
Conc. Result
Result
% Rec % Rec
Limits RPD
RPD Qualifiers
1,1,1-Trichloroethane
mg/L
0.04 0.035
0.036
88 90
70-130
2 20
1,1,2-Trichloroethane
mg/L
0.04 0.034
0.035
85 88
70-130
4 20
1,1-Dichloroethene
mg/L
0.04 0.034
0.035
86 88
70-130
2 20
1,2,4-Trichlorobenzene
mg/L
0.04 0.036
0.037
90 92
70-130
2 20
1,2-Dichlorobenzene
mg/L
0.04 0.034
0.035
85 87
70-130
2 20
1,2-Dichloroethane
mg/L
0.04 0.034
0.035
84 87
70-130
3 20
1,2-Dichloropropane
mg/L
0.04 0.034
0.034
85 86
70-130
1 20
1,4-Dichlorobenzene
mg/L
0.04 0.035
0.036
88 91
70-130
3 20
Benzene
mg/L
0.04 0.035
0.036
88 89
70-130
2 20
Carbon tetrachloride
mg/L
0.04 0.035
0.037
88 93
70-130
6 20
Chlorobenzene
mg/L
0.04 0.034
0.035
85 88
70-130
4 20
cis-1,2-Dichloroethene
mg/L
0.04 0.033
0.034
82 84
70-130
2 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is
presented to the right of
the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 98 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE & LCSD:
5272747
5272748
Spike
LCS
LCSD
LCS
LCSD
% Rec
Max
Parameter
Units
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qualifiers
Ethylbenzene
mg/L
0.04
0.036
0.037
89
92
70-130
4
20
Methylene Chloride
mg/L
0.04
0.034
0.034
84
84
70-130
0
20
Styrene
mg/L
0.04
0.037
0.039
93
99
70-130
6
20
Tetrachloroethene
mg/L
0.04
0.036
0.037
89
93
70-130
4
20
Toluene
mg/L
0.04
0.035
0.036
87
90
70-130
3
20
Trichloroethene
mg/L
0.04
0.035
0.035
88
88
70-130
0
20
Vinyl chloride
mg/L
0.04
0.038
0.039
94
98
70-130
4
20
Xylene (Total)
mg/L
0.12
0.11
0.11
92
95
70-130
4
20
1,2-Dichlorobenzene-d4(S)
%
99
98
70-130
4-Bromofluorobenzene (S)
%
99
99
70-130
Toluene-d8(S)
%
101
100
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 99 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QC Batch: 959124 Analysis Method: EPA 524.2
QC Batch Method: EPA 524.2 Analysis Description: 524.2 MSV
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 92691921016, 92691921017
METHOD BLANK: 5274536
Matrix:
Water
Associated Lab Samples: 92691921016,
92691921017
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
trans-1,2-Dichloroethene
mg/L
<0.00027
0.00050
0.00027 10/18/23 14:16
1,2-Dichlorobenzene-d4 (S)
%
102
70-130
10/18/23 14:16
4-Bromofluorobenzene (S)
%
103
70-130
10/18/23 14:16
Toluene-d8 (S)
%
103
70-130
10/18/23 14:16
LABORATORY CONTROL SAMPLE & LCSD:
5274537
5274538
Spike
LCS LCSD
LCS
LCSD
% Rec Max
Parameter
Units Conc.
Result Result
% Rec
% Rec
Limits RPD RPD Qualifiers
trans-1,2-Dichloroethene
mg/L 0.04
0.032 0.030
79
75
70-130 5 20
1,2-Dichlorobenzene-d4 (S)
%
102
99
70-130
4-Bromofluorobenzene (S)
%
101
104
70-130
Toluene-d8(S)
%
106
109
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 100 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 804926 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92691921001, 92691921002, 92691921003, 92691921005, 92691980005
METHOD BLANK: 4168375
Matrix:
Water
Associated Lab Samples: 92691921001,
92691921002, 92691921003, 92691921005, 92691980005
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
<0.31
1.0
0.31
10/09/23 09:21
1,1,1-Trichloroethane
ug/L
<0.33
1.0
0.33
10/09/23 09:21
1,1,2,2-Tetrachloroethane
ug/L
<0.22
1.0
0.22
10/09/23 09:21
1,1,2-Trichloroethane
ug/L
<0.32
1.0
0.32
10/09/23 09:21
1,1-Dichloroethane
ug/L
<0.37
1.0
0.37
10/09/23 09:21
1,1-Dichloroethene
ug/L
<0.35
1.0
0.35
10/09/23 09:21
1,1-Dichloropropene
ug/L
<0.43
1.0
0.43
10/09/23 09:21
1,2,3-Trichlorobenzene
ug/L
<0.81
1.0
0.81
10/09/23 09:21
1,2,3-Trichloropropane
ug/L
<0.26
1.0
0.26
10/09/23 09:21
1,2,4-Trichlorobenzene
ug/L
<0.64
1.0
0.64
10/09/23 09:21
1,2-Dibromo-3-chloropropane
ug/L
<0.34
2.0
0.34
10/09/23 09:21
1,2-Dibromoethane (EDB)
ug/L
<0.27
1.0
0.27
10/09/23 09:21
1,2-Dichlorobenzene
ug/L
<0.34
1.0
0.34
10/09/23 09:21
1,2-Dichloroethane
ug/L
<0.32
1.0
0.32
10/09/23 09:21
1,2-Dichloropropane
ug/L
<0.36
1.0
0.36
10/09/23 09:21
1,3-Dichlorobenzene
ug/L
<0.34
1.0
0.34
10/09/23 09:21
1,3-Dichloropropane
ug/L
<0.28
1.0
0.28
10/09/23 09:21
1,4-Dichlorobenzene
ug/L
<0.33
1.0
0.33
10/09/23 09:21
2,2-Dichloropropane
ug/L
<0.39
1.0
0.39
10/09/23 09:21
2-Butanone (MEK)
ug/L
<4.0
5.0
4.0
10/09/23 09:21
2-Chlorotoluene
ug/L
<0.32
1.0
0.32
10/09/23 09:21
2-Hexanone
ug/L
<0.48
5.0
0.48
10/09/23 09:21
4-Chlorotoluene
ug/L
<0.32
1.0
0.32
10/09/23 09:21
4-Methyl-2-pentanone (MIBK)
ug/L
<2.7
5.0
2.7
10/09/23 09:21
Acetone
ug/L
<5.1
25.0
5.1
10/09/23 09:21
Benzene
ug/L
<0.34
1.0
0.34
10/09/23 09:21
Bromobenzene
ug/L
<0.29
1.0
0.29
10/09/23 09:21
Bromochloromethane
ug/L
<0.47
1.0
0.47
10/09/23 09:21
Bromodichloromethane
ug/L
<0.31
1.0
0.31
10/09/23 09:21
Bromoform
ug/L
<0.34
1.0
0.34
10/09/23 09:21
Bromomethane
ug/L
<1.7
2.0
1.7
10/09/23 09:21 v2
Carbon tetrachloride
ug/L
<0.33
1.0
0.33
10/09/23 09:21
Chlorobenzene
ug/L
<0.28
1.0
0.28
10/09/23 09:21
Chloroethane
ug/L
<0.65
1.0
0.65
10/09/23 09:21
Chloroform
ug/L
<0.43
1.0
0.43
10/09/23 09:21
Chloromethane
ug/L
<0.54
1.0
0.54
10/09/23 09:21
cis-1,2-Dichloroethene
ug/L
<0.38
1.0
0.38
10/09/23 09:21
cis-1,3-Dichloropropene
ug/L
<0.36
1.0
0.36
10/09/23 09:21
Dibromochloromethane
ug/L
<0.36
1.0
0.36
10/09/23 09:21
Dibromomethane
ug/L
<0.39
1.0
0.39
10/09/23 09:21
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 101 of 229

Pace Analytical Services, LLC
(A`?a
/'L��le2225 Riverside Dr.
r Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
METHOD BLANK: 4168375 Matrix: Water
Associated Lab Samples: 92691921001, 92691921002, 92691921003, 92691921005, 92691980005
Blank Reporting
Parameter Units Result Limit MDL
Analyzed Qualifiers
Dichlorodifluoromethane
ug/L
<0.35
1.0
0.35
10/09/23 09:21
Diisopropyl ether
ug/L
<0.31
1.0
0.31
10/09/23 09:21
Ethylbenzene
ug/L
<0.30
1.0
0.30
10/09/23 09:21
Hexachloro-1,3-butadiene
ug/L
<1.5
2.0
1.5
10/09/23 09:21
m&p-Xylene
ug/L
<0.71
2.0
0.71
10/09/23 09:21
Methyl-tert-butyl ether
ug/L
<0.42
1.0
0.42
10/09/23 09:21
Methylene Chloride
ug/L
<2.0
5.0
2.0
10/09/23 09:21
Naphthalene
ug/L
<0.64
1.0
0.64
10/09/23 09:21
o-Xylene
ug/L
<0.34
1.0
0.34
10/09/23 09:21
p-Isopropyltoluene
ug/L
<0.41
1.0
0.41
10/09/23 09:21
Styrene
ug/L
<0.29
1.0
0.29
10/09/23 09:21
Tetrachloroethene
ug/L
<0.29
1.0
0.29
10/09/23 09:21
Toluene
ug/L
<0.24
1.0
0.24
10/09/23 09:21
trans-1,2-Dichloroethene
ug/L
<0.40
1.0
0.40
10/09/23 09:21
trans- 1,3-Dichloropropene
ug/L
<0.36
1.0
0.36
10/09/23 09:21
Trichloroethene
ug/L
<0.38
1.0
0.38
10/09/23 09:21
Trichlorofluoromethane
ug/L
<0.30
1.0
0.30
10/09/23 09:21
Vinyl acetate
ug/L
<1.3
2.0
1.3
10/09/23 09:21
Vinyl chloride
ug/L
<0.39
1.0
0.39
10/09/23 09:21
Xylene (Total)
ug/L
<0.34
1.0
0.34
10/09/23 09:21
1,2-Dichloroethane-d4 (S)
%
97
70-130
10/09/23 09:21
4-Bromofluorobenzene (S)
%
98
70-130
10/09/23 09:21
Toluene-d8 (S)
%
98
70-130
10/09/23 09:21
LABORATORY CONTROL SAMPLE:
4168376
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
20
20.0
100
70-130
1,1,1-Trichloroethane
ug/L
20
17.7
89
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
19.5
97
70-130
1,1,2-Trichloroethane
ug/L
20
19.1
96
70-130
1,1-Dichloroethane
ug/L
20
18.0
90
70-130
1,1-Dichloroethene
ug/L
20
18.2
91
69-131
1,1-Dichloropropene
ug/L
20
19.8
99
70-132
1,2,3-Trichlorobenzene
ug/L
20
24.0
120
70-132
1,2,3-Trichloropropane
ug/L
20
19.1
95
70-130
1,2,4-Trichlorobenzene
ug/L
20
21.4
107
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
21.1
106
70-130
1,2-Dibromoethane (EDB)
ug/L
20
19.5
98
70-130
1,2-Dichlorobenzene
ug/L
20
19.4
97
70-130
1,2-Dichloroethane
ug/L
20
18.3
91
70-130
1,2-Dichloropropane
ug/L
20
18.6
93
70-130
1,3-Dichlorobenzene
ug/L
20
19.2
96
70-130
1,3-Dichloropropane
ug/L
20
18.3
92
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 102 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
LABORATORY CONTROL SAMPLE:
Parameter
4168376
Units
Spike
Conc.
1,4-Dichlorobenzene
ug/L
20
2,2-Dichloropropane
ug/L
20
2-Butanone (MEK)
ug/L
40
2-Chlorotoluene
ug/L
20
2-Hexanone
ug/L
40
4-Chlorotoluene
ug/L
20
4-Methyl-2-pentanone (MIBK)
ug/L
40
Acetone
ug/L
40
Benzene
ug/L
20
Bromobenzene
ug/L
20
Bromochloromethane
ug/L
20
Bromodichloromethane
ug/L
20
Bromoform
ug/L
20
Bromomethane
ug/L
20
Carbon tetrachloride
ug/L
20
Chlorobenzene
ug/L
20
Chloroethane
ug/L
20
Chloroform
ug/L
20
Chloromethane
ug/L
20
cis-1,2-Dichloroethene
ug/L
20
cis-1,3-Dichloropropene
ug/L
20
Dibromochloromethane
ug/L
20
Dibromomethane
ug/L
20
Dichlorodifluoromethane
ug/L
20
Diisopropyl ether
ug/L
20
Ethylbenzene
ug/L
20
Hexachloro-1,3-butadiene
ug/L
20
m&p-Xylene
ug/L
40
Methyl-tert-butyl ether
ug/L
20
Methylene Chloride
ug/L
20
Naphthalene
ug/L
20
o-Xylene
ug/L
20
p-Isopropyltoluene
ug/L
20
Styrene
ug/L
20
Tetrachloroethene
ug/L
20
Toluene
ug/L
20
trans-1,2-Dichloroethene
ug/L
20
trans- 1,3-Dichloropropene
ug/L
20
Trichloroethene
ug/L
20
Trichlorofluoromethane
ug/L
20
Vinyl acetate
ug/L
40
Vinyl chloride
ug/L
20
Xylene (Total)
ug/L
60
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
19.1
96
70-130
19.3
97
69-130
39.9
100
67-133
19.0
95
70-130
41.3
103
70-133
18.8
94
70-130
39.6
99
70-130
38.7
97
67-130
18.4
92
70-130
19.0
95
70-130
19.5
98
70-130
18.4
92
70-130
19.8
99
70-133
16.5
83
41-148 v3
18.0
90
70-130
19.3
97
70-130
18.4
92
41-157
18.5
93
70-130
17.2
86
59-141
18.0
90
70-130
19.4
97
70-130
18.9
95
70-130
19.1
96
70-130
19.1
95
54-147
18.7
94
70-130
19.0
95
70-130
21.1
105
70-134
38.3
96
70-130
18.9
94
70-130
17.8
89
62-130
25.6
128
70-135
19.0
95
70-130
20.1
101
70-130
19.7
99
70-130
18.6
93
70-130
18.4
92
70-130
18.4
92
70-130
19.4
97
70-130
18.7
94
70-130
18.6
93
57-130
39.0
97
70-141
16.2
81
66-140
57.2
95
70-130
97
70-130
101
70-130
98
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 103 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4168377
MS
92691946003 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
4168378
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
24.9
23.6
124
118
70-146
5
30
1,1,1-Trichloroethane
ug/L
ND
20
20
24.3
22.9
122
114
70-150
6
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
24.5
23.1
123
116
66-144
6
30
1,1,2-Trichloroethane
ug/L
ND
20
20
24.2
22.9
121
115
70-142
6
30
1,1-Dichloroethane
ug/L
ND
20
20
25.3
23.4
122
112
68-150
8
30
1,1-Dichloroethene
ug/L
ND
20
20
24.6
22.9
123
114
64-162
7
30
1,1-Dichloropropene
ug/L
ND
20
20
26.0
23.8
130
119
70-160
9
30
1,2,3-Trichlorobenzene
ug/L
ND
20
20
28.1
27.1
141
135
66-151
4
30
1,2,3-Trichloropropane
ug/L
ND
20
20
23.4
22.7
117
114
66-144
3
30
1,2,4-Trichlorobenzene
ug/L
ND
20
20
25.9
24.4
129
122
69-147
6
30
1,2-Dibromo-3-
ug/L
ND
20
20
25.3
23.7
127
118
62-146
7
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
24.2
22.9
121
114
70-143
6
30
1,2-Dichlorobenzene
ug/L
ND
20
20
24.5
23.5
123
118
70-142
4
30
1,2-Dichloroethane
ug/L
ND
20
20
24.4
23.1
122
116
68-145
5
30
1,2-Dichloropropane
ug/L
ND
20
20
23.7
22.9
118
114
70-144
3
30
1,3-Dichlorobenzene
ug/L
ND
20
20
25.6
24.1
128
121
70-142
6
30
1,3-Dichloropropane
ug/L
ND
20
20
24.0
22.2
120
111
70-141
8
30
1,4-Dichlorobenzene
ug/L
ND
20
20
31.1
30.1
122
117
70-140
3
30
2,2-Dichloropropane
ug/L
ND
20
20
26.5
24.9
132
125
58-160
6
30
2-Butanone (MEK)
ug/L
ND
40
40
49.1
45.9
123
115
57-156
7
30
2-Chlorotoluene
ug/L
ND
20
20
24.8
23.4
124
117
70-148
6
30
2-Hexanone
ug/L
ND
40
40
50.8
47.3
127
118
62-153
7
30
4-Chlorotoluene
ug/L
ND
20
20
24.6
23.3
123
116
70-144
5
30
4-Methyl-2-pentanone
ug/L
ND
40
40
49.7
46.6
124
116
65-144
7
30
(MIBK)
Acetone
ug/L
ND
40
40
46.6
43.8
116
110
49-162
6
30
Benzene
ug/L
2.1
20
20
26.3
25.1
121
115
68-144
5
30
Bromobenzene
ug/L
ND
20
20
24.2
22.9
121
115
70-144
6
30
Bromochloromethane
ug/L
ND
20
20
24.4
23.4
122
117
70-148
4
30
Bromodichloromethane
ug/L
ND
20
20
23.7
21.8
119
109
70-141
8
30
Bromoform
ug/L
ND
20
20
24.5
22.6
122
113
59-144
8
30
Bromomethane
ug/L
ND
20
20
20.0
19.7
100
98
23-190
2
30 v3
Carbon tetrachloride
ug/L
ND
20
20
24.5
23.3
123
117
70-147
5
30
Chlorobenzene
ug/L
ND
20
20
29.8
28.6
122
116
70-143
4
30
Chloroethane
ug/L
ND
20
20
24.2
22.9
121
115
55-190
5
30
Chloroform
ug/L
ND
20
20
24.6
23.4
123
117
67-148
5
30
Chloromethane
ug/L
ND
20
20
22.8
21.5
114
107
38-180
6
30
cis-1,2-Dichloroethene
ug/L
ND
20
20
25.2
24.2
122
117
67-151
4
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
24.5
22.9
123
114
70-142
7
30
Dibromochloromethane
ug/L
ND
20
20
24.4
23.3
122
116
68-140
5
30
Dibromomethane
ug/L
ND
20
20
23.0
22.3
115
112
70-142
3
30
Dichlorodifluoromethane
ug/L
ND
20
20
27.2
24.7
136
124
15-200
10
30
Diisopropyl ether
ug/L
ND
20
20
24.1
22.3
120
112
62-149
7
30
Ethylbenzene
ug/L
ND
20
20
24.3
23.1
122
115
70-145
5
30
Hexachloro-1,3-butadiene
ug/L
ND
20
20
27.0
25.6
135
128
64-164
5
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 104 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4168377
4168378
MS
MSD
92691946003
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
m&p-Xylene
ug/L
ND
40
40
49.0
46.5
122
116
70-148
5
30
Methyl-tert-butyl ether
ug/L
ND
20
20
24.5
22.3
118
107
64-146
9
30
Methylene Chloride
ug/L
ND
20
20
23.2
21.6
116
108
54-149
7
30
Naphthalene
ug/L
ND
20
20
27.5
27.0
137
135
62-154
2
30
o-Xylene
ug/L
ND
20
20
24.2
22.9
121
115
70-145
5
30
p-Isopropyltoluene
ug/L
ND
20
20
26.4
25.2
132
126
70-153
5
30
Styrene
ug/L
ND
20
20
24.8
23.2
124
116
70-147
6
30
Tetrachloroethene
ug/L
ND
20
20
24.1
22.8
121
114
70-145
6
30
Toluene
ug/L
ND
20
20
23.9
22.5
120
113
65-146
6
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
24.2
22.9
121
114
69-155
6
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
24.3
22.9
122
115
70-142
6
30
Trichloroethene
ug/L
ND
20
20
24.0
22.8
120
114
70-152
5
30
Trichlorofluoromethane
ug/L
ND
20
20
25.0
22.9
125
114
60-158
9
30
Vinyl acetate
ug/L
ND
40
40
51.9
48.2
130
121
56-157
7
30
Vinyl chloride
ug/L
ND
20
20
22.5
20.9
109
101
51-178
7
30
Xylene (Total)
ug/L
ND
60
60
73.1
69.4
122
116
70-146
5
30
1,2-Dichloroethane-d4 (S)
%
97
97
70-130
4-Bromofluorobenzene (S)
%
100
99
70-130
Toluene-d8 (S)
%
98
99
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 105 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 804927 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92691921004
METHOD BLANK: 4168379
Associated Lab Samples: 92691921004
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
<0.31
1.0
0.31
10/09/23 09:40
1,1,1-Trichloroethane
ug/L
<0.33
1.0
0.33
10/09/23 09:40
1,1,2,2-Tetrachloroethane
ug/L
<0.22
1.0
0.22
10/09/23 09:40
1,1,2-Trichloroethane
ug/L
<0.32
1.0
0.32
10/09/23 09:40
1,1-Dichloroethane
ug/L
<0.37
1.0
0.37
10/09/23 09:40
1,1-Dichloroethene
ug/L
<0.35
1.0
0.35
10/09/23 09:40
1,1-Dichloropropene
ug/L
<0.43
1.0
0.43
10/09/23 09:40
1,2,3-Trichlorobenzene
ug/L
<0.81
1.0
0.81
10/09/23 09:40
1,2,3-Trichloropropane
ug/L
<0.26
1.0
0.26
10/09/23 09:40
1,2,4-Trichlorobenzene
ug/L
<0.64
1.0
0.64
10/09/23 09:40
1,2-Dibromo-3-chloropropane
ug/L
<0.34
2.0
0.34
10/09/23 09:40
1,2-Dibromoethane (EDB)
ug/L
<0.27
1.0
0.27
10/09/23 09:40
1,2-Dichlorobenzene
ug/L
<0.34
1.0
0.34
10/09/23 09:40
1,2-Dichloroethane
ug/L
<0.32
1.0
0.32
10/09/23 09:40
1,2-Dichloropropane
ug/L
<0.36
1.0
0.36
10/09/23 09:40
1,3-Dichlorobenzene
ug/L
<0.34
1.0
0.34
10/09/23 09:40
1,3-Dichloropropane
ug/L
<0.28
1.0
0.28
10/09/23 09:40
1,4-Dichlorobenzene
ug/L
<0.33
1.0
0.33
10/09/23 09:40
2,2-Dichloropropane
ug/L
<0.39
1.0
0.39
10/09/23 09:40
2-Butanone (MEK)
ug/L
<4.0
5.0
4.0
10/09/23 09:40
2-Chlorotoluene
ug/L
<0.32
1.0
0.32
10/09/23 09:40
2-Hexanone
ug/L
<0.48
5.0
0.48
10/09/23 09:40
4-Chlorotoluene
ug/L
<0.32
1.0
0.32
10/09/23 09:40
4-Methyl-2-pentanone (MIBK)
ug/L
<2.7
5.0
2.7
10/09/23 09:40
Acetone
ug/L
<5.1
25.0
5.1
10/09/23 09:40
Benzene
ug/L
<0.34
1.0
0.34
10/09/23 09:40
Bromobenzene
ug/L
<0.29
1.0
0.29
10/09/23 09:40
Bromochloromethane
ug/L
<0.47
1.0
0.47
10/09/23 09:40
Bromodichloromethane
ug/L
<0.31
1.0
0.31
10/09/23 09:40
Bromoform
ug/L
<0.34
1.0
0.34
10/09/23 09:40
Bromomethane
ug/L
<1.7
2.0
1.7
10/09/23 09:40 v2
Carbon tetrachloride
ug/L
<0.33
1.0
0.33
10/09/23 09:40
Chlorobenzene
ug/L
<0.28
1.0
0.28
10/09/23 09:40
Chloroethane
ug/L
<0.65
1.0
0.65
10/09/23 09:40
Chloroform
ug/L
<0.43
1.0
0.43
10/09/23 09:40
Chloromethane
ug/L
<0.54
1.0
0.54
10/09/23 09:40
cis-1,2-Dichloroethene
ug/L
<0.38
1.0
0.38
10/09/23 09:40
cis-1,3-Dichloropropene
ug/L
<0.36
1.0
0.36
10/09/23 09:40
Dibromochloromethane
ug/L
<0.36
1.0
0.36
10/09/23 09:40
Dibromomethane
ug/L
<0.39
1.0
0.39
10/09/23 09:40
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 106 of 229

Pace Analytical Services, LLC
(A`?a
/'L��le2225 Riverside Dr.
r Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
METHOD BLANK: 4168379
Associated Lab Samples: 92691921004
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
Dichlorodifluoromethane
ug/L
<0.35
1.0
0.35
10/09/23 09:40
Diisopropyl ether
ug/L
<0.31
1.0
0.31
10/09/23 09:40
Ethylbenzene
ug/L
<0.30
1.0
0.30
10/09/23 09:40
Hexachloro-1,3-butadiene
ug/L
<1.5
2.0
1.5
10/09/23 09:40
m&p-Xylene
ug/L
<0.71
2.0
0.71
10/09/23 09:40
Methyl-tert-butyl ether
ug/L
<0.42
1.0
0.42
10/09/23 09:40
Methylene Chloride
ug/L
<2.0
5.0
2.0
10/09/23 09:40
Naphthalene
ug/L
<0.64
1.0
0.64
10/09/23 09:40
o-Xylene
ug/L
<0.34
1.0
0.34
10/09/23 09:40
p-Isopropyltoluene
ug/L
<0.41
1.0
0.41
10/09/23 09:40
Styrene
ug/L
<0.29
1.0
0.29
10/09/23 09:40
Tetrachloroethene
ug/L
<0.29
1.0
0.29
10/09/23 09:40
Toluene
ug/L
<0.24
1.0
0.24
10/09/23 09:40
trans-1,2-Dichloroethene
ug/L
<0.40
1.0
0.40
10/09/23 09:40
trans- 1,3-Dichloropropene
ug/L
<0.36
1.0
0.36
10/09/23 09:40
Trichloroethene
ug/L
<0.38
1.0
0.38
10/09/23 09:40
Trichlorofluoromethane
ug/L
<0.30
1.0
0.30
10/09/23 09:40
Vinyl acetate
ug/L
<1.3
2.0
1.3
10/09/23 09:40
Vinyl chloride
ug/L
<0.39
1.0
0.39
10/09/23 09:40
Xylene (Total)
ug/L
<0.34
1.0
0.34
10/09/23 09:40
1,2-Dichloroethane-d4 (S)
%
97
70-130
10/09/23 09:40
4-Bromofluorobenzene (S)
%
97
70-130
10/09/23 09:40
Toluene-d8 (S)
%
98
70-130
10/09/23 09:40
LABORATORY CONTROL SAMPLE:
4168380
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
20
20.5
102
70-130
1,1,1-Trichloroethane
ug/L
20
18.3
92
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
19.7
99
70-130
1,1,2-Trichloroethane
ug/L
20
18.8
94
70-130
1,1-Dichloroethane
ug/L
20
18.3
92
70-130
1,1-Dichloroethene
ug/L
20
18.7
94
69-131
1,1-Dichloropropene
ug/L
20
19.9
99
70-132
1,2,3-Trichlorobenzene
ug/L
20
21.8
109
70-132
1,2,3-Trichloropropane
ug/L
20
19.1
95
70-130
1,2,4-Trichlorobenzene
ug/L
20
20.4
102
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
19.7
99
70-130
1,2-Dibromoethane (EDB)
ug/L
20
20.3
101
70-130
1,2-Dichlorobenzene
ug/L
20
19.8
99
70-130
1,2-Dichloroethane
ug/L
20
17.9
90
70-130
1,2-Dichloropropane
ug/L
20
18.5
93
70-130
1,3-Dichlorobenzene
ug/L
20
20.0
100
70-130
1,3-Dichloropropane
ug/L
20
19.2
96
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 107 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
LABORATORY CONTROL SAMPLE:
Parameter
4168380
Units
Spike
Conc.
1,4-Dichlorobenzene
ug/L
20
2,2-Dichloropropane
ug/L
20
2-Butanone (MEK)
ug/L
40
2-Chlorotoluene
ug/L
20
2-Hexanone
ug/L
40
4-Chlorotoluene
ug/L
20
4-Methyl-2-pentanone (MIBK)
ug/L
40
Acetone
ug/L
40
Benzene
ug/L
20
Bromobenzene
ug/L
20
Bromochloromethane
ug/L
20
Bromodichloromethane
ug/L
20
Bromoform
ug/L
20
Bromomethane
ug/L
20
Carbon tetrachloride
ug/L
20
Chlorobenzene
ug/L
20
Chloroethane
ug/L
20
Chloroform
ug/L
20
Chloromethane
ug/L
20
cis-1,2-Dichloroethene
ug/L
20
cis-1,3-Dichloropropene
ug/L
20
Dibromochloromethane
ug/L
20
Dibromomethane
ug/L
20
Dichlorodifluoromethane
ug/L
20
Diisopropyl ether
ug/L
20
Ethylbenzene
ug/L
20
Hexachloro-1,3-butadiene
ug/L
20
m&p-Xylene
ug/L
40
Methyl-tert-butyl ether
ug/L
20
Methylene Chloride
ug/L
20
Naphthalene
ug/L
20
o-Xylene
ug/L
20
p-Isopropyltoluene
ug/L
20
Styrene
ug/L
20
Tetrachloroethene
ug/L
20
Toluene
ug/L
20
trans-1,2-Dichloroethene
ug/L
20
trans- 1,3-Dichloropropene
ug/L
20
Trichloroethene
ug/L
20
Trichlorofluoromethane
ug/L
20
Vinyl acetate
ug/L
40
Vinyl chloride
ug/L
20
Xylene (Total)
ug/L
60
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
20.1
100
70-130
19.8
99
69-130
38.3
96
67-133
20.0
100
70-130
41.1
103
70-133
19.6
98
70-130
39.1
98
70-130
36.4
91
67-130
19.2
96
70-130
19.3
97
70-130
19.2
96
70-130
18.8
94
70-130
20.4
102
70-133
17.3
87
41-148 v3
19.4
97
70-130
19.9
100
70-130
18.6
93
41-157
18.5
92
70-130
17.4
87
59-141
18.5
92
70-130
20.0
100
70-130
20.2
101
70-130
19.5
97
70-130
20.0
100
54-147
18.7
94
70-130
19.9
99
70-130
21.7
108
70-134
39.8
100
70-130
18.0
90
70-130
18.3
91
62-130
23.2
116
70-135
19.6
98
70-130
21.1
105
70-130
20.3
102
70-130
19.2
96
70-130
19.1
95
70-130
19.2
96
70-130
19.6
98
70-130
19.6
98
70-130
18.8
94
57-130
40.7
102
70-141
16.6
83
66-140
59.4
99
70-130
91
70-130
101
70-130
98
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 108 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4168381
MS
92691946007 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
4168382
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
22.0
23.7
110
118
70-146
7
30
1,1,1-Trichloroethane
ug/L
ND
20
20
21.1
22.2
105
111
70-150
5
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
21.2
23.7
106
119
66-144
11
30
1,1,2-Trichloroethane
ug/L
ND
20
20
20.8
23.4
104
117
70-142
12
30
1,1-Dichloroethane
ug/L
ND
20
20
21.4
22.9
107
115
68-150
7
30
1,1-Dichloroethene
ug/L
ND
20
20
21.4
23.4
107
117
64-162
9
30
1,1-Dichloropropene
ug/L
ND
20
20
22.4
24.2
112
121
70-160
8
30
1,2,3-Trichlorobenzene
ug/L
ND
20
20
26.6
27.4
133
137
66-151
3
30
1,2,3-Trichloropropane
ug/L
ND
20
20
20.5
22.5
103
112
66-144
9
30
1,2,4-Trichlorobenzene
ug/L
ND
20
20
22.6
24.8
113
124
69-147
9
30
1,2-Dibromo-3-
ug/L
ND
20
20
22.2
24.6
111
123
62-146
10
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
21.3
23.8
107
119
70-143
11
30
1,2-Dichlorobenzene
ug/L
ND
20
20
21.0
23.9
105
120
70-142
13
30
1,2-Dichloroethane
ug/L
ND
20
20
21.3
23.2
106
116
68-145
9
30
1,2-Dichloropropane
ug/L
ND
20
20
20.3
23.0
101
115
70-144
12
30
1,3-Dichlorobenzene
ug/L
ND
20
20
21.3
24.0
107
120
70-142
12
30
1,3-Dichloropropane
ug/L
ND
20
20
20.2
23.0
101
115
70-141
13
30
1,4-Dichlorobenzene
ug/L
ND
20
20
24.9
27.7
106
120
70-140
11
30
2,2-Dichloropropane
ug/L
ND
20
20
22.4
23.8
112
119
58-160
6
30
2-Butanone (MEK)
ug/L
ND
40
40
44.3
48.0
111
120
57-156
8
30
2-Chlorotoluene
ug/L
ND
20
20
21.0
23.5
105
117
70-148
11
30
2-Hexanone
ug/L
ND
40
40
44.1
48.7
110
122
62-153
10
30
4-Chlorotoluene
ug/L
ND
20
20
21.0
23.1
105
116
70-144
10
30
4-Methyl-2-pentanone
ug/L
ND
40
40
41.9
46.5
105
116
65-144
10
30
(MIBK)
Acetone
ug/L
ND
40
40
40.5
43.1
101
108
49-162
6
30
Benzene
ug/L
2.4
20
20
23.2
25.1
104
114
68-144
8
30
Bromobenzene
ug/L
ND
20
20
20.5
23.3
103
116
70-144
13
30
Bromochloromethane
ug/L
ND
20
20
21.4
23.7
107
119
70-148
10
30
Bromodichloromethane
ug/L
ND
20
20
21.4
22.9
107
114
70-141
7
30
Bromoform
ug/L
ND
20
20
22.2
23.8
111
119
59-144
7
30
Bromomethane
ug/L
ND
20
20
18.9
20.7
94
103
23-190
9
30 v3
Carbon tetrachloride
ug/L
ND
20
20
21.8
23.6
109
118
70-147
8
30
Chlorobenzene
ug/L
ND
20
20
24.0
26.5
105
117
70-143
10
30
Chloroethane
ug/L
ND
20
20
22.4
22.9
112
115
55-190
2
30
Chloroform
ug/L
ND
20
20
21.4
23.8
107
119
67-148
11
30
Chloromethane
ug/L
ND
20
20
19.9
21.3
100
107
38-180
7
30
cis-1,2-Dichloroethene
ug/L
ND
20
20
22.2
23.6
106
114
67-151
6
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
20.9
22.9
104
114
70-142
9
30
Dibromochloromethane
ug/L
ND
20
20
21.0
24.0
105
120
68-140
13
30
Dibromomethane
ug/L
ND
20
20
20.1
22.9
100
114
70-142
13
30
Dichlorodifluoromethane
ug/L
ND
20
20
21.8
23.9
109
119
15-200
9
30
Diisopropyl ether
ug/L
ND
20
20
20.5
22.7
103
114
62-149
10
30
Ethylbenzene
ug/L
ND
20
20
20.7
22.8
104
114
70-145
10
30
Hexachloro-1,3-butadiene
ug/L
ND
20
20
23.1
25.8
115
129
64-164
11
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 109 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4168381
4168382
MS
MSD
92691946007
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
m&p-Xylene
ug/L
ND
40
40
41.1
46.1
103
115
70-148
11
30
Methyl-tert-butyl ether
ug/L
ND
20
20
20.5
22.8
102
114
64-146
11
30
Methylene Chloride
ug/L
ND
20
20
20.0
22.2
100
111
54-149
10
30
Naphthalene
ug/L
ND
20
20
26.6
27.5
133
137
62-154
3
30
o-Xylene
ug/L
ND
20
20
20.3
22.8
102
114
70-145
11
30
p-Isopropyltoluene
ug/L
ND
20
20
21.6
24.6
108
123
70-153
13
30
Styrene
ug/L
ND
20
20
21.2
23.8
106
119
70-147
12
30
Tetrachloroethene
ug/L
ND
20
20
20.6
23.2
103
116
70-145
12
30
Toluene
ug/L
ND
20
20
20.1
22.5
100
113
65-146
11
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
20.5
22.6
102
113
69-155
10
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
21.2
23.7
106
119
70-142
11
30
Trichloroethene
ug/L
ND
20
20
21.0
22.5
105
112
70-152
7
30
Trichlorofluoromethane
ug/L
ND
20
20
21.4
23.1
107
116
60-158
8
30
Vinyl acetate
ug/L
ND
40
40
44.9
49.4
112
124
56-157
10
30
Vinyl chloride
ug/L
ND
20
20
18.8
20.5
94
103
51-178
9
30
Xylene (Total)
ug/L
ND
60
60
61.5
68.9
102
115
70-146
11
30
1,2-Dichloroethane-d4 (S)
%
103
98
70-130
4-Bromofluorobenzene (S)
%
98
99
70-130
Toluene-d8 (S)
%
97
98
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 110 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 805293 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92691980002, 92691980003, 92691980004
METHOD BLANK: 4170055 Matrix:
Associated Lab Samples: 92691980002, 92691980003, 92691980004
Blank
Parameter Units Result
Water
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
<0.31
1.0
0.31
10/11/23 00:25
1,1,1-Trichloroethane
ug/L
<0.33
1.0
0.33
10/11/23 00:25
1,1,2,2-Tetrachloroethane
ug/L
<0.22
1.0
0.22
10/11/23 00:25
1,1,2-Trichloroethane
ug/L
<0.32
1.0
0.32
10/11/23 00:25
1,1-Dichloroethane
ug/L
<0.37
1.0
0.37
10/11/23 00:25
1,1-Dichloroethene
ug/L
<0.35
1.0
0.35
10/11/23 00:25
1,1-Dichloropropene
ug/L
<0.43
1.0
0.43
10/11/23 00:25
1,2,3-Trichlorobenzene
ug/L
<0.81
1.0
0.81
10/11/23 00:25
1,2,3-Trichloropropane
ug/L
<0.26
1.0
0.26
10/11/23 00:25
1,2,4-Trichlorobenzene
ug/L
<0.64
1.0
0.64
10/11/23 00:25
1,2-Dibromo-3-chloropropane
ug/L
<0.34
2.0
0.34
10/11/23 00:25
1,2-Dibromoethane (EDB)
ug/L
<0.27
1.0
0.27
10/11/23 00:25
1,2-Dichlorobenzene
ug/L
<0.34
1.0
0.34
10/11/23 00:25
1,2-Dichloroethane
ug/L
<0.32
1.0
0.32
10/11/23 00:25
1,2-Dichloropropane
ug/L
<0.36
1.0
0.36
10/11/23 00:25
1,3-Dichlorobenzene
ug/L
<0.34
1.0
0.34
10/11/23 00:25
1,3-Dichloropropane
ug/L
<0.28
1.0
0.28
10/11/23 00:25
1,4-Dichlorobenzene
ug/L
<0.33
1.0
0.33
10/11/23 00:25
2,2-Dichloropropane
ug/L
<0.39
1.0
0.39
10/11/23 00:25
2-Butanone (MEK)
ug/L
<4.0
5.0
4.0
10/11/23 00:25
2-Chlorotoluene
ug/L
<0.32
1.0
0.32
10/11/23 00:25
2-Hexanone
ug/L
<0.48
5.0
0.48
10/11/23 00:25
4-Chlorotoluene
ug/L
<0.32
1.0
0.32
10/11/23 00:25
4-Methyl-2-pentanone (MIBK)
ug/L
<2.7
5.0
2.7
10/11/23 00:25
Acetone
ug/L
<5.1
25.0
5.1
10/11/23 00:25
Benzene
ug/L
<0.34
1.0
0.34
10/11/23 00:25
Bromobenzene
ug/L
<0.29
1.0
0.29
10/11/23 00:25
Bromochloromethane
ug/L
<0.47
1.0
0.47
10/11/23 00:25
Bromodichloromethane
ug/L
<0.31
1.0
0.31
10/11/23 00:25
Bromoform
ug/L
<0.34
1.0
0.34
10/11/23 00:25
Bromomethane
ug/L
<1.7
2.0
1.7
10/11/23 00:25
Carbon tetrachloride
ug/L
<0.33
1.0
0.33
10/11/23 00:25
Chlorobenzene
ug/L
<0.28
1.0
0.28
10/11/23 00:25
Chloroethane
ug/L
<0.65
1.0
0.65
10/11/23 00:25
Chloroform
ug/L
<0.43
1.0
0.43
10/11/23 00:25
Chloromethane
ug/L
<0.54
1.0
0.54
10/11/23 00:25
cis-1,2-Dichloroethene
ug/L
<0.38
1.0
0.38
10/11/23 00:25
cis-1,3-Dichloropropene
ug/L
<0.36
1.0
0.36
10/11/23 00:25
Dibromochloromethane
ug/L
<0.36
1.0
0.36
10/11/23 00:25
Dibromomethane
ug/L
<0.39
1.0
0.39
10/11/23 00:25
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
v2
v2
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 111 of 229

Pace Analytical Services, LLC
(A`?a
/'L��le2225 Riverside Dr.
r Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
METHOD BLANK: 4170055
Matrix:
Water
Associated Lab Samples:
92691980002, 92691980003, 92691980004
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
Dichlorodifluoromethane
ug/L
<0.35
1.0
0.35
10/11/23 00:25
Diisopropyl ether
ug/L
<0.31
1.0
0.31
10/11/23 00:25
Ethylbenzene
ug/L
<0.30
1.0
0.30
10/11/23 00:25
Hexachloro-1,3-butadiene
ug/L
<1.5
2.0
1.5
10/11/23 00:25
m&p-Xylene
ug/L
<0.71
2.0
0.71
10/11/23 00:25
Methyl-tert-butyl ether
ug/L
<0.42
1.0
0.42
10/11/23 00:25
Methylene Chloride
ug/L
<2.0
5.0
2.0
10/11/23 00:25
Naphthalene
ug/L
<0.64
1.0
0.64
10/11/23 00:25
o-Xylene
ug/L
<0.34
1.0
0.34
10/11/23 00:25
p-Isopropyltoluene
ug/L
<0.41
1.0
0.41
10/11/23 00:25
Styrene
ug/L
<0.29
1.0
0.29
10/11/23 00:25
Tetrachloroethene
ug/L
<0.29
1.0
0.29
10/11/23 00:25
Toluene
ug/L
<0.24
1.0
0.24
10/11/23 00:25
trans-1,2-Dichloroethene
ug/L
<0.40
1.0
0.40
10/11/23 00:25
trans- 1,3-Dichloropropene
ug/L
<0.36
1.0
0.36
10/11/23 00:25
Trichloroethene
ug/L
<0.38
1.0
0.38
10/11/23 00:25
Trichlorofluoromethane
ug/L
<0.30
1.0
0.30
10/11/23 00:25
Vinyl acetate
ug/L
<1.3
2.0
1.3
10/11/23 00:25 v2
Vinyl chloride
ug/L
<0.39
1.0
0.39
10/11/23 00:25
Xylene (Total)
ug/L
<0.34
1.0
0.34
10/11/23 00:25
1,2-Dichloroethane-d4 (S)
%
97
70-130
10/11/23 00:25
4-Bromofluorobenzene (S)
%
99
70-130
10/11/23 00:25
Toluene-d8 (S)
%
105
70-130
10/11/23 00:25
LABORATORY CONTROL SAMPLE:
4170056
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
20
19.3
97
70-130
1,1,1-Trichloroethane
ug/L
20
19.4
97
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
20.1
100
70-130
1,1,2-Trichloroethane
ug/L
20
20.2
101
70-130
1,1-Dichloroethane
ug/L
20
18.7
94
70-130
1,1-Dichloroethene
ug/L
20
19.7
98
69-131
1,1-Dichloropropene
ug/L
20
20.2
101
70-132
1,2,3-Trichlorobenzene
ug/L
20
19.1
96
70-132
1,2,3-Trichloropropane
ug/L
20
19.2
96
70-130
1,2,4-Trichlorobenzene
ug/L
20
18.7
93
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
18.8
94
70-130
1,2-Dibromoethane (EDB)
ug/L
20
20.2
101
70-130
1,2-Dichlorobenzene
ug/L
20
19.4
97
70-130
1,2-Dichloroethane
ug/L
20
20.5
102
70-130
1,2-Dichloropropane
ug/L
20
19.5
97
70-130
1,3-Dichlorobenzene
ug/L
20
19.2
96
70-130
1,3-Dichloropropane
ug/L
20
19.5
98
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 112 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
LABORATORY CONTROL SAMPLE:
Parameter
4170056
Units
Spike
Conc.
1,4-Dichlorobenzene
ug/L
20
2,2-Dichloropropane
ug/L
20
2-Butanone (MEK)
ug/L
40
2-Chlorotoluene
ug/L
20
2-Hexanone
ug/L
40
4-Chlorotoluene
ug/L
20
4-Methyl-2-pentanone (MIBK)
ug/L
40
Acetone
ug/L
40
Benzene
ug/L
20
Bromobenzene
ug/L
20
Bromochloromethane
ug/L
20
Bromodichloromethane
ug/L
20
Bromoform
ug/L
20
Bromomethane
ug/L
20
Carbon tetrachloride
ug/L
20
Chlorobenzene
ug/L
20
Chloroethane
ug/L
20
Chloroform
ug/L
20
Chloromethane
ug/L
20
cis-1,2-Dichloroethene
ug/L
20
cis-1,3-Dichloropropene
ug/L
20
Dibromochloromethane
ug/L
20
Dibromomethane
ug/L
20
Dichlorodifluoromethane
ug/L
20
Diisopropyl ether
ug/L
20
Ethylbenzene
ug/L
20
Hexachloro-1,3-butadiene
ug/L
20
m&p-Xylene
ug/L
40
Methyl-tert-butyl ether
ug/L
20
Methylene Chloride
ug/L
20
Naphthalene
ug/L
20
o-Xylene
ug/L
20
p-Isopropyltoluene
ug/L
20
Styrene
ug/L
20
Tetrachloroethene
ug/L
20
Toluene
ug/L
20
trans-1,2-Dichloroethene
ug/L
20
trans- 1,3-Dichloropropene
ug/L
20
Trichloroethene
ug/L
20
Trichlorofluoromethane
ug/L
20
Vinyl acetate
ug/L
40
Vinyl chloride
ug/L
20
Xylene (Total)
ug/L
60
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
19.0
95
70-130
17.3
87
69-130
33.4
84
67-133 v3
18.4
92
70-130
37.7
94
70-133
18.4
92
70-130
36.1
90
70-130
39.2
98
67-130
18.9
94
70-130
18.9
94
70-130
19.2
96
70-130
19.5
97
70-130
18.3
91
70-133
14.4
72
41-148 v3
19.1
96
70-130
19.3
96
70-130
18.6
93
41-157
19.0
95
70-130
15.5
77
59-141
18.8
94
70-130
18.8
94
70-130
19.0
95
70-130
20.0
100
70-130
22.3
111
54-147
17.7
88
70-130
19.1
95
70-130
18.5
92
70-134
37.1
93
70-130
18.3
91
70-130
19.8
99
62-130
20.1
101
70-135
18.7
93
70-130
18.8
94
70-130
18.8
94
70-130
18.2
91
70-130
18.4
92
70-130
18.8
94
70-130
18.5
93
70-130
19.9
99
70-130
20.5
103
57-130
33.3
83
70-141 v3
14.5
72
66-140
55.8
93
70-130
104
70-130
99
70-130
98
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 113 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
MATRIX SPIKE SAMPLE:
4170057
92691980002
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
<0.31
20
22.2
111
70-146
1,1,1-Trichloroethane
ug/L
<0.33
20
23.8
119
70-150
1,1,2,2-Tetrachloroethane
ug/L
<0.22
20
21.3
107
66-144
1,1,2-Trichloroethane
ug/L
<0.32
20
21.6
108
70-142
1,1-Dichloroethane
ug/L
1.2
20
23.7
112
68-150
1,1-Dichloroethene
ug/L
<0.35
20
24.4
122
64-162
1,1-Dichloropropene
ug/L
<0.43
20
24.7
124
70-160
1,2,3-Trichlorobenzene
ug/L
<0.81
20
19.7
98
66-151
1,2,3-Trichloropropane
ug/L
<0.26
20
20.9
105
66-144
1,2,4-Trichlorobenzene
ug/L
<0.64
20
20.0
99
69-147
1,2-Dibromo-3-chloropropane
ug/L
<0.34
20
19.9
100
62-146
1,2-Dibromoethane (EDB)
ug/L
<0.27
20
21.4
107
70-143
1,2-Dichlorobenzene
ug/L
<0.34
20
21.5
107
70-142
1,2-Dichloroethane
ug/L
<0.32
20
22.4
112
68-145
1,2-Dichloropropane
ug/L
<0.36
20
22.9
114
70-144
1,3-Dichlorobenzene
ug/L
<0.34
20
21.8
109
70-142
1,3-Dichloropropane
ug/L
<0.28
20
21.7
108
70-141
1,4-Dichlorobenzene
ug/L
<0.33
20
27.0
135
70-140
2,2-Dichloropropane
ug/L
<0.39
20
23.7
119
58-160
2-Butanone (MEK)
ug/L
<4.0
40
35.3
88
57-156
2-Chlorotoluene
ug/L
<0.32
20
21.4
107
70-148
2-Hexanone
ug/L
<0.48
40
39.7
99
62-153
4-Chlorotoluene
ug/L
<0.32
20
21.5
108
70-144
4-Methyl-2-pentanone (MIBK)
ug/L
<2.7
40
38.1
95
65-144
Acetone
ug/L
<5.1
40
40.4
100
49-162
Benzene
ug/L
0.36J
20
23.2
114
68-144
Bromobenzene
ug/L
<0.29
20
21.4
107
70-144
Bromochloromethane
ug/L
<0.47
20
21.5
108
70-148
Bromodichloromethane
ug/L
<0.31
20
21.6
108
70-141
Bromoform
ug/L
<0.34
20
19.4
97
59-144
Bromomethane
ug/L
<1.7
20
19.2
96
23-190 v3
Carbon tetrachloride
ug/L
<0.33
20
23.6
118
70-147
Chlorobenzene
ug/L
0.49J
20
22.7
111
70-143
Chloroethane
ug/L
<0.65
20
22.3
112
55-190
Chloroform
ug/L
<0.43
20
22.1
111
67-148
Chloromethane
ug/L
<0.54
20
18.0
90
38-180
cis-1,2-Dichloroethene
ug/L
0.98J
20
22.7
109
67-151
cis-1,3-Dichloropropene
ug/L
<0.36
20
21.6
108
70-142
Dibromochloromethane
ug/L
<0.36
20
20.7
104
68-140
Dibromomethane
ug/L
<0.39
20
21.7
109
70-142
Dichlorodifluoromethane
ug/L
<0.35
20
23.6
118
15-200
Diisopropyl ether
ug/L
<0.31
20
19.1
96
62-149
Ethylbenzene
ug/L
<0.30
20
22.1
111
70-145
Hexachloro-1,3-butadiene
ug/L
<1.5
20
21.8
109
64-164
m&p-Xylene
ug/L
<0.71
40
44.2
110
70-148
Methyl-tert-butyl ether
ug/L
<0.42
20
20.2
100
64-146
Methylene Chloride
ug/L
<2.0
20
21.9
109
54-149
Results presented on
this page are in the units indicated
by the "Units" column except where
an alternate unit is
presented to the right
of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 114 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
MATRIX SPIKE SAMPLE:
Parameter
4170057
Units
92691980002
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Naphthalene
ug/L
<0.64
20
20.1
98
62-154
o-Xylene
ug/L
<0.34
20
21.4
107
70-145
p-Isopropyltoluene
ug/L
<0.41
20
21.6
108
70-153
Styrene
ug/L
<0.29
20
21.5
107
70-147
Tetrachloroethene
ug/L
<0.29
20
22.3
110
70-145
Toluene
ug/L
<0.24
20
21.5
107
65-146
trans-1,2-Dichloroethene
ug/L
<0.40
20
22.9
115
69-155
trans- 1,3-Dichloropropene
ug/L
<0.36
20
20.8
104
70-142
Trichloroethene
ug/L
<0.38
20
23.9
119
70-152
Trichlorofluoromethane
ug/L
<0.30
20
25.0
125
60-158
Vinyl acetate
ug/L
<1.3
40
35.6
89
56-157
Vinyl chloride
ug/L
<0.39
20
17.5
87
51-178
Xylene (Total)
ug/L
<0.34
60
65.6
109
70-146
1,2-Dichloroethane-d4 (S)
%
97
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
97
70-130
SAMPLE DUPLICATE: 4170058
Parameter
Units
92691980003
Result
Dup
Result RPD
1,1,1,2-Tetrachloroethane
ug/L
<0.31
<0.31
1,1,1-Trichloroethane
ug/L
<0.33
<0.33
1,1,2,2-Tetrachloroethane
ug/L
<0.22
<0.22
1,1,2-Trichloroethane
ug/L
<0.32
<0.32
1,1-Dichloroethane
ug/L
<0.37
<0.37
1,1-Dichloroethene
ug/L
<0.35
<0.35
1,1-Dichloropropene
ug/L
<0.43
<0.43
1,2,3-Trichlorobenzene
ug/L
<0.81
<0.81
1,2,3-Trichloropropane
ug/L
<0.26
<0.26
1,2,4-Trichlorobenzene
ug/L
<0.64
<0.64
1,2-Dibromo-3-chloropropane
ug/L
<0.34
<0.34
1,2-Dibromoethane (EDB)
ug/L
<0.27
<0.27
1,2-Dichlorobenzene
ug/L
<0.34
<0.34
1,2-Dichloroethane
ug/L
<0.32
<0.32
1,2-Dichloropropane
ug/L
<0.36
<0.36
1,3-Dichlorobenzene
ug/L
<0.34
<0.34
1,3-Dichloropropane
ug/L
<0.28
<0.28
1,4-Dichlorobenzene
ug/L
<0.33
<0.33
2,2-Dichloropropane
ug/L
<0.39
<0.39
2-Butanone (MEK)
ug/L
<4.0
<4.0
2-Chlorotoluene
ug/L
<0.32
<0.32
2-Hexanone
ug/L
<0.48
<0.48
4-Chlorotoluene
ug/L
<0.32
<0.32
4-Methyl-2-pentanone (MIBK)
ug/L
<2.7
<2.7
Acetone
ug/L
<5.1
<5.1
Max
RPD Qualifiers
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 115 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
SAMPLE DUPLICATE: 4170058
Parameter
Units
92691980003
Result
Dup
Result
Benzene
ug/L
<0.34
<0.34
Bromobenzene
ug/L
<0.29
<0.29
Bromochloromethane
ug/L
<0.47
<0.47
Bromodichloromethane
ug/L
<0.31
<0.31
Bromoform
ug/L
<0.34
<0.34
Bromomethane
ug/L
<1.7
<1.7
Carbon tetrachloride
ug/L
<0.33
<0.33
Chlorobenzene
ug/L
<0.28
<0.28
Chloroethane
ug/L
<0.65
<0.65
Chloroform
ug/L
<0.43
<0.43
Chloromethane
ug/L
<0.54
<0.54
cis-1,2-Dichloroethene
ug/L
<0.38
<0.38
cis-1,3-Dichloropropene
ug/L
<0.36
<0.36
Dibromochloromethane
ug/L
<0.36
<0.36
Dibromomethane
ug/L
<0.39
<0.39
Dichlorodifluoromethane
ug/L
<0.35
<0.35
Diisopropyl ether
ug/L
<0.31
<0.31
Ethylbenzene
ug/L
<0.30
<0.30
Hexachloro-1,3-butadiene
ug/L
<1.5
<1.5
m&p-Xylene
ug/L
<0.71
<0.71
Methyl-tert-butyl ether
ug/L
<0.42
<0.42
Methylene Chloride
ug/L
<2.0
<2.0
Naphthalene
ug/L
<0.64
<0.64
o-Xylene
ug/L
<0.34
<0.34
p-Isopropyltoluene
ug/L
<0.41
<0.41
Styrene
ug/L
<0.29
<0.29
Tetrachloroethene
ug/L
<0.29
<0.29
Toluene
ug/L
<0.24
<0.24
trans-1,2-Dichloroethene
ug/L
<0.40
<0.40
trans- 1,3-Dichloropropene
ug/L
<0.36
<0.36
Trichloroethene
ug/L
<0.38
<0.38
Trichlorofluoromethane
ug/L
<0.30
<0.30
Vinyl acetate
ug/L
<1.3
<1.3
Vinyl chloride
ug/L
<0.39
<0.39
Xylene (Total)
ug/L
<0.34
<0.34
1,2-Dichloroethane-d4 (S)
%
95
95
4-Bromofluorobenzene (S)
%
99
99
Toluene-d8 (S)
%
103
107
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Max
RPD RPD Qualifiers
30
30
30
30
30
30 v2
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 116 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 805590 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92691980001, 92692397001, 92692397002, 92692397003, 92692397004
METHOD BLANK: 4171449 Matrix: Water
Associated Lab Samples: 92691980001, 92692397001, 92692397002, 92692397003, 92692397004
Blank Reporting
Parameter Units Result Limit MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
<0.31
1.0
0.31
10/11/23 14:28
1,1,1-Trichloroethane
ug/L
<0.33
1.0
0.33
10/11/23 14:28
1,1,2,2-Tetrachloroethane
ug/L
<0.22
1.0
0.22
10/11/23 14:28
1,1,2-Trichloroethane
ug/L
<0.32
1.0
0.32
10/11/23 14:28
1,1-Dichloroethane
ug/L
<0.37
1.0
0.37
10/11/23 14:28
1,1-Dichloroethene
ug/L
<0.35
1.0
0.35
10/11/23 14:28
1,1-Dichloropropene
ug/L
<0.43
1.0
0.43
10/11/23 14:28
1,2,3-Trichlorobenzene
ug/L
<0.81
1.0
0.81
10/11/23 14:28
1,2,3-Trichloropropane
ug/L
<0.26
1.0
0.26
10/11/23 14:28
1,2,4-Trichlorobenzene
ug/L
<0.64
1.0
0.64
10/11/23 14:28
1,2-Dibromo-3-chloropropane
ug/L
<0.34
2.0
0.34
10/11/23 14:28
1,2-Dibromoethane (EDB)
ug/L
<0.27
1.0
0.27
10/11/23 14:28
1,2-Dichlorobenzene
ug/L
<0.34
1.0
0.34
10/11/23 14:28
1,2-Dichloroethane
ug/L
<0.32
1.0
0.32
10/11/23 14:28
1,2-Dichloropropane
ug/L
<0.36
1.0
0.36
10/11/23 14:28
1,3-Dichlorobenzene
ug/L
<0.34
1.0
0.34
10/11/23 14:28
1,3-Dichloropropane
ug/L
<0.28
1.0
0.28
10/11/23 14:28
1,4-Dichlorobenzene
ug/L
<0.33
1.0
0.33
10/11/23 14:28
2,2-Dichloropropane
ug/L
<0.39
1.0
0.39
10/11/23 14:28
2-Butanone (MEK)
ug/L
<4.0
5.0
4.0
10/11/23 14:28
2-Chlorotoluene
ug/L
<0.32
1.0
0.32
10/11/23 14:28
2-Hexanone
ug/L
<0.48
5.0
0.48
10/11/23 14:28
4-Chlorotoluene
ug/L
<0.32
1.0
0.32
10/11/23 14:28
4-Methyl-2-pentanone (MIBK)
ug/L
<2.7
5.0
2.7
10/11/23 14:28
Acetone
ug/L
<5.1
25.0
5.1
10/11/23 14:28
Benzene
ug/L
<0.34
1.0
0.34
10/11/23 14:28
Bromobenzene
ug/L
<0.29
1.0
0.29
10/11/23 14:28
Bromochloromethane
ug/L
<0.47
1.0
0.47
10/11/23 14:28
Bromodichloromethane
ug/L
<0.31
1.0
0.31
10/11/23 14:28
Bromoform
ug/L
<0.34
1.0
0.34
10/11/23 14:28
Bromomethane
ug/L
<1.7
2.0
1.7
10/11/23 14:28
Carbon tetrachloride
ug/L
<0.33
1.0
0.33
10/11/23 14:28
Chlorobenzene
ug/L
<0.28
1.0
0.28
10/11/23 14:28
Chloroethane
ug/L
<0.65
1.0
0.65
10/11/23 14:28
Chloroform
ug/L
<0.43
1.0
0.43
10/11/23 14:28
Chloromethane
ug/L
<0.54
1.0
0.54
10/11/23 14:28
cis-1,2-Dichloroethene
ug/L
<0.38
1.0
0.38
10/11/23 14:28
cis-1,3-Dichloropropene
ug/L
<0.36
1.0
0.36
10/11/23 14:28
Dibromochloromethane
ug/L
<0.36
1.0
0.36
10/11/23 14:28
Dibromomethane
ug/L
<0.39
1.0
0.39
10/11/23 14:28
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 117 of 229

Pace Analytical Services, LLC
(A`?a
/'L��le2225 Riverside Dr.
r Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
METHOD BLANK: 4171449 Matrix: Water
Associated Lab Samples: 92691980001, 92692397001, 92692397002, 92692397003, 92692397004
Blank Reporting
Parameter Units Result Limit MDL
Analyzed Qualifiers
Dichlorodifluoromethane
ug/L
<0.35
1.0
0.35
10/11/23 14:28
Diisopropyl ether
ug/L
<0.31
1.0
0.31
10/11/23 14:28
Ethylbenzene
ug/L
<0.30
1.0
0.30
10/11/23 14:28
Hexachloro-1,3-butadiene
ug/L
<1.5
2.0
1.5
10/11/23 14:28
m&p-Xylene
ug/L
<0.71
2.0
0.71
10/11/23 14:28
Methyl-tert-butyl ether
ug/L
<0.42
1.0
0.42
10/11/23 14:28
Methylene Chloride
ug/L
<2.0
5.0
2.0
10/11/23 14:28
Naphthalene
ug/L
<0.64
1.0
0.64
10/11/23 14:28
o-Xylene
ug/L
<0.34
1.0
0.34
10/11/23 14:28
p-Isopropyltoluene
ug/L
<0.41
1.0
0.41
10/11/23 14:28
Styrene
ug/L
<0.29
1.0
0.29
10/11/23 14:28
Tetrachloroethene
ug/L
<0.29
1.0
0.29
10/11/23 14:28
Toluene
ug/L
<0.24
1.0
0.24
10/11/23 14:28
trans-1,2-Dichloroethene
ug/L
<0.40
1.0
0.40
10/11/23 14:28
trans- 1,3-Dichloropropene
ug/L
<0.36
1.0
0.36
10/11/23 14:28
Trichloroethene
ug/L
<0.38
1.0
0.38
10/11/23 14:28
Trichlorofluoromethane
ug/L
<0.30
1.0
0.30
10/11/23 14:28
Vinyl acetate
ug/L
<1.3
2.0
1.3
10/11/23 14:28
Vinyl chloride
ug/L
<0.39
1.0
0.39
10/11/23 14:28
Xylene (Total)
ug/L
<0.34
1.0
0.34
10/11/23 14:28
1,2-Dichloroethane-d4 (S)
%
101
70-130
10/11/23 14:28
4-Bromofluorobenzene (S)
%
102
70-130
10/11/23 14:28
Toluene-d8 (S)
%
101
70-130
10/11/23 14:28
LABORATORY CONTROL SAMPLE:
4171450
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
20
20.5
103
70-130
1,1,1-Trichloroethane
ug/L
20
21.5
107
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
19.5
98
70-130
1,1,2-Trichloroethane
ug/L
20
21.2
106
70-130
1,1-Dichloroethane
ug/L
20
21.4
107
70-130
1,1-Dichloroethene
ug/L
20
24.3
122
69-131
1,1-Dichloropropene
ug/L
20
22.8
114
70-132
1,2,3-Trichlorobenzene
ug/L
20
18.3
92
70-132
1,2,3-Trichloropropane
ug/L
20
20.0
100
70-130
1,2,4-Trichlorobenzene
ug/L
20
18.6
93
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
18.0
90
70-130
1,2-Dibromoethane (EDB)
ug/L
20
20.6
103
70-130
1,2-Dichlorobenzene
ug/L
20
18.9
94
70-130
1,2-Dichloroethane
ug/L
20
21.3
106
70-130
1,2-Dichloropropane
ug/L
20
22.1
110
70-130
1,3-Dichlorobenzene
ug/L
20
19.2
96
70-130
1,3-Dichloropropane
ug/L
20
19.9
99
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 118 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
LABORATORY CONTROL SAMPLE:
Parameter
4171450
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,4-Dichlorobenzene
ug/L
20
19.1
95
70-130
2,2-Dichloropropane
ug/L
20
21.4
107
69-130
2-Butanone (MEK)
ug/L
40
41.2
103
67-133
2-Chlorotoluene
ug/L
20
19.9
99
70-130
2-Hexanone
ug/L
40
38.8
97
70-133
4-Chlorotoluene
ug/L
20
19.5
97
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
40
39.0
98
70-130
Acetone
ug/L
40
46.1
115
67-130
Benzene
ug/L
20
21.1
106
70-130
Bromobenzene
ug/L
20
19.2
96
70-130
Bromochloromethane
ug/L
20
22.0
110
70-130
Bromodichloromethane
ug/L
20
20.8
104
70-130
Bromoform
ug/L
20
18.1
90
70-133
Bromomethane
ug/L
20
17.2
86
41-148
Carbon tetrachloride
ug/L
20
21.9
109
70-130
Chlorobenzene
ug/L
20
19.5
98
70-130
Chloroethane
ug/L
20
22.4
112
41-157
Chloroform
ug/L
20
21.9
110
70-130
Chloromethane
ug/L
20
18.0
90
59-141
cis-1,2-Dichloroethene
ug/L
20
21.7
108
70-130
cis-1,3-Dichloropropene
ug/L
20
21.2
106
70-130
Dibromochloromethane
ug/L
20
19.9
100
70-130
Dibromomethane
ug/L
20
20.6
103
70-130
Dichlorodifluoromethane
ug/L
20
22.8
114
54-147
Diisopropyl ether
ug/L
20
19.6
98
70-130
Ethylbenzene
ug/L
20
19.9
100
70-130
Hexachloro-1,3-butadiene
ug/L
20
18.3
91
70-134
m&p-Xylene
ug/L
40
40.3
101
70-130
Methyl-tert-butyl ether
ug/L
20
19.7
99
70-130
Methylene Chloride
ug/L
20
21.9
110
62-130
Naphthalene
ug/L
20
19.0
95
70-135
o-Xylene
ug/L
20
19.5
98
70-130
p-Isopropyltoluene
ug/L
20
19.3
97
70-130
Styrene
ug/L
20
19.9
100
70-130
Tetrachloroethene
ug/L
20
19.0
95
70-130
Toluene
ug/L
20
20.4
102
70-130
trans-1,2-Dichloroethene
ug/L
20
22.4
112
70-130
trans- 1,3-Dichloropropene
ug/L
20
21.0
105
70-130
Trichloroethene
ug/L
20
21.3
107
70-130
Trichlorofluoromethane
ug/L
20
19.3
97
57-130
Vinyl acetate
ug/L
40
41.7
104
70-141
Vinyl chloride
ug/L
20
17.6
88
66-140
Xylene (Total)
ug/L
60
59.8
100
70-130
1,2-Dichloroethane-d4 (S)
%
97
70-130
4-Bromofluorobenzene (S)
%
102
70-130
Toluene-d8 (S)
%
100
70-130
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 119 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4172164
MS
92692397001 Spike
Parameter Units Result Conc.
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1, 2,2-Tetrachloroethane
1,1, 2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2-Dibromo-3-
chloropropane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEK)
2-Chlorotoluene
2-Hexanone
4-Chlorotoluene
4-Methyl-2-pentanone
(MIBK)
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
4172165
MSD
Spike MS MSD MS MSD % Rec
Conc. Result Result % Rec % Rec Limits
ug/L
<0.31
20
20
24.2
22.8
121
114
70-146
ug/L
<0.33
20
20
24.5
23.9
123
120
70-150
ug/L
<0.22
20
20
22.8
22.1
114
111
66-144
ug/L
<0.32
20
20
23.9
23.1
120
116
70-142
ug/L
<0.37
20
20
25.6
24.5
128
123
68-150
ug/L
<0.35
20
20
26.8
26.8
134
134
64-162
ug/L
<0.43
20
20
26.6
25.9
133
129
70-160
ug/L
<0.81
20
20
20.0
19.6
100
98
66-151
ug/L
<0.26
20
20
22.4
22.0
112
110
66-144
ug/L
<0.64
20
20
20.8
20.5
104
102
69-147
ug/L
<0.34
20
20
20.7
19.7
104
99
62-146
Max
RPD RPD Qual
6 30
2 30
3 30
3 30
4 30
0 30
3 30
2 30
2 30
2 30
5 30
ug/L
<0.27
20
20
24.0
22.9
120
114
70-143
5
30
ug/L
<0.34
20
20
21.2
20.4
106
102
70-142
4
30
ug/L
<0.32
20
20
24.1
23.4
120
117
68-145
3
30
ug/L
<0.36
20
20
25.8
24.4
129
122
70-144
6
30
ug/L
<0.34
20
20
21.8
20.8
109
104
70-142
5
30
ug/L
<0.28
20
20
23.2
22.8
116
114
70-141
2
30
ug/L
<0.33
20
20
24.2
22.9
121
115
70-140
5
30
ug/L
<0.39
20
20
25.6
24.5
128
122
58-160
4
30
ug/L
<4.0
40
40
46.2
44.9
116
112
57-156
3
30
ug/L
<0.32
20
20
22.7
21.6
113
108
70-148
5
30
ug/L
<0.48
40
40
47.9
47.0
120
118
62-153
2
30
ug/L
<0.32
20
20
22.3
20.8
111
104
70-144
7
30
ug/L
<2.7
40
40
46.8
44.5
117
111
65-144
5
30
ug/L
<5.1
40
40
48.5
45.9
121
115
49-162
6
30
ug/L
<0.34
20
20
25.1
23.7
124
117
68-144
6
30
ug/L
<0.29
20
20
22.2
20.7
111
104
70-144
7
30
ug/L
<0.47
20
20
25.3
23.2
126
116
70-148
9
30
ug/L
<0.31
20
20
23.6
22.9
118
115
70-141
3
30
ug/L
<0.34
20
20
21.4
21.1
107
105
59-144
2
30
ug/L
<1.7
20
20
19.0
19.2
95
96
23-190
1
30
ug/L
<0.33
20
20
25.1
24.5
126
123
70-147
2
30
ug/L
1.4
20
20
24.0
23.4
113
110
70-143
2
30
ug/L
<0.65
20
20
25.0
23.1
125
115
55-190
8
30
ug/L
<0.43
20
20
25.7
23.7
129
118
67-148
8
30
ug/L
<0.54
20
20
19.6
19.0
98
95
38-180
3
30
ug/L
0.76J
20
20
25.6
24.6
124
119
67-151
4
30
ug/L
<0.36
20
20
24.1
22.9
120
114
70-142
5
30
ug/L
<0.36
20
20
23.4
22.6
117
113
68-140
4
30
ug/L
<0.39
20
20
23.7
22.3
119
111
70-142
6
30
ug/L
<0.35
20
20
25.1
24.0
126
120
15-200
5
30
ug/L
<0.31
20
20
23.2
22.6
116
113
62-149
3
30
ug/L
<0.30
20
20
22.7
22.3
114
111
70-145
2
30
ug/L
<1.5
20
20
22.3
21.8
112
109
64-164
2
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 120 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4172164
4172165
MS
MSD
92692397001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
m&p-Xylene
ug/L
<0.71
40
40
45.5
44.4
114
111
70-148
3
30
Methyl-tert-butyl ether
ug/L
<0.42
20
20
22.6
21.7
111
107
64-146
4
30
Methylene Chloride
ug/L
<2.0
20
20
25.0
24.3
125
122
54-149
3
30
Naphthalene
ug/L
<0.64
20
20
20.4
20.2
102
101
62-154
1
30
o-Xylene
ug/L
<0.34
20
20
22.5
22.0
112
110
70-145
2
30
p-Isopropyltoluene
ug/L
<0.41
20
20
22.6
21.8
113
109
70-153
3
30
Styrene
ug/L
<0.29
20
20
21.8
21.2
109
106
70-147
3
30
Tetrachloroethene
ug/L
<0.29
20
20
21.7
21.1
109
105
70-145
3
30
Toluene
ug/L
<0.24
20
20
23.3
22.2
116
111
65-146
5
30
trans-1,2-Dichloroethene
ug/L
<0.40
20
20
26.6
26.1
133
131
69-155
2
30
trans-1,3-Dichloropropene
ug/L
<0.36
20
20
24.2
22.9
121
114
70-142
6
30
Trichloroethene
ug/L
<0.38
20
20
24.6
23.3
123
117
70-152
5
30
Trichlorofluoromethane
ug/L
<0.30
20
20
22.4
21.0
112
105
60-158
6
30
Vinyl acetate
ug/L
<1.3
40
40
45.5
43.3
114
108
56-157
5
30
Vinyl chloride
ug/L
<0.39
20
20
20.2
19.4
101
97
51-178
4
30
Xylene (Total)
ug/L
<0.34
60
60
68.0
66.4
113
111
70-146
2
30
1,2-Dichloroethane-d4 (S)
%
98
97
70-130
4-Bromofluorobenzene (S)
%
100
101
70-130
Toluene-d8 (S)
%
100
100
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 121 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 806580 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92691921018
METHOD BLANK: 4176457
Associated Lab Samples: 92691921018
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
<0.31
1.0
0.31
10/16/23 10:25
1,1,1-Trichloroethane
ug/L
<0.33
1.0
0.33
10/16/23 10:25
1,1,2,2-Tetrachloroethane
ug/L
<0.22
1.0
0.22
10/16/23 10:25
1,1,2-Trichloroethane
ug/L
<0.32
1.0
0.32
10/16/23 10:25
1,1-Dichloroethane
ug/L
<0.37
1.0
0.37
10/16/23 10:25
1,1-Dichloroethene
ug/L
<0.35
1.0
0.35
10/16/23 10:25
1,1-Dichloropropene
ug/L
<0.43
1.0
0.43
10/16/23 10:25
1,2,3-Trichlorobenzene
ug/L
<0.81
1.0
0.81
10/16/23 10:25
1,2,3-Trichloropropane
ug/L
<0.26
1.0
0.26
10/16/23 10:25
1,2,4-Trichlorobenzene
ug/L
<0.64
1.0
0.64
10/16/23 10:25
1,2-Dibromo-3-chloropropane
ug/L
<0.34
2.0
0.34
10/16/23 10:25
1,2-Dibromoethane (EDB)
ug/L
<0.27
1.0
0.27
10/16/23 10:25
1,2-Dichlorobenzene
ug/L
<0.34
1.0
0.34
10/16/23 10:25
1,2-Dichloroethane
ug/L
<0.32
1.0
0.32
10/16/23 10:25
1,2-Dichloropropane
ug/L
<0.36
1.0
0.36
10/16/23 10:25
1,3-Dichlorobenzene
ug/L
<0.34
1.0
0.34
10/16/23 10:25
1,3-Dichloropropane
ug/L
<0.28
1.0
0.28
10/16/23 10:25
1,4-Dichlorobenzene
ug/L
<0.33
1.0
0.33
10/16/23 10:25
2,2-Dichloropropane
ug/L
<0.39
1.0
0.39
10/16/23 10:25
2-Butanone (MEK)
ug/L
<4.0
5.0
4.0
10/16/23 10:25
2-Chlorotoluene
ug/L
<0.32
1.0
0.32
10/16/23 10:25
2-Hexanone
ug/L
<0.48
5.0
0.48
10/16/23 10:25
4-Chlorotoluene
ug/L
<0.32
1.0
0.32
10/16/23 10:25
4-Methyl-2-pentanone (MIBK)
ug/L
<2.7
5.0
2.7
10/16/23 10:25
Acetone
ug/L
<5.1
25.0
5.1
10/16/23 10:25
Benzene
ug/L
<0.34
1.0
0.34
10/16/23 10:25
Bromobenzene
ug/L
<0.29
1.0
0.29
10/16/23 10:25
Bromochloromethane
ug/L
<0.47
1.0
0.47
10/16/23 10:25
Bromodichloromethane
ug/L
<0.31
1.0
0.31
10/16/23 10:25
Bromoform
ug/L
<0.34
1.0
0.34
10/16/23 10:25
Bromomethane
ug/L
<1.7
2.0
1.7
10/16/23 10:25 v2
Carbon tetrachloride
ug/L
<0.33
1.0
0.33
10/16/23 10:25
Chlorobenzene
ug/L
<0.28
1.0
0.28
10/16/23 10:25
Chloroethane
ug/L
<0.65
1.0
0.65
10/16/23 10:25
Chloroform
ug/L
<0.43
1.0
0.43
10/16/23 10:25
Chloromethane
ug/L
<0.54
1.0
0.54
10/16/23 10:25
cis-1,2-Dichloroethene
ug/L
<0.38
1.0
0.38
10/16/23 10:25
cis-1,3-Dichloropropene
ug/L
<0.36
1.0
0.36
10/16/23 10:25
Dibromochloromethane
ug/L
<0.36
1.0
0.36
10/16/23 10:25
Dibromomethane
ug/L
<0.39
1.0
0.39
10/16/23 10:25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 122 of 229

Pace Analytical Services, LLC
(A`?a
/'L��le2225 Riverside Dr.
r Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
METHOD BLANK: 4176457
Associated Lab Samples: 92691921018
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
Dichlorodifluoromethane
ug/L
<0.35
1.0
0.35
10/16/23 10:25
Diisopropyl ether
ug/L
<0.31
1.0
0.31
10/16/23 10:25
Ethylbenzene
ug/L
<0.30
1.0
0.30
10/16/23 10:25
Hexachloro-1,3-butadiene
ug/L
<1.5
2.0
1.5
10/16/23 10:25
m&p-Xylene
ug/L
<0.71
2.0
0.71
10/16/23 10:25
Methyl-tert-butyl ether
ug/L
<0.42
1.0
0.42
10/16/23 10:25
Methylene Chloride
ug/L
<2.0
5.0
2.0
10/16/23 10:25
Naphthalene
ug/L
<0.64
1.0
0.64
10/16/23 10:25
o-Xylene
ug/L
<0.34
1.0
0.34
10/16/23 10:25
p-Isopropyltoluene
ug/L
<0.41
1.0
0.41
10/16/23 10:25
Styrene
ug/L
<0.29
1.0
0.29
10/16/23 10:25
Tetrachloroethene
ug/L
<0.29
1.0
0.29
10/16/23 10:25
Toluene
ug/L
<0.24
1.0
0.24
10/16/23 10:25
trans-1,2-Dichloroethene
ug/L
<0.40
1.0
0.40
10/16/23 10:25
trans- 1,3-Dichloropropene
ug/L
<0.36
1.0
0.36
10/16/23 10:25
Trichloroethene
ug/L
<0.38
1.0
0.38
10/16/23 10:25
Trichlorofluoromethane
ug/L
<0.30
1.0
0.30
10/16/23 10:25
Vinyl acetate
ug/L
<1.3
2.0
1.3
10/16/23 10:25
Vinyl chloride
ug/L
<0.39
1.0
0.39
10/16/23 10:25
Xylene (Total)
ug/L
<0.34
1.0
0.34
10/16/23 10:25
1,2-Dichloroethane-d4 (S)
%
108
70-130
10/16/23 10:25
4-Bromofluorobenzene (S)
%
98
70-130
10/16/23 10:25
Toluene-d8 (S)
%
101
70-130
10/16/23 10:25
LABORATORY CONTROL SAMPLE:
4176458
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
20
20.2
101
70-130
1,1,1-Trichloroethane
ug/L
20
21.7
108
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
18.7
94
70-130
1,1,2-Trichloroethane
ug/L
20
20.6
103
70-130
1,1-Dichloroethane
ug/L
20
19.9
99
70-130
1,1-Dichloroethene
ug/L
20
21.1
105
69-131
1,1-Dichloropropene
ug/L
20
21.0
105
70-132
1,2,3-Trichlorobenzene
ug/L
20
20.4
102
70-132
1,2,3-Trichloropropane
ug/L
20
18.3
91
70-130
1,2,4-Trichlorobenzene
ug/L
20
19.6
98
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
19.9
100
70-130
1,2-Dibromoethane (EDB)
ug/L
20
20.0
100
70-130
1,2-Dichlorobenzene
ug/L
20
20.0
100
70-130
1,2-Dichloroethane
ug/L
20
21.6
108
70-130
1,2-Dichloropropane
ug/L
20
20.0
100
70-130
1,3-Dichlorobenzene
ug/L
20
19.1
95
70-130
1,3-Dichloropropane
ug/L
20
19.0
95
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 123 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
LABORATORY CONTROL SAMPLE:
Parameter
4176458
Units
Spike
Conc.
1,4-Dichlorobenzene
ug/L
20
2,2-Dichloropropane
ug/L
20
2-Butanone (MEK)
ug/L
40
2-Chlorotoluene
ug/L
20
2-Hexanone
ug/L
40
4-Chlorotoluene
ug/L
20
4-Methyl-2-pentanone (MIBK)
ug/L
40
Acetone
ug/L
40
Benzene
ug/L
20
Bromobenzene
ug/L
20
Bromochloromethane
ug/L
20
Bromodichloromethane
ug/L
20
Bromoform
ug/L
20
Bromomethane
ug/L
20
Carbon tetrachloride
ug/L
20
Chlorobenzene
ug/L
20
Chloroethane
ug/L
20
Chloroform
ug/L
20
Chloromethane
ug/L
20
cis-1,2-Dichloroethene
ug/L
20
cis-1,3-Dichloropropene
ug/L
20
Dibromochloromethane
ug/L
20
Dibromomethane
ug/L
20
Dichlorodifluoromethane
ug/L
20
Diisopropyl ether
ug/L
20
Ethylbenzene
ug/L
20
Hexachloro-1,3-butadiene
ug/L
20
m&p-Xylene
ug/L
40
Methyl-tert-butyl ether
ug/L
20
Methylene Chloride
ug/L
20
Naphthalene
ug/L
20
o-Xylene
ug/L
20
p-Isopropyltoluene
ug/L
20
Styrene
ug/L
20
Tetrachloroethene
ug/L
20
Toluene
ug/L
20
trans-1,2-Dichloroethene
ug/L
20
trans- 1,3-Dichloropropene
ug/L
20
Trichloroethene
ug/L
20
Trichlorofluoromethane
ug/L
20
Vinyl acetate
ug/L
40
Vinyl chloride
ug/L
20
Xylene (Total)
ug/L
60
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
19.0
95
70-130
21.4
107
69-130
40.3
101
67-133
19.2
96
70-130
40.4
101
70-133
19.7
98
70-130
41.2
103
70-130
42.2
105
67-130
19.1
95
70-130
19.2
96
70-130
20.3
101
70-130
21.4
107
70-130
20.2
101
70-133
14.3
71
41-148 v3
22.3
112
70-130
19.2
96
70-130
18.9
94
41-157
20.3
101
70-130
19.2
96
59-141
20.3
102
70-130
20.0
100
70-130
19.5
97
70-130
19.9
99
70-130
26.2
131
54-147
19.9
100
70-130
19.3
97
70-130
19.5
97
70-134
39.8
100
70-130
19.2
96
70-130
20.4
102
62-130
19.5
97
70-135
19.2
96
70-130
19.4
97
70-130
19.3
96
70-130
19.2
96
70-130
19.3
97
70-130
20.5
103
70-130
21.3
106
70-130
20.5
103
70-130
21.4
107
57-130
42.1
105
70-141
17.3
86
66-140
59.0
98
70-130
106
70-130
101
70-130
103
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 124 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4176459
MS
92693117001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
4176460
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
24.5
23.3
123
117
70-146
5
30
1,1,1-Trichloroethane
ug/L
ND
20
20
24.4
21.6
122
108
70-150
12
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
22.9
21.1
114
105
66-144
8
30
1,1,2-Trichloroethane
ug/L
ND
20
20
23.3
21.4
117
107
70-142
9
30
1,1-Dichloroethane
ug/L
ND
20
20
22.9
20.4
115
102
68-150
12
30
1,1-Dichloroethene
ug/L
ND
20
20
24.3
22.1
122
110
64-162
10
30
1,1-Dichloropropene
ug/L
ND
20
20
24.0
21.9
120
110
70-160
9
30
1,2,3-Trichlorobenzene
ug/L
ND
20
20
26.7
23.6
134
118
66-151
12
30
1,2,3-Trichloropropane
ug/L
ND
20
20
22.3
20.1
112
101
66-144
10
30
1,2,4-Trichlorobenzene
ug/L
ND
20
20
27.1
24.7
135
124
69-147
9
30
1,2-Dibromo-3-
ug/L
ND
20
20
23.3
20.2
117
101
62-146
14
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
23.8
21.8
119
109
70-143
9
30
1,2-Dichlorobenzene
ug/L
ND
20
20
25.7
22.8
128
114
70-142
12
30
1,2-Dichloroethane
ug/L
ND
20
20
23.2
20.7
116
104
68-145
11
30
1,2-Dichloropropane
ug/L
ND
20
20
22.4
21.0
112
105
70-144
6
30
1,3-Dichlorobenzene
ug/L
ND
20
20
25.4
23.1
127
115
70-142
10
30
1,3-Dichloropropane
ug/L
ND
20
20
23.0
20.4
115
102
70-141
12
30
1,4-Dichlorobenzene
ug/L
ND
20
20
25.3
22.9
127
115
70-140
10
30
2,2-Dichloropropane
ug/L
ND
20
20
24.7
22.6
123
113
58-160
9
30
2-Butanone (MEK)
ug/L
ND
40
40
43.4
37.8
108
94
57-156
14
30
2-Chlorotoluene
ug/L
ND
20
20
25.2
23.0
126
115
70-148
9
30
2-Hexanone
ug/L
ND
40
40
49.0
44.9
123
112
62-153
9
30
4-Chlorotoluene
ug/L
ND
20
20
25.4
23.4
127
117
70-144
8
30
4-Methyl-2-pentanone
ug/L
ND
40
40
46.2
41.6
116
104
65-144
11
30
(MIBK)
Acetone
ug/L
ND
40
40
43.1
37.3
108
93
49-162
14
30
Benzene
ug/L
ND
20
20
22.7
20.5
113
102
68-144
10
30
Bromobenzene
ug/L
ND
20
20
24.6
22.6
123
113
70-144
8
30
Bromochloromethane
ug/L
ND
20
20
23.3
20.3
116
102
70-148
14
30
Bromodichloromethane
ug/L
ND
20
20
23.5
21.0
118
105
70-141
12
30
Bromoform
ug/L
ND
20
20
22.3
20.7
111
103
59-144
7
30
Bromomethane
ug/L
ND
20
20
18.2
16.4
91
82
23-190
11
30 v3
Carbon tetrachloride
ug/L
ND
20
20
25.2
23.6
126
118
70-147
6
30
Chlorobenzene
ug/L
ND
20
20
23.0
21.7
115
108
70-143
6
30
Chloroethane
ug/L
ND
20
20
22.5
20.6
113
103
55-190
9
30
Chloroform
ug/L
ND
20
20
23.2
21.1
116
106
67-148
10
30
Chloromethane
ug/L
ND
20
20
22.2
20.2
111
101
38-180
10
30
cis-1,2-Dichloroethene
ug/L
ND
20
20
22.6
20.6
113
103
67-151
9
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
22.4
20.5
112
103
70-142
9
30
Dibromochloromethane
ug/L
ND
20
20
23.4
20.9
117
104
68-140
12
30
Dibromomethane
ug/L
ND
20
20
23.6
21.4
118
107
70-142
10
30
Dichlorodifluoromethane
ug/L
ND
20
20
30.6
26.9
153
134
15-200
13
30
Diisopropyl ether
ug/L
ND
20
20
21.5
19.3
107
97
62-149
10
30
Ethylbenzene
ug/L
ND
20
20
23.4
21.9
117
109
70-145
7
30
Hexachloro-1,3-butadiene
ug/L
ND
20
20
29.7
27.1
149
136
64-164
9
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 125 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4176459
4176460
MS
MSD
92693117001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
m&p-Xylene
ug/L
ND
40
40
48.1
44.4
120
111
70-148
8
30
Methyl-tert-butyl ether
ug/L
ND
20
20
20.7
18.5
104
93
64-146
11
30
Methylene Chloride
ug/L
ND
20
20
22.4
20.3
112
101
54-149
10
30
Naphthalene
ug/L
ND
20
20
25.1
22.7
125
113
62-154
10
30
o-Xylene
ug/L
ND
20
20
23.2
22.0
116
110
70-145
5
30
p-Isopropyltoluene
ug/L
ND
20
20
28.2
25.6
141
128
70-153
10
30
Styrene
ug/L
ND
20
20
22.8
21.6
114
108
70-147
5
30
Tetrachloroethene
ug/L
ND
20
20
23.7
21.5
118
108
70-145
10
30
Toluene
ug/L
ND
20
20
21.9
20.8
109
104
65-146
5
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
23.3
21.1
117
105
69-155
10
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
23.4
21.6
117
108
70-142
8
30
Trichloroethene
ug/L
ND
20
20
23.5
22.1
118
110
70-152
6
30
Trichlorofluoromethane
ug/L
ND
20
20
26.1
23.3
130
117
60-158
11
30
Vinyl acetate
ug/L
ND
40
40
45.8
40.5
114
101
56-157
12
30
Vinyl chloride
ug/L
ND
20
20
20.6
18.2
103
91
51-178
12
30
Xylene (Total)
ug/L
ND
60
60
71.3
66.3
119
111
70-146
7
30
1,2-Dichloroethane-d4 (S)
%
104
101
70-130
4-Bromofluorobenzene (S)
%
98
99
70-130
Toluene-d8 (S)
%
100
97
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 126 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 806582 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92691921015
METHOD BLANK: 4176467
Associated Lab Samples: 92691921015
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
<0.31
1.0
0.31
10/16/23 10:44
1,1,1-Trichloroethane
ug/L
<0.33
1.0
0.33
10/16/23 10:44
1,1,2,2-Tetrachloroethane
ug/L
<0.22
1.0
0.22
10/16/23 10:44
1,1,2-Trichloroethane
ug/L
<0.32
1.0
0.32
10/16/23 10:44
1,1-Dichloroethane
ug/L
<0.37
1.0
0.37
10/16/23 10:44
1,1-Dichloroethene
ug/L
<0.35
1.0
0.35
10/16/23 10:44
1,1-Dichloropropene
ug/L
<0.43
1.0
0.43
10/16/23 10:44
1,2,3-Trichlorobenzene
ug/L
<0.81
1.0
0.81
10/16/23 10:44
1,2,3-Trichloropropane
ug/L
<0.26
1.0
0.26
10/16/23 10:44
1,2,4-Trichlorobenzene
ug/L
<0.64
1.0
0.64
10/16/23 10:44
1,2-Dibromo-3-chloropropane
ug/L
<0.34
2.0
0.34
10/16/23 10:44
1,2-Dibromoethane (EDB)
ug/L
<0.27
1.0
0.27
10/16/23 10:44
1,2-Dichlorobenzene
ug/L
<0.34
1.0
0.34
10/16/23 10:44
1,2-Dichloroethane
ug/L
<0.32
1.0
0.32
10/16/23 10:44
1,2-Dichloropropane
ug/L
<0.36
1.0
0.36
10/16/23 10:44
1,3-Dichlorobenzene
ug/L
<0.34
1.0
0.34
10/16/23 10:44
1,3-Dichloropropane
ug/L
<0.28
1.0
0.28
10/16/23 10:44
1,4-Dichlorobenzene
ug/L
<0.33
1.0
0.33
10/16/23 10:44
2,2-Dichloropropane
ug/L
<0.39
1.0
0.39
10/16/23 10:44
2-Butanone (MEK)
ug/L
<4.0
5.0
4.0
10/16/23 10:44
2-Chlorotoluene
ug/L
<0.32
1.0
0.32
10/16/23 10:44
2-Hexanone
ug/L
<0.48
5.0
0.48
10/16/23 10:44
4-Chlorotoluene
ug/L
<0.32
1.0
0.32
10/16/23 10:44
4-Methyl-2-pentanone (MIBK)
ug/L
<2.7
5.0
2.7
10/16/23 10:44
Acetone
ug/L
<5.1
25.0
5.1
10/16/23 10:44
Benzene
ug/L
<0.34
1.0
0.34
10/16/23 10:44
Bromobenzene
ug/L
<0.29
1.0
0.29
10/16/23 10:44
Bromochloromethane
ug/L
<0.47
1.0
0.47
10/16/23 10:44
Bromodichloromethane
ug/L
<0.31
1.0
0.31
10/16/23 10:44
Bromoform
ug/L
<0.34
1.0
0.34
10/16/23 10:44
Bromomethane
ug/L
<1.7
2.0
1.7
10/16/23 10:44 v2
Carbon tetrachloride
ug/L
<0.33
1.0
0.33
10/16/23 10:44
Chlorobenzene
ug/L
<0.28
1.0
0.28
10/16/23 10:44
Chloroethane
ug/L
<0.65
1.0
0.65
10/16/23 10:44
Chloroform
ug/L
<0.43
1.0
0.43
10/16/23 10:44
Chloromethane
ug/L
<0.54
1.0
0.54
10/16/23 10:44
cis-1,2-Dichloroethene
ug/L
<0.38
1.0
0.38
10/16/23 10:44
cis-1,3-Dichloropropene
ug/L
<0.36
1.0
0.36
10/16/23 10:44
Dibromochloromethane
ug/L
<0.36
1.0
0.36
10/16/23 10:44
Dibromomethane
ug/L
<0.39
1.0
0.39
10/16/23 10:44
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 127 of 229

Pace Analytical Services, LLC
(A`?a
/'L��le2225 Riverside Dr.
r Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
METHOD BLANK: 4176467
Associated Lab Samples: 92691921015
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
Dichlorodifluoromethane
ug/L
<0.35
1.0
0.35
10/16/23 10:44
Diisopropyl ether
ug/L
<0.31
1.0
0.31
10/16/23 10:44
Ethylbenzene
ug/L
<0.30
1.0
0.30
10/16/23 10:44
Hexachloro-1,3-butadiene
ug/L
<1.5
2.0
1.5
10/16/23 10:44
m&p-Xylene
ug/L
<0.71
2.0
0.71
10/16/23 10:44
Methyl-tert-butyl ether
ug/L
<0.42
1.0
0.42
10/16/23 10:44
Methylene Chloride
ug/L
<2.0
5.0
2.0
10/16/23 10:44
Naphthalene
ug/L
<0.64
1.0
0.64
10/16/23 10:44
o-Xylene
ug/L
<0.34
1.0
0.34
10/16/23 10:44
p-Isopropyltoluene
ug/L
<0.41
1.0
0.41
10/16/23 10:44
Styrene
ug/L
<0.29
1.0
0.29
10/16/23 10:44
Tetrachloroethene
ug/L
<0.29
1.0
0.29
10/16/23 10:44
Toluene
ug/L
<0.24
1.0
0.24
10/16/23 10:44
trans-1,2-Dichloroethene
ug/L
<0.40
1.0
0.40
10/16/23 10:44
trans- 1,3-Dichloropropene
ug/L
<0.36
1.0
0.36
10/16/23 10:44
Trichloroethene
ug/L
<0.38
1.0
0.38
10/16/23 10:44
Trichlorofluoromethane
ug/L
<0.30
1.0
0.30
10/16/23 10:44
Vinyl acetate
ug/L
<1.3
2.0
1.3
10/16/23 10:44
Vinyl chloride
ug/L
<0.39
1.0
0.39
10/16/23 10:44
Xylene (Total)
ug/L
<0.34
1.0
0.34
10/16/23 10:44
1,2-Dichloroethane-d4 (S)
%
98
70-130
10/16/23 10:44
4-Bromofluorobenzene (S)
%
102
70-130
10/16/23 10:44
Toluene-d8 (S)
%
105
70-130
10/16/23 10:44
LABORATORY CONTROL SAMPLE:
4176468
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
20
19.8
99
70-130
1,1,1-Trichloroethane
ug/L
20
18.4
92
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
20.0
100
70-130
1,1,2-Trichloroethane
ug/L
20
22.1
111
70-130
1,1-Dichloroethane
ug/L
20
20.6
103
70-130
1,1-Dichloroethene
ug/L
20
22.5
112
69-131
1,1-Dichloropropene
ug/L
20
22.1
110
70-132
1,2,3-Trichlorobenzene
ug/L
20
21.1
106
70-132
1,2,3-Trichloropropane
ug/L
20
18.9
95
70-130
1,2,4-Trichlorobenzene
ug/L
20
21.3
106
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
19.8
99
70-130
1,2-Dibromoethane (EDB)
ug/L
20
20.3
101
70-130
1,2-Dichlorobenzene
ug/L
20
19.2
96
70-130
1,2-Dichloroethane
ug/L
20
18.1
90
70-130
1,2-Dichloropropane
ug/L
20
21.1
105
70-130
1,3-Dichlorobenzene
ug/L
20
19.8
99
70-130
1,3-Dichloropropane
ug/L
20
20.0
100
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 128 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
LABORATORY CONTROL SAMPLE:
Parameter
4176468
Units
Spike
Conc.
1,4-Dichlorobenzene
ug/L
20
2,2-Dichloropropane
ug/L
20
2-Butanone (MEK)
ug/L
40
2-Chlorotoluene
ug/L
20
2-Hexanone
ug/L
40
4-Chlorotoluene
ug/L
20
4-Methyl-2-pentanone (MIBK)
ug/L
40
Acetone
ug/L
40
Benzene
ug/L
20
Bromobenzene
ug/L
20
Bromochloromethane
ug/L
20
Bromodichloromethane
ug/L
20
Bromoform
ug/L
20
Bromomethane
ug/L
20
Carbon tetrachloride
ug/L
20
Chlorobenzene
ug/L
20
Chloroethane
ug/L
20
Chloroform
ug/L
20
Chloromethane
ug/L
20
cis-1,2-Dichloroethene
ug/L
20
cis-1,3-Dichloropropene
ug/L
20
Dibromochloromethane
ug/L
20
Dibromomethane
ug/L
20
Dichlorodifluoromethane
ug/L
20
Diisopropyl ether
ug/L
20
Ethylbenzene
ug/L
20
Hexachloro-1,3-butadiene
ug/L
20
m&p-Xylene
ug/L
40
Methyl-tert-butyl ether
ug/L
20
Methylene Chloride
ug/L
20
Naphthalene
ug/L
20
o-Xylene
ug/L
20
p-Isopropyltoluene
ug/L
20
Styrene
ug/L
20
Tetrachloroethene
ug/L
20
Toluene
ug/L
20
trans-1,2-Dichloroethene
ug/L
20
trans- 1,3-Dichloropropene
ug/L
20
Trichloroethene
ug/L
20
Trichlorofluoromethane
ug/L
20
Vinyl acetate
ug/L
40
Vinyl chloride
ug/L
20
Xylene (Total)
ug/L
60
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
18.3
92
70-130
21.2
106
69-130
37.6
94
67-133
19.3
97
70-130
39.6
99
70-133
19.2
96
70-130
38.3
96
70-130
34.7
87
67-130
22.6
113
70-130
19.7
98
70-130
21.9
109
70-130
19.3
96
70-130
18.4
92
70-133
15.8
79
41-148 v3
21.6
108
70-130
19.5
97
70-130
20.4
102
41-157
17.7
89
70-130
19.8
99
59-141
19.2
96
70-130
21.0
105
70-130
19.0
95
70-130
21.4
107
70-130
26.2
131
54-147
19.2
96
70-130
19.8
99
70-130
21.3
107
70-134
39.7
99
70-130
18.9
95
70-130
19.7
98
62-130
21.2
106
70-135
19.7
99
70-130
21.3
107
70-130
21.0
105
70-130
19.7
99
70-130
20.2
101
70-130
21.3
106
70-130
21.0
105
70-130
21.6
108
70-130
18.3
92
57-130
31.3
78
70-141
18.2
91
66-140
59.5
99
70-130
89
70-130
104
70-130
101
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 129 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4176469
MS
92693218001 Spike
Parameter Units Result Conc.
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1, 2,2-Tetrachloroethane
1,1, 2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2-Dibromo-3-
chloropropane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEK)
2-Chlorotoluene
2-Hexanone
4-Chlorotoluene
4-Methyl-2-pentanone
(MIBK)
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
4176470
MSD
Spike MS MSD MS MSD % Rec
Conc. Result Result % Rec % Rec Limits
ug/L
ND
20
20
22.2
26.3
111
132
70-146
ug/L
ND
20
20
24.0
28.6
120
143
70-150
ug/L
ND
20
20
22.1
25.9
111
129
66-144
ug/L
ND
20
20
21.7
25.7
109
129
70-142
ug/L
ND
20
20
24.4
29.2
122
146
68-150
ug/L
ND
20
20
26.4
31.3
132
156
64-162
ug/L
ND
20
20
26.8
31.9
134
159
70-160
ug/L
ND
20
20
21.5
25.6
108
128
66-151
ug/L
ND
20
20
21.3
25.3
107
126
66-144
ug/L
ND
20
20
22.7
26.1
114
130
69-147
ug/L
ND
20
20
21.9
25.2
110
126
62-146
Max
RPD RPD Qual
17 30
18 30
16 30
17 30
18 30
17 30
17 30
17 30
17 30
14 30
14 30
ug/L
ND
20
20
22.4
26.6
112
133
70-143
17
30
ug/L
ND
20
20
23.0
26.8
115
134
70-142
15
30
ug/L
ND
20
20
22.6
26.8
113
134
68-145
17
30
ug/L
ND
20
20
23.8
27.7
119
138
70-144
15
30
ug/L
ND
20
20
23.4
27.7
117
138
70-142
17
30
ug/L
ND
20
20
22.2
26.5
111
133
70-141
18
30
ug/L
ND
20
20
23.1
26.7
116
133
70-140
14
30
ug/L
ND
20
20
25.8
30.4
129
152
58-160
17
30
ug/L
ND
40
40
44.6
52.8
111
132
57-156
17
30
ug/L
ND
20
20
24.5
28.5
123
143
70-148
15
30
ug/L
ND
40
40
49.2
58.2
123
146
62-153
17
30
ug/L
ND
20
20
24.7
28.7
124
143
70-144
15
30
ug/L
ND
40
40
45.1
53.5
113
134
65-144
17
30
ug/L
ND
40
40
43.1
49.9
108
125
49-162
15
30
ug/L
ND
20
20
23.6
27.5
118
138
68-144
15
30
ug/L
ND
20
20
22.9
26.7
114
134
70-144
16
30
ug/L
ND
20
20
22.8
26.6
114
133
70-148
15
30
ug/L
ND
20
20
21.7
25.8
109
129
70-141
17
30
ug/L
ND
20
20
20.0
24.4
100
122
59-144
20
30
ug/L
ND
20
20
22.8
27.3
114
137
23-190
18
30
ug/L
ND
20
20
23.8
28.3
119
141
70-147
17
30
ug/L
ND
20
20
22.7
26.6
114
133
70-143
16
30
ug/L
ND
20
20
24.9
29.4
124
147
55-190
17
30
ug/L
ND
20
20
22.8
28.0
114
140
67-148
20
30
ug/L
ND
20
20
23.7
28.3
119
141
38-180
18
30
ug/L
ND
20
20
24.2
28.2
121
141
67-151
15
30
ug/L
ND
20
20
22.6
26.6
113
133
70-142
17
30
ug/L
ND
20
20
21.5
25.6
108
128
68-140
17
30
ug/L
ND
20
20
21.0
24.5
105
123
70-142
16
30
ug/L
ND
20
20
31.7
37.6
159
188
15-200
17
30 IH,v1
ug/L
ND
20
20
23.8
28.6
119
143
62-149
18
30
ug/L
ND
20
20
23.2
27.3
116
136
70-145
16
30
ug/L
ND
20
20
24.2
28.7
121
143
64-164
17
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 130 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4176469
4176470
MS
MSD
92693218001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
m&p-Xylene
ug/L
ND
40
40
47.4
55.3
119
138
70-148
15
30
Methyl-tert-butyl ether
ug/L
ND
20
20
22.0
26.6
109
132
64-146
19
30
Methylene Chloride
ug/L
ND
20
20
23.5
28.1
117
140
54-149
18
30
Naphthalene
ug/L
ND
20
20
23.3
26.8
116
134
62-154
14
30
o-Xylene
ug/L
ND
20
20
22.9
26.9
114
135
70-145
16
30
p-Isopropyltoluene
ug/L
ND
20
20
25.9
30.2
129
151
70-153
16
30
Styrene
ug/L
ND
20
20
23.3
27.6
116
138
70-147
17
30
Tetrachloroethene
ug/L
ND
20
20
21.9
26.0
109
130
70-145
17
30
Toluene
ug/L
ND
20
20
22.4
26.1
112
130
65-146
15
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
24.1
28.9
120
144
69-155
18
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
22.4
26.5
112
133
70-142
17
30
Trichloroethene
ug/L
ND
20
20
23.4
27.2
117
136
70-152
15
30
Trichlorofluoromethane
ug/L
ND
20
20
25.5
30.1
127
151
60-158
17
30
Vinyl acetate
ug/L
ND
40
40
49.7
60.0
124
150
56-157
19
30
Vinyl chloride
ug/L
ND
20
20
22.8
27.3
114
137
51-178
18
30
Xylene (Total)
ug/L
ND
60
60
70.3
82.3
117
137
70-146
16
30
1,2-Dichloroethane-d4 (S)
%
104
106
70-130
4-Bromofluorobenzene (S)
%
102
101
70-130
Toluene-d8 (S)
%
102
101
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 131 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QC Batch: 805079 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92691921001, 92691921002, 92691921003, 92691921004, 92691980001, 92691980002, 92691980003,
92691980004
METHOD BLANK: 4169103
Matrix:
Water
Associated Lab Samples:
92691921001, 92691921002, 92691921003, 92691921004, 92691980001, 92691980002, 92691980003,
92691980004
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
<0.86
2.0
0.86 10/09/23 18:25
1,2-Dichloroethane-d4 (S)
%
85
67-130
10/09/23 18:25
Toluene-d8 (S)
%
90
70-130
10/09/23 18:25
LABORATORY CONTROL SAMPLE: 4169104
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 19.0 95 70-130
1,2-Dichloroethane-d4 (S) % 83 67-130
Toluene-d8 (S) % 89 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4169105
4169106
MS
MSD
92691921001 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L 62.7 20
20 86.4 83.5
118
104
55-137
3 30
1,2-Dichloroethane-d4 (S)
%
86
86
67-130
30
Toluene-d8 (S)
%
93
93
70-130
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 132 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 805656 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92692397001, 92692397002, 92692397003
METHOD BLANK: 4171910
Matrix:
Water
Associated Lab Samples:
92692397001, 92692397002, 92692397003
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
<0.86
2.0
0.86 10/12/23 13:34
1,2-Dichloroethane-d4 (S)
%
89
67-130
10/12/23 13:34
Toluene-d8 (S)
%
91
70-130
10/12/23 13:34
LABORATORY CONTROL SAMPLE: 4171911
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 21.2 106 70-130
1,2-Dichloroethane-d4 (S) % 88 67-130
Toluene-d8(S) % 91 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4171912
4171913
MS
MSD
92692397001 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L 13.4 20
20 32.1 32.1
94
93
55-137
0 30
1,2-Dichloroethane-d4 (S)
%
94
94
67-130
30
Toluene-d8 (S)
%
93
93
70-130
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 133 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 806628 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92691921015
METHOD BLANK: 4176796
Matrix:
Water
Associated Lab Samples: 92691921015
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
<0.86
2.0
0.86 10/16/23 13:10
1,2-Dichloroethane-d4 (S)
%
90
67-130
10/16/23 13:10
Toluene-d8 (S)
%
93
70-130
10/16/23 13:10
LABORATORY CONTROL SAMPLE: 4176797
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 20.5 103 70-130
1,2-Dichloroethane-d4 (S) % 92 67-130
Toluene-d8 (S) % 93 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4176798
4176799
MS
MSD
92693212005 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L 10.5 20
20 32.5 31.4
110
104
55-137
4 30
1,2-Dichloroethane-d4 (S)
%
90
90
67-130
30
Toluene-d8 (S)
%
93
94
70-130
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 134 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 804890 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E Water APP9 RV MSSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92691921001, 92691921002, 92691921003, 92691980001, 92691980002, 92691980003
METHOD BLANK: 4168267 Matrix: Water
Associated Lab Samples: 92691921001, 92691921002, 92691921003, 92691980001, 92691980002, 92691980003
Blank Reporting
Parameter Units Result Limit MDL Analyzed
1,2,4,5-Tetrachlorobenzene
ug/L
<4.5
10.0
4.5
10/09/23 18:09
1,3,5-Trinitrobenzene
ug/L
<5.5
10.0
5.5
10/09/23 18:09
1,3-Dinitrobenzene
ug/L
<3.8
10.0
3.8
10/09/23 18:09
1,4-Naphthoquinone
ug/L
<4.4
5.0
4.4
10/09/23 18:09
1-Naphthalenamine
ug/L
<6.0
10.0
6.0
10/09/23 18:09
2,2'-Oxybis(1-ch loropropane)
ug/L
<1.2
10.0
1.2
10/09/23 18:09
2,3,4,6-Tetrachlorophenol
ug/L
<1.5
10.0
1.5
10/09/23 18:09
2,4,5-Trichlorophenol
ug/L
<1.4
10.0
1.4
10/09/23 18:09
2,4,6-Trichlorophenol
ug/L
<1.6
10.0
1.6
10/09/23 18:09
2,4-Dichlorophenol
ug/L
<1.4
10.0
1.4
10/09/23 18:09
2,4-Dimethylphenol
ug/L
<1.7
10.0
1.7
10/09/23 18:09
2,4-Dinitrophenol
ug/L
<26.0
50.0
26.0
10/09/23 18:09
2,4-Dinitrotoluene
ug/L
<1.6
10.0
1.6
10/09/23 18:09
2,6-Dichlorophenol
ug/L
<4.2
10.0
4.2
10/09/23 18:09
2,6-Dinitrotoluene
ug/L
<1.7
10.0
1.7
10/09/23 18:09
2-Acetylaminofluorene
ug/L
<4.1
10.0
4.1
10/09/23 18:09
2-Chloronaphthalene
ug/L
<1.7
10.0
1.7
10/09/23 18:09
2-Chlorophenol
ug/L
<1.2
10.0
1.2
10/09/23 18:09
2-Methylnaphthalene
ug/L
<1.9
10.0
1.9
10/09/23 18:09
2-Methylphenol(o-Cresol)
ug/L
<1.9
10.0
1.9
10/09/23 18:09
2-Naphthalenamine
ug/L
<5.4
10.0
5.4
10/09/23 18:09
2-Nitroaniline
ug/L
<3.0
20.0
3.0
10/09/23 18:09
2-Nitrophenol
ug/L
<1.4
10.0
1.4
10/09/23 18:09
3&4-Methyl phenol (m&p Cresol)
ug/L
<1.2
10.0
1.2
10/09/23 18:09
3,3'-Dichlorobenzidine
ug/L
<8.1
20.0
8.1
10/09/23 18:09
3,3'-Dimethylbenzidine
ug/L
<31.1
50.0
31.1
10/09/23 18:09
3-Methylcholanthrene
ug/L
<3.7
10.0
3.7
10/09/23 18:09
3-Nitroaniline
ug/L
<3.8
20.0
3.8
10/09/23 18:09
4,6-Dinitro-2-methyl phenol
ug/L
<7.8
20.0
7.8
10/09/23 18:09
4-Aminobiphenyl
ug/L
<4.7
10.0
4.7
10/09/23 18:09
4-Bromophenylphenyl ether
ug/L
<1.8
10.0
1.8
10/09/23 18:09
4-ChIoro-3-methyl phenol
ug/L
<3.3
10.0
3.3
10/09/23 18:09
4-Chloroaniline
ug/L
<3.6
20.0
3.6
10/09/23 18:09
4-Chlorophenylphenyl ether
ug/L
<2.0
10.0
2.0
10/09/23 18:09
4-Nitroaniline
ug/L
<5.1
20.0
5.1
10/09/23 18:09
4-Nitrophenol
ug/L
<6.6
50.0
6.6
10/09/23 18:09
5-Nitro-o-toluidine
ug/L
<3.8
10.0
3.8
10/09/23 18:09
7,12-Dimethylbenz(a)anthracene
ug/L
<3.0
10.0
3.0
10/09/23 18:09
Acenaphthene
ug/L
<2.0
10.0
2.0
10/09/23 18:09
Acenaphthylene
ug/L
<2.0
10.0
2.0
10/09/23 18:09
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
IH
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 135 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
METHOD BLANK: 4168267 Matrix: Water
Associated Lab Samples: 92691921001, 92691921002, 92691921003, 92691980001, 92691980002, 92691980003
Blank Reporting
Parameter Units Result Limit MDL Analyzed
Acetophenone
ug/L
<1.5
10.0
1.5
10/09/23 18:09
Anthracene
ug/L
<2.3
10.0
2.3
10/09/23 18:09
Benzo(a)anthracene
ug/L
<2.7
10.0
2.7
10/09/23 18:09
Benzo(a)pyrene
ug/L
<2.8
10.0
2.8
10/09/23 18:09
Benzo(b)fluoranthene
ug/L
<2.6
10.0
2.6
10/09/23 18:09
Benzo(g,h,i)perylene
ug/L
<2.8
10.0
2.8
10/09/23 18:09
Benzo(k)fluoranthene
ug/L
<2.7
10.0
2.7
10/09/23 18:09
Benzyl alcohol
ug/L
<2.9
20.0
2.9
10/09/23 18:09
bis(2-Chloroethoxy)methane
ug/L
<1.8
10.0
1.8
10/09/23 18:09
bis(2-Chloroethyl) ether
ug/L
<1.9
10.0
1.9
10/09/23 18:09
bis(2-Ethylhexyl)phthalate
ug/L
<3.7
6.0
3.7
10/09/23 18:09
Butylbenzylphthalate
ug/L
<3.1
10.0
3.1
10/09/23 18:09
Chlorobenzilate
ug/L
<3.8
10.0
3.8
10/09/23 18:09
Chrysene
ug/L
<2.8
10.0
2.8
10/09/23 18:09
Di-n-butylphthalate
ug/L
<2.2
10.0
2.2
10/09/23 18:09
Di-n-octylphthalate
ug/L
<3.9
10.0
3.9
10/09/23 18:09
Diallate
ug/L
<3.4
10.0
3.4
10/09/23 18:09
Dibenz(a,h)anthracene
ug/L
<3.0
10.0
3.0
10/09/23 18:09
Dibenzofuran
ug/L
<2.1
10.0
2.1
10/09/23 18:09
Diethylphthalate
ug/L
<2.0
10.0
2.0
10/09/23 18:09
Dimethoate
ug/L
<3.7
10.0
3.7
10/09/23 18:09
Dimethylphthalate
ug/L
<2.1
10.0
2.1
10/09/23 18:09
Diphenylamine
ug/L
<3.0
10.0
3.0
10/09/23 18:09
Disulfoton
ug/L
<4.6
10.0
4.6
10/09/23 18:09
Ethyl methanesulfonate
ug/L
<3.0
20.0
3.0
10/09/23 18:09
Famphur
ug/L
<6.1
10.0
6.1
10/09/23 18:09
Fluoranthene
ug/L
<2.2
10.0
2.2
10/09/23 18:09
Fluorene
ug/L
<2.1
10.0
2.1
10/09/23 18:09
Hexachlorobenzene
ug/L
<2.2
10.0
2.2
10/09/23 18:09
Hexachlorocyclopentadiene
ug/L
<1.6
10.0
1.6
10/09/23 18:09
Hexachloroethane
ug/L
<1.4
10.0
1.4
10/09/23 18:09
Hexachloropropene
ug/L
<2.7
10.0
2.7
10/09/23 18:09
Indeno(1,2,3-cd)pyrene
ug/L
<2.9
10.0
2.9
10/09/23 18:09
Isodrin
ug/L
<2.8
10.0
2.8
10/09/23 18:09
Isophorone
ug/L
<1.7
10.0
1.7
10/09/23 18:09
Isosafrole
ug/L
<2.5
10.0
2.5
10/09/23 18:09
Kepone
ug/L
<14.1
20.0
14.1
10/09/23 18:09
Methapyrilene
ug/L
<17.0
50.0
17.0
10/09/23 18:09
Methyl methanesulfonate
ug/L
<3.1
5.0
3.1
10/09/23 18:09
Methyl parathion
ug/L
<3.7
10.0
3.7
10/09/23 18:09
N-Nitroso-di-n-butylamine
ug/L
<2.0
10.0
2.0
10/09/23 18:09
N-Nitroso-di-n-propylamine
ug/L
<1.3
10.0
1.3
10/09/23 18:09
N-Nitrosodiethylamine
ug/L
<2.3
10.0
2.3
10/09/23 18:09
N-Nitrosodimethylamine
ug/L
<1.9
10.0
1.9
10/09/23 18:09
N-Nitrosodiphenylamine
ug/L
<3.0
10.0
3.0
10/09/23 18:09
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
v1
v1
v1
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 136 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
METHOD BLANK: 4168267 Matrix: Water
Associated Lab Samples: 92691921001, 92691921002, 92691921003, 92691980001, 92691980002, 92691980003
Blank Reporting
Parameter Units Result Limit MDL Analyzed
N-Nitrosomethylethylamine
ug/L
<7.5
10.0
7.5
10/09/23 18:09
N-Nitrosopiperidine
ug/L
<2.5
10.0
2.5
10/09/23 18:09
N-Nitrosopyrrolidine
ug/L
<3.1
10.0
3.1
10/09/23 18:09
Nitrobenzene
ug/L
<1.9
10.0
1.9
10/09/23 18:09
O,O,O-Triethylphosphorothioate
ug/L
<2.6
10.0
2.6
10/09/23 18:09
O-Toluidine
ug/L
<2.6
10.0
2.6
10/09/23 18:09
P-Dimethylaminoazobenzene
ug/L
<2.4
5.0
2.4
10/09/23 18:09
p-Phenylenediamine
ug/L
<10.0
10.0
10.0
10/09/23 18:09
Parathion (Ethyl parathion)
ug/L
<3.9
10.0
3.9
10/09/23 18:09
Pentachlorobenzene
ug/L
<3.4
10.0
3.4
10/09/23 18:09
Pentachloronitrobenzene
ug/L
<3.3
10.0
3.3
10/09/23 18:09
Pentachlorophenol
ug/L
<3.8
20.0
3.8
10/09/23 18:09
Phenacetin
ug/L
<3.6
10.0
3.6
10/09/23 18:09
Phenanthrene
ug/L
<2.0
10.0
2.0
10/09/23 18:09
Phenol
ug/L
<1.4
10.0
1.4
10/09/23 18:09
Phorate
ug/L
<3.6
10.0
3.6
10/09/23 18:09
Pronamide
ug/L
<3.1
10.0
3.1
10/09/23 18:09
Pyrene
ug/L
<2.2
10.0
2.2
10/09/23 18:09
Safrole
ug/L
<2.3
10.0
2.3
10/09/23 18:09
Thionazin
ug/L
<2.9
10.0
2.9
10/09/23 18:09
2,4,6-Tribromophenol (S)
%
131
10-164
10/09/23 18:09
2-Fluorobiphenyl (S)
%
95
10-130
10/09/23 18:09
2-Fluorophenol (S)
%
83
10-130
10/09/23 18:09
Nitrobenzene-d5 (S)
%
116
10-138
10/09/23 18:09
Phenol-d6 (S)
%
61
10-130
10/09/23 18:09
Terphenyl-d14 (S)
%
104
19-191
10/09/23 18:09
LABORATORY CONTROL SAMPLE:
Parameter
4168268
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,2,4,5-Tetrachlorobenzene
ug/L
50
47.5
95
10-130
1,3,5-Trinitrobenzene
ug/L
50
31.1
62
55-200
1,3-Dinitrobenzene
ug/L
50
57.0
114
48-176
1,4-Naphthoquinone
ug/L
50
40.6
81
18-130
1-Naphthalenamine
ug/L
50
39.2
78
29-149
2,2'-Oxybis(1-chloropropane)
ug/L
50
36.5
73
21-135
2,3,4,6-Tetrachlorophenol
ug/L
50
52.4
105
39-157
2,4,5-Trichlorophenol
ug/L
50
56.9
114
38-147
2,4,6-Trichlorophenol
ug/L
50
53.2
106
34-142
2,4-Dichlorophenol
ug/L
50
51.1
102
36-136
2,4-Dimethylphenol
ug/L
50
49.6
99
38-134
2,4-Dinitrophenol
ug/L
250
252
101
10-169
2,4-Dinitrotoluene
ug/L
50
51.2
102
44-154
2,6-Dichlorophenol
ug/L
50
55.3
111
37-145
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Qualifiers
v1
IL
v1
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 137 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE:
Parameter
4168268
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
2,6-Dinitrotoluene
ug/L
50
54.3
109
44-156
2-Acetylaminofluorene
ug/L
50
42.2
84
25-175
2-Chloronaphthalene
ug/L
50
42.8
86
25-130
2-Chlorophenol
ug/L
50
46.8
94
29-130
2-Methylnaphthalene
ug/L
50
44.1
88
23-130
2-Methylphenol(o-Cresol)
ug/L
50
41.4
83
31-130
2-Naphthalenamine
ug/L
50
44.9
90
34-147
2-Nitroaniline
ug/L
100
104
104
39-145
2-Nitrophenol
ug/L
50
52.5
105
29-142
3&4-Methyl phenol (m&p Cresol)
ug/L
50
42.5
85
30-130
3,3'-Dichlorobenzidine
ug/L
100
113
113
44-158
3,3'-Dimethylbenzidine
ug/L
100
143
143
38-200lH
3-Methylcholanthrene
ug/L
50
53.4
107
46-153
3-Nitroaniline
ug/L
100
106
106
45-152
4,6-Dinitro-2-methyl phenol
ug/L
100
99.0
99
39-158
4-Aminobiphenyl
ug/L
50
44.4
89
30-144
4-Bromophenylphenyl ether
ug/L
50
50.3
101
47-147
4-Chloro-3-methylphenol
ug/L
100
100
100
40-138
4-Chloroaniline
ug/L
100
95.3
95
35-130
4-Chlorophenylphenyl ether
ug/L
50
51.5
103
36-139
4-Nitroaniline
ug/L
100
107
107
46-157
4-Nitrophenol
ug/L
250
134
54
17-130
5-Nitro-o-toluidine
ug/L
50
52.0
104
50-182
7,12-Dimethylbenz(a)anthracene
ug/L
50
48.4
97
46-157
Acenaphthene
ug/L
50
45.5
91
34-135
Acenaphthylene
ug/L
50
47.3
95
35-137
Acetophenone
ug/L
50
43.1
86
30-137
Anthracene
ug/L
50
46.4
93
47-146
Benzo(a)anthracene
ug/L
50
48.4
97
48-160
Benzo(a)pyrene
ug/L
50
50.0
100
47-165
Benzo(b)fluoranthene
ug/L
50
54.4
109
49-171
Benzo(g,h,i)perylene
ug/L
50
47.2
94
46-166
Benzo(k)fluoranthene
ug/L
50
50.8
102
55-162
Benzyl alcohol
ug/L
100
91.7
92
29-132
bis(2-Chloroethoxy)methane
ug/L
50
47.6
95
33-136
bis(2-Chloroethyl) ether
ug/L
50
45.3
91
30-142
bis(2-Ethylhexyl)phthalate
ug/L
50
53.8
108
46-173
Butylbenzylphthalate
ug/L
50
51.5
103
53-169
Chlorobenzilate
ug/L
50
55.7
111
43-155
Chrysene
ug/L
50
47.0
94
54-152
Di-n-butylphthalate
ug/L
50
50.0
100
49-161
Di-n-octylphthalate
ug/L
50
56.3
113
50-166
Diallate
ug/L
50
50.1
100
47-136
Dibenz(a,h)anthracene
ug/L
50
48.3
97
46-166
Dibenzofuran
ug/L
50
46.8
94
37-136
Diethylphthalate
ug/L
50
48.4
97
45-149
Dimethoate
ug/L
50
56.9
114
49-145
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 138 of 229

Pace Analytical Services, LLC
(A)`?a
/'L��le2225 Riverside Dr.
r Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
LABORATORY CONTROL SAMPLE:
Parameter
4168268
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Dimethylphthalate
ug/L
50
49.0
98
43-145
Diphenylamine
ug/L
50
47.4
95
49-142
Disulfoton
ug/L
50
48.2
96
42-130
Ethyl methanesulfonate
ug/L
50
47.2
94
26-135
Famphur
ug/L
100
74.2
74
10-130
Fluoranthene
ug/L
50
50.8
102
50-153
Fluorene
ug/L
50
48.2
96
42-142
Hexachlorobenzene
ug/L
50
48.2
96
44-138
Hexachlorocyclopentadiene
ug/L
50
44.6
89
10-130 v1
Hexachloroethane
ug/L
50
27.1
54
10-130
Hexachloropropene
ug/L
50
24.9
50
10-130 v1
Indeno(1,2,3-cd)pyrene
ug/L
50
46.5
93
46-166
Isodrin
ug/L
50
51.2
102
48-141
Isophorone
ug/L
50
50.2
100
36-135
Isosafrole
ug/L
50
45.2
90
33-135
Kepone
ug/L
100
82.7
83
10-130 v1
Methapyrilene
ug/L
50
<17.0
2
10-185 L2
Methyl methanesulfonate
ug/L
50
41.5
83
21-130
Methyl parathion
ug/L
50
59.4
119
57-173
N-Nitroso-di-n-butylamine
ug/L
50
56.4
113
28-130
N-Nitroso-di-n-propylamine
ug/L
50
51.5
103
33-140
N-Nitrosodiethylamine
ug/L
50
50.7
101
27-141
N-Nitrosodimethylamine
ug/L
50
38.6
77
24-130
N-Nitrosodiphenylamine
ug/L
50
47.4
95
46-144
N-Nitrosomethylethylamine
ug/L
50
46.9
94
22-141
N-Nitrosopiperidine
ug/L
50
51.8
104
36-141
N-Nitrosopyrrolidine
ug/L
50
49.1
98
31-145
Nitrobenzene
ug/L
50
46.6
93
33-133
O,O,O-Triethylphosphorothioate
ug/L
50
57.2
114
30-152 v1
O-Toluidine
ug/L
50
46.9
94
30-131
P-Dimethylaminoazobenzene
ug/L
50
24.3
49
23-130IL
p-Phenylenediamine
ug/L
<10.0
Parathion (Ethyl parathion)
ug/L
50
55.8
112
52-169
Pentachlorobenzene
ug/L
50
55.7
111
31-136 v1
Pentachloronitrobenzene
ug/L
50
65.1
130
59-177
Pentachlorophenol
ug/L
100
96.5
97
21-163
Phenacetin
ug/L
50
50.4
101
52-159
Phenanthrene
ug/L
50
46.6
93
47-146
Phenol
ug/L
50
29.8
60
19-130
Phorate
ug/L
50
49.1
98
35-184
Pronamide
ug/L
50
53.4
107
53-155
Pyrene
ug/L
50
48.9
98
53-155
Safrole
ug/L
50
49.1
98
31-130
Thionazin
ug/L
50
52.6
105
46-148
2,4,6-Tribromophenol (S)
%
152
10-164
2-Fluorobiphenyl (S)
%
120
10-130
2-Fluorophenol (S)
%
96
10-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 139 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 4168268
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrobenzene-d5 (S) % 133 10-138
Phenol-d6 (S) % 76 10-130
Terphenyl-d14 (S) % 113 19-191
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4168277
MS
35829241003 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
4168278
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,2,4,5-Tetrachlorobenzene
ug/L
4.51-1
50
50
31.9
42.4
64
85
12-130
28
30 H3
1,3,5-Trinitrobenzene
ug/L
5.51-1
50
50
26.0
29.3
52
59
34-200
12
30 H3
1,3-Dinitrobenzene
ug/L
3.81-1
50
50
42.8
50.5
86
101
34-183
16
30 H3
1,4-Naphthoquinone
ug/L
4.41-1
50
50
44.6
52.0
89
104
14-136
15
30 H3
1-Naphthalenamine
ug/L
6.01-1
50
50
23.9
29.7
48
59
10-173
22
30 H3
2,2'-Oxybis(1-
ug/L
1.21-1
50
50
24.0
30.6
48
61
11-143
24
30 H3
chloropropane)
2,3,4,6-Tetrachlorophenol
ug/L
1.51-1
50
50
43.6
48.9
87
98
10-180
12
30 H3
2,4,5-Trichlorophenol
ug/L
1.41-1
50
50
41.1
50.2
82
100
10-170
20
30 H3
2,4,6-Trichlorophenol
ug/L
1.6U
50
50
36.5
48.5
73
97
10-166
28
30 H3
2,4-Dichlorophenol
ug/L
1 AU
50
50
32.9
43.2
66
86
10-153
27
30 H3
2,4-Dimethylphenol
ug/L
1.7U
50
50
32.9
42.4
66
85
20-147
25
30 H3
2,4-Dinitrophenol
ug/L
26.01-1
250
250
207
244
83
98
10-172
17
30 H3
2,4-Dinitrotoluene
ug/L
1.61-1
50
50
44.2
48.2
88
96
30-164
8
30 H3
2,6-Dichlorophenol
ug/L
4.2U
50
50
35.6
45.8
71
92
10-161
25
30 H3
2,6-Dinitrotoluene
ug/L
1.7U
50
50
41.6
50.2
83
100
31-163
19
30 H3
2-Acetylam inofl uorene
ug/L
4.1U
50
50
46.8
54.0
94
108
20-166
14
30 H3
2-Chloronaphthalene
ug/L
1.7U
50
50
29.4
39.3
59
79
15-134
29
30 H3
2-Chlorophenol
ug/L
1.21-1
50
50
30.1
39.0
60
78
10-139
26
30 H3
2-Methyl naphthalene
ug/L
1.91-1
50
50
32.0
39.9
64
80
12-130
22
30 H3
2-Methyl phenol(o-Cresol)
ug/L
1.91-1
50
50
27.7
34.3
55
69
19-132
21
30 H3
2-Naphthalenamine
ug/L
5.4U
50
50
<5.4
<5.4
5
6
10-164
30 H3,M1
2-Nitroaniline
ug/L
3.OU
100
100
79.1
97.5
79
98
23-154
21
30 H3
2-Nitrophenol
ug/L
1 AU
50
50
32.8
44.0
66
88
10-159
29
30 H3
3&4-Methylphenol(m&p
ug/L
1.2U
50
50
26.9
36.5
54
73
13-136
30
30 H3
Cresol)
3,3'-Dichlorobenzidine
ug/L
8.1 U
100
100
71.9
79.0
72
79
10-178
9
30 H3
3,3'-Dimethylbenzidine
ug/L
311.111.1
100
100
<31.1
<31.1
2
3
10-200
30 H3,IH,
M1
3-Methylcholanthrene
ug/L
3.71-1
50
50
47.7
52.3
95
105
36-158
9
30 H3
3-Nitroaniline
ug/L
3.81-1
100
100
83.2
95.1
83
95
20-166
13
30 H3
4,6-Dinitro-2-methylphenol
ug/L
7.81-1
100
100
85.2
95.5
85
95
10-187
11
30 H3
4-Aminobiphenyl
ug/L
4.71-1
50
50
30.9
35.7
62
71
10-181
14
30 H3
4-Bromophenylphenyl ether
ug/L
1.81-1
50
50
37.7
45.5
75
91
31-157
19
30 H3
4-Chloro-3-methylphenol
ug/L
3.31-1
100
100
73.4
90.2
73
90
27-146
20
30 H3
4-Chloroaniline
ug/L
3.61-1
100
100
60.7
78.2
61
78
13-143
25
30 H3
4-Chlorophenylphenyl ether
ug/L
2.01-1
50
50
36.8
46.0
74
92
23-149
22
30 H3
4-Nitroaniline
ug/L
5.1U
100
100
96.4
99.7
96
100
24-171
3
30 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 140 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4168277
MS
35829241003 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
4168278
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
4-Nitrophenol
ug/L
6.6U
250
250
134
144
54
58
10-130
7
30 H3
5-Nitro-o-toluidine
ug/L
3.8U
50
50
46.3
50.1
93
100
33-192
8
30 H3
7,12-
ug/L
3.OU
50
50
43.8
46.9
88
94
36-161
7
30 H3
Dimethylbenz(a)anthracene
Acenaphthene
ug/L
2.OU
50
50
31.3
40.8
63
82
21-147
26
30 H3
Acenaphthylene
ug/L
2.OU
50
50
32.5
42.8
65
86
19-150
27
30 H3
Acetophenone
ug/L
1.5U
50
50
28.4
36.5
57
73
22-145
25
30 H3
Anthracene
ug/L
2.3U
50
50
38.5
43.0
77
86
36-152
11
30 H3
Benzo(a)anth race ne
ug/L
2.7U
50
50
44.3
47.1
89
94
42-163
6
30 H3
Benzo(a)pyrene
ug/L
2.8U
50
50
44.7
48.1
89
96
40-169
7
30 H3
Benzo(b)fluoranthene
ug/L
2.6U
50
50
49.3
52.6
99
105
40-177
7
30 H3
Benzo(g,h,i)perylene
ug/L
2.8U
50
50
42.5
44.6
85
89
38-174
5
30 H3
Benzo(k)fluoranthene
ug/L
2.7U
50
50
47.0
48.1
94
96
41-171
2
30 H3
Benzyl alcohol
ug/L
2.9U
100
100
59.8
78.5
60
79
18-141
27
30 H3
bis(2-
ug/L
1.8U
50
50
30.7
39.2
61
78
19-146
24
30 H3
Chloroethoxy)methane
bis(2-Chloroethyl) ether
ug/L
1.9U
50
50
28.7
36.7
57
73
19-151
25
30 H3
bis(2- Ethyl hexyl)phthalate
ug/L
3.7U
50
50
48.2
51.7
94
101
42-168
7
30 H3
Butylbenzylphthalate
ug/L
3.1 U
50
50
46.8
50.1
94
100
42-177
7
30 H3
Chlorobenzilate
ug/L
3.8U
50
50
50.6
54.9
101
110
36-158
8
30 H3
Chrysene
ug/L
2.8U
50
50
43.2
46.4
86
93
43-159
7
30 H3
Di-n-butylphthalate
ug/L
2.2U
50
50
44.3
46.6
89
93
42-160
5
30 H3
Di-n-octylphthalate
ug/L
3.9U
50
50
51.6
55.1
103
110
42-171
6
30 H3
Diallate
ug/L
3AU
50
50
37.8
45.4
76
91
38-139
18
30 H3
Dibenz(a,h)anthracene
ug/L
3.OU
50
50
43.0
45.4
86
91
40-171
5
30 H3
Dibenzofuran
ug/L
2.1U
50
50
32.2
42.4
64
85
23-147
27
30 H3
Diethylphthalate
ug/L
2.OU
50
50
41.3
45.7
83
91
33-157
10
30 H3
Dimethoate
ug/L
3.7U
50
50
51.2
55.8
102
112
41-146
9
30 H3
Dimethylphthalate
ug/L
2.1 U
50
50
38.7
45.8
77
92
27-154
17
30 H3
Diphenylamine
ug/L
3.OU
50
50
38.4
44.8
77
90
38-146
15
30 H3
Disulfoton
ug/L
4.6U
50
50
39.4
45.4
79
91
39-130
14
30 H3
Ethyl methanesulfonate
ug/L
3.OU
50
50
30.7
39.5
61
79
25-136
25
30 H3
Famphur
ug/L
6.1U
100
100
73.9
67.4
74
67
10-130
9
30 H3
Fluoranthene
ug/L
2.2U
50
50
45.0
48.1
90
96
42-157
7
30 H3
Fluorene
ug/L
2.1U
50
50
35.1
43.8
70
88
25-155
22
30 H3
Hexachlorobenzene
ug/L
2.2U
50
50
37.7
45.7
75
91
32-145
19
30 H3
Hexachlorocyclopentadiene
ug/L
1.6U
50
50
32.1
43.5
64
87
10-130
30
30 H3,v1
Hexachloroethane
ug/L
1 AU
50
50
22.5
27.7
45
55
10-130
21
30 H3
Hexachloropropene
ug/L
2.7U
50
50
23.6
28.5
47
57
10-130
19
30 H3,v1
Indeno(1,2,3-cd)pyrene
ug/L
2.9U
50
50
41.5
43.7
83
87
39-174
5
30 H3
Isodrin
ug/L
2.8U
50
50
42.7
48.2
85
96
34-148
12
30 H3
Isophorone
ug/L
1.7U
50
50
33.6
42.7
67
85
19-146
24
30 H3
Isosafrole
ug/L
2.5U
50
50
29.0
39.8
58
80
25-139
31
30 H3,R1
Kepone
ug/L
14.1 U
100
100
86.4
77.9
86
78
10-130
10
30 H3,v1
Methapyrilene
ug/L
17.OU
50
50
<17.0
<17.0
16
21
10-200
30 H3
Methyl methanesulfonate
ug/L
3.1 U
50
50
27.5
34.6
55
69
22-130
23
30 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 141 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4168277 4168278
Parameter Units
Methyl parathion
ug/L
N-Nitroso-di-n-butylamine
ug/L
N-Nitroso-di-n-propylamine
ug/L
N-Nitrosodiethylamine
ug/L
N-Nitrosodimethylamine
ug/L
N-Nitrosodiphenylamine
ug/L
N-Nitrosomethylethylamine
ug/L
N-Nitrosopiperidine
ug/L
N-Nitrosopyrrolidine
ug/L
Nitrobenzene
ug/L
0,0,0-
ug/L
Triethylphosphorothioate
O-Toluidine
ug/L
P-
ug/L
Dimethylaminoazobenzene
p-Phenylenediamine
ug/L
Parathion (Ethyl parathion)
ug/L
Pentachlorobenzene
ug/L
Pentachloronitrobenzene
ug/L
Pentachlorophenol
ug/L
Phenacetin
ug/L
Phenanthrene
ug/L
Phenol
ug/L
Phorate
ug/L
Pronamide
ug/L
Pyrene
ug/L
Safrole
ug/L
Thionazin
ug/L
2,4,6-Tribromophenol (S)
%
2-Fluorobiphenyl (S)
%
2-Fluorophenol (S)
%
Nitrobenzene-d5 (S)
%
Phenol-d6 (S)
%
Terphenyl-d14 (S)
%
MS
35829241003
Spike
Result
Conc.
3.7U
50
2.OU
50
1.3U
50
2.3U
50
1.9U
50
3.OU
50
7.5U
50
2.5U
50
3.1U
50
1.9U
50
2.6U
50
2.6U
50
2AU
50
10.0U
3.9U
50
3AU
50
3.3U
50
3.8U
100
3.6U
50
2.OU
50
1 AU
50
3.6U
50
3.1U
50
2.2U
50
2.3U
50
2.9U
50
MSD
Spike
Conc.
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
100
50
50
50
50
50
50
50
50
MS
Result
52.6
37.4
34.2
33.0
25.7
38.4
32.8
34.1
33.4
30.0
37.8
24.0
21.9
<10.0
49.8
37.5
54.8
82.4
44.5
38.8
19.9
39.3
47.4
44.5
31.8
45.2
MSD
Result
57.4
47.6
44.1
43.5
33.2
44.8
38.8
44.5
43.2
39.0
47.8
34.5
23.8
<10.0
54.5
49.7
60.1
89.9
48.8
43.2
26.3
46.2
51.0
47.4
42.6
50.5
MS
% Rec
105
75
68
66
51
77
66
68
67
60
76
48
44
100
75
110
82
89
78
40
79
95
89
64
90
116
75
60
83
48
91
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
MSD % Rec
% Rec Limits
115 48-174
95 19-130
88 20-150
87 27-140
66 13-130
90 33-149
78 22-144
89 31-144
86 27-146
78 19-145
96 25-138
69 24-133
48 17-130
109 46-168
99 28-140
120 46-177
90 10-188
98 41-167
86 38-150
53 10-130
92 36-176
102 43-159
95 42-163
85 26-134
101 37-152
139 10-164
104 10-130
80 10-130
108 10-138
66 10-130
100 19-191
Max
RPD RPD Qual
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
9 30 H3
24 30 H3
25 30 H3
28 30 H3
25 30 H3
15 30 H3
17 30 H3
26 30 H3
26 30 H3
26 30 H3
23 30 H3,v1
36 30 H3,R1
8 30 H3,IL
30 H3
9 30 H3
28 30 H3,v1
9 30 H3
9 30 H3
9 30 H3
11 30 H3
28 30 H3
16 30 H3
7 30 H3
6 30 H3
29 30 H3
11 30 H3
Page 142 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 805457 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E Water APP9 RV MSSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92691921004, 92691980004
METHOD BLANK: 4170936
Associated Lab Samples: 92691921004, 92691980004
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
1,2,4,5-Tetrachlorobenzene
ug/L
<4.5
10.0
4.5
10/12/23 10:47
1,3,5-Trinitrobenzene
ug/L
<5.5
10.0
5.5
10/12/23 10:47 v2
1,3-Dinitrobenzene
ug/L
<3.8
10.0
3.8
10/12/23 10:47
1,4-Naphthoquinone
ug/L
<4.4
5.0
4.4
10/12/23 10:47
1-Naphthalenamine
ug/L
<6.0
10.0
6.0
10/12/23 10:47
2,2'-Oxybis(1-chloropropane)
ug/L
<1.2
10.0
1.2
10/12/23 10:47
2,3,4,6-Tetrachlorophenol
ug/L
<1.5
10.0
1.5
10/12/23 10:47
2,4,5-Trichlorophenol
ug/L
<1.4
10.0
1.4
10/12/23 10:47
2,4,6-Trichlorophenol
ug/L
<1.6
10.0
1.6
10/12/23 10:47
2,4-Dichlorophenol
ug/L
<1.4
10.0
1.4
10/12/23 10:47
2,4-Dimethylphenol
ug/L
<1.7
10.0
1.7
10/12/23 10:47
2,4-Dinitrophenol
ug/L
<26.0
50.0
26.0
10/12/23 10:47
2,4-Dinitrotoluene
ug/L
<1.6
10.0
1.6
10/12/23 10:47
2,6-Dichlorophenol
ug/L
<4.2
10.0
4.2
10/12/23 10:47
2,6-Dinitrotoluene
ug/L
<1.7
10.0
1.7
10/12/23 10:47
2-Acetylaminofluorene
ug/L
<4.1
10.0
4.1
10/12/23 10:47
2-Chloronaphthalene
ug/L
<1.7
10.0
1.7
10/12/23 10:47
2-Chlorophenol
ug/L
<1.2
10.0
1.2
10/12/23 10:47
2-Methylnaphthalene
ug/L
<1.9
10.0
1.9
10/12/23 10:47
2-Methylphenol(o-Cresol)
ug/L
<1.9
10.0
1.9
10/12/23 10:47
2-Naphthalenamine
ug/L
<5.4
10.0
5.4
10/12/23 10:47
2-Nitroaniline
ug/L
<3.0
20.0
3.0
10/12/23 10:47
2-Nitrophenol
ug/L
<1.4
10.0
1.4
10/12/23 10:47
3&4-Methyl phenol (m&p Cresol)
ug/L
<1.2
10.0
1.2
10/12/23 10:47
3,3'-Dichlorobenzidine
ug/L
<8.1
20.0
8.1
10/12/23 10:47
3,3'-Dimethylbenzidine
ug/L
<31.1
50.0
31.1
10/12/23 10:47 IH
3-Methylcholanthrene
ug/L
<3.7
10.0
3.7
10/12/23 10:47
3-Nitroaniline
ug/L
<3.8
20.0
3.8
10/12/23 10:47
4,6-Dinitro-2-methyl phenol
ug/L
<7.8
20.0
7.8
10/12/23 10:47
4-Aminobiphenyl
ug/L
<4.7
10.0
4.7
10/12/23 10:47
4-Bromophenylphenyl ether
ug/L
<1.8
10.0
1.8
10/12/23 10:47
4-ChIoro-3-methyl phenol
ug/L
<3.3
10.0
3.3
10/12/23 10:47
4-Chloroaniline
ug/L
<3.6
20.0
3.6
10/12/23 10:47
4-Chlorophenylphenyl ether
ug/L
<2.0
10.0
2.0
10/12/23 10:47
4-Nitroaniline
ug/L
<5.1
20.0
5.1
10/12/23 10:47
4-Nitrophenol
ug/L
<6.6
50.0
6.6
10/12/23 10:47
5-Nitro-o-toluidine
ug/L
<3.8
10.0
3.8
10/12/23 10:47
7,12-Dimethylbenz(a)anthracene
ug/L
<3.0
10.0
3.0
10/12/23 10:47
Acenaphthene
ug/L
<2.0
10.0
2.0
10/12/23 10:47
Acenaphthylene
ug/L
<2.0
10.0
2.0
10/12/23 10:47
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 143 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
METHOD BLANK: 4170936
Associated Lab Samples: 92691921004, 92691980004
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Acetophenone
ug/L
<1.5
10.0
1.5
10/12/23 10:47
Anthracene
ug/L
<2.3
10.0
2.3
10/12/23 10:47
Benzo(a)anthracene
ug/L
<2.7
10.0
2.7
10/12/23 10:47
Benzo(a)pyrene
ug/L
<2.8
10.0
2.8
10/12/23 10:47
Benzo(b)fluoranthene
ug/L
<2.6
10.0
2.6
10/12/23 10:47
Benzo(g,h,i)perylene
ug/L
<2.8
10.0
2.8
10/12/23 10:47
Benzo(k)fluoranthene
ug/L
<2.7
10.0
2.7
10/12/23 10:47
Benzyl alcohol
ug/L
<2.9
20.0
2.9
10/12/23 10:47
bis(2-Chloroethoxy)methane
ug/L
<1.8
10.0
1.8
10/12/23 10:47
bis(2-Chloroethyl) ether
ug/L
<1.9
10.0
1.9
10/12/23 10:47
bis(2-Ethylhexyl)phthalate
ug/L
<3.7
6.0
3.7
10/12/23 10:47
Butylbenzylphthalate
ug/L
<3.1
10.0
3.1
10/12/23 10:47
Chlorobenzilate
ug/L
<3.8
10.0
3.8
10/12/23 10:47
Chrysene
ug/L
<2.8
10.0
2.8
10/12/23 10:47
Di-n-butylphthalate
ug/L
<2.2
10.0
2.2
10/12/23 10:47
Di-n-octylphthalate
ug/L
<3.9
10.0
3.9
10/12/23 10:47
Diallate
ug/L
<3.4
10.0
3.4
10/12/23 10:47
Dibenz(a,h)anthracene
ug/L
<3.0
10.0
3.0
10/12/23 10:47
Dibenzofuran
ug/L
<2.1
10.0
2.1
10/12/23 10:47
Diethylphthalate
ug/L
<2.0
10.0
2.0
10/12/23 10:47
Dimethoate
ug/L
<3.7
10.0
3.7
10/12/23 10:47
Dimethylphthalate
ug/L
<2.1
10.0
2.1
10/12/23 10:47
Diphenylamine
ug/L
<3.0
10.0
3.0
10/12/23 10:47
Disulfoton
ug/L
<4.6
10.0
4.6
10/12/23 10:47
Ethyl methanesulfonate
ug/L
<3.0
20.0
3.0
10/12/23 10:47
Famphur
ug/L
<6.1
10.0
6.1
10/12/23 10:47
Fluoranthene
ug/L
<2.2
10.0
2.2
10/12/23 10:47
Fluorene
ug/L
<2.1
10.0
2.1
10/12/23 10:47
Hexachlorobenzene
ug/L
<2.2
10.0
2.2
10/12/23 10:47
Hexachlorocyclopentadiene
ug/L
<1.6
10.0
1.6
10/12/23 10:47
Hexachloroethane
ug/L
<1.4
10.0
1.4
10/12/23 10:47
Hexachloropropene
ug/L
<2.7
10.0
2.7
10/12/23 10:47
Indeno(1,2,3-cd)pyrene
ug/L
<2.9
10.0
2.9
10/12/23 10:47
Isodrin
ug/L
<2.8
10.0
2.8
10/12/23 10:47
Isophorone
ug/L
<1.7
10.0
1.7
10/12/23 10:47
Isosafrole
ug/L
<2.5
10.0
2.5
10/12/23 10:47
Kepone
ug/L
<14.1
20.0
14.1
10/12/23 10:47
Methapyrilene
ug/L
<17.0
50.0
17.0
10/12/23 10:47
Methyl methanesulfonate
ug/L
<3.1
5.0
3.1
10/12/23 10:47
Methyl parathion
ug/L
<3.7
10.0
3.7
10/12/23 10:47
N-Nitroso-di-n-butylamine
ug/L
<2.0
10.0
2.0
10/12/23 10:47
N-Nitroso-di-n-propylamine
ug/L
<1.3
10.0
1.3
10/12/23 10:47
N-Nitrosodiethylamine
ug/L
<2.3
10.0
2.3
10/12/23 10:47
N-Nitrosodimethylamine
ug/L
<1.9
10.0
1.9
10/12/23 10:47
N-Nitrosodiphenylamine
ug/L
<3.0
10.0
3.0
10/12/23 10:47
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
v1
v1
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 144 of 229

Pace Analytical Services, LLC
(A)`?a
/'L��le2225 Riverside Dr.
r Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
METHOD BLANK: 4170936
Associated Lab Samples: 92691921004, 92691980004
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
N-Nitrosomethylethylamine
ug/L
<7.5
10.0
7.5
10/12/23 10:47
N-Nitrosopiperidine
ug/L
<2.5
10.0
2.5
10/12/23 10:47
N-Nitrosopyrrolidine
ug/L
<3.1
10.0
3.1
10/12/23 10:47
Nitrobenzene
ug/L
<1.9
10.0
1.9
10/12/23 10:47
O,O,O-Triethylphosphorothioate
ug/L
<2.6
10.0
2.6
10/12/23 10:47 v1
O-Toluidine
ug/L
<2.6
10.0
2.6
10/12/23 10:47
P-Dimethylaminoazobenzene
ug/L
<2.4
5.0
2.4
10/12/23 10:47 IL
p-Phenylenediamine
ug/L
<10.0
10.0
10.0
10/12/23 10:47
Parathion (Ethyl parathion)
ug/L
<3.9
10.0
3.9
10/12/23 10:47
Pentachlorobenzene
ug/L
<3.4
10.0
3.4
10/12/23 10:47
Pentachloronitrobenzene
ug/L
<3.3
10.0
3.3
10/12/23 10:47
Pentachlorophenol
ug/L
<3.8
20.0
3.8
10/12/23 10:47
Phenacetin
ug/L
<3.6
10.0
3.6
10/12/23 10:47
Phenanthrene
ug/L
<2.0
10.0
2.0
10/12/23 10:47
Phenol
ug/L
<1.4
10.0
1.4
10/12/23 10:47
Phorate
ug/L
<3.6
10.0
3.6
10/12/23 10:47
Pronamide
ug/L
<3.1
10.0
3.1
10/12/23 10:47
Pyrene
ug/L
<2.2
10.0
2.2
10/12/23 10:47
Safrole
ug/L
<2.3
10.0
2.3
10/12/23 10:47
Thionazin
ug/L
<2.9
10.0
2.9
10/12/23 10:47
2,4,6-Tribromophenol (S)
%
93
10-164
10/12/23 10:47
2-Fluorobiphenyl (S)
%
75
10-130
10/12/23 10:47
2-Fluorophenol (S)
%
61
10-130
10/12/23 10:47
Nitrobenzene-d5 (S)
%
83
10-138
10/12/23 10:47
Phenol-d6 (S)
%
43
10-130
10/12/23 10:47
Terphenyl-d14 (S)
%
105
19-191
10/12/23 10:47
LABORATORY CONTROL SAMPLE:
Parameter
4170937
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,2,4,5-Tetrachlorobenzene
ug/L
50
57.1
114
10-130
1,3,5-Trinitrobenzene
ug/L
50
35.6
71
55-200 v3
1,3-Dinitrobenzene
ug/L
50
70.7
141
48-176
1,4-Naphthoquinone
ug/L
50
61.4
123
18-130
1-Naphthalenamine
ug/L
50
38.2
76
29-149
2,2'-Oxybis(1-chloropropane)
ug/L
50
65.5
131
21-135
2,3,4,6-Tetrachlorophenol
ug/L
50
73.0
146
39-157
2,4,5-Trichlorophenol
ug/L
50
75.8
152
38-147 L1
2,4,6-Trichlorophenol
ug/L
50
69.1
138
34-142
2,4-Dichlorophenol
ug/L
50
65.7
131
36-136
2,4-Dimethylphenol
ug/L
50
60.1
120
38-134
2,4-Dinitrophenol
ug/L
250
352
141
10-169
2,4-Dinitrotoluene
ug/L
50
73.6
147
44-154
2,6-Dichlorophenol
ug/L
50
61.8
124
37-145
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 145 of 229

Project: Jackson County Fall 2023
Pace Project No.: 92691921
LABORATORY CONTROL SAMPLE: 4170937
Parameter
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
2,6-Dinitrotoluene
ug/L
50
74.9
150
44-156
2-Acetylaminofluorene
ug/L
50
60.3
121
25-175
2-Chloronaphthalene
ug/L
50
58.6
117
25-130
2-Chlorophenol
ug/L
50
57.5
115
29-130
2-Methylnaphthalene
ug/L
50
61.3
123
23-130
2-Methylphenol(o-Cresol)
ug/L
50
48.5
97
31-130
2-Naphthalenamine
ug/L
50
29.0
58
34-147
2-Nitroaniline
ug/L
100
135
135
39-145
2-Nitrophenol
ug/L
50
68.3
137
29-142
3&4-Methyl phenol (m&p Cresol)
ug/L
50
51.0
102
30-130
3,3'-Dichlorobenzidine
ug/L
100
155
155
44-158
3,3'-Dimethylbenzidine
ug/L
100
31.8J
32
38-2001H,L2
3-Methylcholanthrene
ug/L
50
68.3
137
46-153
3-Nitroaniline
ug/L
100
145
145
45-152
4,6-Dinitro-2-methyl phenol
ug/L
100
136
136
39-158
4-Aminobiphenyl
ug/L
50
42.0
84
30-144
4-Bromophenylphenyl ether
ug/L
50
67.4
135
47-147
4-Chloro-3-methylphenol
ug/L
100
129
129
40-138
4-Chloroaniline
ug/L
100
116
116
35-130
4-Chlorophenylphenyl ether
ug/L
50
69.7
139
36-139
4-Nitroaniline
ug/L
100
149
149
46-157
4-Nitrophenol
ug/L
250
187
75
17-130
5-Nitro-o-toluidine
ug/L
50
65.4
131
50-182
7,12-Dimethylbenz(a)anthracene
ug/L
50
63.2
126
46-157
Acenaphthene
ug/L
50
60.5
121
34-135
Acenaphthylene
ug/L
50
63.0
126
35-137
Acetophenone
ug/L
50
53.1
106
30-137
Anthracene
ug/L
50
64.7
129
47-146
Benzo(a)anthracene
ug/L
50
69.4
139
48-160
Benzo(a)pyrene
ug/L
50
72.3
145
47-165
Benzo(b)fluoranthene
ug/L
50
80.1
160
49-171
Benzo(g,h,i)perylene
ug/L
50
68.3
137
46-166
Benzo(k)fluoranthene
ug/L
50
71.7
143
55-162
Benzyl alcohol
ug/L
100
112
112
29-132
bis(2-Chloroethoxy)methane
ug/L
50
58.7
117
33-136
bis(2-Chloroethyl) ether
ug/L
50
51.8
104
30-142
bis(2-Ethylhexyl)phthalate
ug/L
50
77.4
155
46-173
Butylbenzylphthalate
ug/L
50
75.9
152
53-169
Chlorobenzilate
ug/L
50
72.7
145
43-155
Chrysene
ug/L
50
68.8
138
54-152
Di-n-butylphthalate
ug/L
50
71.9
144
49-161
Di-n-octylphthalate
ug/L
50
84.6
169
50-166 L1
Diallate
ug/L
50
57.6
115
47-136
Dibenz(a,h)anthracene
ug/L
50
70.0
140
46-166
Dibenzofuran
ug/L
50
62.4
125
37-136
Diethylphthalate
ug/L
50
69.4
139
45-149
Dimethoate
ug/L
50
66.6
133
49-145
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 146 of 229

Pace Analytical Services, LLC
(A)`?a
/'L��le2225 Riverside Dr.
r Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
LABORATORY CONTROL SAMPLE:
Parameter
4170937
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Dimethylphthalate
ug/L
50
68.8
138
43-145
Diphenylamine
ug/L
50
65.2
130
49-142
Disulfoton
ug/L
50
55.1
110
42-130
Ethyl methanesulfonate
ug/L
50
49.1
98
26-135
Famphur
ug/L
100
98.6
99
10-130
Fluoranthene
ug/L
50
72.8
146
50-153
Fluorene
ug/L
50
65.9
132
42-142
Hexachlorobenzene
ug/L
50
66.7
133
44-138
Hexachlorocyclopentadiene
ug/L
50
62.3
125
10-130
Hexachloroethane
ug/L
50
34.5
69
10-130
Hexachloropropene
ug/L
50
37.1
74
10-130 v1
Indeno(1,2,3-cd)pyrene
ug/L
50
66.2
132
46-166
Isodrin
ug/L
50
65.9
132
48-141
Isophorone
ug/L
50
59.8
120
36-135
Isosafrole
ug/L
50
52.5
105
33-135
Kepone
ug/L
100
112
112
10-130 v1
Methapyrilene
ug/L
50
<17.0
8
10-185 L2
Methyl methanesulfonate
ug/L
50
42.6
85
21-130
Methyl parathion
ug/L
50
72.9
146
57-173
N-Nitroso-di-n-butylamine
ug/L
50
60.8
122
28-130
N-Nitroso-di-n-propylamine
ug/L
50
59.7
119
33-140
N-Nitrosodiethylamine
ug/L
50
54.8
110
27-141
N-Nitrosodimethylamine
ug/L
50
43.9
88
24-130
N-Nitrosodiphenylamine
ug/L
50
65.2
130
46-144
N-Nitrosomethylethylamine
ug/L
50
49.6
99
22-141
N-Nitrosopiperidine
ug/L
50
59.5
119
36-141
N-Nitrosopyrrolidine
ug/L
50
53.4
107
31-145
Nitrobenzene
ug/L
50
55.0
110
33-133
O,O,O-Triethylphosphorothioate
ug/L
50
66.5
133
30-152 v1
O-Toluidine
ug/L
50
45.6
91
30-131
P-Dimethylaminoazobenzene
ug/L
50
31.5
63
23-130IL
p-Phenylenediamine
ug/L
<10.0
Parathion (Ethyl parathion)
ug/L
50
68.2
136
52-169
Pentachlorobenzene
ug/L
50
64.8
130
31-136
Pentachloronitrobenzene
ug/L
50
82.0
164
59-177
Pentachlorophenol
ug/L
100
132
132
21-163
Phenacetin
ug/L
50
62.0
124
52-159
Phenanthrene
ug/L
50
65.6
131
47-146
Phenol
ug/L
50
33.8
68
19-130
Phorate
ug/L
50
55.3
111
35-184
Pronamide
ug/L
50
69.2
138
53-155
Pyrene
ug/L
50
71.9
144
53-155
Safrole
ug/L
50
59.0
118
31-130
Thionazin
ug/L
50
66.6
133
46-148
2,4,6-Tribromophenol (S)
%
112
10-164
2-Fluorobiphenyl (S)
%
94
10-130
2-Fluorophenol (S)
%
67
10-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 147 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
LABORATORY CONTROL SAMPLE:
4170937
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Nitrobenzene-d5 (S)
%
92
10-138
Phenol-d6 (S)
%
52
10-130
Terphenyl-d14 (S)
%
110
19-191
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4170940
4170941
MS
MSD
92691892002
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result % Rec % Rec
Limits
RPD
RPD Qual
1,2,4,5-Tetrachlorobenzene
ug/L
ND
50
45.5
29.7
43.4
59
95
12-130
38
30 R1
1,3,5-Trinitrobenzene
ug/L
ND
50
45.5
23.6
28.4
47
62
34-200
18
30 v3
1,3-Dinitrobenzene
ug/L
ND
50
45.5
53.5
59.5
107
131
34-183
11
30
1,4-Naphthoquinone
ug/L
ND
50
45.5
33.9
55.5
68
122
14-136
48
30 R1
1-Naphthalenamine
ug/L
ND
50
45.5
35.6
32.1
71
71
10-173
10
30
2,2'-Oxybis(1-
ug/L
ND
50
45.5
37.8
49.4
76
109
11-143
27
30
chloropropane)
2,3,4,6-Tetrachlorophenol
ug/L
ND
50
45.5
3AJ
51.9
7
114
10-180
30 M1
2,4,5-Trichlorophenol
ug/L
ND
50
45.5
9.7J
55.4
19
122
10-170
30
2,4,6-Trichlorophenol
ug/L
ND
50
45.5
3.3J
50.6
7
111
10-166
30 M1
2,4-Dichlorophenol
ug/L
ND
50
45.5
11.0
48.2
22
106
10-153
126
30 R1
2,4-Dimethylphenol
ug/L
ND
50
45.5
35.0
44.5
70
98
20-147
24
30
2,4-Dinitrophenol
ug/L
ND
250
227
<26.0
261
9
115
10-172
30 M1
2,4-Dinitrotoluene
ug/L
ND
50
45.5
49.0
53.0
98
117
30-164
8
30
2,6-Dichlorophenol
ug/L
ND
50
45.5
<4.2
53.8
8
118
10-161
30 M1
2,6-Dinitrotoluene
ug/L
ND
50
45.5
49.1
55.1
98
121
31-163
12
30
2-Acetylam inofl uorene
ug/L
ND
50
45.5
55.9
52.1
112
115
20-166
7
30
2-Chloronaphthalene
ug/L
ND
50
45.5
31.5
42.3
63
93
15-134
29
30
2-Chlorophenol
ug/L
ND
50
45.5
11.1
44.2
22
97
10-139
119
30 R1
2-Methyl naphthalene
ug/L
ND
50
45.5
30.5
41.9
61
92
12-130
32
30 R1
2-Methyl phenol(o-Cresol)
ug/L
ND
50
45.5
27.5
38.1
55
84
19-132
32
30 R1
2-Naphthalenamine
ug/L
ND
50
45.5
28.4
13.2
57
29
10-164
73
30 R1
2-Nitroaniline
ug/L
ND
100
90.9
89.2
92.1
89
101
23-154
3
30
2-Nitrophenol
ug/L
ND
50
45.5
10.8
51.3
22
113
10-159
130
30 R1
3&4-Methylphenol(m&p
ug/L
ND
50
45.5
27.0
39.9
54
88
13-136
38
30 R1
Cresol)
3,3'-Dichlorobenzidine
ug/L
ND
100
90.9
102
108
102
119
10-178
6
30
3,3'-Dimethylbenzidine
ug/L
ND
100
90.9
76.5
43.1J
76
47
10-200
30 IH
3-Methylcholanthrene
ug/L
ND
50
45.5
58.1
58.5
116
129
36-158
1
30
3-Nitroaniline
ug/L
ND
100
90.9
104
100
104
110
20-166
4
30
4,6-Dinitro-2-methylphenol
ug/L
ND
100
90.9
9.7J
101
10
111
10-187
30
4-Aminobiphenyl
ug/L
ND
50
45.5
41.1
37.4
82
82
10-181
9
30
4-Bromophenylphenyl ether
ug/L
ND
50
45.5
45.6
50.2
91
110
31-157
10
30
4-Chloro-3-methylphenol
ug/L
ND
100
90.9
78.9
94.3
79
104
27-146
18
30
4-Chloroaniline
ug/L
ND
100
90.9
67.7
83.1
68
91
13-143
20
30
4-Chlorophenylphenyl ether
ug/L
ND
50
45.5
43.1
51.0
86
112
23-149
17
30
4-Nitroaniline
ug/L
ND
100
90.9
105
96.4
105
106
24-171
8
30
4-Nitrophenol
ug/L
ND
250
227
<6.6
138
0
61
10-130
30 M1
Results presented on this page are in the units
indicated by the
"Units" column except where
an alternate unit is presented to the right of the result.
REPORT
OF LABORATORY ANALYSIS
This report shall not be reproduced,
except
in full,
Date: 02/23/2024 01:48 PM
without
the written consent of Pace Analytical Services, LLC.
Page 148 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4170940
4170941
MS
MSD
92691892002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
5-Nitro-o-toluidine
ug/L
ND
50
45.5
49.9
53.4
100
118
33-192
7
30
7,12-
ug/L
ND
50
45.5
51.2
52.3
102
115
36-161
2
30
Dimethylbenz(a)anthracene
Acenaphthene
ug/L
ND
50
45.5
35.1
44.2
70
97
21-147
23
30
Acenaphthylene
ug/L
ND
50
45.5
36.2
45.8
72
101
19-150
23
30
Acetophenone
ug/L
ND
50
45.5
31.7
40.3
63
89
22-145
24
30
Anthracene
ug/L
ND
50
45.5
45.8
47.0
92
103
36-152
3
30
Benzo(a)anth race ne
ug/L
ND
50
45.5
51.4
50.4
103
111
42-163
2
30
Benzo(a)pyrene
ug/L
ND
50
45.5
53.1
52.8
106
116
40-169
1
30
Benzo(b)fluoranthene
ug/L
ND
50
45.5
58.5
58.1
117
128
40-177
1
30
Benzo(g,h,i)perylene
ug/L
ND
50
45.5
48.9
49.1
98
108
38-174
0
30
Benzo(k)fluoranthene
ug/L
ND
50
45.5
52.5
52.4
105
115
41-171
0
30
Benzyl alcohol
ug/L
ND
100
90.9
68.9
87.8
69
97
18-141
24
30
bis(2-
ug/L
ND
50
45.5
32.8
42.1
66
93
19-146
25
30
Chloroethoxy)methane
bis(2-Chloroethyl) ether
ug/L
ND
50
45.5
32.5
40.8
65
90
19-151
23
30
bis(2- Ethyl hexyl)phthalate
ug/L
ND
50
45.5
58.1
56.9
116
125
42-168
2
30
Butylbenzylphthalate
ug/L
ND
50
45.5
58.3
56.8
117
125
42-177
2
30
Chlorobenzilate
ug/L
ND
50
45.5
61.0
61.8
122
136
36-158
1
30
Chrysene
ug/L
ND
50
45.5
50.7
49.7
101
109
43-159
2
30
Di-n-butylphthalate
ug/L
ND
50
45.5
52.1
51.9
104
114
42-160
0
30
Di-n-octylphthalate
ug/L
ND
50
45.5
64.3
63.2
129
139
42-171
2
30
Diallate
ug/L
ND
50
45.5
43.4
49.1
87
108
38-139
12
30
Dibenz(a,h)anthracene
ug/L
ND
50
45.5
49.5
50.4
99
111
40-171
2
30
Dibenzofuran
ug/L
ND
50
45.5
37.4
46.0
75
101
23-147
21
30
Diethylphthalate
ug/L
ND
50
45.5
48.8
50.6
98
111
33-157
4
30
Dimethoate
ug/L
ND
50
45.5
50.2
54.5
100
120
41-146
8
30
Dimethylphthalate
ug/L
ND
50
45.5
44.6
49.8
89
110
27-154
11
30
Diphenylamine
ug/L
ND
50
45.5
45.8
47.0
92
103
38-146
3
30
Disulfoton
ug/L
ND
50
45.5
44.0
46.0
88
101
39-130
4
30
Ethyl methanesulfonate
ug/L
ND
50
45.5
33.4
43.1
67
95
25-136
25
30
Famphur
ug/L
ND
100
90.9
47.5
79.5
47
87
10-130
50
30 R1
Fluoranthene
ug/L
ND
50
45.5
52.3
51.7
105
114
42-157
1
30
Fluorene
ug/L
ND
50
45.5
40.4
47.8
81
105
25-155
17
30
Hexachlorobenzene
ug/L
ND
50
45.5
44.0
48.6
88
107
32-145
10
30
Hexachlorocyclopentadiene
ug/L
ND
50
45.5
26.7
39.4
53
87
10-130
38
30 R1
Hexachloroethane
ug/L
ND
50
45.5
19.8
22.4
40
49
10-130
12
30
Hexachloropropene
ug/L
ND
50
45.5
14.6
21.6
29
47
10-130
39
30 R1,v1
Indeno(1,2,3-cd)pyrene
ug/L
ND
50
45.5
48.1
47.9
96
105
39-174
0
30
Isodrin
ug/L
ND
50
45.5
53.1
56.2
106
124
34-148
6
30
Isophorone
ug/L
ND
50
45.5
34.7
43.9
69
97
19-146
23
30
Isosafrole
ug/L
ND
50
45.5
32.9
43.3
66
95
25-139
27
30
Kepone
ug/L
ND
100
90.9
67.4
98.1
67
108
10-130
37
30 R1,v1
Methapyrilene
ug/L
ND
50
45.5
52.4
<15.5
105
10
10-200
30
Methyl methanesulfonate
ug/L
ND
50
45.5
28.6
37.5
57
82
22-130
27
30
Methyl parathion
ug/L
ND
50
45.5
56.4
61.7
113
136
48-174
9
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 149 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4170940
4170941
MS
MSD
92691892002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
N-Nitroso-di-n-butylamine
ug/L
ND
50
45.5
39.3
51.5
79
113
19-130
27
30
N-Nitroso-di-n-propylamine
ug/L
ND
50
45.5
36.5
46.2
73
102
20-150
24
30
N-Nitrosodiethylamine
ug/L
ND
50
45.5
37.7
49.5
75
109
27-140
27
30
N-Nitrosodimethylamine
ug/L
ND
50
45.5
26.8
33.6
54
74
13-130
23
30
N-Nitrosodiphenylamine
ug/L
ND
50
45.5
45.8
47.0
92
103
33-149
3
30
N-Nitrosomethylethylamine
ug/L
ND
50
45.5
35.5
44.8
71
99
22-144
23
30
N-Nitrosopiperidine
ug/L
ND
50
45.5
38.3
50.3
77
111
31-144
27
30
N-Nitrosopyrrolidine
ug/L
ND
50
45.5
36.2
47.4
72
104
27-146
27
30
Nitrobenzene
ug/L
ND
50
45.5
31.5
42.0
63
92
19-145
29
30
0,0,0-
ug/L
ND
50
45.5
41.9
56.5
84
124
25-138
30
30 v1
Triethylphosphorothioate
O-Toluidine
ug/L
ND
50
45.5
33.6
40.1
67
88
24-133
18
30
P-
ug/L
ND
50
45.5
26.0
27.0
52
59
17-130
4
30 IL
Dimethylaminoazobenzene
p-Phenylenediamine
ug/L
ND
<10.0
<9.1
30
Parathion (Ethyl parathion)
ug/L
ND
50
45.5
55.5
58.0
111
128
46-168
5
30
Pentachlorobenzene
ug/L
ND
50
45.5
41.8
54.4
84
120
28-140
26
30
Pentachloronitrobenzene
ug/L
ND
50
45.5
56.6
68.3
113
150
46-177
19
30
Pentachlorophenol
ug/L
ND
100
90.9
9.2J
93.7
9
103
10-188
30 M1
Phenacetin
ug/L
ND
50
45.5
49.7
52.4
99
115
41-167
5
30
Phenanthrene
ug/L
ND
50
45.5
46.1
47.4
92
104
38-150
3
30
Phenol
ug/L
ND
50
45.5
13.1
26.8
26
59
10-130
69
30 R1
Phorate
ug/L
ND
50
45.5
41.7
46.8
83
103
36-176
12
30
Pronamide
ug/L
ND
50
45.5
56.0
57.7
112
127
43-159
3
30
Pyrene
ug/L
ND
50
45.5
54.5
52.7
109
116
42-163
3
30
Safrole
ug/L
ND
50
45.5
34.9
48.6
70
107
26-134
33
30 R1
Thionazin
ug/L
ND
50
45.5
51.0
56.7
102
125
37-152
11
30
2,4,6-Tribromophenol (S)
%
17
114
10-164
2-Fluorobiphenyl (S)
%
60
93
10-130
2-Fluorophenol (S)
%
6
72
10-130
SO
Nitrobenzene-d5 (S)
%
60
91
10-138
Phenol-d6 (S)
%
19
58
10-130
Terphenyl-d14 (S)
%
92
111
19-191
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 150 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 805860 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E Water APP9 RV MSSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92692397001, 92692397003
METHOD BLANK: 4172952
Associated Lab Samples: 92692397001, 92692397003
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
1,2,4,5-Tetrachlorobenzene
ug/L
<4.5
10.0
4.5
10/13/23 13:16
1,3,5-Trinitrobenzene
ug/L
<5.5
10.0
5.5
10/13/23 13:16 v2
1,3-Dinitrobenzene
ug/L
<3.8
10.0
3.8
10/13/23 13:16
1,4-Naphthoquinone
ug/L
<4.4
5.0
4.4
10/13/23 13:16
1-Naphthalenamine
ug/L
<6.0
10.0
6.0
10/13/23 13:16
2,2'-Oxybis(1-chloropropane)
ug/L
<1.2
10.0
1.2
10/13/23 13:16
2,3,4,6-Tetrachlorophenol
ug/L
<1.5
10.0
1.5
10/13/23 13:16
2,4,5-Trichlorophenol
ug/L
<1.4
10.0
1.4
10/13/23 13:16
2,4,6-Trichlorophenol
ug/L
<1.6
10.0
1.6
10/13/23 13:16
2,4-Dichlorophenol
ug/L
<1.4
10.0
1.4
10/13/23 13:16
2,4-Dimethylphenol
ug/L
<1.7
10.0
1.7
10/13/23 13:16
2,4-Dinitrophenol
ug/L
<26.0
50.0
26.0
10/13/23 13:16
2,4-Dinitrotoluene
ug/L
<1.6
10.0
1.6
10/13/23 13:16
2,6-Dichlorophenol
ug/L
<4.2
10.0
4.2
10/13/23 13:16
2,6-Dinitrotoluene
ug/L
<1.7
10.0
1.7
10/13/23 13:16
2-Acetylaminofluorene
ug/L
<4.1
10.0
4.1
10/13/23 13:16
2-Chloronaphthalene
ug/L
<1.7
10.0
1.7
10/13/23 13:16
2-Chlorophenol
ug/L
<1.2
10.0
1.2
10/13/23 13:16
2-Methylnaphthalene
ug/L
<1.9
10.0
1.9
10/13/23 13:16
2-Methylphenol(o-Cresol)
ug/L
<1.9
10.0
1.9
10/13/23 13:16
2-Naphthalenamine
ug/L
<5.4
10.0
5.4
10/13/23 13:16
2-Nitroaniline
ug/L
<3.0
20.0
3.0
10/13/23 13:16
2-Nitrophenol
ug/L
<1.4
10.0
1.4
10/13/23 13:16
3&4-Methyl phenol (m&p Cresol)
ug/L
<1.2
10.0
1.2
10/13/23 13:16
3,3'-Dichlorobenzidine
ug/L
<8.1
20.0
8.1
10/13/23 13:16
3,3'-Dimethylbenzidine
ug/L
<31.1
50.0
31.1
10/13/23 13:16 IH
3-Methylcholanthrene
ug/L
<3.7
10.0
3.7
10/13/23 13:16
3-Nitroaniline
ug/L
<3.8
20.0
3.8
10/13/23 13:16
4,6-Dinitro-2-methyl phenol
ug/L
<7.8
20.0
7.8
10/13/23 13:16
4-Aminobiphenyl
ug/L
<4.7
10.0
4.7
10/13/23 13:16
4-Bromophenylphenyl ether
ug/L
<1.8
10.0
1.8
10/13/23 13:16
4-ChIoro-3-methyl phenol
ug/L
<3.3
10.0
3.3
10/13/23 13:16
4-Chloroaniline
ug/L
<3.6
20.0
3.6
10/13/23 13:16
4-Chlorophenylphenyl ether
ug/L
<2.0
10.0
2.0
10/13/23 13:16
4-Nitroaniline
ug/L
<5.1
20.0
5.1
10/13/23 13:16
4-Nitrophenol
ug/L
<6.6
50.0
6.6
10/13/23 13:16
5-Nitro-o-toluidine
ug/L
<3.8
10.0
3.8
10/13/23 13:16
7,12-Dimethylbenz(a)anthracene
ug/L
<3.0
10.0
3.0
10/13/23 13:16
Acenaphthene
ug/L
<2.0
10.0
2.0
10/13/23 13:16
Acenaphthylene
ug/L
<2.0
10.0
2.0
10/13/23 13:16
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 151 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
METHOD BLANK: 4172952
Associated Lab Samples: 92692397001, 92692397003
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Acetophenone
ug/L
<1.5
10.0
1.5
10/13/23 13:16
Anthracene
ug/L
<2.3
10.0
2.3
10/13/23 13:16
Benzo(a)anthracene
ug/L
<2.7
10.0
2.7
10/13/23 13:16
Benzo(a)pyrene
ug/L
<2.8
10.0
2.8
10/13/23 13:16
Benzo(b)fluoranthene
ug/L
<2.6
10.0
2.6
10/13/23 13:16
Benzo(g,h,i)perylene
ug/L
<2.8
10.0
2.8
10/13/23 13:16
Benzo(k)fluoranthene
ug/L
<2.7
10.0
2.7
10/13/23 13:16
Benzyl alcohol
ug/L
<2.9
20.0
2.9
10/13/23 13:16
bis(2-Chloroethoxy)methane
ug/L
<1.8
10.0
1.8
10/13/23 13:16
bis(2-Chloroethyl) ether
ug/L
<1.9
10.0
1.9
10/13/23 13:16
bis(2-Ethylhexyl)phthalate
ug/L
<3.7
6.0
3.7
10/13/23 13:16
Butylbenzylphthalate
ug/L
<3.1
10.0
3.1
10/13/23 13:16
Chlorobenzilate
ug/L
<3.8
10.0
3.8
10/13/23 13:16
Chrysene
ug/L
<2.8
10.0
2.8
10/13/23 13:16
Di-n-butylphthalate
ug/L
<2.2
10.0
2.2
10/13/23 13:16
Di-n-octylphthalate
ug/L
<3.9
10.0
3.9
10/13/23 13:16
Diallate
ug/L
<3.4
10.0
3.4
10/13/23 13:16
Dibenz(a,h)anthracene
ug/L
<3.0
10.0
3.0
10/13/23 13:16
Dibenzofuran
ug/L
<2.1
10.0
2.1
10/13/23 13:16
Diethylphthalate
ug/L
<2.0
10.0
2.0
10/13/23 13:16
Dimethoate
ug/L
<3.7
10.0
3.7
10/13/23 13:16
Dimethylphthalate
ug/L
<2.1
10.0
2.1
10/13/23 13:16
Diphenylamine
ug/L
<3.0
10.0
3.0
10/13/23 13:16
Disulfoton
ug/L
<4.6
10.0
4.6
10/13/23 13:16
Ethyl methanesulfonate
ug/L
<3.0
20.0
3.0
10/13/23 13:16
Famphur
ug/L
<6.1
10.0
6.1
10/13/23 13:16
Fluoranthene
ug/L
<2.2
10.0
2.2
10/13/23 13:16
Fluorene
ug/L
<2.1
10.0
2.1
10/13/23 13:16
Hexachlorobenzene
ug/L
<2.2
10.0
2.2
10/13/23 13:16
Hexachlorocyclopentadiene
ug/L
<1.6
10.0
1.6
10/13/23 13:16
Hexachloroethane
ug/L
<1.4
10.0
1.4
10/13/23 13:16
Hexachloropropene
ug/L
<2.7
10.0
2.7
10/13/23 13:16
Indeno(1,2,3-cd)pyrene
ug/L
<2.9
10.0
2.9
10/13/23 13:16
Isodrin
ug/L
<2.8
10.0
2.8
10/13/23 13:16
Isophorone
ug/L
<1.7
10.0
1.7
10/13/23 13:16
Isosafrole
ug/L
<2.5
10.0
2.5
10/13/23 13:16
Kepone
ug/L
<14.1
20.0
14.1
10/13/23 13:16
Methapyrilene
ug/L
<17.0
50.0
17.0
10/13/23 13:16
Methyl methanesulfonate
ug/L
<3.1
5.0
3.1
10/13/23 13:16
Methyl parathion
ug/L
<3.7
10.0
3.7
10/13/23 13:16
N-Nitroso-di-n-butylamine
ug/L
<2.0
10.0
2.0
10/13/23 13:16
N-Nitroso-di-n-propylamine
ug/L
<1.3
10.0
1.3
10/13/23 13:16
N-Nitrosodiethylamine
ug/L
<2.3
10.0
2.3
10/13/23 13:16
N-Nitrosodimethylamine
ug/L
<1.9
10.0
1.9
10/13/23 13:16
N-Nitrosodiphenylamine
ug/L
<3.0
10.0
3.0
10/13/23 13:16
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
v1
v1
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 152 of 229

Pace Analytical Services, LLC
(A)`?a
/'L��le2225 Riverside Dr.
r Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
METHOD BLANK: 4172952
Associated Lab Samples: 92692397001, 92692397003
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
N-Nitrosomethylethylamine
ug/L
<7.5
10.0
7.5
10/13/23 13:16
N-Nitrosopiperidine
ug/L
<2.5
10.0
2.5
10/13/23 13:16
N-Nitrosopyrrolidine
ug/L
<3.1
10.0
3.1
10/13/23 13:16
Nitrobenzene
ug/L
<1.9
10.0
1.9
10/13/23 13:16
O,O,O-Triethylphosphorothioate
ug/L
<2.6
10.0
2.6
10/13/23 13:16 v1
O-Toluidine
ug/L
<2.6
10.0
2.6
10/13/23 13:16
P-Dimethylaminoazobenzene
ug/L
<2.4
5.0
2.4
10/13/23 13:16 IL
p-Phenylenediamine
ug/L
<10.0
10.0
10.0
10/13/23 13:16
Parathion (Ethyl parathion)
ug/L
<3.9
10.0
3.9
10/13/23 13:16
Pentachlorobenzene
ug/L
<3.4
10.0
3.4
10/13/23 13:16
Pentachloronitrobenzene
ug/L
<3.3
10.0
3.3
10/13/23 13:16 v1
Pentachlorophenol
ug/L
<3.8
20.0
3.8
10/13/23 13:16
Phenacetin
ug/L
<3.6
10.0
3.6
10/13/23 13:16
Phenanthrene
ug/L
<2.0
10.0
2.0
10/13/23 13:16
Phenol
ug/L
<1.4
10.0
1.4
10/13/23 13:16
Phorate
ug/L
<3.6
10.0
3.6
10/13/23 13:16
Pronamide
ug/L
<3.1
10.0
3.1
10/13/23 13:16
Pyrene
ug/L
<2.2
10.0
2.2
10/13/23 13:16
Safrole
ug/L
<2.3
10.0
2.3
10/13/23 13:16
Thionazin
ug/L
<2.9
10.0
2.9
10/13/23 13:16
2,4,6-Tribromophenol (S)
%
17
10-166
10/13/23 13:16
2-Fluorobiphenyl (S)
%
51
10-130
10/13/23 13:16
2-Fluorophenol (S)
%
12
10-130
10/13/23 13:16
Nitrobenzene-d5 (S)
%
61
10-133
10/13/23 13:16
Phenol-d6 (S)
%
21
10-130
10/13/23 13:16
Terphenyl-d14 (S)
%
64
10-193
10/13/23 13:16
LABORATORY CONTROL SAMPLE:
Parameter
4172953
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,2,4,5-Tetrachlorobenzene
ug/L
50
53.4
107
18-130
1,3,5-Trinitrobenzene
ug/L
50
33.0
66
59-200 v3
1,3-Dinitrobenzene
ug/L
50
68.8
138
51-170
1,4-Naphthoquinone
ug/L
50
49.2
98
32-132
1-Naphthalenamine
ug/L
50
40.0
80
35-140
2,2'-Oxybis(1-chloropropane)
ug/L
50
54.0
108
23-130
2,3,4,6-Tetrachlorophenol
ug/L
50
60.4
121
38-154
2,4,5-Trichlorophenol
ug/L
50
63.4
127
36-150
2,4,6-Trichlorophenol
ug/L
50
59.1
118
30-151
2,4-Dichlorophenol
ug/L
50
54.4
109
36-140
2,4-Dimethylphenol
ug/L
50
50.9
102
36-155
2,4-Dinitrophenol
ug/L
250
297
119
10-169
2,4-Dinitrotoluene
ug/L
50
62.0
124
46-160
2,6-Dichlorophenol
ug/L
50
62.4
125
34-156
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 153 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE:
Parameter
4172953
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
2,6-Dinitrotoluene
ug/L
50
64.0
128
47-161
2-Acetylaminofluorene
ug/L
50
60.2
120
39-184
2-Chloronaphthalene
ug/L
50
45.0
90
29-134
2-Chlorophenol
ug/L
50
48.9
98
29-130
2-Methylnaphthalene
ug/L
50
46.0
92
26-130
2-Methylphenol(o-Cresol)
ug/L
50
43.2
86
32-130
2-Naphthalenamine
ug/L
50
51.5
103
23-145
2-Nitroaniline
ug/L
100
113
113
41-150
2-Nitrophenol
ug/L
50
55.8
112
31-145
3&4-Methyl phenol (m&p Cresol)
ug/L
50
45.9
92
29-130
3,3'-Dichlorobenzidine
ug/L
100
131
131
46-153
3,3'-Dimethylbenzidine
ug/L
100
73.9
74
24-200lH
3-Methylcholanthrene
ug/L
50
66.7
133
31-195
3-Nitroaniline
ug/L
100
122
122
47-156
4,6-Dinitro-2-methyl phenol
ug/L
100
114
114
23-161
4-Aminobiphenyl
ug/L
50
44.6
89
26-151
4-Bromophenylphenyl ether
ug/L
50
55.5
111
45-143
4-Chloro-3-methylphenol
ug/L
100
111
111
42-143
4-Chloroaniline
ug/L
100
96.3
96
37-135
4-Chlorophenylphenyl ether
ug/L
50
57.1
114
43-140
4-Nitroaniline
ug/L
100
123
123
47-157
4-Nitrophenol
ug/L
250
163
65
10-130
5-Nitro-o-toluidine
ug/L
50
64.1
128
54-170
7,12-Dimethylbenz(a)anthracene
ug/L
50
61.4
123
29-176
Acenaphthene
ug/L
50
48.7
97
38-138
Acenaphthylene
ug/L
50
51.1
102
39-139
Acetophenone
ug/L
50
46.0
92
34-135
Anthracene
ug/L
50
52.5
105
45-136
Benzo(a)anthracene
ug/L
50
57.4
115
52-151
Benzo(a)pyrene
ug/L
50
59.7
119
46-165
Benzo(b)fluoranthene
ug/L
50
66.0
132
44-170
Benzo(g,h,i)perylene
ug/L
50
56.2
112
39-171
Benzo(k)fluoranthene
ug/L
50
60.9
122
43-168
Benzyl alcohol
ug/L
100
98.5
98
33-134
bis(2-Chloroethoxy)methane
ug/L
50
48.3
97
37-140
bis(2-Chloroethyl) ether
ug/L
50
44.4
89
33-136
bis(2-Ethylhexyl)phthalate
ug/L
50
64.1
128
50-169
Butylbenzylphthalate
ug/L
50
64.5
129
50-174
Chlorobenzilate
ug/L
50
74.1
148
46-167
Chrysene
ug/L
50
56.4
113
52-148
Di-n-butylphthalate
ug/L
50
58.1
116
51-154
Di-n-octylphthalate
ug/L
50
68.7
137
44-170
Diallate
ug/L
50
56.8
114
49-147
Dibenz(a,h)anthracene
ug/L
50
57.1
114
41-171
Dibenzofuran
ug/L
50
50.8
102
42-157
Diethylphthalate
ug/L
50
58.9
118
50-149
Dimethoate
ug/L
50
64.7
129
52-169
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 154 of 229

Pace Analytical Services, LLC
(A)`?a
/'L��le2225 Riverside Dr.
r Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
LABORATORY CONTROL SAMPLE:
Parameter
4172953
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Dimethylphthalate
ug/L
50
58.5
117
47-146
Diphenylamine
ug/L
50
54.0
108
53-142
Disulfoton
ug/L
50
55.4
111
45-135
Ethyl methanesulfonate
ug/L
50
50.6
101
27-146
Famphur
ug/L
100
94.0
94
13-130
Fluoranthene
ug/L
50
57.6
115
51-152
Fluorene
ug/L
50
54.0
108
46-143
Hexachlorobenzene
ug/L
50
54.6
109
40-139
Hexachlorocyclopentadiene
ug/L
50
40.7
81
10-130
Hexachloroethane
ug/L
50
27.1
54
10-130
Hexachloropropene
ug/L
50
29.3
59
10-130 v1
Indeno(1,2,3-cd)pyrene
ug/L
50
54.9
110
40-172
Isodrin
ug/L
50
66.0
132
50-150
Isophorone
ug/L
50
50.5
101
37-143
Isosafrole
ug/L
50
51.8
104
35-130
Kepone
ug/L
100
133
133
12-130 L1,v1
Methapyrilene
ug/L
50
<17.0
8
10-188 L2
Methyl methanesulfonate
ug/L
50
43.2
86
24-135
Methyl parathion
ug/L
50
71.8
144
59-174
N-Nitroso-di-n-butylamine
ug/L
50
62.5
125
33-130
N-Nitroso-di-n-propylamine
ug/L
50
52.6
105
38-145
N-Nitrosodiethylamine
ug/L
50
56.8
114
26-145
N-Nitrosodimethylamine
ug/L
50
37.2
74
30-130
N-Nitrosodiphenylamine
ug/L
50
54.0
108
46-144
N-Nitrosomethylethylamine
ug/L
50
50.7
101
19-138
N-Nitrosopiperidine
ug/L
50
59.6
119
35-147
N-Nitrosopyrrolidine
ug/L
50
55.9
112
31-142
Nitrobenzene
ug/L
50
43.7
87
33-136
O,O,O-Triethylphosphorothioate
ug/L
50
67.7
135
27-136 v1
O-Toluidine
ug/L
50
48.5
97
27-140
P-Dimethylaminoazobenzene
ug/L
50
31.8
64
23-130IL
p-Phenylenediamine
ug/L
<10.0
Parathion (Ethyl parathion)
ug/L
50
66.3
133
59-171
Pentachlorobenzene
ug/L
50
65.1
130
42-138
Pentachloronitrobenzene
ug/L
50
83.2
166
64-185 v1
Pentachlorophenol
ug/L
100
110
110
19-156
Phenacetin
ug/L
50
60.0
120
57-174
Phenanthrene
ug/L
50
52.5
105
49-143
Phenol
ug/L
50
31.0
62
18-130
Phorate
ug/L
50
55.5
111
41-200
Pronamide
ug/L
50
68.0
136
59-174
Pyrene
ug/L
50
61.1
122
48-156
Safrole
ug/L
50
58.0
116
31-136
Thionazin
ug/L
50
66.3
133
52-151
2,4,6-Tribromophenol (S)
%
114
10-166
2-Fluorobiphenyl (S)
%
84
10-130
2-Fluorophenol (S)
%
68
10-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 155 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
LABORATORY CONTROL SAMPLE:
4172953
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Nitrobenzene-d5 (S)
%
87
10-133
Phenol-d6 (S)
%
55
10-130
Terphenyl-d14 (S)
%
98
10-193
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4172954
4172955
MS
MSD
92692397003
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result % Rec % Rec
Limits
RPD
RPD Qual
1,2,4,5-Tetrachlorobenzene
ug/L
<4.5
100
100
81.6
82.6
82
83
10-136
1
30
1,3,5-Trinitrobenzene
ug/L
<5.5
100
100
47.3
48.4
47
48
32-200
2
30 v3
1,3-Dinitrobenzene
ug/L
<3.8
100
100
107
109
107
109
30-173
2
30
1,4-Naphthoquinone
ug/L
<4.4
100
100
70.9
73.8
71
74
10-144
4
30
1-Naphthalenamine
ug/L
<6.0
100
100
79.4
95.9
79
96
10-156
19
30
2,2'-Oxybis(1-
ug/L
<1.2
100
100
101
92.0
101
92
10-132
9
30
chloropropane)
2,3,4,6-Tetrachlorophenol
ug/L
<1.5
100
100
<3.0
<3.0
3
2
10-185
30 M1
2,4,5-Trichlorophenol
ug/L
<1.4
100
100
14.0J
6.8J
14
7
10-174
30 M1
2,4,6-Trichlorophenol
ug/L
<1.6
100
100
5AJ
<3.1
5
0
10-173
30 M1
2,4-Dichlorophenol
ug/L
<1.4
100
100
28.3
8.OJ
28
8
10-153
30 M1
2,4-Dimethylphenol
ug/L
<1.7
100
100
93.3
83.8
93
84
12-157
11
30
2,4-Dinitrophenol
ug/L
<26.0
500
500
<52.0
<52.0
0
0
10-165
30 M1
2,4-Dinitrotoluene
ug/L
<1.6
100
100
106
106
106
106
29-168
0
30
2,6-Dichlorophenol
ug/L
<4.2
100
100
9.6J
<8.4
10
0
10-178
30 M1
2,6-Dinitrotoluene
ug/L
<1.7
100
100
112
111
112
111
28-168
1
30
2-Acetylam inofl uorene
ug/L
<4.1
100
100
104
107
104
107
20-194
3
30
2-Chloronaphthalene
ug/L
<1.7
100
100
83.6
79.2
84
79
11-136
5
30
2-Chlorophenol
ug/L
<1.2
100
100
34.0
11.91
34
12
10-134
30
2-Methyl naphthalene
ug/L
<1.9
100
100
87.5
85.0
87
85
10-131
3
30
2-Methyl phenol(o-Cresol)
ug/L
<1.9
100
100
76.3
57.7
76
58
10-130
28
30
2-Naphthalenamine
ug/L
<5.4
100
100
76.4
87.9
76
88
10-147
14
30
2-Nitroaniline
ug/L
<3.0
200
200
201
195
100
98
19-156
3
30
2-Nitrophenol
ug/L
<1.4
100
100
12.1J
6.8J
12
7
10-160
30 M1
3&4-Methylphenol(m&p
ug/L
<1.2
100
100
72.3
50.4
72
50
10-132
36
30 R1
Cresol)
3,3'-Dichlorobenzidine
ug/L
<8.1
200
200
235
242
117
121
10-173
3
30
3,3'-Dimethylbenzidine
ug/L
<31.1
200
200
396
480
198
240
10-200
19
30 IH,M1
3-Methylcholanthrene
ug/L
<3.7
100
100
108
114
108
114
10-200
5
30
3-Nitroaniline
ug/L
<3.8
200
200
218
221
109
111
19-169
2
30
4,6-Dinitro-2-methylphenol
ug/L
<7.8
200
200
21.0J
22.2J
10
11
10-178
30
4-Aminobiphenyl
ug/L
<4.7
100
100
81.5
94.8
81
95
10-170
15
30
4-Bromophenylphenyl ether
ug/L
<1.8
100
100
101
100
101
100
28-149
1
30
4-Chloro-3-methylphenol
ug/L
<3.3
200
200
170
117
85
59
18-148
37
30 R1
4-Chloroaniline
ug/L
<3.6
200
200
183
178
91
89
10-141
3
30
4-Chlorophenylphenyl ether
ug/L
<2.0
100
100
104
100
104
100
24-144
3
30
4-Nitroaniline
ug/L
<5.1
200
200
220
222
110
111
18-170
1
30
4-Nitrophenol
ug/L
<6.6
500
500
<13.2
<13.2
0
0
10-130
30 M1
Results presented on this page are in the units
indicated by the
"Units" column except where
an alternate unit is presented to the right of the result.
REPORT
OF LABORATORY ANALYSIS
This report shall not be reproduced,
except
in full,
Date: 02/23/2024 01:48 PM
without
the written consent of Pace Analytical Services, LLC.
Page 156 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4172954
4172955
MS
MSD
92692397003
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
5-Nitro-o-toluidine
ug/L
<3.8
100
100
95.7
101
96
101
38-167
5
30
7,12-
ug/L
<3.0
100
100
105
102
105
102
10-182
3
30
Dimethylbenz(a)anthracene
Acenaphthene
ug/L
<2.0
100
100
89.3
84.8
89
85
18-142
5
30
Acenaphthylene
ug/L
<2.0
100
100
92.3
88.3
92
88
18-143
5
30
Acetophenone
ug/L
<1.5
100
100
83.1
80.9
83
81
10-142
3
30
Anthracene
ug/L
<2.3
100
100
95.1
94.5
95
95
32-138
1
30
Benzo(a)anth race ne
ug/L
<2.7
100
100
102
105
102
105
41-155
3
30
Benzo(a)pyrene
ug/L
<2.8
100
100
106
109
106
109
10-167
3
30
Benzo(b)fluoranthene
ug/L
<2.6
100
100
126
119
126
119
31-172
6
30
Benzo(g,h,i)perylene
ug/L
<2.8
100
100
109
103
109
103
26-177
6
30
Benzo(k)fluoranthene
ug/L
<2.7
100
100
118
111
118
111
31-168
7
30
Benzyl alcohol
ug/L
<2.9
200
200
176
173
88
86
10-136
2
30
bis(2-
ug/L
<1.8
100
100
86.4
81.3
86
81
12-143
6
30
Chloroethoxy)methane
bis(2-Chloroethyl) ether
ug/L
<1.9
100
100
81.6
75.4
82
75
10-139
8
30
bis(2- Ethyl hexyl)phthalate
ug/L
<3.7
100
100
115
119
115
119
41-173
4
30
Butylbenzylphthalate
ug/L
<3.1
100
100
117
117
117
117
38-182
0
30
Chlorobenzilate
ug/L
<3.8
100
100
114
122
114
122
33-175
7
30
Chrysene
ug/L
<2.8
100
100
102
104
102
104
41-152
2
30
Di-n-butylphthalate
ug/L
<2.2
100
100
105
106
105
106
37-162
1
30
Di-n-octylphthalate
ug/L
<3.9
100
100
124
128
124
128
36-176
3
30
Diallate
ug/L
<3.4
100
100
82.4
86.1
82
86
26-155
4
30
Dibenz(a,h)anthracene
ug/L
<3.0
100
100
110
105
110
105
29-175
5
30
Dibenzofuran
ug/L
<2.1
100
100
91.1
87.7
91
88
23-144
4
30
Diethylphthalate
ug/L
<2.0
100
100
106
106
106
106
33-154
1
30
Dimethoate
ug/L
<3.7
100
100
95.5
99.5
96
100
41-169
4
30
Dimethylphthalate
ug/L
<2.1
100
100
103
99.9
103
100
29-150
4
30
Diphenylamine
ug/L
<3.0
100
100
95.8
95.0
96
95
34-146
1
30
Disulfoton
ug/L
<4.6
100
100
86.1
89.6
86
90
36-133
4
30
Ethyl methanesulfonate
ug/L
<3.0
100
100
78.9
75.6
79
76
10-147
4
30
Famphur
ug/L
<6.1
200
200
90.1
89.1
45
45
10-130
1
30
Fluoranthene
ug/L
<2.2
100
100
105
105
105
105
40-156
0
30
Fluorene
ug/L
<2.1
100
100
95.8
93.1
96
93
26-148
3
30
Hexachlorobenzene
ug/L
<2.2
100
100
97.0
97.7
97
98
27-145
1
30
Hexachlorocyclopentadiene
ug/L
<1.6
100
100
79.2
79.4
79
79
10-130
0
30
Hexachloroethane
ug/L
<1.4
100
100
47.8
50.2
48
50
10-130
5
30
Hexachloropropene
ug/L
<2.7
100
100
53.9
54.1
54
54
10-130
0
30 v1
Indeno(1,2,3-cd)pyrene
ug/L
<2.9
100
100
106
101
106
101
28-176
5
30
Isodrin
ug/L
<2.8
100
100
100
106
100
106
33-153
5
30
Isophorone
ug/L
<1.7
100
100
91.4
85.6
91
86
14-145
7
30
Isosafrole
ug/L
<2.5
100
100
77.0
78.9
77
79
13-136
2
30
Kepone
ug/L
<14.1
200
200
37AJ
36.5J
19
18
10-130
30 v1
Methapyrilene
ug/L
<17.0
100
100
78.7J
90.8J
79
91
10-200
30
Methyl methanesulfonate
ug/L
<3.1
100
100
66.5
64.0
67
64
10-138
4
30
Methyl parathion
ug/L
<3.7
100
100
103
108
103
108
44-177
5
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 157 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4172954
4172955
MS
MSD
92692397003
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
N-Nitroso-di-n-butylamine
ug/L
<2.0
100
100
97.5
95.3
97
95
14-133
2
30
N-Nitroso-di-n-propylamine
ug/L
<1.3
100
100
97.0
91.1
97
91
12-149
6
30
N-Nitrosodiethylamine
ug/L
<2.3
100
100
83.6
84.5
84
84
10-148
1
30
N-Nitrosodimethylamine
ug/L
<1.9
100
100
68.0
61.6
68
62
10-130
10
30
N-Nitrosodiphenylamine
ug/L
<3.0
100
100
95.8
95.0
96
95
29-149
1
30
N-Nitrosomethylethylamine
ug/L
<7.5
100
100
82.3
76.4
82
76
10-139
7
30
N-Nitrosopiperidine
ug/L
<2.5
100
100
90.1
88.5
90
88
14-151
2
30
N-Nitrosopyrrolidine
ug/L
<3.1
100
100
87.1
85.5
87
86
14-143
2
30
Nitrobenzene
ug/L
<1.9
100
100
82.3
75.9
82
76
10-145
8
30
0,0,0-
ug/L
<2.6
100
100
103
104
103
104
10-142
0
30 v1
Triethylphosphorothioate
O-Toluidine
ug/L
<2.6
100
100
81.5
84.8
82
85
10-137
4
30
P-
ug/L
<2.4
100
100
50.4
53.8
50
54
17-130
7
30 IL
Dimethylaminoazobenzene
p-Phenylenediamine
ug/L
<10.0
<20.0
<20.0
30
Parathion (Ethyl parathion)
ug/L
<3.9
100
100
102
108
102
108
45-174
6
30
Pentachlorobenzene
ug/L
<3.4
100
100
97.0
98.4
97
98
20-143
2
30
Pentachloronitrobenzene
ug/L
<3.3
100
100
114
118
114
118
39-186
3
30 v1
Pentachlorophenol
ug/L
<3.8
200
200
<7.5
<7.5
0
0
10-178
30 M1
Phenacetin
ug/L
<3.6
100
100
90.7
98.1
91
98
36-185
8
30
Phenanthrene
ug/L
<2.0
100
100
94.9
93.5
95
93
36-146
2
30
Phenol
ug/L
<1.4
100
100
37.0
19.8J
37
20
10-130
30
Phorate
ug/L
<3.6
100
100
82.4
85.6
82
86
26-200
4
30
Pronamide
ug/L
<3.1
100
100
102
108
102
108
40-181
5
30
Pyrene
ug/L
<2.2
100
100
109
111
109
111
42-156
2
30
Safrole
ug/L
<2.3
100
100
90.1
90.3
90
90
10-142
0
30
Thionazin
ug/L
<2.9
100
100
104
103
104
103
31-159
1
30
2,4,6-Tribromophenol (S)
%
9
4
10-166
SO
2-Fluorobiphenyl (S)
%
77
75
10-130
2-Fluorophenol (S)
%
12
3
10-130
SO
Nitrobenzene-d5(S)
%
84
78
10-133
Phenol-d6 (S)
%
33
14
10-130
Terphenyl-d14(S)
%
89
90
10-193
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 158 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 806460 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E Water APP9 RV MSSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92691921015
METHOD BLANK: 4176150
Associated Lab Samples: 92691921015
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Qualifiers
1,2,4,5-Tetrachlorobenzene
ug/L
<4.5
10.0
4.5
10/17/23 11:54
1,3,5-Trinitrobenzene
ug/L
<5.5
10.0
5.5
10/17/23 11:54
v2
1,3-Dinitrobenzene
ug/L
<3.8
10.0
3.8
10/17/23 11:54
1,4-Naphthoquinone
ug/L
<4.4
5.0
4.4
10/17/23 11:54
1-Naphthalenamine
ug/L
<6.0
10.0
6.0
10/17/23 11:54
2,2'-Oxybis(1-chloropropane)
ug/L
<1.2
10.0
1.2
10/17/23 11:54
2,3,4,6-Tetrachlorophenol
ug/L
<1.5
10.0
1.5
10/17/23 11:54
2,4,5-Trichlorophenol
ug/L
<1.4
10.0
1.4
10/17/23 11:54
v1
2,4,6-Trichlorophenol
ug/L
<1.6
10.0
1.6
10/17/23 11:54
2,4-Dichlorophenol
ug/L
<1.4
10.0
1.4
10/17/23 11:54
2,4-Dimethylphenol
ug/L
<1.7
10.0
1.7
10/17/23 11:54
2,4-Dinitrophenol
ug/L
<26.0
50.0
26.0
10/17/23 11:54
2,4-Dinitrotoluene
ug/L
<1.6
10.0
1.6
10/17/23 11:54
2,6-Dichlorophenol
ug/L
<4.2
10.0
4.2
10/17/23 11:54
2,6-Dinitrotoluene
ug/L
<1.7
10.0
1.7
10/17/23 11:54
2-Acetylaminofluorene
ug/L
<4.1
10.0
4.1
10/17/23 11:54
2-Chloronaphthalene
ug/L
<1.7
10.0
1.7
10/17/23 11:54
2-Chlorophenol
ug/L
<1.2
10.0
1.2
10/17/23 11:54
2-Methylnaphthalene
ug/L
<1.9
10.0
1.9
10/17/23 11:54
2-Methylphenol(o-Cresol)
ug/L
<1.9
10.0
1.9
10/17/23 11:54
2-Naphthalenamine
ug/L
<5.4
10.0
5.4
10/17/23 11:54
2-Nitroaniline
ug/L
<3.0
20.0
3.0
10/17/23 11:54
2-Nitrophenol
ug/L
<1.4
10.0
1.4
10/17/23 11:54
v1
3&4-Methyl phenol (m&p Cresol)
ug/L
<1.2
10.0
1.2
10/17/23 11:54
3,3'-Dichlorobenzidine
ug/L
<8.1
20.0
8.1
10/17/23 11:54
3,3'-Dimethylbenzidine
ug/L
<31.1
50.0
31.1
10/17/23 11:54
IH,v1
3-Methylcholanthrene
ug/L
<3.7
10.0
3.7
10/17/23 11:54
3-Nitroaniline
ug/L
<3.8
20.0
3.8
10/17/23 11:54
4,6-Dinitro-2-methyl phenol
ug/L
<7.8
20.0
7.8
10/17/23 11:54
4-Aminobiphenyl
ug/L
<4.7
10.0
4.7
10/17/23 11:54
4-Bromophenylphenyl ether
ug/L
<1.8
10.0
1.8
10/17/23 11:54
4-ChIoro-3-methyl phenol
ug/L
<3.3
10.0
3.3
10/17/23 11:54
4-Chloroaniline
ug/L
<3.6
20.0
3.6
10/17/23 11:54
4-Chlorophenylphenyl ether
ug/L
<2.0
10.0
2.0
10/17/23 11:54
4-Nitroaniline
ug/L
<5.1
20.0
5.1
10/17/23 11:54
4-Nitrophenol
ug/L
<6.6
50.0
6.6
10/17/23 11:54
5-Nitro-o-toluidine
ug/L
<3.8
10.0
3.8
10/17/23 11:54
7,12-Dimethylbenz(a)anthracene
ug/L
<3.0
10.0
3.0
10/17/23 11:54
Acenaphthene
ug/L
<2.0
10.0
2.0
10/17/23 11:54
Acenaphthylene
ug/L
<2.0
10.0
2.0
10/17/23 11:54
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 159 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
METHOD BLANK: 4176150
Associated Lab Samples: 92691921015
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Acetophenone
ug/L
<1.5
10.0
1.5
10/17/23 11:54
Anthracene
ug/L
<2.3
10.0
2.3
10/17/23 11:54
Benzo(a)anthracene
ug/L
<2.7
10.0
2.7
10/17/23 11:54
Benzo(a)pyrene
ug/L
<2.8
10.0
2.8
10/17/23 11:54
Benzo(b)fluoranthene
ug/L
<2.6
10.0
2.6
10/17/23 11:54
Benzo(g,h,i)perylene
ug/L
<2.8
10.0
2.8
10/17/23 11:54
Benzo(k)fluoranthene
ug/L
<2.7
10.0
2.7
10/17/23 11:54
Benzyl alcohol
ug/L
<2.9
20.0
2.9
10/17/23 11:54
bis(2-Chloroethoxy)methane
ug/L
<1.8
10.0
1.8
10/17/23 11:54
bis(2-Chloroethyl) ether
ug/L
<1.9
10.0
1.9
10/17/23 11:54
bis(2-Ethylhexyl)phthalate
ug/L
<3.7
6.0
3.7
10/17/23 11:54
Butylbenzylphthalate
ug/L
<3.1
10.0
3.1
10/17/23 11:54
Chlorobenzilate
ug/L
<3.8
10.0
3.8
10/17/23 11:54
Chrysene
ug/L
<2.8
10.0
2.8
10/17/23 11:54
Di-n-butylphthalate
ug/L
<2.2
10.0
2.2
10/17/23 11:54
Di-n-octylphthalate
ug/L
<3.9
10.0
3.9
10/17/23 11:54
Diallate
ug/L
<3.4
10.0
3.4
10/17/23 11:54
Dibenz(a,h)anthracene
ug/L
<3.0
10.0
3.0
10/17/23 11:54
Dibenzofuran
ug/L
<2.1
10.0
2.1
10/17/23 11:54
Diethylphthalate
ug/L
<2.0
10.0
2.0
10/17/23 11:54
Dimethoate
ug/L
<3.7
10.0
3.7
10/17/23 11:54
Dimethylphthalate
ug/L
<2.1
10.0
2.1
10/17/23 11:54
Diphenylamine
ug/L
<3.0
10.0
3.0
10/17/23 11:54
Disulfoton
ug/L
<4.6
10.0
4.6
10/17/23 11:54
Ethyl methanesulfonate
ug/L
<3.0
20.0
3.0
10/17/23 11:54
Famphur
ug/L
<6.1
10.0
6.1
10/17/23 11:54
Fluoranthene
ug/L
<2.2
10.0
2.2
10/17/23 11:54
Fluorene
ug/L
<2.1
10.0
2.1
10/17/23 11:54
Hexachlorobenzene
ug/L
<2.2
10.0
2.2
10/17/23 11:54
Hexachlorocyclopentadiene
ug/L
<1.6
10.0
1.6
10/17/23 11:54
Hexachloroethane
ug/L
<1.4
10.0
1.4
10/17/23 11:54
Hexachloropropene
ug/L
<2.7
10.0
2.7
10/17/23 11:54
Indeno(1,2,3-cd)pyrene
ug/L
<2.9
10.0
2.9
10/17/23 11:54
Isodrin
ug/L
<2.8
10.0
2.8
10/17/23 11:54
Isophorone
ug/L
<1.7
10.0
1.7
10/17/23 11:54
Isosafrole
ug/L
<2.5
10.0
2.5
10/17/23 11:54
Kepone
ug/L
<14.1
20.0
14.1
10/17/23 11:54
Methapyrilene
ug/L
<17.0
50.0
17.0
10/17/23 11:54
Methyl methanesulfonate
ug/L
<3.1
5.0
3.1
10/17/23 11:54
Methyl parathion
ug/L
<3.7
10.0
3.7
10/17/23 11:54
N-Nitroso-di-n-butylamine
ug/L
<2.0
10.0
2.0
10/17/23 11:54
N-Nitroso-di-n-propylamine
ug/L
<1.3
10.0
1.3
10/17/23 11:54
N-Nitrosodiethylamine
ug/L
<2.3
10.0
2.3
10/17/23 11:54
N-Nitrosodimethylamine
ug/L
<1.9
10.0
1.9
10/17/23 11:54
N-Nitrosodiphenylamine
ug/L
<3.0
10.0
3.0
10/17/23 11:54
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
v1
v1
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 160 of 229

Pace Analytical Services, LLC
(A)`?a
/'L��le2225 Riverside Dr.
r Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
METHOD BLANK: 4176150
Associated Lab Samples: 92691921015
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Qualifiers
N-Nitrosomethylethylamine
ug/L
<7.5
10.0
7.5
10/17/23 11:54
N-Nitrosopiperidine
ug/L
<2.5
10.0
2.5
10/17/23 11:54
N-Nitrosopyrrolidine
ug/L
<3.1
10.0
3.1
10/17/23 11:54
Nitrobenzene
ug/L
<1.9
10.0
1.9
10/17/23 11:54
O,O,O-Triethylphosphorothioate
ug/L
<2.6
10.0
2.6
10/17/23 11:54
v1
O-Toluidine
ug/L
<2.6
10.0
2.6
10/17/23 11:54
P-Dimethylaminoazobenzene
ug/L
<2.4
5.0
2.4
10/17/23 11:54
IL
p-Phenylenediamine
ug/L
<10.0
10.0
10.0
10/17/23 11:54
Parathion (Ethyl parathion)
ug/L
<3.9
10.0
3.9
10/17/23 11:54
Pentachlorobenzene
ug/L
<3.4
10.0
3.4
10/17/23 11:54
v1
Pentachloronitrobenzene
ug/L
<3.3
10.0
3.3
10/17/23 11:54
v1
Pentachlorophenol
ug/L
<3.8
20.0
3.8
10/17/23 11:54
Phenacetin
ug/L
<3.6
10.0
3.6
10/17/23 11:54
Phenanthrene
ug/L
<2.0
10.0
2.0
10/17/23 11:54
Phenol
ug/L
<1.4
10.0
1.4
10/17/23 11:54
Phorate
ug/L
<3.6
10.0
3.6
10/17/23 11:54
Pronamide
ug/L
<3.1
10.0
3.1
10/17/23 11:54
Pyrene
ug/L
<2.2
10.0
2.2
10/17/23 11:54
Safrole
ug/L
<2.3
10.0
2.3
10/17/23 11:54
v1
Thionazin
ug/L
<2.9
10.0
2.9
10/17/23 11:54
2,4,6-Tribromophenol (S)
%
97
10-166
10/17/23 11:54
2-Fluorobiphenyl (S)
%
89
10-130
10/17/23 11:54
2-Fluorophenol (S)
%
64
10-130
10/17/23 11:54
Nitrobenzene-d5 (S)
%
82
10-133
10/17/23 11:54
Phenol-d6 (S)
%
45
10-130
10/17/23 11:54
Terphenyl-d14 (S)
%
100
10-193
10/17/23 11:54
LABORATORY CONTROL SAMPLE:
Parameter
4176151
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,2,4,5-Tetrachlorobenzene
ug/L
50
59.3
119
18-130
1,3,5-Trinitrobenzene
ug/L
50
35.0
70
59-200
1,3-Dinitrobenzene
ug/L
50
72.3
145
51-170
1,4-Naphthoquinone
ug/L
50
47.2
94
32-132
1-Naphthalenamine
ug/L
50
61.8
124
35-140
2,2'-Oxybis(1-chloropropane)
ug/L
50
54.4
109
23-130
2,3,4,6-Tetrachlorophenol
ug/L
50
60.0
120
38-154
2,4,5-Trichlorophenol
ug/L
50
63.5
127
36-150 v1
2,4,6-Trichlorophenol
ug/L
50
58.9
118
30-151
2,4-Dichlorophenol
ug/L
50
53.9
108
36-140
2,4-Dimethylphenol
ug/L
50
51.5
103
36-155
2,4-Dinitrophenol
ug/L
250
158
63
10-169
2,4-Dinitrotoluene
ug/L
50
59.5
119
46-160
2,6-Dichlorophenol
ug/L
50
63.3
127
34-156
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 161 of 229

Project: Jackson County Fall 2023
Pace Project No.: 92691921
LABORATORY CONTROL SAMPLE: 4176151
Parameter
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
2,6-Dinitrotoluene
ug/L
50
61.8
124
47-161
2-Acetylaminofluorene
ug/L
50
69.3
139
39-184
2-Chloronaphthalene
ug/L
50
46.3
93
29-134
2-Chlorophenol
ug/L
50
47.6
95
29-130
2-Methylnaphthalene
ug/L
50
47.3
95
26-130
2-Methylphenol(o-Cresol)
ug/L
50
43.7
87
32-130
2-Naphthalenamine
ug/L
50
63.9
128
23-145
2-Nitroaniline
ug/L
100
112
112
41-150
2-Nitrophenol
ug/L
50
55.1
110
31-145 v1
3&4-Methyl phenol (m&p Cresol)
ug/L
50
45.0
90
29-130
3,3'-Dichlorobenzidine
ug/L
100
135
135
46-153
3,3'-Dimethylbenzidine
ug/L
100
250
250
24-2001H,L1,v1
3-Methylcholanthrene
ug/L
50
72.0
144
31-195
3-Nitroaniline
ug/L
100
121
121
47-156
4,6-Dinitro-2-methyl phenol
ug/L
100
95.1
95
23-161
4-Aminobiphenyl
ug/L
50
64.1
128
26-151
4-Bromophenylphenyl ether
ug/L
50
52.5
105
45-143
4-Chloro-3-methylphenol
ug/L
100
112
112
42-143
4-Chloroaniline
ug/L
100
99.9
100
37-135
4-Chlorophenylphenyl ether
ug/L
50
58.6
117
43-140
4-Nitroaniline
ug/L
100
119
119
47-157
4-Nitrophenol
ug/L
250
146
58
10-130
5-Nitro-o-toluidine
ug/L
50
66.7
133
54-170
7,12-Dimethylbenz(a)anthracene
ug/L
50
62.3
125
29-176
Acenaphthene
ug/L
50
50.0
100
38-138
Acenaphthylene
ug/L
50
52.0
104
39-139
Acetophenone
ug/L
50
44.7
89
34-135
Anthracene
ug/L
50
51.1
102
45-136
Benzo(a)anthracene
ug/L
50
56.5
113
52-151
Benzo(a)pyrene
ug/L
50
59.9
120
46-165
Benzo(b)fluoranthene
ug/L
50
66.0
132
44-170
Benzo(g,h,i)perylene
ug/L
50
56.7
113
39-171
Benzo(k)fluoranthene
ug/L
50
58.7
117
43-168
Benzyl alcohol
ug/L
100
94.1
94
33-134
bis(2-Chloroethoxy)methane
ug/L
50
48.5
97
37-140
bis(2-Chloroethyl) ether
ug/L
50
43.6
87
33-136
bis(2-Ethylhexyl)phthalate
ug/L
50
60.0
120
50-169
Butylbenzylphthalate
ug/L
50
62.2
124
50-174
Chlorobenzilate
ug/L
50
75.0
150
46-167
Chrysene
ug/L
50
55.6
111
52-148
Di-n-butylphthalate
ug/L
50
56.6
113
51-154
Di-n-octylphthalate
ug/L
50
68.5
137
44-170
Diallate
ug/L
50
54.6
109
49-147
Dibenz(a,h)anthracene
ug/L
50
57.8
116
41-171
Dibenzofuran
ug/L
50
52.3
105
42-157
Diethylphthalate
ug/L
50
57.5
115
50-149
Dimethoate
ug/L
50
67.7
135
52-169
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 162 of 229

Pace Analytical Services, LLC
(A)`?a
/'L��le2225 Riverside Dr.
r Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
LABORATORY CONTROL SAMPLE:
Parameter
4176151
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Dimethylphthalate
ug/L
50
55.7
111
47-146
Diphenylamine
ug/L
50
49.2
98
53-142
Disulfoton
ug/L
50
59.3
119
45-135
Ethyl methanesulfonate
ug/L
50
52.2
104
27-146
Famphur
ug/L
100
64.8
65
13-130
Fluoranthene
ug/L
50
55.4
111
51-152
Fluorene
ug/L
50
53.4
107
46-143
Hexachlorobenzene
ug/L
50
52.1
104
40-139
Hexachlorocyclopentadiene
ug/L
50
49.0
98
10-130 v1
Hexachloroethane
ug/L
50
26.8
54
10-130
Hexachloropropene
ug/L
50
38.0
76
10-130 v1
Indeno(1,2,3-cd)pyrene
ug/L
50
56.1
112
40-172
Isodrin
ug/L
50
62.7
125
50-150
Isophorone
ug/L
50
51.2
102
37-143
Isosafrole
ug/L
50
53.1
106
35-130
Kepone
ug/L
100
93.5
94
12-130 v1
Methapyrilene
ug/L
50
46.7J
93
10-188 v1
Methyl methanesulfonate
ug/L
50
44.8
90
24-135
Methyl parathion
ug/L
50
72.6
145
59-174
N-Nitroso-di-n-butylamine
ug/L
50
65.6
131
33-130 L1
N-Nitroso-di-n-propylamine
ug/L
50
51.9
104
38-145
N-Nitrosodiethylamine
ug/L
50
56.5
113
26-145
N-Nitrosodimethylamine
ug/L
50
38.8
78
30-130
N-Nitrosodiphenylamine
ug/L
50
49.2
98
46-144
N-Nitrosomethylethylamine
ug/L
50
52.2
104
19-138
N-Nitrosopiperidine
ug/L
50
60.5
121
35-147
N-Nitrosopyrrolidine
ug/L
50
55.2
110
31-142
Nitrobenzene
ug/L
50
45.2
90
33-136
O,O,O-Triethylphosphorothioate
ug/L
50
68.1
136
27-136 v1
O-Toluidine
ug/L
50
53.9
108
27-140
P-Dimethylaminoazobenzene
ug/L
50
32.0
64
23-130IL
p-Phenylenediamine
ug/L
<10.0
Parathion (Ethyl parathion)
ug/L
50
65.8
132
59-171
Pentachlorobenzene
ug/L
50
69.4
139
42-138 L1,v1
Pentachloronitrobenzene
ug/L
50
86.3
173
64-185 v1
Pentachlorophenol
ug/L
100
103
103
19-156
Phenacetin
ug/L
50
60.6
121
57-174
Phenanthrene
ug/L
50
51.9
104
49-143
Phenol
ug/L
50
30.8
62
18-130
Phorate
ug/L
50
44.0
88
41-200
Pronamide
ug/L
50
69.3
139
59-174
Pyrene
ug/L
50
57.3
115
48-156
Safrole
ug/L
50
59.1
118
31-136 v1
Thionazin
ug/L
50
67.3
135
52-151
2,4,6-Tribromophenol (S)
%
122
10-166
2-Fluorobiphenyl (S)
%
103
10-130
2-Fluorophenol(S)
%
74
10-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 163 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
LABORATORY CONTROL SAMPLE:
4176151
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Nitrobenzene-d5 (S)
%
103
10-133
Phenol-d6 (S)
%
61
10-130
Terphenyl-d14(S)
%
121
10-193
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4176152
4176153
MS
MSD
92691921015
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
1,2,4,5-Tetrachlorobenzene
ug/L
<4.5
100
100
117
105
117
105
10-136
11
30
1,3,5-Trinitrobenzene
ug/L
<5.5
100
100
73.3
59.6
73
60
32-200
21
30 v3
1,3-Dinitrobenzene
ug/L
<3.8
100
100
153
125
153
125
30-173
20
30
1,4-Naphthoquinone
ug/L
<4.4
100
100
105
87.6
105
88
10-144
18
30
1-Naphthalenamine
ug/L
<6.0
100
100
101
95.5
101
95
10-156
6
30
2,2'-Oxybis(1-
ug/L
<1.2
100
100
98.5
89.4
99
89
10-132
10
30
chloropropane)
2,3,4,6-Tetrachlorophenol
ug/L
<1.5
100
100
109
96.4
109
96
10-185
12
30
2,4,5-Trichlorophenol
ug/L
<1.4
100
100
123
107
123
107
10-174
14
30 v1
2,4,6-Trichlorophenol
ug/L
<1.6
100
100
113
96.0
113
96
10-173
17
30
2,4-Dichlorophenol
ug/L
<1.4
100
100
100
88.9
100
89
10-153
12
30
2,4-Dimethylphenol
ug/L
<1.7
100
100
92.7
86.3
93
86
12-157
7
30
2,4-Dinitrophenol
ug/L
<26.0
500
500
341
197
68
39
10-165
53
30 R1
2,4-Dinitrotoluene
ug/L
<1.6
100
100
109
98.3
109
98
29-168
10
30
2,6-Dichlorophenol
ug/L
<4.2
100
100
129
113
129
113
10-178
13
30
2,6-Dinitrotoluene
ug/L
<1.7
100
100
122
105
122
105
28-168
16
30
2-Acetylam inofl uorene
ug/L
<4.1
100
100
149
127
149
127
20-194
16
30
2-Chloronaphthalene
ug/L
<1.7
100
100
92.7
82.5
93
83
11-136
12
30
2-Chlorophenol
ug/L
<1.2
100
100
92.3
85.5
92
85
10-134
8
30
2-Methyl naphthalene
ug/L
<1.9
100
100
92.8
85.3
93
85
10-131
8
30
2-Methyl phenol(o-Cresol)
ug/L
<1.9
100
100
79.8
72.7
80
73
10-130
9
30
2-Naphthalenamine
ug/L
<5.4
100
100
84.7
77.2
85
77
10-147
9
30
2-Nitroaniline
ug/L
<3.0
200
200
213
182
106
91
19-156
16
30
2-Nitrophenol
ug/L
<1.4
100
100
100
94.4
100
94
10-160
6
30 v1
3&4-Methylphenol(m&p
ug/L
<1.2
100
100
86.2
74.0
86
74
10-132
15
30
Cresol)
3,3'-Dichlorobenzidine
ug/L
<8.1
200
200
240
212
120
106
10-173
13
30
3,3'-Dimethylbenzidine
ug/L
<31.1
200
200
455
447
228
223
10-200
2
30 IH,MO,
v1
3-Methylcholanthrene
ug/L
<3.7
100
100
144
118
144
118
10-200
20
30
3-Nitroaniline
ug/L
<3.8
200
200
229
199
115
99
19-169
14
30
4,6-Dinitro-2-methylphenol
ug/L
<7.8
200
200
199
162
99
81
10-178
20
30
4-Aminobiphenyl
ug/L
<4.7
100
100
113
110
113
110
10-170
3
30
4-Bromophenylphenyl ether
ug/L
<1.8
100
100
108
94.2
108
94
28-149
14
30
4-Chloro-3-methylphenol
ug/L
<3.3
200
200
215
185
108
92
18-148
15
30
4-Chloroaniline
ug/L
<3.6
200
200
182
169
91
84
10-141
8
30
4-Chlorophenylphenyl ether
ug/L
<2.0
100
100
109
97.8
109
98
24-144
11
30
4-Nitroaniline
ug/L
<5.1
200
200
224
201
112
100
18-170
11
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 164 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4176152
MS
92691921015 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
4176153
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
4-Nitrophenol
ug/L
<6.6
500
500
292
239
58
48
10-130
20
30
5-Nitro-o-toluidine
ug/L
<3.8
100
100
130
115
130
115
38-167
12
30
7,12-
ug/L
<3.0
100
100
125
105
125
105
10-182
17
30
Dimethylbenz(a)anthracene
Acenaphthene
ug/L
<2.0
100
100
94.7
84.4
95
84
18-142
11
30
Acenaphthylene
ug/L
<2.0
100
100
101
88.2
101
88
18-143
13
30
Acetophenone
ug/L
<1.5
100
100
88.5
75.4
89
75
10-142
16
30
Anthracene
ug/L
<2.3
100
100
97.3
86.4
97
86
32-138
12
30
Benzo(a)anth race ne
ug/L
<2.7
100
100
107
93.2
107
93
41-155
14
30
Benzo(a)pyrene
ug/L
<2.8
100
100
109
94.9
109
95
10-167
13
30
Benzo(b)fluoranthene
ug/L
<2.6
100
100
123
104
123
104
31-172
17
30
Benzo(g,h,i)perylene
ug/L
<2.8
100
100
104
93.1
104
93
26-177
11
30
Benzo(k)fluoranthene
ug/L
<2.7
100
100
106
92.2
106
92
31-168
14
30
Benzyl alcohol
ug/L
<2.9
200
200
185
165
92
82
10-136
11
30
bis(2-
ug/L
<1.8
100
100
83.7
79.6
84
80
12-143
5
30
Chloroethoxy)methane
bis(2-Chloroethyl) ether
ug/L
<1.9
100
100
83.5
76.3
84
76
10-139
9
30
bis(2- Ethyl hexyl)phthalate
ug/L
<3.7
100
100
116
98.9
116
99
41-173
16
30
Butylbenzylphthalate
ug/L
<3.1
100
100
118
100
118
100
38-182
17
30
Chlorobenzilate
ug/L
<3.8
100
100
149
127
149
127
33-175
16
30
Chrysene
ug/L
<2.8
100
100
105
91.5
105
92
41-152
14
30
Di-n-butylphthalate
ug/L
<2.2
100
100
108
100
108
100
37-162
7
30
Di-n-octylphthalate
ug/L
<3.9
100
100
133
114
133
114
36-176
15
30
Diallate
ug/L
<3.4
100
100
113
95.3
113
95
26-155
17
30
Dibenz(a,h)anthracene
ug/L
<3.0
100
100
108
93.2
108
93
29-175
15
30
Dibenzofuran
ug/L
<2.1
100
100
95.2
86.8
95
87
23-144
9
30
Diethylphthalate
ug/L
<2.0
100
100
106
93.6
106
94
33-154
12
30
Dimethoate
ug/L
<3.7
100
100
133
115
133
115
41-169
15
30
Dimethylphthalate
ug/L
<2.1
100
100
111
92.4
111
92
29-150
18
30
Diphenylamine
ug/L
<3.0
100
100
99.0
86.5
99
87
34-146
13
30
Disulfoton
ug/L
<4.6
100
100
115
101
115
101
36-133
13
30
Ethyl methanesulfonate
ug/L
<3.0
100
100
104
94.8
104
95
10-147
9
30
Famphur
ug/L
<6.1
200
200
105
97.0
53
49
10-130
8
30
Fluoranthene
ug/L
<2.2
100
100
111
101
111
101
40-156
10
30
Fluorene
ug/L
<2.1
100
100
99.2
89.7
99
90
26-148
10
30
Hexachlorobenzene
ug/L
<2.2
100
100
105
92.5
105
92
27-145
13
30
Hexachlorocyclopentadiene
ug/L
<1.6
100
100
90.7
88.2
91
88
10-130
3
30 v1
Hexachloroethane
ug/L
<1.4
100
100
53.5
51.9
54
52
10-130
3
30
Hexachloropropene
ug/L
<2.7
100
100
81.8
88.0
82
88
10-130
7
30 v1
Indeno(1,2,3-cd)pyrene
ug/L
<2.9
100
100
105
90.5
105
91
28-176
15
30
Isodrin
ug/L
<2.8
100
100
134
121
134
121
33-153
10
30
Isophorone
ug/L
<1.7
100
100
88.4
84.9
88
85
14-145
4
30
Isosafrole
ug/L
<2.5
100
100
112
94.7
112
95
13-136
16
30
Kepone
ug/L
<14.1
200
200
169
140
85
70
10-130
19
30 v1
Methapyrilene
ug/L
<17.0
100
100
134
133
134
133
10-200
1
30 v1
Methyl methanesulfonate
ug/L
<3.1
100
100
91.7
80.6
92
81
10-138
13
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 165 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4176152 4176153
Parameter
Units
92691921015
Result
MS
Spike
Conc.
MSD
Spike
Conc.
Methyl parathion
ug/L
<3.7
100
100
N-Nitroso-di-n-butylamine
ug/L
<2.0
100
100
N-Nitroso-di-n-propylamine
ug/L
<1.3
100
100
N-Nitrosodiethylamine
ug/L
<2.3
100
100
N-Nitrosodimethylamine
ug/L
<1.9
100
100
N-Nitrosodiphenylamine
ug/L
<3.0
100
100
N-Nitrosomethylethylamine
ug/L
<7.5
100
100
N-Nitrosopiperidine
ug/L
<2.5
100
100
N-Nitrosopyrrolidine
ug/L
<3.1
100
100
Nitrobenzene
ug/L
<1.9
100
100
0,0,0-
ug/L
<2.6
100
100
Triethylphosphorothioate
O-Toluidine
ug/L
<2.6
100
100
P-
ug/L
<2.4
100
100
Dimethylaminoazobenzene
p-Phenylenediamine
ug/L
<10.0
Parathion (Ethyl parathion)
ug/L
<3.9
100
100
Pentachlorobenzene
ug/L
<3.4
100
100
Pentachloronitrobenzene
ug/L
<3.3
100
100
Pentachlorophenol
ug/L
<3.8
200
200
Phenacetin
ug/L
<3.6
100
100
Phenanthrene
ug/L
<2.0
100
100
Phenol
ug/L
<1.4
100
100
Phorate
ug/L
<3.6
100
100
Pronamide
ug/L
<3.1
100
100
Pyrene
ug/L
<2.2
100
100
Safrole
ug/L
<2.3
100
100
Thionazin
ug/L
<2.9
100
100
2,4,6-Tribromophenol (S)
%
2-Fluorobiphenyl (S)
%
2-Fluorophenol (S)
%
Nitrobenzene-d5 (S)
%
Phenol-d6 (S)
%
Terphenyl-d14 (S)
%
MS
Result
145
131
98.8
118
70.6
99.0
109
111
112
80.8
129
103
64.2
<20.0
141
135
169
195
127
98.9
59.0
90.2
140
107
120
131
MSD
Result
133
115
84.4
105
66.5
86.5
97.4
105
95.5
79.2
123
86.9
55.9
<20.0
126
121
148
164
109
85.6
56.6
78.7
119
93.9
109
115
MS
% Rec
145
131
99
118
71
99
109
111
112
81
129
103
64
141
135
169
97
127
99
59
90
140
107
120
131
119
97
73
87
56
109
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
MSD % Rec
% Rec Limits
133 44-177
115 14-133
84 12-149
105 10-148
67 10-130
87 29-149
97 10-139
105 14-151
96 14-143
79 10-145
123 10-142
87 10-137
56 17-130
126 45-174
121 20-143
148 39-186
82 10-178
109 36-185
86 36-146
57 10-130
79 26-200
119 40-181
94 42-156
109 10-142
115 31-159
94 10-166
77 10-130
60 10-130
76 10-133
49 10-130
87 10-193
Max
RPD RPD Qual
9 30
14 30
16 30
12 30
6 30
13 30
11 30
6 30
16 30
2 30
5 30 v1
17 30
14 30 IL
30
11 30
11 30 v1
14 30 v1
17 30
15 30
14 30
4 30
14 30
16 30
13 30
10 30 v1
13 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 166 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 806698 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E Water APP9 RV MSSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92692397002
METHOD BLANK: 4177232
Associated Lab Samples: 92692397002
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Qualifiers
1,2,4,5-Tetrachlorobenzene
ug/L
<4.5
10.0
4.5
10/17/23 13:10
1,3,5-Trinitrobenzene
ug/L
<5.5
10.0
5.5
10/17/23 13:10
v2
1,3-Dinitrobenzene
ug/L
<3.8
10.0
3.8
10/17/23 13:10
1,4-Naphthoquinone
ug/L
<4.4
5.0
4.4
10/17/23 13:10
1-Naphthalenamine
ug/L
<6.0
10.0
6.0
10/17/23 13:10
2,2'-Oxybis(1-chloropropane)
ug/L
<1.2
10.0
1.2
10/17/23 13:10
2,3,4,6-Tetrachlorophenol
ug/L
<1.5
10.0
1.5
10/17/23 13:10
2,4,5-Trichlorophenol
ug/L
<1.4
10.0
1.4
10/17/23 13:10
3g
2,4,6-Trichlorophenol
ug/L
<1.6
10.0
1.6
10/17/23 13:10
2,4-Dichlorophenol
ug/L
<1.4
10.0
1.4
10/17/23 13:10
2,4-Dimethylphenol
ug/L
<1.7
10.0
1.7
10/17/23 13:10
2,4-Dinitrophenol
ug/L
<26.0
50.0
26.0
10/17/23 13:10
2,4-Dinitrotoluene
ug/L
<1.6
10.0
1.6
10/17/23 13:10
2,6-Dichlorophenol
ug/L
<4.2
10.0
4.2
10/17/23 13:10
2,6-Dinitrotoluene
ug/L
<1.7
10.0
1.7
10/17/23 13:10
2-Acetylaminofluorene
ug/L
<4.1
10.0
4.1
10/17/23 13:10
2-Chloronaphthalene
ug/L
<1.7
10.0
1.7
10/17/23 13:10
2-Chlorophenol
ug/L
<1.2
10.0
1.2
10/17/23 13:10
2-Methylnaphthalene
ug/L
<1.9
10.0
1.9
10/17/23 13:10
2-Methylphenol(o-Cresol)
ug/L
<1.9
10.0
1.9
10/17/23 13:10
2-Naphthalenamine
ug/L
<5.4
10.0
5.4
10/17/23 13:10
2-Nitroaniline
ug/L
<3.0
20.0
3.0
10/17/23 13:10
2-Nitrophenol
ug/L
<1.4
10.0
1.4
10/17/23 13:10
v1
3&4-Methyl phenol (m&p Cresol)
ug/L
<1.2
10.0
1.2
10/17/23 13:10
3,3'-Dichlorobenzidine
ug/L
<8.1
20.0
8.1
10/17/23 13:10
3,3'-Dimethylbenzidine
ug/L
<31.1
50.0
31.1
10/17/23 13:10
IH,v1
3-Methylcholanthrene
ug/L
<3.7
10.0
3.7
10/17/23 13:10
3-Nitroaniline
ug/L
<3.8
20.0
3.8
10/17/23 13:10
4,6-Dinitro-2-methyl phenol
ug/L
<7.8
20.0
7.8
10/17/23 13:10
4-Aminobiphenyl
ug/L
<4.7
10.0
4.7
10/17/23 13:10
4-Bromophenylphenyl ether
ug/L
<1.8
10.0
1.8
10/17/23 13:10
4-ChIoro-3-methyl phenol
ug/L
<3.3
10.0
3.3
10/17/23 13:10
4-Chloroaniline
ug/L
<3.6
20.0
3.6
10/17/23 13:10
4-Chlorophenylphenyl ether
ug/L
<2.0
10.0
2.0
10/17/23 13:10
4-Nitroaniline
ug/L
<5.1
20.0
5.1
10/17/23 13:10
4-Nitrophenol
ug/L
<6.6
50.0
6.6
10/17/23 13:10
5-Nitro-o-toluidine
ug/L
<3.8
10.0
3.8
10/17/23 13:10
7,12-Dimethylbenz(a)anthracene
ug/L
<3.0
10.0
3.0
10/17/23 13:10
Acenaphthene
ug/L
<2.0
10.0
2.0
10/17/23 13:10
Acenaphthylene
ug/L
<2.0
10.0
2.0
10/17/23 13:10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 167 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
METHOD BLANK: 4177232
Associated Lab Samples: 92692397002
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Acetophenone
ug/L
<1.5
10.0
1.5
10/17/23 13:10
Anthracene
ug/L
<2.3
10.0
2.3
10/17/23 13:10
Benzo(a)anthracene
ug/L
<2.7
10.0
2.7
10/17/23 13:10
Benzo(a)pyrene
ug/L
<2.8
10.0
2.8
10/17/23 13:10
Benzo(b)fluoranthene
ug/L
<2.6
10.0
2.6
10/17/23 13:10
Benzo(g,h,i)perylene
ug/L
<2.8
10.0
2.8
10/17/23 13:10
Benzo(k)fluoranthene
ug/L
<2.7
10.0
2.7
10/17/23 13:10
Benzyl alcohol
ug/L
<2.9
20.0
2.9
10/17/23 13:10
bis(2-Chloroethoxy)methane
ug/L
<1.8
10.0
1.8
10/17/23 13:10
bis(2-Chloroethyl) ether
ug/L
<1.9
10.0
1.9
10/17/23 13:10
bis(2-Ethylhexyl)phthalate
ug/L
<3.7
6.0
3.7
10/17/23 13:10
Butylbenzylphthalate
ug/L
<3.1
10.0
3.1
10/17/23 13:10
Chlorobenzilate
ug/L
<3.8
10.0
3.8
10/17/23 13:10
Chrysene
ug/L
<2.8
10.0
2.8
10/17/23 13:10
Di-n-butylphthalate
ug/L
<2.2
10.0
2.2
10/17/23 13:10
Di-n-octylphthalate
ug/L
<3.9
10.0
3.9
10/17/23 13:10
Diallate
ug/L
<3.4
10.0
3.4
10/17/23 13:10
Dibenz(a,h)anthracene
ug/L
<3.0
10.0
3.0
10/17/23 13:10
Dibenzofuran
ug/L
<2.1
10.0
2.1
10/17/23 13:10
Diethylphthalate
ug/L
<2.0
10.0
2.0
10/17/23 13:10
Dimethoate
ug/L
<3.7
10.0
3.7
10/17/23 13:10
Dimethylphthalate
ug/L
<2.1
10.0
2.1
10/17/23 13:10
Diphenylamine
ug/L
<3.0
10.0
3.0
10/17/23 13:10
Disulfoton
ug/L
<4.6
10.0
4.6
10/17/23 13:10
Ethyl methanesulfonate
ug/L
<3.0
20.0
3.0
10/17/23 13:10
Famphur
ug/L
<6.1
10.0
6.1
10/17/23 13:10
Fluoranthene
ug/L
<2.2
10.0
2.2
10/17/23 13:10
Fluorene
ug/L
<2.1
10.0
2.1
10/17/23 13:10
Hexachlorobenzene
ug/L
<2.2
10.0
2.2
10/17/23 13:10
Hexachlorocyclopentadiene
ug/L
<1.6
10.0
1.6
10/17/23 13:10
Hexachloroethane
ug/L
<1.4
10.0
1.4
10/17/23 13:10
Hexachloropropene
ug/L
<2.7
10.0
2.7
10/17/23 13:10
Indeno(1,2,3-cd)pyrene
ug/L
<2.9
10.0
2.9
10/17/23 13:10
Isodrin
ug/L
<2.8
10.0
2.8
10/17/23 13:10
Isophorone
ug/L
<1.7
10.0
1.7
10/17/23 13:10
Isosafrole
ug/L
<2.5
10.0
2.5
10/17/23 13:10
Kepone
ug/L
<14.1
20.0
14.1
10/17/23 13:10
Methapyrilene
ug/L
<17.0
50.0
17.0
10/17/23 13:10
Methyl methanesulfonate
ug/L
<3.1
5.0
3.1
10/17/23 13:10
Methyl parathion
ug/L
<3.7
10.0
3.7
10/17/23 13:10
N-Nitroso-di-n-butylamine
ug/L
<2.0
10.0
2.0
10/17/23 13:10
N-Nitroso-di-n-propylamine
ug/L
<1.3
10.0
1.3
10/17/23 13:10
N-Nitrosodiethylamine
ug/L
<2.3
10.0
2.3
10/17/23 13:10
N-Nitrosodimethylamine
ug/L
<1.9
10.0
1.9
10/17/23 13:10
N-Nitrosodiphenylamine
ug/L
<3.0
10.0
3.0
10/17/23 13:10
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
v1
v1
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 168 of 229

Pace Analytical Services, LLC
(A)`?a
/'L��le2225 Riverside Dr.
r Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
METHOD BLANK: 4177232
Associated Lab Samples: 92692397002
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Qualifiers
N-Nitrosomethylethylamine
ug/L
<7.5
10.0
7.5
10/17/23 13:10
N-Nitrosopiperidine
ug/L
<2.5
10.0
2.5
10/17/23 13:10
N-Nitrosopyrrolidine
ug/L
<3.1
10.0
3.1
10/17/23 13:10
Nitrobenzene
ug/L
<1.9
10.0
1.9
10/17/23 13:10
O,O,O-Triethylphosphorothioate
ug/L
<2.6
10.0
2.6
10/17/23 13:10
v1
O-Toluidine
ug/L
<2.6
10.0
2.6
10/17/23 13:10
P-Dimethylaminoazobenzene
ug/L
<2.4
5.0
2.4
10/17/23 13:10
IL
p-Phenylenediamine
ug/L
<10.0
10.0
10.0
10/17/23 13:10
Parathion (Ethyl parathion)
ug/L
<3.9
10.0
3.9
10/17/23 13:10
Pentachlorobenzene
ug/L
<3.4
10.0
3.4
10/17/23 13:10
v1
Pentachloronitrobenzene
ug/L
<3.3
10.0
3.3
10/17/23 13:10
v1
Pentachlorophenol
ug/L
<3.8
20.0
3.8
10/17/23 13:10
Phenacetin
ug/L
<3.6
10.0
3.6
10/17/23 13:10
Phenanthrene
ug/L
<2.0
10.0
2.0
10/17/23 13:10
Phenol
ug/L
<1.4
10.0
1.4
10/17/23 13:10
Phorate
ug/L
<3.6
10.0
3.6
10/17/23 13:10
Pronamide
ug/L
<3.1
10.0
3.1
10/17/23 13:10
Pyrene
ug/L
<2.2
10.0
2.2
10/17/23 13:10
Safrole
ug/L
<2.3
10.0
2.3
10/17/23 13:10
v1
Thionazin
ug/L
<2.9
10.0
2.9
10/17/23 13:10
2,4,6-Tribromophenol (S)
%
137
10-166
10/17/23 13:10
2-Fluorobiphenyl (S)
%
109
10-130
10/17/23 13:10
2-Fluorophenol (S)
%
89
10-130
10/17/23 13:10
Nitrobenzene-d5 (S)
%
115
10-133
10/17/23 13:10
Phenol-d6 (S)
%
59
10-130
10/17/23 13:10
Terphenyl-d14 (S)
%
111
10-193
10/17/23 13:10
LABORATORY CONTROL SAMPLE & LCSD:
Parameter
4177233
Spike
Units Conc.
4177234
LCS LCSD
Result Result
LCS
% Rec
LCSD
% Rec
% Rec
Limits
RPD
Max
RPD Qualifiers
1,2,4,5-Tetrachlorobenzene
ug/L
50
48.2
58.3
96
117
18-130
19
30
1,3,5-Trinitrobenzene
ug/L
50
33.9
38.2
68
76
59-200
12
30 v3
1,3-Dinitrobenzene
ug/L
50
60.2
72.5
120
145
51-170
19
30
1,4-Naphthoquinone
ug/L
50
37.9
46.7
76
93
32-132
21
30
1-Naphthalenamine
ug/L
50
39.8
42.4
80
85
35-140
6
30
2,2'-Oxybis(1-chloropropane)
ug/L
50
45.0
54.2
90
108
23-130
19
30
2,3,4,6-Tetrachlorophenol
ug/L
50
51.7
60.2
103
120
38-154
15
30
2,4,5-Trichlorophenol
ug/L
50
49.4
61.3
99
123
36-150
22
30 v1
2,4,6-Trichlorophenol
ug/L
50
44.8
57.4
90
115
30-151
25
30
2,4-Dichlorophenol
ug/L
50
41.3
57.8
83
116
36-140
33
30 R1
2,4-Dimethylphenol
ug/L
50
40.1
55.2
80
110
36-155
32
30 R1
2,4-Dinitrophenol
ug/L
250
260
303
104
121
10-169
15
30
2,4-Dinitrotoluene
ug/L
50
54.4
62.3
109
125
46-160
13
30
2,6-Dichlorophenol
ug/L
50
49.4
67.0
99
134
34-156
30
30
Results presented on this page are in the
units indicated by the "Units"
column except where an alternate unit is
presented to the right of the
result.
REPORT OF LABORATORY ANALYSIS
This report shall
not be reproduced, except in full,
Date: 02/23/2024 01:48 PM
without the written consent
of Pace Analytical Services,
LLC.
Page 169 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
LABORATORY CONTROL SAMPLE & LCSD:
4177233
4177234
Spike
LCS
LCSD
LCS
LCSD
% Rec
Max
Parameter
Units
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qualifiers
2,6-Dinitrotoluene
ug/L
50
50.2
63.4
100
127
47-161
23
30
2-Acetylaminofluorene
ug/L
50
65.7
69.9
131
140
39-184
6
30
2-Chloronaphthalene
ug/L
50
37.3
48.0
75
96
29-134
25
30
2-Chlorophenol
ug/L
50
40.0
49.8
80
100
29-130
22
30
2-Methylnaphthalene
ug/L
50
41.1
51.2
82
102
26-130
22
30
2-Methylphenol(o-Cresol)
ug/L
50
34.4
44.6
69
89
32-130
26
30
2-Naphthalenamine
ug/L
50
47.3
52.2
95
104
23-145
10
30
2-Nitroaniline
ug/L
100
88.6
108
89
108
41-150
20
30
2-Nitrophenol
ug/L
50
44.4
60.1
89
120
31-145
30
30 v1
3&4-Methyl phenol (m&p Cresol)
ug/L
50
37.2
44.2
74
88
29-130
17
30
3,3'-Dichlorobenzidine
ug/L
100
125
138
125
138
46-153
10
30
3,3'-Dimethylbenzidine
ug/L
100
<31.1
<31.1
11
5
24-200
30 IH,L2,v1
3-Methylcholanthrene
ug/L
50
69.2
73.6
138
147
31-195
6
30
3-Nitroaniline
ug/L
100
104
120
104
120
47-156
14
30
4,6-Dinitro-2-methyl phenol
ug/L
100
104
117
104
117
23-161
11
30
4-Aminobiphenyl
ug/L
50
43.8
46.7
88
93
26-151
6
30
4-Bromophenylphenyl ether
ug/L
50
46.1
56.1
92
112
45-143
19
30
4-Chloro-3-methylphenol
ug/L
100
84.1
114
84
114
42-143
30
30
4-Chloroaniline
ug/L
100
75.2
100
75
100
37-135
28
30
4-Chlorophenylphenyl ether
ug/L
50
44.8
58.2
90
116
43-140
26
30
4-Nitroaniline
ug/L
100
116
130
116
130
47-157
12
30
4-Nitrophenol
ug/L
250
155
174
62
70
10-130
11
30
5-Nitro-o-toluidine
ug/L
50
62.5
68.0
125
136
54-170
9
30
7,12-Dimethylbenz(a)anthracene
ug/L
50
59.3
63.2
119
126
29-176
6
30
Acenaphthene
ug/L
50
37.7
50.1
75
100
38-138
28
30
Acenaphthylene
ug/L
50
39.1
51.9
78
104
39-139
28
30
Acetophenone
ug/L
50
37.0
45.9
74
92
34-135
21
30
Anthracene
ug/L
50
47.4
53.1
95
106
45-136
11
30
Benzo(a)anthracene
ug/L
50
55.0
60.4
110
121
52-151
9
30
Benzo(a)pyrene
ug/L
50
58.0
62.3
116
125
46-165
7
30
Benzo(b)fluoranthene
ug/L
50
59.5
69.7
119
139
44-170
16
30
Benzo(g,h,i)perylene
ug/L
50
52.2
56.6
104
113
39-171
8
30
Benzo(k)fluoranthene
ug/L
50
54.6
61.4
109
123
43-168
12
30
Benzyl alcohol
ug/L
100
77.2
97.1
77
97
33-134
23
30
bis(2-Chloroethoxy)methane
ug/L
50
37.7
50.1
75
100
37-140
28
30
bis(2-Chloroethyl) ether
ug/L
50
38.9
45.0
78
90
33-136
15
30
bis(2-Ethylhexyl)phthalate
ug/L
50
59.6
65.6
119
131
50-169
10
30
Butylbenzylphthalate
ug/L
50
58.7
64.1
117
128
50-174
9
30
Chlorobenzilate
ug/L
50
71.9
76.9
144
154
46-167
7
30
Chrysene
ug/L
50
54.5
60.0
109
120
52-148
10
30
Di-n-butylphthalate
ug/L
50
54.6
60.2
109
120
51-154
10
30
Di-n-octylphthalate
ug/L
50
65.3
73.1
131
146
44-170
11
30
Diallate
ug/L
50
48.7
56.9
97
114
49-147
16
30
Dibenz(a,h)anthracene
ug/L
50
55.8
57.6
112
115
41-171
3
30
Dibenzofuran
ug/L
50
39.5
51.6
79
103
42-157
26
30
Diethylphthalate
ug/L
50
51.5
59.2
103
118
50-149
14
30
Dimethoate
ug/L
50
67.4
73.2
135
146
52-169
8
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 170 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
LABORATORY CONTROL SAMPLE & LCSD:
4177233
4177234
Spike
LCS
LCSD
LCS
LCSD
% Rec
Max
Parameter
Units
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qualifiers
Dimethylphthalate
ug/L
50
46.8
56.7
94
113
47-146
19
30
Diphenylamine
ug/L
50
45.8
53.5
92
107
53-142
15
30
Disulfoton
ug/L
50
51.4
57.3
103
115
45-135
11
30
Ethyl methanesulfonate
ug/L
50
42.3
50.5
85
101
27-146
18
30
Famphur
ug/L
100
99.5
121
100
121
13-130
20
30
Fluoranthene
ug/L
50
56.9
62.0
114
124
51-152
9
30
Fluorene
ug/L
50
42.8
53.4
86
107
46-143
22
30
Hexachlorobenzene
ug/L
50
47.9
55.6
96
111
40-139
15
30
Hexachlorocyclopentadiene
ug/L
50
44.3
54.6
89
109
10-130
21
30 v1
Hexachloroethane
ug/L
50
28.1
30.8
56
62
10-130
9
30
Hexachloropropene
ug/L
50
35.7
41.3
71
83
10-130
14
30 v1
Indeno(1,2,3-cd)pyrene
ug/L
50
54.1
55.2
108
110
40-172
2
30
Isodrin
ug/L
50
62.1
68.6
124
137
50-150
10
30
Isophorone
ug/L
50
38.8
52.4
78
105
37-143
30
30
Isosafrole
ug/L
50
39.8
52.3
80
105
35-130
27
30
Kepone
ug/L
100
113
144
113
144
12-130
24
30 L1,v1
Methapyrilene
ug/L
50
<17.0
<17.0
9
6
10-188
30 L2,v1
Methyl methanesulfonate
ug/L
50
38.4
46.3
77
93
24-135
19
30
Methyl parathion
ug/L
50
70.7
77.3
141
155
59-174
9
30
N-Nitroso-di-n-butylamine
ug/L
50
46.4
65.3
93
131
33-130
34
30 L1,R1
N-Nitroso-di-n-propylamine
ug/L
50
42.2
51.1
84
102
38-145
19
30
N-Nitrosodiethylamine
ug/L
50
46.7
59.3
93
119
26-145
24
30
N-Nitrosodimethylamine
ug/L
50
33.1
40.2
66
80
30-130
19
30
N-Nitrosodiphenylamine
ug/L
50
45.8
53.5
92
107
46-144
15
30
N-Nitrosomethylethylamine
ug/L
50
47.0
56.5
94
113
19-138
18
30
N-Nitrosopiperidine
ug/L
50
47.3
60.7
95
121
35-147
25
30
N-Nitrosopyrrolidine
ug/L
50
43.1
54.6
86
109
31-142
23
30
Nitrobenzene
ug/L
50
36.5
45.9
73
92
33-136
23
30
O,O,O-Triethylphosphorothioate
ug/L
50
52.7
70.3
105
141
27-136
29
30 L1,v1
O-Toluidine
ug/L
50
40.5
47.1
81
94
27-140
15
30
P-Dimethylaminoazobenzene
ug/L
50
31.4
32.6
63
65
23-130
4
30 IL
p-Phenylenediamine
ug/L
<10.0
<10.0
30
Parathion (Ethyl parathion)
ug/L
50
66.5
71.2
133
142
59-171
7
30
Pentachlorobenzene
ug/L
50
51.2
66.8
102
134
42-138
26
30 v1
Pentachloronitrobenzene
ug/L
50
78.4
86.3
157
173
64-185
10
30 v1
Pentachlorophenol
ug/L
100
98.9
111
99
111
19-156
11
30
Phenacetin
ug/L
50
61.9
66.7
124
133
57-174
8
30
Phenanthrene
ug/L
50
47.7
53.8
95
108
49-143
12
30
Phenol
ug/L
50
25.9
30.2
52
60
18-130
15
30
Phorate
ug/L
50
39.8
44.9
80
90
41-200
12
30
Pronamide
ug/L
50
67.2
72.0
134
144
59-174
7
30
Pyrene
ug/L
50
54.8
61.4
110
123
48-156
11
30
Safrole
ug/L
50
46.8
61.0
94
122
31-136
26
30 v1
Thionazin
ug/L
50
61.7
69.8
123
140
52-151
12
30
2,4,6-Tribromophenol (S)
%
138
148
10-166
2-Fluorobiphenyl (S)
%
94
113
10-130
2-Fluorophenol(S)
%
76
91
10-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 171 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE & LCSD:
4177233
4177234
Spike
LCS LCSD LCS LCSD
% Rec Max
Parameter
Units Conc.
Result Result % Rec % Rec
Limits RPD RPD Qualifiers
Nitrobenzene-d5 (S)
%
96 109
10-133
Phenol-d6 (S)
%
59 67
10-130
Terphenyl-d14 (S)
%
117 122
10-193
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 172 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 806167 Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92691980001, 92691980002, 92691980003, 92691980004
METHOD BLANK: 4174746 Matrix: Water
Associated Lab Samples: 92691980001, 92691980002, 92691980003, 92691980004
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Alkalinity, Total as CaCO3 mg/L <5.0 5.0 5.0 10/13/23 14:24
LABORATORY CONTROL SAMPLE: 4174747
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 52.8 106 80-120
LABORATORY CONTROL SAMPLE: 4174748
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 52.1 104 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4174749 4174750
MS MSD
92691980003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 43.4 50 50 95.7 97.4 105 108 80-120 2 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4174751 4174752
MS MSD
92691980004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 29.7 50 50 83.6 84.2 108 109 80-120 1 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 173 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 807249 Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92692397001, 92692397002, 92692397003
METHOD BLANK: 4180050 Matrix: Water
Associated Lab Samples: 92692397001, 92692397002, 92692397003
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Alkalinity, Total as CaCO3 mg/L <5.0 5.0 5.0 10/18/23 15:08
LABORATORY CONTROL SAMPLE: 4180051
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 49.2 98 80-120
LABORATORY CONTROL SAMPLE: 4180052
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 49.9 100 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4180053 4180054
MS MSD
92692476001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 23.0 50 50 71.5 71.4 97 97 80-120 0 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4180055 4180056
MS MSD
92692476002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L <5.0 50 50 51.7 50.2 97 94 80-120 3 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 174 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 807816 Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92691921015
METHOD BLANK: 4182938
Matrix:
Water
Associated Lab Samples: 92691921015
Blank
Reporting
Parameter
Units
Result
Limit
Alkalinity, Total as CaCO3
mg/L
<5.0
5.0
LABORATORY CONTROL SAMPLE:
4182939
Spike
LCS
Parameter
Units
Conc.
Result
Alkalinity, Total as CaCO3
mg/L
50
51.2
LABORATORY CONTROL SAMPLE:
4182940
Spike
LCS
Parameter
Units
Conc.
Result
Alkalinity, Total as CaCO3
mg/L
50
50.5
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
MDL Analyzed Qualifiers
5.0 10/20/23 11:29
LCS % Rec
% Rec Limits Qualifiers
102 80-120
LCS % Rec
% Rec Limits Qualifiers
101 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4182943 4182944
MS MSD
92693094001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 17.5 50 50 69.0 69.1 103 103 80-120 0 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4183232 4183233
MS MSD
92693094016 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 173 50 50 230 230 114 114 80-120 0 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 175 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QC Batch: 806831 Analysis Method: SM 3500-Fe B-2011
QC Batch Method: SM 3500-Fe B-2011 Analysis Description: Iron, Ferrous
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92691921015, 92691980001, 92691980002, 92691980003, 92691980004, 92692397001, 92692397002,
92692397003
METHOD BLANK: 4177968 Matrix: Water
Associated Lab Samples: 92691921015, 92691980001, 92691980002, 92691980003, 92691980004, 92692397001, 92692397002,
92692397003
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Iron, Ferrous mg/L 0.043J 0.50 0.040 10/17/23 11:22 N2
LABORATORY CONTROL SAMPLE:
4177969
Parameter
Units
Iron, Ferrous
mg/L
SAMPLE DUPLICATE: 4177970
Parameter
Units
Iron, Ferrous
mg/L
SAMPLE DUPLICATE: 4177971
Parameter
Units
Iron, Ferrous
mg/L
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
1.5 1.5 102 90-110 N2
92691980004 Dup Max
Result Result RPD RPD Qualifiers
0.054J 0.086J 10 H3,N2
92691980003 Dup Max
Result Result RPD RPD Qualifiers
0.068J 0.062J 10 H3,N2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 176 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QC Batch: 805139 Analysis Method: SM 4500-S2D-2011
QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92691921002, 92691921003, 92691921004, 92691980001, 92691980002, 92691980003, 92691980004,
92692397001,92692397002,92692397003
METHOD BLANK: 4169553 Matrix: Water
Associated Lab Samples: 92691921002, 92691921003, 92691921004, 92691980001, 92691980002, 92691980003, 92691980004,
92692397001,92692397002,92692397003
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Sulfide mg/L <0.022 0.10 0.022 10/11/23 01:15
LABORATORY CONTROL SAMPLE: 4169554
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide mg/L 0.5 0.53 105 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4169555 4169556
MS MSD
92691981001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND 0.5 0.5 0.55 0.58 107 113 80-120 6 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4169557 4169558
MS MSD
92691981003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND 0.5 0.5 0.55 0.56 106 109 80-120 3 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 177 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 807120 Analysis Method: SM 4500-S2D-2011
QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92691921015
METHOD BLANK: 4179433
Matrix:
Water
Associated Lab Samples: 92691921015
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
Sulfide
mg/L
<0.022
0.10
0.022 10/18/23 03:51
LABORATORY CONTROL SAMPLE:
4179434
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Sulfide
mg/L
0.5
0.47
94 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4179435 4179436
MS MSD
92692802001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND 0.5 0.5 0.54 0.53 103 101 80-120 2 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4179437 4179438
MS MSD
92693396007 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L 0.048J 0.5 0.5 0.48J 0.41J 86 72 80-120 10 D3,M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 178 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 804809 Analysis Method: SM 521 OB-2011
QC Batch Method: SM 521OB-2011 Analysis Description: 5210E BOD, 5 day
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92691980001, 92691980002, 92691980003, 92691980004
METHOD BLANK: 4168052 Matrix: Water
Associated Lab Samples: 92691980001, 92691980002, 92691980003, 92691980004
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
BOD, 5 day mg/L <2.0 2.0 2.0 10/12/23 00:48 2g
LABORATORY CONTROL SAMPLE: 4168053
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
BOD, 5 day mg/L 198 184 93 84.6-115 2g
SAMPLE DUPLICATE: 4168055
92691972001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
BOD, 5 day mg/L 1210 1250 3 25 2g
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 179 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 805413 Analysis Method: SM 521 OB-2011
QC Batch Method: SM 521OB-2011 Analysis Description: 5210E BOD, 5 day
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92692397001, 92692397002, 92692397003
METHOD BLANK: 4170817 Matrix: Water
Associated Lab Samples: 92692397001, 92692397002, 92692397003
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
BOD, 5 day mg/L <2.0 2.0 2.0 10/16/23 09:32
LABORATORY CONTROL SAMPLE: 4170819
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
BOD, 5 day mg/L 198 186 94 84.6-115
SAMPLE DUPLICATE: 4170820
92692397003 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
BOD, 5 day mg/L <2.0 <2.0 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 180 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 806318 Analysis Method: SM 521 OB-2016
QC Batch Method: SM 521OB-2016 Analysis Description: 5210E BOD, 5 day
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92691921015
METHOD BLANK: 4175757
Matrix:
Water
Associated Lab Samples: 92691921015
Blank
Reporting
Parameter
Units
Result
Limit
BOD, 5 day
mg/L
<2.0
2.0
LABORATORY CONTROL SAMPLE:
4175759
Spike
LCS
Parameter
Units
Conc.
Result
BOD, 5 day
mg/L
198
172
SAMPLE DUPLICATE: 4175760
92693223002
Dup
Parameter
Units
Result
Result
BOD, 5 day
mg/L
184
182
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
MDL Analyzed Qualifiers
2.0 10/19/23 03:58
LCS % Rec
% Rec Limits Qualifiers
87 84.6-115
Max
RPD RPD Qualifiers
1 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 181 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 807436 Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92691980001, 92691980002, 92691980003, 92691980004
METHOD BLANK: 4181121 Matrix: Water
Associated Lab Samples: 92691980001, 92691980002, 92691980003, 92691980004
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Chemical Oxygen Demand mg/L <12.5 25.0 12.5 10/19/23 23:54
LABORATORY CONTROL SAMPLE: 4181122
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chemical Oxygen Demand mg/L 750 774 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4181123 4181124
MS MSD
92692434001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand mg/L 29.6 100 100 127 132 97 102 90-110 4 3 R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4181125 4181126
MS MSD
92692903004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand mg/L 65.1 100 100 129 136 64 71 90-110 5 3 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 182 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 807437 Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92692397001, 92692397002, 92692397003
METHOD BLANK: 4181127 Matrix: Water
Associated Lab Samples: 92692397001, 92692397002, 92692397003
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Chemical Oxygen Demand mg/L <12.5 25.0 12.5 10/20/23 00:00
LABORATORY CONTROL SAMPLE: 4181128
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chemical Oxygen Demand mg/L 750 772 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4181129 4181130
MS MSD
92693356003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand mg/L 113 100 100 219 219 107 107 90-110 0 3
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4181131 4181132
MS MSD
92693653003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand mg/L 34.3 100 100 141 143 107 109 90-110 2 3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 183 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 808318 Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92691921015
METHOD BLANK: 4185383
Associated Lab Samples: 92691921015
Parameter Units
Chemical Oxygen Demand mg/L
LABORATORY CONTROL SAMPLE: 4185384
Parameter Units
Chemical Oxygen Demand mg/L
Matrix: Water
Blank Reporting
Result Limit
<12.5 25.0
Spike LCS
Conc. Result
750 751
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
MDL Analyzed Qualifiers
12.5 10/25/23 04:51
LCS % Rec
% Rec Limits Qualifiers
100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4185385 4185386
MS MSD
92693040002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand mg/L 30.2 100 100 140 140 109 109 90-110 0 3
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4185387 4185388
MS MSD
92693040004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand mg/L 30.2 100 100 133 135 102 105 90-110 2 3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 184 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 806612 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92691980001, 92691980002, 92691980003, 92691980004, 92692397001, 92692397002
METHOD BLANK: 4176620 Matrix: Water
Associated Lab Samples: 92691980001, 92691980002, 92691980003, 92691980004, 92692397001, 92692397002
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Organic Carbon mg/L <0.50 1.0 0.50 10/16/23 13:44
LABORATORY CONTROL SAMPLE: 4176621
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Organic Carbon mg/L 25 23.9 95 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4176622 4176623
MS MSD
92691932005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon mg/L 5.1 25 25 28.4 28.2 93 92 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4176624 4176625
MS MSD
92691980003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon mg/L 2.7 25 25 26.0 26.2 93 94 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 185 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 808120 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92692397003
METHOD BLANK: 4184356
Associated Lab Samples: 92692397003
Parameter Units
Total Organic Carbon mg/L
LABORATORY CONTROL SAMPLE: 4184357
Parameter Units
Total Organic Carbon mg/L
Matrix: Water
Blank Reporting
Result Limit
<0.50 1.0
Spike LCS
Conc. Result
25 23.6
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
MDL Analyzed Qualifiers
0.50 10/23/23 11:05
LCS % Rec
% Rec Limits Qualifiers
95 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4184358 4184359
MS MSD
92692560001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon mg/L ND 25 25 23.1 23.4 92 93 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4184360 4184361
MS MSD
92692560002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon mg/L ND 25 25 24.0 24.0 93 93 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 186 of 229

QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 808121 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92691921015
METHOD BLANK: 4184362
Associated Lab Samples: 92691921015
Parameter Units
Total Organic Carbon mg/L
LABORATORY CONTROL SAMPLE: 4184363
Parameter Units
Total Organic Carbon mg/L
Matrix: Water
Blank Reporting
Result Limit
<0.50 1.0
Spike LCS
Conc. Result
25 23.7
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
MDL Analyzed Qualifiers
0.50 10/23/23 20:52
LCS % Rec
% Rec Limits Qualifiers
95 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4184364 4184365
MS MSD
92693942002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon mg/L 3470 25 25 3420 3480 -176 36 90-110 2 10 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4184366 4184367
MS MSD
92692312001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon mg/L 4.0 25 25 28.7 24.3 99 81 90-110 17 10 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 187 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 804768 Analysis Method: EPA 9056A
QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92691980001, 92691980002, 92691980003, 92691980004
METHOD BLANK: 4167755
Matrix: Water
Associated Lab Samples:
92691980001, 92691980002, 92691980003, 92691980004
Blank Reporting
Parameter
Units
Result Limit
MDL Analyzed Qualifiers
Chloride
mg/L
<0.60 1.0
0.60 10/06/2317:13
Nitrate as N
mg/L
<0.060 0.10
0.060 10/06/23 17:13
Sulfate
mg/L
<0.50 1.0
0.50 10/06/2317:13
LABORATORY CONTROL SAMPLE: 4167756
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chloride mg/L 50 50.1 100 90-110
Nitrate as N mg/L 2.5 2.4 97 90-110
Sulfate mg/L 50 50.2 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4167757
4167758
MS
MSD
92691980001 Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter Units
Result Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD RPD Qual
Chloride mg/L
0.73J 50
50
55.0
54.7
109
108
90-110
0 10
Nitrate as N mg/L
0.22 2.5
2.5
2.9
2.9
108
107
90-110
1 10
Sulfate mg/L
0.80J 50
50
58.3
57.1
115
113
90-110
2 10 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 188 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 805361 Analysis Method: EPA 9056A
QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92692397001, 92692397002, 92692397003
METHOD BLANK: 4170555
Matrix: Water
Associated Lab Samples:
92692397001, 92692397002, 92692397003
Blank Reporting
Parameter
Units
Result Limit
MDL Analyzed Qualifiers
Chloride
mg/L
<0.60 1.0
0.60 10/10/2319:49
Nitrate as N
mg/L
<0.060 0.10
0.060 10/10/23 19:49
Sulfate
mg/L
<0.50 1.0
0.50 10/10/2319:49
LABORATORY CONTROL SAMPLE: 4170556
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chloride mg/L 50 52.0 104 90-110
Nitrate as N mg/L 2.5 2.5 100 90-110
Sulfate mg/L 50 52.3 105 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4170557
4170558
MS
MSD
92692397002 Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter Units
Result Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD RPD Qual
Chloride mg/L
67.7 50
50
110
111
85
86
90-110
1 10 M1
Nitrate as N mg/L
<0.060 2.5
2.5
2.4
2.5
96
98
90-110
3 10
Sulfate mg/L
<0.50 50
50
50.9
52.1
102
104
90-110
2 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 189 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Jackson County Fall 2023
Pace Project No.: 92691921
QC Batch: 806285 Analysis Method: EPA 9056A
QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92691921015
METHOD BLANK: 4175388
Matrix: Water
Associated Lab Samples: 92691921015
Blank Reporting
Parameter
Units
Result Limit
MDL Analyzed Qualifiers
Chloride
mg/L
<0.60 1.0
0.60 10/13/2318:32
Nitrate as N
mg/L
<0.060 0.10
0.060 10/13/23 18:32
Sulfate
mg/L
<0.50 1.0
0.50 10/13/2318:32
LABORATORY CONTROL SAMPLE: 4175389
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chloride mg/L 50 53.3 107 90-110
Nitrate as N mg/L 2.5 2.4 97 90-110
Sulfate mg/L 50 53.5 107 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4175390
4175391
MS
MSD
92691921015 Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter Units
Result Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD RPD Qual
Chloride mg/L
30.6 50
50
80.5
81.4
100
102
90-110
1 10
Nitrate as N mg/L
4.2 2.5
2.5
5.9
6.0
70
71
90-110
0 10 H1,M1
Sulfate mg/L
3.0 50
50
55.7
56.4
106
107
90-110
1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC.
Page 190 of 229

Pace Analytical Services, LLC
(A`?a
/'L��le2225 Riverside Dr.
r Asheville, NC 28804
[phone]
QUALIFIERS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
2g Readout not completed within method requirements, 5 days +/- 6 hours.
3g v1
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
H1 Analysis conducted outside the EPA method holding time.
H2 Extraction or preparation conducted outside EPA method holding time.
H3 Sample was received or analysis requested beyond the recognized method holding time.
IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.
IL This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be
considered an estimated value.
L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.
L2 Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 191 of 229

Pace Analytical Services, LLC
(A)`?a
/'L��le2225 Riverside Dr.
r Asheville, NC 28804
[phone]
QUALIFIERS
Project: Jackson County Fall 2023
Pace Project No.: 92691921
ANALYTE QUALIFIERS
P2 Re -extraction or re -analysis could not be performed due to insufficient sample amount.
P4 Sample field preservation does not meet EPA or method recommendations for this analysis.
R1 RPD value was outside control limits.
SO Surrogate recovery outside laboratory control limits.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 192 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Jackson County Fall 2023
92691921
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92691980001
MW-06-20231005
RSK 175 Modified
805861
92691980002
MW-01-20231005
RSK 175 Modified
805861
92691980003
MW-02-20231005
RSK 175 Modified
805861
92691980004
DUP-20231005
RSK 175 Modified
805861
92692397001
MW-04-20231009
RSK 175 Modified
805861
92692397002
MW-05R-20231009
RSK 175 Modified
805861
92692397003
MW-07-20231009
RSK 175 Modified
805861
92691921001
LT-01-20231004
EPA 3010A
805306
EPA 6020B
805406
92691921001
LT-01-20231004
EPA 3010A
806465
EPA 6020B
806488
92691921002
SW-01-20231004
EPA 3010A
805306
EPA 6020B
805406
92691921003
SW-02-20231004
EPA 3010A
805306
EPA 6020B
805406
92691921004
SW-03-20231004
EPA 3010A
805306
EPA 6020B
805406
92691980001
MW-06-20231005
EPA 3010A
805306
EPA 6020B
805406
92691980001
MW-06-20231005
EPA 3010A
807246
EPA 6020B
807301
92691980002
MW-01-20231005
EPA 3010A
805306
EPA 6020B
805406
92691980002
MW-01-20231005
EPA 3010A
814645
EPA 6020B
814654
92691980003
MW-02-20231005
EPA 3010A
805306
EPA 6020B
805406
92691980003
MW-02-20231005
EPA 3010A
807246
EPA 6020B
807301
92691980004
DUP-20231005
EPA 3010A
805306
EPA 6020B
805406
92691980004
DUP-20231005
EPA 3010A
807246
EPA 6020B
807301
92692397001
MW-04-20231009
EPA 3010A
806465
EPA 6020B
806488
92692397001
MW-04-20231009
EPA 3010A
807246
EPA 6020B
807301
92692397002
MW-05R-20231009
EPA 3010A
806465
EPA 6020B
806488
92692397002
MW-05R-20231009
EPA 3010A
814645
EPA 6020B
814654
92692397003
MW-07-20231009
EPA 3010A
806465
EPA 6020B
806488
92692397003
MW-07-20231009
EPA 3010A
807246
EPA 6020B
807301
92691921015
MW-03-20231011
EPA 3010A
807639
EPA 6020B
807701
92691921001
LT-01-20231004
EPA 7470A
806184
EPA 7470A
806260
92691921002
SW-01-20231004
EPA 7470A
806184
EPA 7470A
806260
92691921003
SW-02-20231004
EPA 7470A
806184
EPA 7470A
806260
92691921004
SW-03-20231004
EPA 7470A
806184
EPA 7470A
806260
92691980001
MW-06-20231005
EPA 7470A
806184
EPA 7470A
806260
92691980002
MW-01-20231005
EPA 7470A
806184
EPA 7470A
806260
92691980003
MW-02-20231005
EPA 7470A
806184
EPA 7470A
806260
92691980004
DUP-20231005
EPA 7470A
806184
EPA 7470A
806260
92692397001
MW-04-20231009
EPA 7470A
805815
EPA 7470A
805895
92692397002
MW-05R-20231009
EPA 7470A
805815
EPA 7470A
805895
92692397003
MW-07-20231009
EPA 7470A
805815
EPA 7470A
805895
92691921015
MW-03-20231011
EPA 7470A
806808
EPA 7470A
806950
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except
in full,
Date: 02/23/2024
01:48 PM
without the written consent of Pace Analytical Services, LLC.
Page 193 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Jackson County Fall 2023
92691921
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92691921001
LT-01-20231004
EPA 3510C
804890
EPA 8270E
805110
92691921002
SW-01-20231004
EPA 3510C
804890
EPA 8270E
805110
92691921003
SW-02-20231004
EPA 3510C
804890
EPA 8270E
805110
92691921004
SW-03-20231004
EPA 3510C
805457
EPA 8270E
805793
92691980001
MW-06-20231005
EPA 3510C
804890
EPA 8270E
805110
92691980002
MW-01-20231005
EPA 3510C
804890
EPA 8270E
805110
92691980003
MW-02-20231005
EPA 3510C
804890
EPA 8270E
805110
92691980004
DUP-20231005
EPA 3510C
805457
EPA 8270E
805793
92692397001
MW-04-20231009
EPA 3510C
805860
EPA 8270E
806023
92692397002
MW-05R-20231009
EPA 3510C
806698
EPA 8270E
806736
92692397003
MW-07-20231009
EPA 3510C
805860
EPA 8270E
806023
92691921015
MW-03-20231011
EPA 3510C
806460
EPA 8270E
806735
92691921016
DW-01-20231011
EPA 524.2
958810
92691921016
DW-01-20231011
EPA 524.2
959124
92691921017
DW-02-20231011
EPA 524.2
958810
92691921017
DW-02-20231011
EPA 524.2
959124
92691921001
LT-01-20231004
EPA 8260D
804926
92691921002
SW-01-20231004
EPA 8260D
804926
92691921003
SW-02-20231004
EPA 8260D
804926
92691921004
SW-03-20231004
EPA 8260D
804927
92691921005
TB-20231004
EPA 8260D
804926
92691980001
MW-06-20231005
EPA 8260D
805590
92691980002
MW-01-20231005
EPA 8260D
805293
92691980003
MW-02-20231005
EPA 8260D
805293
92691980004
DUP-20231005
EPA 8260D
805293
92691980005
TB-20231005
EPA 8260D
804926
92692397001
MW-04-20231009
EPA 8260D
805590
92692397002
MW-05R-20231009
EPA 8260D
805590
92692397003
MW-07-20231009
EPA 8260D
805590
92692397004
TB-20231009
EPA 8260D
805590
92691921015
MW-03-20231011
EPA 8260D
806582
92691921018
TB-20231011
EPA 8260D
806580
92691921001
LT-01-20231004
EPA 8260D Mod.
805079
92691921002
SW-01-20231004
EPA 8260D Mod.
805079
92691921003
SW-02-20231004
EPA 8260D Mod.
805079
92691921004
SW-03-20231004
EPA 8260D Mod.
805079
92691980001
MW-06-20231005
EPA 8260D Mod.
805079
92691980002
MW-01-20231005
EPA 8260D Mod.
805079
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 194 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Jackson County Fall 2023
92691921
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method Batch
92691980003
MW-02-20231005
EPA 8260D Mod.
805079
92691980004
DUP-20231005
EPA 8260D Mod.
805079
92692397001
MW-04-20231009
EPA 8260D Mod.
805656
92692397002
MW-05R-20231009
EPA 8260D Mod.
805656
92692397003
MW-07-20231009
EPA 8260D Mod.
805656
92691921015
MW-03-20231011
EPA 8260D Mod.
806628
92691980001
MW-06-20231005
SM 2320B-2011
806167
92691980002
MW-01-20231005
SM 2320B-2011
806167
92691980003
MW-02-20231005
SM 2320B-2011
806167
92691980004
DUP-20231005
SM 2320B-2011
806167
92692397001
MW-04-20231009
SM 2320B-2011
807249
92692397002
MW-05R-20231009
SM 2320B-2011
807249
92692397003
MW-07-20231009
SM 2320B-2011
807249
92691921015
MW-03-20231011
SM 2320B-2011
807816
92691980001
MW-06-20231005
SM 3500-Fe D#4
815656
92691980002
MW-01-20231005
SM 3500-Fe D#4
815656
92691980003
MW-02-20231005
SM 3500-Fe D#4
815656
92691980004
DUP-20231005
SM 3500-Fe D#4
815656
92692397001
MW-04-20231009
SM 3500-Fe D#4
815656
92692397002
MW-05R-20231009
SM 3500-Fe D#4
815656
92692397003
MW-07-20231009
SM 3500-Fe D#4
815656
92691921015
MW-03-20231011
SM 3500-Fe D#4
815656
92691980001
MW-06-20231005
SM 3500-Fe B-2011
806831
92691980002
MW-01-20231005
SM 3500-Fe B-2011
806831
92691980003
MW-02-20231005
SM 3500-Fe B-2011
806831
92691980004
DUP-20231005
SM 3500-Fe B-2011
806831
92692397001
MW-04-20231009
SM 3500-Fe B-2011
806831
92692397002
MW-05R-20231009
SM 3500-Fe B-2011
806831
92692397003
MW-07-20231009
SM 3500-Fe B-2011
806831
92691921015
MW-03-20231011
SM 3500-Fe B-2011
806831
92691921002
SW-01-20231004
SM 4500-S2D-2011
805139
92691921003
SW-02-20231004
SM 4500-S2D-2011
805139
92691921004
SW-03-20231004
SM 4500-S2D-2011
805139
92691980001
MW-06-20231005
SM 4500-S2D-2011
805139
92691980002
MW-01-20231005
SM 4500-S2D-2011
805139
92691980003
MW-02-20231005
SM 4500-S2D-2011
805139
92691980004
DUP-20231005
SM 4500-S2D-2011
805139
92692397001
MW-04-20231009
SM 4500-S2D-2011
805139
92692397002
MW-05R-20231009
SM 4500-S2D-2011
805139
92692397003
MW-07-20231009
SM 4500-S2D-2011
805139
92691921015
MW-03-20231011
SM 4500-S2D-2011
807120
92691980001
MW-06-20231005
SM 5210B-2011
804809
SM 5210B-2011 804827
92691980002
MW-01-20231005
SM 5210B-2011
804809
SM 5210B-2011 804827
92691980003
MW-02-20231005
SM 5210B-2011
804809
SM 5210B-2011 804827
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/23/2024
01:48 PM
without the written consent of Pace Analytical Services, LLC.
Page 195 of 229

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Jackson County Fall 2023
92691921
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92691980004
DUP-20231005
SM 5210B-2011
804809
SM
5210B-2011
804827
92692397001
MW-04-20231009
SM 5210B-2011
805413
SM
5210B-2011
805466
92692397002
MW-05R-20231009
SM 5210B-2011
805413
SM
5210B-2011
805466
92692397003
MW-07-20231009
SM 5210B-2011
805413
SM
5210B-2011
805466
92691921015
MW-03-20231011
SM 5210B-2016
806318
SM
5210B-2016
806359
92691980001
MW-06-20231005
SM 5220D-2011
807436
SM
5220D-2011
807722
92691980002
MW-01-20231005
SM 5220D-2011
807436
SM
5220D-2011
807722
92691980003
MW-02-20231005
SM 5220D-2011
807436
SM
5220D-2011
807722
92691980004
DUP-20231005
SM 5220D-2011
807436
SM
5220D-2011
807722
92692397001
MW-04-20231009
SM 5220D-2011
807437
SM
5220D-2011
807723
92692397002
MW-05R-20231009
SM 5220D-2011
807437
SM
5220D-2011
807723
92692397003
MW-07-20231009
SM 5220D-2011
807437
SM
5220D-2011
807723
92691921015
MW-03-20231011
SM 5220D-2011
808318
SM
5220D-2011
808608
92691980001
MW-06-20231005
SM 5310B-2014
806612
92691980002
MW-01-20231005
SM 5310B-2014
806612
92691980003
MW-02-20231005
SM 5310B-2014
806612
92691980004
DUP-20231005
SM 5310B-2014
806612
92692397001
MW-04-20231009
SM 5310B-2014
806612
92692397002
MW-05R-20231009
SM 5310B-2014
806612
92692397003
MW-07-20231009
SM 5310B-2014
808120
92691921015
MW-03-20231011
SM 5310B-2014
808121
92691980001
MW-06-20231005
EPA 9056A
804768
92691980002
MW-01-20231005
EPA 9056A
804768
92691980003
MW-02-20231005
EPA 9056A
804768
92691980004
DUP-20231005
EPA 9056A
804768
92692397001
MW-04-20231009
EPA 9056A
805361
92692397002
MW-05R-20231009
EPA 9056A
805361
92692397003
MW-07-20231009
EPA 9056A
805361
92691921015
MW-03-20231011
EPA 9056A
806285
Date: 02/23/2024 01:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 196 of 229

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Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
October 30, 2023
Angela Baioni
Pace Analytical Charlotte
9800 Kincey Ave.
Suite 100
Huntersville, NC 28078
RE: Project: 92691921
Pace Project No.: 20293188
Dear Angela Baioni:
Enclosed are the analytical results for sample(s) received by the laboratory on October 14, 2023. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Baton Rouge
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kyara Nichols
[e-mail]
[phone]
Project Manager
Enclosures
cc: Brittany Gardner, Pace Analytical Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pag@W b6229

Project: 92691921
Pace Project No.: 20293188
Pace Analytical Services Baton Rouge
7979 Innovation Park Drive Ste A, Baton Rouge, LA
70820-7402
Louisiana Dept of Enviromental Quality (NELAC/LELAP):
01979
Florida Dept of Health (NELAC/FELAP): E87854
DoD ELAP (A2LA) #: 6429.01
Alabama DEM #: 41900
Alaska DEC-DW #: LA00024
Alaska DEC CS -LAP #: 21-001
Arkansas DEQ #: 88-0655
California ELAP #: 3063
Georgia DPD M C050
Hawaii DOH State Laboratories Division
Illinois EPA#: 200048
Kansas DoHE #: E-10354
Kentucky DEP UST Branch #: 123054
Louisiana DOH #: LA036
Minnesota DOH #: 2233799
Mississippi State Dept of Health
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
CERTIFICATIONS
Montana Department of Environmental Quality
Nebraska DHHS #: NE-OS-35.21
Nevada DCNR DEP #: LA00024
New York DOH M 12149
North Carolina DEQ - WW & GW #: 618
North Dakota DEQ #: R195
Ohio EPA#: 87782
Oklahoma Dept of Environmental Quality #: 9403
Oregon ELAP #: 4168
Pennsylvania Dept of Environmental Protection #: 68-
05973
South Carolina DHEC #: 73006001
Texas CEQ #: T104704178-23-15
Utah DOH M LA00024
Virginia DCLS #: 6460215
Washington Dept of Ecology #: C929
Wisconsin DNR #: 399139510
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Pagf9.IW2)6229

SAMPLE SUMMARY
Project: 92691921
Pace Project No.: 20293188
Lab ID
Sample ID
Matrix
Date Collected
Date Received
20293188001
MW-03-20231011
Water
10/11/2311:27
10/14/23 10:18
20293188002
MW-03-20231011
Air
10/11/2311:27
10/14/23 10:18
20293188003
MW-06-20231005
Water
10/05/2315:42
10/14/23 10:18
20293188004
MW-06-20231005
Air
10/05/2315:42
10/14/23 10:18
20293188005
MW-01-20231005
Water
10/05/2313:56
10/14/23 10:18
20293188006
MW-02-20231005
Water
10/05/2311:55
10/14/23 10:18
20293188007
DUP-20231005
Water
10/05/23 09:36
10/14/23 10:18
20293188008
DUP-20231005
Air
10/05/23 09:36
10/14/23 10:18
20293188009
MW-04-20231009
Water
10/09/2315:36
10/14/23 10:18
20293188010
MW-04-20231009
Air
10/09/2315:36
10/14/23 10:18
20293188011
MW-05R-20231009
Water
10/09/2317:38
10/14/23 10:18
20293188012
MW-07-20231009
Water
10/09/2313:03
10/14/23 10:18
20293188013
MW-07-20231009
Air
10/09/2313:03
10/14/23 10:18
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
Pagf9.W3)6229

SAMPLE ANALYTE COUNT
Project: 92691921
Pace Project No.: 20293188
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
20293188001
MW-03-20231011
RSK175
BDP
4
RSK175
LB
1
Pace
ENV-SOP-BTRO-0042
LHM
9
20293188002
MW-03-20231011
AM20
LB
1
20293188003
MW-06-20231005
RSK175
LB
1
Pace
ENV-SOP-BTRO-0042
LHM
9
20293188004
MW-06-20231005
AM20
LB
1
20293188005
MW-01-20231005
RSK175
LB
1
Pace
ENV-SOP-BTRO-0042
LHM
9
20293188006
MW-02-20231005
RSK175
LB
1
Pace
ENV-SOP-BTRO-0042
LHM
9
20293188007
DUP-20231005
RSK175
LB
1
Pace
ENV-SOP-BTRO-0042
LHM
9
20293188008
DUP-20231005
AM20
LB
1
20293188009
MW-04-20231009
RSK175
LB
1
Pace
ENV-SOP-BTRO-0042
LHM
9
20293188010
MW-04-20231009
AM20
LB
1
20293188011
MW-05R-20231009
RSK175
LB
1
Pace
ENV-SOP-BTRO-0042
LHM
9
20293188012
MW-07-20231009
RSK175
LB
1
Pace
ENV-SOP-BTRO-0042
LHM
9
20293188013
MW-07-20231009
AM20
LB
1
PASI-BR = Pace Analytical Services - Baton Rouge
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pagf9.44b6229

Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
ANALYTICAL RESULTS
Project: 92691921
Pace Project No.: 20293188
Sample: MW-03-20231011 Lab ID: 20293188001 Collected: 10/11/23 11:27 Received: 10/14/23 10:18 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
BR RSK175 Headspace
Analytical Method: RSK175
Pace Analytical Services - Baton Rouge
Ethane
ND ug/L
5.0
1 10/23/2314:59
74-84-0
Ethene
ND ug/L
5.0
1 10/23/2314:59
74-85-1
Methane
ND ug/L
10.0
1 10/23/2314:59
74-82-8
Surrogates
Methyl-tert-butyl-ether-d3 (S)
111 %. 70-130
1 10/23/23 14:59
BR RSK175 CO2 in Headspace
Analytical Method: RSK175
Pace Analytical Services - Baton Rouge
Carbon dioxide
200000 ug/L
1200
1 10/19/23 11:37
124-38-9
BR AM23G Low Level VFA
Analytical Method: Pace ENV-SOP-BTRO-0042
Pace Analytical Services - Baton Rouge
Pentanoic Acid
ND mg/L
0.50
1 10/18/23 09:34
109-52-4 N2
Acetic Acid
ND mg/L
0.50
1 10/18/23 09:34
64-19-7
Butyric Acid
ND mg/L
0.50
1 10/18/23 09:34
107-92-6
Formic acid
ND mg/L
0.50
1 10/18/23 09:34
64-18-6
Hexanoic Acid
ND mg/L
0.50
1 10/18/23 09:34
142-62-1 L2,N2
Lactic Acid
ND mg/L
0.50
1 10/18/23 09:34
50-21-5
i-Pentanoic Acid
ND mg/L
0.50
1 10/18/23 09:34
503-74-2 N2
Propionic Acid
ND mg/L
0.50
1 10/18/23 09:34
79-09-4
Pyruvic Acid
ND mg/L
0.50
1 10/18/23 09:34
127-17-3
Date: 10/30/2023 05:12 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pagf9.'�RH)6229

ANALYTICAL RESULTS
Project: 92691921
Pace Project No.: 20293188
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
Sample: MW-03-20231011 Lab ID: 20293188002 Collected: 10/11/23 11:27 Received: 10/14/23 10:18 Matrix: Air
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
BR Hydrogen by AM20 in Vapor Analytical Method: AM20
Pace Analytical Services - Baton Rouge
Hydrogen 10 nMoles 1.9 1 10/16/2310:56 1333-74-0
Date: 10/30/2023 05:12 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pag@d*6Eb6229

Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
ANALYTICAL RESULTS
Project: 92691921
Pace Project No.: 20293188
Sample: MW-06-20231005
Lab ID: 20293188003 Collected:
10/05/23
15:42
Received: 10/14/23 10:18 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No.
Qual
BR RSK175 CO2 in Headspace
Analytical Method: RSK175
Pace Analytical Services - Baton Rouge
Carbon dioxide
227000 ug/L
1200
1
10/19/23 09:46
124-38-9
BRAM23G Low Level VFA
Analytical Method: Pace ENV-SOP-BTRO-0042
Pace Analytical Services - Baton Rouge
Pentanoic Acid
ND mg/L
5.0
10
10/18/23 19:23
109-52-4
N2
Acetic Acid
ND mg/L
5.0
10
10/18/23 19:23
64-19-7
Butyric Acid
ND mg/L
5.0
10
10/18/23 19:23
107-92-6
Formic acid
ND mg/L
5.0
10
10/18/23 19:23
64-18-6
Hexanoic Acid
ND mg/L
5.0
10
10/18/23 19:23
142-62-1
1-2,100,
N2
Lactic Acid
ND mg/L
5.0
10
10/18/23 19:23
50-21-5
D3
i-Pentanoic Acid
ND mg/L
5.0
10
10/18/23 19:23
503-74-2
N2
Propionic Acid
ND mg/L
5.0
10
10/18/23 19:23
79-09-4
Pyruvic Acid
ND mg/L
5.0
10
10/18/23 19:23
127-17-3
Date: 10/30/2023 05:12 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pag@dWb6229

ANALYTICAL RESULTS
Project: 92691921
Pace Project No.: 20293188
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
Sample: MW-06-20231005 Lab ID: 20293188004 Collected: 10/05/23 15:42 Received: 10/14/23 10:18 Matrix: Air
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
BR Hydrogen by AM20 in Vapor Analytical Method: AM20
Pace Analytical Services - Baton Rouge
Hydrogen 102 nMoles 9.5 5 10/16/2311:50 1333-74-0
Date: 10/30/2023 05:12 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pagf9.IW8)6229

Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
ANALYTICAL RESULTS
Project: 92691921
Pace Project No.: 20293188
Sample: MW-01-20231005
Lab ID: 20293188005 Collected: 10/05/23
13:56
Received: 10/14/23 10:18 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No.
Qual
BR RSK175 CO2 in Headspace
Analytical Method: RSK175
Pace Analytical Services - Baton Rouge
Carbon dioxide
227000 ug/L 60000
50
10/19/23 10:02
124-38-9
BRAM23G Low Level VFA
Analytical Method: Pace ENV-SOP-BTRO-0042
Pace Analytical Services - Baton Rouge
Pentanoic Acid
ND mg/L 5.0
10
10/18/23 04:38
109-52-4
N2
Acetic Acid
ND mg/L 5.0
10
10/18/23 04:38
64-19-7
Butyric Acid
ND mg/L 5.0
10
10/18/23 04:38
107-92-6
Formic acid
ND mg/L 5.0
10
10/18/23 04:38
64-18-6
Hexanoic Acid
ND mg/L 5.0
10
10/18/23 04:38
142-62-1
L2,N2
Lactic Acid
ND mg/L 5.0
10
10/18/23 04:38
50-21-5
D3
i-Pentanoic Acid
ND mg/L 5.0
10
10/18/23 04:38
503-74-2
N2
Propionic Acid
ND mg/L 5.0
10
10/18/23 04:38
79-09-4
Pyruvic Acid
ND mg/L 5.0
10
10/18/23 04:38
127-17-3
Date: 10/30/2023 05:12 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pagf9.�*99)6229

Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
ANALYTICAL RESULTS
Project: 92691921
Pace Project No.: 20293188
Sample: MW-02-20231005
Lab ID: 20293188006 Collected: 10/05/23
11:55
Received: 10/14/23 10:18 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No.
Qual
BR RSK175 CO2 in Headspace
Analytical Method: RSK175
Pace Analytical Services - Baton Rouge
Carbon dioxide
64900 ug/L 60000
50
10/19/23 10:18
124-38-9
BRAM23G Low Level VFA
Analytical Method: Pace ENV-SOP-BTRO-0042
Pace Analytical Services - Baton Rouge
Pentanoic Acid
ND mg/L 5.0
10
10/18/23 20:37
109-52-4
N2
Acetic Acid
ND mg/L 5.0
10
10/18/23 20:37
64-19-7
Butyric Acid
ND mg/L 5.0
10
10/18/23 20:37
107-92-6
Formic acid
ND mg/L 5.0
10
10/18/23 20:37
64-18-6
Hexanoic Acid
ND mg/L 5.0
10
10/18/23 20:37
142-62-1
L2,N2
Lactic Acid
ND mg/L 5.0
10
10/18/23 20:37
50-21-5
D3
i-Pentanoic Acid
ND mg/L 5.0
10
10/18/23 20:37
503-74-2
N2
Propionic Acid
ND mg/L 5.0
10
10/18/23 20:37
79-09-4
Pyruvic Acid
ND mg/L 5.0
10
10/18/23 20:37
127-17-3
Date: 10/30/2023 05:12 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pa@ao 0(b6229

Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
ANALYTICAL RESULTS
Project: 92691921
Pace Project No.: 20293188
Sample: DUP-20231005
Lab ID: 20293188007 Collected:
10/05/23
09:36
Received: 10/14/23 10:18 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No.
Qual
BR RSK175 CO2 in Headspace
Analytical Method: RSK175
Pace Analytical Services - Baton Rouge
Carbon dioxide
202000 ug/L
1200
1
10/19/23 10:33
124-38-9
BRAM23G Low Level VFA
Analytical Method: Pace ENV-SOP-BTRO-0042
Pace Analytical Services - Baton Rouge
Pentanoic Acid
ND mg/L
5.0
10
10/18/23 05:03
109-52-4
N2
Acetic Acid
ND mg/L
5.0
10
10/18/23 05:03
64-19-7
Butyric Acid
ND mg/L
5.0
10
10/18/23 05:03
107-92-6
Formic acid
ND mg/L
5.0
10
10/18/23 05:03
64-18-6
Hexanoic Acid
ND mg/L
5.0
10
10/18/23 05:03
142-62-1
L2,N2
Lactic Acid
ND mg/L
5.0
10
10/18/23 05:03
50-21-5
D3
i-Pentanoic Acid
ND mg/L
5.0
10
10/18/23 05:03
503-74-2
N2
Propionic Acid
ND mg/L
5.0
10
10/18/23 05:03
79-09-4
Pyruvic Acid
ND mg/L
5.0
10
10/18/23 05:03
127-17-3
Date: 10/30/2023 05:12 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pa@ao 1 b6229

ANALYTICAL RESULTS
Project: 92691921
Pace Project No.: 20293188
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
Sample: DUP-20231005 Lab ID: 20293188008 Collected: 10/05/23 09:36 Received: 10/14/23 10:18 Matrix: Air
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
BR Hydrogen by AM20 in Vapor Analytical Method: AM20
Pace Analytical Services - Baton Rouge
Hydrogen 87.9 nMoles 9.5 5 10/16/2312:05 1333-74-0
Date: 10/30/2023 05:12 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pa@ao 22)6229

Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
ANALYTICAL RESULTS
Project: 92691921
Pace Project No.: 20293188
Sample: MW-04-20231009
Lab ID: 20293188009 Collected: 10/09/23
15:36
Received: 10/14/23 10:18 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No.
Qual
BR RSK175 CO2 in Headspace
Analytical Method: RSK175
Pace Analytical Services - Baton Rouge
Carbon dioxide
124000 ug/L 60000
50
10/19/23 10:49
124-38-9
BRAM23G Low Level VFA
Analytical Method: Pace ENV-SOP-BTRO-0042
Pace Analytical Services - Baton Rouge
Pentanoic Acid
ND mg/L 2.5
5
10/18/23 08:20
109-52-4
N2
Acetic Acid
ND mg/L 2.5
5
10/18/23 08:20
64-19-7
Butyric Acid
ND mg/L 2.5
5
10/18/23 08:20
107-92-6
Formic acid
ND mg/L 2.5
5
10/18/23 08:20
64-18-6
Hexanoic Acid
ND mg/L 2.5
5
10/18/23 08:20
142-62-1
L2,N2
Lactic Acid
ND mg/L 2.5
5
10/18/23 08:20
50-21-5
D3
i-Pentanoic Acid
ND mg/L 2.5
5
10/18/23 08:20
503-74-2
N2
Propionic Acid
ND mg/L 2.5
5
10/18/23 08:20
79-09-4
Pyruvic Acid
ND mg/L 2.5
5
10/18/23 08:20
127-17-3
Date: 10/30/2023 05:12 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pa@ao 316229

ANALYTICAL RESULTS
Project: 92691921
Pace Project No.: 20293188
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
Sample: MW-04-20231009 Lab ID: 20293188010 Collected: 10/09/23 15:36 Received: 10/14/23 10:18 Matrix: Air
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
BR Hydrogen by AM20 in Vapor Analytical Method: AM20
Pace Analytical Services - Baton Rouge
Hydrogen 292 nMoles 190 100 10/16/2312:25 1333-74-0
Date: 10/30/2023 05:12 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pa@e044b6229

Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
ANALYTICAL RESULTS
Project: 92691921
Pace Project No.: 20293188
Sample: MW-05R-20231009
Lab ID: 20293188011 Collected: 10/09/23
17:38
Received: 10/14/23 10:18 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No.
Qual
BR RSK175 CO2 in Headspace
Analytical Method: RSK175
Pace Analytical Services - Baton Rouge
Carbon dioxide
6010000 ug/L 60000
50
10/19/23 11:05
124-38-9
BRAM23G Low Level VFA
Analytical Method: Pace ENV-SOP-BTRO-0042
Pace Analytical Services - Baton Rouge
Pentanoic Acid
ND mg/L 10.0
20
10/18/23 08:45
109-52-4
N2
Acetic Acid
ND mg/L 10.0
20
10/18/23 08:45
64-19-7
Butyric Acid
ND mg/L 10.0
20
10/18/23 08:45
107-92-6
Formic acid
ND mg/L 10.0
20
10/18/23 08:45
64-18-6
Hexanoic Acid
ND mg/L 10.0
20
10/18/23 08:45
142-62-1
L2,N2
Lactic Acid
ND mg/L 10.0
20
10/18/23 08:45
50-21-5
D3
i-Pentanoic Acid
ND mg/L 10.0
20
10/18/23 08:45
503-74-2
N2
Propionic Acid
ND mg/L 10.0
20
10/18/23 08:45
79-09-4
Pyruvic Acid
ND mg/L 10.0
20
10/18/23 08:45
127-17-3
Date: 10/30/2023 05:12 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pa@ao 5a)6229

Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
ANALYTICAL RESULTS
Project: 92691921
Pace Project No.: 20293188
Sample: MW-07-20231009
Lab ID: 20293188012 Collected: 10/09/23
13:03
Received: 10/14/23 10:18 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No.
Qual
BR RSK175 CO2 in Headspace
Analytical Method: RSK175
Pace Analytical Services - Baton Rouge
Carbon dioxide
276000 ug/L 60000
50
10/19/23 11:21
124-38-9
BRAM23G Low Level VFA
Analytical Method: Pace ENV-SOP-BTRO-0042
Pace Analytical Services - Baton Rouge
Pentanoic Acid
ND mg/L 2.5
5
10/18/23 09:09
109-52-4
N2
Acetic Acid
ND mg/L 2.5
5
10/18/23 09:09
64-19-7
Butyric Acid
ND mg/L 2.5
5
10/18/23 09:09
107-92-6
Formic acid
ND mg/L 2.5
5
10/18/23 09:09
64-18-6
Hexanoic Acid
ND mg/L 2.5
5
10/18/23 09:09
142-62-1
L2,N2
Lactic Acid
ND mg/L 2.5
5
10/18/23 09:09
50-21-5
D3
i-Pentanoic Acid
ND mg/L 2.5
5
10/18/23 09:09
503-74-2
N2
Propionic Acid
ND mg/L 2.5
5
10/18/23 09:09
79-09-4
Pyruvic Acid
ND mg/L 2.5
5
10/18/23 09:09
127-17-3
Date: 10/30/2023 05:12 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pa@ao ft6229

ANALYTICAL RESULTS
Project: 92691921
Pace Project No.: 20293188
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
Sample: MW-07-20231009 Lab ID: 20293188013 Collected: 10/09/23 13:03 Received: 10/14/23 10:18 Matrix: Air
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
BR Hydrogen by AM20 in Vapor Analytical Method: AM20
Pace Analytical Services - Baton Rouge
Hydrogen 3.9 nMoles 1.9 1 10/16/2311:35 1333-74-0
Date: 10/30/2023 05:12 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pa@ao 7b6229

QUALITY CONTROL DATA
Project: 92691921
Pace Project No.: 20293188
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
QC Batch: 303842 Analysis Method: AM20
QC Batch Method: AM20 Analysis Description: BR Hydrogen by AM20 in Vapor
Laboratory: Pace Analytical Services - Baton Rouge
Associated Lab Samples: 20293188002, 20293188004, 20293188008, 20293188010, 20293188013
METHOD BLANK: 1454017 Matrix: Air
Associated Lab Samples: 20293188002, 20293188004, 20293188008, 20293188010, 20293188013
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Hydrogen nMoles ND 1.9 10/16/23 09:47
LABORATORY CONTROL SAMPLE & LCSD: 1454018 1454016
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers
Hydrogen nMoles 11.9 11.8 11.7 99 98 70-130 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2023 05:12 PM without the written consent of Pace Analytical Services, LLC.
Pa@eo &b6229

Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
QUALITY CONTROL DATA
Project: 92691921
Pace Project No.: 20293188
QC Batch: 304274
Analysis Method: RSK175
QC Batch Method: RSK175
Analysis Description: BR RSK175W Headspace
Laboratory: Pace
Analytical Services - Baton Rouge
Associated Lab Samples: 20293188001
METHOD BLANK: 1456578
Matrix: Water
Associated Lab Samples: 20293188001
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Ethane
ug/L
ND 5.0
10/23/2314:43
Ethene
ug/L
ND 5.0
10/23/2314:43
Methane
ug/L
ND 10.0
10/23/2314:43
Methyl-tert-butyl-ether-d3 (S)
%.
94 70-130
10/23/23 14:43
LABORATORY CONTROL SAMPLE & LCSD:
1456579
1456580
Spike LCS LCSD
LCS LCSD
% Rec Max
Parameter
Units
Conc. Result Result
% Rec % Rec
Limits RPD RPD Qualifiers
Ethane
ug/L
243 222 270
91 111
70-130 20 20
Ethene
ug/L
296 270 325
91 110
70-130 19 20
Methane
ug/L
945 810 1000
86 106
70-130 21 20 R1
Methyl-tert-butyl-ether-d3 (S)
%.
118 85
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2023 05:12 PM without the written consent of Pace Analytical Services, LLC.
Pa@eo 99)6229

QUALITY CONTROL DATA
Project: 92691921
Pace Project No.: 20293188
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
QC Batch: 304144 Analysis Method: RSK175
QC Batch Method: RSK175 Analysis Description: BR RSK175 CO2 in Headspace
Laboratory: Pace Analytical Services - Baton Rouge
Associated Lab Samples: 20293188001, 20293188003, 20293188005, 20293188006, 20293188007, 20293188009, 20293188011,
20293188012
METHOD BLANK: 1455642 Matrix: Water
Associated Lab Samples: 20293188001, 20293188003, 20293188005, 20293188006, 20293188007, 20293188009, 20293188011,
20293188012
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Carbon dioxide ug/L ND 1200 10/19/23 09:14
LABORATORY CONTROL SAMPLE: 1455643
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Carbon dioxide ug/L 33800 29000 86 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1455644 1455645
MS MSD
20293583003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Carbon dioxide ug/L 334000 33800 33800 378000 350000 130 46 70-130 8 20 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2023 05:12 PM without the written consent of Pace Analytical Services, LLC.
Pa@e�R20(b6229

QUALITY CONTROL DATA
Project: 92691921
Pace Project No.: 20293188
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
QC Batch: 303946 Analysis Method: Pace ENV-SOP-BTRO-0042
QC Batch Method: Pace ENV-SOP-BTRO-0042 Analysis Description: BR AM23G Low Level VFA
Laboratory: Pace Analytical Services - Baton Rouge
Associated Lab Samples: 20293188001, 20293188005, 20293188007, 20293188009, 20293188011, 20293188012
METHOD BLANK: 1454399
Matrix:
Water
Associated Lab Samples:
20293188001, 20293188005, 20293188007, 20293188009, 20293188011,
20293188012
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Acetic Acid
mg/L
ND
0.50
10/18/23 00:56
Butyric Acid
mg/L
ND
0.50
10/18/23 00:56
Formic acid
mg/L
ND
0.50
10/18/23 00:56
Hexanoic Acid
mg/L
ND
0.50
10/18/23 00:56 N2
i-Pentanoic Acid
mg/L
ND
0.50
10/18/23 00:56 N2
Lactic Acid
mg/L
ND
0.50
10/18/23 00:56
Pentanoic Acid
mg/L
ND
0.50
10/18/23 00:56 N2
Propionic Acid
mg/L
ND
0.50
10/18/23 00:56
Pyruvic Acid
mg/L
ND
0.50
10/18/23 00:56
LABORATORY CONTROL SAMPLE:
1454400
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Acetic Acid
mg/L
2
2.0
101
70-130
Butyric Acid
mg/L
2
1.8
88
70-130
Formic acid
mg/L
2
1.9
96
70-130
Hexanoic Acid
mg/L
2
1.1
56
70-130 L2,N2
i-Pentanoic Acid
mg/L
2
1.7
83
70-130 N2
Lactic Acid
mg/L
2
2.0
100
70-130
Pentanoic Acid
mg/L
2
1.4
70
70-130 N2
Propionic Acid
mg/L
2
1.9
95
70-130
Pyruvic Acid
mg/L
2
1.9
94
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1454831
1454832
MS
MSD
20292449011
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Acetic Acid
mg/L
ND
20
20
20.5
20.4
101 101
70-130
0
20
Butyric Acid
mg/L
ND
20
20
18.2
18.0
91 90
70-130
1
20
Formic acid
mg/L
ND
20
20
19.2
19.1
96 95
70-130
0
20
Hexanoic Acid
mg/L
ND
20
20
8.0
8.0
39 39
70-130
1
20 MO, N2
i-Pentanoic Acid
mg/L
ND
20
20
16.2
16.0
81 80
70-130
2
20 N2
Lactic Acid
mg/L
11.4
20
20
30.3
30.6
95 96
70-130
1
20 M3
Pentanoic Acid
mg/L
ND
20
20
12.3
12.4
61 62
70-130
1
20 M1,N2
Propionic Acid
mg/L
ND
20
20
19.7
19.7
99 98
70-130
0
20
Pyruvic Acid
mg/L
ND
20
20
18.8
18.8
94 94
70-130
0
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2023 05:12 PM without the written consent of Pace Analytical Services, LLC.
Pa@e�R22b6229

QUALITY CONTROL DATA
Project: 92691921
Pace Project No.: 20293188
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
QC Batch: 304086 Analysis Method: Pace ENV-SOP-BTRO-0042
QC Batch Method: Pace ENV-SOP-BTRO-0042 Analysis Description: BR AM23G Low Level VFA
Laboratory: Pace Analytical Services - Baton Rouge
Associated Lab Samples: 20293188003, 20293188006
METHOD BLANK: 1455195
Matrix:
Water
Associated Lab Samples: 20293188003, 20293188006
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Acetic Acid
mg/L
ND
0.50
10/18/2318:33
Butyric Acid
mg/L
ND
0.50
10/18/2318:33
Formic acid
mg/L
ND
0.50
10/18/23 18:33
Hexanoic Acid
mg/L
ND
0.50
10/18/2318:33
N2
i-Pentanoic Acid
mg/L
ND
0.50
10/18/2318:33
N2
Lactic Acid
mg/L
ND
0.50
10/18/2318:33
Pentanoic Acid
mg/L
ND
0.50
10/18/2318:33
N2
Propionic Acid
mg/L
ND
0.50
10/18/2318:33
Pyruvic Acid
mg/L
ND
0.50
10/18/2318:33
LABORATORY CONTROL SAMPLE:
1455196
Spike
LCS
LCS %
Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Acetic Acid
mg/L
2
2.0
100
70-130
Butyric Acid
mg/L
2
1.7
87
70-130
Formic acid
mg/L
2
1.9
96
70-130
Hexanoic Acid
mg/L
2
1.0
52
70-130 L2,N2
i-Pentanoic Acid
mg/L
2
1.6
80
70-130 N2
Lactic Acid
mg/L
2
2.0
100
70-130
Pentanoic Acid
mg/L
2
1.4
70
70-130 N2
Propionic Acid
mg/L
2
1.9
95
70-130
Pyruvic Acid
mg/L
2
1.9
95
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1456622
MS
20293188003 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
1456623
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
Acetic Acid
mg/L
ND
20
20
21.1
21.1
101
101
70-130
0
20
Butyric Acid
mg/L
ND
20
20
17.6
17.6
88
88
70-130
0
20
Formic acid
mg/L
ND
20
20
19.6
19.6
97
97
70-130
0
20
Hexanoic Acid
mg/L
ND
20
20
11.6
11.6
54
54
70-130
0
20 MO, N2
i-Pentanoic Acid
mg/L
ND
20
20
15.7
15.7
79
78
70-130
1
20 N2
Lactic Acid
mg/L
ND
20
20
20.5
20.6
100
100
70-130
1
20
Pentanoic Acid
mg/L
ND
20
20
14.3
14.1
72
71
70-130
1
20 N2
Propionic Acid
mg/L
ND
20
20
19.2
19.2
95
95
70-130
0
20
Pyruvic Acid
mg/L
ND
20
20
19.3
19.3
96
97
70-130
0
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2023 05:12 PM without the written consent of Pace Analytical Services, LLC.
Pa@e�R222)6229

Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
QUALIFIERS
Project: 92691921
Pace Project No.: 20293188
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
INC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The Nelac Institute
ANALYTE QUALIFIERS
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
L2 Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M3 Matrix spike recovery was outside laboratory control limits due to matrix interferences.
N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2023 05:12 PM without the written consent of Pace Analytical Services, LLC. Pa@e�R223)6229

QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: 92691921
Pace Project No.: 20293188
Lab ID Sample ID QC Batch Method QC Batch
20293188002
MW-03-20231011
AM20
303842
20293188004
MW-06-20231005
AM20
303842
20293188008
DUP-20231005
AM20
303842
20293188010
MW-04-20231009
AM20
303842
20293188013
MW-07-20231009
AM20
303842
20293188001
MW-03-20231011
RSK175
304274
20293188001
MW-03-20231011
RSK175
304144
20293188003
MW-06-20231005
RSK175
304144
20293188005
MW-01-20231005
RSK175
304144
20293188006
MW-02-20231005
RSK175
304144
20293188007
DUP-20231005
RSK175
304144
20293188009
MW-04-20231009
RSK175
304144
20293188011
MW-05R-20231009
RSK175
304144
20293188012
MW-07-20231009
RSK175
304144
20293188001
MW-03-20231011
Pace ENV-SOP-BTRO-
303946
0042
20293188003
MW-06-20231005
Pace ENV-SOP-BTRO-
304086
0042
20293188005
MW-01-20231005
Pace ENV-SOP-BTRO-
303946
0042
20293188006
MW-02-20231005
Pace ENV-SOP-BTRO-
304086
0042
20293188007
DUP-20231005
Pace ENV-SOP-BTRO-
303946
0042
20293188009
MW-04-20231009
Pace ENV-SOP-BTRO-
303946
0042
20293188011
MW-05R-20231009
Pace ENV-SOP-BTRO-
303946
0042
20293188012
MW-07-20231009
Pace ENV-SOP-BTRO-
303946
0042
Date: 10/30/2023 05:12 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
7979 Innovation Park Drive
Baton Rouge, LA 70820
[phone]
Analytical Method
Analytical
Batch
Pal@e�R244b6229

TransferInternal
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Workorder Name: Jackson
Cert. Needed:
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Report o
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Subcontract To
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Pace Analytical Charlotte
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PS 10/5/202315:42 92691980001 Water
X
X X
3 MW-01-20231005
4
PS 10/5/202313:56 92691980002 Water
X
X
MW-02-20231005
PS 1015/202311,55 92691980003 Water
X
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5 OUP-20231005
PS 10/5/2023 09:36 92691980004 Water
X
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***!n order to maintain client confidentiality, location/name of the sampling site, sampler's name
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not be provided on this COC document.
owner laboratory.
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Workorder Name:
Yes a No
Report To ...° .
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Requeste Analysis.
Pace Analytical Charlotte
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9800 Kincey Avo. Suite 100
7979 Innovation Park Road
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