1803_CatawbaCo_BlackburnLF_March2022_FID1741337_20220712

ENR USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #:
'NC DENR I I Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6)
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i)
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
LaBella Associates (Joyce Engineering)
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: G. Van Ness Burbach, Ph.D., P.G. Phone: [phone]
E-mail: [e-mail]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Blackburn Resource 3993 Rocky Ford Rd 18-03 .0500 March 22-24, 2022
Recovery Facility Newton, NC .1600
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring a Detection Monitoring ❑X Assessment Monitoring ❑ Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑
Leachate monitoring data
Surface water monitoring data ❑
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points. dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
G. Van Ness Burbach, Ph.D., PG Senior Technical Consultant [phone]
Title (Area Code) Telephone Number
­51'7/12 1-91aD Affix NC LW sed/ Professional Geologist Seal
/ %tlq rhrr
Signature
12-D Oak Branch Dr, Greensboro, NC 27407
Facility Representative Address
C-07s2
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009
Date
.•''o��N
SEAL
1349 =
%�NESS

LaBeLLa
Powered by oartnershir).
July 12, 2022
Mr. Perry Sugg
Compliance Hydrogeologist
Division of Waste Management/Solid Waste Section
1646 Mail Service Center
Raleigh, NC 27699-1646
Via Email: [e-mail]
RE: Catawba County Blackburn Landfill, Permit # 18-03
March 2022 Semiannual Water Quality Monitoring Report
La Bella Project No. 2213190, Phase 02
Dear Perry:
On behalf of Catawba County, North Carolina, La Bella Associates is submitting the attached
Semiannual Water Quality Monitoring Report for the Blackburn Resource Recovery Facility (AKA, the
Blackburn Landfill) Permit Number 18-03. The 2022 first semiannual monitoring event was
performed on March 22-24, 2022. A NCDEQ Environmental Monitoring Reporting Form (EMRF) is
attached.
If we can provide any additional information, please contact me at [e-mail] or (336)
323-0092. Thank you.
Respectfully submitted,
La Bella Associates
Van Burbach, PhD, PG
Sr. Technical Consultant
Attachments: EMRF
Water Quality Monitoring Report
cc: Rodney Hamby, Catawba County
Pete Shonka, Catawba County
12 D Oak Branch Dr I Greensboro, NC 27407 1 p [phone]
www.labellapc.com

Prepared For:
Catawba County
Utilities and Engineering Department
Post Office Box 389
Newton, North Carolina 28658
Submitted by:
LaBella Associates
12D Oak Branch Drive
Greensboro, NC 27407
[phone]
NC License No. C-0782
LaBeRa
Powered by partnership.
March 2022 SEMIANNUAL
WATER QUALITY MONITORING REPORT
BLACKBURN RESOURCE RECOVERY FACILITY
Permit No. 18-03
J U LY 2022
PROJECT NO. 2213190

March 2022 Water Quality Monitoring Report
Blackburn Landfill, Permit # 18-03
Catawba County, North Carolina
TABLE OF CONTENTS
1.0
INTRODUCTION.............................................................................................................................1
1.1
Site Information..............................................................................................................................1
1.2
Site Geology and Hydrogeology......................................................................................................1
1.3
Regulatory Status............................................................................................................................2
2.0
FACILITY MONITORING PROGRAM...............................................................................................2
2.1
Groundwater Monitoring Program.................................................................................................2
2.2
Surface Water Monitoring Program...............................................................................................3
2.3
Leachate Monitoring Program........................................................................................................4
3.0
March 2022 SAMPLING EVENT...................................................................................................4
3.1
Field Work........................................................................................................................................4
3.1.1 Groundwater Monitoring................................................................................................................... 4
3.1.2 Surface Water Monitoring................................................................................................................. 5
3.1.3 Leachate Monitoring.........................................................................................................................5
3.1.4 Blanks................................................................................................................................................ 5
3.2
Laboratory Analysis and Quality Control........................................................................................5
4.0
HYDROGEOLOGICAL CONDITIONS...............................................................................................6
5.0
DATA ANALYSIS.............................................................................................................................7
5.1
Analytical Results for Groundwater and Comparison to Standards............................................7
5.1.1 MSW Unit 1 (Closed Unit).................................................................................................................. 7
5.1.2 MSW Units 2 and 3 (Subtitle D)........................................................................................................ 8
5.1.3 C&D Unit 1 (Closed) and Unit 2 (Active)........................................................................................... 8
5.1.4 Dissolved Metals............................................................................................................................... 8
5.3
Analytical Results for Surface Water and Comparison to Standards..........................................8
5.4
Leachate Data Analyses.................................................................................................................9
5.5
Statistical Analyses.........................................................................................................................9
6.0
CONCLUSIONS..............................................................................................................................9
7.0
REFERENCES................................................................................................................................9
March 2022 Water Quality Monitoring Report LaBella Associates
Catawba County Blackburn Landfill, Permit No. 18-03 July 2022
i

Tables
Figure
March 2022 Water Quality Monitoring Report
Blackburn Landfill, Permit # 18-03
Catawba County, North Carolina
TABLE OF CONTENTS (CONTINUED)
Table 1
Groundwater Elevations (March 2022)
Table 2
Field Parameters (March 2022)
Table 3
Groundwater Flow Velocities (March 2022)
Table 4A
MSW Unit 1 Detected Constituents (March 2022)
Table 4B
MSW Units 2 & 3 Detected Constituents (March 2022)
Table 4C
C&D Units 1 & 2 Detected Constituents (March 2022)
Table 4D
Surface Water Detected Constituents (March 2022)
Table 5
Exceedances of Standards (March 2022)
Table 6
Total Metals Analyses (March 2022)
Table 7
Detected Parameters in Leachate (March 2022)
Figure 1 Site Location Map
Drawing
Drawing 1 Groundwater Potentiometric Surface Map (March 2022)
Appendices
Appendix 1 Well Construction Data
Appendix 2 Field Data Logs
Appendix 3 Laboratory Analytical Reports
March 2022 Water Quality Monitoring Report LaBella Associates
Catawba County Blackburn Landfill, Permit No. 18-03 July 2022
ii

1.0 INTRODUCTION
1.1 Site Information
The Catawba County Blackburn Resource Recovery Facility (the facility) is owned and operated by
Catawba County under Solid Waste Permit No. 18-03. The facility property is located on Rocky Ford
Road, approximately six miles southwest of Newton, North Carolina. The approximate property
boundary and disposal area are indicated on a portion of the USGS 71/2 minute topographic map for
Reepsville, North Carolina (Figure 1). Four solid waste disposal units are maintained by Catawba
County at this facility, as shown on Drawing 1, including:
• Blackburn Landfill, Closed Portion (Unit 1): a closed, unlined, municipal solid waste (MSW)
landfill area, located in the south-central portion of the facility property.
• Blackburn Landfill, Subtitle D Facility (Units 2 and 3): an active, lined, MSW landfill on the
south side of North Carolina Route 2019, contiguous to the north of Unit 1.
• New construction and demolition (C & D) Landfill (C & D Unit 2): located to the south of the
active Subtitle D disposal area and west of the Closed Unit 1.
• Old C & D Landfill (C & D Unit 1), a closed C & D landfill located across Route 2019 to the
north of the active Subtitle D disposal area.
1.2 Site Geology and Hydrogeology
The Blackburn Resource Recovery Facility is located within the Inner Piedmont Belt of the Piedmont
Physiographic Province. The bedrock of the Inner Piedmont Belt is characterized by medium to high
grade metamorphic rocks ranging from marble to schist to gneiss, intruded by varying age plutons. A
surface layer of saprolite over a transition zone of partially weathered bedrock, covers most of the
area. In the Piedmont, the thickness of saprolite averages about 52 feet, and in some cases, may
exceed depths of 100 feet (Daniel, 1990). The Inner Piedmont is bounded on the northwest by the
Brevard Fault zone and on the southeast by the Kings Mountain Belt and faults and shear zones that
define the central Piedmont structure.
Rock units depicted on the North Carolina Geologic Survey - Geologic Map of North Carolina (1985)
in the vicinity of the Blackburn Landfill Facility include interlayered; minor layers and lenses of
hornblende gneiss, metagabbro, mica schist, and granitic rock of the Inner Piedmont, Chauga Belt,
Smith River Allochthon, and Sauratown Mountain belts. Based on observations and data collection
during previous subsurface exploration at the site, the site geology appears to be consistent with the
regional mapping described on the Geologic Map of North Carolina, and rock cores were all
described as biotite gneiss with localized granite masses. No outcrop was encountered on the site
(CDM-Smith, 2018).
Groundwater flow at the facility, as is typical for the Inner Piedmont Belt, is primarily within the
saprolite and the partially weathered bedrock (transition zone); however, some flow also occurs
along major fractures within the competent bedrock. The uppermost aquifer includes all three
zones. The water table typically reflects topography, and groundwater flows from the higher
topography (recharge areas) to the valleys where it discharges to perennial creeks, which flow to the
South Fork of the Catawba River, located east of the facility. The South Fork of the Catawba River is
classified WS-V, for waters protected as water supplies which are generally upstream and draining to
Class WS-IV waters or waters used by industry to supply their employees with drinking water or as
waters formerly used as water supply. These waters are also protected for Class C uses.
March 2022 Water Quality Monitoring Report LaBella Associates
Catawba County Blackburn Landfill, Permit No. 18-03 July 2022
1

1.3 Regulatory Status
Catawba County completes water quality monitoring at the Blackburn Landfill in accordance with the
North Carolina Solid Waste Management Regulations (NCSWMR - 15A NCAC 13B) § 1633 (Detection
Monitoring Program) for all units except the Closed MSW Unit 1. MSW Unit 1 is monitored under an
Assessment Monitoring program, as described under NCSWMR § 1634. In February 2019, NCDEQ
approved a reduction in the required Assessment Monitoring requirements, eliminating the
requirement for annual NC Appendix II sampling.
Surface water at the facility is monitored semiannually in accordance with NCSWMR § 0602 in
conjunction with the groundwater monitoring events. The facility's leachate is also sampled during
each semiannual event.
The facility currently monitors groundwater and surface water for the constituents listed in 40 CFR
Part 258 Appendix I, incorporated by reference into the NCSWMR (NC Appendix 1), plus 1,4-dioxane
for all of the MSW units. The C&D Units are monitored for NC Appendix I VOCs, 8 RCRA metals,
tetrahydrofuran (THF), and 1,4-dioxane.
2.0 FACILITY MONITORING PROGRAM
2.1 Groundwater Monitoring Program
Water quality monitoring is conducted semiannually at the facility, typically in March and September.
Well MW-20 serves as the upgradient background monitoring well for MSW Unit 1, MSW Unit 2, MSW
Unit 3, and C&D Unit 1. MW-21 serves as the background well for C&D Unit 2.
The Unit 1 compliance monitoring network includes wells MW-5, MW-5A, MW-6, MW-6D, MW-7, and
MW-11. Two piezometers, PZ-85B and PZ-86B, located along the eastern side of Unit 1, are
included in the network in order to monitor impacts of landfill gas from the closed area to
groundwater in the vicinity.
The Unit 2 monitoring network includes wells MW-12R, MW-13, MW-14, MW-15, MW-16, and
MW- 17. Well MW-12 was replaced with MW-12R prior to the second semiannual 2019 event due to
damage to the inner well casing of MW-12 that prevented purging of the well.
The Unit 3 monitoring network includes wells MW-31R, MW-32, MW-33R, MW-35, and MW-36. Well
MW-34 was removed in preparation for construction of expansion cell Unit 3, Phase 2. Well MW-33
was damaged by a vehicle and had to be repaired prior to the second semiannual event of 2020,
which changed the elevation of the top of casing, and the well was renamed MW-33R.
The C&D Unit 1 monitoring system includes wells MW-2, MW-26, and MW-27. The C&D Unit 2
compliance wells include MW-24, MW-25, MW-28, MW- 29, and MW-30. In addition to the above
groundwater sampling points, several wells across the site are used only for water level monitoring.
The following table summarizes the groundwater monitoring network and shows the analytical
parameters currently required for each well. The locations of the monitoring wells are shown on
Drawing 1 and the well construction data are included in Appendix 1.
March 2022 Water Quality Monitoring Report LaBella Associates
Catawba County Blackburn Landfill, Permit No. 18-03 July 2022
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Well ID
Classification
Monitoring Program
Required Analyses
MW-20
Background
(MSW Units 1,2,&3, C&D Unit 1)
Assessment
NC Appendix I
& 1,4-Dioxane
M W-5
MSW- Unit 1 Compliance
Assessment
NC Appendix I
& 1,4-Dioxane
M W-5A
M W-6
MW-6D
MW-7
M W-11
PZ-85 B
PZ-86B
MW-12R
MSW-Unit 2 Compliance
Detection
NC Appendix I
& 1,4-Dioxane
M W-13
MW-14
MW-15
M W-16
M W-17
M W-31R
MSW Unit 3 Compliance
Detection
NC Appendix I
& 1,4-Dioxane
M W-32
MW-33R
MW-35
M W-36
MW-2
C&D Unit 1 Compliance
Detection
NC Appendix I VOCs;
8 RCRA metals; THF;
& 1,4-Dioxane
MW-26
MW-27
MW-21
Background (C&D Unit 2 only)
Detection
NC Appendix I VOCs;
8 RCRA metals; THF;
& 1,4-Dioxane
M W-24
C&D Unit 2 Compliance
MW-25
MW-28
M W-29
M W-30
2.2 Surface Water Monitoring Program
The surface water monitoring program for the facility includes seven sampling locations associated
with the three MSW units as follows:
• Unit 1- Surface water locations SMP-1 and SMP-3;
• Unit 2 - Underdrains U-1, U-2, and U-3; and
• Unit 3 - Surface water locations SMP-4 and SMP-5.
SMP-1 and SMP- 3 are located on the intermittent creek that runs along the west side of MSW Units
1 and 2 and the east side of C&D Unit 2. SMP-3 is the upstream location and SMP-1 is downstream.
U-1, U-2, and U-3 are located at the base of the western slope of MSW Unit 2, upgradient of SMP-3.
SMP-4 is located on an intermittent creek downstream from the sedimentation basin east of MSW
Unit 3. SMP-5 is located on an intermittent creek east of MSW Unit 1. The locations of these
sampling points are shown on Drawing 1. Surface water at the facility is sampled semiannually in
conjunction with the groundwater monitoring events. All surface water samples are analyzed for NC
Appendix I parameters and 1,4-dioxane.
March 2022 Water Quality Monitoring Report LaBella Associates
Catawba County Blackburn Landfill, Permit No. 18-03 July 2022
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The surface water at the facility flows offsite to the South Fork of the Catawba River, located east of
the facility. The South Fork of the Catawba River is classified WS-V, which are waters protected as
water supplies which are generally upstream and draining to Class WS-IV waters, or waters used by
industry to supply their employees with drinking water, or as waters formerly used as water supply.
2.3 Leachate Monitoring Program
The facility's leachate is also sampled during each semiannual event. Leachate is sampled directly
from the facility's leachate collection system, shown on Drawing 1. The leachate sample is analyzed
for NC Appendix I parameters, COD, BOD, nitrate, sulfate, and orthophosphate.
3.0 March 2022 SAMPLING EVENT
3.1 Field Work
3.1.1 Groundwater Monitoring
On March 22-24, 2022, personnel from Labella Associates, visited Blackburn Landfill to conduct the
first semiannual sampling event of 2022 (March 2022 Sampling Event). The sampling event
included obtaining water levels to the nearest 0.01 foot, purging the wells, and collecting
groundwater samples from twenty-nine monitoring wells, included all of the wells described in
Section 2.1 above. The water level data and calculated groundwater elevations are presented in
Table 1.
Monitoring wells were purged and sampled using either disposable bailers or a 12-volt submersible
pump. Measurements of temperature, pH, specific conductivity, dissolved oxygen, oxidation
reduction potential, and turbidity were recorded prior to purging, after each purge volume, and prior
to sampling. Copies of the field data logs are presented in Appendix 2 and the field parameters are
summarized in Table 2.
Prior to sampling, laboratory -supplied containers were prepared with the following information:
• Monitoring well number (completed by laboratory/field personnel);
• Date and time of sample collection (completed by laboratory/field personnel);
• Initials of sampling personnel (completed by laboratory/field personnel);
• Project name and number (completed by the laboratory/field personnel);
• Chemical preservative (completed by the laboratory/field personnel); and
• Requested chemical analysis (completed by the laboratory/field personnel).
Groundwater samples from each monitoring well were collected directly from the bailers or pump in
the laboratory -provided containers within 24 hours of the final purge volume. Immediately after
collection, the samples were placed in a laboratory -provided cooler and chilled on ice for transport to
the laboratory.
In addition to samples for total metals analyses (whether Appendix I metals or RCRA metals), filtered
samples for dissolved metals analyses were obtained from some wells which exhibited high turbidity.
These samples were sent to the laboratory with instructions to hold them and not run the dissolved
metals analyses until after the results for the total metals analyses were available.
March 2022 Water Quality Monitoring Report LaBella Associates
Catawba County Blackburn Landfill, Permit No. 18-03 July 2022
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3.1.2 Surface Water Monitoring
During the March 2022 Sampling Event, surface water points SW-3, SW-4, and SW-5 were sampled.
Surface water point SW-1, and underdrains U-1, U-2, and U-3 were either dry or had no flow and
could not be sampled. The surface water samples were collected by submerging a clean,
unpreserved sample jar into the stream flow, being careful to avoid sampling -induced turbidity, and
then dispensing the sample into the laboratory -prepared containers. The samples were then placed
in a cooler and chilled on ice. Copies of the field data logs are presented in Appendix 2 and the field
parameters are summarized in Table 2.
3.1.3 Leachate Monitoring
Leachate samples were collected from the leachate sampling port on the back of leachate tank #2
during the March 2022 Sampling Event. Prepared sampling containers were filled directly from the
port, placed in a cooler, and chilled on ice. At the time of sampling, leachate was measured for
temperature, pH, specific conductivity, dissolved oxygen, oxidation reduction potential, and turbidity.
Copies of the field data logs are presented in Appendix 2 and the field parameters are summarized
in Table 2.
3.1.4 Blanks
In addition to samples collected for compliance monitoring at the Blackburn Landfill, a Trip Blank
that was prepared by the laboratory accompanied the volatile sampling containers to and from the
laboratory. The Trip Blank was analyzed for NC Appendix I volatile organics plus THE and 1,4-
dioxane. A Field Blank was not collected by LaBella personnel as part of the March 2022 Sampling
Event due to a laboratory error.
3.2 Laboratory Analysis and Quality Control
The groundwater, surface water, and leachate samples collected during the March 2022 Sampling
Event were submitted to ENCO Laboratories, Inc. of Cary, North Carolina under chain -of -custody
control for analysis. LaBella requested a Level II data report for the final laboratory reports.
According to the laboratory reports, the samples were received by the laboratory on March 25, 2022,
in good condition, properly preserved, at the required temperature, and within the hold times for
each analytical method.
The complete laboratory analytical data packages and chains of custody are included in Appendix 3.
Upon receipt of the laboratory data packages, the data was reviewed by LaBella personnel for the
following:
• General typographical errors;
• Correct analyses performed and within method specified hold times;
• Biased data results based on Matrix Spike, Matrix Spike Duplicate, and Laboratory
Control Samples;
• Blank qualified data (B-flags); and
• Groundwater detections above the 15A NCAC 2L.0202 (NC2L) Groundwater Standards.
• Surface water detections above the 15A NCAC 2B (NC2B) Surface Water Standards, the
NC In -Stream Target Values (ISTV), or the EPA National Recommended Water Quality
Criteria (NRWQC).
March 2022 Water Quality Monitoring Report LaBella Associates
Catawba County Blackburn Landfill, Permit No. 18-03 July 2022
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After initial review of the total metals analytical results, LaBella requested that ENCO run the
dissolved metals analyses for barium in MW-27, cobalt in MW-6, MW-7, and MW-11, and chromium
in MW-6, MW-24, and MW-29. These were the metals detected in exceedance of the NC21-
standards in the total metals analyses.
4.0 HYDROGEOLOGICAL CONDITIONS
Depth to groundwater was measured in the compliance monitoring wells at the site prior to purging.
The groundwater elevations were calculated by subtracting the depth to groundwater from the
surveyed measuring point elevation (top of casing) at each monitoring well. Groundwater elevations
from the March 2022 Sampling Event are presented in Table 1. The groundwater elevation contours
shown on Drawing 1 are based on data from the March 2022 Sampling Event
The estimated horizontal groundwater gradients along the flow paths shown on Drawing 1 were
calculated using the data from the March 2022 Sampling Event are presented in Table 3. The
estimated horizontal groundwater gradients (i) range from 0.025 to 0.052 with an average horizontal
gradient of 0.034.
Hydraulic conductivities (K) and effective porosities (ne) were taken from the First Semiannual 2021
Groundwater Monitoring Report for the facility (Pace, March 2022), with the assumption that these
values were derived from slug tests and porosity tests, respectively, from the facility monitoring
wells; however, the specific source for these values was not cited. A hydraulic conductivity of K = 7.7
x 10-4 cm/sec was used for MSW Units 2 and 3. A hydraulic conductivity of K = 1.9 x 10-3 cm/sec
was used for MSW Unit 1 and C&D Units 1 and 2. An effective porosity of 21% (ne = 0.21) was used
for the whole facility.
Linear groundwater flow velocities for wells screened in saprolite were computed using the following
modified Darcy equation:
where:
V = KI/ne,
V = average linear velocity (feet per day - ft/day);
K = hydraulic conductivity (ft/day);
i = horizontal hydraulic gradient; and
ne = effective porosity.
Based on calculations from the March 2022 Sampling Event, the estimated linear groundwater flow
velocity for the site ranges from 97 feet/year to 486 feet/year with an average of 281 feet/year
(Table 3). This falls within the range of historical estimates for groundwater flow velocities at this
site.
The linear velocity equation and resulting rates are based on simplified assumptions of a
homogeneous, isotropic, porous aquifer. This equation may yield inaccurate velocities when applied
to heterogeneous and/or anisotropic conditions such as may exist at this site. The regolith and
fractured bedrock common in Piedmont terrain are characteristically heterogeneous and often
exhibit some anisotropy.
March 2022 Water Quality Monitoring Report LaBella Associates
Catawba County Blackburn Landfill, Permit No. 18-03 July 2022
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5,0 DATA ANALYSIS
The complete analytical data packages from the March 2022 Sampling Event were received from
ENCO Laboratories, Inc., on April 12, 2022. The complete data packages and chains of custody are
included in Appendix 3.
5.1 Analytical Results for Groundwater and Comparison to Standards
Analytical results from groundwater samples were compared directly to applicable groundwater
protection standards (GPS), which are the North Carolina Groundwater Standards found in 15A NCAC
02L.0202 (NC2L Standards). Note that estimated concentrations below the Method Reporting Limit
(MRL) are not considered exceedances of the standard, even if the estimated value is higher than
the standard. Tables 4A-4C summarize the constituents detected in all monitoring wells and Table 5
summarizes all the constituents detected in exceedance of their respective standards during the
March 2022 sampling event.
5.1.1 MSW Unit 1(Closed Unit)
Table 4A presents the constituents detected in the monitoring wells and piezometers associated
with the closed MSW Unit 1. The inorganic constituents detected in the Unit 1 wells and piezometers
at quantified concentrations above the method reporting limit (MRL) during the March 2022
Sampling Event include: barium (all wells), chromium (MW-6), cobalt (MW-6, MW-7, MW-11), and
nickel (MW-6).
The organic constituents detected in the Unit 1 wells and piezometers at quantified concentrations
above the MRL during the March 2022 sampling event include: 1,1-dichloroethane (MW-5, MW-5A,
MW-6, MW-6D, PZ-85B, PZ-86B), cis-1,2- dichloroethylene (MW-5, MW-5A, MW-11, PZ-85B, PZ-86B),
1,2-dichloropropane (PZ-86B), 1,4-dichlorobenzene (MW-5, MW-5A, MW-6, MW-7, MW-11, PZ-86B),
1,4-dioxane (MW-5, MW-6, MW-6D), benzene (MW-5, MW-5A, MW-6, MW-7, MW-11, PZ-86B),
chlorobenzene (MW-5, MW-6, MW-7, MW-11, PZ-86B), dichlorodifluoromethane (MW-5, MW-6),
methylene chloride (MW-5, MW-5A, PZ-86B), tetrachloroethylene (MW-5, MW-5A, MW-6, PZ-85B,
PZ-86B), trichloroethylene (MW-5, MW-5A, MW-6, PZ-85B, PZ-86B), trichlorofluoromethane (MW-6),
and vinyl chloride (MW-6, PZ-86B).
Of the quantified detections in Unit 1 monitoring wells and piezometers, the following constituents
were detected in exceedance of their respective GPS (see Table 5):
• Chromium (MW-6);
• Cobalt (MW-6, MW-7, MW-11);
• 1,1-Dichloroethane (MW-5, MW-5A, MW-6, PZ-86B);
• 1,4-DichIorobenzene (MW-6, MW-7);
• 1,4-Dioxane (MW-5, MW-6, MW-6D);
• 1,2-dichloropropane (PZ-86B);
• Benzene (MW-5, MW-5A, MW-6, MW-7, MW-11, PZ-86B);
• Methylene Chloride (PZ-86B);
• Tetrachloroethylene (MW-5, MW-5A, MW-6, PZ-85B, PZ-86B);
• Trichloroethene (MW-5, MW-5A, MW-6, PZ-85B, PZ-86B); and
• Vinyl Chloride (MW-6, PZ-86B).
March 2022 Water Quality Monitoring Report LaBella Associates
Catawba County Blackburn Landfill, Permit No. 18-03 July 2022
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5.1.2 MSW Units 2 and 3 (Subtitle D)
Table 48 presents the constituents detected in the monitoring wells associated with Subtitle D MSW
Units 2 and 3. The only inorganic constituent detected in the Subtitle D wells at quantified
concentrations above the MRL during the March 2022 Sampling Event was barium (all wells). There
were no organic constituents with quantified detections above the MRL.
There were no constituents detected in exceedance of their respective GPS were (See Table 5):
5.1.3 C&D Unit 1(Closed) and Unit 2 (Active)
Table 4C presents the constituents detected in the monitoring wells associated with C&D landfill
Units 1 and 2. The inorganic constituents detected in the C&D wells at quantified concentrations
above the MRL during the March 2022 sampling event include: barium (MW-2, MW-20, MW-21,
MW-26, MW-27, MW-24, MW-25, MW-28, MW-29, MW-30); and chromium (MW-24, MW-29).
The organic constituents detected in the C&D wells at quantified concentrations above the MRL
during the March 2022 sampling event include 1,4-dioxane (MW-2, MW-27, MW-24, MW-25,
MW-28); benzene (MW-24, MW-25); and tetrahydrofuran (MW-24, MW-25).
Of the quantified detections in the C&D monitoring wells, the following constituents were detected in
exceedance of their respective GPS (see Table 5):
• 1,4-dioxane (MW-2, MW-24, MW-25, MW-28);
• Barium (MW-27);
• Benzene (MW-24, MW-25);
• Chromium (MW-24, MW-29); and
• Tetrahydrofuran (MW-24, MW-25).
5.1.4 Dissolved Metals
Field -filtered samples were collected for dissolved metals analyses for all wells in the field. The
laboratory was instructed to hold these samples pending the results of the total metals analyses.
Upon review of the total metals results, the laboratory was instructed to run dissolved metals
analyses for barium in MW-27; chromium in MW-6, MW-24, and MW-29; and cobalt in MW-6, MW-7,
and MW-11. The results of the dissolved metals analyses are presented in Table 6, and the
complete laboratory analytical reports are included in Appendix 3.
Chromium in MW-29, cobalt in MW-11, and barium in MW-27 presence came back higher in the
dissolved metal samples than in the total metals samples. All other dissolved metal samples
showed a decrease in concentrations compared to their total metal counterparts; however, only
dissolved chromium in MW-6 and MW-24 were below the NC21L Standard.
5.3 Analytical Results for Surface Water and Comparison to Standards
Analytical results from surface water samples were compared directly to applicable surface water
standards, which are either the North Carolina Surface Water Standards found in 15A NCAC 02B
(NC2B Standards), the NCDEQ Instream Target Values (ISTVs) for constituents with no listed NC2B
Standard, or the US -EPA National Recommended Water Quality Criteria (NRWQC) for constituents
with no listed NC2B Standard or ISTV.
Surface water standards for a given constituent vary depending on the classification of the water
body. The surface water at the facility flows offsite to the South Fork of the Catawba River, which is
March 2022 Water Quality Monitoring Report LaBella Associates
Catawba County Blackburn Landfill, Permit No. 18-03 July 2022
8

classified WS-V, for waters protected as water supplies which are upstream of Class WS-IV waters,
used by industry to supply their employees with drinking water, or waters formerly used as water
supply. Therefore, the standards applied to the results for this facility were the standards for fresh
water supplies or freshwater fish consumption, whichever was lower. In addition, for some
constituents, there are standards for both acute and chronic exposure; in which case the lower of the
two standards was used. For several metals, the NC213 standards are dependent on hardness;
therefore, all surface water samples were analyzed for hardness in addition to the required analyses,
and the standards were calculated based on the hardness for each sample.
Table 4D summarizes the constituents detected in all surface water samples during the March 2022
sampling event, and constituents detected in exceedance of their respective standards are included
in Table 5. Note that estimated concentrations below the Method Reporting Limit (MRL) are not
considered exceedances of the standard, even if the estimated value is higher than the standard.
The only inorganic constituent detected at quantified concentrations above the MRL in surface water
samples was barium (all samples). There were no organic constituents detected at quantified
concentrations above the MRL in surface water samples. No constituents were detected in
exceedance of their respective surface water standards during the March 2022 Sampling Event.
5.4 Leachate Data Analyses
Concentrations of constituents and parameters reported for the leachate sample collected during
the March 2022 sampling event are summarized in Table 7. The leachate results are consistent
with historical data. The complete laboratory analytical report for leachate is included in Appendix 3.
5.5 Statistical Analyses
No statistical Analyses were performed for this report.
6.0 CONCLUSIONS
The groundwater analytical results for all units at the Blackburn Landfill from the March 2022
Sampling Event are generally consistent with historical data. There were numerous GPS
exceedances across the site as a whole.
We recommend that the Blackburn Landfill MSW Unit 1 remain in modified Assessment Monitoring
and that the rest of the facility remain in the Detection Monitoring program. The next semiannual
sampling event is tentatively scheduled for September 2022.
7.0 REFERENCES
Brown, Philip M., Chief Geologist, 1985, Geologic Map of North Carolina, The North Carolina Geologic
Survey, scale 1:500,000.
CDM Smith, Inc., 2017. Blackburn Resource and Recovery Facility - Unit 3, Phase 2, Desion
Hvdrogeologic Report.
CDM Smith, Inc., March 2018. Blackburn Resource and Recovery Facility Water Quality Monitoring
Plan.
March 2022 Water Quality Monitoring Report LaBella Associates
Catawba County Blackburn Landfill, Permit No. 18-03 July 2022
9

Daniel, III, C.C., 1990. Evaluation of Site -Selection Criteria, Well Design, Monitoring Techniques, and
Cost Analysis for a Groundwater Supply in Piedmont Crystalline Rocks. North Carolina, USGS Water
Supply Paper 2341, 35 p.
Goldsmith, R., et. al., 1988. Geologic Map of the Charlotte 10x20 Quadrangle, North Carolina. USGS
Miscellaneous Map Series 1-251E, 1:250,000.
Heath, R.C., 1989, The Piedmont Ground -Water System, in Ground Water in the Piedmont; Edited by
Daniel, C., White, R., and Stone, P., Proceedings published by Clemson University, pp. 1-13.
McGill Associates, 2007. Permit No. 18-03 Catawba County, Permit to Construct Municipal Solid
Waste Landfill, Unit 3, Phase 1.
North Carolina Dept. Environment, Health, and Natural Resources (NCDEHNR), 1995, Draft N.C.
Water Quality Monitoring Guidance Document for Solid Waste Facilities.
Pace Analytical Services, March 2021. 2nd Semiannual 2020 Groundwater Monitoring Report -
Blackburn Landfill.
March 2022 Water Quality Monitoring Report LaBella Associates
Catawba County Blackburn Landfill, Permit No. 18-03 July 2022
10

TABLES
Table 1
Table 2
Table 3
Table 4A
Table 413
Table 4C
Table 4D
Table 5
Table 6
Table 7
Groundwater Elevations (March 2022)
Field Parameters (March 2022)
Groundwater Flow Velocities (March 2022)
MSW Unit 1 Detected Constituents (March 2022)
MSW Units 2&3 Detected Constituents (March 2022)
C&D Units 1&2 Detected Constituents (March 2022)
Surface Water Detected Constituents (March 2022)
Exceedances of Standards (March 2022)
Dissolved Metals Analyses (March 2022)
Leachate Detected Parameters (March 2022)

TABLE 1: Groundwater Elevations (March 2022)
Well ID
TOC Elev.
(Ft-AMSL)
DTW
(Ft-BTOC)
GW Elev.
(Ft-AMSL)
UNIT 1(Closed)
MW-5
823.32
5.70
817.62
MW-5A
822.79
4.97
817.82
MW-6
829.36
5.55
823.81
MW-6D
829.93
4.92
825.01
MW-7
842.49
10.55
831.94
MW-11
852.25
15.75
836.50
M W-20
929.92
36.97
892.95
PZ-85B
879.89
18.56
861.33
PZ-86B
867.24
31.96
835.28
UNIT 2 (Subtitle D)
MW-12R
852.89
17.80
835.09
M W-13
842.61
5.93
836.68
MW-14
844.52
5.99
838.53
MW-15
846.11
8.81
837.30
MW-16
857.16
j 6.70
j 850.46
MW-17
867.69
1 7.10
860.59
UNIT 3 (Subtitle D)
MW-31R
887.50
20.80
866.70
MW-32
884.71
22.16
862.55
MW-33R
882.22
17.70
864.52
MW-35
905.46
32.24
873.22
MW-36
880.15
13.58
866.57
Old C&D Unit 1
MW-2
866.65
16.75
849.90
M W-3
848.98
4.55
844.43
MW-26
871.20
3.42
867.78
MW-27
862.08
11.57
850.51
New C&D Unit 2
MW-21
924.85
48.03
876.82
MW-24
842.34
11.12
831.22
MW-25
830.31
5.14
825.17
MW-28
825.31
3.76
821.55
MW-29
839.26
8.94
830.32
MW-30
847.26
14.88
832.38
TOC Elev. = Top of Casing Elevation Ft-AMSL = Feet above mean sea level
DTW = Depth to Water (static) Ft-BTOC = Feet below top of casing
GW Elev. = Groundwater Elevation
DTW Measurments made on March 22-24, 2022.
Catawba Co. - Blackburn Landfill
Permit # 18-03 LaBella Associates

TABLE 2: Field Parameters (March 2022)
SAMPLE ID
PARAMETER
RESULT
UNITS
SAMPLE DATE
Groundwater
Temperature
16.8
°C
pH
6.26
S.U.
Conductivity
1309
PS/Cm
DO
0.46
mg/L
MW-2
3/23/2022
ORP
61.2
mv
Turbidity
15.5
NTU
Static Water Level
16.75
ft-btoc
Well Depth
23.99
ft-btoc
Temperature
16.9
°C
pH
6.35
S.U.
Conductivity
243.6
PS/Cm
DO
0.0
mg/L
MW-5A
3/22/2022
ORP
44.1
my
Turbidity
1.14
NTU
Static Water Level
4.97
ft-btoc
Well Depth
48.40
ft-btoc
Temperature
14.5
°C
pH
6.92
S.U.
Conductivity
313.3
PS/Cm
DO
0.70
mg/L
MW-5
3/23/2022
ORP
98.4
my
Turbidity
2.81
NTU
Static Water Level
5.70
ft-btoc
Well Depth
17.69
ft-btoc
Temperature
16.4
°C
pH
6.30
S.U.
Conductivity
1387
PS/CM
0.10
mg/L
MW-6
ARP
3/22/2022
mv
Turbidity
13.2
NTU
Static Water Level
5.55
ft-btoc
Well Depth
17.60
ft-btoc
Temperature
18.1
°C
pH
7.05
S.U.
Conductivity
190.2
PS/Cm
MW-6D
DO
-----
mg/L
3/22/2022
ORP
44.4
my
Turbidity
1.03
NTU
Static Water Level
4.92
ft-btoc
Well Depth
53.35
ft-btoc
LaBella Associates
Catawba Co., Blackburn Landfill
Permit # 18-03 1 of 7

TABLE 2: Field Parameters (March 2022)
SAMPLE ID
PARAMETER
RESULT
UNITS
SAMPLE DATE
Temperature
16.3
°C
pH
6.36
S.U.
Conductivity
650
PS/Cm
DO
.8
MW-7
ORPTurbidity
1 9
g/L
3/23/2022
4.17
NTU
Static Water Level
10.55
ft-btoc
Well Depth
17.40
ft-btoc
Temperature
17.8
°C
pH
5.86
S.U.
Conductivity
330.9
PS/Cm
DO
00.07
mg/L
MW-11
ORPTurbidity
3/22/2022
9.13
NTU
Static Water Level
15.75
ft-btoc
Well Depth
26.60
ft-btoc
Temperature
18.5
°C
pH
6.02
S.U.
Conductivity
303.1
PS/Cm
DO
18
mg/L
MW-12R
3/23/2022
Turbidity
26.9
NTU
Static Water Level
17.8
ft-btoc
Well Depth
22.95
ft-btoc
Temperature
13.1
°C
pH
6.38
S.U.
Conductivity
80.0
PS/Cm
DO
2.45
mg/L
MW-13
3/23/2022
ORP
127.4
mv
Turbidity
2.49
NTU
Static Water Level
5.93
ft-btoc
Well Depth
18.6
ft-btoc
Temperature
14.1
°C
pH
6.13
S.U.
Conductivity
60.2
PS/cm
DO
2.65
mg/L
MW-14
3/23/2022
ORP
140.0
mV
Turbidity
9.60
NTU
Static Water Level
5.99
ft-btoc
Well Depth
13.0
ft-btoc
Temperature
13.4
°C
pH
5.95
S.U.
Conductivity
92.7
PS/cm
D0
mg/L
MW-15
3/22/2022
ORP
2.15
mv
Turbidity
7.76
NTU
Static Water Level
8.81
ft-btoc
Well Depth
14.5
ft-btoc
LaBella Associates
Catawba Co., Blackburn Landfill
Permit # 18-03 2 of 7

TABLE 2: Field Parameters (March 2022)
SAMPLE ID
PARAMETER
RESULT
UNITS
SAMPLE DATE
Temperature
13.4
°c
pH
6.13
S.U.
Conductivity
67.6
PS/cm
DO
MW-16
g/L
3/23/2022
ORPTurbidity
1.79
20.4
NTU
Static Water Level
6.70
ft-btoc
Well Depth
21.77
ft-btoc
Temperature
13.9
°C
pH
6.46
S.U.
Conductivity
48.2
PS/cm
DO
1.62
mg/L
MW-17
3/23/2022
ORP
84.3mv
Turbidity
87.8
NTU
Static Water Level
7.10
ft-btoc
Well Depth
20.60
ft-btoc
Temperature
17.4
°C
pH
7.07
S.U.
Conductivity
87.1
PS/cm
DO
.2
mg/L
MW-20
3/23/2022
ORPTurbidity
1 9
19.0
NTU
Static Water Level
36.97
ft-btoc
Well Depth
50.63
ft-btoc
Temperature
16.1
°C
pH
6.07
S.U.
Conductivity
57.7
PS/Cm
DO
.5
mg/L
MW-21
3/23/2022
ORPTurbidity
2 2
8.58
NTU
Static Water Level
48.03
ft-btoc
Well Depth
62.63
ft-btoc
Temperature
15.0
°C
pH
6.47
S.U.
Conductivity
1749
PS/cm
DO
0.54
mg/L
MW-24
3/23/2022
ORP
244.5
mV
Turbidity
13.4
NTU
Static Water Level
11.12
ft-btoc
Well Depth
22.78
ft-btoc
Temperature
14.0
°C
pH
6.50
S.U.
Conductivity
1611
PS/cm
mg/L
MW-25
3/23/2022
ORP
14 0
Turbidity
9.25
NTU
Static Water Level
5.14
ft-btoc
Well Depth
13.94
ft-btoc
LaBella Associates
Catawba Co., Blackburn Landfill
Permit # 18-03 3 of 7

TABLE 2: Field Parameters (March 2022)
SAMPLE ID
PARAMETER
RESULT
UNITS
SAMPLE DATE
Temperature
12.9
°C
pH
7.04
S.U.
Conductivity
201.6
PS/cm
DO
.04
g/L
MW-26
3/23/2022
ORPmv
13.7
Turbidity
16.6
NTU
Static Water Level
3.42
ft-btoc
Well Depth
22.41
ft-btoc
Temperature
15.9
°C
pH
6.44
S.U.
Conductivity
3446
PS/cm
DO
mg/L
MW-27
3/23/2022
ORPTurbidity
93.1
13.6
NTU
Static Water Level
11.57
ft-btoc
Well Depth
28.0
ft-btoc
Temperature
12.7
°C
pH
6.10
S.U.
Conductivity
213.2
PS/Cm
DO
mL
MW-28
3/24/2022
ORP
2.52
m
Turbidity
7.80
NTU
Static Water Level
3.76
ft-btoc
Well Depth
14.92
ft-btoc
Temperature
13.4
°C
pH
6.17
S.U.
Conductivity
289.2
PS/Cm
DO
mg/L
MW-29
3/24/2022
ORP
2.41
mv
Turbidity
4.80
NTU
Static Water Level
8.94
ft-btoc
Well Depth
23.13
ft-btoc
Temperature
15.3
°C
pH
6.12
S.U.
Conductivity
162.1
PS/Cm
DO
0.92
mg/L
MW-30
3/24/2022
ORP
229.1
mV
Turbidity
23.3
NTU
Static Water Level
14.88
ft-btoc
Well Depth
22.85
ft-btoc
Temperature
16.9
°C
pH
5.96
S.U.
Conductivity
115.3
PS/cm
DO
.6
mg/L
MW-31R
3/24/2022
ORPTurbidity
2 2
18.1
NTU
Static Water Level
20.8
ft-btoc
Well Depth
32.20
ft-btoc
LaBella Associates
Catawba Co., Blackburn Landfill
Permit # 18-03 4 of 7

TABLE 2: Field Parameters (March 2022)
SAMPLE ID
PARAMETER
RESULT
UNITS
SAMPLE DATE
Temperature
16.0
°c
pH
5.89
S.U.
Conductivity
41.4
PS/cm
DO
mg/L
MW-32
3/24/2022
ORPTurbidity
2.19
114
NTU
Static Water Level
22.16
ft-btoc
Well Depth
32.75
ft-btoc
Temperature
16.5
°C
pH
5.75
S.U.
Conductivity
88.3
PS/cm
DO
mg/L
MW-33R
3/24/2022
ORPTurbidity
2.99
11.4
NTU
Static Water Level
17.7
ft-btoc
Well Depth
29.75
ft-btoc
Temperature
16.5
°C
pH
7.77
S.U.
Conductivity
47.8
PS/Cm
DO
.4
mg/L
MW-35
3/24/2022
ORPTurbidity
1 2
85.9
NTU
Static Water Level
32.24
ft-btoc
Well Depth
37.90
ft-btoc
Temperature
15.7
°C
pH
6.11
S.U.
Conductivity
40.1
PS/Cm
DO
6
mg/L
MW-36
3/24/2022
ORP
227
Turbidity
12.8
NTU
Static Water Level
13.58
ft-btoc
Well Depth
25.81
ft-btoc
Temperature
16.6
°C
pH
6.07
S.U.
Conductivity
151.3
PS/cm
DO
0.37
mg/L
PZ- 85B
3/23/2022
ORP
250.9
mV
Turbidity
6.8
NTU
Static Water Level
18.56
ft-btoc
Well Depth
44.0
ft-btoc
Temperature
16.2
°C
pH
6.12
S.U.
Conductivity
233.7
PS/cm
D0
0.87
mg/L
PZ-86B
3/23/2022
ORP
2415
Turbidity
2.49
NTU
Static Water Level
31.96
ft-btoc
Well Depth
52.78
ft-btoc
LaBella Associates
Catawba Co., Blackburn Landfill
Permit # 18-03 5 of 7

TABLE 2: Field Parameters (March 2022)
SAMPLE ID
PARAMETER
RESULT
UNITS
SAMPLE DATE
Surface Water
Temperature
DRY
°C
pH
DRY
S.U.
Conductivity
DRY
PS/Cm
U 1
3/23/2022
DO
DRY
mg/L
ORP
DRY
my
Turbidity
DRY
NTU
Temperature
DRY
°C
pH
DRY
S.U.
Conductivity
DRY
PS/Gm
U 2
3/23/2022
DO
DRY
mg/L
ORP
DRY
my
Turbidity
DRY
NTU
Temperature
DRY
°C
pH
DRY
S.U.
Conductivity
DRY
PS/Cm
U 3
3/23/2022
DO
DRY
mg/L
ORP
DRY
my
Turbidity
DRY
NTU
Temperature
DRY
°C
pH
DRY
S.U.
Conductivity
DRY
PS/cm
SMP 1
3/24/2022
DO
DRY
mg/L
ORP
DRY
my
Turbidity
DRY
NTU
Temperature
13.5
°C
pH
7.04
S.U.
Conductivity
72.8
PS/CM
SMP 3
3/24/2022
DO
7.07
mg/L
ORP
143.3
my
Turbidity
21.7
NTU
Temperature
13.7
°C
pH
6.91
S.U.
Conductivity
84.2
PS/cm
SMP 4
3/24/2022
DO
7.23
mg/L
ORP
143.5
my
Turbidity
30.9
NTU
Temperature
13.4
°C
pH
6.78
S.U.
Conductivity
75.7
PS/Cm
SMP 5
3/24/2022
DO
6.27
mg/L
ORP
126.4
my
Turbidity
34.4
NTU
LaBella Associates
Catawba Co., Blackburn Landfill
Permit # 18-03 6 of 7

TABLE 2: Field Parameters (March 2022)
SAMPLE ID
PARAMETER
RESULT
UNITS
SAMPLE DATE
Leachate
Temperature
7.08
°C
pH
17.0
S.U.
Conductivity
5642
PS/Cm
Leachate
3/24/2022
DO
0.0
mg/L
ORP
-89.4
my
Turbidity
52.5
NTU
Notes: °C = degrees Centigrade
S.U. = Standard Units
pS/cm = microSemens per centimeter
NTU = Nephelometric Turbidity Units
mg/L = milligrams per liter
my = millivolts
ft-btoc = feet below top of casing
LaBella Associates
Catawba Co., Blackburn Landfill
Permit # 18-03 7 of 7

TABLE 3: Hydraulic Gradients and Velocities (March 2022)
Water Levels Measured: March 22-24, 2022
LAN FDFI LL
UNIT
GRADIENT
CALCULATION
SEGMENT
FLOW LINE
LENGTH
(feet)
FLOW
DIRECTION
GROUNDWATER
ELEVATION
(feet)
HORIZONTAL
GRADIENT
i
HYDRAULIC
CONDUCTIVITY
K (cm/sec)
HYDRAULIC
CONDUCTIVITY
K (feet/year)
EFFECTIVE
POROSITY
n
LINEAR
VELOCITY
V (feet/year)
885
C&D Unit 1
I 1
991
NE
0.0303
1.90E-03
1.97E+03
0.21
283
855
885
MSW Units 2-3
12
1,562
SW
0.0256
7.70E-04
7.97E+02
0.21
97
845
875
C&D Unit 2
I g
964
E
0.0519
1.90E-03
1.97E+03
0.21
486
825
855
MSW Unit 1
1 q
1,096
SW
0.0274
1.90E-03
1.97E+03
0.21
256
825
AVERAGE:
0.0338
AVERAGE:
281
Notes:
Modified Darcy Equation: V = Kiln ; assumes a homogeneous, isotropic, porous aquifer.
K and n taken from Second Semiannual 2021 Groundwater Monitoring Report - Balckburn Landfill (Pace Analytical, September 2021).
Gradient segments based on the March 2022 groundwater potentiometric surface map (Drawing 1) .
La Bella Associates
Catawba County, Blackburn Landfill July 2022
Permit No. 18-03

TABLE 4A: MSW Unit 1 Detected Constituents (March 2022)
SAMPLE ID
PARAMETER
RESULTS
DILUTION
METHOD
MOIL
MRL
STANDARD
SOURCE
UNIT
COLLECTION DATE
Unit 1
Barium
202
1
6010D
1.1
1.1
700
NC 2L
pg/L
Cobalt
3.26 J
1
6010D
1.4
1.4
1
NC 2L
pg/L
1,1-Dichloroethane
9.2
1
8260D
0.13
0.13
6
NC 2L
pg/L
cis-1,2-Dichloroethylene
12
1
8260D
0.15
0.15
70
NC 2L
pg/L
1,4-Dichlorobenzene
3.2
1
8260D
0.19
0.19
6
NC 21
pg/L
MW-5
1,4-Dioxane
19
1
8260D
0.8
0.8
3
NC 2L
pg/L
3/23/2022
Benzene
1.8
1
8260D
0.15
0.15
1
NC 2L
pg/L
Chlorobenzene
2.1
1
8260D
0.17
0.17
50
NC 2L
pg/L
Dichlorodifluoromethane
13
1
8260D
0.2
0.2
1000
NC 21
pg/L
Methylene chloride
1.1
1
8260D
0.23
0.23
5
NC 2L
pg/L
Tetrachloroethylene
3.3
1
8260D
0.17
0.17
0.7
NC 21
pg/L
Trichloroethylene
7.6
1
8260D
0.15
1 0.15
3
NC 2L
pg/L
Barium
224
1
6010D
1.1
1.1
700
NC 2L
pg/L
Vanadium
6.04 J
1
6010D
1.4
1.4
7
NC 2L
pg/L
1,14Dichloroethane
6.2
1
8260D
0.13
0.13
6
NC 2L
pg/L
cis-1,2-Dichloroethylene
36
1
8260D
0.15
0.15
70
NC 2L
pg/L
MW-5A
IA-Dichlorobenzene
2.3
1
8260D
0.19
0.19
6
NC 2L
pg/L
3/22/2022
Benzene
1.7
1
8260D
0.15
0.15
1
NC 2L
pg/L
Methylene chloride
1.1
1
8260D
0.23
0.23
5
NC 2L
pg/L
Tetrachloroethylene
6.1
1
8260D
0.17
0.17
0.7
NC 2L
pg/L
Trichloroethylene
12
1
8260D
0.15
1 0.15
3
1 NC 21-
pg/L
Barium
328
1
6010D
1.1
1.1
700
NC 2L
pg/L
Chromium
11.5
1
6010D
1.4
1.4
10
NC 2L
pg/L
Cobalt
116
1
6010D
1.4
1.4
1
NC 2L
pg/L
Nickel
11.5
1
6010D
2.2
2.2
100
NC 2L
pg/L
Zinc
4.86 J
1
6010D
4.4
4.4
1000
NC 2L
pg/L
1,1-Dichloroethane
12
1
8260D
0.13
0.13
6
NC 2L
pg/L
1,4-Dichlorobenzene
10
1
8260D
0.19
0.19
6
NC 2L
pg/L
1,4-Dioxane
100
5
8260D
4
4
3
NC 2L
pg/L
MW-6
Benzene
4
1
8260D
0.15
0.15
1
NC 2L
pg/L
3/22/2022
Chlorobenzene
4.6
1
8260D
0.17
0.17
50
NC 2L
pg/L
Dichlorodifluoromethane
3.8
1
8260D
0.2
0.2
1000
NC 2L
pg/L
o-Dichlorobenzene
0.55 J
1
8260D
0.19
0.19
0.19
MRL
pg/L
Tetrachloroethylene
2.2
1
8260D
0.17
0.17
0.7
NC 2L
pg/L
Trichloroethylene
3.3
1
8260D
0.15
0.15
3
NC 21
pg/L
Trichlorofluoromethane
9.2
1
8260D
0.24
0.24
2000
NC 2L
pg/L
Vinyl chloride
2.7
1
8260D
0.32
0.32
0.03
NC 21
pg/L
Xylenes
0.72 J
1
8260D
0.45
0.45
500
NC 2L
pg/L
Barium
118
1
6010D
1.1
1.1
700
NC 2L
pg/L
Vanadium
7.13 J
1
6010D
1.4
1.4
7
NC 2L
pg/L
MW-61)
1,1-Dichloroethane
2.2
1
8260D
0.13
0.13
6
NC 2L
pg/L
3/22/2022
1,4-Dioxane
5.0
1
8260D
0.8
0.8
3
NC 2L
pg/L
Methylene chloride
0.88 J
1
8260D
0.23
0.23
5
NC 2L
pg/L
Barium
262
1
6010D
1.1
1.1
700
NC 2L
pg/L
Chromium
4.88 J
1
6010D
1.4
1.4
10
NC 2L
pg/L
Cobalt
31.8
1
6010D
1.4
1.4
1
NC 2L
pg/L
Nickel
8.41 J
1
6010D
2.2
2.2
100
NC 2L
pg/L
Thallium
0.645 J
1
6020B
0.22
0.22
2
NC 2L
pg/L
MW-7
Zinc
4.86 J
1
6010D
4.4
4.4
1000
NC 2L
pg/L
3/23/2022
cis-1,2-Dichloroethylene
0.95 J
1
8260D
0.15
0.15
70
NC 2L
pg/L
1,4-Dichlorobenzene
7.6
1
8260D
0.19
0.19
6
NC 2L
pg/L
1,4-Dioxane
0.85 J
1
8260D
0.8
0.8
3
NC 2L
pg/L
Benzene
2.8
1
8260D
0.15
0.15
1
NC 2L
pg/L
Chlorobenzene
2.9
1
8260D
0.17
0.17
50
NC 2L
pg/L
Barium
224
1
6010D
1.1
1.1
700
NC 2L
pg/L
Cobalt
64.6
1
6010D
1.4
1.4
1
NC 2L
pg/L
Nickel
4.5 J
1
6010D
2.2
2.2
100
NC 2L
pg/L
Vanadium
3.1 J
1
6010D
1.4
1.4
7
NC 2L
pg/L
MW-11
Zinc
7.5 J
1
6010D
4.4
4.4
1000
NC 2L
pg/L
3/22/2022
cis-1,2-Dichloroethylene
2.1
1
8260D
0.15
0.15
70
NC 2L
pg/L
IA-Dichlorobenzene
5.1
1
8260D
0.19
0.19
6
NC 2L
pg/L
Benzene
7.1
1
8260D
0.15
0.15
1
NC 2L
pg/L
Chlorobenzene
8.2
1
8260D
0.17
0.17
50
NC 2L
pg/L
Catawba County, Blackburn Landfill La Bella Associates
Permit # 18-03 Page 1 of 2

TABLE 4A: MSW Unit 1 Detected Constituents (March 2022)
SAMPLE ID
PARAMETER
RESULTS
I DILUTION
METHOD
I MOIL
I MRL
I STANDARD
SOURCE
UNIT
COLLECTION DATE
AL Unit 1
Barium
79.3
1
6010D
1.1
1.1
700
NC 2L
pg/L
Chromium
6.36 J
1
6010D
1.4
1.4
10
NC 2L
pg/L
856
1,1-Dichloroethane
1.5
1
8260D
0.13
0.13
6
NC 2L
pg/L
3/23/2022
PZ
cis-1,2-Dichloroethylene
3.2
1
8260D
0.15
0.15
70
NC 2L
pg/L
Tetrachloroethylene
8.9
1
8260D
0.17
0.17
0.7
NC 2L
pg/L
Trichloroethylene
3.1
1
8260D
0.15
0.15
3
NC 2L
pg/L
Barium
115
1
6010D
1.1
1.1
700
NC 2L
pg/L
Vanadium
2.54 J
1
6010D
1.4
1.4
7
NC 2L
pg/L
1,1-Dichloroethane
16
1
8260D
0.13
0.13
6
NC 2L
pg/L
cis-1,2-Dichloroethylene
69
1
8260D
0.15
0.15
70
NC 2L
pg/L
1,2-Dichioropropane
4.6
1
8260D
0.1
0.1
0.6
NC 2L
pg/L
1,4-Dichlorobenzene
3.3
1
8260D
0.19
0.19
6
NC 2L
pg/L
PZ-86B
Benzene
2.3
1
8260D
0.15
0.15
1
NC 2L
pg/L
3/23/2022
Chlorobenzene
1.5
1
8260D
0.17
0.17
50
NC 2L
pg/L
Methylene chloride
6.4
1
8260D
0.23
0.23
5
NC 2L
pg/L
Tetrachloroethylene
27
1
8260D
0.17
0.17
0.7
NC 2L
pg/L
Trichloroethylene
30
1
8260D
0.15
0.15
3
NC 2L
pg/L
Vinyl chloride
2.3
1
8260D
0.32
0.32
0.03
NC 2L
pg/L
Xylenes
Barium
0.83 J1 1 1 8260D 1 0.45 1 0.45
Background MSW Unit 1,2, 3, and C&D Unit 1
47.8 1 6010D 1.1 1.1
500
700
1 NC 2L
NC 2L
pg/L
pg/L
Chromium
2.04 J
1
6010D
1.4
1.4
10
NC 2L
pg/L
MW-20
Cobalt
2.16 J
1
6010D
1.4
1.4
1
NC 2L
pg/L
3/23/2022
Copper
3.68 J
1
6010D
1.6
1.6
1000
NC 2L
pg/L
Vanadium
1.82 J
1
6010D
1.4
1.4
7
NC 2L
pg/L
Zinc
7.86 J
1
6010D
4.4
4.4
1000
NC 2L
pg/L
Notes: MDL= Method Detection Limit GPS = Groundwater Protection Standard
MRL= Method Reporting Limit NC21- = NC Groundwater Standard from 15A NCAC 2L.202
J = Estimated concentrations below the MRL
Bold results are exceedances of the applicable standards.
Catawba County, Blackburn Landfill LaBella Associates
Permit # 18-03 Page 2 of 2

TABLE 4B: MSW Units 2 and 3 Detected Constituents (March 2022)
SAMPLE ID
PARAMETER
RESULTS
DILUTION
METHOD
I MDL
I MRL
I STANDARD
SOURCE
I UNIT
I COLLECTION DATE
Unit 2
Barium
159
1
6010D
1.1
1.1
700
NC 2L
pg/L
Chromium
6.97 J
1
6010D
1.4
1.4
10
NC 2L
pg/L
MW-12R
Zinc
8.42 J
1
6010D
4.4
4.4
1000
NC 2L
pg/L
3/23/2022
1,2-cis-Dichloroethylene
0.81 J
1
8260D
0.15
0.15
70
NC 2L
pg/L
Vinyl chloride
0.53 J
1
8260D
0.32
0.32
0.03
NC 2L
pg/L
Barium
37.3
1
6010D
1.1
1.1
700
NC 2L
pg/L
MW-13
Chromium
2.88 J
1
6010D
1.4
1.4
10
NC 2L
pg/L
3/23/2022
Vanadium and Compounds
1.53 J
1
6010D
1.4
1.4
7
NC 2L
pg/L
Zinc
8.26 J
1
6010D
4.4
4.4
1000
NC 2L
pg/L
Barium
27.8
1
6010D
1.1
1.1
700
NC 2L
pg/L
MW-14
Vanadium and Compounds
1.59 J
1
6010D
1.4
1.4
7
NC 2L
pg/L
3/23/2022
MW-15
Barium
25.3
1
6010D
1.1
1.1
700
NC 2L
pg/L
3/22/2022
Chromium
2.23 J
1
6010D
1.4
1.4
10
NC 2L
pg/L
Barium
29.5
1
6010D
1.1
1.1
700
NC 2L
pg/L
MW-16
Copper
1.99 J
1
6010D
1.6
1.6
1000
NC 2L
pg/L
3/23/2022
Zinc
4.76 J
1
6010D
4.4
4.4
1000
NC 2L
pg/L
Barium
41.3
1
6010D
1.1
1.1
700
NC 2L
pg/L
Chromium
1.78 J
1
6010D
1.4
1.4
10
NC 2L
pg/L
MW-17
Cobalt
2.71 J
1
6010D
1.4
1.4
1
NC 2L
pg/L
3/23/2022
Copper
4.27 J
1
6010D
1.6
1.6
1000
NC 2L
pg/L
Vanadium and Compounds
5.61 J
1
6010D
1.4
1.4
7
NC 2L
pg/L
Zinc
Barium
7.16 J
103
1
1
6010D
Unit 3
6010D
4.4
1.1
4.4
1.1
1000
700
NC 2L
NC 2L
pg/L
pg/L
MW-31R
Chromium
3.07 J
1
6010D
1.4
1.4
10
NC 2L
pg/L
3/24/2022
Copper
1.75 J
1
6010D
1.6
1.6
1000
NC 2L
pg/L
Zinc
4.91 J
1
6010D
4.4
4.4
1000
NC 2L
pg/L
Barium
138
1
6010D
1.1
1.1
700
NC 2L
pg/L
Beryllium
0.178 J
1
6010D
0.16
0.16
4
NC 2L
pg/L
Chromium
2.22 J
1
6010D
1.4
1.4
10
NC 2L
pg/L
MW-32
Cobalt
3.48 J
1
6010D
1.4
1.4
1
NC 2L
pg/L
3/24/2022
Copper
1.85 J
1
6010D
1.6
1.6
1000
NC 2L
pg/L
Zinc
4.96 J
1
6010D
4.4
4.4
1000
NC 2L
pg/L
Barium
65.7
1
6010D
1.1
1.1
700
NC 2L
pg/L
Chromium
1.66 J
1
6010D
1.4
1.4
10
NC 2L
pg/L
3/24/2022
MW-33R
Cobalt
2.29 J
1
6010D
1.4
1.4
1
NC 2L
pg/L
Zinc
5.93 J
1
6010D
4.4
4.4
1000
NC 2L
pg/L
Barium
30.2
1
6010D
1.1
1.1
700
NC 2L
pg/L
MW-35
Chromium
3.30 J
1
6010D
1.4
1.4
10
NC 2L
pg/L
3/24/2022
Zinc
7.94 J
1
6010D
4.4
4.4
1000
NC 2L
pg/L
Barium
94.0
1
6010D
1.1
1.1
700
NC 2L
pg/L
MW-36
Chromium
3.00 J
1
6010D
1.4
1.4
10
NC 2L
pg/L
3/24/2022
Zinc
Barium
5.40 J 1 6010D 4.4 4.4 1000
Background MSW Unit 1,2, 3, and C&D Unit 1
47.8 1 6010D 1.1 1.1 700
NC 2L
NC 2L
pg/L
pg/L
Chromium
2.04 J
1
6010D
1.4
1.4
10
NC 2L
pg/L
MW-20
Cobalt
2.16 J
1
6010D
1.4
1.4
1
NC 2L
pg/L
3/23/2022
Copper
3.68 J
1
6010D
1.6
1.6
1000
NC 2L
pg/L
Vanadium and Compounds
1.82 J
1
6010D
1.4
1.4
7
NC 2L
pg/L
Zinc
7.86 J
1
6010D
4.4
4.4
1000
NC 2L
pg/L
Notes: MDL= Method Detection Limit
MRL =Method Reporting Limit
J = Estimated concentrations below the MRL
Bold results are exceedances of the applicable standards.
GPS = Groundwater Protection Standard
NC21- = NC Groundwater Standard from 15A NCAC 2L.202
Catawba County, Blackburn Landfill La Bella Associates
Permit # 18-03 Page 1 of 1

TABLE 4C: C and D Units 1 and 2 Detected Constituents (March 2022)
SAMPLE ID
PARAMETER
RESULTS
I DILUTION
METHOD I MDL
I MRL
STANDARD
SOURCE
UNIT
COLLECTION DATE
C&D Unit 1
Barium
436
1
6010D
1.1
1.1
700
NC 2L
pg/L
2
Chromium
3.29 J
1
6010D
1.4
1.4
10
NC 2L
pg/L
MW
1,4-Dioxane
3.7
1
8260D
0.8
0.8
3
NC 2L
pg/L
3/23/2022
Benzene
0.52 J
1
8260D
0.15
0.15
1
NC 2L
pg/L
MW-26
Barium
58.8
1
6010D
1.1
1.1
700
NC 2L
pg/L
3/23/2022
Barium
1710
1
6010D
1.1
1.1
700
NC 2L
pg/L
MW-27
Chromium
9.33 J
1
6010D
1.4
1.4
10
NC 2L
pg/L
3/23/2022
1,4-Dioxane
2.5
1
8260D
C&D Unit 2
0.8
0.8
3
NC 2L
pg/L
Barium
304
1
6010D
1.1
1.1
700
NC 2L
pg/L
Chromium
11.4
1
6010D
1.4
1.4
10
NC 2L
pg/L
MW-24
1,4-Dioxane
9.1
1
8260D
0.8
0.8
3
NC 2L
pg/L
3/23/2022
Benzene
1.1
1
8260D
0.15
0.15
1
NC 2L
pg/L
Tetrahydrofuran
11
1
8260D
0.53
0.53
0.53
MRL
pg/L
MW-25
Barium
Chromium
1,4-Dioxane
Benzene
Tetrahydrofuran
299
7.64 J
26
1.8
51
1
1
1
1
1
6010D
6010D
8260D
8260D
8260D
1.1
1.4
0.8
0.15
0.53
1.1
1.4
0.8
0.15
0.53
700
10
3
1
0.53
NC 2L
NC 2L
NC 2L
NC 2L
MRL
pg/L
pg/L
pg/L
pg/L
pg/L
3/23/2022
Barium
110
1
6010D
1.1
1.1
700
NC 21-
pg/L
MW-28
Chromium
1.49 J
1
6010D
1.4
1.4
10
NC 2L
pg/L
3/24/2022
1,4-Dioxane
7.3
1
8260D
0.8
0.8
1 3
NC 2L
pg/L
MW-29
Barium
Chromium
1,4-Dioxane
132
26.2
1.7 J
1
1
1
6010D
6010D
8260D
1.1
1.4
0.8
1.1
1.4
0.8
700
10
3
NC 2L
NC 2L
NC 2L
pg/L
pg/L
pg/L
3/24/2022
Barium
53.3
1
6010D
1.1
1.1
700
NC 2L
pg/L
MW-30
Chromium
1.93 JI
1
I 6010D
t 1.4
1.4
10
NC 2L
pg/L
3/24/2022
1,4-Dioxane
0.82 JI
1
1 8260D
1 0.8
0.8
3
NC 2L
pg/L
Background MSW Unit 1,2, 3, and C&D Unit 1
Barium
47.8
1
6010D
1.1
1.1
700
NC 2L
pg/L
Chromium
2.04 J
1
6010D
1.4
1.4
10
NC 2L
pg/L
MW-20
Cobalt
2.16 J
1
6010D
1.4
1.4
1
NC 2L
pg/L
Copper
3.68 J
1
6010D
1.6
1.6
1000
NC 2L
pg/L
3/23/2022
Vanadium
1.82 J
1
6010D
1.4
1.4
7
NC 2L
pg/L
MW-21
Zinc
Barium
7.86 J
98.6
1 6010D 4.4 4.4
Background C&D Unit 2
1 1 6010D 1 1.1 1.1
1000
700
NC 2L
NC 2L
pg/L
soff-
pg/L
3/23/2022
Chromium
1 3.89 JI
1
I 6010D
1 1.4
1 1.4
1 10
1 NC 2L
pg/L
Notes: MDL= Method Detection Limit GPS = Groundwater Protection Standard
MRL= Method Reporting Limit NC21- = NC Groundwater Standard from 15A NCAC 2L.202
J = Estimated concentrations below the MRL
Bold results are exceedances of the applicable standards.
Catawba County, Blackburn Landfill LaBella Associates
Permit # 18-03 Page 1 of 1

TABLE 4D: Surface Water Detected Constituents (March 2022)
SAMPLE ID
PARAMETER
RESULTS
I DILUTION
METHOD
MDL
I MRL
STANDARD
SOURCE
UNIT
COLLECTION DATE
Barium
Surface Water
28.8 1 6010D 1.1
1.1
1000
NC 2B
pg/L
Chromium
2.01 J
1
6010D
1.4
1.4
25.36
NC 2B
pg/L
SW-3
Copper
1.79 J
1
6010D
1.6
1.6
2.93
NC 2B
pg/L
3/24/2022
Vanadium
2.37 J
1
6010D
1.4
1.4
1.4
MRL
pg/L
Hardness, Ca, Mg
27 B
1
SM 2340B-2011
0.02
0.02
mg/I
SW-4
Barium
48.3
1
6010D
1.1
1.1
1000
NC 2B
pg/L
3/24/2022
Hardness, Ca, Mg
31 B
1
SM 2340B-2011
0.02
0.02
mg/I
Barium
48.3
1
6010D
1.1
1.1
1000
NC 2B
pg/L
Chromium
3.11 J
1
6010D
1.4
1.4
25.36
NC 2B
pg/L
SW-5
Cobalt
2.15 J
1
6010D
1.4
1.4
3
ISTV
pg/L
3/24/2022
Copper
2.05 J
1
6010D
1.6
1.6
2.93
NC 2B
pg/L
Vanadium
6.28 J
1
6010D
1.4
1.4
1.4
MRL
pg/L
Hardness, Ca, Mg
27 B
1
SM 2340B-2011
0.02
0.02
mg/I
Notes: MDL= Method Detection Limit
MRL= Method Reporting Limit
J = Estimated concentrations below the MRL
B = Blank -qualified result
NC26 = NC Surface Water Standard from 15A NCAC 2B
NC213* = Hardness -dependant NC2B
ISTV = In -Stream Target Values
Catawba County, Blackburn Landfill La Bella Associates
Permit # 18-03 Page 1 of 1

TABLE 5: Exceedances of Standards (March 2022)
SAMPLE ID
PARAMETER
RESULTS
I DILUTION
I METHOD
MDL
I MRL
I STANDARD
I SOURCE
I UNIT
I COLLECTION DATE
Unit 1
1,1-Dichloroethane
9.2
1
8260D
0.13
0.13
6
NC 2L
pg/L
1,4-Dioxane
19
1
8260D
0.8
0.8
3
NC 2L
pg/L
MW-5
Benzene
1.8
1
8260D
0.15
0.15
1
NC 2L
pg/L
3/23/2022
Tetrachloroethylene
3.3
1
8260D
0.17
0.17
0.7
NC 2L
pg/L
Trichloroethylene
7.6
1
8260D
0.15
0.15
3
NC 2L
pg/L
1,1-Dichloroethane
6.2
1
8260D
0.13
0.13
6
NC 2L
pg/L
Benzene
1.7
1
8260D
0.15
0.15
1
NC 2L
pg/L
MW-5A
Tetrachloroethylene
6.1
1
8260D
0.17
0.17
0.7
NC 2L
pg/L
3/22/2022
Trichloroethylene
12
1
8260D
0.15
0.15
3
NC 2L
pg/L
Chromium
11.5
1
6010D
1.4
1.4
10
NC 2L
pg/L
Cobalt
116
1
6010D
1.4
1.4
1
NC 2L
pg/L
1,1-Dichloroethane
12
1
8260D
0.13
0.13
6
NC 2L
pg/L
1,4-Dichlorobenzene
10
1
8260D
0.19
0.19
6
NC 2L
pg/L
MW-6
1,4-Dioxane
100
5
8260D
4
4
3
NC 2L
pg/L
3/22/2022
Benzene
4
1
8260D
0.15
0.15
1
NC 2L
pg/L
Tetrachloroethylene
2.2
1
8260D
0.17
0.17
0.7
NC 2L
pg/L
Trichloroethylene
3.3
1
8260D
0.15
0.15
3
NC 2L
pg/L
Vinyl chloride
2.7
1
8260D
0.32
0.32
0.03
NC 2L
pg/L
MW-61)
1,4-Dioxane
5
1
8260D
0.8
0.8
3
NC 2L
pg/L
3/22/2022
Cobalt
31.8
1
6010D
1.4
1.4
1
NC 2L
pg/L
MW-7
1,4-Dichlorobenzene
7.6
1
8260D
0.19
0.19
6
NC 2L
pg/L
3/23/2022
Benzene
2.8
1
8260D
0.15
0.15
1
NC 2L
pg/L
Cobalt
64.6
1
6010D
1.4
1.4
1
NC 2L
pg/L
MW-11
Benzene
7.1
1
8260D
0.15
0.15
1
NC 2L
I pg/L
3/22/2022
Tetrachloroethylene
8.9
1
8260D
0.17
0.17
0.7
NC 2L
pg/L
PZ 85B
Trichloroethylene
3.1
1
8260D
0.15
0.15
3
NC 2L
pg/L
3/23/2022
1,1-Dichloroethane
16
1
8260D
0.13
0.13
6
NC 2L
pg/L
1,2-Dichloropropane
4.6
1
8260D
0.1
0.1
0.6
NC 2L
pg/L
Benzene
2.3
1
8260D
0.15
0.15
1
NC 2L
pg/L
PZ-86B
Methylene chloride
6.4
1
8260D
0.23
0.23
5
NC 2L
pg/L
3/23/2022
Tetrachloroethylene
27
1
8260D
0.17
0.17
0.7
NC 2L
pg/L
Trichloroethylene
30
1
8260D
0.15
0.15
3
NC 2L
pg/L
Vinyl chloride
2.3
1
8260D
0.32
0.32
0.03
NC 21
pg/L
C&D Unit 1
MW-2
1,4-Dioxane
3.7
1 1
8260D
1 0.8
0.8
3
NC 21
pg/L
3/23/2022
MW-27
Barium
1710
1 1
6010D
1 1.1
1.1
700
NC 2L
pg/L
3/23/2022
C&D Unit 2
Chromium
11.4
1
6010D
1.4
1.4
10
NC 2L
pg/L
1,4-Dioxane
9.1
1
8260D
0.8
0.8
3
NC 2L
pg/L
MW-24
Benzene
1.1
1
8260D
0.15
0.15
1
NC 2L
pg/L
3/23/2022
Tetrahydrofuran
11
1
8260D
0.53
0.53
0.53
MRL
pg/L
1,4-Dioxane
26
1
8260D
0.8
0.8
3
NC 2L
pg/L
MW-25
Benzene
1.8
1
8260D
0.15
0.15
1
NC 2L
pg/L
3/23/2022
Tetrahydrofuran
51
1
8260D
0.53
0.53
0.53
MRL
ug/L
MW-28
1,4-Dioxane
7.3
1 1
1 8260D
0.8
0.8
1 3
NC 2L
pg/L
3/24/2022
MW-29
Chromium
26.2
1 1
1 6010D
1.4
1.4
1 10
NC 2L
pg/L
3/24/2022
Notes: MDL= Method Detection Limit GPS = Groundwater Protection Standard
MRL= Method Reporting Limit NC21- = NC Groundwater Standard from 15A NCAC 2L.202
Catawba County- Blackburn Landfill LaBella Associates
Permit # 18-03 Page 1 of 1

TABLE 6: Dissolved Metals Analyses (March 2022)
Sample ID
Parameter
Result
Units
Method
MDL
MRL
Collect Date
Unit 1
MW-6
Cobalt (dissolved)
115
pg/L
EPA 6010D
1.4 1.4
3/23/2022
Chromium (dissolved)
7.36 J
pg/L
EPA 6010D
1.4 1.4
MW-11
Cobalt (dissolved)
71.5
pg/L
EPA 6010D
1.4 1.4
3/22/2022
MW-7
Cobalt (dissolved)
32.7
pg/L
EPA 6010D
1.4 1.4
1 3/23/2022
C&D
Unit 1
MW-27
Barium (dissolved)
1770
1 pg/L
EPA 6010D
1.1
1.1
3/23/2022
C & D Unit 2
MW-24
Chromium (dissolved)
6.8 J
pg/L
EPA 6010D
1.4 1.4
3/23/2022
MW-29
Chromium (dissolved)
29.8
pg/L
EPA 6010D
1.4 1.4
3/24/2022
Notes: MDL= Method Detection Limit
MRL= Method Reporting Limit
J = Estimated concentrations below the MRL
Catawba Co., Blackburn Landfill LaBella Associates
Permit #18-03 Page 1 of 1 July 2022

TABLE 7: Detected Parameters in Leachate (March 2022)
SAMPLE ID
RESULTS
DILUTION
METHOD
MDL
MRL
UNIT
COLLECTION DATE
Leachate
Antimony
7.92
1
6020B
0.74
0.74
pg/L
Barium
173
1
6010D
1.1
1.1
pg/L
Chromium
97.6
1
6010D
1.4
1.4
pg/L
Cobalt
13.5
1
6010D
1.4
1.4
pg/L
Nickel
50.7
1
6010D
2.2
2.2
pg/L
Vanadium
12.5
1
6010D
1.4
1.4
pg/L
Zinc
58
1
6010D
4.4
4.4
pg/L
Leachate
Acetone
3300
10
8260D
100
100
pg/L
3/24/2022
Biochemical Oxygen Demand (BOD)
590
1
SM 5210 B-2011
2
2
mg/I
COD -Chemical Oxygen Demand
1200
1
SM5220D-2011
20
20
mg/1
Methyl Ethyl Ketone (2-Butanone)
3800
20
8260D
26
26
pg/L
Methyl Isobutyl Ketone (4-methyl-2-pentanone)
59 J
20
8260D
22
22
pg/L
Nitrate (as N)
0.056 J
1
353.2
0.041
0.041
mg/I
Nitrate + Nitrite (as N)
0.056 J
1
353.2
0.041
0.041
mg/I
Orthophosphate as P
0.51 B
1
365.1
0.16
0.16
mg/I
Toluene
72
10
1 8260D
1 1.4
1 1.4
1 pg/L
Notes: MDL = Method Detection Limit
MRL = Method Reporting Limit
J = Estimated concentrations below the MRL
B = Blank -qualified detection
Catawba County, Blackburn Landfill LaBella Associates
Permit # 18-03 Page 1 of 1

FIGURE
Figure 1 Site Location Map

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Powered by partnership. DRAWING NAME: DRAWN BY: DATE: PROJECT NO.:
400 S. TRYON STREET SITE LOCATION MAP RWH 05/215/2021 221161.00
CHARLOTTE, INC 6266
PHONE: [phone]
PROJECT NAME: DRAWING NUMBER:
BLACKBURN LANDFILL PERMIT #18-03 1
labellapc.com © 2021 LaBella Associates ROCKY FORD ROAD ROAD, NEWTON, NC
I,\CATAWBA—NEWTON\SLM —USGS PDF\, 1 BLACNBURN SIZE LOCATION MAP 2021.tlwg

DRAWING
Drawing 1 Groundwater Potentiometric Surface Map (March 2022)

LEGEND
NOTES
EXISTING 10 FT CONTOUR
90
1. STATIC WATER LEVELS MEASURED ON MARCH 22-24, 2022
EXISTING 2 FT CONTOUR
2. GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION BETWEEN AND
EXTRAPOLATION FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWN FIELD
GRAVEL ROAD
CONDITIONS. THEREFORE, GROUNDWATER CONTOURS MUST BE ASSUMED TO BE APPROXIMATE.
PAVED ROAD
3. GROUNDWATER ELEVATIONS ARE MEASURED IN FEET AND REFERENCED TO MEAN SEA LEVEL.
LIMITS OF WASTE —
—
POINT IN TIME GROUNDWATER CONTOUR
(APPROXIMATE) 1 FT. CONTOUR INTERVAL
GROUNDWATER FLOW PATHWAY USED TO
CALCULATE HYDRAULIC GRADIENT
SEGMENT USED FOR GRADIENT CALCULATION
Z1
GROUNDWATER MONITORING WELL LOCATION,
-
MW-11 NM
= NOT MEASURED
IDENTIFICATION, AND GROUNDWATER ELEVATION
ELEV AB
= ABANDONED
SURFACE WATER MONITORING LOCATIONS
Q
SW-# / U-#
AND IDENTIFICATIONS
LEACHATE MONITORING LOCATION AND
Q
LEACHATE MANHOLE
IDENTIFICATION
NOT MONITORED
SEGMENT LENGTH
(D F =
(D= 59w,LF
(D= 964 LF
e
G
V
GP-18
GP-19
/`F.rII GP-2
873.22
GP-17
If� A �fl
866.57 �,864;52 j
UNIT
UNIT 3
P
I
1/6
862.55
GP-8
•
_30
I eR
MSW UN 1
CLOSE REA
836.50
m
3
GP-12
C&D
16
UNIT 2 co
co
CAL®
��!t• .
�ll���!•..mi�
0
IM-,
- OPERA
: N
GRAPHIC SCALE
0 125 250 500
(FEET)
UZ3 LaBeLLa
Powered by partnership.
2211 W. M EADOWVI EW ROAD
GREENSBORO, NC 27407
PHONE: [phone]
Iabellapc.com
© 2022 LaBella Associates
CATAWBA COUNTY
NEWTON, NORTH CAROLINA
BLACKBURN LANDFILL PERMIT #18-03
ROCKY FORD ROAD ROAD, NEWTON, NC
NO: DATE: DESCRIPTION:
Revisions
PROJECT NUMBER:
2213190.00
DRAWN BY: RH
REVIEWED BY: EW
ISSUED FOR:
GROUNDWATER REPORT
DATE:
06/13/22
DRAWING NAME:
POTENTIOMETRIC SURFACE
CONTOUR MAP
MARCH 22-24, 2022
DRAWING NUMBER:
1

APPENDICES
Appendix 1 Well Construction Data
Appendix 2 Field Data Logs
Appendix 3 Laboratory Analytical Reports

Appendix 1
Well Construction Data

APPENDIX 1: Well Construction Data
Well ID
Installation
Date
Well Diameter
Inches
Total Depth
Ft-BTOC
Top of Screen
Ft-BGS
Screen
Length
Feet
Geology/Lithology
TOC Elev.
Ft-AMSL
GS Elev.
Ft-AMSL
DTW
Ft-BTOC
GW Elev.
Ft-AMSL
Fasting
Feet
Northing
Feet
MSW Unit 1 (Closed)
MW-5
8/26/1994
2
17.7
5.0
10
Sand & Silt
823.32
820.82
6.74
816.58
1314686.01
679515.69
MW-5A
6/2/1994
2
48.4
36.0
10
Gneiss
822.79
819.99
6.00
816.79
1314686.01
679501.67
MW-6
8/23/1994
2
17.6
5.0
10
Sand
829.36
827.35
6.13
823.23
1314277.04
680206.18
MW-61)
N/A
2
53.4
40.3
10
N/A
829.93
826.66
5.44
824.49
1314288.67
680165.92
MW-7
8/24/1994
2
17.4
5.0
10
Sand & Silt
842.49
840.09
11.78
830.71
1314012.71
680725.96
MW-11
12/9/1997
1 2
1 26.6
1 10.0
1 15
1 Sand
1 852.25
1 850.75
1 16.70
1 835.55
1 1313859.95
1 681053.99
MW-20
N/A
2
50.6
28.3
15
N/A
929.92
927.21
34.65
895.27
1313958.35
683439.81
PZ-858
N/A
2
44.0
36.6
5
N/A
879.89
877.29
1
18.88
861.01
1315505.32
680939.43
PZ-868
N/A
2
57.8
49.9
5
N/A
867.24
864.54
30.22
837.02
1315747.41
679824.06
MSW Unit 2 (Subtitle D)
MW-12R
2019
2
23.0
7.0
10
Sand
852.89
N/A
19.02
833.87
1313664.15
681091.99
MW-13
12/8/1997
2
18.6
6.5
10
Saprolite (Sand & Silt)
842.61
840.96
6.55
836.06
1313420.18
681201.67
MW-14
12/8/1997
2
14.6
5.0
8
Sand & Silt
844.52
842.82
6.45
838.07
1313296.28
681304.91
MW-15
12/8/1997
2
14.5
5.0
8
Sand & Silt
846.11
844.31
4.40
841.71
1313150.82
681486.21
MW-16
12/9/1997
2
21.8
5.0
15
Silt & Sand
857.16
854.96
7.73
849.43
1312854.11
681900.84
MW-17
1 12/9/1997
1 2
20.6
5.0
15
1 Sand & Silt
867.69
865.89
8.85
1 858.84
1 1312714.28
1 682167.09
MSW Unit 3 (Subtitle D)
MW-31R
N/A
2
32.7
N/A
N/A
N/A
887.50
884.90
20.50
867.00
1315461.4-4
681485.63
MW-32
N/A
2
32.8
N/A
N/A
N/A
884.71
N/A
22.18
862.53
1315743.95
681786.60
MW-33R
N/A
2
29.8
N/A
N/A
N/A
882.22
N/A
17.82
864.40
1315419.69
682280.60
MW-35
8/31/2020
2
35.0
5.0
15
N/A
905.46
903.14
30.60
874.86
1315340.20
683045.06
MW-36
9/4/2020
2
23.0
5.0
15
N/A
880.15
877.45
13.44
866.71
1315406.56
682604.91
MW-2
N/A
2
24.0
N/A
N/A
N/A
866.65
864.30
17.56
849.09
1314690.83
684593.38
MW-26
N/A
2
22.4
N/A
N/A
N/A
871.20
N/A
5.94
865.26
1314990.99
684090.66
MW-27
N/A
2
28.0
N/A
N/A
N/A
862.08
N/A
12.65
849.43
1315028.16
684518.68
MW-21
N/A
2
62.6
42.6
15
N/A
924.85
922.23
46.21
878.64
1313140.60
680087.80
MW-24
N/A
2
22.8
2.5
17.1
N/A
842.34
839.50
11.64
830.70
1313695.85
680710.41
MW-25
N/A
2
13.9
1.8
11
N/A
830.31
827.51
5.81
824.50
1314067.06
680243.47
MW-28
6/25/2007
2
14.9
1.7
10
Sand & PWR
825.31
822.26
8.85
816.46
1314295.64
679794.83
MW-29
6/25/2007
2
23.1
4.8
15
Silt & Sand
839.26
836.33
11.74
827.52
1314213.91
679499.18
MW-30
1 6/22/2007
1 2
1 22.9
1 4.7
1 15
1 Silt & Sand
847.26
844.53
15.99
831.27
1313902.53
679314.99
NOTES: TOC Elev. = Top of Casing Elevation Ft-BGS = Feet below ground surface DTW Measurments made on September 22-23, 2021.
GS Elev. - Ground Surface Elevation Ft-BTOC = Feet below top of casing
DTW = Depth to Water (static) Ft-AMSL = Feet above mean sea level
GW Elev. = Groundwater Elevation
Catawba Co. - Blackburn Landfill
Permit # 18-03 LaBella Associates

Appendix 2
Field Data Logs

DATE: /2-7-
La Beta
GROUND WATER SAMPLING LOG
Project Name: _CAl aiA.AlL ✓ ! "4--)i .Ew Project No. /Task No.:
Well ID: _1i - 2 Sampler(s): k�
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT)
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled witt
2 inches
a"'�- feet
r9-3,ctGl, feet
-4 • 9q feet [DTB-DTW]
gallons
_
gallons
= 3. (P
gallons
S �o
gallons
Depth to Water before Sampling: N--
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
t
13z;t
lb,s
a
b01
qJ, l
D,Oa�)
Ltq-, -7-
ZZr
3 6 b
(330
149,
' ­309
0 14
N/ I , C)L
M s-
Date of sample:
3 23
Before
Sampling:
Comments (weather conditions, odor, color, silt, etc.): 5
Signature: !, ��-- Date: u
QA/QC Sign Off: Date: 13 ea.a

�i
LaBdLa DATE: 31234 o D2
1_ GROUND WATER SAMPLING LOG
Project Name: ��4WJQ-NCAC�bL)rn Project No. No.: �221319UA/
Well ID: Mw-3 Sampler(s)&�J / KE %
Well Location:
Well Diameter: 2 inches
Initial Depth to Water (DTW): y. SS feet
Depth to Bottom (DTB): feet
Water Column Thickness (WCT): feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 = gallons
For 4" Well: WCT X 0.653 = gallons
For THREE Well Volumes: WV X 3 = gallons
Actual Amount Purged/Bailed: gallons
Purged with: Bailer Pump Other:
Sampled with: Bailer Pump Other:
Depth to Water before Sampling:
feet
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
Date of sample:
Before
Sampling:
Comments (weather conditions, odor, color, silt, etc.):
lJ6klu- Lbi-f i Oa-r LI,
Signature: oelizA-111� Date:__.. LAr t 91 zuzz
QA/QC Sign Off: C Date: LAZ-

F1 LaBeRa
DATE: c3 za -Vy �'
GROUND WATER SAMPLING LOG
Project Name: 41k4A-151aah4, on Project No. /Task No.:
Well ID: MW �� _ Sampler(s): e'wy
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well:
For THREE Well Volumes:
Actual Amount Pur;
Purged with:
WCT X 0.163
WCT X 0.653
WVX3
2 inches
J4 qn feet
(e. y 0 feet
q 3. q Z feet [DTB-DTW]
_ e gallons
� gallons
gallons
�3 _,_gallons
Sampled with: Bailer f urno Other:
Depth to Water before Sampling: feet
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
(VA
(Al
-kQ .3
9--- -fl
fif4,
• I
lo:fL42-
� q
g27,3
I c O
J ` 3(©
4. �.
11-
15-6
22, 6
3.
S
;?q3.
�� v
uy, /
1,14
�-
Date of sample:(Owl
ry
�V�- 11
�
Before
Sampling:
Comments (weather conditions, odor, color, silt, etc.): --0'S Gt, 'nax-
Signature: k . Dat
QA/QC Sign Off: Date:
2

P. LaR( Ra
DATE: ZZ�ti/
GROUND WATER SAMPLING LOG
Project Name:z�ba — fM&jq&1m Project No. /Task No.: 2-Z-) -61 y t? 169 P
Well ID: __Sampler(s): WQv 3ty7
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well
For THREE Well Volumes:
Actual Amount Pui
Purged with:
Sampled with:
WCT X 0.653
WVX3
Bailed:
2 inches
feet
G' feet
feet [DTB-DTW]
gallons
gallons
= S� gallons
gallons
Other:
Other:
Depth to Water before Sampling:>y S feet
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
o
l �-
1 q. I
b, T(P
4q 4b, -:f
0.0
i-op
l�
6, Yq
220, s
0. (o
1 a -p-
754,s
�- vqq,
�
q�s I �
Kz
51
1 1S4
1q,1
30
)qS-, N
l . T3
��icl
313
I
Date of sample:
31123'
Before
Sampling:
I�Sa
,5
(p,Cl�
�1�.3
t�.•ia
q�.�
�,dl
Comments (weather conditions, odor, color, silt, etc.): 407 Su,atr-
Signature:
QA/QC Sign Off:
Date:
-q- 22
13(V�o92

DATE: JZ:7-- z Ll )Sz-
GROUND LaBoUa
WATER SAMPLING LOG
Project Name: roject No. /Task No.:
Well ID: Sampler(s): t47--le,-w / obi
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well:
WCT X 0.163
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
2 inches
5, �`S feet
1 —+4 (PO feet
1 c'�- feet [DTB-DTW]
= 1.1
gallons
_ '--�—
gallons
gallons
gallons
Purged with: E I S)i Pump Other:
Sampled with: ile Pump Other:
Depth to Water before Sampling:
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
o
rH b
1(- b
b.
2T5-
O. 00
t q
I
1&' 3
&'
S9
o. v
3. �
&, ;�&
J-e�'---o
v- ,-s
5.--1
I�-z�"
I(r.�
U 3a
1ST)q
o,
-14. 0
I .a
Date of sample:
Before
Sampling:
Comments (weather conditions, odor, color, silt, etc.): 3Q"S�rY
Signature: �� Date:
�I
QA/QC Sign Off: Date:
13 J ';-0.2

-2
DATE:
LaBetta
GROUND WATER SAMPLING LOG
Project Name: 1SW A'LM Project No. /Task No.: 'Z�94 150 D )
Well ID: P �4 — (a L� Sampler(s): �
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well:
WCT X 0.163
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled wits
2 inches
2- feet
3�
met
3 feet [DTB-DTW]
gallons
_ gallons
Z gallons
,? gallons
Depth to Water before Sampling: feet
Gallons
Time
Temp
(°C)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
0
(ag40
Kb, 1
s+
o� I F,
Q. I LP
�;_a, 9
j G, l
-�C1
ct/, �-
fJ��
s�-.v2-
Date of sample:
Before
Sampling:
Comments (weather conditions, odor, color, silt, etc.): 10V S41k,74
Signature: Date:
QA/QC Sign Off.• Date: 44113 �. �

DATE: �Z—N��'
� - LaBetLa
GROUND WATER SAMPLING LOG j
Project Name: (tWk0 - b(44'0k&) Project No. /Task No.: 2.-y1 -�s l W/O)
Well ID: k �N; ---� Sampler(s):
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well:
WCT X 0.163
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled wits
2 inches
11), S< feet
�+14D feet
(O. 0 !S7 feet [DTB-DTW]
_ 1
gallons
_
gallons
= 3.3
gallons
gallons
Depth to Water before Sampling: I V. `fy feet
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
It N(0
I�
�• �'
��
�'
l ���
1' S, o
P2-
�•�
llez
�•3
Date of sample:
Before
Sampling:
(2
0.
q
Comments (yw�eather conditions, odor, color, silt, etc.): `�rS SW , �
a
Signature: Date: QA/QC Sign Off• Date: i3 0

P . LaB( Ua
DATE: 22.-2-/Z2.
if
GROUND WATER SAMPLING LOG
Project Name: C�?�-�t�I�LI�u� Project No. /Task No.: °tO c7
Well ID: IN��I Sampler(s): r �'� b{
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT)
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well:
WCT X 0.163
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled witt
2 inches
-J- feet
-2(0• tPD feet
—IQ ► E�7 feet [DTB-DTW]
�► gallons
gallons
_ S. 3 gallons
E,'3 gallons
Depth to Water before Sampling: '�- feet
Gallons
Time
Temp
(°C)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
Ilplq
i�.s
5.
IS-'S�
(9.
o
y�.q
3.
Ikei
IT
S► lq
301A
17-1 -3
�.
5; 3
Its la
57t?&
330tq
9 F �3
��-
Date of sample:
S
��
Before
Sampling:
Comments (weather conditions, odor, color, silt, etc.): go
Signature:
Date:
QA/QC Sign Off: ram % Date: q_1 t 11 a 0

P. LaB( Ua
DATE',- 4Zr 2�
GROUND WATER SAMPLING LOG
Project Name: 6!.;K,wb0_ xn Project No. /Task No.: W101
Well ID: a Sampler(s): 1:aq
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled wit[
2 inches
—4 feet
_2 -.q feet
5, l5 feet [DTB-DTW]
0- 0 gallons
_ gallons
gallons
gallons
Depth to Water before Sampling: feet
Gallons
Time
Temp
(°C)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
0
1�,l
5_.93
?! 0.,6
oYc)
tv � �
���
I
Date of sample:
2
4�3/`Zz_
Before
Sampling:
_
(S3�
�-�
(0.02-
c03,
�'
S� SCl
Comments (weather conditions, odor, color, silt, etc.): —TO",s S6cMj- phi,
Signature: T� Dat
QA/QC Sign Off. Date:

DATE: 17
� LaBe[La GROUND WATER SAMPLING LOG
Project Name: C— B14444ki,rel Project No. /Task No.:2,o D o/
Well ID: _ t+'� ' Sampler(s): SWLILL-
0
Well Location:
Well Diameter: 2 inches
Initial Depth to Water (DTW): ! •R feet
Depth to Bottom (DTB): feet
Water Column Thickness (WCT): feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 = gallons
For 4" Well: WCT X 0.653 = arallons
For THREE Well Volumes: WV X 3 = I`or3 gallons
Actual Amount Purged/Bailed: 4P• 3 gallons
Purged with:
Sampled witl
Depth to Water before Sampling: 5 qQ feet
Gallons
Time
Temp
(0C)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
O
1 W
13- Lf
(�,
WIq
I---
I
UZ
13,q
k,,3,q
3Tq
Cp.
[ (A
13,E
10 ,-1
1, qt
16-, ).
LP�d
�
Date of sample:
a 23 2
Before
Sampling:
15
13
(o �S��
h
�[�
�2�'r y
o2, yq
Comments (weather conditions, odor, color, silt, etc.): '112=3 Sirfj4 pUWaz"
W's "A 5t4-o
Signature: --� _ Date
QA/QC Sign Off: Date: .
Z�
i31a-0z

P LaRt Ra
DATE Z2-2- /?_?_
GROUND WATER SAMPLING LOG
Project Name:! -6'&U to -V gAbU. t0 ` Project No. /Task No.: 2-Z1 4�
Well ID: Sampler(s): k
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT)
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well:
WCT X 0.163
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled witl
nches
5: `f q feet
1119 feet
D q feet [DTB-DTW]
= I (
gallons
_
gallons
= 3:3
gallons
3. '3
gallons
Depth to Water before Sampling: 15-:57 feet
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
t. I
16S.'a
130
( ,Is
go I. a
v. f3
Iq-)-,g
11%q
13.2
(0,05
19'b" -
3.3
I'SS25
13.3
(P
mil, y
D •Q�
IS �. I
I u, a
Date of sample:
?/242a
Before
Sampling
1515
�• (
(p. 3G'.
;Z
a� Gym
�
�1
q.
Comments (weather conditions, odor, color, silt, etc.): r� !im �r
Signature: Dat
QA/QC Sign Off: Date:
a oar

DATE: 7r 2�1
LaBeUa
GROUND WATER SAMPLING LOG
Project Name: Project No. /Task No.: 19D10/
Well ID:ku-1 Sampler(s): Y4 e'-
Rao
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well
For 4" Well:
WCT X 0.163
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled witl
Depth to Water before Sampling: J
2 inches
rg bi feet
feet
feet [DTB-DTW]
�. gallons
gallons
_ gallons
__gallons
feet
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
sL3q
I L3,(P
5a -
eq.,Lf
�c� _3
kg
0 .Li
1,2q
1q,4
(0��3
I ,
1 b
13, 2
, D 1
-;z
q,
q2,::
OAS-
20911 1
-T, -R­�
lcli
Date of sample:
�I
Before
Sampling:
Comments (weather conditions, odor, color, silt, etc.): -TdrS QtA !rjz
Signature: h . Z-0-0" Date: W-7'2—
QA/QC Sign Off: Date: L 13 e20;2g

n LaBelLa
DATE: 24 - 2
GROUND WATER SAMPLING LOG
Project Name: �(� �I�thl�r Project No. /Task No.: O �/
Well ID: Muj l (,p Sampler(s):_
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT)
2 inches
feet
feet
feet [DTB-DTW]
Calculation for One Well Volume (WV): -e's-
For 2" Well: WCT X 0.163 =-gallons
For 4" Well: WCT X 0.653 = �^ gallons
For THREE Well Volumes: WV X 3 = aallons
Actual Amount Purged/Bailed:, J allons
Purged with: B6& Pump Other:
Sampled with: 9 ii -e-Y' Pump__ Other:
Depth to Water before Sampling: Cfeet
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
c)SLO
LOU
I
1. I
1 yl
1
C�
Date of sample:
Before
Sampling
I '�
//13
l�
//
Ip�,�o
q
�,
ii
I��
©-Lf
t
Comments (weather conditions, odor, color, silt, etc.): 'iQ��
Signature: Dati
QA/QC Sign Off: Date:
Is

DATE: 2i�_
LaB( Ua
GROUND WATER SAMPLING LOG
Project Name: � �(,iJb/� ` LlaL/►')Project No. No.: �i �%� 0/0
-6
Well ID: kwtw Sampler(s): k ��
Well Location:
Well Diameter: 2 inches
Initial Depth to Water (DTW): `1, 0 feet
Depth to Bottom (DTB): cQa&o feet
Water Column Thickness (WCT): feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 gallons
For 4" Well: WCT X 0.653 = gallons
For THREE Well Volumes: WV X 3 gallons
Actual Amount Purged/Bailed: 3 e 5�L gallons
Purged with:
Sampled wits
Depth to Water before Sampling: i1q I feet
Gallons
Time
Temp
(°C)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
o, 00
Jv
w�
l
Date of sample:
3k*
Before
Sampling:
HOC
�3•�
�O, "! �
� �. �
� - � Z
��• �
� �
k�
Comments (weather conditions, odor, color, silt, etc.): '
Signature:
QA/QC Sig

DATE: —11 Z v21
0,--LaBelLa
GROUNDWATER SAMPLING LOG
Project Name:
Project No. /Task No.:S2 1 3 1y l
Well ID: _. �'� + �- (� Sampler(s): :�J/
Well Location:
Well Diameter:
2 inches
Initial Depth to Water (DTW):
_ feet
Depth to Bottom (DTB):
feet
Water Column Thickness (WCT):
feet [D -DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
= Mons
For 4" Well: WCT X 0.653
= allons
For THREE Well Volumes: WV X 3
= allons
Actual Amount Purged/Bailed:
gallons
Purged with: Bailer PUMP.Ot
r:
Sampled with: Bailer Pump
ther:
Depth to Water before Sampling:
feet
Gallons
Time
Temp
(OC)
pH
(S.U.)
ond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
Date of sample:
Before
Sampling:
Comments (weather conditions, odor, color, silt, etc.): -� S'i�.yl�
W -L N ba ,
Signature: Z--
QA/QC Sign Off:
Date: y/ q /2 v
Date: 13�aQ

DATE: 3/zL ��Z�
LaBetta GROUND WATER SAMPLING LOG
Project Name: Cdaub_a-o- Project No. /Task No.: ZzI 31 qV /oI
Well ID:. iAW --20 Sampler(s): K4w /1-&,
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well:
WCT X 0.163
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled witt
2 inches
feet
S'D, feet
13. l9 feet [DTB-DTW]
02, gallons
gallons
Cp. .gallons
D gallons
Depth to Water before Sampling: 31L. 0 _feet
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
Q
3
?a
103, `3
3 ati
31.
7-2-
Spa
�, (�
�� T1
81.2
It 0&
3zy
�
O��
70o a
l l
Date of sample:
3h,
Before
Sampling:
I6f�G
`"' �'
����
g�c l
�i Z6
1 U q
)q, v
Comments (weather conditions, odor, color, silt, etc.): �S JqA n
Signature:. 14 ,CYO--fJ�/ Date:
QA/QC Sign Off: Date: -
q
13

P La Be[La
DATE: 3 ^�
GROUND WATER SAMPLING LOG
Project Name: eA" IIJ� � Project No. /Task No.: '72 )319 010t
Well ID: [ r��- ( Sampler(s): 4-- li't'j 44
Well Location:
Well Diameter: 2 inches
Initial Depth to Water (DTW): 45, U5 feet
Depth to Bottom (DTB): feet
Water Column Thickness (WCT): T, (P feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 = �'� gallons
For 4" Well: WCT X 0.653 = gallons
For THREE Well Volumes: WV X 3 gallons
Actual Amount Purged/Bailed: .2----gallons
Purged with: JQr Puma Other:
Sampled with: dQr Pump Other:
Depth to Water before Sampling: '-- feet
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
If2c�
I("
'�o
►. M�-
1 12
t
Ql vto,
4b, q
�-
11_:�5
Date of sample:
51zaliZ
Before
Sampling:
Comments (weather conditions, odor, color, silt, etc.): MS ??gi/)
Signature: 6-1 �14::L Dat
QA/QC Sign Off: Date:

P La BetLa
DATE: z3 ZZ
GROUNDWATER SAMPLING LOG
Project Name: hzc, L vT1 Project No. /Task No.:
I 3r�
Well ID: U1i..z2
�- Sampler(s): 6�— �� ,.
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3 =
Actual Amount Purged/Bailed:
Purged with: Bailer F
Sampled with: Bailer F
Depth to Water before Sampling:
2 inches
Ifti.q S feet
eet
et
feet
gal
Ilons
Ilons
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond
(pS/ )
01
Dis.02
(mVL)
ORP
(mV)
Turb.
(NTU)
Initials
Date of sample:
Before
Sampling:
Comments (wea(thejr�,co�n�d`itions, odor, color, silt, etc.):
Signature: F-
QA/QC Sign Off:
Date: q l 13 1 9-0 g..)-

P LaBe La
DATE:4L�
GROUND WATER SAMPLING LOG
Project Name: Ubk-&J"&NWPrcject No. /Task No.: C?D
Well ID: t" 1 vq Sampler(s): leL � S
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 =
For 4" Well: WCT X 0.653 =
For THREE Well Volumes: WV X 3 =
Actual Amount Purged/Bailed:
Purged with: Bailer Pump
Sampled with: Bailer Pumpt
Depth to Water before Sampling:
2 inches
Q, 1) feet
feet
feet
feet [
Ilons
Ilons
Ilons
Ilons
DTW]
Gallons
Time
Temp
(°C)
pH
(S .)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
Date of sample:
Before
Sampling:
Comments (weather conditions, odor, color, silt, etc.):
Signature: Ty'y- —t l' Date
QA/QC Sign Off: Date:
13 'I Q?--

P LaB( Ua
DATE:
GROUND WATER SAMPLING LOG
Project Name: &44.4- Project No. No.: 9 9-I IbIl
Well ID: LW - gm Sampler(s): 4stx
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT)
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well:
WCT X 0.163
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled with:
2 inches
Z feet
a7 o� feet
A feet [DTB-DTW]
•� gallons
_ gallons
_ 1- gallons
gallons
Depth to Water before Sampling: �-feet
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(PS/CM)
Dis. 02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
6
iW, 0
q, -7
5, S-4-
2,3
5.
Date of sample:
Before
Sampling:
Comments (weather conditions, odor, color, silt, etc.): S7'S Re&n
QA/QC Sign Off:

DATE: 3 Zz —Z,q 22•
LaBetLa
pa"',eleu11 GROUND WATER SAMPLING LOG
Project Name: 4Wb&_ Lt � Project No. /Task No.: 22 If3IE Ol o'
Well ID: KA W-a 3 Sampler(s):
Well Location:
Well Diameter:
2 inches
Initial Depth to Water (DTW):
67,14 feet
Depth to Bottom (DTB):
, 0Y feet
Water Column Thickness (WCT):
S• feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
gallons
For 4" Well: WCT X 0.653
= gallons
For THREE Well Volumes: WV X 3
= Yra _gallons
Actual Amount Purged/Bailed:
L11 1 gallons
Purged with:
Sampled witt
Depth to Water before Sampling:
feet
Gallons
Time
Temp
(°C)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
v
I21�5_
MCI
1g31
I. It
Iz v
13,K
-+5
)37-4
I2
1a3 -
R'6
Iz+o
13,0
�' W
1 s3�
o• W
- q. j�-
u, a
1 z2i
jq v
tp;z
(01)
►v
-1N.v
�.2�
Date of sample:
31312 -
Before
Sampling:
��
l�C
Comments (weather conditions, odor, color, silt, etc.): ��5
Signature: ��� _"}' 1 �Y Date: J ?'1ZZ
QA/QC Sign 0ff: Date: cl 1) 3 1 /-2�

LaBetLa
DATE: &` 7,q IZZ-,
//''� f^ GROUND WATER SAMPLING LOG
Project Name: l u iCU./ � 12"k l Project No. /Task No.: :ZZ (q b 161
Well ID: M N -2(p Sampler(s): kg- uU 1-o q
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT)
2 inches
3.g%Z feet
�2. N / feet
ICf feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 = & gallons
For 4" Well: WCT X 0.653 = gallons
For THREE Well Volumes: WV X 3 = -3 gallons
Actual Amount Purged/Bailed: -X R, jgallons
Purged with: Pump Other:
Sampled with:
Depth to Water beforea pling: , q-3 feet
Gallons
Time
Temp
(°C)
pH
(S.U.)
Cond.
(PS/CM)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
0
1350o
[ �. �'
1-. s'3
1014
4,so
E 1-/, I
I y- y
3.1
lgoD
10
(,v3
�a a
aqo
qg'E,
20,
Date of sample:
l
2
Before
Sampling:
i q4)
124
�,M
a`�v 1.lD
1. Dq
�3•
I (0.
Comments (weather conditions, odor, color, silt, etc.):_ D 'r- Ray?
Signature:
Date: q
QA/QC Sign Off: Date:
131 90aa

DATE:LaBetta
{,,.,,_:.,_a f,'! trier sh,p GROUND WATER SAMPLING LOG
Project Name: CPTrw9A -�3ZAcLburO Project No. No.: l'3190 ��I
Well ID: (''11 J -a7 Sampler(s): «Cf W IJ&
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well
For 4" Well:
WCT X 0.163
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
2 inches
M • 5-7 feet
98,0 feet
I& • y 3 feet [DTB-DTW]
_ gallons
"—� gallons
8< gallons
—gallons
Purged with: aileT Pump Other:
Sampled with: � Pump Other:
Depth to Water before Sampling: /J feet
Gallons
Time
Temp
(°C)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
�ytg
19.3
6.31
(a37
'56,0
it a6
9..-7
Hal
&
.L4
16.1
93.1
13.E
Date of sample:�3
Before
j
mireSampling:
I
Comments (weather conditions, odor, color, silt, etc.): 50' 3 1p, q,0
Signature:
QA/QC S
Date: _ &12va2

e LaBetLa
DATE: V Z� - zq/ZZ'
GROUND WATER SAMPLING LOG
Project Name: CAI� ��-' _ Project No. o.:
Well ID: � �y—� ask N
Sampler(s): ; bS 1
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled witP
ches
3: ip feet
feet
//, /& feet [DTB-DTW]
�- gallons
gallons
5, allons
gallons
Depth to Water before Sampling: 13,Ul G feet
Gallons
Time
Temp
(°C)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
12JA S­
13, S-
--7-,O*kl
�� ►
I-
- 6-z.e.,
13 Lf
Icy
l , q
17,q T
13, 0
1�, &2
6,C1T
—5 3M
13$
Ki
3.'6
1
0
&,s3
qOs q
0i f-3
1
1
15--T
f oliz-1
1-3A
L0
5"D,
Date of sample:
312A1 122
Before
Sampling:
M-30
12,T
6,10
Comments (weather conditions, odor, color, silt, etc.): I.S
Signature: 1415�6� Dat
QA/QC Sign 0ff: Date:
y 13 /gQgp-

k _=
DATE: 37-�i 2rL
LaBoUa
GROUND WATER SAMPLING LOG
Project Name: CJ4,(AJb i3 Project No. /Task No.: 7�7 o/
Well ID: �"V -�1 Sampler(s): U-61
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT)
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well:
For THREE Well Volumes:
Actual Amount Purged,
Purged with: E
Sampled with:
Depth to Water before
WCT X 0.163
WCT X 0.653
WVX3
ailed:
2 inches
feet
. 13 feet
114• 1 I feet [DTB-DTW]
3gallons
_ gallons
gallons
—gallons
Other:
Other:
mpling: e. Oq feet
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
I (�
3 ,
6A&
1-2
c --v -
�-a'p
���►.�
5�
25
5
io.
I11lo
�,
t .v
l,��
►,3
J2-
Date of sample:
g f 2,4 124
Before
Sampling:
(�, t♦
- a-
a� �
a N
�0
Comments (weather conditions, odor, color, silt, etc.): Sb� Kaa r\,
Signature: ��-� Dat
QA/QC Sign Off: Date:
22
0

DATE: 3 21,
G� LaBoRa
GROUNDWATER SAMPLING LOG
Project Name: Project No. /Task No.:
Well ID: M tlQ —:50 Sampler(s):
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT)
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled with:
2 inches
Ieet
feet
�• �' feet [DTB-DTW]
1• :3 gallons
gallons
gallons
,3,41 _gallons
Other:
Depth to Water before Sampling: �y� 8� feet
Gallons
Time
Temp
(°C)
pH
(S.U.)
Cond.
(PS/CM)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
1. 3
loS�t
l & (�
�.�fY�
I S3, v
S:
Z2 .1
3e
i
a.
11O2,
1S$
&' 21-
IS111
2 5 3.1
j 1dLf
113
I 3
s; ��
3 4A
PM
kf,
Date of sample:Before
,
Sampling:
Comments (weather conditions, odor, color, silt, etc.): 5 ftQ.c MA
Signature: 0 Dati
QA/QC Sign Off: Date:
aoaa

P LaB( Ua
DATE: �3 Jyj�
r/
4 GROUND WATER SAMPLING LOG
Project Name: aiau Yh�/ Y �_;4� Project No. /Task No.:yZZ-1i 9v D/
Well ID: M AJ 3 Sampler(s):_ArA Qv_I�L�
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT)
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well:
WCT X 0.163
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled witl
2 inches
�•!0 feet
s� feet
feet [DTB-DTW]
gallons
_ gallons
gallons
gallons
Depth to Water before Sampling: cP_O. W feet
Gallons
Time
Temp
(°C)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
qw3'
, g
(09_Ll
12
6j
l rt.,�
a,acb
xy, 3
Ici
lo_;
Date of sample:Befre
Sampling:
���'
� '�
%/1 �3
3. (0�
Z-30•
�• 1
C
Comments (weather conditions, odor, color, silt, etc.): �T:S k'd:�14..
Signature: Date:
QA/QC Sign Off. Date: _
aaa--QL

P La Rolla
DATE: 3 17_2_-?'q17_2_
GROUND WATER SAMPLING LOG
Project Name: 0,44&wbQ 61G.r&bu4,m Project No. /Task No.: ZZ- D
Well ID: r 32 Sampler(s):
h,yM- II COT - I • ,
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT)
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled witl
2 inches
'Z2. la feet
Z. fis feet
• J feet [DTB-DTW]
• _'T gallons
Depth to Water before Sampling: 3-7, CO feet
gallons
-gallons
gallons
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
p Z
i(0,L7
�0(
(oo�•
WA
C�
30 <
Ll"n
s16
3,4
1 5,9
,3
3,b,o
q,13
07&0rq
-30
G'
il3�a
�� ��i
�,3
3°l,
4,
Date of sample:
3�
Before
Sampling:
Comments (weather conditions, odor, color, silt, etc.): 'S ka&e}
Signature:. 1
QA/QC Sign Off:

DATE: 3 ��
La Bella
GROUND WATER SAMPLING LOG
Project Name:.IfitVk✓ Project No. /Task No.: 7 t'"--b00
Well ID: M — Sampler(s): K�� 4
Well Location:
Well Diameter: 2 inches
Initial Depth to Water (DTW): feet
Depth to Bottom (DTB): 4 feet
Water Column Thickness (WCT): 1 .aS" feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 = . `"! gallons
For 4" Well: WCT X 0.653 � gallons
For THREE Well Volumes: WV X 3 = r gallons
Actual Amount Purged/Bailed: S, gallons
Purged with: B;r Pump Other:
Sampled with: ail r Pump Other:
Depth to Water before Sampling: feet
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
0
! 0
I-q-, I
s , (0
y6, /
V.L3q
W4,1
lc>,q
I
l,'t�
4-4v
16'e)
s,sq
43,E
(.a
'ifM-v
K
3 ►a 2-
0g2;5
I
5,644
5fp. 0
i1ty
a
> i D
. �
rya-
IJ-,Z
5,�s
Date of sample:
3 /Z-q 11,
�&
Before
Sampling:
��I
S3
g�,�
L ��
a�� .
t j•�
l�
Comments (weather conditions, odor, color, silt, etc.):n)
Signature:
QA/QC Sign Off:
Date:
�/
z
Date:
3
oga

Fl: LaB( Ua
DATE:27-' 7-2-
�daWkk--
GROUND WATER SAMPLING LOG
Project Name: 61U*Jk& - - Project No. No.: 2;r?-13
Well ID: 1A V% __ _ _ Sampler(s):
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well:
ITiTIOIN I]RI c3
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled wits
2 inches
feet
feet
�- 4 Q feet [DTB-DTW]
�.q gallons
gallons
a gallons
gallons
Depth to Water before Sampling: 32, 30 feet
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
°?q
j�,q
�,��
w,2
.1,►
let, T.y
l-u
0,9
1 &,q
(�
.3
qJ-6
aW 9-
rl__
,
Date of sample:
3 k'
?--
Before
Sampling:
.3
��g, S
���
��,
fa`
PP
I�s��
�
Comments (weather conditions, odor, color, silt, etc.):
Signature: Dat
QA/QC Sign Off: Date:
� 2Z
0

-zy
La Bella DATE:
GROUND WATER SAMPLING LOG
Project Name: 6� `� M4 '6Uh Project No. /Task No.: LJ'q/
Well ID: '" c3� _ Sampler(s): ��1 J67
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
2 inches
f 3, S$ feet
a7S. B feet
J2. Zz feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 = _ �� O gallons
For 4" Well: WCT X 0.653 = gallons
For THREE Well Volumes: WV X 3 = gallons
Actual Amount Purged/Bailed: ,� : a gallons
Purged with: Bor Pump Other:
Sampled with:
Depth to Water before Sampling:
feet
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
a
qu V
161
51�
3?.
(9-33
cZ ,, a
s". I
kef
I , i
s,. 131
, , vR
. 62
9_W
l�
R0t
�J
5. TS
30.
q,
a
> two
I
Ez
Date of sample:
3 f jy�
Before
Sampling:
0%15
i, ��
�P, it
go, 1
3• qb
Comments (weather conditions, odor, color, silt, etc.): Q �5 Pa4:;1I
Signature:
QA/QC Sign Off:

R LaB( Ua
DATE: 3 ZZ-Zy 22-
GROUND WATER SAMPLING LOG
Project Name: _aba - L(rubvrry� Project No. /Task No.: 22-r3
Well ID: Sampler(s):- �L
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled with:
2 inches
I J.56 feet
jI `LI feet
SLP feet [DTB-DTW]
q 2 gallons
_ gallons
= rr2•la F-allons
gallons
Other:
Depth to Water before Sampling: — feet
Gallons
Time
Temp
(°C)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
DO-
�(
�: gI
I sa , (6
3'sn
IT 0
l
2
[o i
1L4
C
�2.(P
101-:r
U,U
(n.C5V
1SI,3
Date of sample:
��
Q�,
Before
Sampling:
Comments (weather conditions, odor, color, silt, etc.):'M°S J42,- r1 _
Signature: K. 5A4_a-- Dat
QA/QC Sign Off: Date:
.?-P-

n LaB( Ua
DATE: 7_2-7,q Az_
GROUND WATER SAMPLING LOG
Project Name: 2 ham- &4vkJw_4,na_ Project No. /Task No.: 'ZZ 13 / ct d /
Well ID: Az — ?) (P �_ _ Sampler(s): K QJ 12G67
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled wit
Depth to Water before Sampling:
2 inches
31
. feet
5"R,'_feet
_ o2 0, (61 feet [DTB-DTW]
< <'% gallons
gallons
gallons
gallons
Gallons
Time
Temp
(OC)
pH
(S.U.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
o —lost
i64
6,11
Iqv9
--
M5,M
3r-1�
[�
1 %q
I.
��Iq
a.
V3J
l W -
�� I i
l/ r Ll J
[ 0. -z-
c0
�(,�
�, I�
33,E
n,�
�i,S
�,qq
Date of sample:
3/7 el
Before
Sampling:
Comments (weather conditions, odor, color, silt, etc.): SV ` 5 &0
Signature: k' ✓�
QA/QC Sign Off:
Date:
y//3/90.2�

DATE: 3 2� zZ
La BetLa
.. GROUND WATER SAMPLING LOG
Project Name: CGt7l.aLtJht -- 614 C6Y1 Project No. /Task No.: z24c 410
l
Well ID: 'SG-P Sampler(s):_ _ 'emu /271
Well Location:
Well Diameter: 2 inches
Initial Depth to Water (DTW): feet
Depth to Bottom (DTB): feet
Water Column Thickness (WCT): feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 gallons
For 4" Well: WCT X 0.653 gallons
For THREE Well Volumes: WV X 3 /th
allons
Actual Amount Purged/Bailed: gallons
Purged with: Bailer Pum
Sampled with: Bailer Pum Other:
Depth to Water before Sampling: Z feet
Gallons
Time
Temp
(OC)
p
.U.)
Cond.
(pS/cm)
Dis.02
(mVL)
ORP
(mV)
Turb.
(NTU)
Initials
Date of sample:
Before
Sampling:
Comments (weather conditions, odor, color, silt, etc.): W"s -Sif a f _
^JL OntlA
Signature: Q-L�: _ Date: 2—
QA/QC Sign Off: Date: �Lf 131 aoa-2

P,_ LaBetLa
DATE: 3 v'(A-Z
GROUNDWATER SAMPLING LOG
Project Name CUa42 _NvAm'r1 Project No. /Task No.: �2a cl o d /
Well ID: b _Hy L Sampler(s):__ _ ;L w / 961
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with: Bailer P
Sampled with: Bailer P
Depth to Water before Sampling:
2 inches
a feet
feet
feet [DXDTW]
961lons
= gaiions
= gallons
-gallons
Otf(e
01
Other:
feet
Gallons
Time
Temp
p
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
Date of sample:
Before
Sampling:
Comme (weather conditions, odor, color, silt, etc.): J60 S
r.,L-
&V.A
Signature:
QA/QC Sign Off:
Date: 14113 I .1_o

P., Laeella
DATE:,-& hz,
1 11
GROUND WATER SAMPLING LOG
Project Name d lt�,tl�i�-- Gr�r/��i Project No. /Task No.:11- IN it a p /
Well ID: Sampler(s): 14z-- f -9- I
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 =
For 4" Well: WCT X 0.653 =
For THREE Well Volumes: WV X 3 =
Actual Amount Purged/Bailed:
Purged with: Bailer Pump
Sampled with: Bailer Pump1
Depth to Water before Sampling:
2 inches
19'S feet
feet
feet
DTB-DTW]
lions
lions
lions
lions
Gallons
Time
Temp
(OC)
p
.)
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
Date of sample:
Before
Sampling:
Comm nts (weather conditions, odor, color, silt, etc.): (00'J SUAA,'/ „
Signature: IF
QA/QC Sign Off:

DATE: i 2-2,
LaBeUa
po"v4fer;�� GROUND WATER SAMPLING LOG
Project Name: &ZLZ"ni Project No. /Task NZ'n
ZZ 61
Well ID: t---L4Sam ler s : 6J�
Well Location:
Well Diameter:
inches
2'
Initial Depth to Water (DTW):
j
. `I feet
Depth to Bottom (DTB):
Water Column Thickness (WCT):
TW]
Calculation for One Well Volume (WV):
Ze
For 2" Well: WCT X 0.163
=
For 4" Well: WCT X 0.653
=For
THREE Well Volumes: WV X 3
=
Actual Amount Purged/Bailed:
gallons
/th
Purged with: Bailer PumD
Sampled with: Bailer F
Depth to Water before Sampling:
feet
Gallons
Time
Temp
(OC)
pH
( .)
01
Cond.
(pS/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
Date of sample:
Before
Sampling:
Comments
Signature:
QA/QC Sign Off:

f! LaBeRa
0
DATE
povyededt,' GROUND WATER SAMPLING LOG /
Project Name: 414,Project wr;z
.: Z7 ( 1 a
Well ID: c p ` H I _ Sampler(s):
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with: Bailer F
Sampled with: Bailer F
Depth to Water before Sampling:
2 inches
v feet
feet
feet [DTB-DTW]
gallons
_ - =10
=
feet
Ilons
Gallons
Time
Temp
(OC)
pH
(S.U.)
Co
/cm)
Dis.02
(mg/L)
ORP
(mV)
Turb.
(NTU)
Initials
Date of sample:
Before
Sampling:
Cori—MALAA
weather conditions, odor, color, silt, etc.): 'a �3 e _
, 11,,_4 I_-�>1r
Signature:
QA/QC Sign Off:
Date: __qi 3 /�o-

0 LaBetta
Project Name:
Surface Point ID:
Location:
Field Parameters:
Time of Sampling:
pH:
Temperature:
Conductivity:
Turbidity:
Dissolved Oxygen
Oxidation -Reduction Potential
DATE: 3 Z--
SURFACE WATER MONITORING LOG
�16Project/Task No.: 2131 CI Q a I
_[Sampler(s):
(0C)
(US/cm)
(ntu)
(mg/L)
(mv)
Comments/Sample Description (weather conditions, odor, color, silt, etc.):
Summary/Sketch of Sampling Location
A
Signatu
QA/QC Sign Off:
Date: �/�
Date: _l f 13 /;Z0 9 2

DATE: 7 N 27-
LaBetta
p ��SURFACE WATER MONITORING LOG
Project Name: -��t Li,cv �c� - U 1G,14u li Proje1ctt/Task No.:
Surface Point ID::SW-3 Sampler(s):
Location:
Field Parameters:
Time of Sampling:
W30
pH:iQ
Temperature:
c� ��
(° C)
Conductivity:
(US/cm)
Turbidity:
(ntu)
Dissolved Oxygenjj�,,C�'�
_ (mg/L)
Oxidation -Reduction Potential
//
1 ` ,31
(mv)
Comments/Sample Description (weather conditions, odor, color, silt, etc.):
Summary/S
Signature: K-
QA/QC Sign Off>4 �P�
IZPAw-R
13 I ao.2.1_

P LaBella
DATE: LEZ'
f/�1��
SURFACE WATER MONITORING LOG
Project Name: 0&7k'.b 44 — 6Project/Ta k No.: "2-2,O jo 1
Surface Point Sampler(s): k1, ICG" J61
Location:
Field Parameters:
Time of Sampling:
pH:
Temperature:
Conductivity:
Turbidity:
Dissolved Oxygen
Oxidation -Reduction Potential
131--T
(°C)
64 r Z
(US/cm)
3 b . �
(ntu)
q-° �3
(mg/L)
/q-J.
(mv)
Comments/Sample Description (weather conditions, odor, color, silt, etc.):
Summary/Sketch of Sampling Locatio
Ski—
RJO
V.w-32
Signature: f l'�� Date:
y' 3 IQ�2
QA/QC Sign Off: Date:

P. LaBetta
DATE:
SURFACE WATER MONITORING LOG
Project Name: Gt- BIA:. kLw Project/Tas No.: 2 l 19O v
Surface Point ID: �Sw v9 Sampler(s):
Field Parameters:
Time of Sampling:
pH:
Temperature:
Conductivity:
Turbidity:
Dissolved Oxygen
Oxidation -Reduction Potential
"! S-T
�26
(aC)
--
I�• (
BSI:
(US/cm)
(ntu)
(Q Z
(mg/L)
17 'T
(mv)
Comments/Sample Description (weather conditions, odor, color, silt, etc.):
Signature: L '1_41
QA/QC Sign
Summary/Sketch of Ong Location
7 d"v? i,, /I
Date: `Z / '11-1Z12—
Date: f 13 /9 0-22-

La Betta
DATE: 3/�, k-
/1 ` p Iftalh6m,
SURFACE WATER MONITORING LOG
Project Name:_Cd �,vY�L Project/Task No.: 721 a101 QZol
Surface Point ID: — I Sampler(s): �/' (Ai' J t,
Location:
Field Parameters:
Time of Sampling:
pH:
Temperature:
Conductivity:
Turbidity:
Dissolved Oxygen
Oxidation -Reduction Potential
(aC)
(US/cm)
(ntu)
(mg/L)
(mv)
Comments/Sample Description (weather conditions, odor, color, silt, etc.):
Summary/Sketch of Sampling Location
(.t 1
Signature:
QA/QC Sign Off:
Date:
Date:

e LaBetta
Project Name:
Surface Point ID: - Sampler(s
Location:
Field Parameters:
Time of Sampling:
pH:
Temperature:
Conductivity:
Turbidity:
Dissolved Oxygen
Oxidation -Reduction Potential
DATE: F%
(O C )
(US/CM)
(ntu)
(mg/L)
(mv)
Comme WSample Description (weather conditions, odor, color, silt, etc.):
Summary/Sketch of Sampling Location
w
Signature: k.
QA/QC Sign Off:
� L a,,fJ' �'' / i
Z/ /`_T_
Date:T133 L;zo,-a
©l

DATE:
LaB< tta
SURFACE WATER MONITORING LOG
Project Name: �(�" - g< C-4.kbwyl Project/Task No.: 22 l ci ca(
Surface Point ID: 1A _ `y Sampler(s): to C�
Locatio
Field Parameters:
Time of Sampling:
pH:
Temperature:
Conductivity:
Turbidity:
Dissolved Oxygen
Oxidation -Reduction Potential
(aC)
(US/cm)
(ntu)
(mg/L)
(mv)
Comments/Sample Description (weather conditions, odor, color, silt, etc.):
Summary/Sketch of Sampling Location
Mw- 1s
i�1u-3
V u;�vt iZdj
Signature: Kf� Date:
QA/QC Sign Off: Date: y 3 'a-C;

n LaBella
DATE: 3 Z''fL2-z-
SURFACE WATER MONITORING LOG
Project Name: C_A9,i Vb4 Project/Task No.: 22 j ?jJ clp 0l
Surface Point ID:� Sampler(s): 7� ��Q () J i
Location:
Field Parameters:
Time of Sampling:
pH:
Temperature:
Conductivity:
Turbidity:
Dissolved Oxygen
/Ds-v
)7,0
6-bYa (US/cm)
57L9, 5 (ntu)
p, v
(mg/L)
Oxidation -Reduction Potential (mv)
Comments/Sample Description (weather conditions, odor, color, silt, etc.):
Summary/Sketch of Sampling Location
Signature: K'��
QA/QC Sign Off:
GJ
Date: / ,
Date:_q/1
3 19oa2

Appendix 3
Laboratory Analytical Reports

ENCO Laboratones
Accurate. Timely. Responsive. Innovative.
102-A Woodwinds Industrial Court
Cary NC, 27511
Phone: [phone] FAX: [phone]
Tuesday, April 12, 2022
La Bella Associates, PC (LA039)
Attn: Van Burbach
12-D Oak Branch Drive
Greensboro, NC 27407
RE: Laboratory Results for
Project Number: 2211161.01, Project Name/Desc: Catawba Co Blackburn Facility - Blanks
ENCO Workorder(s):
CF03667,CF03668,CF03669,CF03670,CF03671,CF03672,CF03673,CF03674
Dear Van Burbach,
Enclosed is a copy of your laboratory report for test samples received by our laboratory on
Friday, March 25, 2022.
Unless otherwise noted in an attached project narrative, all samples were received in
acceptable condition and processed in accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained in this report are in compliance with NELAC standards, except
as noted in the project narrative if applicable. This report shall not be reproduced except in
full, without the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further information, please do not hesitate to contact me.
Sincerely,
Amanda L. Gaines
Project Manager
Enclosure(s)
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 1 of

(� �Eo
www.encolabs.com
SAMPLE SUMMARY/LABORATORY CHRONICLE
Client ID: 1803-TripBlank
Lab ID: CF03667-01
Sampled: 03/24/22 10:50
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 8260D
EPA 503013_MS
04/07/22
03/29/22 14:48
03/30/22 03:45
EPA 8260D
EPA 503013_MS
04/07/22
04/04/22 20:25
04/05/22 08:16
Client ID: 1803-MW2
Lab ID: CF03668-01
Sampled: 03/23/22 13:30
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/19/22
03/30/22 09:37
04/01/22 10:37
EPA 7470A
EPA 245.1
04/20/22
04/01/22 04:21
04/05/22 05:42
EPA 8260D
EPA 503013_MS
04/06/22
03/31/22 11:32
03/31/22 17:06
EPA 8260D
EPA 5030B_MS
04/06/22
04/04/22 16:00
04/04/22 22:11
Client ID: 1803-MW26
Lab ID: CF03668-02
Sampled: 03/23/22 14:40
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/19/22
03/30/22 09:37
04/01/22 10:40
EPA 7470A
EPA 245.1
04/20/22
04/01/22 04:21
04/05/22 05:44
EPA 8260D
EPA 503013_MS
04/06/22
03/31/22 11:32
03/31/22 17:31
EPA 8260D
EPA 503013_MS
04/06/22
04/04/22 16:00
04/04/22 22:39
Client ID: 1803-MW27
Lab ID: CF03668-03
Sampled: 03/23/22 14:25
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/19/22
03/30/22 09:37
04/01/22 10:42
EPA 7470A
EPA 245.1
04/20/22
04/01/22 04:21
04/05/22 05:46
EPA 8260D
EPA 5030B_MIS
04/06/22
03/31/22 11:32
03/31/22 17:57
EPA 8260D
EPA 503013_MS
04/06/22
04/04/22 16:00
04/04/22 23:06
Client ID: 1803-MW21
Lab ID: CF03669-01
Sampled: 03/23/22 11:35
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/19/22
03/30/22 09:37
04/01/22 09:52
EPA 7470A
EPA 245.1
04/20/22
04/01/22 04:21
04/05/22 05:49
EPA 8260D
EPA 503013_MS
04/06/22
03/29/22 14:48
03/30/22 01:11
EPA 8260D
EPA 503013_MS
04/06/22
04/04/22 16:00
04/04/22 23:34
Client ID: 1803-MW24
Lab ID: CF03669-02
Sampled: 03/23/22 11:59
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/19/22
03/30/22 09:37
04/01/22 10:45
EPA 7470A
EPA 245.1
04/20/22
04/01/22 04:21
04/05/22 05:57
EPA 8260D
EPA 503013_MS
04/06/22
03/29/22 14:48
03/30/22 01:36
EPA 8260D
EPA 503013_MS
04/06/22
04/01/22 19:44
04/02/22 23:25
Client ID: 1803-MW25
Lab ID: CF03669-03
Sampled: 03/23/22 12:21
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/19/22
03/30/22 09:37
04/01/22 10:48
EPA 7470A
EPA 245.1
04/20/22
04/01/22 04:21
04/05/22 05:59
EPA 8260D
EPA 503013_MS
04/06/22
03/29/22 14:48
03/30/22 02:02
EPA 8260D
EPA 503013_MS
04/06/22
04/01/22 19:44
04/02/22 23:52
Client ID: 1803-MW28
Lab ID: CF03669-04
Sampled: 03/24/22 09:30
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/20/22
03/30/22 09:37
04/01/22 10:51
EPA 7470A
EPA 245.1
04/21/22
04/01/22 04:21
04/05/22 06:02
EPA 8260D
EPA 5030B_MS
04/07/22
03/29/22 14:48
03/30/22 02:28
EPA 8260D
EPA 5030B_MS
04/07/22
04/04/22 20:25
04/05/22 12:52
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 2 Of 118

(� �Eo
www.encolabs.com
SAMPLE SUMMARY/LABORATORY CHRONICLE
Client ID: 1803-MW29
Lab ID: CF03669-05
Sampled: 03/24/22 09:23
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/20/22
03/30/22 09:37
04/01/22 10:54
EPA 7470A
EPA 245.1
04/21/22
04/01/22 04:21
04/05/22 06:04
EPA 8260D
EPA 503013_MS
04/07/22
03/29/22 14:48
03/30/22 02:54
EPA 8260D
EPA 503013_MS
04/07/22
04/04/22 20:25
04/05/22 13:20
Client ID: 1803-MW30
Lab ID: CF03669-06
Sampled: 03/24/22 09:15
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/20/22
03/30/22 09:37
04/01/22 10:56
EPA 7470A
EPA 245.1
04/21/22
04/01/22 04:21
04/05/22 06:07
EPA 8260D
EPA 503013_MS
04/07/22
03/29/22 14:48
03/30/22 03:19
EPA 8260D
EPA 503013_MS
04/07/22
04/04/22 20:25
04/05/22 13:48
Client ID: 1803-Leachate
Lab ID: CF03670-01
Sampled: 03/24/22 10:50
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 300.0
NO PREP
04/21/22
04/07/22 09:10
04/07/22 16:10
EPA 353.2
NO PREP
03/26/22 10:50
03/25/22 15:39
03/25/22 17:29
EPA 353.2
[CALC]
03/26/22 10:50
04/07/22 09:18
04/07/22 14:48
EPA 353.2
NO PREP
04/21/22
04/07/22 09:18
04/07/22 14:48
EPA 365.1
NO PREP
03/26/22 10:50
03/25/22 15:46
03/25/22 17:55
EPA 6010D
EPA 3005A
09/20/22
03/30/22 09:37
04/01/22 10:59
EPA 6020B
EPA 3005A
09/20/22
03/29/22 05:12
04/04/22 10:43
EPA 8260D
EPA 503013_MS
04/07/22
04/04/22 20:25
04/05/22 14:16
SM 5210 B-2011
NO PREP
03/26/22 10:50
03/25/22 12:30
03/25/22 12:30
SM 5220D-2011
Same
04/21/22
04/01/22 10:10
04/01/22 12:43
Client ID: 1803-Leachate
Lab ID: CF03670-01RE1
Sampled: 03/24/22 10:50
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 8260D
EPA 5030B_MS
04/07/22
04/07/22 12:49
04/07/22 19:35
Client ID: 1803-SW3
Lab ID: CF03671-01
Sampled: 03/24/22 10:30
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/20/22
03/30/22 09:37
04/01/22 11:02
EPA 6020E
EPA 3005A
09/20/22
03/29/22 05:12
04/04/22 10:47
EPA 8260D
EPA 503013_MS
04/07/22
03/31/22 11:32
03/31/22 13:14
EPA 8260D
EPA 503013_MS
04/07/22
04/04/22 20:25
04/05/22 14:44
SM 2340B-2011
EPA 3005A
12/17/24
03/30/22 09:37
04/01/22 11:02
Client ID: 1803-SW4
Lab ID: CF03671-02
Sampled: 03/24/22 10:15
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/20/22
03/30/22 09:37
04/01/22 11:12
EPA 6020B
EPA 3005A
09/20/22
03/29/22 05:12
04/04/22 11:06
EPA 8260D
EPA 503013_MS
04/07/22
03/31/22 11:32
03/31/22 13:39
EPA 8260D
EPA 503013_MS
04/07/22
04/04/22 16:00
04/05/22 00:01
SM 2340B-2011
EPA 3005A
12/17/24
03/30/22 09:37
04/01/22 11:12
Client ID: 1803-SWS
Lab ID: CF03671-03
Sampled: 03/24/22 09:57
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/20/22
03/30/22 09:37
04/01/22 11:14
EPA 6020E
EPA 3005A
09/20/22
03/29/22 05:12
04/04/22 11:10
EPA 8260D
EPA 503013_MS
04/07/22
03/31/22 11:32
03/31/22 14:05
EPA 8260D
EPA 503013_MS
04/07/22
04/04/22 16:00
04/05/22 00:29
SM 2340B-2011
EPA 3005A
12/17/24
03/30/22 09:37
04/01/22 11:14
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 3 Of

(� �Eo
www.encolabs.com
SAMPLE SUMMARY/LABORATORY CHRONICLE
Client ID: 1803-MWS
Lab ID: CF03672-01
Sampled: 03/23/22 15:52
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/19/22
03/30/22 09:37
04/01/22 11:17
EPA 6020E
EPA 3005A
09/19/22
03/29/22 05:12
04/04/22 11:14
EPA 8260D
EPA 503013_MS
04/06/22
03/30/22 13:00
03/31/22 01:48
EPA 8260D
EPA 503013_MS
04/06/22
04/01/22 19:44
04/03/22 00:20
Client ID: 1803-MWSA
Lab ID: CF03672-02
Sampled: 03/22/22 17:50
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/18/22
03/30/22 09:37
04/01/22 11:20
EPA 6020E
EPA 3005A
09/18/22
03/29/22 05:12
04/04/22 11:18
EPA 8260D
EPA 503013_MS
04/05/22
03/30/22 13:00
03/31/22 02:13
EPA 8260D
EPA 503013_MS
04/05/22
04/01/22 15:00
04/01/22 23:03
Client ID: 1803-MW6
Lab ID: CF03672-03
Sampled: 03/23/22 17:25
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/19/22
03/30/22 09:37
04/01/22 11:22
EPA 6020B
EPA 3005A
09/19/22
03/29/22 05:12
04/04/22 11:23
EPA 8260D
EPA 503013_MS
04/06/22
04/01/22 15:09
04/02/22 10:29
Client ID: 1803-MW6
Lab ID: CF03672-03RE1
Sampled: 03/23/22 17:25
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 8260D
EPA 503013_MS
04/06/22
03/31/22 11:32
03/31/22 12:48
Client ID: 1803-MW6D
Lab ID: CF03672-04
Sampled: 03/23/22 17:50
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/19/22
03/30/22 09:37
04/01/22 11:25
EPA 6020E
EPA 3005A
09/19/22
03/29/22 05:12
04/04/22 11:27
EPA 8260D
EPA 503013_MS
04/06/22
03/30/22 13:00
03/31/22 03:05
EPA 8260D
EPA 503013_MS
04/06/22
04/01/22 15:09
04/02/22 10:56
Client ID: 1803-MW7
Lab ID: CF03672-05
Sampled: 03/23/22 15:42
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/19/22
03/30/22 09:37
04/01/22 11:27
EPA 6020E
EPA 3005A
09/19/22
03/29/22 05:12
04/04/22 11:31
EPA 8260D
EPA 503013_MS
04/06/22
03/30/22 13:00
03/31/22 03:31
EPA 8260D
EPA 503013_MS
04/06/22
04/01/22 15:09
04/02/22 11:24
Client ID: 1803-MWll
Lab ID: CF03672-06
Sampled: 03/22/22 16:19
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/18/22
03/29/22 05:09
04/01/22 13:01
EPA 6020E
EPA 3005A
09/18/22
03/29/22 05:12
04/04/22 11:35
EPA 8260D
EPA 503013_MS
04/05/22
03/30/22 13:00
03/31/22 03:57
EPA 8260D
EPA 5030B_MS
04/05/22
04/01/22 15:00
04/01/22 23:31
Client ID: 1803-MW20
Lab ID: CF03672-07
Sampled: 03/23/22 16:04
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/19/22
03/29/22 05:09
04/01/22 13:11
EPA 6020B
EPA 3005A
09/19/22
03/29/22 05:12
04/04/22 11:40
EPA 8260D
EPA 503013_MS
04/06/22
03/30/22 13:00
03/31/22 04:22
EPA 8260D
EPA 503013_MS
04/06/22
04/01/22 15:09
04/02/22 11:51
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 4 Of 118

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SAMPLE SUMMARY/LABORATORY CHRONICLE
Client ID: 1803-PZBSB
Lab ID: CF03672-08
Sampled: 03/23/22 10:17
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/19/22
03/29/22 05:09
04/01/22 13:06
EPA 6020E
EPA 3005A
09/19/22
03/29/22 05:12
04/04/22 11:44
EPA 8260D
EPA 503013_MS
04/06/22
03/30/22 13:00
03/31/22 04:48
EPA 8260D
EPA 503013_MS
04/06/22
04/01/22 15:09
04/02/22 12:19
Client ID: 1803-PZ86B
Lab ID: CF03672-09
Sampled: 03/23/22 10:40
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/19/22
03/29/22 05:09
04/01/22 13:09
EPA 6020E
EPA 3005A
09/19/22
03/29/22 05:12
04/04/22 11:58
EPA 8260D
EPA 503013_MS
04/06/22
03/30/22 13:00
03/31/22 05:14
EPA 8260D
EPA 503013_MS
04/06/22
04/01/22 15:09
04/02/22 12:46
Client ID: 1803-MW12R
Lab ID: CF03673-01
Sampled: 03/23/22 15:35
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/19/22
03/29/22 05:09
04/01/22 11:33
EPA 6020B
EPA 3005A
09/19/22
03/29/22 05:12
04/04/22 12:02
EPA 8260D
EPA 503013_MS
04/06/22
03/31/22 11:32
03/31/22 14:31
EPA 8260D
EPA 5030B_MS
04/06/22
04/01/22 15:09
04/02/22 13:14
Client ID: 1803-MW13
Lab ID: CF03673-02
Sampled: 03/23/22 15:23
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/19/22
03/29/22 05:09
04/01/22 13:14
EPA 6020B
EPA 3005A
09/19/22
03/29/22 05:12
04/04/22 12:06
EPA 8260D
EPA 503013_MS
04/06/22
03/31/22 11:32
03/31/22 14:57
EPA 8260D
EPA 503013_MS
04/06/22
04/01/22 15:09
04/02/22 13:41
Client ID: 1803-MW14
Lab ID: CF03673-03
Sampled: 03/23/22 15:15
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/19/22
03/29/22 05:09
04/01/22 13:17
EPA 6020B
EPA 3005A
09/19/22
03/29/22 05:12
04/04/22 12:10
EPA 8260D
EPA 5030B_MIS
04/06/22
03/31/22 11:32
03/31/22 15:23
EPA 8260D
EPA 503013_MS
04/06/22
04/01/22 15:09
04/02/22 14:09
Client ID: 1803-MW15
Lab ID: CF03673-04
Sampled: 03/22/22 15:42
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/18/22
03/29/22 05:09
04/01/22 13:25
EPA 6020E
EPA 3005A
09/18/22
03/29/22 05:12
04/04/22 12:15
EPA 8260D
EPA 503013_MS
04/05/22
03/31/22 11:32
03/31/22 15:48
EPA 8260D
EPA 503013_MS
04/05/22
04/01/22 15:00
04/01/22 23:58
Client ID: 1803-MW16
Lab ID: CF03673-05
Sampled: 03/23/22 15:07
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/19/22
03/29/22 05:09
04/01/22 13:27
EPA 6020E
EPA 3005A
09/19/22
03/29/22 05:12
04/04/22 12:19
EPA 8260D
EPA 503013_MS
04/06/22
03/31/22 11:32
03/31/22 16:14
EPA 8260D
EPA 503013_MS
04/06/22
04/01/22 15:09
04/02/22 14:37
Client ID: 1803-MW17
Lab ID: CF03673-06
Sampled: 03/23/22 14:56
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/19/22
03/29/22 05:09
04/01/22 13:30
EPA 6020E
EPA 3005A
09/19/22
03/29/22 05:12
04/04/22 12:23
EPA 8260D
EPA 503013_MS
04/06/22
03/31/22 11:32
03/31/22 16:40
EPA 8260D
EPA 503013_MS
04/06/22
04/01/22 15:09
04/02/22 15:05
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Pager) Of 118

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SAMPLE SUMMARY/LABORATORY CHRONICLE
Client ID: 1803-MW31R
Lab ID: CF03674-01
Sampled: 03/24/22 09:06
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/20/22
03/29/22 05:09
04/01/22 13:32
EPA 6020E
EPA 3005A
09/20/22
03/29/22 05:15
04/04/22 14:15
EPA 8260D
EPA 503013_MS
04/07/22
03/31/22 11:32
03/31/22 18:23
EPA 8260D
EPA 503013_MS
04/07/22
04/04/22 16:00
04/05/22 01:51
Client ID: 1803-MW32
Lab ID: CF03674-02
Sampled: 03/24/22 08:58
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/20/22
03/29/22 05:09
04/01/22 13:35
EPA 6020E
EPA 3005A
09/20/22
03/29/22 05:15
04/04/22 14:20
EPA 8260D
EPA 503013_MS
04/07/22
03/31/22 11:32
03/31/22 18:49
EPA 8260D
EPA 503013_MS
04/07/22
04/04/22 16:00
04/05/22 02:18
Client ID: 1803-MW33R
Lab ID: CF03674-03
Sampled: 03/24/22 08:51
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/20/22
03/29/22 05:09
04/01/22 13:37
EPA 6020B
EPA 3005A
09/20/22
03/29/22 05:15
04/04/22 14:24
EPA 8260D
EPA 503013_MS
04/07/22
03/31/22 11:32
03/31/22 19:15
EPA 8260D
EPA 5030B_MS
04/07/22
04/04/22 16:00
04/05/22 02:46
Client ID: 1803-MW35
Lab ID: CF03674-04
Sampled: 03/24/22 08:35
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/20/22
03/29/22 05:09
04/01/22 13:40
EPA 6020B
EPA 3005A
09/20/22
03/29/22 05:15
04/04/22 14:28
EPA 8260D
EPA 503013_MS
04/07/22
03/31/22 11:32
03/31/22 19:40
EPA 8260D
EPA 503013_MS
04/07/22
04/04/22 16:00
04/05/22 03:13
Client ID: 1803-MW36
Lab ID: CF03674-05
Sampled: 03/24/22 08:45
Received: 03/25/22 14:00
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 6010D
EPA 3005A
09/20/22
03/29/22 05:09
04/01/22 13:42
EPA 6020B
EPA 3005A
09/20/22
03/29/22 05:15
04/04/22 14:32
EPA 8260D
EPA 5030B_MIS
04/07/22
03/31/22 11:32
03/31/22 20:06
EPA 8260D
EPA 503013_MS
04/07/22
04/04/22 16:00
04/05/22 03:40
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 6 Of 118

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SAMPLE DETECTION SUMMARY
Client ID: 1803-MW2
Lab ID:
CF03668-01
Analvte
Results
Flag
MDL
PQL
Units
Method
Notes
1,4-Dioxane
3.7
0.80
2.0
ug/L
EPA 8260D
Barium - Total
436
1.10
10.0
ug/L
EPA 6010D
Benzene
0.52
J
0.15
1.0
ug/L
EPA 8260D
Chromium - Total
3.29
J
1.40
10.0
ug/L
EPA 6010D
Client ID: 1803-MW26
Lab ID:
CF03668-02
Analvte
Results
Flag
MDL
PQL
Units
Method
Notes
Barium - Total
58.8
1.10
10.0
ug/L
EPA 6010D
Client ID: 1803-MW27
Lab ID:
CF03668-03
Analvte
Results
Flag
MDL
PQL
Units
Method
Notes
1,4-Dioxane
2.5
0.80
2.0
ug/L
EPA 8260D
Barium - Total
1710
1.10
10.0
ug/L
EPA 6010D
Chromium - Total
9.33
J
1.40
10.0
ug/L
EPA 6010D
Client ID: 1803-MW21
Lab ID:
CF03669-01
Analvte
Results
Flag
MDL
PQL
Units
Method
Notes
Barium - Total
98.6
1.10
10.0
ug/L
EPA 6010D
Chromium - Total
3.89
1
1.40
10.0
ug/L
EPA 6010D
Client ID: 1803-MW24
Lab ID:
CF03669-02
Analvte
Results
Flag
MDL
PQL
Units
Method
Notes
1,4-Dioxane
9.1
0.80
2.0
ug/L
EPA 8260D
Barium - Total
304
1.10
10.0
ug/L
EPA 6010D
Benzene
1.1
0.15
1.0
ug/L
EPA 8260D
Chromium - Total
11.4
1.40
10.0
ug/L
EPA 6010D
Tetrahydrofuran
11
0.53
1.0
ug/L
EPA 8260D
Client ID: 1803-MW25
Lab ID:
CF03669-03
Analvte
Results
Flag
MDL
PQL
Units
Method
Notes
1,4-Dioxane
26
0.80
2.0
ug/L
EPA 8260D
Barium - Total
299
1.10
10.0
ug/L
EPA 6010D
Benzene
1.8
0.15
1.0
ug/L
EPA 8260D
Chromium - Total
7.64
J
1.40
10.0
ug/L
EPA 6010D
Tetrahydrofuran
51
0.53
1.0
uq/L
EPA 8260D
Client ID: 1803-MW28
Lab ID:
CF03669-04
Analvte
Results
Flag
MDL
PQL
Units
Method Notes
1,4-Dioxane
7.3
0.80
2.0
ug/L
EPA 8260D
Barium - Total
110
1.10
10.0
ug/L
EPA 6010D
Chromium - Total
1.49
J
1.40
10.0
ug/L
EPA 6010D
Client ID: 1803-MW29
Lab ID:
CF03669-05
Analvte
Results
Flag
MDL
PQL
Units
Method Notes
1,4-Dioxane
1.7
1
0.80
2.0
ug/L
EPA 8260D
Barium - Total
132
1.10
10.0
ug/L
EPA 6010D
Chromium - Total
26.2
1.40
10.0
ug/L
EPA 6010D
Client ID: 1803-MW30
Lab ID:
CF03669-06
Analvte
Results
Flag
MDL
PQL
Units
Method Notes
1,4-Dioxane
0.82
J
0.80
2.0
ug/L
EPA 8260D
Barium - Total
53.3
1.10
10.0
ug/L
EPA 6010D
Chromium - Total
1.93
J
1.40
10.0
ug/L
EPA 6010D
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 7 Of 118

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SAMPLE DETECTION SUMMARY
Client ID: 1803-Leachate
Lab ID:
CF03670-01
Analvte
Results
Flag
MDL
Q
Units
Method
Notes
Acetone
3300
D
100
200
ug/L
EPA 8260D
R-04
Antimony - Total
7.92
0.740
2.00
ug/L
EPA 6020E
Barium - Total
173
1.10
10.0
ug/L
EPA 6010D
Biochemical Oxygen Demand
590
2.0
2.0
mg/L
SM 5210 B-2011
Chemical Oxygen Demand
1200
20
20
mg/L
SM 5220D-2011
Chromium - Total
97.6
1.40
10.0
ug/L
EPA 6010D
Cobalt - Total
13.5
1.40
10.0
ug/L
EPA 6010D
Nickel - Total
50.7
2.20
10.0
ug/L
EPA 6010D
Nitrate as N
0.056
J
0.041
0.10
mg/L
EPA 353.2
Nitrate/Nitrite as N
0.056
J
0.041
0.10
mg/L
EPA 353.2
Orthophosphate as P
0.51
B
0.16
0.50
mg/L
EPA 365.1
Toluene
72
D
1.4
10
ug/L
EPA 8260D
R-04
Vanadium - Total
12.5
1.40
10.0
ug/L
EPA 6010D
Zinc - Total
58.0
4.40
10.0
ug/L
EPA 6010D
Client ID: 1803-Leachate
Lab ID:
CF03670-01RE1
Analvte
Results
Flag
MDL
PQL
Units
Method
Notes
2-Butanone
3800
D
26
100
ug/L
EPA 8260D
R-04
4-Methyl-2-pentanone
59
]D
22
100
uq/L
EPA 8260D
R-04
I Client ID: 1803-SW3 Lab ID: CF03671-01
Analvte
Results
Flag
MDL
PQL
Units
Method Notes
Barium - Total
28.8
1.10
10.0
ug/L
EPA 6010D
Chromium - Total
2.01
J
1.40
10.0
ug/L
EPA 6010D
Copper - Total
1.79
J
1.60
10.0
ug/L
EPA 6010D
Hardness - Total
27
B
0.020
0.0
mg/L
SM 2340B-2011
Vanadium - Total
2.37
J
1.40
10.0
ug/L
EPA 6010D
Client ID: 1803-SW4
Lab ID:
CF03671-02
Analvte
Results
Flag
MDL
PQL
Units
Method Notes
Barium - Total
48.3
1.10
10.0
ug/L
EPA 6010D
Hardness - Total
31
B
0.020
0.0
mg/L
SM 2340B-2011
Client ID: 1803-SWS
Lab ID:
CF03671-03
Analvte
Results
Flag
MDL
PQL
Units
Method Notes
Barium - Total
48.3
1.10
10.0
ug/L
EPA 6010D
Chromium - Total
3.11
J
1.40
10.0
ug/L
EPA 6010D
Cobalt - Total
2.15
J
1.40
10.0
ug/L
EPA 6010D
Copper - Total
2.05
J
1.60
10.0
ug/L
EPA 6010D
Hardness - Total
27
B
0.020
0.0
mg/L
SM 2340B-2011
Vanadium - Total
6.28
J
1.40
10.0
uq/L
EPA 6010D
Client ID: 1803-MWS
Lab ID:
CF03672-01
Analvte
Results
Flag MDL
PQL
Units
Method Notes
1,1-Dichloroethane
9.2
0.13
1.0
ug/L
EPA 8260D
1,4-Dichlorobenzene
3.2
0.19
1.0
ug/L
EPA 8260D
1,4-Dioxane
19
0.80
2.0
ug/L
EPA 8260D
Barium - Total
202
1.10
10.0
ug/L
EPA 6010D
Benzene
1.8
0.15
1.0
ug/L
EPA 8260D
Chlorobenzene
2.1
0.17
1.0
ug/L
EPA 8260D
cis-1,2-Dichloroethene
12
0.15
1.0
ug/L
EPA 8260D
Cobalt - Total
3.26
J 1.40
10.0
ug/L
EPA 6010D
Dichlorodifluoromethane
13
0.20
1.0
ug/L
EPA 8260D
Methylene chloride
1.1
0.23
1.0
ug/L
EPA 8260D 0-01
Tetrachloroethene
3.3
0.17
1.0
ug/L
EPA 8260D
Trichloroethene
7.6
0.15
1.0
ug/L
EPA 8260D
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 8 Of 118

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SAMPLE DETECTION SUMMARY
Client ID: 1803-MWSA
Lab ID:
CF03672-02
Analvte
Results
Flag
MDL
Q
Units
Method
Notes
1,1-Dichloroethane
6.2
0.13
1.0
ug/L
EPA 8260D
1,4-Dichlorobenzene
2.3
0.19
1.0
ug/L
EPA 8260D
Barium - Total
224
1.10
10.0
ug/L
EPA 6010D
Benzene
1.7
0.15
1.0
ug/L
EPA 8260D
cis-1,2-Dichloroethene
36
0.15
1.0
ug/L
EPA 8260D
Methylene chloride
1.1
0.23
1.0
ug/L
EPA 8260D
0-01
Tetrachloroethene
6.1
0.17
1.0
ug/L
EPA 8260D
Trichloroethene
12
0.15
1.0
ug/L
EPA 8260D
Vanadium - Total
6.04
J
1.40
10.0
ug/L
EPA 6010D
Client ID: 1803-MW6
Lab ID:
CF03672-03
Analvte
Results
Flag
MDL
Q
Units
Method
Notes
1,1-Dichloroethane
12
0.13
1.0
ug/L
EPA 8260D
1,2-Dichlorobenzene
0.55
J
0.19
1.0
ug/L
EPA 8260D
1,4-Dichlorobenzene
10
0.19
1.0
ug/L
EPA 8260D
Barium - Total
328
1.10
10.0
ug/L
EPA 6010D
Benzene
4.0
0.15
1.0
ug/L
EPA 8260D
Chlorobenzene
4.6
0.17
1.0
ug/L
EPA 8260D
Chromium - Total
11.5
1.40
10.0
ug/L
EPA 6010D
Cobalt - Total
116
1.40
10.0
ug/L
EPA 6010D
Dichlorodifluoromethane
3.8
0.20
1.0
ug/L
EPA 8260D
Nickel - Total
11.5
2.20
10.0
ug/L
EPA 6010D
Tetrachloroethene
2.2
0.17
1.0
ug/L
EPA 8260D
Trichloroethene
3.3
0.15
1.0
ug/L
EPA 8260D
Trichlorofluoromethane
9.2
0.24
1.0
ug/L
EPA 8260D
Vinyl chloride
2.7
0.32
1.0
ug/L
EPA 8260D
Xylenes (Total)
0.72
J
0.45
3.0
ug/L
EPA 8260D
Zinc - Total
4.86
J
4.40
10.0
ug/L
EPA 6010D
Client ID: 1803-MW6
Lab ID:
CF03672-03RE1
Analvte
Results
Flag
MDL
PQL
Units
Method
Notes
1,4-Dioxane
100
D
4.0
10
ug/L
EPA 8260D
Client ID: 1803-MW6D
Lab ID:
CF03672-04
Analvte
Results
Flag
MDL
PQL
Units
Method
Notes
1,1-Dichloroethane
2.2
0.13
1.0
ug/L
EPA 8260D
1,4-Dioxane
5.0
0.80
2.0
ug/L
EPA 8260D
Barium - Total
118
1.10
10.0
ug/L
EPA 6010D
Methylene chloride
0.88
1
0.23
1.0
ug/L
EPA 8260D
0-01
Vanadium - Total
7.13
1
1.40
10.0
ug/L
EPA 6010D
Client ID: 1803-MW7
Lab ID:
CF03672-05
Analvte
Results
Flag
MDL
PQL
Units
Method
Notes
1,4-Dichlorobenzene
7.6
0.19
1.0
ug/L
EPA 8260D
1,4-Dioxane
0.85
1
0.80
2.0
ug/L
EPA 8260D
Barium - Total
262
1.10
10.0
ug/L
EPA 6010D
Benzene
2.8
0.15
1.0
ug/L
EPA 8260D
Chlorobenzene
2.9
0.17
1.0
ug/L
EPA 8260D
Chromium - Total
4.88
J
1.40
10.0
ug/L
EPA 6010D
cis-1,2-Dichloroethene
0.95
J
0.15
1.0
ug/L
EPA 8260D
Cobalt - Total
31.8
1.40
10.0
ug/L
EPA 6010D
Nickel - Total
8.41
J
2.20
10.0
ug/L
EPA 6010D
Thallium - Total
0.645
J
0.220
2.00
ug/L
EPA 6020E
Zinc - Total
4.86
J
4.40
10.0
ug/L
EPA 6010D
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 9 Of 118

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SAMPLE DETECTION SUMMARY
Client ID: 1803-MW31
Lab ID:
CF03672-06
Analvte
Results
Flag
MDL
Q
Units
Method
Notes
1,4-Dichlorobenzene
5.1
0.19
1.0
ug/L
EPA 8260D
Barium - Total
224
1.10
10.0
ug/L
EPA 6010D
Benzene
7.1
0.15
1.0
ug/L
EPA 8260D
Chlorobenzene
8.2
0.17
1.0
ug/L
EPA 8260D
cis-1,2-Dichloroethene
2.1
0.15
1.0
ug/L
EPA 8260D
Cobalt - Total
64.6
1.40
10.0
ug/L
EPA 6010D
Nickel - Total
4.50
J
2.20
10.0
ug/L
EPA 6010D
Vanadium - Total
3.10
J
1.40
10.0
ug/L
EPA 6010D
Zinc - Total
7.50
J
4.40
10.0
ug/L
EPA 6010D
Client ID: 1803-MW20
Lab ID:
CF03672-07
Analvte
Results
Flag
MDL
Q
Units
Method
Notes
Barium - Total
47.8
1.10
10.0
ug/L
EPA 6010D
Chromium - Total
2.04
J
1.40
10.0
ug/L
EPA 6010D
Cobalt - Total
2.16
J
1.40
10.0
ug/L
EPA 6010D
Copper - Total
3.68
J
1.60
10.0
ug/L
EPA 6010D
Vanadium - Total
1.82
J
1.40
10.0
ug/L
EPA 6010D
Zinc - Total
7.86
J
4.40
10.0
ug/L
EPA 6010D
Client ID: 1803-PZBSB
Lab ID:
CF03672-08
Analvte
Results
Flag
MDL
Q
Units
Method
Notes
1,1-Dichloroethane
1.5
0.13
1.0
ug/L
EPA 8260D
Barium - Total
79.3
1.10
10.0
ug/L
EPA 6010D
Chromium - Total
6.36
J
1.40
10.0
ug/L
EPA 6010D
cis-1,2-Dichloroethene
3.2
0.15
1.0
ug/L
EPA 8260D
Tetrachloroethene
8.9
0.17
1.0
ug/L
EPA 8260D
Trichloroethene
3.1
0.15
1.0
ug/L
EPA 8260D
Client ID: 1803-PZ86B
Lab ID:
CF03672-09
Analvte
Results
Flag
MDL
Q
Units
Method
Notes
1,1-Dichloroethane
16
0.13
1.0
ug/L
EPA 8260D
1,2-Dichloropropane
4.6
0.10
1.0
ug/L
EPA 8260D
1,4-Dichlorobenzene
3.3
0.19
1.0
ug/L
EPA 8260D
Barium - Total
115
1.10
10.0
ug/L
EPA 6010D
Benzene
2.3
0.15
1.0
ug/L
EPA 8260D
Chlorobenzene
1.5
0.17
1.0
ug/L
EPA 8260D
cis-1,2-Dichloroethene
69
0.15
1.0
ug/L
EPA 8260D
Methylene chloride
6.4
0.23
1.0
ug/L
EPA 8260D
Tetrachloroethene
27
0.17
1.0
ug/L
EPA 8260D
Trichloroethene
30
0.15
1.0
ug/L
EPA 8260D
Vanadium - Total
2.54
J
1.40
10.0
ug/L
EPA 6010D
Vinyl chloride
2.3
0.32
1.0
ug/L
EPA 8260D
0.83 J 0.45 3.0 uq/L EPA 8260D
I Client ID: 1803-MW12R Lab ID: CF03673-01
Analvte
Results
Flag
MDL
PQL
Units
Method Notes
Barium - Total
159
1.10
10.0
ug/L
EPA 6010D
Chromium - Total
6.97
J
1.40
10.0
ug/L
EPA 6010D
cis-1,2-Dichloroethene
0.81
J
0.15
1.0
ug/L
EPA 8260D
Vinyl chloride
0.53
J
0.32
1.0
ug/L
EPA 8260D
Zinc - Total
8.42
J
4.40
10.0
ug/L
EPA 6010D
Client ID: 1803-MW33
Lab ID:
CF03673-02
Analvte
Results
Flag
MDL
PQL
Units
Method Notes
Barium - Total
37.3
1.10
10.0
ug/L
EPA 6010D
Chromium - Total
2.88
1
1.40
10.0
ug/L
EPA 6010D
Vanadium - Total
1.53
1
1.40
10.0
ug/L
EPA 6010D
Zinc - Total
8.26
1
4.40
10.0
ug/L
EPA 6010D
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 10 Of 118

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SAMPLE DETECTION SUMMARY
Client ID: 1803-MW34
Lab ID:
CF03673-03
Analvte
Results
Flag
MDL
PQL
Units
Method Notes
Barium - Total
27.8
1.10
10.0
ug/L
EPA 6010D
Vanadium - Total
1.59
J
1.40
10.0
ug/L
EPA 6010D
Client ID: 1803-MW15
Lab ID:
CF03673-04
Analvte
Results
Flag
MDL
PQL
Units
Method Notes
Barium - Total
25.3
1.10
10.0
ug/L
EPA 6010D
Chromium - Total
2.23
J
1.40
10.0
uq/L
EPA 6010D
Client ID: 1803-MW16
Lab ID:
CF03673-05
Analvte
Results
Flag
MDL
PQL
Units
Method Notes
Barium - Total
29.5
1.10
10.0
ug/L
EPA 6010D
Copper - Total
1.99
J
1.60
10.0
ug/L
EPA 6010D
Zinc - Total
4.76
J
4.40
10.0
ug/L
EPA 6010D
Client ID: 1803-MW37
Lab ID:
CF03673-06
Analvte
Results
Flag
MDL
PQL
Units
Method Notes
Barium - Total
41.3
1.10
10.0
ug/L
EPA 6010D
Chromium - Total
1.78
J
1.40
10.0
ug/L
EPA 6010D
Cobalt - Total
2.71
J
1.40
10.0
ug/L
EPA 6010D
Copper - Total
4.27
J
1.60
10.0
ug/L
EPA 6010D
Vanadium - Total
5.61
J
1.40
10.0
ug/L
EPA 6010D
Zinc - Total
7.16
J
4.40
10.0
ug/L
EPA 6010D
Client ID: 1803-MW31R
Lab ID:
CF03674-01
Analvte
Results
Flag
MDL
PQL
Units
Method Notes
Barium - Total
103
1.10
10.0
ug/L
EPA 6010D
Chromium - Total
3.07
J
1.40
10.0
ug/L
EPA 6010D
Copper - Total
1.75
J
1.60
10.0
ug/L
EPA 6010D
Zinc - Total
4.91
J
4.40
10.0
uq/L
EPA 6010D
I Client ID: 1803-MW32 Lab ID: CF03674-02
Analvte
Results
Flag
MDL
PQL
Units
Method Notes
Barium - Total
138
1.10
10.0
ug/L
EPA 6010D
Beryllium - Total
0.178
J
0.160
1.00
ug/L
EPA 6010D
Chromium - Total
2.22
J
1.40
10.0
ug/L
EPA 6010D
Cobalt - Total
3.48
J
1.40
10.0
ug/L
EPA 6010D
Copper - Total
1.85
J
1.60
10.0
ug/L
EPA 6010D
Zinc - Total
4.96
J
4.40
10.0
ug/L
EPA 6010D
Client ID: 1803-MW33R
Lab ID:
CF03674-03
Analvte
Results
Flag
MDL
PQL
Units
Method Notes
Barium - Total
65.7
1.10
10.0
ug/L
EPA 6010D
Chromium - Total
1.66
J
1.40
10.0
ug/L
EPA 6010D
Cobalt - Total
2.29
J
1.40
10.0
ug/L
EPA 6010D
Zinc - Total
5.93
J
4.40
10.0
uq/L
EPA 6010D
Client ID: 1803-MW35
Lab ID:
CF03674-04
Analvte
Results
Flag
MDL
PQL
Units
Method Notes
Barium - Total
30.2
1.10
10.0
ug/L
EPA 6010D
Chromium - Total
3.30
1
1.40
10.0
ug/L
EPA 6010D
Zinc - Total
7.94
1
4.40
10.0
ug/L
EPA 6010D
Client ID: 1803-MW36
Lab ID:
CF03674-05
Analvte
Results
Flag
MDL
PQL
Units
Method Notes
Barium - Total
94.0
1.10
10.0
ug/L
EPA 6010D
Chromium - Total
3.00
J
1.40
10.0
ug/L
EPA 6010D
Zinc - Total
5.40
J
4.40
10.0
ug/L
EPA 6010D
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 11 Of 118

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ANALYTICAL RESULTS
Description: 1803-TripBlank Lab Sample ID:CF03667-01 Received: 03/25/22 14:00
Matrix: Water Sampled:03/24/22 10:50 Work Order: CF03667
Project: Catawba Cc Blackburn Facility - Blanks Sampled By: K.Estes/E.Wright/Greyson
Volatile Organic Compounds by GCMS
^ - ENCO Cary rertified analyte [NC 591]
Analyte ICAS Numberl
Results
Flaa
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
1,1,1,2-Tetrachloroethane [630-20-6]A
0.17
u
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
1,1,1-Trichloroethane [71-55-6]A
0.12
u
ug/L
1
0.12
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
1,1,2,2-Tetrachloroethane [79-34-5]A
0.28
u
ug/L
1
0.28
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
1,1,2-Trichloroethane [79-00-5]A
0.14
u
ug/L
1
0.14
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
1,1-Dichloroethane [75-34-3]^
0.13
u
ug/L
1
0.13
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
1,1-Dichloroethene [75-35-4]^
0.21
u
ug/L
1
0.21
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
u
ug/L
1
0.23
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
u
ug/L
1
0.48
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
1,2-Dibromoethane [106-93-4]^
0.66
u
ug/L
1
0.66
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
u
ug/L
1
0.19
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
1,2-Dichloroethane [107-06-2]^
0.21
u
ug/L
1
0.21
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
1,2-Dichloropropane [78-87-5]^
0.10
u
ug/L
1
0.10
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
1,4-Dichlorobenzene [106-46-7]^
0.19
u
ug/L
1
0.19
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
2-Butanone [78-93-3]A
1.3
u
ug/L
1
1.3
5.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
2-Hexanone [591-78-6]A
0.88
u
ug/L
1
0.88
5.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
u
ug/L
1
1.1
5.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY QV-01
Acetone [67-64-1]A
10
u
ug/L
1
10
20
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Acrylonitrile [107-13-1]^
3.5
u
ug/L
1
3.5
10
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Benzene[71-43-2]A
0.15
u
ug/L
1
0.15
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Bromochloromethane [74-97-5]A
0.48
u
ug/L
1
0.48
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Bromodichloromethane [75-27-4]^
0.17
u
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Bromoform [75-25-2]^
0.22
u
ug/L
1
0.22
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Bromomethane [74-83-9]A
0.14
u
ug/L
1
0.14
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY QV-01
Carbon disulfide [75-15-0]A
1.5
u
ug/L
1
1.5
5.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Carbon tetrachloride [56-23-5]A
0.17
u
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Chlorobenzene[108-90-7]A
0.17
u
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Chloroethane [75-00-3]A
0.23
u
ug/L
1
0.23
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Chloroform [67-66-3]^
0.18
u
ug/L
1
0.18
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Chloromethane [74-87-3]A
0.13
u
ug/L
1
0.13
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
cis-1,2-Dichloroethene [156-59-2]^
0.15
u
ug/L
1
0.15
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
cis-1,3-Dichloropropene [10061-01-5]A
0.20
u
ug/L
1
0.20
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Dibromochloromethane [124-48-1]A
0.17
u
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Dibromomethane [74-95-3]A
0.27
u
ug/L
1
0.27
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Ethylbenzene[100-41-4]A
0.13
u
ug/L
1
0.13
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Iodomethane [74-88-4]^
1.7
u
ug/L
1
1.7
5.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Methylene chloride [75-09-2]A
0.23
u
ug/L
1
0.23
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Styrene[100-42-5]A
0.11
u
ug/L
1
0.11
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Tetrachloroethene [127-18-4]A
0.17
u
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Tetrahydrofuran [109-99-9]^
0.53
u
ug/L
1
0.53
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Toluene [108-88-3]^
0.14
u
ug/L
1
0.14
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
u
ug/L
1
0.21
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
u
ug/L
1
0.15
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
trans-1,4-Dichloro-2-butene [110-57-6]A
0.70
u
ug/L
1
0.70
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Trichloroethene [79-01-6]^
0.15
u
ug/L
1
0.15
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Trichlorofluoromethane [75-69-4]^
0.24
u
ug/L
1
0.24
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
Vinyl acetate [108-05-4]A
0.95
u
ug/L
1
0.95
5.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY QV-01
Vinyl chloride [75-01-4]^
0.32
u
ug/L
1
0.32
1.0
2DO4035
EPA 8260D
04/05/22
08:16
RKY
FINAL
This report relates only to the sample as received
by the
laboratory,
and may only be reproduced in full.
I Page 1 2 Of 118

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ANALYTICAL RESULTS
Description: 1803-TripBlank Lab Sample ID:CF03667-01 Received: 03/25/22 14:00
Matrix: Water Sampled:03/24/22 10:50 Work Order: CF03667
Project: Catawba Co Blackburn Facility - Blanks Sampled By: K.Estes/E.Wright/Greyson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte KAS Numberl Results Flaa Units DF MDL POLL Batch Method Analyzed AX Notes
Xylenes (Total) [1330-20-7]^ 0.45 U ug/L 1 0.45 3.0 2DO4035 EPA 8260D 04/05/22 08:16 RKY
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By Notes
4-Bromofluorobenzene
56
1
50.0
112 %
53-136
2DO4035
EPA 6260D
04105122 08:16
RKY
Dibromofluoromethane
50
1
50.0
100 %
67-129
2DO4035
EPA 6260D
04105122 08:16
RKY
Toluene-d8
55
1
50.0
110 %
59-134
2DO4035
EPA 6260D
04105122 08:16
RKY
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
Ay Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80 2.0
2C29041
EPA 8260D
03/30/22 03:45
KKW
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Analyzed
ffly Notes
Toluene-d8
4.7
1
5.00
95 %
75-125
2C29041
EPA 8260D
03130122 03:45
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 1 3 Of 118

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ANALYTICAL RESULTS
Description: 1803-MW2 Lab Sample ID:CF03668-01 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 13:30 Work Order: CF03668
Project: Catawba Co Blackburn Facility - C & D Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds
by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte ICAS Numberl
Results
Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
1,1,1,2-Tetrachloroethane [630-20-6]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
1,1,1-Trichloroethane [71-55-6]^
0.12
U
ug/L
1
0.12
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
1,1,2,2-Tetrachloroethane [79-34-5]^
0.28
U
ug/L
1
0.28
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
1,1,2-Trichloroethane [79-00-5]^
0.14
U
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
1,1-Dichloroethane [75-34-3]^
0.13
U
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
1,1-Dichloroethene [75-35-4]^
0.21
U
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
U
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
U
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
1,2-Dibromoethane [106-93-4]^
0.66
U
ug/L
1
0.66
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
U
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
1,2-Dichloroethane [107-06-2]^
0.21
U
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
1,2-Dichloropropane [78-87-5]^
0.10
U
ug/L
1
0.10
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
1,4-Dichlorobenzene [106-46-7]^
0.19
U
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
2-Butanone [78-93-3]^
1.3
U
ug/L
1
1.3
5.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
2-Hexanone [591-78-6]^
0.88
U
ug/L
1
0.88
5.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
U
ug/L
1
1.1
5.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Acetone[67-64-1]^
10
U
ug/L
1
10
20
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Acrylonitrile [107-13-1]^
3.5
U
ug/L
1
3.5
10
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Benzene [71-43-2]^
0.52
J
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Bromochloromethane [74-97-5]^
0.48
U
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Bromodichloromethane [75-27-4]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Bromoform [75-25-2]^
0.22
U
ug/L
1
0.22
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Bromomethane [74-83-9]^
0.14
U
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY QV-01
Carbon disulfide [75-15-0]^
1.5
U
ug/L
1
1.5
5.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Carbon tetrachloride [56-23-5]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Chlorobenzene [108-90-7]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Chloroethane [75-00-3]^
0.23
U
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY QV-01
Chloroform [67-66-3]^
0.18
U
ug/L
1
0.18
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Chloromethane [74-87-3]^
0.13
U
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
cis- 1,2-Dichloroethene [156-59-2]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
cis- 1,3-Dichloropropene [10061-01-5]^
0.20
U
ug/L
1
0.20
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Dibromochloromethane [124-48-1]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Dibromomethane [74-95-3]^
0.27
U
ug/L
1
0.27
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Ethylbenzene [100-41-4]^
0.13
U
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Iodomethane [74-88-4]^
1.7
U
ug/L
1
1.7
5.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Methylene chloride [75-09-2]^
0.23
U
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Styrene [100-42-5]^
0.11
U
ug/L
1
0.11
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Tetrachloroethene [127-18-4]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Tetrahydrofuran [109-99-9]^
0.53
U
ug/L
1
0.53
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Toluene [108-88-3]^
0.14
U
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
U
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
trans-1,4-Dichloro-2-butene [110-57-6]^
0.70
U
ug/L
1
0.70
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Trichloroethene [79-01-6]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Trichlorofluoromethane [75-69-4]^
0.24
U
ug/L
1
0.24
1.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
Vinyl acetate [108-05-4]^
0.95
U
ug/L
1
0.95
5.0
2DO4032
EPA 8260D
04/04/22
22:11
RKY
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 1 4 Of 118

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ANALYTICAL RESULTS
Description: 1803-MW2 Lab Sample ID:CF03668-01 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 13:30 Work Order: CF03668
Project: Catawba Co Blackburn Facility - C & D Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl Results Flag
Units
DF MDL P L Batch Method Analyzed By Notes
Vinyl chloride [75-01-4]^ 0.32 U
ug/L
1 0.32 1.0 2DO4032 EPA 8260D 04/04/22 22:11 RKY
Xylenes (Total) [1330-20-7]^ 0.45 U
ug/L
1 0.45 3.0 2DO4032 EPA 8260D 04/04/22 22:11 RKY
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
ffy
Notes
4-Bromofluorobenzene
58
1
50.0
115 %
53-136
2DO4032
EPA 8260D
04104122 22:11
RKY
Dibromofluoromethane
50
1
50.0
101 %
67-129
2DO4032
EPA 8260D
04104122 22:11
RKY
Toluene-d8
57
1
50.0
115 %
59-134
2DO4032
EPA 8260D
04104122 22:11
RKY
Metals by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
By
Notes
Mercury [7439-97-6]^
0.150
U
ug/L
1
0.150 0.200
2DO1002
EPA 7470A
04/05/22 05:42
CPH
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
By
Notes
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60 10.0
2C29002
EPA 6010D
04/01/22 10:37
JDH
Barium [7440-39-3]^
436
ug/L
1
1.10 10.0
2C29002
EPA 6010D
04/01/22 10:37
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360 1.00
2C29002
EPA 6010D
04/01/22 10:37
JDH
Chromium [7440-47-3]^
3.29
J
ug/L
1
1.40 10.0
2C29002
EPA 6010D
04/01/22 10:37
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10 10.0
2C29002
EPA 6010D
04/01/22 10:37
JDH
Selenium [7782-49-2]^
6.20
U
ug/L
1
6.20 10.0
2C29002
EPA 6010D
04/01/22 10:37
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90 10.0
2C29002
EPA 6010D
04/01/22 10:37
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
By
Notes
1,4-Dioxane [123-91-1]^
3.7
ug/L
1
0.80 2.0
201031
EPA 8260D
03/31/22 17:06
KKW
Surrogates
Results
DF
So/ke Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By
Notes
Toluene-&
5.1
1
5.00
102 %
75-125
201031
EPA 8260D
0313112217:06
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 15 Of H

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ANALYTICAL RESULTS
Description: 1803-MW26 Lab Sample ID:CF03668-02 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 14:40 Work Order: CF03668
Project: Catawba Co Blackburn Facility - C & D Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds
by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte ICAS Numberl
Results
Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
1,1,1,2-Tetrachloroethane [630-20-6]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
1,1,1-Trichloroethane [71-55-6]^
0.12
U
ug/L
1
0.12
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
1,1,2,2-Tetrachloroethane [79-34-5]^
0.28
U
ug/L
1
0.28
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
1,1,2-Trichloroethane [79-00-5]^
0.14
U
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
1,1-Dichloroethane [75-34-3]^
0.13
U
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
1,1-Dichloroethene [75-35-4]^
0.21
U
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
U
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
U
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
1,2-Dibromoethane [106-93-4]^
0.66
U
ug/L
1
0.66
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
U
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
1,2-Dichloroethane [107-06-2]^
0.21
U
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
1,2-Dichloropropane [78-87-5]^
0.10
U
ug/L
1
0.10
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
1,4-Dichlorobenzene [106-46-7]^
0.19
U
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
2-Butanone [78-93-3]^
1.3
U
ug/L
1
1.3
5.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
2-Hexanone [591-78-6]^
0.88
U
ug/L
1
0.88
5.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
U
ug/L
1
1.1
5.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Acetone[67-64-1]^
10
U
ug/L
1
10
20
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Acrylonitrile [107-13-1]^
3.5
U
ug/L
1
3.5
10
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Benzene [71-43-2]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Bromochloromethane [74-97-5]^
0.48
U
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Bromodichloromethane [75-27-4]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Bromoform [75-25-2]^
0.22
U
ug/L
1
0.22
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Bromomethane [74-83-9]^
0.14
U
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY QV-01
Carbon disulfide [75-15-0]^
1.5
U
ug/L
1
1.5
5.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Carbon tetrachloride [56-23-5]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Chlorobenzene [108-90-7]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Chloroethane [75-00-3]^
0.23
U
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY QV-01
Chloroform [67-66-3]^
0.18
U
ug/L
1
0.18
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Chloromethane [74-87-3]^
0.13
U
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
cis- 1,2-Dichloroethene [156-59-2]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
cis- 1,3-Dichloropropene [10061-01-5]^
0.20
U
ug/L
1
0.20
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Dibromochloromethane [124-48-1]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Dibromomethane [74-95-3]^
0.27
U
ug/L
1
0.27
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Ethylbenzene [100-41-4]^
0.13
U
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Iodomethane [74-88-4]^
1.7
U
ug/L
1
1.7
5.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Methylene chloride [75-09-2]^
0.23
U
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Styrene [100-42-5]^
0.11
U
ug/L
1
0.11
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Tetrachloroethene [127-18-4]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Tetrahydrofuran [109-99-9]^
0.53
U
ug/L
1
0.53
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Toluene [108-88-3]^
0.14
U
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
U
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
trans-1,4-Dichloro-2-butene [110-57-6]^
0.70
U
ug/L
1
0.70
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Trichloroethene [79-01-6]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Trichlorofluoromethane [75-69-4]^
0.24
U
ug/L
1
0.24
1.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
Vinyl acetate [108-05-4]^
0.95
U
ug/L
1
0.95
5.0
2DO4032
EPA 8260D
04/04/22
22:39
RKY
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 1 6 Of 118

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ANALYTICAL RESULTS
Description: 1803-MW26 Lab Sample ID:CF03668-02 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 14:40 Work Order: CF03668
Project: Catawba Co Blackburn Facility - C & D Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl Results Flag
Units
DF MDL P L Batch Method Analyzed By Notes
Vinyl chloride [75-01-4]^ 0.32 U
ug/L
1 0.32 1.0 2DO4032 EPA 8260D 04/04/22 22:39 RKY
Xylenes (Total) [1330-20-7]^ 0.45 U
ug/L
1 0.45 3.0 2DO4032 EPA 8260D 04/04/22 22:39 RKY
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
ffy
Notes
4-Bromofluorobenzene
54
1
50.0
107 %
53-136
2DO4032
EPA 8260D
04104122 22:39
RKY
Dibromofluoromethane
53
1
50.0
106 %
67-129
2DO4032
EPA 8260D
04104122 22:39
RKY
Toluene-d8
56
1
50.0
113 %
59-134
2DO4032
EPA 8260D
04104122 22:39
RKY
Metals by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
Ay
Notes
Mercury [7439-97-6]^
0.150
U
ug/L
1
0.150 0.200
2DO1002
EPA 7470A
04/05/22 05:44
CPH
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
Ay
Notes
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60 10.0
2C29002
EPA 6010D
04/01/22 10:40
JDH
Barium [7440-39-3]^
58.8
ug/L
1
1.10 10.0
2C29002
EPA 6010D
04/01/22 10:40
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360 1.00
2C29002
EPA 6010D
04/01/22 10:40
JDH
Chromium [7440-47-3]^
1.40
U
ug/L
1
1.40 10.0
2C29002
EPA 6010D
04/01/22 10:40
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10 10.0
2C29002
EPA 6010D
04/01/22 10:40
JDH
Selenium [7782-49-2]^
6.20
U
ug/L
1
6.20 10.0
2C29002
EPA 6010D
04/01/22 10:40
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90 10.0
2C29002
EPA 6010D
04/01/22 10:40
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80 2.0
201031
EPA 8260D
03/31/22 17:31
KKW
Surrogates
Results
DF
So/ke Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By
Notes
Toluene-&
4.9
1
5.00
98 %
75-125
201031
EPA 8260D
031311221731
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 17 Of H

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ANALYTICAL RESULTS
Description: 1803-MW27 Lab Sample ID:CF03668-03 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 14:25 Work Order: CF03668
Project: Catawba Co Blackburn Facility - C & D Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds
by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte ICAS Numberl
Results
Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
1,1,1,2-Tetrachloroethane [630-20-6]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
1,1,1-Trichloroethane [71-55-6]^
0.12
U
ug/L
1
0.12
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
1,1,2,2-Tetrachloroethane [79-34-5]^
0.28
U
ug/L
1
0.28
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
1,1,2-Trichloroethane [79-00-5]^
0.14
U
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
1,1-Dichloroethane [75-34-3]^
0.13
U
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
1,1-Dichloroethene [75-35-4]^
0.21
U
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
U
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
U
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
1,2-Dibromoethane [106-93-4]^
0.66
U
ug/L
1
0.66
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
U
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
1,2-Dichloroethane [107-06-2]^
0.21
U
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
1,2-Dichloropropane [78-87-5]^
0.10
U
ug/L
1
0.10
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
1,4-Dichlorobenzene [106-46-7]^
0.19
U
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
2-Butanone [78-93-3]^
1.3
U
ug/L
1
1.3
5.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
2-Hexanone [591-78-6]^
0.88
U
ug/L
1
0.88
5.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
U
ug/L
1
1.1
5.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Acetone[67-64-1]^
10
U
ug/L
1
10
20
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Acrylonitrile [107-13-1]^
3.5
U
ug/L
1
3.5
10
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Benzene [71-43-2]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Bromochloromethane [74-97-5]^
0.48
U
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Bromodichloromethane [75-27-4]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Bromoform [75-25-2]^
0.22
U
ug/L
1
0.22
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Bromomethane [74-83-9]^
0.14
U
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY QV-01
Carbon disulfide [75-15-0]^
1.5
U
ug/L
1
1.5
5.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Carbon tetrachloride [56-23-5]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Chlorobenzene [108-90-7]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Chloroethane [75-00-3]^
0.23
U
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY QV-01
Chloroform [67-66-3]^
0.18
U
ug/L
1
0.18
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Chloromethane [74-87-3]^
0.13
U
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
cis- 1,2-Dichloroethene [156-59-2]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
cis- 1,3-Dichloropropene [10061-01-5]^
0.20
U
ug/L
1
0.20
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Dibromochloromethane [124-48-1]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Dibromomethane [74-95-3]^
0.27
U
ug/L
1
0.27
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Ethylbenzene [100-41-4]^
0.13
U
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Iodomethane [74-88-4]^
1.7
U
ug/L
1
1.7
5.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Methylene chloride [75-09-2]^
0.23
U
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Styrene [100-42-5]^
0.11
U
ug/L
1
0.11
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Tetrachloroethene [127-18-4]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Tetrahydrofuran [109-99-9]^
0.53
U
ug/L
1
0.53
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Toluene [108-88-3]^
0.14
U
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
U
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
trans-1,4-Dichloro-2-butene [110-57-6]^
0.70
U
ug/L
1
0.70
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Trichloroethene [79-01-6]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Trichlorofluoromethane [75-69-4]^
0.24
U
ug/L
1
0.24
1.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
Vinyl acetate [108-05-4]^
0.95
U
ug/L
1
0.95
5.0
2DO4032
EPA 8260D
04/04/22
23:06
RKY
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 1 8 Of 118

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ANALYTICAL RESULTS
Description: 1803-MW27 Lab Sample ID:CF03668-03 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 14:25 Work Order: CF03668
Project: Catawba Co Blackburn Facility - C & D Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl Results Flag
Units
DF MDL P L Batch Method Analyzed By Notes
Vinyl chloride [75-01-4]^ 0.32 U
ug/L
1 0.32 1.0 2DO4032 EPA 8260D 04/04/22 23:06 RKY
Xylenes (Total) [1330-20-7]^ 0.45 U
ug/L
1 0.45 3.0 2DO4032 EPA 8260D 04/04/22 23:06 RKY
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
ffy
Notes
4-Bromofluorobenzene
54
1
50.0
109 %
53-136
2DO4032
EPA 8260D
04104122 23:06
RKY
Dibromofluoromethane
51
1
50.0
102 %
67-129
2DO4032
EPA 8260D
04104122 23:06
RKY
Toluene-d8
55
1
50.0
110 %
59-134
2DO4032
EPA 8260D
04104122 23:06
RKY
Metals by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
By
Notes
Mercury [7439-97-6]^
0.150
U
ug/L
1
0.150 0.200
2DO1002
EPA 7470A
04/05/22 05:46
CPH
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
By
Notes
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60 10.0
2C29002
EPA 6010D
04/01/22 10:42
JDH
Barium [7440-39-3]^
1710
ug/L
1
1.10 10.0
2C29002
EPA 6010D
04/01/22 10:42
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360 1.00
2C29002
EPA 6010D
04/01/22 10:42
JDH
Chromium [7440-47-3]^
9.33
J
ug/L
1
1.40 10.0
2C29002
EPA 6010D
04/01/22 10:42
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10 10.0
2C29002
EPA 6010D
04/01/22 10:42
JDH
Selenium [7782-49-2]^
6.20
U
ug/L
1
6.20 10.0
2C29002
EPA 6010D
04/01/22 10:42
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90 10.0
2C29002
EPA 6010D
04/01/22 10:42
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
By
Notes
1,4-Dioxane [123-91-1]^
2.5
ug/L
1
0.80 2.0
201031
EPA 8260D
03/31/22 17:57
KKW
Surrogates
Results
DF
So/ke Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By
Notes
Toluene-&
4.7
1
5.00
94 %
75-125
201031
EPA 8260D
0313112217:57
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 19 Of H

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW21 Lab Sample ID:CF03669-01 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 11:35 Work Order: CF03669
Project: Catawba Co Blackburn Facility - C & D Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds
by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte ICAS Numberl
Results
Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
1,1,1,2-Tetrachloroethane [630-20-6]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
1,1,1-Trichloroethane [71-55-6]^
0.12
U
ug/L
1
0.12
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
1,1,2,2-Tetrachloroethane [79-34-5]^
0.28
U
ug/L
1
0.28
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
1,1,2-Trichloroethane [79-00-5]^
0.14
U
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
1,1-Dichloroethane [75-34-3]^
0.13
U
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
1,1-Dichloroethene [75-35-4]^
0.21
U
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
U
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
U
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
1,2-Dibromoethane [106-93-4]^
0.66
U
ug/L
1
0.66
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
U
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
1,2-Dichloroethane [107-06-2]^
0.21
U
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
1,2-Dichloropropane [78-87-5]^
0.10
U
ug/L
1
0.10
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
1,4-Dichlorobenzene [106-46-7]^
0.19
U
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
2-Butanone [78-93-3]^
1.3
U
ug/L
1
1.3
5.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
2-Hexanone [591-78-6]^
0.88
U
ug/L
1
0.88
5.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
U
ug/L
1
1.1
5.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Acetone[67-64-1]^
10
U
ug/L
1
10
20
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Acrylonitrile [107-13-1]^
3.5
U
ug/L
1
3.5
10
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Benzene [71-43-2]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Bromochloromethane [74-97-5]^
0.48
U
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Bromodichloromethane [75-27-4]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Bromoform [75-25-2]^
0.22
U
ug/L
1
0.22
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Bromomethane [74-83-9]^
0.14
U
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY QV-01
Carbon disulfide [75-15-0]^
1.5
U
ug/L
1
1.5
5.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Carbon tetrachloride [56-23-5]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Chlorobenzene [108-90-7]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Chloroethane [75-00-3]^
0.23
U
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY QV-01
Chloroform [67-66-3]^
0.18
U
ug/L
1
0.18
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Chloromethane [74-87-3]^
0.13
U
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
cis- 1,2-Dichloroethene [156-59-2]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
cis- 1,3-Dichloropropene [10061-01-5]^
0.20
U
ug/L
1
0.20
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Dibromochloromethane [124-48-1]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Dibromomethane [74-95-3]^
0.27
U
ug/L
1
0.27
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Ethylbenzene [100-41-4]^
0.13
U
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Iodomethane [74-88-4]^
1.7
U
ug/L
1
1.7
5.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Methylene chloride [75-09-2]^
0.23
U
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Styrene [100-42-5]^
0.11
U
ug/L
1
0.11
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Tetrachloroethene [127-18-4]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Tetrahydrofuran [109-99-9]^
0.53
U
ug/L
1
0.53
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Toluene [108-88-3]^
0.14
U
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
U
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
trans-1,4-Dichloro-2-butene [110-57-6]^
0.70
U
ug/L
1
0.70
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Trichloroethene [79-01-6]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Trichlorofluoromethane [75-69-4]^
0.24
U
ug/L
1
0.24
1.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
Vinyl acetate [108-05-4]^
0.95
U
ug/L
1
0.95
5.0
2DO4032
EPA 8260D
04/04/22
23:34
RKY
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 20 Of 118

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ANALYTICAL RESULTS
Description: 1803-MW21 Lab Sample ID:CF03669-01 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 11:35 Work Order: CF03669
Project: Catawba Co Blackburn Facility - C & D Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl Results Flag
Units
DF MDL P L Batch Method Analyzed By Notes
Vinyl chloride [75-01-4]^ 0.32 U
ug/L
1 0.32 1.0 2DO4032 EPA 8260D 04/04/22 23:34 RKY
Xylenes (Total) [1330-20-7]^ 0.45 U
ug/L
1 0.45 3.0 2DO4032 EPA 8260D 04/04/22 23:34 RKY
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
ffy
Notes
4-Bromofluorobenzene
53
1
50.0
106 %
53-136
2DO4032
EPA 8260D
04104122 23:34
RKY
Dibromofluoromethane
51
1
50.0
102 %
67-129
2DO4032
EPA 8260D
04104122 23:34
RKY
Toluene-d8
56
1
50.0
112 %
59-134
2DO4032
EPA 8260D
04104122 2334
RKY
Metals by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
Ay
Notes
Mercury [7439-97-6]^
0.150
U
ug/L
1
0.150 0.200
2DO1002
EPA 7470A
04/05/22 05:49
CPH
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
Ay
Notes
Arsenic [7440-38-2]^
7.60
U
ug/L
1
7.60 10.0
2C29002
EPA 6010D
04/01/22 09:52
JDH
Barium [7440-39-3]^
98.6
ug/L
1
1.10 10.0
2C29002
EPA 6010D
04/01/22 09:52
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360 1.00
2C29002
EPA 6010D
04/01/22 09:52
JDH
Chromium [7440-47-3]^
3.89
J
ug/L
1
1.40 10.0
2C29002
EPA 6010D
04/01/22 09:52
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10 10.0
2C29002
EPA 6010D
04/01/22 09:52
JDH
Selenium [7782-49-2]^
6.20
U
ug/L
1
6.20 10.0
2C29002
EPA 6010D
04/01/22 09:52
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90 10.0
2C29002
EPA 6010D
04/01/22 09:52
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80 2.0
2C29041
EPA 8260D
03/30/22 01:11
KKW
Surrogates
Results
DF
So/ke Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By
Notes
Toluene-&
5.3
1
5.00
106 %
75-125
2C29041
EPA 8260D
03130122 01:11
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 21 Of H

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ANALYTICAL RESULTS
Description: 1803-MW24 Lab Sample ID:CF03669-02 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 11:59 Work Order: CF03669
Project: Catawba Cc Blackburn Facility - C & D Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flan
Units
DF
MDL
I'Q
Batch
Method
Analyzed
By
Notes
1,1,1,2-Tetrachloroethane [630-20-6]A
0.17
U
ug/L
1
0.17
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
1,1,1-Trichloroethane [71-55-6]A
0.12
U
ug/L
1
0.12
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
1,1,2,2-Tetrachloroethane [79-34-5]A
0.28
U
ug/L
1
0.28
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
1,1,2-Trichloroethane [79-00-5]A
0.14
U
ug/L
1
0.14
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
1,1-Dichloroethane [75-34-3]A
0.13
U
ug/L
1
0.13
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
1,1-Dichloroethene [75-35-4]A
0.21
U
ug/L
1
0.21
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
1,2,3-Trichloropropane [96-18-4]A
0.23
U
ug/L
1
0.23
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
1,2-Dibromo-3-chloropropane [96-12-8]A
0.48
U
ug/L
1
0.48
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
1,2-Dibromoethane [106-93-4]A
0.66
U
ug/L
1
0.66
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
1,2-Dichlorobenzene [95-50-1]A
0.19
U
ug/L
1
0.19
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
1,2-Dichloroethane [107-06-2]A
0.21
U
ug/L
1
0.21
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
1,2-Dichloropropane [78-87-5]A
0.10
U
ug/L
1
0.10
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
1,4-Dichlorobenzene [106-46-7]A
0.19
U
ug/L
1
0.19
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
2-Butanone [78-93-3]A
1.3
U
ug/L
1
1.3
5.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
QV-01
2-Hexanone [591-78-6]A
0.88
U
ug/L
1
0.88
5.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
4-Methyl-2-pentanone [108-10-1]A
1.1
U
ug/L
1
1.1
5.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
QV-01
Acetone [67-64-1]A
10
U
ug/L
1
10
20
2DO1023
EPA 8260D
04/02/22 23:25
RKY
QV-01
Acrylonitrile [107-13-1]A
3.5
U
ug/L
1
3.5
10
2DO1023
EPA 8260D
04/02/22 23:25
RKY
QV-01
Benzene [71-43-2]A
1.1
ug/L
1
0.15
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
Bromochloromethane [74-97-5]A
0.48
U
ug/L
1
0.48
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
Bromodichloromethane [75-27-4]A
0.17
U
ug/L
1
0.17
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
Bromoform [75-25-2]A
0.22
U
ug/L
1
0.22
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
Bromomethane [74-83-9]A
0.14
U
ug/L
1
0.14
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
QV-01
Carbon disulfide [75-15-0]A
1.5
U
ug/L
1
1.5
5.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
Carbon tetrachloride [56-23-5]A
0.17
U
ug/L
1
0.17
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
Chlorobenzene[108-90-7]A
0.17
U
ug/L
1
0.17
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
Chloroethane [75-00-3]A
0.23
U
ug/L
1
0.23
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
QV-01
Chloroform [67-66-3]A
0.18
U
ug/L
1
0.18
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
Chloromethane [74-87-3]A
0.13
U
ug/L
1
0.13
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
QV-01
cis-1,2-Dichloroethene [156-59-2]A
0.15
U
ug/L
1
0.15
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
cis-1,3-Dichloropropene [10061-01-5]A
0.20
U
ug/L
1
0.20
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
Dibromochloromethane [124-48-1]A
0.17
U
ug/L
1
0.17
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
Dibromomethane [74-95-3]A
0.27
U
ug/L
1
0.27
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
Ethylbenzene [100-41-4]A
0.13
U
ug/L
1
0.13
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
Iodomethane [74-88-4]A
1.7
U
ug/L
1
1.7
5.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
Methylene chloride [75-09-2]A
0.23
U
ug/L
1
0.23
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
Styrene[100-42-5]A
0.11
U
ug/L
1
0.11
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
Tetrachloroethene [127-18-4]A
0.17
U
ug/L
1
0.17
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
Tetrahydrofuran [109-99-9]A
11
ug/L
1
0.53
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
Toluene [108-88-3]A
0.14
U
ug/L
1
0.14
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
trans-1,2-Dichloroethene [156-60-5]A
0.21
U
ug/L
1
0.21
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
trans-1,3-Dichloropropene [10061-02-6]A
0.15
U
ug/L
1
0.15
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
trans-1,4-Dichloro-2-butene [110-57-6]A
0.70
U
ug/L
1
0.70
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
Trichloroethene [79-01-6]A
0.15
U
ug/L
1
0.15
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
Trichlorofluoromethane [75-69-4]A
0.24
U
ug/L
1
0.24
1.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
Vinyl acetate [108-05-4]A
0.95
U
ug/L
1
0.95
5.0
2DO1023
EPA 8260D
04/02/22 23:25
RKY
QV-01
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 22 Of 118

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ANALYTICAL RESULTS
Description: 1803-MW24 Lab Sample ID:CF03669-02 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 11:59 Work Order: CF03669
Project: Catawba Co Blackburn Facility - C & D Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl Results Flag
Units
DF MDL P L Batch Method Analyzed By Notes
Vinyl chloride [75-01-4]^ 0.32 U
ug/L
1 0.32 1.0 2DO1023 EPA 8260D 04/02/22 23:25 RKY
Xylenes (Total) [1330-20-7]^ 0.45 U
ug/L
1 0.45 3.0 2DO1023 EPA 8260D 04/02/22 23:25 RKY
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
ffy
Notes
4-Bromofluorobenzene
55
1
50.0
110 %
53-136
2DO1023
EPA 8260D
04102122 23:25
RKY
Dibromofluoromethane
47
1
50.0
95 %
67-129
2DO1023
EPA 8260D
04102122 23:25
RKY
Toluene-d8
58
1
50.0
117 %
59-134
2DO1023
EPA 8260D
04102122 23:25
RKY
Metals by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
By
Notes
Mercury [7439-97-6]^
0.150
U
ug/L
1
0.150 0.200
2DO1002
EPA 7470A
04/05/22 05:57
CPH
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
By
Notes
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60 10.0
2C29002
EPA 6010D
04/01/22 10:45
JDH
Barium [7440-39-3]^
304
ug/L
1
1.10 10.0
2C29002
EPA 6010D
04/01/22 10:45
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360 1.00
2C29002
EPA 6010D
04/01/22 10:45
JDH
Chromium [7440-47-3]^
11.4
ug/L
1
1.40 10.0
2C29002
EPA 6010D
04/01/22 10:45
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10 10.0
2C29002
EPA 6010D
04/01/22 10:45
JDH
Selenium [7782-49-2]^
6.20
U
ug/L
1
6.20 10.0
2C29002
EPA 6010D
04/01/22 10:45
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90 10.0
2C29002
EPA 6010D
04/01/22 10:45
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
By
Notes
1,4-Dioxane [123-91-1]^
9.1
ug/L
1
0.80 2.0
2C29041
EPA 8260D
03/30/22 01:36
KKW
Surrogates
Results
DF
So/ke Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By
Notes
Toluene-&
4.8
1
5.00
95 %
75-125
2C29041
EPA 8260D
03130122 01:36
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 23 Of H

00�
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW25 Lab Sample ID:CF03669-03 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 12:21 Work Order: CF03669
Project: Catawba Cc Blackburn Facility - C & D Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flan
Units
DF
MDL
I'Q
Batch
Method
Analyzed
By
Notes
1,1,1,2-Tetrachloroethane [630-20-6]A
0.17
U
ug/L
1
0.17
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
1,1,1-Trichloroethane [71-55-6]A
0.12
U
ug/L
1
0.12
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
1,1,2,2-Tetrachloroethane [79-34-5]A
0.28
U
ug/L
1
0.28
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
1,1,2-Trichloroethane [79-00-5]A
0.14
U
ug/L
1
0.14
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
1,1-Dichloroethane [75-34-3]A
0.13
U
ug/L
1
0.13
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
1,1-Dichloroethene [75-35-4]A
0.21
U
ug/L
1
0.21
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
1,2,3-Trichloropropane [96-18-4]A
0.23
U
ug/L
1
0.23
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
1,2-Dibromo-3-chloropropane [96-12-8]A
0.48
U
ug/L
1
0.48
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
1,2-Dibromoethane [106-93-4]A
0.66
U
ug/L
1
0.66
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
1,2-Dichlorobenzene [95-50-1]A
0.19
U
ug/L
1
0.19
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
1,2-Dichloroethane [107-06-2]A
0.21
U
ug/L
1
0.21
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
1,2-Dichloropropane [78-87-5]A
0.10
U
ug/L
1
0.10
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
1,4-Dichlorobenzene [106-46-7]A
0.19
U
ug/L
1
0.19
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
2-Butanone [78-93-3]A
1.3
U
ug/L
1
1.3
5.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
QV-01
2-Hexanone [591-78-6]A
0.88
U
ug/L
1
0.88
5.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
4-Methyl-2-pentanone [108-10-1]A
1.1
U
ug/L
1
1.1
5.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
QV-01
Acetone [67-64-1]A
10
U
ug/L
1
10
20
2DO1023
EPA 8260D
04/02/22 23:52
RKY
QV-01
Acrylonitrile [107-13-1]A
3.5
U
ug/L
1
3.5
10
2DO1023
EPA 8260D
04/02/22 23:52
RKY
QV-01
Benzene [71-43-2]A
1.8
ug/L
1
0.15
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
Bromochloromethane [74-97-5]A
0.48
U
ug/L
1
0.48
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
Bromodichloromethane [75-27-4]A
0.17
U
ug/L
1
0.17
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
Bromoform [75-25-2]A
0.22
U
ug/L
1
0.22
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
Bromomethane [74-83-9]A
0.14
U
ug/L
1
0.14
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
QV-01
Carbon disulfide [75-15-0]A
1.5
U
ug/L
1
1.5
5.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
Carbon tetrachloride [56-23-5]A
0.17
U
ug/L
1
0.17
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
Chlorobenzene[108-90-7]A
0.17
U
ug/L
1
0.17
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
Chloroethane [75-00-3]A
0.23
U
ug/L
1
0.23
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
QV-01
Chloroform [67-66-3]A
0.18
U
ug/L
1
0.18
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
Chloromethane [74-87-3]A
0.13
U
ug/L
1
0.13
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
QV-01
cis-1,2-Dichloroethene [156-59-2]A
0.15
U
ug/L
1
0.15
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
cis-1,3-Dichloropropene [10061-01-5]A
0.20
U
ug/L
1
0.20
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
Dibromochloromethane [124-48-1]A
0.17
U
ug/L
1
0.17
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
Dibromomethane [74-95-3]A
0.27
U
ug/L
1
0.27
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
Ethylbenzene [100-41-4]A
0.13
U
ug/L
1
0.13
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
Iodomethane [74-88-4]A
1.7
U
ug/L
1
1.7
5.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
Methylene chloride [75-09-2]A
0.23
U
ug/L
1
0.23
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
Styrene[100-42-5]A
0.11
U
ug/L
1
0.11
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
Tetrachloroethene [127-18-4]A
0.17
U
ug/L
1
0.17
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
Tetrahydrofuran [109-99-9]A
51
ug/L
1
0.53
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
Toluene [108-88-3]A
0.14
U
ug/L
1
0.14
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
trans-1,2-Dichloroethene [156-60-5]A
0.21
U
ug/L
1
0.21
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
trans-1,3-Dichloropropene [10061-02-6]A
0.15
U
ug/L
1
0.15
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
trans-1,4-Dichloro-2-butene [110-57-6]A
0.70
U
ug/L
1
0.70
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
Trichloroethene [79-01-6]A
0.15
U
ug/L
1
0.15
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
Trichlorofluoromethane [75-69-4]A
0.24
U
ug/L
1
0.24
1.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
Vinyl acetate [108-05-4]A
0.95
U
ug/L
1
0.95
5.0
2DO1023
EPA 8260D
04/02/22 23:52
RKY
QV-01
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 24 Of 118

(� �Eo
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ANALYTICAL RESULTS
Description: 1803-MW25 Lab Sample ID:CF03669-03 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 12:21 Work Order: CF03669
Project: Catawba Co Blackburn Facility - C & D Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl Results Flag
Units
DF MDL P L Batch Method Analyzed By Notes
Vinyl chloride [75-01-4]^ 0.32 U
ug/L
1 0.32 1.0 2DO1023 EPA 8260D 04/02/22 23:52 RKY
Xylenes (Total) [1330-20-7]^ 0.45 U
ug/L
1 0.45 3.0 2DO1023 EPA 8260D 04/02/22 23:52 RKY
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
ffy
Notes
4-Bromofluorobenzene
54
1
50.0
109 %
53-136
2DO1023
EPA 8260D
04102122 23:52
RKY
Dibromofluoromethane
48
1
50.0
96 %
67-129
2DO1023
EPA 8260D
04102122 23:52
RKY
Toluene-d8
56
1
50.0
113 %
59-134
2DO1023
EPA 8260D
04102122 23:52
RKY
Metals by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
By
Notes
Mercury [7439-97-6]^
0.150
U
ug/L
1
0.150 0.200
2DO1002
EPA 7470A
04/05/22 05:59
CPH
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
By
Notes
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60 10.0
2C29002
EPA 6010D
04/01/22 10:48
JDH
Barium [7440-39-3]^
299
ug/L
1
1.10 10.0
2C29002
EPA 6010D
04/01/22 10:48
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360 1.00
2C29002
EPA 6010D
04/01/22 10:48
JDH
Chromium [7440-47-3]^
7.64
J
ug/L
1
1.40 10.0
2C29002
EPA 6010D
04/01/22 10:48
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10 10.0
2C29002
EPA 6010D
04/01/22 10:48
JDH
Selenium [7782-49-2]^
6.20
U
ug/L
1
6.20 10.0
2C29002
EPA 6010D
04/01/22 10:48
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90 10.0
2C29002
EPA 6010D
04/01/22 10:48
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
By
Notes
1,4-Dioxane [123-91-1]^
26
ug/L
1
0.80 2.0
2C29041
EPA 8260D
03/30/22 02:02
KKW
Surrogates
Results
DF
So/ke Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By
Notes
Toluene-&
4.7
1
5.00
94 %
75-125
2C29041
EPA 8260D
03130122 02:02
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 25 Of H

(� �Eo
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ANALYTICAL RESULTS
Description: 1803-MW28 Lab Sample ID:CF03669-04 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 09:30 Work Order: CF03669
Project: Catawba Co Blackburn Facility - C & D Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte ICAS Numberl
Results
Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
By
Notes
1,1,1,2-Tetrachloroethane [630-20-6]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
1,1,1-Trichloroethane [71-55-6]^
0.12
U
ug/L
1
0.12
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
1,1,2,2-Tetrachloroethane [79-34-5]^
0.28
U
ug/L
1
0.28
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
1,1,2-Trichloroethane [79-00-5]^
0.14
U
ug/L
1
0.14
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
1,1-Dichloroethane [75-34-3]^
0.13
U
ug/L
1
0.13
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
1,1-Dichloroethene [75-35-4]^
0.21
U
ug/L
1
0.21
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
U
ug/L
1
0.23
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
U
ug/L
1
0.48
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
1,2-Dibromoethane [106-93-4]^
0.66
U
ug/L
1
0.66
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
U
ug/L
1
0.19
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
1,2-Dichloroethane [107-06-2]^
0.21
U
ug/L
1
0.21
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
1,2-Dichloropropane [78-87-5]^
0.10
U
ug/L
1
0.10
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
1,4-Dichlorobenzene [106-46-7]^
0.19
U
ug/L
1
0.19
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
2-Butanone [78-93-3]^
1.3
U
ug/L
1
1.3
5.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
2-Hexanone [591-78-6]^
0.88
U
ug/L
1
0.88
5.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
U
ug/L
1
1.1
5.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
QV-01
Acetone[67-64-1]^
10
U
ug/L
1
10
20
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Acrylonitrile [107-13-1]^
3.5
U
ug/L
1
3.5
10
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Benzene [71-43-2]^
0.15
U
ug/L
1
0.15
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Bromochloromethane [74-97-5]^
0.48
U
ug/L
1
0.48
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Bromodichloromethane [75-27-4]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Bromoform [75-25-2]^
0.22
U
ug/L
1
0.22
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Bromomethane [74-83-9]^
0.14
U
ug/L
1
0.14
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
QV-01
Carbon disulfide [75-15-0]^
1.5
U
ug/L
1
1.5
5.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Carbon tetrachloride [56-23-5]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Chlorobenzene [108-90-7]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Chloroethane [75-00-3]^
0.23
U
ug/L
1
0.23
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Chloroform [67-66-3]^
0.18
U
ug/L
1
0.18
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Chloromethane [74-87-3]^
0.13
U
ug/L
1
0.13
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
cis- 1,2-Dichloroethene [156-59-2]^
0.15
U
ug/L
1
0.15
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
cis- 1,3-Dichloropropene [10061-01-5]^
0.20
U
ug/L
1
0.20
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Dibromochloromethane [124-48-1]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Dibromomethane [74-95-3]^
0.27
U
ug/L
1
0.27
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Ethylbenzene [100-41-4]^
0.13
U
ug/L
1
0.13
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Iodomethane [74-88-4]^
1.7
U
ug/L
1
1.7
5.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Methylene chloride [75-09-2]^
0.23
U
ug/L
1
0.23
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Styrene [100-42-5]^
0.11
U
ug/L
1
0.11
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Tetrachloroethene [127-18-4]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Tetrahydrofuran [109-99-9]^
0.53
U
ug/L
1
0.53
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Toluene [108-88-3]^
0.14
U
ug/L
1
0.14
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
U
ug/L
1
0.21
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
U
ug/L
1
0.15
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
trans-1,4-Dichloro-2-butene [110-57-6]^
0.70
U
ug/L
1
0.70
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Trichloroethene [79-01-6]^
0.15
U
ug/L
1
0.15
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Trichlorofluoromethane [75-69-4]^
0.24
U
ug/L
1
0.24
1.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
Vinyl acetate [108-05-4]^
0.95
U
ug/L
1
0.95
5.0
2DO4035
EPA 8260D
04/05/22 12:52
RKY
QV-01
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 26 Of 118

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ANALYTICAL RESULTS
Description: 1803-MW28 Lab Sample ID:CF03669-04 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 09:30 Work Order: CF03669
Project: Catawba Co Blackburn Facility - C & D Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl Results Flag
Units
DF MDL P L Batch Method Analyzed By Notes
Vinyl chloride [75-01-4]^ 0.32 U
ug/L
1 0.32 1.0 2DO4035 EPA 8260D 04/05/22 12:52 RKY
Xylenes (Total) [1330-20-7]^ 0.45 U
ug/L
1 0.45 3.0 2DO4035 EPA 8260D 04/05/22 12:52 RKY
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
ffy
Notes
4-Bromofluorobenzene
52
1
50.0
105 %
53-136
2DO4035
EPA 8260D
04105122 12:52
RKY
Dibromofluoromethane
50
1
50.0
100 %
67-129
2DO4035
EPA 8260D
0410512212:52
RKY
Toluene-d8
55
1
50.0
110 %
59-134
2DO4035
EPA 8260D
0410512212:52
RKY
Metals by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
By
Notes
Mercury [7439-97-6]^
0.150
U
ug/L
1
0.150 0.200
2DO1002
EPA 7470A
04/05/22 06:02
CPH
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
By
Notes
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60 10.0
2C29002
EPA 6010D
04/01/22 10:51
JDH
Barium [7440-39-3]^
110
ug/L
1
1.10 10.0
2C29002
EPA 6010D
04/01/22 10:51
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360 1.00
2C29002
EPA 6010D
04/01/22 10:51
JDH
Chromium [7440-47-3]^
1.49
J
ug/L
1
1.40 10.0
2C29002
EPA 6010D
04/01/22 10:51
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10 10.0
2C29002
EPA 6010D
04/01/22 10:51
JDH
Selenium [7782-49-2]^
6.20
U
ug/L
1
6.20 10.0
2C29002
EPA 6010D
04/01/22 10:51
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90 10.0
2C29002
EPA 6010D
04/01/22 10:51
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
By
Notes
1,4-Dioxane [123-91-1]^
7.3
ug/L
1
0.80 2.0
2C29041
EPA 8260D
03/30/22 02:28
KKW
Surrogates
Results
DF
So/ke Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By
Notes
Toluene-&
4.8
1
5.00
95 %
75-125
2C29041
EPA 8260D
03130122 02:28
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 27 Of H

(� �Eo
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ANALYTICAL RESULTS
Description: 1803-MW29 Lab Sample ID:CF03669-05 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 09:23 Work Order: CF03669
Project: Catawba Co Blackburn Facility - C & D Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds
by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte ICAS Numberl
Results
Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
By
Notes
1,1,1,2-Tetrachloroethane [630-20-6]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
1,1,1-Trichloroethane [71-55-6]^
0.12
U
ug/L
1
0.12
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
1,1,2,2-Tetrachloroethane [79-34-5]^
0.28
U
ug/L
1
0.28
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
1,1,2-Trichloroethane [79-00-5]^
0.14
U
ug/L
1
0.14
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
1,1-Dichloroethane [75-34-3]^
0.13
U
ug/L
1
0.13
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
1,1-Dichloroethene [75-35-4]^
0.21
U
ug/L
1
0.21
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
U
ug/L
1
0.23
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
U
ug/L
1
0.48
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
1,2-Dibromoethane [106-93-4]^
0.66
U
ug/L
1
0.66
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
U
ug/L
1
0.19
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
1,2-Dichloroethane [107-06-2]^
0.21
U
ug/L
1
0.21
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
1,2-Dichloropropane [78-87-5]^
0.10
U
ug/L
1
0.10
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
1,4-Dichlorobenzene [106-46-7]^
0.19
U
ug/L
1
0.19
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
2-Butanone [78-93-3]^
1.3
U
ug/L
1
1.3
5.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
2-Hexanone [591-78-6]^
0.88
U
ug/L
1
0.88
5.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
U
ug/L
1
1.1
5.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
QV-01
Acetone[67-64-1]^
10
U
ug/L
1
10
20
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Acrylonitrile [107-13-1]^
3.5
U
ug/L
1
3.5
10
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Benzene [71-43-2]^
0.15
U
ug/L
1
0.15
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Bromochloromethane [74-97-5]^
0.48
U
ug/L
1
0.48
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Bromodichloromethane [75-27-4]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Bromoform [75-25-2]^
0.22
U
ug/L
1
0.22
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Bromomethane [74-83-9]^
0.14
U
ug/L
1
0.14
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
QV-01
Carbon disulfide [75-15-0]^
1.5
U
ug/L
1
1.5
5.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Carbon tetrachloride [56-23-5]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Chlorobenzene [108-90-7]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Chloroethane [75-00-3]^
0.23
U
ug/L
1
0.23
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Chloroform [67-66-3]^
0.18
U
ug/L
1
0.18
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Chloromethane [74-87-3]^
0.13
U
ug/L
1
0.13
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
cis- 1,2-Dichloroethene [156-59-2]^
0.15
U
ug/L
1
0.15
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
cis- 1,3-Dichloropropene [10061-01-5]^
0.20
U
ug/L
1
0.20
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Dibromochloromethane [124-48-1]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Dibromomethane [74-95-3]^
0.27
U
ug/L
1
0.27
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Ethylbenzene [100-41-4]^
0.13
U
ug/L
1
0.13
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Iodomethane [74-88-4]^
1.7
U
ug/L
1
1.7
5.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Methylene chloride [75-09-2]^
0.23
U
ug/L
1
0.23
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Styrene [100-42-5]^
0.11
U
ug/L
1
0.11
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Tetrachloroethene [127-18-4]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Tetrahydrofuran [109-99-9]^
0.53
U
ug/L
1
0.53
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Toluene [108-88-3]^
0.14
U
ug/L
1
0.14
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
U
ug/L
1
0.21
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
U
ug/L
1
0.15
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
trans-1,4-Dichloro-2-butene [110-57-6]^
0.70
U
ug/L
1
0.70
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Trichloroethene [79-01-6]^
0.15
U
ug/L
1
0.15
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Trichlorofluoromethane [75-69-4]^
0.24
U
ug/L
1
0.24
1.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
Vinyl acetate [108-05-4]^
0.95
U
ug/L
1
0.95
5.0
2DO4035
EPA 8260D
04/05/22 13:20
RKY
QV-01
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 28 Of 118

(� �Eo
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ANALYTICAL RESULTS
Description: 1803-MW29 Lab Sample ID:CF03669-05 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 09:23 Work Order: CF03669
Project: Catawba Co Blackburn Facility - C & D Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl Results Flag
Units
DF MDL P L Batch Method Analyzed By Notes
Vinyl chloride [75-01-4]^ 0.32 U
ug/L
1 0.32 1.0 2DO4035 EPA 8260D 04/05/22 13:20 RKY
Xylenes (Total) [1330-20-7]^ 0.45 U
ug/L
1 0.45 3.0 2DO4035 EPA 8260D 04/05/22 13:20 RKY
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
ffy
Notes
4-Bromofluorobenzene
52
1
50.0
103 %
53-136
2DO4035
EPA 8260D
04105122 13:20
RKY
Dibromofluoromethane
47
1
50.0
95 %
67-129
2DO4035
EPA 8260D
0410512213:20
RKY
Toluene-d8
56
1
50.0
112 %
59-134
2DO4035
EPA 8260D
0410512213:20
RKY
Metals by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
By
Notes
Mercury [7439-97-6]^
0.150
U
ug/L
1
0.150 0.200
2DO1002
EPA 7470A
04/05/22 06:04
CPH
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
By
Notes
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60 10.0
2C29002
EPA 6010D
04/01/22 10:54
JDH
Barium [7440-39-3]^
132
ug/L
1
1.10 10.0
2C29002
EPA 6010D
04/01/22 10:54
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360 1.00
2C29002
EPA 6010D
04/01/22 10:54
JDH
Chromium [7440-47-3]^
26.2
ug/L
1
1.40 10.0
2C29002
EPA 6010D
04/01/22 10:54
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10 10.0
2C29002
EPA 6010D
04/01/22 10:54
JDH
Selenium [7782-49-2]^
6.20
U
ug/L
1
6.20 10.0
2C29002
EPA 6010D
04/01/22 10:54
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90 10.0
2C29002
EPA 6010D
04/01/22 10:54
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
By
Notes
1,4-Dioxane [123-91-1]^
1.7
J
ug/L
1
0.80 2.0
2C29041
EPA 8260D
03/30/22 02:54
KKW
Surrogates
Results
DF
So/ke Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By
Notes
Toluene-&
4.9
1
5.00
98 %
75-125
2C29041
EPA 8260D
03130122 02:54
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 29 Of H

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW30 Lab Sample ID:CF03669-06 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 09:15 Work Order: CF03669
Project: Catawba Co Blackburn Facility - C & D Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds
by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte ICAS Numberl
Results
Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
By
Notes
1,1,1,2-Tetrachloroethane [630-20-6]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
1,1,1-Trichloroethane [71-55-6]^
0.12
U
ug/L
1
0.12
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
1,1,2,2-Tetrachloroethane [79-34-5]^
0.28
U
ug/L
1
0.28
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
1,1,2-Trichloroethane [79-00-5]^
0.14
U
ug/L
1
0.14
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
1,1-Dichloroethane [75-34-3]^
0.13
U
ug/L
1
0.13
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
1,1-Dichloroethene [75-35-4]^
0.21
U
ug/L
1
0.21
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
U
ug/L
1
0.23
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
U
ug/L
1
0.48
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
1,2-Dibromoethane [106-93-4]^
0.66
U
ug/L
1
0.66
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
U
ug/L
1
0.19
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
1,2-Dichloroethane [107-06-2]^
0.21
U
ug/L
1
0.21
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
1,2-Dichloropropane [78-87-5]^
0.10
U
ug/L
1
0.10
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
1,4-Dichlorobenzene [106-46-7]^
0.19
U
ug/L
1
0.19
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
2-Butanone [78-93-3]^
1.3
U
ug/L
1
1.3
5.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
2-Hexanone [591-78-6]^
0.88
U
ug/L
1
0.88
5.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
U
ug/L
1
1.1
5.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
QV-01
Acetone[67-64-1]^
10
U
ug/L
1
10
20
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Acrylonitrile [107-13-1]^
3.5
U
ug/L
1
3.5
10
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Benzene [71-43-2]^
0.15
U
ug/L
1
0.15
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Bromochloromethane [74-97-5]^
0.48
U
ug/L
1
0.48
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Bromodichloromethane [75-27-4]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Bromoform [75-25-2]^
0.22
U
ug/L
1
0.22
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Bromomethane [74-83-9]^
0.14
U
ug/L
1
0.14
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
QV-01
Carbon disulfide [75-15-0]^
1.5
U
ug/L
1
1.5
5.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Carbon tetrachloride [56-23-5]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Chlorobenzene [108-90-7]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Chloroethane [75-00-3]^
0.23
U
ug/L
1
0.23
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Chloroform [67-66-3]^
0.18
U
ug/L
1
0.18
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Chloromethane [74-87-3]^
0.13
U
ug/L
1
0.13
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
cis- 1,2-Dichloroethene [156-59-2]^
0.15
U
ug/L
1
0.15
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
cis- 1,3-Dichloropropene [10061-01-5]^
0.20
U
ug/L
1
0.20
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Dibromochloromethane [124-48-1]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Dibromomethane [74-95-3]^
0.27
U
ug/L
1
0.27
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Ethylbenzene [100-41-4]^
0.13
U
ug/L
1
0.13
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Iodomethane [74-88-4]^
1.7
U
ug/L
1
1.7
5.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Methylene chloride [75-09-2]^
0.23
U
ug/L
1
0.23
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Styrene [100-42-5]^
0.11
U
ug/L
1
0.11
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Tetrachloroethene [127-18-4]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Tetrahydrofuran [109-99-9]^
0.53
U
ug/L
1
0.53
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Toluene [108-88-3]^
0.14
U
ug/L
1
0.14
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
U
ug/L
1
0.21
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
U
ug/L
1
0.15
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
trans-1,4-Dichloro-2-butene [110-57-6]^
0.70
U
ug/L
1
0.70
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Trichloroethene [79-01-6]^
0.15
U
ug/L
1
0.15
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Trichlorofluoromethane [75-69-4]^
0.24
U
ug/L
1
0.24
1.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
Vinyl acetate [108-05-4]^
0.95
U
ug/L
1
0.95
5.0
2DO4035
EPA 8260D
04/05/22 13:48
RKY
QV-01
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 30 Of 118

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ANALYTICAL RESULTS
Description: 1803-MW30 Lab Sample ID:CF03669-06 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 09:15 Work Order: CF03669
Project: Catawba Co Blackburn Facility - C & D Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl Results Flag
Units
DF MDL P L Batch Method Analyzed By Notes
Vinyl chloride [75-01-4]^ 0.32 U
ug/L
1 0.32 1.0 2DO4035 EPA 8260D 04/05/22 13:48 RKY
Xylenes (Total) [1330-20-7]^ 0.45 U
ug/L
1 0.45 3.0 2DO4035 EPA 8260D 04/05/22 13:48 RKY
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
ffy
Notes
4-Bromofluorobenzene
53
1
50.0
106 %
53-136
2DO4035
EPA 8260D
04105122 13:48
RKY
Dibromofluoromethane
49
1
50.0
98 %
67-129
2DO4035
EPA 8260D
0410512213:48
RKY
Toluene-d8
56
1
50.0
112 %
59-134
2DO4035
EPA 8260D
0410512213:48
RKY
Metals by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
Ay
Notes
Mercury [7439-97-6]^
0.150
U
ug/L
1
0.150 0.200
2DO1002
EPA 7470A
04/05/22 06:07
CPH
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
By
Notes
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60 10.0
2C29002
EPA 6010D
04/01/22 10:56
JDH
Barium [7440-39-3]^
53.3
ug/L
1
1.10 10.0
2C29002
EPA 6010D
04/01/22 10:56
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360 1.00
2C29002
EPA 6010D
04/01/22 10:56
JDH
Chromium [7440-47-3]^
1.93
J
ug/L
1
1.40 10.0
2C29002
EPA 6010D
04/01/22 10:56
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10 10.0
2C29002
EPA 6010D
04/01/22 10:56
JDH
Selenium [7782-49-2]^
6.20
U
ug/L
1
6.20 10.0
2C29002
EPA 6010D
04/01/22 10:56
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90 10.0
2C29002
EPA 6010D
04/01/22 10:56
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL PQL
Batch
Method
Analyzed
By
Notes
1,4-Dioxane [123-91-1]^
0.82
J
ug/L
1
0.80 2.0
2C29041
EPA 8260D
03/30/22 03:19
KKW
Surrogates
Results
DF
So/ke Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By
Notes
Toluene-&
4.9
1
5.00
98 %
75-125
2C29041
EPA 8260D
03130122 03:19
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 31 Of H

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ANALYTICAL RESULTS
Description: 1803-Leachate Lab Sample ID:CF03670-01 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 10:50 Work Order: CF03670
Project: Catawba Co Blackburn Facility - Leachate Sampled By: K.Estes/E.Wright
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte ICAS Numberl
Results
Flaa
Units
DF
MDL
POLL
Batch
Method
Analyzed
AX
Notes
1,1,1,2-Tetrachloroethane [630-20-6]^
1.7
UD
ug/L
10
1.7
10
2DO4035
EPA 8260D
04/05/22 14:16
RKY
R-04
1,1,1-Trichloroethane [71-55-6]^
1.2
UD
ug/L
10
1.2
10
2DO4035
EPA 8260D
04/05/22 14:16
RKY
R-04
1,1,2,2-Tetrachloroethane [79-34-5]^
2.8
UD
ug/L
10
2.8
10
2DO4035
EPA 8260D
04/05/22 14:16
RKY
R-04
1,1,2-Trichloroethane [79-00-5]^
1.4
UD
ug/L
10
1.4
10
2DO4035
EPA 8260D
04/05/22 14:16
RKY
R-04
1,1-Dichloroethane [75-34-3]^
1.3
UD
ug/L
10
1.3
10
2DO4035
EPA 8260D
04/05/22 14:16
RKY
R-04
1,1-Dichloroethene [75-35-4]^
2.1
UD
ug/L
10
2.1
10
2DO4035
EPA 8260D
04/05/22 14:16
RKY
R-04
1,2,3-Trichloropropane [96-18-4]^
2.3
UD
ug/L
10
2.3
10
2DO4035
EPA 8260D
04/05/22 14:16
RKY
R-04
1,2-Dibromo-3-chloropropane [96-12-8]^
4.8
UD
ug/L
10
4.8
10
2DO4035
EPA 8260D
04/05/22 14:16
RKY
R-04
1,2-Dibromoethane [106-93-4]^
6.6
UD
ug/L
10
6.6
10
2DO4035
EPA 8260D
04/05/22 14:16
RKY
R-04
1,2-Dichlorobenzene [95-50-1]^
1.9
UD
ug/L
10
1.9
10
2DO4035
EPA 8260D
04/05/22 14:16
RKY
R-04
1,2-Dichloroethane [107-06-2]^
2.1
UD
ug/L
10
2.1
10
2DO4035
EPA 8260D
04/05/22 14:16
RKY
R-04
1,2-Dichloropropane [78-87-5]^
1.0
UD
ug/L
10
1.0
10
2DO4035
EPA 8260D
04/05/22 14:16
RKY
R-04
1,4-Dichlorobenzene [106-46-7]^
1.9
UD
ug/L
10
1.9
10
2DO4035
EPA 8260D
04/05/22 14:16
RKY
R-04
2-Butanone [78-93-3]^
3800
D
ug/L
20
26
100
2DO7015
EPA 8260D
04/07/22 19:35
RKY
R-04
2-Hexanone [591-78-6]^
8.8
UD
ug/L
10
8.8
50
2DO4035
EPA 8260D
04/05/22 14:16
RKY
R-04
4-Methyl-2-pentanone [108-10-1]^
59
JD
ug/L
20
22
100
2DO7015
EPA 8260D
04/07/22 19:35
RKY
R-04
Acetone [67-64-1]^
3300
D
ug/L
10
100
200
2DO4035
EPA 8260D
04/05/22 14:16
RKY
R-04
Acrylonitrile [107-13-1]^
35
UD
ug/L
10
35
100
2DO4035
EPA 8260D
04/05/22 14:16
RKY
R-04
Benzene [71-43-2]^
1.5
UD
ug/L
10
1.5
10
2DO4035
EPA 8260D
04/05/22 14:16
RKY
R-04
Bromochloromethane [74-97-5]^
4.8
UD
ug/L
10
4.8
10
2DO4035
EPA 8260D
04/05/22 14:16
RKY
R-04
Bromodichloromethane [75-27-4]^
1.7
UD
ug/L
10
1.7
10
2DO4035
EPA 8260D
04/05/22 14:16
RKY
R-04
Bromoform [75-25-2]^
2.2
UD
ug/L
10
2.2
10
2DO4035
EPA 8260D
04/05/22 14:16
RKY
R-04
Bromomethane [74-83-9]^
1.4
UD
ug/L
10
1.4
10
2DO4035
EPA 8260D
04/05/22 14:16
RKY
QV-01,
R-04
Carbon disulfide [75-15-0]^
15
UD
ug/L
10
15
50
2DO4035
EPA
8260D
04/05/22
14:16
RKY
R-04
Carbon tetrachloride [56-23-5]^
1.7
UD
ug/L
10
1.7
10
2DO4035
EPA
8260D
04/05/22
14:16
RKY
R-04
Chlorobenzene [108-90-7]^
1.7
UD
ug/L
10
1.7
10
2DO4035
EPA
8260D
04/05/22
14:16
RKY
R-04
Chloroethane [75-00-3]^
2.3
UD
ug/L
10
2.3
10
2DO4035
EPA
8260D
04/05/22
14:16
RKY
R-04
Chloroform [67-66-3]^
1.8
UD
ug/L
10
1.8
10
2DO4035
EPA
8260D
04/05/22
14:16
RKY
R-04
Chloromethane [74-87-3]^
1.3
UD
ug/L
10
1.3
10
2DO4035
EPA
8260D
04/05/22
14:16
RKY
R-04
cis- 1,2-Dichloroethene [156-59-2]^
1.5
UD
ug/L
10
1.5
10
2DO4035
EPA
8260D
04/05/22
14:16
RKY
R-04
cis- 1,3-Dichloropropene [10061-01-5]^
2.0
UD
ug/L
10
2.0
10
2DO4035
EPA
8260D
04/05/22
14:16
RKY
R-04
Dibromochloromethane [124-48-1]^
1.7
UD
ug/L
10
1.7
10
2DO4035
EPA
8260D
04/05/22
14:16
RKY
R-04
Dibromomethane [74-95-3]^
2.7
UD
ug/L
10
2.7
10
2DO4035
EPA
8260D
04/05/22
14:16
RKY
R-04
Ethylbenzene [100-41-4]^
1.3
UD
ug/L
10
1.3
10
2DO4035
EPA
8260D
04/05/22
14:16
RKY
R-04
Iodomethane[74-88-4]^
17
UD
ug/L
10
17
50
2DO4035
EPA
8260D
04/05/22
14:16
RKY
R-04
Methylene chloride [75-09-2]^
2.3
UD
ug/L
10
2.3
10
2DO4035
EPA
8260D
04/05/22
14:16
RKY
R-04
Styrene [100-42-5]^
1.1
UD
ug/L
10
1.1
10
2DO4035
EPA
8260D
04/05/22
14:16
RKY
R-04
Tetrachloroethene [127-18-4]^
1.7
UD
ug/L
10
1.7
10
2DO4035
EPA
8260D
04/05/22
14:16
RKY
R-04
Toluene [108-88-3]^
72
D
ug/L
10
1.4
10
2DO4035
EPA
8260D
04/05/22
14:16
RKY
R-04
trans-1,2-Dichloroethene [156-60-5]^
2.1
UD
ug/L
10
2.1
10
2DO4035
EPA
8260D
04/05/22
14:16
RKY
R-04
trans-1,3-Dichloropropene [10061-02-6]^
1.5
UD
ug/L
10
1.5
10
2DO4035
EPA
8260D
04/05/22
14:16
RKY
R-04
trans-1,4-Dichloro-2-butene [110-57-6]^
7.0
UD
ug/L
10
7.0
10
2DO4035
EPA
8260D
04/05/22
14:16
RKY
R-04
Trichloroethene [79-01-6]^
1.5
UD
ug/L
10
1.5
10
2DO4035
EPA
8260D
04/05/22
14:16
RKY
R-04
Trichlorofluoromethane [75-69-4]^
2.4
UD
ug/L
10
2.4
10
2DO4035
EPA
8260D
04/05/22
14:16
RKY
R-04
Vinyl acetate [108-05-4]^
9.5
UD
ug/L
10
9.5
50
2DO4035
EPA
8260D
04/05/22
14:16
RKY
QV-01,
R-04
FINAL
This report relates only to the sample as received
by the
laboratory,
and may only be reproduced in full.
Page 32 Of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-Leachate Lab Sample ID:CF03670-01 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 10:50 Work Order: CF03670
Project: Catawba Co Blackburn Facility - Leachate Sampled By: K.Estes/E.Wright
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl Results Flaa Units DF MDL POLL Batch Method Analyzed AX Notes
Vinyl chloride [75-01-4]^ 3.2 UD ug/L 10 3.2 10 2DO4035 EPA 8260D 04/05/22 14:16 RKY R-04
Xylenes (Total) [1330-20-7]^ 4.5 UD ug/L 10 4.5 30 2DO4035 EPA 8260D 04/05/22 14:16 RKY R-04
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By
Notes
4-Bromofluorobenzene
49
1
50.0
99 %
53-136
2DO4035
EPA 8260D
04105122 14:16
RKY
R-04
4-Bromofluorobenzene
48
1
50.0
95 %
53-136
2DO7015
EPA 6260D
04107122 19:35
RKY
R-04
Dibromofluoromethane
48
1
50.0
95 %
67-129
2DO4035
EPA 6260D
0410512214:16
RKY
R-04
Dibromofluoromethane
46
1
50.0
92 %
67-129
2DO7015
EPA 6260D
0410712219:35
RKY
R-04
Toluene-d8
54
1
50.0
108 %
59-134
2DO4035
EPA 6260D
0410512214:16
RKY
R-04
Toluene-d8
52
1
50.0
104 %
59-134
2DO7015
EPA 6260D
041071221935
RKY
R-04
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flaa
Units
DF
MDL
POLL
Batch
Method
Analyzed
Ay
Notes
Antimony [7440-36-0]A
7.92
ug/L
2
0.740
2.00
2C29004
EPA 6020B
04/04/22 10:43
JDH
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29002
EPA 6010D
04/01/22 10:59
JDH
Barium [7440-39-3]A
173
ug/L
1
1.10
10.0
2C29002
EPA 6010D
04/01/22 10:59
JDH
Beryllium [7440-41-7]^
0.160
u
ug/L
1
0.160
1.00
2C29002
EPA 6010D
04/01/22 10:59
JDH
Cadmium [7440-43-9]^
0.360
u
ug/L
1
0.360
1.00
2C29002
EPA 6010D
04/01/22 10:59
JDH
Chromium [7440-47-3]A
97.6
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 10:59
JDH
Cobalt[7440-48-4]A
13.5
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 10:59
JDH
Copper[7440-50-8]^
1.60
u
ug/L
1
1.60
10.0
2C29002
EPA 6010D
04/01/22 10:59
JDH
Lead [7439-92-1]^
3.10
u
ug/L
1
3.10
10.0
2C29002
EPA 6010D
04/01/22 10:59
JDH
Nickel[7440-02-O]A
50.7
ug/L
1
2.20
10.0
2C29002
EPA 6010D
04/01/22 10:59
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29004
EPA 6020B
04/04/22 10:43
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29002
EPA 6010D
04/01/22 10:59
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29004
EPA 6020B
04/04/22 10:43
JDH
Vanadium [7440-62-2]A
12.5
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 10:59
JDH
Zinc[7440-66-6]A
58.0
ug/L
1
4.40
10.0
2C29002
EPA 6010D
04/01/22 10:59
JDH
Classical Chemistry Parameters
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flaa
Units
DF
MDL
POLL
Batch
Method
Analyzed
Ay
Notes
Biochemical Oxygen Demand^
590
mg/L
1
2.0
2.0
2C25008
SM 5210 B-2011
03/25/22 12:30
JOC
Chemical Oxygen Demand^
1200
mg/L
2
20
20
2DO1006
SM 5220D-2011
04/01/22 12:43
JOC
Nitrate as N [14797-55-8]
0.056
J
mg/L
1
0.041
0.10
[CALC]
EPA 353.2
04/07/22 14:48
MSE
Nitrate/Nitrite as NA
0.056
J
mg/L
1
0.041
0.10
2DO7010
EPA 353.2
04/07/22 14:48
MSE
Nitrite as N [14797-65-0]^
0.017
U
mg/L
1
0.017
0.10
2C25027
EPA 353.2
03/25/22 17:29
MSE
Orthophosphate as P [1426-54-42]
0.51
B
mg/L
1
0.16
0.50
2C25028
EPA 365.1
03/25/22 17:55
MSE
Sulfate as SO4 [14808-79-8]^
2.9
U
mg/L
1
2.9
5.0
2DO7008
EPA 300.0
04/07/22 16:10
MSE
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 33 Of 118

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www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-SW3 Lab Sample ID:CF03671-01 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 10:30 Work Order: CF03671
Project: Catawba Co Blackburn Facility - Unit 1 - 3 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds
by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte ICAS Numberl
Results
Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
By
Notes
1,1,1,2-Tetrachloroethane [630-20-6]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
1,1,1-Trichloroethane [71-55-6]^
0.12
U
ug/L
1
0.12
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
1,1,2,2-Tetrachloroethane [79-34-5]^
0.28
U
ug/L
1
0.28
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
1,1,2-Trichloroethane [79-00-5]^
0.14
U
ug/L
1
0.14
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
1,1-Dichloroethane [75-34-3]1
0.13
U
ug/L
1
0.13
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
1,1-Dichloroethene [75-35-4]1
0.21
U
ug/L
1
0.21
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
1,2,3-Trichloropropane [96-18-4]1
0.23
U
ug/L
1
0.23
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
U
ug/L
1
0.48
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
1,2-Dibromoethane [106-93-4]1
0.66
U
ug/L
1
0.66
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
U
ug/L
1
0.19
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
1,2-Dichloroethane [107-06-2]1
0.21
U
ug/L
1
0.21
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
1,2-Dichloropropane [78-87-5]1
0.10
U
ug/L
1
0.10
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
1,4-Dichlorobenzene [106-46-7]1
0.19
U
ug/L
1
0.19
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
2-Butanone [78-93-3]^
1.3
U
ug/L
1
1.3
5.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
2-Hexanone [591-78-6]1
0.88
U
ug/L
1
0.88
5.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
U
ug/L
1
1.1
5.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
QV-01
Acetone[67-64-1]^
10
U
ug/L
1
10
20
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Acrylonitrile [107-13-1]^
3.5
U
ug/L
1
3.5
10
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Benzene [71-43-2]^
0.15
U
ug/L
1
0.15
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Bromochloromethane [74-97-5]^
0.48
U
ug/L
1
0.48
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Bromodichloromethane [75-27-4]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Bromoform [75-25-2]^
0.22
U
ug/L
1
0.22
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Bromomethane [74-83-9]^
0.14
U
ug/L
1
0.14
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
QV-01
Carbon disulfide [75-15-0]^
1.5
U
ug/L
1
1.5
5.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Carbon tetrachloride [56-23-5]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Chlorobenzene [108-90-7]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Chloroethane [75-00-3]^
0.23
U
ug/L
1
0.23
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Chloroform [67-66-3]^
0.18
U
ug/L
1
0.18
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Chloromethane [74-87-3]^
0.13
U
ug/L
1
0.13
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
cis- 1,2-Dichloroethene [156-59-2]^
0.15
U
ug/L
1
0.15
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
cis- 1,3-Dichloropropene [10061-01-5]^
0.20
U
ug/L
1
0.20
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Dibromochloromethane [124-48-1]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Dibromomethane [74-95-3]^
0.27
U
ug/L
1
0.27
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Dichlorodifluoromethane [75-71-8]^
0.20
U
ug/L
1
0.20
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Ethylbenzene [100-41-4]^
0.13
U
ug/L
1
0.13
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Iodomethane [74-88-4]^
1.7
U
ug/L
1
1.7
5.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Methylene chloride [75-09-2]^
0.23
U
ug/L
1
0.23
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Styrene [100-42-5]^
0.11
U
ug/L
1
0.11
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Tetrachloroethene [127-18-4]^
0.17
U
ug/L
1
0.17
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Toluene [108-88-3]^
0.14
U
ug/L
1
0.14
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
U
ug/L
1
0.21
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
U
ug/L
1
0.15
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
trans-1,4-Dichloro-2-butene [110-57-6]^
0.70
U
ug/L
1
0.70
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Trichloroethene [79-01-6]^
0.15
U
ug/L
1
0.15
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Trichlorofluoromethane [75-69-4]^
0.24
U
ug/L
1
0.24
1.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
Vinyl acetate [108-05-4]^
0.95
U
ug/L
1
0.95
5.0
2DO4035
EPA 8260D
04/05/22 14:44
RKY
QV-01
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 34 Of 118

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ANALYTICAL RESULTS
Description: 1803-SW3 Lab Sample ID:CF03671-01 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 10:30 Work Order: CF03671
Project: Catawba Co Blackburn Facility - Unit 1 - 3 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte fCAS Numberl Results Flag
Units
DF MDL P L Batch Method Analyzed By Notes
Vinyl chloride [75-01-4]1 0.32 U
ug/L
1 0.32 1.0 2DO4035 EPA 8260D 04/05/22 14:44 RKY
Xylenes (Total) [1330-20-7]1 0.45 U
ug/L
1 0.45 3.0 2DO4035 EPA 8260D 04/05/22 14:44 RKY
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
ffy
Notes
4-Bromofluorobenzene
53
1
50.0
107 %
53-136
2DO4035
EPA 8260D
04105122 14:44
RKY
Dibromofluoromethane
47
1
50.0
94 %
67-129
2DO4035
EPA 8260D
0410512214:44
RKY
Toluene-d8
53
1
50.0
106 %
59-134
2DO4035
EPA 8260D
0410512214:44
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte fCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
By
Notes
Antimony[7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29004
EPA 6020B
04/04/22 10:47
JDH
Arsenic [7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29002
EPA 6010D
04/01/22 11:02
JDH
Barium [7440-39-3]^
28.8
ug/L
1
1.10
10.0
2C29002
EPA 6010D
04/01/22 11:02
JDH
Beryllium [7440-41-7]^
0.160
U
ug/L
1
0.160
1.00
2C29002
EPA 6010D
04/01/22 11:02
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29002
EPA 6010D
04/01/22 11:02
JDH
Chromium [7440-47-3]^
2.01
J
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:02
JDH
Cobalt [7440-48-4]^
1.40
U
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:02
JDH
Copper[7440-50-8]^
1.79
J
ug/L
1
1.60
10.0
2C29002
EPA 6010D
04/01/22 11:02
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29002
EPA 6010D
04/01/22 11:02
JDH
Nickel[7440-02-0]^
2.20
U
ug/L
1
2.20
10.0
2C29002
EPA 6010D
04/01/22 11:02
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29004
EPA 6020B
04/04/22 10:47
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29002
EPA 6010D
04/01/22 11:02
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29004
EPA 6020B
04/04/22 10:47
JDH
Vanadium [7440-62-2]^
2.37
J
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:02
JDH
Zinc [7440-66-6]^
4.40
U
ug/L
1
4.40
10.0
2C29002
EPA 6010D
04/01/22 11:02
JDH
Classical Chemistry Parameters
^ - ENCO Cary certified analyte [NC 591]
Analyte fCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
Hardness^
27
B
mg/L
1
0.020
0.0
2C29002
SM 2340B-2011
04/01/22 11:02
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte fCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80
2.0
201031
EPA 8260D
03/31/22 13:14
KKW
Surrogates
Results
DF
So/ke Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
"
Notes
Toluene-&
4.8
1
5.00
96 %
75-125
201031
EPA 8260D
0313112213:14
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 35 Of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-SW4 Lab Sample ID:CF03671-02 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 10:15 Work Order: CF03671
Project: Catawba Co Blackburn Facility - Unit 1 - 3 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds
by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte ICAS Numberl
Results
Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
1,1,1,2-Tetrachloroethane [630-20-6]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
1,1,1-Trichloroethane [71-55-6]^
0.12
U
ug/L
1
0.12
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
1,1,2,2-Tetrachloroethane [79-34-5]^
0.28
U
ug/L
1
0.28
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
1,1,2-Trichloroethane [79-00-5]^
0.14
U
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
1,1-Dichloroethane [75-34-3]1
0.13
U
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
1,1-Dichloroethene [75-35-4]1
0.21
U
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
1,2,3-Trichloropropane [96-18-4]1
0.23
U
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
U
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
1,2-Dibromoethane [106-93-4]1
0.66
U
ug/L
1
0.66
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
U
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
1,2-Dichloroethane [107-06-2]1
0.21
U
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
1,2-Dichloropropane [78-87-5]1
0.10
U
ug/L
1
0.10
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
1,4-Dichlorobenzene [106-46-7]1
0.19
U
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
2-Butanone [78-93-3]^
1.3
U
ug/L
1
1.3
5.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
2-Hexanone [591-78-6]1
0.88
U
ug/L
1
0.88
5.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
U
ug/L
1
1.1
5.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Acetone[67-64-1]^
10
U
ug/L
1
10
20
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Acrylonitrile [107-13-1]^
3.5
U
ug/L
1
3.5
10
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Benzene [71-43-2]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Bromochloromethane [74-97-5]^
0.48
U
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Bromodichloromethane [75-27-4]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Bromoform [75-25-2]^
0.22
U
ug/L
1
0.22
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Bromomethane [74-83-9]^
0.14
U
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY QV-01
Carbon disulfide [75-15-0]^
1.5
U
ug/L
1
1.5
5.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Carbon tetrachloride [56-23-5]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Chlorobenzene [108-90-7]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Chloroethane [75-00-3]^
0.23
U
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY QV-01
Chloroform [67-66-3]^
0.18
U
ug/L
1
0.18
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Chloromethane [74-87-3]^
0.13
U
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
cis- 1,2-Dichloroethene [156-59-2]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
cis- 1,3-Dichloropropene [10061-01-5]^
0.20
U
ug/L
1
0.20
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Dibromochloromethane [124-48-1]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Dibromomethane [74-95-3]^
0.27
U
ug/L
1
0.27
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Dichlorodifluoromethane [75-71-8]^
0.20
U
ug/L
1
0.20
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Ethylbenzene [100-41-4]^
0.13
U
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Iodomethane [74-88-4]^
1.7
U
ug/L
1
1.7
5.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Methylene chloride [75-09-2]^
0.23
U
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Styrene [100-42-5]^
0.11
U
ug/L
1
0.11
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Tetrachloroethene [127-18-4]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Toluene [108-88-3]^
0.14
U
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
U
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
trans-1,4-Dichloro-2-butene [110-57-6]^
0.70
U
ug/L
1
0.70
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Trichloroethene [79-01-6]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Trichlorofluoromethane [75-69-4]^
0.24
U
ug/L
1
0.24
1.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
Vinyl acetate [108-05-4]^
0.95
U
ug/L
1
0.95
5.0
2DO4032
EPA 8260D
04/05/22
00:01
RKY
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 36 Of 118

(� �Eo
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ANALYTICAL RESULTS
Description: 1803-SW4 Lab Sample ID:CF03671-02 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 10:15 Work Order: CF03671
Project: Catawba Co Blackburn Facility - Unit 1 - 3 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte fCAS Numberl Results Flag
Units
DF MDL P L Batch Method Analyzed By Notes
Vinyl chloride [75-01-4]1 0.32 U
ug/L
1 0.32 1.0 2DO4032 EPA 8260D 04/05/22 00:01 RKY
Xylenes (Total) [1330-20-7]1 0.45 U
ug/L
1 0.45 3.0 2DO4032 EPA 8260D 04/05/22 00:01 RKY
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
ffy
Notes
4-Bromofluorobenzene
53
1
50.0
107 %
53-136
2DO4032
EPA 8260D
04105122 00:01
RKY
Dibromofluoromethane
52
1
50.0
104 %
67-129
2DO4032
EPA 8260D
04105122 00:01
RKY
Toluene-d8
58
1
50.0
116 %
59-134
2DO4032
EPA 8260D
04105122 00:01
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte fCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
By
Notes
Antimony[7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29004
EPA 6020B
04/04/22 11:06
JDH
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29002
EPA 6010D
04/01/22 11:12
JDH
Barium [7440-39-3]^
48.3
ug/L
1
1.10
10.0
2C29002
EPA 6010D
04/01/22 11:12
JDH
Beryllium [7440-41-7]^
0.160
U
ug/L
1
0.160
1.00
2C29002
EPA 6010D
04/01/22 11:12
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29002
EPA 6010D
04/01/22 11:12
JDH
Chromium [7440-47-3]^
1.40
U
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:12
JDH
Cobalt [7440-48-4]^
1.40
U
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:12
JDH
Copper[7440-50-8]^
1.60
U
ug/L
1
1.60
10.0
2C29002
EPA 6010D
04/01/22 11:12
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29002
EPA 6010D
04/01/22 11:12
JDH
Nickel[7440-02-0]^
2.20
U
ug/L
1
2.20
10.0
2C29002
EPA 6010D
04/01/22 11:12
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29004
EPA 6020B
04/04/22 11:06
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29002
EPA 6010D
04/01/22 11:12
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29004
EPA 6020B
04/04/22 11:06
JDH
Vanadium [7440-62-2]^
1.40
U
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:12
JDH
Zinc [7440-66-6]^
4.40
U
ug/L
1
4.40
10.0
2C29002
EPA 6010D
04/01/22 11:12
JDH
Classical Chemistry Parameters
^ - ENCO Cary certified analyte [NC 591]
Analyte fCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
Hardness^
31
B
mg/L
1
0.020
0.0
2C29002
SM 2340B-2011
04/01/22 11:12
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte fCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80
2.0
201031
EPA 8260D
03/31/22 13:39
KKW
Surrogates
Results
DF
So/ke Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
"
Notes
Toluene-&
4.8
1
5.00
96 %
75-125
201031
EPA 8260D
031311221339
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 37 Of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-SW5 Lab Sample ID:CF03671-03 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 09:57 Work Order: CF03671
Project: Catawba Co Blackburn Facility - Unit 1 - 3 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds
by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte ICAS Numberl
Results
Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
1,1,1,2-Tetrachloroethane [630-20-6]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
1,1,1-Trichloroethane [71-55-6]^
0.12
U
ug/L
1
0.12
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
1,1,2,2-Tetrachloroethane [79-34-5]^
0.28
U
ug/L
1
0.28
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
1,1,2-Trichloroethane [79-00-5]^
0.14
U
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
1,1-Dichloroethane [75-34-3]1
0.13
U
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
1,1-Dichloroethene [75-35-4]1
0.21
U
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
1,2,3-Trichloropropane [96-18-4]1
0.23
U
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
U
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
1,2-Dibromoethane [106-93-4]1
0.66
U
ug/L
1
0.66
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
U
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
1,2-Dichloroethane [107-06-2]1
0.21
U
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
1,2-Dichloropropane [78-87-5]1
0.10
U
ug/L
1
0.10
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
1,4-Dichlorobenzene [106-46-7]1
0.19
U
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
2-Butanone [78-93-3]^
1.3
U
ug/L
1
1.3
5.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
2-Hexanone [591-78-6]1
0.88
U
ug/L
1
0.88
5.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
U
ug/L
1
1.1
5.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Acetone[67-64-1]^
10
U
ug/L
1
10
20
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Acrylonitrile [107-13-1]^
3.5
U
ug/L
1
3.5
10
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Benzene [71-43-2]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Bromochloromethane [74-97-5]^
0.48
U
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Bromodichloromethane [75-27-4]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Bromoform [75-25-2]^
0.22
U
ug/L
1
0.22
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Bromomethane [74-83-9]^
0.14
U
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY QV-01
Carbon disulfide [75-15-0]^
1.5
U
ug/L
1
1.5
5.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Carbon tetrachloride [56-23-5]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Chlorobenzene [108-90-7]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Chloroethane [75-00-3]^
0.23
U
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY QV-01
Chloroform [67-66-3]^
0.18
U
ug/L
1
0.18
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Chloromethane [74-87-3]^
0.13
U
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
cis- 1,2-Dichloroethene [156-59-2]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
cis- 1,3-Dichloropropene [10061-01-5]^
0.20
U
ug/L
1
0.20
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Dibromochloromethane [124-48-1]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Dibromomethane [74-95-3]^
0.27
U
ug/L
1
0.27
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Dichlorodifluoromethane [75-71-8]^
0.20
U
ug/L
1
0.20
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Ethylbenzene [100-41-4]^
0.13
U
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Iodomethane [74-88-4]^
1.7
U
ug/L
1
1.7
5.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Methylene chloride [75-09-2]^
0.23
U
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Styrene [100-42-5]^
0.11
U
ug/L
1
0.11
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Tetrachloroethene [127-18-4]^
0.17
U
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Toluene [108-88-3]^
0.14
U
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
U
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
trans-1,4-Dichloro-2-butene [110-57-6]^
0.70
U
ug/L
1
0.70
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Trichloroethene [79-01-6]^
0.15
U
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Trichlorofluoromethane [75-69-4]^
0.24
U
ug/L
1
0.24
1.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
Vinyl acetate [108-05-4]^
0.95
U
ug/L
1
0.95
5.0
2DO4032
EPA 8260D
04/05/22
00:29
RKY
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 38 Of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-SW5 Lab Sample ID:CF03671-03 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 09:57 Work Order: CF03671
Project: Catawba Co Blackburn Facility - Unit 1 - 3 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte fCAS Numberl Results Flag
Units
DF MDL P L Batch Method Analyzed By Notes
Vinyl chloride [75-01-4]1 0.32 U
ug/L
1 0.32 1.0 2DO4032 EPA 8260D 04/05/22 00:29 RKY
Xylenes (Total) [1330-20-7]1 0.45 U
ug/L
1 0.45 3.0 2DO4032 EPA 8260D 04/05/22 00:29 RKY
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
ffy
Notes
4-Bromofluorobenzene
53
1
50.0
106 %
53-136
2DO4032
EPA 8260D
04105122 00:29
RKY
Dibromofluoromethane
49
1
50.0
97 %
67-129
2DO4032
EPA 8260D
04105122 00:29
RKY
Toluene-d8
56
1
50.0
11396
59-134
2DO4032
EPA 8260D
04105122 00:29
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte fCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
By
Notes
Antimony[7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29004
EPA 6020B
04/04/22 11:10
JDH
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29002
EPA 6010D
04/01/22 11:14
JDH
Barium [7440-39-3]^
48.3
ug/L
1
1.10
10.0
2C29002
EPA 6010D
04/01/22 11:14
JDH
Beryllium [7440-41-7]^
0.160
U
ug/L
1
0.160
1.00
2C29002
EPA 6010D
04/01/22 11:14
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29002
EPA 6010D
04/01/22 11:14
JDH
Chromium [7440-47-3]^
3.11
J
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:14
JDH
Cobalt[7440-48-4]^
2.15
J
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:14
JDH
Copper[7440-50-8]^
2.05
J
ug/L
1
1.60
10.0
2C29002
EPA 6010D
04/01/22 11:14
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29002
EPA 6010D
04/01/22 11:14
JDH
Nickel[7440-02-0]^
2.20
U
ug/L
1
2.20
10.0
2C29002
EPA 6010D
04/01/22 11:14
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29004
EPA 6020B
04/04/22 11:10
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29002
EPA 6010D
04/01/22 11:14
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29004
EPA 6020B
04/04/22 11:10
JDH
Vanadium [7440-62-2]^
6.28
J
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:14
JDH
Zinc [7440-66-6]^
4.40
U
ug/L
1
4.40
10.0
2C29002
EPA 6010D
04/01/22 11:14
JDH
Classical Chemistry Parameters
^ - ENCO Cary certified analyte [NC 591]
Analyte fCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
Hardness^
27
B
mg/L
1
0.020
0.0
2C29002
SM 2340B-2011
04/01/22 11:14
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte fCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80
2.0
201031
EPA 8260D
03/31/22 14:05
KKW
Surrogates
Results
DF
So/ke Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
"
Notes
Toluene-&
5.0
1
5.00
100 %
75-125
201031
EPA 8260D
0313112214:05
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 39 Of 118

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www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW5 Lab Sample ID:CF03672-01 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 15:52 Work Order: CF03672
Project: Catawba Co Blackburn Facility - Unit 1 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte ICAS Numberl
Results
Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
By
Notes
1,1,1,2-Tetrachloroethane [630-20-6]^
0.17
U
ug/L
1
0.17
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
1,1,1-Trichloroethane [71-55-6]^
0.12
U
ug/L
1
0.12
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
1,1,2,2-Tetrachloroethane [79-34-5]^
0.28
U
ug/L
1
0.28
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
1,1,2-Trichloroethane [79-00-5]^
0.14
U
ug/L
1
0.14
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
1,1-Dichloroethane [75-34-3]A
9.2
ug/L
1
0.13
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
1,1-Dichloroethene [75-35-4]^
0.21
U
ug/L
1
0.21
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
U
ug/L
1
0.23
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
U
ug/L
1
0.48
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
1,2-Dibromoethane [106-93-4]^
0.66
U
ug/L
1
0.66
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
U
ug/L
1
0.19
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
1,2-Dichloroethane [107-06-2]^
0.21
U
ug/L
1
0.21
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
1,2-Dichloropropane [78-87-5]^
0.10
U
ug/L
1
0.10
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
1,4-Dichlorobenzene [306-46-7]A
3.2
ug/L
1
0.19
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
2-Butanone [78-93-3]^
1.3
U
ug/L
1
1.3
5.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
QV-01
2-Hexanone [591-78-6]^
0.88
U
ug/L
1
0.88
5.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
U
ug/L
1
1.1
5.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
QV-01
Acetone[67-64-1]^
10
U
ug/L
1
10
20
2DO1023
EPA 8260D
04/03/22 00:20
RKY
QV-01
Acrylonitrile [107-13-1]^
3.5
U
ug/L
1
3.5
10
2DO1023
EPA 8260D
04/03/22 00:20
RKY
QV-01
Benzene [71-43-2]A
1.8
ug/L
1
0.15
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
Bromochloromethane [74-97-5]^
0.48
U
ug/L
1
0.48
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
Bromodichloromethane [75-27-4]^
0.17
U
ug/L
1
0.17
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
Bromoform [75-25-2]^
0.22
U
ug/L
1
0.22
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
Bromomethane [74-83-9]^
0.14
U
ug/L
1
0.14
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
QV-01
Carbon disulfide [75-15-0]^
1.5
U
ug/L
1
1.5
5.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
Carbon tetrachloride [56-23-5]^
0.17
U
ug/L
1
0.17
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
Chlorobenzene [308-90-7]A
2.1
ug/L
1
0.17
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
Chloroethane [75-00-3]^
0.23
U
ug/L
1
0.23
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
QV-01
Chloroform [67-66-3]^
0.18
U
ug/L
1
0.18
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
Chloromethane [74-87-3]^
0.13
U
ug/L
1
0.13
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
QV-01
cis- 1,2-Dichloroethene [156-59-2]A
12
ug/L
1
0.15
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
cis- 1,3-Dichloropropene [10061-01-5]^
0.20
U
ug/L
1
0.20
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
Dibromochloromethane [124-48-1]^
0.17
U
ug/L
1
0.17
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
Dibromomethane [74-95-3]^
0.27
U
ug/L
1
0.27
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
Dichlorodifluoromethane [75-71-8]A
13
ug/L
1
0.20
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
Ethylbenzene [100-41-4]^
0.13
U
ug/L
1
0.13
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
Iodomethane [74-88-4]^
1.7
U
ug/L
1
1.7
5.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
Methylene chloride [75-09-2]A
1.1
ug/L
1
0.23
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
0-01
Styrene [100-42-5]^
0.11
U
ug/L
1
0.11
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
Tetrachloroethene [127-18-4]A
3.3
ug/L
1
0.17
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
Toluene [108-88-3]^
0.14
U
ug/L
1
0.14
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
U
ug/L
1
0.21
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
U
ug/L
1
0.15
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
trans-1,4-Dichloro-2-butene [110-57-6]^
0.70
U
ug/L
1
0.70
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
Trichloroethene [79-01-6]A
7.6
ug/L
1
0.15
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
Trichlorofluoromethane [75-69-4]^
0.24
U
ug/L
1
0.24
1.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
Vinyl acetate [108-05-4]^
0.95
U
ug/L
1
0.95
5.0
2DO1023
EPA 8260D
04/03/22 00:20
RKY
QV-01
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 40 Of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW5 Lab Sample ID:CF03672-01 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 15:52 Work Order: CF03672
Project: Catawba Co Blackburn Facility - Unit 1 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl Results Flag
Units
DF MDL P L Batch Method Analyzed By Notes
Vinyl chloride [75-01-4]^ 0.32 U
ug/L
1 0.32 1.0 2DO1023 EPA 8260D 04/03/22 00:20 RKY
Xylenes (Total) [1330-20-7]^ 0.45 U
ug/L
1 0.45 3.0 2DO1023 EPA 8260D 04/03/22 00:20 RKY
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
ffy
Notes
4-Bromofluorobenzene
54
1
50.0
108 %
53-136
2DO1023
EPA 8260D
04103122 00:20
RKY
Dibromofluoromethane
46
1
50.0
92 %
67-129
2DO1023
EPA 8260D
04103122 00:20
RKY
Toluene-d8
56
1
50.0
112 %
59-134
2DO1023
EPA 8260D
04103122 00:20
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
By
Notes
Antimony[7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29004
EPA 6020B
04/04/22 11:14
JDH
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29002
EPA 6010D
04/01/22 11:17
JDH
Barium [7440-39-3]^
202
ug/L
1
1.10
10.0
2C29002
EPA 6010D
04/01/22 11:17
JDH
Beryllium [7440-41-7]^
0.160
U
ug/L
1
0.160
1.00
2C29002
EPA 6010D
04/01/22 11:17
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29002
EPA 6010D
04/01/22 11:17
JDH
Chromium [7440-47-3]^
1.40
U
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:17
JDH
Cobalt[7440-48-4]^
3.26
J
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:17
JDH
Copper[7440-50-8]^
1.60
U
ug/L
1
1.60
10.0
2C29002
EPA 6010D
04/01/22 11:17
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29002
EPA 6010D
04/01/22 11:17
JDH
Nickel[7440-02-0]^
2.20
U
ug/L
1
2.20
10.0
2C29002
EPA 6010D
04/01/22 11:17
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29004
EPA 6020B
04/04/22 11:14
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29002
EPA 6010D
04/01/22 11:17
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29004
EPA 6020B
04/04/22 11:14
JDH
Vanadium [7440-62-2]^
1.40
U
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:17
JDH
Zinc [7440-66-6]^
4.40
U
ug/L
1
4.40
10.0
2C29002
EPA 6010D
04/01/22 11:17
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
19
ug/L
1
0.80
2.0
200024
EPA 8260D
03/31/22 01:48
KKW
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
"
Notes
Toluene-&
4.8
1
5.00
95 %
75-125
200024
EPA 8260D
03131122 01:48
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 41 Of 118

0Nk"q09
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW5A Lab Sample ID:CF03672-02 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/22/22 17:50 Work Order: CF03672
Project: Catawba Cc Blackburn Facility - Unit 1 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flan
Units
DF
MDL
I'Q
Batch
Method
Analyzed
By
Notes
1,1,1,2-Tetrachloroethane [630-20-6]^
0.17
U
ug/L
1
0.17
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
1,1,1-Trichloroethane [71-55-6]^
0.12
U
ug/L
1
0.12
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
1,1,2,2-Tetrachloroethane [79-34-5]^
0.28
U
ug/L
1
0.28
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
1,1,2-Trichloroethane [79-00-5]^
0.14
U
ug/L
1
0.14
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
1,1-Dichloroethane [75-34-3]^
6.2
ug/L
1
0.13
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
1,1-Dichloroethene [75-35-4]^
0.21
U
ug/L
1
0.21
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
U
ug/L
1
0.23
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
U
ug/L
1
0.48
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
1,2-Dibromoethane [106-93-4]^
0.66
U
ug/L
1
0.66
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
U
ug/L
1
0.19
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
1,2-Dichloroethane [107-06-2]^
0.21
U
ug/L
1
0.21
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
1,2-Dichloropropane [78-87-5]^
0.10
U
ug/L
1
0.10
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
1,4-Dichlorobenzene [106-46-7]^
2.3
ug/L
1
0.19
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
2-Butanone [78-93-3]^
1.3
U
ug/L
1
1.3
5.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
QV-01
2-Hexanone [591-78-6]^
0.88
U
ug/L
1
0.88
5.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
U
ug/L
1
1.1
5.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
QV-01
Acetone [67-64-1]^
10
U
ug/L
1
10
20
2DO1018
EPA 8260D
04/01/22 23:03
RKY
QV-01
Acrylonitrile [107-13-1]^
3.5
U
ug/L
1
3.5
10
2DO1018
EPA 8260D
04/01/22 23:03
RKY
QV-01
Benzene [71-43-2]^
1.7
ug/L
1
0.15
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
Bromochloromethane [74-97-5]^
0.48
U
ug/L
1
0.48
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
Bromodichloromethane [75-27-4]^
0.17
U
ug/L
1
0.17
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
Bromoform [75-25-2]^
0.22
U
ug/L
1
0.22
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
Bromomethane [74-83-9]^
0.14
U
ug/L
1
0.14
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
QV-01
Carbon disulfide [75-15-0]^
1.5
U
ug/L
1
1.5
5.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
Carbon tetrachloride [56-23-5]^
0.17
U
ug/L
1
0.17
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
Chlorobenzene[108-90-7]^
0.17
U
ug/L
1
0.17
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
Chloroethane [75-00-3]^
0.23
U
ug/L
1
0.23
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
QV-01
Chloroform [67-66-3]^
0.18
U
ug/L
1
0.18
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
Chloromethane [74-87-3]^
0.13
U
ug/L
1
0.13
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
cis-1,2-Dichloroethene [156-59-2]^
36
ug/L
1
0.15
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
cis-1,3-Dichloropropene [10061-01-5]^
0.20
U
ug/L
1
0.20
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
Dibromochloromethane [124-48-1]^
0.17
U
ug/L
1
0.17
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
Dibromomethane [74-95-3]^
0.27
U
ug/L
1
0.27
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
Dichlorodifluoromethane [75-71-8]^
0.20
U
ug/L
1
0.20
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
Ethylbenzene [100-41-4]^
0.13
U
ug/L
1
0.13
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
Iodomethane [74-88-4]^
1.7
U
ug/L
1
1.7
5.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
Methylene chloride [75-09-2]^
1.1
ug/L
1
0.23
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
0-01
Styrene [100-42-5]^
0.11
U
ug/L
1
0.11
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
Tetrachloroethene [127-18-4]^
6.1
ug/L
1
0.17
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
Toluene [108-88-3]^
0.14
U
ug/L
1
0.14
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
U
ug/L
1
0.21
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
U
ug/L
1
0.15
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
trans-1,4-Dichloro-2-butene [110-57-6]^
0.70
U
ug/L
1
0.70
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
Trichloroethene [79-01-6]^
12
ug/L
1
0.15
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
Trichlorofluoromethane [75-69-4]^
0.24
U
ug/L
1
0.24
1.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
Vinyl acetate [108-05-4]^
0.95
U
ug/L
1
0.95
5.0
2DO1018
EPA 8260D
04/01/22 23:03
RKY
QV-01
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 42 Of 118

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ANALYTICAL RESULTS
Description: 1803-MW5A Lab Sample ID:CF03672-02 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/22/22 17:50 Work Order: CF03672
Project: Catawba Co Blackburn Facility - Unit 1 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl Results Flag
Units
DF MDL P L Batch Method Analyzed By Notes
Vinyl chloride [75-01-4]^ 0.32 U
ug/L
1 0.32 1.0 2DO1018 EPA 8260D 04/01/22 23:03 RKY
Xylenes(Total)[1330-20-7]^ 0.45 U
ug/L
1 0.45 3.0 2DO1018 EPA 8260D 04/01/22 23:03 RKY
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
ffy
Notes
4-Bromofluorobenzene
56
1
50.0
ill %
53-136
2DO1018
EPA 8260D
04101122 23:03
RKY
Dibromofluoromethane
51
1
50.0
103 %
67-129
2DO1018
EPA 8260D
04101122 23:03
RKY
Toluene-d8
57
1
50.0
11496
59-134
2DO1018
EPA 8260D
04101122 23:03
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
By
Notes
Antimony[7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29004
EPA 6020B
04/04/22 11:18
JDH
Arsenic [7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29002
EPA 6010D
04/01/22 11:20
JDH
Barium [7440-39-3]^
224
ug/L
1
1.10
10.0
2C29002
EPA 6010D
04/01/22 11:20
JDH
Beryllium [7440-41-7]^
0.160
U
ug/L
1
0.160
1.00
2C29002
EPA 6010D
04/01/22 11:20
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29002
EPA 6010D
04/01/22 11:20
JDH
Chromium [7440-47-3]^
1.40
U
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:20
JDH
Cobalt [7440-48-4]^
1.40
U
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:20
JDH
Copper[7440-50-8]^
1.60
U
ug/L
1
1.60
10.0
2C29002
EPA 6010D
04/01/22 11:20
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29002
EPA 6010D
04/01/22 11:20
JDH
Nickel[7440-02-0]^
2.20
U
ug/L
1
2.20
10.0
2C29002
EPA 6010D
04/01/22 11:20
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29004
EPA 6020B
04/04/22 11:18
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29002
EPA 6010D
04/01/22 11:20
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29004
EPA 6020B
04/04/22 11:18
JDH
Vanadium [7440-62-2]^
6.04
J
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:20
JDH
Zinc [7440-66-6]^
4.40
U
ug/L
1
4.40
10.0
2C29002
EPA 6010D
04/01/22 11:20
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80
2.0
200024
EPA 8260D
03/31/22 02:13
KKW
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
"
Notes
Toluene-&
4.7
1
5.00
94 %
75-125
200024
EPA 8260D
03131122 02:13
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 43 Of 118

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www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW6 Lab Sample ID:CF03672-03 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 17:25 Work Order: CF03672
Project: Catawba Co Blackburn Facility - Unit 1 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte ICAS Numberl
Results
Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
By
Notes
1,1,1,2-Tetrachloroethane [630-20-6]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
1,1,1-Trichloroethane [71-55-6]^
0.12
U
ug/L
1
0.12
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
1,1,2,2-Tetrachloroethane [79-34-5]^
0.28
U
ug/L
1
0.28
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
1,1,2-Trichloroethane [79-00-5]^
0.14
U
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
1,1-Dichloroethane [75-34-3]A
12
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
1,1-Dichloroethene [75-35-4]^
0.21
U
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
U
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
U
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
1,2-Dibromoethane [106-93-4]^
0.66
U
ug/L
1
0.66
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
1,2-Dichlorobenzene [95-50-1]A
0.55
1
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
1,2-Dichloroethane [107-06-2]^
0.21
U
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
1,2-Dichloropropane [78-87-5]^
0.10
U
ug/L
1
0.10
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
1,4-Dichlorobenzene [306-46-7]A
10
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
2-Butanone [78-93-3]^
1.3
U
ug/L
1
1.3
5.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
2-Hexanone [591-78-6]^
0.88
U
ug/L
1
0.88
5.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
U
ug/L
1
1.1
5.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Acetone [67-64-1]^
10
U
ug/L
1
10
20
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Acrylonitrile [107-13-1]^
3.5
U
ug/L
1
3.5
10
2DO1019
EPA 8260D
04/02/22 10:29
RKY
QV-01
Benzene [71-43-2]A
4.0
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Bromochloromethane [74-97-5]^
0.48
U
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Bromodichloromethane [75-27-4]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Bromoform [75-25-2]^
0.22
U
ug/L
1
0.22
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Bromomethane [74-83-9]^
0.14
U
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
QV-01
Carbon disulfide [75-15-0]^
1.5
U
ug/L
1
1.5
5.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Carbon tetrachloride [56-23-5]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Chlorobenzene [308-90-7]A
4.6
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Chloroethane [75-00-3]^
0.23
U
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
QV-01
Chloroform [67-66-3]^
0.18
U
ug/L
1
0.18
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Chloromethane [74-87-3]^
0.13
U
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
cis- 1,2-Dichloroethene [156-59-2]^
0.15
U
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
cis- 1,3-Dichloropropene [10061-01-5]^
0.20
U
ug/L
1
0.20
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Dibromochloromethane [124-48-1]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Dibromomethane [74-95-3]^
0.27
U
ug/L
1
0.27
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Dichlorodifluoromethane [75-71-8]A
3.8
ug/L
1
0.20
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Ethylbenzene [100-41-4]^
0.13
U
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Iodomethane [74-88-4]^
1.7
U
ug/L
1
1.7
5.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Methylene chloride [75-09-2]^
0.23
U
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Styrene [100-42-5]^
0.11
U
ug/L
1
0.11
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Tetrachloroethene [127-18-4]A
2.2
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Toluene [108-88-3]^
0.14
U
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
U
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
U
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
trans-1,4-Dichloro-2-butene [110-57-6]^
0.70
U
ug/L
1
0.70
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Trichloroethene [79-01-6]A
3.3
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Trichlorofluoromethane [75-69-4]A
9.2
ug/L
1
0.24
1.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
Vinyl acetate [108-05-4]^
0.95
U
ug/L
1
0.95
5.0
2DO1019
EPA 8260D
04/02/22 10:29
RKY
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 44 Of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW6 Lab Sample ID:CF03672-03 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 17:25 Work Order: CF03672
Project: Catawba Co Blackburn Facility - Unit 1 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes
Vinyl chloride [75-01-4]^ 2.7 ug/L 1 0.32 1.0 2DO1019 EPA 8260D 04/02/22 10:29 RKY
Xylenes(Total)[1330-20-7]^ 0.72 J ug/L 1 0.45 3.0 2DO1019 EPA 8260D 04/02/22 10:29 RKY
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
ffy
Notes
4-Bromofluorobenzene
57
1
50.0
114 %
53-136
2DO1019
EPA 8260D
04102122 10:29
RKY
Dibromofluoromethane
50
1
50.0
100 %
67-129
2DO1019
EPA 8260D
0410212210:29
RKY
Toluene-d8
56
1
50.0
113 %
59-134
2DO1019
EPA 8260D
0410212210:29
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
By
Notes
Antimony[7440-36-0]^
0.740
u
ug/L
2
0.740
2.00
2C29004
EPA 6020B
04/04/22 11:23
JDH
Arsenic [7440-38-2]^
7.60
u
ug/L
1
7.60
10.0
2C29002
EPA 6010D
04/01/22 11:22
JDH
Barium [7440-39-3]^
328
ug/L
1
1.10
10.0
2C29002
EPA 6010D
04/01/22 11:22
JDH
Beryllium [7440-41-7]^
0.160
u
ug/L
1
0.160
1.00
2C29002
EPA 6010D
04/01/22 11:22
JDH
Cadmium [7440-43-9]^
0.360
u
ug/L
1
0.360
1.00
2C29002
EPA 6010D
04/01/22 11:22
JDH
Chromium [7440-47-3]^
11.5
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:22
JDH
Cobalt[7440-48-4]^
116
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:22
JDH
Copper[7440-50-8]^
1.60
u
ug/L
1
1.60
10.0
2C29002
EPA 6010D
04/01/22 11:22
JDH
Lead [7439-92-1]^
3.10
u
ug/L
1
3.10
10.0
2C29002
EPA 6010D
04/01/22 11:22
JDH
Nickel[7440-02-0]^
11.5
ug/L
1
2.20
10.0
2C29002
EPA 6010D
04/01/22 11:22
JDH
Selenium [7782-49-2]^
1.82
u
ug/L
2
1.82
2.00
2C29004
EPA 6020B
04/04/22 11:23
JDH
Silver [7440-22-4]^
1.90
u
ug/L
1
1.90
10.0
2C29002
EPA 6010D
04/01/22 11:22
JDH
Thallium [7440-28-0]^
0.220
u
ug/L
2
0.220
2.00
2C29004
EPA 6020B
04/04/22 11:23
JDH
Vanadium [7440-62-2]^
1.40
u
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:22
JDH
Zinc[7440-66-6]^
4.86
J
ug/L
1
4.40
10.0
2C29002
EPA 6010D
04/01/22 11:22
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
100
D
ug/L
5
4.0
10
201031
EPA 8260D
03/31/22 12:48
KKW
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
"
Notes
Toluene-&
5.0
1
5.00
100 %
75-125
201031
EPA 8260D
0313112212:48
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 45 Of 118

0Nk"q09
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW6D Lab Sample ID:CF03672-04 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 17:50 Work Order: CF03672
Project: Catawba Cc Blackburn Facility - Unit 1 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flan
Units
DF
MDL
I'Q
Batch
Method
Analyzed
By
Notes
1,1,1,2-Tetrachloroethane [630-20-6]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
1,1,1-Trichloroethane [71-55-6]^
0.12
U
ug/L
1
0.12
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
1,1,2,2-Tetrachloroethane [79-34-5]^
0.28
U
ug/L
1
0.28
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
1,1,2-Trichloroethane [79-00-5]^
0.14
U
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
1,1-Dichloroethane [75-34-3]^
2.2
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
1,1-Dichloroethene [75-35-4]^
0.21
U
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
U
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
U
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
1,2-Dibromoethane [106-93-4]^
0.66
U
ug/L
1
0.66
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
U
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
1,2-Dichloroethane [107-06-2]^
0.21
U
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
1,2-Dichloropropane [78-87-5]^
0.10
U
ug/L
1
0.10
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
1,4-Dichlorobenzene [106-46-7]^
0.19
U
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
2-Butanone [78-93-3]^
1.3
U
ug/L
1
1.3
5.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
2-Hexanone [591-78-6]^
0.88
U
ug/L
1
0.88
5.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
u
ug/L
1
1.1
5.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
Acetone [67-64-1]^
10
u
ug/L
1
10
20
2DO1019
EPA 8260D
04/02/22 10:56
RKY
Acrylonitrile [107-13-1]^
3.5
u
ug/L
1
3.5
10
2DO1019
EPA 8260D
04/02/22 10:56
RKY
QV-01
Benzene [71-43-2]^
0.15
u
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
Bromochloromethane [74-97-5]^
0.48
u
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
Bromodichloromethane [75-27-4]^
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
Bromoform [75-25-2]^
0.22
u
ug/L
1
0.22
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
Bromomethane [74-83-9]^
0.14
u
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
QV-01
Carbon disulfide [75-15-0]^
1.5
U
ug/L
1
1.5
5.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
Carbon tetrachloride [56-23-5]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
Chlorobenzene [108-90-7]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
Chloroethane [75-00-3]^
0.23
U
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
QV-01
Chloroform [67-66-3]^
0.18
U
ug/L
1
0.18
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
Chloromethane [74-87-3]^
0.13
U
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
cis-1,2-Dichloroethene [156-59-2]^
0.15
U
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
cis-1,3-Dichloropropene [10061-01-5]^
0.20
U
ug/L
1
0.20
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
Dibromochloromethane [124-48-1]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
Dibromomethane [74-95-3]^
0.27
U
ug/L
1
0.27
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
Dichlorodifluoromethane [75-71-8]^
0.20
U
ug/L
1
0.20
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
Ethylbenzene [100-41-4]^
0.13
U
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
Iodomethane [74-88-4]^
1.7
U
ug/L
1
1.7
5.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
Methylene chloride [75-09-2]^
0.88
J
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
0-01
Styrene [100-42-5]^
0.11
U
ug/L
1
0.11
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
Tetrachloroethene [127-18-4]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
Toluene [108-88-3]^
0.14
U
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
U
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
U
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
trans-1,4-Dichloro-2-butene [110-57-6]^
0.70
U
ug/L
1
0.70
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
Trichloroethene [79-01-6]^
0.15
U
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
Trichlorofluoromethane [75-69-4]^
0.24
U
ug/L
1
0.24
1.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
Vinyl acetate [108-05-4]^
0.95
U
ug/L
1
0.95
5.0
2DO1019
EPA 8260D
04/02/22 10:56
RKY
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 46 Of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW6D Lab Sample ID:CF03672-04 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 17:50 Work Order: CF03672
Project: Catawba Co Blackburn Facility - Unit 1 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl Results Flag
Units
DF MDL P L Batch Method Analyzed By Notes
Vinyl chloride [75-01-4]^ 0.32 U
ug/L
1 0.32 1.0 2DO1019 EPA 8260D 04/02/22 10:56 RKY
Xylenes(Total)[1330-20-7]^ 0.45 U
ug/L
1 0.45 3.0 2DO1019 EPA 8260D 04/02/22 10:56 RKY
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
ffy
Notes
4-Bromofluorobenzene
52
1
50.0
104 %
53-136
2DO1019
EPA 8260D
04102122 10:56
RKY
Dibromofluoromethane
47
1
50.0
94 %
67-129
2DO1019
EPA 8260D
0410212210:56
RKY
Toluene-d8
55
1
50.0
110 %
59-134
2DO1019
EPA 8260D
0410212210:56
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
By
Notes
Antimony[7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29004
EPA 6020B
04/04/22 11:27
JDH
Arsenic [7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29002
EPA 6010D
04/01/22 11:25
JDH
Barium [7440-39-3]^
118
ug/L
1
1.10
10.0
2C29002
EPA 6010D
04/01/22 11:25
JDH
Beryllium [7440-41-7]^
0.160
U
ug/L
1
0.160
1.00
2C29002
EPA 6010D
04/01/22 11:25
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29002
EPA 6010D
04/01/22 11:25
JDH
Chromium [7440-47-3]^
1.40
U
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:25
JDH
Cobalt [7440-48-4]^
1.40
U
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:25
JDH
Copper[7440-50-8]^
1.60
U
ug/L
1
1.60
10.0
2C29002
EPA 6010D
04/01/22 11:25
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29002
EPA 6010D
04/01/22 11:25
JDH
Nickel[7440-02-0]^
2.20
U
ug/L
1
2.20
10.0
2C29002
EPA 6010D
04/01/22 11:25
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29004
EPA 6020B
04/04/22 11:27
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29002
EPA 6010D
04/01/22 11:25
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29004
EPA 6020B
04/04/22 11:27
JDH
Vanadium [7440-62-2]^
7.13
J
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:25
JDH
Zinc [7440-66-6]^
4.40
U
ug/L
1
4.40
10.0
2C29002
EPA 6010D
04/01/22 11:25
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
5.0
ug/L
1
0.80
2.0
200024
EPA 8260D
03/31/22 03:05
KKW
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
"
Notes
Toluene-&
5.0
1
5.00
99 %
75-125
200024
EPA 8260D
03131122 03:05
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 47 Of 118

0Nk"q09
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW7 Lab Sample ID:CF03672-05 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 15:42 Work Order: CF03672
Project: Catawba Cc Blackburn Facility - Unit 1 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flan
Units
DF
MDL
I'Q
Batch
Method
Analyzed
By
Notes
1,1,1,2-Tetrachloroethane [630-20-6]A
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
1,1,1-Trichloroethane [71-55-6]A
0.12
U
ug/L
1
0.12
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
1,1,2,2-Tetrachloroethane [79-34-5]A
0.28
U
ug/L
1
0.28
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
1,1,2-Trichloroethane [79-00-5]A
0.14
U
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
1,1-Dichloroethane [75-34-3]A
0.13
U
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
1,1-Dichloroethene [75-35-4]A
0.21
U
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
1,2,3-Trichloropropane [96-18-4]A
0.23
U
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
1,2-Dibromo-3-chloropropane [96-12-8]A
0.48
U
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
1,2-Dibromoethane [106-93-4]A
0.66
U
ug/L
1
0.66
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
1,2-Dichlorobenzene [95-50-1]A
0.19
U
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
1,2-Dichloroethane [107-06-2]A
0.21
U
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
1,2-Dichloropropane [78-87-5]A
0.10
U
ug/L
1
0.10
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
1,4-Dichlorobenzene [106-46-7]A
7.6
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
2-Butanone [78-93-3]A
1.3
U
ug/L
1
1.3
5.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
2-Hexanone [591-78-6]A
0.88
U
ug/L
1
0.88
5.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
4-Methyl-2-pentanone [108-10-1]A
1.1
u
ug/L
1
1.1
5.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Acetone [67-64-1]A
10
u
ug/L
1
10
20
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Acrylonitrile [107-13-1]A
3.5
u
ug/L
1
3.5
10
2DO1019
EPA 8260D
04/02/22 11:24
RKY
QV-01
Benzene [71-43-2]A
2.8
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Bromochloromethane [74-97-5]A
0.48
u
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Bromodichloromethane [75-27-4]A
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Bromoform [75-25-2]A
0.22
u
ug/L
1
0.22
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Bromomethane [74-83-9]A
0.14
u
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
QV-01
Carbon disulfide [75-15-0]A
1.5
U
ug/L
1
1.5
5.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Carbon tetrachloride [56-23-5]A
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Chlorobenzene [108-90-7]A
2.9
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Chloroethane [75-00-3]A
0.23
U
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
QV-01
Chloroform [67-66-3]A
0.18
U
ug/L
1
0.18
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Chloromethane [74-87-3]A
0.13
U
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
cis-1,2-Dichloroethene [156-59-2]A
0.95
J
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
cis-1,3-Dichloropropene [10061-01-5]A
0.20
U
ug/L
1
0.20
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Dibromochloromethane [124-48-1]A
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Dibromomethane [74-95-3]A
0.27
U
ug/L
1
0.27
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Dichlorodifluoromethane [75-71-8]A
0.20
U
ug/L
1
0.20
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Ethylbenzene [100-41-4]A
0.13
U
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Iodomethane [74-88-4]A
1.7
U
ug/L
1
1.7
5.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Methylene chloride [75-09-2]A
0.23
U
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Styrene [100-42-5]A
0.11
U
ug/L
1
0.11
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Tetrachloroethene [127-18-4]A
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Toluene [108-88-3]A
0.14
U
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
trans-1,2-Dichloroethene [156-60-5]A
0.21
U
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
trans-1,3-Dichloropropene [10061-02-6]A
0.15
U
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
trans-1,4-Dichloro-2-butene [110-57-6]A
0.70
U
ug/L
1
0.70
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Trichloroethene [79-01-6]A
0.15
U
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Trichlorofluoromethane [75-69-4]A
0.24
U
ug/L
1
0.24
1.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
Vinyl acetate [108-05-4]A
0.95
U
ug/L
1
0.95
5.0
2DO1019
EPA 8260D
04/02/22 11:24
RKY
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 48 Of 118

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ANALYTICAL RESULTS
Description: 1803-MW7 Lab Sample ID:CF03672-05 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 15:42 Work Order: CF03672
Project: Catawba Co Blackburn Facility - Unit 1 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl Results Flag
Units
DF MDL P L Batch Method Analyzed By Notes
Vinyl chloride [75-01-4]^ 0.32 U
ug/L
1 0.32 1.0 2DO1019 EPA 8260D 04/02/22 11:24 RKY
Xylenes(Total)[1330-20-7]^ 0.45 U
ug/L
1 0.45 3.0 2DO1019 EPA 8260D 04/02/22 11:24 RKY
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
ffy
Notes
4-Bromofluorobenzene
53
1
50.0
107 %
53-136
2DO1019
EPA 8260D
04102122 11:24
RKY
Dibromofluoromethane
48
1
50.0
95 %
67-129
2DO1019
EPA 8260D
0410212211:24
RKY
Toluene-d8
55
1
50.0
ill %
59-134
2DO1019
EPA 8260D
0410212211:24
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
By
Notes
Antimony[7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29004
EPA 6020B
04/04/22 11:31
JDH
Arsenic [7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29002
EPA 6010D
04/01/22 11:27
JDH
Barium [7440-39-3]^
262
ug/L
1
1.10
10.0
2C29002
EPA 6010D
04/01/22 11:27
JDH
Beryllium [7440-41-7]^
0.160
U
ug/L
1
0.160
1.00
2C29002
EPA 6010D
04/01/22 11:27
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29002
EPA 6010D
04/01/22 11:27
JDH
Chromium [7440-47-3]^
4.88
J
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:27
JDH
Cobalt[7440-48-4]^
31.8
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:27
JDH
Copper[7440-50-8]^
1.60
U
ug/L
1
1.60
10.0
2C29002
EPA 6010D
04/01/22 11:27
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29002
EPA 6010D
04/01/22 11:27
JDH
Nickel[7440-02-0]^
8.41
J
ug/L
1
2.20
10.0
2C29002
EPA 6010D
04/01/22 11:27
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29004
EPA 6020B
04/04/22 11:31
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29002
EPA 6010D
04/01/22 11:27
JDH
Thallium [7440-28-0]^
0.645
J
ug/L
2
0.220
2.00
2C29004
EPA 6020B
04/04/22 11:31
JDH
Vanadium [7440-62-2]^
1.40
U
ug/L
1
1.40
10.0
2C29002
EPA 6010D
04/01/22 11:27
JDH
Zinc[7440-66-6]^
4.86
J
ug/L
1
4.40
10.0
2C29002
EPA 6010D
04/01/22 11:27
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.85
J
ug/L
1
0.80
2.0
200024
EPA 8260D
03/31/22 03:31
KKW
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
"
Notes
Toluene-&
4.7
1
5.00
93 %
75-125
200024
EPA 8260D
03131122 0331
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 49 Of 118

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ANALYTICAL RESULTS
Description: 1803-MWll Lab Sample ID:CF03672-06 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/22/22 16:19 Work Order: CF03672
Project: Catawba Cc Blackburn Facility - Unit 1 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flan
Units
DF
MDL
I'Q
Batch
Method
Analyzed
By
Notes
1,1,1,2-Tetrachloroethane [630-20-6]A
0.17
U
ug/L
1
0.17
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
1,1,1-Trichloroethane [71-55-6]A
0.12
U
ug/L
1
0.12
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
1,1,2,2-Tetrachloroethane [79-34-5]A
0.28
U
ug/L
1
0.28
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
1,1,2-Trichloroethane [79-00-5]A
0.14
U
ug/L
1
0.14
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
1,1-Dichloroethane [75-34-3]A
0.13
U
ug/L
1
0.13
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
1,1-Dichloroethene [75-35-4]A
0.21
U
ug/L
1
0.21
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
1,2,3-Trichloropropane [96-18-4]A
0.23
U
ug/L
1
0.23
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
1,2-Dibromo-3-chloropropane [96-12-8]A
0.48
U
ug/L
1
0.48
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
1,2-Dibromoethane [106-93-4]A
0.66
U
ug/L
1
0.66
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
1,2-Dichlorobenzene [95-50-1]A
0.19
U
ug/L
1
0.19
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
1,2-Dichloroethane [107-06-2]A
0.21
U
ug/L
1
0.21
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
1,2-Dichloropropane [78-87-5]A
0.10
U
ug/L
1
0.10
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
1,4-Dichlorobenzene [106-46-7]A
5.1
ug/L
1
0.19
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
2-Butanone [78-93-3]A
1.3
U
ug/L
1
1.3
5.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
QV-01
2-Hexanone [591-78-6]A
0.88
U
ug/L
1
0.88
5.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
4-Methyl-2-pentanone [108-10-1]A
1.1
U
ug/L
1
1.1
5.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
QV-01
Acetone [67-64-1]A
10
U
ug/L
1
10
20
2DO1018
EPA 8260D
04/01/22 23:31
RKY
QV-01
Acrylonitrile [107-13-1]A
3.5
U
ug/L
1
3.5
10
2DO1018
EPA 8260D
04/01/22 23:31
RKY
QV-01
Benzene [71-43-2]A
7.1
ug/L
1
0.15
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
Bromochloromethane [74-97-5]A
0.48
U
ug/L
1
0.48
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
Bromodichloromethane [75-27-4]A
0.17
U
ug/L
1
0.17
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
Bromoform [75-25-2]A
0.22
U
ug/L
1
0.22
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
Bromomethane [74-83-9]A
0.14
U
ug/L
1
0.14
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
QV-01
Carbon disulfide [75-15-0]A
1.5
U
ug/L
1
1.5
5.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
Carbon tetrachloride [56-23-5]A
0.17
U
ug/L
1
0.17
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
Chlorobenzene [108-90-7]A
8.2
ug/L
1
0.17
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
Chloroethane [75-00-3]A
0.23
U
ug/L
1
0.23
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
QV-01
Chloroform [67-66-3]A
0.18
U
ug/L
1
0.18
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
Chloromethane [74-87-3]A
0.13
U
ug/L
1
0.13
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
cis-1,2-Dichloroethene [156-59-2]A
2.1
ug/L
1
0.15
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
cis-1,3-Dichloropropene [10061-01-5]A
0.20
U
ug/L
1
0.20
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
Dibromochloromethane [124-48-1]A
0.17
U
ug/L
1
0.17
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
Dibromomethane [74-95-3]A
0.27
U
ug/L
1
0.27
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
Dichlorodifluoromethane [75-71-8]A
0.20
U
ug/L
1
0.20
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
Ethylbenzene [100-41-4]A
0.13
U
ug/L
1
0.13
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
Iodomethane [74-88-4]A
1.7
U
ug/L
1
1.7
5.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
Methylene chloride [75-09-2]A
0.23
U
ug/L
1
0.23
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
Styrene [100-42-5]A
0.11
U
ug/L
1
0.11
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
Tetrachloroethene [127-18-4]A
0.17
U
ug/L
1
0.17
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
Toluene [108-88-3]A
0.14
U
ug/L
1
0.14
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
trans-1,2-Dichloroethene [156-60-5]A
0.21
U
ug/L
1
0.21
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
trans-1,3-Dichloropropene [10061-02-6]A
0.15
U
ug/L
1
0.15
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
trans-1,4-Dichloro-2-butene [110-57-6]A
0.70
U
ug/L
1
0.70
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
Trichloroethene [79-01-6]A
0.15
U
ug/L
1
0.15
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
Trichlorofluoromethane [75-69-4]A
0.24
U
ug/L
1
0.24
1.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
Vinyl acetate [108-05-4]A
0.95
U
ug/L
1
0.95
5.0
2DO1018
EPA 8260D
04/01/22 23:31
RKY
QV-01
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 50 Of 118

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ANALYTICAL RESULTS
Description: 1803-MWll Lab Sample ID:CF03672-06 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/22/22 16:19 Work Order: CF03672
Project: Catawba Co Blackburn Facility - Unit 1 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl Results Flag
Units
DF MDL P L Batch Method Analyzed By Notes
Vinyl chloride [75-01-4]^ 0.32 U
ug/L
1 0.32 1.0 2DO1018 EPA 8260D 04/01/22 23:31 RKY
Xylenes(Total)[1330-20-7]^ 0.45 U
ug/L
1 0.45 3.0 2DO1018 EPA 8260D 04/01/22 23:31 RKY
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
ffy
Notes
4-Bromofluorobenzene
56
1
50.0
ill %
53-136
2DO1018
EPA 8260D
04101122 23:31
RKY
Dibromofluoromethane
47
1
50.0
95 %
67-129
2DO1018
EPA 8260D
04101122 23:31
RKY
Toluene-d8
56
1
50.0
113 %
59-134
2DO1018
EPA 8260D
04101122 2331
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
By
Notes
Antimony[7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29004
EPA 6020B
04/04/22 11:35
JDH
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29003
EPA 6010D
04/01/22 13:01
JDH
Barium [7440-39-3]^
224
ug/L
1
1.10
10.0
2C29003
EPA 6010D
04/01/22 13:01
JDH
Beryllium [7440-41-7]^
0.160
U
ug/L
1
0.160
1.00
2C29003
EPA 6010D
04/01/22 13:01
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29003
EPA 6010D
04/01/22 13:01
JDH
Chromium [7440-47-3]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:01
JDH
Cobalt[7440-48-4]^
64.6
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:01
JDH
Copper[7440-50-8]^
1.60
U
ug/L
1
1.60
10.0
2C29003
EPA 6010D
04/01/22 13:01
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29003
EPA 6010D
04/01/22 13:01
JDH
Nickel[7440-02-0]^
4.50
J
ug/L
1
2.20
10.0
2C29003
EPA 6010D
04/01/22 13:01
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29004
EPA 6020B
04/04/22 11:35
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29003
EPA 6010D
04/01/22 13:01
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29004
EPA 6020B
04/04/22 11:35
JDH
Vanadium [7440-62-2]^
3.10
J
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:01
JDH
Zinc[7440-66-6]^
7.50
J
ug/L
1
4.40
10.0
2C29003
EPA 6010D
04/01/22 13:01
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80
2.0
200024
EPA 8260D
03/31/22 03:57
KKW
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
"
Notes
Toluene-&
4.7
1
5.00
94 %
75-125
200024
EPA 8260D
03131122 03:57
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 51 Of 118

0Nk"q09
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW20 Lab Sample ID:CF03672-07 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 16:04 Work Order: CF03672
Project: Catawba Cc Blackburn Facility - Unit 1 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flan
Units
DF
MDL
I'Q
Batch
Method
Analyzed
By
Notes
1,1,1,2-Tetrachloroethane [630-20-6]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
1,1,1-Trichloroethane [71-55-6]^
0.12
U
ug/L
1
0.12
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
1,1,2,2-Tetrachloroethane [79-34-5]^
0.28
U
ug/L
1
0.28
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
1,1,2-Trichloroethane [79-00-5]^
0.14
U
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
1,1-Dichloroethane [75-34-3]^
0.13
U
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
1,1-Dichloroethene [75-35-4]^
0.21
U
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
U
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
U
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
1,2-Dibromoethane [106-93-4]^
0.66
U
ug/L
1
0.66
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
U
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
1,2-Dichloroethane [107-06-2]^
0.21
U
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
1,2-Dichloropropane [78-87-5]^
0.10
U
ug/L
1
0.10
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
1,4-Dichlorobenzene [106-46-7]^
0.19
U
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
2-Butanone [78-93-3]^
1.3
U
ug/L
1
1.3
5.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
2-Hexanone [591-78-6]^
0.88
U
ug/L
1
0.88
5.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
u
ug/L
1
1.1
5.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Acetone [67-64-1]^
10
u
ug/L
1
10
20
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Acrylonitrile [107-13-1]^
3.5
u
ug/L
1
3.5
10
2DO1019
EPA 8260D
04/02/22 11:51
RKY
QV-01
Benzene[71-43-2]^
0.15
u
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Bromochloromethane [74-97-5]^
0.48
u
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Bromodichloromethane [75-27-4]^
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Bromoform [75-25-2]^
0.22
u
ug/L
1
0.22
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Bromomethane [74-83-9]^
0.14
u
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
QV-01
Carbon disulfide [75-15-0]^
1.5
U
ug/L
1
1.5
5.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Carbon tetrachloride [56-23-5]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Chlorobenzene[108-90-7]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Chloroethane [75-00-3]^
0.23
U
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
QV-01
Chloroform [67-66-3]^
0.18
U
ug/L
1
0.18
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Chloromethane [74-87-3]^
0.13
U
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
cis-1,2-Dichloroethene [156-59-2]^
0.15
U
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
cis-1,3-Dichloropropene [10061-01-5]^
0.20
U
ug/L
1
0.20
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Dibromochloromethane [124-48-1]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Dibromomethane [74-95-3]^
0.27
U
ug/L
1
0.27
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Dichlorodifluoromethane [75-71-8]^
0.20
U
ug/L
1
0.20
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Ethylbenzene [100-41-4]^
0.13
U
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Iodomethane [74-88-4]^
1.7
U
ug/L
1
1.7
5.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Methylene chloride [75-09-2]^
0.23
U
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Styrene [100-42-5]^
0.11
U
ug/L
1
0.11
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Tetrachloroethene [127-18-4]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Toluene [108-88-3]^
0.14
U
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
U
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
U
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
trans-1,4-Dichloro-2-butene [110-57-6]^
0.70
U
ug/L
1
0.70
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Trichloroethene [79-01-6]^
0.15
U
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Trichlorofluoromethane [75-69-4]^
0.24
U
ug/L
1
0.24
1.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
Vinyl acetate [108-05-4]^
0.95
U
ug/L
1
0.95
5.0
2DO1019
EPA 8260D
04/02/22 11:51
RKY
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 52 Of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW20 Lab Sample ID:CF03672-07 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 16:04 Work Order: CF03672
Project: Catawba Co Blackburn Facility - Unit 1 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl Results Flag
Units
DF MDL P L Batch Method Analyzed By Notes
Vinyl chloride [75-01-4]^ 0.32 U
ug/L
1 0.32 1.0 2DO1019 EPA 8260D 04/02/22 11:51 RKY
Xylenes(Total)[1330-20-7]^ 0.45 U
ug/L
1 0.45 3.0 2DO1019 EPA 8260D 04/02/22 11:51 RKY
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
ffy
Notes
4-Bromofluorobenzene
53
1
50.0
107 %
53-136
2DO1019
EPA 8260D
04102122 11:51
RKY
Dibromofluoromethane
47
1
50.0
93 %
67-129
2DO1019
EPA 8260D
0410212211:51
RKY
Toluene-d8
55
1
50.0
110 %
59-134
2DO1019
EPA 8260D
0410212211:51
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
By
Notes
Antimony[7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29004
EPA 6020B
04/04/22 11:40
JDH
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29003
EPA 6010D
04/01/22 13:11
JDH
Barium [7440-39-3]^
47.8
ug/L
1
1.10
10.0
2C29003
EPA 6010D
04/01/22 13:11
JDH
Beryllium [7440-41-7]^
0.160
U
ug/L
1
0.160
1.00
2C29003
EPA 6010D
04/01/22 13:11
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29003
EPA 6010D
04/01/22 13:11
JDH
Chromium [7440-47-3]^
2.04
J
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:11
JDH
Cobalt[7440-48-4]^
2.16
J
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:11
JDH
Copper[7440-50-8]^
3.68
J
ug/L
1
1.60
10.0
2C29003
EPA 6010D
04/01/22 13:11
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29003
EPA 6010D
04/01/22 13:11
JDH
Nickel[7440-02-0]^
2.20
U
ug/L
1
2.20
10.0
2C29003
EPA 6010D
04/01/22 13:11
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29004
EPA 6020B
04/04/22 11:40
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29003
EPA 6010D
04/01/22 13:11
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29004
EPA 6020B
04/04/22 11:40
JDH
Vanadium [7440-62-2]^
1.82
J
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:11
JDH
Zinc[7440-66-6]^
7.86
J
ug/L
1
4.40
10.0
2C29003
EPA 6010D
04/01/22 13:11
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80
2.0
200024
EPA 8260D
03/31/22 04:22
KKW
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
"
Notes
Toluene-&
5.0
1
5.00
100 %
75-125
200024
EPA 8260D
03131122 04:22
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 53 Of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-PZ85B Lab Sample ID:CF03672-08 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 10:17 Work Order: CF03672
Project: Catawba Co Blackburn Facility - Unit 1 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte ICAS Numberl
Results
Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
By
Notes
1,1,1,2-Tetrachloroethane [630-20-6]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
1,1,1-Trichloroethane [71-55-6]^
0.12
U
ug/L
1
0.12
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
1,1,2,2-Tetrachloroethane [79-34-5]^
0.28
U
ug/L
1
0.28
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
1,1,2-Trichloroethane [79-00-5]^
0.14
U
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
1,1-Dichloroethane [75-34-3]A
1.5
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
1,1-Dichloroethene [75-35-4]^
0.21
U
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
U
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
U
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
1,2-Dibromoethane [106-93-4]^
0.66
U
ug/L
1
0.66
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
U
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
1,2-Dichloroethane [107-06-2]^
0.21
U
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
1,2-Dichloropropane [78-87-5]^
0.10
U
ug/L
1
0.10
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
1,4-Dichlorobenzene [106-46-7]^
0.19
U
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
2-Butanone [78-93-3]^
1.3
U
ug/L
1
1.3
5.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
2-Hexanone [591-78-6]^
0.88
U
ug/L
1
0.88
5.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
U
ug/L
1
1.1
5.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Acetone [67-64-1]^
10
U
ug/L
1
10
20
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Acrylonitrile [107-13-1]^
3.5
U
ug/L
1
3.5
10
2DO1019
EPA 8260D
04/02/22 12:19
RKY
QV-01
Benzene [71-43-2]^
0.15
U
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Bromochloromethane [74-97-5]^
0.48
U
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Bromodichloromethane [75-27-4]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Bromoform [75-25-2]^
0.22
U
ug/L
1
0.22
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Bromomethane [74-83-9]^
0.14
U
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
QV-01
Carbon disulfide [75-15-0]^
1.5
U
ug/L
1
1.5
5.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Carbon tetrachloride [56-23-5]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Chlorobenzene [108-90-7]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Chloroethane [75-00-3]^
0.23
U
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
QV-01
Chloroform [67-66-3]^
0.18
U
ug/L
1
0.18
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Chloromethane [74-87-3]^
0.13
U
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
cis- 1,2-Dichloroethene [156-59-2]A
3.2
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
cis- 1,3-Dichloropropene [10061-01-5]^
0.20
U
ug/L
1
0.20
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Dibromochloromethane [124-48-1]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Dibromomethane [74-95-3]^
0.27
U
ug/L
1
0.27
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Dichlorodifluoromethane [75-71-8]^
0.20
U
ug/L
1
0.20
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Ethylbenzene [100-41-4]^
0.13
U
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Iodomethane [74-88-4]^
1.7
U
ug/L
1
1.7
5.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Methylene chloride [75-09-2]^
0.23
U
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Styrene [100-42-5]^
0.11
U
ug/L
1
0.11
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Tetrachloroethene [127-18-4]A
8.9
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Toluene [108-88-3]^
0.14
U
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
U
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
U
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
trans-1,4-Dichloro-2-butene [110-57-6]^
0.70
U
ug/L
1
0.70
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Trichloroethene [79-01-6]A
3.1
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Trichlorofluoromethane [75-69-4]^
0.24
U
ug/L
1
0.24
1.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
Vinyl acetate [108-05-4]^
0.95
U
ug/L
1
0.95
5.0
2DO1019
EPA 8260D
04/02/22 12:19
RKY
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 54 Of 118

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www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-PZ85B Lab Sample ID:CF03672-08 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 10:17 Work Order: CF03672
Project: Catawba Co Blackburn Facility - Unit 1 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl Results Flag
Units
DF MDL P L Batch Method Analyzed By Notes
Vinyl chloride [75-01-4]^ 0.32 U
ug/L
1 0.32 1.0 2DO1019 EPA 8260D 04/02/22 12:19 RKY
Xylenes(Total)[1330-20-7]^ 0.45 U
ug/L
1 0.45 3.0 2DO1019 EPA 8260D 04/02/22 12:19 RKY
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
ffy
Notes
4-Bromofluorobenzene
56
1
50.0
ill %
53-136
2DO1019
EPA 8260D
04102122 12:19
RKY
Dibromofluoromethane
49
1
50.0
97 %
67-129
2DO1019
EPA 8260D
0410212212:19
RKY
Toluene-d8
57
1
50.0
11496
59-134
2DO1019
EPA 8260D
0410212212:19
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
By
Notes
Antimony[7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29004
EPA 6020B
04/04/22 11:44
JDH
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29003
EPA 6010D
04/01/22 13:06
JDH
Barium [7440-39-3]^
79.3
ug/L
1
1.10
10.0
2C29003
EPA 6010D
04/01/22 13:06
JDH
Beryllium [7440-41-7]^
0.160
U
ug/L
1
0.160
1.00
2C29003
EPA 6010D
04/01/22 13:06
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29003
EPA 6010D
04/01/22 13:06
JDH
Chromium [7440-47-3]^
6.36
J
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:06
JDH
Cobalt [7440-48-4]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:06
JDH
Copper[7440-50-8]^
1.60
U
ug/L
1
1.60
10.0
2C29003
EPA 6010D
04/01/22 13:06
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29003
EPA 6010D
04/01/22 13:06
JDH
Nickel[7440-02-0]^
2.20
U
ug/L
1
2.20
10.0
2C29003
EPA 6010D
04/01/22 13:06
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29004
EPA 6020B
04/04/22 11:44
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29003
EPA 6010D
04/01/22 13:06
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29004
EPA 6020B
04/04/22 11:44
JDH
Vanadium [7440-62-2]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:06
JDH
Zinc [7440-66-6]^
4.40
U
ug/L
1
4.40
10.0
2C29003
EPA 6010D
04/01/22 13:06
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80
2.0
200024
EPA 8260D
03/31/22 04:48
KKW
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
"
Notes
Toluene-&
5.0
1
5.00
100 %
75-125
200024
EPA 8260D
03131122 04:48
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page FJJ Of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-PZ86B Lab Sample ID:CF03672-09 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 10:40 Work Order: CF03672
Project: Catawba Co Blackburn Facility - Unit 1 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte ICAS Numberl
Results
Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
By
Notes
1,1,1,2-Tetrachloroethane [630-20-6]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
1,1,1-Trichloroethane [71-55-6]^
0.12
U
ug/L
1
0.12
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
1,1,2,2-Tetrachloroethane [79-34-5]^
0.28
U
ug/L
1
0.28
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
1,1,2-Trichloroethane [79-00-5]^
0.14
U
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
1,1-Dichloroethane [75-34-3]A
16
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
1,1-Dichloroethene [75-35-4]^
0.21
U
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
U
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
U
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
1,2-Dibromoethane [106-93-4]^
0.66
U
ug/L
1
0.66
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
U
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
1,2-Dichloroethane [107-06-2]^
0.21
U
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
1,2-Dichloropropane [78-87-5]A
4.6
ug/L
1
0.10
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
1,4-Dichlorobenzene [306-46-7]A
3.3
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
2-Butanone [78-93-3]^
1.3
U
ug/L
1
1.3
5.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
2-Hexanone [591-78-6]^
0.88
U
ug/L
1
0.88
5.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
U
ug/L
1
1.1
5.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Acetone [67-64-1]^
10
U
ug/L
1
10
20
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Acrylonitrile [107-13-1]^
3.5
U
ug/L
1
3.5
10
2DO1019
EPA 8260D
04/02/22 12:46
RKY
QV-01
Benzene [71-43-2]A
2.3
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Bromochloromethane [74-97-5]^
0.48
U
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Bromodichloromethane [75-27-4]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Bromoform [75-25-2]^
0.22
U
ug/L
1
0.22
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Bromomethane [74-83-9]^
0.14
U
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
QV-01
Carbon disulfide [75-15-0]^
1.5
U
ug/L
1
1.5
5.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Carbon tetrachloride [56-23-5]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Chlorobenzene [308-90-7]A
1.5
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Chloroethane [75-00-3]^
0.23
U
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
QV-01
Chloroform [67-66-3]^
0.18
U
ug/L
1
0.18
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Chloromethane [74-87-3]^
0.13
U
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
cis- 1,2-Dichloroethene [156-59-2]A
69
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
cis- 1,3-Dichloropropene [10061-01-5]^
0.20
U
ug/L
1
0.20
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Dibromochloromethane [124-48-1]^
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Dibromomethane [74-95-3]^
0.27
U
ug/L
1
0.27
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Dichlorodifluoromethane [75-71-8]^
0.20
U
ug/L
1
0.20
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Ethylbenzene [100-41-4]^
0.13
U
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Iodomethane [74-88-4]^
1.7
U
ug/L
1
1.7
5.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Methylene chloride [75-09-2]A
6.4
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Styrene [100-42-5]^
0.11
U
ug/L
1
0.11
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Tetrachloroethene [127-18-4]A
27
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Toluene [108-88-3]^
0.14
U
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
U
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
U
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
trans-1,4-Dichloro-2-butene [110-57-6]^
0.70
U
ug/L
1
0.70
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Trichloroethene [79-01-6]A
30
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Trichlorofluoromethane [75-69-4]^
0.24
U
ug/L
1
0.24
1.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
Vinyl acetate [108-05-4]^
0.95
U
ug/L
1
0.95
5.0
2DO1019
EPA 8260D
04/02/22 12:46
RKY
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 56 Of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-PZ86B Lab Sample ID:CF03672-09 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 10:40 Work Order: CF03672
Project: Catawba Co Blackburn Facility - Unit 1 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes
Vinyl chloride [75-01-4]^ 2.3 ug/L 1 0.32 1.0 2DO1019 EPA 8260D 04/02/22 12:46 RKY
Xylenes(Total)[1330-20-7]^ 0.83 J ug/L 1 0.45 3.0 2DO1019 EPA 8260D 04/02/22 12:46 RKY
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
ffy
Notes
4-Bromofluorobenzene
54
1
50.0
107 %
53-136
2DO1019
EPA 8260D
04102122 12:46
RKY
Dibromofluoromethane
47
1
50.0
95 %
67-129
2DO1019
EPA 8260D
04102122 12:46
RKY
Toluene-d8
53
1
50.0
106 %
59-134
2DO1019
EPA 8260D
04102122 12:46
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
By
Notes
Antimony[7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29004
EPA 6020B
04/04/22 11:58
JDH
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29003
EPA 6010D
04/01/22 13:09
JDH
Barium [7440-39-3]^
115
ug/L
1
1.10
10.0
2C29003
EPA 6010D
04/01/22 13:09
JDH
Beryllium [7440-41-7]^
0.160
U
ug/L
1
0.160
1.00
2C29003
EPA 6010D
04/01/22 13:09
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29003
EPA 6010D
04/01/22 13:09
JDH
Chromium [7440-47-3]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:09
JDH
Cobalt [7440-48-4]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:09
JDH
Copper[7440-50-8]^
1.60
U
ug/L
1
1.60
10.0
2C29003
EPA 6010D
04/01/22 13:09
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29003
EPA 6010D
04/01/22 13:09
JDH
Nickel[7440-02-0]^
2.20
U
ug/L
1
2.20
10.0
2C29003
EPA 6010D
04/01/22 13:09
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29004
EPA 6020B
04/04/22 11:58
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29003
EPA 6010D
04/01/22 13:09
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29004
EPA 6020B
04/04/22 11:58
JDH
Vanadium [7440-62-2]^
2.54
J
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:09
JDH
Zinc [7440-66-6]^
4.40
U
ug/L
1
4.40
10.0
2C29003
EPA 6010D
04/01/22 13:09
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80
2.0
200024
EPA 8260D
03/31/22 05:14
KKW
Surrogates
Results
DF
Soike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
"
Notes
Toluene-&
4.7
1
5.00
94 %
75-125
200024
EPA 8260D
03131122 05:14
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 57 Of 118

0Nk"q09
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW12R Lab Sample ID:CF03673-01 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 15:35 Work Order: CF03673
Project: Catawba Cc Blackburn Facility - Unit 2 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certfied anaiyte [NC 591]
Analyte ICAS Numberl
Results
Flaa
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
1,1,1,2-Tetrachloroethane [630-20-6]A
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
1,1,1-Trichloroethane [71-55-6]A
0.12
U
ug/L
1
0.12
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
1,1,2,2-Tetrachloroethane [79-34-5]A
0.28
U
ug/L
1
0.28
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
1,1,2-Trichloroethane [79-00-5]A
0.14
U
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
1,1-Dichloroethane [75-34-3]A
0.13
U
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
1,1-Dichloroethene [75-35-4]A
0.21
U
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
1,2,3-Trichloropropane [96-18-4]A
0.23
U
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
1,2-Dibromo-3-chloropropane [96-12-8]A
0.48
U
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
1,2-Dibromoethane [106-93-4]A
0.66
U
ug/L
1
0.66
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
1,2-Dichlorobenzene [95-50-1]A
0.19
U
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
1,2-Dichloroethane [107-06-2]A
0.21
U
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
1,2-Dichloropropane [78-87-5]A
0.10
U
ug/L
1
0.10
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
1,4-Dichlorobenzene [106-46-7]A
0.19
U
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
2-Butanone [78-93-3]A
1.3
U
ug/L
1
1.3
5.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
2-Hexanone [591-78-6]A
0.88
U
ug/L
1
0.88
5.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
4-Methyl-2-pentanone [108-10-1]A
1.1
U
ug/L
1
1.1
5.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Acetone [67-64-1]A
10
U
ug/L
1
10
20
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Acrylonitrile [107-13-1]A
3.5
U
ug/L
1
3.5
10
2DO1019
EPA 8260D
04/02/22 13:14
RKY QV-01
Benzene [71-43-2]A
0.15
U
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Bromochloromethane [74-97-5]A
0.48
U
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Bromodichloromethane [75-27-4]A
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Bromoform [75-25-2]A
0.22
U
ug/L
1
0.22
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Bromomethane [74-83-9]A
0.14
U
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY QV-01
Carbon disulfide [75-15-0]A
1.5
U
ug/L
1
1.5
5.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Carbon tetrachloride [56-23-5]A
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Chlorobenzene [108-90-7]A
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Chloroethane [75-00-3]A
0.23
U
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY QV-01
Chloroform [67-66-3]A
0.18
U
ug/L
1
0.18
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Chloromethane [74-87-3]A
0.13
U
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
cis-1,2-Dichloroethene [156-59-2]A
0.81
J
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
cis-1,3-Dichloropropene [10061-01-5]A
0.20
U
ug/L
1
0.20
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Dibromochloromethane [124-48-1]A
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Dibromomethane [74-95-3]A
0.27
U
ug/L
1
0.27
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Ethylbenzene [100-41-4]A
0.13
U
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Iodomethane [74-88-4]A
1.7
U
ug/L
1
1.7
5.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Methylene chloride [75-09-2]A
0.23
U
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Styrene [100-42-5]A
0.11
U
ug/L
1
0.11
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Tetrachloroethene [127-18-4]A
0.17
U
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Toluene [108-88-3]A
0.14
U
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
trans-1,2-Dichloroethene [156-60-5]A
0.21
U
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
trans-1,3-Dichloropropene [10061-02-6]A
0.15
U
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
trans-1,4-Dichloro-2-butene [110-57-6]A
0.70
U
ug/L
1
0.70
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Trichloroethene [79-01-6]A
0.15
U
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Trichlorofluoromethane [75-69-4]A
0.24
U
ug/L
1
0.24
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Vinyl acetate [108-05-4]A
0.95
U
ug/L
1
0.95
5.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Vinyl chloride [75-01-4]A
0.53
J
ug/L
1
0.32
1.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
Xylenes (Total) [1330-20-7]A
0.45
U
ug/L
1
0.45
3.0
2DO1019
EPA 8260D
04/02/22 13:14
RKY
FINAL
This report relates only
to the sample as received by the
laboratory,
and may only be reproduced in full.
I Page 58 Of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW12R Lab Sample ID:CF03673-01 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 15:35 Work Order: CF03673
Project: Catawba Co Blackburn Facility - Unit 2 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By
Notes
4-Bromofluorobenzene
55
1
50.0
110 %
53-136
2DO1019
EPA 6260D
04102122 13:14
RKY
Dibromofluoromethane
48
1
50.0
95 %
67-129
2DO1019
EPA 6260D
0410212213:14
RKY
Toluene-d8
56
1
50.0
112 %
59-134
2DO1019
EPA 6260D
0410212213:14
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
Antimony[7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29004
EPA 6020B
04/04/22 12:02
JDH
Arsenic [7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29003
EPA 6010D
04/01/22 11:33
JDH
Barium [7440-39-3]^
159
ug/L
1
1.10
10.0
2C29003
EPA 6010D
04/01/22 11:33
JDH
Beryllium [7440-41-7]^
0.160
U
ug/L
1
0.160
1.00
2C29003
EPA 6010D
04/01/22 11:33
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29003
EPA 6010D
04/01/22 11:33
JDH
Chromium [7440-47-3]^
6.97
J
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 11:33
JDH
Cobalt [7440-48-4]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 11:33
JDH
Copper[7440-50-8]^
1.60
U
ug/L
1
1.60
10.0
2C29003
EPA 6010D
04/01/22 11:33
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29003
EPA 6010D
04/01/22 11:33
JDH
Nickel[7440-02-0]^
2.20
U
ug/L
1
2.20
10.0
2C29003
EPA 6010D
04/01/22 11:33
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29004
EPA 6020B
04/04/22 12:02
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29003
EPA 6010D
04/01/22 11:33
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29004
EPA 6020B
04/04/22 12:02
JDH
Vanadium [7440-62-2]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 11:33
JDH
Zinc[7440-66-6]^
8.42
J
ug/L
1
4.40
10.0
2C29003
EPA 6010D
04/01/22 11:33
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80
2.0
201031
EPA 8260D
03/31/22 14:31
KKW
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Analyzed
ffly
Notes
Toluene-d8
4.7
1
5.00
95 %
75-125
201031
EPA 8260D
03131122 14:31
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 59 Of H

0Nk"q09
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW13 Lab Sample ID:CF03673-02 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 15:23 Work Order: CF03673
Project: Catawba Cc Blackburn Facility - Unit 2 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certfied anaiyte [NC 591]
Analyte ICAS Numberl
Results
Flaa
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
1,1,1,2-Tetrachloroethane [630-20-6]A
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
1,1,1-Trichloroethane [71-55-6]A
0.12
u
ug/L
1
0.12
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
1,1,2,2-Tetrachloroethane [79-34-5]A
0.28
u
ug/L
1
0.28
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
1,1,2-Trichloroethane [79-00-5]A
0.14
u
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
1,1-Dichloroethane [75-34-3]^
0.13
u
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
1,1-Dichloroethene [75-35-4]^
0.21
u
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
u
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
u
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
1,2-Dibromoethane [106-93-4]^
0.66
u
ug/L
1
0.66
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
u
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
1,2-Dichloroethane [107-06-2]^
0.21
u
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
1,2-Dichloropropane [78-87-5]^
0.10
u
ug/L
1
0.10
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
1,4-Dichlorobenzene [106-46-7]^
0.19
u
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
2-Butanone [78-93-3]A
1.3
u
ug/L
1
1.3
5.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
2-Hexanone [591-78-6]A
0.88
u
ug/L
1
0.88
5.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
u
ug/L
1
1.1
5.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Acetone [67-64-1]A
10
u
ug/L
1
10
20
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Acrylonitrile [107-13-1]^
3.5
u
ug/L
1
3.5
10
2DO1019
EPA 8260D
04/02/22 13:41
RKY QV-01
Benzene [71-43-2]A
0.15
u
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Bromochloromethane [74-97-5]A
0.48
u
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Bromodichloromethane [75-27-4]^
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Bromoform [75-25-2]^
0.22
u
ug/L
1
0.22
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Bromomethane [74-83-9]A
0.14
u
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY QV-01
Carbon disulfide [75-15-0]A
1.5
u
ug/L
1
1.5
5.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Carbon tetrachloride [56-23-5]A
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Chlorobenzene [108-90-7]A
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Chloroethane [75-00-3]A
0.23
u
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY QV-01
Chloroform [67-66-3]^
0.18
u
ug/L
1
0.18
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Chloromethane [74-87-3]A
0.13
u
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
cis-1,2-Dichloroethene [156-59-2]^
0.15
u
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
cis-1,3-Dichloropropene [10061-01-5]A
0.20
u
ug/L
1
0.20
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Dibromochloromethane [124-48-1]A
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Dibromomethane [74-95-3]A
0.27
u
ug/L
1
0.27
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Ethylbenzene [100-41-4]A
0.13
u
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Iodomethane [74-88-4]^
1.7
u
ug/L
1
1.7
5.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Methylene chloride [75-09-2]A
0.23
u
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Styrene [100-42-5]A
0.11
u
ug/L
1
0.11
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Tetrachloroethene [127-18-4]A
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Toluene [108-88-3]^
0.14
u
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
u
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
u
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
trans-1,4-Dichloro-2-butene [110-57-6]A
0.70
u
ug/L
1
0.70
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Trichloroethene [79-01-6]^
0.15
u
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Trichlorofluoromethane [75-69-4]^
0.24
u
ug/L
1
0.24
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Vinyl acetate [108-05-4]A
0.95
u
ug/L
1
0.95
5.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Vinyl chloride [75-01-4]^
0.32
u
ug/L
1
0.32
1.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
Xylenes (Total) [1330-20-7]A
0.45
u
ug/L
1
0.45
3.0
2DO1019
EPA 8260D
04/02/22 13:41
RKY
FINAL
This report relates only to the sample as received by the
laboratory,
and may only be reproduced in full.
I Page 60 of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW13 Lab Sample ID:CF03673-02 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 15:23 Work Order: CF03673
Project: Catawba Co Blackburn Facility - Unit 2 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By
Notes
4-Bromofluorobenzene
55
1
50.0
109 %
53-136
2DO1019
EPA 8260D
04102122 13:41
RKY
Dibromofluoromethane
50
1
50.0
101 %
67-129
2DO1019
EPA 8260D
0410212213:41
RKY
Toluene-d8
55
1
50.0
ill %
59-134
2DO1019
EPA 6260D
0410212213:41
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
Antimony[7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29004
EPA 6020B
04/04/22 12:06
JDH
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29003
EPA 6010D
04/01/22 13:14
JDH
Barium [7440-39-3]^
37.3
ug/L
1
1.10
10.0
2C29003
EPA 6010D
04/01/22 13:14
JDH
Beryllium [7440-41-7]^
0.160
U
ug/L
1
0.160
1.00
2C29003
EPA 6010D
04/01/22 13:14
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29003
EPA 6010D
04/01/22 13:14
JDH
Chromium [7440-47-3]^
2.88
J
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:14
JDH
Cobalt[7440-48-4]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:14
JDH
Copper[7440-50-8]^
1.60
U
ug/L
1
1.60
10.0
2C29003
EPA 6010D
04/01/22 13:14
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29003
EPA 6010D
04/01/22 13:14
JDH
Nickel[7440-02-0]^
2.20
U
ug/L
1
2.20
10.0
2C29003
EPA 6010D
04/01/22 13:14
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29004
EPA 6020B
04/04/22 12:06
JDH
Silver[7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29003
EPA 6010D
04/01/22 13:14
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29004
EPA 6020B
04/04/22 12:06
JDH
Vanadium [7440-62-2]^
1.53
J
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:14
JDH
Zinc[7440-66-6]^
8.26
J
ug/L
1
4.40
10.0
2C29003
EPA 6010D
04/01/22 13:14
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80
2.0
201031
EPA 8260D
03/31/22 14:57
KKW
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Analyzed
ffly
Notes
Toluene-d8
4.6
1
5.00
93 %
75-125
201031
EPA 8260D
0313112214:57
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 61 Of H

0Nk"q09
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW14 Lab Sample ID:CF03673-03 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 15:15 Work Order: CF03673
Project: Catawba Cc Blackburn Facility - Unit 2 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certfied anaiyte [NC 591]
Analyte ICAS Numberl
Results
Flaa
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
1,1,1,2-Tetrachloroethane [630-20-6]A
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
1,1,1-Trichloroethane [71-55-6]A
0.12
u
ug/L
1
0.12
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
1,1,2,2-Tetrachloroethane [79-34-5]A
0.28
u
ug/L
1
0.28
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
1,1,2-Trichloroethane [79-00-5]A
0.14
u
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
1,1-Dichloroethane [75-34-3]^
0.13
u
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
1,1-Dichloroethene [75-35-4]^
0.21
u
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
u
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
u
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
1,2-Dibromoethane [106-93-4]^
0.66
u
ug/L
1
0.66
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
u
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
1,2-Dichloroethane [107-06-2]^
0.21
u
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
1,2-Dichloropropane [78-87-5]^
0.10
u
ug/L
1
0.10
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
1,4-Dichlorobenzene [106-46-7]^
0.19
u
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
2-Butanone [78-93-3]A
1.3
u
ug/L
1
1.3
5.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
2-Hexanone [591-78-6]A
0.88
u
ug/L
1
0.88
5.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
u
ug/L
1
1.1
5.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Acetone [67-64-1]A
10
u
ug/L
1
10
20
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Acrylonitrile [107-13-1]^
3.5
u
ug/L
1
3.5
10
2DO1019
EPA 8260D
04/02/22 14:09
RKY QV-01
Benzene [71-43-2]A
0.15
u
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Bromochloromethane [74-97-5]A
0.48
u
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Bromodichloromethane [75-27-4]^
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Bromoform [75-25-2]^
0.22
u
ug/L
1
0.22
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Bromomethane [74-83-9]A
0.14
u
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY QV-01
Carbon disulfide [75-15-0]A
1.5
u
ug/L
1
1.5
5.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Carbon tetrachloride [56-23-5]A
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Chlorobenzene [108-90-7]A
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Chloroethane [75-00-3]A
0.23
u
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY QV-01
Chloroform [67-66-3]^
0.18
u
ug/L
1
0.18
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Chloromethane [74-87-3]A
0.13
u
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
cis-1,2-Dichloroethene [156-59-2]^
0.15
u
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
cis-1,3-Dichloropropene [10061-01-5]A
0.20
u
ug/L
1
0.20
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Dibromochloromethane [124-48-1]A
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Dibromomethane [74-95-3]A
0.27
u
ug/L
1
0.27
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Ethylbenzene [100-41-4]A
0.13
u
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Iodomethane [74-88-4]^
1.7
u
ug/L
1
1.7
5.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Methylene chloride [75-09-2]A
0.23
u
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Styrene [100-42-5]A
0.11
u
ug/L
1
0.11
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Tetrachloroethene [127-18-4]A
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Toluene [108-88-3]^
0.14
u
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
u
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
u
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
trans-1,4-Dichloro-2-butene [110-57-6]A
0.70
u
ug/L
1
0.70
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Trichloroethene [79-01-6]^
0.15
u
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Trichlorofluoromethane [75-69-4]^
0.24
u
ug/L
1
0.24
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Vinyl acetate [108-05-4]A
0.95
u
ug/L
1
0.95
5.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Vinyl chloride [75-01-4]^
0.32
u
ug/L
1
0.32
1.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
Xylenes (Total) [1330-20-7]A
0.45
u
ug/L
1
0.45
3.0
2DO1019
EPA 8260D
04/02/22 14:09
RKY
FINAL
This report relates only to the sample as received by the
laboratory,
and may only be reproduced in full.
I Page 62 of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW14 Lab Sample ID:CF03673-03 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 15:15 Work Order: CF03673
Project: Catawba Co Blackburn Facility - Unit 2 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By
Notes
4-Bromofluorobenzene
52
1
50.0
104 %
53-136
2DO1019
EPA 6260D
04102122 14:09
RKY
Dibromofluoromethane
48
1
50.0
96 %
67-129
2DO1019
EPA 6260D
0410212214:09
RKY
Toluene-d8
55
1
50.0
111 %
59-134
2DO1019
EPA 6260D
0410212214:09
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
Antimony[7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29004
EPA 6020B
04/04/22 12:10
JDH
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29003
EPA 6010D
04/01/22 13:17
JDH
Barium [7440-39-3]^
27.8
ug/L
1
1.10
10.0
2C29003
EPA 6010D
04/01/22 13:17
JDH
Beryllium [7440-41-7]^
0.160
U
ug/L
1
0.160
1.00
2C29003
EPA 6010D
04/01/22 13:17
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29003
EPA 6010D
04/01/22 13:17
JDH
Chromium [7440-47-3]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:17
JDH
Cobalt[7440-48-4]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:17
JDH
Copper[7440-50-8]^
1.60
U
ug/L
1
1.60
10.0
2C29003
EPA 6010D
04/01/22 13:17
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29003
EPA 6010D
04/01/22 13:17
JDH
Nickel[7440-02-0]^
2.20
U
ug/L
1
2.20
10.0
2C29003
EPA 6010D
04/01/22 13:17
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29004
EPA 6020B
04/04/22 12:10
JDH
Silver[7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29003
EPA 6010D
04/01/22 13:17
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29004
EPA 6020B
04/04/22 12:10
JDH
Vanadium [7440-62-2]^
1.59
J
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:17
JDH
Zinc[7440-66-6]^
4.40
U
ug/L
1
4.40
10.0
2C29003
EPA 6010D
04/01/22 13:17
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80
2.0
201031
EPA 8260D
03/31/22 15:23
KKW
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Analyzed
ffly
Notes
Toluene-d8
5.0
1
5.00
100 %
75-125
201031
EPA 8260D
0313112215:23
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 63 Of H

0Nk"q09
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW15 Lab Sample ID:CF03673-04 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/22/22 15:42 Work Order: CF03673
Project: Catawba Cc Blackburn Facility - Unit 2 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certfied anaiyte [NC 591]
Analyte ICAS Numberl
Results
Flaa
Units
DF
MDL
P L
Batch
Method
Analyzed
By
Notes
1,1,1,2-Tetrachloroethane [630-20-6]A
0.17
u
ug/L
1
0.17
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
1,1,1-Trichloroethane [71-55-6]A
0.12
u
ug/L
1
0.12
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
1,1,2,2-Tetrachloroethane [79-34-5]A
0.28
u
ug/L
1
0.28
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
1,1,2-Trichloroethane [79-00-5]A
0.14
u
ug/L
1
0.14
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
1,1-Dichloroethane [75-34-3]^
0.13
u
ug/L
1
0.13
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
1,1-Dichloroethene [75-35-4]^
0.21
u
ug/L
1
0.21
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
u
ug/L
1
0.23
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
u
ug/L
1
0.48
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
1,2-Dibromoethane [106-93-4]^
0.66
u
ug/L
1
0.66
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
u
ug/L
1
0.19
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
1,2-Dichloroethane [107-06-2]^
0.21
u
ug/L
1
0.21
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
1,2-Dichloropropane [78-87-5]^
0.10
u
ug/L
1
0.10
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
1,4-Dichlorobenzene [106-46-7]^
0.19
u
ug/L
1
0.19
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
2-Butanone [78-93-3]A
1.3
u
ug/L
1
1.3
5.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
QV-01
2-Hexanone [591-78-6]A
0.88
u
ug/L
1
0.88
5.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
u
ug/L
1
1.1
5.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
QV-01
Acetone [67-64-1]A
10
u
ug/L
1
10
20
2DO1018
EPA 8260D
04/01/22 23:58
RKY
QV-01
Acrylonitrile [107-13-1]^
3.5
u
ug/L
1
3.5
10
2DO1018
EPA 8260D
04/01/22 23:58
RKY
QV-01
Benzene[71-43-2]A
0.15
u
ug/L
1
0.15
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
Bromochloromethane [74-97-5]A
0.48
u
ug/L
1
0.48
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
Bromodichloromethane [75-27-4]^
0.17
u
ug/L
1
0.17
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
Bromoform [75-25-2]^
0.22
u
ug/L
1
0.22
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
Bromomethane [74-83-9]A
0.14
u
ug/L
1
0.14
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
QV-01
Carbon disulfide [75-15-0]A
1.5
u
ug/L
1
1.5
5.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
Carbon tetrachloride [56-23-5]A
0.17
u
ug/L
1
0.17
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
Chlorobenzene [108-90-7]A
0.17
u
ug/L
1
0.17
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
Chloroethane [75-00-3]A
0.23
u
ug/L
1
0.23
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
QV-01
Chloroform [67-66-3]^
0.18
u
ug/L
1
0.18
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
Chloromethane [74-87-3]A
0.13
u
ug/L
1
0.13
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
cis-1,2-Dichloroethene [156-59-2]^
0.15
u
ug/L
1
0.15
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
cis-1,3-Dichloropropene [10061-01-5]A
0.20
u
ug/L
1
0.20
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
Dibromochloromethane [124-48-1]A
0.17
u
ug/L
1
0.17
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
Dibromomethane [74-95-3]A
0.27
u
ug/L
1
0.27
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
Ethylbenzene [100-41-4]A
0.13
u
ug/L
1
0.13
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
Iodomethane [74-88-4]^
1.7
u
ug/L
1
1.7
5.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
Methylene chloride [75-09-2]A
0.23
u
ug/L
1
0.23
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
Styrene [100-42-5]A
0.11
u
ug/L
1
0.11
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
Tetrachloroethene [127-18-4]A
0.17
u
ug/L
1
0.17
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
Toluene [108-88-3]^
0.14
u
ug/L
1
0.14
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
u
ug/L
1
0.21
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
u
ug/L
1
0.15
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
trans-1,4-Dichloro-2-butene [110-57-6]A
0.70
u
ug/L
1
0.70
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
Trichloroethene [79-01-6]^
0.15
u
ug/L
1
0.15
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
Trichlorofluoromethane [75-69-4]^
0.24
u
ug/L
1
0.24
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
Vinyl acetate [108-05-4]A
0.95
u
ug/L
1
0.95
5.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
QV-01
Vinyl chloride [75-01-4]^
0.32
u
ug/L
1
0.32
1.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
Xylenes (Total) [1330-20-7]A
0.45
u
ug/L
1
0.45
3.0
2DO1018
EPA 8260D
04/01/22 23:58
RKY
FINAL
This report relates only to the sample as received by the
laboratory,
and may only be reproduced in full.
I Page 64 of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW15 Lab Sample ID:CF03673-04 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/22/22 15:42 Work Order: CF03673
Project: Catawba Co Blackburn Facility - Unit 2 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By
Notes
4-Bromofluorobenzene
56
1
50.0
112 %
53-136
2DO1018
EPA 8260D
04101122 23:58
RKY
Dibromofluoromethane
51
1
50.0
101 %
67-129
2DO1018
EPA 8260D
04101122 23:58
RKY
Toluene-d8
57
1
50.0
115 %
59-134
2DO1018
EPA 6260D
04101122 23:58
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
Antimony[7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29004
EPA 6020B
04/04/22 12:15
JDH
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29003
EPA 6010D
04/01/22 13:25
JDH
Barium [7440-39-3]^
25.3
ug/L
1
1.10
10.0
2C29003
EPA 6010D
04/01/22 13:25
JDH
Beryllium [7440-41-7]^
0.160
U
ug/L
1
0.160
1.00
2C29003
EPA 6010D
04/01/22 13:25
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29003
EPA 6010D
04/01/22 13:25
JDH
Chromium [7440-47-3]^
2.23
J
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:25
JDH
Cobalt[7440-48-4]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:25
JDH
Copper[7440-50-8]^
1.60
U
ug/L
1
1.60
10.0
2C29003
EPA 6010D
04/01/22 13:25
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29003
EPA 6010D
04/01/22 13:25
JDH
Nickel[7440-02-0]^
2.20
U
ug/L
1
2.20
10.0
2C29003
EPA 6010D
04/01/22 13:25
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29004
EPA 6020B
04/04/22 12:15
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29003
EPA 6010D
04/01/22 13:25
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29004
EPA 6020B
04/04/22 12:15
JDH
Vanadium [7440-62-2]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:25
JDH
Zinc [7440-66-6]^
4.40
U
ug/L
1
4.40
10.0
2C29003
EPA 6010D
04/01/22 13:25
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80
2.0
201031
EPA 8260D
03/31/22 15:48
KKW
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Analyzed
ffly
Notes
Toluene-d8
4.8
1
5.00
96 %
75-125
201031
EPA 8260D
03131122 15:48
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 65 Of H

0Nk"q09
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW16 Lab Sample ID:CF03673-05 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 15:07 Work Order: CF03673
Project: Catawba Cc Blackburn Facility - Unit 2 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certfied anaiyte [NC 591]
Analyte ICAS Numberl
Results
Flaa
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
1,1,1,2-Tetrachloroethane [630-20-6]A
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
1,1,1-Trichloroethane [71-55-6]A
0.12
u
ug/L
1
0.12
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
1,1,2,2-Tetrachloroethane [79-34-5]A
0.28
u
ug/L
1
0.28
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
1,1,2-Trichloroethane [79-00-5]A
0.14
u
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
1,1-Dichloroethane [75-34-3]^
0.13
u
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
1,1-Dichloroethene [75-35-4]^
0.21
u
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
u
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
u
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
1,2-Dibromoethane [106-93-4]^
0.66
u
ug/L
1
0.66
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
u
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
1,2-Dichloroethane [107-06-2]^
0.21
u
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
1,2-Dichloropropane [78-87-5]^
0.10
u
ug/L
1
0.10
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
1,4-Dichlorobenzene [106-46-7]^
0.19
u
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
2-Butanone [78-93-3]A
1.3
u
ug/L
1
1.3
5.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
2-Hexanone [591-78-6]A
0.88
u
ug/L
1
0.88
5.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
u
ug/L
1
1.1
5.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Acetone [67-64-1]A
10
u
ug/L
1
10
20
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Acrylonitrile [107-13-1]^
3.5
u
ug/L
1
3.5
10
2DO1019
EPA 8260D
04/02/22 14:37
RKY QV-01
Benzene [71-43-2]A
0.15
u
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Bromochloromethane [74-97-5]A
0.48
u
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Bromodichloromethane [75-27-4]^
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Bromoform [75-25-2]^
0.22
u
ug/L
1
0.22
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Bromomethane [74-83-9]A
0.14
u
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY QV-01
Carbon disulfide [75-15-0]A
1.5
u
ug/L
1
1.5
5.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Carbon tetrachloride [56-23-5]A
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Chlorobenzene [108-90-7]A
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Chloroethane [75-00-3]A
0.23
u
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY QV-01
Chloroform [67-66-3]^
0.18
u
ug/L
1
0.18
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Chloromethane [74-87-3]A
0.13
u
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
cis-1,2-Dichloroethene [156-59-2]^
0.15
u
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
cis-1,3-Dichloropropene [10061-01-5]A
0.20
u
ug/L
1
0.20
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Dibromochloromethane [124-48-1]A
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Dibromomethane [74-95-3]A
0.27
u
ug/L
1
0.27
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Ethylbenzene [100-41-4]A
0.13
u
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Iodomethane [74-88-4]^
1.7
u
ug/L
1
1.7
5.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Methylene chloride [75-09-2]A
0.23
u
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Styrene [100-42-5]A
0.11
u
ug/L
1
0.11
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Tetrachloroethene [127-18-4]A
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Toluene [108-88-3]^
0.14
u
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
u
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
u
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
trans-1,4-Dichloro-2-butene [110-57-6]A
0.70
u
ug/L
1
0.70
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Trichloroethene [79-01-6]^
0.15
u
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Trichlorofluoromethane [75-69-4]^
0.24
u
ug/L
1
0.24
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Vinyl acetate [108-05-4]A
0.95
u
ug/L
1
0.95
5.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Vinyl chloride [75-01-4]^
0.32
u
ug/L
1
0.32
1.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
Xylenes (Total) [1330-20-7]A
0.45
u
ug/L
1
0.45
3.0
2DO1019
EPA 8260D
04/02/22 14:37
RKY
FINAL
This report relates only to the sample as received by the
laboratory,
and may only be reproduced in full.
I Page 66 of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW16 Lab Sample ID:CF03673-05 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 15:07 Work Order: CF03673
Project: Catawba Co Blackburn Facility - Unit 2 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By
Notes
4-Bromofluorobenzene
52
1
50.0
105 %
53-136
2DO1019
EPA 6260D
04102122 14:37
RKY
Dibromofluoromethane
47
1
50.0
94 %
67-129
2DO1019
EPA 6260D
0410212214:37
RKY
Toluene-d8
53
1
50.0
107 %
59-134
2DO1019
EPA 6260D
0410212214:37
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
Antimony[7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29004
EPA 6020B
04/04/22 12:19
JDH
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29003
EPA 6010D
04/01/22 13:27
JDH
Barium [7440-39-3]^
29.5
ug/L
1
1.10
10.0
2C29003
EPA 6010D
04/01/22 13:27
JDH
Beryllium [7440-41-7]^
0.160
U
ug/L
1
0.160
1.00
2C29003
EPA 6010D
04/01/22 13:27
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29003
EPA 6010D
04/01/22 13:27
JDH
Chromium [7440-47-3]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:27
JDH
Cobalt[7440-48-4]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:27
JDH
Copper[7440-50-8]^
1.99
J
ug/L
1
1.60
10.0
2C29003
EPA 6010D
04/01/22 13:27
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29003
EPA 6010D
04/01/22 13:27
JDH
Nickel[7440-02-0]^
2.20
U
ug/L
1
2.20
10.0
2C29003
EPA 6010D
04/01/22 13:27
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29004
EPA 6020B
04/04/22 12:19
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29003
EPA 6010D
04/01/22 13:27
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29004
EPA 6020B
04/04/22 12:19
JDH
Vanadium [7440-62-2]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:27
JDH
Zinc[7440-66-6]^
4.76
J
ug/L
1
4.40
10.0
2C29003
EPA 6010D
04/01/22 13:27
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80
2.0
201031
EPA 8260D
03/31/22 16:14
KKW
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Analyzed
ffly
Notes
Toluene-d8
5.0
1
5.00
99 %
75-125
201031
EPA 8260D
0313112216:14
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 67 Of H

0Nk"q09
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW17 Lab Sample ID:CF03673-06 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 14:56 Work Order: CF03673
Project: Catawba Cc Blackburn Facility - Unit 2 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certfied anaiyte [NC 591]
Analyte ICAS Numberl
Results
Flaa
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
1,1,1,2-Tetrachloroethane [630-20-6]A
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
1,1,1-Trichloroethane [71-55-6]A
0.12
u
ug/L
1
0.12
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
1,1,2,2-Tetrachloroethane [79-34-5]A
0.28
u
ug/L
1
0.28
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
1,1,2-Trichloroethane [79-00-5]A
0.14
u
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
1,1-Dichloroethane [75-34-3]^
0.13
u
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
1,1-Dichloroethene [75-35-4]^
0.21
u
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
u
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
u
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
1,2-Dibromoethane [106-93-4]^
0.66
u
ug/L
1
0.66
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
u
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
1,2-Dichloroethane [107-06-2]^
0.21
u
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
1,2-Dichloropropane [78-87-5]^
0.10
u
ug/L
1
0.10
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
1,4-Dichlorobenzene [106-46-7]^
0.19
u
ug/L
1
0.19
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
2-Butanone [78-93-3]A
1.3
u
ug/L
1
1.3
5.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
2-Hexanone [591-78-6]A
0.88
u
ug/L
1
0.88
5.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
u
ug/L
1
1.1
5.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Acetone [67-64-1]A
10
u
ug/L
1
10
20
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Acrylonitrile [107-13-1]^
3.5
u
ug/L
1
3.5
10
2DO1019
EPA 8260D
04/02/22 15:05
RKY QV-01
Benzene [71-43-2]A
0.15
u
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Bromochloromethane [74-97-5]A
0.48
u
ug/L
1
0.48
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Bromodichloromethane [75-27-4]^
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Bromoform [75-25-2]^
0.22
u
ug/L
1
0.22
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Bromomethane [74-83-9]A
0.14
u
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY QV-01
Carbon disulfide [75-15-0]A
1.5
u
ug/L
1
1.5
5.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Carbon tetrachloride [56-23-5]A
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Chlorobenzene [108-90-7]A
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Chloroethane [75-00-3]A
0.23
u
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY QV-01
Chloroform [67-66-3]^
0.18
u
ug/L
1
0.18
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Chloromethane [74-87-3]A
0.13
u
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
cis-1,2-Dichloroethene [156-59-2]^
0.15
u
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
cis-1,3-Dichloropropene [10061-01-5]A
0.20
u
ug/L
1
0.20
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Dibromochloromethane [124-48-1]A
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Dibromomethane [74-95-3]A
0.27
u
ug/L
1
0.27
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Ethylbenzene [100-41-4]A
0.13
u
ug/L
1
0.13
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Iodomethane [74-88-4]^
1.7
u
ug/L
1
1.7
5.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Methylene chloride [75-09-2]A
0.23
u
ug/L
1
0.23
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Styrene [100-42-5]A
0.11
u
ug/L
1
0.11
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Tetrachloroethene [127-18-4]A
0.17
u
ug/L
1
0.17
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Toluene [108-88-3]^
0.14
u
ug/L
1
0.14
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
u
ug/L
1
0.21
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
u
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
trans-1,4-Dichloro-2-butene [110-57-6]A
0.70
u
ug/L
1
0.70
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Trichloroethene [79-01-6]^
0.15
u
ug/L
1
0.15
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Trichlorofluoromethane [75-69-4]^
0.24
u
ug/L
1
0.24
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Vinyl acetate [108-05-4]A
0.95
u
ug/L
1
0.95
5.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Vinyl chloride [75-01-4]^
0.32
u
ug/L
1
0.32
1.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
Xylenes (Total) [1330-20-7]A
0.45
u
ug/L
1
0.45
3.0
2DO1019
EPA 8260D
04/02/22 15:05
RKY
FINAL
This report relates only to the sample as received by the
laboratory,
and may only be reproduced in full.
I Page 68 of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW17 Lab Sample ID:CF03673-06 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/23/22 14:56 Work Order: CF03673
Project: Catawba Co Blackburn Facility - Unit 2 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By
Notes
4-Bromofluorobenzene
53
1
50.0
106 %
53-136
2DO1019
EPA 6260D
04102122 15:05
RKY
Dibromofluoromethane
44
1
50.0
87 %
67-129
2DO1019
EPA 6260D
0410212215:05
RKY
Toluene-d8
55
1
50.0
110 %
59-134
2DO1019
EPA 6260D
0410212215:05
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
Antimony[7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29004
EPA 6020B
04/04/22 12:23
JDH
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29003
EPA 6010D
04/01/22 13:30
JDH
Barium [7440-39-3]^
41.3
ug/L
1
1.10
10.0
2C29003
EPA 6010D
04/01/22 13:30
JDH
Beryllium [7440-41-7]^
0.160
U
ug/L
1
0.160
1.00
2C29003
EPA 6010D
04/01/22 13:30
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29003
EPA 6010D
04/01/22 13:30
JDH
Chromium [7440-47-3]^
1.78
J
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:30
JDH
Cobalt[7440-48-4]^
2.71
J
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:30
JDH
Copper[7440-50-8]^
4.27
J
ug/L
1
1.60
10.0
2C29003
EPA 6010D
04/01/22 13:30
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29003
EPA 6010D
04/01/22 13:30
JDH
Nickel[7440-02-0]^
2.20
U
ug/L
1
2.20
10.0
2C29003
EPA 6010D
04/01/22 13:30
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29004
EPA 6020B
04/04/22 12:23
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29003
EPA 6010D
04/01/22 13:30
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29004
EPA 6020B
04/04/22 12:23
JDH
Vanadium [7440-62-2]^
5.61
J
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:30
JDH
Zinc[7440-66-6]^
7.16
J
ug/L
1
4.40
10.0
2C29003
EPA 6010D
04/01/22 13:30
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80
2.0
201031
EPA 8260D
03/31/22 16:40
KKW
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Analyzed
ffy
Notes
Toluene-d8
4.9
1
5.00
98 %
75-125
201031
EPA 8260D
0313112216:40
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 69 Of H

0Nk"q09
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW31R Lab Sample ID:CF03674-01 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 09:06 Work Order: CF03674
Project: Catawba Cc Blackburn Facility - Unit 3 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary rertified analyte [NC 591]
Analyte ICAS Numberl
Results
Flaa
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
1,1,1,2-Tetrachloroethane [630-20-6]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
1,1,1-Trichloroethane [71-55-6]A
0.12
u
ug/L
1
0.12
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
1,1,2,2-Tetrachloroethane [79-34-5]A
0.28
u
ug/L
1
0.28
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
1,1,2-Trichloroethane [79-00-5]A
0.14
u
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
1,1-Dichloroethane [75-34-3]^
0.13
u
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
1,1-Dichloroethene [75-35-4]^
0.21
u
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
u
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
u
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
1,2-Dibromoethane [106-93-4]^
0.66
u
ug/L
1
0.66
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
u
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
1,2-Dichloroethane [107-06-2]^
0.21
u
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
1,2-Dichloropropane [78-87-5]^
0.10
u
ug/L
1
0.10
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
1,4-Dichlorobenzene [106-46-7]^
0.19
u
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
2-Butanone [78-93-3]A
1.3
u
ug/L
1
1.3
5.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
2-Hexanone [591-78-6]A
0.88
u
ug/L
1
0.88
5.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
u
ug/L
1
1.1
5.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Acetone [67-64-1]A
10
u
ug/L
1
10
20
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Acrylonitrile [107-13-1]^
3.5
u
ug/L
1
3.5
10
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Benzene[71-43-2]A
0.15
u
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Bromochloromethane [74-97-5]A
0.48
u
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Bromodichloromethane [75-27-4]^
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Bromoform [75-25-2]^
0.22
u
ug/L
1
0.22
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Bromomethane [74-83-9]A
0.14
u
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY QV-01
Carbon disulfide [75-15-0]A
1.5
u
ug/L
1
1.5
5.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Carbon tetrachloride [56-23-5]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Chlorobenzene[108-90-7]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Chloroethane [75-00-3]A
0.23
u
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY QV-01
Chloroform [67-66-3]^
0.18
u
ug/L
1
0.18
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Chloromethane [74-87-3]A
0.13
u
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
cis-1,2-Dichloroethene [156-59-2]^
0.15
u
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
cis-1,3-Dichloropropene [10061-01-5]A
0.20
u
ug/L
1
0.20
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Dibromochloromethane [124-48-1]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Dibromomethane [74-95-3]A
0.27
u
ug/L
1
0.27
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Ethylbenzene[100-41-4]A
0.13
u
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Iodomethane [74-88-4]^
1.7
u
ug/L
1
1.7
5.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Methylene chloride [75-09-2]A
0.23
u
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Styrene[100-42-5]A
0.11
u
ug/L
1
0.11
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Tetrachloroethene [127-18-4]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Toluene [108-88-3]^
0.14
u
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
u
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
u
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
trans-1,4-Dichloro-2-butene [110-57-6]A
0.70
u
ug/L
1
0.70
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Trichloroethene [79-01-6]^
0.15
u
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Trichlorofluoromethane [75-69-4]^
0.24
u
ug/L
1
0.24
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Vinyl acetate [108-05-4]A
0.95
u
ug/L
1
0.95
5.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Vinyl chloride [75-01-4]^
0.32
u
ug/L
1
0.32
1.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
Xylenes (Total) [1330-20-7]A
0.45
u
ug/L
1
0.45
3.0
2DO4032
EPA 8260D
04/05/22 01:51
RKY
FINAL
This report relates only to the sample as received by the
laboratory,
and may only be reproduced in full.
I Page 70 Of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW31R Lab Sample ID:CF03674-01 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 09:06 Work Order: CF03674
Project: Catawba Co Blackburn Facility - Unit 3 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By
Notes
4-Bromofluorobenzene
54
1
50.0
108 %
53-136
2DO4032
EPA 6260D
04105122 01:51
RKY
Dibromofluoromethane
48
1
50.0
96 %
67-129
2DO4032
EPA 6260D
04105122 01:51
RKY
Toluene-d8
55
1
50.0
110 %
59-134
2DO4032
EPA 6260D
04105122 01:51
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
Antimony [7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29005
EPA 6020B
04/04/22 14:15
JDH
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29003
EPA 6010D
04/01/22 13:32
JDH
Barium [7440-39-3]^
103
ug/L
1
1.10
10.0
2C29003
EPA 6010D
04/01/22 13:32
JDH
Beryllium [7440-41-7]^
0.160
U
ug/L
1
0.160
1.00
2C29003
EPA 6010D
04/01/22 13:32
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29003
EPA 6010D
04/01/22 13:32
JDH
Chromium [7440-47-3]^
3.07
J
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:32
JDH
Cobalt[7440-48-4]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:32
JDH
Copper[7440-50-8]^
1.75
J
ug/L
1
1.60
10.0
2C29003
EPA 6010D
04/01/22 13:32
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29003
EPA 6010D
04/01/22 13:32
JDH
Nickel[7440-02-0]^
2.20
U
ug/L
1
2.20
10.0
2C29003
EPA 6010D
04/01/22 13:32
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29005
EPA 6020B
04/04/22 14:15
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29003
EPA 6010D
04/01/22 13:32
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29005
EPA 6020B
04/04/22 14:15
JDH
Vanadium [7440-62-2]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:32
JDH
Zinc[7440-66-6]^
4.91
J
ug/L
1
4.40
10.0
2C29003
EPA 6010D
04/01/22 13:32
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80
2.0
201031
EPA 8260D
03/31/22 18:23
KKW
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Analyzed
ffly
Notes
Toluene-d8
5.0
1
5.00
99 %
75-125
201031
EPA 8260D
0313112218:23
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 71 Of H

0Nk"q09
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW32 Lab Sample ID:CF03674-02 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 08:58 Work Order: CF03674
Project: Catawba Cc Blackburn Facility - Unit 3 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary rertified analyte [NC 591]
Analyte ICAS Numberl
Results
Flaa
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
1,1,1,2-Tetrachloroethane [630-20-6]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
1,1,1-Trichloroethane [71-55-6]A
0.12
u
ug/L
1
0.12
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
1,1,2,2-Tetrachloroethane [79-34-5]A
0.28
u
ug/L
1
0.28
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
1,1,2-Trichloroethane [79-00-5]A
0.14
u
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
1,1-Dichloroethane [75-34-3]^
0.13
u
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
1,1-Dichloroethene [75-35-4]^
0.21
u
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
u
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
u
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
1,2-Dibromoethane [106-93-4]^
0.66
u
ug/L
1
0.66
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
u
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
1,2-Dichloroethane [107-06-2]^
0.21
u
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
1,2-Dichloropropane [78-87-5]^
0.10
u
ug/L
1
0.10
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
1,4-Dichlorobenzene [106-46-7]^
0.19
u
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
2-Butanone [78-93-3]A
1.3
u
ug/L
1
1.3
5.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
2-Hexanone [591-78-6]A
0.88
u
ug/L
1
0.88
5.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
u
ug/L
1
1.1
5.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Acetone [67-64-1]A
10
u
ug/L
1
10
20
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Acrylonitrile [107-13-1]^
3.5
u
ug/L
1
3.5
10
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Benzene[71-43-2]A
0.15
u
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Bromochloromethane [74-97-5]A
0.48
u
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Bromodichloromethane [75-27-4]^
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Bromoform [75-25-2]^
0.22
u
ug/L
1
0.22
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Bromomethane [74-83-9]A
0.14
u
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY QV-01
Carbon disulfide [75-15-0]A
1.5
u
ug/L
1
1.5
5.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Carbon tetrachloride [56-23-5]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Chlorobenzene[108-90-7]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Chloroethane [75-00-3]A
0.23
u
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY QV-01
Chloroform [67-66-3]^
0.18
u
ug/L
1
0.18
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Chloromethane [74-87-3]A
0.13
u
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
cis-1,2-Dichloroethene [156-59-2]^
0.15
u
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
cis-1,3-Dichloropropene [10061-01-5]A
0.20
u
ug/L
1
0.20
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Dibromochloromethane [124-48-1]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Dibromomethane [74-95-3]A
0.27
u
ug/L
1
0.27
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Ethylbenzene[100-41-4]A
0.13
u
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Iodomethane [74-88-4]^
1.7
u
ug/L
1
1.7
5.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Methylene chloride [75-09-2]A
0.23
u
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Styrene[100-42-5]A
0.11
u
ug/L
1
0.11
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Tetrachloroethene [127-18-4]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Toluene [108-88-3]^
0.14
u
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
u
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
u
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
trans-1,4-Dichloro-2-butene [110-57-6]A
0.70
u
ug/L
1
0.70
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Trichloroethene [79-01-6]^
0.15
u
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Trichlorofluoromethane [75-69-4]^
0.24
u
ug/L
1
0.24
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Vinyl acetate [108-05-4]A
0.95
u
ug/L
1
0.95
5.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Vinyl chloride [75-01-4]^
0.32
u
ug/L
1
0.32
1.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
Xylenes (Total) [1330-20-7]A
0.45
u
ug/L
1
0.45
3.0
2DO4032
EPA 8260D
04/05/22
02:18
RKY
FINAL
This report relates only to the sample as received
by the
laboratory,
and may only be reproduced in full.
I Page 72 Of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW32 Lab Sample ID:CF03674-02 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 08:58 Work Order: CF03674
Project: Catawba Co Blackburn Facility - Unit 3 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By
Notes
4-Bromofluorobenzene
52
1
50.0
104 %
53-136
2DO4032
EPA 8260D
04105122 02:18
RKY
Dibromofluoromethane
50
1
50.0
100 %
67-129
2DO4032
EPA 8260D
04105122 02:18
RKY
Toluene-d8
56
1
50.0
ill %
59-134
2DO4032
EPA 6260D
04105122 02:18
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
Antimony[7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29005
EPA 6020B
04/04/22 14:20
JDH
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29003
EPA 6010D
04/01/22 13:35
JDH
Barium [7440-39-3]^
138
ug/L
1
1.10
10.0
2C29003
EPA 6010D
04/01/22 13:35
JDH
Beryllium [7440-41-7]^
0.178
J
ug/L
1
0.160
1.00
2C29003
EPA 6010D
04/01/22 13:35
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29003
EPA 6010D
04/01/22 13:35
JDH
Chromium [7440-47-3]^
2.22
J
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:35
JDH
Cobalt[7440-48-4]^
3.48
J
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:35
JDH
Copper[7440-50-8]^
1.85
J
ug/L
1
1.60
10.0
2C29003
EPA 6010D
04/01/22 13:35
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29003
EPA 6010D
04/01/22 13:35
JDH
Nickel[7440-02-0]^
2.20
U
ug/L
1
2.20
10.0
2C29003
EPA 6010D
04/01/22 13:35
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29005
EPA 6020B
04/04/22 14:20
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29003
EPA 6010D
04/01/22 13:35
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29005
EPA 6020B
04/04/22 14:20
JDH
Vanadium [7440-62-2]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:35
JDH
Zinc[7440-66-6]^
4.96
J
ug/L
1
4.40
10.0
2C29003
EPA 6010D
04/01/22 13:35
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80
2.0
201031
EPA 8260D
03/31/22 18:49
KKW
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Analyzed
ffly
Notes
Toluene-d8
4.7
1
5.00
94 %
75-125
201031
EPA 8260D
0313112218:49
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 73 Of H

0Nk"q09
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW33R Lab Sample ID:CF03674-03 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 08:51 Work Order: CF03674
Project: Catawba Cc Blackburn Facility - Unit 3 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary rertified analyte [NC 591]
Analyte ICAS Numberl
Results
Flaa
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
1,1,1,2-Tetrachloroethane [630-20-6]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
1,1,1-Trichloroethane [71-55-6]A
0.12
u
ug/L
1
0.12
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
1,1,2,2-Tetrachloroethane [79-34-5]A
0.28
u
ug/L
1
0.28
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
1,1,2-Trichloroethane [79-00-5]A
0.14
u
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
1,1-Dichloroethane [75-34-3]^
0.13
u
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
1,1-Dichloroethene [75-35-4]^
0.21
u
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
u
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
u
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
1,2-Dibromoethane [106-93-4]^
0.66
u
ug/L
1
0.66
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
u
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
1,2-Dichloroethane [107-06-2]^
0.21
u
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
1,2-Dichloropropane [78-87-5]^
0.10
u
ug/L
1
0.10
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
1,4-Dichlorobenzene [106-46-7]^
0.19
u
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
2-Butanone [78-93-3]A
1.3
u
ug/L
1
1.3
5.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
2-Hexanone [591-78-6]A
0.88
u
ug/L
1
0.88
5.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
u
ug/L
1
1.1
5.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Acetone [67-64-1]A
10
u
ug/L
1
10
20
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Acrylonitrile [107-13-1]^
3.5
u
ug/L
1
3.5
10
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Benzene[71-43-2]A
0.15
u
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Bromochloromethane [74-97-5]A
0.48
u
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Bromodichloromethane [75-27-4]^
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Bromoform [75-25-2]^
0.22
u
ug/L
1
0.22
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Bromomethane [74-83-9]A
0.14
u
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY QV-01
Carbon disulfide [75-15-0]A
1.5
u
ug/L
1
1.5
5.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Carbon tetrachloride [56-23-5]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Chlorobenzene[108-90-7]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Chloroethane [75-00-3]A
0.23
u
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY QV-01
Chloroform [67-66-3]^
0.18
u
ug/L
1
0.18
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Chloromethane [74-87-3]A
0.13
u
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
cis-1,2-Dichloroethene [156-59-2]^
0.15
u
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
cis-1,3-Dichloropropene [10061-01-5]A
0.20
u
ug/L
1
0.20
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Dibromochloromethane [124-48-1]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Dibromomethane [74-95-3]A
0.27
u
ug/L
1
0.27
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Ethylbenzene[100-41-4]A
0.13
u
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Iodomethane [74-88-4]^
1.7
u
ug/L
1
1.7
5.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Methylene chloride [75-09-2]A
0.23
u
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Styrene[100-42-5]A
0.11
u
ug/L
1
0.11
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Tetrachloroethene [127-18-4]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Toluene [108-88-3]^
0.14
u
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
u
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
u
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
trans-1,4-Dichloro-2-butene [110-57-6]A
0.70
u
ug/L
1
0.70
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Trichloroethene [79-01-6]^
0.15
u
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Trichlorofluoromethane [75-69-4]^
0.24
u
ug/L
1
0.24
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Vinyl acetate [108-05-4]A
0.95
u
ug/L
1
0.95
5.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Vinyl chloride [75-01-4]^
0.32
u
ug/L
1
0.32
1.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
Xylenes (Total) [1330-20-7]A
0.45
u
ug/L
1
0.45
3.0
2DO4032
EPA 8260D
04/05/22 02:46
RKY
FINAL
This report relates only to the sample as received by the
laboratory,
and may only be reproduced in full.
I Page 74 of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW33R Lab Sample ID:CF03674-03 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 08:51 Work Order: CF03674
Project: Catawba Co Blackburn Facility - Unit 3 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By
Notes
4-Bromofluorobenzene
52
1
50.0
105 %
53-136
2DO4032
EPA 6260D
04105122 02:46
RKY
Dibromofluoromethane
49
1
50.0
98 %
67-129
2DO4032
EPA 6260D
04105122 02:46
RKY
Toluene-d8
55
1
50.0
110 %
59-134
2DO4032
EPA 6260D
04105122 02:46
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
Antimony[7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29005
EPA 6020B
04/04/22 14:24
JDH
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29003
EPA 6010D
04/01/22 13:37
JDH
Barium [7440-39-3]^
65.7
ug/L
1
1.10
10.0
2C29003
EPA 6010D
04/01/22 13:37
JDH
Beryllium [7440-41-7]^
0.160
U
ug/L
1
0.160
1.00
2C29003
EPA 6010D
04/01/22 13:37
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29003
EPA 6010D
04/01/22 13:37
JDH
Chromium [7440-47-3]^
1.66
J
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:37
JDH
Cobalt[7440-48-4]^
2.29
J
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:37
JDH
Copper[7440-50-8]^
1.60
U
ug/L
1
1.60
10.0
2C29003
EPA 6010D
04/01/22 13:37
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29003
EPA 6010D
04/01/22 13:37
JDH
Nickel[7440-02-0]^
2.20
U
ug/L
1
2.20
10.0
2C29003
EPA 6010D
04/01/22 13:37
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29005
EPA 6020B
04/04/22 14:24
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29003
EPA 6010D
04/01/22 13:37
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29005
EPA 6020B
04/04/22 14:24
JDH
Vanadium [7440-62-2]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:37
JDH
Zinc[7440-66-6]^
5.93
J
ug/L
1
4.40
10.0
2C29003
EPA 6010D
04/01/22 13:37
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80
2.0
201031
EPA 8260D
03/31/22 19:15
KKW
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Analyzed
ffly
Notes
Toluene-d8
4.9
1
5.00
98 %
75-125
201031
EPA 8260D
0313112219:15
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 75 Of H

0Nk"q09
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW35 Lab Sample ID:CF03674-04 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 08:35 Work Order: CF03674
Project: Catawba Cc Blackburn Facility - Unit 3 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary rertified analyte [NC 591]
Analyte ICAS Numberl
Results
Flaa
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
1,1,1,2-Tetrachloroethane [630-20-6]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
1,1,1-Trichloroethane [71-55-6]A
0.12
u
ug/L
1
0.12
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
1,1,2,2-Tetrachloroethane [79-34-5]A
0.28
u
ug/L
1
0.28
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
1,1,2-Trichloroethane [79-00-5]A
0.14
u
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
1,1-Dichloroethane [75-34-3]^
0.13
u
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
1,1-Dichloroethene [75-35-4]^
0.21
u
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
u
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
u
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
1,2-Dibromoethane [106-93-4]^
0.66
u
ug/L
1
0.66
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
u
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
1,2-Dichloroethane [107-06-2]^
0.21
u
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
1,2-Dichloropropane [78-87-5]^
0.10
u
ug/L
1
0.10
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
1,4-Dichlorobenzene [106-46-7]^
0.19
u
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
2-Butanone [78-93-3]A
1.3
u
ug/L
1
1.3
5.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
2-Hexanone [591-78-6]A
0.88
u
ug/L
1
0.88
5.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
u
ug/L
1
1.1
5.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Acetone [67-64-1]A
10
u
ug/L
1
10
20
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Acrylonitrile [107-13-1]^
3.5
u
ug/L
1
3.5
10
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Benzene[71-43-2]A
0.15
u
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Bromochloromethane [74-97-5]A
0.48
u
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Bromodichloromethane [75-27-4]^
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Bromoform [75-25-2]^
0.22
u
ug/L
1
0.22
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Bromomethane [74-83-9]A
0.14
u
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY QV-01
Carbon disulfide [75-15-0]A
1.5
u
ug/L
1
1.5
5.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Carbon tetrachloride [56-23-5]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Chlorobenzene[108-90-7]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Chloroethane [75-00-3]A
0.23
u
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY QV-01
Chloroform [67-66-3]^
0.18
u
ug/L
1
0.18
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Chloromethane [74-87-3]A
0.13
u
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
cis-1,2-Dichloroethene [156-59-2]^
0.15
u
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
cis-1,3-Dichloropropene [10061-01-5]A
0.20
u
ug/L
1
0.20
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Dibromochloromethane [124-48-1]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Dibromomethane [74-95-3]A
0.27
u
ug/L
1
0.27
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Ethylbenzene[100-41-4]A
0.13
u
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Iodomethane [74-88-4]^
1.7
u
ug/L
1
1.7
5.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Methylene chloride [75-09-2]A
0.23
u
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Styrene[100-42-5]A
0.11
u
ug/L
1
0.11
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Tetrachloroethene [127-18-4]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Toluene [108-88-3]^
0.14
u
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
u
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
u
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
trans-1,4-Dichloro-2-butene [110-57-6]A
0.70
u
ug/L
1
0.70
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Trichloroethene [79-01-6]^
0.15
u
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Trichlorofluoromethane [75-69-4]^
0.24
u
ug/L
1
0.24
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Vinyl acetate [108-05-4]A
0.95
u
ug/L
1
0.95
5.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Vinyl chloride [75-01-4]^
0.32
u
ug/L
1
0.32
1.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
Xylenes (Total) [1330-20-7]A
0.45
u
ug/L
1
0.45
3.0
2DO4032
EPA 8260D
04/05/22
03:13
RKY
FINAL
This report relates only to the sample as received
by the
laboratory,
and may only be reproduced in full.
I Page 76 Of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW35 Lab Sample ID:CF03674-04 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 08:35 Work Order: CF03674
Project: Catawba Co Blackburn Facility - Unit 3 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By
Notes
4-Bromofluorobenzene
56
1
50.0
112 %
53-136
2DO4032
EPA 8260D
04105122 03:13
RKY
Dibromofluoromethane
50
1
50.0
101 %
67-129
2DO4032
EPA 8260D
04105122 03:13
RKY
Toluene-d8
54
1
50.0
109 %
59-134
2DO4032
EPA 6260D
04105122 03:13
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
Antimony[7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29005
EPA 6020B
04/04/22 14:28
JDH
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29003
EPA 6010D
04/01/22 13:40
JDH
Barium [7440-39-3]^
30.2
ug/L
1
1.10
10.0
2C29003
EPA 6010D
04/01/22 13:40
JDH
Beryllium [7440-41-7]^
0.160
U
ug/L
1
0.160
1.00
2C29003
EPA 6010D
04/01/22 13:40
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29003
EPA 6010D
04/01/22 13:40
JDH
Chromium [7440-47-3]^
3.30
J
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:40
JDH
Cobalt[7440-48-4]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:40
JDH
Copper[7440-50-8]^
1.60
U
ug/L
1
1.60
10.0
2C29003
EPA 6010D
04/01/22 13:40
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29003
EPA 6010D
04/01/22 13:40
JDH
Nickel[7440-02-0]^
2.20
U
ug/L
1
2.20
10.0
2C29003
EPA 6010D
04/01/22 13:40
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29005
EPA 6020B
04/04/22 14:28
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29003
EPA 6010D
04/01/22 13:40
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29005
EPA 6020B
04/04/22 14:28
JDH
Vanadium [7440-62-2]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:40
JDH
Zinc[7440-66-6]^
7.94
J
ug/L
1
4.40
10.0
2C29003
EPA 6010D
04/01/22 13:40
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80
2.0
201031
EPA 8260D
03/31/22 19:40
KKW
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Analyzed
ffly
Notes
Toluene-d8
4.7
1
5.00
93 %
75-125
201031
EPA 8260D
0313112219:40
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 77 Of H

0Nk"q09
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW36 Lab Sample ID:CF03674-05 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 08:45 Work Order: CF03674
Project: Catawba Cc Blackburn Facility - Unit 3 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary rertified analyte [NC 591]
Analyte ICAS Numberl
Results
Flaa
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
1,1,1,2-Tetrachloroethane [630-20-6]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
1,1,1-Trichloroethane [71-55-6]A
0.12
u
ug/L
1
0.12
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
1,1,2,2-Tetrachloroethane [79-34-5]A
0.28
u
ug/L
1
0.28
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
1,1,2-Trichloroethane [79-00-5]A
0.14
u
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
1,1-Dichloroethane [75-34-3]^
0.13
u
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
1,1-Dichloroethene [75-35-4]^
0.21
u
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
1,2,3-Trichloropropane [96-18-4]^
0.23
u
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
1,2-Dibromo-3-chloropropane [96-12-8]^
0.48
u
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
1,2-Dibromoethane [106-93-4]^
0.66
u
ug/L
1
0.66
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
1,2-Dichlorobenzene [95-50-1]^
0.19
u
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
1,2-Dichloroethane [107-06-2]^
0.21
u
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
1,2-Dichloropropane [78-87-5]^
0.10
u
ug/L
1
0.10
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
1,4-Dichlorobenzene [106-46-7]^
0.19
u
ug/L
1
0.19
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
2-Butanone [78-93-3]A
1.3
u
ug/L
1
1.3
5.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
2-Hexanone [591-78-6]A
0.88
u
ug/L
1
0.88
5.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
4-Methyl-2-pentanone [108-10-1]^
1.1
u
ug/L
1
1.1
5.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Acetone [67-64-1]A
10
u
ug/L
1
10
20
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Acrylonitrile [107-13-1]^
3.5
u
ug/L
1
3.5
10
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Benzene[71-43-2]A
0.15
u
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Bromochloromethane [74-97-5]A
0.48
u
ug/L
1
0.48
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Bromodichloromethane [75-27-4]^
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Bromoform [75-25-2]^
0.22
u
ug/L
1
0.22
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Bromomethane [74-83-9]A
0.14
u
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY QV-01
Carbon disulfide [75-15-0]A
1.5
u
ug/L
1
1.5
5.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Carbon tetrachloride [56-23-5]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Chlorobenzene[108-90-7]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Chloroethane [75-00-3]A
0.23
u
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY QV-01
Chloroform [67-66-3]^
0.18
u
ug/L
1
0.18
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Chloromethane [74-87-3]A
0.13
u
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
cis-1,2-Dichloroethene [156-59-2]^
0.15
u
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
cis-1,3-Dichloropropene [10061-01-5]A
0.20
u
ug/L
1
0.20
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Dibromochloromethane [124-48-1]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Dibromomethane [74-95-3]A
0.27
u
ug/L
1
0.27
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Ethylbenzene[100-41-4]A
0.13
u
ug/L
1
0.13
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Iodomethane [74-88-4]^
1.7
u
ug/L
1
1.7
5.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Methylene chloride [75-09-2]A
0.23
u
ug/L
1
0.23
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Styrene[100-42-5]A
0.11
u
ug/L
1
0.11
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Tetrachloroethene [127-18-4]A
0.17
u
ug/L
1
0.17
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Toluene [108-88-3]^
0.14
u
ug/L
1
0.14
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
trans-1,2-Dichloroethene [156-60-5]^
0.21
u
ug/L
1
0.21
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
trans-1,3-Dichloropropene [10061-02-6]^
0.15
u
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
trans-1,4-Dichloro-2-butene [110-57-6]A
0.70
u
ug/L
1
0.70
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Trichloroethene [79-01-6]^
0.15
u
ug/L
1
0.15
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Trichlorofluoromethane [75-69-4]^
0.24
u
ug/L
1
0.24
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Vinyl acetate [108-05-4]A
0.95
u
ug/L
1
0.95
5.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Vinyl chloride [75-01-4]^
0.32
u
ug/L
1
0.32
1.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
Xylenes (Total) [1330-20-7]A
0.45
u
ug/L
1
0.45
3.0
2DO4032
EPA 8260D
04/05/22 03:40
RKY
FINAL
This report relates only to the sample as received by the
laboratory,
and may only be reproduced in full.
I Page 78 Of 118

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: 1803-MW36 Lab Sample ID:CF03674-05 Received: 03/25/22 14:00
Matrix: Ground Water Sampled:03/24/22 08:45 Work Order: CF03674
Project: Catawba Co Blackburn Facility - Unit 3 Sampled By: K.Estes/E.Wright/Grayson
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Ana/vzed
By
Notes
4-Bromofluorobenzene
54
1
50.0
107 %
53-136
2DO4032
EPA 8260D
04105122 03:40
RKY
Dibromofluoromethane
50
1
50.0
100 %
67-129
2DO4032
EPA 8260D
04105122 03:40
RKY
Toluene-d8
58
1
50.0
116 %
59-134
2DO4032
EPA 6260D
04105122 03:40
RKY
Metals (total recoverable) by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
Antimony[7440-36-0]^
0.740
U
ug/L
2
0.740
2.00
2C29005
EPA 6020B
04/04/22 14:32
JDH
Arsenic[7440-38-2]^
7.60
U
ug/L
1
7.60
10.0
2C29003
EPA 6010D
04/01/22 13:42
JDH
Barium [7440-39-3]^
94.0
ug/L
1
1.10
10.0
2C29003
EPA 6010D
04/01/22 13:42
JDH
Beryllium [7440-41-7]^
0.160
U
ug/L
1
0.160
1.00
2C29003
EPA 6010D
04/01/22 13:42
JDH
Cadmium [7440-43-9]^
0.360
U
ug/L
1
0.360
1.00
2C29003
EPA 6010D
04/01/22 13:42
JDH
Chromium [7440-47-3]^
3.00
J
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:42
JDH
Cobalt[7440-48-4]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:42
JDH
Copper[7440-50-8]^
1.60
U
ug/L
1
1.60
10.0
2C29003
EPA 6010D
04/01/22 13:42
JDH
Lead [7439-92-1]^
3.10
U
ug/L
1
3.10
10.0
2C29003
EPA 6010D
04/01/22 13:42
JDH
Nickel[7440-02-0]^
2.20
U
ug/L
1
2.20
10.0
2C29003
EPA 6010D
04/01/22 13:42
JDH
Selenium [7782-49-2]^
1.82
U
ug/L
2
1.82
2.00
2C29005
EPA 6020B
04/04/22 14:32
JDH
Silver [7440-22-4]^
1.90
U
ug/L
1
1.90
10.0
2C29003
EPA 6010D
04/01/22 13:42
JDH
Thallium [7440-28-0]^
0.220
U
ug/L
2
0.220
2.00
2C29005
EPA 6020B
04/04/22 14:32
JDH
Vanadium [7440-62-2]^
1.40
U
ug/L
1
1.40
10.0
2C29003
EPA 6010D
04/01/22 13:42
JDH
Zinc[7440-66-6]^
5.40
J
ug/L
1
4.40
10.0
2C29003
EPA 6010D
04/01/22 13:42
JDH
Volatile Organic Compounds by GCMS SIM Isotope Dilution
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
Ay
Notes
1,4-Dioxane [123-91-1]^
0.80
U
ug/L
1
0.80
2.0
201031
EPA 8260D
03/31/22 20:06
KKW
Surrogates
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
Analyzed
ffly
Notes
Toluene-d8
4.9
1
5.00
98 %
75-125
201031
EPA 8260D
03131122 20:06
KKW
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 79 Of H

(� �Eo
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QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 2DO1018 - EPA 5030B MS
Blank (2D01018-BLK1) Prepared: 04/01/2022 15:00 Analyzed: 04/01/2022 19:51
Analvte
Result
Flaq
POL
Units
1,1,1,2-Tetrachloroethane
0.17
U
1.0
ug/L
1,1,1-Trichloroethane
0.12
U
1.0
ug/L
1,1,2,2-Tetrachloroethane
0.28
U
1.0
ug/L
1,1,2-Trichloroethane
0.14
U
1.0
ug/L
1,1-Dichloroethane
0.13
U
1.0
ug/L
1,1-Dichloroethene
0.21
U
1.0
ug/L
1,2,3-Trichloropropane
0.23
U
1.0
ug/L
1,2-Dibromo-3-chloropropane
0.48
U
1.0
ug/L
1,2-Dibromoethane
0.66
U
1.0
ug/L
1,2-Dichlorobenzene
0.19
U
1.0
ug/L
1,2-Dichloroethane
0.21
U
1.0
ug/L
1,2-Dichloropropane
0.10
U
1.0
ug/L
1,4-Dichlorobenzene
0.19
U
1.0
ug/L
2-Butanone
1.3
U
5.0
ug/L
2-Hexanone
0.88
U
5.0
ug/L
4-Methyl-2-pentanone
1.1
U
5.0
ug/L
Acetone
10
U
20
ug/L
Acrylonitrile
3.5
U
10
ug/L
Benzene
0.15
U
1.0
ug/L
Bromochloromethane
0.48
U
1.0
ug/L
Bromodichloromethane
0.17
U
1.0
ug/L
Bromoform
0.22
U
1.0
ug/L
Bromomethane
0.14
U
1.0
ug/L
Carbon disulfide
1.5
U
5.0
ug/L
Carbon tetrachloride
0.17
U
1.0
ug/L
Chlorobenzene
0.17
U
1.0
ug/L
Chloroethane
0.23
U
1.0
ug/L
Chloroform
0.18
U
1.0
ug/L
Chloromethane
0.13
U
1.0
ug/L
cis- 1,2-Dichloroethene
0.15
U
1.0
ug/L
cis- 1,3-Dichloropropene
0.20
U
1.0
ug/L
Dibromochloromethane
0.17
U
1.0
ug/L
Dibromomethane
0.27
U
1.0
ug/L
Dichlorodifluoromethane
0.20
U
1.0
ug/L
Ethylbenzene
0.13
U
1.0
ug/L
Iodomethane
1.7
U
5.0
ug/L
Methylene chloride
0.23
U
1.0
ug/L
Styrene
0.11
U
1.0
ug/L
Tetrachloroethene
0.17
U
1.0
ug/L
Tetrahydrofuran
0.53
U
1.0
ug/L
Toluene
0.14
U
1.0
ug/L
trans-1,2-Dichloroethene
0.21
U
1.0
ug/L
trans-1,3-Dichloropropene
0.15
U
1.0
ug/L
trans-1,4-Dichloro-2-butene
0.70
U
1.0
ug/L
Trichloroethene
0.15
U
1.0
ug/L
Trichlorofluoromethane
0.24
U
1.0
ug/L
Vinyl acetate
0.95
U
5.0
ug/L
Vinyl chloride
0.32
U
1.0
ug/L
Xylenes (Total)
0.45
U
3.0
ug/L
Spike Source %REC
Level Result %REC Limits
RPD
RPD Limit Notes
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 80Of 118

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QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 2DO1018 - EPA 5030B MS - Continued
Blank (2D01018-BLK1) Continued Prepared: 04/01/2022 15:00 Analyzed: 04/01/2022 19:51
Spike Source %REC RPD
Analvte
Result Flaq POL
Units
Level Result %REC Limits RPD Limit Notes
4-Bromofluorobenzene
56
u91L
50.0 112 53-136
Dibromofluoromethane
49
u91L
50.0 99 67-129
Toluene-d8
56
u91L
50.0 113 59-134
LCS (2D01018-BSI)
Prepared: 04/01/2022 15:00 Analyzed: 04/01/2022 18:00
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits RPD
Limit Notes
1,1-Dichloroethene
22
1.0
ug/L
20.0
108
75-133
Benzene
21
1.0
ug/L
20.0
105
80-134
Chlorobenzene
21
1.0
ug/L
20.0
105
80-120
Toluene
20
1.0
ug/L
20.0
101
71-120
Trichloroethene
20
1.0
ug/L
20.0
102
74-120
4-Bromofluorobenzene
57
u91L
50.0
113
53-136
Dibromofluoromethane
49
u91L
50.0
98
67-129
Toluene-d8
56
u91L
50.0
113
59-134
Matrix Spike (2D03018-MS1)
Prepared: 04/01/2022 15:00 Analyzed: 04/01/2022 18:28
Source: CF04469-11
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits RPD
Limit Notes
1,1-Dichloroethene
24
1.0
ug/L
20.0
0.21 U
118
75-133
Benzene
21
1.0
ug/L
20.0
0.15 U
106
80-134
Chlorobenzene
20
1.0
ug/L
20.0
0.17 U
102
80-120
Toluene
21
1.0
ug/L
20.0
0.14 U
105
71-120
Trichloroethene
19
1.0
ug/L
20.0
0.15 U
95
74-120
4-Bromofluorobenzene
55
u91L
50.0
110
53-136
Dibromofluoromethane
50
u91L
50.0
100
67-129
Toluene-d8
55
u91L
50.0
109
59-134
Matrix Spike Dup (21303018-MSD1)
Prepared: 04/01/2022 15:00 Analyzed: 04/01/2022 18:56
Source: CF04469-11
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits
RPD
Limit Notes
1,1-Dichloroethene
21
1.0
ug/L
20.0
0.21 U
106
75-133
10
20
Benzene
21
1.0
ug/L
20.0
0.15 U
103
80-134
3
17
Chlorobenzene
20
1.0
ug/L
20.0
0.17 U
100
80-120
2
16
Toluene
20
1.0
ug/L
20.0
0.14 U
102
71-120
3
17
Trichloroethene
19
1.0
ug/L
20.0
0.15 U
97
74-120
2
22
4-Bromofluorobenzene 56 u91L 50.0 113 53-136
Dibromofluoromethane 50 u91L 50.0 99 67-129
Toluene-d8 56 u91L 50.0 111 59-134
Batch 2DO1019 - EPA 5030B MS
Blank (2D01019-BLK3) Prepared: 04/01/2022 15:09 Analyzed: 04/02/2022 08:39
Spike Source %REC RPD
Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes
1,1,1,2-Tetrachloroethane 0.17 U 1.0 ug/L
1,1,1-Trichloroethane 0.12 U 1.0 ug/L
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 81 Of 118

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QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 2DO1019 - EPA 5030B MS - Continued
Blank (2D01019-BLK1) Continued Prepared: 04/01/2022 15:09 Analyzed: 04/02/2022 08:39
Analvte
Result
Flaq
POL
Units
1,1,2,2-Tetrachloroethane
0.28
U
1.0
ug/L
1,1,2-Trichloroethane
0.14
U
1.0
ug/L
1,1-Dichloroethane
0.13
U
1.0
ug/L
1,1-Dichloroethene
0.21
U
1.0
ug/L
1,2,3-Trichloropropane
0.23
U
1.0
ug/L
1,2-Dibromo-3-chloropropane
0.48
U
1.0
ug/L
1,2-Dibromoethane
0.66
U
1.0
ug/L
1,2-Dichlorobenzene
0.19
U
1.0
ug/L
1,2-Dichloroethane
0.21
U
1.0
ug/L
1,2-Dichloropropane
0.10
U
1.0
ug/L
1,4-Dichlorobenzene
0.19
U
1.0
ug/L
2-Butanone
1.3
U
5.0
ug/L
2-Hexanone
0.88
U
5.0
ug/L
4-Methyl-2-pentanone
1.1
U
5.0
ug/L
Acetone
10
U
20
ug/L
Acrylonitrile
3.5
U
10
ug/L
Benzene
0.15
U
1.0
ug/L
Bromochloromethane
0.48
U
1.0
ug/L
Bromodichloromethane
0.17
U
1.0
ug/L
Bromoform
0.22
U
1.0
ug/L
Bromomethane
0.14
U
1.0
ug/L
Carbon disulfide
1.5
U
5.0
ug/L
Carbon tetrachloride
0.17
U
1.0
ug/L
Chlorobenzene
0.17
U
1.0
ug/L
Chloroethane
0.23
U
1.0
ug/L
Chloroform
0.18
U
1.0
ug/L
Chloromethane
0.13
U
1.0
ug/L
cis- 1,2-Dichloroethene
0.15
U
1.0
ug/L
cis- 1,3-Dichloropropene
0.20
U
1.0
ug/L
Dibromochloromethane
0.17
U
1.0
ug/L
Dibromomethane
0.27
U
1.0
ug/L
Dichlorodifluoromethane
0.20
U
1.0
ug/L
Ethylbenzene
0.13
U
1.0
ug/L
Iodomethane
1.7
U
5.0
ug/L
Methylene chloride
0.23
U
1.0
ug/L
Styrene
0.11
U
1.0
ug/L
Tetrachloroethene
0.17
U
1.0
ug/L
Tetrahydrofuran
0.53
U
1.0
ug/L
Toluene
0.14
U
1.0
ug/L
trans-1,2-Dichloroethene
0.21
U
1.0
ug/L
trans-1,3-Dichloropropene
0.15
U
1.0
ug/L
trans-1,4-Dichloro-2-butene
0.70
U
1.0
ug/L
Trichloroethene
0.15
U
1.0
ug/L
Trichlorofluoromethane
0.24
U
1.0
ug/L
Vinyl acetate
0.95
U
5.0
ug/L
Vinyl chloride
0.32
U
1.0
ug/L
Xylenes (Total)
0.45
U
3.0
ug/L
Spike Source %REC
Level Result %REC Limits
RPD
RPD Limit Notes
4-Bromofluorobenzene 55 u91L 50.0 109 53-136
Dibromofluoromethane 46 u91L 50.0 92 67-129
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full.
Page 82 of 118

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QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 2DO1019 - EPA 5030B MS - Continued
Blank (2D01019-BLK1) Continued Prepared: 04/01/2022 15:09 Analyzed: 04/02/2022 08:39
Spike Source %REC RPD
Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes
Toluene-d8 56 u91L 50.0 113 59-134
LCS (21303019-BS1) Prepared: 04/01/2022 15:09 Analyzed: 04/02/2022 06:49
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits RPD
Limit Notes
1,1-Dichloroethene
21
1.0
ug/L
20.0
105
75-133
Benzene
20
1.0
ug/L
20.0
102
80-134
Chlorobenzene
19
1.0
ug/L
20.0
94
80-120
Toluene
20
1.0
ug/L
20.0
100
71-120
Trichloroethene
18
1.0
ug/L
20.0
92
74-120
4-Bromofluorobenzene
56
ug/L
50.0
112
53-136
Dibromofluoromethane
50
ug/L
50.0
100
67-129
Toluene-d8
58
ug/L
50.0
115
59-134
Matrix Spike (21303019-MS1)
Prepared: 04/01/2022 15:09 Analyzed: 04/02/2022 07:17
Source: CF04469-03
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits RPD
Limit Notes
1,1-Dichloroethene
23
1.0
ug/L
20.0
0.21 U
116
75-133
Benzene
22
1.0
ug/L
20.0
0.15 U
110
80-134
Chlorobenzene
20
1.0
ug/L
20.0
0.17 U
102
80-120
Toluene
21
1.0
ug/L
20.0
0.14 U
106
71-120
Trichloroethene
20
1.0
ug/L
20.0
0.15 U
102
74-120
4-Bromofluorobenzene
56
ug/L
50.0
111
53-136
Dibromofluoromethane
48
ug/L
50.0
96
67-129
Toluene-d8
56
u91L
50.0
111
59-134
Matrix Spike Dup (21303019-MS131)
Prepared: 04/01/2022 15:09 Analyzed: 04/02/2022 07:44
Source: CF04469-03
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits
RPD
Limit Notes
1,1-Dichloroethene
21
1.0
ug/L
20.0
0.21 U
105
75-133
9
20
Benzene
19
1.0
ug/L
20.0
0.15 U
97
80-134
13
17
Chlorobenzene
19
1.0
ug/L
20.0
0.17 U
97
80-120
5
16
Toluene
19
1.0
ug/L
20.0
0.14 U
97
71-120
9
17
Trichloroethene
19
1.0
ug/L
20.0
0.15 U
93
74-120
9
22
4-Bromofluorobenzene 57 u91L 50.0 114 53-136
Dibromofluoromethane 50 u91L 50.0 100 67-129
Toluene-& 56 u91L 50.0 113 59-134
Batch 2DO1023 - EPA 5030B MS
Blank (2D01023-BLK3) Prepared: 04/01/2022 19:44 Analyzed: 04/02/2022 20:40
Spike Source %REC
Analvte
Result
Flaq
POL
Units Level Result %REC Limits
1,1,1,2-Tetrachloroethane
0.17
U
1.0
ug/L
1,1,1-Trichloroethane
0.12
U
1.0
ug/L
1,1,2,2-Tetrachloroethane
0.28
U
1.0
ug/L
1,1,2-Trichloroethane
0.14
U
1.0
ug/L
RPD
RPD Limit Notes
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full
Page 83 of 118

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QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 2DO1023 - EPA 5030B MS - Continued
Blank (2D01023-BLK1) Continued Prepared: 04/01/2022 19:44 Analyzed: 04/02/2022 20:40
Analvte
Result
Flaq
POL
Units
1,1-Dichloroethane
0.13
U
1.0
ug/L
1,1-Dichloroethene
0.21
U
1.0
ug/L
1,2,3-Trichloropropane
0.23
U
1.0
ug/L
1,2-Dibromo-3-chloropropane
0.48
U
1.0
ug/L
1,2-Dibromoethane
0.66
U
1.0
ug/L
1,2-Dichlorobenzene
0.19
U
1.0
ug/L
1,2-Dichloroethane
0.21
U
1.0
ug/L
1,2-Dichloropropane
0.10
U
1.0
ug/L
1,4-Dichlorobenzene
0.19
U
1.0
ug/L
2-Butanone
1.3
U
5.0
ug/L
2-Hexanone
0.88
U
5.0
ug/L
4-Methyl-2-pentanone
1.1
U
5.0
ug/L
Acetone
10
U
20
ug/L
Acrylonitrile
3.5
U
10
ug/L
Benzene
0.15
U
1.0
ug/L
Bromochloromethane
0.48
U
1.0
ug/L
Bromodichloromethane
0.17
U
1.0
ug/L
Bromoform
0.22
U
1.0
ug/L
Bromomethane
0.14
U
1.0
ug/L
Carbon disulfide
1.5
U
5.0
ug/L
Carbon tetrachloride
0.17
U
1.0
ug/L
Chlorobenzene
0.17
U
1.0
ug/L
Chloroethane
0.23
U
1.0
ug/L
Chloroform
0.18
U
1.0
ug/L
Chloromethane
0.13
U
1.0
ug/L
cis- 1,2-Dichloroethene
0.15
U
1.0
ug/L
cis- 1,3-Dichloropropene
0.20
U
1.0
ug/L
Dibromochloromethane
0.17
U
1.0
ug/L
Dibromomethane
0.27
U
1.0
ug/L
Dichlorodifluoromethane
0.20
U
1.0
ug/L
Ethylbenzene
0.13
U
1.0
ug/L
Iodomethane
1.7
U
5.0
ug/L
Methylene chloride
0.23
U
1.0
ug/L
Styrene
0.11
U
1.0
ug/L
Tetrachloroethene
0.17
U
1.0
ug/L
Tetrahydrofuran
0.53
U
1.0
ug/L
Toluene
0.14
U
1.0
ug/L
trans-1,2-Dichloroethene
0.21
U
1.0
ug/L
trans-1,3-Dichloropropene
0.15
U
1.0
ug/L
trans-1,4-Dichloro-2-butene
0.70
U
1.0
ug/L
Trichloroethene
0.15
U
1.0
ug/L
Trichlorofluoromethane
0.24
U
1.0
ug/L
Vinyl acetate
0.95
U
5.0
ug/L
Vinyl chloride
0.32
U
1.0
ug/L
Xylenes (Total)
0.45
U
3.0
ug/L
Spike Source %REC RPD
Level Result %REC Limits RPD Limit Notes
4-Bromofluorobenzene 55 u91L 50.0 109 53-136
Dibromofluoromethane 49 ug/L 50.0 99 67-129
Toluene-d8 56 ug/L 50.0 112 59-134
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 84 Of 118

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QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 2DO1023 - EPA 5030B MS - Continued
LCS (2D01023-BSI) Prepared: 04/01/2022 19:44 Analyzed: 04/02/2022 18:50
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits RPD
Limit Notes
1,1-Dichloroethene
21
1.0
ug/L
20.0
105
75-133
Benzene
21
1.0
ug/L
20.0
103
80-134
Chlorobenzene
20
1.0
ug/L
20.0
101
80-120
Toluene
20
1.0
ug/L
20.0
99
71-120
Trichloroethene
20
1.0
ug/L
20.0
98
74-120
4-Bromofluorobenzene
57
u91L
50.0
115
53-136
Dibromofluoromethane
51
u91L
50.0
103
67-129
Toluene-d8
57
u91L
50.0
114
59-134
Matrix Spike (2D03023-MS1)
Prepared: 04/01/2022 19:44 Analyzed: 04/02/2022 19:17
Source: CF04469-04
Spike
Source
%REC
RPD
Analvte
Result Flaq
Q
Units
Level
Result
%REC
Limits RPD
Limit Notes
1,1-Dichloroethene
22
1.0
ug/L
20.0
0.21 U
109
75-133
Benzene
21
1.0
ug/L
20.0
0.15 U
103
80-134
Chlorobenzene
19
1.0
ug/L
20.0
0.17 U
96
80-120
Toluene
19
1.0
ug/L
20.0
0.14 U
96
71-120
Trichloroethene
18
1.0
ug/L
20.0
0.15 U
91
74-120
4-Bromofluorobenzene
55
u91L
50.0
110
53-136
Dibromofluoromethane
52
u91L
50.0
104
67-129
Toluene-d8
57
u91L
50.0
114
59-134
Matrix Spike Dup (2D03023-MSD1)
Prepared: 04/01/2022 19:44 Analyzed: 04/02/2022 19:45
Source: CF04469-04
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits
RPD
Limit Notes
1,1-Dichloroethene
23
1.0
ug/L
20.0
0.21 U
113
75-133
4
20
Benzene
21
1.0
ug/L
20.0
0.15 U
107
80-134
4
17
Chlorobenzene
21
1.0
ug/L
20.0
0.17 U
106
80-120
10
16
Toluene
21
1.0
ug/L
20.0
0.14 U
104
71-120
8
17
Trichloroethene
21
1.0
ug/L
20.0
0.15 U
103
74-120
13
22
4-Bromofluorobenzene 56 u91L 50.0 113 53-136
Dibromofluoromethane 52 u91L 50.0 105 67-129
Toluene-d8 57 u91L 50.0 115 59-134
Batch 2DO4032 - EPA 5030B MS
Blank (2D04032-BLK3) Prepared: 04/04/2022 16:00 Analyzed: 04/04/2022 19:26
Spike Source %REC
Analvte
Result
Flaq
POL
Units Level Result %REC Limits
1,1,1,2-Tetrachloroethane
0.17
U
1.0
ug/L
1,1,1-Trichloroethane
0.12
U
1.0
ug/L
1,1,2,2-Tetrachloroethane
0.28
U
1.0
ug/L
1,1,2-Trichloroethane
0.14
U
1.0
ug/L
1,1-Dichloroethane
0.13
U
1.0
ug/L
1,1-Dichloroethene
0.21
U
1.0
ug/L
1,2,3-Trichloropropane
0.23
U
1.0
ug/L
1,2-Dibromo-3-chloropropane
0.48
U
1.0
ug/L
1,2-Dibromoethane
0.66
U
1.0
ug/L
1,2-Dichlorobenzene
0.19
U
1.0
ug/L
FINAL
This report relates only to
the sample as received by the laboratory, and may only be reproduced in full.
RPD
RPD Limit Notes
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QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 2DO4032 - EPA 5030B MS - Continued
Blank (2D04032-BLK1) Continued Prepared: 04/04/2022 16:00 Analyzed: 04/04/2022 19:26
Spike
Source
%REC
RPD
Analvte
Result
Flaq
POL
Units
Level
Result
%REC
Limits RPD
Limit Notes
1,2-Dichloroethane
0.21
U
1.0
ug/L
1,2-Dichloropropane
0.10
U
1.0
ug/L
1,4-Dichlorobenzene
0.19
U
1.0
ug/L
2-Butanone
1.3
U
5.0
ug/L
2-Hexanone
0.88
U
5.0
ug/L
4-Methyl-2-pentanone
1.1
U
5.0
ug/L
Acetone
10
U
20
ug/L
Acrylonitrile
3.5
U
10
ug/L
Benzene
0.15
U
1.0
ug/L
Bromochloromethane
0.48
U
1.0
ug/L
Bromodichloromethane
0.17
U
1.0
ug/L
Bromoform
0.22
U
1.0
ug/L
Bromomethane
0.14
U
1.0
ug/L
Carbon disulfide
1.5
U
5.0
ug/L
Carbon tetrachloride
0.17
U
1.0
ug/L
Chlorobenzene
0.17
U
1.0
ug/L
Chloroethane
0.23
U
1.0
ug/L
Chloroform
0.18
U
1.0
ug/L
Chloromethane
0.13
U
1.0
ug/L
cis- 1,2-Dichloroethene
0.15
U
1.0
ug/L
cis- 1,3-Dichloropropene
0.20
U
1.0
ug/L
Dibromochloromethane
0.17
U
1.0
ug/L
Dibromomethane
0.27
U
1.0
ug/L
Dichlorodifluoromethane
0.20
U
1.0
ug/L
Ethylbenzene
0.13
U
1.0
ug/L
Iodomethane
1.7
U
5.0
ug/L
Methylene chloride
0.23
U
1.0
ug/L
Styrene
0.11
U
1.0
ug/L
Tetrachloroethene
0.17
U
1.0
ug/L
Tetrahydrofuran
0.53
U
1.0
ug/L
Toluene
0.14
U
1.0
ug/L
trans-1,2-Dichloroethene
0.21
U
1.0
ug/L
trans-1,3-Dichloropropene
0.15
U
1.0
ug/L
trans-1,4-Dichloro-2-butene
0.70
U
1.0
ug/L
Trichloroethene
0.15
U
1.0
ug/L
Trichlorofluoromethane
0.24
U
1.0
ug/L
Vinyl acetate
0.95
U
5.0
ug/L
Vinyl chloride
0.32
U
1.0
ug/L
Xylenes (Total)
0.45
U
3.0
ug/L
4-Bromofluorobenzene
53
ug/L
50.0
106
53-136
Dibromofluoromethane
50
ug/L
50.0
100
67-129
Toluene-d8
55
ug/L
50.0
110
59-134
LCS (21304032-BSI)
Prepared: 04/04/2022 16:00 Analyzed: 04/04/2022 17:35
Spike
Source
%REC
RPD
Analvte
Result
Flaq
POL
Units
Level
Result
%REC
Limits RPD
Limit Notes
1,1-Dichloroethene
22
1.0
ug/L
20.0
109
75-133
Benzene
20
1.0
ug/L
20.0
100
80-134
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 86 Of 118

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QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 2DO4032 - EPA 5030B MS - Continued
LCS (2D04032-BSI) Continued Prepared: 04/04/2022 16:00 Analyzed: 04/04/2022 17:35
Spike Source %REC RPD
Analvte
Result Flaq
POL
Units
Level Result %REC Limits RPD Limit Notes
Chlorobenzene
19
1.0
ug/L
20.0 97 80-120
Toluene
19
1.0
ug/L
20.0 95 71-120
Trichloroethene
19
1.0
ug/L
20.0 95 74-120
4-Bromofluorobenzene
52
ug/L
50.0 104 53-136
Dibromofluoromethane
46
u9/L
50.0 96 67-129
Toluene-d8
57
ug/L
50.0 113 59-134
Matrix Spike (2D04032-MS1)
Prepared: 04/04/2022 16:00 Analyzed: 04/04/2022 18:03
Source: CF04469-05
Spike
Source
%REC RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits RPD Limit Notes
1,1-Dichloroethene
22
1.0
ug/L
20.0
0.21 U
109
75-133
Benzene
21
1.0
ug/L
20.0
0.15 U
106
80-134
Chlorobenzene
21
1.0
ug/L
20.0
0.17 U
104
80-120
Toluene
20
1.0
ug/L
20.0
0.14 U
102
71-120
Trichloroethene
19
1.0
ug/L
20.0
0.15 U
93
74-120
4-Bromofluorobenzene
56
ug/L
50.0
111
53-136
Dibromofluoromethane
51
ug/L
50.0
102
67-129
Toluene-d8
55
u9/L
50.0
111
59-134
Matrix Spike Dup (21304032-MS131)
Prepared: 04/04/2022 16:00 Analyzed: 04/04/2022 18:31
Source: CF04469-05
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits
RPD
Limit Notes
1,1-Dichloroethene
23
1.0
ug/L
20.0
0.21 U
113
75-133
4
20
Benzene
20
1.0
ug/L
20.0
0.15 U
98
80-134
8
17
Chlorobenzene
20
1.0
ug/L
20.0
0.17 U
98
80-120
6
16
Toluene
19
1.0
ug/L
20.0
0.14 U
96
71-120
6
17
Trichloroethene
19
1.0
ug/L
20.0
0.15 U
94
74-120
0.8
22
4-Bromofluorobenzene 55 u9/L 50.0 109 53-136
Dibromofluoromethane 51 u9/L 50.0 101 67-129
Toluene-d8 54 ug/L 50.0 109 59-134
Batch 2DO4035 - EPA 5030B MS
Blank (2D04035-BLK3) Prepared: 04/04/2022 20:25 Analyzed: 04/05/2022 07:48
Analvte
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1, 2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dich loroethane
1,1-Dichloroethene
1, 2, 3-Trich I o rop ropa ne
1,2-Di bromo-3-ch loropropane
1,2-Dibromoethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
FINAL
Spike Source %REC
Result
Flaq
POL
Units Level Result %REC Limits
0.17
U
1.0
ug/L
0.12
U
1.0
ug/L
0.28
U
1.0
ug/L
0.14
U
1.0
ug/L
0.13
U
1.0
ug/L
0.21
U
1.0
ug/L
0.23
U
1.0
ug/L
0.48
U
1.0
ug/L
0.66
U
1.0
ug/L
0.19
U
1.0
ug/L
0.21
U
1.0
ug/L
0.10
U
1.0
ug/L
This report relates only to
the sample as received by the laboratory, and may only be reproduced in full.
RPD
RPD Limit Notes
Page 87 of 118

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QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 2DO4035 - EPA 5030B MS - Continued
Blank (2D04035-BLK1) Continued Prepared: 04/04/2022 20:25 Analyzed: 04/05/2022 07:48
Analvte
Result
Flaq
POL
Units
1,4-Dichlorobenzene
0.19
U
1.0
ug/L
2-Butanone
1.3
U
5.0
ug/L
2-Hexanone
0.88
U
5.0
ug/L
4-Methyl-2-pentanone
1.1
U
5.0
ug/L
Acetone
10
U
20
ug/L
Acrylonitrile
3.5
U
10
ug/L
Benzene
0.15
U
1.0
ug/L
Bromochloromethane
0.48
U
1.0
ug/L
Bromodichloromethane
0.17
U
1.0
ug/L
Bromoform
0.22
U
1.0
ug/L
Bromomethane
0.14
U
1.0
ug/L
Carbon disulfide
1.5
U
5.0
ug/L
Carbon tetrachloride
0.17
U
1.0
ug/L
Chlorobenzene
0.17
U
1.0
ug/L
Chloroethane
0.23
U
1.0
ug/L
Chloroform
0.18
U
1.0
ug/L
Chloromethane
0.13
U
1.0
ug/L
cis- 1,2-Dichloroethene
0.15
U
1.0
ug/L
cis- 1,3-Dichloropropene
0.20
U
1.0
ug/L
Dibromochloromethane
0.17
U
1.0
ug/L
Dibromomethane
0.27
U
1.0
ug/L
Dichlorodifluoromethane
0.20
U
1.0
ug/L
Ethylbenzene
0.13
U
1.0
ug/L
Iodomethane
1.7
U
5.0
ug/L
Methylene chloride
0.23
U
1.0
ug/L
Styrene
0.11
U
1.0
ug/L
Tetrachloroethene
0.17
U
1.0
ug/L
Tetrahydrofuran
0.53
U
1.0
ug/L
Toluene
0.14
U
1.0
ug/L
trans-1,2-Dichloroethene
0.21
U
1.0
ug/L
trans-1,3-Dichloropropene
0.15
U
1.0
ug/L
trans-1,4-Dichloro-2-butene
0.70
U
1.0
ug/L
Trichloroethene
0.15
U
1.0
ug/L
Trichlorofluoromethane
0.24
U
1.0
ug/L
Vinyl acetate
0.95
U
5.0
ug/L
Vinyl chloride
0.32
U
1.0
ug/L
Xylenes (Total)
0.45
U
3.0
ug/L
Spike Source %REC RPD
Level Result %REC Limits RPD Limit Notes
4-Bromofluorobenzene 55
u91L
50.0 110 53-136
Dibromofluoromethane 50
u91L
50.0 100 67-129
Toluene-d8 55
u91L
50.0 109 59-134
LCS (21304035-BSI)
Prepared: 04/04/2022 20:25 Analyzed: 04/05/2022 05:58
Spike
Source
%REC RPD
Analvte
Result Flaq
POL
Units
Level
Result %REC
Limits RPD Limit Notes
1,1-Dichloroethene
21
1.0
ug/L
20.0
104
75-133
Benzene
20
1.0
ug/L
20.0
100
80-134
Chlorobenzene
19
1.0
ug/L
20.0
97
80-120
Toluene
18
1.0
ug/L
20.0
92
71-120
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 88 Of 118

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QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 2DO4035 - EPA 5030B MS - Continued
LCS (2D04035-BSI) Continued Prepared: 04/04/2022 20:25 Analyzed: 04/05/2022 05:58
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits RPD
Limit Notes
Trichloroethene
18
1.0
ug/L
20.0
92
74-120
4-Bromofluorobenzene
55
u91L
50.0
110
53-136
Dibromofluoromethane
51
u91L
50.0
103
67-129
Toluene-d8
56
u91L
50.0
112
59-134
Matrix Spike (21304035-MS1)
Prepared: 04/04/2022 20:25 Analyzed: 04/05/2022 06:26
Source: CF04469-06
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits RPD
Limit Notes
1,1-Dichloroethene
23
1.0
ug/L
20.0
0.21 U
113
75-133
Benzene
20
1.0
ug/L
20.0
0.15 U
102
80-134
Chlorobenzene
19
1.0
ug/L
20.0
0.17 U
96
80-120
Toluene
20
1.0
ug/L
20.0
0.14 U
99
71-120
Trichloroethene
19
1.0
ug/L
20.0
0.15 U
94
74-120
4-Bromofluorobenzene
51
u91L
50.0
102
53-136
Dibromofluoromethane
53
u91L
50.0
106
67-129
Toluene-d8
56
u91L
50.0
112
59-134
Matrix Spike Dup (21304035-MS131)
Prepared: 04/04/2022 20:25 Analyzed: 04/05/2022 06:53
Source: CF04469-06
Spike
Source
%REC
RPD
Analvte
Result Flaa
Q
Units
Level
Result
%REC
Limits
RPD
Limit Notes
1,1-Dichloroethene
23
1.0
ug/L
20.0
0.21 U
113
75-133
0.3
20
Benzene
21
1.0
ug/L
20.0
0.15 U
104
80-134
2
17
Chlorobenzene
19
1.0
ug/L
20.0
0.17 U
97
80-120
0.9
16
Toluene
20
1.0
ug/L
20.0
0.14 U
101
71-120
2
17
Trichloroethene
19
1.0
ug/L
20.0
0.15 U
96
74-120
2
22
4-Bromofluorobenzene 53 u91L 50.0 106 53-136
Dibromofluoromethane 51 u91L 50.0 102 67-129
Toluene-d8 55 u91L 50.0 109 59-134
Batch 2DO7015 - EPA 5030E MS
Blank (2D07015-BLK1) Prepared: 04/07/2022 12:49 Analyzed: 04/07/2022 18:12
Analvte
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2,3-Trichloropropane
1,2-Di bromo-3-ch loropropane
1,2-Dibromoethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,4-Dichlorobenzene
2-Butanone
FINAL
Spike Source %REC
Result
Flaci
POL
Units Level Result %REC Limits
0.17
U
1.0
ug/L
0.12
U
1.0
ug/L
0.28
U
1.0
ug/L
0.14
U
1.0
ug/L
0.13
U
1.0
ug/L
0.21
U
1.0
ug/L
0.23
U
1.0
ug/L
0.48
U
1.0
ug/L
0.66
U
1.0
ug/L
0.19
U
1.0
ug/L
0.21
U
1.0
ug/L
0.10
U
1.0
ug/L
0.19
U
1.0
ug/L
1.3
U
5.0
ug/L
This report relates only to
the sample as received by the laboratory, and may only be reproduced in full.
RPD
RPD Limit Notes
Page 89 of 118

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QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 2DO7015 - EPA 5030B MS - Continued
Blank (2D07015-BLK1) Continued Prepared: 04/07/2022 12:49 Analyzed: 04/07/2022 18:12
Spike
Source
%REC
RPD
Analvte
Result
Flaq
POL
Units
Level
Result
%REC
Limits RPD
Limit Notes
2-Hexanone
0.88
U
5.0
ug/L
4-Methyl-2-pentanone
1.1
U
5.0
ug/L
Acetone
10
U
20
ug/L
Acrylonitrile
3.5
U
10
ug/L
Benzene
0.15
U
1.0
ug/L
Bromochloromethane
0.48
U
1.0
ug/L
Bromodichloromethane
0.17
U
1.0
ug/L
Bromoform
0.22
U
1.0
ug/L
Bromomethane
0.14
U
1.0
ug/L
Carbon disulfide
1.5
U
5.0
ug/L
Carbon tetrachloride
0.17
U
1.0
ug/L
Chlorobenzene
0.17
U
1.0
ug/L
Chloroethane
0.23
U
1.0
ug/L
Chloroform
0.18
U
1.0
ug/L
Chloromethane
0.13
U
1.0
ug/L
cis- 1,2-Dichloroethene
0.15
U
1.0
ug/L
cis- 1,3-Dichloropropene
0.20
U
1.0
ug/L
Dibromochloromethane
0.17
U
1.0
ug/L
Dibromomethane
0.27
U
1.0
ug/L
Ethylbenzene
0.13
U
1.0
ug/L
Iodomethane
1.7
U
5.0
ug/L
Methylene chloride
0.23
U
1.0
ug/L
Styrene
0.11
U
1.0
ug/L
Tetrachloroethene
0.17
U
1.0
ug/L
Toluene
0.14
U
1.0
ug/L
trans-1,2-Dichloroethene
0.21
U
1.0
ug/L
trans-1,3-Dichloropropene
0.15
U
1.0
ug/L
trans-1,4-Dichloro-2-butene
0.70
U
1.0
ug/L
Trichloroethene
0.15
U
1.0
ug/L
Trichlorofluoromethane
0.24
U
1.0
ug/L
Vinyl acetate
0.95
U
5.0
ug/L
Vinyl chloride
0.32
U
1.0
ug/L
Xylenes (Total)
0.45
U
3.0
ug/L
4-Bromofluorobenzene
45
u91L
50.0
91
53-136
Dibromofluoromethane
44
u91L
50.0
88
67-129
Toluene-d8
50
u91L
50.0
101
59-134
LCS (2D07015-BSI)
Prepared: 04/07/2022 12:49 Analyzed: 04/07/2022 16:20
Spike
Source
%REC
RPD
Analvte
Result
Flaq
POL
Units
Level
Result
%REC
Limits RPD
Limit Notes
1,1-Dichloroethene
17
1.0
ug/L
20.0
87
75-133
Benzene
18
1.0
ug/L
20.0
90
80-134
Chlorobenzene
20
1.0
ug/L
20.0
99
80-120
Toluene
20
1.0
ug/L
20.0
98
71-120
Trichloroethene
17
1.0
ug/L
20.0
84
74-120
4-Bromofluorobenzene
49
u91L
50.0
97
53-136
Dibromofluoromethane
45
u91L
50.0
90
67-129
Toluene-d8
49
u91L
50.0
97
59-134
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 90of 118

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QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 2D07015 - EPA 5030B MS - Continued
Matrix Spike (2D07015-MS1) Prepared: 04/07/2022 12:49 Analyzed: 04/07/2022 16:48
Source: CF04800-03
Spike
Source
%REC RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits RPD Limit Notes
1,1-Dichloroethene
19
1.0
ug/L
20.0
0.21 U
96
75-133
Benzene
18
1.0
ug/L
20.0
0.15 U
91
80-134
Chlorobenzene
20
1.0
ug/L
20.0
0.17 U
100
80-120
Toluene
20
1.0
ug/L
20.0
0.14 U
100
71-120
Trichloroethene
17
1.0
ug/L
20.0
0.15 U
86
74-120
4-Bromofluorobenzene
46
u91L
50.0
91
53-136
Dibromofluoromethane
47
u91L
50.0
94
67-129
Toluene-d8
48
u91L
50.0
97
59-134
Matrix Spike Dup (21307015-MS131)
Prepared: 04/07/2022 12:49 Analyzed: 04/07/2022 17:16
Source: CF04800-03
Spike
Source
%REC
RPD
Analvte
Result Flaq
Q
Units
Level
Result
%REC
Limits
RPD
Limit Notes
1,1-Dichloroethene
18
1.0
ug/L
20.0
0.21 U
88
75-133
8
20
Benzene
18
1.0
ug/L
20.0
0.15 U
91
80-134
0.8
17
Chlorobenzene
19
1.0
ug/L
20.0
0.17 U
93
80-120
7
16
Toluene
19
1.0
ug/L
20.0
0.14 U
95
71-120
5
17
Trichloroethene
18
1.0
ug/L
20.0
0.15 U
88
74-120
2
22
4-Bromofluorobenzene 48 u91L 50.0 96 53-136
Dibromofluoromethane 49 u91L 50.0 98 67-129
Toluene-d8 51 u91L 50.0 101 59-134
Metals by EPA 6000/7000 Series Methods - Quality Control
Batch 2D01002 - EPA 245.1
Blank (2D01002-BLK3) Prepared: 04/01/2022 04:21 Analyzed: 04/05/2022 04:53
Spike Source %REC RPD
Analvte Result Flaa Q Units Level Result %REC Limits RPD Limit Notes
Mercury 0.150 U 0.200 ug/L
LCS (2D01002-BS3) Prepared: 04/01/2022 04:21 Analyzed: 04/05/2022 04:57
Spike Source %REC
RPD
Analvte
Result Flaq
POL
Units
Level Result %REC Limits RPD
Limit Notes
Mercury
5.61
0.200
ug/L
5.00 112 80-120
Matrix Spike (2D03002-MS1)
Prepared: 04/01/2022 04:21 Analyzed: 04/05/2022 05:00
Source: CF02863-02
Spike Source %REC
RPD
Analvte
Result Flaq
POL
Units
Level Result %REC Limits RPD
Limit Notes
Mercury
5.47
0.200
ug/L
5.00 0.150 U 109 75-125
Matrix Spike Dup (21303002-MS131)
Prepared: 04/01/2022 04:21 Analyzed: 04/05/2022 05:03
Source: CF02863-02
Spike Source %REC
RPD
Analvte
Result Flaa
Q
Units
Level Result %REC Limits RPD
Limit Notes
Mercury
5.33
0.200
ug/L
5.00 0.150 U 107 75-125 3
25
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 91 Of 118

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QUALITY CONTROL DATA
Metals by EPA 6000/7000 Series Methods - Quality Control
Batch 2DO1002 - EPA 245.1 - Continued
Post Spike (2D01002-PS3) Prepared: 04/01/2022 04:21 Analyzed: 04/05/2022 05:05
Source: CF02863-02
Spike Source %REC RPD
Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes
Mercury 6.06 0.200 ug/L 4.76 0.0290 127 75-125 QM-08
Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control
Batch 2C29002 - EPA 3005A
Blank (2C29002-BLK3)
Prepared: 03/30/2022 09:37 Analyzed: 04/01/2022 09:49
Spike Source %REC RPD
Analvte
Result
Flaq
POL
Units
Level Result %REC Limits RPD Limit Notes
Arsenic
7.60
U
10.0
ug/L
Barium
1.10
U
10.0
ug/L
Beryllium
0.160
U
1.00
ug/L
Cadmium
0.360
U
1.00
ug/L
Chromium
1.40
U
10.0
ug/L
Cobalt
1.40
U
10.0
ug/L
Copper
1.60
U
10.0
ug/L
Lead
3.10
U
10.0
ug/L
Nickel
2.20
U
10.0
ug/L
Selenium
6.20
U
10.0
ug/L
Silver
1.90
U
10.0
ug/L
Vanadium
1.40
U
10.0
ug/L
Zinc
4.40
U
10.0
ug/L
LCS (2C29002-BS1)
Prepared: 03/30/2022 09:37 Analyzed: 04/01/2022 10:13
Spike
Source %REC RPD
Analvte
Result Flaq
POL
Units
Level
Result %REC Limits RPD Limit Notes
Arsenic
203
10.0
ug/L
200
101 80-120
Barium
198
10.0
ug/L
200
99 80-120
Beryllium
19.6
1.00
ug/L
20.0
98 80-120
Cadmium
20.2
1.00
ug/L
20.0
101 80-120
Chromium
195
10.0
ug/L
200
97 80-120
Cobalt
204
10.0
ug/L
200
102 80-120
Copper
194
10.0
ug/L
200
97 80-120
Lead
199
10.0
ug/L
200
100 80-120
Nickel
199
10.0
ug/L
200
99 80-120
Selenium
212
10.0
ug/L
200
106 80-120
Silver
195
10.0
ug/L
200
97 80-120
Vanadium
193
10.0
ug/L
200
96 80-120
Zinc
201
10.0
ug/L
200
101 80-120
Matrix Spike (2C29002-MS1)
Prepared:
03/30/2022 09:37 Analyzed: 04/01/2022 10:16
Source: CF03669-01
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits
RPD Limit Notes
Arsenic
200
10.0
ug/L
200
7.60 U
100
75-125
Barium
291
10.0
ug/L
200
98.6
96
75-125
Beryllium
19.3
1.00
ug/L
20.0
0.160 U
97
75-125
Cadmium
19.6
1.00
ug/L
20.0
0.360 U
98
75-125
Chromium
195
10.0
ug/L
200
3.89
96
75-125
Cobalt
197
10.0
ug/L
200
1.40 U
99
75-125
FINAL
This report relates only to
the sample as received by the
laboratory, and
may only be
reproduced in
full.
Page 92 Of 118

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QUALITY CONTROL DATA
Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control
Batch 2C29002 - EPA 3005A - Continued
Matrix Spike (2C29002-MSI) Continued
Prepared:
03/30/2022
09:37 Analyzed: 04/01/2022 10:16
Source: CF03669-01
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC Limits RPD
Limit Notes
Copper
188
10.0
ug/L
200
1.60 U
94 75-125
Lead
194
10.0
ug/L
200
3.10 U
97 75-125
Nickel
198
10.0
ug/L
200
2.20 U
99 75-125
Selenium
197
10.0
ug/L
200
6.20 U
99 75-125
Silver
190
10.0
ug/L
200
1.90 U
95 75-125
Vanadium
190
10.0
ug/L
200
2.36
94 75-125
Zinc
201
10.0
ug/L
200
4.40 U
100 75-125
Matrix Spike Dup (2C29002-MSD1)
Prepared:
03/30/2022
09:37 Analyzed: 04/01/2022 10:19
Source: CF03669-01
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC Limits RPD
Limit Notes
Arsenic
199
10.0
ug/L
200
7.60 U
100 75-125 0.5
20
Barium
277
10.0
ug/L
200
98.6
89 75-125 5
20
Beryllium
18.9
1.00
ug/L
20.0
0.160 U
94 75-125 2
20
Cadmium
19.3
1.00
ug/L
20.0
0.360 U
97 75-125 1
20
Chromium
190
10.0
ug/L
200
3.89
93 75-125 3
20
Cobalt
194
10.0
ug/L
200
1.40 U
97 75-125 1
20
Copper
185
10.0
ug/L
200
1.60 U
92 75-125 2
20
Lead
191
10.0
ug/L
200
3.10 U
95 75-125 1
20
Nickel
189
10.0
ug/L
200
2.20 U
94 75-125 5
20
Selenium
203
10.0
ug/L
200
6.20 U
101 75-125 3
20
Silver
185
10.0
ug/L
200
1.90 U
93 75-125 2
20
Vanadium
185
10.0
ug/L
200
2.36
91 75-125 3
20
Zinc
191
10.0
ug/L
200
4.40 U
96 75-125 5
20
Post Spike (2C29002-PSI)
Prepared:
03/30/2022
09:37 Analyzed: 04/01/2022 10:21
Source: CF03669-01
Spike
Source
%REC
RPD
Analvte
Result
Flaq POL
Units
Level
Result
%REC
Limits RPD
Limit Notes
Arsenic
0.208
0.0100
mg/L
0.200
0.00208
103
80-120
Barium
0.296
0.0100
mg/L
0.200
0.0986
99
80-120
Beryllium
0.0199
0.00100
mg/L
0.0200
2.77E-5
99
80-120
Cadmium
0.0203
0.00100
mg/L
0.0200
-2.37E-5
101
80-120
Chromium
0.200
0.0100
mg/L
0.200
0.00389
98
80-120
Cobalt
0.203
0.0100
mg/L
0.200
0.000208
101
80-120
Copper
0.193
0.0100
mg/L
0.200
0.000783
96
80-120
Lead
0.201
0.0100
mg/L
0.200
-0.000323
100
80-120
Nickel
0.204
0.0100
mg/L
0.200
0.000830
102
80-120
Selenium
0.209
0.0100
mg/L
0.200
-0.00326
104
80-120
Silver
0.200
0.0100
mg/L
0.200
0.000946
100
80-120
Vanadium
0.194
0.0100
mg/L
0.200
0.00236
96
80-120
Zinc
0.208
0.0100
mg/L
0.200
0.00217
103
80-120
Batch 1C29003 - EPA 3005A
Blank (2C29003-BLK1)
Prepared:
03/29/2022
05:09 Analyzed: 04/01/2022 11:30
Spike
Source
%REC
RPD
Analvte
Result
Flaq POL
Units
Level
Result
%REC
Limits RPD
Limit Notes
Arsenic
7.60
U 10.0
ug/L
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 93 Of 118

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QUALITY CONTROL DATA
Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control
Batch 2C29003 - EPA 3005A - Continued
Blank (2C29003-BLK3) Continued Prepared: 03/29/2022 05:09 Analyzed: 04/01/2022 11:30
Spike Source %REC RPD
Analvte
Result
Flaq
POL
Units
Level Result %REC Limits RPD Limit Notes
Barium
1.10
U
10.0
ug/L
Beryllium
0.160
U
1.00
ug/L
Cadmium
0.360
U
1.00
ug/L
Chromium
1.40
U
10.0
ug/L
Cobalt
1.40
U
10.0
ug/L
Copper
1.60
U
10.0
ug/L
Lead
3.10
U
10.0
ug/L
Nickel
2.20
U
10.0
ug/L
Silver
1.90
U
10.0
ug/L
Vanadium
1.40
U
10.0
ug/L
Zinc
4.40
U
10.0
ug/L
LCS (2C29003-BSI)
Prepared: 03/29/2022 05:09 Analyzed: 04/01/2022 11:35
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC Limits RPD
Limit Notes
Arsenic
199
10.0
ug/L
200
100 80-120
Barium
192
10.0
ug/L
200
96 80-120
Beryllium
19.0
1.00
ug/L
20.0
95 80-120
Cadmium
19.7
1.00
ug/L
20.0
98 80-120
Chromium
189
10.0
ug/L
200
95 80-120
Cobalt
197
10.0
ug/L
200
98 80-120
Copper
187
10.0
ug/L
200
93 80-120
Lead
195
10.0
ug/L
200
97 80-120
Nickel
193
10.0
ug/L
200
96 80-120
Silver
189
10.0
ug/L
200
95 80-120
Vanadium
185
10.0
ug/L
200
93 80-120
Zinc
196
10.0
ug/L
200
98 80-120
Matrix Spike (2C29003-MS1)
Prepared:
03/29/2022
05:09 Analyzed: 04/01/2022 12:51
Source: CF03673-01
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC Limits RPD
Limit Notes
Arsenic
210
10.0
ug/L
200
7.60 U
105 75-125
Barium
358
10.0
ug/L
200
159
100 75-125
Beryllium
19.8
1.00
ug/L
20.0
0.160 U
99 75-125
Cadmium
19.5
1.00
ug/L
20.0
0.360 U
98 75-125
Chromium
202
10.0
ug/L
200
6.97
98 75-125
Cobalt
201
10.0
ug/L
200
1.40 U
100 75-125
Copper
187
10.0
ug/L
200
1.60 U
94 75-125
Lead
198
10.0
ug/L
200
3.10 U
99 75-125
Nickel
199
10.0
ug/L
200
2.20 U
99 75-125
Silver
195
10.0
ug/L
200
1.90 U
97 75-125
Vanadium
193
10.0
ug/L
200
1.40 U
96 75-125
Zinc
211
10.0
ug/L
200
8.42
101 75-125
Matrix Spike Dup (2C29003-MSD1)
Prepared:
03/29/2022
05:09 Analyzed: 04/01/2022 12:53
Source: CF03673-01
Spike Source %REC RPD
Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes
Arsenic 210 10.0 ug/L 200 7.60 U 105 75-125 0.3 20
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 94 of 118

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QUALITY CONTROL DATA
Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control
Batch 2C29003 - EPA 3005A - Continued
Matrix Spike Dup (2C29003-MSD1)
Continued
Prepared:
03/29/2022
05:09 Analyzed: 04/01/2022 12:53
Source: CF03673-01
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC Limits RPD
Limit Notes
Barium
361
10.0
ug/L
200
159
101 75-125 0.8
20
Beryllium
19.5
1.00
ug/L
20.0
0.160 U
98 75-125 2
20
Cadmium
19.8
1.00
ug/L
20.0
0.360 U
99 75-125 1
20
Chromium
200
10.0
ug/L
200
6.97
96 75-125 1
20
Cobalt
203
10.0
ug/L
200
1.40 U
102 75-125 1
20
Copper
186
10.0
ug/L
200
1.60 U
93 75-125 0.8
20
Lead
197
10.0
ug/L
200
3.10 U
98 75-125 0.6
20
Nickel
201
10.0
ug/L
200
2.20 U
100 75-125 0.8
20
Silver
193
10.0
ug/L
200
1.90 U
96 75-125 1
20
Vanadium
191
10.0
ug/L
200
1.40 U
96 75-125 0.8
20
Zinc
215
10.0
ug/L
200
8.42
103 75-125 2
20
Post Spike (2C29003-PSI)
Prepared:
03/29/2022
05:09 Analyzed: 04/01/2022 12:56
Source: CF03673-01
Spike
Source
%REC RPD
Analvte
Result
Flaq POL
Units
Level
Result
%REC
Limits RPD Limit Notes
Arsenic
0.213
0.0100
mg/L
0.200
0.00411
104
80-120
Barium
0.369
0.0100
mg/L
0.200
0.159
105
80-120
Beryllium
0.0206
0.00100
mg/L
0.0200
3.10E-5
103
80-120
Cadmium
0.0203
0.00100
mg/L
0.0200
-0.000236
102
80-120
Chromium
0.209
0.0100
mg/L
0.200
0.00697
101
80-120
Cobalt
0.209
0.0100
mg/L
0.200
0.00118
104
80-120
Copper
0.192
0.0100
mg/L
0.200
-0.000804
96
80-120
Lead
0.205
0.0100
mg/L
0.200
-0.00185
103
80-120
Nickel
0.206
0.0100
mg/L
0.200
0.000534
103
80-120
Silver
0.207
0.0100
mg/L
0.200
0.000927
103
80-120
Vanadium
0.198
0.0100
mg/L
0.200
0.000136
99
80-120
Zinc
0.220
0.0100
mg/L
0.200
0.00842
106
80-120
Batch 2C29004 - EPA 3005A
Blank (2C29004-BLK3)
Prepared:
03/29/2022
05:12 Analyzed: 04/04/2022 10:01
Spike Source %REC RPD
Analvte
Result
Flaq
POL
Units
Level Result %REC Limits RPD Limit Notes
Antimony
0.370
U
1.00
ug/L
Selenium
0.910
U
1.00
ug/L
Thallium
0.110
U
1.00
ug/L
LCS (2C29004-BSI)
Prepared: 03/29/2022 05:12 Analyzed: 04/04/2022 10:06
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits RPD
Limit Notes
Antimony
20.1
1.00
ug/L
20.0
100
80-120
Selenium
21.5
1.00
ug/L
20.0
107
80-120
Thallium
20.4
1.00
ug/L
20.0
102
80-120
Matrix Spike (2C29004-MS1)
Prepared: 03/29/2022 05:12 Analyzed: 04/04/2022 10:25
Source: CF02863-02
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits RPD
Limit Notes
Antimony
43.1
2.00
ug/L
40.0
0.740 U
108
75-125
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 95 of 118

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QUALITY CONTROL DATA
Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control
Batch 2C29004 - EPA 3005A - Continued
Matrix Spike (2C29004-MSI) Continued
Prepared: 03/29/2022 05:12 Analyzed: 04/04/2022 10:25
Source: CF02863-02
Spike Source %REC
RPD
Analvte
Result Flaq
POL
Units
Level Result %REC Limits RPD
Limit Notes
Selenium
41.0
2.00
ug/L
40.0 1.82 U 102 75-125
Thallium
41.5
2.00
ug/L
40.0 0.220 U 104 75-125
Matrix Spike Dup (2C29004-MSD3)
Prepared: 03/29/2022 05:12 Analyzed: 04/04/2022 10:30
Source: CF02863-02
Spike Source %REC
RPD
Analvte
Result Flaq
POL
Units
Level Result %REC Limits RPD
Limit Notes
Antimony
45.1
2.00
ug/L
40.0 0.740 U 113 75-125 4
20
Selenium
43.6
2.00
ug/L
40.0 1.82 U 109 75-125 6
20
Thallium
43.2
2.00
ug/L
40.0 0.220 U 108 75-125 4
20
Post Spike (2C29004-PSI)
Prepared: 03/29/2022 05:12 Analyzed: 04/04/2022 10:34
Source: CF02863-02
Spike Source %REC RPD
Analvte
Result Flaq
POL
Units
Level Result %REC Limits RPD Limit Notes
Antimony
22.0
1.00
ug/L
20.0 0.00774 110 75-125
Selenium
21.8
1.00
ug/L
20.0-0.0585 109 75-125
Thallium
21.2
1.00
ug/L
20.0 0.0254 106 75-125
Batch 2C29005 - EPA 3005A
Blank (2C29005-BLK3)
Prepared: 03/29/2022 05:15 Analyzed: 04/04/2022 12:28
Spike Source %REC RPD
Analvte
Result
Flaq
POL
Units
Level Result %REC Limits RPD Limit Notes
Antimony
0.370
U
1.00
ug/L
Selenium
0.910
U
1.00
ug/L
Thallium
0.110
U
1.00
ug/L
LCS (2C29005-BSI)
Prepared: 03/29/2022 05:15 Analyzed: 04/04/2022 12:36
Spike Source %REC
RPD
Analvte
Result Flaq
POL
Units
Level Result %REC Limits RPD
Limit Notes
Antimony
22.0
1.00
ug/L
20.0 110 80-120
Selenium
21.9
1.00
ug/L
20.0 110 80-120
Thallium
21.5
1.00
ug/L
20.0 108 80-120
Matrix Spike (2C29005-MS1)
Prepared: 03/29/2022 05:15 Analyzed: 04/04/2022 13:00
Source: CF02862-01
Spike Source %REC
RPD
Analvte
Result Flaq
POL
Units
Level Result %REC Limits RPD
Limit Notes
Antimony
43.3
2.00
ug/L
40.0 0.740 U 108 75-125
Selenium
41.9
2.00
ug/L
40.0 1.82 U 105 75-125
Thallium
40.4
2.00
ug/L
40.0 0.220 U 101 75-125
Matrix Spike Dup (2C29005-MSD3)
Prepared: 03/29/2022 05:15 Analyzed: 04/04/2022 13:04
Source: CF02862-01
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits
RPD
Limit Notes
Antimony
45.0
2.00
ug/L
40.0
0.740 U
112
75-125
4
20
Selenium
42.1
2.00
ug/L
40.0
1.82 U
105
75-125
0.6
20
Thallium
42.4
2.00
ug/L
40.0
0.220 U
106
75-125
5
20
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 96 Of 118