1119_DukeAsheville_Q12023_WQMR_FID1810688_20230712

(� DUKE
ENERGY
July 12, 2023
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
2090 U.S. Highway 70
Swannanoa, NC 28778
Attn: Ms. Sarah Moutos (submitted electronically)
Re: Semiannual Water Quality Monitoring Report — March 2023
CCR Landfill
Permit No. 1119-INDUS-2020
Asheville Steam Electric Plant
Buncombe County, North Carolina
Dear Ms. Moutos:
526 South Church St.
Charlotte, NC 28202
Mailing Address
P.O. Box 1006
Mail Code EC 13K.
Charlotte, NC 28201-1006
Duke Energy is providing the results of the March 2023 semiannual water quality monitoring for the Duke
Energy Progress Asheville CCR Landfill (1119-INDUS), located in Arden, Buncombe County, North Carolina.
Sampling was conducted on March 20, 2023, in accordance with the approved Water Quality Monitoring Plan
(WQMP). The March 2023 monitoring event included samples from nine groundwater monitoring wells, three
surface water locations, and one sample of composite leachate. One seep location is designated in the WQMP,
however seep sample DP-4 were not sampled during the March 2023 sampling event because of dry
conditions.
The groundwater analytical results are compared to the groundwater standards found in Title 15A NCAC 02L
.0202 (02L Standards). The surface water and seep analytical results are compared to the surface water
standards found in Title 15A NCAC 02B .0211 (02B Standard) for Class C waters. Leachate analytical results
are not compared to groundwater or surface water quality standards.
Duke Energy personnel sample designated locations for groundwater, surface water, and leachate at the
Asheville CCR Landfill semiannually during March and September. The next water quality monitoring event for
the CCR Landfill is planned for September 2023 with a report of monitoring results to follow.
If you have any questions or concerns with this submittal, please do not hesitate to contact me at
Ashley. Healy6a)duke-energv.com or [phone].
Respectfully submitted,
j4VAi
Ashley Healy, P.G.
Environmental Services
Attachments: Semiannual Water Quality Monitoring Report — March 2023 Sampling Event; SynTerra, July 2023
cc (via e-mail): Claire Osborn, NCDEQ
www.duke-energy.com Page 1 of 2

Elizabeth Werner, NCDEQ
Sherri Stanley, NCDEQ
Ed Mussler, NCDEQ
Joe Wilson, Duke Energy
John Toepfer, Duke Energy
Connor Zahora, Duke Energy
Teresa Williams, Duke Energy
Tyler Hardin, Duke Energy
Kelly Ferri, SynTerra
Craig Eady, SynTerra
www.duke-energy.com Page 2 of 2

DENR USE ONLY ❑Paper Report [-]Electronic Data - Email CD (data loaded: Yes / No) Doc/Event #:
NC DENR I I Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
• Prepare one form for each individually monitored unit.
• Please type or print legibly.
• Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
• Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
• Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
• Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
SynTerra Corporation (Consultant)
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Kelly Ferri Phone: [phone]
E-mail: kferri(cDsvnterracorp.com
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit# (.0500 or.1600) October 20-24, 2006)
Duke Energy Progress 46 Duke Energy Lane 11119-INDUS-2020 1.0500 March 20, 2023
Asheville Steam Electric Plant Arden, NC 28704
CCR Landfill
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ❑X Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑
Leachate monitoring data
Surface water monitoring data ❑
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Craig D. Eady Project Manager [phone]
Facility Representative Name (Print) Title (Area Code) Telephone Number
7/7/2023
Signature Date
148 River Street, Suite 220, Greenville, SC 29601
Facility Representative Address
C-1478 / North Carolina Geological Corporation Number C-387
Affix NC Licensed/ Professional Geologist Seal
4�I I�f + t f}
`h R()'ff r
\ +•• S •tj I'
+ SEAL
•:COL pCa,�;+'ice:
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009

REPORT VERIFICATION
PROJECT: SEMIANNUAL WATER QUALITY MONITORING REPORT
MARCH 2O23 SAMPLING EVENT
ASHEVILLE STEAM ELECTRIC PLANT
CCR LANDFILL
PERMIT NO. 1119-INDUS-2020
TITLE: MARCH 2O23 SAMPLING EVENT
This document has been reviewed for accuracy and quality commensurate with the intended
application.
Prepared by: Date
Approved by: Date
Project Manager: Craig Eady, PLG
7/7/2023
7/7/2023
Licensed Geologist Seal:
IIIIIojfj
.� Q.•. �N I r
SEAL
X � • '��� Cap .*'
SynTerra
148 River Street, Suite 220
Greenville, SC 29601
North Carolina Geological Corporation Number C-387

17
Terra Science &Engineering Consultants
synsynterracorp.com
SEMIANNUAL
WATER QUALITY MONITORING REPORT
MARCH 2O23 SAMPLING EVENT
CCR LANDFILL
PERMIT NO. 1119-INDUS-2020)
ASHEVILLE STEAM ELECTRIC PLANT
46 DUKE ENERGY LANE
ARDEN, NORTH CAROLINA 28704
JULY 7, 2023
PREPARED FOR
DUKE
ENERGY:
PROGRES'
DUKE ENERGY PROGRESS, LLC
Craig D Eacly, NC 1.(. #1599 Ryan Badum
Senior Peer eviewer Project Scientist
s
!' Kelly Ferri
Project Manager

Semiannual Water Quality Monitoring Report — March 2023 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
TABLE OF CONTENTS
SECTION PAGE
1.0 INTRODUCTION AND BACKGROUND..........................................................................1-1
1.1 Site and Landfill Information......................................................................................1-1
1.2 Hydrogeologic Setting................................................................................................1-1
1.3 Landfill Semiannual Monitoring Program...................................................................1-2
2.0 METHODS.................................................................................................................. 2-1
2.1 Sampling and Analysis Methods.................................................................................2-1
2.2 Regulatory Criteria.....................................................................................................2-1
2.3 Statement of Work.....................................................................................................2-1
3.0 RESULTS.....................................................................................................................3-1
3.1 Site Groundwater Flow...............................................................................................3-1
3.2 Historical Range Data.................................................................................................3-1
3.3 Analytical Results.......................................................................................................3-2
3.4 Quality Assurance/Quality Control.............................................................................3-2
4.0 REFERENCES...............................................................................................................4-1
LIST OF FIGURES
Figure 1 Site Location Map
Figure 2 Sample Locations
Figure 3A Groundwater Level Map — Surficial and Transition Flow Zones
Figure 3B Groundwater Level Map — Bedrock Flow Zone
LIST OF TABLES
Table 1 Well Construction Summary
Table 2 Groundwater, Surface Water, and Leachate Monitoring Parameters
Table 3 Field Data Parameters
Table 4 Groundwater Seepage Velocities
Table 5 Groundwater Field Results and Analytical Detections
Table 6 Field and Analytical Results that Equal or Exceed Groundwater Quality Standards
Table 7 Surface Water Field Results and Analytical Detections
Table 8 Leachate Field Results and Analytical Detections
LIST OF APPENDICES
Appendix A Field Sampling Forms
Appendix B Laboratory Report and Chain -of -Custody Forms
July 2023 Page i
Project: 00.0069.34.07.02

Semiannual Water Quality Monitoring Report — March 2023 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
LIST OF ACRONYMS
02L
Title 15A, NCAC 02L .0202(g) Groundwater Quality Standards
02B
Title 15A, NCAC 02B .0200 Surface Water and Wetland standards
Asheville Plant
Asheville Steam Electric Plant
CAMA
Coal Ash Management Act
CCR
coal combustion residuals
Duke Energy
Duke Energy Progress, LLC
DWM
Division of Waste Management
EDD
electronic data deliverable
Landfill
Asheville CCR Landfill
MSE
mechanically stabilized earth
NCAC
North Carolina Administrative Code
NCDEQ
North Carolina Department of Environmental Quality
Site
Asheville Steam Electric Plant
SWLF
Solid Waste Landfill
SWS
Solid Waste Section
TDS
total dissolved solids
USEPA
U.S. Environmental Protection Agency
WQMP
Water Quality Monitoring Plan
July 2023 Page H
Project: 00.0069.34.07.02

Semiannual Water Quality Monitoring Report — March 2023 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
f��>• I ►19.1611111I4111 9 IQ ► I_10 1113Uffel KC11:191110 L7
This semiannual report pertains to the Duke Energy Progress, LLC (Duke Energy) Asheville
Steam Electric Plant (Asheville Plant, Site) Coal Combustion Residual (CCR) Landfill (Landfill;
Permit No. 1119-INDUS-2020) and documents the results of the March 2023 groundwater,
surface water, seep, and leachate monitoring event.
Monitoring results show that groundwater constituents greater than comparison criteria are
attributable to natural variation and not the CCR Landfill, except sulfate concentrations in one
monitoring well (LMW-3B). Additional monitoring and data are needed to determine the cause
and significance of the sulfate concentration greater than historical background concentrations.
1.1 Site and Landfill Information
Duke Energy owns and operates the Asheville Steam Electric Plant, located on approximately
786 acres, addressed at 46 Duke Energy Lane in Arden, Buncombe County, North Carolina.
(Figure 1).
The Asheville Plant began operations in 1964 with construction of two coal-fired power -
generating units to generate electricity. Throughout the period of coal-fired generation, CCR
was managed and stored on -Site in the 1964 and 1982 Ash Basins. The Asheville Plant ceased
burning coal in January 2020, and the coal-fired units were replaced with a natural gas
combined cycle station for electricity generation; thus, the facility no longer generates CCR.
Excavation of the 1982 Ash Basin was completed in September 2016, and excavation of the
1964 Ash Basin was completed in June 2022.
Development and construction activities for the on -Site double lined CCR Landfill began in
February 2020 and were completed in March 2021. The CCR Landfill was constructed in an area
previously developed as a laydown yard, located north of and adjacent to the 1964 Ash Basin
(Figure 1). The CCR Landfill was constructed to support the last phase of ash excavation from
the 1964 Ash Basin. The Landfill received a Permit Approval to Operate from the North Carolina
Department of Environmental Quality (NCDEQ) on April 1, 2021, and initial placement of CCR
material in the Landfill occurred on the same day. The Landfill Operations Plan (Geosyntec,
2021) and Landfill Permit outline a variety of landfill -approved wastes; however, the primary
waste disposed of in the Landfill is CCR (fly ash and bottom ash). Landfill closure was initiated in
September 2022 and closure was completed in April 2023.
1.2 Hydrogeologic Setting
The Asheville Plant is located within the Blue Ridge physiographic province, where soil overlying
the bedrock has formed from the in -place weathering of bedrock. Groundwater at the Site
typically occurs in three interconnected flow zones. The shallowest groundwater flow zone —
the surficial flow zone — occurs in the residual soil and/or the upper section of saprolite.
Beneath the surficial flow zone, the transition zone flow zone occurs in the lower portions of
the saprolite and partially weathered bedrock and is the most permeable part of the Site
July 2023 Page 1-1
Project: 00.0069.34.07.02

Semiannual Water Quality Monitoring Report — March 2023 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
hydrogeologic system. Bedrock underlies the transition zone and comprises the least
permeable flow zone of the Site's hydrogeologic system, where groundwater flow occurs
predominantly along fractures, joints, and faults. Groundwater is usually encountered in the
surficial flow zone; however, as the hydrogeologic units above the bedrock thins to the west
and northwest, groundwater is encountered only within the lower hydrogeologic unit(s).
Groundwater flow direction at the Landfill is generally to the west toward an unnamed stream,
and to the northwest toward a wetland area and several unnamed streams, which converge
into Powell Creek. The wetland area and streams act as groundwater discharge zones
downgradient of the Landfill. Those surface waters are classified as Class C under Title 15A of
the North Carolina Administrative Code (NCAC), Subchapter 02B, Surface Water and Standards
(02B standards). Flow from those surface water features eventually reaches the French Broad
River, located to the west.
1.3 Landfill Semiannual Monitoring Program
The Water Quality Monitoring Plan (WQMP), Revision 2 (Geosyntec, 2019) for the CCR Landfill
was submitted to NCDEQ on October 31, 2019, and approved on February 7, 2020. A WQMP
Revision 3 is anticipated to be submitted in Q3 2023.
The Landfill semiannual monitoring program, described in detail in the WQMP, consists of 9
groundwater, 3 surface water, 1 seep, and 1 leachate monitoring locations and are summarized
below. The monitoring locations are shown on Figure 2. A summary of monitoring well
construction information is presented in Table 1 and analytical parameters for the Landfill
semiannual groundwater monitoring program is summarized in Table 2.
July 2023 Page 1-2
Project: 00.0069.34.07.02

Semiannual Water Quality Monitoring Report — March 2023 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
MONITORING WELLS
MEDIA
COMMENTS
OR SAMPLE LOCATIONS
Background
CB-9, CB-9SL, CB-9BR
Groundwater
LMW-1S, LMW-1B
See Table 1 Well Construction
Summary for monitoring well
LMW-2T, LMW-2B,
construction information.
Downgradient Groundwater
LWM-313, LMW-4B
Three surface water monitoring
locations in two streams located west
and north-northwest, adjacent, and
LF-SW-1, LF-SW-2, LF-SW-3
downgradient of the Landfill (sampled
if flow is present during semiannual
monitoring).
Surface Water
Drainpipe for groundwater seepage
from the northwest portion of the
DP-4
Landfill's mechanically stabilized earth
(MSE) berm (sampled if flow is present
during semiannual monitoring).
Leachate sample, representing
leachate from the entire Landfill, is
Leachate
LCS-1
collected from an in -line sampling
point along the forcemain conveying
leachate from the Landfill to the
Leachate Storage Tank.
Notes:
1. The WQMP identifies the surface water samples as SW-1, SW-2, and SW-3. Identification was revised to differentiate between other Site
monitoring program surface water locations.
The WQMP identifies the leachate collection sample as L-1. Identification was revised in the field during sample collection.
Two additional groundwater monitoring wells (LMW-IT and LMW-2S) were included as proposed monitoring wells in the WQMP but were
not installed. Monitoring well LMW-1T was proposed to be screened in the transition zone; however, no transition zone was observed
during drilling. Monitoring well LMW-2S was not installed because the surficial aquifer was not present at the proposed location.
July 2023 Page 1-3
Project: 00.0069.34.07.02

Semiannual Water Quality Monitoring Report — March 2023 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
2.0 METHODS
2.1 Sampling and Analysis Methods
Groundwater, surface water, seep, and leachate sampling was conducted by Duke Energy
personnel (Duke Energy North Carolina Field Certification #5193) on March 20, 2023, in
accordance with the North Carolina Solid Waste Management Guidelines. Copies of the field
sampling forms are included in Appendix A. Duke Energy Analytical Laboratory (North Carolina
Laboratory Certification #248) and Pace Analytical Laboratory (North Carolina Laboratory
Certification #40) analyzed the reported parameters and constituents. The laboratory report
and chain -of -custody forms are included in Appendix B.
Duke Energy developed a list of parameters and constituents using guidance from the NCDEQ
Division of Waste Management (DWM), Solid Waste Section (SWS). The samples were analyzed
using the updated parameter and constituent list, approved by NCDEQ on March 20, 2023. The
monitoring parameters, along with the U.S. Environmental Protection Agency (USEPA) Solid
Waste (SW)-846 analytical methods, Title 15A, NCAC, Subchapter 02L .0202(g), Groundwater
Quality Standards (02L standards), and 15A NCAC 02B .0200 Surface Water and Wetland
standards (0213 standards) for Class C waters are present in Table 2.
2.2 Regulatory Criteria
Evaluation of the semiannual monitoring analytical results are compared to the following
regulatory criteria:
Groundwater
• 02L standards
Surface Water/Seep
• 02B standards
2.3 Statement of Work
The following tasks were completed for semiannual water quality monitoring:
• Groundwater, surface water, and leachate were collected on March 20, 2023. (Duke
personnel completed this task.)
• Compared groundwater analytical results to 02L standards and historical concentration
ranges.
• Compared surface water analytical results to 02B standards and historical concentration
ranges.
• Developed generalized groundwater contour maps using groundwater elevation data
collected during the March 2023 groundwater monitoring event.
2023 Page 2-1
Project: 00.0069.34.07.02

Semiannual Water Quality Monitoring Report — March 2023 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
• Calculated groundwater flow velocities based on groundwater elevations at wells
perpendicular to groundwater flow.
• Converted the laboratory provided electronic data deliverable (EDD) to the format
requirements of the NCDEQ DWM EDD template and submitted copies of the EDDs to
the NCDEQ DWM with this report.
• Prepared and submitted this Semiannual Water Quality Monitoring Report.
July 2023 Page 2-2
Project: 00.0069.34.07.02

Semiannual Water Quality Monitoring Report — March 2023 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
3.1 Site Groundwater Flow
Groundwater flow in the aquifer beneath the Landfill footprint flows generally to the west
toward an unnamed stream, and to the northwest toward a wetland area and several unnamed
streams, which converge into Powell Creek.
Generalized groundwater elevation contours and groundwater flow direction arrows in the
vicinity of the CCR Landfill are shown on Figure 3A for the surficial and transition flow zones,
and Figure 313 for the bedrock flow zone. These contours were developed by calculating
groundwater elevations in each monitoring well using the depth -to -water -level measurements
taken during the March 2023 monitoring event. In addition, water -level measurements from
nearby groundwater monitoring wells included in other Site groundwater monitoring programs
were used. Depth -to -water measurements and calculated groundwater elevations are
presented in Table 3. Calculated groundwater flow velocities are presented in Table 4.
Calculated groundwater elevations based on depth -to -water measurements gauged during the
March 2023 monitoring event indicate groundwater at the Landfill generally flows to the west
and northwest, consistent with historical Site observations.
3.2 Historical Range Data
Newly Installed Landfill Groundwater Monitoring Wells
The WQMP included collecting four groundwater samples from each new Landfill monitoring
well prior to the Landfill becoming operational (baseline samples). The four baseline monitoring
events occurred between September 2020 and January 2021, with samples collected from each
well approximately once every 30 days. The baseline monitoring included measuring
groundwater field parameters, gauging depth -to -water in the wells, and analysis of the
collected groundwater samples for the list of parameters and constituents outlined in the
WQMP (same parameter list sampled and analyzed for in the Landfill semiannual monitoring
program). The results of the four baseline sampling events were submitted in the Groundwater
Monitoring Report Baseline Sampling Events #1 Through #4 — CCR Landfill (Baseline Report)
(SynTerra, 2021). For each newly installed monitoring well, historical ranges of constituent
concentrations were calculated using the analytical results from the four baseline monitoring
events.
Existing Wells Incorporated into the Landfill Monitoring Program
Monitoring wells CB-9, CP-9SL, and CP-9BR existed at the Site prior to Landfill development but
are incorporated into the Landfill monitoring program. Those three wells were not sampled
during baseline sampling events for the newly installed wells. Rather, data from these wells,
collected as part of other regulatory sampling programs well in advance of Landfill operations,
were used to satisfy the initial baseline sampling requirements. Historical concentration ranges
July 2023 Page 3-1
Project: 00.0069.34.07.02

Semiannual Water Quality Monitoring Report — March 2023 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
for existing wells were established using all available data collected prior to initiation of Landfill
operations (November 2012 to January 2021).
3.3 Analytical Results
A summary of the groundwater, surface water, and leachate field data is presented in Table 3.
The analytical results and reference comparisons discussed below are summarized in Tables 5
through 8. Sample locations are depicted on Figure 2.
Groundwater Results
Field and analytical results for the collected downgradient and background groundwater
samples are presented in Table 5. Groundwater analytical results are compared with 02L
standards. Constituent concentrations equal to or greater than their 02L standard are noted in
Table 5 in bold font. The laboratory analytical reports are included as Appendix B.
A summary of the downgradient groundwater field and analytical results that are equal to or
greater than applicable comparison criteria are presented in Table 6.
The groundwater concentrations in Table 6, which are identified as being equal to or greater
than the 02L standard (or less than for pH), are attributable to natural variation, except for
sulfate in LMW-3B, which is only slightly greater than the 02L standard and greater than
historical background concentrations. Further investigation is pending to determine the cause
and significance of the sulfate concentration in LMW-3B.
Surface Water
Field and analytical results for surface water samples are presented in Table 7. The sample
locations are shown on Figure 2. Analytical results for surface water and seep samples, as
available, are compared with applicable 02B Class C surface water standards. Seep location DP-
4 was not sampled during the March 2023 sampling event because of dry conditions. No
surface water samples collected during the March 2023 sampling event were greater than or
equal to applicable 02B Class C surface water standards.
Leachate
A leachate sample (LCS-1) was collected from the leachate collection discharge pipe on the
west side of the Landfill. Analytical results are presented in Table 8. Leachate analytical results
are not compared to groundwater (02L standards) or surface water (0213 standards) quality
standards and are provided for informational purposes only.
3.4 Quality Assurance/Quality Control
Field -performed quality assurance and quality control (QA/QC) consisted of the collection and
analysis of two field blanks (one on each day of sampling) to evaluate if possible impacts were
imparted to the samples by the sample container, preservative, or other exogenous sources. A
field duplicate sample was also collected to estimate sampling and laboratory precision. Iron
July 2023 Page 3-2
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Semiannual Water Quality Monitoring Report — March 2023 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
was detected in the field blank at a concentration greater than the method detection limit.
However, all data were validated and deemed usable.
Select samples were diluted, as is normal laboratory practice, to bring samples within the
calibrated range of the analysis. Specifics regarding the samples that were diluted, including the
dilution amount, are reported in the lab report. Additional QA/QC data, laboratory analyses,
and chain -of -custody forms are included in Appendix B.
July 2023 Page 3-3
Project: 00.0069.34.07.02

Semiannual Water Quality Monitoring Report — March 2023 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
Geosyntec. (2019). Water Quality Monitoring Plan Revision Z Asheville Steam Electric Plant CCR
Landfill, October 2019.
Geosyntec. (2021). Operations Plan, Asheville Steam Electric Plant, CCR Landfill (1119-INDUS)
Rev. Z February 19, 2021.
SynTerra. (2021). Groundwater Monitoring Report Baseline Sampling Events #1 Through #4 —
CCR Landfill, Asheville Steam Electric Plant. April 2021.
July 2023 Page 4-1
Project: 00.0069.34.07.02

Semiannual Water Quality Monitoring Report — March 2023 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
FIGURES
L7
synTerra
Science & Engineering Consultants

ICCR LANDFILL]—
•
1964 ASH BASIN
WASTE BOUNDARY7—
T
L r
j-'i
0
tj
♦ Ll
r = RETIRED ASHEVILLE
STEAM ELECTRIC
L
_J1982 ASH BASIN
WASTE BOUNDARY
V/4DUKE ENERGY PROGRESS�
ROPERTY BOUNDARY
ASHEVILLE COMBINED
CYCLE STATION
Asheville
NOTES:
1. ALL BOUNDARIES ARE APPROXIMATE.
2. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS.
3. USGS TOPOGRAPHIC MAP OBTAINED FROM ESRI ONLINE,
LAST UPDATED AUGUST 2021.
FIGURE 1
DUKE
SITE LOCATION MAP
ENERGY
NCOMBE
BUCOUNTY
SEMIANNUAL WATER QUALITY MONITORING REPORT
MARCH 2023 SAMPLING EVENT
PROGRESS
ASHEVILLE STEAM ELECTRIC PLANT
ASHEVILLE
CHARLOTTE
ARDEN, NORTH CAROLINA
DRAWN BY: B. MCGANN
DATE: 11/10/2022
REVISED BY E ORDEMANN
DATE 06/06/2C�23
GRAPHIC SCALE
GRA LIM 2.—
CHECKED
ECKE. .1. Il. FERRI
DATE C11012C 23
synTerra
APPROVED BY. K. FERRI
DATE: 06/06/2023
(IN FEET)
www-s7nterracorp-com
PROJECT MANAGER K FERRI

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■
GROUNDWATER FLOW DIRECTION
/ INFERRED WATER ELEVATION CONTOUR (20' INTERVAL)
WASTE BOUNDARY t
LANDFILL LIMIT OF WASTE
0000 / / I 1 LANDFILL REVIEW BOUNDARY
/ I 1 LANDFILL REVIEW BOUNDARY — - — LANDFILL COMPLIANCE BOUNDARY
i v (APPROXIMATELY 80LEACHATE FORCEMAIN
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m ) DUKE ENERGY PROPERTY BOUNDARY
♦ � � � I STREAM TWT
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♦, �oB _ / I / TOPOGRAPHIC CONTOUR (10' INTERVAL)
LANDFILL COMPLIANCE NOTES:
{ U BOUNDARY 1.' - MONITORING WELL PART OF ANOTHER REGULATORY SAMPLE PROGRAM AND USED
2180
(APPROXIMATELY 160'
FOR GROUNDWATER ELEVATION DATA ONLY.
/ _ `/
ICB-9SL CB-9 FROM WASTE 2. W.E. - WATER ELEVATION (APPROXIMATE).
2170 , 2144.82 214448 ;BOUNDARY) 3. ALL SAMPLE LOCATIONS ARE APPROXIMATE.
- _�,� ♦
2160)(_ , ' ♦ r .4� - 4. THE DEPICTED STREAMS AND WETLANDS DATA WERE APPROVED BY THE US ARMY
CORPS OF ENGINEERS (USAGE) ON MAY 19, 2016 -JURISDICTIONAL DETERMINATION SAW
%♦ 2014-00189. TAYLOR WISEMAN AND TAYLOR (TWT) PERFORMED THE SURVEY OF THE
FEATURES.
♦ •
5. ALL BOUNDARIES ARE APPROXIMATE.
l 2140 ,♦s' '+ - t
LEACHATE "'
• MW-13D* _ _
_ 6. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS.
y , _ . ` 2124-24 _ _ �'
COLLECTION'`S h ♦, 7. AERIAL IMAGERY IS A COMBINATION OF DUKE ENERGY PROPELLERAERIAL
+ I.���� ♦i' I -- PHOTOGRAPHY COLLECTED ON MARCH 272023 AND AERIAL PHOTOGRAPHY OBTAINED
TANK ,� �� `—� - ♦ I - -� FROM ESRI COLLECTED ON JUNE 1, 2020
~ ; - - '2:60..�—Z1 I i ♦ ';-: •y ` .• 8. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE
�� �i.■ �.. �, i� �'�; . __ COORDINATE SYSTEM RIPS 3200 (NAD83).
r:
'+ 9. GROUNDWATER ELEVATIONS BASED ON WATER LEVELS COLLECTED MARCH 20, 2023.
5 �
'"`"=.'(- �,�, _ rv' "•'�•.• �' 10. THE WOMP IDENTIFIES THE SURFACE WATER SAMPLES AS SW-1, SW-2, AND SW-3.
IDENTIFICATION WAS REVISED TO DIFFERENTIATE BETWEEN OTHER SITE MONITORING
PROGRAM SURFACE WATER LOCATIONS. THE WQMP IDENTIFIES THE LEACHATE
COLLECTION SAMPLE AS L-1. IDENTIFICATION WAS REVISED IN THE FIELD DURING SAMPLE
COLLECTION.
(' DUKE 75 GROAPHIC(IN FEET)
SCALE
DUKE150 FIGURE 3A
ENERGY GROUNDWATER LEVEL MAP
(
PROGRESS SURFICIAL AND TRANSITION FLOW ZONES
a DRAWN Br. B.MCGANN DATE-12/08/2021 SEMIANNUAL WATER QUALITY MONITORING REPORT
REVISED` CHECKED
E.FERRI NN DATE_06/06/2023 MARCH 2023 SAMPLING EVENT
CB-$* Y �� CHECKED BY: K. FERRI DATE: 06/06/2023
2092.13 ilv APPROVED BY K. FERRI DATE 06/06/2023
' PROJECT MANAGER K ERDt.com lASHEVILLE STEAM ELECTRIC PLANT
smTerra Yerracor p ARDEN, NORTH CAROLINA

/,
LMW-4B Za2o �.
2079.87
N
S
-
10,
LEACHATE
:TION
TANK
0
♦
♦I
LMW-2B
2056.39
G
i
26
/ LMW-1B ♦
2146.64 zjso.
/ 1
WASTE BOUNDARY(
/ 1
00 \ LANDFILL REVIEW BOUNDAR
(APPROXIMATELY 80'
' 1 FROM WASTE BOUNDARY)
I
LANDFILL COMPLIANCE
. BOUNDARY
(APPROXIMATELY 160'
2d80 -
za�o
CB-9BR i FROM WASTE
2129.56 ♦ BOUNDARY)
? o MW-13BR` +, Y ♦�
\ _ 2124.4610
u. .
LEGEND
SURFACE WATER SAMPLE LOCATION
LEACHATE SAMPLE LOCATION
0 DRAINPIPE SAMPLE LOCATION
Ie DECTECTION MONITORING WELL
BACKGROUND MONITORING WELL
GROUNDWATER FLOW DIRECTION
-- INFERRED WATER ELEVATION CONTOUR (20' INTERVAL)
LANDFILL LIMIT OF WASTE
LANDFILL REVIEW BOUNDARY
Y — - — LANDFILL COMPLIANCE BOUNDARY
LEACHATE FORCEMAIN
DUKE ENERGY PROPERTY BOUNDARY
STREAM (TWT)
® WETLANDS (TWT)
TOPOGRAPHIC CONTOUR (10' INTERVAL)
NOTES:
1. * - MONITORING WELL PART OF ANOTHER REGULATORY SAMPLE PROGRAM AND USED
FOR GROUNDWATER ELEVATION DATA ONLY.
2. W.E. - WATER ELEVATION (APPROXIMATE).
3. ALL SAMPLE LOCATIONS ARE APPROXIMATE.
4. THE DEPICTED STREAMS AND WETLANDS DATA WERE APPROVED BY THE US ARMY
CORPS OF ENGINEERS (USAGE) ON MAY 19, 2016 - JURISDICTIONAL DETERMINATION SAW
2014-00189. TAYLOR WISEMAN AND TAYLOR (TWT) PERFORMED THE SURVEY OF THE
FEATURES.
5. ALL BOUNDARIES ARE APPROXIMATE
` 6. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS.
7. AERIAL IMAGERY IS A COMBINATION OF DUKE ENERGY PROPELLERAERIAL
PHOTOGRAPHY COLLECTED ON MARCH 27 2023 AND AERIAL PHOTOGRAPHY OBTAINED
FROM ESRI COLLECTED ON JUNE 1, 2020
8. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE
COORDINATE SYSTEM RIPS 3200 (NAD83).
9. GROUNDWATER ELEVATIONS BASED ON WATER LEVELS COLLECTED MARCH 20, 2023.
GRAPHIC SCALE
I (' DUKE
75 0 75 150
ENERGY
(IN FEET)
PROGRESS
-.
_r
•
�}
��
synTerm
DRAWN BY: B. MCGANN DATE_12/08/2021
REVISED BY E NN DATE_ 06/06/2023
CHECKED BY: K.. FERRI FERRI DATE: 06/06/2023
APPROVED BY. K. FERRI DATE 06/06/2023
PROJECT MANAGER: K-FERRI
www.synterracorp.com
10. THE WQMP IDENTIFIES THE SURFACE WATER SAMPLES AS SW-1, SW-2, AND SW-3.
IDENTIFICATION WAS REVISED TO DIFFERENTIATE BETWEEN OTHER SITE MONITORING
PROGRAM SURFACE WATER LOCATIONS. THE WQMP IDENTIFIES THE LEACHATE
COLLECTION SAMPLE AS L-1. IDENTIFICATION WAS REVISED IN THE FIELD DURING SAMPLE
COLLECTION.
FIGURE 3B
GROUNDWATER LEVEL MAP
BEDROCK FLOW ZONE
SEMIANNUAL WATER QUALITY MONITORING REPORT
MARCH 2O23 SAMPLING EVENT
ASHEVILLE STEAM ELECTRIC PLANT
ARDEN, NORTH CAROLINA

Semiannual Water Quality Monitoring Report — March 2023 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
TABLES
L7
synTerra
Science & Engineering Consultants

TABLE 1
WELL CONSTRUCTION SUMMARY
SEMIANNUAL WATER QUALITY MONITORING REPORT
MARCH 2O23 SAMPLING EVENT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Well ID
Date
Installed
Flow Zone
Material
Diameter
(Inches)
Latitude
(degrees)
Longitude
(degrees)
Well Depth
(Ft, BTOC)
Screened
Interval
(Ft, BGS)
Measuring Point TOC
(Ft, NAVD 88)
Ground Surface
(Ft, NAVD 88)
Groundwater
Elevation
(Ft NAVD 88)
Depth to Water
(Ft BTOQ
CB-9*
10/8/2012
Surficial
PVC
2
35.4720450
-82.5467520
65.60
52-62
2182.08
2178.86
2144.97
37.11
CB-9BR
4/21/2015
Bedrock
PVC
2
35.4720311
-82.5467707
97.85
83-93
2181.11
2178.15
2130.40
50.71
CB-9SL*
4/21/2015
Saprolite
PVC
2
35.4720577
-82.5467646
78.10
69-74
2181.42
2178.17
2145.32
36.10
LMW-1B
9/11/2020
Bedrock
PVC
2
35.4732130
-82.5469693
103.20
91-101
2169.67
2169.53
2147.67
22.00
LMW-is*
8/31/2020
Surficial
PVC
2
35.4731733
-82.5469538
66.60
55-65
2169.73
2169.58
2144.89
24.84
LMW-2B
9/11/2020
Bedrock
PVC
2
35.4740577
-82.5491559
110.30
100.5-110.5
2121.16
2120.84
2056.73
64.43
LMW-2T
9/11/2020
Transition
PVC
2
35.4741121
-82.5491312
87.00
76-86
2123.11
2123.20
2058.47
64.64
LMW-3B
9/11/2020
Bedrock
PVC
2
35.4734715
-82.5496049
45.30
33-43
2102.89
2102.80
2069.42
33.47
LMW-4B
9/11/2020
Bedrock
PVC
2
35.4729336
-82.5506071
49.25
39-49
2102.67
2102.57
2080.94
21.73
Notes:
* - Indicates background groundwater monitoring well.
Groundwater elevations are based on data collected during the March 2023 sampling event.
BGS - below ground surface
BTOC - below top of casing
CCR - coal combustion residual
Ft - feet
NAD 83 - Horizontal coordinates based on the North American Datum of 1983.
NAVD 88 - Vertical elevations in feet based on North American Vertical Datum of 1988.
NM - not measured
PVC - polyvinylchloride
TOC - top of casing
Prepared by: RBP Checked by: DAT
Page 1 of 1

TABLE 2
SUMMARY OF CONSTITUENTS AND ANALYTICAL METHODS
SEMIANNUAL WATER QUALITY MONITORING REPORT
MARCH 2O23 SAMPLING EVENT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Constituent
Units
Analytical Methods
15A NCAC 02L
Standards for
Groundwater
15A NCAC 02B
Standards, ISTV, and
USEPA Criteria for
Surface Water
In Situ Parameters
Field pH
S.U.
Multi -Parameter Water Quality Meter
6.5-8.5
6.0-9.0
Field Specific Conductance
[10/cm
Multi -Parameter Water Quality Meter
NE
NE
Field Temperature
degrees Celsius
Multi -Parameter Water Quality Meter
NE
<_ 29
Field Dissolved Oxygen
mg/L
Multi -Parameter Water Quality Meter
NE
>_ 4
Field Oxidation Reduction Potential
mV
Multi -Parameter Water Quality Meter
NE
NE
Field Turbidity
NTU
Turbidimeter
NE
Streams <_ 50
Water Level
feet
Water Level Meter
NE
NE
Laboratory Analyses
Antimony
µg/L
EPA 200.8 / SW 6020E
1
5,300#
Arsenic
µg/L
EPA 200.8 / SW 6020B
10
10
Barium
µg/L
EPA 200.7 / SW 6010D
700
21,000$
Beryllium
µg/L
EPA 200.8 / SW 6020B
4
NE
Beryllium (dissolved)
µg/L
EPA 200.8 / SW 6020E
NE
65^
Boron
µg/L
EPA 200.7 / SW 6010D
700
34,000#
Cadmium
µg/L
EPA 200.8 / SW 6020E
2
NE
Cadmium (dissolved)
µg/L
EPA 200.8 / SW 6020B
NE
0.75^'t
Calcium
mg/L
EPA 200.7 / SW 6010D
NE
NE
Chloride
mg/L
EPA 300.0 / EPA 9056A
250
230
Chromium
µg/L
EPA 200.8 / SW 6020E
10
NE
Chromium (dissolved)
µg/L
EPA 200.8 / SW 6020B
NE
180""
Cobalt
µg/L
EPA 200.8 / SW 6020E
1
4$
Copper
µg/L
EPA 200.8 / SW 6020B
1,000
NE
Copper (dissolved)
µg/L
EPA 200.8 / SW 6020E
NE
3.6"'t
Fluoride
mg/L
EPA 300.0 / EPA 9056A
2
1.8
Iron
µg/L
EPA 200.7 / SW 6010D
300
1,000*
Lead
µg/L
EPA 200.8 / SW 6020B
15
NE
Lead (dissolved)
µg/L
EPA 200.8 / SW 6020E
NE
14A't
Lithium
µg/L
EPA 200.7 / SW 6010D
NE
NE
Magnesium
mg/L
EPA 200.7 / SW 6010D
NE
NE
Manganese
µg/L
EPA 200.7 / SW 6010D
50
100*
Mercury
µg/L
EPA 245.1 / SW 7470A
1
0.012
Molybdenum
µg/L
EPA 200.8 / SW 6020B
NE
2,000$
Nickel
µg/L
EPA 200.8 / SW 6020E
100
NE
Nickel (dissolved)
µg/L
EPA 200.8 / SW 6020B
NE
140^'t
Nitrate
mg/L
EPA 300.0 / EPA 9056A
10
NE
Selenium
µg/L
EPA 200.8 / SW 6020B
20
NE
Selenium (dissolved)
µg/L
EPA 200.8 / SW 6020E
NE
3.1&
Silver
µg/L
EPA 200.8 or SW 6020A
20
NE
Silver (dissolved)
µg/L
EPA 200.8 or SW 6020A
NE
0.30A't
Sulfate
mg/L
EPA 300.0 / EPA 9056A
250
NE
Thallium
µg/L
EPA 200.8 / SW 6020E
2
2$
Total Dissolved Solids
mg/L
SM 2540C / EPA 160.1 / ASTM D5907
500
NE
Total Hardness
mg/L
Calculation (2.497 (calcium) + 4.118 (magnesium))
NE
NE
Vanadium
µg/L
EPA 200.8 / SW 6020B
7
NE
Zinc
µg/L
EPA 200.7 / SW 6010D
1,000
NE
Zinc (dissolved)
µg/L
EPA 200.7 / SW 6010D
NE
36"t
Prepared by: KHF Checked by: SAS TJG
Notes:
Constituents analyzed in the WQMP were approved by NCDEQ on March 20, 2023.
15A NCAC 02L Standards for Groundwater - North Carolina Class GA Standards found in 15A NCAC 02L .0202 Groundwater Quality Standards (effective April 1, 2022).
15A NCAC 02B Standards for Surface Water - 15A NCAC 02B Standards for Class C surface waters. North Carolina surface water and wetland standards (effective September 1, 2022).
ISTV for Surface Water - In -stream target values established per 15A NCAC 02B .0202 and .0208.
USEPA Criteria for Surface Water - U.S. Environmental Protection Agency National Recommended Water Quality Criteria
For 15A NCAC 02B Standards and ISTVs with acute and chronic criteria, the acute criteria are considered more applicable to grab sampling; therefore, those values are presented.
Dissolved constituents are applicable to surface water analytical parameters only.
$ - An exceedance of a published ISTV is not automatically a violation of the water quality standard for toxicity. Comparison value presented is the lesser of the Aquatic Life & Secondary Recreation or Fish
- ISTV is based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not applicable to sampling method. An exceedance of a published ISTV is not
automatically a violation of the water quality standard for toxicity.
USEPA National Recommended Water Quality Criteria are not a regulation, nor do they impose a legally -binding requirement. Therefore, comparisons with these criteria are for situational context.
Comparison criteria based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not applicable to sampling method and provided for screening
t - Hardness -dependent standard calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening purposes only.
`- Hardness -dependent standard for chromium III calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening purposes only.
&- Selenium standard for lotic water based on a 30-dayaverage. Not applicable to the sampling method and provided for screening purposes only.
EPA - Environmental Protection Agency
µg/L - micrograms per liter
µQ/cm - micro -ohms per centimeter
mg/L - milligrams per liter
mV - millivolts
NCDEQ- North Carolina Department of Environmental Quality
NE - not established
NTU - nephelometric turbidity units
S.U. - standard units
SW - Solid Waste
Page 1 of 1

TABLE 3
FIELD DATA PARAMETERS
SEMIANNUAL WATER QUALITY MONITORING REPORT
MARCH 2O23 SAMPLING EVENT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Sample ID
Sample
Date
Appearance
Odor
Purge
Method
Average
Pump Rate
(mL/min)
Temp
(Deg C)
Specific
Conductance
(µmhos/cm)
pH
(S.U.)
ORP
(mV)
Dissolved
Oxygen
(mg/L)
Turbidity
(NTU)
Depth
to Water
(Ft BTOC)
Measuring Point
TOC
Groundwater
Elevation
(Ft NAVD 88)
Groundwater Parameters
C13-9
3/21/2023
Clear
None
Low Flow
180
13
31
4.5
377
2.00
1.2
37.11
2182.08
2144.97
C13-91311
3/20/2023
Clear
None
Low Flow
300
15
86
5.9
329
0.48
2.0
50.71
2181.11
2130.40
CB-9SL
3/20/2023
Clear
None
Low Flow
120
15
50
5.5
352
2.30
1.4
36.10
2181.42
2145.32
LMW-113
3/21/2023
Clear
None
Low Flow
250
12
107
6.0
292
0.39
1.9
22.00
2169.67
2147.67
LMW-1S
3/21/2023
Clear
None
Low Flow
300
14
64
5.6
311
2.06
3.1
24.84
2169.73
2144.89
LMW-213
3/21/2023
Clear
None
Low Flow
300
14
70
5.7
211
1.62
1.7
64.43
2121.16
2056.73
LMW-2T
3/21/2023
Clear
None
Low Flow
180
17
65
5.7
294
5.70
3.1
64.64
2123.11
2058.47
LMW-313
3/21/2023
Clear
None
Low Flow
180
12
519
6.2
308
1.64
2.6
33.47
2102.89
2069.42
LMW-413
3/21/2023
Clear
None
Low Flow
350
13
338
6.3
185
0.35
8.2
21.73
2102.67
2080.94
Surface Water Parameters
LF-SW-1
3/20/2023
Clear
None
NA
NA
5
361
6.4
451
12.42
2.8
NA
NA
NA
LF-SW-2
3/20/2023
Clear
None
NA
NA
7
99
6.7
426
10.93
3.0
NA
NA
NA
LF-SW-3
3/20/2023
Clear
None
NA
NA
12
122
7.5
356
9.81
2.6
NA
NA
NA
DP-4
Dry, not sampled.
Leachate Collection Parameters
LCS-1
1 3/20/2023
Clear
None
NA
NA
16
1563
6.7
368
5.52
4.5
NA
NA
NA
Notes:
µmhos/cm - micromhos per centimeter
BTOC - below top of casing
Deg C - degrees Celsius
ft - feet
mg/L - milligrams per liter
mL/min - milliliters per minute
mV - millivolts
NA - not applicable
NAVD88 - North American Vertical Datum of 1988
NTU - Nephelometric turbidity units
ORP - oxidation reduction potential
S.U. - standard units
Prepared by: TG/KHF Checked by: EMH
Page 1 of 1

TABLE 4
GROUNDWATER SEEPAGE VELOCITIES
SEMIANNUAL WATER QUALITY MONITORING REPORT
MARCH 2O23 SAMPLING EVENT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Surficial and Transition Flow Zone
Upgradient
Downgradient
Seepage
Groundwater
Groundwater
K
Ah
Distance
Well ID
Effective Porosity
Velocity
Elevation
Elevation
1
(ft/day)
(ft)
(ft)
(ft/day)
(Ft NAVD 88)
(Ft NAVD 88)
LMW-1S to LMW-2T
2144.89
2058.47
0.33
86.42
733
0.2
0.195
Bedrock Flow Zone
Upgradient
Downgradient
Seepage
Well ID
Groundwater
Groundwater
K
ah
Distance
Effective Porosity
Velocity
Elevation
Elevation
(ft/day)'
(ft)
(ft)
(ft/day)Z
(Ft NAVD 88)
(Ft NAVD 88)
LMW-16 to LMW-2B
2147.67
2056.73
1.96
90.94
720
0.001
247.6
C13-961R to LMW-3B
2130.40
2069.42
1.96
60.98
993
0.001
120.3
Notes:
i
- Hydraulic conductivity values taken from slug test performed on monitoring wells with in each flow zone.
z - Value represents an estimate of the velocity of groundwater through bedrock fractures.
Groundwater elevations are based on water level data collected on March 20-21, 2022.
Monitoring wells are not listed where groundwater contour information is unavailable to calculate velocity.
Hydraulic gradients and groundwater velocities are approximate.
Effective porosity taken from the Updated Groundwater Flow and Transport Modeling Report for Asheville Steam Electric Plant, Arden, NC - September 2022.
ft - feet
ft/day - feet per day
NAVD 88 - North American Vertical Datum 1988
Prepared by: EMH Checked by: RBP
Page 1 of 1

TABLE 5
GROUNDWATER FIELD RESULTS AND ANALYTICAL DETECTIONS
SEMIANNUAL WATER QUALITY MONITORING REPORT
MARCH 2O23 SAMPLING EVENT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Parameter
SWS ID
Units
Monitoring Wells
MDL
SW GWPS
15A NCAC 02L
Standard'
CB-9
CB-9BR
CB-9SL
LMW-113
LMW-1S
LMW-26
LMW-2T
LMW-313
LMW-413
pH
320
S.U.
4.5
5.9
5.5
6.0
5.6
5.7
5.7
6.2
6.3
-
NE
6.5-8.5
Temperature
325
Deg C
13
15
15
12
14
14
17
12
13
-
NE
NE
Specific Conductance
323
µmhos/cm
31
86
50
107
64
70
65
519
338
-
NE
NE
Dissolved Oxygen
-
mg/L
2.00
0.48
2.30
0.39
2.06
1.62
5.70
1.64
0.35
-
NE
NE
Oxidation Reduction Potential
336
mV
377
329
352
292
311
211
294
208
185
-
NE
NE
Eh
-
mV
582
534
557
467
516
416
499
513
390
-
NE
NE
Turbidity
330
NTU
1.2
2.0
1.4
1.9
3.1
1.7
3.1
2.6
8.2
-
NE
NE
Antimony
13
µg/L
<1
<1
<1
<1
<1
<1
<1
<1
<1
0.104
NE
1
Arsenic
14
µg/L
<1
<1
<1
<1
<1
<1
<1
0.131 J
0.288 J
0.111
NE
10
Barium
15
µg/L
29
28
46
28
44
44
32
84
37
2
NE
700
Beryllium
23
µg/L
<1
<1
0.279 J
<1
<1
<1
<1
<1
1.09
2
NE
4
Boron
428
µg/L
11J
6J
5J
6J
6J
13J
27J
10.1
38J
5
NE
700
Cadmium
34
µg/L
0.047 J
<1
<1
<1
<1
<1
0.04 J
<1
<1
0.032
NE
2
Chloride
301
mg/L
6.3
7.6
7.7
8.2
6.1
7.7
9.6
3.1
7.6
0.0154
NE
250
Chromium
51
µg/L
NA
0.246 J
0.714 J
0.486 J
0.955 J
0.682 J
0.271 J
0.295 J
<1
0.185
NE
10
Cobalt
53
µg/L
0.872 J
<1
<1
<1
0.509 J
0.108 J
0.392 J
0.291 J
18.6
0.077
NE
1
Copper
54
µg/L
0.968 J
<1
<1
<1
0.832 J
<1
<1
0.79 J
<1
1
NE
1,000
Fluoride
312
mg/L
<0.1
0.05 J
0.05 J
<0.1
<0.1
<0.1
<0.1
<0.1
0.47 J
0.0479
NE
2
Iron
340
µg/L
20
98
21
68 J
413
37
182
38
10600
4
NE
300
Lead
131
µg/L
0
<1
0.056 J
0.081 J
0.146 J
0.115 J
0.084 J
0.082 J
<1
0.037
NE
15
Manganese
342
µg/L
0.04 J
46
11
4 J
52
8
21
200
4990
1
NE
50
Mercury
132
µg/L
<0.05
<0.05
<0.05
<0.05
<0.05
<0.05
<0.05
<0.05
<0.05
0.01
NE
1
Nickel
152
µg/L
1.03
0.491 J
0.469 J
0.517 J
4.29
0.332 J
0.301 J
0.384 J
5.6
1
NE
100
Nitrate (as N)
303
mg-N/L
0.82
0.23
0.24
0.02 J
0.49
0.25
0.06 J
1.5
1.1
0.002
NE
10
Selenium
183
µg/L
<1
<1
<1
<1
<1
<1
<1
<1
<1
0.193
NE
20
Silver
184
µg/L
<1
0.093 J
0.682 J
0.084 J
0.042 J
<1
0.042 J
<1
<1
0.035
NE
20
Sulfate
315
mg/L
0.08 J
1.4
0.25
0.28
0.26
2.6
4.4
260
89
0.0428
NE
250
Thallium
194
µg/L
0.067 J
<0.2
<0.2
<0.2
0.051 J
<0.2
<0.2
<0.2
<0.2
0.041
NE
2
Total Dissolved Solids
311
mg/L
<25
79
40
95
58
65
47
535
281
25
NE
500
Vanadium
209
µg/L
<0.3
<0.03
<0.3
0.418
0.451
0.535
0.359
0.177 J
<0.3
0.114
NE
7
Zinc
213
1 µg/L
10
<5
<5
<5
6
<5
<5
<5
<5
4
NE
1,000
Notes:
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System as of OS/04/2023.
Bold concentrations are equal to or greater than the 15A NCAC 02L Standard (for pH bold indicates a measurement less than or greater than the indicated range).
1 - 15A NCAC 02L Standards for groundwater - North Carolina groundwater quality standards (effective April 1, 2022).
CB-9/BR/SL and LMW-1B/S are background groundwater monitoring wells.
Samples collected by Duke personnel on March 21, 2023.
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
MDL - Laboratory Method Detection Limit; MDL values presented are for samples not diluted by the laboratory during analysis.
<- Concentration not detected at or above the adjusted reporting limit.
°C - degrees Celsius
mV - millivolts
mg/L - milligrams per liter
mg-N/L - milligrams nitrogen per liter
NCAC - North Carolina Administrative Code
NE - not established
NTU - Nephelometric turbidity units
S.U. - standard units
SW GWPS - Solid Waste Groundwater Protection Standard
SWS ID - Solid Waste Section Identification Number
µmhos/cm - micromhos per centimeter
µg/L - micrograms per liter
Prepared by EMH Checked by: TG
Page 1 of 1

TABLE 6
FIELD AND ANALYTICAL RESULTS THAT EQUAL OR EXCEED GROUNDWATER QUALITY STANDARDS
SEMIANNUAL WATER QUALITY MONITORING REPORT
MARCH 2O23 SAMPLING EVENT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
15A NCAC
Historical
Parameter
Sample ID
March 2023Units
02L
Concentration
Cause and Significance
Concentration
Standards
Range
LMW-213
5.7
5.3 - 5.8
Natural variation, within historical concentration range.
Natural variation, greater than historical concentration range but within background
LMW-2T
5.7
5.3 - 5.6
concentration range (4.5 - 6.4 S.U.).3
pH
S.U.
6.5-8.5
LMW-313
6.2
5.5 - 6.4
Natural variation, within historical concentration range.
Natural variation, less than historical concentration range but within background
LMW-46
6.3
6.4 - 6.6
concentration range (4.5 - 6.4 S.U.).3
Cobalt
LMW-413
25.8
µg/L
1
56.7 - 75.6
Natural variation, less than historical concentration range.
Iron
LMW-46
10,600
µg/L
300
20,800 - 27,400
Natural variation, less than historical concentration range.
LMW-36
200
299 - 774
Natural variation, within historical concentration range.
Manganese
µg/L
50
LMW-46
4,990
10,000 - 13,800
Natural variation, less than historical concentration range.
Cause and significance cannot be determined at this time.
Sulfate
LMW-36
260
mg/L
250
75 - 230
Further investigation pending
Total dissolved
LMW-313
535
mg/L
500
45 - 696
Natural variation, within historical concentration range.
solids
Prepared by: RBP Checked by: KHF
Notes:
- 15A NCAC 02L Standards for groundwater - North Carolina groundwater quality standards (effective April 1, 2022).
Z - Historical concentration ranges are based on data from the four baseline monitoring events that occurred between September 2020 and January 2021, prior to waste placement in the CCR Landfill.
3 - The background concentration range is based on data collected from upgradient bedrock monitoring wells during Landfill compliance sampling events (September 2020 through March 2023).
µg/L - micrograms per liter
mg/L - milligrams per liter
S.U. - standard units
Page 1 of 1

TABLE 7
SURFACE WATER FIELD RESULTS AND ANALYTICAL DETECTIONS
SEMIANNUAL WATER QUALITY MONITORING REPORT
MARCH 2O23 SAMPLING EVENT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Parameter
l
SWS ID
Units
Surface Water Sample ID
MDL
15A NCAC 02B
(Class C)Z
LF-SW-1
LF-SW-2
LF-SW-3
Field pH
320
S.U.
6.4
6.7
7.5
-
6.0 - 9.0
Field Specific Conductance
323
µmhos/cm
361
99
122
-
NE
Field Temperature
325
Deg C
5
7
12
-
:529
Field Dissolved Oxygen
-
mg/L
12.42
10.93
9.81
-
2A
Field Oxidation Reduction Potential
336
mV
451
426
356
-
NE
Field Turbidity
330
NTUs
2.8
3.0
2.6
-
Streams <_50
Laboratory Analyses
Antimony
13
µg/L
<1
<1
<1
0.104
5,300#
Arsenic
14
µg/L
<1
<1
<1
0.111
10
Barium
15
µg/L
29
18
15
2
21,000$
Beryllium
23
µg/L
<1
<1
<1
2
NE
Beryllium (dissolved)
23
µg/L
<1
<1
<1
0.249
65'
Boron
428
µg/L
20 J
21 J
23 J
5
34,000#
Cadmium
34
µg/L
0.039 J
0.127 J
<1
0.032
NE
Cadmium (dissolved)
34
µg/L
0.072 J
0.142 J
<1
0.032
0.75^'t
Calcium
375
mg/L
17.8
7.12
4.82
0.012
NE
Chloride
301
mg/L
2.5
8.1
9.8
0.0154
230
Chromium
51
µg/L
0.417 J
0.206 J
0.217 J
0.185
NE
Chromium (dissolved)
51
µg/L
0.206 J
<1
<1
0.185
180"
Cobalt
53
µg/L
0.078 J
0.308 J
<1
0.077
4$
Copper
54
µg/L
<1
<1
<1
1
NE
Copper (dissolved)
54
µg/L
<1
<1
<1
0.787
3.6"t
Fluoride
312
mg/L
<0.1
<0.1
<0.1
0.0479
1.8
Iron
340
µg/L
47
212
54
4
1,000*
Lead
131
µg/L
0.064 J
<1
0.064 J
0.037
NE
Lead (dissolved)
131
µg/L
0.078 J
<1
<1
0.037
14"t
Lithium
NA
µg/L
4 J
3 J
3.1
0.002
NE
Magnesium
376
mg/L
6.14
2.75
1.79
0.008
NE
Manganese
342
µg/L
3J
231
7
1
100*
Mercury
132
µg/L
<0.05
<0.05
<0.05
0.01
0.012
Molybdenum
397
µg/L
<1
<1
1.77 J
0.18
2,000$
Nickel
152
µg/L
<1
<1
<1
1
NE
Nickel (dissolved)
152
µg/L
0.554 J
0.472 J
0.337 J
0.256
140^'t
Nitrate (as Nitrogen)
303
mg-N/L
0.12
0.15
0.09
0.002
NE
Selenium
183
µg/L
0.406 J
<1
0.212 J
0.193
NE
Selenium (dissolved)
183
µg/L
NA
NA
NA
NA
3.1&
Silver
184
µg/L
<1
<1
<1
0.035
NE
Silver (dissolved)
184
0.049 J
0.049 J
<1
<1
0.035
0.30^'t
Sulfate
315
mg/L
51
11
4.1
0.0428
NE
Thallium
194
µg/L
<0.2
<0.2
<0.2
0.041
2$
Total Dissolved Solids
311
mg/L
108
57.0
48.0
25
NE
Total Hardness
NA
mg/L
69.6
29.1
19.4
NA
NE
Vanadium
209
µg/L
<0.3
<0.3
<0.3
0.114
NE
Zinc
213
µg/L
<5
<5
<5
0.004
NE
Zinc (dissolved)
213
µg/L
5
5 J
<5
0.004
36"
Prepared by: EMH RBP Checked by: DAT
Notes:
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System as of 05/04/2023.
Bold concentrations are equal to or greater than the 15A NCAC 02B Standards for Class C surface waters (for pH, bold indicates a measurement less than or greater than the indicated range).
15A NCAC 02B Standards for Class C surface waters. North Carolina surface water and wetland standards (effective September 1, 2022)
Samples collected by Duke Energy personnel on March 20, 2023.
1- Solid Waste Section Identification. Unique identification assigned by the Section.
$ - An exceedance of a published ISTV is not automatically a violation of the water quality standard for toxicity. Comparison value presented is the lesser of the Aquatic Life & Secondary Recreation or
Fish Consumption value.
- ISTV is based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not applicable to sampling method. An exceedance of a published ISTV is not
automatically a violation of the water quality standard for toxicity.
USEPA National Recommended Water Quality Criteria are not a regulation, nor do they impose a legally -binding requirement. Therefore, comparisons with these criteria are for situational context.
Comparison criteria based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not applicable to sampling method and provided for screening
purposes only.
t - Hardness -dependent standard calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening purposes only.
x - Hardness -dependent standard for chromium III calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening purposes only.
& Selenium standard for lotic water based on a 30-day average. Not applicable to the sampling method and provided for screening purposes only.
no relevant information.
< - Concentration not detected at or greater than the adjusted reporting limit.
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
MDL - laboratory method detection limit; MDL values presented are for samples not diluted by the laboratory during analysis.
°C - degrees Celsius
mg/L - milligrams per liter
mg-N/L - milligrams nitrogen per liter
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
mV - millivolts
NA - not applicable
NE- not established
NE - Not established per 15A NCAC 02B.
NTU - nephelometric turbidity units
S.U.- standard units
SWS ID - Solid Waste Section Identification Number
Page 1 of 1

TABLE 8
LEACHATE FIELD RESULTS AND ANALYTICAL DETECTIONS
SEMIANNUAL WATER QUALITY MONITORING REPORT
MARCH 2O23 SAMPLING EVENT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Parameter
SWS ID
Units
Leachate Collection Sample
MDL
LCS-11,2
pH
320
S.U.
6.7
Specific Conductance
323
µmhos/cm
1563
Temperature
325
Deg C
16
Dissolved Oxygen
-
mg/L
5.52
Oxidation Reduction Potential
336
mV
368
Eh
-
mV
573
Turbidity
330
NTUs
4.5
-
Antimony
13
µg/L
0.9651
0.104
Arsenic
14
µg/L
3.72
0.111
Barium
15
µg/L
36
2
Beryllium
23
µg/L
<1
2
Boron
428
µg/L
9,630
5
Cadmium
34
µg/L
0.046 J
0.032
Chloride
301
mg/L
36
0.0154
Chromium
51
µg/L
0.8811
0.185
Cobalt
53
µg/L
0.2341
0.077
Copper
54
µg/L
1.14J
1
Fluoride
312
mg/L
1.11
0.0479
Iron
340
µg/L
385 J
4
Lead
131
µg/L
0.2891
0.037
Manganese
342
µg/L
246J
1
Mercury
132
µg/L
<0.05
0.01
Nickel
152
µg/L
3.07
1
Nitrate (as N)
303
mg-N/L
0.23 J
0.002
Selenium
183
µg/L
35.1
0.193
Silver
184
µg/L
<1
0.035
Sulfate
315
mg/L
670
0.0428
Thallium
194
µg/L
0.0961
0.041
Total Dissolved Solids
311
mg/L
1560
25
Vanadium
209
µg/L
2.94 J
0.114
Zinc
213
µg/L
<5
4
Notes:
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System as of 05/04/2023.
Sample collected by SynTerra and Duke personnel on September 26, 2022.
Comparative criteria are not applied to leachate collection samples.
The WQMP identifies the leachate collection sample as L-1. Identification was revised in the field during sampling collection.
<- Concentration not detected at or greater than the adjusted reporting limit
"C - degrees Celsius
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
MDL - Laboratory Method Detection Limit; MDL values presented are for samples not diluted by the laboratory during analysis.
mg N/L - milligrams nitrogen per liter
mg/L - milligrams per liter
mV - millivolts
NTU - Nephelometric turbidity unit
S.U. -standard units
SWS ID - Solid Waste Section Identification Number
WQMP - Water Quality Monitoring Plan
Prepared by: EMH Checked by: TG
Page 1 of 1

Semiannual Water Quality Monitoring Report — March 2023 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
APPENDIX A
FIELD SAMPLING FORMS
L7
synTerra
Science & Engineering Consultants

DCAMA F_�CCRF—,]Landfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY,
FIELD SAMPLING t1 '06 DUKE I
,E
Site: A56viKe- Well/SW ID: C9-7 Date: 3-y-Z3
GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: 01,
COMPANY: l❑ DUKE ENERGY
❑ OTHER:
WEATHER:
QSUNNY ❑ PARTLY CLOUDY ❑ OVERCAST []RAIN ❑SNOW AIR TEMP: 30 -F
FIELD METER TYPE/ SERIAL#: 61SIOLIC
TURBIDIMETER TYPE/ SERIAL #: 3i
START PURGE TIME: OV15 SAMPLE COLLECTION TIME: 0530
PUMP/TUBING INTAKE DEPTH:
74.1to (ft)
DEPTH TO WATER: 37•11 (ft)
MULT FACTOR *: 0.163 ['(radius/12)2"3.147.48]
WELL DIAMETER: I tp
(in)
HEIGHT OF WC: 39. -M (ft)
WELL VOLUME: Oft (gal)
WELL DEPTH:-76.4to
(it)
TOTAL VOLUME PURGED: o'93 (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
R
°
0 Tubing/Pump /Pump Inspected (psi) (sec) (Sec) Low Flow Sampling Stabilization Criteria
❑Good [Tubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event PH f 0.1 standard unit
Additional Notes: Specific Conductance f 5% in (IS/cm
• DO t 0.2 mg/L or 10% saturation
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
(x)
(gallons OR mL)
(x.xx)
VC)
W
(mg/L)
(x.xx)
(PS/cm)
W
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
oii1$
i7.6q
$0
0.15
11
°t
cl.
I. L
ab2�
3�1�-
Ise
a•35
12
2.1H
W.3G
e
2
b2'
t' 'n
bo
e3 v
Y-15
314
01
bb2'1
36.01
tg9
6• 5
(
l.gFS
32
N.K8
3%,
1.6
ob'5a
•ati
I tsV
a. �g
t
Z
31
w.s C>
3Z-7
�•Z
rL-cAae M=I-=K I U I HE bAUK OF I HIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ONO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? EYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES Q NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?[—] YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR /Node H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH (� ne Minor Strong
ADDITIONAL NOTES: APPEARANCE ar Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

F—]CAMA [-
CCR o Landfill F—]NPDES ❑DGW❑ASW ❑LRB❑ SPECIAL STUDY !fi�rr
l.J R
FIELDS P'LI Le�6
ENERGY
Site: 44vv,,14c, Well/SW ID: CAJ 89 Date: 3- zo-23
GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: C%Z WEATHER: []SUNNY❑ PARTLY CLOUDY ❑ OVERCAST []RAIN []SNOW AIR TEMP: °F
COMPANY: F71 DUKE ENERGY FIELD METER TYPE/ SERIAL#: 95MM
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #: 3'32c.
START PURGE TIME: 13S`1 SAMPLE COLLECTION TIME: 4ft l (15
PUMP/TUBING INTAKE DEPTH: Q1. / 2 (ft) DEPTH TO WATER: 50' 7 I (ft) MULT FACTOR * 0.163 [*(radius112)2*3.14*7.481
WELL DIAMETER: O (in) HEIGHT OF WC: y5•KI (ft) WELL VOLUME: 7,40 (gal)
WELL DEPTH: H6. 1 7- (ft) TOTAL VOLUME PURGED: I. 6 0 (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
R
0
❑ Tubing/Pump Inspected I (psi) I (sec) I (sec) I Low Flow Sampling Stabilization Criteria
RGood Tubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event PH f 0.1 standard unit
Additional Notes: Specific Conductance t 5%u in NS/cm
Cie. b-e DO ± 0.2 mg/L or 10%e saturation
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
(x)
(gallons OR mL)
(x.xx)
(°C)
W
(mg/L)
(x.xx)
(PS/CM)
W
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
1351
St.2v
300
0,�0
15
ZZI
a$
6./q
t-u
300
o'bo
1
I. o
RI
6.06
I'jos
51.36
3w
,4 U
/5
0.61
99
Se 1
33
IKob
St.3L
'00
I•'Ln
15
0.51
67
5.94
336
�•d
tKaK
5;(•36
3UD
15
O.Su
S7
.5•013
327
r-L
(Kb2.
506
3w
(5
o. KZ
$6
5.013
3z
Z. 0
I'LEASt KEl-tK I U 1 HE BACK Oh I HIS SHEE I IF THE CHART ABOVE 15 FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? [:]YES 0 NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES?,"❑YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES E� NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?❑—j-YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR tn. H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH Minor Strong
ADDITIONAL NOTES: APPEARANCE Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
i
Version 1.2 Revised 09/29/2022 HPB

[:]CAMA FCCRF-]Landfill F—]NPDES ❑ DGWFASW F]LRB ❑ SPECIAL STUDY,
Site: /k,c.,14-, Well/SW ID: G6-0(si.
Date: 3- Zo -z 3
111 GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: 01— WEATHER: ❑SUNNY ❑ PARTLY CLOUDY ❑ OVERCAST ❑ RAIN SNOW AIR TEMP: °F
COMPANY: [7] DUKE ENERGY FIELD METER TYPE/ SERIAL M °I5195t
❑ OTHER: TURBIDIMETER TYPE/ SERIAL M 3)2rt
START PURGE TIME: JSGD SAMPLE COLLECTION TIME: 15 (D
PUMP/TUBING INTAKE DEPTH: �7 �2 (ft) DEPTH TO WATER: 36.10 (ft) MU LT FACTOR *• 0.163 ['(radius/1z)2.3.14.7.481
WELL DIAMETER: 20 (in) HEIGHT OF WC: 4,rs(o (ft) WELL VOLUME: '?o (gal)
WELL DEPTH: gq. q (ft) TOTAL VOLUME PURGED: 6.17 (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
/
PUMP SETTING:
R
R
D
❑ Tubin m /Pup Inspected (Psi) (sec) (sec) Low Flow Sampling Stabilization Criteria
❑Good [Tubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event PH f 0.1 standard unit
Additional Notes: Specific Conductance t 5% In pS/cm
DO t 0.2 mg/L or 10% saturation
Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
(x)
(gallons OR mL)
(x.xx)
VC)
W
(mg/L)
(x.xx)
(PS/cm)
W
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
1503
3-7• 5`1
I Zo
0.10
15
1,/. l 0
5 Z
5. H dl
3 5K
z q
150
30-so
110
O.iq
115
2 3
50
5-4.5
35z
1.11
N ►. 22
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? [:]YES E NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? AYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? nYESLINO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR No 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH Minor Strong
ADDITIONAL NOTES: APPEARANCE ge
r Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD;
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

ECAMA F—]CCR Landfill ONPDES ❑ DGWMASW MLRB ❑ SPECIAL STUDY.
Site: 456vk
Well/SW ID: y_q
Date: 3- Zy-Lj
El GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELDSTAFF: 627- WEATHER: QSUNNY ❑PARTLYCLOUDY ❑OVERCAST []RAIN ❑SNOW AIRTEMP:�7 -F
COMPANY: ❑ DUKE ENERGY FIELD METER TYPE/ SERIAL M 95/M
❑ OTHER: TURBIDIMETER TYPE/ SERIAL M 3374
START PURGE TIME: QSO SAMPLE COLLECTION TIME:
PUMP/TUBING INTAKE DEPTH: ` (ft) DEPTH TO WATER: — (ft) MULT FACTOR *: 0.163 [*(radius/12)2*3.14*7.48]
WELL DIAMETER: (in) HEIGHT OF WC: (ft) WELL VOLUME: (gal)
WELL DEPTH: (ft) TOTAL VOLUME PURGED: (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
R
D
❑ Tubing/Pump Inspected I (Psi) I (se-) I (sec) I Low Flow Sampling Stabilization Criteria
❑Good LjTubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event PH t 0.1 standard unit
• Specific Conductance t 5% In pS/cm
Additional Notes: DO * 0.2 mg/L or 10% saturation
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
W
(gallons OR mL)
(x.xx)
VC)
W
(mg/L)
(x.xx)
(PS/CM)
W
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
d FLU
FLtASt KtFEK I O THE BACK OF THI5 SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? RJYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?Q YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR None H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH None Minor Strong
ADDITIONAL NOTES: APPEARANCE Clear Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

F-]CAMA ❑CCRLandfill F-]NPDES ❑ DGW❑ASW F-]LRB ❑ SPECIAL STUDY,
Site: Asl cvik Well/SW ID: 1 Date: 3•20-23
GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: 01
COMPANY: ❑ DUKE ENERGY
❑ OTHER:
WEATHER: .SUNNY ❑PARTLY CLOUDY ❑OVERCAST ❑RAIN ❑SNOW AIRTEMP: ys °F
FIELD METER TYPE/SERIAL M 95148y
TURBIDIMETER TYPE/ SERIAL M 33?.`I
START PURGE TIME: 12K(SAMPLE COLLECTION TIME: 125o
PUMP/TUBING INTAKE DEPTH: (ft) DEPTH TO WATER: _ (ft) MULT FACTOR*: 0.163 [^(radius/12)2.3.14'7,4e]
WELL DIAMETER: (in) HEIGHT OF WC: (ft) WELL VOLUME: - (gal)
WELL DEPTH: (ft) TOTAL VOLUME PURGED: I.�S (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other( &Z" )
PURGE METHOD:
i
SAMPLING METHOD:
%
PUMP SETTING:
P
R
13
❑ Tubing/Pump Inspected I msv I (see) I (see) I Low Flow Sampling Stabilization Criteria
[-]Good Tubing Bad []Pump Bad ❑Changed/Cleaned ❑Correct Next Event PH f 0.1 standard unit
Additional Notes: Specific Conductance t 5% In pS/cm
• DO f 0.2 mg/L or 10% saturation
$w� Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mUmin)
N
(gallons OR mL)
(x.xx)
VC)
(x)
(mg/L)
(x.xx)
(PS/cm)
W
(Su)
(x.xx)
(mv)
W
(NTU)
(x.x)
IZKL
—
50D a
O . SO
16
5"3Y
IS 61
6•?2
31?
y. 2
IZK�S
Suv t
i.2S
!6
5 SZ
fS63>�K
365
NS
t'LtASt Ktl-tK I U I tit 5AUK OF 11115 SHtEr IF T HI-- CHART ABUVE 15 FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ElYES [INO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? ❑i YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑ YES ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? ❑ YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR No 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH a Minor Strong
ADDITIONAL NOTES: APPEARANCE ar Cloudy Turbid Red/Iron Film on Surface Sheen Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

❑CAMA ❑CCRoLandfill FNPDES ❑ DGWFJASW FLRB ❑ SPECIAL STUDY,
Site:
Well/SW ID: LF-Sw-t
Date: 3-ZO-23
T o( DUKE
E ER N'
❑GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑ WLO [:]WELL DEVELOPMENT
FIELD STAFF: (I-X WEATHER: QSUNNY ❑PARTLY CLOUDY ❑OVERCAST ❑RAIN ❑SNOW AIR TEMP: YV "F
COMPANY /❑ DUKE ENERGY FIELD METER TYPE/ SERIAL #: 95149
❑ OTHER: TURBIDIMETER TYPE/ SERIAL M b2l
START PURGE TIME: 1125 SAMPLE COLLECTION TIME: 1136
PUMP/TUBING INTAKE DEPTH: (ft) DEPTH TO WATER: (ft) MOLT FACTOR'": 0.163 ['(radius/12)2'3.14'7.48)
WELL DIAMETER: (in) HEIGHT OF WC: (ft) WELL VOLUME: (gal)
WELL DEPTH: — (ft) TOTAL VOLUME PURGED: 0. to (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( 3 )
PURGEMETHOD:
r
SAMPLING METHOD:
PUMP SETTING:
e
R
o
❑ Tubing/Pump Inspected I (psi) I (see) I (sec) I Low Flow Sampling Stabilization Criteria
❑Good LjTubing Bad "Pump Bad ❑Changed/Cleaned❑Correct Next Event pH f 0.1 standard unit
Additional Notes: Specific Conductance f 5% In NS/cm
• DO f 0.2 mg/L or 10% saturation
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
W
(gallons OR mL)
(x.xx)
CC)
W
(mg/L)
(x.xx)
(tIS/cm)
W
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
112'
_
30
d, 05
7
fl.o2
3'K5
6.34
`!?o
4.0
;o
0.IV
5
t2'12
367
g.36
KSl
2.9
IfLtASt KEI-EK I U I Ht BACK OF 1 HIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? AYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?© YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR (e H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH d%1�,ne Minor Strong
ADDITIONAL NOTES: APPEARANCE �( lear Cloudy Turbid Red/Iron Film on Surface Sheen �F nas Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

F-]CAMA F-]CCR [--]Landfill [—]NPDES ❑ DGW❑ASW F-] LRBFJ SPECIAL STUDY
ota
FIELD SAMPLING LOG DUKE
E ERG'
Site: 454w,/4- Well/SW ID: GF-3U/- z Date: 3 20-z3
GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: 672, WEATHER: [?SUNNY ❑PARTLY CLOUDY ❑OVERCAST ❑RAIN SNOW AIR TEMP: 'la °F
COMPANY`. Q DUKE ENERGY FIELD METER TYPE/ SERIAL #: g lciS�
❑ OTHER: TURBIDIMETER TYPE/ SERIAL M 7 Z9
START PURGE TIME: lIg5 SAMPLE COLLECTION TIME: 1150
PUMP/TUBING INTAKE DEPTH: (ft) DEPTH TO WATER: L' (ft) MULT FACTOR *: 0.163 [*(radius112)2,*3.14*7.481
WELL DIAMETER: (In) HEIGHT OF"WC: (ft) WELL VOLUME: (gal)
WELL DEPTH: (ft) TOTAL VOLUME PURGED: LI O (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( &t4o )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
R
°
4:6V
❑ Tubing/Pump /Pump Inspected I (psi) I (sec) I (Sec)
❑Good [Tubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event
Additional Notes:
Low Flow Sampling Stabilization Criteria
• pH t 0.1 standard unit
Specific Conductance t 5% In pS/cm
• DO ± 0.2 mg/L or 10% saturation
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
W
(gallons OR mL)
(x.xx)
(°C)
W
(mg/L)
(x.xx)
(PS/cm)
W
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
1005 -1
- ?.a
6
11.31
1(4
6.56
3,12,
3,S
tty
too o 4
1-6� Lf. 0
7
lo.
`%%
`.
N26
3 v
str..cwi �fuv
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? El YES ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?[YES ®NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR No a H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH a Minor Strong
ADDITIONAL NOTES: APPEARANCE t / a Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

ECAMA ❑CCRF,-]Landfill ❑NPDES ❑ DGW❑ASW F-]LRB ❑ SPECIAL STUDY.
FIELD SAMPLING LOG
Site: A-s�tt4 c. Well/SW ID: 15-5w-3
Date: 3- zD- 23
DUKE
" EEN
GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: (✓% , WEATHER: QSUNNY ❑ PARTLY CLOUDY ❑ OVERCAST [:]RAIN []SNOW AIR TEMP _ 3 -F
COMPANY: Q DUKE ENERGY FIELD METER TYPE/ SERIAL M `79'ig
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #: 53M
START PURGE TIME: 1310 SAMPLE COLLECTION TIME: i315
PUMP/TUBING INTAKE DEPTH. (ft) DEPTH TO WATER: (ft) MOLT FACTOR *• 0.163 [*(radius/12)2*3.14*7.48]
WELL DIAMETER: (in) HEIGHT OF WC: (ft) WELL VOLUME: - (gal)
WELL DEPTH: - (ft) TOTAL VOLUME PURGED: ° (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other( bp.Mg )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
R
D
❑ Tubing/Pump /Pump Inspected I (psi)I (sec) I (Sec)
❑Good [Tubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event
Additional Notes:
Low Flow Sampling Stabilization Criteria
pH f 0.1 standard unit
• Specific Conductance t 5% in pS/cm
• DO f 0.2 mg/L or 10% saturation
* Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
W
(gallons OR mL)
(x.xx)
VC)
W
(mg/L)
(x.xx)
(PS/CM)
W
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
13t2
5LV +
0.510
13
q.2q
►M
7.53
361
3.0
A-SXA
Soo +
LtA
12
agl
IZ2
7.K7
336
7.g
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ N
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR (9e 1-12S
ODOR STRENGTH Ghe Minor
ADDITIONAL NOTES: APPEARANCE Tar Cloudy
O
WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? AYES [:]NO
IS THE LOCATION FIELD VEHICLE ACCESSIBLE?[] YES 0 NO
DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
Petroleum
Strong
Turbid
Earthy Musty Undetermined
Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

F—]CAMA F,—]CCR FLandfill [—]NPDES ❑ DGW❑ASW F�LRB ❑ SPECIAL STUDY
FIELD SAMPLING L DUKE
ENE M
Site: 404k Well/SW ID: LAV - 18 Date:
❑GROUNDWATER SAMPLE❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: C?Z
COMPANY: 0 DUKE ENERGY
❑ OTHER:
WEATHER: []SUNNY ❑PARTLYCLOUDY []OVERCAST ❑RAIN ❑SNOW AIRTEMP: 'F
FIELD METER TYPE/ SERIAL #: 95111l4
TURBIDIMETER TYPE/ SERIAL #: 33717
START PURGE TIME:SAMPLE COLLECTION TIME: Da&5
PUMPITUBING INTAKE DEPTH: DEPTH TO WATER: 7-7-00 (ft) MULT FACTOR *• 0.163 [*(radius/12)2*3.14*7,48]
WELL DIAMETER: Z ® (in) HEIGHT OF WC: (ft) WELL VOLUME: 13.29 (gal)
WELL DEPTH: 105. 2 (ft) TOTAL VOLUME PURGED: 1.�5 (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
R
D
El Tubing/Pump /Pump Inspected I (Psi I (s") I (`) I Low Flow Sampling Stabilization Criteria
Good [Tubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event pH f 0.1 standard unit
• Specific Conductance t 5% In µS/cm
Additional Notes: DO t 0.2 mg/L or 10%u saturation
�► Lf Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
W
(gallons OR mL)
(x.xx)
VC)
W
(mg/L)
(x.xx)
(PS/CM)
W
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
085)
24LN
ZSo
0•M
q
.83
101
5•77
777
Z.L
obSH
22•$7
0.50
to
0401
/o-7
j',Rv
3 b
0,%5-)
ZZVC.o
r7.DS
11
0.qK
106
5.1
zsy
zL
oatA
22.60
1. w
( I
0.4(y
1 105
5-vit.
21P
?.5
0 olo3
2.2.6t;
Z; o
4-7,5
12
0. yj
o -7
-7
211 Z
1.41
1'LtAbt Kt1-tK I U I Ht UAUK OF 1 HIS SHtt IF IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? ❑YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?❑ - YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR &e 1­12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH Qne Minor Strong
ADDITIONAL NOTES: APPEARANCE Gar Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

ECAMA [?CCR Landfill F�NPDES ❑ DGWF�ASW F—]LRB ❑ SPECIAL STUDY
FIELD SAMPLING LOG DUKE
EEG'
Site: 4s4%ik Well/SW ID: t-mA/- I s Date: 3- 21-23
❑GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: OIL- WEATHER: ©SUNNY ElPARTLY CLOUDY ❑ OVERCAST ❑ RAIN ❑SNOW AIR TEMP: "F
COMPANY: Q DUKE ENERGY FIELD METER TYPE/ SERIAL #: 45mG
❑ OTHER: TURBIDIMETER TYPE/ SERIAL M 33"
START PURGE TIME: 0 11S SAMPLE COLLECTION TIME: 0e,50
PUMP/TUBING INTAKE DEPTH: 61 5 (ft) DEPTH TO WATER: Z Ni$ (ft) MULT FACTOR *: 0.1/63 ['(radius/12)2`3.14"7.48]
WELL DIAMETER: 2.0 (in) HEIGHT OF WC: y� �` (ft) WELL VOLUME: 1.6 1 (gal)
WELL DEPTH: 6C• 60 (ft) TOTAL VOLUME PURGED`. I•bu (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
e
o
0 Tubing/Pump /Pump Inspected I (Pso I (sec) I (sec) I Low Flow Sampling Stabilization Criteria
❑Good [Tubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event pH f 0.1 standard unit
Additional Notes: Specific Conductance t 5% In NS/cm
• DO t 0.2 mg/L or 10% saturation
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
W
(gallons OR mL)
(x.xx)
VC)
W
(mg/L)
(x.xx)
(PS/CM)
W
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
00133
25'tt
300
0.30
13
7-.941
6ID
5.61
324
4.0
OC13L
'15.11
0.60
14
z.1Z
63
5'•S4
319
w.Z
olks 1
2.5.1z1
0,010
14
1.11.1
6K
5.5
3Z0
3.9
001a2
15.ZI
I.Zo
1q
7.02
95
318
2,
o°tKS
25.2t
1.5v
/,(
2•u5
66
5.56
31L
21s
&Clalb
2�i•2t
300
1•bb
14
2.0t
3111
3.1
rLtAAt: Kr—f-tK I U I Ht tiACK UI- I HI' SHtt I IF I Him CHART ABOVE 15 FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? AYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?❑ YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR F.
H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH a Minor Strong
ADDITIONAL NOTES: APPEARANCE ear Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
ONE
y
�
1
Version 1.2 Revised 09/29/2022 HPB

F—]CAMA F—_]CCR�—,]Landfill F-]NPDES ❑ DGW❑ASW F-]LRB ❑ SPECIAL STUDY,
Site:isGr,�c
Weil/SW ID: LMV-213
Date: 3'20-23
El GROUNDWATER SAMPLE [—]SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: Ci7� WEATHER: ❑SUNNY ❑ PARTLY CLOUDY ❑ OVERCAST ❑ RAIN FISNOW AIR TEMP: °F
COMPANY: DUKE ENERGY FIELD METER TYPE/ SERIAL #: RSl
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #: *3314
START PURGE TIME: 0�- I SAMPLE COLLECTION TIME: 131 D
PUMPITUBING INTAKE DEPTH: 105 (ft) DEPTH TO WATER: 6`1•43 (ft) MULT FACTOR-: 0.163 ['(radius/12)2'3.14"7.48]
WELL DIAMETER: ?. o (in) HEIGHT OF WC: 45.S7 (ft) WELL VOLUME: 7. YSs (gal)
WELL DEPTH: 110. -3 (ft) TOTAL VOLUME PURGED: 1.50 (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
`
PUMP SETTING:
'
e
o
❑ Tubin /Pump Inspected �PS� (sec) (sec)
❑Good [Tubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event
Additional Notes:
Low Flow Sampling Stabilization Criteria
• pH ± 0.1 standard unit
Specfc Conductance t 5% In NS/cm
• DO t 0.2 mg/L or 10%e saturation
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC'
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
W
(gallons OR mL)
(x.xx)
VC)
W
(mg/L)
(x.xx)
(PS/CM)
W
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
12515
6y q2
3vo
0"10
12
4.C1'L
66
.q.5
23'1
2•�s
1256
65.04
0• Co
t 3
z I 1
601
5.71
2 ZD
r-
tti5
.OH
VAO
(ti
1.70
'7n
5.7S
aIL
2K
61
.04
I .'jw
1 H
(• 6 6
7(
515
Z I
r• z
I"S6
vtil
1,w
1.50
l • 62
70
5-77-
zit
1.17
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES El NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? [f]YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑ YES 0 NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?Q YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 ^ (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR VRe 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH Minor Strong
ADDITIONAL NOTES: APPEARANCE g,e
ar Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

❑CAMA [—]CCRLandfill F-]NPDES F-] DGW[-] ASWF-]LRB ❑ SPECIAL STUDY
Site: _ 4,5kevAe Well/SW ID: W W- 2i
Date: 3- 21-.�3
El GROUNDWATER SAMPLE❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: C%Z- WEATHER: QSUNNY ❑PARTLYCLOUDY ❑OVERCAST ❑RAIN ❑SNOW AIRTEMP: Y6 °F
COMPANY: Q DUKE ENERGY FIELD METER TYPE/ SERIAL #; fQW
❑ OTHER: TURBIDIMETER TYPE/ SERIALM 332'
START PURGE TIME: /3 "16 SAMPLE COLLECTION TIME: 14l0
PUMP/TUBING INTAKE DEPTH:y(' (ft) DEPTH TO WATER: 0.64 4 (ft) MULT FACTOR *: 0.163 ["(radiusrt2)2"3:14"7.48]
WELL DIAMETER: 2.6 (in) HEIGHT OF WC: 24,31, (ft) WELL VOLUME: 3.1Ii (gal)
WELL DEPTH: 81-0 (ft) TOTAL VOLUME PURGED: 615 (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
i
SAMPLING METHOD:
r
PUMP SETTING:
P
RI
D
❑ Tubin /Pump Inspected I (Psi) I (Sec) I (Sec)
QGood Tubing Bad "Pump Bad ❑Changed/Cleaned ❑Correct Next Event
Additional Notes:
Low Flow Sampling Stabilization Criteria
• pH :1 0.1 standard unit
• Specific Conductance t 5% in pS/cm
• DO ± 0.2 mg/L or 10% saturation
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
b0
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
W
(gallons OR mL)
(x.xx)
(*C)
W
(mg/L)
(x.xx)
(PS/CM)
W
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
1350
("ta5
p
0.15
IL
3.5
61
575
ZZL.
8.1
153
65.02
(bo
0.30
(6
H, I'L
6
5.
ZZ0
b,i
I
155-05
0.50
16
5.01
b
5 •70
28
S•0
Ilsol
1
o. 65
5.6q
20Iv
3.(
(Lto2
0.%b
I7
72b
4
5411
Wit(
V.2
NO
65.
11*
o.a5
1-1
6
3.
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)?
❑ YES Q NO
IS A TURBIDITY METER DUPLICATE REQUIRED?
❑ YES ✓❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN; WITHIN 15%? ❑ YES ❑ N
O
WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? DYES ❑ NO
IS THE LOCATION FIELD VEHICLE ACCESSIBLE? Q YES ❑ NO
DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
Petroleum
Strong
Turbid
Earthy Musty Undetermined
Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

�CAMA F,-]CCRF,-]Landfill [:]NPDES ❑ DGW❑ASW [-] LRBFJ SPECIAL STUDY
FIELD SAMPLING L ot DUKE
G ENER '
Site: A56wlk Well/SW ID: LAW-3 3 Date: 3-2/-z3
GROUNDWATER SAMPLE❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE WLO WELL DEVELOPMENT
FIELD STAFF: G7L WEATHER: QSUNNY ❑PARTLY CLOUDY ❑OVERCAST ❑RAIN FISNOW AIR TEMP: 10 °F
COMPANY: F/� DUKE ENERGY FIELD METER TYPE/ SERIAL M g151R8Z
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #: 33 M
START PURGE TIME: /Ito SAMPLE COLLECTION TIME: 1135
PUMP/TUBING INTAKE DEPTH: YO (ft) DEPTH TO WATER: 33•K7 (ft) MULT FACTOR *: 0,163 ['(radius112)2'3.14"7.48]
WELL DIAMETER: Z (in) HEIGHT OF WC: 1 53 (ft) WELL VOLUME: 1.93 (gal)
WELL DEPTH: q 5. 30 (ft) TOTAL VOLUME PURGED: 1.35 (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
i
PUMP SETTING:
P
R
Tubing/Pump /Pump Inspected I (Fs) I (sec) I (Sec) I
Good [Tubing Bad []Pump Bad ❑Changed/Cleaned 7Correct Next Event
Additional Notes:
Low Flow Sampling Stabilization Criteria
• pH f 0.1 standard unit
• Specific Conductance t 5%in pS/cm
• DO t 0.2 mg/L or 10% saturation
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
(x)
(gallons OR mL)
(x.xx)
VC)
(x)
(mg/L)
(x.xx)
(MS/cm)
(x)
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
1114
34,12
(tN
09.Zu
11
57•35
S41
9.49
-4a
13.9
111
3 bt o
q5t)
v • H o
11
3, ZL
S 13
9. 2A
Z $ w
3. 8
111w
3 • ')1
0.55
12
7. 6o
S50
6. Z.
2qN
1. 7
t1113311.
0.'7S
I2
G q0
51
. -Z3
300
Z./0
IIZ(,
3,f-),I
a•a
12
1.76
6.22
104
_o
11"
3N 11.
i• l5
12
1.51
519,
4.ZS
1 3E-
2. t
It 3
3 '1.l'1.
G -Sq
3e%
2. t:
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENTNEEDED (>10 NTUS)? ❑ YES Q NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? DYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? YES Q NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?[;] YES Q NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES R NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR F..'
H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH Minor Strong
ADDITIONAL NOTES: APPEARANCE Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

[:]CAMA F-,]CCRaLandfiill ❑NPDES ❑ DGW❑ASW [—]LRB ❑ SPECIAL STUDY.
Site: As�ct lr -
Well/SW ID: o4V - K 6
Date: 3-21-Z3
El GROUNDWATER SAMPLE [:]SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: OIL WEATHER: []SUNNY ❑ PARTLY CLOUDY ❑ OVERCAST ❑ RAIN []SNOW AIR TEMP Y 2 -F
COMPANY: ❑i DUKE ENERGY FIELD METER TYPE/ SERIAL M 11 SIRdb
❑ OTHER: TURBIDIMETER TYPE/ SERIAL M iwl
START PURGE TIME: (00% SAMPLE COLLECTION TIME: I h35
PUMP/TUBING INTAKE DEPTH: qq (ft) DEPTH TO WATER: V-13 (ft) MULT FACTOR *: 0.163 ['(radius/12)2"3.14"7.48]
WELL DIAMETER: 2-0 (in) HEIGHT OF WC: 27-52 (ft) WELL VOLUME: `(.45 (gal)
WELL DEPTH: yk 25 (ft) TOTAL VOLUME PURGED: 2•20 (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
R
D.
❑ Tubin /Pump Inspected (Psi) I (Sec) I (Sec) I Low Flow Sampling Stabilization Criteria
❑Good LjTubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event pH t 0.1 standard unit
Additional Notes: Specific Conductance t 5% in pS/cm
• DO t 0.2 mg/L or 10% saturation
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
W
(gallons OR mL)
(x.xx)
(°C)
W
(mg/L)
(x.xx)
(PS/cm)
W
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
I012
Z2c1
35u
0.35
12.
1.50
36N
4.114
2151
C 5 -Z
Lot
Z.tt.
35a
op, Ia
IZ
0.7b
2
2011
$1. N
to
2
1.05
13
0. S v
L. -zq
20v
57.3
I• `to
13
0.41Z
3140
4.V5
184
37.1
lb 7A
1.75
13
0.131
A.tS
160
26.4
t
2L.11e
31tb
2.I0
13
0.36
3°IV
6•ZG
1701
1810
0120
2Z I6
3'eso
2.45
13
0.3
3
G. Z&
t Ss2
11.0
to
Z2.t6
.550
2.P&0
1'15
0.3-
3
. G
t 5
2s•z
VLtAbt Kt -tK I U 1 Fit UALA Ur I H15 SHEET IF T HE CHART A13OVE 15 FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES © NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? ['YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES Q-NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?Q YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%0? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH i-1,
Minor Strong
ADDITIONAL NOTES: APPEARANCE Cloudy Turbid Red/Iron Film on Surface Sheen (5s Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

[—]CAMA F_JCCR Landfill E:]NPDES ❑ DGW❑ASW F_JLRB ❑ SPECIAL STUDY
DAILY CALIBRATION LOG
Site: 4t.411. t,F Date: 3-20'L3
,o& DUKE
ENERGY,
FIELD PERSONNEL: G77-
WEATHER: []SUNNY❑PARTLY CLOUDY ❑OVERCAST ❑RAIN ❑SNOW TEMPERATURE (APPROX):
INSITU SERIAL M 951 qg(- ^F
2100Q SERIAL #: SS11
Buffer
Chart
MeterPH
Within t
1050
Lot Number
Expiration
Temperature
pH
Reading
Time:
0.1 su?
(°C)
(su)
(su)
7.00 su
213013
vY-3a-�3
10,96
?,cr7
7 c Z
Cif N
10.01 su
Ze7370
06-31 -Z3
3.54
w-11
tn•Z'S
N
4.01 su
214 no
06-30-Z3
17.(0
tf.w
Y.03
N
Check of 7.00 su as Live Reading
213013
614•30-Z3
(U- 24
7.rn
7.10
N
Post Calibration- Date: t Time: toyo
Within t
0.2 su?
7.00 su
213o13
04-so-V
13.16
7vS
7•c/7
ap N
10.01 Su
Z07370
06-31-7.3
IN.vT
r1/ i2
N
4.01 su
Z14Z.Zo
06-30-Z3
11.111
qpi
Y,a
N
Specific Conductivity
Time: Iwo
Lot Number
Expiration
Buffer
Temperature (°C)
Meter
Reading (Ns)
Within t
10%?
Standard Value: 7Zo Ps
E1721 (3
0S-01.Z3
6 AV.Yt
N
Calibration Check of
227 Ns as Live Reading
L 2321 C
11 -01- 23
6. 34
Z2 7. 7
J,) N
Post Calibration- Date: 3-Z1- Z 3 Time: 1095 - --
720 Ns
r721b
5-1-23
1� S1, 1
724. v
N
ORP
Buffer
Adjusted
Meter
Time: 1105
Lot Number
Expiration
Temperature
Value
Reading
Within t
20%?
VC)
(mV)
(mV)
wZq mV
222`I
0$'3°'Z3 6.66 473 •(?(•q N
Time:
PostCalibration- Date:
42q mV
t22�1
oa ;0-23
6.66
4
'17(.1
V i
Revised 12118/2018 KKH

[—]CAMA F-,-]CCRF--]Landfill [:]NPDES ❑ DGW❑ASW ILRB _J SPECIAL STUDY,
DAILY CALIBRATION LOG
Site: Date: 34.v-Z) Field Personnel:
•f' DUKE
ENERGY.
G1Z
Barometric
Meter
Dissolved Oxygen
Temperature
Chart DO
% Saturation
Pressure
Reading
Within t 0.57
Time:
VC)
(mg/L.)(%Sat)
11rh
(mmHg)
(mg/L.)
5•�8
i13.�15
,
kuo"(.
N
Calibration Check as Live
L
Reading
5' �6
?13 • l%
i1.•?
'' 63
Ivy. 3Lt
N
Post Calibration -
Date: 3-ZI
IS•Zv
715.V'L
$N
�c'2
g5•�I�
� N
Time: 1610
Turbidity
Time: 11110
Standard (NTU)
Acceptance
Range (NTU)
Meter Reading
(NTU)
Within
10.0
± D. 5
/6 . u
�c �5%?
ci N
Post Calibration -
Date: 3-V
Time: 1O(5
10.0
+ 0. 5
10- p
(� N
Daily Turbidity Meter BLANK
DI Water (NTU)
Less than 0.10 NTU?
Date: -4w 5-Zo
NTime:
it CO
Revised 12118/2018 KKH

�CAMA �CCR Landfill �NPDES ❑ DGW❑ASW �LRB ❑SPECIAL STUDY,
DAILY CALIBRATION LOG
Site: 434e1, k I Date: 3-21-23
V
DUKE
ENERGY.
FIELD PERSONNEL: GiZ
WEATHER: []SUNNY [_]PARTLYCLOUDY ❑ OVERCAST []RAIN ❑SNOW TEMPERATURE (APPROx):
INSITU SERIAL M 9511186 "F
2100Q SERIAL #: SSM
Buffer
Chart
MeterpH
Within t
`��
Lot
Lot Number
Expiration
Temperature
pH
Reading
Time: law
su?
(°C)
(su)
(su)
7.00 su
213013
oY-3o-23
13 IG
7. oS
70'1
e) N
10.01 su
Z67370
09-31 -Z3
1 N•r/L
to. 12
10•I(,
Y) N
4.01 su
21427-o
06-30-Z3
129'q
3,4Z
dal
6# N
Check of 7.00 su as Live Reading
Z13013
oN-3o-23
13.3v
707
0 N
Post Calibration- Date: 3-Z I Time: 1gb0
Within t
0.2 su?
7.00 su
213013
04-30-Zp
IG.2o
7us
7.04
N
10.01 Su
207370
09-31-2.3
tb •Z.5
W.11
10.10
N
4.01 su
Z14Z2.o
oh-30-23
16.07-
3•1111
`i•01
N
Specific Conductivity
Buffer
Meter
Within t
Time: (#V5
Lot Number
Expiration
Temperature (°C)
Reading (ps)
10%?
Standard Value: 7Zo ps
E1721 a
oS-ol-z;
tN•22
?ZK.o
N
Calibration Check of
2ZS• 1
2Z7 ps as Live Reading
L 2321 G
11 -01 - 7-3
1 N• Ko
N
Post Calibration- Date: Time: S
7 Z 0 ps
1� 21
5 1-ti3
11.. o L
�ZO .
N
Buffer
Adjusted
Meter
ORP
Within t
Lot Number
Expiration
Temperature
Value
Reading
Time: 1105
20%?
(°C)
(mV)
(mV)
421 mV
222`l
oS-30-z.3 -66 `n 3 '-171-1 N
Time: 15 Lo
Post Calibration- Date: 3.21
NZh mV
22Z`1
0$ 30-23
1 ( &.`lo
1 151
g53.1.
QS N
Revised 12118/2018 KKH

[-]CAMA [-]CCRF�:]Landfill [-]NPDES ❑ DGW[-]ASW ILRB u SPECIAL STUDY.
DUKE
ENERGY
DAILY CALIBRATION LOG
Site: ,Q ,, Date: 3-21 Field Personnel: CIZ
Barometric
Meter%
Dissolved Oxvsaen
Temperature
Chart DO
Saturation
Pressure
Reading
Within t 0.57
Time:
VC)C)
(mg/L)
(%Sat)
I DAD
(mmHg)
(mg/L)
l5.Zo
7150-L
'.�{
ZdZ
gS 43£
N
Calibration Check as Live
15. go
715.oh
�.3
416
9S.22t
N
Reading
Post Calibration -
Date: 3-7,1
176q-
716.10
Yo
(0l.2Zt
Time: r515
N
Acceptance
Turbidity
Standard (NTU)
Range (NTU)
Meter Reading
Within t
Time:
(NTU)
5%?
(o.o
0.5
1 G.o
C-� N
Post Calibration -
Date: 3-21
1 0. v
4 0.15
%0. U
6! N
Time: 1510
Daily Turbidity Meter BLANK
DI Water (NTU)
Less than 0.10 NTU?
Date: �- Zi
N
Time: 1015
Revised 12/18/2018 KKH

Semiannual Water Quality Monitoring Report — March 2023 Sampling Event
Asheville Steam Electric Plant — CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
r
APPENDIX B
LABORATORY REPORT AND
CHAIN -OF -CUSTODY FORMS
1610
synTerra
Science & Engineering Consultants

DUE Analytical Laboratory
ENERGY
Y
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J23030368
Project Name: ASHEVILLE - ASHEVILLE STATE LF DETECTION MONITORING
Task Code: LF
Customer Name(s): Ashley Healy,B Moeller, D Obrien,J Stowe,C Zahora
Customer Address: Asheville Steam Station
200 CP and L Drive
Arden,NC 28704
Lab Contact: Peggy Kendall Phone: [phone]
Report Authorized By: Date:
(Signature)
Pegg endall
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
4/5/2023
Page 1 of 29
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions: Page 2 of 29
Sample ID
Plant/Station
Collection
Date and Time
Collected By
Sample Description
2023006822
ASHEVILLE
20-Mar-23 11:30 AM
Connor Zahora
ASV LF-SW-1
2023006823
ASHEVILLE
20-Mar-23 11:50 AM
Connor Zahora
ASV LF-SW-2
2023006824
ASHEVILLE
20-Mar-23 12:50 PM
Connor Zahora
ASV LCS-1
2023006825
ASHEVILLE
20-Mar-23 1:15 PM
Connor Zahora
ASV LF-SW-3
2023006826
ASHEVILLE
20-Mar-23 2:15 PM
Connor Zahora
ASV CB-9BR
2023006827
ASHEVILLE
20-Mar-23 3:10 PM
Connor Zahora
ASV CB-9SL
2023006828
ASHEVILLE
20-Mar-23
Connor Zahora
ASV FD-20230320-1
2023006829
ASHEVILLE
20-Mar-23 12:00 PM
Connor Zahora
ASV FB-20230320-1200
8 Total Samples

Page 3 of 29
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
d❑ Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
d❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
❑ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 4/5/2023

Certificate of Laboratory Analysis Page 4 of 29
This report shall not be reproduced, except in full.
Order # J23030368
Site: ASV LF-SW-1
Sample #:
2023006822
Collection Date: 03/20/2023 11:30 AM
Loc code: ASV LF-SW-1
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q23030304
Chloride
2.5
mg/L
0.1
0.0154
1
EPA 9056A
03/21/2023 08:18
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
03/21/2023 08:18
BGN9034
Nitrate
0.51
mg/L
0.1
0.0209
1
EPA 9056A
03/21/2023 08:18
BGN9034
Nitrate as N
0.12
mg-N/L
0.023
0.002
1
EPA 9056A
03/21/2023 08:18
BGN9034
Sulfate
51
mg/L
1
0.0428
10
EPA 9056A
03/21/2023 08:18
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q23030421
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q23030327
Zinc (Zn)
0.005
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q23030328
Barium (Ba)
0.029
mg/L
0.005
0.002
Boron (B)
0.02 J
mg/L
0.05
0.005
Calcium (Ca)
17.8
mg/L
0.05
0.012
Iron (Fe)
0.047
mg/L
0.01
0.004
Lithium (Li)
0.004 J
mg/L
0.005
0.002
Magnesium (Mg)
6.14
mg/L
0.02
0.008
Manganese (Mn)
0.003 J
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
69.6
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23030332
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.072 J
ug/L
1
0.032
Chromium (Cr)
0.206 J
ug/L
1
0.185
Copper (Cu)
0.787 U
ug/L
1
0.787
Lead (Pb)
0.078 J
ug/L
1
0.037
Nickel (Ni)
0.554 J
ug/L
1
0.256
Silver (Ag)
0.049 J
ug/L
1
0.035
1 EPA 7470A
03/28/2023 12:51
JAA5429
1 SW 6010D
03/23/2023 11:01
CELL106
1 SW 6010D
03/23/2023 12:00
CELL106
1 SW 601OD
03/23/2023 12:00
CELL106
1 SW 6010D
03/23/2023 12:00
CELL106
1 SW 6010D
03/23/2023 12:00
CELL106
1 SW 6010D
03/23/2023 12:00
CELL106
1 SW 6010D
03/23/2023 12:00
CELL106
1 SW 6010D
03/23/2023 12:00
CELL106
1 SW 601OD
03/23/2023 12:00
CELL106
1 SW 6010D
03/23/2023 12:00
CELL106
1 SW 6020B
03/23/2023 02:31
MHALL3
1 SW 6020B
03/23/2023 02:31
MHALL3
1 SW 6020B
03/23/2023 02:31
MHALL3
1 SW 6020B
03/23/2023 02:31
MHALL3
1 SW 6020B
03/23/2023 02:31
MHALL3
1 SW 6020B
03/23/2023 02:31
MHALL3
1 SW 6020B
03/23/2023 02:31
MHALL3

Certificate of Laboratory Analysis Page 5 of 29
This report shall not be reproduced, except in full.
Order # J23030368
Site: ASV LF-SW-1
Sample #:
2023006822
Collection Date: 03/20/2023 11:30 AM
Loc code: ASV LF-SW-1
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS - Q23030333
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
03/22/2023 22:01
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
03/22/2023 22:01
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
03/22/2023 22:01
MHALL3
Cadmium (Cd)
0.039 J
ug/L
1
0.032
1
SW 6020B
03/22/2023 22:01
MHALL3
Chromium (Cr)
0.417 J
ug/L
1
0.185
1
SW 6020B
03/22/2023 22:01
MHALL3
Cobalt (Co)
0.078 J
ug/L
1
0.077
1
SW 6020B
03/22/2023 22:01
MHALL3
Copper (Cu)
0.787 U
ug/L
1
0.787
1
SW 6020B
03/22/2023 22:01
MHALL3
Lead (Pb)
0.064 J
ug/L
1
0.037
1
SW 6020B
03/22/2023 22:01
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020B
03/22/2023 22:01
MHALL3
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
SW 6020B
03/22/2023 22:01
MHALL3
Selenium (Se)
0.406 J
ug/L
1
0.193
1
SW 6020B
03/22/2023 22:01
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
03/22/2023 22:01
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
03/22/2023 22:01
MHALL3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020B
03/22/2023 22:01
MHALL3
TOTAL DISSOLVED SOLIDS - Q23030341
TDS
108
mg/L
25
25
1
SM2540C
03/22/202310:34
EBATIAN

Certificate of Laboratory Analysis Page 6 of 29
This report shall not be reproduced, except in full.
Order # J23030368
Site: ASV LF-SW-2 Sample #: 2023006823
Collection Date: 03/20/2023 11:50 AM Loc code: ASV LF-SW-2 Matrix: GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
INORGANIC IONS BY IC - Q23030304
Chloride
8.1
mg/L
0.1
0.0154
Fluoride
0.0479 U
mg/L
0.1
0.0479
Nitrate
0.69
mg/L
0.1
0.0209
Nitrate as N
0.15
mg-N/L
0.023
0.002
Sulfate
11
mg/L
0.5
0.0428
MERCURY (COLD VAPOR) IN WATER - Q23030421
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q23030327
Zinc (Zn)
0.005 J
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q23030328
Barium (Ba)
0.018
mg/L
0.005
0.002
Boron (B)
0.021 J
mg/L
0.05
0.005
Calcium (Ca)
7.12
mg/L
0.05
0.012
Iron (Fe)
0.212
mg/L
0.01
0.004
Lithium (Li)
0.003 J
mg/L
0.005
0.002
Magnesium (Mg)
2.75
mg/L
0.02
0.008
Manganese (Mn)
0.231
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
29.1
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23030332
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.142 J
ug/L
1
0.032
Chromium (Cr)
0.185 U
ug/L
1
0.185
Copper (Cu)
0.787 U
ug/L
1
0.787
Lead (Pb)
0.037 U
ug/L
1
0.037
Nickel (Ni)
0.472 J
ug/L
1
0.256
Silver (Ag)
0.035 U
ug/L
1
0.035
DF
Method
Analysis Date/Time
Analyst
1
EPA 9056A
03/21/2023 09:40
BGN9034
1
EPA 9056A
03/21/2023 09:40
BGN9034
1
EPA 9056A
03/21/2023 09:40
BGN9034
1
EPA 9056A
03/21/2023 09:40
BGN9034
5
EPA 9056A
03/21/2023 09:40
BGN9034
1
EPA 7470A
03/28/2023 12:53
JAA5429
1
SW 6010D
03/23/2023 10:47
CELL106
1
SW 6010D
03/23/2023 11:46
CELL106
1
SW 601OD
03/23/2023 11:46
CELL106
1
SW 6010D
03/23/2023 11:46
CELL106
1
SW 6010D
03/23/2023 11:46
CELL106
1
SW 6010D
03/23/2023 11:46
CELL106
1
SW 6010D
03/23/2023 11:46
CELL106
1
SW 6010D
03/23/2023 11:46
CELL106
1
SW 601OD
03/23/2023 11:46
CELL106
1
SW 6010D
03/23/2023 11:46
CELL106
1
SW 6020B
03/23/2023 02:57
MHALL3
1
SW 6020B
03/23/2023 02:57
MHALL3
1
SW 6020B
03/23/2023 02:57
MHALL3
1
SW 6020B
03/23/2023 02:57
MHALL3
1
SW 6020B
03/23/2023 02:57
MHALL3
1
SW 6020B
03/23/2023 02:57
MHALL3
1
SW 6020B
03/23/2023 02:57
MHALL3

Certificate of Laboratory Analysis Page 7 of 29
This report shall not be reproduced, except in full.
Order # J23030368
Site: ASV LF-SW-2
Sample #:
2023006823
Collection Date: 03/20/2023 11:50 AM
Loc code: ASV LF-SW-2
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS - Q23030333
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
03/22/2023 22:44
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
03/22/2023 22:44
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
03/22/2023 22:44
MHALL3
Cadmium (Cd)
0.127 J
ug/L
1
0.032
1
SW 6020B
03/22/2023 22:44
MHALL3
Chromium (Cr)
0.206 J
ug/L
1
0.185
1
SW 6020B
03/22/2023 22:44
MHALL3
Cobalt (Co)
0.308 J
ug/L
1
0.077
1
SW 6020B
03/22/2023 22:44
MHALL3
Copper (Cu)
0.787 U
ug/L
1
0.787
1
SW 6020B
03/22/2023 22:44
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
03/22/2023 22:44
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020B
03/22/2023 22:44
MHALL3
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
SW 6020B
03/22/2023 22:44
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
03/22/2023 22:44
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
03/22/2023 22:44
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
03/22/2023 22:44
MHALL3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020B
03/22/2023 22:44
MHALL3
TOTAL DISSOLVED SOLIDS - Q23030341
TDS
57.0
mg/L
25
25
1
SM2540C
03/22/202310:34
EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23030368
Site: ASV LCS-1
Collection Date: 03/20/2023 12:50 PM Loc code: ASV LCS-1
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23030304
Sample #: 2023006824
Matrix: GW RCRA
Page 8 of 29
Method Analysis Date/Time Analyst
Chloride
36
mg/L
2
0.0154
20
EPA 9056A
03/21/2023 10:12
BGN9034
Fluoride
1.1 J
mg/L
2
0.0479
20
EPA 9056A
03/21/2023 10:12
BGN9034
Nitrate
1 J
mg/L
2
0.0209
20
EPA 9056A
03/21/2023 10:12
BGN9034
Nitrate as N
0.23 J
mg-N/L
0.46
0.002
20
EPA 9056A
03/21/2023 10:12
BGN9034
Sulfate
670
mg/L
20
0.0428
200
EPA 9056A
03/21/2023 10:12
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q23030421
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
03/28/2023 12:55
JAA5429
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q23030327
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
03/23/2023 11:06
CELL106
TOTAL RECOVERABLE METALS BY ICP - Q23030328
Barium (Ba)
0.036
mg/L
0.005
0.002
1
SW 6010D
03/23/2023 12:05
CELL106
Boron (B)
9.63
mg/L
0.05
0.005
1
SW 601OD
03/23/2023 12:05
CELL106
Calcium (Ca)
322
mg/L
0.5
0.012
10
SW 6010D
03/23/2023 12:05
CELL106
Iron (Fe)
0.385
mg/L
0.01
0.004
1
SW 6010D
03/23/2023 12:05
CELL106
Lithium (Li)
0.078
mg/L
0.005
0.002
1
SW 6010D
03/23/2023 12:05
CELL106
Magnesium (Mg)
67.5
mg/L
0.02
0.008
1
SW 6010D
03/23/2023 12:05
CELL106
Manganese (Mn)
0.246
mg/L
0.005
0.001
1
SW 6010D
03/23/2023 12:05
CELL106
Total Hardness (Ca and Mg)
1080
mg/L
0.19
1
SW 601OD
03/23/2023 12:05
CELL106
(CaCO3)
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
03/23/2023 12:05
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23030332
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
03/23/2023 03:06
MHALL3
Cadmium (Cd)
0.047 J
ug/L
1
0.032
1
SW 6020B
03/23/2023 03:06
MHALL3
Chromium (Cr)
0.416 J
ug/L
1
0.185
1
SW 6020B
03/23/2023 03:06
MHALL3
Copper (Cu)
0.861 J
ug/L
1
0.787
1
SW 6020B
03/23/2023 03:06
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
03/23/2023 03:06
MHALL3
Nickel (Ni)
2.69
ug/L
1
0.256
1
SW 6020B
03/23/2023 03:06
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
03/23/2023 03:06
MHALL3

Certificate of Laboratory Analysis Page 9 of 29
This report shall not be reproduced, except in full.
Order # J23030368
Site: ASV LCS-1
Sample #:
2023006824
Collection Date: 03/20/2023 12:50 PM
Loc code: ASV LCS-1
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS - Q23030333
Antimony (Sb)
0.965 J
ug/L
1
0.104
1
SW 6020B
03/22/2023 22:52
MHALL3
Arsenic (As)
3.72
ug/L
1
0.111
1
SW 6020B
03/22/2023 22:52
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
03/22/2023 22:52
MHALL3
Cadmium (Cd)
0.046 J
ug/L
1
0.032
1
SW 6020B
03/22/2023 22:52
MHALL3
Chromium (Cr)
0.881 J
ug/L
1
0.185
1
SW 6020B
03/22/2023 22:52
MHALL3
Cobalt (Co)
0.234 J
ug/L
1
0.077
1
SW 6020B
03/22/2023 22:52
MHALL3
Copper (Cu)
1.14
ug/L
1
0.787
1
SW 6020B
03/22/2023 22:52
MHALL3
Lead (Pb)
0.289 J
ug/L
1
0.037
1
SW 6020B
03/22/2023 22:52
MHALL3
Molybdenum (Mo)
456
ug/L
1
0.18
1
SW 6020B
03/22/2023 22:52
MHALL3
Nickel (Ni)
3.07
ug/L
1
0.256
1
SW 6020B
03/22/2023 22:52
MHALL3
Selenium (Se)
35.1
ug/L
1
0.193
1
SW 6020B
03/22/2023 22:52
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
03/22/2023 22:52
MHALL3
Thallium (TI) Low Level
0.096 J
ug/L
0.2
0.041
1
SW 6020B
03/22/2023 22:52
MHALL3
Vanadium (V) Low Level
2.94
ug/L
0.3
0.114
1
SW 6020B
03/22/2023 22:52
MHALL3
TOTAL DISSOLVED SOLIDS - Q23030341
TDS
1560
mg/L
25
25
1
SM2540C
03/22/202310:34
EBATIAN

Certificate of Laboratory Analysis Page 10 of 29
This report shall not be reproduced, except in full.
Order # J23030368
Site: ASV LF-SW-3 Sample #: 2023006825
Collection Date: 03/20/2023 01:15 PM Loc code: ASV LF-SW-3 Matrix: GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
INORGANIC IONS BY IC - Q23030304
Chloride
9.8
mg/L
0.1
0.0154
Fluoride
0.0479 U
mg/L
0.1
0.0479
Nitrate
0.40
mg/L
0.1
0.0209
Nitrate as N
0.09
mg-N/L
0.023
0.002
Sulfate
4.1
mg/L
0.1
0.0428
MERCURY (COLD VAPOR) IN WATER - Q23030421
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q23030327
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q23030328
Barium (Ba)
0.015
mg/L
0.005
0.002
Boron (B)
0.023 J
mg/L
0.05
0.005
Calcium (Ca)
4.83
mg/L
0.05
0.012
Iron (Fe)
0.054
mg/L
0.01
0.004
Lithium (Li)
0.003 J
mg/L
0.005
0.002
Magnesium (Mg)
1.79
mg/L
0.02
0.008
Manganese (Mn)
0.007
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
19.4
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23030332
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.032 U
ug/L
1
0.032
Chromium (Cr)
0.185 U
ug/L
1
0.185
Copper (Cu)
0.787 U
ug/L
1
0.787
Lead (Pb)
0.037 U
ug/L
1
0.037
Nickel (Ni)
0.337 J
ug/L
1
0.256
Silver (Ag)
0.035 U
ug/L
1
0.035
DF
Method
Analysis Date/Time
Analyst
1
EPA 9056A
03/21/2023 09:56
BGN9034
1
EPA 9056A
03/21/2023 09:56
BGN9034
1
EPA 9056A
03/21/2023 09:56
BGN9034
1
EPA 9056A
03/21/2023 09:56
BGN9034
1
EPA 9056A
03/21/2023 09:56
BGN9034
1
EPA 7470A
03/28/2023 12:58
JAA5429
1
SW 6010D
03/23/2023 11:11
CELL106
1
SW 6010D
03/23/2023 12:09
CELL106
1
SW 601OD
03/23/2023 12:09
CELL106
1
SW 6010D
03/23/2023 12:09
CELL106
1
SW 6010D
03/23/2023 12:09
CELL106
1
SW 6010D
03/23/2023 12:09
CELL106
1
SW 6010D
03/23/2023 12:09
CELL106
1
SW 6010D
03/23/2023 12:09
CELL106
1
SW 601OD
03/23/2023 12:09
CELL106
1
SW 6010D
03/23/2023 12:09
CELL106
1
SW 6020B
03/23/2023 03:14
MHALL3
1
SW 6020B
03/23/2023 03:14
MHALL3
1
SW 6020B
03/23/2023 03:14
MHALL3
1
SW 6020B
03/23/2023 03:14
MHALL3
1
SW 6020B
03/23/2023 03:14
MHALL3
1
SW 6020B
03/23/2023 03:14
MHALL3
1
SW 6020B
03/23/2023 03:14
MHALL3

Certificate of Laboratory Analysis Page 11 of 29
This report shall not be reproduced, except in full.
Order # J23030368
Site: ASV LF-SW-3
Sample #:
2023006825
Collection Date: 03/20/2023 01:15 PM
Loc code: ASV LF-SW-3
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS - Q23030333
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
03/22/2023 23:00
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
03/22/2023 23:00
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
03/22/2023 23:00
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
03/22/2023 23:00
MHALL3
Chromium (Cr)
0.217 J
ug/L
1
0.185
1
SW 6020B
03/22/2023 23:00
MHALL3
Cobalt (Co)
0.077 U
ug/L
1
0.077
1
SW 6020B
03/22/2023 23:00
MHALL3
Copper (Cu)
0.787 U
ug/L
1
0.787
1
SW 6020B
03/22/2023 23:00
MHALL3
Lead (Pb)
0.064 J
ug/L
1
0.037
1
SW 6020B
03/22/2023 23:00
MHALL3
Molybdenum (Mo)
1.77
ug/L
1
0.18
1
SW 6020B
03/22/2023 23:00
MHALL3
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
SW 6020B
03/22/2023 23:00
MHALL3
Selenium (Se)
0.212 J
ug/L
1
0.193
1
SW 6020B
03/22/2023 23:00
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
03/22/2023 23:00
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
03/22/2023 23:00
MHALL3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020B
03/22/2023 23:00
MHALL3
TOTAL DISSOLVED SOLIDS - Q23030341
TDS
48.0
mg/L
25
25
1
SM2540C
03/22/202310:34
EBATIAN

Certificate of Laboratory Analysis Page 12 of 29
This report shall not be reproduced, except in full.
Order # J23030368
Site: ASV CB-9BR Sample #: 2023006826
Collection Date: 03/20/2023 02:15 PM Loc code: ASV CB-9BR Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23030304
Chloride 7.6 mg/L
Fluoride 0.05 J mg/L
Nitrate 0.23 mg/L
Nitrate as N 0.05 mg-N/L
Sulfate 1.4 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23030421
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23030328
Barium (Ba)
0.028
mg/L
Boron (B)
0.006 J
mg/L
Calcium (Ca)
10.3
mg/L
Iron (Fe)
0.098
mg/L
Lithium (Li)
0.010
mg/L
Magnesium (Mg)
3.36
mg/L
Manganese (Mn)
0.046
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23030333
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.246 J
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.308 J
ug/L
Nickel (Ni)
0.491 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.093 J
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.114 U
ug/L
TOTAL DISSOLVED SOLIDS
- Q23030341
TDS 79.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
03/21/2023 09:07
BGN9034
0.1
0.0479
1
EPA 9056A
03/21/2023 09:07
BGN9034
0.1
0.0209
1
EPA 9056A
03/21/2023 09:07
BGN9034
0.023
0.002
1
EPA 9056A
03/21/2023 09:07
BGN9034
0.1
0.0428
1
EPA 9056A
03/21/2023 09:07
BGN9034
0.05
0.01
1
EPA 7470A
03/28/2023 13:00
JAA5429
0.005
0.002
1
SW 6010D
03/23/2023 12:14
CELL106
0.05
0.005
1
SW 6010D
03/23/2023 12:14
CELL106
0.05
0.012
1
SW 6010D
03/23/2023 12:14
CELL106
0.01
0.004
1
SW 6010D
03/23/2023 12:14
CELL106
0.005
0.002
1
SW 6010D
03/23/2023 12:14
CELL106
0.02
0.008
1
SW 6010D
03/23/2023 12:14
CELL106
0.005
0.001
1
SW 6010D
03/23/2023 12:14
CELL106
0.005
0.004
1
SW 601OD
03/23/2023 12:14
CELL106
1
0.104
1
SW 6020B
03/22/2023 23:09
MHALL3
1
0.111
1
SW 6020B
03/22/2023 23:09
MHALL3
1
0.249
1
SW 6020B
03/22/2023 23:09
MHALL3
1
0.032
1
SW 6020B
03/22/2023 23:09
MHALL3
1
0.185
1
SW 6020B
03/22/2023 23:09
MHALL3
1
0.077
1
SW 6020B
03/22/2023 23:09
MHALL3
1
0.787
1
SW 6020B
03/22/2023 23:09
MHALL3
1
0.037
1
SW 6020B
03/22/2023 23:09
MHALL3
1
0.18
1
SW 6020B
03/22/2023 23:09
MHALL3
1
0.256
1
SW 6020B
03/22/2023 23:09
MHALL3
1
0.193
1
SW 6020B
03/22/2023 23:09
MHALL3
1
0.035
1
SW 6020B
03/22/2023 23:09
MHALL3
0.2
0.041
1
SW 6020B
03/22/2023 23:09
MHALL3
0.3
0.114
1
SW 6020B
03/22/2023 23:09
MHALL3
25
25
1
SM2540C
03/22/202310:34
EBATIAN

Certificate of Laboratory Analysis Page 13 of 29
This report shall not be reproduced, except in full.
Order # J23030368
Site: ASV CB-9SL Sample #: 2023006827
Collection Date: 03/20/2023 03:10 PM Loc code: ASV CB-9SL Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23030304
Chloride 7.7 mg/L
Fluoride 0.05 J mg/L
Nitrate 1.1 mg/L
Nitrate as N 0.24 mg-N/L
Sulfate 0.25 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23030421
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23030328
Barium (Ba)
0.046
mg/L
Boron (B)
0.005 J
mg/L
Calcium (Ca)
3.71
mg/L
Iron (Fe)
0.021
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
2.11
mg/L
Manganese (Mn)
0.001 J
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23030333
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.279 J
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.714 J
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.056 J
ug/L
Molybdenum (Mo)
0.214 J
ug/L
Nickel (Ni)
0.469 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.682 J
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.114 U
ug/L
TOTAL DISSOLVED SOLIDS
- Q23030341
TDS 40.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
03/21/2023 09:23
BGN9034
0.1
0.0479
1
EPA 9056A
03/21/2023 09:23
BGN9034
0.1
0.0209
1
EPA 9056A
03/21/2023 09:23
BGN9034
0.023
0.002
1
EPA 9056A
03/21/2023 09:23
BGN9034
0.1
0.0428
1
EPA 9056A
03/21/2023 09:23
BGN9034
0.05
0.01
1
EPA 7470A
03/28/2023 13:02
JAA5429
0.005
0.002
1
SW 6010D
03/23/2023 12:19
CELL106
0.05
0.005
1
SW 6010D
03/23/2023 12:19
CELL106
0.05
0.012
1
SW 6010D
03/23/2023 12:19
CELL106
0.01
0.004
1
SW 6010D
03/23/2023 12:19
CELL106
0.005
0.002
1
SW 6010D
03/23/2023 12:19
CELL106
0.02
0.008
1
SW 6010D
03/23/2023 12:19
CELL106
0.005
0.001
1
SW 6010D
03/23/2023 12:19
CELL106
0.005
0.004
1
SW 601OD
03/23/2023 12:19
CELL106
1
0.104
1
SW 6020B
03/22/2023 23:17
MHALL3
1
0.111
1
SW 6020B
03/22/2023 23:17
MHALL3
1
0.249
1
SW 6020B
03/22/2023 23:17
MHALL3
1
0.032
1
SW 6020B
03/22/2023 23:17
MHALL3
1
0.185
1
SW 6020B
03/22/2023 23:17
MHALL3
1
0.077
1
SW 6020B
03/22/2023 23:17
MHALL3
1
0.787
1
SW 6020B
03/22/2023 23:17
MHALL3
1
0.037
1
SW 6020B
03/22/2023 23:17
MHALL3
1
0.18
1
SW 6020B
03/22/2023 23:17
MHALL3
1
0.256
1
SW 6020B
03/22/2023 23:17
MHALL3
1
0.193
1
SW 6020B
03/22/2023 23:17
MHALL3
1
0.035
1
SW 6020B
03/22/2023 23:17
MHALL3
0.2
0.041
1
SW 6020B
03/22/2023 23:17
MHALL3
0.3
0.114
1
SW 6020B
03/22/2023 23:17
MHALL3
25
25
1
SM2540C
03/22/202310:35
EBATIAN

Certificate of Laboratory Analysis Page 14 of 29
This report shall not be reproduced, except in full.
Order # J23030368
Site: ASV_FD-20230320-1
Duplicate
Sample #:
2023006828
Collection Date: 03/20/2023
Loc code: ASV FD
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q23030304
Chloride
36
mg/L
2
0.0154
20
EPA 9056A
03/21/2023 07:47
BGN9034
Fluoride
1 J
mg/L
2
0.0479
20
EPA 9056A
03/21/2023 07:47
BGN9034
Nitrate
0.96 J
mg/L
2
0.0209
20
EPA 9056A
03/21/2023 07:47
BGN9034
Nitrate as N
0.22 J
mg-N/L
0.46
0.002
20
EPA 9056A
03/21/2023 07:47
BGN9034
Sulfate
660
mg/L
20
0.0428
200
EPA 9056A
03/21/2023 07:47
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q23030421
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q23030327
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q23030328
Barium (Ba)
0.048
mg/L
0.005
0.002
Boron (B)
9.81
mg/L
0.05
0.005
Calcium (Ca)
319
mg/L
0.5
0.012
Iron (Fe)
1.16
mg/L
0.01
0.004
Lithium (Li)
0.079
mg/L
0.005
0.002
Magnesium (Mg)
68.6
mg/L
0.02
0.008
Manganese (Mn)
0.351
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23030332
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.052 J
ug/L
1
0.032
Chromium (Cr)
0.403 J
ug/L
1
0.185
Copper (Cu)
1.42
ug/L
1
0.787
Lead (Pb)
0.037 U
ug/L
1
0.037
Nickel (Ni)
2.98
ug/L
1
0.256
Silver (Ag)
0.035 U
ug/L
1
0.035
1 EPA 7470A
03/28/2023 13:11
JAA5429
1 SW 6010D
03/23/2023 11:15
CELL106
1 SW 6010D
03/23/2023 12:23
CELL106
1 SW 601OD
03/23/2023 12:23
CELL106
10 SW 6010D
03/23/2023 12:23
CELL106
1 SW 6010D
03/23/2023 12:23
CELL106
1 SW 6010D
03/23/2023 12:23
CELL106
1 SW 6010D
03/23/2023 12:23
CELL106
1 SW 6010D
03/23/2023 12:23
CELL106
1 SW 601OD
03/23/2023 12:23
CELL106
1 SW 6020B
03/23/2023 03:22
MHALL3
1 SW 6020B
03/23/2023 03:22
MHALL3
1 SW 6020B
03/23/2023 03:22
MHALL3
1 SW 6020B
03/23/2023 03:22
MHALL3
1 SW 6020B
03/23/2023 03:22
MHALL3
1 SW 6020B
03/23/2023 03:22
MHALL3
1 SW 6020B
03/23/2023 03:22
MHALL3

Certificate of Laboratory Analysis Page 15 of 29
This report shall not be reproduced, except in full.
Order # J23030368
Site: ASV_FD-20230320-1 Duplicate
Sample #:
2023006828
Collection Date: 03/20/2023
Loc code: ASV FD
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS - Q23030333
Antimony (Sb)
0.89 J
ug/L
1
0.104
1
SW 6020B
03/22/2023 23:26
MHALL3
Arsenic (As)
4.78
ug/L
1
0.111
1
SW 6020B
03/22/2023 23:26
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
03/22/2023 23:26
MHALL3
Cadmium (Cd)
0.058 J
ug/L
1
0.032
1
SW 6020B
03/22/2023 23:26
MHALL3
Chromium (Cr)
1.62
ug/L
1
0.185
1
SW 6020B
03/22/2023 23:26
MHALL3
Cobalt (Co)
0.689 J
ug/L
1
0.077
1
SW 6020B
03/22/2023 23:26
MHALL3
Copper (Cu)
2.22
ug/L
1
0.787
1
SW 6020B
03/22/2023 23:26
MHALL3
Lead (Pb)
0.914 J
ug/L
1
0.037
1
SW 6020B
03/22/2023 23:26
MHALL3
Molybdenum (Mo)
458
ug/L
1
0.18
1
SW 6020B
03/22/2023 23:26
MHALL3
Nickel (Ni)
3.76
ug/L
1
0.256
1
SW 6020B
03/22/2023 23:26
MHALL3
Selenium (Se)
40.3
ug/L
1
0.193
1
SW 6020B
03/22/2023 23:26
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
03/22/2023 23:26
MHALL3
Thallium (TI) Low Level
0.105 J
ug/L
0.2
0.041
1
SW 6020B
03/22/2023 23:26
MHALL3
Vanadium (V) Low Level
4.39
ug/L
0.3
0.114
1
SW 6020B
03/22/2023 23:26
MHALL3
TOTAL DISSOLVED SOLIDS - Q23030341
TDS
1570
mg/L
25
25
1
SM2540C
03/22/202310:35
EBATIAN

Certificate of Laboratory Analysis Page 16 of 29
This report shall not be reproduced, except in full.
Order # J23030368
Site: ASV FB-20230320-1200 Field Blank Sample #: 2023006829
Collection Date: 03/20/2023 12:00 PM Loc code: ASV QA Matrix: GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
INORGANIC IONS BY IC - Q23030304
Chloride
0.0154 U
mg/L
0.1
0.0154
Fluoride
0.0479 U
mg/L
0.1
0.0479
Nitrate
0.0209 U
mg/L
0.1
0.0209
Nitrate as N
0.002 U
mg-N/L
0.023
0.002
Sulfate
0.0428 U
mg/L
0.1
0.0428
MERCURY (COLD VAPOR) IN WATER - Q23030421
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q23030327
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q23030328
Barium (Ba)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.005 J
mg/L
0.05
0.005
Calcium (Ca)
0.034 J
mg/L
0.05
0.012
Iron (Fe)
0.004 U
mg/L
0.01
0.004
Lithium (Li)
0.002 U
mg/L
0.005
0.002
Magnesium (Mg)
0.008 U
mg/L
0.02
0.008
Manganese (Mn)
0.001 U
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23030332
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.032 U
ug/L
1
0.032
Chromium (Cr)
0.185 U
ug/L
1
0.185
Copper (Cu)
0.787 U
ug/L
1
0.787
Lead (Pb)
0.037 U
ug/L
1
0.037
Nickel (Ni)
0.256 U
ug/L
1
0.256
Silver (Ag)
0.035 U
ug/L
1
0.035
DF
Method
Analysis Date/Time
Analyst
1
EPA 9056A
03/21/2023 07:30
BGN9034
1
EPA 9056A
03/21/2023 07:30
BGN9034
1
EPA 9056A
03/21/2023 07:30
BGN9034
1
EPA 9056A
03/21/2023 07:30
BGN9034
1
EPA 9056A
03/21/2023 07:30
BGN9034
1
EPA 7470A
03/28/2023 13:05
JAA5429
1
SW 6010D
03/23/2023 11:20
CELL106
1
SW 6010D
03/23/2023 12:28
CELL106
1
SW 601OD
03/23/2023 12:28
CELL106
1
SW 6010D
03/23/2023 12:28
CELL106
1
SW 6010D
03/23/2023 12:28
CELL106
1
SW 6010D
03/23/2023 12:28
CELL106
1
SW 6010D
03/23/2023 12:28
CELL106
1
SW 6010D
03/23/2023 12:28
CELL106
1
SW 601OD
03/23/2023 12:28
CELL106
1
SW 6020B
03/23/2023 03:31
MHALL3
1
SW 6020B
03/23/2023 03:31
MHALL3
1
SW 6020B
03/23/2023 03:31
MHALL3
1
SW 6020B
03/23/2023 03:31
MHALL3
1
SW 6020B
03/23/2023 03:31
MHALL3
1
SW 6020B
03/23/2023 03:31
MHALL3
1
SW 6020B
03/23/2023 03:31
MHALL3

Certificate of Laboratory Analysis Page 17 of 29
This report shall not be reproduced, except in full.
Order # J23030368
Site: ASV FB-20230320-1200
Field Blank
Sample #:
2023006829
Collection Date: 03/20/2023 12:00 PM
Loc code: ASV QA
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS - Q23030333
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
03/22/2023 23:34
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
03/22/2023 23:34
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
03/22/2023 23:34
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
03/22/2023 23:34
MHALL3
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
SW 6020B
03/22/2023 23:34
MHALL3
Cobalt (Co)
0.077 U
ug/L
1
0.077
1
SW 6020B
03/22/2023 23:34
MHALL3
Copper (Cu)
0.787 U
ug/L
1
0.787
1
SW 6020B
03/22/2023 23:34
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
03/22/2023 23:34
MHALL3
Molybdenum (Mo)
0.294 J
ug/L
1
0.18
1
SW 6020B
03/22/2023 23:34
MHALL3
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
SW 6020B
03/22/2023 23:34
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
03/22/2023 23:34
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
03/22/2023 23:34
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
03/22/2023 23:34
MHALL3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020B
03/22/2023 23:34
MHALL3
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.

Certificate of Laboratory Analysis Page 18 of 29
This report shall not be reproduced, except in full.
Order # J23030368
Level II QC Summary
Q23030304 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Fluoride
0
0
mg/L
1
0.0479
0.1
< MDL
Nitrate
0
0
mg/L
1
0.0209
0.1
< MDL
Sulfate
0.002
0.002
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
5.16
5.16
mg/L
1
0.0154
5
103
80
120
Fluoride
4.95
4.95
mg/L
1
0.0479
5
98.9
80
120
Nitrate
5.24
5.24
mg/L
1
0.0209
5
105
80
120
Sulfate
5.23
5.23
mg/L
1
0.0428
5
105
80
120
MS # 1
Parent Sample:
J23030368 -- 2023006822
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Qualifier
Chloride
7.3
7.3
mg/L
1
0.0154
5
95.2
80
120
Fluoride
4.73
4.73
mg/L
1
0.0479
5
94.2
80
120
Nitrate
5.35
5.35
mg/L
1
0.0209
5
96.8
80
120
Sulfate
5.5
55
mg/L
10
0.0428
5
85.2
80
120
MSD # 1
Parent Sample:
J23030368 -- 2023006822
Parameter
Measured
Final
Units
Dil
MDL
Sake
% Recovery
LCL
UCL
RPD
Qualifier
Chloride
7.23
7.23
mg/L
1
0.0154
5
93.6
80
120
1.63
Fluoride
4.67
4.67
mg/L
1
0.0479
5
92.9
80
120
1.37
Nitrate
5.27
5.27
mg/L
1
0.0209
5
95.1
80
120
1.69
Sulfate
5.49
54.9
mg/L
10
0.0428
5
82.6
80
120
3.1

Certificate of Laboratory Analysis Page 19 of 29
This report shall not be reproduced, except in full.
Order # J23030368
Level II QC Summary
Q23030421 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.001
0
ug/L
1
0.01
0.05
< MDL
Blank # 2
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.001
-0.001
ug/L
1
0.01
0.05
< MDL
Blank # 3
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.008
-0.001
ug/L
1
0.01
0.05
< MDL
Blank # 4
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.01
0.008
ug/L
1
0.01
0.05
< MDL
Blank # 5
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.01
0.01
ug/L
1
0.01
0.05
= MDL
Blank # 6
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.003
0.01
ug/L
1
0.01
0.05
= MDL
Blank # 7
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.004
0.003
ug/L
1
0.01
0.05
< MDL
Blank # 8
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.004
0.004
ug/L
1
0.01
0.05
< MDL
Blank # 9
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.004
ug/L
1
0.01
0.05
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL Qualifier
Mercury (Hg)
1.8
1.8
ug/L
1
0.01
2
90.3
85
115
LCS # 2
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL Qualifier
Mercury (Hg)
1.75
1.75
ug/L
1
0.01
2
87.3
85
115

Certificate of Laboratory Analysis Page 20 of 29
This report shall not be reproduced, except in full.
Order # J23030368
Level II QC Summary
Q23030421 HG 7470 MERCURY (COLD VAPOR) IN WATER
LCS # 3
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.74
1.74
ug/L
1
0.01
2
87
85 115
LCS # 4
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.75
1.75
ug/L
1
0.01
2
87.5
85 115
MS # 1
Parent Sample:
J23030269 -- 2023006222
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.995
0.995
ug/L
1
0.01
1
99.5
75 125
MSD # 1
Parent Sample:
J23030269 -- 2023006222
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1
1
ug/L
1
0.01
1
100
75 125 0.9
MS # 2
Parent Sample:
J23030269 -- 2023006232
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.98
0.98
ug/L
1
0.01
1
98
75 125
MSD # 2
Parent Sample:
J23030269 -- 2023006232
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1
1
ug/L
1
0.01
1
100
75 125 2.42
MS # 3
Parent Sample:
J23030297 -- 2023006393
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.954
0.954
ug/L
1
0.01
1
95.4
75 125
MSD # 3
Parent Sample:
J23030297 -- 2023006393
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.962
0.962
ug/L
1
0.01
1
96.2
75 125 0.835
MS # 4
Parent Sample:
J23030297 -- 2023006403
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.981
0.981
ug/L
1
0.01
1
98.1
75 125
MSD # 4
Parent Sample:
J23030297 -- 2023006403
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1
1
ug/L
1
0.01
1
100
75 125 2.02
MS # 5
Parent Sample:
J23030297 -- 2023006413
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.719
0.719
ug/L
1
0.01
1
71.9
75 125
M

Certificate of Laboratory Analysis Page 21 of 29
This report shall not be reproduced, except in full.
Order # J23030368
Level II QC Summary
Q23030421
HG 7470
MERCURY (COLD VAPOR) IN WATER
MSD # 5
Parent Sample:
J23030297 -- 2023006413
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.715
0.715
ug/L
1
0.01
1
71.5
75 125 0.558
M
MS # 6
Parent Sample:
J23030368 -- 2023006828
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.838
0.838
ug/L
1
0.01
1
83.8
75 125
MSD # 6
Parent Sample:
J23030368 -- 2023006828
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.84
0.84
ug/L
1
0.01
1
84
75 125 0.238
MS # 7
Parent Sample:
J23030374 -- 2023006868
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.977
0.977
ug/L
1
0.01
1
97.7
75 125
MSD # 7
Parent Sample:
J23030374 -- 2023006868
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.959
0.959
ug/L
1
0.01
1
95.9
75 125 1.86
MS # 8
Parent Sample:
J23030392 -- 2023006944
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.874
0.874
ug/L
1
0.01
1
87.4
75 125
MSD # 8
Parent Sample:
J23030392 -- 2023006944
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.862
0.862
ug/L
1
0.01
1
86.2
75 125 1.38

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23030368
Level II QC Summary
Q23030327 ICP_DIS_TRM TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
Blank # 1
Page 22 of 29
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Zinc (Zn)
0.000817
0.000817
mg/L
1
0.004
0.005
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Zinc (Zn)
5.25
5.25
mg/L
1
0.004
5
105
80
120
MS # 1
Parent Sample:
J23030368 -- 2023006823
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Zinc (Zn)
5.23
5.23
mg/L
1
0.004
5
105
70
130
MSD # 1
Parent Sample:
J23030368 -- 2023006823
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Zinc (Zn)
5.21
5.21
mg/L
1
0.004
5
104
70
130 0.479
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23030368
Level II QC Summary
Q23030328 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
0.000096
0.000096
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.00254
0.00254
mg/L
1
0.005
0.05
< MDL
Calcium (Ca)
0.0203
0.0203
mg/L
1
0.012
0.05
> MDL
Iron (Fe)
0.00236
0.00236
mg/L
1
0.004
0.01
< MDL
Lithium (Li)
0.000779
0.000779
mg/L
1
0.002
0.005
< MDL
Magnesium (Mg)
0.00205
0.00205
mg/L
1
0.008
0.02
< MDL
Manganese (Mn)
-0.00043
-0.00043
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
0.000425
0.000425
mg/L
1
0.004
0.005
< MDL
LCS # 1
Page 23 of 29
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5.27
5.27
mg/L
1
0.002
5
105
80
120
Boron (B)
4.98
4.98
mg/L
1
0.005
5
99.5
80
120
Calcium (Ca)
4.93
4.93
mg/L
1
0.012
5
98.6
80
120
Iron (Fe)
5.11
5.11
mg/L
1
0.004
5
102
80
120
Lithium (Li)
4.97
4.97
mg/L
1
0.002
5
99.4
80
120
Magnesium (Mg)
5.05
5.05
mg/L
1
0.008
5
101
80
120
Manganese (Mn)
4.92
4.92
mg/L
1
0.001
5
98.4
80
120
Zinc (Zn)
5.09
5.09
mg/L
1
0.004
5
102
80
120
MS # 1
Parent Sample:
J23030368
-- 2023006823
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5.29
5.29
mg/L
1
0.002
5
105
75
125
Boron (B)
4.77
4.77
mg/L
1
0.005
5
95.1
75
125
Calcium (Ca)
12.1
12.1
mg/L
1
0.012
5
100
75
125
Iron (Fe)
5.31
5.31
mg/L
1
0.004
5
102
75
125
Lithium (Li)
5
5
mg/L
1
0.002
5
99.9
75
125
Magnesium (Mg)
7.61
7.61
mg/L
1
0.008
5
97.2
75
125
Manganese (Mn)
5.13
5.13
mg/L
1
0.001
5
98
75
125
Zinc (Zn)
4.99
4.99
mg/L
1
0.004
5
99.8
75
125
MSD # 1
Parent Sample:
J23030368
-- 2023006823
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
Barium (Ba)
5.37
5.37
mg/L
1
0.002
5
107
75
125
1.56
Boron (B)
5.09
5.09
mg/L
1
0.005
5
101
75
125
6.41
Calcium (Ca)
12.3
12.3
mg/L
1
0.012
5
103
75
125
1.25
Iron (Fe)
5.42
5.42
mg/L
1
0.004
5
104
75
125
2.13
Lithium (Li)
5.1
5.1
mg/L
1
0.002
5
102
75
125
1.98
Magnesium (Mg)
7.64
7.64
mg/L
1
0.008
5
97.7
75
125
0.341
Manganese (Mn)
5.24
5.24
mg/L
1
0.001
5
100
75
125
2.04
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 24 of 29
This report shall not be reproduced, except in full.
Order # J23030368
Level II QC Summary
Q23030328 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
MSD # 1 Parent Sample: J23030368 -- 2023006823
Parameter Measured Final Units Dil MDL Spike % Recovery LCL UCL RPD Qualifier
Zinc (Zn) 5.21 5.21 mg/L 1 0.004 5 104 75 125 4.18

Certificate of Laboratory Analysis Page 25 of 29
This report shall not be reproduced, except in full.
Order # J23030368
Level II QC Summary
Q23030332 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Blank # 1
LCS # 1
MS # 1
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Beryllium (Be)
-0.012
-0.012
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
-0.004
-0.004
ug/L
1
0.032
1
< MDL
Chromium (Cr)
-0.023
-0.023
ug/L
1
0.185
1
< MDL
Copper (Cu)
-0.003
-0.003
ug/L
1
0.787
1
< MDL
Lead (Pb)
-0.002
-0.002
ug/L
1
0.037
1
< MDL
Nickel (Ni)
0.001
0.001
ug/L
1
0.256
1
< MDL
Silver (Ag)
0.002
0.002
ug/L
1
0.035
1
< MDL
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Beryllium (Be)
47
47
ug/L
1
0.249
50
94
80
120
Cadmium (Cd)
46.7
46.7
ug/L
1
0.032
50
93.3
80
120
Chromium (Cr)
48
48
ug/L
1
0.185
50
96.1
80
120
Copper (Cu)
46.3
46.3
ug/L
1
0.787
50
92.7
80
120
Lead (Pb)
48.4
48.4
ug/L
1
0.037
50
96.9
80
120
Nickel (Ni)
45.4
45.4
ug/L
1
0.256
50
90.8
80
120
Silver (Ag)
47.1
47.1
ug/L
1
0.035
50
94.2
80
120
Parent Sample:
J23030368 -- 2023006822
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Beryllium (Be)
47.6
47.6
ug/L
1
0.249
50
95.1
75
125
Cadmium (Cd)
46.8
46.8
ug/L
1
0.032
50
93.4
75
125
Chromium (Cr)
47.4
47.4
ug/L
1
0.185
50
94.5
75
125
Copper (Cu)
46.2
46.2
ug/L
1
0.787
50
91
75
125
Lead (Pb)
48.3
48.3
ug/L
1
0.037
50
96.5
75
125
Nickel (Ni)
45.6
45.6
ug/L
1
0.256
50
90.1
75
125
Silver (Ag)
46.7
46.7
ug/L
1
0.035
50
93.2
75
125
Parent Sample:
J23030368 -- 2023006822
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Beryllium (Be)
46.9
46.9
ug/L
1
0.249
50
93.7
75
125
1.44
Cadmium (Cd)
47.1
47.1
ug/L
1
0.032
50
94
75
125
0.651
Chromium (Cr)
48
48
ug/L
1
0.185
50
95.5
75
125
1.1
Copper (Cu)
46.5
46.5
ug/L
1
0.787
50
91.6
75
125
0.732
Lead (Pb)
48.5
48.5
ug/L
1
0.037
50
96.8
75
125
0.323
Nickel (Ni)
46
46
ug/L
1
0.256
50
90.9
75
125
0.807
Silver (Ag)
46.6
46.6
ug/L
1
0.035
50
93.2
75
125
0.0558
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 26 of 29
This report shall not be reproduced, except in full.
Order # J23030368
Level II QC Summary
Q23030333 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
-0.071
-0.071
ug/L
1
0.104
1
< MDL
Arsenic (As)
-0.032
-0.032
ug/L
1
0.111
1
< MDL
Beryllium (Be)
-0.012
-0.012
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.001
0.001
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.002
0.002
ug/L
1
0.185
1
< MDL
Cobalt (Co)
0
0
ug/L
1
0.077
1
< MDL
Copper (Cu)
0.096
0.096
ug/L
1
0.787
1
< MDL
Lead (Pb)
0.002
0.002
ug/L
1
0.037
1
< MDL
Molybdenum (Mo)
0.025
0.025
ug/L
1
0.18
1
< MDL
Nickel (Ni)
-0.009
-0.009
ug/L
1
0.256
1
< MDL
Selenium (Se)
0.007
0.007
ug/L
1
0.193
1
< MDL
Silver (Ag)
0.001
0.001
ug/L
1
0.035
1
< MDL
Thallium (TI) Low Level
0.005
0.005
ug/L
1
0.041
0.2
< MDL
Vanadium (V) Low Level
-0.105
-0.105
ug/L
1
0.114
0.3
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
46.4
46.4
ug/L
1
0.104
50
92.8
80
120
Arsenic (As)
44.6
44.6
ug/L
1
0.111
50
89.2
80
120
Beryllium (Be)
45.6
45.6
ug/L
1
0.249
50
91.2
80
120
Cadmium (Cd)
45.6
45.6
ug/L
1
0.032
50
91.2
80
120
Chromium (Cr)
46.9
46.9
ug/L
1
0.185
50
93.9
80
120
Cobalt (Co)
44.9
44.9
ug/L
1
0.077
50
89.9
80
120
Copper (Cu)
45.5
45.5
ug/L
1
0.787
50
90.9
80
120
Lead (Pb)
47.5
47.5
ug/L
1
0.037
50
95
80
120
Molybdenum (Mo)
46.8
46.8
ug/L
1
0.18
50
93.5
80
120
Nickel (Ni)
44.9
44.9
ug/L
1
0.256
50
89.8
80
120
Selenium (Se)
43.2
43.2
ug/L
1
0.193
50
86.4
80
120
Silver (Ag)
46.3
46.3
ug/L
1
0.035
50
92.6
80
120
Thallium (TI) Low Level
46.2
46.2
ug/L
1
0.041
50
92.4
80
120
Vanadium (V) Low Level
46.9
46.9
ug/L
1
0.114
50
93.8
80
120
MS # 1
Parent Sample:
J23030368
-- 2023006822
Parameter
Measured
Final
Units
Dil
MDL
alAke
% Recovery
LCL
UCL
Antimony (Sb)
47.3
47.3
ug/L
1
0.104
50
94.7
75
125
Arsenic (As)
45.9
45.9
ug/L
1
0.111
50
91.7
75
125
Beryllium (Be)
46.9
46.9
ug/L
1
0.249
50
93.7
75
125
Cadmium (Cd)
46.4
46.4
ug/L
1
0.032
50
92.6
75
125
Chromium (Cr)
48
48
ug/L
1
0.185
50
95.2
75
125
Cobalt (Co)
45.2
45.2
ug/L
1
0.077
50
90.3
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23030368
Level II QC Summary
Q23030333 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
Copper (Cu)
45.8
45.8
ug/L
1
0.787
50
Lead (Pb)
48.2
48.2
ug/L
1
0.037
50
Molybdenum (Mo)
47.6
47.6
ug/L
1
0.18
50
Nickel (Ni)
45.3
45.3
ug/L
1
0.256
50
Selenium (Se)
44.8
44.8
ug/L
1
0.193
50
Silver (Ag)
46.1
46.1
ug/L
1
0.035
50
Thallium (TI) Low Level
46.8
46.8
ug/L
1
0.041
50
Vanadium (V) Low Level
48.2
48.2
ug/L
1
0.114
50
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
Antimony (Sb)
47.5
47.5
ug/L
1
0.104
50
Arsenic (As)
46.5
46.5
ug/L
1
0.111
50
Beryllium (Be)
47.5
47.5
ug/L
1
0.249
50
Cadmium (Cd)
47
47
ug/L
1
0.032
50
Chromium (Cr)
47.7
47.7
ug/L
1
0.185
50
Cobalt (Co)
45.3
45.3
ug/L
1
0.077
50
Copper (Cu)
46
46
ug/L
1
0.787
50
Lead (Pb)
47.9
47.9
ug/L
1
0.037
50
Molybdenum (Mo)
47.5
47.5
ug/L
1
0.18
50
Nickel (Ni)
45.2
45.2
ug/L
1
0.256
50
Selenium (Se)
45.4
45.4
ug/L
1
0.193
50
Silver (Ag)
46.5
46.5
ug/L
1
0.035
50
Thallium (TI) Low Level
46.8
46.8
ug/L
1
0.041
50
Vanadium (V) Low Level
48.4
48.4
ug/L
1
0.114
50
Page 27 of 29
Parent Sample: J23030368 -- 2023006822
% Recovery
LCL
UCL
91
75
125
96.3
75
125
95.2
75
125
90.2
75
125
88.7
75
125
92.2
75
125
93.6
75
125
96.5
75
125
Parent Sample: J23030368 -- 2023006822
% Recovery
LCL
UCL
RPD
95
75
125
0.382
93
75
125
1.46
94.9
75
125
1.3
94
75
125
1.47
94.5
75
125
0.71
90.4
75
125
0.139
91.3
75
125
0.329
95.7
75
125
0.558
94.9
75
125
0.299
90.1
75
125
0.0999
90
75
125
1.36
92.9
75
125
0.761
93.6
75
125
0.0192
96.9
75
125
0.424
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 28 of 29
This report shall not be reproduced, except in full.
Order # J23030368
Level II QC Summary
Q23030341 TDS TOTAL DISSOLVED SOLIDS
Blank # 1
Blank # 2
Parameter Measured Final
TDS 6.7
Parameter Measured Final
TDS 0
Duplicate # 1
Parameter Measured Final
TDS 351
Duplicate # 2
Parameter Measured Final
TDS 282
LCS # 1
LCS # 2
Parameter Measured Final
TDS 509
Parameter Measured Final
TDS 498
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Parent Sample:
J23020018 -- 2023002238
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
8.31
Parent Sample:
J23030372 -- 2023006851
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
0.354
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
102
90
110
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
99.6
90
110

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
.Zv ;
Duke Energy Analytical Laboratory i
_._._._._._._._._._._._._._._.-.
i_______.___._._._._._._._._._._._._._._._._._._—Anal cal L ------- *--- Use Only
abora
------------------------------------------
i Page 29 of 29
!Order III AIL 3':U 13 Matrix WATER
.%' DUKE
Mail Code 3119Hn°n (auaalna 7406)
y„ NC x_ Page _1_of 1_
ENERGY..
° .gab, N C. � �"ra
3�_ DISTRIBUTION
ilagg
a Tima
palnes2rs '
SAMPLE PROGRAM ORIGINAL to LAB, COPY to CLIENT
:__._._._._._._._._. -------------
Fu:
Ground Water _X_ NPDES_
Drinking Water_ UST_
Project Name ASHEVILLE STATE LF DETECTION
Pnone r+^:
iVan r
'
MONITORING
'.._.._.__...__.._.._..!r._.:3.1q1_.._...._.._.._.._.._.._.._.._.._.._RCRA
Waste
........................._.__.__.._.._..__
i
Client: HEALY ASHLEY, BRYAN MOELLER, DEE P0 #
O'BRIEN, JOSH STOWE, CONNOR ZAHORA Filtration (0.45 um)
!
4
Unfiltered
4
Filtered
Operating Unit: AE00 Process:NGRDWTR Account: I
'.._..--'------'--.-'--.._.._.._.._.._.._.._.._.._.._.._.._.i Preservative
ICE
ICE
- _.
".---'-"
Project: AAE000315 Activity to: Facility ID:ASV Container Volume (mL)
600
300
5o0
250
Program / EQuiS Task Code:ASV LF Sub-Programrrask Code: Container Type
PET
PET
HDPE
HOPE
ANIONS by
(Metals Prep - 7RM) ICP -
a
o o m z
m
y
9056A: CI, F,
SW601OD: Be, B, Ca, Fe, Li,
> 3 o a
-
Customer to complete all appropriate non -shaded areas. z rc
TDS
--
NO3-N (48-Hr
Mg, Mn, Zn (s) / Hg EPA 7470A
l IMS SW60208: Sb,
rn o rn
G
c
o
Sample Description or ID
Hold Time),
- As, Be,
rOn
w w
SAMPLE ID Collection Information d. n
i
SO4
Ctl, Cr, Co, Cu, Pb, Me, Ni, Se,
Ag, TI, V (141
c d
°
NUMBER Date Time Printed Name Signature
w N O
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ASV_ LF - SvJ-t
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1150
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1,
TOTAL # CONTAINERS
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Customer to sign ate below
Relinquished By V Z�LD ima
Acceptetl By:
Date/T me
Requested Turnaround
�f'�1
pta� p
Relinquished By Date/Tim
Accep By: Daterrime
01
21 Days
t 00
c
m 9
a °
7
• �L
Relinquishetl By Date/Tima
Accepted By: DatelT'ime
• c
c �
C o
14 Days
Seal/Locked By DatelTime
SealecilLock Opened By Date/Time
n.
Days
E a
� a
Comments
STATE EDO REQUIRED/ EQUIS REQUIRED -DISSOLVED METALS: Be, Cd, Cr, Cu, Pb, NI, Ag, Zn Note: Hardness by Calculation (Ca - Mg ICP TRM) added to SW-#, DP-4, and LCS-1
I
•Other
Leachate
• Add. Cost Will Apply
v

Analytical Data Review Checklist - Aqueous
Facility/Site
Asheville Steam Electric Plant
State
NC
Location/Sample IDs
CB-91311, CB-9SL, LCS-1, LF-SW-1, LF-SW-2, LF-SW-3
References:
- ELN/A
❑v 1 ❑
Duke Central Lab
Lab Report ID Sample Date Sample Receipt Date Analysis Complete Date Groundwater
/23030368 3/20/2023 3/21/2023 4/5/2023 ❑ Surface Water
❑ Other
National Functional Guidelines for Inorganic Superfund Methods Data Review (USEPA 2020)
Guidance on Environmental Data Verification and Data Validation (USEPA 2002)
Radiochemical Data Verification and Validation (MARLAP 2004)
� Sample Receipt and Chain of Custody
I� 1) Do the sample IDs and laboratory analyses recorded on the Chain of Custody match the sample IDs and analyses listed in the laboratory package?
❑v
❑ l
❑
la) Do the dates and times of sampling listed on the Chain of Custody match the laboratory report?
0
❑
❑
❑
❑
(]
2) Is the sample temperature upon receipt at the laboratory recorded on the Chain of Custody form less than 6 degrees Celsius? If NO, then:
2a) Was the presence of wet ice noted in the cooler? OR
❑
❑
0
2b) Were the samples collected less than two hours prior to receipt at the lab?
❑�
❑
❑
3) Was the proper sample preservation checked and documented on the Chain of Custody or sample receipt form?
❑
1 ❑�
❑
4) Are there any special notes, exceptions, and/or anomalies listed either on the Chain of Custody or sample receipt form?
O
❑
❑
5) Was the transfer of custody of the samples properly documented and traceable through signature, date, and time by all persons who relinquished and/or received
custody of the samples?
❑
❑ ❑�
®®Batch
6) Do the values for the field parameters listed on the Chain of Custody match the values entered in the lab report?
eAssurance/Quality
7) Was the holding time for preparation and/or analysis met for each parameter?
❑
❑
❑�
7a) Total Alkalinity, Bicarbonate Alkalinity, Carbonate Alkalinity: Analyzed within 14 days of collection
❑�
❑
❑
7b) Bromide, Chloride, Fluoride, and Sulfate (Anions): Analyzed within 28 days of collection
❑
❑
l]
7c) Sulfide: Analyzed within 7 days of collection
0
❑
❑
7d) TOC and/or Nitrate -Nitrite: Analyzed within 28 days of collection
❑
❑
l]
7e) Total Phosphorus (TP) and Dissolved TP: Analyzed within 28 days of collection
❑
❑
(]
7f) Hexavalent Chromium: Analyzed within 24 hours (unpreserved) / 28 days (preserved) of collection
0
❑
❑
7g) Mercury and Dissolved Mercury: Analyzed within 28 days of collection (preserved)
0
❑
❑
7h) Total and Dissolved Metals: Analyzed within 180 days of collection
0
❑
71) TSS and TDS: Analyzed within 7 days of collection
❑
❑
0
7J) Radionuclides: Analyzed within 180 days of collection
❑
❑
❑
❑
I]
0
7k) Methane: Analyzed within 14 days (preserved) / 7 days (unpreserved) of collection
71) Oil and Grease: Analyzed within 28 days of collection
❑�
❑
❑
8) Are there any qualifiers assigned by the laboratory and if so, are the qualifier definitions provided?
❑
❑
0
❑
9) Method Blank- Were any parameters detected in the method blank(s)?
9a) If YES, were any target analyses detected in the samples at concentrations less than ten times the method blank concentration?
❑
❑
❑�
❑
10) Laboratory Control Sample - Were any parameters flagged by the lab as being outside the limits of control in the associated laboratory control sample (LCS)?
10a) If YES, was the parameter recovery less than 50 percent or greater than 150 percent?
❑
❑
❑v
10b) Were the some parameters detected in the samples?
❑�
❑
❑
11) Matrix Spike Sample - Did the laboratory provide matrix spike results (MS/MSD)? If so, then:
❑�
❑
❑
111a) Was the original sample spiked a project sample? If so, then:
❑
❑�
❑
11 b) Were any parameters flagged by the lab as being outside the limits of control in the associated matrix spike sample?

Batch
7❑!Assurance/Quality
0 ❑ ❑ 12) Laboratory Duplicate Sample - Did the laboratory provide lab duplicate sample results? If so, then:
0 ❑ 12a) Was the sample analyzed as a laboratory duplicate a project sample? If so, then:
❑ ❑ 0 12b) Were any parameters flagged by the lab as being outside the limits of control in the laboratory duplicate sample?
0 ❑ ❑ 13) Field Duplicate Sample - Is the relative percent difference between the parent and field duplicate sample results greater than 35 percent?
0 ❑ ❑ 14) Field/Equipment/Trip Blanks - Were any parameters detected in the associated field, equipment, and/or trip blanks?
0 ❑ ❑ 14a) If yes, were any target analytes detected in the samples at a concentration less than ten times the Field/Equipment/Trip Blank concentration?
❑v
❑ ❑ 15) Were initial and continuing calibration blank information within acceptable criteria per the lab report?
❑
❑v ❑ 16) Were any reporting limits for diluted, non -detect results greater than the screening criteria?
❑ ❑ 17) Radionuclides: Are quality control sample results provided?
❑ ❑ ❑� 17a) Are any results flagged or qualified?
❑ ❑ ❑° 17b) Are Uncertainty, MDC, Tracer/ and/or Carrier/ provided for each sample?
The questions on this checklist refer to basic review of laboratory analytical reports for completeness and accuracy of data. Any responses requiring follow up action with the analytical lab or field personnel must be
noted in the summary section at the end of this form before the data can be approved for use by technical leads.
Lab Qualifiers:
J (Duke) -Analyte detected above the MDL, but below the RL; analyte concentration should be considered an estimate.
7
M (Duke) - MS and/or MSD recovery was outside of the control limits; the associated LCS recovery was acceptable. (This qualifier is for a non -project QC sample.)
U (Duke) -Analyte was analyzed for, but not detected above the MDL.
Validation Qualifiers:
R- Result is unusable. The sample result is rejected due to serious deficiencies in meeting quality control criteria; the analyte may or may not be present in the sample.
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
U-Analyte was analyzed form but not detected above the minimum detectable concentration (MDC) or method detection limit (MDL).
B -Target analyte detected in the method blank an in the sample at a concentration less than 10x the blank concentration.
• The RPD between LCS-1 and the field duplicate is greater than 35%for Iron (0.385/1.16 mg/L), Manganese (0.246/0.351 mg/L), Chromium (0.881/1.62 ug/L), Copper (1.14/2.22 ug/L),
Vanadium (2.94/4.39 ug/L), and Dissolved Copper (0.861/1.42 ug/L).
• Boron (0.005 mg/L), Calcium (0.034 mg/L), and Molybdenum (0.294 ug/L) were detected in the Field Blank; Boron and Molybdenum were also detected in the samples at concentrations less
than 10x the blank concentrations.
Review Determination: ❑ Usable 0 Usable with Required Actions ❑ Unusable
Signatures: Date:
Data Quality Reviewer REB 4/20/2023
Technical Lead KHF 7/6/2023

DUE Analytical Laboratory
ENERGY
Y
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J23030391
Project Name: ASHEVILLE - ASHEVILLE STATE LF DETECTION MONITORING
Task Code: LF
Customer Name(s): Ashley Healy,B Moeller, D Obrien,J Stowe,C Zahora
Customer Address: Asheville Steam Station
200 CP and L Drive
Arden,NC 28704
Lab Contact: Peggy Kendall Phone: [phone]
Report Authorized By: Date:
(Signature)
Peggy endall
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
4/5/2023
Page 1 of 22
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Page 2 of 22
Sample ID
Plant/Station
Collection
Date and Time
Collected By
Sample Description
2023006935
ASHEVILLE
21-Mar-23
8:30 AM
Connor Zahora
ASV—CB-9
2023006936
ASHEVILLE
21-Mar-23
9:05 AM
Connor Zahora
ASV LMW-1 B
2023006937
ASHEVILLE
21-Mar-23
9:50 AM
Connor Zahora
ASV LMW-1 S
2023006938
ASHEVILLE
21-Mar-23
10:35 AM
Connor Zahora
ASV LMW-4B
2023006939
ASHEVILLE
21-Mar-23
11:35 AM
Connor Zahora
ASV LMW-3B
2023006940
ASHEVILLE
21-Mar-23
1:10 PM
Connor Zahora
ASV LMW-2B
2023006941
ASHEVILLE
21-Mar-23
2:10 PM
Connor Zahora
ASV LMW-2T
2023006942
ASHEVILLE
21-Mar-23
Connor Zahora
ASV FD-20230321-1
2023006943
ASHEVILLE
21-Mar-23
2:30 PM
Connor Zahora
ASV FB-20230321-1430
9 Total Samples

Page 3 of 22
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
d❑ Job Summary Report
J❑ Sample Identification
❑ Technical Validation of Data Package
d❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
❑ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 4/5/2023

Certificate of Laboratory Analysis Page 4 of 22
This report shall not be reproduced, except in full.
Order # J23030391
Site: ASV CB-9 Sample #: 2023006935
Collection Date: 03/21/2023 08:30 AM Loc code: ASV-CB-9 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23030321
Chloride 6.3 mg/L
Fluoride 0.0479 U mg/L
Nitrate 0.82 mg/L
Nitrate as N 0.19 mg-N/L
Sulfate 0.08 J mg/L
MERCURY (COLD VAPOR) IN WATER - Q23030421
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23030355
Barium (Ba)
0.029
mg/L
Boron (B)
0.011 J
mg/L
Calcium (Ca)
0.429
mg/L
Iron (Fe)
0.020
mg/L
Lithium (Li)
0.005
mg/L
Magnesium (Mg)
0.854
mg/L
Manganese (Mn)
0.031
mg/L
Zinc (Zn)
0.010
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23030360
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.047 J
ug/L
Chromium (Cr)
0.324 J
ug/L
Cobalt (Co)
0.872 J
ug/L
Copper (Cu)
0.968 J
ug/L
Lead (Pb)
0.04 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
1.03
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.067 J
ug/L
Vanadium (V) Low Level
0.114 U
ug/L
TOTAL DISSOLVED SOLIDS
- Q23030341
TDS 25 U mg/L
Method Analysis Date/Time Analyst
0.5
0.0154
5
EPA 9056A
03/22/2023 07:54
BGN9034
0.1
0.0479
1
EPA 9056A
03/22/2023 07:54
BGN9034
0.1
0.0209
1
EPA 9056A
03/22/2023 07:54
BGN9034
0.023
0.002
1
EPA 9056A
03/22/2023 07:54
BGN9034
0.1
0.0428
1
EPA 9056A
03/22/2023 07:54
BGN9034
0.05
0.01
1
EPA 7470A
03/28/2023 14:55
JAA5429
0.005
0.002
1
SW 6010D
03/23/2023 16:54
CELL106
0.05
0.005
1
SW 6010D
03/23/2023 16:54
CELL106
0.05
0.012
1
SW 6010D
03/23/2023 16:54
CELL106
0.01
0.004
1
SW 6010D
03/23/2023 16:54
CELL106
0.005
0.002
1
SW 6010D
03/23/2023 16:54
CELL106
0.02
0.008
1
SW 6010D
03/23/2023 16:54
CELL106
0.005
0.001
1
SW 6010D
03/23/2023 16:54
CELL106
0.005
0.004
1
SW 601OD
03/23/2023 16:54
CELL106
1
0.104
1
SW 6020B
03/23/2023 15:49
MHALL3
1
0.111
1
SW 6020B
03/23/2023 15:49
MHALL3
1
0.249
1
SW 6020B
03/23/2023 15:49
MHALL3
1
0.032
1
SW 6020B
03/23/2023 15:49
MHALL3
1
0.185
1
SW 6020B
03/23/2023 15:49
MHALL3
1
0.077
1
SW 6020B
03/23/2023 15:49
MHALL3
1
0.787
1
SW 6020B
03/23/2023 15:49
MHALL3
1
0.037
1
SW 6020B
03/23/2023 15:49
MHALL3
1
0.18
1
SW 6020B
03/23/2023 15:49
MHALL3
1
0.256
1
SW 6020B
03/23/2023 15:49
MHALL3
1
0.193
1
SW 6020B
03/23/2023 15:49
MHALL3
1
0.035
1
SW 6020B
03/23/2023 15:49
MHALL3
0.2
0.041
1
SW 6020B
03/23/2023 15:49
MHALL3
0.3
0.114
1
SW 6020B
03/23/2023 15:49
MHALL3
25
25
1
SM2540C
03/22/202310:39
EBATIAN

Certificate of Laboratory Analysis Page 5 of 22
This report shall not be reproduced, except in full.
Order # J23030391
Site: ASV LMW-1 B Sample #: 2023006936
Collection Date: 03/21/2023 09:05 AM Loc code: ASV LMW-lB Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23030321
Chloride 8.2 mg/L
Fluoride 0.0479 U mg/L
Nitrate 0.08 J mg/L
Nitrate as N 0.02 J mg-N/L
Sulfate 0.28 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23030421
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23030355
Barium (Ba)
0.028
mg/L
Boron (B)
0.006 J
mg/L
Calcium (Ca)
10.1
mg/L
Iron (Fe)
0.068
mg/L
Lithium (Li)
0.008
mg/L
Magnesium (Mg)
4.63
mg/L
Manganese (Mn)
0.004 J
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23030360
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.486 J
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.081 J
ug/L
Molybdenum (Mo)
0.87 J
ug/L
Nickel (Ni)
0.517 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.084 J
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.418
ug/L
TOTAL DISSOLVED SOLIDS
- Q23030341
TDS 95.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
03/22/2023 08:59
BGN9034
0.1
0.0479
1
EPA 9056A
03/22/2023 08:59
BGN9034
0.1
0.0209
1
EPA 9056A
03/22/2023 08:59
BGN9034
0.023
0.002
1
EPA 9056A
03/22/2023 08:59
BGN9034
0.1
0.0428
1
EPA 9056A
03/22/2023 08:59
BGN9034
0.05
0.01
1
EPA 7470A
03/28/2023 14:58
JAA5429
0.005
0.002
1
SW 6010D
03/23/2023 16:40
CELL106
0.05
0.005
1
SW 6010D
03/23/2023 16:40
CELL106
0.05
0.012
1
SW 6010D
03/23/2023 16:40
CELL106
0.01
0.004
1
SW 6010D
03/23/2023 16:40
CELL106
0.005
0.002
1
SW 6010D
03/23/2023 16:40
CELL106
0.02
0.008
1
SW 6010D
03/23/2023 16:40
CELL106
0.005
0.001
1
SW 6010D
03/23/2023 16:40
CELL106
0.005
0.004
1
SW 601OD
03/23/2023 16:40
CELL106
1
0.104
1
SW 6020B
03/23/2023 16:31
MHALL3
1
0.111
1
SW 6020B
03/23/2023 16:31
MHALL3
1
0.249
1
SW 6020B
03/23/2023 16:31
MHALL3
1
0.032
1
SW 6020B
03/23/2023 16:31
MHALL3
1
0.185
1
SW 6020B
03/23/2023 16:31
MHALL3
1
0.077
1
SW 6020B
03/23/2023 16:31
MHALL3
1
0.787
1
SW 6020B
03/23/2023 16:31
MHALL3
1
0.037
1
SW 6020B
03/23/2023 16:31
MHALL3
1
0.18
1
SW 6020B
03/23/2023 16:31
MHALL3
1
0.256
1
SW 6020B
03/23/2023 16:31
MHALL3
1
0.193
1
SW 6020B
03/23/2023 16:31
MHALL3
1
0.035
1
SW 6020B
03/23/2023 16:31
MHALL3
0.2
0.041
1
SW 6020B
03/23/2023 16:31
MHALL3
0.3
0.114
1
SW 6020B
03/23/2023 16:31
MHALL3
25
25
1
SM2540C
03/22/202310:39
EBATIAN

Certificate of Laboratory Analysis Page 6 of 22
This report shall not be reproduced, except in full.
Order # J23030391
Site: ASV LMW-lS Sample #: 2023006937
Collection Date: 03/21/2023 09:50 AM Loc code: ASV LMW-lS Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23030321
Chloride 6.1 mg/L
Fluoride 0.0479 U mg/L
Nitrate 2.2 mg/L
Nitrate as N 0.49 mg-N/L
Sulfate 0.26 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23030421
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23030355
Barium (Ba)
0.044
mg/L
Boron (B)
0.006 J
mg/L
Calcium (Ca)
5.97
mg/L
Iron (Fe)
0.413
mg/L
Lithium (Li)
0.005 J
mg/L
Magnesium (Mg)
2.06
mg/L
Manganese (Mn)
0.052
mg/L
Zinc (Zn)
0.006
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23030360
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.955 J
ug/L
Cobalt (Co)
0.509 J
ug/L
Copper (Cu)
0.832 J
ug/L
Lead (Pb)
0.146 J
ug/L
Molybdenum (Mo)
0.733 J
ug/L
Nickel (Ni)
4.29
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.042 J
ug/L
Thallium (TI) Low Level
0.051 J
ug/L
Vanadium (V) Low Level
0.451
ug/L
TOTAL DISSOLVED SOLIDS
- Q23030341
TDS 58.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
03/22/2023 09:15
BGN9034
0.1
0.0479
1
EPA 9056A
03/22/2023 09:15
BGN9034
0.1
0.0209
1
EPA 9056A
03/22/2023 09:15
BGN9034
0.023
0.002
1
EPA 9056A
03/22/2023 09:15
BGN9034
0.1
0.0428
1
EPA 9056A
03/22/2023 09:15
BGN9034
0.05
0.01
1
EPA 7470A
03/28/2023 15:00
JAA5429
0.005
0.002
1
SW 6010D
03/23/2023 16:59
CELL106
0.05
0.005
1
SW 6010D
03/23/2023 16:59
CELL106
0.05
0.012
1
SW 6010D
03/23/2023 16:59
CELL106
0.01
0.004
1
SW 6010D
03/23/2023 16:59
CELL106
0.005
0.002
1
SW 6010D
03/23/2023 16:59
CELL106
0.02
0.008
1
SW 6010D
03/23/2023 16:59
CELL106
0.005
0.001
1
SW 6010D
03/23/2023 16:59
CELL106
0.005
0.004
1
SW 601OD
03/23/2023 16:59
CELL106
1
0.104
1
SW 6020B
03/23/2023 16:39
MHALL3
1
0.111
1
SW 6020B
03/23/2023 16:39
MHALL3
1
0.249
1
SW 6020B
03/23/2023 16:39
MHALL3
1
0.032
1
SW 6020B
03/23/2023 16:39
MHALL3
1
0.185
1
SW 6020B
03/23/2023 16:39
MHALL3
1
0.077
1
SW 6020B
03/23/2023 16:39
MHALL3
1
0.787
1
SW 6020B
03/23/2023 16:39
MHALL3
1
0.037
1
SW 6020B
03/23/2023 16:39
MHALL3
1
0.18
1
SW 6020B
03/23/2023 16:39
MHALL3
1
0.256
1
SW 6020B
03/23/2023 16:39
MHALL3
1
0.193
1
SW 6020B
03/23/2023 16:39
MHALL3
1
0.035
1
SW 6020B
03/23/2023 16:39
MHALL3
0.2
0.041
1
SW 6020B
03/23/2023 16:39
MHALL3
0.3
0.114
1
SW 6020B
03/23/2023 16:39
MHALL3
25
25
1
SM2540C
03/22/202310:39
EBATIAN

Certificate of Laboratory Analysis Page 7 of 22
This report shall not be reproduced, except in full.
Order # J23030391
Site: ASV LMW-4B Sample #: 2023006938
Collection Date: 03/21/2023 10:35 AM Loc code: ASV LMW-4B Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23030321
Chloride 7.6 mg/L
Fluoride 0.47 J mg/L
Nitrate 4.7 mg/L
Nitrate as N 1.1 mg-N/L
Sulfate 89 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23030421
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23030355
Barium (Ba)
0.037
mg/L
Boron (B)
0.038 J
mg/L
Calcium (Ca)
42.2
mg/L
Iron (Fe)
10.6
mg/L
Lithium (Li)
0.019
mg/L
Magnesium (Mg)
13.6
mg/L
Manganese (Mn)
4.99
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23030360
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.288 J
ug/L
Beryllium (Be)
1.09
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.185 U
ug/L
Cobalt (Co)
18.6
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
3.36
ug/L
Nickel (Ni)
5.60
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.114 U
ug/L
TOTAL DISSOLVED SOLIDS
- Q23030341
TDS 281 mg/L
Method Analysis Date/Time Analyst
0.5
0.0154
5
EPA 9056A
03/22/2023 10:04
BGN9034
0.5
0.0479
5
EPA 9056A
03/22/2023 10:04
BGN9034
0.5
0.0209
5
EPA 9056A
03/22/2023 10:04
BGN9034
0.115
0.002
5
EPA 9056A
03/22/2023 10:04
BGN9034
2.5
0.0428
25
EPA 9056A
03/22/2023 10:04
BGN9034
0.05
0.01
1
EPA 7470A
03/28/2023 15:02
JAA5429
0.005
0.002
1
SW 6010D
03/23/2023 17:03
CELL106
0.05
0.005
1
SW 6010D
03/23/2023 17:03
CELL106
0.05
0.012
1
SW 6010D
03/23/2023 17:03
CELL106
0.01
0.004
1
SW 6010D
03/23/2023 17:03
CELL106
0.005
0.002
1
SW 6010D
03/23/2023 17:03
CELL106
0.02
0.008
1
SW 6010D
03/23/2023 17:03
CELL106
0.005
0.001
1
SW 6010D
03/23/2023 17:03
CELL106
0.005
0.004
1
SW 601OD
03/23/2023 17:03
CELL106
1
0.104
1
SW 6020B
03/23/2023 16:48
MHALL3
1
0.111
1
SW 6020B
03/23/2023 16:48
MHALL3
1
0.249
1
SW 6020B
03/23/2023 16:48
MHALL3
1
0.032
1
SW 6020B
03/23/2023 16:48
MHALL3
1
0.185
1
SW 6020B
03/23/2023 16:48
MHALL3
1
0.077
1
SW 6020B
03/23/2023 16:48
MHALL3
1
0.787
1
SW 6020B
03/23/2023 16:48
MHALL3
1
0.037
1
SW 6020B
03/23/2023 16:48
MHALL3
1
0.18
1
SW 6020B
03/23/2023 16:48
MHALL3
1
0.256
1
SW 6020B
03/23/2023 16:48
MHALL3
1
0.193
1
SW 6020B
03/23/2023 16:48
MHALL3
1
0.035
1
SW 6020B
03/23/2023 16:48
MHALL3
0.2
0.041
1
SW 6020B
03/23/2023 16:48
MHALL3
0.3
0.114
1
SW 6020B
03/23/2023 16:48
MHALL3
25
25
1
SM2540C
03/22/202310:39
EBATIAN

Certificate of Laboratory Analysis Page 8 of 22
This report shall not be reproduced, except in full.
Order # J23030391
Site: ASV LMW-3B Sample #: 2023006939
Collection Date: 03/21/2023 11:35 AM Loc code: ASV LMW-3B Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23030321
Chloride 3.1 mg/L
Fluoride 0.0479 U mg/L
Nitrate 6.6 mg/L
Nitrate as N 1.5 mg-N/L
Sulfate 260 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23030421
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23030355
Barium (Ba)
0.084
mg/L
Boron (B)
0.01 J
mg/L
Calcium (Ca)
104
mg/L
Iron (Fe)
0.038
mg/L
Lithium (Li)
0.003 J
mg/L
Magnesium (Mg)
23.2
mg/L
Manganese (Mn)
0.200
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23030360
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.131 J
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.295 J
ug/L
Cobalt (Co)
0.291 J
ug/L
Copper (Cu)
0.79 J
ug/L
Lead (Pb)
0.082 J
ug/L
Molybdenum (Mo)
1.27
ug/L
Nickel (Ni)
0.384 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.177 J
ug/L
TOTAL DISSOLVED SOLIDS
- Q23030341
TDS 535 mg/L
Method Analysis Date/Time Analyst
0.5
0.0154
5
EPA 9056A
03/22/2023 10:20
BGN9034
0.5
0.0479
5
EPA 9056A
03/22/2023 10:20
BGN9034
0.5
0.0209
5
EPA 9056A
03/22/2023 10:20
BGN9034
0.115
0.002
5
EPA 9056A
03/22/2023 10:20
BGN9034
5
0.0428
50
EPA 9056A
03/22/2023 10:20
BGN9034
0.05
0.01
1
EPA 7470A
03/28/2023 15:05
JAA5429
0.005
0.002
1
SW 6010D
03/23/2023 17:08
CELL106
0.05
0.005
1
SW 6010D
03/23/2023 17:08
CELL106
0.5
0.012
10
SW 6010D
03/23/2023 17:08
CELL106
0.01
0.004
1
SW 6010D
03/23/2023 17:08
CELL106
0.005
0.002
1
SW 6010D
03/23/2023 17:08
CELL106
0.02
0.008
1
SW 6010D
03/23/2023 17:08
CELL106
0.005
0.001
1
SW 6010D
03/23/2023 17:08
CELL106
0.005
0.004
1
SW 601OD
03/23/2023 17:08
CELL106
1
0.104
1
SW 6020B
03/23/2023 17:21
MHALL3
1
0.111
1
SW 6020B
03/23/2023 17:21
MHALL3
1
0.249
1
SW 6020B
03/23/2023 17:21
MHALL3
1
0.032
1
SW 6020B
03/23/2023 17:21
MHALL3
1
0.185
1
SW 6020B
03/23/2023 17:21
MHALL3
1
0.077
1
SW 6020B
03/23/2023 17:21
MHALL3
1
0.787
1
SW 6020B
03/23/2023 17:21
MHALL3
1
0.037
1
SW 6020B
03/23/2023 17:21
MHALL3
1
0.18
1
SW 6020B
03/23/2023 17:21
MHALL3
1
0.256
1
SW 6020B
03/23/2023 17:21
MHALL3
1
0.193
1
SW 6020B
03/23/2023 17:21
MHALL3
1
0.035
1
SW 6020B
03/23/2023 17:21
MHALL3
0.2
0.041
1
SW 6020B
03/23/2023 17:21
MHALL3
0.3
0.114
1
SW 6020B
03/23/2023 17:21
MHALL3
25
25
1
SM2540C
03/22/202310:39
EBATIAN

Certificate of Laboratory Analysis Page 9 of 22
This report shall not be reproduced, except in full.
Order # J23030391
Site: ASV LMW-2B Sample #: 2023006940
Collection Date: 03/21/2023 01:10 PM Loc code: ASV LMW-2B Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23030321
Chloride 7.7 mg/L
Fluoride 0.0479 U mg/L
Nitrate 1.1 mg/L
Nitrate as N 0.25 mg-N/L
Sulfate 2.6 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23030421
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23030355
Barium (Ba)
0.044
mg/L
Boron (B)
0.013 J
mg/L
Calcium (Ca)
5.26
mg/L
Iron (Fe)
0.037
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.86
mg/L
Manganese (Mn)
0.008
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23030360
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.682 J
ug/L
Cobalt (Co)
0.108 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.115 J
ug/L
Molybdenum (Mo)
0.302 J
ug/L
Nickel (Ni)
0.332 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.535
ug/L
TOTAL DISSOLVED SOLIDS
- Q23030341
TDS 65.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
03/22/2023 09:31
BGN9034
0.1
0.0479
1
EPA 9056A
03/22/2023 09:31
BGN9034
0.1
0.0209
1
EPA 9056A
03/22/2023 09:31
BGN9034
0.023
0.002
1
EPA 9056A
03/22/2023 09:31
BGN9034
0.1
0.0428
1
EPA 9056A
03/22/2023 09:31
BGN9034
0.05
0.01
1
EPA 7470A
03/28/2023 15:07
JAA5429
0.005
0.002
1
SW 6010D
03/23/2023 17:13
CELL106
0.05
0.005
1
SW 6010D
03/23/2023 17:13
CELL106
0.05
0.012
1
SW 6010D
03/23/2023 17:13
CELL106
0.01
0.004
1
SW 6010D
03/23/2023 17:13
CELL106
0.005
0.002
1
SW 6010D
03/23/2023 17:13
CELL106
0.02
0.008
1
SW 6010D
03/23/2023 17:13
CELL106
0.005
0.001
1
SW 6010D
03/23/2023 17:13
CELL106
0.005
0.004
1
SW 601OD
03/23/2023 17:13
CELL106
1
0.104
1
SW 6020B
03/23/2023 17:30
MHALL3
1
0.111
1
SW 6020B
03/23/2023 17:30
MHALL3
1
0.249
1
SW 6020B
03/23/2023 17:30
MHALL3
1
0.032
1
SW 6020B
03/23/2023 17:30
MHALL3
1
0.185
1
SW 6020B
03/23/2023 17:30
MHALL3
1
0.077
1
SW 6020B
03/23/2023 17:30
MHALL3
1
0.787
1
SW 6020B
03/23/2023 17:30
MHALL3
1
0.037
1
SW 6020B
03/23/2023 17:30
MHALL3
1
0.18
1
SW 6020B
03/23/2023 17:30
MHALL3
1
0.256
1
SW 6020B
03/23/2023 17:30
MHALL3
1
0.193
1
SW 6020B
03/23/2023 17:30
MHALL3
1
0.035
1
SW 6020B
03/23/2023 17:30
MHALL3
0.2
0.041
1
SW 6020B
03/23/2023 17:30
MHALL3
0.3
0.114
1
SW 6020B
03/23/2023 17:30
MHALL3
25
25
1
SM2540C
03/22/202310:39
EBATIAN

Certificate of Laboratory Analysis Page 10 of 22
This report shall not be reproduced, except in full.
Order # J23030391
Site: ASV LMW-2T Sample #: 2023006941
Collection Date: 03/21/2023 02:10 PM Loc code: ASV LMW-2T Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23030321
Chloride 9.6 mg/L
Fluoride 0.0479 U mg/L
Nitrate 0.41 mg/L
Nitrate as N 0.09 mg-N/L
Sulfate 4.4 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23030421
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23030355
Barium (Ba)
0.032
mg/L
Boron (B)
0.027 J
mg/L
Calcium (Ca)
3.19
mg/L
Iron (Fe)
0.182
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.23
mg/L
Manganese (Mn)
0.021
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23030360
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.04 J
ug/L
Chromium (Cr)
0.271 J
ug/L
Cobalt (Co)
0.392 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.084 J
ug/L
Molybdenum (Mo)
0.202 J
ug/L
Nickel (Ni)
0.301 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.042 J
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.359
ug/L
TOTAL DISSOLVED SOLIDS
- Q23030341
TDS 47.0 mg/L
Method Analysis Date/Time Analyst
0.5
0.0154
5
EPA 9056A
03/22/2023 09:48
BGN9034
0.1
0.0479
1
EPA 9056A
03/22/2023 09:48
BGN9034
0.1
0.0209
1
EPA 9056A
03/22/2023 09:48
BGN9034
0.023
0.002
1
EPA 9056A
03/22/2023 09:48
BGN9034
0.1
0.0428
1
EPA 9056A
03/22/2023 09:48
BGN9034
0.05
0.01
1
EPA 7470A
03/28/2023 15:09
JAA5429
0.005
0.002
1
SW 6010D
03/23/2023 17:17
CELL106
0.05
0.005
1
SW 6010D
03/23/2023 17:17
CELL106
0.05
0.012
1
SW 6010D
03/23/2023 17:17
CELL106
0.01
0.004
1
SW 6010D
03/23/2023 17:17
CELL106
0.005
0.002
1
SW 6010D
03/23/2023 17:17
CELL106
0.02
0.008
1
SW 6010D
03/23/2023 17:17
CELL106
0.005
0.001
1
SW 6010D
03/23/2023 17:17
CELL106
0.005
0.004
1
SW 601OD
03/23/2023 17:17
CELL106
1
0.104
1
SW 6020B
03/23/2023 17:38
MHALL3
1
0.111
1
SW 6020B
03/23/2023 17:38
MHALL3
1
0.249
1
SW 6020B
03/23/2023 17:38
MHALL3
1
0.032
1
SW 6020B
03/23/2023 17:38
MHALL3
1
0.185
1
SW 6020B
03/23/2023 17:38
MHALL3
1
0.077
1
SW 6020B
03/23/2023 17:38
MHALL3
1
0.787
1
SW 6020B
03/23/2023 17:38
MHALL3
1
0.037
1
SW 6020B
03/23/2023 17:38
MHALL3
1
0.18
1
SW 6020B
03/23/2023 17:38
MHALL3
1
0.256
1
SW 6020B
03/23/2023 17:38
MHALL3
1
0.193
1
SW 6020B
03/23/2023 17:38
MHALL3
1
0.035
1
SW 6020B
03/23/2023 17:38
MHALL3
0.2
0.041
1
SW 6020B
03/23/2023 17:38
MHALL3
0.3
0.114
1
SW 6020B
03/23/2023 17:38
MHALL3
25
25
1
SM2540C
03/22/202310:40
EBATIAN

Certificate of Laboratory Analysis Page 11 of 22
This report shall not be reproduced, except in full.
Order # J23030391
Site: ASV_FD-20230321-1 Duplicate Sample #: 2023006942
Collection Date: 03/21/2023 Loc code: ASV FD Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23030321
Chloride 8.2 mg/L
Fluoride 0.0479 U mg/L
Nitrate 0.08 J mg/L
Nitrate as N 0.02 J mg-N/L
Sulfate 0.28 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23030421
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23030355
Barium (Ba)
0.028
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
9.78
mg/L
Iron (Fe)
0.020
mg/L
Lithium (Li)
0.007
mg/L
Magnesium (Mg)
4.63
mg/L
Manganese (Mn)
0.001 J
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23030360
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.304 J
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.448 J
ug/L
Nickel (Ni)
0.265 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.401
ug/L
TOTAL DISSOLVED SOLIDS
- Q23030341
TDS 95.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
03/22/2023 08:43
BGN9034
0.1
0.0479
1
EPA 9056A
03/22/2023 08:43
BGN9034
0.1
0.0209
1
EPA 9056A
03/22/2023 08:43
BGN9034
0.023
0.002
1
EPA 9056A
03/22/2023 08:43
BGN9034
0.1
0.0428
1
EPA 9056A
03/22/2023 08:43
BGN9034
0.05
0.01
1
EPA 7470A
03/28/2023 15:11
JAA5429
0.005
0.002
1
SW 6010D
03/23/2023 17:22
CELL106
0.05
0.005
1
SW 6010D
03/23/2023 17:22
CELL106
0.05
0.012
1
SW 6010D
03/23/2023 17:22
CELL106
0.01
0.004
1
SW 6010D
03/23/2023 17:22
CELL106
0.005
0.002
1
SW 6010D
03/23/2023 17:22
CELL106
0.02
0.008
1
SW 6010D
03/23/2023 17:22
CELL106
0.005
0.001
1
SW 6010D
03/23/2023 17:22
CELL106
0.005
0.004
1
SW 6010D
03/23/2023 17:22
CELL106
1
0.104
1
SW 6020B
03/23/2023 17:46
MHALL3
1
0.111
1
SW 6020B
03/23/2023 17:46
MHALL3
1
0.249
1
SW 6020B
03/23/2023 17:46
MHALL3
1
0.032
1
SW 6020B
03/23/2023 17:46
MHALL3
1
0.185
1
SW 6020B
03/23/2023 17:46
MHALL3
1
0.077
1
SW 6020B
03/23/2023 17:46
MHALL3
1
0.787
1
SW 6020B
03/23/2023 17:46
MHALL3
1
0.037
1
SW 6020B
03/23/2023 17:46
MHALL3
1
0.18
1
SW 6020B
03/23/2023 17:46
MHALL3
1
0.256
1
SW 6020B
03/23/2023 17:46
MHALL3
1
0.193
1
SW 6020B
03/23/2023 17:46
MHALL3
1
0.035
1
SW 6020B
03/23/2023 17:46
MHALL3
0.2
0.041
1
SW 6020B
03/23/2023 17:46
MHALL3
0.3
0.114
1
SW 6020B
03/23/2023 17:46
MHALL3
25
25
1
SM2540C
03/22/202310:40
EBATIAN

Certificate of Laboratory Analysis Page 12 of 22
This report shall not be reproduced, except in full.
Order # J23030391
Site: ASV FB-20230321-1430 Field Blank Sample #: 2023006943
Collection Date: 03/21/2023 02:30 PM Loc code: ASV QA Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23030321
Chloride 0.0154 U mg/L
Fluoride 0.0479 U mg/L
Nitrate 0.03 J mg/L
Nitrate as N 0.01 J mg-N/L
Sulfate 0.0428 U mg/L
MERCURY (COLD VAPOR) IN WATER - Q23030421
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23030355
Barium (Ba)
0.002 U
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
0.012 U
mg/L
Iron (Fe)
0.004 U
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
0.008 U
mg/L
Manganese (Mn)
0.001 U
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS - Q23030360
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.185 U
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.256 U
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.114 U
ug/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
03/22/2023 07:22
BGN9034
0.1
0.0479
1
EPA 9056A
03/22/2023 07:22
BGN9034
0.1
0.0209
1
EPA 9056A
03/22/2023 07:22
BGN9034
0.023
0.002
1
EPA 9056A
03/22/2023 07:22
BGN9034
0.1
0.0428
1
EPA 9056A
03/22/2023 07:22
BGN9034
0.05
0.01
1
EPA 7470A
03/28/2023 15:25
JAA5429
0.005
0.002
1
SW 6010D
03/23/2023 17:26
CELL106
0.05
0.005
1
SW 6010D
03/23/2023 17:26
CELL106
0.05
0.012
1
SW 6010D
03/23/2023 17:26
CELL106
0.01
0.004
1
SW 6010D
03/23/2023 17:26
CELL106
0.005
0.002
1
SW 6010D
03/23/2023 17:26
CELL106
0.02
0.008
1
SW 6010D
03/23/2023 17:26
CELL106
0.005
0.001
1
SW 6010D
03/23/2023 17:26
CELL106
0.005
0.004
1
SW 601OD
03/23/2023 17:26
CELL106
1
0.104
1
SW 6020B
03/23/2023 17:55
MHALL3
1
0.111
1
SW 6020B
03/23/2023 17:55
MHALL3
1
0.249
1
SW 6020B
03/23/2023 17:55
MHALL3
1
0.032
1
SW 6020B
03/23/2023 17:55
MHALL3
1
0.185
1
SW 6020B
03/23/2023 17:55
MHALL3
1
0.077
1
SW 6020B
03/23/2023 17:55
MHALL3
1
0.787
1
SW 6020B
03/23/2023 17:55
MHALL3
1
0.037
1
SW 6020B
03/23/2023 17:55
MHALL3
1
0.18
1
SW 6020B
03/23/2023 17:55
MHALL3
1
0.256
1
SW 6020B
03/23/2023 17:55
MHALL3
1
0.193
1
SW 6020B
03/23/2023 17:55
MHALL3
1
0.035
1
SW 6020B
03/23/2023 17:55
MHALL3
0.2
0.041
1
SW 6020B
03/23/2023 17:55
MHALL3
0.3
0.114
1
SW 6020B
03/23/2023 17:55
MHALL3
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.

Certificate of Laboratory Analysis Page 13 of 22
This report shall not be reproduced, except in full.
Order # J23030391
Level II QC Summary
Q23030321 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Fluoride
0
0
mg/L
1
0.0479
0.1
< MDL
Nitrate
0
0
mg/L
1
0.0209
0.1
< MDL
Sulfate
0.002
0.002
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
4.85
4.85
mg/L
1
0.0154
5
96.9
80
120
Fluoride
4.64
4.64
mg/L
1
0.0479
5
92.8
80
120
Nitrate
4.9
4.9
mg/L
1
0.0209
5
97.9
80
120
Sulfate
4.9
4.9
mg/L
1
0.0428
5
98.1
80
120
MS # 1
Parent Sample:
J23030391
-- 2023006935
Parameter
Measured
Final
Units
Di
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
2.23
11.1
mg/L
5
0.0154
5
97
80
120
Fluoride
4.55
4.55
mg/L
1
0.0479
5
90.7
80
120
Nitrate
5.67
5.67
mg/L
1
0.0209
5
97
80
120
Sulfate
4.95
4.95
mg/L
1
0.0428
5
97.5
80
120
MSD # 1
Parent Sample:
J23030391
-- 2023006935
Parameter
Measured
Final
Units
Dil
MDL
Sake
% Recovery
LCL
UCL
RPD
Qualifier
Chloride
2.21
11.1
mg/L
5
0.0154
5
95.6
80
120
1.45
Fluoride
4.54
4.54
mg/L
1
0.0479
5
90.4
80
120
0.353
Nitrate
5.62
5.62
mg/L
1
0.0209
5
96
80
120
1.06
Sulfate
4.95
4.95
mg/L
1
0.0428
5
97.5
80
120
0.041

Certificate of Laboratory Analysis Page 14 of 22
This report shall not be reproduced, except in full.
Order # J23030391
Level II QC Summary
Q23030421 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.001
0
ug/L
1
0.01
0.05
< MDL
Blank # 2
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.001
-0.001
ug/L
1
0.01
0.05
< MDL
Blank # 3
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.008
-0.001
ug/L
1
0.01
0.05
< MDL
Blank # 4
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.01
0.008
ug/L
1
0.01
0.05
< MDL
Blank # 5
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.01
0.01
ug/L
1
0.01
0.05
= MDL
Blank # 6
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.003
0.01
ug/L
1
0.01
0.05
= MDL
Blank # 7
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.004
0.003
ug/L
1
0.01
0.05
< MDL
Blank # 8
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.004
0.004
ug/L
1
0.01
0.05
< MDL
Blank # 9
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.004
ug/L
1
0.01
0.05
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL Qualifier
Mercury (Hg)
1.8
1.8
ug/L
1
0.01
2
90.3
85
115
LCS # 2
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL Qualifier
Mercury (Hg)
1.75
1.75
ug/L
1
0.01
2
87.3
85
115

Certificate of Laboratory Analysis Page 15 of 22
This report shall not be reproduced, except in full.
Order # J23030391
Level II QC Summary
Q23030421 HG 7470 MERCURY (COLD VAPOR) IN WATER
LCS # 3
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.74
1.74
ug/L
1
0.01
2
87
85 115
LCS # 4
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.75
1.75
ug/L
1
0.01
2
87.5
85 115
MS # 1
Parent Sample:
J23030269 -- 2023006222
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.995
0.995
ug/L
1
0.01
1
99.5
75 125
MSD # 1
Parent Sample:
J23030269 -- 2023006222
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1
1
ug/L
1
0.01
1
100
75 125 0.9
MS # 2
Parent Sample:
J23030269 -- 2023006232
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.98
0.98
ug/L
1
0.01
1
98
75 125
MSD # 2
Parent Sample:
J23030269 -- 2023006232
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1
1
ug/L
1
0.01
1
100
75 125 2.42
MS # 3
Parent Sample:
J23030297 -- 2023006393
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.954
0.954
ug/L
1
0.01
1
95.4
75 125
MSD # 3
Parent Sample:
J23030297 -- 2023006393
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.962
0.962
ug/L
1
0.01
1
96.2
75 125 0.835
MS # 4
Parent Sample:
J23030297 -- 2023006403
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.981
0.981
ug/L
1
0.01
1
98.1
75 125
MSD # 4
Parent Sample:
J23030297 -- 2023006403
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1
1
ug/L
1
0.01
1
100
75 125 2.02
MS # 5
Parent Sample:
J23030297 -- 2023006413
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.719
0.719
ug/L
1
0.01
1
71.9
75 125
M

Certificate of Laboratory Analysis Page 16 of 22
This report shall not be reproduced, except in full.
Order # J23030391
Level II QC Summary
Q23030421
HG 7470
MERCURY (COLD VAPOR) IN WATER
MSD # 5
Parent Sample:
J23030297 -- 2023006413
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.715
0.715
ug/L
1
0.01
1
71.5
75 125 0.558
M
MS # 6
Parent Sample:
J23030368 -- 2023006828
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.838
0.838
ug/L
1
0.01
1
83.8
75 125
MSD # 6
Parent Sample:
J23030368 -- 2023006828
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.84
0.84
ug/L
1
0.01
1
84
75 125 0.238
MS # 7
Parent Sample:
J23030374 -- 2023006868
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.977
0.977
ug/L
1
0.01
1
97.7
75 125
MSD # 7
Parent Sample:
J23030374 -- 2023006868
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.959
0.959
ug/L
1
0.01
1
95.9
75 125 1.86
MS # 8
Parent Sample:
J23030392 -- 2023006944
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.874
0.874
ug/L
1
0.01
1
87.4
75 125
MSD # 8
Parent Sample:
J23030392 -- 2023006944
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.862
0.862
ug/L
1
0.01
1
86.2
75 125 1.38

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23030391
Level II QC Summary
Q23030355 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
0.000041
0.000041
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.00129
0.00129
mg/L
1
0.005
0.05
< MDL
Calcium (Ca)
-0.00121
-0.00121
mg/L
1
0.012
0.05
< MDL
Iron (Fe)
0.000775
0.000775
mg/L
1
0.004
0.01
< MDL
Lithium (Li)
-0.000034
-0.000034
mg/L
1
0.002
0.005
< MDL
Magnesium (Mg)
0.000067
0.000067
mg/L
1
0.008
0.02
< MDL
Manganese (Mn)
-0.000526
-0.000526
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
0.000354
0.000354
mg/L
1
0.004
0.005
< MDL
LCS # 1
Page 17 of 22
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5.36
5.36
mg/L
1
0.002
5
107
80
120
Boron (B)
5
5
mg/L
1
0.005
5
100
80
120
Calcium (Ca)
5.1
5.1
mg/L
1
0.012
5
102
80
120
Iron (Fe)
5.22
5.22
mg/L
1
0.004
5
104
80
120
Lithium (Li)
5.04
5.04
mg/L
1
0.002
5
101
80
120
Magnesium (Mg)
5.13
5.13
mg/L
1
0.008
5
103
80
120
Manganese (Mn)
4.98
4.98
mg/L
1
0.001
5
99.7
80
120
Zinc (Zn)
5.26
5.26
mg/L
1
0.004
5
105
80
120
MS # 1
Parent Sample:
J23030391
-- 2023006936
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5.35
5.35
mg/L
1
0.002
5
106
75
125
Boron (B)
5.02
5.02
mg/L
1
0.005
5
100
75
125
Calcium (Ca)
15.3
15.3
mg/L
1
0.012
5
105
75
125
Iron (Fe)
5.24
5.24
mg/L
1
0.004
5
104
75
125
Lithium (Li)
5.03
5.03
mg/L
1
0.002
5
100
75
125
Magnesium (Mg)
9.55
9.55
mg/L
1
0.008
5
98.3
75
125
Manganese (Mn)
4.93
4.93
mg/L
1
0.001
5
98.6
75
125
Zinc (Zn)
5.18
5.18
mg/L
1
0.004
5
104
75
125
MSD # 1
Parent Sample:
J23030391
-- 2023006936
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
Barium (Ba)
5.45
5.45
mg/L
1
0.002
5
108
75
125
1.78
Boron (B)
5.07
5.07
mg/L
1
0.005
5
101
75
125
0.931
Calcium (Ca)
15.4
15.4
mg/L
1
0.012
5
107
75
125
0.533
Iron (Fe)
5.32
5.32
mg/L
1
0.004
5
105
75
125
1.51
Lithium (Li)
5.12
5.12
mg/L
1
0.002
5
102
75
125
1.73
Magnesium (Mg)
9.63
9.63
mg/L
1
0.008
5
100
75
125
0.897
Manganese (Mn)
5.02
5.02
mg/L
1
0.001
5
100
75
125
1.69
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 18 of 22
This report shall not be reproduced, except in full.
Order # J23030391
Level II QC Summary
Q23030355 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
MSD # 1 Parent Sample: J23030391 -- 2023006936
Parameter Measured Final Units Dil MDL Spike % Recovery LCL UCL RPD Qualifier
Zinc (Zn) 5.25 5.25 mg/L 1 0.004 5 105 75 125 1.36

Certificate of Laboratory Analysis Page 19 of 22
This report shall not be reproduced, except in full.
Order # J23030391
Level II QC Summary
Q23030360 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
-0.034
-0.034
ug/L
1
0.104
1
< MDL
Arsenic (As)
0.028
0.028
ug/L
1
0.111
1
< MDL
Beryllium (Be)
0.047
0.047
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.037
0.037
ug/L
1
0.032
1
> MDL
Chromium (Cr)
-0.008
-0.008
ug/L
1
0.185
1
< MDL
Cobalt (Co)
0.036
0.036
ug/L
1
0.077
1
< MDL
Copper (Cu)
0.036
0.036
ug/L
1
0.787
1
< MDL
Lead (Pb)
0.031
0.031
ug/L
1
0.037
1
< MDL
Molybdenum (Mo)
0.052
0.052
ug/L
1
0.18
1
< MDL
Nickel (Ni)
0.01
0.01
ug/L
1
0.256
1
< MDL
Selenium (Se)
-0.035
-0.035
ug/L
1
0.193
1
< MDL
Silver (Ag)
0.014
0.014
ug/L
1
0.035
1
< MDL
Thallium (TI) Low Level
0.019
0.019
ug/L
1
0.041
0.2
< MDL
Vanadium (V) Low Level
0.011
0.011
ug/L
1
0.114
0.3
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
50.5
50.5
ug/L
1
0.104
50
101
80
120
Arsenic (As)
49.6
49.6
ug/L
1
0.111
50
99.2
80
120
Beryllium (Be)
51.1
51.1
ug/L
1
0.249
50
102
80
120
Cadmium (Cd)
50.4
50.4
ug/L
1
0.032
50
101
80
120
Chromium (Cr)
51
51
ug/L
1
0.185
50
102
80
120
Cobalt (Co)
49.9
49.9
ug/L
1
0.077
50
99.8
80
120
Copper (Cu)
50.2
50.2
ug/L
1
0.787
50
100
80
120
Lead (Pb)
51.4
51.4
ug/L
1
0.037
50
103
80
120
Molybdenum (Mo)
50.9
50.9
ug/L
1
0.18
50
102
80
120
Nickel (Ni)
49.9
49.9
ug/L
1
0.256
50
99.9
80
120
Selenium (Se)
48.4
48.4
ug/L
1
0.193
50
96.9
80
120
Silver (Ag)
50.5
50.5
ug/L
1
0.035
50
101
80
120
Thallium (TI) Low Level
49.7
49.7
ug/L
1
0.041
50
99.3
80
120
Vanadium (V) Low Level
51.1
51.1
ug/L
1
0.114
50
102
80
120
MS # 1
Parent Sample:
J23030391
-- 2023006935
Parameter
Measured
Final
Units
Dil
MDL
alAke
% Recovery
LCL
UCL
Antimony (Sb)
49.1
49.1
ug/L
1
0.104
50
98.3
75
125
Arsenic (As)
47.8
47.8
ug/L
1
0.111
50
95.4
75
125
Beryllium (Be)
47.9
47.9
ug/L
1
0.249
50
95.7
75
125
Cadmium (Cd)
49.5
49.5
ug/L
1
0.032
50
98.9
75
125
Chromium (Cr)
50.1
50.1
ug/L
1
0.185
50
99.5
75
125
Cobalt (Co)
49.2
49.2
ug/L
1
0.077
50
96.7
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23030391
Level II QC Summary
Q23030360 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
Copper (Cu)
50.4
50.4
ug/L
1
0.787
50
Lead (Pb)
50.4
50.4
ug/L
1
0.037
50
Molybdenum (Mo)
50
50
ug/L
1
0.18
50
Nickel (Ni)
49.2
49.2
ug/L
1
0.256
50
Selenium (Se)
48.1
48.1
ug/L
1
0.193
50
Silver (Ag)
49.5
49.5
ug/L
1
0.035
50
Thallium (TI) Low Level
48.3
48.3
ug/L
1
0.041
50
Vanadium (V) Low Level
49.6
49.6
ug/L
1
0.114
50
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
Antimony (Sb)
50.1
50.1
ug/L
1
0.104
50
Arsenic (As)
48.7
48.7
ug/L
1
0.111
50
Beryllium (Be)
49.4
49.4
ug/L
1
0.249
50
Cadmium (Cd)
50.2
50.2
ug/L
1
0.032
50
Chromium (Cr)
50.8
50.8
ug/L
1
0.185
50
Cobalt (Co)
50.4
50.4
ug/L
1
0.077
50
Copper (Cu)
50.6
50.6
ug/L
1
0.787
50
Lead (Pb)
51.3
51.3
ug/L
1
0.037
50
Molybdenum (Mo)
50.7
50.7
ug/L
1
0.18
50
Nickel (Ni)
50.4
50.4
ug/L
1
0.256
50
Selenium (Se)
48.6
48.6
ug/L
1
0.193
50
Silver (Ag)
50.8
50.8
ug/L
1
0.035
50
Thallium (TI) Low Level
49.2
49.2
ug/L
1
0.041
50
Vanadium (V) Low Level
51.2
51.2
ug/L
1
0.114
50
Page 20 of 22
Parent Sample: J23030391 -- 2023006935
% Recovery
LCL
UCL
98.8
75
125
101
75
125
99.8
75
125
96.4
75
125
96.1
75
125
98.9
75
125
96.5
75
125
99.2
75
125
Parent Sample: J23030391 -- 2023006935
% Recovery
LCL
UCL
RPD
100
75
125
1.93
97.3
75
125
2
98.6
75
125
2.96
100
75
125
1.45
101
75
125
1.56
99
75
125
2.4
99.3
75
125
0.515
103
75
125
1.73
101
75
125
1.51
98.7
75
125
2.35
97
75
125
0.955
102
75
125
2.72
98.3
75
125
1.81
102
75
125
3.21
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 21 of 22
This report shall not be reproduced, except in full.
Order # J23030391
Level II QC Summary
Q23030341 TDS TOTAL DISSOLVED SOLIDS
Blank # 1
Blank # 2
Parameter Measured Final
TDS 6.7
Parameter Measured Final
TDS 0
Duplicate # 1
Parameter Measured Final
TDS 351
Duplicate # 2
Parameter Measured Final
TDS 282
LCS # 1
LCS # 2
Parameter Measured Final
TDS 509
Parameter Measured Final
TDS 498
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Parent Sample:
J23020018 -- 2023002238
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
8.31
Parent Sample:
J23030372 -- 2023006851
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
0.354
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
102
90
110
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
99.6
90
110

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
-2 r ,
Duke Energy Analytical Laboratory i
i_._._._._._._._._._._._._._._._._._._._._.-._._.------------------------- Ana cd Labotato Use On_._._._._._._._._._.-._._._._._._._._._._._._._.-.-._._._._._._._._._._._i
Page 22 of 22
Order ) Matrix WATER
DUKE�!
Mao CodeM007A3 (Buading74ea) i
t"'°Ale.
saa,awagx,m,y.mm NC X_ ! Page_t_of 1_
6C_
ENERGY.
N.C.F.f
Hmla(704)2 N.. tB07a
DISTRIBUTION
itoggad B Da a pm
pa)a7e•st4s !
SAMPLE PROGRAM i ORIGINAL to LAB, COPY to CLIENT
F?!Ll>°!1>n?�4 _._. !
! L
Ground Water_X_ NPDES_ !
Drinking Water_ UST
Project Name ASHEVILLE STATE LF DETECTION
Phme No:
i Vendor
MONITORING
i
r
RCRA Waste _
Client: HEALY ASHLEY, BRYAN MOELLER, BEE 'Po s
O'BRIEN, JOSH STOWE, CONNOR ZAHORA ! i Filtration (0.46 um)
b
Unfiltered
b
Filtered
Operating Unit: AE00 Process:NGRDWiR Account: Preservative
ICE
ICE
Project: AAE000315 Activity ID: Facility ID:ASV Container Volume (mL)
Soo
300
Soo
250
Program ! EQuiS Task Code:ASV LF Sub-Program/Task Code: Container Type
PET
PET
HDPE
HOPe
ANIONS by
(Metals Prep - TRM) ICP -
O _
p o tO Z
" a
C
i c
-
9056A: Cl, F,
SW601OD: Be, B, Ca, Fe, Li,
w m
> o a
5
m
p appropriate non -shaded areas- z w
Customer to complete all a
Sample Description or ID a a
p
TDS
-
NO3-N'(46-Hr
Mg, Mn, Zn (5) / Hg EPA 7470A
/ IMS-SW602OB: Sb, As, Be,
u0i O O a
°
p
i- - - -- - - -- i
Hold Time),
Cd, Cr, Co, Cu, Pb, Mo, Ni, Se,
< y
a
SAMPLE ID Collection Information
i E 'a
SO4
All, TI, V (14)
W c d
e
NUMBER i Date Time Printed Name Signature
^I 0
H
ASV_
3-21-113
0830
COU VM-Ml.+ortA
�j�
0
3
ASV_ LAW-1
o
3
Asv_ LMrw - S
o950
><
I
C,
!.�
Asv_ LtAW
toss
L
3<
t
m
Asv_ L 1AUJ I f1
ills
vr
yyd
ASV_ LMw - 2 f3
I to
r
t
o
rfy�
ASV_LMW -
i b
r
t
o
ASV
ASV
ASV_
!.
ASV
ASV
ASV_
ASV_
•.
ASV
jyz
ASV_ Fa-2owsow-t
3-21-z3
—
COW-04 AK
Z
/,,�,
vas `_
x
t
t
o
3
yy�
ASV_
Ir
e
t
I
o
Z
ASV
!
TOTAL M CONTAINERS
0
0
0
0
0
0
0
0
0
0
0
0
1 0
1 0
Customer to sign ate be]ow
Relinquished By / DateTT' a
Accepted By:
Requested Turnaround
rota� 0
Relinquished By femme
Acce d By: Date/Time
_ z
a v
A�
a
••
21 Days
14 Day.,
Relinquished By Daterrime
Accepted By: DatelTime
c E
Y E
Seal/Locked By Date/Time
Sealed/Lock Opened By DatelTime
n L
7 Days
E -
_
� O
Comments
STATE EDD REQUIRED / EQUIS REQUIRED ****DISSOLVED METALS: Be, Cd, Cr, Cu, Pb, NI, Ag, Zn Note: Hardness by Calculation (Ca + Mg ICP_TRM) added to SW-#, DP-4, and LCS-1
E
'Cther
Leachate
m
U
' Add, Cost Will Apply

Analytical Data Review Checklist - Aqueous
Facility/Site
Asheville Steam Electric Plant
State
NC
Location/Sample IDs
CB-9, LMW-1B, LMW-IS, LMW-2B, LMW-2T, LMW-3B, LMW-4B
References:
- ELN/A
❑v 1 ❑
Duke Central Lab
Lab Report ID Sample Date Sample Receipt Date Analysis Complete Date 0 Groundwater
/23030391 3/21/2023 3/22/2023 4/5/2023 ❑ Surface water
❑ Other
National Functional Guidelines for Inorganic Superfund Methods Data Review (USEPA 2020)
Guidance on Environmental Data Verification and Data Validation (USEPA 2002)
Radiochemical Data Verification and Validation (MARLAP 2004)
� Sample Receipt and Chain of Custody
1) Do the sample IDs and laboratory analyses recorded on the Chain of Custody match the sample IDs and analyses listed in the laboratory package?
❑�
❑
❑
la) Do the dates and times of sampling listed on the Chain of Custody match the laboratory report?
0
❑
❑
❑
❑
❑�
2) Is the sample temperature upon receipt at the laboratory recorded on the Chain of Custody form less than 6 degrees Celsius? If NO, then:
2a) Was the presence of wet ice noted in the cooler? OR
❑
❑
❑�
2b) Were the samples collected less than two hours prior to receipt at the lab?
❑�
❑
❑
3) Was the proper sample preservation checked and documented on the Chain of Custody or sample receipt form?
❑
❑�
❑
4) Are there any special notes, exceptions, and/or anomalies listed either on the Chain of Custody or sample receipt form?
❑
❑v
❑
15) Was the transfer of custody of the samples properly documented and traceable through signature, date, and time by all persons who relinquished and/or received
custody of the samples?
❑
7❑�❑
❑ ❑�
®®Batch
6) Do the values for the field parameters listed on the Chain of Custody match the values entered in the lab report?
eAssurance/Quality
7) Was the holding time for preparation and/or analysis met for each parameter?
❑
❑�
7a) Total Alkalinity, Bicarbonate Alkalinity, Carbonate Alkalinity: Analyzed within 14 days of collection
❑
❑
7b) Bromide, Chloride, Fluoride, and Sulfate (Anions): Analyzed within 28 days of collection
❑
❑
l]
7c) Sulfide: Analyzed within 7 days of collection
0
❑
❑
7d) TOC and/or Nitrate -Nitrite: Analyzed within 28 days of collection
❑
❑
l]
7e) Total Phosphorus (TP) and Dissolved TP: Analyzed within 28 days of collection
❑
❑
(]
7f) Hexavalent Chromium: Analyzed within 24 hours (unpreserved) / 28 days (preserved) of collection
0
❑
❑
7g) Mercury and Dissolved Mercury: Analyzed within 28 days of collection (preserved)
0
❑
❑
7h) Total and Dissolved Metals: Analyzed within 180 days of collection
0
❑
71) TSS and TDS: Analyzed within 7 days of collection
❑
❑
0
7J) Radionuclides: Analyzed within 180 days of collection
❑
❑
❑
❑
I]
0
7k) Methane: Analyzed within 14 days (preserved) / 7 days (unpreserved) of collection
71) Oil and Grease: Analyzed within 28 days of collection
❑�
❑
❑
8) Are there any qualifiers assigned by the laboratory and if so, are the qualifier definitions provided?
❑
0
9) Method Blank- Were any parameters detected in the method blank(s)?
❑
❑
9a) If YES, were any target analyses detected in the samples at concentrations less than ten times the method blank concentration?
❑
❑
❑�
❑
❑
)]
10) Laboratory Control Sample - Were any parameters flagged by the lab as being outside the limits of control in the associated laboratory control sample (LCS)?
1 Do) If YES, was the parameter recovery less than 50 percent or greater than 150 percent?
❑
❑
2
10b) Were the some parameters detected in the samples?
❑�
❑
❑
11) Matrix Spike Sample - Did the laboratory provide matrix spike results (MS/MSD)? If so, then:
❑�
❑
❑
111a) Was the original sample spiked a project sample? If so, then:
❑
❑�
❑
11 b) Were any parameters flagged by the lab as being outside the limits of control in the associated matrix spike sample?

Batch
7❑!Assurance/Quality
0 ❑ ❑ 12) Laboratory Duplicate Sample - Did the laboratory provide lab duplicate sample results? If so, then:
0 ❑ 12a) Was the sample analyzed as a laboratory duplicate a project sample? If so, then:
❑ ❑ 0 12b) Were any parameters flagged by the lab as being outside the limits of control in the laboratory duplicate sample?
0 ❑ ❑ 13) Field Duplicate Sample - Is the relative percent difference between the parent and field duplicate sample results greater than 35 percent?
0 ❑ ❑ 14) Field/Equipment/Trip Blanks - Were any parameters detected in the associated field, equipment, and/or trip blanks?
0 ❑ ❑ 14a) If yes, were any target analytes detected in the samples at a concentration less than ten times the Field/Equipment/Mia Blank concentration?
❑v
❑ ❑ 15) Were initial and continuing calibration blank information within acceptable criteria per the lab report?
❑
❑� ❑ 16) Were any reporting limits for diluted, non -detect results greater than the screening criteria?
❑ ❑ 17) Radionuclides: Are quality control sample results provided?
❑ ❑ ❑� 17a) Are any results flagged or qualified?
❑ ❑ ❑° 17b) Are Uncertainty, MDC, Tracer/ and/or Carrier% provided for each sample?
The questions on this checklist refer to basic review of laboratory analytical reports for completeness and accuracy of data. Any responses requiring follow up action with the analytical lab or field personnel must be
noted in the summary section at the end of this form before the data can be approved for use by technical leads.
Lab Qualifiers:
J (Duke) -Analyte detected above the MDL, but below the RL; analyte concentration should be considered an estimate.
7
M (Duke) - MS and/or MSD recovery was outside of the control limits; the associated LCS recovery was acceptable. (This qualifier is for a non -project QC sample.)
U (Duke) -Analyte was analyzed for, but not detected above the MDL.
Validation Qualifiers:
R- Result is unusable. The sample result is rejected due to serious deficiencies in meeting quality control criteria; the analyte may or may not be present in the sample.
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
U-Analyte was analyzed form but not detected above the minimum detectable concentration (MDC) or method detection limit (MDL).
B -Target analyte detected in the method blank an in the sample at a concentration less than 10x the blank concentration.
• The RPD between LMW-113 and the field duplicate is greater than 35% for Iron (0.068/0.020 mg/L).
• Nitrate (0.03 mg/L) and Nitrate as N (0.01 mg-N/L) were detected in the Field Blank; Nitrate and Nitrate as N were also detected in the samples at concentrations less than lox the blank
concentrations.
Review Determination: ❑ Usable 0 Usable with Required Actions ❑ Unusable
Signatures: Date:
Data Quality Reviewer REB 4/20/2023
Technical Lead KHF 7/6/2023