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HomeMy WebLinkAbout6003_Mecklenburg_YorkRoad_MSWLF_CAER_FID1817134_20230831ENR USE ONLY: OPaper Report ❑Electronic Data - Email CD data loaded: Yes / No Doc/Event #: NC DENR Environmental Monitoring Division of Waste Management - Solid Waste Reportina Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e g. naturally occurring, off -site source, pre-existing condition, etc.) Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits Attach a notification table of any methane gas values that attain or exceed explosive gas levels This includes any structures on or nearby the facility (NCAC 138 .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. bona waste monitori Name of entity submitting Data Submittal Information i (laboratory, consultant, facility owner): Geosyntec Consultants of NC, P.C. Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Amy Kenwell E-mail: AKenwell@Geosyntec.com Facility name: City of Charlotte Former York Road Landfill Facility Address: 1525 West Tyvola Road Charlotte, NC 28217 Phone: (704) 227-0843 NC Landfill Rule: Actual sampling dates (e g., Facility Permit # (.0500 or .1600) October 20-24, 2006) Not Applicable - Corrective 60-03 0500 Action Evaluation Report presenting previously reported data Environmental Status: (Check all that apply) Initial/Background Monitoring 0 Detection Monitoring 0 Assessment Monitoring _f Corrective Action T e of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Methane gas monitoring data Groundwater monitoring data from private water supply wells Corrective action data (specify) Leachate monitoring data Surface water monitoring data Other(specify) Notification attached? e No. No groundwater or surface water standards were exceeded. Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct, Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Amy Kenwell Senior Geologist (704) 227-0843 Facility Representative Na a (Print) Title 8/31 /2023 Sign 1t a Date 1300 South Mint Street Suite 300, Charlotte, NC, 28203 Facility Representative Address C-3500 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 (Area Code) Telephone Number Affix NC vGeologist Seal C A -.E. N �� ti 2518 �..;,a�oG�., m�a®tea ❑ K���`�� �'d'►Y�a�i104it � Prepared for City of Charlotte General Services Department 600 East 4th Street CHARLOTTET. Charlotte, NC 28202 CORRECTIVE ACTION EVALUATION REPORT FORMER YORK ROAD LANDFILL NCDEQ PERMIT NO. 60-03 WEST TYVOLA ROAD AND SOUTH TRYON STREET CHARLOTTE, NORTH CAROLINA Prepared by.• Geosyntec° consultants Geosyntec Consultants of NC, P.C. 1300 S. Mint St., Suite 300 Charlotte, NC 28203 Project Number: GC5699H August 2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 TABLE OF CONTENTS 1. INTRODUCTION................................................................................................ 5 1.1 Site Description and Background................................................................ 5 1.2 Aquifer Characteristics................................................................................ 6 1.3 Contaminant Distribution............................................................................ 8 1.3.1 Saprolite and PWR Groundwater................................................... 9 1.3.2 Bedrock Groundwater.................................................................. 10 1.4 Description of Site Conceptual Model ...................................................... 12 1.5 Regulatory Status....................................................................................... 14 2. CORRECTIVE ACTION SUMMARY............................................................. 17 2.1 Aquifer Conditions and Plume Characteristics ......................................... 17 2.1.1 Physical Changes in Aquifer Characteristics .................................... 17 2.1.2 Chemical Changes in Aquifer Characteristics .................................. 17 2.1.3 Physical Changes in Plume Characteristics ...................................... 18 2.1.4 Chemical Changes in Plume Characteristics .................................... 18 2.2 Refining the Site Conceptual Model......................................................... 19 2.3 Evaluation of Impacts................................................................................ 21 2.3.1 Contaminant Concentrations........................................................ 22 2.3.2 Impacts at Point of Compliance ................................................... 27 2.3.3 Off -Site Migration Evaluation...................................................... 30 4. SUMMARY, CONCLUSIONS, AND RECOMMENDATIONS ..................... 33 4.1 Summary and Conclusions........................................................................ 33 4.2 Recommendations..................................................................................... 34 5. REFERENCES................................................................................................... 36 GC5699H/CAR230086 3 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former Pork Road Landfill, Charlotte, North Carolina August 2023 LIST OF TABLES Table 1 Groundwater Well Construction Details Table 2 Historical Groundwater Elevations Table 3 Historical Groundwater Monitoring Data Table 4 Existing Groundwater and Surface Water Sampling Schedule Table 5 March 2023 Detected Constituents in Groundwater Table 6 Summary of Mann -Kendall Trend Analysis for VOCs Table 7 Historical Vertical Hydraulic Gradients Table 8 March 2023 Detected Constituents in Surface Water Table 9 Proposed Groundwater and Surface Water Sampling Schedule LIST OF FIGURES Figure 1 Site Location Map Figure 2 Site Plan Figure 3 Unconsolidated Potentiometric Surface Map (2 March 2023) Figure 4A Plume Map — Saprolite Figure 4B Plume Map — PWR Figure 4C Plume Map — Bedrock Figure 5A DMW-01 and DDW-01 Time Trends Figure 5B DDW-02, DDW-03, DMW-01, and DMW-06 Time Trends LIST OF APPENDICES Appendix A Site Current Conditions Photolog Appendix B Boring Logs and Cross -Sections Appendix C Sample Field Sampling Sheets Appendix D Sample Chain of Custody Appendix E Geophysical Investigation Appendix F Receptor Survey Map Appendix G Biochlor Model Appendix H Groundwater PFAS Analytical Data Summary (Police & Fire Training Academy) GC5699H/CAR230086 4 08.2023 Geosyntec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 1. INTRODUCTION On behalf of the City of Charlotte, Geosyntec Consultants of NC, P.C. (Geosyntec) has prepared this Corrective Action Evaluation Report (CAER) for the City of Charlotte's former York Road Landfill (Figure 1). This report presents an updated Assessment of Corrective Measures prepared in 2003 by Delta Environmental Consultants, Inc. (Delta) based on the results of assessment and mitigation activities conducted through May 2023 of groundwater and surface water monitoring conducted at the former landfill. As requested by Jaclynne Drummond of the North Carolina Department of Environmental Quality (NCDEQ) on a 13 February 2023 call, this CAER was prepared in general accordance with the NCDEQ Solid Waste Section Guidelines for Corrective Action Evaluation Reports. This report focuses on groundwater and surface water conditions at the Site and does not address landfill gas which is managed as described in the Water Quality and Landfill Gas Monitoring Plan ("Monitoring Plan"; Geosyntec, 2017). While the 2003 Delta report did not identify a remedy, a 2009 email between Hart & Hickman and Jaclynne Drummond referenced the collection of monitored natural attenuation (MNA) parameters. Following approximately 20 years of groundwater and surface water monitoring, the Conceptual Site Model (CSM) has been re-evaluated herein and the characteristics of the impacted groundwater plume, which include select volatile organic compounds (VOCs) and metals (described in Section 1.3), have been re -visited. A re-evaluation of the remedial approach was conducted including the spatial, temporal, and analytical monitoring requirements. 1.1 Site Description and Background The former York Road Landfill (herein referred to as the "Site") is an approximately 400- acre site located along West Tyvola Road and South Tryon Street (Highway 49) in Charlotte, Mecklenburg County, North Carolina (Figure 1). The Site was operated as an unlined municipal solid waste landfill from approximately 1968 to 1986, with the last expansion occurring in 1983 (under NCDEQ Facility Permit Number 60-03). The landfill waste placement area consisted of a total of approximately 168-acres, which was divided into six cells referred to as Landfill Areas A through F, as shown in Figure 2. The precise locations of waste placement boundaries are uncertain and have been estimated based on historical drawings by others and electromagnetic mapping. During operation, GC5699H/CAR230086 5 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 commercial, industrial, and domestic solid wastes were added to the landfill using excavation -and -fill and ramp disposal techniques. The former landfill was developed with the construction of West Tyvola Road, a golf course, and a recreational park following closure in 1986. Today, the Site is utilized by the Harry L. Jones, Sr. Golf Course (formerly Renaissance Park Golf Course) and Renaissance Park, which includes recreational facilities for softball, volleyball, skateboarding, walking, hiking, biking, dog exercise, and disc golf. A photographic log of current Site conditions is included in Appendix A. 1.2 Aquifer Characteristics The Site is located within the Charlotte Belt of the Piedmont Physiographic Province. The topography of the Piedmont Province is generally characterized by gently rolling hills ranging in elevation from approximately 300 to 1,200 feet (ft) above mean sea level (AMSL), and the Site elevation ranges from approximately 580 in the northeast to 680 ft AMSL near Sugar Creek to the southwest. Geologically, the province is comprised primarily of crystalline metamorphic rocks (schists and gneiss, and to a lesser extent, phyllite and slate) of Precambrian to Paleozoic age. These units are often highly deformed with multiple fracture and foliation planes, which promote anisotropic groundwater flow. The occurrence and movement of groundwater at the Site is typical of the Piedmont formation, and generally occurs within three hydrogeologic units. Site monitoring wells are screened in each, as summarized in Table 1. Two shallow hydrogeologic units typically occur within the soils and saprolite (weathered residuum which mantles bedrock). The saprolite consists of a mixture of silty sands, clayey sands, silts, and sands coarsening with depth that are up to 20 feet thick. A deeper hydrogeologic unit is generally associated with secondary porosity (fractures or open spaces) within the crystalline bedrock. An approximately 5-foot thick transition zone of fractured bedrock occurs between saprolite and bedrock and is generally referred to as partially weathered rock (PWR). Boring logs and cross -sections developed by Delta are included in Appendix B. The depth to groundwater at the Site ranges from an average of 2 feet below ground surface (ft bgs) in bedrock well DDW-03A near Sugar Creek to approximately 55 ft bgs in PWR well DMW-08 to the east. Groundwater elevations since 2006 have ranged from 548.98 ft AMSL (bedrock well DMW-02A in September 2012) to 647.11 ft AMSL (saprolite well DMW-A in September 2020, disregarding a suspected anomalous value GC5699H/CAR230086 6 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 in September 2009 which was approximately 25 feet above average and anticipated to be erroneous) as shown in Table 2. Groundwater flow in the shallow hydrogeologic units are controlled by local topographic features, with recharge occurring in upland areas and discharge occurring in drainage features such as streams, rivers, or lakes. At the Site, groundwater flows towards Sugar Creek on the southwestern boundary with some influence from the North and South tributaries to Sugar Creek which run through the Site on either side of a north -south trending bedrock ridge (Figure 3). The groundwater flow south of the Site has been impacted by the construction of a multi -family residential complex with a man-made pond located approximately 400 ft south of DMW-02A. In September 2018, the average water table elevation at DMW-02A began to rise and the timing correlated to the residential complex construction. Increases in water table elevations at DMW-02 and DMW-02A since 2018 may be a result of the proximity of these monitoring wells to the residential complex and man-made pond. Recharge to the shallow hydrogeologic unit is primarily the result of infiltrating precipitation. Groundwater flow in the bedrock water -bearing zone is controlled by the distribution and degree of interconnection of openings in the rock. Sustained well yields in the Piedmont were reported to average 15 to 30 gallons per minute (gpm) (Charles C. Daniel, III and R.A. Payne, 1990; as referenced in Delta, 2003). Slug tests performed on Site wells in 1996 indicated a saprolite and PWR hydraulic conductivity of 2.71 feet per day (ft/day) to 5.45 ft/day (Delta, 2003). Geosyntec anticipates that this hydraulic conductivity may be dominated by the coarser PWR unit and that the shallow saprolite, particularly where higher silt content exists, may have substantially lower hydraulic conductivity. The bedrock hydraulic conductivity was reported to be between 0.02 ft/day to 5.88 ft/day and were highly dependent on the weathering and fracture network, generally decreasing with depth (Delta, 2003). Delta also calculated estimated groundwater flow velocities using a grain size correlation to estimate effective porosity. The average gradient used in their calculation was 0.011 ft/ft which is similar to the gradient most recently measured in March 2023 of 0.013 ft/ft, which has remained very consistent in recent years. The calculated groundwater flow velocity was reported to be 0.53 ft/day for saprolite and PWR, 1.43 ft/day for upper bedrock, and 0.026 ft/day for lower bedrock (Delta, 2003). Based on this velocity, groundwater located at DMW-A (the furthest upgradient well) during Delta's reporting in 2003 would take approximately 25 years to reach DMW-05 along Sugar Creek in the saprolite/PWR zone. This suggests that groundwater from the farthest reaches of Landfill GC5699H/CAR230086 7 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 Area F, installed through 1986, has likely already reached the property boundary. At least one pore volume of groundwater beneath the landfill cells has likely moved through the system and groundwater at the property boundary in 2023 represents water migrating from upgradient following landfill placement. Decreased groundwater VOC concentrations detected in Site monitoring wells likely result from degradation of the contaminant sources within the waste over time. Additional details on aquifer characteristics and geologic studies are included in Delta's report (2003). 1.3 Contaminant Distribution A summary of previous water quality investigations was provided in the 2003 report by Delta. Groundwater monitoring was first conducted in 1981 and continued intermittently through 1996. Quarterly reporting of groundwater conditions began in 1998 and transitioned to semi-annual in 1999. The present-day groundwater monitoring network shown on Figure 2 was complete by 2015. Well construction details are provided in Table 1, historical groundwater elevations (March 2006 through March 2023) are summarized in Table 2, historical groundwater sampling analytical results (March 2008 through March 2023) are included in Table 3 and the existing groundwater and surface water sampling schedule is included in Table 4. Contaminants of concern (COCs) identified in the 2003 report by Delta included benzene, chloroethane, cis-1,2-dichloroethene (cis-1,2-DCE), 1, 1 -dichloroethane (1,1-DCA), 1,2-dichlorobenzene, 1,4-dichlorobenzene, 1,2-dichloropropane, tetrachloroethene (PCE), tichloroethene (TCE), and vinyl chloride. In 2023, groundwater COCs with concentrations above respective NCDEQ Title 15A of the North Carolina Administrative Code (NCAC), Subchapter 2L Standards include 1,4-dioxane, 1,1-DCA, 1,2-dichloroethane (1,2-DCA), 1,2-dichloropropane, 1,4-dichlorobenzene, benzene, TCE, PCE, and vinyl chloride. Chloroethane, cis-1,2-DCE, and 1,2-dichlorobenzene have been removed from the COC list while 1,2-DCA and 1,4-dioxane were added. In addition, metals including barium, cadmium, iron, lead, and manganese were added to the COC list. In 2003, iron and manganese were detected above 2L Standards but were considered background concentrations. The following sections present contaminant distributions in the saprolite, PWR, and bedrock units as shown on Figures 4A through 4C. Contaminant distribution is anticipated to potentially extend off -Site in bedrock to the southeast but be limited to the GC5699H/CAR230086 8 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 southwest by Sugar Creek, which is a hydraulic divide between Site groundwater and off - Site groundwater. The shallow groundwater elevation at DDW-03A (Table 2) and consistent upward hydraulic gradient at the DDW-03A/DDW-03/DMW-06 and DDW-OIA/DDW-01 well nests support this though there may be a seasonal downward gradient at the DDW-02/DMW-05 well cluster in March of most years (Table 5). DMW-05 is screened to 20 ft bgs across PWR and saprolite where the upward gradient is not as consistent as between bedrock and saprolite/PWR. In addition to Site data, a network of 14 saprolite/PWR wells and eleven bedrock wells located west of Sugar Creek indicate that the horizontal hydraulic gradient is to the east towards Sugar Creek (Hart & Hickman, 2023). This off -Site data confirms that Sugar Creek acts as a hydraulic divide in the saprolite and PWR groundwater. 1.3.1 Saprolite and PWR Groundwater As summarized in Table 1, 20 monitoring wells that are part of the current monitoring network are screened in the saprolite and PWR zones (including one well screened across PWR and bedrock). The saprolite and PWR units are discussed together in this section as several well screens overlap between saprolite and PWR. Nine (9) saprolite/PWR wells are monitored for groundwater quality (Table 4). Most of the analytical monitoring network is located along the downgradient (southwestern and southeastern) boundaries of the Site. L3.L1 VOCS March 2023 analytical results from the saprolite and PWR wells indicate VOCs above respective NCDEQ 2L Standards in select wells along the downgradient boundary including DMW-05 (1,4-dioxane), DDW-02 (1,1-DCA and 1,4-dioxane), DMW-06 (1,2-dichloropropane, 1,4-dichlorobenzene, 1,4-dioxane, TCE, and vinyl chloride), DDW-03 (1,2-dichloropropane, 1,4-dioxane, and vinyl chloride), and DMW-01 (vinyl chloride) as summarized in Table 6 and on Figures 4A through 4B. Many VOC concentrations hover within an order of magnitude of the 2L Standard and some vary from exceedance to non-exceedance between sampling events. For example, benzene at DMW-01 was above the NCDEQ 2L Standard in September 2015, September 2018, September 2019, and September 2021 but below the NCDEQ 2L Standard in 12 other monitoring events between 2015 and 2023 (Table 3-F). Mann -Kendall analyses (summarized in Table 7 and described further in Section 2.3.1.1) indicate primarily decreasing trends of VOCs with NCDEQ 2L Standard exceedances in March 2023. GC5699H/CAR230086 9 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 Following the March 2023 monitoring, Mann -Kendall analyses identified an increasing trend of 1,4-dichlorobenzene at DMW-06 and decreasing trends for remaining saprolite and PWR wells with 2L Standard exceedances. 1.3.1.2 Metals Iron and/or manganese were above the respective 2L Standards in six PWR/saprolite wells in March 2023 including YRW-IOC, DMW-05, DMW-06, DMW-02, DMW-01, and DMW-08. Three of these wells (YRW-IOC, DMW-02, and DMW-08) are located approximately cross -gradient of the landfill cells and the concentrations of iron and manganese do not appear to correlate well with elevated VOC impacts, though this could be a result of waste heterogeneity. This was also noted in the 2003 report, where iron and manganese were attributed to background conditions. While iron and manganese did not exceed 2L Standards in upgradient well DMW-A, they could be released from lithologic units through changes in groundwater characteristics (pH, oxidation, etc.) caused by the waste. YRW-1 OC, which is only downgradient of the edge of a waste cell, has historically had the highest concentrations of iron in groundwater (Table 3). In 2023, cadmium was above the 2L Standard of 2 micrograms per liter (µg/L) in monitoring well DMW-01 which is located just outside Landfill Area A on the southeastern property boundary. Cadmium is fairly consistently above the 2L Standard at DMW-01 with historical concentrations up to 63 µg/L since 2008. While cadmium has periodically exceeded the 2L Standard in other Site wells, the concentrations are less than 5 µg/L so the cadmium impacts appear fairly localized near DMW-01, potentially as a result of the waste composition in this area. 1.3.2 Bedrock Groundwater As summarized in Table 1, seven (7) monitoring wells that are part of the current monitoring network are screened in the bedrock zone, five (5) of which (DDW-01, DDW-01A, DDW-03A, DMW-02A, and DMW-0213) are monitored for groundwater quality. Two of the bedrock monitoring wells (DDW-01 and DDW-01A) are located along the southwestern boundary of the Site, one (DDW-03A) in the southernmost point at the confluence of Sugar Creek and the South Tributary, and two (DMW-02A and DMW-0213) off -Site to the south. GC5699H/CAR230086 10 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 1.3.2.1 VOCs March 2023 analytical results from these wells (summarized in Table 6 and on Figure 4C) indicate 2L Standard exceedances in the wells along the southwestern boundary (DDW-01 and DDW-OIA). These wells are co -located, and open from 45 to 60 ft bgs and 90 to 100 ft vgs, respectively. Only TCE and vinyl chloride exceeded 2L Standards in both wells in March 2023. Benzene and 1,4-dioxane additionally exceeded respective 2L Standards in the deeper well (DDW-OIA) while 1,1-DCA, 1,2-dichloropropane, and PCE exceeded 2L Standards in the shallower well (DDW-01). As with the saprolite and PWR, many VOC concentrations are within an order of magnitude of the NCDEQ 2L Standard and some vary from exceedance to non-exceedance between sampling events (for example, benzene at DMW-02B as shown in Table 3-I). Mann -Kendall analyses (summarized in Table 7 and described further in Section 2.3.1.1) indicate primarily decreasing trends. Following the March 2023 monitoring, Mann -Kendall analyses identified increasing trends of TCE and vinyl chloride at DDW-01A and 1,1-DCA and TCE at DDW-01. Data indicate the concentrations of VOCs in bedrock at this location along Sugar Creek appear to be increasing but impacts are not migrating to downstream bedrock wells. Most of the increasing trends are of PCE daughter products and may reflect reductive dichlorination. Concentrations of benzene exceeded the 2L Standard in DDW-03A, the bedrock well at the confluence of Sugar Creek and the South Tributary, in 2023 while other VOCs analyzed had concentrations below the 2L Standards. The co -located PWR and saprolite wells at this location had impacts of several VOCs including 1,2-dichloropropane, 1,4-dichlorobenzene, TCE, and vinyl chloride above the 2L Standards (Table 6) which do not appear to be migrating to bedrock, likely due to a consistently upward vertical hydraulic gradient at this location (Table 5). There were no VOC exceedances in off -Site bedrock monitoring well DMW-02A open from 35 to 47 ft bgs while the deeper well DMW-02B open from 74.5 to 84.5 ft bgs had exceedances of 1,2-DCA and 1,4-dioxane in March 2023. 1,2-DCA has not previously exceeded the 2L Standard at this well and 1,4-dioxane was analyzed for the first time in March 2023, however, other VOC exceedances occur historically at DMW-02B (Table 3-I). Benzene at DMW-02B first exceeded the 2L Standard in September 2017 which was prior to the change in hydraulic gradient. Vinyl chloride first exceeded the 2L Standard in September 2021, following the change in hydraulic gradient. The variation GC5699H/CAR230086 11 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 of these compounds from above to below the 2L Standard between monitoring events suggests the edge of a groundwater plume. The distribution of 1,4-dioxane results are inconsistent with a shallow on -Site source. Three of the wells with 1,4-dioxane 2L Standard exceedances had one or less other VOC 2L Standard exceedances (DDW-02, DMW-02B, DMW-05). In some cases (DDW-0 1 /DDW-0 I A, DMW-05/DDW-02, and DMW-02A/DMW-02B) the deeper well had higher 1,4-dioxane concentrations than the shallow well at the same location. Only at well cluster DMW-06/DDW-03/DDW-03A does the 1,4-dioxane concentration decrease in the bedrock well. This suggests that 1,4-dioxane in area groundwater may be comingling from multiple sources including potential off -Site sources. 1.3.2.2 Metals For metals, iron was above the 2L Standard of 300 µg/L in DDW-01 along the southwestern boundary with a concentration of 386 µg/L in 2023. Iron concentrations at this well have varied between 36,700 µg/L in 1995 and 55 µg/L in 2010. Iron has typically been below the 2L Standard at co -located deep well DMW-0IA. Barium and lead were above respective 2L Standards in off -Site well DMW-02A in the most recent monitoring data. Barium at DMW-02A has been consistent since approximately 2013 while the concentrations of lead have risen in 2022 and 2023. Recent changes of lead concentrations at this well may reflect installation of a man-made pond upgradient of DMW-02A which also caused an approximately 40-foot rise of groundwater elevation. Barium and lead have consistently been below the 2L Standard at co -located deep well DMW-02B. 1.4 Description of Site Conceptual Model A CSM was developed as part of the 2003 Assessment and Corrective Measures Report by Delta and is summarized below. Changes to the CSM are addressed in Section 2.2 Based on the Site stratigraphy, hydrogeology, and contaminant distribution, the following conclusions from Delta (2003) describe the occurrence, distribution, and potential movement of VOC-impacted groundwater at the Site: • The Site is underlain by approximately 40 to 50 feet of regolith (saprolite and PWR) consisting primarily of silty sand with some clayey sand, silt, and sand GC5699H/CAR230086 12 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 from weathering of igneous rocks. The PWR zone varies in thickness and transitions from finer grained soils to coarse grained soils as it approaches the bedrock. Bedrock consists of slightly fractured porphyritic metamorphosed quartz diorite, diorite, and tonalite beginning between 17 and 63 ft bgs. • In 2003, depth to groundwater was reported to be between approximately 3 ft bgs in the Sugar Creek floodplain to 25 ft bgs at higher elevations. The unconfined surficial aquifer has been encountered in the regolith and bedrock with no confining layer. • Groundwater generally flows to the west-southwest towards Sugar Creek, with localized flow to the North and South Tributaries which bisect the Site. • Hydraulic conductivity within the saprolite and PWR was calculated to range from 2.71 to 5.45 ft/day. Upper fractured bedrock hydraulic conductivity was calculated to be 3.89 to 5.88 ft/day while at depth it decreased to 0.02 to 0.05 ft/day. Average hydraulic gradient was calculated to be 0.011 ft/ft in regolith and 0.015 ft/ft in bedrock, resulting in estimated groundwater flow velocity of 0.53 ft/day in regolith and 1.43 ft/day in bedrock. Groundwater from fractured bedrock was believed to flow upwards to discharge into Sugar Creek and the tributaries at a rate of 0.026 ft/day. Recent data supports this theory, with consistent upward hydraulic gradients at most well nests adjacent to Sugar Creek, as discussed in Section 1.3.1. • VOCs had been identified in groundwater downgradient of the landfill waste cells but were not present within the first 25 feet of subsurface or beyond 65 ft bgs. Delta reported that dissolved VOCs were primarily observed in the PWR and upper fractured bedrock between 25 and 65 ft bgs. At the time, benzene, 1,2-dichloropropane, cis-1,2-DCE, PCE, TCE, and vinyl chloride with concentrations up to I I I µg/L were identified with the highest concentrations at DMW-01, along the southeastern property boundary. • The horizontal extent of VOC-impacted groundwater was estimated to be within approximately 500 feet downgradient of the edge of waste adjacent to Landfill Areas A and C near the southeastern Site boundary. GC5699H/CAR230086 13 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 • The vertical extent of VOC-impacted groundwater was estimated to be within the top 30 feet of bedrock at depths up to 65 ft bgs. Cross -sections from Delta's report are provided in Appendix B. These identified a preferential hydraulic pathway in the coarse PWR and upper fractured bedrock. VOC impacts from the landfill moved preferentially along this pathway and were not identified in shallower saprolite or deeper competent bedrock at the time. VOC impacts have been detected near the southwestern Sugar Creek and southeastern property boundaries. In 2003, VOCs were below 2L Standards at southwestern boundary compliance monitoring well DDW-02 where the compliance boundary was defined as 50 feet from the property boundary because there was insufficient space for a 250-ft boundary from waste. At well DDW-03, located 25 feet within the compliance boundary near the southwest corner of the Site, PCE, TCE, and vinyl chloride were detected above the respective 2L Standards suggesting that the edge of the plume was at or near the compliance boundary. On the southeastern property boundary, YRW-06A is located within the 250-ft compliance boundary while the boundary was adjusted to be 50 feet from the property boundary at DMW-01. Each well reported exceedances of the 2L Standards (TCE and vinyl chloride at YRW-06A and 1,2-dichloropropane and cis-1,2-DCE at DMW-01). Compliance monitoring wells for the deeper aquifer DDW-0IA, DDW-03A, DMW-02B, and DDW-06 did not have reported VOC concentrations above detection in February 2003. 1.5 Regulatory Status The York Road Landfill was closed under the 10 NCAC 10G, Section .0500 rules as referenced in the 21 August 1987 closure letter from the North Carolina Department of Human Resources, Division of Health Services. These regulations were transferred and recodified into title 15A NCAC 13B Solid Waste Management Rules, effective April 1990. The 2003 report by Delta lists Federal and State regulations with potential applicability at the Site, the following of which are considered likely applicable to the current Site operations: • 40 Code of Federal Regulations (CFR) Part I-99 of the Clean Air Act; GC5699H/CAR230086 14 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 o now potentially 40 CFR Chapter I, Subchapter C, Part 99 (reserved) • National Ambient Air Quality Standards (NAAQS), 29 CFR Part 1910 Occupational Safety and Health Administration (OSHA); o now references Title 40 CFR Part 50 for NAAQS though OSHA reference is still applicable • Fish and Wildlife Conservation Act; • 15A NCAC 13B — Solid Waste Management Rules; • 15A NCAC 213.0200 — Surface Water Quality; • 15A NCAC 213.0100 —Surface Water Discharges; o now references procedures for assignment of water quality standards. Section .0400 on effluent limitations may be more applicable but Section .0200 remains the most applicable for this Site. • 15A NCAC 2L.0200 — Ground Water Quality; • 15A NCAC 2D.0400 — Air Pollution Control Requirements; o now references ambient air quality standards • 15A NCAC 2D.0500 — Remediation System Emissions. Water quality and landfill gas monitoring at the Former York Road Landfill is conducted pursuant to the Water Quality and Landfill Gas Monitoring Plan ("Monitoring Plan"; Geosyntec, 2017), which was approved by the NCDEQ in a 7 March 2017 letter. The Groundwater and Surface Water Sampling Schedule from the Monitoring Plan, presented in Table 4, is conducted semi-annually, typically in March and September. Example field sampling sheets are included in Appendix C and an example chain of custody is included in Appendix D. As stated in the Monitoring Plan, the 15A NCAC 13B Section .0500 rules and closure letter for the Site do not specify landfill gas monitoring requirements. Therefore, landfill GC5699H/CAR230086 15 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 gas monitoring is regularly conducted in general accordance with the Monitoring Plan, which was developed to provide reasonable protection to public health and the environment. Select landfill gas monitoring points from this plan have been informally removed due to demolition, burial, or abandonment of the locations. Landfill gas monitoring is conducted on a quarterly basis (typically in January, April, July, and October). GC5699H/CAR230086 16 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 2. CORRECTIVE ACTION SUMMARY The following sections describe the changes in aquifer and plume conditions, the CSM, and an evaluation of impacts. Since the 2003 report by Delta, approximately 20 years of semi-annual groundwater and surface water monitoring has been conducted at the Site. Landfill gas management has also been conducted, including quarterly monitoring, installation or renovation of extraction systems near potential receptors, and installation of additional landfill gas and water level monitoring points. In 2017 and 2018, select portions of the waste boundary along Tryon Street, in Renaissance Park, and the northeast boundary were mapped by Geo Solutions Ltd. using Electromagnetic (EM) equipment (Appendix E). Figures in this report which show waste cells reflect this data. 2.1 Aquifer Conditions and Plume Characteristics The following sections describe physical and chemical changes to aquifer conditions and plume characteristics between 2003 and 2023. 2.1.1 Physical Changes in Aquifer Characteristics No physical changes in aquifer characteristics were observed other than a potential change in gradient along portions of the southeastern boundary of the Site which was previously more southwestward and is now more westward. Groundwater elevations have risen substantially to the south of the Site following construction of a multi -family residential complex with a man-made pond which may locally change the direction of groundwater flow from DMW-02, DMW-02A, and DMW-02B to be upgradient of the Site rather than cross -gradient. In addition, the EM survey identified the landfill waste boundary closer to South Tryon Street than initially anticipated and in one location is within 50 feet of the property boundary (Figure 2). Based on responses at different frequencies, Geo Solutions concluded that the composition of buried waste is primarily household garbage rather than abundant buried metallic materials. 2.1.2 Chemical Changes in Aquifer Characteristics No chemical changes in aquifer characteristics have been identified. Field pH has been recorded generally within one pH unit for individual wells from at least 2011 through 2023 (Table 3). Specific conductance field readings have remained generally within 500 microSiemens per centimeter (µS/cm) from at least 2011 through 2023 with the exception of decreasing specific conductance at DMW-02A (Table 3). DMW-02A historically had GC5699H/CAR230086 17 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 the highest specific conductance from the Site well network with a concentration over 8,000 µS/cm in 2011. By 2023, the specific conductance had decreased to less than 6,000 µS/cm. This well also has consistently shown a pH over 12 with one exception, which could indicate grout in the well so the specific conductance may not reflect aquifer conditions. Field observations have noted that landfill wastes have not undergone decomposition to the extent anticipated based on the age of the landfill cells. In select areas of Landfill Area D (Figure 2) where disposal occurred from 1980 through 1983, legible paper materials were observed in boring cuttings within the past ten years. 2.1.3 Physical Changes in Plume Characteristics The lateral extent of VOC-impacted groundwater appears to be similar to 2003 based on the available well network. Estimated plume diagrams based on total VOC concentrations (which was calculated as a summation of VOCs which exceeded the NCDEQ 2L Standard in one or more wells in March 2023) are shown on Figures 4A through 4C for saprolite, PWR, and bedrock, respectively. The vertical extent of impacts has increased in both directions in limited areas where data is available near DDW-01, DDW-02B, and DMW-05. Between 2003 and 2023, NCDEQ 2L Standard exceedances were observed in the DMW-05 shallow well screened from approximately 5 to 25 ft bgs (though the only detected VOC since 2011 was 1,4-dioxane which was not analyzed in 2003) and VOC impacts (typically benzene, 1,2-DCA, and vinyl chloride as well as 1,4-dioxane) have been observed in deeper bedrock wells up to 133 ft bgs. 2.1.4 Chemical Changes in Plume Characteristics The highest VOC concentration detected in March 2023 was 81.4 µg/L (1,4-dioxane at DDW-03) as summarized in Table 6. Other than 1,4-dioxane, which was not sampled at the Site until March 2023, the highest VOC concentration on -Site was 25.5 µg/L of cis-1,2-DCE at DDW-03 in March 2023 which is below the NCDEQ 2L Standard of 70 µg/L. Table 6 and Figures 4A through 4C show total VOCs (summation of VOCs above respective NCDEQ 2L Standards in one or more wells) for each well in March 2023. A second summation in Table 6 also removed 1,4-dioxane as this was not a VOC analyzed in 2003, therefore the totals from 2023 were not directly comparable to the totals from 2003 with this additional parameter. GC5699H/CAR230086 18 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 The highest total VOCs in 2023 excluding 1,4-dioxane were 22.8 µg/L at DMW-06 which is below the maximum VOC concentration of 111 µg/L, reported for 20031. At DMW-01, along the southeastern property boundary, the total VOC concentration decreased from I I I µg/L in 2003 (the highest at the time) to 0.9 µg/L in 2023 for compounds exceeding NCDEQ 2L Standards in at least one well. In addition, Mann Kendall trend analysis presented in Table 7 and discussed in Section 2.3.1.1 found dominantly downward trends except at the DDW-01 bedrock well nest and one compound at DMW-06. Plots of compounds with NCDEQ 2L Standard exceedances in March 2023 and over 50% detections are shown on Figures 5A and 5B. Figure 5A includes DDW-01 and DDW-OIA which had low concentrations when the trend analysis began in 2008 but are still showing mostly stable or decreasing impacts since peaks in 2009 (except TCE in DDW-01 and vinyl chloride in DDW-OlA which may result from reductive dechlorination). Figure 513 shows that, in most wells, the concentrations of VOC compounds are decreasing. The increasing 1,4-dichlorobenzene trend at DMW-06 results from two recent results and concentrations have been hovering just above and below the 2L Standard of 6 µg/L since 2008. The combination of total VOC summations, trend analysis, and scatter plots suggest that VOC impacts in groundwater from the landfill, particularly in saprolite and PWR, are generally decreasing. 2.2 Refining the Site Conceptual Model Based on data collected since Delta's report (2003) changes to the occurrence, distribution, and potential movement of VOC-impacted groundwater (which was the focus of the original CSM) at the Site are: • The CSM for aquifer characteristics has not changed. The average hydraulic gradient in March 2023 was estimated to be 0.013 ft/ft in regolith, similar to the 2003 estimate of 0.011 ft/ft. • Groundwater elevations and flow directions are consistent with the prior CSM with the exception of portions of the southeastern boundary. In data collected between 2015 and 2023, depth to groundwater was reported to be between approximately ground surface in the Sugar Creek floodplain to 60 ft bgs at higher ' Note that it is unclear how the total VOCs were calculated in 2003. GC5699H/CAR230086 19 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 topography. Groundwater elevations have risen substantially to the south of the Site at DMW-02A, following construction of a multi -family residential complex with a man-made pond which may locally change the direction of groundwater flow along portions of the southeastern boundary. Other than that area, groundwater flow direction has remained similar to historic observations. • A calculation of vertical gradients since 2006 is shown in Table 5 and changes the previous CSM slightly. The previous CSM noted an upward gradient between deep bedrock and PWR wells. This remains the case near Sugar Creek at the DDW-03A/DDW-03 well nest which has bedrock and PWR/saprolite screened wells. The upward gradient is also consistently seen at the co -located saprolite well (DMW-06) and at bedrock well pair DMW-OIA/DMW-01. PWR/saprolite well pair DDW-02/DMW-05 shows less consistent upward gradients and several pairs in the central area of the Site (DDW-05/DMW-09 and DDW-06/DMW-B between bedrock and saprolite) average a negative gradient. At the DMW-02B/DMW-02A bedrock well nest, there was historically a strong upward gradient which has changed to a downward gradient since 2019, likely because of construction of a man-made pond nearby which is increasing the hydraulic head in the shallow bedrock. • The vertical extent of impacts has changed since the prior CSM. In March 2023, 1,4-dioxane was detected above the 2L Standard in monitoring well DMW-05 which is screened within the top 25 feet of subsurface and previously assumed to be above contamination. Several VOCs were detected above 2L Standards in DMW-06 where the well depth is 29.5 ft bgs, supporting the 2003 conclusion that VOC impacts are primarily restricted to the PWR and fractured bedrock zones below 25 ft bgs. On the other hand, benzene, 1,4-dioxane, TCE, and vinyl chloride concentrations were detected above the 2L Standards in DDW-OIA and benzene was detected above the 2L Standards in DDW-03A, both of which are screened below 65 ft bgs which changes the prior CSM that impacts did not extend below 65 ft bgs. 2L Standard exceedances of 1,2-DCA and 1,4-dioxane were also observed in deep bedrock well DMW-02B in March 2023, while benzene and vinyl chloride are more frequently detected at that location, though this well is not downgradient of the influence of waste. In 2003, the vertical extent of VOC- impacted bedrock groundwater was estimated to be within 80 ft bgs and limited GC5699H/CAR230086 20 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 to the upper 30 feet of highly fractured bedrock, whereas data from 2023 indicates impacts may be as deep as 133 ft bgs. • Many VOC concentrations have decreased between 2003 and 2023 based on Mann Kendall analysis (Table 7). The highest total VOC concentration in 2023 (including only VOCs which exceeded the 2L Standard in one or more wells in March 2023 so impacts below the 2L Standard would not inflate the concentrations) and excluding 1,4-dioxane (which was not measured in 2003) is 58.6 µg/L which is below the maximum VOC concentration of 111 µg/L reported for 2003. At DMW-01, along the southeastern property boundary, the total VOC concentration went from 111 µg/L in 2003 to 0.9 µg/L in 2023 which suggests the plume has attenuated along portions of the southeastern boundary. Based on concentrations of total VOCs above the 2L Standard in at least one monitoring well in March 2023 as compared to February 2003 in PWR wells near the confluence of Sugar Creek and the South Tributary (DMW-06 from 82 µg/L to 22.8 µg/L and DDW-03 from 100 µg/L to 14.4 µg/L excluding 1,4-dioxane which was not analyzed in 2003), the plume has likely also receded along the southeastern portion of the southwestern boundary. • The horizontal extent of VOC-impacted groundwater has receded along the southeastern boundary based on decreased concentrations of 1,2-dichloropropane, 1,4-dichloropropane, TCE, and vinyl chloride at DMW-01 (Table-3F) and remained consistent to decreasing along the southwestern boundary based on concentrations of vinyl chloride at DMW-06 which remain two orders of magnitude above the NCDEQ 2L Standard in 2023 (Table 6). The extent of VOC impacts was estimated to be within approximately 500 feet downgradient of the edge of waste adjacent to Landfill Areas A and C near the southeastern Site boundary in 2003. Based on the low concentration of VOCs along the southeastern boundary this may have receded. The hydraulic divide of Sugar Creek (described in Section 1.2) along the southwestern boundary indicates that the estimated extent of VOC impacts from 2003 is likely consistent for PWR groundwater along the southwestern boundary. 2.3 Evaluation of Impacts Updated plume maps are provided in Figures 4A through 4C. Estimated extent of the groundwater plumes in each hydrogeologic unit were inferred based on the edge of waste, GC5699H/CAR230086 21 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 available data, and the hydraulic divide at Sugar Creek (described in Section 1.2). The edge of impacts was defined as total VOC concentration of 5 µg/L based on a summation of VOCs which are above the 2L Standard in one or more wells in March 2023. A summation was used rather than individual VOCs because the distribution of individual VOCs is complicated by irregularity of the waste. VOC impacts continue to be detected near the southwestern Sugar Creek (DMW-06, DMW-03, DMW-03A, DDW-02, DMW- 05, DDW-01, and DDW-01A) and southeastern (DMW-01) property boundaries. 2.3.1 Contaminant Concentrations 2.3.1.1 Groundwater A summary of detected constituents and field parameters (pH, specific conductance, and temperature) from monitoring well samples collected during the March 2023 groundwater sampling event is included in Table 6 and laboratory analytical reports were included in the most recent monitoring report (Geosyntec, 2023). The following is summarized from that report. VOCs, metals and 1,4-dioxane were detected in samples collected from Site monitoring wells in March 2023. Select compounds were detected above the estimated quantitation limit (EQL) in several wells at concentrations above the 2L Standards. One or more VOCs exceeded their 2L Standard in 9 of the 14 groundwater monitoring wells sampled, and one or more metals were detected above their 2L Standards in 8 of the 14 monitoring wells sampled for metals analyses (2 excluding iron and manganese). Figures 4A through 4C display maps with exceedances of the 2L Standards shown for each well. The March 2023 analytical results reveal the following: • 1,1-DCA was detected above its 2L Standard of 6 µg/L in two wells: DDW-01 at 7.3 µg/L and DDW-02 at 8.9 µg/L. • 1,2-DCA was detected above its 2L Standard of 0.4 µg/L in one well: DMW-02B at 0.51 µg/L (J-qualified as estimated). Exceedances with J qualifiers indicate that the analyte was detected below the reporting limit of the measuring instrument, so the laboratory considers these detections as estimated values. GC5699H/CAR230086 22 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 • 1,2-Dichloropropane was detected above its 2L Standard of 0.6 µg/L in three wells: DDW-01 at 0.87 µg/L (J-qualified), DDW-03 at 2.5 µg/L (1.6 µg/L in the duplicate), and DMW-06 at 2.5 µg/L. • 1,4-Dichlorobenzene was detected above its 2L Standard of 6 µg/L in one well: DMW-06 at 7.6 µg/L. • Benzene was detected above its 2L Standard of 1 µg/L in two wells: DDW-01A at 2.0 µg/L, and DDW-03A at 4.7 µg/L. • TCE was detected above its 2L Standard of 3 µg/L in three wells: DDW-01 at 5.0 µg/L, DDW-01A at 3.6 µg/L, and DMW-06 at 4.4 µg/L. • PCE was detected above its 2L Standard of 0.7 µg/L in one well: DDW-01 at 6.1 µg/L. • Vinyl chloride was detected above its 2L Standard of 0.03 µg/L in five wells: DDW-01 at 1.8 µg/L, DDW-01A at 1.5 µg/L, DDW-03 at 3.3 µg/L (2.2 µg/L in the duplicate), DMW-01 at 0.93 µg/L (J-qualified), and DMW-06 at 3.3 µg/L. • 1,4-dioxane was detected above its 2L Standard of 3 µg/L in six wells: DDW-01A at 4.7 µg/L, DDW-02 at 30.2 µg/L, DDW-03 at 81.4 µg/L (81.3 µg/L in the duplicate), DMW-02B at 8.9 µg/L, DMW-05 at 7.4 µg/L, and DMW-06 at 66.1 µg/L. Three of the wells with 1,4-dioxane 2L Standard exceedances had one or less other VOC 2L Standard exceedances (DDW-02, DMW-02B, DMW-05). In some cases (DDW-0l/DDW-0lA, DMW-05/DDW-02, and DMW-02A/DMW-02B) the deeper well had higher 1,4-dioxane concentrations than the shallow well at the same location. Only at well cluster DMW-06/DDW-03/DDW-03A does the 1,4-dioxane concentration decrease in the bedrock well. • Barium was detected above its 2L Standard of 700 µg/L in one well: DMW-02A at 1,090 µg/L. • Cadmium was detected above its 2L Standard of 2 µg/L in one well: DMW-01 at 44.5 µg/L. GC5699H/CAR230086 23 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 • Iron was detected above its 2L Standard of 300 µg/L in six wells: DDW-01 at 386 µg/L,, DMW-01 at 16,100 µg/L, DMW-02 at 3,840 µg/L, DMW-05 at 10,000 µg/L, DMW-08 at 597 µg/L, and YRW-IOC at 117,000 µg/L. • Lead was detected above its 2L Standard of 15 µg/L in one well: DMW-02A at 187 µg/L. • Manganese was detected above its 2L Standard of 50 µg/L in five wells: DMW-01 at 665 µg/L, DMW-02 at 2,950 µg/L, DMW-05 at 3,570 µg/L, DMW-06 at 252 µg/L, and YRW-IOC at 1,230 µg/L. Historic groundwater analytical data are included in Table 3. A statistical analysis of the monitoring well VOC data was performed to identify groundwater quality trends. The Mann -Kendall non -parametric test was performed on performance monitoring wells for each VOC with a concentration above the 2L Standard in March 2023, and where less than half of data points in the data set were non -detect. The Mann -Kendall test was utilized to evaluate whether the concentration of each VOC exhibits a statistically significant increasing or decreasing trend at a given confidence interval; for this evaluation, a confidence interval of 95% was applied. Earth Science Information Systems' Esdat Version 5.1 software was used to perform the trend analysis. EPA guidance on statistical analyses for groundwater data has indicated that a concentration value lower than any of the detected measurements should be assigned when an analytical result is "non -detect" (USEPA, 2009). Therefore, zero values were assigned to non -detects in this analysis. Table 7 presents the results of the trend analysis for VOCs. This analysis was performed on data collected since March 2008, which were readily available in the Site's database. The results of the Mann -Kendall trend analysis are summarized as follows: • Eight (8) decreasing VOC concentration trends are considered statistically significant at 95% confidence: PCE at DDW-01; l,l-DCA at DDW-02; 1,2-dichloropropane and vinyl chloride at DDW-03; vinyl chloride at DMW-01; and 1,2-dichloropropane, TCE, and vinyl chloride at DMW-06. GC5699H/CAR230086 24 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 • Five (5) increasing VOC concentration trends are considered statistically significant at 95% confidence: 1,1-DCA and TCE at DDW-01; TCE and vinyl chloride at DDW-0IA; and 1,4-dichlorobenzene at DMW-06. Mann -Kendall trend analyses were conducted for six (6) VOC compounds across six (6) of the Site well locations (DDW-01, DDW-01A, DDW-02, DDW-03, DMW-01, and DMW-06) and plots of this data are shown on Figure 5A and Figure 5B. Trend analyses were not conducted for compounds where concentrations were above the 2L Standard in March 2023 and more than half of data points in the historical data series were non -detect: 1,2-dichloropropane and vinyl chloride at DDW-01, benzene at DDW-01A, benzene at DDW-03A, and 1,2-DCA at DMW-02B. These series were excluded from the analysis as the Mann -Kendall analysis is not considered appropriate in evaluating trends when more than half of data points are non -detect. In addition, trend analysis was not conducted for 1,4-dioxane for any of its five (5) exceedances as the samples were analyzed for 1,4-dioxane for the first time in March 2023. Decreasing concentration trends for all but five (5) of the VOCs analyzed provides statistical evidence of the overall improvement to the groundwater quality for VOCs at the Site as a result of natural attenuation processes. The historical presence of chlorinated daughter products of PCE (TCE, cis-1,2-DCE, and vinyl chloride), particularly the increase of these compounds in bedrock wells DDW-01 and DDW-01A, may indicate that some reductive dechlorination has occurred in Site groundwater, which can occur naturally under favorable conditions. In addition to the reductive biological process, other biodegradation and natural processes such as oxidation of compounds under aerobic conditions, sorption, dilution, and chemical degradation, may contribute to natural attenuation of VOCs in groundwater, which will lead to reductions of their concentrations over time. Some of these attenuation methods are described further in Delta's 2003 report. A Biochlor model is described in Section 2.3.3.1. While select metals (iron, manganese, barium, cadmium, and lead during the most recent monitoring event) consistently or sporadically exceed 2L Standards in select wells, these impacts are not generally co -located with VOC Site impacts and are often in wells upgradient or side -gradient of anticipated landfill impacts including YRW-10C, DMW-08, DMW-02, and DMW-02A. In the 2003 report iron and manganese were attributed to background conditions. While iron and manganese did not exceed 2L Standards in upgradient well DMW-A, they could be released from lithologic units through changes in groundwater characteristics (pH, oxidation, etc.) caused by the waste. GC5699H/CAR230086 25 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 YRW-IOC, which is only downgradient of the edge of a waste cell, has historically had the highest concentrations of iron in groundwater (Table 3). 2.3.1.2 Surface Water A summary of detected constituents and field parameters (pH, specific conductance, and temperature) from samples collected during the March 2023 surface water sampling event is included in Table 8, and laboratory analytical reports were included in the most recent monitoring report (Geosyntec, 2023). Surface water samples were collected from six locations (NT-1, NT-2, SC-1, SC-2, ST-1, and ST-3) (Figure 2). • Total chromium was detected above the Title 15A NCAC Subchapter 2B Surface Water Quality Standard (213 Standard) of 11 µg/L in 2015 with a concentration of 12.6 µg/L at NT-2 and in 2019 the chromium concentration was 15.4 µg/L at SC-1 and 12.8 µg/L at SC-2. • Lead exceeded the 2B Standard of 14 µg/L with a concentration of 22 µg/L during one monitoring event in 2010 at NT-I. Mercury concentrations were 0.14 µg/L (J-qualified) during a 2011 monitoring event at SC-1 which was above the 2B Standard of 0.012 µg/L. No other metals were detected above 2B Standards in surface water samples since at least 2008. Four VOC compounds, 1,1-DCA, TCE, PCE, and vinyl chloride exceeded 2B Standards at NT-2 in 2010. Bromodichloromethane and/or chlorodibromomethane exceeded 2B Standards at SC-1 and SC-2 in 2010. No other 2B Standard exceedances of VOCs have occurred in Site surface water since at least 2008 with the exception of 1,4-dioxane, described below (Table 3). Surface water samples were analyzed for 1,4-dioxane for the first time in March 2023. 1,4-dioxane was detected above its 2B Standard of 0.35 µg/L at locations NT-1 (0.71 µg/L [J-qualified]), SC-1 (0.66 µg/L [J-qualified]), SC-2 (0.84 µg/L [J-qualified]), and ST-1 (5.0 µg/L). One of these locations (SC-1) is upriver of potential landfill influence. GC5699H/CAR230086 26 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 Concentrations of 1,4-dioxane are higher in the South Tributary than in the north tributary and Sugar Creek. 2.3.2 Impacts at Point of Compliance As discussed above, the source of metal concentrations in groundwater has less certainty than VOC impacts, therefore the discussion related to points of compliance has been limited to VOC impacts above respective 2L Standards. Groundwater results from the past 15 years of monitoring (since 2008) are included in Table 3 and evaluated herein. 2.3.2.1 Southeastern Boundary The southeastern boundary is located along South Tryon Street and is adjacent to Landfill Area A (Figures 4A through 4C). Three monitoring wells are sampled along this boundary including DMW-08 at the upgradient edge of waste, DMW-01 along the property boundary, and off -Site well DMW-02 which is within 300 ft of the property line. At DMW-08, PCE is the only VOC to historically exceed 2L Standards since 2008 and the most recent PCE exceedance was in April 2009 with a concentration of 0.89 µg/L (J-qualified) compared to the 2L Standard of 0.7 µg/L. No VOCs have exceeded 2L Standards at DMW-02 since at least 2008. This suggests that these two wells delineate impacts to the northeast and southeast in saprolite and PWR. At DMW-01, located at the property boundary and point of compliance, VOCs have been historically detected above the 2L Standards including, but not limited to, 1,2-dichloropropane, 1,4-dichlorobenzene, benzene, cis-1,2-DCE, TCE, and vinyl chloride (Table 3-F). VOC concentrations have decreased over time and, in 2022 and 2023, only vinyl chloride exceeded the 2L Standard of 0.03 µg/L with a concentration of 0.93 µg/L (J-qualified). A Mann -Kendall analysis from the most recent monitoring report (Geosyntec, 2023) indicated a statistically decreasing concentration of vinyl chloride at this well (Table 7 and Figure 5B), suggesting VOCs are attenuating along the southeastern boundary. Off -Site bedrock wells DMW-02A and DMW-02B are described in Section 2.3.3.2. GC5699H/CAR230086 27 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 2.3.2.2 South western Boundary The southwestern boundary is located along Sugar Creek and is adjacent to Landfill Area C (Figures 4A through 4C). Ten monitoring wells are located along this boundary, eight of which are part of the monitoring program. These include saprolite wells YRW-10C and DMW-06, PWR/saprolite wells DDW-03 and DMW-05, PWR well DDW-02, and bedrock wells DDW-01, DDW-01A, and DDW-03A. In saprolite, YRW-10C is located at the upgradient edge of waste and has no VOC 2L Standard exceedances since at least 2008. Near the Sugar Creek and Tributary B confluence, saprolite well DMW-06 has had VOC 2L Standard exceedances including 1,1-DCA, 1,2-DCA, 1,2-dichloropropane, 1,4-dichlorobenzene, 1,4-dioxane, TCE, PCE, and vinyl chloride. The VOC concentrations have generally decreased over time with only 1,2-dichloropropane, 1,4-dichlorobenzene, 1,4-dioxane, TCE, and vinyl chloride exceeding 2L Standards in 2023 (Table 6). Mann -Kendall analysis indicates statistically decreasing concentrations except for 1,4-dioxane which has only been measured once and 1,4-dichlorobenzene which was increasing (Table 7). The 1,4-dichlorobenzene concentration was 7.6 µg/L which is only slightly above the 2L Standard of 6 µg/L and has hovered around this concentration since at least 2008 (Figure 5B) while the 1,4-dioxane concentration of 66.1 µg/L was more than an order of magnitude above the 3 µg/L 2L Standard. Saprolite/PWR well DDW-03 has a similar history to co -located DMW-06 with exceedances of 1,2-DCA, 1,2-dichloropropane, 1,4-dichlorobenzene, 1,4-dioxane, benzene, TCE, and vinyl chloride since 2008. Only 1,4-dioxane, 1,2-dichloropropane, and vinyl chloride exceeded the 2L Standards in 2023 with decreasing trends for the latter two compounds (Table 7). The concentration of 1,4-dioxane at DDW-03 was the highest on -Site at 81.4 µg/L. Monitoring well DMW-05 is also screened in saprolite/PWR but further north along Sugar Creek. In September 2010 there were 2L Standard exceedances of 1,1-DCA and PCE in this well and in September 2011 there were exceedances of 1,1-DCA, 1,2-dichloropropane, TCE, PCE, and vinyl chloride. Since then, the only VOC 2L Standard exceedance was 1,4-dioxane in 2023 (Table 34). PWR well DDW-02 is co -located with DMW-05 and has historical exceedances of 1,1-DCA, 1,2-DCA, benzene, PCE, trichlorofluoromethane, and vinyl chloride. Notably, there were no 2L Standard exceedances in September 2010 or 2011, suggesting that the two co -located wells may have been mis-labeled during these sampling events GC5699H/CAR230086 28 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 (Table 3-C). VOC concentrations have decreased over time and only 1,1-DCA and 1,4-dioxane exceeded 2L Standards at DDW-02 in 2023. The statistically decreasing trend for 1,1-DCA (Table 7 and Figure 5B) with a concentration of 8.9 µg/L in 2023 compared to the 2L Standard of 6 µg/L indicates that VOC concentrations continue to attenuate in PWR along the southwestern boundary. Bedrock well DDW-03A is located at the confluence of Sugar Creek and Tributary B and the only VOC with concentrations above the 2L Standard since 2008 is benzene. The 2023 concentration of benzene in this well was 4.7 µg/L compared to the 2L Standard of 1 µg/L and has consistently exceeded the 2L Standard since 2017 (Table 3-E). Benzene is below the 2L Standard in the co -located saprolite and PWR wells DMW-06 and DDW-03. Bedrock wells DDW-01 and DDW-01A are co -located along the northern portion of the southwestern boundary. These wells have had 2L Standard exceedances of 1,1-DCA, 1,2-dichloropropane, 1,4-dioxane (deeper well DDW-01A only), benzene, TCE, PCE, and vinyl chloride since 2008. At DDW-01, 1,1-DCA, 1,2-dichloropropane, TCE, PCE, and vinyl chloride remain above the 2L Standards in 2023 (Table 6) and Mann -Kendall analysis indicates upward trends for 1,1-DCA and TCE but a downward trend for PCE (Table 7 and Figure 5A). TCE and vinyl chloride are similarly increasing at DDW-0IA while PCE has decreased to below the 2L Standard. Benzene and 1,4-dioxane also remain above the 2L Standard at DDW-01A in 2023. The decreasing PCE and increasing daughter product concentrations suggest reductive dechlorination is occurring in bedrock along the southwestern boundary. 2.3.2.3 Vertical Point of Compliance — Deep Bedrock Compliance monitoring wells for the deeper aquifer DDW-01A, DDW-03A and DMW-02B reported VOC concentrations above 2L Standards in March 2023, suggesting potential downward migration of VOCs into the deeper bedrock (Table 6). Other than recent hydraulic changes near DMW-02B, these wells have shown a consistent upward gradient, suggesting that vertical migration of VOC impacts would migrate by dispersion and diffusion rather than advection. At DDW-0IA, concentrations of TCE and vinyl chloride above the 2L Standard correlate with shallower bedrock well DDW-01 and indicate reductive dichlorination. Fairly consistent exceedances of the benzene 2L Standard in DDW-01A, DDW-03A, and GC5699H/CAR230086 29 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 DMW-02B do not appear to correlate to shallower wells which historically show few 2L Standard exceedances for benzene. DDW-OIA and DMW-02B also had 2L Standard exceedances of 1,4-dioxane in March 2023 whereas their shallower counterparts were below the 2L Standard for this compound. 2.3.3 Off -Site Migration Evaluation Off -Site migration was evaluated for the three hydrogeologic units combined using a BIOCHLOR model for the southeastern boundary and southwestern boundary based on groundwater flow direction and concentrations in nearby wells. In addition, off -Site migration into surface water was considered. A receptor survey showing wells, springs, and surface water intakes used as potable water within 1,500 feet from the edge of waste (as applicable) is included as Appendix F. This shows two inactive and two abandoned water supply wells west of Sugar Creek and three non -drinking water supply wells approximately 1,500 feet south of the waste boundaries. 2.3.3.1 BIOCHLOR Model In 2003, Delta used the BIOCHLOR Natural Attenuation Decision Support System (BIOCHLOR) by the United States Environmental Protection Agency (EPA) to simulate downgradient chlorinated ethene concentrations at the Site through natural attenuation via advection, dispersion, linear adsorption, and biotransformation (reductive dechlorination). This program specifically models PCE and daughter products. The model in 2003 predicted that PCE would attenuate to below the 2L Standard in 2012, TCE by 2017, cis-1,2-DCE by 2004, and vinyl chloride by 2020. By 2019 (with one exception in 2022), PCE in saprolite and PWR monitoring wells was below the 2L Standard of 0.7 µg/L, seven to ten years after the model predicted. Similarly, TCE was slightly above the 2L Standard of 3 µg/L in one saprolite well (DMW-06) with a concentration of 4.4 µg/L in 2023, six years after it was predicted to attenuate. Vinyl chloride remains above the 2L Standard of 0.03 µg/L in five wells (three in saprolite/PWR) with concentrations up to 3.3 µg/L. Overall, the 2003 model prediction appears to be within a decade for PCE and TCE but is incorrect for vinyl chloride, which is still an order of magnitude above the 2L Standard. The March 2023 groundwater monitoring data does not provide an appropriate flowpath from the source area to downgradient with which to re -calibrate the model. In 2003, Delta evaluated YRW-06A as a source area for DDW-03 and DMW-01 as a source area for GC5699H/CAR230086 30 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 DMW-02A (which is upgradient to cross -gradient based on recent hydraulic monitoring) in order to predict the time to attenuation. March 2023 data from YRW-06A is not available, but concentrations at DDW-06 can be used as surrogate source area concentrations while holding the other model assumptions the same as 2003. In this scenario, TCE is anticipated to decrease to below the 2L Standard within 450 feet of the source and vinyl chloride over 750 feet from the source after 25 years. Biochlor input and output are shown in Appendix G and derivation of input values is described in the Delta report (2003). These results suggest that the Sugar Creek hydraulic boundary, rather than attenuation, is controlling migration. 2.3.3.2 Southeastern Boundary As described above, only select metals have exceeded the 2L Standards at DMW-02 since at least 2008. These metals could represent background conditions (as stated in the 2003 report) or factors unrelated to the landfill. No VOCs have exceeded 2L Standards at DMW-02 since at least 2008, suggesting that off -Site migration of VOCs along the southeastern boundary is not occurring in the PWR. In bedrock, benzene and vinyl chloride periodically exceed the 2L Standard and there were exceedances of 1,2-DCA and 1,4-dioxane at DMW-02B in March 2023 but not in previous monitoring events (though note that 1,4-dioxane was not previously sampled). Benzene at DMW-02B first exceeded the 2L Standard in September 2017 which was prior to the change in hydraulic gradient. Vinyl chloride first exceeded the 2L Standard in September 2021, following the reversal in hydraulic gradient which changed the vertical gradient to downwards and the horizontal groundwater flow direction to be towards the landfill. The variation of benzene and vinyl chloride compounds from above to below the 2L Standard between monitoring events suggests the edge of a groundwater plume (Table 2-I). Benzene and vinyl chloride also periodically exceed the 2L Standard in PWR well DMW-01 on the southeastern boundary which is cross -gradient of DMW-02B. 1,2-DCA and 1,4-dioxane have not exceeded the 2L Standard at DMW-01. Benzene and vinyl chloride also have not exceeded the 2L Standard in shallower well DMW-02A co -located with DMW-02B since at least 2008. While off -Site impacts may exist at DMW-02B, the hydraulic gradient at this location is towards the Site following construction of a man- made pond (Figure 3), therefore, impacts would not travel further off -Site. GC5699H/CAR230086 31 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 2.3.3.3 Southwestern Boundary While concentrations of VOCs along the southwestern boundary exceed 2L Standards, this boundary is located along Sugar Creek which acts as a hydraulic divide for shallow groundwater migration. The shallow groundwater elevation at DDW-03A (Table 2) and consistent upward hydraulic gradient at the DDW-03/DDW-03A and DDW-01/DDW- 01A well nests (Table 5) support this. In addition to Site data, a network of 14 saprolite/PWR wells and eleven bedrock wells located west of Sugar Creek indicate that the horizontal hydraulic gradient is to the east towards Sugar Creek (Hart & Hickman, 2023). This off -Site data confirms that Sugar Creek acts as a hydraulic divide for saprolite and PWR groundwater. 2.3.3.4 Surface Water Surface water concentrations since 2008 are included in Table 3 and do not indicate impacts from VOCs in groundwater. Upstream locations SC-1, NT-2, and ST-3 have shown single -event 2B Standard exceedances for 1,4-dioxane, bromodichloromethane, and chlorodibromomethane (SC-1) and 1,1-DCA (NT-2). At downstream locations SC-2, NT-1, and ST-1 the only VOC with exceedances of the 2B Standard is 1,4-dioxane. The March 2023 1,4-dioxane concentrations at SC-2, NT-1, and ST-1, respectively were 0.84 µg/L (J-qualified), 0.71 µg/L (J-qualified), and 5.0 µg/L as compared to the 2B Standard water supply in stream target value of 0.35 µg/L and upstream concentration 0.66 µg/L (J-qualified) in SC-1. Other than 1,4-dioxane, there does not appear to be any VOC impacts in the surface water and the only 1,4-dioxane concentration more than 1 µg/L above the 2B Standard is located at ST-1 in the South Tributary. The confluence of this tributary with Sugar Creek occurs upstream of sample SC-2 where 1,4-dioxane concentrations were less than 0.2 µg/L above the upstream concentrations from north of the confluence. As such, there does not appear to be off -Site migration of landfill impacts through surface water with the potential exception of low concentrations of 1,4-dioxane. The low concentrations of 1,4-dioxane observed in Sugar Creek should decrease with distance through dilution and photodegradation (Dehghani et al, 2022). GC5699H/CAR230086 32 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former Pork Road Landfill, Charlotte, North Carolina August 2023 4. SUMMARY, CONCLUSIONS, AND RECOMMENDATIONS The following sections summarize findings conclusions, and future recommendations based on data collected since the 2003 Assessment of Corrective Measures Report (Delta, 2003). 4.1 Summary and Conclusions • Aquifer conditions and plume characteristics have remained similar to 2003. Overall VOC concentrations have decreased but the vertical extent of impacts has increased. • The CSM remains similar to that developed in 2003 with the exception of a reversal of hydraulic gradient off -Site to the south as a result of a man-made pond which drives water towards or cross -gradient of the Site. In addition, select VOC compounds have been detected in deep bedrock wells including benzene and 1,4- dioxane which do not correlate to shallow wells. • Contaminant concentrations have decreased with time with a few exceptions (mostly PCE degradation products) which have increasing concentrations in select wells. • VOC impacts above the 2L Standards have been identified in saprolite and PWR wells along the property boundaries (DMW-01, DMW-06, DDW-03, DDW-02, and DMW-05) at the Site in 2023, however, they are generally lower than those identified in 2003. Metals above the 2L Standards have additionally been detected in saprolite and PWR wells YRW-IOC, DMW-08, D MW-01, DMW-02, DMW-06, and DMW-05. • Vertical dispersion of impacts appears to have occurred with VOC impacts detected in shallow bedrock well DDW-01 and deep bedrock wells (DDW-01 A, DDW-03A, and DMW-02B). Metals above the 2L Standards have additionally been detected in bedrock wells DMW-02A and DDW-01. • Off -Site migration of landfill impacts is limited to the southwest for saprolite and PWR groundwater by a hydraulic divide at Sugar Creek. VOC concentrations GC5699H/CAR230086 33 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former Pork Road Landfill, Charlotte, North Carolina August 2023 in the creek do not show impacts from the landfill with the potential exception of 1,4-dioxane though this compound has only been analyzed once to date. Along the southeastern boundary, concentrations of VOCs have decreased and off -Site wells do not indicate migration within the PWR unit though VOC impacts have been detected in bedrock groundwater. 4.2 Recommendations Based on this evaluation, minor modifications of the monitoring program are warranted including the temporal and analytical monitoring requirements. Geosyntec recommends the following modifications to the selected remedy: • Reduction of the groundwater and surface water monitoring frequency from semi- annual to annual. Nearly 30 years of data show primarily decreasing VOC concentrations in groundwater and a plume contained by low concentrations along the southeastern boundary and a hydraulic divide (Sugar Creek) along the southwestern boundary. • Reduction of the reporting frequency from semi-annual to annual to match the proposed reduction in monitoring frequency. • Modification of the analytical list to add 1,4-dioxane (per NCDEQ's 29 May 2018 memorandum entitled "1,4-Dioxane Analysis, Solid Waste Section Limits, and Laboratory Analytical Methods") and per- and polyfluoroalkyl substances (PFAS) for at least two consecutive sampling events (per NCDEQ's 13 March 2023 memorandum entitled "PFAS Monitoring Requirements for Solid Waste Sanitary Landfills" and subsequent 17 July 2023 memorandum entitled "Clarification of PFAS Monitoring Requirements for Solid Waste Sanitary Landfills ". Geosyntec proposes that an annual groundwater and surface water monitoring program begin in September 2024 (removing the September 2023 and March 2024 events) in accordance with the proposed schedule shown in Table 9. This timeline will allow sufficient time to modify the Water Quality and Landfill Gas Monitoring Plan ("Monitoring Plan"; Geosyntec, 2017) to incorporate the changes above. This will include temporarily changing from a passive sample collection method with passive diffusion bags (PDBs) to a low -flow sampling method due to the volume requirements of the Solid Waste Section requested PFAS analysis (EPA Method 1633). GC5699H/CAR230086 34 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former Pork Road Landfill, Charlotte, North Carolina August 2023 In addition, a September monitoring event would coordinate with the City of Charlotte's annual groundwater monitoring at the Police and Fire Training Academy (Academy) site located at 1770 Shopton Road, across Little Sugar Creek from the Site. The routine monitoring program for the Academy includes sampling 10 York Road Site monitoring wells for PFAS including YRW-1 OC, YRW-09A, DMW-05, DDW-02, DDW-03, DMW- 06, DMW-02, DDW-01A, DDW-01, and DDW-03A. Groundwater samples from these or a subset of these wells have been analyzed for PFAS annually since 2020 using EPA Method 537.1. PFAS sampling results from those monitoring events are included in Appendix H. Additional data will be collected in September or October 2023 as part of routine monitoring for the Academy site and will be provided to NCDEQ. Geosyntec and the City of Charlotte request until September 2024 to evaluate changes to the monitoring program, revise sampling methodologies, evaluate laboratory methods, and correlate with the monitoring program at the adjacent Academy site. GC5699H/CAR230086 35 08.2023 Geosptec ° consultants Geosyntec Consultants of NC, P.C. Corrective Action Evaluation Report Former York Road Landfill, Charlotte, North Carolina August 2023 5. REFERENCES Dehghani, M, Naseri, M., Nadeem, H., Banaszak Holl, M, Batchelor, W, 2022, Photocatalytic Degradation of 1,4-Dioxane and Malachite Green over Zinc Oxide/Cellulose Nanofiber Using UVA/B from Direct Sunlight and a Continuous Flow Reactor. ACS EST Water 2022, 2, 5, 786-797. Delta Environmental Consultants, Inc, 2003, Assessment of Corrective Measures Report, Former York Road Landfill, NCDENR Permit No. 60-03. Daniel, Charles C, III, and Payne, R.A., 1990, Hydrogeologic Unit Map of the Piedmont and Blue Ridge Provinces of North Carolina, USGS Water -Resources Investigations Report 90-4035. Geosyntec, 2017, Water Quality and Landfill Gas Monitoring Plan, Former York Road Landfill NCDEQ Permit No. 60-03. Geosyntec, 2023, Semi -Annual Monitoring Report, First Half 2023, Former York Road Landfill, NCDENR Permit No. 60-03. Hart & Hickman, 2023, Annual Groundwater Monitoring and PFAS Assessment Report Revision No. 01, Charlotte Police and Fire Training Academy, EPA ID #NCD991278623. USEPA, 2009, Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance. GC5699H/CAR230086 36 08.2023 TABLES Table 1 Groundwater Well Construction Details Former York Road Landfill Charlotte, North Carolina Well ID Well Depth (ft BTOC) Lithology TOC Elevation (ft above NGVD) Ground Elevation (ft above NGVD) Top of Screened Interval (ft above NGVD) Bottom of Screened Interval (ft above NGVD Screened Length (ft) March 2023 Water Level (ft BTOC) March 2023 Groundwater Elevation (ft above NGVD) DDW-01 60.0 Bedrock 585.49 583.26 538.25 523.25 15.0 7.12 578.37 DDW-OlA 100.0 Bedrock 585.06 583.31 493.30 483.30 10.0 6.30 578.76 DDW-02 55.0 PWR 587.96 585.57 545.53 530.53 15.0 11.99 575.97 DDW-03 61.0 PWR/Saprolite 585.59 582.72 536.72 521.72 15.0 10.26 575.33 DDW-03A 133.0 Bedrock 584.70 582.89 464.86 449.86 15.0 3.08 581.62 DDW-05 50.0 Bedrock 602.13 599.81 564.79 549.79 15.0 5.43 596.70 DDW-06 70.0 Bedrock/PWR 621.88 619.32 564.32 549.32 15.0 29.70 592.18 DMW-01 45.0 PWR 626.55 626.75 596.75 581.75 15.0 32.79 593.76 DMW-02 1 22.0 PWR/Saprolite 597.33 597.53 1 585.53 575.53 10.0 6.52 590.81 DMW-02A 47.0 Bedrock 595.51 593.54 558.54 546.54 12.0 1.25 594.26 DMW-02B 84.5 Bedrock 595.20 593.52 518.52 508.52 10.0 5.98 589.22 DMW-05 20.0 PWR/Saprolite 587.98 585.59 580.59 565.59 15.0 11.95 576.03 DMW-06 29.5 Saprolite 584.76 582.39 562.89 552.89 10.0 10.24 574.52 DMW-08 62.0 PWR 670.48 670.69 623.69 608.69 15.0 56.27 614.21 DMW-09 20.0 Saprolite 1 602.48 599.70 594.70 579.70 15.0 5.59 596.89 DMW-A 1 45.0 Saprolite 684.52 684.52 659.52 639.52 20.0 40.48 644.04 DMW-B 30.0 Saprolite 622.29 619.50 604.50 589.50 15.0 29.88 592.41 NEB-PZ-1 41.5 Saprolite 667.79 667.49 641.09 626.09 15.0 NEB-PZ-2 34.6 Saprolite 660.71 660.94 641.24 626.24 15.0 NEB-PZ-3 29.5 PWR 641.52 641.70 627.00 612.00 15.0 - YRW-06A 27.9 Saprolite 587.63 585.11 567.11 557.11 10.0 8.89 578.74 YRW-07 23.1 Saprolite 624.80 622.93 604.93 599.93 5.0 13.09 611.71 YRW-08A 22.8 Saprolite 587.45 584.22 566.22 561.22 5.0 YRW-09A 26.5 Saprolite 586.11 582.86 560.86 555.86 5.0 YRW-IOC 16.5 Saprolite 589.37 585.96 574.46 1 569.46 1 5.0 13.48 575.89 YRW-11B 20.0 Saprolite 602.96 600.19 585.19 1 580.19 1 5.0 6.03 596.93 WSW-2 80.0 Details not known WSW-3 100.0 1 Details not known Notes: 1. PWR - Partially Weathered Rock; NGVD - National Geodetic Vertical Datum; BTOC - below top of casing. 2. Well construction information derived from historical site -related monitoring reports prepared by HDR and Delta, with the exception of NEB-PZ-1, -2, and -3. These piezometers were surveyed by GEL on 09 November 2015. 3. WSW-2 and WSW-3 well depths reported by well owner. CAR23OO86 Page 1 of 1 Geosyntec Consultants of NC, P.C. Table 2 Historical Groundwater Elevations Former York Road Landfill Charlotte, North Carolina Well ID Mar-06 Sep-06 Feb-07 Sep-07 Mar-08 Sep-08 Mar-09 Sep-09 Mar-10 Sep-10 Mar-11 Sep-11 Mar-12 Sep-12 Mar-13 Sep-13 Mar-14 Sep-14 DDW-01 578.01 577.95 579.17 575.59 577.66 577.21 578.74 576.48 578.81 576.32 577.60 576.26 578.09 577.07 578.74 576.58 578.79 576.77 DDW-OlA 578.41 578.32 579.54 575.97 578.01 577.61 579.14 576.88 579.20 576.68 577.94 576.66 578.46 577.47 579.10 576.96 579.16 577.17 DDW-02 575.77 575.58 576.81 574.01 575.91 575.42 577.07 574.70 576.59 574.60 575.73 574.50 575.91 574.90 576.33 574.77 576.52 574.80 DDW-03 575.57 575.26 576.26 574.00 575.34 574.83 576.37 574.53 576.17 574.54 575.44 574.40 575.56 574.77 575.78 574.70 576.16 574.73 DDW-03A 1 580.34 579.70 1 581.05 578.75 579.95 579.32 580.87 579.42 1 581.70 579.66 580.03 579.39 1 580.57 580.04 1 580.86 580.20 581.53 579.91 DDW-05 597.88 597.25 598.39 595.84 597.68 596.59 598.15 596.10 597.83 594.73 597.60 595.25 597.24 596.28 597.83 1 595.95 598.21 1 597.19 DDW-06 592.35 591.77 592.89 591.44 591.38 591.70 591.77 592.07 593.45 591.84 591.29 590.71 591.43 590.74 591.07 591.04 591.85 591.10 DMW-01 592.25 591.30 594.27 590.91 590.81 590.42 591.14 591.00 595.44 592.05 590.52 590.29 590.92 590.36 590.38 590.95 591.25 591.35 DMW-02 585.14 584.15 584.84 583.33 584.19 583.43 585.04 583.87 585.48 583.87 584.05 583.29 584.41 584.11 584.69 584.17 585.30 584.33 DMW-02A 552.51 551.63 552.22 550.12 549.81 550.96 553.01 552.32 556.11 1 556.06 552.37 1 550.44 551.58 1 548.98 550.83 552.17 555.06 553.39 DMW-02B 1 590.03 589.85 1 590.89 589.50 592.95 589.30 590.23 589.54 590.64 589.28 589.72 589.10 589.63 589.28 589.77 589.52 590.34 589.58 DMW-05 575.87 575.63 578.24 573.50 576.78 574.96 578.94 574.08 577.49 573.95 576.10 574.17 576.50 574.67 1 577.48 574.39 577.38 574.38 DMW-06 574.94 574.59 575.55 573.44 574.76 574.23 575.76 573.96 575.47 573.97 574.88 573.83 574.87 574.13 575.09 574.07 575.46 574.08 DMW-08 614.08 615.03 614.28 613.76 612.36 611.35 610.82 610.85 611.32 612.09 611.13 610.65 610.59 610.80 610.69 610.86 610.68 612.02 DMW-09 597.82 597.40 598.55 596.04 597.96 596.78 598.25 596.27 597.97 594.95 597.85 595.45 597.47 596.49 598.02 596.17 598.36 597.42 DMW-A 645.90 645.70 646.32 645.56 644.15 643.77 643.60 644.95 1 644.94 643.19 1 642.92 642.97 642.68 642.32 643.31 642.92 643.98 DMW-B 1 592.51 591.90 1 593.05 591.61 591.46 591.11 591.79 592.29 593.60 592.09 591.41 590.85 591.56 590.84 591.15 591.23 591.99 1 591.27 YRW-06A 576.72 577.78 577.33 577.76 577.30 579.04 577.29 576.98 578.30 1 577.40 1 578.29 577.39 578.89 1 577.44 YRW-07 - - 608.29 612.10 609.59 612.45 610.07 612.60 609.88 - 608.83 610.56 609.65 611.03 609.75 612.17 610.61 YRW-IOC 575.92 575.78 577.13 574.64 575.95 575.36 576.86 575.01 577.12 574.99 575.82 574.97 575.84 575.21 576.14 574.97 576.31 575.02 YRW-1IB - - 595.71 597.99 598.09 598.36 1 598.36 1 598.12 594.66 - 595.52 1 597.29 596.28 598.08 596.02 598.59 597.35 Notes: Groundwater elevations above are dispalyed in ft above National Geodetic Vertical Datum. Data prior to 2015 were obtained from previous reports prepared by others. Blank cells represent unavailable historical data or no reading taken. Highest Period Reading Lowest Period Reading Bold values are suspected to be anomalous (Sep-09 at DMW-A) CAR230086 Page 1 of 2 Geosyntec Consultants of NC, P.C. Table 2 Historical Groundwater Elevations Former York Road Landfill Charlotte, North Carolina Well ID Mar-15 Sep-15 Mar-16 Sep-16 Mar-17 Sep-17 Mar-18 Sep-18 Mar-19 Sep-19 Mar-20 Sep-20 Mar-21 Sep-21 Mar-22 Nov-22 Mar-23 DDW-01 578.69 575.19 578.00 575.98 577.83 576.49 578.19 576.10 579.09 577.36 579.01 577.03 579.24 576.84 577.61 576.72 578.37 DDW-OlA 578.75 575.54 578.36 576.34 578.17 576.86 578.50 576.44 579.45 577.72 579.34 577.43 579.58 577.21 578.01 577.09 578.76 DDW-02 576.31 573.73 576.02 574.22 575.57 574.53 575.61 574.00 576.57 575.20 576.47 575.06 576.63 574.92 575.46 574.70 575.97 DDW-03 575.93 573.74 575.79 574.21 575.28 574.40 575.08 573.67 575.73 574.61 575.60 574.57 575.83 574.49 574.93 574.35 575.33 DDW-03A 580.91 1 578.71 581.79 1 579.51 580.67 1 580.18 580.73 1 578.87 582.92 579.65 1 582.92 581.25 1 583.15 581.66 1 581.75 580.20 1 581.62 DDW-05 598.74 595.03 597.88 596.02 597.83 596.63 597.91 595.62 598.35 596.45 597.98 595.62 597.77 595.73 596.33 595.14 596.70 DDW-06 591.15 590.01 592.95 590.98 591.16 591.22 590.74 590.40 593.69 592.11 592.99 592.20 593.23 591.51 591.44 590.64 592.18 DMW-01 591.14 591.25 595.21 594.59 591.86 594.01 594.59 589.78 595.20 592.05 594.93 593.39 596.46 594.43 593.80 591.63 593.76 DMW-02 584.88 583.36 585.58 584.21 584.46 584.42 584.62 582.35 586.82 583.67 586.50 584.50 590.63 590.28 590.37 590.18 590.81 DMW-02A 552.75 550.79 555.26 550.74 554.04 556.90 563.63 570.98 593.07 594.07 594.41 594.27 594.09 593.79 593.34 593.25 594.26 DMW-02B 590.16 1 589.04 590.55 1 589.51 589.72 589.66 1 589.87 581.75 592.20 1 582.18 589.85 1 584.86 589.42 1 587.94 589.37 1 585.88 589.22 DMW-05 577.13 573.30 576.34 573.81 575.74 574.08 576.10 573.60 577.33 574.93 577.65 574.60 577.54 574.26 575.33 574.03 576.03 DMW-06 575.26 573.17 575.07 573.65 574.63 573.75 574.44 573.15 574.91 573.90 574.72 573.83 574.83 573.66 574.13 573.60 574.52 DMW-08 611.77 611.50 612.51 613.45 612.62 612.44 611.89 611.77 612.81 614.45 614.24 622.88 617.51 617.07 615.93 614.84 614.21 DMW-09 598.88 595.25 598.01 596.24 598.06 596.85 598.14 595.81 598.48 596.67 598.11 595.86 597.94 595.98 596.66 595.38 596.89 DMW-A 643.33 642.60 644.28 644.15 642.87 643.08 642.26 642.42 644.71 645.91 645.92 647.11 647.07 646.84 645.18 644.28 644.04 DMW-B 591.29 1 590.17 593.23 1 591.19 591.34 1 591.43 590.89 1 590.58 593.94 1 592.35 593.23 592.46 593.46 591.74 591.64 590.82 592.41 YRW-06A 578.54 576.35 578.67 576.96 577.90 577.28 577.81 576.51 579.16 577.49 578.86 577.64 579.41 577.86 578.28 1 577.65 578.74 YRW-07 611.67 608.72 612.61 610.13 610.82 610.22 610.90 609.22 614.06 611.65 613.69 611.64 613.84 612.42 611.11 609.91 611.71 YRW-IOC 576.16 574.33 575.61 574.53 575.46 574.74 575.46 574.51 576.49 575.08 576.53 574.91 576.44 574.72 575.07 574.73 575.89 YRW-11B 598.84 595.09 598.19 596.06 597.97 596.67 598.09 595.63 598.97 596.46 598.31 595.52 598.22 595.61 597.43 594.97 596.93 Notes: Groundwater elevations above are dispalyed in ft above National Geodetic Vertical Datum. Data prior to 2015 were obtained from previous reports prepared by others. Blank cells represent unavailable historical data or no reading taken. Highest Period Reading Lowest Period Reading Bold values are suspected to be anomalous (Sep-09 at DMW-A) CAR230086 Page 2 of 2 Geosyntec Consultants of NC, P.C. Table 3-A Historical Groundwater Monitoring Data (DDW-01) Former York Road Landfill Charlotte, North Carolina Sample Date 3/18/2008 9/17/2008 4/7/2009 9/9/2009 3/10/2010 9/23/2010 3/29/2011 9/21/2011 3/20/2012 9/26/2012 3/6/2013 9/10/2013 3/26/2014 9/23/2014 3/6/2015 9/22/2015 Constituent Units NC 2L 1, 1 -dichloroethane µ /L 6 3.0 6.7 8.0 9.3 7.7 8.8 5.8 3.2 - 3.3J 2.9 - 3.1J 2AJ 2AJ 4.OJ 2.1 2.9J 1.6 3.0 1, 1 -dichloroethene L 350 - 1.1 1.2J 1.4J 1.1J 1.4 - - - - - - - - 1,2-dichloroethane /L 0.4 - - - - - - 0.16J - 1,2-dichloro ro ane L 0.6 - 0.56J 0.58J 0.60J 0.68 0.59J 0.34J - 0.34J - 0.35J - 1,4-dichlorobenzene /L 6 - - - - - - - 1,4-dioxane L 3 - - - - - - - Acetone L 6,000 31.0 - - - - - - - - - - - Barium L 700 17.0 18.0 18.01 20.OJ 19.01 24.0 90.5 21.5 - 23 AJ 22.4 - 22.8J 20.0 22.OJ 20.9J 22.3 21.6J 22.8 20.3 Benzene /L 1 - - - - - - - - - - - - - - Cadmium /L 2 - - - - - - - - Chloride /L 250,000 - - 10,000 - - - - - Chlorobenzene L 50 - - - - - - - - 0.24J Chloromethane L 3 - - - - - 0.28J 0.26J - Chromium III+VI L 10 1.7J 3.2J 4.1J 4.8J 5.1J 8.1 2J 5.7J - - - - - - cis- l,2-dichloroethene L 1 70 1.8 4.9 6.2 8.1 7.0 8.3 4.9 3 - 3.1J 2.5J 2.1J 2.1J 4J 2.5 3.8J 2.2 4.3 COD L - - - 33,000 - - - - - - - - - Dichlorodifluoromethane L 1,000 - I - - - - - - - - - - - - - - - Specific Conductance S/cm - - - - - - 340 1 326 241 324 363 312 360 351 - 358 Iron L 300 67.0 170 87.OJ 55.0 438 629 - 971 193 - 307J 108J 276J 78.1J 122 - 56.7 62.6 Lead L 15 - - - - 0.39J - - - - - - Man anew L 50 2.OJ 3.OJ 1.0J 14.OJ 2.OJ 3.OJ 266 13 - 27J 8.01 - 6.OJ - Merc L 1 - - O.01J - 0.12J 0.26 - - - Nitrate (as NO3-) gg/L 10,000 - 400 - - - - - - - - - H SU - - - 6.9 6.8 6.4 6.7 7.4 6.7 7.1 6.9 1 6.8 Sulphate L 250,000 - 1,5001 - - - - - - - - Temperature °C - - - - 16.4 1 17.8 16.5 16.7 15.8 17.0 16.6 16.8 16.9 Tetrachloroethene µ /L 0.7 3.6 12.0 14.0 12.0 12.0 13.0 5.9 2.2 3.0 1.9 1.5 2.6 Toluene /L 600 - - - - - - - - - - - - - - - - Trichloroethene /L 3 0.95J 3.1 3.4 3.3 3.6 3.9 1.5 0.95 - 1J 0.99 - LIJ 0.79J 0.85J 1.1 0.71J 1.1 1.9 Trichlorofluoromethane /L 2,000 - 1.7J 1.1 1.2J 1.1 J 1.2 0.42J 0.22J 0.21 - 0.26J 0.40J - - - - - Turbidi NTU - - - 25.0 1 36.0 3.0 2.0 3.0 7.0 2.0 6.4 Vinyl Chloride 0.03 - - - - - - - - - X lene (m & ) /L 500 2.0 - - - - - X lene o L 500 1.0 - - - - - NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 2L was obtained from NCDEQ Solid Waste Section (https://deq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 1 of 2 Geosyntec Consultants of NC, P.C. Table 3-A Historical Groundwater Monitoring Data (DDW-01) Former York Road Landfill Charlotte, North Carolina Sample Date 3/24/2016 9/27/2016 3/27/2017 9/26/2017 3/30/2018 9/28/2018 4/5/2019 9/20/2019 3/31/2020 9/29/2020 3/25/2021 9/28/2021 1 3/30/2022 1 10/5/2022 3/28/2023 Constituent Units NC 2L 1, 1 -dichloroethane µ /L 6 1.7 6.5 6.1 5.5 5.7 - 5.7 4.8 8.0 .4 7.3 1, 1 -dichloroethene /L 350 - - - - - - - - - - - - 0.65 J 0.63 J 1,2-dichloroethane /L 0.4 - - - - - - - - 1,2-dichloro ro ane /L 0.6 - - - - - - 1.1 0.87 J 0.87 J 1,4-dichlorobenzene /L 6 - - - 1.5 - 2.6 - 0.66 J - 1,4-dioxane 3 - - - - - - - 1 1.5 Acetone /L 6,000 - - - - - - - - - - - - - - Barium L 700 24.0 25.0 26.7 22.7 25.2 45.9 30.0 27.5 26.8 29.5 26 28.6 22.3 - 23.6 Benzene /L 1 - - - - - - - - - - - - 0.5 J 0.63 J Cadmium L 2 - - - - - - - - Chloride /L 250,000 - - - - - - - - - - - - - - Chlorobenzene L 50 - 2.6 3.1 3.0 4.5 - 3.8 5.2 4.5 3.4 4.5 4.7 4.6 4.3 Chloromethane L 3 - - - - - - - - - - - - - - Chromium III+VI L 10 10.0 9.1 9.8 W 11.0 9.4 8.1 - - - - - - - - 4.4 cis-1,2-dichloroethene /L 70 2.5 12.3 12.1 11.6 14.7 - 13.9 19.8 15.7 17.0 12.4 16.5 20.3 19.2 19.6 COD L - - - - - - - - - - - - - - - - Dichlorodifluoromethane L 1 1,000 - - - - - - - - - - - 7 8 Specific Conductance S/cm - 366 362 361 354 366 307 329 342 346 353 334 346 395 355 1,092 Iron L 300 76.1 1,030 - 240.0 4,160 - 844 - 900 - 322 456 597 Lead L 15 - - - - - - - - - - Man anew L 50 7.0 19.0 12.9 293 102 78.1 75.8 102 79.3 27 Mercury L 1 - - - - - - - - - Nitrate as NO3- L 10,000 - - - - - - - - - - - - - - - H SU - 6.9 1 6.9 6.8 6.9 6.8 7.2 6.7 6.9 6.8 6.5 6.8 6.8 6.83 6.6 6.72 Sulphate L 250,000 - - - - - - - - - - - - - - - Temperature °C - 16.7 21.5 17.7 21.3 17.9 22.6 16.1 19.7 16.5 19.7 17.6 20 17 17.9 20.5 Tetrachloroethene µ /L 0.7 1.4 6.7 8.2 6.2 1.5 4.2 4.9 1 4.2 4.9 4.4 1 5.8 6.0 6.9 1 6.1 Toluene /L 600 - - - - - - - - - - - - - - 0.54 J Trichloroethene /L 3 3.1 3.8 2.6 4.9 6.4 4.4 4.4 3.1 3.9 5.8 5.3 5 Trichlorofluoromethane /L 1 2,000 - - - - - - - - - 0.5 - Turbidi - - - - Vinyl Chloride "gg/L 0.03 1.6 J 0.66 J 1.8 X lene (m & ) 500 - - - X lene o500 - - NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 2L was obtained from NCDEQ Solid Waste Section (https://deq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 2 of 2 Geosyntec Consultants of NC, P.C. Table 3-B Historical Groundwater Monitoring Data (DDW-01A) Former York Road Landfill Charlotte, North Carolina Sample Date 3/18/2008 9/17/2008 4/7/2009 9/9/2009 3/10/2010 9/23/2010 3/29/2011 9/21/2011 3/20/2012 9/26/2012 3/6/2013 9/10/2013 3/26/2014 9/23/2014 3/6/2015 Constituent Units NC 2L 1, 1 -dichloroethane /L 6 1.6 4.6 4.9J 6.3 5.1 6.0 5.4 3.3J 2.5J 2.3J 2.OJ 2AJ 7.1 0.63J 1.7 1,2-dichloroethane /L 0.4 - - - - - - - - - - - 0.17J 0.36J - - 1,2-dichloro ro ane /L 0.6 0.56J 0.52J 0.591 0.54J 0.70 - 0.50J 0.35J 0.42J 0.84J - 1,4-dichlorobenzene /L 6 - - - - - - - - - 0.68J - 1,4-dioxane /L 3 - - - - - - - - - 2-Hexanone MBK /L - - - - - - - - - - - 0.67J Acetone /L 6,000 - - - 1.2J - 14AJ - - - 19.7J - - Barium /L 700 52.0 85.0 91.0 89.01 80.OJ 80.0 438 56.3J 51.3J 44.6J 46.1J 79.8J 79.2 59.1J 52.3 Benzene /L 1 0.55 - - - 0AIJ 0.76J 0.29J - - - 0.32J - - Carbon Disulfide /L 700 - - - - - - 3.2 4.3J 2.7J 2.5J 3.1 J 4AJ - 3.OJ Chloride /L 250,000 - - 14,000 - - - - - - - - - - - Chlorobenzene /L 50 0.86J 3.1 3.5 3.2 3.9 4.3 3.0 1.91 1.01 1.2J 1.2J 1.3J 6.1 0.55J 1.1 Chloromethane /L 3 - - - - - - - - - 0.191 - - - - - Chromium III+VI /L 10 - - 0.7J 0.91 - 5.2 45.2 - - - - - - - cis- l,2-dichloroethene /L 70 2.8 9.4 11.0 14.0 12.0 14.0 11.5 7.8 5.6 5.5 4.8J 6.7 20.6 2.2J 4.9 COD /L - - - 37,000 - - - - - - - - - - - - Dichlorodifluoromethane /L 1,000 - - - - - - - - - - - - Ethanol /L - - - - - - - - - - - - - - - Specific Conductance µS/cm - - - - 526 528 504 509 601 466 531 497 488 Iron /L 300 - - 230 - 350J - - - - - - - - - - - Lead /L 15 - 1.5 - 0.12 - - - - - - - - - Man anew /L 50 - - 28.OJ - - - - - - - - - 7.3 Nitrate as NO3- /L 10,000 - - 400 - - - - - - - - - - - H SU - - - - - - 6.7 6.7 6.6 6.7 7.1 6.6 6.9 6.6 Selenium /L 20 1 - I- - -1 0.8J - - - - - - - - Sul hate /L 250,000 - - 150,000 - - - - - - - - - Trichloroethene /L 3 0.75J 4.4 4.5 5.5 4.9 3.0 1 2.0 1.7 1.6 1.4 5.7 0.55J Temperature °C - - - - - 16.1 17.7 17.7 16.5 16.3 16.9 16.9 16.8 Tetrachloroethene /L 0.7 4.6 3.5 2.1 - - 0.49J 0.55J 0.61J 0.501 6.7 - Trichlorofluoromethane /L 2,000 - - - - - 0.23J - - 0.21J - - - - Turbidi NTU I - - - - 26.0 34.0 8.0 6.0 1.0 2.0 3.5 Vinyl Chloride /L 0.03 - 0.72J 1.1J r 1.5 0.98J - - - X lene (m & ) /L 500 - 2.0 - - - - - - - 1.1J X lene o /L 500 - 1.0 - - i 0.56J NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 2L was obtained from NCDEQ Solid Waste Section (https://deq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 1 of 2 Geosyntec Consultants of NC, P.C. Table 3-B Historical Groundwater Monitoring Data (DDW-01A) Former York Road Landfill Charlotte, North Carolina Sample Date 9/22/2015 3/24/2016 9/27/2016 3/27/2017 9/26/2017 3/30/2018 9/28/2018 4/5/2019 9/20/2019 3/31/2020 9/29/2020 3/25/2021 9/28/2021 3/30/2022 10/7/2022 3/28/2023 Constituent Units NC 2L 1, 1 -dichloroethane /L 6 2.8 1.9 5.4 3.4 4.8 4.2 2.1 5.0 6.1 4.7 5.4 4.5 5.6 7.7 6.3 4.3 1,2-dichloroethane /L 0.4 - - - - - - - - - - - - - - - - 1,2-dichloro ro ane /L 0.6 - - - - - - - 1.3 .0 1,4-dichlorobenzene /L 6 - - - - - - - - - 1,4-dioxane /L 3 - - - - - - - - 4.7 2-Hexanone MBK /L - - - - - - - - - Acetone /L 6,000 - - - - - - - - 13.3 J Barium /L 700 45.4 55.8 72.9 64.0 67.5 72.2 69.4 67.5 66.5 63.6 64.2 65.1 83.5 34.1 - 60.8 Benzene /L 1 - - - - - 3.1 8.7 6.2 4.6 5.3 5.5 2.7 - 1.5 2.0 Carbon Disulfide /L 700 6.6 2.0 9.0 - 4.4 - 4.2 - 15.0 - - - - - Chloride /L 250,000 - - - - - - - - - - - - - - - - Chlorobenzene /L 50 1.9 1.3 3.6 1.6 3.7 3.3 1.0 3.4 4.1 3.2 3.3 3.3 4.9 4.2 2.8 Chloromethane /L 3 - - - - - - - - - - - - - - - Chromium III+VI /L 10 - - - - - - - - - - - - - - - - cis- l,2-dichloroethene /L 70 10.1 5.7 15.4 4.8 15.5 14.4 4.4 17.1 25.2 17.7 18.4 15.2 19.2 26.4 1 21.6 13.9 COD /L - - - - - - - - - - - - - - - - - Dichlorodifluoromethane /L 1,000 - - - - 1.11 Ethanol /L - - - - - 323 Specific Conductance µS/cm - 495 500 433 301 428 430 404 427 437 410 422 414 461 480 494 1,010 Iron /L 300 - - - - - - - - - - - - - - - Lead /L 15 - - Manganese /L 50 - - - - - Nitrate as NO3- /L 10,000 - - - - - H SU - 6.7 6.7 7.0 10.6 6.9 7.0 8.4 6.7 6.9 6.9 6.5 6.8 6.8 6.6 6.7 6.9 Selenium /L 20 - - - - - - - - - - - - - - - - Sul hate /L 250,000 - - - - - - - - - - - - Trichloroethene /L 3 2.0 .1 1.4 4.1 4.6 4.4 5.9 4.2 4.7 4.4 4.5 7.4 Temperature °C - 16.9 16.4 20.7 17.5 20.8 17.9 22.5 16.1 19.4 16.5 19.8 19.2 19.5 19.4 19.7 Tetrachloroethene /L 0.7 - - 1.7 1.0 1.0 0.71 J Trichlorofluoromethane /L 2,000 - - - - - - Turbidi NTU - 2.5 - - - - - - - Vinyl Chloride /L 0.03 2.6 3.4 1.3 1.4 1.2 1.7J 1.0 1.5 2.0 2.4 1.7 1.5 X lene (m & ) /L 500 - - X lene o /L 500 - NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 2L was obtained from NCDEQ Solid Waste Section (https://deq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 2 of 2 Geosyntec Consultants of NC, P.C. Table 3-C Historical Groundwater Monitoring Data (DDW-02) Former York Road Landfill Charlotte, North Carolina Sample Date 3/18/2008 9/17/2008 4/8/2009 9/10/2009 3/10/2010 9/23/2010 3/29/2011 9/20/2011 3/21/2012 9/26/2012 3/5/2013 9/10/2013 3/26/2014 9/23/2014 3/11/2015 Constituent Units NC 2L 1,1-dichloroethane /L 6 35.0 41.0 54.0 46.0 50.0 2.4 16.7 2.2J 5.3 4.0J 27.1 22.1 7.1 6.5 3.9 1,1-dichloroethene /L 350 0.60J 0.66J 1.0 - 0.911 - - - - - - - - 1,2-dichlorobenzene /L 20 - 0.59 - 0.35J 0.901 1,2-dichloroethane /L 0.4 - 0.54J - 0.31J 0.181 - 0.37J 0.18J 1,4-dichlorobenzene /L 6 0.60J 0.55J 1.0 0.72J 1.1 1.1 0.45J 0.93J 0.35J 1.6 1,4-dioxane /L 3 - - - - Arsenic /L 10 - - - - 1.4 - - - - Barium /L 700 65.0 76.0 100 84J 120 150 88J 84.9J 73.3J 121 106 87.7 89AJ 87.4 Benzene /L 1 1.1 1.4 2.1 1.1 2.0 - 1.0 - - - Cadmium /L 2 - - - - 1.7 - Chloride /L 250,000 54,000 - - Chlorobenzene /L 50 - 0.76J 0.80 0.86J 1.2J Chloromethane /L 3 - - 0.44J 0.28J Chromium (111+VI) /L 10 - 0.5J 0.81 0.6J 13.0 5.8 - - cis- l,2-dichloroethene /L 70 3.6 4.2 6.3 5.7 6.8 1.4 2.3 1.3J 0.86J 0.69J 4.7J 3.2J 1.4 1.2J COD L - - - 32,000J - - - -- Diisopropyl ether /L 70 - Specific ConductancePS/cm - 485 512 508 473 663 485 679 541 Iron /L 300 60J - - - - - - - - - Lead /L 15 1.7J 1.4J 1.7 - Manganese µ /L 50 - - - - - - - - 136 Mercury µ /L 1 0.27 0.24 7.2 0.52 0.21 - 0.12J 0.37 0.14J 0.14J 0.16J - H SU - - - - - 6.4 6.2 6.1 6.0 6.1 6.0 6.2 6.1 Selenium µ /L 20 - 4.1J 5.3 - - - - - - - - Sul hate µ /L 250,000 4,400 - - Trichloroethene µ /L 3 IAJ 1.4J 1.7J 1.3J 1.7J - - - - 1.0 0.56J - - Tem °C - - - - - - 16.9 18.3 17.9 17.5 16.7 17.6 17 17.4 Tetrachloroethene µ /L 0.7 1.4 1.2 1.4 1.1 1.3 0.46J - - - 1.2 0.63J - - Trichlorofluoromethane /L 2,000 - 1.0J - - - - - - 0.33J 0.21J - - Turbidit NTU - i - - - - - 65.0 29.0 2.0 8.0 1.0 5.0 5.0 Vinyl chloride /L 0.03 0.53J NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 2L was obtained from NCDEQ Solid Waste Section (https:Hdeq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 1 of 2 Geosyntec Consultants of NC, P.C. Table 3-C Historical Groundwater Monitoring Data (DDW-02) Former York Road Landfill Charlotte, North Carolina Sample Date 9/22/2015 3/22/2016 9/27/2016 3/27/2017 9/26/2017 3/30/2018 9/28/2018 4/5/2019 9/20/2019 3/31/2020 9/29/2020 3/25/2021 9/28/2021 3/30/2022 10/5/2022 3/28/2023 Constituent Units NC 2L 1,1-dichloroethane /L 6 3.7 1.6 11.4 10.0 8.4 8.2 9.9 8.6 9.8 8.4 6.8 4.7 6.5 9.2 6.6 8.9 1,1-dichloroethene /L 350 - - - - - - - - - - - - - - - - 1,2-dichlorobenzene /L 20 1.2 1.0 1.3 1.1 1.5 1.0 1.6 1.2 2.0 1,2-dichloroethane /L 0.4 - - - - - - - - - - - - - - 1,4-dichlorobenzene /L 6 1.5 2.2 1.7 2.1 2.5 2.3 2.1 2.8 2.31 3.6 2.6 - 1,4-dioxane /L 3 - - - - - - - - - - - 30.2 Arsenic /L 10 - - - - - - - - - - - - - Barium /L 700 86.1 83.8 161 194 173 208 218 259 218 277 251 324 265 177 - 336 Benzene /L 1 - - - - - - - - - 5.2 - - 1.3 - 0.51 J - Cadmium /L 2 2.0 2.5 2.9 1.5 1.9 1.4 1.8 - Chloride /L 250,000 - - - - - - - - - - - - - - Chlorobenzene /L 50 1.3 1.7 1.6 2.0 2.1 2.3 2.5 2.4 3.3 2.8 4.4 3.3 5.7 Chloromethane /L 3 - - - - - - - - - - - - - Chromium (III+VI) /L 10 - - - - - - - - - - - - - 2.0 cis-1,2-dichloroethene /L 70 3.1 2.9 2.6 2.6 2.9 2.5 3.2 2.5 2.0 1.3 1.9 2.2 1.6 2.3 COD /L - - - - - - - - - - - - - - - Diisopropyl ether /L 70 - - - - - - - - - - - - - - - 0.25 J Specific Conductance S/cm - 604 732 784 800 804 846 905 995 891 1,015 919 1,055 887 1,041 894 1,279 Iron µ /L 300 - - - - - - - - - - - - - - Lead /L 15 Manganese µ /L 50 - - - - - - - - Mercu µ /L 1 - - - - 0.42 0.63 1.2 2.3 - 0.55 0.24 0.22 0.61 - H SU - 6.1 6.4 6.2 6.0 6.1 6.2 5.9 6.0 6.1 6.0 6.0 5.9 6.0 5.9 5.7 6.0 Selenium µ /L 20 - - - - - - - - - - - - - - - - Sul hate µ /L 250,000 Trichloroethene µ /L 3 - - - - - - - - - - - - - Tem °C - 17.5 16.8 21.7 18.1 22.1 19.3 22.8 16.8 19.4 17.1 20.3 18.3 20.8 17.6 18.1 20.6 Tetrachloroethene µ /L 0.7 - Trichlorofluoromethane µ /L 2,000 Turbidity NTU - 2.5 Vinyl chloride /L 0.03 NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 21, are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 2L was obtained from NCDEQ Solid Waste Section (https:Hdeq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 2 of 2 Geosyntec Consultants of NC, P.C. Table 3-D Historical Groundwater Monitoring Data (DDW-03) Former York Road Landfill Charlotte, North Carolina Sample Date 3/19/2008 9/17/2008 4/l/2009 9/10/2009 3/10/2010 3/29/2011 9/20/2011 3/21/2012 9/25/2012 3/5/2013 9/10/2013 3/26/2014 9/24/2014 3/5/2015 9/23/2015 3/22/2016 Constituent Units NC 2L 1, 1 -dichloroethane /L 6 9.6 11.0 10.0 12.0 9.4 10.6 9.5 4.1J 4AJ 7.8 7.4 3.1 2.7J 2.4 2.9 1.2 1,2-dichlorobenzene /L 20 0.69J 0.981 1.2 0.73J 0.97J 1.0 - 0.34J 1.IJ 032J - 0.31J - - - 1,2-dichloroethane L 0.4 1.2 1.2 1.3 1.3 1.1 1.3 0.30J 0.8J 0.65 0.95J 1.1 0.7J 0.64J 1,2-dichloro ro ane /L 0.6 3.1 2.5 3.3 2.8 2.8 1.6 1.5 2.6 2.3 1.3 1.2 - 1,4-dichlorobenzene /L 6 6.0 6 7. 6.3 6.4 6.8 0.36J 2.8 2.5 3.6 2.5 2.6 2.3 2.5 1,4-dioxane /L 3 - - - - - - - - - - - - Acetone /L 6,000 18 2.7J TIJ Arsenic /L 10 3.2J - - 1.2J - - - - - - - - - - - Barium /L 700 300 310 310 330 300 376 384 378 349 386 366 369 371 394 410 367 Benzene L 1 0.54 0.62 0.55 0.59J 0.51J 0.50J - - - 0.46J - - - - - - Cadmium /L 2 - - - 2.0 Chloride /L 250,000 - - 240,000 - - - - - - - Chlorobenzene /L 50 3.1 3.6 3.3 2.9J 3.5 3.8 IAJ 1.3J 4.3 2.1J 1.3 1.3J 1.1 1.3 Chromium III+VI /L 10 - - 0.7J 1.1J - - - - - - - 6.9J - - - cis- l,2-dichloroethene /L 70 41.0 47.0 46.0 53.0 42.0 46.7 1.4J 19.5 19.1 32.8 33.5 14.7 13.8 11.9 14.5 6.4 COD /L - - 92,000 - - - - - - - - - - - - Diisopropyl ether /L 70 - - - - - - - - - - - Specific ConductancePS/cm 1,366 1,387 1,470 1,550 1,470 1,580 1,530 1,564 1,563 1,453 Lead /L 15 3.6J - - - - - - - - - - Merc /L 1 0.03J 0.16J - 0.12J - O.1J - - - - H SU 6.0 6.1 6.0 5.9 6.0 5.9 6.2 6.0 6.1 6.1 Selenium L 20 - - - - - - - - 14.8 - - Sul hate /L 250,000 8,600 - - Trichloroethene /L 3 8.6 1 9.4 9.2 6.8 - - 2.5 7.5 4.5 2.3 2.6 1.7 1.6 - Temp °C - - - - - 16.2 17.8 17.3 17.1 16.1 17 14.5 17 - 17 16.7 Tetrachloroethene /L 0.7 3.4 3.4 2.9 3.1 3.0 - 2.8 1.1 0.56J trans-1,2-dichloroethene /L 1 100 1.6J 1.6J 1.7J 1.91 1.5J 1.6 1.2J 0.78J Trichlorofluoromethane /L 1 2,000 0.40J - - - TurbidityNTU - - - - - 56 33 5 6 1 2 1 2 1 9.5 Vin l chloride /L 1 0.03 8.6 8.1 9.0 1 6.0 6.9 0.89J 0.911 3.8 1.6 0.73J I 0.73J NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 2L was obtained from NCDEQ Solid Waste Section (https://deq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 1 of 2 Geosyntec Consultants of NC, P.C. Table 3-D Historical Groundwater Monitoring Data (DDW-03) Former York Road Landfill Charlotte, North Carolina Sample Date 9/27/2016 F 3/27/2017 9/26/2017 3/30/2018 9/28/2018 4/5/2019 9/20/2019 3/31/2020 9/29/2020 3/25/2021 9/28/2021 3/30/2022 10/5/2022 3/28/2023 Constituent Units NC 2L 1, 1 -dichloroethane /L 6 5.3 3.8 4.3 3.4 - 3.5 4.2 3.7 4.5 3.5 3.7 3.1 - 3.3 3.0 3.6 - 4.0 3.7 - 4.0 2.8 - 4.7 1,2-dichlorobenzene /L 20 1.2 - - - - - - - - - 1.3 - 1.6 1.5 - 1.6 0.89 J - 1.4 1,2-dichloroethane /L 0.4 - - - - - - - - 0.45 J 1,2-dichloro ro ane /L 0.6 1.9 1.7 2.3 - 2.5 1.6 1.8 7 1.9 1.4 - 1.5 1.7 1.7 - 2.3 2.1 - 2.3 1.6 - 2.5 1,4-dichlorobenzene /L 6 5.9 4.6 2.7 4.1 2.6 2.6 - 2.5 1.9 - 2.0 2.3 6.6 - 7.2 7.1 - 8.1 4.4 1,4-dioxane /L 3 - - - - - - - - - 81.3 - 81.4 Acetone /L 6,000 11.0 J 14.2 J Arsenic /L 10 - - - - - - - - - - - - Barium L 700 415 438 373 417 - 418 424 417 407 420 447 421 - 423 418 398 - 410 423 - 432 Benzene /L 1 - - - 1.4-1.6 1.4 1.5 - - - 1.4 0.37 J - 0.45 J 0.51 J - 0.53 J Cadmium /L 2 - - 2.2 Chloride /L 250,000 - - - - - - - - - Chlorobenzene /L 50 4.0 3.5 3.2 2.3 - 2.4 3.6 2.5 3.1 2.8 2.5-2.6 2.9 5.4 - 6.3 6.4 - 7.0 4.7 - 7 Chromium III+VI /L 10 - - - - - - - - - - cis- l,2-dichloroethene 70 28.6 21.0 21.8 17.1 - 18.9 21.8 17.3 25.6 17.5 17.0 14.4 - 14.9 14.9 19.7 - 22.2 21.1 - 22.1 14.6 - 25.5 COD L - - - - - - - - Diisopropyl ether /L 70 - - - - - - - - - - - - - 0.37 J - 0.53 J Specific ConductanceAS/cm - 1,588 1,579 1,544 1,495 1,615 1,555 1,625 1,564 1,613 1,623 1,611 1,550 1,446 2,236 Lead L 15 - - 7.9 - - - - - - - - - - - Merc 1 - - - - - - 0.51 - - - - - - H SU 6.2 6.1 6.2 6.5 6.2 6.1 6.2 6.2 6.1 6.1 6.2 6.1 5.8 6.4 Selenium L 20 - - - - - - - - - - - - - - Sul hate /L 250,000 Trichloroethene /L 3 3.1 2.7 2.5 3.1 2.9 2.3 1.7- 1.9 1.9 2.8 - 3.4 3.3 - 3.5 2.7 - 3.4 Temp °C - 20.6 17.2 20.9 17.1 21.4 16.2 18.7 16.3 20.3 17.4 19.4 16.3 17.7 18.8 Tetrachloroethene /L 0.7 1.0 - - - - - - - - 0.47 J - 0.59 J trans-1,2-dichloroethene /L 100 0.56 J - 0.65 J Trichlorofluoromethane /L 2,000 Turbidity NTU - - Vin 1 chloride 0.03 1 3.0 1 2.2 1 2.9 3.0 2.4 - 2.4 2.5 - 2.8 1 2.6-2.9 NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 2L was obtained from NCDEQ Solid Waste Section (https://deq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR23OO86 Page 2 of 2 Geosyntec Consultants of NC, P.C. Table 3-E Historical Groundwater Monitoring Data (DDW-03A) Former York Road Landfill Charlotte, North Carolina Sample Date 3/26/2008 1 9/17/2008 1 4/l/2009 1 9/10/2009 1 3/10/2010 1 3/29/2011 1 9/20/2011 1 3/21/2012 1 9/25/2012 1 3/6/2013 1 9/10/2013 1 3/26/2014 1 9/23/2014 1 3/11/2015 1 9/23/2015 1 3/22/2016 Constituent Units NC 2L 1,1-dichloroethane 6 0.40J 0.42J - - Acetone 6,000 1,300 1,100 12.0 Arsenic 10 2.4.1 2.5J - - - Barium 700 53.0 52.0 40.0 49J 39J 42.6 34.4.1 41.3J 32.7J 33.3J 31.4J 32.1 31.1J 30.8 40.9 41.9 Benzene 1 - - Cadmium 2 Carbon disulfide 700 Chloride 250,000 8,000 Chloromethane 3 - 0.62J Chromium III+VI 10 0.81 0.7J I.I.I 11.8 - 5.2J cis-1,2-dichloroethene 70 0.96J 1.8 1.1 1.01 23J 3.0 3.7J 2.1J 1.3J 1.91 2.1J 1.6 2.0 1.4 1.7 1.3 COD - - - 59,000 - - - - - - - - - - - Specific ConductancePS/cm 1,056 1,053 1,010 1,020 1,220 922 1,150 987 1,087 1,079 Iron L 300 110J - - - - - - 54.1 Lead 15 2.7.1 1.4J Manganese 50 16 Mercury L 1 0.011 - - 0.191 - - - - - - H SU 7.2 6.5 8.1 8.1 8.2 8.2 7.8 7.2 8.0 8.1 Selenium 20 5.3J - 6.5.1 - - - - - 23.4 - - Sul hate L 250,000 510,000 - - - Trichloroethene /L 3 0.82J 0.86.1 0.60J 0.76J 0.67.1 0.51J Temp °C - 15.9 18.0 18.3 17.8 14.5 19.7 16.0 16.8 17.6 17.2 Turbidity NTU - 82.0 73.0 59.0 29.0 6.0 12.0 41 20.6 X lene m & L 0.91J - X lene o L 0.42J NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 2L was obtained from NCDEQ Solid Waste Section (https:Hdeq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 1 of 2 Geosyntec Consultants of NC, P.C. Table 3-E Historical Groundwater Monitoring Data (DDW-03A) Former York Road Landfill Charlotte, North Carolina Sample Date 9/27/2016 1 3/27/2017 1 9/26/2017 1 3/30/2018 1 9/28/2018 1 4/5/2019 1 9/20/2019 1 3/31/2020 1 9/29/2020 1 3/25/2021 1 9/28/2021 1 3/30/2022 1 10/5/2022 1 3/28/2023 Constituent Units NC 2L 1,1-dichloroethane 6 - Acetone 6,000 31.8 42.7 37.7 27.9 Arsenic L 10 - Barium 700 31.7 41.9 33.9 39.5 37.0 36.6 33.2 35.1 33.9 33.0 31.8 30.1 29.8 Benzene 1 1.1 2.0 3.8 4.2 3. 4.0 5.1 Cadmium 2 - - - 1.2 Carbon disulfide 700 3.9 8.9 3.5 - Chloride L 250,000 - - - Chloromethane /L 3 Chromium III+VI 10 cis-1,2-dichloroethene 70 1.0 0.32 J COD - - - - - - - Specific ConductancePS/cm 1,081 1,074 - 1,055 1,003 1,009 1,019 991 975 968 965 903 793 1,549 Iron L 300 - 176 - - - - - - - - Lead 15 6.5 - Man anew L 50 Mercury L 1 - - - - - - - - - - - H SU 7.4 7.2 7.5 7.6 7.7 8.0 7.8 7.7 7.7 7.8 7.8 7.99 7.91 Selenium L 20 - - - - - - - - - - - Sul hate /L 250,000 - Trichloroethene L 3 - Tem °C 20.4 16.6 18.5 21.6 15.6 19.6 15.9 19.9 17.0 19.6 16.4 17.1 18.8 Turbidity NTU - X lene m & L - - - - - - - - - - - - - - X lene o L NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected 4. NC 2L was obtained from NCDEQ Solid Waste Section(https:Hdeq.nc.gov/abouUdivisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 2 of 2 Geosyntec Consultants of NC, P.C. Table 3-F Historical Groundwater Monitoring Data (DMW-01) Former York Road Landfill Charlotte, North Carolina Sample Date 3/18/2008 9/16/2008 9/18/2008 4/6/2009 1 9/9/2009 1 3/11/2010 9/23/2010 3/31/2011 9/20/2011 3/19/2012 9/24/2012 3/4/2013 9/9/2013 3/25/2014 9/22/2014 3/6/2015 Constituent Units NC 2L 1,1-dichloroethane /L 6 1.0 1.2 - 1.7J 1.6J 0.88J 1.0 0.85J 1.3J 0.94J 0.84J 1.1J 1.4J 1.1 1.11 - 1,2-dichlorobenzene /L 20 8.6 10 7.0 9.0 10 5.8 4.9 5.0 5.3 5.4 6.1 5.6 5.2 5.3 4.0 1,2-dichloroethane /L 0.4 - - - - - - - 0.18J - 0.13J - - 0.191 - - 1,2-dichloro ro ane /L 0.6 3.0 3.6 3.6 3.1 3.0 3.0 3.1 3.3 3.1 3 3.2 2.8 1,4-dichlorobenzene /L 6 23 26 21 17.1 16.1 17.0 17.6 19.3 18.6 18.1 21.3 17.0 Acetone /L 6,000 280 1511 41J 6.2J 760L 4.6J 2.9J - - Arsenic /L 10 3.5J 3.1J 2.1J - - 0.82J 2.7J 8.01 6.2J 7.01 - 5.5J 6.9J - Barium /L 700 140 160 170 120 110 120 160 182 178 173 156 138 139 125 144 Benzene /L 1 1.8 1.7 - 1.7 0.98J 1.1 0.77J 1.8 1.7 1.3 .5 1.5 1.3 0.911 1.1 Cadmium /L 2 - 1.3 1.0 0.6J 0.48J 2.2 - 1.8 - 1.4 2.3 2.4 L 12.5 Carbon disulfide /L 700 - - - 1.3J - Chloride /L 250,000 24,000 - - - - - Chlorobenzene /L 50 2.8 3.2 1.0 2.1 3.1 2.8 2 2J 2.1J 2J 2.3J 2.4J 2.3 3.2 2.4 Chromium III+VI /L 10 - - - - - 6.4 - - - - - - - - - cis- l,2-dichloroethene /L 70 60 75 35 78 54 60 49.3 45.9 40.3 42.7 38.1 43.7 38.8 39.6 34.0 COD /L - - 53,000 - - - - - - - - Field Specific Conductance S/cm - - - - - - - 551 707 590 442 621 529 648 575 - Iron /L 300 40,000 36,000 21,000 - 40,000 45,000 28,000 20,000 27,700 32,700 29,800 28,400 26,800 29,100 29,300 39,400 47,400 Lead /L 15 - - - - - 0.801 - 5.7J 5.9J - - - - - 6.3 Manganese /L 50 11,000 48,000 9,700 10,000 1 8,700 18,000 21,800 21,500 19,000 16,200 15,900 13,500 13,400 22,200 22,600 Mercury /L 1 - - - - - - 0.31 - - - - - - - - Meth 1 ethyl ketone /L 4,000 - - Nitrate as NO3- /L 10,000 400 - - - - - - - - H Field pH -Units - 6.0 6.1 5.9 6.1 1 6.2 6.0 6.0 5.7 Selenium /L 20 7.0J 0.83J - - - - - - Silver /L 20 0.3J 1.1J 2.3J Sulphate /L 250,000 4100J - - - Trichloroethene /L 3 0.98J I 0.59J 3.4 1.SJ 2.3 1.7 1.7 0.87J 1 1.2 0.91 0.56J Temp oC - - 17.3 19.4 20.9 19 17.2 20 16.7 19.6 Tetrachloroethene /L 0.7 0.68J - - 0.47J - - - - - Toluene /L 600 - - - - - trans- l,2-dichloroethene /L 100 1.6J 1.6.1 0.68J 1.5J 1.1.1 1.6 1.1 1.01 0.74J 0.79J 0.83J 0.87J 0.69.1 0.85.1 Turbidity NTU - - - - - - - 36 63 4 3 4 13 12 Vinyl chloride /L 0.03 6.8 7.1 8 5.3 5.4 2.6 3.8 2.5 2.5 2.0 2.5 4.1 X lene m & /L 2 X lene o /L 1 NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 2L was obtained from NCDEQ Solid Waste Section (https:Hdeq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 1 of 2 Geosyntec Consultants of NC, P.C. Table 3-F Historical Groundwater Monitoring Data (DMW-01) Former York Road Landfill Charlotte, North Carolina Sample Date 9/21/2015 3/24/2016 9/28/2016 3/27/2017 9/26/2017 3/30/2018 9/27/2018 4/5/2019 9/20/2019 3/31/2020 9/29/2020 3/25/2021 9/28/2021 3/30/2022 10/5/2022 3/28/2023 Constituent Units NC 2L 1,1-dichloroethane /L 6 1.2 - 1.3 1.6 2.2 1.6 1.1 - - - - - - - - - - - 1,2-dichlorobenzene /L 20 5.0 - 5.1 3.6 1.8 - 1,2-dichloroethane /L 0.4 - - - - - - - - 1,2-dichloro ro ane /L 0.6 2.7 - 2.9 2.5 2.2 1.2 1.9 1.5 0.51 J 1,4-dichlorobenzene /L 6 17.7 - 18.5 7.0 4.0 3.1 - 1.5 2.6 10 - - - Acetone /L 6,000 - 103 138 - - 115 144 Arsenic /L 10 - - - - - - - - - - - - - Barium /L 700 136 - 137 111 142 144 105 91.3 104 93.8 189 70.9 198 60.4 133 - 148 52.5 - 71.5 Benzene /L 1 1.5 - - - - - 73.6 - 14.3 - - - 2.8 - 3.3 - 1.2 - Cadmium /L 2 3.0 - 3.9 1.1 35.1 8.3 26.2 27.2 62.7 23.2 11.2 10.0 20.1 - 23.6 20.2 5.3 44.5 Carbon disulfide /L 700 Chloride /L 250,000 Chlorobenzene /L 50 2.5 2.7 1.7 - Chromium III+VI /L 10 - 5.6 5.6 - - - - - - - - 2.0 cis-1,2-dichloroethene /L 70 30.2 - 31.1 23 29.6 21.0 18.0 2.1 5.5 1.1 12.9 13.4 8.0 - 8.7 3.9 2.2 COD /L - - - - Field Specific Conductance S/cm - 659 478 602 475 395 318 215 54.1 188 103 469 69.5 230 91.0 139.9 767 Iron /L 300 38,900 - 39,000 17,100 20,700 - 23,600 - 11,200 14,400 - 55,400 - 28,400 - 30,300 4,680 16,900 16,100 Lead /L 15 - - - - - - - - - - Man anew /L 50 16,300 - 17,800 22,600 23,100 11,100 1,550 4,310 119400 4,380 - 4,770 804 19220 665 Mercury /L 1 - - - - - - - - - Meth 1 ethyl ketone /L 4,000 5.2 Nitrate as NO3- /L 10,000 - - - - - - - - - - - - - H Field H Units 6.1 6.1 1 6.1 5.8 6.0 6.5 5.7 4.8 5.7 6.2 5.7 5.8 5.7 5.6 5.3 5.8 Selenium /L 20 - Silver /L 20 Sulphate /L 250,000 Trichloroethene /L 3 - 3.8 Temp oC - 19.2 18.1 22.6 18.7 21.2 19.0 22.3 15.2 18.7 17.9 20.2 17.3 19.8 16.1 17.4 18.2 Tetrachloroethene /L 0.7 - - - - - - - - - Toluene /L 600 1.0 trans-1,2-dichloroethene /L 100 - Turbidi NTU - 6.0 - Vinyl chloride /L 0.03 1.9 - 2.1 2.8 3.2 2.3 1 2.6 1.2 1.1 2.3 3.2 1.4 0.93 J X lene m & L - X lene o /L I - NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 21, Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 21, are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 2L was obtained from NCDEQ Solid Waste Section (https:Hdeq.ne.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 2 of 2 Geosyntec Consultants of NC, P.C. Table 3-G Historical Groundwater Monitoring Data (DMW-02) Former York Road Landfill Charlotte, North Carolina Sample Date 3/20/2008 9/16/2008 3/31/2009 9/10/2009 3/11/2010 3/30/2011 9/19/2011 3/19/2012 9/24/2012 3/4/2013 9/9/2013 1 3/25/2014 1 9/22/2014 1 3/6/2015 1 9/21/2015 1 3/23/2016 Constituent Units NC 2L 1,4-dioxane /L 3 - - - - - - - - - - - - - - - - Acetone 6,000 33 24 5.9JL Arsenic 10 2.8J 3.1J - 2.9J - - - - - - Barium 700 32 57 25 47J 69J 27.9 25.2J 46.1 J 32.8 - 34.7J 46.3J 29.6J 23.3 19.2J 30.8 22.3 36.9 Cadmium 2 - - - - - - - - - - - Chloride /L 250,000 6,100 - - - - - - - - Chloromethane /L 3 - 0.13J Chromium (III+VI) 10 I AJ 0.6J 2.OJ 1.07 cis-1,2-dichloroethene 70 COD - 17,000J - - - - - - - - - - Specific Conductance S/cm - - - 1,254 1,390 1,210 918 1,250 1,320 1,310 1,170 - 1,216 1,249 Iron WL 300 1,100 7,000 50-1,300J 4,300 - 4,400 8,500 1,850 885 4,800 2,390 - 2,710 4,750 2,090 1,530 2,300 2,540 727 2,990 Lead L 15 11 5.9 - 3.8 - 4.1 J 7.0J - - 5.6J - - - - - - - - Man anew 50 69 160 57 110 -120 170 63 52 108 73 - 76 110 66 60 70 72 49 75 Methyl Ethyl Ketone L 4,000 - - - - - - - - - - - - - - - - H SU - 6.9 7.6 7.1 7.5 6.9 7.4 7.5 7.3 7.2 7.6 Selenium 20 4.5J - 7.9J - - - - - - 32.8 - - Sul hate 250,000 670,000 - - - - - - - - - - Temp °C - I - 17.0 20.0 19.9 20.1 17.1 20.5 17.2 19.5 19.4 17.9 Toluene µg/L NTU 1 - - - Turbidi - - - 13.0 245 158 77.0 39.0 109 100 81.6 1 - NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 2L was obtained from NCDEQ Solid Waste Section (https://deq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 1 of 2 Geosyntec Consultants of NC, P.C. Table 3-G Historical Groundwater Monitoring Data (DMW-02) Former York Road Landfill Charlotte, North Carolina Sample Date 9/28/2016 1 3/27/2017 1 9/26/2017 1 3/30/2018 1 9/27/2018 1 4/5/2019 1 9/20/2019 1 3/31/2020 1 9/29/2020 1 3/25/2021 1 9/28/2021 1 3/30/2022 1 10/5/2022 3/28/2023 Constituent Units NC 2L 1,4-dioxane /L 3 - - - - - - - - - - - - - 0.38 J Acetone 6,000 - - - Arsenic 10 - - - - - - - - - - - Barium 700 18.5 18.2 11.9 17.4 167 32.1 28.1 40.4 55.9 44.5 8.8 19.0 26.1 Cadmium 2 - - - - - - - - - - 3.0 - - Chloride 250,000 Chloromethane 3 Chromium III+VI) 10 cis-1,2-dichloroethene L 70 1.8 1.8 COD L - - - - - - - - - - - - Specific Conductance S/cm - 1,257 1,273 1,241 1,237 948 1,165 596 1,073 801 1,068 166 287 111 920 Iron L 300 - 141 - 1,550 -1,630 - 4,920 - 2,210 - 6,190 2,910 5,910 3,840 Lead L 15 - - - - - - - - - Man anew L 50 39 37 3,380 1,210 464 748 789 2,520 2,950 Methyl Ethyl Ketone L 4,000 - - - - - - - - - - - - - - H SU - 7.3 7.4 7.5 7.2 6.8 7.4 6.6 7.3 6.6 7.3 6.8 7.1 6.6 7.4 Selenium 20 - - - - - - - - - - - - - - Sul hate 250,000 - - - - - - - - - - - - Tem °C - 23.6 19.7 24.3 20.1 24.3 18.4 22.7 17.6 24.1 19.3 23.5 16.0 18.5 20.8 Toluene µg/L NTU 1 0.78 J Turbidity - NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detecte 4. NC 2L was obtained from NCDEQ Solid Waste Section (https://deq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 2 of 2 Geosyntec Consultants of NC, P.C. Table 3-H Historical Groundwater Monitoring Data (DMW-02A) Former York Road Landfill Charlotte, North Carolina Sample Date 3/19/2008 9/16/2008 4/3/2009 9/11/2009 3/11/2010 3/30/2011 9/19/2011 3/22/2012 9/27/2012 3/5/2013 9/11/2013 3/25/2014 9/22/2014 3/12/2015 9/22/2015 Constituent Units NC 2L 1, 1 -dichloroethane /L 6 - - - - - 2.0 - 1.6J - - - - - - - 1,2-dichloroethane /L 0.4 - - - - - - - - - 1,4-dichlorobenzene /L 6 - - - - - 0.56J - 0.56J - - - - - - Methyl Ethyl Ketone /L 1 4000 6.0 8.9 3.8J 3.7J 5.1J - - 8.7J 5AJ 7.5J 4.8J 6AJ 8.1 2-hexanone MBK /L - 4.2 3.3 - - - - - - 0.48J 2.91 - - 5.9 Acetone /L 6 000 6,700 6,800 4,100 5,4001 - 4,000 - 1,430 471 318 115 131 112 120 Arsenic /L 10 4.7J 3.1J - 2.5J - - - - - 5.9J - - - - Barium /L 700 130 160 330 420 576 72.2J 1,020 1,130 1,180 Benzene /L 1 - - - - - 0.41J - 0.45J - - - - - - - Bromomethane /L - - - - - - - - - - - Cadmium /L 2 - - - - - - - - Chloride /L 250,000 - 4,000 - - - - - - - Chlorobenzene /L 50 - - - - 0.76J 0.73J - - - Chloromethane /L 3 - - - - - 0.44J - 0.54J - - - - - Chromium III+VI /L 10 11 9.3 8.9J 6.7J 7.5 9.5J 5AJ - 6.3J 6.OJ 7.0 9.91 6.2 5.9 cis-1,2-dichloroethene /L 70 - - - - - 3.5 3.2J - - - - - - COD /L - - 210,000 - - - - - - - - Ethanol /L - - - - - - - - - - - - - - Specific Conductance S/cm - - - 8,150 8,350 8,240 7,040 7,370 7,360 7,710 6,750 7,146 Iron /L 300 - 88J - - - - - - - - - - Lead /L 15 2.6J 1.8J - 1.3J 2.7J - 5.0 - - - 12.1 15.2 Nitrate as NO3- /L 10,000 2,400 - - - - - - - - - - H SU - - - 12.7 12.3 12.5 12.4 12.6 12.4 12.4 10.8 12.3 Selenium /L 20 6.OJ 7.7J - 11J - - - - - - - 50.4 - Silver /L 20 - - 13.5 - 12.4 16.1 - 17.1 Sulphate /L 250,000 59,000J - - - - - - Trichloroethene /L 3 - - 0.58J - 0.811 - - - - - - Temp °C - - - 15.2 17.3 19.0 17.0 15.5 18.6 16.0 18.9 16.1 Tetrachloroethene /L 0.7 - - 0.95J - 1.1 - - - - - - Toluene /L 600 - - - - - - - - - Turbidi NTU 34 0 3 47 1 30.2 NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 2L was obtained from NCDEQ Solid Waste Section (https://deq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 1 of 2 Geosyntec Consultants of NC, P.C. Table 3-H Historical Groundwater Monitoring Data (DMW-02A) Former York Road Landfill Charlotte, North Carolina Sample Date 3/24/2016 9/28/2016 3/27/2017 9/26/2017 3/30/2018 9/27/2018 4/5/2019 9/20/2019 3/31/2020 9/29/2020 3/25/2021 9/28/2021 3/30/2022 10/7/2022 3/28/2023 Constituent Units NC 2L 1, 1 -dichloroethane /L 6 - - - - - - - - - - - - - - - 1,2-dichloroethane /L 0.4 - - - - - - - - - - - 1,4-dichlorobenzene /L 6 - - - - - - - - - - - - - - Meth 1 Ethyl Ketone /L 1 4000 - - - 12.9 6.7 6.6 6.6 8.8 12.4 8.4 13.0 10.0 11.6 10.9 2-hexanone MBK /L I - - - - - - - - - - - - - - - - Acetone /L 6 000 57.7 70.4 73.6 57.1 61.1 93.2 74.0 99.8 95.1 114 109 118 107 135 118 Arsenic /L 10 - - - - - - - - - - - - - Barium /L 700 1,460 1,270 1,210 1,390 1,410 1,280 0 1,240 1,260 1,120 1,090 1,090 Benzene /L 1 - - - - - - - - - - - - 0.34 J - Bromomethane /L - - - -I - - - 10.7 Cadmium /L 2 - - - - 3.4 - - - Chloride /L 250,000 - - - - - - - Chlorobenzene /L 50 - - - - - - - Chloromethane /L 3 - - - - - - 0.65 J Chromium III+VI /L 10 5.9 5.2 5.2 - 5.1 - 5.3 - 5.8 6.7 6.5 cis-1,2-dichloroethene /L 70 - - - - - - - - - - COD /L - - - - - - - - Ethanol /L - - - - - - - - - - - - - - - 111 J Specific Conductance S/cm - 7,830 6,708 6,800 6,522 6,538 6,309 6,891 6,701 6,114 6,140 5,974 5,627 5,086 4,480 5,925 Iron /L 300 - - - - - - - - - - - - - - - Lead /L 15 5.7 - - 6.2 - - - - - - 614 187 Nitrate as NO3- /L 10,000 - - - - - - - - - - - H SU - 12.5 12.4 12.4 12.4 12.5 12.0 12.3 12.3 12.4 11.9 12.3 12.2 12.9 12.37 - Selenium /L 20 - - - - - - - - - - - - - - - Silver /L 20 - - - - - - - Sulphate /L 250,000 - - - - - - - - Trichloroethene /L 3 - - - - - - - - - - - - - - - Temp °C - 16.5 21.9 16.8 23.0 18.1 22.2 17.7 19.0 16.0 21.8 17.5 23.1 14.3 21.4 18.8 Tetrachloroethene /L 0.7 - - - - - - - - Toluene /L 600 - - - - 0.99 J Turbidi NTU - - - - - NC 21, - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 21, was obtained from NCDEQ Solid Waste Section (https://deq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 2 of 2 Geosyntec Consultants of NC, P.C. Table 3-I Historical Groundwater Monitoring Data (DMW-O2B) Former York Road Landfill Charlotte, North Carolina Sam le Date 3/19/2008 1 9/16/2008 1 4/3/2009 1 9/10/2009 1 3/11/2010 1 3/30/2011 1 9/22/2011 1 3/22/2012 1 9/27/2012 1 3/7/2013 1 9/11/2013 1 3/25/2014 1 9/25/2014 1 3/12/2015 1 9/22/2015 3/22/2016 Constituent Units NC 2L 1,1-dichloroethane /L 6 1.9 1.8 LU 2.5J 1.7J 2.2 1.91 1.7J 1.91 0.94J 1AJ 1.8 1.4 1,2-dichlorobenzene /L 20 - - - - - - - - - - - - - - - - 1,2-dichloroethane L 0.4 1.4 1.3 1.3 4 1.1 0.99J 1.0 6J 0.76J 1,4-dichlorobenzene /L 6 0.64J 0.63J 0.57J 0.72J 0.64J 0.581 0.50J 0.42J 0.59J 0.39J 0.65J 1,4-dioxane /L 3 - - - - - - - - - - - - - - - - 2-hexanone MBK /L - - - - - - - - 0.80J - - - - - - - - Acetone /L 6,000 33 56 4.1JL 2.7J 5.9J 1,760 Arsenic /L 10 3.3J 2.3J 2.3J 4.7J 1.5J Barium /L 700 7.OJ 8.5J 7.3J 8.01 15.OJ 35.1 16.1J 12.8J 17AJ I3.5J 10.9 51.0 13.5 1 10.5 30.0 Benzene /L 1 0.52 0.53J 0.44J 0.50J 0.37J 0.25J 0.31J Carbon disulfide /L 1 - - - - - - - - - - - - - - - - Chloride /L 250,000 - - ,29000 - - - - - - - - - - - - - Chlorobenzene /L 50 0.59J 0.65J 0.65J 0.801 0.71J 0.51J 0.92J 0.55J 0.32J 1.0J Chromium III+VI /L 10 0.7J 0.4 0.91 IAJ 13.3 6.5J 10.7 cis-1,2-dichloroethene /L 70 2.1 2.5 2.0 3.0 2.6J 3.5 3.3J 1.5J 3.4J 3.8J 2.1 4.1J 2.6 5.9 4.7 COD /L - - - ,24000J - - - - - - - - - - - - - Specific Conductance S/cm 447 450 350 469 507 399 468 455 455 467 Iron /L 300 - - 120J - - - - - - - - - - - - - Lead /I, 15 2.0 - - - - - - - - - - - - - - - H SU 8.0 7.5 7.9 9.3 7.7 7.9 7.6 7.8 8.7 7.7 Selenium /L 20 4.9J 4AJ 5.1J Silver /L 20 - - - - - - - 14.7 - - - - - - - - Sul hate /L 250,000 - - 62,000 - - 11- - - - - - I - - - - - Trichloroethene /L 3 0.61J 0.66J 0.52J 0.60J 0.891 0.70J 0.881 1.8 Temp °C 16.0 17.0 19.9 17.3 15.6 18.7 15.0 16.9 16.5 19.4 Tetrachloroethene /L 0.7 0.55J 0.64J 0.64J 0.80J 1.1 0.991 1.0 1.6 0.991 1.5 1.4 Turbidi NTU 259 790 95 82 35 53 165 24.2 Vin 1 chloride I lAg/L 0.03 NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 2L was obtained from NCDEQ Solid Waste Section (https://deq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR23OO86 Pagel of 2 Geosyntec Consultants of NC, P.C. Table 3-I Historical Groundwater Monitoring Data (DMW-02B) Former York Road Landfill Charlotte, North Carolina Sam IeDate 9/28/2016 1 3/27/2017 1 9/26/2017 1 3/30/2018 1 9/27/2018 1 4/5/2019 1 9/20/2019 1 3/31/2020 1 9/29/2020 1 3/25/2021 1 9/28/2021 1 3/30/2022 1 10/5/2022 3/28/2023 Constituent Units NC 2L 1,1-dichloroethane /L 6 1.5 1.2 1.2 1.1 1.2 2.1 1.4 1.3 2.0 2.4 1,2-dichlorobenzene /L 20 0.36 J 1,2-dichloroethane /L 0.4 0.51 J 1,4-dichlorobenzene /L 6 2.0 2.1 1,4-dioxane /L 3 8.9 2-hexanone MBK /L - - - - - - - - - - - - - - - Acetone /L 6,000 - - - - - - - - - - - - - - Arsenic /L 10 - - - - - - - - - - - - - - Barium /L 700 8.4 8.3 5.8 6.5 6.9 8.0 7.8 8.1 7.1 11.1 9.6 10.0 14.2 Benzene /L 1 1.1 3.3 2.3 4.9 5.0 1.7 1.3 2.5 2.8 1.0 2.0 Carbon disulfide /L 1 3.6 Chloride /L 250,000 - - - - - - - - - - - - - - Chlorobenzene /L 50 1.2 2.0 1.9 Chromium I11+VI /L 10 - - - - - - - - - - - - - - cis- l,2-dichloroethene /L 70 6.1 4.3 4.6 4.6 3.3 4.0 5.7 3.6 1 11 5.3 COD /L - - - - - - - - - - - - - - - S ecific Conductance S/cm 499 471 471 468 391 529 398 647 431 670 632 756 495 823 Iron /L 300 - - - - - - - - - - - - - - Lead /L 15 - - - - - - - - - - - - - - H SU 9.8 7.5 7.7 7.5 7.3 8.2 7.5 7.4 7.3 7.3 7.4 9.0 7.1 7.4 Selenium /L 20 - - - - - - - - - - - - - - Silver /L 20 - - - - - - - - - - - - - - Sul hate /L 25Q000 - - - - - - - - - - - - - - Trichloroethene /L 3 0.72 J Temp°C 21.6 16.8 23.3 17.4 23.9 18.1 19.1 16.0 22.2 17.0 23.8 14.8 15.0 18.0 Tetrachloroethene /L 0.7 .1 1.1 Turbidi NTU Vin 1 chloride /L 0.03 7 0.51 J NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1.Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 2L was obtained from NCDEQ Solid Waste Section (https://deq.ne.gov/about/divisions/waste-management/waste-management- niles/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 2 of 2 Geosyntec Consultants of NC, P.C. Table 34 Historical Groundwater Monitoring Data (DMW-05) Former York Road Landfill Charlotte, North Carolina Sample Date 3/18/2008 9/17/2008 4/8/2009 9/10/2009 3/10/2010 9/23/2010 3/29/2011 9/20/2011 3/20/2012 9/25/2012 3/5/2013 9/10/2013 3/26/2014 9/23/2014 3/11/2015 9/23/2015 Constituent Units NC 2L 1, 1 -dichloroethane L 6 - 0.86J - 2.2J - 28 1.6 7. - 2.OJ - 2.2J - 2.7J - 3.1 1, 1 -dichloroethene 7 - - - - - 0.53 - - 1,2-dichlorobenzene /L 20 - - - 0.63J 1.0 - 0.49J 0.44J 0.33J 0.30J 0.32J 1,2-dichloro ro ane /L 0.6 - - - - - - - 2.2 - - - - 1,4-dichlorobenzene /L 6 - 0.61J 0.901 1.4 2.4 0.66 0.51.1 4.3 1.3 0.93J 0.37J 0.95J 0.95J 1.2 1,4-dioxane L 3 - - - - - - - - - - - Acetone /L 6,000 17 68 70J 61 Arsenic /L 10 - 6.4J - - - - 3.2J - - - - - - - Barium L 700 62.0 140 93.0 180 140 110 120 105 152 145 107 175 63.8 155 116 145 Benzene L 1 - - - - - 0.64 - - - - - - - - - - Chloride µ L 250,000 100,000 - - - - - Chlorobenzene L 50 - - 1.7J 0.25J 2.3J 1.4J 0.97J 0.68J 0.98J 1.5 0.82J 2.3 Chloroethane L 3,000 - - 23.2 Chloromethane L 3 - 0.64J - Chromium (III+VI) µ 10 3.1J 1.0J OAJ 4.8 - - cis- l,2-dichloroethene 70 0.61J - 1.2J 3.8 1.1 32.6 0.27J 1.4J 0.94J 1.4J COD L - 43,000J - - - - - - - - - - Specific Conductance S/cm - - - - - - 1,084 1,060 777 978 1,200 1,300 845 1,027 - 1,550 Iron µ /L 300 2,300 12,000 7,900 - 9,200 9,600 16,000 270 7,760 12,100 14,300 8,930 7,310 12,400 8,340 10,800 8,350 243 Lead L 15 2.1J 2.3J - - - 0.38J - - - - - - - - - - Mananew /L 50 2,100 3,200 2,600 2,800 2,200 530 3,060 3,130 2,780 2,360 1,940 2,9401 1,570 2,520 1,920 7,300 H SU - - - - - - - 6.4 1 6.4 6.2 6.4 6.3 6.4 6.6 6.4 - 6.6 Selenium µg/L 20 - 8.01 1 2.6 - - - - Silver /L 20 - 0.3J - - Sulphate /L 250,000 - 130,000 - - - - Trichloroethene /L 3 - - 0.96 - 4.9 - - Temp °C - - - 16.6 19.4 19.3 20.0 15.4 19.8 15.9 21.9 15.4 Tetrachloroethene /L 0.7 0.8 - 1.8 - - - - - - - Toluene L 600 - - - trans-1,2-dichloroethene RWL 100 - - - 0.66J Turbidi NTU I - - - - - 54 48 15 24 8 8 1 12 6.0 Vin 1 chloride /L 0.03 - - - - - - - NC 21, - Title 15A of the North Carolina Administrative Code, Subchapter 21, Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 21, was obtained from NCDEQ Solid Waste Section (https://deq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 1 of 2 Geosyntec Consultants of NC, P.C. Table 34 Historical Groundwater Monitoring Data (DMW-05) Former York Road Landfill Charlotte, North Carolina Sample Date 3/22/2016 9/27/2016 3/27/2017 9/26/2017 3/30/2018 9/28/2018 4/5/2019 9/20/2019 3/31/2020 9/29/2020 3/25/2021 9/28/2021 3/30/2022 10/5/2022 3/28/2023 Constituent Units NC 2L 1, 1 -dichloroethane L 6 - - - - - - - - - - - - - 0.38 J - 1,1-dichloroethene 7 - - - - - - - - - - - - 1,2-dichlorobenzene /L 20 - - - - - - - - - - - 1,2-dichloro ro ane /L 0.6 - - - - - - - - - - - 1,4-dichlorobenzene L 6 1.3 - 1.5 - - - - - - - - - 1,4-dioxane L 3 - - - - - - - - - Acetone /L 6,000 - - - - - - - Arsenic /L 10 - - - - - - Barium /L 700 119 - 129 57 64.4 62.7 67.6 66.9 67.2 46.1 57.3 58.0 68.0 53.1 162 - 90.1 Benzene L 1 - - - - - - - - - - - - - 0.37 J - Chloride µ 250,000 - - - - - - - Chlorobenzene /L 50 1.3 - - Chloroethane /L 3,000 - - Chloromethane /L 3 - - Chromium (III+VI) µ /L 10 - - - cis-1,2-dichloroethene /L 70 - - - COD /L - - - Specific ConductancePS/cm - 1,008 1,280 1,249 1,061 1,421 1,167 856 398 940 904 696 866 943 857 1,897 Iron µ /L 300 13,000 - 14,200 14,900 - 23,600 - 12,400 - 18,400 - 24,600 - 13,200 12,800 19,400 10,000 Lead L 15 - - - - - - - - - Mananew L 50 2,230 - 2,390 5,810 - 6,440 - 2,600 - 4,290 - 4,050 - 4,140 2,530 5,830 3,570 H SU - 6.5 6.5 6.4 6.6 6.6 6.4 6.6 7.5 6.6 6.5 6.7 6.5 6.3 6.2 6.4 Selenium µg/L 20 - - - - - - - - - - - - - - - Silver µ /L 20 Sulphate L 250,000 - Trichloroethene /L 3 - - - - - - - - - - - - - - Temp °C - 17.1 23.2 18.6 24.0 19.4 25.1 16.6 19.1 17.0 21.9 17.9 21.8 16.9 20.2 19.5 Tetrachloroethene µ 0.7 - - - - - - - - - - - - - - - Toluene /L 600 - 1.2 trans-1,2-dichloroethene /L 100 - - Turbidity NTU - Vinyl chloride /L 0.03 - - - - NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 2L was obtained from NCDEQ Solid Waste Section (https://deq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 2 of 2 Geosyntec Consultants of NC, P.C. Table 3-K Historical Groundwater Monitoring Data (DMW-06) Former York Road Landfill Charlotte, North Carolina Sample Date 3/19/2008 9/17/2008 4/1/2009 9/10/2009 3/10/2010 3/29/2011 9/20/2011 3/20/2012 9/25/2012 3/4/2013 9/10/2013 1 3/26/2014 9/24,2014 3/5/2015 9/23/2015 Constituent Units NC 2L 1,1-dichloroethane /L 6 8.6 9.0 9.0 10 7.7 - 8.2 9.5 - 8.0 6.8 6.4 8.6 - 9.1 6.4 5.8 5.9 1,2-dichlorobenzene µ /L 20 0.52J 0.74J 0.981 0.58J 0.63 - 0.64J 0.73J 0.74J 0.72.1 0.801 0.85J 0.76 - 0.77J 0.79 - 0.82J 0.87J - - 1,2-dichloroethane /L 0.4 0.95J 0.97J 1.0 1.0 0.88 - 0.891 1.0 - 1.0 0.88J 0.86J 0.99 -1.OJ 0.82 - 0.86J 0.79J - - 1,2-dichloro ro ane /L 0.6 2.2 2.4 2.1 2.6 2.2 2.4 2.3 2.4 2.2 2.3 2.4 2.2-2.3 1.9 2.0 2.2 1,4-dichlorobenzene /L 6 4.9 5.5 6.5 5.6 5.2 5.7 5.4 5.8 5.6 5.8 5.1 5.7 5.7 5.7 6.1 1,4-dioxane /L 3 - - - - - - - - - - - - - - Acetone /L 6,000 56 5.6 - 8.6J 7.2J - Arsenic /L 10 2.5J - - - - - - - - Barium /L 700 430 460 480 490 470 - 510 565 556 511 516 550 575 - 617 540 - 550 549 575 608 Benzene µ /L 1 - 0.51 - 0.52J - 0.42J 0.38J 0.45J - 0.42J 0.43 - 0.47J 0.40 - 0.42J 0.44.1 - - Chloride /L 250,000 - - 200,000 - - - - - - - - - Chlorobenzene /L 50 2.6 3.1 2.8 2.7J 3.0 - 3.1 3.5 3.3 3.4 3.2 3.9 3.4 3.5 3.8 3.5 3.7 Chloromethane /L 3 - - - - - - 0.56J - - - - - - - - Chromium III+VI /L 10 - 3.9J 0.6J 9.11 6.5 - 7.2J 11.6 - - - - 6.4.1 - - cis- l,2-dichloroethene /L 70 38 41 43 50 38 - 40 45.9 41.1 39.6 37.3 32.5 45.9 - 46.6 34.9 - 35.2 32.8 32.6 41.1 COD /L - - - 100,000 - - - - - - - - - - - Diisopropyl ether /L 70 - - - - - - - - - - Specific Conductance µS/cm - - - - - 1,182 1,182 849 1,170 1,250 1,188 1,350 1,408 - 1,301 Iron /L 300 64 1,600 100 2,700 2,500 - 2,600 2,000 568 378 221J 349 183 - 368J 338 - 354 246J 174 102 Lead /L 15 2.7J 1.91 - - 1 - 1.4J - - - - - - - - - - Man anew /L 50 81 80 98 100 - 110 113 ENEW&MEM 14 128 126 -135 133 - 135 136 144 157 Mercury µ /L 1 0.181 - - 0.25 - 0.27 0.93 0.14J 0.13J - 0.15J 0.11J - - - Meth 1 Tert Butyl Ether µ /L 20 - - - - - - - - H SU - - 6.2 6.2 6.1 6.1 6.1 6.1 6.3 6.3 6.1 Selenium /L 20 4.2J - - - - - - 11.6 - Silver µ /L 20 0.5J - 0.6J - - Sul hate µ /L 250,000 - - 7,800 - - - - - - - - - Trichloroethene /L 3 8.2 9.3 8.9 8.6 8.0 - 8.5 6.2 6.6 7.3 6.3 7.3 6.5 - 6.7 6.1-6.2 5.9 5.6 4.8 Tern °C - - - - - 15.4 17.5 18.0 17.4 15.9 19.6 15.4 16.3 - 16.9 Tetrachloroethene µ /L 0.7 3.3 4.0 3.5 3.0 2.8 - 2.9 2.7 2.6 2.6 2.1 2.6 1 1.9 1.9 - 2.0 2.3 1.8 1.6 Toluene /L 600 - - - - - - - - - - - - - - trans- l,2-dichloroethene /L 100 1.4J 1.51 1.5J 1.7J 1.3J 1.5 1.3J L 1J L.1J 1.5J 1.0 1.01 1.0 1.2 Trichlorolluoromethane /L 2,000 0.35J - - - - - - - - - Turbidi NTU - - - - - - 65 56 8 5 7 20 11 - 6.25 Vin 1 chloride /L 0.03 8.5 8.4 8.0 9.1 5.9-6.2 6.7 r 7.4 6.8 5.3 3.7 5.0 - 5.1 4.8 4.9 4.4 4.3 NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 21, are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 21, was obtained from NCDEQ Solid Waste Section (https://deq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 1 of 2 Geosyntec Consultants of NC, P.C. Table 3-K Historical Groundwater Monitoring Data (DMW-06) Former York Road Landfill Charlotte, North Carolina Sample Date 3/24/2016 1 /27/2016 3/27/2017 9/26/2017 3/30/2018 9/28/2018 4/5/2019 9/20/2019 3/31/2020 9/29/2020 3/25/2021 9/28/2021 3/30/2022 10/5/2022 3/28/2023 Constituent Units NC 2L 1,1-dichloroethane /L 6 5.1 5.5 - 4.8 4.7 4.7 4.2 4.5 4.2 4.8 4.3 4.2 3.3 3.9 4.0 3.6 4.1 1,2-dichlorobenzene µ /L 20 - - - - - 1.0 1.1 1.0 1.1 - - 1.0 1.1 1.3 1,2-dichloroethane /L 0.4 - - - - - - - - - - - - 0.55 J - 1,2-dichloro ro ane /L 0.6 2.2 2.0 - 1.8 2.2 1.8 2.8 1.9 2.2 2.2 2.3 2.3 1.6 2.2 2.1 2.1 15 1,4-dichlorobenzene /L 6 5.5 5.3 -5.0 6.0 5.3 - 5.2 5.6 6.4 5.6 5.7 5.4 6.0 6.0 6.5 7.6 1,4-dioxane /L 3 - - - - - - - - - - - - - 66.1 Acetone /L 6,000 15 J Arsenic /L 10 - - - - - - - - - - - - - Barium /L 700 634 592-567 593 638 628 619 614 636 623 644 634 681 612 616 686 Benzene /L 1 - - - - - - - - - - - - - 0.35 J 0.32 J Chloride /L 250,000 - - - - - - - - - - - - - - Chlorobenzene /L 50 3.7 3.7-3.5 3.8 4.0 3.9 4.3 4.3 5.1 4.4 4.4 4.3 5.0 5.0 5.3 6.1 Chloromethane /L 3 - - - - - - - - - - - - - - Chromium III+VI /L 10 - - - - - - - - - - - - - - cis- l,2-dichloroethene /L 70 28.3 31.7 - 28.8 26.6 28.9 24.9 28.1 25.0 34.0 26.2 25.6 19.5 24.1 27.0 25.3 25.3 COD /L - - - - - - - - - - Diisopropyl ether /L 70 - - - - - - - - - - - - - 0.43 J Specific Conductance S/cm - 1,323 1,300 1,328 715 1,409 1,363 1,336 1,413 1,412 1,447 1.464 1,446 1,262 1,226 2,177 Iron /L 300 98 135 - 184 - 169 - 133 - 71.4 - - 61.9 63.0 - - Lead it a/L 15 - 5.3 - - - - - - - Manganese /L 50 2 154-160 - 262 184 - 258 252 Mercury /L 1 - - 0.32 - - - - - Meth 1 Tert Butyl Ether /L 20 - - - - - - - - - - - - - 0.39 J H SU - 6.3 6.3 6.0 6.2 6.2 6.1 5.9 6.2 6.2 6.2 6.1 6.8 6.2 5.84 6.12 Selenium /L 20 - - - - - - - - - - - - - - - Silver /L 20 - - - - Sulphate /L 250,000 - - - - - - - - - - - - - - Trichloroethene /L 3 5.5 4.9 - 4.3 5.0 4.4 4.9 4.1 4.6 5.1 4.1 3.9 2.7 3.5 4.0 3.7 4.4 Tern °C - 16.5 21.8 16.9 20.9 17.0 21.7 16.0 17.3 16.3 19.9 17.5 19.4 15.4 17.8 18.8 Tetrachloroethene /L 0.7 1.7 1 1.3 1.3 1.2 - 1.2 1.1 - - - 0.92 J 0.61 J Toluene /L 600 - - - - - 1.6 trans-1,2-dichloroethene /L 100 0.61 J 0.64 J Trichlorofluoromethane /L 1 2,000 1 1 - - Turbidi NTU Vin 1 chloride I ug/L 1 0.03 3.7 3.9 - 3.2 2.7 3.3 3.3 3.0 3.4 J 2.6 1.9 2.3 3.5 3.2 3.3 NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 21, was obtained from NCDEQ Solid Waste Section (https://deq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 2 of 2 Geosyntec Consultants of NC, P.C. Table 3-L Historical Groundwater Monitoring Data (DMW-08) Former York Road Landfill Charlotte, North Carolina Sample Date 3/20/2008 9/16/2008 4/6/2009 9/9/2009 1 3/11/2010 9/23/2010 3/31/2011 9/20/2011 3/19/2012 9/24/2012 3/4/2013 9/9/2013 3/25/2014 9/22/2014 1 3/6/2015 1 9/21/2015 Constituent Units NC 2L 1,4-dioxane L 3 - - - - - - - - - - - - - - - - Acetone L 6,000 19 12 130 430 300 - - - - - Arsenic L 10 - - - - - - 5.0 - - 5AJ - - Barium L 700 8.81 110 120 130 11.01 330 403 128 195 85.1J 89.7J 33.3J 37.6 84.5J 69.2 - 70.8 55.2 Cadmium L 2 - - 2.9 4.8 0.72J - - - 1.2 Chloride L 250,000 - 6,600 - - - - Chloromethane L 3 - - - 0.22J Chromium (III+VI) L 10 0.2J 2.3J 2.2J 2.5J 8.6 COD L - 130,000 - - - - Specific Conductance S/cm - - - - - - 168 169 163 121 177 144 159 156 146 Iron µg/L 300 1 81 13,000 1,200 - 16,000 17,000 65J 24,000 50,200 15,400 23,700 9,710 10,600 3,790 10,100 7,990 - 8,260 5,890 Lead L 15 - 3.5J - 1.4J 4.8 - 5.1J - - - - - - - Mananew L 50 2J 190 200 200 2J 440 688 208 317 122 139 40J 52 138 110-111 85 Nitrate as NO3- L 10,000 - 560 - - - - - - - - - - - - H SU - - 6.5 6.6 5.8 6.5 6.6 6.4 6.5 6.2 6.5 Silver L 20 0.4J 0.7J - - - - - - - - - Sul hate 250,000 2,800J - - - - - - - - - Temp °C - - - 16.7 18.8 20.3 19.4 17.1 20.0 17.6 19.7 18.7 Tetrachloroethene µ L 0.7 0.77J 0.94J 0.89J 0.67J 0.61 J 0.68 0.72J 0.68J 0.48J 0.50J 0.68J 0.49J - - - Toluene L 600 - - - - - - - - - - - - - Turbidi NTU - - 675 999 624 363 127 1 245 403 157 X lene m & L - 2.0 - - - - - - - X lene o L - 1.0 - NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 21, are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 2L was obtained from NCDEQ Solid Waste Section (https://deq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 1 of 2 Geosyntec Consultants of NC, P.C. Table 3-L Historical Groundwater Monitoring Data (DMW-08) Former York Road Landfill Charlotte, North Carolina Sample Date 3/23/2016 9/28/2016 3/27/2017 9/26/2017 3/30/2018 9/27/2018 4/5/2019 9/20/2019 3/31/2020 9/29/2020 3/25/2021 9/28/2021 3/30/2022 10/5/2022 3/28/2023 Constituent Units NC 2L 1,4-dioxane L 3 - - - - - - - - - - - - - - 0.58 J Acetone L 6,000 - - 25.7 - 13.9 J Arsenic L 10 - - - - - - - - - - - - - - Banum L 700 176 11.2 10.3 10.3 9.5 10.7 12.7 12.5 - 7.9 23.2 46.7 25.0 15.5 Cadmium L 2 - 1.2 1.4 1.4 - 1.2 1.8 1.7 - - 2.8 H) - Chloride L 250,000 - - - - - - - - Chloromethane L 3 - Chromium (III+VI) L 10 - COD L - - - - - - - - - - - - - - - - Specific Conductance S/cm - 151 164 149 156 122 157 140 145 141 70.1 76.7 186 189 181 274 Iron µ L 300 19,800 296 - 400 - 245 - 367 - 242 - 4,530 2,570 3,060 597 Lead L 15 - - - - - - - - - - Man anew L 50 243 38 8.0 28.4 9.9 - 16.0 107 53.0 56.3 12.5 Nitrate as NO3- L 10,000 - - - - - - - - - - - - - - - H SU - 6.6 6.6 6.1 6.6 6.5 6.3 6.3 6.6 6.6 5.2 5.9 6.5 7.0 6.3 6.5 Silver 20 - - - - - - - - - - - - - - - Sul hate 250,000 - - - - - - - - - - - - - - - Temp °C - 18.0 21.6 18.0 20.8 18.3 22.0 17.0 18.7 17.9 21.3 18.2 20.3 16.1 17.4 19.6 Tetrachloroethene µ 0.7 - - - - - - - - - - - - - - - Toluene L 600 Turbidity NTU - - - - - - - X lene m & L - - - - - - - X lene o L - - - I- - NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 21, are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 2L was obtained from NCDEQ Solid Waste Section (https://deq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 2 of 2 Geosyntec Consultants of NC, P.C. Table 3-M Historical Groundwater Monitoring Data (DMW-A) Former York Road Landfill Charlotte, North Carolina Sample Date 3/25/2008 3/26/2008 9/18/2008 1 4/2/2009 9/9/2009 3/11/2010 3/30/2011 9/19/2011 3/19/2012 9/24/2012 3/4/2013 9/9/2013 3/25/2014 9/22/2014 3/6/2015 9/21/2015 Constituent Units NC 2L Acetone /L 6,000 - - - 10 - 20 - 6.8JL - - - - - - - - - - Barium /L 700 51 26 110 28 - 31 140 53J 63 261 200 136 103 - 184 117 85.5 67.8J 67.4 65.9 Benzene /L 1 - - - - - - - - - - - - - - Chloride /L 250,000 - - - 2,400 - - - - - - - - - - Chromium III+VI L 10 9.0 7.4 19 11 23 13 9.6 46.5 37.7 24 19.7 - 30.8 19.1 15.9 10.0 11.2 11.3 COD /L - - - - 18,000J - - - - - - - - - - - Specific Conductance S/cm - - - - - 70.0 78.0 75.0 52.0 78.0 64.0 79.0 74.0 - 70.0 Iron L 300 58 8,400 570 - 2,400 11,000 4,000 1,960 26,800 20,800 13,200 10,200-18,300 11,500 7,650 4,950 5,300 4,980 Lead /L 15 - - 3.8J 1.1 - 1.7J 3.5J 1.91 - 8.11 5.6J 6J - - - - - Man anew /L 50 24 110 16 130 43J 35 355 262 149 102-242 123 84 65 63 57 Mercury /L 1 - - - 0.01J - - - - - - - - - - Nitrate as NO3- L 10,000 1,900 H SU - - 7.5 6.6 6.5 6.3 6.4 6.3 6.4 5.7 6.3 Silver /L 20 0.3J 0.5J - - - - - - - - - Sul hate L 250,000 3,000 - - - - - Ternp °C - - 18.5 20.1 21.3 20 20 20.7 19.3 20.4 20.0 Toluene /L 600 - - - - Turbidi NTU - - - 209 736 706 193 365 430 157 - 108 NC 21, - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 2L was obtained from NCDEQ Solid Waste Section (https://deq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 1 of 2 Geosyntec Consultants of NC, P.C. Table 3-M Historical Groundwater Monitoring Data (DMW-A) Former York Road Landfill Charlotte, North Carolina Sample Date 3/24/2016 9/28/2016 3/27/2017 9/26/2017 3/30/2018 9/27/2018 4/5/2019 9/20/2019 3/31/2020 9/29/2020 3/25/2021 9/28/2021 3/30/2022 10/5/2022 1 3/28/2023 Constituent Units NC 2L Acetone /L 6,000 - - - - - - - - - - - - - - Barium /L 700 66.5 26.6 26.5 26.7 28.0 26.2 27.0 27.0 22.6 29.1 27.6 29.5 24.0 - 29.0 Benzene /L 1 - - - - - - - - - - - - - - Chloride L 250,000 - Chromium III+VI L 10 11.6 - COD /L - - - - - - - - - - - - - - - - Specific Conductance S/cm - 70.5 79.8 95.4 91.1 74.9 85.0 64.5 73.0 72.4 87.2 76.7 76.2 73.0 231 355 Iron L 300 5,030 1,160 - 1,540 - 614 - 1,160 - 3,860 - 2,040 246 778 - Lead L 15 - - - - - - - - - - Manizanese L 50 58 104 248 135 221 316 41 73.8 8.4 Mercury /L 1 - - - - - - - - - Nitrate as NO3- L 10,000 - - - - - - - - - - - H SU - 6.4 6.3 6.6 6.5 6.2 5.8 6.1 6.3 6.3 5.7 5.9 6.1 6.3 6.2 6.3 Silver L 20 - - - - - - - - - - - - - - - Sul hate L 250,000 - - - - - - - - - Temp °C - 19.2 21.1 20.7 24.5 19.3 22.7 18.1 18.7 18.7 23.2 18.2 20.0 20.4 17.0 18.1 Toluene I tig/L 600 - - 0.75 J Turbidity NTU - - NC 21, - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 2L was obtained from NCDEQ Solid Waste Section (https://deq.nc.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 2 of 2 Geosyntec Consultants of NC, P.C. Table 3-N Historical Groundwater Monitoring Data (YRW-10C) Former York Road Landfill Charlotte, North Carolina Sample Date 3/18/2008 1 9/18/2008 1 4/7/2009 1 9/9/2009 1 3/10/2010 1 9/23/2010 1 3/29/2011 1 9/21/2011 1 3/20/2012 1 9/25/2012 1 3/5/2013 1 9/10/2013 1 3/26/2014 1 9/23/2014 1 3/6/2015 1 922/2015 Constituent Units NC 21, 1,1-dichloroethane /L 6 0.5J 0.68J 0.56J 0.47J 0.42J 1,4-dioxane /L 3 Acetone /L 6,000 1,700 600 17J 1,000 50 - 57 Arsenic ggIL 10 8.11 4.8J 9.7J 2.8 - 6.0 - 6.6J 8.9J Barium L 700 440 420 410 470 430 400-450 446 466 388 425 378 500 414 473-478 408 512 Cadmium /L 2 0.2J 1.3 - 2.4 .5 - - Carbon disulfide I 700 - - - - - - - - - - - - 1.91 - - - Chloride /I, 250,000 46,000 Chlorobenzene /L 50 0.55J 0.61J 0.65J - - 0.76J 0.89J 0.27J 0.87J - Chromium III+VI /L 10 6.2 - 7.2 12.9 9.4 - 9.6J COD /L 84,000 Specific Conductance gs1cm - - - - - - 1,135 1,108 547 963 821 915 832 1,107 - 1,216 Iron /I. 300 120,000 130,000 120,000 120,000 150,000 100,000 - 120,000 95,800 88,800 93,300 88,000 85,700 126,000 95,400 93,700 - 94,000 108,000 112,000 Lead 15 - - - - - 0.28 - 1.1 J - - 6.3J - - - - 7.4 - 8J - - Man anew /L 1 50 2,600 1,900 1 2,200 2,800 1,300 1 2,400 3,620 3,110 1,500 2,840 1 1,920 2,620 2,080 3,210 - 3,230 2,970 3,310 Mercury /L 1 - - - - - - - - - - - 0.11 J - - Nitrate as NO3-) /I, 10,000 - - 400 - - - - - H SU - - 6.4 6.3 6.2 6.2 6.2 6.3 6.4 6.2 6.3 Selenium /I, 20 21 16J 31 3.0 - 3.3 5.OJ 11.5 14.6 10.9 Silver /L 20 I.IJ 4.1J 6AJ - - Sul hate /L 250,000 6.000J - - - Temp C 15.6 19.2 18.4 1 19.3 16.3 18.9 16.7 18.1 18.8 Tert-Bu lbenzene I gg/L 70 - - Toluene jj 2/1, 600 - - Turbidi NTU - 126.0 75.0 141.0 22.0 15.0 44.0 96.0 56.2 X lene m & /L 2.0 - - X lene o /L I 1 1.0 NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1.Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2L are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. 4. NC 2L was obtained from NCDEQ Solid Waste Section (https:Hdeq.ne.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 1 of 2 Geosyntec Consultants of NC, P.C. Table 3-N Historical Groundwater Monitoring Data (YRW-10C) Former York Road Landfill Charlotte, North Carolina Sample Date 3/24/2016 1 9/27/2016 1 3/27/2017 1 9/26/2017 1 3/30/2018 1 9/28/2018 1 4/5/2019 1 9/20/2019 1 3/31/2020 1 9/29/2020 1 3/25/2021 1 9/28/2021 1 3/30/2022 1 10/5/2022 3/28/2023 Constituent Units NC 2L 1,1-dichloroethane /L 6 - - - - - - - - - - - - - - - 1,4-dioxane /L 3 0.92 J Acetone /L 6,000 - - - - - - - - - - - - - - Arsenic ggil, 10 - - - - - 26.3 Barium /L 700 415 473 378 522 389 551 428 481 1,290 482 400 518 460 504 434 Cadmium /L 2 - - - - - - 1.8 - - - 1.1 - Carbon disulfide /L 700 - - 1.2 Chloride /L 250,000 - - - - Chlorobenzene /L 50 1.1 - - - - 3.2 - - - 3.3 - 0.7 J 1.6 Chromium III+VI /L 10 - - - - COD /L - - - - - Specific Conductance gs1cm 884 1,221 743 645 726 1,300 738 1,149 669 1,213 708 1,042 647 1,078 1,372 Iron /L 300 119,000 116,000 - 115,000 - 108,000 - 102,000 - 116,000 - 113,000 105,000 110,000 117,000 Lead 15 - - - - - - - - Man anew /L 50 2,040 3,150 - 68.0 - 3,380 - 2,840 - 2,930 - 2,580 1,600 3,070 1,230 Mercury /L 1 - - - - - - - - - - - - - - - Nitrate (as NO3-) /L 10,000 - - - H SU 6.4 6.3 6.4 6.4 6.4 6.4 6.3 6.4 6.4 6.3 6.4 6.5 62 6.0 6.4 Selenium /L 20 - - - - - - - Silver /L 20 Sulphate /L 250,000 - - - - - - - - - - Tem °C 17.3 24.3 19.2 22.7 18.6 24.2 17.1 19.9 16.9 20.9 19.2 22.7 17.1 19.6 1 20.2 Tert-Bu lbenzene /L 70 - - - 0.54 J Toluene /L 600 0.8 J Turbidity NTU - X lene m & /L X lene o /L NC 21, - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 21, are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detecte 4. NC 2L was obtained from NCDEQ Solid Waste Section (https:Hdeq.ne.gov/about/divisions/waste-management/waste-management- rules/solid-waste-rules) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 2 of 2 Geosyntec Consultants of NC, P.C. Table 3-O Historical Surface Water Monitoring Data (NT-1) Former York Road Landfill Charlotte, North Carolina Sample Date 3/17/2008 9/15/2008 3/31/2009 9/9/2009 3/9/2010 9/23/2010 3/29/2011 9/22/2011 3/21/2012 9/26/2012 3/6/2013 9/11/2013 3/27/2014 9/24/2014 3/11/2015 9/24/2015 Constituent Units NC 2B 1, 1 -dichloroethane /L 6a - - - - - - - - 0.88J - - - - - - - 1,4-dioxane µ /L 0.35` Acetone µ /L 31002 - - - - 1.6J - - 6.2J - - - - - - - - Arsenic /L 102 - - - - - 0.55J - - - - - - - - - - Barium µ /I, 1,000, 50 42 70 110 52J 360 30.9 59.7J 57.6J 52.7J 36J 61.1J 91.6 47.2J 52.2 88.2 Chromium III+VI µ /L 11b 0.2J 0.2J 1.6J - 1.01 3.4 - - - - - - - - - - cis- l,2-dichloroethene µ /L 602 - - - - - - - 0.59J - - - - - - - Specific Conductance S/cm - - - - - 140 180 151 185 182 158 187 204 - 215 Iron µ /L - - - - - - - - - - - - - - - 3,690 - Lead µ /L 14b - - 1.2J - 1.0J - - - - - - - - - Manganese µ /L - - - - - - - - - - - - - - - 557 - Mercury /L 0.012b - - - - - 0.1J - - - - - - - - - - H SU - - - - - - - 6.9 6.5 6.4 6.6 6.9 6.6 6.8 7.4 - 6.4 Selenium µ /L 5b - - - - 4.8J - - - - - - - - - - - Silver /L 30b - - - 0.5J - - - - - - - - - - - - Temp loc - - - - - - - 15.4 21.7 1 22.5 1 23.6 11.4 23.3 15.4 16.9 - 18.6 Toluene /L 11b - - - - - 1.5 - - I - I - - - - I - - - Turbidi NTU I - - - - -I - 149 1 13.0 1 112 10.0 48.0 52.0 1 1.0 1 - 46.4 NC 2B - Title 15A of the North Carolina Administrative Code, Subchapter 2B Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units a - Water supply standard b - Freshwater aquatic life standard for chronic exposure c - Water supply in stream target value Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2B are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. Refer to analytical reports for information on which analyses were performed. 4. NC 2B standards were obtained from NCDEQ Water Resources Planning Section (https://deq.nc.gov/nc-stdstable-09222017) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 1 of 2 Geosyntec Consultants of NC, P.C. Table 3-O Historical Surface Water Monitoring Data (NT-1) Former York Road Landfill Charlotte, North Carolina Sample Date 3/21/2016 9/27/2016 3/28/2017 9/52017 3/9/2018 9/25/2018 4/5/2019 9/20/2019 3/31/2020 9/29/2020 3/25/2021 9/28/2021 3/30/2022 10/5/2022 3/28/2023 Constituent Units NC 2B 1, 1 -dichloroethane /L 6a - - - - - - - - - - - - - - - 1,4-dioxane µ /L 0.35` 0.71 J Acetone µ /L 3,1002 - - - - - - - - - - - - 10.5 J Arsenic /L 102 - - - - - - - - - - - - - - - Barium µ /L 1000a 58.8 59.1 47.4 55.0 68.8 77.9 28.8 35.2 47.1 43.5 50.5 39.0 43.2 - 189 Chromium III+VI µ /L 11b - 7.2 - - - - - - - - - - - - 3.0 cis-1,2-dichloroethene µ /L 602 - - - - - - - - - - - - - - - Specific Conductance S/cm - 220 91.8 154 195 204 244 57.2 189 173 178 193 138 212 113 225 Iron µ /L - - - - - - - - - - - - - - - - Lead µ /LManganese µ /L - - - - - - - - - - - - Mercury /L 0.012b - - - - - - - - - - - - - - H SU - 6.9 6.7 6.8 6.8 7.2 6.5 6.6 7.1 7.0 6.5 6.9 6.9 7.0 6.9 7.1 Selenium µ /L 5b - - - - - - - - - - - - - - - Silver /L 30b - - - - - - - - - - - - - - - Temp °C - 9.0 23.7 22.0 24.3 12.2 24.1 14.5 19.7 15.4 22.2 14.1 20.6 14.9 15.3 18.4 Toluene /l- 11b - - 2.3 Turbidity NTU - - - NC 2B - Title 15A of the North Carolina Administrative Code, Subchapter 2B Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units a - Water supply standard b - Freshwater aquatic life standard for chronic exposure c - Water supply in stream target value Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2B are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. Refer to analytical reports for information on which analyses were performed. 4. NC 2B standards were obtained from NCDEQ Water Resources Planning Section (https://deq.nc.gov/nc-stdstable-09222017) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 2 of 2 Geosyntec Consultants of NC, P.C. Table 3-P Historical Surface Water Monitoring Data (NT-2) Former York Road Landfill Charlotte, North Carolina Sample Date 3/17/2008 9/15/2008 9/18/2008 3/31/2009 9/9/2009 3/9/2010 9/23/2010 3/29/2011 9/22/2011 3/21/2012 3/6/2013 3/27/2014 9/24/2014 3/11/2015 Constituent Units NC 2B 1,1-dichloroethane 6a - 0.70J - - 1.5J 0.981 9.7 - - - - - - - 1,1-dichloroethene 300a - - - - - - 0.59 - - - - - - - 4-Meth 1-2- entanone 2 800a - - - - - - - - - - - - - 6.9 Acetone 3100a - - - - - 1.7J - - 6.7J 12.6J - - - - Arsenic 10a - - - - - - 4.6 - - - - - - - Barium 1000a 52 - 35 60 51J 49J 140 58.6 17J 125.0 54.2J 47.1 25.1J 75.5 Benzene 1.19a - - - - - - 0.83 - - - - - - - Cadmium 0.82b - - - - - - 0.17J - - - - Chloromethane /L 2.6a - - - - - - - - 0.21J - - - Chromium III+VI 11b - - 0.5J 2.3J 2.6J - 5.5 - - - - - 12.6 cis-1,2-dichloroethene 60a - 0.56J - - 1.8J 0.94J 9.4 - - - - - - - Specific Conductance S/cm - - - - - - - - 196 140 142 307 269 191 - Iron - - - - - - - - - - - - - 8,910 Lead 14b - - - - - - 3.3 - - - - 8.9 Manganese - - - - - - - - - - - - - - 134 H SU - - - - - - - - 6.7 7.1 6.5 6.8 7.1 7.9 - Selenium 5b - - - - - 0.72J - - - - - - - Silver /L 30b - - - - 0.2J - - - - - - Trichloroethene 2.5a - 0.69J - - 0.891 0.76J 7.6 - - - - - - - Temp °C - - - - - - - 12.0 22.9 22.9 10.2 13.6 17.5 - Tetrachloroethene 0.7a 0.59J 0.77J - - - 0.881 4.1 - - - - - - - Turbidity NTU - - - - - - - 62 83 5 21 20 Vinyl chloride /L 0.025a - - - - 0.7J 2.5 - - - - - NC 2B - Title 15A of the North Carolina Administrative Code, Subchapter 2B Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units a - Water supply standard b - Freshwater aquatic life standard for chronic exposure Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2B are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. Refer to analytical reports for information on which analyses were performed. 4. NC 2B standards were obtained from NCDEQ Water Resources Planning Section(https://deq.nc.gov/nc-stdstable-09222017) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 1 of 2 Geosyntec Consultants of NC, P.C. Table 3-P Historical Surface Water Monitoring Data (NT-2) Former York Road Landfill Charlotte, North Carolina Sample Date 9/24/2015 3/21/2016 9/27/2016 3/28/2017 9/5/2017 3/9/2018 9/25/2018 4/5/2019 9/20/2019 3/31/2020 9/29/2020 1 3/25/2021 1 3/30/2022 10/5/2022 3/28/2023 Constituent Units NC 2B 1,1-dichloroethane 6a - - - - CIO Z q +C� a - zSpecific Q a - 44 q +C� a - - - - - - 1,1-dichloroethene 300a - - - - - - - - - - - - 4-Meth 1-2- entanone 2 800a - - - - - - - - - - - Acetone 3100a - - - - - - - - - - - Arsenic 10a - - - - - - - - - - - - Barium 1000a 48.0 45.0 66.7 38.6 61.3 41.7 47.4 34.3 95.6 42.7 - 31.0 Benzene 1.19a - - - - - - - - - - - - Cadmium 0.82b - - - - - - - - - - Chloromethane 2 6a - - - - - - - - - - Chromium III+VI 11b - - 7.4 - - - cis-1,2-dichloroethene 60a - - - Conductance S/cm - 265 307 155 212 228 187 279 131 225 155 85.6 200 Iron - - - - - - - - - - - - Lead 14bManganese - - - - - - - - - - - - - H SU - 6.9 7.0 7.0 6.8 7.0 7.0 6.8 5.8 6.7 6.8 6.5 7.0 Selenium /L Sb - - - - - - - - Silver /L 30b - - - - - - - Trichloroethene /L 2 5a - - Temp °C - 17.5 11.7 22.6 21.8 4.6 14.2 14.9 20.8 14.3 1 14.0 1 15.8 1 17.9 Tetrachloroethene /L 0.7' - - - - - - - - - - - - Turbidi NTU - 31.4 - - - - - - Vinyl chloride /L 0.0253 - - - - - - - NC 2B - Title 15A of the North Carolina Administrative Code, Subchapter 2B Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units a - Water supply standard b - Freshwater aquatic life standard for chronic exposure Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2B are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. Refer to analytical reports for information on which analyses were performed. 4. NC 2B standards were obtained from NCDEQ Water Resources Planning Section (https://deq.nc.gov/nc-stdstable-09222017) on 8 May 2023. 5. Analytical results with 7 qualifier indicate estimated values. CAR230086 Page 2 of 2 Geosyntec Consultants of NC, P.C. Table 3-Q Historical Surface Water Monitoring Data (SC-1) Former York Road Landfill Charlotte, North Carolina Sample Date 3/17/2008 9/18/2008 3/31/2009 9/9/2009 3/9/2010 9/23/2010 3/29/2011 9/22/2011 3/22/2012 9/26/2012 3/6/2013 9/11/2013 3/27/2014 9/24/2014 3/11/2015 9/23/2015 Constituent Units NC 2B 1,4-dioxane /L 0.35` Acetone /L 3 100' 2.1J 2.8J 5.9J 10.6J Arsenic /L 10' 2.8J 2.5J - - Barium /L 1000' 29.0 30.0 35.0 22J 24J 24.0 22.4 25.8J 33.6J 21.6J 28.9J 19.5J 30.6 25.1J 26.4 15.7 Bromodichloromethane /L 0.55' 0.63J - Chlorodibromomethane /L 0.8' L1.1 Chloroform /L 60' 0.811 Chloromethane /L 2.6' 0.24J Chromium III+VI /L 11, 0.6J 0.91 5.8 0.91 0.6J 5.9 Specific Conductance Its/cm 287 242 261 311 310 319 379 418 438 Iron /L - - 388 - Lead /L 14' 1.91 0.36J Manganese /L - - - - - - - - - - - - - 36.5 - Mercury /L 0.012' 0.14J H SU 6.9 7.2 7.6 7.4 1 7 1 7.5 1 7.1 7.8 1 7.4 Selenium L 5e 0.6J Temp°C 14.7 22.6 1 20.7 24.8 1 10.6 1 26.9 1 15.0 19.7 1 24.5 Turbidity NTU 70.0 1 9.0 2.0 1 26.0 1 10.0 1 7.0 1 9.0 1 2.2 NC 2B - Title 15A of the North Carolina Administrative Code, Subchapter 2B Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units a - Water supply standard b - Freshwater aquatic life standard for chronic exposure c - Water supply in stream target value Notes: 1.Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2B are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. Refer to analytical reports for information on which analyses were performed. 4. NC 2B standards were obtained from NCDEQ Water Resources Planning Section(https://deq.nc.gov/nc-stdstable-09222017) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 1 of 2 Geosyntec Consultants of NC, P.C. Table 3-Q Historical Surface Water Monitoring Data (SC-1) Former York Road Landfill Charlotte, North Carolina Sample3/21/2016 9/27/2016 3/28/2017 9/5/2017 3/9/2018 9/25/2018 4/5/2019 9/20/2019 3/31/2020 9/29/2020 3/25/2021 9/28/2021 3/30/2022 10/5/2022 3/28/2023 Constituent Units 1,4-dioxane /L Acetone /L Arsenic /L - - - - - - - - Barium /L 32.2 44.5 29.6 24.7 28.3 28.6 81.0 25.6 30.0 27.6 30.7 22.9 23.3 24.6 Bromodichloromethane /L - - Chlorodibromomethane /L Chloroform /L Chloromethane /L 2.6' - Chromium III+VI /L 116 - 15.4 Specific Conductance S/cm 286 1,750 200 315 352 191 74 370 332 340 222 349 224 316 752 Iron /L - - - - - - - - Lead /L 14' 10.6 Manganese /L - - - - - - - - - - - Mercury /L 0.012" - - - - - - - - - - - - - - - H ISU 7.5 1 6.8 1 7.2 1 7.5 1 7.5 1 7.7 7.0 1 7.6 1 7.6 7.2 7.4 7.7 7.5 1 7.3 1 7.9 Selenium I ltg/L 5n Tem °C 15 23.8 20.9 27.1 13.6 26.5 14.6 22.0 16.7 24.3 15.6 24.1 16.2 121 18.9 Turbidi NTU NC 2B - Title 15A of the North Carolina Administrative Code, Subchapter 2B Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units a - Water supply standard b - Freshwater aquatic life standard for chronic exposure c - Water supply in stream target value Notes: 1.Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2B are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. Refer to analytical reports for information on which analyses were performed. 4. NC 2B standards were obtained from NCDEQ Water Resources Planning Section (https:Hdeq.nc.gov/nc-stdstable-09222017) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 2 of 2 Geosyntec Consultants of NC, P.C. Table 3-R Historical Surface Water Monitoring Data (SC-2) Former York Road Landfill Charlotte, North Carolina Sample Date 3/17/2008 9/15/2008 3/31/2009 9/9/2009 3/9/2010 9/23/2010 3/31/2011 9/22/2011 3/22/2012 9/26/2012 3/7/2013 9/12/2013 3/27/2014 9/24/2014 3/12/2015 Constituent Units NC 213 1,4-dioxane L 0.35` - - - - - - - - - - - - - - - Acetone L 3100a - 2.6J 2.6J 7.OJ - - Arsenic L 10a - - 1.7J - - 0.56J - - - - - - Barium L 1 1000a 30 55 36 26J 28J 21 34.5 26.2J 44.1J 25.2J 38AJ 21.8J 32.0 32.9J 66.4 Bromodichloromethane L 0.552 - - - - 0.54J - - - - - - - Chlorodibromomethane L 0.4a - - - - - Chloroform L 60a - - 1.1J - - - 0.22J - - - Chromium III+VI L 11b 0.6J 0.3J 1.2J 1.6J 1.11 6.7 3.lJ - - - - - - 6.OJ 6.4 Specific Conductance S/cm - - - 251 252 261 355 361 300 392 410 - Lead L 14b 1.0J 1.1 i 0.39J - - - - - - - - 5.4 MercuryL 0.012b O.011 - - - - - - - - - - - H SU - - 6.7 7.2 7.5 7.6 7.4 7.4 7.4 7.8 Trichloroethene L 2.52 - - 0.81J - - - - - - - Temp °C - - 12.1 24.6 22.0 22.9 10.2 25.1 15.0 19.5 - ,Turbidity NTU - - - - - - - 75.4 9.0 49.0 31.0 2.0 6.0 23.0 NC 2B - Title 15A of the North Carolina Administrative Code, Subchapter 2B Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units a - Water supply standard b - Freshwater aquatic life standard for chronic exposure c - Water supply in stream target value Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2B are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. Refer to analytical reports for information on which analyses were performed. 4. NC 2B standards were obtained from NCDEQ Water Resources Planning Section(https://deq.nc.gov/nc-stdstable-09222017) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 1 of 2 Geosyntec Consultants of NC, P.C. Table 3-R Historical Surface Water Monitoring Data (SC-2) Former York Road Landfill Charlotte, North Carolina Sample Date 9/21/2015 3/24/2016 9/28/2016 3/28/2017 9/5/2017 3/9/2018 9/25/2018 4/5/2019 9/20/2019 3/31/2020 9/29/2020 3/25/2021 9/28/2021 3/30/2022 10/5/2022 3/28/2023 Constituent Units NC 213 1,4-dioxane µ /L 0.35` - - - - - - - - - - - - - - - 0.84 J Acetone µ L 31008 - - - - - - - - Arsenic L 10, - - - - - - - - - - - - - - - Barium µ /L 1 1000a 27.8 40.8 41.0 31.3 47.4 29.8 31.5 61.7 30.3 33 30.9 35.0 23.6 26.0 26.0 Bromodichloromethane µ /L 0.552 - - - - - - - - - - - - - - Chlorodibromomethane µ L 0.4' - - - - Chloroform L 602 - _ - - Chromium III+VI µ L 11b 5.0 - - - 5.9 - - 12.8 - - - - - - - - Specific Conductance µS/cm - 354 384 246 200 325 354 357 87.9 345 337 338 317 349 341 285 740 Lead uglL 14b - - - - 5.5 - - 7.3 - - - - - - - - Merc L 0.012b - - - - - - - - - - - - - - - - H SU - 7.1 8.5 7.2 7.2 7.3 7.8 7.4 7.5 7.8 8.0 7.1 7.9 7.8 8.1 7.4 7.5 Trichloroethene L 2.52 - - - - - - - - - - - Temp °C - 23.0 20.1 27.5 21.9 28.9 13.4 25.9 16.6 24.9 16.5 25.5 17.4 26.3 15.0 17.1 18.8 ,Turbidity NTU 60.0 - - - - - - - - - - - - - NC 2B - Title 15A of the North Carolina Administrative Code, Subchapter 2B Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units a - Water supply standard b - Freshwater aquatic life standard for chronic exposure c - Water supply in stream target value Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2B are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. Refer to analytical reports for information on which analyses were performed. 4. NC 2B standards were obtained from NCDEQ Water Resources Planning Section(https://deq.nc.gov/nc-stdstable-09222017) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 2 of 2 Geosyntec Consultants of NC, P.C. Table 3-S Historical Surface Water Monitoring Data (NT-2) Former York Road Landfill Charlotte, North Carolina Sample Date 3/17/2008 9/15/2008 3/31/2009 9/9/2009 3/9/2010 9/23/2010 3/29/2011 9/22/2011 3/22/2012 9/26/2012 3/7/2013 3/27/2014 9/23/2014 3/11/2015 9/23/2015 Constituent Units NC 2B 1,4-dioxane 0.35` - - - - - - - - - - - - - - - Acetone /L 3100a - - - - 16.OJ - 2.3J 7.7J - - - - - - - Arsenic /L 10a - 4.OJ - - 0.0 - - - - - - - - - Barium /L 1000a 55.0 35.0 66.0 50.OJ 77.OJ 48.0 48.4 94.4J 70.9J 71.OJ 50.7J 70.8 64.8J 68.4 45.6 Chlorobenzene /L 140b - - - 0.66J - - - - - 0.34J 0.28J - - - Chloromethane /L 2.6a - - - - - 0.65J - 0.191 - - - - - Chromium III+VI /L 11b 0AJ 0.5J 0.91 0.81 5.8 - - - - - - - - - Specific Conductance S/cm - - - - - 293 722 365 547 308 397 385 - 287 Iron /L - - - - - - - - - - - - 2,730 - Lead 14b - - - 0.5J - - - - - - - - Manganese - - - - - - - - - - - 481 - H SU - - - - - 7.3 7.1 7.5 7.2 7.7 6.8 7.6 - 6.9 Selenium /L 5b - - - 0.72J - - - - - - - - - ITemp °C - - - - 11.3 21.2 19.6 18.6 9.5 12.7 17.4 - 19.9 ITurbidity INTU I- I - - 55.0 69.0 15.0 24.0 35.0 34.0 - 20.3 NC 2B - Title 15A of the North Carolina Administrative Code, Subchapter 2B Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units a - Water supply standard b - Freshwater aquatic life standard for chronic exposure c - Water supply in stream target value Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2B are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. Refer to analytical reports for information on which analyses were performed. 4. NC 2B standards were obtained from NCDEQ Water Resources Planning Section (https://deq.nc.gov/nc-stdstable-09222017) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 1 of 2 Geosyntec Consultants of NC, P.C. Table 3-S Historical Surface Water Monitoring Data (NT-2) Former York Road Landfill Charlotte, North Carolina Sample Date 3/21/2016 9/28/2016 3/28/2017 9/5/2017 3/9/2018 9/25/2018 4/5/2019 9/20/2019 3/31/2020 9/29/2020 3/25/2021 9/28/2021 3/30/2022 10/5/2022 3/28/2023 Constituent Units NC 2B 1,4-dioxane /L 0.35` - - - - - - - - - - - - - - Acetone 3100a - - - - - - - - - - - - - - - Arsenic 10a - - - - - - - - - - - - - - - Banum 1000a 68.3 62.1 55.1 48.4 56.0 84.0 37.7 78.5 74.3 74.9 71.6 98.2 75.4 - 64.0 Chlorobenzene 140b - - - - - - - - - - - - - - - Chloromethane 2 6a - - - - - - - - - - - - Chromium III+VI 11b - - - - - - - - - - - 8.8 - - - Specific Conductance S/cm - 431 248 273 259 326 348 84 584 399 401 398 309 407 237 620 Iron - - - - - - - - - - - - - - - Lead /L 146 - - - - - - - - - - - Manganese - - - - - - - - - - - - - - - - H SU - 7.5 7.0 7.3 6.9 7.4 7.3 6.7 7.4 7.1 7.0 7.4 7.4 7.3 6.9 7.5 Selenium /L 5b - - - - - - - - - - - - - - - ITemp °C - 10.8 24.6 19.6 22.0 6.7 24.1 14.2 17.9 15.9 21.1 15.2 17.4 11.0 13.0 18.3 ITurbidity NTU I- - - - - - - - - - - NC 2B - Title 15A of the North Carolina Administrative Code, Subchapter 2B Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units a - Water supply standard b - Freshwater aquatic life standard for chronic exposure c - Water supply in stream target value Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2B are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. Refer to analytical reports for information on which analyses were performed. 4. NC 2B standards were obtained from NCDEQ Water Resources Planning Section(https://deq.nc.gov/nc-stdstable-09222017) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 2 of 2 Geosyntec Consultants of NC, P.C. Table 3-T Historical Surface Water Monitoring Data (ST-3) Former York Road Landfill Charlotte, North Carolina Sample Date 3/28/2017 1 9/5/2017 1 3/9/2018 1 9/25/2018 1 4/5/2019 1 9/20/2019 1 3/31/2020 1 9/29/2020 1 3/25/2021 1 9/28/2021 1 3/30/2022 1 10/5/2022 3/28/2023 Constituent Units NC 2B Barium L 1,000, 24.8 32.1 37.0 39.1 30.1 37.6 41.2 38.9 41.4 53.7 37.1 - 42.2 Chromium III+VI L 11" - - - - - - - - - - - 3.7 Specific ConductancePS/cm 102 177 209 234 44.2 202 240 212 246 162 224 108 233 H SU - 6.7 6.4 6.7 7.1 6.7 7.3 7.2 6.8 7.3 7.5 8.8 7.3 7.4 Temp °C 18.6 24.2 5.1 24.3 14.0 17.4 15.4 22.0 14.0 17.2 14.1 12.4 16 NC 2B - Title 15A of the North Carolina Administrative Code, Subchapter 2B Standards µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units °C - Degrees Celsius NTU - Nephelometric Turbidity Units a - Water supply standard b - Freshwater aquatic life standard for chronic exposure Notes: 1. Only constituents detected in one or more samples since March 2008 are shown. 2. Values exceeding NC 2B are displayed in bold and shaded gray. 3. Blank table entries indicate that the constituent was either not sampled or not detected. Refer to analytical reports for information on which analyses were performed. 4. NC 2B standards were obtained from NCDEQ Water Resources Planning Section(https://deq.nc.gov/nc-stdstable-09222017) on 8 May 2023. 5. Analytical results with J qualifier indicate estimated values. CAR230086 Page 1 of 1 Geosyntec Consultants of NC, P.C. Table 4 Existing Groundwater and Surface Water Sampling Schedule Former York Road Landfill Charlotte, North Carolina Sample Sample Type VOCs (EPA 8260) RCRA Metals (EPA 6020 & 7470) Total Iron & Manganese (EPA 6020) 1 4-Dioxane (EPA 8260SIM) Field Parameters Water Level Field Blank Blank S S A O Trip Blank Blank S O DDW-01 Ground Water S S A O S S DDW-01A Ground Water S S O S S DDW-02 Ground Water S S O S S DDW-03 Ground Water S S O S S DDW-03A Ground Water S S O S S DDW-05 Ground Water S DDW-06 Ground Water S DMW-01 Ground Water S S A O S S DMW-02 Ground Water S S A O S S DMW-02A Ground Water S S O S S DMW-02B Ground Water S S O S S DMW-05 Ground Water S S A O S S DMW-06 Ground Water S S A O S S DMW-08 Ground Water S S A O S S DMW-09 Ground Water S DMW-A Ground Water S S A O S S DMW-B Ground Water S Duplicate Ground Water S S A O S YRW-06A Ground Water S YRW-07 Ground Water S YRW-10C Ground Water S S A O S S YRW-11B Ground Water S NT-1 Surface Water S S O S NT-2 Surface Water S S O S SC-1 Surface Water S S O S SC-2 Surface Water S S O S ST-1 Surface Water S S O S ST-3 Surface Water S S O S WSW-2 Water Supply Well A* A* WSW-3 Water Supply Well A* A* Notes: 1. EPA - Environmental Protection Agency 2. RCRA - Resource Conservation and Recovery Act 3. VOCs - volatile organic compounds 4. S - Semi-annual frequency, A - Annual frequency, or O - schedule to be determined 5. Field parameters include conductivity, pH, and temperature. 6. RCRA metals include arsenic, barium, cadmium, chromium, lead, mercury, selenium, and silver. 7. One trip blank should be included with every sample shipment. 8. * indicates that water supply well was permanently abandoned by others on 21 September 2022. CAR230086 Page 1 of 1 Geosyntec Consultants of NC, P.C. Table 5 Historical Vertical Hydraulic Gradients Former York Road Landfill Charlotte, North Carolina Well Pair tTotal Depth Difference oft) Mar-06 Sep-06 Feb-07 Sep-07 Mar-08 Sep-08 Mar-09 Sep-09 Mar-10 Sep-10 Mar-11 Sep-11 Mar-12 Sep-12 Mar-13 Sep-13 Mar-14 Sep-14 DDW-OIAIDDW-01 40 0.010 0.009 0.009 0.009 0.009 0.010 0.010 0.010 0.010 0.009 0.008 0.009 0.010 0.009 0.009 0.009 DDW-02/DMW-05 35 -0.003 -0.001 -0.041 0.015 -0.025 0.013 -0.053 0.018 -0.026 0.019 -0.011 0.009 -0.017 0.007 -0.033 0.011 -0.025 0.012 DDW-03/DMW-06 31.5 0.020 0.021 0.023 0.018 0.018 0.019 0.019 0.018 0.022 0.018 0.018 0.018 0.022 0.020 0.022 0.020 0.022 0.021 DDW-03A/DDW-03 72 0.066 0.062 0.067 0.066 0.064 0.062 0.063 0.068 0.077 0.071 0.064 0.069 0.070 0.073 0.071 0.076 0.075 0.072 DDW-05/DMW-09 20.5 0.003 -0.007 -0.008 -0.010 -0.014 -0.009 -0.005 -0.008 -0.007 -0.011 -0.012 -0.010 -0.011 -0.010 -0.009 -0.011 -0.007 -0.011 DDW-06/DMW-B 40 -0.004 -0.003 -0.004 -0.004 -0.002 15 0.000 -0.005 -0.004 -0.006 -0.003 -0.003 -0.003 -0.002 -0.002 -0.005 -0.003 -0.004 DMW-02B/DMW-02A T_ 1.001 1.019 1.031 1.050 1.150 1.022 0.993 0.993 0.921 0.886 0.996 1.031 1.015 1.075 1.038 0.996 0.941 0.965 Notes: Vertical gradients above are dispalyed in ft/ft based on groundwater elevations in Table 1 and the difference of total well depth. Data prior to 2015 were obtained from previous reports prepared by others. No Hi ies eno ea " Lowest Period Reading Positive values indicate an upward gradient; negative values indicate a downward gradient. CAR230086 Page 1 of 2 Geosyntec Consultants of NC, P.C. Table 5 Historical Vertical Hydraulic Gradients Former York Road Landfill Charlotte, North Carolina Well Pair Mar-15 Sep-15 Mar-16 Sep-16 Mar-17 Sep-17 Mar-18 Sep-18 Mar-19 Sep-1 9 Mar-20 Sep-20 Mar-21 Sep-21 Mar-22 Nov-22 Mar-23 DDW-OIAIDDW-01 0.001 0.009 0.009 0.009 0.008 0.009 0.008 0.009 0.009 0.009 0.008 0.010 0.008 0.009 0.010 0.009 0.010 DDW-02/DMW-05 -0.023 0.012 -0.009 0.012 -0.005 0.013 -0.014 0.011 -0.022 0.008 -0.034 0.013 -0.026 0.019 0.004 0.01 -0.002 DDW-03/DMW-06 0.021 0.018 0.023 0.018 0.021 0.021 0.020 .0 77 0.026 0.023 0.028 0.023 0.032 0.026 0.025 0.024 0.026 DDW-03A/DDW-03 0.069 0.069 0.083 0.074 0.075 0.080 0.078 0.072 0.100 0.070 0.102 0.093 0.102 0.100 0.095 0.081 0.087 DDW-05/DMW-09 -0.007 -0.011 -0.006 -0.011 -0.011 -0.011 -0.011 -0.009 -0.006 -0.011 -0.006 -0.012 -0.008 -0.012 bW.016 -0.012 -0.009 DDW-06/DMW-B -0.003 -0.004 -0.007 -0.005 -0.004 -0.005 -0.004 -0.005 -0.006 -0.006 -0.006 -0.006 -0.006 -0.006 -0.005 -0.004 -0.006 DMW-02B/DNI 02A 0.998 1.020 0.941 L034 0.951 0.874 0.700 0.217 -0.023 -0.317 -0.122 -0.251 -0.125 -0.156 -0.106 -0.197 -0.134 Notes: Groundwater elevations above are dispalyed in ft above National Geodetic Vertical Datum. Data prior to 2015 were obtained from previous reports prepared by others. es eno ea mg owes[ Period Reading CAR230086 Page 2 of 2 Geosyntec Consultants of NC, P.C. Table 6 March 2023 Detected Constituents in Groundwater Former York Road Landfill Charlotte, North Carolina Location DDW-01 DDW-OIA DDW-02 DDW-03 DDW-03 DUP DDW-03A DMW-01 DMW-02 DMW-02A DMW-02B DMW-05 DMW-06 DMW-08 DMW-A YRW-10C Sample Date 3/28/2023 3/28/2023 3/28/2023 3/28/2023 3/28/2023 3/28/2023 3/28/2023 3/28/2023 3/28/2023 3/28/2023 3/28/2023 3/28/2023 3/28/2023 3/28/2023 3/28/2023 Method Constituent Units EQL NC 2L MCL Barium L 2 700 2,000 23.6 60.8 336 423 432 29.8 71.5 26.1 14.2 90.1 686 15.5 29 434 Cadmium L 2 2 5 - - 44.5 - - EPA 6020B Chromium III+VI Iron 2 200 10 300 100 - 4.4 386 2.0 2.0 16,100 6.5 - 10,000 - 117,000 Lead 2 15 - - - - - - - Man anew 2 - 27 - - - - 665 - 3,570 12.5 8.4 1,23 1,1-dichloroethane L 1 - 7.3 43 8.9 4.7 2.8 - 2.4 - 4.1 - - 1 1-dichloroethene L 1 M 7 0.63 - - - - 1,2-dichlorobenzene L 1 600 - 2.0 1.4 0.89 0.30 1.3 1,2-dichloroethane L 1 5 - - - - 0.51 - 1,2-dichloropropane µg/L 1 5 0.87 2. - - - - - - 1,4-dichlorobenzene /L 1 6 75 - - - 4.4 - 2.1 Methyl Ethyl Ketone /L 5 4,000 - - - - 10.9 - - - Acetone /L 25 6,000 - - 13.3 - 14.2 - 144 118 15 13.9 Benzene /L 1 1 5 0.63 0.53 0.51 4.7 - - 0.32 - Bromomethane /L 5 - - - - - 10.7 - - - EPA Chlorobenzene /L 1 50 100 4.3 2.8 5.7 7.0 4.7 - 1.9 6.1 1.6 Chloromethane /L 2 3 - - - - 0.65 - - - 8260D cis- l,2-dichloroethene 1 70 70 19.6 13.9 2.3 25.5 14.6 2.2 - 5.3 25.3 Dichlorodifluoromethane /L 2 1000 - 8.0 1.1 - - - - - Diisopropyl ether /L 1 70 - - 0.25 0.53 0.37 0.43 Ethanol /L 200 - 323 - - - III - MTBE /L 1 20 - - - - - - 0.39 Trichloroethene /L 1 3 5 5.0 3. 3.4 2.7 0.72 - tert-bu lbenzene /L 1 70 - - - - - - - 0.54 Tetrachloroethene L 1 0.7 5 6.1 0.71 0.61 - - - Toluene L 1 600 1,000 0 s4 - - 1.0 0.78 0.99 1.2 1.6 1.1 0.75 0.8 trans-1,2-dichloroethene L 1 100 100 - 0.82 - - - - 0.64 - - - Vinyl chloride µ L 1 0.03 2 .8 1.5 3.3 0.93 - - EPA 8260D by SIM 1,4-Dioxane µg/L 1 3 - 1.5 4.7 3 81.4 - - 0.38 - 0.58 - 0.92 Temp,°C 20.5 19.7 20.6 18.8 18.8 18.8 18.2 20.8 18.8 1 18.0 1 19.5 1 18.8 1 19.6 1 18.1 20.2 Field pH Field SU 6.72 6.86 5.99 6.40 6.40 1 7.91 5.80 7.36 12.26 1 7.36 1 6.40 1 6.12 1 6.45 1 6.26 6.35 Field Specific Conductance S/cm 1,092 1 1,010 1,279 2,236 1 2,236 1 1,549 767 920 1 5,925 1 823 1 1,897 1 2,177 1 274 1 355 1,372 Total VOCs with 2L Exceedances (in at least one location)l 23.2 1 16.8 1 39.1 1 95.8 1 95.5 1 4.7 1 0.9 1 0.4 1 0.0 1 14.6 1 7.4 1 88.9 1 0.6 1 0.0 1 0.9 Total VOCs with 2L Exceedances (in at least one location excluding 1,4-dioxane)l 21.7 1 12.1 1 8.9 1 14.4 1 14.2 1 4.7 1 0.9 1 0.0 1 0.0 1 5.7 1 0.0 1 22.8 1 0.0 1 0.0 1 0.0 Notes: 1. Only detected constituents are included in the table. 2. Values with a J qualifier (shown in itallics) were estimated because the detections were above the MDL but below the EQL (which is being represented by the laboratory RL). 3. Values exceeding the NC 2L standard are displayed in bold and shaded gray. 4. Values are not considered exceedances if values are not above respective NC 2L Standards when rounded to the same decimal precisions as the respective NC 2L Standards. 5. Blank table entries indicate that the constituent was either not sampled (in the case of iron and manganese) or not detected above the MDL. Refer to analytical reports for information on which analyses were performed. 6. NC 2L standards were obtained from NCDEQ Solid Waste Section on 25 April 2023. (https://deq.nc.gov/about/divisions/waste-management/prograrn-guidance/solid-waste-section/environmental-monitoring). EPA - Environmental Protection Agency SIM - Selected Ion Monitoring MDL - Method Detection Limit EQL - Estimated Quantitation Limit RL - Reporting Limit NC 2L - Title 15A of the North Carolina Administrative Code, Subchapter 2L Standards MCL - Maximum Contaminant Level (National Primary Drinking Water Regulations) µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units CAR230086 Page 1 of 1 Geosyntec Consultants of NC, P.C. Table 7 Summary of Mann -Kendall Trend Analysis for VOCs Former York Road Landfill Charlotte, North Carolina Well Constituent Mann -Kendall Trend No. of Points DDW-01 1, 1 -dichloroethane Up 35 DDW-01 Tetrachloroethene Down 35 DDW-01 Trichloroethene Up 35 DDW-01A Trichloroethene Up 31 DDW-01A Vinyl chloride Up 31 DDW-02 1, 1 -dichloroethane Down 31 DDW-03 1,2-dichloropropane Down 34 DDW-03 Vinyl chloride Down 34 DMW-01 Vinyl chloride Down 34 DMW-06 1,2-dichloropropane Down 35 DMW-06 1,4-dichlorobenzene Up 35 DMW-06 ITrichloroetbene I Down 1 35 DMW-06 IVinyl chloride I Down 1 35 No. Downward Trends: 8 No. Upward Trends: 5 No. No Trend: 0 Notes: 1. Trends are reported at 95% confidence interval. 2. Analysis was performed on volatile organic compound (VOC) constituents with concentrations above the 2L Standard in March 2023. 3. Analysis included data collected since March 2008. 4. To avoid the effect of changing method detection limits, non -detects were replaced by zero (USEPA Unified Guidance, March 2009). 5. Only datasets with greater than 50% detections were analyzed. 6. Trend analyses were implemented using the EarthScience Information System Esdat Version 5.1.58. CAR230086 Page 1 of 1 Geosyntec Consultants of NC, P.C. Table 8 March 2023 Detected Constituents in Surface Water Former York Road Landfill Charlotte, North Carolina Location NT-1 NT-2 SC-1 SC-2 ST-1 ST-3 Sample Date 3/28/2023 3/28/2023 3/28/2023 3/28/2023 3/28/2023 3/28/2023 Method Constituent Units EQL NC 2B MCL EPA Barium µg/L 2 1,000 a 2,000 189 31 24.6 26 64 41.2 6020B Chromium (III+VI) µg/L 2 11 b 100 3.0 - - - - 3.7 EPA Acetone µg/L 25 3,100 a - 10.5J - - - - - 8260D Toluene /L 1 11 b 1,000 2.3 - - - - - EPA 8260D by SIM 1,4-Dioxane µg/L 1 0.35 a - - 0.66J 0.1 - 0.71J Temp °C - - - 18.4 17.9 18.9 18.8 18.3 16.0 Field pH (Field) SU - - - 7.12 7.02 7.88 7.48 7.50 7.36 Field Specific Conductance S/cm - - - 224.7 200.2 752 740 620 233.1 Notes: 1. Only detected constituents are included in the table. 2. Values exceeding the NC 2B standard are displayed in bold and shaded gray. 3. Values with a J qualifier were estimated because the detections were above the MDL but below the EQL (which is being represented by the laboratory RL). 4. Blank table entries indicate that the constituent was not detected. 5. NC 2B standards were obtained from NCDEQ Water Resources Planning Section: (https://www.deq.nc.gov/about/divisions/water-resources/water-planning/classification-standards/surface-water-standards) on 13 April 2023. EPA - United States Environmental Protection Agency SIM - Selected Ion Monitoring EQL - Estimated Quantitation Limit RL - Reporting Limit MCL - Maximum Contaminant Level (National Primary Drinking Water Regulations) µg/L - Micrograms per liter µS/cm - Microsiemens per centimeter SU - Standard Units a - Water supply standard b - Freshwater aquatic life standard for chronic exposure CAR230086 Page 1 of 1 Geosyntec Consultants of NC, P.C. Table 9 Proposed Groundwater and Surface Water Sampling Schedule Former York Road Landfill Charlotte, North Carolina Sample Sample Type VOCs (EPA 8260) RCRA Metals (EPA 6020 & 7470 Total Iron & Manganese (EPA 6020) 1 4-Dioxane (EPA 8260SIM) PFAS (EPA 1633) Field Parameters Water Level Field Blank Blank A A A A A Trip Blank Blank A A A DDW-01 Ground Water A A A A A A A DDW-01A Ground Water A A A A A A DDW-02 Ground Water A A A A A A DDW-03 Ground Water A A A A A A DDW-03A Ground Water A A A A A A DDW-05 Ground Water A DDW-06 Ground Water A DMW-01 Ground Water A A A A A A A DMW-02 Ground Water A A A A A A A DMW-02A Ground Water A A A A A A DMW-02B Ground Water A A A A A A DMW-05 Ground Water A A A A A A A DMW-06 Ground Water A A A A A A A DMW-08 Ground Water A A A A A A A DMW-09 Ground Water A DMW-A Ground Water A A A A A A A DMW-B Ground Water A Duplicate Ground Water A A A A A A YRW-06A Ground Water A YRW-07 Ground Water A YRW-10C Ground Water A A A A A A A YRW-11B Ground Water A NT-1 Surface Water A A A A A NT-2 Surface Water A A A A A SC-1 Surface Water A A A A A SC-2 Surface Water A A A A A ST-1 Surface Water A A A A A ST-3 Surface Water A A A A A WSW-2 Water Supply Well None None WSW-3 Water Supply Well None None Notes: 1. EPA - Environmental Protection Agency 2. RCRA - Resource Conservation and Recovery Act 3. VOCs - volatile organic compounds 4. PFAS - per and poly-fluoroalkyl substances 5. A - Annual frequency (fall) 6. Field parameters include conductivity, pH, and temperature. 7. RCRA metals include arsenic, barium, cadmium, chromium, lead, mercury, selenium, and silver. 8. One trip blank should be included with every sample shipment. 9. * indicates that water supply well was permanently abandoned by others on 21 September 2022. CAR230086 Page 1 of 1 Geosyntec Consultants of NC, P.C. FIGURES �e _ y0 O 0 e�0 p 00 ®l Pe PIPER LN O� 0 -LAKE BLVD 00 ' o D m 1 1 Q EVAN SRD ko ONT RD ej!!y CIIA WIGNT of CR4H. z°OORipC f �FNTfR D �1 < - R �O � O e �o o e� s 0 �P LR�L ®TTE a , 01 P�p� \ The Art LANDFILL AREA D —� institute of * r LANDFILL AREA F SeEE ' ��o e� 1980-1983 darlotte �—y� 1984-1986 cRD` PROPERTY LINED J oo Q°NT9o_ KA E A F ork m - Memorial a Q - •:" % Cem\ CLUBHyO(USE N RENAISSANCE E B / MAINTENANCE BUILDING LANDFILL AREA E A 1983-1984 C LANDFILL AREA B / 1974-1980 LANDFILL AREA C l `b 1972-1976 / I� �1si�_ \ Mission �\ LANDFILL AREA A Ho mp Church Cem p0\ �<<O O 1968-1972 wRo Z SHOPTON RD �`� jYVOL,,CENTRE,DR z fj jO y0 gARE �\ _ SRO C°O�� SHARVIEW CIR ?� JACOBS----_- � 3 FORK (N o EGREfN OR £CHODq EE DR-700 0 OEDE ky, 9FTY z V 0 2000' 4000' 4". �� h c eso. .; SCALE IN FEET 2E ,, REFERENCES: SITE LOCATION MAP 1. PROPERTY LINES OBTAINED FROM MECKLENBURG FORMER YORK ROAD LANDFILL COUNTY GIs. CHARLOTTE, NORTH CAROLINA 2. U.S.G.S. 7.5 MINUTE QUADRANGLE CHARLOTTE WEST, �ie05YCltec DATED 2019. consultants Figure: 3. APPROXIMATE WASTE BOUNDARY OBTAINED FROM EM csKca�wwnuora r.. MAPPING PERFORMED BY GEO SOLUTIONS, LTD, OBTAINED 23 OCT 2017 AND HISTORICAL DRAWINGS. CHARLOTTE, NC AUGUST 2023 \\CHARLOTTE-01\DATA\CADD\_PROJECTS\C\CITY OF CHARLOTTEWORK ROAD LANDFILL\CORRECTIVE ACTION EVALUATION REPORT (GC5699H.01)\DRAWINGS\SHEETS\GC5699F002.DWG (24 July 2023) mjerome n SC-1 �a UA �I y 1�4 11 N-IN NT-2 Aiy.• e F— I LANDFILL AREA F 1984-1986 JOHN A CROSLAND tij£=i''`' k r SCHOOL NEB-PZ 1* L NEB-PZ-2 NORTHEAST ABOUNDARY EXTRACTION LANDFILL �+ '� ' SYSTEM� AREA D 1980-1983 NEB-PZ-3 ST-3 DMW-B YRW-07 O �.r ,.:rr�• . _ , •;�'1"1'rs � O f �•t..r NT-1 r ST-2 ,�•,,: •s - Y,�• _• DDW-05 E"!T. Ar -� a+,t ! YRW 11 B DMW 09 '1 ` `t ! �`y r F . yi 7 �• I Y'4F L .` k n.w _'_..."...'. • �- .. a'-f:'a.. •. v r 't �+ .�.:1 GOLF- '4 CLUBHOUSE .• . • �r h . LANDFILL r AREA B r-;No 01 i + r 1974-1980 LANDFILL r �r A' • r' YRW-10C AREA E •.� re •: < 1983-1984 RENAISSANCE YRW-09A y MAINTENANCE - LANDFILL DDW-X01A AREA DMW-08 .•°f:- BUILDING DDW-01 1968-1972' ' �r YRW-08A DMW 05 .DDW-02 O ` LANDFILL DMW 01� AREA C +_; � >✓ fir.. p �-�� •-F 1972-1976 c LEATHERMAN MAINTENANCE BUILDING YRW-06A - DDW-03AST-1 DMW-02A O DMW 06 DDW-03 O DMW-02 DMW-02B SC-2V-1 - t o� " I r r• WSW-2 WSW-3 LEGEND REFERENCES APPROXIMATE PROPERTY BOUNDARY STREAM GROUNDWATER COMPLIANCE BOUNDARY (NOTE 5) SHALLOW MONITORING WELL (SCREEN <25 ft BGL) INTERMEDIATE MONITORING WELL (SCREEN 25-65 ft BGL) DEEP MONITORING WELL (SCREEN >65 ft BGL) STREAM SAMPLE LOCATION • WATER SUPPLY WELL (NOTE 7) ❑ PIEZOMETER .s r'.�:a ���,�'� ram. 4-.rti �,' R .dY• ••�,'�..! - '.�;'�• `.+�:- ..;�. `r � �� fir"• �"w' .! i'`aYI.s1 4.4 1. AERIAL PHOTOGRAPHY OBTAINED FROM NEARMAP, DATE OF PHOTOGRAPHY JANUARY 27, 2023. 2. PROPERTY LINES OBTAINED FROM MECKLENBURG COUNTY GIS. 3. WELL AND MONITORING LOCATIONS APPROXIMATED FROM DRAWINGS PREPARED BY HDR. 4. STREAM LOCATIONS FROM MECKLENBURG COUNTY GIS, NORTH CAROLINA OPEN MAPPING WEBSITE, 20141014, CREEKS AND STREAMS. 5. THE GROUNDWATER COMPLIANCE BOUNDARY IS DEFINED AS 500 FEET FROM THE WASTE BOUNDARY, OR THE PROPERTY BOUNDARY, WHICHEVER IS CLOSEST. 6. APPROXIMATE WASTE BOUNDARY OBTAINED FROM EM MAPPING PERFORMED BY GEO SOLUTIONS, LTD, OBTAINED 23 OCT 2017 AND HISTORICAL DRAWINGS. 7. WATER SUPPLY WELLS WERE PERMANENTLY ABANDONED BY OTHERS ON 21 SEPTEMBER 2022. 0 600' 1200' SCALE IN FEET SITE PLAN FORMER YORK ROAD LANDFILL CHARLOTTE, NORTH CAROLINA Geosyntec° consultants Figure CHARLOTTE, NC AUGUST 2023 \\CHARLOTTE-01\DATA\CADD\_PROJECTS\C\CITY OF CHARLOTTE\YORK ROAD LANDFILL\CORRECTIVE ACTION EVALUATION REPORT (GC5699H.01)\DRAWINGS\SHEETS\GC5699F003.DWG (21 August 2023) mjerome pqa Im � 6 DMW-B 1 (592.41) '. r S90 ` S8 ' I O i 'YRW-10C (575.89) iAr 4 `r i9"01ADDW46 (578.76) i 4DDW-01 \ LANDFILL AREA E 1983-1984 '6-07_/°u (611.71) (578.37), 1y t i ryn,:Hy, DMW-05 LANDFILL (576.03) AREA C 1972-1976 LANDFILL AREA B 1974-1980 a � � DMW-A��� "} /r(644.04t 4 110 • t YRW-11 B (596.93) I LANDFILL , AREA A 1968-1972 / DDW-05 , �(596.70) DMW-09 (596.89) 61 O \ DMW-080000' (614.21) r DDW-02 � YRW-06A o (575.97) (578.74) DMW-01 o 04 (593.76)01 DDW-03A CP DMW-02A * ' ,( ) " 594.26 �DMW-02 I i DMW-02B w d (590DDW.81) -03 (589.22) •�f r s�`! X' (574.52) , K��� (575.33) .rar .Ir�a rY t{ d Ky —_.. ",A JY.+F+-IN►' &.._� j. r r r ' - 3�7. _ I Nr J"T M ! 4.1g�•,,}, �p,7w' k �I;;dgr, X "^,y I�„- 1, 'i�-c, .. `i4RR _��J ✓'� x .O , # it'''4 r*r F k yO.b'�:.;... a F_!� .4+ i'� t ~ A t q Y� m s�#•r v d►.4' �• OWN �'r �s ^�a � 4 v. N.v. i� 1 ;..0 ✓.r W r /• WSW 2 �Y. .1- ^WSW-3 � � .e _ ara W 1r ':���' '� x�sr �4 � ,� M tt„ �r•. +�gi�1.` :.r !"`= ;.� F, s a ai(:+r'�•' .rye .'L. +4: � 1'L ,' i N; . r a d �` ' l �Jr � `�� J � s �y �'%�i g � •� ' a^�. � `�. ,f' LEGEND REFERENCES APPROXIMATE PROPERTY BOUNDARY 1. AERIAL PHOTOGRAPHY OBTAINED FROM 7. FLOW DIRECTION WEST OF SUGAR CREEK NEARMAP, DATE OF PHOTOGRAPHY FROM HART & HICKMAN, 2023. STREAM (NOTE 5) JANUARY 27, 2023. (575.33) GROUNDWATER ELEVATION (FT. NGVD) 2. PROPERTY LINES OBTAINED FROM MECKLENBURG COUNTY GIS. GROUNDWATER CONTOUR 3. WELL AND MONITORING LOCATIONS 0 600' 1200' APPROXIMATED FROM DRAWINGS PREPARED GROUNDWATER FLOW DIRECTION BY HDR. SCALE IN FEET SHALLOW MONITORING WELL 4. STREAM LOCATIONS FROM MECKLENBURG (SCREEN <25 ft BGL) COUNTY GIS, NORTH CAROLINA OPEN UNCONSOLIDATED POTENTIOMETRIC MAPPING WEBSITE, 20141014, CREEKS AND SURFACE MAP 2 MARCH 2O23 INTERMEDIATE MONITORING WELL STREAMS. (SCREEN 25-65 ft BGL) 5. APPROXIMATE WASTE BOUNDARY OBTAINED FORMER YORK ROAD LANDFILL FROM EM MAPPING PERFORMED BY GEO CHARLOTTE NORTH CAROLINA DEEP MONITORING WELL SOLUTIONS, LTD, OBTAINED 23 OCT 2017 AND r (SCREEN >65 ft BGL) HISTORICAL DRAWINGS. GeosyCitec 6. WATER SUPPLY WELLS WERE PERMANENTLY • WATER SUPPLY WELL ABANDONED BY OTHERS ON 21 SEPTEMBER consultants 2022. GeoWntec Consultants of NC, P.C. * INDICATES BEDROCK WELL WAS NOT USED FOR CONTOURING CHARLOTTE, NC AUGUST 2023 Figure: 3 \\CHARLOTTE-01\DATA\CADD\_PROJECTS\C\CITY OF CHARLOTTE\YORK ROAD LANDFILL\CORRECTIVE ACTION EVALUATION REPORT (GC5699H.01)\DRAWINGS\SHEETS\GC5699F004A.DWG (21 August 2023) mjerome IN IN v OAij <9 i DDW-06{ Gt4sv__'3 YRW-10C 03/28/2023 IRON 117,000 MANGANESE 1,230 i / LANDFILL AREA E 1983-1984 Y. YRW-10(-,�l (0.92) YRW-09A �. DDW 01A k DDW-01 ._ YRW-08A 05 ` (7.40) DDW-02 LANDFILL DMW-05 03/28/2023 IRON 10,000 MANGANESE 3,570 1,4-DIOXANE 7.4 AREA C 1972-1976 w r a DDW-03A DMW-06� (88 93) DMW-A,. 03/28/2023 \ a, NO EX CEEDANCES fDM4 W � �ta 00 .0t,k NN LANDFILL AREA F LANDFILL 1984-1986 AREA D � 3 LANDFILL AREA B 1974-1980 1980-1983 / DDW-05 YRW-•111BB� DMW-09 LANDFILL AREA A 1968-1972 4 � IMW-08 V 0 ' . r ✓+ II O ar{ DDW-03 � t r r (95.83) WSW-2 RW-0 / � s4 /W-01 DMW-02 03/28/2023 IRON 3,84 MANGANESE 2,95 DMW-02 (0.38) . f13 F, %, 7. '►'it WSW-3 i11_ 7 (VOTES LEGEND 1. TOTAL VOLATILE ORGANIC COMPOUND (VOC) CONCENTRATIONS APPROXIMATE PROPERTY BOUNDARY BASED ON SUMMATION OF VOCS WITH CONCENTRATIONS ABOVE THE NORTH CAROLINA ADMINISTRATIVE CODE SUBCHAPTER STREAM 2L.0202 STANDARDS IN ONE OR MORE WELLS IN MARCH 2O23. 2. INFERRED 5 MICROGRAM PER LITER (lag/L) PLUME BOUNDARY 5 lag/L ISOCONCENTRATION LINE BASED ON LOCATION OF WASTE, WELLS BELOW 5 lag/L VOCS OF (DASHED WHERE INFERRED) CONCERN IN MARCH 2O23, AND HYDRAULIC DIVIDE AT SUGAR CREEK. 3. RESULTS SHOWN IN MICROGRAMS PER LITER (lag/L). 4. NC 2L - TITLE 15A OF THE NORTH CAROLINA ADMINISTRATIVE CODE, SUBCHAPTER 2L STANDARDS. 5 ONLY DETECTED CONSTITUENTS ABOVE NC 2L STANDARDS ARE SHOWN. DETECTIONS WERE CONSIDERED NOT ABOVE 2L STANDARDS WHEN REPORTED CONCENTRATION PRECISIONS WERE ROUNDED TO PRECISIONS OF RESPECTIVE CONSTITUENT NC 2L STANDARDS. 6 STREAM LOCATIONS FROM MECKLENBURG COUNTY GIS, NORTH CAROLINA OPEN MAPPING WEBSITE, 20141014, CREEKS AND STREAMS. 7. FOR FULL LEGEND AND REFERENCES, SEE FIGURE 2. 8. WATER SUPPLY WELLS WERE PERMANENTLY ABANDONED BY OTHERS ON 21 SEPTEMBER 2022. DMW-06 03/28/2023 1,2-DICHLOROPROPANE 2.5 1,4-DICHLOROBENZENE 7.6 1,4-DIOXANE 66.1 MANGANESE 252 TRICHLOROETHENE 4.4 VINYL CHLORIDE 3.3 DMW-01 3/30/2022 1,1-DICHLOROETHANE 6.0 1,2-DICHLOROETHANE 0.4 1,2-DICHLOROPROPANE 0.6 1,4-DICHLOROBENZENE 6.0 1,4-DIOXANE 3 BARIUM 700 BENZENE 1.0 CADMIUM 2.0 IRON 300 LEAD 15 MANGANESE 50 TRICHLOROETHENE 3.0 TETRACHLOROETHENE 0.7 VINYL CHLORIDE 9.03 DDW-03 03/28/2023 1,2-DICHLOROPROPANE 2.5 1,4-DIOXANE 81.4 VINYL CHLORIDE 3.3 MONITORING WELL I.D. SAMPLE DATE 0 600' 1200' SCALE IN FEET PLUME MAP SAPROLITE FORMER YORK ROAD LANDFILL CHARLOTTE, NORTH CAROLINA Geosyntec Figure: consultants Geosyntec ConsultantsoMC P.C. 9. 'J' INDICATES CONCENTRATION IS ESTIMATED AS IT WAS NC 2L 4A DETECTED BELOW THE ENVIRONMENTAL QUANTITATION UNIT. EXCEEDANCE CRITERIA CHARLOTTE, NC AUGUST 2023 \\CHARLOTTE-01\DATA\CADD\_PROJECTS\C\CITY OF CHARLOTTE\YORK ROAD LANDFILL\CORRECTIVE ACTION EVALUATION REPORT (GC5699H.01)\DRAWINGS\SHEETS\GC5699F004B.DWG (21 August 2023) mjerome —N— � ^8i,d i i YRW-10C s x vf�t " tr 4Y/q l xr W DMW r I (7. i DMW-B OF d � t 3,•�i• `�k -"fir'.. a.;��.h: LANDFILL AREA E 1983-1984 �. DDW-01` � DDW-01` / ._ YRW-08A -05 N 40) DMW-05 03/28/2023 IRON 10,000 MANGANESE 3,570 1,4-DIOXANE 7.4 LANDFILL \ AREA C 1972-1976 DDW-02_/ (3910) DDW-03A� DMW-06 At y>,�1- p+w " t�,y..,1F-..M •t'.; +' f'yy . , x 3 �j'� 'f ,f�' ;� r {>i f �'� hrd . R:.•�p� _,};, ,-a. .r•r. af�- ,,ppM�.'� h`c ..';;." X t� _.A# •_ Grp^ a v - C @'• k' '0R„�; • r .. •+"'°! #R.\.k+'a :.FI t,;. ,�,:r�-"` r,ra,...,,% �( .. �:?"S r, ;',4t •t pt.1' t, "''t, q �#: ''��}%� r}'fir: {t q , �r:a': � �!' ,t � J� .& �A [ 1 0. � ;�� �►� ' . •� ,, 3�w�,� 50 �.y �" #-.#� ' .�, *, I �'' '�zl i� �A � <••� C7�.,�, :x �;,.•,,, �1v <r r.t f d. ''Sr ► r. F 7d� of .« ^ p 4 p �I •d��Nf+ �p .��'� :i, � t +• ��; YI r`t. r 'll �a �'*.] M^-y" !WSW2 .f^.;{! r C „ �WSW-3PI`"�} ,"�'.,+ �'r,, k,. 'i ff� wr, r• 1•' S7 rA9�1L,7C:Fw't,Ml (VOTES LEGEND 1. TOTAL VOLATILE ORGANIC COMPOUND (VOC) CONCENTRATIONS APPROXIMATE PROPERTY BOUNDARY BASED ON SUMMATION OF VOCS WITH CONCENTRATIONS ABOVE THE NORTH CAROLINA ADMINISTRATIVE CODE SUBCHAPTER STREAM 2L.0202 STANDARDS IN ONE OR MORE WELLS IN MARCH 2O23. 2. INFERRED 5 MICROGRAM PER LITER (IJg/L) PLUME BOUNDARY 5 Ng/L ISOCONCENTRATION LINE BASED ON LOCATION OF WASTE, WELLS BELOW 5 lag/L VOCS OF (DASHED WHERE INFERRED) CONCERN IN MARCH 2O23, AND HYDRAULIC DIVIDE AT SUGAR F, {Q!#�•�Idf! ,� � �: :;:;°2uk,+.t�,tnr�'ar+`;d.•f�:i..y'�y s ' [ / DMW A° i F r � 2 LANDFILL AREA F LANDFILL 1984-1986 AREA D 1980-1983 *-YRW-07 , / i DDW-05 YRW-11 Bh� DMW-09 \ LANDFILL AREA B 1974-1980 es ' —� rJA� DMW-01 03/28/2023 CADMIUM 44.5 IRON 16,100 MANGANESE 665 VINYL CHLORIDE 0.93J DDW-02 03/28/2023 1,1-DICHLOROETHANE 8.9 1,4-DIOXANE 30.2 4. NC 2L - TITLE 15A OF THE NORTH CAROLINA ADMINISTRATIVE CODE, SUBCHAPTER 2L STANDARDS. 5 ONLY DETECTED CONSTITUENTS ABOVE NC 2L STANDARDS ARE SHOWN. DETECTIONS WERE CONSIDERED NOT ABOVE NC 2L STANDARDS WHEN REPORTED CONCENTRATION PRECISIONS WERE ROUNDED TO PRECISIONS OF RESPECTIVE CONSTITUENT NC 2L STANDARDS. 6 STREAM LOCATIONS FROM MECKLENBURG COUNTY GIS, NORTH CAROLINA OPEN MAPPING WEBSITE, 20141014, CREEKS AND STREAMS. 7. FOR FULL LEGEND AND REFERENCES, SEE FIGURE 2. 8. WATER SUPPLY WELLS WERE PERMANENTLY ABANDONED BY OTHERS ON 21 SEPTEMBER 2022. /0001� �1 / DMW-01 (0.93) �' IRW 06A r• '.pMW 02B3 �, < `A';:„'. yrF ! Or 1Yf; DM -02A :., .�, V D DMW-02J (0.38) DDW-03 4 r 'v DDW-03 03/28/2023 1,2-DICHLOROPROPANE 2.5 1,4-DIOXANE 81 .4 VINYL CHLORIDE 3.3 DMW-01 3/30/2022 1,1-DICHLOROETHANE 6.0 1,2-DICHLOROETHANE 0.4 1,2-DICHLOROPROPANE 0.6 1,4-DICHLOROBENZENE 6.0 1,4-DIOXANE 3 BARIUM 700 BENZENE 1.0 CADMIUM 2.0 IRON 300 LEAD 15 MANGANESE 50 TRICHLOROETHENE 3.0 TETRACHLOROETHENE 0.7 VINYL CHLORIDE 0.03 9. 'J' INDICATES CONCENTRATION IS ESTIMATED AS IT WAS NC 2L DETECTED BELOW THE ENVIRONMENTAL QUANTITATION UNIT. EXCEEDANCE CRITERIA DMW-02 03/28/2023 IRON 3,840 MANGANESE 2,950 0 600' 1200' SCALE IN FEET PLUME MAP PWR FORMER YORK ROAD LANDFILL CHARLOTTE, NORTH CAROLINA Geosyntec Figure: consultants Geosyntec Consultants of NC, P.C. 4 B CHARLOTTE, NC AUGUST 2023 \\CHARLOTTE-01\DATA\CADD\_PROJECTS\C\CITY OF CHARLOTTE\YORK ROAD LANDFILL\CORRECTIVE ACTION EVALUATION REPORT (GC5699H.01)\DRAWINGS\SHEETS\GC5699F004C.DWG (21 August 2023) mjerome 1-�O DMW AAr� •. f 4 '• LANDFILL AREA F LANDFILL 1984-1986 AREA D 19 0- 983 afi x YRW-07 DMW-B DDW-06{ .: 711h • � . , t � l"` � w Spa * 4.4 ri+ ��g s?'F �P31 z�y DDW 05 d �q�,.#fit Y_RW 11B DMW 09 vp y s' .�E,'� f2p3 ,�za, .� � - a -�;9r .-"'G- ' 'ems` � v .r r' � t(`•�' �i. 1°X;,9 ,' :aa� # 3."SLR' $ !+. § t�j°',�`M. , '• '.' r"� �`6-�''1 �,"'.j� Ow LANDFILL AREA B a y a YRW-10C 1974-1980 LANDFILL AREA E +✓ . 1983-1984 • Y r.% DDW-01 A 16.81) LANDFILL / Q.. 09A YRW ,, DDW-01A �- AREA A DMW 08 03/28/2023 1968-1972 BENZENE 2.0 1,4-DIOXANE 4.7 \ t' TRICHLOROETHENE 3.6 YRW-08A / VINYL CHLORIDE 1.5 ,DMW-05 DDW-01 DM DDW-02 / W-01 DMW-02B 03/28/2023 (2320) ` LANDFILL AREA 1,2-DICHLOROETHANE 0.51J t s; DDW-01 1972-1976 1,4-DIOXANE 8.9 03/28/2023 1,1-DICHLOROETHANE 7.3 YRW 06A DMW-02 w 1,2-DICHLOROPROPANE 0.87J DDW 03A , p 70) IRON 386 a'+ DMW-02A TETRACHLOROETHENE 6.1 / DMW-02B� (0.00) p TRICHLOROETHENE 5.0 DDW-03A y \/ (14.63) i, VINYL CHLORIDE 1.8 03/28/2023 DMW-06' off. r+M BENZENE a.7 DMW-02A 03/28/2023 .r DDW-03, L BARIUM 1,090 ¢ LEAD 187 �,- k}?t{y0 _ ,.1ggJ ni.., m•'$I,"`� +.[ 4j;g ,+;•.J 47i: R♦.. �k� ! p ia f � WSW-2 WSW-3, cf' {�" ,� k`. A -ly i :, �'•s '^T°�°n ,� (VOTES LEGEND 1. TOTAL VOLATILE ORGANIC COMPOUND (VOC) CONCENTRATIONS APPROXIMATE PROPERTY BOUNDARY BASED ON SUMMATION OF VOCS WITH CONCENTRATIONS ABOVE THE NORTH CAROLINA ADMINISTRATIVE CODE SUBCHAPTER STREAM 2L.0202 STANDARDS IN ONE OR MORE WELLS IN MARCH 2O23. 2. INFERRED 5 MICROGRAM PER LITER (IJg/L) PLUME BOUNDARY 5 Ng/L ISOCONCENTRATION LINE BASED ON LOCATION OF WASTE, WELLS BELOW 5 lag/L VOCS OF (DASHED WHERE INFERRED) CONCERN IN MARCH 2O23, AND HYDRAULIC DIVIDE AT SUGAR CREEK. 3. RESULTS SHOWN IN MICROGRAMS PER LITER (Ng/L). 4. NC 2L - TITLE 15A OF THE NORTH CAROLINA ADMINISTRATIVE CODE, SUBCHAPTER 2L STANDARDS. 5 ONLY DETECTED CONSTITUENTS ABOVE NC 2L STANDARDS ARE SHOWN. DETECTIONS WERE CONSIDERED NOT ABOVE NC 2L STANDARDS WHEN REPORTED CONCENTRATION PRECISIONS WERE ROUNDED TO PRECISIONS OF RESPECTIVE CONSTITUENT NC 2L STANDARDS. 6 STREAM LOCATIONS FROM MECKLENBURG COUNTY GIS, NORTH CAROLINA OPEN MAPPING WEBSITE, 20141014, CREEKS AND STREAMS. 7. FOR FULL LEGEND AND REFERENCES, SEE FIGURE 2. 8. WATER SUPPLY WELLS WERE PERMANENTLY ABANDONED BY OTHERS ON 21 SEPTEMBER 2022. DMW-01 3/30/2022 1,1-DICHLOROETHANE 6.0 1,2-DICHLOROETHANE 0.4 1,2-DICHLOROPROPANE 0.6 1,4-DICHLOROBENZENE 6.0 1,4-DIOXANE 3 BARIUM 700 BENZENE 1.0 CADMIUM 2.0 IRON 300 LEAD 15 MANGANESE 50 TRICHLOROETHENE 3.0 TETRACHLOROETHENE 0.7 VINYL CHLORIDE 9.03 MONITORING WELL I.D. SAMPLE DATE 0 600' 1200' SCALE IN FEET PLUME MAP BEDROCK FORMER YORK ROAD LANDFILL CHARLOTTE, NORTH CAROLINA Geosyntec consultants Figure Geosyntec ConsulMntsofNC P.C. 9. 'S INDICATES CONCENTRATION IS ESTIMATED AS IT WAS NC 2L 4C DETECTED BELOW THE ENVIRONMENTAL QUANTITATION UNIT. EXCEEDANCE CRITERIA CHARLOTTE, NC AUGUST 2023 1,1-dichloroethane 10 9 8 7 6 e 5 4 3 2 1 0 18 Mar 08 13 Dec 10 8 Sep 13 4 Jun 16 1 Mar 19 25 Nov 21 Trichloroethene 8 7 6 5 J 4 3 2 1 0 18 Mar 08 13 Dec 10 8 Sep 13 4 Jun 16 1 Mar 19 25 Nov 21 Tetrachloroethene 14 12 10 8 o� 6 4 2 0 18 Mar 08 13 Dec 10 8 Sep 13 4 Jun 16 1 Mar 19 25 Nov 21 Vinyl Chloride 3.5 3 2.5 2 1.5 1 0.5 0 18 Mar 08 13 Dec 10 8 Sep 13 4 Jun 16 1 Mar 19 25 Nov 21 DDW-01 —4&--- DDW-01A — — —2L Stand and 1,1-dichloroethane 50 40 30 I 20 I 10 0 18 Mar 08 13 Dec 10 8Sep 13 4Jun 16 1Mar 19 25 Nov 21 1,4-dichlorobenzene 30 25 20 e 15 10 5 0 18 Mar 08 13 Dec 10 8Sep 13 4Jun 16 1Mar 19 25 Nov 21 i,o-aicnioropro pane 5 4.5 4 3.5 3 e 2.5 2 1.5 1 0.5 0 18 Mar 08 13 Dec 10 8 Sep 13 4 Jun 16 1 Mar 19 25 Nov 21 Trichloroethene 10 8 6 4 2 0 18 Mar 08 13 Dec 10 8Sep 13 4Jun 16 1Mar 19 25 Nov 21 Vinyl Chloride to 9 8 7 6 a 5 4 3 2 1 0 18 Mar 08 13 Dec 10 8Sep 13 4Jun 16 1Mar 19 25 Nov 21 $ DDW-02 --E— DDw-03 —� DM1N-01 DMW-06 — — — 2LStandard APPENDICES APPENDIX A Site Current Conditions Photolog GEOSYNTEC CONSULTANTS Photographic Record Geosyntec consultants Geowniec Consultnms of NC, P.C. Client: City of Charlotte Site Name: York Road Landfill ICI a p Satellite4e Renaissance Gulf Course Project Number: Site Location: Ph-'PRenaissance ark' Skate Park 4? r r Re nee Dog Park tiY r ha rlotte City Tennis Ask ilmer's Commercial Home services rr GC5699H Renaissance Park, 1536 Charlotte, NC 28217 Ipw 9 The John Dp� chool Renaissance Golf Course - Renais anti Park Renaissance Disc Golf Park -Gold Jeff Adams Tennis Center W Tyvola Rd, Colliers Engineeri & Design 9 .. �. R 4 Veterans Bridge H Vk Public Storage Leatherman Golf Learning Center oa rd shortcuts Map data . 2023 l e Terms of Use we 9 York Memoria York Memori ti cnarion� Church of Chri - R-6 L P- rt a map error Geosyntec ° consultants Geos"tec Consultants of NC, P.C. GEOSYNTEC CONSULTANTS Geosyntec° Photographic Record consultantsGcosvn[ec Consultants of NC, P.C. Client: City of Charlotte Project Number: GC5699H Site Name: York Road Landfill Site Location: Renaissance Park, 1536 W Tyvola Rd, Charlotte, NC 28217 Photograph 1 Date: 04/21 /2023 Direction: NE Comments: Methane Detection System in • Renaissance Park Concession Stand �T Photograph 2 Date: 04/21 /2023 Direction: E F= 1� !iL t t Comments: Volleyball courts in Renaissance Park Geosyntec consultants Geosyn[ec Consultants of NC, P.C. GEOSYNTEC CONSULTANTS Geosyntec° Photographic Record `°'lswtailt5 Gcosvn[ec Consultants of NC, P.C. Client: City of Charlotte Project Number: GC5699H Site Name: York Road Landfill Site Location: Renaissance Park, 1536 W Tyvola Rd, Charlotte, NC 28217 Photograph 3 ` n+ Date: 04/21 /2023 Direction: W Comments: Renaissance Park Concession Stand l Photograph 4 Date: 04/21 /2023 Direction: E Comments: Northeast Boundary Blower System# at Renaissance Park - - � .- �.--_- -L,. yet•—• _ -._ _ �-- - - "`- '' _ ..M1 t _ _ � _ �" -- .T - •- _ -.-_ Geosyntec consultants Geosyn[ec Consultants of NC, P.C. GEOSYNTEC CONSULTANTS Geosyntec° Photographic Record consultantsGcosvn[ec Consultants of NC, P.C. Client: City of Charlotte Project Number: GC5699H Site Name: York Road Landfill Site Location: Renaissance Park, 1536 W Tyvola Rd, Charlotte, NC 28217 Photograph 5 ' Date: 04/21 /2023 Direction: E Comments: Northeast Boundary Blower System at Renaissance Park I _ 4'k I� 1 Kai lF s %11%�" L �ti4it�ti r � ■Yt R ' J Photograph 6 f Date: 04/21 /2023 Direction: E Comments: Northeast Boundary Blower System _ at Renaissance Park 1 i _ r � I I E_■ Geosyntec consultants Geosyn[ec Consultants of NC, P.C. GEOSYNTEC CONSULTANTS Geosyntec° Photographic Record consultantsGcosvn[ec Consultants of NC, P.C. Client: City of Charlotte Project Number: GC5699H Site Name: York Road Landfill Site Location: Renaissance Park, 1536 W Tyvola Rd, Charlotte, NC 28217 Photograph 7 ,� I _ Date: 04/21 /2023 Direction: NW Comments: Methane Detection System Harry at --:=_- L. Jones Sr. golf course r 4 - maintenance building # I F -Jt*Ak�k max. I•Illilrllll11111`IIIIII Ili' IIIIII.lII'II III , K I i �._N I- Photograph 8 Date: 04/21 /2023 + ter. Direction: SW Comments: Leathermans Driving Range maintenance building (off -site) ;. S- T WN MOLL • - -'- Geosyntec consultants Geosyn[ec Consultants of NC, P.C. GEOSYNTEC CONSULTANTS Geosyntec° Photographic Record consultantsGcosvn[ec Consultants of NC, P.C. Client: City of Charlotte Project Number: GC5699H Site Name: York Road Landfill Site Location: Renaissance Park, 1536 W Tyvola Rd, Charlotte, NC 28217 Photograph 9 •- Date: 04/21 /2023 Direction: E Comments: Leathermans Driving Range (off - site) -; .4 .tip _,: Photograph 10 Date: 04/21 /2023 ,. Direction: S E comments: `� '`''FP Harry L. Jones Sr. Golf Course Clubhouse Blower System p T I F 6 a 1 i I "''1711 4 Geosyntec consultants Geosyn[ec Consultants of NC, P.C. GEOSYNTEC CONSULTANTS Geosyntec° Photographic Record consultantsGcosvn[ec Consultants of NC, P.C. Client: City of Charlotte Project Number: GC5699H Site Name: York Road Landfill Site Location: Renaissance Park, 1536 W Tyvola Rd, Charlotte, NC 28217 Photograph 11 Date: 04/21 /2023 Direction: W Comments: i Harry L. Jones Sr. Golf Course Clubhouse Blower System , • x - - r; ,r. r M 1. 1 � K r r �I I I t k f ,4 Photograph 12 • 07 28 2023 Date. / / . y r I Direction: - I Comments: Harry L. Jones Sr. Golf Course / Y ki F Clubhouse Blower System '; I 5 , f 7. + �� • _ - r •t 1 T i Geosyntec consultants Geosyn[ec Consultants of NC, P.C. �`. .; 1.. �1ykl, y �yi• �• ��� i i �'-�• _ _ � of y � � '77i •••s�r \ ; a K _•t - fi - •.ii*1�� r 1 ell wiv dr le AL lb w••ti.irk 10 r i •` r 40 co � � ;� • 'tis ..� ti J �- � +_ ^'—•_ t : � a ter, � � � :� �r , " � � � _ ; •�L. .►ter._... -� - . - r -lam Pt rsw�' l J. rt - Al!_ tv ION 1 � k'llb +' • � t � — *` f � _• -r � � 1 f_�. F Tea J � I� r; R �tl� ■ .• 1 — �. 9.0 IL 9 Ab 41. NO vp lk lee IL Wf oee dW- 16 f w L ..w, �{ y•A �a•.° F � ■ I APPENDIX B Boring Logs and Cross -Sections 0 I 0 M 0 11 0 0 0 0 0 0 C ro C Project Number. EO91-014 Site Id: DDW-01A Project Name: YORK ROAD LANDFILL Location: YORK ROAD LANDFILL, CHARLOTTE, NC ,0///Delta Environmental Aconsultant5, Inc.. Contractor. GEOLOGICAL EXPLOR. Elevation: 585.06'. Consulting Firm: Delta Datum: Mean Sea Level Logged By: Measuring Point:585.O6' Date(s):.O5/24/01 — 05/29/01 Conductor Casing: type: Steel dia: 6.00in fm: 0.00' to: 85.50' Purpose: Monitoring Well, Deep Blank Casing: Dulling Method: Hollow Stem Auger/Air Rotary type: PVC dia: 2.00in fm: —1.8' to: 90.00' Remarks: borehole 12' to 30', 10* to 85.5', 6' to 102' Screens: type: Slotted size: 0.01Oirdia: 2.00in fm: 90.00' to:1OO.00' Annular Fill: type: Grout fm: 0.00' to: 80.00' type: Betonite fm: 80.00' to: 88.00' type: Sand Pack generic fm: 88.00' to:1O2.00' Well Construction v v c z a o Material Description > a 0 E 3 a a v MP. EL. 585.0 o d d o O ML BOREHOLE = 12 Alluvium: sandy, clayey Sill, brown to dark brown, fine to very fine grained sand. 580 10 CL Muv= Clay to silly Clay, brown to dark brown. 570 20 SP Alluvium: Sand, well sorted bluish to greenish grey, saturated. Unconsolidated, very fluid. Air dull looses in Air rotary return sand. being lost in sand zone. 560 Formation becomes stiffer, may be beginning of soprorite or partially weathered rock No cuttings seen, lost in overlying sand zone. 30 — — — WR BOREHOLE = 10' Bedrodc Granitic intrusive rock Becomes more competent with depth. 550 — — — BR 40 - 540 50 530 Page 1 of 2 0 41 r� L� 0 X 10 0 0 G Project Number. E091-014 Site Id: DDW-01A Delta �////� Project Name: YORK ROAD LANDFILL Location: YORK ROAD LANDFILL, CHARLOTTE, NC Consultontstalnc. Contractor. GEOLOGICAL IXPLOR. ' Elevation: 585.06 Consulting firm: Delta Datum: Mean Sea Level Logged By: Measuring Point:585.06' Date(s):05/24/01 — 05/29/01 Conductor Casing: type: Steel dia: 6.00in fm: 0.00' to: 85.50' Purpose: Monitoring Well, Deep Blank Casing: Drilling Method: Hollow Stem Auger/Air Rotary type: PVC dia: 2.00in fm: —1.8' to: 90.00' Remarks: borehole 12' to 30', 10* to 85.5, 6' to 102' Screens: type: Slotted size: 0.010india: 2.00in fm: 90.00' to:100.00, Annular fill: type: Grout fm: 0.00' to: 80.00' type: Betonite fm: 80.00' to: 88.00' type: Sand Pack(generic) fm: 88.00' to:102.00' Well Construction Z ppCn 3� o Material Description > L a > d E 3 a t d c c> 520 70 510 80 500 80ROW = 6' AT 85.5' 90 490 100 480 110 470 Page 2 of 2 0 0 0 0 s I A 0 0 0 In 0 0 0 0 11 Project Number. E091-014 Site Id: DMW-02A Delta A/m/Environmental Project Name: YORK ROAD LANDFILL Location: YORK ROAD LANDFILL, CHARLOTTE, NC A Consultants, Inc. Contractor. GEOLOGICAL ExPLOR. Elevation: 595.51' Consulting Firm: Delta Datum: Mean Sea Level Logged By: Measuring Point:595.51' Date(s):05/14/01 — 05/20/01 Conductor Casing: type: Steel dia: 6.00in fm: 0.00' to: 29.00' Purpose: Monitoring Well, Intermediate Blank Casing: Drilling Method: Hollow Stem Auger/Air Rotary type: dia: 2.00in fm: —2.0' to: 35.00' Remarks: Borehole 14" to 20', 10" to 29', 6" to 47" Screens: type: Slotted size: 0.010irdia: 2.00in fm: 35.00' to: 47.00' Annular Fill: type: Grout fm: 0.00' to: 27.00' type: Betanite fm: 27.00' to: 33.00' type: Sand Pack(generic) fm: 33.00' to: 47.00' Well Construction v z o 0 o Material Description O a o ca d E G O a a c !n c� M w o cn m > c.D ML BOREHOLE APPROX. 12 Saprolite: Sandy silt. 590 WR Boulder (?); Competent granitic rock encountered between 7' and 9' 10 --- WR Saprolite: Sandy silt with gravel size rock fragments. Rock fragments become more frequent and larger with depth. 580 Partially weathered rock: Pebble to cobble size rock fragments. 20 BR BOREHOLE = 10" Bedrock. 570 30 BOREHOLE = 6" 560 40 550 50 540 Page 1 of 1 E I e 7 I I L=I r_1 8 L. e i Ill I L-1 a r_� Project Number. E091-014 Site Id: DDW-03A D e I t a Project Name: YORK ROAD LANDFILL Location: YORK ROAD LANDFILL, CHARLOTTE, NC Environmental Contractor. GEOLOGICAL EXPLOR. Elevation: 584.70 Consultants, lnc. Consulting Firm: Delta Datum: Mean Sea Level Logged By: Measuring Point:584.70' Dote(s):05/30/01 — 06/01/01 Conductor Casing: type: PVC dia: 6.00in fm: 0,00' to: 85.00' Purpose: Monitoring Well, Deep Blank Casing: Dulling Method: Hollow Stem Auger/Air Rotary type: PVC dia: 2.00in fm: —1.8' to:118.00' Remarks: borehole 12" to 30', 10' to 85', 6' to 133' Screens: type: Slotted size: 0.010irdia: 2.DOin fm: 118.00' to:133.00' Annular Fill: type: Grout fm: 0.00' to: 106.00' type: Betonite fm: 106.00' to:115.00' 1 type: Sand Pack(generic) fm: 115.00' to:133.00' Well Construction z Material Description o o a; o cl a N MP. EL. 584.7 w CDo�'c cn m > co`� BOREHOLE = 12 Alluvium: sandy silt, brown to dark brown. 580 10 J CL Alluvium: silty Clay, Brown to dark brown. 570 20 SP Alluvium: Sand, well sorted, greenish gray, medium to fine grained. 560 30 — — — BR BOREHOLE = 10" Bedrock: Phoneritic, felsic, igneous rock, granitic in composition. 550 40 540 50 530 Page 1 of 3 0 C J I c �r I 0 ro I I I ro Ri Project Number. E091-014 Site Id: DDW-03A Delta 1///,'A' Project Name: YORK ROAD LANDFILL Location: YORK ROAD LANDFILL, CHARLOTTE, NC Contractor. GEOLOGICAL IXPLOR. Elevation: 584.70' Consult ntsEnvironmentolnc. Consulting Firm: Delta Datum: Mean Sea Level Logged By: ` Measuring Point:584.70' Date(s):05/30/01 — 06/01/01 Conductor Casing: type: PVC dia: 6.00in fm: 0.00' to: 85.00' Purpose: Monitoring Well, Deep Blank Casing: Drilling Method: Hollow Stem Auger/Air Rotary type: PVC dia: 2.00in fm: —1.8' to:118.00' Remarks: borehole 12' to 30', 10' to 85, 6' to 133' Screens: type: Slotted size: 0.01 Oirdia: 2.00in fm: 118.00' to:133.00' Annular Fill: type: Grout fm: 0.00' to:106.00' type: Betonite fm: 106.00' to:115.00' Sand Pack(generic) fm: 115.00' to:133.00' Well Construction v z o Material Description > a $ d E o U ; L 0 t a U cN� W O � IN m > C� 520 70 510 80 500 BOREHOLE = 6" 90 490 100 480 110 470 Page 2 of 3 0 �I 0- 11 in In B 0 e 11 Project Number. E091-014 . Site Id: DDW-03A Delta Project Name: YORK ROAD LANDFILL Location: YORK ROAD LANDFILL, CHARLOTTE, NC Environ onsultontstc Inc. Contractor. GEOLOGICAL EXPLOR. Elevation: 584.70' Consulting Firm: Delta Datum: Mean Sea Level Logged By: Measuring Point:584.70' Date(s):05/30/01 — 06/01/01 Conductor Casing: type: PVC dia: 6.00in fm: 0.00' to: 85.00' Purpose: Monitoring Well, Deep Blank Casing: Dulling Method: Hollow Stem Auger/Air Rotary type: PVC dia: 2.00in fm: —1.8' to:118.00' Remarks: borehole 12" to 30', 10' to 85', 6' to 133' Screens: type: Slotted size: 0.010india: 2.00in fm: 118.00' to: 133.00' Annular Fill: type: Grout fm: 0.00' to: 106.00' type: Betonite fm:106.00' to: 115.00' type: Sand Pack(generic) fm:115.00' to:133.00' Well Construction z -0-3 o Material Description > n > c�i d E ; a L o C-3 460 130 450 140 440 150 I l 430 . 160 420 \ 170 410 Page 3 of 3 di it I do 0 0 do P 11 0 I Project Number: E091-014 Site Id: DMW-02B 1////De I t a Project Name: YORK ROAD LANDFILL Location: YORK ROAD LANDFILL, CHARLOTTE, NC Environmental AConsultants, Inc. Contractor: GEOLOGICAL EXPLOR. Elevation: 595.20'. Consulting Firm: Delta Datum: Mean Sea Level Logged By: Measuring Point:595.20' Date(s):05/16/01 — 05/18/01 Conductor Casing: type: PVC dia: 4.00in fm: 0.00' to: 60.00' Purpose: Monitoring Well, Deep Blank Casing: Drilling Method: Hollow Stem Auger/Air Rotary type: PVC dia: 2.00in fm: —1.7' to: 74.50' Remarks: borehole 16" to 13', 10" to 23', 6" to 60', 3" Screens: core to 84.5' type: Slotted size: 0.01 Oindia: 2.00in fm: 74.50' to: 84.50' Annular Fill: type: Grout fm: 0.00' to: 70.00' type: Betonite fm: 70.00' to: 72.50' type: Sand Pack (generic) fm: 72.50' to: 84.50' Well Construction z 0 Material Description C 0 y y 0 v 0 U o a E 3 a o ; MP. EL. 595.2 4, o � o kn m o >rr � ML BOREHOLE APPROX. 16. Soprofite: Brown to dark Brown, sandy silt. 590 10 BR BOREHOLE = 10' 580 Bedrock Granitic intrusive rock, competent. --- BR 20 Weathered zone, Black, fine grained, very triable (easily crushed between fingers). --- BR Granitic intrusivg rock, competent. BOREHOLE = 6 570 30 560 40 550 50 540 Page 1 of 2 I I I I C 71 I C C Project Number: E091-014 Site Id: DMW-028 AAD e I t a Project Name: YORK ROAD LANDFILL Location: YORK ROAD LANDFLL, CHARLOTTE, NC Consultants, tolnc. Contractor: GEOLOGICAL EXPLOR. Elevation: 595.20' Consulting Firm: Delta Datum: Mean Sea Level Logged By: Measuring Point:595.20' Dote(s):05/16/01 — 05/18/01 Conductor Casing: type: PVC dia: 4.00in fm: 0.00' to: 60.00' Purpose: Monitoring Well, Deep Blank Casing: Drilling Method: Hollow Stem Auger/Air Rotary type: PVC dia: 2.00in fm: —1.7' to: 74.50' Remarks: borehole 16" to 13', 10" to 23', 6" to 60', 3" Screens: core to 84.5' type: Slotted size: 0.010india: 2.00in fm: 74.50' to: 84.50' Annular Fill: type: Grout fm: 0.00' to: 70.00' type: Betonite fm: 70.00' to: 72.50' type: Sand Pack (generic) fm: 72.50' to: 84.50' Well Construction � Material Description v d U U 1 adi avi o BOREHOLE Cored from 60 to 84.5' 530 70 520 80 510 90 500 100 490 110 480 Page 2 of 2 A I 0 0 , I 711 0 I L� LFJ a 11 Project Number: E091-014 Site Id: DMW—A Project Name: YORK ROAD LANDFILL Location: YORK ROAD AND TYVOLA, CHARLOTTE, NC ANAC)eltEx Contractor: GEOLOGICAL EXPLOR. Elevation: 684.52' E°"`°°te7m �°�°l'a °`. E-i"'M �o � t—t Consulting Firm: Delta Datum: Mean Sea Level Logged By: MKM Conductor Casing: type: dia:.00in fm:.00' to:.00' Date(s): 11/05/92 — 11/05/92 Purpose: Monitoring Well, Shallow Blank Casing: type: PVC dia: 2.00in fm:.5' to: 25.00' Drilling Method: Hollow Stem Auger Annular Fill: Screens: type: BENTONITE-CEMENT GROUT fm:.50' to: 20.00' type: Slotted size: .01Oin dia: 2.00in fm: 25.00' to: 45.00' type: Bentonite Pellets fm: 20.00' to: 22.00' Remarks: type:20-28 TORPEDO SAND fm:22.00' to:45.00' Well Construction Material Description � O o � o a o V E 3 o Q a MP. EL. 684.52 W N C� N cl� O N O m p C7 V1 MIL SILTY LOAM TOP SOIL, RED -BROWN (CUTTINGS) 680 1 s SILT WITH MICA AND SOME CLAY, PINK -TAN BLACK MINERALIZATION ALONG FRACTURES 10 2 e e SILT WITH MICA AND SOME CLAY, PINK -TAN -BLACK MINERALIZATION ALONG FRACTURE, HIGHLY VARIABLE 670 356 7 SILTY WITH MICA AND FINE SAND, SOME CLAY, HIGHLY VARIABLE COLOR, RED -BROWN -TAN MINERALIZED 20 4 6 E SILT WITH FINE SAND AND MICA, NUMEROUS REMNANT GRAINS, WEATHERED TO SILT, HIGHLY MINERALIZED RED -TAN 660 5 6 6 SILT WITH MICA AND FINE SAND — TAN —GRAY HIGHLY VARIABLE COLOR, NUMEROUS WEATHERED GRAINS 30 6 a i SILT WITH FINE SAND AND MICA, GRAY -GRAY, NUMEROUS WEATHER GRAINS 650 S SILT -TAN -HOMOGENEOUS, SOME FINE SAND Page 1 of 2 I 0 I 0 0 0 L� 11 0 11 0 7 x n Project Number: E091-014 Site Id: DMW—A Project Name: YORK ROAD LANDFILL Location: YORK ROAD AND TYVOLA, CHARLOTTE, NC AAAClelta Contractor: GEOLOGICAL EXPLOR. Elevation: 684.52' `°"`°°'°.'`°f ` °°.1°` Caanolte, W Caro.l1.. ina Consulting Firm: Delta Datum: Mean Sea Level Logged By: MKM Conductor Casing: type: dia:.00in fm:.00' to:.00' Date(s): 11 /05/92 — 11 /05/92 Purpose: Monitoring Well, Shallow Blank Casing: type: PVC dia: 2.00in fm:.5' to: 25.00' Drilling Method: Hollow Stem Auger Annular Fill: Screens: type: BENTONITE—CEMENT GROUT fm:.50' to: 20.00' type: Slotted size: .01Oin dia: 2.00in fm: 25.00' to: 45.00' type: Bentonite Pellets fm: 20.00' to: 22.00' type: 20-28 TORPEDO SAND fm:22.00' to: 45.00' Remarks: Well Construction o o Material Description Z J O a d o oco � co U w o kf � cn m 8 2 2 SILT WITH BLUE GREEN WEATHERED GRAINS, TAN MATRIX, SOME FINE SAND, SLIGHT MINERALIZATION 640 9 ' 5 SILT WITH MICA AND NUMEROUS SAND LAYERS, MANY GREEN WEATHERED GRAINS 50 630 60 620 70 610 Page 2 of 2 0 it 0 I M A it 11 0 A I 0 0 Project Number: E091-014 Site Id: DMW-01 Project Name: YORK ROAD LANDFILL Location: York Road Landfill, Charlotte, NC Aft E)C—Ata Contractor: Hardin &Huber, Inc. Elevation: 626.75' E'nironrnenlol Consultants, Ina. CMrlolte, North Carolina Consulting Firm: Delta Datum: Mean Sea Level Logged By: SSG Conductor Casing: type: dia:.00in fm:.00' to:.00' Date(s):11/03/90 — 11/03/90 Purpose: Monitoring Well, Shallow Blank Casing: type: PVC dia: 2.00in fm: .2' to: 30.00' Drilling Method: Hollow Stem Auger/Air Rotary Annular Fill: Screens: type: BENTONITE—CEMENT GROUT fm:.50' to: 23.00' type: Slotted size: .01Oin dia: 2.00in fm: 30.00' to: 45.00' type: Bentonite Pellets fm: 23.00' to: 25.00' type: 20-28 TORPEDO SAND fm: 25.00' to: 45.00' Remarks: Switched to Air Rotary at 38 feet. Well Construction v o O Material Description C O a� i LJ v o y O y 0 C, y cr� Z O E p 1n 0 O U 3 O co O d _ - U a o C7 o O U � MP. EL. 626.55 bL SILT/CLAY, RED, MICACEOUS, LOW D, LOW PLASTICITY, ORGANICS, I I I I I I I I I I I I I MOTTLED, DRY 1 6 14 0 ppm I I I I I I I I I I I I I I 1s I I I I I I I I I I 620 I I I I I I I I I I I I I I I I I I I SAPROLITE, MED/FINE GRAINED, GRANULAR, BROWN AND WHITE/GRAY 10 BANDED, MICACEOUS, LOW CLAY, LOW D, NO PLASTICITY, NO COHESION, DRY 2 ` ; is 0 ppm SAME AS ABOVE — DRY 610 3 's 0 ppm 20 SAPROLITE SAME AS ABOVE — DRY 4 ; 0 ppm 38 16 SAME AS ABOVE — DRY, PIECES OF FINE GRAINED/DARK IGNEOUS ROCK — POSSIBLY DIKE MATERIAL 600 5 's 1 PPm e 30 SAME AS ABOVE WET/MOIST 6 51 R 7 ppm BEDROCK, GRANITE TEXTURE, 50% BIOTITE/HORNEBLEND, 50% PLAGIOCLASE, LOW TO NO FOLIATION, COARSE GRAINED 590 Page 1 of 2 0 it A fit 0 0 I 0 0 Project Number: E091-014 Site Id: DMW-01 Project Name: YORK ROAD LANDFILL Location: York Road Landfill, Charlotte, NC AAA EDO C-- I t 8L Contractor: Hardin & Huber, Inc. Elevation: 626.75' `,wi, `°It —"' ° he-tte..No h Ce-fi Consulting Firm: Delta Datum: Mean Sea Level Logged By: SSG Conductor Casing: type: dia:.00in fm:.00' to:.00' Date(s): 11/03/90 — 11/03/90 Purpose: Monitoring Well, Shallow Blank Casing: type: PVC dia: 2.00in fm: .2' to: 30.00' Drilling Method: Hollow Stem Auger/Air Rotary Annular Fill: Screens: type: BENTONITE—CEMENT GROUT fm:.50' to: 23.00' type: Slotted size:.010in dia: 2.00in fm: 30.00' to: 45.00' type: Bentonite Pellets fm: 23.00' to: 25.00' Remarks: Switched to Air Rotary at 38 feet. type: 20-28 TORPEDO SAND fm: 25.00' to: 45.00' Well Construction Material Description c U d p C 3 CD p C.)N W C U7 m d - TD—AIR ROTARY BORING AT 45 FEET 580 50 570 60 560 70 550 Page 2 of 2 0, 0 0 0 0 M G x 0 x 0 I 0 Project Number: Site Id: DMW-02 Project Name: YORK ROAD LANDFILL Location: York Road Landfill, Charlotte, NC ANA E elta Contractor: Hardin & Huber, Inc. Elevation: 597.53' `°"`°tt,. North `°°aolina' °` C�°r1oLLe, NOM Carolina Consulting Firm: Delta Datum: Mean Sea Level Logged By: SSG Conductor Casing: type: Carbon Steel dia: 8.00in fm:.00' to:.50' Date(s): 11/03/90 - 11/03/90 Purpose: Monitoring Well, Shallow Blank Casing: type: PVC dia: 2.00in fm:.2' to: 12.00' Drilling Method: Hollow Stem Auger/Air Rotary Annular Fill: Screens: type: BENTONITE-CEMENT GROUT fm:.50' to: 5.00' type: Slotted size: -01Oin dia: 2.00in fm: 12.00' to: 22.00' type: Bentonite Pellets fm: 5.00' to: 7.00' type: 20-28 TORPEDO SAND fm: 7.00' to: 22.00' Remarks: Switched to Air Rotary at 18 feet. Well Construction v o Material Description Z J a) o a) E o 3 a MP. EL. 597.33 U-1 o m ML SILT/CLAY, RED, MICACEOUS, LOW D, LOW PLASTICITY, MOTTLED, DRY/MOIST 5 0 PPM 590 SAPROLITE, MED/FINE GRAINED, GRANULAR, DARK GRAY TO BROWN, COMPOSITIONAL BANDS, LOW D, NO PLASTICITY, DRY 10 2 '7 9 19 0.1 PPm SAME AS ABOVE - FINER GRAINED 3 090 100 ppm 580 51 R BEDROCK, GRANITE TEXTURE, 50% HORNEBLENDE/BIOTITE, 50% PLAGIOCLASE, LOW TO NO FOLIATION, COARSE GRAINED 20 TOTAL DEPTH- AIR ROTARY BORING AT 22 FEET 570 i 30 560 Page 1 of 1 0 0 A 0 M 0 0 0 0 0 0 D Project Number: E091-014 Site Id: DMW-05 Project Name: YORK ROAD LANDFILL Location: York Road Landfill, Charlotte, NC delta An"A. Contractor: Ground Water Protect Elevation: 585.59' North Carolina Chanotle. N C� fi Consulting Firm: Delta Datum: Mean Sea Level Logged By: Rick Powell Conductor Casing: type: dia:.00in fm:.00' to:.00' Date(s):09/06/95 — 09/06/95 Purpose: Monitoring Well, Shallow Blank Casing: type: PVC dia: 2.00in fm: —2.4' to: 5.00' Drilling Method: Hollow Stem Auger Annular Fill: Screens: type: BENTONITE—CEMENT GROUT fm:.00' to: 2.00' type: Slotted size: .01Oin dia_ 2.00in fm: 5.00' to: 20.00' type: Bentonite Pellets fm: 2.00' to: 3.00' Remarks: Soils logged at DDW-02. Field designation is type: 20-28 TORPEDO SAND fm: 3.00' to: 20.00' DMW-05A. Rebar lost in original DMW-05. Well Construction Material Description MP. EL. 587.98 C O � Q > Q O U O U o a UJ O UJ E O 3 O a p o � U C/) U 00: V') CO C7 580 10 570 20 560 30 550 Page 1 of 1 0 0 0 I 0 7 0 I 0 0 Project Number: E091-014 Site Id: DMW-06 AAAE>elta Project Name: YORK ROAD LANDFILL Location: York Road Landfill, Charlotte, NC Contractor: Ground Water Protect Elevation: 582.39' E.A--ld cans hmtl, Ina. chanolla. Now C—lino Consulting Firm: Delta Datum: Mean Sea Level Logged By: Rick Powell Conductor Casing: type: dia:.00in fm:.00' to:.00' Date(s): 09/O1 /95 — 09/01 /95 Purpose: Monitoring Well, Shallow Blank Casing: type: PVC dia: 2.00in fm: —2.4' to: 19.50, Drilling Method: Hollow Stem Auger Annular Fill: Screens: type: BENTONITE—CEMENT GROUT fm:.00' to: 15.00' type: Slotted size: .01Oin dia: 2.00in fm: 19.50' to: 29.50' type: Bentonite Pellets fm: 15.00' to: 17.00' type:20-28 TORPEDO SAND fm: 17.00' to:29.50' Remarks: Well Construction v o W Material Description MP. EL. 584.76 C _ z j O n . 6 ai L Q ' n 3 a - n a N U a� a) o o N SC 580 1 ; BROWN/GRAY CLAYEY FINE SAND WITH ORGANICS. WET TO SATURATED. a 10 2 z WATER POURING FROM SPLIT SPOON. ALTERNATING LAYERS OR GRAY/BROWN 000,SC/CH 3 FAT SILTY CLAY AND GRAY/BROWN CLAYEY FINE TO COARSE SAND. 570 ORGANICS PRESENT, SATURATED, LAST 4" —SP— POORLY SORTED GRAY FINE SAND, LITTLE TO FINE, NONPLASTIC 3 3 SP LIGHT GRAY POORLY SORTED FINE MEDIUM SAND. LITTLE TO NO FINES. 3 20 4 z 3 SP AS ABOVE 560 30 550 Page 1 of 1 a 0 0 0 0 0 0 I 0 0 11 0 0 no Project Number: E091-014 Site Id: DMW-08 Project Nome: YORK ROAD LANDFILL Location: York Road Landfill, Charlotte, NC Aft�elta Gnmlotte, North (,° It"t Chmlott, "" C°"a'"°°I°' °` Contractor: Ground Water Protect Elevation: 670.69' Consulting Firm: Delta Datum: Mean Sea Level Logged By: Rick Powell Conductor Casing: type: dia:.00in fm:.00' to:.00' Date(s):08/28/95 — 08/28/95 Purpose: Monitoring Well, Shallow Blank Casing: type: PVC dia: 2.00in fm:.2' to: 47.00' Drilling Method: Hollow Stem Auger Annular Fill: Screens: type: BENTONITE—CEMENT GROUT fm:.00' to: 43.00' type: Slotted size:.O10in dia: 2.00in fm: 47.00' to: 62.00' type: Bentonite Pellets fm: 43.00' to: 45.00' Remarks: type:20-28 TORPEDO SAND fm:45.00' to: 70.00' Well Construction v o � o Material Description p Z U J O U a 3 a a MP. EL. 670.48 o o o In 670 ML 1 6 TAN/BLACK/WHITE/ORANGISH BROWN FINE SANDY SILT. NONPLASTIC. EXHIBITS RELIC STRUCTURE/FOLIATION, MICACEOUS - MOIST 660 10 2 s 6 6 ML AS ABOVE, NON -PLASTIC, RELIC STRUCTURE 3 55 7 ML AS ABOVE. FOLIATION HAS BEEN ROUGHLY 45 DEGREES FROM HORIZONTAL 6 650 20 4 e 9 ML AS ABOVE 5 ' y 13 ML AS ABOVE 30 6 6 ML 640 4 15 AS ABOVE 7 24 ML AS ABOVE 25 Page 1 of 2 0 0 11 0 0 a a 0 I 0 0 0 I Project Number: E091-014 Site Id: DMW-08 Project Name: YORK ROAD LANDFILL Location: York Road Landfill, Charlotte, NC AAA�elte CnaAolte. Norttl Carolina . No C 1m, Contractor: Ground Water Protect Elevation: 670.69' Consulting Firm: Delta Datum: Mean Sea Level Logged By: Rick Powell Conductor Casing: type: dia:.00in fm:.00' to:.00' Date(s):08/28/95 — 08/28/95 Purpose: Monitoring Well, Shallow Blank Casing: type: PVC dia: 2.00in fm: .2' to: 47.00' Drilling Method: Hollow Stem Auger Annular Fill: Screens: type: BENTONITE—CEMENT GROUT fm:.00' to: 43.00' type: Slotted size:.Ol0in dia: 2.00in fm: 47.00' to: 62.00' type: Bentonite Pellets fm: 43.00' to: 45.00' Remarks: type:20-28 TORPEDO SAND fm:45-00' to:70.00' Well Construction w o Material Description c O z p o J O U a t a > O a E 3 `OQ C /1 U aJ 0 O O V) 630 834 53 RRST 20" AS ABOVE, LAST 4° WHITE TO GRAY, VERY DENSE 9 sz'e/r M AS ABOVE TO PARTIALLY WEATHERED DIORITE(?). DO NOT SEE ANY QUARTZ FRAGMENTS. MOIST 50 620 60 610 70 600 Page 2 of 2 0 A I 0 0 0 1 0 7 11 0 I Project Number: E091-014 Site Id: DDW-01 Project Name: YORK ROAD LANDFILL Location: York Road Landfill, Charlotte, NC AAACoelta E� '. e, ° "L°n `°N°M G°lin. °� H.M °` Ch.,1. Contractor: Ground Water Protect Elevation: 583.36' Consulting Firm: Delta Datum: Mean Sea Level Logged By: John McCrea Conductor Casing: type: PVC dia: 6.00in fm:.00' to: 38.75' Date(s): 09/07/95 — 09/08/95 Purpose: Monitoring Well, Deep Blank Casing: type: PVC dia: 2.00in fm: —2.1' to: 45.00, Drilling Method: Hollow Stem Auger/Air Hammer Annular Fill: Screens: type: BENTONITE—CEMENT GROUT fm:.00' to: 41.00' type: Slotted size: .01Oin dia: 2.00in fm: 45.00' to: 60.00' type: Bentonite Pellets fm: 41.00' to: 43.00' type: 20-28 TORPEDO SAND fm: 43.00' to: 60.00' Remarks: Soils logged at DMW-06. Well Construction Material Description MP. EL, 585.49 C O 6 a) L d 0 W a o 3 O C� L a 2 cr) UN . ML 580 1 ; 9 RED BROWN CLAYEY SILT, FIRM, DRY —MOIST, LOW TO MEDIUM PLASTICITY 10 2 s 4 ppm CL LIGHT GRAY CLAY WITH OXIDIZED ZONES (MOTTLED APPEARANCE) FIRM, MEDIUM PLASTICITY, MOIST 570 3 3 4 ppm CL GRAY SILTY CLAY, AS ABOVE; OVER LIGHT GRAY CLAYEY SAND, WET, 3 MEDIUM GRAINED 20 q ; 2.5 ppm... SP GRAY, FINE —MEDIUM GRAINED SAND, WET 560 5 8 6.2 ppm. SP AS ABOVE OVER PARTIALLY WEATHERED ROCK, MICACEOUS, GRAY/DARK A GREEN, SOME OXIDATION, ONE UNWEATHERED VEIN 30 BEDROCK 550 Page 1 of 2 I a 0 if 0 A- 0 0 0 0 0 J1 Project Number: E091-014 _ Site Id: DDW-01 Project Name: YORK ROAD LANDFILL Location: York Road Landfill, Charlotte, NC Aft�Glta Contractor: Ground Water Protect Elevation: 583.36' `°"'°°°"°`°` C° `°Ii,"' °` Consulting Firm: Delta Datum: Mean Sea Level Logged By: John McCrea Conductor Casing: type: PVC dia: 6.001n fm:.00' to: 38.75' Date(s): 09/07/95 — 09/08/95 Purpose: Monitoring Well, Deep Blank Casing: type: PVC dia: 2.00in fm: —2.1' to: 45.00' Drilling Method: Hollow Stem Auger/Air Hammer Annular Fill: Screens: type: BENTONITE—CEMENT GROUT fm:.00' to: 41.00' type: Slotted size:.01 Oin dia: 2.00in fm: 45.00' to: 60.00' type: Bentonite Pellets fm: 41.00' to: 43.00' type: 20-28 TORPEDO SAND fm: 43.00' to: 60.00' Remarks: Soils logged at DMW-06. Well Construction v o Material Description c -O Z z =o J 0 N d a)O O N E O V1 W 0 Of N m Li CD ZD 540 50 530 60 — —— 520 70 510 Page 2 of 2 0 I I I a 11 J IJ �r 0 0 y Project Number: E091-014 Site Id: DDW-02 Project Name: YORK ROAD LANDFILL Location: York Road Landfill, Charlotte, NC AAAC)elta CnaAotte, NOM Cerdiea , No � C—lino Contractor: Ground Water Protect Elevation: 585.57' Consulting Firm: Delta Datum: Mean Sea Level Logged By: Rick Powell Conductor Casing: type: PVC dia: 6.00in fm:.00' to: 35.00' Dote(s): 09/05/95 — 09/06/95 Purpose: Monitoring Well, Deep Blank Casing: type: PVC dia: 2.00in fm: —2.4' to: 40.00' Drilling Method: Hollow Stem Auger/Air Hammer Annular Fill: Screens: type: BENTONITE—CEMENT GROUT fm:.00' to: 36.00' type: Slotted size:.O10in dia: 2.00in fm: 40.00' to: 55.00' type: Bentonite Pellets fm: 36.00' to: 38.00' Remarks: Switched to Air Hammer at 30 feet. type: 20-28 TORPEDO SAND fm: 38.00' to: 55.00' Well Construction v o Material Description MP. EL. 587.96 z j 0 0 > a O cD Q o 3 O a a p N U j N N O (n O] p > CD (/1 :D SC 580 1 3 BROWN/DARK GRAY CLAYEY FINE SAND 10 2 z SC LIGHT GRAY BROWN CLAYEY FINE SAND, SATURATED 570 3 3 CH TAN/ORANGISH BROWN/LIGHT GRAY FINE SANDY CLAY, HIGH PLASTICITY, SATURATED 20 4 e o a SP TAN/RUST POORLY SORTED FINE TO MEDIUM SAND 560 30 BEDROCK 550 Page 1 of 2 0 0 I 0 0 III I 0 0 Project Number: E091-014 Site Id: DDW-02 AMA,E)elta Project Name: YORK ROAD LANDFILL Location: York Road Landfill, Charlotte, NC E.m,. , North Carolina C'"`aa'e"'d `aC� U° ' °` Contractor: Ground Water Protect Elevation: 585.57' Consulting Firm: Delta Datum: Mean Sea Level Logged By: Rick Powell Conductor Casing: type: PVC dia: 6.001n fm:.00' to: 35.00' Date(s): 09/05/95 — 09/06/95 Purpose: Monitoring Well, Deep Blank Casing: type: PVC dia: 2.00in fm: —2.4' to: 40.00' Drilling Method: Hollow Stem Auger/Air Hammer Annular Fill: Screens: type: BENTONITE—CEMENT GROUT fm:.00' to: 36.00' type: Slotted size:.O10in dia: 2.00in fm: 40.00' to: 55.00' type: Bentonite Pellets fm: 36.00' to: 38.00' Remarks: Switched to Air Hammer at 30 feet. type: 20-28 TORPEDO SAND fm: 38.00' to: 55.00' Well Construction Material Description � w y U o a Lj c2 o > s a N > N o E 3 O a p s CL o to N w o Q:: cn m > c� 540 50 530 60 520 70 510 Page 2 of 2 0 0 0 I 0 x I 7 x 0 Project Number: E091-014 Site Id: DDW-03 Project Name: YORK ROAD LANDFILL Location: York Road Landfill, Charlotte, NC AAAE:)elta Entirorxnenlal ConsAlanle, Inc., Chor,olle, Nodh Carolina Contractor: Ground Water Protect Elevation: 582.72' Consulting Firm: Delta Datum: Mean Sea Level Logged By: Rick Powell Conductor Casing: type: PVC dia: 6.00in fm:.00' to: 40.00' Date(s): 09/05/95 — 09/05/95 Purpose: Monitoring Well, Deep Blank Casing: type: PVC dia: 2.00in fm: —2.9' to: 46.00' Drilling Method: Hollow Stem Auger/Air Hammer Annular Fill: Screens: type: BENTONITE—CEMENT GROUT fm:.00' to: 41.00' type: Slotted size: .010in dia: 2.00in fm: 46.00' to: 61.00' type: Bentonite Pellets fm: 41.00' to: 43.00' Remarks: SOILS LOGGED AT DMW-06 type: 20-28 TORPEDO SAND fm: 43.00' to: 61.00' Well Construction MP. EL. 585.59 Material Description c z � J o o O a0i a o O O p a V)a�i V) EJ C) Of V) O] > C7 _—D 580 10 570 20 560 30 AUGER REFUSAL AT 30' 550 Page 1 of 2 0 0 0 0 0 0 rol 0 0 0 0 0 A Project Number: E091-014 Site Id: DDW-03 Project Name: YORK ROAD LANDFILL Location: York Road Landfill, Charlotte, NC Aft [D 4--- 1 t SL Contractor: Ground Water Protect Elevation: 582.72' D"imCah,tt N, `C—fi `9' le, NOM Colofi 110 Consulting Firm: Delta Datum: Mean Sea Level Logged By: Rick Powell Conductor Casing: type: PVC dia: 6.00in fm:.00' to: 40.00' Date(s): 09/05/95 — 09/05/95. Purpose: Monitoring Well, Deep Blank Casing: type: PVC dia: 2.00in fm: —2.9' to: 46.00' Drilling Method: Hollow Stem Auger/Air Hammer Annular Fill: Screens: type: BENTONITE—CEMENT GROUT fm:.00' to: 41.00' type: Slotted size:.010in dia: 2.00in fm: 46.00' to: 61.00' type: Bentonite Pellets fm: 41.00' to: 43.00' Remarks: SOILS LOGGED AT DMW-06 type: 20-28 TORPEDO SAND fm: 43.00' to: 61.00' Well Construction v d o Material Description o _ w z o= U J u v o U o Q> L a aU > o (U E o 3 0 a 0 (n w o V) 540 50 530 60 520 70 510 Page 2 of 2 0 Z W 0 J OSW) 1333 NI NOLLVA313 O O O O O O O O O O O O O O O O O rn m I, to L to N O M O I" co 0 O 4 LO LO cA to to U) U) u7 LO d' .0h � It UJ Q o�p.:l M O 0 I ` 0 0 e p O 4 r 13 ! 0 > O w r....O a❑�`- of c� LO, O ^. ir O 0 _ . L a►_ aQo . w .' I . N U O Q O 1 L off, . Z O � O e �nr `r 7Ci_ O H= O W Q g O I Q ' z v D Z LLJ g p <. u , O U � 0 `V � n - U O O � O / � Z Q V) E J� O U Z Z .. 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I lz- 0 ui _ 7 ' . °' 121 1� '�' �.. _ QN _ W��- W o_ O 0 0 0 o O O O O o o O 0 0 0 0 o O) CO I' (0 0 't K) N O 0) CO n cD m (O CO to Ln 0 to LO U) to m In Ln d O O N W z 0 0) Q •- Q W N Z OLLJ a o z 0 O ,p U rn w W 0 Q U 0 Q w z J_ W cl O C9 Z Q � U � U w U J Q O O p Cl. o � 0 N w V W z o a W m W O 0 N w Q z � m Y O U O U Z O W F-- m W 0 0 J w W z W O Z m O Of H I,- z Z 0 Z w Q 0� Z zQ g =. 0 ~ W J m LLI F- w O O w Z 0 °d a❑ i a m Z Z —j O O H L) _j U V) _ V) Z V)Z O w J Z U Q O w C) O w Q W O 2 F 0 v O C c E {0 c_ O �7 C W U APPENDIX C Sample Field Sampling Sheets Date! 3/2120Z3 Site: Farmer York Road Landfill Well ill DDu'-0t 71mc � f 4u4 1 na� Water Level in UTDC) 4 t Tatal Deptlt [R U1.0c) 60'IOC` 1'UII I}eploycd Y PI)II l9nllom Deplh (ft BTOC} [ J Well Candfalon Notes �� cr � brOut� lc�c•!�- ❑DW-OtA : IG , 100 Y 11 S5DDY. Y-0 � bs•Gk�. NQQiGG�?C•� 61 Y Sq EE rl Y ,��a•08133 DDW-05 50 16D toGk ,w►S5s1 DDW-06 rTy �- r t• 72 03 !1 ° DMW-ol 053 ?, ti 45 fY; Y DhiW 0x 100 C 15, ' ' 22 I"�: Y �� i 1 �� DMW-M Im 1.¢5 47 141 Y ys r•► 1oriL b��; Qe.Z Gfr,CYt� DMW-02B 84-5 1t Y VD V` 51� 6 r�.Sti J bCOY �t I DMW-05 y _1�' jQ� 1 1 11 �--j 1 i 20 I� Y yn v 1OCJ� bi'd 1 SG4L afe twjii� ruC6 1; b DM W-06 l � tc). 3 29-5 � 31 Y .QG DMW.08 1� y� 5ita d } 62 fV� Y V�Ji+� DMW-09 11O 20 DMW-A IvQ �� • f.� g 45 f Y DMW-f3 YRW-06A 1 S-+� 27.9 �a� r 1 �C,� YRW-07 ` •(J 73-08 lag YAW-mc 16.5 i-A Y lr 1� 1169%ru% IocAL; YRW-118 ! _ 20 125 At Date:3/28/23 Site: Former York Road Landfill Conditions: Partly cloud morning, sunny in afternoon 60-70s°F Field Personnel: Nick Hotzelt Well ID Time Water Level (itBTOC) Confirm PDB>2 ft Below Water Table Tem C p � ) pH (s.o.) Spec. Conductivity (VS/cm) Comments DDW-01 13:00 7.18 Yes 20.5 6.72 1,092 DDW-01A 13:10 643 Yes 19.7 6.86 1,010 Sulfur odor; little black in water DDW-02 12:25 12.06 Yes 20.6 5.99 1,279 DDW-03 I1:10 10.38 Yes 18.8 6.40 2,236 Duplicate sample collected concurrently with DDW-03 DDW-03A I1:00 1.02 Yes 18.8 7.91 1,549 Sulfur odor; little black in water DMW-01 10:25 30.46 Yes 18.2 5.80 767 DMW-02 16:15 6.35 Yes 20.8 7.36 920 DMW-02A 16:35 0.51 Yes 18.8 12.26 5,925 DMW-02B 16:45 5.82 Yes 18.0 7.36 823 DMW-05 12:35 11.61 - 1 ft below water table 19.5 6.40 1,897 DMW-06 11:20 10.35 Yes 18.8 6.12 2,177 DMW-08 1000 56.33 - 1 ft below water table 19.6 6.45 274.4 DMW-A 8:45 40.30 Yes 18.1 6.26 354.5 YRW-10C 13:45 13.68 Yes 20.2 6.35 1,372 Comments: Calibrate YSI at 8:15am prior to sampling. VOCs, 1,4-dioxane, and field parameters sampled from the lower passive diffusion bag, and RCRA metals collected from upper passive diffusion bag. Field blank collected at 17:05 using water used to fill passive diffusion bags. EON Products DI Water ASTM D1193 Type 1 Order #FSW 110 Lot #L2214. Date: Site: Former York Road Landfill Conditions: Partly cloud morning. sunnv in afternoon 60-70s°F Field Personnel: Nick Hotzelt Well ID Time Temp (*C) pH (s.u.) Spec. Conductivity (µS/em) Dissolved Oxygen (mg/L) ORP (mV) Comments NT-1 15:20 18.4 7.12 224.7 6.11 -12.8 Water in this location more stagnant than other locations. Organic matter present. NT-2 15:00 17.9 7.02 200.2 6.87 5.7 SC-1 15:30 18.9 7.88 752 8.22 -4.3 SC-2 11:55 18.8 7.48 740 7.13 -13.9 ST-1 1205 18.3 7.50 620 8.46 -55.6 ST-3 9:20 16.0 7.36 233.1 6.93 35.7 Comments: APPENDIX D Sample Chain of Custody 01%oi CHAIN OF CUSTODY mawAGE 1 OF 'ol SGS North Ameriea Inc. - Scottwp rr m. vjz�- ffirblln Project Information Requested Analysis I see TEST CODE sh.#Q Matrix Codes �� FBI.. _ ■ ■ all _� = Cmm,,ml-B—R—lW-QCSummary iTJ r Lam_ .. ■ ■... .-: Copy AEHSA Q-002-0-FORM-Scott-St.—COC-FINAL httpalwww sgsscom/en/terms-and-condition& FC3795: Chain of Custody Page 1 of 3 N L SGS122 of 215 FC3795 00 all CHAIN OF CUSTODY 17COSW,45GEAQ OF a SNorth America Inc. - Scott 500 Ambassador Caffery Parkway, Scott, LA 70583 TEL. 337.237,4775 FAX: 33T237.7838 W W W.9g9.COmlehSUSa r-Bnt:x»apxngp 0 Crolro ��� 41 cs puote ro s Job p Client) Reporting Information proact Information Re uested Ana Vsls see TEST CODE sheet Matrix Codes Campany Name GeoS neat Cats l�wniS Project Name(('. ♦elf \� 1 ,. A /y'�� 1 {�i J• L+ mil` > \ 1' n �Vj(/ •' J O Q S O Y R ff]] tTj ������777rrr 'T L1`) � � (, p t• H o DW-Drinking Water GW -Ground Water SWn Wse wafer so -Soil 5L-Sludge SED-Sediment 00b Oil O-Otherir MR-oiir SOL- Otllar Solid FBW FieN Blank P ERR- menl8rk Re- - Rinse Blank TB -Trip Blank BnRgl AdW0.0 i 0 Sr f`ne 5t \v Swpl (o LJ T egnnammmanan iralBemnlrmmN. o C y 9ote Auc C, WWI City SMm C NC comm�ny ASnM Prolael Cdnlacl E-mat CA.11Q P(.1.GR Gf S/ u` 1 l� rr7 1 1 x-� 5lreet Aderesa P^M1ole[Ns y1,9 1 • 3� — CIIImt PurcDase Orders Cry Slate Zip Sampler(,) Names Plmn, () �j 3 �s�'Qj ) agar Proect Man qq !"A xr�,S,.l\a ,Atmndom m Field ID! Point of Collection an mberarpreaervaaeaNee C—P 1, pale Ti­ sampled By Malr. b-4 a °Ne $ 0 6 w LAB USE ONLY W- 3ja8 33 S INAH 6w (o \ X I x x X ` W- Oc 6w I i I I I I VI x NY- 1 I i 5ao 1 sw I I I I I I I XIx u "T- a sW I I I I I X I x . sw I I III x I x x - a sw x x 1 ST - ap ;W a s�-3 as sue+ x x z� Y t b.� 1a05ffTT x x xi I - 1L Ask v k X Turnaround Time I Businesstl ,) Data Deliverable Information I Com ent,l Special Instructions 54s1andara lg Buslness Days Appl—d BY(SCS 11): 11-: 5 Business Days RUSH �4Business Days RUSH 3 Business Days RUSH 3 Business Days RUSH 1 Business Day EMERGENCY Other Ems and &Rush TlAdamuvallehbvll ulrmadW i TAT C111emml"A"(Leve11) TRRP Q Commercial "B" (Leve12) Q RECAP 0 FULLTI (Level 3-4) 0 Slate Forms REDT1 ILeve13e9) 0 EDD Formal Q Commercial "C" 0 Omar Commercial "A"=Resuit'Only, Commercial "B' = Results OC Summary iiOmr1lgKIM'C'= Results♦ Ce Smeary + Padial Row Uels Note: Sample inventory iS verified upon receipt in the Laboratory ' Smnpbo Custody ..at be dsdullwntad aw each time sem ea than [sn InclGdl ierdalFre X a ay 9a tR OW tine: Z3 Reuel RpanauhMd 6y: p Rellnquisbee ey: 4 DMB/ Im DaM l Tlmo: 2xalintl ay: !� Recelvetl By: .4 ellnqulahed by ngler: 3 q eel (TMr. patens y. 3 elingulsM1e 5 y RdlslTime: slue y 5 c c bw,Sealro ❑Inlact preserved wM1ereapplicaola Onlce CoolarT mp ❑ Nai _ ❑ Absent Therm lo. Copy of EHSA-OAC-W26-0O-F0RMSadll - SO,d,M COC-FINAL http:fl w sgsComlenllerms-and-Conditions. FC3795: Chain of Custody Page 2 of 3 SGS123 of 215 FC3795 APPENDIX E Geophysical Investigation Geo Solutions Ltd. P.O. Box 293 Conway, North Carolina 27820 (252)578-3233 June 25, 2018 Amy Kenwell, P.G. Geosyntec Consultants of NC, PC 1300 S. Mint Street Charlotte, NC 28203 Re: York Landfill Boundary Evaluation Dear Ms. Kenwell: Geo Solutions Limited, Inc. (Geo Solutions) is pleased to submit this report to Geosyntec Consultants of NC, PC (Geosyntec) of a geophysical evaluation conducted the York Landfill located in Charlotte, North Carolina. Background Geosyntec contracted Geo Solutions to complete a geophysical evaluation of the suspected landfill boundary in two areas of the York Landfill located in Charlotte, North Carolina. The two areas that were evaluated area shown on Figures 1 and 2 respectively both of which are delineated in yellow. The location of the area shown on Figure 1 is along the North side of Tryon Street on the property of Harry L. Jones Sr. Golf Course. The location of the area shown on Figure 2 is the Northeastern boundary of the York Landfill at Renaissance Park and Northward onto a school property. The landfill boundary was evaluated in this area. FIGURE 1 1 LEGEND Survev Honndary MULTIFREOUENCY EM GEOPHYSICAL SURVEY York Landfill Charlotla, NC Map Scale Ircl o 1. 0-o Solutions Ltd_ Figure 1. Site map of the area surveyed along Tryon Street located in Charlotte North Carolina. The survey boundary is delineated in yellow. FIGURE 2 7 ` LEGEND server eo��a,ry MULTIFREOUENCY EM GEOPHYSICAL SURVEY York Lanfill Chadolta, NC Map scale lhl •]30 1�.�11I5 Gco Solutions Ltd. Figure 2. Site map of the survey area Northeast of Renaissance Park located in Charlotte North Carolina. The survey boundary is delineated in yellow. Technical Approach Geo Solutions completed all field work on June 1 lth and 12th 2018. The same technical approach was completed for both survey areas. The following is Geo Solutions' technical approach that was completed during the geophysical evaluation to assist Geosyntec with their investigation. 1. An electromagnetic (EM) evaluation was completed using a Geophex Model GEM-2 multifrequency electromagnetic profiler. The EM data was collected on a hand-held data logger that communicated with the GEM-2 unit via Bluetooth. The GEM-2 was connected to a Hemisphere Model A-325 GPS unit which is augmented by the Wide Area Augmentation System (WAAS) and is capable of submeter accuracy that provided real-time location data. The EM profiler was mounted on a custom plastic sled and towed behind a Honda Rancher all -terrain vehicle (ATV) through the open areas of the site and hand carried through the wooded areas. At the survey area at the Northeast Boundary and on the school grounds the EM profile spacing was approximately 3 feet or less. At the survey area along S. Tryon Street, the EM profile spacing was approximately 5-10 feet or less through most of the surveyed area except where thick areas of vegetation were encountered. 2. Once adequate survey coverage was achieved, the EM field data were post -processed to merge the GPS and EM data into a comma separated variable (CSV) file that was then transferred to a laptop computer. These data were then processed using an inversion program to calculate the apparent conductivity and in -phase values for each EM frequency collected (1470Hz, 4110 Hz, 9810 Hz, 32,190 Hz, 60000 Hz, and 90030 Hz). Typically, the in -phase data (sometimes referred to as the metal detection mode) is more representative of surficial and buried metallic materials whereas the apparent conductivity is more representative of non- metallic conductive surficial and buried materials. By evaluating both the in -phase and apparent conductivity response the horizontal extents of the buried landfill materials can be characterized. 3. Geo Solutions compiled site maps showing the EM results. The results show the apparent conductivity and in -phase values for the surveyed areas. From this the suspected landfill was evaluated. 4. Photographs of the site were collected and can be viewed on Appendix A for Tryon Street survey and Appendix B for the School Property survey. Results Electromagnetic Survey along Tryon Street at the Suspected Landfill Boundary Figure 3 displays the EM profiles collected across the site. Here, the green dotted lines indicate the location of each multifrequency EM data point collected. EM profiles for this area were run roughly Northwest/Southeast to attempt to survey the boundary of the landfill. All the frequencies were evaluated and the 9810 Hz data was chosen to create figures for this report because it appeared to provide a uniform representation of the overall data base in comparison to the other 6 frequencies. Figure 4 displays the results of the 9810 Hz apparent conductivity data across the surveyed area. Here, the orange and red hues indicate areas of surficial and buried conductive materials while the green hues indicate background site conditions. Based on the results of the 9810 Hz apparent conductivity there appears to be a separation between the landfill and Tryon Street. Moreover, there is a large change in topography North of Tryon Street which corresponds to the elevated apparent conductivity values (Appendix A, Photograph 3). However, there is an area at the southwestern boundary of the landfill that approaches Tryon Street. Here, the apparent conductivity values are slightly elevated above background site conditions. Also, shown on Figure 4 is an area of elevated conductivity which is South and West of the landfill. Here, the presence of scattered debris and a culvert pipe were observed. There is an area of elevated apparent conductivity southeast of the landfill boundary near Tryon Street. This area is delineated on Figure 4. Figure 5 displays the results of the 9810 Hz in -phase data. The in -phase mode was much less responsive than the apparent conductivity. This is typical of municipal landfills and indicates that the composition of the buried waste in this area is mainly household garbage rather than abundant buried metallic materials. Figure 6 is a composite map of both the apparent conductivity and in -phase results. Here, the estimated landfill boundary has been delineated. Coordinates from twenty-nine points along the estimated landfill boundary have been tabulated in Table 1 reported in NC State Plane (ft) NAD 1983. Electromagnetic Survey at Northeastern Boundary of Renaissance Park and School Grounds Figure 7 displays the EM profiles collected across the Northeastern boundary of Renaissance Park and extending onto the school property. Here, the green dotted lines indicate the location of each multifrequency EM data point collected. All the frequencies were evaluated and the 9810 Hz data was chosen to create figures for this report because it appeared to provide a uniform representation of the overall data base in comparison to the other 6 frequencies. Figure 8 displays the results of the 9810 Hz apparent conductivity data across the surveyed area. Here, the orange and red hues indicate areas of surficial and buried conductive materials while the green hues indicate background site conditions. The survey area included the alignment of the methane collection system which includes pipes, wells, protective well covers, and a trench collection system. The position of this system is pointed out on Figure 8. This subsurface and surface infrastructure created an elevated apparent conductivity response along this area however, it is not related to buried waste materials. The landfill boundary was detected south of the methane collection system near Renaissance Park. Here, an abrupt change in apparent conductivity was observed which marks the landfill boundary. This would suggest that the buried waste does not extend past the methane collection trench. There are areas of elevated conductivity that can be observed in the apparent conductivity data on the school property. It appears that the subgrade material beneath the asphalt both within the recess areas and parking lots is very conductive. It is not likely that this is related to the York Landfill but rather the material type that was used during construction of the school property. The area south of the asphalted surface within the recess area is slightly elevated in apparent conductivity. The apparent conductivity response is much weaker here as compared to the landfill observed at Renaissance Park and is not thought to be related to buried waste materials. There was interference from the school building and outdoor tables in the recess area. This interference did not affect the integrity of the apparent conductivity evaluation (Appendix B, Photograph 3). Figure 9 displays the results of the 9810 Hz in -phase data. A very similar pattern to the apparent conductivity data was observed in the 9810 Hz in -phase data. Along the methane collection system metallic and non-metallic materials area present. The protective covers along the collection system are composed of metal and therefore have an elevated in -phase response. The asphalt areas at the school property have an elevated in -phase response. Two steel pipes that run from the school beneath the recess area were detected during the survey. There was interference from the School building and outdoor tables in the recess area. This interference did not affect the integrity of the in -phase evaluation. Conclusions Electromagnetic Survey along Tryon Street at the Suspected Landfill BoundarX • Geo Solutions completed a detailed EM survey of the York Landfill along its boundary near Tryon Street located in Charlotte, North Carolina. • There is a clear separation between the York Landfill and Tryon Street along the majority of the area surveyed. There is a large change in topography North of Tryon Street which corresponds to the elevated apparent conductivity values. • There is an area of elevated conductivity which is South and West of the landfill. Here, the presence of scattered debris and a culvert pipe were observed. • There is an area of elevated apparent conductivity and in -phase response southeast of the landfill boundary near Tryon Street. This elevated EM response may be related to subsurface unities however it is possible that it is related to buried waste materials in this isolated area. Electromagnetic Survey at Northeastern Boundary of Renaissance Park and School Grounds • Geo Solutions completed a detailed EM survey of the York Landfill Northeast of Renaissance Park along a methane collection system and onto a School property located in Charlotte, North Carolina. • The landfill boundary was detected south of the methane collection system near Renaissance Park. The buried waste does not appear to extend past the methane collection system. • The asphalted areas surveyed on the school property was both elevated in apparent conductivity and in -phase values. This likely related to the construction materials beneath the asphalt surfaces and not related to buried waste. • There is an area of slightly elevated apparent conductivity south of the asphalted surface in the recess area at the school property. This is the location of methane detection in the past. The EM response in this area is much weaker than the landfill observed at Renaissance Park and is not likely to be related to buried waste. Geo Solutions is pleased to have been provided this opportunity, please give us a call should you have any questions concerning the above information. Very truly yours, GEO SOLUTIONS LIMITED, INC. 9d""'_"6fzL John DeLoatch, Project Manager Boundary Point Easting (NC State Plane (ft) NAD 83) Northing (NC State Plane (ft) NAD 83) 1 1428979.53 520913.70 2 1429039.96 520888.34 3 1429098.62 520889.46 4 1429124.75 520873.98 5 1429166.89 520911.08 6 1429151.31 520936.69 7 1429198.18 520980.59 8 1429263.56 521029.86 9 1429321.86 521070.08 10 1429389.45 521114.71 11 1429435.56 521120.68 12 1429486.89 521157.59 13 1429527.70 521185.51 14 1429541.31 521233.53 15 1429591.52 521271.62 16 1429628.97 521304.20 17 1429648.05 521338.31 18 1429694.51 521361.52 19 1429712.65 521406.00 20 1429757.09 521443.05 21 1429798.13 521482.47 22 1429849.23 521507.88 23 1429886.70 521541.62 24 1429924.24 521578.81 25 1429964.13 521618.25 26 1430018.02 521667.76 27 1430061.28 521703.68 281 1430118.641 521754.27 291 1430163.451 521809.70 Table 1. Boundary Coordinates of York Landfill Near Tryon Street. '. ' 4 FIGURE 1 LEGEND Survey Boundary MULTIFREQUENCY EM GEOPHYSICAL SURVEY York Landfill Charlotte, NC Map Scale (ft) ONE 0 200 400 600 1 " = 200' Geo Solutions Ltd. FIGURE 2 LEGEND Survey Boundary MULTIFREQUENCY EM GEOPHYSICAL SURVEY York Landfill Charlotte, NC 0 115 230 1" =115' Geo Solutions Lt . d 4� FIGURE 3 LEGEND Indicates Location of MFEM Survey Point MULTIFREQUENCY EM GEOPHYSICAL SURVEY York Landfill Charlotte, NC Map Scale (ft) ONE 0 200 400 600 1 " = 200' Geo Solutions Ltd. FIGURE 4 4 LEGEND Apparent Conductivity Data 9810 Hz 1000 180 - 155 130 105 80 55 30 5 -20 -45 -70 -95 -120 -145 -170 1-195 — — — — — — — Area of Bevated Conductivity 4 MULTIFREQUENCY EM GEOPHYSICAL SURVEY York Landfill Charlotte, NC Map Scale (ft) ow- 0 200 400 600 1 " = 200' Geo Solutions Lt . d FIGURE 5 t , , , Area of 8 evated ' In -phase Fbspom LEGEND In -Phase Data 9810 Hz 100000 7200 6200 5200 *' 4200 3200 2200 _ = 1200 200 -800 -1800 -2800 -3800 -4800 ~� -5800 -6800 -7800 _ � R — — — — — Area of Bevated in -phase Response 4 MULTIFREQUENCY EM GEOPHYSICAL SURVEY York Landfill Charlotte, NC Map Scale (ft) y - .., 1 " = 200' 000 S }4 Geo Solutions Ltd. FIGURE 6 LEGEND Composite Data Outline of Suspected Landfill "- r " .. 4 Area of 8 evated ki 1. �L parent CAndAt- uctivit �400x W-— Estimated Landfill Boundary - - - - - - - Area of Bevated Conductivity MULTIFREQUENCY EM GEOPHYSICAL SURVEY York Landfill Charlotte, NC Map Scale (ft) NEU- 0 60 120 180 1 " = 200' Geo Solutions Lt . d FIGURE 7 LEGEND Indicates Location of MFEM Survey Point MULTIFREQUENCY EM GEOPHYSICAL SURVEY York Landfill Charlotte, NC Map Scal a (ft ) 0 115 230 1" =115' Geo Solutions Lt . d 4� evated Conductivit �'n r r Tables Bevated Conductivity X h FIGURE 8 LEGEND Apparent Conductivity Data 9810 Hz �1000 370 330 290 250 210 170 130 90 50 10 -30 -70 -110 -150 -190 -230 -270 -310 -350 -390 MULTIFREQUENCY EM GEOPHYSICAL SURVEY York Landfill Charlotte, NC Map Scal a (ft ) 0 115 230 1" =115' Geo Solutions Lt . d 4� V Bevated In -phase t Response creel Ripes Bevated In -phase - Response FIGURE 9 LEGEND In -Phase Data 9810 Hz 100000 14800 13200 11600 10000 8400 6800 5200 3600 2000 400 -1200 -2800 -4400 -6000 -7600 -9200 -10800 -12400 -14000 -15600 MULTIFREQUENCY EM GEOPHYSICAL SURVEY York Landfill Charlotte, NC Map Scal a (ft ) 0 115 230 1" =115' Geo Solutions Lt . d 4� 3� P iotograph 2. Lookl E r� so .r,... r ate^. rr� h,i•- _O' - - •�C. -. •fir , t LANDFI l_L N.A 901 LS • ` .. 'try _ - - ' S saw r ■ NI • �kr -' ;•- - - - - . - _ --ter' -�• JF Y lot - oil A -JAM _ r K:\_PROJECTS\C\CITY OF CHARLOTTEWORK ROAD LANDFILL\FIGURES\GC5699B.01\GC5699B.01 F001.DWG (25 October 2017) mfabrizio HMO � SD-01 6 SD-02 �. SD-03 04 BLP-18 O BLP-17�� BSB-2 O �o . , BLP-19 BLP-16; ' LP-20 BLP-8 O BLP-15 0 ; L P-21, BLP-1 4 BLP-3 0 BS13-1 BLP-22 O IsSD-28 O, BLP-14 PC-01 BSB-3 SD-30 LP-2 SD-17 SD-27 ' BLP-130 -Q SD-26 OBLP- OBLP-4 SD p P fir._ BLP-23 SD-25 SQ'19 j. SD-06 SD-05 PC-05 SD-24 LP-5 SD-21` **� co�O SD-22 SD-20 OBLP-12 SD-42 BLP-24 BLIj-1 OBLP 6 SD- O` SD-23 �LP-10 O BLP-11 SQ-14 - �B&P-25 O SD-15 ' LP-26 BSB-5 BSB-4 O r �y. �;;- . O SD-16 BLP 30 ► (� Jt r `.; SLP-10 , � O' `BLP-29 BLP-27 O r �LP-7 - SD-12 O BLP-28 O LP-9 SLP-6 a O SD-11 +.;;. D-13 SLP-5 O G O _ # 7 ` i SD-10 �O p F SD-07 ' - O SLP-10 % LEGEND a f APPROXIMATE PROPERTY BOUNDARY = c0� �cQ) o ,SD-09 j ----------I AREA OF SUSPECTED BURIED WASTE -----------1 (NOTE 5) STREAM REFERENCES O LIGHT POLE 1. AERIAL PHOTOGRAPHY OBTAINED FROM NC ONEMAP GEOSPATIAL PORTAL WEB SITE, © DATED 2015. SCORE BOARD 0 200' 400' 2. PROPERTY LINES OBTAINED FROM STORM DRAINS MECKLENBURG COUNTY GIS. SCALE IN FEET LANDFILL GAS MIGRATION CONTROL 3. STREAM LOCATIONS FROM MECKLENBURG COUNTY GIS, NORTH CAROLINA OPEN SYSTEM BUILDING (APPROXIMATE) RENAISSANCE PARK MAPPING WEBSITE, 20141014, CREEKS AND LFG MIGRATION CONTROL SYSTEM STREAMS. SELECTED SITE FEATURES EXTRACTION WELL 4. CONTOUR DATA FROM LIDAR DATA FORMER YORK ROAD LANDFILL COLLECTED 2012 OBTAINED 24 OCT 2017 CHARLOTTE, NORTH CAROLINA 42+ METHANE MONITORING PROBE FROM MECKLENBURG COUNTY PUBLIC LOCATION OPEN MAPPING WEBSITE. (SU-03R TRENCH SYSTEM EXTRACTION WELL 5. APPROXIMATE WASTE BOUNDARY OBTAINED GeosynteC"' Figure: FROM EM MAPPING PERFORMED BY GEO consultants EW-2 PASSIVE LANDFILL GAS EXTRACTION SOLUTIONS, LTD, OBTAINED 23 OCT 2017 1 WELL AND HISTORICAL DRAWINGS. CHARLOTTE, NC OCTOBER 2017 PRIVILEGED AND CONFIDENTIAL A; a 47 4� i ; ► `� 1! A -Aw W`''¢ ,51 52 0 �D 4 Interfence from Building and Metal Fence R 53 At °0 0 FA 9 a 4 Elevated Conductivit i 19 7 23 2 �CIO aCl) k h i 16 5 26 a a Q) 46- 36 5••t-3.-s�,,,� ! iR }. 0 3334 =;• dh Electromagnetic Survey Renaissance Park - Former York Landfill Prepared for Geosyntec Consultants 32190 Hz EM Response Surveyed: 10/17/2017 200 175 150 E 125 U) 100 E 75 50 U 25 _0 0 U -25 -50 C � N -75 -100 Q Q -125 -150 -175 -200 LEGEND 5 Boudary of A Suspected Buried Landfill Debris Geo Solutions Ltd. Map Scale (ft) 0 225 450 1 "=225' APPENDIX F Receptor Survey Map \\CHARLOTTE-01\DATA\CADD\_PROJECTS\C\CITY OF CHARLOTTE\YORK ROAD LANDFILL\CORRECTIVE ACTION EVALUATION REPORT (GC5699H.01)\DRAWINGS\SHEETS\GC5699F006.DWG (30 August 2023) mjerome w X� 1/0 PNI Rr s;4 �Q�Wi r. JOHN CROSLAND SCHOOL .> <:l .N/ - '`..l w . ` f'. •�. s ljli LANDFILL AREA D \ 1980-1983 ST-3 "� •3= Ak ST-2 ...J GOLF r 1�• CLUBHOUSE �.7 WSW-4 • 5t I LANDFILL AREA E 1983-1984 r LANDFILL AREA C 1972-1976 SC-2 r _r. •� ' x _'" WSW_ ., WSW-3 • 54, JIN,, . ! a 5Q,lk �' „m ms� • tf LEGEND — — APPROXIMATE PROPERTY BOUNDARY STREAM 1500' BUFFER STREAM SAMPLE LOCATION • ABANDONED WATER SUPPLY WELL • NON -DRINKING WATER SUPPLY WELL • INACTIVE WATER SUPPLY WELL LANDFILL AREA F 1984-1986 LANDFILL AREA B 1974-1980 •`fir �1 i � � REFERENCES L LEATHERMAN MAINTENANCE BUILDING i, ire WSW- �`i I� ,' ;t XX On 4 �� 4 A �• N kY'c die^ 1. AERIAL PHOTOGRAPHY OBTAINED FROM NEARMAP, DATE OF PHOTOGRAPHY JANUARY 27, 2023. 2. PROPERTY LINES OBTAINED FROM MECKLENBURG COUNTY GIS. 3. WELL AND MONITORING LOCATIONS APPROXIMATED FROM DRAWINGS PREPARED BY HDR. 4. STREAM LOCATIONS FROM MECKLENBURG COUNTY GIS, NORTH CAROLINA OPEN MAPPING WEBSITE, 20141014, CREEKS AND STREAMS. 5. APPROXIMATE WASTE BOUNDARY OBTAINED FROM EM MAPPING PERFORMED BY GEO SOLUTIONS, LTD, OBTAINED 23 OCT 2017 AND HISTORICAL DRAWINGS. RENAISSANCE MAINTENANCE BUILDING -7N i... rib.. _:r 0 800' 1600' SCALE IN FEET RECEPTOR SURVEY MAP FORMER YORK ROAD LANDFILL CHARLOTTE, NORTH CAROLINA Geosyntec consultants Appendix GeosYntec Consultants of NC, P.C. H CHARLOTTE, NC AUGUST 2023 APPENDIX G Biochlor Model BIOCHLCR Natural Attenuation Decision Support System Version 2.2 Excel2000 TYPE OF CHLORINATED SOLVENT- Ethenes Ethanes 5. GENERAL Q Simulation Time" 1. ADVECTION AModeled Area Width' Seepage Velocity' Vs 193.5 (fttyr) Modeled Area Length' or :Zane 1 Length" Hydraulic Conductivity k (crrysec) :Zane 2 Length* Hydraulic Gradient i (loft) Effective Porosity n ...................................................................................................... 2. DISPERSION Alpha x� 34 (ft) Calc. (Alpha y) / (Alpha x)' (_} 0.1 Alpha x (Alpha a) / (Alpha x)' 1.E-99 H ........................................................................................ I ADSORPTION Retardation Factor' R or Soil Bulk Density, rho 1.5 (kg/L) FractionOrganicCarbon, foc I 1-OE-3 (-) Partition Coefficient Koc PCE 426 (Ukg) 4.20 (-} TCE 130 (Ukg) 1.98 H DCE 125 (Ukg) 1.94 (-} VC 30 (Ukg) 1.22 (-} ETH 302 (Ukg) 3.27 (-} Common R (used in model)' = 1.98 4. BIOTRANSFORMATION -7st order ❑ecay Coefficient' Zone 1 ?� (1/yr) half-life (yrs) Yield PCE TCE LO.3 1..95 0.79 TCE DCE 210 0.74 DCE VC 1.90 0.64 C 6. SOURCE DATA Source Options 25 (yr) 1800 (ft) 750 (ft) 750 (ft) 0 (ft) FYPE: Decaying Single Planar Source Thickness in Sat. Zone" =1 (ft) Y1 Width" (ft) 600 ks" Conc_ (mg.,Q, C1 (Ijyr) PCE .001 0 TCE 004 0 DCE 025 0 VC 003 0 ETH 0 7. FIELD DATA FOR COMPARISON PCE CDnc_ (mg/L) .TCE Conc. (mg/L) JDCE Canc. (mg/L) VC Conc. (mg/L) ETH Canc. (mg/L) Distance from Source Ift) Date Data Collected ...................................................................... Data Input Instructions: > > 5 1. Enter value directly .... or T or 2_ Calculate by filling in gray 0.02 cells. Press Enter, then Cc (To restore formulas, hit 'Restore Formulas" button } Variable' - Data used directly in model_ Test if Biotransformation Natural Attenuation is Occurring 4 Screening Protocol York Road Landfill Run Name C i I_ ---- a t W ZoneL-Zone 1 Vertical Plane Source: ❑etermine Source Well Location and Input Solvent Concentrations View of Plume Looking Dawn Observed Centerline Canc. at Manitoring Wells VC ETH 2.557 F 0.27 0.45 8_ CHOOSE TYPE OF OUTPUT TO SEE: Zone 2 k (1/yr) half-life (yrs) PCE TCE D.Ufla #• f e Restore TCE DCE e.eflfl F i SELF RUN RUN ARRAY DCE4 VC aflfl F CENTERLINE VC � ETH D.000 F _ SEE Paste Unprotect DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mg/L) at Z=0 Distance from Source (ft) TCE No Degradation Biotransformation Field Data from Site J 0 75 150 225 300 375 450 525 600 675 750 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.0044 0.004 0.004 0.003 0.003 0.003 0.002 0.002 0.002 0.002 0.001 -No Degradation/Production 1.000 E. 0.100 c O b 0.010 c d v c 0 0.001 0 Prepare Animation Mon -Sequential 1st Order Decay Well Locations o Field Data from Site 100 200 300 400 500 Distance From Source (ft.) Log Linear 600 700 800 mpui See PCE See TCE See DCE See VC See ETH JTo Array DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mg/L) at Z=0 Distance from Source (ft) VC No Degradation Biotransformation Field Data from Site J 0 75 150 225 300 375 450 525 600 675 750 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.0033 0.003 0.002 0.002 0.002 0.001 0.001 0.001 0.001 0.001 0.001 -No Degradation/Production 1.000 T �. 0.100 c O E c 0.010 m c 0 V 0.001 0 Prepare Animation Mon -Sequential 1st Order Decay Well Locations o Field Data from Site 100 200 300 400 500 Distance From Source (ft.) Log Linear 800 77Kj— 750 600 700 800 See PCE See TCE See DCE See VC See ETH Input J • - —.. J To Array APPENDIX H Groundwater PFAS Analytical Data Summary (Police &Fire Training Academy) Groundwater PFAS Analytical Data Summary Police & Fire Training Academy Charlotte, North Carolina H&H Job No. CLT-701 Screening Criteria NC 2L2 NC PHG3 Sample ID DDW-01 DDW-OlA DDW-02 DDW-03 9/29/2021 10/24/2022 9/29/2021 10/24/2022 10/6/2020 9/29/2021 10/24/2022 11/6/2020 9/30/2021 10/24/2022 Date (ng/1) (ng/1) PFASI Perfluorobutanoic acid (PFBA) 5.2 4.6 15 7.3 170 210 61 340 340 250 5 NS Perfluoropentanoic acid (PFPeA) 3.2 5.3 8.4 4.8 35 43 15 48 50 38 2 NS Perfluorohexanoic acid (PFHxA) 5.9 5.8 12 6.3 84 94 32 150 140 110 2 NS Perfluoroheptanoic acid (PFHpA) 2.0 2.6 3.6 3.4 23 28 10 32 34 22 2 NS Perfluorooctanoic acid (PFOA) 3.2 2.5 6.1 4.3 51 65 23 38 43 28 2 NS Perfluorononanoic acid (PFNA) <0.25 <0.25 <0.25 0.62 J 0.94 J 0.96 J 0.99 J <0.25 <0.26 <0.25 2 NS Perfluorodecanoic acid (PFDA) <0.29 <0.28 <0.28 1.0 J <0.29 <0.29 0.70 J <0.51 <0.29 <0.28 2 NS Perfluoroundecanoic acid (PFUnA) <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.1 <1.0 <1.0 <1.0 2 NS Perfluorododecanoic acid (PFDoA) <0.51 <0.50 <0.50 <0.51 <0.51 <0.51 <0.53 <0.51 <0.52 <0.50 2 NS Perfluorotridecanoic Acid (PFTrDA) <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.3 <1.2 <1.2 <1.2 2 NS Perfluoropentanesulfonic acid (PFPeS) 0.811 <0.27 0.71 J <0.28 NA 8.0 2.9 NA 14 9.3 2 NS Perfluorobutanesulfonic acid (PFBS) 1.11 0.61 J 1.6 J 1.11 14 17 5.0 29 27 14 2 NS Perfluorohexanesulfonic acid (PFHxS) 1.3 J 1.11 2.0 3.5 13 13 4.0 22 24 12 2 NS Perfluoroheptanesulfonic Acid (PFHpS) <0.18 <0.17 <0.17 <1.9 0.55 J <0.17 <0.18 0.86 J 2.5 <0.17 2 NS Perfluorooctanesulfonic acid (PFOS) 4.9 2.5 2.5 9.3 14 18 8.8 22 23 14 2 NS Perfluorononanesulfonic acid (PFNS) <0.34 <0.34 <0.34 <0.34 NA <0.34 <0.36 NA <0.35 <0.34 2 NS Perfluorodecanesulfonic acid (PFDS) <0.30 <0.29 <0.29 <0.30 <0.30 <0.29 <0.31 <0.30 <0.30 <0.29 2 NS Perfluorooctane Sulfonamide (FOSA) <0.91 <0.89 <0.89 <0.91 <0.91 <0.90 <0.95 <0.92 <0.93 <0.90 2 NS N-ethyl perfluorooctanesulfonamidoacetic acid (NEtFOSAA) <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.3 <1.2 <1.2 <1.2 10 NS N-methyl perfluorooctanesulfonamidoacetic acid (NMeFOSAA) <1.1 1.3 J <1.1 <1.1 <1.1 <1.1 <1.2 <1.1 <1.1 1.5 J 10 NS Perfluorotetradecanoic acid (PFTeA) <0.68 <0.66 <0.67 <0.68 <0.67 <0.67 <0.71 <0.68 <0.69 <0.67 2 NS 6:2 FTS <2.3 <2.3 <2.3 7.4 J <2.3 <2.3 <2.4 <2.3 <2.4 <2.3 10 NS 4:2 FTS <0.22 <0.22 <0.22 <0.22 NA <0.22 <0.23 NA <0.23 <0.22 2 NS 8:2 FTS <0.43 <0.42 <0.42 <0.43 <0.42 <0.42 <0.45 <0.43 <0.44 <0.42 10 NS 4,8-Dioxa-3H-perfluorononanoic acid (ADONA) <0.37 <0.36 <0.37 <0.37 NA <0.37 <0.39 NA <0.38 <0.37 2 NS HFPO-DA (GenX) <1.4 <1.4 <1.4 <1.4 NA <1.4 <1.5 NA <1.4 <1.4 4 140 9C1-PF3ONS <0.22 <0.22 <0.22 <0.22 NA <0.22 <0.23 NA <0.23 <0.22 2 NS 11Cl-PF30UdS <0.30 <0.29 <0.29 <0.30 NA <0.29 <0.31 NA <0.30 <0.29 2 NS 10:2 FTS <0.62 <0.61 <0.61 <0.62 NA <0.62 <0.65 NA <0.63 <0.61 2 NS Total PFAS 27.61 26.31 51.91 49.02 405.49 496.96 163.39 681.86 697.50 498.80 NS NS Notes: ng/L = nanograms/Liter (ppt) Bold indicates exceeds groundwater standard. PFAS = Per- and polyfluorinated alkyl substances; A = Not Analyzed; NS = Not Specified; E = Estimated result above calibration range; J - The analyte was positively identified but the value is estimated below the reporting limit ' 10/20, 9/21, & 10/22 samples by Test America for expanded list PFAS via Method 537 (modified). 2NCAC Title 15A, Subchapter 2L Groundwater Standards, effective April 1, 2022; the 2L Groundwater Standard used at this site is the laboratory practical quantitation limit (PQL) for the analyzed PFAS compounds. 3NC PHG = North Carolina Department of Health and Human Services Provisional Health Goal for Drinking Water, July 2017. Table 10 (Page 1 of 2) File: 2022 TablesRI.Asm\Table 10 GW PFAS data (6) Date: 8/23/2023 Hart & Hickman, PC Groundwater PFAS Analytical Data Summary Police & Fire Training Academy Charlotte, North Carolina H&H Job No. CLT-701 Screening Criteria NC 2L2 NC PHG3 Sample ID DDW-03A DMW-02 DMW-05 DMW-06 YRW-09A YRW-IOC 11/6/2020 9/29/2021 10/25/2022 9/30/2021 10/25/2022 10/6/2020 9/29/2021 10/24/2022 11/6/2020 9/30/2021 10/24/2022 9/29/2021 10/24/2022 9/29/2021 10/24/2022 Date (ng/1) (ng/1) PFAS1 Perfluorobutanoic acid (PFBA) 8.9 7.2 8.2 <2.2 2.6 J 170 130 160 260 250 250 4.4 5.8 50 350 E 5 NS Perfluoropentanoic acid (PFPeA) 13 13 14 1.2 J 1.6 J 58 ' 55 67 40 42 41 1.5 J 1.6 J 81 210 2 NS Perfluorohexanoic acid (PFHxA) 17 13 16 1.3 J 1.6 J 75 58 80 120 110 130 2.8 4.0 62 200 2 NS Perfluoroheptanoic acid (PFHpA) 45 47 56 0.58 J 0.73 J 23 19 26 26 27 29 1.0 J 1.11 24 63 2 NS Perfluorooctanoic acid (PFOA) 32 26 30 1.9 1.6 J 49 43 64 32 38 40 1.6 J 1.8 48 95 2 NS Perfluorononanoic acid (PFNA) 5.4 3.9 4.4 0.41 J 0.32 J 0.66 J 0.61 J 0.82 J <0.25 0.28 J <0.26 <0.23 <0.24 0.85 J 0.811 2 NS Perfluorodecanoic acid (PFDA) 11 6.6 7.6 <0.29 <0.28 <0.29 <0.28 <0.26 <0.28 <0.30 <0.29 <0.26 <0.28 <0.27 <0.26 2 NS Perfluoroundecanoic acid (PFUnA) <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.98 <0.91 <1.0 <1.1 <1.0 <0.94 <1.0 <0.96 <0.91 2 NS Perfluorododecanoic acid (PFDoA) 1.4 J 1.11 1.11 <0.52 <0.50 <0.51 <0.49 <0.46 <0.50 <0.53 <0.52 <0.47 <0.50 <0.48 <0.45 2 NS Perfluorotridecanoic Acid (PFTrDA) <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.1 <1.2 <1.2 <1.2 <1.1 <1.2 <1.1 <1.1 2 NS Perfluoropentanesulfonic acid (PFPeS) NA <0.27 0.94 J <0.28 <0.27 NA 3.7 5.9 NA 12 14 0.37 J 0.37 J 5.5 8.9 2 NS Perfluorobutanesulfonic acid (PFBS) 0.28 J <0.18 0.30 J 0.58 J 0.75 J 14 13 17 25 24 26 0.87 J 0.85 J 13 18 2 NS Perfluorohexanesulfonic acid (PFHxS) <0.52 <0.52 <0.53 0.68 J 1.11 14 9.6 14 19 18 23 0.72 J 0.96 J 50 28 2 NS Perfluoroheptanesulfonic Acid (PFHpS) <0.17 <0.17 <0.18 <0.18 <0.17 0.35 J <0.17 0.26 J 0.73 J 1.4 J 1.0 J <0.16 <0.17 <0.17 <0.16 2 NS Perfluorooctanesulfonic acid (PFOS) <0.49 <0.49 <0.50 4.1 1.9 9.6 11 14 20 23 23 0.86 J <0.49 <0.47 4.9 2 NS Perfluorononanesulfonic acid (PFNS) NA <0.34 <0.34 <0.35 <0.34 NA <0.33 <0.31 NA <0.35 <0.35 <0.32 <0.34 <0.32 <0.30 2 NS Perfluorodecanesulfonic acid (PFDS) <0.29 <0.29 <0.30 <0.30 <0.29 <0.30 <0.29 <0.27 <0.29 <0.31 <0.30 <0.27 <0.29 <0.28 <0.26 2 NS Perfluorooctane Sulfonamide (FOSA) <0.89 <0.89 <0.91 <0.92 <0.89 2.3 0.90 J <0.81 <0.90 <0.94 <0.93 <0.84 <0.29 <0.85 <0.81 2 NS N-ethyl perfluorooctanesulfonamidoacetic acid (NEtFOSAA) <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.1 <1.2 <1.2 <1.2 <1.1 <1.2 <1.1 <1.1 10 NS N-methyl perfluorooctanesulfonamidoacetic acid (NMeFOSAA) <1.1 <1.1 <1.1 <1.1 <1.1 <1.1 <1.1 <1.0 <1.1 <1.1 <1.1 <1.0 <1.1 <1.0 <0.99 10 NS Perfluorotetradecanoic acid (PFTeA) <0.66 <0.66 <0.68 <0.68 <0.66 <0.68 <0.65 <0.61 <0.67 <0.70 <0.69 <0.62 <0.66 <0.64 <0.60 2 NS 6:2 FTS <2.3 <2.3 <2.3 <2.3 <2.3 <2.3 <2.2 <2.1 <2.3 <2.4 <2.4 <2.1 <2.3 <2.2 <2.1 10 NS 4:2 FTS NA <0.22 <0.22 <0.22 <0.22 NA <0.21 <0.20 NA <0.23 <0.23 <0.20 <0.22 <0.21 <0.20 2 NS 8:2 FTS <0.42 <0.42 <0.43 <0.43 <0.42 <0.43 <0.41 <0.38 <0.42 <0.44 <0.44 <0.39 <0.42 <0.40 <0.38 10 NS 4,8-Dioxa-3H-perfluorononanoic acid (ADONA) NA <0.36 <0.37 <0.37 <0.36 NA <0.36 <0.33 NA <0.38 <0.38 <0.34 <0.36 <0.35 <0.33 2 NS HFPO-DA (GenX) NA <1.4 <1.4 <1.4 <1.4 NA <1.3 <1.2 NA <1.4 <1.4 <1.3 <1.4 <1.3 <1.2 4 140 9C1-PF30NS NA <0.22 <0.22 <0.22 <0.22 NA <0.21 <0.20 NA <0.23 <0.23 <0.20 <0.22 <0.21 <0.20 2 NS 11C1-PF3OUdS NA <0.29 <0.30 <0.30 <0.29 NA <0.29 <0.27 NA <0.31 <0.30 <0.27 <0.29 <0.28 <0.26 2 NS 10:2 FTS NA <0.61 <0.62 <0.63 <0.61 NA <0.60 <0.56 NA <0.64 <0.63 <0.57 <0.61 <0.58 <0.55 2 NS Total PFAS 133.98 1 117.80 1 138.54 1 10.75 1 12.20 1 415.91 1 343.81 1 448.98 1 542.73 1 545.68 1 577.00 1 14.12 1 16.48 1 334.35 1 978.61 1 NS I NS Notes: ng/L = nanograms/Liter (ppt) Bold indicates exceeds groundwater standard. RB-1 = Equipment rinse blank of PVC bailer PFAS = Per- and polyfluorinated alkyl substances; NA = Not Analyzed; NS = Not Specified; E = Estimated result above calibration range; J - The analyte was positively identified but the value is estimated below the reporting limit ' 10/20, 9/21, & 10/22 samples by Test America for expanded list PFAS via Method 537 (modified). 2NCAC Title 15A, Subchapter 2L Groundwater Standards, effective April 1, 2022; the 2L Groundwater Standard used at this site is the laboratory practical quantitation limit (PQL) for the analyzed PFAS compounds. 3NC PHG = North Carolina Department of Health and Human Services Provisional Health Goal for Drinking Water, July 2017. Table 10 (Page 2 of 2) File: 2022 TablesRl Asm\Table 10 GW PFAS data (8) Date: 8/23/2023 Hart & Hickman, PC