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HomeMy WebLinkAbout3901_Granville_Oxford_MSWLF_CDLF_Unit1_Sept22GW_FID1771755_20230201hart 'L hickman ■ SMARTER ENVIRONMENTAL SOLUTIONS Via E-Mail sbray@garTett-moore.com January 30, 2023 Garrett & Moore, Inc. 1029 West South Street Raleigh, NC 27603 Attn: Mr. Stefan Bray, PE Re: Water Quality Monitoring Report — September/October 2022 Granville County Oxford Unit 1 Landfill Oxford, Granville County, NC Facility Permit No. 3 901 -CDLF- 1997 H&H Job No. GMI-004 Dear Stefan: Hart & Hickman, PC (H&H) is submitting the attached Water Quality Monitoring Report — September/October 2022 documenting sample results for the Oxford Unit 1 Landfill for the second semiannual sampling event of 2022. H&H appreciates the opportunity to work with you on this project. If you have any questions or require additional information, please do not hesitate to contact us at 704-586-0007. Very truly yours, Hart & Hickman, PC Jason Soban, PG Project Manager Jeffrey 011ison Project Environmental Scientist 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 704_S86.0007 main 3921 Sunset Ridge Rd, Suite 301 Raleigh, NC 27607 www.harthickman.com 919.847.4241 main I E] NR USE. ohs ;� ©Paper Report ❑Electronic Data - Email CD. data loaded: Yes / No Doc/Event #: 'NC DENR Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are 'Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6) Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards The notification must include a preliminary analysis of the cause and significance of each value_ (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i) Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646_ Solid Waste Mo.n"ftoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Garrett & Moore, Inc. Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Stefan Brav Phone: 919-792-1903 E-mail: sbray@garrett-moore.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Granville County 15854 Landfill Road September 29 & October 5, Oxford Landfill Unit 1 Oxford, NC 27565 3901-CDLF-1997 .1600 2022 Environmental Status: (Check all that apply) Initial/Background Monitoring Detection Monitoring Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells ❑X Leachate monitoring data ❑ Surface water monitoring data Methane gas monitoring data Corrective action data (specify) MINA Parameters Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Jason Soban, PG Consultant for Facility (704) 887-4622 Facility Representative Name (Print) Title (Area Code) Telephone Number I -SO Affix NC Licensed/ Professional Geologist Seal Signature Date 2923 S Tryon Street, Suite 100, Charlotte, NC 28203 Facility Representative Address C-1269 (Engineering) 245 (Geology) NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 ►,»a�tCA rr�,el4r�pry� 2, SEAL 2318 %j'a���i4 L�71,••rlS�ea �I+`��f�+r �ef�eRi�re�n►�+'���eg� Water Quality Monitoring Report September/October 2022 Granville County Oxford Unit 1 Landfill Oxford, North Carolina Permit No. 3901-CDLF-1997 H&H Job No. GMI-004 January 30, 2023 GARRETT &MOOREEP22 Engineering for the POMF and WasN Industries hart � hickman SMARTER ENVIRONMENTAL SOLUTIONS 2923 South Tryon Street, Suite 100 3921 Sunset Ridge Rd , Suite 301 Charlotte, NC 28203 Raleigh, NC 27607 www.harthickman.com 704.586.0007 main 919,847.4241 main Water Quality Monitoring Report — September/October 2022 Granville County Oxford Unit 1 Landfill Oxford, North Carolina Permit No. 3901-CDLF-1997 H&H Job No. GMI-004 Table of Contents Section Pate 1.0 Introduction.................................................................................................................I 1.1 Site Information........................................................................................................1 1.2 Regulatory Status......................................................................................................2 1.3 Groundwater Monitoring Program...........................................................................4 1.4 Surface Water Monitoring Program.........................................................................5 2.0 Water Quality Monitoring Activities........................................................................7 2.1 Water Level Measurements......................................................................................7 2.2 Groundwater Sampling Methods..............................................................................7 2.3 Surface Water Sampling Methods............................................................................8 2.4 Sample Equipment Management..............................................................................8 2.5 Sample Handling and Laboratory Analyses.............................................................9 3.0 Water Quality Monitoring Results..........................................................................10 3.1 Groundwater Flow and Hydraulic Gradient...........................................................10 3.2 Groundwater Analytical Results.............................................................................11 3.3 Surface Water Analytical Results...........................................................................12 3.4 Quality Assurance/Quality Control Results............................................................13 4.0 Corrective Action Evaluation..................................................................................15 4.1 Monitored Natural Attenuation Parameters............................................................15 4.2 Evaluation of Plume Stability and Trends..............................................................15 5.0 Conclusions ................................................................................................................18 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 hart h i c km a n Second Half GWM/GMI.004 Granville County Oxford Unit 1_WQMR Sept 2022.docx P. SMARTER ENVIRONMENTAL SOLUTIONS List of Tables Table 1 Summary of Well Construction Details Table 2 Summary of Groundwater Elevations Table 3 Summary of Field Parameters Table 4 Summary of Groundwater Flow Velocity Table 5 Summary of Groundwater and Surface Water Analytical Results Table 6 Summary of Monitored Natural Attenuation Parameters List of Figures Figure 1 Site Location Map Figure 2 Site Plan Figure 3 Groundwater Potentiometric Map (September 29, 2022) List of Appendices Appendix A Groundwater and Surface Water Sampling Records Appendix B Laboratory Analytical Reports Appendix C Summary of Historical Groundwater Elevations Appendix D Summary of Historical Constituents in Groundwater Appendix E Summary of Historical Constituents in Surface Water Appendix F Summary of Historical Monitoring Natural Attenuation Parameters Appendix G Concentration vs. Time Charts ii https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 -Granville Co. Oxford LF Unit 1/2022 ■ Second Half GWM/GMI.004 Granville County Oxford Unit 1_WQMR Sept 2022.docx hart : h i C km a n SMARTER ENVIRONMENTAL SOLUTIONS Water Quality Monitoring Report — September/October 2022 Granville County Oxford Unit 1 Landfill Oxford, North Carolina Permit No. 3901-CDLF-1997 H&H Job No. GMI-004 1.0 Introduction This Water Quality Monitoring Report (Report) has been prepared by Hart & Hickman, PC (H&H) to document the methods and results of semi-annual groundwater and surface water monitoring activities conducted at the Granville County Oxford Unit 1 Landfill located at 6584 Landfill Road, Oxford, Granville County, North Carolina. A site location map is included as Figure 1. Water quality monitoring at the site was performed in general accordance with the Corrective Action Plan (May 2005) and Water Quality Monitoring Plan (March 2019) which were approved by the North Carolina Department of Environmental Quality (DEQ) Solid Waste Section (SWS). 1.1 Site Information The Granville County Oxford Landfill consists of two separate waste disposal units (Unit 1 and Unit 2). The facility is owned and operated by Granville County under Permit Numbers 3901- CDLF-1997 (Unit 1) and 3901-MSWLF-2012 (Unit 2) issued by DEQ SWS. The permitted facility consists of approximately 283 acres, of which approximately 29 acres constitutes the Unit 1 waste unit and 37.3 acres constitutes the Unit 2 waste unit. A site layout map that depicts the facility features is included as Figure 2. The subject Oxford Unit 1 Landfill is a former unlined municipal solid waste (MSW) landfill originally permitted for disposal of domestic, institutional, industrial, agricultural, and demolition wastes. The Oxford Unit 1 Landfill was closed in 1997. Between 1997 and 2017, the facility disposed of construction and demolition (C&D) waste on top of the closed MSW landfill in accordance with the Transition Plan dated 1994. The Oxford Unit 2 Landfill is a Subtitle-D MSW landfill which was permitted to operate in February 2013 and began receiving waste in May 2013. This report covers water quality monitoring conducted at the Oxford Unit 1 Landfill. A separate Water Quality Monitoring Report will be submitted for the Oxford Unit 2 Landfill. 1 https://harthick.shmepoint.com/sites/MwtuFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/GMI.004 Granville County Oxford Unit 1_WQMR Sept 2022.docx Ad hart hickman SMARTER ENVIRONMENTAL SOLUTION5 1.2 Regulatory Status The Oxford Unit 1 Landfill has remained in an Assessment Monitoring Program since 1995 due to detections of volatile organic compounds (VOCs) above the North Carolina 2L Groundwater Standards (2L Standards). In 2003, benzene (MW-4R) and vinyl chloride (MW-5) were detected in site groundwater at concentrations above their respective 2L Standards. Benzene has not been detected above its 2L Standard since 2003. Vinyl chloride has been detected above its 2L Standard from 2003 to present. Granville County received a letter from DEQ dated August 20, 2003, that requested to proceed with assessment activities at the Oxford Unit 1 Landfill. An overview of the site regulatory status including changes to the monitoring program is provided below. 2003 through 2005 Nature and Extent Study and Assessment of Corrective Measures An Assessment of Corrective Measures (ACM) and Nature and Extent Study (NES) were initiated in 2003 due to 2L Standard exceedances of benzene (MW-4R) and vinyl chloride (MW-5R) in site groundwater. In May 2005, Granville County submitted an NES, ACM, and a Quantitative Risk Assessment (QRA) as required by DEQ. Granville County held a public meeting for the ACM on August 21, 2006. 2008 through 2010 Corrective Action Plan A Corrective Action Plan (CAP) was submitted in June 2008, with revisions in October 2008 and March 2009. The CAP proposed Monitored Natural Attenuation (MNA) as the primary remedy, supplemented with Control of Decomposition Gasses as a secondary remedy. The CAP was approved by DEQ on April 23, 2009. The gas interception trench was installed in July 2009. The last sampling event for the Baseline MNA was completed in December 2010. 2010 Alternate Source Demonstration for Iron and Manganese An Alternate Source Demonstration (ASD; dated October 26, 2010) for Iron and Manganese was submitted to DEQ after the requirements for additional constituent monitoring for C&D facilities showed elevated concentrations of iron and manganese across multiple site wells in June 2010. The ASD showed that the concentrations of iron and manganese were a result of natural occurrence 2 14 hart hickman https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/GMI.004 Granville County Oxford Unit 1_WQMR Sept 2022.docx SMARTER ENVIRONMENTAL SOLUTIONS in site soil and not a release from the landfill. The ASD for Iron and Manganese was approved by DEQ on June 9, 2011. 2010 First Corrective Action Evaluation Report The first Corrective Action Evaluation Report (CAER) was submitted to DEQ on November 29, 2010, and approved by DEQ on January 27, 2011. Based on the data presented in the CAER, DEQ denied a request to remove some of the MNA parameters but approved a reduced alternate monitoring frequency as follows; carbon dioxide, ferrous iron, volatile fatty acids, total organic carbon (TOC), sulfide, and dissolved ethane and ethene for every third year on a semi-annual basis. DEQ also approved removing benzene and cis-1, 2-dichloroethene from the constituent of concern (COC) list and adding 1,1-dichloroethane. An ASD for chromium, thallium, and total dissolved solids (TDS) in MW-IA was included in the 2010 CAER and was also approved by DEQ. 2012 COC List Update In February 2012, beta-BHC was added to the COC list due to a confirmed exceedance during the December 2011 sampling event. 2014 Monitoring Program Changes Changes to the monitoring program were requested in a letter submitted to DEQ on May 22, 2014. The following changes were approved by DEQ in their June 3, 2014 response letter: monitoring wells MW-2, MW-3R, MW-4R, and MW-6R reverted back to detection monitoring (Appendix I constituents) from assessment monitoring (Appendix II constituents); NES-1 S and NES- I D were removed from the groundwater corrective action monitoring network; and, sampling for MNA parameters in monitoring wells MW-3RR and MW-4R was discontinued. 2015 Second Corrective Action Evaluation Report The second CAER was submitted to DEQ on July 10, 2015, and approved by DEQ on July 30, 2015. The DEQ approval included the removal of 1,1-dichloroethane and beta-BHC from the COC list due to the lack of recent exceedances. This left vinyl chloride as the only COC for the facility. 3 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/GMI.004 Granville County Oxford Unit 1_WQMR Sept 2022.docx 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS 2018 and 2019 Water Quality Monitoring Plan A Water Quality Monitoring Plan (WQMP) for the Oxford Landfill Units 1 and 2 was submitted to DEQ in January 2018 and revised in March 2019. The WQMP describes the sampling protocols for groundwater and surface water monitoring at the site. The WQMP included 1,4-dioxane as a COC due to a confirmed exceedance during the August 2018 sampling event. 2020 Third Corrective Action Evaluation Report The third CAER was submitted to DEQ on June 5, 2020, and approved by DEQ on June 22, 2020. The DEQ approval included the removal of Biochlor modeling since site constituents have changed from anaerobic to aerobic, and the modification of the sampling frequency of the MNA parameters sulfide, volatile fatty acids, TOC, dissolved carbon dioxide, ferrous iron, ethane, and ethene to two events every five years corresponding to the two events immediately prior to the due date of the next five year CAER. 1.3 Groundwater Monitoring Program The groundwater monitoring program at the Oxford Unit 1 Landfill consists of the following six monitoring wells: MW-2, MW-3RR, MW-4R, MW-5R, MW-6R, and MW-7. Monitoring well MW-7 is located southeast of the landfill and serves as a background location. The compliance network consists of monitoring wells MW-2, MW-3RR, MW-4R, MW-5R, and MW-6R which are situated around the perimeter of the landfill. Monitoring well MW-1 A (a former background well) is only monitored for groundwater elevations. In addition, performance well NES-2S and sentinel well NES-213 are located downgradient of the landfill and sampled under the CAP for the facility. Monitoring well NES-2S is also a compliance well for the Oxford Unit 2 Landfill and MW-7 is a background well for Oxford Unit 2. The monitoring well locations and other site features are identified in Figure 2. A summary of well construction details is provided in Table 1. Groundwater samples are collected semi-annually (with the exception of NES-21) only sampled annually) for select analyses per the WQMP. Sample analyses include North Carolina Solid Waste Management Rules Appendix I and/or Appendix II constituents (hereafter referred to as Appendix 4 14 hart hickman https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/GMI.004 Granville County Oxford Unit 1_WQMR Sept 2022.docx SMARTER ENVIRONMENTAL SOLUTIONS I constituents and Appendix II constituents, respectively), select C&D parameters (alkalinity, chloride, iron, manganese, mercury, sulfate, total dissolved solids [TDS], tetrahydrofuran, pH, temperature, and specific conductance), and/or COCs (i.e., 1,4-dioxane and vinyl chloride). Note the required Appendix II sample analysis for each groundwater monitoring well during the second half semi-annual event varies, and the required second half semi-annual analysis consist of those analytes detected in that well during the first half semi-annual event each year. As noted above, the site's full list of MNA parameters is collected during two events every five years corresponding to the two events immediately prior to the due date of the next five-year CAER (i.e., second half event 2024 and first half event 2025). However, a reduced list of MNA parameters (alkalinity, chloride, dissolved hydrogen, dissolved methane, nitrate, sulfate, pH, temperature, specific conductance, oxidation reduction potential [ORP], turbidity, and dissolved oxygen [DO]) are collected semi-annually from select monitoring wells (NES-2S, MW-5R, and MW-7) and annually from the sentinel well (NES-21)). A summary of the well locations and sample analyses for the semi-annual sampling events is provided below. Well ID Classification First Half Analyses Second Half Analyses MW-IA Observation Not Sampled Not Sampled MW-2 Compliance App. I + App. II, C&D App. I + App. II Det., C&D MW-3RR Compliance App. I + App. II, C&D App. I + App. II Det., C&D MW-4R Compliance App. I + App. II, C&D App. I + App. II Det., C&D MW-5R Compliance App. I + App. II, C&D, MNA App. I + App. II Det., C&D, MNA MW-6R Compliance App. I + App. II, C&D App. I + App. II Det., C&D MW-7 Background App. I + App. II, C&D, MNA App. I + App. II Det., C&D, MNA NES-2S Performance COCs, MNA COCs, MNA NES-21) Sentinel COCs, MNA Not Sampled 1.4 Surface Water Monitoring Program The surface water monitoring program at the Oxford Unit 1 Landfill consists of collecting samples from two locations which are located upstream (SW-1) and downstream (SW-2) of the waste unit. Sampling point SW-1 is located in a sedimentation basin near the upgradient southeast corner of 5 14 hart hickman https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/GMI.004 Granville County Oxford Unit 1_WQMR Sept 2022.docx SMARTER ENVIRONMENTAL SOLUTIONS Unit 1. Sampling point SW-2 is located downgradient and southeast of Unit 1 along an unnamed tributary to Little Grassy Creek. Little Grassy Creek is classified as a Class C (Aquatic Life and Secondary Recreation) stream. The locations of the surface water monitoring points are identified in Figure 2. Surface water samples are collected semi-annually and analyzed for Appendix I constituents plus 1,4-dioxane. 0 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/GMI.004 Granville County Oxford Unit I_WQMR Sept 2022.docx 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS 2.0 Water Quality Monitoring Activities 2.1 Water Level Measurements On September 29, 2022, H&H measured depth -to -water and total depths in monitoring wells MW- IA, MW-2, MW-3RR, MW-4R, MW-5R, MW-6R, MW-7, NES-2S, and NES-213. Depth -to - water measurements were collected from the top -of -casing utilizing a decontaminated electronic water level indicator. Depth -to -water measurements were made after the wells were opened for a sufficient period of time to allow water levels to equilibrate with atmospheric pressure. Water level measurements and calculated groundwater elevations are presented in Table 2. 2.2 Groundwater Sampling Methods On September 29 and October 5, 2022, H&H collected groundwater samples from site monitoring wells MW-2, MW-3RR, MW-4R, MW-5R, MW-6R, MW-7, and NES-2S. Groundwater sampling activities began on September 29, 2022; however, due to severe weather conditions related to a tropical storm the sampling event was completed on October 5, 2022. Monitoring well MW-7 serves as the upgradient background well for the facility, and monitoring wells MW-2, MW-3RR, MW-4R, MW-5R, MW-6R, NES-2S, and NES-213 serve as compliance monitoring wells. In accordance with the WQMP, monitoring well NES-213 is sampled annually and sampling at this location was completed during the first half semi-annual event in February 2022. The groundwater samples were collected and handled in accordance with the sampling protocols included in the site WQMP as well as the DEQ SWS Guidelines for Groundwater, Soil, and Surface Water Sampling document. Monitoring wells were purged utilizing a peristaltic pump under low flow (< 200 milliliters/minute) conditions. Water levels were recorded during the purging process to ensure the pump rate did not cause significant drawdown of the water column, and samples were collected following the stabilization of field parameters over three consecutive readings. Field measurements of pH, temperature, specific conductance, ORP, and DO were measured using a YSI Pro Plus or YSI 556 water quality meter. Turbidity was measured using a HF Scientific Micro 7 14 hart hickman https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/GMI.004 Granville County Oxford Unit 1_WQMR Sept 2022.docx SMARTER ENVIRONMENTAL SOLUTIONS TPI or Hach 2100Q turbidity meter. A summary of the final field parameters recorded prior to sample collection are presented in Table 3. Copies of groundwater sampling forms containing pertinent information recorded in the field during purging and sampling at each monitoring well are provided in Appendix A. The results of the field -measured water quality parameters indicate that the values measured in groundwater collected from site monitoring wells were within applicable stabilization criteria. Groundwater at the site is acidic based on the pH values measured in the field (5.52 to 6.99 Standard Units). Specific conductance values ranged from 71 (MW-2) to 1,048 (MW-6R) microsiemens per centimeter (µS/cm) in groundwater at site monitoring wells. Turbidity values ranged from 0.32 (MW-5R) to 67.9 (MW-2) nephelometric turbidity units (NTUs). The collected groundwater sample from MW-2 exhibited a turbidity above the target level of 10 NTU; however, considerable time was spent purging the well at a low flow rate to achieve a lower turbidity sample, and the turbidity level in the well was generally stable at the time of collection. 2.3 Surface Water Sampling Methods On September 29, 2022, H&H collected surface water samples from sample locations SW-1 and SW-2 (Figure 2). Surface water samples were collected in general accordance with the WQMP as well as the DEQ SWS Guidelines for Groundwater, Soil, and Surface Water Sampling document. Field parameters were measured during sample collection and copies of surface water sampling forms are provided in Appendix A. A summary of field parameters recorded prior to sample collection is provided in Table 3. 2.4 Sample Equipment Management All reusable sampling equipment (e.g., water level indicator) was properly decontaminated between sampling locations with a non -phosphate soap and water wash, followed by multiple rinses with distilled water. New disposable nitrile or latex gloves were worn during all sampling activities. Disposable sampling equipment/material was discarded after each use. 8 14 hart hickman https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/GMI.004 Granville County Oxford Unit 1_WQMR Sept 2022.docx SMARTER ENVIRONMENTAL SOLUTIONS 2.5 Sample Handling and Laboratory Analyses Upon sample collection, samples for laboratory analysis were placed directly into dedicated laboratory -supplied sample bottles, labeled, and placed into ice -filled coolers. A chain -of -custody record was completed and included sample description, analyses required, matrix, sample container information, and date and time of sample collection. The samples were transported on ice, under standard protocol, to Pace Analytical Services, Inc. (Pace) in Huntersville, North Carolina. Pace is a North Carolina -certified laboratory. The laboratory analytical reports and chain -of -custody records for the September/October 2022 sampling event are included in Appendix B. A summary of samples collected during the subject reporting period is provided below. The groundwater samples from monitoring wells MW-2R, MW-3RR, MW-4R, and MW-6R were analyzed for Appendix I constituents plus 1,4-dioxane and C&D parameters. The groundwater samples from monitoring wells MW-5R and MW-7 were analyzed for Appendix I constituents plus 1,4-dioxane, C&D parameters, and MNA parameters. In accordance with the WQMP, groundwater samples (with the exception of NES-2S and NES-21)) are also analyzed for Appendix II constituents previously detected during the first half semi-annual monitoring event; however, no Appendix II constituents were detected during the first half 2022 monitoring event; therefore, no analysis for Appendix II constituents was completed for the second half 2022 monitoring event. The groundwater samples from NES-2S were analyzed for COCs (i.e., vinyl chloride and 1,4- dioxane) and MNA parameters. The surface water samples from SW-1 and SW- 2 were analyzed for Appendix I constituents plus 1,4-dioxane and hardness. 0 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/GMI.004 Granville County Oxford Unit 1_WQMR Sept 2022.docx 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS 3.0 Water Quality Monitoring Results Groundwater and surface water monitoring activities were conducted at the site on September 29 and October 5, 2022. Groundwater and surface water samples were collected and analyzed in accordance with the DEQ approved CAP, changes to the CAP documented in DEQ approved CAERs (November 2010, July 2015, and June 2020), and the DEQ approved WQMP (March 2019). The monitoring results are discussed in the following sections. 3.1 Groundwater Flow and Hydraulic Gradient A summary of monitoring well gauging and water level elevation data is provided in Table 2. Historical groundwater elevation data is provided in Appendix C. Groundwater flow direction, average hydraulic gradient, and average interstitial flow velocity were derived from water -level measurements recorded during the September/October 2022 sampling event. A potentiometric map generated from the September 29, 2022 gauging event is provided as Figure 3. The September 2022 water levels were similar to historical seasonal fluctuations observed at the site. Consistent with historical trends, the overall direction of shallow groundwater flow at the site is generally to the north to northeast towards an unnamed tributary to Little Grassy Creek. The hydraulic gradient in the vicinity of each well was derived by dividing the elevation difference between water table elevations measured at the monitoring wells and proximal potentiometric contour lines, by the perpendicular horizontal distance between the wells and potentiometric contours (Figure 3 and Table 4). The potentiometric contours indicate an average hydraulic gradient of approximately 0.0094 ft/ft. Results of in -situ slug testing reported by others (LaBella Associates, 2021) indicate an average hydraulic conductivity value in the shallow surficial aquifer of approximately 7.31 x 10-2 feet/day (approximately 26.7 feet/year). Using the horizontal hydraulic gradient measurements, the individual estimate of hydraulic conductivity, and an assumed effective porosity of 0.31 (LaBella Associates, 2021), the range of average interstitial groundwater flow velocities for the shallow surficial aquifer was calculated using the following equation: Vx = (K/ne) x dh/dl. 10 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/GMI.004 Granville County Oxford Unit 1_WQMR Sept 2022.docx 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS Where: Vx = average interstitial groundwater flow velocity; K = hydraulic conductivity; ne = effective porosity; and, dh/d1= horizontal hydraulic gradient Average linear flow velocities are estimated to range between approximately 0.02 to 3.45 feet/year (approximately 0.0001 to 0.0094 feet/day), with a geometric mean of 0.81 feet/year (0.0022 feet/day). These values are generally consistent with prior monitoring events. Table 4 summarizes the data used to calculate the average interstitial groundwater flow velocity in the vicinity of each monitoring well. 3.2 Groundwater Analytical Results Semi-annual groundwater sampling consisted of collecting samples from seven site monitoring wells. A summary of groundwater constituent detections from the September/October 2022 sampling event is provided in Table 5. Historical analytical results are presented in Appendix D. Consistent with the CAP and subsequent changes documented in DEQ approved CAERs, the primary COCs for the site include 1,4-dioxane and vinyl chloride. A summary of groundwater results for site COCs and other exceedances is provided below. Organic Analyses The analytical results indicate VOCs benzene, 2-butanone, chlorobenzene, chloroform, cis,1-2- dichloroethene, 1,1-dichloroethane, 1,2-dichlorobenzene, 1,4-dichlorobenzene, 1,4-dioxane, and vinyl chloride were detected at concentrations above laboratory method detection limits (MDLs) in one or more wells during the September/October 2022 sampling event. 1,4-Dioxane (up to 70.2 µg/L) was detected at a concentration above its 2L Standard (3 µg/L) in monitoring wells MW- 3RR, MW-4R, MW-5R, and MW-6R. The detected concentration of 1,4-dioxane in monitoring well MW-3RR during September 2022 is the highest detection of 1,4-dioxane at the site to date. Vinyl chloride was detected at an estimated J-flag concentration above its 2L Standard (0.03 µg/L) in monitoring well MW-5R (0.59 J µg/L) and the concentration is consistent with historical 11 14 hart hickman https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/GMI.004 Granville County Oxford Unit 1_WQMR Sept 2022.docx SMARTER ENVIRONMENTAL SOLUTIONS detections at this location. No other organic constituents were detected above 2L Standards during the September/October 2022 sampling event. Inorganic Anal The analytical results indicate metals barium, cadmium, cobalt, iron, manganese, and vanadium were detected at concentrations above MDLs in one or more wells during the September/October 2022 sampling event. Cobalt (9.5 µg/L) was detected at a concentration above its 2L Standard (1 µg/L) in monitoring well MW-3RR and concentrations are consistent with historical detections in this general area of the site (i.e., MW-3R). Iron (MW-2, MW-3RR, MW-6R, and MW-7) and manganese (MW-2, MW-3RR, MW-5R, and MW-6R) were detected at concentrations above their respective 2L Standards (300 µg/L, 50 µg/L), and concentrations are consistent with historical detections at these locations. Metals iron and manganese have been demonstrated and approved to be naturally occurring at the site. No other metal constituents were detected above 2L Standards during the September/October 2022 sampling event. C&D Parameters C&D parameters alkalinity, chloride, and sulfate were detected at concentrations above MDLs in one or more wells during the September/October 2022 sampling event, and concentrations are consistent with historical detections. TDS was detected at concentrations above its 2L Standard (500,000 µg/L) in MW-4R (517,000 µg/L) and MW-6R (668,000 µg/L), and concentrations are consistent with historical detections at these locations. 3.3 Surface Water Analytical Results Semi-annual surface water sampling consisted of collecting samples from one upstream (SW-1) and one downstream (SW-2) location. A summary of surface water constituent detections from the September 2022 sampling event is provided in Table 5. Historical analytical results are presented in Appendix E. A discussion of the results of the September 2022 sampling event is provided below. 12 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/GMI.004 Granville County Oxford Unit 1_WQMR Sept 2022.docx 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS The analytical results indicate one constituent (barium) was detected above the MDL in both upstream (SW-1) and downstream (SW-2) sample locations. North Carolina has not established a 2B Surface Water Standard for barium; however, the results indicate concentrations are below their respective North Carolina In -Stream Target Value for Surface Water (ISTV). A review of historical data indicates the current concentrations at SW-1 and SW-2 are comparable to prior detections at these locations. No other constituents were detected above MDLs during the September 2022 sampling event. 3.4 Quality Assurance/Quality Control Results Quality assurance procedures and protocols for sampling activities were conducted in general accordance with the DEQ-approved CAP and WQMP. Quality assurance samples included the collection of a trip blank and field blank sample. Samples were received by the lab in good condition and met holding times and preservation requirements. Based upon a review of the data packages, no significant quality assurance/quality control (QA/QC) issues were identified for the laboratory analyses. In summary, the QA/QC results indicate that the data collected during the semiannual monitoring event is suitable for its intended purpose. Trip Blanks Laboratory -filled trip blanks accompanied the sampling team during sampling and the transport of VOC samples to the laboratory. The trip blank samples serve as a QC check on potential external contamination and/or cross -contamination between VOC water samples during shipping and storage. The trip blank sample was analyzed for Appendix I VOCs and 1,4-dioxane. The results indicate no constituents were detected above laboratory MDLs. Field RlanV,, A field blank sample was collected in the field by exposing laboratory -supplied deionized water to the sampling environment. The field blank is used to evaluate the potential for contamination of a sample by site contaminants from a source not associated with the samples collected. The field blank sample was analyzed for Appendix I constituents, detected Appendix II constituents 13 14 hart hickman https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/GMI.004 Granville County Oxford Unit 1_WQMR Sept 2022.docx SMARTER ENVIRONMENTAL SOLUTIONS from the first sampling event of 2022, and 1,4-dioxane. The results indicate no constituents were detected above laboratory MDLs. 14 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/GMI.004 Granville County Oxford Unit I_WQMR Sept 2022.docx 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS 4.0 Corrective Action Evaluation 4.1 Monitored Natural Attenuation Parameters Groundwater samples collected during the September/October 2022 sampling event from monitoring wells MW-5R, MW-7, and NES-2S were analyzed for MNA parameters. The groundwater MNA parameter results for the current sampling event are summarized in Table 6. Historical groundwater MNA parameter results are provided in Appendix F. A summary of the MNA parameters collected from the above locations is provided below: • MNA Field Parameters: temperature, pH, conductivity, ORP, turbidity, and DO. • MNA Laboratory Parameters: alkalinity, chloride, dissolved hydrogen, dissolved methane, nitrate, sulfate. Based on the June 22, 2020, response from DEQ to the CAER dated June 5, 2020, the MNA parameters including sulfide, volatile fatty acids, TOC, dissolved carbon dioxide, ferrous iron, ethane, and ethene will be analyzed for two events every five years, corresponding to the two events immediately preceding each CAER. The next CAER is due after the first half semi-annual sampling event of 2025. The MNA results from the current sampling event will supplement the comprehensive results collected for the five-year period to evaluate MNA as the remedy for this site, a discussion of the evaluation will be detail in the next CAER. 4.2 Evaluation of Plume Stability and Trends As required by the CAP, this Report includes an evaluation of plume stability and contaminant concentration trends based on analytical results obtained from performance well NES-2S. In addition, constituent exceedances at other compliance monitoring wells (i.e., MW-2, MW-3RR, MW-4R, MW-5R, and MW-6R) are discussed in this section. The September/October 2022 results indicate organic compound 1,4-dioxane and vinyl chloride; and inorganic compounds cobalt, iron, and manganese are the only constituents detected in site groundwater at concentrations above 2L Standards. In addition, TDS was detected above its 2L Standard in two site wells. As 15 14 hart hickman https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/GMI.004 Granville County Oxford Unit 1_WQMR Sept 2022.docx SMARTER ENVIRONMENTAL SOLUTIONS previously noted, an ASD for the facility showed iron and manganese to be naturally occurring, and therefore, these compounds are not discussed in this section. Charts that depict constituent concentrations versus time for current (1,4-dioxane and vinyl chloride) and former (1,1- dichloroethane) site COCs are provided in Appendix G. A discussion of the concentration trends in site groundwater is provided below. IA-Dioxane As required by the DEQ SWS, beginning in 2018 groundwater and surface water samples collected at the site have been analyzed for 1,4-dioxane. Chart 1 presents a plot of 1,4-dioxane concentrations for monitoring wells with previous detections. The results of the September/October 2022 sampling event indicate 1,4-dioxane was detected above its 2L Standard in compliance monitoring wells MW-3RR, MW-4R, MW-5R, and MW-6R. As shown on the chart, the 1,4-dioxane concentrations are generally stable and current concentrations are consistent with historical detections at the site, with the exception of MW-3RR. In September 2022, a new landfill phase development at the Oxford Unit 2 landfill resulted in the abandonment of MW-3R and the installation of replacement well MW-3RR nearby (MW-3RR located approximately 100 ft south of former MW-3R). The results for the first completed sampling event of monitoring well MW-3RR indicated the highest detected concentration of 1,4- dioxane at the site to date; however, the concentration at MW-3RR (70.2 µg/L) is similar to recent detections in site groundwater (up to 65.1 µg/L at MW-5R). Site monitoring results indicate 1,4-dioxane exceedances are limited to compliance wells MW- 3RR, MW-4R, MW-5R, and MW-6R. The current results indicate 1,4-dioxane was not detected above the MDL in groundwater (NES-2S) and surface water (SW-2) samples collected from locations downgradient of the landfill. This COC will continue to be monitored during future semi-annual sampling events. Vinyl Chloride and 1, 1 -Dichloroethane Chart 2 and Chart 3 present a plot of vinyl chloride and 1,1-dichloroethane concentrations for monitoring well MW-5R, respectively. The charts demonstrate a continued decreasing trend for 16 14 hart hickman https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/GMI.004 Granville County Oxford Unit 1_WQMR Sept 2022.docx SMARTER ENVIRONMENTAL SOLUTIONS these constituents at MW-5R. DEQ approved the removal of 1,1-dichloroethane from the site COC list in 2015, and the current results indicate concentrations at this location continue to decrease and remain below its 2L Standard. The September/October 2022 results indicate that vinyl chloride concentrations at MW-5R (0.59 J µg/L) continue to decrease but remain above its 2L Standard (0.03 µg/L). Site monitoring results indicate vinyl chloride detections and exceedances are limited to compliance monitoring well MW-5R. In addition, 1, 1 -dichloroethane was last detected above its 2L Standard in MW-5R during the June 2011 sampling event and concentrations have since generally decreased. Since there have been no detections of these compounds in samples collected from surface water at SW-2 or sentinel well NES-2S, there is no indication that the organic impacts detected at MW-5R are migrating downgradient. These COCs will continue to be monitored during future semiannual sampling events. CC)halt The September/October 2022 sample results indicate cobalt (9.5 µg/L in MW-3RR) was detected above its 2L Standard (1 µg/L). A review of historical data indicates current concentrations at this location are comparable to prior detections in this general area of the site (i.e., MW-3R) and concentrations do not appear to be increasing. This metal was also previously detected in background well MW-7 at concentrations above its 2L Standard (up to 5 µg/L). As previously recommended, based on detections of this metal above 2L Standards, it is recommended that an ASD be conducted to establish background levels for cobalt. Additionally, since there was no detection of this compound in samples collected from downgradient surface water location SW-2, there is no indication that the inorganic impacts detected at MW-5R are migrating downgradient. Cobalt will continue to be monitored during future semi-annual sampling events. 17 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/GMI.004 Granville County Oxford Unit 1_WQMR Sept 2022.docx 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS 5.0 Conclusions Semi-annual water quality monitoring activities were conducted at the site on September 29 and October 5, 2022. The groundwater results indicate the landfill monitoring well network remains adequate to monitor the site. A review of plume stability and concentration trends indicates that the selected remedy of natural attenuation remains appropriate for the site. Based on the September/October 2022 results, trends for site COCs remain consistent with the prior sampling event and the facility will continue work in the Assessment Monitoring and Corrective Action programs. A summary of the results is provided below. • Consistent with historical trends, the overall direction of groundwater flow at the site is north to northeast towards an unnamed tributary to Little Grassy Creek. • 1,4-Dioxane (MW-3RR, MW-4R, MW-5R, and MW-6R) was detected in groundwater at concentrations above its 2L Standard. The 1,4-dioxane concentrations are consistent with historical concentrations detected at each location, with the exception of MW-3RR. In September 2022, a new landfill phase development resulted in the abandonment of MW- 3R and the installation of replacement well MW-3RR nearby. The results for the first completed sampling event MW-3RR indicated the highest detected concentration of 1,4- dioxane at the site to date; however, the concentration at MW-3RR (70.2 µg/L) is similar to recent detections in groundwater at the site (up to 65.1 µg/L in MW-5R). • Vinyl chloride (MW-5R) was detected in groundwater at a concentration above its 2L Standard. Vinyl chloride concentrations are consistent with historical concentrations at MW-5R and continue to show a decreasing trend. • Iron (MW-2, MW-3RR, MW-6R, and MW-7) and manganese (MW-2, MW-3RR, MW- 5R, and MW-6R) were detected at concentrations above their respective 2L Standards; however, these metals have been demonstrated and approved to be naturally occurring at the site. The concentrations are consistent with historical detections at these locations. 18 14 hart hickman https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/GMI.004 Granville County Oxford Unit 1_WQMR Sept 2022.docx SMARTER ENVIRONMENTAL SOLUTIONS • Cobalt (MW-3RR) was detected at a concentration above its 2L Standard. The concentration is consistent with historical detections of cobalt at the site. Based on consistent detections of this metal above 2L Standards, it is recommended that an ASD be conducted to establish background levels for cobalt. • Surface water results indicate constituents were not detected at concentrations above their applicable surface water standards. 19 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/GMI.004 Granville County Oxford Unit I_WQMR Sept 2022.docx 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS Table 1 Summary of Well Construction Details Granville County Oxford Unit 1 Landfill Oxford, North Carolina H&H Job No. GMI-004 Ground TOC TOC Top of Bottom Total Depth Auger Screened Well ID Date Installed Northing Easting Elevation Elevation Screen Screen Refusal Comments (ft AGS) (ft BTOC) Lithology (ft AMSL) (ft AMSL) (ft BTOC) (ft BTOC) (ft BGS) MW-1A 952141.6930 2110755.3908 535.18 538.18 3` 10.00 25.00 25.00 > 22 Saprolite No longer Sampled MW-2 -- 953940.0174 2110351.7384 517.00 518.62 1.62 14.12 29.12 29.12 21.00 Saprolite/Bedrock Unit 1 Compliance MW-3RR 9/8/2022 953933.99 2111630.18 500.82 503.37 2.55 21.97 26.55 26.55 25.00 Bedrock Unit 1 Compliance MW-4R 8/26/1999 954975.1334 2110797.9991 504.90 507.34 2.44 52.44 62.44 62.44 17.50 Bedrock Unit 1 Compliance MW-5R 8/25/1999 954947.2480 2111685.6720 487.24 489.95 2.71 29.71 39.71 39.71 22.00 Bedrock Unit 1 Compliance MW-6R 8/25/1999 954725.8325 2110287.6108 504.42 506.81 2.39 32.39 42.39 42.39 13.00 Bedrock Unit 1 Compliance NES-1S 5/1/2004 955167.9708 2111057.1915 514.35 516.93 2.58 21.08 36.08 36.58 27.00 Saprolite/Bedrock No longer Sampled NES-1D 5/1/2004 955177.3548 2111054.7005 514.38 516.62 2.24 65.74 80.74 81.24 27.00 Bedrock Abandoned Unit 1 CAP NES-2S 5/1/2004 955091.290 2111945.3411 474.53 477.20 2.67 13.67 23.67 24.17 9.00 Saprolite Performance NES-2D 5/1/2004 955081.7805 2111946.7398 474.72 477.43 2.71 53.71 68.71 69.21 21.50 Bedrock Unit 1 CAP Sentinel Units 1 & 2 MW-7 7/28/2008 953292.1160 2112043.4480 531.24 534.24 3.00 22.5 37.50 37.50 34.50 Saprolite Background Well Notes: Well information obtained from LaBella Associates Water Quality Monitoring Report - February 2021 Event. MW-3RR survey data provided by Garrett & Moore, Inc. following the reinstallation of the well in September 2022. ft = feet; AMSL = above mean sea level; AGS = above ground surface TOC = top of casing; BTOC = below top of casing; ` = estimated value -- = unknown; CAP = corrective action plan Table 1 (Page 1 of /1) hltps://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM fo /Oxrd Unit 1 Tables 1-6.xlsx Hart & Hickman, Pl. Table 2 Summary of Groundwater Elevations Granville County Oxford Unit 1 Landfill Oxford, North Carolina H&H Job No. GMI-004 Well ID Total Depth ( ft BTOC) TOC Elevation (ft AMSL) September 29, 2022 Depth to Groundwater (ft BTOC) Groundwater Elevation (ft AMSL) MW-1 A 25.00 538.18 25.99 512.19 M W-2 29.12 518.62 17.55 501.07 M W-3 RR 26.55 503.37 18.65 484.72 MW-4R 62.44 507.34 11.39 495.95 MW-5R 39.71 489.95 23.40 466.55 MW-6R 42.39 506.81 11.70 495.11 M W-7 37.50 534.24 26.77 507.47 NES-2S 23.67 477.20 5.65 471.55 NES-2D 68.71 477.43 4.44 472.99 Notes: Well information obtained from LaBella Associates 2021 Water Quality Monitoring Report - February 2021 Event. MW-3RR survey data provided by Garrett & Moore, Inc. following the reinstallation of the well in September 2022. TOC = top of casing; ft BTOC = feet below top of casing ft AMSL= feet above mean sea level Table 2 (Page 1 of 1) Hart & Hickman, PC https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/Tables/Oxford Unit 1 Tables 1-6.xlsx Table 3 Summary of Field Parameters Granville County Oxford Unit 1 Landfill Oxford, North Carolina H&H Job No. GMI-004 Sample ID Sample Date Field Parameter Result Unit Groundwater MW-2 10/5/2022 Conductivity 71PS/CM Dissolved Oxygen 0.34 m /1 ORP 36.5 mV pH 5.52 S.U. Temperature 16.43 oC Turbidity 67.9 NTU MW-3RR 9/29/2022 Conductivity 646PS/CM Dissolved Oxygen 0.69 m /I ORP -23.3 mV H 6.68 S.U. Temperature 17.91 oC Turbidity 8.05 NTU MW-4R 10/5/2022 Conductivity 823PS/CM Dissolved Oxygen 1.39 m /l ORP 31.3 mV pH 6.99 S.U. Temperature 18.73 oC Turbidity 1.66 NTU MW-5R 9/29/2022 Conductivity 552PS/CM Dissolved Oxygen 0.67 m /I ORP 50.3 mV H 6.08 S.U. Temperature 15.63 oC Turbidity 0.32 NTU MW-6R 10/5/2022 Conductivity 1,048PS/CM Dissolved Oxygen 0.59 m /l ORP -75.4 mV pH 6.72 S.U. Temperature 17.40 oC Turbidity 7.33 NTU MW-7 9/29/2022 Conductivity 392.1PS/CM Dissolved Oxygen 2.07 m /I ORP 118.3 mV H 6.31 S.U. Temperature 18.1 oC Turbidity 9.11 NTU NES-2S 9/29/2022 Conductivity 269.5PS/CM Dissolved Oxygen 0.26 m /l ORP 61.4 mV pH 6.34 S.U. Temperature 17.5 oC Turbidity 1.61 NTU Table 3 (Page 1 of 1) Hart & Hickman, PC https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/Tables/Oxford Unit 1 Tables 1-6.xlsx Table 3 Summary of Field Parameters Granville County Oxford Unit 1 Landfill Oxford, North Carolina H&H Job No. GMI-004 Sample ID Sample Date Field Parameter Result Unit Surface Water SW-1 9/29/2022 Conductivity 107.8PS/CM Dissolved Oxygen 3.44 m /I ORP 74.9 mV pH 6.87 S.U. Temperature 18.4 °C Turbidity 12.45 NTU SW-2 9/29/2022 Conductivity 188.5PS/cm Dissolved Oxygen 6.15 m /I ORP 88.5 mV H 6.75 S.U. Temperature 15.7 °C Turbidity 3.94 NTU Notes: S.U. = standard units; °C = degrees Celsius; pS/cm = microsiemens per centimeter NTU = nephelometric turbidity unit; mg/L = milligrams per liter; mV = millivolts ORP = oxidation reduction potential Table 3 (Page 2 of 1) Hart & Hickman, PC https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/Tables/Oxford Unit 1 Tables 1-6.xlsx Table 4 Summary of Groundwater Flow Velocity Granville County Oxford Unit 1 Landfill Oxford, North Carolina H&H Job No. GMI-004 Well ID Hydraulic Conductivity(l)Elevation (ft/day) Groundwater (ft AMSL) Reference Elevation (ft AMSL) Delta Elevation (ft) Map Length (ft) Hydraulic Gradient (ft/ft) Effective Porosity �,� Groundwater Flow Velocity (ft/day) Groundwater Flow Velocity (ft/year) MW-1A 7.31E-02 512.19 510.00 2.19 369.47 0.0059 0.310 0.0014 0.51 MW-2 7.31 E-02 501.07 500.00 1.07 100.54 0.0106 0.310 0.0025 0.92 MW-3RR 7.31 E-02 484.72 480.00 4.72 355.15 0.0133 0.310 0.0031 1.14 MW-4R 7.31 E-02 495.95 490.00 5.95 177.46 0.0335 0.310 0.0079 2.89 MW-5R 7.31 E-02 466.55 470.00 3.45 86.10 0.0401 0.310 0.0094 3.45 MW-6R 7.31 E-02 495.11 495.00 0.11 455.50 0.0002 0.310 0.0001 0.02 MW-7 7.31 E-02 507.47 505.00 2.47 65.64 0.0376 0.310 0.0089 3.24 NES-2S 7.31E-02 471.55 475.00 3.45 575.66 0.0060 0.310 0.0014 0.52 Minimum -- -- -- -- 0.0002 -- 0.0001 0.02 Maximum -- -- -- -- 0.0401 -- 0.0094 3.45 Geometric Mean -- -- -- -- 0.0094 -- 0.0022 0.81 Notes: 1) Hydraulic conductivity and porosity values from Labella Associates Water Quality Monitoring Report - February 2021 Event Hydraulic conductivity was based on the geometric mean of values from slug tests conducted on saprolite wells at the facilib. in 2019 and the effective porosity value was estimated at 31 % of the laboratory determined porosity for soil samples form the facility ft = feet; ft/day = feet per day; ft/year = feet per year AMSL = feet above mean sea level; -- = not applicable Vx = (K/ne) x dh/dl Vx = groundwater flow velocity K = hydraulic conductivity ne = effective porosity dh/dl = hydraulic gradient Table 4 (Page 1 of 1) https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/Tables/Oxford Unit 1 Tables 1-6 Hart & Hickman, Pl./ Table 5 Summary of Groundwater and Surface Water Analytical Results Granville County Oxford Unit 1 Landfill Oxford, North Carolina H&H Job No. GMI-004 Well ID Sample Date Parameter Result (Ng/L) Standard (Ng/L) Source (1 &2) Groundwater MW-2 10/5/2022 Alkalinity 15,400 NE Barium 10.5 700 NC 2L Chloride 2,500 250,000 NC 2L Iron 1,840 300 NC 2L Manganese 175 50 NC 2L Sulfate 6,700 250,000 NC 2L Total Dissolved Solids 148,000 500,000 NC 2L Vanadium 4.8 J 7 NC 2L MW-3RR 9/29/2022 1,4-Dioxane 70.2 3 NC 2L Alkalinity 205,000 NE - Barium 43.5 700 NC 2L Cadmium 0.55 J 2 NC 2L Chloride 41,700 250,000 NC 2L Chlorobenzene 0.51 J 50 NC 2L Chloroform 2.1 70 NC 2L Cobalt 9.5 1 NC 2L Iron 3,210 300 NC 2L Manganese 3,480 50 NC 2L Sulfate 42,400 250,000 NC 2L Total Dissolved Solids 399,000 500,000 NC 2L MW-4R 10/5/2022 1,4-Dioxane 19.3 3 NC 2L Alkalinity 345,000 NE Barium 40.1 700 NC 2L Chloride 69,400 250,000 NC 2L Manganese 15.6 50 NC 2L Sulfate 23,700 250,000 NC 2L Total Dissolved Solids 517,000 500,000 NC 2L MW-5R 9/29/2022 1,1-Dichloroethane 1.1 6 NC 2L 1,2-Dichlorobenzene 1.4 20 NC 2L 1,4-Dichlorobenzene 0.96 J 6 NC 2L 1,4-Dioxane 65.1 3 NC 2L Alkalinity 182,000 NE - Barium 56.0 700 NC 2L Benzene 0.35 J 1 NC 2L Chloride 52,300 250,000 NC 2L Chlorobenzene 1.9 50 NC 2L cis- 1,2-Dichloroethene 1.9 70 NC 2L Iron 116 300 NC 2L Manganese 335 50 NC 2L Sulfate 8,500 250,000 NC 2L Total Dissolved Solids 326,000 500,000 NC 2L Vinyl Chloride 0.59 J 0.03 NC 2L MW-6R 10/5/2022 1, 1 -Dichloroethane 1.4 6 NC 2L cis- 1,2-Dichloroethene 0.97 J 70 NC 2L 1,4-Dioxane 11.0 3 NC 2L Barium 155 700 NC 2L Alkalinity 313,000 NE Chloride 166,000 250,000 NC 2L Iron 5,930 300 NC 2L Manganese 2,180 50 NC 2L Sulfate 8,500 250,000 NC 2L Total Dissolved Solids 668,000 500,000 NC 2L Table 5 (Page 1 of 1) https:/Iharthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 First Half GWM/Tables/Oxford Unit 1 Tables 1-6.xlsx Hart & Hickman, PC Table 5 Summary of Groundwater and Surface Water Analytical Results Granville County Oxford Unit 1 Landfill Oxford, North Carolina H&H Job No. GMI-004 Well ID Sample Date Parameter Result (Ng/L) Standard (Ng/L) Source (1 &2) Groundwater MW-7 9/29/2022 Alkalinity 144,000 NE - Barium 4.3 J 700 NC 2L 2-Butanone MEK 5.1 4,000 NC 2L Chloride 7,600 250,000 NC 2L 1,4-Dioxane 1.7 J 3 NC 2L Iron 472 300 NC 2L Manganese 20.9 50 NC 2L Nitrogen, Nitrate 240 10,000 NC 2L Sulfate 41,200 250,000 NC 2L Total Dissolved Solids 246,000 500,000 NC 2L NES-2S 9/29/2022 Barium 33.7 700 NC 2L Alkalinity 77,400 NE - Chloride 10,400 250,000 NC 2L Nitrogen, Nitrate 200 10,000 NC 2L Sulfate 30,100 250,000 NC 2L Surface Water SW-1 9/29/2022 Barium 23.5 21,000 ISTV (3) Hardness 32,700 NE - SW-2 9/29/2022 Barium 25.3 21,000 ISTV j3) Hardness 62,300 NE - Notes: 1. NC 2L Standards are the Title 15A NCAC 02L .0202 Groundwater Standards dated April 1, 2022. 2. 15A NCAC 2B Water Quality Standards (21B Standards) for Surface Water (Class C Waters) dated July 26, 2021. 3. No 2B Standard established, value shown is North Carolina In -Stream Target Values for Surface Waters (ISTV). Bold concentrations exceed the NC 2L Standard for groundwater or NC 2B Standard for surface water. pg/L = micrograms per liter; -- = not applicable; NE = Not Established; Table 5 (Page 2 of 1) https:/Iharthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 First Half GWM/Tables/Oxford Unit 1 Tables 1-6.xlsx Hart & Hickman, PC Table 6 Summary of Monitored Natural Attenuation Parameters Granville County Oxford Unit 1 Landfill Oxford, North Carolina H&H Job No. GMI-004 Well ID Sample Date Parameter Result (µJ/L) Standard /L MW-5R 9/29/2022 Alkalinity (total as CaCO3) 182,000 NE MW-7 9/29/2022 144,000 NE NES-2S 9/29/2022 77,400 NE MW-5R 9/29/2022 Chloride 52,300 250,000 MW-7 9/29/2022 7,600 250,000 NES-2S 9/29/2022 10,400 250,000 MW-5R 9/29/2022 Methane 63 NE MW-7 9/29/2022 <5.0 NE NES-2S 9/29/2022 74 NE MW-5R 9/29/2022 Nitrogen, Nitrate <100 10,000 MW-7 9/29/2022 240 10,000 NES-2S 9/29/2022 200 10,000 MW-5R 9/29/2022 Sulfate 8,500 250,000 MW-7 9/29/2022 41,200 250,000 NES-2S 9/29/2022 30,100 250,000 MW-5R 9/29/2022 Dissolved Hydrogen 1.0 J(Z) NE MW-7 9/29/2022 9.2(2) NE NES-2S 9/29/2022 0.78 J(2) NE MW-2 10/5/2022 Total Dissolved Solids 148,000 500,000 MW-3RR 9/29/2022 399,000 500,000 MW-4R 10/5/2022 517,000 500,000 MW-5R 9/29/2022 326,000 500,000 MW-6R 10/5/2022 668,000 500,000 MW-7 1 9/29/2022 246,000 1 500,000 Notes: 1. NC 2L Standards are the Title 15A NCAC 02L .0202 Groundwater Standards dated April 1, 2022. 2. Dissolved Hydrogen units shown in nanometers (nM). Bold concentrations exceed the NC 2L Standard for groundwater. ug/L = micrograms per liter; NS = Not Sampled; ND = Not Detected; NE = Not Established Table 7 (Page 1 of 2) Hart & Hickman, PC https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 First Half GWM/Tables/Oxford Unit 1 Tables 1-6.xlsx APPROXIMATE LIMITS OF WASTE UNIT 1 l 4 "Y j 4 ^^^^ERTY BOUNDARY APPROXIMATE SrERr (4_ LIMITS OF WASTE UNIT 2 i USGS The National Map: National Boundaries Dataset, 3DEP Elevation Program, Geographic Names Information System, National Hydrography Dataset, National Land Cover Database, National Structures Dataset, and National Transportation Dataset; USGS Global Ecosystems; U.S. Census Bureau TIGER/Line data; USFS Road Data; Natural Earth Data; U.S. Department of State Humanitarian Information Unit; and NOAA National Centers for Environmental Information, U.S. Coastal Relief Model. Data refreshed August, 2021. TITLE o 2,000 4,000 SITE LOCATION MAP NPROJECT SCALE IN FEET OXFORD LANDFILL UNIT 1 GRANVILLE COUNTY U.S.G.S. QUADRANGLE MAP OXFORD, NORTH CAROLINA 2923 South Tryon Street - Suite 100 BEREA, NORTH CAROLINA2019 hart hickman Charlotte, North Carolina28203 704-586-0007 (p) 704-586-0373 (t) OXFORD, NORTH CAROLINA 2019 SMARTER E NVrFro 7jMENT LL soLUVONs License # C-1269 / # C-245 Geology 3 QUADRANGLE DATE: 11-21-22 REVISION NO: 0 7.5 MINUTE SERIES (TOPOGRAPHIC) JOB NO: GMI-004 FIGURE NO: 1 T. 4661, GO 150' 7n 490 506 7 'o _ _ •r �/ // y � I I , _ • ��-•��-,� �90 �`.,.-� /��'�' J r /// /ram/1 // 1 r /- � ,� do 46 ib 16 ! ram... -� � I � 1 ��� •. I :�26 I \ ,� 1 \ � 1 j - \ '�.... Ig r li l I it \ ter/ � / // � r \ \ �'\ � ��✓ (/� � I 1 v\ ^\ 1 530 Appendix A Groundwater and Surface Water Sampling Records 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS K G �&I- hart hickman SMARTER ENVIRONMENTAL SOLUTIONS LOW -FLOW GROUNDWATER SAMPLING RECORD Stabilization Criteria Primary: Secondary: pH +/- 0.1 unit DO +/- 0.2 mg/L S. Cond. +/- 5% ORP +/- 20 mV Turb. +/- 10% (<10 NTLIs for metals) Water Level: slight or stable drawdown during purging Job No: G t'�r , aoy Well ID: / t C.% — "L Well Location: a K F Facility Name: 5 �- Fol L� UA�k Date: [01��2 Top of Casing Elevation (ft msl): Casing Material: Volume of Water Per Well Volume: gallons Total Well Depth (ftToq: Depth to Water (ftTOC): i,7. G Well Diameter: 2 Sampling Personnel: C C" Screen Interval (ftTOC)- /�. 5' - Z�• Type of Pump: `?y is4r-the, Tubing Material: GD Pump/Tubing set at: ft Weather Conditions: S" &,, ^' �50r- NOTES`"'`'�� b � We'll S"f} �:'Mi 44- bf' GROUNDWATER SAMPLING PARAMETERSt Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity Time Level Pumped Rate (mall] (°CI(AS/cm) SU mV LNTUj, ' SD M6 n. 5 - 0` I S�''',�` 1� Pc. 7 i IG t, 7 1Ul7[7 1'�k.0'16 touy? 7 —C-� -7 I Sov 2 S -7--Z-- /. 7 3 0 Z e--Q:r�_ o -S.7 f 9i _3-?3 7. � 5 _ l o I s t K. S 2 5as l _�3_ -71 � �(7 I0''LO l`i'31-- 5c7c��, [.'mil ► /5.V6 L� 1CAI I �2-.S `3 3Sc r•3-7]� 97 7' 151. &7 f03CQ 0.31 -Z(-.a(11' Z-9 t -GI 2I.g 113 7 3i`. Other Sample Parameters: Sampled at: ��� Parameters taken/with: ��'� S~�(% h rti 2/cr, (F4-A— 6�" /bo'u. - (NM) Sample Delivered to: � by (14AN"e-r at Field Filtration: ® Yes (j) No If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives): -4. "S:\BBB Master Templates\Forms - 2022 Forms\Low Flow Groundwater Sampling Form.pdf' Stabilization criteria guidelines from the EPA SESD Operating Last Updated: 2/14/2022 Procedure for Groundwater Sampling, dated April 26, 2017. hart � ''hickman SMARTER ENVIRONMENTAL SOLUTIONS LOW -FLOW GROUNDWATER SAMPLING RECORD Job No: C t'(1 � C)C4 Well ID: LJ — Well Location: f�,,`t-c��� w, Facility Name: IjxF'2rS (,F uo 1 Date: I0) 5 -o- Top of Casing Elevation (ft msl): Casing Material: F� _-_ Volume of Water Per Well Volume: gallons Total Well Depth (ftTOC): ` �' Depth to Water (ftTOC): / 3. 6`Z Well Diameter: Sampling Personnel:-(— ccsr& , Screen Interval (ftTOC). ) Li • S Stabilization Criteria Primary: Secondary: pH +/- 0.1 unit DO +/- 0.2 mg/L S. Cond. +/- 5% ORP +/- 20 mV Turb. +/- 10% (<10 NTLIs for metals) Water Level: slight or stable drawdown during purging Z -Lg.S Type of Pump: Po-t� lc-) Fr L Tubing Material: C Pump/Tubing set at: ft Weather Conditions: S L" A n -r ^' (05 " ►� NOTES: din t ��r�. rc� ; ����r, AQ:�► c 7 P. GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity Time Level Pumped Rate {mg-/11 S/cm (SU), (MV) �NTU ++ `,[°C] S,5 1 LA-� o L2 Soo 3 -. 4 Ie�, --T>� l l O 5 1' l- 7 .�-s7b S^ � 3 G. S Other Sample Parameters: Sampled at: l ❑15, Parameters taken with: �S ss �'^-j A41A 2�06(Z (Ccsk" Sample Delivered to: I a£t. hY,9,4,r•1J.[ by at Field Filtration: ()Yes 0 No If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives): ;,/ AC l � `1- �;' �3•� -Z-S 1"1 r+fte_. � i S L � •� r� L wl k AIG� Sour. � .I �,t �. s} (��/1.� %- Z Sv r l� fo,- .,1 Jti. Z 37� i s. Forc F"Y'cett) 'S:\BBB Master Templates\Forms - 2022 Forms\Low Flow Groundwater Sampling Form.pdf' Stabilization criteria guidelines from the EHA SLSu Uperanng Last Updated: 2/1412022 Procedure for Groundwater Sampling, dated April 26, 2017 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS LOW -FLOW GROUNDWATER SAMPLING RECORD Stabilization Criteria Primary: Secondary: pH +/- 0.1 unit DO +/- 0.2 mg/L S. Cond. +/- 5% ORP +/- 20 mV Turb. +/- 10% (<10 NTUs for metals) Water Level: slight or stable drawdown during purging Job No: GMS, Do 4 Well ID: MVJ- 3RR Well Location: - OXfo j , 14L Facility Name: QX ,,� L-nAPA Date: G 42" 42-o Top of Casing Elevation (ft msl): Casing Material:_ _PVC1- _ — Volume of Water Per Well Volume: gallons Total Well Depth (ftTOC) Z. 3A Depth to Water (ftTOC): AK 65' - _ Well Diameter: Sampling Personnel: �" PA Screen Interval (ftTOC): - n Type of Pump: 1'p'r,I AaG NG Tubing Material. LDPE Pump/Tubing set at: ft D Weather Conditions: Ci(DuAV NOTES: GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping D❑ Temp. S. Cond. Ply ORP Turbidity Time Level Pumped Rate m !I C-C-1 us/cm) (SU) mV) (NNTU) Iq�gs R L 14D inzw„ -z5 0. get 713 H a17 �-t moo_ 3S II ; SD CO)A 1.3 L "�rndn 1. q5 r. co C9 C. �- 3s it _ I 11 : 55 � i. t L Io0 ki �_ L --;Z0. D 14. 00 ao.gs Q-z L TM,L�.rl+ -S7 ` . T-3 r�iSq 76 --17. `7 �f_ ?D I�:o5 a. _ —faa ..�. 0.7� I'7.'�S _ � _� L Z(). Ix in Qt.SiK L I Qg ri C) - &1 17, D 646 C. 60 -.23. 3 <�? Os Other Sample Parameters. n1A Sampled at: bR, 1 a Sample Delivered to: Field Filtration: O Yes O No Parameters taken with: 5S6 MP5 P PA,cr61rq TAILcg&r by - If yes, which sample parameters were field filtered: A//A Sample Parameter Containers (Types, Number of Containers, Preservatives): ; f ' % S Pry - Ix at r, 1 "S:\BBB Master TemplatesTorms - 2022 Farms\Low Flow Groundwater Sampling Form pdf' UftQrLnSt _ 6 hS ( I Y 'SW HL ri o, (014 Stabilization criteria guidelines from the EPA SESD Operating Procedure fnr (;roundwater Samolina. dated Andl 26. 2017 hart ;!w hickman SMARTER ENVIRONMENTAL SOLUTIONS LOW -FLOW GROUNDWATER SAMPLING RECORD Facility Name: Stabilization Criteria Primary: Secondary: pH +/- 0.1 unit DO +/- 0.2 mg/L S. Cond. +/- 5% ORP +/- 20 mV Turb. +/- 10% (<10 NTUs for metals) Water Level: slight or stable drawdown during purging Job No: GAI - Go `1 Well ID: '� w - `l (F" Well Location: "(- Date: Az Top of Casing Elevation (ft msl): Casing Material: `% L Volume of Water Per Well Volume: gallons Total Well Depth (ftTOC): r Depth to Water (ftTOC): 11. 87 Well Diameter: 2 Sampling Personnel: �C,..'I Screen Interval (ftTOC): 5-0 - to O Type of Pump: f &cS 1rA Tubing Material: Pump/Tubing set at: ft Weather Conditions: -51'n8=7^' �s�� NOTES: �1AO,S�K�d 64faA 4 GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity Time Level Pumped Rate LM-9 _/l LLCI Slcm � L) LN-T— ) j`f� i $`_ L �b�McI,v., 2- S`1 1 S. �f 7y 9 -7 '25- 3 74f$ 7, 7 — t 1.C7y d �.s7P4 "?� -. j ti I � � aR 7' O9 17,0 — �'� ,4-) 'LSDd .130 �$ 70 $�1 7 os 20.3 I(. T 1oc?o I .`bC� _ iS. G% 19l 1� 7. L� 1`� S 1— 2 4 a00 I.S9 )$ S i t. 7 4Z_t -7- 21 -7 S 3 a. C - 1Ll t>t Other Sample Parameters: Sampled at: Parameters taken with: YaA �%p, y-P�. jW4) ' Sample Delivered to:_ Pam, Ncw A_,,Pvrk - by ,(: sr,.. at Field Filtration: Q Yes Q No If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers,` Preservatives): w — VVR�yS -K 5 I `-�rak+aw `�C VExr� u/ Nt�� I\fLfl+l s ZSI;, L. t_ vn CTs�T ? �J.n L i 5 �a fur ` 'S:\BBB Master Templates\Forms -2022 Forms\Low Flow Groundwater Sampling Form.pdf' '"''"'"". '""' "'" " .' """' `"I-'-" I Last Updated: 2/14/2022 Procedure for Groundwater Sampling, dated April 26, 2017- hart hickman SMARTER -r1VlW)NNl[NIo\L SOLUTIONS Stabilization Criteria Primary: Secondary: pH +/- 0.1 unit DO +/- 0.2 mg/L S. Cond +/- 5% ORP +/- 20 mV Job No: &AX:. LOW -FLOW GROUNDWATER Turb. +/- 10% (<10 NTUs for metals) Well ID: KW -SR Level: slight or stable SAMPLING RECORD `` drawdown during purging Well Location: JV Facility Name De�� tJ 9; 1} Date: 51a9 I'Roxx Top of Casing Elevation (ft msl)._ _ _ Casing Material- Py C- Volume Volume of Water Per Well Volume: gallons Total Well Depth (ftTOC): _ Depth to Water (ftTOC): 93AP Well Diameter: DZ I&Sbf t Sampling Personnel.__.�� _ Screen Interval (ftTOC) - Type of Pump. Tubing Material.__ LV pa Pump/Tubing set at: ti ft Weather Conditions: 60%jkZe F NOTES. GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity Time Level Pumped Rate m 1! cc) IS/cm (SU) (MV) (NTuI `1S C. 5, Dq -51 I uo ,f r�� ! ,p f] _ �.�s > S _ _ 3 r s 1.g �.�+ — � a 5 a 2.5 L l_�V ia+-f c ^ _ n. a m � S52 6�i72 3� . I 3. sa_ 3. n C �..� 1 1�►, _ — l5. C5� -A2. 6. of _ � 4�• 6 ��'L Other Sample Parameters.. Sampled at: L .�3a Parameters taken with:U�C 5SC MRS s Sample Delivered to,.— by _ _ at _. Field Filtration: Q Yes Q No If yes, which sample parameters were field filtered: NIA Sample Parameter Containers (Types, Number of Containers, Preservatives) )LKI MDA7 t u _ Tl'.� . ,o 1��. ���Q �3 x LM"L Amxs Cis r s w f 1 "S.\BBB Master Templates\Forms - 2022 Forms,\Lorw Flow Groundwater Sampling Form.por �o1y , �(�� Q �sad�ed , 4��C7�CJ (3 k y�j�roc1. edure for Gro gurpe6nes from the EPA SESD Operating Last Updated 2/1412022 �� VlvS / 1- Procedure for �rou�tdwaser Sampling, doled April 26, 2017. __ Stabilization Criteria hart_' hickman Primary: Secondary: �- +/- 0.1 DO +/- 0.2 , �• C-)c) G\ pH unit mg/L Job No: ' SMARTER ENVIRONMENTAL SOLUTIONS S. Cond. +/- 5% ORP +/- 20 mV GROUNDWATER +/- 10% (<10 NTUs for metals) /� (,J -- Well ID: Ia 0LOW-FLOW Water Level: slight or stable Water SAMPLING RECORD drawdown during purging Well Location: Facility Name: 0,4Tnf �F �� Date: Top of Casing Elevation (ft msl): Casing Material: iUL Volume of Water Per Well Volume: gallons Total Well Depth (ftTOC): L� Depth to ater (ftTOC): Well Diameter: 2 Sampling Personnel:- C a.iS'c.46x Screen Interval (ftTOC): '7) U Type of Pump: I�{5�,:.(� Z ` Tubing Material: Pump/Tubing set at: ft Weather Conditions: v n n "' NOTES: &-coji Z,95 GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping ❑O Temp. S. Cond. pH ORP Turbidity Time Level Pumped Rate Im m LS/cm (Sul LMDYI fNTU1 C9 MG i0o�1, �. 1 3 5T7 (0617 -70.LA 12't,1 li? S(I Ioty-) C7- 9�1l 1-1.1-17 14 03Z C, -70 — 75'-7 — 1 22G l �00 a- 7 -L 1-7. Ica 1,031 G - 7 i:_ —7C, 1 ^ ? ' C)- (0-1- 11 , 35 o l-i s _ -? -7— — 7.s, q 7 -7 3 Other Sample Parameter : _ _ Sampled at: � Z� Parameters taken with. ("C"i 5���^S�, YSt— SEb 1601 W),-14 Sample Delivered to: i A Le by C oc)!i is at Field Filtration: ()Yes O No If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Numbero`f- Containers, Preservatives)*1i 3 x \j(>A S� W1 \A(-\i 3KrU�bwS W nl l 1 IL-S I •t• `,� Jbr+�L �'n� r.Eti:. Gcw� �410�bLlsV\T4,T(✓ 1.�0 h�. ❑ t��1 C] r G.[ M1-4.IiAL �JVMIr ^'♦• V/\fii�' w". 7[S V W,X, "S:\BBB Master Templates\Forms -2022 Forms\Low Flow Groundwater Sampling Form pdf' Stabilization criteria guidelines from the EPA SESD Operating Last Updated: 2/14/2022 Procedure for Groundwater Sampling, dated April 26, 2017. Stabilization Criteria hart �_��" hiekman Primary: Secondary: h`- pH +/- 0.1 unit DO +/- 0.2 mg/L Job No: oz�cy SMARTER ENVIRONMENTAL SOLUTIONS S. Cond. +/- 5% ORP +/- 20 mV LOW -FLOW GROUNDWATER Turb. +/- 10% (<10 NTUs for metals) Well ID: M d ✓ --7 Water Level: slight or stable SAMPLING RECORD drawdown during purging Well Location: © �� L Facility Name: c-'-� o) � nDate: Top of Casing Elevation (ft msl): Casing Material: f V C Volume of Water Per Well Volume: gallons Total Well Depth (ftTOC): ] Depth to Water MTOC): L -7-7 Well Diameter: 2 `` Sampling Personnel Screen Screen Interval (ftTOC) / p • S - �`1. S Type of Pump: 2t`i.S �41 "�- Tubing Material: p Pump/Tubing set at: ft Weather Conditions: C\ bi-, �1 '4 >u Via° NOTES: USz�.rcn,,, i.s ctZ& no+- rc u�c 4'114rAS ;'l r. Cl[c. 01-+ hew 37.5Z`h+.,_ GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity Time Level Pumaed Rate [moll] (LCJ 5/cm I (SU) mV W-ul 1� to . "L '3 � i✓J n.1. _7 . [20 _ _ i 7. `1.7.ra - ''� , � � Ito, 7 A ` r il�b f�ia.s�z �.'z SV �• 33 17.1 � �� a � 3 I!5 S 'L& 3bbU z v . 3_ `"` , 0 _ _}Z. i -� `t i -7 l�U� '.JS�-`�— ''i9Jw ` - 'i //R. $ _S + u i Other Sample Parameters: Sampled at: \'-.-U Parameters taken with: Y� Pr K,S P� A4� °r K� f U-t , Sample Delivered to: Pei"." "." � �'' I� by K at . Field Filtration: © Yes Q No If yes, which sample parameters were'field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives): V ocs ('3"- va, C.,/kCl) I rC- 0,6 K, 3•c UC'_-s is s0A.c '± / ' S:\BBB Master Templates\Forms -2022 Forms\Low Flow Groundwater Sampling Form.pdf' """" I-— "--" ^" """'"' w Last Updated: 211412022 Procedure for Groundwater Sampling, dated April 26, 2017 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS LOW -FLOW GROUNDWATER SAMPLING RECORD Facility Name: C)-K4'. L)' : F Top of Casing Elevation (ft msl): Total Well Depth (ftTOC): 2 / . 5 Stabilization Criteria Primary: Secondary: pH +/- 0.1 unit DO +/- 0.2 mg/L S. Cond. +/- 5% ORP +/- 20 mV Turb. +/- 10% (<10 NTUs for metals) Water Level: slight or stable drawdown during purging Job No: �/�i - CXDLr Well ID: Well Location: Date: Casing Material: Iyc Volume of Water Per Well Volume: Depth to Water (ftTOC): S, Well Diameter: 2° gallons Sampling Personnel: rr" � I Screen Interval (ftTOC): - 2 (• 5- Type of Pump: f e.'kytiti' Tubing Material: L I Pump/Tubing set at: ft Weather Conditions: ©v,-(-,cf R k 7."r- NOTES: �`""d Lt� 11 O1 &10r- GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity Time Level Pumped Rate im m cci S[cm � au-1LmV] {NTU] ��r 15Z:-.,tA.. r . 7 s 5-, . i r-il � 1 `11 :9 �Sy,�L CM G / ?'• q -Z71.3 7I. - Y9, . ( 3y0O& �. z-tv _ f S' z6Y- _ 311 Other Sample Parameters: Sampled at: �.�r7 fn Parameters taken with:^ (pi,,) Aic Sample Delivered to, by �4 at Field Filtration: O Yes Q No If yes, which sample parameters were Vrfield filtered: I Sample Parameter Containers (Types, Number of Containers, Preservatives): OC-S �SK Vas' of j4C) { yC U 13 w/HC i } ILtJ Tyr �� �SCJ n L i�i�L� U 1 1W } AfL-G,1we�M �2S'O M L r411... if.[+;;_s �'vrl P' +ems i 'S:1BBB Master Templates\Forms - 2022 Forms\Low Flow Groundwater Sampling Form pdf' Stabilization criteria guidelines from the EPA SESD Operating Last Updated: 2/14/2022 Procedure for Groundwater Sampling, dated April 26, 2017. hart 14t hickman SMARTER ENVIRONMENTAL SOLUTIONS LOW -FLOW GROUNDWATER SAMPLING RECORD Job No: (� 'L- - Cam`'( , , oOS Well ID: Sr p r (,--�--,tf-t Well Location: 0 ?c Ir,., j- ti G Facility Name: ����r 1, L F: UA"'-H; 14 2 Date: � �2q,-L Z Top of Casing Elevation (ft msl):- Casing Material: Volume of Water Per Well Volume: gallons Total Well Depth (ftTOC): Depth to Water 7 (ftTOC): _ Well Diameter: Sampling Personnel: Screen Interval (ftTOC): - Type of Pump: _ Tubing Material: Pump/Tubing set at: ft Weather Conditions: C( a k 7 n OF NOTES: S'i,.l-'1 34wouL. W-" A-�., a.,,A GROUNDWATER SAMPLING PARAMETERS e0- cvlV-f-k 1 GA Water Volume Pumping DO Temp. S. Cond. pH Time Level Pumped Rate Lmgm u(US/cm)_(SU) Other Sample Parameters: U ORP Turbidity mV (NTU) Sampled at: p Parameters taken with: yrSZ FrUAL'-C-n,-"PT (ta+h) Sample Delivered to:I -� �Sr1��\L� by �e-� -K at Field Filtration: O Yes O No If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives): vor-s K<A 10 k - b i� Vo kc I '— Tr- /low "S:\BBB Master Templates\Forms - 2022 Forms\Low Flow Groundwater Sampling Form.pdr' Stabilization criteria guidelines from the EPA SESD Operating Last Updated: 2/14/2022 Procedure for Groundwater Sampling, dated April 26, 2017. Appendix B Laboratory Analytical Reports 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 November 01, 2022 Jeffrey 011ison Hart & Hickman 3921 Sunset Ridge Rd. Ste. 301 Raleigh, NC 27607 RE: Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Dear Jeffrey 011ison: Enclosed are the analytical results for sample(s) received by the laboratory on September 30, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Gulf Coast • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte A revised laboratory report is being submitted on 11/1/22 to report MDLs and applicable J values, per client request. If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni for Taylor M Cannon taylor.cannon@pacelabs.com (704)875-9092 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Pace Analytical Gulf Coast 7979 Innovation Park Drive, Baton Rouge, LA 70820 Arkansas Certification #: 88-0655 DoD ELAP Certification #: 6429-01 Florida Certification #: E87854 Illinois Certification #: 004585 Kansas Certification #: E-10354 Louisiana/LELAP Certification #: 01955 North Carolina Certification #: 618 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 CERTIFICATIONS North Dakota Certification #: R-195 Oklahoma Certification #: 2019-101 South Carolina Certification #: 73006001 Texas Certification #: T104704178-19-11 USDA Soil Permit # P330-19-00209 Virginia Certification #: 460215 Washington Certification #: C929 South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Lab ID Sample ID Matrix Date Collected Date Received 92628588001 MW-3RR Water 09/29/2212:10 09/30/22 10:30 92628588002 MW-5R Water 09/29/2215:34 09/30/22 10:30 92628588003 MW-7 Water 09/29/22 12:20 09/30/22 10:30 92628588004 NES-2S Water 09/29/2215:26 09/30/22 10:30 92628588005 SW-1 Water 09/29/2218:45 09/30/22 10:30 92628588006 SW-2 Water 09/29/2218:10 09/30/22 10:30 92628588008 TRIP BLANK Water 09/29/22 00:00 09/30/22 10:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: GM1.004/.005 OXFORD LANDFILL 92628588 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92628588001 MW-3RR EPA 601 OD DEC, RDT 16 PASI-A EPA 6020E CRW 1 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D LMB 51 PASI-C EPA 8260D Mod. LMB 3 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2011 MAB2 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 2 PASI-A 92628588002 MW-5R AM20GAX LMB 1 GCLA RSK-175 LMB 1 GCLA EPA 601 OD DEC, RDT 16 PASI-A EPA 6020E CRW 1 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D LMB 51 PASI-C EPA 8260D Mod. LMB 3 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2011 MAB2 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 3 PASI-A 92628588003 MW-7 AM20GAX LMB 1 GCLA RSK-175 LMB 1 GCLA EPA 601 OD DEC, RDT 16 PASI-A EPA 6020E CRW 1 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D LMB 51 PASI-C EPA 8260D Mod. LMB 3 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2011 MAB2 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 3 PASI-A 92628588004 NES-2S AM20GAX LMB 1 GCLA RSK-175 LMB 1 GCLA EPA 601 OD DEC, RDT 14 PASI-A EPA 6020E CRW 1 PASI-A EPA 8260D LMB 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C SM 2320B-2011 SMS 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 3 PASI-A 92628588005 SW-1 EPA 601 OD DEC, RDT 15 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA 6020E CRW 1 PASI-A EPA 8260D LMB 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92628588006 SW-2 EPA 601 OD DEC, RDT 15 PASI-A EPA 6020E CRW 1 PASI-A EPA 8260D LMB 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92628588008 TRIP BLANK EPA 8260D SAS 51 PASI-C EPA 8260D Mod. LMB 3 PASI-C GCLA = Pace Analytical Gulf Coast PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Sample: MW-3RR Lab ID: 92628588001 Collected: 09/29/22 12:10 Received: 09/30/22 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 10/05/22 01:02 10/05/22 22:00 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 10/05/22 01:02 10/10/22 19:59 7440-38-2 Barium 43.5 ug/L 5.0 3.5 1 10/05/22 01:02 10/05/22 22:00 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 10/05/22 01:02 10/05/22 22:00 7440-41-7 Cadmium 0.55.1 ug/L 1.0 0.40 1 10/05/22 01:02 10/05/22 22:00 7440-43-9 Chromium ND ug/L 5.0 3.7 1 10/05/22 01:02 10/05/22 22:00 7440-47-3 Cobalt 9.5 ug/L 5.0 3.6 1 10/05/22 01:02 10/05/22 22:00 7440-48-4 Copper ND ug/L 5.0 4.3 1 10/05/22 01:02 10/05/22 22:00 7440-50-8 Iron 3210 ug/L 50.0 41.5 1 10/05/22 01:02 10/05/22 22:00 7439-89-6 Lead ND ug/L 5.0 4.5 1 10/05/22 01:02 10/10/22 19:59 7439-92-1 Manganese 3480 ug/L 5.0 3.4 1 10/05/22 01:02 10/05/22 22:00 7439-96-5 Nickel ND ug/L 5.0 3.5 1 10/05/22 01:02 10/05/22 22:00 7440-02-0 Selenium ND ug/L 10.0 4.7 1 10/05/22 01:02 10/10/22 19:59 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/05/22 01:02 10/05/22 22:00 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 10/05/22 01:02 10/05/22 22:00 7440-62-2 Zinc ND ug/L 10.0 9.5 1 10/05/22 01:02 10/05/22 22:00 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 10/05/22 09:53 10/10/22 17:37 7440-28-0 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane Date: 11/01/2022 12:12 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 10/05/2211:57 10/06/2213:46 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 0.51J ug/L 1.0 ND ug/L 1.0 2.1 ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 5.1 1 10/04/22 16:26 67-64-1 1.8 1 10/04/22 16:26 107-13-1 0.34 1 10/04/22 16:26 71-43-2 0.47 1 10/04/22 16:26 74-97-5 0.31 1 10/04/22 16:26 75-27-4 0.34 1 10/04/22 16:26 75-25-2 1.7 1 10/04/22 16:26 74-83-9 4.0 1 10/04/22 16:26 78-93-3 0.36 1 10/04/22 16:26 75-15-0 0.33 1 10/04/22 16:26 56-23-5 0.28 1 10/04/22 16:26 108-90-7 0.65 1 10/04/22 16:26 75-00-3 0.43 1 10/04/22 16:26 67-66-3 0.54 1 10/04/22 16:26 74-87-3 0.34 1 10/04/22 16:26 96-12-8 0.36 1 10/04/22 16:26 124-48-1 0.27 1 10/04/22 16:26 106-93-4 0.39 1 10/04/22 16:26 74-95-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v3 v3 v2,v3 Page 6 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Sample: MW-3RR Lab ID: 92628588001 Collected: 09/29/22 12:10 Received: 09/30/22 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Date: 11/01/2022 12:12 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.34 1 10/04/2216:26 95-50-1 ND ug/L 1.0 0.33 1 10/04/2216:26 106-46-7 ND ug/L 1.0 0.56 1 10/04/2216:26 110-57-6 ND ug/L 1.0 0.37 1 10/04/2216:26 75-34-3 ND ug/L 1.0 0.32 1 10/04/2216:26 107-06-2 ND ug/L 1.0 0.35 1 10/04/2216:26 75-35-4 ND ug/L 1.0 0.38 1 10/04/2216:26 156-59-2 ND ug/L 1.0 0.40 1 10/04/2216:26 156-60-5 ND ug/L 1.0 0.36 1 10/04/2216:26 78-87-5 ND ug/L 1.0 0.36 1 10/04/22 16:26 10061-01-5 ND ug/L 1.0 0.36 1 10/04/2216:26 10061-02-6 ND ug/L 1.0 0.30 1 10/04/2216:26 100-41-4 ND ug/L 5.0 0.48 1 10/04/2216:26 591-78-6 ND ug/L 20.0 9.7 1 10/04/2216:26 74-88-4 ND ug/L 5.0 2.0 1 10/04/2216:26 75-09-2 ND ug/L 5.0 2.7 1 10/04/2216:26 108-10-1 ND ug/L 1.0 0.29 1 10/04/2216:26 100-42-5 ND ug/L 1.0 0.31 1 10/04/2216:26 630-20-6 ND ug/L 1.0 0.22 1 10/04/2216:26 79-34-5 ND ug/L 1.0 0.29 1 10/04/2216:26 127-18-4 ND ug/L 10.0 3.5 1 10/04/2216:26 109-99-9 ND ug/L 1.0 0.48 1 10/04/2216:26 108-88-3 ND ug/L 1.0 0.33 1 10/04/2216:26 71-55-6 ND ug/L 1.0 0.32 1 10/04/2216:26 79-00-5 ND ug/L 1.0 0.38 1 10/04/2216:26 79-01-6 ND ug/L 1.0 0.30 1 10/04/2216:26 75-69-4 ND ug/L 1.0 0.26 1 10/04/2216:26 96-18-4 ND ug/L 2.0 1.3 1 10/04/2216:26 108-05-4 ND ug/L 1.0 0.39 1 10/04/2216:26 75-01-4 ND ug/L 1.0 0.34 1 10/04/2216:26 1330-20-7 98 % 70-130 1 10/04/2216:26 460-00-4 97 % 70-130 1 10/04/2216:26 17060-07-0 101 % 70-130 1 10/04/2216:26 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 70.2 ug/L 2.0 0.86 1 10/01/2219:15 123-91-1 100 % 70-130 1 10/01 /22 19:15 17060-07-0 92 % 70-130 1 10/01 /22 19:15 2037-26-5 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville 205 mg/L 5.0 5.0 1 10/01 /22 19:14 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Sample: MW-3RR Parameters Lab ID: 92628588001 Collected: Report Results Units Limit 09/29/22 12:10 MDL DF Received: 09/30/22 10:30 Matrix: Water Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C-2011 Pace Analytical Services -Asheville Total Dissolved Solids 399 mg/L 25.0 25.0 1 10/01/22 11:16 300.0 IC anions 48hr Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Chloride 41.7 mg/L 1.0 0.60 1 09/30/2217:50 16887-00-6 Sulfate 42.4 mg/L 1.0 0.50 1 09/30/2217:50 14808-79-8 Date: 11/01/2022 12:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Sample: MW-5R Lab ID: 92628588002 Collected: 09/29/22 15:34 Received: 09/30/22 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Indicator Gases Bubblestrip H2 Analytical Method: AM20GAX Pace Analytical Gulf Coast Hydrogen 1.0J nM 1.9 0.49 1 10/05/2210:02 1333-74-0 Biodegradation Indicator Gases Analytical Method: RSK-175 Pace Analytical Gulf Coast Methane 63 ug/L 5.0 2.0 1 10/05/22 08:04 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 10/05/22 01:02 10/05/22 22:14 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 10/05/22 01:02 10/10/22 20:30 7440-38-2 Barium 56.0 ug/L 5.0 3.5 1 10/05/22 01:02 10/05/22 22:14 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 10/05/22 01:02 10/05/22 22:14 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 10/05/22 01:02 10/05/22 22:14 7440-43-9 Chromium ND ug/L 5.0 3.7 1 10/05/22 01:02 10/05/22 22:14 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 10/05/22 01:02 10/05/22 22:14 7440-48-4 Copper ND ug/L 5.0 4.3 1 10/05/22 01:02 10/05/22 22:14 7440-50-8 Iron 116 ug/L 50.0 41.5 1 10/05/22 01:02 10/05/22 22:14 7439-89-6 Lead ND ug/L 5.0 4.5 1 10/05/22 01:02 10/10/22 20:30 7439-92-1 Manganese 335 ug/L 5.0 3.4 1 10/05/22 01:02 10/05/22 22:14 7439-96-5 Nickel ND ug/L 5.0 3.5 1 10/05/22 01:02 10/05/22 22:14 7440-02-0 Selenium ND ug/L 10.0 4.7 1 10/05/22 01:02 10/10/22 20:30 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/05/22 01:02 10/05/22 22:14 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 10/05/22 01:02 10/05/22 22:14 7440-62-2 Zinc ND ug/L 10.0 9.5 1 10/05/22 01:02 10/05/22 22:14 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 10/05/22 09:53 10/10/22 18:04 7440-28-0 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury ND ug/L 0.20 0.12 1 10/05/2211:57 10/06/2213:48 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 10/04/22 16:44 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 10/04/22 16:44 107-13-1 Benzene 0.35J ug/L 1.0 0.34 1 10/04/22 16:44 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 10/04/22 16:44 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 10/04/22 16:44 75-27-4 Bromoform ND ug/L 1.0 0.34 1 10/04/22 16:44 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 10/04/22 16:44 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 10/04/22 16:44 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 10/04/22 16:44 75-15-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /01 /2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Sample: MW-5R Lab ID: 92628588002 Collected: 09/29/22 15:34 Received: 09/30/22 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Carbon tetrachloride ND ug/L 1.0 0.33 1 10/04/22 16:44 56-23-5 Chlorobenzene 1.9 ug/L 1.0 0.28 1 10/04/22 16:44 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 10/04/22 16:44 75-00-3 Chloroform ND ug/L 1.0 0.43 1 10/04/22 16:44 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 10/04/22 16:44 74-87-3 v2 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 10/04/22 16:44 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 10/04/22 16:44 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 10/04/22 16:44 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 10/04/22 16:44 74-95-3 1,2-Dichlorobenzene 1.4 ug/L 1.0 0.34 1 10/04/22 16:44 95-50-1 1,4-Dichlorobenzene 0.96J ug/L 1.0 0.33 1 10/04/22 16:44 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 10/04/22 16:44 110-57-6 1,1-Dichloroethane 1.1 ug/L 1.0 0.37 1 10/04/22 16:44 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 10/04/22 16:44 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 10/04/22 16:44 75-35-4 cis-1,2-Dichloroethene 1.9 ug/L 1.0 0.38 1 10/04/22 16:44 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 10/04/22 16:44 156-60-5 1,2-Dichloropropene ND ug/L 1.0 0.36 1 10/04/22 16:44 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 0.36 1 10/04/22 16:44 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.36 1 10/04/22 16:44 10061-02-6 Ethylbenzene ND ug/L 1.0 0.30 1 10/04/22 16:44 100-41-4 2-Hexanone ND ug/L 5.0 0.48 1 10/04/22 16:44 591-78-6 lodomethane ND ug/L 20.0 9.7 1 10/04/22 16:44 74-88-4 Methylene Chloride ND ug/L 5.0 2.0 1 10/04/22 16:44 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 2.7 1 10/04/22 16:44 108-10-1 Styrene ND ug/L 1.0 0.29 1 10/04/22 16:44 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.31 1 10/04/22 16:44 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 10/04/22 16:44 79-34-5 Tetrachloroethene ND ug/L 1.0 0.29 1 10/04/22 16:44 127-18-4 Tetrahydrofuran ND ug/L 10.0 3.5 1 10/04/22 16:44 109-99-9 Toluene ND ug/L 1.0 0.48 1 10/04/22 16:44 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.33 1 10/04/22 16:44 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.32 1 10/04/22 16:44 79-00-5 Trichloroethene ND ug/L 1.0 0.38 1 10/04/22 16:44 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.30 1 10/04/22 16:44 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.26 1 10/04/22 16:44 96-18-4 Vinyl acetate ND ug/L 2.0 1.3 1 10/04/22 16:44 108-05-4 Vinyl chloride 0.591 ug/L 1.0 0.39 1 10/04/22 16:44 75-01-4 Xylene (Total) ND ug/L 1.0 0.34 1 10/04/22 16:44 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 98 % 70-130 1 10/04/22 16:44 460-00-4 1,2-Dichloroethane-d4 (S) 99 % 70-130 1 10/04/22 16:44 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 10/04/22 16:44 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/01/2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Sample: MW-5R Lab ID: 92628588002 Collected: 09/29/22 15:34 Received: 09/30/22 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) 65.1 ug/L 2.0 0.86 1 10/01/22 19:34 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 102 % 70-130 1 10/01/22 19:34 17060-07-0 Toluene-d8 (S) 101 % 70-130 1 10/01/22 19:34 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 182 mg/L 5.0 5.0 1 10/01/22 16:03 2540C Total Dissolved Solids Analytical Method: SM 2540C-2011 Pace Analytical Services -Asheville Total Dissolved Solids 326 mg/L 25.0 25.0 1 10/01/22 11:16 300.0 IC anions 48hr Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Chloride 52.3 mg/L 1.0 0.60 1 09/30/2219:09 16887-00-6 Nitrate as N ND mg/L 0.10 0.060 1 09/30/22 19:09 14797-55-8 Sulfate 8.5 mg/L 1.0 0.50 1 09/30/2219:09 14808-79-8 Date: 11/01/2022 12:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Sample: MW-7 Lab ID: 92628588003 Collected: 09/29/22 12:20 Received: 09/30/22 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Indicator Gases Bubblestrip H2 Analytical Method: AM20GAX Pace Analytical Gulf Coast Hydrogen 9.2 nM 1.9 0.49 1 10/05/2210:14 1333-74-0 Biodegradation Indicator Gases Analytical Method: RSK-175 Pace Analytical Gulf Coast Methane ND ug/L 5.0 2.0 1 10/05/22 08:15 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 10/05/22 01:02 10/05/22 22:18 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 10/05/22 01:02 10/10/22 20:34 7440-38-2 Barium 4.3J ug/L 5.0 3.5 1 10/05/22 01:02 10/05/22 22:18 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 10/05/22 01:02 10/05/22 22:18 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 10/05/22 01:02 10/05/22 22:18 7440-43-9 Chromium ND ug/L 5.0 3.7 1 10/05/22 01:02 10/05/22 22:18 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 10/05/22 01:02 10/05/22 22:18 7440-48-4 Copper ND ug/L 5.0 4.3 1 10/05/22 01:02 10/05/22 22:18 7440-50-8 Iron 472 ug/L 50.0 41.5 1 10/05/22 01:02 10/05/22 22:18 7439-89-6 Lead ND ug/L 5.0 4.5 1 10/05/22 01:02 10/10/22 20:34 7439-92-1 Manganese 20.9 ug/L 5.0 3.4 1 10/05/22 01:02 10/05/22 22:18 7439-96-5 Nickel ND ug/L 5.0 3.5 1 10/05/22 01:02 10/05/22 22:18 7440-02-0 Selenium ND ug/L 10.0 4.7 1 10/05/22 01:02 10/10/22 20:34 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/05/22 01:02 10/05/22 22:18 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 10/05/22 01:02 10/05/22 22:18 7440-62-2 Zinc ND ug/L 10.0 9.5 1 10/05/22 01:02 10/05/22 22:18 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 10/05/22 09:53 10/10/22 18:08 7440-28-0 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury ND ug/L 0.20 0.12 1 10/05/2211:57 10/06/2213:50 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 10/04/22 17:02 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 10/04/22 17:02 107-13-1 Benzene ND ug/L 1.0 0.34 1 10/04/22 17:02 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 10/04/22 17:02 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 10/04/22 17:02 75-27-4 Bromoform ND ug/L 1.0 0.34 1 10/04/22 17:02 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 10/04/22 17:02 74-83-9 2-Butanone (MEK) 5.1 ug/L 5.0 4.0 1 10/04/22 17:02 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 10/04/22 17:02 75-15-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /01 /2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Sample: MW-7 Lab ID: 92628588003 Collected: 09/29/22 12:20 Received: 09/30/22 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Carbon tetrachloride ND ug/L 1.0 0.33 1 10/04/22 17:02 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 10/04/22 17:02 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 10/04/22 17:02 75-00-3 Chloroform ND ug/L 1.0 0.43 1 10/04/22 17:02 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 10/04/22 17:02 74-87-3 v2 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 10/04/22 17:02 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 10/04/22 17:02 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 10/04/22 17:02 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 10/04/22 17:02 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 10/04/22 17:02 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 10/04/22 17:02 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 10/04/22 17:02 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 10/04/22 17:02 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 10/04/22 17:02 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 10/04/22 17:02 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 10/04/22 17:02 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 10/04/22 17:02 156-60-5 1,2-Dichloropropene ND ug/L 1.0 0.36 1 10/04/22 17:02 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 0.36 1 10/04/22 17:02 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.36 1 10/04/22 17:02 10061-02-6 Ethylbenzene ND ug/L 1.0 0.30 1 10/04/22 17:02 100-41-4 2-Hexanone ND ug/L 5.0 0.48 1 10/04/22 17:02 591-78-6 lodomethane ND ug/L 20.0 9.7 1 10/04/22 17:02 74-88-4 Methylene Chloride ND ug/L 5.0 2.0 1 10/04/22 17:02 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 2.7 1 10/04/22 17:02 108-10-1 Styrene ND ug/L 1.0 0.29 1 10/04/22 17:02 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.31 1 10/04/22 17:02 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 10/04/22 17:02 79-34-5 Tetrachloroethene ND ug/L 1.0 0.29 1 10/04/22 17:02 127-18-4 Tetrahydrofuran ND ug/L 10.0 3.5 1 10/04/22 17:02 109-99-9 Toluene ND ug/L 1.0 0.48 1 10/04/22 17:02 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.33 1 10/04/22 17:02 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.32 1 10/04/22 17:02 79-00-5 Trichloroethene ND ug/L 1.0 0.38 1 10/04/22 17:02 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.30 1 10/04/22 17:02 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.26 1 10/04/22 17:02 96-18-4 Vinyl acetate ND ug/L 2.0 1.3 1 10/04/22 17:02 108-05-4 Vinyl chloride ND ug/L 1.0 0.39 1 10/04/22 17:02 75-01-4 Xylene (Total) ND ug/L 1.0 0.34 1 10/04/22 17:02 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 97 % 70-130 1 10/04/22 17:02 460-00-4 1,2-Dichloroethane-d4 (S) 97 % 70-130 1 10/04/22 17:02 17060-07-0 Toluene-d8 (S) 102 % 70-130 1 10/04/22 17:02 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/01/2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Sample: MW-7 Lab ID: 92628588003 Collected: 09/29/22 12:20 Received: 09/30/22 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) 1.7J ug/L 2.0 0.86 1 10/01/22 19:53 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 101 % 70-130 1 10/01/22 19:53 17060-07-0 Toluene-d8 (S) 113 % 70-130 1 10/01/22 19:53 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 144 mg/L 5.0 5.0 1 10/01/22 16:29 2540C Total Dissolved Solids Analytical Method: SM 2540C-2011 Pace Analytical Services -Asheville Total Dissolved Solids 246 mg/L 25.0 25.0 1 10/01/22 11:16 300.0 IC anions 48hr Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Chloride 7.6 mg/L 1.0 0.60 1 09/30/2218:37 16887-00-6 Nitrate as N 0.24 mg/L 0.10 0.060 1 09/30/22 18:37 14797-55-8 Sulfate 41.2 mg/L 1.0 0.50 1 09/30/2218:37 14808-79-8 Date: 11/01/2022 12:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Sample: NES-2S Lab ID: 92628588004 Collected: 09/29/22 15:26 Received: 09/30/22 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Indicator Gases Bubblestrip H2 Analytical Method: AM20GAX Pace Analytical Gulf Coast Hydrogen 0.78J nM 1.9 0.49 1 10/05/2210:26 1333-74-0 Biodegradation Indicator Gases Analytical Method: RSK-175 Pace Analytical Gulf Coast Methane 74 ug/L 5.0 2.0 1 10/05/22 08:27 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 10/05/22 01:02 10/05/22 22:21 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 10/05/22 01:02 10/10/22 20:37 7440-38-2 Barium 33.7 ug/L 5.0 3.5 1 10/05/22 01:02 10/05/22 22:21 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 10/05/22 01:02 10/05/22 22:21 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 10/05/22 01:02 10/05/22 22:21 7440-43-9 Chromium ND ug/L 5.0 3.7 1 10/05/22 01:02 10/05/22 22:21 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 10/05/22 01:02 10/05/22 22:21 7440-48-4 Copper ND ug/L 5.0 4.3 1 10/05/22 01:02 10/05/22 22:21 7440-50-8 Lead ND ug/L 5.0 4.5 1 10/05/22 01:02 10/10/22 20:37 7439-92-1 Nickel ND ug/L 5.0 3.5 1 10/05/22 01:02 10/05/22 22:21 7440-02-0 Selenium ND ug/L 10.0 4.7 1 10/05/22 01:02 10/10/22 20:37 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/05/22 01:02 10/05/22 22:21 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 10/05/22 01:02 10/05/22 22:21 7440-62-2 Zinc ND ug/L 10.0 9.5 1 10/05/22 01:02 10/05/22 22:21 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 10/05/22 09:53 10/10/22 18:12 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 10/04/22 17:21 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 10/04/22 17:21 107-13-1 Benzene ND ug/L 1.0 0.34 1 10/04/22 17:21 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 10/04/22 17:21 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 10/04/22 17:21 75-27-4 Bromoform ND ug/L 1.0 0.34 1 10/04/22 17:21 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 10/04/22 17:21 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 10/04/22 17:21 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 10/04/22 17:21 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 10/04/22 17:21 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 10/04/22 17:21 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 10/04/22 17:21 75-00-3 Chloroform ND ug/L 1.0 0.43 1 10/04/22 17:21 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 10/04/22 17:21 74-87-3 v2 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 10/04/22 17:21 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /01 /2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Sample: NES-2S Lab ID: 92628588004 Collected: 09/29/22 15:26 Received: 09/30/22 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Dibromochloromethane ND ug/L 1.0 0.36 1 10/04/22 17:21 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 10/04/22 17:21 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 10/04/22 17:21 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 10/04/22 17:21 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 10/04/22 17:21 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 10/04/22 17:21 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 10/04/22 17:21 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 10/04/22 17:21 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 10/04/22 17:21 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 10/04/22 17:21 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 10/04/22 17:21 156-60-5 1,2-Dichloropropene ND ug/L 1.0 0.36 1 10/04/22 17:21 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 0.36 1 10/04/22 17:21 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.36 1 10/04/22 17:21 10061-02-6 Ethylbenzene ND ug/L 1.0 0.30 1 10/04/22 17:21 100-41-4 2-Hexanone ND ug/L 5.0 0.48 1 10/04/22 17:21 591-78-6 lodomethane ND ug/L 20.0 9.7 1 10/04/22 17:21 74-88-4 Methylene Chloride ND ug/L 5.0 2.0 1 10/04/22 17:21 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 2.7 1 10/04/22 17:21 108-10-1 Styrene ND ug/L 1.0 0.29 1 10/04/22 17:21 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.31 1 10/04/22 17:21 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 10/04/22 17:21 79-34-5 Tetrachloroethene ND ug/L 1.0 0.29 1 10/04/22 17:21 127-18-4 Toluene ND ug/L 1.0 0.48 1 10/04/22 17:21 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.33 1 10/04/22 17:21 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.32 1 10/04/22 17:21 79-00-5 Trichloroethene ND ug/L 1.0 0.38 1 10/04/22 17:21 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.30 1 10/04/22 17:21 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.26 1 10/04/22 17:21 96-18-4 Vinyl acetate ND ug/L 2.0 1.3 1 10/04/22 17:21 108-05-4 Vinyl chloride ND ug/L 1.0 0.39 1 10/04/22 17:21 75-01-4 Xylene (Total) ND ug/L 1.0 0.34 1 10/04/22 17:21 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 10/04/22 17:21 460-00-4 1,2-Dichloroethane-d4 (S) 105 % 70-130 1 10/04/22 17:21 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 10/04/22 17:21 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 0.86 1 10/01/22 20:12 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 103 % 70-130 1 10/01/22 20:12 17060-07-0 Toluene-d8 (S) 102 % 70-130 1 10/01/22 20:12 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/01/2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Sample: NES-2S Lab ID: 92628588004 Collected: 09/29/22 15:26 Received: 09/30/22 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 77.4 mg/L 5.0 5.0 1 10/01/22 16:40 300.0 IC anions 48hr Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Chloride 10.4 mg/L 1.0 0.60 1 09/30/2218:53 16887-00-6 Nitrate as N 0.20 mg/L 0.10 0.060 1 09/30/22 18:53 14797-55-8 Sulfate 30.1 mg/L 1.0 0.50 1 09/30/2218:53 14808-79-8 Date: 11/01/2022 12:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Sample: SW-1 Lab ID: 92628588005 Collected: 09/29/22 18:45 Received: 09/30/22 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Hardness, Total(SM 2340B) Vanadium Zinc Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville ND ug/L 5.0 3.0 1 10/05/22 01:02 10/05/22 22:25 7440-36-0 ND ug/L 10.0 4.7 1 10/05/22 01:02 10/10/22 20:48 7440-38-2 23.5 ug/L 5.0 3.5 1 10/05/22 01:02 10/05/22 22:25 7440-39-3 ND ug/L 1.0 0.70 1 10/05/22 01:02 10/05/22 22:25 7440-41-7 ND ug/L 1.0 0.40 1 10/05/22 01:02 10/05/22 22:25 7440-43-9 ND ug/L 5.0 3.7 1 10/05/22 01:02 10/05/22 22:25 7440-47-3 ND ug/L 5.0 3.6 1 10/05/22 01:02 10/05/22 22:25 7440-48-4 ND ug/L 5.0 4.3 1 10/05/22 01:02 10/05/22 22:25 7440-50-8 ND ug/L 5.0 4.5 1 10/05/22 01:02 10/10/22 20:48 7439-92-1 ND ug/L 5.0 3.5 1 10/05/22 01:02 10/05/22 22:25 7440-02-0 ND ug/L 10.0 4.7 1 10/05/22 01:02 10/10/22 20:48 7782-49-2 ND ug/L 5.0 2.5 1 10/05/22 01:02 10/05/22 22:25 7440-22-4 32700 ug/L 662 131 1 10/05/22 01:02 10/05/22 22:25 ND ug/L 5.0 3.9 1 10/05/22 01:02 10/05/22 22:25 7440-62-2 ND ug/L 10.0 9.5 1 10/05/22 01:02 10/05/22 22:25 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 10/05/22 09:53 10/10/22 18:16 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 10/04/22 17:39 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 10/04/22 17:39 107-13-1 Benzene ND ug/L 1.0 0.34 1 10/04/22 17:39 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 10/04/22 17:39 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 10/04/22 17:39 75-27-4 Bromoform ND ug/L 1.0 0.34 1 10/04/22 17:39 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 10/04/22 17:39 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 10/04/22 17:39 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 10/04/22 17:39 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 10/04/22 17:39 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 10/04/22 17:39 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 10/04/22 17:39 75-00-3 Chloroform ND ug/L 1.0 0.43 1 10/04/22 17:39 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 10/04/22 17:39 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 10/04/22 17:39 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 10/04/22 17:39 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 10/04/22 17:39 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 10/04/22 17:39 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 10/04/22 17:39 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 10/04/22 17:39 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 10/04/22 17:39 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 10/04/22 17:39 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 10/04/22 17:39 107-06-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /01 /2022 12:12 PM without the written consent of Pace Analytical Services, LLC. v2 Page 18 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Sample: SW-1 Lab ID: 92628588005 Collected: 09/29/22 18:45 Received: 09/30/22 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/01/2022 12:12 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.35 1 10/04/2217:39 75-35-4 ND ug/L 1.0 0.38 1 10/04/2217:39 156-59-2 ND ug/L 1.0 0.40 1 10/04/2217:39 156-60-5 ND ug/L 1.0 0.36 1 10/04/2217:39 78-87-5 ND ug/L 1.0 0.36 1 10/04/22 17:39 10061-01-5 ND ug/L 1.0 0.36 1 10/04/2217:39 10061-02-6 ND ug/L 1.0 0.30 1 10/04/2217:39 100-41-4 ND ug/L 5.0 0.48 1 10/04/2217:39 591-78-6 ND ug/L 20.0 9.7 1 10/04/2217:39 74-88-4 ND ug/L 5.0 2.0 1 10/04/2217:39 75-09-2 ND ug/L 5.0 2.7 1 10/04/2217:39 108-10-1 ND ug/L 1.0 0.29 1 10/04/2217:39 100-42-5 ND ug/L 1.0 0.31 1 10/04/2217:39 630-20-6 ND ug/L 1.0 0.22 1 10/04/2217:39 79-34-5 ND ug/L 1.0 0.29 1 10/04/2217:39 127-18-4 ND ug/L 1.0 0.48 1 10/04/2217:39 108-88-3 ND ug/L 1.0 0.33 1 10/04/2217:39 71-55-6 ND ug/L 1.0 0.32 1 10/04/2217:39 79-00-5 ND ug/L 1.0 0.38 1 10/04/2217:39 79-01-6 ND ug/L 1.0 0.30 1 10/04/2217:39 75-69-4 ND ug/L 1.0 0.26 1 10/04/2217:39 96-18-4 ND ug/L 2.0 1.3 1 10/04/2217:39 108-05-4 ND ug/L 1.0 0.39 1 10/04/2217:39 75-01-4 ND ug/L 1.0 0.34 1 10/04/2217:39 1330-20-7 97 % 70-130 1 10/04/2217:39 460-00-4 101 % 70-130 1 10/04/2217:39 17060-07-0 101 % 70-130 1 10/04/2217:39 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 10/01/22 20:31 123-91-1 102 % 70-130 1 10/01 /22 20:31 17060-07-0 104 % 70-130 1 10/01 /22 20:31 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Sample: SW-2 Lab ID: 92628588006 Collected: 09/29/22 18:10 Received: 09/30/22 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Hardness, Total(SM 2340B) Vanadium Zinc Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville ND ug/L 5.0 3.0 1 10/05/22 01:02 10/05/22 22:28 7440-36-0 ND ug/L 10.0 4.7 1 10/05/22 01:02 10/10/22 20:51 7440-38-2 25.3 ug/L 5.0 3.5 1 10/05/22 01:02 10/05/22 22:28 7440-39-3 ND ug/L 1.0 0.70 1 10/05/22 01:02 10/05/22 22:28 7440-41-7 ND ug/L 1.0 0.40 1 10/05/22 01:02 10/05/22 22:28 7440-43-9 ND ug/L 5.0 3.7 1 10/05/22 01:02 10/05/22 22:28 7440-47-3 ND ug/L 5.0 3.6 1 10/05/22 01:02 10/05/22 22:28 7440-48-4 ND ug/L 5.0 4.3 1 10/05/22 01:02 10/05/22 22:28 7440-50-8 ND ug/L 5.0 4.5 1 10/05/22 01:02 10/10/22 20:51 7439-92-1 ND ug/L 5.0 3.5 1 10/05/22 01:02 10/05/22 22:28 7440-02-0 ND ug/L 10.0 4.7 1 10/05/22 01:02 10/10/22 20:51 7782-49-2 ND ug/L 5.0 2.5 1 10/05/22 01:02 10/05/22 22:28 7440-22-4 62300 ug/L 662 131 1 10/05/22 01:02 10/05/22 22:28 ND ug/L 5.0 3.9 1 10/05/22 01:02 10/05/22 22:28 7440-62-2 ND ug/L 10.0 9.5 1 10/05/22 01:02 10/05/22 22:28 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 10/05/22 09:53 10/10/22 18:20 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 10/04/22 17:58 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 10/04/22 17:58 107-13-1 Benzene ND ug/L 1.0 0.34 1 10/04/22 17:58 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 10/04/22 17:58 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 10/04/22 17:58 75-27-4 Bromoform ND ug/L 1.0 0.34 1 10/04/22 17:58 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 10/04/22 17:58 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 10/04/22 17:58 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 10/04/22 17:58 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 10/04/22 17:58 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 10/04/22 17:58 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 10/04/22 17:58 75-00-3 Chloroform ND ug/L 1.0 0.43 1 10/04/22 17:58 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 10/04/22 17:58 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 10/04/22 17:58 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 10/04/22 17:58 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 10/04/22 17:58 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 10/04/22 17:58 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 10/04/22 17:58 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 10/04/22 17:58 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 10/04/22 17:58 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 10/04/22 17:58 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 10/04/22 17:58 107-06-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /01 /2022 12:12 PM without the written consent of Pace Analytical Services, LLC. v2 Page 20 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Sample: SW-2 Lab ID: 92628588006 Collected: 09/29/22 18:10 Received: 09/30/22 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/01/2022 12:12 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.35 1 10/04/2217:58 75-35-4 ND ug/L 1.0 0.38 1 10/04/2217:58 156-59-2 ND ug/L 1.0 0.40 1 10/04/2217:58 156-60-5 ND ug/L 1.0 0.36 1 10/04/2217:58 78-87-5 ND ug/L 1.0 0.36 1 10/04/22 17:58 10061-01-5 ND ug/L 1.0 0.36 1 10/04/2217:58 10061-02-6 ND ug/L 1.0 0.30 1 10/04/2217:58 100-41-4 ND ug/L 5.0 0.48 1 10/04/2217:58 591-78-6 ND ug/L 20.0 9.7 1 10/04/2217:58 74-88-4 ND ug/L 5.0 2.0 1 10/04/2217:58 75-09-2 ND ug/L 5.0 2.7 1 10/04/2217:58 108-10-1 ND ug/L 1.0 0.29 1 10/04/2217:58 100-42-5 ND ug/L 1.0 0.31 1 10/04/2217:58 630-20-6 ND ug/L 1.0 0.22 1 10/04/2217:58 79-34-5 ND ug/L 1.0 0.29 1 10/04/2217:58 127-18-4 ND ug/L 1.0 0.48 1 10/04/2217:58 108-88-3 ND ug/L 1.0 0.33 1 10/04/2217:58 71-55-6 ND ug/L 1.0 0.32 1 10/04/2217:58 79-00-5 ND ug/L 1.0 0.38 1 10/04/2217:58 79-01-6 ND ug/L 1.0 0.30 1 10/04/2217:58 75-69-4 ND ug/L 1.0 0.26 1 10/04/2217:58 96-18-4 ND ug/L 2.0 1.3 1 10/04/2217:58 108-05-4 ND ug/L 1.0 0.39 1 10/04/2217:58 75-01-4 ND ug/L 1.0 0.34 1 10/04/2217:58 1330-20-7 96 % 70-130 1 10/04/2217:58 460-00-4 100 % 70-130 1 10/04/2217:58 17060-07-0 103 % 70-130 1 10/04/2217:58 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 10/01/22 20:50 123-91-1 101 % 70-130 1 10/01 /22 20:50 17060-07-0 106 % 70-130 1 10/01 /22 20:50 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Sample: TRIP BLANK Lab ID: 92628588008 Collected: 09/29/22 00:00 Received: 09/30/22 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Date: 11/01/2022 12:12 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 5.1 1 10/02/2219:23 67-64-1 ND ug/L 10.0 1.8 1 10/02/2219:23 107-13-1 ND ug/L 1.0 0.34 1 10/02/2219:23 71-43-2 ND ug/L 1.0 0.47 1 10/02/2219:23 74-97-5 ND ug/L 1.0 0.31 1 10/02/2219:23 75-27-4 ND ug/L 1.0 0.34 1 10/02/2219:23 75-25-2 ND ug/L 2.0 1.7 1 10/02/2219:23 74-83-9 ND ug/L 5.0 4.0 1 10/02/2219:23 78-93-3 ND ug/L 2.0 0.36 1 10/02/2219:23 75-15-0 ND ug/L 1.0 0.33 1 10/02/2219:23 56-23-5 ND ug/L 1.0 0.28 1 10/02/2219:23 108-90-7 ND ug/L 1.0 0.65 1 10/02/2219:23 75-00-3 ND ug/L 1.0 0.43 1 10/02/2219:23 67-66-3 ND ug/L 1.0 0.54 1 10/02/2219:23 74-87-3 ND ug/L 2.0 0.34 1 10/02/2219:23 96-12-8 ND ug/L 1.0 0.36 1 10/02/2219:23 124-48-1 ND ug/L 1.0 0.27 1 10/02/2219:23 106-93-4 ND ug/L 1.0 0.39 1 10/02/2219:23 74-95-3 ND ug/L 1.0 0.34 1 10/02/2219:23 95-50-1 ND ug/L 1.0 0.33 1 10/02/2219:23 106-46-7 ND ug/L 1.0 0.56 1 10/02/2219:23 110-57-6 ND ug/L 1.0 0.37 1 10/02/2219:23 75-34-3 ND ug/L 1.0 0.32 1 10/02/2219:23 107-06-2 ND ug/L 1.0 0.35 1 10/02/2219:23 75-35-4 ND ug/L 1.0 0.38 1 10/02/2219:23 156-59-2 ND ug/L 1.0 0.40 1 10/02/2219:23 156-60-5 ND ug/L 1.0 0.36 1 10/02/2219:23 78-87-5 ND ug/L 1.0 0.36 1 10/02/22 19:23 10061-01-5 ND ug/L 1.0 0.36 1 10/02/2219:23 10061-02-6 ND ug/L 1.0 0.30 1 10/02/2219:23 100-41-4 ND ug/L 5.0 0.48 1 10/02/2219:23 591-78-6 ND ug/L 20.0 9.7 1 10/02/2219:23 74-88-4 ND ug/L 5.0 2.0 1 10/02/2219:23 75-09-2 ND ug/L 5.0 2.7 1 10/02/2219:23 108-10-1 ND ug/L 1.0 0.29 1 10/02/2219:23 100-42-5 ND ug/L 1.0 0.31 1 10/02/2219:23 630-20-6 ND ug/L 1.0 0.22 1 10/02/2219:23 79-34-5 ND ug/L 1.0 0.29 1 10/02/2219:23 127-18-4 ND ug/L 10.0 3.5 1 10/02/2219:23 109-99-9 ND ug/L 1.0 0.48 1 10/02/2219:23 108-88-3 ND ug/L 1.0 0.33 1 10/02/2219:23 71-55-6 ND ug/L 1.0 0.32 1 10/02/2219:23 79-00-5 ND ug/L 1.0 0.38 1 10/02/2219:23 79-01-6 ND ug/L 1.0 0.30 1 10/02/2219:23 75-69-4 ND ug/L 1.0 0.26 1 10/02/2219:23 96-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IN Page 22 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Sample: TRIP BLANK Parameters Lab ID: 92628588008 Collected: Report Results Units Limit 09/29/22 00:00 MDL DF Received: 09/30/22 10:30 Matrix: Water Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Vinyl acetate ND ug/L 2.0 1.3 1 10/02/22 19:23 108-05-4 Vinyl chloride ND ug/L 1.0 0.39 1 10/02/22 19:23 75-01-4 Xylene (Total) ND ug/L 1.0 0.34 1 10/02/22 19:23 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 94 % 70-130 1 10/02/22 19:23 460-00-4 1,2-Dichloroethane-d4 (S) 114 % 70-130 1 10/02/22 19:23 17060-07-0 Toluene-d8 (S) 110 % 70-130 1 10/02/22 19:23 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 0.86 1 10/01/22 15:05 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 111 % 70-130 1 10/01/22 15:05 17060-07-0 Toluene-d8 (S) 109 % 70-130 1 10/01/22 15:05 2037-26-5 Date: 11/01/2022 12:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 48 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 QC Batch: 751115 Analysis Method: AM20GAX QC Batch Method: AM20GAX Analysis Description: Indicator Gases Bubble Strip H2 Laboratory: Pace Analytical Gulf Coast Associated Lab Samples: 92628588002, 92628588003, 92628588004 METHOD BLANK: 2403342 Matrix: Air Associated Lab Samples: 92628588002, 92628588003, 92628588004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Hydrogen nM ND 1.9 0.49 10/05/22 06:35 LABORATORY CONTROL SAMPLE & LCSD: 2403343 2403344 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Hydrogen nM 12 12 11 98 95 70-130 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /01 /2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 48 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 QC Batch: 751162 Analysis Method: RSK-175 QC Batch Method: RSK-175 Analysis Description: Biodegradation Indicator Gases Laboratory: Pace Analytical Gulf Coast Associated Lab Samples: 92628588002, 92628588003, 92628588004 METHOD BLANK: 2403704 Matrix: Water Associated Lab Samples: 92628588002, 92628588003, 92628588004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Methane ug/L ND 5.0 2.0 10/05/22 06:10 LABORATORY CONTROL SAMPLE & LCSD: 2403705 2403706 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Methane ug/L 380 330 330 87 87 70-130 0 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /01 /2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 48 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 QC Batch: 727674 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92628588001, 92628588002, 92628588003 METHOD BLANK: 3789251 Matrix: Water Associated Lab Samples: 92628588001, 92628588002, 92628588003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.12 10/06/2213:00 LABORATORY CONTROL SAMPLE: 3789252 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.5 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3789253 3789254 MS MSD 92628412001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.1 2.2 84 87 75-125 3 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /01 /2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 48 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 QC Batch: 727880 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92628588001, 92628588002, 92628588003, 92628588004, 92628588005, 92628588006 METHOD BLANK: 3790578 Matrix: Water Associated Lab Samples: 92628588001, 92628588002, 92628588003, 92628588004, 92628588005, 92628588006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 3.0 10/05/22 21:46 Arsenic ug/L ND 10.0 4.7 10/10/2219:52 Barium ug/L ND 5.0 3.5 10/05/22 21:46 Beryllium ug/L ND 1.0 0.70 10/05/22 21:46 Cadmium ug/L ND 1.0 0.40 10/05/22 21:46 Chromium ug/L ND 5.0 3.7 10/10/2219:52 Cobalt ug/L ND 5.0 3.6 10/05/22 21:46 Copper ug/L ND 5.0 4.3 10/05/22 21:46 Hardness, Total(SM 2340B) ug/L ND 662 131 10/05/22 21:46 Iron ug/L ND 50.0 41.5 10/05/22 21:46 Lead ug/L ND 5.0 4.5 10/10/2219:52 Manganese ug/L ND 5.0 3.4 10/05/22 21:46 Nickel ug/L ND 5.0 3.5 10/05/22 21:46 Selenium ug/L ND 10.0 4.7 10/10/2219:52 Silver ug/L ND 5.0 2.5 10/05/22 21:46 Vanadium ug/L ND 5.0 3.9 10/05/22 21:46 Zinc ug/L ND 10.0 9.5 10/05/22 21:46 LABORATORY CONTROL SAMPLE: 3790579 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 500 496 99 80-120 Arsenic ug/L 500 476 95 80-120 Barium ug/L 500 487 97 80-120 Beryllium ug/L 500 490 98 80-120 Cadmium ug/L 500 494 99 80-120 Chromium ug/L 500 495 99 80-120 Cobalt ug/L 500 505 101 80-120 Copper ug/L 500 523 105 80-120 Hardness, Total(SM 2340B) ug/L 33100 32900 99 80-120 Iron ug/L 5000 4920 98 80-120 Lead ug/L 500 494 99 80-120 Manganese ug/L 500 514 103 80-120 Nickel ug/L 500 502 100 80-120 Selenium ug/L 500 483 97 80-120 Silver ug/L 250 234 93 80-120 Vanadium ug/L 500 536 107 80-120 Zinc ug/L 500 502 100 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/01/2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 48 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 MATRIX SPIKE & MATRIX SPIKE Parameter DUPLICATE: 3790580 MS 92628588001 Spike Units Result Conc. MSD Spike Conc. 3790581 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Antimony ug/L ND 500 500 514 506 103 101 75-125 1 20 Arsenic ug/L ND 500 500 498 491 99 97 75-125 2 20 Barium ug/L 43.5 500 500 546 532 100 98 75-125 3 20 Beryllium ug/L ND 500 500 509 498 102 100 75-125 2 20 Cadmium ug/L 0.55J 500 500 520 514 104 103 75-125 1 20 Chromium ug/L ND 500 500 520 502 104 100 75-125 3 20 Cobalt ug/L 9.5 500 500 518 512 102 100 75-125 1 20 Copper ug/L ND 500 500 534 517 107 103 75-125 3 20 Hardness, Total(SM 2340B) ug/L 95000 33100 33100 131000 127000 110 97 75-125 3 20 Iron ug/L 3210 5000 5000 8340 8170 102 99 75-125 2 20 Lead ug/L ND 500 500 487 481 97 96 75-125 1 20 Manganese ug/L 3480 500 500 4090 3980 121 100 75-125 3 20 Nickel ug/L ND 500 500 510 505 101 100 75-125 1 20 Selenium ug/L ND 500 500 518 510 103 102 75-125 2 20 Silver ug/L ND 250 250 241 237 96 95 75-125 2 20 Vanadium ug/L ND 500 500 553 537 110 107 75-125 3 20 Zinc ug/L ND 500 500 522 514 103 101 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /01 /2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 48 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 QC Batch: 727920 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92628588001, 92628588002, 92628588003, 92628588004, 92628588005, 92628588006 METHOD BLANK: 3790630 Matrix: Water Associated Lab Samples: 92628588001, 92628588002, 92628588003, 92628588004, 92628588005, 92628588006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.47 0.050 10/10/2217:29 LABORATORY CONTROL SAMPLE: 3790631 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 25 25.6 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3790632 3790633 MS MSD 92628588001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 25 25 25.7 26.0 103 104 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /01 /2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 48 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 QC Batch: 727360 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92628588008 METHOD BLANK: 3787851 Associated Lab Samples: 92628588008 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 10/02/22 18:47 1,1,1-Trichloroethane ug/L ND 1.0 0.33 10/02/22 18:47 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 10/02/22 18:47 1,1,2-Trichloroethane ug/L ND 1.0 0.32 10/02/22 18:47 1,1-Dichloroethane ug/L ND 1.0 0.37 10/02/22 18:47 1,1-Dichloroethene ug/L ND 1.0 0.35 10/02/22 18:47 1,2,3-Trichloropropane ug/L ND 1.0 0.26 10/02/22 18:47 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 10/02/22 18:47 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 10/02/22 18:47 1,2-Dichlorobenzene ug/L ND 1.0 0.34 10/02/22 18:47 1,2-Dichloroethane ug/L ND 1.0 0.32 10/02/22 18:47 1,2-Dichloropropane ug/L ND 1.0 0.36 10/02/22 18:47 1,4-Dichlorobenzene ug/L ND 1.0 0.33 10/02/22 18:47 2-Butanone (MEK) ug/L ND 5.0 4.0 10/02/22 18:47 2-Hexanone ug/L ND 5.0 0.48 10/02/22 18:47 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 10/02/22 18:47 Acetone ug/L ND 25.0 5.1 10/02/22 18:47 Acrylonitrile ug/L ND 10.0 1.8 10/02/22 18:47 Benzene ug/L ND 1.0 0.34 10/02/22 18:47 Bromochloromethane ug/L ND 1.0 0.47 10/02/22 18:47 Bromodichloromethane ug/L ND 1.0 0.31 10/02/22 18:47 Bromoform ug/L ND 1.0 0.34 10/02/22 18:47 Bromomethane ug/L ND 2.0 1.7 10/02/22 18:47 Carbon disulfide ug/L ND 2.0 0.36 10/02/22 18:47 Carbon tetrachloride ug/L ND 1.0 0.33 10/02/22 18:47 Chlorobenzene ug/L ND 1.0 0.28 10/02/22 18:47 Chloroethane ug/L ND 1.0 0.65 10/02/22 18:47 Chloroform ug/L ND 1.0 0.43 10/02/22 18:47 Chloromethane ug/L ND 1.0 0.54 10/02/22 18:47 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 10/02/22 18:47 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 10/02/22 18:47 Dibromochloromethane ug/L ND 1.0 0.36 10/02/22 18:47 Dibromomethane ug/L ND 1.0 0.39 10/02/22 18:47 Ethylbenzene ug/L ND 1.0 0.30 10/02/22 18:47 lodomethane ug/L ND 20.0 9.7 10/02/22 18:47 Methylene Chloride ug/L ND 5.0 2.0 10/02/22 18:47 Styrene ug/L ND 1.0 0.29 10/02/22 18:47 Tetrachloroethene ug/L ND 1.0 0.29 10/02/22 18:47 Tetrahydrofuran ug/L ND 10.0 3.5 10/02/22 18:47 Toluene ug/L ND 1.0 0.48 10/02/22 18:47 IK Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /01 /2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 48 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 METHOD BLANK: 3787851 Matrix: Water Associated Lab Samples: 92628588008 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.40 10/02/22 18:47 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 10/02/22 18:47 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 10/02/22 18:47 Trichloroethene ug/L ND 1.0 0.38 10/02/22 18:47 Trichlorofluoromethane ug/L ND 1.0 0.30 10/02/22 18:47 Vinyl acetate ug/L ND 2.0 1.3 10/02/22 18:47 Vinyl chloride ug/L ND 1.0 0.39 10/02/22 18:47 Xylene (Total) ug/L ND 1.0 0.34 10/02/22 18:47 1,2-Dichloroethane-d4 (S) % 118 70-130 10/02/22 18:47 4-Bromofluorobenzene (S) % 96 70-130 10/02/22 18:47 Toluene-d8 (S) % 111 70-130 10/02/22 18:47 LABORATORY CONTROL SAMPLE: 3787852 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 54.3 109 70-130 1,1,1-Trichloroethane ug/L 50 54.3 109 70-130 1,1,2,2-Tetrachloroethane ug/L 50 54.7 109 70-130 1,1,2-Trichloroethane ug/L 50 53.1 106 70-130 1,1-Dichloroethane ug/L 50 53.0 106 70-130 1,1-Dichloroethene ug/L 50 54.3 109 70-130 1,2,3-Trichloropropane ug/L 50 54.7 109 70-130 1,2-Dibromo-3-chloropropane ug/L 50 53.7 107 70-131 1,2-Dibromoethane (EDB) ug/L 50 52.8 106 70-130 1,2-Dichlorobenzene ug/L 50 52.3 105 70-130 1,2-Dichloroethane ug/L 50 55.6 111 70-130 1,2-Dichloropropane ug/L 50 50.9 102 70-130 1,4-Dichlorobenzene ug/L 50 51.2 102 70-130 2-Butanone (MEK) ug/L 100 106 106 70-134 2-Hexanone ug/L 100 114 114 70-131 4-Methyl-2-pentanone (MIBK) ug/L 100 108 108 70-130 Acetone ug/L 100 106 106 70-133 Acrylonitrile ug/L 250 272 109 70-130 Benzene ug/L 50 47.2 94 70-130 Bromochloromethane ug/L 50 52.1 104 70-130 Bromodichloromethane ug/L 50 52.5 105 70-130 Bromoform ug/L 50 52.3 105 70-130 Bromomethane ug/L 50 45.0 90 45-151 Carbon disulfide ug/L 50 48.1 96 70-130 Carbon tetrachloride ug/L 50 51.6 103 70-130 Chlorobenzene ug/L 50 52.6 105 70-130 Chloroethane ug/L 50 57.6 115 39-152 IK Chloroform ug/L 50 53.6 107 70-130 Chloromethane ug/L 50 50.0 100 58-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/01/2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 48 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 LABORATORY CONTROL SAMPLE: Parameter 3787852 Units Spike Conc. LCS Result LCS % Rec % Rec Limits cis-1,2-Dichloroethene ug/L 50 54.6 109 70-130 cis-1,3-Dichloropropene ug/L 50 55.1 110 70-130 Dibromochloromethane ug/L 50 55.1 110 70-130 Dibromomethane ug/L 50 45.3 91 70-130 Ethylbenzene ug/L 50 52.4 105 70-130 lodomethane ug/L 100 107 107 53-141 Methylene Chloride ug/L 50 54.0 108 66-130 Styrene ug/L 50 52.3 105 70-130 Tetrachloroethene ug/L 50 49.5 99 70-130 Tetrahydrofuran ug/L 500 570 114 70-130 Toluene ug/L 50 49.0 98 70-130 trans-1,2-Dichloroethene ug/L 50 53.8 108 70-130 trans- 1,3-Dichloropropene ug/L 50 55.4 111 70-130 trans-1,4-Dichloro-2-butene ug/L 50 55.3 111 57-185 Trichloroethene ug/L 50 49.4 99 70-130 Trichlorofluoromethane ug/L 50 46.1 92 62-130 Vinyl acetate ug/L 100 115 115 70-144 Vinyl chloride ug/L 50 51.9 104 62-130 Xylene (Total) ug/L 150 158 105 70-130 1,2-Dichloroethane-d4 (S) % 111 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 100 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3787853 MS 92628486006 Spike Parameter Units Result Conc. MSD Spike Conc. 3787854 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 20.6 21.6 103 108 70-141 5 30 1,1,1-Trichloroethane ug/L ND 20 20 26.5 25.3 132 126 70-150 5 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.5 22.2 108 111 69-142 3 30 1,1,2-Trichloroethane ug/L ND 20 20 23.5 22.1 118 110 70-138 6 30 1,1-Dichloroethane ug/L ND 20 20 24.9 24.0 125 120 70-150 4 30 1,1-Dichloroethene ug/L ND 20 20 26.5 26.0 132 130 70-156 2 30 1,2,3-Trichloropropane ug/L ND 20 20 21.4 20.3 107 102 70-140 5 30 1,2-Dibromo-3- ug/L ND 20 20 22.1 22.3 111 112 68-146 1 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.3 22.9 107 114 70-138 7 30 1,2-Dichlorobenzene ug/L ND 20 20 20.3 22.0 102 110 70-141 8 30 1,2-Dichloroethane ug/L ND 20 20 24.8 23.4 124 117 69-143 6 30 1,2-Dichloropropane ug/L ND 20 20 23.0 23.6 115 118 68-156 3 30 1,4-Dichlorobenzene ug/L ND 20 20 20.4 20.4 102 102 70-142 0 30 2-Butanone (MEK) ug/L ND 40 40 47.1 43.1 118 108 60-157 9 30 2-Hexanone ug/L ND 40 40 45.2 46.2 113 115 68-146 2 30 4-Methyl-2-pentanone ug/L ND 40 40 41.4 43.2 104 108 70-141 4 30 (MIBK) Acetone ug/L ND 40 40 48.4 45.8 121 115 58-157 5 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result Date: 11/01/2022 12:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 32 of 48 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3787853 3787854 MS MSD 92628486006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acrylonitrile ug/L ND 100 100 123 117 123 117 69-147 4 30 Benzene ug/L ND 20 20 21.5 21.1 108 106 70-142 2 30 Bromochloromethane ug/L ND 20 20 25.0 23.7 125 118 70-146 6 30 Bromodichloromethane ug/L ND 20 20 23.5 22.2 117 111 70-139 6 30 Bromoform ug/L ND 20 20 20.4 20.5 102 103 64-140 0 30 Bromomethane ug/L ND 20 20 23.8 21.8 119 109 28-192 9 30 Carbon disulfide ug/L ND 20 20 24.0 23.2 120 116 70-151 4 30 Carbon tetrachloride ug/L ND 20 20 26.3 25.3 131 127 70-148 4 30 Chlorobenzene ug/L ND 20 20 21.6 22.4 108 112 70-141 4 30 Chloroethane ug/L ND 20 20 31.9 29.4 159 147 58-191 8 30 IK,v1 Chloroform ug/L ND 20 20 25.1 23.8 125 119 70-148 5 30 Chloromethane ug/L ND 20 20 25.1 23.9 125 119 43-162 5 30 cis-1,2-Dichloroethene ug/L ND 20 20 25.7 24.6 128 123 68-151 4 30 cis-1,3-Dichloropropene ug/L ND 20 20 23.4 23.4 117 117 70-139 0 30 Dibromochloromethane ug/L ND 20 20 22.5 21.1 112 106 70-144 6 30 Dibromomethane ug/L ND 20 20 19.0 19.5 95 97 70-139 2 30 Ethylbenzene ug/L ND 20 20 22.6 22.8 113 114 70-143 1 30 lodomethane ug/L ND 40 40 49.1 46.0 123 115 35-171 6 30 Methylene Chloride ug/L ND 20 20 23.3 22.9 117 114 62-149 2 30 Styrene ug/L ND 20 20 20.8 21.4 104 107 70-143 3 30 Tetrachloroethene ug/L ND 20 20 19.5 20.9 97 104 70-145 7 30 Tetrahydrofuran ug/L ND 200 200 244 226 122 113 69-144 8 30 Toluene ug/L ND 20 20 21.3 21.8 107 109 70-142 2 30 trans-1,2-Dichloroethene ug/L ND 20 20 26.0 24.5 130 122 70-151 6 30 trans-1,3-Dichloropropene ug/L ND 20 20 23.7 23.3 119 116 70-139 2 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 18.8 18.8 94 94 51-159 0 30 Trichloroethene ug/L ND 20 20 22.0 22.6 110 113 62-146 3 30 Trichlorofluoromethane ug/L ND 20 20 24.3 23.8 121 119 63-153 2 30 Vinyl acetate ug/L ND 40 40 50.1 46.7 125 117 61-162 7 30 v1 Vinyl chloride ug/L ND 20 20 27.2 26.3 136 132 61-163 3 30 Xylene (Total) ug/L ND 60 60 65.0 66.8 108 111 70-143 3 30 1,2-Dichloroethane-d4 (S) % 122 111 70-130 4-Bromofluorobenzene (S) % 99 99 70-130 Toluene-d8 (S) % 100 101 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /01 /2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 48 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 QC Batch: 727685 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92628588001, 92628588002, 92628588003, 92628588004, 92628588005, 92628588006 METHOD BLANK: 3789304 Matrix: Water Associated Lab Samples: 92628588001, 92628588002, 92628588003, 92628588004, 92628588005, 92628588006 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 10/04/22 23:46 1,1,1-Trichloroethane ug/L ND 1.0 0.33 10/04/22 23:46 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 10/04/22 23:46 1,1,2-Trichloroethane ug/L ND 1.0 0.32 10/04/22 23:46 1,1-Dichloroethane ug/L ND 1.0 0.37 10/04/22 23:46 1,1-Dichloroethene ug/L ND 1.0 0.35 10/04/22 23:46 1,2,3-Trichloropropane ug/L ND 1.0 0.26 10/04/22 23:46 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 10/04/22 23:46 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 10/04/22 23:46 1,2-Dichlorobenzene ug/L ND 1.0 0.34 10/04/22 23:46 1,2-Dichloroethane ug/L ND 1.0 0.32 10/04/22 23:46 1,2-Dichloropropane ug/L ND 1.0 0.36 10/04/22 23:46 1,4-Dichlorobenzene ug/L ND 1.0 0.33 10/04/22 23:46 2-Butanone (MEK) ug/L ND 5.0 4.0 10/04/22 23:46 2-Hexanone ug/L ND 5.0 0.48 10/04/22 23:46 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 10/04/22 23:46 Acetone ug/L ND 25.0 5.1 10/04/22 23:46 Acrylonitrile ug/L ND 10.0 1.8 10/04/22 23:46 Benzene ug/L ND 1.0 0.34 10/04/22 23:46 Bromochloromethane ug/L ND 1.0 0.47 10/04/22 23:46 Bromodichloromethane ug/L ND 1.0 0.31 10/04/22 23:46 Bromoform ug/L ND 1.0 0.34 10/04/22 23:46 Bromomethane ug/L ND 2.0 1.7 10/04/22 23:46 Carbon disulfide ug/L ND 2.0 0.36 10/04/22 23:46 Carbon tetrachloride ug/L ND 1.0 0.33 10/04/22 23:46 Chlorobenzene ug/L ND 1.0 0.28 10/04/22 23:46 Chloroethane ug/L ND 1.0 0.65 10/04/22 23:46 Chloroform ug/L ND 1.0 0.43 10/04/22 23:46 Chloromethane ug/L ND 1.0 0.54 10/04/22 23:46 v2 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 10/04/22 23:46 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 10/04/22 23:46 Dibromochloromethane ug/L ND 1.0 0.36 10/04/22 23:46 Dibromomethane ug/L ND 1.0 0.39 10/04/22 23:46 Ethylbenzene ug/L ND 1.0 0.30 10/04/22 23:46 lodomethane ug/L ND 20.0 9.7 10/04/22 23:46 Methylene Chloride ug/L ND 5.0 2.0 10/04/22 23:46 Styrene ug/L ND 1.0 0.29 10/04/22 23:46 Tetrachloroethene ug/L ND 1.0 0.29 10/04/22 23:46 Tetrahydrofuran ug/L ND 10.0 3.5 10/04/22 23:46 Toluene ug/L ND 1.0 0.48 10/04/22 23:46 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/01/2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 48 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 METHOD BLANK: 3789304 Matrix: Water Associated Lab Samples: 92628588001, 92628588002, 92628588003, 92628588004, 92628588005, 92628588006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.40 10/04/22 23:46 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 10/04/22 23:46 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 10/04/22 23:46 Trichloroethene ug/L ND 1.0 0.38 10/04/22 23:46 Trichlorofluoromethane ug/L ND 1.0 0.30 10/04/22 23:46 Vinyl acetate ug/L ND 2.0 1.3 10/04/22 23:46 Vinyl chloride ug/L ND 1.0 0.39 10/04/22 23:46 Xylene (Total) ug/L ND 1.0 0.34 10/04/22 23:46 1,2-Dichloroethane-d4 (S) % 95 70-130 10/04/22 23:46 4-Bromofluorobenzene (S) % 97 70-130 10/04/22 23:46 Toluene-d8 (S) % 102 70-130 10/04/22 23:46 LABORATORY CONTROL SAMPLE: Parameter 3789305 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 52.3 105 70-130 1,1,1-Trichloroethane ug/L 50 46.8 94 70-130 1,1,2,2-Tetrachloroethane ug/L 50 49.6 99 70-130 1,1,2-Trichloroethane ug/L 50 50.2 100 70-130 1,1-Dichloroethane ug/L 50 44.9 90 70-130 1,1-Dichloroethene ug/L 50 44.1 88 70-130 1,2,3-Trichloropropane ug/L 50 48.4 97 70-130 1,2-Dibromo-3-chloropropane ug/L 50 52.3 105 70-131 1,2-Dibromoethane (EDB) ug/L 50 51.1 102 70-130 1,2-Dichlorobenzene ug/L 50 50.6 101 70-130 1,2-Dichloroethane ug/L 50 43.0 86 70-130 1,2-Dichloropropane ug/L 50 48.1 96 70-130 1,4-Dichlorobenzene ug/L 50 48.7 97 70-130 2-Butanone (MEK) ug/L 100 96.9 97 70-134 2-Hexanone ug/L 100 106 106 70-131 4-Methyl-2-pentanone (MIBK) ug/L 100 99.0 99 70-130 Acetone ug/L 100 96.5 97 70-133 Acrylonitrile ug/L 250 249 99 70-130 Benzene ug/L 50 45.5 91 70-130 Bromochloromethane ug/L 50 47.5 95 70-130 Bromodichloromethane ug/L 50 48.1 96 70-130 Bromoform ug/L 50 54.0 108 70-130 Bromomethane ug/L 50 46.7 93 45-151 Carbon disulfide ug/L 50 45.7 91 70-130 Carbon tetrachloride ug/L 50 50.4 101 70-130 Chlorobenzene ug/L 50 49.4 99 70-130 Chloroethane ug/L 50 45.6 91 39-152 Chloroform ug/L 50 45.0 90 70-130 Chloromethane ug/L 50 42.6 85 58-130 v3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/01/2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 48 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 LABORATORY CONTROL SAMPLE: Parameter 3789305 Units Spike Conc. LCS Result LCS % Rec % Rec Limits cis-1,2-Dichloroethene ug/L 50 45.2 90 70-130 cis-1,3-Dichloropropene ug/L 50 51.5 103 70-130 Dibromochloromethane ug/L 50 51.2 102 70-130 Dibromomethane ug/L 50 48.5 97 70-130 Ethylbenzene ug/L 50 48.7 97 70-130 lodomethane ug/L 100 101 101 53-141 Methylene Chloride ug/L 50 46.9 94 66-130 Styrene ug/L 50 52.0 104 70-130 Tetrachloroethene ug/L 50 49.1 98 70-130 Tetrahydrofuran ug/L 500 492 98 70-130 Toluene ug/L 50 45.8 92 70-130 trans-1,2-Dichloroethene ug/L 50 47.0 94 70-130 trans- 1,3-Dichloropropene ug/L 50 50.9 102 70-130 trans-1,4-Dichloro-2-butene ug/L 50 44.7 89 57-185 Trichloroethene ug/L 50 50.8 102 70-130 Trichlorofluoromethane ug/L 50 42.6 85 62-130 Vinyl acetate ug/L 100 102 102 70-144 Vinyl chloride ug/L 50 46.5 93 62-130 Xylene (Total) ug/L 150 148 99 70-130 1,2-Dichloroethane-d4 (S) % 88 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 97 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3789306 MS 92628588001 Spike Parameter Units Result Conc. MSD Spike Conc. 3789307 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 26.1 26.0 131 130 70-141 1 30 1,1,1-Trichloroethane ug/L ND 20 20 25.1 24.7 126 124 70-150 2 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 25.1 25.4 125 127 69-142 1 30 1,1,2-Trichloroethane ug/L ND 20 20 25.2 23.3 126 116 70-138 8 30 1,1-Dichloroethane ug/L ND 20 20 23.3 23.2 117 116 70-150 0 30 1,1-Dichloroethene ug/L ND 20 20 24.1 23.7 120 118 70-156 2 30 1,2,3-Trichloropropane ug/L ND 20 20 24.7 23.0 123 115 70-140 7 30 1,2-Dibromo-3- ug/L ND 20 20 26.6 26.7 133 133 68-146 0 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 26.1 25.6 130 128 70-138 2 30 1,2-Dichlorobenzene ug/L ND 20 20 25.0 25.0 125 125 70-141 0 30 1,2-Dichloroethane ug/L ND 20 20 22.5 22.9 112 114 69-143 2 30 1,2-Dichloropropane ug/L ND 20 20 24.7 24.3 124 121 68-156 2 30 1,4-Dichlorobenzene ug/L ND 20 20 25.1 25.2 125 126 70-142 0 30 2-Butanone (MEK) ug/L ND 40 40 53.5 47.9 134 120 60-157 11 30 2-Hexanone ug/L ND 40 40 54.4 52.6 136 131 68-146 4 30 4-Methyl-2-pentanone ug/L ND 40 40 49.7 46.5 124 116 70-141 7 30 (MIBK) Acetone ug/L ND 40 40 56.6 51.2 142 128 58-157 10 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result Date: 11/01/2022 12:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 36 of 48 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3789306 3789307 MS MSD 92628588001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acrylonitrile ug/L ND 100 100 129 124 129 124 69-147 4 30 Benzene ug/L ND 20 20 23.6 22.4 118 112 70-142 5 30 Bromochloromethane ug/L ND 20 20 25.7 24.8 128 124 70-146 4 30 Bromodichloromethane ug/L ND 20 20 25.2 24.3 126 122 70-139 4 30 Bromoform ug/L ND 20 20 26.8 25.7 134 128 64-140 4 30 Bromomethane ug/L ND 20 20 24.2 23.0 121 115 28-192 5 30 v3 Carbon disulfide ug/L ND 20 20 22.5 22.4 113 112 70-151 0 30 Carbon tetrachloride ug/L ND 20 20 26.2 25.6 131 128 70-148 2 30 Chlorobenzene ug/L 0.51J 20 20 25.6 26.4 126 129 70-141 3 30 Chloroethane ug/L ND 20 20 24.2 24.1 121 121 58-191 0 30 v3 Chloroform ug/L 2.1 20 20 25.2 24.6 116 113 70-148 2 30 Chloromethane ug/L ND 20 20 23.7 22.9 118 114 43-162 3 30 v3 cis-1,2-Dichloroethene ug/L ND 20 20 23.9 23.8 120 119 68-151 0 30 cis-1,3-Dichloropropene ug/L ND 20 20 26.0 24.7 130 123 70-139 5 30 Dibromochloromethane ug/L ND 20 20 26.5 26.3 132 131 70-144 1 30 Dibromomethane ug/L ND 20 20 26.1 24.4 131 122 70-139 7 30 Ethylbenzene ug/L ND 20 20 25.1 25.0 126 125 70-143 1 30 lodomethane ug/L ND 40 40 48.9 47.1 122 118 35-171 4 30 Methylene Chloride ug/L ND 20 20 24.9 24.4 125 122 62-149 2 30 Styrene ug/L ND 20 20 26.3 25.9 132 130 70-143 2 30 Tetrachloroethene ug/L ND 20 20 24.2 24.7 121 123 70-145 2 30 Tetrahydrofuran ug/L ND 200 200 251 244 126 122 69-144 3 30 Toluene ug/L ND 20 20 24.4 23.1 122 116 70-142 5 30 trans-1,2-Dichloroethene ug/L ND 20 20 24.2 24.6 121 123 70-151 2 30 trans-1,3-Dichloropropene ug/L ND 20 20 26.2 25.2 131 126 70-139 4 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 16.1 19.6 80 98 51-159 20 30 Trichloroethene ug/L ND 20 20 26.2 24.8 131 124 62-146 6 30 Trichlorofluoromethane ug/L ND 20 20 22.5 23.1 112 115 63-153 3 30 Vinyl acetate ug/L ND 40 40 50.9 47.5 127 119 61-162 7 30 Vinyl chloride ug/L ND 20 20 25.4 25.2 127 126 61-163 1 30 Xylene (Total) ug/L ND 60 60 75.1 75.4 125 126 70-143 0 30 1,2-Dichloroethane-d4 (S) % 97 94 70-130 4-Bromofluorobenzene (S) % 100 102 70-130 Toluene-d8 (S) % 99 97 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /01 /2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 48 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 QC Batch: 727317 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92628588008 METHOD BLANK: 3787732 Matrix: Water Associated Lab Samples: 92628588008 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 10/01/22 14:07 1,2-Dichloroethane-d4 (S) % 104 70-130 10/01/22 14:07 Toluene-d8 (S) % 105 70-130 10/01/22 14:07 LABORATORY CONTROL SAMPLE: 3787733 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 18.2 91 70-130 1,2-Dichloroethane-d4 (S) % 101 70-130 Toluene-d8(S) % 102 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3787734 3787735 MS MSD 92628458008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 21.3 22.0 106 110 63-136 3 30 1,2-Dichloroethane-d4 (S) % 105 106 70-130 30 Toluene-d8 (S) % 107 105 70-130 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /01 /2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 48 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 QC Batch: 727318 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92628588001, 92628588002, 92628588003, 92628588004, 92628588005, 92628588006 METHOD BLANK: 3787736 Matrix: Water Associated Lab Samples: 92628588001, 92628588002, 92628588003, 92628588004, 92628588005, 92628588006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 10/01/22 14:08 1,2-Dichloroethane-d4 (S) % 90 70-130 10/01/22 14:08 Toluene-d8 (S) % 99 70-130 10/01/22 14:08 LABORATORY CONTROL SAMPLE: 3787737 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 18.9 94 70-130 1,2-Dichloroethane-d4 (S) % 97 70-130 Toluene-d8(S) % 102 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3787738 3787739 MS MSD 92628458030 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 21.0 19.0 105 95 63-136 10 30 1,2-Dichloroethane-d4 (S) % 108 102 70-130 30 Toluene-d8 (S) % 104 106 70-130 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /01 /2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 48 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 QC Batch: 727323 Analysis Method: SM 2320B-2011 QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92628588001, 92628588002, 92628588003, 92628588004 METHOD BLANK: 3787752 Matrix: Water Associated Lab Samples: 92628588001, 92628588002, 92628588003, 92628588004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Alkalinity, Total as CaCO3 mg/L ND 5.0 5.0 10/01/22 14:58 LABORATORY CONTROL SAMPLE: 3787753 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 mg/L 50 50.3 101 80-120 LABORATORY CONTROL SAMPLE: 3787754 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 mg/L 50 51.0 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3787755 3787756 MS MSD 92628237001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 26.3 50 50 75.1 74.5 98 96 80-120 1 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3787757 3787758 MS MSD 92628237002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 26.0 50 50 78.3 77.9 105 104 80-120 1 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /01 /2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 48 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 QC Batch: 727291 Analysis Method: SM 2540C-2011 QC Batch Method: SM 2540C-2011 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92628588001, 92628588002, 92628588003 METHOD BLANK: 3787639 Matrix: Water Associated Lab Samples: 92628588001, 92628588002, 92628588003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Dissolved Solids mg/L ND 25.0 25.0 10/01/22 11:15 LABORATORY CONTROL SAMPLE: 3787640 Spike LCS Parameter Units Conc. Result Total Dissolved Solids mg/L 250 256 SAMPLE DUPLICATE: 3787641 92628085001 Dup Parameter Units Result Result Total Dissolved Solids mg/L 6460000 ug/L 6600 LCS % Rec % Rec Limits Qualifiers 102 90-110 Max RPD RPD Qualifiers 2 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/01/2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 48 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 QC Batch: 727186 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92628588001, 92628588002, 92628588003, 92628588004 METHOD BLANK: 3787305 Matrix: Water Associated Lab Samples: 92628588001, 92628588002, 92628588003, 92628588004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chloride mg/L ND 1.0 0.60 09/30/2216:18 Nitrate as N mg/L ND 0.10 0.060 09/30/22 16:18 Sulfate mg/L ND 1.0 0.50 09/30/2216:18 LABORATORY CONTROL SAMPLE: 3787306 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 50 48.1 96 90-110 Nitrate as N mg/L 2.5 2.4 95 90-110 Sulfate mg/L 50 48.5 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3787307 3787308 MS MSD 92628482001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L 4.7 50 50 52.9 53.3 96 97 90-110 1 10 Nitrate as N mg/L 0.50 2.5 2.5 3.0 3.0 99 99 90-110 1 10 Sulfate mg/L 3.2 50 50 51.6 52.1 97 98 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /01 /2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/01/2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: GM1.004/.005 OXFORD 92628588 LANDFILL Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92628588002 MW-5R AM20GAX 751115 92628588003 MW-7 AM20GAX 751115 92628588004 NES-2S AM20GAX 751115 92628588002 MW-5R RSK-175 751162 92628588003 MW-7 RSK-175 751162 92628588004 NES-2S RSK-175 751162 92628588001 MW-3RR EPA 3010A 727880 EPA 6010D 727892 92628588002 MW-5R EPA 3010A 727880 EPA 6010D 727892 92628588003 MW-7 EPA 3010A 727880 EPA 6010D 727892 92628588004 NES-2S EPA 3010A 727880 EPA 6010D 727892 92628588005 SW-1 EPA 3010A 727880 EPA 6010D 727892 92628588006 SW-2 EPA 3010A 727880 EPA 6010D 727892 92628588001 MW-3RR EPA 3010A 727920 EPA 6020B 728088 92628588002 MW-5R EPA 3010A 727920 EPA 6020B 728088 92628588003 MW-7 EPA 3010A 727920 EPA 6020B 728088 92628588004 NES-2S EPA 3010A 727920 EPA 6020B 728088 92628588005 SW-1 EPA 3010A 727920 EPA 6020B 728088 92628588006 SW-2 EPA 3010A 727920 EPA 6020B 728088 92628588001 MW-3RR EPA 7470A 727674 EPA 7470A 728041 92628588002 MW-5R EPA 7470A 727674 EPA 7470A 728041 92628588003 MW-7 EPA 7470A 727674 EPA 7470A 728041 92628588001 MW-3RR EPA 8260D 727685 92628588002 MW-5R EPA 8260D 727685 92628588003 MW-7 EPA 8260D 727685 92628588004 NES-2S EPA 8260D 727685 92628588005 SW-1 EPA 8260D 727685 92628588006 SW-2 EPA 8260D 727685 92628588008 TRIP BLANK EPA 8260D 727360 92628588001 MW-3RR EPA 8260D Mod. 727318 92628588002 MW-5R EPA 8260D Mod. 727318 92628588003 MW-7 EPA 8260D Mod. 727318 92628588004 NES-2S EPA 8260D Mod. 727318 92628588005 SW-1 EPA 8260D Mod. 727318 92628588006 SW-2 EPA 8260D Mod. 727318 92628588008 TRIP BLANK EPA 8260D Mod. 727317 92628588001 MW-3RR SM 2320B-2011 727323 92628588002 MW-5R SM 2320B-2011 727323 92628588003 MW-7 SM 2320B-2011 727323 92628588004 NES-2S SM 2320E-2011 727323 92628588001 MW-3RR SM 2540C-2011 727291 92628588002 MW-5R SM 2540C-2011 727291 92628588003 MW-7 SM 2540C-2011 727291 92628588001 MW-3RR EPA 300.0 Rev 2.1 1993 727186 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/01/2022 12:12 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: GM1.004/.005 OXFORD LANDFILL Pace Project No.: 92628588 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92628588002 MW-511 EPA 300.0 Rev 2.1 1993 727186 92628588003 MW-7 EPA 300.0 Rev 2.1 1993 727186 92628588004 NES-2S EPA 300.0 Rev 2.1 1993 727186 Date: 11/01/2022 12:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Batch Page 45 of 48 DG# Title: ENV�FRWHUNI-0003 v04—S . a . mple Conditid Upon Receipt Co. P tabomory receiving samples: Ashkille.4. EdenCxreenwood[] Huntersville[I RalelghL] Mecl,--;--,*'F-r—J r-' S a m pie Cc pdftioFi ClIent Narne: U13Dn Re eipt Project N., W011:92628588 Courier: ed EX OUPS E]USPS kht cCommercialPace []0thbr: 926281,588 1 Custedy.SeaVl?resent? []yes XN a Seals Intact? []Yes )000 Pad04Na;e!10b 006ble WraDBubble Bags E:]Nonc ❑ Other Th4 0 H-6 bm*td-h'. Type orice; et E]BILe CoolerTeino"4 I 1.7 Correction Factor; Add/Subtract ('C) Cooler temp Corrected (T) . USOA Regulated Soil ( ZN/A, water.Lg6rn;pl el Did sarnplesior.ig!na(e tn.a quarandne ZWfthin the Udi .SfAtqr.'C-A ,orsc (check rnafos)?.MYes 014a ?d W-ihiri Rush Turn An 3. Date/InWals Persion.E.*amt."ins contents- LLI �0 Ls ftldgk3l Tissue Ffbzent Dyes E]No EIPJA [Wane Te rnp should be above freezing to V�c ElSampleswohemp-criti2fia-. Samples on ice, cooftrigpirotem. has begun. Did samples origipatorpm a foreign source (internationally, includirig Hawaii and Puerto FRO? nYes rIN6 Correc! dontali*rs Used? 91 as []N6 []N/A 6. -Pace Cantaineirs-Used7P Wes NaQ C]N/A Contairters Intact? MyLis [:]No EIN/A 7. I)Walvedanalysil,! Samples Field FRergd3i I- - yes- No '!rt3 ©N/A 8. 5a,mp!wLaWs Mitch COC21. es -Eig. [jNJA 9. Matrix: UIP 01anK Fresent? PqYr EltYo EJN/A 11. Trip BlanIcCustody Seals present? Erfes EIND ONfa COMMENTS/SAMPLE DISCREPANCY i - Lot 10 Of split CObtairiers- CLIENT NOTIFICATIONIRESOWTION Pe*rj.c�ontacted,. Project Manager SCURF Review: r;'494' rolwiii&�i a' A%Y , '�G . ,- . Date/Ti me: Date: uaxe; Quaftrax ID: 69614 Page 1 of 2 Page 46 of 48 1' ''c ' DC# Title; ENV.FRM-HUN9-0084 01 Tech Spec Sample Condition Upon Receipt i —r K,.tb=n Effective pate: 0511212022 *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 {water] 00C, LLHg "Bottom half of box is to list number of bottles ***Check all. unpreserved Nitrates for chlorine Project N ON: 92628588 PM: TIIC Due Date: 10/07/22 CLIENT: 92-Hart_Ral U " z u 41b E W _ z cn L! a 'J E v Z ca Z c [J n o M a m Z C 7 U c o 0_ N a m Z v a C 7 rL ..4 rl m ry v 00 ry = V rl Ln 4 a IL V 0 Z n m a m z ¢ N U a !E v a. m n n a Lf a 7 a m a R tx r j 3 2 i' ? E W a v N u a 41 l7 M u a y n N = E .�� l7 a 2 ¢ J rn t� 4 ,d ? Z W Q E of t7 o = M 0 z cNn NQ. Z O > a C7 z v d O a 0 C O 7 v 0 o = yy P o0� 2 o u tx7 a li ?. m N uWt ��„ ? VNu�lJE N C. re O VI V d Opp M m diL. a J Q a N O VI N = a -y W n. C Q Eu m n r/n 3 l XN (� 3-1 1 XN 3 3 1 1 3 a 3 5 � is I �! t g 9 10 11 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added lot N Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (I Out of hold, lncorrect preservative, out of temp, incorrect containers) Qualtrax Document ID: 70677 Page 2 of 2 Page 47 of 48 a� It 'S rz (WA) a+Lugg,) lenpsa�j MNV t3 c� i sel alellaSleFucl'JO Anu�ieVM atvl•N a��y7ary Pa+losslp OW2Agaus%O`(l p •l Olc* Aq %;B; 4 G9LB hq OOA "4;0 N�p41aY1 N v a EGZS12N `Q 2 HOEN m N IDN EONH apgLH ra.vasa:eu� SL+7Htl11i0� d0 i n'alc:Nno� irdv;ai 3"kll\IS c � f0 4 � F !n ❑ C �1 .L 3 idltr> � a � ii � (ik�l � sor � a,v� cas} 3Qm n ;o wZ1wi o a m Q ° o a s o "@ a "os awoSKpH c� Q m q N FF 15 M � v G= M L 4 M❑ P 6 O V be O a a t Lu n �? e a R � 9 1 OS q N a' (wm Felu SRl LLeg �appO Paleag FtKil�rrl {wti) mr Uo D "^ Imu `n .5, - u D n Page 48 of 48 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 November 07, 2022 Jeffrey 011ison Hart & Hickman 3921 Sunset Ridge Rd. Ste. 301 Raleigh, NC 27607 RE: Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 Dear Jeffrey 011ison: Enclosed are the analytical results for sample(s) received by the laboratory on October 06, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte A revised report is being issued on 11/1 to report all missing analytes. A revised report is being issued on 11/7/22 to remove extra reported metals per client request. If you have any questions concerning this report, please feel free to contact me. Sincerely, Taylor M Cannon taylor.cannon@pacelabs.com (704)875-9092 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS r e This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 39 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 VirginiaNELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 39 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 Lab ID Sample ID Matrix Date Collected Date Received 92630055001 MW-2 Water 10/05/2211:05 10/06/22 14:19 92630055002 MW-4R Water 10/05/2214:55 10/06/22 14:19 92630055003 MW-6R Water 10/05/2212:36 10/06/22 14:19 92630055004 Field Blank -Unit 1 Water 10/05/22 14:35 10/06/22 14:19 92630055005 Trip Blank Water 10/05/22 00:00 10/06/22 14:19 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 39 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: GMI-004 Oxford LF Unit 1 92630055 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92630055001 MW-2 EPA 601 OD SBW 16 PASI-A EPA 6020E CRW 1 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D SAS 51 PASI-C EPA 8260D Mod. LMB 3 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2011 CS1 1 PASI-A EPA 300.0 Rev 2.1 1993 JCM 2 PASI-A 92630055002 MW-4R EPA 601 OD SBW 16 PASI-A EPA 6020E CRW 1 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D SAS 51 PASI-C EPA 8260D Mod. LMB 3 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2011 CS1 1 PASI-A EPA 300.0 Rev 2.1 1993 JCM 2 PASI-A 92630055003 MW-6R EPA 601 OD SBW 16 PASI-A EPA 6020E CRW 1 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D SAS 51 PASI-C EPA 8260D Mod. LMB 3 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2011 CS1 1 PASI-A EPA 300.0 Rev 2.1 1993 JCM 2 PASI-A 92630055004 Field Blank -Unit 1 EPA 601 OD SBW 16 PASI-A EPA 6020E CRW 1 PASI-A EPA 8260D LMB 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92630055005 Trip Blank EPA 8260D LMB 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 39 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 Sample: MW-2 Lab ID: 92630055001 Collected: 10/05/22 11:05 Received: 10/06/22 14:19 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 10/10/2211:59 10/14/2215:33 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 10/10/2211:59 10/14/2215:33 7440-38-2 Barium 10.5 ug/L 5.0 3.5 1 10/10/2211:59 10/14/2215:33 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 10/10/2211:59 10/14/2215:33 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 10/10/2211:59 10/14/2215:33 7440-43-9 Chromium ND ug/L 5.0 3.7 1 10/10/2211:59 10/14/2215:33 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 10/10/2211:59 10/14/2215:33 7440-48-4 Copper ND ug/L 5.0 4.3 1 10/10/2211:59 10/14/2215:33 7440-50-8 Iron 1840 ug/L 50.0 41.5 1 10/10/2211:59 10/14/2215:33 7439-89-6 Lead ND ug/L 5.0 4.5 1 10/10/2211:59 10/14/2215:33 7439-92-1 Manganese 175 ug/L 5.0 3.4 1 10/10/2211:59 10/14/2215:33 7439-96-5 Nickel ND ug/L 5.0 3.5 1 10/10/2211:59 10/14/2215:33 7440-02-0 Selenium ND ug/L 10.0 4.7 1 10/10/2211:59 10/14/2215:33 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/10/2211:59 10/14/2215:33 7440-22-4 Vanadium 4.8J ug/L 5.0 3.9 1 10/10/2211:59 10/14/2215:33 7440-62-2 Zinc ND ug/L 10.0 9.5 1 10/10/2211:59 10/14/2215:33 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 10/25/2214:00 10/26/2218:32 7440-28-0 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane Date: 11/07/2022 05:22 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 10/25/2213:30 10/26/2215:23 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 5.1 1 10/11/2217:04 67-64-1 1.8 1 10/11 /22 17:04 107-13-1 0.34 1 10/11 /22 17:04 71-43-2 0.47 1 10/11/2217:04 74-97-5 0.31 1 10/11/2217:04 75-27-4 0.34 1 10/11/2217:04 75-25-2 1.7 1 10/11/2217:04 74-83-9 4.0 1 10/11/2217:04 78-93-3 0.36 1 10/11/2217:04 75-15-0 0.33 1 10/11/2217:04 56-23-5 0.28 1 10/11 /22 17:04 108-90-7 0.65 1 10/11/2217:04 75-00-3 0.43 1 10/11/2217:04 67-66-3 0.54 1 10/11/2217:04 74-87-3 0.34 1 10/11/2217:04 96-12-8 0.36 1 10/11 /22 17:04 124-48-1 0.27 1 10/11 /22 17:04 106-93-4 0.39 1 10/11/2217:04 74-95-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 39 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 Sample: MW-2 Lab ID: 92630055001 Collected: 10/05/22 11:05 Received: 10/06/22 14:19 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Date: 11/07/2022 05:22 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.34 1 10/11/2217:04 95-50-1 ND ug/L 1.0 0.33 1 10/11/2217:04 106-46-7 ND ug/L 1.0 0.56 1 10/11/2217:04 110-57-6 ND ug/L 1.0 0.37 1 10/11/2217:04 75-34-3 ND ug/L 1.0 0.32 1 10/11/2217:04 107-06-2 ND ug/L 1.0 0.35 1 10/11/2217:04 75-35-4 ND ug/L 1.0 0.38 1 10/11/2217:04 156-59-2 ND ug/L 1.0 0.40 1 10/11/2217:04 156-60-5 ND ug/L 1.0 0.36 1 10/11/2217:04 78-87-5 ND ug/L 1.0 0.36 1 10/11/2217:04 10061-01-5 ND ug/L 1.0 0.36 1 10/11/2217:04 10061-02-6 ND ug/L 1.0 0.30 1 10/11/2217:04 100-41-4 ND ug/L 5.0 0.48 1 10/11/2217:04 591-78-6 ND ug/L 20.0 9.7 1 10/11/2217:04 74-88-4 ND ug/L 5.0 2.0 1 10/11/2217:04 75-09-2 ND ug/L 5.0 2.7 1 10/11/2217:04 108-10-1 ND ug/L 1.0 0.29 1 10/11/2217:04 100-42-5 ND ug/L 1.0 0.31 1 10/11/2217:04 630-20-6 ND ug/L 1.0 0.22 1 10/11/2217:04 79-34-5 ND ug/L 1.0 0.29 1 10/11/2217:04 127-18-4 ND ug/L 10.0 3.5 1 10/11/2217:04 109-99-9 ND ug/L 1.0 0.48 1 10/11/2217:04 108-88-3 ND ug/L 1.0 0.33 1 10/11/2217:04 71-55-6 ND ug/L 1.0 0.32 1 10/11/2217:04 79-00-5 ND ug/L 1.0 0.38 1 10/11/2217:04 79-01-6 ND ug/L 1.0 0.30 1 10/11/2217:04 75-69-4 ND ug/L 1.0 0.26 1 10/11/2217:04 96-18-4 ND ug/L 2.0 1.3 1 10/11/2217:04 108-05-4 ND ug/L 1.0 0.39 1 10/11/2217:04 75-01-4 ND ug/L 1.0 0.34 1 10/11/2217:04 1330-20-7 101 % 70-130 1 10/11/2217:04 460-00-4 97 % 70-130 1 10/11/2217:04 17060-07-0 104 % 70-130 1 10/11/2217:04 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 10/10/22 22:56 123-91-1 95 % 70-130 1 10/10/22 22:56 17060-07-0 97 % 70-130 1 10/10/22 22:56 2037-26-5 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville 15.4 mg/L 5.0 5.0 1 10/11/2210:03 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 39 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 Sample: MW-2 Parameters Lab ID: 92630055001 Collected: Report Results Units Limit 10/05/22 11:05 MDL DF Received: 10/06/22 14:19 Matrix: Water Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 254OC-2011 Pace Analytical Services -Asheville Total Dissolved Solids 148 mg/L 25.0 25.0 1 10/10/22 16:48 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Chloride 2.5 mg/L 1.0 0.60 1 10/10/22 20:34 16887-00-6 Sulfate 6.7 mg/L 1.0 0.50 1 10/10/22 20:34 14808-79-8 Date: 11/07/2022 05:22 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 39 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 Sample: MW-4R Lab ID: 92630055002 Collected: 10/05/22 14:55 Received: 10/06/22 14:19 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 10/10/2211:59 10/14/2215:47 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 10/10/2211:59 10/14/2215:47 7440-38-2 Barium 40.1 ug/L 5.0 3.5 1 10/10/2211:59 10/14/2215:47 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 10/10/2211:59 10/14/2215:47 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 10/10/2211:59 10/14/2215:47 7440-43-9 Chromium ND ug/L 5.0 3.7 1 10/10/2211:59 10/14/2215:47 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 10/10/2211:59 10/14/2215:47 7440-48-4 Copper ND ug/L 5.0 4.3 1 10/10/2211:59 10/14/2215:47 7440-50-8 Iron ND ug/L 50.0 41.5 1 10/10/2211:59 10/14/2215:47 7439-89-6 Lead ND ug/L 5.0 4.5 1 10/10/2211:59 10/14/2215:47 7439-92-1 Manganese 15.6 ug/L 5.0 3.4 1 10/10/2211:59 10/14/2215:47 7439-96-5 Nickel ND ug/L 5.0 3.5 1 10/10/2211:59 10/14/2215:47 7440-02-0 Selenium ND ug/L 10.0 4.7 1 10/10/2211:59 10/14/2215:47 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/10/2211:59 10/14/2215:47 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 10/10/2211:59 10/14/2215:47 7440-62-2 Zinc ND ug/L 10.0 9.5 1 10/10/2211:59 10/14/2215:47 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 10/25/2214:00 10/26/2218:36 7440-28-0 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane Date: 11/07/2022 05:22 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 10/25/2213:30 10/26/2215:26 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 5.1 1 10/11/2217:22 67-64-1 1.8 1 10/11 /22 17:22 107-13-1 0.34 1 10/11 /22 17:22 71-43-2 0.47 1 10/11/2217:22 74-97-5 0.31 1 10/11/2217:22 75-27-4 0.34 1 10/11/2217:22 75-25-2 1.7 1 10/11/2217:22 74-83-9 4.0 1 10/11/2217:22 78-93-3 0.36 1 10/11/2217:22 75-15-0 0.33 1 10/11/2217:22 56-23-5 0.28 1 10/11 /22 17:22 108-90-7 0.65 1 10/11/2217:22 75-00-3 0.43 1 10/11/2217:22 67-66-3 0.54 1 10/11/2217:22 74-87-3 0.34 1 10/11/2217:22 96-12-8 0.36 1 10/11 /22 17:22 124-48-1 0.27 1 10/11 /22 17:22 106-93-4 0.39 1 10/11/2217:22 74-95-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 39 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 Sample: MW-4R Lab ID: 92630055002 Collected: 10/05/22 14:55 Received: 10/06/22 14:19 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Date: 11/07/2022 05:22 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.34 1 10/11/2217:22 95-50-1 ND ug/L 1.0 0.33 1 10/11/2217:22 106-46-7 ND ug/L 1.0 0.56 1 10/11/2217:22 110-57-6 ND ug/L 1.0 0.37 1 10/11/2217:22 75-34-3 ND ug/L 1.0 0.32 1 10/11/2217:22 107-06-2 ND ug/L 1.0 0.35 1 10/11/2217:22 75-35-4 ND ug/L 1.0 0.38 1 10/11/2217:22 156-59-2 ND ug/L 1.0 0.40 1 10/11/2217:22 156-60-5 ND ug/L 1.0 0.36 1 10/11/2217:22 78-87-5 ND ug/L 1.0 0.36 1 10/11/2217:22 10061-01-5 ND ug/L 1.0 0.36 1 10/11/2217:22 10061-02-6 ND ug/L 1.0 0.30 1 10/11/2217:22 100-41-4 ND ug/L 5.0 0.48 1 10/11/2217:22 591-78-6 ND ug/L 20.0 9.7 1 10/11/2217:22 74-88-4 ND ug/L 5.0 2.0 1 10/11/2217:22 75-09-2 ND ug/L 5.0 2.7 1 10/11/2217:22 108-10-1 ND ug/L 1.0 0.29 1 10/11/2217:22 100-42-5 ND ug/L 1.0 0.31 1 10/11/2217:22 630-20-6 ND ug/L 1.0 0.22 1 10/11/2217:22 79-34-5 ND ug/L 1.0 0.29 1 10/11/2217:22 127-18-4 ND ug/L 10.0 3.5 1 10/11/2217:22 109-99-9 ND ug/L 1.0 0.48 1 10/11/2217:22 108-88-3 ND ug/L 1.0 0.33 1 10/11/2217:22 71-55-6 ND ug/L 1.0 0.32 1 10/11/2217:22 79-00-5 ND ug/L 1.0 0.38 1 10/11/2217:22 79-01-6 ND ug/L 1.0 0.30 1 10/11/2217:22 75-69-4 ND ug/L 1.0 0.26 1 10/11/2217:22 96-18-4 ND ug/L 2.0 1.3 1 10/11/2217:22 108-05-4 ND ug/L 1.0 0.39 1 10/11/2217:22 75-01-4 ND ug/L 1.0 0.34 1 10/11/2217:22 1330-20-7 101 % 70-130 1 10/11/2217:22 460-00-4 97 % 70-130 1 10/11/2217:22 17060-07-0 105 % 70-130 1 10/11/2217:22 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 19.3 ug/L 2.0 0.86 1 10/10/22 23:15 123-91-1 95 % 70-130 1 10/10/22 23:15 17060-07-0 99 % 70-130 1 10/10/22 23:15 2037-26-5 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville 345 mg/L 5.0 5.0 1 10/11/2211:29 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 39 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 Sample: MW-4R Parameters Lab ID: 92630055002 Collected: Report Results Units Limit 10/05/22 14:55 MDL DF Received: 10/06/22 14:19 Matrix: Water Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 254OC-2011 Pace Analytical Services -Asheville Total Dissolved Solids 517 mg/L 25.0 25.0 1 10/10/22 16:48 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Chloride 69.4 mg/L 1.0 0.60 1 10/10/22 21:23 16887-00-6 Sulfate 23.7 mg/L 1.0 0.50 1 10/10/22 21:23 14808-79-8 Date: 11/07/2022 05:22 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 39 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 Sample: MW-6R Lab ID: 92630055003 Collected: 10/05/22 12:36 Received: 10/06/22 14:19 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 10/10/2211:59 10/14/2215:50 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 10/10/2211:59 10/14/2215:50 7440-38-2 Barium 155 ug/L 5.0 3.5 1 10/10/2211:59 10/14/2215:50 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 10/10/2211:59 10/14/2215:50 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 10/10/2211:59 10/14/2215:50 7440-43-9 Chromium ND ug/L 5.0 3.7 1 10/10/2211:59 10/14/2215:50 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 10/10/2211:59 10/14/2215:50 7440-48-4 Copper ND ug/L 5.0 4.3 1 10/10/2211:59 10/14/2215:50 7440-50-8 Iron 5930 ug/L 50.0 41.5 1 10/10/2211:59 10/14/2215:50 7439-89-6 Lead ND ug/L 5.0 4.5 1 10/10/2211:59 10/14/2215:50 7439-92-1 Manganese 2180 ug/L 5.0 3.4 1 10/10/2211:59 10/14/2215:50 7439-96-5 Nickel ND ug/L 5.0 3.5 1 10/10/2211:59 10/14/2215:50 7440-02-0 Selenium ND ug/L 10.0 4.7 1 10/10/2211:59 10/14/2215:50 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/10/2211:59 10/14/2215:50 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 10/10/2211:59 10/14/2215:50 7440-62-2 Zinc ND ug/L 10.0 9.5 1 10/10/2211:59 10/14/2215:50 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 10/25/2214:00 10/26/2218:40 7440-28-0 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane Date: 11/07/2022 05:22 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 10/25/2213:30 10/26/2215:28 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 5.1 1 10/11/2217:40 67-64-1 1.8 1 10/11 /22 17:40 107-13-1 0.34 1 10/11 /22 17:40 71-43-2 0.47 1 10/11/2217:40 74-97-5 0.31 1 10/11/2217:40 75-27-4 0.34 1 10/11/2217:40 75-25-2 1.7 1 10/11/2217:40 74-83-9 4.0 1 10/11/2217:40 78-93-3 0.36 1 10/11/2217:40 75-15-0 0.33 1 10/11/2217:40 56-23-5 0.28 1 10/11 /22 17:40 108-90-7 0.65 1 10/11/2217:40 75-00-3 0.43 1 10/11/2217:40 67-66-3 0.54 1 10/11/2217:40 74-87-3 0.34 1 10/11/2217:40 96-12-8 0.36 1 10/11 /22 17:40 124-48-1 0.27 1 10/11 /22 17:40 106-93-4 0.39 1 10/11/2217:40 74-95-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 39 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 Sample: MW-6R Lab ID: 92630055003 Collected: 10/05/22 12:36 Received: 10/06/22 14:19 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Date: 11/07/2022 05:22 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.34 1 10/11/2217:40 95-50-1 ND ug/L 1.0 0.33 1 10/11/2217:40 106-46-7 ND ug/L 1.0 0.56 1 10/11/2217:40 110-57-6 1.4 ug/L 1.0 0.37 1 10/11/2217:40 75-34-3 ND ug/L 1.0 0.32 1 10/11/2217:40 107-06-2 ND ug/L 1.0 0.35 1 10/11/2217:40 75-35-4 0.97J ug/L 1.0 0.38 1 10/11/2217:40 156-59-2 ND ug/L 1.0 0.40 1 10/11/2217:40 156-60-5 ND ug/L 1.0 0.36 1 10/11/2217:40 78-87-5 ND ug/L 1.0 0.36 1 10/11/2217:40 10061-01-5 ND ug/L 1.0 0.36 1 10/11/2217:40 10061-02-6 ND ug/L 1.0 0.30 1 10/11/2217:40 100-41-4 ND ug/L 5.0 0.48 1 10/11/2217:40 591-78-6 ND ug/L 20.0 9.7 1 10/11/2217:40 74-88-4 ND ug/L 5.0 2.0 1 10/11/2217:40 75-09-2 ND ug/L 5.0 2.7 1 10/11/2217:40 108-10-1 ND ug/L 1.0 0.29 1 10/11/2217:40 100-42-5 ND ug/L 1.0 0.31 1 10/11/2217:40 630-20-6 ND ug/L 1.0 0.22 1 10/11/2217:40 79-34-5 ND ug/L 1.0 0.29 1 10/11/2217:40 127-18-4 ND ug/L 10.0 3.5 1 10/11/2217:40 109-99-9 ND ug/L 1.0 0.48 1 10/11/2217:40 108-88-3 ND ug/L 1.0 0.33 1 10/11/2217:40 71-55-6 ND ug/L 1.0 0.32 1 10/11/2217:40 79-00-5 ND ug/L 1.0 0.38 1 10/11/2217:40 79-01-6 ND ug/L 1.0 0.30 1 10/11/2217:40 75-69-4 ND ug/L 1.0 0.26 1 10/11/2217:40 96-18-4 ND ug/L 2.0 1.3 1 10/11/2217:40 108-05-4 ND ug/L 1.0 0.39 1 10/11/2217:40 75-01-4 ND ug/L 1.0 0.34 1 10/11/2217:40 1330-20-7 101 % 70-130 1 10/11/2217:40 460-00-4 97 % 70-130 1 10/11/2217:40 17060-07-0 103 % 70-130 1 10/11/2217:40 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 11.0 ug/L 2.0 0.86 1 10/10/22 23:34 123-91-1 97 % 70-130 1 10/10/22 23:34 17060-07-0 98 % 70-130 1 10/10/22 23:34 2037-26-5 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville 313 mg/L 5.0 5.0 1 10/11/2211:38 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 39 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 Sample: MW-6R Parameters Lab ID: 92630055003 Collected: Report Results Units Limit 10/05/22 12:36 MDL DF Received: 10/06/22 14:19 Matrix: Water Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C-2011 Pace Analytical Services -Asheville Total Dissolved Solids 668 mg/L 50.0 50.0 1 10/10/22 16:48 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Chloride 166 mg/L 3.0 1.8 3 10/11/2214:07 16887-00-6 Sulfate 8.5 mg/L 1.0 0.50 1 10/10/22 21:40 14808-79-8 Date: 11/07/2022 05:22 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 39 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 Sample: Field Blank -Unit 1 Lab ID: 92630055004 Collected: 10/05/22 14:35 Received: 10/06/22 14:19 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 10/10/2211:59 10/14/2215:54 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 10/10/2211:59 10/14/2215:54 7440-38-2 Barium ND ug/L 5.0 3.5 1 10/10/2211:59 10/14/2215:54 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 10/10/2211:59 10/14/2215:54 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 10/10/2211:59 10/14/2215:54 7440-43-9 Chromium ND ug/L 5.0 3.7 1 10/10/2211:59 10/14/2215:54 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 10/10/2211:59 10/14/2215:54 7440-48-4 Copper ND ug/L 5.0 4.3 1 10/10/2211:59 10/14/2215:54 7440-50-8 Iron ND ug/L 50.0 41.5 1 10/10/2211:59 10/14/2215:54 7439-89-6 Lead ND ug/L 5.0 4.5 1 10/10/2211:59 10/14/2215:54 7439-92-1 Manganese ND ug/L 5.0 3.4 1 10/10/2211:59 10/14/2215:54 7439-96-5 Nickel ND ug/L 5.0 3.5 1 10/10/2211:59 10/14/2215:54 7440-02-0 Selenium ND ug/L 10.0 4.7 1 10/10/2211:59 10/14/2215:54 7782-49-2 Silver ND ug/L 5.0 2.5 1 10/10/2211:59 10/14/2215:54 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 10/10/2211:59 10/14/2215:54 7440-62-2 Zinc ND ug/L 10.0 9.5 1 10/10/2211:59 10/14/2215:54 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 10/25/2214:00 10/26/2218:44 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 10/08/22 23:44 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 10/08/22 23:44 107-13-1 Benzene ND ug/L 1.0 0.34 1 10/08/22 23:44 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 10/08/22 23:44 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 10/08/22 23:44 75-27-4 Bromoform ND ug/L 1.0 0.34 1 10/08/22 23:44 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 10/08/22 23:44 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 10/08/22 23:44 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 10/08/22 23:44 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 10/08/22 23:44 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 10/08/22 23:44 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 10/08/22 23:44 75-00-3 Chloroform ND ug/L 1.0 0.43 1 10/08/22 23:44 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 10/08/22 23:44 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 10/08/22 23:44 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 10/08/22 23:44 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 10/08/22 23:44 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 10/08/22 23:44 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 10/08/22 23:44 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 10/08/22 23:44 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 10/08/22 23:44 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 10/08/22 23:44 75-34-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /07/2022 05:22 PM without the written consent of Pace Analytical Services, LLC. v2 Page 14 of 39 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 Sample: Field Blank -Unit 1 Lab ID: 92630055004 Collected: 10/05/22 14:35 Received: 10/06/22 14:19 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/07/2022 05:22 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.32 1 10/08/22 23:44 107-06-2 ND ug/L 1.0 0.35 1 10/08/22 23:44 75-35-4 ND ug/L 1.0 0.38 1 10/08/22 23:44 156-59-2 ND ug/L 1.0 0.40 1 10/08/22 23:44 156-60-5 ND ug/L 1.0 0.36 1 10/08/22 23:44 78-87-5 ND ug/L 1.0 0.36 1 10/08/22 23:44 10061-01-5 ND ug/L 1.0 0.36 1 10/08/22 23:44 10061-02-6 ND ug/L 1.0 0.30 1 10/08/22 23:44 100-41-4 ND ug/L 5.0 0.48 1 10/08/22 23:44 591-78-6 ND ug/L 20.0 9.7 1 10/08/22 23:44 74-88-4 ND ug/L 5.0 2.0 1 10/08/22 23:44 75-09-2 ND ug/L 5.0 2.7 1 10/08/22 23:44 108-10-1 ND ug/L 1.0 0.29 1 10/08/22 23:44 100-42-5 ND ug/L 1.0 0.31 1 10/08/22 23:44 630-20-6 ND ug/L 1.0 0.22 1 10/08/22 23:44 79-34-5 ND ug/L 1.0 0.29 1 10/08/22 23:44 127-18-4 ND ug/L 1.0 0.48 1 10/08/22 23:44 108-88-3 ND ug/L 1.0 0.33 1 10/08/22 23:44 71-55-6 ND ug/L 1.0 0.32 1 10/08/22 23:44 79-00-5 ND ug/L 1.0 0.38 1 10/08/22 23:44 79-01-6 ND ug/L 1.0 0.30 1 10/08/22 23:44 75-69-4 ND ug/L 1.0 0.26 1 10/08/22 23:44 96-18-4 ND ug/L 2.0 1.3 1 10/08/22 23:44 108-05-4 ND ug/L 1.0 0.39 1 10/08/22 23:44 75-01-4 ND ug/L 1.0 0.34 1 10/08/22 23:44 1330-20-7 95 % 70-130 1 10/08/22 23:44 460-00-4 105 % 70-130 1 10/08/22 23:44 17060-07-0 101 % 70-130 1 10/08/22 23:44 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 10/10/22 20:23 123-91-1 96 % 70-130 1 10/10/22 20:23 17060-07-0 103 % 70-130 1 10/10/22 20:23 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 39 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 Sample: Trip Blank Lab ID: 92630055005 Collected: 10/05/22 00:00 Received: 10/06/22 14:19 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Date: 11/07/2022 05:22 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 5.1 1 10/09/22 00:02 67-64-1 ND ug/L 10.0 1.8 1 10/09/22 00:02 107-13-1 ND ug/L 1.0 0.34 1 10/09/22 00:02 71-43-2 ND ug/L 1.0 0.47 1 10/09/22 00:02 74-97-5 ND ug/L 1.0 0.31 1 10/09/22 00:02 75-27-4 ND ug/L 1.0 0.34 1 10/09/22 00:02 75-25-2 ND ug/L 2.0 1.7 1 10/09/22 00:02 74-83-9 v2 ND ug/L 5.0 4.0 1 10/09/22 00:02 78-93-3 ND ug/L 2.0 0.36 1 10/09/22 00:02 75-15-0 ND ug/L 1.0 0.33 1 10/09/22 00:02 56-23-5 ND ug/L 1.0 0.28 1 10/09/22 00:02 108-90-7 ND ug/L 1.0 0.65 1 10/09/22 00:02 75-00-3 ND ug/L 1.0 0.43 1 10/09/22 00:02 67-66-3 ND ug/L 1.0 0.54 1 10/09/22 00:02 74-87-3 ND ug/L 2.0 0.34 1 10/09/22 00:02 96-12-8 ND ug/L 1.0 0.36 1 10/09/22 00:02 124-48-1 ND ug/L 1.0 0.27 1 10/09/22 00:02 106-93-4 ND ug/L 1.0 0.39 1 10/09/22 00:02 74-95-3 ND ug/L 1.0 0.34 1 10/09/22 00:02 95-50-1 ND ug/L 1.0 0.33 1 10/09/22 00:02 106-46-7 ND ug/L 1.0 0.56 1 10/09/22 00:02 110-57-6 ND ug/L 1.0 0.37 1 10/09/22 00:02 75-34-3 ND ug/L 1.0 0.32 1 10/09/22 00:02 107-06-2 ND ug/L 1.0 0.35 1 10/09/22 00:02 75-35-4 ND ug/L 1.0 0.38 1 10/09/22 00:02 156-59-2 ND ug/L 1.0 0.40 1 10/09/22 00:02 156-60-5 ND ug/L 1.0 0.36 1 10/09/22 00:02 78-87-5 ND ug/L 1.0 0.36 1 10/09/22 00:02 10061-01-5 ND ug/L 1.0 0.36 1 10/09/22 00:02 10061-02-6 ND ug/L 1.0 0.30 1 10/09/22 00:02 100-41-4 ND ug/L 5.0 0.48 1 10/09/22 00:02 591-78-6 ND ug/L 20.0 9.7 1 10/09/22 00:02 74-88-4 ND ug/L 5.0 2.0 1 10/09/22 00:02 75-09-2 ND ug/L 5.0 2.7 1 10/09/22 00:02 108-10-1 ND ug/L 1.0 0.29 1 10/09/22 00:02 100-42-5 ND ug/L 1.0 0.31 1 10/09/22 00:02 630-20-6 ND ug/L 1.0 0.22 1 10/09/22 00:02 79-34-5 ND ug/L 1.0 0.29 1 10/09/22 00:02 127-18-4 ND ug/L 1.0 0.48 1 10/09/22 00:02 108-88-3 ND ug/L 1.0 0.33 1 10/09/22 00:02 71-55-6 ND ug/L 1.0 0.32 1 10/09/22 00:02 79-00-5 ND ug/L 1.0 0.38 1 10/09/22 00:02 79-01-6 ND ug/L 1.0 0.30 1 10/09/22 00:02 75-69-4 ND ug/L 1.0 0.26 1 10/09/22 00:02 96-18-4 ND ug/L 2.0 1.3 1 10/09/22 00:02 108-05-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 39 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 Sample: Trip Blank Parameters Lab ID: 92630055005 Collected: Report Results Units Limit 10/05/22 00:00 MDL DF Received: 10/06/22 14:19 Matrix: Water Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Vinyl chloride ND ug/L 1.0 0.39 1 10/09/22 00:02 75-01-4 Xylene (Total) ND ug/L 1.0 0.34 1 10/09/22 00:02 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 93 % 70-130 1 10/09/22 00:02 460-00-4 1,2-Dichloroethane-d4 (S) 107 % 70-130 1 10/09/22 00:02 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 10/09/22 00:02 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 0.86 1 10/10/22 20:42 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 95 % 70-130 1 10/10/22 20:42 17060-07-0 Toluene-d8 (S) 97 % 70-130 1 10/10/22 20:42 2037-26-5 Date: 11/07/2022 05:22 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 39 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 QC Batch: 732630 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92630055001, 92630055002, 92630055003 METHOD BLANK: 3813395 Matrix: Water Associated Lab Samples: 92630055001, 92630055002, 92630055003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.12 10/26/2214:53 LABORATORY CONTROL SAMPLE: 3813396 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.7 109 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3813397 3813398 MS MSD 92629248001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.7 2.6 104 101 75-125 3 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /07/2022 05:22 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 39 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 QC Batch: 729047 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92630055001, 92630055002, 92630055003, 92630055004 METHOD BLANK: 3796439 Matrix: Water Associated Lab Samples: 92630055001, 92630055002, 92630055003, 92630055004 Blank Reporting Parameter Units Result Limit MDL Analyzed Antimony ug/L ND 5.0 3.0 10/14/2215:12 Arsenic ug/L ND 10.0 4.7 10/14/2215:12 Barium ug/L ND 5.0 3.5 10/14/2215:12 Beryllium ug/L ND 1.0 0.70 10/14/2215:12 Cadmium ug/L ND 1.0 0.40 10/14/2215:12 Chromium ug/L ND 5.0 3.7 10/14/2215:12 Cobalt ug/L ND 5.0 3.6 10/14/2215:12 Copper ug/L ND 5.0 4.3 10/14/2215:12 Iron ug/L ND 50.0 41.5 10/14/2215:12 Lead ug/L ND 5.0 4.5 10/14/2215:12 Manganese ug/L ND 5.0 3.4 10/14/2215:12 Nickel ug/L ND 5.0 3.5 10/14/2215:12 Selenium ug/L ND 10.0 4.7 10/14/2215:12 Silver ug/L ND 5.0 2.5 10/14/2215:12 Vanadium ug/L ND 5.0 3.9 10/14/2215:12 Zinc ug/L ND 10.0 9.5 10/14/2215:12 LABORATORY CONTROL SAMPLE: Parameter 3796440 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 470 94 80-120 Arsenic ug/L 500 463 93 80-120 Barium ug/L 500 485 97 80-120 Beryllium ug/L 500 474 95 80-120 Cadmium ug/L 500 479 96 80-120 Chromium ug/L 500 483 97 80-120 Cobalt ug/L 500 468 94 80-120 Copper ug/L 500 482 96 80-120 Iron ug/L 5000 4830 97 80-120 Lead ug/L 500 484 97 80-120 Manganese ug/L 500 493 99 80-120 Nickel ug/L 500 481 96 80-120 Selenium ug/L 500 467 93 80-120 Silver ug/L 250 230 92 80-120 Vanadium ug/L 500 519 104 80-120 Zinc ug/L 500 478 96 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /07/2022 05:22 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 39 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: GMI-004 Oxford LF Unit 1 92630055 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3796441 3796442 MS MSD 92630055001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 491 493 98 99 75-125 0 20 Arsenic ug/L ND 500 500 486 489 97 97 75-125 1 20 Barium ug/L 10.5 500 500 515 519 101 102 75-125 1 20 Beryllium ug/L ND 500 500 505 507 101 101 75-125 0 20 Cadmium ug/L ND 500 500 500 501 100 100 75-125 0 20 Chromium ug/L ND 500 500 504 506 101 101 75-125 0 20 Cobalt ug/L ND 500 500 496 498 98 99 75-125 0 20 Copper ug/L ND 500 500 500 502 99 100 75-125 0 20 Iron ug/L 1840 5000 5000 7060 7080 104 105 75-125 0 20 Lead ug/L ND 500 500 498 500 99 100 75-125 0 20 Manganese ug/L 175 500 500 693 691 104 103 75-125 0 20 Nickel ug/L ND 500 500 503 505 100 101 75-125 0 20 Selenium ug/L ND 500 500 512 514 102 103 75-125 0 20 Silver ug/L ND 250 250 239 241 96 96 75-125 1 20 Vanadium ug/L 4.8J 500 500 545 547 108 108 75-125 0 20 Zinc ug/L ND 500 500 504 505 100 100 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /07/2022 05:22 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 39 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 QC Batch: 732272 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92630055001, 92630055002, 92630055003, 92630055004 METHOD BLANK: 3811602 Matrix: Water Associated Lab Samples: 92630055001, 92630055002, 92630055003, 92630055004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.47 0.050 10/26/2217:00 LABORATORY CONTROL SAMPLE: 3811603 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 25 25.6 103 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3811606 3811607 MS MSD 92629259012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 25 25 26.2 26.2 105 105 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /07/2022 05:22 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 39 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 QC Batch: 728948 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92630055004, 92630055005 METHOD BLANK: 3796238 Associated Lab Samples: 92630055004, 92630055005 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 10/08/22 17:05 1,1,1-Trichloroethane ug/L ND 1.0 0.33 10/08/22 17:05 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 10/08/22 17:05 1,1,2-Trichloroethane ug/L ND 1.0 0.32 10/08/22 17:05 1,1-Dichloroethane ug/L ND 1.0 0.37 10/08/22 17:05 1,1-Dichloroethene ug/L ND 1.0 0.35 10/08/22 17:05 1,2,3-Trichloropropane ug/L ND 1.0 0.26 10/08/22 17:05 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 10/08/22 17:05 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 10/08/22 17:05 1,2-Dichlorobenzene ug/L ND 1.0 0.34 10/08/22 17:05 1,2-Dichloroethane ug/L ND 1.0 0.32 10/08/22 17:05 1,2-Dichloropropane ug/L ND 1.0 0.36 10/08/22 17:05 1,4-Dichlorobenzene ug/L ND 1.0 0.33 10/08/22 17:05 2-Butanone (MEK) ug/L ND 5.0 4.0 10/08/22 17:05 2-Hexanone ug/L ND 5.0 0.48 10/08/22 17:05 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 10/08/22 17:05 Acetone ug/L ND 25.0 5.1 10/08/22 17:05 Acrylonitrile ug/L ND 10.0 1.8 10/08/22 17:05 Benzene ug/L ND 1.0 0.34 10/08/22 17:05 Bromochloromethane ug/L ND 1.0 0.47 10/08/22 17:05 Bromodichloromethane ug/L ND 1.0 0.31 10/08/22 17:05 Bromoform ug/L ND 1.0 0.34 10/08/22 17:05 Bromomethane ug/L ND 2.0 1.7 10/08/22 17:05 v2 Carbon disulfide ug/L ND 2.0 0.36 10/08/22 17:05 Carbon tetrachloride ug/L ND 1.0 0.33 10/08/22 17:05 Chlorobenzene ug/L ND 1.0 0.28 10/08/22 17:05 Chloroethane ug/L ND 1.0 0.65 10/08/22 17:05 Chloroform ug/L ND 1.0 0.43 10/08/22 17:05 Chloromethane ug/L ND 1.0 0.54 10/08/22 17:05 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 10/08/22 17:05 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 10/08/22 17:05 Dibromochloromethane ug/L ND 1.0 0.36 10/08/22 17:05 Dibromomethane ug/L ND 1.0 0.39 10/08/22 17:05 Ethylbenzene ug/L ND 1.0 0.30 10/08/22 17:05 lodomethane ug/L ND 20.0 9.7 10/08/22 17:05 Methylene Chloride ug/L ND 5.0 2.0 10/08/22 17:05 Styrene ug/L ND 1.0 0.29 10/08/22 17:05 Tetrachloroethene ug/L ND 1.0 0.29 10/08/22 17:05 Toluene ug/L ND 1.0 0.48 10/08/22 17:05 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 10/08/22 17:05 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /07/2022 05:22 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 39 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 METHOD BLANK: 3796238 Associated Lab Samples: 92630055004, 92630055005 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 10/08/22 17:05 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 10/08/22 17:05 Trichloroethene ug/L ND 1.0 0.38 10/08/22 17:05 Trichlorofluoromethane ug/L ND 1.0 0.30 10/08/22 17:05 Vinyl acetate ug/L ND 2.0 1.3 10/08/22 17:05 Vinyl chloride ug/L ND 1.0 0.39 10/08/22 17:05 Xylene (Total) ug/L ND 1.0 0.34 10/08/22 17:05 1,2-Dichloroethane-d4 (S) % 104 70-130 10/08/22 17:05 4-Bromofluorobenzene (S) % 91 70-130 10/08/22 17:05 Toluene-d8 (S) % 101 70-130 10/08/22 17:05 LABORATORY CONTROL SAMPLE: Parameter 3796239 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 46.0 92 70-130 1,1,1-Trichloroethane ug/L 50 48.4 97 70-130 1,1,2,2-Tetrachloroethane ug/L 50 54.2 108 70-130 1,1,2-Trichloroethane ug/L 50 47.8 96 70-130 1,1-Dichloroethane ug/L 50 50.1 100 70-130 1,1-Dichloroethene ug/L 50 54.9 110 70-130 1,2,3-Trichloropropane ug/L 50 51.6 103 70-130 1,2-Dibromo-3-chloropropane ug/L 50 46.3 93 70-131 1,2-Dibromoethane (EDB) ug/L 50 47.9 96 70-130 1,2-Dichlorobenzene ug/L 50 49.6 99 70-130 1,2-Dichloroethane ug/L 50 50.2 100 70-130 1,2-Dichloropropane ug/L 50 49.3 99 70-130 1,4-Dichlorobenzene ug/L 50 47.7 95 70-130 2-Butanone (MEK) ug/L 100 115 115 70-134 2-Hexanone ug/L 100 109 109 70-131 4-Methyl-2-pentanone (MIBK) ug/L 100 106 106 70-130 Acetone ug/L 100 122 122 70-133 Acrylonitrile ug/L 250 282 113 70-130 Benzene ug/L 50 45.0 90 70-130 Bromochloromethane ug/L 50 49.7 99 70-130 Bromodichloromethane ug/L 50 44.9 90 70-130 Bromoform ug/L 50 45.1 90 70-130 Bromomethane ug/L 50 44.2 88 45-151 v3 Carbon disulfide ug/L 50 55.5 111 70-130 Carbon tetrachloride ug/L 50 43.2 86 70-130 Chlorobenzene ug/L 50 47.9 96 70-130 Chloroethane ug/L 50 56.2 112 39-152 Chloroform ug/L 50 49.5 99 70-130 Chloromethane ug/L 50 58.6 117 58-130 cis-1,2-Dichloroethene ug/L 50 49.8 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /07/2022 05:22 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 39 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 LABORATORY CONTROL SAMPLE: Parameter 3796239 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 46.1 92 70-130 Dibromochloromethane ug/L 50 43.8 88 70-130 Dibromomethane ug/L 50 46.3 93 70-130 Ethylbenzene ug/L 50 47.5 95 70-130 lodomethane ug/L 100 92.8 93 53-141 Methylene Chloride ug/L 50 49.8 100 66-130 Styrene ug/L 50 48.9 98 70-130 Tetrachloroethene ug/L 50 44.4 89 70-130 Toluene ug/L 50 46.5 93 70-130 trans-1,2-Dichloroethene ug/L 50 51.2 102 70-130 trans- 1,3-Dichloropropene ug/L 50 45.4 91 70-130 trans-1,4-Dichloro-2-butene ug/L 50 52.5 105 57-185 Trichloroethene ug/L 50 48.6 97 70-130 Trichlorofluoromethane ug/L 50 50.7 101 62-130 Vinyl acetate ug/L 100 108 108 70-144 Vinyl chloride ug/L 50 61.7 123 62-130 Xylene (Total) ug/L 150 143 95 70-130 1,2-Dichloroethane-d4 (S) % 102 70-130 4-Bromofluorobenzene (S) % 102 70-130 Toluene-d8 (S) % 98 70-130 MATRIX SPIKE SAMPLE: Parameter 3796240 Units 92630064001 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 20.3 101 70-141 1,1,1-Trichloroethane ug/L ND 20 22.0 110 70-150 1,1,2,2-Tetrachloroethane ug/L ND 20 21.4 107 69-142 1,1,2-Trichloroethane ug/L ND 20 20.4 102 70-138 1,1-Dichloroethane ug/L ND 20 22.7 113 70-150 1,1-Dichloroethene ug/L ND 20 26.8 134 70-156 1,2,3-Trichloropropane ug/L ND 20 20.4 102 70-140 1,2-Dibromo-3-chloropropane ug/L ND 20 17.5 88 68-146 1,2-Dibromoethane (EDB) ug/L ND 20 20.1 100 70-138 1,2-Dichlorobenzene ug/L ND 20 21.0 105 70-141 1,2-Dichloroethane ug/L ND 20 21.6 108 69-143 1,2-Dichloropropene ug/L ND 20 22.4 112 68-156 1,4-Dichlorobenzene ug/L ND 20 20.8 104 70-142 2-Butanone (MEK) ug/L ND 40 44.2 110 60-157 2-Hexanone ug/L ND 40 41.6 104 68-146 4-Methyl-2-pentanone (MIBK) ug/L ND 40 43.2 108 70-141 Acetone ug/L ND 40 45.3 113 58-157 Acrylonitrile ug/L ND 100 113 113 69-147 Benzene ug/L ND 20 19.5 98 70-142 Bromochloromethane ug/L ND 20 21.8 109 70-146 Bromodichloromethane ug/L ND 20 20.6 103 70-139 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /07/2022 05:22 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 39 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 MATRIX SPIKE SAMPLE: Parameter 3796240 Units 92630064001 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Bromoform ug/L ND 20 18.3 91 64-140 Bromomethane ug/L ND 20 19.4 97 28-192 v3 Carbon disulfide ug/L ND 20 26.7 134 70-151 Carbon tetrachloride ug/L ND 20 19.6 98 70-148 Chlorobenzene ug/L ND 20 21.5 107 70-141 Chloroethane ug/L ND 20 25.5 128 58-191 Chloroform ug/L ND 20 23.0 115 70-148 Chloromethane ug/L ND 20 26.2 131 43-162 cis-1,2-Dichloroethene ug/L ND 20 22.3 112 68-151 cis-1,3-Dichloropropene ug/L ND 20 20.0 100 70-139 Dibromochloromethane ug/L ND 20 18.5 92 70-144 Dibromomethane ug/L ND 20 20.4 102 70-139 Ethylbenzene ug/L ND 20 21.0 105 70-143 lodomethane ug/L ND 40 40.9 102 35-171 Methylene Chloride ug/L ND 20 22.7 113 62-149 Styrene ug/L ND 20 20.4 102 70-143 Tetrachloroethene ug/L ND 20 21.2 106 70-145 Toluene ug/L ND 20 21.8 109 70-142 trans-1,2-Dichloroethene ug/L ND 20 23.2 116 70-151 trans- 1,3-Dichloropropene ug/L ND 20 20.7 103 70-139 trans-1,4-Dichloro-2-butene ug/L ND 20 17.2 86 51-159 Trichloroethene ug/L ND 20 22.0 110 62-146 Trichlorofluoromethane ug/L ND 20 23.7 119 63-153 Vinyl acetate ug/L ND 40 43.7 109 61-162 Vinyl chloride ug/L ND 20 27.5 137 61-163 Xylene (Total) ug/L ND 60 63.1 105 70-143 1,2-Dichloroethane-d4 (S) % 100 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 103 70-130 SAMPLE DUPLICATE: 3796241 Parameter Units 92630067001 Result Dup Result RPD Max RPD 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropene ug/L ND ND 30 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /07/2022 05:22 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 39 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 SAMPLE DUPLICATE: 3796241 Parameter Units 92630067001 Result Dup Result RPD Max RPD 1,4-Dichlorobenzene ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 v2 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 30 Methylene Chloride ug/L ND ND 30 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl acetate ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 107 105 4-Bromofluorobenzene (S) % 91 94 Toluene-d8 (S) % 101 103 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /07/2022 05:22 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 39 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 QC Batch: 729368 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92630055001, 92630055002, 92630055003 METHOD BLANK: 3798203 Matrix: Associated Lab Samples: 92630055001, 92630055002, 92630055003 Blank Parameter Units Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 10/11/22 13:45 1,1,1-Trichloroethane ug/L ND 1.0 0.33 10/11/22 13:45 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 10/11/22 13:45 1,1,2-Trichloroethane ug/L ND 1.0 0.32 10/11/22 13:45 1,1-Dichloroethane ug/L ND 1.0 0.37 10/11/22 13:45 1,1-Dichloroethene ug/L ND 1.0 0.35 10/11/22 13:45 1,2,3-Trichloropropane ug/L ND 1.0 0.26 10/11/22 13:45 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 10/11/22 13:45 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 10/11/22 13:45 1,2-Dichlorobenzene ug/L ND 1.0 0.34 10/11/22 13:45 1,2-Dichloroethane ug/L ND 1.0 0.32 10/11/22 13:45 1,2-Dichloropropane ug/L ND 1.0 0.36 10/11/22 13:45 1,4-Dichlorobenzene ug/L ND 1.0 0.33 10/11/22 13:45 2-Butanone (MEK) ug/L ND 5.0 4.0 10/11/22 13:45 2-Hexanone ug/L ND 5.0 0.48 10/11/22 13:45 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 10/11/22 13:45 Acetone ug/L ND 25.0 5.1 10/11/22 13:45 Acrylonitrile ug/L ND 10.0 1.8 10/11/22 13:45 Benzene ug/L ND 1.0 0.34 10/11/22 13:45 Bromochloromethane ug/L ND 1.0 0.47 10/11/22 13:45 Bromodichloromethane ug/L ND 1.0 0.31 10/11/22 13:45 Bromoform ug/L ND 1.0 0.34 10/11/22 13:45 Bromomethane ug/L ND 2.0 1.7 10/11/22 13:45 Carbon disulfide ug/L ND 2.0 0.36 10/11/22 13:45 Carbon tetrachloride ug/L ND 1.0 0.33 10/11/22 13:45 Chlorobenzene ug/L ND 1.0 0.28 10/11/22 13:45 Chloroethane ug/L ND 1.0 0.65 10/11/22 13:45 Chloroform ug/L ND 1.0 0.43 10/11/22 13:45 Chloromethane ug/L ND 1.0 0.54 10/11/22 13:45 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 10/11/22 13:45 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 10/11/22 13:45 Dibromochloromethane ug/L ND 1.0 0.36 10/11/22 13:45 Dibromomethane ug/L ND 1.0 0.39 10/11/22 13:45 Ethylbenzene ug/L ND 1.0 0.30 10/11/22 13:45 lodomethane ug/L ND 20.0 9.7 10/11/22 13:45 Methylene Chloride ug/L ND 5.0 2.0 10/11/22 13:45 Styrene ug/L ND 1.0 0.29 10/11/22 13:45 Tetrachloroethene ug/L ND 1.0 0.29 10/11/22 13:45 Tetrahydrofuran ug/L ND 10.0 3.5 10/11/22 13:45 Toluene ug/L ND 1.0 0.48 10/11/22 13:45 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /07/2022 05:22 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 39 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 METHOD BLANK: 3798203 Matrix: Associated Lab Samples: 92630055001, 92630055002, 92630055003 Blank Parameter Units Result Water Reporting Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.40 10/11/22 13:45 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 10/11/22 13:45 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 10/11/22 13:45 Trichloroethene ug/L ND 1.0 0.38 10/11/22 13:45 Trichlorofluoromethane ug/L ND 1.0 0.30 10/11/22 13:45 Vinyl acetate ug/L ND 2.0 1.3 10/11/22 13:45 Vinyl chloride ug/L ND 1.0 0.39 10/11/22 13:45 Xylene (Total) ug/L ND 1.0 0.34 10/11/22 13:45 1,2-Dichloroethane-d4 (S) % 95 70-130 10/11/22 13:45 4-Bromofluorobenzene (S) % 101 70-130 10/11/22 13:45 Toluene-d8 (S) % 107 70-130 10/11/22 13:45 LABORATORY CONTROL SAMPLE: 3798204 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 48.2 96 70-130 1,1,1-Trichloroethane ug/L 50 48.1 96 70-130 1,1,2,2-Tetrachloroethane ug/L 50 46.8 94 70-130 1,1,2-Trichloroethane ug/L 50 47.9 96 70-130 1,1-Dichloroethane ug/L 50 46.0 92 70-130 1,1-Dichloroethene ug/L 50 47.5 95 70-130 1,2,3-Trichloropropane ug/L 50 46.0 92 70-130 1,2-Dibromo-3-chloropropane ug/L 50 47.4 95 70-131 1,2-Dibromoethane (EDB) ug/L 50 49.1 98 70-130 1,2-Dichlorobenzene ug/L 50 46.9 94 70-130 1,2-Dichloroethane ug/L 50 46.8 94 70-130 1,2-Dichloropropane ug/L 50 48.4 97 70-130 1,4-Dichlorobenzene ug/L 50 45.7 91 70-130 2-Butanone (MEK) ug/L 100 101 101 70-134 2-Hexanone ug/L 100 97.4 97 70-131 4-Methyl-2-pentanone (MIBK) ug/L 100 92.9 93 70-130 Acetone ug/L 100 95.7 96 70-133 Acrylonitrile ug/L 250 244 98 70-130 Benzene ug/L 50 44.4 89 70-130 Bromochloromethane ug/L 50 49.0 98 70-130 Bromodichloromethane ug/L 50 47.6 95 70-130 Bromoform ug/L 50 48.8 98 70-130 Bromomethane ug/L 50 47.3 95 45-151 Carbon disulfide ug/L 50 47.5 95 70-130 Carbon tetrachloride ug/L 50 46.7 93 70-130 Chlorobenzene ug/L 50 45.6 91 70-130 Chloroethane ug/L 50 52.1 104 39-152 Chloroform ug/L 50 46.3 93 70-130 Chloromethane ug/L 50 51.2 102 58-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /07/2022 05:22 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 39 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 LABORATORY CONTROL SAMPLE: Parameter 3798204 Units Spike Conc. LCS Result LCS % Rec % Rec Limits cis-1,2-Dichloroethene ug/L 50 47.1 94 70-130 cis-1,3-Dichloropropene ug/L 50 48.9 98 70-130 Dibromochloromethane ug/L 50 48.2 96 70-130 Dibromomethane ug/L 50 46.9 94 70-130 Ethylbenzene ug/L 50 45.1 90 70-130 lodomethane ug/L 100 89.5 89 53-141 Methylene Chloride ug/L 50 45.9 92 66-130 Styrene ug/L 50 47.8 96 70-130 Tetrachloroethene ug/L 50 44.5 89 70-130 Tetrahydrofuran ug/L 500 498 100 70-130 Toluene ug/L 50 43.1 86 70-130 trans-1,2-Dichloroethene ug/L 50 47.9 96 70-130 trans- 1,3-Dichloropropene ug/L 50 49.2 98 70-130 trans-1,4-Dichloro-2-butene ug/L 50 47.0 94 57-185 Trichloroethene ug/L 50 48.2 96 70-130 Trichlorofluoromethane ug/L 50 46.6 93 62-130 Vinyl acetate ug/L 100 107 107 70-144 Vinyl chloride ug/L 50 50.8 102 62-130 Xylene (Total) ug/L 150 137 91 70-130 1,2-Dichloroethane-d4 (S) % 98 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 98 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3798205 MS 92628454002 Spike Parameter Units Result Conc. MSD Spike Conc. 3798206 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 100 100 99.9 107 100 107 70-141 7 30 1,1,1-Trichloroethane ug/L ND 100 100 110 119 110 119 70-150 7 30 1,1,2,2-Tetrachloroethane ug/L ND 100 100 100 106 100 106 69-142 6 30 1,1,2-Trichloroethane ug/L ND 100 100 106 111 106 111 70-138 5 30 1,1-Dichloroethane ug/L ND 100 100 106 116 106 116 70-150 9 30 1,1-Dichloroethene ug/L ND 100 100 114 121 114 121 70-156 6 30 1,2,3-Trichloropropane ug/L ND 100 100 96.6 104 97 104 70-140 8 30 1,2-Dibromo-3- ug/L ND 100 100 100 103 100 103 68-146 3 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 100 100 99.0 108 99 108 70-138 9 30 1,2-Dichlorobenzene ug/L ND 100 100 102 105 102 105 70-141 3 30 1,2-Dichloroethane ug/L ND 100 100 105 112 105 112 69-143 7 30 1,2-Dichloropropane ug/L ND 100 100 109 117 109 117 68-156 7 30 1,4-Dichlorobenzene ug/L ND 100 100 102 105 102 105 70-142 3 30 2-Butanone (MEK) ug/L 1120 200 200 3780 4040 1330 1460 60-157 7 30 E,M1 2-Hexanone ug/L ND 200 200 209 231 102 113 68-146 10 30 4-Methyl-2-pentanone ug/L ND 200 200 240 252 109 115 70-141 5 30 (MIBK) Acetone ug/L 1740 200 200 3910 4110 1090 1190 58-157 5 30 E,M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result Date: 11/07/2022 05:22 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 29 of 39 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3798205 3798206 MS MSD 92628454002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acrylonitrile ug/L ND 500 500 543 595 109 119 69-147 9 30 Benzene ug/L ND 100 100 104 112 103 110 70-142 7 30 Bromochloromethane ug/L ND 100 100 109 118 109 118 70-146 8 30 Bromodichloromethane ug/L ND 100 100 105 111 105 111 70-139 6 30 Bromoform ug/L ND 100 100 93.3 98.9 93 99 64-140 6 30 Bromomethane ug/L ND 100 100 108 119 108 119 28-192 10 30 Carbon disulfide ug/L ND 100 100 113 121 113 121 70-151 7 30 Carbon tetrachloride ug/L ND 100 100 108 115 108 115 70-148 7 30 Chlorobenzene ug/L ND 100 100 101 108 101 108 70-141 6 30 Chloroethane ug/L ND 100 100 122 136 122 136 58-191 10 30 Chloroform ug/L ND 100 100 111 122 111 122 70-148 9 30 Chloromethane ug/L ND 100 100 119 130 119 130 43-162 9 30 cis-1,2-Dichloroethene ug/L ND 100 100 110 118 110 118 68-151 7 30 cis-1,3-Dichloropropene ug/L ND 100 100 108 115 108 115 70-139 7 30 Dibromochloromethane ug/L ND 100 100 95.0 103 95 103 70-144 8 30 Dibromomethane ug/L ND 100 100 105 109 105 109 70-139 3 30 Ethylbenzene ug/L 9.6 100 100 108 116 98 106 70-143 7 30 lodomethane ug/L ND 200 200 194 208 97 104 35-171 7 30 Methylene Chloride ug/L ND 100 100 107 116 102 111 62-149 8 30 Styrene ug/L ND 100 100 103 112 103 112 70-143 8 30 Tetrachloroethene ug/L ND 100 100 101 106 101 106 70-145 5 30 Tetrahydrofuran ug/L 315 1000 1000 2420 2560 211 224 69-144 5 30 M1 Toluene ug/L ND 100 100 135 141 131 138 70-142 5 30 trans-1,2-Dichloroethene ug/L ND 100 100 113 120 113 120 70-151 6 30 trans-1,3-Dichloropropene ug/L ND 100 100 107 114 107 114 70-139 6 30 trans-1,4-Dichloro-2-butene ug/L ND 100 100 101 107 101 107 51-159 5 30 Trichloroethene ug/L ND 100 100 112 119 112 119 62-146 6 30 Trichlorofluoromethane ug/L ND 100 100 112 121 112 121 63-153 8 30 Vinyl acetate ug/L ND 200 200 213 223 106 112 61-162 5 30 Vinyl chloride ug/L ND 100 100 122 133 122 133 61-163 9 30 Xylene (Total) ug/L 10.5 300 300 324 343 104 111 70-143 6 30 1,2-Dichloroethane-d4 (S) % 99 99 70-130 4-Bromofluorobenzene (S) % 101 102 70-130 Toluene-d8 (S) % 100 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /07/2022 05:22 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 39 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 QC Batch: 729188 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92630055001, 92630055002, 92630055003, 92630055004, 92630055005 METHOD BLANK: 3797501 Matrix: Water Associated Lab Samples: 92630055001, 92630055002, 92630055003, 92630055004, 92630055005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 10/10/22 14:01 1,2-Dichloroethane-d4 (S) % 106 70-130 10/10/22 14:01 Toluene-d8 (S) % 106 70-130 10/10/22 14:01 LABORATORY CONTROL SAMPLE: 3797502 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 18.1 91 70-130 1,2-Dichloroethane-d4 (S) % 106 70-130 Toluene-d8 (S) % 107 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3797503 3797504 MS MSD 92630055003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane(p-Dioxane) ug/L 11.0 20 20 27.9 31.6 84 103 63-136 12 30 1,2-Dichloroethane-d4 (S) % 103 98 70-130 30 Toluene-d8 (S) % 100 97 70-130 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /07/2022 05:22 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 39 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 QC Batch: 728957 Analysis Method: SM 2320B-2011 QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92630055001, 92630055002, 92630055003 METHOD BLANK: 3796250 Matrix: Water Associated Lab Samples: 92630055001, 92630055002, 92630055003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Alkalinity, Total as CaCO3 mg/L ND 5.0 5.0 10/11/22 09:44 LABORATORY CONTROL SAMPLE: 3796251 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 mg/L 50 49.8 100 80-120 LABORATORY CONTROL SAMPLE: 3796252 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 mg/L 50 50.1 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3796253 3796254 MS MSD 92629775002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 30.0 50 50 79.7 80.8 99 102 80-120 1 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /07/2022 05:22 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 39 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 QC Batch: 729035 Analysis Method: SM 2540C-2011 QC Batch Method: SM 2540C-2011 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92630055001, 92630055002, 92630055003 METHOD BLANK: 3796401 Matrix: Water Associated Lab Samples: 92630055001, 92630055002, 92630055003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Dissolved Solids mg/L ND 25.0 25.0 10/10/22 16:48 LABORATORY CONTROL SAMPLE: 3796402 Spike LCS Parameter Units Conc. Result Total Dissolved Solids mg/L 250 260 SAMPLE DUPLICATE: 3796403 92629610002 Dup Parameter Units Result Result Total Dissolved Solids mg/L 376 388 LCS % Rec % Rec Limits Qualifiers 104 90-110 Max RPD RPD Qualifiers 3 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /07/2022 05:22 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 39 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 QC Batch: 729175 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92630055001, 92630055002, 92630055003 METHOD BLANK: 3797405 Matrix: Water Associated Lab Samples: 92630055001, 92630055002, 92630055003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chloride mg/L ND 1.0 0.60 10/10/22 20:02 Sulfate mg/L ND 1.0 0.50 10/10/22 20:02 LABORATORY CONTROL SAMPLE: 3797406 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 50 51.6 103 90-110 Sulfate mg/L 50 51.6 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3797407 3797408 MS MSD 92630055001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L 2.5 50 50 55.1 55.0 105 105 90-110 0 10 Sulfate mg/L 6.7 50 50 59.0 59.0 105 105 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3797409 3797410 MS MSD 92630072010 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L 8.5 50 50 61.8 62.1 107 107 90-110 1 10 Sulfate mg/L ND 50 50 53.2 53.6 105 106 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /07/2022 05:22 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 39 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALIFIERS Project: GMI-004 Oxford LF Unit 1 Pace Project No.: 92630055 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS E Analyte concentration exceeded the calibration range. The reported result is estimated. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /07/2022 05:22 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 39 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: GMI-004 Oxford LF Unit 1 92630055 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92630055001 MW-2 EPA 3010A 729047 EPA 6010D 729162 92630055002 MW-4R EPA 3010A 729047 EPA 6010D 729162 92630055003 MW-6R EPA 3010A 729047 EPA 6010D 729162 92630055004 Field Blank -Unit 1 EPA 3010A 729047 EPA6010D 729162 92630055001 MW-2 EPA 3010A 732272 EPA 6020B 732754 92630055002 MW-4R EPA 3010A 732272 EPA 6020B 732754 92630055003 MW-611 EPA 3010A 732272 EPA 6020B 732754 92630055004 Field Blank -Unit 1 EPA 3010A 732272 EPA 6020B 732754 92630055001 MW-2 EPA 7470A 732630 EPA 7470A 732808 92630055002 MW-4R EPA 7470A 732630 EPA 7470A 732808 92630055003 MW-6R EPA 7470A 732630 EPA 7470A 732808 92630055001 MW-2 EPA 8260D 729368 92630055002 MW-4R EPA 8260D 729368 92630055003 MW-6R EPA 8260D 729368 92630055004 Field Blank -Unit 1 EPA 8260D 728948 92630055005 Trip Blank EPA 8260D 728948 92630055001 MW-2 EPA 8260D Mod. 729188 92630055002 MW-4R EPA 8260D Mod. 729188 92630055003 MW-6R EPA 8260D Mod. 729188 92630055004 Field Blank -Unit 1 EPA 8260D Mod. 729188 92630055005 Trip Blank EPA 8260D Mod. 729188 92630055001 MW-2 SM 2320B-2011 728957 92630055002 MW-4R SM 2320B-2011 728957 92630055003 MW-6R SM 2320B-2011 728957 92630055001 MW-2 SM 2540C-2011 729035 92630055002 MW-4R SM 2540C-2011 729035 92630055003 MW-6R SM 2540C-2011 729035 92630055001 MW-2 EPA 300.0 Rev 2.1 1993 729175 92630055002 MW-4R EPA 300.0 Rev 2.1 1993 729175 92630055003 MW-6R EPA 300.0 Rev 2.1 1993 729175 Date: 11/07/2022 05:22 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 36 of 39 f L#�.f+-_ r ILIe: r_t4v-rr"rl-nrt uiv i-uurss vu'I_ziample t;onaltlon upon eceipt -I�ace Effective Date: 05/121202205/12/2022 Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville 0 Raleigh[] Mechanicsville❑ Atlanta❑ Kernersville[] Sam• - Condition Client Name: ' Project �p� : g2630055 ##: Courier: ❑Fed Ex ❑UPS ❑LISPS ❑Client 1111111111111111111111 Commercial Race ❑Other. 92630055 Custody Seal Present? ❑Yes PNo Seals Intact? ❑Yes ❑�No DatelInitials Person Examining Contents: Packing Material: ❑Bubble Wrap [Bubble Bags ❑None ❑ Other Blological Tissue, Frozen? Thermometer: ❑Yes [:]No '❑N/A Q,`IRGun ID: 1 Type of ice: ' Wet ❑Blue ❑None 2 Correction Factor: Cooler Temp; - ' Add/Subtract (°C) L . Temp should be above freezing to 6'C Cooler Temp Corrected (°C); Damples out of temp criteria. Samples on ice, cooling process � has begun USDA Regulated Soft ( 0 N/A, water sample) Did samples originate in a,gparantine zone within the United States: CA, NY. or SC Did samples originate from a fnreion cnurrn (check maps)? maps)? LJYes UND "nclucrsng Hawaii and Puerto Rico)? []Yes [�Na Comments/Discrepancy: Chain of Custody Present? ❑Yes ❑No ❑N/A 1. Samples Arrived within Hold Time? Short Hold Time Analysis (472 hr.)? ❑Yes ❑Yes ❑No ❑No ❑N/A ❑N/A 2. 3. Rush Turn Around Time Requested? ❑Yes ❑No ❑NIA 4. Sufficient Volume? ❑Yes ❑No ❑N/A 5. Correct Containers Used? -Pace Containers Used? ❑Yes ❑Yes []No ❑No ❑N/A ❑N/A 6. Containers Intact? ❑.Yes ❑No ❑NIA 7. Dissolved analysis: Samples Field Filtered? Sample Labels Match COC? -Includes DateMme/ID/Anaiysis Matrix: ❑Yes ❑Yes 1 �. y ❑Na []No ❑N/A []N/A 8. 9. Headspace In VOA Vials (>5.6mm)? Oyes ❑i o ❑N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? []Yes QYes ❑No ❑No El NIA. ❑N/A 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Date/Time: Project Manager SCURF Review: Date: Project Manaeer SRF RRIAPUr• Field Data Required? LjYes ❑Na Page 37 of 39 Qualtrax ID, 69614 Page 1 of 2 I-'vvrr r ruU. tvv-rr%m-nUiv i-uuu,s vu-i 7arripie Uoncinion upon Receipt >dt�G� - F- Effective Date: 05112/202205/12/2022 *Check mark top half of box if pH and/or dechiorination is verified and Project # WO 92fi30055 within the acceptance range for preservation samples. PM: TMC Due Date: 10/ 13/22 Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHS CLIENT: 92—Mart_Raw l **Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine k E W Z w G Y Ix J E 4 H a a m Z a Q V a J of u'1 N M a m Z al i QILI ? a J o in y] N a m a w e ¢ _� d iv = r-1 .3i a m C a O 4V+ a J E M r7 wt a m CL ZZ a J c N 2 m a m o Z �l ° N u a J E N .-7 rii Q a m u N 'i Z d J E N r7 m a co a f1 j y rbr C 3: 5 LL U7 3 a Z m E Q `m s e-i r/ l'i a v S S E Q 0) � ri i w L7 a ? Hra N Q J E 0 , M L7 a 0 M = E Q v �. -' ri -F l4 a r 4 v d 7n N Z 4 J E Lon N v, M l9 ¢ .. U _ Z 4 J E in CV a m C7 a u O 7 q 7G T t9 a 7- M N Z O �! E 0 Ch t7 y _ Q aG C > E O q M L7 � Z O a x O > i O �T 0 t7 a GZ V O fV=Vl O '7 m i7 ❑ a ,z m .. m 7 d m a y 77 d w I m E Ln N LYg N a �^, fo ci LA YO Z a 61 V W E E a O Ln Ln L kW M h ca a z o a S z a Z a)m G ? a E c ncc a G E O O O H CJ Q a C LJ ¢ o I t r 2 -1 I ✓ 4 7 8 9 10 1I 122 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot q adjusted added Ii.iLC• Y���C11C4e1 Liiaru �> a uiscrepancy arrecting North Carolina compuance samples, a copy of this form will he seat to the North Carolina DENRCertifrcation Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 38 of 39 Quaitrax ID; 69614 Page 2 of 2 m n ro j o w ra s ITEM #� m Z' °�_ w m o n m m c �• O N 91 O odi C ^ j 1 f. tj p 5 S ai 71 m r + n I v m M 3 m 3 c�0 'n r rl F N Ar i k-r)'I I @onto ooa ] x a A T if a o iE a a A m 1° n n m m 0 to n o { \ -� _ - - — -- • MATRIX CODE {see vadd modes to left) rl 1° c SAMPLETYPE (EGRAS C=COMP) O T m n m n i i.) { Vr� M 4 r1 z n ti m p 0 o D Z _ 3 rn a 6., a m m Z m m m m SAMPLE TEMP AT COLLECTION in c _j � - -_ _ - �. # OF CONTAINERS m m a o n 3 T Ilk- Unpreservad v v y 7 H2SO4 itCr - y }` HNO3 NCI � d a CD NaOH v r'r Na2S203 y .I o -- y m AMelhanal o CD Other (0 Analyses Test YIN M l �. VOC by 8260 - - - - j� Metals by 6010 m z S — { 1, 4 Oio cane by 6260 rn r1 3 a T/ Trip BLANK n a u r 11 a O � D r u 21. A \ - to a Z N s X W TEMP in C D ro Residual Chlorine (Y/N) �}. Z n' �n o o Received on Ice y n (YIN) o `y Custody Sealed o Cooler = w V�f C Samples Intact MN) c m 0 W m CL 3 0 CL m ra = aA_ n A 7 Z a q � � n ID;�0 y , 0 o n 5K C N CA n m r- 0 m G) N > a0> O C rL N �ny aro ?: m � � f^^D D �t .0 m CCD E CL y w rr m � OA N (D r n C,C 30 =r 3 Cr m 7 D CL � 51 N 0 n :3 c El 01 m � Page 39 of 39 Appendix C Summary of Historical Groundwater Elevations 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS Appendix C Summary of Historical Groundwater Elevations Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Groundwater Elevations (ft AMSL) Date Background Downgradient Performance/Sentinel MW-1 MW-1A MW-7 MW-2 MW-3RR' MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D 09/10/99 101.71 517.91 -- 507.76 481.40 493.62 467.65 496.53 -- -- -- 11 /16/99 105.76 522.86 -- 506.32 483.55 494.83 468.75 498.24 -- -- -- 05/10/00 109.47 527.66 -- 507.89 487.20 499.63 470.65 500.59 -- -- -- - 10/26/00 103.54 518.89 -- 504.12 480.86 495.21 467.39 496.95 -- -- -- -- 04/18/01 107.87 526.23 -- 508.01 486.62 498.50 470.79 500.21 -- -- -- -- 10/27/01 -- 514.65 -- 501.42 478.79 494.79 466.70 494.92 -- -- -- - 06/10/02 -- 515.06 -- 502.91 480.10 495.19 467.06 496.26 -- -- -- -- 11 /19/02 -- 518.61 -- 512.08 489.84 498.82 471.80 498.70 -- -- -- -- 06/27/03 -- 529.42 -- 508.76 488.69 500.79 471.72 501.38 -- -- -- -- 12/29/03 -- 528.91 -- 509.06 488.06 499.94 471.10 501.21 -- -- -- -- 06/29/04 -- 520.03 -- 505.24 481.10 497.84 467.72 499.21 -- -- -- -- 12/28/04 -- 526.73 -- 509.09 485.27 499.14 469.51 500.76 -- -- -- -- 06/29/05 -- 520.37 -- 504.64 481.10 497.60 467.63 499.15 -- -- -- -- 12/29/05 -- 519.54 -- 509.66 482.69 498.33 468.57 499.25 -- -- -- -- 06/27/06 -- 517.93 - 507.85 481.85 497.64 468.00 498.63 -- -- -- -- 12/27/06 -- 523.00 -- 511.07 489.81 499.43 471.76 500.83 493.70 -- 469.82 -- 07/12/07 -- 516.94 -- 502.49 479.84 497.17 467.18 497.59 -- -- -- -- 12/18/07 -- 510.35 -- 501.46 477.54 495.40 464.09 493.14 -- -- -- -- 07/07/08 -- 515.96 -- 501.99 479.52 497.04 466.79 496.71 -- -- -- -- 12/16/08 -- 532.53 - 509.80 487.98 498.08 470.11 499.29 489.19 488.63 469.47 472.71 07/07/09 -- 518.28 -- 505.37 481.57 497.43 467.88 499.36 490.38 490.07 467.73 470.91 12/14/09 -- 533.10 -- 511.89 491.93 500.61 473.65 501.48 494.70 493.21 470.98 467.14 06/22/10 -- 518.45 -- 506.72 485.92 499.94 469.67 499.68 493.47 493.07 468.97 471.53 12/13/10 -- 509.41 -- 507.89 482.82 498.20 467.87 496.65 488.89 -- 468.03 -- 06/20/11 -- 515.17 513.91 504.60 482.72 499.96 467.76 498.63 492.11 491.51 468.03 474.35 12/05/11 -- 513.35 507.92 507.44 484.94 498.29 468.45 497.17 488.15 487.45 468.25 464.93 06/13/12 -- 514.08 513.48 507.48 485.36 499.29 468.04 498.85 487.08 490.33 468.81 467.64 12/12/12 -- 511.34 506.86 503.10 481.55 497.24 466.90 494.83 486.84 486.26 467.26 461.41 04/29/13 -- 515.88 513.26 509.38 485.47 500.82 469.60 501.15 492.31 491.64 470.45 455.26 08/05/13 -- 517.21 514.33 505.98 484.47 500.29 468.65 500.83 494.12 -- 469.29 -- 02/25/14 -- 514.06 511.75 509.82 486.32 501.50 473.05 501.99 491.83 491.54 470.28 461.18 08/12/14 -- 519.34 511.98 507.52 485.44 499.25 468.90 499.30 491.92 491.41 470.29 460.31 03/11/15 -- 524.32 516.39 510.37 487.12 502.94 474.18 504.41 500.98 500.12 470.63 473.63 08/18/15 -- 516.53 512.39 503.47 482.97 500.94 466.45 498.81 492.38 -- 469.25 449.71 02/16/16 -- 526.03 515.79 510.07 486.93 501.84 475.45 503.66 500.23 -- 471.15 469.18 08/10/16 -- 520.07 514.29 507.08 484.07 500.34 468.20 500.89 491.95 - 470.40 453.23 02/14/17 -- 524.14 510.89 507.72 484.44 500.34 468.86 501.06 491.73 468.85 453.13 08/23/17 -- 523.08 508.84 506.59 482.82 497.02 467.19 498.16 491.68 - 469.80 452.94 02/06/18 -- 522.73 505.74 507.91 485.62 498.54 468.25 500.31 491.78 471.40 470.93 08/14/18 -- 514.72 510.22 504.44 484.15 498.36 467.48 498.66 -- -- 470.81 474.46 02/05/19 -- 529.50 515.74 509.70 488.03 502.08 472.38 503.41 472.18 475.98 08/07/19 -- 517.02 512.11 503.93 484.68 498.37 467.68 499.01 - 472.31 475.33 02/12/20 -- -- 511.37 510.52 488.77 500.56 473.66 501.32 - -- 472.76 -- 02/12/20 -- -- -- 510.52 488.77 -- -- -- -- -- -- -- 02/13/20 -- -- -- -- -- 500.56 -- 501.32 -- -- -- -- 02/14/20 -- -- 511.37 -- -- -- 473.66 -- - -- 472.76 -- 02/17/20 -- -- 511.73 -- -- - 472.68 -- 472.60 -- 03/19/20 -- -- 512.69 -- -- 469.45 -- - -- 471.82 -- 05/18/20 - -- 513.94 -- -- -- 469.60 -- 471.35 475.83 08/25/20 -- 512.24 507.82 487.29 498.99 -- 499.46 -- -- -- -- 08/26/20 -- 519.93 -- -- -- -- 477.37 -- -- 472.25 473.78 09/29/20 -- -- - 508.90 488.08 -- -- -- -- -- -- -- 09/30/20 -- -- -- -- -- -- 472.08 -- -- -- -- 02/10/21 -- 533.68 517.28 511.01 489.88 502.51 474.72 503.79 -- 472.06 474.72 08/18/21 -- 517.68 511.96 504.72 485.57 498.55 467.86 499.16 - 471.20 -- 02/15/22 -- 517.67 507.49 506.51 486.60 498.23 468.10 497.75 -- 471.26 474.68 09/29/22 512.19 507.47 1 501.07 1 484.72 495.95 466.55 495.11 - 471.55 1 472.99 Notes: 1. Monitoring well MW-3RR was installed in September 2022 to replace abandoned monitoring well MW-3R. Data shown in the table prior to the September 2022 monitoring event for MW-3RR was collected from abandoned monitoring well MW-3R. Groundwater elevations from September 1999 through February 2021 obtained from LaBella Associates Water Quality Monitoring Report - February 202' Groundwater elevations from August 2021 obtained from Garrett & Moore, Inc. Water Quality Monitoring Report - August 2021 Event. ft AMSL = ft above mean sea level -- = not applicable Appendix C (Page 1 of1) https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2022 Second Half GWM/Tables/Oxford Unit 1 Historic Tables Hart & Hickman, Pl. Appendix D Summary of Historical Constituents in Groundwater 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analy[e Sample Date MDL MW-7 MW-2 MW-3RR' MW-4R MW-SR MW-6R NB-2S NE- -Inorganics Antimony 09/14/94 --- --- ND --- --- --- ND --- --- 12/02/94 -- -- ND -- -- -- ND -- -- NC2L=1µg/L 02/08/95 --- --- ND --- --- --- ND --- --- 03/02/95 -- --- ND -- -- -- ND --- -- 11/17/95 ___ ___ ND ___ ___ ___ ND 05/23/96 --- --- ND -- -- -- ND --- -- 11/14/96 ___ ___ ND ___ ___ ___ ND 06/18/97 --- --- ND --- --- __ ND --- __ 12/02/97 ___ ___ ND ___ ___ ___ ND 05/27/98 --- --- ND --- --- __ ND --- __ 11/16/98 ___ ___ ND ___ ___ ___ ND 09/10/99 --- --- ND ND ND ND --- --- -- 11/16/99 --- --- ND ND ND ND --- --- --- 05/10/00 --- --- ND ND ND 68 --- --- -- 10/26/00 --- --- ND ND ND ND --- --- --- 04/18/01 --- --- ND ND ND ND -- --- -- 10/27/01 --- --- ND ND ND ND --- --- --- 06/13/02 --- --- ND ND ND ND -- --- -- 11/19/02 --- --- ND ND ND ND --- --- --- 06/27/03 --- --- ND ND ND ND --- --- -- 12/30/03 --- --- ND ND ND ND --- --- --- 06/30/04 --- --- ND ND ND ND -- --- -- 12/29/04 --- --- ND ND ND ND --- --- --- 06/29/05 --- --- ND ND ND ND -- --- -- 12/29/05 --- --- ND ND ND ND --- --- --- 06/28/06 --- --- ND ND ND ND --- --- -- 12/28/06 --- --- ND ND ND ND --- --- --- 07/02/07 --- --- ND ND ND ND -- --- -- 12/19/07 --- --- ND ND ND ND --- --- --- 07/08/08 --- --- ND ND ND ND --- --- -- 12/16/08 2.6 --- ND ND ND ND --- --- --- 07/08/09 2.6 --- ND ND ND ND -- --- -- 12/15/09 2.6 --- ND ND ND ND --- --- --- 06/23/10 2.6 --- ND ND ND ND --- --- --- 12/14/10 2.6 --- ND ND ND ND --- --- --- 06/21/11 5 ND ND ND ND ND -- --- -- 12/06/11 5 ND ND ND ND ND --- --- --- 06/13/12 5 ND ND ND ND ND --- --- --- 12/11/12 5 ND ND ND ND ND --- --- --- 04/29/13 5 ND ND ND ND ND -- --- -- O8/06/13 5 ND ND ND ND ND --- --- --- 02/25/14 5 ND ND ND ND ND --- --- - 08/13/14 5 ND ND ND ND ND --- --- --- 03/12/15 3.8 ND ND ND ND ND -- --- -- O8/19/15 3.8 ND ND ND ND ND --- --- --- 02/18/16 3.8 ND ND ND ND ND -- --- -- 08/11/16 3.8 ND ND ND ND ND --- --- --- 02/15/17 3.9 ND ND ND ND ND -- --- -- 08/24/17 3.9 ND ND ND ND ND --- --- --- 02/07/18 3.9 ND ND ND ND ND -- --- -- 08/15/18 3.9 ND ND ND ND ND --- --- --- 02/06/19 3.9 ND ND ND ND ND --- --- -- O8/08/19 3 ND ND ND ND ND --- --- --- 02/14/20 3 ND ND ND ND ND --- --- -- 08/26/20 3 ND ND ND ND ND ND --- --- 02/10/21 4.7 ND 5.7 1 --- ND ND --- --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 "' 3 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NA NS Arsenic 09/14/94 --- --- ND --- --- --- ND --- --- 12/02/94 --- --- ND --- --- __ ND --- --- NC2L=10 µg/L 02/08/95 --- --- ND --- --- --- ND --- --- 03/02/95 --- --- ND --- --- -- ND --- -- 11/17/95 ___ ___ ND ___ ___ ___ ND 05/23/96 --- --- ND --- --- -- ND --- -- 11/14/96 --- --- ND --- --- --- ND --- --- 06/18/97 __ __ 14 --- --- __ 5 --- __ 12/02/97 ___ ___ ND ___ ___ ___ ND 05/27/98 -_ __ ND --- --- __ ND --- __ 11/16/98 ___ ___ 12 ___ ___ ___ 6 09/10/99 -- -- ND ND ND 11 --- --- -- 11/16/99 --- --- ND ND ND ND --- --- --- 05/10/00 -- -- ND ND ND ND -- --- -- 10/26/00 --- --- ND ND ND ND --- --- --- 04/18/01 -- -- ND ND ND ND -- --- -- 10/27/01 --- --- ND ND ND ND --- --- --- 06/13/02 --- --- ND ND ND ND --- --- -- 11/19/02 --- --- ND ND ND ND --- --- --- 06/27/03 --- --- ND ND ND ND --- --- -- 12/30/03 --- --- ND ND ND ND --- --- --- 06/30/04 --- --- ND ND ND ND --- --- -- 12/29/04 --- --- ND ND ND ND --- --- --- 06/29/05 --- --- ND ND ND ND -- --- -- 12/29/05 --- --- ND ND ND ND --- --- --- 06/28/06 --- --- ND ND ND ND --- --- -- 12/28/06 --- --- ND ND ND ND --- --- --- 07/12/07 --- --- 4.9 1 ND ND ND --- --- -- 12/19/07 --- --- 2.9 1 ND ND ND --- --- --- 07/08/08 --- --- 3.7 1 ND ND ND -- --- -- 12/16/08 2.7 --- ND ND ND ND --- --- --- 07/08/09 2.7 --- ND ND 4.9 1 ND --- --- -- 12/15/09 2.7 --- 3.2 1 ND ND ND --- --- --- 06/23/10 2.7 --- 2.7 1 ND 5.2 1 ND -- --- -- 12/14/10 2.7 --- ND ND 4.4 1 ND --- --- --- 06/21/11 5 ND ND ND ND ND --- --- -- 12/06/11 5 ND ND ND ND ND --- --- --- 06/13/12 5 ND ND ND ND ND -- --- -- 12/11/12 5 ND ND ND ND ND --- --- --- 04/29/13 5 ND ND ND ND ND --- --- -- O8/06/13 5 ND ND ND ND ND --- --- --- 02/25/14 5 ND ND ND ND ND -- --- -- O8/13/14 5 ND ND ND ND ND --- --- --- 03/12/15 2.5 ND 5.5 1 2.9 1 3.8 1 ND --- --- -- O8/19/15 2.5 ND ND ND ND ND --- --- --- 02/18/16 2.5 ND ND ND ND ND -- --- -- 08/11/16 2.5 ND 3.5 1 ND 3.2 1 ND --- --- --- 02/15/17 5 ND ND ND ND ND --- --- -- 08/24/17 5 ND ND ND ND ND --- --- --- 02/07/18 5 ND ND ND ND ND -- --- -- 08/15/18 5 ND 5.3 1 ND ND ND --- --- --- 02/06/19 5 ND ND ND ND ND --- --- -- O8/08/19 4.7 ND 5.5 1 ND ND ND --- --- --- 02/14/20 4.7 ND ND ND 5.4 1 ND --- --- -- 08/25/20 4.7 ND 5.5 1 7.1 1 ND ND --- --- --- 02/10/21 4.3 ND ND --- ND 4.9 1 --- --- -- 08/18/21 4.7 ___ 9 1 ___ ___ ___ ___ ___ ___ 08/19/21 4.7 --- --- --- 6.3 1 -- -- --- -- 02/15/22 4.7 --- --- 5.4 1 --- --- --- --- --- 09 29 221p 4.7 <10.0 <10.0 <10.0 <10.0 <10,a <10.0 NA NS Appendix D (Page 1 of 23) snr>,mann�<k.snare 1Pros«.1--1-,cMwwco.o,ra,a 11 wn-s«o.a urn, 1.>m 1.- Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-5R MW-611 NES-2S NES-21) Barium 09/14/94 -- -- 260 -- -- -- 1,740 -- -- 12/02/94 ___ ___ ND ___ ___ ___ ND NC 2L=700 µg/L 02/08/95 -- -- ND -- -- -- ND --- -- 03/02/95 ___ ___ ND ___ ___ ___ ND 11/17/95 -- -- ND -- -- -- ND --- -- 05/23/96 ___ ___ ND ___ ___ ___ ND 11/14/96 --- --- 600 --- --- -- 21 --- -- 06/18/97 --- --- 280 --- --- --- 700 --- --- 12/02/97 --- --- 150 --- --- -- 260 --- -- 05/27/98 --- --- 95 --- --- --- 350 --- --- 11/16/98 -- -- 4,800 --- --- -- 5,900 --- -- 09/10/99 --- --- ND ND ND ND --- --- --- 11/16/99 --- --- ND ND ND ND --- --- -- 05/10/00 --- --- ND ND ND ND --- --- --- 10/26/00 --- --- ND ND ND ND -- --- -- 04/18/01 --- --- ND ND ND ND --- --- --- 10/27/01 --- --- ND ND ND ND -- --- -- 06/13/02 --- --- ND ND ND ND --- --- --- 11/19/02 --- --- ND ND ND ND -- --- -- 06/27/03 --- --- ND ND ND ND --- --- --- 12/30/03 --- --- ND ND ND ND --- --- -- 06/30/04 --- --- ND ND ND ND --- --- --- 12/29/04 --- --- ND ND ND ND --- --- -- 06/29/05 --- --- ND ND ND ND --- --- --- 12/29/05 --- --- ND ND ND ND -- --- -- 06/28/06 --- --- ND ND ND ND --- --- --- 12/28/06 --- --- 30.8 24.8 78.5 33.4 -- --- -- 07/12/07 --- --- 13.8 1 24.5 1 82.5 1 27.3 1 --- --- --- 12/19/07 --- --- 14.7 B 20.1 B 28.7 B 27.2 B --- --- -- 07/08/08 --- --- 21.7 1 19.6 1 54.1 1 35.3 1 --- --- --- 12/16/08 0.2 --- 11.2 B 16.5 B 27.0 B 38.8 B --- --- -- 07/08/09 0.2 --- 11.9 B 26.6 B 74.6 B 34.2 B --- --- --- 12/15/09 0.2 --- 16.4 B 18.8 B 38.2 B 39.8 B --- --- -- 06/23/10 0.2 --- 12.0 B 17.7 B 107 B 36.7 B --- --- --- 12/14/30 0.2 --- 11.7 B 26.8 B 37.6 B 46.1 6 --- --- -- 06/21/11 5 6.8 1 14.6 1 18.6 1 37.2 1 41.7 1 --- --- --- 12/06/11 5 16.2 1 13.2 1 27.8 1 38.4 1 43.3 1 --- --- -- 06/13/12 5 9.2 1 16.5 1 20.4 1 52.2 1 39 1 --- --- --- 12/11/12 5 5.2 1 12.6 1 17.2 1 32.1 1 47.3 1 --- --- -- 04/29/13 5 ND 14.7 1 19.6 1 37.6 1 42.2 1 --- --- --- 08/06/13 5 ND 19.7 1 18.7 1 39.8 1 43.1 1 --- --- -- 02/25/14 5 5.6 1 15.3 1 52.7 1 38 1 48 1 --- --- --- 08/13/14 5 ND 19 1 28.4 1 37.7 1 49.6 1 --- --- -- 03/12/15 2.5 12.4 1 13.3 1 28 1 38.6 1 38.9 1 --- --- --- 08/19/15 2.5 4.9 1 17.5 1 25.3 1 36.2 1 42.2 1 --- --- -- 02/18/16 2.5 4.4 1 12.1 1 15.7 1 36.4 1 36.7 1 --- --- --- 08/I1/16 2.5 3.9 1 22.4 1 16.1 1 42.1 1 38.6 1 --- --- -- 02/15/17 2.5 6.1 1 18.2 1 18.6 1 37.2 1 38.9 1 --- --- --- 08/24/17 2.5 11.1 1 18 1 17.1 1 30.9 1 43.1 1 --- --- -- 02/07/18 2.5 3.9 1 15.4 1 18 1 44.6 1 48.7 1 --- --- --- 08/15/18 2.5 3.8 1 21.7 1 16.6 1 39.9 1 41.6 1 --- --- -- 02/06/19 2.5 4 1 15.8 17.4 39.1 52.8 --- --- --- 08/08/19 1 4.5 1 25 32.2 39.3 44.1 --- --- -- 02/14/20 1 11 15.7 23 36.3 45.8 --- --- --- 08/25/20 --- 8.8 63 34.8 37 50.6 124 --- -- 02/10/21 4.7 4.7 1 ND --- --- ND ND --- --- 08/18/21 3.5 40 10.3 17.2 --- 39.9 142 --- -- 08/19/21 3.5 --- --- --- 46.5 --- --- --- --- 02/15/22 3.5 --- 12.5 23 --- --- 147 --- -- 02/16/22 3.5 --- --- --- 62.6 --- --- --- --- 02/17/22 3.5 --- --- --- --- 40.8 --- --- --- 092g 22 i'I 1 3.5 4.3 1 10.5 43.5 40.1 56.0 155 NA NS Beryllium 09/14/94 --- --- ND --- --- --- ND --- --- 12/02/94 --- --- ND --- --- --- ND --- __ NC 2L=4 µg/L 02/08/95 --- --- ND --- --- --- ND --- --- 03/02/95 --- -- ND --- --- --- ND --- -- 11/17/95 ___ ___ ND ___ ___ ___ ND 05/23/96 --- -- ND --- --- -- ND --- -- 11/14/96 ___ ___ ND ___ ___ ___ ND 06/18/97 --- __ 3 --- --- __ 3 --- __ 12/02/97 ___ ___ ND ___ ___ ___ 1 05/27/98 --- __ 2 --- --- _- 3 --- __ 11/16/98 ___ ___ 2 ___ ___ ___ 4 09/10/99 --- -- ND ND ND ND --- --- -- 11/16/99 --- --- ND ND ND ND --- --- --- 05/10/00 --- --- ND ND ND ND -- --- -- 10/26/00 --- --- ND ND ND ND --- --- --- 04/18/01 --- --- ND ND ND ND -- --- -- 10/27/01 --- --- ND ND ND ND --- --- --- 06/10/02 --- --- ND ND ND ND --- --- -- 06/13/02 --- --- ND ND ND ND --- --- --- 11/19/02 --- --- ND ND ND ND --- --- -- 06/27/03 --- --- ND ND ND ND --- --- --- 12/30/03 --- --- ND ND ND ND --- --- -- 06/30/04 --- --- ND ND ND ND --- --- --- 12/29/04 --- --- ND ND ND ND -- --- -- 06/29/05 --- --- ND ND ND ND --- --- --- 12/29/05 --- --- ND ND ND ND -- --- -- 06/28/06 --- --- ND ND ND ND --- --- --- 12/28/06 --- --- ND ND ND ND --- --- -- 07/12/07 --- --- ND ND ND ND --- --- --- 12/19/07 --- --- ND ND ND ND -- --- -- 07/08/08 --- --- 0.14 1 0.1 1 ND ND --- --- --- 12/16/08 0.1 --- ND ND ND 0.18 1 --- --- -- 07/08/09 0.1 --- ND ND ND ND --- --- --- 12/15/09 0.1 --- ND ND ND ND -- --- -- 06/23/10 0.1 --- ND ND ND ND --- --- --- 12/14/10 0.1 --- ND ND ND ND -- --- -- 06/21/11 1 ND ND ND ND ND --- --- --- 12/06/11 1 ND ND ND ND ND --- --- -- 06/13/12 1 ND ND ND ND ND --- --- --- 12/11/12 1 ND ND ND ND ND -- --- -- 04/29/13 1 ND ND ND ND ND --- --- --- 08/06/13 1 ND ND ND ND ND --- --- -- 02/25/14 1 ND ND ND ND ND --- --- --- 08/13/14 1 ND ND ND ND ND -- --- -- 03/12/15 0.5 ND ND ND ND ND --- --- --- 08/19/15 0.5 ND ND ND ND ND --- --- -- 02/18/16 0.5 ND ND ND ND ND --- --- --- 08/11/16 0.5 ND ND ND ND ND -- --- -- 02/15/17 0.5 ND ND ND ND ND --- --- --- 08/24/17 0.5 ND ND ND ND ND -- --- -- 02/07/18 0.5 ND ND ND ND ND --- --- --- 08/15/18 0.5 ND ND ND ND ND --- --- -- 02/06/19 0.5 ND ND ND ND ND --- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 0.2 ND 0.28 1 ND ND ND --- --- --- 08/25/20 0.7 ND ND ND ND ND --- - --- 02/10/21 9.5 ND ND --- --- ND ND --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 ") 0.7 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA NS Appendix D (Page 2 of 23) �np>,madn�<k.sn­L1ros« G-ft&Q-111a co.G,ra,d LF unit„�s«dnd 1m1GII-I- unit, I.>m I.- Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analy[e Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-5R MW-611 NES-2S NES-21) Cadmium 09/14/94 -- -- ND -- -- -- 1 -- -- 12/02/94 ___ ___ ND ___ ___ ___ ND NC 2L=2 µg/L 02/08/95 -- --- ND -- -- -- ND --- -- 03/02/95 ___ ___ ND ___ ___ ___ ND 11/17/95 -- --- ND -- -- -- ND --- -- 05/23/96 ___ ___ ND ___ ___ ___ ND 11/14/96 --- --- ND --- --- -- ND --- -- 06/18/97 ___ ___ ND ___ ___ ___ 3 12/02/97 --- --- ND --- --- __ ND --- __ 05/27/98 ___ ___ ND ___ ___ ___ 1 11/16/98 --- --- ND --- --- -- 4 --- -- 09/10/99 --- --- ND 1 ND ND --- --- --- 11/16/99 --- --- ND ND ND ND -- --- -- 05/10/00 --- --- ND ND ND ND --- --- --- 10/26/00 --- --- ND ND ND ND --- --- -- 04/18/01 --- --- ND ND ND ND --- --- --- 10/27/01 --- --- 2 2 ND ND --- --- -- 06/10/02 --- --- ND 3 ND ND --- --- --- 06/13/02 --- --- ND 3 ND ND -- --- -- 11/19/02 --- --- 3 2 ND 1 --- --- --- 06/27/03 --- --- ND ND ND ND --- --- -- 12/30/03 --- --- ND ND ND ND --- --- --- 06/30/04 --- --- ND 1 ND ND --- --- -- 12/29/04 --- --- ND ND ND ND --- --- --- 06/29/05 --- --- ND ND ND ND -- --- -- 12/29/05 --- --- ND ND ND ND --- --- --- 06/28/06 --- --- ND ND ND ND -- --- -- 12/28/06 --- --- ND ND ND ND --- --- --- 07/12/07 --- --- ND ND ND ND --- --- -- 12/19/07 --- --- ND ND ND ND --- --- --- 07/08/08 --- --- ND ND ND ND -- --- -- 12/16/08 0.5 --- ND ND ND ND --- --- --- 07/08/09 0.5 --- ND ND ND ND --- --- -- 12/15/09 0.5 --- ND ND ND ND --- --- --- 06/23/10 0.5 --- ND ND ND ND -- --- -- 12/14/10 0.5 --- ND ND ND ND --- --- --- 06/21/11 1 ND ND ND ND ND --- --- -- 12/06/11 1 ND ND ND ND ND --- --- --- 06/13/12 1 ND ND ND ND ND -- --- --- 12/11/12 1 ND ND ND ND ND --- --- --- 04/29/13 1 ND ND ND ND ND --- --- -- O8/06/13 1 ND ND ND ND ND --- --- --- 02/25/14 1 ND ND ND ND ND -- --- -- O8/13/14 1 ND ND ND ND ND --- --- --- 03/12/15 0.5 ND ND ND ND ND --- --- -- O8/19/15 0.5 ND ND ND ND ND --- --- --- 02/18/16 0.5 ND ND ND ND ND -- --- -- 08/11/16 0.5 ND ND ND ND ND --- --- --- 02/15/17 0.5 ND ND ND ND ND --- --- -- 08/24/17 0.5 ND ND ND ND ND --- --- --- 02/07/18 0.5 ND ND ND ND ND --- --- -- 08/15/18 0.5 ND ND ND ND ND --- --- --- 02/06/19 0.5 ND ND ND ND ND -- --- -- 08/08/19 0.4 ND ND ND ND ND --- --- --- 02/14/20 0.4 ND ND ND ND ND --- --- -- 08/25/20 0.4 ND ND ND ND ND --- --- --- 02/10/21 0.29 ND --- --- ND ND 0.92 1 --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 0.4 --- --- --- --- --- 0.47 1 --- --- 09 29 22 "' 0.4 <3.0 <3.0 0.55 1 <1.0 <1.0 <1.0 NA NS Chromium 09/14/94 --- --- 91 --- --- --- 177 --- --- 12/02/94 --- --- 88 --- --- __ 24 --- --- NC 2L=10 µ91L 02/08/95 --- --- 56 --- --- --- 19 --- --- 03/02/95 --- 66 --- --- -- 10 --- -- 11/17/95 ___ ___ 53 ___ ___ ___ ND 05/23/96 --- 34 --- --- -- ND --- -- 11/14/96 ___ ___ 8 ___ ___ ___ 8 06/18/97 --- 100 --- --- -- 83 --- -- 12/02/97 ___ ___ 14 ___ ___ ___ 26 05/27/98 --- --- 31 --- --- --- 40 --- __ 11/16/98 --- --- 130 --- --- --- 260 --- --- 09/10/99 --- --- ND 40 ND ND --- --- -- 11/16/99 --- --- ND ND ND ND --- --- --- 05/10/00 --- ND ND ND ND -- --- -- 10/26/00 --- --- ND ND ND ND --- --- --- 04/18/01 --- --- ND 13 ND ND --- --- -- 10/27/01 --- --- 16 56 10 ND --- --- --- 06/10/02 --- --- ND 13 ND ND --- --- -- 06/13/02 --- --- ND 17 ND ND --- --- --- 11/19/02 --- --- 12 ND ND ND --- --- -- 06/27/03 --- --- 13 ND ND 37 --- --- --- 12/30/03 --- --- ND ND ND ND --- --- -- 06/30/04 --- --- ND ND ND ND --- --- --- 12/29/04 --- --- ND ND ND ND --- --- -- 06/29/05 --- --- ND ND ND ND --- --- --- 12/29/05 --- --- ND ND ND ND -- --- -- 06/28/06 --- --- ND 67 ND ND --- --- --- 12/28/06 --- --- 8.9 1 ND ND ND -- --- -- 07/12/07 --- --- ND ND ND ND --- --- --- 12/19/07 --- 2.4 1 2.5 1 ND 2.4 1 --- --- -- 07/08/08 --- --- 8 1 2.8 1 ND 1.9 1 --- --- --- 12/06/08 0.4 --- 2 1 3.2 1 ND 1.9 1 --- --- -- 07/08/09 0.4 --- 3.3 1 7.2 1 ND 0.86 1 --- --- --- 12/15/09 0.4 --- 4.6 1 3.6 1 ND 0.64 1 --- --- -- 06/23/10 0.4 --- 4.1 1 2.6 B 0.9 B 1.3 B --- --- --- Resample 08/12/10 0.4 --- --- --- --- --- --- 12/14/10 0.4 --- 2.8 1 9.1 1 1 1 1.2 1 --- --- --- 06/21/11 5 ND ND ND ND ND --- --- -- 12/06/11 5 ND ND 11.6 ND ND --- --- --- Resample 01/25/12 5 --- --- 6.1 1 --- -- -- --- -- 06/13/12 5 ND 5.1 1 7.5 1 ND ND --- --- --- 12/11/12 5 ND ND ND ND ND --- --- -- 04/29/13 5 ND ND ND ND ND --- --- --- 08/06/13 5 ND 7.4 1 ND ND ND --- --- -- 02/25/14 5 ND ND 19.6 ND ND --- --- --- 08/13/14 5 ND 6.1 1 6.6 1 ND ND --- --- -- 03/12/15 2.5 ND 3.3 1 10.6 ND ND --- --- --- 08/19/15 2.5 ND 5.9 1 7.5 1 ND ND -- --- -- 02/18/16 2.5 ND ND ND ND ND --- --- --- 08/11/16 2.5 3.4 1 11 3.1 1 2.7 1 ND --- --- -- 02/15/17 2.5 ND 6.8 1 2.9 1 ND 3.1 1 --- --- --- 08/24/17 2.5 ND 7.6 1 ND ND ND -- --- -- 02/07/18 2.5 ND 5.1 1 ND ND ND --- --- --- 08/15/18 2.5 ND 12.5 3.2 1 ND ND -- --- -- Resample 11/02/18 2.5 --- 4.1 1 --- --- --- --- --- --- 02/06/19 2.5 ND 4.4 1 3.3 1 ND 5.8 -- --- -- 08/08/19 1 ND 8.5 1.8 1 ND ND --- --- --- 02/14/20 1 3 1 5.1 ND ND 2.5 1 --- --- -- O8/25/20 3.7 ND 22.6 10.9 ND 4.2 1 --- --- --- Resample 09/29/20 3.7 --- 6 ND --- --- --- --- -- 02/10/21 0.2 ND --- --- ND 0.34 1 ND --- --- 08/18/21 3.7 --- 4 1 --- --- --- --- --- _- 02/15/22 3.7 ___ 4 1 ___ ___ ___ ___ ___ ___ 09 29 22 "' 3.7 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NA NS Appendix D (Page 3 of 23) �nr>,mann�<k.snare 1Pros«.1--1-,cMwwco.o,ra,a 11 wn-s«o.a urn, I.>m I.- Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-4R MW-511 MW-6R NES-2S NES-2D Cobalt 09/14/94 -- -- NO -- -- -- NO -- -- 12/02/94 ___ ___ 53 ___ ___ ___ ND NC 2L=1µg/L 02/08/95 -- -- NO -- -- -- 23 --- -- 03/02/95 ___ ___ 22 ___ ___ ___ 24 11/17/95 -- -- 31 -- -- -- 15 --- -- 05/23/96 ___ ___ 19 ___ ___ ___ 16 11/14/96 -- -- 55 --- --- -- 16 --- -- 06/18/97 ___ ___ 52 ___ ___ ___ 28 12/02/97 __ -_ 16 --- --- --- 14 --- __ 05/27/98 ___ ___ 13 ___ ___ ___ 18 11/16/98 _- __ 54 --- --- __ 45 --- __ 09/10/99 --- --- NO 32 NO NO --- --- --- 11/16/99 --- --- NO NO NO NO -- --- -- 05/10/00 --- --- NO NO NO NO --- --- --- 10/26/00 --- --- 35 11 NO NO -- --- -- 04/18/01 --- --- NO 21 NO NO --- --- --- 10/27/01 --- --- NO 28 NO NO --- --- -- 06/10/02 --- --- 11 15 NO NO --- --- --- 06/13/02 --- --- 11 15 NO ND --- --- -- 11/19/02 --- --- NO ND NO NO --- --- --- 06/27/03 --- --- 12 NO NO ND --- --- -- 12/30/03 --- --- NO ND NO NO --- --- --- 06/30/04 --- --- NO NO NO NO -- --- -- 12/29/04 --- --- 12 ND NO NO --- --- --- 06/29/05 --- --- NO NO NO NO - --- -- 12/29/05 --- --- 11 NO NO NO --- --- --- 06/28/06 --- --- NO 21.3 NO NO --- --- -- 12/28/06 --- --- 16.4 NO NO NO --- --- --- 07/12/07 --- --- 11.2 NO NO NO -- --- -- 12/19/07 --- --- 17 4.6 B 1.1 B 1.4 B --- --- --- 07/08/08 --- --- 15 B 4.2 B 3.1 B 5 B -- --- -- 12/16/08 0.6 --- 11 3.2 B 1.4 a 3.1 B --- --- --- 07/08/09 0.6 --- 10.6 NO NO NO --- --- -- 12/15/09 0.6 --- 8.8 1 NO NO NO --- --- --- 06/23/10 0.6 --- 11.8 NO NO NO -- --- -- Resample 08/12/10 0.6 --- --- --- --- --- --- --- --- 12/14/10 0.6 --- 10.9 3.7 B NO 3.1 B --- --- -- 06/21/11 5 NO 11.6 NO ND NO --- --- --- 12/06/11 5 5 1 9.3 1 NO NO NO --- --- -- 06/13/12 5 NO 10.7 ND NO NO --- --- --- 12/31/12 5 NO 10.1 NO NO ND -- --- -- 04/29/13 5 ND 13 ND NO NO --- --- --- 08/06/13 5 NO 20.5 NO NO NO --- --- -- 02/25/14 5 ND 13.9 11.4 NO NO --- --- --- 08/13/14 5 NO 9.5 1 NO NO NO --- --- -- 03/12/15 2.5 NO 8 1 NO NO NO --- --- --- 08/19/15 2.5 NO 11.8 NO NO NO -- --- -- 02/18/16 2.5 NO 7.5 1 NO NO NO --- --- --- 08/11/16 2.5 NO 12.7 NO NO NO -- --- -- 02/15/17 2.5 NO 11.3 NO NO NO --- --- --- 08/24/17 2.5 NO 14.1 NO NO NO -- --- -- 02/07/18 2.5 NO 6.5 1 NO ND NO --- --- --- 08/15/18 2.5 NO 11.6 NO NO NO -- --- -- 11/02/18 2.5 --- 8.3 1 --- --- --- --- --- --- 02/06/19 2.5 NO 10.2 NO NO NO --- --- -- Resample 03/14/19 2.5 --- 5.2 --- --- --- --- --- --- O8/08/19 1.1 NO 11.3 3 1 ND NO -- --- -- 02/14/20 1.1 2.7 1 8.2 NO 1.4 1 1.5 1 --- --- --- 08/25/20 3.6 NO 17.8 NO NO NO --- --- -- 02/10/21 0.3 NO --- --- NO 0.96 1 ND --- --- 08/18/21 3.6 --- 10.5 --- --- --- --- --- -- 02/15/22 3.6 --- 5.8 4.8 1 --- --- 5.8 --- --- 09 29 22 "' 3.6 <5.0 <5.0 9.5 <5.0 <5.0 <5.0 NA NS Copper 09/14/94 --- 130 --- --- --- NO --- -- 12/02/94 ___ ___ NO ___ ___ ___ NO NC 2L=1,000 µg/L 02/08/95 --- --- NO --- --- --- NO --- -- 03/02/95 ___ ___ NO ___ ___ ___ NO 11/17/95 --- --- NO --- --- -- NO --- -- 05/23/96 ___ ___ NO ___ ___ ___ NO 11/14/96 --- --- 54 --- --- -- 15 --- -- 06/18/97 ___ ___ 97 ___ ___ ___ 45 12/02/97 --- --- 24 --- --- __ 17 --- __ 05/27/98 ___ ___ 26 ___ ___ ___ 28 11/16/98 --- 150 --- --- --- 80 --- -- 09/10/99 --- --- NO ND NO ND --- --- --- 11/16/99 --- --- NO NO NO NO --- --- -- 05/10/00 --- --- NO NO NO NO --- --- --- 10/26/00 --- --- NO NO NO NO -- --- -- 04/18/01 --- --- NO NO NO NO --- --- --- 10/27/01 --- --- NO NO NO NO --- --- -- 06/13/02 --- --- NO ND NO NO --- --- --- 11/19/02 --- --- NO NO NO NO --- --- -- 06/27/03 --- --- NO ND NO NO --- --- --- 12/30/03 --- --- NO NO NO NO --- --- -- 06/30/04 --- --- NO ND NO ND --- --- --- 12/29/04 --- --- NO NO NO NO -- --- -- 06/29/05 --- --- NO ND NO ND --- --- --- 12/29/05 --- --- NO NO NO NO -- --- -- 06/28/06 --- --- NO ND NO NO --- --- --- 12/28/06 --- --- 3.5 1 1.7 B 2.5 B 0.9 B --- --- -- 07/12/07 --- --- NO 2 1 NO NO --- --- --- 12/19/07 --- --- 4.6 B 3.8 B 0.56 B 1.9 B --- --- -- 07/08/08 --- --- 9.3 1 1.6 1 NO NO --- --- --- 12/16/08 0.3 --- 2.1 1 2.3 1 NO 6.9 1 --- --- -- 07/08/09 0.3 --- 1.6 1 3.3 1 NO NO --- --- --- 12/15/09 0.3 --- 2.9 1 2.7 1 NO 2.1 1 --- --- -- 06/23/10 0.3 --- 2 1 1.1 1 NO 0.86 1 --- --- --- Resample 08/12/10 0.3 --- --- --- --- -- --- 12/14/10 0.3 --- 1.8 B 8.1 1 0.39 B 5.9 1 --- --- --- 06/21/11 5 NO NO NO NO NO --- --- -- 12/06/11 5 15.5 ND 10 ND NO --- --- --- 06/13/12 5 NO NO 5.6 1 NO NO -- --- -- 12/11/12 5 NO ND NO ND NO --- --- --- 04/29/13 5 NO NO NO NO NO -- --- -- O8/06/13 5 NO 6.6 1 NO ND NO --- --- --- 02/25/14 5 NO NO 14.7 NO 6.4 1 --- --- -- O8/13/14 5 NO ND NO ND NO --- --- --- 03/12/15 2.5 NO ND 7.6 1 NO NO --- --- -- O8/19/15 2.5 NO 5 1 6.8 1 ND NO --- --- --- 02/18/16 2.5 NO NO 3.6 1 NO NO -- --- -- 08/11/16 2.5 NO 7.8 1 NO NO NO --- --- --- 02/15/17 2.5 NO 6.3 1 NO NO NO - --- -- 08/24/17 2.5 5.1 1 3.7 1 NO NO NO --- --- --- 02/07/18 2.5 NO 10 3.4 1 NO NO --- --- -- 08/15/18 2.5 ND 7.4 1 2.8 1 NO NO --- --- --- 02/06/19 2.5 NO NO NO NO 8.1 --- --- -- O8/08/19 2.1 2.5 1 7.1 4.9 1 5 NO --- --- --- 02/14/20 2.1 5.5 4.1 1 NO NO 7.5 -- --- -- 08/25/20 4.3 ND 23.5 13.2 NO 14.2 --- --- --- Resample 09/29/20 4.3 --- NO --- --- -- --- --- -- 02/10/21 0.2 NO 1 NO --- NO 0.91 1 NO --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 "' 4.3 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NA NS Appendix D (Page 4 of 23) �nr>,mann�<k.snare 1Pros«.1--1-,cMwwco.o,ra,a 11 unit -s«ona unit, I.>m I.- Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MWAR MW-SR MW-611 NES-2S NES-21) Iron 06/23/10 14 -- 4150 1040 102 1 413 -- -- -- Resample 08/12/10 140 --- --- --- --- --- --- --- --- NC2L=300 µg/L 12/14/10 14 --- 3210 3880 141 1 877 --- --- -- 06/21/11 50 2190 6030 667 114 1 981 --- --- --- 12/06/11 50 8610 2680 5420 86.1 1 287 1 --- --- -- 06/13/12 50 1770 5610 3280 63.4 1 698 --- --- --- 12/11/12 50 1680 4020 1260 ND 545 -- --- -- 04/29/13 50 414 3500 1130 112 1 635 --- --- --- 08/06/13 50 397 8970 307 ND 378 -- --- -- 02/25/14 50 1040 7060 9750 102 1 2030 --- --- --- 08/13/14 50 209 1 5380 3030 107 1 904 --- --- -- 03/12/15 25 269 1 3680 6040 40.8 1 262 1 --- --- --- 08/19/15 25 156 1 7250 3780 34.9 1 58 1 --- --- -- 02/18/16 25 243 1 792 270 1 43 1 86 1 --- --- --- 08/11/16 25 292 1 10400 839 104 1 ND --- --- -- 02/15/17 25 633 6250 1400 104 1 30 1 --- --- --- 08/24/17 25 3680 9740 792 46.8 1 39 1 --- --- -- 02/07/18 25 323 6740 849 126 1 61 1 --- --- --- 08/15/18 25 340 14000 1200 75.5 1 ND --- --- -- 02/06/19 25 183 3960 1440 54.8 2070 --- --- --- 08/08/19 19.5 176 8240 1770 35.1 1 25 1 --- --- -- 02/14/20 19.5 3750 5050 317 22.4 1 1870 --- --- --- 08/25/20 41.5 1570 18800 6280 ND 2570 984 --- -- Resample 09/29/20 41.5 --- 6320 702 --- 286 --- --- --- 02/10/21 0.3 ND --- --- ND 0.69 1 ND --- -- 08/18/21 41.5 246 6480 241 --- 226 3290 --- --- 08/19/21 41.5 --- --- --- 169 -- --- --- -- 02/15/22 41.5 --- 5110 351 --- --- 6030 --- --- 02/16/22 41.5 --- --- --- 662 -- --- --- -- 09 29 22 i'I 1 41.5 472 1840 3210 <50.0 116 5930 NA NS Lead 09/14/94 --- --- 230 --- --- --- 190 --- --- 12/02/94 --- 26 -_ __ __ 31 --- __ NC 2L=15 µ91L 02/08/95 --- --- 23 --- --- --- 15 --- --- 03/02/95 --- 14 -- --- -- ND --- -- 11/17/95 ___ ___ ND ___ ___ ___ ND 05/23/96 --- 10 --- --- -- ND --- -- 11/14/96 --- --- ND --- --- --- ND --- --- 06/18/97 --- 21 --- --- __ 70 --- __ 12/02/97 ___ ___ 20 ___ ___ ___ 24 05/27/98 --- 23 --- --- __ 32 --- __ 11/16/98 --- --- 33 --- --- --- 110 --- --- 09/10/99 --- --- ND 14 ND ND --- --- -- 11/16/99 --- --- ND ND ND 11 --- --- --- 05/10/00 --- --- ND ND ND ND -- --- -- 10/26/00 --- --- ND ND ND ND --- --- --- 04/18/01 --- --- ND ND ND ND -- --- -- 10/27/01 --- --- 28 15 ND 18 --- --- --- 06/10/02 --- --- 13 ND ND ND --- --- -- 06/13/02 --- --- 13 ND ND ND --- --- --- 11/19/02 --- --- ND ND ND ND --- --- --- 06/27/03 --- --- ND ND ND 10 --- --- --- 12/30/03 --- --- ND ND ND ND -- --- -- 06/30/04 --- --- ND ND ND ND --- --- --- 12/29/04 --- --- ND ND ND ND --- --- -- 06/29/05 --- --- ND ND ND ND --- --- --- 12/29/05 --- --- ND ND ND ND -- --- -- 06/28/06 --- --- ND ND ND ND --- --- --- 12/28/06 --- --- 2 1 ND ND ND --- --- -- 07/12/07 --- --- ND ND ND ND --- --- --- 12/19/07 --- --- ND ND ND ND -- --- -- 07/08/08 --- --- ND ND ND ND --- --- --- 12/16/08 4 --- ND ND ND ND --- --- -- 07/08/09 4 --- ND ND ND ND --- --- --- 12/15/09 4 --- ND ND ND ND --- --- -- 06/23/10 4 --- ND ND ND ND --- --- --- 12/14/10 4 --- ND ND ND ND -- --- -- 06/21/11 5 ND ND ND ND ND --- --- --- 12/06/11 5 ND ND ND ND ND --- --- -- 06/13/12 5 ND ND ND ND ND --- --- --- 12/11/12 5 ND ND ND ND ND -- --- -- 04/29/13 5 ND ND ND ND ND --- --- --- 08/06/13 5 ND ND ND ND ND --- --- --- 02/25/14 5 ND ND ND ND ND --- --- --- 08/13/14 5 ND ND ND ND ND -- --- -- 03/12/15 2.5 ND ND ND ND ND --- --- --- 08/19/15 2.5 ND 2.9 1 ND ND ND --- --- --- 02/18/16 2.5 ND ND ND ND ND --- --- --- 08/11/16 2.5 ND 2.7 1 ND ND ND -- --- -- 02/15/17 2.5 ND ND ND ND ND --- --- --- 08/24/17 2.5 ND ND ND ND ND --- --- -- 02/07/18 2.5 ND 2.8 1 ND ND ND --- --- --- 08/15/18 2.5 ND ND ND ND ND -- --- -- 02/06/19 2.5 ND ND ND ND ND --- --- --- 08/08/19 1.6 ND ND ND ND ND --- --- -- 02/14/20 1.6 ND 2.4 1 2.1 1 ND ND --- --- --- 08/25/20 4.5 ND ND ND ND ND --- --- --- 02/10/21 3.5 4.1 1 --- --- ND ND ND --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 ") 4.5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NA NS Manganese 06/23/10 0.3 --- 217 44 B 513 127 --- --- -- Resample 08/12/10 3 --- --- --- --- --- --- --- --- NC2L=50 L 121410 0.3 --- 208 139 730 194 --- --- -- 06/21/11 5 38.2 1 245 36.9 1 833 130 --- --- --- 12/06/11 5 198 216 170 808 187 -- --- -- 06/13/12 5 41.7 1 226 95.8 760 125 --- --- --- 12/11/12 5 33.8 1 230 28.9 1 770 279 -- --- -- 04/29/13 5 14.2 1 193 47.3 1 724 139 --- --- --- 08/06/13 5 10.3 1 273 38.5 1 749 135 -- --- -- 02/25/14 5 29.8 1 222 340 897 154 --- --- --- 08/13/14 5 5.8 1 209 108 1230 125 --- --- -- 03/12/15 2.5 6 1 210 200 676 104 --- --- --- 08/19/15 2.5 4.3 1 288 199 802 103 --- --- -- 02/18/16 2.5 5.4 1 201 72.7 981 82.4 --- --- --- 08/11/16 2.5 5.9 1 336 122 1550 100 -- --- -- 02/15/17 2.5 15.5 1 234 246 1390 91.4 --- --- --- 08/24/17 2.5 94.7 344 116 999 98.3 --- --- -- 02/07/18 2.5 7.6 1 168 196 1160 158 --- --- --- 08/15/18 2.5 6.7 1 284 63.6 937 105 -- --- -- 02/06/19 2.5 5.5 226 79 1050 121 --- --- --- 08/08/19 0.9 6 272 995 1020 97.6 --- --- -- 02/14/20 0.9 85.8 175 606 983 117 --- --- --- 08/25/20 --- 35.2 356 407 764 117 2100 --- -- Resample 09/29/20 3.4 --- 186 --- --- --- --- --- --- 02/30/21 4.3 4.4 1 --- --- ND ND ND --- -- 08/18/21 3.4 82.4 262 470 --- 82 2310 --- --- 08/19/21 3.4 --- --- --- 864 -- --- --- -- 02/15/22 3.4 --- 192 1140 --- --- 2390 --- --- 02/16/22 3.4 --- --- --- 35.9 -- --- --- -- 02/17/22 3.4 --- --- --- --- 103 --- --- --- 09 29 22 i'i 3.4 20.9 175 3480 15.6 335 2180 NA NS Appendix D (Page 5 of 23) s snare 1Pros«.1--1-,cMwwco.o,ra,a 11 unit -s«ona unit, a.>m I.- Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analy[e Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-511 MW-611 NES-2S NES-2D Mercury 11/17/95 -- -- NO -- -- -- NO -- -- 12/02/97 ___ ___ NO ___ ___ ___ NO NC2L=1 µg/L 03/23/98 -- -- NO -- -- -- NO --- -- 05/27/98 ___ ___ NO ___ ___ ___ NO 11/16/98 -- -- NO --- --- --- NO --- -- 09/10/99 --- --- NO NO NO NO --- --- --- 11/16/99 -- --- NO NO NO NO -- --- -- 05/10/00 --- --- NO NO NO NO --- --- --- 10/26/00 --- --- NO NO NO NO --- --- -- 04/18/01 --- --- NO ND NO ND --- --- --- 10/27/01 --- --- --- --- --- 06/10/02 --- --- NO NO ND NO --- --- --- 06/13/02 --- --- NO NO NO NO -- --- -- 11/19/02 --- --- --- --- --- ___ ___ ___ ___ 06/27/03 --- --- NO NO NO 0.78 --- --- -- 12/30/03 --- --- NO NO NO NO --- --- --- 06/30/04 --- --- NO NO NO NO --- --- -- 12/29/04 --- --- NO NO NO NO --- --- --- 06/29/05 --- --- NO NO NO NO --- --- -- 12/29/05 --- --- ND NO NO NO --- --- --- 06/28/06 --- --- NO NO NO NO -- --- -- 12/28/06 --- --- ND NO ND NO --- --- --- 07/12/07 --- --- NO NO NO NO -- --- -- 12/19/07 --- --- ND NO ND ND --- --- --- 07/08/08 --- --- NO NO NO NO --- --- -- 12/16/08 0.09 --- NO NO NO NO --- --- --- 07/08/09 0.07 --- NO NO NO NO --- --- -- 12/15/09 0.07 --- NO NO NO NO --- --- --- 06/23/10 0.07 --- NO NO 0.094 J NO --- --- -- 12/14/10 0.07 ND NO NO NO --- --- --- 06/21/11 0.1 NO NO NO NO NO -- --- -- 12/06/11 0.1 NO ND NO ND NO --- --- --- 06/13/12 0.1 NO NO NO NO NO --- --- -- 12/11/12 0.1 NO NO NO NO NO --- --- --- 04/29/13 0.1 NO NO NO NO NO -- --- -- 08/06/13 0.1 NO NO NO NO NO --- --- --- 02/25/14 0.1 NO NO NO NO NO --- --- --- 08/13/14 0.1 NO NO NO NO NO --- --- --- 03/12/15 0.1 NO NO NO NO NO --- --- -- 08/19/15 0.1 NO ND NO NO NO --- --- --- 02/18/16 0.1 NO NO NO NO NO -- --- -- 08/11/16 0.1 NO 0.11 1 NO ND NO --- --- --- 02/15/17 0.1 NO NO NO NO NO --- --- -- 08/24/17 0.1 NO NO NO NO NO --- --- --- 02/07/18 0.1 NO 0.11 1 NO NO NO -- --- -- 08/15/18 0.1 NO NO NO NO NO --- --- --- 02/06/19 0.1 NO NO NO NO NO - --- -- 08/08/19 0.1 NO NO NO NO NO --- --- --- 02/14/20 0.1 NO NO NO --- NO -- --- -- 08/25/20 0.12 NO 0.13 1 NO NO NO --- --- --- 02/10/21 0.26 NO NO --- --- --- -- --- -- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 i'I 1 0.12 <0.20 1 <0.20 <0.20 <0.20 I <0.20 <0.20 1 NA INS Nickel 09/14/94 --- --- NO --- --- --- NO --- --- 12/02/94 --- --- 119 --- --- -- NO --- --- NC2L=100 µg/L 02/08/95 --- --- NO --- --- --- NO --- --- 03/02/95 --- --- NO --- --- -- NO --- -- 11/17/95 ___ ___ NO ___ ___ ___ NO 05/23/96 --- --- NO --- --- -- NO --- -- 11/14/96 ___ ___ NO ___ ___ ___ NO 06/18/97 --- --- 65 --- --- -- NO --- -- 12/02/97 ___ ___ NO ___ ___ ___ NO 05/27/98 --- --- NO --- --- __ NO --- __ 11/16/98 --- --- NO --- --- --- 150 --- --- 09/10/99 --- --- NO NO NO NO --- --- -- 11/16/99 --- --- NO NO NO NO --- --- --- 05/10/00 --- --- NO NO NO NO -- --- -- 10/26/00 --- --- NO NO NO NO --- --- --- 04/18/01 --- --- NO NO NO NO -- --- -- 10/27/01 --- --- NO 59 ND NO --- --- --- 06/10/02 --- --- NO NO ND NO -- --- --- 06/13/02 --- --- NO NO NO NO --- --- --- 11/19/02 --- --- NO NO NO NO --- --- -- 06/27/03 --- --- NO NO NO NO --- --- --- 12/30/03 --- --- NO NO ND ND --- --- -- 06/30/04 --- --- NO ND NO NO --- --- --- 12/29/04 --- --- NO NO NO ND -- --- -- 06/29/05 --- --- NO ND NO NO --- --- --- 12/29/05 --- --- NO NO NO NO --- --- -- 06/28/06 --- --- NO ND NO NO --- --- --- 12/28/06 --- --- 7 1 7.2 1 2.4 1 NO -- --- -- 07/12/07 --- --- 3.2 1 2.5 1 NO ND --- --- --- 12/19/07 --- --- 3.2 1 5 NO 2.3 1 --- --- -- 07/08/08 --- --- 5.3 1 2.3 1 NO 1.7 1 --- --- --- 12/16/08 1.7 --- 2.3 B 2.5 B NO 2.7 B --- --- -- 07/08/09 1.7 --- 3.2 1 6 1 NO 1.8 1 --- --- --- 12/15/09 1.7 --- 3.6 B 4.4 B 2.1 B 2.6 B --- --- -- 06/23/10 1.7 --- 2.3 1 NO NO NO --- --- --- 12/14/10 1.7 --- 1.8 B 2.6 B NO NO -- --- -- 06/21/11 5 NO NO NO NO NO --- --- --- 12/06/11 5 NO NO 6.4 1 NO NO -- --- -- 06/13/12 5 NO NO NO NO NO --- --- --- 12/11/12 5 NO NO NO NO NO -- --- -- 04/29/13 5 NO NO NO NO NO --- --- --- 08/06/13 5 NO NO NO NO NO --- --- -- 02/25/14 5 NO ND 11.3 1 ND NO --- --- --- 08/13/14 5 NO NO NO NO NO --- --- -- 03/12/15 2.5 NO ND 11.7 1 ND NO --- --- --- 08/19/15 2.5 NO 3.7 1 8.9 1 NO NO -- --- -- 02/18/16 2.5 NO ND 3.2 1 ND NO --- --- --- 08/11/16 2.5 NO 6.4 1 6.7 1 NO NO --- --- -- 02/15/17 2.5 NO 4.9 1 8.8 1 NO NO --- --- --- 08/24/17 2.5 3.3 1 5.6 1 4.6 1 NO NO -- --- -- 02/07/18 2.5 NO NO 4.8 1 NO NO --- --- --- 08/15/18 2.5 NO 5.5 1 3.4 J NO NO --- --- -- 02/06/19 2.5 NO 2.9 1 3.1 1 NO 2.8 1 --- --- --- 08/08/19 0.9 0.93 1 4.3 1 9.8 1.1 1 1.3 1 --- --- -- 02/14/20 0.9 2.5 1 3.2 1 7.1 1.9 1 1.7 1 --- --- --- 08/25/20 3.5 NO 12.6 11.7 NO NO --- --- -- 02/10/21 3 ND NO --- NO ND NO --- --- 08/18/21 3.5 --- --- 8.4 --- --- --- --- -- 02/15/22 3.5 --- --- 7.3 --- --- 3.6 1 --- --- 09 29 22 "' 3.5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NA NS Appendix D (Page 6 of 23) snare 1Pros«.1--1-,cMwwco.o,ra,a 11 wn-s«o.a urn, I.>m I.- Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analy[e Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-511 MW-611 NES-2S NES-2D Selenium 09/14/94 -- -- NO -- -- -- NO -- -- 12/02/94 ___ ___ NO ___ ___ ___ NO NC 2L=20 µ8/L 02/08/95 -- --- NO -- -- -- NO --- -- 03/02/95 ___ ___ NO ___ ___ ___ NO 11/17/95 -- --- NO -- -- -- NO --- -- 05/23/96 ___ ___ NO ___ ___ ___ NO 11/14/96 --- --- NO --- -- -- NO --- -- 06/18/97 ___ ___ NO ___ ___ ___ NO 12/02/97 --- --- NO --- --- _- NO --- __ 05/27/98 ___ ___ NO ___ ___ ___ NO 11/16/98 --- --- NO --- --- --- NO --- -- 09/10/99 --- --- NO NO NO NO --- --- --- 11/16/99 --- --- NO NO NO NO --- --- -- 05/10/00 --- --- ND NO NO NO --- --- --- 10/26/00 --- --- NO NO NO NO -- --- -- 04/18/01 --- --- ND NO ND NO --- --- --- 10/27/01 --- --- NO NO NO NO -- --- -- 06/13/02 --- --- ND NO ND NO --- --- --- 11/19/02 --- --- NO NO NO NO --- --- -- 06/27/03 --- --- NO NO NO NO --- --- --- 12/30/03 --- --- NO NO NO NO --- --- -- 06/30/04 --- --- NO NO NO NO --- --- --- 12/29/04 --- --- NO NO NO ND --- --- -- 06/29/05 --- --- NO ND NO NO --- --- --- 12/29/05 --- --- NO NO NO ND --- --- -- 06/28/06 --- --- NO ND NO NO --- --- --- 12/28/06 --- --- NO NO NO NO --- --- -- 07/12/07 --- --- NO ND NO NO --- --- --- 12/19/07 --- --- NO NO NO NO -- --- -- 07/08/08 --- --- NO NO NO ND --- --- --- 12/16/08 3.8 --- NO NO NO NO --- --- -- 07/08/09 3.8 --- NO NO NO NO --- --- --- 12/15/09 3.8 --- NO NO NO NO -- --- -- 06/23/10 3.8 --- NO NO NO NO --- --- --- 12/14/10 3.8 --- NO NO NO NO --- --- -- 06/21/11 10 NO NO NO NO NO --- --- --- 12/06/11 10 NO NO NO NO NO -- --- -- 06/13/12 10 NO NO NO NO NO --- --- --- 12/11/12 10 NO NO NO NO NO --- --- -- 04/29/13 10 NO ND NO NO NO --- --- --- 08/06/13 10 NO NO NO NO NO -- --- -- 02/25/14 10 NO NO NO NO NO --- --- --- 08/13/14 10 NO NO NO NO NO --- --- -- 03/12/15 5 NO NO NO NO NO --- --- --- 08/19/15 5 NO NO NO NO NO -- --- -- 02/18/16 5 NO ND NO ND NO --- --- --- 08/11/16 5 NO NO NO NO NO - --- -- 02/15/17 5 NO ND NO ND NO --- --- --- 08/24/17 5 NO NO NO NO NO -- --- -- 02/07/18 5 NO ND NO ND NO --- --- --- 08/15/18 5 NO NO NO ND NO -- --- -- 02/06/19 5 NO NO NO NO NO --- --- --- 08/08/19 4.7 NO NO NO NO NO --- --- -- 02/14/20 4.7 NO NO NO NO NO --- --- --- 08/25/20 4.7 NO NO NO NO 5.9 1 --- --- -- 02/10/21 0.7 ND NO --- NO --- NO --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 "' 4.7 <10.0 <10.0 <10.0 <10.0 <10.0 <10.0 NA NS Silver 09/14/94 --- --- ND --- --- --- NO --- -- 12/02/94 ___ ___ NO ___ ___ ___ NO NC 2L=20 µ8/L 02/08/95 --- --- NO --- --- --- NO --- -- 03/02/95 ___ ___ NO ___ ___ ___ NO 11/17/95 --- --- NO -- --- -- NO --- -- 05/23/96 ___ ___ NO ___ ___ ___ NO 11/14/96 --- --- NO -- --- -- NO --- -- 06/18/97 ___ ___ NO ___ ___ ___ NO 12/02/97 --- __ NO --- --- __ 4 --- __ 05/27/98 ___ ___ NO ___ ___ ___ NO 11/16/98 --- -- NO --- --- -- NO --- -- 09/10/99 --- --- ND NO NO NO --- --- --- 11/16/99 --- -- NO NO NO NO --- --- -- 05/10/00 --- --- ND NO NO NO --- --- --- 10/26/00 --- --- NO NO NO NO -- --- -- 04/18/01 --- --- ND NO ND NO --- --- --- 10/27/01 --- --- NO NO NO NO -- --- -- 06/13/02 --- --- ND NO ND NO --- --- --- 11/19/02 --- --- NO NO NO NO --- --- -- 06/27/03 --- --- NO NO NO NO --- --- --- 12/30/03 --- --- NO NO NO NO --- --- -- 06/30/04 --- --- NO ND NO NO --- --- --- 12/29/04 --- --- NO NO NO ND -- --- -- 06/29/05 --- --- NO ND NO NO --- --- --- 12/29/05 --- --- NO NO NO NO --- --- -- 06/28/06 --- --- NO ND NO NO --- --- --- 12/28/06 --- --- NO NO NO NO -- --- -- 07/12/07 --- --- NO NO NO ND --- --- --- 12/19/07 --- --- NO NO 0.26 1 NO -- --- -- 07/08/08 --- --- 0.27 1 0.41 1 0.83 1 0.39 1 --- --- --- 12/16/08 0.1 --- NO 0.25 1 0.53 1 0.4 1 --- --- -- 07/08/09 0.1 --- NO NO 0.17 1 NO --- --- --- 12/15/09 0.1 --- NO 0.32 1 0.64 1 0.53 1 --- --- -- 06/23/10 0.1 --- NO NO 0.13 1 0.13 1 --- --- --- 12/14/10 0.1 --- NO 0.24 B 0.58 B 0.34 B --- --- -- 06/21/11 5 NO NO NO NO NO --- --- --- 12/06/11 5 NO NO NO NO NO -- --- -- 06/13/12 5 NO NO NO NO NO --- --- --- 12/11/12 5 NO NO NO NO NO -- --- -- 04/29/13 5 NO NO NO NO NO --- --- --- 08/06/13 5 NO NO NO NO NO --- --- -- 02/25/14 5 NO NO NO NO NO --- --- --- 08/13/14 5 NO NO NO NO NO --- --- -- 03/12/15 2.5 NO ND NO ND NO --- --- --- 08/19/15 2.5 NO NO NO NO NO -- --- -- 02/18/16 2.5 NO NO NO NO NO --- --- --- 08/11/16 2.5 NO NO NO NO NO --- --- -- 02/15/17 2.5 NO NO NO NO NO --- --- --- 08/24/17 2.5 NO NO NO NO NO -- --- -- 02/07/18 2.5 NO NO NO NO NO --- --- --- 08/15/18 2.5 NO NO NO NO NO --- --- -- 02/06/19 2.5 NO NO NO ND NO --- --- --- 08/08/19 2.5 NO NO NO NO NO --- --- -- 02/14/20 2.5 NO NO NO NO NO --- --- --- 08/25/20 2.5 NO NO NO NO NO --- --- -- 02/10/21 0.4 ND NO --- NO --- NO --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 "' 2.5 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NA NS Appendix D (Page 7 of 23) snare 1Pros«.1--1-,cMwwco.o,ra,a 11 wn -s«o.a urn, I.>m I.- Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analy[e Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-511 MW-611 NES-2S NES-21) Sulfide 11/17/95 -- -- ND -- -- -- ND -- -- 12/02/97 ___ ___ ND ___ ___ ___ ND NC 2L = NE 03/23/98 -- -- 1000 -- -- -- 1400 --- -- 05/27/98 --- --- 1000 --- --- --- ND --- --- 11/16/98 -- 13000 --- --- -- ND --- -- 09/10/99 --- --- NO ND ND ND --- --- --- 11/16/99 -- --- ND ND ND ND --- --- -- 05/10/00 --- --- 17000 5000 47000 33000 --- --- --- 10/26/00 --- --- ND NO ND ND -- --- -- 04/18/01 --- --- ND ND NO ND --- --- --- 06/13/02 --- ND ND ND ND -- --- -- 06/27/03 --- --- --- --- --- ___ ___ ___ ___ 12/30/03 --- --- --- -- 06/30/04 --- --- NO 7 NO ND --- --- --- 12/29/04 --- -- - --- --- 06/29/05 --- --- ND ND ND ND --- --- --- 12/29/05 --- --- ND ND 1700 B ND --- --- -- 06/28/06 --- --- ND ND ND ND --- --- --- 12/28/06 --- --- ND S00 1 ND ND -- --- -- 07/12/07 --- --- ND ND ND ND --- --- --- 12/19/07 --- --- ND ND ND ND --- --- -- 07/08/08 --- --- ND ND ND ND --- --- --- 12/16/08 100 --- ND 1S0 1 ND 141 1 --- --- -- 07/08/09 100 --- ND ND ND ND --- --- --- 12/15/09 100 --- ND ND ND ND --- --- -- 06/23/10 100 --- ND ND ND ND --- --- --- 12/14/10 100 --- ND ND ND ND --- --- -- 06/21/11 100 ND ND ND ND ND --- --- --- 12/06/11 100 ND ND ND ND ND -- --- -- 06/13/12 100 ND ND ND ND ND --- --- --- 12/11/12 100 ND ND ND ND 117 1 --- --- -- 04/29/13 100 ND NO ND NO ND --- --- --- 08/06/13 100 ND ND ND NO ND --- --- -- 02/25/14 100 ND ND 141 1 189 1 ND --- --- --- 08/13/14 50 ND --- --- -- ND --- --- -- 03/12/15 100 ND --- --- --- ND --- --- --- 08/19/15 100 ND --- --- -- ND -- --- -- 02/18/16 100 ND --- --- --- ND --- --- --- 08/11/16 100 ND -- --- -- ND --- --- -- 02/15/17 100 ND --- --- --- ND --- --- --- 08/24/17 100 ND -- --- --- ND -- --- -- 02/07/18 100 ND --- --- --- ND --- --- --- 02/06/19 50 ND --- --- -- ND --- --- -- O8/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA O8/25/20 50 ND --- --- --- ND --- --- --- 02/30/21 50 ND --- --- -- ND --- --- -- O8/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 i'I NA NA NA NA NA NA NA NA NS Thallium 09/14/94 --- --- ND --- --- --- ND --- --- 12/02/94 ... --- ND --- --- __ ND --- __ NC 2L=2 µg/L 02/08/95 --- --- ND --- --- --- ND --- --- 03/02/95 --- --- ND --- --- -- ND --- -- 11/17/95 ___ ___ NO ___ ___ ___ ND 05/23/96 --- --- ND --- --- -- ND --- -- 11/14/96 --- --- ND --- --- --- ND --- --- 06/18/97 --- --- ND --- --- --- ND --- -- 12/02/97 ___ ___ ND ___ ___ ___ ND 05/27/98 --- __ ND --- --- --- ND --- __ 11/16/98 ___ ___ ND ___ ___ ___ ND 09/10/99 --- -- ND ND ND ND --- --- -- 11/16/99 --- --- ND ND ND ND --- --- --- 05/10/00 --- -- ND ND ND ND --- --- -- 10/26/00 --- --- ND ND ND ND --- --- --- 04/18/01 --- -- ND ND ND ND -- --- -- 10/27/01 --- --- ND ND ND ND --- --- --- 06/13/02 --- -- NO ND ND ND -- --- -- 11/19/02 --- --- ND ND ND ND --- --- --- 06/27/03 --- --- ND ND ND ND --- --- -- 12/30/03 --- --- ND ND ND ND --- --- --- 06/30/04 --- --- ND ND ND ND --- --- -- 12/29/04 --- --- ND ND ND ND --- --- --- 06/29/05 --- --- ND ND ND ND --- --- -- 12/29/05 --- --- NO ND NO ND --- --- --- 06/28/06 --- --- ND ND ND ND -- --- -- 12/28/06 --- --- ND ND NO ND --- --- --- 07/12/07 --- --- ND NO ND ND --- --- -- 12/19/07 --- --- ND ND ND ND --- --- --- 07/08/08 --- --- 4.5 1 ND ND ND -- --- -- 12/16/08 3 --- ND ND ND ND --- --- --- 07/08/09 3 --- ND ND ND ND --- --- -- 12/15/09 3 --- ND ND ND 3.8 1 --- --- --- 06/23/10 3 --- ND ND ND ND -- --- -- Resample 08/12/10 30 --- --- --- --- --- --- --- --- 12/14/10 3 --- ND ND 8.1 ND - --- -- 06/21/11 5.4 ND ND ND ND ND --- --- --- 12/06/11 5.4 ND ND ND ND ND - --- -- 06/13/12 5.4 ND ND ND ND ND --- --- --- 12/11/12 5.4 ND ND ND ND ND -- --- -- 04/29/13 5.4 NO ND NO ND ND --- --- --- 08/06/13 5.4 ND ND ND ND ND --- --- -- 02/25/14 5.4 ND ND ND ND ND --- --- --- 08/13/14 5.4 ND ND ND ND ND -- --- -- 03/12/15 5 ND ND ND ND ND --- --- --- 08/19/15 5 ND ND ND ND ND --- --- -- 02/18/16 5 ND ND ND ND NO --- --- --- 08/11/16 5 ND ND ND ND ND -- --- -- 02/15/17 0.02 ND ND ND ND ND --- --- --- 08/24/17 0.02 ND ND ND ND ND --- --- --- 02/07/18 0.028 ND ND ND ND ND --- --- --- 08/15/18 0.02 ND ND ND ND ND --- --- -- 02/06/19 0.06 ND ND ND ND ND --- --- --- 08/08/19 0.11 ND ND ND ND ND --- --- -- 02/14/20 0.06 ND ND ND ND ND --- --- --- 08/25/20 0.05 ND 0.12 ND NO ND -- -- -- 02/10/21 0.24 ND NO --- --- --- --- --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 221�1 0.05 <0.47 <0.47 <0.47 <0.47 <0.47 <0.47 NA NS Tin 07/08/08 --- 1.9 1 3 1 3 1 3.6 1 --- --- --- 12/16/08 1.8 --- --- --- --- --- --- NC2L=2,000 µg/L 07/08/09 1.8 -- ND ND 1.8 1 ND --- --- 12/15/09 ___ ___ ___ ___ ___ ___ ___ 06/23/10 1.8 -- ND ND 1.9 1 2.5 1 -- --- -- 12/14/10 --- --- --- --- --- ___ ___ ___ ___ 06/21/11 5 ND ND ND ND ND -- --- -- 12/06/11 5 --- --- --- --- --- --- 06/13/12 5 ND ND NO ND ND --- --- 12/11/12 --- --- --- --- --- ___ ___ ___ ___ 04/29/13 5 ND ND NO ND ND --- --- -- 08/06/13 --- --- --- --- --- ___ ___ ___ ___ 02/25/14 5 ND ND ND NO, ND -- --- -- 08/13/14 --- --- --- --- --- ___ ___ ___ ___ 03/12/15 2.5 ND --- --- -- ND -- --- -- 02/18/16 2.5 ND --- --- --- ND --- --- --- 02/15/17 2.5 ND --- --- --- ND -- --- -- O8/24/17 2.5 ND --- --- --- ND --- --- --- 02/07/18 2.5 ND ND --- ND ND -- --- -- 02/06/19 2.5 ND ND ND ND ND --- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA O8/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 0.7 ND --- ND --- --- --- --- --- O8/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 ") NA NA NA NA NA NA NA NA NS Appendix D (Page 8 of 23) �np>,madn�<k.sn­L1ros« G-ft&Q-111a co.o,ra,d LF unit„�s«dnd 1.11G11 ,m- unit, I.-T.- Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MWAR MW-SR MW-611 NES-2S NES-21) Total Cyanide 07/08/08 ND ND 6.2 1 ND 12/16/08 --- --- --- --- --- --- --- --- --- NC 2L NE 07/08/09 5 ND ND ND ND 12/15/09 --- --- --- --- --- 06/23/10 5 ND ND ND ND 12/14/10 --- --- --- --- --- --- --- --- --- 06/21/11 5 ND ND ND ND ND 12/06/11 --- --- --- --- --- --- --- --- --- 06/13/12 5 5.8 1 6.2 j 5.2 1 --- ... --- ... 12/11/12 --- --- --- --- --- --- --- --- --- 04/29/13 5 ND ND ND ND ND 08/06/13 --- --- --- --- --- --- --- --- --- 02/25/14 5 ND ND ND ND ND 08/13/14 --- --- --- --- --- --- --- --- --- 02/06/19 NA NA NA NA NA NA NA NA NA 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22 i'i NA NA NA NA NA NA NA NA NS Total Dissolved Solids 06/23/10 250000 96200 184000 364000 237000 12/14/10 25000 100000 218000 372000 260000 NC 2L 500,000 Vi 06/21/11 5000 170000 89000 194000 374000 238000 12/06/11 174000 92000 168000 378000 242000 06/13/12 25000 189000 98000 184000 390000 253000 12/11/12 25000 199000 141000 199000 427,000 274000 04/29/13 25000 170000 114000 183000 416000 276000 08/06/13 25000 179000 142000 175000 421000 291000 02/25/14 25000 173000 109000 206000 405,000 281000 08/13/14 25000 172000 184000 187000 446000 319000 03/12/15 229000 113000 184000 430000 256000 08/19/15 217000 149000 172000 431000 303000 02/18/16 25000 162000 84000 140000 412000 237000 08/11/16 25000 213000 122000 171000 437000 301000 02/15/17 25000 233000 62000 154000 438000 277000 08/24/17 25000 226000 114000 160000 418000 270000 02/07/18 235000 124000 170000 444000 308000 08/15/18 25000 249000 238000 164000 458000 303000 02/06/19 25000 246000 124000 172000 468000 334000 08/08/19 25000 256000 228000 188000 469000 323000 02/14/20 25000 249000 141000 165000 468000 317000 08/25/20 262000 232000 196000 465,000 357000 660000 02/10/21 271000 --- --- --- --- --- --- --- 08/18/21 259000 96000 168000 294000 562000 02/15/22 50000 117000 175000 732000 Ig 02/16/22 50000 526000 --- --- --- --- 02/17/22 25000 268000 328000 09/29/22 "' . 25000 246000 148000 399000 517000 326000 668000 NA NS Tritium (Hydrogen-3) 02/06/19 NA NA NA NA NA NA NA NA NA 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 0.49 --- --- --- --- 0.95 1 02/10/21 NA NA NA NA NA NA NA NA NA 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA NC 2L = NE 09/29/22 ") NA NA NA NA NA NA NA NA NS Vanadium 09/14/94 390 340 12/02/94 233 ND NC 2L 7 ug/L 02/08/95 132 ND 03/02/95 173 ND 11/17/95 84 ND 05/23/96 103 ND 11/14/96 140 22 06/18/97 310 82 12/02/97 52 27 05/27/98 71 41 11/16/98 340 97 09/10/99 ND ND ND ND 11/16/99 ND ND ND ND 05/10/00 ND ND ND ND 10/26/00 ND ND ND ND 04/18/01 ND ND ND ND 10/27/01 67 53 ND 63 06/10/02 ND ND ND ND 06/13/02 ND ND ND ND 11/19/02 ND ND ND ND 06/27/03 ND ND ND 94 12/30/03 ND ND ND ND 06/30/04 ND ND ND ND 12/29/04 ND ND ND ND 06/29/05 ND ND ND ND 12/29/05 ND ND ND ND 06/28/06 ND 71.1 ND ND 12/28/06 28.4 ND ND 1.8 1 07/12/07 3.4 1 2.2 1 ND ND 12/19/07 7.6 3.2 1 1.1 B 0.82 B Resample 02/14/08 7.2 --- --- --- --- --- --- Filtered 07/08/08 21.9 1 2.2 1 0.94 B 0.78 B 12/16/08 0.2 4.9 1 3.4 1 0.84 B 6.1 1 07/08/09 0.2 10.6 1 8.3 1 1.7 B 1.9 B 12/15/09 0.2 12.1 1 3.8 1 1.3 B 2.3 B 06/23/10 0.2 10.7 1 2 1 0.51 1 1.2 1 Resample 08/12/10 0.2 --- --- --- --- --- --- --- --- 12/14/10 0.2 7.3 1 8 1 1.2 B 4 1 06/21/11 5 5.9 1 14.6 1 ND ND ND 12/06/11 5 19.8 1 5.3 1 10 1 ND ND 06/13/12 5 5.2 1 13 1 6.5 1 ND ND 12/11/12 5 ND 7.4 1 ND ND ND 04/29/13 5 ND 8.4 1 ND ND ND 08/06/13 5 ND 27.6 ND ND ND 02/25/14 5 ND 18.6 1 19 1 ND 7 1 08/13/14 5 ND is 1 7.2 1 ND ND 03/12/15 2.5 ND 9.5 1 14.8 1 ND 3.3 1 08/19/15 2.5 ND 19.2 1 8.3 1 ND ND 02/18/16 2.5 ND ND ND ND ND 08/11/16 2.5 ND 25.2 ND ND ND 02/15/17 2.5 ND 13.9 1 ND ND ND 08/24/17 2.5 10.3 1 23.7 1 ND ND ND 02/07/18 2.5 ND 18.1 1 2.6 1 ND ND 08/15/18 2.5 ND 34.5 2.6 1 ND ND Resample 11/02/18 2.5 13 1 --- --- --- --- ... --- 02/06/19 2.5 ND 10.4 3.5 1 ND 9.5 Resample 03/14/19 2.5 10 --- ... --- --- --- --- 08/08/19 1.3 2.2 1 23.4 4.8 1 ND ND 02/14/20 1.3 9.2 13.1 ND ND 9.3 08/25/20 3.9 4.4 1 53 13.5 ND 12.2 Resample 09/29/20 3.9 17.5 ND ND 02/10/21 4.3 ND ND ND ND 08/18/21 3.9 11.3 --- --- --- --- --- --- 02/15/22 3.9 12.5 --- --- --- --- --- --- 09/29/22 in 3.9 <5.0 4.8 1 <5.0 <5.0 <5.0 <5.0 NA NS Appendix D (Page 9 of 23) 0­1 Pros-G-fts 1-- C., - 11 U.it - S...d '.I' GII-I- Wit I I.- I.- Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-511 MW-611 NES-2S NES-2D Zinc 09/14/94 -- -- 400 -- -- -- 640 -- -- 12/02/94 --- --- 380 --- --- --- 98 --- --- NC 2L=1,000 pg/L 02/08/95 -- -- 236 -- -- -- 108 --- -- 03/02/95 --- --- 102 --- --- --- NO --- --- 11/17/95 -- - 154 -- -- -- NO --- -- 05/23/96 --- --- 116 --- --- --- NO --- --- 11/14/96 --- 140 --- --- -- 48 --- -- 06/18/97 --- --- 250 --- --- --- 190 --- --- 12/02/97 --- --- 110 --- --- -- 130 --- -- 05/27/98 --- --- 90 --- --- --- 110 --- --- 11/16/98 --- --- 3600 --- --- -- 3900 --- -- 09/10/99 --- --- NO 96 NO NO --- --- --- 11/16/99 --- --- NO NO NO NO -- --- -- 05/10/00 --- --- NO ND NO NO --- --- --- 10/26/00 --- --- NO NO NO NO -- --- -- 04/18/01 --- --- NO 64 NO NO --- --- --- 10/27/01 --- --- 55 136 NO 32 --- --- -- 06/10/02 --- --- NO 72 NO NO --- --- --- 06/13/02 --- --- NO 72 NO NO --- --- -- 11/19/02 --- --- NO NO NO NO --- --- --- 06/27/03 --- --- NO NO NO 52 --- --- -- 12/30/03 --- --- NO ND ND NO --- --- --- 06/30/04 -- -- NO NO NO ND --- --- -- 12/29/04 --- --- NO ND NO NO --- --- --- 06/29/05 -- -- NO NO NO NO -- --- -- 12/29/05 --- --- NO ND NO NO --- --- --- 06/28/06 -- -- NO 126 NO NO -- --- -- 12/28/06 --- --- 14 7.8 1 NO ND --- --- --- 07/12/07 --- --- 3.6 1 6.5 1 NO NO --- --- -- 12/19/07 --- --- 0.4 B NO 4.5 B ND --- --- --- 07/08/08 --- 12.6 NO NO NO -- --- -- 12/16/08 0.4 --- 0.45 1 3.8 1 NO 12.3 --- --- --- 07/08/09 0.4 --- 0.67 1 7 1 NO NO --- --- -- 12/15/09 0.4 --- 5.5 B 6.9 B NO 1.9 B --- --- --- 06/23/10 0.4 --- 2.2 1 1 1 NO NO --- --- -- 12/14/10 0.4 --- 16.3 B 12.6 B NO NO --- --- --- 06/21/11 10 NO NO NO NO NO -- --- -- 12/06/11 10 21.8 B NO 21 B NO ND --- --- --- 06/13/12 10 NO NO 14 NO NO -- --- -- 12/11/12 10 NO NO NO NO NO --- --- --- 04/29/13 10 NO NO NO NO NO --- --- -- O8/06/13 10 NO NO NO NO NO --- --- --- 02/25/14 10 NO NO 31.9 NO NO -- --- -- O8/13/14 10 NO NO 24.1 NO NO --- --- --- 03/12/15 5 9.2 B 11.5 B 24.3 B 6.8 B 7.5 B --- --- -- O8/19/15 5 NO 7.2 B 16.3 B ND NO --- --- --- 02/18/16 5 14.8 NO NO 6.6 1 NO -- --- -- 08/11/16 5 NO 18.2 8.6 1 ND NO --- --- --- 02/15/17 5 NO 14.7 8 1 NO NO -- --- -- 08/24/17 5 9.2 1 8.1 1 10.7 NO NO --- --- --- 02/07/18 5 NO NO NO NO NO --- --- -- 08/15/18 5 NO 15.3 6.6 1 NO NO --- --- --- 02/06/19 5 NO NO NO NO NO --- --- -- O8/08/19 3.9 ND 7.2 1 6 1 NO NO --- --- --- 02/14/20 3.9 9.6 1 5.8 1 NO NO 4.4 1 -- --- -- 08/25/20 9.5 ND 32 20.6 NO ND --- --- --- 02/30/21 4.5 NO NO --- NO NO --- --- -- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 "' 1 9.5 110.0 <10.0 <10.0 <10.0 <10.0 <10.0 NA NS Appendix D (Page 10 of 23) snare 1Pros«.1--1-,cMwwco.o,ra,a 11 unit -s«ona unit, 1.>m 1.- Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RRz MW-4R MW-SR MW-6R NES-IS NES-2D Organics 1,1-Dichloroethane 11/11/16/99 --- --- ND ND ND 6 --- --- --- 09/14/94 -- -- ND -- -- -- ND --- -- NC2L=6 µg/L 12/02/94 --- --- ND --- --- --- ND --- --- 02/08/95 --- -- ND -- -- -- ND --- -- 03/02/95 ___ ___ ND ___ ___ ___ ND 11/17/95 --- --- ND -- -- -- ND --- -- 05/23/96 ___ ___ ND ___ ___ ___ 7 11/14/96 --- --- ND --- --- -- ND --- -- 06/18/97 ___ ___ ND ___ ___ ___ 9.7 12/02/97 --- --- ND --- --- __ ND --- __ 05/27/98 ___ ___ ND ___ ___ ___ 12 11/16/98 --- --- ND --- --- --- 5.2 --- __ 09/10/99 --- --- ND ND ND ND --- --- --- 12/16/99 --- --- --- --- --- 5 --- --- __ 05/10/00 --- --- ND ND ND 6 --- --- --- 10/26/00 --- --- ND ND ND 7 -- --- -- 04/18/01 --- --- ND ND ND 6 --- --- --- 10/27/01 --- --- ND ND ND 7 --- --- -- 06/10/02 --- --- ND ND ND 6 --- --- --- 06/13/02 --- --- ND ND ND 6 --- --- -- 11/19/02 --- --- ND ND ND ND --- --- --- 06/27/03 --- --- ND ND ND 7.2 -- --- -- 12/30/03 --- --- ND ND ND 6.3 --- --- --- 06/30/04 --- --- ND ND ND 6.5 -- --- -- 12/29/04 --- --- ND ND ND 6.9 --- --- --- 06/29/05 --- --- ND ND ND 7 --- --- -- 12/29/05 --- --- ND ND ND 6 --- --- --- 06/28/06 --- --- ND ND ND 6.6 -- --- -- 12/28/06 --- --- ND ND ND 5.3 --- --- --- 07/12/07 --- --- ND 0.33 1 ND 5.4 --- --- -- Resample 08/21/07 --- --- --- 0.4 1 --- --- --- --- --- 12/19/07 --- --- ND ND ND 6.2 -- --- -- 07/08/08 --- --- ND ND ND 5.1 --- --- --- 12/16/08 0.32 --- ND ND ND 3.4 1 --- --- -- 07/08/09 0.32 --- ND ND ND 9.3 --- --- --- 12/15/09 0.32 --- ND ND ND 6.4 --- --- -- 06/23/10 0.32 --- ND ND ND 6.5 --- --- --- 12/14/10 0.32 --- ND ND ND 3.9 1 --- --- -- 06/21/11 0.32 ND ND ND ND 6.7 --- --- --- 12/06/11 0.32 ND ND ND ND 3 1 --- --- -- 06/13/12 0.32 ND ND ND ND 3.7 1 --- --- --- 12/12/12 0.32 ND ND ND ND 2.5 1 --- --- -- 04/29/13 0.32 ND ND ND ND 5.8 --- --- --- 08/06/13 0.32 ND ND ND ND 5 --- --- -- 02/25/14 0.32 ND ND ND ND 4.5 1 --- --- --- 08/13/14 0.32 ND ND ND ND 3.4 1 --- --- -- 03/12/15 0.32 ND ND ND ND 4.2 1 --- --- --- 08/19/15 0.32 ND ND ND ND 3.7 1 --- --- -- 02/18/16 0.32 ND ND ND ND 3.4 1 --- --- --- 08/11/16 0.32 ND ND ND ND 3.4 1 --- --- -- 02/15/17 0.32 ND ND ND ND ND --- --- --- 08/24/17 0.32 ND ND ND ND 2.2 1 --- --- -- 02/07/18 0.32 ND ND ND ND 1.7 1 --- --- --- 08/16/18 0.32 ND ND ND ND 2.4 1 --- --- -- 02/06/19 0.27 ND ND ND ND 3 --- --- --- 08/07/19 0.27 ND ND ND ND 2.2 --- --- -- 02/14/20 0.27 ND ND ND ND 2.3 --- --- --- 08/25/20 0.27 ND ND ND ND 2 1.2 --- -- 02/10/21 0.62 ND ND --- ND ND ND --- --- 08/18/21 0.37 --- --- 1.6 1.3 --- -- 02/15/22 0.37 --- --- --- --- --- 1.4 --- --- 02/17/22 0.37 --- --- --- -- 1.4 --- -- -- 09 29 22 "' 0.37 <1.0 <1.0 <1.0 <1.0 1.1 1.4 NA NS 1,2-Dichlorobenzene 07/12/07 --- --- ND ND ND 0.6 1 --- --- --- 12/19/07 --- --- ND 0.32 1 ND 0.99 1 --- --- -- NC2L=20 µg/L 07/08/08 --- --- ND ND ND 1.3 1 --- --- --- 12/16/08 0.3 --- ND ND ND 0.73 1 --- --- -- 07/08/09 0.3 --- ND ND ND 1.1 1 --- --- --- 12/15/09 0.3 --- ND ND ND 0.99 1 --- --- -- 06/23/10 0.3 --- ND ND ND 1 1 --- --- --- 12/14/30 0.3 --- ND ND ND 0.78 1 --- --- -- 06/21/11 0.3 ND ND ND ND 1.1 1 --- --- --- 12/06/11 0.3 ND ND ND ND 0.74 1 --- --- -- 06/13/12 0.3 ND ND ND ND 1.1 1 --- --- --- 12/12/12 0.3 ND ND ND ND 1.1 1 --- --- -- 04/29/13 0.3 ND ND ND ND 1.2 1 --- --- --- 08/06/13 0.3 ND ND ND ND 1.2 1 --- --- -- 02/25/14 0.3 ND ND ND ND 1.1 1 --- --- --- 08/13/14 0.3 ND ND ND ND 1.1 1 --- --- -- 03/12/15 0.3 ND ND ND ND 0.89 1 --- --- --- 08/19/15 0.3 ND ND ND ND 1.2 1 --- --- -- 02/18/16 0.3 ND ND ND ND 1 1 --- --- --- 08/11/16 0.3 ND ND ND ND 1.2 1 --- --- -- 02/15/17 0.3 ND ND ND ND 1.1 1 --- --- --- 08/24/17 0.3 ND ND ND ND 1 1 --- --- -- 02/07/18 0.3 ND ND ND ND 1.1 1 --- --- --- 08/16/18 0.3 ND ND ND ND 1.2 1 --- --- -- 02/06/19 0.29 ND ND ND ND 1.4 --- --- --- 08/07/19 0.29 ND ND ND ND 0.82 1 --- --- -- 02/14/20 0.29 ND ND ND ND 1.1 --- --- --- 08/25/20 0.29 ND ND ND ND 1.1 --- --- -- 02/10/21 0.49 ND ND ND ND ND --- --- --- 08/18/21 0.34 --- --- --- --- 0.87 1 --- --- -- 02/17/22 0.34 --- --- --- --- 0.99 1 --- --- --- 09 29 221�1 0.34 <1.0 <1.0 <1.0 <1.0 1.4 <1.0 NA NS 1,2-Dichloroethane 08/06/13 0.12 ND ND 0.62 1 ND ND --- --- -- 02/25/14 0.12 ND ND ND ND ND --- --- --- NC2L=0.4 µg/L 08/13/14 0.12 ND ND ND ND ND --- --- -- 03/12/15 0.12 ND ND ND ND ND --- --- --- 08/19/15 0.24 ND ND ND ND ND --- --- -- 02/18/16 0.24 ND ND ND ND ND --- --- --- 08/11/16 0.24 ND ND ND ND ND --- --- -- 02/15/17 0.24 ND ND ND ND ND --- --- --- 08/24/17 0.24 0.24 1 ND ND ND 0.25 1 --- --- -- 02/07/18 0.24 ND ND ND ND ND --- --- --- 08/16/18 0.24 ND ND ND ND ND -- --- -- 02/06/19 0.34 ND ND ND ND ND --- --- --- 08/07/19 0.34 ND ND ND ND ND --- --- -- 02/14/20 0.34 ND ND ND ND ND --- --- --- 08/25/20 0.34 ND ND ND ND ND --- --- -- 02/10/21 2.3 ND ND --- ND ND ND --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 "' 0.32 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA NS Appendix D (Page 11 of 23) �np>,mann<k.snereo«�L�omn�revMa.,.��a.,,s�ana o«�m.�waa.Mes Pros« G-ftaco.o,ra,a Lr wn „zoo s«o.a urn, a.>m 1.- Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date MDL MVI-7 MW-2 MW-3RR' MW-4R MW-SR MVI-611 NES-2S NES-21) 1,3-Dichloroben-e 07/08/08 ND ND ND 0.29 1 12/16/08 --- --- --- --- --- --- --- --- --- NC 2L 200 lig/L 07/08/09 0.24 ND ND ND 0.38 1 12/15/09 --- --- --- --- --- --- --- --- --- 06/23/10 0.24 ND ND 0.35 1 12/14/10 --- --- --- --- --- --- --- --- --- 06/21/11 0.24 ND ND ND 0.32 1 12/06/11 --- --- --- --- --- --- --- --- --- 06/13/12 0.24 ND ND ND ND 0.29 1 12/12/12 --- --- --- --- --- --- --- --- --- 04/29/13 0.24 ND ND ND ND 0.36 1 08/06/13 --- --- --- --- --- --- --- --- --- 02/25/14 0.24 ND ND ND ND 0.29 1 08/13/14 --- --- --- --- --- --- --- --- --- 03/12/15 0.24 ND ND 02/18/16 0.24 ND 0.31 1 08/11/16 0.24 ND ND 02/15/17 0.24 ND 0.38 1 08/24/17 0.24 ND ND 02/07/18 0.24 ND ND 02/06/19 0.22 ND ND ND ND 0.37 1 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 0.51 ND ND 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22 "' NA NA NA NA NA NA NA NA NS 1,4-Dichlorobenzene 09/14/94 ND ND 12/02/94 ND ND NC 2L 6 Vg/L 02/08/95 ND ND 03/02/95 ND ND 11/17/95 ND ND 05/23/96 ND ND 11/14/96 ND ND 06/18/97 ND ND 12/02/97 ND ND 05/27/98 ND ND 11/16/98 ND 2.2 09/10/99 ND ND ND ND 11/16/99 ND ND ND ND 05/10/00 ND ND ND ND 10/26/00 ND ND ND ND 04/18/01 ND ND ND ND 10/27/01 ND ND ND ND 06/13/02 ND ND ND ND 11/19/02 ND ND ND ND 06/27/03 ND ND ND ND 12/30/03 ND ND ND ND 06/30/04 ND ND ND ND 12/29/04 ND ND ND ND 06/29/05 ND ND ND ND 12/29/05 ND ND ND ND 06/28/06 ND ND ND ND 12/28/06 ND ND ND ND 07/12/07 ND 0.32 1 ND ND Resample 08/21/07 0.3 1 --- --- --- --- --- 12/19/07 ND 0.52 1 ND 0.71 1 07/08/08 ND ND ND 0.96 1 12/16/08 0.33 ND ND ND 0.64 1 07/08/09 0.33 ND ND ND 0.84 1 12/15/09 0.33 ND ND ND 0.76 1 06/23/10 0.33 ND ND ND 0.79 1 12/14/10 0.33 ND ND ND 0.96 B 06/21/11 0.33 ND ND ND ND I 12/06/11 0.33 ND ND ND ND 0.81 1 06/13/12 0.33 ND ND ND ND 0.77 1 12/12/12 0.33 ND ND ND ND 0.83 1 04/29/13 0.33 ND ND ND ND 1 08/06/13 0.33 ND ND ND ND 1 02/25/14 0.33 ND ND ND ND 0.82 1 08/13/14 0.33 ND ND ND ND 0.97 1 03/12/15 0.33 ND ND ND ND 0.86 1 08/19/15 0.33 ND ND ND ND 1 02/18/16 0.33 ND ND ND ND 0.92 1 08/11/16 0.33 ND ND ND ND 0.93 j 02/15/17 0.33 ND ND ND ND 1.1 08/24/17 0.33 ND ND ND ND 0.81 j 02/07/18 0.33 ND ND ND ND 0.81 1 08/16/18 0.33 ND ND ND ND 1.1 02/06/19 0.26 ND ND ND ND ND 08/07/19 0.26 ND ND ND ND ND 02/14/20 0.26 ND ND ND ND ND 08/25/20 0.26 ND ND ND ND 0.79 1 02/10/21 0.41 ND ND ND ND ND 08/18/21 NA NA NA NA NA NA NA NA NA 02/17/22 0.33 --- --- --- --- 0.71 1 09/29/22 ") , 0.33 <1.0 <1.0 <1.0 <1.0 0.96 1 <1.0 NA NS Appendix D (Page 12 of 23) 0­1 -J-1-- 1-- C., - 11 U.it - S...d Wit 1 1.- 1.- Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analy[e Sample Date MDL MW-7 MW-2 MW-3RR' MWAR MW-511 MW-611 NES-2S NES-21) 1,4-Dioxane 08/16/18 1.9 ND ND 16.5 21.2 41.6 -- -- -- 02/06/19 1.9 ND ND 21 26.8 57.9 --- --- --- NC2L=3 Ng/L 08/07/19 1.9 ND ND 15.7 23.1 44.5 --- --- -- 02/14/20 1.2 --- ND 13.8 23.6 44.2 --- --- --- 08/25/20 1.2 ND ND 14.6 27.7 47.4 6.1 --- -- 02/10/21 0.12 ND --- --- --- --- --- --- --- 08/18/21 0.86 --- -- 11.8 -- 36.6 7 --- -- 08/19/21 0.86 --- --- --- 25.1 --- --- --- --- 02/15/22 0.86 --- --- 14.2 --- -- 9.1 --- -- 02/16/22 0.86 --- --- --- 23.7 --- --- --- --- 02/17/22 0.86 --- --- --- --- 47.4 --- --- -- 09 29 22 "' 0.86 1.7 J 1 <2.0 70.2 19.3 65.1 1 11.0 <2.0 NS 2-Hexanone 05/27/98 --- --- ND --- --- --- 61 --- --- 11/16/98 --- --- ND --- --- -- ND --- -- NC2L=NE 09/10/99 --- --- ND ND ND ND --- --- --- 11/16/99 --- --- ND ND ND ND --- --- -- O5/10/00 --- --- ND ND ND ND --- --- --- 10/26/00 --- --- ND ND ND ND --- --- -- 04/18/01 --- --- ND ND ND ND --- --- --- 10/27/01 --- --- ND ND ND ND --- --- -- 06/13/02 --- --- ND ND ND ND --- --- --- 11/19/02 --- --- ND ND ND ND --- --- -- 06/27/03 --- --- ND ND ND ND --- --- --- 12/30/03 --- --- ND ND ND ND -- --- -- 06/30/04 --- --- ND ND ND ND --- --- --- 12/29/04 --- --- ND ND ND ND --- --- -- 06/29/05 --- --- ND ND ND ND --- --- --- 12/29/05 --- --- ND ND ND ND -- --- -- 06/28/06 --- --- ND ND ND ND --- --- --- 12/28/06 --- --- ND ND ND ND --- --- -- 07/12/07 --- --- ND ND ND ND --- --- --- 12/19/07 --- --- ND ND ND ND -- --- -- 07/08/08 --- --- ND ND ND ND --- --- --- 12/16/08 0.46 --- ND ND ND ND -- --- -- 07/08/09 0.46 --- ND ND ND ND --- --- --- 12/15/09 0.46 --- ND ND ND ND --- --- -- 06/23/10 0.46 --- ND ND ND ND --- --- --- 12/14/10 0.46 --- ND ND ND ND -- --- -- 06/21/11 0.46 ND ND ND ND ND --- --- --- 12/06/11 0.46 ND ND ND ND ND -- --- -- 06/13/12 0.46 ND ND ND ND ND --- --- --- 12/12/12 0.46 ND ND ND ND ND --- --- -- 04/29/13 0.46 ND ND ND ND ND --- --- --- 08/06/13 0.46 ND ND 0.55 1 ND ND -- --- -- 02/25/14 0.46 ND ND ND ND ND --- --- --- 08/13/14 0.46 ND ND ND ND ND --- --- -- 03/12/15 0.46 ND ND ND ND ND --- --- --- 08/19/15 0.46 ND ND ND ND ND -- --- -- 02/18/16 0.46 ND ND ND ND ND --- --- --- 08/11/16 0.46 ND ND ND ND ND --- --- -- 02/15/17 0.46 ND ND ND ND ND --- --- --- 08/24/17 0.46 ND ND ND ND ND -- --- -- 02/07/18 0.46 ND ND ND ND ND --- --- --- 08/16/18 0.46 ND ND ND ND ND --- --- -- 02/06/19 0.57 ND ND ND ND ND --- --- --- 08/07/19 0.57 ND ND ND ND ND -- --- -- 02/14/20 0.57 ND ND ND ND ND --- --- --- 08/25/20 0.57 ND ND ND ND ND --- --- -- 02/10/21 0.26 ND ND --- ND ND ND --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 "' 0.48 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NA NS 4.4'-DDT 06/23/10 0.0037 --- ND ND ND 0.016 J --- --- -- 12/14/10 ___ ___ ___ ___ ___ ND NC 2L=0.1 pg/L 06/21/11 0.0036 ND ND ND ND ND --- --- -- 12/06/11 ___ ___ ___ ___ ___ ND 06/13/12 0.05 ND ND ND ND 0.09 1 --- --- -- 12/12/12 ___ ___ ___ ___ ___ ND 04/29/13 0.05 ND ND ND ND ND --- --- -- 08/06/13 ___ ___ ___ ___ ___ ND 02/25/14 0.05 ND ND ND ND ND --- --- -- 08/13/14 --- --- --- --- --- ___ ___ ___ ___ 03/12/15 0.05 ND --- --- --- ND -- --- -- 02/18/16 0.05 ND --- --- --- ND --- --- --- 08/11/16 0.05 --- -- --- --- --- -- --- 02/15/17 0.05 ND --- --- --- ND --- --- --- 02/07/18 0.053 ND -- --- --- ND --- --- -- 02/06/19 0.05 ND --- --- --- ND --- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 "' NA NA NA NA NA NA NA NA NS Acetone 12/15/09 2.2 --- ND ND ND ND --- --- -- 06/23/10 2.2 --- ND ND ND ND --- --- --- NC2L=6,000 pg/L 12/14/10 2.2 ND ND ND ND --- --- -- 06/21/11 2.2 ND 3.8 B 2.8 ND ND --- --- --- 12/06/11 2.2 ND ND ND ND ND --- --- -- 06/13/12 2.2 ND ND ND ND ND --- --- --- 12/12/12 10 ND ND ND ND ND --- --- -- 04/29/13 10 ND ND ND ND ND --- --- --- 08/06/13 10 ND ND ND ND ND --- --- -- 02/25/14 10 ND ND ND ND ND --- --- --- 08/13/14 10 ND ND ND ND ND -- --- -- 03/12/15 10 ND ND ND ND ND --- --- --- 08/19/15 10 ND ND ND ND ND --- --- -- 02/18/16 10 ND ND ND ND ND --- --- --- 08/11/16 10 ND ND ND ND ND --- --- -- 02/15/17 10 ND ND ND ND ND --- --- --- 08/24/17 10 ND ND ND ND ND --- --- -- 02/07/18 10 ND ND ND ND ND --- --- --- 08/16/18 10 ND ND ND ND ND --- --- -- 02/06/19 6.2 ND ND ND ND ND --- --- --- 08/07/19 6.2 ND ND ND ND ND -- --- -- 02/14/20 6.2 ND ND ND ND ND --- --- --- 08/25/20 6.2 ND ND ND ND ND --- --- -- 02/10/21 0.27 ND ND --- ND ND ND --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 "' 5.1 <25.0 <25.0 <25.0 <25.0 <25.0 NS <25.0 NS Appendix D (Page 13 of 23) LFUnn „--�.I... n.m.-Unn, �.-T.... Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-5R MW-611 NES-2S NES-21) Aldrin 11/17/95 -- -- ND -- -- -- ND — -- 12/02/97 ___ ___ ND ___ ___ ___ ND NC 2L=0.002 µg/L 03/23/98 -- --- ND -- -- -- ND --- -- 05/27/98 ___ ___ ND ___ ___ ___ ND 11/16/98 -- --- ND --- --- --- ND --- -- 09/10/99 --- --- ND ND ND ND --- --- --- 11/16/99 -- --- ND ND ND ND --- --- -- 05/10/00 --- --- ND ND ND ND --- --- --- 10/26/00 -- --- ND ND ND ND -- --- -- 04/18/01 --- --- ND ND ND ND --- --- --- 06/13/02 -- --- ND ND ND ND -- --- -- 06/27/03 --- --- ND ND ND ND --- --- --- 12/30/03 --- --- -- 06/30/04 --- --- ND ND ND ND --- --- --- 12/29/04 --- --- --- --- --- 06/29/05 --- --- ND ND ND ND --- --- --- 12/29/05 --- --- -- 06/28/06 --- --- ND ND ND ND --- --- --- 12/28/06 -- --- -- 07/12/07 --- --- ND ND ND ND --- --- --- 12/19/07 --- --- -- 07/08/08 --- --- ND ND ND ND --- --- --- 12/16/08 --- -- --- -- 07/08/09 0.05 --- ND ND ND ND --- --- --- 12/15/09 --- -- --- -- 06/23/10 0.00053 --- ND ND ND ND --- --- --- 12/14/10 ... -- _. --- --- 06/21/11 0.0005 ND ND ND ND ND --- --- --- 12/06/11 --- --- -- --- --- 06/13/12 0.05 ND ND ND ND ND --- --- --- 12/12/12 --- --- -- --- 04/29/13 0.05 ND ND ND ND ND --- --- --- 08/06/13 --- --- _- --- --- 02/25/14 0.05 ND ND ND ND ND --- --- --- 08/13/14 --- --- --- --- --- 03/12/15 0.05 ND --- --- --- ND --- --- --- 02/18/16 0.05 ND --- --- -- ND -- --- -- 08/11/16 0.05 --- --- --- --- --- --- 02/15/17 0.05 ND -- --- -- ND -- --- -- 02/07/18 0.053 ND --- --- --- ND --- --- --- 02/06/19 0.05 ND -- --- -- ND --- --- -- O8/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 221'1 I NA NA NA NA NA NA NA NA NS Alpha-BHC 11/17/95 --- --- ND --- --- --- ND --- --- 12/02/97 ... --- ND --- --- __ ND --- __ NC 2L=0.006 µg/L 03/23/98 --- --- ND --- --- --- ND --- --- 05/27/98 --- --- ND --- --- --- 0.053 --- -- 11/16/98 ___ ___ ND ___ ___ ___ ND 09/10/99 --- --- ND ND ND ND --- --- -- 11/16/99 --- --- ND ND ND ND --- --- --- 05/10/00 --- --- ND ND ND ND -- --- -- 10/26/00 --- --- ND ND ND ND --- --- --- 04/18/01 --- --- ND ND ND ND -- --- -- 06/13/02 --- --- ND ND ND ND --- --- --- 06/27/03 --- --- ND ND ND ND -- --- -- 12/30/03 --- --- --- --- --- ___ ___ ___ ___ 06/30/04 --- --- ND ND ND ND -- --- -- 12/29/04 --- --- --- --- --- ___ ___ ___ ___ 06/29/05 --- --- ND ND ND ND -- --- -- 12/29/05 --- --- --- --- --- ___ ___ ___ ___ 06/28/06 --- — ND ND ND ND --- --- -- 12/28/06 --- --- --- --- --- ___ ___ ___ ___ 07/12/07 --- — ND ND ND ND -- --- -- 12/19/07 --- --- --- --- --- ___ ___ ___ ___ 07/08/08 --- --- ND ND ND ND --- --- -- 12/16/08 --- --- --- --- --- ___ ___ ___ ___ 07/08/09 0.05 --- ND ND ND ND -- --- -- 12/15/09 --- --- --- --- --- ___ ___ ___ ___ 06/23/10 0.00032 --- ND ND ND ND --- --- -- 12/14/10 --- --- --- --- --- ___ ___ ___ ___ 06/21/11 0.0003 ND ND 0.054 ND ND --- --- -- Resample 07/28/11 0.0003 --- --- ND --- --- --- --- --- 12/06/11 --- --- --- --- --- 06/13/12 0.05 ND ND ND ND ND --- --- --- 12/12/12 --- --- --- --- --- 04/29/13 0.05 ND ND ND ND ND --- --- --- 08/06/13 --- --- --- --- --- 02/25/14 0.05 ND ND ND ND ND --- --- --- 08/13/14 --- --- --- --- --- 03/12/15 0.05 ND --- --- --- ND --- --- --- 02/18/16 0.05 ND -- --- --- ND -- --- -- 08/11/16 0.05 --- --- --- --- --- --- 02/15/17 0.05 ND -- --- --- ND -- --- -- 02/07/18 0.053 ND --- --- --- ND --- --- --- 02/06/19 0.05 ND -- --- --- ND -- --- -- O8/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA O8/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 "' NA NA NA NA NA NA NA NA NS Appendix D (Page 14 of 23) �np>,madn�<k.snereo«���dmn�revMa.,.��a.,,ssand o«�m.nwaa.Mes Pros« G—ftQ-111a co.o,ra,d LF unit„�s«dnd 1.11G11 ,m— unit, a.>m 1.— Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analy[e Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-5R MW-611 NES-2S NES-21) Benzene 09/14/94 -- -- ND -- -- -- ND - -- 12/02/94 ___ ___ ND ___ ___ ___ ND NC 2L=1µg/L 02/08/95 -- --- ND -- -- -- ND --- -- 03/02/95 ___ ___ ND ___ ___ ___ ND 11/17/95 -- --- ND -- -- -- ND --- -- 05/23/96 ___ ___ ND ___ ___ ___ ND 11/14/96 --- --- ND --- -- -- ND --- -- 06/18/97 ___ ___ ND ___ ___ ___ ND 12/02/97 --- --- ND --- --- __ ND --- __ 05/27/98 ___ ___ ND ___ ___ ___ ND 11/16/98 --- --- ND --- --- -- ND --- -- 09/10/99 --- --- ND ND ND ND --- --- --- 11/16/99 --- --- ND ND ND ND --- --- -- 05/10/00 --- --- ND ND ND ND --- --- --- 10/26/00 -- -- ND ND ND ND -- --- -- 04/18/01 --- --- ND ND ND ND --- --- --- 10/27/01 -- -- ND ND ND ND -- --- -- 06/10/02 --- --- ND ND ND ND --- --- --- 06/13/02 --- --- ND ND ND ND --- --- -- 11/19/02 --- --- ND ND ND ND --- --- --- 06/27/03 --- --- ND ND 7 ND --- --- -- 12/30/03 --- --- ND ND 12 ND --- --- --- 06/30/04 --- --- ND ND ND ND --- --- -- 12/29/04 --- --- ND ND ND ND --- --- --- 06/29/05 --- --- ND ND ND ND --- --- -- 12/29/05 --- --- ND ND ND ND --- --- --- 06/28/06 --- --- ND ND ND ND -- --- -- 12/28/06 --- --- ND ND ND ND --- --- --- 07/12/07 --- --- ND ND ND 0.4 1 --- --- -- 12/19/07 --- --- ND ND ND 0.53 1 --- --- --- 07/08/08 --- --- ND ND ND 0.59 1 --- --- -- 12/16/08 0.25 --- ND ND ND 0.4 1 --- --- --- 07/08/09 0.25 --- ND ND ND 0.54 1 --- --- -- 12/15/09 0.25 --- ND ND ND 0.37 1 --- --- --- 06/23/10 0.25 --- ND ND ND 0.42 1 --- --- -- 12/14/10 0.25 --- ND ND ND ND --- --- --- 06/21/11 0.25 ND ND ND ND 0.39 1 --- --- -- 12/06/11 0.25 ND ND ND ND 0.4 1 --- --- --- 06/13/12 0.25 ND ND ND ND ND --- --- --- 12/12/12 0.25 ND ND ND ND 0.41 1 --- --- --- 04/29/13 0.25 ND ND ND ND 0.33 1 --- --- -- O8/06/13 0.25 ND ND ND ND 0.4 1 --- --- --- 02/25/14 0.25 ND ND ND ND 0.4 1 --- --- -- O8/13/14 0.25 ND ND ND ND 0.41 1 --- --- --- 03/12/15 0.25 ND ND ND ND ND --- --- -- O8/19/15 0.25 ND ND ND ND 0.35 1 --- --- --- 02/18/16 0.25 ND ND ND ND ND --- --- -- 08/11/16 0.25 ND ND ND ND 0.34 1 --- --- --- 02/15/17 0.25 ND ND ND ND ND --- --- -- 08/24/17 0.25 ND ND ND ND 0.3 1 --- --- --- 02/07/18 0.25 ND ND ND ND 0.31 1 --- --- -- 08/16/18 0.25 ND ND ND ND 0.35 1 --- --- --- 02/06/19 0.15 ND ND ND ND 0.43 1 --- --- -- 08/07/19 0.15 ND ND ND ND 0.36 1 --- --- --- 02/14/20 0.15 ND ND ND ND ND --- --- -- 08/25/20 0.15 ND ND ND ND ND --- --- --- 02/30/21 1.9 ND ND --- ND ND ND --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 "' 0.34 <3.0 <3.0 <3.0 <1.0 0.35 J <1.0 NA NS Benzo(g,h,i)perylene 06/21/11 0.79 ND ND ND ND 1.1 --- --- --- 12/06/11 --- --- --- --- --- NC2L=200 µg/L 06/13/12 0.38 ND ND ND ND ND --- --- --- 12/12/12 --- --- --- --- --- 04/29/13 0.38 ND ND ND ND ND --- --- --- 08/06/13 --- --- --- --- --- 02/25/14 0.38 ND ND ND ND ND --- --- --- 08/13/14 --- --- --- --- 03/12/15 0.45 ND --- --- --- ND --- --- --- 02/18/16 0.38 ND -- --- --- ND -- -- -- 08/11/16 0.38 --- --- --- --- --- --- 02/15/17 0.38 ND -- --- --- ND --- --- -- 08/24/17 2.1 ND --- --- --- ND --- --- --- 02/07/18 2.1 ND -- --- --- ND -- --- -- 02/06/19 1.8 ND --- --- --- ND --- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 221'1 NA NA NA NA NA NA NA NA NS Beta-BHC 06/27/03 --- -- ND 0.068 ND ND --- --- -- 12/30/03 --- --- ND ND ND ND --- --- --- NC2L=0.02 µg/L 06/30/04 --- --- ND ND ND ND --- --- -- 12/29/04 --- --- ND ND ND ND --- --- --- 06/29/05 --- --- ND ND ND ND -- --- -- 12/29/05 --- --- ND ND ND ND --- --- --- 06/28/06 --- --- ND ND ND ND -- --- -- 12/28/06 --- --- --- --- --- ___ ___ ___ ___ 07/12/07 --- --- ND ND ND ND --- --- -- 12/19/07 --- --- ND ND ND ND --- --- --- 07/08/08 --- --- ND ND ND ND --- --- -- 12/16/08 0.05 --- ND ND ND ND --- --- --- 07/08/09 0.05 --- ND ND ND ND --- --- -- 12/15/09 0.01 --- ND ND ND ND --- --- --- 06/23/10 0.00053 --- ND ND ND ND --- --- -- 12/14/10 0.0005 --- ND ND ND ND --- --- --- 06/21/11 0.0005 ND ND ND ND ND --- --- -- 12/06/11 0.05 ND ND ND ND 0.059 --- --- --- Resample 01/25/12 0.05 ND --- --- --- 0.082 -- --- -- 06/13/12 0.05 ND ND ND ND ND --- --- --- 12/12/12 0.05 ND ND ND ND 0.078 -- --- -- 04/29/13 0.05 ND ND ND ND ND --- --- --- 08/06/13 0.05 ND ND ND ND ND --- --- -- 02/25/14 0.05 ND ND ND ND 0.056 --- --- --- 08/13/14 0.05 ND --- --- --- ND --- 03/12/15 0.05 ND --- --- --- ND --- --- --- 08/19/15 0.05 ND -- --- --- ND -- --- -- 02/18/16 0.05 ND --- --- --- ND --- --- --- 08/11/16 0.05 ND -- --- --- ND --- --- -- 02/15/17 0.05 ND --- --- --- ND --- --- --- 02/07/18 0.053 ND -- --- --- ND -- --- -- 02/06/19 0.05 ND --- --- --- ND --- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 0.014 ND -- --- --- 0.066 -- -- -- Resample 09/29/20 0.014 --- --- --- --- ND --- --- --- 02/10/21 NA NA NA NA NA NA NA NA NA O8/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 ") NA NA NA NA NA NA NA NA NS Appendix D (Page 15 of 23) s snare 1Pros«.1--1-,cMwwco.o,ra,a 11 wn „zoo s«o.a urn, a.>m 1.- Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date MDL MVI-7 MVI-2 MW-3RR' MWAR MW-511 MVI-611 NES-2S NES-2D Bis(2-ethylhexyl)phthaIate 06/21/11 0.79 NO 2.5 1 NO 4.5 NO 12/06/11 --- --- --- --- --- --- --- --- --- NC 2L 3 jAg/L 06/13/12 0.79 NO NO NO NO NO 12/12/12 --- --- --- --- --- --- --- --- --- 04/29/13 0.79 NO NO NO NO NO 08/06/13 --- --- --- --- --- --- --- --- --- 02/25/14 0.79 NO NO 40.4 5 NO Resample 04/15/14 0.79 NO --- --- --- --- --- 08/13/14 ... --- ... --- --- --- --- --- --- 03/12/15 0.49 NO NO 02/18/16 0.85 NO NO 08/11/16 0.85 --- --- --- --- --- --- --- --- 02/15/17 0.85 NO NO 08/24/17 2.3 NO NO 02/07/18 2.3 NO NO 02/06/19 1.4 NO NO 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22 (') . NA NA NA NA NA NA NA NA NS Carbon Disulfide 06/18/97 NO 16 12/02/97 NO 23 NC 2L 700 jAg/L 05/27/98 NO 46 11/16/98 NO 33.5 09/10/99 NO NO NO NO 11/16/99 NO ND NO NO 05/10/00 NO NO NO ND 10/26/00 NO ND NO NO 04/18/01 NO NO NO NO 10/27/01 NO ND NO NO 06/13/02 NO NO NO NO 11/19/02 NO NO NO ND 06/27/03 NO NO NO NO 12/30/03 NO NO NO NO 06/30/04 NO NO NO NO 12/29/04 NO NO NO NO 06/29/05 NO NO NO NO 12/29/05 NO NO NO NO 06/28/06 NO NO NO NO 12/28/06 NO NO NO NO 07/12/07 NO NO NO NO 12/19/07 NO NO NO NO 07/08/08 NO NO NO NO 12/16/08 1.2 NO NO NO NO 07/08/09 1.2 NO NO NO NO 12/15/09 1.2 NO ND NO NO 06/23/10 1.2 NO NO NO ND 12/14/10 1.2 NO ND NO NO 06/21/11 1.2 NO NO NO NO NO 12/06/11 1.2 NO NO NO NO ND 06/13/12 1.2 NO NO NO NO NO 12/12/12 1.2 NO NO NO NO NO 04/29/13 1.2 NO NO NO NO NO 08/06/13 1.2 NO NO NO NO NO 02/25/14 1.2 NO NO NO NO NO 08/13/14 1.2 NO NO NO NO NO 03/12/15 1.2 NO NO NO NO NO 08/19/15 1.2 NO ND NO NO NO 02/18/16 1.2 NO NO NO NO NO 08/11/16 1.2 NO ND NO ND NO 02/15/17 1.2 NO NO NO NO NO 08/24/17 1.2 NO NO NO NO NO 02/07/18 1.2 NO NO NO NO NO 08/16/18 1.2 NO NO NO ND NO 02/06/19 0.4 NO NO NO ND NO 08/07/19 0.4 NO NO NO NO NO 02/14/20 0.4 NO NO NO NO NO 08/25/20 0.4 NO NO NO NO NO 02/10/21 0.24 NO NO NO NO NO 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22 (') 0.36 2.0 <2.0 <2.0 <2.0 <2.0 <2.0 NA NS Chloride 06/23/10 5000 NO 37400 40000 39700 12/14/10 5000 5100 38400 44500 39600 NC 2L 250,000 Vg/L 06/21/11 5000 8600 NO 35800 45300 41400 12/06/11 5000 9340 NO 28600 49200 39200 06/13/12 1000 9410 4540 29400 49300 46400 12/11/12 1000 8570 5220 30800 50600 46600 04/29/13 1000 9550 4120 30000 49800 22300 08/06/13 1000 7590 5180 25700 50100 48700 02/25/14 1000 9140 5510 33200 60300 57400 08/13/14 500 8030 4070 21300 97600 43400 03/12/15 500 8840 4350 20700 51700 42600 08/19/15 500 9440 5160 23200 51500 48500 02/18/16 500 17200 4600 20600 69500 49700 08/11/16 500 9410 4430 23200 57300 51300 02/15/17 2500 10900 4970 29300 59100 49200 1,F 08/24/17 500 10500 4120 21700 59300 50300 02/07/18 500 10000 4790 23000 60200 58600 08/15/18 Soo 9620 --- --- --- --- --- --- --- 02/06/19 500 10300 5030 22300 64600 57800 08/08/19 2500 10100 7030 20400 66500 MI 54400 02/14/20 500 9070 4490 17200 62300 47700 08/25/20 9570 16400 19000 67100 47000 160000 02/10/21 10400 45800 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 2500 3980 14600 147000 02/16/22 3000 69200 --- --- ... --- 02/17/22 600 8600 43600 9700 5000 09/29/22 (') , 600 , 7600 2500 41700 69400 52300 166000 10400 NS Appendix D (Page 16 of 23) 0­1 1 roJ-G-ft& C., - LF U.it I � S...d Wit 1 1.- 1.- Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analy[e Sample Date MDL MW-7 MW-2 MW-3RRz MW-411 MW-511 MW-611 NES-2S NES-21) Chlorobenzene 11/16/98 -- -- ND -- -- -- ND -- -- 09/10/99 --- --- ND ND ND ND --- --- --- NC2L=50 µg/L 11/16/99 -- -- ND ND ND ND --- --- -- 05/10/00 --- --- ND ND ND ND --- --- --- 10/26/00 -- --- ND ND ND ND -- --- -- 04/18/01 --- --- ND ND ND ND --- --- --- 10/27/01 -- --- ND ND ND ND -- --- -- 06/13/02 --- --- ND ND ND ND --- --- --- 11/19/02 -- --- ND ND ND ND --- --- -- 06/27/03 --- --- ND ND ND ND --- --- --- 12/30/03 -- --- ND ND ND ND -- --- -- 06/30/04 --- --- ND ND ND ND --- --- --- 12/29/04 --- -- ND ND ND ND --- --- -- 06/29/05 --- --- ND ND ND ND --- --- --- 12/29/05 --- -- ND ND ND ND -- --- -- 06/28/06 --- --- ND ND ND ND --- --- --- 12/28/06 --- --- ND ND ND ND --- --- -- 07/12/07 --- --- ND ND ND 0.34 1 --- --- --- 12/19/07 --- --- ND 0.64 1 ND 0.44 1 --- --- -- 07/08/08 --- --- ND ND ND 0.97 1 --- --- --- 12/16/08 0.23 --- ND ND ND 0.42 1 --- --- -- 07/08/09 0.23 --- ND 0.25 1 ND 0.57 1 --- --- --- 12/15/09 0.23 --- ND 0.25 1 ND 0.49 1 --- --- -- 06/23/10 0.23 --- ND 0.26 1 ND 0.53 1 --- --- --- 12/14/10 0.23 --- ND ND ND 0.93 B --- --- -- 06/21/11 0.23 ND ND 0.27 1 ND 0.65 1 --- --- --- 12/06/11 0.23 ND ND ND ND 0.63 1 --- --- -- 06/13/12 0.23 ND ND ND ND 0.55 1 --- --- --- 12/12/12 0.23 ND ND ND ND 1 1 --- --- -- 04/29/13 0.23 ND ND ND ND 0.7 1 --- --- --- 08/06/13 0.23 ND ND ND ND 0.83 1 --- --- -- 02/25/14 0.23 ND ND ND ND 0.78 1 --- --- --- 08/13/14 0.23 ND ND ND ND 0.87 1 --- --- -- 03/12/15 0.23 ND ND ND ND 0.64 1 --- --- --- 08/19/15 0.23 ND ND ND ND 0.89 1 --- --- -- 02/18/16 0.23 ND ND ND ND 0.79 1 --- --- --- 08/11/16 0.23 ND ND ND ND 0.96 1 --- --- -- 02/15/17 0.23 ND ND ND ND 0.9 1 --- --- --- 08/24/17 0.23 ND ND ND ND 0.78 1 --- --- -- 02/07/18 0.23 ND ND ND ND 0.91 1 --- --- --- 08/16/18 0.23 ND ND ND ND 1.1 1 --- --- -- 02/06/19 0.23 ND ND ND ND 1.3 --- --- --- 08/07/19 0.23 ND ND ND ND ND --- --- -- 02/14/20 0.23 ND ND ND ND ND --- --- --- 08/25/20 0.23 ND ND ND ND 1.1 --- --- -- 02/10/21 0.29 ND ND --- ND ND ND --- --- 08/18/21 0.28 --- --- --- --- 0.9 1 --- --- -- 02/17/22 0.28 --- --- --- --- 1.2 --- --- --- 09 29 22 "' 0.28 <1.0 I <1.0 0.51 1 <1.0 1 1.9 <1.0 I NA NS Chloroethane 09/14/94 --- --- ND --- --- --- ND --- -- 12/02/94 ___ ___ ND ___ ___ ___ ND NC 2L=3,000 µg/L 02/08/95 --- --- ND --- --- --- 35 --- -- 03/02/95 ___ ___ ND ___ ___ ___ 24 11/17/95 --- --- ND --- --- __ 27 --- __ 05/23/96 ___ ___ ND ___ ___ ___ 56 11/14/96 --- --- ND --- --- -- ND --- -- 06/18/97 ___ ___ ND ___ ___ ___ 63 12/02/97 --- --- ND --- --- --- 64 --- __ 05/27/98 ___ ___ ND ___ ___ ___ 78 11/16/98 -- -- ND --- --- -- 36.2 --- -- 09/10/99 --- --- ND ND ND ND --- --- --- 11/16/99 -- -- ND ND ND ND --- --- -- 05/10/00 --- --- ND ND ND ND --- --- --- 10/26/00 -- -- ND ND ND ND --- --- -- 04/18/01 --- --- ND ND ND ND --- --- --- 10/27/01 -- -- ND ND ND ND -- --- -- 06/13/02 --- --- ND ND ND ND --- --- --- 11/19/02 --- --- ND ND ND ND --- --- -- 06/27/03 --- --- ND ND ND ND --- --- --- 12/30/03 --- --- ND ND ND ND -- --- -- 06/30/04 --- --- ND ND ND ND --- --- --- 12/29/04 --- --- ND ND ND ND --- --- -- 06/29/05 --- --- ND ND ND ND --- --- --- 12/29/05 --- --- ND ND ND ND --- --- -- 06/28/06 --- --- ND ND ND ND --- --- --- 12/28/06 --- --- ND ND ND ND -- --- -- 07/12/07 --- --- ND ND ND ND --- --- --- 12/19/07 --- --- ND ND ND ND --- --- - 07/08/08 --- --- ND ND ND ND --- --- --- 12/16/08 0.54 --- ND ND ND ND -- --- -- 07/08/09 0.54 --- ND ND ND ND --- --- --- 12/15/09 0.54 --- ND ND ND ND --- --- -- 06/23/10 0.54 --- ND ND ND ND --- --- --- 12/14/10 0.54 --- ND ND ND ND -- --- -- 06/21/11 0.54 ND ND ND ND ND --- --- --- 12/06/11 0.54 ND ND ND ND ND -- --- -- 06/13/12 0.54 ND ND ND ND ND --- --- --- 12/12/12 0.54 ND ND ND ND ND -- --- -- 04/29/13 0.54 ND ND ND ND ND --- --- --- 08/06/13 0.54 ND ND ND ND ND -- --- -- 02/25/14 0.54 ND ND ND ND ND --- --- --- 08/13/14 0.54 ND ND ND ND ND --- --- -- 03/12/15 0.54 ND ND ND ND ND --- --- --- 08/19/15 0.54 ND ND ND ND ND -- --- -- 02/18/16 0.54 ND ND ND ND ND --- --- --- 08/11/16 0.54 ND ND ND ND ND --- --- -- 02/15/17 0.54 ND ND ND ND ND --- --- --- 08/24/17 0.54 ND ND ND ND ND -- --- -- 02/07/18 0.54 ND ND ND ND ND --- --- --- 08/16/18 0.54 ND ND ND ND ND --- --- -- 02/06/19 0.49 ND ND ND ND 0.54 1 --- --- --- 08/07/19 0.49 ND ND ND ND ND --- --- -- 02/14/20 0.49 ND ND ND ND ND --- --- --- 08/25/20 0.49 ND ND ND ND ND ND --- -- 02/10/21 0.3 ND ND --- ND ND --- --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 "' 0.65 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA NS Chloromethane 06/23/10 0.11 --- ND 0.12 1 ND ND --- --- -- 12/14/10 0.11 --- ND ND ND ND --- --- --- NC2L=3 µg/L 06/21/11 0.11 ND ND ND ND ND --- --- -- 12/06/11 0.11 ND ND ND ND ND --- --- --- 06/13/12 0.11 ND ND ND ND ND -- --- -- 12/12/12 0.11 ND ND ND ND ND --- --- --- 04/29/13 0.11 ND ND ND ND ND -- --- -- 08/06/13 0.11 ND ND ND ND ND --- --- --- 02/25/14 0.11 ND ND ND ND ND --- --- -- 08/13/14 0.11 ND ND ND ND ND --- --- --- 03/12/15 0.11 ND ND ND ND ND -- --- -- 08/19/15 0.11 ND ND ND ND ND --- --- --- 02/18/16 0.11 ND ND ND ND ND --- --- -- 08/11/16 0.11 ND ND ND ND 0.12 1 --- --- --- 02/15/17 0.11 ND ND ND ND ND -- --- -- 08/24/17 0.11 ND ND ND ND ND --- --- --- 02/07/18 0.11 ND ND ND ND ND -- --- -- 08/16/18 0.11 ND ND ND ND ND --- --- --- 02/06/19 0.39 ND ND ND ND ND -- --- -- O8/07/19 0.39 ND ND ND ND ND --- --- --- 02/14/20 0.39 ND ND ND ND ND --- --- -- O8/25/20 0.39 ND ND ND ND ND --- --- --- 02/10/21 0.31 ND ND ND ND ND -- --- -- O8/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 092g 22 I 0.54 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA NS Appendix D (Page 17 of 23) �np>,madn�<k.snare 11ros« G-ft&Q-111a co.o,ra,d Lr wn„�s«d.d 1.11G11 ,m.vomaa Wit 1.>m 1.- Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-511 MW-611 NES-2S NES-21) cis-1,2-Dichloroethene 09/14/94 -- -- ND -- -- -- ND -- -- 12/02/94 ___ ___ ND ___ ___ ___ ND NC 2L=70 µB/L 02/08/95 -- --- ND -- -- -- ND --- -- 03/02/95 ___ ___ ND ___ ___ ___ ND 11/17/95 -- --- ND -- -- -- ND --- -- 05/23/96 ___ ___ ND ___ ___ ___ ND 11/14/96 --- --- ND --- --- -- ND --- -- 06/18/97 ___ ___ ND ___ ___ ___ ND 12/02/97 --- --- ND --- --- __ ND --- -_ 05/27/98 ___ ___ ND ___ ___ ___ 5.8 11/16/98 -- -- ND --- --- --- 3.7 --- -- 09/10/99 --- --- ND ND ND ND --- --- --- 11/16/99 -- -- ND ND ND 7 --- --- -- 12/16/99 _.. ___ ___ ___ ___ 7 05/10/00 -- -- ND ND ND 8 -- --- -- 10/26/00 --- --- ND ND ND 9 --- --- --- 04/18/01 --- --- ND ND ND 7 -- --- -- 10/27/01 --- --- ND ND ND 13 --- --- --- 06/10/02 --- --- ND ND ND 8 -- --- -- 06/13/02 --- --- ND ND ND 8 --- --- --- 11/19/02 --- --- ND ND ND ND --- --- -- 06/27/03 --- --- ND ND ND 12 --- --- --- 12/30/03 --- --- ND ND ND 10 --- --- -- 06/30/04 --- --- ND ND ND 9.3 --- --- --- 12/29/04 --- --- ND ND ND 9.4 --- --- -- 06/29/05 --- --- ND ND ND 8 --- --- --- 12/29/05 --- --- ND ND ND 8 -- --- -- 06/28/06 --- --- ND ND ND 8.8 --- --- --- 12/28/06 --- --- ND ND ND 6 --- --- -- 07/12/07 --- --- ND ND ND 6.2 --- --- --- 12/19/07 --- --- ND ND ND 7.2 -- --- -- 07/08/08 --- --- ND ND ND 9.9 --- --- --- 12/16/08 1.9 --- ND ND 0.91 4.2 1 --- --- -- 07/08/09 0.19 --- ND ND ND 7.7 --- --- --- 12/15/09 0.19 --- ND ND ND 7.4 -- --- -- 06/23/10 0.19 --- ND ND ND 7.1 --- --- --- 12/14/10 0.19 --- ND ND ND ND -- --- -- 06/21/11 0.19 ND ND ND ND 6.4 --- --- --- 12/06/11 0.19 ND ND ND ND 3 1 --- --- -- 06/13/12 0.19 ND ND ND ND 4.3 1 --- --- --- 12/12/12 0.19 ND ND ND ND 3.3 1 --- --- -- 04/29/13 0.19 ND ND ND ND 4.8 1 --- --- --- 08/06/13 0.19 ND ND ND ND 3.6 1 --- --- -- 02/25/14 0.19 ND ND ND ND 3.7 1 --- --- --- 08/13/14 0.19 ND ND ND ND 2.8 1 --- --- -- 03/12/15 0.19 ND ND ND ND 2.6 1 --- --- --- 08/19/15 0.19 ND ND ND ND 3.1 1 --- --- -- 02/18/16 0.19 ND ND ND ND 2.5 1 --- --- --- 08/11/16 0.19 ND ND ND ND 2.7 1 --- --- -- 02/15/17 0.19 ND ND ND ND ND --- --- --- 08/24/17 0.19 ND ND ND ND 1.4 1 --- --- -- 02/07/18 0.19 ND ND ND ND 0.79 1 --- --- --- 08/16/18 0.19 ND ND ND ND 1.2 1 --- --- -- 02/06/19 0.29 ND ND ND ND 0.79 1 --- --- --- 08/07/19 0.29 ND ND ND ND 0.86 1 --- --- -- 02/14/20 0.29 ND ND ND ND 0.86 1 --- --- --- 08/25/20 0.29 ND ND ND ND 0.65 1 --- --- -- 02/10/21 3.3 ND --- --- ND ND ND --- --- 08/18/21 0.38 --- --- --- --- --- 0.83 1 --- -- 02/15/22 0.38 --- --- --- --- --- 0.82 1 --- --- 09 29 22 "' 0.38 <1.0 <1.0 <1.0 <1.0 1.9 0.97 J NA NS Dibem(a,h)anthracene 06/21/11 0.79 ND ND ND ND 1.2 1 --- --- -- 12/06/11 --- --- --- --- --- ___ ___ ___ --- NC 2L 0.005 µB/L 06/13/12 0.55 ND ND ND ND ND -- --- -- 12/12/12 --- --- --- --- --- ___ ___ ___ ___ 04/29/13 0.55 ND ND ND ND ND -- --- -- 08/06/13 --- --- --- --- --- ___ ___ ___ ___ 02/25/14 0.55 ND ND ND ND ND -- --- -- 08/13/14 --- --- --- --- --- ___ ___ ___ ___ 03/12/15 0.49 ND -- --- --- ND --- --- -- 02/18/16 0.55 ND --- --- --- ND --- --- --- 08/11/16 0.55 --- -- --- -- -- --- --- 02/15/17 0.55 ND --- --- --- ND --- --- --- 08/24/17 2 ND -- --- -- ND -- --- -- 02/07/18 2.1 ND --- --- --- ND --- --- --- 02/06/19 1.9 ND -- --- -- ND --- -- -- O8/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 i'i NA NA NA NA NA NA NA NA NS Dichlorodifluoromethane 11/17/95 --- --- ND --- --- --- ND --- --- 12/02/97 --- --- ND --- --- -_ ND --- __ NC 2L=1,000 µg/L 03/23/98 --- --- ND --- --- --- 6 --- --- 05/27/98 --- --- ND --- --- --- ND --- __ 11/16/98 ___ ___ ND ___ ___ ___ ND 09/10/99 --- --- ND ND ND ND --- --- -- 11/16/99 --- --- ND ND ND ND --- --- --- 05/30/00 --- --- ND ND ND ND -- --- -- 10/26/00 --- --- ND ND ND ND --- --- --- 04/18/01 --- --- ND ND ND ND -- --- -- 06/13/02 --- --- ND ND ND ND --- --- --- 06/27/03 --- --- ND ND ND ND --- --- -- 12/30/03 --- --- --- --- --- ___ ___ ___ ___ 06/30/04 --- --- ND ND ND ND --- --- -- 12/29/04 --- --- --- --- --- ___ ___ ___ ___ 06/29/05 --- ND ND ND ND -- --- -- 12/29/05 --- --- --- --- --- ___ ___ ___ ___ 06/28/06 --- --- ND ND ND ND -- --- -- 12/28/06 --- --- --- --- --- ___ ___ ___ ___ 07/12/07 --- --- ND ND ND ND --- --- -- 12/19/07 --- --- --- --- --- ___ ___ ___ ___ 07/08/08 --- -- ND ND ND ND -- --- -- 12/16/08 ___ ___ ND ___ ___ ___ ___ ___ ___ 07/08/09 0.21 -- ND ND ND 0.37 1 --- --- -- 12/15/09 --- --- --- --- --- ___ ___ ___ ___ 06/23/10 0.21 - ND ND ND 0.29 1 --- --- -- 12/14/10 --- --- --- --- --- ___ ___ ___ ___ 06/21/11 0.21 ND ND ND ND 0.36 1 --- --- -- 12/06/11 --- --- --- --- --- ___ ___ ___ ___ 06/13/12 0.21 ND ND ND ND ND -- --- -- 12/12/12 --- --- --- --- --- ___ ___ ___ ___ 04/29/13 0.21 ND ND ND ND ND -- --- -- 08/06/13 --- --- --- --- --- ___ ___ ___ ___ 02/25/14 0.21 ND ND ND ND ND -- --- -- 08/13/14 --- --- --- --- --- ___ ___ ___ ___ 03/12/15 0.21 ND --- --- --- ND --- --- -- 02/18/16 0.21 ND --- --- --- ND --- --- --- 08/11/16 0.21 --- --- --- -- -- 02/15/17 0.21 ND --- --- --- ND --- --- --- 08/24/17 0.21 ND --- --- -- ND -- --- -- 02/07/18 0.21 ND --- --- --- ND --- --- --- 02/06/19 0.23 ND ND ND ND ND -- -- -- O8/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA O8/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 0.21 ND --- --- -- -- O8/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 092g 22 i'i NA NA NA NA NA NA NA NA NS Appendix D (Page 18 of 23) �np>,madn�<k.snereo«���dmn�revMa.,.��a.,,s�and o«�m.nwaa.Mes Pros« G-ftQ-111a co.o,ra,d LF unit„�s«dnd 1.11G11 ,m- unit, a.>m 1.- Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-4R MW-5R MW-6R NES-2S NES-2D Dieldfin 11/17/95 -- -- ND -- -- -- ND -- -- 12/02/97 ___ ___ ND ___ ___ ___ ND NC 2L=0.002 µg/L 03/23/98 -- -- ND -- -- -- ND --- -- 05/27/98 ___ ___ ND ___ ___ ___ ND 11/16/98 -- -- ND --- --- -- ND --- -- 09/10/99 --- --- ND ND ND ND --- --- --- 11/16/99 --- --- ND ND ND ND --- --- -- 05/10/00 --- --- ND ND ND ND --- --- --- 10/26/00 -- --- ND ND ND ND --- --- -- 04/18/01 --- --- ND ND ND ND --- --- --- 06/13/02 --- --- ND ND ND ND -- --- -- 06/27/03 --- --- ND ND ND ND --- --- --- 12/30/03 --- -- --- -- 06/30/04 --- --- ND ND ND ND --- --- --- 12/29/04 -- --- --- -- 06/29/05 --- --- ND ND ND ND --- --- --- 12/29/05 --- --- --- --- --- 06/28/06 --- --- ND ND ND ND --- --- --- 12/28/06 --- --- -- 07/12/07 --- --- ND ND ND ND --- --- --- 12/19/07 --- --- --- --- --- 07/08/08 --- --- ND ND ND ND --- --- --- 12/16/08 --- --- -- 07/08/09 0.05 --- ND ND ND ND --- --- --- 12/15/09 -- --- --- -- 06/23/10 0.00053 --- ND ND ND ND --- --- --- 12/14/10 --- --- _- --- --- 06/21/11 0.0005 ND ND ND ND ND --- --- --- 12/06/11 --- --- - --- --- 06/13/12 0.05 ND ND ND ND ND --- --- --- 12/12/12 --- --- _- --- --- ND 04/29/13 0.05 ND ND ND ND ND --- --- --- 08/06/13 --- --- _- ... --- ND --- --- __ 02/25/14 0.05 ND ND ND ND ND --- --- --- 08/13/14 --- --- _- --- --- 03/12/15 0.05 ND --- --- --- ND --- --- --- 02/18/16 0.05 ND -- --- --- ND --- --- -- O8/11/16 0.05 --- --- --- --- --- --- 02/15/17 0.05 ND -- --- -- ND -- --- -- 02/07/18 0.053 ND --- --- --- ND --- --- --- 02/06/19 0.05 ND -- --- --- ND 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA O8/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 (u NA NA NA NA NA NA NA NA NS Diethyl phth a late 11/17/95 --- --- ND --- --- --- ND --- --- 12/02/97 --- --- ND --- --- __ ND NC 2L=6,000 µg/L 03/23/98 --- --- ND --- --- --- ND --- --- 05/27/98 --- --- ND --- --- --- ND --- __ 11/16/98 ___ ___ ND ___ ___ ___ ND 09/10/99 --- --- ND ND ND ND --- --- -- 11/16/99 --- --- ND ND ND ND --- --- --- 05/10/00 --- --- ND ND ND ND -- --- -- 10/26/00 --- --- ND ND ND ND --- --- --- 04/18/01 --- --- ND ND ND ND -- --- -- 06/13/02 --- --- ND ND ND ND --- --- --- 06/27/03 --- --- ND ND ND ND -- --- -- 12/30/03 --- --- --- --- --- ___ ___ ___ ___ 06/30/04 --- --- ND ND ND ND --- --- -- 12/29/04 --- --- --- --- --- ___ ___ ___ ___ 06/29/05 --- --- ND ND ND ND --- --- -- 06/28/06 --- --- ND ND ND ND --- --- --- 12/28/06 --- --- -- 07/12/07 --- --- ND ND ND ND --- --- --- 12/19/07 -- --- -- 07/08/08 --- --- ND ND ND ND --- --- --- 12/16/08 --- --- -- 07/08/09 2.7 --- --- ND ND ND --- --- --- 12/15/09 -- --- -- 06/23/10 3.9 --- ND ND ND ND --- --- --- 12/14/10 --- --- -- --- --- 06/21/11 0.58 ND ND ND ND ND --- --- --- 12/06/11 --- --- --- --- --- 06/13/12 0.58 ND ND ND ND ND --- --- --- 12/12/12 --- --- --- --- --- 04/29/13 0.58 ND ND ND ND ND --- --- --- 08/06/13 --- --- --- --- --- 02/25/14 0.58 ND ND ND ND ND --- --- --- 08/13/14 --- --- --- --- --- 03/12/15 0.91 ND --- --- --- ND --- --- --- 02/18/16 1.3 ND -- --- -- ND --- --- -- 08/11/16 1.3 --- --- --- --- --- --- 02/15/17 1.3 ND -- --- -- ND -- --- -- 08/24/17 1.6 ND --- --- --- ND --- --- --- 02/07/18 1.7 ND -- --- -- ND -- --- -- 02/06/19 2 ND --- --- --- ND --- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 "' NA NA NA NA NA NA NA NA NS Endosulfan 1 06/21/11 0.0007 ND ND 0.52 ND ND --- --- -- Resample 07/28/11 0.0007 --- --- ND --- --- --- --- --- NC2L=40 µg/L 12/06/11 --- --- --- ND --- -- -- --- -- 06/13/12 0.05 ND ND 0.33 ND ND --- --- --- 12/12/12 0.05 ND ND 1.33 ND ND -- --- -- 04/29/13 0.05 ND ND ND ND ND --- --- --- 08/06/13 0.05 ND ND ND ND ND -- --- -- 02/25/14 0.05 ND ND ND ND ND --- --- --- 08/13/14 0.05 ND --- --- -- ND --- --- -- 03/12/15 0.05 ND --- --- --- ND --- --- --- 08/19/15 0.05 ND -- --- -- ND -- --- -- 02/18/16 0.05 ND --- --- --- ND --- --- --- 08/11/16 0.05 ND -- --- -- ND --- --- -- 02/15/17 0.05 ND --- --- --- ND --- --- --- 02/07/18 0.053 ND -- --- --- ND 02/06/19 0.05 ND --- --- --- ND --- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA O8/25/20 0.0094 ND --- --- --- 0.036 J --- --- -- 02/10/21 NA NA NA NA NA NA NA NA NA O8/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 "' NA NA NA NA NA NA NA NA NS Endosulfan Sulfate 06/13/12 0.05 ND ND 0.09 1 ND ND --- --- -- 12/12/12 ___ ___ ___ ND ___ ___ ___ --- NC 2L=40 Pei- 04/29/13 0.05 ND ND ND ND ND --- --- -- 08/06/13 ___ ___ ___ ___ ___ ND 02/25/14 0.05 ND ND ND ND ND -- --- -- 08/13/14 --- --- --- 03/12/15 0.05 ND --- --- ND --- 02/18/16 0.05 ND --- --- --- ND --- --- --- 08/11/16 0.05 --- -- --- -- --- -- --- 02/15/17 0.05 ND --- --- --- ND --- --- --- 02/07/18 0.053 ND -- --- --- ND --- --- -- 02/06/19 0.05 ND --- --- --- ND --- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 "' NA NA NA NA NA NA NA NA NS Appendix D (Page 19 of 23) sns>,m>nn<k.>n>�>o«�n=omn�revM»,.n,�>.,,ss>na c«>m.nwaa.M»repPros«.,,c>mna Moo�.,cMww-c�nN��a co.o,ra,a �F wn „�o�s«ona am,cwMn>n�.>,o aunn, H�>mn>.>a» Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analy[e Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-5R MW-611 NES-2S NES-21) Heptachlor 11/17/95 -- -- ND -- -- -- ND -- -- 12/02/97 ___ ___ ND ___ ___ ___ ND NC 2L=0.008 µg/L 03/23/98 -- --- ND -- -- -- ND --- -- 05/27/98 ___ ___ ND ___ ___ ___ ND 11/16/98 -- --- ND --- --- -- ND --- -- 09/10/99 --- --- ND ND ND ND --- --- --- 11/16/99 --- --- ND ND ND ND --- --- -- 05/10/00 --- --- ND ND ND ND --- --- --- 10/26/00 --- --- ND ND ND ND -- --- -- 04/18/01 --- --- ND ND ND ND --- --- --- 06/13/02 --- --- ND ND ND ND -- --- -- 06/27/03 --- --- ND ND ND ND --- --- --- 12/30/03 -- --- -- 06/30/04 --- --- ND ND ND ND --- --- --- 12/29/04 --- --- --- --- --- 06/29/05 --- --- ND ND ND ND --- --- --- 12/29/05 -- --- -- 06/28/06 --- --- ND ND ND ND --- --- --- 12/28/06 --- -- ND ND ND ND --- --- -- 07/12/07 --- --- ND ND ND ND --- --- --- 12/19/07 -- --- -- 07/08/08 --- --- ND ND ND ND --- --- --- 12/16/08 --- --- -- 07/08/09 0.05 --- ND ND ND ND -- --- --- 12/15/09 --- -- -- --- --- 06/23/10 0.0016 --- ND ND ND ND --- --- --- 12/14/10 --- --- -- --- --- 06/21/11 0.0015 ND ND ND ND ND --- --- --- 12/06/11 --- --- -- --- --- 06/13/12 0.05 ND ND ND ND ND --- --- --- 12/12/12 --- --- _- ND _- -- _- --- _- 04/29/13 0.05 ND ND ND ND ND --- --- --- 08/06/13 --- -- -- --- --- ND 02/25/14 0.05 ND ND ND ND ND --- --- --- 08/13/14 --- --- -- --- --- 03/12/15 0.05 ND --- --- --- ND --- --- --- 02/18/16 0.05 ND --- --- -- ND --- --- -- 08/11/16 0.05 --- --- --- --- --- --- 02/15/17 0.05 ND -- --- -- ND -- --- -- 02/07/18 0.053 ND --- --- --- ND --- --- --- 02/06/19 0.05 ND -- --- -- ND --- --- -- O8/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA O8/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 221'1 I NA NA NA NA NA NA NA NA NS Indeno(1,2,3-cd)pyrene 06/21/11 0.79 ND ND ND ND 1.2 1 --- --- --- 12/06/11 --- --- -- --- ... NC2L=0.05 µg/L 06/13/12 0.29 ND ND ND ND ND --- --- --- 12/12/12 --- --- -- --- --- 04/29/13 0.29 ND ND ND ND ND --- --- --- 08/06/13 --- --- -- --- --- 02/25/14 0.29 ND --- ND ND ND --- --- --- 08/13/14 --- --- -- --- --- 03/12/15 0.53 ND --- --- --- ND --- --- --- 02/18/16 0.29 ND -- --- --- ND O8/11/16 0.29 --- --- --- --- --- --- 02/15/17 0.29 ND -- --- --- ND -- --- -- 08/24/17 2 ND --- --- --- ND --- --- --- 02/07/18 2.1 ND -- --- --- ND --- --- -- 02/06/19 1.7 ND --- --- --- ND --- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA 08/08/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 221'1 NA NA NA NA NA NA NA NA NS Methane 02/06/19 NA NA NA NA NA NA NA NA NA 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 3.4 --- --- --- --- 95 --- --- --- 02/10/21 3.4 ND --- --- --- 110 --- --- --- 08/18/21 NA NA NA NA NA NA NA NA NA NC 2L=NE 02/17/22 3.4 --- --- --- --- 81.6 --- 28.2 --- 09 29 22(') 2 <5.0 NA NA NA 63 NA 74 NS Methoxychlor 11/17/95 --- --- ND --- --- --- ND -- --- 12/02/97 ___ ___ ND ___ ___ ___ ND NC 2L=40 µg/L 03/23/98 --- --- ND --- --- --- ND --- -- 05/27/98 ___ ___ ND ___ ___ ___ ND 11/16/98 --- --- ND --- --- --- ND --- -- 09/10/99 --- --- ND ND ND ND --- --- --- 11/16/99 --- --- ND ND ND ND --- --- -- 05/10/00 --- --- ND ND ND ND --- --- --- 10/26/00 --- --- ND ND ND ND -- --- -- 04/18/01 --- --- ND ND ND ND --- --- --- 06/13/02 --- --- ND ND ND ND -- --- -- 12/30/03 --- --- --- --- --- ___ ___ ___ ___ 06/30/04 --- --- ND ND ND ND --- --- -- 12/29/04 --- --- --- --- --- ___ ___ ___ ___ 06/29/05 --- --- ND ND ND ND --- --- -- 12/29/05 --- --- --- --- --- ___ ___ ___ ___ 06/28/06 --- - ND ND ND ND -- --- -- 12/28/06 --- --- --- --- --- ___ ___ ___ ___ 07/12/07 --- --- ND ND ND ND -- --- -- 12/19/07 --- --- --- --- --- ___ ___ ___ ___ 07/08/08 --- --- ND ND ND ND -- --- -- 12/16/08 --- --- --- --- --- ___ ___ ___ ___ 07/08/09 0.5 --- ND ND ND ND -- --- -- 12/15/09 --- --- --- --- --- ___ ___ ___ ___ 06/23/30 0.0074 --- ND ND ND ND --- --- -- 12/14/10 --- --- --- --- --- ___ ___ ___ ___ 06/21/11 0.007 ND ND ND ND ND --- --- -- 12/06/11 --- --- --- --- --- ___ ___ ___ ___ 06/13/12 0.15 ND ND ND ND ND --- --- -- 12/12/12 ___ ___ ___ ND ___ ___ ___ ___ ___ 04/29/13 0.15 ND ND ND ND ND -- --- -- 08/06/13 ___ ___ ___ ___ ___ ND 02/25/14 0.15 ND ND ND ND ND --- --- -- 08/13/14 --- --- --- --- --- ___ ___ ___ ___ 03/12/15 0.15 ND --- --- --- ND -- --- -- 02/18/16 0.15 ND --- --- --- ND --- --- --- 08/11/16 0.15 --- -- --- --- --- 02/15/17 0.15 ND --- --- --- ND --- --- --- 02/07/18 0.16 ND -- --- -- ND -- --- -- 02/06/19 0.15 ND --- --- --- ND --- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22(') NA NA NA NA NA NA NA NA NS Appendix D (Page 20 of 23) �np>,madn�<k.snare 1Pros«.1--1-,cMwwco.o,ra,d 11 wn-s«d.d'.I'G11 ,m.vomaa Wit I.>m I.- Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-4R MW-5R MW-6R NES-2S NES-2D Methylene Chloride 09/14/94 -- -- NO -- -- -- NO -- -- 12/02/94 ___ ___ NO ___ ___ ___ NO NC 2L=5 µg/L 02/08/95 -- -- NO -- -- -- NO --- -- 03/02/95 ___ ___ NO ___ ___ ___ 6 11/17/95 -- --- NO -- -- -- NO --- -- 05/23/96 ___ ___ NO ___ ___ ___ 17 11/14/96 --- --- NO --- --- -- 8.2 --- -- 06/18/97 ___ ___ NO ___ ___ ___ 12 12/02/97 _- --- NO --- --- --- NO --- __ 05/27/98 ___ ___ NO ___ ___ ___ 15 11/16/98 -- --- NO --- --- -- NO --- -- 09/10/99 --- --- NO NO NO NO --- --- --- 11/16/99 -- --- NO NO NO NO --- --- -- 05/10/00 --- --- NO NO NO NO --- --- --- 10/26/00 --- --- NO NO NO NO -- --- -- 04/18/01 --- --- NO NO NO NO --- --- --- 10/27/01 --- --- NO NO NO NO --- --- -- 06/13/02 --- --- NO NO NO NO --- --- --- 11/19/02 --- --- NO NO NO NO --- --- -- 06/27/03 --- --- NO NO ND NO --- --- --- 12/30/03 --- --- NO NO NO NO --- --- -- 06/30/04 --- --- NO ND NO NO --- --- --- 12/29/04 --- --- NO NO NO ND -- --- -- 06/29/05 --- --- NO ND NO NO --- --- --- 12/29/05 --- --- NO NO NO NO -- --- -- 06/28/06 --- --- NO ND NO NO --- --- --- 12/28/06 --- --- NO NO NO NO --- --- -- 07/12/07 --- --- NO NO NO ND --- --- --- 12/19/07 --- --- NO NO NO NO -- --- -- 07/08/08 --- --- NO NO NO ND --- --- --- 12/16/08 0.97 --- NO NO NO NO --- --- -- 07/08/09 0.97 --- NO NO NO NO --- --- --- 12/15/09 0.97 --- NO NO NO NO -- --- -- 06/23/10 0.97 --- NO NO NO NO --- --- --- 12/14/10 0.97 --- NO NO NO NO --- --- -- 06/21/11 0.97 NO NO NO NO NO --- --- --- 12/06/11 0.97 NO NO NO NO NO -- --- -- 06/13/12 0.97 NO NO NO NO NO --- --- --- 12/12/12 0.97 NO NO NO NO NO --- --- -- 04/29/13 0.97 NO ND NO ND NO --- --- --- 08/06/13 0.97 NO NO NO NO NO -- --- -- 02/25/14 0.97 NO NO NO NO NO --- --- --- 08/13/14 0.97 NO NO NO NO NO --- --- -- 03/12/15 0.97 NO NO NO NO NO --- --- --- 08/19/15 0.97 NO NO NO NO NO -- --- -- 02/18/16 0.97 NO ND NO ND NO --- --- --- 08/11/16 0.97 NO NO NO NO NO -- --- -- 02/15/17 0.97 NO ND NO ND NO --- --- --- 08/24/17 0.97 NO ND NO NO NO -- --- -- 02/07/18 0.97 NO ND NO ND NO --- --- --- 08/16/18 0.97 NO NO NO NO NO -- --- -- 02/06/19 3.7 NO NO NO NO NO --- --- --- 08/07/19 3.7 NO NO NO NO NO --- --- -- 02/14/20 3.7 ND NO ND NO ND --- --- --- 08/25/20 3.7 NO NO NO NO NO --- --- -- 02/10/21 0.24 ND --- --- NO ND NO --- --- 08/19/21 --- --- --- --- --- __ 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 "' 2 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NA NS Naphthalene 07/08/08 --- --- NO NO NO NO -- --- -- 12/16/08 --- --- --- --- --- ___ ___ ___ --- NC 2L 6 µg/L 07/08/09 0.24 -- NO NO NO NO -- --- -- 12/15/09 --- --- --- --- --- ___ ___ ___ ___ 06/23/10 0.24 --- NO NO NO NO -- --- -- 12/14/10 --- --- --- --- --- ___ ___ ___ ___ 06/21/11 0.24 NO NO NO NO NO -- --- -- 12/06/11 --- --- --- --- --- ___ ___ ___ ___ 06/13/12 0.24 NO NO NO NO NO --- --- -- 12/12/12 --- --- --- --- --- ___ ___ ___ ___ 04/29/13 0.24 NO NO NO NO NO -- --- -- 08/06/13 --- --- --- --- --- ___ ___ ___ ___ 02/25/14 0.24 NO NO NO NO NO --- --- -- 08/13/14 --- --- --- 03/12/15 0.24 NO --- --- --- NO --- --- 02/18/16 0.24 NO --- --- --- NO --- --- --- 08/11/16 0.24 --- -- --- --- 02/15/17 0.24 NO --- --- --- NO --- --- --- 08/24/17 0.24 NO --- --- -- NO -- --- -- 02/07/18 0.24 NO --- --- --- NO --- --- --- 02/06/19 0.35 NO NO NO NO NO -- --- -- O8/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA O8/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 0.22 NO --- --- -- -- --- O8/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 ") NA NA NA NA NA NA NA NA INS Phorate 11/17/95 --- --- NO --- --- --- NO --- --- 12/02/97 --- --- NO --- --- __ NO --_ --- NC2L=1µg/L 11/16/98 --- --- NO --- --- --- NO --- --- 09/10/99 --- --- NO NO NO NO --- --- -- 05/10/00 --- --- NO 1 NO 0.8 --- --- --- 10/26/00 --- --- NO 5.2 NO NO -- --- -- 04/18/01 --- --- NO NO NO NO --- --- --- 06/13/02 --- --- NO NO NO NO -- --- -- 06/27/03 --- --- NO NO NO NO --- --- --- 12/30/03 --- --- --- --- --- --- -- --- -- 06/30/04 --- --- NO NO NO NO --- --- --- 12/29/04 --- --- --- --- --- --- -- --- -- 06/29/05 --- --- NO NO NO NO --- --- --- 12/29/05 -- --- -- 06/28/06 --- --- NO NO NO NO --- --- --- 12/28/06 --- --- -- 07/12/07 --- --- NO NO NO NO --- --- --- 12/19/07 -- --- -- 07/08/08 --- --- NO NO NO NO --- --- --- 12/16/08 --- --- -- 07/08/09 6.6 --- --- NO NO NO --- --- --- 12/15/09 -- --- -- 06/23/10 7.7 --- NO NO ND NO --- --- --- 12/14/10 --- --- _- --- --- 06/21/11 5.4 NO ND NO ND NO --- --- --- 12/06/11 --- --- --- --- --- 06/13/12 5.4 NO NO NO NO NO --- --- --- 12/12/12 --- --- --- --- --- 04/29/13 5.4 NO NO NO NO NO --- --- --- 08/06/13 --- --- --- --- --- 02/25/14 5.4 ND NO ND NO ND --- --- --- 08/13/14 --- --- --- --- --- 03/12/15 0.83 ND --- --- --- ND --- --- --- 02/18/16 1.1 NO -- --- --- NO -- --- -- 08/11/16 1.1 --- --- --- --- --- --- 02/15/17 1.1 NO -- --- --- NO -- --- -- 08/24/17 1.7 NO --- --- --- NO --- --- --- 02/07/18 1.8 NO -- --- --- NO --- --- -- 02/06/19 1.1 NO --- --- --- NO --- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22(') NA NA NA NA NA NA NA NA INS Appendix D (Page 21 of 23) �np>,madn�<k.snereo«���dmn�revMa.,.��a.,,s�and o«�m.�waa.Mes Pros« G-ftQ-111a co.o,ra,d LF wn„�s«d.d 1.11G11 ,m- Wit a.>m 1.- Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MWAR MW-SR MW-6R NES-2S NES-21) Sulfate 06/23/10 -- -- 14800 7180 9140 ND -- -- -- 12/14/10 --- --- 14500 9210 9700 ND --- --- --- NC2L=250,000 µB/L 06/21/11 --- 24400 11400 7490 7740 ND --- --- -- 12/06/11 5000 39800 13800 8000 7730 ND --- --- --- 06/13/12 2000 25400 J 13700 J 8140 J 8400 1 2790 J --- --- -- 12/11/12 2000 28000 J 14800 J 9120 J 10100 1 4420 J --- --- --- 04/29/13 2000 26100 J 12300 J 9150 J 17100 J 2730 J --- --- -- 08/06/13 2000 25300 J 7370 1 7830 J 11700 1 2760 J --- --- --- 02/25/14 2000 28900 J 11200 J 8130 J 9550 1 2590 J --- --- -- 08/13/14 1000 31900 J 9370 1 7910 J 11600 J 2450 J --- --- --- 03/12/15 1000 32600 J 12100 J 8040 J 8340 1 3400 J --- --- -- 08/19/15 10000 42900 J 10200 J 8110 J 10400 J 2890 J --- --- --- 02/18/16 2000 39300 J 11200 J 7960 J 10300 J 3830 1 --- --- -- 08/11/16 5000 112000 J 8500 1 7700 1 10300 J 3100 1 --- --- --- 02/15/17 1000 47100 J 11200 J 7860 1 7940 J 3510 1 --- --- -- 08/24/17 500 49700 1 9940 1 8310 1 9260 1 6680 1 --- --- --- 02/07/18 500 42800 J 7990 1 6650 1 6110 1 4000 1 --- --- -- 08/15/18 500 55200 J 7690 1 7130 1 6470 1 4200 1 --- --- --- 02/06/19 500 55700 12100 7360 9440 4350 -- --- -- 08/08/19 500 51500 9890 7450 7570 6710 --- --- --- 02/14/20 500 52000 8990 6370 9410 5960 -- --- - 08/25/20 500 53300 7420 6680 7850 7000 4610 --- --- 02/30/21 500 65500 --- --- -- 8500 --- --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 500 --- 8380 6760 -- -- 6150 --- --- 02/16/22 500 --- --- --- 8370 --- --- --- --- 02/17/22 500 57500 --- --- --- 8500 --- 23300 50100 09 29 22"' 1 1000 41200 1 6700 42400 23700 1 8500 8500 1 30100 NS Toluene 06/18/97 --- --- ND --- --- --- ND --- --- 12/02/97 --- --- ND --- --- __ ND --- __ NC 2L=600 µg/L 05/27/98 --- --- ND --- --- --- ND --- --- 11/16/98 --- --- ND --- --- -- ND --- -- 09/10/99 --- --- 7 ND ND ND --- --- --- 10/19/99 --- -- ND --- --- -- --- --- -- 11/16/99 --- --- ND ND ND ND --- --- --- 05/10/00 --- -- ND ND ND ND - --- -- 10/26/00 --- --- ND ND ND ND --- --- --- 04/18/01 --- -- ND ND ND ND -- --- -- 10/27/01 --- --- ND ND ND ND --- --- --- 06/13/02 --- --- ND ND ND ND -- --- -- 11/19/02 --- --- ND ND ND ND --- --- --- 06/27/03 --- ND ND ND ND --- --- -- 12/30/03 --- --- ND ND ND ND --- --- --- 06/30/04 --- ND ND ND ND -- --- -- 12/29/04 --- --- ND ND ND ND --- --- --- 06/29/05 --- --- ND ND ND ND --- --- -- 12/29/05 --- --- ND ND ND ND --- --- --- 06/28/06 --- --- ND ND ND ND -- --- -- 12/28/06 --- --- ND ND ND ND --- --- --- 07/12/07 --- --- ND ND ND ND --- --- -- 12/19/07 --- --- ND ND ND ND --- --- --- 07/08/08 --- --- ND ND ND ND --- --- -- 12/16/08 0.26 --- ND ND ND ND --- --- --- 07/08/09 0.26 --- ND ND ND ND --- --- -- 12/15/09 0.26 --- ND ND ND ND --- --- --- 06/23/10 0.26 --- ND ND ND ND --- --- -- 12/14/10 0.26 ND ND ND ND --- --- --- 06/21/11 0.26 ND ND ND ND ND -- --- -- 12/06/11 0.26 ND ND ND ND ND --- --- --- 06/13/12 0.26 ND ND ND ND ND --- --- -- 12/12/12 0.26 ND ND ND ND ND --- --- --- 04/29/13 0.26 ND ND ND ND ND --- --- -- 08/06/13 0.26 ND ND ND ND ND --- --- --- 02/25/14 0.26 ND ND ND ND ND -- --- -- 08/13/14 0.26 ND ND ND ND ND --- --- --- 03/12/15 0.26 ND ND ND ND ND --- --- -- 08/19/15 0.26 ND ND ND ND ND --- --- --- 02/18/16 0.26 ND ND ND ND ND -- --- -- 08/11/16 0.26 ND ND ND ND ND --- --- --- 02/15/17 0.26 ND ND ND ND ND --- --- -- O8/24/17 0.26 ND ND ND ND ND --- --- --- 02/07/18 0.26 ND ND ND ND ND -- --- -- O8/16/18 0.26 ND ND ND ND ND --- --- --- 02/06/19 0.24 ND ND ND ND ND --- --- -- O8/07/19 0.24 ND ND ND ND ND --- --- --- 02/14/20 0.24 ND ND ND ND ND -- --- -- 08/25/20 0.24 ND ND ND ND ND --- --- --- 02/10/21 0.26 ND --- --- ND ND ND --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 "' 0.48 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA NS Trans-1,4-Dichloro-2-Butene 05/27/98 --- --- ND --- --- --- 6.9 --- --- 11/16/98 --- --- ND --- --- -- ND --- -- NC2L=NE 09/10/99 --- --- ND ND ND ND --- --- --- 11/16/99 --- --- ND ND ND ND --- --- -- 05/10/00 --- --- ND ND ND ND --- --- --- 10/26/00 --- --- ND ND ND ND -- --- -- 04/18/01 --- --- ND ND ND ND --- --- --- 10/27/01 --- --- ND ND ND ND -- --- -- 06/13/02 --- --- ND ND ND ND --- --- --- 11/19/02 --- --- ND ND ND ND --- --- -- 06/27/03 --- --- ND ND ND ND --- --- --- 12/30/03 --- --- ND ND ND ND --- --- -- 06/30/04 --- --- ND ND ND ND --- --- --- 12/29/04 --- --- ND ND ND ND -- --- -- 06/29/05 --- --- ND ND ND ND --- --- --- 12/29/05 --- --- ND ND ND ND -- --- -- 06/28/06 --- --- ND ND ND ND --- --- --- 12/28/06 --- --- ND ND ND ND -- --- -- 07/12/07 --- --- ND ND ND ND --- --- --- 12/19/07 --- --- ND ND ND ND -- --- -- 07/08/08 --- --- ND ND ND ND --- --- --- 12/16/08 1 --- ND ND ND ND --- --- -- 07/08/09 1 --- ND ND ND ND --- --- --- 12/15/09 1 --- ND ND ND ND -- --- -- 06/23/10 1 --- ND ND ND ND --- --- --- 12/14/10 1 --- ND ND ND ND --- --- -- 06/21/11 1 ND ND ND ND ND --- --- --- 12/06/11 1 ND ND ND ND ND -- --- -- 06/13/12 1 ND ND ND ND ND --- --- --- 12/12/12 1 ND ND ND ND ND --- --- -- 04/29/13 1 ND ND ND ND ND --- --- --- 08/06/13 1 ND ND ND ND ND -- --- -- 02/25/14 1 ND ND ND ND ND --- --- --- 08/13/14 1 ND ND ND ND ND --- --- -- 03/12/15 1 ND ND ND ND ND --- --- --- 08/19/15 1 ND ND ND ND ND -- --- -- 02/18/16 1 ND ND ND ND ND --- --- --- 08/11/16 1 ND ND ND ND ND --- --- -- 02/15/17 1 ND ND ND ND ND --- --- --- 08/24/17 1 ND ND ND ND ND -- --- -- 02/07/18 1 ND ND ND ND ND --- --- --- 08/16/18 1 ND ND ND ND ND -- --- -- 02/06/19 0.54 ND ND ND ND ND --- --- --- 08/07/19 0.5 ND ND ND ND ND -- --- -- 02/14/20 0.54 ND ND ND ND ND --- --- --- 08/25/20 0.54 ND ND ND ND ND -- --- -- 02/10/21 0.9 ND --- --- ND ND ND --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 "' 0.56 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA NS Appendix D (Page 22 of 23) snr>,madn�<k.snereo«���dmn�revMa.,.��a.,,ssand o«�m.�waa.Mes Pros« G-ftQ-111a co.o,ra,d 11 wn„�s«d.d 1.11GII ,m- Wit I.>m I.- Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-5R MW-611 NES-2S NES-21) Trichlomethylene 12/02/97 -- -- ND -- -- -- ND - -- 05/27/98 ___ ___ ND ___ ___ ___ ND NC 21 3 µg/L 11/16/98 -- --- ND -- -- -- 2.9 --- -- 09/10/99 --- --- ND ND ND ND --- --- --- 11/16/99 -- --- ND ND ND ND -- --- -- 05/10/00 --- --- ND ND ND ND --- --- --- 10/26/00 -- --- ND ND ND ND --- --- -- 04/18/01 --- --- ND ND ND ND --- --- --- 10/27/01 -- --- ND ND ND ND -- --- -- 06/13/02 --- --- ND ND ND ND --- --- --- 11/19/02 -- --- ND ND ND ND --- --- -- 06/27/03 --- --- ND ND ND ND --- --- --- 12/30/03 --- --- ND ND ND ND -- --- -- 06/30/04 --- --- ND ND ND ND --- --- --- 12/29/04 --- --- ND ND ND ND --- --- -- 06/29/05 --- --- ND ND ND ND --- --- --- 12/29/05 --- --- ND ND ND ND -- --- -- 06/28/06 --- --- ND ND ND ND --- --- --- 12/28/06 --- --- ND ND ND ND --- --- -- 07/12/07 --- --- ND ND ND 0.68 1 --- --- --- 12/19/07 --- --- ND ND ND 0.64 1 --- --- -- 07/08/08 --- --- ND ND ND 0.51 1 --- --- --- 12/16/08 0.47 --- ND ND ND ND --- --- -- 07/08/09 0.47 --- ND ND ND 0.53 1 --- --- --- 12/15/09 0.47 --- ND ND ND ND --- --- -- 06/23/10 0.47 --- ND ND ND ND --- --- --- 12/14/10 0.47 --- ND ND ND ND --- --- -- 06/21/11 0.47 ND ND ND ND ND --- --- --- 12/06/11 0.47 ND ND ND ND ND -- --- -- 06/13/12 0.47 ND ND ND ND ND --- --- --- 12/12/12 0.47 ND ND ND ND ND --- --- -- 04/29/13 0.47 ND ND ND ND ND --- --- --- 08/06/13 0.47 ND ND ND ND ND -- --- -- 02/25/14 0.47 ND ND ND ND ND --- --- --- 08/13/14 0.47 ND ND ND ND ND --- --- -- 03/12/15 0.47 ND ND ND ND ND --- --- --- 08/19/15 0.47 ND ND ND ND ND -- --- --- 02/18/16 0.47 ND ND ND ND ND --- --- --- 08/11/16 0.47 ND ND ND ND ND --- --- -- 02/15/17 0.47 ND ND ND ND ND --- --- --- 08/24/17 0.47 ND ND ND ND ND -- --- -- 02/07/18 0.47 ND ND ND ND ND --- --- --- 08/16/18 0.47 ND ND ND ND ND --- --- -- 02/06/19 0.22 ND ND ND ND ND --- --- --- 08/07/19 0.22 ND ND ND ND ND -- --- -- 02/14/20 0.22 ND ND ND ND ND --- --- --- 08/25/20 0.22 ND ND ND ND ND -- --- --- 02/10/21 0.26 ND --- --- ND ND ND --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09 29 22 "' 0.38 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA NS Vinyl Chloride 09/14/94 --- --- ND --- --- --- ND --- -- 12/02/94 ___ ___ ND ___ ___ ___ ND NC 21 0.03 µg/L 02/08/95 --- --- ND --- --- -- ND --- -- 03/02/95 ___ ___ ND ___ ___ ___ ND 11/17/95 --- --- ND --- --- -- ND --- -- 05/23/96 ___ ___ ND ___ ___ ___ ND 11/14/96 --- --- ND --- --- -- ND --- -- 06/18/97 ___ ___ ND ___ ___ ___ ND 12/02/97 --- --- ND --- --- -_ ND --- __ 05/27/98 ___ ___ ND ___ ___ ___ ND 11/16/98 --- --- ND --- --- --- ND --- -- 09/10/99 --- --- ND ND ND ND --- --- --- 11/16/99 --- -- ND ND ND ND --- --- -- 05/10/00 --- --- ND ND ND 12 --- --- --- 10/26/00 --- -- ND ND ND ND --- --- -- 04/18/01 --- --- ND ND ND ND --- --- --- 10/27/01 --- --- ND ND ND ND -- --- -- 06/10/02 --- --- ND ND ND ND --- --- --- 06/13/02 --- --- ND ND ND ND --- --- -- 11/19/02 --- --- ND ND ND ND --- --- --- 06/27/03 --- --- ND ND ND 26.9 --- --- -- 12/30/03 --- --- ND ND ND 30 --- --- --- 06/30/04 --- --- ND ND ND 11 --- --- -- 12/29/04 --- --- ND ND ND 12 --- --- --- 06/29/05 --- --- ND ND ND 14 -- --- -- 12/29/05 --- --- ND ND ND 15 --- --- --- 06/28/06 --- --- ND ND ND 12.5 --- --- -- 12/28/06 --- --- ND ND ND 8.9 --- --- --- 07/12/07 --- --- ND ND ND 8.3 -- --- -- 12/19/07 --- --- ND ND ND 8.4 --- --- --- 07/08/08 --- --- ND ND ND 10.6 --- --- -- 12/16/08 0.62 --- ND ND ND 5 --- --- --- 07/08/09 0.62 --- ND ND ND 13.3 -- --- -- 12/15/09 0.62 --- ND ND ND 9.9 --- --- --- 06/23/10 0.62 --- ND ND ND 11.2 -- --- -- 12/14/10 0.62 --- ND ND ND 8.4 --- --- --- 06/21/11 0.62 ND ND ND ND 10.5 -- --- -- 12/06/11 0.62 ND ND ND ND 4.1 --- --- --- 06/13/12 0.62 ND ND ND ND 6.6 -- --- -- 12/12/12 0.62 ND ND ND ND 3.3 --- --- --- 04/29/13 0.62 ND ND ND ND 7.6 --- --- -- 08/06/13 0.62 ND ND ND ND 9.1 --- --- --- 02/25/14 0.62 ND ND ND ND 6.8 --- --- -- 08/13/14 0.62 ND ND ND ND 5.4 --- --- --- 03/12/15 0.62 ND ND ND ND 5.1 --- --- -- 08/19/15 0.62 ND ND ND ND 5 --- --- --- 02/18/16 0.62 ND ND ND ND 5.4 --- --- --- 08/11/16 0.62 ND ND ND ND 5.6 --- --- --- 02/15/17 0.62 ND ND ND ND 1.4 -- --- -- 08/24/17 0.62 ND ND ND ND 2.1 --- --- --- 02/07/18 0.62 ND ND ND ND 1.8 --- --- --- 08/16/18 0.62 ND ND ND ND 3.5 --- --- --- 02/06/19 0.24 ND ND ND ND 4.9 -- --- -- 08/07/19 0.24 ND ND ND ND 2.8 --- --- --- 02/14/20 0.24 ND ND ND ND 2.1 --- --- -- 08/25/20 0.24 ND ND ND ND 1.9 --- --- --- 02/10/21 0.19 ND --- --- ND 2.0 ND --- -- 08/18/21 0.39 --- --- --- --- 1.3 --- --- --- 02/17/22 0.39 --- --- --- -- 0.88 1 --- --- -- 09 29 221'I 0.39 <3.0 <1.0 <1.0 <1.0 0.59 1 <1.0 <3.0 NS Xylene (Total) 02/06/19 NA NA NA NA NA NA NA NA NA 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA O8/18/21 0.34 --- --- 1.5 --- --- 1.6 --- --- 02/15/22 NA NA NA NA NA NA NA NA NA NC 21-=500 µg/L 0929221'I 0.34 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA NS Notes. 1. September 2022 MW-2, MW-4R, and MW-6R sampled collected on 10/05/22. 2. Monitoring well MW-3RR was installed in September 2022 to replace abandoned monitoring well MW-3R. Data shown in the table prior to the September 2022 monitoring event for MW-3RR was collected from abandoned monitoring well MW-3R. Analytical results from September 1994 through February 2021 obtained from La Bella Associates Water Quality Monitoring Report - February 2021 Event. Analytical results from August 2021 obtained from Garrett & Moore, Inc. Water Quality Monitoring Report- August 2021 Event. NC 2L Standards are the Title 15A NCAC 02L.0202 Groundwater Standards dated April 1, 2022. Bold concentrations exceed the NC21- Standard for groundwater. All concentrations are in micrograms per liter (µg/L). NA = not analyzed/not reported; ND = not detected; RL= reporting limit; NS = not sampled; NE = not established; --- = no data B = blank -qualified data; result is expected to be biased high based on concentrations in the blank. 1= Estimated value between the MDL and the MRL; MDL= laboratory method detection limit; MRL= laboratory method reporting limit Appendix D (Page 23 of 23) snr>,mann<k.snereo«�n�omn�revMa.,.n,�a.,,ssana c«�m.nwaa.Mes Pros«.,,camna Moo�.,cMww-c��N��a co. o,ra,a rrwn „-- �m,... 101.vomaa Unn, �.-Tau. Hart & Hickman, PC Appendix E Summary of Historical Constituents in Surface Water 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS Appendix E Summary of Historical Constituents in Surface Water Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date DL SW-1 SW-2 Inorganics Antimony 06/23/10 2.6 2.8 J ND 12/14/10 2.6 ND Dry ISTV 131 = 5,300 pg/L 06/21/11 5 ND Dry 12/06/11 5 ND ND 06/13/12 5 ND ND 12/11/12 5 ND Dry 04/29/13 5 ND ND 08/06/13 5 ND ND 02/25/14 5 ND ND 08/13/14 5 ND ND 03/11/15 3.8 ND ND 08/19/15 3.8 ND Dry 02/18/16 3.8 ND ND 08/11/16 3.8 ND ND 02/15/17 3.9 ND ND 08/24/17 3.9 ND --- 02/06/18 3.9 ND ND 08/16/18 3.9 ND ND 02/06/19 3.9 ND ND 08/08/19 3 ND ND 02/13/20 3 ND ND 08/26/20 3 3.3 J ND 02/10/21 4.5 ND --- 08/18/21 ND ND 02/15/22 3 ND ND 09/29/22 3 <5.0 <5.0 Arsenic 12/19/07 NR 5.3 Dry 07/08/08 NR ND Dry NC2B 1) = 340 pg/L 12/16/08 2.7 ND ND 07/08/09 2.7 ND Dry 12/15/09 2.7 ND 2.7 J 06/23/10 2.7 9.2 J ND 12/14/10 2.7 3.1 Dry 06/21/11 5 ND Dry 12/06/11 5 ND ND 06/13/12 5 6.5 J ND 12/11/12 5 ND Dry 04/29/13 5 ND ND 08/06/13 5 5.5 J ND 02/25/14 5 ND ND 08/13/14 5 ND ND 03/11/15 2.5 4.9 J 2.7 J 08/19/15 2.5 ND Dry 02/18/16 2.5 ND ND 08/11/16 2.5 6.8 J 7.3 J 02/15/17 5 ND ND 08/24/17 5 ND --- 02/06/18 5 ND ND 08/16/18 5 ND ND 02/06/19 5 ND ND 08/08/19 4.7 5.1 J ND 02/13/20 5 ND ND 08/26/20 4.7 ND ND 02/10/21 3.5 ND --- 08/18/21 ND --- 02/15/22 4.7 ND ND 09/29/22 4.7 <10.0 <10.0 Barium 09/14/94 NR 160 ND 12/02/94 NR ND ND ISTV (3) = 21,000 pg/L 02/08/95 NR ND ND 03/02/95 NR ND ND 11/17/95 NR ND ND 05/23/96 NR ND ND 11/14/96 NR 69 29 06/18/97 NR 64 25 12/02/97 NR 61 41 05/27/98 NR 130 50 11/16/98 NR 93 100 09/10/99 NR ND ND 11/16/99 NR ND ND 05/10/00 NR ND ND 10/26/00 NR ND ND 04/18/01 NR ND ND 11/19/02 NR NS ND 06/27/03 NR ND ND 12/30/03 NR ND ND 06/30/04 NR ND ND 12/29/04 NR ND ND 06/29/05 NR ND ND 12/29/05 NR ND ND 06/28/06 NR ND ND 12/28/06 NR 40 47.2 07/12/07 NR 66.2 J Dry 12/19/07 NR 112 Dry 07/08/08 NR 89 J Dry 12/16/08 0.2 42.1 B 54.8 J 07/08/09 0.2 101 Dry 12/15/09 0.2 36.3 B 48.4 B 06/23/10 0.2 115 B 39.1 B 12/14/10 0.2 97.4 J Dry 06/21/11 5 66.3 J Dry 12/06/11 5 59.7 J 55.3 J 06/13/12 5 161 85.4 J 12/11/12 5 71.1 J Dry 04/29/13 5 43.5 J 43.5 J 08/06/13 5 80.3 J 23.8 02/25/14 5 63.9 J 61.8 J 08/13/14 5 47.4 J 43.9 J 03/11/15 2.5 28.5 J 42.0 J 08/19/15 2.5 37 J Dry 02/18/16 2.5 58.2 J 55 J 08/11/16 2.5 175 152 02/15/17 2.5 285 38.2 J 08/24/17 2.5 31.6 J --- 02/06/18 2.5 22.4 J 33.5 J 08/16/18 2.5 19.1 J 28.3 J 02/06/19 2.5 47.6 30.7 08/08/19 1 23 17.3 02/13/20 1 18.4 26.4 08/26/20 3.5 15.5 21.3 02/10/21 4.7 ND --- 08/18/21 3.5 20.9 18.4 02/15/22 3.5 16.7 23.2 08/18/21 3.5 20.9 18.4 02/15/22 3.5 16.7 23.2 09/29/22 3.5 23.5 25.3 Appendix E (Page 1 of 88) https:l/harthlck sharepoint.cam/sites/MasterFiles-1ISh-I Documents/A -Master ProjectslGarrett & Moore/GMI-004 - Granville Co. Oxtord LF Unit 112022 Second Half GWM/Tahles/OAord Unit 1 Historic Tables Hart & Hickman, PC Appendix E Summary of Historical Constituents in Surface Water Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date DL SW-1 SW-2 Beryllium 11/16/98 NR 1 1 09/10/99 NR ND ND NC2B 1) = 65 Ng/L 11/16/99 NR ND ND 05/10/00 NR ND ND 10/26/00 NR ND ND 04/18/01 NR ND ND 11/19/02 NR ND ND 06/27/03 NR ND ND 12/30/03 NR ND ND 06/30/04 NR ND ND 12/29/04 NR ND ND 06/29/05 NR ND ND 12/29/05 NR ND ND 06/28/06 NR ND ND 12/28/06 NR ND ND 07/12/07 NR ND Dry 12/19/07 NR 0.93 J Dry 07/08/08 NR 0.47 J Dry 12/16/08 0.1 0.21 J 0.27 J 07/08/09 0.1 0.29 J Dry 12/15/09 0.1 0.27 J 0.22 J 06/23/10 0.1 1.2 ND 12/14/10 0.1 0.78 J Dry 06/21/11 1 ND Dry 12/06/11 1 ND ND 06/13/12 1 1.5 ND 12/11/12 1 ND Dry 04/29/13 1 ND ND 08/06/13 1 ND ND 02/25/14 1 ND ND 08/13/14 1 ND ND 03/11/15 0.5 ND ND 08/19/15 0.5 ND Dry 02/18/16 0.5 ND ND 08/11/16 0.5 1.9 1.7 02/15/17 0.5 ND ND 08/24/17 0.5 ND --- 02/06/18 0.5 ND ND 08/16/18 0.5 ND ND 02/06/19 0.5 ND ND 08/08/19 0.2 ND ND 02/13/20 0.2 ND 0.46 JB 08/26/20 0.7 ND ND 02/10/21 4.3 4.7 J --- 08/18/21 ND ND 02/15/22 0.7 ND ND 09/29/22 0.7 <1.0 <1.0 Cadmium 11/19/02 NR ND 1 06/27/03 NR ND ND NC2B SWA 14) = 1.03 Ng/L 12/30/03 NR ND ND NC2B SW-214) = 1.81 pg/L 06/30/04 NR ND ND 12/29/04 NR ND ND 06/29/05 NR ND ND 12/29/05 NR ND ND 06/28/06 NR ND ND 12/28/06 NR ND ND 07/12/07 NR ND Dry 12/19/07 NR ND Dry 07/08/08 NR ND Dry 12/16/08 0.5 ND ND 07/08/09 0.5 ND Dry 12/15/09 0.5 ND ND 06/23/10 0.5 ND ND 12/14/10 0.5 ND Dry 06/21/11 1 ND Dry 12/06/11 1 ND ND 06/13/12 1 ND ND 12/11/12 1 ND Dry 04/29/13 1 ND ND 08/06/13 1 ND ND 02/25/14 1 ND ND 08/13/14 1 ND ND 03/11/15 0.5 ND ND 08/19/15 0.5 ND ND 02/18/16 0.5 ND ND 08/11/16 0.5 ND ND 02/15/17 0.5 ND ND 08/24/17 0.5 ND --- 02/06/18 0.5 ND ND 08/16/18 0.5 ND ND 02/06/19 0.5 ND ND 08/08/19 0.4 ND ND 02/13/20 0.4 ND ND 08/26/20 0.4 ND ND 02/10/21 3.9 ND --- 08/18/21 0.4 0.44 J --- 02/15/22 0.4 ND ND 09/29/22 0.4 <1.0 <1.0 Appendix E (Page 2 of 88) https Hharthlck shay .ht.cam/sites/MasterFiles-1/Shared Documents/A -Master ProjectslGarrett & Moore/GMI-004 - Granville Co. Oxtord LF Unit 112022 Second Half GWM/Tahles/OAord Unit 1 Historic Tables Hart & Hickman, PC Appendix E Summary of Historical Constituents in Surface Water Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date DL SW-1 SW-2 Chromium 26-Oct-00 NR ND ND 06/18/97 NR 12 ND NC213 SWA 14) = 228.09 Ng/L 12/02/97 NR 8 ND NC2B SW-214) = 386.71 pg/L 05/27/98 NR 15 ND 11/16/98 NR 30 31 09/10/99 NR 24 ND 11/16/99 NR ND ND 05/10/00 NR ND ND 04/18/01 NR ND ND 11/19/02 NR ND ND 06/27/03 NR ND ND 12/30/03 NR ND ND 06/30/04 NR ND ND 12/29/04 NR ND ND 06/29/05 NR ND ND 12/29/05 NR ND ND 06/28/06 NR 12.6 ND 12/28/06 NR 4.8 J 6.1 1 07/12/07 NR ND Dry 12/19/07 NR 27.9 Dry 07/08/08 NR 19.3 Dry 12/06/08 0.4 6.4 J 8.4 J 07/08/09 0.4 12.9 Dry 12/15/09 0.4 6 1 5 1 06/23/10 0.4 41.8 4.8 1 08/12/10 0.4 44.4 NS 12/14/10 0.4 32.4 Dry 06/21/11 5 12.1 Dry 12/06/11 5 11.8 7.5 1 06/13/12 5 46.1 20.7 12/11/12 5 19.1 Dry 04/29/13 5 5.8 1 5.8 1 08/06/13 5 ND ND 02/25/14 5 13.5 13.2 08/13/14 5 10.8 10 J 03/11/15 2.5 4 1 3.1 J 08/19/15 2.5 ND Dry 02/18/16 2.5 ND ND 08/11/16 2.5 63 55.1 09/13/16 2.5 ND DRY 02/15/17 2.5 6.1 J 7.2 J 08/24/17 2.5 7 J --- 02/06/18 2.5 2.8 1 5.4 1 08/16/18 2.5 ND 3.2 1 02/06/19 2.5 3 J ND 08/08/19 1 2.6 J 2.1 J 02/13/20 1 2 J 3.6 1 08/26/20 3.7 ND ND 02/10/21 3 ND ND 8/18/201 ND ND 02/15/22 3.7 --- 3.7 1 09/29/22 3.7 <5.0 <5.0 Cobalt 11/14/96 NR 3 ND 06/18/97 NR 3 ND ISTV (3) = 16 pg/L 12/02/97 NR ND ND O5/27/98 NR 8 5 11/16/98 NR 4.9 5.9 09/10/99 NR ND ND 11/16/99 NR ND ND 05/10/00 NR ND ND 10/26/00 NR ND ND 04/18/01 NR ND ND 11/19/02 NR ND ND 06/27/03 NR ND ND 12/30/03 NR ND ND 06/30/04 NR ND ND 12/29/04 NR ND ND 06/29/05 NR ND ND 12/29/05 NR ND ND 06/28/06 NR ND ND 12/28/06 NR ND 2.8 J 07/12/07 NR ND Dry 12/19/07 NR 34.3 Dry 07/08/08 NR 10 B Dry 12/16/08 0.6 4.8 B 5.1 B 07/08/09 0.6 7.2 J Dry 12/15/09 0.6 1.6 J 1.3 J 06/23/10 0.6 23 2.7 J 08/12/10 0.6 30.5 NS 12/14/10 0.6 27 Dry 06/21/11 5 5.4 J Dry 12/06/11 5 ND ND 06/13/12 5 12.5 6.5 J 12/11/12 5 ND Dry 04/29/13 5 10.2 10.8 08/06/13 5 9 J ND 02/25/14 5 10.1 10.6 08/13/14 5 ND ND 03/11/15 2.5 ND ND 08/19/15 2.5 ND Dry 02/18/16 2.5 ND ND 08/11/16 2.5 16.7 12.7 02/15/17 2.5 4 J ND 08/24/17 2.5 ND --- 02/06/18 2.5 ND ND 08/16/18 2.5 ND ND 02/06/19 2.5 ND ND 08/08/19 1.1 1.4 1 ND 02/13/20 1 ND ND 08/26/20 3.6 ND ND 02/10/21 4.7 --- ND 08/18/21 ND ND 02/15/22 3.6 ND ND 09/29/22 3.6 <5.0 <5.0 Appendix E (Page 3 of 88) https:l/harthlck sharepoint.cam/sites/MasterFiles-1ISh-I Documents/A -Master ProjectslGarrett & Moore/GMI-004 - Granville Co. Oxtord LF Unit 112022 Second Half GWM/Tahles/OAord Unit 1 Historic Tables Hart & Hickman, PC Appendix E Summary of Historical Constituents in Surface Water Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date DL SW-1 SW-2 Copper 06/18/97 NR 11 ND 12/02/97 NR 11 ND NC213 SWA i° = 4.69 pg/L 05/27/98 NR 21 ND NC213 SW-2 141 = 8.60 pg/L 11/16/98 NR 14 16 09/10/99 NR ND ND 11/16/99 NR ND ND 05/10/00 NR ND ND 10/26/00 NR ND ND 04/18/01 NR ND ND 11/19/02 NR INS ND 06/27/03 NR ND ND 12/30/03 NR ND ND 06/30/04 NR ND ND 12/29/04 NR ND ND 06/29/05 NR ND ND 12/29/05 NR ND ND 06/28/06 NR ND ND 12/28/06 NR 3 B 3.9 07/12/07 NR ND Dry 12/19/07 NR 23.7 Dry 07/08/08 0.3 14.7 Dry 12/16/08 0.3 6.4 J 8 J 07/08/09 0.3 7 J Dry 12/15/09 0.3 5.2 J 4.4 J 06/23/10 0.3 23.9 2.7 J 08/12/10 0.3 25.9 ND 12/14/10 5 21.1 Dry 06/21/11 5 7.7 J Dry 12/06/11 5 12.5 7.7 J 06/13/12 5 34.5 14.8 12/11/12 5 16.4 Dry 04/29/13 5 7.7 J 7.4 J 08/06/13 5 5.5 J ND 02/25/14 5 11.2 10.3 08/13/14 2.5 9.6 J 7.7 J 03/11/15 2.5 3.1 J 2.6 J 08/19/15 2.5 ND Dry 02/18/16 2.5 6.3 J 5.7 J 08/11/16 2.5 39.9 34.5 09/13/16 2.5 9.3 B DRY 02/15/17 2.5 5.8 J 5.2 J 08/24/17 2.5 4.5 J --- 02/06/18 2.5 6.8 J 8 J 08/16/18 2.5 3.9 J 3 J 02/06/19 2.5 ND ND 08/08/19 2.1 4.4 J 3.6 J 02/13/20 2.1 3.7 J 4.4 J 08/26/20 4.3 ND ND 02/10/21 0.7 --- ND 08/18/21 ND ND 02/15/22 4.3 ND ND 09/29/22 4.3 <5.0 <5.0 Hardness, Total (SM 23408) 02/06/19 662 38800 55700 08/08/19 131 19800 26400 02/13/20 131 16900 29200 08/26/20 131 12500 29500 02/10/21 0 --- ND 08/18/21 131 24700 46600 09/29/22 131 32700 62300 Iron 08/24/17 25 9760 -- 08/16/18 25 3320 2750 NRWQC 12) = 1,000 µg/L 02/10/21 3.7 -- ND 08/18/21 02/15/22 -- NA NA 09/29/22 NA NA NA Lead 26-Oct-00 NR ND ND 12/02/97 NR ND 6 NC213 SW-1 141 = 18.77 pg/L 05/27/98 NR 8 ND NC213 SW-2 141 = 38.44 pg/L 11/16/98 NR 7.3 8.9 09/10/99 NR ND ND 11/16/99 NR ND ND 05/10/00 NR ND ND 04/18/01 NR ND ND 11/19/02 NR ND ND 06/27/03 NR ND ND 12/30/03 NR ND ND 06/30/04 NR ND ND 12/29/04 NR ND ND 06/29/05 NR ND ND 12/29/05 NR ND ND 06/28/06 NR ND ND 12/28/06 NR ND 4.8 J 07/12/07 NR 3.2 J Dry 12/19/07 NR ND Dry 07/08/08 NR ND Dry 12/16/08 4 ND ND 07/08/09 4 ND Dry 12/15/09 4 ND ND 06/23/10 4 9.2 J ND 12/14/10 4 5.1 J Dry 06/21/11 5 ND Dry 12/06/11 5 ND ND 06/13/12 5 14.3 5.5 J 12/11/12 5 ND Dry 04/29/13 5 ND ND 08/06/13 5 ND ND 02/25/14 5 ND ND 08/13/14 5 ND ND 03/11/15 2.5 ND ND 08/19/15 2.5 ND Dry 02/18/16 2.5 4 J 2.6 J 08/11/16 2.5 16.6 13.6 09/13/16 2.5 4.1 J DRY 02/15/17 2.5 2.5 J 2.5 J 08/24/17 2.5 2.5 J --- 02/06/18 2.5 ND ND 08/16/18 2.5 ND ND 02/06/19 2.5 ND ND 08/08/19 1.6 ND ND 02/13/20 1.6 ND ND 08/26/20 4.5 ND ND 02/10/21 3.6 --- ND 08/18/21 ND ND 02/15/22 4.5 ND ND 09/29/22 4.5 <5.0 <5.0 Appendix E (Page 4 of 88) https:l/harthlck sharepoint.cam/sites/MasterFiles-1ISh-I Documents/A -Master ProjectslGarrett & Moore/GMI-004 - Granville Co. Oxtord LF Unit 112022 Second Half GWM/Tables/OAord Unit 1 Historic Tables Hart & Hickman, PC Appendix E Summary of Historical Constituents in Surface Water Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date DL SW-1 SW-2 Manganese 08/24/17 2.5 244 --- 08/16/18 2.5 176 45.2 1 NRWQC 12) = 100 µg/L 02/10/21 4.3 --- ND 08/18/21 --- 02/15/22 -- NA NA 09/29/22 NA NA NA Nickel 12/28/06 NR 4.6 J 6.2 J 07/12/07 NR 4 1 Dry NC213 SWA 14)= 181.87 µg/L 12/19/07 NR 21.9 Dry NC213 SW-2 14) = 313.76 µg/L 07/08/08 NR 12.1 J Dry 12/16/08 1.7 5.2 B 6.8 B 07/08/09 1.7 10 J Dry 12/15/09 1.7 4.8 4.7 B 06/23/10 1.7 21.5 J ND 12/14/10 1.7 14.4 J Dry 06/21/11 5 5.8 1 Dry 12/06/11 5 7.2 J ND 06/13/12 5 17.1 J 7.5 1 12/11/12 5 7.6 J Dry 04/29/13 5 ND ND 08/06/13 5 ND ND 02/25/14 5 7.3 J 6.6 J 08/13/14 5 7.5 J 5.4 1 03/11/15 2.5 3 1 2.8 J 08/19/15 2.5 ND Dry 02/18/16 2.5 3.3 J 3 J 08/11/16 2.5 22.8 J 19.4 1 02/15/17 2.5 4.2 1 4.1 1 08/24/17 2.5 3.7 J --- 02/06/18 2.5 ND 3.2 J 08/16/18 2.5 ND ND 02/06/19 2.5 ND ND 08/08/19 0.9 2.9 J 1.8 J 02/13/20 0.9 2.5 1 3.2 J 08/26/20 3.5 ND ND 02/10/21 3 ND ND 08/18/21 ND ND 02/15/22 3.5 ND ND 09/29/22 3.5 <5.0 <5.0 Selenium 12/19/07 NR 15.6 Dry 07/08/08 NR ND Dry NC2B i'i = 5 µg/L 12/16/08 3.8 3.9 B ND 07/08/09 3.8 ND Dry 12/15/09 3.8 ND ND 06/23/10 3.8 ND ND 12/14/10 3.8 5.9 J Dry 06/21/11 10 ND Dry 12/06/11 10 ND ND 06/13/12 10 ND ND 12/11/12 10 ND Dry 04/29/13 10 ND ND 08/06/13 10 ND ND 02/25/14 10 ND ND 08/13/14 10 ND ND 03/11/15 5 ND ND 08/19/15 5 ND Dry 02/18/16 5 ND ND 08/11/16 5 ND 6 J 02/15/17 5 ND ND 08/24/17 5 ND --- 02/06/18 5 ND ND 08/16/18 5 ND ND 02/06/19 5 ND ND 08/08/19 4.7 ND ND 02/13/20 5 ND ND 08/26/20 4.7 ND ND 02/10/21 4.7 ND ND 08/18/21 ND ND 02/15/22 4.7 ND ND 09/29/22 4.7 <10.0 <10.0 Silver 07/08/08 NR 0.22 J 0 12/16/08 0.1 ND Dry NC213 i'i= 0.06 µg/L 07/08/09 0.1 ND 0.11 J 12/15/09 0.1 ND Dry 06/23/10 0.1 ND 0.19 J 12/14/10 0.1 0.21 B ND 06/21/11 5 ND Dry 12/06/11 5 ND Dry 06/13/12 5 ND ND 12/11/12 5 ND ND 04/29/13 5 ND Dry 08/06/13 5 ND ND 02/25/14 5 ND ND 08/13/14 5 ND ND 03/11/15 2.5 ND ND 08/19/15 2.5 ND ND 02/18/16 2.5 ND Dry 08/11/16 2.5 ND ND 02/15/17 2.5 ND ND 08/24/17 2.5 ND ND 02/06/18 2.5 ND --- 08/16/18 2.5 ND ND 02/06/19 2.5 ND ND 08/08/19 2.5 ND ND 02/13/20 2.5 ND ND 08/26/20 2.5 ND ND 02/10/21 0.7 ND ND 08/18/21 ND ND 02/15/22 2.5 ND ND 09/29/22 2.5 <5.0 <5.0 Appendix E (Page 5 of 88) https:l/harthlck sharepoint.cam/sites/MasterFiles-1ISh-I Documents/A -Master ProjectslGarrett & Moore/GMI-004 - Granville Co. Oxtord LF Unit 112022 Second Half GWM/Tahles/OAord Unit 1 Historic Tables Hart & Hickman, PC Appendix E Summary of Historical Constituents in Surface Water Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date DL SW-1 SW-2 Thallium 12/19/07 NR 5.1 J Dry 07/08/08 NR 5.2 J Dry ISTV (3) = 2 µg/L 12/16/08 3 ND ND 07/08/09 3 ND Dry 12/15/09 3 ND ND 06/23/10 3 ND ND 08/12/10 30 INS INS 12/14/10 3 6.5 Dry 06/21/11 5.4 8.2 Dry 12/06/11 5.4 ND ND 06/13/12 5.4 ND ND 12/11/12 5.4 ND Dry 04/29/13 5.4 ND ND 08/06/13 5.4 ND ND 02/25/14 5.4 ND ND 08/13/14 5.4 ND ND 03/11/15 5 ND ND 08/19/15 5 ND Dry 02/18/16 5 ND ND 08/11/16 5 ND ND 02/15/17 0.02 ND ND 08/24/17 0.02 ND --- 02/06/18 0.028 ND ND 08/16/18 0.02 ND ND 02/06/19 0.06 ND ND 08/08/19 0.11 ND ND 02/13/20 0.11 ND ND 08/26/20 0.05 ND ND 02/10/21 0.05 --- --- 08/18/21 ND ND 02/15/22 0.05 ND ND 09/29/22 0.05 <0.47 <0.47 Vanadium 11/14/96 NR 11 5 06/18/97 NR 20 ND NC2B Not Established 12/02/97 NR 16 ND 05/27/98 NR 44 ND 11/16/98 NR 44 47 09/10/99 NR ND ND 11/16/99 NR ND ND 05/10/00 NR ND ND 10/26/00 NR ND ND 04/18/01 NR ND ND 11/19/02 NR ND ND 06/27/03 NR ND ND 12/30/03 NR ND ND 06/30/04 NR ND ND 12/29/04 NR ND ND 06/29/05 NR ND ND 12/29/05 NR ND ND 06/28/06 NR ND ND 12/28/06 NR 8.6 J 10.7 07/12/07 NR 5.3 J ND 12/19/07 NR 41.2 ND 02/14/08 NR 12.4 Dry 07/08/08 NR 38.2 Dry 12/16/08 0.2 11.5 J 14.1 J 07/08/09 0.2 24.3 J Dry 12/15/09 0.2 10 J 7 J 06/23/10 0.2 63.4 8.3 J 08/12/10 0.2 67.9 NS 12/14/10 0.2 52.3 Dry 06/21/11 5 25.3 Dry 12/06/11 5 19.7 J 13 J 06/13/12 5 130 61.5 12/11/12 5 50.7 Dry 04/29/13 5 16.9 J 18.4 J 08/06/13 5 15.4 J ND 02/25/14 5 29.2 29.4 08/13/14 5 18 J 18.2 J 03/11/15 2.5 7.8 J 8.3 J 08/19/15 2.5 2.8 J Dry 02/18/16 2.5 6.4 J 6.1 J 08/11/16 2.5 160 144 02/15/17 2.5 18.2 J 20.8 J 08/24/17 2.5 20.5 J --- 02/06/18 2.5 6.9 J 14.4 J 08/16/18 2.5 7.6 J 5.8 J 02/06/19 2.5 6.5 4.9 J 08/08/19 1.3 8.5 6.7 02/13/20 1.3 4.1 J 8.1 08/26/20 3.9 ND 7.2 02/10/21 3.7 ND ND 08/18/21 ND ND 02/15/22 3.9 6.1 9.9 09/29/22 3.9 <5.0 <5.0 Appendix E (Page 6 of 88) https:l/harthlck sharepoint.cam/siteslMasterFiles-1/Shared Documents/A -Master ProjectslGarrett & Moore/GMI-004 - Granville Co. Oxtord LF Unit 112022 Second Half GWM/Tahles/OAord Unit 1 Historic Tables Hart & Hickman, PC Appendix E Summary of Historical Constituents in Surface Water Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date DL SW-1 SW-2 Zinc 09/14/94 NR ND ND 12/02/94 NR 61 ND NC213 SWA (4) = 45.45 µg/L 02/08/95 NR ND ND NC2B SW-2 14)= 78.47 µg/L 03/02/95 NR 64 ND 11/17/95 NR ND ND 05/23/96 NR ND ND 11/14/96 NR ND ND 06/18/97 NR 26 ND 12/02/97 NR 32 40 05/27/98 NR 57 28 11/16/98 NR 28 31 09/10/99 NR ND ND 11/16/99 NR ND ND 05/10/00 NR ND ND 10/26/00 NR ND ND 04/18/01 NR ND ND 11/19/02 NR NS ND 06/27/03 NR ND ND 12/30/03 NR ND ND 06/30/04 NR ND ND 12/29/04 NR ND ND 06/29/05 NR ND ND 12/29/05 NR ND ND 06/28/06 NR ND ND 12/28/06 NR 7.4 J 8.5 J 07/12/07 NR 10.2 Dry 12/19/07 NR 24.1 B Dry 07/08/08 NR 17.2 Dry 12/16/08 0.4 8.9 J 11.9 07/08/09 0.4 9.4 J Dry 12/15/09 0.4 8.3 B 8.5 B 06/23/10 0.4 29.3 4 J 12/14/10 0.4 25.1 B Dry 06/21/11 10 10.9 Dry 12/06/11 10 15 B 10.3 B 06/13/12 10 46.3 19.8 12/11/12 10 25.4 Dry 04/29/13 10 13.8 12.5 08/06/13 10 11.3 ND 02/25/14 10 15 14.8 B 08/13/14 10 14.3 ND 03/11/15 5 62.3 11.6 B 08/19/15 5 ND Dry 02/18/16 5 13 11 08/11/16 5 66.4 54.1 09/13/16 5 14.5 J, B DRY 02/15/17 5 11 9.6 J 08/24/17 5 7.6 J J --- 02/06/18 5 9.4 J J 6.8 J 08/16/18 5 6.2 J J ND 02/06/19 5 ND ND 08/08/19 3.9 7.3 J J ND 02/13/20 3.9 8.2 J J 7.7 J 08/26/20 9.5 ND ND 02/10/21 3.6 ND ND 08/18/21 9.5 11.7 --- 02/15/22 9.5 ND ND 09/29/22 9.5 <10.0 <10.0 Appendix E (Page 7 of 88) https:l/harthlck sharepoint.cam/sites/MasterFiles-1ISh-I Documents/A -Master ProjectslGarrett & Moore/GMI-004 - Granville Co. Oxtord LF Unit 112022 Second Half GWM/Tahles/OAord Unit 1 Historic Tables Hart & Hickman, PC Appendix E Summary of Historical Constituents in Surface Water Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date DL SWA SW-2 Organics 1,4-Dioxane 08/16/18 1.9 ND 4.5 02/06/19 1.9 ND 5.9 ISTV i' = 80 µg/L 08/08/19 1.2 ND 2.6 02/13/20 1.2 ND ND 08/26/20 1.2 ND 4.1 02/10/21 0.1 --- --- 08/18/21 0.86 --- 4.8 02/15/22 0.86 ND 5.2 09/29/22 0.86 <2.0 <2.0 2-Hexanone 06/23/10 0.46 1.5 J ND 12/14/10 0.46 ND Dry NC213 Not Established 06/21/11 0.46 ND Dry 12/06/11 0.46 ND ND 06/13/12 0.46 ND ND 12/12/12 0.46 0.47 J Dry 04/29/13 0.46 ND ND 08/06/13 0.46 ND ND 02/25/14 0.46 ND ND 08/13/14 0.46 ND ND 03/11/15 0.46 ND ND 08/19/15 0.46 ND Dry 02/18/16 0.46 ND ND 08/11/16 0.46 1.2 J ND 02/15/17 0.46 ND ND 08/24/17 0.46 ND --- 02/06/18 0.46 ND ND 08/16/18 0.46 ND ND 02/06/19 0.57 ND ND 08/08/19 0.57 ND ND 02/13/20 0.57 ND ND 08/26/20 0.57 ND ND 02/10/21 0.54 ND --- 08/18/21 ND ND 02/15/22 0.48 ND ND 09/29/22 0.48 <5.0 <5.0 Acetone 12/15/09 2.2 3.9 B 3.2 B 06/23/10 2.2 5.4 B 2.2 B ISTV (3)= 2,000 pg/L 12/14/10 2.2 ND Dry 06/21/11 2.2 3.4 B Dry 12/06/11 2.2 ND ND 06/13/12 2.2 2.2 B ND 12/12/12 10 ND Dry 04/29/13 10 ND ND 08/06/13 10 ND ND 02/25/14 10 ND ND 08/13/14 10 ND ND 03/11/15 10 ND ND 08/19/15 10 ND Dry 02/18/16 10 ND ND 08/11/16 10 ND ND 02/15/17 10 ND ND 08/24/17 10 ND --- 02/06/18 10 ND ND 08/16/18 10 ND ND 02/06/19 6.2 ND ND 08/08/19 6.2 ND ND 02/13/20 6.2 ND ND 08/26/20 6.2 ND ND 02/10/21 0.2 ND ND 08/18/21 ND ND 02/15/22 5.1 ND ND 09/29/22 5.1 <25.0 <25.0 Methylene Chloride 04/29/13 0.97 0.98 J ND 08/06/13 0.97 ND ND ISTV (3)= 11,000 pg/L 02/25/14 0.97 ND ND 08/13/14 0.97 ND ND 03/11/15 0.97 ND ND 08/19/15 0.97 ND Dry 02/18/16 0.97 ND ND 08/11/16 0.97 ND ND 02/15/17 0.97 ND ND 08/24/17 0.97 ND --- 02/06/18 0.97 ND ND 08/16/18 0.97 ND ND 02/06/19 3.7 ND ND 08/08/19 3.7 ND ND 02/13/20 3.7 ND ND 08/26/20 3.7 ND ND 02/10/21 4.5 ND ND 08/18/21 02/15/22 2 ND ND 09/29/22 2 <5.0 <5.0 Notes: 1. 15A NCAC 213 Water Quality Standards (26 Standards) for Surface Water (Class C) dated July 26, 202 2. No 2B Standard established, value shown is EPA Nationally Recommended Water Quality Criteria (NRI Life & Human Health. 3. No 2B Standard or NWQC established, value shown is North Carolina In -Stream Target Values for Surf 4. NC 2B Standards for hardness -dependent metals calculated using total hardness values from Septemb Groundwater Sampling Event (SW-1 = 32,700 ug/L; SW-2 = 62,300 ug/L). Analytical results from November 1996 through February 2021 obtained from LaBella Associates Water Q Report - February 2021 Event. Analytical results from August 2021 obtained from Garrett & Moore, Inc. Water Quality Monitoring Report - Bold concentrations exceed the NC 213 Standard or ISTV. All concentrations are in micrograms per liter (pg/L). J = Estimated concentration above the adjusted method detection limit and below the adjusted method rer B = blank -qualified data; result is expected to be biased high based on concentrations in the blanks. MRL = laboratory method reporting limit; MDL = laboratory method detection limit; B = Blank -qualified data, result is expected to be biased high based on concentrations in the blanks NR = Not Reported; NE= Not established; --- = Not Sampled/ Data not available; DRY = Surface water point considered to be dry; ND = Not detected above laboratory method reporting lin Appendix E (Page 8 of 88) helps://harthic .sharepolnt.wWslteslMaster iles-1/Shared Doc enta~-Master ProJecla/Ganed & Moore/GMI-004 - Grenville Co. Oxford LF Unit 1/2022 Second Half GWM/rables/Oxford Unit 1 Historic Tables Hart & Hickman, PC Appendix F Summary of Historical Monitoring Natural Attenuation Parameters 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS Appendix F Summary of Historical Monitored Natural Attenuation Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 ®®®®®®®®®®® Temperature Appendix F (Page 1 d 8) Hart & Hickman, PC Appendix F Summary of Historical Monitored Natural Attenuation Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 ®®®®®®®®®®® ��o®®000moo ��o®®000moo ��o®®000moo ��o®®000moo ��®o®000moo ��®o®000®oo �mmmmmmmmmm �m�mmmmmmmmm® Diwolved Carbon Dioxide ��mm®�mmmmm ��mmmmmm®ram ®�mmmmm®®m® ��m®®®ram®gym ��maa®aaaa� �mmmmmmmmmm �m�mmmmmmmmm® Appendix F (Page 2 of 8) Hart & Hickman, PC Appendix F Summary of Historical Monitored Natural Attenuation Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 ®®®®®®®®®®® Dissolved Oxygen (DO) Dissolved Hydrogen �®m�mmm®mom AppanEix F (Page 3 of 8) Hart & Hickman, PC Appendix F Summary of Historical Monitored Natural Attenuation Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 ®®®®®®®®®®® ��m�mmmmmm® ��m�mmmmmm� em��m�mmm�m�® ��m�®®mom®mom �emmmmmmmm® �ammmmmmmmm em�ammmmmmmm® ��m®®®ram®gym App dx F (Page 4 aI 8) Hart & Hickman, PC Appendix F Summary of Historical Monitored Natural Attenuation Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 ®®®®®®®®®®® ���®mmmmmmm® Hydrogen Sulfide ��m®®®ram®ram ��m®®®ram®ram �ammmmmmmm® �ammmmmmmmm em�ammmmmmmm® Total Organic Carbon (TOC) ��®mmmmmmm® ��®mmmm®mom �m��mmmmmmmm® Alkalinity (Total as CaCD,) ��m®®®gym®ram ��m®®®gym®mom Appendix F (Page 5 d 8) Hart & Hickman, PC Appendix F Summary of Historical Monitored Natural Attenuation Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 ®®®®®®®®®®® ���®mmmmmmm® Ethyl— (Ethere)) ��m®®®ram®ram ��m®®®ram®ram ��m®®mmm®ram ��m®®mmm®ram ��m®®mmm®ram ��m®®mmm®ram ��®0mmmmmmm ��mm®®mom®ram ��mmmmm�m�m ��mmmmm�m�m App dx F(Page 6 d 8) Hart & Hickman, PC Appendix F Summary of Historical Monitored Natural Attenuation Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 ®®®®®®®®®®® ��m®®mmm®ram ��m®®mmm®ram ��m®®mmm®ram ��m®®mmm®ram App dx F(Page 1 d 8) Hart & Hickman, PC Appendix F Summary of Historical Monitored Natural Attenuation Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 ®®®®®®®®®®® Propionic Acid ��m®®mmm®ram ��m®®mmm®ram ��®m�mmmmmm Hexanoic Acid -Hexi Acid ��®m�mmmmmm Pentanoic Acid ��®m�mmmmmm ��®m�mmmmmm Total Volatile Fatty Acids ��m®®mmm®ram Tritium illydrogen-3 ��®m�mmmmmm tom' 't���®m�mmmmm® Notes; Results from 2003 through February 2021 obtained from La Bella Associates Water Quality Monitoring Report - February 2022 Event. Results from August 2021 obtained from Garrett & Moore, Inc. Water Quality Monitoring Report- August 2022 Event. Method detection limits vary between samples for fatty acid analysis, the higher method detection limit reported for each constituent for samples collected in February 2022 is shown. 1. MW-2, MW4R, and M W-6R samples collected on 10/05/22. 2. Monitoring well M WARR was Installed In September 2022 to replace abandoned monitoring well M W-3R. Data shown in the table prior to the September 2022 monitoring event for M W-3RR was collected from abandoned monitoring well M W-3R. mg/L - milligrams per Ilter, µg/L - micrograms per liter; nM = nanometers; --= Not applicable and/or Not Reported; ND = Not Detected; 1= Estimated concentration above the method detection limit and below the method reporting limit; S.U. - standard units; °C = degrees Celsius; pS/cm - mlcrosiemens per centimeter; mV - millivolts; NA = not analyzed; NS = not sampled; NI - Well not yet Installed. A,xx ix F(Page 8 of 8) Hart & Hickman, PC Appendix G Concentration vs. Time Charts 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS E11011 70.0 J 50.0 ho - 40.0 c a� v c 30.0 U 20.0 liIIIIA 0.0 1 07/19/18 Chart 1 114-Dioxane Concentrations vs. Time MW-3R, MW-4R, MW-5R, & MW-6R 02/04/19 08/23/19 03/10/20 09/26/20 04/14/21 10/31/21 05/19/22 12/05/22 Date Note: Non -detect values are graphed equal to the reporting limit. * MW-3R f M W-3RR MW-4R MW-5R MW-6R 2L Standard (3 µg/L) Chart 2 Vinyl Chloride vs. Time MW-5R 30 25 20 J C 0 41 15 f MW-5R c 2L Standard (0.03µg/L) 0 U 10 5 V A 0 03/20/03 09/05/05 02/22/08 08/10/10 01/26/13 07/15/15 12/31/17 06/18/20 12/05/22 Note: Non -detect values are graphed equal to the reporting limit. Date Chart 3 1,1-Dichloroethane vs. Time MW-SR 10 9 8 7 J 0.0 -A/ /VV w I c 0 5 BMW-5R c u 2L Standard (6 µg/L) 0 4 U 3 2 1 0-1 05/20/99 12/10/02 07/02/06 01/22/10 08/14/13 03/06/17 09/26/20 04/18/24 Note: Non -detect values are graphed equal to the reporting limit. Date