3612_DukeAllen_RABLF_Sept2023_Leachate Report_FID1825679_20231230

DUKE
ENERGY,
December 30, 2023
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
2090 U.S. 70 Highway
Swannanoa, NC 28778-8211
Subject: 2023 Second Semi-annual Leachate Sampling Results
Retired Ash Basin Ash Landfill, Phase I, Cells 1 and 2, Permit #36-12
Allen Steam Station
Gaston County, North Carolina
Dear Ms. Moutos:
526 South Church Street
Charlotte, NC 28202
Mail Code: DEP-36A
In accordance with the current landfill Operations Plan, Duke Energy Carolinas, LLC (Duke Energy) is providing
the results of semi-annual leachate sampling for the Allen Steam Station (Allen) Retired Ash Basin (RAB) Ash
Landfill located in Gaston County, North Carolina.
On September 13, 2023, leachate samples were collected from the leachate collection system at sample ports
for Cell 1 and Cell 2 as depicted on Figure 1.
Samples were collected by Duke Energy personnel. A summary of sampling results can be found in Table 1.
Laboratory analytical and field forms are provided as Attachments 1 and 2, respectively. Please note that this
was the first leachate sampling event for the Allen RAB Ash Landfill utilizing the harmonized constituents and
analytical methods approved by the Section on March 20, 2023. Per the harmonized list, calcium lithium,
magnesium, and molybdendum were included in this sampling event, in addition to the historical Allen RAB
Ash Landfill leachate parameters. Since this sampling event comprises only leachate, the parameters tested are
not bound by state groundwater or surface water standards.
The Allen RAB Ash Landfill leachate is sampled semi-annually, typically during the March and September
timeframes. The next landfill leachate sampling event will occur around March 2024 with documentation to
follow.
If you have any questions or concerns, please contact me at 704-382-7171 or at.Courtney.Murphv@duke-
energy.com.
Sincerely, r
&qAyGf1 ffk4)i1
Courtney W. Murphy, P.G.
Environmental Services
Cc (via email): Mr. Jeff Flanagan — Duke Energy
Mr. Scott Harris — Duke Energy
Mr. Preston McCloud — Duke Energy
Mr. Kenneth McKinney — Duke Energy
Ms. Kimberlee Witt — Duke Energy
Page 1 of 1

DENR USE ONLY: I I ❑Pope, Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #:
NC DENR I IEnvironmental Monitoring
Division of Waste Management - Solid Waste Reaortina Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such. these documents are
available for inspection and examination by any person upon request INC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables. and Electronic Data Deliverable to: Compliance Unit. NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center. Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory. consultant. facility owner):
Duke Energy Carolinas, LLC
Contact for questions about data formatting. Include data preparer's name. telephone number and E-mail address:
Name: (;n„rtnev W Mumhv PG Phone: r7n4) 3AV-7171
E-mail: c.ourtnev Mumhvt7rluke-enarnv cnm
Facility name:
Retired Ash Basin (RAB) Ash
Landfill
Duke Energy
Allen Steam Station
Facility Address:
253 Plant Allen Rd.
Belmont. NC 28012
Facility Permit #
L12
INC Landfill Rule: Actual sampling dates (e.g..
(.0500 or .1600) October 20-24. 2006)
.0500 September 13, 2023
Environmental Status: (Check all that apply)
Initial/Background Monitoring IX Detection Monitoring Assessment Monitoring I Corrective Action
ype of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells LJ Methane gas monitoring data
Groundwater monitoring data from private water supply wells Corrective action data (specify)
X Leachate monitoring data
Surface water monitoring data n Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
_ Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates. analytical values. INC 2L groundwater standard. NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore. I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels. and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement. representation, or certification including the possibility of a fine and imprisonment.
Courtney W. Murphy, P.G. Lead Environmental Specialist [phone]
Facility Representative Name (Print) Title (Area Code) Telephone Number
Courtn e M u r h Digitally signed by Courtney Murphy 12/30/2023 Affix NC Licensed/ Professional Geologist Seal
Y p Y Date: 2023.12.30 1725 12-05'00'
Signature
Date
Duke Energy Corporation, Mail Code DEP-36A, 526 South Church St, Charlotte, NC 28202
Facility Representative Address
#F-0566
INC PE Finn License Number (if applicable effective May 1, 2009)
Revised 612009

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Table 1- Leachate Analytical Data
Allen Steam Station
Notes:
Retired Ash Basin (RAB) Ash Landfill (Permit No. 36-12)
Constituent
Analytical Result
(µg/L unless otherwise noted)
September 13, 2023
Cell 1
Cell 2
Antimony
0.104 U
0.104 U
Arsenic
15.3
35.5
Barium
30
32
Beryllium
0.833 J
0.757 J
Boron
65,600 M4
184,000
Cadmium
3.65
0.908 J
Calcium
440 M4 mg/L
447 mg/L
Chloride
110 mg/L
160 mg/L
Chromium
1.08 J
0.743 J
Cobalt
852
871 M4
Copper
82,600 mg/L
39,700 mg/L
Fluoride
0.0479 U mg/L
0.44 J mg/L
Iron
12
13
Lead
0.333 J
0.229 J
Lithium
22.0 mg/L
4.32 mg/L
Magnesium
435 M4 mg/L
158 mg/L
Manganese
13,600
15,000
Mercury
0.03 J, M
0.04 J
Molybdendum
139
1,940 M4
Nickel
379
68.5
Nitrate (as N)
88 mg-N/L
21 mg-N/L
Selenium
27.3
97.2
Silver
0.035 U
0.051 J
Sulfate
4,000 mg/L
3,000 mg/L
TDS
6,310 mg/L
5,180 mg/L
Thallium
9.86
1.92
Vanadium
0.481 J
0.237 J
Zinc
0.353 mg/L
0.098 mg/L
pH
5.01 S.U.
4.64 S.U.
Temperature (°C)
21
20
Dissolved Oxygen (mg/L)
1.01
1.77
ORP (mV)
435
440
Specific Conductivity (VS/cm)
6418
5130
Turbidity (NTU)
1.1
0.6
µg/L = micrograms per liter
mg/L = milligrams per liter
mg-N/L = milligrams of Nitrogen per liter
S.U. = standard units
'C = degrees Celcius
NTU = nephelometric turbidity unit
ORP = oxidation-reduction potential
mV = millivolts
0/cm = microSiemens per centimeter
J = Analyte detected above the Method Detection Limit (MDL), but below the
Reporting Limit (RL). Analyte concentration should be considered an estimate.
U = Analyte concentration below MDL.
M = Matrix Spike and/or Matrix Spike Duplicate recovery was outside of the
control limits. The associated Laboratory Control Spike (LCS) recovery was
acceptable.
M4 = The spike recovery value was unusable since the analyte concentration in
the sample was disproportionate to the spike level. The associated Laboratory
Control Spike recovery was acceptable.

Attachment 1
Allen Retired Ash Basin (RAB) Ash Landfill
Semi -Annual Monitoring Event
Leachate Analytical Results

DUKE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J23090222
Project Name:
ALLEN - RAB LANDFILL
Task Code:
LF
Customer Name(s):
C Murphy,B Moeller,DOBrien,J Stowe,C Zahora,Synter
Customer Address:
Allen Steam Station
253 Plant Allen Road
Belmont, NC 28012
Lab Contact: Peggy Kendall Phone: [phone]
Report Authorized By: Piet 9147-o" pate: 10/6/2023
(Signature)
Peggy Kendall
Program Comments:
QC Note:
LCS-Cell1 Hg MS/MSD recoveries fell below the QC limits. The blank and LCS were within the control limits.
Sulfate(0.013 mg/L), boron (0.082 mg/L), and lithium (0.007 mg/L) were detected in the field blank.
Data Flags & Calculations:
Page 1 of 16
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
2023022650 ALLEN
13-Sep-23 9:05 AM
2023022651 ALLEN
13-Sep-23 9:10 AM
2023022652 ALLEN
13-Sep-23 9:15 AM
3 Total Samples
Page 2 of 16
Collected By Sample Description
Connor Zahora
ALN_LCS-CELL1
Connor Zahora
ALN_LCS-CELL2
Connor Zahora
ALN_FB-20230913-0915

Page 3 of 16
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
❑d Job Summary Report
❑d Sample Identification
❑� Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑� Analytical Laboratory QC Report
❑ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 10/6/2023

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090222
Site: ALN LCS-CELL1
Collection Date: 09/13/2023 09:05 AM Loc code: ALN LCS-CELL1
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23090173
Chloride
110
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
390
mg/L
Nitrate as N
88
mg-N/L
Sulfate
4000
mg/L
MERCURY (COLD VAPOR) IN WATER - Q23090199
Mercury (Hg)
0.03 J
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23090232
Barium (Ba)
0.030
mg/L
Boron (B)
65.6
mg/L
Calcium (Ca)
440
mg/L
Iron (Fe)
0.012
mg/L
Lithium (Li)
22.0
mg/L
Magnesium (Mg)
435
mg/L
Manganese (Mn)
13.6
mg/L
Zinc (Zn)
0.353
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23090237
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
15.3
ug/L
Beryllium (Be)
0.833 J
ug/L
Cadmium (Cd)
3.65
ug/L
Chromium (Cr)
1.08 J
ug/L
Cobalt (Co)
852
ug/L
Copper (Cu)
82.6
ug/L
Lead (Pb)
0.333 J
ug/L
Molybdenum (Mo)
139
ug/L
Nickel (Ni)
379
ug/L
Selenium (Se)
27.3
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
9.86
ug/L
Vanadium (V)
0.481 J
ug/L
TOTAL DISSOLVED SOLIDS -
023090207
TDS 6310 mg/L
Sample #: 2023022650
Matrix: GW RCRA
Page 4 of 16
Method Analysis Date/Time Analyst
5
0.0154
50
EPA 9056A
09/14/2023 12:41
BGN9034
5
0.0479
50
EPA 9056A
09/14/2023 12:41
BGN9034
5
0.0209
50
EPA 9056A
09/14/2023 12:41
BGN9034
1.15
0.002
50
EPA 9056A
09/14/2023 12:41
BGN9034
100
0.0428
1000
EPA 9056A
09/14/2023 12:41
BGN9034
M
0.05
0.01
1
EPA 7470A
09/15/2023 10:34
SNEGLIA
0.005
0.002
1
SW 601OD
09/19/2023 11:36
EBATIAN
M4
0.5
0.005
10
SW 601OD
09/19/2023 11:36
EBATIAN
M4
0.5
0.012
10
SW 601OD
09/19/2023 11:36
EBATIAN
0.01
0.004
1
SW 601OD
09/19/2023 11:36
EBATIAN
0.05
0.002
10
SW 601OD
09/19/2023 11:36
EBATIAN
M4
2
0.008
100
SW 601OD
09/19/2023 11:36
EBATIAN
0.005
0.001
1
SW 601OD
09/19/2023 11:36
EBATIAN
0.005
0.004
1
SW 601OD
09/19/2023 11:36
EBATIAN
2
0.104
2
SW 6020B
09/19/2023 14:01
MHALL3
2
0.111
2
SW 6020B
09/19/2023 14:01
MHALL3
2
0.249
2
SW 6020E
09/19/2023 14:01
MHALL3
2
0.032
2
SW 6020E
09/19/2023 14:01
MHALL3
2
0.185
2
SW 6020B
09/19/2023 14:01
MHALL3
100
0.077
100
SW 6020E
09/19/2023 14:01
MHALL3
2
0.787
2
SW 6020B
09/19/2023 14:01
MHALL3
2
0.037
2
SW 6020E
09/19/2023 14:01
MHALL3
2
0.18
2
SW 6020E
09/19/2023 14:01
MHALL3
2
0.256
2
SW 6020B
09/19/2023 14:01
MHALL3
2
0.193
2
SW 6020B
09/19/2023 14:01
MHALL3
2
0.035
2
SW 6020E
09/19/2023 14:01
MHALL3
0.4
0.041
2
SW 6020B
09/19/2023 14:01
MHALL3
2
0.114
2
SW 6020E
09/19/2023 14:01
MHALL3
100
25
1
SM2540C
09/18/2023 08:43
SNEGLIA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090222
Site: ALN LCS-CELL2
Collection Date: 09/13/2023 09:10 AM Loc code: ALN LCS-CELL2
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23090173
Chloride
160
mg/L
Fluoride
0.44 J
mg/L
Nitrate
92
mg/L
Nitrate as N
21
mg-N/L
Sulfate
3000
mg/L
MERCURY (COLD VAPOR) IN WATER - Q23090199
Mercury (Hg)
0.04 J
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23090232
Barium (Ba)
0.032
mg/L
Boron (B)
184
mg/L
Calcium (Ca)
447
mg/L
Iron (Fe)
0.013
mg/L
Lithium (Li)
4.32
mg/L
Magnesium (Mg)
158
mg/L
Manganese (Mn)
15.0
mg/L
Zinc (Zn)
0.098
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23090237
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
35.5
ug/L
Beryllium (Be)
0.757 J
ug/L
Cadmium (Cd)
0.908 J
ug/L
Chromium (Cr)
0.743 J
ug/L
Cobalt (Co)
871
ug/L
Copper (Cu)
39.7
ug/L
Lead (Pb)
0.229 J
ug/L
Molybdenum (Mo)
1940
ug/L
Nickel (Ni)
68.5
ug/L
Selenium (Se)
97.2
ug/L
Silver (Ag)
0.051 J
ug/L
Thallium (TI) Low Level
1.92
ug/L
Vanadium (V)
0.237 J
ug/L
TOTAL DISSOLVED SOLIDS -
023090207
TDS 5180 mg/L
Sample #: 2023022651
Matrix: GW RCRA
Page 5 of 16
Method Analysis Date/Time Analyst
5
0.0154
50
EPA 9056A
09/14/2023 13:12
BGN9034
5
0.0479
50
EPA 9056A
09/14/2023 13:12
BGN9034
5
0.0209
50
EPA 9056A
09/14/2023 13:12
BGN9034
1.15
0.002
50
EPA 9056A
09/14/2023 13:12
BGN9034
100
0.0428
1000
EPA 9056A
09/14/2023 13:12
BGN9034
0.05
0.01
1
EPA 7470A
09/15/2023 10:41
SNEGLIA
0.005
0.002
1
SW 601OD
09/19/2023 11:50
EBATIAN
0.5
0.005
10
SW 601OD
09/19/2023 11:50
EBATIAN
0.5
0.012
10
SW 601OD
09/19/2023 11:50
EBATIAN
0.01
0.004
1
SW 601OD
09/19/2023 11:50
EBATIAN
0.005
0.002
1
SW 601OD
09/19/2023 11:50
EBATIAN
0.2
0.008
10
SW 601OD
09/19/2023 11:50
EBATIAN
0.005
0.001
1
SW 601OD
09/19/2023 11:50
EBATIAN
0.005
0.004
1
SW 601OD
09/19/2023 11:50
EBATIAN
1
0.104
1
SW 6020B
09/19/2023 12:41
MHALL3
1
0.111
1
SW 6020B
09/19/2023 12:41
MHALL3
1
0.249
1
SW 6020E
09/19/2023 12:41
MHALL3
1
0.032
1
SW 6020E
09/19/2023 12:41
MHALL3
1
0.185
1
SW 6020B
09/19/2023 12:41
MHALL3
M4 100
0.077
100
SW 6020E
09/19/2023 12:41
MHALL3
1
0.787
1
SW 6020B
09/19/2023 12:41
MHALL3
1
0.037
1
SW 6020E
09/19/2023 12:41
MHALL3
M4 100
0.18
100
SW 6020E
09/19/2023 12:41
MHALL3
1
0.256
1
SW 6020B
09/19/2023 12:41
MHALL3
1
0.193
1
SW 6020B
09/19/2023 12:41
MHALL3
1
0.035
1
SW 6020E
09/19/2023 12:41
MHALL3
0.2
0.041
1
SW 6020B
09/19/2023 12:41
MHALL3
1
0.114
1
SW 6020E
09/19/2023 12:41
MHALL3
100
25
1
SM2540C
09/18/2023 08:43
SNEGLIA

Certificate of Laboratory Analysis Page 6 of 16
This report shall not be reproduced, except in full.
Order # J23090222
Site: ALN FB-20230913-0915 Field Blank Sample #: 2023022652
Collection Date: 09/13/2023 09:15 AM Loc code: ALN QA Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23090173
Chloride 0.0154 U mg/L
Fluoride 0.0479 U mg/L
Nitrate 0.03 J mg/L
Nitrate as N 0.01 J mg-N/L
Sulfate 0.13 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23090199
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23090232
Barium (Ba)
0.002 U
mg/L
Boron (B)
0.082
mg/L
Calcium (Ca)
0.012 U
mg/L
Iron (Fe)
0.004 U
mg/L
Lithium (Li)
0.007
mg/L
Magnesium (Mg)
0.008 U
mg/L
Manganese (Mn)
0.001 U
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23090237
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.185 U
ug/L
Cobalt (Co)
0.489 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.256 U
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V)
0.114 U
ug/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
09/14/2023 11:38
BGN9034
0.1
0.0479
1
EPA 9056A
09/14/2023 11:38
BGN9034
0.1
0.0209
1
EPA 9056A
09/14/2023 11:38
BGN9034
0.023
0.002
1
EPA 9056A
09/14/2023 11:38
BGN9034
0.1
0.0428
1
EPA 9056A
09/14/2023 11:38
BGN9034
0.05
0.01
1
EPA 7470A
09/15/2023 10:43
SNEGLIA
0.005
0.002
1
SW 601OD
09/19/2023 11:55
EBATIAN
0.05
0.005
1
SW 601OD
09/19/2023 11:55
EBATIAN
0.05
0.012
1
SW 601OD
09/19/2023 11:55
EBATIAN
0.01
0.004
1
SW 601OD
09/19/2023 11:55
EBATIAN
0.005
0.002
1
SW 601OD
09/19/2023 11:55
EBATIAN
0.02
0.008
1
SW 601OD
09/19/2023 11:55
EBATIAN
0.005
0.001
1
SW 601OD
09/19/2023 11:55
EBATIAN
0.005
0.004
1
SW 601OD
09/19/2023 11:55
EBATIAN
1
0.104
1
SW 6020B
09/19/2023 14:35
MHALL3
1
0.111
1
SW 6020B
09/19/2023 14:35
MHALL3
1
0.249
1
SW 6020E
09/19/2023 14:35
MHALL3
1
0.032
1
SW 6020E
09/19/2023 14:35
MHALL3
1
0.185
1
SW 6020B
09/19/2023 14:35
MHALL3
1
0.077
1
SW 6020E
09/19/2023 14:35
MHALL3
1
0.787
1
SW 6020B
09/19/2023 14:35
MHALL3
1
0.037
1
SW 6020E
09/19/2023 14:35
MHALL3
1
0.18
1
SW 6020E
09/19/2023 14:35
MHALL3
1
0.256
1
SW 6020B
09/19/2023 14:35
MHALL3
1
0.193
1
SW 6020B
09/19/2023 14:35
MHALL3
1
0.035
1
SW 6020E
09/19/2023 14:35
MHALL3
0.2
0.041
1
SW 6020B
09/19/2023 14:35
MHALL3
1
0.114
1
SW 6020E
09/19/2023 14:35
MHALL3

Certificate of Laboratory Analysis Page 7 of 16
This report shall not be reproduced, except in full.
Order # J23090222
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.
M Matrix Spike and/or Matrix Spike Duplicate recovery was outside of the control limits. The associated Laboratory Control
Spike (LCS) recovery was acceptable.
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate to the spike level.
The associated Laboratory Control Spike recovery was acceptable.

Certificate of Laboratory Analysis Page 8 of 16
This report shall not be reproduced, except in full.
Order # J23090222
Level II QC Summary
Q23090173 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Fluoride
0
0
mg/L
1
0.0479
0.1
< MDL
Nitrate
0
0
mg/L
1
0.0209
0.1
< MDL
Sulfate
0.002
0.002
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
5.24
5.24
mg/L
1
0.0154
5
105
80
120
Fluoride
5.08
5.08
mg/L
1
0.0479
5
102
80
120
Nitrate
5.31
5.31
mg/L
1
0.0209
5
106
80
120
Sulfate
5.19
5.19
mg/L
1
0.0428
5
104
80
120
MS # 1
Parent Sample:
J23090285 -- 2023023002
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
1.94
9.7
mg/L
5
0.0154
5
101
80
120
Fluoride
5.32
5.32
mg/L
1
0.0479
5
106
80
120
Nitrate
5.34
5.34
mg/L
1
0.0209
5
102
80
120
Sulfate
7.38
7.38
mg/L
1
0.0428
5
95.3
80
120
MSD # 1
Parent Sample:
J23090285 -- 2023023002
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Qualifier
Chloride
1.95
9.72
mg/L
5
0.0154
5
101
80
120
0.495
Fluoride
5.39
5.39
mg/L
1
0.0479
5
108
80
120
1.21
Nitrate
5.38
5.38
mg/L
1
0.0209
5
102
80
120
0.804
Sulfate
7.45
7.45
mg/L
1
0.0428
5
96.7
80
120
1.46

Certificate of Laboratory Analysis Page 9 of 16
This report shall not be reproduced, except in full.
Order # J23090222
Level II QC Summary
Q23090199 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.01
0.01
ug/L
1
0.01
0.05
= MDL
Blank # 2
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.004
0.004
ug/L
1
0.01
0.05
< MDL
Blank # 3
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.007
0.007
ug/L
1
0.01
0.05
< MDL
Blank # 4
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.009
0.009
ug/L
1
0.01
0.05
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery LCL UCL
Qualifier
Mercury (Hg)
2.08
2.08
ug/L
1
0.01
2
104 85 115
LCS # 2
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
2.06
2.06
ug/L
1
0.01
2
103
85 115
MS # 1
Parent Sample:
J23090222 -- 2023022650
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL UCL
Qualifier
Mercury (Hg)
0.264
0.264
ug/L
1
0.01
1
23.7
75 125
M
MSD # 1
Parent Sample:
J23090222 -- 2023022650
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.265
0.265
ug/L
1
0.01
1
23.8
75 125 0.421
M
MS # 2
Parent Sample:
J23090248 -- 2023022814
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.03
1.03
ug/L
1
0.01
1
102
75 125
MSD # 2
Parent Sample:
J23090248 -- 2023022814
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.01
1.01
ug/L
1
0.01
1
100
75 125 2.07
MS # 3
Parent Sample:
J23090285 -- 2023023009
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1
1
ug/L
1
0.01
1
99.2
75 125

Certificate of Laboratory Analysis Page 10 of 16
This report shall not be reproduced, except in full.
Order # J23090222
Level II QC Summary
Q23090199 HG 7470 MERCURY (COLD VAPOR) IN WATER
MSD # 3
MS # 4
MSD # 4
Parameter Measured Final
Mercury (Hg) 1 1
Parameter Measured Final
Mercury (Hg) 0.987 0.987
Parameter Measured Final
Mercury (Hg) 0.977 0.977
Parent Sample:
J23090285 -- 2023023009
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD Qualifier
ug/L
1
0.01
1
99.5
75 125 0.302
Parent Sample:
J23090300 -- 2023023068
Units
Dil
MDL
Spike
% Recovery
LCL UCL Qualifier
ug/L
1
0.01
1
97.8
75 125
Parent Sample:
J23090300 -- 2023023068
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD Qualifier
ug/L
1
0.01
1
96.8
75 125 1.03
Qualifiers:
M Matrix Spike and/or Matrix Spike Duplicate recovery was outside of the control limits. The associated
Laboratory Control Spike (LCS) recovery was acceptable.

Certificate of Laboratory Analysis Page 11 of 16
This report shall not be reproduced, except in full.
Order # J23090222
Level II QC Summary
Q23090232 ICP_TRM TOTAL RECOVERABLE METALS BY 1CP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration Qualifier
Barium (Ba)
-0.000077
-0.000077
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.000274
0.000274
mg/L
1
0.005
0.05
< MDL
Calcium (Ca)
0.00451
0.00451
mg/L
1
0.012
0.05
< MDL
Iron (Fe)
-0.000117
-0.000117
mg/L
1
0.004
0.01
< MDL
Lithium (Li)
0.00118
0.00118
mg/L
1
0.002
0.005
< MDL
Magnesium (Mg)
-0.00489
-0.00489
mg/L
1
0.008
0.02
< MDL
Manganese (Mn)
-0.000318
-0.000318
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
-0.00127
-0.00127
mg/L
1
0.004
0.005
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Barium (Ba)
5.19
5.19
mg/L
1
0.002
5
104
80
120
Boron (B)
4.9
4.9
mg/L
1
0.005
5
98
80
120
Calcium (Ca)
4.98
4.98
mg/L
1
0.012
5
99.7
80
120
Iron (Fe)
5.11
5.11
mg/L
1
0.004
5
102
80
120
Lithium (Li)
4.87
4.87
mg/L
1
0.002
5
97.4
80
120
Magnesium (Mg)
4.95
4.95
mg/L
1
0.008
5
99
80
120
Manganese (Mn)
4.9
4.9
mg/L
1
0.001
5
98
80
120
Zinc (Zn)
5
5
mg/L
1
0.004
5
103
80
120
MS # 1
Parent Sample:
J23090222
-- 2023022650
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
Qualifier
Barium (Ba)
4.01
4.01
mg/L
1
0.002
5
79.7
75
125
Boron (B)
7.05
70.5
mg/L
10
0.005
5
99.1
75
125
Calcium (Ca)
44.6
446
mg/L
10
0.012
5
124
75
125
Iron (Fe)
4.98
4.98
mg/L
1
0.004
5
99.3
75
125
Lithium (Li)
2.72
27.2
mg/L
10
0.002
5
103
75
125
Magnesium (Mg)
4.35
435
mg/L
100
0.008
5
0
75
125
M4
Manganese (Mn)
18.4
18.4
mg/L
1
0.001
5
95.6
75
125
Zinc (Zn)
4.78
4.78
mg/L
1
0.004
5
101
75
125
MSD # 1
Parent Sample:
J23090222
-- 2023022650
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Qualifier
Barium (Ba)
4.07
4.07
mg/L
1
0.002
5
80.9
75
125
1.46
Boron (B)
7.21
72.1
mg/L
10
0.005
5
131
75
125
2.27
M4
Calcium (Ca)
45.6
456
mg/L
10
0.012
5
320
75
125
2.18
M4
Iron (Fe)
4.99
4.99
mg/L
1
0.004
5
99.6
75
125
0.301
Lithium (Li)
2.77
27.7
mg/L
10
0.002
5
115
75
125
2.16
Magnesium (Mg)
4.34
434
mg/L
100
0.008
5
0
75
125
0.0868
M4
Manganese (Mn)
18.6
18.6
mg/L
1
0.001
5
101
75
125
1.41

Certificate of Laboratory Analysis Page 12 of 16
This report shall not be reproduced, except in full.
Order # J23090222
Level II QC Summary
Q23090232 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
MSD # 1 Parent Sample: J23090222 -- 2023022650
Parameter Measured Final Units Dil MDL Spike % Recovery LCL UCL RPD Qualifier
Zinc (Zn) 4.81 4.81 mg/L 1 0.004 5 101 75 125 12.5
Qualifiers:
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate
to the spike level. The associated Laboratory Control Spike recovery was acceptable.

Certificate of Laboratory Analysis Page 13 of 16
This report shall not be reproduced, except in full.
Order # J23090222
Level II QC Summary
Q23090237 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
0.008
0.008
ug/L
1
0.104
1
< MDL
Arsenic (As)
0.023
0.023
ug/L
1
0.111
1
< MDL
Beryllium (Be)
-0.003
-0.003
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.003
0.003
ug/L
1
0.032
1
< MDL
Chromium (Cr)
-0.052
-0.052
ug/L
1
0.185
1
< MDL
Cobalt (Co)
-0.003
-0.003
ug/L
1
0.077
1
< MDL
Copper (Cu)
-0.002
-0.002
ug/L
1
0.787
1
< MDL
Lead (Pb)
-0.004
-0.004
ug/L
1
0.037
1
< MDL
Molybdenum (Mo)
0.009
0.009
ug/L
1
0.18
1
< MDL
Nickel (Ni)
0.003
0.003
ug/L
1
0.256
1
< MDL
Selenium (Se)
-0.11
-0.11
ug/L
1
0.193
1
< MDL
Silver (Ag)
0.003
0.003
ug/L
1
0.035
1
< MDL
Thallium (TI) Low Level
-0.012
-0.012
ug/L
1
0.041
0.2
< MDL
Vanadium (V)
-0.004
-0.004
ug/L
1
0.114
1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
Antimony (Sb)
48.3
48.3
ug/L
1
0.104
50
96.7
80
120
Arsenic (As)
48.6
48.6
ug/L
1
0.111
50
97.2
80
120
Beryllium (Be)
51.2
51.2
ug/L
1
0.249
50
102
80
120
Cadmium (Cd)
49.8
49.8
ug/L
1
0.032
50
99.6
80
120
Chromium (Cr)
50.1
50.1
ug/L
1
0.185
50
100
80
120
Cobalt (Co)
51.2
51.2
ug/L
1
0.077
50
102
80
120
Copper (Cu)
51.5
51.5
ug/L
1
0.787
50
103
80
120
Lead (Pb)
50.8
50.8
ug/L
1
0.037
50
102
80
120
Molybdenum (Mo)
50.8
50.8
ug/L
1
0.18
50
102
80
120
Nickel (Ni)
50.8
50.8
ug/L
1
0.256
50
102
80
120
Selenium (Se)
48.7
48.7
ug/L
1
0.193
50
97.3
80
120
Silver (Ag)
51.5
51.5
ug/L
1
0.035
50
103
80
120
Thallium (TI) Low Level
50.6
50.6
ug/L
1
0.041
50
101
80
120
Vanadium (V)
49.9
49.9
ug/L
1
0.114
50
99.7
80
120
MS # 1
Parent Sample:
J23090222
-- 2023022651
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
48.6
48.6
ug/L
1
0.104
50
97.1
75
125
Arsenic (As)
85.5
85.5
ug/L
1
0.111
50
100
75
125
Beryllium (Be)
43
43
ug/L
1
0.249
50
84.6
75
125
Cadmium (Cd)
48
48
ug/L
1
0.032
50
94.2
75
125
Chromium (Cr)
45.4
45.4
ug/L
1
0.185
50
89.3
75
125
Cobalt (Co)
8.78
878
ug/L
100
0.077
50
13.7
75
125
Qualifier
Qualifier
Qualifier
M4

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090222
Level II QC Summary
Q23090237 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
Copper (Cu)
87.7
87.7
ug/L
1
0.787
50
Lead (Pb)
51.3
51.3
ug/L
1
0.037
50
Molybdenum (Mo)
18.5
1850
ug/L
100
0.18
50
Nickel (Ni)
116
116
ug/L
1
0.256
50
Selenium (Se)
150
150
ug/L
1
0.193
50
Silver (Ag)
46.3
46.3
ug/L
1
0.035
50
Thallium (TI) Low Level
51.7
51.7
ug/L
1
0.041
50
Vanadium (V)
46.9
46.9
ug/L
1
0.114
50
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
Antimony (Sb)
47.7
47.7
ug/L
1
0.104
50
Arsenic (As)
85.8
85.8
ug/L
1
0.111
50
Beryllium (Be)
42.7
42.7
ug/L
1
0.249
50
Cadmium (Cd)
47.4
47.4
ug/L
1
0.032
50
Chromium (Cr)
44.8
44.8
ug/L
1
0.185
50
Cobalt (Co)
8.84
884
ug/L
100
0.077
50
Copper (Cu)
87.8
87.8
ug/L
1
0.787
50
Lead (Pb)
50.8
50.8
ug/L
1
0.037
50
Molybdenum (Mo)
18.2
1820
ug/L
100
0.18
50
Nickel (Ni)
117
117
ug/L
1
0.256
50
Selenium (Se)
144
144
ug/L
1
0.193
50
Silver (Ag)
45.9
45.9
ug/L
1
0.035
50
Thallium (TI) Low Level
51.3
51.3
ug/L
1
0.041
50
Vanadium (V)
46.8
46.8
ug/L
1
0.114
50
Qualifiers:
Page 14 of 16
Parent Sample: J23090222 -- 2023022651
% Recovery
LCL
UCL
95.9
75
125
102
75
125
0
75
125
95.8
75
125
105
75
125
92.5
75
125
99.5
75
125
93.4
75
125
Parent Sample: J23090222 -- 2023022651
% Recovery
LCL
UCL
RPD
95.3
75
125
1.82
100
75
125
0.473
83.9
75
125
0.784
93
75
125
1.28
88.2
75
125
1.29
25.4
75
125
59.6
96.2
75
125
0.287
101
75
125
0.949
0
75
125
0
96.7
75
125
0.891
94.4
75
125
10.3
91.8
75
125
0.838
98.7
75
125
0.805
93.2
75
125
0.253
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate
to the spike level. The associated Laboratory Control Spike recovery was acceptable.
Qualifier
M4
Qualifier
M4
M4

Certificate of Laboratory Analysis Page 15 of 16
This report shall not be reproduced, except in full.
Order # J23090222
Level II QC Summary
Q23090207 TDS TOTAL DISSOLVED SOLIDS
Blank # 1
Blank # 2
Parameter Measured Final
TDS -0.4
Parameter Measured Final
TDS -0.5
Duplicate # 1
Parameter Measured Final
TDS 539
Duplicate # 2
Parameter Measured Final
TDS 807
LCS # 1
LCS # 2
Parameter Measured Final
TDS 483
Parameter Measured Final
TDS 485
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Parent Sample:
J23090249 -- 2023022817
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
0
Parent Sample:
J23090287 -- 2023023019
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
3.79
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
96.6
90
110
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
97
90
110

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
i
DUKE Duke Energy Analytical Laboratory ! i Analytical LaboratoryUse Onlyrdyt:
-` Mae C°de MG03A2 Bulldls 7r0s1 Matrix WATER
1333BHagers Ferry Rd i Order# J23090222
ENERGY HNMera°Ill$ 3e07e 245 Logged By 3 ma
pal e7 N.C.N. C.
_._._._._._._._._._._._._._._._._. ._ _ _ F,::.�ate?ss°�e._._______,�
Project Name ALLEN RAB LANDFILL Phone N°: 'Vendor
•
PERMIT#: 3612-INDUS ._.._.._.._. _.._.. CoolTame.l�l._.._.._.._.._.._.._.._.._.._.._.._.
Client COURTNEY MURPHY, RANDY GANTT, BRYAN • PO e '
MOELLER, DEE O'BRIEN, JOSH STOWE Filtration (0.46 um)
Operating Unit: AS00 Process:BENVWS Account: preservative
i._.._.._.._.._.._.._.._.._.._.._..-..-..-..-..-.._.._.._.._.._.._.._.._.._ •
Project: Activity to: Facility ID: ALN Container Volume (ml-)
Program I EQuIS Task Code: ALN Sub-Program/Task Code: Container Type
LCSILF
w
Customer to complete all appropriate non -shaded areas, m rc C
.._.._.._.._.._.._..� Sample Description or ID
ID i Collection Information
SAMPLENUMBERi o "
Date Time Printed Name Signature u o`
_
e.ma"O"°'""'"°F'°"' scX
SAMPLE PROGRAM
Ground Water_X_ NPDES _
Drinking Water_ UST_
RCRA Waste _
_.._.._.._.._.._.._.._..-.._.._..-.._.._.._.._..
b Unfiltered
ICE
500 300
HOPE PET
(Metals Prep - TRM) I
(ICP - SW 6010D) Be, B, Cl, F,
Ca, Fe, Li, Mg, Mn, Zn NO3-N
(8)1 Hg (SW 7470A) I (48-Hr
(IMS - SW 60208) Sb, Hold
As, Be, Cd, Cr, Co, Cu, Time),
Pb, Mo, NI, Se, Ag, SO4
TI LL V 14
I O OI l O
9 _
; Page
ORIGINAL t0 LAB, COPY to CLIENT
b Filtered
ICE
500
PET
TDS
c
o
U
:
c
~
i�
2023022650 i
ALN_LCS-CELL1
9-13-23
U405
(,WAVE 7.4-10dA
x
1
1
1
3
2023022651
ALN_LCS-CELL2
OgID
x
1
1
1
3
2023022652
ALN_FB-20230k13 - 00115
01IS
x
1
1
2
^i
i
i
�i
i
�i
..................... .. - ,....- .........
Relinquished ByDate/Time
( /
11
Accepted Date/Timeq
/.� ��rt
Requested Turnaround
1-►3-Z 3
1
/� ZI is �$r
C/too
cY10i
a
e
Relinquished By DatelTime
Accepts y: DatelTime
21 Days
c
w
a o
Relinquished By DatelTime
Accepted By: DatelTime
. E
c E
c v
14 Days X
Seal/Locked By Date/Time
Sealed/Lock Opened By DatelTime
a :
'7 Days
E a
c
`m
Comments
m
'Other
EQUIS EDD Required
' Add. Cost Will Apply
U

Attachment 2
Allen Retired Ash Basin (RAB) Ash Landfill
Semi -Annual Monitoring Event
Leachate Field Forms

❑CAMA ❑CCR❑Landfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY &S(F
FIELD S �("
SAMPLING LOG DUKE
Site: /� 1�,7 Well/SW ID: CEU- I Date: N3-z3
❑i GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE, ❑ WLO [—]WELL DEVELOPMENT
FIELD STAFF: 6 7Z'
COMPANY: Q DUKE ENERGY
❑ OTHER:
WEATHER:
[]SUNNY ❑PARTLYCLOUDY ❑OVERCAST ❑RAIN ❑SNOW AIRTEMP: °F
FIELD METER TYPE/ SERIAL #: 9S/y9�
TURBIDIMETER TYPE/ SERIAL #: s31s1
START PURGE TIME: 0g00 SAMPLE COLLECTION TIME: 076
PUMPITUBING INTAKE DEPTH: () DEPTH TO WATER: (ft) MULT FACTOR *: 0.163 ['(radius/12)2*3.14`7.48]
WELL DIAMETER: (in) HEIGHT OF WC: (ft) WELL VOLUME: (gal)
WELL DEPTH: (ft) TOTAL VOLUME PURGED: [ (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
a
a
o
Liroc4-fG.
..(Psi) ( (sec) (sec) Low Flow Sampling Stabilization Criteria
• pH f 0.1 standard unit
• Specific Conductance t 5% In NSlcm
DO t 0.2 mg11
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
W
(gallons OR mL)
(x.xx)
CC)
W
(mg/L)
(x.xx)
(PS/CM)
W
(su)
(x.xx)
(mv)
N
(NTU)
(x.x)
02
Svv
o•SD
Z Z
3.3 Z
3K2
S-04
VZ3
3 Y
d qrA
I
93 s
I
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? AYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑ YES ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? AYES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR gone H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH Minor Strong
ADDITIONAL NOTES:APPEARANCE Cloudy Turbid Red/iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
l
/
Version 1.0 Revised 12/17/2018 RDP

❑CAMA ❑CCR ❑Landfill ❑NPDES ❑ DGW❑ASW ❑ LRB SPECIAL STUDY ,&fWC
FIELD SAMPLING LOG .t DUKE
ENERG�
Site: A&A Well/SW ID: abt, L Date: -i3-Z3
2 GROUNDWATER SAMPLE❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: 6) L
COMPANY: Q DUKE ENERGY
❑ OTHER:
WEATHER: ❑SUNNY ❑PARTLYCLOUDY ❑OVERCAST ❑RAIN FISNOW AIR TEMP: °F
FIELD METER TYPE/ SERIAL M `1 6R�
TURBIDIMETER TYPE/ SERIAL #: 33?'j
START PURGE TIME: 0107 SAMPLE COLLECTION TIME: C)q/D
PUMPITUBING INTAKE DEPTH: (ft) DEPTH TO WATER: (ft) MULT FACTOR *• 0.163 I*(radius/12)2*3.14*7.48)
WELL DIAMETER: (in) HEIGHT OF WC: (ft) WELL VOLUME: (gal)
WELL DEPTH: (ft) TOTAL VOLUME PURGED: w (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
R
D
030 I (sec) I (sec) ( Low Flow Sampling Stabilization Criteria
• pH t 0.1 standard unit
• Specific Conductance t 5% in pS/cm
• DO f 0.2 mg/t
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
—ORP
TURBIDITY
(FT)
(x.xx)
(mUrnin)
(x)
(gallons OR mL)
(x.xx)
VC)
W
(mg/L)
(x.xx)
(NS/cm)
(x)_
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
dIV&
—
SOD
0-so
z1
6.65_
51Zq
U-2
Y3/
OSf'
rxjoti
Sw
/.w
2�
l.�'t
Srsv
y�H
y`�n
a6
rL.CA.. t Ktrttt I U 111E bAUK OF I HIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? [EYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? [—}YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR on 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH Ran Minor Strong
ADDITIONAL NOTES:
APPEARANCE le Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 12/17/2018 RDP