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HomeMy WebLinkAboutSF_F_NONCD0002287_20230919_FRB_PASI(2) Peoples Cleaners NONCD000 2287 Pre-CERCLA Screening References September 2023 1) United States Environmental Protection Agency (EPA) 40 Code of Federal Regulations - Part 300, Hazard Ranking System, July 1, 2019, Available On-line at: https://semspub.epa.gov/work/HQ/100002489.pdf 2) United States Environmental Protection Agency, Superfund Chemical Data Matrix, Appendix B, Updated July, 2022. Query at:https://www.epa.gov/superfund/superfund-chemical- data-matrix-scdm-query 3) Mecklenburg County NC Geographic Information System (GIS): Polaris 3G (mecklenburgcountync.gov) 4) Google Earth Latitude and Longitude Determinations, Aerial Maps and Imagery: Google Earth 5) NC DEQ Superfund Section Inactive Hazardous Sites Branch: ARC GIS IHSB Map Viewer: IHSB Map Viewer (arcgis.com). 6) Cooper Environmental, Inc, Charlotte, NC: “Phase I Environmental Site Assessment, Peoples Cleaners, 1930 Beatties Ford Road, Charlotte, North Carolina, Cooper Project No. 95202.” December 4, 1995. 7) Swope, Eric, Compliance Coordinator, North Carolina Department of Environmental Quality (NCDEQ), Division of Waste Management (DWM), Superfund Section, Dry-Cleaning Solvent Cleanup Act (DSCA): “DSCA Outreach Inspection Report, Peoples Cleaners, Charlotte, Mecklenburg County, NC”, August 22, 2008. 8) Kim, Aram, NCDEQ, DWM, Superfund Section, DSCA Compliance Program: “Compliance Inspection Report, Peoples Cleaners, Charlotte, Mecklenburg County, NC”, January 11, 2018. 9) Gregory, Johnny, Internal Revenue Service, Criminal Investigation Division, Group 902/North-South Carolina District, 6635 Executive Circle Drive, Suite 180, Charlotte, NC 28212: “Court Forfeiture and Leasing Documents, 1930 Beatties Ford Road”, March 14, 1994. 10) Cooper Environmental, Inc, Charlotte, NC: “Phase II Environmental Site Assessment Reort, Peoples Cleaners, 1930 Beatties Ford Road, Charlotte, North Carolina, Cooper Project No. 96026”, March 4, 1996. 11) Overcash, Keith, P.E, Regional Supervisor, Department of Environment, Health and Natural Resources (DEHNR), Division of Water Quality (DWQ), “Notice of Violation Letter, Peoples Cleaners, Mr. Quillie Smith, Charlotte, Mecklenburg County, NC”, July 29, 1996. 12) Gibson, Judith, Register of Deeds, Mecklenburg County, Charlotte, NC: “United States Internal Revenue Service Deed Transfer, 1930 Beatties Ford Road”, June 30, 1997. 13) Fountain, Niki, Project Manager, NCDEQ, DWM, Superfund Section, DSCA: “Program Choice Letter, Peoples Cleaners, Charlotte, Mecklenburg County, NC”, May 7, 2007. 14) Swope, Eric, Compliance Coordinator, NCDEQ, DWM, Superfund Section, DSCA: “DSCA Outreach Inspection Report, Peoples Cleaners, Charlotte, Mecklenburg County, NC”, March 13, 2007. 15) Fountain, Niki, Project Manager, NCDEQ, DWM, Superfund Section, DSCA: Memo, “Peoples Cleaners File Transfer to IHSB”, May 7, 2007. 16) Kim, Aram, NCDEQ, DWM, Superfund Section, DSCA Compliance Program: “Compliance Inspection Report, Peoples Cleaners, Charlotte, Mecklenburg County, NC”, January 11, 2018. 17) King, Jay, Project Manager, NCDEQ, DWM, Superfund Section, DSCA: “Notice of Dry-Cleaning Solvent Contamination: Peoples Cleaners, DC600006”, February 17, 2020. 18) Cobbs, Ne’Shonda, NCDEQ, DWM, Superfund Section, DSCA Compliance Program: “Compliance Inspection Report, Peoples Cleaners, Charlotte, Mecklenburg County, NC”, June 8, 2022. 19) King, Jay, Project Manager, NCDEQ, DWM, Superfund Section, DSCA: E- communication re: “Peoples Cleaners surface water sample location”, January 9, 2023. 20) Fortney, Caroline, Portfolio Manager, City of Charlotte, General Services: E-communication re: “2015 Custer Street Access and Proposed Phoenix Rising Subdivision”, February 28, 2023. 21) Wood Environmental & Infrastructure Solutions, Inc, Charlotte, NC: “Report of Phase II Environmental Assessment, Proposed Phoenix Rising Subdivision, Custer Street and LaSalle Street, Charlotte, North Carolina, 28215, Wood Project No. 6228-20-6016.01.36”, July 23, 2021. 22) Heath, Ralph, Basic Elements of Groundwater Hydrology with Reference to Conditions in North Carolina, Parts I-II, US Geological Survey Water Resources Investigations Open-File Report 80-44, 1980: report.pdf (usgs.gov) 23) North Carolina Geological Survey, 1985, Geological Map of North Carolina: Raleigh, North Carolina Department of Natural Resources and Community Development, Geological Section, scale 1:5,000,000, in color: The Geology of North Carolina (arcgis.com) 24) United States Department of Agriculture Soil Conservation Service, Soil Survey of Mecklenburg County, North Carolina. June 1980: Mecklenburg Soil Survey (mecknc.gov) 25) US Department of Agriculture (USDA), Natural Resources Conservation Service, Web Soil Survey: Web Soil Survey (usda.gov) 26) Mecklenburg County NC Health Department Well Information System (WIS) 4.0 LUESA-GIS Map Viewer: Well Information System 4.0 (mecklenburgcountync.gov) 27) City of Charlotte, Charlotte Water Source Water Protection Website: Water Quality > Source Water Protection (charlottenc.gov) 28) NCDEQ Source Water Assessment Program (SWAP) Info 2.0 GIS Mapping Tool: SWAPInfo 2.0 (arcgis.com) 29) US EPA Vapor Intrusion Screening (VISL) Level Calculator Output. January 23, 2023: Vapor Intrusion Screening Level Home (ornl.gov) 30) City of Charlotte Stormwater Pipe/Open Drainage Maps: City of Charlotte Open Data Portal (charlottenc.gov) 31) North Carolina Wildlife Resources Commission Fishing Areas GIS Mapping Tool: NC Fishing Areas & Trout Waters (ncpaws.org). 32) US Fish and Wildlife Service National Wetland Inventory Online Wetland Mapper: https://www.fws.gov/wetlands/data/mapper.html 33) NCDEQ, Natural Heritage Program Data Explorer: Map | North Carolina Natural Heritage Data Explorer (natureserve.org). 34) White, Jeffrey R., NCDEQ Superfund Section: Pre-CERCLA Screening Passive Soil Gas Investigation Field Sampling Notes. February 27 and March 9, 2023. 35) Cobbs, Ne’Shonda, Compliance Inspector, NCDEQ, DWM, Superfund Section, DSCA Compliance Program: Letter with Attachment to Smith, Quillie Smith, Owner, Peoples Cleaners (600017C), June 22, 2023. Attachment: DCSA Compliance Program, Inspection Report, Peoples Cleaners, Charlotte, Mecklenburg County, NC, June 16, 2023. 36) Davidson, Landon, Project Manager, NC DEHNR, DWM: Record of Conversation, “Peoples Cleaners NC Legislative Inquiry Report – UST Removal”, August 15-16, 2007. 37) Caldwell, Shawna, Hydrogeologist, NC Mecklenburg County Government, Groundwater and Wastewater Services: E-communication re: “New Drinking Water Wells”, August 9, 2023. Attachment: 1942 and 1948 Saint Mark Street Drinking Water Well Laboratory Analytical Results, 2022. 38) US EPA Safe Drinking Water Information System (SDWIS) Query: Mecklenburg County, NC. January August 9, 2023: SDWIS Search | Envirofacts | US EPA 39) U.S. Census Bureau Quick Facts Query: Mecklenburg County, NC. U.S. Census Bureau QuickFacts: Mecklenburg County, North Carolina; North Carolina REFERENCE 1 Pt. 300, App. A 40 CFR Ch. I (7-1-19 Edition) involuntarily obtains ownership or control of property by virtue of its function as sovereig·n; (2)Acquisitions by or transfers to a government entity or its agent (includ­ing governmental lending and credit institutions, loan guarantors, loan in­surers, and financial reg·ulatory enti­ties which acquire security interests or properties of failed private lending or depository institutions) acting as a conservator or receiver pursuant to a clear and direct statutory mandate or reg·ulatory authority; (3)Acquisitions or transfers of assetsthroug·h foreclosure and its equivalents (as defined in 40 OFR 300.ll00(d)(l)) or other means by a Federal, state, or local government entity in the course of administering a g·overnmental loan or loan guarantee or loan insurance progTam; and (4)Acquisitions by or transfers to a government entity pursuant to seizure or forfeiture authority. (b)Nothing· in this section or in OEROLA section 101(20)(D) or section 101(35)(A)(ii) affects the applicability of 40 OFR 300.1100 to any security inter­est, property, or asset acquired pursu­ant to an involuntary acquisition or transfer, as described in this section. NOTE TO PARAGRAPHS (a)(3) AND (b OF THIS SECTION: Reference to 40 CFR 300.1100 is a ref­erence to the provisions regarding secured creditors in CERCLA sections 101(20)(:E)-(G), 42 U.S.C. 9601(20)(:E)-(G). See Section 2504(a) of the Asset Conservation, Lender Liability, and Deposit Insurance Protection Act, Pub­lic Law, 104---208, 110 Stat. 3009-462, 3009-468 (1996). APPENDIX A TO PART 300-THE HAZARD RANKING SYSTEM Table of Contents List of Figures List of Tables 1.0. Introduction. 1.1 Definitions. 2.0 Evaluations Common to Multiple Path-ways. 2.1 Overview. 2.1.1 Calculation of HRS site score. 2.1.2 Calculation of pathway score. 2.1.3 Common evaluations. 2.2 Characterize sources. 2.2.1 Identify sources. 2.2.2 Identify hazardous substances associ­ated with a source. 2.2.3 Identify hazardous substances avail­able to a pathway. 2.3 Likelihood of release. 2.4 Waste characteristics. 2.4.1 Selection of substance potentially pos­ing· greatest hazard. 2.4.1.1 Toxicity factor. 2.4.1.2 Hazardous substance selection. 2,4,2 Hazardous waste quantity, 2.4.2.l Source hazardous waste quantity. 2.4.2.1.1 Hazardous constituent quantity. 2.4.2.1.2 Hazardous wastestream quantity. 2.4.2,1.3 Volume. 2.4.2.1.4 Area. 2.4.2.1.5 Calculation of source hazardous waste quantity value, 2.4.2.2 Calculation of hazardous waste quantity factor value, 2.4,3 Waste characteristics factor category value. 2.4.3.1 Factor category value. 2.4.3.2 Factor category value, considering bioaccumulation potential. 2,5 Targets. 2.5,l Determination of level of actual con-tamination at a sampling location. 2.6.2 Comparison to benchmarks. 3,0 Ground Water Migration Pathway, 3,0,1 General considerations, 3.0.1.1 Ground water target distance limit. 3.0.1.2 Aquifer boundaries. 3.0.1.2,1 Aquifer interconnections, 3,0,1.2.2 Aquifer discontinuities, 3.0.1.3 Karst aquifer. 3.1 Likelihood of release, 3,1.1 Observed release, 3,1,2 Potential to release, 3.1.2.l Containment, 3.1.2.2 Net precipitation, 3.1.2.3 Depth to aquifer. 3.1.2.4 Travel time. 3,1.2.5 Calculation of potential to release factor value, 3.1.3 Calculation of likelihood of release factor category value. 3.2 Waste characteristics, 3,2,1 Toxicity/mobility, 3.2.1.l Toxicity. 3.2.1.2 Mobility, 3.2.1.3 Calculation of toxicity/mobility factor value, 3,2,2 Hazardous waste quantity, 3,2.3 Calculation of waste characteristics factor category value, 3,3 Targets. 3.3,l Nearest well, 3.3,2 Population. 3.3.2.l Level of contamination. 3.3.2.2 Level I concentrations. 3.3,2,3 Level II concentrations, 3.3.2.4 Potential contamination, 3,3,2,5 Calculation of population factor value, 3,3,3 Resources. 3,3.4 Wellhead Protection Area, 3,3,5 Calculation of targets factor category value, 3.4 Ground water migration score for an aq­uifer, 110 1 REFERENCE 2 REFERENCE 3 SITE MECKLENBURG COUNTY, North Carolina POLARIS 3G PARCEL OWNERSHIP AND GIS SUMMARY Date Printed: 05/14/2023 Identity Parcel ID GIS ID 07503605 07503605 Ownership Owner Name Mailing Address LEVINE C/O SOL LEVINE OF LEVINE & 1930 BEATTIES FORD RD CHARLOTTE NC 28216 QUILLIE SMITH 1930 BEATTIES FORD RD CHARLOTTE NC 28216 Property Characteristics Legal desc P1A-C &2A & B B1 M3-288 & PT CLOSED ALLEY Land Area 0.49 AC Fire District CITY OF CHARLOTTE Special District Account Type INDIVIDUAL Municipality CHARLOTTE Property Use COMMERCIAL Deed Reference(s) and Sale Price Deed Sale Date Sale Price 09155-193 07/16/1997 $0.00 08220-717 07/21/1995 $0.00 Site Location ETJ Area Charlotte Charlotte Historic District No Charlotte 6/30/2011 Annexation Area No Census Tract #48 Zoning Contact appropriate Planning Department or see Map. Water Quality Buffer Parcel Inside Water Quality Buffer No Post Construction District Jurisdiction Charlotte District Central Catawba FEMA and Community Floodplain FEMA Panel#3710454500J FEMA Panel Date 03/02/2009 FEMA Flood Zone OUT:VIEW FEMA FLOODPLAIN TO VERIFY Community Flood Zone OUT:VIEW COMMUNITY FLOODPLAIN TO VERIFY Stream Watershed Districts Stream Watershed Name IRWIN Situs Addresses Tied to Parcel 1930 BEATTIES FORD RD CHARLOTTE 04/10/2014 from Mecklenburg County This map or report is prepared for the inventory of real property within Mecklenburg County and is compiled from recorded deeds, plats, tax maps, surveys, planimetric maps, and other public records and data. Users of this map or report are hereby notified that the aforementioned public primary information sources should be consulted for verification. Mecklenburg County and its mapping contractors assume no legal responsibility for the information contained herein. Page 1/1 SITE SITE SITE Nearest Residence SITE University Park Creative Arts School SITE Kids R Us Academy SITE Phoenix Rising Proposed Housing Development 2235 Haines St. WSW01/15/2023 St. Mark Street - WSWs01/15/2023 st paul street01/15/2023 REFERENCE 4 SITE SITE SITE Residential Residential Future Residential Water Meter SITE SITE REFERENCE 5 SITE SITE SITE SITE SITE PPE 1 SITE PPE 1 SITE PPE 1 PPE 2 SITE PPE 2 SITE PPE 2 SITE PPE 2PPE1 SITE PPE 2PPE1 SITE SITE PPE 2 Surface Water Sample Location REFERENCE 6 REFERENCE 7 NORTH CAROLINA DIVISION OF WASTE MANAGEMENT Dry Cleaning Solvent Cleanup Act (DSCA) Compliance Program Outreach Inspection Report Date: 08/22/2008 Facility Identification Peoples Cleaners Facility ID: 600017C DAQ ID: D076 (Meck) EPA Generator ID: NCD986188084 County/FIPS: Mecklenburg/119 Facility Data Peoples Dry Cleaners 1930 Beatties Ford Road Charlotte, NC 28216 Lat: 35m 15d 42.2s Long: 80m 51d 16.5s SIC : 7216 / Dry Cleaning Plants, Except Rugs NAICS: 81232 / Drycleaning and Laundry Services (except Coin-Operated) Date of Facility Establishment: ~ 1990 Compliance Data Inspection Date: 08/22/2008 Time In: 9:50 am Time Out: 11:50 am Inspector(s): ECS/ADR Operating Status: O/Operating Compliance Code(s): M-MMP violation Action Code: 54/INSPECTION - STATE COMPLIANCE INSPECTION Contact Data Classification Data Solvent: Perchloroethylene System: Dry-to-Dry Installation Date: ?? /2007 Installation Category: Existing/New Consumption Category: Small HW Generator Status : CESQG DSCA Site Number : 60-0006 (IHSB) Facility Contact Quillie Smith 1930 Beatties Ford Road Charlotte, NC 28269 (704) 392-4092 Facility Owner Quillie Smith 1930 Beatties Ford Road Charlotte, NC 28269 (704) 392-4092 Property Owner Quillie Smith & Sol Levine 1930 Beatties Ford Road Charlotte, NC 28269 (704) 392-4092 Inspector’s Signature: Date of Signature: Comments: (MMP and RCRA procedural and recordkeeping requirements) NESHAP Status determined by Mecklenburg Co. AQ (NOV issued) (I) DIRECTIONS: From the Mooresville Regional Office at 610 East Center Avenue in Mooresville, go west on East Center Avenue. Turn left onto S. Main St. (NC-152). Turn right onto W. McClelland Ave. (NC-152). Turn left onto NC-150. Merge onto I-77 South. Merge onto I-85 S via Exit 13B toward Spartanburg and take the Beatties Ford Rd. exit- (Exit 37). Turn right onto Beatties Ford Rd and the dry cleaning facility is located on the left at 1930 Beatties Ford Road. (II) FACILITY DESCRIPTION: Peoples Cleaners is classified as an existing small dry cleaner facility, which has been operated by Mr. Quillie Smith, since approximately 1990. Peoples Cleaners was previously a bakery and fish market (1985-1990), and a filling station from the 1950’s to around 1985. PCE/TCE contamination has been discovered on this property, and the site (60-0006) has been deferred to the Inactive Hazardous Sites Branch. Peoples Cleaners has two dry-to-dry dry cleaning machines installed on site. The Realstar RS-260 dry cleaning machine was no longer in operation, and was de-energized, but contained solvent and solvent waste. The machine was not installed within secondary containment. The Aero-Tech USA 410 dry cleaning machine was operational and did have secondary containment and a refrigerated condenser. Based on the quantity of hazardous waste stored on site and historically generated the facility, Peoples Cleaners is considered to be classified as a Conditionally Exempt Small Quantity Generator (CESQG) at the time of the inspection. Peoples Cleaners now uses MCF as the primary transporter to deliver the facility generated hazardous waste to the TDS facility. No waste manifests were available for review. Dry Cleaning Equipment Summary Machine Number Type of Machine Manufacturer Model # Serial # Date (year) of manufacture Date (year) Of Installation Solvent used Observed Operating ? 1 Dry to dry RealStar RS-260 60-B2-171 ? ? perc No 2 Dry to dry Aero-Tech USA 410 ? ? 2007 Perc No (III) INSPECTION SUMMARY: On August 22, 2007, Eric Swope, Compliance Coordinator and Alicia Roh, Compliance Inspector, with the North Carolina Division of Waste Management, Dry Cleaning Solvent Cleanup Act (DSCA) Program conducted an outreach training visit at Peoples Cleaners. The inspectors met with Mr. Quillie Smith, store owner, who provided the inspectors access to the facility’s equipment and available records. Peoples Cleaners had received an Outreach Visit from the DSCA Compliance program on March 13, 2007. An outreach Corrective Action letter, outlining the needed improvements required to ensure environmental compliance with the applicable MMP and RCRA regulations was sent by certified mail to Mr. Quillie Smith, owner of Peoples Cleaners, on March 15, 2007. No response was received by DSCA Compliance. A signed certified mail card was not received by DSCA compliance either. During the initial Outreach Visit, Mr. Smith explained that a fire had occurred at his store approximately 2 weeks prior. One of the dryers had caught fire during the night. Smoke and water damage were prevalent on site in the vicinity of the dry cleaning machines, washers and dryers. Since the fire incident, Mr. Smith stated that he was operating as a pickup location and another plant was performing the dry cleaning until he could get his plant back in operation. Mr. Smith had also received a letter in the mail from the DSCA cleanup program regarding a discovery of contamination on the property. The Realstar RS-260 dry cleaning machine was operational but did not have secondary containment. Contact water from the dry cleaning machine was collected in an uncovered container that was not stored within spill containment. A lid from a waste drum was placed underneath the solvent pump to catch leaks/oil from the solvent pump. The Aero-Tech USA 410 dry cleaning machine was not operational but did have secondary containment. Water had accumulated in the spill containment underneath the Aerotech dry-cleaning machine, likely leftover from when the fire was extinguished. The carbon filter housings of the Aerotech dry cleaning machine were removed. Perc sensitivity was detected with the halogen leak detector in the vicinity of the open filter housings, and along the floor in front of the dry cleaning machine where the vinyl tiles were removed. It was brought to Mr. Quillie Smith’s attention that vacuum pump condensate and contact water produced by mopping near the dry cleaning machines were to be treated as contact water. The vacuum pump exhausted to the interior of the plant and the condensate was not collected and discharged to the floor. Mr. Smith was advised to begin collecting the vacuum pump condensate in a waste container and transfer to either a hazardous waste drum or treat on site utilizing a wastewater treatment unit (mister/evaporator). Wastewater treatment equipment was not used on site. The designated hazardous waste storage area was located in the boiler room. The waste drums were not stored within spill containment, were not labeled as hazardous waste, were not dated with the recommended accumulation start date, and were not properly sealed. Filters were placed in open waste drums that were not properly labeled or sealed. Depleted dry cleaning machine filters were also observed in a waste dumpster behind the facility. Mr. Smith was also reminded to periodically empty the spotting table waste and dispose in a hazardous waste drum. The Emergency Information Form (in case of a spill or other emergency) was provided to Mr. Quillie Smith, and he was instructed to complete and post this form close to the telephone. Absorbent spill clean-up materials were not available on site. The following records were kept onsite and were available for review: machine operation manual. The following records were not kept onsite and were not available for review: perc purchase receipts, perc 12-month running total, Leak Detection and Repair log, receipts pertaining to equipment purchases, modifications and repairs, log of the condenser exit temperature, Material Safety Data Sheets (MSDS) for solvents and spotting agents, Hazardous Waste Inspection Log, monthly Waste Generation Log, and manifests for waste pickup. Mr. Smith did not maintain the required recordkeeping in the 2007 DSCA Calendar. Machine maintenance concerns were noted during the outreach visit: Mr. Smith was not aware of where to read the condenser exit temperature or the proper high/low pressure gauge settings/readings for the refrigeration system. Mr. Smith was advised to contact his mechanic or the manufacturer of the dry cleaning machine regarding the refrigeration system readings, and to maintain all required recordkeeping for the facility in the 2007 DSCA Compliance calendar. The following observations were noted by S. David Ross Sr. Air Quality Specialist, Mecklenburg County Air Quality, during his inspection on May 23, 2007: The facility was not operating in compliance, nor were records kept in compliance with the dry cleaning NESHAP found in 40 CFR 63 Subpart M. On-Site Equipment: RealStar 35 pound dry-to-dry machine using perchloroethylene as the dry cleaning solvent. While operational, this unit was not operating during the inspection. There were clothes in the drum. Odors behind the machine indicated there are perceptible leaks. Mr. Smith indicated the machine's pump broke in March 2007 after the facility had a fire, and he was decommissioning the machine this week. Mr. Smith stated that he performs daily leak detection, but does not keep records of such. Aero-Tech 35-pound dry-to-dry machine using perchloroethylene as the dry cleaning solvent. This machine was delivered to the site in April 2007, but has not been installed, nor has it been loaded with perchloroethylene. Informed Mr. Smith that when this machine is made operational, he will have to perform records of weekly leak detection, any repairs made, operating conditions, quantitative emissions due to leaks, and concentration of perchloroethylene in drum at end of wash/dry cycle. Record Review: Mr. Smith was given copies of the DSCA calendars, but has not been keeping the records. He was informed that the record keeping is mandatory, and the calendars are a convenient place to keep them. Part of the record keeping is perchloroethylene purchases. Mr. Smith stated that he has been acting as a pick-up store for a year or more. Most of his work he has taken to Park Square Cleaners and Uptown Cleaners, according to Mr. Smith. Other Issues: Mr. Smith was informed that when the Aero-Tech dry cleaning machine becomes operational, he will have to use a quantitative perchloroethylene detector as specified in 40 CFR 63.322 - "Standards" paragraph (o) - "Additional Requirements." When asked where he can get one, I directed him to his dry cleaning equipment/supplies provider. A Notice of Violation (NOV) was issued for Failure to perform leak detection and make appropriate repairs, and failure to record leak detection and perc purchases. During a follow-up re-inspection, the following observations were noted by S. David Ross Sr. Air Quality Specialist, Mecklenburg County Air Quality, on October 29, 2007: No operational violations were noted; however, the facility still is not keeping records required by the MACT. During the inspection, facility owner Mr. Smith stated that he had returned from a funeral, and this was not a good time to discuss the matter. Another copy of MCAQ's dry cleaner registration from was left with Mr. Smith, as well as a business card with David Ross's MCAQ address and phone number so assistance can be provided in completing the application. When asked if Mr. Smith has a copy of the State's Dry Cleaner Calendar in the store, he pulled it off the desk, and stated that he is not using it. Mr. Smith stated that the RealStar perchloroethylene dry cleaning machine, which had leaks as represented by the presence of odors during the May 23, 2007 inspection, no longer is used. The machine still sits in place in the store. It was not operating during this inspection. Mr. Smith stated that he now uses the AeroTech dry cleaning machine, which was not yet operational during the May 23, 2007 inspection. There were no odors detected around this machine during this inspection. A Notice of Violation (NOV) was issued for Failure to perform leak detection and make appropriate repairs, and failure to record leak detection and perc purchases. The following is a summary of Peoples Cleaner’s compliance with respect to the DSCA Required Minimum Management Practices provided in 15A NCAC 02S.0202, and the Resource Conservation and Recovery Act (RCRA) referenced in 40 CFR part 261.5 and 262. Mecklenburg County Air Quality has previously determined Peoples Cleaner’s compliance status regarding the National Emission Standards for Hazardous Air Pollutants (NESHAP) found in 40 CFR Part 63 Subpart M requirements. MMPs: 15A NCAC 02S .0202 The Realstar, 3rd Generation dry cleaning machine was fitted with a closed container solvent transfer system, a refrigerated condenser, but without secondary containment (Pictures 3, 4). This machine was de-energized and was no longer in use. The Aerotech, 3rd Generation dry cleaning machine was fitted with a closed container solvent transfer system, a refrigerated condenser, and secondary containment (Picture 5). Separator (contact) water from the Aerotech dry cleaning machine was collected in an uncovered container that was stored inside the spill containment of the machine (Picture 6). The vacuum pump condensate that was previously discharged onto the floor was manually drained and collected in a dual container system (Picture 8). The onsite wastewater treatment unit (Galaxy mister) was not located within spill containment and no maintenance log was kept (Picture 9). Excess contact water was stored in a 13 gallon drum that was not stored within spill containment (Picture 10). Dry cleaning machine lint filter debris observed disposed in an uncovered 5-gallon bucket located behind the Aerotech machine (Picture 13). A sump drain was observed located behind the facility exterior. Slight perc sensitivity detected was detected in the drain. Contact water possibly had been discharged into the drain previously (Picture 16). A dumpster was also observed outside the facility. The bottom of the dumpster was severely corroded with portions of the base missing. Evidence of prior perc waste disposal was detected in the dumpster (Picture 14). Spill containment was not installed underneath/around each container that contained waste. The Emergency Information form was not prominently posted inside the facility. Adsorbent spill cleanup supplies were not readily available on site. The following records were kept and available for review: None. Underground storage tanks associated with the dry cleaning plant on the property were not observed. (RCRA) Hazardous Waste Regulations: 40 CFR Part 261.5 and 262 The hazardous waste storage area was located in the boiler room. Although several of the drums were empty, drums containing waste were not labeled as hazardous waste, were not dated (recommended), not adequately sealed, and not stored within spill containment (Picture 11). The drums that contained waste were one full 15-gallon liquid waste drum, and two 15-gallon waste drums containing depleted cartridge filters. A hazardous waste drum was observed behind the Aerotech machine. The drum contained waste, and was not labeled, not dated (recommended), not adequately sealed, and not stored within spill containment (Picture 12). Strong perc odor was detected. Excess waste drums was observed at the back of the property near the dumpster. The drums appeared empty, or filling with rainwater (Picture 15). The following records were available for review: None. A review of a manifest history from April 1, 2007 to August 29, 2008, provided by MCF, indicated that 180 pounds of waste were removed on May 8, 2007. During the inspection visit, Mr. Quillie Smith stated that waste had not been picked up since the initial Outreach Visit in March 2007. Operations resumed approximately 3-4 months after the initial Outreach Visit. NESHAP: 40 CFR Part 63 Subpart M Although Mecklenburg County Air Quality (MCAQ) retains the authority to inspect and enforce the NESHAP regulations, the following potential violations were observed by the DSCA inspectors. The potential violations will be referred to Mecklenburg County Air Quality. The owner/operation manuals for the dry cleaning machines were not available at the time of the inspection. The owner was not using the 2008 DSCA Compliance Calendar, and did use the 2007 DSCA Compliance Calendar. None of the required monitoring had been performed and the required logs/records have not been kept. (perc purchase receipts, 12-month running total of perc purchases, condenser exit temp log, LDAR log). Although the Realstar machine had been de-energized, the machine contained solvent/waste solvent. Therefore the machine was still ‘active’ by definition. The Aero-Tech machine was operating at the time of the inspection. Inspectors used the TIF halogen detector to determine if perc vapors were present inside the facility. The TIF monitor indicated sensitivity (presence of perc vapors) at the following locations during the inspection: Aerotech Machine: Strong sensitivity was detected around the ‘funnel’ (where non-virgin solvent can be added into the machine), and a pressurized air line that the owner stated was ‘circulating’ air through the drum. Based on a review of the MCAQ report, the Aerotech machine was delivered to the site in April 2007, and was in operation by October 2007. Therefore DSCA understands that this was a 3rd Generation machine installed after December 2005, and would require a non-vented secondary carbon adsorber or equivalent control device. (IV) CONCLUSIONS: Based on observations documented by the DSCA Inspector during the August 22, 2008 inspection, it is believed that Peoples Cleaners is in violation of the following regulations: MMPs - 15A NCAC 02S.0202 (b)(1) Discharging water/wastes containing dry-cleaning solvent into the sewer or land of the state. (b)(1) Failure to maintain complete and current invoices for waste disposal and/or documentation of on site waste treatment if a proper device is utilized. (b)(2) Failure to install spill containment under and around all dry cleaning machines and waste solvent storage areas by January 1, 2002. (b)(2) Failure to maintain emergency spill cleanup materials and an emergency response plan on the premises. (V) RECOMMENDATIONS: A Notice of Violation and Recommendation for Enforcement, (NOV/NRE) was issued to Peoples Cleaners for violations of the DSCA MMPs. It is recommended that a follow up inspection be conducted in November 2008 to establish compliance. If the facility is in non-compliance at that time, it is recommended that an enforcement action be initiated by DSCA, or if necessary, terminate the clean-up agreement. If no response to the NOV/NRE issued by DSCA is received, it is recommended that a follow up inspection occur the first week of July and that immediate Enforcement action be initiated for non-compliance. REFERENCE 8 NORTH CAROLINA DIVISION OF WASTE MANAGEMENT Dry Cleaning Solvent Cleanup Act (DSCA) Compliance Program Inspection Report Date: 1/11/2018 Facility Identification Peoples Cleaners Facility ID: 600017C EPA Generator ID: NCD986188084 County/FIPS: Mecklenburg/119 DSCA Cleanup ID: DC600006 Facility Data Peoples Cleaners 1930 Beatties Ford Road Charlotte NC 28216 Lat: 35.261722 Long: -80.854583 SIC: 7216 / Dry Cleaning Plants, Except Rugs NAICS: 81232/ Dry Cleaning and Laundry Services (except Coin-Operated) Date of Facility Establishment: 1990 Compliance Data Inspection Date: 1/11/2018 Time In: 08:30 AM Time Out: 09:00 AM Inspectors: Aram Kim, Neshonda Cobbs Operating Status: OO/Operating Compliance Codes: In Violation of MMP Action Code: 01/Inspection Contact Data Classification Data Service Type: Pickup (Full Service Inactive) Solvent: Perchloroethylene System: Dry-to-Dry Installation Date: Installation Category: New Consumption Category: Small HW Generator Status: CESQG Facility Contact Quillie Smith 1930 Beatties Ford Rd. Charlotte, NC 28269 (704) 392-4092 Facility Owner Quillie Smith 1930 Beatties Ford Rd. Charlotte, NC 28269 (704) 392-4092 Property Owner Quillie Smith 1930 Beatties Ford Rd. Charlotte, NC 28269 (704) 392-4092 Inspector’s Signature: Date of Signature: 1/11/18 Comments: NOV/NRE will be issued for repeated violations. (I) DIRECTIONS: From the Mooresville Regional Office at 610 East Center Avenue in Mooresville, go west on East Center Avenue. Turn left onto S. Main St. (NC-152). Turn right onto W. McClelland Ave. (NC-152). Turn left onto NC- 150. Merge onto I-77 South. Merge onto I-85 S via Exit 13B toward Spartanburg and take the Beatties Ford Rd. exit- (Exit 37). Turn right onto Beatties Ford Rd and the dry cleaning facility is located on the left at 1930 Beatties Ford Road. (II) FACILITY HISTORY: Peoples Cleaners has been operated by Mr. Quillie Smith, since approximately 1990. Peoples Cleaners was previously a bakery and fish market (1985-1990), and a filling station from the 1950’s to around 1985. PCE/TCE contamination has been discovered on this property, and the site (60-0006) has been deferred to the Inactive Hazardous Sites Branch. Mr. Smith explained that a fire had occurred at his store in March 2007. In 2012 thedry cleaning operation became inactive and continued to function as a pick-up store. The Garments that require dry cleaning are taken to Bennett's Ultra Cleaners. Solvent History: Solvent Dates Used Perchloroethylene 1990 to Present Previous Inspections: Date Visit Type Violation Type(s) Worst Violation(s) Action(s) Taken Response Due Received Date Inspector 3/10/2016 Inspection MMP No spill containment under four 15-gallon drums. NOV sent on 3/17/2016 4/8/2016 N/A or Not Rec'd Jack Kitchen CHKLST sent on 3/10/2016 None 3/5/2015 Inspection MMP No spill containment CHKLST sent on 3/6/2015 3/27/2015 N/A or Not Rec'd Jack Kitchen 8/22/2008 Inspection MMP Release, no spill pan for DC machine, recordkeeping NOVNRE sent on 9/10/2008 9/24/2008 9/23/2008 Alicia Roh 3/13/2007 Outreach Training Visit MMP Release, no spill pan for DC machine, recordkeeping CAL sent on 3/15/2007 4/2/2007 N/A or Not Rec'd Eric Swope Complaints: None DSCA Sampling: None (III) FACILITY CLASSIFICATION: NESHAP INSTALLATION CATEGORY – New: Peoples Cleaners utilizes a 3rd Generation dry-to-dry dry cleaning machine that was installed in 2007. Since the dry cleaning machine was installed after December 9, 1991, the dry cleaning machine is classified as a 'New' machine installation. Dry Cleaning Equipment Summary No Type of Machine Gen Manufacturer (Mfr) Model # Serial # Mfr Date Install Date End Date Solvent Used Observed Operating? 1 Dry-to- Dry 3rd RealStar RS-260 60-B2- 171 -- -- 2012 Perchloroethylene Removed 2 Dry-to- Dry 3rd Aero-Tech USA 410 -- -- 2007 N/A Perchloroethylene No NESHAP SOURCE CATEGORY - SMALL: Peoples Cleaners is classified as a Small Area Source because it purchased less than 140 gallons of perc during the previous 12-month period. Based on a review of the receipts for the past year, Peoples Cleaners did not purchase any perc in the last 12 months. HAZARDOUS WASTE GENERATOR CATEGORY - CESQG: Peoples Cleaners is classified as a Conditionally Exempt Small Quantity Generator (CESQG) because the facility has routinely generated less than 220 pounds of waste per month during the past 12 months, and stores less than 2,200 pounds of hazardous waste on site. XXXX full 15- gallon drums of hazardous waste were observed on site at the time of the inspection (approx. 250 lbs). The facility utilizes an onsite wastewater treatment unit (WWTU) to dispose of facility-generated contact water. (IV) INSPECTION SUMMARY: On January 11, 2018, Aram Kim and Neshonda Cobbs, Compliance Inspectors, with the North Carolina Division of Waste Management, Dry Cleaning Solvent Cleanup Act (DSCA) Program conducted a Compliance Inspection at Peoples Cleaners. The inspectors met with Mr. Quillie Smith, store owner, who provided the inspector access to the facility's equipment and available records. The Realstar RS-260 3rd generation dry cleaning machine was removed from the facility in 2012. The Aero-Tech USA dry- to-dry 3rd generation dry cleaning machine (picture 1) is remained on site. Even though the machine is still connected to power, the solvent tanks appeared to be empty of perc and the machine has not been in operation since 2012. The facility continues to be operated as a pickup store only. All garments are sent to Bennett Ultra Cleaners to be cleaned. The facility boiler remains nonfunctional at the time of the inspection. Multiple 15-gallon waste drums were observed inside the boiler room at the rear of the facility (picture 2). Three 15-gallon hazardous perc waste drums appeared to contain liquid waste or waste filters from the perc dry cleaning machines. It was difficult to check how full each drum was due to the limited light and access space in the boiler room. Two waste drums which could be storing waste were not stored within spill containment and three drums were stored within inadequate spill containment. The inspectors explained to the owner that the drums containing waste should be either removed by the licensed waste hauler or stored within adequately sized spill containment for 15-gallon drums. The inspectors briefly discussed the decommissioning process of the facility with the owner. The inspectors provided contact information of several licensed waste haulers for Mr. Smith. The dry cleaning machine has not been in use for at least 5 years and no dry cleaning waste had been removed from the facility in the past three years. Logbooks for leak inspections, repairs, and monitoring have not been kept or required. Perc had not been purchased since 2012. Emergency information form was completed and posted on site. Emergency spill cleanup material was stored on site. The following is a summary of Peoples Cleaners' compliance with respect to the DSCA Required Minimum Management Practices provided in 15A NCAC 02S.0202 and Recovery Act (RCRA) referenced in 40 CFR part 261.5 and 262. It was strongly recommended that Mr. Quillie Smith contact Mecklenburg County Air Quality with questions regarding Peoples Cleaners' compliance with the National Emission Standards for Hazardous Air Pollutants (NESHAP) found in 40 CFR Part 63 Subpart M requirements. MMP VIOLATIONS - 15A NCAC 02S.0202 1. Spill containment was not installed under and around the waste solvent storage containers. 2. The spill containment being utilized has a volumetric capacity less than 110 percent of the largest container that it is storing. NESHAP VIOLATIONS - 40 CFR Part 63 Subpart M NOTE: The Mecklenburg County Air Quality Program retains the authority to determine the facility's NESHAP compliance status. None RCRA VIOLATIONS - Hazardous Waste Regulations: 40 CFR Part 262.34 None (V) CONCLUSIONS: Based on observations documented by the DSCA Inspectors during the January 11, 2018 inspection, Peoples Cleaners is currently in violation of the following regulations: MMPs - 15A NCAC 02S.0202 (b)(2) Failure to maintain spill containment under and around the waste solvent storage area by January 1, 2002 [15 NCAC 0202 (b)(2)]. Spill containment shall have a volumetric capacity of 110 percent of the largest vessel, tank, or container within the spill containment area and shall be capable of preventing the release of the applicable dry cleaning solvent beyond the spill containment area for a period of at least 72 hours. (b)(2) Failure to install spill containment with a volumetric capacity of 110 percent of the largest vessel, tank, or container within the spill containment area and capable of preventing the release of the applicable dry cleaning solvent beyond the spill containment area for a period of at least 72 hours. [15 NCAC 0202 (b)(2)]. NESHAP - 40 CFR Part 63 Subpart M NOTE: The Mecklenburg County Air Quality Program retains the authority to determine the facility's NESHAP compliance status. None RCRA- Hazardous Waste Regulations: 40 CFR Part 261 - 262 None (VI) ENFORCEMENT HISTORY (Penalties): None (VII) RECOMMENDATIONS: A DSCA Compliance Program Checklist (#02532) was issued to Mr. Quillie Smith, owner of Peoples Cleaners, indicating the compliance issues to be addressed. A Notice of Violation (NOV)/Notice of Recommendation for Enforcement (NRE) will be issued to Mr. Quillie Smith for the violations observed during the inspection. DSCA Supervisors will determine if enforcement and civil penalties are warranted after reviewing a written response from Peoples Cleaners. A follow-up inspection should be conducted by January 11, 2019 to confirm compliance. (VIII) PHOTOGRAPHS: Picture 1: Aero-Tech USA 3rd generation dry-to-dry dry cleaning machine. Machine has not been in operation since 2012. Machine is partially decommissioned, but still connected to electricity. Picture 2: Several 15-gallon hazardous waste drums observed inside the boiler room. Three drums appeared to be partially full of liquid and or filter waste. Spill containment was either not installed or not adequate. REFERENCE 9 JUL-25-1996 09=03 902 f._ ...:SIMILE TRANSMISSION COVER PAGE INTERNAL REVENUE SERVICE CRIMINAL fNVESTIGA TlON DIVISION GROUP 902/NORTH-SOUTH CAROLINA DISTRICT 6635 EXECUTIVE CIRCLE DRIVE. SUITE 180 CHARLOTIE, NORTH CAROLINA 28212 VOICE: (704) 566-5188 FAX: (704) 566-5399 From; [ J [ ] {<~ r. ] [ ] l ] Michael Lutz, Group Manager Cynthia Fish Johnny Gregory Betty Hollingworth Floyd Mitchell Other Other [ 1 Tom Novota [ ] Dennis 0 • Dell [ 1 Brenda Shore [ ] Jeff Smith [ ] Kathy Sorrell [ ] David Sousa To: f ~· !;:±~...:L..:!::.-::':i:;.....--zr--, __ ______.~ nate: r 7/r;!(r 6 ] Transmitted:[ 7 pages+ cover] P.01 Contents; [ & ~ d lSC U.t£,d, 4~ z:r C.-:fJ fl? IE t!ottAt I~.< fii<FetY71f '!11 e ,,..,,~~ ~rdi!~-; ":~~w~~(ik1J L_'!. __ --~-_ _5_.u_QbJ_ __ Sm5~e2~,r tf1 This communication is intended for the sole use of the individual to whom it is addressed and may contain information that is privileged, confidential, and exempt from disclosure under applicable law. lf the reader of this commwtication is not the intended recipient, or the employee or agent for delivering the communication to the intended recipient, you are hereby notified that any dissemination, distribution, or copying of this conm\unication is strictly prohibited. If you have received this communication in error, please notify the sender immediately by telephone call and return the communication to the address above via the United States Postal Service. nlffC.-frfVl1 1 u~inlfVS P/I{ ~eed cOft€'!. It-rtrftet( c/,c.u,lf{"ttV'tJ lfl C»0. 5'6~ .. 5/f.], '1lle cf'Pdr~~~twr pe~-h )'o sell )'},t 1'-"~~{;;tt f" '115 o111 J?lfF'J ;r twt..r:-~ c 1111 ljlt{ f!Yt. as some t''dl!l'llc.e... 1~71?rf l,relf1 JUL-25-1996 09:04 902 P.02 .... -. > Ulf:tTBD STATES DlS'l'RICT COURT WES'l'ERN DiftUCI' 01' ROR'l'H OAAOLnfA CJIAlU.Oirrl DIVUXOif .. _ FILED CHMLCm'£. N.C. ~·· \,iourt (;\IIJII'h ._.. •' "', W Dil' of N. c. CIVXL tfO. l: 93CV198-MU . UfU'l'ED li'l'ATE5 OF NmftlCA, Plaintiff, v. ) ) ) ) ) ) 1930 BEA'rl'IIS PORD ROAD, ) CIIARID1'1'E, ROJl1!'8 CAROLINA, AS ) IIORE PARTic:vu.Jt.LY DESCRIBED AS ) LOTS lA, lB, lC, 2A ARD 28, ) .BLOCK 1, LDlC!OtJf Hl!:tCHTS, nP ) 8001<. 3, PAGE 288, AS :RBCORDBD ) IN DIED BOOK 5608, PAGE 194, ) MICKLBHBURG COUM'l'I fUBLXC ) .REGZS'l'RY' ) Defendant. ) ) THXS MATTER i~ before tb• ~ upon P1a1nt1t~•• MO~ion ~or Final J\ldca-nt of Forfeitura1 filed March ..fJL 1994, and it appearing 1:bat the Vnited states Jlar&bal published notiae of tbis •otion in accordanc. with law and tllat due notice waa :p~:operly •a4e, the D:Rlrt tinds: 1. Tbat prooess was 4Uly is5ued in this aation •nd ~t the Detendent v.s duly aei•ed by th• Uni~ad States Rarebal pura~t to •aid process; 2. .Tbat no penon (other tJlan tile cn.arlotte-ar.ckleabuq Tax Collector) have filed any clai• or uswer within tbe tiae fhaa4 by lavr 3. 'tbat the tJni 'tlld states stipulated i:o 1:he iilterest of the Cbarlotte-HeckleftbUrg Tax Collector, 4. 11Jat the vnlted. s~·~·· hnbe):' -~ipu1·~-~0 t=h• in~.re.~ of Quillie Smitb in tbis action, despite his failur-e to file a claim and answe~; 5. Tbe allegations of the eo-plaint are taken aa adaittedJ and, 4. ~ aetion. token by the unite4 state• and it• •geata, im:l.udi119 any ota-t• anA local. law •n:row-o.......t o:rri.ola1s .. JUL-25-1996 09:04 902 P.03 -· .. . ' "·-· ~ war• reasonable, proper, anci in good fai~b, in accordance with 28 u.s.c. I 2465. J •· . BaRd upon the above fi.ndinqs. IT IS • 11BRBBY. OltDDBD11 ADJUDGED .UD OICIEID; 1.. That final judpeai: i• hereby entered ago1Mt the Del.n- dant. ( u .ore particularl.y clea<n'~ in paravnpb 4 of the COJiplaint lor J'orf•iture .iD Ru filed. by the United states in this action), and all right, tlt1e, and int~=st in said Def~ndan~, e:xcept as ~~lJ' set fofth herein, is now v .. t.ed and haa been vested ainue 1:ha date of the first criainal oet tiVii'MJ raice t.u ~is forfeiture in the United StateR of america1 · 2. 'l'bat th.a interest of the Cbal"lotte-M•ckl.nlnu:9 Tax COllector i• to :be paid out of the proceeds txoa the dispo•ition of the Defendant, o~ auch otba~ aaurca of t'Und• as the Vnited. fta.tea Harahel de-apprgp~i•t.• ancl in accordance with 1aw1 said inte~et of the Cha.rlotte- Mecklenbu%'9 Tax coll.c:tozo is to be deteminecl by ~ United St•tes Kanh&l un12er local, st.te, and fedaJ!'a1 law at the ti.e of final di•po•ition of the DetendantJ J. That the specific sua of $9, l7a. 00 w1 tbout J.n~erest 1a to be paid tg Quillie Slllith, by and through his attomay ~ Sol Levine, laq •• upon ~inal dispo~~ition o;C the Defen• dant, after all. costs of the United St:atu voveX'2'aaADt are tint nc::overecl and all intereet of tbe Charlotte- MeckleMuJ:9 Tax Collector an pai4J 3. Tb•~ any an4 all Gt:bea!' pe~ONt olabinw any ript, tiUe, or int•~•t in or to the De.tendaft~ u. benby held in default; 4. That na other right. title, or interest in the Defenr!ant &M.ll.~exiet exce~Jt for thoaa &XpN1J8ly set torth hereilu andr JUL-25-1996 09:05 902 Mr. Quillie Smi~h 1930 Beatties Ford Road Charloete, NC 28216 J U.S. Departmerat" .ustice Ap:t"il 24, 1.995 Re: Case Number 3:93CV198 Dea.r Mr. Smith: P.04 'It has come to our attention t.hat no payment hae :been recei 11ed since March 13 , l.!i 95 • AccoNing to the rental. agreement, your rent payments of $900. oo are due the first Qe each month. Thus, on May l, 1995, you are respOnSible to pay $900.00 for the month of April and $900.00 for the month of May. We will axpect payment in the amount of $1,800-00, payable ~o the U.S. Marshals Service and mailed to the addrass in the letterhead above so that ~t is received on or before May 9, 1995. I understand that you hava been in eommunications with the Inter-nal Revenue Service. Perhaps you del.ayed l)ayment since there will be a transfer to that office. Be odvia•d, hgwever, tbct.t our office received a note J::t:om IRS which indicating that they will only Qe responsible for collection of the rent from Mr. Smith ft:'CICI\ the date that they take posseasion of the .suhj eot property from the O'SMS • I see that my la•t ~ette~ to YQU, dated February 22, ·1995, inforrued you stated, •payments should be made payable to the U.S. Marshals Service until you are notified that IRS does in fact bave custody of thte subject property. '' That. etatement st.11~ applies. Sincerely, Property Management Specialist cc·: Johnny Gregory, Internal Revenue Service cc: Frad HUd$on, United States Attorn~'& Office I _ ~-2719% ~~. 902 Mr. Ouillie smith 1930 Beatties Vord ~ad Cha:r:lotte, NC ) O.S..Deparbaeatof Jusdce United Slates .Marsbals Sc=rvice We,..,.. Dfnrlct D/ Ntmh CarollluJ u..w .... c...-... lfMIOIU,._, '-ro.litot .... 7/fl ~.NtNIAC'4Nfi!M 3102 February 22, 1995 Re: 3 : 9 3CV'198, 193 0 B&ATTISS FOIU) ROAD, cmuu:.oTTE Dear Mr. Smith: P.05 The above mentioned property was forfeited March 22, 1994. It was discussed in a meeting with IRS on Cecember 19 and was the subject of a letter eo IRS dated December ~&, and was discussed aga~n in the meetin~· with IRS on Feb~ 2, 1995. · Apparently, the Internal Revenue Service is very aware that this property is an IRS, Depa~t of 'l'ra;a11u:ry, case; and thay have the ~ights to acqui~ cuatody of same. we are currently inqui:r:ing ae to the status of the OltDD. TO S'DBS'!'I"fO"tB C'O'S':ODDN. We will not officially transfer the ~ope.rty tc IRS until we ha~e a filea ~opy of same. Our office had a sale contract and were intending to close and simply forward the proceeds to Internal Reavenue Service EXecutive Otfice. S&id contract was signed by you, the proEipec;:tive buyer, on November 9, 1994. The United States Attorney1 a Office appr(W'ed the sale of the property to you. Yotll! ofl.•r. which indicated a selling prica of fl.OO, 00 0. 00, wa• acc:ept•d by the OSMS, and the closing was to be on or betore January 31, 19~5. lboleVer, it is QU~ unde;r;standin.g thilt you requested t:llat our office consider an extension to the contract, but our office is net willing to do ao. we are, by copy of thie letter, informing certain parties of this cleci.sion. eo ltOT renew the ~:ontrac:t, and we a.J;e in•tead wai,ieg o~ ~~ ~ Sub&tit.'!,te CUgt;gd;tan so !;ha& the f!iooert;v cap be turnf!d QDi a; IRS. We are also reminding and in ~ng the same parties of the del~n~cy in your rent payments. JUL-25-1996 09:06 902 BEiqT DRJ•INQORICY R.BNTAL AGREEMENT, COPY A"rrACBBJ:), UIDICATBD $900.00 PER MONTH. PROM MR. QUIJ;,I,IB SMITH TO tl9MS BRQDIHXW P/'l./93 • . I count .1.8 months fro10 and irlc~uding september, 1.993 to and inc1~ng February. 1994. Meaning 18 X $900 • $1,.200.00. The aMOunt of rent :received. is $6,110.00. The cUfference, the delinquency. thereto~, is ll.2la.QO. Of course, there is the negotiation which al~owed $9,1?2.00 to be disbursed to you upon t:he cloein9 of the propert-y pu:r:suant. to the Orde~ dated 3/16/94. However, it goes without saying that $9,l72.00 is less than $9,250.00, eo there will be nothing ~aid TO you from ths sale of tbe property. YOQ owe $78.00. and with aach pa•a~g month beginning and including March, J.995, the debt to the united States increases $900.00. Whether the Internal .ReV"anue. Service enters into a selling eontr~ct with you or nQt, you are accountable. to pay your rent obligation. Ne wi~l accept $78.00 for your arrearage in your FebrQary, 1995 rent, and $900.00 is due March 1, 1995. Payments should be made payable t:o u.s_ Marahala S&:rvic:e until you a.re notifia<1 that IRS does iq fact have custody of the subject property. Thi~ prgperty will be taken off the market by our contr•et Ccmpan¥ as of February 24, ~995-Thie property wil1 become ~he responsiQility of the Internal Revanua Sa%Vioe somet::i.ma the3:'"o.-ftor. we are waiting for the Order to SUbstitute CUstodian, and IRS cannoe assume CWiJtody until. that point. Sincerely, WALTER B. EDMISTEN ·unit sta~ y; JAnG ftltlLLBR .Asset Forfeiture Specialist AttaeblneJlt: Copy of Rental Agree11lftnt: copy with attacbmant to: P.06 Mr. Johnny Gregory, Internal Revenue Service-~~~~~ Mr. Edwil_l Hunter, Realtor.. ?J ~ ~~.? ..., l"z:'ank 'Mhi tney, AtJSA ....J The attoxuey who wx:ote on behalf of Mr. SUdth, sol Levine Deputy tJni ted States Marshal Steve Gladden *Note to Mr. Hunter; Plea~te take the property off the mcu:ket:. we '-Fill. info%lla }"'01a' of"fice of other developments as well. _ JUL-25-1996 09=06 902 -. .. •r:wnw•= ~-t: ·ta t:be P:~-4 WS~ IIIC I t: ••• ~ era t·tt'!r.tf1 _, !let:wa-. ~ OCc:upul.t: aDd 'tba-U.U.'blll!! St:aw• ~-~ (._) , 11: is. agraad. tlaa'l:' ._ a COIIIUtiaa of caat'l EIUIId ac=t'\\penC!" .. tba QO.,._t w.t.ll. be ~•ibl.e. ·~J:" tall JWQD ;t o~ •11 zwew -·r~~ to~ ate ar aeJ.~ az ~ pi:OJIC:tj" br tDe Ua.Ltad. Stat a • lflla'bal.s serrtca-. RlliDtal ,._ tnll bill .ada peya&ll• to 1:l2a P.07 -ttaitalt Stat:ea. ~ br t1.t'le al.7'. Mid:. 1d.11. '-..... uaar:dell t:G t:tae -_: V.lta.& Stac.a ,._...1• SeJ:"'tc:.t at' 1:tle ~ apac~~1ed below or .. -~ ta aur Sucb. .-rsoa o:r: .ea.t.:Lt1.88 ... •r -...-cs~1-br the ttui ta4 ~ Sbrt'ea' lfaZ'abals se~tca. · Oc J'iiHQta. 1JDCl!arataad tbat" _,. a~tr 4••o•it:.. ........_ raaotal, L• 1 p&J nt:• or .ar g~-* -j--~ .,_ 4Jl.tCIIItle, .-tell .....-paid to -.r pw&a~ or ..etti• pno~ to ttaa sei~NZt~ bY' tSie U'lai'tlld: ::.IStart.a **'ell•il·• ~--lillie~ \! SII$EUI'il..tey err t:1a U'll1.tad. Rates .. I II• ~ en:-'tla ~'bill • .._ Clc:Riw"• zt. 'JI:r' t:t.-oe ear ~ ae tat::. _., 1. • r •• :IIIII:' ~ • r • ,, ... a rtwc:w ~ f!4 t=--...;L:I t'·• eoe.. -'*-• u~t~ wc.P ~l. J:a:D•• co.u:t: •5CIM1a-rt • r Na en ,., ... • ~ 1a:'tiQ1.: .e. ~ = I: ~:' ::~ = ~¥.1Wi,., ~ ia --t:!la ~ I ., Oc:Qa-t. ....., adllltaJ.edgnnt t1aa1: t:tl1.-. 42': •• ••t: ,._ ._. ~ .. ........, •'taal4.. ..-ay:z ad t::u .-.r 1:11at oec•a.-ata ~ -.a. t:aai-....:~ wLUJ. • ggpr ot au. a ag:J:• st. All XMrta or c:o:r:z:aa~ ~ 1M Co:c'NIIU'da4 to: U'lli.t:a4 Stat .. ~· S'ea:Yice P.O. ~ 710 ~. NC 28802. (704)2.71-tan .ln'N: .J•~ MU.l.c Da1:a .. ;: .. 2s~2 .?· TOTAL P.07 REFERENCE 10 REFERENCE 11 REFERENCE 12 REFERENCE 13 &, ~A ~;;~~ NCDE_N_R North Carolina Department of Environment and Natural Resources Dexter R. Matthews, Director Division of Waste Management March 8, 2007 CERTIFIED MAIL RETURN RECEIPT QUILLIE SMITH I SOL LEVINE 1930 BEATTIES FORD RD CHARLOTTE, NC 28216 RE: Discovery of Dry-Cleaning Contamination Michael F. Easley, Governor William G. Ross Jr., Secretary The Division of Waste Management has received information indicating dry-cleaning solvent contamination at 1930 Beatties Ford Rd, Charlotte, Mecklenburg County. Unless further investigation proves the contamination is from a source not originating from this property, you as the dry cleaner or property owner are considered a potentially responsible party (PRP) and liable for the costs of any assessment and remediation. You have a choice in deciding under which of the two state environmental over-site programs the assessment and remediation of the contamination will be managed: Dry-Cleaning Solvent Cleanup Act (DSCA) Program -Sites contaminated with dry-cleaning solvent may be eligible for access to the DSCA Fund. • The majority of the assessment and remediation costs will be covered by the Fund minus a deductible and co-pay. • The DSCA Program will manage the cleanup of the site. • The site's priority ranking will dictate when the site will be cleaned up to risk-based standards. Inactive Hazardous Sites (IHS) Program -Property owners, business owners or business operators that decide not to participate in the DSCA Program will be placed in the IHS Program by default. • The PRP may cover all of the costs of assessment and remediation. Please direct any questions or correspondence to: Division of Waste Management Attn: Niki Fountain 1646 Mail Service Center Raleigh, North Carolina 27699-1646 (919)508-8452 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 Phone 919.508.8400\ FAX 919.715.3605\ Internet http://wastenotnc.org An Equal Opportunity I Affirmative Action Employer-Printed on Dual Purpose Recycled Paper ~.' Contamination Discovery Letter March 8, 2007 DSCA Site 060-0006 QUILLIE SMITH I SOL LEVINE Page 2 If we do not receive a reply from you within 60 days, the site will be placed on the IHS Program's site list and you will be responsible for all costs of assessment and remediation. Sincerely, G'lAJu·~ Niki Fountain DSCA Project Manager cc: REFERENCE 14 NORTH CAROLINA DIVISION OF WASTE MANAGEMENT Dry Cleaning Solvent Cleanup Act (DSCA) Compliance Program Outreach Inspection Report Date: 03/13/2007 Facility Identification Peoples Cleaners Facility ID: 600017C DAQ ID: EPA Generator ID: NCD986188084 County/FIPS: Mecklenburg/119 Facility Data Peoples Cleaners 1930 Beatties Ford Road Charlotte, NC 28269 Lat: 35m 15d 42.2s Long: 80m 51d 16.5s SIC : 7216 / Dry Cleaning Plants, Except Rugs NAICS: 81232 / Drycleaning and Laundry Services (except Coin-Operated) Date of Facility Establishment: ~ 1990 Compliance Data Inspection Date: 03/13/2007 Time In: 1:18 pm Time Out: 3:30 pm Inspector(s): ECS/ADR Operating Status: O/Operating Compliance Code(s): M-MMP violation Action Code: 00/ Outreach Training visit Contact Data Classification Data Solvent: Perchloroethylene System: Dry-to-Dry Installation Date: ?? Installation Category: Existing Consumption Category: Small HW Generator Status : CESQG DSCA Site Number : N/A Facility Contact Quillie Smith 1930 Beatties Ford Road Charlotte, NC 28269 (704) 392-4092 Facility Owner Quillie Smith 1930 Beatties Ford Road Charlotte, NC 28269 (704) 392-4092 Property Owner Quillie Smith & Sol Levine 1930 Beatties Ford Road Charlotte, NC 28269 (704) 392-4092 Inspector’s Signature: Date of Signature: Comments: Outreach CA letter issued by certified mail 3/19/2007? (MMPs and RCRA procedural and recordkeeping requirements) NESHAP Status to be determined by Mecklenburg Co. AQ Recommend follow up inspection no later than March 2008 (I) DIRECTIONS: From the Mooresville Regional Office at 610 East Center Avenue in Mooresville, go west on East Center Avenue. Turn left onto S. Main St. (NC-152). Turn right onto W. McClelland Ave. (NC-152). Turn left onto NC-150. Merge onto I-77 South. Merge onto I-85 S via Exit 13B toward Spartanburg and take the Beatties Ford Rd. exit- (Exit 37). Turn right onto Beatties Ford Rd and the dry cleaning facility is located on the left at 1930 Beatties Ford Road. (II) FACILITY DESCRIPTION: Peoples Cleaners is classified as an existing small dry cleaner facility, which has been operated by Mr. Quillie Smith, since approximately 1990. Peoples Cleaners was previously a bakery and fish market (1985-1990), and a filling station from the 1950’s to around 1985. Peoples Cleaners has two dry-to-dry dry cleaning machines installed on site. Although the Realstar RS-260 dry cleaning machine was operational, it was not in use during the outreach visit and was not installed within secondary containment. The Aero-Tech USA 410 dry cleaning machine was not operational but did have secondary containment. Based on the quantity of hazardous waste stored on site and historically generated the facility, Peoples Cleaners is considered to be classified as a Conditionally Exempt Small Quantity Generator (CESQG) at the time of the inspection. Peoples Cleaners uses Safety Kleen as the primary transporter to deliver the facility generated hazardous waste to the TDS facility, also owned and operated by Safety Kleen. Dry Cleaning Equipment Summary Machine Number Type of Machine Manufacturer Model # Serial # Date (year) of manufacture Date (year) Of Installation Solvent used Observed Operating ? 1 Dry to dry RealStar RS-260 ? perc No 2 Dry to dry Aero-Tech USA 410 ? Perc No (III) INSPECTION SUMMARY: On March 13, 2007, Eric Swope, Compliance Coordinator and Alicia Roh, Compliance Inspector, with the North Carolina Division of Waste Management, Dry Cleaning Solvent Cleanup Act (DSCA) Program conducted an outreach training visit at Peoples Cleaners. The inspectors met with Mr. Quillie Smith, store owner, who provided the inspectors access to the facility’s equipment and available records. The following is a summary of Peoples Cleaner’s compliance with respect to the DSCA Required Minimum Management Practices provided in 15A NCAC 02S.0202, and the Resource Conservation and Recovery Act (RCRA) referenced in 40 CFR part 261.5 and 262. It was strongly recommended that Mr. Smith contact Mecklenburg County Air Quality in order to determine Peoples Cleaner’s compliance with the National Emission Standards for Hazardous Air Pollutants (NESHAP) found in 40 CFR Part 63 Subpart M requirements. During a discussion with Mr. Smith regarding facility operations, Mr. Smith explained that a fire had occurred at his store approximately 2 weeks prior. One of the dryers had caught fire during the night. Smoke and water damage were prevalent on site in the vicinity of the dry cleaning machines, washers and dryers. Since the fire incident, Mr. Smith stated that he was operating as a pickup location and another plant was performing the dry cleaning until he could get his plant back in operation. Mr. Smith had also received a letter in the mail from the DSCA cleanup program regarding a discovery of contamination on the property. The Realstar RS-260 dry cleaning machine was operational but did not have secondary containment. Contact water from the dry cleaning machine was collected in an uncovered container that was not stored within spill containment. A lid from a waste drum was placed underneath the solvent pump to catch leaks/oil from the solvent pump. The Aero-Tech USA 410 dry cleaning machine was not operational but did have secondary containment. Water had accumulated in the spill containment underneath the Aerotech dry-cleaning machine, likely leftover from when the fire was extinguished. The carbon filter housings of the Aerotech dry cleaning machine were removed. Perc sensitivity was detected with the halogen leak detector in the vicinity of the open filter housings, and along the floor in front of the dry cleaning machine where the vinyl tiles were removed. It was brought to Mr. Quillie Smith’s attention that vacuum pump condensate and contact water produced by mopping near the dry cleaning machines were to be treated as contact water. The vacuum pump exhausted to the interior of the plant and the condensate was not collected and discharged to the floor. Mr. Smith was advised to begin collecting the vacuum pump condensate in a waste container and transfer to either a hazardous waste drum or treat on site utilizing a wastewater treatment unit (mister/evaporator). Wastewater treatment equipment was not used on site. The designated hazardous waste storage area was located in the boiler room. The waste drums were not stored within spill containment, were not labeled as hazardous waste, were not dated with the recommended accumulation start date, and were not properly sealed. Filters were placed in open waste drums that were not properly labeled or sealed. Depleted dry cleaning machine filters were also observed in a waste dumpster behind the facility. Mr. Smith was also reminded to periodically empty the spotting table waste and dispose in a hazardous waste drum. The Emergency Information Form (in case of a spill or other emergency) was provided to Mr. Quillie Smith, and he was instructed to complete and post this form close to the telephone. Absorbent spill clean-up materials were not available on site. The following records were kept onsite and were available for review: machine operation manual. The following records were not kept onsite and were not available for review: perc purchase receipts, perc 12-month running total, Leak Detection and Repair log, receipts pertaining to equipment purchases, modifications and repairs, log of the condenser exit temperature, Material Safety Data Sheets (MSDS) for solvents and spotting agents, Hazardous Waste Inspection Log, monthly Waste Generation Log, and manifests for waste pickup. Mr. Smith did not maintain the required recordkeeping in the 2007 DSCA Calendar. Machine maintenance concerns were noted during the outreach visit: Mr. Smith was not aware of where to read the condenser exit temperature or the proper high/low pressure gauge settings/readings for the refrigeration system. Mr. Smith was advised to contact his mechanic or the manufacturer of the dry cleaning machine regarding the refrigeration system readings, and to maintain all required recordkeeping for the facility in the 2007 DSCA Compliance calendar. (IV) CONCLUSIONS: Peoples Cleaners has received an outreach visit from the DSCA Compliance program in which inspectors reviewed all of the applicable regulations that apply to the facility. An outreach corrective action letter, outlining all of the needed improvements required to ensure environmental compliance was sent by certified mail to Mr. Quillie Smith, owner of Peoples Cleaners, on March 19, 2007. (V) RECOMMENDATIONS: Peoples Cleaners is required to respond to DSCA compliance by April 2, 2007 as to what actions have been taken to address items 1-19 in the corrective action letter. If the response is received by DSCA by the requested date no further action is required. It is recommended that a DSCA compliance inspection be conducted by March 2008. It was strongly recommended that Mr. Smith contact Mecklenburg County Air Quality in order to determine Peoples Cleaner’s compliance with the National Emission Standards for Hazardous Air Pollutants (NESHAP) found in 40 CFR Part 63 Subpart M requirements. To: Mr. Quillie Smith, Owner Peoples Cleaners 1930 Beatties Ford Road Charlotte, Mecklenburg County North Carolina 28216 From: Mr. Eric Swope, Compliance Coordinator North Carolina Department of Environment and Natural Resources (NCDENR) Division of Waste Management (DWM) Dry-Cleaning Solvent Cleanup Act (DSCA) Program Date: March 15, 2007 Please address the following issues at Peoples Cleaners, as discussed during our on-site meeting on March 13, 2007. 1) Install spill containment (secondary containment) underneath and around all dry-cleaning machines, dry-cleaning solvent pumps and stills. 2) Install spill containment (secondary containment) under all hazardous waste storage areas. 3) All hazardous waste drums and containers containing waste (including contact water containers) must be sealed (except when adding or removing wastes) and stored in spill containment. 4) Remove and properly dispose or treat the water that has collected in the spill containment (secondary containment) underneath the Aerotech dry-cleaning machine. 5) All hazardous waste drums containing any waste solvent must be labeled “Hazardous Waste.” 6) Small Quantity Generators (SQG) are required to label hazardous waste drums with the accumulation start date (the date waste was initially added to the drum). DSCA advises all cleaners subject to the hazardous waste requirements to label waste drums with both the accumulation start date and the end date (the date drum is sealed for waste pickup). Based on a review of the EPA Envirofacts database, the EPA ID number assigned to your facility location (at 2133 Beatties Ford Road) is NCD986188084. 7) All depleted dry cleaning machine filters must be properly disposed in hazardous waste drums. This includes dry cleaning filters observed in a waste dumpster behind the facility. 8) Replace the back cover of the carbon filter housings of the Aerotech dry cleaning machine. 9) Complete the Emergency Information Form (in case of a spill or other emergency) and post this form close to the telephone. 10) Absorbent spill clean-up materials must be available on site for use to clean up any spills. (Your solvent supplier can advise you regarding the proper absorbent materials to use.) 11) Treat vacuum pump condensate as contact water. Discontinue releasing untreated vacuum pump water (contact water) onto the floor. Begin collecting the vacuum pump condensate in a waste container and transfer to either a hazardous waste drum or treat on site utilizing a wastewater treatment unit (mister/evaporator). 12) Maintain on site receipts of manifests pertaining to waste pickup (please keep these organized and in order from most recent to oldest). EPA regulations state these need to be on site for 3 years. It is recommended that you log the hazardous waste pickup manifests in the “Hazardous Waste Manifest Log-for waste shipped off site” table at the back of the calendar. 13) Maintain on site receipts pertaining to equipment purchases, modifications and repairs. 14) Begin immediately keeping all required (highlighted red) monthly recordkeeping logs found in the 2007 DSCA Compliance Calendar. 15) It is recommended that you contact your solvent supplier in order to obtain records pertaining to your solvent purchases. 16) It is recommended that you ask the manufacturer or mechanic who services the dry cleaning machine where to read the condenser exit temperature at the end of the drying cycle. If there is not a refrigerated condenser exit temperature readout, it needs to be installed. It is required to maintain condenser exit temperatures below 45 degrees Fahrenheit at the end of the drying/cleaning cycle, to ensure efficient recovery of perchloroethylene vapors. 17) Make sure you have the Material Safety Data Sheets (MSDS) for perchloroethylene, spotting agents and all other solvents that are used at your facility and keep onsite (can be obtained from your solvent supplier). It is recommended that you keep these in a binder. 18) Mop water may potentially contain perc and therefore would be considered contact water. DSCA strongly recommends that such mop water be either drummed as hazardous waste or treated by utilizing an onsite wastewater treatment unit (mister/evaporator). 19) Periodically empty the spotting table waste and dispose in a hazardous waste drum. Note: Items 20-22 are only necessary if you choose to treat your contact water onsite with a waste water treatment unit (mister or evaporator) 20) In the future, if you choose to utilize an on-site waste water treatment unit (mister/evaporator) to treat your contact/separator water instead of drumming as hazardous waste, DSCA strongly recommends the utilization of 2 carbon filters (to insure that the contact water containing perc solvent is completely recovered and not released into the environment). 21) In the future, when or if you utilize an on-site waste water treatment unit, begin keeping the “Onsite Waste Water Treatment Unit: (Evaporator/mister) Log” found in the 2007 DSCA Compliance Calendar once you install and operate the new onsite waste treatment unit. 22) In the future, when or if you utilize an on-site waste water treatment unit, spill containment is required under all on-site waste treatment units (mister or evaporators). Please thoroughly review the 2007 DSCA Compliance Calendar and immediately begin keeping the required records and documentation. Please also review the “Minimum Management Practice (MMPs)” compliance requirements and the “Letter of Introduction” as it lists items that compliance inspectors will need to review to determine environmental compliance at your dry cleaner facility. The Mecklenburg County Air Quality program should be contacted regarding an explanation of NESHAP requirements that apply to your facility and to determine your NESHAP compliance status. Please reply by email or submit a written response to the address below by April 2, 2007, as to the actions you have taken to address the above items 1-19. Division of Waste Management DSCA Compliance Program – Attn: Eric Swope 1646 Mail Service Center Raleigh, North Carolina 27699-1646 We appreciate your immediate attention to these concerns. Thank you for your cooperation and assistance during the site visit on March 13, 2007. Regards, Eric Swope eric.swope@ncmail.net 919-508-8457 Alicia Roh alicia.roh@ncmail.net 919-218-0015 Peoples Cleaners Outreach Visit 1930 Beatties Ford Road March 13, 2007 Charlotte NC 28216 ECS/ADR (704) 392-4092 Page 1 of 3 Picture 1: Peoples Dry Cleaners (Mecklenburg County) Picture 3: Dry to Dry Realstar RS-260 dry cleaning machine with no spill (secondary) containment around and underneath. Picture 2: Storefront Picture 4: Back of dry cleaning machine showing no spill containment. Separator (contact) water is collecting in an uncovered bucket and is not in spill containment. Peoples Cleaners Outreach Visit 1930 Beatties Ford Road March 13, 2007 Charlotte NC 28216 ECS/ADR (704) 392-4092 Page 2 of 3 Picture 5: Dry to Dry Areotech USA 410 dry cleaning machine with spill (secondary) containment. (Not in service) Picture 7: Spotting table?? Picture 6: Back of dry cleaning machine. Water remaining in spill containment from the fire?? Picture 8: Vacuum press, exhausting to the air, and possibly draining onto the floor. Peoples Cleaners Outreach Visit 1930 Beatties Ford Road March 13, 2007 Charlotte NC 28216 ECS/ADR (704) 392-4092 Page 3 of 3 Picture 10: Waste filters placed in waste container; not sealed. Picture 9: Hazardous waste storage drums an empty solvent drums (?) in the boiler room. Not adequately labeled. Picture 12: Depleted filter observed in dumpster located at the rear exterior of the facility. Picture 11: Open filter housing Aerotech machine. REFERENCE 15 REFERENCE 16 NORTH CAROLINA DIVISION OF WASTE MANAGEMENT Dry Cleaning Solvent Cleanup Act (DSCA) Compliance Program Inspection Report Date: 1/11/2018 Facility Identification Peoples Cleaners Facility ID: 600017C EPA Generator ID: NCD986188084 County/FIPS: Mecklenburg/119 DSCA Cleanup ID: DC600006 Facility Data Peoples Cleaners 1930 Beatties Ford Road Charlotte NC 28216 Lat: 35.261722 Long: -80.854583 SIC: 7216 / Dry Cleaning Plants, Except Rugs NAICS: 81232/ Dry Cleaning and Laundry Services (except Coin-Operated) Date of Facility Establishment: 1990 Compliance Data Inspection Date: 1/11/2018 Time In: 08:30 AM Time Out: 09:00 AM Inspectors: Aram Kim, Neshonda Cobbs Operating Status: OO/Operating Compliance Codes: In Violation of MMP Action Code: 01/Inspection Contact Data Classification Data Service Type: Pickup (Full Service Inactive) Solvent: Perchloroethylene System: Dry-to-Dry Installation Date: Installation Category: New Consumption Category: Small HW Generator Status: CESQG Facility Contact Quillie Smith 1930 Beatties Ford Rd. Charlotte, NC 28269 (704) 392-4092 Facility Owner Quillie Smith 1930 Beatties Ford Rd. Charlotte, NC 28269 (704) 392-4092 Property Owner Quillie Smith 1930 Beatties Ford Rd. Charlotte, NC 28269 (704) 392-4092 Inspector’s Signature: Date of Signature: 1/11/18 Comments: NOV/NRE will be issued for repeated violations. (I) DIRECTIONS: From the Mooresville Regional Office at 610 East Center Avenue in Mooresville, go west on East Center Avenue. Turn left onto S. Main St. (NC-152). Turn right onto W. McClelland Ave. (NC-152). Turn left onto NC- 150. Merge onto I-77 South. Merge onto I-85 S via Exit 13B toward Spartanburg and take the Beatties Ford Rd. exit- (Exit 37). Turn right onto Beatties Ford Rd and the dry cleaning facility is located on the left at 1930 Beatties Ford Road. (II) FACILITY HISTORY: Peoples Cleaners has been operated by Mr. Quillie Smith, since approximately 1990. Peoples Cleaners was previously a bakery and fish market (1985-1990), and a filling station from the 1950’s to around 1985. PCE/TCE contamination has been discovered on this property, and the site (60-0006) has been deferred to the Inactive Hazardous Sites Branch. Mr. Smith explained that a fire had occurred at his store in March 2007. In 2012 thedry cleaning operation became inactive and continued to function as a pick-up store. The Garments that require dry cleaning are taken to Bennett's Ultra Cleaners. Solvent History: Solvent Dates Used Perchloroethylene 1990 to Present Previous Inspections: Date Visit Type Violation Type(s) Worst Violation(s) Action(s) Taken Response Due Received Date Inspector 3/10/2016 Inspection MMP No spill containment under four 15-gallon drums. NOV sent on 3/17/2016 4/8/2016 N/A or Not Rec'd Jack Kitchen CHKLST sent on 3/10/2016 None 3/5/2015 Inspection MMP No spill containment CHKLST sent on 3/6/2015 3/27/2015 N/A or Not Rec'd Jack Kitchen 8/22/2008 Inspection MMP Release, no spill pan for DC machine, recordkeeping NOVNRE sent on 9/10/2008 9/24/2008 9/23/2008 Alicia Roh 3/13/2007 Outreach Training Visit MMP Release, no spill pan for DC machine, recordkeeping CAL sent on 3/15/2007 4/2/2007 N/A or Not Rec'd Eric Swope Complaints: None DSCA Sampling: None (III) FACILITY CLASSIFICATION: NESHAP INSTALLATION CATEGORY – New: Peoples Cleaners utilizes a 3rd Generation dry-to-dry dry cleaning machine that was installed in 2007. Since the dry cleaning machine was installed after December 9, 1991, the dry cleaning machine is classified as a 'New' machine installation. Dry Cleaning Equipment Summary No Type of Machine Gen Manufacturer (Mfr) Model # Serial # Mfr Date Install Date End Date Solvent Used Observed Operating? 1 Dry-to- Dry 3rd RealStar RS-260 60-B2- 171 -- -- 2012 Perchloroethylene Removed 2 Dry-to- Dry 3rd Aero-Tech USA 410 -- -- 2007 N/A Perchloroethylene No NESHAP SOURCE CATEGORY - SMALL: Peoples Cleaners is classified as a Small Area Source because it purchased less than 140 gallons of perc during the previous 12-month period. Based on a review of the receipts for the past year, Peoples Cleaners did not purchase any perc in the last 12 months. HAZARDOUS WASTE GENERATOR CATEGORY - CESQG: Peoples Cleaners is classified as a Conditionally Exempt Small Quantity Generator (CESQG) because the facility has routinely generated less than 220 pounds of waste per month during the past 12 months, and stores less than 2,200 pounds of hazardous waste on site. XXXX full 15- gallon drums of hazardous waste were observed on site at the time of the inspection (approx. 250 lbs). The facility utilizes an onsite wastewater treatment unit (WWTU) to dispose of facility-generated contact water. (IV) INSPECTION SUMMARY: On January 11, 2018, Aram Kim and Neshonda Cobbs, Compliance Inspectors, with the North Carolina Division of Waste Management, Dry Cleaning Solvent Cleanup Act (DSCA) Program conducted a Compliance Inspection at Peoples Cleaners. The inspectors met with Mr. Quillie Smith, store owner, who provided the inspector access to the facility's equipment and available records. The Realstar RS-260 3rd generation dry cleaning machine was removed from the facility in 2012. The Aero-Tech USA dry- to-dry 3rd generation dry cleaning machine (picture 1) is remained on site. Even though the machine is still connected to power, the solvent tanks appeared to be empty of perc and the machine has not been in operation since 2012. The facility continues to be operated as a pickup store only. All garments are sent to Bennett Ultra Cleaners to be cleaned. The facility boiler remains nonfunctional at the time of the inspection. Multiple 15-gallon waste drums were observed inside the boiler room at the rear of the facility (picture 2). Three 15-gallon hazardous perc waste drums appeared to contain liquid waste or waste filters from the perc dry cleaning machines. It was difficult to check how full each drum was due to the limited light and access space in the boiler room. Two waste drums which could be storing waste were not stored within spill containment and three drums were stored within inadequate spill containment. The inspectors explained to the owner that the drums containing waste should be either removed by the licensed waste hauler or stored within adequately sized spill containment for 15-gallon drums. The inspectors briefly discussed the decommissioning process of the facility with the owner. The inspectors provided contact information of several licensed waste haulers for Mr. Smith. The dry cleaning machine has not been in use for at least 5 years and no dry cleaning waste had been removed from the facility in the past three years. Logbooks for leak inspections, repairs, and monitoring have not been kept or required. Perc had not been purchased since 2012. Emergency information form was completed and posted on site. Emergency spill cleanup material was stored on site. The following is a summary of Peoples Cleaners' compliance with respect to the DSCA Required Minimum Management Practices provided in 15A NCAC 02S.0202 and Recovery Act (RCRA) referenced in 40 CFR part 261.5 and 262. It was strongly recommended that Mr. Quillie Smith contact Mecklenburg County Air Quality with questions regarding Peoples Cleaners' compliance with the National Emission Standards for Hazardous Air Pollutants (NESHAP) found in 40 CFR Part 63 Subpart M requirements. MMP VIOLATIONS - 15A NCAC 02S.0202 1. Spill containment was not installed under and around the waste solvent storage containers. 2. The spill containment being utilized has a volumetric capacity less than 110 percent of the largest container that it is storing. NESHAP VIOLATIONS - 40 CFR Part 63 Subpart M NOTE: The Mecklenburg County Air Quality Program retains the authority to determine the facility's NESHAP compliance status. None RCRA VIOLATIONS - Hazardous Waste Regulations: 40 CFR Part 262.34 None (V) CONCLUSIONS: Based on observations documented by the DSCA Inspectors during the January 11, 2018 inspection, Peoples Cleaners is currently in violation of the following regulations: MMPs - 15A NCAC 02S.0202 (b)(2) Failure to maintain spill containment under and around the waste solvent storage area by January 1, 2002 [15 NCAC 0202 (b)(2)]. Spill containment shall have a volumetric capacity of 110 percent of the largest vessel, tank, or container within the spill containment area and shall be capable of preventing the release of the applicable dry cleaning solvent beyond the spill containment area for a period of at least 72 hours. (b)(2) Failure to install spill containment with a volumetric capacity of 110 percent of the largest vessel, tank, or container within the spill containment area and capable of preventing the release of the applicable dry cleaning solvent beyond the spill containment area for a period of at least 72 hours. [15 NCAC 0202 (b)(2)]. NESHAP - 40 CFR Part 63 Subpart M NOTE: The Mecklenburg County Air Quality Program retains the authority to determine the facility's NESHAP compliance status. None RCRA- Hazardous Waste Regulations: 40 CFR Part 261 - 262 None (VI) ENFORCEMENT HISTORY (Penalties): None (VII) RECOMMENDATIONS: A DSCA Compliance Program Checklist (#02532) was issued to Mr. Quillie Smith, owner of Peoples Cleaners, indicating the compliance issues to be addressed. A Notice of Violation (NOV)/Notice of Recommendation for Enforcement (NRE) will be issued to Mr. Quillie Smith for the violations observed during the inspection. DSCA Supervisors will determine if enforcement and civil penalties are warranted after reviewing a written response from Peoples Cleaners. A follow-up inspection should be conducted by January 11, 2019 to confirm compliance. (VIII) PHOTOGRAPHS: Picture 1: Aero-Tech USA 3rd generation dry-to-dry dry cleaning machine. Machine has not been in operation since 2012. Machine is partially decommissioned, but still connected to electricity. Picture 2: Several 15-gallon hazardous waste drums observed inside the boiler room. Three drums appeared to be partially full of liquid and or filter waste. Spill containment was either not installed or not adequate. REFERENCE 17 February 17, 2020 To: Mr. Quillie Smith 1930 Beatties Ford Road Charlotte, NC 28216 Re: Notice of Dry-Cleaning Solvent Contamination 1930 Beatties Ford Road-People’s Cleaners DC600006 Charlotte, Mecklenburg County, North Carolina Dear Mr. Smith: The Division of Waste Management has received information indicating that dry-cleaning solvent contamination was discovered during a site investigation at the above-referenced location. I have included a copy of the site report. This contamination appears to be related to the dry-cleaning facility located on your property. Unless further investigation proves that the contamination is from a source not originating from your property, you as a property owner are considered a potentially responsible party (PRP) and liable for the costs of any assessment and remediation. As I explained, you do have a choice for deciding under which of the two state environmental over-site programs the contamination on the property will be managed. An overview of each program below: Dry-Cleaning Solvent Cleanup Act (DSCA) Program - Sites contaminated with dry-cleaning solvent may be eligible for access to the DSCA Fund. This is the Program I discussed with you on the phone. ▪ The majority of the costs for assessment and remediation will be covered by the Fund minus a deductible and co-pay. There is also a one-time $1,000 application fee to enter the DSCA Program. ▪ The DSCA Program will manage the cleanup of the site. ▪ The site's priority ranking will dictate when the site will be cleaned up to risk-based standards. Inactive Hazardous Sites (IHS) Program - Property owners or business owners that decide not to participate in the DSCA Program will be placed in the IHS Program by default. ▪ The PRP will cover all of the costs of assessment and remediation. ▪ The PRP will be responsible for contracting a registered environmental consultant. DC600006 (People’s Cleaners) 1930 Beatties Ford Road DSCA/IHS Choice Letter Page 2 ▪ Contaminated groundwater that has or will migrate off the property is not eligible for alternate risk- based standards without the approval of off-property owners. There are fees associated with obtaining risk-based alternate groundwater standards. Please direct any questions or correspondence to: Division of Waste Management North Carolina Dry-Cleaning Solvent Act Program Attn: DSCA Program/Jay W. King 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Or contact me directly at: 919.707.8367 jay.king@ncdenr.gov I appreciated the time you gave me to discuss the site and the benefits of the DSCA Program. I also understand that any future financial obligation, for any reason, will be a serious issue for you. Therefore, if I do not receive a reply from you within 60 days, the site will be placed on the IHS Program's site list. Sincerely, Jay W. King, DSCA Project Manager Division of Waste Management, NCDEQ cc: Delonda Alexander, DSCA Program Charlotte Jesneck, IHS Program REFERENCE 18 NORTH CAROLINA DIVISION OF WASTE MANAGEMENT Dry Cleaning Solvent Cleanup Act (DSCA) Compliance Program Inspection Memo Facility Identification Peoples Cleaners Facility ID: 600017C EPA Generator ID: NCD986188084 County/FIPS: Mecklenburg/119 DSCA Cleanup ID: DC600006 Facility Data Peoples Cleaners 1930 Beatties Ford Road Charlotte NC 28216 Lat: 35.261722 Long: -80.854583 SIC: 7216 / Dry Cleaning Plants, Except Rugs NAICS: 81232/ Dry Cleaning and Laundry Services (except Coin-Operated) Date of Facility Establishment: 1990 Compliance Data Inspection Date: 6/8/2022 Time In: 11:00 AM Time Out: 11:10 AM Inspector: Ne’Shonda Cobbs Operating Status: OO/Operating Compliance Codes: In Compliance Action Code: 01/Inspection Contact Data Classification Data Service Type: Pickup (Full Service Inactive) Solvent: Perchloroethylene System: Dry-to-Dry Installation Date: 2007 Installation Category: New Consumption Category: Small HW Generator Status: VSQG Facility Contact Quillie Smith 1930 Beatties Ford Rd. Charlotte, NC 28269 (704) 392-4092 Facility Owner Quillie Smith 1930 Beatties Ford Rd. Charlotte, NC 28269 (704) 392-4092 Property Owner Quillie Smith 1930 Beatties Ford Rd. Charlotte, NC 28269 (704) 392-4092 Inspector’s Signature: Date of Signature: 6/8/22 Comments: Facility has not operated dry-cleaning machine in over 10 years or cleaned any items. Owner just keeps building open. (I) FACILITY HISTORY: Peoples Cleaners has been operated by Mr. Quillie Smith, since approximately 1990. Peoples Cleaners was previously a bakery and fish market (1985-1990), and a filling station from the 1950’s to around 1985. PCE/TCE contamination has been discovered on this property, and the site (60-0006) has been deferred to the Inactive Hazardous Sites Branch. Mr. Smith explained that a fire had occurred at his store in March 2007. In 2012 the dry-cleaning operation became inactive and continued to function as a pick-up store. No garments have been processed at the facility or through pick up location in several years. Solvent History: Solvent Dates Used Perchloroethylene 1990 to Present Dry Cleaning Equipment Summary No Type of Machine Gen Manufacturer (Mfr) Model # Serial # Mfr Date Install Date End Date Solvent Used Observed Operating? 1 Dry-to-Dry 3rd RealStar RS-260 60-B2-171 -- -- 1/1/2012 Perchloroethylene removed 2 Dry-to-Dry 3rd Aero-Tech USA 410 -- -- 1/1/2007 N/A Perchloroethylene no (II) INSPECTION SUMMARY: On June 08, 2022, Ne’Shonda Cobbs, Compliance Inspector, with the North Carolina Division of Waste Management, Dry Cleaning Solvent Cleanup Act (DSCA) Program conducted a Compliance Inspection at Peoples Cleaners. The facility appears to still be open, however, no one was onsite at the time of the inspection. The owner is older and appears to have the facility open even though no business is being processed at the location. Previous inspections indicated that the machine had not been in use in many years. There is no power to the rear of the facility where the dry-cleaning equipment is located. Bennett’s Ultra Clean previously cleaned for the facility but according to the owner of Bennett’s, he has not cleaned for the facility in several years. A letter was sent in January 2020 to the facility in hopes that someone assisting the owner, would read it and reach back out to the program to provide additional details. No response was ever provided. Another letter will be sent to the facility to try to illicit a response to whomever assists the owner. The owner is clearly not independent and has to have assistance to be present at the facility. REFERENCE 19 From:King, Jay W To:White, Jeffrey R Subject:RE: Peoples Cleaners - 1930 Beatties Ford Rd Date:Monday, January 9, 2023 1:16:46 PM Attachments:Re Peoples Cleaners Charlotte.msg image001.png DC600006 _20200217_ChoiceLetter.pdf DC600006_20070308_Correspondence.pdf IH2287_20180921_Lab Results of creek below site.pdf DC600006_19960304_PreDSCA_Ph2EnvAssessment.pdf DC600006_20180924_SWS_Location.jpg Good afternoon Jeffrey. I don’t believe we have met. I’m in Green Square. This site has never been in the DSCA Program. This site has been referred back to IHSB twice now. I talked with Quilly Smith after sending the attached choice letter 2020 about joining the DSCA Program. Non-starter, he can’t afford the initial $1,000 app fee so there is no way he would have been able to fulfill the financial obligations of our program. So back to IHSB jurisdiction. SW sample info attached. Long way from the property, but nothing found. This property was seized at some point by the US Customs Service, details unknown other than the city was giving Mr. Smith loans to buy the property. I couldn’t find my correspondence to Mike, but I do remember doing it. That’s all I got. Jay W. King DSCA Project Manager North Carolina Department of Environmental Quality Office: (919) 707-8367 jay.king@ncdenr.gov From: White, Jeffrey R <jeffrey.white@ncdenr.gov> Sent: Monday, January 9, 2023 12:22 PM To: King, Jay W <Jay.King@ncdenr.gov> Subject: Peoples Cleaners - 1930 Beatties Ford Rd Good Afternoon Mr. King, I am conducting a Pre-CERCLA Screening for the Peoples Cleaners Site, NONCD0002287 that will include some passive soil gas sampling. I found a correspondence dated 8/24/18 with you and a Mr. Mike Rogers regarding the property owner and some surface water sampling. Do you have any further information regarding the surface water sample/assessment and response from the owner, Quilly Smith regarding the DSCA program? Was he cooperative? Any help/information would be appreciated. Thanks! Jeffrey R. White Hydrogeologist, Superfund Section Division of Waste Management North Carolina Department of Environmental Quality Office: (919) 707-8331 | Cell: (704) 692-4578 jeffrey.white@ncdenr.gov From:King, Jay W To:Rogers, Mike Subject:RE: People"s Cleaners 1930 Beatties Ford Rd Date:Friday, August 24, 2018 2:13:02 PM Attachments:image004.jpg image001.jpg Thanks for the correct info about the site. I’ll just ask him what interest Lovine and assoc. has in the property since they are listed as well. Maybe they are just a property manager since it says c/o. 2018_JWK_SIG From: Rogers, Mike Sent: Friday, August 24, 2018 2:01 PM To: King, Jay W <Jay.King@ncdenr.gov> Subject: RE: People's Cleaners 1930 Beatties Ford Rd We don’t have the lab samples back yet. Evidently, there was some sort of drug bust or illegal activity at the site and the US Marshall’s office took the property and Quilly Smith worked at first with them and then with the IRS to obtain the property. During our site visit there, I talked with Quilly and he affirmed there had been a drug bust there. According to the Mecklenburg GIS site, Quilly Smith is the current owner of the property. From: King, Jay W Sent: Friday, August 24, 2018 1:14 PM To: Rogers, Mike <mike.rogers@ncdenr.gov> Subject: People's Cleaners 1930 Beatties Ford Rd Good Afternoon Mike. I’m sure Colin told you I would be calling about subject property. I plan to give Quilly Smith a call about the DSCA Program. Looks like there is evidence enough from the Cooper Environmental report for the site to be an eligible petitioner. I’m still trying to figure out who actually owns the property? Him or Sol Levin and Associates? GIS lists them both. Maybe something to that since I had heard thru another party that the city may have taken the property several years ago but gave it back through a free money program called “city within a city”. So I have to figure out if the financial obligations can be met to qualify for DSCA. Did you get the surface water sample results back yet? Colin told me you guys collected one to the SE of the cleaner? REFERENCE 20 From:Fortney, Caroline To:White, Jeffrey R Cc:Alexander, Pamela; Miller, Matt; Fortney, Caroline Subject:[External] RE: Property Access Letter - 2015 Custer St. Date:Tuesday, February 28, 2023 9:10:16 AM Attachments:image001.pngimage002.png CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Thanks for clarifying that. Let us know if you need anything else from us. Best, Caroline Fortney Portfolio Manager City of Charlotte|General Services 600 East 4th Street, 12th floor Charlotte, NC 28202 (704) 619-2743 | Caroline.Fortney@charlottenc.gov From: White, Jeffrey R <jeffrey.white@ncdenr.gov> Sent: Tuesday, February 28, 2023 8:32 AM To: Fortney, Caroline <Caroline.Fortney@charlottenc.gov> Cc: Alexander, Pamela <Pam.Alexander@charlottenc.gov>; Miller, Matt <matt.miller@woodplc.com> Subject: [EXT]RE: [EXT]RE: [External] Property Access Letter - 2015 Custer St. Caroline, We do not need access to the property owned by the City of Charlotte anymore since PSG sampling was completed via the Phase II (which I appreciate you sending). The sent proposed sampling plan was preliminary and dependent upon final access authorization from property owners. I apologize for not clarifying yesterday that we would not be accessing or installing on the City’s property or any of the others that we did not have signed access agreements for. Jeffrey R. White Hydrogeologist, Superfund Section Division of Waste Management North Carolina Department of Environmental Quality Office: (919) 707-8331 | Cell: (704) 692-4578 jeffrey.white@ncdenr.gov From: Fortney, Caroline <Caroline.Fortney@charlottenc.gov> Sent: Monday, February 27, 2023 8:57 AM To: White, Jeffrey R <jeffrey.white@ncdenr.gov> Cc: Alexander, Pamela <Pam.Alexander@charlottenc.gov>; Miller, Matt <matt.miller@woodplc.com>; Fortney, Caroline <Caroline.Fortney@charlottenc.gov> Subject: RE: [EXT]RE: [External] Property Access Letter - 2015 Custer St. CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Good Morning, Jeffrey, Although we are not opposed to sampling taking place on the property, the City (to my knowledge) has not signed the appropriate paperwork to provide access to the site. Let’s make sure to have the paperwork in place before crews go onto the City’s property. Do you think you still need to do sampling, even with the Phase II report? Assuming you do, I’ll work on getting the access request through the proper channels on my end. Caroline Fortney Portfolio Manager City of Charlotte|General Services 600 East 4th Street, 12th floor Charlotte, NC 28202 (704) 619-2743 | Caroline.Fortney@charlottenc.gov From: White, Jeffrey R <jeffrey.white@ncdenr.gov> Sent: Monday, February 27, 2023 8:51 AM To: Fortney, Caroline <Caroline.Fortney@charlottenc.gov> Cc: Alexander, Pamela <Pam.Alexander@charlottenc.gov>; Miller, Matt <matt.miller@woodplc.com> Subject: [EXT]RE: [External] Property Access Letter - 2015 Custer St. Hi Caroline, Thank you for getting back to me and providing the Phase II report. We will be mobilizing to the site at 1000 and should arrive ~1230-1300. Please feel free to call my cell phone anytime this afternoon while we are in the field to install the other PSG samplers if you feel it may relate or alter our original proposed sampling plan. Otherwise, I am also free for the 0900 – 1300 slot tomorrow. Jeffrey R. White Hydrogeologist, Superfund Section Division of Waste Management North Carolina Department of Environmental Quality Office: (919) 707-8331 | Cell: (704) 692-4578 jeffrey.white@ncdenr.gov From: Fortney, Caroline <Caroline.Fortney@charlottenc.gov> Sent: Friday, February 24, 2023 4:41 PM To: White, Jeffrey R <jeffrey.white@ncdenr.gov> Cc: Alexander, Pamela <Pam.Alexander@charlottenc.gov>; Miller, Matt <matt.miller@woodplc.com>; Fortney, Caroline <Caroline.Fortney@charlottenc.gov> Subject: [External] Property Access Letter - 2015 Custer St. CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Jeffrey, I am following up on your request attached and below. The City recently completed a Phase I and Phase II assessment for this site. We would like to share the Phase II with you and setup a time to touch base about the request early next week. Are you available for 30 mins in any of the time windows below? Monday 11:30am - 1:00pm Monday 1:30am - 5:00pm Tuesday 9:00am-9:30am Tuesday 4:00pm-5:00pm Caroline Fortney Portfolio Manager City of Charlotte|General Services 600 East 4th Street, 12th floor Charlotte, NC 28202 (704) 619-2743 | Caroline.Fortney@charlottenc.gov From: Wells, Ebony <Ebony.Wells@charlottenc.gov> Sent: Tuesday, February 21, 2023 11:57 AM To: Loy, Anne-Rose <AnneRose.Loy@charlottenc.gov>; Radcliff, Anna <Anna.Radcliff@charlottenc.gov>; Sossamon, Leisa <Leisa.Sossamon@charlottenc.gov> Cc: Fortney, Caroline <Caroline.Fortney@charlottenc.gov> Subject: Fwd: [EXT]Property Access Letter - 2015 Custer St. Good afternoon, Please see email below regarding property access to a city owned property for an environmental assessment/sampling. Begin forwarded message: From: "White, Jeffrey R" <jeffrey.white@ncdenr.gov> Date: February 21, 2023 at 11:48:40 AM EST To: "Wells, Ebony" <Ebony.Wells@charlottenc.gov> Subject: [EXT]Property Access Letter - 2015 Custer St.  Ms. Wells, Please see the attachments for the property access form and letter with a brief explanation of the purpose and extent of our environmental assessment/sampling. I’ve also included a preliminary proposed sampling location map dependent upon how many properties respond/grant access. Thank you so much for your help and please do not hesitate to call/email me with any questions. Jeffrey R. White Hydrogeologist, Superfund Section Division of Waste Management North Carolina Department of Environmental Quality Office: (919) 707-8331 | Cell: (704) 692-4578 jeffrey.white@ncdenr.gov REFERENCE 21 Wood Environment & Infrastructure Solutions, Inc. 2801 Yorkmont Road, Suite 100 Charlotte, North Carolina 28208 Licensures: NC Engineering F-1253, Geology C-2478 T: 704-357-8600 www.woodplc.com ‘Wood’ is a trading name for John Wood Group PLC and its subsidiaries July 23, 2021 Ms. Pamela Alexander, MFFI Risk Management/Compliance Officer City of Charlotte Housing & Neighborhood Services (HNS) 600 East Trade Street Charlotte, North Carolina 28202 Subject: Report of Phase II Environmental Site Assessment Proposed Phoenix Rising Subdivision Custer Street and LaSalle Street Charlotte, North Carolina 28215 Wood Project: 6228-20-6016.01.36 Dear Ms. Alexander: Wood Environment & Infrastructure Solutions, Inc. (Wood) is pleased to submit this Report of Phase II Environmental Site Assessment (ESA) for the above-referenced site located in Charlotte, North Carolina. Included in this report is an outline of our understanding of the project information, a description of the assessment activities, a discussion of the laboratory results, and our conclusions. This assessment was completed in general accordance with our proposal Prop21CARO.188, dated June 7, 2021. Project Information The site located at Custer Street and LaSalle Street, Charlotte, North Carolina (Figure 1), is comprised of seven land parcels totaling approximately 2.45 acres of undeveloped former residential lots and undeveloped woodland areas. Wood recently completed a Phase I ESA at the site and identified the following adjoining property that has a potential to create a recognized environmental condition (REC) in connection with the site:  The North Carolina Department of Environmental Quality (NCDEQ) issued a Notice of Violation (NOV) on July 29, 1996 for the People’s Cleaners (1930 Beatties Ford Road) facility based on documented chlorinated solvent contamination from both tetrachlorethylene (PCE) and trichloroethene (TCE) found in the underlying groundwater. A Phase II Environmental Assessment report (dated March 4, 1996) also indicated the presence of accumulated liquid near floor drains and an empty drum that once contained PCE. On January 6, 2020, a Senior Environmental Specialist with the NCDEQ-DSCA Program visited the facility and observed a 15-gallon waste drum containing Phoenix Rising – Report of Phase II ESA Charlotte, North Carolina July 23, 2021 2 PCE stored in the boiler room of the facility. The spill containment container used for the waste drum was noted to not be large enough to hold the required 110% of the drum’s maximum capacity. Another 15-gallon drum of unknown liquid was observed being stored on a pallet in the boiler room of the facility. In addition to the drycleaner, this property was reportedly occupied by a gasoline station (Younges Service Station) from at least 1959 to 1984, and as Peoples Cleaners from at least 1989 to the present. Based on distance from the site, historical usage as a service station and drycleaner and documented groundwater impacts at the neighboring property, Wood considers the People’s Cleaners facility to have the potential to create a REC in connection with the site.  Surrounding properties to the west included a service station at 2012 Beatties Ford Road from at least 1974 to 1994. Based on distance from the site and historical usage as a service station at the adjoining facility located at 2012 Beatties Ford Road (currently Ford’s Used Tires), Wood considers this facility to have the potential to create a REC in connection with the site. City of Charlotte Housing & Neighborhood Services requested Wood perform a Phase II ESA to assess the site for potential impacts related to the identified RECs. The Phase II ESA activities are described in the sections below. Assessment Activities Prior to conducting the sub-surface assessment activities, Wood contacted the North Carolina underground utility location service (811) and a private underground utility locator to mark buried objects such as pipes, tanks, or underground utility lines. The purpose of this effort is to minimize the potential for probing into underground utilities, tanks or lines buried at the subject property. Soil-Gas Sampling and Analyses On July 6, 2021, Wood personnel and probing subcontractor licensed in the State of North Carolina, Innovative Environmental Technologies (IET), mobilized to the site to advance four soil borings for the installation of four temporary soil-gas sampling points (SG-1 to SG-4). The locations of the temporary soil-gas sampling points are shown on Figure 2. The soil-gas sampling was performed in general accordance with the NCDEQ Division of Waste Management (DWM) Vapor Intrusion Guidance, (dated March 2018). The IET probing crew advanced the four soil borings using an AMS PowerProbe 9500-VTR direct-push probe rig. A soil sampler was driven into the soil to remove soil cores from the subsurface. To minimize the potential for cross-contamination between sample locations, a new PVC sleeve (tube) was inserted into the sampler for each soil boring. The borings were advanced to an approximate total depth of five feet below ground surface (bgs). Dedicated soil-gas sampling points were placed into each borehole and connected to disposable tubing extending to the ground surface. A sand pack of approximately 8 to 10 inches thick was placed around the sampling points. The remaining annulus of the boreholes were filled with hydrated bentonite to ground surface. The tubing was then connected to a PVC tee with PVC ball Phoenix Rising – Report of Phase II ESA Charlotte, North Carolina July 23, 2021 3 valves on either side. One side of the tee was connected to a laboratory-provided, dedicated flow controller with an in-line vacuum gauge leading to a 1-liter Summa canister. The other side of the tee was connected to a peristaltic pump for sample train purging. Prior to sample collection, each sample train was purged of stagnant air and a leak-check was performed. The Summa canisters and sample train were surrounded by a helium-shroud for leak-check detection. The helium-shroud consisted of a plastic sheeting placed over the Summa canister and sample tubing, then filled with helium. Wood personnel collected the leak-check sample from the sample point by purging sub-slab soil gas into a Tedlar® bag. The purging flow rate was measured using a Sensidyne Go-Cal Air Flow meter and was conducted at an approximate flow rate of 200 milliliters per minute (mL/min). The leak-check sample was screened in the field for helium using an MGD-2002 Multi-Gas leak (di-electric) detector. Wood personnel also used the helium detector to monitor the concentration of helium inside the shroud. A leak was considered to occur when the helium concentration inside the Tedlar® bag was greater than 10% of the helium concentration within the shroud. Following the leak-check, a soil-gas sample was collected into the Summa canister at an approximate flow rate of 200 mL/min. Following collection of the soil-gas samples, the Summa canisters were delivered under chain-of-custody protocol to Pace Analytical Services, LLC (Pace), an American Industrial Hygiene Association (AIHA) – Laboratory Accreditation Programs (LAP) certified laboratory. The soil-gas samples were analyzed by Pace for volatile organic compounds (VOCs) via EPA Method TO-15. Following collection of the soil-gas samples, the soil-gas sampling points were removed, to the extent possible, and the boreholes were backfilled with bentonite to the ground surface. Soil cuttings generated during the installation of the soil-gas sampling points were spread onsite. Soil-gas sampling field worksheet are included as Attachment A. Groundwater Sampling and Analyses Following the completion of the soil borings for the soil-gas sampling points, on July 6, 2021, the IET probing crew off-set to the side of each boring by about 3 to 4 feet and advanced a second boring for the installation of temporary groundwater monitoring wells. The locations of the four temporary monitoring wells (TW-1 to TW-4) are shown on Figure 2. IET advanced the soil borings for the temporary well installation using the same methods to install the soil-gas sampling points as described above. The soil borings were advanced to an approximate depth of 15 feet bgs, except for TW-4 which was advanced to an approximate depth of 25 feet bgs due to lack of apparent moisture in the silt. Visual and olfactory observations relative to the soil cores were recorded by our field personnel. The soil types encountered in each of the temporary monitoring well borings were recorded to prepare soil boring field worksheets (Attachment B). Phoenix Rising – Report of Phase II ESA Charlotte, North Carolina July 23, 2021 4 The IET probing crew installed a temporary groundwater monitoring well consisting of a one-inch diameter PVC well screen (10-foot length) and riser in each of the four borings. A filter sand pack was placed around each well screen to approximately two feet above the screened interval. A bentonite seal was placed above the sand pack. Following installation, Wood personnel developed monitoring wells TW-1, TW-2, and TW-4 with a peristaltic pump until the purged water is visibly clear. TW-3 was not developed with a peristaltic pump due to the minimal saturated section observed during the installation of TW-3. The temporary wells were left to stabilize overnight prior to groundwater sampling. The temporary monitoring wells’ construction and abandonment driller records are included as Attachment C. On July 6, 2021, Wood personnel collected groundwater samples from the four temporary wells. Prior to sample collection, the well caps for each of the temporary groundwater monitoring wells were removed, and the water level was allowed to stabilize to ambient atmospheric pressure. The water level was measured in each well with an electronic water level probe to determine depth to the water surface from the top of the PVC riser pipe. The depth to groundwater ranged from 5.48 feet in temporary well TW-2 to 14.91 feet in well TW-4. Following the measurement of the depth to water in each well, temporary monitoring wells TW-1, TW-2, TW-3, and TW-4 were sampled using a peristaltic pump and dedicated tubing. The groundwater samples were collected using low flow purging techniques, to the extent possible, in general accordance with EPA Region IV SESD Field Branches Quality System and Technical Procedures guidance. During purging, groundwater field parameters were collected using a YSI ProPlus water quality meter with a commercially manufactured flow cell and an HFS MicroTPI turbidity meter. Groundwater field parameters collected through the flow cell included pH, specific conductivity, dissolved oxygen, temperature, and oxidation reduction potential. In well TW-3, with the least saturated section, the water level was unstable during purging. Therefore, sample collection occurred soon after purging commenced so that there would be water to sample. Following completion of purging, groundwater samples were collected from each well into laboratory- provided containers, placed in a cooler on ice, and delivered to Pace, a North Carolina certified laboratory, under chain-of-custody protocol. The groundwater samples were analyzed by Pace for VOCs via EPA Method 8260. Soil cuttings and purge water generated during the groundwater sampling activities were spread on site. Following sample collection, the PVC casings for the temporary monitoring wells were removed and the boreholes were backfilled using bentonite to the ground surface. Groundwater sampling field worksheets are included as Attachment D. Phoenix Rising – Report of Phase II ESA Charlotte, North Carolina July 23, 2021 5 Analytical Results The results of the soil-gas laboratory analysis are shown on Table 1. The laboratory analytical reports and chain-of-custody forms are included as Attachment E. A summary of the findings is as follows: Soil-Gas  Benzene was detected in the soil-gas samples collected from soil-gas sampling points SG-1, SG-2, SG-3, and SG-4 at concentrations of 43.4, 55.9, 48.3, and 44.6 µg/m3, respectively. The detected concentrations of benzene exceeded the NCDEQ DWM Residential Sub-Slab and Exterior Soil-Gas Screening Levels (SGSLs) of 12 µg/m3.  Naphthalene was detected in the soil-gas samples collected from soil-gas sampling points SG-1, SG-2, SG-3, and SG-4 at concentrations of 7.0, 7.5, 7.4, and 5.5 µg/m3, respectively. The detected concentrations of naphthalene exceeded the NCDEQ DWM Residential SGSLs of 2.8 µg/m3.  Detectable concentrations of acetone, 2-butanone, carbon disulfide, chloroethane, chloromethane, dichlorodifluoromethane, 1,2-dichloropropane, ethanol, ethylbenzene, 4-ethyltoluene, n-heptane, 2-hexanone, 4-methyl-2-pentanone, 2-propanol, propylene, styrene, tetrachloroethene, toluene, trichlorofluoromethane, 1,1,2-trichlorotrifluoroethane, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, vinyl chloride, m&p-xylene, and o-xylene were identified in soil-gas samples collected from at least one soil-gas sampling point. None of these concentrations exceeded the respective NCDEQ DWM Residential SGSLs. No other detectable VOC concentrations were identified in the soil-gas samples collected during this assessment. Groundwater  Results from the VOC analysis of the four groundwater samples did not report constituents above their respective laboratory reporting limits. Risk Assessment The NCDEQ Risk Calculator (June 2021 Version) was used to evaluate cumulative vapor intrusion risk for the site using the highest soil-gas concentration of each detected constituent. This assessment was performed in general accordance with the NCDEQ Risk Calculator User Guide dated February 2021, and the Risk Calculator output is provided as Attachment F. The soil-gas to indoor air pathway was considered for a resident receptor and the results show that neither the target carcinogenic risk (10-4) nor the target hazard index (1.0) was exceeded. Conclusions and Recommendations Based on the results of this assessment, Wood offers the following conclusions and recommendations:  Detectable concentrations of VOCs were not identified in the groundwater samples collected during this assessment. Based on these results, it appears the groundwater impacts identified at Phoenix Rising – Report of Phase II ESA Charlotte, North Carolina July 23, 2021 6 the adjoining People’s Cleaners facility (1930 Beatties Ford Road) or potential impacts from the adjoining former service station at 2012 Beatties Ford Road have not impacted the site and additional groundwater assessment activities are not recommended at this time.  Concentrations of VOCs which exceeded their respective NCDEQ Residential SGSLs were identified in the soil-gas samples collected during this assessment. The highest soil-gas concentration of each detected constituent was evaluated using the NCDEQ Risk Calculator for cumulative vapor intrusion risk and neither the carcinogenic risk or hazard index was exceeded. The results indicate that the potential for contaminant vapor intrusion into the planned residential buildings is low and further evaluation of vapor intrusion or vapor mitigation controls are not warranted at this time. Limitations Wood does not guarantee the subject properties are free of contamination or hazardous waste material due to unknown or latent conditions that may become evident in the future, either on the site or on adjoining or nearby properties. In addition, site conditions might change over time. Should further surface, subsurface, chemical, or other data become available after the date of issue of this report, the findings, conclusions, and recommendations contained herein may have to be modified. Review by Wood of such additional information would be conducted upon receipt of a written request from our client. The findings contained herein are relevant to the dates of Wood’s July 2021 site activities and should not be relied upon to represent conditions at later dates. If changes in the nature, usage, or layout of the property or nearby properties are made, the conclusions and recommendations contained in this report may not be valid. If additional information becomes available, it should be provided to Wood so the original conclusions and recommendations can be modified as necessary. Closing Wood appreciates the opportunity to provide our services to you. If you have questions, please contact the undersigned at (704) 357-5527 at your convenience. Sincerely, Wood Environment & Infrastructure Solutions, Inc. Morgan Snead Helen P. Corley, LG, BCES Staff Scientist Principal Hydrogeologist Enclosures FIGURES 7 4 0 7 2 0 760 740 740 7 2 0 760 720 7 20 760740 740740 720Sources: Esri, HERE, Garmin, Intermap, increment P Corp., GEBCO, USGS,FAO, NPS, NRCAN, GeoBase, IGN, Kadaster NL, Ordnance Survey, EsriJapan, METI, Esri China (Hong Kong), (c) OpenStreetMap contributors, andthe GIS User Community PREPARED BY: DATE: CHECKED BY: DATE: SITE TOPOPHOENIX RISING SUBDIVISIONLASALLE STREET AND CUSTER STREETCHARLOTTE, NORTH CAROLINA Document Path: F:\AMEC_Projects\2020\6228-20-6016 HUD\Pheonix\MXD\TopoUSE1.mxdPROJECT NO:6228206016 LM 3/19/2021 MS 3/19/2021 FIGURE:1 0 500 1,000Feet ¯ §¨¦521 §¨¦277 §¨¦16 §¨¦74 §¨¦77 §¨¦85 Legend Site Boundary Contour (20ft) Wood Environment & Infrastructure Solutions, Inc.2801 Yorkmont Road, Suite 100Charlotte, NC 28208(704) 357-8600 Lasalle St Custer StG a r n e t te P lLegend Site Boundary Parcel PREPARED BY: DATE: CHECKED BY: DATE: SAMPLE LOCATIONSPHOENIX RISING SUBDIVISIONLASALLE STREET AND CUSTER STREETCHARLOTTE, NORTH CAROLINA ¯Document Path: F:\AMEC_Projects\2020\6228-20-6016 HUD\Pheonix\MXD\SampleLocations.mxdPROJECT NO:6228206016 LM 7/23/2021 MS 7/23/2021 FIGURE:1 0 100 20050Feet Wood Environment & Infrastructure Solutions, Inc.2801 Yorkmont Road, Suite 100Charlotte, NC 28208(704) 357-8600 ! ! ! ! Peoples Dry Cleaners/Former Younges Service Station (1930 Beatties Ford Road) SG-1/TW-1 SG-2/TW-2 SG-3/TW-3 SG-4/TW-4 !Soil-Gas/Groundwater Sample Location TABLE Sample ID SG-1 SG-2 SG-3 SG-4 Sample Duration 6-minute 5-minute 5-minute 6-minute Sample Collection Date 7/6/2021 7/6/2021 7/6/2021 7/6/2021 Shroud Helium Concentration (ppm)1,300 46,000 34,000 27,000 Leak Check Helium Concentration (ppm)25 0.0 20 0.0 Acteone 49.8 53.6 78.3 60.2 220,000 Benzene 43.4 55.9 48.3 44.6 12 2-Butanone 16.8 17.4 27.3 9.6 35,000 Carbon Disulfide 117 55.4 49.4 28.8 4,900 Chloroethane <1.0 <1.1 4.3 2.4 70,000 Chloromethane 3.2 1.8 21.9 11.0 630 Dichlorodifluoromethane 2.8 2.8 2.9 2.7 700 1,2-Dichloropropane 4.5 5.5 3.8 2.5 25 Ethanol 29.3 18.3 25.6 13.5 NE Ethylbenzene 16.4 17.4 17.9 12.4 37 4-Ethyltoluene 8.6 6.9 8.3 5.2 NE n-Heptane 14.8 10.4 15.9 16.3 2,800 n-Hexane 58.2 18.1 31.8 35.9 4,900 2-Hexanone 27.1 25.8 28.8 <8.1 210 4-Methyl-2-pentanone 101 82.2 82.4 42.9 21,000 Naphthalene 7.0 7.5 7.4 5.5 2.8 2-Propanol 7.6 <5.0 <5.0 <4.8 1,400 Propylene 88.4 37.6 626 1,100 21,000 Styrene 2.0 2.1 4.4 4.7 7,000 Tetrachloroethene 14.8 105 7.5 9.2 280 Toluene 1,510 4,360 1,580 1,930 35,000 Trichlorofluoromethane 6.0 9.2 7.8 3.4 NE 1,1,2-Trichlorotrifluoroethane <2.9 3.2 3.4 <3.0 35,000 1,2,4-Trimethylbenzene 28.2 21.6 28.4 17.8 420 1,3,5-Trimethylbenzene 7.8 6.3 7.4 5.1 420 Vinyl chloride <0.49 <0.53 2.7 3.6 5.6 m&p-Xylene 51.8 44.3 54.9 35.5 700 o-Xylene 22.0 18.6 23.0 15.3 700 Notes:Prepared By/Date: MAS 7/19/21 1. Concentrations shown in micrograms per meter cubed (µg/m3)Checked By/Date: RPD 7/20/21 2. NCDEQ Residential SGSLs = Division of Waste Management Residential Sub-Slab and Exterior Soil-Gas Screening Levels, dated June 2021 3. TCR = Target Cancer Risk 4. THQ = Target Hazard Quotient 5. Values shown with "<" were not detected above the referenced laboratory reporting limit (RL) 6. Bolded and shaded values exceed the NCDEQ Residential SGSLs 6. NE = Standard not established 7. ppm = parts per million NCDEQ Residential SGSL (TCR = 1.0E-06; THQ=0.2) (µg/m3) Table 1 - Summary of Soil-Gas Analytical Results Phoenix Rising Subdivision Charlotte, North Carolina Wood Project Number 6228-20-6016.01.36 ATTACHMENT A SOIL-GAS SAMPLING FIELD WORKSHEETS ATTACHMENT B SOIL BORING FIELD WORKSHEETS Red, Brown, Brown Clayey SILT Tan, Gold Sandy SILT, black mottling Tan, Gold, Sandy SILT. Wet Boring Terminated at 15 Ft with 10 Ft screen (5-15 ft)Sand 3-15 FtBentonite 0-3 Ft DEPTH (ft) 10 20 30 40 50 60 70 80 90 100 THIS RECORD IS A REASONABLE INTERPRETATIONOF SUBSURFACE CONDITIONS AT THE EXPLORATIONLOCATION. SUBSURFACE CONDITIONS AT OTHERLOCATIONS AND AT OTHER TIMES MAY DIFFER.INTERFACES BETWEEN STRATA ARE APPROXIMATE.TRANSITIONS BETWEEN STRATA MAY BE GRADUAL. 10 20 30 40 50 60 70 80 90 100 PAGE 1 OF 1 BORING NO.: TW-1 SOIL BORING LOG SAMPLES TYPE FINES (%) SPT N-Value (bpf) Moist (%)LEGEND Charlotte HNS July 6, 2021 6228-20-6016 AMS POWER PROB 950VTR 6 Inches ELEV (ft) 5 10 15 20 25 30 35 IDENT SEE KEY SYMBOL SHEET FOR EXPLANATION OFSYMBOLS AND ABBREVIATIONS BELOW. SOIL CLASSIFICATIONAND REMARKS PL (%) STANDARDPENETRATIONTEST(blows per6" increment) LL (%) PROJECT: NORTHING: EASTING: DRILLED: PROJ NUM: DRILLER: EQUIPMENT: METHOD: HOLE DIA.: REMARKS: LOGGED BY: PREPARED BY: CHECKED BY: 0 5 10 15 20 25 30 35 40OLD LOGS.GPJ 7/21/21 Tan, Brown, Clayey SILT Tan Brown, Sandy SILT Tan Brown, Sandy SILT, Wet Boring Terminated at 15 Ft with 10 Ft Screen (5-15 ft) Sand 3-15 FtBent 0-3 Ft DEPTH (ft) 10 20 30 40 50 60 70 80 90 100 THIS RECORD IS A REASONABLE INTERPRETATIONOF SUBSURFACE CONDITIONS AT THE EXPLORATIONLOCATION. SUBSURFACE CONDITIONS AT OTHERLOCATIONS AND AT OTHER TIMES MAY DIFFER.INTERFACES BETWEEN STRATA ARE APPROXIMATE.TRANSITIONS BETWEEN STRATA MAY BE GRADUAL. 10 20 30 40 50 60 70 80 90 100 PAGE 1 OF 1 BORING NO.: TW-2 SOIL BORING LOG SAMPLES TYPE FINES (%) SPT N-Value (bpf) Moist (%)LEGEND Charlotte HNS July 6, 2021 6228-20-6016 AMS POWER PROB 950VTR 6 Inches ELEV (ft) 5 10 15 20 25 30 35 IDENT SEE KEY SYMBOL SHEET FOR EXPLANATION OFSYMBOLS AND ABBREVIATIONS BELOW. SOIL CLASSIFICATIONAND REMARKS PL (%) STANDARDPENETRATIONTEST(blows per6" increment) LL (%) PROJECT: NORTHING: EASTING: DRILLED: PROJ NUM: DRILLER: EQUIPMENT: METHOD: HOLE DIA.: REMARKS: LOGGED BY: PREPARED BY: CHECKED BY: 0 5 10 15 20 25 30 35 40OLD LOGS.GPJ 7/21/21 ASPHALT/GRAVEL Red, Brown, Clayey SILT Brown, Tan, Sandy SILT Brown, Tan, Sandy SILT, Wet Boring Terminated at 15 Ft with 10 Ft Screen (5-10 ft) Sand 3-15 FtBent 0-3 Ft DEPTH (ft) 10 20 30 40 50 60 70 80 90 100 THIS RECORD IS A REASONABLE INTERPRETATIONOF SUBSURFACE CONDITIONS AT THE EXPLORATIONLOCATION. SUBSURFACE CONDITIONS AT OTHERLOCATIONS AND AT OTHER TIMES MAY DIFFER.INTERFACES BETWEEN STRATA ARE APPROXIMATE.TRANSITIONS BETWEEN STRATA MAY BE GRADUAL. 10 20 30 40 50 60 70 80 90 100 PAGE 1 OF 1 BORING NO.: TW-3 SOIL BORING LOG SAMPLES TYPE FINES (%) SPT N-Value (bpf) Moist (%)LEGEND Charlotte HNS July 6, 2021 6228-20-6016 AMS POWER PROB 950VTR 6 Inches ELEV (ft) 5 10 15 20 25 30 35 IDENT SEE KEY SYMBOL SHEET FOR EXPLANATION OFSYMBOLS AND ABBREVIATIONS BELOW. SOIL CLASSIFICATIONAND REMARKS PL (%) STANDARDPENETRATIONTEST(blows per6" increment) LL (%) PROJECT: NORTHING: EASTING: DRILLED: PROJ NUM: DRILLER: EQUIPMENT: METHOD: HOLE DIA.: REMARKS: LOGGED BY: PREPARED BY: CHECKED BY: 0 5 10 15 20 25 30 35 40OLD LOGS.GPJ 7/21/21 Tan, Orange, Clayey SILT Tan, Brown, Clayey SILT Brown Clayey SILT Tan, Orange Clayey SILT Tan, Orange Clayey SILT Boring Terminated at 25 Ft with 10 Ft Screen (15-25 ft) Sand 13-25 FtBent 0-13 Ft DEPTH (ft) 10 20 30 40 50 60 70 80 90 100 THIS RECORD IS A REASONABLE INTERPRETATIONOF SUBSURFACE CONDITIONS AT THE EXPLORATIONLOCATION. SUBSURFACE CONDITIONS AT OTHERLOCATIONS AND AT OTHER TIMES MAY DIFFER.INTERFACES BETWEEN STRATA ARE APPROXIMATE.TRANSITIONS BETWEEN STRATA MAY BE GRADUAL. 10 20 30 40 50 60 70 80 90 100 PAGE 1 OF 1 BORING NO.: TW-4 SOIL BORING LOG SAMPLES TYPE FINES (%) SPT N-Value (bpf) Moist (%)LEGEND Charlotte HNS July 6, 2021 6228-20-6016 AMS POWER PROB 950VTR 6 Inches ELEV (ft) 5 10 15 20 25 30 35 IDENT SEE KEY SYMBOL SHEET FOR EXPLANATION OFSYMBOLS AND ABBREVIATIONS BELOW. SOIL CLASSIFICATIONAND REMARKS PL (%) STANDARDPENETRATIONTEST(blows per6" increment) LL (%) PROJECT: NORTHING: EASTING: DRILLED: PROJ NUM: DRILLER: EQUIPMENT: METHOD: HOLE DIA.: REMARKS: LOGGED BY: PREPARED BY: CHECKED BY: 0 5 10 15 20 25 30 35 40OLD LOGS.GPJ 7/21/21 ATTACHMENT C TEMPORARY MONITORING WELL CONSTRUCTION AND ABANDONMENT RECORDS WELL CONSTRUCTION RECORD (GW-1) For Internal Use Only: Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revised 2-22-2016 1. Well Contractor Information: Well Contractor Name NC Well Contractor Certification Number Company Name 2. Well Construction Permit #: List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.) 3. Well Use (check well use): Water Supply Well: Agricultural Municipal/Public Geothermal (Heating/Cooling Supply) Residential Water Supply (single) Industrial/Commercial Residential Water Supply (shared) Irrigation Non-Water Supply Well: Monitoring Recovery Injection Well: Aquifer Recharge Groundwater Remediation Aquifer Storage and Recovery Salinity Barrier Aquifer Test Stormwater Drainage Experimental Technology Subsidence Control Geothermal (Closed Loop) Tracer Geothermal (Heating/Cooling Return) Other (explain under #21 Remarks) 4. Date Well(s) Completed: Well ID# 5a. Well Location: Facility/Owner Name Facility ID# (if applicable) Physical Address, City, and Zip County Parcel Identification No. (PIN) 5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W 6. Is(are) the well(s): Permanent or Temporary 7. Is this a repair to an existing well: Yes or No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form. 8. For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same construction, only 1 GW-1 is needed. Indicate TOTAL NUMBER of wells drilled: 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- ) 10. Static water level below top of casing: (ft.) If water level is above casing, 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount: 14. WATER ZONES FROM TO DESCRIPTION ft.ft. ft.ft. 15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL ft.ft.in. 16. INNER CASING OR TUBING (geothermal closed-loop) FROM TO DIAMETER THICKNESS MATERIAL ft.ft.in. ft.ft.in. 17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL ft.ft.in. ft.ft.in. 18. GROUT FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT ft.ft. ft.ft. ft.ft. 19. SAND/GRAVEL PACK (if applicable) FROM TO MATERIAL EMPLACEMENT METHOD ft.ft. ft.ft. 20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.) ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. 21. REMARKS 22. Certification: Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner. 23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTRUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617 24b. For Injection Wells: In addition to sending the form to the address in 24a above, also submit one copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636 24c. For Water Supply & Injection Wells: In addition to sending the form to the address(es) above, also submit one copy of this form within 30 days of completion of well construction to the county health department of the county where constructed. Terry White 3287-A IET one 7/6/2021 TW-1 Vacant Lot 2041 Custer St. Charlotte 28216 Mecklenburg 35 15 44 80 51 12 15 10.95 2 1/4 Direct Push 7/8/2021 10.95 15 0 5 1 sch40 PVC 5 15 1 0.010 sch40 PVC 0 3 3 15 Bentonite #2 Sand Poured Poured/4LB See Consultant Log WELL ABANDONMENT RECORD Form GW-30 North Carolina Department of Environmental Quality - Division of Water Resources Revised 2-22-2016 1. Well Contractor Information: Well Contractor Name (or well owner personally abandoning well on his/her property) NC Well Contractor Certification Number Company Name 2. Well Construction Permit #: List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.) if known 3. Well use (check well use): Water Supply Well: Agricultural Municipal/Public Geothermal (Heating/Cooling Supply)Residential Water Supply (single) Industrial/Commercial Residential Water Supply (shared) Irrigation Non-Water Supply Well: Monitoring Recovery Injection Well: Aquifer Recharge Groundwater Remediation Aquifer Storage and Recovery Salinity Barrier Aquifer Test Stormwater Drainage Experimental Technology Subsidence Control Geothermal (Closed Loop)Tracer Geothermal (Heating/Cooling Return) Other (explain under 7g) 4. Date well(s) abandoned: 5a. Well location: Facility/Owner Name Facility ID# (if applicable) Physical Address, City, and Zip County Parcel Identification No. (PIN) 5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W CONSTRUCTION DETAILS OF WELL(S) BEING ABANDONED Attach well construction record(s) if available. For multiple injection or non-water supply wells ONLY with the same construction/abandonment, you can submit one form. 6a. Well ID#: 6b. Total well depth: (ft.) 6c. Borehole diameter: (in.) 6d. Water level below ground surface: (ft.) 6e. Outer casing length (if known): (ft.) 6f. Inner casing/tubing length (if known): (ft.) 6g. Screen length (if known): (ft.) WELL ABANDONMENT DETAILS 7a. For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same well construction/depth, only 1 GW-30 is needed. Indicate TOTAL NUMBER of wells abandoned: 7b. Approximate volume of water remaining in well(s): (gal.) FOR WATER SUPPLY WELLS ONLY: 7c. Type of disinfectant used: 7d. Amount of disinfectant used: 7e. Sealing materials used (check all that apply): Neat Cement Grout Bentonite Chips or Pellets Sand Cement Grout Dry Clay Concrete Grout Drill Cuttings Specialty Grout Gravel Bentonite Slurry Other (explain under 7g) 7f. For each material selected above, provide amount of materials used: 7g. Provide a brief description of the abandonment procedure: 8. Certification: Signature of Certified Well Contractor or Well Owner Date By signing this form, I hereby certify that the well(s) was (were) abandoned in accordance with 15A NCAC 02C .0100 or 2C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner. 9. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well abandonment details. You may also attach additional pages if necessary. SUBMITTAL INSTRUCTIONS 10a. For All Wells: Submit this form within 30 days of completion of well abandonment to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617 10b. For Injection Wells: In addition to sending the form to the address in 10a above, also submit one copy of this form within 30 days of completion of well abandonment to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636 10c. For Water Supply & Injection Wells: In addition to sending the form to the address(es) above, also submit one copy of this form within 30 days of completion of well abandonment to the county health department of the county where abandoned. For Internal Use ONLY: WELL CONSTRUCTION RECORD (GW-1) For Internal Use Only: Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revised 2-22-2016 1. Well Contractor Information: Well Contractor Name NC Well Contractor Certification Number Company Name 2. Well Construction Permit #: List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.) 3. Well Use (check well use): Water Supply Well: Agricultural Municipal/Public Geothermal (Heating/Cooling Supply) Residential Water Supply (single) Industrial/Commercial Residential Water Supply (shared) Irrigation Non-Water Supply Well: Monitoring Recovery Injection Well: Aquifer Recharge Groundwater Remediation Aquifer Storage and Recovery Salinity Barrier Aquifer Test Stormwater Drainage Experimental Technology Subsidence Control Geothermal (Closed Loop) Tracer Geothermal (Heating/Cooling Return) Other (explain under #21 Remarks) 4. Date Well(s) Completed: Well ID# 5a. Well Location: Facility/Owner Name Facility ID# (if applicable) Physical Address, City, and Zip County Parcel Identification No. (PIN) 5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W 6. Is(are) the well(s): Permanent or Temporary 7. Is this a repair to an existing well: Yes or No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form. 8. For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same construction, only 1 GW-1 is needed. Indicate TOTAL NUMBER of wells drilled: 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- ) 10. Static water level below top of casing: (ft.) If water level is above casing, 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount: 14. WATER ZONES FROM TO DESCRIPTION ft.ft. ft.ft. 15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL ft.ft.in. 16. INNER CASING OR TUBING (geothermal closed-loop) FROM TO DIAMETER THICKNESS MATERIAL ft.ft.in. ft.ft.in. 17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL ft.ft.in. ft.ft.in. 18. GROUT FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT ft.ft. ft.ft. ft.ft. 19. SAND/GRAVEL PACK (if applicable) FROM TO MATERIAL EMPLACEMENT METHOD ft.ft. ft.ft. 20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.) ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. 21. REMARKS 22. Certification: Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner. 23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTRUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617 24b. For Injection Wells: In addition to sending the form to the address in 24a above, also submit one copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636 24c. For Water Supply & Injection Wells: In addition to sending the form to the address(es) above, also submit one copy of this form within 30 days of completion of well construction to the county health department of the county where constructed. Terry White 3287-A IET one 7/6/2021 TW-2 Vacant Lot 2041 Custer St. Charlotte 28216 Mecklenburg 35 15 44 80 51 12 15 5.48 2 1/4 Direct Push 7/8/2021 5.48 15 0 5 1 sch40 PVC 5 15 1 0.010 sch40 PVC 0 3 3 15 Bentonite #2 Sand Poured Poured/4LB See Consultant Log WELL ABANDONMENT RECORD Form GW-30 North Carolina Department of Environmental Quality - Division of Water Resources Revised 2-22-2016 1. Well Contractor Information: Well Contractor Name (or well owner personally abandoning well on his/her property) NC Well Contractor Certification Number Company Name 2. Well Construction Permit #: List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.) if known 3. Well use (check well use): Water Supply Well: Agricultural Municipal/Public Geothermal (Heating/Cooling Supply)Residential Water Supply (single) Industrial/Commercial Residential Water Supply (shared) Irrigation Non-Water Supply Well: Monitoring Recovery Injection Well: Aquifer Recharge Groundwater Remediation Aquifer Storage and Recovery Salinity Barrier Aquifer Test Stormwater Drainage Experimental Technology Subsidence Control Geothermal (Closed Loop)Tracer Geothermal (Heating/Cooling Return) Other (explain under 7g) 4. Date well(s) abandoned: 5a. Well location: Facility/Owner Name Facility ID# (if applicable) Physical Address, City, and Zip County Parcel Identification No. (PIN) 5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W CONSTRUCTION DETAILS OF WELL(S) BEING ABANDONED Attach well construction record(s) if available. For multiple injection or non-water supply wells ONLY with the same construction/abandonment, you can submit one form. 6a. Well ID#: 6b. Total well depth: (ft.) 6c. Borehole diameter: (in.) 6d. Water level below ground surface: (ft.) 6e. Outer casing length (if known): (ft.) 6f. Inner casing/tubing length (if known): (ft.) 6g. Screen length (if known): (ft.) WELL ABANDONMENT DETAILS 7a. For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same well construction/depth, only 1 GW-30 is needed. Indicate TOTAL NUMBER of wells abandoned: 7b. Approximate volume of water remaining in well(s): (gal.) FOR WATER SUPPLY WELLS ONLY: 7c. Type of disinfectant used: 7d. Amount of disinfectant used: 7e. Sealing materials used (check all that apply): Neat Cement Grout Bentonite Chips or Pellets Sand Cement Grout Dry Clay Concrete Grout Drill Cuttings Specialty Grout Gravel Bentonite Slurry Other (explain under 7g) 7f. For each material selected above, provide amount of materials used: 7g. Provide a brief description of the abandonment procedure: 8. Certification: Signature of Certified Well Contractor or Well Owner Date By signing this form, I hereby certify that the well(s) was (were) abandoned in accordance with 15A NCAC 02C .0100 or 2C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner. 9. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well abandonment details. You may also attach additional pages if necessary. SUBMITTAL INSTRUCTIONS 10a. For All Wells: Submit this form within 30 days of completion of well abandonment to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617 10b. For Injection Wells: In addition to sending the form to the address in 10a above, also submit one copy of this form within 30 days of completion of well abandonment to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636 10c. For Water Supply & Injection Wells: In addition to sending the form to the address(es) above, also submit one copy of this form within 30 days of completion of well abandonment to the county health department of the county where abandoned. For Internal Use ONLY: WELL CONSTRUCTION RECORD (GW-1) For Internal Use Only: Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revised 2-22-2016 1. Well Contractor Information: Well Contractor Name NC Well Contractor Certification Number Company Name 2. Well Construction Permit #: List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.) 3. Well Use (check well use): Water Supply Well: Agricultural Municipal/Public Geothermal (Heating/Cooling Supply) Residential Water Supply (single) Industrial/Commercial Residential Water Supply (shared) Irrigation Non-Water Supply Well: Monitoring Recovery Injection Well: Aquifer Recharge Groundwater Remediation Aquifer Storage and Recovery Salinity Barrier Aquifer Test Stormwater Drainage Experimental Technology Subsidence Control Geothermal (Closed Loop) Tracer Geothermal (Heating/Cooling Return) Other (explain under #21 Remarks) 4. Date Well(s) Completed: Well ID# 5a. Well Location: Facility/Owner Name Facility ID# (if applicable) Physical Address, City, and Zip County Parcel Identification No. (PIN) 5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W 6. Is(are) the well(s): Permanent or Temporary 7. Is this a repair to an existing well: Yes or No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form. 8. For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same construction, only 1 GW-1 is needed. Indicate TOTAL NUMBER of wells drilled: 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- ) 10. Static water level below top of casing: (ft.) If water level is above casing, 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount: 14. WATER ZONES FROM TO DESCRIPTION ft.ft. ft.ft. 15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL ft.ft.in. 16. INNER CASING OR TUBING (geothermal closed-loop) FROM TO DIAMETER THICKNESS MATERIAL ft.ft.in. ft.ft.in. 17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL ft.ft.in. ft.ft.in. 18. GROUT FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT ft.ft. ft.ft. ft.ft. 19. SAND/GRAVEL PACK (if applicable) FROM TO MATERIAL EMPLACEMENT METHOD ft.ft. ft.ft. 20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.) ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. 21. REMARKS 22. Certification: Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner. 23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTRUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617 24b. For Injection Wells: In addition to sending the form to the address in 24a above, also submit one copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636 24c. For Water Supply & Injection Wells: In addition to sending the form to the address(es) above, also submit one copy of this form within 30 days of completion of well construction to the county health department of the county where constructed. Terry White 3287-A IET one 7/6/2021 TW-3 Vacant Lot 2041 Custer St. Charlotte 28216 Mecklenburg 35 15 44 80 51 12 15 8.74 2 1/4 Direct Push 7/8/2021 8.74 15 0 5 1 sch40 PVC 5 15 1 0.010 sch40 PVC 0 3 3 15 Bentonite #2 Sand Poured Poured/4LB See Consultant Log WELL ABANDONMENT RECORD Form GW-30 North Carolina Department of Environmental Quality - Division of Water Resources Revised 2-22-2016 1. Well Contractor Information: Well Contractor Name (or well owner personally abandoning well on his/her property) NC Well Contractor Certification Number Company Name 2. Well Construction Permit #: List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.) if known 3. Well use (check well use): Water Supply Well: Agricultural Municipal/Public Geothermal (Heating/Cooling Supply)Residential Water Supply (single) Industrial/Commercial Residential Water Supply (shared) Irrigation Non-Water Supply Well: Monitoring Recovery Injection Well: Aquifer Recharge Groundwater Remediation Aquifer Storage and Recovery Salinity Barrier Aquifer Test Stormwater Drainage Experimental Technology Subsidence Control Geothermal (Closed Loop)Tracer Geothermal (Heating/Cooling Return) Other (explain under 7g) 4. Date well(s) abandoned: 5a. Well location: Facility/Owner Name Facility ID# (if applicable) Physical Address, City, and Zip County Parcel Identification No. (PIN) 5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W CONSTRUCTION DETAILS OF WELL(S) BEING ABANDONED Attach well construction record(s) if available. For multiple injection or non-water supply wells ONLY with the same construction/abandonment, you can submit one form. 6a. Well ID#: 6b. Total well depth: (ft.) 6c. Borehole diameter: (in.) 6d. Water level below ground surface: (ft.) 6e. Outer casing length (if known): (ft.) 6f. Inner casing/tubing length (if known): (ft.) 6g. Screen length (if known): (ft.) WELL ABANDONMENT DETAILS 7a. For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same well construction/depth, only 1 GW-30 is needed. Indicate TOTAL NUMBER of wells abandoned: 7b. Approximate volume of water remaining in well(s): (gal.) FOR WATER SUPPLY WELLS ONLY: 7c. Type of disinfectant used: 7d. Amount of disinfectant used: 7e. Sealing materials used (check all that apply): Neat Cement Grout Bentonite Chips or Pellets Sand Cement Grout Dry Clay Concrete Grout Drill Cuttings Specialty Grout Gravel Bentonite Slurry Other (explain under 7g) 7f. For each material selected above, provide amount of materials used: 7g. Provide a brief description of the abandonment procedure: 8. Certification: Signature of Certified Well Contractor or Well Owner Date By signing this form, I hereby certify that the well(s) was (were) abandoned in accordance with 15A NCAC 02C .0100 or 2C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner. 9. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well abandonment details. You may also attach additional pages if necessary. SUBMITTAL INSTRUCTIONS 10a. For All Wells: Submit this form within 30 days of completion of well abandonment to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617 10b. For Injection Wells: In addition to sending the form to the address in 10a above, also submit one copy of this form within 30 days of completion of well abandonment to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636 10c. For Water Supply & Injection Wells: In addition to sending the form to the address(es) above, also submit one copy of this form within 30 days of completion of well abandonment to the county health department of the county where abandoned. For Internal Use ONLY: WELL CONSTRUCTION RECORD (GW-1) For Internal Use Only: Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revised 2-22-2016 1. Well Contractor Information: Well Contractor Name NC Well Contractor Certification Number Company Name 2. Well Construction Permit #: List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.) 3. Well Use (check well use): Water Supply Well: Agricultural Municipal/Public Geothermal (Heating/Cooling Supply) Residential Water Supply (single) Industrial/Commercial Residential Water Supply (shared) Irrigation Non-Water Supply Well: Monitoring Recovery Injection Well: Aquifer Recharge Groundwater Remediation Aquifer Storage and Recovery Salinity Barrier Aquifer Test Stormwater Drainage Experimental Technology Subsidence Control Geothermal (Closed Loop) Tracer Geothermal (Heating/Cooling Return) Other (explain under #21 Remarks) 4. Date Well(s) Completed: Well ID# 5a. Well Location: Facility/Owner Name Facility ID# (if applicable) Physical Address, City, and Zip County Parcel Identification No. (PIN) 5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W 6. Is(are) the well(s): Permanent or Temporary 7. Is this a repair to an existing well: Yes or No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form. 8. For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same construction, only 1 GW-1 is needed. Indicate TOTAL NUMBER of wells drilled: 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- ) 10. Static water level below top of casing: (ft.) If water level is above casing, 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount: 14. WATER ZONES FROM TO DESCRIPTION ft.ft. ft.ft. 15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL ft.ft.in. 16. INNER CASING OR TUBING (geothermal closed-loop) FROM TO DIAMETER THICKNESS MATERIAL ft.ft.in. ft.ft.in. 17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL ft.ft.in. ft.ft.in. 18. GROUT FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT ft.ft. ft.ft. ft.ft. 19. SAND/GRAVEL PACK (if applicable) FROM TO MATERIAL EMPLACEMENT METHOD ft.ft. ft.ft. 20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.) ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. 21. REMARKS 22. Certification: Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner. 23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTRUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617 24b. For Injection Wells: In addition to sending the form to the address in 24a above, also submit one copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636 24c. For Water Supply & Injection Wells: In addition to sending the form to the address(es) above, also submit one copy of this form within 30 days of completion of well construction to the county health department of the county where constructed. Terry White 3287-A IET one 7/6/2021 TW-4 Vacant Lot 2041 Custer St. Charlotte 28216 Mecklenburg 35 15 44 80 51 12 25 14.91 2 1/4 Direct Push 7/8/2021 14.91 25 0 15 1 sch40 PVC 15 25 1 0.010 sch40 PVC 0 13 13 25 Bentonite #2 Sand Poured Poured/11LB See Consultant Log WELL ABANDONMENT RECORD Form GW-30 North Carolina Department of Environmental Quality - Division of Water Resources Revised 2-22-2016 1. Well Contractor Information: Well Contractor Name (or well owner personally abandoning well on his/her property) NC Well Contractor Certification Number Company Name 2. Well Construction Permit #: List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.) if known 3. Well use (check well use): Water Supply Well: Agricultural Municipal/Public Geothermal (Heating/Cooling Supply)Residential Water Supply (single) Industrial/Commercial Residential Water Supply (shared) Irrigation Non-Water Supply Well: Monitoring Recovery Injection Well: Aquifer Recharge Groundwater Remediation Aquifer Storage and Recovery Salinity Barrier Aquifer Test Stormwater Drainage Experimental Technology Subsidence Control Geothermal (Closed Loop)Tracer Geothermal (Heating/Cooling Return) Other (explain under 7g) 4. Date well(s) abandoned: 5a. Well location: Facility/Owner Name Facility ID# (if applicable) Physical Address, City, and Zip County Parcel Identification No. (PIN) 5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W CONSTRUCTION DETAILS OF WELL(S) BEING ABANDONED Attach well construction record(s) if available. For multiple injection or non-water supply wells ONLY with the same construction/abandonment, you can submit one form. 6a. Well ID#: 6b. Total well depth: (ft.) 6c. Borehole diameter: (in.) 6d. Water level below ground surface: (ft.) 6e. Outer casing length (if known): (ft.) 6f. Inner casing/tubing length (if known): (ft.) 6g. Screen length (if known): (ft.) WELL ABANDONMENT DETAILS 7a. For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same well construction/depth, only 1 GW-30 is needed. Indicate TOTAL NUMBER of wells abandoned: 7b. Approximate volume of water remaining in well(s): (gal.) FOR WATER SUPPLY WELLS ONLY: 7c. Type of disinfectant used: 7d. Amount of disinfectant used: 7e. Sealing materials used (check all that apply): Neat Cement Grout Bentonite Chips or Pellets Sand Cement Grout Dry Clay Concrete Grout Drill Cuttings Specialty Grout Gravel Bentonite Slurry Other (explain under 7g) 7f. For each material selected above, provide amount of materials used: 7g. Provide a brief description of the abandonment procedure: 8. Certification: Signature of Certified Well Contractor or Well Owner Date By signing this form, I hereby certify that the well(s) was (were) abandoned in accordance with 15A NCAC 02C .0100 or 2C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner. 9. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well abandonment details. You may also attach additional pages if necessary. SUBMITTAL INSTRUCTIONS 10a. For All Wells: Submit this form within 30 days of completion of well abandonment to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617 10b. For Injection Wells: In addition to sending the form to the address in 10a above, also submit one copy of this form within 30 days of completion of well abandonment to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636 10c. For Water Supply & Injection Wells: In addition to sending the form to the address(es) above, also submit one copy of this form within 30 days of completion of well abandonment to the county health department of the county where abandoned. For Internal Use ONLY: ATTACHMENT D GROUNDWATER SAMPLING FIELD WORKSHEETS ATTACHMENT E LABORATORY ANALYTICAL REPORTS AND CHAIN-OF-CUSTODY FORMS #=CL# July 13, 2021 LIMS USE: FR - MATT MILLER LIMS OBJECT ID: 92548178 92548178 Project: Pace Project No.: RE: Mr. Matt Miller WOOD E&I 2801 Yorkmont Road Charlotte, NC 28208 Phoenix Rising Dear Mr. Miller: Enclosed are the analytical results for sample(s) received by the laboratory on July 07, 2021. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Ryan Brumfield ryan.brumfield@pacelabs.com Project Manager (770)734-4200 Enclosures cc:Mr. Andrew Frantz, WOOD E&I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 26 #=CP# CERTIFICATIONS Pace Project No.: Project: 92548178 Phoenix Rising Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 26 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92548178 Phoenix Rising Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92548178001 TW-1 EPA 8260D 63 PASI-CCL 92548178002 TW-2 EPA 8260D 63 PASI-CSAS 92548178003 TW-3 EPA 8260D 63 PASI-CCL 92548178004 TW-4 EPA 8260D 63 PASI-CCL PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 26 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92548178 Phoenix Rising Sample:TW-1 Lab ID:92548178001 Collected:07/07/21 11:30 Received:07/07/21 15:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Acetone ND ug/L 07/09/21 18:22 67-64-125.0 1 Benzene ND ug/L 07/09/21 18:22 71-43-21.0 1 Bromobenzene ND ug/L 07/09/21 18:22 108-86-11.0 1 Bromochloromethane ND ug/L 07/09/21 18:22 74-97-51.0 1 Bromodichloromethane ND ug/L 07/09/21 18:22 75-27-41.0 1 Bromoform ND ug/L 07/09/21 18:22 75-25-21.0 1 Bromomethane ND ug/L 07/09/21 18:22 74-83-92.0 1 2-Butanone (MEK)ND ug/L 07/09/21 18:22 78-93-35.0 1 Carbon tetrachloride ND ug/L 07/09/21 18:22 56-23-51.0 1 Chlorobenzene ND ug/L 07/09/21 18:22 108-90-71.0 1 Chloroethane ND ug/L 07/09/21 18:22 75-00-31.0 1 Chloroform ND ug/L 07/09/21 18:22 67-66-31.0 1 Chloromethane ND ug/L 07/09/21 18:22 74-87-31.0 1 2-Chlorotoluene ND ug/L 07/09/21 18:22 95-49-81.0 1 4-Chlorotoluene ND ug/L 07/09/21 18:22 106-43-41.0 1 1,2-Dibromo-3-chloropropane ND ug/L 07/09/21 18:22 96-12-82.0 1 Dibromochloromethane ND ug/L 07/09/21 18:22 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 07/09/21 18:22 106-93-41.0 1 Dibromomethane ND ug/L 07/09/21 18:22 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 07/09/21 18:22 95-50-11.0 1 1,3-Dichlorobenzene ND ug/L 07/09/21 18:22 541-73-11.0 1 1,4-Dichlorobenzene ND ug/L 07/09/21 18:22 106-46-71.0 1 Dichlorodifluoromethane ND ug/L 07/09/21 18:22 75-71-8 v11.0 1 1,1-Dichloroethane ND ug/L 07/09/21 18:22 75-34-31.0 1 1,2-Dichloroethane ND ug/L 07/09/21 18:22 107-06-21.0 1 1,1-Dichloroethene ND ug/L 07/09/21 18:22 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 07/09/21 18:22 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 07/09/21 18:22 156-60-51.0 1 1,2-Dichloropropane ND ug/L 07/09/21 18:22 78-87-51.0 1 1,3-Dichloropropane ND ug/L 07/09/21 18:22 142-28-91.0 1 2,2-Dichloropropane ND ug/L 07/09/21 18:22 594-20-71.0 1 1,1-Dichloropropene ND ug/L 07/09/21 18:22 563-58-61.0 1 cis-1,3-Dichloropropene ND ug/L 07/09/21 18:22 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 07/09/21 18:22 10061-02-61.0 1 Diisopropyl ether ND ug/L 07/09/21 18:22 108-20-31.0 1 Ethylbenzene ND ug/L 07/09/21 18:22 100-41-41.0 1 Hexachloro-1,3-butadiene ND ug/L 07/09/21 18:22 87-68-32.0 1 2-Hexanone ND ug/L 07/09/21 18:22 591-78-65.0 1 p-Isopropyltoluene ND ug/L 07/09/21 18:22 99-87-61.0 1 Methylene Chloride ND ug/L 07/09/21 18:22 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 07/09/21 18:22 108-10-15.0 1 Methyl-tert-butyl ether ND ug/L 07/09/21 18:22 1634-04-41.0 1 Naphthalene ND ug/L 07/09/21 18:22 91-20-31.0 1 Styrene ND ug/L 07/09/21 18:22 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 07/09/21 18:22 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 07/09/21 18:22 79-34-51.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/13/2021 12:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 26 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92548178 Phoenix Rising Sample:TW-1 Lab ID:92548178001 Collected:07/07/21 11:30 Received:07/07/21 15:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Tetrachloroethene ND ug/L 07/09/21 18:22 127-18-41.0 1 Toluene ND ug/L 07/09/21 18:22 108-88-31.0 1 1,2,3-Trichlorobenzene ND ug/L 07/09/21 18:22 87-61-61.0 1 1,2,4-Trichlorobenzene ND ug/L 07/09/21 18:22 120-82-11.0 1 1,1,1-Trichloroethane ND ug/L 07/09/21 18:22 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 07/09/21 18:22 79-00-51.0 1 Trichloroethene ND ug/L 07/09/21 18:22 79-01-61.0 1 Trichlorofluoromethane ND ug/L 07/09/21 18:22 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 07/09/21 18:22 96-18-41.0 1 Vinyl acetate ND ug/L 07/09/21 18:22 108-05-42.0 1 Vinyl chloride ND ug/L 07/09/21 18:22 75-01-41.0 1 Xylene (Total)ND ug/L 07/09/21 18:22 1330-20-71.0 1 m&p-Xylene ND ug/L 07/09/21 18:22 179601-23-12.0 1 o-Xylene ND ug/L 07/09/21 18:22 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)99 %07/09/21 18:22 460-00-470-130 1 1,2-Dichloroethane-d4 (S)113 %07/09/21 18:22 17060-07-070-130 1 Toluene-d8 (S)105 %07/09/21 18:22 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/13/2021 12:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 26 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92548178 Phoenix Rising Sample:TW-2 Lab ID:92548178002 Collected:07/07/21 10:40 Received:07/07/21 15:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Acetone ND ug/L 07/08/21 18:58 67-64-125.0 1 Benzene ND ug/L 07/08/21 18:58 71-43-21.0 1 Bromobenzene ND ug/L 07/08/21 18:58 108-86-11.0 1 Bromochloromethane ND ug/L 07/08/21 18:58 74-97-51.0 1 Bromodichloromethane ND ug/L 07/08/21 18:58 75-27-41.0 1 Bromoform ND ug/L 07/08/21 18:58 75-25-2 IK1.0 1 Bromomethane ND ug/L 07/08/21 18:58 74-83-92.0 1 2-Butanone (MEK)ND ug/L 07/08/21 18:58 78-93-35.0 1 Carbon tetrachloride ND ug/L 07/08/21 18:58 56-23-51.0 1 Chlorobenzene ND ug/L 07/08/21 18:58 108-90-71.0 1 Chloroethane ND ug/L 07/08/21 18:58 75-00-3 IH,L11.0 1 Chloroform ND ug/L 07/08/21 18:58 67-66-31.0 1 Chloromethane ND ug/L 07/08/21 18:58 74-87-31.0 1 2-Chlorotoluene ND ug/L 07/08/21 18:58 95-49-81.0 1 4-Chlorotoluene ND ug/L 07/08/21 18:58 106-43-41.0 1 1,2-Dibromo-3-chloropropane ND ug/L 07/08/21 18:58 96-12-82.0 1 Dibromochloromethane ND ug/L 07/08/21 18:58 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 07/08/21 18:58 106-93-41.0 1 Dibromomethane ND ug/L 07/08/21 18:58 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 07/08/21 18:58 95-50-11.0 1 1,3-Dichlorobenzene ND ug/L 07/08/21 18:58 541-73-11.0 1 1,4-Dichlorobenzene ND ug/L 07/08/21 18:58 106-46-71.0 1 Dichlorodifluoromethane ND ug/L 07/08/21 18:58 75-71-81.0 1 1,1-Dichloroethane ND ug/L 07/08/21 18:58 75-34-31.0 1 1,2-Dichloroethane ND ug/L 07/08/21 18:58 107-06-21.0 1 1,1-Dichloroethene ND ug/L 07/08/21 18:58 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 07/08/21 18:58 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 07/08/21 18:58 156-60-51.0 1 1,2-Dichloropropane ND ug/L 07/08/21 18:58 78-87-51.0 1 1,3-Dichloropropane ND ug/L 07/08/21 18:58 142-28-91.0 1 2,2-Dichloropropane ND ug/L 07/08/21 18:58 594-20-71.0 1 1,1-Dichloropropene ND ug/L 07/08/21 18:58 563-58-61.0 1 cis-1,3-Dichloropropene ND ug/L 07/08/21 18:58 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 07/08/21 18:58 10061-02-61.0 1 Diisopropyl ether ND ug/L 07/08/21 18:58 108-20-31.0 1 Ethylbenzene ND ug/L 07/08/21 18:58 100-41-41.0 1 Hexachloro-1,3-butadiene ND ug/L 07/08/21 18:58 87-68-32.0 1 2-Hexanone ND ug/L 07/08/21 18:58 591-78-65.0 1 p-Isopropyltoluene ND ug/L 07/08/21 18:58 99-87-61.0 1 Methylene Chloride ND ug/L 07/08/21 18:58 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 07/08/21 18:58 108-10-15.0 1 Methyl-tert-butyl ether ND ug/L 07/08/21 18:58 1634-04-41.0 1 Naphthalene ND ug/L 07/08/21 18:58 91-20-31.0 1 Styrene ND ug/L 07/08/21 18:58 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 07/08/21 18:58 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 07/08/21 18:58 79-34-51.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/13/2021 12:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 26 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92548178 Phoenix Rising Sample:TW-2 Lab ID:92548178002 Collected:07/07/21 10:40 Received:07/07/21 15:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Tetrachloroethene ND ug/L 07/08/21 18:58 127-18-41.0 1 Toluene ND ug/L 07/08/21 18:58 108-88-31.0 1 1,2,3-Trichlorobenzene ND ug/L 07/08/21 18:58 87-61-61.0 1 1,2,4-Trichlorobenzene ND ug/L 07/08/21 18:58 120-82-11.0 1 1,1,1-Trichloroethane ND ug/L 07/08/21 18:58 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 07/08/21 18:58 79-00-51.0 1 Trichloroethene ND ug/L 07/08/21 18:58 79-01-61.0 1 Trichlorofluoromethane ND ug/L 07/08/21 18:58 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 07/08/21 18:58 96-18-41.0 1 Vinyl acetate ND ug/L 07/08/21 18:58 108-05-42.0 1 Vinyl chloride ND ug/L 07/08/21 18:58 75-01-41.0 1 Xylene (Total)ND ug/L 07/08/21 18:58 1330-20-71.0 1 m&p-Xylene ND ug/L 07/08/21 18:58 179601-23-12.0 1 o-Xylene ND ug/L 07/08/21 18:58 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)98 %07/08/21 18:58 460-00-470-130 1 1,2-Dichloroethane-d4 (S)97 %07/08/21 18:58 17060-07-070-130 1 Toluene-d8 (S)103 %07/08/21 18:58 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/13/2021 12:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 26 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92548178 Phoenix Rising Sample:TW-3 Lab ID:92548178003 Collected:07/07/21 12:00 Received:07/07/21 15:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Acetone ND ug/L 07/09/21 18:40 67-64-125.0 1 Benzene ND ug/L 07/09/21 18:40 71-43-21.0 1 Bromobenzene ND ug/L 07/09/21 18:40 108-86-11.0 1 Bromochloromethane ND ug/L 07/09/21 18:40 74-97-51.0 1 Bromodichloromethane ND ug/L 07/09/21 18:40 75-27-41.0 1 Bromoform ND ug/L 07/09/21 18:40 75-25-21.0 1 Bromomethane ND ug/L 07/09/21 18:40 74-83-92.0 1 2-Butanone (MEK)ND ug/L 07/09/21 18:40 78-93-35.0 1 Carbon tetrachloride ND ug/L 07/09/21 18:40 56-23-51.0 1 Chlorobenzene ND ug/L 07/09/21 18:40 108-90-71.0 1 Chloroethane ND ug/L 07/09/21 18:40 75-00-31.0 1 Chloroform ND ug/L 07/09/21 18:40 67-66-31.0 1 Chloromethane ND ug/L 07/09/21 18:40 74-87-31.0 1 2-Chlorotoluene ND ug/L 07/09/21 18:40 95-49-81.0 1 4-Chlorotoluene ND ug/L 07/09/21 18:40 106-43-41.0 1 1,2-Dibromo-3-chloropropane ND ug/L 07/09/21 18:40 96-12-82.0 1 Dibromochloromethane ND ug/L 07/09/21 18:40 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 07/09/21 18:40 106-93-41.0 1 Dibromomethane ND ug/L 07/09/21 18:40 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 07/09/21 18:40 95-50-11.0 1 1,3-Dichlorobenzene ND ug/L 07/09/21 18:40 541-73-11.0 1 1,4-Dichlorobenzene ND ug/L 07/09/21 18:40 106-46-71.0 1 Dichlorodifluoromethane ND ug/L 07/09/21 18:40 75-71-8 v11.0 1 1,1-Dichloroethane ND ug/L 07/09/21 18:40 75-34-31.0 1 1,2-Dichloroethane ND ug/L 07/09/21 18:40 107-06-21.0 1 1,1-Dichloroethene ND ug/L 07/09/21 18:40 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 07/09/21 18:40 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 07/09/21 18:40 156-60-51.0 1 1,2-Dichloropropane ND ug/L 07/09/21 18:40 78-87-51.0 1 1,3-Dichloropropane ND ug/L 07/09/21 18:40 142-28-91.0 1 2,2-Dichloropropane ND ug/L 07/09/21 18:40 594-20-71.0 1 1,1-Dichloropropene ND ug/L 07/09/21 18:40 563-58-61.0 1 cis-1,3-Dichloropropene ND ug/L 07/09/21 18:40 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 07/09/21 18:40 10061-02-61.0 1 Diisopropyl ether ND ug/L 07/09/21 18:40 108-20-31.0 1 Ethylbenzene ND ug/L 07/09/21 18:40 100-41-41.0 1 Hexachloro-1,3-butadiene ND ug/L 07/09/21 18:40 87-68-32.0 1 2-Hexanone ND ug/L 07/09/21 18:40 591-78-65.0 1 p-Isopropyltoluene ND ug/L 07/09/21 18:40 99-87-61.0 1 Methylene Chloride ND ug/L 07/09/21 18:40 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 07/09/21 18:40 108-10-15.0 1 Methyl-tert-butyl ether ND ug/L 07/09/21 18:40 1634-04-41.0 1 Naphthalene ND ug/L 07/09/21 18:40 91-20-31.0 1 Styrene ND ug/L 07/09/21 18:40 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 07/09/21 18:40 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 07/09/21 18:40 79-34-51.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/13/2021 12:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 26 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92548178 Phoenix Rising Sample:TW-3 Lab ID:92548178003 Collected:07/07/21 12:00 Received:07/07/21 15:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Tetrachloroethene ND ug/L 07/09/21 18:40 127-18-41.0 1 Toluene ND ug/L 07/09/21 18:40 108-88-31.0 1 1,2,3-Trichlorobenzene ND ug/L 07/09/21 18:40 87-61-61.0 1 1,2,4-Trichlorobenzene ND ug/L 07/09/21 18:40 120-82-11.0 1 1,1,1-Trichloroethane ND ug/L 07/09/21 18:40 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 07/09/21 18:40 79-00-51.0 1 Trichloroethene ND ug/L 07/09/21 18:40 79-01-61.0 1 Trichlorofluoromethane ND ug/L 07/09/21 18:40 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 07/09/21 18:40 96-18-41.0 1 Vinyl acetate ND ug/L 07/09/21 18:40 108-05-42.0 1 Vinyl chloride ND ug/L 07/09/21 18:40 75-01-41.0 1 Xylene (Total)ND ug/L 07/09/21 18:40 1330-20-71.0 1 m&p-Xylene ND ug/L 07/09/21 18:40 179601-23-12.0 1 o-Xylene ND ug/L 07/09/21 18:40 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)100 %07/09/21 18:40 460-00-470-130 1 1,2-Dichloroethane-d4 (S)110 %07/09/21 18:40 17060-07-070-130 1 Toluene-d8 (S)102 %07/09/21 18:40 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/13/2021 12:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 26 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92548178 Phoenix Rising Sample:TW-4 Lab ID:92548178004 Collected:07/07/21 13:10 Received:07/07/21 15:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Acetone ND ug/L 07/09/21 18:59 67-64-125.0 1 Benzene ND ug/L 07/09/21 18:59 71-43-21.0 1 Bromobenzene ND ug/L 07/09/21 18:59 108-86-11.0 1 Bromochloromethane ND ug/L 07/09/21 18:59 74-97-51.0 1 Bromodichloromethane ND ug/L 07/09/21 18:59 75-27-41.0 1 Bromoform ND ug/L 07/09/21 18:59 75-25-21.0 1 Bromomethane ND ug/L 07/09/21 18:59 74-83-92.0 1 2-Butanone (MEK)ND ug/L 07/09/21 18:59 78-93-35.0 1 Carbon tetrachloride ND ug/L 07/09/21 18:59 56-23-51.0 1 Chlorobenzene ND ug/L 07/09/21 18:59 108-90-71.0 1 Chloroethane ND ug/L 07/09/21 18:59 75-00-31.0 1 Chloroform ND ug/L 07/09/21 18:59 67-66-31.0 1 Chloromethane ND ug/L 07/09/21 18:59 74-87-31.0 1 2-Chlorotoluene ND ug/L 07/09/21 18:59 95-49-81.0 1 4-Chlorotoluene ND ug/L 07/09/21 18:59 106-43-41.0 1 1,2-Dibromo-3-chloropropane ND ug/L 07/09/21 18:59 96-12-82.0 1 Dibromochloromethane ND ug/L 07/09/21 18:59 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 07/09/21 18:59 106-93-41.0 1 Dibromomethane ND ug/L 07/09/21 18:59 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 07/09/21 18:59 95-50-11.0 1 1,3-Dichlorobenzene ND ug/L 07/09/21 18:59 541-73-11.0 1 1,4-Dichlorobenzene ND ug/L 07/09/21 18:59 106-46-71.0 1 Dichlorodifluoromethane ND ug/L 07/09/21 18:59 75-71-8 v11.0 1 1,1-Dichloroethane ND ug/L 07/09/21 18:59 75-34-31.0 1 1,2-Dichloroethane ND ug/L 07/09/21 18:59 107-06-21.0 1 1,1-Dichloroethene ND ug/L 07/09/21 18:59 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 07/09/21 18:59 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 07/09/21 18:59 156-60-51.0 1 1,2-Dichloropropane ND ug/L 07/09/21 18:59 78-87-51.0 1 1,3-Dichloropropane ND ug/L 07/09/21 18:59 142-28-91.0 1 2,2-Dichloropropane ND ug/L 07/09/21 18:59 594-20-71.0 1 1,1-Dichloropropene ND ug/L 07/09/21 18:59 563-58-61.0 1 cis-1,3-Dichloropropene ND ug/L 07/09/21 18:59 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 07/09/21 18:59 10061-02-61.0 1 Diisopropyl ether ND ug/L 07/09/21 18:59 108-20-31.0 1 Ethylbenzene ND ug/L 07/09/21 18:59 100-41-41.0 1 Hexachloro-1,3-butadiene ND ug/L 07/09/21 18:59 87-68-32.0 1 2-Hexanone ND ug/L 07/09/21 18:59 591-78-65.0 1 p-Isopropyltoluene ND ug/L 07/09/21 18:59 99-87-61.0 1 Methylene Chloride ND ug/L 07/09/21 18:59 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 07/09/21 18:59 108-10-15.0 1 Methyl-tert-butyl ether ND ug/L 07/09/21 18:59 1634-04-41.0 1 Naphthalene ND ug/L 07/09/21 18:59 91-20-31.0 1 Styrene ND ug/L 07/09/21 18:59 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 07/09/21 18:59 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 07/09/21 18:59 79-34-51.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/13/2021 12:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 26 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92548178 Phoenix Rising Sample:TW-4 Lab ID:92548178004 Collected:07/07/21 13:10 Received:07/07/21 15:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Tetrachloroethene ND ug/L 07/09/21 18:59 127-18-41.0 1 Toluene ND ug/L 07/09/21 18:59 108-88-31.0 1 1,2,3-Trichlorobenzene ND ug/L 07/09/21 18:59 87-61-61.0 1 1,2,4-Trichlorobenzene ND ug/L 07/09/21 18:59 120-82-11.0 1 1,1,1-Trichloroethane ND ug/L 07/09/21 18:59 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 07/09/21 18:59 79-00-51.0 1 Trichloroethene ND ug/L 07/09/21 18:59 79-01-61.0 1 Trichlorofluoromethane ND ug/L 07/09/21 18:59 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 07/09/21 18:59 96-18-41.0 1 Vinyl acetate ND ug/L 07/09/21 18:59 108-05-42.0 1 Vinyl chloride ND ug/L 07/09/21 18:59 75-01-41.0 1 Xylene (Total)ND ug/L 07/09/21 18:59 1330-20-71.0 1 m&p-Xylene ND ug/L 07/09/21 18:59 179601-23-12.0 1 o-Xylene ND ug/L 07/09/21 18:59 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)97 %07/09/21 18:59 460-00-470-130 1 1,2-Dichloroethane-d4 (S)108 %07/09/21 18:59 17060-07-070-130 1 Toluene-d8 (S)104 %07/09/21 18:59 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/13/2021 12:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 26 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92548178 Phoenix Rising Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 632081 EPA 8260D EPA 8260D 8260D MSV Low Level Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92548178002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3320255 Associated Lab Samples:92548178002 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 07/08/21 11:58 1,1,1-Trichloroethane ug/L ND 1.0 07/08/21 11:58 1,1,2,2-Tetrachloroethane ug/L ND 1.0 07/08/21 11:58 1,1,2-Trichloroethane ug/L ND 1.0 07/08/21 11:58 1,1-Dichloroethane ug/L ND 1.0 07/08/21 11:58 1,1-Dichloroethene ug/L ND 1.0 07/08/21 11:58 1,1-Dichloropropene ug/L ND 1.0 07/08/21 11:58 1,2,3-Trichlorobenzene ug/L ND 1.0 07/08/21 11:58 1,2,3-Trichloropropane ug/L ND 1.0 07/08/21 11:58 1,2,4-Trichlorobenzene ug/L ND 1.0 07/08/21 11:58 1,2-Dibromo-3-chloropropane ug/L ND 2.0 07/08/21 11:58 1,2-Dibromoethane (EDB)ug/L ND 1.0 07/08/21 11:58 1,2-Dichlorobenzene ug/L ND 1.0 07/08/21 11:58 1,2-Dichloroethane ug/L ND 1.0 07/08/21 11:58 1,2-Dichloropropane ug/L ND 1.0 07/08/21 11:58 1,3-Dichlorobenzene ug/L ND 1.0 07/08/21 11:58 1,3-Dichloropropane ug/L ND 1.0 07/08/21 11:58 1,4-Dichlorobenzene ug/L ND 1.0 07/08/21 11:58 2,2-Dichloropropane ug/L ND 1.0 07/08/21 11:58 2-Butanone (MEK)ug/L ND 5.0 07/08/21 11:58 2-Chlorotoluene ug/L ND 1.0 07/08/21 11:58 2-Hexanone ug/L ND 5.0 07/08/21 11:58 4-Chlorotoluene ug/L ND 1.0 07/08/21 11:58 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 07/08/21 11:58 Acetone ug/L ND 25.0 07/08/21 11:58 Benzene ug/L ND 1.0 07/08/21 11:58 Bromobenzene ug/L ND 1.0 07/08/21 11:58 Bromochloromethane ug/L ND 1.0 07/08/21 11:58 Bromodichloromethane ug/L ND 1.0 07/08/21 11:58 Bromoform ug/L ND 1.0 IK07/08/21 11:58 Bromomethane ug/L ND 2.0 07/08/21 11:58 Carbon tetrachloride ug/L ND 1.0 07/08/21 11:58 Chlorobenzene ug/L ND 1.0 07/08/21 11:58 Chloroethane ug/L ND 1.0 IH07/08/21 11:58 Chloroform ug/L ND 1.0 07/08/21 11:58 Chloromethane ug/L ND 1.0 07/08/21 11:58 cis-1,2-Dichloroethene ug/L ND 1.0 07/08/21 11:58 cis-1,3-Dichloropropene ug/L ND 1.0 07/08/21 11:58 Dibromochloromethane ug/L ND 1.0 07/08/21 11:58 Dibromomethane ug/L ND 1.0 07/08/21 11:58 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/13/2021 12:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 26 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92548178 Phoenix Rising Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3320255 Associated Lab Samples:92548178002 Matrix:Water Analyzed Dichlorodifluoromethane ug/L ND 1.0 07/08/21 11:58 Diisopropyl ether ug/L ND 1.0 07/08/21 11:58 Ethylbenzene ug/L ND 1.0 07/08/21 11:58 Hexachloro-1,3-butadiene ug/L ND 2.0 07/08/21 11:58 m&p-Xylene ug/L ND 2.0 07/08/21 11:58 Methyl-tert-butyl ether ug/L ND 1.0 07/08/21 11:58 Methylene Chloride ug/L ND 5.0 07/08/21 11:58 Naphthalene ug/L ND 1.0 07/08/21 11:58 o-Xylene ug/L ND 1.0 07/08/21 11:58 p-Isopropyltoluene ug/L ND 1.0 07/08/21 11:58 Styrene ug/L ND 1.0 07/08/21 11:58 Tetrachloroethene ug/L ND 1.0 07/08/21 11:58 Toluene ug/L ND 1.0 07/08/21 11:58 trans-1,2-Dichloroethene ug/L ND 1.0 07/08/21 11:58 trans-1,3-Dichloropropene ug/L ND 1.0 07/08/21 11:58 Trichloroethene ug/L ND 1.0 07/08/21 11:58 Trichlorofluoromethane ug/L ND 1.0 07/08/21 11:58 Vinyl acetate ug/L ND 2.0 07/08/21 11:58 Vinyl chloride ug/L ND 1.0 07/08/21 11:58 Xylene (Total)ug/L ND 1.0 07/08/21 11:58 1,2-Dichloroethane-d4 (S)%104 70-130 07/08/21 11:58 4-Bromofluorobenzene (S)%100 70-130 07/08/21 11:58 Toluene-d8 (S)%106 70-130 07/08/21 11:58 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3320256LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 56.950 114 70-130 1,1,1-Trichloroethane ug/L 55.650 111 70-130 1,1,2,2-Tetrachloroethane ug/L 53.350 107 70-130 1,1,2-Trichloroethane ug/L 54.950 110 70-130 1,1-Dichloroethane ug/L 57.550 115 70-130 1,1-Dichloroethene ug/L 53.850 108 70-132 1,1-Dichloropropene ug/L 57.250 114 70-131 1,2,3-Trichlorobenzene ug/L 56.250 112 70-134 1,2,3-Trichloropropane ug/L 52.350 105 70-130 1,2,4-Trichlorobenzene ug/L 57.250 114 70-130 1,2-Dibromo-3-chloropropane ug/L 54.450 109 70-132 1,2-Dibromoethane (EDB)ug/L 54.050 108 70-130 1,2-Dichlorobenzene ug/L 56.950 114 70-130 1,2-Dichloroethane ug/L 53.250 106 70-130 1,2-Dichloropropane ug/L 54.350 109 70-130 1,3-Dichlorobenzene ug/L 56.350 113 70-130 1,3-Dichloropropane ug/L 55.050 110 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/13/2021 12:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 26 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92548178 Phoenix Rising Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3320256LABORATORY CONTROL SAMPLE: LCSSpike 1,4-Dichlorobenzene ug/L 55.950 112 70-130 2,2-Dichloropropane ug/L 60.850 122 70-130 2-Butanone (MEK)ug/L 111100 111 70-133 2-Chlorotoluene ug/L 54.850 110 70-130 2-Hexanone ug/L 103100 103 70-130 4-Chlorotoluene ug/L 54.950 110 70-130 4-Methyl-2-pentanone (MIBK)ug/L 105100 105 70-130 Acetone ug/L 104100 104 70-144 Benzene ug/L 56.350 113 70-130 Bromobenzene ug/L 53.450 107 70-130 Bromochloromethane ug/L 55.050 110 70-130 Bromodichloromethane ug/L 54.850 110 70-130 Bromoform ug/L 49.3 IK509970-131 Bromomethane ug/L 63.150 126 30-177 Carbon tetrachloride ug/L 56.350 113 70-130 Chlorobenzene ug/L 54.150 108 70-130 Chloroethane ug/L 77.4 IH,L15015546-131 Chloroform ug/L 58.750 117 70-130 Chloromethane ug/L 49.650 99 49-130 cis-1,2-Dichloroethene ug/L 54.650 109 70-130 cis-1,3-Dichloropropene ug/L 56.850 114 70-130 Dibromochloromethane ug/L 57.450 115 70-130 Dibromomethane ug/L 53.650 107 70-130 Dichlorodifluoromethane ug/L 53.350 107 52-134 Diisopropyl ether ug/L 54.950 110 70-131 Ethylbenzene ug/L 54.950 110 70-130 Hexachloro-1,3-butadiene ug/L 56.750 113 70-131 m&p-Xylene ug/L 112100 112 70-130 Methyl-tert-butyl ether ug/L 57.750 115 70-130 Methylene Chloride ug/L 53.950 108 68-130 Naphthalene ug/L 56.050 112 70-133 o-Xylene ug/L 56.150 112 70-130 p-Isopropyltoluene ug/L 63.550 127 70-130 Styrene ug/L 57.550 115 70-130 Tetrachloroethene ug/L 54.950 110 70-130 Toluene ug/L 53.450 107 70-130 trans-1,2-Dichloroethene ug/L 54.750 109 70-130 trans-1,3-Dichloropropene ug/L 56.050 112 70-130 Trichloroethene ug/L 55.850 112 70-130 Trichlorofluoromethane ug/L 51.350 103 61-130 Vinyl acetate ug/L 129100 129 70-140 Vinyl chloride ug/L 54.350 109 59-142 Xylene (Total)ug/L 168150 112 70-130 1,2-Dichloroethane-d4 (S)%91 70-130 4-Bromofluorobenzene (S)%101 70-130 Toluene-d8 (S)%95 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/13/2021 12:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 26 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92548178 Phoenix Rising Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 3320257MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92547915007 3320258 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 2000 119 70-135122 22000ND23902440 1,1,1-Trichloroethane ug/L 2000 124 70-148122 12000ND24802450 1,1,2,2-Tetrachloroethane ug/L 2000 109 70-131111 12000ND21802210 1,1,2-Trichloroethane ug/L 2000 123 70-136119 32000ND24602380 1,1-Dichloroethane ug/L 2000 131 70-147130 12000ND26202610 1,1-Dichloroethene ug/L 2000 132 70-158143 92000ND26302870 1,1-Dichloropropene ug/L 2000 129 70-149131 12000ND25902620 1,2,3-Trichlorobenzene ug/L 2000 104 68-140123 162000ND20902460 1,2,3-Trichloropropane ug/L 2000 113 67-137113 02000ND22602250 1,2,4-Trichlorobenzene ug/L 2000 107 70-139119 112000ND21302380 1,2-Dibromo-3-chloropropane ug/L 2000 111 69-136118 62000ND22202370 1,2-Dibromoethane (EDB)ug/L 2000 113 70-137116 32000ND22602320 1,2-Dichlorobenzene ug/L 2000 118 70-133122 42000ND23502450 1,2-Dichloroethane ug/L 2000 117 67-138113 42000ND23402260 1,2-Dichloropropane ug/L 2000 128 70-138124 32000ND25602490 1,3-Dichlorobenzene ug/L 2000 112 70-133118 52000ND22402350 1,3-Dichloropropane ug/L 2000 116 70-136116 02000ND23302320 1,4-Dichlorobenzene ug/L 2000 106 70-133113 72000ND21102270 2,2-Dichloropropane ug/L 2000 121 52-155117 42000ND24202330 2-Butanone (MEK)ug/L 4000 124 61-147126 24000ND49505030 2-Chlorotoluene ug/L 2000 108 70-141117 82000ND21602340 2-Hexanone ug/L 4000 112 67-139109 34000ND44604350 4-Chlorotoluene ug/L 2000 107 70-135112 42000ND21502230 4-Methyl-2-pentanone (MIBK)ug/L 4000 121 67-136116 44000ND48204630 Acetone ug/L 4000 128 55-159131 34000ND51105240 Benzene ug/L 2000 121 67-150123 12000ND24602490 Bromobenzene ug/L 2000 110 70-134119 72000ND22002370 Bromochloromethane ug/L 2000 124 70-146119 42000ND24702370 Bromodichloromethane ug/L 2000 123 70-138123 02000ND24602460 Bromoform ug/L IK200010157-138104 32000ND20202080 Bromomethane ug/L 2000 95 10-20098 32000ND19001960 Carbon tetrachloride ug/L 2000 129 70-147133 32000ND25802650 Chlorobenzene ug/L 2000 116 70-137117 12000ND23202330 Chloroethane ug/L IH200013151-166140 62000ND26302800 Chloroform ug/L 2000 132 70-144135 22000ND27002760 Chloromethane ug/L 2000 132 24-161130 12000ND26302600 cis-1,2-Dichloroethene ug/L 2000 126 67-148127 12000ND25202540 cis-1,3-Dichloropropene ug/L 2000 121 70-142121 02000ND24202420 Dibromochloromethane ug/L 2000 122 68-138118 32000ND24402350 Dibromomethane ug/L 2000 130 70-134127 22000ND26002540 Dichlorodifluoromethane ug/L 2000 106 43-155109 32000ND21202180 Diisopropyl ether ug/L 2000 130 65-146130 02000ND26102600 Ethylbenzene ug/L 2000 116 68-143115 12000256048904860 Hexachloro-1,3-butadiene ug/L 2000 106 62-151119 122000ND21102380 m&p-Xylene ug/L 4000 104 53-157113 3400092801350013800 Methyl-tert-butyl ether ug/L 2000 131 59-156122 72000ND26102450 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/13/2021 12:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 26 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92548178 Phoenix Rising Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 3320257MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92547915007 3320258 MSD Result MSD % Rec RPD MSDMS Spike Conc. Methylene Chloride ug/L 2000 133 64-148130 22000ND26702610 Naphthalene ug/L 2000 98 57-150116 13200083627903160 o-Xylene ug/L 2000 112 68-143116 12000414063906460 p-Isopropyltoluene ug/L 2000 117 70-141127 92000ND23402550 Styrene ug/L 2000 116 70-136121 42000ND24002500 Tetrachloroethene ug/L 2000 119 70-139124 42000ND23902490 Toluene ug/L 2000 86 47-15776 12000134001510014900 trans-1,2-Dichloroethene ug/L 2000 129 70-149125 42000ND25802490 trans-1,3-Dichloropropene ug/L 2000 118 70-138117 12000ND23602350 Trichloroethene ug/L 2000 123 70-149127 32000ND24602540 Trichlorofluoromethane ug/L 2000 127 61-154120 62000ND25402390 Vinyl acetate ug/L 4000 136 48-156136 04000ND54305420 Vinyl chloride ug/L 2000 127 55-172127 02000ND25302540 Xylene (Total)ug/L 6000 107 66-145114 26000134001980020300 1,2-Dichloroethane-d4 (S)%95 70-13094 4-Bromofluorobenzene (S)%97 70-13097 Toluene-d8 (S)%98 70-13098 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/13/2021 12:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 26 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92548178 Phoenix Rising Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 632411 EPA 8260D EPA 8260D 8260D MSV Low Level Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92548178001, 92548178003, 92548178004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3322039 Associated Lab Samples:92548178001, 92548178003, 92548178004 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 07/09/21 14:24 1,1,1-Trichloroethane ug/L ND 1.0 07/09/21 14:24 1,1,2,2-Tetrachloroethane ug/L ND 1.0 07/09/21 14:24 1,1,2-Trichloroethane ug/L ND 1.0 07/09/21 14:24 1,1-Dichloroethane ug/L ND 1.0 07/09/21 14:24 1,1-Dichloroethene ug/L ND 1.0 07/09/21 14:24 1,1-Dichloropropene ug/L ND 1.0 07/09/21 14:24 1,2,3-Trichlorobenzene ug/L ND 1.0 07/09/21 14:24 1,2,3-Trichloropropane ug/L ND 1.0 07/09/21 14:24 1,2,4-Trichlorobenzene ug/L ND 1.0 07/09/21 14:24 1,2-Dibromo-3-chloropropane ug/L ND 2.0 07/09/21 14:24 1,2-Dibromoethane (EDB)ug/L ND 1.0 07/09/21 14:24 1,2-Dichlorobenzene ug/L ND 1.0 07/09/21 14:24 1,2-Dichloroethane ug/L ND 1.0 07/09/21 14:24 1,2-Dichloropropane ug/L ND 1.0 07/09/21 14:24 1,3-Dichlorobenzene ug/L ND 1.0 07/09/21 14:24 1,3-Dichloropropane ug/L ND 1.0 07/09/21 14:24 1,4-Dichlorobenzene ug/L ND 1.0 07/09/21 14:24 2,2-Dichloropropane ug/L ND 1.0 07/09/21 14:24 2-Butanone (MEK)ug/L ND 5.0 07/09/21 14:24 2-Chlorotoluene ug/L ND 1.0 07/09/21 14:24 2-Hexanone ug/L ND 5.0 07/09/21 14:24 4-Chlorotoluene ug/L ND 1.0 07/09/21 14:24 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 07/09/21 14:24 Acetone ug/L ND 25.0 07/09/21 14:24 Benzene ug/L ND 1.0 07/09/21 14:24 Bromobenzene ug/L ND 1.0 07/09/21 14:24 Bromochloromethane ug/L ND 1.0 07/09/21 14:24 Bromodichloromethane ug/L ND 1.0 07/09/21 14:24 Bromoform ug/L ND 1.0 07/09/21 14:24 Bromomethane ug/L ND 2.0 07/09/21 14:24 Carbon tetrachloride ug/L ND 1.0 07/09/21 14:24 Chlorobenzene ug/L ND 1.0 07/09/21 14:24 Chloroethane ug/L ND 1.0 07/09/21 14:24 Chloroform ug/L ND 1.0 07/09/21 14:24 Chloromethane ug/L ND 1.0 07/09/21 14:24 cis-1,2-Dichloroethene ug/L ND 1.0 07/09/21 14:24 cis-1,3-Dichloropropene ug/L ND 1.0 07/09/21 14:24 Dibromochloromethane ug/L ND 1.0 07/09/21 14:24 Dibromomethane ug/L ND 1.0 07/09/21 14:24 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/13/2021 12:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 26 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92548178 Phoenix Rising Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3322039 Associated Lab Samples:92548178001, 92548178003, 92548178004 Matrix:Water Analyzed Dichlorodifluoromethane ug/L ND 1.0 v107/09/21 14:24 Diisopropyl ether ug/L ND 1.0 07/09/21 14:24 Ethylbenzene ug/L ND 1.0 07/09/21 14:24 Hexachloro-1,3-butadiene ug/L ND 2.0 07/09/21 14:24 m&p-Xylene ug/L ND 2.0 07/09/21 14:24 Methyl-tert-butyl ether ug/L ND 1.0 07/09/21 14:24 Methylene Chloride ug/L ND 5.0 07/09/21 14:24 Naphthalene ug/L ND 1.0 07/09/21 14:24 o-Xylene ug/L ND 1.0 07/09/21 14:24 p-Isopropyltoluene ug/L ND 1.0 07/09/21 14:24 Styrene ug/L ND 1.0 07/09/21 14:24 Tetrachloroethene ug/L ND 1.0 07/09/21 14:24 Toluene ug/L ND 1.0 07/09/21 14:24 trans-1,2-Dichloroethene ug/L ND 1.0 07/09/21 14:24 trans-1,3-Dichloropropene ug/L ND 1.0 07/09/21 14:24 Trichloroethene ug/L ND 1.0 07/09/21 14:24 Trichlorofluoromethane ug/L ND 1.0 07/09/21 14:24 Vinyl acetate ug/L ND 2.0 07/09/21 14:24 Vinyl chloride ug/L ND 1.0 07/09/21 14:24 Xylene (Total)ug/L ND 1.0 07/09/21 14:24 1,2-Dichloroethane-d4 (S)%101 70-130 07/09/21 14:24 4-Bromofluorobenzene (S)%101 70-130 07/09/21 14:24 Toluene-d8 (S)%102 70-130 07/09/21 14:24 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3322040LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 53.350 107 70-130 1,1,1-Trichloroethane ug/L 50.650 101 70-130 1,1,2,2-Tetrachloroethane ug/L 54.150 108 70-130 1,1,2-Trichloroethane ug/L 53.850 108 70-130 1,1-Dichloroethane ug/L 49.350 99 70-130 1,1-Dichloroethene ug/L 51.550 103 70-132 1,1-Dichloropropene ug/L 47.550 95 70-131 1,2,3-Trichlorobenzene ug/L 55.050 110 70-134 1,2,3-Trichloropropane ug/L 52.250 104 70-130 1,2,4-Trichlorobenzene ug/L 54.050 108 70-130 1,2-Dibromo-3-chloropropane ug/L 54.450 109 70-132 1,2-Dibromoethane (EDB)ug/L 52.950 106 70-130 1,2-Dichlorobenzene ug/L 52.550 105 70-130 1,2-Dichloroethane ug/L 47.550 95 70-130 1,2-Dichloropropane ug/L 52.950 106 70-130 1,3-Dichlorobenzene ug/L 52.850 106 70-130 1,3-Dichloropropane ug/L 51.650 103 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/13/2021 12:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 26 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92548178 Phoenix Rising Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3322040LABORATORY CONTROL SAMPLE: LCSSpike 1,4-Dichlorobenzene ug/L 52.750 105 70-130 2,2-Dichloropropane ug/L 53.450 107 70-130 2-Butanone (MEK)ug/L 111100 111 70-133 2-Chlorotoluene ug/L 50.750 101 70-130 2-Hexanone ug/L 116100 116 70-130 4-Chlorotoluene ug/L 49.350 99 70-130 4-Methyl-2-pentanone (MIBK)ug/L 112100 112 70-130 Acetone ug/L 119100 119 70-144 Benzene ug/L 51.450 103 70-130 Bromobenzene ug/L 51.150 102 70-130 Bromochloromethane ug/L 50.350 101 70-130 Bromodichloromethane ug/L 52.550 105 70-130 Bromoform ug/L 55.550 111 70-131 Bromomethane ug/L 45.650 91 30-177 Carbon tetrachloride ug/L 52.950 106 70-130 Chlorobenzene ug/L 51.050 102 70-130 Chloroethane ug/L 51.250 102 46-131 Chloroform ug/L 48.450 97 70-130 Chloromethane ug/L 49.850 100 49-130 cis-1,2-Dichloroethene ug/L 49.950 100 70-130 cis-1,3-Dichloropropene ug/L 52.450 105 70-130 Dibromochloromethane ug/L 54.850 110 70-130 Dibromomethane ug/L 54.250 108 70-130 Dichlorodifluoromethane ug/L 61.5 v15012352-134 Diisopropyl ether ug/L 49.250 98 70-131 Ethylbenzene ug/L 50.950 102 70-130 Hexachloro-1,3-butadiene ug/L 52.950 106 70-131 m&p-Xylene ug/L 103100 103 70-130 Methyl-tert-butyl ether ug/L 50.350 101 70-130 Methylene Chloride ug/L 49.850 100 68-130 Naphthalene ug/L 55.750 111 70-133 o-Xylene ug/L 51.450 103 70-130 p-Isopropyltoluene ug/L 52.050 104 70-130 Styrene ug/L 54.150 108 70-130 Tetrachloroethene ug/L 50.150 100 70-130 Toluene ug/L 51.450 103 70-130 trans-1,2-Dichloroethene ug/L 50.350 101 70-130 trans-1,3-Dichloropropene ug/L 54.450 109 70-130 Trichloroethene ug/L 50.450 101 70-130 Trichlorofluoromethane ug/L 57.750 115 61-130 Vinyl acetate ug/L 114100 114 70-140 Vinyl chloride ug/L 51.650 103 59-142 Xylene (Total)ug/L 154150 103 70-130 1,2-Dichloroethane-d4 (S)%95 70-130 4-Bromofluorobenzene (S)%101 70-130 Toluene-d8 (S)%98 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/13/2021 12:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 26 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92548178 Phoenix Rising Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 3322041MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92548198012 3322042 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 8000 114 70-135117 38000ND90809380 1,1,1-Trichloroethane ug/L 8000 123 70-148125 28000ND98109980 1,1,2,2-Tetrachloroethane ug/L 8000 112 70-131113 18000ND89809050 1,1,2-Trichloroethane ug/L 8000 110 70-136116 58000ND88209260 1,1-Dichloroethane ug/L 8000 119 70-147118 18000ND95309410 1,1-Dichloroethene ug/L 8000 122 70-158123 18000ND97509810 1,1-Dichloropropene ug/L 8000 113 70-149116 28000ND90509270 1,2,3-Trichlorobenzene ug/L 8000 102 68-140109 68000ND81608690 1,2,3-Trichloropropane ug/L 8000 105 67-137106 18000ND83908460 1,2,4-Trichlorobenzene ug/L 8000 101 70-139109 88000ND80908730 1,2-Dibromo-3-chloropropane ug/L 8000 99 69-136108 98000ND79008670 1,2-Dibromoethane (EDB)ug/L 8000 111 70-137114 38000ND88709100 1,2-Dichlorobenzene ug/L 8000 108 70-133110 28000ND86008810 1,2-Dichloroethane ug/L 8000 114 67-138115 18000ND90809190 1,2-Dichloropropane ug/L 8000 117 70-138119 18000ND94009530 1,3-Dichlorobenzene ug/L 8000 107 70-133112 48000ND85708960 1,3-Dichloropropane ug/L 8000 110 70-136110 08000ND88108820 1,4-Dichlorobenzene ug/L 8000 108 70-133109 18000ND86708730 2,2-Dichloropropane ug/L 8000 100 52-155108 88000ND80008660 2-Butanone (MEK)ug/L 16000 104 61-147111 616000ND1670017700 2-Chlorotoluene ug/L 8000 112 70-141113 28000ND89309080 2-Hexanone ug/L 16000 107 67-139111 416000ND1710017800 4-Chlorotoluene ug/L 8000 105 70-135106 18000ND83908500 4-Methyl-2-pentanone (MIBK)ug/L 16000 106 67-136110 416000ND1690017600 Acetone ug/L 16000 112 55-159116 416000ND1790018600 Benzene ug/L 8000 117 67-150113 38000ND93509050 Bromobenzene ug/L 8000 110 70-134112 28000ND87608970 Bromochloromethane ug/L 8000 111 70-146123 108000ND88809810 Bromodichloromethane ug/L 8000 113 70-138118 48000ND90709400 Bromoform ug/L 8000 106 57-138107 18000ND84408550 Bromomethane ug/L 8000 110 10-200110 08000ND88308830 Carbon tetrachloride ug/L 8000 118 70-147120 28000ND94309620 Chlorobenzene ug/L 8000 113 70-137114 18000ND90409090 Chloroethane ug/L 8000 148 51-166153 48000ND1180012300 Chloroform ug/L 8000 120 70-144126 58000ND957010100 Chloromethane ug/L 8000 100 24-161103 38000ND80308250 cis-1,2-Dichloroethene ug/L 8000 115 67-148116 1800032201240012500 cis-1,3-Dichloropropene ug/L 8000 107 70-142110 28000ND85808780 Dibromochloromethane ug/L 8000 113 68-138115 28000ND90709220 Dibromomethane ug/L 8000 111 70-134113 18000ND88909020 Dichlorodifluoromethane ug/L v1800010443-155109 58000ND82908700 Diisopropyl ether ug/L 8000 106 65-146111 58000ND84508840 Ethylbenzene ug/L 8000 114 68-143113 18000ND91509040 Hexachloro-1,3-butadiene ug/L 8000 105 62-151110 58000ND84308830 m&p-Xylene ug/L 16000 113 53-157112 116000ND1800017900 Methyl-tert-butyl ether ug/L 8000 103 59-156113 108000ND82409080 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/13/2021 12:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 26 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92548178 Phoenix Rising Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 3322041MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92548198012 3322042 MSD Result MSD % Rec RPD MSDMS Spike Conc. Methylene Chloride ug/L 8000 115 64-148112 38000ND98909640 Naphthalene ug/L 8000 102 57-150110 78000ND81508760 o-Xylene ug/L 8000 111 68-143114 38000ND88909150 p-Isopropyltoluene ug/L 8000 107 70-141110 38000ND85308830 Styrene ug/L 8000 113 70-136115 28000ND90409190 Tetrachloroethene ug/L 8000 109 70-139110 18000ND87408810 Toluene ug/L 8000 115 47-157114 08000ND91609130 trans-1,2-Dichloroethene ug/L 8000 118 70-149122 38000ND94409730 trans-1,3-Dichloropropene ug/L 8000 107 70-138110 38000ND85308780 Trichloroethene ug/L 8000 136 70-149116 38000366004750045900 Trichlorofluoromethane ug/L 8000 125 61-154129 48000ND999010300 Vinyl acetate ug/L 16000 118 48-156124 516000ND1880019800 Vinyl chloride ug/L 8000 112 55-172118 58000ND89909420 Xylene (Total)ug/L 24000 112 66-145113 024000ND2690027100 1,2-Dichloroethane-d4 (S)%104 70-130100 4-Bromofluorobenzene (S)%100 70-130100 Toluene-d8 (S)%100 70-13099 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/13/2021 12:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 26 #=QL# QUALIFIERS Pace Project No.: Project: 92548178 Phoenix Rising DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value.IH The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value.IK Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high.L1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias.v1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/13/2021 12:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 26 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92548178 Phoenix Rising Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92548178001 632411TW-1 EPA 8260D 92548178002 632081TW-2 EPA 8260D 92548178003 632411TW-3 EPA 8260D 92548178004 632411TW-4 EPA 8260D REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/13/2021 12:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 26 Page 24 of 26 Page 25 of 26 Page 26 of 26 #=CL# July 14, 2021 LIMS USE: FR - MATT MILLER LIMS OBJECT ID: 92548079 92548079 Project: Pace Project No.: RE: Mr. Matt Miller WOOD E&I 2801 Yorkmont Road Charlotte, NC 28208 PHOENIX RISING Dear Mr. Miller: Enclosed are the analytical results for sample(s) received by the laboratory on July 07, 2021. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Minneapolis If you have any questions concerning this report, please feel free to contact me. Sincerely, Ryan Brumfield ryan.brumfield@pacelabs.com Project Manager (770)734-4200 Enclosures cc:Mr. Andrew Frantz, WOOD E&I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 20 #=CP# CERTIFICATIONS Pace Project No.: Project: 92548079 PHOENIX RISING Pace Analytical Services, LLC - Minneapolis MN 1700 Elm Street SE, Minneapolis, MN 55414 1800 Elm Street SE, Minneapolis, MN 55414--Satellite Air Lab A2LA Certification #: 2926.01* Alabama Certification #: 40770 Alaska Contaminated Sites Certification #: 17-009* Alaska DW Certification #: MN00064 Arizona Certification #: AZ0014* Arkansas DW Certification #: MN00064 Arkansas WW Certification #: 88-0680 California Certification #: 2929 Colorado Certification #: MN00064 Connecticut Certification #: PH-0256 EPA Region 8 Tribal Water Systems+Wyoming DW Certification #: via MN 027-053-137 Florida Certification #: E87605* Georgia Certification #: 959 Hawaii Certification #: MN00064 Idaho Certification #: MN00064 Illinois Certification #: 200011 Indiana Certification #: C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky DW Certification #: 90062 Kentucky WW Certification #: 90062 Louisiana DEQ Certification #: AI-03086* Louisiana DW Certification #: MN00064 Maine Certification #: MN00064* Maryland Certification #: 322 Michigan Certification #: 9909 Minnesota Certification #: 027-053-137* Minnesota Dept of Ag Approval: via MN 027-053-137 Minnesota Petrofund Registration #: 1240* Mississippi Certification #: MN00064 Missouri Certification #: 10100 Montana Certification #: CERT0092 Nebraska Certification #: NE-OS-18-06 Nevada Certification #: MN00064 New Hampshire Certification #: 2081* New Jersey Certification #: MN002 New York Certification #: 11647* North Carolina DW Certification #: 27700 North Carolina WW Certification #: 530 North Dakota Certification #: R-036 Ohio DW Certification #: 41244 Ohio VAP Certification (1700) #: CL101 Ohio VAP Certification (1800) #: CL110* Oklahoma Certification #: 9507* Oregon Primary Certification #: MN300001 Oregon Secondary Certification #: MN200001* Pennsylvania Certification #: 68-00563* Puerto Rico Certification #: MN00064 South Carolina Certification #:74003001 Tennessee Certification #: TN02818 Texas Certification #: T104704192* Utah Certification #: MN00064* Vermont Certification #: VT-027053137 Virginia Certification #: 460163* Washington Certification #: C486* West Virginia DEP Certification #: 382 West Virginia DW Certification #: 9952 C Wisconsin Certification #: 999407970 Wyoming UST Certification #: via A2LA 2926.01 USDA Permit #: P330-19-00208 *Please Note: Applicable air certifications are denoted with an asterisk (*). REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 20 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92548079 PHOENIX RISING Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92548079001 SG-1 TO-15 61 PASI-MMJL 92548079002 SG-2 TO-15 61 PASI-MMJL 92548079003 SG-3 TO-15 61 PASI-MMJL 92548079004 SG-4 TO-15 61 PASI-MMJL PASI-M = Pace Analytical Services - Minneapolis REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 20 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92548079 PHOENIX RISING Sample:SG-1 Lab ID:92548079001 Collected:07/06/21 14:36 Received:07/07/21 15:15 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: TO-15 Pace Analytical Services - Minneapolis TO15 MSV AIR Acetone 49.8 ug/m3 07/12/21 23:01 67-64-111.3 1.87 Benzene 43.4 ug/m3 07/12/21 23:01 71-43-23.0 1.87 Benzyl chloride ND ug/m3 07/12/21 23:01 100-44-74.9 1.87 Bromodichloromethane ND ug/m3 07/12/21 23:01 75-27-42.5 1.87 Bromoform ND ug/m3 07/12/21 23:01 75-25-29.8 1.87 Bromomethane ND ug/m3 07/12/21 23:01 74-83-91.5 1.87 1,3-Butadiene ND ug/m3 07/12/21 23:01 106-99-00.84 1.87 2-Butanone (MEK)16.8 ug/m3 07/12/21 23:01 78-93-35.6 1.87 Carbon disulfide 117 ug/m3 07/12/21 23:01 75-15-01.2 1.87 Carbon tetrachloride ND ug/m3 07/12/21 23:01 56-23-52.4 1.87 Chlorobenzene ND ug/m3 07/12/21 23:01 108-90-71.8 1.87 Chloroethane ND ug/m3 07/12/21 23:01 75-00-31.0 1.87 Chloroform ND ug/m3 07/12/21 23:01 67-66-34.6 1.87 Chloromethane 3.2 ug/m3 07/12/21 23:01 74-87-30.79 1.87 Cyclohexane ND ug/m3 07/12/21 23:01 110-82-73.3 1.87 Dibromochloromethane ND ug/m3 07/12/21 23:01 124-48-13.2 1.87 1,2-Dibromoethane (EDB)ND ug/m3 07/12/21 23:01 106-93-41.5 1.87 1,2-Dichlorobenzene ND ug/m3 07/12/21 23:01 95-50-15.7 1.87 1,3-Dichlorobenzene ND ug/m3 07/12/21 23:01 541-73-15.7 1.87 1,4-Dichlorobenzene ND ug/m3 07/12/21 23:01 106-46-75.7 1.87 Dichlorodifluoromethane 2.8 ug/m3 07/12/21 23:01 75-71-81.9 1.87 1,1-Dichloroethane ND ug/m3 07/12/21 23:01 75-34-31.5 1.87 1,2-Dichloroethane ND ug/m3 07/12/21 23:01 107-06-21.5 1.87 1,1-Dichloroethene ND ug/m3 07/12/21 23:01 75-35-41.5 1.87 cis-1,2-Dichloroethene ND ug/m3 07/12/21 23:01 156-59-21.5 1.87 trans-1,2-Dichloroethene ND ug/m3 07/12/21 23:01 156-60-51.5 1.87 1,2-Dichloropropane 4.5 ug/m3 07/12/21 23:01 78-87-51.8 1.87 cis-1,3-Dichloropropene ND ug/m3 07/12/21 23:01 10061-01-54.3 1.87 trans-1,3-Dichloropropene ND ug/m3 07/12/21 23:01 10061-02-64.3 1.87 Dichlorotetrafluoroethane ND ug/m3 07/12/21 23:01 76-14-22.7 1.87 Ethanol 29.3 ug/m3 07/12/21 23:01 64-17-53.6 1.87 Ethyl acetate ND ug/m3 07/12/21 23:01 141-78-61.4 1.87 Ethylbenzene 16.4 ug/m3 07/12/21 23:01 100-41-41.7 1.87 4-Ethyltoluene 8.6 ug/m3 07/12/21 23:01 622-96-84.7 1.87 n-Heptane 14.8 ug/m3 07/12/21 23:01 142-82-51.6 1.87 Hexachloro-1,3-butadiene ND ug/m3 07/12/21 23:01 87-68-310.1 1.87 n-Hexane 58.2 ug/m3 07/12/21 23:01 110-54-31.3 1.87 2-Hexanone 27.1 ug/m3 07/12/21 23:01 591-78-67.8 1.87 Methylene Chloride ND ug/m3 07/12/21 23:01 75-09-26.6 1.87 4-Methyl-2-pentanone (MIBK)101 ug/m3 07/12/21 23:01 108-10-17.8 1.87 Methyl-tert-butyl ether ND ug/m3 07/12/21 23:01 1634-04-46.8 1.87 Naphthalene 7.0 ug/m3 07/12/21 23:01 91-20-35.0 1.87 2-Propanol 7.6 ug/m3 07/12/21 23:01 67-63-04.7 1.87 Propylene 88.4 ug/m3 07/12/21 23:01 115-07-11.6 1.87 Styrene 2.0 ug/m3 07/12/21 23:01 100-42-51.6 1.87 1,1,2,2-Tetrachloroethane ND ug/m3 07/12/21 23:01 79-34-52.6 1.87 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/14/2021 06:17 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 20 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92548079 PHOENIX RISING Sample:SG-1 Lab ID:92548079001 Collected:07/06/21 14:36 Received:07/07/21 15:15 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: TO-15 Pace Analytical Services - Minneapolis TO15 MSV AIR Tetrachloroethene 14.8 ug/m3 07/12/21 23:01 127-18-4 C81.3 1.87 Tetrahydrofuran ND ug/m3 07/12/21 23:01 109-99-91.1 1.87 Toluene 1510 ug/m3 07/14/21 01:38 108-88-314.3 18.7 1,2,4-Trichlorobenzene ND ug/m3 07/12/21 23:01 120-82-114.1 1.87 1,1,1-Trichloroethane ND ug/m3 07/12/21 23:01 71-55-62.1 1.87 1,1,2-Trichloroethane ND ug/m3 07/12/21 23:01 79-00-51.0 1.87 Trichloroethene ND ug/m3 07/12/21 23:01 79-01-61.0 1.87 Trichlorofluoromethane 6.0 ug/m3 07/12/21 23:01 75-69-42.1 1.87 1,1,2-Trichlorotrifluoroethane ND ug/m3 07/12/21 23:01 76-13-12.9 1.87 1,2,4-Trimethylbenzene 28.2 ug/m3 07/12/21 23:01 95-63-61.9 1.87 1,3,5-Trimethylbenzene 7.8 ug/m3 07/12/21 23:01 108-67-81.9 1.87 Vinyl acetate ND ug/m3 07/12/21 23:01 108-05-41.3 1.87 Vinyl chloride ND ug/m3 07/12/21 23:01 75-01-40.49 1.87 m&p-Xylene 51.8 ug/m3 07/12/21 23:01 179601-23-13.3 1.87 o-Xylene 22.0 ug/m3 07/12/21 23:01 95-47-61.7 1.87 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/14/2021 06:17 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 20 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92548079 PHOENIX RISING Sample:SG-2 Lab ID:92548079002 Collected:07/06/21 15:04 Received:07/07/21 15:15 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: TO-15 Pace Analytical Services - Minneapolis TO15 MSV AIR Acetone 53.6 ug/m3 07/12/21 22:34 67-64-112.2 2.02 Benzene 55.9 ug/m3 07/12/21 22:34 71-43-23.3 2.02 Benzyl chloride ND ug/m3 07/12/21 22:34 100-44-75.3 2.02 Bromodichloromethane ND ug/m3 07/12/21 22:34 75-27-42.7 2.02 Bromoform ND ug/m3 07/12/21 22:34 75-25-210.6 2.02 Bromomethane ND ug/m3 07/12/21 22:34 74-83-91.6 2.02 1,3-Butadiene ND ug/m3 07/12/21 22:34 106-99-00.91 2.02 2-Butanone (MEK)17.4 ug/m3 07/12/21 22:34 78-93-36.1 2.02 Carbon disulfide 55.4 ug/m3 07/12/21 22:34 75-15-01.3 2.02 Carbon tetrachloride ND ug/m3 07/12/21 22:34 56-23-52.6 2.02 Chlorobenzene ND ug/m3 07/12/21 22:34 108-90-71.9 2.02 Chloroethane ND ug/m3 07/12/21 22:34 75-00-31.1 2.02 Chloroform ND ug/m3 07/12/21 22:34 67-66-35.0 2.02 Chloromethane 1.8 ug/m3 07/12/21 22:34 74-87-30.85 2.02 Cyclohexane ND ug/m3 07/12/21 22:34 110-82-73.5 2.02 Dibromochloromethane ND ug/m3 07/12/21 22:34 124-48-13.5 2.02 1,2-Dibromoethane (EDB)ND ug/m3 07/12/21 22:34 106-93-41.6 2.02 1,2-Dichlorobenzene ND ug/m3 07/12/21 22:34 95-50-16.2 2.02 1,3-Dichlorobenzene ND ug/m3 07/12/21 22:34 541-73-16.2 2.02 1,4-Dichlorobenzene ND ug/m3 07/12/21 22:34 106-46-76.2 2.02 Dichlorodifluoromethane 2.8 ug/m3 07/12/21 22:34 75-71-82.0 2.02 1,1-Dichloroethane ND ug/m3 07/12/21 22:34 75-34-31.7 2.02 1,2-Dichloroethane ND ug/m3 07/12/21 22:34 107-06-21.7 2.02 1,1-Dichloroethene ND ug/m3 07/12/21 22:34 75-35-41.6 2.02 cis-1,2-Dichloroethene ND ug/m3 07/12/21 22:34 156-59-21.6 2.02 trans-1,2-Dichloroethene ND ug/m3 07/12/21 22:34 156-60-51.6 2.02 1,2-Dichloropropane 5.5 ug/m3 07/12/21 22:34 78-87-51.9 2.02 cis-1,3-Dichloropropene ND ug/m3 07/12/21 22:34 10061-01-54.7 2.02 trans-1,3-Dichloropropene ND ug/m3 07/12/21 22:34 10061-02-64.7 2.02 Dichlorotetrafluoroethane ND ug/m3 07/12/21 22:34 76-14-22.9 2.02 Ethanol 18.3 ug/m3 07/12/21 22:34 64-17-53.9 2.02 Ethyl acetate ND ug/m3 07/12/21 22:34 141-78-61.5 2.02 Ethylbenzene 17.4 ug/m3 07/12/21 22:34 100-41-41.8 2.02 4-Ethyltoluene 6.9 ug/m3 07/12/21 22:34 622-96-85.0 2.02 n-Heptane 10.4 ug/m3 07/12/21 22:34 142-82-51.7 2.02 Hexachloro-1,3-butadiene ND ug/m3 07/12/21 22:34 87-68-310.9 2.02 n-Hexane 18.1 ug/m3 07/12/21 22:34 110-54-31.4 2.02 2-Hexanone 25.8 ug/m3 07/12/21 22:34 591-78-68.4 2.02 Methylene Chloride ND ug/m3 07/12/21 22:34 75-09-27.1 2.02 4-Methyl-2-pentanone (MIBK)82.2 ug/m3 07/12/21 22:34 108-10-18.4 2.02 Methyl-tert-butyl ether ND ug/m3 07/12/21 22:34 1634-04-47.4 2.02 Naphthalene 7.5 ug/m3 07/12/21 22:34 91-20-35.4 2.02 2-Propanol ND ug/m3 07/12/21 22:34 67-63-05.0 2.02 Propylene 37.6 ug/m3 07/12/21 22:34 115-07-11.8 2.02 Styrene 2.1 ug/m3 07/12/21 22:34 100-42-51.7 2.02 1,1,2,2-Tetrachloroethane ND ug/m3 07/12/21 22:34 79-34-52.8 2.02 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/14/2021 06:17 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 20 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92548079 PHOENIX RISING Sample:SG-2 Lab ID:92548079002 Collected:07/06/21 15:04 Received:07/07/21 15:15 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: TO-15 Pace Analytical Services - Minneapolis TO15 MSV AIR Tetrachloroethene 105 ug/m3 07/12/21 22:34 127-18-4 C81.4 2.02 Tetrahydrofuran ND ug/m3 07/12/21 22:34 109-99-91.2 2.02 Toluene 4360 ug/m3 07/14/21 10:27 108-88-346.4 60.6 1,2,4-Trichlorobenzene ND ug/m3 07/12/21 22:34 120-82-115.2 2.02 1,1,1-Trichloroethane ND ug/m3 07/12/21 22:34 71-55-62.2 2.02 1,1,2-Trichloroethane ND ug/m3 07/12/21 22:34 79-00-51.1 2.02 Trichloroethene ND ug/m3 07/12/21 22:34 79-01-61.1 2.02 Trichlorofluoromethane 9.2 ug/m3 07/12/21 22:34 75-69-42.3 2.02 1,1,2-Trichlorotrifluoroethane 3.2 ug/m3 07/12/21 22:34 76-13-13.2 2.02 1,2,4-Trimethylbenzene 21.6 ug/m3 07/12/21 22:34 95-63-62.0 2.02 1,3,5-Trimethylbenzene 6.3 ug/m3 07/12/21 22:34 108-67-82.0 2.02 Vinyl acetate ND ug/m3 07/12/21 22:34 108-05-41.4 2.02 Vinyl chloride ND ug/m3 07/12/21 22:34 75-01-40.53 2.02 m&p-Xylene 44.3 ug/m3 07/12/21 22:34 179601-23-13.6 2.02 o-Xylene 18.6 ug/m3 07/12/21 22:34 95-47-61.8 2.02 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/14/2021 06:17 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 20 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92548079 PHOENIX RISING Sample:SG-3 Lab ID:92548079003 Collected:07/06/21 15:24 Received:07/07/21 15:15 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: TO-15 Pace Analytical Services - Minneapolis TO15 MSV AIR Acetone 78.3 ug/m3 07/12/21 23:28 67-64-112.2 2.02 Benzene 48.3 ug/m3 07/12/21 23:28 71-43-23.3 2.02 Benzyl chloride ND ug/m3 07/12/21 23:28 100-44-75.3 2.02 Bromodichloromethane ND ug/m3 07/12/21 23:28 75-27-42.7 2.02 Bromoform ND ug/m3 07/12/21 23:28 75-25-210.6 2.02 Bromomethane ND ug/m3 07/12/21 23:28 74-83-91.6 2.02 1,3-Butadiene ND ug/m3 07/12/21 23:28 106-99-00.91 2.02 2-Butanone (MEK)27.3 ug/m3 07/12/21 23:28 78-93-36.1 2.02 Carbon disulfide 49.4 ug/m3 07/12/21 23:28 75-15-01.3 2.02 Carbon tetrachloride ND ug/m3 07/12/21 23:28 56-23-52.6 2.02 Chlorobenzene ND ug/m3 07/12/21 23:28 108-90-71.9 2.02 Chloroethane 4.3 ug/m3 07/12/21 23:28 75-00-31.1 2.02 Chloroform ND ug/m3 07/12/21 23:28 67-66-35.0 2.02 Chloromethane 21.9 ug/m3 07/12/21 23:28 74-87-30.85 2.02 Cyclohexane ND ug/m3 07/12/21 23:28 110-82-73.5 2.02 Dibromochloromethane ND ug/m3 07/12/21 23:28 124-48-13.5 2.02 1,2-Dibromoethane (EDB)ND ug/m3 07/12/21 23:28 106-93-41.6 2.02 1,2-Dichlorobenzene ND ug/m3 07/12/21 23:28 95-50-16.2 2.02 1,3-Dichlorobenzene ND ug/m3 07/12/21 23:28 541-73-16.2 2.02 1,4-Dichlorobenzene ND ug/m3 07/12/21 23:28 106-46-76.2 2.02 Dichlorodifluoromethane 2.9 ug/m3 07/12/21 23:28 75-71-82.0 2.02 1,1-Dichloroethane ND ug/m3 07/12/21 23:28 75-34-31.7 2.02 1,2-Dichloroethane ND ug/m3 07/12/21 23:28 107-06-21.7 2.02 1,1-Dichloroethene ND ug/m3 07/12/21 23:28 75-35-41.6 2.02 cis-1,2-Dichloroethene ND ug/m3 07/12/21 23:28 156-59-21.6 2.02 trans-1,2-Dichloroethene ND ug/m3 07/12/21 23:28 156-60-51.6 2.02 1,2-Dichloropropane 3.8 ug/m3 07/12/21 23:28 78-87-51.9 2.02 cis-1,3-Dichloropropene ND ug/m3 07/12/21 23:28 10061-01-54.7 2.02 trans-1,3-Dichloropropene ND ug/m3 07/12/21 23:28 10061-02-64.7 2.02 Dichlorotetrafluoroethane ND ug/m3 07/12/21 23:28 76-14-22.9 2.02 Ethanol 25.6 ug/m3 07/12/21 23:28 64-17-53.9 2.02 Ethyl acetate ND ug/m3 07/12/21 23:28 141-78-61.5 2.02 Ethylbenzene 17.9 ug/m3 07/12/21 23:28 100-41-41.8 2.02 4-Ethyltoluene 8.3 ug/m3 07/12/21 23:28 622-96-85.0 2.02 n-Heptane 15.9 ug/m3 07/12/21 23:28 142-82-51.7 2.02 Hexachloro-1,3-butadiene ND ug/m3 07/12/21 23:28 87-68-310.9 2.02 n-Hexane 31.8 ug/m3 07/12/21 23:28 110-54-31.4 2.02 2-Hexanone 28.8 ug/m3 07/12/21 23:28 591-78-68.4 2.02 Methylene Chloride ND ug/m3 07/12/21 23:28 75-09-27.1 2.02 4-Methyl-2-pentanone (MIBK)82.4 ug/m3 07/12/21 23:28 108-10-18.4 2.02 Methyl-tert-butyl ether ND ug/m3 07/12/21 23:28 1634-04-47.4 2.02 Naphthalene 7.4 ug/m3 07/12/21 23:28 91-20-35.4 2.02 2-Propanol ND ug/m3 07/12/21 23:28 67-63-05.0 2.02 Propylene 626 ug/m3 07/14/21 02:34 115-07-117.7 20.2 Styrene 4.4 ug/m3 07/12/21 23:28 100-42-51.7 2.02 1,1,2,2-Tetrachloroethane ND ug/m3 07/12/21 23:28 79-34-52.8 2.02 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/14/2021 06:17 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 20 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92548079 PHOENIX RISING Sample:SG-3 Lab ID:92548079003 Collected:07/06/21 15:24 Received:07/07/21 15:15 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: TO-15 Pace Analytical Services - Minneapolis TO15 MSV AIR Tetrachloroethene 7.5 ug/m3 07/12/21 23:28 127-18-4 C81.4 2.02 Tetrahydrofuran ND ug/m3 07/12/21 23:28 109-99-91.2 2.02 Toluene 1580 ug/m3 07/14/21 02:34 108-88-315.5 20.2 1,2,4-Trichlorobenzene ND ug/m3 07/12/21 23:28 120-82-115.2 2.02 1,1,1-Trichloroethane ND ug/m3 07/12/21 23:28 71-55-62.2 2.02 1,1,2-Trichloroethane ND ug/m3 07/12/21 23:28 79-00-51.1 2.02 Trichloroethene ND ug/m3 07/12/21 23:28 79-01-61.1 2.02 Trichlorofluoromethane 7.8 ug/m3 07/12/21 23:28 75-69-42.3 2.02 1,1,2-Trichlorotrifluoroethane 3.4 ug/m3 07/12/21 23:28 76-13-13.2 2.02 1,2,4-Trimethylbenzene 28.4 ug/m3 07/12/21 23:28 95-63-62.0 2.02 1,3,5-Trimethylbenzene 7.4 ug/m3 07/12/21 23:28 108-67-82.0 2.02 Vinyl acetate ND ug/m3 07/12/21 23:28 108-05-41.4 2.02 Vinyl chloride 2.7 ug/m3 07/12/21 23:28 75-01-40.53 2.02 m&p-Xylene 54.9 ug/m3 07/12/21 23:28 179601-23-13.6 2.02 o-Xylene 23.0 ug/m3 07/12/21 23:28 95-47-61.8 2.02 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/14/2021 06:17 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 20 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92548079 PHOENIX RISING Sample:SG-4 Lab ID:92548079004 Collected:07/06/21 15:44 Received:07/07/21 15:15 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: TO-15 Pace Analytical Services - Minneapolis TO15 MSV AIR Acetone 60.2 ug/m3 07/12/21 23:55 67-64-111.7 1.94 Benzene 44.6 ug/m3 07/12/21 23:55 71-43-23.2 1.94 Benzyl chloride ND ug/m3 07/12/21 23:55 100-44-75.1 1.94 Bromodichloromethane ND ug/m3 07/12/21 23:55 75-27-42.6 1.94 Bromoform ND ug/m3 07/12/21 23:55 75-25-210.2 1.94 Bromomethane ND ug/m3 07/12/21 23:55 74-83-91.5 1.94 1,3-Butadiene ND ug/m3 07/12/21 23:55 106-99-00.87 1.94 2-Butanone (MEK)9.6 ug/m3 07/12/21 23:55 78-93-35.8 1.94 Carbon disulfide 28.8 ug/m3 07/12/21 23:55 75-15-01.2 1.94 Carbon tetrachloride ND ug/m3 07/12/21 23:55 56-23-52.5 1.94 Chlorobenzene ND ug/m3 07/12/21 23:55 108-90-71.8 1.94 Chloroethane 2.4 ug/m3 07/12/21 23:55 75-00-31.0 1.94 Chloroform ND ug/m3 07/12/21 23:55 67-66-34.8 1.94 Chloromethane 11.0 ug/m3 07/12/21 23:55 74-87-30.81 1.94 Cyclohexane ND ug/m3 07/12/21 23:55 110-82-73.4 1.94 Dibromochloromethane ND ug/m3 07/12/21 23:55 124-48-13.4 1.94 1,2-Dibromoethane (EDB)ND ug/m3 07/12/21 23:55 106-93-41.5 1.94 1,2-Dichlorobenzene ND ug/m3 07/12/21 23:55 95-50-15.9 1.94 1,3-Dichlorobenzene ND ug/m3 07/12/21 23:55 541-73-15.9 1.94 1,4-Dichlorobenzene ND ug/m3 07/12/21 23:55 106-46-75.9 1.94 Dichlorodifluoromethane 2.7 ug/m3 07/12/21 23:55 75-71-82.0 1.94 1,1-Dichloroethane ND ug/m3 07/12/21 23:55 75-34-31.6 1.94 1,2-Dichloroethane ND ug/m3 07/12/21 23:55 107-06-21.6 1.94 1,1-Dichloroethene ND ug/m3 07/12/21 23:55 75-35-41.6 1.94 cis-1,2-Dichloroethene ND ug/m3 07/12/21 23:55 156-59-21.6 1.94 trans-1,2-Dichloroethene ND ug/m3 07/12/21 23:55 156-60-51.6 1.94 1,2-Dichloropropane 2.5 ug/m3 07/12/21 23:55 78-87-51.8 1.94 cis-1,3-Dichloropropene ND ug/m3 07/12/21 23:55 10061-01-54.5 1.94 trans-1,3-Dichloropropene ND ug/m3 07/12/21 23:55 10061-02-64.5 1.94 Dichlorotetrafluoroethane ND ug/m3 07/12/21 23:55 76-14-22.8 1.94 Ethanol 13.5 ug/m3 07/12/21 23:55 64-17-53.7 1.94 Ethyl acetate ND ug/m3 07/12/21 23:55 141-78-61.4 1.94 Ethylbenzene 12.4 ug/m3 07/12/21 23:55 100-41-41.7 1.94 4-Ethyltoluene 5.2 ug/m3 07/12/21 23:55 622-96-84.8 1.94 n-Heptane 16.3 ug/m3 07/12/21 23:55 142-82-51.6 1.94 Hexachloro-1,3-butadiene ND ug/m3 07/12/21 23:55 87-68-310.5 1.94 n-Hexane 35.9 ug/m3 07/12/21 23:55 110-54-31.4 1.94 2-Hexanone ND ug/m3 07/12/21 23:55 591-78-68.1 1.94 Methylene Chloride ND ug/m3 07/12/21 23:55 75-09-26.8 1.94 4-Methyl-2-pentanone (MIBK)42.9 ug/m3 07/12/21 23:55 108-10-18.1 1.94 Methyl-tert-butyl ether ND ug/m3 07/12/21 23:55 1634-04-47.1 1.94 Naphthalene 5.5 ug/m3 07/12/21 23:55 91-20-35.2 1.94 2-Propanol ND ug/m3 07/12/21 23:55 67-63-04.8 1.94 Propylene 1100 ug/m3 07/13/21 00:20 115-07-150.9 58.2 Styrene 4.7 ug/m3 07/12/21 23:55 100-42-51.7 1.94 1,1,2,2-Tetrachloroethane ND ug/m3 07/12/21 23:55 79-34-52.7 1.94 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/14/2021 06:17 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 20 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92548079 PHOENIX RISING Sample:SG-4 Lab ID:92548079004 Collected:07/06/21 15:44 Received:07/07/21 15:15 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: TO-15 Pace Analytical Services - Minneapolis TO15 MSV AIR Tetrachloroethene 9.2 ug/m3 07/12/21 23:55 127-18-41.3 1.94 Tetrahydrofuran ND ug/m3 07/12/21 23:55 109-99-91.2 1.94 Toluene 1930 ug/m3 07/13/21 00:20 108-88-344.6 58.2 1,2,4-Trichlorobenzene ND ug/m3 07/12/21 23:55 120-82-114.6 1.94 1,1,1-Trichloroethane ND ug/m3 07/12/21 23:55 71-55-62.2 1.94 1,1,2-Trichloroethane ND ug/m3 07/12/21 23:55 79-00-51.1 1.94 Trichloroethene ND ug/m3 07/12/21 23:55 79-01-61.1 1.94 Trichlorofluoromethane 3.4 ug/m3 07/12/21 23:55 75-69-42.2 1.94 1,1,2-Trichlorotrifluoroethane ND ug/m3 07/12/21 23:55 76-13-13.0 1.94 1,2,4-Trimethylbenzene 17.8 ug/m3 07/12/21 23:55 95-63-61.9 1.94 1,3,5-Trimethylbenzene 5.1 ug/m3 07/12/21 23:55 108-67-81.9 1.94 Vinyl acetate ND ug/m3 07/12/21 23:55 108-05-41.4 1.94 Vinyl chloride 3.6 ug/m3 07/12/21 23:55 75-01-40.50 1.94 m&p-Xylene 35.5 ug/m3 07/12/21 23:55 179601-23-13.4 1.94 o-Xylene 15.3 ug/m3 07/12/21 23:55 95-47-61.7 1.94 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/14/2021 06:17 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 20 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92548079 PHOENIX RISING Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 755496 TO-15 TO-15 TO15 MSV AIR Low Level Laboratory:Pace Analytical Services - Minneapolis Associated Lab Samples:92548079001, 92548079002, 92548079003, 92548079004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:4028316 Associated Lab Samples:92548079001, 92548079002, 92548079003, 92548079004 Matrix:Air Analyzed 1,1,1-Trichloroethane ug/m3 ND 0.56 07/12/21 09:47 1,1,2,2-Tetrachloroethane ug/m3 ND 0.70 07/12/21 09:47 1,1,2-Trichloroethane ug/m3 ND 0.28 07/12/21 09:47 1,1,2-Trichlorotrifluoroethane ug/m3 ND 0.78 07/12/21 09:47 1,1-Dichloroethane ug/m3 ND 0.41 07/12/21 09:47 1,1-Dichloroethene ug/m3 ND 0.40 07/12/21 09:47 1,2,4-Trichlorobenzene ug/m3 ND 3.8 07/12/21 09:47 1,2,4-Trimethylbenzene ug/m3 ND 0.50 07/12/21 09:47 1,2-Dibromoethane (EDB)ug/m3 ND 0.39 07/12/21 09:47 1,2-Dichlorobenzene ug/m3 ND 1.5 07/12/21 09:47 1,2-Dichloroethane ug/m3 ND 0.41 07/12/21 09:47 1,2-Dichloropropane ug/m3 ND 0.47 07/12/21 09:47 1,3,5-Trimethylbenzene ug/m3 ND 0.50 07/12/21 09:47 1,3-Butadiene ug/m3 ND 0.22 07/12/21 09:47 1,3-Dichlorobenzene ug/m3 ND 1.5 07/12/21 09:47 1,4-Dichlorobenzene ug/m3 ND 1.5 07/12/21 09:47 2-Butanone (MEK)ug/m3 ND 1.5 07/12/21 09:47 2-Hexanone ug/m3 ND 2.1 07/12/21 09:47 2-Propanol ug/m3 ND 1.2 07/12/21 09:47 4-Ethyltoluene ug/m3 ND 1.2 07/12/21 09:47 4-Methyl-2-pentanone (MIBK)ug/m3 ND 2.1 07/12/21 09:47 Acetone ug/m3 ND 3.0 07/12/21 09:47 Benzene ug/m3 ND 0.81 MN07/12/21 09:47 Benzyl chloride ug/m3 ND 1.3 07/12/21 09:47 Bromodichloromethane ug/m3 ND 0.68 07/12/21 09:47 Bromoform ug/m3 ND 2.6 07/12/21 09:47 Bromomethane ug/m3 ND 0.39 07/12/21 09:47 Carbon disulfide ug/m3 ND 0.32 07/12/21 09:47 Carbon tetrachloride ug/m3 ND 0.64 07/12/21 09:47 Chlorobenzene ug/m3 ND 0.47 07/12/21 09:47 Chloroethane ug/m3 ND 0.27 07/12/21 09:47 Chloroform ug/m3 ND 1.2 MN07/12/21 09:47 Chloromethane ug/m3 ND 0.21 07/12/21 09:47 cis-1,2-Dichloroethene ug/m3 ND 0.40 07/12/21 09:47 cis-1,3-Dichloropropene ug/m3 ND 1.2 07/12/21 09:47 Cyclohexane ug/m3 ND 0.88 07/12/21 09:47 Dibromochloromethane ug/m3 ND 0.86 07/12/21 09:47 Dichlorodifluoromethane ug/m3 ND 0.50 07/12/21 09:47 Dichlorotetrafluoroethane ug/m3 ND 0.71 07/12/21 09:47 Ethanol ug/m3 ND 0.96 07/12/21 09:47 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/14/2021 06:17 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 20 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92548079 PHOENIX RISING Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:4028316 Associated Lab Samples:92548079001, 92548079002, 92548079003, 92548079004 Matrix:Air Analyzed Ethyl acetate ug/m3 ND 0.37 07/12/21 09:47 Ethylbenzene ug/m3 ND 0.44 07/12/21 09:47 Hexachloro-1,3-butadiene ug/m3 ND 2.7 07/12/21 09:47 m&p-Xylene ug/m3 ND 0.88 07/12/21 09:47 Methyl-tert-butyl ether ug/m3 ND 1.8 07/12/21 09:47 Methylene Chloride ug/m3 ND 1.8 07/12/21 09:47 n-Heptane ug/m3 ND 0.42 07/12/21 09:47 n-Hexane ug/m3 ND 0.36 07/12/21 09:47 Naphthalene ug/m3 ND 1.3 07/12/21 09:47 o-Xylene ug/m3 ND 0.44 07/12/21 09:47 Propylene ug/m3 ND 0.44 07/12/21 09:47 Styrene ug/m3 ND 0.43 07/12/21 09:47 Tetrachloroethene ug/m3 ND 0.34 07/12/21 09:47 Tetrahydrofuran ug/m3 ND 0.30 07/12/21 09:47 Toluene ug/m3 ND 0.38 07/12/21 09:47 trans-1,2-Dichloroethene ug/m3 ND 0.40 07/12/21 09:47 trans-1,3-Dichloropropene ug/m3 ND 1.2 07/12/21 09:47 Trichloroethene ug/m3 ND 0.27 07/12/21 09:47 Trichlorofluoromethane ug/m3 ND 0.57 07/12/21 09:47 Vinyl acetate ug/m3 ND 0.36 07/12/21 09:47 Vinyl chloride ug/m3 ND 0.13 07/12/21 09:47 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 4028317LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1-Trichloroethane ug/m3 57.759.3 97 70-130 1,1,2,2-Tetrachloroethane ug/m3 77.175.4 102 70-132 1,1,2-Trichloroethane ug/m3 61.859.6 104 70-134 1,1,2-Trichlorotrifluoroethane ug/m3 84.283.6 101 70-130 1,1-Dichloroethane ug/m3 46.943.9 107 70-133 1,1-Dichloroethene ug/m3 39.643.5 91 70-130 1,2,4-Trichlorobenzene ug/m3 192177 108 69-132 1,2,4-Trimethylbenzene ug/m3 53.454 99 70-142 1,2-Dibromoethane (EDB)ug/m3 87.882.5 106 70-138 1,2-Dichlorobenzene ug/m3 63.666.2 96 70-146 1,2-Dichloroethane ug/m3 46.244.4 104 70-132 1,2-Dichloropropane ug/m3 53.150.6 105 70-134 1,3,5-Trimethylbenzene ug/m3 53.353.7 99 70-143 1,3-Butadiene ug/m3 23.524.2 97 70-136 1,3-Dichlorobenzene ug/m3 65.766.3 99 70-145 1,4-Dichlorobenzene ug/m3 66.666.3 100 70-140 2-Butanone (MEK)ug/m3 31.932.3 99 50-139 2-Hexanone ug/m3 55.844.8 125 70-148 2-Propanol ug/m3 150149 101 67-135 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/14/2021 06:17 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 20 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92548079 PHOENIX RISING Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 4028317LABORATORY CONTROL SAMPLE: LCSSpike 4-Ethyltoluene ug/m3 54.853.7 102 70-145 4-Methyl-2-pentanone (MIBK)ug/m3 53.744.9 120 70-139 Acetone ug/m3 125128 98 64-130 Benzene ug/m3 40.034.8 115 70-131 Benzyl chloride ug/m3 55.357.6 96 70-130 Bromodichloromethane ug/m3 74.273.1 102 70-133 Bromoform ug/m3 121114 106 70-137 Bromomethane ug/m3 41.442.5 97 64-134 Carbon disulfide ug/m3 38.034.4 110 70-131 Carbon tetrachloride ug/m3 68.669.4 99 70-131 Chlorobenzene ug/m3 50.850.2 101 70-130 Chloroethane ug/m3 27.528.8 95 69-141 Chloroform ug/m3 58.152.4 111 70-130 Chloromethane ug/m3 21.922.6 97 70-130 cis-1,2-Dichloroethene ug/m3 45.743.4 105 70-137 cis-1,3-Dichloropropene ug/m3 57.449.4 116 70-144 Cyclohexane ug/m3 45.737.4 122 70-137 Dibromochloromethane ug/m3 10293.2 109 70-132 Dichlorodifluoromethane ug/m3 53.954.6 99 70-130 Dichlorotetrafluoroethane ug/m3 68.571.2 96 70-130 Ethanol ug/m3 130124 105 63-133 Ethyl acetate ug/m3 41.338.9 106 70-136 Ethylbenzene ug/m3 50.447.8 105 70-142 Hexachloro-1,3-butadiene ug/m3 145133 109 70-135 m&p-Xylene ug/m3 10095.4 105 70-141 Methyl-tert-butyl ether ug/m3 43.939.6 111 70-143 Methylene Chloride ug/m3 193190 101 70-130 n-Heptane ug/m3 50.444.6 113 70-137 n-Hexane ug/m3 39.338 103 70-135 Naphthalene ug/m3 66.265.2 101 67-132 o-Xylene ug/m3 49.447.6 104 70-141 Propylene ug/m3 20.718.9 110 70-130 Styrene ug/m3 48.347 103 70-142 Tetrachloroethene ug/m3 72.473.4 99 70-130 Tetrahydrofuran ug/m3 36.132.1 112 70-136 Toluene ug/m3 49.241.6 118 70-138 trans-1,2-Dichloroethene ug/m3 46.643.6 107 70-130 trans-1,3-Dichloropropene ug/m3 63.050.5 125 70-145 Trichloroethene ug/m3 60.458.4 103 70-130 Trichlorofluoromethane ug/m3 52.062 84 69-135 Vinyl acetate ug/m3 50.846.4 110 70-146 Vinyl chloride ug/m3 29.528 105 70-137 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/14/2021 06:17 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 20 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92548079 PHOENIX RISING Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result QualifiersRPDResult 10568732001 4029321SAMPLE DUPLICATE: 1,1,1-Trichloroethane ug/m3 NDND 1,1,2,2-Tetrachloroethane ug/m3 NDND 1,1,2-Trichloroethane ug/m3 NDND 1,1,2-Trichlorotrifluoroethane ug/m3 .94JND 1,1-Dichloroethane ug/m3 NDND 1,1-Dichloroethene ug/m3 NDND 1,2,4-Trichlorobenzene ug/m3 NDND 1,2,4-Trimethylbenzene ug/m3 1.3JND 1,2-Dibromoethane (EDB)ug/m3 NDND 1,2-Dichlorobenzene ug/m3 NDND 1,2-Dichloroethane ug/m3 NDND 1,2-Dichloropropane ug/m3 NDND 1,3,5-Trimethylbenzene ug/m3 .88JND 1,3-Butadiene ug/m3 NDND 1,3-Dichlorobenzene ug/m3 1.1JND 1,4-Dichlorobenzene ug/m3 6.1 16.0 2-Butanone (MEK)ug/m3 5.9 36.1 2-Hexanone ug/m3 NDND 2-Propanol ug/m3 20.3 120.6 4-Ethyltoluene ug/m3 NDND 4-Methyl-2-pentanone (MIBK)ug/m3 .9JND Acetone ug/m3 42.8 740.0 Benzene ug/m3 .35JND Benzyl chloride ug/m3 NDND Bromodichloromethane ug/m3 NDND Bromoform ug/m3 NDND Bromomethane ug/m3 NDND Carbon disulfide ug/m3 .22JND Carbon tetrachloride ug/m3 NDND Chlorobenzene ug/m3 NDND Chloroethane ug/m3 NDND Chloroform ug/m3 NDND Chloromethane ug/m3 0.86 90.94 cis-1,2-Dichloroethene ug/m3 NDND cis-1,3-Dichloropropene ug/m3 NDND Cyclohexane ug/m3 .91JND Dibromochloromethane ug/m3 NDND Dichlorodifluoromethane ug/m3 2.5 112.8 Dichlorotetrafluoroethane ug/m3 NDND Ethanol ug/m3 151 2148 Ethyl acetate ug/m3 2.4 12.3 Ethylbenzene ug/m3 .89JND Hexachloro-1,3-butadiene ug/m3 NDND m&p-Xylene ug/m3 2.6JND Methyl-tert-butyl ether ug/m3 NDND Methylene Chloride ug/m3 NDND n-Heptane ug/m3 1.6 51.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/14/2021 06:17 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 20 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92548079 PHOENIX RISING Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result QualifiersRPDResult 10568732001 4029321SAMPLE DUPLICATE: n-Hexane ug/m3 1.4 81.3 Naphthalene ug/m3 NDND o-Xylene ug/m3 .96JND Propylene ug/m3 NDND Styrene ug/m3 .86JND Tetrachloroethene ug/m3 NDND Tetrahydrofuran ug/m3 1.3 21.3 Toluene ug/m3 3.5 13.5 trans-1,2-Dichloroethene ug/m3 3.4 23.5 trans-1,3-Dichloropropene ug/m3 NDND Trichloroethene ug/m3 NDND Trichlorofluoromethane ug/m3 16.8 016.8 Vinyl acetate ug/m3 NDND Vinyl chloride ug/m3 NDND Parameter Units Dup Result QualifiersRPDResult 10568732002 4029322SAMPLE DUPLICATE: 1,1,1-Trichloroethane ug/m3 NDND 1,1,2,2-Tetrachloroethane ug/m3 NDND 1,1,2-Trichloroethane ug/m3 NDND 1,1,2-Trichlorotrifluoroethane ug/m3 .77JND 1,1-Dichloroethane ug/m3 NDND 1,1-Dichloroethene ug/m3 NDND 1,2,4-Trichlorobenzene ug/m3 NDND 1,2,4-Trimethylbenzene ug/m3 1.3JND 1,2-Dibromoethane (EDB)ug/m3 NDND 1,2-Dichlorobenzene ug/m3 NDND 1,2-Dichloroethane ug/m3 NDND 1,2-Dichloropropane ug/m3 NDND 1,3,5-Trimethylbenzene ug/m3 .89JND 1,3-Butadiene ug/m3 NDND 1,3-Dichlorobenzene ug/m3 NDND 1,4-Dichlorobenzene ug/m3 6.4 85.9 2-Butanone (MEK)ug/m3 3.4JND 2-Hexanone ug/m3 NDND 2-Propanol ug/m3 2.3JND 4-Ethyltoluene ug/m3 NDND 4-Methyl-2-pentanone (MIBK)ug/m3 NDND Acetone ug/m3 25.5 226.0 Benzene ug/m3 .42JND Benzyl chloride ug/m3 NDND Bromodichloromethane ug/m3 NDND Bromoform ug/m3 NDND Bromomethane ug/m3 NDND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/14/2021 06:17 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 20 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92548079 PHOENIX RISING Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result QualifiersRPDResult 10568732002 4029322SAMPLE DUPLICATE: Carbon disulfide ug/m3 NDND Carbon tetrachloride ug/m3 NDND Chlorobenzene ug/m3 NDND Chloroethane ug/m3 NDND Chloroform ug/m3 NDND Chloromethane ug/m3 0.97 110.87 cis-1,2-Dichloroethene ug/m3 NDND cis-1,3-Dichloropropene ug/m3 NDND Cyclohexane ug/m3 .89JND Dibromochloromethane ug/m3 NDND Dichlorodifluoromethane ug/m3 2.8 142.5 Dichlorotetrafluoroethane ug/m3 NDND Ethanol ug/m3 86.9 1872.2 Ethyl acetate ug/m3 .32JND Ethylbenzene ug/m3 .88JND Hexachloro-1,3-butadiene ug/m3 NDND m&p-Xylene ug/m3 2.5JND Methyl-tert-butyl ether ug/m3 NDND Methylene Chloride ug/m3 NDND n-Heptane ug/m3 1.5 41.6 n-Hexane ug/m3 1.1J1.4 Naphthalene ug/m3 NDND o-Xylene ug/m3 .91JND Propylene ug/m3 NDND Styrene ug/m3 NDND Tetrachloroethene ug/m3 NDND Tetrahydrofuran ug/m3 .8JND Toluene ug/m3 2.1 12.1 trans-1,2-Dichloroethene ug/m3 NDND trans-1,3-Dichloropropene ug/m3 NDND Trichloroethene ug/m3 NDND Trichlorofluoromethane ug/m3 16.9 117.1 Vinyl acetate ug/m3 NDND Vinyl chloride ug/m3 NDND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/14/2021 06:17 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 20 #=QL# QUALIFIERS Pace Project No.: Project: 92548079 PHOENIX RISING DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS Result may be biased high due to carryover from previously analyzed sample.C8 The reporting limit has been raised in accordance with Minnesota Statutes 4740.2100 Subpart 8. C, D. Reporting Limit Evaluation Rule.MN REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/14/2021 06:17 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 20 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92548079 PHOENIX RISING Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92548079001 755496SG-1 TO-15 92548079002 755496SG-2 TO-15 92548079003 755496SG-3 TO-15 92548079004 755496SG-4 TO-15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 07/14/2021 06:17 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 20 Page 20 of 20 ATTACHMENT F NCDEQ RISK CALCULATOR OUTPUT DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: June 2021 Basis: May 2021 EPA RSL Table Site ID: Exposure Unit ID: SG-1 CAS # Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 49.8 1.494 - 6.5E+03 4.6E-05 71-43-2 Benzene 43.4 1.302 3.6E-01 6.3E+00 3.6E-06 4.2E-02 75-15-0 Carbon Disulfide 117 3.51 - 1.5E+02 4.8E-03 74-87-3 Chloromethane 3.2 0.096 - 1.9E+01 1.0E-03 75-71-8 Dichlorodifluoromethane 2.8 0.084 - 2.1E+01 8.1E-04 78-87-5 Dichloropropane, 1,2- 4.5 0.135 7.6E-01 8.3E-01 1.8E-07 3.2E-02 100-41-4 Ethylbenzene 16.4 0.492 1.1E+00 2.1E+02 4.4E-07 4.7E-04 142-82-5 Heptane, N- 14.8 0.444 - 8.3E+01 1.1E-03 110-54-3 Hexane, N- 58.2 1.746 - 1.5E+02 2.4E-03 591-78-6 Hexanone, 2- 27.1 0.813 - 6.3E+00 2.6E-02 67-63-0 Isopropanol 7.6 0.228 - 4.2E+01 1.1E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone) 16.8 0.504 - 1.0E+03 9.7E-05 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 101 3.03 - 6.3E+02 9.7E-04 91-20-3 ~Naphthalene 7 0.21 8.3E-02 6.3E-01 2.5E-06 6.7E-02 115-07-1 Propylene 88.4 2.652 - 6.3E+02 8.5E-04 100-42-5 Styrene 2 0.06 - 2.1E+02 5.8E-05 127-18-4 Tetrachloroethylene 14.8 0.444 1.1E+01 8.3E+00 4.1E-08 1.1E-02 108-88-3 Toluene 1510 45.3 - 1.0E+03 8.7E-03 75-69-4 Trichlorofluoromethane 6 0.18 - - 95-63-6 Trimethylbenzene, 1,2,4- 28.2 0.846 - 1.3E+01 1.4E-02 108-67-8 Trimethylbenzene, 1,3,5- 7.8 0.234 - 1.3E+01 3.7E-03 106-42-3 Xylene, P- 51.8 1.554 - 2.1E+01 1.5E-02 108-38-3 Xylene, m- 51.8 1.554 - 2.1E+01 1.5E-02 95-47-6 Xylene, o- 22 0.66 - 2.1E+01 6.3E-03 Cumulative: 6.8E-06 2.5E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: June 2021 Basis: May 2021 EPA RSL Table Site ID: Exposure Unit ID: SG-2 CAS # Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 53.6 1.608 - 6.5E+03 5.0E-05 71-43-2 Benzene 55.9 1.677 3.6E-01 6.3E+00 4.7E-06 5.4E-02 75-15-0 Carbon Disulfide 55.4 1.662 - 1.5E+02 2.3E-03 74-87-3 Chloromethane 1.8 0.054 - 1.9E+01 5.8E-04 75-71-8 Dichlorodifluoromethane 2.8 0.084 - 2.1E+01 8.1E-04 78-87-5 Dichloropropane, 1,2- 5.5 0.165 7.6E-01 8.3E-01 2.2E-07 4.0E-02 100-41-4 Ethylbenzene 17.4 0.522 1.1E+00 2.1E+02 4.6E-07 5.0E-04 142-82-5 Heptane, N- 10.4 0.312 - 8.3E+01 7.5E-04 110-54-3 Hexane, N- 18.1 0.543 - 1.5E+02 7.4E-04 591-78-6 Hexanone, 2- 25.8 0.774 - 6.3E+00 2.5E-02 78-93-3 Methyl Ethyl Ketone (2-Butanone) 17.4 0.522 - 1.0E+03 1.0E-04 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 82.2 2.466 - 6.3E+02 7.9E-04 91-20-3 ~Naphthalene 7.5 0.225 8.3E-02 6.3E-01 2.7E-06 7.2E-02 115-07-1 Propylene 37.6 1.128 - 6.3E+02 3.6E-04 100-42-5 Styrene 2.1 0.063 - 2.1E+02 6.0E-05 127-18-4 Tetrachloroethylene 105 3.15 1.1E+01 8.3E+00 2.9E-07 7.6E-02 108-88-3 Toluene 4360 130.8 - 1.0E+03 2.5E-02 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 3.2 0.096 - 1.0E+03 1.8E-05 75-69-4 Trichlorofluoromethane 9.2 0.276 - - 95-63-6 Trimethylbenzene, 1,2,4- 21.6 0.648 - 1.3E+01 1.0E-02 108-67-8 Trimethylbenzene, 1,3,5- 6.3 0.189 - 1.3E+01 3.0E-03 106-42-3 Xylene, P- 44.3 1.329 - 2.1E+01 1.3E-02 108-38-3 Xylene, m- 44.3 1.329 - 2.1E+01 1.3E-02 95-47-6 Xylene, o- 18.6 0.558 - 2.1E+01 5.4E-03 Cumulative: 8.4E-06 3.4E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: June 2021 Basis: May 2021 EPA RSL Table Site ID: Exposure Unit ID: SG-3 CAS # Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 78.3 2.349 - 6.5E+03 7.3E-05 71-43-2 Benzene 48.3 1.449 3.6E-01 6.3E+00 4.0E-06 4.6E-02 75-15-0 Carbon Disulfide 49.4 1.482 - 1.5E+02 2.0E-03 74-87-3 Chloromethane 21.9 0.657 - 1.9E+01 7.0E-03 75-71-8 Dichlorodifluoromethane 2.9 0.087 - 2.1E+01 8.3E-04 78-87-5 Dichloropropane, 1,2- 3.8 0.114 7.6E-01 8.3E-01 1.5E-07 2.7E-02 75-00-3 Ethyl Chloride (Chloroethane) 4.3 0.129 - 2.1E+03 1.2E-05 100-41-4 Ethylbenzene 17.9 0.537 1.1E+00 2.1E+02 4.8E-07 5.1E-04 142-82-5 Heptane, N- 15.9 0.477 - 8.3E+01 1.1E-03 110-54-3 Hexane, N- 31.8 0.954 - 1.5E+02 1.3E-03 591-78-6 Hexanone, 2- 28.8 0.864 - 6.3E+00 2.8E-02 78-93-3 Methyl Ethyl Ketone (2-Butanone) 27.3 0.819 - 1.0E+03 1.6E-04 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 82.4 2.472 - 6.3E+02 7.9E-04 91-20-3 ~Naphthalene 7.4 0.222 8.3E-02 6.3E-01 2.7E-06 7.1E-02 115-07-1 Propylene 626 18.78 - 6.3E+02 6.0E-03 100-42-5 Styrene 4.4 0.132 - 2.1E+02 1.3E-04 127-18-4 Tetrachloroethylene 7.5 0.225 1.1E+01 8.3E+00 2.1E-08 5.4E-03 108-88-3 Toluene 1580 47.4 - 1.0E+03 9.1E-03 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 3.4 0.102 - 1.0E+03 2.0E-05 75-69-4 Trichlorofluoromethane 7.8 0.234 - - 95-63-6 Trimethylbenzene, 1,2,4- 28.4 0.852 - 1.3E+01 1.4E-02 108-67-8 Trimethylbenzene, 1,3,5- 7.4 0.222 - 1.3E+01 3.5E-03 75-01-4 Vinyl Chloride 2.7 0.081 1.7E-01 2.1E+01 4.8E-07 7.8E-04 106-42-3 Xylene, P- 54.9 1.647 - 2.1E+01 1.6E-02 108-38-3 Xylene, m- 54.9 1.647 - 2.1E+01 1.6E-02 95-47-6 Xylene, o- 23 0.69 - 2.1E+01 6.6E-03 Cumulative: 7.8E-06 2.6E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: June 2021 Basis: May 2021 EPA RSL Table Site ID: Exposure Unit ID: SG-4 CAS # Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 60.2 1.806 - 6.5E+03 5.6E-05 71-43-2 Benzene 44.6 1.338 3.6E-01 6.3E+00 3.7E-06 4.3E-02 75-15-0 Carbon Disulfide 28.8 0.864 - 1.5E+02 1.2E-03 74-87-3 Chloromethane 11 0.33 - 1.9E+01 3.5E-03 75-71-8 Dichlorodifluoromethane 2.7 0.081 - 2.1E+01 7.8E-04 78-87-5 Dichloropropane, 1,2- 2.5 0.075 7.6E-01 8.3E-01 9.9E-08 1.8E-02 75-00-3 Ethyl Chloride (Chloroethane) 2.4 0.072 - 2.1E+03 6.9E-06 100-41-4 Ethylbenzene 12.4 0.372 1.1E+00 2.1E+02 3.3E-07 3.6E-04 142-82-5 Heptane, N- 16.3 0.489 - 8.3E+01 1.2E-03 110-54-3 Hexane, N- 35.9 1.077 - 1.5E+02 1.5E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone) 9.6 0.288 - 1.0E+03 5.5E-05 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 42.9 1.287 - 6.3E+02 4.1E-04 91-20-3 ~Naphthalene 5.5 0.165 8.3E-02 6.3E-01 2.0E-06 5.3E-02 115-07-1 Propylene 1100 33 - 6.3E+02 1.1E-02 100-42-5 Styrene 4.7 0.141 - 2.1E+02 1.4E-04 127-18-4 Tetrachloroethylene 9.2 0.276 1.1E+01 8.3E+00 2.6E-08 6.6E-03 108-88-3 Toluene 1930 57.9 - 1.0E+03 1.1E-02 75-69-4 Trichlorofluoromethane 3.4 0.102 - - 95-63-6 Trimethylbenzene, 1,2,4- 17.8 0.534 - 1.3E+01 8.5E-03 108-67-8 Trimethylbenzene, 1,3,5- 5.1 0.153 - 1.3E+01 2.4E-03 75-01-4 Vinyl Chloride 3.6 0.108 1.7E-01 2.1E+01 6.4E-07 1.0E-03 106-42-3 Xylene, P- 35.5 1.065 - 2.1E+01 1.0E-02 108-38-3 Xylene, m- 35.5 1.065 - 2.1E+01 1.0E-02 95-47-6 Xylene, o- 15.3 0.459 - 2.1E+01 4.4E-03 Cumulative: 6.8E-06 1.9E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: June 2021 Basis: May 2021 EPA RSL Table Site ID: Exposure Unit ID: Soil Gas (Maximum Concentrations) CAS # Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 78.3 2.349 - 6.5E+03 7.3E-05 71-43-2 Benzene 55.9 1.677 3.6E-01 6.3E+00 4.7E-06 5.4E-02 75-15-0 Carbon Disulfide 117 3.51 - 1.5E+02 4.8E-03 74-87-3 Chloromethane 21.9 0.657 - 1.9E+01 7.0E-03 75-71-8 Dichlorodifluoromethane 2.9 0.087 - 2.1E+01 8.3E-04 78-87-5 Dichloropropane, 1,2- 5.5 0.165 7.6E-01 8.3E-01 2.2E-07 4.0E-02 75-00-3 Ethyl Chloride (Chloroethane) 4.3 0.129 - 2.1E+03 1.2E-05 100-41-4 Ethylbenzene 17.9 0.537 1.1E+00 2.1E+02 4.8E-07 5.1E-04 142-82-5 Heptane, N- 16.3 0.489 - 8.3E+01 1.2E-03 110-54-3 Hexane, N- 58.2 1.746 - 1.5E+02 2.4E-03 591-78-6 Hexanone, 2- 28.8 0.864 - 6.3E+00 2.8E-02 67-63-0 Isopropanol 7.6 0.228 - 4.2E+01 1.1E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone) 27.3 0.819 - 1.0E+03 1.6E-04 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 101 3.03 - 6.3E+02 9.7E-04 91-20-3 ~Naphthalene 7.5 0.225 8.3E-02 6.3E-01 2.7E-06 7.2E-02 115-07-1 Propylene 1100 33 - 6.3E+02 1.1E-02 100-42-5 Styrene 4.7 0.141 - 2.1E+02 1.4E-04 127-18-4 Tetrachloroethylene 105 3.15 1.1E+01 8.3E+00 2.9E-07 7.6E-02 108-88-3 Toluene 4360 130.8 - 1.0E+03 2.5E-02 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 3.4 0.102 - 1.0E+03 2.0E-05 75-69-4 Trichlorofluoromethane 9.2 0.276 - - 95-63-6 Trimethylbenzene, 1,2,4- 28.4 0.852 - 1.3E+01 1.4E-02 108-67-8 Trimethylbenzene, 1,3,5- 7.8 0.234 - 1.3E+01 3.7E-03 75-01-4 Vinyl Chloride 3.6 0.108 1.7E-01 2.1E+01 6.4E-07 1.0E-03 106-42-3 Xylene, P- 54.9 1.647 - 2.1E+01 1.6E-02 108-38-3 Xylene, m- 54.9 1.647 - 2.1E+01 1.6E-02 95-47-6 Xylene, o- 23 0.69 - 2.1E+01 6.6E-03 Cumulative: 9.0E-06 3.8E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator REFERENCE 22 UNITED STATES DEPARTMENT OF THE INTERIOR GEOLOGICAL SURVEY Basic Elements of Ground-Water Hydrology With Reference to Conditions in North Carolina By Ralph C Heath U.S. Geological Survey Water-Resources Investigations Open-File Report 80-44 Prepared in cooperation with the North Carolina Department of Natural^ Resources and Community Development Raleigh, North Carolina 1980 United States Department of the Interior CECIL D. ANDRUS, Secretary GEOLOGICAL SURVEY H. W. Menard, Director For Additional Information Write to: GEOLOGICAL SURVEY Post Office Box 2857 Raleigh, North Carolina 27602 Copies of this report may be purchased from: U.S. GEOLOGICAL SURVEY Open-File Services Section Branch of Distribution Box 25425, Federal Center Denver, Colorado 80225 Preface Ground water is one of North Carolina's most valuable natural resources. It is the primary source-of water supplies in rural areas and is also widely used by industries and municipalities, especially in the Coastal Plain. However, its use is not increasing in proportion to the growth of the State's population and economy. Instead, the present emphasis in water-supply development is on large regional systems based on reservoirs on large streams. The value of ground water as a resource not only depends on its widespread occurrence but also on its generally excellent chemical quality. Thus, in most cases, ground-water does not require treatment prior to use, except as a precaution against unsuspected pollution. However, in an effort to control stream pollution, greater and greater emphasis is being placed on the land disposal of liquid and solid wastes. One result of this may be increasingly widespread deterioration of ground-water quality. The development of ground-water supplies and the protection of ground-water quality requires knowledge of the occurrence of ground water and knowledge of how ground- water systems function. The lack of such knowledge among those involved in the development, management, and regulation of water supplies has been an important element in the avoidance of ground water as a source of large supplies and in the increasing occur- rence of ground-water pollution. This report was prepared as an aid to developing a better understanding of the ground-water resources of the State. It consists of 46 essays grouped into five parts. The topics covered by these essays range from the most basic aspects of ground-water hydrology to the identification and correction of problems that affect the operation of supply wells. The essays were designed both for self study and for use in workshops on ground- water hydrology and on the development and operation of ground-water supplies. Relative to the use of this report in workshops, selected essays have been used in workshops for the staff of the North Carolina Department of Natural Resources and Com- munity Development and in short courses for operators of water systems that utilize wells as a source of supply. The essays used in each workshop and short course were selected on the basis of the background and needs of the group. Finally, most of the essays contain sketches that illustrate the main points covered in the text. However, to facilitate the rearrangement of essays for use in different workshops, they are not numbered and titled as in most technical reports. For those who find this disconcerting, I suggest that the text of each essay simply be viewed as an expanded explanation of the sketches. Ralph C. Heath Definitions of Terms Aquifer (p. 7)1 A water-bearing bed that will yield water in a usable quantity. Bedrock (p . 20) A collective term for the metamorphic and igneous rocks underlying the Piedmont and mountains. Capillary fringe (p . 5 ) The zone above the water table in which water is held by surface tension. Water in the capillary fringe is under a pressure less than atmospheric. Conductivity, hydraulic (p. 12 ) The capacity of a unit cube of rock to transmit water. Cone of depression (p. 49) The depression of heads around a pumping well caused by the withdrawal of water. Confining bed (p.7 ) A layer of rock that hampers the movement of water. Dispersion (p. 40) The extent to which a substance injected into an aquifer spreads as it moves through the aquifer. Drawdown (p. 52) The reduction in head at a point caused by the withdrawal of water from an aquifer. Equipotential line (p. 42 ) A line (on a map) or cross section along which total heads are the same. Flow line (p. 42 ) The idealized path followed by particles of water. Flow net (p. 42 ) The grid pattern formed by a network of flow lines and equipotential lines. Formation (p. 22) A distinct rock layer named for a locality near which it occurs. Gradient, hydraulic (p. 10) Change in head per unit of distance measured in the direction of the steepest change. Head, total (p. 10) The height above a datum plane of the surface of a column of water. It is composed in a ground-water system of elevation head and pressure head. Porosity (p. 9 ) The openings in a rock. ~ Saprolite (p. 20) The soil-like rock that occurs between land surface and bedrock in the Piedmont and mountains. Specific retention (p. 9 ) The volume of water retained in a rock after gravity drainage. Specific yield (p. 9 ) The volume of water that will drain under the influence of gravity from a saturated rock. Storage coefficient (p. 33) The volume of water released from storage in a unit prism of an aquifer when the head is lowered a unit distance. Stratification (p. 36) The layered structure of sedimentary rocks. Transmisslvity (p. 37) The capacity of an aquifer to transmit water. It equals the hydraulic conductivity times the aquifer thickness. Water table (p. 5 ) The level in the zone of saturation at which the pressure is equal to the atmospheric pressure. Zone, saturated (p. 5 ) Subsurface zone in which all interconnected openings are full of water. Zone, unsaturated (p. 5 ) Subsurface zone, usually starting at the land surface, that contains both water and air. 1 Page numbers refer to page on which the term is discussed. IV Contents Page Preface ............................................................................... m Definition of terms .................................................................... iv Part I. INTRODUCTION TO GROUND-WATER HYDROLOGY ........................... j. Ground water as a resource in North Carolina ..................................... 3 Rocks and water ................................................................. ~~4 Underground water .............................................................. 5 Hydrologic cycle ................................................................. e Aquifers and confining beds ...................................................... 7 Porosity of soils and rocks ....................................................... ~a Specific yield and specific retention ............................................... 9 Heads and gradients ............................................................. 10 Hydraulic conductivity ........................................................... 12 Functions of ground-water systems ............................................... 14 Part II. GROUND-WATER GEOLOGY OF NORTH CAROLINA .......................... 17 Physical setting of the ground-water system ....................................... 18 Water-bearing rocks .............................................................. 20 Rock units and aquifers in the Coastal Plain ....................................... 22 Ground-water situation in the Coastal Plain ....................................... 24 Rock units and aquifers in the Piedmont and mountains .......................... 2e Ground-water situation in the Piedmont and mountains ............................ 2? Hydraulic characteristics of the Piedmont and mountain ground-water system ............................................... 28 Selecting well sites in the Piedmont and mountains .............................'... 30 Part III. BASIC HYDRAULIC CONCEPTS AND METHODS .............................. 33 Capillarity and unsaturated flow .................................................. 34 Stratification and unsaturated flow ................................................ 36 Transmissivity ................................................................... 37 Storage coefficient ............................................................... 33 Ground-water flow and dispersion ................................................ 40 Ground-water movement and topography ......................................... 41 Ground-water flow nets .......................................................... 42 Ground-water movement and stratification ........................................ 44 Ground-water velocity ............................................................ 46 The cone of depression .......................................................... 49 The source of water derived from wells ............................................ so Aquifer tests ..................................................................... 52 Analysis of aquifer-test data ...................................................... 54 Time-drawdown analysis ......................................................... 56 Distance - drawdown analysis .................................................... 58 Part IV. BASIC ASPECTS OF GROUND-WATER DEVELOPMENT ....................... 59 Well-construction methods ....................................................... eo Well logs ........................................................................ ea Water-well design ................................................................ 64 Well-acceptance tests ............................................................ ee Well interference ................................................................. 68 Aquifer boundaries ............................................................... ?o Salt-water encroachment ......................................................... 72 Well-field design ................................................................. 74 Part V. OPERATION OF GROUND-WATER SUPPLIES .................................. 77 Measurements of water levels and pumping rates ................................... 78 Supply-well problems — decline in yield ........................................... so Protection of supply wells ......................................................... ea Supply-well problems — changes in water quality .................................. 84 Well records and files ............................................................. ae International system units ........................................... Inside back cover Relation of units of hydraulic conductivity and transmissivity ............................................... Inside back cover Acknowledgments Technical review: M. D. Winner and D. G. Jordan Editorial review: H. S. Revel Drafting: John Teel Typing: Mamie C. Hodge and Janet McBride Cover Photograph . Servicing a continuous water-level recorder on an observation well operated by the U.S. Geological Survey in the Cape Hatteras National Seashore. (Photograph by Ralph C. Heath, U.S. Geological Survey) VI PART I. INTRODUCTION TO GROUND-WATER HYDROLOGY "... all concerned recognize that the quality that the ... wells ... will be retained and of water from the ... River is normally far used as the backup supply ... when the superior to that of the wells ..." chloride concentration in the River becomes ..,, i, .* f *u to° hiQh -••" However, all concerned are aware of the fact that there are times When the river Will -Excerpts from a letter regarding a change in the be unsuitable as a source Of potable water. source of a municipal supply from wells to a stream. To provide for such situations, it was agreed Ground Water As A Resource in North Carolina 1 1 11 n n n n / \i i i i•"• i1 t n IT-\ • m mm ,0^ f- 11 1 111 n *»*» m m n i in in m 11 n n *** <$ sS* sf* *** ',/*»/>,c " r^ J/7/">" r ^(vv. ""*• /^x FTTI /w ^^ —\ A ^^-n ^-> '/pf \V^<^ iii in Y »^i M/\// w&%® III Y^ V w- \^i^^^\^y \(/ y\/lterLt\// In 1975, North Carolina had 224 municipal water systems serving 500 or more customers. Of these systems, 102 obtained a part or all of their water from wells. These systems serve more than 500,000 people with 70 Mgal/day (million gallons per day) of water. These figures show the importance of ground water in North Carolina as a source of municipal supplies. They do not, however, show the overall importance of ground water. In addition to the people served ground water through municipal systems, more than 2,400,000 people living in rural areas (of a total State population of more than 5,000,000) obtain their water supplies from wells and springs. Ground water is also an important source of water for industries and agriculture. The U.S. Geological Survey estimates that 540 Mgal/day of ground water were being used in North Carolina in 1975. Most of this use is in the Coastal Plain region where ground water is obtained from extensive and productive sand and or limestone aquifers. Although the aquifers underlying the Piedmont and moun- tains are much less productive than those in the Coastal Plain, ground water is an important source of supply for small cities and industries and is the primary source for rural homes and farms. Rocks and Water PRIMARY OPENINGS WELL-SORTED SAND POORLY-SORTED SAND POROUS MATERIAL SECONDARY OPENINGS FRACTURED ROCK FRACTURES IN GRANITE CAVERNS IN LIMESTONE Most of the rocks near the Earth's surface are composed of both solids and holes. The solid part is, of course, much more obvious than the holes, but without the holes there would be no underground water to supply wells and springs. There are different kinds of holes in rocks and it is sometimes useful to be aware of these. If the holes were formed at the same time as the rock, they are referred to as primary openings. The pores in sand and gravel are primary openings. The sand aquifers underlying the Coastal Plain contain water in primary openings. If the holes were formed after the rock was formed, they are referred to as secondary openings. The fractures in granite and other igneous and metamorphic rocks are secondary openings. Caverns in limestone, which are formed as ground water slowly dissolves the rock, are an especially important type of secondary opening. Ground water in the bedrock underlying the Piedmont and moun- tains occurs in secondary openings, as does much of that in the limestones underlying the Coastal Plain. Underground Water Surface water LU O CC. oc. CO O IVI CO INTERMEDIATE ZONE CAPILLARY (FRJNGE JJ. L Water table GROUND WATER All water beneath the land surface is referred to as underground water. The equivalent term for water on the land surface is surface water. Underground water occurs in two different zones. One zone, which occurs immediately below the land surface in most areas, contains both water and air and is referred to as the unsaturated zone. The unsaturated zone is almost invariably underlain by a zone in which all interconnected openings are full of water. This zone is referred to as the saturated zone. Water in the saturated zone is the only underground water that is available to supply wells and springs and is the only water to which the name ground water is correctly applied. Recharge of the saturated zone occurs by percolation of water from the land surface through the unsaturated zone. The unsatura- ted zone is, therefore, of great importance to ground-water hydrology. This zone may be divided usefully into three parts (or subzones); (1) the soil zone, (2) the intermediate zone, and (3) the capillary fringe. The upper part - from the land surface to a depth of several feet - is referred to as the so/7 zone. The soil zone is the zone that supports plant growth. It is crisscrossed by living roots, by holes left by decayed roots of earlier vegetation, and by animal and worm burrows. This zone tends to have a higher porosity and to be more permeable than the underlying material. The soil zone is underlain by the intermediate zone, which differs in thickness from place to place depending on the thickness of the soil zone and the depth to the capillary fringe. Moving to the lowest part of the unsaturated zone, the boundary between it and the saturated zone is occupied by the capillary fringe. The capillary fringe results from the attraction between water and rocks. As a result of this attraction, water clings as a film on the surface of rock particles and rises up small- diameter pores against the pull of gravity. Water in the capillary fringe and in the overlying part of the unsaturated zone is under a negative hydraulic pressure - that is, it is under a pressure less than atmospheric. The water table is the level in the saturated zone at which the hydraulic pressure is equal to atmospheric pressure. Hydrologic Cycle The term hydrologic cycle is used to refer to the constant movement of water above, on, and below the Earth's surface. The concept of the hydrologic cycle is central to an understanding of the occurrence of water and the develop- ment and management of water supplies. Although the hydrologic cycle has neither a beginning nor an end, it is convenient to discuss its principal features by starting with evaporation from vegetation, from exposed surfaces including the land surface, and from the ocean. This moisture forms clouds which, under favorable conditions, return the water to the land surface or oceans in the form of precipitation. Precipitation occurs in several forms, including rain, snow, and hail, but we will consider only rain in this discussion. The first rain wets vegetation and other surfaces and then begins to infiltrate into the ground. Infiltration rates vary widely, depending on land use, from possibly as much as an inch per hour in mature forests to a tenth of an inch per hour in silty soils under cultivation. When and if the rate of precipitation exceeds the rate of infiltration, overland flow occurs. The first infiltration replaces soil moisture and thereafter the excess percolates slowly across the intermediate zone to the zone of saturation. The water in the zone of saturation moves downward and laterally to sites of ground-water discharge such as springs on hillsides or seeps in the bottoms of streams and lakes or beneath the ocean. Water reaching streams, both by overland flow and from ground-water discharge, moves to the sea where it is again evaporated to perpetuate the cycle. • Movement is, of course, the key element in the concept of the hydrologic cycle. Some "typical" rates of movement are shown in the following table, along with the distribution of the Earth's water supply. Location Rate of movement Distribution of Earth'* water supply (percent) Atmosphere Water on land surface Water below the land surface Ice caps and glaciers Oceans 100s of miles per day 10s of miles per day feet per day feet per day 0.001 .02 .52 1.88 97.58 Aquifers and Confining Beds Water-table well Artesian well ,_. 5g o 1^ URATED JONE t— en UNCONFINED AQUIFER CONFINING BED CONFINED AQUIFER " '.*•'•'•.'•••'••'.•'.*"• :.:V.::.'/: ::••""•'••//. ••••;•• SAND ':'••'.'•'• • ' . ',' • • •'.•'•'' .'•.-.••'•.'.•'•••• • ••.•:••'.•. ••'••• ••:.•. S^fl^j i i ii i i ii i ii i i i -T — 'L IMESTONE| — 1 1 Il l l li i i \ \ \ 1 7 POTENTIOMETRIC-) SURFACE £ CAPILLARY-, FRINGE J nn<fiim<mimi Wuici Tuuic "^ Well screen Well screen or open hole I s L \ t c u» at < i J i « 3 M M Q. r r From the standpoint of ground-water occurrence, all rocks underlying the Earth's surface are classified either as aquifers or confining beds. An aquifer is a rock unit that will yield water in a usable quantity to a well or spring. (In geological usage, "rock" includes unconsolidated sediments.) A confining bed is a rock unit that restricts the movement of ground water either into or out of adjacent aquifers. Ground water occurs in aquifers under two different conditions. Where water only partly fills an aquifer, the upper surface of the saturated zone is free to rise and decline. The water in such aquifers is said to be unconfined and the aquifers are referred to as unconfined aquifers. Where water completely fills an aquifer that is overlain by a confining bed, the water in the aquifer is said to be confined. Such aquifers are referred to as confined aquifers. Wells open to unconfined aquifers are referred to as water-table wells. The water level in these wells indicates the position of the water table in the surrounding aquifer. Wells drilled into .confined aquifers are referred to as artesian wells. The water level in artesian wells stands at some height above the top of the aquifer but not necessarily above the land surface. The static water level in tightly cased wells open to a confined aquifer stands at the level of the potentiometric surface of the aquifer. Porosity of Soils and Rocks Vu =0.3 ft 3 Vt = 1.0 ft 3 Water — _- o o o o o o o o oo ooooooooo OOO° ° O O O Oo o Dry o o°°°sand °°° o o s u n u Q o OOOOOOOOOOooooooooo 0 oooooooOo ooo o o o o o o < o o 6*0 ^ o o"o~ o * * ~ " '<>•• Saturated |^~sand ^ O<3 O'p O Q"O O O ooo "<» o a o Z! • o o o ooo <a oob "ooo o Porosity (q Volume of voids.( V» ) 0.3 ft 3 Total volume (Vt) 1.0 ft 3 = 0.30 The openings (holes) in a soil or rock are referred to as its porosity. We express porosity either as a decimal fraction or as a percent. Thus t V If we multiply the porosity determined with equation 1 by 100, the result is porosity expres- sed as a percent. Soils are among the most porous of natural materials because soil particles tend to form loose clumps and because of the presence of root holes and animal burrows. where n = porosity, as a decimal fraction, Vt = total volume of a soil or rock sample vs = volume of solids in the sample, and vv = volume of holes (voids). Selected values of porosity (Percent by volume) Material Primary openings Secondary openings Equal-size spheres (marbles) Loosest packing .......... Tighest packing .......... Soil .......................... Clay ......................... Sand ........................ Gravel ....................... Limestone (Castle Hayne) .... Marble (mountains) .......... Granite, gneiss, and schist .... (Piedmont and mountains). 48 26 55 50 25 20 10 10 2 0.1 Specific Yield and Specific Retention S r =0.l ft3 O O Q o o o o e e e o o o_p e e o o~b 0*000000_""<> Moist ~"° ° 000 „„_ J — O • O o o o sand o_o o o o O o o o e a o"o e »~c Water Water retained as a film on rock surfaces and in capillary- size openings after gravity drainage. GRANULAR MATERIAL S y =0.2 ft Water 0.2ft 3 O.I ft 3n = Sv t S r - ——— -h ————= 0.30 y I ft 3 I ft 3 Porosity is important in ground-water hy- drology because it tells us the maximum amount of water a rock can contain when it is saturated. However, it is equally important to know that only a part of this water is available to supply a well or a spring. Hydro legists divide porosity into the part that will drain under the influence of gravity (called specific yield) and the part that is re- tained as a film on rock surfaces and in very- small openings (called specific retention). It should be noted that the physical forces that control specific retention are the same forces involved in the thickness and moisture con- tent of the capillary fringe. Specific yield tells us how much water is available for man's use and specific retention tells us how much water remains in the rock after it is drained. FRACTURED ROCK Thus and s --d by vt where by = specific yield, Sr = specific retention, V^ = volume of water that drains from a total volume of Vt, Vr = volume of water retained in a total volume of Vt, and vt = total volume of a soil or rock sample. Selected values of porosity, specific yield, and specific retention (Percent by volume) Material Porotlty Specific yield Specific retention Soil ............................. Clay ............................. Sand ............................ Gravel ........................... Limestone (Castle Hayne) ........ Marble ........................... Granite, gneiss, and schist ......... 55 50 25 20 20 2 0.1 40 2 22 19 18 1.8 0.09 15 48 3 1 2 0.2 0.01 Heads and Gradients Measuring point ( top of casing ) Well I x*(Alt I0° ft) (Alt 98ft'|Well 2 L/CJJto wat ude of measuring point - 1x///r /r / +- / s >th er t 3 J » J •> /7 »*•in t r uisiunce ILH /uu \\\ ———— ^M Land surface i TV ~~ Head loss(ht) <~™~ T-m_ _L^ __ •a o o>JC « UNCONFINED AQUIFER £ Well Jl >«— 00 }Water table^ Ground- water movement "S Bottom of aquifer — •>. 01 « (National Geodetic uj Datum plane Vertical Datum of 1929) In many ground-water investigations it is either necessary or desirable to know the depth to the water table and the direction and rate of ground-water movement. Both of these require the measurement of the position of the water level in wells. The first step is to identify (and describe) a fixed point - measuring point (MP) - that all measurements will be referred to. The depth to the water level below the measuring point can be measured by any of several means. (See MEASUREMENTS OF WATER LEVELS AND PUMPING RATES.) In order to deter- mine the direction and rate of ground-water movement, it is necessary to measure the depth to water (D to W) in at least three wells and to determine the altitude of their measur- ing points with respect to a common datum plane - usually mean sea level (now officially the National Geodetic Vertical Datum of 1929). If the D to W in a nonflowing well is sub- tracted from the altitude of the MP, the result is the total head at the well. Total head, as we know from fluid mechanics, is composed of elevation head, pressure head, and velocity head. Because ground water moves relatively slowly, we can ignore velocity head. There- fore, the total head at an observation well involves only two components - elevation head and pressure head. Ground water moves in the direction of decreasing total head; this may or may not be in the direction of decreasing pressure head. The equation for total head (hs) is (I) where z is elevation head and is the distance from the datum plane to the point where the pressure head is hp. All other factors being constant, the rate of ground-water movement depends on the hy- draulic gradient. The hydraulic gradient is the change in head per unit of distance in a given direction. If not specified, the direction is understood to be in the direction in which the maximum rate of decrease in head occurs. 10 If we assume that the movement of ground water is in the plane of the preceding draw- ing - in other words, that it moves from well 1 to well 2 - we can calculate the hydraulic gradient from the information given on the drawing. The hydraulic gradient is hL/L where h|_ is the head loss between wells 1 and 2 and L is the distance between them, or h L (100 ft -15 ft) - (98ft-18ft) L " 780ft 85 ft - 80 ft _ 5ft 780 ft 780 ft Gradients are usually expressed in feet/mile or feetper 1000 eetThus Both the direction of ground-water move- ment and the hydraulic gradient can be deter- mined if the following data are available for three wells located in any triangular arrange- ment such as that shown on Sketch A. 1. The relative geographic position of the wells, 2. The distance between the wells, and 3. The relative position of the water level in each well. Steps in the solution are outlined below and illustrated on Sketch B. (a) Identify the well that has the inter- mediate water level-that is, neither the highest nor the lowest water level. (b) Calculate the position between the wells having the highest and lowest water levels at which the ground- water level is the same as in the intermediate well. (c) Draw a straight line between the intermediate well and the point identified in step b between the wells having the highest and lowest water level. This line represents a segment of the water-level contour along which the total head is the same as in the intermediate well. (d) Draw a line perpendicular to the water-level contour and through either the well with the highest or the lowest water level. This line parallels the direction of ground-water move- ment. (e) Divide the difference in water level between the well and the contour by the distance between the well and the contour. The answer is the hydraulic gradient. SKETCH A SKETCH B Well I 26.26 ft. Well 2 26.20 ft Well 3 26.07 ft. 0 25 50 IOO FEET (b) (26.26-26.20) (26.26-26.07) 2I5 26.26 ft. X = 68 ft. (a) Well 2 W.L. = 26.20 ft (e) 26.2 -26.07 HL _ O.I3 ft. L " I33 ft - 5.2 ft/mile 26.07 ft. 11 Hydraulic Conductivity Unit element of aquifer Streamlines representing laminar flow r / i /^".* • 11 —— • IIJ="°, — —r J. « .*. • 5 • • • * * • -.". ' o - . • 0 . - • & • 0 • • *• <»-0 o . • r2T.^«. 7^ 150 ft' day Unit prism of aquifer Aquifers transmit water from recharge areas to discharge areas and thus function as pipe- lines. The factors controlling ground-water movement were first expressed in the form of an equation by Henry Darcy in 1856. Darcy's law is where dl Q is the quantity of water, K is hydraulic conductivity and depends on the size and arrangement of the water- transmitting openings (pores and fractures), A is cross-sectional area through which the flow occurs, and dh/dl is the hydraulic gradient.1 Because the quantity of water (Q) is directly proportional to the hydraulic gradient (dh/dl), we know that ground-water flow is laminar - that is, water particles tend to follow discrete streamlines and not mix with particles in adja- cent streamlines. Hydraulic conductivity is expressed in terms of a unit hydraulic gradient (such as foot per foot) in order to permit ready comparison of the water-transmitting capacity of different materials. The units of hydraulic conductivity are those of velocity. Thus, if we rearrange equation 1 for K, we obtain Adh _ (ft3 day"1 ) (ft) = (ft2) (ft)(2) 'Where hydraulic gradient is discussed as an independent entity, as in the preceding discussion of HE0C6 /JK) GVOIEMS, it is shown s>rrbol ical ly as h{_/L. Where hydraulic gradient appears as one of the factors in an equation, as in equation I, it is shown $>rrbolically as dh/dl to be consistent with other ground-water literature. 12 Hydraulic Conductivity of Selected Rocks Hydraulic conductivity (rounded values) Material_________________(ft/day) [(gal/day)/ft*] (meters/day) Coarse sand .................. Medium sand ................. Silt ........................... Clay .......................... Limestone (Castle Hayne) ..... Saprolite ...................... Granite and gneiss ............ Slate ......................... . . . . . 200 ..... 130 ..... 1 . . . . . 0.001 . . . . . 300 ..... 5 ..... 5 ..... 3 1500 1000 5 0.01 2000 50 50 25 60 40 0.2 0.0004 80 2 2 1 Hydraulic conductivity replaces the term "field coefficient of permeability" and should be used when referring to the water-transmitting characteristic of material in quantitative terms. It is still permissible to refer in qualitative terms to "permeable" and "impermeable" material. PROBLEM - Determine the hydraulic conductivity of the confined aquifer shown in the preceding drawing in both feet per day and gallons per day per square foot. (1) Solution in feet per day (Equation) (Q) (A) (dl/dh) K _ Qdl _ 150 ft3 y 1 y 1 ft _ 150 ft3 _ iqn ft/d K - Adh * day X ft* X 1 ft ' day ft* ' 15° ft/day (2) Conversion of feet per day to gallons per day per square foot 13 Functions of Ground-Water Systems Discharge area GROUND-WATER SYSTEM The aquifers and confining beds underlying any area comprise the ground-water system of the area. Hydraulically, this system serves two functions: (1) it stores water to the extent of its porosity, and (2) it transmits water from re- charge areas to discharge areas. Thus, a ground-water system serves both as a reservoir and as a pipeline. With the exception of cavernous limestones and lava flows, ground- water systems are more effective as reservoirs than as pipelines. Water enters ground-water systems in recharge areas and moves through them, as dictated by hydraulic gradients and hydraulic conductivities, to discharge areas. The identification of recharge areas is becoming increasingly important because of the expanding use of the land surface for waste disposal. In a humid area, such as North Caro- lina, recharge occurs in all interstream areas - that is, in all areas except along streams and their adjoining flood plains. The streams and flood plains are, under most conditions, discharge areas. Recharge rates are generally expressed in terms of volume (such as gallons or ft3), per unit of time (such as a day or a year), and per unit of area (such as a square mile or acre). When the units are reduced to their simpliest form, the result is recharge expressed as a depth of water on the land surface per unit of time. Recharge rates vary from year to year, depending on the amount of precipitation, its seasonal distribution, air temperature, and other factors. Among the other factors are land use. For example, recharge rates are much higher in forest than in cities. 14 Relatively few estimates of recharge rates have been made in North Carolina. The information presently available suggests that rates in the Piedmont and mountains range from about 100,000 gallons per day per square mile in the areas underlain by Triassic rocks to about 250,000 (gal/d)/mi2 in areas underlain by granite and gneiss. Rates in the Coastal Plain are believed to range from about 250,000 (gal/d)/mi2 in areas underlain by clayey soils to 1,000,000 (gal/d)/mi2 in areas underlain by thick sandy soils. The rate of movement of ground water from recharge areas to discharge areas depends on the hydraulic conductivities of the aquifers and confining beds through which the water moves and on the hydraulic gradients. (See GROUND- WATER VELOCITY.) A convenient way of showing the rate is in terms of the time required for ground water to move from different parts of a recharge area to the nearest discharge area. The time ranges from a few days in the zone adjacent to the discharge area to thousands of years (millennia) for water that moves from the central part of the recharge area through the deeper parts of the system. Natural discharge from ground-water systems not only includes the flow of springs and the seepage of water into stream channels, but also evaporation from the upper part of the capillary fringe where it occurs within a few feet of the land surface. Large amounts of water are also withdrawn from the capillary fringe and zone of saturation by plants during the growing season. Thus, discharge areas not only include the channels of perennial streams but also the adjoining flood plains and other low-lying areas. One of the most significant differences between recharge areas and discharge areas is that discharge areas are invariably much smaller in areal extent that recharge areas. This shows, as we would expect, that discharge areas are more "efficient" than recharge areas. Recharge involves unsaturated movement of water in the vertical direction; in other words, in the direction in which the hydraulic conductiv- ity is generally the lowest, whereas discharge involves saturated movement, much of it in the horizontal direction - that is, in the direction of the largest hydraulic conductivity. 15 16 PART II. GROUND-WATER GEOLOGY OF NORTH CAROLINA "It is time that we return to examining hydrologic systems and attempting to describe the systems in a more realistic, quantitative manner. When one comes to solving problems of chemical contamina- tion, it is necessary to quantify the distribution of porosity, dispersivity, and other factors. Dispersivity measured at only a few field locations tends to be large; from three to more than five orders of magnitude larger than those measured in the labora- tory. This suggests that the geologic complexity of real aquifers greatly compli- cates the flow field, causing increased hydrodynamic dispersion. -From remarks by Dr. John Bredehoeft at hearings on "Ground-water quality research and development" before the Subcommittee on Environment and the Atmosphere, 95th Congress, 2nd Session, April 1978, p. 236. 17 Physical Setting of the Ground-Water System MOUNTAINS PIEDMONT COASTAL PLAIN Bint Rid9« front Pi«4mont Pletttu •5-J '-.i'Stt lt»tl^jjxx*W &*&*!&&% Gronitt t«4 6 ntitt 'Cfcoflttlt 6nti*t t«4 Btlt Scftitt I—10 From the standpoint of ground-water hydrology, North Carolina may be divided into two zones, one zone consisting of the Coastal Plain and the other consisting of the Piedmont Plateau and the Appalachian Mountains. Because differences in the ground-water system coincide with the different topographic divisions of the State, it will be useful to briefly review these divisions. As Jasper L. Stuckey, former North Carolina State Geologist, has said, "The State of North Carolina extends from the crest of the Great Smoky and Unaka mountains on the west, to the Atlantic Ocean on the east and lies across three major topographic provinces of the United States. As a result, it is divided into three natural divisions—the Coastal Plain on the east, the Piedmont Plateau in the center, and the Appalachian Mountains on the west. Beginning at sea level at the eastern edge of the State the surface of North Carolina rises gradually in elevation and increases in irregularity until it reaches its maximum height and ruggedness in the Appalachian Mountains on the west." The Coastal Plain includes almost one-half of the area of the State and extends west from the Atlantic Ocean to the Fall Line. The Fall Line is not a line but a zone 30 to 40 miles wide that is marked by discontinuous rapids where major streams leave the bedrock areas of the Piedmont and flow onto the unconsolidated sediments of the Coastal Plain. Altitudes in the Coastal Plain range from sea level at the coast to about 300 to 500 ft. along the Fall Line. The Coastal Plain can conveniently be divided into the Tidewater Region, in which the effect of tides and other oceanic influences are apparent, and the Inner Coastal Plain which, though underlain by unconsolidated (Coastal Plain) sediments, is not subject to direct oceanic effect. The Piedmont Plateau contains about 20,000 mi2, or two-fifths of the land area of the State. It lies between the Coastal Plain on the east and the Appalachian Mountains on the west. Altitudes in the Piedmont range from about 500 ft above sea level along the Fall Line to about 1500 to 2000 ft. along its western border. The Piedmont consists of well- rounded hills and long-rolling ridges with a northeast-southwest trend. Parts of the Piedmont contain prominent hills referred to as mountains, including the Uwharrie Mountains in Montgomery and Randolph Counties, the South Mountains in Burke and Rutherford Counties, and the Brushy Mountains in Wilkes County. The Appalachian Mountains are bounded on the east by the Blue Ridge Mountains and on the west by the Great Smoky and Unaka Mountains. The mountain slopes are gentle, presenting smooth rounded outlines. The mountain region of North Carolina contains the highest peak east of the Mississippi, Mt. Mitchell at 6,684 ft., 43 peaks above 6,000 ft, and 82 peaks between 5,000 and 6,000 ft. in altitude. The eastern Continental Divide follows the Blue Ridge Mountains so that most of the mountain area drains west to the Gulf of Mexico. The streams are well graded and cascades and waterfalls are only locally abundant. Reference: Stuckey, Jasper L, 1965, North Carolina: its geology and mineral resources: North Carolina Depart- ment of Conservation and Development, 550 p. 19 Water-Bearing Rocks The rocks underlying the surface of North Carolina form the environment in which ground water occurs and moves. Geologists divide all rocks exposed at the Earth's surface into one of two great classes: (1) igneous, or (2) sedimentary. Igneous rocks are those that have formed from a molten or partially-molten state. Some types of igneous rocks, including granite, solidify at great depth below the land surface and are referred to as intrusive igneous rocks. Other igneous rocks form from lava or volcanic ash ejected onto the surface and are referred to as extrusive igneous rocks. Sedimentary rocks are rocks formed by the accumulation of sediment in water or from the air. Most sedimentary rocks are unconsolida- ted (soil-like) at the time of formation. If they are, in time, buried deeply enough, or if they undergo certain chemical changes, they may become consolidated. Both igneous and sedimentary rocks may, over the course of geologic time, reach depths beneath the Earth's crust at which they are subjected to great heat and pressure. This may alter both their structural characteristics and their mineral composition to such an extent that they are changed into metamorphic rocks. Depending on their original mode of origin, they may be referred to, for example, as metavolcanic or metasedimentary rocks. North Carolina is underlain by an unusually large number of different types of rocks, including representatives of both the igneous and sedimentary classes and types of both classes that have been subjected to metamor- phism. The major types of rocks are shown on the accompanying generalized geological map. The Piedmont and mountain regions are underlain by igneous and metamorphosed igneous and sedimentary rocks that are referred to collectively as bedrock. They form broad northeast - southwest trending zones in which the rocks are of similar composition and origin. Most of these rocks were formed in the Precambrian and Paleozoic Erasof the Earth's history and thus are at least several hundred million years old. The bedrock in the Piedmont and mountains is exposed at the surface along steep hillsides and stream channels and in roadcuts. In most other areas they are covered by unconsolidated material formed from the breakdown of the bedrock in the process refer- red to by geologists as weathering. This layer of weathered material is referred to as saprolite or residuum. The Coastal Plain region is also underlain by the same types of igneous and methamorphic rocks as those present in the Piedmont. However, in the Coastal Plain they are covered by unconcolidated sedimentary deposits which range in thickness from a few feet along the Fall Line to about 10,000 ft. at Cape Hatteras. (See the geologic section in PHYSICAL SETTING OF THE GROUND- WATER SYSTEM.) The sediments underlying the Coastal Plain include sand, clay, beds composed of seashells, and limestone. 20 84°83"82 to " T .Metamorphosed volconic rocks Yorktown Formation (clays and shell beds) Castle Hayne Limestone (sandy to dense limestone)NvJ Metomorphosed sedimentary and volconic rocksPee Dee Formation (sands, clays limestones)Gneiss and schist Black Creek Formotion (sands, clays, and morls) .*.".\\"\ Mostly micaceous schist •••••I Tuscolooso Formation equi- valent (sands and clays) Triossic rocks(sandstone and conglomerates) 76" Rock Units and Aquifers in the Coastal Plain The Coastal Plain of North Carolina is underlain by sedimentary rocks that were deposited in water in several different layers which geologists refer to as formations. Formations are commonly given names for places near which they are exposed at the land surface, for ease in referring to them in geologic literature. Rock layers are normally given names by geologists if they have a distinct composition or, if of variable composition, include materials deposited during a particular segment of geologic time. Named rock units may or may not coincide with hydrologic units so that in ground-water reports some aquifers may be referred to by the formal geologic names used by geologists, such as the Castle Hayne Limestone and Yorktown Formation, and others may be given more informal names, such as the "Upper aquifer", "Surficial aquifer" or "post-Miocene deposits." The name "Surficial aquifer" indicates the aquifer in any area that is closest to land surface and thus is clearly identifiable, regardless of any other names that may have been assigned to that rock unit. Non-geologists concerned both with ground- water problems and with ground-water studies in the Coastal Plain are probably con- fused by the different named applied to the different hydrologic units. The following chart was prepared in an effort to eliminate some of this confusion. We should note, however, that in preparing the chart we have neither tried to include all formation names nor been overly concerned with the relative geologic age of the formations. The names used in the last two columns can be confusing to the extent that all units are referred to as "aquifers." Confining beds composed of clay occur in all of the formations and in the formations of Cretaceous age clay comprises about half of the total thickness. The two most important aquifers in the Coastal Plain are the upper aquifer and the limestone aquifer. Recharge of the ground- water system is from precipitation on the land surface. Therefore, the surficial aquifer has the largest yield in terms of rate per unit area (for example, gallons per minute per square mile). The upper aquifer is also most subject to pollution from land-surface waste disposal. The limestone aquifer is the most productive aquifer in North Carolina in terms of yields of individual wells. Wells capable of yielding more than 1000 gal/min can. readily be developed in this aquifer. Geologic age Formation or geologic name Names used in some ground-water reports Simpliest useful hydrologic names Pleistocene Pliocene Miocene Oligocene Eocene Paleocene Cretaceous Pleistocene deposits Croatan Formation Yorktown Formation Pungo River Formation Belgrade Formation River Bend Formation Castle Hayne Limestone Beaufort Formation Peedee Formation Black Creek Formation "Tuscaloosa" Formation Post-Miocene deposits Yorktown aquifer Upper aquifer Castle Hayne aquifer Limestone aquifer Beaufort aquifer Cretaceous aquifer Lower aquifer 22 The complex interlaying of the sediments underlying the Coastal Plain is shown in the following cross section. It will also be observed from the cross section that the rock layers (and formations) underlying the Coastal Plain dip toward the coast at a rate of about 15 ft./mi. As a result, each formation occurs at a greater depth below land surface toward the coast. Saprehti and Tirraci dipotiti 0 10 20 30 KILOMETERS Vertical exaggeration X 66 23 Ground-Water Situation in the Coastal Plain T,.-T-~^*:-^t RKTOWN DEPOSITS •>*>:Lj ^^^^^-•--^^^^rr; YORK TOWN -.AQUIFER -'^^^r^jl^f^m S X S±r L.N ' .' ' . ' i . 'CASTLE HAYNE^ AQUIFER ~=-^r Sand —JT Clay Shells Limestone Recharge of the ground-water system in the Coastal Plain occurs in the "upland" areas above the flood plains of perennial streams. Water reaching the saturated zone moves downward and laterally through the system to discharge areas. Ground-water discharge occurs by seepage through the bottoms and sides of streams and drainage ditches and also through evaporation from the top of the capillary fringe in flood plains and other areas in which the water table is within several feet of the land surface During the growing season, ground water is also used by plants whose roots reach the capillary fringe or saturated zone. In the area adjacent to the coast, ground'water also discharges by seepage into the sides and bottoms of estuaries and the ocean. The presence of clay layers in the Coastal Plain formations hampers recharge to the deeper aquifers, so that most of the recharge tends to move laterally to discharge areas through the shallowest aquifers. Recharge to the deepest aquifers occurs only in the central part of the interstream recharge areas. This is an important point relative to waste disposal, in that if pollution of the deeper aquifers is to be avoided, waste disposal sites should be located as close as possible to perennial streams. Prior to the construction of drainage ditches into the central part of the interstream areas, the water table reached the land surface in these areas during the fall, winter, and early spring recharge season. As a result, water was ponded on the surface for periods of several months each year in high-level swamps referred to as pocos/ns. Two regional aspects of the Coastal Plain are of primary importance from the standpoint of ground-water occurrence and availability. The first is the nature of the surficial materials, which controls the recharge to the ground- water system. The second is the geologic con- ditions that control the occurrence of aquifers and confining beds. 24 The materials forming the surface of the Coastal Plain can usefully be divided into sandy and clayey soils on the basis of their effect on ground-water recharge. Recharge in the areas underlain by sandy soils is much more effective than in the areas underlain by clayey soils. One of the consequences of this is a much larger sustained base flow of streams in these areas. The geologic conditions in the area of about 25,000 mi2 occupied by the Coastal Plain differ significantly from one part of the region to another. These differences affect both the occurrence and the availability of ground water. As an aid to understanding the Coastal Plain ground-water system, it is useful to divide the region into four hydrologic areas. Information on these is summarized in the following table in which the areas are listed in order from the simpliest to the most complex. Hydrologic area Geohydrologic characteristics Yield of the most productive w«Hs (gal/mln) Remarks Sand Hilts Outer Banks Castle Hayne Limestone Central Coastal Plain Productive water-bearing sand at the land surface and over- lying, for the most part, much less-productive material. Productive water-bearing sand at the land surface containing fresh water in contact with sea water. Productive limestone overlain and underlain by less-productive sand interbedded with clay. Numerous thin layers of water- bearing sand complexly interbedded with clay. 50-250 25-100 more than 1000 250-1000 Water obtained from both bored wells and from screened drilled and driven wells. Water only slightly mineralized. Water obtained from both shallow, vertical, screened wells, and from horizontal collectors. Fresh-water zone subject to salt-water encroach- ment both from above and below. Drilled open-hole wells. Water moderately hard. Aquifer is confined and large withdrawals affect a large area. Sediments of Cretaceous age comprise most productive zones and is tapped by multiple-screened drilled wells. Water of excellent quality and, in places, naturally softened. Surficial sand aquifer also widely used for domestic supplies. SOILS HYOROLOGIC AREAS Sandy soils 25 Rock Units and Aquifers in the Piedmont and Mountains • ^^^^--M^'M^^^m. rt!tri GREAT SHOP MCTJNTAIM BELT iJj3 ME1ASKDIMENTAEY ROCKS (7771 CAROLIHA SLXp BELT lXj£J tlcxaVOI^AWICS __ n*rit-eiAj>it, CSubimlt) f=~j ARCILLITE(Subunlt) rasa TRIASSIC BASIHS o 10 20 >o «o so The rocks underlying the Piedmont and mountains can be divided into two groups: (1) bedrock, and (2) saprolite (or residuum). The saprolite underlies the land surface and ranges in thickness from a foot or two near bedrock outcrops to more than 100 ft. Bedrock underlies the saprolite and is the parent rock from which the saprolite was derived in the process referred to as weathering. Many stream valleys, especially those of larger streams, are underlain by a layer of material similar in composition to saprolite. This material, which has been deposited by the streams during floods, is correctly referred to as alluvium. However, to avoid unnecessary complications, we will lump the alluvium in with the saprolite for the purpose of this discussion. The bedrock underlying the Piedmont and mountains consists of many different types of igneous and metamorphosed igneous and sedimentary rocks. The Generalized Geologi- cal Map of North Carolina accompanying the discussion of WATER-BEARING ROCKS divides the bedrock in the Piedmont and mountains into six units. The 1:500,000 scale Geologic Map of North Carolina, published in 1958, divides the bedrock in the same area into 48 different units. But, a much larger number of units have been identified and are shown on large scale geologic maps. The bedrock units differ from each other in mineral composition and other geologic characteristics. Fortunately, these differences do not result in large differences in hydraulic characteristics so that it is possible to combine the bedrock units into a relatively small number of hydrogeologic units. The accompanying map shows the hydro- geologic units into which the bedrock in the Piedmont and mountains has been divided by the U.S. Geological Survey and the North Carolina Groundwater Section. The most productive hydrogeologic units are the Great Smoky Mountain belt and the Blue Ridge-Inner Piedmont belt. The least productive units are the Carolina Slate Belt and the Triassic Basins. The Charlotte Belt is intermediate in productivity. 26 Ground-Water Situation in the Piedmont and Mountains The saprolite (weathered rock) that forms the land surface in the Piedmont and mountains consists of unconsolidated granu- lar material. It thus contains water in the pore spaces between rock particles. The bedrock, on the other hand, does not have any significant intergranular (primary) porosity. It contains water, instead, in sheet- like openings formed along fractures (that is, breaks in the otherwise "solid" rock). Fractures in bedrock are of two types: (1) joints, which are breaks along which there has been no differential movement; and (2) faults, which are breaks along which the adjacent rocks have undergone differential movement. Faults are formed during earthquakes and generally contain larger and more extensive openings than those developed along joints. Joints, however, are far more numerous than faults. Fractures (joints and faults) are more abundant under valleys, draws, and other surface depressions than under hills. In fact, geologists assume that it is the presence of fractures that determined the position of valleys in the first place. Fractures tend to be more closely-spaced and the openings developed along them tend to be larger near the surface of the bedrock. Most fractures appear to be non water-bearing below a depth of 300 to 400 ft. Large water-bearing openings, penetrated below this depth are probably associated with faults. The ground-water system in the Piedmont and mountains is recharged by precipitation on the interstream areas. A part of the precipitation infiltrates through the unsatu- rated zone to the water table, which normally occurs in the saprolite. Ground water moves laterally and downward through the saprolite to points of ground- water seepage (springs) on the hillsides and to the streams in the adjacent valleys. Some of the water in the saprolite also moves downward into the bedrock and, thereafter, through the fractures to the adjacent valleys. 27 Hydraulic Characteristics of the Piedmont and Mountain Ground-Water System STORAGE IN SAPROLITE STORAGE IN BEDROCK =H One of the most basic concepts of ground- water hydrology is that aquifers function both as reservoirs, in which water is in storage, and as pipelines, which transmit water from one point to another. This is referred to as the reservoir-pipeline concept This concept forms a useful basis on which to discuss the hydraulic characteristics of the Piedmont and mountain ground-water system. The reservoir (storage) function of aquifers depends on the porosity. The pipeline function depends on the hydraulic conductivity and the thickness of the aquifer. The approximate range in porosity and hydraulic conductivity for the saprolite and bedrock is shown in the following table. Rock type Porosity in percent Saprolite 20-30 Bedrock 0.1-1 Hydraulic conductivity In feet per day 1-20 1-20 The above values suggest that the principal difference between saprolite and bedrock is in water-storage capacity. In other words, the saprolite has the capacity to store a much larger quantity of water than does the bedrock. This is not the entire story, however. As we noted above, the capacity of an aquifer to transmit water depends both on hydraulic conductivity and on aquifer thickness. The part of the bedrock containing water-bearing fractures is several times thicker than the saprolite. 28 We can then, without great error, view the ground-water system in the Piedmont and mountains as consisting of a saprolite reser- voir overlying a bedrock pipeline consisting of numerous small, intercorin~ected~pipes. In the vicinity of a pumping well the bedrock fractures ("pipes") convey water from the saprolite reservoir to the well. The yield of a well drawing from fractured bedrock depends on several factors. The most important of these are believed to be: 1. The number, size, areal extent, and degree of interconnection of the fractures penetrated by the well, 2. The thickness of saturated saprolite in the vicinity of the well and the specific yield of the saprolite, and 3. The hydraulic conductivity of the sapro- lite and the nature of the hydraulic con- nection between the saprolite and the bedrock. The number and the size of the fractures control the rate at which water can enter the well. The areal extent and degree of intercon- nection of the fractures control the size of the area that supplies water to the well. The thickness and the specific yield of the saprolite determines the volume of water available from storage in the saprolite. The hydraulic conductivity of the saprolite and the nature of the hydraulic connection between the saprolite and the bedrock determines the rate at which water can drain from the saprolite into the bedrock fractures. 29 Selecting Well Sites in the Piedmont and Mountains Rock outcrop 5 Number related to topographic position (3) Number related to saprolite thickness Most ground-water supplies in the Piedmont and mountains are obtained from wells that are cased through the saprolite and finished with open holes in the bedrock. The yield of these wells depends on the number and size of the fractures they penetrate. Therefore, where moderate to large supplies of water are needed, well sites should be selected at the places where fractures appear to be most abundant. H. E. LeGrand, of the U.S. Geological Survey, attempted in 1967 to indicate the relative favorability of well sites in the Piedmont and mountains by assigning point values to areas on the basis of saprolite thick- ness and topographic position. The point values assigned by LeGrand to features of the land surface that suggest thickness of saprolite and to different topographic positions are shown below. Selected values of each are also indicated on the above sketch. 30 Features of land surface Point related to saprolite thickness value Bare rock-almost no soil 0-2 Some rock outcrops-very thin soil 2-6 A few rock outcrops-thin soil 6-9 No fresh outcrops-moderately thick soil 9-12 No rock outcrops-thick soil 12-15 Topographic position Steep ridge top Upland steep slope Rounded upland Midpoint of ridge slope Gentle upland slope Broad flat upland Lower part of upland slope Valley bottom of flood plain Draw with small catchment Draw with large catchment Point vaiue 0 2 4 5 7 8 9 12 15 18 The point values for saprolite thickness and topographic position are added and the total is used in conjunction with the following table to estimate the chance of obtaining different yields. (The following table is an abbreviated and slightly modified version of the table prepared by LeGrand.) Total points assigned to a site 5 10 15 20 25 30 Average yield (gal/min) 3 6 15 25 40 60 3 gal/min 50 65 80 90 93 96 Chance of success, 10 gal/min 20 40 55 70 80 90 In percent, for a well to yield at 25 gai/min 5 15 30 50 65 75 50 gal/min 3 15 15 25 45 55 least— 75 gal/min __•» — — 20 35 45 Most of the wells used in LeGrand's analysis were drilled to obtain water for domestic needs at the sites most convenient to the well owners. Thus, no special attempt was made to select the most favorable sites. We know that the chances of success can be greatly improved if wells are not only located in valleys but also at places where the topography suggests the presence of intersecting fractures. In fact, recent studies suggest that where best tech- nology is applied in the selection of well sites, an average yield of 150 gal/min can be expected. Reference: LeGrand, H. E., 1967, Ground water of the Piedmont and Blue Ridge Provinces in the Southeastern States: U.S. Geological Survey Circular 538. 31 REFERENCE 23 REFERENCE 24 Soil Map—Mecklenburg County, North Carolina (Peoples Cleaners) Natural Resources Conservation Service Web Soil Survey National Cooperative Soil Survey 3/16/2023 Page 1 of 339018203901900390198039020603902140390222039023003901820390190039019803902060390214039022203902300512860512940513020513100513180513260513340513420513500513580 512860 512940 513020 513100 513180 513260 513340 513420 513500 513580 35° 15' 49'' N 80° 51' 31'' W35° 15' 49'' N80° 51' 1'' W35° 15' 33'' N 80° 51' 31'' W35° 15' 33'' N 80° 51' 1'' WN Map projection: Web Mercator Corner coordinates: WGS84 Edge tics: UTM Zone 17N WGS84 0 150 300 600 900Feet 0 50 100 200 300Meters Map Scale: 1:3,480 if printed on A landscape (11" x 8.5") sheet. Soil Map may not be valid at this scale. SITE MAP LEGEND MAP INFORMATION Area of Interest (AOI) Area of Interest (AOI) Soils Soil Map Unit Polygons Soil Map Unit Lines Soil Map Unit Points Special Point Features Blowout Borrow Pit Clay Spot Closed Depression Gravel Pit Gravelly Spot Landfill Lava Flow Marsh or swamp Mine or Quarry Miscellaneous Water Perennial Water Rock Outcrop Saline Spot Sandy Spot Severely Eroded Spot Sinkhole Slide or Slip Sodic Spot Spoil Area Stony Spot Very Stony Spot Wet Spot Other Special Line Features Water Features Streams and Canals Transportation Rails Interstate Highways US Routes Major Roads Local Roads Background Aerial Photography The soil surveys that comprise your AOI were mapped at 1:24,000. Warning: Soil Map may not be valid at this scale. Enlargement of maps beyond the scale of mapping can cause misunderstanding of the detail of mapping and accuracy of soil line placement. The maps do not show the small areas of contrasting soils that could have been shown at a more detailed scale. Please rely on the bar scale on each map sheet for map measurements. Source of Map: Natural Resources Conservation Service Web Soil Survey URL: Coordinate System: Web Mercator (EPSG:3857) Maps from the Web Soil Survey are based on the Web Mercator projection, which preserves direction and shape but distorts distance and area. A projection that preserves area, such as the Albers equal-area conic projection, should be used if more accurate calculations of distance or area are required. This product is generated from the USDA-NRCS certified data as of the version date(s) listed below. Soil Survey Area: Mecklenburg County, North Carolina Survey Area Data: Version 22, Sep 12, 2022 Soil map units are labeled (as space allows) for map scales 1:50,000 or larger. Date(s) aerial images were photographed: Mar 13, 2022—May 9, 2022 The orthophoto or other base map on which the soil lines were compiled and digitized probably differs from the background imagery displayed on these maps. As a result, some minor shifting of map unit boundaries may be evident. Soil Map—Mecklenburg County, North Carolina (Peoples Cleaners) Natural Resources Conservation Service Web Soil Survey National Cooperative Soil Survey 3/16/2023 Page 2 of 3 Map Unit Legend Map Unit Symbol Map Unit Name Acres in AOI Percent of AOI CeD2 Cecil sandy clay loam, 8 to 15 percent slopes, moderately eroded 7.3 13.6% CuB Cecil-Urban land complex, 2 to 8 percent slopes 44.1 82.0% Ur Urban land 2.3 4.3% Totals for Area of Interest 53.7 100.0% Soil Map—Mecklenburg County, North Carolina Peoples Cleaners Natural Resources Conservation Service Web Soil Survey National Cooperative Soil Survey 3/16/2023 Page 3 of 3 REFERENCE 25 REFERENCE 26 SITE SITE SITE SITE SITE SITE REFERENCE 27 [Ú [Ú [Ú [Ú ") ") $1 $1 $1 $1 $1 $1 $1 $1 $1 $1 $1 $1 $1 !( !( §¨¦ §¨¦ §¨¦ §¨¦§¨¦ ") ") ") !( !( #* !( ") ") #* #* #* #* #* #* Vest WTP820 Beatties Ford Rd. Franklin WTP5200 Brookshire Blvd. Mt. Island Main Water Intake12548 Pump Station Rd. Lake Norman Water Intake7420 Oliver Hager Rd. Lee S. Dukes WTP7980 Babe Stillwell Rd. Field Crews / Zone 25730 General Commerce Dr. Customer Service & Engineering5100 Brookshire Blvd. Environmental Services Facility & Administration4222 Westmont Dr. LANCASTER CO., SC YORK CO., SC GASTON CO. LINCOLN CO. IREDELL CO. CABARRUS CO. UNION CO. Field Crews / Zone 111609 Horde Dr Field Crews / Zone 44100 West Tyvola Road Field Crews / Zone 312131 Park Rd Installation and Development Services 600 East Trade Street (basement level) Mallard Creek WWTP12400 Hwy 29 North McDowell Creek WWTP4901 Neck Rd. McAlpine Creek WWTP12701 Lancaster Hwy. Sugar Creek WWTP5301 Closeburn Rd. Irwin Creek WWTP4000 Westmont Dr. Oxford Glen Ashe PlantationS Tryon StPark RdStatesville RdN Tryon StSouth BvRea RdProvi dence RdAlbemarle Rd Idlewild Rd W e s t B v Mo nroe R d Wilkinson Bv Brookshire Bv E W T H arris B v E Independence Bv T h e P la za La wyers R d Carmel RdSteele Creek RdCol ony RdCentral Av W W T Harris BvMt Holly-Huntersville RdSharon RdBrief RdSam Furr Rd Sardis Rd Blair RdN Graham StPineville-M atthew s RdB eatties Ford R d Lancaster HyMccoy RdRidge Rd Ar d re y K e ll R d Elm L n N C 73 Hy Johnst on RdMallard Creek RdM ckee RdEastfield RdS un s et Rd Eastway DrOakdale RdU n iversity C ity B vRandolph Rd E 7th StGrey RdHambright Rd Westinghouse Bv N Sharon Amity RdHarrisburg RdMatthews-Mint Hill RdMarvin Rd York Rd Fairview Rd Cabarrus RdHood RdShamrock DrReames RdW Arrowood Rd Plaza Rd Ext E John St East Bv Selwyn AvLittle Rock RdLebanon RdOld Plank Rd Plott RdYorkmont Rd Sh ear er RdPence Rd Gibbon Rd N Davidson StSam Newell RdRama RdDixie River RdE 4th St B ellhav en B v Old Statesville RdChoate Cr Bro w ne R d W e st C a ta w b a A v Tom Short RdHucks Rd Wed di ngt on RdCaldwell RdQueen City Dr Pavili on BvMiranda Rd Hamilton Rd David Cox Rd Remount Rd Craig Av Sledge Rd Moss RdP a rkton R d IBM Dr Barringer DrMarsh Rd Raintree Ln E 36th St Main St Alexander Rd S Trade StZ o a r R d Colville RdSharon LnScaleybark Rd Mclean Rd E Westinghouse Bv N Main StCar owi nds BvQ u ail H ollo w R dEuclid AvKil bor ne Dr S a rd is L nQueens Rd WestW Craighead Rd Rocky River Church RdS Wendover RdEngland StWestmore land Rd High Ridge RdN Old Statesville RdLansdowne RdV e rh oe ff D rJohn Kirk DrBoyce RdBriar Creek RdPerformance Rd McAlway Rd77 77 85 485 85 September 26, 2017­ !(Raw Water Intakes !(Water Treatment Plants $1 Water Tanks & Storage [Ú Water Booster Pump Stations ")Wastewater Treatment Plants #*Field Crew Zone Offices Field Crew ZonesCharlotteCorneliusDavidsonHuntersvilleMatthewsMint HillPineville #*CLTWater Office Locations REFERENCE 28 REFERENCE 29 Output generated 23JAN2023:12:39:29 Commercial Air Inputs 1 Variable Commercial Air Default Value Site-Specific Value AFgw (Attenuation Factor Groundwater) unitless 0.001 0.001 AFss (Attenuation Factor Sub-Slab) unitless 0.03 0.03 ATw (averaging time - composite worker)365 365 EDw (exposure duration - composite worker) yr 25 25 EFw (exposure frequency - composite worker) day/yr 250 250 ETw (exposure time - composite worker) hr 8 8 THQ (target hazard quotient) unitless 0.1 0.1 LT (lifetime) yr 70 70 TR (target risk) unitless 1.0E-06 1.0E-04 Output generated 23JAN2023:12:39:29 Commercial Vapor Intrusion Screening Levels (VISL)2 Key: I = IRIS; P = PPRTV; O = OPP; A = ATSDR; C = Cal EPA; X = PPRTV Screening Level; H = HEAST; D = DWSHA; W = TEF applied; E = RPF applied; U = user provided; G = see RSL User's Guide Section 5; CA = cancer; NC = noncancer. Chemical CAS Number Does the chemical meet the definition for volatility? (HLC>1E-5 or VP>1) Does the chemical have inhalation toxicity data? (IUR and/or RfC) Is Chemical Sufficiently Volatile and Toxic to Pose Inhalation Risk Via Vapor Intrusion from Soil Source? (Cvp > Ci,a,Target?) Is Chemical Sufficiently Volatile and Toxic to Pose Inhalation Risk Via Vapor Intrusion from Groundwater Source? (Chc > Ci,a,Target?) Target Indoor Air Concentration (TCR=0.0001 or THQ=0.1) MIN(Cia,c,Cia,nc) (µg/m3) Toxicity Basis Target Sub-Slab and Near-source Soil Gas Concentration (TCR=0.0001 or THQ=0.1) Csg,Target (µg/m3) Target Groundwater Concentration (TCR=0.0001 or THQ=0.1) Cgw,Target (µg/L) Tetrachloroethylene 127-18-4 Yes Yes Yes Yes 1.75E+01 NC 5.84E+02 2.42E+01 Trichloroethylene 79-01-6 Yes Yes Yes Yes 8.76E-01 NC 2.92E+01 2.18E+00 Is Target Groundwater Concentration < MCL? (Cgw < MCL?) Pure Phase Vapor Concentration Cvp\ (25 ℃)\ (µg/m3) Maximum Groundwater Vapor Concentration Chc\ (µg/m3) Temperature for Maximum Groundwater Vapor Concentration (℃) Lower Explosive Limit LEL (% by volume) LEL Ref IUR (ug/m 3)-1 IUR Ref RfC (mg/m3) RfC Ref Mutagenic Indicator Carcinogenic VISL TCR=0.0001 Cia,c(µg/m3) Noncarcinogenic VISL THQ=0.1 Cia,nc(µg/m3) No (5)1.65E+08 1.49E+08 25 -2.60E-07 I 4.00E-02 I No 4.72E+03 1.75E+01 Yes (5)4.88E+08 5.15E+08 25 8.00 CRC 4.10E-06 I 2.00E-03 I Mut 2.99E+02 8.76E-01 Output generated 23JAN2023:12:39:29 Commercial Vapor Intrusion Risk 3 Chemical CAS Number Site Groundwater Concentration Cgw\ (µg/L) Site Indoor Air Concentration Ci,a\ (µg/m3) VI Carcinogenic Risk CDI (µg/m3) VI Carcinogenic Risk CR VI Hazard CDI (mg/m3) VI Hazard HQ IUR (ug/m3)-1 Tetrachloroethylene 127-18-4 1600 1.16E+03 9.44E+01 2.45E-05 2.64E-01 6.61E+00 2.60E-07 Trichloroethylene 79-01-6 12 4.83E+00 3.94E-01 1.62E-06 1.10E-03 5.52E-01 4.10E-06 *Sum ---2.62E-05 -7.16E+00 - IUR Ref Chronic RfC (mg/m3) RfC Ref Temperature (℃)\ for Groundwater Vapor Concentration Mutagen? I 4.00E-02 IRIS 25 No I 2.00E-03 IRIS 25 Mut -- Output generated 23JAN2023:12:39:29 Chemical Properties 4 Chemical CAS Number Does the chemical meet the definition for volatility? (HLC>1E-5 or VP>1) Does the chemical have inhalation toxicity data? (IUR and/or RfC)MW MW Ref Vapor Pressure VP (mm Hg) VP Ref S (mg/L) S Ref MCL (ug/L) Tetrachloroethylene 127-18-4 Yes Yes 165.83 PHYSPROP 1.85E+01 PHYSPROP 2.06E+02 PHYSPROP 5 Trichloroethylene 79-01-6 Yes Yes 131.39 PHYSPROP 6.90E+01 PHYSPROP 1.28E+03 PHYSPROP 5 HLC (atm-m 3/mole) Henry's Law Constant (unitless) H` and HLC Ref Henry's Law Constant Used in Calcs (unitless) Normal Boiling Point BP (K) BP Ref Critical Temperature TC\ (K) TC\ Ref Enthalpy of vaporization at the normal boiling point ΔHv,b\ (cal/mol) ΔHv,b\ Ref Lower Explosive Limit LEL (% by volume) LEL Ref 1.77E-02 7.24E-01 PHYSPROP 7.24E-01 394.45 PHYSPROP 6.20E+02 YAWS 8288.72 CRC - 9.85E-03 4.03E-01 PHYSPROP 4.03E-01 360.35 PHYSPROP 5.71E+02 YAWS 7504.78 CRC 8.00 CRC Output generated 08JUN2023:16:53:33 Resident Air Inputs 1 Variable Resident Air Default Value Site-Specific Value AFgw (Attenuation Factor Groundwater) unitless 0.001 0.001 AFss (Attenuation Factor Sub-Slab) unitless 0.03 0.03 EDres (exposure duration) years 26 26 ED0-2 (mutagenic exposure duration first phase) years 2 2 ED2-6 (mutagenic exposure duration second phase) years 4 4 ED6-16 (mutagenic exposure duration third phase) years 10 10 ED16-26 (mutagenic exposure duration fourth phase) years 10 10 EFres (exposure frequency) days/year 350 350 EF0-2 (mutagenic exposure frequency first phase) days/year 350 350 EF2-6 (mutagenic exposure frequency second phase) days/year 350 350 EF6-16 (mutagenic exposure frequency third phase) days/year 350 350 EF16-26 (mutagenic exposure frequency fourth phase) days/year 350 350 ETres (exposure time) hours/day 24 24 ET0-2 (mutagenic exposure time first phase) hours/day 24 24 ET2-6 (mutagenic exposure time second phase) hours/day 24 24 ET6-16 (mutagenic exposure time third phase) hours/day 24 24 ET16-26 (mutagenic exposure time fourth phase) hours/day 24 24 THQ (target hazard quotient) unitless 0.1 0.1 LT (lifetime) years 70 70 TR (target risk) unitless 1.0E-06 1.0E-06 Output generated 08JUN2023:16:53:33 Resident Vapor Intrusion Screening Levels (VISL)2 Key: I = IRIS; P = PPRTV; O = OPP; A = ATSDR; C = Cal EPA; X = PPRTV Screening Level; H = HEAST; D = DWSHA; W = TEF applied; E = RPF applied; U = user provided; G = see RSL User's Guide Section 5; CA = cancer; NC = noncancer. Chemical CAS Number Does the chemical meet the definition for volatility? (HLC>1E-5 or VP>1) Does the chemical have inhalation toxicity data? (IUR and/or RfC) Is Chemical Sufficiently Volatile and Toxic to Pose Inhalation Risk Via Vapor Intrusion from Soil Source? (Cvp > Ci,a,Target?) Is Chemical Sufficiently Volatile and Toxic to Pose Inhalation Risk Via Vapor Intrusion from Groundwater Source? (Chc > Ci,a,Target?) Target Indoor Air Concentration (TCR=1E-06 or THQ=0.1) MIN(Cia,c,Cia,nc) (µg/m3) Toxicity Basis Target Sub-Slab and Near-source Soil Gas Concentration (TCR=1E-06 or THQ=0.1) Csg,Target (µg/m3) Target Groundwater Concentration (TCR=1E-06 or THQ=0.1) Cgw,Target (µg/L) Tetrachloroethylene 127-18-4 Yes Yes Yes Yes 4.17E+00 NC 1.39E+02 5.76E+00 Vinyl Chloride 75-01-4 Yes Yes Yes Yes 1.68E-01 CA 5.59E+00 1.47E-01 Is Target Groundwater Concentration < MCL? (Cgw < MCL?) Pure Phase Vapor Concentration Cvp\ (25 ℃)\ (µg/m3) Maximum Groundwater Vapor Concentration Chc\ (µg/m3) Temperature for Maximum Groundwater Vapor Concentration (℃) Lower Explosive Limit LEL (% by volume) LEL Ref IUR (ug/m 3)-1 IUR Ref RfC (mg/m3) RfC Ref Mutagenic Indicator Carcinogenic VISL TCR=1E-06 Cia,c(µg/m3) Noncarcinogenic VISL THQ=0.1 Cia,nc(µg/m3) No (5)1.65E+08 1.49E+08 25 -2.60E-07 I 4.00E-02 I No 1.08E+01 4.17E+00 Yes (2)1.00E+10 1.00E+10 25 3.60 CRC 4.40E-06 I 1.00E-01 I Mut 1.68E-01 1.04E+01 Output generated 08JUN2023:16:53:33 Resident Vapor Intrusion Risk 3 Chemical CAS Number Site Sub-Slab and Exterior Soil Gas Concentration Csg\ (µg/m3) Site Indoor Air Concentration Ci,a\ (µg/m3) VI Carcinogenic Risk CDI (µg/m3) VI Carcinogenic Risk CR VI Hazard CDI (mg/m3) VI Hazard HQ IUR (ug/m 3)-1 IUR Ref Tetrachloroethylene 127-18-4 105 3.15E+00 1.12E+00 2.92E-07 3.02E-03 7.55E-02 2.60E-07 I Vinyl Chloride 75-01-4 3.6 1.08E-01 1.46E-01 6.44E-07 1.04E-04 1.04E-03 4.40E-06 I *Sum ---9.36E-07 -7.65E-02 - Chronic RfC (mg/m 3) RfC Ref Temperature (℃)\ for Groundwater Vapor Concentration Mutagen? 4.00E-02 IRIS 25 No 1.00E-01 IRIS 25 Mut -- Output generated 08JUN2023:16:53:33 Chemical Properties 4 Chemical CAS Number Does the chemical meet the definition for volatility? (HLC>1E-5 or VP>1) Does the chemical have inhalation toxicity data? (IUR and/or RfC)MW MW Ref Vapor Pressure VP (mm Hg) VP Ref S (mg/L) S Ref MCL (ug/L) Tetrachloroethylene 127-18-4 Yes Yes 165.83 PHYSPROP 1.85E+01 PHYSPROP 2.06E+02 PHYSPROP 5 Vinyl Chloride 75-01-4 Yes Yes 62.50 PHYSPROP 2.98E+03 EPI 8.80E+03 PHYSPROP 2 HLC (atm-m 3/mole) Henry's Law Constant (unitless) H` and HLC Ref Henry's Law Constant Used in Calcs (unitless) Normal Boiling Point BP (K) BP Ref Critical Temperature TC\ (K) TC\ Ref Enthalpy of vaporization at the normal boiling point ΔHv,b\ (cal/mol) ΔHv,b\ Ref Lower Explosive Limit LEL (% by volume) LEL Ref 1.77E-02 7.24E-01 PHYSPROP 7.24E-01 394.45 PHYSPROP 6.20E+02 YAWS 8288.72 CRC - 2.78E-02 1.14E+00 PHYSPROP 1.14E+00 259.85 PHYSPROP 4.25E+02 CRC 4971.32 CRC 3.60 CRC Output generated 08JUN2023:16:59:03 Commercial Air Inputs 1 Variable Commercial Air Default Value Site-Specific Value AFgw (Attenuation Factor Groundwater) unitless 0.001 0.001 AFss (Attenuation Factor Sub-Slab) unitless 0.03 0.03 ATcom (averaging time - composite worker)365 365 EDcom (exposure duration - composite worker) yr 25 25 EFcom (exposure frequency - composite worker) day/yr 250 250 ETcom (exposure time - composite worker) hr 8 8 THQ (target hazard quotient) unitless 0.1 0.1 LT (lifetime) yr 70 70 TR (target risk) unitless 1.0E-06 1.0E-06 Output generated 08JUN2023:16:59:03 Commercial Vapor Intrusion Screening Levels (VISL)2 Key: I = IRIS; P = PPRTV; O = OPP; A = ATSDR; C = Cal EPA; X = PPRTV Screening Level; H = HEAST; D = DWSHA; W = TEF applied; E = RPF applied; U = user provided; G = see RSL User's Guide Section 5; CA = cancer; NC = noncancer. Chemical CAS Number Does the chemical meet the definition for volatility? (HLC>1E-5 or VP>1) Does the chemical have inhalation toxicity data? (IUR and/or RfC) Is Chemical Sufficiently Volatile and Toxic to Pose Inhalation Risk Via Vapor Intrusion from Soil Source? (Cvp > Ci,a,Target?) Is Chemical Sufficiently Volatile and Toxic to Pose Inhalation Risk Via Vapor Intrusion from Groundwater Source? (Chc > Ci,a,Target?) Target Indoor Air Concentration (TCR=1E-06 or THQ=0.1) MIN(Cia,c,Cia,nc) (µg/m3) Toxicity Basis Target Sub-Slab and Near-source Soil Gas Concentration (TCR=1E-06 or THQ=0.1) Csg,Target (µg/m3) Target Groundwater Concentration (TCR=1E-06 or THQ=0.1) Cgw ,Target (µg/L) Is Target Groundwater Concentration < MCL? (Cgw < MCL?) Chloroform 67-66-3 Yes Yes Yes Yes 5.33E-01 CA 1.78E+01 3.55E+00 Yes (80) Toluene 108-88-3 Yes Yes Yes Yes 2.19E+03 NC 7.30E+04 8.07E+03 No (1000) Pure Phase Vapor Concentration Cvp\ (25 ℃)\ (µg/m3) Maximum Groundwater Vapor Concentration Chc\ (µg/m3) Temperature for Maximum Groundwater Vapor Concentration (℃) Lower Explosive Limit LEL (% by volume) LEL Ref IUR (ug/m 3)-1 IUR Ref RfC (mg/m3) RfC Ref Mutagenic Indicator Carcinogenic VISL TCR=1E-06 Cia,c(µg/m3) Noncarcinogenic VISL THQ=0.1 Cia,nc(µg/m3) 1.26E+09 1.19E+09 25 -2.30E-05 U 9.77E-02 U No 5.33E-01 4.28E+01 1.41E+08 1.43E+08 25 1.10 U -5.00E+00 U No -2.19E+03 Output generated 08JUN2023:16:59:03 Commercial Vapor Intrusion Risk 3 Chemical CAS Number Site Sub-Slab and Exterior Soil Gas Concentration Csg\ (µg/m3) Site Indoor Air Concentration Ci,a\ (µg/m3) VI Carcinogenic Risk CDI (µg/m3) VI Carcinogenic Risk CR VI Hazard CDI (mg/m 3) VI Hazard HQ IUR (ug/m3)-1 IUR Ref Chronic RfC (mg/m3) RfC Ref Temperature (℃)\ for Groundwater Vapor Concentration Mutagen? Chloroform 67-66-3 7.68 2.30E-01 1.88E-02 4.32E-07 5.26E-05 5.38E-04 2.30E-05 U 9.77E-02 U 25 No Toluene 108-88-3 30.5 9.15E-01 7.46E-02 -2.09E-04 4.18E-05 -5.00E+00 U 25 No *Sum ---4.32E-07 -5.80E-04 --- Output generated 08JUN2023:16:59:03 Chemical Properties 4 Chemical CAS Number Does the chemical meet the definition for volatility? (HLC>1E-5 or VP>1) Does the chemical have inhalation toxicity data? (IUR and/or RfC)MW MW Ref Vapor Pressure VP (mm Hg) VP Ref S (mg/L) S Ref MCL (ug/L) HLC (atm-m 3/mole) Henry's Law Constant (unitless) H` and HLC Ref Chloroform 67-66-3 Yes Yes 119.38 U 1.97E+02 U 7.95E+03 U 80 3.67E-03 1.50E-01 U Toluene 108-88-3 Yes Yes 92.14 U 2.84E+01 U 5.26E+02 U 1000 6.64E-03 2.71E-01 U Henry's Law Constant Used in Calcs (unitless) Normal Boiling Point BP (K) BP Ref Critical Temperature TC\ (K) TC\ Ref Enthalpy of vaporization at the normal boiling point ΔHv,b\ (cal/mol) ΔHv,b\ Ref Lower Explosive Limit LEL (% by volume) LEL Ref 1.50E-01 334.25 U 5.36E+02 U 6990.00 U - 2.71E-01 384.15 U 5.92E+02 U 7930.00 U 1.10 U REFERENCE 30 SITE PPE 1 PPE 2 SITE PPE 1 PPE 2 REFERENCE 31 SITE Catawba River REFERENCE 32 Oakda l eRdMtHollyRd S out hP o i ntRdSunsetRd CharlotteDouglasInt'lAirport Mt Holly Belmont Sedgefield Hoskins Shuffletown Enderly Park SugarCreek274 Westinghouse B lv d ST r y o n StPleasantRdHandsMillHwyHighway21BypNPineville Lake Wylie Sharonbrook Starmount 801ft A l bemarleR d LawyersRdNGrahamStHarr isburgRdBlairRdO l dConcordRdR a n dolphR dR o c ky R iv e rRd MonroeRd CabarrusRd B riefR dBeattiesFordRd S a mB l a c k R dLowerRockyRiverRdHarrisburg NorthCharlotte Idlewild Grove Park Pine Ridge Mint Hill Charlotte ReaR d ReaRdPr o vi denceRdProvidenceRdMon r o e RdCarmelRdI dlewil dRd IdlewildRdSardi s RdW LawyersRd M cKe e R d NC-21 8 WPotterRdSelwyn Park Indian Trail Matthews 1930 Beatties Ford Rd, Charlotte, North Carolina, 28216 Natural Heritage Program Map Esri, NASA, NGA, USGS, City of Charlotte, NC, Esri, HERE, Garmin, SafeGraph, METI/NASA, USGS, EPA, NPS, USDA North Carolina Boundary Rivers Lakes Managed Areas Dedicated Nature Preserve Registered Heritage Area Conservation Easement Other Protection Federal Ownership State Ownership Local Government Ownership Private March 30, 2023 0 3 61.5 mi 0 5 102.5 km 1:233,524 REFERENCE 33 SITE PPE 1 PPE 2 REFERENCE 34 REFERENCE 35 NORTH CAROLINA DIVISION OF WASTE MANAGEMENT Dry Cleaning Solvent Cleanup Act (DSCA) Compliance Program Inspection Report Facility Identification Peoples Cleaners Facility ID: 600017C EPA Generator ID: NCD986188084 County/FIPS: Mecklenburg/119 DSCA Cleanup ID: DC600006 Facility Data Peoples Cleaners 1930 Beatties Ford Road Charlotte NC 28216 Lat: 35.261722 Long: -80.854583 SIC: 7216 / Dry Cleaning Plants, Except Rugs NAICS: 81232/ Dry Cleaning and Laundry Services (except Coin-Operated) Date of Facility Establishment: 1/1/1990 Compliance Data Inspection Date: 6/16/2023 Time In: 10:00 AM Time Out: 10:20 AM Inspector(s): Ne’Shonda Cobbs Operating Status: OO/Operating Compliance Codes: In Violation of MMP Action Code: 01/Inspection Contact Data Classification Data Service Type: Full Service (Closed) Solvent: System: N/A Installation Date: 2007 Installation Category: New Consumption Category: Small HW Generator Status: NA Facility Contact Quillie Smith 1930 Beatties Ford Rd. Charlotte, NC 28269 (704) 392-4092 Facility Owner Quillie Smith 1930 Beatties Ford Rd. Charlotte, NC 28269 (704) 392-4092 Property Owner Quillie Smith 1930 Beatties Ford Rd. Charlotte, NC 28269 (704) 392-4092 Inspector’s Signature: Date of Signature: 6/16/2023 Comments: Waste and equipment have been removed but the owner can’t provide details or records. (I) DIRECTIONS: From the Mooresville Regional Office at 610 East Center Avenue in Mooresville, go west on East Center Avenue. Turn left onto S. Main St. (NC-152). Turn right onto W. McClelland Ave. (NC-152). Turn left onto NC-150. Merge onto I-77 South. Merge onto I-85 S via Exit 13B toward Spartanburg and take the Beatties Ford Rd. exit- (Exit 37). Turn right onto Beatties Ford Rd and the dry-cleaning facility is located on the left at 1930 Beatties Ford Road. (II) FACILITY HISTORY: Peoples Cleaners has been operated by Mr. Quillie Smith, since approximately 1990. Peoples Cleaners was previously a bakery and fish market (1985-1990), and a filling station from the 1950’s to around 1985. PCE/TCE contamination has been discovered on this property, and the site (60-0006) has been deferred to the Inactive Hazardous Sites Branch. Mr. Smith explained that a fire had occurred at his store in March 2007. In 2012 the dry-cleaning operation became inactive and continued to function as a pick-up store. A site visit in June 2023 revealed that the machines had been removed at some point in 2022. Bennett's Ultra Cleaners clean garments on occasions that are dropped off at the facility. Solvent History: Solvent Dates Used Perchloroethylene 1990 to 2022 Previous Inspections: Date Visit Type Violation Type(s) Worst Violation(s) Action(s) Taken Response Due Received Date Inspector 6/8/2022 Inspection In Compliance N/A INF sent on 7/18/2022 8/8/2022 N/A or Not Rec'd Ne’Shonda Cobbs 1/6/2020 Inspection In Compliance N/A INF sent on 1/15/2020 2/5/2020 N/A or Not Rec'd Ne’Shonda Cobbs CHKLST sent on 1/6/2020 8/16/2018 Follow up Inspection In Compliance N/A CHKLST sent on 8/16/2018 None N/A or Not Rec'd Ne’Shonda Cobbs 1/11/2018 Inspection MMP Inadequate spill containment, No spill containment (15-gal waste drums) NOVNRE sent on 2/2/2018 2/23/2018 N/A or Not Rec'd Aram Kim CHKLST sent on 1/11/2018 3/10/2016 Inspection MMP No spill containment under four 15-gallon drums. NOV sent on 3/17/2016 4/8/2016 N/A or Not Rec'd Jack Kitchen CHKLST sent on 3/10/2016 3/5/2015 Inspection MMP No spill containment (specify) CHKLST sent on 3/6/2015 3/27/2015 N/A or Not Rec'd Jack Kitchen 8/22/2008 Inspection -- -- NOVNRE sent on 9/10/2008 9/24/2008 9/23/2008 Alicia Roh 3/13/2007 Outreach Training Visit -- -- CAL sent on 3/15/2007 4/2/2007 N/A or Not Rec'd Eric Swope Complaints: None DSCA Sampling: None (III) FACILITY CLASSIFICATION: Dry Cleaning Equipment Summary No Type of Machine Gen Manufacturer (Mfr) Model # Serial # Mfr Date Install Date End Date Solvent Used Observed Operating? 1 Dry-to- Dry 3rd RealStar RS-260 60-B2- 171 -- -- 1/1/2012 Perchloroethylene removed 2 Dry-to-Dry 3rd Aero-Tech USA 410 -- -- 1/1/2007 12/31/2022 Perchloroethylene removed (IV) INSPECTION SUMMARY: On June 16, 2023, Ne’Shonda Cobbs, compliance inspector, with the North Carolina Division of Waste Management, Dry Cleaning Solvent Cleanup Act (DSCA) program conducted a compliance inspection at Peoples Cleaners. The inspector met with Mr. Quillie Smith, facility owner, who provided the inspector with access to the facility's equipment and available records. The inspector arrived and found that Mr. Smith removed the dry-cleaning machine and possibly the waste as well. Mr. Smith stated that after he received the information letter in 2020, he decided to remove the machine and waste. The inspector was not clear on who completed the machine removal, nor if the waste remained onsite or not. Mr. Smith stated that he removed the machine himself and didn’t have a mechanic or company do the removal. The inspector believes the machine has been taken to a local scrap yard being that it had previously not been operated in years. Mr. Smith couldn’t provide any details as to the name of the facility in which he took the machine. When the inspector tried to gain access to the rear of the facility where the waste had previously been stored, Mr. Smith stated that he cleared out the entire area. He stated that he got rid of the drums along with the machine. When the inspector inquired on how he got rid of the waste, he stated that the company out of GA took it. The inspector assumed based on previous site records and MCF being the company in the area from GA, that they disposed of his waste. Mr. Smith didn’t have any records to verify the removal. The inspector contacted MCF directly and was informed that the last time they removed waste from the facility was in 2019. The inspector also checked with another major waste hauler in the area, and they had no records of a removal from the facility either. The owner is older and does not seem to understand fully or answer clearly when communicating. A CAL will be sent to the facility requesting the disposal information and the location of the machine’s dump site. The inspector was only able to see the area that previously contained the machine, so the assumption that the waste has been removed is based on the owner’s communication. The owner didn’t allow entry into the rear of the facility and the condition of the rear is also unsafe from appearance. The inspector will continue to reach out to the owner to verify how the waste was removed, if at all. ***************See attached photos************ (V) CONCLUSIONS: Based on observations documented by the DSCA Inspector during the June 16, 2023, inspection, Peoples Cleaners is currently in violation of the following regulations: MMPs - 15A NCAC 02S.0202 (b)(1) Failure to maintain complete and current invoices for waste disposal [15A NCAC 02S.0202(b)(1)]. Waste manifests are required to be kept on site for three years and available for review. NESHAP - 40 CFR Part 63 Subpart M NOTE: The Mecklenburg County Air Quality Program retains the authority to determine the facility's NESHAP compliance status. None RCRA- Hazardous Waste Regulations: 40 CFR Part 261 - 262 None (VI) ENFORCEMENT HISTORY (Penalties): None (VII) PHOTOGRAPHS: Picture 1: Store front of People’s Cleaners. Picture 2: Area that previously contained dry-cleaning machine. To: Quillie Smith, Owner Peoples Cleaners (600017C) 1930 Beatties Ford Road Charlotte, NC 28216 From: Ne’Shonda Cobbs, Compliance Inspector North Carolina Department of Environmental Quality (NCDEQ) Division of Waste Management (DWM) Dry-Cleaning Solvent Cleanup Act (DSCA) Program Date: June 22, 2023 On June 16, 2023, a compliance inspection was conducted at your facility. At that time, the inspector observed that the waste and dry-cleaning equipment that had previously been onsite had been removed. The inspector attempted to confirm the waste hauler that removed your waste; however, the company name you provided stated that they did not remove the waste onsite. Please be reminded that maintaining the records for the waste removal is a requirement. Please provide the records to show the manifest of the removal of the waste drums from your facility. Also, even though solvent and/or equipment is no longer onsite, the records are to remain onsite for 5 years per DSCA requirements. Please note that the EPA also requires that they remain onsite for at least 3 years. If you could please include the disposal location of the dry-cleaning equipment as well. At no time shall any dry-cleaning solvent, wastes containing dry-cleaning solvent, or water containing dry-cleaning solvent be discharged onto land or into waters of the State, sanitary sewers, storm drains, floor drains, septic systems, boilers, or cooling-towers. Please submit a written response to the address below by July 13, 2023, with the requested information. Division of Waste Management DSCA Compliance Program – Attn: Delonda Alexander 1646 Mail Service Center Raleigh, NC 27699-1646 Peoples Cleaners June 21, 2023 Page 2 of 2 We appreciate your immediate attention to these concerns. Thank you for your cooperation and assistance during the site visit on June 16, 2023. If you have any questions and/or concerns, please contact me at the number listed below. Regards, Ne’Shonda Cobbs 919-218-8409 REFERENCE 36 REFERENCE 37 From:Caldwell, Shawna To:White, Jeffrey R Subject:[External] RE: [External]RE: Well Records / Lab Date:Wednesday, August 9, 2023 8:18:16 AM Attachments:image001.png 221031010.pdf 220831005.pdf 220912022.pdf CAUTION: External email. Do not click links or open attachments unless verified. Report suspicious emails with the Report Message button located on your Outlook menu bar on the Home tab. Hi Jeffery, I apologize for taking so long to get this to you, but I was trying to get better information/documentation for you. I have attached VOC sampling results for 1942 and 1948 Saint Mark Street. The well at 2235 Haines ST had not been sampled at the time of your inquiry. I have been trying to get the well records we discussed, but I have not been able to get copies of the well construction record for the wells at 1942 and 1948 Saint Mark ST and 2235 Haines ST or the abandonment record for 2204 Lasalle ST yet. I did speak directly to the Mecklenburg County Environmental Specialists responsible for permitting and inspecting the new well installations and the well abandonment. They indicated that they personally inspected the grouting of the casing and the well head completion for the new wells at 1942 and 1948 Saint Mark ST and 2235 Haines ST and the grouting of the well at 2204 Lasalle ST for permanent abandonment. All of these activities met the requirements of the permits according to both 15A NCAC 2C Well Construction Standards and Mecklenburg County Groundwater Well Regulations. The well at 2235 Haines ST was installed in 2020. The wells at Saint Mark ST would have been installed early Fall 2022. The well at 2204 Lasalle ST was permanently abandoned a few years ago. The wells at 2235 Haines ST and 1942 and 1948 Saint Mark ST are all potable wells. The permits for all three of these wells require that the well owner sample these wells every two years for VOCs and report any detections to Mecklenburg County Groundwater and Wastewater Services (GWS). GWS sends reminders when wells are due for the biannual sampling with an offer to complete the sampling through our well testing program. I requested that a sample be collected from the well at 2235 Haines ST, but the results are not yet available. Please let me know if you have questions or I can help otherwise. Thx! Have a great day. Shawna W. Caldwell, PG Hydrogeologist Mecklenburg County Government Groundwater and Wastewater Services 3205 Freedom Dr., Suite 8000 Charlotte, NC 28208 GWS Phone: 704.336.5103 GWS Fax: 704.336.4391 Direct Line: 980.314.1626 Cell Phone: 704.622.5168 shawna.caldwell@mecklenburgcountync.gov CONFIDENTIALITY NOTICE: This message and any attachments included are from the Mecklenburg County Health Department and are for sole use by the intended recipient(s). The information contained herein may include confidential or privileged information. Unauthorized review, forwarding, printing, copying, distributing, or using such information is strictly prohibited and may be unlawful. If you received this message in error, or have reason to believe you are not authorized to receive it, please contact the sender by reply email and destroy all copies of the original message. Thank you! From: White, Jeffrey R <Jeffrey.White@deq.nc.gov> Sent: Monday, August 7, 2023 3:07 PM To: Caldwell, Shawna <Shawna.Caldwell@mecklenburgcountync.gov> Subject: [External]RE: Well Records / Lab CAUTION: This email originated from outside of the organization. Do not click links or open attachments unless you recognize the sender and know the content is safe. Good afternoon Shawna, I was just following up on the VOC laboratory results for the WSW’s located at Saint Mark Street we discussed over the phone a while back related to the People’s Cleaner’s site at 1930 Beatties Ford Road. We are wrapping up the report and although not necessary to include, it would be helpful if we could include them for any potential future assessment/evaluation. Thank you and feel free to call me any time. Jeffrey R. White Hydrogeologist, Federal Remediation Branch Superfund Section, Division of Waste Management North Carolina Department of Environmental Quality New Office Number: (919) 707-8341 New Email Address: jeffrey.white@deq.nc.gov DEQ is updating its email addresses to @deq.nc.gov Employee email addresses may look different, but email performance will not be impacted. From: White, Jeffrey R Sent: Monday, July 17, 2023 12:20 PM To: shawna.caldwell@mecklenburgcountync.gov Subject: RE: Well Records / Lab Hi Shawna, I noticed I requested the wrong address for the well laboratory results and GW-1 form in my previous email. The address is 1942 and 1948 Saint Mark Street. Please let me know if you or anyone else is able to assist with this as we may need to put this on our workplan for sampling if not. Thank you, Jeffrey R. White Hydrogeologist, Federal Remediation Branch Superfund Section, Division of Waste Management North Carolina Department of Environmental Quality New Office Number: (919) 707-8341 New Email Address: jeffrey.white@deq.nc.gov DEQ is updating its email addresses to @deq.nc.gov Employee email addresses may look different, but email performance will not be impacted. From: White, Jeffrey R Sent: Thursday, July 6, 2023 2:00 PM To: shawna.caldwell@mecklenburgcountync.gov Subject: Well Records / Lab Good afternoon Shawna, My name is Jeffrey and I’m working on a Pre-CERCLA Screening (PCS) Assessment related to the Peoples Cleaners site located at 1930 Beatties Ford Road, Charlotte, NC. I have a few questions about some new water supply wells within the study area of the site regarding potential receptors/contaminant pathways. I was able to pull up the records for the two wells located at 1929 & 1933 Saint Paul Street, however, I was unable to find the laboratory results. Do you have access to these and the actual drillers well records? These would be the closest downgradient wells to the Peoples Cleaners site and would be conducive for me to document and include in the assessment. The assessment has mostly focused on the subsurface intrusion pathway of adjacent properties to the site; however, we do look at all potential pathways. I was also unable to pull up the well records for the properties listed below to confirm if they were drinking water wells: - 1929 & 1933 Saint Paul Street (new construction) - 2235 Haines Street (new construction) - 2204 Lasalle Street (appears abandoned) Please feel free to give me a call if it would be easier to discuss. I can also provide you with the PCS report once finalized. Any help would be much appreciated! Jeffrey R. White Hydrogeologist, Federal Remediation Branch Superfund Section, Division of Waste Management North Carolina Department of Environmental Quality New Office Number: (919) 707-8341 New Email Address: jeffrey.white@deq.nc.gov From:Caldwell, Shawna To:White, Jeffrey R Subject:RE: [External] RE: [External]RE: Well Records / Lab Date:Monday, September 18, 2023 12:15:36 PM Attachments:image001.png CAUTION: External email. Do not click links or open attachments unless verified. Report suspicious emails with the Report Message button located on your Outlook menu bar on the Home tab. Yes, these wells have been installed and are active drinking water wells. Pls let me know if you need more info. Thx! Have a great day. Shawna W. Caldwell, PG Senior Hydrogeologist Mecklenburg County Government Groundwater and Wastewater Services 3205 Freedom Dr., Suite 8000 Charlotte, NC 28208 GWS Phone: 704.336.5103 GWS Fax: 704.336.4391 Direct Line: 980.314.1626 Cell Phone: 704.622.5168 shawna.caldwell@mecklenburgcountync.gov CONFIDENTIALITY NOTICE: This message and any attachments included are from the Mecklenburg County Health Department and are for sole use by the intended recipient(s). The information contained herein may include confidential or privileged information. Unauthorized review, forwarding, printing, copying, distributing, or using such information is strictly prohibited and may be unlawful. If you received this message in error, or have reason to believe you are not authorized to receive it, please contact the sender by reply email and destroy all copies of the original message. Thank you! From: White, Jeffrey R <Jeffrey.White@deq.nc.gov> Sent: Tuesday, September 12, 2023 12:36 PM To: Caldwell, Shawna <Shawna.Caldwell@mecklenburgcountync.gov> Subject: RE: [External] RE: [External]RE: Well Records / Lab CAUTION: This email originated from outside of the organization. Do not click links or open attachments unless you recognize the sender and know the content is safe. Hey Shawna, Thanks again for all your help. I just have one more quick question. We may have discussed it on the phone, but I just wanted to double check. Did we confirm the status of the two wells at 1929 & 1933 Saint Paul Street (new construction)? REFERENCE 38 REFERENCE 39