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Home My WebLink About8805_ROSCANS_2011March 2, 2011 Troy Harrison G L A T F E L T E R Beyon d Paper NCDENR -DWM Regional Office Solid Waste Section 2090 U.S. 70 Highway Swannanoa, NC 28778 Dear Mr. Harrison, RECEIVED MAR -9 2011 In compiling the 2010 annual landfill report, we discovered that the water sample collected in July from the drain pipe at the toe of the Sludge Landfill was not tested for dioxin. Subsequently, we requested the lab to resample this discharge and analyze for dioxin. Enclosed is a revised copy of the 2010 landfill report on a CD that includes the dioxin test report from the lab. Ervin Lane has been sent separately a copy of the revised CD and a paper copy of the dioxin test report for updating his notebook. Please let me know if you have any questions or need anything else. 7)}/12k~ D. Mike Cody Special Project and Analytical Services Manager cc: Ervin Lane NCDENR -DWM Central Office Solid Waste Field Operations Branch 1646 Mail Service Center Raleigh, NC 27699-1646 Spring Grove Facility 228 South Ma in Street· Sprin g Grove, PA 17362 U.S.A.· Phone 717-225-4711 • Fax 717-225-5400 www.glatfelter.com INSTRUCTIONS FOR UPDATING THE GLATFELTER 2010 ANNUAL LANDFILL REPORT 1. Replace the CD in the front of the notebook with the enclosed CD, Revision 1 . 2. After the Sludge Landfill July Lab Data divider tab ... a. Remove the first page and replace it with the enclosed revised page titled Sludge Landfill. b. Add the Pace Analytical Test Report, Project No. 10148216, at the end of this section. SLUDGE LANDFILL PACE ANALYTICAL TEST RESULTS PROJECT NO. 9272939, 10133243 and 10148216* (July 2010) *In compiling the 2010 annual landfill report, it was discovered that the water sample collected in July from the drain pipe at the toe of the Sludge Landfill was not tested for dioxin. Subsequently, Pace Analytical was requested to resample this discharge and analyze for dioxin. The test results are contained in Project No. 10148216. ace Analytical" www.pacelabs.com Report Prepared for: Lorri Patton PACE Charlotte 9800 Kincey A venue Huntersville NC 28078 REPORT OF LABORATORY ANALYSIS FOR TCDD Report Prepared Date: February 7, 2011 Report No ..... 10148216_ 1613 Pace Analytical Services, Inc. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607 .1700 Fax: 612.607.6444 Report Information: Pace Project#: 10148216 Sample Receipt Date: 01/27/2011 Client Project#: 9286520 Client Sub PO #: N/ A State Cert #: 27700 Invoicing & Reporting Options: The report provided has been invoiced as a Level 2 2,3,7,8-TCDD Report. Ifan upgrade of this report package is requested, an additional charge may be applied. Please review the attached invoice for accuracy and forward any questions to Nate Habte, your Pace Project Manager. This report has been reviewed by: Scott Unze, Project Manager (612) 607-6383 (612) 607-6444 (fax) scott. unze@pacelabs.com Report of Laboratory Analysis This report should not be reproduced, except in full, without the written consent of Pace Analytical Services. Inc. The results relate only to the samples included in this report. Page 1 of 13 DISCUSSION Pace Analytical Services, Inc. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 This report presents the results from the analysis performed on one sample submitted by a representative of Pace Analytical Services, Inc. The sample was analyzed for the presence or absence of 2,3, 7,8-tetrachlorodibenzo-p-dioxin (2,3, 7,8-TCDD) using a modified version of US EPA Method 16138. The reporting limits were set to correspond to the lowest calibration point and a nominal 1-Liter sample amount. The isotopically-labeled TCDD internal standard in the sample extract was recovered at 92%. All of the labeled standard recoveries obtained for this project were within the target ranges specified in Method 16138. Also, since the quantification of the native TCDD was based on isotope dilution, the data were automatically corrected for recovery and accurate values were obtained. A laboratory method blank was prepared and analyzed with the sample batch as part of our routine quality control procedures. The results show that 2,3,7,8-TCDD was not detected, indicating that the sample processing steps were free of background levels of this congener. Laboratory spike samples were also prepared using clean water that had been fortified with native standard material. The results show that the spiked native TCDD was recovered at 93-95%, with a relative percent difference of 2.1 %. These results indicate high degrees of accuracy and precision for these determinations. Matrix spikes were not prepared with the sample batch. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No ..... 10148216_ 1613 Page 2 of 13 ( Authority Alabama Alaska Arizona Arkansas California Colorado Connecticut EPA Region 5 EPA Region 8 Florida (NELAP Georgia (DNR) Guam Hawaii Idaho Illinois Indiana Indiana Iowa Kansas Kentucky Louisiana Maine Maryland Michigan Minnesota Mississippi TM Minnesota Laboratory Certifications Certificate # Authority 40770 Montana MN00064 Nebraska AZ0014 Nevada 88-0680 New Jersey (NE 01155CA New Mexico MN00064 New York (NEL PH-0256 North Carolina WD-15J North Dakota 8TMS-Q Ohio E87605 Ohio VAP 959 Oklahoma 09-019r Oregon (ELAP) SLD Oregon (OREL MN00064 Pennsylvania 200012 Saipan C-MN-01 South Carolina C-MN-01 Tennesee 368 Tennessee E-10167 Texas 90062 Utah (NELAP) LA0900016 Virginia 2007029 Washington 322 West Virginia 9909 Wisconsin 027-053-137 Wyoming MN00064 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No ..... 10148216 __ 1613 Pace Analytical Services, Inc. 1700 Elm Street -Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Certificate # 92 MN00064201 OA MN002 MN00064 11647 27700 R-036 4150 CL 101 09922 MN200001-005 M N200001-005 68-00563 MP0003 74003001 2818 02818 T104704192-08 PAM 00251 C755 9952C 999407970 8TMS-Q Page 3 of 13 Appendix A Sample Management Report No ..... 10148216_ 1613 Pace Analytical Services, Inc. Page 4 of 13 :~ain of Custody (D "O 0 ;:i korder: 9286520 _CAii Patton :::,~ Analytical Services, Inc. ~800 Kincey Ave., Suite 100 -iJ&ersville, NC 28078 :::,twe (704)875-9092 =ax (704)875-9091 .....>. -u OJ (Q (D 01 0 f·~ ....... .....>. (.,) 'ednesday, January 26, 2011 3:16:23 PM oc Pace Analytical Minnesota 1700 Elm Street SE Suite 200 Minneapolis, MN 55414 Phone (612)607-1700 N cS x Received on Ice or N ~e~!!~· I Results Requested By: 2/16/2011 LAB USE ONLY Y or N \ .... FMT-ALL-C-002rev.OO 24March2009 Page 1 of r:z~· Sc1mple Condition Upon Receipt Client Name: ___ V ..... -a_r..._e _)(_6 ___ _ Project# /O !(I&{)?- 1 ourler: ~ed Ex CJ UPS O USPS O Client D Commercial CJ Pace Other , racking##: 'b:Jo 7 V-t W) DOL6 .. / --- Custody Seal on CooJerJBox Preaent: a yes D no Seals Intact: ~s D no Packing Material: D Bubble Wrap ,· ~ubble Bags O None D Other ___ Temp Blank: Yes _ No ·J Thermometer Used 80344042 oa' Type of loe: ~ Blue None Cooler Temperature Blologlcal Tlsaua ls Frozen: Yes No D Samples on fee, cooling process has begun Date and lnlllale o~'!!rao":~lng contente:) I ?:Tu l ~ Temp should be above freezing to 6°0 Chain of Custodv Present: Chain of Custodv Fiiied Out: Chain of Custody Relinquished: Sampler Narne & Signature on COC: Samples Arrived within Hold Time: Short Hold Time Analvala l<72hr): Ruah Turn Around Time~ Sufficient Volume: Correct Containers Used: -Pace Containers Used: Containers Intact: Fiitered volume received for Dissolved tests . mple Labels match COC: ·Includes date/time/ID/Analysis Matrix: All containers needing acldlbue presa!Vatlon have bean checked. Noncomollance ara noted In 13. All contalne,. needing preservation are found to be In compliance wHh EPA recommendaUon. Comments: efves ClNo ON/A 1. ~s ONo ON/A 2. rives ON~ ON/A 3. Ov,a °"° CINIA 4. £ves 0"" DNIA 5. Oves r3'~ ON/A 6. 0Vfa °'° ON/A 7. ~es ONo ON/A 8. lifv~ No ONIA 9. Gft,/ ONo ON/A DY~ 0; ~A 11. fiihes 0No ON/A 12 . Vv1 0Yes ONo CJfuA 13. ,..,/,IA Samp # Oves ONo 'rJ'IIM E><cep!lons: VOA,Collfonn, roe. Oii and Greass, Wl·OAO (Water: OYes r£io Initial when completed Samples checked for dechlorination: HeadlDflee In VOA Viale { >6mm): Trip Blank Present: Trip Blank Custody Seals Present Pace TriP Blank Lot# (If ourchased): Cllent Notification/ Resolution: Ovea ONo 0V88 ONo Dves ONo OYes ONo ~A 14. °"~ 15. f)(uA 16. ~A Person Contacted: Date/Time: O HN03 O H2S04 ' Lot# of added preservative O NaOH Ffeld Data Required? O HCI Y I N ~~~~~~~~~~~~ ~~~~~~~-- Comments/ Resolution: ~~~~~~~~~~~~~~~~~~~--~~~~~~~~~~~~~~- L Project Manager Review: Date: 1/;; I 1) --~,--..... ~, .... -------- Note: Whenever there Is a discrepancy affecting North Carolina compliance samples, a copy Of this form wlll be sent to tttefNmlhl'Cbat-.i SIIMl!la, Inc. F·L213Rev.OO, 05Aug2009 1700 Elm Street SE, Suite 200, Minneapolis, MN 55414 Report No ..... 10148216_ 1613 Page 6 of 13 ( ace Analytica( Reporting Flags A = Reporting Limit based on signal to noise B = Less than 1 Ox higher than method blank level c = Result obtained from confirmation analysis D = Result obtained from analysis of diluted sample E = Exceeds calibration range I = Interference present J = Estimated value Nn = Value obtained from additional analysis p = R = s = u = v = x = y = * = PCDE Interference Recovery outside target range Peak saturated Analyte not detected Result verified by confirmation analysis %0 Exceeds limits Calculated using average of daily RFs See Discussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No ..... 101482161613 Pace Analytical Services, Inc. 1700 Elm Street -Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Page 7 of 13 Appendix B Sample Analysis Summary Report No ..... 10148216_ 1613 Pace Analytical Services, Inc. Page 8 of 13 ( ace Analytica( Client's Sample ID Lab Sample ID Filename Injected By Total Amount Extracted % Moisture Method 16138 Sample Analysis Results Client -PACE Charlotte SWP-1 9286520001 U110202B_13 SMT 962ml NA Water NA Pace Analytical Services, Inc. 1700 Elm Street -Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Dry Weight Extracted ICALID CCal Filename( s) Method Blank ID NA U101204A U110202A_18 BLANK-277 42 Matrix Dilution Collected Received Extracted Analyzed 01/26/2011 13:30 01/27/2011 09:30 02/01/2011 13:00 02/03/2011 06:54 Native Isomers 2,3,7,8-TCDD Cone pg/L ND EMPC pg/L RL pg/L 10 Cone= Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration RL = Reporting Limit. Internal Standards 2,3,7,8-TCDD-13C Recovery Standard 1,2,3,4-TCDD-13C Cleanup Standard 2,3, 7,8-TCDD-37Cl4 ND = Not Detected NA = Not Applicable NC = Not Calculated REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No ..... 10148216_ 1613 ng's Added 2.00 2.00 0.20 Percent Recovery 92 NA 90 Page 9 of 13 ( ace Analytical" Method 16138 Blank Analysis Results Lab Sample ID BLANK-277 42 Filename U110202A_ 11 Total Amount Extracted 1020 ml !CALIO U101204A CCal Filename(s) U110202A_03 Native Cone EMPC RL Isomers pg/L pg/L pg/L 2,3,7,8-TCDD ND 10 Cone= Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration RL = Reporting Limit Matrix Dilution Extracted Analyzed Injected By Internal Standards 2,3,7,8-TCDD-13C Recovery Standard 1,2,3,4-TCDD-13C Cleanup Standard 2,3, 7,8-TCDD-37Cl4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No ..... 10148216 1613 Pace Analytical Services, Inc. 1700 Elm Street -Suite 200 Minneapolis, MN 55414 Water NA 02/01/2011 02/02/2011 SMT ng's Added 2.00 2.00 0.20 Tel: 612-607-1700 Fax: 612-607-6444 13:00 14:54 Percent Recovery 87 NA 86 Page 10 of 13 ( ace Analytical TM Pace Analytical Services, Inc. 1700 Elm Street -Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Method 16138 Laboratory Control Spike Results Lab Sample ID LCS-27743 Filename U110202A_06 Total Amount Extracted 1020 ml ICALID U101204A CCal Filename U110202A_03 Method Blank ID BLANK-277 42 Compound Cs 2,3,7,8-TCDD 10 2,3, 7,8-TCDD-37Cl4 10 2,3,7,8-TCDD-13C 100 Cs= Concentration Spiked (ng/ml) Cr= Concentration Recovered (ng/ml) Rec. = Recovery (Expressed as Percent) Cr 9.3 8.6 81 Control Limit Reference: Method 1613, Table 6, 10/94 Revision R = Recovery outside of control limits Nn = Value obtained from additional analysis * = See Discussion Matrix Water Dilution NA Extracted 02/01/2011 Analyzed 02/02/2011 Injected By SMT Lower Upper Limit Limit 7.3 14.6 3.7 15.8 25.0 141.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No ..... 10148216 1613 13:00 10:54 % Rec. 93 86 81 Page 11 of 13 ( ace Ana/Vfjca/TM Pace Analytical Services, Inc. 1700 Elm Street -Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Method 16138 Laboratory Control Spike Results Lab Sample ID LCSD-27744 Filename U110202A_07 Total Amount Extracted 1030 ml !CALIO U101204A CCal Filename U110202A_03 Method Blank ID BLANK-277 42 Compound Cs 2,3,7,8-TCDD 10 2,3,7,8-TCDD-37Cl4 10 2,3,7,8-TCDD-13C 100 Cs = Concentration Spiked (ng/ml) Cr= Concentration Recovered (ng/ml) Rec. = Recovery (Expressed as Percent) Cr 9.5 8.9 92 Control Limit Reference: Method 1613, Table 6, 10/94 Revision R = Recovery outside of control limits Nn = Value obtained from additional analysis * = See Discussion Matrix Water Dilution NA Extracted 02/01/2011 Analyzed 02/02/2011 Injected By SMT Lower Upper Limit Limit 7.3 14.6 3.7 15.8 25.0 141.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No ..... 10148216_ 1613 13:00 11 :42 % Rec. 95 89 92 Page 12 of 13 ( ace Analytical TM Method 16138 Pace Analytical Services, Inc. 1700 Elm Street -Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Spike Recovery Relative Percent Difference (RPD) Results Client PACE Charlotte Spike 1 ID LCS-27743 Spike 2 ID LCSD-27744 Spike 1 Filename U110202A_06 Spike 2 Filename U110202A_07 Spike 1 Spike 2 Compound %REC %REC %RPD 2,3,7,8-TCDD 93 95 2.1 %REC= Percent Recovered RPO = The difference between the two values divided by the mean value REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No ..... 10148216 _ 1613 Page 13 of 13