1304_Cabarrus_CharlotteMotorSpeedwayV_MSWLF_LeachateReleaseResults_FID1816861_20230822

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
August 22, 2023
Mike Gurley
Republic Services
5105 Morehead Road
Concord, NC 28027
RE: Project: CMS LANDFILL V
Pace Project No.: 92683146
Dear Mike Gurley:
Enclosed are the analytical results for sample(s) received by the laboratory on July 25, 2023. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Tyriek Hooks
[e-mail]
[phone]
Project Manager
Enclosures
cc: Stoddard Pickrell, Republic Services
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 17

Project: CMS LANDFILL V
Pace Project No.: 92683146
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 17

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CMS LANDFILL V
Pace Project No.: 92683146
Lab ID Sample ID
SAMPLE SUMMARY
Matrix Date Collected Date Received
92683146001 SEDIMENT BASIN Solid 07/25/23 00:00 07/25/23 12:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 17

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: CMS LANDFILL V
Pace Project No.: 92683146
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
92683146001 SEDIMENT BASIN
EPA 8270E
PKS
18
PASI-C
EPA 8260D
SAS
14
PASI-C
EPA 9045D
YEG
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 17

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CMS LANDFILL V
Pace Project No.: 92683146
Lab Sample ID
Method
92683146001
EPA 9045D
SUMMARY OF DETECTION
Client Sample ID
Parameters Result Units Report Limit Analyzed Qualifiers
SEDIMENT BASIN
pH at 25 Degrees C 6.8 Std. Units 0.10 08/18/23 11:33 H3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 17

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: CMS LANDFILL V
Pace Project No.: 92683146
Method: EPA 8270E
Description: 8270E TCLP RVE
Client: Republic Services
Date: August 22, 2023
General Information:
1 sample was analyzed for EPA 8270E by Pace Analytical Services Charlotte. All samples were received in acceptable condition with
any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of
this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
H2: Extraction or preparation conducted outside EPA method holding time.
• SEDIMENT BASIN (Lab ID: 92683146001)
Sample Preparation:
The samples were prepared in accordance with EPA 3510C with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 6 of 17

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: CMS LANDFILL V
Pace Project No.: 92683146
Method: EPA 8260D
Description: 8260D MSV TCLP
Client: Republic Services
Date: August 22, 2023
General Information:
1 sample was analyzed for EPA 8260D by Pace Analytical Services Charlotte. All samples were received in acceptable condition with
any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of
this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
H2: Extraction or preparation conducted outside EPA method holding time.
• SEDIMENT BASIN (Lab ID: 92683146001)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 794927
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92683146001
M1: Matrix spike recovery exceeded QC limits.
• MS (Lab ID: 4118968)
• 1,4-Dichlorobenzene
• Chlorobenzene
• MSD (Lab ID: 4118969)
• 1,4-Dichlorobenzene
• Chlorobenzene
Additional Comments:
Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 17

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: CMS LANDFILL V
Pace Project No.: 92683146
Method: EPA 9045D
Description: 9045 pH Soil
Client: Republic Services
Date: August 22, 2023
General Information:
1 sample was analyzed for EPA 9045D by Pace Analytical Services Asheville. All samples were received in acceptable condition with
any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of
this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
H3: Sample was received or analysis requested beyond the recognized method holding time.
• SEDIMENT BASIN (Lab ID: 92683146001)
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 8 of 17

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: CMS LANDFILL V
Pace Project No.: 92683146
Sample: SEDIMENT BASIN
Lab ID:
92683146001
Collected:
07/25/23 00:00
Received: 07/25/23 12:00 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
8270E TCLP RVE
Analytical
Method: EPA 8270E
Preparation Method:
EPA 3510C
Leachate
Method/Date: EPA 1311; 08/21/23 15:00 Initial pH: 8.36; Final
pH: 5
Pace Analytical
Services
- Charlotte
1,4-Dichlorobenzene
ND
ug/L
50.0
2.1
1
08/22/23 12:50
08/22/23 15:46
106-46-7
H2
2,4-Dinitrotoluene
ND
ug/L
50.0
1.2
1
08/22/23 12:50
08/22/23 15:46
121-14-2
H2
Hexachloro-1,3-butadiene
ND
ug/L
50.0
2.0
1
08/22/23 12:50
08/22/23 15:46
87-68-3
H2
Hexachlorobenzene
ND
ug/L
50.0
1.7
1
08/22/23 12:50
08/22/23 15:46
118-74-1
H2
Hexachloroethane
ND
ug/L
50.0
2.0
1
08/22/23 12:50
08/22/23 15:46
67-72-1
H2
2-Methylphenol(o-Cresol)
ND
ug/L
50.0
1.2
1
08/22/23 12:50
08/22/23 15:46
95-48-7
H2
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
50.0
1.2
1
08/22/23 12:50
08/22/23 15:46
15831-10-4
H2
Nitrobenzene
ND
ug/L
50.0
2.1
1
08/22/23 12:50
08/22/23 15:46
98-95-3
H2
Pentachlorophenol
ND
ug/L
100
2.2
1
08/22/23 12:50
08/22/23 15:46
87-86-5
H2
Pyridine
ND
ug/L
50.0
3.4
1
08/22/23 12:50
08/22/23 15:46
110-86-1
H2
2,4,5-Trichlorophenol
ND
ug/L
50.0
1.4
1
08/22/23 12:50
08/22/23 15:46
95-95-4
H2
2,4,6-Trichlorophenol
ND
ug/L
50.0
1.5
1
08/22/23 12:50
08/22/23 15:46
88-06-2
H2
Surrogates
Nitrobenzene-d5 (S)
136
%
10-138
1
08/22/23 12:50
08/22/23 15:46
4165-60-0
2-Fluorobiphenyl (S)
103
%
10-130
1
08/22/23 12:50
08/22/23 15:46
321-60-8
Terphenyl-dl4 (S)
135
%
19-191
1
08/22/23 12:50
08/22/23 15:46
1718-51-0
Phenol-d6 (S)
57
%
10-130
1
08/22/23 12:50
08/22/23 15:46
13127-88-3
2-Fluorophenol (S)
78
%
10-130
1
08/22/23 12:50
08/22/23 15:46
367-12-4
2,4,6-Tribromophenol (S)
141
%
10-164
1
08/22/23 12:50
08/22/23 15:46
118-79-6
8260D MSV TCLP
Analytical
Method: EPA 8260D
Leachate
Method/Date:
EPA 1311; 08/20/23 12:13
Pace Analytical
Services
- Charlotte
Benzene
ND
ug/L
100
59.8
20
08/21/23 14:37
71-43-2
H2
2-Butanone (MEK)
ND
ug/L
200
158
20
08/21/23 14:37
78-93-3
H2
Carbon tetrachloride
ND
ug/L
100
44.2
20
08/21/23 14:37
56-23-5
H2
Chlorobenzene
ND
ug/L
100
36.0
20
08/21/23 14:37
108-90-7
H2,M1
Chloroform
ND
ug/L
100
56.2
20
08/21/23 14:37
67-66-3
H2
1,4-Dichlorobenzene
ND
ug/L
100
38.2
20
08/21/23 14:37
106-46-7
H2,M1
1,2-Dichloroethane
ND
ug/L
100
26.0
20
08/21/23 14:37
107-06-2
H2
1,1-Dichloroethene
ND
ug/L
100
43.0
20
08/21/23 14:37
75-35-4
H2
Tetrachloroethene
ND
ug/L
100
35.6
20
08/21/23 14:37
127-18-4
H2
Trichloroethene
ND
ug/L
100
37.0
20
08/21/23 14:37
79-01-6
H2
Vinyl chloride
ND
ug/L
100
36.2
20
08/21/23 14:37
75-01-4
H2
Surrogates
1,2-Dichloroethane-d4 (S)
105
%
70-130
20
08/21/23 14:37
17060-07-0
Toluene-d8 (S)
102
%
70-130
20
08/21/23 14:37
2037-26-5
4-Bromofluorobenzene (S)
101
%
70-130
20
08/21/23 14:37
460-00-4
9045 pH Soil
Analytical
Method: EPA 9045D
Pace Analytical
Services
-Asheville
pH at 25 Degrees C
6.8
Std. Units
0.10
0.10
1
08/18/23 11:33
H3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/22/2023 05:06 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 17

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: CMS LANDFILL V
Pace Project No.: 92683146
QC Batch: 794927 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV TCLP
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92683146001
METHOD BLANK: 4118967
Associated Lab Samples: 92683146001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
1,1-Dichloroethene
ug/L
ND
5.0
2.2
08/21/23 12:33
1,2-Dichloroethane
ug/L
ND
5.0
1.3
08/21/23 12:33
1,4-Dichlorobenzene
ug/L
ND
5.0
1.9
08/21/23 12:33
2-Butanone (MEK)
ug/L
ND
10.0
7.9
08/21/23 12:33
Benzene
ug/L
ND
5.0
3.0
08/21/23 12:33
Carbon tetrachloride
ug/L
ND
5.0
2.2
08/21/23 12:33
Chlorobenzene
ug/L
ND
5.0
1.8
08/21/23 12:33
Chloroform
ug/L
ND
5.0
2.8
08/21/23 12:33
Tetrachloroethene
ug/L
ND
5.0
1.8
08/21/23 12:33
Trichloroethene
ug/L
ND
5.0
1.8
08/21/23 12:33
Vinyl chloride
ug/L
ND
5.0
1.8
08/21/23 12:33
1,2-Dichloroethane-d4 (S)
%
103
70-130
08/21/23 12:33
4-Bromofluorobenzene (S)
%
102
70-130
08/21/23 12:33
Toluene-d8 (S)
%
101
70-130
08/21/23 12:33
LABORATORY CONTROL SAMPLE:
Parameter
4118966
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1-Dichloroethene
ug/L
20
19.6
98
70-130
1,2-Dichloroethane
ug/L
20
18.5
92
70-130
1,4-Dichlorobenzene
ug/L
20
19.5
97
70-130
2-Butanone (MEK)
ug/L
40
38.0
95
70-134
Benzene
ug/L
20
19.7
99
70-130
Carbon tetrachloride
ug/L
20
16.8
84
70-130
Chlorobenzene
ug/L
20
19.3
97
70-130
Chloroform
ug/L
20
19.8
99
70-130
Tetrachloroethene
ug/L
20
18.0
90
70-130
Trichloroethene
ug/L
20
18.8
94
70-130
Vinyl chloride
ug/L
20
16.4
82
62-130
1,2-Dichloroethane-d4 (S)
%
97
70-130
4-Bromofluorobenzene (S)
%
103
70-130
Toluene-d8 (S)
%
100
70-130
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/22/2023 05:06 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 17

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: CMS LANDFILL V
Pace Project No.: 92683146
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 4118968
4118969
MS
MSD
92683146001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD
RPD Qual
1,1-Dichloroethene
ug/L
ND
20
20
ND
ND
93
96
70-156
30
1,2-Dichloroethane
ug/L
ND
20
20
ND
ND
105
106
69-143
30
1,4-Dichlorobenzene
ug/L
ND
20
20
51.1J
54.5J
255
273
70-142
30 M1
2-Butanone (MEK)
ug/L
ND
40
40
ND
ND
130
127
60-157
30
Benzene
ug/L
ND
20
20
ND
ND
101
100
70-142
30
Carbon tetrachloride
ug/L
ND
20
20
ND
ND
93
102
70-148
30
Chlorobenzene
ug/L
ND
20
20
40J
40.3J
200
202
70-141
30 M1
Chloroform
ug/L
ND
20
20
ND
ND
100
102
70-148
30
Tetrachloroethene
ug/L
ND
20
20
ND
ND
84
86
70-145
30
Trichloroethene
ug/L
ND
20
20
ND
ND
88
87
62-146
30
Vinyl chloride
ug/L
ND
20
20
ND
ND
72
81
61-163
30
1,2-Dichloroethane-d4 (S)
%
103
102
70-130
4-Bromofluorobenzene (S)
%
101
101
70-130
Toluene-d8 (S)
%
100
101
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/22/2023 05:06 PM without the written consent of Pace Analytical Services, LLC.
Page 11 of 17

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: CMS LANDFILL V
Pace Project No.: 92683146
QC Batch: 795168 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E TCLP MSSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92683146001
METHOD BLANK: 4119737
Associated Lab Samples: 92683146001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
1,4-Dichlorobenzene
ug/L
ND
50.0
2.1
08/22/23 14:55
2,4,5-Trichlorophenol
ug/L
ND
50.0
1.4
08/22/23 14:55
2,4,6-Trichlorophenol
ug/L
ND
50.0
1.5
08/22/23 14:55
2,4-Dinitrotoluene
ug/L
ND
50.0
1.2
08/22/23 14:55
2-Methylphenol(o-Cresol)
ug/L
ND
50.0
1.2
08/22/23 14:55
3&4-Methyl phenol (m&p Cresol)
ug/L
ND
50.0
1.2
08/22/23 14:55
Hexachloro-1,3-butadiene
ug/L
ND
50.0
2.0
08/22/23 14:55
Hexachlorobenzene
ug/L
ND
50.0
1.7
08/22/23 14:55
Hexachloroethane
ug/L
ND
50.0
2.0
08/22/23 14:55
Nitrobenzene
ug/L
ND
50.0
2.1
08/22/23 14:55
Pentachlorophenol
ug/L
ND
100
2.2
08/22/23 14:55
Pyridine
ug/L
ND
50.0
3.4
08/22/23 14:55
2,4,6-Tribromophenol (S)
%
108
10-164
08/22/23 14:55
2-Fluorobiphenyl (S)
%
74
10-130
08/22/23 14:55
2-Fluorophenol (S)
%
68
10-130
08/22/23 14:55
Nitrobenzene-d5 (S)
%
105
10-138
08/22/23 14:55
Phenol-d6 (S)
%
49
10-130
08/22/23 14:55
Terphenyl-d14 (S)
%
119
19-191
08/22/23 14:55
LABORATORY CONTROL SAMPLE: 4120131
Qualifiers
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,4-Dichlorobenzene
ug/L
500
266
53
10-130
2,4,5-Trichlorophenol
ug/L
500
476
95
38-147
2,4,6-Trichlorophenol
ug/L
500
497
99
34-142
2,4-Dinitrotoluene
ug/L
500
472
94
44-154
2-Methylphenol(o-Cresol)
ug/L
500
394
79
31-130
3&4-Methyl phenol (m&p Cresol)
ug/L
500
347
69
30-130
Hexachloro-1,3-butadiene
ug/L
500
295
59
10-130
Hexachlorobenzene
ug/L
500
467
93
44-138
Hexachloroethane
ug/L
500
267
53
10-130
Nitrobenzene
ug/L
500
456
91
33-133
Pentachlorophenol
ug/L
1000
986
99
21-163
Pyridine
ug/L
500
119
24
16-130
2,4,6-Tribromophenol (S)
%
135
10-164
2-Fluorobiphenyl (S)
%
99
10-130
2-Fluorophenol(S)
%
78
10-130
Nitrobenzene-d5 (S)
%
117
10-138
Phenol-d6 (S)
%
63
10-130
Results presented on this
page are in the units
indicated by the "Units"
column except
where an alternate unit
is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/22/2023 05:06 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 17

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: CMS LANDFILL V
Pace Project No.: 92683146
LABORATORY CONTROL SAMPLE:
4120131
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Terphenyl-d14 (S)
%
124
19-191
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
4120129
4120130
MS
MSD
92683146001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
1,4-Dichlorobenzene
ug/L
ND
500
500
266
322
53
64
10-130
19
30
2,4,5-Trichlorophenol
ug/L
ND
500
500
460
458
92
92
10-170
0
30
2,4,6-Trichlorophenol
ug/L
ND
500
500
487
467
97
93
10-166
4
30
2,4-Dinitrotoluene
ug/L
ND
500
500
468
443
94
89
30-164
6
30
2-Methyl phenol(o-Cresol)
ug/L
ND
500
500
395
387
79
77
19-132
2
30
3&4-Methylphenol(m&p
ug/L
ND
500
500
357
355
71
71
13-136
1
30
Cresol)
Hexachloro-1,3-butadiene
ug/L
ND
500
500
289
368
58
74
10-130
24
30
Hexachlorobenzene
ug/L
ND
500
500
449
449
90
90
32-145
0
30
Hexachloroethane
ug/L
ND
500
500
268
336
54
67
10-130
22
30
Nitrobenzene
ug/L
ND
500
500
435
434
87
87
19-145
0
30
Pentachlorophenol
ug/L
ND
1000
1000
1010
1050
101
105
10-188
3
30
Pyridine
ug/L
ND
500
500
129
95.5
26
19
10-130
30
30
2,4,6-Tribromophenol (S)
%
122
128
10-164
2-Fluorobiphenyl (S)
%
92
99
10-130
2-Fluorophenol (S)
%
73
77
10-130
Nitrobenzene-d5 (S)
%
106
110
10-138
Phenol-d6 (S)
%
59
62
10-130
Terphenyl-d14 (S)
%
115
129
19-191
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/22/2023 05:06 PM without the written consent of Pace Analytical Services, LLC.
Page 13 of 17

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: CMS LANDFILL V
Pace Project No.: 92683146
QC Batch: 794511 Analysis Method: EPA 9045D
QC Batch Method: EPA 9045D Analysis Description: 9045 pH
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92683146001
SAMPLE DUPLICATE: 4116740
92683146001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 6.8 6.8 1 10 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/22/2023 05:06 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 17

Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
aceo Huntersville, NC 28078
[phone]
QUALIFIERS
Project: CMS LANDFILL V
Pace Project No.: 92683146
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
H2 Extraction or preparation conducted outside EPA method holding time.
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/22/2023 05:06 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 17

ceo
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: CMS LANDFILL V
Pace Project No.: 92683146
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch Analytical Method Batch
92683146001
SEDIMENT BASIN
EPA 3510C
795168 EPA 8270E 795236
92683146001
SEDIMENT BASIN
EPA 8260D
794927
92683146001
SEDIMENT BASIN
EPA 9045D
794511
Date: 08/22/2023 05:06 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 16 of 17

CHAIN -OF -CUSTODY Analytical Request Document LAB USE ON[' WO# : 92683146 her or MTJL Log-
_ _ ace Analytical II I I
Chain -of -Custody is a LEGAL DOCUMENT -Complete all relevant Fields
Billing Information: WILL BE PRE -FILLED 1 LY
A�
92683146
Container Preservative Type" ILabProject Manager:
Report To: PHIL MURPHY
Email To: [e-mail]
" Prosmvative Types: (11 nitric acid. (2) sulfuric acid. (3) hydrochloric acid, (d) sodium hydroxide, (5) zinc acetate, (0 methanol. {7) sodium hleulfato, (e) sodium
thionuifale, (9) hoxano, (A) ascorbic acid, (B) ammonium sulfate, (C) ammonium hydroxide, (D) TSP, (U) Unpresemod, (0) Olhor
Copy To: EACH PLANT MANAGER
SAc Collection Info/Address: 5105 Morehead Road
Analyses
LAB ProOlelLlne:
Customer Project Name[Number: CMS Landfill V
State Cou ntylCity Timctede Zone Colle
LAB Sample Receipt Checklist:
NC I CabarruslConcord I PT MT CT ET
Custody Seals ProeentAn[act Y N NA
Custody Signatures Present Y N NA
Phone:
SitelFaclllty ID # Charlotte Motor
Compliance Monitoting7
Email:
Speedway
[X ] Yes []No
Collector Signature Present Y N NA
Bottles Intact Y N NA
Collected by (print): John Bullock
Purchase Order #
OW PINS ID #: WA
Correct Bottles Y N NA
Quote #
❑W Location Code #: NIA
SuTHchnt Volume Y N NA
Collected y (signature):
I urnarDund Date squire
TAT IS 10 WORKING DAYS
VOA- Hoadapar:.e Acceptable Y N NA
Immediately Packed on Ice?
RUSH: Same
Yes No
USDA Regulated Soft Y H NA
Samples in holding time Y N NA
Sample Disposal:
Field Filtered (If applicable):
[X ] Dispose as appropriate [I Return
Day Next Day 2 Day 3
[ ] Yes [ ] No
Reslduai Chlorine Proeenl Y N NA
[ ] Archive
[ ] Hold
Day 4 Day 5 Day
(Expedite Charges Apply)
Analysis:
d
N
C
Cf
S?
N
�
LU
W
�
(7
J
O
r—
C4
r
t+
ti
O
r
C)
Cl Strips:
Sample pH Accopta hb Y N HA
pH Stri
Sulfide Present Y H NA
Load Acetate Stripe:
- Matrix Codes (Inserl In Matrix box below): Drinking Water {DW), Ground Water (GW), Wastewater (WW), Product (P), Soil7Solld
(SL), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT)
Customer Sample lD 'M°tr'x"I
Cam
Grab
Collected
(or Composite
Start}
Composite End
Rae Cl
# of
Oars
Date
Time
Date
Time
d LAB USE ONLY: y
bah Samplex comments
_
Sediment Basin
st
a
X
X
X
X
X
X
I
I
1
Customer Remarttsf Special Conditional Possible Hazards:
RECORD PH READING HERE AND WE WILL ADD TO FINAL LAB
REPORT
Type of Ice Used:
Wet [ ] Blue[] Dry l ] None[]
SHORT HOLDS PRESENT (< 72 hours): Y N NIA
LAB Sample Temperature Info:
Temp Blank received: Y N NA
Packing Material Used:
LAB Tracking 9:
MTJL LAB USE ONLY
Therm ID 0:
Table p:
Cooler i Temp Upon Receipt OC
Cooler 1 Therm Corr. Factor oC
Radchem sampla(s) screened:
(<500cpm): [ ] Y [ ] N t ] NA
Sample* received via: [)
FEDEI( []UPS [ ]Cllom [ ] Courier [ ] Pace Courier
ACCT #u
Cooler 1 Corrected Temp oC
Relinquished byfCompany : (Signature) Detefrlme:
Received bylCompany : (Signature)
Daterrime:
Template:
Prelogln:
Comments:
Relinquished bylCampany : (Signature) DaterTime:
Received by/Company: {Signature)
Oaterrime:
Trip Blank Received: Y N WA
PM;
HCL McOH TSP Other
Relinquished bylCompany:{Signature] IDatelTime:
Received 4ylCompany:(Signature)
❑alefrimc:
NanContomnance(E)
Page
PB'
YES ! NO
of
F-ALL-C-010-rev.00, 05Ju=18 Page 17 Ot 17