3902_Granville_Butner_MSWLF_March23GW_FID1812274_20230728

hart '-4 hickman
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Via E-Mail
[e-mail]
July 25, 2023
Garrett & Moore, Inc.
1029 West South Street
Raleigh, NC 27603
sbray(&, garrett-moore. com
Attn: Mr. Stefan Bray, PE
Re: Water Quality Monitoring Report — March 2023
Granville County Butner Landfill
Butner, Granville County, NC
Facility Permit No. 39-02
H&H Job No. GMI-003
Dear Stefan:
Hart & Hickman, PC (H&H) is submitting the attached Water Quality Monitoring Report — March
2023 documenting sample results for the Butner Landfill for the first semi-annual sampling event
of 2023. H&H appreciates the opportunity to work with you on this project. If you have any
questions or require additional information, please do not hesitate to contact us at 704-586-0007.
Very truly yours,
Hart & Hickman, PC
ee r_e
Jason Soban, PG
Project Manager
Jeffrey 011ison
Project Environmental Scientist
2923 South Tryon Street, Suite 100
Charlotte, NC 28203
704.S86.0007 main
3921 Sunset Ridge Rd, Suite 307
Raleigh, NC 27607 www.harthickman.com
919.847.4241 main

I pEiIR USE ONLY ❑Paper Report _]Electronic Data Email CD (data loaded: Yes / No Doc/Event #:
NC DENR I I Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
Garrett & Moore, Inc.
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Stefan Bray Phone: [phone]
E-mail: [e-mail]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Granville County State Road 1004
Butner Landfill Butner. NC 27565 39-02 .1600 (March 28, 2023
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ❑ Detection Monitoring Assessment Monitoring Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells
Groundwater monitoring data from private water supply wells ❑X
Leachate monitoring data El
water monitoring data
Methane gas monitoring data
Corrective action data (specify) MNA Parameters
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached, It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Jason Soban, PG Consultant for Facility [phone]
Facility Representative Name (Print) Title
"7/ 25/ 23
Signature 1/ Date
2923 S Tryon Street, Suite 100, Charlotte, NC 28203
Facility Representative Address
C-1269 (Engineering) 245 (Geology)
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009
Code) Telephone Number
Affix NC Licensed/ Professional Geologist Seal
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Water Quality Monitoring Report
March 2023
Granville County Butner Landfill
Butner, North Carolina
Permit No. 39-02
H&H Job No. GMI-003
July 25, 2023
GARRETT
&MOOREEP22
Engineering for the Power and Waste industries
-.411
hart 'ti• hickman
■
SMARTER ENVIRONMENTAL SOLUTIONS
2923 South Tryon Street, Suite 100 3921 Sunset Ridge Rd , Suite 301
Charlotte, NC 28203 Raleigh, NC 27607 www.harthickman.com
704.586.0007 main 919,847.4241 main

Water Quality Monitoring Report — March 2023
Granville County Butner Landfill
Butner, North Carolina
Permit No. 39-02
H&H Job No. GMI-003
Table of Contents
Section Pate
1.0 Introduction................................................................................................................. I
1.1
Site Information........................................................................................................1
1.2
Regulatory Status......................................................................................................1
1.3
Groundwater Monitoring Program...........................................................................2
1.4
Surface Water Monitoring Program.........................................................................3
2.0 Water Quality Monitoring Activities........................................................................5
2.1
Water Level Measurements......................................................................................5
2.2
Groundwater Sampling Methods..............................................................................5
2.3
Surface Water Sampling Methods............................................................................6
2.4
Sample Equipment Management..............................................................................6
2.5
Sample Handling and Laboratory Analyses.............................................................7
3.0 Water Quality Monitoring Results............................................................................8
3.1
Groundwater Flow and Hydraulic Gradient.............................................................8
3.2
Groundwater Analytical Results...............................................................................9
3.3
Surface Water Analytical Results...........................................................................10
3.4
Quality Assurance/Quality Control Results............................................................11
4.0 Corrective
Action Evaluation..................................................................................13
4.1
Monitored Natural Attenuation Parameters............................................................13
4.2
Phytoremediation....................................................................................................13
4.3
Evaluation of Plume Stability and Trends..............................................................14
5.0 Conclusions
................................................................................................................16
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List of Tables
Table 1
Summary of Well Construction Details
Table 2
Summary of Groundwater Elevations
Table 3
Summary of Field Parameters
Table 4
Summary of Groundwater Flow Velocity
Table 5
Summary of Constituent Detections
Table 6
Summary of Monitored Natural Attenuation Parameters
List of Figures
Figure 1 Site Location Map
Figure 2 Site Plan
Figure 3 Groundwater Potentiometric Map (March 28, 2023)
List of Appendices
Appendix A
Groundwater and Surface Water Sampling Records
Appendix B
Laboratory Analytical Report
Appendix C
Summary of Historical Groundwater Elevations
Appendix D
Summary of Historical Constituents in Groundwater
Appendix E
Summary of Historical Constituents in Surface Water
Appendix F
Summary of Historical Monitoring Natural Attenuation Parameters
Appendix G
Concentration vs. Time Charts
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Water Quality Monitoring Report — March 2023
Granville County Butner Landfill
Butner, North Carolina
Permit No. 39-02
H&H Job No. GMI-003
1.0 Introduction
This Water Quality Monitoring Report (Report) has been prepared by Hart & Hickman, PC (H&H)
to document the methods and results of semi-annual groundwater and surface water monitoring
activities conducted at the Butner Landfill located off State Route 1004 near the Town of Butner,
Granville County, North Carolina. A site location map is included as Figure 1. Water quality
monitoring at the site was performed in general accordance with the Water Quality Monitoring
Program as described in the Corrective Action Plan (May 2014), which was approved by the North
Carolina Department of Environmental Quality (DEQ) Solid Waste Section (SWS).
1.1 Site Information
The Butner Landfill is a closed municipal solid waste (MSW) landfill, located off State Route 1004
near the Town of Butner, Granville County, North Carolina. The Butner facility started receiving
solid waste prior to May 1973. Permit Number 39-02 was issued by the State of North Carolina
on March 3, 1982. The facility stopped receiving solid waste in August 1998. At the present, a
small recycling center and transfer station are operated by the County of Granville at the entrance
of the closed landfill. A site layout map that depicts the facility features is included as Figure 2.
1.2 Regulatory Status
The Butner Landfill entered an Assessment Monitoring Program in December of 1997 because of
detections of volatile organic compounds (VOCs) and pesticides above the North Carolina 2L
Groundwater Standards (2L Standards). An Assessment of Corrective Measures (ACM) was
initiated in 2003, and then suspended by DEQ since there had been no more 2L Standard
exceedances. The Nature and Extent Study (NES) and ACM were recommenced in 2007 when
apparent VOC exceedances of the 2L Standard began to appear; however, they were again
Ad
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suspended when it was determined that the apparent exceedances were not statistically significant
increases (SSIs) above background. An ACM was reinitiated after an exceedance of benzene in
monitoring well MW-2R in December 2012 and was submitted to DEQ in May 2013. Approval
of the ACM was granted in a letter from DEQ dated June 27, 2013. A Corrective Action Plan
(CAP) for monitored natural attenuation (MNA) plus phytoremediation was submitted to DEQ on
May 23, 2014, and was approved by DEQ on June 18, 2014.
The site is currently in an Assessment Monitoring Program and Corrective Action Monitoring
Program. Groundwater and surface water samples are collected semi-annually and analyzed in
accordance with the approved CAP. An overview of the monitoring program is provided in the
following sections.
1.3 Groundwater Monitoring Program
The groundwater monitoring program at the Butner Landfill consists of the following seven
monitoring wells: MW-1R, MW-2R, MW-3R, MW-4, MW-5, MW-6, and NES-1. Monitoring
well MW-1R is located northwest and upgradient of the landfill and serves as a background
location. The compliance network consists of monitoring wells MW-2R, MW-3R, MW-4, MW-
5, and MW-6, which are situated cross -gradient and downgradient of the landfill. Compliance
monitoring wells MW-2R and MW-3R are located at the southern downgradient side of the landfill
and also serve as CAP performance wells. Monitoring well NES-1 is located downgradient of
MW-2R and MW-3R and serves as a CAP sentry well. The monitoring well locations and other
site features are identified on Figure 2. A summary of well construction details is provided in
Table 1.
Groundwater samples are collected semi-annually for select analyses per the CAP. Sample
analyses includes North Carolina Solid Waste Management Rules Appendix I or Appendix II
constituents (hereafter referred to as Appendix I constituents and Appendix II constituents,
respectively), and/or constituents of concern (COCs; i.e., 1,4-dioxane, benzene, and cobalt).
During the first half semi-annual event compliance well analysis for Appendix I and Appendix II
constituents is completed. During the second half semi-annual event compliance well analysis for
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Appendix I and detected Appendix II constituents is completed. As required by DEQ in their
August 3, 2018 letter, tin and any new Appendix II detections are analyzed during each second
half semi-annual event.
Select MNA parameters (alkalinity, biochemical oxygen demand [BOD], chemical oxygen
demand [COD], chloride, ferrous iron, sulfate, methane, nitrate, total organic carbon [TOC], pH,
temperature, and specific conductance) are analyzed on a semi-annual basis for MW-2R and MW-
3R, and annually for NES-1 and MW-1R. As required by DEQ in their January 13, 2021 letter,
six additional MNA parameters (dissolved hydrogen, sulfide, volatiles fatty acids, dissolved
carbon dioxide, ethene, and ethane) are to be sampled for two times every five years corresponding
to the two events immediately preceding the CAER (i.e., second half event 2024 and first half
event 2025). A summary of the well locations and sample analyses for the semi-annual sampling
events is provided below.
Well ID
Classification
First Half Analyses
Second Half Analyses
MW-1R
Background
App. I + App. II, 1,4-
App. I + App. II Det., 1,4-
Dioxane, MNA
Dioxane
MW-2R
Compliance/
App. I + App. II, 1,4-
App. I + App. II Det., 1,4-
Performance
Dioxane, MNA
Dioxane, MNA
MW-3R
Compliance/
App. I + App. II, 1,4-
App. I + App. II Det., 1,4-
Performance
Dioxane, MNA
Dioxane, MNA
MW-4
Compliance
App. I + App. II, 1,4-
App. I + App. II Det., 1,4-
Dioxane
Dioxane
MW-5
Compliance
App. I + App. II, 1,4-
App. I + App. II Det., 1,4-
Dioxane
Dioxane
MW-6
Compliance
App. I + App. II, 1,4-
App. I + App. II Det., 1,4-
Dioxane
Dioxane
NES-1
Sentinel
COCs, MNA
COCs
App. I = Appendix I Constituent; App. II = Appendix II Constituent; Det. = Detected
1.4 Surface Water Monitoring Program
The surface water monitoring program at the Butner Landfill consists of collecting samples from
two locations (SW-1 and SW-2) along an unnamed tributary to Picture Creek which is situated
along the southern downgradient boundary of the site. Picture Creek is classified as a Class IV
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(Water Supply) stream. The surface water sampling points are located downgradient of the facility
at upstream (SW-1) and downstream (SW-2) locations. The locations of the surface water
monitoring points are identified on Figure 2. Surface water samples are collected semi-annually
and analyzed for Appendix I constituents plus 1,4-dioxane.
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2.0 Water Quality Monitoring Activities
2.1 Water Level Measurements
On March 28, 2023, H&H measured depth -to -water and total depths in monitoring wells MW-1R,
MW-2R, MW-3R, MW-4, MW-5, MW-6, and NES-1. Depth -to -water measurements were
collected from the top -of -casing utilizing a decontaminated electronic water level indicator.
Depth -to -water measurements were made after the wells were opened for a sufficient period of
time to allow water levels to equilibrate with atmospheric pressure. Water level measurements
and calculated groundwater elevations are presented in Table 2.
2.2 Groundwater Sampling Methods
On March 28, 2023, H&H collected groundwater samples from site monitoring wells MW-1 R,
MW-2R, MW-3R, MW-4, MW-5, MW-6, and NES-1. Monitoring well MW-1R serves as the
upgradient background well for the facility, and monitoring wells MW-2R, MW- 3R, MW-4, MW-
5, MW-6, and NES-1 serve as compliance monitoring wells. The groundwater samples were
collected and handled in accordance with the sampling protocols included in the site Water Quality
Monitoring Plan as well as the DEQ SWS Guidelines for Groundwater, Soil, and Surface Water
Sampling document.
The monitoring wells were purged utilizing a peristaltic pump or submersible pump under low
flow (< 200 milliliters/minute) conditions. Water levels were recorded during the purging process
to ensure the pump rate did not cause significant drawdown of the water column, and samples were
collected following stabilization of field parameters over three consecutive readings. Field
measurements of pH, temperature, specific conductance, oxygen reduction potential (ORP), and
dissolved oxygen (DO) were measured using a YSI Pro Plus or YSI ProQuatro water quality meter.
Turbidity was measured using a Hach 2100Q turbidity meter. A summary of the final field
parameters recorded prior to sample collection is presented in Table 3. Copies of groundwater
sampling forms containing pertinent information recorded in the field during purging and sampling
at each monitoring well are presented in Appendix A.
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The results of the field -measured water quality parameters indicate that the values measured in
groundwater collected from site monitoring wells were generally within applicable stabilization
criteria. The water levels generally exhibited slight or stable drawdown during the purging process
with some wells (MW-3R, MW-4, and MW-6) continuing to drawdown during low flow pumping
conditions. As discussed in Section 3.2, the data indicate similar analytical results in comparison
to prior sampling events, and the drawdown is not considered to affect the usability of the reported
results. During future sampling events, additional time to achieve stable drawdown and/or
alternative purge methods (volumetric purging) may be used to sample this location. Groundwater
at the site is acidic to slightly basic based on the pH values measured in the field (4.38 to 7.16
Standard Units). Specific conductance values in site groundwater ranged from 92.8 (MW-1R) to
1,824 (MW-2R) microsiemens per centimeter (µS/cm) in groundwater at the site. Turbidity values
ranged from 0.02 (MW-4) to 9.21 (NES-1) nephelometric turbidity units (NTUs).
2.3 Surface Water Sampling Methods
On March 28, 2023, H&H collected surface water samples from sample locations SW-1 and SW-
2 (Figure 2). Surface water samples were collected in general accordance with the site Water
Quality Monitoring Plan (WQMP) as well as the DEQ SWS Guidelines for Groundwater, Soil,
and Surface Water Sampling document. Field parameters were measured during sample collection
and a copy of the surface water sampling form is provided in Appendix A. A summary of field
parameters recorded prior to sample collection is provided in Table 3.
2.4 Sample Equipment Management
Reusable sampling equipment (e.g., water level indicator, bladder pump) was properly
decontaminated between sampling locations with a non -phosphate soap and water wash, followed
by multiple rinses with distilled water. New disposable nitrile gloves were worn during sampling
activities. Disposable sampling equipment/material was discarded after each use.
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2.5 Sample Handling and Laboratory Analyses
Upon sample collection, samples for laboratory analysis were placed directly into dedicated
laboratory -supplied sample bottles, labeled, and placed into ice -filled coolers. A chain -of -custody
record was completed and included sample description, analyses required, matrix, sample
container information, and date and time of sample collection. The samples were transported on
ice, under standard chain -of -custody protocol, to Pace Analytical Services, LLC (Pace) a North
Carolina -certified laboratory. The laboratory analytical report and chain -of -custody record for the
March 2023 sampling event are included in Appendix B. A summary of samples collected during
the subject reporting period is provided below.
The groundwater samples from monitoring wells MW-1R, MW-2R, MW-3R, MW-4, MW-5 and
MW-6 were analyzed for Appendix I constituents and Appendix II constituents plus 1,4-dioxane.
The groundwater samples from monitoring wells MW-1R, MW-2R, MW-3R, and NES-1 were
also analyzed for MNA parameters. Additionally, the groundwater sample from monitoring well
NES-1 was analyzed for benzene, 1,4-dioxane, and cobalt as COCs. The surface water samples
from SW-1 and SW- 2 were analyzed for Appendix I constituents plus 1,4-dioxane.
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3.0 Water Quality Monitoring Results
Groundwater and surface water monitoring activities were conducted at the site on March 28,
2023. Groundwater and surface water samples were collected and analyzed in accordance with
the DEQ approved CAP and changes to the CAP documented in DEQ approved Corrective Action
Evaluation Reports (CAER; December 2016 and December 2020). The monitoring results are
discussed in the following sections.
3.1 Groundwater Flow and Hydraulic Gradient
A summary of monitoring well gauging and water level elevation data is provided in Table 2.
Historical groundwater elevation data is provided in Appendix C. Groundwater flow direction,
average hydraulic gradient, and average interstitial flow velocity were derived from water -level
measurements recorded during the March 2023 sampling event. A potentiometric map generated
from the March 28, 2023 gauging event is provided as Figure 3. The March 2023 water levels
were similar to historical seasonal fluctuations observed at the site. Consistent with historical
trends, the overall direction of shallow groundwater flow at the site is south to southeast towards
the unnamed tributary to Picture Creek.
The hydraulic gradient in the vicinity of each well was derived by dividing the elevation difference
between water table elevations measured at the monitoring wells and proximal potentiometric
contour lines, by the perpendicular horizontal distance between the wells and potentiometric
contours (Figure 3 and Table 4). The potentiometric contours indicate an average hydraulic
gradient of approximately 0.039 ft./ft. Results of in -situ slug testing reported by others (LaBella,
2021) indicate an average hydraulic conductivity value in the shallow surficial aquifer of 6.18 x
10"2 feet/day (approximately 22.6 feet/year). Using the horizontal hydraulic gradient
measurements, the individual estimate of hydraulic conductivity, and an assumed effective
porosity of 0.18 (LaBella, 2021), the range of average interstitial groundwater flow velocities for
the shallow surficial aquifer was calculated using the following equation: Vx = (K/ne) x dh/dl.
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Where:
V,, = average interstitial groundwater flow velocity;
K = hydraulic conductivity;
ne = effective porosity; and,
dh/d1= horizontal hydraulic gradient
Average linear flow velocities are estimated to range between approximately 3.66 to 7.14 feet/year
(0.010 to 0.020 feet/day), with a geometric mean of 4.83 feet/year (0.013 feet/day). These values
are consistent with prior monitoring events. Table 4 summarizes the data used to calculate the
average interstitial groundwater flow velocity in the vicinity of each monitoring well.
3.2 Groundwater Analytical Results
Semi-annual groundwater sampling consisted of collecting samples from seven site monitoring
wells. A summary of groundwater constituent detections from the March 2023 sampling event is
provided in Table 5. Historical analytical results are presented in Appendix D. Consistent with
the CAP and subsequent changes documented in DEQ approved CAERs (December 2016 and
December 2020), the primary COCs for the site include benzene, 1,4-dioxane, and cobalt. A
summary of groundwater results for site COCs and other exceedances is provided below.
Appendix I & 1I VOCs
The analytical results indicate benzene, chlorobenzene, chloroethane, 1,2-dichlorobenzene, 1,4-
dichlorobenzene, dichlorodifluoromethane, 1,4-dioxane, naphthalene, and trichlorofluoromethane
were detected at concentrations above laboratory method detection limits (MDLs) in one or more
wells during the March 2023 sampling event. Benzene was detected at a concentration above its
2L Standard (1 µg/L) in monitoring well MW-2R (1.6 µg/L). The concentration of benzene
detected in MW-2R is consistent with historical data and has been addressed in the ACM
(approved in June 2013) and the CAP (approved in June 2014). 1,4-Dioxane (up to 123 µg/L) was
detected at concentrations above its 2L Standard (3 µg/L) in monitoring wells MW-2R, MW-3R,
and MW-4, and concentrations are consistent with historical detections. No other VOC
constituents were detected above 2L Standards during the March 2023 sampling event.
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Appendix I & II Metals
The analytical results indicate metals barium, beryllium, chromium, cobalt, copper, nickel,
thallium, tin, and zinc were detected at concentrations above MDLs in one or more wells during
the March 2023 sampling event. Cobalt (up to 12.8 µg/L) was detected at concentrations above
its 2L Standard (1 µg/L) in monitoring wells MW-2R, MW-4, and MW-5, and the concentrations
are consistent with historical detections. No other metal constituents were detected above 2L
Standards during the March 2023 sampling event.
Appendix II Additional Analyses
The analytical results indicate that Appendix II Semi-VOCs (SVOCs), pesticides, herbicides, and
polychlorinated biphenyls (PCBs) were not detected above MDLs in the groundwater samples
collected from MW-1R, MW-2R, MW-3R, MW-4, MW-5 and MW-6.
3.3 Surface Water Analytical Results
Semi-annual surface water sampling consisted of collecting samples from on upstream (SW-1)
and one downstream (SW-2) location. A summary of surface water constituent detections from
the March 2023 sampling event is provided in Table 5. Historical analytical results are presented
in Appendix E. A summary of surface water results is provided below.
VOCs
The analytical results indicate 1,4-dioxane (up to 5.2 µg/L) was detected in SW-1 and SW-2 at
concentrations above the laboratory MDL, and concentrations are consistent with historical
detections. North Carolina has not established a North Carolina 213 Water Quality Standard for
Surface Water (213 Standard) for 1,4-dioxane. Results of the surface water sampling indicate both
concentrations of 1,4-dioxane were detected above the North Carolina In -Stream Target Value for
Surface Water (ISTV; 0.35 µg/L). No other VOCs were detected above MDLs during the March
2023 sampling event.
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Matgk
The analytical results indicate barium, chromium, cobalt, and nickel were detected above the
laboratory MDL in one or both of the surface water samples collected during the March 2023
sampling event. The detected concentrations of barium, chromium, and nickel do not exceed the
2B Standards and are generally consistent with historical data. Cobalt does not have a 2B Standard
and the detected concentration was compared to its respective North Carolina In -Stream Target
Value for Surface Water (ISTV; 3 µg/L), and there were no exceedances. No other constituents
were detected above MDLs during the March 2023 sampling event.
3.4 Quality Assurance/Quality Control Results
Quality assurance procedures and protocols for sampling activities were conducted in general
accordance with the DEQ-approved CAP and WQMP. Quality assurance samples included the
collection of a trip blank and field blank sample. Samples were received by the lab in good
condition and met holding times and preservation requirements, with the exception of BOD
analysis for MW-3R and NES-1. Sample results for BOD analysis for wells MW-3R and NES-1
were flagged with an H2 qualifier indicating sample extraction or preparation was conducted
outside the method holding time. However, the March 2023 BOD results for MW-3R and NES-1
are consistent with historical data at these locations, thus the H2 flag is not considered to impact
the usability of these data. Based upon a review of the data packages, no significant quality
assurance/quality control (QA/QC) issues were identified for the laboratory analyses. In summary,
the QA/QC results indicate that the data collected during the semiannual monitoring event is
suitable for its intended purpose.
Trip Blanks
A laboratory -filled trip blank accompanied the sampling team during sampling and the transport
of VOC samples to the laboratory. The trip blank sample serves as a QC check on potential
external contamination and/or cross -contamination between VOC water samples during shipping
and storage. The trip blank sample was analyzed for Appendix I & II VOCs and 1,4-dioxane. The
results indicate no constituents were detected above laboratory MDLs.
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Field Blanks
A field blank sample was collected in the field by exposing laboratory -supplied deionized water
to the sampling environment. The field blank is used to evaluate the potential for contamination
of a sample by site contaminants from a source not associated with the samples collected. The
field blank sample was analyzed for Appendix I constituents, Appendix I1 constituents, and 1,4-
dioxane. The results indicate no constituents were detected above laboratory MDLs.
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4.0 Corrective Action Evaluation
4.1 Monitored Natural Attenuation Parameters
Groundwater samples collected during the March 2023 sampling event from monitoring wells
MW-1R, MW-2R, MW-3R, and NES-1 were analyzed for MNA parameters. The groundwater
MNA parameter results for the current sampling event are summarized in Table 6. Historical
groundwater MNA parameter results are provided as Appendix F. A summary of the MNA
parameters collected from the above locations is provided below:
• MNA Field Parameters: temperature, pH, conductivity, ORP, turbidity, DO, and ferrous
iron.
• MNA Laboratory Parameters: alkalinity, BOD, COD, chloride, methane, nitrate/nitrogen,
sulfate, and TOC.
Based on the January 13, 2021 response from DEQ to the CAER dated December 21, 2020,
additional parameters including dissolved carbon dioxide, dissolved hydrogen, sulfide, volatile
fatty acids, ethene, and ethane will be analyzed for two events every five years, corresponding to
the two events immediately preceding each CAER. The next CAER is due after the second half
semi-annual sampling event of 2025. The MNA results from the current sampling event will
supplement the comprehensive results collected for the five-year period to evaluate MNA as the
remedy for this site, a discussion of the evaluation will be detailed in the next CAER.
4.2 Phytoremediation
The CAP requires completion of an annual phytoremediation tree survey including surveys of tree
species, tree health, and tree maturity within the plume area. The next annual phytoremediation
tree survey for the Butner Landfill is scheduled for summer 2023 and the results will be presented
in the second half 2023 Water Quality Monitoring Report.
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4.3 Evaluation of Plume Stability and Trends
As required by the CAP, this report includes an evaluation of plume stability and contaminant
concentration trends based on analytical results obtained from performance wells MW-2R and
MW-3R. In addition, constituent exceedances at other compliance monitoring wells (i.e., MW-4
and MW-5) are discussed in this section. The March 2023 results indicate VOCs benzene and 1,4-
dioxane, and metal compound cobalt are the only constituents detected in site groundwater at
concentrations above 2L Standards. Charts that depict constituent concentrations versus time for
site COCs (benzene, 1,4-dioxane, and cobalt) are provided in Appendix G. A discussion of the
concentration trends in site groundwater is provided below.
Benzene
Chart 1 presents a plot of benzene concentrations for monitoring wells with previous detections
(MW-2R, MW-3R, and MW-4). Historical results indicate there were no benzene detections in
site groundwater prior to December 2006; however, from December 2006 to present,
concentrations of benzene in MW-2R have routinely been detected above its 2L Standard (1.0
µg/L) with concentrations ranging between non -detect and 2.1 µg/L. During prior monitoring
events, benzene was also detected in MW-3R (up to 0.73J µg/L) and MW-4 (up to 0.44J µg/L) at
estimated concentrations below its 2L Standard. The benzene concentrations from the March 2023
sampling event are consistent with historical detections at the site.
Site monitoring results indicate benzene detections and exceedances are localized and limited to
three compliance monitoring wells. Since there have been no detections of benzene in samples
collected from surface water or sentinel well NES-1, there is no indication that the plume is
migrating toward the property boundary. This COC will continue to be monitored during future
semi-annual sampling events.
1,4-Dioxane
As required by the DEQ Solid Waste Section, beginning in 2018 groundwater and surface water
samples collected at the site have been analyzed for 1,4-dioxane. Chart 2 presents a plot of 1,4-
dioxane concentrations for monitoring wells with previous detections (MW-2R, MW-3R, MW-4,
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and MW-5). The results of the March 2023 sampling event indicate 1,4-dioxane was detected
above its 2L Standard in compliance monitoring wells MW-2R, MW-3R, and MW-4. As shown
on the chart, the 1,4-dioxane concentrations are generally stable and current concentrations are
consistent with historical detections at the site. This COC will continue to be monitored during
future semi-annual sampling events.
Surface water results indicate 1,4-dioxane was detected in both the upstream (SW-1; 1.3 J µg/L)
and downstream (SW-2; 5.2 µg/L) samples at concentrations above its ISTV. 1,4-Dioxane
concentrations in surface water have historically fluctuated at the upstream location between non -
detect and 10.50 µg/L and at the downstream location between non -detect and 54.5 µg/L.
Based on the available data collected since 2018, 1,4-dioxane concentrations in groundwater
appear to be relatively stable, while detections in surface water have fluctuated to varying degrees.
This COC will continue to be monitored during future semi-annual sampling events.
Cobalt
Chart 3 presents a plot of the cobalt concentrations versus time for select monitoring wells where
it has consistently been detected in exceedance of its 2L Standard of 1 µg/L (MW-2R and MW-
5). Cobalt in MW-2R has ranged between non -detect and 38.0 µg/L, but has been consistently
detected between 7.4 and 17.0 µg/L since August 2014. Cobalt in MW-5 has fluctuated between
non -detect and 251 µg/L,, but has been consistently between 9.82 J and 172 µg/L, since August
2014. This COC will continue to be monitored during future semiannual sampling events.
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5.0 Conclusions
Semi-annual water quality monitoring activities were conducted at the site in on March 28, 2023.
The groundwater results indicate the landfill monitoring well network remains adequate to monitor
the site. A review of plume stability and concentration trends indicate that the selected remedies
of natural attenuation and phytoremediation are adequately controlling the plume. Based on the
March 2023 results, site COCs remain consistent with the prior sampling event, and the facility
will continue work in the Assessment Monitoring and Corrective Action programs. A summary
of the results is provided below.
• Consistent with historical trends, the overall direction of groundwater flow at the site is
south to southeast towards the unnamed tributary to Picture Creek.
• Benzene (MW-2R) and 1,4-dioxane (MW-2R, MW-3R, and MW-4) were detected in
groundwater at concentrations above their 2L Standards. The benzene and 1,4-dioxane
concentrations are consistent with historical concentrations detected at each location. No
other VOC constituents were detected above 2L Standards.
• Cobalt (MW-2R, MW-4, and MW-5) was detected in groundwater at concentrations above
its 2L Standard. The cobalt concentrations are consistent with historical concentrations
detected at each location. No other metal constituents were detected above 2L Standards.
• 1,4-Dioxane (SW-1 and SW-2) was detected in surface water at concentrations above its
respective ISTV. The 1,4-dioxane concentrations are consistent with historical
concentrations at each location.
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Table 1
Summary of Well Construction Details
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Ground
TOC
Top of
Top of
Bottom of
Total Well
Depth to
Geologic
Well ID
Latitude
Longitude
Elevation
Elevation
Casing
Screen
Screen
Depth
Bedrock
Unit
(ft AMSL)
(ft AMSL)
(ft AGS)
(ft BTOC)
(ft BTOC)
(ft BTOC)
(ft BTOC)
Fractured
MW-1 R
N 36° 09' 55.49"
W 78° 45' 37.80"
461.01
460.51
0.00
41.00
56.00
56.00
30.00
Bedrock
Weathered
MW-2R
N 36o 09' 38.57"
W 78o 45' 34.97"
326.60
331.60
2.34
3.85
18.85
18.85
13.00
Bedrock
Fractured
MW-3R
N 36o 09' 38.58"
W 78o 45' 34.85"
328.77
330.96
2.18
25.83
35.83
35.83
13.00
Bedrock
Fractured
MW-4
N 36' 09' 38.93"
W 78o 45' 30.15"
338.97
340.80
1.95
16.43
31.43
31.43
13.00
Bedrock
Fractured
MW-5
N 36' 09' 39.35"
W 78' 45' 23.77"
341.88
343.88
2.12
8.52
23.52
23.52
17.00
Bedrock
Fractured
MW-6
N 36° 09' 47.00"
W 78° 45' 25.47"
360.80
362.53
2.00
17.63
32.63
32.63
21.20
Bedrock
Fractured
NES-1
N 36o 09' 35.65"
W 78o 45' 31.59"
326.22
328.40
2.50
15.00
32.80
32.80
26.00
Bedrock
Notes:
Well information obtained from LaBella 2021 Water Quality Monitoring Report
ft = feet; AMSL = above mean sea level
AGS = above ground surface
BTOC = below top of casing
Table 1 (Page 1 of 1)
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Table 2
Summary of Groundwater Elevations
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Well ID
Total Depth
ft BTOC
( )
TOC Elevation
ft AMSL
( )
March 28, 2023
Depth to
Groundwater
(ft BTOC)
Groundwater Elevation
(ft AMSL)
MW-1 R
56.00
460.51
44.11
416.40
MW-2R
18.85
331.60
2.09
329.51
MW-3R
35.83
330.96
2.14
328.82
MW-4
31.43
340.80
6.64
334.16
M W-5
23.52
343.88
8.73
335.15
M W-6
32.63
362.53
9.90
352.63
N ES-1
32.80
328.40
13.11
315.29
Notes:
ft = feet; AMSL = above mean sea level
BTOC = Feet below top of casing
Table 2 (Page 1 of 1)
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Table 3
Summary of Field Parameters
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Sample ID
Sample Date
Field Parameter
Result
Unit
Groundwater
MW-1R
3/28/2023
pH
5.52
S.U.
Temperature
15.6
°C
Conductivity
92.8
PS/cm
Turbidity
1.86
NTU
Dissolved Oxygen
3.90
mg/L
ORP
197.7
mV
MW-2R
3/28/2023
pH
6.46
S.U.
Temperature
14.3
°C
Conductivity
1,824
NS/cm
Turbidity
9.19
NTU
Dissolved Oxygen
0.06
mg/L
ORP
-206.7
mV
MW-3R
3/28/2023
pH
6.92
S.U.
Temperature
14.8
°C
Conductivity
1,390
PS/Cm
Turbidity
3.97
NTU
Dissolved Oxygen
0.21
mg/L
ORP
-45.6
mV
MW-4
3/28/2023
pH
7.16
S.U.
Temperature
16.2
°C
Conductivity
1,543
PS/Cm
Turbidity
0.02
NTU
Dissolved Oxygen
0.09
mg/L
ORP
-212.6
mV
MW-5
3/28/2023
pH
4.87
S.U.
Temperature
15.2
°C
Conductivity
1,657
PS/Cm
Turbidity
9.01
NTU
Dissolved Oxygen
3.42
mg/L
ORP
-306.1
mV
MW-6
3/28/2023
pH
6.65
S.U.
Temperature
16.2
°C
Conductivity
655
PS/Cm
Turbidity
0.72
NTU
Dissolved Oxygen
1.34
mg/L
ORP
165.1
mV
NES-1
3/28/2023
pH
4.38
S.U.
Temperature
14.6
°C
Conductivity
105.8
PS/cm
Turbidity
9.21
NTU
Dissolved Oxygen
1.91
mg/L
ORP
217.2
mV
Surface Water
SW-1
3/28/2023
pH
7.67
S.U.
Temperature
17.0
°C
Conductivity
148.9
PS/Cm
Turbidity
26.4
NTU
Dissolved Oxygen
7.26
mg/L
ORP
149.2
mV
SW-2
3/28/2023
pH
7.59
S.U.
Temperature
17.8
°C
Conductivity
334.2
PS/cm
Turbidity
15.8
NTU
Dissolved Oxygen
7.62
mg/L
ORP
149.9
mV
Notes:
S.U. = standard units; °C = degrees Celsius; pS/cm = microsiemens per centimeter
NTU = nephelometric turbidity unit; mg/L = milligrams per liter; mV = millivolts
ORP = oxidation reduction potential
Table 3 (Page 1 of 2)
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Table 4
Summary of Groundwater Flow Velocity
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Well ID
Hydraulic Conductivity
���
(ft/day)
Groundwater
Elevation
(ft AMSL)
Reference
Elevation
(ft AMSL)
Delta
Elevation
(ft)
Map Length
(ft)
Hydraulic
Gradient (ft/ft)
Effective
Porosity ���
Groundwater
Flow Velocity
(ft/day)
Groundwater
Flow Velocity
(ft/year)
MW-1 R
6.18E-02
416.40
410.00
6.40
112.31
0.057
0.18
0.020
7.14
MW-2R
6.18E-02
329.51
320.00
9.51
255.45
0.037
0.18
0.013
4.67
MW-3R
6.18E-02
328.82
320.00
8.82
251.84
0.035
0.18
0.012
4.39
MW-4
6.18E-02
334.16
330.00
4.16
94.12
0.044
0.18
0.015
5.54
MW-5
6.18E-02
335.15
330.00
5.15
176.39
0.029
0.18
0.010
3.66
MW-6
6.18E-02
352.63
350.00
2.63
85.67
0.031
0.18
0.011
3.85
NES-1
6.18E-02
315.29
320.00
4.71
109.68
0.043
0.18
0.015
5.38
Minimum
--
--
--
--
0.029
--
0.010
3.66
Maximum
--
--
--
--
0.057
--
0.020
7.14
Geometric Mean
--
--
--
--
0.039
--
0.013
4.83
Notes:
1) Hydraulic conductivity and porosity values used from Labella Associates Water Quality Monitoring Report - February 2021 Event.
ft = feet; ft/day = feet per day; ft/year = feet per year
AMSL = feet above mean sea level; -- = not applicable
Vx = (K/ne) x dh/dl
Vx = groundwater flow velocity
K = hydraulic conductivity
ne = effective porosity
dh/dl = hydraulic gradient
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Table 5
Summary of Constituent Detections
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Well ID
Sample Date
Parameter '
Result (µg/L)
Standard
(pg/L)
Source (' 8,2)
Groundwater
MWA R
3/28/2023
Barium
2.24 J
700
NC 2L
MW-2R
3/28/2023
1,2-Dichlorobenzene
1.0
20
NC 2L
1,4-Dichlorobenzene
1.7
6
NC 2L
1,4-Dioxane
123
3
NC 2L
Barium
107
700
NC 2L
Benzene
1.6
1
NC 2L
Chlorobenzene
15.3
50
NC 2L
Chloroethane
0.90 J
3,000
NC 2L
Chromium
2.48 J
10
NC 2L
Cobalt
12.8
1
NC 2L
Dichlorodifluoromethane
6.2
1,000
NC 2L
Naphthalene
1.8
6
NC 2L
Nickel
94.9
100
NC 2L
Tin
36.9 J
2,000
NC 2L
Trichlorofluoromethane
1.5
2,000
NC 2L
MW-3R
3/28/2023
1,2-Dichlorobenzene
1.0
20
NC 2L
1,4-Dichlorobenzene
0.44 J
6
NC 2L
1,4-Dioxane
67.4
3
NC 2L
Barium
75.7
700
NC 2L
Chlorobenzene
12.0
50
NC 2L
Chloroethane
0.86 J
3,000
NC 2L
Cobalt
0.894 J
1
NC 2L
Copper
5.96 J
1,000
NC 2L
Nickel
32.1
100
NC 2L
Tin
16.6 J
2,000
NC 2L
Thallium
0.168 J
2
NC 2L
MW-4
3/28/2023
1,4-Dioxane
45.0
3
NC 2L
Barium
1.11 J
700
NC 2L
Chloroethane
0.79 J
3,000
NC 2L
Cobalt
2.08 J
1
NC 2L
Copper
8.83 J
1,000
NC 2L
Nickel
13.9 B
100
NC 2L
Zinc
11.6 J
1,000
NC 2L
MW-5
3/28/2023
1,4-Dioxane
1.6 J, C8
3
NC 2L
Barium
206
700
NC 2L
Beryllium
0.542 J
4
NC 2L
Cobalt
9.82 J
1
NC 2L
Copper
17.1
1,000
NC 2L
Nickel
3.72 J, B
100
NC 2L
Zinc
19.8 J
1,000
NC 2L
MW-6
3/28/2023
Barium
1.96 J
700
NC 2L
Nickel
1.71 J, B
100
NC 2L
NES-1
3/28/2023
No Constituents Detected
Surface Water
SW-1
3/28/2023
1,4-Dioxane
1.3 J, C8
0.35
ISTV (2)
Barium
35.2
1,000
NC 2B
Chromium
1.97 J
16
NC 2B
Cobalt
1.12 J
3
ISTV �2)
Nickel
3.71 J
25
NC 2B
Hardness
54,900
100,000
NC 2B
SW-2
3/28/2023
1,4-Dioxane
5.2
0.35
ISTV (2)
Barium
42.6
1,000
NC 2B
Nickel
7.10 J, B
25
NC 2B
Hardness
132,000
100,000
NC 2B
Notes:
NC 2L Standards are the Title 15A NCAC 02L .0202 Groundwater Standards (21- Standards) dated April 1, 2022.
15A NCAC 213 Water Quality Standards (26 Standards) for Surface Water (Class WS-IV;NSW) dated July 26, 2021.
Bold concentrations exceed the NC 2L Standard for groundwater or NC 2B Standard for surface water.
1. 2B Standards for hardness -dependent metals are calculated using a site mean hardness value for
hardness results reported for the current sampling event.
2. No 2B Standard or EPA Nationally Recommended Water Quality Criteria (MRWQC) established, value shown is
value shown is North Carolina In -Stream Target Value for Surface Waters (ISTV).
J = Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
B = Analyte was detected in the associated method blank; C8 = Result may be biased high due to carryover from
previously analyzed sample
µg/L = micrograms per liter; -- = not applicable
Table 5 (Page 1 of
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Table 6
Summary of Monitored Natural Attenuation Parameters
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Well ID
Sample Date
Parameter
Result
(µg/L)
2L Standard
(µg/L)
MW-1R
3/28/2023
Chloride
3,840
250,000
MW-2R
3/28/2023
220,000
250,000
MW-3R
3/28/2023
175,000
250,000
NES-1
3/28/2023
4,320
250,000
MW-1 R
3/28/2023
Sulfate
586 J
250,000
MW-2R
3/28/2023
575 J
250,000
MW-3R
3/28/2023
1,060
250,000
NES-1
3/28/2023
6,380
250,000
MW-1 R
3/28/2023
Nitrogen, Nitrate
315
10,000
MW-2R
3/28/2023
24.8 J
10,000
MW-3R
3/28/2023
<10.0
10,000
NES-1
3/28/2023
5,640
10,000
MW-1R
3/28/2023
Methane
<10.0
NE
MW-2R
3/28/2023
577
NE
MW-3R
3/28/2023
96.2
NE
NES-1
3/28/2023
<5.3
NE
MW-1R
3/28/2023
Alkalinity
42,000
NE
MW-2R
3/28/2023
860,000
NE
MW-3R
3/28/2023
731,000
NE
NES-1
3/28/2023
8,900
NE
MW-1R
3/28/2023
Ferrous Iron
<0.5
NE
MW-2R
3/28/2023
4,500
NE
MW-3R
3/28/2023
<0.5
NE
NES-1
3/28/2023
<0.5
NE
MW-1R
3/28/2023
Biological Oxygen Demand
(5 Day)
<2,000
NE
MW-2R
3/28/2023
2,140 B2
NE
MW-3R
3/28/2023
<2,000
NE
NES-1
3/28/2023
<2,000
NE
MW-1R
328/2023
Chemical Oxygen Demand
<12,500
NE
MW-2R
3/28/2023
101,000
NE
MW-3R
3/28/2023
45,400
NE
NES-1
3/28/2023
<12,500
NE
MW-1R
3/28/2023
Total Organic Carbon
<500
NE
MW-2R
3/28/2023
24,300
NE
MW-3R
3/28/2023
9,310
NE
NES-1
3/28/2023
1,110
NE
Notes:
NC 2L Standards are the Title 15A NCAC 02L .0202 Groundwater Standards dated April 1, 2022.
J = Estimated concentration above the adjusted method detection limit and below the adjusted
reporting limit; B2 = Oxygen usage is less than 2.0 for all dilutions set. The reported value is an
estimated less than value and is calculated for the dilution using the most amount of sample;
< value indicates the analyte was not detected above the laboratory method detection limit;
ug/L = micrograms per liter; NS = Not Sampled; ND = Not Detected; NE = Not Established
Table 6 (Page 1 of 1)
Hart & Hickman, PC
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 -Granville Co. Butner LF/2023 First Half GWM/Tables/Butner Tables 1-6

PROPERTY BOUNDARY
APPROXIMATE
LIMITS OF WASTE
USGS-The National Map: National Boundaries Dataset, 3DEP Elevation
Program, Geographic Names Information System, National Hydrography
Dataset, National Land Cover Database, National Structures Dataset, and
National Transportation Dataset; USGS Global Ecosystems; U.S. Census
Bureau TIGER/Line data; USFS Road Data; Natural Earth Data; U.S.
Department of State Humanitarian Information Unit; and NOAA National
Centers for Environmental Information, U.S. Coastal Relief Model.• Data
refreshed August, 2021.
0 2,000 4,000
Niiii
SCALE IN FEET
U.S.G.S. QUADRANGLE MAP
LAKE MICHIE, NORTH CAROLINA 2019
3 QUADRANGLE
7.5 MINUTE SERIES (TOPOGRAPHIC)

-� IIII \ 4\\\\• �\`� ��'�.1��,\\ ,\�1' �.. _� ,� I 1 � �\ \\\\\\111 �..�\�\� \ \ \ �\ �� \ 1
NA
_ J• - .-//�/f//%/ `•.... ///� I I;If�I IIII I � � \ I I III / /
'•-,. / //%// .
/ /.. ��;r,:•• ::�" --��. :i/ ///// �ly
.� �/I�'llfljllllllllr\ \\ I I I / I I /lljllll/1 �,,�•//l// /// / //
_•� �\\ � I � \' � � '�,;.: i /y%% %/%/� � � -�rY/,l I I I LIIIII I I I I / �'y\\\ \ I I � _ // / ///// //////% �\ I((11 ( I / 1 / /� / i ��i///i
/ I
'`;'\ �,\ � —,�i � // I
\ � „_ ,�"�`/\. �_�`/ /: I 1 /-
�_;�I.I �\./11I11 I `5�':/ /IIIII III I ,�\\\\��_—;////
: / I IIII I / {��\\ / / r
�\ /
�.,-��.� �`.�. �.,�� (IIII •.'+ / /// \\1\III . �_. 'r///� �// IIIIIII ///.',,�\� ��iiii/// / III\II\\\\\,\��//�// / _/ /`
:? ..:�--=--� 111 II l "`. (•�_ I \ �I11 _ r`= � ;�:r��ii— � I III I I / . \\�—// / //� / /' II 1 \\ �.;i / /—
��—� 111 I I / ( � \ \\\\\1 \\ \\ / // / / J I I I � _ � // ///, •� IIII \\\ .� �/ / / / / i
iNX
�
'll / r // 111 I 1 / > l" \\ \ \..\\��•� \ � /�•�l _• � l I I .—� / / \1 \ �_/ •/ ��,'��
/ ////// III .I / \_ =—i ��- /i� y.•'�.. /-/� 11 IIII1111(� � / / ( / - \s\ \\\ _— / I i
I IIII I l:: 1.
//I%II1/(/ \ I r'llf'`\`:/ii%//. * r,..�:.///// //-1 1 1 /yr�/��. �?0�_• �I I -• •- i / ��/i�'
//(/ / I \�\\\\ __/jam/� _ _ r._. � \ ;\ \\'I ��/r` ;— .•\ \\ \�// / j�� p ,y,
W . ( ,
� ,�= \\�\ _/� � }T•I .;� _ ;. IIII / / �. w�l.� f��� f/• i� '�y'•,
_ r // / / // ri•l r — — �: �':s�d,�j � � r":r,� ri � � /'>� / �l�'•/� 1� i � � ✓,���/ /i
bp
/A —tic
'%
,,,•'fie � 1 y% %r� a - � � 75\ ! � � /" �.�� '/
_�� 'mot,\. '•� —�• ,r,% �?y' / 1` 1. .r�(F � .�-"� : i�. �"��•'� • t �� — � . � �. � � ':.a�':�r � / i •� �"�• l;'�-rF :�'�'� /�i " / -���— i �' 1 —� � /
7 �" // /. /[�/A• � /a.•7 / ✓'• SL. �/ � � .--� J�` _ l 1 \ �. l — fir' J'vi7f• � � �
aaRR"��, � i �,
,r i� _.� 1y� v olll ! I(( I(II' �;} �1 �. _— �— / �, 's€i , /ti ;'r s,.:a- /

LEGEND
it,
SITE PROPERTY BOUNDARY
APPROXIMATE LIMITS OF WASTE
SURFACE WATER FEATURE
GROUNDWATER MONITORING WELL
SURFACE WATER SAMPLE POINT
GAS PROBE
GASVENT
40
(352.63)
GROUNDWATER ELEVATION (FT AMSL)
X. x
•,T+�.�+ir �'
1
GROUNDWATER ELEVATION CONTOUR
+�.
t�C
`' y''�.+ �"�.`w i '
(FT•
r•
-.ti rVr
�'
(
..F~�17�!'� jM
..•' /;
tYr
_ hvy-y 4.i.r 1APPROXIMATE
GROUNDWATER•
DIRECTION
ICI.
•
,
UNNAMED TRIBUTARY
'. MW-6 OF PICTURE CREEK NOTES:
~ (352.63) 1. APPROXIMATE LIMITS OF WASTE OBTAINED FROM
37p 3�GP-1 LABELLA GROUNDWATER MONITORING REPORTS.
2. APPROXIMATE LOCATIONS OF ENVIRONMENTAL
MONITORING POINTS OBTAINED FROM BUTNER LANDFILL
GRANVILLE COUNTY CORRECTIVE ACTION PLAN DATED
4 MAY 2014 PREPARED BY JOYCE ENGINEERING.
• 36p GV �i fF ' �f.f k: _ 3. AERIAL IMAGERY OBTAINED FROM NCONE MAP, 2021.
&G V r ti f' M l r
� 3 •
. GP-52
p 34b+GP
r1,GP-6
la"pul
(33 .16)) GP 3 MW 5 F s .{ , APPROXIMATE
(335.15)� 0 250 500
MW-3W �"} '' w' SCALE IN FEET
(328.82)! y.
MW-2R
GROUNDWATER POTENTIOMETRIC MAP
330 SW 1
r (MARCH 28, 2023)
#' / BUTNER LANDFILL
+3Lp GRANVILLE COUNTY
•�' S\J) 2 3?� S-1 BUTNER, NORTH CAROLINA
±r NE
.. (315.29)11
hart hackman South Tryon Street -Suite 100
3
� Char
lotte, North Carolina 28203
o z' a
.. 704-586-0007(p) 704-586-0373(I)
SMARTER ENVIRONMENTAL SOLUTIONS License # C-1269 / #C-245 Gcology
DATE: 5-8-23 REVISION NO. 0
h
' JOB NO. GMI-003 FIGURE NO. 3

Appendix A
Groundwater and Surface Water Sampling Records
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

hart ;,%liIiia hickman
SMARTER ENVIRONMENTAL SOLUTIONS
LOW -FLOW GROUNDWATER
SAMPLING RECORD
Job No: C, V�A` C) 0
Well ID:
Well Location: C /vim
Facility Name: J Gyt\ I (;A-Nv Date:
Top of Casing Elevation (ft msl): Casing Material: V --\4 �__ Volume of Water Per Well Volume: gallons
Total Well Depth (ftTOC): Depth to Water (ftTOC)., �I L1 . \� Well Diameter: Z
Sampling Personnel: l (fit Screen Interval (ftTOC) �(.9 C7�
Type of Pump. �`71���G�G��G Tubing Material. Px\ �o\,r Pump/Tubing set at: ft
Weather Conditions: +p NOTES: ax Ilk
GROUNDWATER SAMPLING PARAMETERS
Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity
Time Level Pumped Rate {rr3gll] fLQ Slcm SOU , (mom (NTU)
}'Z�^ ►. .� / '-,V M i 1_5 r G -7 c6 rJ ��r 21 lCls 2c1 41 tsCJ
I Z L n-_,;� rn rl'I t Ml M '�, 'r + �, 1; • Zi to -4 . {o • ! `
12- U 7 - J.( .{cam 24 iii.�+] i--T 3 . to �d . I , t)' ) & L-1. 7
,-- ivr 1 `1 O _i ti ' U � '. `-i ilAi. -7 f —
Other Sample Parameters:
Sampled at: I2IS2 Parameters taken with: �� ��•� ter L.y�_� l () rU
Sample Delivered to: V'� ce- u L by
Field Filtration: ® Yes @ No If yes, which sample parameters were field filtered:
Sample Parameter Containers (Types, Number of Containers, Preservatives): A"" I
6T�_.'l Q\A\(. 0�\o �-
f�5lou NNU 9\w-A w \�
at
1 L � \u5\1�_uv) ��
bl I �Y �6 rnl _JI 0k' ;'11L'-AL aa4 7
0 \� )
"S:\BBB Master Templates\Farms - 2022 Farms\Low Flow Groundwater Sa`1mpli`ng Form.pdf' �/j , �1' 1 r �nA e c+ L `� C, aia❑n¢anon cnrena yumnnnes uom w, "m ...� � P.'."..V
Last Updated: 2/1412022 r'-1 vrl„M\voCS� a7' �l�Ml VAN I" i )QIU�v�"/L)4(A0 M �� 'Y Procedure for Groundwater Sampling, dated April 26, 201T

hart . hickman
SMARTER ENVIRONMENTAL SOLUTIONS
l LOW -FLOW GROUNDWATER j
` SAMPLING RECORD I
Facility Name:
Job No:
Well ID: 6/V w-2
Well Location: j� }r�,� KL
Date: N s 3 %2' 12-3
Top of Casing Elevation (ft msl): Casing Material: V L Volume of Water Per Well Volume: Z, ��� gallons
Total Well Depth (ftTOC): Depth to Water (ftTOC): ?:: 1._ Well Diameter: 2
Sampling Personnel: N "Ai") Screen Interval (ftToq: � `1 -
Type of Pump: Pit � c /l Tubing Material:. Pump/Tubing set at: i Z ft
Weather Conditions: ��� 1-q uol NOTES: F 1� " i
Stabilization Criteria
Primary: Secondary:
pH +/- 0.1 unit DO +/- 0.2 mg/L
S. Cond. +/- 5% ORP +/- 20 mV
Turb. +/- 10% (<10 NTUs for metals)
Water Level: slight or stable
drawdown during purging
GROUNDWATER SAMPLING PARAMETERS
Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity
Time Level Pumped Rate (moll) (VS/cm) SU mV NTU
--•�� �1,��_ --- I z '�liru I .0 1 1�� �� _ 1'lS.y 2,?a • 1
(1�' �U :n► 1'iL+ t+ t li �19 �LA y i Z
t �`[rcj 1'nl 1 i� :,,1 iRt C . 1rZI Li.z _ L T • (�
1-6 �1 ;� rA! 1 y. l s l l . lk . L� 46, L-1Gh i C16%
- Ll i ) ',CVf' 0A I ,'b 1 (� . 11 L� l "q L - I- - ;10 i
I1.1S Z.C1� `�75�,.n1 1 I-L U� � -t - 1CI I I 1,.0
11So 3_0�� Sct,n[ ISv �•o(o I`1.3 1 �,�
Other Sample Parameters:{•c�`Urc �' S7 L
Sampled at, 1 ( -S-b Parameters taken with:
Sample Delivered to: �),P5`^ev1��^ by FY AQ x at
Field Filtration: © Yes a No If yes, which sample parameters werfield filtered:
Sample Parameter Containers (Types, Number of Containers, Preservatives,. x L 4"kr' uA ems. Rc,l;bey { jy ++I 1 Ilc SFr,- UA ,...I RG13 5••]
/k 1 Itr +rT+te
moo nn��io. Tor.,�ia�ee11-1 - 2022 Forms\Low Flow Groundwater Sampling Farm.pdr' f I7 t _ I n 1 ., w � � -.. C 1L 11) T 100n G.�t�cr . _ ..�� 1 Slahldeation cgtanil gwduUnes horn the EPA SESD Operating
Last Updated: 2/1412022 — I-
1
$z7 0
C2� I c��ML C-4V' �.Ks �Crl,1 -

hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS
LOW -FLOW GROUNDWATER
SAMPLING RECORD
Facility Name'
Job No: I V I ! �01
Well ID: N� " ?�?Z•
Well Location:
Date: 7 �.� 1 (i
Top of Casing Elevation (ft msl): Casing Material:-,) Volume of Water Per Well Volume: �j ��0 gallons
Total Well Depth (ftTOC): �1-p Depth to Water (ftTOC): I s VA Well Diameter:
Sampling Personnel. Screen Interval (ftTOC): 7_
Type of Pu
Weather
Stabilization Criteria
Primary: Secondary:
pH +/- 0.1 unit DO +/- 0.2 mg/L
S. Cond. +/- 5% ORP +/- 20 mV
Turb. +/- 10% (<10 NTLIs for metals)
Water Level: slight or stable
drawdown during purging
Tubing Material: L Pump/Tubing set at: 14) ft
[� NOTES: 1��)�,•. 37. 07' b¢z,
GROUNDWATER SAMPLING PARAMETERS
Water Volume Pumping D❑ Temp. S. Cond. pH ORP Turbidity
Time Level Pumpqd Rate [mpll) f 0 S/cm (SU) (mv) fl\!TU�
1 b m v. �L\
t lti ' i �i- iuf­im4 L �
i U 2'L C\ _t w Mk 1 �I �b i L
e-
Other Sample Parameters: �e � %� ` < A —
Sampled at: U bq�' Parameters taken with: �5T' (�l�l=.kv (Jt
Sample Delivered to: �� by. r ' ' '' at
Field Filtration: ® Yes No If yes, which sample parameters were field filtered.
Sample Parameter Containers (Types, Number of Containers, Preservatives)�2.0 ftM$_KyNn�e5 VrQC CkApe `oti� 1 l.Pltn Uko t. �ob 5�6
'hqo m\ m V i1A�V' 00\ uAq\ l �`��',L' 4 V"�1 1 S1 L� rv�\ ��� u 11�� j(X U) `� t��'r�1 +?!� AQ%m iV t w �5�i v i�� � Um' �w\ v [�
mlu!n ,LQ\Nw--uo\ w51t i inn lv� y.brnl Q1w*A IsN -q-j1 11� Mk 1�lµi I ,tio WO W1 ft\ Q`aihA
"S:\BBB Master Templates\Forms - 2022 Forms\Low Flow Groundwater Sampling Farm.pd?'�l'�� l`kS�C N QUA \0 t' [. �'^r`�V ' `r IC V M i hidrr U" y"o,mauor, cnreria gwaeanes rrom me err\ aeau Uperaang
Lest Updated:2114/202Z �y�tuti'mr,IN,��A�i'9n 11\rocedure for Groundwater Sampling, dated April 26, 2017.

hart " hickman
W
SMARTER ENVIRONMENTAL SOLUTIONS
LOW -FLOW GROUNDWATER
SAMPLING RECORD
Facility Name: �rw�v�«e. (2" J�J� r\cr LF
Stabilization Criteria
Primary: Secondary:
pH +/- 0.1 unit DO +/- 0.2 mg/L
S. Cond. +/- 5% ORP +1- 20 mV
Job No: G k -oo J
Turb. +1- 10% (<10 NTLls for metals) Well ID: /('k LJ Lj
1Water Level: slight or stable
drawdown during purging Well Location:
Date: ? ll1 - h'3
Top of Casing Elevation (ft msl): Casing Material: PVC_ Volume of Water Per Well Volume: gallons
Total Well Depth (ftTOC): 3 2 ° Depth to Water (ftTOC): 62' Well Diameter: 2
Sampling Personnel:_ e Cc,ycv Screen Interval (ftTOC): -
1
Type of Pump: Pe nS � � _ Tubing Material:LP PPump/Tubing set at: Z S ft
Weather Conditions: sl -\ .t 5NOTES �N• ' _-�- �� its.. 3 1 . ��{
GROUNDWATER SAMPLING PARAMETERS
Water
Volume
Pumping
DO
Temp.
S. Cond.
pH
ORP
Turbidity
Time
Level
Pumped
Rate
m !1
°C
S/cm
(SSU_)
��
NTU
fau+K!%h•
r
3.3-7
1. rg.
500 tit.
I ob
b. 3-S
/: 1
ts-r 3
44`�
L
1 dut 2
10b
z
�• cat
-r� .�
n . oZ
— 3 �'
0-7-1
S (2&
f tv
�. l �_
! S_ - K
l SN Z
7 r,
� Z.>3.
-o . e>t
i�gll
�4G 3-
ZL-be
-LS00
raD
��
�. • �1
JS�-(I
�. L3
_ 2aG- `t
/Cl, -7
0-02
Ia51
10-IS
iGV
n-ti
/S`?1
7,LZ
Z
p-o2
Other Sample Parameters:
Sampled at: l� D Parameters taken with:
Sample Delivered to:. V(I Q, �S�w by
Field Filtration: ©Yes 0 No If yes, which sample parameters
Sample Parameter Containers (Types, Number of Containers,
'2(ub
at
field filtered: 1M. 1 / C— U /F + ( i
�-e< i[ G iJer e n s frtl ; u�5 fI C Z J VIzL Hbo, Aft I 11 ftkJ5
ICV,.EL —)%,r .,., .v 7-) I < %ahL w�_�--.7,/J;(.434..
"S:\BBB Master Templates\Forms - 2022 Forms\Low Flow Groundwater Sampling Form.pdf' Stabilization criteria guidelines from the EPA SESD Operating
Last Updated: 2/1412022 Procedure for Groundwater Sampling, dated April 26, 2017.

hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS
LOW -FLOW GROUNDWATER
SAMPLING RECORD
Stabilization Criteria
Primary: Secondary:
pH +/- 0.1 unit DO +/- 0.2 mg/L
S. Cond. +/- 5% ORP +/- 20 mV
Turb. +/- 10% (<10 NTUs for metals)
Water Level: slight or stable
drawdown during purging
Job No:
Well ID:
Well Location:
Facility Name: � r ,� r, D. C �- _� d �; 1( Date: � 2'� /Z3
Top of Casing Elevation (ft msl): Casing Material lPU C Volume of Water Per Well Volume:
Total Well Depth (ftTOC): - S . "\ Depth to Water (ftTOC): 3 Well Diameter: 2 L�
Sampling Personnel: CC_-rranL4, Screen Interval (ftTOC): -
Type of Pump: Tubing Material: Pump/Tubing set at: 'L 7
Weather Conditions: N�r--r4l C NOTES: b
^`.f8• -� L4.K 2 3 • -S /
gallons
ft
Lo C
GROUNDWATER SAMPLING PARAMETERS
Water Volume
Pumping DO Temp.
S. Cond. pH
ORP
Turbidity
Time Level Pumped
Rate (mall) (°C)
S/cm (SSUS
mV
(NTU)
0 0..1
I'ai„k,1... 3 Hz. rs. 3
ls� _l7 LA-'1"t
-20-L'
t't
\-(Va -� •_S-'l )S. �3
1 la(�� 3 S­- it
5f.c.ca
5:71 ` 'I I e, C2 L?
1100 '3
(.e7{b - .13
-381.I
4 ,�
15 (Q f�bC�
lUy �.=5�— 1'S❑
C7��C� �a3
-31s�i
W�.�
ISLA -L�[a
1C20 S, l
1(�z�1Lj
15�� CSC
rvU 3•`ili z
rCe3� �.�zr�
-�✓s•t
Z-�3
t00 '�.3'1 r.� Z
Tf
-Z_
��
u j 1
1 r 5 -L GL S 7
Other Sample Parameters:_�/(J�
Sampledat: �SS(
Parameters taken with:
Sample Delivered to: c cvc_2_. �C1 e�h�`
L by I e-, M_X
at
Field Filtration: ®Yes @ No
If yes, which sample parameters were field filtered:
Sample Parameter Containers (Types, Number of Containers, Preservatives):
n,=2 encrA.- l S /xc
ZL_ L ft
( !s)
�/Z.S,L ��-��. 5�i l �ozs-i,L
44.6R C ,,&� 6,1�,.� �., r
S� s �-���1 ��� ��,� �,�_
"S:\BBB Master Templates\Forms - 2022 Farms\Low Flow Groundwater Sampling Form.pdf' zliaDwzamon cmena guioeimes from me trr, ocou uperamng
Last Updated: 2/14/2022 Procedure for Groundwater Sampling, dated April 26, 2017.

hart W hickman
SMARTER ENVIRONMENTAL SOLUTIONS
LOW -FLOW GROUNDWATER
SAMPLING RECORD
Facility Name: �31-nVw�\,l. CPv
`11
Job No: L -r V S.JIJ�
Well ID:
Well Location:
Date: l2`� �n�•?j
I
Top of Casing Elevation (ft msl): Casing Material - Volume of Water Per Well Volume: gallons
Total Well Depth (ftTOC): Depth to Water (ftTOC):�% Well Diameter:
Sampling Personnel. MNZ )� 3 Screen Interval (ftTOC):
Type of Pump: Pe" \ Tubing Material:_ Pump/Tubing set at: 2 ft
Stabilization Criteria
Primary: Secondary:
pH +/- 0.1 unit DO +/- 0.2 mg/L
S. Cond. +/- 5% ORP +/- 20 mV
Turb. +/- 10% (<10 NTUs for metals)
Water Level: slight or stable
drawdown during purging
1 :k
ilJt+�l1
Weather Conditions: [�sl.$'S k _ �� �� 1 NOTES: 7 c� •� ;�
GROUNDWATER SAMPLING PARAMETERS
Water
Volume
Pumping
DO
Temp.
S. Cond.
pH
ORP
Turbidity
Time
Level
Pumped
Rate
(ma/I)
(OC)(VS/cm)
SU
(MV)
(NTU)
Z'%o
`
-1
16'►
�j
63Li ml
C2�? -A
1 5
t�
e4�
` 1'�
k `a 7
l ZS
1. \ C-'�-
Vas ml
ibb- 1 r
t-\(O
W•S
5�
(0.5�
VI0.0%
y L4q
ll.06
l bo�m1
5UeMn\
1 •'-1L
�U,3
U 1�0 1—
i0,U3
11i?3`{1
l� �a�i
�i
"�t V�
_
11a. L
5��
(S ,(05
t (0 15•\
U • 72
Other Sample Parameters:
Sampled at- � L� lFb
Sample Delivered to: I: um : m') IN
Parameters taken with: 1 2A00
by I;-- P �` �'(� at
Field Filtration: ® Yes (.') No If yes, which sample parameters were field filtered:
Sample Parameter Containers (Types, Number of Containers, Preservatives): LZ`t 1 �tv V-'Lf nor 1Ic lb►ekty1) I i �z m]
i' n 1 k�l� l2s hn lI vt4TW 4' % 04 L W O C A� t IN I00MI A
C2'�tuum)i P-"r>r.?Vu Un A9 .II1i � 5 r�c:�e516W-, Uk),nvVy) Mq�� kW. `j11 pC00 L_%,v.tium) mow" •yoM y>-.4 \!Q%. )
'S:\BBB Master Templates\Forms - 2022 Forms\Low Flow Groundwater Sampling Form.pdf' C5'x 1r Q'M � P�MIOA'( v0 NON— 1 ' 101U)C(k - \ Stabilization criteria guidelines from the EPA SESD Operating
Last Updated: 2/14/2022 J Procedure for Groundwater Sampling, dated April 26, 2017.

hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS
LOW -FLOW GROUNDWATER
SAMPLING RECORD
Stabilization Criteria
Primary: Secondary:
pH +/- 0.1 unit DO +/- 0.2 mg/L
S. Cond. +/- 5% ORP +/- 20 mV
Turb. +/- 10% (<10 NTUs for metals)
Water Level: slight or stable
drawdown during purging
Job No
6' � , &�
Well ID: /c/ E5
Well Location:
Facility Name: r� .vcl �� ,,1—r
�Jv �c�— L 1�
Date: .3 /2 $ -t3
Top of Casing Elevation (ft rnsl):
Casing Material: VC Volume of Water Per Well Volume:
gallons
Total Well Depth (ftTOC): 3 3- `V
Depth to Water (ftTOC):
Well Diameter:
2
Sampling Personnel: cc"c I
Screen Interval (ftTOC)
Type of Pump:
Tubing Material. LICIFE
Pump/Tubing set at: �" 2
ft
Weather Conditions: g�nr� �S Ul_
NOTES: e k,,4f -32'
GROUNDWATER SAMPLING PARAMETERS
Water Volume
Pumping D❑ Temp.
S. Cond. pH
ORP
Turbidity
Time Level Pumped
r Rate imsim C—C-1
7S/cm (�
��
(NTU)
r 4pi g ' Hrx7C—
��`'i �
�-22C2
._fi r i-�- 1�i.5
l r Ica _ 0.1
13 '3 `f}
�C- Z
7— S
%-7
`�
t d 3 �� Wiz.^
U22 t. o� l
fr���.(4
3�
lore t _�t�-- l�.i�
�i�. Z_
''
— ` C)Nk
Other Sample Parameters: Q•2k
Sampled at: li L
_ Parameters taken with. 7
2 fo00
Sample Delivered to: l�� _��n.c.V t1� L by
at
Field Filtration: ® Yes No
If yes, which sample parameters were field filtered:
/
S I Parameter Containers (T pes Number of Containers Preservatives): r )F V" ",_ 5 IR�rGk�e�
l
ampe y
/( n�Lu�x25?nL
5�c Vraas • s. qO TL4
'SABBB Master Templates\Fonns - 2022 Forms\Low Flow Groundwater Sampling Form.pdf' / � Stabilization criteria guidelines from the EPA SESD Operating
Last Updated: 2/14/2022 I k�'�T 4,t "�J�`v�SAI�} Procedure for Groundwater Sampling, dated April 26, 2017.

® Surface Water Sampling Form
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS GENERAL INFORMATION
\
Job No.: (,NL1 . on Location No.:�kYkt.! lit-- Date: Z� �'3
Site Name: Lart villa UuA4 ?4nt, Le Location:
Sample Type (�) Grab (❑) Composite (❑) Other �~
Sampling Equipment ([d) Dedicated (❑) Decontaminated (❑) Bailer (❑) Pu�m"p" r.
Material (❑) PVC (❑) Stainless Steel (❑) Teflon ([A) Other (I -
Decontamination Method. Aiconox and Di Water Rinse
LOCATION INFORMATION
Coordinates: r -
Sample Location Dimentions Width Depth to Stream Bed N
PURGING INFORMATION
Time
PH
(SU)
Temp. S. Cond.
(°C) umhos/cm
Redox
Turbidity
(NTT
114
'-lSiAl
r --1 d
(J I Weather Conditions: t7VCiiLC�'S r
Sample Condition: (* Clear (❑) Cloudy
Field Filtration: (❑) Yes (56 No
ainers (Types Numb.e�rs,
�x ��c7Ml Nl��7s
Comments:
(❑) Other.
`0d
1-Z-1
Odor: nov%A-
vt>c
Sample Collector: Nyy 1 Date o v&me:—Luz-b
File: SW Sampling Log, SW Form
Date: 2/20/2018

Surface Water Sampling Form
hart ® hickman
SMARTER ENVIRONMENTAL SOLUTIONS GENERAL INFORMATION rr
Job No.: (3v\&57. C50`3 Location No.: (UA-Vt r NL Date:
Site Name: C-�{iLty it I! P"M Location: S Z
Sample Type () Grab (❑) Composite (❑) Other
Sampling Equipment ([ Dedicated (❑) Decontaminated (❑) Bailer (❑) Pump
Material (❑) PVC (❑) Stainless Steel (❑) Teflon (0) OtherAM
Decontamination Method Alconox and DI Water Rinse
LOCATION INFORMATION
Coordinates: � N
Sample Location Dimentions Width N Depth to Stream Bed_
PURGING INFORMATION
Time
pH
(SU)
Temp.
C)
S. Cond.
(umhos/cm)
Redox
Turbidity
(NT
(07 45
vi.%
33L-L 2-
14q.4
Weather Conditions: 0Vt (CA G-, v `
Sample Condition: (J�j) Clear (❑) Cloudy (❑) Other:
Field Filtration: (❑) Yes ([�]) No
Containers (Types, Numbers,
(lx7<-hWLL �kNOl
Comments
Sample Collector:
AM`)
File: SW Sampling Log, SW Form
Date: 2/20/2018
V6
�— Odor: � 01"',
Date: Zti� Time: i V15

Appendix B
Laboratory Analytical Report
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
May 05, 2023
Jeffrey 011ison
Hart & Hickman
3921 Sunset Ridge Rd.
Ste. 301
Raleigh, NC 27607
RE: Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Dear Jeffrey 011ison:
Enclosed are the analytical results for sample(s) received by the laboratory on March 29, 2023. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace National - Mt. Juliet
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor M Cannon
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 155

laneAnalytical
www,pacelabs.com
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Pace Analytical Services National
12065 Lebanon Road, Mt. Juliet, TN 37122
Alabama Certification #: 40660
Alaska Certification 17-026
Arizona Certification #: AZ0612
Arkansas Certification #: 88-0469
California Certification #: 2932
Canada Certification #: 1461.01
Colorado Certification #: TN00003
Connecticut Certification #: PH-0197
DOD Certification: #1461.01
EPA# TN00003
Florida Certification #: E87487
Georgia DW Certification #: 923
Georgia Certification: NELAP
Idaho Certification #: TN00003
Illinois Certification #: 200008
Indiana Certification #: C-TN-01
Iowa Certification #: 364
Kansas Certification #: E-10277
Kentucky UST Certification #: 16
Kentucky Certification #: 90010
Louisiana Certification #: A130792
Louisiana DW Certification #: LA180010
Maine Certification #: TN0002
Maryland Certification #: 324
Massachusetts Certification #: M-TNO03
Michigan Certification #: 9958
Minnesota Certification #: 047-999-395
Mississippi Certification #: TN00003
Missouri Certification #: 340
Montana Certification M CERT0086
Nebraska Certification #: NE-OS-15-05
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
CERTIFICATIONS
Nevada Certification #: TN-03-2002-34
New Hampshire Certification #: 2975
New Jersey Certification #: TNO02
New Mexico DW Certification
New York Certification #: 11742
North Carolina Aquatic Toxicity Certification #: 41
North Carolina Drinking Water Certification #: 21704
North Carolina Environmental Certificate #: 375
North Dakota Certification #: R-140
Ohio VAP Certification #: CL0069
Oklahoma Certification #: 9915
Oregon Certification #: TN200002
Pennsylvania Certification #: 68-02979
Rhode Island Certification #: LA000356
South Carolina Certification #: 84004
South Dakota Certification
Tennessee DW/Chem/Micro Certification #: 2006
Texas Certification #: T 104704245-17-14
Texas Mold Certification #: LAB0152
USDA Soil Permit #: P330-15-00234
Utah Certification #: TN00003
Virginia Certification #: VT2006
Vermont Dept. of Health: ID# VT-2006
Virginia Certification #: 460132
Washington Certification #: C847
West Virginia Certification #: 233
Wisconsin Certification #: 998093910
Wyoming UST Certification #: via A21-A 2926.01
A21-A-ISO 17025 Certification #: 1461.01
A21-A-ISO 17025 Certification #: 1461.02
AIHA-LAP/LLC EMLAP Certification #:100789
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92659555001
MW-1R
Water
03/28/2312:52
03/29/23 10:30
92659555002
MW-2R
Water
03/28/2311:50
03/29/23 10:30
92659555003
MW-3R
Water
03/28/2310:50
03/29/23 10:30
92659555004
SW-1
Water
03/28/23 00:00
03/29/23 10:30
92659555005
SW-2
Water
03/28/23 00:00
03/29/23 10:30
92659555006
NES-1
Water
03/28/2310:43
03/29/23 10:30
92659555007
MW-4
Water
03/28/2314:02
03/29/23 10:30
92659555008
MW-5
Water
03/28/2315:56
03/29/23 10:30
92659555009
MW-6
Water
03/28/2314:32
03/29/23 10:30
92659555010
FIELD BLANK
Water
03/28/23 15:55
03/29/23 10:30
92659555011
TB
Water
03/28/23 00:00
03/29/23 10:30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
GM1.003 BUTNER LANDFILL
92659555
Analytes
Lab lD
Sample ID
Method
Analysts
Reported
Laboratory
92659555001
MW-1R
EPA8151A
NWH
5
PAN
EPA 8081 B
SEM
21
PASI-C
EPA 8082A
BAJ
8
PASI-C
RSK 175 Modified
TEG
1
PASI-C
EPA 601 OD
ABL
15
PAN
EPA 6020E
LD
1
PAN
EPA 7470A
NDL
1
PAN
EPA 8270E
PKS
112
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
EPA 8260D
TMH
67
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
SM 521OB-2016
MDM
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
ANM
1
PASI-A
SM 4500-CN-E-2016
ANM
1
PASI-A
SM 5220D-2011
MAB2
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92659555002
MW-2R
EPA8151A
NWH
5
PAN
EPA 8081 B
SEM
21
PASI-C
EPA 8082A
BAJ
8
PASI-C
RSK 175 Modified
TEG
1
PASI-C
EPA 601 OD
ABL
15
PAN
EPA 6020E
LD
1
PAN
EPA 7470A
NDL
1
PAN
EPA 8270E
PKS
112
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
EPA 8260D
TMH
67
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
SM 521OB-2016
MDM
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
ANM
1
PASI-A
SM 4500-CN-E-2016
ANM
1
PASI-A
SM 5220D-2011
MAB2
1
PASI-A
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 4 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
SM 531OB-2014
MJP
1
PASI-A
92659555003
MW-3R
EPA8151A
NWH
5
PAN
EPA 8081 B
SEM
21
PASI-C
EPA 8082A
BAJ
8
PASI-C
RSK 175 Modified
TEG
1
PASI-C
EPA 601 OD
ABL
15
PAN
EPA 6020E
LD
1
PAN
EPA 7470A
NDL
1
PAN
EPA 8270E
PKS
112
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
EPA 8260D
TMH
67
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
SM 521OB-2016
MDM
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
ANM
1
PASI-A
SM 4500-CN-E-2016
ANM
1
PASI-A
SM 5220D-2011
MAB2
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92659555004
SW-1
EPA 601 OD
CCE
14
PAN
EPA 6020E
LD
1
PAN
EPA 8260D
CL
50
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
SM2340-97
CCE
1
PAN
92659555005
SW-2
EPA 601 OD
CCE
14
PAN
EPA 6020E
LD
1
PAN
EPA 8260D
CL
50
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
SM2340-97
CCE
1
PAN
92659555006
NES-1
RSK 175 Modified
TEG
1
PASI-C
EPA 601 OD
ABL
1
PAN
EPA 8260D
JJK
4
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 521OB-2016
MDM
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
REPORT OF LABORATORY ANALYSIS
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lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
ANM
1
PASI-A
SM 5220D-2011
JP1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92659555007
MW-4
EPA8151A
NWH
5
PAN
EPA 8081 B
SEM
21
PASI-C
EPA 8082A
BAJ
8
PASI-C
EPA 601 OD
ABL
15
PAN
EPA 6020E
LD
1
PAN
EPA 7470A
NDL
1
PAN
EPA 8270E
PKS
112
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
EPA 8260D
TMH
67
PASI-C
SM 4500-S2D-2011
JP1
1
PASI-A
SM 4500-CN-E-2016
ANM
1
PASI-A
92659555008
MW-5
EPA8151A
NWH
5
PAN
EPA 8081 B
SEM
21
PASI-C
EPA 8082A
BAJ
8
PASI-C
EPA 601 OD
ABL
15
PAN
EPA 6020E
LD
1
PAN
EPA 7470A
NDL
1
PAN
EPA 8270E
PKS
112
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
EPA 8260D
TMH
67
PASI-C
SM 4500-S2D-2011
JP1
1
PASI-A
SM 4500-CN-E-2016
ANM
1
PASI-A
92659555009
MW-6
EPA8151A
NWH
5
PAN
EPA 8081 B
SEM
21
PASI-C
EPA 8082A
BAJ
8
PASI-C
EPA 601 OD
ABL
15
PAN
EPA 6020E
LD
1
PAN
EPA 7470A
NDL
1
PAN
EPA 8270E
PKS
112
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
EPA 8260D
TMH
67
PASI-C
SM 4500-S2D-2011
JP1
1
PASI-A
SM 4500-CN-E-2016
ANM
1
PASI-A
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 6 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Analytes
Lab lD Sample ID
Method
Analysts
Reported
Laboratory
92659555010 FIELD BLANK
EPA8151A
NWH
5
PAN
EPA 8081 B
SEM
21
PASI-C
EPA 8082A
BAJ
8
PASI-C
EPA 601 OD
ABL
15
PAN
EPA 6020E
LD
1
PAN
EPA 7470A
NDL
1
PAN
EPA 8270E
PKS
112
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
EPA 8260D
TMH
67
PASI-C
SM 4500-S2D-2011
JP1
1
PASI-A
SM 4500-CN-E-2016
ANM
1
PASI-A
92659555011 TB
EPA 8260D
TMH
67
PASI-C
PAN = Pace National - Mt. Juliet
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
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lceAnalyircal
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MWAR
Lab ID:
92659555001
Collected:
03/28/23 12:52
Received: 03/29/23 10:30 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
Chlorinated Herb. (GC) 8151A
Analytical
Method: EPA 8151A
Preparation Method: 8151A
Pace National
- Mt. Juliet
2,4-D
ND
ug/L
2.00
0.547
1
04/04/23 14:45
04/06/23 10:42
94-75-7 R1
Dinoseb
ND
ug/L
2.00
0.250
1
04/04/23 14:45
04/06/23 10:42
88-85-7
2,4,5-T
ND
ug/L
2.00
0.258
1
04/04/23 14:45
04/06/23 10:42
93-76-5 R1
2,4,5-TP (Silvex)
ND
ug/L
2.00
0.335
1
04/04/23 14:45
04/06/23 10:42
93-72-1 R1
Surrogates
2,4-DCAA (S)
44.7
%
14.0-158
1
04/04/23 14:45
04/06/23 10:42
19719-28-9
8081 OC Pesticides RVE
Analytical
Method: EPA 8081
B Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
Aldrin
ND
ug/L
0.045
0.013
1
04/04/23 10:24
04/05/23 11:59
309-00-2
alpha-BHC
ND
ug/L
0.045
0.011
1
04/04/23 10:24
04/05/23 11:59
319-84-6
beta-BHC
ND
ug/L
0.045
0.044
1
04/04/23 10:24
04/05/23 11:59
319-85-7
delta-BHC
ND
ug/L
0.045
0.013
1
04/04/23 10:24
04/05/23 11:59
319-86-8
gamma-BHC (Lindane)
ND
ug/L
0.045
0.011
1
04/04/23 10:24
04/05/23 11:59
58-89-9
Chlordane (Technical)
ND
ug/L
0.45
0.14
1
04/04/23 10:24
04/05/23 11:59
57-74-9
4,4'-DDD
ND
ug/L
0.045
0.015
1
04/04/23 10:24
04/05/23 11:59
72-54-8
4,4'-DDE
ND
ug/L
0.045
0.022
1
04/04/23 10:24
04/05/23 11:59
72-55-9
4,4'-DDT
ND
ug/L
0.045
0.023
1
04/04/23 10:24
04/05/23 11:59
50-29-3
Dieldrin
ND
ug/L
0.045
0.014
1
04/04/23 10:24
04/05/23 11:59
60-57-1
Endosulfan I
ND
ug/L
0.045
0.016
1
04/04/23 10:24
04/05/23 11:59
959-98-8
Endosulfan 11
ND
ug/L
0.045
0.014
1
04/04/23 10:24
04/05/23 11:59
33213-65-9
Endosulfan sulfate
ND
ug/L
0.045
0.013
1
04/04/23 10:24
04/05/23 11:59
1031-07-8
Endrin
ND
ug/L
0.045
0.016
1
04/04/23 10:24
04/05/23 11:59
72-20-8
Endrin aldehyde
ND
ug/L
0.045
0.015
1
04/04/23 10:24
04/05/23 11:59
7421-93-4
Heptachlor
ND
ug/L
0.045
0.018
1
04/04/23 10:24
04/05/23 11:59
76-44-8
Heptachlor epoxide
ND
ug/L
0.045
0.026
1
04/04/23 10:24
04/05/23 11:59
1024-57-3
Methoxychlor
ND
ug/L
0.14
0.038
1
04/04/23 10:24
04/05/23 11:59
72-43-5
Toxaphene
ND
ug/L
0.45
0.20
1
04/04/23 10:24
04/05/23 11:59
8001-35-2
Surrogates
Tetrachloro-m-xylene (S)
86
%
10-182
1
04/04/23 10:24
04/05/23 11:59
877-09-8
Decachlorobiphenyl (S)
125
%
10-200
1
04/04/23 10:24
04/05/23 11:59
2051-24-3
8082 GCS PCB RVE
Analytical
Method: EPA 8082A
Preparation Method:
EPA 3510C
Pace Analytical
Services
- Charlotte
PCB-1016 (Aroclor 1016)
ND
ug/L
0.43
0.18
1
04/05/23 22:15
04/07/23 12:54
12674-11-2
PCB-1221 (Aroclor 1221)
ND
ug/L
0.43
0.20
1
04/05/23 22:15
04/07/23 12:54
11104-28-2
PCB-1232 (Aroclor 1232)
ND
ug/L
0.43
0.20
1
04/05/23 22:15
04/07/23 12:54
11141-16-5
PCB-1242 (Aroclor 1242)
ND
ug/L
0.43
0.22
1
04/05/23 22:15
04/07/23 12:54
53469-21-9
PCB-1248 (Aroclor 1248)
ND
ug/L
0.43
0.25
1
04/05/23 22:15
04/07/23 12:54
12672-29-6
PCB-1254 (Aroclor 1254)
ND
ug/L
0.43
0.18
1
04/05/23 22:15
04/07/23 12:54
11097-69-1
PCB-1260 (Aroclor 1260)
ND
ug/L
0.43
0.14
1
04/05/23 22:15
04/07/23 12:54
11096-82-5
Surrogates
Decachlorobiphenyl (S)
115
%
10-193
1
04/05/23 22:15
04/07/23 12:54
2051-24-3
Date: 05/05/2023 12:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MWAR
Lab ID:
92659555001
Collected:
03/28/23 12:52
Received: 03/29/23 10:30 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
RSK 175 Headspace
Analytical
Method: RSK 175
Modified
Pace Analytical
Services - Charlotte
Methane
ND
ug/L
10.0
5.3
1
03/31/2316:24
74-82-8
Metals (ICP) 6010D
Analytical
Method: EPA 601 OD Preparation Method:
3015
Pace National
- Mt. Juliet
Antimony
ND
ug/L
10.0
4.30
1
04/02/2312:18
04/03/2312:24
7440-36-0
Arsenic
ND
ug/L
10.0
4.40
1
04/02/2312:18
04/03/2312:24
7440-38-2
Barium
2.24J
ug/L
5.00
0.736
1
04/02/2312:18
04/03/2312:24
7440-39-3 J
Beryllium
ND
ug/L
2.00
0.330
1
04/02/2312:18
04/03/2312:24
7440-41-7
Cadmium
ND
ug/L
2.00
0.479
1
04/02/2312:18
04/03/2312:24
7440-43-9
Chromium
ND
ug/L
10.0
1.40
1
04/02/2312:18
04/03/2312:24
7440-47-3
Cobalt
ND
ug/L
10.0
0.840
1
04/02/2312:18
04/03/2312:24
7440-48-4
Copper
ND
ug/L
10.0
3.68
1
04/02/2312:18
04/03/2312:24
7440-50-8
Lead
ND
ug/L
6.00
2.99
1
04/02/2312:18
04/03/2312:24
7439-92-1
Nickel
ND
ug/L
10.0
1.61
1
04/02/2312:18
04/03/2312:24
7440-02-0
Selenium
ND
ug/L
10.0
7.35
1
04/02/2312:18
04/03/2312:24
7782-49-2
Silver
ND
ug/L
5.00
1.54
1
04/02/2312:18
04/03/2312:24
7440-22-4
Tin
ND
ug/L
50.0
4.87
1
04/02/2312:18
04/03/2312:24
7440-31-5
Vanadium
ND
ug/L
20.0
4.99
1
04/02/2312:18
04/03/2312:24
7440-62-2
Zinc
ND
ug/L
50.0
6.52
1
04/02/2312:18
04/03/2312:24
7440-66-6
Metals (ICPMS) 6020B
Analytical
Method: EPA 6020E Preparation Method: 3015
Pace National
- Mt. Juliet
Thallium
ND
ug/L
2.00
0.121
1
04/03/2317:07
04/04/2319:15
7440-28-0
Mercury 7470A
Analytical
Method: EPA 7470A Preparation Method: 7470A
Pace National
- Mt. Juliet
Mercury
ND
ug/L
0.200
0.100
1
04/05/2315:29
04/07/2312:03
7439-97-6
8270E APP9 RV
Analytical
Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services - Charlotte
Acenaphthene
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 15:15
83-32-9
Acenaphthylene
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 15:15
208-96-8
Acetophenone
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 15:15
98-86-2
2-Acetylaminofluorene
ND
ug/L
8.3
3.4
1
04/01/23 12:01
04/02/23 15:15
53-96-3
4-Aminobiphenyl
ND
ug/L
8.3
4.0
1
04/01/23 12:01
04/02/23 15:15
92-67-1
Anthracene
ND
ug/L
8.3
1.9
1
04/01/23 12:01
04/02/23 15:15
120-12-7
Benzo(a)anthracene
ND
ug/L
8.3
2.2
1
04/01/23 12:01
04/02/23 15:15
56-55-3
Benzo(a)pyrene
ND
ug/L
8.3
2.3
1
04/01/23 12:01
04/02/23 15:15
50-32-8
Benzo(b)fluoranthene
ND
ug/L
8.3
2.2
1
04/01/23 12:01
04/02/23 15:15
205-99-2
Benzo(g,h,i)perylene
ND
ug/L
8.3
2.4
1
04/01/23 12:01
04/02/23 15:15
191-24-2
Benzo(k)fluoranthene
ND
ug/L
8.3
2.3
1
04/01/23 12:01
04/02/23 15:15
207-08-9
Benzyl alcohol
ND
ug/L
16.7
2.4
1
04/01/23 12:01
04/02/23 15:15
100-51-6
4-Bromophenylphenyl ether
ND
ug/L
8.3
1.5
1
04/01/23 12:01
04/02/23 15:15
101-55-3
Butylbenzylphthalate
ND
ug/L
8.3
2.6
1
04/01/23 12:01
04/02/23 15:15
85-68-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 9 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MWAR Lab ID: 92659555001 Collected: 03/28/23 12:52 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
4-Chloro-3-methyl phenol
ND
ug/L
8.3
2.8
1
04/01/23 12:01
04/02/23 15:15
59-50-7
4-Chloroaniline
ND
ug/L
16.7
3.0
1
04/01/23 12:01
04/02/23 15:15
106-47-8
Chlorobenzilate
ND
ug/L
8.3
3.2
1
04/01/23 12:01
04/02/23 15:15
510-15-6
bis(2-Chloroethoxy)methane
ND
ug/L
8.3
1.5
1
04/01/23 12:01
04/02/23 15:15
111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 15:15
111-44-4
2-Chloronaphthalene
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 15:15
91-58-7
2-Chlorophenol
ND
ug/L
8.3
1.0
1
04/01/23 12:01
04/02/23 15:15
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 15:15
7005-72-3
Chrysene
ND
ug/L
8.3
2.3
1
04/01/23 12:01
04/02/23 15:15
218-01-9
Diallate
ND
ug/L
8.3
2.8
1
04/01/23 12:01
04/02/23 15:15
2303-16-4
Dibenz(a,h)anthracene
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 15:15
53-70-3
Dibenzofuran
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 15:15
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
16.7
6.8
1
04/01/23 12:01
04/02/23 15:15
91-94-1
2,4-Dichlorophenol
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 15:15
120-83-2
2,6-Dichlorophenol
ND
ug/L
8.3
3.5
1
04/01/23 12:01
04/02/23 15:15
87-65-0
Diethylphthalate
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 15:15
84-66-2
Dimethoate
ND
ug/L
8.3
3.0
1
04/01/23 12:01
04/02/23 15:15
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
4.2
2.0
1
04/01/23 12:01
04/02/23 15:15
60-11-7
7,12-Dimethylbenz(a)anthracene
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 15:15
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
41.7
25.9
1
04/01/23 12:01
04/02/23 15:15
119-93-7
2,4-Dimethylphenol
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 15:15
105-67-9
a,a-Dimethylphenylethylamine
ND
ug/L
83.3
51.7
1
04/01/23 12:01
04/02/23 15:15
122-09-8
Dimethylphthalate
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 15:15
131-11-3
Di-n-butylphthalate
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 15:15
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
16.7
6.5
1
04/01/23 12:01
04/02/23 15:15
534-52-1
1,3-Dinitrobenzene
ND
ug/L
8.3
3.1
1
04/01/23 12:01
04/02/23 15:15
99-65-0
2,4-Dinitrophenol
ND
ug/L
41.7
21.7
1
04/01/23 12:01
04/02/23 15:15
51-28-5
2,4-Dinitrotoluene
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 15:15
121-14-2
2,6-Dinitrotoluene
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 15:15
606-20-2
Di-n-octylphthalate
ND
ug/L
8.3
3.3
1
04/01/23 12:01
04/02/23 15:15
117-84-0
Diphenylamine
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 15:15
122-39-4
Disulfoton
ND
ug/L
8.3
3.9
1
04/01/23 12:01
04/02/23 15:15
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
5.0
3.1
1
04/01/23 12:01
04/02/23 15:15
117-81-7
Ethyl methanesulfonate
ND
ug/L
16.7
2.5
1
04/01/23 12:01
04/02/23 15:15
62-50-0
Famphur
ND
ug/L
8.3
5.1
1
04/01/23 12:01
04/02/23 15:15
52-85-7
Fluoranthene
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 15:15
206-44-0
Fluorene
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 15:15
86-73-7
Hexachlorobenzene
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 15:15
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
8.3
1.3
1
04/01/23 12:01
04/02/23 15:15
77-47-4
Hexachloroethane
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 15:15
67-72-1
Hexachloropropene
ND
ug/L
8.3
2.2
1
04/01/23 12:01
04/02/23 15:15
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
8.3
2.4
1
04/01/23 12:01
04/02/23 15:15
193-39-5
Isodrin
ND
ug/L
8.3
2.3
1
04/01/23 12:01
04/02/23 15:15
465-73-6
Isophorone
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 15:15
78-59-1
Isosafrole
ND
ug/L
8.3
2.1
1
04/01/23 12:01
04/02/23 15:15
120-58-1
REPORT OF LABORATORY ANALYSIS
M1
IL
L1,M0
IH,R1
L1,M0
M1,v2
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MWAR Lab ID: 92659555001 Collected: 03/28/23 12:52 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Kepone
ND
ug/L
16.7
11.8
1
04/01/23 12:01
04/02/23 15:15
143-50-0
Methapyrilene
ND
ug/L
41.7
14.2
1
04/01/23 12:01
04/02/23 15:15
91-80-5
3-Methylcholanthrene
ND
ug/L
8.3
3.1
1
04/01/23 12:01
04/02/23 15:15
56-49-5
Methyl methanesulfonate
ND
ug/L
4.2
2.6
1
04/01/23 12:01
04/02/23 15:15
66-27-3
2-Methylnaphthalene
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 15:15
91-57-6
Methyl parathion
ND
ug/L
8.3
3.1
1
04/01/23 12:01
04/02/23 15:15
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 15:15
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
8.3
1.0
1
04/01/23 12:01
04/02/23 15:15
15831-10-4
1-Naphthalenamine
ND
ug/L
8.3
5.0
1
04/01/23 12:01
04/02/23 15:15
134-32-7
2-Naphthalenamine
ND
ug/L
8.3
4.5
1
04/01/23 12:01
04/02/23 15:15
91-59-8
1,4-Naphthoquinone
ND
ug/L
4.2
3.7
1
04/01/23 12:01
04/02/23 15:15
130-15-4
2-Nitroaniline
ND
ug/L
16.7
2.5
1
04/01/23 12:01
04/02/23 15:15
88-74-4
3-Nitroaniline
ND
ug/L
16.7
3.1
1
04/01/23 12:01
04/02/23 15:15
99-09-2
4-Nitroaniline
ND
ug/L
16.7
4.2
1
04/01/23 12:01
04/02/23 15:15
100-01-6
Nitrobenzene
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 15:15
98-95-3
2-Nitrophenol
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 15:15
88-75-5
4-Nitrophenol
ND
ug/L
41.7
5.5
1
04/01/23 12:01
04/02/23 15:15
100-02-7
5-Nitro-o-toluidine
ND
ug/L
8.3
3.2
1
04/01/23 12:01
04/02/23 15:15
99-55-8
N-Nitrosodiethylamine
ND
ug/L
8.3
1.9
1
04/01/23 12:01
04/02/23 15:15
55-18-5
N-Nitrosodimethylamine
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 15:15
62-75-9
N-Nitroso-di-n-butylamine
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 15:15
924-16-3
N-Nitroso-di-n-propylamine
ND
ug/L
8.3
1.1
1
04/01/23 12:01
04/02/23 15:15
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 15:15
86-30-6
N-Nitrosomethylethylamine
ND
ug/L
8.3
6.2
1
04/01/23 12:01
04/02/23 15:15
10595-95-6
N-Nitrosopiperidine
ND
ug/L
8.3
2.1
1
04/01/23 12:01
04/02/23 15:15
100-75-4
N-Nitrosopyrrolidine
ND
ug/L
8.3
2.6
1
04/01/23 12:01
04/02/23 15:15
930-55-2
O,O,O-Triethylphosphorothioate
ND
ug/L
8.3
2.1
1
04/01/23 12:01
04/02/23 15:15
126-68-1
2,2'-Oxybis(1-chloropropane)
ND
ug/L
8.3
0.96
1
04/01/23 12:01
04/02/23 15:15
108-60-1
Parathion (Ethyl parathion)
ND
ug/L
8.3
3.2
1
04/01/23 12:01
04/02/23 15:15
56-38-2
Pentachlorobenzene
ND
ug/L
8.3
2.8
1
04/01/23 12:01
04/02/23 15:15
608-93-5
Pentachloronitrobenzene
ND
ug/L
8.3
2.7
1
04/01/23 12:01
04/02/23 15:15
82-68-8
Pentachlorophenol
ND
ug/L
16.7
3.1
1
04/01/23 12:01
04/02/23 15:15
87-86-5
Phenacetin
ND
ug/L
8.3
3.0
1
04/01/23 12:01
04/02/23 15:15
62-44-2
Phenanthrene
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 15:15
85-01-8
Phenol
ND
ug/L
8.3
1.1
1
04/01/23 12:01
04/02/23 15:15
108-95-2
p-Phenylenediamine
ND
ug/L
8.3
8.3
1
04/01/23 12:01
04/02/23 15:15
106-50-3
Phorate
ND
ug/L
8.3
3.0
1
04/01/23 12:01
04/02/23 15:15
298-02-2
Pronamide
ND
ug/L
8.3
2.6
1
04/01/23 12:01
04/02/23 15:15
23950-58-5
Pyrene
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 15:15
129-00-0
Safrole
ND
ug/L
8.3
1.9
1
04/01/23 12:01
04/02/23 15:15
94-59-7
1,2,4,5-Tetrachlorobenzene
ND
ug/L
8.3
3.7
1
04/01/23 12:01
04/02/23 15:15
95-94-3
2,3,4,6-Tetrachlorophenol
ND
ug/L
8.3
1.3
1
04/01/23 12:01
04/02/23 15:15
58-90-2
Thionazin
ND
ug/L
8.3
2.4
1
04/01/23 12:01
04/02/23 15:15
297-97-2
O-Toluidine
ND
ug/L
8.3
2.2
1
04/01/23 12:01
04/02/23 15:15
95-53-4
2,4,5-TrichIorophenol
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 15:15
95-95-4
REPORT OF LABORATORY ANALYSIS
IH,v1
R1
M1
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 155

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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MWAR
Lab ID:
92659555001
Collected:
03/28/23 12:52
Received: 03/29/23 10:30 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
8270E APP9 RV
Analytical
Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
2,4,6-TrichIorophenol
ND
ug/L
8.3
1.3
1
04/01/23 12:01
04/02/23 15:15
88-06-2
1,3,5-Trinitrobenzene
ND
ug/L
8.3
4.6
1
04/01/23 12:01
04/02/23 15:15
99-35-4
Surrogates
Nitrobenzene-d5 (S)
102
%
10-138
1
04/01/23 12:01
04/02/23 15:15
4165-60-0
2-Fluorobiphenyl (S)
90
%
10-130
1
04/01/23 12:01
04/02/23 15:15
321-60-8
Terphenyl-d14 (S)
115
%
19-191
1
04/01/23 12:01
04/02/23 15:15
1718-51-0
Phenol-d6 (S)
60
%
10-130
1
04/01/23 12:01
04/02/23 15:15
13127-88-3
2-Fluorophenol (S)
76
%
10-130
1
04/01/23 12:01
04/02/23 15:15
367-12-4
2,4,6-Tribromophenol (S)
123
%
10-164
1
04/01/23 12:01
04/02/23 15:15
118-79-6
8260D MSV SIM
Analytical
Method: EPA 8260D Mod.
Pace Analytical
Services
- Charlotte
1,4-Dioxane (p-Dioxane)
ND
ug/L
2.0
0.86
1
03/31/23 21:16
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
87
%
67-130
1
03/31/23 21:16
17060-07-0
Toluene-d8 (S)
93
%
70-130
1
03/31/23 21:16
2037-26-5
8260D MSV Low Level - Acrolein
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
03/31/23 02:20
67-64-1 v1
Acetonitrile
ND
ug/L
50.0
24.8
1
03/31/23 02:20
75-05-8
Acrolein
ND
ug/L
10.0
8.5
1
03/31/23 02:20
107-02-8
Acrylonitrile
ND
ug/L
10.0
1.8
1
03/31/23 02:20
107-13-1
Allyl chloride
ND
ug/L
2.0
0.50
1
03/31/23 02:20
107-05-1
Benzene
ND
ug/L
1.0
0.34
1
03/31/23 02:20
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
03/31/23 02:20
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
03/31/23 02:20
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
03/31/23 02:20
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
03/31/23 02:20
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
03/31/23 02:20
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
03/31/23 02:20
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
03/31/23 02:20
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
03/31/23 02:20
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
03/31/23 02:20
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
03/31/23 02:20
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
03/31/23 02:20
74-87-3 v1
Chloroprene
ND
ug/L
5.0
1.6
1
03/31/23 02:20
126-99-8
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
03/31/23 02:20
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
03/31/23 02:20
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
03/31/23 02:20
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
03/31/23 02:20
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
03/31/23 02:20
95-50-1
1,3-Dichlorobenzene
ND
ug/L
1.0
0.34
1
03/31/23 02:20
541-73-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
03/31/23 02:20
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
03/31/23 02:20
110-57-6
Date: 05/05/2023 12:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MWAR Lab ID: 92659555001 Collected: 03/28/23 12:52 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level -Acrolein
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Ethyl methacrylate
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
4-Methyl-2-pentanone (MIBK)
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 05/05/2023 12:39 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.35
1
03/31/23 02:20
75-71-8
ND
ug/L
1.0
0.37
1
03/31/23 02:20
75-34-3
ND
ug/L
1.0
0.32
1
03/31/23 02:20
107-06-2
ND
ug/L
1.0
0.35
1
03/31/23 02:20
75-35-4
ND
ug/L
1.0
0.38
1
03/31/23 02:20
156-59-2
ND
ug/L
1.0
0.40
1
03/31/23 02:20
156-60-5
ND
ug/L
1.0
0.36
1
03/31/23 02:20
78-87-5
ND
ug/L
1.0
0.28
1
03/31/23 02:20
142-28-9
ND
ug/L
1.0
0.39
1
03/31/23 02:20
594-20-7
ND
ug/L
1.0
0.43
1
03/31/23 02:20
563-58-6
ND
ug/L
1.0
0.36
1
03/31/23 02:20
10061-01-5
ND
ug/L
1.0
0.36
1
03/31/23 02:20
10061-02-6
ND
ug/L
1.0
0.30
1
03/31/23 02:20
100-41-4
ND
ug/L
1.0
0.28
1
03/31/23 02:20
97-63-2
ND
ug/L
2.0
1.5
1
03/31/23 02:20
87-68-3
ND
ug/L
5.0
0.48
1
03/31/23 02:20
591-78-6
ND
ug/L
20.0
9.7
1
03/31/23 02:20
74-88-4
ND
ug/L
100
52.3
1
03/31/23 02:20
78-83-1
ND
ug/L
10.0
4.2
1
03/31/23 02:20
126-98-7 v1
ND
ug/L
5.0
2.0
1
03/31/23 02:20
75-09-2
ND
ug/L
2.0
0.32
1
03/31/23 02:20
80-62-6
ND
ug/L
5.0
2.7
1
03/31/23 02:20
108-10-1
ND
ug/L
1.0
0.64
1
03/31/23 02:20
91-20-3
ND
ug/L
20.0
3.6
1
03/31/23 02:20
107-12-0
ND
ug/L
1.0
0.29
1
03/31/23 02:20
100-42-5
ND
ug/L
1.0
0.31
1
03/31/23 02:20
630-20-6
ND
ug/L
1.0
0.22
1
03/31/23 02:20
79-34-5
ND
ug/L
1.0
0.29
1
03/31/23 02:20
127-18-4
ND
ug/L
1.0
0.24
1
03/31/23 02:20
108-88-3
ND
ug/L
1.0
0.64
1
03/31/23 02:20
120-82-1
ND
ug/L
1.0
0.33
1
03/31/23 02:20
71-55-6
ND
ug/L
1.0
0.32
1
03/31/23 02:20
79-00-5
ND
ug/L
1.0
0.38
1
03/31/23 02:20
79-01-6
ND
ug/L
1.0
0.30
1
03/31/23 02:20
75-69-4
ND
ug/L
1.0
0.26
1
03/31/23 02:20
96-18-4
ND
ug/L
2.0
1.3
1
03/31/23 02:20
108-05-4
ND
ug/L
1.0
0.39
1
03/31/23 02:20
75-01-4
ND
ug/L
1.0
0.34
1
03/31/23 02:20
1330-20-7
95
%
70-130
1
03/31/23 02:20
460-00-4
117
%
70-130
1
03/31/23 02:20
17060-07-0
103
%
70-130
1
03/31/23 02:20
2037-26-5
REPORT
OF LABORATORY ANALYSIS
This report shall not be reproduced,
except in full,
without the written
consent of Pace
Analytical Services, LLC.
Page 13 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MWAR Lab ID: 92659555001 Collected: 03/28/23 12:52 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2320B Alkalinity
Alkalinity, Total as CaCO3
4500S2D Sulfide Water
Sulfide
5210B BOD, 5 day
BOD, 5 day
300.0 IC Anions 28 Days
Sulfate
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
4500 Chloride
Chloride
450OCNE Cyanide, Total
Cyanide
5220D COD
Chemical Oxygen Demand
5310B TOC
Total Organic Carbon
Date: 05/05/2023 12:39 PM
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
42000 ug/L 5000 5000
1
04/06/2317:33
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND ug/L 100 22.0
1
03/31/23 02:48
18496-25-8
Analytical Method: SM 521OB-2016
Pace Analytical Services -Asheville
ND ug/L 2000 2000
1
03/30/23 05:52 04/04/23 02:35
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
586J ug/L 1000 500
1
03/30/23 00:56
14808-79-8
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
315 ug/L 40.0 10.0
1
03/30/23 01:49
14797-55-8
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
3840 ug/L 1000 500
1
03/30/2319:53
16887-00-6
Analytical Method: SM 4500-CN-E-2016 Preparation Method: SM 4500-CN-E-2016
Pace Analytical Services -Asheville
ND ug/L 8.0 6.0
1
04/03/23 18:41 04/03/23 21:51
57-12-5
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
ND ug/L 25000 12500
1
04/03/2312:05 04/03/2315:10
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
ND ug/L 1000 500
1
04/04/23 00:12
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 14 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-2R
Lab ID:
92659555002
Collected:
03/28/23 11:50
Received: 03/29/23 10:30 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
Chlorinated Herb. (GC) 8151A
Analytical
Method: EPA 8151A
Preparation Method: 8151A
Pace National
- Mt. Juliet
2,4-D
ND
ug/L
2.00
0.547
1
04/04/23 14:45
04/06/23 10:53
94-75-7 R1
Dinoseb
ND
ug/L
2.00
0.250
1
04/04/23 14:45
04/06/23 10:53
88-85-7
2,4,5-T
ND
ug/L
2.00
0.258
1
04/04/23 14:45
04/06/23 10:53
93-76-5 R1
2,4,5-TP (Silvex)
ND
ug/L
2.00
0.335
1
04/04/23 14:45
04/06/23 10:53
93-72-1 R1
Surrogates
2,4-DCAA (S)
69.7
%
14.0-158
1
04/04/23 14:45
04/06/23 10:53
19719-28-9
8081 OC Pesticides RVE
Analytical
Method: EPA 8081
B Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
Aldrin
ND
ug/L
0.042
0.012
1
04/04/23 10:24
04/05/23 12:37
309-00-2
alpha-BHC
ND
ug/L
0.042
0.010
1
04/04/23 10:24
04/05/23 12:37
319-84-6
beta-BHC
ND
ug/L
0.042
0.041
1
04/04/23 10:24
04/05/23 12:37
319-85-7
delta-BHC
ND
ug/L
0.042
0.012
1
04/04/23 10:24
04/05/23 12:37
319-86-8
gamma-BHC (Lindane)
ND
ug/L
0.042
0.010
1
04/04/23 10:24
04/05/23 12:37
58-89-9
Chlordane (Technical)
ND
ug/L
0.42
0.13
1
04/04/23 10:24
04/05/23 12:37
57-74-9
4,4'-DDD
ND
ug/L
0.042
0.014
1
04/04/23 10:24
04/05/23 12:37
72-54-8
4,4'-DDE
ND
ug/L
0.042
0.020
1
04/04/23 10:24
04/05/23 12:37
72-55-9
4,4'-DDT
ND
ug/L
0.042
0.022
1
04/04/23 10:24
04/05/23 12:37
50-29-3
Dieldrin
ND
ug/L
0.042
0.012
1
04/04/23 10:24
04/05/23 12:37
60-57-1
Endosulfan I
ND
ug/L
0.042
0.014
1
04/04/23 10:24
04/05/23 12:37
959-98-8
Endosulfan 11
ND
ug/L
0.042
0.013
1
04/04/23 10:24
04/05/23 12:37
33213-65-9
Endosulfan sulfate
ND
ug/L
0.042
0.012
1
04/04/23 10:24
04/05/23 12:37
1031-07-8
Endrin
ND
ug/L
0.042
0.015
1
04/04/23 10:24
04/05/23 12:37
72-20-8
Endrin aldehyde
ND
ug/L
0.042
0.014
1
04/04/23 10:24
04/05/23 12:37
7421-93-4
Heptachlor
ND
ug/L
0.042
0.016
1
04/04/23 10:24
04/05/23 12:37
76-44-8
Heptachlor epoxide
ND
ug/L
0.042
0.024
1
04/04/23 10:24
04/05/23 12:37
1024-57-3
Methoxychlor
ND
ug/L
0.12
0.035
1
04/04/23 10:24
04/05/23 12:37
72-43-5
Toxaphene
ND
ug/L
0.42
0.18
1
04/04/23 10:24
04/05/23 12:37
8001-35-2
Surrogates
Tetrachloro-m-xylene (S)
94
%
10-182
1
04/04/23 10:24
04/05/23 12:37
877-09-8
Decachlorobiphenyl (S)
112
%
10-200
1
04/04/23 10:24
04/05/23 12:37
2051-24-3
8082 GCS PCB RVE
Analytical
Method: EPA 8082A
Preparation Method:
EPA 3510C
Pace Analytical
Services
- Charlotte
PCB-1016 (Aroclor 1016)
ND
ug/L
0.45
0.19
1
04/05/23 22:15
04/07/23 13:06
12674-11-2
PCB-1221 (Aroclor 1221)
ND
ug/L
0.45
0.21
1
04/05/23 22:15
04/07/23 13:06
11104-28-2
PCB-1232 (Aroclor 1232)
ND
ug/L
0.45
0.21
1
04/05/23 22:15
04/07/23 13:06
11141-16-5
PCB-1242 (Aroclor 1242)
ND
ug/L
0.45
0.23
1
04/05/23 22:15
04/07/23 13:06
53469-21-9
PCB-1248 (Aroclor 1248)
ND
ug/L
0.45
0.26
1
04/05/23 22:15
04/07/23 13:06
12672-29-6
PCB-1254 (Aroclor 1254)
ND
ug/L
0.45
0.19
1
04/05/23 22:15
04/07/23 13:06
11097-69-1
PCB-1260 (Aroclor 1260)
ND
ug/L
0.45
0.14
1
04/05/23 22:15
04/07/23 13:06
11096-82-5
Surrogates
Decachlorobiphenyl (S)
126
%
10-193
1
04/05/23 22:15
04/07/23 13:06
2051-24-3
Date: 05/05/2023 12:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-2R Lab ID: 92659555002 Collected: 03/28/23 11:50 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
577
ug/L
10.0
5.3
1
03/31/2316:40
74-82-8
Metals (ICP) 6010D
Analytical Method: EPA 601 OD Preparation Method:
3015
Pace National - Mt. Juliet
Antimony
ND
ug/L
10.0
4.30
1
04/02/2312:18
04/03/2312:35
7440-36-0
Arsenic
ND
ug/L
10.0
4.40
1
04/02/2312:18
04/03/2312:35
7440-38-2
Barium
107
ug/L
5.00
0.736
1
04/02/2312:18
04/03/2312:35
7440-39-3
Beryllium
ND
ug/L
2.00
0.330
1
04/02/2312:18
04/03/2312:35
7440-41-7
Cadmium
ND
ug/L
2.00
0.479
1
04/02/2312:18
04/03/2312:35
7440-43-9
Chromium
2.48J
ug/L
10.0
1.40
1
04/02/2312:18
04/03/2312:35
7440-47-3
Cobalt
12.8
ug/L
10.0
0.840
1
04/02/2312:18
04/03/2312:35
7440-48-4
Copper
ND
ug/L
10.0
3.68
1
04/02/2312:18
04/03/2312:35
7440-50-8
Lead
ND
ug/L
6.00
2.99
1
04/02/2312:18
04/03/2312:35
7439-92-1
Nickel
94.9
ug/L
10.0
1.61
1
04/02/2312:18
04/03/2312:35
7440-02-0
Selenium
ND
ug/L
10.0
7.35
1
04/02/2312:18
04/03/2312:35
7782-49-2
Silver
ND
ug/L
5.00
1.54
1
04/02/2312:18
04/03/2312:35
7440-22-4
Tin
36.9J
ug/L
50.0
4.87
1
04/02/2312:18
04/03/2312:35
7440-31-5
Vanadium
ND
ug/L
20.0
4.99
1
04/02/2312:18
04/03/2312:35
7440-62-2
Zinc
ND
ug/L
50.0
6.52
1
04/02/2312:18
04/03/2312:35
7440-66-6
Metals (ICPMS) 6020B
Analytical Method: EPA 6020E Preparation Method: 3015
Pace National - Mt. Juliet
Thallium
ND
ug/L
2.00
0.121
1
04/04/2316:00
04/04/2319:29
7440-28-0
Mercury 7470A
Analytical Method: EPA 7470A Preparation Method: 7470A
Pace National - Mt. Juliet
Mercury
ND
ug/L
0.200
0.100
1
04/05/2315:29
04/07/2312:05
7439-97-6
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA
3510C
Pace Analytical Services - Charlotte
Acenaphthene
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 15:41
83-32-9
Acenaphthylene
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 15:41
208-96-8
Acetophenone
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 15:41
98-86-2
2-Acetylaminofluorene
ND
ug/L
8.3
3.4
1
04/01/23 12:01
04/02/23 15:41
53-96-3
4-Aminobiphenyl
ND
ug/L
8.3
4.0
1
04/01/23 12:01
04/02/23 15:41
92-67-1
Anthracene
ND
ug/L
8.3
1.9
1
04/01/23 12:01
04/02/23 15:41
120-12-7
Benzo(a)anthracene
ND
ug/L
8.3
2.2
1
04/01/23 12:01
04/02/23 15:41
56-55-3
Benzo(a)pyrene
ND
ug/L
8.3
2.3
1
04/01/23 12:01
04/02/23 15:41
50-32-8
Benzo(b)fluoranthene
ND
ug/L
8.3
2.2
1
04/01/23 12:01
04/02/23 15:41
205-99-2
Benzo(g,h,i)perylene
ND
ug/L
8.3
2.4
1
04/01/23 12:01
04/02/23 15:41
191-24-2
Benzo(k)fluoranthene
ND
ug/L
8.3
2.3
1
04/01/23 12:01
04/02/23 15:41
207-08-9
Benzyl alcohol
ND
ug/L
16.7
2.4
1
04/01/23 12:01
04/02/23 15:41
100-51-6
4-Bromophenylphenyl ether
ND
ug/L
8.3
1.5
1
04/01/23 12:01
04/02/23 15:41
101-55-3
Butylbenzylphthalate
ND
ug/L
8.3
2.6
1
04/01/23 12:01
04/02/23 15:41
85-68-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
J
J
Page 16 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-2R Lab ID: 92659555002 Collected: 03/28/23 11:50 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
4-Chloro-3-methyl phenol
ND
ug/L
8.3
2.8
1
04/01/23 12:01
04/02/23 15:41
59-50-7
4-Chloroaniline
ND
ug/L
16.7
3.0
1
04/01/23 12:01
04/02/23 15:41
106-47-8
Chlorobenzilate
ND
ug/L
8.3
3.2
1
04/01/23 12:01
04/02/23 15:41
510-15-6
bis(2-Chloroethoxy)methane
ND
ug/L
8.3
1.5
1
04/01/23 12:01
04/02/23 15:41
111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 15:41
111-44-4
2-Chloronaphthalene
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 15:41
91-58-7
2-Chlorophenol
ND
ug/L
8.3
1.0
1
04/01/23 12:01
04/02/23 15:41
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 15:41
7005-72-3
Chrysene
ND
ug/L
8.3
2.3
1
04/01/23 12:01
04/02/23 15:41
218-01-9
Diallate
ND
ug/L
8.3
2.8
1
04/01/23 12:01
04/02/23 15:41
2303-16-4
Dibenz(a,h)anthracene
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 15:41
53-70-3
Dibenzofuran
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 15:41
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
16.7
6.8
1
04/01/23 12:01
04/02/23 15:41
91-94-1
2,4-Dichlorophenol
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 15:41
120-83-2
2,6-Dichlorophenol
ND
ug/L
8.3
3.5
1
04/01/23 12:01
04/02/23 15:41
87-65-0
Diethylphthalate
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 15:41
84-66-2
Dimethoate
ND
ug/L
8.3
3.0
1
04/01/23 12:01
04/02/23 15:41
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
4.2
2.0
1
04/01/23 12:01
04/02/23 15:41
60-11-7
7,12-Dimethylbenz(a)anthracene
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 15:41
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
41.7
25.9
1
04/01/23 12:01
04/02/23 15:41
119-93-7
2,4-Dimethylphenol
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 15:41
105-67-9
a,a-Dimethylphenylethylamine
ND
ug/L
83.3
51.7
1
04/01/23 12:01
04/02/23 15:41
122-09-8
Dimethylphthalate
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 15:41
131-11-3
Di-n-butylphthalate
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 15:41
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
16.7
6.5
1
04/01/23 12:01
04/02/23 15:41
534-52-1
1,3-Dinitrobenzene
ND
ug/L
8.3
3.1
1
04/01/23 12:01
04/02/23 15:41
99-65-0
2,4-Dinitrophenol
ND
ug/L
41.7
21.7
1
04/01/23 12:01
04/02/23 15:41
51-28-5
2,4-Dinitrotoluene
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 15:41
121-14-2
2,6-Dinitrotoluene
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 15:41
606-20-2
Di-n-octylphthalate
ND
ug/L
8.3
3.3
1
04/01/23 12:01
04/02/23 15:41
117-84-0
Diphenylamine
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 15:41
122-39-4
Disulfoton
ND
ug/L
8.3
3.9
1
04/01/23 12:01
04/02/23 15:41
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
5.0
3.1
1
04/01/23 12:01
04/02/23 15:41
117-81-7
Ethyl methanesulfonate
ND
ug/L
16.7
2.5
1
04/01/23 12:01
04/02/23 15:41
62-50-0
Famphur
ND
ug/L
8.3
5.1
1
04/01/23 12:01
04/02/23 15:41
52-85-7
Fluoranthene
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 15:41
206-44-0
Fluorene
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 15:41
86-73-7
Hexachlorobenzene
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 15:41
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
8.3
1.3
1
04/01/23 12:01
04/02/23 15:41
77-47-4
Hexachloroethane
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 15:41
67-72-1
Hexachloropropene
ND
ug/L
8.3
2.2
1
04/01/23 12:01
04/02/23 15:41
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
8.3
2.4
1
04/01/23 12:01
04/02/23 15:41
193-39-5
Isodrin
ND
ug/L
8.3
2.3
1
04/01/23 12:01
04/02/23 15:41
465-73-6
Isophorone
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 15:41
78-59-1
Isosafrole
ND
ug/L
8.3
2.1
1
04/01/23 12:01
04/02/23 15:41
120-58-1
REPORT OF LABORATORY ANALYSIS
IL
L1
IH
L1
v2
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-2R Lab ID: 92659555002 Collected: 03/28/23 11:50 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Kepone
ND
ug/L
16.7
11.8
1
04/01/23 12:01
04/02/23 15:41
143-50-0
Methapyrilene
ND
ug/L
41.7
14.2
1
04/01/23 12:01
04/02/23 15:41
91-80-5 IH,v1
3-Methylcholanthrene
ND
ug/L
8.3
3.1
1
04/01/23 12:01
04/02/23 15:41
56-49-5
Methyl methanesulfonate
ND
ug/L
4.2
2.6
1
04/01/23 12:01
04/02/23 15:41
66-27-3
2-Methylnaphthalene
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 15:41
91-57-6
Methyl parathion
ND
ug/L
8.3
3.1
1
04/01/23 12:01
04/02/23 15:41
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 15:41
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
8.3
1.0
1
04/01/23 12:01
04/02/23 15:41
15831-10-4
1-Naphthalenamine
ND
ug/L
8.3
5.0
1
04/01/23 12:01
04/02/23 15:41
134-32-7
2-Naphthalenamine
ND
ug/L
8.3
4.5
1
04/01/23 12:01
04/02/23 15:41
91-59-8
1,4-Naphthoquinone
ND
ug/L
4.2
3.7
1
04/01/23 12:01
04/02/23 15:41
130-15-4
2-Nitroaniline
ND
ug/L
16.7
2.5
1
04/01/23 12:01
04/02/23 15:41
88-74-4
3-Nitroaniline
ND
ug/L
16.7
3.1
1
04/01/23 12:01
04/02/23 15:41
99-09-2
4-Nitroaniline
ND
ug/L
16.7
4.2
1
04/01/23 12:01
04/02/23 15:41
100-01-6
Nitrobenzene
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 15:41
98-95-3
2-Nitrophenol
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 15:41
88-75-5
4-Nitrophenol
ND
ug/L
41.7
5.5
1
04/01/23 12:01
04/02/23 15:41
100-02-7
5-Nitro-o-toluidine
ND
ug/L
8.3
3.2
1
04/01/23 12:01
04/02/23 15:41
99-55-8
N-Nitrosodiethylamine
ND
ug/L
8.3
1.9
1
04/01/23 12:01
04/02/23 15:41
55-18-5
N-Nitrosodimethylamine
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 15:41
62-75-9
N-Nitroso-di-n-butylamine
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 15:41
924-16-3
N-Nitroso-di-n-propylamine
ND
ug/L
8.3
1.1
1
04/01/23 12:01
04/02/23 15:41
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 15:41
86-30-6
N-Nitrosomethylethylamine
ND
ug/L
8.3
6.2
1
04/01/23 12:01
04/02/23 15:41
10595-95-6
N-Nitrosopiperidine
ND
ug/L
8.3
2.1
1
04/01/23 12:01
04/02/23 15:41
100-75-4
N-Nitrosopyrrolidine
ND
ug/L
8.3
2.6
1
04/01/23 12:01
04/02/23 15:41
930-55-2
O,O,O-Triethylphosphorothioate
ND
ug/L
8.3
2.1
1
04/01/23 12:01
04/02/23 15:41
126-68-1
2,2'-Oxybis(1-chloropropane)
ND
ug/L
8.3
0.96
1
04/01/23 12:01
04/02/23 15:41
108-60-1
Parathion (Ethyl parathion)
ND
ug/L
8.3
3.2
1
04/01/23 12:01
04/02/23 15:41
56-38-2
Pentachlorobenzene
ND
ug/L
8.3
2.8
1
04/01/23 12:01
04/02/23 15:41
608-93-5
Pentachloronitrobenzene
ND
ug/L
8.3
2.7
1
04/01/23 12:01
04/02/23 15:41
82-68-8
Pentachlorophenol
ND
ug/L
16.7
3.1
1
04/01/23 12:01
04/02/23 15:41
87-86-5
Phenacetin
ND
ug/L
8.3
3.0
1
04/01/23 12:01
04/02/23 15:41
62-44-2
Phenanthrene
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 15:41
85-01-8
Phenol
ND
ug/L
8.3
1.1
1
04/01/23 12:01
04/02/23 15:41
108-95-2
p-Phenylenediamine
ND
ug/L
8.3
8.3
1
04/01/23 12:01
04/02/23 15:41
106-50-3
Phorate
ND
ug/L
8.3
3.0
1
04/01/23 12:01
04/02/23 15:41
298-02-2
Pronamide
ND
ug/L
8.3
2.6
1
04/01/23 12:01
04/02/23 15:41
23950-58-5
Pyrene
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 15:41
129-00-0
Safrole
ND
ug/L
8.3
1.9
1
04/01/23 12:01
04/02/23 15:41
94-59-7
1,2,4,5-Tetrachlorobenzene
ND
ug/L
8.3
3.7
1
04/01/23 12:01
04/02/23 15:41
95-94-3
2,3,4,6-Tetrachlorophenol
ND
ug/L
8.3
1.3
1
04/01/23 12:01
04/02/23 15:41
58-90-2
Thionazin
ND
ug/L
8.3
2.4
1
04/01/23 12:01
04/02/23 15:41
297-97-2
O-Toluidine
ND
ug/L
8.3
2.2
1
04/01/23 12:01
04/02/23 15:41
95-53-4
2,4,5-TrichIorophenol
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 15:41
95-95-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-2R
Lab ID:
92659555002
Collected:
03/28/23 11:50
Received: 03/29/23 10:30 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
8270E APP9 RV
Analytical
Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
2,4,6-TrichIorophenol
ND
ug/L
8.3
1.3
1
04/01/23 12:01
04/02/23 15:41
88-06-2
1,3,5-Trinitrobenzene
ND
ug/L
8.3
4.6
1
04/01/23 12:01
04/02/23 15:41
99-35-4
Surrogates
Nitrobenzene-d5 (S)
46
%
10-138
1
04/01/23 12:01
04/02/23 15:41
4165-60-0
2-Fluorobiphenyl (S)
43
%
10-130
1
04/01/23 12:01
04/02/23 15:41
321-60-8
Terphenyl-d14 (S)
68
%
19-191
1
04/01/23 12:01
04/02/23 15:41
1718-51-0
Phenol-d6 (S)
33
%
10-130
1
04/01/23 12:01
04/02/23 15:41
13127-88-3
2-Fluorophenol (S)
32
%
10-130
1
04/01/23 12:01
04/02/23 15:41
367-12-4
2,4,6-Tribromophenol (S)
75
%
10-164
1
04/01/23 12:01
04/02/23 15:41
118-79-6
8260D MSV SIM
Analytical
Method: EPA 8260D Mod.
Pace Analytical
Services
- Charlotte
1,4-Dioxane (p-Dioxane)
123
ug/L
4.0
1.7
2
04/04/23 00:14
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
98
%
67-130
2
04/04/23 00:14
17060-07-0
Toluene-d8 (S)
98
%
70-130
2
04/04/23 00:14
2037-26-5
8260D MSV Low Level - Acrolein
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
03/31/23 04:23
67-64-1 v1
Acetonitrile
ND
ug/L
50.0
24.8
1
03/31/23 04:23
75-05-8
Acrolein
ND
ug/L
10.0
8.5
1
03/31/23 04:23
107-02-8
Acrylonitrile
ND
ug/L
10.0
1.8
1
03/31/23 04:23
107-13-1
Allyl chloride
ND
ug/L
2.0
0.50
1
03/31/23 04:23
107-05-1
Benzene
1.6
ug/L
1.0
0.34
1
03/31/23 04:23
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
03/31/23 04:23
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
03/31/23 04:23
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
03/31/23 04:23
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
03/31/23 04:23
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
03/31/23 04:23
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
03/31/23 04:23
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
03/31/23 04:23
56-23-5
Chlorobenzene
15.3
ug/L
1.0
0.28
1
03/31/23 04:23
108-90-7
Chloroethane
0.901
ug/L
1.0
0.65
1
03/31/23 04:23
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
03/31/23 04:23
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
03/31/23 04:23
74-87-3 v1
Chloroprene
ND
ug/L
5.0
1.6
1
03/31/23 04:23
126-99-8
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
03/31/23 04:23
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
03/31/23 04:23
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
03/31/23 04:23
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
03/31/23 04:23
74-95-3
1,2-Dichlorobenzene
1.0
ug/L
1.0
0.34
1
03/31/23 04:23
95-50-1
1,3-Dichlorobenzene
ND
ug/L
1.0
0.34
1
03/31/23 04:23
541-73-1
1,4-Dichlorobenzene
1.7
ug/L
1.0
0.33
1
03/31/23 04:23
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
03/31/23 04:23
110-57-6
Date: 05/05/2023 12:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 19 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-2R Lab ID: 92659555002 Collected: 03/28/23 11:50 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level -Acrolein
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Ethyl methacrylate
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
4-Methyl-2-pentanone (MIBK)
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 05/05/2023 12:39 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
6.2
ug/L
1.0
0.35
1
03/31/23 04:23
75-71-8
ND
ug/L
1.0
0.37
1
03/31/23 04:23
75-34-3
ND
ug/L
1.0
0.32
1
03/31/23 04:23
107-06-2
ND
ug/L
1.0
0.35
1
03/31/23 04:23
75-35-4
ND
ug/L
1.0
0.38
1
03/31/23 04:23
156-59-2
ND
ug/L
1.0
0.40
1
03/31/23 04:23
156-60-5
ND
ug/L
1.0
0.36
1
03/31/23 04:23
78-87-5
ND
ug/L
1.0
0.28
1
03/31/23 04:23
142-28-9
ND
ug/L
1.0
0.39
1
03/31/23 04:23
594-20-7
ND
ug/L
1.0
0.43
1
03/31/23 04:23
563-58-6
ND
ug/L
1.0
0.36
1
03/31/23 04:23
10061-01-5
ND
ug/L
1.0
0.36
1
03/31/23 04:23
10061-02-6
ND
ug/L
1.0
0.30
1
03/31/23 04:23
100-41-4
ND
ug/L
1.0
0.28
1
03/31/23 04:23
97-63-2
ND
ug/L
2.0
1.5
1
03/31/23 04:23
87-68-3
ND
ug/L
5.0
0.48
1
03/31/23 04:23
591-78-6
ND
ug/L
20.0
9.7
1
03/31/23 04:23
74-88-4
ND
ug/L
100
52.3
1
03/31/23 04:23
78-83-1
ND
ug/L
10.0
4.2
1
03/31/23 04:23
126-98-7 v1
ND
ug/L
5.0
2.0
1
03/31/23 04:23
75-09-2
ND
ug/L
2.0
0.32
1
03/31/23 04:23
80-62-6
ND
ug/L
5.0
2.7
1
03/31/23 04:23
108-10-1
1.8
ug/L
1.0
0.64
1
03/31/23 04:23
91-20-3
ND
ug/L
20.0
3.6
1
03/31/23 04:23
107-12-0
ND
ug/L
1.0
0.29
1
03/31/23 04:23
100-42-5
ND
ug/L
1.0
0.31
1
03/31/23 04:23
630-20-6
ND
ug/L
1.0
0.22
1
03/31/23 04:23
79-34-5
ND
ug/L
1.0
0.29
1
03/31/23 04:23
127-18-4
ND
ug/L
1.0
0.24
1
03/31/23 04:23
108-88-3
ND
ug/L
1.0
0.64
1
03/31/23 04:23
120-82-1
ND
ug/L
1.0
0.33
1
03/31/23 04:23
71-55-6
ND
ug/L
1.0
0.32
1
03/31/23 04:23
79-00-5
ND
ug/L
1.0
0.38
1
03/31/23 04:23
79-01-6
1.5
ug/L
1.0
0.30
1
03/31/23 04:23
75-69-4
ND
ug/L
1.0
0.26
1
03/31/23 04:23
96-18-4
ND
ug/L
2.0
1.3
1
03/31/23 04:23
108-05-4
ND
ug/L
1.0
0.39
1
03/31/23 04:23
75-01-4
ND
ug/L
1.0
0.34
1
03/31/23 04:23
1330-20-7
115
%
70-130
1
03/31/23 04:23
460-00-4
116
%
70-130
1
03/31/23 04:23
17060-07-0
104
%
70-130
1
03/31/23 04:23
2037-26-5
REPORT
OF LABORATORY ANALYSIS
This report shall not be reproduced,
except in full,
without the written
consent of Pace
Analytical Services, LLC.
Page 20 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-2R Lab ID: 92659555002 Collected: 03/28/23 11:50 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2320B Alkalinity
Alkalinity, Total as CaCO3
4500S2D Sulfide Water
Sulfide
5210B BOD, 5 day
BOD, 5 day
300.0 IC Anions 28 Days
Sulfate
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
4500 Chloride
Chloride
450OCNE Cyanide, Total
Cyanide
5220D COD
Chemical Oxygen Demand
5310B TOC
Total Organic Carbon
Date: 05/05/2023 12:39 PM
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
860000 ug/L 5000 5000
1
04/07/23 23:59
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND ug/L 100 22.0
1
03/31/23 02:48
18496-25-8
Analytical Method: SM 521OB-2016
Pace Analytical Services -Asheville
2140 ug/L 2000 2000
1
03/30/23 05:52 04/04/23 02:43
B2
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
575J ug/L 1000 500
1
03/30/23 01:12
14808-79-8
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
24.8.11 ug/L 40.0 10.0
1
03/30/23 01:48
14797-55-8
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
220000 ug/L 10000 5000
10
03/30/23 20:08
16887-00-6
Analytical Method: SM 4500-CN-E-2016 Preparation Method: SM 4500-CN-E-2016
Pace Analytical Services -Asheville
ND ug/L 8.0 6.0
1
04/03/23 18:41 04/03/23 21:53
57-12-5
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
101000 ug/L 25000 12500
1
04/03/2312:05 04/03/2315:10
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
24300 ug/L 1000 500
1
04/04/23 00:28
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 21 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-3R
Lab ID:
92659555003
Collected:
03/28/23 10:50
Received: 03/29/23 10:30 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
Chlorinated Herb. (GC) 8151A
Analytical
Method: EPA 8151A
Preparation Method: 8151A
Pace National
- Mt. Juliet
2,4-D
ND
ug/L
2.00
0.547
1
04/04/23 14:45
04/06/23 11:04
94-75-7 R1
Dinoseb
ND
ug/L
2.00
0.250
1
04/04/23 14:45
04/06/23 11:04
88-85-7
2,4,5-T
ND
ug/L
2.00
0.258
1
04/04/23 14:45
04/06/23 11:04
93-76-5 R1
2,4,5-TP (Silvex)
ND
ug/L
2.00
0.335
1
04/04/23 14:45
04/06/23 11:04
93-72-1 R1
Surrogates
2,4-DCAA (S)
66.2
%
14.0-158
1
04/04/23 14:45
04/06/23 11:04
19719-28-9
8081 OC Pesticides RVE
Analytical
Method: EPA 8081
B Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
Aldrin
ND
ug/L
0.045
0.013
1
04/04/23 10:24
04/05/23 12:50
309-00-2
alpha-BHC
ND
ug/L
0.045
0.011
1
04/04/23 10:24
04/05/23 12:50
319-84-6
beta-BHC
ND
ug/L
0.045
0.044
1
04/04/23 10:24
04/05/23 12:50
319-85-7
delta-BHC
ND
ug/L
0.045
0.013
1
04/04/23 10:24
04/05/23 12:50
319-86-8
gamma-BHC (Lindane)
ND
ug/L
0.045
0.011
1
04/04/23 10:24
04/05/23 12:50
58-89-9
Chlordane (Technical)
ND
ug/L
0.45
0.14
1
04/04/23 10:24
04/05/23 12:50
57-74-9
4,4'-DDD
ND
ug/L
0.045
0.015
1
04/04/23 10:24
04/05/23 12:50
72-54-8
4,4'-DDE
ND
ug/L
0.045
0.022
1
04/04/23 10:24
04/05/23 12:50
72-55-9
4,4'-DDT
ND
ug/L
0.045
0.023
1
04/04/23 10:24
04/05/23 12:50
50-29-3
Dieldrin
ND
ug/L
0.045
0.014
1
04/04/23 10:24
04/05/23 12:50
60-57-1
Endosulfan I
ND
ug/L
0.045
0.016
1
04/04/23 10:24
04/05/23 12:50
959-98-8
Endosulfan 11
ND
ug/L
0.045
0.014
1
04/04/23 10:24
04/05/23 12:50
33213-65-9
Endosulfan sulfate
ND
ug/L
0.045
0.013
1
04/04/23 10:24
04/05/23 12:50
1031-07-8
Endrin
ND
ug/L
0.045
0.016
1
04/04/23 10:24
04/05/23 12:50
72-20-8
Endrin aldehyde
ND
ug/L
0.045
0.015
1
04/04/23 10:24
04/05/23 12:50
7421-93-4
Heptachlor
ND
ug/L
0.045
0.018
1
04/04/23 10:24
04/05/23 12:50
76-44-8
Heptachlor epoxide
ND
ug/L
0.045
0.026
1
04/04/23 10:24
04/05/23 12:50
1024-57-3
Methoxychlor
ND
ug/L
0.14
0.038
1
04/04/23 10:24
04/05/23 12:50
72-43-5
Toxaphene
ND
ug/L
0.45
0.20
1
04/04/23 10:24
04/05/23 12:50
8001-35-2
Surrogates
Tetrachloro-m-xylene (S)
118
%
10-182
1
04/04/23 10:24
04/05/23 12:50
877-09-8
Decachlorobiphenyl (S)
100
%
10-200
1
04/04/23 10:24
04/05/23 12:50
2051-24-3
8082 GCS PCB RVE
Analytical
Method: EPA 8082A
Preparation Method:
EPA 3510C
Pace Analytical
Services
- Charlotte
PCB-1016 (Aroclor 1016)
ND
ug/L
0.45
0.19
1
04/05/23 22:15
04/07/23 13:19
12674-11-2
PCB-1221 (Aroclor 1221)
ND
ug/L
0.45
0.21
1
04/05/23 22:15
04/07/23 13:19
11104-28-2
PCB-1232 (Aroclor 1232)
ND
ug/L
0.45
0.21
1
04/05/23 22:15
04/07/23 13:19
11141-16-5
PCB-1242 (Aroclor 1242)
ND
ug/L
0.45
0.23
1
04/05/23 22:15
04/07/23 13:19
53469-21-9
PCB-1248 (Aroclor 1248)
ND
ug/L
0.45
0.26
1
04/05/23 22:15
04/07/23 13:19
12672-29-6
PCB-1254 (Aroclor 1254)
ND
ug/L
0.45
0.19
1
04/05/23 22:15
04/07/23 13:19
11097-69-1
PCB-1260 (Aroclor 1260)
ND
ug/L
0.45
0.14
1
04/05/23 22:15
04/07/23 13:19
11096-82-5
Surrogates
Decachlorobiphenyl (S)
123
%
10-193
1
04/05/23 22:15
04/07/23 13:19
2051-24-3
Date: 05/05/2023 12:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 22 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-3R Lab ID: 92659555003 Collected: 03/28/23 10:50 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane 96.2 ug/L 10.0 5.3 1
Metals (ICP) 6010D Analytical Method: EPA 601 OD Preparation Method: 3015
Pace National - Mt. Juliet
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Tin
Vanadium
Zinc
Metals (ICPMS) 6020B
Thallium
Mercury 7470A
Mercury
8270E APP9 RV
Acenaphthene
Acenaphthylene
Acetophenone
2-Acetylaminofluorene
4-Aminobiphenyl
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Benzyl alcohol
4-Bromophenylphenyl ether
Butylbenzylphthalate
Date: 05/05/2023 12:39 PM
03/31/23 16:56 74-82-8
ND
ug/L
10.0
4.30
1
04/02/2312:18
04/03/2312:37
7440-36-0
ND
ug/L
10.0
4.40
1
04/02/2312:18
04/03/2312:37
7440-38-2
75.7
ug/L
5.00
0.736
1
04/02/2312:18
04/03/2312:37
7440-39-3
ND
ug/L
2.00
0.330
1
04/02/2312:18
04/03/2312:37
7440-41-7
ND
ug/L
2.00
0.479
1
04/02/2312:18
04/03/2312:37
7440-43-9
ND
ug/L
10.0
1.40
1
04/02/2312:18
04/03/2312:37
7440-47-3
0.894J
ug/L
10.0
0.840
1
04/02/2312:18
04/03/2312:37
7440-48-4
5.96J
ug/L
10.0
3.68
1
04/02/2312:18
04/03/2312:37
7440-50-8
ND
ug/L
6.00
2.99
1
04/02/2312:18
04/03/2312:37
7439-92-1
32.1
ug/L
10.0
1.61
1
04/02/2312:18
04/03/2312:37
7440-02-0
ND
ug/L
10.0
7.35
1
04/02/2312:18
04/03/2312:37
7782-49-2
ND
ug/L
5.00
1.54
1
04/02/2312:18
04/03/2312:37
7440-22-4
16.6J
ug/L
50.0
4.87
1
04/02/2312:18
04/03/2312:37
7440-31-5
ND
ug/L
20.0
4.99
1
04/02/2312:18
04/03/2312:37
7440-62-2
ND
ug/L
50.0
6.52
1
04/02/2312:18
04/03/2312:37
7440-66-6
J
J
J
Analytical Method: EPA 6020E Preparation Method: 3015
Pace National - Mt. Juliet
0.168J ug/L 2.00 0.121 1 04/03/2317:07 04/04/2319:18 7440-28-0 J
Analytical Method: EPA 7470A Preparation Method: 7470A
Pace National - Mt. Juliet
ND ug/L 0.200 0.100 1 04/05/2315:29 04/07/2312:11 7439-97-6
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
ND
ug/L
8.3
1.7
1
04/01/2312:01
04/02/23 16:06
83-32-9
ND
ug/L
8.3
1.6
1
04/01/2312:01
04/02/23 16:06
208-96-8
ND
ug/L
8.3
1.2
1
04/01/2312:01
04/02/23 16:06
98-86-2
ND
ug/L
8.3
3.4
1
04/01/2312:01
04/02/23 16:06
53-96-3
ND
ug/L
8.3
4.0
1
04/01/2312:01
04/02/23 16:06
92-67-1
ND
ug/L
8.3
1.9
1
04/01/2312:01
04/02/23 16:06
120-12-7
ND
ug/L
8.3
2.2
1
04/01/2312:01
04/02/23 16:06
56-55-3
ND
ug/L
8.3
2.3
1
04/01/2312:01
04/02/23 16:06
50-32-8
ND
ug/L
8.3
2.2
1
04/01/2312:01
04/02/23 16:06
205-99-2
ND
ug/L
8.3
2.4
1
04/01 /23 12:01
04/02/23 16:06
191-24-2
ND
ug/L
8.3
2.3
1
04/01/2312:01
04/02/23 16:06
207-08-9
ND
ug/L
16.7
2.4
1
04/01 /23 12:01
04/02/23 16:06
100-51-6
ND
ug/L
8.3
1.5
1
04/01 /23 12:01
04/02/23 16:06
101-55-3
ND
ug/L
8.3
2.6
1
04/01/2312:01
04/02/23 16:06
85-68-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 23 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-3R Lab ID: 92659555003 Collected: 03/28/23 10:50 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
4-Chloro-3-methyl phenol
ND
ug/L
8.3
2.8
1
04/01/23 12:01
04/02/23 16:06
59-50-7
4-Chloroaniline
ND
ug/L
16.7
3.0
1
04/01/23 12:01
04/02/23 16:06
106-47-8
Chlorobenzilate
ND
ug/L
8.3
3.2
1
04/01/23 12:01
04/02/23 16:06
510-15-6
bis(2-Chloroethoxy)methane
ND
ug/L
8.3
1.5
1
04/01/23 12:01
04/02/23 16:06
111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 16:06
111-44-4
2-Chloronaphthalene
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 16:06
91-58-7
2-Chlorophenol
ND
ug/L
8.3
1.0
1
04/01/23 12:01
04/02/23 16:06
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 16:06
7005-72-3
Chrysene
ND
ug/L
8.3
2.3
1
04/01/23 12:01
04/02/23 16:06
218-01-9
Diallate
ND
ug/L
8.3
2.8
1
04/01/23 12:01
04/02/23 16:06
2303-16-4
Dibenz(a,h)anthracene
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 16:06
53-70-3
Dibenzofuran
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 16:06
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
16.7
6.8
1
04/01/23 12:01
04/02/23 16:06
91-94-1
2,4-Dichlorophenol
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 16:06
120-83-2
2,6-Dichlorophenol
ND
ug/L
8.3
3.5
1
04/01/23 12:01
04/02/23 16:06
87-65-0
Diethylphthalate
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 16:06
84-66-2
Dimethoate
ND
ug/L
8.3
3.0
1
04/01/23 12:01
04/02/23 16:06
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
4.2
2.0
1
04/01/23 12:01
04/02/23 16:06
60-11-7
7,12-Dimethylbenz(a)anthracene
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 16:06
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
41.7
25.9
1
04/01/23 12:01
04/02/23 16:06
119-93-7
2,4-Dimethylphenol
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 16:06
105-67-9
a,a-Dimethylphenylethylamine
ND
ug/L
83.3
51.7
1
04/01/23 12:01
04/02/23 16:06
122-09-8
Dimethylphthalate
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 16:06
131-11-3
Di-n-butylphthalate
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 16:06
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
16.7
6.5
1
04/01/23 12:01
04/02/23 16:06
534-52-1
1,3-Dinitrobenzene
ND
ug/L
8.3
3.1
1
04/01/23 12:01
04/02/23 16:06
99-65-0
2,4-Dinitrophenol
ND
ug/L
41.7
21.7
1
04/01/23 12:01
04/02/23 16:06
51-28-5
2,4-Dinitrotoluene
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 16:06
121-14-2
2,6-Dinitrotoluene
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 16:06
606-20-2
Di-n-octylphthalate
ND
ug/L
8.3
3.3
1
04/01/23 12:01
04/02/23 16:06
117-84-0
Diphenylamine
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 16:06
122-39-4
Disulfoton
ND
ug/L
8.3
3.9
1
04/01/23 12:01
04/02/23 16:06
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
5.0
3.1
1
04/01/23 12:01
04/02/23 16:06
117-81-7
Ethyl methanesulfonate
ND
ug/L
16.7
2.5
1
04/01/23 12:01
04/02/23 16:06
62-50-0
Famphur
ND
ug/L
8.3
5.1
1
04/01/23 12:01
04/02/23 16:06
52-85-7
Fluoranthene
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 16:06
206-44-0
Fluorene
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 16:06
86-73-7
Hexachlorobenzene
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 16:06
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
8.3
1.3
1
04/01/23 12:01
04/02/23 16:06
77-47-4
Hexachloroethane
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 16:06
67-72-1
Hexachloropropene
ND
ug/L
8.3
2.2
1
04/01/23 12:01
04/02/23 16:06
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
8.3
2.4
1
04/01/23 12:01
04/02/23 16:06
193-39-5
Isodrin
ND
ug/L
8.3
2.3
1
04/01/23 12:01
04/02/23 16:06
465-73-6
Isophorone
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 16:06
78-59-1
Isosafrole
ND
ug/L
8.3
2.1
1
04/01/23 12:01
04/02/23 16:06
120-58-1
REPORT OF LABORATORY ANALYSIS
IL
L1
IH
L1
v2
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-3R Lab ID: 92659555003 Collected: 03/28/23 10:50 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Kepone
ND
ug/L
16.7
11.8
1
04/01/23 12:01
04/02/23 16:06
143-50-0
Methapyrilene
ND
ug/L
41.7
14.2
1
04/01/23 12:01
04/02/23 16:06
91-80-5 IH,v1
3-Methylcholanthrene
ND
ug/L
8.3
3.1
1
04/01/23 12:01
04/02/23 16:06
56-49-5
Methyl methanesulfonate
ND
ug/L
4.2
2.6
1
04/01/23 12:01
04/02/23 16:06
66-27-3
2-Methylnaphthalene
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 16:06
91-57-6
Methyl parathion
ND
ug/L
8.3
3.1
1
04/01/23 12:01
04/02/23 16:06
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 16:06
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
8.3
1.0
1
04/01/23 12:01
04/02/23 16:06
15831-10-4
1-Naphthalenamine
ND
ug/L
8.3
5.0
1
04/01/23 12:01
04/02/23 16:06
134-32-7
2-Naphthalenamine
ND
ug/L
8.3
4.5
1
04/01/23 12:01
04/02/23 16:06
91-59-8
1,4-Naphthoquinone
ND
ug/L
4.2
3.7
1
04/01/23 12:01
04/02/23 16:06
130-15-4
2-Nitroaniline
ND
ug/L
16.7
2.5
1
04/01/23 12:01
04/02/23 16:06
88-74-4
3-Nitroaniline
ND
ug/L
16.7
3.1
1
04/01/23 12:01
04/02/23 16:06
99-09-2
4-Nitroaniline
ND
ug/L
16.7
4.2
1
04/01/23 12:01
04/02/23 16:06
100-01-6
Nitrobenzene
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 16:06
98-95-3
2-Nitrophenol
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 16:06
88-75-5
4-Nitrophenol
ND
ug/L
41.7
5.5
1
04/01/23 12:01
04/02/23 16:06
100-02-7
5-Nitro-o-toluidine
ND
ug/L
8.3
3.2
1
04/01/23 12:01
04/02/23 16:06
99-55-8
N-Nitrosodiethylamine
ND
ug/L
8.3
1.9
1
04/01/23 12:01
04/02/23 16:06
55-18-5
N-Nitrosodimethylamine
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 16:06
62-75-9
N-Nitroso-di-n-butylamine
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 16:06
924-16-3
N-Nitroso-di-n-propylamine
ND
ug/L
8.3
1.1
1
04/01/23 12:01
04/02/23 16:06
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 16:06
86-30-6
N-Nitrosomethylethylamine
ND
ug/L
8.3
6.2
1
04/01/23 12:01
04/02/23 16:06
10595-95-6
N-Nitrosopiperidine
ND
ug/L
8.3
2.1
1
04/01/23 12:01
04/02/23 16:06
100-75-4
N-Nitrosopyrrolidine
ND
ug/L
8.3
2.6
1
04/01/23 12:01
04/02/23 16:06
930-55-2
O,O,O-Triethylphosphorothioate
ND
ug/L
8.3
2.1
1
04/01/23 12:01
04/02/23 16:06
126-68-1
2,2'-Oxybis(1-chloropropane)
ND
ug/L
8.3
0.96
1
04/01/23 12:01
04/02/23 16:06
108-60-1
Parathion (Ethyl parathion)
ND
ug/L
8.3
3.2
1
04/01/23 12:01
04/02/23 16:06
56-38-2
Pentachlorobenzene
ND
ug/L
8.3
2.8
1
04/01/23 12:01
04/02/23 16:06
608-93-5
Pentachloronitrobenzene
ND
ug/L
8.3
2.7
1
04/01/23 12:01
04/02/23 16:06
82-68-8
Pentachlorophenol
ND
ug/L
16.7
3.1
1
04/01/23 12:01
04/02/23 16:06
87-86-5
Phenacetin
ND
ug/L
8.3
3.0
1
04/01/23 12:01
04/02/23 16:06
62-44-2
Phenanthrene
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 16:06
85-01-8
Phenol
ND
ug/L
8.3
1.1
1
04/01/23 12:01
04/02/23 16:06
108-95-2
p-Phenylenediamine
ND
ug/L
8.3
8.3
1
04/01/23 12:01
04/02/23 16:06
106-50-3
Phorate
ND
ug/L
8.3
3.0
1
04/01/23 12:01
04/02/23 16:06
298-02-2
Pronamide
ND
ug/L
8.3
2.6
1
04/01/23 12:01
04/02/23 16:06
23950-58-5
Pyrene
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 16:06
129-00-0
Safrole
ND
ug/L
8.3
1.9
1
04/01/23 12:01
04/02/23 16:06
94-59-7
1,2,4,5-Tetrachlorobenzene
ND
ug/L
8.3
3.7
1
04/01/23 12:01
04/02/23 16:06
95-94-3
2,3,4,6-Tetrachlorophenol
ND
ug/L
8.3
1.3
1
04/01/23 12:01
04/02/23 16:06
58-90-2
Thionazin
ND
ug/L
8.3
2.4
1
04/01/23 12:01
04/02/23 16:06
297-97-2
O-Toluidine
ND
ug/L
8.3
2.2
1
04/01/23 12:01
04/02/23 16:06
95-53-4
2,4,5-TrichIorophenol
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 16:06
95-95-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-3R
Lab ID:
92659555003
Collected:
03/28/23 10:50
Received: 03/29/23 10:30 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
8270E APP9 RV
Analytical
Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
2,4,6-TrichIorophenol
ND
ug/L
8.3
1.3
1
04/01/23 12:01
04/02/23 16:06
88-06-2
1,3,5-Trinitrobenzene
ND
ug/L
8.3
4.6
1
04/01/23 12:01
04/02/23 16:06
99-35-4
Surrogates
Nitrobenzene-d5 (S)
62
%
10-138
1
04/01/23 12:01
04/02/23 16:06
4165-60-0
2-Fluorobiphenyl (S)
55
%
10-130
1
04/01/23 12:01
04/02/23 16:06
321-60-8
Terphenyl-d14 (S)
93
%
19-191
1
04/01/23 12:01
04/02/23 16:06
1718-51-0
Phenol-d6 (S)
36
%
10-130
1
04/01/23 12:01
04/02/23 16:06
13127-88-3
2-Fluorophenol (S)
44
%
10-130
1
04/01/23 12:01
04/02/23 16:06
367-12-4
2,4,6-Tribromophenol (S)
97
%
10-164
1
04/01/23 12:01
04/02/23 16:06
118-79-6
8260D MSV SIM
Analytical
Method: EPA 8260D Mod.
Pace Analytical
Services
- Charlotte
1,4-Dioxane (p-Dioxane)
67.4
ug/L
2.0
0.86
1
03/31/23 21:54
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
79
%
67-130
1
03/31/23 21:54
17060-07-0
Toluene-d8 (S)
90
%
70-130
1
03/31/23 21:54
2037-26-5
8260D MSV Low Level - Acrolein
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
03/31/23 04:40
67-64-1 v1
Acetonitrile
ND
ug/L
50.0
24.8
1
03/31/23 04:40
75-05-8
Acrolein
ND
ug/L
10.0
8.5
1
03/31/23 04:40
107-02-8
Acrylonitrile
ND
ug/L
10.0
1.8
1
03/31/23 04:40
107-13-1
Allyl chloride
ND
ug/L
2.0
0.50
1
03/31/23 04:40
107-05-1
Benzene
ND
ug/L
1.0
0.34
1
03/31/23 04:40
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
03/31/23 04:40
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
03/31/23 04:40
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
03/31/23 04:40
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
03/31/23 04:40
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
03/31/23 04:40
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
03/31/23 04:40
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
03/31/23 04:40
56-23-5
Chlorobenzene
12.0
ug/L
1.0
0.28
1
03/31/23 04:40
108-90-7
Chloroethane
0.86J
ug/L
1.0
0.65
1
03/31/23 04:40
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
03/31/23 04:40
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
03/31/23 04:40
74-87-3 v1
Chloroprene
ND
ug/L
5.0
1.6
1
03/31/23 04:40
126-99-8
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
03/31/23 04:40
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
03/31/23 04:40
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
03/31/23 04:40
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
03/31/23 04:40
74-95-3
1,2-Dichlorobenzene
1.0
ug/L
1.0
0.34
1
03/31/23 04:40
95-50-1
1,3-Dichlorobenzene
ND
ug/L
1.0
0.34
1
03/31/23 04:40
541-73-1
1,4-Dichlorobenzene
0.44J
ug/L
1.0
0.33
1
03/31/23 04:40
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
03/31/23 04:40
110-57-6
Date: 05/05/2023 12:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 26 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-3R Lab ID: 92659555003 Collected: 03/28/23 10:50 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level -Acrolein
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Ethyl methacrylate
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
4-Methyl-2-pentanone (MIBK)
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 05/05/2023 12:39 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.35
1
03/31/23 04:40
75-71-8
ND
ug/L
1.0
0.37
1
03/31/23 04:40
75-34-3
ND
ug/L
1.0
0.32
1
03/31/23 04:40
107-06-2
ND
ug/L
1.0
0.35
1
03/31/23 04:40
75-35-4
ND
ug/L
1.0
0.38
1
03/31/23 04:40
156-59-2
ND
ug/L
1.0
0.40
1
03/31/23 04:40
156-60-5
ND
ug/L
1.0
0.36
1
03/31/23 04:40
78-87-5
ND
ug/L
1.0
0.28
1
03/31/23 04:40
142-28-9
ND
ug/L
1.0
0.39
1
03/31/23 04:40
594-20-7
ND
ug/L
1.0
0.43
1
03/31/23 04:40
563-58-6
ND
ug/L
1.0
0.36
1
03/31/23 04:40
10061-01-5
ND
ug/L
1.0
0.36
1
03/31/23 04:40
10061-02-6
ND
ug/L
1.0
0.30
1
03/31/23 04:40
100-41-4
ND
ug/L
1.0
0.28
1
03/31/23 04:40
97-63-2
ND
ug/L
2.0
1.5
1
03/31/23 04:40
87-68-3
ND
ug/L
5.0
0.48
1
03/31/23 04:40
591-78-6
ND
ug/L
20.0
9.7
1
03/31/23 04:40
74-88-4
ND
ug/L
100
52.3
1
03/31/23 04:40
78-83-1
ND
ug/L
10.0
4.2
1
03/31/23 04:40
126-98-7 v1
ND
ug/L
5.0
2.0
1
03/31/23 04:40
75-09-2
ND
ug/L
2.0
0.32
1
03/31/23 04:40
80-62-6
ND
ug/L
5.0
2.7
1
03/31/23 04:40
108-10-1
ND
ug/L
1.0
0.64
1
03/31/23 04:40
91-20-3
ND
ug/L
20.0
3.6
1
03/31/23 04:40
107-12-0
ND
ug/L
1.0
0.29
1
03/31/23 04:40
100-42-5
ND
ug/L
1.0
0.31
1
03/31/23 04:40
630-20-6
ND
ug/L
1.0
0.22
1
03/31/23 04:40
79-34-5
ND
ug/L
1.0
0.29
1
03/31/23 04:40
127-18-4
ND
ug/L
1.0
0.24
1
03/31/23 04:40
108-88-3
ND
ug/L
1.0
0.64
1
03/31/23 04:40
120-82-1
ND
ug/L
1.0
0.33
1
03/31/23 04:40
71-55-6
ND
ug/L
1.0
0.32
1
03/31/23 04:40
79-00-5
ND
ug/L
1.0
0.38
1
03/31/23 04:40
79-01-6
ND
ug/L
1.0
0.30
1
03/31/23 04:40
75-69-4
ND
ug/L
1.0
0.26
1
03/31/23 04:40
96-18-4
ND
ug/L
2.0
1.3
1
03/31/23 04:40
108-05-4
ND
ug/L
1.0
0.39
1
03/31/23 04:40
75-01-4
ND
ug/L
1.0
0.34
1
03/31/23 04:40
1330-20-7
109
%
70-130
1
03/31/23 04:40
460-00-4
113
%
70-130
1
03/31/23 04:40
17060-07-0
118
%
70-130
1
03/31/23 04:40
2037-26-5
REPORT
OF LABORATORY ANALYSIS
This report shall not be reproduced,
except in full,
without the written
consent of Pace
Analytical Services, LLC.
Page 27 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-3R Lab ID: 92659555003 Collected: 03/28/23 10:50 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2320B Alkalinity
Alkalinity, Total as CaCO3
4500S2D Sulfide Water
Sulfide
5210B BOD, 5 day
BOD, 5 day
300.0 IC Anions 28 Days
Sulfate
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
4500 Chloride
Chloride
450OCNE Cyanide, Total
Cyanide
5220D COD
Chemical Oxygen Demand
5310B TOC
Total Organic Carbon
Date: 05/05/2023 12:39 PM
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
731000 ug/L 5000 5000
1
04/08/23 00:10
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND ug/L 100 22.0
1
03/31/23 02:49
18496-25-8
Analytical Method: SM 521OB-2016
Pace Analytical Services -Asheville
ND ug/L 2000 2000
1
03/31/23 02:49 04/05/23 01:04
H2
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
1060 ug/L 1000 500
1
04/01 /23 00:29
14808-79-8
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
ND ug/L 40.0 10.0
1
03/31/23 04:00
14797-55-8
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
175000 ug/L 6000 3000
6
03/30/23 20:17
16887-00-6
Analytical Method: SM 4500-CN-E-2016 Preparation Method: SM 4500-CN-E-2016
Pace Analytical Services -Asheville
ND ug/L 8.0 6.0
1
04/03/23 18:41 04/03/23 21:59
57-12-5
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
45400 ug/L 25000 12500
1
04/03/2312:05 04/03/2315:10
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
9310 ug/L 1000 500
1
04/04/23 00:50
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 28 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: SW-1 Lab ID: 92659555004 Collected: 03/28/23 00:00 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
Metals (ICP) 6010D
Analytical Method: EPA 6010D Preparation Method: 3015
Pace National - Mt. Juliet
Antimony
ND
ug/L
10.0
4.30
1
04/02/2312:18
04/03/2312:40
7440-36-0
Arsenic
ND
ug/L
10.0
4.40
1
04/02/2312:18
04/03/2312:40
7440-38-2
Barium
35.2
ug/L
5.00
0.736
1
04/02/2312:18
04/03/2312:40
7440-39-3
Beryllium
ND
ug/L
2.00
0.330
1
04/02/2312:18
04/03/2312:40
7440-41-7
Cadmium
ND
ug/L
2.00
0.479
1
04/02/2312:18
04/03/2312:40
7440-43-9
Chromium
1.97J
ug/L
10.0
1.40
1
04/02/2312:18
04/03/2312:40
7440-47-3
Cobalt
1.12J
ug/L
10.0
0.840
1
04/02/2312:18
04/03/2312:40
7440-48-4
Copper
ND
ug/L
10.0
3.68
1
04/02/2312:18
04/03/2312:40
7440-50-8
Lead
ND
ug/L
6.00
2.99
1
04/02/2312:18
04/03/2312:40
7439-92-1
Nickel
3.71J
ug/L
10.0
1.61
1
04/02/2312:18
04/03/2312:40
7440-02-0
Selenium
ND
ug/L
10.0
7.35
1
04/02/2312:18
04/03/2312:40
7782-49-2
Silver
ND
ug/L
5.00
1.54
1
04/02/2312:18
04/03/2312:40
7440-22-4
Vanadium
ND
ug/L
20.0
4.99
1
04/02/2312:18
04/03/2312:40
7440-62-2
Zinc
ND
ug/L
50.0
6.52
1
04/02/2312:18
04/03/2312:40
7440-66-6
Metals (ICPMS) 6020B
Analytical Method: EPA 6020E Preparation Method: 3015
Pace National - Mt. Juliet
Thallium
ND
ug/L
2.00
0.121
1
04/03/2317:07
04/04/2319:22
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
03/31/23 05:53
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
03/31/23 05:53
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
03/31/23 05:53
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
03/31/23 05:53
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
03/31/23 05:53
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
03/31/23 05:53
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
03/31/23 05:53
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
03/31/23 05:53
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
03/31/23 05:53
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
03/31/23 05:53
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
03/31/23 05:53
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
03/31/23 05:53
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
03/31/23 05:53
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
03/31/23 05:53
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
03/31/23 05:53
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
03/31/23 05:53
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
03/31/23 05:53
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
03/31/23 05:53
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
03/31/23 05:53
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
03/31/23 05:53
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
03/31/23 05:53
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
03/31/23 05:53
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
03/31/23 05:53
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
03/31/23 05:53
75-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
J
J
B,J
Page 29 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: SW-1 Lab ID: 92659555004 Collected: 03/28/23 00:00 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Calculated Results
Hardness, Total(SM 2340B)
Date: 05/05/2023 12:39 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
20.0
ND
ug/L
5.0
ND
ug/L
5.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
100
%
70-130
94
%
70-130
105
%
70-130
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1.3J ug/L 2.0
83 % 67-130
92 % 70-130
0.38
1
03/31/23 05:53
156-59-2
0.40
1
03/31/23 05:53
156-60-5
0.36
1
03/31/23 05:53
78-87-5
0.36
1
03/31/23 05:53
10061-01-5
0.36
1
03/31/23 05:53
10061-02-6
0.30
1
03/31/23 05:53
100-41-4
0.48
1
03/31/23 05:53
591-78-6
9.7
1
03/31/23 05:53
74-88-4
2.0
1
03/31/23 05:53
75-09-2
2.7
1
03/31/23 05:53
108-10-1
0.29
1
03/31/23 05:53
100-42-5
0.31
1
03/31/23 05:53
630-20-6
0.22
1
03/31/23 05:53
79-34-5
0.29
1
03/31/23 05:53
127-18-4
0.24
1
03/31/23 05:53
108-88-3
0.33
1
03/31/23 05:53
71-55-6
0.32
1
03/31/23 05:53
79-00-5
0.38
1
03/31/23 05:53
79-01-6
0.30
1
03/31/23 05:53
75-69-4
0.26
1
03/31/23 05:53
96-18-4
1.3
1
03/31/23 05:53
108-05-4 IK
0.39
1
03/31/23 05:53
75-01-4
0.34
1
03/31/23 05:53
1330-20-7
1 03/31/23 05:53 460-00-4
1 03/31/23 05:53 17060-07-0
1 03/31/23 05:53 2037-26-5
0.86 1
8
03/31/23 22:13 123-91-1 C8
03/31/23 22:13 17060-07-0
03/31/23 22:13 2037-26-5
Analytical Method: SM2340-97 Preparation Method: SM2340B
Pace National - Mt. Juliet
54900 ug/L 2500 198 1 04/03/2312:40 04/03/2312:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 30 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: SW-2 Lab ID: 92659555005 Collected: 03/28/23 00:00 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
Metals (ICP) 6010D
Analytical Method: EPA 6010D Preparation Method: 3015
Pace National - Mt. Juliet
Antimony
ND
ug/L
10.0
4.30
1
04/02/2312:18
04/03/2312:43
7440-36-0
Arsenic
ND
ug/L
10.0
4.40
1
04/02/2312:18
04/03/2312:43
7440-38-2
Barium
42.6
ug/L
5.00
0.736
1
04/02/2312:18
04/03/2312:43
7440-39-3
Beryllium
ND
ug/L
2.00
0.330
1
04/02/2312:18
04/03/2312:43
7440-41-7
Cadmium
ND
ug/L
2.00
0.479
1
04/02/2312:18
04/03/2312:43
7440-43-9
Chromium
ND
ug/L
10.0
1.40
1
04/02/2312:18
04/03/2312:43
7440-47-3
Cobalt
ND
ug/L
10.0
0.840
1
04/02/2312:18
04/03/2312:43
7440-48-4
Copper
ND
ug/L
10.0
3.68
1
04/02/2312:18
04/03/2312:43
7440-50-8
Lead
ND
ug/L
6.00
2.99
1
04/02/2312:18
04/03/2312:43
7439-92-1
Nickel
7.10J
ug/L
10.0
1.61
1
04/02/2312:18
04/03/2312:43
7440-02-0 B,J
Selenium
ND
ug/L
10.0
7.35
1
04/02/2312:18
04/03/2312:43
7782-49-2
Silver
ND
ug/L
5.00
1.54
1
04/02/2312:18
04/03/2312:43
7440-22-4
Vanadium
ND
ug/L
20.0
4.99
1
04/02/2312:18
04/03/2312:43
7440-62-2
Zinc
ND
ug/L
50.0
6.52
1
04/02/2312:18
04/03/2312:43
7440-66-6
Metals (ICPMS) 6020B
Thallium
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
Date: 05/05/2023 12:39 PM
Analytical Method: EPA 6020E Preparation Method: 3015
Pace National - Mt. Juliet
ND
ug/L
2.00
0.121
1
04/03/2317:07 04/04/2319:25
7440-28-0
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
5.1
1
03/31/23 06:10
67-64-1
ND
ug/L
10.0
1.8
1
03/31/23 06:10
107-13-1
ND
ug/L
1.0
0.34
1
03/31/23 06:10
71-43-2
ND
ug/L
1.0
0.47
1
03/31/23 06:10
74-97-5
ND
ug/L
1.0
0.31
1
03/31/23 06:10
75-27-4
ND
ug/L
1.0
0.34
1
03/31/23 06:10
75-25-2
ND
ug/L
2.0
1.7
1
03/31/23 06:10
74-83-9
ND
ug/L
5.0
4.0
1
03/31/23 06:10
78-93-3
ND
ug/L
2.0
0.36
1
03/31/23 06:10
75-15-0
ND
ug/L
1.0
0.33
1
03/31/23 06:10
56-23-5
ND
ug/L
1.0
0.28
1
03/31/23 06:10
108-90-7
ND
ug/L
1.0
0.65
1
03/31/23 06:10
75-00-3
ND
ug/L
1.0
0.43
1
03/31/23 06:10
67-66-3
ND
ug/L
1.0
0.54
1
03/31/23 06:10
74-87-3
ND
ug/L
2.0
0.34
1
03/31/23 06:10
96-12-8
ND
ug/L
1.0
0.36
1
03/31/23 06:10
124-48-1
ND
ug/L
1.0
0.27
1
03/31/23 06:10
106-93-4
ND
ug/L
1.0
0.39
1
03/31/23 06:10
74-95-3
ND
ug/L
1.0
0.34
1
03/31/23 06:10
95-50-1
ND
ug/L
1.0
0.33
1
03/31/23 06:10
106-46-7
ND
ug/L
1.0
0.56
1
03/31/23 06:10
110-57-6
ND
ug/L
1.0
0.37
1
03/31/23 06:10
75-34-3
ND
ug/L
1.0
0.32
1
03/31/23 06:10
107-06-2
ND
ug/L
1.0
0.35
1
03/31/23 06:10
75-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 31 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: SW-2 Lab ID: 92659555005 Collected: 03/28/23 00:00 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Calculated Results
Hardness, Total(SM 2340B)
Date: 05/05/2023 12:39 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.38
1
03/31/23 06:10
156-59-2
ND
ug/L
1.0
0.40
1
03/31/23 06:10
156-60-5
ND
ug/L
1.0
0.36
1
03/31/23 06:10
78-87-5
ND
ug/L
1.0
0.36
1
03/31/23 06:10
10061-01-5
ND
ug/L
1.0
0.36
1
03/31/23 06:10
10061-02-6
ND
ug/L
1.0
0.30
1
03/31/23 06:10
100-41-4
ND
ug/L
5.0
0.48
1
03/31/23 06:10
591-78-6
ND
ug/L
20.0
9.7
1
03/31/23 06:10
74-88-4
ND
ug/L
5.0
2.0
1
03/31/23 06:10
75-09-2
ND
ug/L
5.0
2.7
1
03/31/23 06:10
108-10-1
ND
ug/L
1.0
0.29
1
03/31/23 06:10
100-42-5
ND
ug/L
1.0
0.31
1
03/31/23 06:10
630-20-6
ND
ug/L
1.0
0.22
1
03/31/23 06:10
79-34-5
ND
ug/L
1.0
0.29
1
03/31/23 06:10
127-18-4
ND
ug/L
1.0
0.24
1
03/31/23 06:10
108-88-3
ND
ug/L
1.0
0.33
1
03/31/23 06:10
71-55-6
ND
ug/L
1.0
0.32
1
03/31/23 06:10
79-00-5
ND
ug/L
1.0
0.38
1
03/31/23 06:10
79-01-6
ND
ug/L
1.0
0.30
1
03/31/23 06:10
75-69-4
ND
ug/L
1.0
0.26
1
03/31/23 06:10
96-18-4
ND
ug/L
2.0
1.3
1
03/31/23 06:10
108-05-4
ND
ug/L
1.0
0.39
1
03/31/23 06:10
75-01-4
ND
ug/L
1.0
0.34
1
03/31/23 06:10
1330-20-7
100
%
70-130
1
03/31/23 06:10
460-00-4
94
%
70-130
1
03/31/23 06:10
17060-07-0
108
%
70-130
1
03/31/23 06:10
2037-26-5
Analytical Method: EPA 8260D
Mod.
Pace Analytical Services
- Charlotte
5.2
ug/L
2.0
0.86
1
03/31/23 22:32
123-91-1
91
%
67-130
1
03/31/23 22:32
17060-07-0
95
%
70-130
1
03/31/23 22:32
2037-26-5
Analytical Method: SM2340-97 Preparation Method: SM2340B
Pace National - Mt. Juliet
132000
ug/L
2500
198
1 04/03/2312:43
04/03/2312:43
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
IK
Page 32 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: NES-1 Lab ID: 92659555006 Collected: 03/28/23 10:43 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
Metals (ICP) 6010D
Cobalt
8260D MSV Low Level Landfill
Benzene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
5210B BOD, 5 day
BOD, 5 day
300.0 IC Anions 28 Days
Sulfate
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
4500 Chloride
Chloride
5220D COD
Chemical Oxygen Demand
Date: 05/05/2023 12:39 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
ND ug/L 10.0 5.3
1
03/31/2317:41
74-82-8
Analytical Method: EPA 601 OD Preparation Method:
3015
Pace National - Mt. Juliet
ND ug/L 10.0 0.840
1 04/02/2312:18
04/03/2312:51
7440-48-4
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND ug/L 1.0 0.34
1
03/31/23 01:34
71-43-2
104 % 70-130
1
03/31/23 01:34
460-00-4
106 % 70-130
1
03/31/23 01:34
17060-07-0
96 % 70-130
1
03/31/23 01:34
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
ND ug/L 2.0 0.86
1
03/31/23 22:51
123-91-1
83 % 67-130
1
03/31/23 22:51
17060-07-0
92 % 70-130
1
03/31/23 22:51
2037-26-5
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
8900 ug/L 5000 5000
1
04/06/2317:53
Analytical Method: SM 521OB-2016
Pace Analytical Services -Asheville
ND ug/L 2000 2000
1 03/31/23 02:49
04/05/23 01:03
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
6380 ug/L 1000 500
1
04/01 /23 00:46
14808-79-8
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
5640 ug/L 200 50.0
5
03/31/23 04:42
14797-55-8
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
4320 ug/L 1000 500
1
03/30/2319:59
16887-00-6
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
ND ug/L 25000 12500
1 04/07/23 01:26
04/07/23 05:17
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
H2
Page 33 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: NES-1 Lab ID: 92659555006 Collected: 03/28/23 10:43 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon 1110 ug/L 1000 500 1 04/06/23 15:52 7440-44-0
Date: 05/05/2023 12:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 34 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-4
Lab ID:
92659555007
Collected:
03/28/23 14:02
Received: 03/29/23 10:30 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
Chlorinated Herb. (GC) 8151A
Analytical
Method: EPA 8151A
Preparation Method: 8151A
Pace National
- Mt. Juliet
2,4-D
ND
ug/L
2.00
0.547
1
04/04/23 14:45
04/06/23 11:16
94-75-7
R1
Dinoseb
ND
ug/L
2.00
0.250
1
04/04/23 14:45
04/06/23 11:16
88-85-7
2,4,5-T
ND
ug/L
2.00
0.258
1
04/04/23 14:45
04/06/23 11:16
93-76-5
R1
2,4,5-TP (Silvex)
ND
ug/L
2.00
0.335
1
04/04/23 14:45
04/06/23 11:16
93-72-1
R1
Surrogates
2,4-DCAA (S)
71.5
%
14.0-158
1
04/04/23 14:45
04/06/23 11:16
19719-28-9
8081 OC Pesticides RVE
Analytical
Method: EPA 8081
B Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
Aldrin
ND
ug/L
0.042
0.012
1
04/04/23 10:24
04/05/23 13:02
309-00-2
alpha-BHC
ND
ug/L
0.042
0.010
1
04/04/23 10:24
04/05/23 13:02
319-84-6
beta-BHC
ND
ug/L
0.042
0.041
1
04/04/23 10:24
04/05/23 13:02
319-85-7
delta-BHC
ND
ug/L
0.042
0.012
1
04/04/23 10:24
04/05/23 13:02
319-86-8
gamma-BHC (Lindane)
ND
ug/L
0.042
0.010
1
04/04/23 10:24
04/05/23 13:02
58-89-9
Chlordane (Technical)
ND
ug/L
0.42
0.13
1
04/04/23 10:24
04/05/23 13:02
57-74-9
4,4'-DDD
ND
ug/L
0.042
0.014
1
04/04/23 10:24
04/05/23 13:02
72-54-8
4,4'-DDE
ND
ug/L
0.042
0.020
1
04/04/23 10:24
04/05/23 13:02
72-55-9
4,4'-DDT
ND
ug/L
0.042
0.022
1
04/04/23 10:24
04/05/23 13:02
50-29-3
Dieldrin
ND
ug/L
0.042
0.012
1
04/04/23 10:24
04/05/23 13:02
60-57-1
Endosulfan I
ND
ug/L
0.042
0.014
1
04/04/23 10:24
04/05/23 13:02
959-98-8
Endosulfan 11
ND
ug/L
0.042
0.013
1
04/04/23 10:24
04/05/23 13:02
33213-65-9
Endosulfan sulfate
ND
ug/L
0.042
0.012
1
04/04/23 10:24
04/05/23 13:02
1031-07-8
Endrin
ND
ug/L
0.042
0.015
1
04/04/23 10:24
04/05/23 13:02
72-20-8
Endrin aldehyde
ND
ug/L
0.042
0.014
1
04/04/23 10:24
04/05/23 13:02
7421-93-4
Heptachlor
ND
ug/L
0.042
0.016
1
04/04/23 10:24
04/05/23 13:02
76-44-8
Heptachlor epoxide
ND
ug/L
0.042
0.024
1
04/04/23 10:24
04/05/23 13:02
1024-57-3
Methoxychlor
ND
ug/L
0.12
0.035
1
04/04/23 10:24
04/05/23 13:02
72-43-5
Toxaphene
ND
ug/L
0.42
0.18
1
04/04/23 10:24
04/05/23 13:02
8001-35-2
Surrogates
Tetrachloro-m-xylene (S)
191
%
10-182
1
04/04/23 10:24
04/05/23 13:02
877-09-8
S3
Decachlorobiphenyl (S)
149
%
10-200
1
04/04/23 10:24
04/05/23 13:02
2051-24-3
8082 GCS PCB RVE
Analytical
Method: EPA 8082A
Preparation Method:
EPA 3510C
Pace Analytical
Services
- Charlotte
PCB-1016 (Aroclor 1016)
ND
ug/L
0.42
0.18
1
04/05/23 22:15
04/07/23 13:31
12674-11-2
PCB-1221 (Aroclor 1221)
ND
ug/L
0.42
0.19
1
04/05/23 22:15
04/07/23 13:31
11104-28-2
PCB-1232 (Aroclor 1232)
ND
ug/L
0.42
0.19
1
04/05/23 22:15
04/07/23 13:31
11141-16-5
PCB-1242 (Aroclor 1242)
ND
ug/L
0.42
0.21
1
04/05/23 22:15
04/07/23 13:31
53469-21-9
PCB-1248 (Aroclor 1248)
ND
ug/L
0.42
0.24
1
04/05/23 22:15
04/07/23 13:31
12672-29-6
PCB-1254 (Aroclor 1254)
ND
ug/L
0.42
0.18
1
04/05/23 22:15
04/07/23 13:31
11097-69-1
PCB-1260 (Aroclor 1260)
ND
ug/L
0.42
0.13
1
04/05/23 22:15
04/07/23 13:31
11096-82-5
Surrogates
Decachlorobiphenyl (S)
121
%
10-193
1
04/05/23 22:15
04/07/23 13:31
2051-24-3
Date: 05/05/2023 12:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 35 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-4
Lab ID:
92659555007
Collected:
03/28/23 14:02
Received: 03/29/23 10:30 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
Metals (ICP) 6010D
Analytical
Method: EPA 6010D Preparation Method: 3015
Pace National
- Mt. Juliet
Antimony
ND
ug/L
10.0
4.30
1
04/02/2312:18
04/03/2312:54
7440-36-0
Arsenic
ND
ug/L
10.0
4.40
1
04/02/2312:18
04/03/2312:54
7440-38-2
Barium
1.11J
ug/L
5.00
0.736
1
04/02/2312:18
04/03/2312:54
7440-39-3
J
Beryllium
ND
ug/L
2.00
0.330
1
04/02/2312:18
04/03/2312:54
7440-41-7
Cadmium
ND
ug/L
2.00
0.479
1
04/02/2312:18
04/03/2312:54
7440-43-9
Chromium
ND
ug/L
10.0
1.40
1
04/02/2312:18
04/03/2312:54
7440-47-3
Cobalt
2.08J
ug/L
10.0
0.840
1
04/02/2312:18
04/03/2312:54
7440-48-4
J
Copper
8.83.11
ug/L
10.0
3.68
1
04/02/2312:18
04/03/2312:54
7440-50-8
J
Lead
ND
ug/L
6.00
2.99
1
04/02/2312:18
04/03/2312:54
7439-92-1
Nickel
13.9
ug/L
10.0
1.61
1
04/02/2312:18
04/03/2312:54
7440-02-0
B
Selenium
ND
ug/L
10.0
7.35
1
04/02/2312:18
04/03/2312:54
7782-49-2
Silver
ND
ug/L
5.00
1.54
1
04/02/2312:18
04/03/2312:54
7440-22-4
Tin
ND
ug/L
50.0
4.87
1
04/02/2312:18
04/03/2312:54
7440-31-5
Vanadium
ND
ug/L
20.0
4.99
1
04/02/2312:18
04/03/2312:54
7440-62-2
Zinc
11.6J
ug/L
50.0
6.52
1
04/02/2312:18
04/03/2312:54
7440-66-6
J
Metals (ICPMS) 6020B
Analytical
Method: EPA 6020E Preparation Method: 3015
Pace National
- Mt. Juliet
Thallium
ND
ug/L
2.00
0.121
1
04/03/2317:07
04/04/2319:28
7440-28-0
Mercury 7470A
Mercury
8270E APP9 RV
Acenaphthene
Acenaphthylene
Acetophenone
2-Acetylaminofluorene
4-Aminobiphenyl
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Benzyl alcohol
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-ChIoro-3-methyl phenol
4-Chloroaniline
Chlorobenzilate
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
Date: 05/05/2023 12:39 PM
Analytical Method: EPA 7470A Preparation Method: 7470A
Pace National - Mt. Juliet
ND ug/L 0.200 0.100 1 04/05/2315:29 04/07/2312:14 7439-97-6
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
ND
ug/L
8.3
1.7
1
04/01/2312:01
04/02/23 16:32
83-32-9
ND
ug/L
8.3
1.6
1
04/01/2312:01
04/02/23 16:32
208-96-8
ND
ug/L
8.3
1.2
1
04/01/2312:01
04/02/23 16:32
98-86-2
ND
ug/L
8.3
3.4
1
04/01/2312:01
04/02/23 16:32
53-96-3
ND
ug/L
8.3
4.0
1
04/01/2312:01
04/02/23 16:32
92-67-1
ND
ug/L
8.3
1.9
1
04/01/2312:01
04/02/23 16:32
120-12-7
ND
ug/L
8.3
2.2
1
04/01/2312:01
04/02/23 16:32
56-55-3
ND
ug/L
8.3
2.3
1
04/01/2312:01
04/02/23 16:32
50-32-8
ND
ug/L
8.3
2.2
1
04/01/2312:01
04/02/23 16:32
205-99-2
ND
ug/L
8.3
2.4
1
04/01 /23 12:01
04/02/23 16:32
191-24-2
ND
ug/L
8.3
2.3
1
04/01/2312:01
04/02/23 16:32
207-08-9
ND
ug/L
16.7
2.4
1
04/01 /23 12:01
04/02/23 16:32
100-51-6
ND
ug/L
8.3
1.5
1
04/01 /23 12:01
04/02/23 16:32
101-55-3
ND
ug/L
8.3
2.6
1
04/01/2312:01
04/02/23 16:32
85-68-7
ND
ug/L
8.3
2.8
1
04/01/2312:01
04/02/23 16:32
59-50-7
ND
ug/L
16.7
3.0
1
04/01/2312:01
04/02/23 16:32
106-47-8
ND
ug/L
8.3
3.2
1
04/01/2312:01
04/02/23 16:32
510-15-6
ND
ug/L
8.3
1.5
1
04/01 /23 12:01
04/02/23 16:32
111-91-1
ND
ug/L
8.3
1.6
1
04/01 /23 12:01
04/02/23 16:32
111-44-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 36 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-4 Lab ID: 92659555007 Collected: 03/28/23 14:02 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
2-Chloronaphthalene
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 16:32
91-58-7
2-Chlorophenol
ND
ug/L
8.3
1.0
1
04/01/23 12:01
04/02/23 16:32
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 16:32
7005-72-3
Chrysene
ND
ug/L
8.3
2.3
1
04/01/23 12:01
04/02/23 16:32
218-01-9
Diallate
ND
ug/L
8.3
2.8
1
04/01/23 12:01
04/02/23 16:32
2303-16-4
Dibenz(a,h)anthracene
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 16:32
53-70-3
Dibenzofuran
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 16:32
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
16.7
6.8
1
04/01/23 12:01
04/02/23 16:32
91-94-1
2,4-Dichlorophenol
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 16:32
120-83-2
2,6-Dichlorophenol
ND
ug/L
8.3
3.5
1
04/01/23 12:01
04/02/23 16:32
87-65-0
Diethylphthalate
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 16:32
84-66-2
Dimethoate
ND
ug/L
8.3
3.0
1
04/01/23 12:01
04/02/23 16:32
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
4.2
2.0
1
04/01/23 12:01
04/02/23 16:32
60-11-7
7,12-Dimethylbenz(a)anthracene
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 16:32
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
41.7
25.9
1
04/01/23 12:01
04/02/23 16:32
119-93-7
2,4-Dimethylphenol
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 16:32
105-67-9
a,a-Dimethylphenylethylamine
ND
ug/L
83.3
51.7
1
04/01/23 12:01
04/02/23 16:32
122-09-8
Dimethylphthalate
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 16:32
131-11-3
Di-n-butylphthalate
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 16:32
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
16.7
6.5
1
04/01/23 12:01
04/02/23 16:32
534-52-1
1,3-Dinitrobenzene
ND
ug/L
8.3
3.1
1
04/01/23 12:01
04/02/23 16:32
99-65-0
2,4-Dinitrophenol
ND
ug/L
41.7
21.7
1
04/01/23 12:01
04/02/23 16:32
51-28-5
2,4-Dinitrotoluene
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 16:32
121-14-2
2,6-Dinitrotoluene
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 16:32
606-20-2
Di-n-octylphthalate
ND
ug/L
8.3
3.3
1
04/01/23 12:01
04/02/23 16:32
117-84-0
Diphenylamine
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 16:32
122-39-4
Disulfoton
ND
ug/L
8.3
3.9
1
04/01/23 12:01
04/02/23 16:32
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
5.0
3.1
1
04/01/23 12:01
04/02/23 16:32
117-81-7
Ethyl methanesulfonate
ND
ug/L
16.7
2.5
1
04/01/23 12:01
04/02/23 16:32
62-50-0
Famphur
ND
ug/L
8.3
5.1
1
04/01/23 12:01
04/02/23 16:32
52-85-7
Fluoranthene
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 16:32
206-44-0
Fluorene
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 16:32
86-73-7
Hexachlorobenzene
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 16:32
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
8.3
1.3
1
04/01/23 12:01
04/02/23 16:32
77-47-4
Hexachloroethane
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 16:32
67-72-1
Hexachloropropene
ND
ug/L
8.3
2.2
1
04/01/23 12:01
04/02/23 16:32
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
8.3
2.4
1
04/01/23 12:01
04/02/23 16:32
193-39-5
Isodrin
ND
ug/L
8.3
2.3
1
04/01/23 12:01
04/02/23 16:32
465-73-6
Isophorone
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 16:32
78-59-1
Isosafrole
ND
ug/L
8.3
2.1
1
04/01/23 12:01
04/02/23 16:32
120-58-1
Kepone
ND
ug/L
16.7
11.8
1
04/01/23 12:01
04/02/23 16:32
143-50-0
Methapyrilene
ND
ug/L
41.7
14.2
1
04/01/23 12:01
04/02/23 16:32
91-80-5
3-Methylcholanthrene
ND
ug/L
8.3
3.1
1
04/01/23 12:01
04/02/23 16:32
56-49-5
Methyl methanesulfonate
ND
ug/L
4.2
2.6
1
04/01/23 12:01
04/02/23 16:32
66-27-3
2-Methylnaphthalene
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 16:32
91-57-6
REPORT OF LABORATORY ANALYSIS
IL
L1
IH
L1
v2
IH,v1
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-4 Lab ID: 92659555007 Collected: 03/28/23 14:02 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Methyl parathion
ND
ug/L
8.3
3.1
1
04/01/23 12:01
04/02/23 16:32
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 16:32
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
8.3
1.0
1
04/01/23 12:01
04/02/23 16:32
15831-10-4
1-Naphthalenamine
ND
ug/L
8.3
5.0
1
04/01/23 12:01
04/02/23 16:32
134-32-7
2-Naphthalenamine
ND
ug/L
8.3
4.5
1
04/01/23 12:01
04/02/23 16:32
91-59-8
1,4-Naphthoquinone
ND
ug/L
4.2
3.7
1
04/01/23 12:01
04/02/23 16:32
130-15-4
2-Nitroaniline
ND
ug/L
16.7
2.5
1
04/01/23 12:01
04/02/23 16:32
88-74-4
3-Nitroaniline
ND
ug/L
16.7
3.1
1
04/01/23 12:01
04/02/23 16:32
99-09-2
4-Nitroaniline
ND
ug/L
16.7
4.2
1
04/01/23 12:01
04/02/23 16:32
100-01-6
Nitrobenzene
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 16:32
98-95-3
2-Nitrophenol
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 16:32
88-75-5
4-Nitrophenol
ND
ug/L
41.7
5.5
1
04/01/23 12:01
04/02/23 16:32
100-02-7
5-Nitro-o-toluidine
ND
ug/L
8.3
3.2
1
04/01/23 12:01
04/02/23 16:32
99-55-8
N-Nitrosodiethylamine
ND
ug/L
8.3
1.9
1
04/01/23 12:01
04/02/23 16:32
55-18-5
N-Nitrosodimethylamine
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 16:32
62-75-9
N-Nitroso-di-n-butylamine
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 16:32
924-16-3
N-Nitroso-di-n-propylamine
ND
ug/L
8.3
1.1
1
04/01/23 12:01
04/02/23 16:32
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 16:32
86-30-6
N-Nitrosomethylethylamine
ND
ug/L
8.3
6.2
1
04/01/23 12:01
04/02/23 16:32
10595-95-6
N-Nitrosopiperidine
ND
ug/L
8.3
2.1
1
04/01/23 12:01
04/02/23 16:32
100-75-4
N-Nitrosopyrrolidine
ND
ug/L
8.3
2.6
1
04/01/23 12:01
04/02/23 16:32
930-55-2
O,O,O-Triethylphosphorothioate
ND
ug/L
8.3
2.1
1
04/01/23 12:01
04/02/23 16:32
126-68-1
2,2'-Oxybis(1-chloropropane)
ND
ug/L
8.3
0.96
1
04/01/23 12:01
04/02/23 16:32
108-60-1
Parathion (Ethyl parathion)
ND
ug/L
8.3
3.2
1
04/01/23 12:01
04/02/23 16:32
56-38-2
Pentachlorobenzene
ND
ug/L
8.3
2.8
1
04/01/23 12:01
04/02/23 16:32
608-93-5
Pentachloronitrobenzene
ND
ug/L
8.3
2.7
1
04/01/23 12:01
04/02/23 16:32
82-68-8
Pentachlorophenol
ND
ug/L
16.7
3.1
1
04/01/23 12:01
04/02/23 16:32
87-86-5
Phenacetin
ND
ug/L
8.3
3.0
1
04/01/23 12:01
04/02/23 16:32
62-44-2
Phenanthrene
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 16:32
85-01-8
Phenol
ND
ug/L
8.3
1.1
1
04/01/23 12:01
04/02/23 16:32
108-95-2
p-Phenylenediamine
ND
ug/L
8.3
8.3
1
04/01/23 12:01
04/02/23 16:32
106-50-3
Phorate
ND
ug/L
8.3
3.0
1
04/01/23 12:01
04/02/23 16:32
298-02-2
Pronamide
ND
ug/L
8.3
2.6
1
04/01/23 12:01
04/02/23 16:32
23950-58-5
Pyrene
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 16:32
129-00-0
Safrole
ND
ug/L
8.3
1.9
1
04/01/23 12:01
04/02/23 16:32
94-59-7
1,2,4,5-Tetrachlorobenzene
ND
ug/L
8.3
3.7
1
04/01/23 12:01
04/02/23 16:32
95-94-3
2,3,4,6-Tetrachlorophenol
ND
ug/L
8.3
1.3
1
04/01/23 12:01
04/02/23 16:32
58-90-2
Thionazin
ND
ug/L
8.3
2.4
1
04/01/23 12:01
04/02/23 16:32
297-97-2
O-Toluidine
ND
ug/L
8.3
2.2
1
04/01/23 12:01
04/02/23 16:32
95-53-4
2,4,5-Trichlorophenol
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 16:32
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
8.3
1.3
1
04/01/23 12:01
04/02/23 16:32
88-06-2
1,3,5-Trinitrobenzene
ND
ug/L
8.3
4.6
1
04/01/23 12:01
04/02/23 16:32
99-35-4
Surrogates
Nitrobenzene-d5 (S)
97
%
10-138
1
04/01/23 12:01
04/02/23 16:32
4165-60-0
2-Fluorobiphenyl (S)
88
%
10-130
1
04/01/23 12:01
04/02/23 16:32
321-60-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-4 Lab ID: 92659555007 Collected: 03/28/23 14:02 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Surrogates
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV Low Level -Acrolein
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Allyl chloride
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Chloroprene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
Date: 05/05/2023 12:39 PM
111
%
19-191
1
04/01 /23 12:01
04/02/23 16:32
1718-51-0
53
%
10-130
1
04/01 /23 12:01
04/02/23 16:32
13127-88-3
49
%
10-130
1
04/01/2312:01
04/02/23 16:32
367-12-4
91
%
10-164
1
04/01 /23 12:01
04/02/23 16:32
118-79-6
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
45.0 ug/L 2.0
85
%
67-130
93
%
70-130
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
ND
ug/L
50.0
ND
ug/L
10.0
ND
ug/L
10.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
0.79J
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
0.86 1
I
03/31/23 23:10 123-91-1
03/31/23 23:10 17060-07-0
03/31/23 23:10 2037-26-5
5.1
1
03/31/23 04:58
67-64-1
24.8
1
03/31/23 04:58
75-05-8
8.5
1
03/31/23 04:58
107-02-8
1.8
1
03/31/23 04:58
107-13-1
0.50
1
03/31/23 04:58
107-05-1
0.34
1
03/31/23 04:58
71-43-2
0.47
1
03/31/23 04:58
74-97-5
0.31
1
03/31/23 04:58
75-27-4
0.34
1
03/31/23 04:58
75-25-2
1.7
1
03/31/23 04:58
74-83-9
4.0
1
03/31/23 04:58
78-93-3
0.36
1
03/31/23 04:58
75-15-0
0.33
1
03/31/23 04:58
56-23-5
0.28
1
03/31/23 04:58
108-90-7
0.65
1
03/31/23 04:58
75-00-3
0.43
1
03/31/23 04:58
67-66-3
0.54
1
03/31/23 04:58
74-87-3
1.6
1
03/31/23 04:58
126-99-8
0.34
1
03/31/23 04:58
96-12-8
0.36
1
03/31/23 04:58
124-48-1
0.27
1
03/31/23 04:58
106-93-4
0.39
1
03/31/23 04:58
74-95-3
0.34
1
03/31/23 04:58
95-50-1
0.34
1
03/31/23 04:58
541-73-1
0.33
1
03/31/23 04:58
106-46-7
0.56
1
03/31/23 04:58
110-57-6
0.35
1
03/31/23 04:58
75-71-8
0.37
1
03/31/23 04:58
75-34-3
0.32
1
03/31/23 04:58
107-06-2
0.35
1
03/31/23 04:58
75-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v1
v1
Page 39 of 155

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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-4 Lab ID: 92659555007 Collected: 03/28/23 14:02 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level -Acrolein
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Ethyl methacrylate
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
4-Methyl-2-pentanone (MIBK)
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
Date: 05/05/2023 12:39 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.38
1
03/31/23 04:58
156-59-2
ND
ug/L
1.0
0.40
1
03/31/23 04:58
156-60-5
ND
ug/L
1.0
0.36
1
03/31/23 04:58
78-87-5
ND
ug/L
1.0
0.28
1
03/31/23 04:58
142-28-9
ND
ug/L
1.0
0.39
1
03/31/23 04:58
594-20-7
ND
ug/L
1.0
0.43
1
03/31/23 04:58
563-58-6
ND
ug/L
1.0
0.36
1
03/31/23 04:58
10061-01-5
ND
ug/L
1.0
0.36
1
03/31/23 04:58
10061-02-6
ND
ug/L
1.0
0.30
1
03/31/23 04:58
100-41-4
ND
ug/L
1.0
0.28
1
03/31/23 04:58
97-63-2
ND
ug/L
2.0
1.5
1
03/31/23 04:58
87-68-3
ND
ug/L
5.0
0.48
1
03/31/23 04:58
591-78-6
ND
ug/L
20.0
9.7
1
03/31/23 04:58
74-88-4
ND
ug/L
100
52.3
1
03/31/23 04:58
78-83-1
ND
ug/L
10.0
4.2
1
03/31/23 04:58
126-98-7
ND
ug/L
5.0
2.0
1
03/31/23 04:58
75-09-2
ND
ug/L
2.0
0.32
1
03/31/23 04:58
80-62-6
ND
ug/L
5.0
2.7
1
03/31/23 04:58
108-10-1
ND
ug/L
1.0
0.64
1
03/31/23 04:58
91-20-3
ND
ug/L
20.0
3.6
1
03/31/23 04:58
107-12-0
ND
ug/L
1.0
0.29
1
03/31/23 04:58
100-42-5
ND
ug/L
1.0
0.31
1
03/31/23 04:58
630-20-6
ND
ug/L
1.0
0.22
1
03/31/23 04:58
79-34-5
ND
ug/L
1.0
0.29
1
03/31/23 04:58
127-18-4
ND
ug/L
1.0
0.24
1
03/31/23 04:58
108-88-3
ND
ug/L
1.0
0.64
1
03/31/23 04:58
120-82-1
ND
ug/L
1.0
0.33
1
03/31/23 04:58
71-55-6
ND
ug/L
1.0
0.32
1
03/31/23 04:58
79-00-5
ND
ug/L
1.0
0.38
1
03/31/23 04:58
79-01-6
ND
ug/L
1.0
0.30
1
03/31/23 04:58
75-69-4
ND
ug/L
1.0
0.26
1
03/31/23 04:58
96-18-4
ND
ug/L
2.0
1.3
1
03/31/23 04:58
108-05-4
ND
ug/L
1.0
0.39
1
03/31/23 04:58
75-01-4
ND
ug/L
1.0
0.34
1
03/31/23 04:58
1330-20-7
111
%
70-130
1
03/31/23 04:58
460-00-4
109
%
70-130
1
03/31/23 04:58
17060-07-0
104
%
70-130
1
03/31/23 04:58
2037-26-5
v1
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND ug/L 100 22.0 1 03/31/23 02:50 18496-25-8
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 40 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-4 Lab ID: 92659555007 Collected: 03/28/23 14:02 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
4500CNE Cyanide, Total Analytical Method: SM 4500-CN-E-2016 Preparation Method: SM 4500-CN-E-2016
Pace Analytical Services -Asheville
Cyanide ND ug/L 8.0 6.0 1 04/03/23 18:41 04/03/23 22:00 57-12-5
Date: 05/05/2023 12:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 41 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-5
Lab ID:
92659555008
Collected:
03/28/23 15:56
Received: 03/29/23 10:30 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
Chlorinated Herb. (GC) 8151A
Analytical
Method: EPA 8151A
Preparation Method: 8151A
Pace National
- Mt. Juliet
2,4-D
ND
ug/L
2.00
0.547
1
04/04/23 14:45
04/06/23 11:27
94-75-7 R1
Dinoseb
ND
ug/L
2.00
0.250
1
04/04/23 14:45
04/06/23 11:27
88-85-7
2,4,5-T
ND
ug/L
2.00
0.258
1
04/04/23 14:45
04/06/23 11:27
93-76-5 R1
2,4,5-TP (Silvex)
ND
ug/L
2.00
0.335
1
04/04/23 14:45
04/06/23 11:27
93-72-1 R1
Surrogates
2,4-DCAA (S)
48.4
%
14.0-158
1
04/04/23 14:45
04/06/23 11:27
19719-28-9
8081 OC Pesticides RVE
Analytical
Method: EPA 8081
B Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
Aldrin
ND
ug/L
0.042
0.012
1
04/04/23 10:24
04/05/23 13:15
309-00-2
alpha-BHC
ND
ug/L
0.042
0.010
1
04/04/23 10:24
04/05/23 13:15
319-84-6
beta-BHC
ND
ug/L
0.042
0.041
1
04/04/23 10:24
04/05/23 13:15
319-85-7
delta-BHC
ND
ug/L
0.042
0.012
1
04/04/23 10:24
04/05/23 13:15
319-86-8
gamma-BHC (Lindane)
ND
ug/L
0.042
0.010
1
04/04/23 10:24
04/05/23 13:15
58-89-9
Chlordane (Technical)
ND
ug/L
0.42
0.13
1
04/04/23 10:24
04/05/23 13:15
57-74-9
4,4'-DDD
ND
ug/L
0.042
0.014
1
04/04/23 10:24
04/05/23 13:15
72-54-8
4,4'-DDE
ND
ug/L
0.042
0.020
1
04/04/23 10:24
04/05/23 13:15
72-55-9
4,4'-DDT
ND
ug/L
0.042
0.022
1
04/04/23 10:24
04/05/23 13:15
50-29-3
Dieldrin
ND
ug/L
0.042
0.012
1
04/04/23 10:24
04/05/23 13:15
60-57-1
Endosulfan I
ND
ug/L
0.042
0.014
1
04/04/23 10:24
04/05/23 13:15
959-98-8
Endosulfan 11
ND
ug/L
0.042
0.013
1
04/04/23 10:24
04/05/23 13:15
33213-65-9
Endosulfan sulfate
ND
ug/L
0.042
0.012
1
04/04/23 10:24
04/05/23 13:15
1031-07-8
Endrin
ND
ug/L
0.042
0.015
1
04/04/23 10:24
04/05/23 13:15
72-20-8
Endrin aldehyde
ND
ug/L
0.042
0.014
1
04/04/23 10:24
04/05/23 13:15
7421-93-4
Heptachlor
ND
ug/L
0.042
0.016
1
04/04/23 10:24
04/05/23 13:15
76-44-8
Heptachlor epoxide
ND
ug/L
0.042
0.024
1
04/04/23 10:24
04/05/23 13:15
1024-57-3
Methoxychlor
ND
ug/L
0.12
0.035
1
04/04/23 10:24
04/05/23 13:15
72-43-5
Toxaphene
ND
ug/L
0.42
0.18
1
04/04/23 10:24
04/05/23 13:15
8001-35-2
Surrogates
Tetrachloro-m-xylene (S)
90
%
10-182
1
04/04/23 10:24
04/05/23 13:15
877-09-8
Decachlorobiphenyl (S)
120
%
10-200
1
04/04/23 10:24
04/05/23 13:15
2051-24-3
8082 GCS PCB RVE
Analytical
Method: EPA 8082A
Preparation Method:
EPA 3510C
Pace Analytical
Services
- Charlotte
PCB-1016 (Aroclor 1016)
ND
ug/L
0.42
0.18
1
04/05/23 22:15
04/07/23 13:44
12674-11-2
PCB-1221 (Aroclor 1221)
ND
ug/L
0.42
0.19
1
04/05/23 22:15
04/07/23 13:44
11104-28-2
PCB-1232 (Aroclor 1232)
ND
ug/L
0.42
0.19
1
04/05/23 22:15
04/07/23 13:44
11141-16-5
PCB-1242 (Aroclor 1242)
ND
ug/L
0.42
0.21
1
04/05/23 22:15
04/07/23 13:44
53469-21-9
PCB-1248 (Aroclor 1248)
ND
ug/L
0.42
0.24
1
04/05/23 22:15
04/07/23 13:44
12672-29-6
PCB-1254 (Aroclor 1254)
ND
ug/L
0.42
0.18
1
04/05/23 22:15
04/07/23 13:44
11097-69-1
PCB-1260 (Aroclor 1260)
ND
ug/L
0.42
0.13
1
04/05/23 22:15
04/07/23 13:44
11096-82-5
Surrogates
Decachlorobiphenyl (S)
118
%
10-193
1
04/05/23 22:15
04/07/23 13:44
2051-24-3
Date: 05/05/2023 12:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 42 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-5
Lab ID:
92659555008
Collected:
03/28/23 15:56
Received: 03/29/23 10:30 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
Metals (ICP) 6010D
Analytical
Method: EPA 601 OD Preparation Method: 3015
Pace National
- Mt. Juliet
Antimony
ND
ug/L
10.0
4.30
1
04/02/2312:18
04/03/2312:56
7440-36-0
Arsenic
ND
ug/L
10.0
4.40
1
04/02/2312:18
04/03/2312:56
7440-38-2
Barium
206
ug/L
5.00
0.736
1
04/02/2312:18
04/03/2312:56
7440-39-3
Beryllium
0.542J
ug/L
2.00
0.330
1
04/02/2312:18
04/03/2312:56
7440-41-7
J
Cadmium
ND
ug/L
2.00
0.479
1
04/02/2312:18
04/03/2312:56
7440-43-9
Chromium
ND
ug/L
10.0
1.40
1
04/02/2312:18
04/03/2312:56
7440-47-3
Cobalt
9.82J
ug/L
10.0
0.840
1
04/02/2312:18
04/03/2312:56
7440-48-4
J
Copper
17.1
ug/L
10.0
3.68
1
04/02/2312:18
04/03/2312:56
7440-50-8
Lead
ND
ug/L
6.00
2.99
1
04/02/2312:18
04/03/2312:56
7439-92-1
Nickel
3.72J
ug/L
10.0
1.61
1
04/02/2312:18
04/03/2312:56
7440-02-0
B,J
Selenium
ND
ug/L
10.0
7.35
1
04/02/2312:18
04/03/2312:56
7782-49-2
Silver
ND
ug/L
5.00
1.54
1
04/02/2312:18
04/03/2312:56
7440-22-4
Tin
ND
ug/L
50.0
4.87
1
04/02/2312:18
04/03/2312:56
7440-31-5
Vanadium
ND
ug/L
20.0
4.99
1
04/02/2312:18
04/03/2312:56
7440-62-2
Zinc
19.8J
ug/L
50.0
6.52
1
04/02/2312:18
04/03/2312:56
7440-66-6
J
Metals (ICPMS) 6020B
Analytical
Method: EPA 6020E Preparation Method: 3015
Pace National
- Mt. Juliet
Thallium
ND
ug/L
2.00
0.121
1
04/03/2317:07
04/04/2319:32
7440-28-0
Mercury 7470A
Mercury
8270E APP9 RV
Acenaphthene
Acenaphthylene
Acetophenone
2-Acetylaminofluorene
4-Aminobiphenyl
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Benzyl alcohol
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-ChIoro-3-methyl phenol
4-Chloroaniline
Chlorobenzilate
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
Date: 05/05/2023 12:39 PM
Analytical Method: EPA 7470A Preparation Method: 7470A
Pace National - Mt. Juliet
ND ug/L 0.200 0.100 1 04/05/2315:29 04/07/2312:16 7439-97-6
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
ND
ug/L
8.3
1.7
1
04/01/2312:01
04/02/23 16:58
83-32-9
ND
ug/L
8.3
1.6
1
04/01/2312:01
04/02/23 16:58
208-96-8
ND
ug/L
8.3
1.2
1
04/01/2312:01
04/02/23 16:58
98-86-2
ND
ug/L
8.3
3.4
1
04/01/2312:01
04/02/23 16:58
53-96-3
ND
ug/L
8.3
4.0
1
04/01/2312:01
04/02/23 16:58
92-67-1
ND
ug/L
8.3
1.9
1
04/01/2312:01
04/02/23 16:58
120-12-7
ND
ug/L
8.3
2.2
1
04/01/2312:01
04/02/23 16:58
56-55-3
ND
ug/L
8.3
2.3
1
04/01/2312:01
04/02/23 16:58
50-32-8
ND
ug/L
8.3
2.2
1
04/01/2312:01
04/02/23 16:58
205-99-2
ND
ug/L
8.3
2.4
1
04/01 /23 12:01
04/02/23 16:58
191-24-2
ND
ug/L
8.3
2.3
1
04/01/2312:01
04/02/23 16:58
207-08-9
ND
ug/L
16.7
2.4
1
04/01 /23 12:01
04/02/23 16:58
100-51-6
ND
ug/L
8.3
1.5
1
04/01 /23 12:01
04/02/23 16:58
101-55-3
ND
ug/L
8.3
2.6
1
04/01/2312:01
04/02/23 16:58
85-68-7
ND
ug/L
8.3
2.8
1
04/01/2312:01
04/02/23 16:58
59-50-7
ND
ug/L
16.7
3.0
1
04/01/2312:01
04/02/23 16:58
106-47-8
ND
ug/L
8.3
3.2
1
04/01/2312:01
04/02/23 16:58
510-15-6
ND
ug/L
8.3
1.5
1
04/01 /23 12:01
04/02/23 16:58
111-91-1
ND
ug/L
8.3
1.6
1
04/01 /23 12:01
04/02/23 16:58
111-44-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 43 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-5 Lab ID: 92659555008 Collected: 03/28/23 15:56 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
2-Chloronaphthalene
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 16:58
91-58-7
2-Chlorophenol
ND
ug/L
8.3
1.0
1
04/01/23 12:01
04/02/23 16:58
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 16:58
7005-72-3
Chrysene
ND
ug/L
8.3
2.3
1
04/01/23 12:01
04/02/23 16:58
218-01-9
Diallate
ND
ug/L
8.3
2.8
1
04/01/23 12:01
04/02/23 16:58
2303-16-4
Dibenz(a,h)anthracene
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 16:58
53-70-3
Dibenzofuran
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 16:58
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
16.7
6.8
1
04/01/23 12:01
04/02/23 16:58
91-94-1
2,4-Dichlorophenol
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 16:58
120-83-2
2,6-Dichlorophenol
ND
ug/L
8.3
3.5
1
04/01/23 12:01
04/02/23 16:58
87-65-0
Diethylphthalate
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 16:58
84-66-2
Dimethoate
ND
ug/L
8.3
3.0
1
04/01/23 12:01
04/02/23 16:58
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
4.2
2.0
1
04/01/23 12:01
04/02/23 16:58
60-11-7
7,12-Dimethylbenz(a)anthracene
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 16:58
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
41.7
25.9
1
04/01/23 12:01
04/02/23 16:58
119-93-7
2,4-Dimethylphenol
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 16:58
105-67-9
a,a-Dimethylphenylethylamine
ND
ug/L
83.3
51.7
1
04/01/23 12:01
04/02/23 16:58
122-09-8
Dimethylphthalate
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 16:58
131-11-3
Di-n-butylphthalate
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 16:58
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
16.7
6.5
1
04/01/23 12:01
04/02/23 16:58
534-52-1
1,3-Dinitrobenzene
ND
ug/L
8.3
3.1
1
04/01/23 12:01
04/02/23 16:58
99-65-0
2,4-Dinitrophenol
ND
ug/L
41.7
21.7
1
04/01/23 12:01
04/02/23 16:58
51-28-5
2,4-Dinitrotoluene
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 16:58
121-14-2
2,6-Dinitrotoluene
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 16:58
606-20-2
Di-n-octylphthalate
ND
ug/L
8.3
3.3
1
04/01/23 12:01
04/02/23 16:58
117-84-0
Diphenylamine
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 16:58
122-39-4
Disulfoton
ND
ug/L
8.3
3.9
1
04/01/23 12:01
04/02/23 16:58
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
5.0
3.1
1
04/01/23 12:01
04/02/23 16:58
117-81-7
Ethyl methanesulfonate
ND
ug/L
16.7
2.5
1
04/01/23 12:01
04/02/23 16:58
62-50-0
Famphur
ND
ug/L
8.3
5.1
1
04/01/23 12:01
04/02/23 16:58
52-85-7
Fluoranthene
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 16:58
206-44-0
Fluorene
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 16:58
86-73-7
Hexachlorobenzene
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 16:58
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
8.3
1.3
1
04/01/23 12:01
04/02/23 16:58
77-47-4
Hexachloroethane
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 16:58
67-72-1
Hexachloropropene
ND
ug/L
8.3
2.2
1
04/01/23 12:01
04/02/23 16:58
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
8.3
2.4
1
04/01/23 12:01
04/02/23 16:58
193-39-5
Isodrin
ND
ug/L
8.3
2.3
1
04/01/23 12:01
04/02/23 16:58
465-73-6
Isophorone
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 16:58
78-59-1
Isosafrole
ND
ug/L
8.3
2.1
1
04/01/23 12:01
04/02/23 16:58
120-58-1
Kepone
ND
ug/L
16.7
11.8
1
04/01/23 12:01
04/02/23 16:58
143-50-0
Methapyrilene
ND
ug/L
41.7
14.2
1
04/01/23 12:01
04/02/23 16:58
91-80-5
3-Methylcholanthrene
ND
ug/L
8.3
3.1
1
04/01/23 12:01
04/02/23 16:58
56-49-5
Methyl methanesulfonate
ND
ug/L
4.2
2.6
1
04/01/23 12:01
04/02/23 16:58
66-27-3
2-Methylnaphthalene
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 16:58
91-57-6
REPORT OF LABORATORY ANALYSIS
IL
L1
IH
L1
v2
IH,v1
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-5 Lab ID: 92659555008 Collected: 03/28/23 15:56 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Methyl parathion
ND
ug/L
8.3
3.1
1
04/01/23 12:01
04/02/23 16:58
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 16:58
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
8.3
1.0
1
04/01/23 12:01
04/02/23 16:58
15831-10-4
1-Naphthalenamine
ND
ug/L
8.3
5.0
1
04/01/23 12:01
04/02/23 16:58
134-32-7
2-Naphthalenamine
ND
ug/L
8.3
4.5
1
04/01/23 12:01
04/02/23 16:58
91-59-8
1,4-Naphthoquinone
ND
ug/L
4.2
3.7
1
04/01/23 12:01
04/02/23 16:58
130-15-4
2-Nitroaniline
ND
ug/L
16.7
2.5
1
04/01/23 12:01
04/02/23 16:58
88-74-4
3-Nitroaniline
ND
ug/L
16.7
3.1
1
04/01/23 12:01
04/02/23 16:58
99-09-2
4-Nitroaniline
ND
ug/L
16.7
4.2
1
04/01/23 12:01
04/02/23 16:58
100-01-6
Nitrobenzene
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 16:58
98-95-3
2-Nitrophenol
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 16:58
88-75-5
4-Nitrophenol
ND
ug/L
41.7
5.5
1
04/01/23 12:01
04/02/23 16:58
100-02-7
5-Nitro-o-toluidine
ND
ug/L
8.3
3.2
1
04/01/23 12:01
04/02/23 16:58
99-55-8
N-Nitrosodiethylamine
ND
ug/L
8.3
1.9
1
04/01/23 12:01
04/02/23 16:58
55-18-5
N-Nitrosodimethylamine
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 16:58
62-75-9
N-Nitroso-di-n-butylamine
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 16:58
924-16-3
N-Nitroso-di-n-propylamine
ND
ug/L
8.3
1.1
1
04/01/23 12:01
04/02/23 16:58
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 16:58
86-30-6
N-Nitrosomethylethylamine
ND
ug/L
8.3
6.2
1
04/01/23 12:01
04/02/23 16:58
10595-95-6
N-Nitrosopiperidine
ND
ug/L
8.3
2.1
1
04/01/23 12:01
04/02/23 16:58
100-75-4
N-Nitrosopyrrolidine
ND
ug/L
8.3
2.6
1
04/01/23 12:01
04/02/23 16:58
930-55-2
O,O,O-Triethylphosphorothioate
ND
ug/L
8.3
2.1
1
04/01/23 12:01
04/02/23 16:58
126-68-1
2,2'-Oxybis(1-chloropropane)
ND
ug/L
8.3
0.96
1
04/01/23 12:01
04/02/23 16:58
108-60-1
Parathion (Ethyl parathion)
ND
ug/L
8.3
3.2
1
04/01/23 12:01
04/02/23 16:58
56-38-2
Pentachlorobenzene
ND
ug/L
8.3
2.8
1
04/01/23 12:01
04/02/23 16:58
608-93-5
Pentachloronitrobenzene
ND
ug/L
8.3
2.7
1
04/01/23 12:01
04/02/23 16:58
82-68-8
Pentachlorophenol
ND
ug/L
16.7
3.1
1
04/01/23 12:01
04/02/23 16:58
87-86-5
Phenacetin
ND
ug/L
8.3
3.0
1
04/01/23 12:01
04/02/23 16:58
62-44-2
Phenanthrene
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 16:58
85-01-8
Phenol
ND
ug/L
8.3
1.1
1
04/01/23 12:01
04/02/23 16:58
108-95-2
p-Phenylenediamine
ND
ug/L
8.3
8.3
1
04/01/23 12:01
04/02/23 16:58
106-50-3
Phorate
ND
ug/L
8.3
3.0
1
04/01/23 12:01
04/02/23 16:58
298-02-2
Pronamide
ND
ug/L
8.3
2.6
1
04/01/23 12:01
04/02/23 16:58
23950-58-5
Pyrene
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 16:58
129-00-0
Safrole
ND
ug/L
8.3
1.9
1
04/01/23 12:01
04/02/23 16:58
94-59-7
1,2,4,5-Tetrachlorobenzene
ND
ug/L
8.3
3.7
1
04/01/23 12:01
04/02/23 16:58
95-94-3
2,3,4,6-Tetrachlorophenol
ND
ug/L
8.3
1.3
1
04/01/23 12:01
04/02/23 16:58
58-90-2
Thionazin
ND
ug/L
8.3
2.4
1
04/01/23 12:01
04/02/23 16:58
297-97-2
O-Toluidine
ND
ug/L
8.3
2.2
1
04/01/23 12:01
04/02/23 16:58
95-53-4
2,4,5-Trichlorophenol
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 16:58
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
8.3
1.3
1
04/01/23 12:01
04/02/23 16:58
88-06-2
1,3,5-Trinitrobenzene
ND
ug/L
8.3
4.6
1
04/01/23 12:01
04/02/23 16:58
99-35-4
Surrogates
Nitrobenzene-d5 (S)
84
%
10-138
1
04/01/23 12:01
04/02/23 16:58
4165-60-0
2-Fluorobiphenyl (S)
71
%
10-130
1
04/01/23 12:01
04/02/23 16:58
321-60-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-5 Lab ID: 92659555008 Collected: 03/28/23 15:56 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Surrogates
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV Low Level -Acrolein
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Allyl chloride
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Chloroprene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
Date: 05/05/2023 12:39 PM
106
%
19-191
1
04/01 /23 12:01
04/02/23 16:58
1718-51-0
46
%
10-130
1
04/01 /23 12:01
04/02/23 16:58
13127-88-3
57
%
10-130
1
04/01/2312:01
04/02/23 16:58
367-12-4
108
%
10-164
1
04/01 /23 12:01
04/02/23 16:58
118-79-6
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
1.6J
ug/L
2.0
0.86
1
03/31/23 23:29
123-91-1 C8
86
%
67-130
1
03/31/23 23:29
17060-07-0
92
%
70-130
1
03/31/23 23:29
2037-26-5
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
25.0
5.1
1
03/31/23 02:38
67-64-1 v1
ND
ug/L
50.0
24.8
1
03/31/23 02:38
75-05-8
ND
ug/L
10.0
8.5
1
03/31/23 02:38
107-02-8
ND
ug/L
10.0
1.8
1
03/31/23 02:38
107-13-1
ND
ug/L
2.0
0.50
1
03/31/23 02:38
107-05-1
ND
ug/L
1.0
0.34
1
03/31/23 02:38
71-43-2
ND
ug/L
1.0
0.47
1
03/31/23 02:38
74-97-5
ND
ug/L
1.0
0.31
1
03/31/23 02:38
75-27-4
ND
ug/L
1.0
0.34
1
03/31/23 02:38
75-25-2
ND
ug/L
2.0
1.7
1
03/31/23 02:38
74-83-9
ND
ug/L
5.0
4.0
1
03/31/23 02:38
78-93-3
ND
ug/L
2.0
0.36
1
03/31/23 02:38
75-15-0
ND
ug/L
1.0
0.33
1
03/31/23 02:38
56-23-5
ND
ug/L
1.0
0.28
1
03/31/23 02:38
108-90-7
ND
ug/L
1.0
0.65
1
03/31/23 02:38
75-00-3
ND
ug/L
1.0
0.43
1
03/31/23 02:38
67-66-3
ND
ug/L
1.0
0.54
1
03/31/23 02:38
74-87-3 v1
ND
ug/L
5.0
1.6
1
03/31/23 02:38
126-99-8
ND
ug/L
2.0
0.34
1
03/31/23 02:38
96-12-8
ND
ug/L
1.0
0.36
1
03/31/23 02:38
124-48-1
ND
ug/L
1.0
0.27
1
03/31/23 02:38
106-93-4
ND
ug/L
1.0
0.39
1
03/31/23 02:38
74-95-3
ND
ug/L
1.0
0.34
1
03/31/23 02:38
95-50-1
ND
ug/L
1.0
0.34
1
03/31/23 02:38
541-73-1
ND
ug/L
1.0
0.33
1
03/31/23 02:38
106-46-7
ND
ug/L
1.0
0.56
1
03/31/23 02:38
110-57-6
ND
ug/L
1.0
0.35
1
03/31/23 02:38
75-71-8
ND
ug/L
1.0
0.37
1
03/31/23 02:38
75-34-3
ND
ug/L
1.0
0.32
1
03/31/23 02:38
107-06-2
ND
ug/L
1.0
0.35
1
03/31/23 02:38
75-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 46 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-5 Lab ID: 92659555008 Collected: 03/28/23 15:56 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level -Acrolein
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Ethyl methacrylate
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
4-Methyl-2-pentanone (MIBK)
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
Date: 05/05/2023 12:39 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.38
1
03/31/23 02:38
156-59-2
ND
ug/L
1.0
0.40
1
03/31/23 02:38
156-60-5
ND
ug/L
1.0
0.36
1
03/31/23 02:38
78-87-5
ND
ug/L
1.0
0.28
1
03/31/23 02:38
142-28-9
ND
ug/L
1.0
0.39
1
03/31/23 02:38
594-20-7
ND
ug/L
1.0
0.43
1
03/31/23 02:38
563-58-6
ND
ug/L
1.0
0.36
1
03/31/23 02:38
10061-01-5
ND
ug/L
1.0
0.36
1
03/31/23 02:38
10061-02-6
ND
ug/L
1.0
0.30
1
03/31/23 02:38
100-41-4
ND
ug/L
1.0
0.28
1
03/31/23 02:38
97-63-2
ND
ug/L
2.0
1.5
1
03/31/23 02:38
87-68-3
ND
ug/L
5.0
0.48
1
03/31/23 02:38
591-78-6
ND
ug/L
20.0
9.7
1
03/31/23 02:38
74-88-4
ND
ug/L
100
52.3
1
03/31/23 02:38
78-83-1
ND
ug/L
10.0
4.2
1
03/31/23 02:38
126-98-7
ND
ug/L
5.0
2.0
1
03/31/23 02:38
75-09-2
ND
ug/L
2.0
0.32
1
03/31/23 02:38
80-62-6
ND
ug/L
5.0
2.7
1
03/31/23 02:38
108-10-1
ND
ug/L
1.0
0.64
1
03/31/23 02:38
91-20-3
ND
ug/L
20.0
3.6
1
03/31/23 02:38
107-12-0
ND
ug/L
1.0
0.29
1
03/31/23 02:38
100-42-5
ND
ug/L
1.0
0.31
1
03/31/23 02:38
630-20-6
ND
ug/L
1.0
0.22
1
03/31/23 02:38
79-34-5
ND
ug/L
1.0
0.29
1
03/31/23 02:38
127-18-4
ND
ug/L
1.0
0.24
1
03/31/23 02:38
108-88-3
ND
ug/L
1.0
0.64
1
03/31/23 02:38
120-82-1
ND
ug/L
1.0
0.33
1
03/31/23 02:38
71-55-6
ND
ug/L
1.0
0.32
1
03/31/23 02:38
79-00-5
ND
ug/L
1.0
0.38
1
03/31/23 02:38
79-01-6
ND
ug/L
1.0
0.30
1
03/31/23 02:38
75-69-4
ND
ug/L
1.0
0.26
1
03/31/23 02:38
96-18-4
ND
ug/L
2.0
1.3
1
03/31/23 02:38
108-05-4
ND
ug/L
1.0
0.39
1
03/31/23 02:38
75-01-4
ND
ug/L
1.0
0.34
1
03/31/23 02:38
1330-20-7
108
%
70-130
1
03/31/23 02:38
460-00-4
117
%
70-130
1
03/31/23 02:38
17060-07-0
119
%
70-130
1
03/31/23 02:38
2037-26-5
v1
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND ug/L 100 22.0 1 03/31/23 02:51 18496-25-8
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 47 of 155

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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-5 Lab ID: 92659555008 Collected: 03/28/23 15:56 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
4500CNE Cyanide, Total Analytical Method: SM 4500-CN-E-2016 Preparation Method: SM 4500-CN-E-2016
Pace Analytical Services -Asheville
Cyanide ND ug/L 8.0 6.0 1 04/03/23 18:41 04/03/23 22:01 57-12-5
Date: 05/05/2023 12:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 48 of 155

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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-6
Lab ID:
92659555009
Collected:
03/28/23 14:32
Received: 03/29/23 10:30 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
Chlorinated Herb. (GC) 8151A
Analytical
Method: EPA 8151A
Preparation Method: 8151A
Pace National
- Mt. Juliet
2,4-D
ND
ug/L
2.00
0.547
1
04/04/23 14:45
04/06/23 11:38
94-75-7 R1
Dinoseb
ND
ug/L
2.00
0.250
1
04/04/23 14:45
04/06/23 11:38
88-85-7
2,4,5-T
ND
ug/L
2.00
0.258
1
04/04/23 14:45
04/06/23 11:38
93-76-5 R1
2,4,5-TP (Silvex)
ND
ug/L
2.00
0.335
1
04/04/23 14:45
04/06/23 11:38
93-72-1 R1
Surrogates
2,4-DCAA (S)
59.6
%
14.0-158
1
04/04/23 14:45
04/06/23 11:38
19719-28-9
8081 OC Pesticides RVE
Analytical
Method: EPA 8081
B Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
Aldrin
ND
ug/L
0.050
0.014
1
04/04/23 10:24
04/05/23 13:28
309-00-2
alpha-BHC
ND
ug/L
0.050
0.012
1
04/04/23 10:24
04/05/23 13:28
319-84-6
beta-BHC
ND
ug/L
0.050
0.049
1
04/04/23 10:24
04/05/23 13:28
319-85-7
delta-BHC
ND
ug/L
0.050
0.014
1
04/04/23 10:24
04/05/23 13:28
319-86-8
gamma-BHC (Lindane)
ND
ug/L
0.050
0.012
1
04/04/23 10:24
04/05/23 13:28
58-89-9
Chlordane (Technical)
ND
ug/L
0.50
0.16
1
04/04/23 10:24
04/05/23 13:28
57-74-9
4,4'-DDD
ND
ug/L
0.050
0.017
1
04/04/23 10:24
04/05/23 13:28
72-54-8
4,4'-DDE
ND
ug/L
0.050
0.024
1
04/04/23 10:24
04/05/23 13:28
72-55-9
4,4'-DDT
ND
ug/L
0.050
0.026
1
04/04/23 10:24
04/05/23 13:28
50-29-3
Dieldrin
ND
ug/L
0.050
0.015
1
04/04/23 10:24
04/05/23 13:28
60-57-1
Endosulfan I
ND
ug/L
0.050
0.017
1
04/04/23 10:24
04/05/23 13:28
959-98-8
Endosulfan 11
ND
ug/L
0.050
0.016
1
04/04/23 10:24
04/05/23 13:28
33213-65-9
Endosulfan sulfate
ND
ug/L
0.050
0.015
1
04/04/23 10:24
04/05/23 13:28
1031-07-8
Endrin
ND
ug/L
0.050
0.018
1
04/04/23 10:24
04/05/23 13:28
72-20-8
Endrin aldehyde
ND
ug/L
0.050
0.016
1
04/04/23 10:24
04/05/23 13:28
7421-93-4
Heptachlor
ND
ug/L
0.050
0.020
1
04/04/23 10:24
04/05/23 13:28
76-44-8
Heptachlor epoxide
ND
ug/L
0.050
0.028
1
04/04/23 10:24
04/05/23 13:28
1024-57-3
Methoxychlor
ND
ug/L
0.15
0.042
1
04/04/23 10:24
04/05/23 13:28
72-43-5
Toxaphene
ND
ug/L
0.50
0.22
1
04/04/23 10:24
04/05/23 13:28
8001-35-2
Surrogates
Tetrachloro-m-xylene (S)
79
%
10-182
1
04/04/23 10:24
04/05/23 13:28
877-09-8
Decachlorobiphenyl (S)
121
%
10-200
1
04/04/23 10:24
04/05/23 13:28
2051-24-3
8082 GCS PCB RVE
Analytical
Method: EPA 8082A
Preparation Method:
EPA 3510C
Pace Analytical
Services
- Charlotte
PCB-1016 (Aroclor 1016)
ND
ug/L
0.043
0.018
1
04/05/23 22:15
04/07/23 13:57
12674-11-2
PCB-1221 (Aroclor 1221)
ND
ug/L
0.043
0.020
1
04/05/23 22:15
04/07/23 13:57
11104-28-2
PCB-1232 (Aroclor 1232)
ND
ug/L
0.043
0.020
1
04/05/23 22:15
04/07/23 13:57
11141-16-5
PCB-1242 (Aroclor 1242)
ND
ug/L
0.043
0.022
1
04/05/23 22:15
04/07/23 13:57
53469-21-9
PCB-1248 (Aroclor 1248)
ND
ug/L
0.043
0.025
1
04/05/23 22:15
04/07/23 13:57
12672-29-6
PCB-1254 (Aroclor 1254)
ND
ug/L
0.043
0.018
1
04/05/23 22:15
04/07/23 13:57
11097-69-1
PCB-1260 (Aroclor 1260)
ND
ug/L
0.043
0.014
1
04/05/23 22:15
04/07/23 13:57
11096-82-5
Surrogates
Decachlorobiphenyl (S)
129
%
10-193
1
04/05/23 22:15
04/07/23 13:57
2051-24-3
Date: 05/05/2023 12:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 49 of 155

lceAnalyircal
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-6 Lab ID: 92659555009 Collected: 03/28/23 14:32 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
Metals (ICP) 6010D
Analytical Method: EPA 6010D Preparation Method: 3015
Pace National - Mt. Juliet
Antimony
ND
ug/L
10.0
4.30
1
04/02/2312:18
04/03/2312:59
7440-36-0
Arsenic
ND
ug/L
10.0
4.40
1
04/02/2312:18
04/03/2312:59
7440-38-2
Barium
1.96J
ug/L
5.00
0.736
1
04/02/2312:18
04/03/2312:59
7440-39-3
Beryllium
ND
ug/L
2.00
0.330
1
04/02/2312:18
04/03/2312:59
7440-41-7
Cadmium
ND
ug/L
2.00
0.479
1
04/02/2312:18
04/03/2312:59
7440-43-9
Chromium
ND
ug/L
10.0
1.40
1
04/02/2312:18
04/03/2312:59
7440-47-3
Cobalt
ND
ug/L
10.0
0.840
1
04/02/2312:18
04/03/2312:59
7440-48-4
Copper
ND
ug/L
10.0
3.68
1
04/02/2312:18
04/03/2312:59
7440-50-8
Lead
ND
ug/L
6.00
2.99
1
04/02/2312:18
04/03/2312:59
7439-92-1
Nickel
1.71J
ug/L
10.0
1.61
1
04/02/2312:18
04/03/2312:59
7440-02-0
Selenium
ND
ug/L
10.0
7.35
1
04/02/2312:18
04/03/2312:59
7782-49-2
Silver
ND
ug/L
5.00
1.54
1
04/02/2312:18
04/03/2312:59
7440-22-4
Tin
ND
ug/L
50.0
4.87
1
04/02/2312:18
04/03/2312:59
7440-31-5
Vanadium
ND
ug/L
20.0
4.99
1
04/02/2312:18
04/03/2312:59
7440-62-2
Zinc
ND
ug/L
50.0
6.52
1
04/02/2312:18
04/03/2312:59
7440-66-6
Metals (ICPMS) 6020B
Analytical Method: EPA 6020E Preparation Method: 3015
Pace National - Mt. Juliet
Thallium
ND
ug/L
2.00
0.121
1
04/03/2317:07
04/04/2319:35
7440-28-0
Mercury 7470A
Mercury
8270E APP9 RV
Acenaphthene
Acenaphthylene
Acetophenone
2-Acetylaminofluorene
4-Aminobiphenyl
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Benzyl alcohol
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-ChIoro-3-methyl phenol
4-Chloroaniline
Chlorobenzilate
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
Date: 05/05/2023 12:39 PM
Analytical Method: EPA 7470A Preparation Method: 7470A
Pace National - Mt. Juliet
ND ug/L 0.200 0.100 1 04/05/2315:29 04/07/2312:18 7439-97-6
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
ND
ug/L
10.0
2.0
1
04/01/2312:01
04/02/23 17:24
83-32-9
ND
ug/L
10.0
2.0
1
04/01/2312:01
04/02/23 17:24
208-96-8
ND
ug/L
10.0
1.5
1
04/01/2312:01
04/02/23 17:24
98-86-2
ND
ug/L
10.0
4.1
1
04/01/2312:01
04/02/23 17:24
53-96-3
ND
ug/L
10.0
4.7
1
04/01/2312:01
04/02/23 17:24
92-67-1
ND
ug/L
10.0
2.3
1
04/01/2312:01
04/02/23 17:24
120-12-7
ND
ug/L
10.0
2.7
1
04/01/2312:01
04/02/23 17:24
56-55-3
ND
ug/L
10.0
2.8
1
04/01/2312:01
04/02/23 17:24
50-32-8
ND
ug/L
10.0
2.6
1
04/01/2312:01
04/02/23 17:24
205-99-2
ND
ug/L
10.0
2.8
1
04/01 /23 12:01
04/02/23 17:24
191-24-2
ND
ug/L
10.0
2.7
1
04/01/2312:01
04/02/23 17:24
207-08-9
ND
ug/L
20.0
2.9
1
04/01 /23 12:01
04/02/23 17:24
100-51-6
ND
ug/L
10.0
1.8
1
04/01 /23 12:01
04/02/23 17:24
101-55-3
ND
ug/L
10.0
3.1
1
04/01/2312:01
04/02/23 17:24
85-68-7
ND
ug/L
10.0
3.3
1
04/01/2312:01
04/02/23 17:24
59-50-7
ND
ug/L
20.0
3.6
1
04/01/2312:01
04/02/23 17:24
106-47-8
ND
ug/L
10.0
3.8
1
04/01/2312:01
04/02/23 17:24
510-15-6
ND
ug/L
10.0
1.8
1
04/01 /23 12:01
04/02/23 17:24
111-91-1
ND
ug/L
10.0
1.9
1
04/01 /23 12:01
04/02/23 17:24
111-44-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
J
B,J
Page 50 of 155

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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-6 Lab ID: 92659555009 Collected: 03/28/23 14:32 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
2-Chloronaphthalene
ND
ug/L
10.0
1.7
1
04/01/23 12:01
04/02/23 17:24
91-58-7
2-Chlorophenol
ND
ug/L
10.0
1.2
1
04/01/23 12:01
04/02/23 17:24
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
10.0
2.0
1
04/01/23 12:01
04/02/23 17:24
7005-72-3
Chrysene
ND
ug/L
10.0
2.8
1
04/01/23 12:01
04/02/23 17:24
218-01-9
Diallate
ND
ug/L
10.0
3.4
1
04/01/23 12:01
04/02/23 17:24
2303-16-4
Dibenz(a,h)anthracene
ND
ug/L
10.0
3.0
1
04/01/23 12:01
04/02/23 17:24
53-70-3
Dibenzofuran
ND
ug/L
10.0
2.1
1
04/01/23 12:01
04/02/23 17:24
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
20.0
8.1
1
04/01/23 12:01
04/02/23 17:24
91-94-1
2,4-Dichlorophenol
ND
ug/L
10.0
1.4
1
04/01/23 12:01
04/02/23 17:24
120-83-2
2,6-Dichlorophenol
ND
ug/L
10.0
4.2
1
04/01/23 12:01
04/02/23 17:24
87-65-0
Diethylphthalate
ND
ug/L
10.0
2.0
1
04/01/23 12:01
04/02/23 17:24
84-66-2
Dimethoate
ND
ug/L
10.0
3.7
1
04/01/23 12:01
04/02/23 17:24
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
5.0
2.4
1
04/01/23 12:01
04/02/23 17:24
60-11-7
7,12-Dimethylbenz(a)anthracene
ND
ug/L
10.0
3.0
1
04/01/23 12:01
04/02/23 17:24
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
50.0
31.1
1
04/01/23 12:01
04/02/23 17:24
119-93-7
2,4-Dimethylphenol
ND
ug/L
10.0
1.7
1
04/01/23 12:01
04/02/23 17:24
105-67-9
a,a-Dimethylphenylethylamine
ND
ug/L
100
62.0
1
04/01/23 12:01
04/02/23 17:24
122-09-8
Dimethylphthalate
ND
ug/L
10.0
2.1
1
04/01/23 12:01
04/02/23 17:24
131-11-3
Di-n-butylphthalate
ND
ug/L
10.0
2.2
1
04/01/23 12:01
04/02/23 17:24
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
20.0
7.8
1
04/01/23 12:01
04/02/23 17:24
534-52-1
1,3-Dinitrobenzene
ND
ug/L
10.0
3.8
1
04/01/23 12:01
04/02/23 17:24
99-65-0
2,4-Dinitrophenol
ND
ug/L
50.0
26.0
1
04/01/23 12:01
04/02/23 17:24
51-28-5
2,4-Dinitrotoluene
ND
ug/L
10.0
1.6
1
04/01/23 12:01
04/02/23 17:24
121-14-2
2,6-Dinitrotoluene
ND
ug/L
10.0
1.7
1
04/01/23 12:01
04/02/23 17:24
606-20-2
Di-n-octylphthalate
ND
ug/L
10.0
3.9
1
04/01/23 12:01
04/02/23 17:24
117-84-0
Diphenylamine
ND
ug/L
10.0
3.0
1
04/01/23 12:01
04/02/23 17:24
122-39-4
Disulfoton
ND
ug/L
10.0
4.6
1
04/01/23 12:01
04/02/23 17:24
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
6.0
3.7
1
04/01/23 12:01
04/02/23 17:24
117-81-7
Ethyl methanesulfonate
ND
ug/L
20.0
3.0
1
04/01/23 12:01
04/02/23 17:24
62-50-0
Famphur
ND
ug/L
10.0
6.1
1
04/01/23 12:01
04/02/23 17:24
52-85-7
Fluoranthene
ND
ug/L
10.0
2.2
1
04/01/23 12:01
04/02/23 17:24
206-44-0
Fluorene
ND
ug/L
10.0
2.1
1
04/01/23 12:01
04/02/23 17:24
86-73-7
Hexachlorobenzene
ND
ug/L
10.0
2.2
1
04/01/23 12:01
04/02/23 17:24
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
10.0
1.6
1
04/01/23 12:01
04/02/23 17:24
77-47-4
Hexachloroethane
ND
ug/L
10.0
1.4
1
04/01/23 12:01
04/02/23 17:24
67-72-1
Hexachloropropene
ND
ug/L
10.0
2.7
1
04/01/23 12:01
04/02/23 17:24
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
10.0
2.9
1
04/01/23 12:01
04/02/23 17:24
193-39-5
Isodrin
ND
ug/L
10.0
2.8
1
04/01/23 12:01
04/02/23 17:24
465-73-6
Isophorone
ND
ug/L
10.0
1.7
1
04/01/23 12:01
04/02/23 17:24
78-59-1
Isosafrole
ND
ug/L
10.0
2.5
1
04/01/23 12:01
04/02/23 17:24
120-58-1
Kepone
ND
ug/L
20.0
14.1
1
04/01/23 12:01
04/02/23 17:24
143-50-0
Methapyrilene
ND
ug/L
50.0
17.0
1
04/01/23 12:01
04/02/23 17:24
91-80-5
3-Methylcholanthrene
ND
ug/L
10.0
3.7
1
04/01/23 12:01
04/02/23 17:24
56-49-5
Methyl methanesulfonate
ND
ug/L
5.0
3.1
1
04/01/23 12:01
04/02/23 17:24
66-27-3
2-Methylnaphthalene
ND
ug/L
10.0
1.9
1
04/01/23 12:01
04/02/23 17:24
91-57-6
REPORT OF LABORATORY ANALYSIS
IL
L1
IH
L1
v2
IH,v1
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 51 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-6 Lab ID: 92659555009 Collected: 03/28/23 14:32 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Methyl parathion
ND
ug/L
10.0
3.7
1
04/01/23 12:01
04/02/23 17:24
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
10.0
1.9
1
04/01/23 12:01
04/02/23 17:24
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
10.0
1.2
1
04/01/23 12:01
04/02/23 17:24
15831-10-4
1-Naphthalenamine
ND
ug/L
10.0
6.0
1
04/01/23 12:01
04/02/23 17:24
134-32-7
2-Naphthalenamine
ND
ug/L
10.0
5.4
1
04/01/23 12:01
04/02/23 17:24
91-59-8
1,4-Naphthoquinone
ND
ug/L
5.0
4.4
1
04/01/23 12:01
04/02/23 17:24
130-15-4
2-Nitroaniline
ND
ug/L
20.0
3.0
1
04/01/23 12:01
04/02/23 17:24
88-74-4
3-Nitroaniline
ND
ug/L
20.0
3.8
1
04/01/23 12:01
04/02/23 17:24
99-09-2
4-Nitroaniline
ND
ug/L
20.0
5.1
1
04/01/23 12:01
04/02/23 17:24
100-01-6
Nitrobenzene
ND
ug/L
10.0
1.9
1
04/01/23 12:01
04/02/23 17:24
98-95-3
2-Nitrophenol
ND
ug/L
10.0
1.4
1
04/01/23 12:01
04/02/23 17:24
88-75-5
4-Nitrophenol
ND
ug/L
50.0
6.6
1
04/01/23 12:01
04/02/23 17:24
100-02-7
5-Nitro-o-toluidine
ND
ug/L
10.0
3.8
1
04/01/23 12:01
04/02/23 17:24
99-55-8
N-Nitrosodiethylamine
ND
ug/L
10.0
2.3
1
04/01/23 12:01
04/02/23 17:24
55-18-5
N-Nitrosodimethylamine
ND
ug/L
10.0
1.9
1
04/01/23 12:01
04/02/23 17:24
62-75-9
N-Nitroso-di-n-butylamine
ND
ug/L
10.0
2.0
1
04/01/23 12:01
04/02/23 17:24
924-16-3
N-Nitroso-di-n-propylamine
ND
ug/L
10.0
1.3
1
04/01/23 12:01
04/02/23 17:24
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
10.0
3.0
1
04/01/23 12:01
04/02/23 17:24
86-30-6
N-Nitrosomethylethylamine
ND
ug/L
10.0
7.5
1
04/01/23 12:01
04/02/23 17:24
10595-95-6
N-Nitrosopiperidine
ND
ug/L
10.0
2.5
1
04/01/23 12:01
04/02/23 17:24
100-75-4
N-Nitrosopyrrolidine
ND
ug/L
10.0
3.1
1
04/01/23 12:01
04/02/23 17:24
930-55-2
O,O,O-Triethylphosphorothioate
ND
ug/L
10.0
2.6
1
04/01/23 12:01
04/02/23 17:24
126-68-1
2,2'-Oxybis(1-chloropropane)
ND
ug/L
10.0
1.2
1
04/01/23 12:01
04/02/23 17:24
108-60-1
Parathion (Ethyl parathion)
ND
ug/L
10.0
3.9
1
04/01/23 12:01
04/02/23 17:24
56-38-2
Pentachlorobenzene
ND
ug/L
10.0
3.4
1
04/01/23 12:01
04/02/23 17:24
608-93-5
Pentachloronitrobenzene
ND
ug/L
10.0
3.3
1
04/01/23 12:01
04/02/23 17:24
82-68-8
Pentachlorophenol
ND
ug/L
20.0
3.8
1
04/01/23 12:01
04/02/23 17:24
87-86-5
Phenacetin
ND
ug/L
10.0
3.6
1
04/01/23 12:01
04/02/23 17:24
62-44-2
Phenanthrene
ND
ug/L
10.0
2.0
1
04/01/23 12:01
04/02/23 17:24
85-01-8
Phenol
ND
ug/L
10.0
1.4
1
04/01/23 12:01
04/02/23 17:24
108-95-2
p-Phenylenediamine
ND
ug/L
10.0
10.0
1
04/01/23 12:01
04/02/23 17:24
106-50-3
Phorate
ND
ug/L
10.0
3.6
1
04/01/23 12:01
04/02/23 17:24
298-02-2
Pronamide
ND
ug/L
10.0
3.1
1
04/01/23 12:01
04/02/23 17:24
23950-58-5
Pyrene
ND
ug/L
10.0
2.2
1
04/01/23 12:01
04/02/23 17:24
129-00-0
Safrole
ND
ug/L
10.0
2.3
1
04/01/23 12:01
04/02/23 17:24
94-59-7
1,2,4,5-Tetrachlorobenzene
ND
ug/L
10.0
4.5
1
04/01/23 12:01
04/02/23 17:24
95-94-3
2,3,4,6-Tetrachlorophenol
ND
ug/L
10.0
1.5
1
04/01/23 12:01
04/02/23 17:24
58-90-2
Thionazin
ND
ug/L
10.0
2.9
1
04/01/23 12:01
04/02/23 17:24
297-97-2
O-Toluidine
ND
ug/L
10.0
2.6
1
04/01/23 12:01
04/02/23 17:24
95-53-4
2,4,5-Trichlorophenol
ND
ug/L
10.0
1.4
1
04/01/23 12:01
04/02/23 17:24
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
10.0
1.6
1
04/01/23 12:01
04/02/23 17:24
88-06-2
1,3,5-Trinitrobenzene
ND
ug/L
10.0
5.5
1
04/01/23 12:01
04/02/23 17:24
99-35-4
Surrogates
Nitrobenzene-d5 (S)
90
%
10-138
1
04/01/23 12:01
04/02/23 17:24
4165-60-0
2-Fluorobiphenyl (S)
81
%
10-130
1
04/01/23 12:01
04/02/23 17:24
321-60-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 52 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-6 Lab ID: 92659555009 Collected: 03/28/23 14:32 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Surrogates
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV Low Level -Acrolein
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Allyl chloride
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Chloroprene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
Date: 05/05/2023 12:39 PM
105
%
19-191
1
04/01 /23 12:01
04/02/23 17:24
1718-51-0
51
%
10-130
1
04/01 /23 12:01
04/02/23 17:24
13127-88-3
63
%
10-130
1
04/01/2312:01
04/02/23 17:24
367-12-4
108
%
10-164
1
04/01 /23 12:01
04/02/23 17:24
118-79-6
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
ND ug/L 2.0
93
%
67-130
94
%
70-130
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
ND
ug/L
50.0
ND
ug/L
10.0
ND
ug/L
10.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
0.86 1
I
03/31/23 23:48 123-91-1
03/31/23 23:48 17060-07-0
03/31/23 23:48 2037-26-5
5.1
1
03/31/23 02:55
67-64-1
24.8
1
03/31/23 02:55
75-05-8
8.5
1
03/31/23 02:55
107-02-8
1.8
1
03/31/23 02:55
107-13-1
0.50
1
03/31/23 02:55
107-05-1
0.34
1
03/31/23 02:55
71-43-2
0.47
1
03/31/23 02:55
74-97-5
0.31
1
03/31/23 02:55
75-27-4
0.34
1
03/31/23 02:55
75-25-2
1.7
1
03/31/23 02:55
74-83-9
4.0
1
03/31/23 02:55
78-93-3
0.36
1
03/31/23 02:55
75-15-0
0.33
1
03/31/23 02:55
56-23-5
0.28
1
03/31/23 02:55
108-90-7
0.65
1
03/31/23 02:55
75-00-3
0.43
1
03/31/23 02:55
67-66-3
0.54
1
03/31/23 02:55
74-87-3
1.6
1
03/31/23 02:55
126-99-8
0.34
1
03/31/23 02:55
96-12-8
0.36
1
03/31/23 02:55
124-48-1
0.27
1
03/31/23 02:55
106-93-4
0.39
1
03/31/23 02:55
74-95-3
0.34
1
03/31/23 02:55
95-50-1
0.34
1
03/31/23 02:55
541-73-1
0.33
1
03/31/23 02:55
106-46-7
0.56
1
03/31/23 02:55
110-57-6
0.35
1
03/31/23 02:55
75-71-8
0.37
1
03/31/23 02:55
75-34-3
0.32
1
03/31/23 02:55
107-06-2
0.35
1
03/31/23 02:55
75-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v1
v1
Page 53 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-6 Lab ID: 92659555009 Collected: 03/28/23 14:32 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level -Acrolein
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Ethyl methacrylate
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
4-Methyl-2-pentanone (MIBK)
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
Date: 05/05/2023 12:39 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.38
1
03/31/23 02:55
156-59-2
ND
ug/L
1.0
0.40
1
03/31/23 02:55
156-60-5
ND
ug/L
1.0
0.36
1
03/31/23 02:55
78-87-5
ND
ug/L
1.0
0.28
1
03/31/23 02:55
142-28-9
ND
ug/L
1.0
0.39
1
03/31/23 02:55
594-20-7
ND
ug/L
1.0
0.43
1
03/31/23 02:55
563-58-6
ND
ug/L
1.0
0.36
1
03/31/23 02:55
10061-01-5
ND
ug/L
1.0
0.36
1
03/31/23 02:55
10061-02-6
ND
ug/L
1.0
0.30
1
03/31/23 02:55
100-41-4
ND
ug/L
1.0
0.28
1
03/31/23 02:55
97-63-2
ND
ug/L
2.0
1.5
1
03/31/23 02:55
87-68-3
ND
ug/L
5.0
0.48
1
03/31/23 02:55
591-78-6
ND
ug/L
20.0
9.7
1
03/31/23 02:55
74-88-4
ND
ug/L
100
52.3
1
03/31/23 02:55
78-83-1
ND
ug/L
10.0
4.2
1
03/31/23 02:55
126-98-7
ND
ug/L
5.0
2.0
1
03/31/23 02:55
75-09-2
ND
ug/L
2.0
0.32
1
03/31/23 02:55
80-62-6
ND
ug/L
5.0
2.7
1
03/31/23 02:55
108-10-1
ND
ug/L
1.0
0.64
1
03/31/23 02:55
91-20-3
ND
ug/L
20.0
3.6
1
03/31/23 02:55
107-12-0
ND
ug/L
1.0
0.29
1
03/31/23 02:55
100-42-5
ND
ug/L
1.0
0.31
1
03/31/23 02:55
630-20-6
ND
ug/L
1.0
0.22
1
03/31/23 02:55
79-34-5
ND
ug/L
1.0
0.29
1
03/31/23 02:55
127-18-4
ND
ug/L
1.0
0.24
1
03/31/23 02:55
108-88-3
ND
ug/L
1.0
0.64
1
03/31/23 02:55
120-82-1
ND
ug/L
1.0
0.33
1
03/31/23 02:55
71-55-6
ND
ug/L
1.0
0.32
1
03/31/23 02:55
79-00-5
ND
ug/L
1.0
0.38
1
03/31/23 02:55
79-01-6
ND
ug/L
1.0
0.30
1
03/31/23 02:55
75-69-4
ND
ug/L
1.0
0.26
1
03/31/23 02:55
96-18-4
ND
ug/L
2.0
1.3
1
03/31/23 02:55
108-05-4
ND
ug/L
1.0
0.39
1
03/31/23 02:55
75-01-4
ND
ug/L
1.0
0.34
1
03/31/23 02:55
1330-20-7
109
%
70-130
1
03/31/23 02:55
460-00-4
109
%
70-130
1
03/31/23 02:55
17060-07-0
111
%
70-130
1
03/31/23 02:55
2037-26-5
v1
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND ug/L 100 22.0 1 03/31/23 02:51 18496-25-8
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 54 of 155

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ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: MW-6 Lab ID: 92659555009 Collected: 03/28/23 14:32 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
4500CNE Cyanide, Total Analytical Method: SM 4500-CN-E-2016 Preparation Method: SM 4500-CN-E-2016
Pace Analytical Services -Asheville
Cyanide ND ug/L 8.0 6.0 1 04/03/23 18:41 04/03/23 22:02 57-12-5
Date: 05/05/2023 12:39 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: FIELD BLANK
Lab ID:
92659555010
Collected:
03/28/23 15:55
Received: 03/29/23 10:30 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
Chlorinated Herb. (GC) 8151A
Analytical
Method: EPA 8151A
Preparation Method: 8151A
Pace National
- Mt. Juliet
2,4-D
ND
ug/L
2.00
0.547
1
04/04/23 14:45
04/06/23 11:49
94-75-7 R1
Dinoseb
ND
ug/L
2.00
0.250
1
04/04/23 14:45
04/06/23 11:49
88-85-7
2,4,5-T
ND
ug/L
2.00
0.258
1
04/04/23 14:45
04/06/23 11:49
93-76-5 R1
2,4,5-TP (Silvex)
ND
ug/L
2.00
0.335
1
04/04/23 14:45
04/06/23 11:49
93-72-1 R1
Surrogates
2,4-DCAA (S)
56.2
%
14.0-158
1
04/04/23 14:45
04/06/23 11:49
19719-28-9
8081 OC Pesticides RVE
Analytical
Method: EPA 8081
B Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
Aldrin
ND
ug/L
0.042
0.012
1
04/04/23 10:24
04/05/23 13:40
309-00-2
alpha-BHC
ND
ug/L
0.042
0.010
1
04/04/23 10:24
04/05/23 13:40
319-84-6
beta-BHC
ND
ug/L
0.042
0.041
1
04/04/23 10:24
04/05/23 13:40
319-85-7
delta-BHC
ND
ug/L
0.042
0.012
1
04/04/23 10:24
04/05/23 13:40
319-86-8
gamma-BHC (Lindane)
ND
ug/L
0.042
0.010
1
04/04/23 10:24
04/05/23 13:40
58-89-9
Chlordane (Technical)
ND
ug/L
0.42
0.13
1
04/04/23 10:24
04/05/23 13:40
57-74-9
4,4'-DDD
ND
ug/L
0.042
0.014
1
04/04/23 10:24
04/05/23 13:40
72-54-8
4,4'-DDE
ND
ug/L
0.042
0.020
1
04/04/23 10:24
04/05/23 13:40
72-55-9
4,4'-DDT
ND
ug/L
0.042
0.022
1
04/04/23 10:24
04/05/23 13:40
50-29-3
Dieldrin
ND
ug/L
0.042
0.012
1
04/04/23 10:24
04/05/23 13:40
60-57-1
Endosulfan I
ND
ug/L
0.042
0.014
1
04/04/23 10:24
04/05/23 13:40
959-98-8
Endosulfan 11
ND
ug/L
0.042
0.013
1
04/04/23 10:24
04/05/23 13:40
33213-65-9
Endosulfan sulfate
ND
ug/L
0.042
0.012
1
04/04/23 10:24
04/05/23 13:40
1031-07-8
Endrin
ND
ug/L
0.042
0.015
1
04/04/23 10:24
04/05/23 13:40
72-20-8
Endrin aldehyde
ND
ug/L
0.042
0.014
1
04/04/23 10:24
04/05/23 13:40
7421-93-4
Heptachlor
ND
ug/L
0.042
0.016
1
04/04/23 10:24
04/05/23 13:40
76-44-8
Heptachlor epoxide
ND
ug/L
0.042
0.024
1
04/04/23 10:24
04/05/23 13:40
1024-57-3
Methoxychlor
ND
ug/L
0.12
0.035
1
04/04/23 10:24
04/05/23 13:40
72-43-5
Toxaphene
ND
ug/L
0.42
0.18
1
04/04/23 10:24
04/05/23 13:40
8001-35-2
Surrogates
Tetrachloro-m-xylene (S)
91
%
10-182
1
04/04/23 10:24
04/05/23 13:40
877-09-8
Decachlorobiphenyl (S)
122
%
10-200
1
04/04/23 10:24
04/05/23 13:40
2051-24-3
8082 GCS PCB RVE
Analytical
Method: EPA 8082A
Preparation Method:
EPA 3510C
Pace Analytical
Services
- Charlotte
PCB-1016 (Aroclor 1016)
ND
ug/L
0.42
0.18
1
04/05/23 22:15
04/07/23 14:09
12674-11-2
PCB-1221 (Aroclor 1221)
ND
ug/L
0.42
0.19
1
04/05/23 22:15
04/07/23 14:09
11104-28-2
PCB-1232 (Aroclor 1232)
ND
ug/L
0.42
0.19
1
04/05/23 22:15
04/07/23 14:09
11141-16-5
PCB-1242 (Aroclor 1242)
ND
ug/L
0.42
0.21
1
04/05/23 22:15
04/07/23 14:09
53469-21-9
PCB-1248 (Aroclor 1248)
ND
ug/L
0.42
0.24
1
04/05/23 22:15
04/07/23 14:09
12672-29-6
PCB-1254 (Aroclor 1254)
ND
ug/L
0.42
0.18
1
04/05/23 22:15
04/07/23 14:09
11097-69-1
PCB-1260 (Aroclor 1260)
ND
ug/L
0.42
0.13
1
04/05/23 22:15
04/07/23 14:09
11096-82-5
Surrogates
Decachlorobiphenyl (S)
99
%
10-193
1
04/05/23 22:15
04/07/23 14:09
2051-24-3
Date: 05/05/2023 12:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: FIELD BLANK Lab ID: 92659555010 Collected: 03/28/23 15:55 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
Metals (ICP) 6010D
Analytical Method: EPA 6010D Preparation Method: 3015
Pace National - Mt. Juliet
Antimony
ND
ug/L
10.0
4.30
1
04/02/2312:18
04/03/2313:02
7440-36-0
Arsenic
ND
ug/L
10.0
4.40
1
04/02/2312:18
04/03/2313:02
7440-38-2
Barium
ND
ug/L
5.00
0.736
1
04/02/2312:18
04/03/2313:02
7440-39-3
Beryllium
ND
ug/L
2.00
0.330
1
04/02/2312:18
04/03/2313:02
7440-41-7
Cadmium
ND
ug/L
2.00
0.479
1
04/02/2312:18
04/03/2313:02
7440-43-9
Chromium
ND
ug/L
10.0
1.40
1
04/02/2312:18
04/03/2313:02
7440-47-3
Cobalt
ND
ug/L
10.0
0.840
1
04/02/2312:18
04/03/2313:02
7440-48-4
Copper
ND
ug/L
10.0
3.68
1
04/02/2312:18
04/03/2313:02
7440-50-8
Lead
ND
ug/L
6.00
2.99
1
04/02/2312:18
04/03/2313:02
7439-92-1
Nickel
ND
ug/L
10.0
1.61
1
04/02/2312:18
04/03/2313:02
7440-02-0
Selenium
ND
ug/L
10.0
7.35
1
04/02/2312:18
04/03/2313:02
7782-49-2
Silver
ND
ug/L
5.00
1.54
1
04/02/2312:18
04/03/2313:02
7440-22-4
Tin
ND
ug/L
50.0
4.87
1
04/02/2312:18
04/03/2313:02
7440-31-5
Vanadium
ND
ug/L
20.0
4.99
1
04/02/2312:18
04/03/2313:02
7440-62-2
Zinc
ND
ug/L
50.0
6.52
1
04/02/2312:18
04/03/2313:02
7440-66-6
Metals (ICPMS) 6020B
Analytical Method: EPA 6020E Preparation Method: 3015
Pace National - Mt. Juliet
Thallium
ND
ug/L
2.00
0.121
1
04/03/2317:07
04/04/2319:38
7440-28-0
Mercury 7470A
Mercury
8270E APP9 RV
Acenaphthene
Acenaphthylene
Acetophenone
2-Acetylaminofluorene
4-Aminobiphenyl
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Benzyl alcohol
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-ChIoro-3-methyl phenol
4-Chloroaniline
Chlorobenzilate
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
Date: 05/05/2023 12:39 PM
Analytical Method: EPA 7470A Preparation Method: 7470A
Pace National - Mt. Juliet
ND ug/L 0.200 0.100 1 04/05/2315:29 04/07/2312:20 7439-97-6
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
ND
ug/L
8.3
1.7
1
04/01/2312:01
04/02/23 17:49
83-32-9
ND
ug/L
8.3
1.6
1
04/01/2312:01
04/02/23 17:49
208-96-8
ND
ug/L
8.3
1.2
1
04/01/2312:01
04/02/23 17:49
98-86-2
ND
ug/L
8.3
3.4
1
04/01/2312:01
04/02/23 17:49
53-96-3
ND
ug/L
8.3
4.0
1
04/01/2312:01
04/02/23 17:49
92-67-1
ND
ug/L
8.3
1.9
1
04/01/2312:01
04/02/23 17:49
120-12-7
ND
ug/L
8.3
2.2
1
04/01/2312:01
04/02/23 17:49
56-55-3
ND
ug/L
8.3
2.3
1
04/01/2312:01
04/02/23 17:49
50-32-8
ND
ug/L
8.3
2.2
1
04/01/2312:01
04/02/23 17:49
205-99-2
ND
ug/L
8.3
2.4
1
04/01 /23 12:01
04/02/23 17:49
191-24-2
ND
ug/L
8.3
2.3
1
04/01/2312:01
04/02/23 17:49
207-08-9
ND
ug/L
16.7
2.4
1
04/01 /23 12:01
04/02/23 17:49
100-51-6
ND
ug/L
8.3
1.5
1
04/01 /23 12:01
04/02/23 17:49
101-55-3
ND
ug/L
8.3
2.6
1
04/01/2312:01
04/02/23 17:49
85-68-7
ND
ug/L
8.3
2.8
1
04/01/2312:01
04/02/23 17:49
59-50-7
ND
ug/L
16.7
3.0
1
04/01/2312:01
04/02/23 17:49
106-47-8
ND
ug/L
8.3
3.2
1
04/01/2312:01
04/02/23 17:49
510-15-6
ND
ug/L
8.3
1.5
1
04/01 /23 12:01
04/02/23 17:49
111-91-1
ND
ug/L
8.3
1.6
1
04/01 /23 12:01
04/02/23 17:49
111-44-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 57 of 155

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9800 Kincey Ave. Suite 100
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[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: FIELD BLANK Lab ID: 92659555010 Collected: 03/28/23 15:55 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
2-Chloronaphthalene
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 17:49
91-58-7
2-Chlorophenol
ND
ug/L
8.3
1.0
1
04/01/23 12:01
04/02/23 17:49
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 17:49
7005-72-3
Chrysene
ND
ug/L
8.3
2.3
1
04/01/23 12:01
04/02/23 17:49
218-01-9
Diallate
ND
ug/L
8.3
2.8
1
04/01/23 12:01
04/02/23 17:49
2303-16-4
Dibenz(a,h)anthracene
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 17:49
53-70-3
Dibenzofuran
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 17:49
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
16.7
6.8
1
04/01/23 12:01
04/02/23 17:49
91-94-1
2,4-Dichlorophenol
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 17:49
120-83-2
2,6-Dichlorophenol
ND
ug/L
8.3
3.5
1
04/01/23 12:01
04/02/23 17:49
87-65-0
Diethylphthalate
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 17:49
84-66-2
Dimethoate
ND
ug/L
8.3
3.0
1
04/01/23 12:01
04/02/23 17:49
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
4.2
2.0
1
04/01/23 12:01
04/02/23 17:49
60-11-7
7,12-Dimethylbenz(a)anthracene
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 17:49
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
41.7
25.9
1
04/01/23 12:01
04/02/23 17:49
119-93-7
2,4-Dimethylphenol
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 17:49
105-67-9
a,a-Dimethylphenylethylamine
ND
ug/L
83.3
51.7
1
04/01/23 12:01
04/02/23 17:49
122-09-8
Dimethylphthalate
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 17:49
131-11-3
Di-n-butylphthalate
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 17:49
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
16.7
6.5
1
04/01/23 12:01
04/02/23 17:49
534-52-1
1,3-Dinitrobenzene
ND
ug/L
8.3
3.1
1
04/01/23 12:01
04/02/23 17:49
99-65-0
2,4-Dinitrophenol
ND
ug/L
41.7
21.7
1
04/01/23 12:01
04/02/23 17:49
51-28-5
2,4-Dinitrotoluene
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 17:49
121-14-2
2,6-Dinitrotoluene
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 17:49
606-20-2
Di-n-octylphthalate
ND
ug/L
8.3
3.3
1
04/01/23 12:01
04/02/23 17:49
117-84-0
Diphenylamine
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 17:49
122-39-4
Disulfoton
ND
ug/L
8.3
3.9
1
04/01/23 12:01
04/02/23 17:49
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
5.0
3.1
1
04/01/23 12:01
04/02/23 17:49
117-81-7
Ethyl methanesulfonate
ND
ug/L
16.7
2.5
1
04/01/23 12:01
04/02/23 17:49
62-50-0
Famphur
ND
ug/L
8.3
5.1
1
04/01/23 12:01
04/02/23 17:49
52-85-7
Fluoranthene
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 17:49
206-44-0
Fluorene
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 17:49
86-73-7
Hexachlorobenzene
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 17:49
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
8.3
1.3
1
04/01/23 12:01
04/02/23 17:49
77-47-4
Hexachloroethane
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 17:49
67-72-1
Hexachloropropene
ND
ug/L
8.3
2.2
1
04/01/23 12:01
04/02/23 17:49
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
8.3
2.4
1
04/01/23 12:01
04/02/23 17:49
193-39-5
Isodrin
ND
ug/L
8.3
2.3
1
04/01/23 12:01
04/02/23 17:49
465-73-6
Isophorone
ND
ug/L
8.3
1.4
1
04/01/23 12:01
04/02/23 17:49
78-59-1
Isosafrole
ND
ug/L
8.3
2.1
1
04/01/23 12:01
04/02/23 17:49
120-58-1
Kepone
ND
ug/L
16.7
11.8
1
04/01/23 12:01
04/02/23 17:49
143-50-0
Methapyrilene
ND
ug/L
41.7
14.2
1
04/01/23 12:01
04/02/23 17:49
91-80-5
3-Methylcholanthrene
ND
ug/L
8.3
3.1
1
04/01/23 12:01
04/02/23 17:49
56-49-5
Methyl methanesulfonate
ND
ug/L
4.2
2.6
1
04/01/23 12:01
04/02/23 17:49
66-27-3
2-Methylnaphthalene
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 17:49
91-57-6
REPORT OF LABORATORY ANALYSIS
IL
L1
IH
L1
v2
IH,v1
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 58 of 155

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ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: FIELD BLANK Lab ID: 92659555010 Collected: 03/28/23 15:55 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Methyl parathion
ND
ug/L
8.3
3.1
1
04/01/23 12:01
04/02/23 17:49
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 17:49
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
8.3
1.0
1
04/01/23 12:01
04/02/23 17:49
15831-10-4
1-Naphthalenamine
ND
ug/L
8.3
5.0
1
04/01/23 12:01
04/02/23 17:49
134-32-7
2-Naphthalenamine
ND
ug/L
8.3
4.5
1
04/01/23 12:01
04/02/23 17:49
91-59-8
1,4-Naphthoquinone
ND
ug/L
4.2
3.7
1
04/01/23 12:01
04/02/23 17:49
130-15-4
2-Nitroaniline
ND
ug/L
16.7
2.5
1
04/01/23 12:01
04/02/23 17:49
88-74-4
3-Nitroaniline
ND
ug/L
16.7
3.1
1
04/01/23 12:01
04/02/23 17:49
99-09-2
4-Nitroaniline
ND
ug/L
16.7
4.2
1
04/01/23 12:01
04/02/23 17:49
100-01-6
Nitrobenzene
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 17:49
98-95-3
2-Nitrophenol
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 17:49
88-75-5
4-Nitrophenol
ND
ug/L
41.7
5.5
1
04/01/23 12:01
04/02/23 17:49
100-02-7
5-Nitro-o-toluidine
ND
ug/L
8.3
3.2
1
04/01/23 12:01
04/02/23 17:49
99-55-8
N-Nitrosodiethylamine
ND
ug/L
8.3
1.9
1
04/01/23 12:01
04/02/23 17:49
55-18-5
N-Nitrosodimethylamine
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 17:49
62-75-9
N-Nitroso-di-n-butylamine
ND
ug/L
8.3
1.6
1
04/01/23 12:01
04/02/23 17:49
924-16-3
N-Nitroso-di-n-propylamine
ND
ug/L
8.3
1.1
1
04/01/23 12:01
04/02/23 17:49
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
8.3
2.5
1
04/01/23 12:01
04/02/23 17:49
86-30-6
N-Nitrosomethylethylamine
ND
ug/L
8.3
6.2
1
04/01/23 12:01
04/02/23 17:49
10595-95-6
N-Nitrosopiperidine
ND
ug/L
8.3
2.1
1
04/01/23 12:01
04/02/23 17:49
100-75-4
N-Nitrosopyrrolidine
ND
ug/L
8.3
2.6
1
04/01/23 12:01
04/02/23 17:49
930-55-2
O,O,O-Triethylphosphorothioate
ND
ug/L
8.3
2.1
1
04/01/23 12:01
04/02/23 17:49
126-68-1
2,2'-Oxybis(1-chloropropane)
ND
ug/L
8.3
0.96
1
04/01/23 12:01
04/02/23 17:49
108-60-1
Parathion (Ethyl parathion)
ND
ug/L
8.3
3.2
1
04/01/23 12:01
04/02/23 17:49
56-38-2
Pentachlorobenzene
ND
ug/L
8.3
2.8
1
04/01/23 12:01
04/02/23 17:49
608-93-5
Pentachloronitrobenzene
ND
ug/L
8.3
2.7
1
04/01/23 12:01
04/02/23 17:49
82-68-8
Pentachlorophenol
ND
ug/L
16.7
3.1
1
04/01/23 12:01
04/02/23 17:49
87-86-5
Phenacetin
ND
ug/L
8.3
3.0
1
04/01/23 12:01
04/02/23 17:49
62-44-2
Phenanthrene
ND
ug/L
8.3
1.7
1
04/01/23 12:01
04/02/23 17:49
85-01-8
Phenol
ND
ug/L
8.3
1.1
1
04/01/23 12:01
04/02/23 17:49
108-95-2
p-Phenylenediamine
ND
ug/L
8.3
8.3
1
04/01/23 12:01
04/02/23 17:49
106-50-3
Phorate
ND
ug/L
8.3
3.0
1
04/01/23 12:01
04/02/23 17:49
298-02-2
Pronamide
ND
ug/L
8.3
2.6
1
04/01/23 12:01
04/02/23 17:49
23950-58-5
Pyrene
ND
ug/L
8.3
1.8
1
04/01/23 12:01
04/02/23 17:49
129-00-0
Safrole
ND
ug/L
8.3
1.9
1
04/01/23 12:01
04/02/23 17:49
94-59-7
1,2,4,5-Tetrachlorobenzene
ND
ug/L
8.3
3.7
1
04/01/23 12:01
04/02/23 17:49
95-94-3
2,3,4,6-Tetrachlorophenol
ND
ug/L
8.3
1.3
1
04/01/23 12:01
04/02/23 17:49
58-90-2
Thionazin
ND
ug/L
8.3
2.4
1
04/01/23 12:01
04/02/23 17:49
297-97-2
O-Toluidine
ND
ug/L
8.3
2.2
1
04/01/23 12:01
04/02/23 17:49
95-53-4
2,4,5-Trichlorophenol
ND
ug/L
8.3
1.2
1
04/01/23 12:01
04/02/23 17:49
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
8.3
1.3
1
04/01/23 12:01
04/02/23 17:49
88-06-2
1,3,5-Trinitrobenzene
ND
ug/L
8.3
4.6
1
04/01/23 12:01
04/02/23 17:49
99-35-4
Surrogates
Nitrobenzene-d5 (S)
92
%
10-138
1
04/01/23 12:01
04/02/23 17:49
4165-60-0
2-Fluorobiphenyl (S)
83
%
10-130
1
04/01/23 12:01
04/02/23 17:49
321-60-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 59 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: FIELD BLANK
Lab ID:
92659555010
Collected:
03/28/23
15:55 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF Prepared
Analyzed
CAS No. Qual
8270E APP9 RV
Analytical
Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services
- Charlotte
Surrogates
Terphenyl-d14 (S)
106
%
19-191
1 04/01/23 12:01
04/02/23 17:49
1718-51-0
Phenol-d6 (S)
53
%
10-130
1 04/01/23 12:01
04/02/23 17:49
13127-88-3
2-Fluorophenol (S)
64
%
10-130
1 04/01/23 12:01
04/02/23 17:49
367-12-4
2,4,6-Tribromophenol (S)
108
%
10-164
1 04/01/23 12:01
04/02/23 17:49
118-79-6
8260D MSV SIM
Analytical
Method: EPA 8260D Mod.
Pace Analytical
Services
- Charlotte
1,4-Dioxane (p-Dioxane)
ND
ug/L
2.0
0.86
1
03/31/23 19:03
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
82
%
67-130
1
03/31/23 19:03
17060-07-0
Toluene-d8 (S)
91
%
70-130
1
03/31/23 19:03
2037-26-5
8260D MSV Low Level - Acrolein
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
03/31/23 01:28
67-64-1 v1
Acetonitrile
ND
ug/L
50.0
24.8
1
03/31/23 01:28
75-05-8
Acrolein
ND
ug/L
10.0
8.5
1
03/31/23 01:28
107-02-8
Acrylonitrile
ND
ug/L
10.0
1.8
1
03/31/23 01:28
107-13-1
Allyl chloride
ND
ug/L
2.0
0.50
1
03/31/23 01:28
107-05-1
Benzene
ND
ug/L
1.0
0.34
1
03/31/23 01:28
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
03/31/23 01:28
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
03/31/23 01:28
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
03/31/23 01:28
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
03/31/23 01:28
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
03/31/23 01:28
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
03/31/23 01:28
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
03/31/23 01:28
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
03/31/23 01:28
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
03/31/23 01:28
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
03/31/23 01:28
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
03/31/23 01:28
74-87-3 v1
Chloroprene
ND
ug/L
5.0
1.6
1
03/31/23 01:28
126-99-8
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
03/31/23 01:28
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
03/31/23 01:28
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
03/31/23 01:28
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
03/31/23 01:28
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
03/31/23 01:28
95-50-1
1,3-Dichlorobenzene
ND
ug/L
1.0
0.34
1
03/31/23 01:28
541-73-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
03/31/23 01:28
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
03/31/23 01:28
110-57-6
Dichlorodifluoromethane
ND
ug/L
1.0
0.35
1
03/31/23 01:28
75-71-8
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
03/31/23 01:28
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
03/31/23 01:28
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
03/31/23 01:28
75-35-4
REPORT OF LABORATORY
ANALYSIS
This report
shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM
without the written
consent of Pace Analytical Services, LLC.
Page 60 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: FIELD BLANK Lab ID: 92659555010 Collected: 03/28/23 15:55 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level -Acrolein
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Ethyl methacrylate
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
4-Methyl-2-pentanone (MIBK)
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
Date: 05/05/2023 12:39 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.38
1
03/31/23 01:28
156-59-2
ND
ug/L
1.0
0.40
1
03/31/23 01:28
156-60-5
ND
ug/L
1.0
0.36
1
03/31/23 01:28
78-87-5
ND
ug/L
1.0
0.28
1
03/31/23 01:28
142-28-9
ND
ug/L
1.0
0.39
1
03/31/23 01:28
594-20-7
ND
ug/L
1.0
0.43
1
03/31/23 01:28
563-58-6
ND
ug/L
1.0
0.36
1
03/31/23 01:28
10061-01-5
ND
ug/L
1.0
0.36
1
03/31/23 01:28
10061-02-6
ND
ug/L
1.0
0.30
1
03/31/23 01:28
100-41-4
ND
ug/L
1.0
0.28
1
03/31/23 01:28
97-63-2
ND
ug/L
2.0
1.5
1
03/31/23 01:28
87-68-3
ND
ug/L
5.0
0.48
1
03/31/23 01:28
591-78-6
ND
ug/L
20.0
9.7
1
03/31/23 01:28
74-88-4
ND
ug/L
100
52.3
1
03/31/23 01:28
78-83-1
ND
ug/L
10.0
4.2
1
03/31/23 01:28
126-98-7
ND
ug/L
5.0
2.0
1
03/31/23 01:28
75-09-2
ND
ug/L
2.0
0.32
1
03/31/23 01:28
80-62-6
ND
ug/L
5.0
2.7
1
03/31/23 01:28
108-10-1
ND
ug/L
1.0
0.64
1
03/31/23 01:28
91-20-3
ND
ug/L
20.0
3.6
1
03/31/23 01:28
107-12-0
ND
ug/L
1.0
0.29
1
03/31/23 01:28
100-42-5
ND
ug/L
1.0
0.31
1
03/31/23 01:28
630-20-6
ND
ug/L
1.0
0.22
1
03/31/23 01:28
79-34-5
ND
ug/L
1.0
0.29
1
03/31/23 01:28
127-18-4
ND
ug/L
1.0
0.24
1
03/31/23 01:28
108-88-3
ND
ug/L
1.0
0.64
1
03/31/23 01:28
120-82-1
ND
ug/L
1.0
0.33
1
03/31/23 01:28
71-55-6
ND
ug/L
1.0
0.32
1
03/31/23 01:28
79-00-5
ND
ug/L
1.0
0.38
1
03/31/23 01:28
79-01-6
ND
ug/L
1.0
0.30
1
03/31/23 01:28
75-69-4
ND
ug/L
1.0
0.26
1
03/31/23 01:28
96-18-4
ND
ug/L
2.0
1.3
1
03/31/23 01:28
108-05-4
ND
ug/L
1.0
0.39
1
03/31/23 01:28
75-01-4
ND
ug/L
1.0
0.34
1
03/31/23 01:28
1330-20-7
115
%
70-130
1
03/31/23 01:28
460-00-4
110
%
70-130
1
03/31/23 01:28
17060-07-0
111
%
70-130
1
03/31/23 01:28
2037-26-5
v1
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND ug/L 100 22.0 1 03/31/23 02:52 18496-25-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 61 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: FIELD BLANK Lab ID: 92659555010 Collected: 03/28/23 15:55 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
4500CNE Cyanide, Total Analytical Method: SM 4500-CN-E-2016 Preparation Method: SM 4500-CN-E-2016
Pace Analytical Services -Asheville
Cyanide ND ug/L 8.0 6.0 1 04/03/23 18:41 04/03/23 22:02 57-12-5
Date: 05/05/2023 12:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 62 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: TB Lab ID: 92659555011 Collected: 03/28/23 00:00 Received: 03/29/23 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level -Acrolein
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Allyl chloride
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Chloroprene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Ethyl methacrylate
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Date: 05/05/2023 12:39 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
5.1
1
03/31/23 01:45
67-64-1 v1
ND
ug/L
50.0
24.8
1
03/31/23 01:45
75-05-8
ND
ug/L
10.0
8.5
1
03/31/23 01:45
107-02-8
ND
ug/L
10.0
1.8
1
03/31/23 01:45
107-13-1
ND
ug/L
2.0
0.50
1
03/31/23 01:45
107-05-1
ND
ug/L
1.0
0.34
1
03/31/23 01:45
71-43-2
ND
ug/L
1.0
0.47
1
03/31/23 01:45
74-97-5
ND
ug/L
1.0
0.31
1
03/31/23 01:45
75-27-4
ND
ug/L
1.0
0.34
1
03/31/23 01:45
75-25-2
ND
ug/L
2.0
1.7
1
03/31/23 01:45
74-83-9
ND
ug/L
5.0
4.0
1
03/31/23 01:45
78-93-3
ND
ug/L
2.0
0.36
1
03/31/23 01:45
75-15-0
ND
ug/L
1.0
0.33
1
03/31/23 01:45
56-23-5
ND
ug/L
1.0
0.28
1
03/31/23 01:45
108-90-7
ND
ug/L
1.0
0.65
1
03/31/23 01:45
75-00-3
ND
ug/L
1.0
0.43
1
03/31/23 01:45
67-66-3
ND
ug/L
1.0
0.54
1
03/31/23 01:45
74-87-3 v1
ND
ug/L
5.0
1.6
1
03/31/23 01:45
126-99-8
ND
ug/L
2.0
0.34
1
03/31/23 01:45
96-12-8
ND
ug/L
1.0
0.36
1
03/31/23 01:45
124-48-1
ND
ug/L
1.0
0.27
1
03/31/23 01:45
106-93-4
ND
ug/L
1.0
0.39
1
03/31/23 01:45
74-95-3
ND
ug/L
1.0
0.34
1
03/31/23 01:45
95-50-1
ND
ug/L
1.0
0.34
1
03/31/23 01:45
541-73-1
ND
ug/L
1.0
0.33
1
03/31/23 01:45
106-46-7
ND
ug/L
1.0
0.56
1
03/31/23 01:45
110-57-6
ND
ug/L
1.0
0.35
1
03/31/23 01:45
75-71-8
ND
ug/L
1.0
0.37
1
03/31/23 01:45
75-34-3
ND
ug/L
1.0
0.32
1
03/31/23 01:45
107-06-2
ND
ug/L
1.0
0.35
1
03/31/23 01:45
75-35-4
ND
ug/L
1.0
0.38
1
03/31/23 01:45
156-59-2
ND
ug/L
1.0
0.40
1
03/31/23 01:45
156-60-5
ND
ug/L
1.0
0.36
1
03/31/23 01:45
78-87-5
ND
ug/L
1.0
0.28
1
03/31/23 01:45
142-28-9
ND
ug/L
1.0
0.39
1
03/31/23 01:45
594-20-7
ND
ug/L
1.0
0.43
1
03/31/23 01:45
563-58-6
ND
ug/L
1.0
0.36
1
03/31/23 01:45
10061-01-5
ND
ug/L
1.0
0.36
1
03/31/23 01:45
10061-02-6
ND
ug/L
1.0
0.30
1
03/31/23 01:45
100-41-4
ND
ug/L
1.0
0.28
1
03/31/23 01:45
97-63-2
ND
ug/L
2.0
1.5
1
03/31/23 01:45
87-68-3
ND
ug/L
5.0
0.48
1
03/31/23 01:45
591-78-6
ND
ug/L
20.0
9.7
1
03/31/23 01:45
74-88-4
ND
ug/L
100
52.3
1
03/31/23 01:45
78-83-1
ND
ug/L
10.0
4.2
1
03/31/23 01:45
126-98-7 v1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 63 of 155

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
Sample: TB
Parameters
Lab ID:
Results
92659555011
Units
Collected:
Report
Limit
03/28/23 00:00
MDL DF
Received: 03/29/23 10:30 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level - Acrolein
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
Methylene Chloride
ND
ug/L
5.0
2.0
1
03/31/23 01:45
75-09-2
Methyl methacrylate
ND
ug/L
2.0
0.32
1
03/31/23 01:45
80-62-6
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
03/31/23 01:45
108-10-1
Naphthalene
ND
ug/L
1.0
0.64
1
03/31/23 01:45
91-20-3
Propionitrile
ND
ug/L
20.0
3.6
1
03/31/23 01:45
107-12-0
Styrene
ND
ug/L
1.0
0.29
1
03/31/23 01:45
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
03/31/23 01:45
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
03/31/23 01:45
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
03/31/23 01:45
127-18-4
Toluene
ND
ug/L
1.0
0.24
1
03/31/23 01:45
108-88-3
1,2,4-Trichlorobenzene
ND
ug/L
1.0
0.64
1
03/31/23 01:45
120-82-1
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
03/31/23 01:45
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
03/31/23 01:45
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
03/31/23 01:45
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
03/31/23 01:45
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
03/31/23 01:45
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
03/31/23 01:45
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
03/31/23 01:45
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
03/31/23 01:45
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
107
%
70-130
1
03/31/23 01:45
460-00-4
1,2-Dichloroethane-d4 (S)
106
%
70-130
1
03/31/23 01:45
17060-07-0
Toluene-d8 (S)
105
%
70-130
1
03/31/23 01:45
2037-26-5
Date: 05/05/2023 12:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 64 of 155

lV11.1 Analytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 2034529 Analysis Method: EPA 8151A
QC Batch Method: 8151A Analysis Description: Chlorinated Herb. (GC) 8151A
Laboratory: Pace National - Mt. Juliet
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555007, 92659555008, 92659555009, 92659555010
METHOD BLANK: R3910270-1
Matrix:
Water
Associated Lab Samples:
92659555001, 92659555002, 92659555003, 92659555007, 92659555008, 92659555009,
92659555010
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
2,4-D
ug/L
ND
2.00
0.547
04/06/23 00:08
Dinoseb
ug/L
ND
2.00
0.250
04/06/23 00:08
2,4,5-T
ug/L
ND
2.00
0.258
04/06/23 00:08
2,4,5-TP (Silvex)
ug/L
ND
2.00
0.335
04/06/23 00:08
2,4-DCAA (S)
%
59
14.0-158
04/06/23 00:08
LABORATORY CONTROL SAMPLE & LCSD:
R3910270-2
R3910270-3
Spike
LCS
LCSD
LCS
LCSD
% Rec
Max
Parameter
Units
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qualifiers
2,4-D
ug/L
5.00
2.84
3.51
56.8
70.2
50.0-120
21.1
20 P9,R1
Dinoseb
ug/L
5.00
3.39
4.01
67.8
80.2
36.0-134
16.8
20
2,4,5-T
ug/L
5.00
3.22
3.98
64.4
79.6
54.0-120
21.1
20 R1
2,4,5-TP (Silvex)
ug/L
5.00
2.65
3.41
53.0
68.2
50.0-125
25.1
20 P9,R1
2,4-DCAA (S)
%
66.4
83.4
14.0-158
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 65 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 765201 Analysis Method: RSK 175 Modified
QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555006
METHOD BLANK: 3973221 Matrix: Water
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555006
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Methane ug/L ND 10.0 5.3 03/31/2314:02
LABORATORY CONTROL SAMPLE: 3973222
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Methane ug/L 297 289 97 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3973224 3973225
MS MSD
92659785001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Methane ug/L ND 297 297 314 270 104 89 70-130 15 20
SAMPLE DUPLICATE: 3973223
92659546001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Methane ug/L 29.6 24.8 18 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 66 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 2034081 Analysis Method: EPA 6010D
QC Batch Method: 3015 Analysis Description: Metals (ICP) 6010D
Laboratory: Pace National - Mt. Juliet
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555004, 92659555005, 92659555006, 92659555007,
92659555008,92659555009,92659555010
METHOD BLANK: R3908660-1 Matrix: Water
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555004, 92659555005, 92659555006, 92659555007,
92659555008,92659555009,92659555010
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Antimony
ug/L
ND
10.0
4.30
04/03/2312:19
Arsenic
ug/L
ND
10.0
4.40
04/03/2312:19
Barium
ug/L
ND
5.00
0.736
04/03/2312:19
Beryllium
ug/L
ND
2.00
0.330
04/03/2312:19
Cadmium
ug/L
ND
2.00
0.479
04/03/2312:19
Chromium
ug/L
ND
10.0
1.40
04/03/2312:19
Cobalt
ug/L
ND
10.0
0.840
04/03/2312:19
Copper
ug/L
ND
10.0
3.68
04/03/2312:19
Lead
ug/L
ND
6.00
2.99
04/03/2312:19
Nickel
ug/L
1.73J
10.0
1.61
04/03/2312:19 J
Selenium
ug/L
ND
10.0
7.35
04/03/2312:19
Silver
ug/L
ND
5.00
1.54
04/03/2312:19
Tin
ug/L
ND
50.0
4.87
04/03/2312:19
Vanadium
ug/L
ND
20.0
4.99
04/03/2312:19
Zinc
ug/L
ND
50.0
6.52
04/03/2312:19
LABORATORY CONTROL SAMPLE:
Parameter
R3908660-2
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Antimony
ug/L
1000
974
97.4
80.0-120
Arsenic
ug/L
1000
981
98.1
80.0-120
Barium
ug/L
1000
1020
102
80.0-120
Beryllium
ug/L
1000
962
96.2
80.0-120
Cadmium
ug/L
1000
994
99.4
80.0-120
Chromium
ug/L
1000
956
95.6
80.0-120
Cobalt
ug/L
1000
990
99.0
80.0-120
Copper
ug/L
1000
995
99.5
80.0-120
Lead
ug/L
1000
982
98.2
80.0-120
Nickel
ug/L
1000
976
97.6
80.0-120
Selenium
ug/L
1000
1030
103
80.0-120
Silver
ug/L
200
191
95.5
80.0-120
Tin
ug/L
1000
985
98.5
80.0-120
Vanadium
ug/L
1000
987
98.7
80.0-120
Zinc
ug/L
1000
969
96.9
80.0-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 67 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
GM1.003 BUTNER LANDFILL
92659555
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3908660-4
R3908660-5
MS
MSD
92659555001
Spike
Spike
MS
MSD
MS
MSD % Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec Limits
RPD
RPD Qual
Antimony
ug/L
ND
1000
1000
981
982
98.1
98.2 75.0-125
0.034
20
Arsenic
ug/L
ND
1000
1000
970
961
97.0
96.1 75.0-125
0.963
20
Barium
ug/L
2.24
1000
1000
1010
998
101
99.6 75.0-125
1.70
20
Beryllium
ug/L
ND
1000
1000
963
964
96.3
96.4 75.0-125
0.103
20
Cadmium
ug/L
ND
1000
1000
988
976
98.8
97.6 75.0-125
1.24
20
Chromium
ug/L
ND
1000
1000
946
945
94.6
94.5 75.0-125
0.106
20
Cobalt
ug/L
ND
1000
1000
982
969
98.2
96.9 75.0-125
1.39
20
Copper
ug/L
ND
1000
1000
986
979
98.6
97.9 75.0-125
0.725
20
Lead
ug/L
ND
1000
1000
972
956
97.2
95.6 75.0-125
1.68
20
Nickel
ug/L
ND
1000
1000
971
957
97.1
95.7 75.0-125
1.43
20
Selenium
ug/L
ND
1000
1000
1020
1010
102
101 75.0-125
0.706
20
Silver
ug/L
ND
200
200
188
186
93.9
93.2 75.0-125
0.721
20
Tin
ug/L
ND
1000
1000
991
985
99.1
98.5 75.0-125
0.641
20
Vanadium
ug/L
ND
1000
1000
974
964
97.4
96.4 75.0-125
1.05
20
Zinc
ug/L
ND
1000
1000
957
942
95.7
94.2 75.0-125
1.60
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 68 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 2034089 Analysis Method: EPA 6020B
QC Batch Method: 3015 Analysis Description: Metals (ICPMS) 6020B
Laboratory: Pace National - Mt. Juliet
Associated Lab Samples: 92659555001, 92659555003, 92659555004, 92659555005, 92659555007, 92659555008, 92659555009,
92659555010
METHOD BLANK: R3909268-1 Matrix: Water
Associated Lab Samples: 92659555001, 92659555003, 92659555004, 92659555005, 92659555007, 92659555008, 92659555009,
92659555010
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Thallium ug/L ND 2.00 0.121 04/04/2317:29
LABORATORY CONTROL SAMPLE: R3909268-2
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Thallium ug/L 50.0 50.4 101 80.0-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3909268-4 R3909268-5
MS MSD
L1600480-01 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Thallium ug/L ND 50.0 50.0 48.9 48.8 97.8 97.6 75.0-125 0.238 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 69 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 2035514 Analysis Method: EPA 6020B
QC Batch Method: 3015 Analysis Description: Metals (ICPMS) 6020B
Laboratory: Pace National - Mt. Juliet
Associated Lab Samples: 92659555002
METHOD BLANK: R3909282-6
Associated Lab Samples: 92659555002
Parameter Units
Thallium ug/L
LABORATORY CONTROL SAMPLE: R3909282-7
Parameter Units
Thallium ug/L
Matrix: Water
Blank Reporting
Result Limit
ND 2.00
Spike LCS
Conc. Result
50.0 48.3
MDL Analyzed Qualifiers
0.121 04/04/23 19:19
LCS % Rec
% Rec Limits Qualifiers
96.6 80.0-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3909282-4 R3909282-5
MS MSD
L1601349-04 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Thallium ug/L ND 50.0 50.0 47.9 48.6 95.8 97.3 75.0-125 1.54 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 70 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 2033921 Analysis Method: EPA 7470A
QC Batch Method: 7470A Analysis Description: Mercury 7470A
Laboratory: Pace National - Mt. Juliet
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555007, 92659555008, 92659555009, 92659555010
METHOD BLANK: R3910599-1 Matrix: Water
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555007, 92659555008, 92659555009, 92659555010
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Mercury ug/L ND 0.200 0.100 04/07/2311:52
LABORATORY CONTROL SAMPLE: R3910599-2
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 3.00 2.74 91.3 80.0-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3910599-3 R3910599-4
MS MSD
L1600512-04 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND 3.00 3.00 2.76 2.79 92.0 93.0 75.0-125 1.08 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 71 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 764919 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92659555004, 92659555005
METHOD BLANK: 3971846
Associated Lab Samples: 92659555004, 92659555005
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
03/31/23 00:50
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
03/31/23 00:50
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
03/31/23 00:50
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
03/31/23 00:50
1,1-Dichloroethane
ug/L
ND
1.0
0.37
03/31/23 00:50
1,1-Dichloroethene
ug/L
ND
1.0
0.35
03/31/23 00:50
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
03/31/23 00:50
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
03/31/23 00:50
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
03/31/23 00:50
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
03/31/23 00:50
1,2-Dichloroethane
ug/L
ND
1.0
0.32
03/31/23 00:50
1,2-Dichloropropane
ug/L
ND
1.0
0.36
03/31/23 00:50
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
03/31/23 00:50
2-Butanone (MEK)
ug/L
ND
5.0
4.0
03/31/23 00:50
2-Hexanone
ug/L
ND
5.0
0.48
03/31/23 00:50
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
03/31/23 00:50
Acetone
ug/L
ND
25.0
5.1
03/31/23 00:50
Acrylonitrile
ug/L
ND
10.0
1.8
03/31/23 00:50
Benzene
ug/L
ND
1.0
0.34
03/31/23 00:50
Bromochloromethane
ug/L
ND
1.0
0.47
03/31/23 00:50
Bromodichloromethane
ug/L
ND
1.0
0.31
03/31/23 00:50
Bromoform
ug/L
ND
1.0
0.34
03/31/23 00:50
Bromomethane
ug/L
ND
2.0
1.7
03/31/23 00:50
Carbon disulfide
ug/L
ND
2.0
0.36
03/31/23 00:50
Carbon tetrachloride
ug/L
ND
1.0
0.33
03/31/23 00:50
Chlorobenzene
ug/L
ND
1.0
0.28
03/31/23 00:50
Chloroethane
ug/L
ND
1.0
0.65
03/31/23 00:50
Chloroform
ug/L
ND
1.0
0.43
03/31/23 00:50
Chloromethane
ug/L
ND
1.0
0.54
03/31/23 00:50
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
03/31/23 00:50
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
03/31/23 00:50
Dibromochloromethane
ug/L
ND
1.0
0.36
03/31/23 00:50
Dibromomethane
ug/L
ND
1.0
0.39
03/31/23 00:50
Ethylbenzene
ug/L
ND
1.0
0.30
03/31/23 00:50
lodomethane
ug/L
ND
20.0
9.7
03/31/23 00:50
Methylene Chloride
ug/L
ND
5.0
2.0
03/31/23 00:50
Styrene
ug/L
ND
1.0
0.29
03/31/23 00:50
Tetrachloroethene
ug/L
ND
1.0
0.29
03/31/23 00:50
Toluene
ug/L
ND
1.0
0.24
03/31/23 00:50
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
03/31/23 00:50
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 72 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
METHOD BLANK: 3971846
Associated Lab Samples: 92659555004, 92659555005
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit MDL
trans- 1,3-Dichloropropene
ug/L
ND
1.0
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
Trichloroethene
ug/L
ND
1.0
Trichlorofluoromethane
ug/L
ND
1.0
Vinyl acetate
ug/L
ND
2.0
Vinyl chloride
ug/L
ND
1.0
Xylene (Total)
ug/L
ND
1.0
1,2-Dichloroethane-d4 (S)
%
95
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
108
70-130
Analyzed
0.36 03/31 /23 00:50
0.56 03/31 /23 00:50
0.38 03/31 /23 00:50
0.30 03/31 /23 00:50
1.3 03/31 /23 00:50
0.39 03/31 /23 00:50
0.34 03/31 /23 00:50
03/31 /23 00:50
03/31 /23 00:50
03/31 /23 00:50
LABORATORY CONTROL SAMPLE:
Parameter
3971847
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
20
20.4
102
70-130
1,1,1-Trichloroethane
ug/L
20
21.5
107
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
20.3
102
70-130
1,1,2-Trichloroethane
ug/L
20
21.1
106
70-130
1,1-Dichloroethane
ug/L
20
20.7
104
70-130
1,1-Dichloroethene
ug/L
20
22.2
111
70-130
1,2,3-Trichloropropane
ug/L
20
19.2
96
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
17.0
85
70-131
1,2-Dibromoethane (EDB)
ug/L
20
19.7
98
70-130
1,2-Dichlorobenzene
ug/L
20
20.4
102
70-130
1,2-Dichloroethane
ug/L
20
20.6
103
70-130
1,2-Dichloropropane
ug/L
20
20.9
105
70-130
1,4-Dichlorobenzene
ug/L
20
20.6
103
70-130
2-Butanone (MEK)
ug/L
40
39.9
100
70-134
2-Hexanone
ug/L
40
39.9
100
70-131
4-Methyl-2-pentanone (MIBK)
ug/L
40
41.1
103
70-130
Acetone
ug/L
40
36.0
90
70-133
Acrylonitrile
ug/L
100
106
106
70-130
Benzene
ug/L
20
20.4
102
70-130
Bromochloromethane
ug/L
20
20.2
101
70-130
Bromodichloromethane
ug/L
20
19.9
99
70-130
Bromoform
ug/L
20
18.0
90
70-130
Bromomethane
ug/L
20
20.8
104
45-151
Carbon disulfide
ug/L
20
20.2
101
70-130
Carbon tetrachloride
ug/L
20
20.8
104
70-130
Chlorobenzene
ug/L
20
20.7
103
70-130
Chloroethane
ug/L
20
23.0
115
39-152
Chloroform
ug/L
20
21.4
107
70-130
Chloromethane
ug/L
20
23.1
115
58-130
cis-1,2-Dichloroethene
ug/L
20
21.4
107
70-130
Qualifiers
KI
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 73 of 155

Pace Analytical Services, LLC
9800
lCtaac,Analyfical ® Kiney Ave. Suite 100
Huntersville, NC 28078
0788
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
LABORATORY CONTROL SAMPLE:
Parameter
3971847
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
cis-1,3-Dichloropropene
ug/L
20
19.8
99
70-130
Dibromochloromethane
ug/L
20
19.4
97
70-130
Dibromomethane
ug/L
20
19.5
98
70-130
Ethylbenzene
ug/L
20
20.0
100
70-130
lodomethane
ug/L
40
38.2
95
53-141
Methylene Chloride
ug/L
20
19.2
96
66-130
Styrene
ug/L
20
20.7
104
70-130
Tetrachloroethene
ug/L
20
19.7
99
70-130
Toluene
ug/L
20
20.3
102
70-130
trans-1,2-Dichloroethene
ug/L
20
22.1
111
70-130
trans- 1,3-Dichloropropene
ug/L
20
19.8
99
70-130
trans-1,4-Dichloro-2-butene
ug/L
20
21.5
108
57-185
Trichloroethene
ug/L
20
21.3
106
70-130
Trichlorofluoromethane
ug/L
20
20.6
103
62-130
Vinyl acetate
ug/L
40
42.3
106
70-144 IK
Vinyl chloride
ug/L
20
17.8
89
62-130
Xylene (Total)
ug/L
60
61.3
102
70-130
1,2-Dichloroethane-d4 (S)
%
101
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
99
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3971848
MS
92659389010 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3971849
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
Max
RPD RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
1000
1000
19AJ
20.6J
2
2
70-141
30 M1
1,1,1-Trichloroethane
ug/L
ND
1000
1000
ND
ND
2
2
70-150
30 M1
1,1,2,2-Tetrachloroethane
ug/L
ND
1000
1000
24.OJ
21AJ
2
2
69-142
30 M1
1,1,2-Trichloroethane
ug/L
ND
1000
1000
21.5J
20.9J
2
2
70-138
30 M1
1,1-Dichloroethane
ug/L
ND
1000
1000
19.6J
19AJ
2
2
70-150
30 M1
1,1-Dichloroethene
ug/L
ND
1000
1000
ND
ND
2
2
70-156
30 M1
1,2,3-Trichloropropane
ug/L
ND
1000
1000
23.8J
21.OJ
2
2
70-140
30 M1
1,2-Dibromo-3-
ug/L
ND
1000
1000
28.6J
17.8J
3
2
68-146
30 M1
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
1000
1000
20.OJ
19.91
2
2
70-138
30 M1
1,2-Dichlorobenzene
ug/L
ND
1000
1000
27.9J
25.OJ
3
2
70-141
30 M1
1,2-Dichloroethane
ug/L
ND
1000
1000
22.2J
19AJ
2
2
69-143
30 M1
1,2-Dichloropropane
ug/L
ND
1000
1000
ND
ND
2
2
68-156
30 M1
1,4-Dichlorobenzene
ug/L
ND
1000
1000
29.5J
26.9J
3
3
70-142
30 M1
2-Butanone (MEK)
ug/L
17000
2000
2000
17700
18200
34
55
60-157
2 30 M1
2-Hexanone
ug/L
ND
2000
2000
93.6J
95.9J
3
3
68-146
30 M1
4-Methyl-2-pentanone
ug/L
ND
2000
2000
203J
200J
3
2
70-141
30 M1
(MIBK)
Acetone ug/L
13600 2000 2000 15200 16100 80 123 58-157
6 30
Acrylonitrile ug/L
ND 5000 5000 1111 97.5J 2 2 69-147
30 M1
Benzene ug/L
ND 1000 1000 23.7J 23.6J 2 2 70-142
30 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM
without the written consent of Pace Analytical Services, LLC.
Page 74 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 3971848
3971849
MS
MSD
92659389010
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD RPD Qual
Bromochloromethane
ug/L
ND
1000
1000
ND
ND
1
1
70-146
30 M1
Bromodichloromethane
ug/L
ND
1000
1000
15AJ
16.2J
2
2
70-139
30 M1
Bromoform
ug/L
ND
1000
1000
18.9J
17.8J
2
2
64-140
30 M1
Bromomethane
ug/L
ND
1000
1000
ND
ND
1
1
28-192
30 M1
Carbon disulfide
ug/L
ND
1000
1000
18.2J
ND
2
2
70-151
30 M1
Carbon tetrachloride
ug/L
ND
1000
1000
ND
ND
1
2
70-148
30 M1
Chlorobenzene
ug/L
ND
1000
1000
21.OJ
20.3J
2
2
70-141
30 M1
Chloroethane
ug/L
ND
1000
1000
ND
ND
2
1
58-191
30 M1
Chloroform
ug/L
ND
1000
1000
ND
ND
2
2
70-148
30 M1
Chloromethane
ug/L
ND
1000
1000
ND
ND
1
1
43-162
30 M1
cis-1,2-Dichloroethene
ug/L
ND
1000
1000
20.8J
20.2J
2
2
68-151
30 M1
cis-1,3-Dichloropropene
ug/L
ND
1000
1000
18.3J
ND
2
2
70-139
30 M1
Dibromochloromethane
ug/L
ND
1000
1000
18.2J
ND
2
2
70-144
30 M1
Dibromomethane
ug/L
ND
1000
1000
ND
ND
2
1
70-139
30 M1
Ethylbenzene
ug/L
ND
1000
1000
38.2J
37.6J
2
2
70-143
30 M1
lodomethane
ug/L
ND
2000
2000
ND
ND
1
1
35-171
30 IK,M1,
v3
Methylene Chloride
ug/L
ND
1000
1000
182J
181J
-1
-1
62-149
30 M1,v1
Styrene
ug/L
ND
1000
1000
21AJ
18AJ
2
2
70-143
30 M1
Tetrachloroethene
ug/L
ND
1000
1000
16.2J
17.3J
2
2
70-145
30 M1
Toluene
ug/L
57.7
1000
1000
78.5
75.1
2
2
70-142
4 30 M1
trans-1,2-Dichloroethene
ug/L
ND
1000
1000
ND
ND
2
2
70-151
30 M1
trans-1,3-Dichloropropene
ug/L
ND
1000
1000
ND
18.5J
2
2
70-139
30 M1
trans-1,4-Dichloro-2-butene
ug/L
ND
1000
1000
ND
ND
3
2
51-159
30 M1
Trichloroethene
ug/L
ND
1000
1000
ND
ND
2
1
62-146
30 M1
Trichlorofluoromethane
ug/L
ND
1000
1000
ND
ND
1
1
63-153
30 M1,v3
Vinyl acetate
ug/L
ND
2000
2000
ND
ND
2
2
61-162
30 M1
Vinyl chloride
ug/L
ND
1000
1000
ND
ND
1
1
61-163
30 M1,v3
Xylene (Total)
ug/L
ND
3000
3000
ND
ND
0
0
70-143
30 MS
1,2-Dichloroethane-d4 (S)
%
106
106
70-130
4-Bromofluorobenzene (S)
%
99
99
70-130
Toluene-d8 (S)
%
101
101
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 75 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 764931
Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D
Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92659555006
METHOD BLANK: 3971910
Matrix: Water
Associated Lab Samples: 92659555006
Blank Reporting
Parameter
Units
Result Limit MDL
Analyzed Qualifiers
Benzene
ug/L
ND 1.0
0.34 03/31/23 00:40
1,2-Dichloroethane-d4 (S)
%
108 70-130
03/31/23 00:40
4-Bromofluorobenzene (S)
%
97 70-130
03/31/23 00:40
Toluene-d8 (S)
%
101 70-130
03/31/23 00:40
LABORATORY CONTROL SAMPLE: 3971911
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
Benzene
ug/L
20 20.6 103
70-130
1,2-Dichloroethane-d4 (S)
%
105
70-130
4-Bromofluorobenzene (S)
%
101
70-130
Toluene-d8 (S)
%
99
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3971912 3971913
MS MSD
92659513001
Spike Spike MS MSD
MS MSD % Rec Max
Parameter Units
Result
Conc. Conc. Result Result
% Rec % Rec Limits RPD RPD Qual
Benzene ug/L
ND
20 20 22.1 21.4
111 107 70-142 3 30
1,2-Dichloroethane-d4 (S) %
95 93 70-130
4-Bromofluorobenzene (S) %
97 98 70-130
Toluene-d8 (S) %
96 96 70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 76 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 765280 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92659555001, 92659555003, 92659555004, 92659555005, 92659555006, 92659555007, 92659555008,
92659555009,92659555010
METHOD BLANK: 3973702
Matrix:
Water
Associated Lab Samples:
92659555001, 92659555003, 92659555004,
92659555005, 92659555006, 92659555007, 92659555008,
92659555009,92659555010
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
0.86 03/31/23 18:07
1,2-Dichloroethane-d4 (S)
%
88
67-130
03/31/23 18:07
Toluene-d8 (S)
%
94
70-130
03/31/23 18:07
LABORATORY CONTROL SAMPLE: 3973703
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 17.6 88 70-130
1,2-Dichloroethane-d4 (S) % 88 67-130
Toluene-d8(S) % 94 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3973704
3973705
MS
MSD
92659673008 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L ND 20
20 19.8 18.4
99
91
55-137
8 30 H1
1,2-Dichloroethane-d4 (S)
%
94
91
67-130
30
Toluene-d8 (S)
%
95
93
70-130
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 77 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 765583 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92659555002
METHOD BLANK: 3975244
Matrix:
Water
Associated Lab Samples: 92659555002
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
0.86 04/03/23 17:55
1,2-Dichloroethane-d4 (S)
%
86
67-130
04/03/23 17:55
Toluene-d8 (S)
%
92
70-130
04/03/23 17:55
LABORATORY CONTROL SAMPLE: 3975245
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 18.3 92 70-130
1,2-Dichloroethane-d4 (S) % 92 67-130
Toluene-d8(S) % 94 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3975246
3975247
MS
MSD
92659539007 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L 0.88J 20
20 19.4 18.1
92
86
55-137
7 30
1,2-Dichloroethane-d4 (S)
%
79
82
67-130
30
Toluene-d8 (S)
%
87
88
70-130
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 78 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 765038 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555007, 92659555008, 92659555009, 92659555010,
92659555011
METHOD BLANK: 3972572
Matrix: Water
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555007, 92659555008, 92659555009, 92659555010,
92659555011
Parameter
Units
Blank
Result
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
03/31/23 00:53
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
03/31/23 00:53
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
03/31/23 00:53
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
03/31/23 00:53
1,1-Dichloroethane
ug/L
ND
1.0
0.37
03/31/23 00:53
1,1-Dichloroethene
ug/L
ND
1.0
0.35
03/31/23 00:53
1,1-Dichloropropene
ug/L
ND
1.0
0.43
03/31/23 00:53
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
03/31/23 00:53
1,2,4-Trichlorobenzene
ug/L
ND
1.0
0.64
03/31/23 00:53
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
03/31/23 00:53
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
03/31/23 00:53
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
03/31/23 00:53
1,2-Dichloroethane
ug/L
ND
1.0
0.32
03/31/23 00:53
1,2-Dichloropropane
ug/L
ND
1.0
0.36
03/31/23 00:53
1,3-Dichlorobenzene
ug/L
ND
1.0
0.34
03/31/23 00:53
1,3-Dichloropropane
ug/L
ND
1.0
0.28
03/31/23 00:53
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
03/31/23 00:53
2,2-Dichloropropane
ug/L
ND
1.0
0.39
03/31/23 00:53
2-Butanone (MEK)
ug/L
ND
5.0
4.0
03/31/23 00:53
2-Hexanone
ug/L
ND
5.0
0.48
03/31/23 00:53
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
03/31/23 00:53
Acetone
ug/L
ND
25.0
5.1
03/31/23 00:53
Acetonitrile
ug/L
ND
50.0
24.8
03/31/23 00:53
Acrolein
ug/L
ND
10.0
8.5
03/31/23 00:53
Acrylonitrile
ug/L
ND
10.0
1.8
03/31/23 00:53
Allyl chloride
ug/L
ND
2.0
0.50
03/31/23 00:53
Benzene
ug/L
ND
1.0
0.34
03/31/23 00:53
Bromochloromethane
ug/L
ND
1.0
0.47
03/31/23 00:53
Bromodichloromethane
ug/L
ND
1.0
0.31
03/31/23 00:53
Bromoform
ug/L
ND
1.0
0.34
03/31/23 00:53
Bromomethane
ug/L
ND
2.0
1.7
03/31/23 00:53
Carbon disulfide
ug/L
ND
2.0
0.36
03/31/23 00:53
Carbon tetrachloride
ug/L
ND
1.0
0.33
03/31/23 00:53
Chlorobenzene
ug/L
ND
1.0
0.28
03/31/23 00:53
Chloroethane
ug/L
ND
1.0
0.65
03/31/23 00:53
Chloroform
ug/L
ND
1.0
0.43
03/31/23 00:53
Chloromethane
ug/L
ND
1.0
0.54
03/31/23 00:53
Chloroprene
ug/L
ND
5.0
1.6
03/31/23 00:53
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
03/31/23 00:53
v1
v1
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 79 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
METHOD BLANK: 3972572 Matrix: Water
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555007, 92659555008, 92659555009, 92659555010,
92659555011
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
03/31/23 00:53
Dibromochloromethane
ug/L
ND
1.0
0.36
03/31/23 00:53
Dibromomethane
ug/L
ND
1.0
0.39
03/31/23 00:53
Dichlorodifluoromethane
ug/L
ND
1.0
0.35
03/31/23 00:53
Ethyl methacrylate
ug/L
ND
1.0
0.28
03/31/23 00:53
Ethylbenzene
ug/L
ND
1.0
0.30
03/31/23 00:53
Hexachloro-1,3-butadiene
ug/L
ND
2.0
1.5
03/31/23 00:53
lodomethane
ug/L
ND
20.0
9.7
03/31/23 00:53
Isobutanol
ug/L
ND
100
52.3
03/31/23 00:53
Methacrylonitrile
ug/L
ND
10.0
4.2
03/31/23 00:53 v1
Methyl methacrylate
ug/L
ND
2.0
0.32
03/31/23 00:53
Methylene Chloride
ug/L
ND
5.0
2.0
03/31/23 00:53
Naphthalene
ug/L
ND
1.0
0.64
03/31/23 00:53
Propionitrile
ug/L
ND
20.0
3.6
03/31/23 00:53
Styrene
ug/L
ND
1.0
0.29
03/31/23 00:53
Tetrachloroethene
ug/L
ND
1.0
0.29
03/31/23 00:53
Toluene
ug/L
ND
1.0
0.24
03/31/23 00:53
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
03/31/23 00:53
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
03/31/23 00:53
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
03/31/23 00:53
Trichloroethene
ug/L
ND
1.0
0.38
03/31/23 00:53
Trichlorofluoromethane
ug/L
ND
1.0
0.30
03/31/23 00:53
Vinyl acetate
ug/L
ND
2.0
1.3
03/31/23 00:53
Vinyl chloride
ug/L
ND
1.0
0.39
03/31/23 00:53
Xylene (Total)
ug/L
ND
1.0
0.34
03/31/23 00:53
1,2-Dichloroethane-d4 (S)
%
111
70-130
03/31/23 00:53
4-Bromofluorobenzene (S)
%
110
70-130
03/31/23 00:53
Toluene-d8 (S)
%
101
70-130
03/31/23 00:53
LABORATORY CONTROL SAMPLE:
3972573
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
20
19.9
99
70-130
1,1,1-Trichloroethane
ug/L
20
22.0
110
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
23.3
116
70-130
1,1,2-Trichloroethane
ug/L
20
21.7
108
70-130
1,1-Dichloroethane
ug/L
20
21.4
107
70-130
1,1-Dichloroethene
ug/L
20
22.3
111
70-130
1,1-Dichloropropene
ug/L
20
23.3
117
70-130
1,2,3-Trichloropropane
ug/L
20
21.3
107
70-130
1,2,4-Trichlorobenzene
ug/L
20
18.5
93
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
18.9
95
70-131
1,2-Dibromoethane (EDB)
ug/L
20
20.0
100
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 80 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
LABORATORY CONTROL SAMPLE:
Parameter
3972573
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,2-Dichlorobenzene
ug/L
20
19.3
96
70-130
1,2-Dichloroethane
ug/L
20
23.4
117
70-130
1,2-Dichloropropane
ug/L
20
22.0
110
70-130
1,3-Dichlorobenzene
ug/L
20
18.9
94
70-130
1,3-Dichloropropane
ug/L
20
20.5
102
70-130
1,4-Dichlorobenzene
ug/L
20
19.0
95
70-130
2,2-Dichloropropane
ug/L
20
21.0
105
68-135
2-Butanone (MEK)
ug/L
40
47.2
118
70-134
2-Hexanone
ug/L
40
48.3
121
70-131
4-Methyl-2-pentanone (MIBK)
ug/L
40
47.2
118
70-130
Acetone
ug/L
40
47.0
117
70-133 v1
Acetonitrile
ug/L
200
232
116
70-130
Acrolein
ug/L
100
118
118
52-170
Acrylonitrile
ug/L
100
123
123
70-130
Allyl chloride
ug/L
20
19.9
100
70-130
Benzene
ug/L
20
20.5
103
70-130
Bromochloromethane
ug/L
20
21.0
105
70-130
Bromodichloromethane
ug/L
20
21.0
105
70-130
Bromoform
ug/L
20
20.1
101
70-130
Bromomethane
ug/L
20
14.6
73
45-151
Carbon disulfide
ug/L
20
21.0
105
70-130
Carbon tetrachloride
ug/L
20
22.4
112
70-130
Chlorobenzene
ug/L
20
19.7
99
70-130
Chloroethane
ug/L
20
20.8
104
39-152
Chloroform
ug/L
20
20.4
102
70-130
Chloromethane
ug/L
20
25.9
129
58-130 v1
Chloroprene
ug/L
20
23.5
118
70-130
cis-1,2-Dichloroethene
ug/L
20
22.3
112
70-130
cis-1,3-Dichloropropene
ug/L
20
21.6
108
70-130
Dibromochloromethane
ug/L
20
21.7
108
70-130
Dibromomethane
ug/L
20
20.0
100
70-130
Dichlorodifluoromethane
ug/L
20
21.9
109
54-133
Ethyl methacrylate
ug/L
20
22.3
111
70-130
Ethylbenzene
ug/L
20
20.3
101
70-130
Hexachloro-1,3-butadiene
ug/L
20
20.7
103
70-135
lodomethane
ug/L
40
38.2
95
53-141
Isobutanol
ug/L
400
478
120
70-136
Methacrylonitrile
ug/L
200
240
120
70-130 v1
Methyl methacrylate
ug/L
20
21.5
107
70-130
Methylene Chloride
ug/L
20
21.2
106
66-130
Naphthalene
ug/L
20
19.9
99
70-130
Propionitrile
ug/L
200
243
121
70-130
Styrene
ug/L
20
21.0
105
70-130
Tetrachloroethene
ug/L
20
18.4
92
70-130
Toluene
ug/L
20
20.2
101
70-130
trans-1,2-Dichloroethene
ug/L
20
22.4
112
70-130
trans- 1,3-Dichloropropene
ug/L
20
21.7
108
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 81 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
LABORATORY CONTROL SAMPLE:
3972573
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
trans-1,4-Dichloro-2-butene
ug/L
20
32.5
163
57-185
Trichloroethene
ug/L
20
20.5
103
70-130
Trichlorofluoromethane
ug/L
20
20.3
101
62-130
Vinyl acetate
ug/L
40
44.3
111
70-144
Vinyl chloride
ug/L
20
18.0
90
62-130
Xylene (Total)
ug/L
60
61.8
103
70-130
1,2-Dichloroethane-d4 (S)
%
111
70-130
4-Bromofluorobenzene (S)
%
117
70-130
Toluene-d8 (S)
%
103
70-130
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
3972574
3972575
MS
MSD
92659721004
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result % Rec % Rec
Limits
RPD
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
19.9
24.0
99
120
70-141
19
30 H1
1,1,1-Trichloroethane
ug/L
ND
20
20
19.6
22.1
98
111
70-150
12
30 H1
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
17.8
21.0
89
105
69-142
16
30 H1
1,1,2-Trichloroethane
ug/L
ND
20
20
19.8
22.2
99
111
70-138
11
30 H1
1,1-Dichloroethane
ug/L
ND
20
20
18.0
20.9
90
105
70-150
15
30 H1
1,1-Dichloroethene
ug/L
ND
20
20
19.1
22.0
95
110
70-156
14
30 H1
1,1-Dichloropropene
ug/L
ND
20
20
19.2
23.4
96
117
70-150
19
30 H1
1,2,3-Trichooropropane
ug/L
ND
20
20
17.7
20.5
89
103
70-140
15
30 H1
1,2,4-Trichoorobenzene
ug/L
ND
20
20
20.1
23.9
100
119
70-146
17
30 H1
1,2-Dibromo-3-
ug/L
ND
20
20
20.4
21.9
102
109
68-146
7
30 H1
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
19.2
22.4
96
112
70-138
15
30 H1
1,2-Dichlorobenzene
ug/L
ND
20
20
19.5
22.8
97
114
70-141
16
30 H1
1,2-Dichloroethane
ug/L
ND
20
20
18.3
20.7
91
103
69-143
12
30 H1
1,2-Dichloropropane
ug/L
ND
20
20
18.4
20.6
92
103
68-156
11
30 H1
1,3-Dichlorobenzene
ug/L
ND
20
20
19.8
23.0
99
115
70-143
15
30 H1
1,3-Dichloropropane
ug/L
ND
20
20
18.0
21.5
90
107
70-138
18
30 H1
1,4-Dichlorobenzene
ug/L
ND
20
20
19.1
22.4
96
112
70-142
16
30 H1
2,2-Dichloropropane
ug/L
ND
20
20
19.2
22.1
96
111
52-170
14
30 H1
2-Butanone (MEK)
ug/L
ND
40
40
32.6
36.0
82
90
60-157
10
30 H1
2-Hexanone
ug/L
ND
40
40
35.9
40.6
90
102
68-146
12
30 H1
4-Methyl-2-pentanone
ug/L
ND
40
40
35.7
40.0
89
100
70-141
11
30 H1
(MIBK)
Acetone
ug/L
ND
40
40
31.9
35.4
80
89
58-157
11
30 H1
Acetonitrile
ug/L
ND
200
200
164
183
82
92
66-153
11
30 H1
Acrolein
ug/L
ND
100
100
71.4
83.0
71
83
10-200
15
30 H1
Acrylonitrile
ug/L
ND
100
100
86.0
96.9
86
97
69-147
12
30 H1
Allyl chloride
ug/L
ND
20
20
17.5
20.7
87
104
65-153
17
30 H1
Benzene
ug/L
ND
20
20
19.4
22.5
97
113
70-142
15
30 H1
Bromochloromethane
ug/L
ND
20
20
20.1
22.0
101
110
70-146
9
30 H1
Bromodichloromethane
ug/L
ND
20
20
18.9
21.5
94
107
70-139
13
30 H1
Bromoform
ug/L
ND
20
20
19.2
22.5
96
113
64-140
16
30 H1
Results presented
on this page are in the
units
indicated by the
"Units" column except where
an alternate unit is presented to the right of the result.
REPORT
OF
LABORATORY ANALYSIS
This report shall
not be reproduced,
except
in full,
Date: 05/05/2023 12:39 PM
without
the written consent of Pace Analytical Services, LLC.
Page 82 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 3972574
3972575
MS
MSD
92659721004
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Bromomethane
ug/L
ND
20
20
15.2
17.4
76
87
28-192
14
30 H1
Carbon disulfide
ug/L
ND
20
20
18.4
21.0
92
105
70-151
13
30 H1
Carbon tetrachloride
ug/L
ND
20
20
19.9
22.8
100
114
70-148
13
30 H1
Chlorobenzene
ug/L
ND
20
20
19.2
23.0
96
115
70-141
18
30 H1
Chloroethane
ug/L
ND
20
20
17.5
20.9
88
104
58-191
17
30 H1
Chloroform
ug/L
ND
20
20
19.8
22.2
99
111
70-148
11
30 H1
Chloromethane
ug/L
ND
20
20
17.6
20.1
88
100
43-162
13
30 H1
Chloroprene
ug/L
ND
20
20
19.0
22.9
95
115
69-158
19
30 H1
cis-1,2-Dichloroethene
ug/L
ND
20
20
18.3
21.5
92
108
68-151
16
30 H1
cis-1,3-Dichloropropene
ug/L
ND
20
20
19.1
22.4
95
112
70-139
16
30 H1
Dibromochloromethane
ug/L
ND
20
20
19.3
22.8
96
114
70-144
17
30 H1
Dibromomethane
ug/L
ND
20
20
20.5
23.5
103
117
70-139
13
30 H1
Dichlorodifluoromethane
ug/L
ND
20
20
24.6
28.5
123
143
39-171
15
30 H1
Ethyl methacrylate
ug/L
ND
20
20
17.5
20.1
88
101
70-140
14
30 H1
Ethylbenzene
ug/L
ND
20
20
18.6
21.9
93
109
70-143
16
30 H1
Hexachloro-1,3-butadiene
ug/L
ND
20
20
21.5
26.7
107
133
64-163
21
30 H1
lodomethane
ug/L
ND
40
40
40.4
47.5
101
119
35-171
16
30 H1
Isobutanol
ug/L
ND
400
400
309
347
77
87
49-152
12
30 H1
Methacrylonitrile
ug/L
ND
200
200
166
187
83
94
66-145
12
30 H1
Methyl methacrylate
ug/L
ND
20
20
18.5
20.5
93
102
70-135
10
30 H1
Methylene Chloride
ug/L
ND
20
20
16.1
18.4
80
92
62-149
13
30 H1
Naphthalene
ug/L
ND
20
20
21.3
23.7
106
119
67-147
11
30 H1
Propionitrile
ug/L
ND
200
200
177
189
88
95
69-143
7
30 H1
Styrene
ug/L
ND
20
20
19.8
23.5
99
117
70-143
17
30 H1
Tetrachloroethene
ug/L
ND
20
20
19.5
23.3
97
116
70-145
18
30 H1
Toluene
ug/L
ND
20
20
18.6
21.7
93
108
70-142
15
30 H1
trans-1,2-Dichloroethene
ug/L
ND
20
20
18.0
21.1
90
105
70-151
16
30 H1
trans-1,3-Dichloropropene
ug/L
ND
20
20
19.3
22.1
97
110
70-139
13
30 H1
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
19.5
22.5
97
113
51-159
15
30 H1
Trichloroethene
ug/L
ND
20
20
20.3
23.4
102
117
62-146
14
30 H1
Trichlorofluoromethane
ug/L
ND
20
20
19.8
23.2
99
116
63-153
16
30 H1
Vinyl acetate
ug/L
ND
40
40
35.5
40.4
89
101
61-162
13
30 H1
Vinyl chloride
ug/L
ND
20
20
15.0
17.3
75
87
61-163
14
30 H1
Xylene (Total)
ug/L
ND
60
60
57.1
67.8
95
113
70-143
17
30
1,2-Dichloroethane-d4 (S)
%
93
92
70-130
4-Bromofluorobenzene (S)
%
96
97
70-130
Toluene-d8 (S)
%
97
96
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 83 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 765668 Analysis Method: EPA 8081 B
QC Batch Method: EPA 3510C Analysis Description: 8081 OC Pesticides Red Vol
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555007, 92659555008, 92659555009, 92659555010
METHOD BLANK: 3975521 Matrix: Water
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555007, 92659555008, 92659555009, 92659555010
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
4,4'-DDD
ug/L
ND
0.050
0.017
04/05/23 14:18
4,4'-DDE
ug/L
ND
0.050
0.024
04/05/23 14:18
4,4'-DDT
ug/L
ND
0.050
0.026
04/05/23 14:18
Aldrin
ug/L
ND
0.050
0.014
04/05/23 14:18
alpha-BHC
ug/L
ND
0.050
0.012
04/05/23 14:18
beta-BHC
ug/L
ND
0.050
0.049
04/05/23 14:18
Chlordane (Technical)
ug/L
ND
0.50
0.16
04/05/23 14:18
delta-BHC
ug/L
ND
0.050
0.014
04/05/23 14:18
Dieldrin
ug/L
ND
0.050
0.015
04/05/23 14:18
Endosulfan I
ug/L
ND
0.050
0.017
04/05/23 14:18
Endosulfan 11
ug/L
ND
0.050
0.016
04/05/23 14:18
Endosulfan sulfate
ug/L
ND
0.050
0.015
04/05/23 14:18
Endrin
ug/L
ND
0.050
0.018
04/05/23 14:18
Endrin aldehyde
ug/L
ND
0.050
0.016
04/05/23 14:18
gamma-BHC (Lindane)
ug/L
ND
0.050
0.012
04/05/23 14:18
Heptachlor
ug/L
ND
0.050
0.020
04/05/23 14:18
Heptachlor epoxide
ug/L
ND
0.050
0.028
04/05/23 14:18
Methoxychlor
ug/L
ND
0.15
0.042
04/05/23 14:18
Toxaphene
ug/L
ND
0.50
0.22
04/05/23 14:18
Decachlorobiphenyl (S)
%
111
10-200
04/05/23 14:18
Tetrachloro-m-xylene (S)
%
74
10-182
04/05/23 14:18
LABORATORY CONTROL SAMPLE:
3975522
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
4,4'-DDD
ug/L
0.25
0.33
131
50-178
4,4'-DDE
ug/L
0.25
0.30
121
43-164
4,4'-DDT
ug/L
0.25
0.33
132
23-198
Aldrin
ug/L
0.25
0.22
87
13-137
alpha-BHC
ug/L
0.25
0.22
87
32-161
beta-BHC
ug/L
0.25
0.26
105
54-180
delta-BHC
ug/L
0.25
0.25
100
42-169
Dieldrin
ug/L
0.25
0.29
114
42-173
Endosulfan I
ug/L
0.25
0.24
97
44-168
Endosulfan II
ug/L
0.25
0.25
100
45-176
Endosulfan sulfate
ug/L
0.25
0.28
110
48-178
Endrin
ug/L
0.25
0.33
130
46-178
Endrin aldehyde
ug/L
0.25
0.23
93
35-168
gamma-BHC (Lindane)
ug/L
0.25
0.23
93
38-162
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 84 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
LABORATORY CONTROL SAMPLE:
3975522
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Heptachlor
ug/L
0.25
0.25
101
25-153
Heptachlor epoxide
ug/L
0.25
0.24
97
43-170
Methoxychlor
ug/L
0.75
0.82
109
37-187
Decachlorobiphenyl (S)
%
128
10-200
Tetrachloro-m-xylene (S)
%
85
10-182
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
3975523
3975524
MS
MSD
92659555001
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
4,4'-DDD
ug/L
ND
0.45
0.45
0.76
0.76
168
168
13-200
0
30
4,4'-DDE
ug/L
ND
0.45
0.45
0.71
0.71
157
157
10-182
0
30
4,4'-DDT
ug/L
ND
0.45
0.45
0.79
0.79
175
175
10-200
0
30
Aldrin
ug/L
ND
0.45
0.45
0.53
0.53
117
117
10-161
0
30
alpha-BHC
ug/L
ND
0.45
0.45
0.55
0.55
121
121
10-186
0
30
beta-BHC
ug/L
ND
0.45
0.45
0.59
0.59
129
129
10-200
0
30
delta-BHC
ug/L
ND
0.45
0.45
0.59
0.59
130
130
11-199
0
30
Dieldrin
ug/L
ND
0.45
0.45
0.68
0.68
149
149
10-185
0
30
Endosulfan I
ug/L
ND
0.45
0.45
0.59
0.59
130
130
10-191
0
30
Endosulfan II
ug/L
ND
0.45
0.45
0.60
0.60
132
132
10-200
0
30
Endosulfan sulfate
ug/L
ND
0.45
0.45
0.66
0.66
144
144
17-199
0
30
Endrin
ug/L
ND
0.45
0.45
0.76
0.76
167
167
11-193
0
30
Endrin aldehyde
ug/L
ND
0.45
0.45
0.55
0.55
122
122
10-198
0
30
gamma-BHC (Lindane)
ug/L
ND
0.45
0.45
0.57
0.57
125
125
10-190
0
30
Heptachlor
ug/L
ND
0.45
0.45
0.59
0.59
131
131
13-166
0
30
Heptachlor epoxide
ug/L
ND
0.45
0.45
0.58
0.58
128
128
10-200
0
30
Methoxychlor
ug/L
ND
1.4
1.4
2.0
2.0
144
144
10-200
0
30
Decachlorobiphenyl (S)
%
130
130
10-200
Tetrachloro-m-xylene (S)
%
98
98
10-182
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 85 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 766271 Analysis Method: EPA 8082A
QC Batch Method: EPA 3510C Analysis Description: 8082 GCS PCB
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555007, 92659555008, 92659555009, 92659555010
METHOD BLANK: 3978865
Matrix:
Water
Associated Lab Samples:
92659555001, 92659555002, 92659555003, 92659555007, 92659555008, 92659555009,
92659555010
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
PCB-1016 (Aroclor 1016)
ug/L
ND
0.50
0.21
04/07/23 16:41
PCB-1221 (Aroclor 1221)
ug/L
ND
0.50
0.23
04/07/23 16:41
PCB-1232 (Aroclor 1232)
ug/L
ND
0.50
0.23
04/07/23 16:41
PCB-1242 (Aroclor 1242)
ug/L
ND
0.50
0.25
04/07/23 16:41
PCB-1248 (Aroclor 1248)
ug/L
ND
0.50
0.29
04/07/23 16:41
PCB-1254 (Aroclor 1254)
ug/L
ND
0.50
0.21
04/07/23 16:41
PCB-1260 (Aroclor 1260)
ug/L
ND
0.50
0.16
04/07/23 16:41
Decachlorobiphenyl (S)
%
102
10-193
04/07/23 16:41
LABORATORY CONTROL SAMPLE: 3978866
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
PCB-1016 (Aroclor 1016) ug/L 5 5.8 115 34-137
PCB-1260 (Aroclor 1260) ug/L 5 5.9 118 39-145
Decachlorobiphenyl (S) % 128 10-193
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3978867
3978868
MS
MSD
92660016001 Spike
Spike MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result
Result
% Rec
% Rec
Limits
RPD RPD Qual
PCB-1016 (Aroclor 1016)
ug/L ND 50
50 42.4
31.8
85
64
10-153
29 30
PCB-1260 (Aroclor 1260)
ug/L ND 50
50 34.7
25.7
69
51
10-156
30 30
Decachlorobiphenyl (S)
%
64
59
10-193
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 86 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 765346 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E Water APP9 RV MSSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555007, 92659555008, 92659555009, 92659555010
METHOD BLANK: 3973978 Matrix: Water
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555007, 92659555008, 92659555009, 92659555010
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,2,4,5-Tetrachlorobenzene
ug/L
ND
10.0
4.5
04/02/23 13:32
1,3,5-Trinitrobenzene
ug/L
ND
10.0
5.5
04/02/23 13:32
1,3-Dinitrobenzene
ug/L
ND
10.0
3.8
04/02/23 13:32
1,4-Naphthoquinone
ug/L
ND
5.0
4.4
04/02/23 13:32
1-Naphthalenamine
ug/L
ND
10.0
6.0
04/02/23 13:32
2,2'-Oxybis(1-chloropropane)
ug/L
ND
10.0
1.2
04/02/23 13:32
2,3,4,6-Tetrachlorophenol
ug/L
ND
10.0
1.5
04/02/23 13:32
2,4,5-Trichlorophenol
ug/L
ND
10.0
1.4
04/02/23 13:32
2,4,6-Trichlorophenol
ug/L
ND
10.0
1.6
04/02/23 13:32
2,4-Dichlorophenol
ug/L
ND
10.0
1.4
04/02/23 13:32
2,4-Dimethylphenol
ug/L
ND
10.0
1.7
04/02/23 13:32
2,4-Dinitrophenol
ug/L
ND
50.0
26.0
04/02/23 13:32
2,4-Dinitrotoluene
ug/L
ND
10.0
1.6
04/02/23 13:32
2,6-Dichlorophenol
ug/L
ND
10.0
4.2
04/02/23 13:32
2,6-Dinitrotoluene
ug/L
ND
10.0
1.7
04/02/23 13:32
2-Acetylaminofluorene
ug/L
ND
10.0
4.1
04/02/23 13:32
2-Chloronaphthalene
ug/L
ND
10.0
1.7
04/02/23 13:32
2-Chlorophenol
ug/L
ND
10.0
1.2
04/02/23 13:32
2-Methylnaphthalene
ug/L
ND
10.0
1.9
04/02/23 13:32
2-Methylphenol(o-Cresol)
ug/L
ND
10.0
1.9
04/02/23 13:32
2-Naphthalenamine
ug/L
ND
10.0
5.4
04/02/23 13:32
2-Nitroaniline
ug/L
ND
20.0
3.0
04/02/23 13:32
2-Nitrophenol
ug/L
ND
10.0
1.4
04/02/23 13:32
3&4-Methyl phenol (m&p Cresol)
ug/L
ND
10.0
1.2
04/02/23 13:32
3,3'-Dichlorobenzidine
ug/L
ND
20.0
8.1
04/02/23 13:32
3,3'-Dimethylbenzidine
ug/L
ND
50.0
31.1
04/02/23 13:32
3-Methylcholanthrene
ug/L
ND
10.0
3.7
04/02/23 13:32
3-Nitroaniline
ug/L
ND
20.0
3.8
04/02/23 13:32
4,6-Dinitro-2-methyl phenol
ug/L
ND
20.0
7.8
04/02/23 13:32
4-Aminobiphenyl
ug/L
ND
10.0
4.7
04/02/23 13:32
4-Bromophenylphenyl ether
ug/L
ND
10.0
1.8
04/02/23 13:32
4-ChIoro-3-methyl phenol
ug/L
ND
10.0
3.3
04/02/23 13:32
4-Chloroaniline
ug/L
ND
20.0
3.6
04/02/23 13:32
4-Chlorophenylphenyl ether
ug/L
ND
10.0
2.0
04/02/23 13:32
4-Nitroaniline
ug/L
ND
20.0
5.1
04/02/23 13:32
4-Nitrophenol
ug/L
ND
50.0
6.6
04/02/23 13:32
5-Nitro-o-toluidine
ug/L
ND
10.0
3.8
04/02/23 13:32
7,12-Dimethylbenz(a)anthracene
ug/L
ND
10.0
3.0
04/02/23 13:32
a,a-Dimethylphenylethylamine
ug/L
ND
100
62.0
04/02/23 13:32
Acenaphthene
ug/L
ND
10.0
2.0
04/02/23 13:32
IH
v2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 87 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
METHOD BLANK: 3973978 Matrix: Water
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555007, 92659555008, 92659555009, 92659555010
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Acenaphthylene
ug/L
ND
10.0
2.0
04/02/23 13:32
Acetophenone
ug/L
ND
10.0
1.5
04/02/23 13:32
Anthracene
ug/L
ND
10.0
2.3
04/02/23 13:32
Benzo(a)anthracene
ug/L
ND
10.0
2.7
04/02/23 13:32
Benzo(a)pyrene
ug/L
ND
10.0
2.8
04/02/23 13:32
Benzo(b)fluoranthene
ug/L
ND
10.0
2.6
04/02/23 13:32
Benzo(g,h,i)perylene
ug/L
ND
10.0
2.8
04/02/23 13:32
Benzo(k)fluoranthene
ug/L
ND
10.0
2.7
04/02/23 13:32
Benzyl alcohol
ug/L
ND
20.0
2.9
04/02/23 13:32
bis(2-Chloroethoxy)methane
ug/L
ND
10.0
1.8
04/02/23 13:32
bis(2-Chloroethyl) ether
ug/L
ND
10.0
1.9
04/02/23 13:32
bis(2-Ethylhexyl)phthalate
ug/L
ND
6.0
3.7
04/02/23 13:32
Butylbenzylphthalate
ug/L
ND
10.0
3.1
04/02/23 13:32
Chlorobenzilate
ug/L
ND
10.0
3.8
04/02/23 13:32
Chrysene
ug/L
ND
10.0
2.8
04/02/23 13:32
Di-n-butylphthalate
ug/L
ND
10.0
2.2
04/02/23 13:32
Di-n-octylphthalate
ug/L
ND
10.0
3.9
04/02/23 13:32
Diallate
ug/L
ND
10.0
3.4
04/02/23 13:32
Dibenz(a,h)anthracene
ug/L
ND
10.0
3.0
04/02/23 13:32
Dibenzofuran
ug/L
ND
10.0
2.1
04/02/23 13:32
Diethylphthalate
ug/L
ND
10.0
2.0
04/02/23 13:32
Dimethoate
ug/L
ND
10.0
3.7
04/02/23 13:32
Dimethylphthalate
ug/L
ND
10.0
2.1
04/02/23 13:32
Diphenylamine
ug/L
ND
10.0
3.0
04/02/23 13:32
Disulfoton
ug/L
ND
10.0
4.6
04/02/23 13:32
Ethyl methanesulfonate
ug/L
ND
20.0
3.0
04/02/23 13:32
Famphur
ug/L
ND
10.0
6.1
04/02/23 13:32
Fluoranthene
ug/L
ND
10.0
2.2
04/02/23 13:32
Fluorene
ug/L
ND
10.0
2.1
04/02/23 13:32
Hexachlorobenzene
ug/L
ND
10.0
2.2
04/02/23 13:32
Hexachlorocyclopentadiene
ug/L
ND
10.0
1.6
04/02/23 13:32
Hexachloroethane
ug/L
ND
10.0
1.4
04/02/23 13:32
Hexachloropropene
ug/L
ND
10.0
2.7
04/02/23 13:32
Indeno(1,2,3-cd)pyrene
ug/L
ND
10.0
2.9
04/02/23 13:32
Isodrin
ug/L
ND
10.0
2.8
04/02/23 13:32
Isophorone
ug/L
ND
10.0
1.7
04/02/23 13:32
Isosafrole
ug/L
ND
10.0
2.5
04/02/23 13:32
Kepone
ug/L
ND
20.0
14.1
04/02/23 13:32
Methapyrilene
ug/L
ND
50.0
17.0
04/02/23 13:32 IH,v1
Methyl methanesulfonate
ug/L
ND
5.0
3.1
04/02/23 13:32
Methyl parathion
ug/L
ND
10.0
3.7
04/02/23 13:32
N-Nitroso-di-n-butylamine
ug/L
ND
10.0
2.0
04/02/23 13:32
N-Nitroso-di-n-propylamine
ug/L
ND
10.0
1.3
04/02/23 13:32
N-Nitrosodiethylamine
ug/L
ND
10.0
2.3
04/02/23 13:32
N-Nitrosodimethylamine
ug/L
ND
10.0
1.9
04/02/23 13:32
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 88 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
METHOD BLANK: 3973978 Matrix: Water
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555007, 92659555008, 92659555009, 92659555010
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
N-Nitrosodiphenylamine
ug/L
ND
10.0
3.0
04/02/23 13:32
N-Nitrosomethylethylamine
ug/L
ND
10.0
7.5
04/02/23 13:32
N-Nitrosopiperidine
ug/L
ND
10.0
2.5
04/02/23 13:32
N-Nitrosopyrrolidine
ug/L
ND
10.0
3.1
04/02/23 13:32
Nitrobenzene
ug/L
ND
10.0
1.9
04/02/23 13:32
O,O,O-Triethylphosphorothioate
ug/L
ND
10.0
2.6
04/02/23 13:32
O-Toluidine
ug/L
ND
10.0
2.6
04/02/23 13:32
P-Dimethylaminoazobenzene
ug/L
ND
5.0
2.4
04/02/23 13:32 IL
p-Phenylenediamine
ug/L
ND
10.0
10.0
04/02/23 13:32
Parathion (Ethyl parathion)
ug/L
ND
10.0
3.9
04/02/23 13:32
Pentachlorobenzene
ug/L
ND
10.0
3.4
04/02/23 13:32
Pentachloronitrobenzene
ug/L
ND
10.0
3.3
04/02/23 13:32
Pentachlorophenol
ug/L
ND
20.0
3.8
04/02/23 13:32
Phenacetin
ug/L
ND
10.0
3.6
04/02/23 13:32
Phenanthrene
ug/L
ND
10.0
2.0
04/02/23 13:32
Phenol
ug/L
ND
10.0
1.4
04/02/23 13:32
Phorate
ug/L
ND
10.0
3.6
04/02/23 13:32
Pronamide
ug/L
ND
10.0
3.1
04/02/23 13:32
Pyrene
ug/L
ND
10.0
2.2
04/02/23 13:32
Safrole
ug/L
ND
10.0
2.3
04/02/23 13:32
Thionazin
ug/L
ND
10.0
2.9
04/02/23 13:32
2,4,6-Tribromophenol (S)
%
106
10-164
04/02/23 13:32
2-Fluorobiphenyl (S)
%
73
10-130
04/02/23 13:32
2-Fluorophenol(S)
%
68
10-130
04/02/23 13:32
Nitrobenzene-d5 (S)
%
92
10-138
04/02/23 13:32
Phenol-d6 (S)
%
55
10-130
04/02/23 13:32
Terphenyl-d14 (S)
%
101
19-191
04/02/23 13:32
LABORATORY CONTROL SAMPLE:
Parameter
3973979
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,2,4,5-Tetrachlorobenzene
ug/L
50
59.1
118
10-130
1,3,5-Trinitrobenzene
ug/L
50
59.6
119
55-200
1,3-Dinitrobenzene
ug/L
50
72.6
145
48-176
1,4-Naphthoquinone
ug/L
50
57.4
115
18-130
1-Naphthalenamine
ug/L
50
62.7
125
29-149
2,2'-Oxybis(1-chloropropane)
ug/L
50
49.0
98
21-135
2,3,4,6-Tetrachlorophenol
ug/L
50
62.8
126
39-157
2,4,5-Trichlorophenol
ug/L
50
63.0
126
38-147
2,4,6-Trichlorophenol
ug/L
50
61.7
123
34-142
2,4-Dichlorophenol
ug/L
50
60.0
120
36-136
2,4-Dimethylphenol
ug/L
50
93.2
186
38-134 L1
2,4-Dinitrophenol
ug/L
250
279
112
10-169
2,4-Dinitrotoluene
ug/L
50
58.8
118
44-154
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 89 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
LABORATORY CONTROL SAMPLE:
Parameter
3973979
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
2,6-Dichlorophenol
ug/L
50
68.8
138
37-145
2,6-Dinitrotoluene
ug/L
50
63.3
127
44-156
2-Acetylaminofluorene
ug/L
50
59.0
118
25-175
2-Chloronaphthalene
ug/L
50
56.3
113
25-130
2-Chlorophenol
ug/L
50
54.9
110
29-130
2-Methylnaphthalene
ug/L
50
52.2
104
23-130
2-Methylphenol(o-Cresol)
ug/L
50
54.2
108
31-130
2-Naphthalenamine
ug/L
50
67.2
134
34-147
2-Nitroaniline
ug/L
100
115
115
39-145
2-Nitrophenol
ug/L
50
62.2
124
29-142
3&4-Methyl phenol (m&p Cresol)
ug/L
50
50.7
101
30-130
3,3'-Dichlorobenzidine
ug/L
100
130
130
44-158
3,3'-Dimethylbenzidine
ug/L
100
195
195
38-2001H
3-Methylcholanthrene
ug/L
50
75.1
150
46-153
3-Nitroaniline
ug/L
100
121
121
45-152
4,6-Dinitro-2-methyl phenol
ug/L
100
130
130
39-158
4-Aminobiphenyl
ug/L
50
53.7
107
30-144
4-Bromophenylphenyl ether
ug/L
50
59.1
118
47-147
4-ChIoro-3-methyl phenol
ug/L
100
115
115
40-138
4-Chloroaniline
ug/L
100
108
108
35-130
4-Chlorophenylphenyl ether
ug/L
50
55.1
110
36-139
4-Nitroaniline
ug/L
100
115
115
46-157
4-Nitrophenol
ug/L
250
212
85
17-130
5-Nitro-o-toluidine
ug/L
50
77.6
155
50-182
7,12-Dimethylbenz(a)anthracene
ug/L
50
81.2
162
46-157 L1
a,a-Dimethylphenylethylamine
ug/L
50
ND
18
10-130 v3
Acenaphthene
ug/L
50
56.5
113
34-135
Acenaphthylene
ug/L
50
57.1
114
35-137
Acetophenone
ug/L
50
52.0
104
30-137
Anthracene
ug/L
50
53.7
107
47-146
Benzo(a)anthracene
ug/L
50
59.4
119
48-160
Benzo(a)pyrene
ug/L
50
58.8
118
47-165
Benzo(b)fluoranthene
ug/L
50
63.3
127
49-171
Benzo(g,h,i)perylene
ug/L
50
60.4
121
46-166
Benzo(k)fluoranthene
ug/L
50
58.4
117
55-162
Benzyl alcohol
ug/L
100
102
102
29-132
bis(2-Chloroethoxy)methane
ug/L
50
56.2
112
33-136
bis(2-Chloroethyl) ether
ug/L
50
53.6
107
30-142
bis(2-Ethylhexyl)phthalate
ug/L
50
63.5
127
46-173
Butylbenzylphthalate
ug/L
50
67.4
135
53-169
Chlorobenzilate
ug/L
50
76.9
154
43-155
Chrysene
ug/L
50
57.8
116
54-152
Di-n-butylphthalate
ug/L
50
58.4
117
49-161
Di-n-octylphthalate
ug/L
50
69.8
140
50-166
Diallate
ug/L
50
63.6
127
47-136
Dibenz(a,h)anthracene
ug/L
50
61.8
124
46-166
Dibenzofuran
ug/L
50
55.7
111
37-136
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 90 of 155

Pace Analytical Services, LLC
9800
lCtaac,Analyfical ® Kiney Ave. Suite 100
Huntersville, NC 28078
0788
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
LABORATORY CONTROL SAMPLE:
Parameter
3973979
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Diethylphthalate
ug/L
50
56.0
112
45-149
Dimethoate
ug/L
50
72.5
145
49-145
Dimethylphthalate
ug/L
50
56.3
113
43-145
Diphenylamine
ug/L
50
58.1
116
49-142
Disulfoton
ug/L
50
58.9
118
42-130
Ethyl methanesulfonate
ug/L
50
62.7
125
26-135
Famphur
ug/L
100
89.8
90
10-130
Fluoranthene
ug/L
50
57.4
115
50-153
Fluorene
ug/L
50
56.6
113
42-142
Hexachlorobenzene
ug/L
50
58.1
116
44-138
Hexachlorocyclopentadiene
ug/L
50
56.8
114
10-130
Hexachloroethane
ug/L
50
34.1
68
10-130
Hexachloropropene
ug/L
50
40.2
80
10-130
Indeno(1,2,3-cd)pyrene
ug/L
50
61.8
124
46-166
Isodrin
ug/L
50
62.1
124
48-141
Isophorone
ug/L
50
58.9
118
36-135
Isosafrole
ug/L
50
67.5
135
33-135
Kepone
ug/L
100
90.4
90
10-130
Methapyrilene
ug/L
50
17.OJ
34
10-185IH,v1
Methyl methanesulfonate
ug/L
50
60.9
122
21-130
Methyl parathion
ug/L
50
77.2
154
57-173
N-Nitroso-di-n-butylamine
ug/L
50
56.0
112
28-130
N-Nitroso-di-n-propylamine
ug/L
50
55.2
110
33-140
N-Nitrosodiethylamine
ug/L
50
67.2
134
27-141
N-Nitrosodimethylamine
ug/L
50
49.8
100
24-130
N-Nitrosodiphenylamine
ug/L
50
58.1
116
46-144
N-Nitrosomethylethylamine
ug/L
50
63.7
127
22-141
N-Nitrosopiperidine
ug/L
50
70.5
141
36-141
N-Nitrosopyrrolidine
ug/L
50
62.2
124
31-145
Nitrobenzene
ug/L
50
58.2
116
33-133
O,O,O-Triethylphosphorothioate
ug/L
50
63.4
127
30-152
O-Toluidine
ug/L
50
59.5
119
30-131
P-Dimethylaminoazobenzene
ug/L
50
35.9
72
23-130IL
p-Phenylenediamine
ug/L
ND
Parathion (Ethyl parathion)
ug/L
50
76.6
153
52-169
Pentachlorobenzene
ug/L
50
62.5
125
31-136
Pentachloronitrobenzene
ug/L
50
81.8
164
59-177
Pentachlorophenol
ug/L
100
128
128
21-163
Phenacetin
ug/L
50
77.5
155
52-159
Phenanthrene
ug/L
50
56.5
113
47-146
Phenol
ug/L
50
37.2
74
19-130
Phorate
ug/L
50
67.2
134
35-184
Pronamide
ug/L
50
75.5
151
53-155
Pyrene
ug/L
50
60.0
120
53-155
Safrole
ug/L
50
62.0
124
31-130
Thionazin
ug/L
50
65.1
130
46-148
2,4,6-Tribromophenol (S)
%
141
10-164
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 91 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
LABORATORY CONTROL SAMPLE:
3973979
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
2-Fluorobiphenyl (S)
%
111
10-130
2-Fluorophenol(S)
%
93
10-130
Nitrobenzene-d5 (S)
%
122
10-138
Phenol-d6 (S)
%
75
10-130
Terphenyl-d14 (S)
%
128
19-191
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
3974052
3974053
MS
MSD
92659555001
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result % Rec % Rec
Limits
RPD
RPD Qual
1,2,4,5-Tetrachlorobenzene
ug/L
ND
83.3
83.3
89.9
93.5
108
112
12-130
4
30
1,3,5-Trinitrobenzene
ug/L
ND
83.3
83.3
101
98.9
121
119
34-200
2
30
1,3-Dinitrobenzene
ug/L
ND
83.3
83.3
127
119
152
143
34-183
6
30
1,4-Naphthoquinone
ug/L
ND
83.3
83.3
104
115
125
138
14-136
10
30 M1
1-Naphthalenamine
ug/L
ND
83.3
83.3
107
91.3
128
110
10-173
15
30
2,2'-Oxybis(1-
ug/L
ND
83.3
83.3
86.0
80.8
103
97
11-143
6
30
chloropropane)
2,3,4,6-Tetrachlorophenol
ug/L
ND
83.3
83.3
107
99.9
128
120
10-180
7
30
2,4,5-Trichlorophenol
ug/L
ND
83.3
83.3
106
102
127
122
10-170
4
30
2,4,6-Trichlorophenol
ug/L
ND
83.3
83.3
104
100
125
120
10-166
4
30
2,4-Dichlorophenol
ug/L
ND
83.3
83.3
101
95.7
121
115
10-153
5
30
2,4-Dimethylphenol
ug/L
ND
83.3
83.3
158
149
190
179
20-147
6
30 MO
2,4-Dinitrophenol
ug/L
ND
417
417
484
468
116
112
10-172
3
30
2,4-Dinitrotoluene
ug/L
ND
83.3
83.3
102
96.0
123
115
30-164
6
30
2,6-Dichlorophenol
ug/L
ND
83.3
83.3
113
109
135
131
10-161
3
30
2,6-Dinitrotoluene
ug/L
ND
83.3
83.3
107
98.9
128
119
31-163
8
30
2-Acetylam inofl uorene
ug/L
ND
83.3
83.3
96.6
91.8
116
110
20-166
5
30
2-Chloronaphthalene
ug/L
ND
83.3
83.3
92.0
90.0
110
108
15-134
2
30
2-Chlorophenol
ug/L
ND
83.3
83.3
94.2
88.5
113
106
10-139
6
30
2-Methyl naphthalene
ug/L
ND
83.3
83.3
86.2
83.3
103
100
12-130
3
30
2-Methyl phenol(o-Cresol)
ug/L
ND
83.3
83.3
100
86.8
120
104
19-132
15
30
2-Naphthalenamine
ug/L
ND
83.3
83.3
100
68.1
121
82
10-164
38
30 R1
2-Nitroaniline
ug/L
ND
167
167
192
182
115
109
23-154
5
30
2-Nitrophenol
ug/L
ND
83.3
83.3
104
103
125
123
10-159
1
30
3&4-Methylphenol(m&p
ug/L
ND
83.3
83.3
96.4
80.5
116
97
13-136
18
30
Cresol)
3,3'-Dichlorobenzidine
ug/L
ND
167
167
210
195
126
117
10-178
7
30
3,3'-Dimethylbenzidine
ug/L
ND
167
167
282
106
169
63
10-200
91
30 IH,R1
3-Methylcholanthrene
ug/L
ND
83.3
83.3
121
115
146
138
36-158
6
30
3-Nitroaniline
ug/L
ND
167
167
206
190
123
114
20-166
8
30
4,6-Dinitro-2-methylphenol
ug/L
ND
167
167
216
213
129
128
10-187
1
30
4-Aminobiphenyl
ug/L
ND
83.3
83.3
84.4
70.1
101
84
10-181
19
30
4-Bromophenylphenyl ether
ug/L
ND
83.3
83.3
95.5
94.8
115
114
31-157
1
30
4-Chloro-3-methylphenol
ug/L
ND
167
167
198
181
119
108
27-146
9
30
4-Chloroaniline
ug/L
ND
167
167
179
164
107
98
13-143
9
30
4-Chlorophenylphenyl ether
ug/L
ND
83.3
83.3
92.3
87.7
111
105
23-149
5
30
Results presented
on this page are in the units
indicated by the
"Units" column except where
an alternate unit is presented to the right of the result.
REPORT
OF LABORATORY ANALYSIS
This report shall not be reproduced,
except
in full,
Date: 05/05/2023 12:39 PM
without
the written consent of Pace Analytical Services, LLC.
Page 92 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 3974052
3974053
MS
MSD
92659555001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
4-Nitroaniline
ug/L
ND
167
167
198
177
119
106
24-171
11
30
4-Nitrophenol
ug/L
ND
417
417
347
316
83
76
10-130
9
30
5-Nitro-o-toluidine
ug/L
ND
83.3
83.3
133
122
159
146
33-192
9
30
7,12-
ug/L
ND
83.3
83.3
136
131
163
157
36-161
4
30 MO
Dimethylbenz(a)anthracene
a,a-
ug/L
ND
83.3
83.3
ND
ND
0
0
10-180
30 M1,v2
Dimethylphenylethylamine
Acenaphthene
ug/L
ND
83.3
83.3
94.9
90.9
114
109
21-147
4
30
Acenaphthylene
ug/L
ND
83.3
83.3
95.7
91.6
115
110
19-150
4
30
Acetophenone
ug/L
ND
83.3
83.3
92.3
86.4
111
104
22-145
7
30
Anthracene
ug/L
ND
83.3
83.3
88.0
84.3
106
101
36-152
4
30
Benzo(a)anth race ne
ug/L
ND
83.3
83.3
98.5
92.9
118
111
42-163
6
30
Benzo(a)pyrene
ug/L
ND
83.3
83.3
96.4
91.7
116
110
40-169
5
30
Benzo(b)fluoranthene
ug/L
ND
83.3
83.3
104
103
125
123
40-177
1
30
Benzo(g,h,i)perylene
ug/L
ND
83.3
83.3
90.7
89.6
109
107
38-174
1
30
Benzo(k)fluoranthene
ug/L
ND
83.3
83.3
97.7
90.6
117
109
41-171
7
30
Benzyl alcohol
ug/L
ND
167
167
176
167
106
100
18-141
6
30
bis(2-
ug/L
ND
83.3
83.3
92.7
89.9
111
108
19-146
3
30
Chloroethoxy)methane
bis(2-Chloroethyl) ether
ug/L
ND
83.3
83.3
92.5
87.4
111
105
19-151
6
30
bis(2- Ethyl hexyl)phthalate
ug/L
ND
83.3
83.3
107
99.0
128
119
42-168
7
30
Butylbenzylphthalate
ug/L
ND
83.3
83.3
113
104
136
125
42-177
8
30
Chlorobenzilate
ug/L
ND
83.3
83.3
158
151
189
181
36-158
4
30 M1
Chrysene
ug/L
ND
83.3
83.3
95.3
90.9
114
109
43-159
5
30
Di-n-butylphthalate
ug/L
ND
83.3
83.3
98.0
90.7
118
109
42-160
8
30
Di-n-octylphthalate
ug/L
ND
83.3
83.3
113
102
136
122
42-171
11
30
Diallate
ug/L
ND
83.3
83.3
104
102
124
122
38-139
2
30
Dibenz(a,h)anthracene
ug/L
ND
83.3
83.3
93.9
91.6
113
110
40-171
3
30
Dibenzofuran
ug/L
ND
83.3
83.3
93.5
88.5
112
106
23-147
5
30
Diethylphthalate
ug/L
ND
83.3
83.3
98.3
89.4
118
107
33-157
10
30
Dimethoate
ug/L
ND
83.3
83.3
120
113
144
136
41-146
6
30
Dimethylphthalate
ug/L
ND
83.3
83.3
96.5
91.0
116
109
27-154
6
30
Diphenylamine
ug/L
ND
83.3
83.3
94.2
92.9
113
112
38-146
1
30
Disulfoton
ug/L
ND
83.3
83.3
97.6
92.1
117
111
39-130
6
30
Ethyl methanesulfonate
ug/L
ND
83.3
83.3
106
104
127
124
25-136
2
30
Famphur
ug/L
ND
167
167
172
186
103
112
10-130
8
30
Fluoranthene
ug/L
ND
83.3
83.3
93.8
86.6
113
104
42-157
8
30
Fluorene
ug/L
ND
83.3
83.3
96.0
90.4
115
109
25-155
6
30
Hexachlorobenzene
ug/L
ND
83.3
83.3
93.8
91.8
113
110
32-145
2
30
Hexachlorocyclopentadiene
ug/L
ND
83.3
83.3
92.3
94.1
111
113
10-130
2
30
Hexachloroethane
ug/L
ND
83.3
83.3
53.9
55.9
65
67
10-130
4
30
Hexachloropropene
ug/L
ND
83.3
83.3
52.3
61.5
63
74
10-130
16
30
Indeno(1,2,3-cd)pyrene
ug/L
ND
83.3
83.3
94.3
91.8
113
110
39-174
3
30
Isodrin
ug/L
ND
83.3
83.3
103
95.7
123
115
34-148
7
30
Isophorone
ug/L
ND
83.3
83.3
99.1
95.1
119
114
19-146
4
30
Isosafrole
ug/L
ND
83.3
83.3
110
110
132
132
25-139
1
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 93 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3974052
MS
92659555001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3974053
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
Kepone
ug/L
ND
167
167
165
187
99
112
10-130
13
30
Methapyrilene
ug/L
ND
83.3
83.3
ND
ND
31
17
10-200
30 IH,v1
Methyl methanesulfonate
ug/L
ND
83.3
83.3
104
99.1
125
119
22-130
5
30
Methyl parathion
ug/L
ND
83.3
83.3
129
121
155
145
48-174
7
30
N-Nitroso-di-n-butylamine
ug/L
ND
83.3
83.3
93.3
89.6
112
108
19-130
4
30
N-Nitroso-di-n-propylamine
ug/L
ND
83.3
83.3
100
92.8
120
111
20-150
8
30
N-Nitrosodiethylamine
ug/L
ND
83.3
83.3
113
115
135
138
27-140
2
30
N-Nitrosodimethylamine
ug/L
ND
83.3
83.3
83.3
78.6
100
94
13-130
6
30
N-Nitrosodiphenylamine
ug/L
ND
83.3
83.3
94.2
92.9
113
112
33-149
1
30
N-Nitrosomethylethylamine
ug/L
ND
83.3
83.3
106
103
127
124
22-144
3
30
N-Nitrosopiperidine
ug/L
ND
83.3
83.3
119
115
143
138
31-144
4
30
N-Nitrosopyrrolidine
ug/L
ND
83.3
83.3
118
110
142
132
27-146
7
30
Nitrobenzene
ug/L
ND
83.3
83.3
93.7
92.6
112
111
19-145
1
30
0,0,0-
ug/L
ND
83.3
83.3
96.5
101
116
121
25-138
4
30
Triethylphosphorothioate
O-Toluidine
ug/L
ND
83.3
83.3
98.4
81.1
118
97
24-133
19
30
P-
ug/L
ND
83.3
83.3
61.1
59.0
73
71
17-130
3
30 IL
Dimethylaminoazobenzene
p-Phenylenediamine
ug/L
ND
ND
ND
30
Parathion (Ethyl parathion)
ug/L
ND
83.3
83.3
132
120
158
144
46-168
10
30
Pentachlorobenzene
ug/L
ND
83.3
83.3
104
100
124
120
28-140
4
30
Pentachloronitrobenzene
ug/L
ND
83.3
83.3
136
131
164
157
46-177
4
30
Pentachlorophenol
ug/L
ND
167
167
206
202
124
121
10-188
2
30
Phenacetin
ug/L
ND
83.3
83.3
129
122
155
146
41-167
6
30
Phenanthrene
ug/L
ND
83.3
83.3
92.9
88.5
111
106
38-150
5
30
Phenol
ug/L
ND
83.3
83.3
68.0
56.7
82
68
10-130
18
30
Phorate
ug/L
ND
83.3
83.3
112
108
134
129
36-176
4
30
Pronamide
ug/L
ND
83.3
83.3
127
118
152
142
43-159
7
30
Pyrene
ug/L
ND
83.3
83.3
101
99.4
121
119
42-163
1
30
Safrole
ug/L
ND
83.3
83.3
98.8
98.9
119
119
26-134
0
30
Thionazin
ug/L
ND
83.3
83.3
115
106
138
127
37-152
9
30
2,4,6-Tribromophenol (S)
%
127
128
10-164
2-Fluorobiphenyl (S)
%
99
105
10-130
2-Fluorophenol (S)
%
82
81
10-130
Nitrobenzene-d5 (S)
%
108
111
10-138
Phenol-d6 (S)
%
73
64
10-130
Terphenyl-d14 (S)
%
117
119
19-191
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 94 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 766385 Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659555001, 92659555006
METHOD BLANK: 3979186 Matrix: Water
Associated Lab Samples: 92659555001, 92659555006
Blank Reporting
Parameter Units Result Limit
Alkalinity, Total as CaCO3 ug/L ND 5000
LABORATORY CONTROL SAMPLE: 3979187
Spike LCS
Parameter Units Conc. Result
Alkalinity, Total as CaCO3 ug/L 50000 51400
MDL Analyzed Qualifiers
5000 04/06/2317:11
LCS % Rec
% Rec Limits Qualifiers
103 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3979189 3979190
MS MSD
92659639004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L 163000 50000 50000 218000 222000 110 117 80-120 2 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3979191 3979192
MS MSD
92659666001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L 96700 50000 50000 154000 155000 114 116 80-120 1 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 95 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 766839 Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659555002, 92659555003
METHOD BLANK: 3982054 Matrix: Water
Associated Lab Samples: 92659555002, 92659555003
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Alkalinity, Total as CaCO3 ug/L ND 5000 5000 04/07/23 23:42
LABORATORY CONTROL SAMPLE: 3982055
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 ug/L 50000 51500 103 80-120
LABORATORY CONTROL SAMPLE: 3982056
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 ug/L 50000 52600 105 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3982061 3982062
MS MSD
92661090002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L 48.2 mg/L 50000 50000 104000 106000 113 116 80-120 2 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 96 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 765059 Analysis Method: SM 4500-S2D-2011
QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555007, 92659555008, 92659555009, 92659555010
METHOD BLANK: 3972639 Matrix: Water
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555007, 92659555008, 92659555009, 92659555010
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Sulfide ug/L ND 100 22.0 03/31/23 02:35
LABORATORY CONTROL SAMPLE: 3972640
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide ug/L 500 559 112 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3972641 3972642
MS MSD
92659613001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide ug/L ND 500 500 550 570 108 112 80-120 4 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3972643 3972644
MS MSD
92659555010 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide ug/L ND 500 500 540 567 108 113 80-120 5 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 97 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 764747 Analysis Method: SM 521 OB-2016
QC Batch Method: SM 521OB-2016 Analysis Description: 5210E BOD, 5 day
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659555001, 92659555002
METHOD BLANK: 3971090 Matrix: Water
Associated Lab Samples: 92659555001, 92659555002
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
BOD, 5 day ug/L ND 2000 2000 04/04/23 02:51
LABORATORY CONTROL SAMPLE:
3971092
Spike
LCS LCS % Rec
Parameter
Units
Conc.
Result % Rec Limits Qualifiers
BOD, 5 day
ug/L
198000
196000 99 84.6-115
SAMPLE DUPLICATE: 3971093
92659354001
Dup Max
Parameter
Units
Result
Result RPD RPD Qualifiers
BOD, 5 day
ug/L
27.2 mg/L
30000 10 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 98 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 765055 Analysis Method: SM 521 OB-2016
QC Batch Method: SM 521OB-2016 Analysis Description: 5210E BOD, 5 day
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659555003, 92659555006
METHOD BLANK: 3972624 Matrix: Water
Associated Lab Samples: 92659555003, 92659555006
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
BOD, 5 day ug/L ND 2000 2000 04/05/23 01:20
LABORATORY CONTROL SAMPLE:
3972627
Spike
LCS LCS % Rec
Parameter
Units
Conc.
Result % Rec Limits Qualifiers
BOD, 5 day
ug/L
198000
198000 100 84.6-115
SAMPLE DUPLICATE: 3972628
92659508001
Dup Max
Parameter
Units
Result
Result RPD RPD Qualifiers
BOD, 5 day
ug/L
703 mg/L
745000 6 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 99 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 764738 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659555001, 92659555002
METHOD BLANK: 3971058 Matrix: Water
Associated Lab Samples: 92659555001, 92659555002
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Sulfate ug/L ND 1000 500 03/29/23 21:32
LABORATORY CONTROL SAMPLE: 3971059
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfate ug/L 50000 50700 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3971060 3971061
MS MSD
92659555002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate ug/L 575J 50000 50000 51500 52600 102 104 90-110 2 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 100 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 765128 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659555003, 92659555006
METHOD BLANK: 3972863 Matrix: Water
Associated Lab Samples: 92659555003, 92659555006
Blank Reporting
Parameter Units Result Limit
Sulfate ug/L ND 1000
LABORATORY CONTROL SAMPLE: 3972864
Spike LCS
Parameter Units Conc. Result
Sulfate ug/L 50000 52400
MDL Analyzed Qualifiers
500 03/31 /23 21:12
LCS % Rec
% Rec Limits Qualifiers
105 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3972865 3972866
MS MSD
92659779003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate ug/L 1.0 mg/L 50000 50000 53100 53400 104 105 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3972867 3972868
MS MSD
92659639002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate ug/L 47700 50000 50000 99900 95300 104 95 90-110 5 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 101 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 764752 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659555001, 92659555002
METHOD BLANK: 3971101 Matrix: Water
Associated Lab Samples: 92659555001, 92659555002
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Nitrogen, Nitrate ug/L ND 40.0 10.0 03/30/23 01:40
LABORATORY CONTROL SAMPLE: 3971102
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate ug/L 1500 1440 96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3971103 3971104
MS MSD
92659364001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate ug/L 0.088 1500 1500 1850 1880 118 120 90-110 2 10
mg/L
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3971105 3971106
MS MSD
92659562003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate ug/L 10 mg/L 1500 1500 11400 11400 93 95 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 102 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 765067 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659555003, 92659555006
METHOD BLANK: 3972667 Matrix: Water
Associated Lab Samples: 92659555003, 92659555006
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Nitrogen, Nitrate ug/L ND 40.0 10.0 03/31/23 03:52
LABORATORY CONTROL SAMPLE: 3972668
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate ug/L 1500 1440 96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3972669 3972670
MS MSD
92659555006 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate ug/L 5640 1500 1500 7280 7170 110 102 90-110 2 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3972671 3972672
MS MSD
92659750003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate ug/L ND 1500 1500 1570 1550 105 103 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 103 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 764939 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555006
METHOD BLANK: 3971958 Matrix: Water
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555006
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Chloride ug/L ND 1000 500 03/30/2319:29
LABORATORY CONTROL SAMPLE: 3971959
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chloride ug/L 20000 20600 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3971960 3971961
MS MSD
92659140001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride ug/L 108 mg/L 10000 10000 118000 116000 102 85 90-110 1 10 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3971962 3971963
MS MSD
92658702001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride ug/L 3570 mg/L 10000 10000 3500000 3490000 -731 -743 90-110 0 10 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Page 104 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 765550 Analysis Method: SM 4500-CN-E-2016
QC Batch Method: SM 4500-CN-E-2016 Analysis Description: 450OCNE Cyanide, Total
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555007, 92659555008, 92659555009, 92659555010
METHOD BLANK: 3975100 Matrix: Water
Associated Lab Samples: 92659555001, 92659555002, 92659555003, 92659555007, 92659555008, 92659555009, 92659555010
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Cyanide ug/L ND 8.0 6.0 04/03/23 21:49
LABORATORY CONTROL SAMPLE: 3975101
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Cyanide ug/L 100 103 103 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3975102 3975103
MS MSD
92659555001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Cyanide ug/L ND 100 100 97.8 102 98 102 80-120 4 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3975104 3975105
MS MSD
92659555002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Cyanide ug/L ND 100 100 89.7 87.6 89 87 80-120 2 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 105 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 765448 Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659555001, 92659555002, 92659555003
METHOD BLANK: 3974291 Matrix: Water
Associated Lab Samples: 92659555001, 92659555002, 92659555003
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Chemical Oxygen Demand ug/L ND 25000 12500 04/03/23 15:03
LABORATORY CONTROL SAMPLE: 3974292
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chemical Oxygen Demand ug/L 750000 766000 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3974293 3974294
MS MSD
92659072001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand ug/L 43.1 mg/L 100000 100000 149000 149000 106 106 90-110 0 3
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3974295 3974296
MS MSD
92659072002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand ug/L 294 mg/L 100000 100000 393000 393000 99 99 90-110 0 3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 106 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 766594 Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659555006
METHOD BLANK: 3980733 Matrix: Water
Associated Lab Samples: 92659555006
Blank Reporting
Parameter Units Result Limit
Chemical Oxygen Demand ug/L ND 25000
LABORATORY CONTROL SAMPLE: 3980734
Spike LCS
Parameter Units Conc. Result
Chemical Oxygen Demand ug/L 750000 766000
MDL Analyzed Qualifiers
12500 04/07/23 05:16
LCS % Rec
% Rec Limits Qualifiers
102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3980735 3980736
MS MSD
92659774037 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand ug/L ND 100000 100000 132000 132000 122 122 90-110 0 3 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3980737 3980738
MS MSD
92660304003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand ug/L 37.1 mg/L 100000 100000 144000 152000 107 114 90-110 5 3 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 107 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 765462 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659555001, 92659555002, 92659555003
METHOD BLANK: 3974423 Matrix: Water
Associated Lab Samples: 92659555001, 92659555002, 92659555003
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Organic Carbon ug/L ND 1000 500 04/03/23 14:27
LABORATORY CONTROL SAMPLE: 3974425
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Organic Carbon ug/L 25000 24100 97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3974426 3974427
MS MSD
92659672001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon ug/L 1.0 mg/L 25000 25000 24500 24300 94 93 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3974428 3974429
MS MSD
92659545005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon ug/L ND 25000 25000 24900 24500 97 95 90-110 2 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 108 of 155

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
QC Batch: 766460 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659555006
METHOD BLANK: 3979774
Associated Lab Samples: 92659555006
Parameter Units
Total Organic Carbon ug/L
LABORATORY CONTROL SAMPLE: 3979775
Parameter Units
Total Organic Carbon ug/L
Matrix: Water
Blank Reporting
Result Limit
ND 1000
Spike LCS
Conc. Result
25000 24100
MDL Analyzed Qualifiers
500 04/06/2313:55
LCS % Rec
% Rec Limits Qualifiers
96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3979776 3979777
MS MSD
92660161001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon ug/L ND 25000 25000 23600 23400 93 92 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3979778 3979779
MS MSD
92659645001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon ug/L 2.3 mg/L 25000 25000 25500 25700 92 93 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM without the written consent of Pace Analytical Services, LLC.
Page 109 of 155

Pace Analytical Services, LLC
9800
lCtaac,Analyfical ® Kiney Ave. Suite 100
Huntersville, NC 28078
0788
www.pacelabs.com [phone]
QUALIFIERS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
WORKORDER QUALIFIERS
WO: 92659555
[1]
ANALYTE QUALIFIERS
B Analyte was detected in the associated method blank.
B2 Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated
for the dilution using the most amount of sample.
C8 Result may be biased high due to carryover from previously analyzed sample.
H1 Analysis conducted outside the EPA method holding time.
H2 Extraction or preparation conducted outside EPA method holding time.
IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
IL This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be
considered an estimated value.
J Analyte detected below the reporting limit, therefore result is an estimate. This qualifier is also used for all TICs.
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services, LLC
ceAnalytrcal ® 9800 Kiney Ave. Suite 100
Huntersville, NC 28078078
www.pacelabs.com [phone]
QUALIFIERS
Project: GM1.003 BUTNER LANDFILL
Pace Project No.: 92659555
ANALYTE QUALIFIERS
L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
MS Analyte recovery in the matrix spike was outside QC limits for one or more of the constituent analytes used in the
calculated result.
P9 RPD between the primary and confirmatory analysis exceeded 40%.
R1 RPD value was outside control limits.
S3 Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
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lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
GM1.003 BUTNER LANDFILL
92659555
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92659555001
MWAR
8151A
2034529
EPA 8151A
2034529
92659555002
MW-211
8151A
2034529
EPA 8151A
2034529
92659555003
MW-311
8151A
2034529
EPA 8151A
2034529
92659555007
MW-4
8151A
2034529
EPA 8151A
2034529
92659555008
MW-5
8151A
2034529
EPA 8151A
2034529
92659555009
MW-6
8151A
2034529
EPA 8151A
2034529
92659555010
FIELD BLANK
8151A
2034529
EPA 8151A
2034529
92659555001
MWA R
EPA 3510C
765668
EPA 8081 B
765998
92659555002
MW-2R
EPA 3510C
765668
EPA 8081 B
765998
92659555003
MW-3R
EPA 3510C
765668
EPA 8081 B
765998
92659555007
MW-4
EPA 3510C
765668
EPA 8081 B
765998
92659555008
MW-5
EPA 3510C
765668
EPA 8081 B
765998
92659555009
MW-6
EPA 3510C
765668
EPA 8081 B
765998
92659555010
FIELD BLANK
EPA 3510C
765668
EPA 8081 B
765998
92659555001
MWA R
EPA 3510C
766271
EPA 8082A
766692
92659555002
MW-2R
EPA 3510C
766271
EPA 8082A
766692
92659555003
MW-3R
EPA 3510C
766271
EPA 8082A
766692
92659555007
MW-4
EPA 3510C
766271
EPA 8082A
766692
92659555008
MW-5
EPA 3510C
766271
EPA 8082A
766692
92659555009
MW-6
EPA 3510C
766271
EPA 8082A
766692
92659555010
FIELD BLANK
EPA 3510C
766271
EPA 8082A
766692
92659555001
MWA R
RSK 175 Modified
765201
92659555002
MW-2R
RSK 175 Modified
765201
92659555003
MW-3R
RSK 175 Modified
765201
92659555006
NES-1
RSK 175 Modified
765201
92659555001
MWA R
3015
2034081
EPA6010D
2034081
92659555002
MW-2R
3015
2034081
EPA6010D
2034081
92659555003
MW-311
3015
2034081
EPA6010D
2034081
92659555004
SW-1
3015
2034081
EPA6010D
2034081
92659555005
SW-2
3015
2034081
EPA6010D
2034081
92659555006
NES-1
3015
2034081
EPA6010D
2034081
92659555007
MW-4
3015
2034081
EPA6010D
2034081
92659555008
MW-5
3015
2034081
EPA6010D
2034081
92659555009
MW-6
3015
2034081
EPA6010D
2034081
92659555010
FIELD BLANK
3015
2034081
EPA6010D
2034081
92659555001
MWA R
3015
2034089
EPA 6020B
2034089
92659555002
MW-211
3015
2035514
EPA 6020B
2035514
92659555003
MW-3R
3015
2034089
EPA 6020B
2034089
92659555004
SW-1
3015
2034089
EPA 6020B
2034089
92659555005
SW-2
3015
2034089
EPA 6020B
2034089
92659555007
MW-4
3015
2034089
EPA 6020B
2034089
92659555008
MW-5
3015
2034089
EPA 6020B
2034089
92659555009
MW-6
3015
2034089
EPA 6020B
2034089
92659555010
FIELD BLANK
3015
2034089
EPA 6020B
2034089
92659555001
MWA R
7470A
2033921
EPA 7470A
2033921
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except
in full,
Date: 05/05/2023 12:39 PM
without the written consent of Pace Analytical Services, LLC.
Page 112 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
GM1.003 BUTNER LANDFILL
92659555
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92659555002
MW-211
7470A
2033921
EPA 7470A
2033921
92659555003
MW-311
7470A
2033921
EPA 7470A
2033921
92659555007
MW-4
7470A
2033921
EPA 7470A
2033921
92659555008
MW-5
7470A
2033921
EPA 7470A
2033921
92659555009
MW-6
7470A
2033921
EPA 7470A
2033921
92659555010
FIELD BLANK
7470A
2033921
EPA 7470A
2033921
92659555001
MWA R
EPA 3510C
765346
EPA 8270E
765383
92659555002
MW-2R
EPA 3510C
765346
EPA 8270E
765383
92659555003
MW-3R
EPA 3510C
765346
EPA 8270E
765383
92659555007
MW-4
EPA 3510C
765346
EPA 8270E
765383
92659555008
MW-5
EPA 3510C
765346
EPA 8270E
765383
92659555009
MW-6
EPA 3510C
765346
EPA 8270E
765383
92659555010
FIELD BLANK
EPA 3510C
765346
EPA 8270E
765383
92659555004
SW-1
EPA 8260D
764919
92659555005
SW-2
EPA 8260D
764919
92659555006
NES-1
EPA 8260D
764931
92659555001
MWA R
EPA 8260D Mod.
765280
92659555002
MW-2R
EPA 8260D Mod.
765583
92659555003
MW-3R
EPA 8260D Mod.
765280
92659555004
SW-1
EPA 8260D Mod.
765280
92659555005
SW-2
EPA 8260D Mod.
765280
92659555006
NES-1
EPA 8260D Mod.
765280
92659555007
MW-4
EPA 8260D Mod.
765280
92659555008
MW-5
EPA 8260D Mod.
765280
92659555009
MW-6
EPA 8260D Mod.
765280
92659555010
FIELD BLANK
EPA 8260D Mod.
765280
92659555001
MWA R
EPA 8260D
765038
92659555002
MW-2R
EPA 8260D
765038
92659555003
MW-3R
EPA 8260D
765038
92659555007
MW-4
EPA 8260D
765038
92659555008
MW-5
EPA 8260D
765038
92659555009
MW-6
EPA 8260D
765038
92659555010
FIELD BLANK
EPA 8260D
765038
92659555011
TB
EPA 8260D
765038
92659555004
SW-1
SM2340B
2034081
SM2340-97
2034081
92659555005
SW-2
SM2340B
2034081
SM2340-97
2034081
92659555001
MWA R
SM 2320E-2011
766385
92659555002
MW-211
SM 2320B-2011
766839
92659555003
MW-311
SM 2320B-2011
766839
92659555006
NES-1
SM 2320E-2011
766385
92659555001
MWAR
SM 4500-S2D-2011
765059
92659555002
MW-2R
SM 4500-S2D-2011
765059
92659555003
MW-3R
SM 4500-S2D-2011
765059
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/05/2023 12:39 PM
without the written consent of Pace Analytical Services, LLC.
Page 113 of 155

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
GM1.003 BUTNER LANDFILL
92659555
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92659555007
MW-4
SM 4500-S2D-2011
765059
92659555008
MW-5
SM 4500-S2D-2011
765059
92659555009
MW-6
SM 4500-S2D-2011
765059
92659555010
FIELD BLANK
SM 4500-S2D-2011
765059
92659555001
MW-1R
SM 5210B-2016
764747
SM
5210B-2016
764769
92659555002
MW-2R
SM 5210B-2016
764747
SM
5210B-2016
764769
92659555003
MW-311
SM 5210B-2016
765055
SM
5210B-2016
765072
92659555006
NES-1
SM 5210E-2016
765055
SM
5210B-2016
765072
92659555001
MWA R
EPA 300.0 Rev 2.1 1993
764738
92659555002
MW-2R
EPA 300.0 Rev 2.1 1993
764738
92659555003
MW-311
EPA 300.0 Rev 2.1 1993
765128
92659555006
NES-1
EPA 300.0 Rev 2.1 1993
765128
92659555001
MWA R
EPA 353.2 Rev 2.0 1993
764752
92659555002
MW-2R
EPA 353.2 Rev 2.0 1993
764752
92659555003
MW-311
EPA 353.2 Rev 2.0 1993
765067
92659555006
NES-1
EPA 353.2 Rev 2.0 1993
765067
92659555001
MWA R
SM 4500-CI-E-2011
764939
92659555002
MW-2R
SM 4500-CI-E-2011
764939
92659555003
MW-3R
SM 4500-CI-E-2011
764939
92659555006
NES-1
SM 4500-CI-E-2011
764939
92659555001
MWA R
SM 4500-CN-E-2016
765550
SM
4500-CN-E-2016
765649
92659555002
MW-2R
SM 4500-CN-E-2016
765550
SM
4500-CN-E-2016
765649
92659555003
MW-3R
SM 4500-CN-E-2016
765550
SM
4500-CN-E-2016
765649
92659555007
MW-4
SM 4500-CN-E-2016
765550
SM
4500-CN-E-2016
765649
92659555008
MW-5
SM 4500-CN-E-2016
765550
SM
4500-CN-E-2016
765649
92659555009
MW-6
SM 4500-CN-E-2016
765550
SM
4500-CN-E-2016
765649
92659555010
FIELD BLANK
SM 4500-CN-E-2016
765550
SM
4500-CN-E-2016
765649
92659555001
MWA R
SM 5220D-2011
765448
SM
5220D-2011
765568
92659555002
MW-2R
SM 5220D-2011
765448
SM
5220D-2011
765568
92659555003
MW-3R
SM 5220D-2011
765448
SM
5220D-2011
765568
92659555006
NES-1
SM 5220D-2011
766594
SM
5220D-2011
766608
92659555001
MWA R
SM 5310E-2014
765462
92659555002
MW-2R
SM 5310B-2014
765462
92659555003
MW-3R
SM 5310B-2014
765462
92659555006
NES-1
SM 5310E-2014
766460
Date: 05/05/2023 12:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 114 of 155

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DU —Title., ENV-FRM-HUN1-0083 02 Sawplo Condition Upon Rocolpt
Effective Date: 11/14/2022 8:18:30 AM
*Check mark top half of box If pH and/or dechlorination Is verlfied and Project if
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❑C11_TiEle: ENV-FRM-HUN1.0083 02 Sample Condition Upcm Rerelpt
Effootivo Date; 11/14/2022 8:18:30 AM
*Check mark top half of box if pH and/or dechlorination is verified and
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DClUltle: ENV-FRM-HUN1-0083 v02 -Sainple Conclitlon Upoti Receipt
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Effective Date: 11/14/2022 8;183D AM
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Page 124 of 155

DC# Title: ENV-FRM-HUN1-0083 02 Sample Condition Upon Receipt
I -lace,
Effective Date: 11/14/2022 8:18:30 AM
*Check mark top half of box If pH and/or dechlorination Is verified and
within the acceptance range for preservation samples.
Exceptions: VOA, Coliform, TOC, Oil an(] Grease, D80/8015 (waled DOC, Mfg
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49ace' DC# Title: ENV•FRM-HUN1-0083 v02 Sample Condition Upon Receipt
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Effective Date:11/14/2022 8:18:30 AM
*Check mark top half of box if pH and/or dechlorination is verified and Project 4
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Page 127 of 155

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Page 128 of 155

�—aCMnalyfical"
r
Sam le Receiving Non -Conformance Form (NCF) _
1E iated yDate: 30(3 Affix WorkorderlLogin Label Here or List Pace
Client; r Workorder Number or MTJL Log -In Number
f 4or->?— -f� k f'1
cjC7 Here
1. If Chain -of -Custody (COC) is not received: contact client and it necessary, fill out a COC and indicate that it was filled arrt by
lab personnel. Note issues on this NCI=.
2. If COC is incomplete, clleck applicable Issues below and acid details where appropriate:
Collection date/lime missing or
Analyses or analytos: trussing or
Samples listed on COC do riot match samples
incorrect
clarification needed
received (missing, addilional, etc.
Sample IDs on COC do not
match sample inbels
Required trip blanks were not received
Re aired si natures are missing
Comments/Details/Other Issues not listed above:
3. Sample intectrity issues: check applicable issues below and acid details where appropriate.
Samples: Condilion needs to be brought to
Samples. Past bolding tune
lah ersonnel's attention details below
Presarvation.Inipioper
Temperature: not within acceptance criteria (typically
Samples: Not field filtered
Containers: Broken or compromised
O-FC
Samples: Insufficient volume
received
Containers: Incorrect
Tem eratkire: Samples arrived frozen
Samples: Cooler damaged or
Custody Seals: Missing or compromised on
corn ronised
samples, trip blanks or coolers
Vials received with improper Beads ace
Samples: contain chlorine or
sulfides
Packing Material: insufficient/lm ro er
Mier:
Comments/Detalls:
D �-e C 2 o, p r o wr c � C� L � ' cJ a P c ►� r n � _ � yr s
4, If Samples not preserved properly and Sample Receiving adjusts pH, add detalls below:
Sample ID:
Date/Time:
AniounUtype pros added:
Preserved by:
Initial and Final pli:
Lot#of Ares added:
Sample ID:
DatefTime:
Amount/type pres added:
Preserved by
Initial and Final pi I:
1 Lot # of pres added:
Sample ID:
DatefTime:
Amount/type pres added:
1
Preserved by:
Initial and Final )11:
Lot #of pres added:
5. Client Contact: if client is contacted for anv issue listed a
PM initials: Dateffime:
Client Comments/Instructions:
fill in details below:
F-ALL-C-011-rev.00, 05Ju12018
Page 129 of 155

Ace, DC# Title: ENV-ERM-HUN1-0083 02—Sample Condition Upon Receipt
,Itc,.hlrcPc
Effoctive Date: 11/14/2022 8:18:30 AM
*Check mark top half of box if pH and/or dechlorination is verified and Project 4
within the acceptance range for preservation samples.
Exceptlons: VOA, ColiforrtL TOC, Oil and Grease, DRO/8015 (water) 00C, LLlig
*Bottom half of box Is to list number of bottles
** *Check all unpreserved Nitrates for chlorine
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Note: WhCncveVthere$54di5C1ePdFKV0lfecting North Carolina compliance samplvs, acopy of this form will he!enl la ti%e Nod hCarolira DFNR62rtif1cafion Office (f_e•
Out of hold, incorrect prmCrvd€ive, nut of tornp, incorrect containers.
NVvi,
Page 130 of 155

�AnalyticalTM
www.pacelabs.com
Report Prepared for:
Taylor Cannon
PACE Charlotte
9800 Kincey Ave.
Huntersville NC 28078
REPORT OF
LABORATORY
ANALYSIS FOR
TCDD
Report Prepared Date:
May 5, 2023
Pace Analytical Services, LLC.
1700 Elm Street
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
Report Information:
PaceProject#:10650068
Sample Receipt Date: 04/20/2023
Client Project #: 92659555
Client Sub PO #: N/A
State Cert #: 530
Invoicing & Reporting Options:
The report provided has been invoiced as a Level 2
2,3,7,8-TCDD Report. If an upgrade of this report
package is requested, an additional charge may be
applied.
Please review the attached invoice for accuracy and
forward any questions to Isaac Johnson, your Pace
Project Manager.
This report has been reviewed by:
%M'G
May 05, 2023
Isaac Johnson, Project Manager
[phone]
[phone] (fax)
[e-mail]
Report of Laboratory Analysis
Thisreportshouldnotbereproduced,exceptinfull,
withoutthewrittenconsentotPaceAnalyticalServices,Inc.
The results reIate onIytothesamp lesincluded inthis report.
Page 131 of 155
Report No ..... 10650068_1613BTCDD_L2_R1_dfr Revision 1 Page 1 of 25

aceAnalytical
DISCUSSION
Pace Analytical Services, LLC.
1700 Elm Street
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
This report presents the results from the analyses performed on seven samples
submitted by a representative of Pace Analytical Services, LLC. The samples were
analyzed for the presence or absence of 2,3,7,8-tetrachlorodibenzo-p-dioxin
(2,3,7,8-TCDD) using USEPA Method 1613B. This report was revised to provide
statistically -derived method detection limits (MDLs) that were adjusted for sample
extraction amount.
The isotopically -labeled TCDD internal standard in the sample extracts was recovered
at 50-79%. All of the labeled standard recoveries obtained for this project were within
the target ranges specified in Method 1613B. Also, since the quantification of the native
TCDD was based on isotope dilution, the data were automatically corrected for
recovery and accurate values were obtained. In cases where the estimated detection
limits (EDLs) were above the MDLs, the EDLs were provided and flagged "A".
A laboratory method blank was prepared and analyzed with each sample batch as part
of our routine quality control procedures. The results show the blanks to be free of
2,3,7,8-TCDD at the reporting limits.
Laboratory spike samples were also prepared using clean reference matrix that had
been fortified with native standard material. The results show that the spiked native
TCDD was recovered at 103-111 % with relative percent differences of 0.9-1.0%. These
results were within the target ranges for the method. Matrix spikes were not prepared
with the extraction batches.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
withoutthe written consentof Pace Analytical Services, Inc. Page 132 of 155
Report No ..... 10650068_1613BTCDD_L2_R1_dfr Revision 1 Page 2 of 25

TM
Minnesota Laboratory Certifications
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Authority
Certificate #
Authority
Certificate #
Missouri
10100
A2LA
2926.01
Montana
CERT0092
Alabama
40770
Nebraska
NE-OS-18-06
Alaska-DW
MN00064
Nevada
MN00064
Alaska -UST
17-009
New Hampshire
2081
Arizona
AZ0014
New Jersey
MN002
Arkansas - WW
88-0680
New York
11647
Arkansas-DW
MN00064
North Carolina-
27700
California
2929
North Carolina-
530
Colorado
MN00064
North Dakota
R-036
Connecticut
PH-0256
Ohio-DW
41244
Florida
E87605
Ohio-VAP (170
CL101
Georgia
959
Ohio-VAP (180
CL110
Hawaii
MN00064
Oklahoma
9507
Idaho
MN00064
Oregon -Primary
MN300001
Illinois
200011
Oregon -Second
MN200001
Indiana
C-MN-01
Pennsylvania
68-00563
Iowa
368
Puerto Rico
MN00064
Kansas
E-10167
South Carolina
74003
Kentucky-DW
90062
Tennessee
TN02818
Kentucky-WW
90062
Texas
T104704192
Louisiana-DEQ
AI-84596
Utah
MN00064
Louisiana-DW
MN00064
Vermont
VT-027053137
Maine
MN00064
Virginia
460163
Maryland
322
Washington
C486
Michigan
9909
West Virginia-D
382
Minnesota
027-053-137
West Virginia-D
9952C
Minnesota-Ag
via MN 027-053
Wisconsin
999407970
Minnesota-Petr
1240
Wyoming -UST
via A2LA 2926.
Mississippi
MN00064
REPORT O F LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page 133 of 155
Report No ..... 10650068_16136TCDD_L2_R1_dfr Revision 1 Page 3 of 25

QD
aceAnalytical
Appendix A
Sample Management
REPORT OF LABORATORY ANALYSIS
Pace Analytical Services, LLC
1700 Elm Street, Suite 200
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
www.pacelabs.com
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Report No ..... 10650068_1613BTCDD_L2_R1_dfr Revision 1
Page 134 of 155
Page 4 of 25

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Page 135 V1155
Page 5 of 25

DC#_Title: ENV-FRM-MIN4-0150 v13_Sample Condition Upon Receipt (SCUR)
Effective Date: 4/14/2023
Sample Condition Client Name: Project #:
Upon Receipt I , ME a(-%r[)4fe
Courier: VFedEx ❑ UPS ❑ LISPS ❑ Client
❑ Pace ❑ SpeeDee ❑ Commercial
❑ See Exceptions
WQ## ;1 Q65Q068
PM: IJJ Due Date: 05/21/23
CLIENT: PASI—CHRLT
Tracking Number: �2 M/ z j �jl CJ f l ENV-FRM-MIN4-0142
Custody Seal on Cooler/Box Present? ❑ Yes VNo Seals Intact? ❑ Yes VNo Biological Tissue Frozen? ❑ Yes ❑ No 1WN/A
Packing Material: ❑ Bubble Wrap Bubble Bags ❑ None ❑ Other Temp Blank? ❑ Yes VNo
Thermometer: ❑ T1 (0461) V/ T2 (0436) ❑ T3 (04Sq) ❑ T4 (n402) ❑ TS (017R) Type of Ice:VWet ❑ Blue ❑ Dry ❑ None
❑ T6 (0235) ❑ T7 (0042) ❑ T8 (0775) ❑ T9(0727) ❑ 01339252/1710 ❑ Melted
Did Samples Originate in West Virginia? ❑ Yes VNo Were All Container Temps Taken? [:]Yes ❑ No MN/A
Temp should be above freezing to 6 °C Cooler temp Read w/Temp Blank: °C
Average Corrected Temp
(no temp blank only): ©. S °C
Correction Factor: V e, Cooler Temp Corrected w/temp blank: °C
�ee Exceptions ENV-FRM-MIN4-0142 ❑ 1 Container
USDA Regulated Soil: (W N/A water sampl' other: ) Date/Initials of Person Examining Contents: 8j6;,)%XO_ , r
Did samples originate in a quarantine zone within the United States: AL, AR, AZ CA, FL, Did samples originate from a foreign source (internationally,
GA, ID, LA, MS, NC, NM, NY, OK, OR, SC, TN, TX, or VA (check maps)? ❑ Yes ❑ No including Hawaii and Puerto Rico)? ❑ Yes ❑ No
If Yes to either question. fill out a Reeulated Soil Checklist (ENV-FRM-MIN4-01S4) and include with SCUR/COC nanerwork_
Location(Checkone): Duluth Minneapolis
Virginia
COMMENTS
Chain of Custody Present and Filled Out?
4,Yes
LJ
No
1.
Chain of Custody Relinquished?
Yes
No
2.
Sampler Name and/or Signature on COC?
LJYes
h4
No
N/A
3.
Samples Arrived within Hold Time?
LV
Yes
LJ
No
4. If fecal: <8 hrs LJ >8 hr, <24 No
Short Hold Time Analysis (<72 hr)?
LJ Yes
6Z No
5. F7 Fecal Coliform HPC Total Coliform/E.coli
❑ BOD/cBOD ❑ Hex Chrom❑ Turbidity ❑ Nitrate
❑ Nitrite❑ Orthophos ❑ Other
Rush Turn Around Time Requested?
Yes
NpZb
6. j .
Sufficient Sample Volume?
Yes
o
7. 1 �, �,. �„ v i b M tt v ".*- #—
Correct Containers Used?
M
Yes
7J No
LJ N/A
8.
-Pace Containers Used?
VYes
❑ No
Containers Intact?
M
Yes
H No
9.
Field Filtered Volume Received for Dissolved Tests?
U
Yes
NO
M N/A
10. Is sediment visible in the dissolved container? Yes 1_1 No
Is sufficient information available to reconcile the samples to the
M Yes
LJ No
11. If no, write ID/Date/Time of container below:
COC?
0 n 1L'� 3 16%5n 'yh eG ❑ See Exceptions
_
Matrix: �.. Waterl__L_] Soil �� Oil _] Other
Irla �e,5 re ENV-FRM-MIN4-0142
All containers needing acid/base preservation have been
Yes
Ll No
M N/A
12. Sample #
checked?
All containers needing preservation are found to be in ❑ Yes
❑ No
VN/A
❑ NaOH ❑ HNO3
compliance with EPA recommendation?
❑ H2SO4 ❑ Zinc Acetate
(HNO3, H2SO4, <2pH, NaOH >9 Sulfide, NaOH>10 Cyanide)
Exceptions: VOA, Coliform, TOC/DOC Oil and Grease, DRO/8015 U Yes
❑ No
N/A
Positive for Residual ❑ Yes ❑ See Exceptions
(water) and Dioxins/PFAS
Chlorine? ❑ No ENV-FRM-MIN4-0142
(*If adding preservative to a container, it must be added to
pH Paper Lot #
Residual Chlorine
0-6 Roll
0-6 StrT
F14rip
associated field and equipment blanks --verify with PM first.)
Headspace in Methyl Mercury Container?
U Yes
No
VJ
N/A
13.
Extra labels present on soil VOA or WIDRO containers?
0 Yes
No
N/A
14. See Exceptions
Headspace in VOA Vials (greater than 6mm)? ❑ Yes
❑ No
N/A I
ENV-FRM-MIN4-0142
3 Trip Blanks Present?
Yes
No
VJ N/A 1
15.
Trip Blank Custody Seals Present? ❑ Yes
❑ No
N/A
Pace Trip Blank Lot # (if purchased):
CLIENT NOTIFICATION/RESOLUTION
Person Contacted:
Comments/Resolution:
Project Manager Review:
Field Data Required? LJ Yes U No
Date/Time:
Date: 04/21 /23
NOTE: Whenever there is a discrepancy affecting North Ca ance samples, a copy 10, is form will be sent to the North Carolina DEHNR Certification Office (i.e., out of hold, incorrect preservative, out of
temp, incorrect containers).
Labeled By: 6 � Line: y
Qualtrax ID: 52742 Pace' Analytical Services, LLC PP`age I of 5
Report No ..... 10650068_1613EITCDD_L2_R1_dfr Revision 1 Page 6 of 25

�Ceb
DC#_Title: ENV-FRM-MIN4-0142 02_Sample Condition Upon Receipt
(SCUR) Exception Form
AKAEVEILAL LEAIILES
Effective Date: 09/22/2022
Workorder #:
a
If yes, indicate who was contacted, date and time.
If no, indicate reason why.
If anything is OVER 6.00 C, you MUST document containers in this section HERE
pH Adjustment
Log for Preserved
Samples
Type
pH
Amount
In Compliance
Upon, ,
' Date-,
Ti L— -
Added,
Lot #
pH -
After•
- ;
Sampie ID'
Preserve„
,Receipt;
Adjusted
Adjusted:
„(mL) :
`Added,
, After„'
.Addition?
' Initials
❑ Yes
❑ No
❑ Yes
❑ No
❑ Yes
❑ No
❑ Yes
❑ No
❑ Yes
❑ No
❑ Yes
❑ No
❑ Yes
❑ No
❑ Yes
❑ No
Comments:
Qualtrax ID: 52763 Page 1 of 1
Page 137 of 155
Report No ..... 10650068_1613BTCDD_L2_R1_dfr Revision 1 Page 7 of 25

DC#_Title: ENV-FRM-MIN4-0150 v11_Sample Condition Upon Receipt (SCUR)
Effective Date: 11/16/2022
Client Name: Project #:
' mr— NA-TtopAL_
Courier: FedEx ❑ LIPS ❑ LISPS ❑ Client
Pace ❑ SpeeDee ❑ Commercial
❑ See Exceptions
Tracking Number: &a w 2igg ENV-FRM-MIN4-0142
Custody Seal on Cooler/Box Present? Yes ❑ No Seals Intact? .Yes ❑ No Biological Tissue Frozen? ❑ Yes ❑ No K N/A
Packing Material: kBubble Wrap Bubble Bags ❑ None ❑ Other Temp Blank? XYes ❑ No
Thermometer: ❑ Tl (0461) ❑ T2 (1336) ❑ T3 (0459) ❑ T4 (0254) M_TS (0178) Type of Ice: Wet ❑ Blue ❑ Dry ❑ None
❑ T6 (0235) ❑ T7 (0042) ❑ T8.(0775) ❑ T9(0727) ❑ 01339252/1710 Melted
10650068
IDid Samples Originate In West Virginia? ❑ Yes A,No Were All Container Temps Taken? ❑ Yes DK No ❑ N/A I
Temp should be above freezing to 6'C Cooler temp Read w/Temp Blank: —o• (c °C I Average Corrected Temp
(no temp blank only): °C
Correction Factor: O 2 Cooler Temp Corrected w/temp blank: - 0 • c6 °C ❑ See Exceptions ENV-FRM-MIN4-0142 ❑ 1 Container
USDA Regulated Soil: ((N/A water ample/other: ) Date/Initials of Person Examining Contents:
Did samples originate In a quarant ne zone within the United States: AL, AR, AZ CA, L, Did samples originate from a foreign source (internationally,
GA, ID, LA, MS, NC, NM, NY, OK, OR, SC, TN, TX, or VA (check maps)? ❑ Yes No including Hawaii and Puerto Rico)? ❑ Yes V No
If Yes to either auestion. fill out a Reeulated Soil Checklist (ENV-FRM-MIN4-0154) and Include with SCUR/COC nanerwork.
Location (Check one): Duluth Minneapolis LJ Virginia
COMMENTS
Chain of Custody Present and Filled Out?
I I Yes I
No
1.
Chain of Custody Relinquished?
LJ Yes
H No
2,
Sampler Name and/or Signature on COC?
H Yes LJ
No LJ N/A
3.
Samples Arrived within Hold Time?
Yes LJ
No
4. If fecal: LJ <8 hrs LJ >8 hr, <24 LJ No
Short Hold Time Analysis (<72 hr)7 LJ Yes No
5. LJ Fecal Coliforml I HPCLJ Total Coliform/E.coli
❑ BOD/cBOD Hex Chrom❑ Turbidity ❑ Nitrate
Nitrite LJ Ortho hos Other
Rush Turn Around Time Requested? Yes
No
16.
Sufficient Sample Volume? LJ Yes
No
7.
Correct Containers Used? L Yes LJ
No N/A
8.
-Pace Containers Used? ❑ Yes
❑ No
Containers Intact? LJ Yes LJ
No
9.
Field Filtered Volume Received for Dissolved Tests? LJ Yes LJ
No LJ N/A
10. Is sediment visible in the dissolved container? Ll Yes LJ No
Is sufficient information available to reconcile the samples to the LJ Yes H No
11. If no, write ID/Date/Time of container below:
COC?
❑ See Exceptions
Matrix: Water❑ Soil ❑ Oil ❑ Other
ENV-FRM-MIN4-0142
All containers needing acid/base preservation have been LJ Yes No LJ N/A
12. Sample #
checked?
All containers needing preservation are found to be in ❑ Yes ❑ No ❑ N/A
❑ NaOH ❑ HNO3
compliance with EPA recommendation?
❑ H2SO4 ❑ Zinc Acetate
(HNO3, H2SO4, <2pH, NaOH >9 Sulfide, NaOH>10 Cyanide)
Exceptions: VOA, Coliform, TOC/DOC Oil and Grease, DRO/8015 ❑ Yes ❑ No ❑ N/A
Positive for Residual ❑ Yes ❑ See Exceptions
(water) and Dioxins/PFAS
Chlorine? ❑ No ENV-FRM-MIN4-0142
(*If adding preservative to a container, it must be added to
pH Paper Lot #
Residual Chlorine
0-6 Roll
0-6 Strip
0-14 Strip
associated field and equipment blanks —verify with PM first.)
Headspace In Methyl Mercury Container?
Yes
NO
W N/A
13.
Extra labels present on soll VOA or WIDRO containers?
Yes
No
LJ N/A
14. See Exceptions
Headspace in VOA Vials (greater than 6mm)?
❑ Yes
No
❑ N/A
ENV-FRM-MIN4-0142
3 Trlp Blanks Present?
H Yes LJ
No
LJ N/A
15.
Trip Blank Custody Seals Present?
❑ Yes n
No
❑ N/A
Pace Trip Blank Lot # (if purchased):
CLIENT NOTIFICATION/RESOLUTION
Person Contacted:
Comments/Resolution:
Project Manager Review:
NOTE; Whenever there Is a discrepancy affecting North
temp, Incorrect containers).
Qualtrax ID: 52742
Field Data Required? LJ Yes U IVO
Date/Time:
�r Date: 04/21/23
nce samples, a copy oft il form will be sent to the North Carolina DEHNR Certification Office (i.e., out of hold, incorrect preservative, out of
Labeled By: Line:
Pace® Analytical Services, LLC Page 1 of 1
Page 138 of 155
Report No ..... 10650068_1613BTCDD_1-2_R1_dfr Revision 1 Page 8 of 25

QD
aceAnalytical
Reporting Flags
A = Reporting Limit based on signal to noise (EDL)
B = Less than 1 Ox higher than method blank level
C = Result obtained from confirmation analysis
D = Result obtained from analysis of diluted sample
E = Exceeds calibration range
H2 = Extracted outside of holding time
I = Isotope ratio out of specification
J = Estimated value
Pace Analytical Services, LLC
1700 Elm Street, Suite 200
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
www.pacelabs.com
L = Suppressive interference, analyte may be biased low
Nn = Value obtained from additional analysis
P = PCDE Interference
R = Recovery outside target range
S = Peak saturated
U = Analyte not detected
V = Result verified by confirmation analysis
X = %D Exceeds limits
Y = Calculated using average of daily RFs
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 139 of 155
Page 9 of 25
Report No ..... 10650068_1613BTCDD_L2_R1_dfr Revision 1

QD
aceAnalytical
Appendix B
Sample Analysis Summary
REPORT OF LABORATORY ANALYSIS
Pace Analytical Services, LLC
1700 Elm Street, Suite 200
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
www.pacelabs.com
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Report No ..... 10650068_1613BTCDD_L2_R1_dfr Revision 1
Page 140 of 155
Page 10 of 25

Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Dry Weight Extracted
ICAL ID
CCal Filename(s)
Method Blank ID
Native
Isomers
Method 1613B Sample Analysis Results
Client - PACE Charlotte
MW-1 R
92659555001
L230504A_10
SMT
107 mL
NA
NA
L230501
L230504A_07
BLANK-105461
Conc EMPC
pg/L pg/L
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Matrix
Water
Dilution
NA
Collected
03/28/2023 12:52
Received
04/20/2023 08:50
Extracted
04/25/2023 09:45
Analyzed
05/04/2023 10:03
MDL Internal
ng's Percent
pg/L Standards
Added Recovery
2,3,7,8-TCDD ND ----- 21 2,3,7,8-TCDD-13C 2.00 79
Recovery Standard
1,2,3,4-TCDD-13C 2.00 NA
Cleanup Standard
2,3,7,8-TCDD-37CI4 0.20 85
Conc = Concentration (Totals include 2,3,7,8-substituted isomers). ND = Not Detected
EMPC = Estimated Maximum Possible Concentration NA = Not Applicable
MDL = Method Detection Limit NC = Not Calculated
R = Recovery outside target range
E= Exceeds calibration range
REPORTOF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10650068_1613BTCDD_L2_R1_dfr Revision 1
Page 141 of 155
Page 11 of 25

Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Dry Weight Extracted
ICAL ID
CCal Filename(s)
Method Blank ID
Native
Isomers
Method 1613B Sample Analysis Results
Client - PACE Charlotte
MW-2R
92659555002
L230504A_11
SMT
321 mL
NA
NA
L230501
L230504A_07
BLANK-105436
Conc EMPC
pg/L pg/L
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Matrix
Water
Dilution
NA
Collected
03/28/2023 11:50
Received
04/20/2023 08:50
Extracted
04/22/2023 10:25
Analyzed
05/04/2023 10:47
MDL Internal
ng's Percent
pg/L Standards
Added Recovery
2,3,7,8-TCDD ND ----- 6.9 2,3,7,8-TCDD-13C 2.00 57
Recovery Standard
1,2,3,4-TCDD-13C 2.00 NA
Cleanup Standard
2,3,7,8-TCDD-37CI4 0.20 61
Conc = Concentration (Totals include 2,3,7,8-substituted isomers). ND = Not Detected
EMPC = Estimated Maximum Possible Concentration NA = Not Applicable
MDL = Method Detection Limit NC = Not Calculated
R = Recovery outside target range
E= Exceeds calibration range
REPORTOF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10650068_1613BTCDD_L2_R1_dfr Revision 1
Page 142 of 155
Page 12 of 25

Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Dry Weight Extracted
ICAL ID
CCal Filename(s)
Method Blank ID
Native
Isomers
Method 1613B Sample Analysis Results
Client - PACE Charlotte
MW-3R
92659555003
L230504A_12
SMT
429 mL
NA
NA
L230501
L230504A_07
BLANK-105436
Conc EMPC
pg/L pg/L
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Matrix
Water
Dilution
NA
Collected
03/28/2023 10:50
Received
04/20/2023 08:50
Extracted
04/22/2023 10:25
Analyzed
05/04/2023 11:32
MDL Internal
ng's Percent
pg/L Standards
Added Recovery
2,3,7,8-TCDD ND ----- 5.1 2,3,7,8-TCDD-13C 2.00 58
Recovery Standard
1,2,3,4-TCDD-13C 2.00 NA
Cleanup Standard
2,3,7,8-TCDD-37CI4 0.20 66
Conc = Concentration (Totals include 2,3,7,8-substituted isomers). ND = Not Detected
EMPC = Estimated Maximum Possible Concentration NA = Not Applicable
MDL = Method Detection Limit NC = Not Calculated
R = Recovery outside target range
E= Exceeds calibration range
REPORTOF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10650068_1613BTCDD_L2_R1_dfr Revision 1
Page 143 of 155
Page 13 of 25

Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Dry Weight Extracted
ICAL ID
CCal Filename(s)
Method Blank ID
Native
Isomers
Method 1613B Sample Analysis Results
Client - PACE Charlotte
MW-4
92659555007
L230504A_13
SMT
1030 mL
NA
NA
L230501
L230504A_07
BLANK-105436
Conc EMPC
pg/L pg/L
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Matrix
Water
Dilution
NA
Collected
03/28/2023 14:02
Received
04/20/2023 08:50
Extracted
04/22/2023 10:25
Analyzed
05/04/2023 12:16
MDL Internal
ng's Percent
pg/L Standards
Added Recovery
2,3,7,8-TCDD ND ----- 2.1 2,3,7,8-TCDD-13C 2.00 50
Recovery Standard
1,2,3,4-TCDD-13C 2.00 NA
Cleanup Standard
2,3,7,8-TCDD-37CI4 0.20 55
Conc = Concentration (Totals include 2,3,7,8-substituted isomers). ND = Not Detected
EMPC = Estimated Maximum Possible Concentration NA = Not Applicable
MDL = Method Detection Limit NC = Not Calculated
R = Recovery outside target range
E= Exceeds calibration range
REPORTOF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.
Report No ..... 10650068_1613BTCDD_L2_R1_dfr Revision 1
Page 144 of 155
Page 14 of 25

Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Dry Weight Extracted
ICAL ID
CCal Filename(s)
Method Blank ID
Native
Isomers
Method 1613B Sample Analysis Results
Client - PACE Charlotte
MW-5
92659555008
L230504A_14
SMT
1030 mL
NA
NA
L230501
L230504A_07
BLANK-105436
Conc EMPC
pg/L pg/L
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Matrix
Water
Dilution
NA
Collected
03/28/2023 15:56
Received
04/20/2023 08:50
Extracted
04/22/2023 10:25
Analyzed
05/04/2023 13:01
MDL Internal
ng's Percent
pg/L Standards
Added Recovery
2,3,7,8-TCDD ND ----- 2.1 2,3,7,8-TCDD-13C 2.00 61
Recovery Standard
1,2,3,4-TCDD-13C 2.00 NA
Cleanup Standard
2,3,7,8-TCDD-37CI4 0.20 70
Conc = Concentration (Totals include 2,3,7,8-substituted isomers). ND = Not Detected
EMPC = Estimated Maximum Possible Concentration NA = Not Applicable
MDL = Method Detection Limit NC = Not Calculated
R = Recovery outside target range
E= Exceeds calibration range
REPORTOF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.
Report No ..... 10650068_1613BTCDD_L2_R1_dfr Revision 1
Page 145 of 155
Page 15 of 25

Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Dry Weight Extracted
ICAL ID
CCal Filename(s)
Method Blank ID
Native
Isomers
Method 1613B Sample Analysis Results
Client - PACE Charlotte
MW-6
92659555009
L230504A_15
SMT
1020 mL
NA
NA
L230501
L230504A_07
BLANK-105436
Conc EMPC
pg/L pg/L
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Matrix
Water
Dilution
NA
Collected
03/28/2023 14:32
Received
04/20/2023 08:50
Extracted
04/22/2023 10:25
Analyzed
05/04/2023 13:45
MDL Internal
ng's Percent
pg/L Standards
Added Recovery
2,3,7,8-TCDD ND ----- 2.4 A 2,3,7,8-TCDD-13C 2.00 56
Recovery Standard
1,2,3,4-TCDD-13C 2.00 NA
Cleanup Standard
2,3,7,8-TCDD-37CI4 0.20 64
Conc = Concentration (Totals include 2,3,7,8-substituted isomers). ND = Not Detected
EMPC = Estimated Maximum Possible Concentration NA = Not Applicable
MDL = Method Detection Limit NC = Not Calculated
A = Reporting Limit based on signal to noise (EDL)
R = Recovery outside target range
E= Exceeds calibration range
REPORTOF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10650068_1613BTCDD_L2_R1_dfr Revision 1
Page 146 of 155
Page 16 of 25

Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Dry Weight Extracted
ICAL ID
CCal Filename(s)
Method Blank ID
Native
Isomers
Method 1613B Sample Analysis Results
Client - PACE Charlotte
FIELD BLANK
92659555010
L230504A_16
SMT
1040 mL
NA
NA
L230501
L230504A_07
BLANK-105436
Conc EMPC
pg/L pg/L
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Matrix
Water
Dilution
NA
Collected
03/28/2023 15:55
Received
04/20/2023 08:50
Extracted
04/22/2023 10:25
Analyzed
05/04/2023 14:30
MDL Internal
ng's Percent
pg/L Standards
Added Recovery
2,3,7,8-TCDD ND ----- 2.1 A 2,3,7,8-TCDD-13C 2.00 53
Recovery Standard
1,2,3,4-TCDD-13C 2.00 NA
Cleanup Standard
2,3,7,8-TCDD-37CI4 0.20 66
Conc = Concentration (Totals include 2,3,7,8-substituted isomers). ND = Not Detected
EMPC = Estimated Maximum Possible Concentration NA = Not Applicable
MDL = Method Detection Limit NC = Not Calculated
A = Reporting Limit based on signal to noise (EDL)
R = Recovery outside target range
E= Exceeds calibration range
REPORTOF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10650068_1613BTCDD_L2_R1_dfr Revision 1
Page 147 of 155
Page 17 of 25

Lab Sample Name
Lab Sample ID
Filename
Total Amount Extracted
ICAL ID
CCal Filename(s)
Native
Isomers
TM
�ical
Method 1613B Blank Analysis Results
DFBLKKR
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
BLANK-105461
Matrix
Water
L230429A_06
Dilution
NA
1030 mL
Extracted
04/25/2023 09:45
L230302
Analyzed
04/29/2023 10:30
1-23042813_20
Injected By
JRH
Conc EMPC MDL Internal ng's Percent
pg/L pg/L pg/L Standards Added Recovery
2,3,7,8-TCDD ND ----- 2.1 2,3,7,8-TCDD-13C 2.00 73
Recovery Standard
1,2,3,4-TCDD-13C 2.00 NA
Cleanup Standard
2,3,7,8-TCDD-37CI4 0.20 92
Conc=Concentration (Totals include 2,3,7,8-substituted isomers)
EMPC = Estimated Maximum Possible Concentration
MDL = Method Detection Limit
REPORTOF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.
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Page 148 of 155
Page 18 of 25

Lab Sample Name
Lab Sample ID
Filename
Total Amount Extracted
ICAL ID
CCal Filename(s)
Native
Isomers
TM
�ical
Method 1613B Blank Analysis Results
DFBLKKI
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
BLANK-105436
Matrix
Water
L230502A_10
Dilution
NA
1000 mL
Extracted
04/22/2023 10:25
L230501
Analyzed
05/02/2023 12:54
L230502A 04
Injected By
SMT
Conc EMPC MDL Internal ng's Percent
pg/L pg/L pg/L Standards Added Recovery
2,3,7,8-TCDD ND ---- 2.2 2,3,7,8-TCDD-13C 2.00 53
Recovery Standard
1,2,3,4-TCDD-13C 2.00 NA
Cleanup Standard
2,3,7,8-TCDD-37CI4 0.20 69
Conc=Concentration (Totals include 2,3,7,8-substituted isomers)
EMPC = Estimated Maximum Possible Concentration
MDL = Method Detection Limit
REPORTOF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10650068_1613BTCDD_L2_R1_dfr Revision 1
Page 149 of 155
Page 19 of 25

AAnalvtical�
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Method 1613B Laboratory Control Spike Results
Lab Sample ID
LCS-105462
Filename
L230429A_12
Matrix
Water
Total Amount Extracted
1010 mL
Dilution
NA
ICAL ID
L230302
Extracted
04/25/2023 09AE
CCal Filename
L230428B_20
Analyzed
04/29/2023 14:5E
Method Blank ID
BLANK-105461
Injected By
JRH
Lower
Upper
Compound
Cs Cr
Limit
Limit
Rec.
2,3,7,8-TCDD
10
10
7.3
14.6
104
2,3,7,8-TCDD-37CI4
10
9.1
3.7
15.8
91
2,3,7,8-TCDD-13C
100
70
25.0
141.0
70
Cs = Concentration Spiked (ng/mL)
Cr = Concentration Recovered (ng/mL)
Rec. = Recovery (Expressed as Percent)
Control Limit Reference: Method 1613, Table 6, 10/94 Revision
R = Recovery outside of control limits
Nn = Value obtained from additional analysis
*=See Discussion
REPORTOF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10650068_1613BTCDD_L2_R1_dfr Revision 1
Page 150 of 155
Page 20 of 25

AAnalvtical�
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Method 1613B Laboratory Control Spike Results
Lab Sample ID
LCS-105437
Filename
L230502A_05
Matrix
Water
Total Amount Extracted
996 mL
Dilution
NA
ICAL ID
L230501
Extracted
04/22/2023 10:25
CCal Filename
L230502A_04
Analyzed
05/02/2023 09:12
Method Blank ID
BLANK-105436
Injected By
SMT
Lower
Upper
Compound
Cs Cr
Limit
Limit
Rec.
2,3,7,8-TCDD
10
11
7.3
14.6
110
2,3,7,8-TCDD-37CI4
10
6.7
3.7
15.8
67
2,3,7,8-TCDD-13C
100
44
25.0
141.0
44
Cs = Concentration Spiked (ng/mL)
Cr = Concentration Recovered (ng/mL)
Rec. = Recovery (Expressed as Percent)
Control Limit Reference: Method 1613, Table 6, 10/94 Revision
R = Recovery outside of control limits
Nn = Value obtained from additional analysis
*=See Discussion
REPORTOF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10650068_1613BTCDD_L2_R1_dfr Revision 1
Page 151 of 155
Page 21 of 25

AAnalvtical�
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Method 1613B Laboratory Control Spike Results
Lab Sample ID
LCSD-105463
Filename
L230429A_13
Matrix
Water
Total Amount Extracted
1000 mL
Dilution
NA
ICAL ID
L230302
Extracted
04/25/2023 09AE
CCal Filename
L230428B_20
Analyzed
04/29/2023 15:42
Method Blank ID
BLANK-105461
Injected By
JRH
Lower
Upper
Compound
Cs Cr
Limit
Limit
Rec.
2,3,7,8-TCDD
10
10
7.3
14.6
103
2,3,7,8-TCDD-37CI4
10
9.6
3.7
15.8
96
2,3,7,8-TCDD-13C
100
77
25.0
141.0
77
Cs = Concentration Spiked (ng/mL)
Cr = Concentration Recovered (ng/mL)
Rec. = Recovery (Expressed as Percent)
Control Limit Reference: Method 1613, Table 6, 10/94 Revision
R = Recovery outside of control limits
Nn = Value obtained from additional analysis
*=See Discussion
REPORTOF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10650068_1613BTCDD_L2_R1_dfr Revision 1
Page 152 of 155
Page 22 of 25

AAnalvtical�
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Method 1613B Laboratory Control Spike Results
Lab Sample ID
LCSD-105438
Filename
L230502A_06
Matrix
Water
Total Amount Extracted
990 mL
Dilution
NA
ICAL ID
L230501
Extracted
04/22/2023 10:25
CCal Filename
L230502A_04
Analyzed
05/02/2023 09:55
Method Blank ID
BLANK-105436
Injected By
SMT
Lower
Upper
Compound
Cs Cr
Limit
Limit
Rec.
2,3,7,8-TCDD
10
11
7.3
14.6
111
2,3,7,8-TCDD-37CI4
10
6.1
3.7
15.8
61
2,3,7,8-TCDD-13C
100
45
25.0
141.0
45
Cs = Concentration Spiked (ng/mL)
Cr = Concentration Recovered (ng/mL)
Rec. = Recovery (Expressed as Percent)
Control Limit Reference: Method 1613, Table 6, 10/94 Revision
R = Recovery outside of control limits
Nn = Value obtained from additional analysis
*=See Discussion
REPORTOF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.
Report No ..... 10650068_1613BTCDD_L2_R1_dfr Revision 1
Page 153 of 155
Page 23 of 25

a
Client
Spike 1 ID
Spike 1 Filename
Compound
TM
►cal
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Method 1613B
Spike Recovery Relative Percent Difference (RPD) Results
PACE Charlotte
LCS-105462 Spike 2 ID LCSD-105463
L230429A 12 Spike 2 Filename L230429A 13
Spike 1 Spike 2
%REC %REC %RPD
2,3,7,8-TCDD 104 103 1.0
%REC = Percent Recovered
RPD = The difference between the two values divided by the mean value
REPORTOF LABORATORY ANALYSIS
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Report No ..... 10650068_1613BTCDD_L2_R1_dfr Revision 1
Page 154 of 155
Page 24 of 25

a
Client
Spike 1 ID
Spike 1 Filename
Compound
TM
►cal
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Method 1613B
Spike Recovery Relative Percent Difference (RPD) Results
PACE Charlotte
LCS-105437 Spike 2 ID LCSD-105438
L230502A 05 Spike 2 Filename L230502A 06
Spike 1 Spike 2
%REC %REC %RPD
2,3,7,8-TCDD 110 111 0.9
%REC = Percent Recovered
RPD = The difference between the two values divided by the mean value
REPORTOF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.
Report No ..... 10650068_1613BTCDD_L2_R1_dfr Revision 1
Page 155 of 155
Page 25 of 25

Appendix C
Summary of Historical Groundwater Elevations
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

Appendix C
Summary of Historical Groundwater Elevations
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Groundwater Elevations (ft AMSL)
Date
Background
Downgradient
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
8/21/99
418.68
329.13
328.06
330.50
330.83
352.10
NI
11/16/99
419.75
325.38
324.51
331.53
334.33
352.97
NI
5/10/00
424.53
329.60
328.83
334.15
334.49
355.72
NI
10/26/00
419.21
329.26
328.15
331.33
330.94
352.78
NI
4/18/01
418.76
329.42
328.63
333.57
334.36
354.22
NI
10/26/01
412.53
329.04
327.94
330.57
330.23
350.92
NI
6/13/02
413.70
328.38
327.41
330.21
330.29
351.04
NI
11/19/02
413.40
329.25
328.35
331.57
337.17
350.94
NI
06/27/03
423.61
329.57
328.93
334.24
333.99
355.21
NI
12/29/03
420.23
329.70
329.11
334.49
334.78
354.92
NI
06/30/04
418.81
329.38
328.48
332.26
331.39
353.10
NI
12/28/04
418.02
329.50
328.91
333.45
334.14
355.14
NI
06/29/05
418.81
329.10
329.26
331.62
330.90
352.76
NI
12/29/05
413.38
329.29
328.71
332.78
334.27
351.52
NI
06/27/06
414.75
329.17
328.40
332.18
333.56
353.43
NI
12/28/06
415.54
329.40
328.86
333.57
335.24
354.02
NI
07/12/07
438.64
328.69
327.97
331.31
330.52
352.30
NI
12/18/07
412.59
328.94
328.08
330.32
327.92
347.90
306.54
07/08/08
414.52
329.20
326.00
331.46
330.85
351.03
NM
12/17/08
412.79
329.39
328.84
333.15
335.03
350.82
NM
07/09/09
417.16
329.17
329.48
332.30
331.36
352.17
310.12
12/16/29
418.11
329.55
329.09
334.57
336.94
352.87
NM
06/24/10
422.42
329.41
328.77
333.65
333.15
353.62
NM
12/13/10
415.96
329.49
328.85
332.81
330.34
350.08
NM
06/20/11
416.00
328.95
328.18
336.77
331.38
351.83
NM
12/05/11
412.94
329.31
328.65
332.32
329.51
349.87
NM
06/12/11
414.56
329.10
328.35
332.52
331.33
351.75
312.5
12/12/12
412.83
329.19
328.36
331.67
330.35
349.48
NM
05/01/13
415.69
329.65
329.13
334.49
335.15
353.63
317.11
08/05/13
417.97
329.02
328.41
333.32
332.83
353.01
NM
02/24/14
415.81
329.68
329.17
334.48
331.63
351.78
316.15
08/11/14
416.23
329.38
328.48
332.04
329.08
350.08
310.93
03/10/15
417.09
329.87
329.45
335.07
336.42
353.13
317.55
08/17/15
417.71
328.65
327.81
331.05
327.73
347.63
308.80
02/17/16
418.51
330.10
329.71
335.05
337.53
353.44
317.87
08/09/16
418.59
329.50
328.61
332.95
330.95
352.03
312.65
02/13/17
415.21
329.45
328.96
333.10
333.03
350.83
313.45
08/22/17
414.68
328.55
327.61
331.60
329.78
350.38
310.55
02/05/18
412.31
329.41
328.21
332.07
328.87
348.18
317.10
08/14/18
415.86
328.96
327.96
331.97
329.68
350.12
312.51
02/04/19
420.86
329.67
329.28
335.62
335.42
355.30
316.02
08/06/19
420.05
329.35
328.37
332.98
329.73
351.46
310.34
02/12/20
417.43
329.75
329.30
335.65
336.08
352.38
317.67
08/27/20
418.84
329.18
328.55
333.42
330.48
351.34
310.90
02/11/21
421.71
329.93
329.62
336.59
336.17
355.52
318.10
08/19/21
420.22
329.50
328.71
333.67
330.13
351.84
310.29
02/15/22
415.99
329.57
329.00
334.15
330.53
350.12
312.55
09/28/22
414.20
328.48
327.43
331.12
327.62
347.59
307.54
03/28/23
1 416.40
1 329.51
1 328.82
1 334.16
1 335.15
1 352.63
1 315.29
Notes.
Groundwater elevations from August 1999 through February 2021 obtained from LaBelle Associates Water Quality
Monitoring Report - February 2021 Event.
Groundwater elevations from August 2021 obtained from Garrett & Moore, Inc. Water Quality Monitoring Report - August
2021 Event.
ft AMSL = ft above mean sea level
NM = water level not measure
NI = well not yet installed
Appendix C (Page 1 of 1)
https://hanhick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2023 First Half GW M/rables/ Hart &Hickman PC
Butner Historic Tables.Aax

Appendix D
Summary of Historical Constituents in Groundwater
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-211
MW-311
MW-4
MW-5
MW-6
NES-1
1,1-Dichloroethane
12/01/97
---
ND
ND
1.0
ND
ND
ND
---
05/20/98
---
ND
ND
ND
ND
ND
ND
---
NC21-=6µg/L
11/19/98
---
ND
ND
ND
ND
ND
ND
---
07/21/99
---
ND
ND
ND
ND
ND
ND
---
11/16/99
---
ND
ND
ND
ND
ND
ND
---
05/10/00
---
ND
ND
ND
ND
ND
ND
--
10/26/00
---
ND
ND
ND
ND
ND
ND
---
04/18/01
---
ND
ND
ND
ND
ND
ND
---
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
---
ND
ND
ND
ND
ND
ND
---
11/19/02
---
ND
ND
ND
ND
ND
ND
---
06/27/03
---
ND
ND
ND
ND
ND
ND
---
12/30/03
---
ND
ND
ND
ND
ND
ND
---
06/30/04
---
ND
ND
ND
ND
ND
ND
---
12/29/04
---
ND
ND
ND
ND
ND
ND
---
06/29/05
---
ND
ND
ND
ND
ND
ND
---
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
---
ND
ND
ND
ND
ND
ND
---
12/29/06
---
ND
ND
ND
ND
ND
ND
---
07/12/07
---
ND
ND
0.36J
0.52J
ND
ND
--
12/19/07
---
ND
ND
ND
0.571
ND
ND
ND
07/08/08
---
ND
ND
ND
0.60J
ND
ND
--
12/17/08
0.32
ND
ND
ND
0.511
ND
ND
--
07/09/09
0.32
ND
ND
ND
0.84J
ND
ND
ND
12/16/09
0.32
ND
ND
ND
0.731
ND
ND
---
06/24/10
0.32
ND
ND
ND
0.53J
ND
ND
---
12/13/10
0.32
ND
ND
ND
0.601
ND
ND
---
06/20/11
0.32
ND
ND
ND
0.63J
ND
ND
---
12/05/11
0.32
ND
ND
ND
0.671
ND
ND
ND
06/11/12
0.32
ND
ND
ND
ND
ND
ND
---
12/12/12
0.32
ND
ND
ND
0.61J
ND
ND
ND
05/01/13
0.32
ND
ND
ND
0.62J
ND
ND
---
05/08/13
0.32
ND
ND
ND
0.53J
ND
ND
ND
02/24/14
0.32
ND
ND
ND
0.501
ND
ND
ND
08/12/14
0.32
ND
ND
ND
0.47J
ND
ND
ND
03/10/15
0.32
ND
ND
ND
0.501
ND
ND
---
08/18/15
0.32
ND
ND
ND
0.49J
ND
ND
ND
02/16/16
0.32
ND
ND
ND
0.45J
ND
ND
---
08/09/16
0.32
ND
ND
ND
0.34J
ND
ND
---
02/13/17
0.32
ND
ND
ND
0.33J
ND
ND
---
08/22/17
0.32
ND
ND
ND
0.37J
ND
ND
---
02/05/18
0.32
ND
ND
ND
0.38J
ND
ND
---
08/13/18
0.32
ND
ND
ND
0.37J
ND
ND
---
02/04/19
0.27
ND
ND
ND
0.36J
ND
ND
---
08/07/19
0.27
ND
ND
ND
ND
ND
ND
---
02/12/20
0.27
ND
ND
ND
0.33J
ND
ND
---
08/27/20
0.27
ND
ND
ND
ND
ND
ND
---
02/11/21
0.27
ND
ND
ND
ND
ND
ND
--
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
0.37
ND
ND
ND
ND
ND
ND
NA
9/28/221
0.37
ND
ND
ND
ND
ND
ND
NA
03/28/23
0.37
ND
ND
ND
ND
ND
ND
NA
1,2-Dichlorobenzene
12/01/97
---
ND
3.0
2.0
1.0
ND
ND
---
05/20/98
--
ND
ND
ND
ND
ND
ND
---
NC21-=20 pg/L
11/19/98
---
ND
2.4
2.3
ND
ND
ND
---
07/21/99
--
ND
ND
ND
ND
ND
ND
---
11/16/99
---
ND
ND
ND
ND
ND
ND
---
05/10/00
--
ND
ND
ND
ND
ND
ND
---
10/26/00
---
ND
ND
ND
ND
ND
ND
---
04/18/01
--
ND
ND
ND
ND
ND
ND
---
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
--
ND
ND
ND
ND
ND
ND
---
11/19/02
---
ND
ND
ND
ND
ND
ND
---
06/27/03
--
ND
ND
ND
ND
ND
ND
---
12/30/03
---
ND
ND
ND
ND
ND
ND
---
06/30/04
--
ND
ND
ND
ND
ND
ND
---
12/29/04
---
ND
ND
ND
ND
ND
ND
---
06/29/05
--
ND
ND
ND
ND
ND
ND
---
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
--
ND
ND
ND
ND
ND
ND
---
12/29/06
---
ND
1.5
2.3
ND
ND
ND
---
07/12/07
--
ND
1.4J
1.71
0.31J
ND
ND
---
12/19/07
---
ND
1.6
2.0
0.37J
ND
ND
ND
07/08/08
---
ND
1.6J
2.0J
0.391
ND
ND
--
12/17/08
0.3
ND
1.41
1.91
ND
ND
ND
---
07/09/09
0.3
ND
1.61
2.0J
0.361
ND
ND
ND
12/16/09
0.3
ND
1.61
2.0J
0.33J
ND
ND
---
06/24/30
0.3
ND
0.96J
1.7
0.31J
ND
ND
---
12/13/10
0.3
ND
1.91
1.91
0.43J
ND
ND
---
06/20/11
0.3
ND
1.51
1.71
0.37J
ND
ND
---
12/05/11
0.3
ND
1.31
1.6J
ND
ND
ND
---
06/11/12
0.3
ND
1.01
1.51
ND
ND
ND
ND
12/12/12
0.3
ND
1.31
1.7J
ND
ND
ND
---
05/01/13
0.3
ND
1.2J
1.61
ND
ND
ND
ND
08/05/13
0.3
ND
1.21
1.6J
0.301
ND
ND
---
02/24/14
0.3
ND
1.4J
0.64J
ND
ND
ND
ND
08/12/14
0.3
ND
1.21
1.51
ND
ND
ND
ND
03/10/15
0.3
ND
1.11
1.11
ND
ND
ND
ND
08/18/15
0.3
ND
0.88J
1.3J
ND
ND
ND
---
02/16/16
0.3
ND
1.11
1.41
ND
ND
ND
ND
08/09/16
0.3
ND
1.21
1.4J
ND
ND
ND
---
02/13/17
0.3
ND
1.2J
1.41
ND
ND
ND
---
08/22/17
0.3
ND
1.21
1.5J
ND
ND
ND
---
02/05/18
0.3
ND
1.01
1.41
ND
ND
ND
---
08/13/18
0.3
ND
1.21
1.6J
ND
ND
ND
---
02/04/19
0.29
ND
1.01
ND
ND
ND
ND
---
08/07/19
0.29
ND
0.62J
1.2
ND
ND
ND
---
02/12/20
0.29
ND
0.82J
0.71J
ND
ND
ND
---
08/27/20
0.29
ND
1.20
1.3
ND
ND
ND
---
02/11/21
0.29
ND
1.10
0.83J
ND
ND
ND
--
08/19/21
0.29
ND
1.1
1.1
ND
ND
ND
ND
02/16/22
0.34
ND
0.61
ND
ND
ND
ND
NA
9/28/221
0.34
ND
1.2
1.3
ND
ND
ND
NA
03/28/23
0.34
ND
1 1.0
1 1.0
ND
ND
ND
NA
Appendix D (Page t of 25)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-111
MW-2R
MW-3R
VW-4
MW-5
MW-6
NES-1
1,2-Dichloroethane
12/17/08
0.12
NO
NO
0.151
ND
NO
NO
---
07/09/09
0.12
NO
NO
NO
NO
NO
NO
NO
NC21-=0.4 µg/L
12/16/09
0.12
NO
ND
0.14J
NO
NO
NO
---
06/24/10
0.12
NO
NO
NO
NO
NO
NO
---
12/13/10
0.12
NO
NO
NO
NO
NO
NO
---
06/20/11
0.12
NO
NO
NO
NO
NO
NO
--
12/05/11
0.12
NO
NO
NO
NO
0.181
NO
--
06/11/12
0.12
NO
NO
NO
NO
NO
NO
NO
12/12/12
0.12
NO
NO
NO
NO
0.20J
NO
--
05/01/13
0.12
NO
NO
NO
NO
NO
NO
NO
08/05/13
0.12
NO
NO
NO
NO
NO
NO
--
02/24/14
0.12
NO
NO
NO
NO
NO
NO
NO
08/12/14
0.12
NO
NO
NO
NO
NO
NO
NO
03/10/15
0.12
NO
NO
NO
NO
NO
NO
NO
08/18/15
0.24
NO
NO
0.33J
0.29J
0.36J
NO
--
02/16/16
0.24
NO
NO
NO
NO
NO
NO
NO
08/09/16
0.24
NO
NO
NO
NO
NO
NO
---
02/13/17
0.24
NO
NO
NO
NO
NO
NO
---
08/22/17
0.24
NO
NO
NO
NO
NO
NO
---
02/05/18
0.24
0.25J
NO
0.37J
NO
0.43J
NO
---
08/13/18
0.24
NO
NO
NO
NO
NO
NO
---
02/04/19
0.34
NO
NO
NO
NO
NO
ND
---
08/07/19
0.34
NO
NO
NO
NO
NO
NO
---
02/12/20
0.34
NO
ND
NO
NO
NO
ND
---
08/27/20
0.34
NO
NO
NO
NO
NO
NO
---
02/11/21
0.34
NO
ND
NO
NO
NO
ND
---
08/19/21
NR
NO
NO
NO
NO
NO
NO
NO
02/16/22
0.32
NO
ND
NO
NO
NO
ND
NA
9/28/22'
0.32
ND
NO
NO
ND
NO
ND
NA
03/28/23
0.32
NO
NO
NO
NO
NO
NO
NA
1,4-Dichlorobenzene
09/08/94
---
ND
NO
5.0
ND
ND
ND
---
12/01/94
---
NO
NO
5.0
NO
NO
NO
---
NC21-=6µg/L
02/09/95
---
ND
8.0
6.0
NO
ND
ND
---
03/02/95
--
NO
7.0
6.0
NO
ND
NO
---
11/15/95
---
ND
7.0
6.0
NO
ND
ND
---
05/28/96
--
NO
NO
NO
NO
ND
NO
---
11/22/96
---
ND
ND
NO
NO
ND
ND
---
06/17/97
--
NO
7.6
6.2
NO
ND
NO
---
12/01/97
---
ND
6.0
5.0
4.0
ND
ND
---
05/20/98
--
NO
7.6
NO
NO
ND
NO
---
11/19/98
---
ND
3.7
2.8
NO
ND
ND
---
07/21/99
--
NO
NO
NO
NO
NO
NO
---
11/16/99
---
ND
ND
NO
NO
ND
ND
---
05/10/00
--
NO
NO
NO
NO
NO
NO
---
10/26/00
---
NO
5.0
6.0
NO
ND
ND
---
04/18/01
--
NO
NO
5.0
6.0
NO
NO
---
10/27/01
---
NO
ND
NO
NO
NO
ND
---
06/13/02
--
NO
NO
NO
NO
NO
NO
---
11/19/02
---
NO
ND
NO
NO
NO
ND
---
06/27/03
--
NO
NO
NO
NO
NO
NO
---
12/30/03
---
NO
NO
NO
NO
ND
ND
---
06/30/04
--
NO
NO
NO
NO
ND
NO
---
12/29/04
---
ND
NO
NO
NO
ND
ND
---
06/29/05
--
NO
NO
NO
NO
ND
NO
---
12/29/05
---
ND
NO
NO
NO
ND
ND
---
06/28/06
--
NO
NO
NO
NO
ND
NO
---
12/29/06
---
ND
3.0
3.3
NO
ND
ND
---
02/23/07
--
-
3.2
3.3
---
---
---
---
07/12/07
---
ND
3.3
2.9
0.31J
ND
ND
---
12/19/07
---
NO
3.0
2.7
NO
NO
NO
NO
07/08/08
---
ND
3.0
2.4
NO
ND
ND
---
12/17/08
0.33
NO
2.9
2.5
ND
NO
NO
---
07/09/09
0.33
NO
ND
NO
ND
NO
ND
NO
12/16/09
0.33
NO
2.8
2.2
ND
NO
NO
---
06/24/10
0.33
NO
1.6
NO
ND
NO
ND
---
12/13/10
0.33
NO
3.1
1.9
ND
NO
NO
---
06/20/11
0.33
NO
2.7
1.6
ND
NO
ND
---
12/05/I1
0.33
NO
2.2
1.4
ND
ND
NO
---
06/11/12
0.33
NO
1.8
1.4
ND
ND
ND
NO
12/12/12
0.33
NO
2.4
1.3
NO
ND
NO
---
05/01/13
0.33
NO
2.1
1.2
NO
NO
ND
ND
08/05/13
0.33
NO
2.0
1.3
NO
NO
NO
---
02/24/14
0.33
NO
2.2
1.8
NO
NO
NO
ND
08/12/14
0.33
NO
2.4
1.3
NO
ND
NO
NO
03/10/15
0.33
ND
2.2
1.1
NO
ND
NO
ND
08/18/15
0.33
ND
1.5
1.1
NO
ND
NO
---
02/16/16
0.33
ND
2.0
1.0
NO
ND
NO
ND
08/09/16
0.33
ND
1.9
1.0
NO
ND
NO
---
02/13/17
0.33
ND
1.9
0.901
NO
ND
NO
---
08/22/17
0.33
ND
1.9
0.961
NO
ND
NO
---
02/05/18
0.33
ND
1.6
1.1
NO
ND
NO
---
08/13/18
0.33
ND
1.9
1.1
NO
ND
NO
---
02/04/19
0.26
ND
NO
ND
NO
NO
NO
---
08/07/19
0.26
ND
NO
NO
NO
NO
NO
---
02/12/20
0.26
ND
NO
ND
NO
NO
NO
---
08/27/20
0.26
ND
2.1
1.4
NO
NO
NO
---
02/11/21
0.26
ND
1.9
0.8J
NO
NO
NO
---
08/19/21
0.33
ND
2.0
1.1
ND
NO
NO
NO
02/16/22
0.33
ND
0.8
ND
ND
NO
ND
NA
9/28/22'
0.33
NO
ND
NO
NO
NO
ND
NA
03/28/23
1 0.33
1 NO
1.7
0.441
I NO
I NO
I NO
I NA
Appendix D (Page 2 of 25)
M��K, �,.�oMy,,a.,��es-„snerea oo��men�aw.�e,�,cae�mee�na Moo,��M�-0o3. ��m���e�o.a�e,r.ao�nn, xa,�wMRaere�ae, H�s,�,�.ae�� Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-211
MW-3R
VW-4
MW-5
MW-6
NES-1
1,4-Dioxane (p-Dioxane)
08/13/18
1.9
NO
88.0
53.1
40.7
2.01
NO
---
02/04/19
1.9
NO
132
49.6
49.8
ND
NO
NO
NC21-=3 µg/L
08/07/19
1.2
NO
98.1
51.7
32.7
3.1
NO
---
02/12/20
1.2
NO
98.2
44.4
36
NO
NO
---
08/27/20
1.2
NO
113
50.0
39.3
3.0
NO
NO
02/11/21
1.2
NO
118
.111
40.6
1.SJ
NO
--
08/19/21
1.2
NO
89.7
52.8
39.8
5.2
NO
NO
02/16/22
1.7
NO
107
50.3
37.4
5.5
NO
0.92
9/28/22'
0.86
NO
98.7
59.0
40.7
7.8
NO
0.92J
03/28/23
1.7
NO
1 123
67.4
45.0
1 1.6 J, C8
NO
NO
2,4-D
06/27/03
---
---
5.9
NO
NO
NO
---
--
12/30/03
---
NO
NO
NO
NO
NO
NO
--
NC21-=70 µg/L
06/30/04
--
NO
NO
NO
NO
NO
NO
--
12/29/04
---
NO
NO
NO
NO
NO
NO
---
06/29/05
--
NO
NO
NO
NO
NO
NO
---
12/29/05
---
NO
NO
NO
NO
NO
NO
---
06/28/06
--
NO
NO
NO
NO
NO
NO
---
12/29/06
---
NO
NO
NO
NO
NO
NO
---
07/12/07
--
NO
NO
NO
NO
NO
NO
---
12/19/07
---
NO
NO
NO
NO
NO
NO
NO
04/08/08
--
NO
NO
NO
NO
NO
NO
---
12/17/08
---
NO
NO
NO
NO
NO
NO
---
07/09/09
---
NO
NO
NO
NO
NO
NO
---
12/16/09
0.11
NO
NO
NO
NO
NO
NO
---
06/24/10
0.23
NO
NO
NO
NO
NO
NO
---
12/10/10
0.22
NO
NO
NO
NO
NO
NO
---
06/20/11
0.22
NO
NO
NO
NO
NO
NO
---
12/05/11
0.22
NO
NO
NO
NO
NO
NO
---
06/11/12
0.22
NO
NO
NO
NO
NO
NO
---
12/12/12
0.22
NO
NO
NO
NO
NO
NO
---
05/01/13
0.22
NO
NO
NO
NO
NO
NO
---
08/05/13
0.22
NO
NO
NO
NO
NO
NO
---
02/24/14
0.22
NO
NO
NO
NO
NO
NO
---
08/12/14
0.22
NO
NO
NO
---
---
---
---
03/10/15
0.24
NO
NO
NO
--
---
--
---
08/18/15
0.24
NO
NO
NO
---
---
---
---
02/16/16
0.23
NO
NO
NO
--
--
--
---
08/09/16
0.24
NO
NO
NO
---
---
---
---
02/13/17
0.22
NO
NO
NO
--
--
--
---
08/22/17
0.24
NO
NO
NO
---
---
---
---
02/05/18
0.24
NO
NO
NO
--
--
--
---
02/04/19
1.6
NO
NO
NO
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/20
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
NA
NA
NA
NA
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
0.547
NO
NO
NO
NO
NO
NO
NO
2-Butanone(MEK)
12/17/08
0.96
NO
NO
NO
NO
1.21
NO
---
07/09/09
0.96
NO
NO
NO
NO
NO
NO
NO
NC21-=4,000 pg/L
12/16/09
0.96
NO
ND
NO
NO
NO
NO
---
06/24/10
0.96
NO
NO
NO
NO
NO
NO
---
12/13/10
0.96
NO
ND
NO
NO
NO
NO
---
06/20/11
0.96
NO
NO
NO
NO
NO
NO
---
12/05/11
0.96
NO
ND
NO
NO
NO
NO
---
06/11/12
0.96
NO
NO
NO
NO
NO
NO
NO
12/12/12
0.96
NO
ND
NO
NO
NO
NO
--
05/01/13
0.96
NO
NO
NO
NO
NO
NO
NO
05/08/13
0.96
NO
ND
NO
NO
NO
NO
--
02/24/14
0.96
NO
NO
NO
NO
NO
NO
NO
08/12/14
0.96
NO
ND
NO
NO
NO
NO
NO
03/10/15
0.96
NO
NO
NO
NO
NO
NO
NO
08/18/15
0.96
NO
ND
NO
NO
NO
NO
--
02/16/16
0.96
NO
NO
NO
NO
NO
NO
NO
08/09/16
0.96
NO
ND
NO
NO
NO
NO
---
02/13/17
0.96
NO
NO
NO
NO
NO
NO
---
08/22/17
0.96
NO
ND
NO
NO
NO
NO
---
02/05/18
0.96
NO
NO
NO
NO
NO
NO
---
08/13/18
0.96
NO
NO
NO
NO
NO
NO
---
02/04/19
3.3
NO
NO
NO
NO
NO
NO
--
08/07/19
3.3
NO
NO
NO
NO
NO
NO
---
02/12/20
3.3
NO
NO
NO
NO
NO
NO
---
08/27/20
3.3
NO
ND
NO
NO
NO
NO
---
02/11/21
3.3
NO
ND
NO
NO
NO
NO
--
08/19/21
4
NO
4.91
NO
ND
NO
NO
NO
02/16/22
4
NO
ND
NO
ND
NO
NO
NA
9/28/22'
4
NO
ND
NO
NO
NO
NO
NA
03/28/23
4.0
NO
ND
NO
NO
NO
NO
NA
2-Methylnaphthalene
06/24/10
5.1
NO
38.9
NO
NO
NO
NO
---
08/12/10
4.2
--
NO
---
--
--
--
---
NC21-=30 µg/L
12/13/10
---
---
---
---
---
---
---
---
06/20/11
0.3
NO
NO
NO
NO
NO
NO
---
12/05/11
---
---
---
---
06/11/12
0.28
NO
NO
NO
NO
NO
NO
---
12/12/12
---
---
---
---
05/01/13
0.28
NO
NO
NO
NO
NO
NO
---
08/05/13
---
---
---
---
02/24/14
0.28
NO
NO
NO
NO
NO
NO
---
08/12/14
---
---
---
---
03/10/15
1
NO
NO
NO
---
---
-
---
02/16/16
0.3
NO
ND
NO
---
---
---
---
02/13/17
0.3
NO
NO
NO
--
--
--
---
08/22/17
1.4
NO
ND
NO
---
---
---
---
02/05/18
1.5
NO
NO
NO
--
--
--
---
02/04/19
2.8
NO
ND
NO
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
1.7
NO
NO
NO
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
1.6
NO
NO
NO
NO
NO
NO
NA
4,4'-DDD
06/11/12
0.05
NO
NO
0.13
NO
NO
NO
---
07/19/12
0.05
---
---
NO
---
---
--
---
NC21-=0.1 µg/L
12/12/12
--
---
---
---
---
---
--
---
05/01/13
0.05
NO
NO
NO
NO
NO
NO
---
08/05/13
---
---
---
---
02/24/14
0.05
NO
NO
NO
NO
NO
NO
---
08/12/14
--
---
---
---
---
03/10/15
0.05
NO
NO
NO
---
---
---
---
02/16/16
0.05
NO
NO
NO
---
---
---
---
02/13/17
0.05
NO
NO
NO
---
---
---
---
02/05/18
0.052
NO
NO
NO
---
---
---
---
02/04/19
0.05
NO
NO
NO
---
--
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
09/27/20
NA
NA
NA
NA
NA
NA
NA
NA
2/11/2021
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
0.015
NO
NO
NO
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
1 0.017
1 NO
I NO
I NO
I NO
I ND
I NO
I NA
Appendix D (Page 3 of 25)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-111
MW-2R
MW-311
MWA
MW-5
MW-6
NES-1
4,4'DDT
06/11/12
0.05
ND
ND
0.10
ND
ND
ND
---
07/19/12
0.05
---
---
0.063 J
---
---
---
---
NC21-=0.1 µg/L
12/12/12
---
---
---
---
---
---
---
---
05/01/13
0.05
ND
ND
ND
ND
ND
ND
---
08/05/13
--
---
---
---
---
02/24/14
0.05
ND
ND
ND
ND
ND
ND
---
08/12/14
--
---
---
---
---
03/10/15
0.05
ND
ND
ND
---
---
---
---
02/16/16
0.05
ND
ND
ND
---
---
---
---
02/13/17
0.05
ND
ND
ND
---
---
---
---
02/05/18
0.052
ND
ND
ND
---
---
---
---
02/04/19
0.05
ND
ND
ND
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
NA
NA
NA
NA
NA
NA
NA
NA
9/28/221
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
0.026
ND
ND
ND
ND
ND
ND
NA
Acetone
10/27/01
---
244 B
109 B
ND
130 B
128 B
476 B
---
06/13/02
---
ND
ND
ND
ND
ND
ND
---
NC21-=6,000 µg/L
11/19/02
--
ND
ND
ND
ND
ND
ND
---
06/27/03
---
ND
ND
ND
ND
ND
ND
---
12/30/03
--
ND
ND
ND
ND
ND
ND
---
06/30/04
---
ND
ND
ND
ND
ND
ND
---
12/29/04
--
ND
ND
ND
ND
ND
ND
---
06/29/05
---
ND
ND
ND
ND
ND
ND
---
12/29/05
--
ND
ND
ND
ND
ND
ND
---
06/28/06
---
ND
ND
ND
ND
ND
ND
---
12/29/06
--
ND
ND
ND
ND
ND
ND
---
07/12/07
---
ND
ND
ND
ND
ND
ND
---
12/19/07
--
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
ND
ND
ND
ND
ND
ND
---
12/17/08
20
ND
ND
ND
ND
ND
ND
---
07/09/09
20
ND
ND
ND
ND
ND
ND
ND
12/16/09
2.2
ND
ND
ND
ND
ND
ND
---
06/24/10
2.2
ND
18.5 B
6.5 B
ND
2.2 B
ND
---
12/13/10
2.2
ND
ND
ND
ND
ND
ND
---
06/20/11
2.2
ND
ND
ND
ND
ND
2.4 B
---
12/05/11
2.2
ND
2.3 B
ND
ND
ND
ND
---
06/11/12
2.2
ND
3.5 B
ND
ND
ND
ND
ND
12/12/12
10
ND
ND
ND
ND
ND
ND
---
05/01/13
10
ND
ND
ND
ND
ND
ND
ND
08/05/13
10
ND
ND
ND
ND
ND
ND
---
02/24/14
10
ND
ND
ND
ND
ND
ND
ND
08/12/14
10
ND
ND
ND
ND
ND
ND
ND
03/10/15
10
ND
ND
ND
ND
ND
ND
ND
08/18/15
10
ND
ND
ND
ND
ND
ND
ND
02/16/16
10
ND
ND
ND
ND
ND
ND
ND
08/09/16
10
ND
ND
ND
ND
ND
ND
---
02/13/17
10
ND
ND
ND
ND
ND
ND
---
08/22/17
30
ND
ND
ND
ND
ND
ND
---
02/05/18
10
ND
ND
ND
ND
ND
ND
---
08/13/18
10
ND
ND
ND
ND
ND
ND
---
02/04/19
6.2
ND
ND
ND
ND
ND
ND
---
08/07/19
6.2
ND
ND
ND
ND
ND
ND
---
02/12/20
6.2
ND
ND
ND
ND
ND
ND
---
08/27/20
6.2
ND
ND
ND
ND
ND
ND
---
02/11/21
6.2
ND
ND
ND
ND
ND
ND
---
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
5.1
ND
ND
ND
ND
ND
ND
NA
9/28/221
5.1
ND
ND
ND
ND
ND
ND
NA
03/28/23
5.1
ND
ND
ND
ND
ND
ND
NA
Antimony
09/08/94
---
ND
ND
ND
ND
ND
ND
---
12/01/94
---
ND
ND
ND
ND
ND
ND
---
NC21-= 1 µg/L
02/09/95
---
ND
ND
ND
ND
ND
ND
---
03/02/95
---
ND
ND
ND
ND
ND
ND
---
11/15/95
---
ND
ND
ND
ND
ND
ND
---
05/28/96
---
ND
ND
ND
ND
ND
ND
---
11/22/96
---
ND
ND
ND
ND
ND
ND
---
06/17/97
---
ND
ND
ND
ND
ND
ND
---
12/01/97
---
ND
ND
ND
ND
ND
ND
---
05/20/98
---
ND
ND
ND
ND
ND
ND
---
11/19/98
---
ND
ND
ND
ND
ND
ND
---
07/21/99
---
ND
ND
ND
ND
ND
ND
---
11/16/99
---
ND
ND
ND
ND
ND
ND
---
05/10/00
---
ND
80
38
32
33
31
---
10/26/00
---
30
ND
ND
ND
ND
ND
---
04/18/01
---
ND
ND
ND
ND
ND
ND
---
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
---
ND
ND
ND
ND
ND
ND
---
11/19/02
---
ND
ND
ND
ND
ND
ND
---
06/27/03
---
ND
ND
ND
ND
ND
ND
---
12/30/03
---
ND
ND
ND
ND
ND
ND
---
06/30/04
---
ND
ND
ND
ND
ND
ND
---
12/29/04
---
ND
ND
ND
ND
ND
ND
---
06/29/05
---
ND
ND
ND
ND
ND
ND
---
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
---
ND
ND
ND
ND
ND
ND
---
12/29/06
---
ND
ND
ND
ND
ND
ND
---
07/12/07
---
ND
ND
ND
ND
ND
ND
---
12/19/07
---
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
ND
ND
ND
ND
ND
ND
---
12/17/08
2.6
ND
ND
ND
ND
ND
ND
---
07/09/09
2.6
ND
ND
ND
ND
ND
ND
ND
12/16/09
2.6
ND
ND
ND
ND
ND
ND
---
06/24/10
2.6
ND
ND
ND
2.9J
ND
ND
---
12/13/10
2.6
ND
ND
3.0J
ND
2.81
ND
---
06/20/11
5
ND
ND
ND
ND
6.0
ND
---
12/05/11
5
ND
ND
ND
ND
ND
ND
---
06/11/12
5
ND
ND
ND
ND
ND
ND
ND
12/12/12
5
ND
ND
ND
ND
ND
ND
--
05/01/13
5
ND
ND
ND
ND
ND
ND
ND
08/05/13
5
ND
ND
ND
ND
ND
ND
--
02/24/14
5
8.8
ND
ND
ND
ND
ND
ND
08/12/14
5
ND
10.5
8.0
ND
ND
ND
--
03/10/15
3.8
ND
7.1
6.5
3.9J
ND
ND
---
08/18/15
3.8
ND
6.2
4.8J
4.11
ND
ND
---
02/16/16
3.8
ND
9.9
6.5
4.3J
ND
ND
---
08/09/16
3.8
ND
7.7
ND
ND
ND
ND
---
02/13/17
3.9
ND
ND
ND
ND
ND
ND
---
08/22/17
3.9
ND
ND
ND
ND
ND
ND
---
02/05/18
3.9
ND
ND
ND
ND
ND
ND
---
08/13/18
3.9
ND
ND
ND
ND
ND
ND
---
02/04/19
3.9
ND
ND
ND
ND
ND
ND
---
08/07/19
3
ND
ND
ND
ND
ND
ND
---
02/12/20
3
ND
ND
ND
ND
ND
ND
---
08/27/20
3
ND
ND
ND
ND
ND
ND
---
02/11/21
3
ND
ND
ND
ND
ND
ND
---
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
3
ND
ND
ND
ND
ND
ND
NA
9/28/221
3
ND
ND
ND
ND
ND
ND
NA
03/28/23
1 4.30
1 ND
ND
ND
ND
ND
ND
NA
Appendix D (Page 4 of 25)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-111
MW-211
MW-311
MWA
MW-5
MW-6
NES-1
Arsenic
09/08/94
---
NO
ND
ND
ND
NO
NO
---
12/01/94
---
NO
NO
NO
NO
NO
NO
---
NC21-= 10 µg/L
02/09/95
---
NO
ND
NO
NO
NO
NO
---
03/02/95
---
NO
NO
NO
NO
NO
NO
---
11/15/95
---
NO
ND
NO
NO
NO
NO
---
05/28/96
---
NO
NO
NO
NO
NO
NO
---
11/22/96
---
NO
ND
NO
NO
NO
NO
--
06/17/97
---
6.01
15.0
ND
NO
NO
NO
---
12/01/97
---
NO
5.0J
ND
NO
NO
NO
---
05/20/98
---
NO
ND
ND
NO
NO
NO
---
11/19/98
---
NO
ND
ND
NO
NO
NO
---
07/21/99
---
NO
ND
ND
NO
NO
NO
---
11/16/99
---
NO
ND
ND
NO
NO
NO
---
05/30/00
---
NO
ND
ND
NO
NO
NO
---
10/26/00
---
NO
ND
ND
NO
NO
NO
---
04/18/01
---
NO
ND
ND
NO
NO
NO
---
10/27/01
---
NO
ND
ND
NO
NO
NO
---
06/13/02
---
NO
ND
ND
NO
NO
NO
---
11/19/02
---
NO
ND
ND
NO
NO
NO
---
06/27/03
---
NO
ND
ND
NO
NO
NO
---
12/30/03
---
NO
ND
ND
NO
NO
NO
---
06/30/04
---
NO
ND
ND
NO
NO
NO
---
12/29/04
---
NO
ND
NO
NO
NO
NO
---
06/29/05
---
NO
NO
NO
NO
NO
NO
---
12/29/05
---
NO
ND
NO
NO
NO
NO
---
06/28/06
---
NO
NO
NO
NO
NO
NO
--
12/29/06
---
2.01
ND
NO
NO
NO
NO
--
07/12/07
---
NO
NO
NO
NO
NO
NO
--
12/19/07
---
NO
4.1J
NO
NO
NO
NO
NO
07/08/08
---
NO
4.9J
NO
NO
NO
NO
--
12/17/08
2.7
NO
ND
NO
NO
NO
NO
--
07/09/09
2.7
NO
13.5
10.9
5.6J
NO
4.0J
NO
12/16/09
2.7
NO
10.6
6.4J
5.01
ND
3.61
---
06/24/10
2.7
NO
11.8
8.11
8.2 J
3.31
3.1 J
---
08/12/10
2.7
--
---
7.2J
---
---
---
---
08/31/10
2.7
--
15.4
---
---
---
---
---
12/13/10
2.7
ND
4.9J
2.7J
5.4J
ND
ND
---
06/20/11
5
ND
ND
ND
ND
ND
ND
---
12/05/11
5
ND
ND
ND
ND
ND
ND
---
06/11/12
5
ND
5.4J
ND
NO
NO
NO
NO
12/12/12
5
NO
NO
NO
NO
NO
NO
---
05/01/13
5
NO
NO
NO
NO
NO
NO
NO
08/05/13
5
NO
NO
5.6J
ND
ND
ND
--
02/24/14
5
ND
6.4J
NO
NO
NO
NO
NO
08/12/14
5
NO
NO
NO
NO
NO
NO
---
03/10/15
2.5
4.11
5.4J
NO
NO
3.11
3.2J
---
08/18/15
2.5
NO
5.11
NO
NO
NO
NO
---
02/16/16
2.5
NO
NO
NO
NO
NO
NO
---
08/09/16
2.5
NO
NO
NO
ND
NO
NO
---
02/13/17
5
NO
NO
NO
ND
NO
NO
---
08/22/17
5
NO
NO
NO
ND
NO
NO
---
02/05/18
5
NO
NO
NO
ND
NO
NO
---
08/13/18
5
NO
5.41
NO
ND
NO
NO
---
02/04/19
5
NO
5.7J
NO
ND
NO
NO
---
08/07/19
4.7
NO
NO
NO
ND
NO
NO
---
02/12/20
4.7
NO
NO
NO
ND
NO
NO
--
08/27/20
4.7
NO
NO
NO
ND
NO
NO
--
02/11/21
4.7
4.91
10.01
NO
ND
NO
NO
--
08/19/21
NR
NO
NO
NO
ND
NO
NO
NO
02/16/22
4.7
NO
11.5
11.2
9.0
5.2
5.9
NA
9/28/22'
4.7
NO
NO
NO
NO
NO
NO
NA
03/28/23
4.40
NO
NO
NO
NO
NO
NO
NA
Barium
09/08/94
---
NO
270
NO
NO
830
860
---
12/01/94
---
NO
NO
NO
NO
NO
NO
--
NC21-=700 µg/L
02/09/95
---
NO
NO
NO
NO
510
NO
---
03/02/95
--
NO
NO
NO
NO
NO
NO
---
11/15/95
---
NO
NO
NO
NO
NO
NO
---
05/28/96
--
NO
NO
NO
NO
NO
NO
---
11/22/96
---
NO
82
30
NO
15
NO
---
06/17/97
--
200
320
37
17
210
31
---
12/01/97
---
61.0
180
43
46
220
33
---
05/20/98
--
30.0
150
45
13
180
22
---
11/19/98
---
48.0
120
42
NO
380
12
---
07/21/99
--
NO
NO
NO
NO
NO
NO
---
11/16/99
---
NO
NO
NO
NO
NO
NO
---
05/10/00
--
NO
NO
NO
NO
NO
NO
---
04/18/01
---
NO
NO
NO
NO
NO
NO
---
10/26/01
--
NO
NO
NO
NO
NO
NO
---
10/27/01
---
NO
NO
NO
NO
NO
NO
---
06/13/02
--
NO
NO
NO
NO
NO
NO
---
11/19/02
---
NO
NO
NO
NO
NO
NO
---
06/27/03
--
NO
NO
NO
NO
NO
NO
---
12/30/03
---
NO
NO
NO
NO
NO
NO
---
06/30/04
--
NO
NO
NO
NO
NO
NO
---
12/29/04
---
NO
NO
NO
NO
NO
NO
---
06/29/05
--
NO
NO
NO
NO
NO
NO
---
12/29/05
---
NO
NO
NO
NO
NO
NO
---
06/28/06
--
NO
NO
NO
NO
NO
NO
---
12/29/06
---
5.2 J
120
64.9
1.5 J
64.1
1.8 J
---
07/12/07
--
2.5 J
129
65.7 J
1.11
77.0 J
1.31
---
12/19/07
---
2.8 B
99.2
50.0 B
1.4 B
49.6 B
1.7 B
87.8
07/08/08
---
5.81
102
58.4 J
1.1 B
57.91
1.2 B
--
12/17/08
0.2
2.7 B
92.9 J
53.1 B
1.26
55.5 J
1.1 B
---
07/09/09
0.2
4.6 B
121
63.4 B
0.37 B
81.4 B
0.94 B
72.4 B
12/16/09
0.2
2.9 B
108
62.8 B
0.61 B
56.8 B
0.87 B
---
06/24/10
0.2
2.5 B
115 B
61.1 B
1.6 B
93.5 B
1.4 B
---
12/13/10
0.2
4.3 B
122
67.91
1.3 B
90.6 J
1.5 B
---
06/20/11
5
NO
108
70.7J
ND
84.7J
NO
---
12/05/11
5
NO
118
73.01
NO
90.6J
NO
---
06/11/12
5
NO
138
65.2J
NO
76.4J
NO
61.3J
12/12/12
5
NO
113
64.7J
ND
73.61
NO
---
05/01/13
5
NO
118
69.11
ND
84.2J
NO
81.21
08/05/13
5
NO
ill
65.1J
NO
95.61
NO
---
02/24/14
5
NO
93.8J
44.8J
ND
139
NO
NO
08/12/14
5
NO
125
66.4J
ND
121
NO
---
03/10/15
2.5
3.0J
109
61.81
ND
116
ND
---
08/18/15
2.5
4.41
119
63.1J
ND
81.31
NO
---
02/16/16
2.5
5.2 J
123
72.7 J
3.0 J
126
NO
---
08/09/16
2.5
4.51
123
73.3J
ND
109
NO
---
02/13/17
2.5
7.8 J
112
68.3 J
NO
151
5.6 J
---
08/22/17
2.5
NO
102
64.5J
NO
99.91
NO
---
02/05/18
2.5
8.01
117
73.5J
NO
161
NO
---
08/13/18
2.5
3.8J
116
67.6J
NO
103
NO
---
02/04/19
2.5
NO
104
44.3
NO
110
NO
---
08/07/19
1
5.4
113
73.8
1.2 J
95.1
1.91
---
02/12/20
1
3.6 J
110
56.2
2.5 J
147
1.6 J
---
08/27/20
3.5
4.5J
127
83.2
NO
128
NO
---
02/11/21
3.5
5.3
116
74.4
NO
161
NO
---
08/19/21
3.5
6.2
119
72.7
NO
131
NO
72.3
02/16/22
3.5
4.4
ill
61.2
NO
78.3
NO
NA
9/28/22'
3.5
NO
110
79.5
NO
42.5
NO
NA
03/28/23
1 0.736
1 2.241
1 107
1 75.7
1 1.111
206
1.96J
NA
Appendix D (Page 5 of 25)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-18
MW-28
MW-38
MWA
MW-5
MW-6
NES-1
Benzene
09/08/94
---
ND
ND
ND
ND
ND
ND
---
12/01/94
---
ND
ND
ND
ND
ND
ND
---
NC21-= 1 µg/L
02/09/95
---
ND
ND
ND
ND
ND
ND
---
03/02/95
---
ND
ND
ND
ND
ND
ND
---
11/15/95
---
ND
ND
ND
ND
ND
ND
---
05/28/96
---
ND
ND
ND
ND
ND
ND
---
11/22/96
---
ND
ND
ND
ND
ND
ND
---
06/17/97
---
ND
ND
ND
ND
ND
ND
---
12/01/97
---
ND
ND
ND
ND
ND
ND
---
05/20/98
---
ND
ND
ND
ND
ND
ND
---
11/19/98
---
ND
ND
ND
ND
ND
ND
---
07/21/99
---
ND
ND
ND
ND
ND
ND
---
11/16/99
---
ND
ND
ND
ND
ND
ND
---
05/10/00
---
ND
ND
ND
ND
ND
ND
---
10/26/00
---
ND
ND
ND
ND
ND
ND
---
04/18/01
---
ND
ND
ND
ND
ND
ND
---
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
---
ND
ND
ND
ND
ND
ND
---
11/19/02
---
ND
ND
ND
ND
ND
ND
---
06/27/03
---
ND
ND
ND
ND
ND
ND
---
12/30/03
---
ND
ND
ND
ND
ND
ND
---
06/30/04
---
ND
ND
ND
ND
ND
ND
---
12/29/04
---
ND
ND
ND
ND
ND
ND
---
06/29/05
---
ND
ND
ND
ND
ND
ND
---
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
---
ND
ND
ND
ND
ND
ND
---
12/29/06
---
ND
1.5
ND
ND
ND
ND
---
02/23/07
---
--
1.2
---
---
---
---
---
07/12/07
---
ND
1.9
ND
ND
ND
ND
---
12/19/07
---
ND
1.8
0.48J
0.26J
ND
ND
ND
07/08/08
---
ND
1.4
0.511
0.32)
ND
ND
---
12/17/08
0.25
ND
1.7
0.54J
ND
ND
ND
---
07/09/09
0.25
ND
1.7
0.341
ND
ND
ND
ND
12/16/09
0.25
ND
1.7
0.60J
0.29J
ND
ND
---
06/24/10
0.25
ND
0.77J
0.49J
0.33J
ND
ND
---
12/13/10
0.25
ND
1.8
0.591
0.37J
ND
ND
---
02/08/11
0.25
--
1.4
---
---
---
---
---
06/20/11
0.25
ND
1.7
0.601
0.39J
ND
ND
---
12/05/11
0.25
ND
1.4
0.69J
0.40J
ND
ND
---
06/11/12
0.25
ND
ND
0.511
ND
ND
ND
ND
12/12/12
0.25
ND
1.6
0.731
0.321
ND
ND
---
01/30/13
0.25
ND
1.4
--
---
---
ND
ND
05/01/13
0.25
ND
1.3
0.561
0.271
ND
ND
ND
08/05/13
0.25
ND
1.6
0.64J
0.441
ND
ND
---
02/24/14
0.25
ND
1.4
ND
ND
ND
ND
ND
08/12/14
0.25
ND
1.7
0.61J
0.251
ND
ND
ND
03/10/15
0.25
ND
1.3
0.541
ND
ND
ND
ND
08/18/15
0.25
ND
1.5
0.661
0.321
ND
ND
---
02/16/16
0.25
ND
1.3
0.561
ND
ND
ND
ND
08/09/16
0.25
ND
1.4
0.53J
0.291
ND
ND
ND
02/13/17
0.25
ND
1.2
0.61J
ND
ND
ND
ND
08/22/17
0.25
ND
1.3
0.54J
ND
ND
ND
ND
02/05/18
0.25
ND
1.2
0.67J
ND
ND
ND
ND
08/13/18
0.25
ND
1.3
0.611
0.291
ND
ND
ND
02/04/19
0.15
ND
1.6
ND
ND
ND
ND
ND
08/07/19
0.15
ND
1.7
0.541
0.301
ND
ND
ND
02/12/20
0.15
ND
1.5
ND
ND
ND
ND
ND
08/27/20
0.15
ND
1.9
0.491
ND
ND
ND
ND
02/11/21
0.15
ND
1.8
ND
ND
ND
ND
---
08/19/21
0.30
ND
2.1
0.49J
ND
0.38J
ND
ND
02/16/22
0.34
ND
1.5
ND
ND
ND
ND
ND
9/28/221
0.34
ND
1.9
0.47J
0.37J
ND
ND
ND
03/28/23
0.34
ND
1.6
ND
ND
ND
ND
ND
Bemo(g,h,i)perylene
06/20/11
0.4
ND
ND
ND
ND
ND
1.4J
---
12/05/11
---
---
---
---
NC2L=200 µg/L
06/11/12
0.38
ND
ND
ND
ND
ND
ND
---
12/12/12
---
---
---
---
05/01/13
0.38
ND
ND
ND
ND
ND
ND
---
08/05/13
---
---
---
---
02/24/14
0.38
ND
ND
ND
ND
ND
ND
---
08/12/14
---
---
---
---
03/10/15
0.5
ND
ND
ND
-
---
02/16/16
0.4
ND
ND
ND
---
---
---
---
02/13/17
0.4
ND
ND
ND
--
--
--
---
08/22/17
2.1
ND
ND
ND
---
---
---
---
02/05/18
2.2
ND
ND
ND
--
--
--
---
02/04/19
1.8
ND
ND
ND
---
---
---
---
02/16/22
2.6
ND
ND
ND
NA
NA
NA
NA
9/28/221
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
1 2.8
1 ND
ND
I ND
ND
ND
I ND
NA
Appendix D (Page 6 of 25)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Beryllium
09/08/94
---
ND
ND
ND
ND
ND
ND
---
12/01/94
---
ND
ND
ND
ND
4.0
ND
---
NC21-=4µg/L
02/09/95
---
ND
ND
ND
ND
ND
ND
---
03/02/95
---
ND
ND
ND
ND
2.0
ND
---
11/15/95
---
ND
ND
ND
ND
ND
ND
---
05/28/96
---
ND
ND
ND
ND
6.0
ND
---
11/22/96
---
ND
ND
ND
ND
3.0
ND
---
06/17/97
---
2.0
3.0
ND
ND
1.0
ND
---
12/01/97
---
ND
ND
ND
ND
ND
ND
---
05/20/98
---
ND
ND
ND
ND
ND
ND
--
11/19/98
---
ND
ND
ND
ND
2.0
ND
-
07/21/99
---
ND
ND
ND
ND
ND
ND
-
11/16/99
---
ND
ND
ND
ND
ND
ND
-
05/10/00
---
ND
ND
ND
ND
ND
ND
-
10/26/00
---
ND
ND
ND
ND
ND
ND
-
04/18/01
---
ND
12.0
ND
ND
ND
ND
--
10/27/01
---
ND
ND
ND
ND
ND
ND
--
06/13/02
---
ND
ND
ND
ND
ND
ND
--
11/19/02
---
ND
ND
ND
ND
ND
ND
--
06/27/03
---
ND
ND
ND
ND
ND
ND
--
12/30/03
---
ND
ND
ND
ND
ND
ND
--
06/30/04
---
ND
ND
ND
ND
ND
ND
--
12/29/04
---
ND
ND
ND
ND
ND
ND
--
06/29/05
---
ND
ND
ND
ND
ND
ND
--
12/29/05
---
ND
ND
ND
ND
ND
ND
--
06/28/06
---
ND
ND
ND
ND
ND
ND
--
12/29/06
---
ND
ND
ND
ND
ND
ND
--
07/12/07
---
ND
ND
ND
ND
ND
ND
--
12/19/07
---
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
ND
ND
ND
ND
ND
ND
--
12/17/08
0.1
ND
ND
ND
ND
0.14J
ND
--
07/09/09
0.1
ND
0.181
0.22J
0.17J
ND
ND
0.23J
12/16/09
0.1
ND
0.15J
0.171
0.151
0.25J
ND
--
06/24/10
0.1
ND
ND
0.27J
0.16J
ND
ND
--
12/13/10
0.1
ND
ND
ND
ND
ND
ND
---
06/20/11
1
ND
ND
ND
ND
ND
ND
--
12/05/11
1
ND
ND
ND
ND
ND
ND
---
06/11/12
1
ND
ND
ND
ND
ND
ND
ND
12/12/12
1
ND
ND
ND
ND
ND
ND
---
05/01/13
1
ND
ND
ND
ND
ND
ND
ND
08/05/13
1
ND
ND
ND
ND
ND
ND
---
02/24/14
1
ND
ND
ND
ND
ND
ND
ND
08/12/14
1
ND
ND
ND
ND
ND
ND
---
03/10/15
0.5
ND
ND
ND
ND
ND
ND
---
08/18/15
0.5
ND
ND
ND
ND
ND
ND
---
02/16/16
0.5
ND
ND
ND
ND
ND
ND
---
08/09/16
0.5
ND
ND
ND
ND
ND
ND
---
02/13/17
0.5
ND
ND
ND
ND
0.57J
ND
---
08/22/17
0.5
ND
ND
ND
ND
ND
ND
---
02/05/18
0.5
ND
ND
ND
ND
ND
ND
---
08/13/18
0.5
ND
ND
ND
ND
ND
ND
---
02/04/19
0.5
ND
ND
ND
ND
ND
ND
---
08/07/19
0.2
ND
ND
ND
ND
ND
ND
---
02/12/20
0.2
0.27J
ND
ND
ND
ND
0.21J
---
08/27/20
0.7
ND
ND
ND
ND
ND
ND
---
02/11/21
0.7
ND
ND
ND
ND
ND
ND
---
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
0.7
ND
ND
ND
ND
ND
ND
NA
9/28/22'
0.7
ND
ND
ND
ND
ND
ND
NA
03/28/23
0.330
ND
I ND
ND
ND
0.542J
ND
NA
Beta-BHC
06/11/12
0.05
ND
ND
0.16
ND
ND
ND
---
07/19/12
0.05
---
--
ND
---
---
---
---
NC21-=0.02 pg/L
12/12/12
---
---
---
---
---
---
---
---
05/01/13
0.05
ND
ND
ND
ND
ND
ND
---
08/05/13
---
---
---
---
02/24/14
0.05
ND
0.052
ND
ND
ND
ND
---
04/15/14
0.05
---
ND
---
---
---
---
---
08/12/14
---
--
--
---
03/10/15
0.1
ND
ND
ND
---
---
---
---
02/16/16
0.1
ND
ND
ND
--
--
--
---
02/13/17
0.1
ND
ND
ND
---
---
---
---
02/05/18
0.1
ND
ND
ND
--
--
--
---
02/04/19
0.1
ND
ND
ND
---
---
---
---
08/07/19
0.1
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
0.044
ND
ND
ND
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
0.049
ND
ND
ND
ND
ND
ND
NA
Bis(2-Ethylhexl)phtha late
02/24/14
0.79
2.61
ND
ND
ND
ND
ND
ND
04/15/14
0.79
ND
ND
ND
ND
ND
ND
ND
NC21-=3 µg/L
08/12/14
---
---
---
---
---
---
---
---
03/30/15
0.5
ND
ND
ND
---
---
---
---
02/16/16
0.9
ND
ND
ND
---
---
---
---
02/13/17
0.9
ND
ND
ND
---
---
---
---
08/22/17
2.3
ND
ND
ND
---
---
---
---
02/05/18
2.4
ND
ND
ND
---
---
---
---
02/04/19
1.4
ND
ND
ND
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
1 3.7
ND
ND
ND
ND
ND
ND
NA
Appendix D (Page 7 of 25)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-SR
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Bromomethane
12/17/08
0.29
NO
NO
0.581
NO
NO
NO
---
07/09/09
0.29
NO
NO
NO
NO
NO
ND
NO
NC21-= 10 pg/L
12/16/09
0.29
NO
NO
NO
NO
NO
ND
---
06/24/10
0.29
NO
NO
NO
NO
NO
NO
---
12/13/10
0.29
NO
NO
NO
NO
NO
NO
---
06/20/11
0.29
NO
NO
NO
NO
NO
NO
---
12/05/11
0.29
NO
NO
NO
NO
NO
NO
NO
06/11/12
0.29
NO
NO
NO
NO
NO
NO
NO
12/12/12
0.29
NO
NO
NO
NO
NO
NO
---
05/01/13
0.29
NO
NO
NO
NO
NO
NO
NO
08/05/13
0.29
NO
NO
NO
NO
NO
NO
--
02/24/14
0.29
NO
NO
NO
NO
NO
NO
NO
08/12/14
0.29
NO
NO
NO
NO
NO
NO
NO
03/10/15
0.29
NO
NO
NO
NO
NO
NO
NO
08/18/15
0.29
NO
NO
NO
NO
NO
NO
---
02/16/16
0.29
NO
NO
NO
NO
NO
NO
NO
08/09/16
0.29
NO
NO
NO
NO
NO
NO
---
02/13/17
0.29
NO
NO
NO
NO
NO
NO
---
08/22/17
0.29
NO
NO
NO
NO
NO
NO
---
02/05/18
0.29
NO
ND
NO
NO
NO
NO
---
08/13/18
0.29
NO
NO
NO
NO
NO
NO
---
02/04/19
0.62
NO
ND
NO
NO
NO
NO
---
08/07/19
0.62
NO
NO
NO
NO
NO
NO
---
02/12/20
0.62
NO
ND
NO
NO
NO
NO
---
08/27/20
0.62
NO
NO
NO
NO
NO
NO
---
02/11/21
0.62
NO
ND
NO
NO
NO
NO
---
08/19/21
NR
NO
NO
NO
NO
NO
NO
NO
02/16/22
1.7
NO
NO
NO
NO
NO
NO
NA
9/28/221
2
NO
NO
NO
NO
NO
NO
NA
03/28/23
1.7
ND
ND
NO
NO
ND
ND
NA
Cadmium
09/08/94
---
NO
NO
NO
NO
NO
4.0
--
12/01/94
---
ND
NO
NO
NO
ND
ND
---
NC21-=2µ9/L
02/09/95
--
NO
NO
NO
NO
NO
NO
--
03/02/95
---
ND
NO
NO
NO
ND
ND
---
11/15/95
--
NO
NO
NO
NO
NO
NO
---
05/28/96
---
ND
NO
NO
NO
ND
ND
---
11/22/96
--
NO
NO
NO
NO
NO
NO
---
06/17/97
---
ND
3.0
1.0
NO
ND
NO
---
12/01/97
--
NO
2.0
NO
NO
NO
NO
---
05/20/98
---
ND
NO
NO
NO
ND
ND
---
11/19/98
--
NO
NO
NO
NO
NO
NO
---
07/21/99
---
ND
NO
NO
NO
ND
ND
---
11/16/99
--
NO
3.0
3.0
NO
2.0
NO
---
05/10/00
---
5.0
NO
NO
NO
ND
ND
---
10/26/00
--
NO
2.0
NO
NO
NO
NO
---
04/18/01
---
NO
11.0
NO
NO
ND
NO
---
10/27/01
--
NO
NO
NO
NO
NO
NO
---
06/13/02
---
ND
2.0
NO
NO
ND
NO
---
11/19/02
--
2.0
2.0
NO
NO
2.0
NO
---
06/27/03
---
NO
NO
NO
NO
ND
ND
---
12/30/03
--
NO
1.0
NO
NO
NO
NO
---
06/30/04
---
NO
NO
NO
ND
NO
ND
---
12/29/04
--
NO
NO
NO
NO
ND
NO
---
06/29/05
---
ND
ND
NO
ND
NO
ND
---
12/29/05
--
NO
NO
NO
NO
ND
NO
---
06/28/06
---
ND
ND
NO
ND
ND
ND
---
12/29/06
--
NO
NO
NO
NO
ND
NO
---
07/12/07
---
ND
ND
NO
ND
ND
ND
---
12/19/07
--
NO
NO
NO
NO
ND
NO
NO
07/08/08
---
ND
ND
NO
NO
ND
ND
---
12/17/08
0.5
NO
NO
NO
NO
ND
NO
---
07/09/09
0.5
ND
1.4
NO
NO
ND
ND
NO
12/16/09
0.5
NO
NO
NO
NO
NO
NO
---
06/24/10
0.5
NO
ND
NO
NO
NO
ND
---
12/13/10
0.5
NO
NO
NO
NO
NO
NO
---
06/20/11
1
NO
ND
NO
NO
NO
ND
---
12/05/11
1
NO
NO
NO
NO
NO
NO
---
06/11/12
1
NO
ND
NO
NO
NO
ND
NO
12/12/12
1
NO
NO
NO
NO
NO
NO
---
05/01/13
1
NO
ND
NO
NO
NO
ND
NO
08/05/13
1
NO
NO
NO
NO
NO
NO
---
02/24/14
1
NO
ND
NO
NO
NO
ND
NO
08/12/14
1
NO
NO
NO
NO
NO
NO
---
03/10/15
0.5
NO
ND
NO
NO
NO
ND
---
08/18/15
0.5
NO
ND
NO
NO
NO
NO
---
02/16/16
0.5
NO
ND
NO
NO
NO
ND
---
08/09/16
0.5
NO
NO
NO
NO
NO
NO
---
02/13/17
0.5
NO
ND
NO
NO
NO
ND
---
08/22/17
0.5
NO
NO
NO
NO
NO
NO
---
02/05/18
0.5
NO
ND
ND
NO
NO
ND
---
08/13/18
0.5
NO
NO
ND
NO
NO
NO
---
02/04/19
0.5
NO
ND
ND
NO
NO
NO
---
08/07/19
0.4
NO
NO
NO
0.48J
NO
NO
---
02/12/20
0.4
ND
ND
ND
0.69J
NO
ND
---
08/27/20
0.4
ND
NO
NO
NO
ND
NO
---
02/11/21
0.4
ND
0.7J
0.7J
1.10
ND
ND
---
08/19/21
NR
ND
NO
NO
NO
ND
NO
NO
02/16/22
0.4
ND
0.46
ND
0.43
0.47
NO
9/28/221
0.4 0.4
NO
0.54J
NO
0.67J
0.941
ND
NA
03/28/23
0.479
NO
NO
NO
NO
NO
NO
NA
Carbon disulfide
06/17/97
---
NO
64.0
NO
NO
NO
ND
---
12/01/97
---
NO
5.0
8.0
NO
NO
NO
---
NC21-=700 µg/L
05/20/98
---
NO
7.5
6.2
NO
NO
NO
---
11/19/98
---
NO
NO
NO
NO
NO
NO
---
07/21/99
---
NO
ND
NO
NO
NO
NO
---
11/16/99
---
NO
NO
NO
NO
NO
NO
---
05/10/00
---
NO
ND
NO
NO
NO
NO
---
10/26/00
---
NO
NO
NO
NO
NO
NO
---
04/18/01
---
NO
ND
NO
NO
NO
NO
---
10/27/01
---
NO
NO
NO
NO
NO
NO
---
06/13/02
---
NO
ND
NO
NO
NO
NO
---
11/19/02
---
NO
NO
NO
NO
NO
NO
---
06/27/03
---
NO
ND
NO
NO
NO
NO
---
12/30/03
---
NO
NO
NO
NO
NO
NO
---
06/30/04
---
NO
ND
NO
NO
NO
NO
---
12/29/04
---
NO
NO
NO
NO
NO
NO
---
06/29/05
---
NO
ND
NO
NO
NO
NO
---
12/29/05
---
NO
NO
NO
NO
NO
ND
---
06/28/06
---
NO
ND
NO
NO
NO
NO
---
12/29/06
---
NO
NO
NO
NO
NO
ND
---
07/12/07
---
NO
ND
NO
NO
NO
NO
---
12/19/07
---
NO
NO
NO
NO
NO
ND
NO
07/08/08
---
NO
ND
NO
NO
NO
NO
---
12/17/08
1.2
NO
ND
NO
NO
NO
NO
---
07/09/09
1.2
NO
ND
NO
NO
NO
ND
NO
12/16/09
1.2
NO
NO
NO
NO
NO
NO
--
06/24/10
1.2
NO
ND
NO
NO
NO
ND
---
12/13/10
1.2
NO
NO
NO
NO
NO
NO
---
06/20/11
1.2
NO
NO
NO
NO
NO
NO
---
12/05/11
1.2
NO
NO
NO
NO
NO
NO
---
06/11/12
1.2
NO
NO
NO
NO
NO
NO
NO
12/12/12
1.2
NO
NO
NO
NO
NO
NO
--
05/01/13
1.2
NO
NO
NO
NO
NO
NO
NO
08/05/13
1.2
NO
NO
NO
NO
NO
NO
---
02/24/14
1.2
NO
ND
NO
NO
NO
NO
NO
08/12/14
1.2
NO
NO
NO
NO
NO
NO
NO
03/10/15
1.2
NO
ND
NO
NO
NO
NO
NO
08/18/15
1.2
NO
NO
NO
NO
NO
NO
---
02/16/16
1.2
NO
ND
NO
NO
NO
NO
NO
08/09/16
1.2
NO
ND
NO
NO
NO
NO
---
02/13/17
1.2
NO
ND
NO
NO
NO
NO
---
08/22/17
1.2
NO
NO
NO
NO
NO
NO
---
02/05/18
1.2
NO
NO
NO
NO
NO
NO
---
08/13/18
1.2
NO
NO
NO
NO
NO
NO
---
02/04/19
0.4
NO
NO
NO
NO
NO
NO
---
08/07/19
0.4
NO
NO
NO
NO
NO
NO
---
02/12/20
0.4
NO
NO
NO
NO
NO
NO
---
08/27/20
0.4
NO
NO
NO
ND
NO
NO
---
02/11/21
0.4
NO
NO
NO
NO
NO
NO
---
08/19/21
NR
NO
NO
NO
ND
NO
NO
NO
02/16/22
0.73
NO
NO
NO
NO
NO
NO
NA
9/28/221
0.36
NO
NO
NO
NO
NO
NO
NA
03/28/23
1 0.36
1 NO
I ND
I NO
I NO
I ND
I ND
I NA
Appendix D (Page 8 of 25)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-111
VW-2R
MW-3R
VW-4
MW-5
MW-6
NES-1
Chlorobenzene
09/08/94
---
ND
10.0
7.0
ND
ND
ND
---
12/01/94
---
ND
ND
7.0
ND
ND
ND
---
NC21-=50 µg/L
02/09/95
---
ND
13.0
8.0
6.0
ND
ND
---
03/02/95
---
ND
12.0
9.0
ND
ND
ND
---
11/15/95
---
ND
14.0
8.0
9.0
ND
ND
---
05/28/96
---
ND
11.0
9.0
10.0
ND
ND
---
11/22/96
---
ND
15.0
ND
11.0
ND
ND
---
06/17/97
---
ND
19.0
11.0
14.0
ND
ND
---
12/01/97
---
ND
17.0
9.0
14.0
ND
ND
---
05/20/98
---
ND
20.0
8.6
12.0
ND
ND
---
11/19/98
---
ND
17.2
9.2
10.0
ND
ND
---
07/21/99
---
ND
14.0
10.0
11.0
ND
ND
---
11/16/99
---
ND
16.0
10.0
8.0
ND
ND
---
05/10/00
---
ND
17.0
11.0
10.0
ND
ND
---
10/26/00
---
ND
16.0
12.0
9.0
ND
ND
---
04/18/01
---
ND
16.0
13.0
6.0
ND
ND
---
10/27/01
---
ND
17.0
12.0
9.0
ND
ND
---
06/13/02
---
ND
16.0
11.0
8.0
ND
ND
---
11/19/02
---
ND
18.0
15.0
9.0
ND
ND
---
06/27/03
---
ND
17.7
13.3
7.4
ND
ND
---
12/30/03
---
ND
20.0
15.0
6.1
ND
ND
---
06/30/04
---
ND
18.0
15.0
9.9
ND
ND
---
12/29/04
---
ND
19.0
16.0
9.4
ND
ND
---
06/29/05
---
ND
15.0
13.0
8.0
ND
ND
---
12/29/05
---
ND
18.0
16.0
5.0
ND
ND
---
06/28/06
---
ND
16.5
10.8
7.8
ND
ND
---
12/29/06
---
ND
17.0
17.0
4.2
ND
ND
---
07/12/07
---
ND
17.0
16.0
ND
ND
ND
--
12/19/07
---
ND
17.3
16.9
4.7
ND
ND
ND
07/08/08
---
ND
17.2
17.4
6.5
ND
ND
--
12/17/08
0.23
ND
15.9
15.6
2.6J
ND
ND
--
07/09/09
0.23
ND
16.1
17.2
6.1
ND
ND
ND
12/16/09
0.23
ND
15.5
17.7
4.8
ND
ND
--
06/24/10
0.23
ND
8.3
15.7
6.3
ND
ND
---
12/13/10
0.23
ND
17.7
18.2
6.4
ND
ND
---
06/20/11
0.23
ND
16.3
17.2
6.7
ND
ND
---
12/05/11
0.23
ND
14.2
17.0
5.8
ND
ND
--
06/11/12
0.23
ND
12.0
14.8
4.4
ND
ND
ND
12/12/12
0.23
ND
15.8
17.9
4.5
ND
ND
--
05/01/13
0.23
ND
14.0
16.6
3.0J
ND
ND
ND
08/05/13
0.23
ND
14.4
15.9
4.6
ND
ND
---
02/24/14
0.23
ND
16.3
2.5J
1.4J
ND
ND
ND
08/12/14
0.23
ND
15.6
18.3
3.6
ND
ND
ND
03/10/15
0.23
ND
16.0
17.0
2.1J
ND
ND
ND
08/18/15
0.23
ND
12.8
17.6
4.3
ND
ND
---
02/16/16
0.23
ND
13.5
16.4
1.51
ND
ND
ND
08/09/16
0.23
ND
13.5
16.9
4.2
ND
ND
---
02/13/17
0.23
ND
13.6
18.0
1.3J
ND
ND
---
08/22/17
0.23
ND
14.2
19.9
1.2
ND
ND
---
02/05/18
0.23
ND
13.5
17.3
0.54J
ND
ND
---
08/13/18
0.23
ND
14.5
22.2
3.4
ND
ND
---
02/04/19
0.23
ND
13.6
0.35J
1.3
ND
ND
---
08/07/19
0.23
ND
10.2
16.9
ND
ND
ND
---
02/12/20
0.23
ND
ND
ND
2.0
0.32J
ND
---
08/27/20
0.23
ND
16.1
17.5
4.1
ND
ND
---
02/11/21
0.23
ND
15.1
7.3
2.2
ND
ND
---
08/19/21
0.30
ND
15.4
15.7
4.2
ND
ND
ND
02/16/22
0.28
ND
11.4
4.5
1.3
0.49
ND
NA
9/28/221
0.28
ND
15.4
17.7
ND
ND
ND
NA
03/28/23
0.28
ND
15.3
12.0
ND
ND
ND
NA
Chloroethane
12/01/97
---
ND
5.0
2.0
2.0
ND
ND
---
05/20/98
---
ND
ND
ND
ND
ND
ND
--
NC21-=3,000 µg/L
11/19/98
---
ND
ND
ND
ND
ND
ND
---
07/21/99
--
ND
ND
ND
ND
ND
ND
---
11/16/99
---
ND
ND
ND
ND
ND
ND
---
05/30/00
--
ND
ND
ND
ND
ND
ND
---
10/26/00
---
ND
ND
ND
ND
ND
ND
---
04/18/01
--
ND
ND
ND
ND
ND
ND
---
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
--
ND
ND
ND
ND
ND
ND
---
11/19/02
---
ND
ND
ND
ND
ND
ND
---
06/27/03
--
ND
ND
ND
ND
ND
ND
---
12/30/03
---
ND
ND
ND
ND
ND
ND
---
06/30/04
--
ND
ND
ND
ND
ND
ND
---
12/29/04
---
ND
ND
ND
ND
ND
ND
---
06/29/05
--
ND
ND
ND
ND
ND
ND
---
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
--
ND
ND
ND
ND
ND
ND
---
12/29/06
---
ND
2.2
1.9
ND
ND
ND
---
07/12/07
--
ND
ND
ND
ND
ND
ND
---
12/19/07
---
ND
1.9
1.9
1.5
ND
ND
ND
07/08/08
---
ND
2.2J
2.51
1.81
ND
ND
---
12/17/08
0.54
ND
1.6J
ND
ND
ND
ND
---
07/09/09
0.54
ND
ND
ND
3.8J
ND
ND
ND
12/16/09
0.54
ND
ND
2.2J
2.0J
ND
ND
---
06/24/30
0.54
ND
ND
2.1J
2.0J
ND
ND
---
12/13/10
0.54
ND
1.8J
2.0J
1.7J
ND
ND
---
06/20/11
0.54
ND
1.2J
2.2J
2.0J
ND
ND
---
12/05/11
0.54
ND
1.3J
2.0J
1.7J
ND
ND
---
06/11/12
0.54
ND
ND
ND
ND
ND
ND
ND
12/12/12
0.54
ND
ND
ND
ND
ND
ND
---
05/01/13
0.54
ND
ND
1.9J
2.7J
ND
ND
ND
08/05/13
0.54
ND
ND
2.0J
2.2J
ND
ND
---
02/24/14
0.54
ND
1.11
0.82J
ND
ND
ND
ND
08/12/14
0.54
ND
1.11
1.501
1.11
ND
ND
ND
03/10/15
0.54
ND
1.01
1.801
0.811
ND
ND
ND
08/18/15
0.54
ND
1.2J
2.0J
3.7J
ND
ND
---
02/16/16
0.54
ND
1.11
1.8J
0.79J
ND
ND
ND
08/09/16
0.54
ND
0.68J
2.4J
1.5J
ND
ND
---
02/13/17
0.54
ND
0.76J
1.6J
1.11
ND
ND
---
08/22/17
0.54
ND
1.3J
2.0J
1.6J
ND
ND
---
02/05/18
0.54
ND
1.7J
1.7J
0.68J
ND
ND
---
08/13/18
0.54
ND
1.2J
2.4J
1.40J
ND
ND
---
02/04/19
0.49
ND
1.3
ND
0.79J
ND
ND
---
08/07/19
0.49
ND
0.94J
1.9
1.3
ND
ND
---
02/12/20
0.49
ND
1.6
1.3
1.5
ND
ND
---
08/27/20
0.49
ND
0.87J
1.5
1.1
ND
ND
---
02/11/21
0.49
ND
1.2
1.0 J, V1
1.3 v1
ND
ND
---
08/19/21
0.70
ND
0.92J
1.4
1.2
ND
ND
ND
02/16/22
0.65
ND
1.6
1.4
1.5
ND
ND
NA
9/28/221
0.65
ND
ND
ND
ND
ND
ND
NA
03/28/23
1 0.65
1 ND
0.901
0.86J
0.791
I ND
I ND
I NA
Appendix D (Page 9 of 25)
M��K, �,.�oMy,,a.,��es-„snerea oo��men�aw.�e,�,r,ae�m�e�na Moo,��M�-0o3. ��n����e�o.a�e,rraoza ran, xa,�wMRaere�ae, H�s,�,�.ae�� Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-211
MW-3R
VW-4
MW-5
MW-6
NES-1
Chloromethane
07/09/09
0.11
NO
ND
ND
ND
NO
NO
NO
12/16/09
0.11
NO
ND
NO
NO
NO
NO
---
NC21-=3 µg/L
06/24/10
0.11
NO
ND
NO
NO
NO
0.11J
---
12/13/10
0.11
NO
ND
NO
NO
NO
NO
---
06/20/11
0.11
NO
ND
NO
NO
NO
NO
---
12/05/11
0.11
NO
ND
NO
NO
NO
NO
---
06/11/12
0.11
NO
ND
NO
NO
NO
NO
NO
12/12/12
0.11
NO
ND
NO
NO
NO
NO
---
05/01/13
0.11
NO
ND
NO
NO
NO
NO
NO
08/05/13
0.11
NO
ND
NO
NO
NO
NO
---
02/24/14
0.11
NO
ND
NO
NO
NO
NO
NO
08/12/14
0.11
NO
ND
NO
NO
NO
NO
NO
03/10/15
0.11
NO
ND
NO
NO
NO
NO
NO
08/18/15
0.11
NO
ND
NO
NO
NO
NO
---
02/16/16
0.11
NO
ND
NO
NO
NO
NO
---
08/09/16
0.11
NO
ND
NO
NO
NO
NO
---
02/13/17
0.11
0.20 B
ND
0.22 B
0.23 B
0.19 B
0.32 B
---
08/22/17
0.11
NO
ND
NO
NO
NO
NO
---
02/05/18
0.11
NO
ND
NO
NO
NO
NO
---
08/13/18
0.11
NO
ND
NO
NO
NO
NO
--
02/04/19
0.39
NO
ND
NO
NO
NO
NO
---
08/07/19
0.39
NO
ND
NO
NO
NO
NO
---
02/12/20
0.39
NO
ND
NO
NO
NO
NO
---
08/27/20
0.39
NO
ND
NO
NO
NO
NO
---
02/11/21
0.39
NO
ND
NO
NO
NO
NO
NO
08/19/21
NR
NO
ND
NO
NO
NO
NO
NO
02/16/22
0.54
NO
ND
NO
NO
NO
NO
NA
9/28/221
0.54
NO
NO
NO
NO
NO
NO
NA
03/28/23
0.54
NO
ND
NO
NO
NO
ND
NA
Chromium
09/08/94
--
8.0
44.0
NO
6.0
48.0
80.0
---
12/01/94
---
14.0
ND
NO
NO
18.0
NO
---
NC21-=10 µg/L
02/09/95
--
14.0
ND
NO
10.0
NO
NO
---
03/02/95
---
ND
ND
NO
NO
NO
NO
---
11/15/95
--
13.0
13.0
NO
NO
NO
NO
---
05/28/96
---
33.0
ND
NO
NO
NO
NO
---
11/22/96
--
3.0
ND
NO
NO
NO
3.0
---
06/17/97
---
11.0
43.0
NO
3.1
2.0
6.0
---
12/01/97
--
29.0
ND
NO
NO
NO
NO
---
05/20/98
---
10.0
3.0
NO
NO
12.0
NO
---
11/19/98
--
17.0
3.0
NO
NO
5.0
NO
---
07/21/99
---
NO
ND
NO
NO
ND
NO
---
11/16/99
--
NO
ND
NO
NO
NO
NO
---
05/10/00
---
NO
ND
NO
NO
ND
NO
---
10/26/00
--
NO
ND
NO
NO
NO
NO
---
04/18/01
---
NO
12.0
NO
NO
ND
NO
---
10/27/01
--
NO
ND
NO
NO
NO
NO
---
06/13/02
---
NO
ND
NO
NO
ND
NO
---
11/19/02
--
NO
ND
NO
NO
NO
NO
---
06/27/03
---
NO
ND
NO
NO
NO
ND
---
12/30/03
--
NO
NO
NO
NO
NO
NO
---
06/30/04
---
NO
NO
NO
NO
NO
ND
---
12/29/04
--
NO
NO
NO
NO
NO
NO
---
06/29/05
---
NO
NO
NO
NO
NO
ND
---
12/29/05
--
NO
NO
NO
NO
NO
NO
---
06/28/06
---
NO
NO
NO
NO
NO
ND
---
12/29/06
--
NO
NO
NO
NO
NO
NO
---
07/12/07
---
NO
NO
NO
NO
NO
ND
---
12/19/07
---
NO
2.0 B
NO
NO
NO
NO
1.1 B
07/08/08
---
NO
0.54J
0.58J
NO
NO
NO
---
12/17/08
0.4
0.731
1.81
0.96 J
NO
0.96 J
0.70 J
---
07/09/09
0.4
1.2 J
2.4 J
1.1 J
1.61
0.68 J
0.53 J
4.8 J
12/16/09
0.4
1.3J
NO
ND
NO
0.951
NO
---
06/24/10
0.4
1.1 B
3.5 B
2.8 B
2.4 B
1.2 B
1.4 B
---
12/13/10
0.4
2.5 J
1.3 J
1.8 J
0.69 J
0.571
1.2 J
---
06/20/11
5
NO
ND
NO
NO
NO
ND
---
12/05/11
5
NO
NO
NO
NO
NO
NO
---
06/11/12
5
NO
8.6J
NO
NO
NO
ND
ND
12/12/12
5
NO
5.2J
NO
NO
NO
NO
--
05/01/13
5
NO
ND
NO
NO
NO
ND
ND
08/05/13
5
NO
NO
NO
NO
NO
NO
---
02/24/14
5
NO
ND
NO
NO
NO
ND
NO
08/12/14
5
NO
NO
NO
NO
NO
NO
---
03/10/15
2.5
NO
ND
NO
NO
NO
ND
---
08/18/15
2.5
NO
2.7J
NO
NO
NO
6.7J
---
02/16/16
2.5
NO
ND
NO
ND
NO
ND
---
08/09/16
2.5
2.8 B
2.8 B
NO
ND
NO
NO
---
02/13/17
2.5
NO
2.6J
NO
ND
NO
ND
---
08/22/17
2.5
NO
NO
NO
ND
NO
NO
---
02/05/18
2.5
NO
ND
NO
ND
NO
NO
---
08/13/18
2.5
NO
NO
NO
ND
NO
NO
---
02/04/19
2.5
NO
NO
NO
ND
ND
NO
---
08/07/19
1
NO
NO
NO
ND
NO
NO
---
02/12/20
1
1.5J
NO
NO
1.11
NO
NO
---
08/27/20
3.7
NO
NO
NO
NO
NO
NO
---
02/11/21
3.7
4.1J
4 J
NO
NO
NO
NO
---
08/19/21
NR
NO
NO
NO
NO
NO
NO
NO
02/16/22
3.7
NO
NO
NO
NO
NO
NO
NA
9/28/221
3.7
NO
NO
NO
NO
NO
NO
NA
03/28/23
1 1.40
1 NO
2.48J
I ND
I ND
I ND
I ND
I NA
Appendix D (Page 10 of 25)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-111
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Cobalt
09/08/94
---
ND
ND
ND
ND
ND
ND
---
12/01/94
---
11.0
ND
13.0
16.0
22.0
ND
---
NC21-=1µ8/1-
02/09/95
---
20.0
14.0
ND
48.0
39.0
ND
---
03/02/95
---
16.0
21.0
ND
29.0
121.0
ND
---
11/15/95
---
20.0
21.0
ND
ND
27.0
ND
---
05/28/96
---
30.0
16.0
ND
ND
122
ND
---
11/22/96
---
6.0
13.0
ND
4.7
93.0
ND
---
06/17/97
---
130
38.0
ND
6.0
45.0
3.0
---
12/01/97
---
32.0
21.0
ND
12.0
36.0
4.0
---
05/20/98
---
15.0
16.0
2.0
9.0
too
3.0
---
11/19/98
---
21.0
16.0
2.0
7.0
180
3.0
---
07/21/99
---
ND
16.0
ND
ND
100
ND
---
11/16/99
---
ND
15.0
ND
ND
38.0
ND
---
05/10/00
---
ND
17.0
ND
ND
61.0
ND
---
10/26/00
---
ND
15.0
ND
ND
ND
ND
---
04/18/01
---
ND
27.0
ND
ND
74.0
ND
---
10/27/01
---
ND
12.0
ND
ND
47.0
ND
---
06/13/02
---
ND
14.0
ND
ND
251
ND
---
11/19/02
---
ND
10.0
ND
ND
57.0
ND
---
06/27/03
---
ND
15.0
ND
ND
75.0
ND
---
12/30/03
---
ND
17.0
ND
ND
52.0
ND
---
06/30/04
---
ND
16.0
ND
ND
31.0
ND
---
12/29/04
---
ND
11.0
ND
ND
46.0
ND
---
06/29/05
---
ND
11.0
ND
ND
43.0
ND
---
12/29/05
---
ND
12.0
ND
ND
30.0
ND
---
06/28/06
---
ND
ND
ND
ND
72.5
ND
---
12/29/06
---
ND
11.4
ND
ND
37.5
ND
---
07/12/07
---
ND
11.8
ND
2.7
58.4
ND
---
12/19/07
---
2.5B
ND
ND
2.0B
103
2.6B
8.06
07/08/08
---
10.38
12.16
2.06
9.0 B
130
4.8 B
--
12/17/08
0.6
2.1 B
11.8 B
2.3 B
3.6 B
43.7
1.6 B
--
07/09/09
0.6
ND
6.2J
ND
ND
too
ND
2.2J
12/16/09
0.6
ND
4.7J
ND
ND
6.6J
ND
--
06/24/10
0.6
ND
16.3
ND
ND
25.0
ND
---
12/13/10
0.6
2.5B
15.5
ND
ND
(129}
(ND}
---
06/20/11
5
ND
14.2
ND
ND
81.8
ND
---
12/05/11
5
ND
12.7
ND
ND
146
ND
---
01/25/12
5
--
---
---
---
47.5
---
---
06/11/12
5
ND
14.2
ND
ND
101
ND
ND
12/12/12
5
ND
11.3
ND
ND
113
ND
---
05/01/13
5
ND
24.3
ND
ND
34.0
ND
ND
08/05/13
5
ND
24.7
ND
ND
50.9
ND
---
02/24/14
5
ND
18.4
ND
ND
9.6J
ND
ND
08/12/14
5
ND
9.4J
ND
ND
46.3
ND
---
03/10/15
2.5
ND
8.7J
ND
ND
39.2
ND
---
08/18/15
2.5
ND
9.3J
ND
ND
116
ND
---
02/16/16
2.5
ND
10.0
ND
ND
13.1
ND
---
08/09/16
2.5
ND
10.01
ND
ND
144
ND
---
02/13/17
2.5
ND
8.3J
ND
ND
78.7
ND
---
08/22/17
2.5
ND
7.4J
ND
ND
51.1
ND
---
02/05/18
2.5
ND
8.3J
ND
ND
172
ND
---
08/13/18
2.5
ND
10.7
ND
ND
97.7
ND
---
02/04/19
2.5
ND
9.9
ND
ND
24
ND
---
08/07/19
1.1
ND
11.3
ND
ND
127
ND
ND
02/12/20
1.1
ND
7.5
ND
ND
11.4
ND
2.11
08/27/20
3.6
ND
9.7
ND
ND
88.7
ND
ND
02/11/21
3.6
ND
10.8
ND
ND
18.6
ND
3.81
08/19/21
3.6
ND
11.1
ND
ND
91.0
ND
ND
02/16/22
3.6
ND
16.2
6.2
7.6
40.2
3.8
0.26
9/28/221
3.6
ND
17.0
7.7
11.8
37.9
ND
ND
03/28/23
1 0.840
1 ND
1 12.8
1 0.894J
2.08J
9.821
I ND
I ND
Appendix D (Page 11 of 25)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-111
MW-211
MW-3R
MW-4
MW-5
MW-6
NES-1
Copper
09/08/94
---
NO
ND
ND
ND
NO
660
---
12/01/94
---
NO
ND
NO
NO
NO
NO
---
NC21-= 1,000 pg/L
02/09/95
---
NO
ND
NO
NO
NO
NO
---
03/02/95
---
NO
ND
NO
NO
NO
NO
---
11/15/95
---
NO
ND
NO
NO
NO
NO
---
05/28/96
---
NO
ND
NO
NO
NO
NO
---
11/22/96
---
NO
ND
32.0
13.0
100
NO
---
06/17/97
---
34.0
350
13.0
37.0
28.0
77.0
---
12/01/97
---
19.0
72.0
14.0
88.0
15.0
34.0
---
05/20/98
---
12.0
4&0
380
41.0
53.0
28.0
---
11/19/98
---
10.0
ND
410
28.0
53.0
14.0
---
07/21/99
---
NO
ND
NO
NO
NO
NO
---
11/16/99
---
NO
ND
NO
NO
NO
NO
---
05/10/00
---
NO
ND
NO
NO
NO
NO
---
10/26/00
---
NO
ND
NO
NO
NO
NO
---
04/18/01
---
NO
ND
NO
NO
NO
NO
---
10/27/01
---
NO
ND
NO
NO
NO
NO
---
06/13/02
---
NO
ND
NO
NO
NO
NO
---
11/19/02
---
NO
ND
NO
NO
NO
NO
---
06/27/03
---
NO
ND
NO
NO
NO
NO
---
12/30/03
---
NO
ND
NO
NO
NO
NO
---
06/30/04
---
NO
ND
NO
NO
NO
NO
---
12/29/04
---
NO
ND
NO
NO
NO
NO
---
06/29/05
---
NO
ND
NO
NO
NO
NO
---
12/29/05
---
NO
ND
NO
NO
NO
NO
---
06/28/06
---
NO
ND
NO
NO
NO
NO
---
12/29/06
---
NO
ND
11.3
5.501
10.4
1.90 B
---
07/12/07
---
NO
NO
13.4
7.90
2.6J
NO
--
12/19/07
---
2.0 B
NO
8.6 B
3.8 B
7.0 B
0.73 B
5.8 B
07/08/08
---
0.64 J
NO
12.1
3.7 J
8.5 J
NO
--
12/17/08
0.3
0.801
13.6
10.2
3.9 J
11.9
0.37 J
--
07/09/09
0.3
NO
NO
6.3J
NO
5.7J
NO
8.81
12/16/09
0.3
NO
NO
9.2J
1.6J
5.7J
NO
--
06/24/10
0.3
NO
NO
10
1.2J
5.1J
NO
---
12/13/10
0.3
1.1 B
NO
13.6
5.8 J
5.6 J
0.59 B
---
06/20/11
5
NO
NO
15.3
8.11
8.7J
NO
---
12/05/11
5
NO
NO
16.9
10.01
7.6J
NO
---
06/11/12
5
NO
10.7
12.2
6.3J
7.4J
ND
ND
12/12/12
5
ND
ND
11.6
8.5J
10.4
NO
---
05/01/13
5
NO
NO
13.6
5.81
9.6J
NO
ND
08/05/13
5
NO
NO
14.3
NO
10.2
NO
---
02/24/14
5
NO
NO
12.2
NO
5.1J
NO
NO
08/12/14
5
NO
NO
10.5
NO
NO
NO
---
03/10/15
2.5
NO
NO
8.7J
NO
15.5
NO
---
08/18/15
2.5
NO
NO
6.7J
5.61
10.1
ND
---
02/16/16
2.5
ND
ND
7.8J
NO
5.1J
NO
---
08/09/16
2.5
NO
NO
5.4J
ND
7.81
NO
---
02/13/17
2.5
NO
NO
6.8J
4.3J
14.5
9.4J
---
08/22/17
2.5
NO
NO
6.5J
NO
5.7J
4.4J
---
02/05/18
2.5
NO
6.5 J
9.0 J
5.51
12.4
2.6 J
---
08/13/18
2.5
NO
5.51
12.2
3.7J
48.8
NO
---
02/04/19
2.5
NO
3.0J
5.4
8.0
4.3J
NO
---
08/07/19
2.1
NO
3.5 J
6.0
7.2
4.4 J
2.3 J
---
02/12/20
2.1
NO
NO
9.8
12.7
3.3J
NO
---
08/27/20
4.3
NO
ND
5.3
13.5
5.6
NO
---
02/11/21
4.3
NO
ND
84.8
9.6
NO
NO
---
08/19/21
4.3
13.7
ND
ND
NO
NO
NO
ND
02/16/22
4.3
7.9
ND
ND
NO
NO
NO
NA
9/28/221
4.3
NO
ND
NO
NO
NO
NO
NA
03/28/23
3.68
NO
ND
5.96J
8.83J
17.1
NO
NA
Cyanide
07/09/09
5
NO
NO
NO
NO
46.9
NO
NO
09/28/09
5
--
---
---
---
NO
---
---
NC21-=70 µg/L
12/16/09
---
--
---
---
---
---
--
--
06/24/10
5
NO
NO
NO
NO
NO
NO
---
12/13/10
---
--
---
---
---
06/20/11
5
NO
NO
NO
NO
NO
NO
---
12/05/11
--
--
---
---
06/11/12
5
NO
6.4J
ND
NO
8.71
ND
---
12/12/12
--
--
---
---
05/01/13
5
NO
NO
ND
NO
NO
ND
---
08/05/13
---
--
---
---
---
02/24/14
5
NO
NO
NO
NO
NO
ND
NO
08/12/14
5
NO
NO
NO
NO
NO
ND
NO
03/10/15
5
9.5 B
7.5 B
8.5 B
8.8 B
11.8 B
6.6 B
---
02/16/16
4
NO
NO
NO
---
--
--
---
02/13/17
4
NO
NO
NO
---
---
---
---
08/22/17
4
NO
NO
NO
--
--
--
---
02/05/18
4
NO
ND
NO
---
---
---
---
02/04/19
6
NO
ND
NO
--
--
--
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
NA
NA
NA
NA
NA
NA
NA
NA
9/28/221
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
6.0
NO
NO
NO
NO
NO
NO
NA
Delta-BHC
06/11/12
0.05
NO
NO
0.090
NO
NO
NO
---
07/19/12
0.05
---
---
NO
---
---
---
---
NC21-=NE
12/12/12
--
---
---
---
---
---
--
---
05/01/13
0.05
NO
NO
NO
NO
NO
NO
---
08/05/13
---
---
---
---
02/24/14
0.05
NO
NO
NO
NO
NO
NO
---
08/12/14
--
---
---
---
---
03/10/15
0.01
NO
NO
NO
---
---
---
---
02/16/16
0.05
NO
NO
NO
---
---
---
---
02/13/17
0.05
NO
NO
NO
---
---
---
---
02/05/18
0.052
NO
NO
NO
---
---
---
---
02/04/19
0.05
NO
NO
NO
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
0.013
NO
NO
NO
NA
NA
NA
NA
9/28/221
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
0.014
NO
NO
NO
NO
NO
NO
NA
Appendix D (Page 12 of 25)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
VW-4
MW-5
MW-6
NES-1
Dibenz(a,h)anthracene
06/20/11
0.55
ND
ND
ND
ND
ND
1.51
---
12/05/11
---
---
---
---
NC2L=0.005 µg/L
06/11/12
0.55
ND
ND
ND
ND
ND
ND
---
12/12/12
---
---
---
---
05/01/13
0.55
ND
ND
ND
ND
ND
ND
---
08/05/13
---
---
---
---
02/24/14
0.55
ND
ND
ND
ND
ND
ND
---
08/12/14
--
---
---
---
---
03/10/15
0.5
ND
ND
ND
---
---
---
---
02/16/16
0.6
ND
ND
ND
---
---
---
---
02/13/17
0.6
ND
ND
ND
---
---
---
---
08/22/17
2
ND
ND
ND
---
---
---
---
02/05/18
2.1
ND
ND
ND
---
---
---
---
02/04/19
1.9
ND
ND
ND
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
2.7
ND
ND
ND
NA
NA
NA
NA
9/28/221
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
3.0
ND
ND
ND
ND
ND
ND
NA
Dichlorodifluoromethane
02/05/18
0.21
ND
0.36J
ND
---
---
---
---
02/04/19
0.23
ND
ND
ND
--
--
--
---
NC21-=1,000 µg/L
02/11/21
0.23
ND
ND
ND
---
---
---
---
02/16/22
0.35
ND
ND
ND
NA
NA
NA
NA
9/28/221
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
0.35
ND
6.2
ND
ND
ND
ND
NA
Diethyl phthalate
02/04/19
2
ND
7.1J
ND
---
---
---
---
NC21-=6,000 µg/L
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
NA
NA
NA
NA
NA
NA
NA
NA
9/28/221
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
2.0
ND
ND
ND
ND
ND
ND
NA
Dinoseb
03/10/15
0.061
ND
ND
0.111
---
---
---
---
02/16/16
0.058
ND
ND
ND
---
---
---
---
NC21-=7µg/L
02/13/17
0.057
ND
ND
ND
---
---
---
---
08/22/17
0.062
ND
ND
ND
---
---
---
---
02/05/18
0.061
ND
ND
ND
---
---
---
---
02/04/19
1.2
ND
ND
ND
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
NA
NA
NA
NA
NA
NA
NA
NA
9/28/221
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
0.250
ND
ND
ND
ND
ND
ND
NA
Endosulfan 1
02/04/19
0.05
---
0.078
0.19
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
NC2L=40 µg/L
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/20
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
0.016
ND
ND
ND
NA
NA
NA
NA
9/28/221
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
0.015
ND
ND
I ND
I ND
ND
ND
NA
Appendix D (Page 13 of 25)
M��K, �,.�oMy,,a.,��es-„snerea oo��men�aw.�e,�,rae�m�e�na Moo,��M�-0o3. ��n����eco.a�e,�.aoza ran, xa,�wMRaere�ae, H�s,�,�.ae�� Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-111
MW-211
MW-311
MW-4
MW-5
MW-6
NES-1
Endrin aldehyde
06/11/12
0.05
NO
ND
0.14
NO
NO
NO
---
12/12/12
0.05
NO
NO
NO
NO
NO
ND
---
NC21-=2µ9/1-
05/01/13
0.05
NO
ND
NO
NO
NO
NO
---
08/05/13
0.05
NO
NO
NO
NO
NO
ND
---
02/24/14
0.05
NO
ND
NO
NO
NO
NO
---
08/12/14
0.05
NO
NO
NO
---
---
---
---
03/10/15
0.05
NO
ND
NO
---
---
---
---
08/18/15
0.05
NO
NO
NO
---
---
---
---
02/16/16
0.05
NO
ND
NO
---
---
---
---
08/09/16
0.05
NO
NO
NO
---
---
---
---
02/13/17
0.05
NO
ND
NO
---
---
---
---
02/05/18
0.052
NO
ND
NO
---
---
---
---
02/04/19
0.05
NO
ND
NO
---
---
---
---
8/7/2019
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
0.015
NO
NO
NO
NA
NA
NA
NA
9/28/221
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
0.016
NO
NO
NO
NO
ND
NO
NA
Ethylbemene
12/17/08
0.3
NO
0.31J
ND
NO
NO
NO
---
07/09/09
0.3
ND
NO
NO
NO
ND
ND
NO
NC21-=600 µg/L
12/16/09
0.3
NO
NO
NO
NO
NO
NO
--
06/24/10
0.3
ND
ND
NO
NO
ND
ND
---
12/13/30
0.3
NO
NO
NO
NO
NO
NO
---
06/20/11
0.3
NO
ND
NO
NO
NO
ND
---
12/05/11
0.3
NO
NO
NO
NO
NO
NO
---
06/11/12
0.3
NO
ND
NO
NO
NO
ND
NO
12/12/12
0.3
NO
NO
NO
NO
NO
NO
--
05/01/13
0.3
NO
ND
NO
NO
NO
ND
NO
08/05/13
0.3
NO
NO
NO
NO
NO
NO
---
02/24/14
0.3
NO
ND
NO
NO
NO
ND
NO
08/12/14
0.3
NO
NO
NO
NO
NO
NO
NO
03/10/15
0.3
NO
ND
ND
NO
NO
ND
ND
08/18/15
0.3
NO
NO
NO
NO
NO
NO
---
02/16/16
0.3
NO
ND
ND
NO
NO
NO
ND
08/09/16
0.3
NO
NO
NO
NO
NO
NO
---
02/13/17
0.3
NO
ND
ND
NO
NO
NO
---
08/22/17
0.3
NO
NO
NO
NO
NO
NO
---
02/05/18
0.3
NO
ND
ND
NO
NO
NO
---
08/13/18
0.3
NO
NO
NO
NO
NO
NO
---
02/04/19
0.26
NO
NO
ND
NO
NO
NO
---
08/07/19
0.26
NO
NO
NO
NO
NO
NO
---
02/12/20
0.26
NO
NO
ND
NO
NO
NO
---
08/27/20
0.26
NO
NO
NO
NO
NO
NO
---
02/11/21
0.26
NO
NO
ND
NO
NO
NO
---
08/19/21
NR
NO
NO
NO
NO
NO
NO
NO
02/16/22
0.3
NO
0.4
0.57
NO
NO
NO
NA
9/28/221
0.3
NO
NO
NO
NO
NO
NO
NA
03/28/23
0.30
NO
NO
NO
NO
NO
ND
NA
Fluorene
06/24/10
3.8
NO
4.3J
NO
NO
NO
NO
--
08/12/10
3.1
---
NO
---
---
---
---
---
NC21-=300 µg/L
12/13/10
---
---
---
---
---
---
---
---
06/20/11
0.2
NO
NO
NO
NO
NO
NO
---
12/05/11
---
---
---
---
06/11/12
0.21
NO
NO
NO
NO
NO
NO
---
12/12/12
---
---
---
---
05/01/13
0.21
NO
NO
NO
NO
NO
NO
---
08/05/13
---
---
--
---
02/24/14
0.21
NO
NO
NO
NO
ND
NO
---
08/12/14
---
---
---
---
03/10/15
1
NO
NO
NO
---
---
---
---
02/16/16
0.2
NO
NO
NO
---
---
---
---
02/13/17
0.2
NO
NO
NO
---
---
---
---
08/22/17
1.6
NO
NO
NO
---
---
---
---
02/05/18
1.6
NO
NO
NO
---
---
---
---
02/04/19
3
NO
NO
NO
---
---
---
---
02/16/22
1.9
NO
NO
NO
NA
NA
NA
NA
9/28/221
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
2.1
ND
ND
NO
NO
ND
NO
NA
gamma-BHC(Lindane)
06/27/03
---
NO
0.085
NO
NO
NO
NO
---
12/30/03
---
ND
ND
NO
ND
ND
NO
---
NC21-=0.03 µg/L
06/30/04
--
NO
ND
NO
NO
NO
NO
---
12/29/04
---
ND
ND
NO
NO
ND
NO
---
06/29/05
--
NO
ND
NO
NO
NO
NO
---
12/29/05
---
ND
ND
NO
NO
ND
NO
---
06/28/06
--
NO
ND
NO
NO
NO
NO
---
12/29/06
---
ND
ND
NO
NO
ND
NO
---
07/12/07
--
NO
ND
NO
NO
NO
NO
---
12/19/07
---
ND
ND
NO
NO
ND
NO
NO
07/08/08
---
NO
ND
NO
NO
NO
NO
---
12/17/08
0.05
ND
ND
NO
NO
ND
NO
---
07/09/09
0.05
NO
NO
NO
NO
NO
NO
---
12/16/09
0.01
ND
ND
NO
NO
ND
NO
---
06/24/10
0.00021
NO
NO
0.052
NO
NO
NO
---
08/12/10
0.0002
---
---
NO
---
---
---
---
12/13/10
0.0002
NO
NO
0.013J
NO
NO
NO
---
06/20/11
0.0002
ND
NO
0.066
ND
ND
NO
---
07/28/11
0.0002
---
--
NO
---
---
---
---
12/05/11
0.05
ND
ND
NO
ND
ND
NO
---
06/11/12
0.05
NO
ND
NO
NO
NO
NO
---
12/12/12
0.05
ND
ND
NO
ND
ND
NO
---
05/01/13
0.05
NO
ND
NO
NO
NO
NO
---
08/05/13
0.05
ND
ND
NO
ND
ND
NO
---
02/24/14
0.05
NO
ND
NO
NO
NO
NO
---
08/12/14
0.05
ND
ND
NO
---
---
---
---
03/10/15
0.05
NO
ND
NO
--
---
--
---
08/18/15
0.05
NO
ND
NO
---
---
---
---
02/16/16
0.05
NO
ND
NO
--
--
--
---
08/09/16
0.05
ND
ND
NO
---
---
---
---
02/13/17
0.05
NO
NO
NO
--
--
--
---
02/05/18
0.052
ND
ND
NO
---
---
---
---
02/04/19
0.05
NO
NO
NO
---
---
--
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
0.011
NO
ND
NO
NA
NA
NA
NA
9/28/221
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
1 0.012
1 NO
I NO
I NO
I NO
I NO
I NO
I NA
Appendix D (Page 14 of 25)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-111
MW-211
MW-3R
VW-4
MW-5
MW-6
NES-1
Heptachlor
06/27/03
---
NO
0.03
0.17
ND
NO
NO
---
12/30/03
---
NO
ND
ND
NO
NO
NO
--
NC21-=0.008 µel-
06/30/04
---
NO
NO
NO
NO
NO
NO
--
12/29/04
---
NO
ND
NO
NO
NO
NO
-
06/29/05
---
NO
NO
NO
NO
NO
NO
--
12/29/05
---
NO
ND
NO
NO
NO
NO
-
06/28/06
---
NO
ND
NO
NO
NO
NO
--
12/29/06
---
NO
ND
NO
NO
NO
NO
-
07/12/07
---
NO
NO
NO
NO
NO
NO
--
12/19/07
---
NO
ND
NO
NO
NO
NO
NO
07/08/08
---
NO
NO
NO
NO
NO
NO
--
12/17/08
0.05
NO
ND
NO
NO
NO
NO
--
07/09/09
0.05
NO
NO
NO
NO
NO
NO
---
12/16/09
0.02
NO
ND
NO
NO
NO
NO
---
06/24/10
0.0015
NO
NO
NO
NO
NO
NO
---
12/13/10
0.05
NO
ND
NO
NO
NO
NO
---
06/20/11
0.05
NO
ND
NO
NO
NO
NO
---
12/05/11
0.05
NO
0.062
NO
NO
NO
NO
---
01/25/12
0.05
---
ND
---
---
---
---
---
06/11/12
0.05
NO
ND
NO
NO
NO
NO
---
12/12/12
0.05
NO
NO
NO
NO
NO
NO
---
05/01/13
0.05
NO
ND
NO
NO
NO
NO
---
08/05/13
0.05
NO
NO
NO
NO
NO
NO
---
02/24/14
0.05
NO
ND
NO
NO
NO
NO
---
08/12/14
0.05
NO
NO
NO
---
---
---
---
03/10/15
0.05
NO
ND
NO
---
---
---
---
08/18/15
0.05
NO
ND
NO
---
---
---
---
02/16/16
0.05
NO
ND
NO
---
---
---
---
08/09/16
0.05
NO
ND
NO
---
---
---
---
02/13/17
0.05
NO
ND
NO
---
---
---
---
02/05/18
0.052
NO
ND
NO
---
---
---
---
02/04/19
0.05
NO
ND
NO
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
0.018
NO
ND
NO
NA
NA
NA
NA
9/28/221
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
0.020
NO
ND
NO
NO
NO
NO
NA
Indeno(1,2,3-cd)pyrene
06/20/11
0.29
NO
ND
NO
NO
NO
1.3J
---
12/05/11
---
---
--
---
---
NC2L=0.05 pg/L
06/11/12
0.29
NO
NO
NO
NO
NO
NO
---
12/12/12
---
---
--
---
---
05/01/13
0.29
NO
NO
NO
NO
NO
NO
---
08/05/13
--
---
--
---
---
02/24/14
0.29
NO
NO
NO
NO
ND
NO
---
08/12/14
---
---
--
---
---
03/10/15
0.5
NO
ND
NO
---
---
---
---
02/16/16
0.3
NO
NO
NO
--
--
--
---
02/13/17
0.3
NO
NO
NO
---
---
---
---
08/22/17
2
NO
NO
NO
--
--
--
---
02/05/18
2.1
NO
NO
NO
---
---
---
---
02/04/19
1.7
NO
NO
NO
---
--
--
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
2.6
NO
ND
NO
NA
NA
NA
NA
9/28/22
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
1 2.9
1 NO
I ND
I NO
I NO
I NO
I NO
I NA
Appendix D (Page 15 of 25)
nn��K, �,.�oMy,,a.,��es-„snerea oo��men�aw.�e,�,eae�m�e�na Moo,��M�-0o3. a�n����e�o.a�e,rrao�r�n, ea,�wMRaere�ae, H�s,�,�.ae�� Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-SR
MW-2R
MW-3R
VW-4
MW-5
MW-6
NES-1
Isobutanol
06/24/10
35
ND
59.01
ND
ND
ND
ND
---
12/13/10
---
---
--
---
NC2L=NE
06/20/11
35
ND
39.5J
ND
ND
ND
ND
---
12/05/11
--
---
---
---
---
---
---
ND
06/11/12
35
ND
ND
ND
ND
ND
ND
---
12/12/12
--
---
---
---
---
05/01/13
35
ND
ND
ND
ND
ND
ND
---
08/05/13
___
ND
___
___
___
___
___
___
02/24/14
35
ND
ND
ND
ND
ND
ND
---
08/12/14
35
ND
ND
ND
ND
ND
ND
---
03/10/15
35
ND
ND
ND
---
---
---
---
02/16/16
35
ND
42.5J
ND
---
---
---
---
02/13/17
35
ND
ND
ND
---
---
---
---
08/22/17
35
ND
ND
ND
---
---
---
---
02/05/18
35
ND
ND
ND
---
---
---
---
02/04/19
66.4
ND
ND
ND
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
66.4
ND
ND
ND
---
---
---
---
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
52.3
ND
ND
ND
NA
NA
NA
NA
9/28/221
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
52.3
ND
ND
ND
ND
ND
ND
NA
Lead
09/08/94
---
ND
13.0
ND
ND
30.0
36.0
---
12/01/94
---
11.0
ND
ND
ND
36.0
ND
---
NC21-=15 µg/L
02/09/95
---
ND
ND
ND
10
37.0
ND
---
03/02/95
---
ND
ND
ND
ND
44.0
ND
---
11/15/95
---
ND
ND
ND
ND
ND
ND
---
05/28/96
---
ND
ND
ND
ND
42.0
ND
---
11/22/96
---
ND
ND
ND
ND
13.0
ND
---
06/17/97
---
20.0
29.0
ND
ND
13.0
ND
---
12/01/97
---
8.0
14.0
ND
5.0
14.0
ND
---
05/20/98
---
ND
6.0
ND
6.0
21.0
ND
---
11/19/98
---
5.0
ND
ND
ND
58.0
ND
---
07/21/99
---
ND
12.0
14.0
ND
ND
ND
---
11/16/99
---
ND
ND
ND
ND
ND
ND
---
05/10/00
---
ND
ND
ND
ND
ND
ND
---
10/26/00
---
ND
ND
ND
ND
ND
ND
---
04/18/01
---
ND
ND
ND
ND
ND
ND
---
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
---
11.0
ND
ND
ND
ND
ND
---
11/19/02
---
ND
ND
ND
ND
12.0
ND
---
06/27/03
---
ND
ND
ND
ND
ND
ND
---
12/30/03
---
ND
ND
ND
ND
ND
ND
---
06/30/04
---
ND
ND
ND
ND
ND
ND
--
12/29/04
---
ND
ND
ND
ND
ND
ND
--
06/29/05
---
ND
ND
ND
ND
ND
ND
--
12/29/05
---
ND
ND
ND
ND
ND
ND
--
06/28/06
---
ND
ND
ND
ND
ND
ND
--
12/29/06
---
ND
ND
ND
ND
ND
2.1J
---
07/12/07
---
ND
ND
ND
ND
ND
ND
---
12/19/07
---
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
ND
ND
ND
ND
ND
ND
--
12/17/08
4
ND
ND
ND
ND
ND
ND
--
07/09/09
4
ND
ND
ND
ND
ND
ND
ND
12/16/09
4
ND
ND
ND
ND
ND
ND
--
06/24/10
4
ND
ND
ND
ND
ND
ND
--
12/13/10
4
ND
ND
ND
ND
ND
ND
--
06/20/11
5
ND
ND
ND
ND
ND
ND
--
12/05/11
5
ND
ND
ND
ND
ND
ND
--
06/11/12
5
ND
ND
ND
ND
ND
ND
ND
12/12/12
5
ND
ND
ND
ND
ND
ND
--
05/01/13
5
ND
ND
ND
ND
ND
ND
ND
08/05/13
5
ND
ND
ND
ND
ND
ND
--
02/24/14
5
ND
ND
ND
ND
ND
ND
ND
08/12/14
5
ND
ND
ND
ND
ND
ND
---
03/10/15
2.5
ND
ND
ND
ND
ND
ND
---
08/18/15
2.5
ND
ND
ND
ND
ND
ND
---
02/16/16
2.5
ND
ND
ND
ND
ND
ND
---
08/09/16
2.5
ND
5.11
ND
ND
ND
ND
---
02/13/17
2.5
ND
ND
ND
ND
ND
ND
---
08/22/17
2.5
ND
2.8J
ND
ND
ND
ND
---
02/05/18
2.5
ND
ND
ND
ND
ND
ND
---
08/13/18
2.5
ND
ND
ND
ND
4.6J
ND
---
02/04/19
2.5
ND
ND
ND
ND
ND
ND
---
08/07/19
1.6
ND
2.0J
ND
ND
ND
ND
---
02/12/20
1.6
1.91
2.1 J
2.1 J
2.8 J
3.1 J
2.3 J
---
08/27/20
4.5
ND
ND
ND
ND
ND
ND
---
02/11/21
4.5
ND
ND
ND
ND
ND
ND
--
08/19/21
4.5
ND
4.7J
ND
ND
ND
ND
ND
02/16/22
4.5
ND
6.6
5.4
6.4
ND
ND
NA
9/28/221
4.5
ND
ND
ND
ND
ND
ND
NA
03/28/23
1 2.99
1 ND
I ND
I ND
I ND
I ND
I ND
I NA
Appendix D (Page 16 of 25)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-111
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Mercury
12/01/97
---
ND
ND
ND
ND
ND
ND
---
11/19/98
---
ND
ND
ND
ND
ND
ND
---
NC21-= 1 µg/L
11/16/99
---
ND
0.59
0.65
0.65
0.76
ND
---
05/10/00
---
--
ND
ND
ND
ND
---
---
10/26/00
---
--
ND
ND
ND
ND
---
---
04/18/01
---
--
ND
ND
ND
ND
---
---
06/13/02
---
--
ND
ND
ND
ND
---
---
06/27/03
---
--
ND
ND
ND
ND
---
---
12/30/03
---
--
---
---
06/30/04
---
ND
ND
ND
ND
ND
ND
---
12/29/04
---
--
---
---
06/29/05
---
ND
ND
ND
ND
ND
ND
---
12/29/05
---
--
--
---
06/28/06
---
ND
ND
ND
ND
ND
ND
---
12/29/06
---
--
---
---
07/12/07
---
ND
ND
ND
ND
ND
ND
---
12/19/07
---
--
---
---
---
--
---
ND
07/08/08
---
ND
ND
ND
ND
ND
ND
---
12/17/08
---
--
---
---
07/09/09
0.07
ND
ND
ND
ND
ND
ND
---
12/16/09
---
--
---
---
06/24/10
0.07
ND
ND
ND
ND
ND
0.098J
---
12/13/10
---
--
---
---
06/20/11
0.1
ND
ND
ND
ND
ND
ND
---
12/05/11
---
--
---
---
06/11/12
0.1
ND
ND
ND
ND
ND
ND
ND
12/12/12
---
--
---
---
05/01/13
0.1
ND
ND
ND
ND
ND
ND
---
08/05/13
---
--
---
---
02/24/14
0.1
ND
ND
ND
ND
ND
ND
ND
08/12/14
---
--
---
---
03/10/15
0.1
ND
ND
ND
---
---
---
---
02/16/16
0.1
ND
ND
ND
---
---
---
---
02/13/17
0.1
ND
ND
ND
---
---
---
---
08/22/17
0.1
ND
ND
ND
---
---
---
---
02/05/18
0.1
ND
ND
ND
---
---
---
---
02/04/19
0.1
ND
ND
ND
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
0.12
ND
ND
ND
---
---
---
---
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
0.12
ND
ND
ND
NA
NA
NA
NA
9/28/221
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
0.100
ND
ND
ND
ND
ND
ND
NA
Methylene Chloride
07/09/09
0.97
ND
ND
ND
ND
ND
ND
ND
12/16/09
0.97
ND
ND
ND
ND
ND
ND
---
NC21-=5 µg/L
06/24/10
0.97
ND
19.0
ND
ND
ND
ND
---
08/12/10
0.97
---
ND
---
---
---
---
---
12/13/10
0.97
ND
ND
ND
ND
ND
ND
---
06/20/11
0.97
ND
ND
ND
ND
ND
ND
---
12/05/11
0.97
ND
ND
ND
ND
ND
ND
---
06/11/12
0.97
ND
ND
---
ND
ND
ND
ND
12/12/12
0.97
ND
ND
ND
ND
ND
ND
---
05/01/13
0.97
ND
ND
ND
ND
ND
ND
ND
08/05/13
0.97
ND
ND
ND
ND
ND
ND
---
02/24/14
0.97
1.0
ND
ND
ND
ND
ND
ND
08/12/14
0.97
ND
ND
ND
ND
ND
ND
ND
03/10/15
0.97
ND
ND
ND
ND
ND
ND
ND
08/18/15
0.97
1.3
1.1
1.6
ND
ND
ND
ND
02/16/16
0.97
ND
ND
ND
ND
ND
ND
ND
08/09/16
0.97
ND
ND
1.0B
ND
ND
ND
---
02/13/17
0.97
ND
ND
ND
ND
ND
ND
---
08/22/17
0.97
ND
ND
ND
ND
ND
ND
---
02/05/18
0.97
ND
ND
ND
ND
ND
ND
---
08/13/18
0.97
ND
ND
ND
ND
ND
ND
---
02/04/19
3.7
ND
ND
ND
ND
ND
ND
---
08/07/19
3.7
ND
ND
ND
ND
ND
ND
---
02/12/20
3.7
ND
ND
ND
ND
ND
ND
---
08/27/20
3.7
ND
ND
ND
ND
ND
ND
---
02/11/21
3.7
ND
ND
ND
ND
ND
ND
---
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
2
ND
ND
ND
ND
ND
ND
NA
9/28/221
2
ND
ND
ND
ND
ND
ND
NA
03/28/23
2.0
ND
ND
ND
ND
I ND
ND
NA
Naphthalene
07/08/08
---
ND
3.8J
ND
ND
ND
---
--
12/17/08
---
---
---
---
NC2L=6µg/L
07/09/09
0.24
ND
2.4J
ND
ND
ND
---
---
12/16/09
---
---
---
---
06/24/10
0.24
ND
7.4J
ND
ND
ND
---
---
12/13/10
---
---
--
---
06/20/11
0.24
ND
4.6J
ND
ND
ND
---
---
12/05/11
--
---
---
---
---
06/11/12
0.2
ND
4.6J
ND
ND
ND
ND
ND
12/12/12
---
---
---
---
05/01/13
0.24
ND
5.11
ND
ND
ND
---
---
08/05/13
---
---
---
---
02/24/14
0.24
ND
5.8J
ND
ND
ND
---
---
08/12/14
--
---
---
---
---
03/10/15
0.2
ND
5.4J
ND
---
---
---
---
02/16/16
0.2
ND
5.7J
ND
---
---
---
---
02/13/17
0.2
ND
6.11
ND
---
---
---
---
08/22/17
0.2
ND
7.0 J
0.45 J
---
---
---
---
02/05/18
0.2
ND
5.71
ND
---
---
---
---
02/04/19
0.4
ND
4.2 J
ND
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
0.4
ND
3.7
ND
--
---
---
---
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
0.12
ND
ND
ND
NA
NA
NA
NA
9/28/221
0.64
ND
3.6
ND
ND
ND
ND
NA
03/28/23
1 0.64
1 ND
1 1.8
1 ND
I ND
I ND
I ND
I NA
Appendix D (Page 17 of 25)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-111
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Nickel
09/08/94
---
ND
ND
ND
ND
ND
ND
---
12/01/94
---
ND
ND
ND
ND
ND
ND
---
NC21-= 100 µ8/1-
02/09/95
---
ND
72
ND
ND
ND
ND
---
03/02/95
---
ND
100
ND
ND
ND
ND
---
11/15/95
---
ND
61.0
ND
ND
ND
ND
---
05/28/96
---
ND
85.0
ND
ND
ND
ND
---
11/22/96
---
ND
72.0
ND
ND
ND
ND
---
06/17/97
---
75
98.0
ND
ND
ND
ND
---
12/01/97
---
ND
89.0
ND
ND
ND
ND
---
05/20/98
---
ND
91.0
ND
ND
ND
ND
---
11/19/98
---
ND
83.0
ND
ND
ND
ND
---
07/21/99
---
ND
109
ND
ND
ND
ND
---
11/16/99
---
ND
122
ND
ND
ND
ND
---
05/10/00
---
ND
104
ND
ND
ND
ND
---
10/26/00
---
ND
93.0
ND
ND
ND
ND
---
04/18/01
---
ND
107
ND
ND
ND
ND
---
10/27/01
---
ND
92.0
ND
ND
ND
ND
---
06/13/02
---
ND
98.0
ND
ND
ND
ND
---
11/19/02
---
ND
74.0
ND
ND
ND
ND
---
06/27/03
---
ND
85.0
ND
ND
ND
ND
---
12/30/03
---
ND
100
ND
ND
ND
ND
---
06/30/04
---
ND
120 (81.0)
ND
ND
ND
ND
---
12/29/04
---
ND
100
ND
ND
ND
ND
---
06/29/05
---
ND
150
ND
ND
ND
ND
--
12/29/05
---
ND
96.0
ND
ND
ND
ND
---
06/28/06
---
ND
88.7
ND
ND
ND
ND
---
12/29/06
---
ND
94.7
30.1
14.2
8.91
ND
---
07/12/07
---
ND
99.0
30.6J
13.9J
13.7J
ND
---
12/19/07
---
ND
83.4
23.7
11.0
18.3
ND
11.4
07/08/08
---
ND
76.0
28.1 J
11.5 J
27.0 J
ND
---
12/17/08
1.7
ND
75.5
27.8J
12.2)
11.0B
ND
---
07/09/09
1.7
2.2 J
93.5
29.4 J
11.71
23.2 J
ND
13.1 J
12/16/09
1.7
ND
81.2
28.2 J
11.8 B
2.6 B
ND
---
06/24/10
1.7
ND
76.3
19.7 J
9.01
7.0 J
4.5 J
---
12/13/10
1.7
ND
83.0
23.5J
6.8B
20.7J
ND
---
06/20/11
5
ND
78.8
30.11
11.2J
15.3J
ND
--
12/05/11
5
ND
89.1
32.8J
11.71
24.3J
ND
--
06/11/12
5
ND
91.8
28.9J
10.01
17.3J
ND
ND
12/12/12
5
ND
91.8
29.2J
9.3J
21.1J
ND
--
05/01/13
5
ND
89.6
31.9J
10.4J
5.71
ND
ND
08/05/13
5
ND
87.9
28.11
9.01
8.4J
ND
--
02/24/14
5
ND
83.1
16.7J
10.4J
ND
ND
ND
08/12/14
5
ND
97.9
29.01
12.91
13.2J
ND
---
03/30/15
2.5
ND
91.9
32.9J
12.3J
8.21
ND
---
08/18/15
2.5
ND
98.0
28.01
11.91
26.2 J
5.4 J
---
02/16/16
2.5
ND
92.0
35.4J
12.7J
3.71
ND
---
08/09/16
2.5
3.3 J
88.9
29.01
12.2 J
30.7 J
ND
---
02/13/17
2.5
ND
89.6
30.4J
13.5J
16.2J
ND
---
08/22/17
2.5
ND
94.2
28.2 J
12.3 J
13.5 J
ND
---
02/05/18
2.5
ND
87.6
29.8 J
11.7 J
28.5 J
ND
---
08/13/18
2.5
ND
88.9
29.0J
12.31
21.9J
ND
---
02/04/19
2.5
ND
85.7
17.4
10.7
5.5
ND
---
08/07/19
0.9
ND
92.6
27.8
11.7
18.7
ND
---
02/12/20
0.9
1.11
89.9
20.5
13.2
3.41
ND
---
08/27/20
3.5
ND
99.1
19.5
12.2
18.1
ND
---
02/11/21
3.5
ND
91.8
21.4
13.5
3.91
ND
---
08/19/21
3.5
3.51
100
24.8
15.1
15.9
ND
7.1
02/16/22
3.5
4.8
99.3
19.9
16.2
9.1
ND
NA
9/28/221
3.5
ND
101
31
15.2
10.9
ND
NA
03/28/23
1 1.61
1 ND
1 94.9
1 32.1
1 13.9 B
3.72 J, B
1.71 J, B
I NA
Appendix D (Page 18 of 25)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-SR
MW-2R
MW-3R
MW-0
MW-5
MW-6
NES-1
N-Nitroso-di-n-butylamine
02/24/14
7.5
ND
ND
ND
8.61
ND
ND
ND
08/12/14
---
---
--
---
NC2L= NE
03/10/15
1.3
ND
ND
ND
---
---
---
---
02/16/16
2.2
ND
ND
ND
---
---
---
---
02/13/17
2.2
ND
ND
ND
---
---
---
---
08/22/17
1.6
ND
ND
ND
---
---
---
---
02/05/18
1.6
ND
ND
ND
---
---
---
---
02/04/19
2.2
ND
ND
ND
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
2.6
ND
ND
ND
NA
NA
NA
NA
9/28/221
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
2.0
ND
ND
ND
ND
ND
ND
NA
Phorate
04/18/01
---
---
3.2
ND
ND
ND
---
---
10/27/01
--
ND
8.1
ND
ND
ND
ND
---
NC21-=1µg/L
06/13/02
---
ND
ND
ND
ND
ND
ND
---
11/19/02
--
ND
ND
ND
ND
ND
ND
---
06/27/03
---
ND
ND
ND
ND
ND
ND
---
06/30/04
--
ND
ND
ND
ND
ND
ND
---
06/29/05
---
ND
ND
ND
ND
ND
ND
---
12/29/05
--
---
--
---
06/28/06
---
ND
ND
ND
ND
ND
ND
---
12/29/06
---
---
---
--
---
07/12/07
---
ND
ND
ND
ND
ND
ND
---
12/19/07
--
---
--
---
---
--
--
ND
07/08/08
---
ND
ND
ND
ND
ND
ND
---
12/17/08
---
---
--
--
---
07/09/09
6.6
ND
ND
ND
ND
ND
ND
---
12/16/09
---
---
--
--
---
06/24/10
6.5
ND
ND
ND
ND
ND
ND
---
12/13/10
---
---
—
---
---
06/20/11
5.4
ND
ND
ND
ND
ND
ND
---
12/05/11
---
---
—
---
---
06/11/12
5.4
ND
ND
ND
ND
ND
ND
---
12/12/12
---
---
--
---
---
05/01/13
5.4
ND
ND
ND
ND
ND
ND
---
08/05/13
---
__
__
---
---
02/24/14
5.4
---
ND
ND
ND
ND
ND
---
08/12/14
---
--
--
---
---
03/10/15
0.8
ND
ND
ND
---
---
--
---
02/16/16
1.1
ND
--
ND
--
--
--
---
02/13/17
1.1
ND
ND
ND
---
---
---
---
08/22/17
1.7
ND
ND
ND
--
--
--
---
02/05/18
1.8
ND
ND
ND
---
---
---
---
02/04/19
1.1
ND
ND
ND
--
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
2.6
ND
ND
ND
NA
NA
NA
NA
9/28/221
NA
NA
NA
NA
NA
NA
NA
NA
03/28/23
1 3.6
1 ND
I ND
I ND
I ND
I ND
I ND
I NA
Appendix D (Page 19 of 25)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-111
MW-211
MW-38
MWA
MW-5
MW-6
NES-1
Selenium
09/08/94
---
NO
ND
ND
ND
NO
NO
---
12/01/94
---
NO
NO
NO
NO
NO
NO
---
NC21-=20 µg/L
02/09/95
---
NO
ND
NO
NO
NO
NO
---
03/02/95
---
NO
NO
NO
NO
NO
NO
---
11/15/95
---
NO
ND
NO
NO
NO
NO
---
05/28/96
---
NO
NO
NO
NO
NO
NO
---
11/22/96
---
NO
ND
NO
NO
NO
NO
---
06/17/97
---
NO
NO
NO
NO
NO
NO
---
12/01/97
---
NO
ND
NO
NO
NO
NO
---
05/20/98
---
NO
NO
NO
NO
NO
NO
---
11/19/98
---
NO
ND
NO
NO
NO
NO
---
07/21/99
---
NO
NO
NO
NO
36.0
NO
---
11/16/99
---
NO
ND
NO
NO
NO
NO
---
05/30/00
---
NO
NO
NO
NO
NO
NO
---
10/26/00
---
NO
ND
NO
NO
NO
NO
---
04/18/01
---
NO
NO
NO
NO
NO
NO
---
10/27/01
---
NO
ND
NO
NO
NO
NO
---
06/13/02
---
NO
NO
NO
NO
NO
NO
---
11/19/02
---
NO
ND
NO
NO
NO
NO
---
06/27/03
---
NO
ND
NO
NO
NO
NO
---
12/30/03
---
NO
ND
NO
NO
NO
NO
---
06/30/04
---
NO
ND
NO
NO
NO
NO
--
12/29/04
---
NO
ND
NO
NO
NO
NO
---
06/29/05
---
NO
NO
NO
NO
NO
NO
---
12/29/05
---
NO
ND
NO
NO
NO
NO
---
06/28/06
---
NO
NO
NO
NO
NO
NO
--
12/29/06
---
NO
NO
NO
NO
NO
NO
--
07/12/07
---
NO
NO
NO
NO
NO
NO
--
12/19/07
---
NO
11.5
NO
NO
NO
NO
NO
07/08/08
---
NO
NO
NO
NO
NO
NO
--
12/17/08
3.8
4.8 B
5.1 B
4.8 B
NO
NO
NO
--
07/09/09
3.8
NO
NO
4.2J
ND
ND
ND
ND
12/16/09
3.8
ND
ND
ND
5.1J
NO
NO
--
06/24/10
3.8
NO
NO
NO
ND
NO
NO
---
12/13/10
3.8
NO
NO
NO
ND
NO
NO
---
06/20/11
30
NO
NO
NO
ND
NO
NO
---
12/05/11
10
NO
NO
NO
ND
NO
NO
---
06/11/12
30
NO
NO
NO
ND
NO
NO
NO
12/12/12
10
NO
NO
NO
ND
NO
NO
---
05/01/13
10
NO
NO
NO
ND
NO
NO
NO
08/05/13
10
NO
NO
NO
ND
NO
NO
---
02/24/14
10
NO
NO
NO
ND
NO
NO
NO
08/12/14
10
NO
NO
NO
ND
NO
NO
---
03/10/15
5
NO
NO
NO
ND
NO
NO
---
08/18/15
5
NO
NO
NO
ND
NO
NO
---
02/16/16
5
NO
NO
NO
ND
NO
NO
---
08/09/16
5
NO
NO
NO
ND
NO
NO
---
02/13/17
5
NO
NO
NO
ND
NO
NO
---
08/22/17
5
NO
NO
NO
ND
NO
NO
---
02/05/18
5
NO
NO
NO
ND
NO
NO
---
08/13/18
5
NO
NO
NO
ND
NO
NO
---
02/04/19
5
NO
NO
NO
ND
NO
NO
---
08/07/19
4.7
NO
NO
NO
ND
NO
NO
---
02/12/20
4.7
NO
NO
NO
ND
NO
NO
---
08/27/20
4.7
NO
NO
NO
ND
NO
NO
---
02/11/21
4.7
NO
NO
NO
ND
NO
NO
---
08/19/21
NR
NO
NO
NO
ND
NO
NO
NO
02/16/22
4.7
NO
7.7
NO
5.8
NO
NO
NA
9/28/221
4.7
NO
4.91
NO
NO
NO
NO
NA
03/28/23
7.35
NO
NO
NO
NO
NO
NO
NA
Silver
09/08/94
---
NO
NO
NO
NO
NO
NO
---
12/01/94
--
NO
NO
NO
NO
NO
NO
--
NC21-=20 µg/L
02/09/95
---
NO
NO
NO
NO
NO
NO
---
03/02/95
--
NO
NO
NO
NO
NO
NO
---
11/15/95
---
NO
NO
NO
NO
NO
NO
---
05/28/96
--
NO
NO
NO
NO
NO
NO
---
11/22/96
---
NO
NO
NO
NO
NO
NO
---
06/17/97
--
NO
NO
NO
NO
NO
NO
--
12/01/97
---
NO
8.0
NO
NO
NO
3.0
---
05/20/98
--
NO
NO
NO
NO
NO
NO
---
11/19/98
---
NO
NO
NO
NO
NO
NO
---
07/21/99
--
NO
NO
NO
NO
NO
NO
--
11/16/99
---
NO
NO
NO
NO
NO
NO
---
05/10/00
--
NO
NO
NO
NO
NO
NO
---
10/26/00
---
NO
NO
NO
NO
NO
NO
---
04/18/01
--
NO
15.0
NO
NO
NO
NO
--
10/27/01
---
NO
NO
NO
NO
NO
NO
---
06/13/02
--
NO
NO
NO
NO
NO
NO
---
11/19/02
---
NO
NO
NO
NO
NO
NO
---
06/27/03
--
NO
NO
NO
NO
NO
NO
---
12/30/03
---
NO
NO
NO
NO
NO
NO
---
06/30/04
--
NO
NO
NO
NO
NO
NO
---
12/29/04
---
NO
NO
NO
NO
NO
NO
---
06/29/05
--
NO
NO
NO
NO
NO
NO
---
12/29/05
---
NO
NO
NO
NO
NO
NO
---
06/28/06
--
NO
NO
NO
NO
NO
NO
---
12/29/06
---
NO
NO
NO
NO
NO
NO
---
07/12/07
--
NO
NO
NO
NO
NO
NO
---
12/19/07
---
NO
0.57J
0.60J
0.55J
NO
0.33J
NO
07/08/08
---
NO
2.7 J
2.3 J
1.11
0.221
0.69 J
---
12/17/08
0.1
0.13 J
1.81
1.4 J
0.85 J
0.12 J
0.51 J
---
07/09/09
0.1
NO
0.84J
0.63J
0.45J
NO
0.11.1
NO
12/16/09
0.1
0.12 J
2.0 J
1.6 J
1.0 J
0.12 J
0.52 J
---
06/24/10
0.1
NO
0.38.1
0.33J
0.35J
NO
NO
---
12/13/10
0.1
0.15 B
1.3 J
0.991
0.45 B
(ND)
(ND)
---
06/20/11
5
NO
NO
NO
NO
NO
NO
---
12/05/11
5
NO
NO
NO
NO
NO
NO
---
06/11/12
5
NO
NO
NO
NO
NO
NO
NO
12/12/12
5
NO
NO
NO
NO
NO
NO
---
05/01/13
5
NO
NO
NO
NO
NO
NO
NO
08/05/13
5
NO
ND
NO
NO
NO
NO
---
02/24/14
5
NO
NO
NO
NO
NO
NO
NO
08/12/14
5
NO
NO
NO
NO
NO
NO
---
03/30/15
2.5
NO
NO
NO
NO
NO
NO
---
08/18/15
2.5
NO
NO
NO
NO
NO
NO
---
02/16/16
2.5
NO
NO
NO
NO
NO
NO
---
08/09/16
2.5
NO
ND
NO
NO
NO
NO
---
02/13/17
2.5
NO
NO
NO
NO
NO
NO
---
08/22/17
2.5
NO
ND
NO
NO
NO
NO
---
02/05/18
2.5
NO
NO
NO
NO
NO
NO
---
08/13/18
2.5
NO
ND
NO
NO
NO
NO
---
02/04/19
2.5
NO
NO
NO
NO
NO
NO
---
08/07/19
2.5
NO
ND
NO
NO
NO
NO
---
02/12/20
2.5
NO
NO
NO
NO
NO
NO
---
08/27/20
2.5
NO
ND
NO
NO
NO
NO
---
02/31/21
2.5
NO
NO
NO
NO
NO
NO
---
08/19/21
NR
NO
NO
NO
NO
NO
NO
NO
02/16/22
2.5
NO
NO
NO
NO
NO
NO
NA
9/28/221
2.5
NO
NO
NO
NO
NO
NO
NA
03/28/23
1 1.54
1 NO
I NO
I NO
I NO
I NO
I NO
I NA
Appendix D (Page 20 of 25)
M��K, �,.�oMy,,a.,��es-„snerea oo��men�aw.�e,�,oae�mve�na Moo,�vM�-0o3. v�m���e�o.a�e,�.ao�nn, x�,�wMRaere�ae, H�s,�,�.ae�� Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-111
MW-211
MW-3R
MW-4
MW-5
MW-6
NES-1
Thallium
09/08/94
---
NO
ND
ND
ND
NO
NO
---
12/01/94
---
NO
NO
NO
NO
NO
NO
---
NC21-=2µ8/1-
02/09/95
---
NO
ND
NO
NO
NO
NO
---
03/02/95
---
NO
NO
NO
NO
NO
NO
---
11/15/95
---
NO
ND
NO
NO
NO
NO
---
05/28/96
---
NO
NO
NO
NO
NO
NO
---
11/22/96
---
NO
ND
NO
NO
NO
NO
---
06/17/97
---
NO
3.0
NO
NO
NO
NO
---
12/01/97
---
NO
ND
NO
NO
NO
NO
---
05/20/98
---
NO
NO
NO
NO
NO
NO
---
11/19/98
---
NO
ND
NO
NO
NO
NO
---
07/21/99
---
NO
NO
NO
NO
NO
NO
---
11/16/99
---
NO
ND
NO
NO
NO
NO
---
05/30/00
---
NO
NO
NO
NO
NO
NO
---
10/26/00
---
NO
ND
NO
NO
NO
NO
---
04/18/01
---
NO
NO
NO
NO
NO
NO
---
10/27/01
---
NO
ND
NO
NO
NO
NO
---
06/13/02
---
NO
NO
NO
NO
NO
NO
---
11/19/02
---
NO
ND
NO
NO
NO
NO
---
06/27/03
---
NO
ND
NO
NO
NO
NO
--
12/30/03
---
NO
ND
NO
NO
NO
NO
---
06/30/04
---
NO
NO
NO
NO
NO
NO
---
12/29/04
---
NO
10.01
ND
NO
NO
NO
---
06/29/05
---
NO
22.0
13.0
NO
NO
NO
--
12/29/05
---
NO
23.0
20.0
NO
NO
NO
---
06/28/06
---
NO
25.7
12.6
NO
NO
NO
---
12/29/06
---
NO
ND
ND
NO
NO
NO
---
07/12/07
---
NO
ND
ND
NO
NO
NO
---
12/19/07
---
NO
4.0J
ND
NO
NO
NO
NO
07/08/08
---
NO
NO
NO
NO
NO
NO
--
12/17/08
3
NO
3.2J
3.21
ND
ND
ND
--
07/09/09
3
ND
ND
ND
4.1J
ND
ND
ND
12/16/09
3
ND
ND
ND
ND
ND
ND
--
06/24/10
3
ND
ND
5.2J
3.1J
ND
ND
---
12/13/10
3
ND
ND
7.7
ND
ND
ND
---
06/20/11
5.4
ND
ND
ND
ND
ND
ND
---
12/05/11
5.4
ND
ND
ND
ND
ND
ND
---
06/11/12
5.4
ND
ND
ND
ND
ND
ND
ND
12/12/12
5.4
ND
ND
ND
ND
ND
ND
---
05/01/13
5.4
ND
ND
ND
ND
ND
ND
ND
08/05/13
5.4
ND
ND
ND
ND
ND
ND
--
02/24/14
5.4
ND
ND
ND
ND
ND
ND
ND
08/12/14
5.4
ND
ND
ND
ND
ND
ND
---
03/10/15
5
ND
ND
ND
ND
ND
ND
---
08/18/15
5
ND
ND
ND
ND
ND
ND
---
02/16/16
5
ND
ND
ND
ND
ND
ND
---
08/09/16
5
ND
ND
ND
ND
ND
ND
---
02/13/17
0.02
0.023J
0.040J
NO
ND
0.035J
NO
---
08/22/17
0.02
NO
NO
NO
ND
0.033J
NO
---
02/05/18
0.03
NO
NO
NO
ND
0.047J
NO
---
08/13/18
0.02
NO
NO
NO
ND
0.037J
NO
---
02/04/19
0.06
NO
NO
NO
NO
NO
NO
--
08/07/19
0.06
NO
NO
NO
NO
NO
NO
---
02/12/20
0.06
NO
NO
NO
NO
NO
NO
--
08/27/20
0.05
NO
NO
NO
NO
NO
NO
---
02/11/21
0.05
NO
NO
NO
NO
NO
NO
--
08/19/21
NR
NO
NO
NO
NO
NO
NO
0.069J
02/16/22
0.05
NO
NO
NO
NO
NO
NO
NA
9/28/221
0.05
NO
NO
NO
NO
NO
NO
NA
03/28/23
0.121
NO
I NO
0.168J
NO
NO
NO
NA
Tin
12/01/97
---
NO
NO
NO
NO
NO
NO
---
11/19/98
---
NO
NO
NO
NO
NO
NO
--
NC21-=2,000 µ8/L
11/16/99
---
NO
ND
NO
NO
NO
NO
---
10/26/00
--
--
NO
NO
NO
NO
--
---
04/18/01
---
--
ND
NO
NO
NO
---
---
10/27/01
--
-
--
---
06/13/02
---
NO
NO
NO
NO
NO
NO
---
11/19/02
--
--
--
---
06/27/03
---
NO
149
127
NO
NO
NO
---
12/30/03
--
NO
ND
NO
NO
NO
NO
---
06/30/04
---
NO
ND
NO
NO
NO
NO
---
12/29/04
--
NO
ND
NO
NO
NO
NO
---
06/29/05
---
NO
ND
NO
NO
NO
NO
---
12/29/05
--
NO
ND
NO
NO
NO
NO
---
06/28/06
---
NO
NO
NO
NO
NO
NO
---
12/29/06
--
NO
41.1
14.4
3.2J
NO
NO
---
07/12/07
---
NO
35.2J
13.9J
5.2J
NO
NO
---
12/19/07
--
NO
33.6
7.4
NO
NO
NO
ND
07/08/08
---
4.4 J
28.6 J
15.11
5.4 J
3.0 J
3.6 J
---
12/17/08
1.8
NO
22.5J
9.2J
ND
ND
ND
---
07/09/09
1.8
ND
21.4J
8.6J
ND
ND
ND
---
12/16/09
1.8
ND
26.3J
10.7J
NO
NO
NO
---
06/24/10
1.8
NO
23.4 J
10.71
3.2 J
2.2 J
1.91
---
12/13/10
1.8
NO
30.3J
12.1J
5.8J
ND
ND
---
06/20/11
5
ND
26.8J
13.81
ND
ND
ND
---
12/05/11
5
ND
25.8J
13.9J
ND
NO
NO
---
06/11/12
5
NO
22.2J
9.01
ND
NO
NO
NO
12/12/12
5
NO
30.0J
13.2J
ND
NO
NO
---
05/01/13
5
NO
25.8J
12.2J
ND
NO
NO
---
08/05/13
5
NO
22.7J
12.5J
ND
NO
NO
---
02/24/14
5
NO
26.7J
11.7J
9.8J
ND
ND
ND
08/12/14
5
ND
30.71
8.21
ND
NO
NO
---
03/10/15
2.5
NO
28.7J
11.1J
NO
NO
NO
---
08/18/15
2.5
NO
27.71
7.5J
NO
NO
NO
---
02/16/16
2.5
NO
28.6J
10.4J
---
---
---
---
08/09/16
2.5
NO
20.9 J
5.4 J
--
--
--
---
02/13/17
2.5
ND
25.5 B
7.8 B
---
---
---
---
08/22/17
2.5
NO
17.2 J
5.3 J
--
--
--
---
02/05/18
2.5
NO
20.3 J
9.5 J
---
---
---
---
08/13/18
2.5
NO
22.2J
7.4J
--
--
ND
---
02/04/19
2.5
ND
24.8
5.5
---
---
---
---
08/07/19
1.6
ND
29.3
9.7
--
--
--
---
02/12/20
1.6
ND
26.0
5.8
---
---
---
---
08/27/20
4.7
ND
27.6
5.1
--
--
--
---
02/11/21
4.7
ND
30.1
8.0
---
---
---
---
08/19/21
4.7
ND
26.2
6.5
ND
--
ND
---
02/16/22
4.7
ND
28.2
11.2
NA
NA
NA
NA
9/28/221
4.7
ND
52.1
34.8
20.8
14.6
11.6
NA
03/28/23
1 4.87
1 ND
36.9J
16.61
I ND
I ND
I ND
I NA
Appendix D (Page 21 of 25)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-111
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Toluene
05/20/98
---
NO
NO
8.1
NO
NO
NO
---
11/19/98
---
NO
NO
NO
NO
NO
NO
---
NC21-=600µ l-
07/21/99
---
NO
NO
NO
NO
NO
NO
---
11/16/99
---
NO
NO
NO
NO
NO
NO
---
05/10/00
---
NO
NO
NO
NO
NO
NO
---
04/18/01
---
NO
NO
NO
NO
NO
NO
---
10/26/01
---
NO
NO
NO
NO
NO
NO
---
10/27/01
---
NO
NO
NO
NO
NO
NO
---
06/13/02
---
NO
NO
NO
NO
NO
NO
---
11/19/02
---
NO
NO
NO
NO
NO
NO
---
06/27/03
---
NO
NO
NO
NO
NO
NO
---
12/30/03
---
NO
NO
NO
NO
NO
NO
---
06/30/04
---
NO
NO
NO
NO
NO
NO
---
12/29/04
---
NO
NO
NO
NO
NO
NO
---
06/29/05
---
NO
NO
NO
NO
NO
NO
---
12/29/05
---
NO
NO
NO
NO
NO
NO
---
06/28/06
---
NO
NO
NO
NO
NO
NO
---
12/29/06
---
NO
NO
NO
NO
NO
NO
---
07/12/07
---
NO
0.49 B
NO
NO
NO
NO
---
12/19/07
---
NO
0.51J
NO
NO
NO
NO
NO
07/08/08
---
NO
0.39J
NO
NO
1.3
NO
--
12/17/08
0.26
1.4
1.6
NO
NO
11.7
NO
--
07/09/09
0.26
NO
0.46J
NO
NO
NO
NO
NO
12/16/09
0.26
NO
0.42J
NO
NO
NO
NO
--
06/24/10
0.26
NO
NO
NO
NO
NO
NO
---
12/13/10
0.26
NO
0.54J
NO
NO
NO
NO
---
06/20/11
0.26
NO
0.34J
NO
NO
NO
NO
---
12/05/11
0.26
NO
0.28J
NO
NO
0.3J
NO
---
06/11/12
0.26
NO
0.28J
NO
NO
NO
NO
NO
12/12/12
0.26
NO
0.29J
NO
NO
0.36J
NO
---
05/01/13
0.26
NO
NO
NO
NO
NO
NO
NO
08/05/13
0.26
NO
0.29J
NO
NO
NO
NO
--
02/24/14
0.26
NO
NO
NO
NO
NO
NO
NO
08/12/14
0.26
NO
NO
NO
NO
NO
NO
NO
03/10/15
0.26
NO
NO
NO
NO
NO
NO
NO
08/18/15
0.26
NO
NO
NO
NO
NO
NO
--
02/16/16
0.26
NO
NO
NO
NO
NO
NO
NO
08/09/16
0.26
NO
0.33J
NO
NO
NO
NO
---
02/13/17
0.26
NO
NO
NO
NO
NO
NO
---
08/22/17
0.26
NO
NO
NO
NO
NO
NO
---
02/05/18
0.26
NO
NO
NO
NO
NO
NO
---
08/13/18
0.26
NO
NO
NO
NO
0.44J
NO
---
02/04/19
0.24
NO
NO
NO
NO
NO
NO
---
08/07/19
0.24
NO
NO
NO
NO
NO
NO
---
02/12/20
0.24
NO
NO
NO
NO
NO
NO
---
08/27/20
0.24
NO
NO
NO
NO
NO
NO
---
02/11/21
0.24
NO
NO
NO
NO
NO
NO
---
08/19/21
NR
NO
NO
NO
NO
NO
NO
NO
02/16/22
0.48
NO
1.1
1.9
NO
NO
NO
NA
9/28/221
0.48
NO
NO
NO
NO
NO
NO
NA
03/28/23
0.24
NO
NO
NO
NO
NO
NO
NA
trans-1,4-Dichloro-2-butene
05/20/98
--
NO
NO
5.1
NO
NO
NO
---
11/19/98
---
NO
NO
NO
NO
NO
NO
---
NC21-=NE
07/21/99
--
NO
NO
NO
NO
NO
NO
--
11/16/99
---
NO
ND
NO
NO
NO
NO
---
05/10/00
--
NO
NO
NO
NO
NO
NO
---
10/26/00
---
NO
ND
NO
NO
NO
NO
---
04/18/01
--
NO
NO
NO
NO
NO
NO
---
10/27/01
---
NO
ND
NO
NO
NO
NO
---
11/19/02
--
NO
NO
NO
NO
NO
NO
---
06/27/03
---
NO
ND
NO
NO
NO
NO
---
12/30/03
--
NO
NO
NO
NO
NO
NO
---
06/30/04
---
NO
ND
NO
NO
NO
NO
---
12/29/04
--
NO
NO
NO
NO
NO
NO
---
06/29/05
---
NO
ND
NO
NO
NO
NO
---
12/29/05
--
NO
NO
NO
NO
NO
NO
---
06/28/06
---
NO
ND
NO
NO
NO
NO
---
12/29/06
--
NO
NO
NO
NO
NO
NO
---
07/12/07
---
NO
ND
NO
NO
NO
NO
---
12/19/07
--
NO
NO
NO
NO
NO
NO
NO
07/08/08
---
NO
ND
NO
NO
NO
NO
---
12/17/08
1
NO
NO
NO
ND
NO
NO
---
07/09/09
1
NO
ND
NO
ND
NO
NO
NO
12/16/09
1
NO
NO
NO
ND
NO
NO
---
06/24/10
1
NO
ND
NO
ND
NO
NO
---
12/13/30
1
NO
NO
NO
ND
NO
NO
---
06/20/11
1
NO
ND
NO
ND
NO
NO
---
12/05/11
1
NO
NO
NO
NO
NO
NO
---
06/11/12
1
NO
ND
NO
NO
NO
NO
ND
12/12/12
1
NO
NO
NO
NO
NO
NO
--
05/01/13
1
NO
ND
NO
NO
NO
NO
ND
08/05/13
1
NO
NO
NO
NO
NO
NO
---
02/24/14
1
NO
ND
NO
NO
NO
NO
NO
08/12/14
1
NO
NO
NO
NO
NO
NO
NO
03/10/15
1
NO
ND
NO
NO
NO
NO
NO
08/18/15
1
NO
NO
NO
NO
NO
NO
---
02/16/16
1
NO
ND
NO
NO
NO
NO
NO
08/09/16
1
NO
NO
NO
NO
NO
NO
---
02/13/17
1
NO
ND
NO
NO
NO
NO
---
08/22/17
1
NO
NO
NO
NO
NO
NO
---
02/05/18
1
NO
ND
NO
NO
NO
NO
---
08/13/18
1
NO
NO
NO
NO
NO
NO
---
02/04/19
0.5
NO
ND
NO
NO
NO
NO
---
08/07/19
0.54
NO
NO
NO
NO
NO
NO
---
02/12/20
0.54
NO
ND
NO
NO
NO
NO
---
08/27/20
0.54
NO
NO
NO
NO
NO
NO
---
02/11/21
0.54
NO
ND
NO
NO
NO
NO
---
08/19/21
NR
NO
NO
NO
NO
NO
NO
NO
02/16/22
0.56
NO
ND
NO
NO
NO
NO
NA
9/28/221
0.56
NO
ND
NO
NO
NO
NO
NA
03/28/23
1 0.56
1 NO
I NO
I NO
I NO
I NO
I NO
I NA
Appendix D (Page 22 of 25)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-SR
MW-2R
MW-311
MW-4
MW-5
MW-6
NES-1
Trichlorofluoromethane
9/28/22'
0.30
ND
1.4
ND
ND
ND
ND
NA
NC21-=2000 µg/L
03/28/23
0.30
ND
1.5
ND
ND
ND
ND
NA
Vanadium
09/08/94
---
ND
ND
ND
ND
ND
130
---
12/01/94
---
63.0
ND
ND
45.0
ND
ND
---
NC21-=7µg/L
02/09/95
---
ND
ND
ND
ND
ND
ND
---
03/02/95
---
41.0
ND
ND
45.0
ND
ND
---
11/15/95
---
ND
ND
ND
ND
ND
ND
---
05/28/96
---
83.0
ND
ND
ND
ND
ND
---
11/22/96
---
7.0
17
ND
21.0
ND
ND
---
06/17/97
---
450
560
ND
19.0
ND
ND
---
12/01/97
---
62.0
88.0
ND
41.0
ND
10.0
---
05/20/98
---
25.0
15.0
ND
10.0
5.0
ND
---
11/19/98
---
33.0
29.0
5.0
16.0
9.0
5.0
---
07/21/99
---
ND
ND
ND
ND
ND
ND
---
11/16/99
---
ND
ND
ND
ND
ND
ND
---
05/10/00
---
ND
ND
ND
ND
ND
ND
---
10/26/00
---
ND
ND
ND
ND
ND
ND
---
04/18/01
---
ND
ND
ND
ND
ND
ND
---
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
---
ND
ND
ND
ND
ND
ND
---
11/19/02
---
ND
ND
ND
ND
ND
ND
---
06/27/03
---
ND
ND
ND
ND
ND
ND
---
12/30/03
---
ND
ND
ND
ND
ND
ND
---
06/30/04
---
ND
ND
ND
ND
ND
ND
--
12/29/04
---
ND
ND
ND
ND
ND
ND
---
06/29/05
---
ND
ND
ND
ND
ND
ND
---
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
---
ND
ND
ND
ND
ND
ND
---
12/29/06
---
2.71
ND
ND
14.5
ND
1.01
---
07/12/07
---
ND
ND
ND
19.4J
ND
ND
--
12/19/07
---
2.2B
2.2B
ND
15.7J
3.0B
1.2B
4.0J
07/08/08
---
2.6 J
2.4 J
N D
14.6 J
1.4 J
1.2 J
---
12/17/08
0.2
1.9 B
2.3 B
ND
13.9 J
2.5 B
1.2 B
--
07/09/09
0.2
3.9 B
9.7 J
2.5 B
18.4 J
2.9 B
2.2 B
8.51
12/16/09
0.2
2.0 B
4.41
1.3 B
14.0 J
2.2 B
1.5 B
--
06/24/10
0.2
1.81
4.41
1.5 J
13.3 J
2.2 J
1.3 J
--
12/13/10
0.2
3.21
3.6 J
0.35 B
16.6 J
1.8 B
1.0 B
---
06/20/11
5
ND
ND
ND
14.5J
ND
ND
---
12/05/11
5
ND
ND
ND
13.5J
ND
ND
---
06/11/12
5
ND
18.01
ND
12.3J
ND
ND
ND
12/12/12
5
ND
ND
ND
13.6J
ND
ND
--
05/01/13
5
ND
ND
ND
6.3J
ND
ND
ND
08/05/13
5
ND
ND
ND
10.2J
ND
ND
--
02/24/14
5
ND
ND
ND
12.9J
ND
ND
ND
08/12/14
5
ND
ND
ND
18.6J
ND
ND
---
03/30/15
2.5
3.1J
11.6J
6.2J
13.4J
ND
ND
---
08/18/15
2.5
3.41
6.81
3.6J
19.6J
2.81
ND
---
02/16/16
2.5
2.7J
3.3J
ND
14.4J
ND
ND
---
08/09/16
2.5
2.51
3.51
ND
21.2J
ND
ND
---
02/13/17
2.5
4.4J
4.1J
ND
18.4J
3.0J
2.9J
--
08/22/17
2.5
ND
6.61
ND
20.6J
2.61
ND
---
02/05/18
2.5
3.6J
4.4J
ND
17.6J
ND
2.5J
---
08/13/18
2.5
ND
5.31
ND
20.4J
2.91
ND
---
02/04/19
2.5
ND
3.5J
ND
12.0
ND
ND
---
08/07/19
1.3
2.61
4.11
1.9 J
22.1
1.7 J
2.41
---
02/12/20
1.3
ND
ND
ND
17.0
ND
1.4J
--
08/27/20
3.9
ND
ND
ND
21.1
ND
ND
6.8
02/11/21
3.9
ND
ND
ND
13.4
ND
ND
7.2
08/19/21
3.9
ND
4.81
ND
ND
ND
ND
ND
02/16/22
3.9
ND
5.1
ND
ND
ND
ND
NA
9/28/22'
3.9
ND
ND
ND
ND
ND
ND
NA
03/28/23
1 4.99
1 ND
I ND
I ND
I ND
I ND
I ND
I NA
Appendix D (Page 23 of 25)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-18
MW-28
MW-311
MW-4
MW-5
MW-6
NES-1
Vinyl chloride
09/08/94
---
ND
ND
12.0
ND
ND
ND
---
12/01/94
---
ND
ND
13.0
ND
ND
ND
---
NC21-=0.03 pg/L
02/09/95
---
ND
ND
15.0
ND
ND
ND
---
03/02/95
---
ND
ND
14.0
ND
ND
ND
---
11/15/95
---
ND
ND
11.0
ND
ND
ND
---
05/28/96
---
ND
ND
ND
ND
ND
ND
---
11/22/96
---
ND
ND
ND
ND
ND
ND
---
06/17/97
---
ND
ND
ND
ND
ND
ND
---
12/01/97
---
ND
ND
7.0
4.0
ND
ND
---
05/20/98
---
ND
ND
ND
ND
ND
ND
---
11/19/98
---
ND
ND
ND
ND
ND
ND
---
07/21/99
---
ND
ND
ND
ND
ND
ND
---
11/16/99
---
ND
ND
ND
ND
ND
ND
---
05/10/00
---
ND
ND
ND
ND
ND
ND
---
10/26/00
---
ND
ND
ND
ND
ND
ND
---
04/18/01
---
ND
ND
ND
ND
ND
ND
---
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
---
ND
ND
ND
ND
ND
ND
---
11/19/02
---
ND
ND
ND
ND
ND
ND
---
06/27/03
---
ND
ND
ND
ND
ND
ND
--
12/30/03
---
ND
ND
ND
ND
ND
ND
---
06/30/04
---
ND
ND
ND
ND
ND
ND
---
12/29/04
---
ND
ND
ND
ND
ND
ND
---
06/29/05
---
ND
ND
ND
ND
ND
ND
---
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
---
ND
ND
ND
ND
ND
ND
--
12/29/06
---
ND
ND
0.981
ND
ND
ND
---
02/23/07
---
--
--
1.0
--
--
--
---
07/12/07
---
ND
ND
ND
ND
ND
ND
---
12/19/07
---
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
ND
ND
0.76J
ND
ND
ND
---
12/17/08
0.62
ND
ND
0.76J
ND
ND
ND
---
07/09/09
0.62
ND
ND
0.991
ND
ND
ND
ND
12/16/09
0.62
ND
ND
0.81J
ND
ND
ND
---
06/24/10
0.62
ND
ND
0.77J
ND
ND
ND
---
12/13/10
0.62
ND
ND
ND
ND
ND
ND
---
06/20/11
0.62
ND
ND
ND
ND
ND
ND
---
12/05/11
0.62
ND
ND
ND
ND
ND
ND
---
06/11/12
0.62
ND
ND
ND
ND
ND
ND
ND
12/12/12
0.62
ND
ND
ND
ND
ND
ND
---
05/01/13
0.62
ND
ND
ND
ND
ND
ND
ND
08/05/13
0.62
ND
ND
ND
ND
ND
ND
---
02/24/14
0.62
ND
ND
ND
ND
ND
ND
ND
08/12/14
0.62
ND
ND
ND
ND
ND
ND
ND
03/10/15
0.62
ND
ND
ND
ND
ND
ND
ND
08/18/15
0.62
ND
ND
ND
ND
ND
ND
---
02/16/16
0.62
ND
ND
ND
ND
ND
ND
ND
08/09/16
0.62
ND
ND
ND
ND
ND
ND
---
02/13/17
0.62
ND
ND
ND
ND
ND
ND
---
08/22/17
0.62
ND
ND
ND
ND
ND
ND
---
02/05/18
0.62
ND
ND
0.63J
ND
ND
ND
---
08/13/18
0.62
ND
ND
0.72J
ND
ND
ND
---
02/04/19
0.24
ND
ND
ND
ND
ND
ND
---
08/07/19
0.24
ND
ND
1.1
ND
ND
ND
---
09/04/19
0.24
--
--
ND
--
-
--
---
02/12/20
0.24
ND
ND
ND
ND
ND
ND
---
08/27/20
0.24
ND
ND
1.1
ND
ND
ND
---
09/30/20
0.24
-
--
ND
--
--
--
---
02/11/21
0.24
ND
ND
0.531
ND
ND
ND
---
08/19/21
0.39
ND
ND
0.84J
ND
ND
ND
ND
02/16/22
0.39
ND
ND
ND
ND
ND
ND
NA
9/28/221
0.39
ND
ND
0.72J
ND
ND
ND
NA
03/28/23
1 0.39
1 ND
I ND
I ND
I ND
I ND
I ND
I NA
Appendix D (Page 24 of 25)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-111
MW-211
MW-3R
MWA
MW-5
MW-6
NES-1
Xylenes, total
12/29/06
---
NO
1.4
NO
NO
NO
NO
---
07/12/07
---
NO
1.2J
NO
NO
NO
NO
---
NC21-=500 µg/L
12/19/07
---
NO
2.0
NO
NO
NO
ND
NO
07/08/08
---
NO
1.11
NO
NO
NO
NO
---
12/17/08
0.66
1.41
2.7
ND
NO
NO
NO
---
07/09/09
0..
NO
1.51
ND
NO
NO
NO
NO
12/16/09
0.66
NO
2.2
NO
NO
NO
NO
---
06/24/10
0.66
NO
0.73J
NO
NO
NO
NO
---
12/13/10
0.66
NO
2.0
NO
NO
NO
NO
---
06/20/11
0.66
NO
1.4J
NO
NO
NO
NO
---
12/05/11
0.66
NO
1.11
NO
NO
NO
NO
---
06/11/12
0.66
NO
0.911
NO
NO
NO
NO
NO
12/12/12
0.66
NO
0.97J
NO
ND
NO
NO
---
05/01/13
0.66
NO
0.68J
NO
ND
NO
NO
NO
08/05/13
0.66
NO
NO
NO
ND
NO
NO
---
02/24/14
0.66
NO
NO
NO
ND
NO
NO
NO
08/12/14
0.66
NO
NO
NO
ND
NO
NO
NO
03/10/15
0.66
NO
NO
NO
ND
NO
NO
NO
08/18/15
0.66
NO
NO
NO
ND
NO
NO
---
02/16/16
0.66
NO
NO
NO
ND
NO
NO
NO
08/09/16
0.66
NO
NO
NO
ND
NO
NO
---
02/13/17
0.66
NO
ND
NO
ND
NO
NO
---
08/22/17
0.66
NO
ND
NO
ND
NO
NO
---
02/05/18
0.66
NO
ND
NO
ND
NO
NO
---
08/13/18
0.66
NO
ND
NO
ND
NO
NO
---
02/04/19
0.63
NO
ND
NO
ND
NO
NO
---
08/07/19
0.63
NO
ND
NO
ND
NO
NO
---
02/12/20
0.63
NO
ND
NO
ND
NO
NO
---
08/27/20
0.63
NO
ND
NO
ND
NO
NO
---
02/11/21
0.63
NO
NO
NO
ND
NO
NO
---
08/19/21
0.34
NO
0.82J
NO
ND
NO
0.35J
NO
02/16/22
0.34
NO
2.9
3.8
ND
NO
NO
NA
9/28/22'
0.34
ND
NO
NO
ND
ND
ND
NA
03/28/23
0.34
NO
NO
NO
NO
NO
NO
NA
Zinc
09/08/94
---
110
160
NO
NO
320
430
---
12/01/94
---
132
NO
NO
70
164
NO
---
NC21-= 1,000 µg/L
02/09/95
---
144
89
NO
91
79
74
---
03/02/95
--
67
NO
NO
NO
111
NO
---
11/15/95
---
NO
50
NO
NO
ND
ND
---
05/28/96
--
136
NO
NO
NO
122
NO
---
11/22/96
---
79.0
48.0
28.0
NO
38.0
ND
---
06/17/97
--
370
410
33.0
39.0
36.0
69.0
---
12/01/97
---
140
110
11.0
45.0
34.0
30.0
---
05/20/98
--
70.0
63.0
23.0
31.0
47.0
34.0
---
11/19/98
---
61.0
33.0
21.0
17.0
53.0
10.0
---
07/21/99
--
NO
NO
NO
NO
NO
ND
---
11/16/99
---
ND
ND
NO
NO
ND
ND
---
05/10/00
--
NO
NO
NO
NO
NO
NO
---
10/26/00
---
NO
ND
NO
NO
NO
ND
---
04/18/01
--
NO
NO
NO
NO
NO
NO
---
10/27/01
---
NO
ND
NO
NO
ND
ND
---
06/13/02
--
NO
NO
NO
NO
382
NO
---
11/19/02
---
NO
ND
NO
NO
ND
ND
---
06/27/03
--
NO
NO
NO
NO
NO
NO
---
12/30/03
---
NO
ND
NO
NO
ND
ND
---
06/30/04
--
NO
NO
NO
NO
NO
NO
---
12/29/04
---
NO
ND
NO
66.0
ND
ND
---
06/29/05
--
NO
54.0
56.0
NO
NO
NO
---
12/29/05
---
ND
NO
NO
ND
NO
NO
---
06/28/06
--
NO
NO
NO
NO
NO
NO
---
12/29/06
---
8.01
NO
ND
4.11
4.31
4.11
---
07/12/07
--
9.6J
NO
ND
NO
NO
NO
---
12/19/07
---
4.3 B
14.3 B
6.3 B
NO
ND
NO
2.4 B
07/08/08
--
5.9 B
NO
ND
NO
4.1 B
NO
---
12/17/08
0.4
2.4 B
6.3 J
ND
NO
4.61
0.60 B
---
07/09/09
0.4
3.4 B
NO
ND
NO
NO
NO
6.1 B
12/16/09
0.4
4.6 B
NO
ND
NO
7.4 B
NO
---
06/24/30
0.4
0.58J
NO
NO
NO
NO
1.3J
---
12/13/10
0.4
4.5 B
NO
NO
NO
ND
NO
---
06/20/11
10
NO
NO
NO
NO
ND
NO
---
12/05/11
10
NO
NO
NO
NO
ND
ND
---
06/11/12
10
NO
20.9
NO
NO
ND
NO
NO
12/12/12
10
NO
NO
NO
NO
ND
ND
---
05/01/13
30
NO
NO
NO
NO
11.8
NO
10.0
08/05/13
10
ND
NO
NO
NO
NO
NO
---
02/24/14
10
NO
NO
NO
NO
NO
NO
NO
08/12/14
10
ND
NO
NO
NO
16.9
NO
---
08/18/15
5
7.4J
NO
ND
NO
5.2J
NO
---
02/16/16
5
14.5
16.7
17.8
46.1
5.91
NO
---
08/09/16
5
12.0
7.71
ND
NO
NO
NO
---
02/13/17
5
12.3
ND
NO
ND
9.81
6.01
---
08/22/17
5
NO
6.3J
NO
NO
NO
NO
---
02/05/18
5
6.71
17.9
NO
NO
ND
ND
---
08/13/18
5
NO
NO
NO
NO
8.11
NO
---
02/04/19
5
6.81
NO
5.0J
NO
ND
ND
---
08/07/19
3.9
8.3J
NO
NO
NO
NO
NO
---
02/12/20
3.9
4.31
ND
NO
NO
4.51
ND
---
08/27/20
9.5
NO
NO
NO
ND
NO
NO
---
02/11/21
9.5
12.9
ND
NO
ND
ND
ND
---
08/19/21
9.5
44.2
NO
NO
ND
NO
NO
NO
02/16/22
9.5
36.0
ND
NO
ND
ND
ND
NA
9/28/22'
9.5
NO
ND
NO
NO
NO
ND
NA
03/28/23
1 6.52
1 NO
I NO
I NO
1 11.6J
19.81
I NO
I NA
Notes.
Analytical results from September 1994 through February 2021 obtained from La Bella Associates Water Quality Monitoring Report - February 2021 Event.
Analytical results from August 2021 obtained from Garrett & Moore, Inc. Water Quality Monitoring Report - August 2021 Event,
NC 2L Standards are the Title 15A NCAC 02L .0202 Groundwater Standards dated April 1, 2022.
Bold concentrations exceed the NC 2L Standard.
All results are in micrograms per liter (ug/L(.
1. September 2022 MW-1R sample collected on 09/29/2022.
1= Estimated concentration above the method detection limit but below the laboratory reporting limit; <values shown in the table indicate less than the
laboratory repotting limit; B = Analyte was detected in the associated method blank; C8 = Result may be biased high due to carryover from previously analyzed sample
NO = Not detected; NR = Not reported; NE = Not established; ---= Not sampled, NA = Data not available; MDL = Laboratory method detection limil
Appendix D (Page 25 of 25)
M��K, �,.�oMy,,a.,��es-„snerea oo��men�aw.ve,�,eae�mve�na Moo,�vM�-0o3. x�n����eco.a�e,rraoza ran, e�,vwMRaewre�ae, H�s,�,�.ae�� Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
SW-1
SW-2
Metals
Arsenic
06/24/10
2.7
4.30 J
2.90 J
12/13/10
2.7
ND
ND
NC2B = 10 lag/L
06/20/11
5.0
ND
ND
12/05/11
5.0
ND
ND
06/11/12
5.0
ND
ND
12/12/12
5.0
ND
ND
05/01/13
5.0
ND
ND
08/05/13
5.0
ND
ND
02/24/14
5.0
ND
ND
08/12/14
5.0
---
ND
03/10/15
2.5
ND
ND
08/18/15
---
Dry
Dry
02/16/16
2.5
ND
ND
08/09/16
2.5
3.10 B
ND
02/13/17
5.0
ND
ND
08/22/17
5.0
ND
ND
02/05/18
5.0
ND
ND
08/13/18
5.0
ND
ND
02/04/19
5.0
ND
ND
08/07/19
4.7
ND
ND
02/12/20
4.7
ND
ND
08/27/20
---
Dry
Dry
02/11/21
4.7
---
ND
08/19/21
10.0
ND
ND
02/16/22
4.7
6.6 J
ND
09/28/22
4.7
Dry
ND
03/28/23
4.40
ND
ND
Barium
11/22/96
---
37.0
37.0
06/17/97
---
37.0
62.0
NC2B = 1,000 lag/L
12/01/97
---
53.0
45.0
05/20/98
---
24.0
69.0
11 /19/98
---
ND
100
07/21/99
---
ND
ND
11/16/99
---
ND
ND
05/10/00
---
ND
ND
10/26/00
---
ND
ND
04/18/01
---
ND
ND
10/27/01
---
ND
ND
06/13/02
---
---
---
11/19/02
---
ND
ND
06/27/03
---
ND
ND
12/30/03
---
ND
ND
06/30/04
---
ND
ND
12/29/04
---
ND
ND
12/29/04
---
ND
ND
06/29/05
---
ND
ND
12/29/05
---
ND
ND
06/28/06
---
ND
ND
12/29/06
---
37.5
40.6
07/12/07
---
33.3 J
---
12/19/07
---
52.6 B
149.0
07/08/08
---
33.8 J
161.0
12/17/08
0.2
30.2 B
33.5 B
07/09/09
0.2
36.8 B
78.4 B
12/16/09
0.2
31.2 B
36.2 B
06/24/10
0.2
34.5 B
71.3 B
12/13/10
0.2
36.1 B
91.0 J
06/20/11
5.0
40.3 J
93.0 J
12/05/11
5.0
32.9 J
59 .0 J
06/11/12
5.0
40.0 J
95.6 J
12/12/12
5.0
45.0 J
97.8 J
05/01/13
5.0
32.7 J
43.1 J
08/05/13
5.0
49.9 J
79.8 J
02/24/14
5.0
29.0 J
30.4 J
08/12/14
5.0
---
121
03/10/15
2.5
29.0 J
32.1 J
08/18/15
---
Dry
Dry
02/16/16
2.5
33.1 J
33.5 J
08/09/16
2.5
43.3 J
105
02/13/17
2.5
45.3 J
60.4 J
08/22/17
2.5
39.7 J
88.7 J
02/05/18
2.5
32.5 J
29.1 J
08/13/18
2.5
70.0 J
86.6 J
02/04/19
2.5
29.1
33.1
08/07/19
1.0
70.0
94.4
02/12/20
1.0
27.6
30.3
08/27/20
---
Dry
Dry
02/11/21
3.5
---
31.20
08/19/21
3.5
45.1
91.90
02/16/22
3.5
41.8
27.90
09/28/22
4.7
Dry
144.00
03/28/23
0.736
35.2
42.6
Appendix E (Page 1 of 8)
https://harlhick.sharepoint.com/sites/MasterF!Ies-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2023 First Half GWM/Tables/Butner Historic Tables Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
SW-1
SW-2
Beryllium
07/08/08
---
0.32 J
ND
12/17/08
0.1
ND
ND
NC2B = 65
07/09/09
0.1
ND
ND
12/16/09
0.1
0.12 J
ND
06/24/10
0.1
ND
ND
12/13/10
0.1
ND
ND
06/20/11
1.0
N D
ND
12/05/11
1.0
ND
ND
06/11/12
1.0
ND
ND
12/12/12
1.0
ND
ND
05/01/13
1.0
ND
ND
08/05/13
1.0
ND
ND
02/24/14
1.0
ND
ND
08/12/14
1.0
---
ND
03/10/15
0.50
ND
ND
08/18/15
---
Dry
Dry
02/16/16
0.50
ND
ND
08/09/16
0.50
N D
ND
02/13/17
0.50
ND
ND
08/22/17
0.50
N D
ND
02/05/18
0.50
N D
ND
08/13/18
0.50
ND
ND
02/04/19
0.50
ND
ND
08/07/19
0.20
ND
ND
02/12/20
0.20
0.21 J
0.25 J
08/27/20
---
Dry
Dry
02/11/21
0.7
---
ND
08/19/21
1.0
ND
ND
02/16/22
0.7
ND
ND
09/28/22
4.7
Dry
ND
03/28/23
0.330
ND
ND
Chromium
06/17/97
---
ND
3.00
12/01 /97
---
N D
ND
NC2B= 16 pg/L
05/20/98
---
ND
ND
11/19/98
---
ND
ND
07/21 /99
---
N D
ND
11/16/99
---
ND
ND
05/10/00
---
ND
ND
10/26/00
---
ND
ND
04/18/01
---
ND
ND
10/27/01
---
ND
ND
06/13/02
---
---
---
11/19/02
---
ND
ND
06/27/03
---
N D
ND
12/30/03
---
ND
ND
06/30/04
---
ND
ND
12/29/04
---
ND
ND
06/29/05
---
ND
ND
12/29/05
---
ND
ND
06/28/06
---
ND
ND
12/29/06
---
ND
ND
07/12/07
---
ND
---
12/19/07
---
2.20 B
2.60 B
07/08/08
---
2.50 J
2.20 J
12/17/08
0.4
1.40 J
2.60 J
07/09/09
0.4
2.6 J
1 .2 J
12/16/09
0.4
4.1 J
3.4 J
06/24/10
0.4
3.3 B
7.3 J
12/13/10
0.4
1.4 J
1.5 J
06/20/11
5.0
ND
ND
12/05/11
5.0
ND
ND
06/11/12
5.0
ND
7.2 J
12/12/12
5.0
ND
8.2 J
05/01/13
5.0
5.7 J
ND
08/05/13
5.0
ND
ND
02/24/14
5.0
ND
ND
08/12/14
5.0
---
ND
03/10/15
2.5
4.4 J
3.6 J
08/18/15
---
Dry
Dry
02/16/16
2.5
4.6 J
6.8 J
08/09/16
2.5
ND
ND
02/13/17
2.5
ND
ND
08/22/17
2.5
ND
ND
02/05/18
2.5
6.9 J
7.9 J
08/13/18
2.5
5.9 J
ND
02/04/19
2.5
ND
ND
08/07/19
1.0
ND
ND
02/12/20
1.0
5.3
4.7 J
08/27/20
---
Dry
Dry
02/11/21
3.7
---
4.00 J
08/19/21
5.0
ND
ND
02/16/22
3.7
ND
ND
09/28/22
4.7
Dry
ND
03/28/23
1.40
1.97J
ND
Appendix E (Page 2 of 8)
https://harlhick.sharepoint.com/sites/MasterF!Ies-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2023 First Half GWM/Tables/Butner Historic Tables Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
SW-1
SW-2
Cobalt
05/20/98
---
2.0
2.0
11/19/98
---
ND
3.0
ISTV j0.j = 3 pg/L
07/21/99
---
ND
ND
11/16/99
---
ND
ND
05/10/00
---
ND
ND
10/26/00
---
ND
ND
04/18/01
---
ND
ND
10/27/01
---
N D
22.0
06/13/02
---
---
---
11/19/02
---
ND
ND
06/27/03
---
ND
10.0
12/30/03
---
ND
ND
06/30/04
---
ND
ND
12/29/04
---
ND
ND
06/29/05
---
ND
ND
12/29/05
---
ND
ND
06/28/06
---
ND
ND
12/29/06
---
ND
ND
07/12/07
---
ND
---
12/19/07
---
4.2 B
1.20 B
07/08/08
---
4.80 B
10.5 B
12/17/08
0.6
1.70 B
1.1 B
07/09/09
0.6
ND
ND
12/16/09
0.6
ND
1.0 J
06/24/10
0.6
ND
ND
12/13/10
0.6
4.4 B
ND
06/20/11
5.0
ND
ND
12/05/11
5.0
ND
ND
Resampled
01/25/12
5.0
---
---
06/11/12
5.0
ND
5.10 J
12/12/12
5.0
ND
ND
05/01/13
5.0
ND
ND
08/05/13
5.0
ND
ND
02/24/14
5.0
ND
ND
08/12/14
5.0
---
ND
03/10/15
2.5
ND
ND
08/18/15
---
Dry
Dry
02/16/16
2.5
ND
ND
08/09/16
2.5
ND
ND
02/13/17
2.5
ND
ND
08/22/17
2.5
ND
ND
02/05/18
2.5
ND
ND
08/13/18
2.5
6.0 J
ND
02/04/19
2.5
ND
ND
08/07/19
1.1
2.5 J
ND
02/12/20
1.1
ND
ND
08/27/20
---
Dry
Dry
02/11/21
3.6
---
ND
08/19/21
5.0
ND
ND
02/16/22
3.6
ND
ND
09/28/22
4.7
Dry
10.7
03/28/23
0.840
1.12 J
ND
Copper
12/29/06
---
1.3 B
1.10 B
07/12/07
---
ND
---
NRWQC 131= 1,300 pg/L
12/19/07
---
5.3 B
ND
07/08/08
---
1.7 J
4.20 J
12/17/08
0.3
1.40 J
1.50 J
07/09/09
0.3
ND
ND
12/16/09
0.3
1.90 J
2.00 J
06/24/10
0.3
ND
3.10 J
12/13/10
0.3
0.31 B
ND
06/20/11
5.0
ND
ND
12/05/11
5.0
ND
ND
06/11/12
5.0
ND
5.50 J
12/12/12
5.0
ND
ND
05/01/13
5.0
ND
ND
08/05/13
5.0
ND
ND
02/24/14
5.0
ND
ND
08/12/14
5.0
---
ND
03/10/15
2.5
ND
ND
08/18/15
---
Dry
Dry
02/16/16
2.5
2.90 J
3.40 J
08/09/16
2.5
ND
ND
02/13/17
2.5
ND
ND
08/22/17
2.5
ND
ND
02/05/18
2.5
3.8 J
3.8 J
08/13/18
2.5
4.1 J
ND
02/04/19
2.5
ND
ND
08/07/19
2.1
3.2 J
3.3 J
02/12/20
2.1
3.9 J
3.4 J
08/27/20
---
Dry
Dry
02/11/21
4.3
---
ND
08/19/21
5.0
ND
ND
02/16/22
4.3
ND
ND
09/28/22
4.7
Dry
ND
03/28/23
3.68
ND
ND
Appendix E (Page 3 of 8)
https://harlhick.sharepoint.com/sites/MasterF!Ies-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2023 First Half GWM/Tables/Butner Historic Tables Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
SW-1
SW-2
Lead
05/20/98
---
ND
8.00
11/19/98
---
ND
ND
NC2BIlj = 18.96 pg/L
07/21/99
---
ND
10.0
11/16/99
---
ND
ND
05/10/00
---
ND
ND
10/26/00
---
ND
ND
04/18/01
---
ND
ND
10/27/01
---
ND
ND
06/13/02
---
---
---
11/19/02
---
ND
ND
06/27/03
---
ND
ND
12/30/03
---
ND
ND
06/30/04
---
ND
ND
12/29/04
---
ND
ND
06/29/05
---
ND
ND
12/29/05
---
ND
ND
06/28/06
---
ND
ND
12/29/06
---
ND
ND
07/12/07
---
ND
---
12/19/07
---
ND
ND
07/08/08
---
ND
ND
12/17/08
4.0
ND
ND
07/09/09
4.0
ND
ND
12/16/09
4.0
ND
ND
06/24/10
4.0
ND
ND
12/13/10
4.0
ND
ND
06/20/11
5.0
ND
ND
12/05/11
5.0
ND
ND
06/11/12
5.0
ND
ND
12/12/12
5.0
ND
ND
05/01/13
5.0
ND
ND
08/05/13
5.0
ND
ND
02/24/14
5.0
ND
ND
08/12/14
5.0
---
ND
03/10/15
2.5
ND
ND
08/18/15
---
Dry
Dry
02/16/16
2.5
ND
ND
08/09/16
2.5
ND
ND
02/13/17
2.5
ND
ND
08/22/17
2.5
ND
ND
02/05/18
2.5
ND
ND
08/13/18
2.5
ND
ND
NC2B I2j = 44.53 pg/L
02/04/19
2.5
ND
ND
NC21B I2j = 250.55 pg/L
08/07/19
1.6
2.2 J
ND
NUB I2j = 23.02 pg/L
02/12/20
1.6
ND
ND
08/27/20
---
Dry
Dry
NUB (2)=43.71 pg/L
02/11/21
4.5
---
ND
08/19/21
5.0
ND
ND
02/16/22
4.5
ND
ND
NC21B I2j = 280.85 pg/L
09/28/22
4.7
Dry
ND
NUB I2j = 59.98 u /L
03/28/23
2.99
ND
ND
Nickel
12/29/04
---
ND
ND
06/29/05
---
ND
ND
NC26= 25 pg/L
12/29/05
---
ND
ND
06/28/06
---
ND
ND
12/29/06
---
ND
2.9 J
07/12/07
---
3.8 J
---
12/19/07
---
6.0
31.5
07/08/08
---
3.2 J
29.8 J
12/17/08
1.7
2.4 B
4.0 B
07/09/09
1.7
4.1 J
12.3 J
12/16/09
1.7
3.8 B
4.4 B
06/24/10
1.7
ND
2.0 J
12/13/10
1.7
ND
14.2 J
06/20/11
5.0
ND
7.8 J
12/05/11
5.0
ND
5.3 J
06/11/12
5.0
ND
11.0 J
12/12/12
5.0
ND
13 .8 J
05/01/13
5.0
ND
ND
08/05/13
5.0
ND
5.6 J
02/24/14
5.0
ND
ND
08/12/14
5.0
---
20.3 J
03/10/15
2.5
3.0 J
3.8 J
08/18/15
---
Dry
Dry
02/16/16
2.5
2.9 J
4.7 J
08/09/16
2.5
3.3 J
15.2 J
02/13/17
2.5
ND
7.3 J
08/22/17
2.5
ND
16 .3 J
02/05/18
2.5
5.3 J
4.4 J
08/13/18
2.5
7.3 J
12.4 J
02/04/19
2.5
ND
2.7 J
08/07/19
0.90
8.8
14.8
02/12/20
0.90
3.1 J
4.6 J
08/27/20
---
Dry
Dry
02/11/21
3.5
---
4.40 J
08/19/21
3.5
ND
25.1
02/16/22
3.5
6.5
ND
09/28/22
4.7
Dry
46.6
03/28/23
1.61
3.71 J
7.10 J, B
Appendix E (Page 4 of 8)
https://harlhick.sharepoint.com/sites/MasterF!Ies-l/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2023 First Half GWM/Tables/Butner Historic Tables Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
SW-1
SW-2
Silver
07/12/07
---
2.20 J
---
12/19/07
---
ND
0.34 J
NUB I'j = 0.48 pg/L
07/08/08
---
0.35 B
1.00 J
12/17/08
0.1
ND
ND
07/09/09
0.1
ND
0.10 J
12/16/09
0.1
ND
0.16 J
06/24/10
0.1
ND
0.26 J
12/13/10
0.1
ND
0.28 B
06/20/11
5.0
ND
ND
12/05/11
5.0
ND
ND
06/11/12
5.0
ND
ND
12/12/12
5.0
ND
ND
05/01/13
5.0
ND
ND
08/05/13
5.0
ND
ND
02/24/14
5.0
ND
ND
08/12/14
5.0
---
ND
03/10/15
2.5
ND
ND
08/18/15
---
Dry
Dry
02/16/16
2.5
ND
ND
08/09/16
2.5
ND
ND
02/13/17
2.5
ND
ND
08/22/17
2.5
ND
ND
02/05/18
2.5
ND
ND
08/13/18
2.5
ND
ND
NUB (2) = 1.79 pg/L
02/04/19
2.5
ND
ND
NC21B (2) = 28.85 pg/L
08/07/19
2.5
ND
ND
NUB (2) = 0.64 pg/L
02/12/20
2.5
ND
ND
08/27/20
---
Dry
Dry
NUB (2)= 1.74 pg/L
02/11/21
2.5
---
ND
08/19/21
5.0
ND
ND
02/16/22
2.5
ND
ND
NC21B (2) = 34.91 pg/L
09/28/22
4.7
Dry
ND
NUB (2) = 2.86 /L
03/28/23
1.54
ND
ND
Thallium
12/29/04
---
ND
ND
06/29/05
---
ND
ND
ISTV (4)= 2 pg/L
12/29/05
---
ND
ND
06/28/06
---
ND
ND
12/29/06
---
ND
ND
07/12/07
---
ND
---
12/19/07
---
3.60 J
ND
07/08/08
---
3.40 J
ND
12/17/08
3.0
ND
ND
07/09/09
3.0
ND
ND
12/16/09
3.0
ND
ND
06/24/10
3.0
ND
ND
12/13/10
3.0
3.80 J
ND
06/20/11
5.4
ND
ND
12/05/11
5.4
ND
ND
06/11/12
5.4
ND
ND
12/12/12
5.4
ND
ND
05/01/13
5.4
ND
ND
08/05/13
5.4
ND
ND
02/24/14
5.4
ND
ND
08/12/14
5.4
ND
03/10/15
5.0
ND
ND
08/18/15
---
Dry
Dry
02/16/16
5.0
ND
ND
08/09/16
5.0
ND
ND
02/13/17
0.020
ND
ND
08/22/17
0.020
ND
ND
02/05/18
0.028
ND
ND
08/13/18
0.020
ND
ND
02/04/19
0.060
ND
ND
08/07/19
0.060
ND
ND
02/12/20
0.060
ND
ND
08/27/20
---
Dry
Dry
02/11 /21
0.1
ND
08/19/21
0.47
ND
ND
02/16/22
0.05
ND
ND
09/28/22
4.70
Dry
ND
03/28/23
0.121
ND
ND
Appendix E (Page 5 of 8)
https://harlhick.sharepoint.com/sites/MasterF!Ies-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2023 First Half GWM/Tables/Butner Historic Tables Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
SW-1
SW-2
Vanadium
12/29/06
---
1.60 J
2.00 J
07/12/07
---
4.60 J
---
SWSO) 25 pg/L
12/19/07
---
3.30 J
1.40 B
07/08/08
---
5.20 J
2.30 J
12/17/08
0.2
1.80 B
2.70 B
07/09/09
0.2
5.00 B
3.40 B
12/16/09
0.2
3.60 J
3.50 J
06/24/10
0.2
5.80 J
2.60 J
12/13/10
0.2
1.60 B
0.67 B
06/20/11
5.0
ND
ND
12/05/11
5.0
ND
ND
06/11/12
5.0
ND
11.5 J
12/12/12
5.0
ND
ND
05/01/13
5.0
ND
ND
08/05/13
5.0
ND
ND
02/24/14
5.0
ND
ND
08/12/14
5.0
---
ND
03/10/15
2.5
3.9 J
4.7 J
08/18/15
---
Dry
Dry
02/16/16
2.5
4.1 J
5.8 J
08/09/16
2.5
2.9 J
2.8 J
02/13/17
2.5
ND
ND
08/22/17
2.5
2.8 J
ND
02/05/18
2.5
6.6 J
5.9 J
08/13/18
2.5
8.3 J
3.1 J
02/04/19
2.5
2.9 J
2.7 J
08/07/19
1.3
1.4 J
2.3 J
02/12/20
1.3
4.5 J
5.0
08/27/20
---
Dry
Dry
02/11/21
3.9
ND
08/19/21
5.0
ND
ND
02/16/22
3.9
ND
4.4
09/28/22
4.7
Dry
ND
03/28/23
4.99
ND
ND
Zinc
11/22/96
---
11.0
ND
06/17/97
---
ND
ND
NC2B j'j = 45.80 pg/L
12/01/97
---
20.0
ND
05/20/98
---
20.0
28.0
11/19/98
---
ND
ND
07/21/99
---
ND
ND
11/16/99
---
ND
ND
05/10/00
---
ND
ND
10/26/00
---
ND
ND
04/18/01
---
ND
ND
10/27/01
---
ND
ND
06/13/02
---
---
---
11/19/02
---
ND
ND
06/27/03
---
ND
ND
12/30/03
---
ND
ND
06/30/04
---
ND
ND
12/29/04
---
ND
ND
06/29/05
---
ND
ND
12/29/05
---
ND
ND
06/28/06
---
ND
ND
12/29/06
---
ND
ND
07/12/07
---
ND
---
12/19/07
---
24.6 B
ND
07/08/08
---
ND
ND
12/17/08
0.4
ND
0.89 B
07/09/09
0.4
ND
4.90 B
12/16/09
0.4
2.60 B
2.60 B
06/24/10
0.4
ND
14.9
12/13/10
0.4
ND
9.80 B
06/20/11
10.0
ND
ND
12/05/11
10.0
ND
ND
06/11/12
10.0
ND
ND
12/12/12
10.0
ND
ND
05/01/13
10.0
ND
16.80
08/05/13
10.0
ND
ND
02/24/14
10.0
ND
ND
08/12/14
10.0
---
ND
03/10/15
5.0
7.7 B
7.8 B
08/18/15
---
Dry
Dry
02/16/16
5.0
7.0 J
ND
08/09/16
5.0
ND
ND
02/13/17
5.0
ND
5.2 J
08/22/17
5.0
ND
ND
02/05/18
5.0
ND
ND
08/13/18
5.0
6.0 J
ND
NC2B (2) = 87.87 pg/L
02/04/19
5.0
ND
ND
NUB (2) = 345.27 pg/L
08/07/19
3.9
ND
ND
NC21B (2) = 53.05 pg/L
02/12/20
3.9
ND
ND
08/27/20
---
Dry
Dry
NC21B (2) = 86.62 pg/L
02/11/21
9.5
---
ND
08/19/21
10.0
ND
ND
02/16/22
9.5
ND
ND
NC26 (2) = 379.30 pg/L
09/28/22
4.7
Dry
ND
NC21B (2) = 110.64 /L
03/28/23
6.52
ND
ND
Total Hardness (SM 2340B)
02/04/19
662
57,100
85,300
08/07/19
131
316,000
460,000
NUB = 100,000 pg/L
02/12/20
131
18,300
60,200
08/27/20
---
---
---
02/11/21
131.0
---
70,000
08/19/21
---
---
---
02/16/22
---
---
---
09/28/22
4.7
Dry
789,000
03/28/23
198
54,900
132,000
Appendix E (Page 6 of 8)
https://harlhick.sharepoint.com/sites/MasterF!Ies-l/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2023 First Half GWM/Tables/Butner Historic Tables Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
SW-1
SW-2
VOCs
Acetone
10/27/01
---
168 B
337 B
06/13/02
---
---
---
ISTV I4j = 3100 ug/L
06/13/02
11/19/02
---
ND
ND
06/27/03
---
ND
ND
12/30/03
---
ND
ND
06/30/04
---
ND
ND
12/29/04
---
ND
ND
06/29/05
---
ND
ND
12/29/05
---
ND
ND
06/28/06
---
ND
ND
12/29/06
---
ND
ND
07/12/07
---
ND
---
12/19/07
---
12.7 B
ND
07/08/08
---
ND
ND
12/17/08
20
ND
ND
07/09/09
20
ND
ND
12/16/09
2.2
ND
ND
06/24/10
2.2
2.80 B
ND
12/13/10
2.2
ND
3.00 J
06/20/11
2.2
ND
3.80 B
12/05/11
2.2
ND
7.20 B
06/11/12
2.2
ND
5.50 B
12/12/12
10.0
ND
ND
05/01/13
10.0
ND
ND
08/05/13
10.0
ND
ND
02/24/14
10.0
ND
ND
08/12/14
10.0
---
ND
03/10/15
10.0
ND
ND
08/18/15
---
Dry
Dry
02/16/16
10.0
ND
ND
08/09/16
10.0
ND
ND
02/13/17
10.0
ND
ND
08/22/17
10.0
ND
ND
02/05/18
10.0
ND
ND
08/13/18
10.0
ND
ND
02/04/19
6.2
ND
ND
08/07/19
6.2
ND
ND
02/12/20
6.2
ND
ND
08/27/20
---
Dry
Dry
02/11/21
6.2
---
ND
08/19/21
25.0
ND
ND
02/16/22
5.1
ND
ND
09/28/22
4.7
Dry
ND
03/28/23
5.1
ND
ND
Chlorobenzene
06/27/03
---
ND
7.20
12/30/03
---
ND
ND
NUB = 488 pg/L
06/30/04
---
ND
ND
12/29/04
---
ND
ND
06/29/05
---
ND
ND
12/29/05
---
ND
ND
06/28/06
---
ND
ND
12/29/06
---
ND
ND
07/12/07
---
ND
---
12/19/07
---
ND
ND
07/08/08
---
ND
ND
12/17/08
0.23
ND
ND
07/09/09
0.23
ND
ND
12/16/09
0.23
ND
ND
06/24/10
0.23
ND
ND
12/13/10
0.23
ND
ND
06/20/11
0.23
ND
ND
12/05/11
0.23
ND
ND
06/11/12
0.23
ND
ND
12/12/12
0.23
ND
ND
05/01/13
0.23
ND
ND
08/05/13
0.23
ND
ND
02/24/14
0.23
ND
ND
08/12/14
0.23
ND
03/10/15
0.23
ND
ND
08/18/15
---
Dry
Dry
02/16/16
0.23
ND
ND
08/09/16
0.23
ND
ND
02/13/17
0.23
ND
ND
08/22/17
0.23
ND
ND
02/05/18
0.23
ND
ND
08/13/18
0.23
ND
ND
02/04/19
0.23
ND
ND
08/07/19
0.23
ND
ND
02/12/20
0.23
ND
ND
08/27/20
---
Dry
Dry
02/11/21
0.2
---
ND
08/19/21
1.0
ND
ND
02/16/22
0.28
ND
ND
09/28/22
4.70
Dry
ND
03/28/23
0.28
ND
ND
Appendix E (Page 7 of 8)
https://harlhick.sharepoint.com/sites/MasterF!Ies-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2023 First Half GWM/Tables/Butner Historic Tables Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
SW-1
SW-2
Chloromethane
07/09/09
0.11
ND
0.19 J
12/16/09
0.11
ND
ND
ISTV j0.j = 2.6 pg/L
06/24/10
0.11
ND
ND
12/13/10
0.11
ND
ND
06/20/11
0.11
ND
ND
12/05/11
0.11
ND
ND
06/11/12
0.11
ND
ND
12/12/12
0.11
ND
ND
05/01/13
0.11
ND
ND
08/05/13
0.11
ND
ND
02/24/14
0.11
ND
ND
08/12/14
0.11
---
ND
03/10/15
0.11
ND
ND
08/18/15
---
Dry
Dry
02/16/16
0.11
ND
ND
08/09/16
0.11
ND
ND
02/13/17
0.11
0.17 J
0.19 J
08/22/17
0.11
ND
ND
02/05/18
0.11
ND
ND
08/13/18
0.11
ND
ND
02/04/19
0.39
ND
ND
08/07/19
0.39
ND
ND
02/12/20
0.39
ND
ND
08/27/20
---
Dry
Dry
02/11/21
0.4
---
ND
08/19/21
1.0
ND
ND
02/16/22
0.5
ND
ND
09/28/22
4.7
Dry
ND
03/28/23
0.54
ND
ND
1,4-Dioxane (p-Dioxane)
08/13/18
1.9
ND
14.1
02/04/19
1.9
ND
ND
ISTV (3) = 0.35 ua/L
08/07/19
1.2
10.50
22.3
02/12/20
1.2
ND
1.2 J
08/27/20
---
Dry
Dry
02/11/21
1.2
---
3.00
08/19/21
1.0
ND
26.0
02/16/22
0.86
6.0
ND
09/28/22
4.7
Dry
54.5
03/28/23
0.86
1.3 J
5.2
Notes:
Analytical results from November 1996 through February 2021 obtained from LaBella
Associates Water Quality Monitoring Report - February 2021 Event.
Analytical results from August 2021 obtained from Garrett & Moore, Inc. Water Quality
Monitoring Report - August 2021 Event.
15A NCAC 213 Water Quality Standards (26 Standards) for Surface Water (Class WS IV,
nutrient sensitive waters [NSW]) dated July 26, 2021.
Bold concentrations exceed the NC 2B Standard.
1. For surface water sampling events without hardness data, 2B Standard exceedances
for hardness -dependent metals shown are calculated using a published median
value of 33 mg/L obtained from North Carolina Hardness Statistics for Picture Creek.
2. For surface water sampling events during which hardness data was collected,
2B Standards for hardness -dependent metals are calculated using a site mean
hardness value for that specific sampling event. For sampling events with site mean
hardness values above 400 mg/L, a maximun 400 mg/L value was used to calculate the
26 Standard.
3. No 26 Standard established, value shown is EPA Nationally Recommended Water Quality
Criteria (NRWQC) for Aquatic Life & Human Health.
4. No 26 Standard or NWQC established, value shown is North Carolina In -Stream Target
Values for Surface Waters (ISTV).
5. No 26 Standard, NWQC, or ISTV established, value shown is Solid Waste Section Limits (SWSL).
All concentrations are in micrograms per liter (pg/L).
J = Estimated concentration above the adjusted method detection limit and below the
adjusted method reporting limit; B = Blank -qualified data, result is expected to be biased
high based on concentrations in the blanks; MDL = laboratory method detection limit;
ND = Not detected above laboratory method reporting limit; NR = Not Reported;
NE= Not established; --- = Not sampled; VOC = Volatile organic compound;
< values shown in the table indicate less than the laboratory MDL, or laboratory repoting
limit if no MDL reported.
Appendix E (Page 8 of 8)
https://harlhick.sharepoint.com/sites/MasterF!Ies-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2023 First Half GWM/Tables/Butner Historic Tables Hart & Hickman, PC

Appendix F
Summary of Historical Monitoring Natural Attenuation Parameters
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

Appendix F
Summary of Historical Monitored Natural Attenuation
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Parameter
Date
Units
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Temperature (FP)
12/30/03
°C
15.40
11.10
11.20
12.50
13.60
14.20
---
12/19/07
°C
12.30
12.50
13.10
14.40
14.90
14.40
13.30
05/01/13
°C
15.70
13.70
15.10
14.40
14.20
14.20
12.50
08/14/14
°C
17.80
18.00
19.20
19.40
16.80
17.20
16.00
03/10/15
°C
17.30
16.00
15.90
13.80
13.30
13.70
16.10
08/18/15
°C
16.43
17.78
17.79
17.25
16.47
16.64
16.05
02/16/16
°C
14.60
13.80
14.40
14.00
12.00
13.40
13.10
08/09/16
°C
16.40
17.30
19.40
18.20
17.10
16.80
17.90
02/13/17
°C
14.80
14.40
14.90
15.70
14.10
15.30
15.20
08/22/17
°C
17.40
17.90
17.90
17.50
17.40
16.60
17.80
02/05/18
°C
13.06
11.66
13.05
14.46
13.83
14.53
12.25
08/13/18
°C
17.40
21.10
18.20
19.30
20.60
18.40
16.60
02/04/19
°C
13.20
15.50
16.50
14.90
14.50
15.40
13.70
08/06/19
°C
17.00
22.70
17.60
19.90
17.30
18.20
16.00
08/14/19
°C
---
---
---
---
---
24.30
---
02/12/20
°C
17.20
14.30
14.80
16.50
15.10
16.40
14.80
08/27/20
°C
17.20
18.90
19.90
22.20
20.30
21.10
20.10
09/30/20
°C
---
---
19.30
---
---
---
---
02/11/21
°C
15.10
12.40
13.60
11.80
11.50
11.30
14.00
08/19/21
°C
19.70
19.40
19.90
25.30
19.30
22.30
17.70
02/16/22
°C
14.90
20.60
10.70
16.90
14.20
10.40
14.70
09/28/22'
°C
15.9
17.8
17.8
17.77
17.23
17.2
16.69
03/28/23
°C
15.6
14.3
14.8
16.2
15.2
16.2
14.6
pH (FP)
12/30/03
S.U.
7.31
6.54
6.81
6.90
7.24
7.29
---
12/19/07
S.U.
6.89
6.90
7.07
6.87
7.39
6.67
7.64
05/01/13
S.U.
7.32
6.37
6.61
6.42
6.92
7.13
6.10
08/14/14
S.U.
5.84
6.36
6.96
6.79
7.00
6.48
5.59
03/10/15
S.U.
6.11
6.37
6.56
6.30
6.25
6.55
5.68
08/18/15
S.U.
5.12
6.68
6.48
6.76
7.03
6.78
4.94
02/16/16
S.U.
6.15
6.15
6.61
6.69
7.14
6.10
6.52
08/09/16
S.U.
4.79
5.05
5.30
5.06
4.41
5.75
6.46
02/13/17
S.U.
6.10
6.55
6.76
6.78
6.24
7.37
6.23
08/22/17
S.U.
6.58
6.46
6.45
6.98
7.53
7.16
7.16
02/05/18
S.U.
7.11
6.80
7.01
7.33
7.22
7.54
5.53
08/13/18
S.U.
6.30
6.45
6.64
6.38
7.15
7.03
5.54
02/04/19
S.U.
6.17
6.44
7.16
6.87
6.07
7.02
5.13
08/06/19
S.U.
8.84
6.17
6.49
6.69
7.44
7.49
6.79
08/14/19
S.U.
---
---
---
---
---
6.47
---
02/12/20
S.U.
5.63
4.88
6.30
6.73
6.27
7.10
8.72
08/27/20
S.U.
5.08
6.13
6.42
6.45
6.71
6.73
5.48
09/30/20
S.U.
---
---
6.57
---
---
---
---
02/11/21
S.U.
5.65
6.13
6.45
5.94
6.30
6.15
4.38
08/19/21
S.U.
5.52
6.27
6.59
6.36
6.52
6.60
4.94
02/16/22
S.U.
5.64
6.29
6.77
6.41
6.73
6.62
4.95
09/28/22'
S.U.
5.98
6.38
6.70
6.36
6.96
6.95
4.88
03/28/23
S.U.
5.52
6.46
6.92
7.16
4.87
6.65
4.38
Conductivity (FP)
12/19/07
PS/cm
96.00
1964.00
1591.00
1245.00
---
---
510.00
05/01/13
PS/cm
111.00
1587.00
1357.00
1150.00
195.00
594.00
69.60
08/14/14
PS/cm
231.00
1897.00
1534.00
1413.00
522.00
565.00
172.60
03/10/15
PS/cm
90.00
996.00
1277.00
1186.00
106.00
504.00
114.00
08/18/15
PS/cm
134.00
1630.00
1680.00
1244.00
617.00
534.00
83.00
02/16/16
PS/cm
72.40
1611.00
1369.00
1234.00
164.00
474.00
78.20
08/09/16
PS/cm
100.70
1924.00
1535.00
1475.00
660.00
600.00
95.60
02/13/17
PS/cm
68.00
1535.00
1314.00
1155.00
272.00
508.00
89.60
08/22/17
PS/cm
77.10
1,752
1350.00
1446.00
755.00
560.00
175.00
02/05/18
PS/cm
80.00
1460.00
1247.00
1230.00
676.00
633.00
50.00
08/13/18
PS/cm
101.20
2013.00
1608.00
1569.00
870.00
620.00
131.20
02/04/19
PS/cm
107.90
1692.00
1266.00
1364.00
276.10
546.00
91.60
08/06/19
PS/cm
113.40
1719.00
1307.00
1287.00
775.00
545.30
98.50
08/14/19
PS/cm
---
---
---
---
---
559.00
---
02/12/20
PS/cm
94.80
1946.00
1475.00
1471.00
276.90
588.30
95.50
08/27/20
PS/cm
82.40
1601.00
1217.00
1335.00
773.00
577.00
140.50
09/30/20
PS/cm
---
---
1409.00
---
---
---
---
02/11/21
PS/cm
85.20
1251.00
1004.00
838.00
211.30
323.80
65.90
08/19/21
PS/cm
127.40
206.20
1568.00
1658.00
1044.00
630.00
125.60
02/16/22
PS/cm
91.60
2095.00
1543.00
1421.00
1056.00
604.80
81.40
09/28/22'
PS/cm
77.9
2016
1590
1667
1391
684
184
03/28/23
PS/cm
92.8
1824
1390
1543
1657
655
105.8
Redox Potential (ORP) (FP)
12/30/03
mV
257.2
76.20
207.6
212.70
187.30
123.60
---
12/19/07
mV
146.00
45.00
142.00
134.00
---
---
138.00
05/01/13
mV
111.70
-26.70
55.20
120.50
---
---
227.10
08/14/14
mV
115.80
-37.20
86.90
---
---
---
---
03/10/15
mV
87.00
0.80
56.30
---
---
---
96.70
08/18/15
mV
134.70
-96.30
-68.80
-33.90
-49.90
---
182.80
02/16/16
mV
111.70
-47.30
16.90
---
---
---
173.40
08/09/16
mV
56.00
-43.10
-6.90
---
---
---
---
02/13/17
mV
87.40
0.80
-16.50
---
---
---
---
08/22/17
mV
102.90
-37.10
87.00
---
---
---
116.70
02/05/18
mV
57.10
29.50
49.40
---
---
---
109.20
08/13/18
mV
117.90
-60.50
-49.30
---
---
64.40
28.40
02/04/19
mV
197.70
-64.30
132.20
---
9.60
---
281.20
08/06/19
mV
164.70
-69.30
-33.70
171.60
188.60
232.60
231.80
08/14/19
mV
---
---
---
---
---
237.60
---
02/12/20
mV
336.50
33.40
22.40
254.50
299.90
282.00
245.60
08/27/20
mV
242.70
-10.80
12.40
190.30
196.50
188.00
240.60
09/30/20
mV
---
---
232.30
---
---
---
---
02/11/21
mV
166.80
4.10
34.80
197.40
---
278.80
284.50
08/19/21
mV
112.30
65.00
79.90
58.70
52.50
125.00
42.30
02/16/22
mV
172.30
-48.00
-8.80
88.00
-1.50
194.70
282.80
09/28/22'
mV
206.1
-84.7
-52.2
40.8
-42.1
41.6
139.1
03/28/23
mV
1 192.7
-206.7
1 -45.6
1 -212.6
1 -306.1
1 165.1
217.2
Appendix F (Page 1 of 6)
https://harthick.shampoint.w WsitesIMasterFiles-l/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2023 First HaH GWMF-ables/Butner Historic Tables Hart & Hickman, PC

Appendix F
Summary of Historical Monitored Natural Attenuation
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Parameter
Date
Units
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Dissolved Oxygen (DO) (FP)
12/30/03
mg/L
9.49
4.84
---
---
---
---
---
12/19/07
mg/L
---
1.88
1.44
3.21
---
---
0.70
05/01/13
mg/L
4.40
1.37
1.79
4.65
---
---
2.90
08/14/14
mg/L
4.44
3.26
2.48
---
---
---
2.80
03/10/15
mg/L
3.84
1.47
1.80
---
---
---
1.85
08/18/15
mg/L
4.95
5.75
1.30
---
3.79
---
1.77
02/16/16
mg/L
4.45
3.66
2.51
---
---
---
3.72
08/09/16
mg/L
3.17
2.87
2.29
---
---
---
---
02/13/17
mg/L
5.37
3.16
2.14
---
---
---
---
08/22/17
mg/L
5.43
2.24
4.02
---
---
---
5.86
02/05/18
mg/L
8.08
6.61
9.16
---
---
---
8.36
08/13/18
mg/L
6.31
3.20
2.35
---
---
4.80
3.91
02/04/19
mg/L
1.26
1.82
4.17
---
4.17
---
1.63
08/06/19
mg/L
3.77
0.32
0.26
4.55
5.30
2.76
3.04
08/14/19
mg/L
---
---
---
---
---
1.95
---
02/12/20
mg/L
5.11
0.65
1.36
4.30
3.48
2.44
6.37
08/27/20
mg/L
0.63
0.22
0.48
5.04
6.22
4.14
3.16
09/30/20
mg/L
---
---
2.00
---
---
---
---
02/11/21
mg/L
1.75
1.05
0.40
7.40
5.41
3.23
2.18
08/19/21
mg/L
0.68
3.55
1.02
0.31
0.19
1.88
2.07
02/16/22
mg/L
2.06
0.14
0.99
0.34
0.32
3.62
2.94
09/28/22'
mg/L
4.72
0.29
0.18
0.60
0.30
0.47
0.51
03/28/23
mg/L
3.90
0.06
0.21
0.09
3.42
1.34
1.91
Dissolved CO2 (FP)
12/19/07
mg/L
25.00
365.00
175.00
295.00
---
---
60.00
05/01/13
mg/L
30.00
245.00
125.00
225.00
---
---
45.00
08/14/14
mg/L
60.00
390.00
185.00
---
---
---
75.00
03/10/15
mg/L
50.00
110.00
75.00
---
---
---
50.00
08/18/15
mg/L
30.00
275.00
125.00
---
---
---
60.00
02/16/16
mg/L
30.00
210.00
230.00
---
---
---
20.00
08/09/16
mg/L
---
185.00
210.00
---
---
---
---
02/13/17
mg/L
---
---
---
---
---
---
---
08/22/17
mg/L
---
---
---
---
---
---
---
02/05/18
mg/L
---
---
---
---
---
---
---
08/13/18
mg/L
---
---
---
---
---
---
---
02/04/19
mg/L
75.00
---
130.00
---
---
---
---
08/06/19
mg/L
---
475.00
250.00
---
---
---
---
02/12/20
mg/L
---
260.00
---
---
---
---
---
08/27/20
mg/L
---
---
---
---
---
---
---
02/11/21
mg/L
---
---
---
---
---
---
---
08/19/21
mg/L
---
---
---
---
---
02/16/22
mg/L
---
---
---
---
---
---
---
09/28/22'
mg/L
---
---
---
---
---
---
03/28/23
mg/L
---
---
---
---
---
---
---
Fe, Ferrous (+2) (FP)
12/30/03
mg/L
ND
1.50
ND
ND
0.22
ND
---
12/19/07
mg/L
ND
7.20
ND
ND
---
---
0.20
05/01/13
mg/L
ND
1.00
ND
ND
---
---
ND
08/14/14
mg/L
ND
2.50
ND
---
---
---
ND
03/10/15
mg/L
ND
5.30
ND
---
---
---
ND
08/18/15
mg/L
ND
4.50
1.00
---
---
---
ND
02/16/16
mg/L
ND
4.00
1.30
---
---
---
ND
08/09/16
mg/L
---
3.10
1.00
---
---
---
---
02/13/17
mg/L
ND
3.00
1.50
---
---
---
---
08/22/17
mg/L
ND
3.50
1.50
---
---
---
ND
02/05/18
mg/L
ND
4.00
0.50
---
---
---
ND
08/13/18
mg/L
ND
5.50
0.20
---
---
---
---
02/04/19
mg/L
ND
---
ND
---
---
---
---
08/06/19
mg/L
---
3.50
0.50
---
---
---
---
02/12/20
mg/L
---
1.00
0.50
---
---
---
---
08/27/20
mg/L
---
4.50
1.00
---
---
---
---
02/11/21
mg/L
0.00
1.50
0.50
---
---
---
0.00
08/19/21
mg/L
---
---
---
---
--
02/16/22
mg/L
---
---
---
---
---
---
09/28/22'
mg/L
---
7.00
0.50
---
---
---
---
03/28/23
mg/L
ND
4.5
ND
---
---
---
ND
Alkalinity (CaCO3)
12/30/03
mg/L
37.00
800.00
690.00
640.00
68.00
350.00
---
12/19/07
mg/L
39.00
763.00
726.00
619.00
---
---
190.00
05/01/13
mg/L
43.40
757.00
660.00
645.00
---
---
10.40
08/14/14
mg/L
41.10
784.00
661.00
---
---
---
14.50
03/10/15
mg/L
38.00
744.00
653.00
---
---
---
8.80
08/18/15
mg/L
37.80
772.00
664.00
---
---
---
10.30
02/16/16
mg/L
41.20
792.00
741.00
---
---
---
8.73
08/09/16
mg/L
---
783.00
629.00
---
---
---
---
02/13/17
mg/L
37.90
753.00
654.00
---
---
---
8.79
08/22/17
mg/L
42.40
766.00
678.00
---
---
---
10.20
02/05/18
mg/L
44.40
821.00
752.00
---
---
---
7.52
08/13/18
mg/L
---
768.00
722.00
---
---
---
---
02/04/19
mg/L
62.00
856.00
638.00
---
---
---
7.02
08/06/19
mg/L
---
839.00
754.00
---
---
---
---
02/02/20
mg/L
---
818.00
646.00
---
---
---
---
08/27/20
mg/L
47.60
909.00
735.00
---
---
---
---
02/11/21
mg/L
53.90
875.00
724.00
---
---
---
ND
08/19/21
mg/L
---
914.00
636.00
---
---
---
---
02/16/22
mg/L
35.00
820.00
630.00
---
---
---
5.00
09/28/22'
mg/L
---
864.00
792.00
---
---
---
---
03/28/23
mg/L
42.00
860.00
731.00
---
I ---
I ---
1 8.90
Appendix F (Page 2 of /6+)
https://harthick.shampoint.w WsitesIMasterFiles-l/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2023 First HaH GWM/Tables/Butner Historic Tables Hart & Hickman, Pl.

Appendix F
Summary of Historical Monitored Natural Attenuation
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Parameter
Date
Units
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Chloride
12/30/03
ni
3.50
280.00
170.00
82.00
13.00
44.00
---
12/19/07
ni
ND
13.10
297.00
89.10
---
---
7.90
05/01/13
ni
3.54
258.00
180.00
123.00
---
---
2.85
08/14/14
ni
5.53
264.00
144.00
---
---
---
5.00
03/10/15
ni
3.80
266.00
194.00
---
---
---
4.09
08/18/15
ni
4.69
267.00
178.00
---
---
---
3.90
02/16/16
ni
3.92
274.00
186.00
---
---
---
3.24
08/09/16
mg/L
---
269.00
191.00
---
---
---
---
02/13/17
mg/L
3.45
309.00
215.00
---
---
---
5.09
08/22/17
ni
3.73
318.00
214.00
---
---
---
5.86
02/05/18
ni
3.92
280.00
205.00
---
---
---
2.52
08/13/18
ni
-
221.00
165.00
---
---
---
---
02/04/19
ni
3.42
221.00
147.00
---
---
---
4.52
08/06/19
ni
---
203.00
154.00
---
---
---
---
02/12/20
ni
---
224.00
153.00
---
---
---
---
08/27/20
ni
3.84
208.00
148.00
---
---
---
5.33
02/11/21
ni
3.67
201.00
148.00
---
---
---
4.06
08/19/21
ni
---
0.217
0.157
---
---
---
---
02/16/22
ni
---
---
---
---
---
09/28/22'
ni
---
191.00
150.00
---
---
---
---
03/28/23
ni
3.84
220.00
175.00
---
---
---
4.32
Dissolved Hydrogen
05/01/13
nM
0.40
0.63
0.61
0.50
---
---
0.47
08/14/14
nM
1.40
1.60
5.40
-
---
---
1.40
03/10/15
nM
1.20
1.40
1.40
1.00
---
---
1.40
08/18/15
nM
1.70
2.20
1.70
---
---
---
1.50
02/16/16
nM
2.00
1.70
1.90
---
---
---
1.50
08/09/16
nM
---
1.50
1.60
---
---
02/13/17
nM
---
---
---
---
---
08/22/17
nM
---
---
---
---
---
02/05/18
nM
---
---
---
---
---
08/13/18
nM
---
---
---
---
---
02/04/19
nM
6.70
7.60
7.40
---
---
---
---
08/06/19
nM
---
2.00
5.40
---
---
---
6.80
02/12/20
nM
---
5.80
2.70
---
---
---
---
08/27/20
nM
---
1.0 J
1.2 J
---
---
---
---
09/10/20
nM
1.80
---
---
---
---
---
---
02/11/21
nM
---
---
---
---
---
---
2.40
08/19/21
nM
---
---
---
---
02/16/22
nM
1.2 J
1.3 J
3.2
---
---
---
2.40
09/28/221
nM
---
---
---
---
---
03/28/23
nM
---
---
---
---
---
Nitrate-N
12/30/03
ni
0.12
ND
ND
ND
ND
0.13
---
12/19/07
ni
ND
ND
ND
ND
---
---
13.00
05/01/13
ni
0.16
ND
ND
ND
---
---
3.58
08/14/14
mg/L
.115 J
ND
ND
---
---
---
2.02 J
03/10/15
mg/L
.252 J
ND
ND
---
---
---
2.56 J
08/18/15
mg/L
.124 J
ND
ND
---
---
---
3.27 J
02/16/16
mg/L
.36 J
ND
ND
---
---
---
2.54 J
08/09/16
mg/L
---
ND
ND
---
---
---
---
02/13/17
mg/L
.248 J
.189 J
ND
---
---
---
2.63 J
08/22/17
mg/L
.118 J
.0186 J
.0451 J
---
---
---
4.06 J
02/05/18
mg/L
.310 J
ND
.0120 J
---
---
---
1.15 J
08/13/18
mg/L
---
ND
ND
---
---
---
---
02/04/19
ni
0.20
ND
0.11
---
---
---
6.50
08/06/19
ni
---
ND
ND
---
---
---
---
02/12/20
ni
---
0.07
0.36
---
---
---
---
08/27/20
ni
ND
ND
ND
---
---
---
6.34
02/11/21
ni
0.06
ND
0.06
---
---
---
4.65
08/19/21
ni
---
ND
ND
---
---
---
02/16/22
ni
ND
ND
ND
---
---
---
ND
09/28/221
ni
---
<0.10
<0.10
---
---
---
---
03/28/23
ni
0.315
0.0248 J
ND
---
---
---
5.64
Sulfate
12/30/03
ni
ND
ND
ND
2.60
9.60
9.00
---
12/19/07
ni
ND
ND
ND
ND
---
---
36.80
05/01/13
ni
ND
ND
ND
4.69
---
---
10.70
08/14/14
mg/L
1.08 J
1.2 J
ND
---
---
---
5.84 J
03/10/15
mg/L
1.52 J
1.13 J
1.52 J
---
---
---
7.04 J
08/18/15
mg/L
1.56 J
1.31 J
2.49 J
---
---
---
5.24 J
02/16/16
ni
1.5 J
1.7 J
1.8 J
---
---
---
10.0 J
08/09/16
ni
---
1.22
1.75 J
---
---
---
---
02/13/17
mg/L
1.53 J
1.59 J
1.78 J
---
---
---
11.9 J
08/22/17
mg/L
ND
ND
.626 J
---
---
---
11.2 J
02/05/18
ni
ND
ND
.627 J
---
---
---
7.48 J
08/13/18
ni
ND
ND
.630 J
---
---
---
---
02/04/19
ni
1.15
ND
1.10
---
---
---
6.75
08/06/19
ni
---
ND
.711 J
---
---
---
---
02/12/20
ni
---
ND
.85 J
---
---
---
---
08/27/20
ni
ND
ND
ND
---
---
---
5.21
02/11/21
ni
1.41
ND
0.82
---
---
---
5.92
08/19/21
ni
---
ND
ND
---
---
---
---
02/16/22
mg/L
ND
ND
0.543 J
---
---
---
6.62
09/28/221
ni
---
<1.0
<1.0
---
---
---
---
03/28/23
ni
.586 J
.575 J
1.06
---
---
---
6.38
Sulfide
08/14/14
ni
ND
ND
ND
---
---
---
ND
03/10/15
ni
ND
ND
ND
---
---
---
ND
08/18/15
ni
ND
ND
ND
---
---
---
1.00
02/16/16
ni
ND
ND
ND
---
---
---
ND
08/09/16
ni
---
ND
ND
---
---
---
---
02/13/17
mg/L
ND
ND
ND
---
---
---
---
08/22/17
mg/L
ND
ND
ND
---
---
---
---
02/05/18
ni
---
---
---
---
---
---
---
08/13/18
ni
---
---
---
---
---
---
---
02/04/19
ni
ND
ND
ND
---
---
---
ND
08/06/19
ni
ND
ND
---
---
---
---
02/12/20
ni
0.083 J
ND
---
---
---
---
08/27/20
ni
ND
ND
ND
---
---
---
ND
02/11/21
ni
---
---
---
---
---
---
---
08/19/21
ni
---
---
---
---
---
--
02/16/22
ni
ND
ND
ND
---
---
---
ND
09/28/221
ni
---
---
---
---
---
---
03/28/23
ni
ND
I ND
I ND
I ND
ND
ND
ND
Appendix F (Page 3 of �6+)
https//haahlck.sharepoinLcomisiles/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 -Granville Co. Butner LF/2023 First Hal( GWM/Tables/Butner Historic Tables Hart & Hickman, Pl.

Appendix F
Summary of Historical Monitored Natural Attenuation
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Parameter
Date
Units
MWAR
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Total Organic Carbon
12/19/07
ni
2.90
54.30
23.20
17.20
---
---
7.20
05/01/13
ni
2.24
29.50
30.00
19.40
---
---
5.74
08/14/14
ni
ND
229.00
25.50
---
---
---
8.39
03/10/15
ni
0.781J
34.80
9.54
---
---
---
1.88
08/18/15
ni
0.917J
32.90
9.86
---
---
---
27.80
02/16/16
ni
1.50
27.60
8.46
---
---
---
40.90
08/09/16
mg/L
---
29.40
9.53
---
---
---
---
02/13/17
mg/L
ND
28.50
9.72
---
---
---
1.36
08/22/17
mg/L
ND
29.10
9.92
---
---
---
1.71
02/05/18
ni
ND
25.90
11.40
---
---
---
4.24
08/13/18
ni
ND
25.80
10.20
---
---
---
ND
02/04/19
ni
ND
27.90
8.02
---
---
---
1.60
08/06/19
ni
---
33.30
15.10
---
---
---
---
02/12/20
ni
---
25.40
7.46
---
---
---
---
08/27/20
ni
0.689 J
29.80
8.19
---
---
---
0.916 J
02/11/21
ni
ND
28.20
7.68
---
---
---
1.61
08/19/21
ni
---
28.20
7.69
---
---
---
---
02/16/22
ni
ND
26.50
7.80
---
---
---
1.18
09/28/221
ni
---
26.40
8.30
---
---
---
---
03/28/23
ni
ND
24.30
9.31
---
---
---
1.11
Biochemical Oxygen Demand (BOD 5-day)
08/14/14
ni
ND
83.40
2.49
---
---
---
-
03/10/15
ni
2.55
10.60
ND
---
---
---
ND
08/18/15
ni
2.22
11.80
2.00
---
---
---
2.00
02/16/16
ni
ND
60.00
6.60
---
---
---
ND
08/09/16
ni
---
11.60
ND
---
---
---
02/13/17
ni
ND
9.5 J
ND
---
---
---
ND
08/22/17
ni
ND
ND
ND
---
---
---
ND
02/05/18
ni
ND
5.60
ND
---
---
---
ND
08/13/18
ni
ND
71.80
3.56
---
---
---
ND
02/04/19
ni
ND
7.50
ND
---
---
---
ND
08/06/19
ni
---
8.00
ND
---
---
---
---
02/12/20
ni
---
6.30
ND
---
---
---
---
08/27/20
ni
ND
9.45
ND
---
---
---
ND
02/11/21
ni
ND
9.87
ND
---
---
---
ND
08/19/21
ni
---
6.38
ND
---
---
---
02/16/22
ni
ND
8.00
ND
---
---
---
ND
09/28/221
ni
---
6.1 B3
<2.0
---
---
---
---
03/28/23
ni
ND
2.14 B2
ND
---
---
---
ND
Chemical Oxygen Demand (COD)
08/14/14
ni
ND
132.00
ND
---
---
---
50.00
03/10/15
ni
15.0 J
235.00
96.00
---
---
---
ND
08/18/15
ni
25.00
110.00
756.00
---
---
---
25.00
02/16/16
ni
ND
295.00
50.00
---
---
---
ND
08/09/16
ni
-
131.00
50.00
---
---
---
-
02/13/17
mg/L
17 J
119.00
43.00
---
---
---
22 J
08/22/17
mg/L
ND
121.00
74.00
---
---
---
16 J
02/05/18
ni
ND
113.00
51.00
---
---
---
46.00
08/13/18
ni
ND
112.00
73.90
---
---
---
ND
02/04/19
ni
ND
101.00
26.50
---
---
---
ND
08/06/19
ni
123.00
45.50
---
---
---
02/12/20
ni
160.00
36.10
---
---
---
08/27/20
ni
ND
112.00
35.90
---
---
---
ND
02/11/21
ni
ND
108.00
38.00
---
---
---
ND
08/19/21
ni
-
121.00
48.20
---
---
---
02/16/22
ni
ND
105.00
32.10
---
---
---
ND
09/28/221
ni
---
119.00
49.30
---
---
---
---
03/28/23
ni
ND
101.00
45.40
---
---
---
ND
Dissolved Ethane
12/30/03
ni
ND
ND
ND
---
---
---
---
12/19/07
ni
ND
ND
ND
NO
ND
NO
---
05/01/13
ni
ND
ND
ND
NO
---
---
ND
08/14/14
ni
ND
ND
0.0036 J
NO
---
---
ND
03/10/15
ni
ND
ND
ND
---
---
---
ND
08/18/15
ni
0.01
0.01
0.01
---
---
---
ND
02/16/16
ni
ND
ND
ND
---
---
---
0.01
08/09/16
mg/L
---
1.6 J
2.6 J
---
---
---
ND
02/13/17
ni
---
---
---
---
---
08/22/17
ni
---
---
---
---
---
02/05/18
ni
---
---
---
---
---
08/13/18
ni
---
---
---
---
---
02/04/19
ni
ND
ND
ND
ND
ND
ND
ND
08/06/19
ni
ND
2.0 J
---
---
---
---
ND
02/12/20
ni
ND
0.0026 J
---
---
---
---
ND
08/27/20
ni
ND
ND
---
---
---
---
ND
02/11/21
ni
---
---
---
---
---
---
---
08/19/21
ni
---
---
---
---
---
--
02/16/22
ni
---
---
---
---
---
09/28/22'
ni
---
---
---
---
---
---
03/28/23
ni
---
---
---
---
---
---
Dissolved Ethene
12/01/03
ni
ND
ND
ND
NO
ND
ND
---
12/19/07
ni
ND
ND
ND
NO
ND
---
ND
05/01/13
ni
ND
ND
0.0017
0.00
ND
---
ND
08/14/14
ni
ND
ND
ND
ND
---
---
ND
03/10/15
ni
ND
NO
ND
ND
---
---
ND
08/18/15
ni
0.01
0.01
0.01
0.01
---
---
0.01
02/16/16
ni
ND
ND
ND
ND
---
---
ND
08/09/16
ni
---
NO
ND
ND
---
---
---
02/13/17
ni
---
---
---
---
---
08/22/17
ni
---
---
---
---
---
02/05/18
ni
---
---
---
---
---
08/13/18
ni
---
---
---
---
---
---
02/04/19
ni
ND
ND
ND
ND
ND
ND
ND
08/06/19
ni
ND
ND
0.0016 J
.0016 J
---
---
ND
02/12/20
ni
ND
0.00
ND
ND
---
---
ND
08/27/20
ni
ND
ND
ND
ND
---
---
ND
02/11/21
ni
---
---
---
---
---
08/19/21
ni
---
---
---
---
02/16/22
ni
---
---
---
---
---
09/28/22'
ni
---
---
---
---
---
---
03/28/23
ni
I ---
I ---
I ---
I ---
I ---
I ---
Appendix F (Page 4 of �6+)
Mips//haahlck.sharepoinLcomisiles/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 -Granville Co. Butner LF/2023 First Hal( GWM/Tables/Butner Historic Tables Hart & Hickman, Pl.

Appendix F
Summary of Historical Monitored Natural Attenuation
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Parameter
Date
Units
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Dissolved Methane
12/30/03
mg/L
ND
0.66
0.13
0.01
0.00
ND
---
12/19/07
mg/L
ND
0.12
0.19
ND
---
---
ND
05/01/13
mg/L
ND
0.04
0.10
0.03
---
---
ND
08/14/14
mg/L
ND
1.29
0.28
---
---
---
ND
03/10/15
mg/L
0.01
1.00
0.16
---
---
---
ND
08/18/15
mg/L
0.00
2.16
0.32
---
---
---
0.00
02/16/16
mg/L
0.007 J
0.87
0.10
---
---
---
0.0016 J
08/09/16
mg/L
-
1.85
0.21
---
---
---
---
02/13/17
mg/L
---
---
---
---
---
08/22/17
mg/L
---
---
---
---
---
02/05/18
mg/L
---
---
---
---
---
08/13/18
mg/L
---
---
---
---
---
02/04/19
mg/L
ND
27.20
ND
ND
ND
ND
ND
08/06/19
mg/L
ND
5.00
0.49
---
---
---
ND
02/12/20
mg/L
ND
4.50
0.38
---
---
---
ND
08/27/20
mg/L
ND
6.00
0.50
---
---
---
ND
02/11/21
mg/L
ND
6.66
0.52
---
---
---
ND
08/19/21
mg/L
---
7.21
0.603
---
---
---
---
02/16/22
mg/L
ND
4.61
0.397
---
---
---
ND
09/28/221
ril
---
2.30
0.270
---
---
---
---
03/28/23
mg/L
ND
0.577
0.0962
---
---
---
ND
Pyruvic Acid
12/19/07
mg/L
2.50
ND
1.50
2.00
---
---
1.20
05/01/13
mg/L
ND
ND
ND
ND
---
---
ND
08/14/14
mg/L
ND
ND
ND
---
---
---
ND
03/10/15
mg/L
0.41 J
0.41 J
0.41 J
---
---
---
0.41 J
08/18/15
mg/L
ND
ND
ND
---
---
---
ND
02/16/16
mg/L
ND
ND
ND
---
---
---
ND
08/09/16
mg/L
---
ND
ND
---
---
---
---
02/13/17
mg/L
---
---
---
---
---
08/22/17
ril
---
---
---
---
---
02/05/18
ril
---
---
---
---
---
08/13/18
ril
---
---
---
---
---
02/04/19
ril
---
---
---
---
---
08/06/19
ril
ND
ND
ND
---
---
---
ND
02/12/20
ril
---
---
---
---
---
08/27/20
ril
ND
ND
ND
ND
02/11/21
ril
---
---
---
---
---
08/19/21
ril
---
---
---
---
02/16/22
ril
ND
ND
ND
---
---
---
ND
09/28/221
ril
---
---
---
---
---
---
03/28/23
mg/L
---
---
---
---
---
---
Lactic Acid
12/19/07
mg/L
ND
5.40
11.90
3.10
---
---
ND
05/01/13
mg/L
ND
ND
ND
ND
---
---
ND
08/14/14
ni
4.2 J
ND
ND
---
---
---
ND
03/10/15
ni
ND
ND
ND
---
---
---
ND
08/18/15
ni
ND
ND
ND
---
---
---
ND
02/16/16
ril
ND
ND
ND
---
---
---
ND
08/09/16
ril
---
ND
ND
---
---
---
---
02/13/17
ril
---
---
---
---
---
08/22/17
ril
---
---
---
---
---
02/05/18
ril
---
---
---
---
---
08/13/18
ril
---
---
---
---
---
02/04/19
ril
---
---
---
---
---
08/06/19
ril
ND
ND
0.087 J
---
---
---
ND
02/12/20
ril
---
---
---
---
---
08/27/20
ril
ND
ND
ND
---
---
---
ND
02/11/21
ril
---
---
---
---
---
08/19/21
mg/L
---
---
---
---
02/16/22
mg/L
230 J
ND
ND
---
---
---
ND
09/28/221
ril
---
---
---
---
---
---
03/28/23
mg/L
---
---
---
---
---
---
Acetic Acid
12/19/07
mg/L
ND
ND
ND
ND
---
---
ND
05/01/13
mg/L
ND
ND
ND
ND
---
---
ND
08/14/14
ril
ND
ND
ND
---
---
---
ND
03/10/15
ril
ND
ND
ND
---
---
---
ND
08/18/15
mg/L
ND
ND
0.97 J
---
---
---
ND
02/16/16
mg/L
ND
ND
ND
---
---
---
ND
08/09/16
ril
-
ND
ND
---
---
---
---
02/13/17
ril
---
---
---
08/22/17
ril
---
---
---
02/05/18
ril
---
---
---
08/13/18
ni
---
---
---
02/04/19
ni
---
---
---
08/06/19
ni
ND
0.097 J
0.34
---
---
---
ND
02/12/20
ril
---
---
---
08/27/20
ril
0.53
4.7 J
0.53
---
---
---
0.56
02/11/21
ni
---
---
---
08/19/21
ni
---
---
---
---
02/16/22
ni
ND
ND
ND
---
---
---
0.13
09/28/221
ril
---
---
---
---
---
---
03/28/23
mg/L
---
---
---
---
---
---
Propionic Acid
12/19/07
mg/L
ND
63.70
38.30
12.80
---
---
ND
05/01/13
mg/L
ND
ND
ND
ND
---
---
ND
08/14/14
ni
ND
ND
ND
---
---
---
ND
03/10/15
ni
ND
ND
ND
---
---
---
ND
08/18/15
ni
ND
ND
ND
---
---
---
ND
02/16/16
ril
ND
ND
ND
---
---
---
ND
08/09/16
ril
---
ND
ND
---
---
---
---
08/22/17
ril
---
---
---
02/13/17
ril
---
---
08/22/17
ril
---
---
---
02/05/18
ril
---
---
---
08/13/18
ril
---
---
---
02/04/19
ril
---
---
---
08/06/19
ril
---
0.0058 J
0.0045 J
---
---
---
---
02/12/20
ril
---
---
---
08/27/20
ril
ND
ND
ND
ND
02/11/21
ril
---
---
---
08/19/21
ril
---
---
02/16/22
ril
ND
ND
ND
---
---
---
ND
09/28/221
ril
---
---
---
---
---
---
03/28/23
mg/L
---
---
---
---
---
---
Appendix F (Page 5 of �6+)
https//haahlck.sharepoinLcomisiles/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 -Granville Co. Butner LF/2023 First Hal( GWM/Tables/Butner Historic Tables Hart & Hickman, Pl.

Appendix F
Summary of Historical Monitored Natural Attenuation
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Parameter
Date
Units
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Butyric Acid
12/19/07
mg/L
ND
ND
ND
ND
---
---
ND
05/01/13
mg/L
ND
ND
ND
ND
---
---
ND
08/14/14
mg/L
ND
ND
ND
---
---
---
ND
03/10/15
mg/L
ND
ND
ND
---
---
---
ND
08/18/15
mg/L
ND
ND
ND
---
---
---
ND
02/16/16
mg/L
ND
ND
ND
---
---
---
ND
08/09/16
mg/L
---
ND
ND
---
---
---
---
02/13/17
mg/L
---
---
---
08/22/17
mg/L
---
---
---
02/05/18
mg/L
---
---
---
---
08/13/18
mg/L
---
---
---
---
02/04/19
mg/L
---
---
---
---
08/06/19
mg/L
---
0.22
ND
---
---
---
---
02/12/20
mg/L
---
---
---
08/27/20
mg/L
ND
ND
0.066 J
---
---
---
ND
02/11/21
mg/L
---
---
---
08/19/21
mg/L
---
---
---
--
02/16/22
mg/L
ND
ND
ND
---
---
---
ND
09/28/22'
mg/L
---
---
---
---
---
---
03/28/23
mg/L
---
---
---
---
---
---
---
Formic Acid
08/06/19
mg/L
---
1.10
1.60
---
---
---
---
02/12/20
mg/L
---
---
---
---
---
---
---
08/27/20
mg/L
4.90
45.00
4.80
---
---
---
5.10
02/11/21
mg/L
---
---
---
---
---
---
---
08/19/21
mg/L
---
---
---
---
---
02/16/22
mg/L
1.2
42
9.2
---
---
---
4
09/28/22'
mg/L
---
---
---
---
---
---
03/28/23
mg/L
---
---
---
---
---
---
---
Total Volatile Fatty Acids (sum of above 6 acids)
12/19/07
mg/L
2.50
69.10
51.70
17.90
---
---
1.20
05/01/13
mg/L
ND
ND
ND
---
---
---
ND
08/14/14
mg/L
4.2 J
ND
ND
---
---
---
ND
03/10/15
mg/L
ND
ND
ND
---
---
---
ND
08/18/15
mg/L
ND
ND
0.97 J
---
---
---
ND
02/16/16
mg/L
ND
ND
ND
---
---
---
ND
08/09/16
mg/L
---
ND
ND
---
---
02/13/17
mg/L
---
---
---
---
---
---
---
08/22/17
mg/L
---
---
---
---
---
---
---
02/05/18
mg/L
---
---
---
---
---
---
---
08/13/18
mg/L
---
---
---
---
---
---
---
02/04/19
mg/L
---
---
---
---
---
---
---
08/06/19
mg/L
---
1.32
1.94
---
---
02/12/20
mg/L
---
---
---
---
---
---
---
08/27/20
mg/L
5.43
49.70
5.40
---
---
---
5.66
02/11/21
mg/L
---
---
---
---
---
---
---
08/19/21
mg/L
---
---
---
---
---
---
02/16/22
mg/L
231.20
42.00
9.20
---
---
---
4.13
09/28/22'
mg/L
---
---
---
---
---
---
03/28/23
mg/L
---
I ---
I ---
I ---
I ---
I ---
Notes:
Analytical results from December 2003 through February 2021 obtained from La Bella Associates Water Quality Monitoring Report - February 2021 Event
Analytical results from August 2021 obtained from Garrett & Moore, Inc. Water Quality Monitoring Report - August 2021 Event
Method detection limits vary between samples for fatty acid analysis, the higher method detection limit reported for each constituent for samples collected it
February 2022 is shown.
1. September 2022 MW-1R sample collected on 09/29/2022.
mg/L = milligrams per liter; nanometers; --- = Not Sampled and/or Not Reported; ND = Not Detected; MDL = method detection limit;
MRL = method reporting limit; J = Estimated concentration above the adjusted method detection limit and below the adjusted
method reporting limit; S.U. = standard units; °C = degrees Celsius; µS/cm = microsiemens per centimeter; mV = millivolts
133 = The dissolved oxygen depletion of the dilution water blank exceeded 0.2 mg/L
Appendix F (Page 6 of /6+)
https://harthick.shampoint.w WsitesIMasterFiles-l/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2023 First HaH GWM/Tables/Butner Historic Tables Hart & Hickman, Pl.

Appendix G
Concentration vs. Time Charts
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

Chart 1
Benzene Concentrations vs. Time
M W-2 R, M W-3 R, & M W-4
2.5
2.0
F� A
ova 1.5
o MW-2R
c�
+, M W- R
c
u MW-4
u° 1 0 2L Standard (1 µg/L)
0.5
0.0
10/10/06 9/9/08 8/10/10 7/10/12 6/10/14 5/10/16 4/10/18 3/10/20 2/8/22 1/9/24
Note: Non -detect values are graphed equal to the method detection limit. Date

Chart 2
1,4-Dioxane Concentrations vs. Time
MW-2R, MW-3R, MW-4, & MW-5
140.0
Wz1x111
100.0
J
bA
=- 80.0
40.0
20.0
0.0 11
7/19/18 2/4/19 8/23/19 3/10/20 9/26/20
Note: Non -detect values are graphed equal to the method detection limit. Date
4/14/21 10/31/21 5/19/22 12/5/22 6/23/23
MW-2R
MW-3R
MW-4
MW-5
2L Standard (3 µg/L)

Chart 3
Cobalt Concentrations vs. Tlme
MW-2R & MW-5
300
250
200
J
C
0
150 MW-2R
c
v
U
0 2L Standard (1 µg/L)
u
100
50
0
6/15/94 9/27/97 1/9/01 4/23/04 8/6/07 11/18/10 3/2/14 6/14/17 9/26/20 1/9/24
Note: Non -detect values are graphed equal to the method detection limit. Date