6004_DukeMcGuire_LFNo2_WQMR_FID1741301_20221017

DUKE
ENERGY.
October 17, 2022
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
1646 Mail Service Center
Raleigh, North Carolina 28778
Attn: Ms. Sarah Moutos (submitted electronically)
Re: Semi -Annual Water Quality Monitoring Report — June 2022
Duke Energy Carolinas, LLC
McGuire Nuclear Station
Landfill No. 2 (Synthetically Lined), Permit #60-04
Dear Ms. Moutos:
Duke Energy
McGuire Nuclear Station
12700 Hagers Ferry Road
Huntersville, NC 28078
Duke Energy is providing the result of the first 2022 semi-annual groundwater monitoring for the Duke Energy Carolinas
McGuire Landfill No. 2 (Synthetically Lined), located near Huntersville, North Carolina.
On June 28-29, 2022, groundwater, surface water, and leachate samples were collected in accordance with the McGuire
Landfill Sampling and Analysis Plan (SAP).
The groundwater sampling field and analytical results are summarized in Table 4. The analytical results for the constituents
are compared to the groundwater standards found in Title 15A NCAC 02L .0202 (2L Standards). Groundwater results with
values that attain or exceed the 2L Standards (or outside of 2L Standard range for pH) are indicated on Table 4 by yellow
highlighting. A summary of the groundwater analytical results that attain or exceed the 2L Standards (or outside of 2L
Standard range for pH) and a preliminary analysis of the cause and significance of such occurrences are presented in
Table 5. In one or more wells, pH measurements were reported outside of the 2L Standard pH range, but no other 2L
exceedances were reported for the June 2022 monitoring event.
The surface water field and analytical results are summarized in Table 6. The surface water analytical results for the
constituents are compared to the surface water standards found in Title 15A NCAC 02B .0211 (26 Standard) for Class C
waters. No 2B Standards were exceeded during the June 2022 monitoring event.
The leachate field and analytical results are summarized in Table 7. The leachate sample was collected from the in -flow
pipe which conveys leachate from the landfill into the leachate pond.
Duke Energy personnel sample designated locations for groundwater, surface water, and leachate at the McGuire Landfill
No. 2 (Synthetically Lined) semi-annually during June and December. The next water quality monitoring event for Landfill
No. 2 is planned for December 2022 with a report of monitoring results to follow.
If you need additional information regarding this submittal, please contact Ashley Healy at Ashley. Healy(a)-duke-energy.com
or [phone].
Sincere ,
i
Bre t ar
Duke Energy
McGuire Nuclear Station
Plant Manager
www.duke-energy.com Page 1 of 1

�6_r=NR'�itSEONL ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #:
NC DENR I IEnvironmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off --site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring °Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
S&ME, Inc. (Consultant for Duke Energy)
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Julie P. Robertson, P.G.
E-mail: [e-mail]
Phone: [phone]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Duke Energy Carolinas, LLC 12700 Hagers Ferry Road
McGuire, Landfill No. 2 6004 .0500 June 28 - 29, 2022
(Synthetically Lined) Huntersville, NC 28078
Environmental Status: (Check all that apply)
Initial/Background Monitoring xx Detection Monitoring Assessment Monitoring Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells Methane gas monitoring data
Groundwater monitoring data from private water supply wells Corrective action data (specify)
Leachate monitoring data ❑
Surface water monitoring data Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
ex Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Julie P. Robertson, P.G. Senior Geologist 704-523-4726
Facilitv Representative Name (Print) Title (Area Code) Telephone Number
' 10/11/2021 Affix NC Licensed/ Professional Geologist Seal
Signature Date
9
2016 Ayrsiey Town Blvd., Suite 2-A, Charlotte, NC 28273�,,°"
Facility Representative Address
- l
S&ME Engineering License # F-0176, S&ME Geology License # C-145
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009

DENR USE ONLY ❑Paper Report ❑Electronic Data -Email CD (data loaded: Yes / No Doc/Event #:
NC DENR Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
S&ME, Inc. (Consultant for Duke Energy)
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Julie P. Robertson, P.G.
E-mail: [e-mail]
Phone: [phone]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or. 1600) October 20-24, 2006)
Duke Energy Carolinas, LLC 12700 Hagers Ferry Road
McGuire, Landfill No. 2 Huntersville, NC 28078 6004 .0500 June 1 - 2, 2020
(Synthetically Lined)
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring �X Detection Monitoring ❑ Assessment Monitoring Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑
Leachate monitoring data ❑
Surface water monitoring data
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
RX Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Julie P. Robertson, P.G. Senior Geologist 704-523-4726
Facility Representative Name (Print) Title (Area Code) Telephone Number
Affix NC Licensed/ Professional Geologist Seal
Signature Date
9751 Southern Pine Blvd., Charlotte, NC 28273
Facility Representative Address
S&ME Engineering License # F-0176, S&ME Geology License # C-145
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009

Semi -Annual Water Quality Monitoring Report
June 2022 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 2
(Synthetically Lined) Permit No. 6004-INDUS
Mecklenburg County, North Carolina
S&ME Project No. 21350075, Ph. 05

REPORT VERIFICATION
PROJECT: SEMI-ANNUAL WATER QUALITY MONITORING REPORT
DUKE ENERGY CAROLINAS, MCGUIRE, LANDFILL NO. 2
(SYNTHETICALLY LINED) PERMIT NO. 6004-INDUS
S&ME PROJECT NO. 21350075, PH. 05
TITLE: JUNE 2022 SAMPLING EVENT
This document has been reviewed for accuracy and quality commensurate with the intended
application.
Prepared by:
Approved by:
Date: 10/11 /2022
Date: 10/11 /2022
Group Leader — Energy + Environment: Julie P. Robertson, PG
Licensed Geologist Seal:
S&ME, Inc.
2016 Ayrsley Town Blvd., Suite 2-A
Charlotte, North Carolina 28273
North Carolina Geological Corporation Number C-145
S&ME, Inc. 12016 Ayrsley Town Blvd., Suite 2-A I Charlotte, NC 282731 p 704.523.4726 1 www.smeinc.com

Semi -Annual Water Quality Monitoring Report — June 2022 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 2
(Synthetically Lined) Permit No. 6004-INDUS
S&ME Project No. 21350075, Ph. 05 I I
Table of Contents
1.0 Background........................................................................................................................1
1.1 Site Description...............................................................................................................................1
1.2 Hydrologic Setting.........................................................................................................................1
1.3 Monitoring Program......................................................................................................................1
2.0 Methods..............................................................................................................................2
2.1 Sampling and Analysis Methods.................................................................................................2
2.1.1 Groundwater, Surface Water, and Leachate.....................................................................................3
2.1.2 Radiological Samples.........................................................................................................................3
2.2 Statement of Work..........................................................................................................................3
3.0 Results.................................................................................................................................4
3.1 Site Groundwater Flow................................................................................................................. 4
3.2 Analytical Results...........................................................................................................................4
3.2.1 Groundwater.....................................................................................................................................4
3.2.2 Surface Water.................................................................................................................................... 4
3.2.3 Leachate.............................................................................................................................................5
3.2.4 Radiological Samples.........................................................................................................................5
3.2.5 Quality Assurance / Quality Control...............................................................................................5
Appendices
Appendix I — Figures
Appendix II — Tables
Appendix III — Field Sampling Forms
Appendix IV — Laboratory Reports and Chain -of -Custody Forms
Appendix V — Rainfall Data and Leachate Generation Rates (January 2022 through June 2022)
October 11, 2022

Semi -Annual Water Quality Monitoring Report — June 2022 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 2
(Synthetically Lined) Permit No. 6004-INDUS
S&ME Project No. 21350075, Ph. 05
1.0 Background
1.1 Site Description
The Duke Energy Carolinas, McGuire, Landfill #2 (Synthetically Lined)' (hereafter, landfill) is located at the McGuire
Nuclear Station in Mecklenburg County, North Carolina. The landfill is permitted under North Carolina
Department of Environmental Quality (NCDEQ) Solid Waste Permit No. 6004-INDUS and currently accepts waste.
The landfill was constructed with a high -density polyethylene (HDPE) synthetic liner and leachate collection and
removal system. Leachate and contact stormwater are collected in a synthetically lined leachate collection pond
and pumped to the McGuire Nuclear Station wastewater treatment system. The landfill and surrounding areas are
shown on Figure 1 in Appendix I.
1.2 Hydrologic Setting
The landfill is located south of North Carolina (NC) Highway 73, north of Cashion Road and west of Lindeman
Road as shown on Figures 1 and 2 in Appendix I. Cashion Road runs along a surface water divide, with surface
flow draining to the northwest and the southeast. A surface water drainage feature located northeast of the
landfill drains towards the northwest to an unnamed perennial stream, which discharges into the Catawba River.
The Catawba River is classified as a Water Supply -IV water source, (WS-IV).
1.3 Monitoring Program
As described in the Sampling and Analysis Plan (SAP) dated May 19, 2022, the current monitoring system at the
landfill consists of the following:
Monitoring Wells:
MW-5R2
MW-8
MW-5A
MW-8A
MW-6
MW-9
MW-6A
MW-9A
MW-7R
MW-10A
MW-7A
' In response to the North Carolina Division of Public Health, Radiation Protection Section, November 17, 2006 letter to Duke
Energy, LLC, Duke Energy offered to indicate the landfill as synthetically lined in reports.
2 Replacement monitoring wells were installed on October 10 (MW-7R) and 11 (MW-5R), 2076 because the original wells did not
consistently produce enough water for sampling. Replacement wells were installed to deeper depths with a 15-foot screened
interval, per approval from NCDEQ. See Approval Replacement Monitoring Wells MW-5 and MW-7 signed by Elizabeth Werner,
Permitting Hydrogeologist dated July 27, 2076.
October 11, 2022

Semi -Annual Water Quality Monitoring Report — June 2022 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 2
(Synthetically Lined) Permit No. 6004-INDUS
S&ME Project No. 21350075, Ph. 05
Surface Water Sample Locations:
Leachate Sample Location:
SW-1
SW-2
Leachate Pond (in -flow pipe)
Monitoring wells were installed as well pairs consisting of one shallow well and one deep well (with the exception
of monitoring well MW-10A, which does not have an accompanying shallow well). Wells with "A" designations
represent the deeper well within each well pair. Wells with "R" designations are replacement wellsz. As designated
in the SAP, monitoring well location MW-5R is upgradient and considered to represent background
conditions for the landfill. Well pair MW-9 and MW-9A were installed adjacent to and downgradient from the
leachate pond. The remaining wells were installed adjacent to the landfill. Well construction information is
summarized in Table 1 in Appendix II.
Surface water samples are collected from two locations, SW-1 and SW-2, as shown on Figure 2 in Appendix I.
Surface water sample location SW-1 is collected from an unnamed perennial stream northeast of the landfill and
serves as the background surface water sample location for this monitoring program. Surface water sample
location SW-2 is also collected from this unnamed perennial steam, northwest of the landfill and downstream
from surface water sample location SW-1.
The leachate sample is collected from the end of the in -flow pipe, which conveys leachate from the landfill to the
synthetically lined leachate collection pond. The leachate pond resumed permanent operational status in February
2021 after the synthetic liner system was replaced at the end of 2020. While the leachate pond was out of service,
leachate was rerouted through a temporary bypass system directly to the McGuire Nuclear Station wastewater
treatment system. The locations of the monitoring wells, surface water samples, and the leachate pond sample
location are shown on Figure 2 in Appendix I.
2.0 Methods
2.1 Sampling and Analysis Methods
Groundwater, surface water, and leachate sampling activities were performed by Duke Energy Groundwater
Science Group (Duke Energy Carolinas Field Certification #99046001), in general accordance with the North
Carolina Solid Waste Management Guidelines. Copies of the June 2022 field sampling forms are included in
Appendix III. The parameters and constituents reported were selected in accordance with the SAP and the
NCDEQ Division of Waste Management, Solid Waste Section and were analyzed by the Duke Energy Analytical
Laboratory (North Carolina Laboratory Certification #248), Pace Analytical Services (North Carolina Laboratory
Certification #329), and EnRad Laboratories. The laboratory reports and chain -of -custody forms are included in
Appendix IV.
October 11, 2022

Semi -Annual Water Quality Monitoring Report — June 2022 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 2 �r
(Synthetically Lined) Permit No. 6004-INDUS
S&ME Project No. 21350075, Ph. 05
2.1.1 Groundwater, Surface Water, and Leachate
The groundwater, surface water, and leachate samples were analyzed for the following parameters using the
following analytical methods in accordance with the SAP:
• Barium, calcium, magnesium, potassium, and sodium using Solid Waste (SW)-846 Method 6010D
• Arsenic, cadmium, chromium, lead, selenium, and silver using SW-846 Method 6020B
• Mercury using SW-846 Method 7470A
• Sulfate and Chloride using SW-846 Method 9056A
• TPH Diesel Range Organics (TPH-DRO) using SW-846 Method 8015C Modified with 3520C sample
Preparation
• 1,4-Dioxane using SW-846 Method 8260B (SIM) with 5030B sample preparation.
• Alkalinity using Method SM2320B
• Volatile organic compounds (VOCs) using SW-846 Method 8260
The surface water sample was also field -filtered using a 0.45-micron in -line filter and dissolved analyses were
performed for the following constituents:
• Arsenic, cadmium, chromium, lead, and silver using SW-846 Method 6020B
2.1.2 Radiological Samples
In accordance with the requirements of the Radioactive Materials License No. 060-0379-7 issued by the North
Carolina Department of Health and Human Services Radiation Protection Section, the following radiological
analyses were performed on groundwater and surface water samples:
• Gross alpha and beta radioactivity using EPA Method 900
• Tritium using EPA Method 906.0 Modified
• Gamma radioactivity for select isotopes
2.2 Statement of Work
S&ME completed the following tasks:
• Received field sampling data from Duke Energy (performed by Duke Energy Groundwater Sciences Group)
for monitoring wells MW-5R, MW-5A, MW-6, MW-6A, MW-7R, MW-7A, MW-8, MW-8A, MW-9, MW-9A,
and MW-10A. Field sampling data was also received for surface water sample locations SW-1 and SW-2
October 11, 2022 3

Semi -Annual Water Quality Monitoring Report — June 2022 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 2 �r
(Synthetically Lined) Permit No. 6004-INDUS
S&ME Project No. 21350075, Ph. 05
and the leachate pond. The samples were collected between June 28t" and 291", 2022, and S&ME received
the data from Duke Energy via e-mail correspondence from Ashley Healy (Duke Energy) to Julie Robertson
and Jasmine Tayouga (S&ME) on July 1, 2022.
• Reviewed the laboratory analytical results and the Electronic Data Deliverables (EDDs) provided by Duke
Energy for the samples noted above.
• Developed a shallow groundwater contour map and calculated groundwater flow velocities using survey
data and groundwater levels measured by Duke Energy Groundwater Sciences Group.
3.0 Results
3.1 Site Groundwater Flow
Shallow groundwater surface contours and groundwater flow direction in the vicinity of the landfill are shown on
Figure 3 in Appendix I. These contours were developed using the depth to groundwater measurements in the
shallow wells on the date of sampling and top of well casing elevations. Calculated groundwater flow velocities are
presented on Table 2 in Appendix II.
Based on groundwater elevations calculated for the June 2022 sampling event, groundwater flow is generally from
the southeast to the north and northwest toward the Catawba River.
3.2 Analytical Results
3.2.1 Groundwater
Laboratory results for groundwater samples were compared to the Title 15A NCAC Subchapter 2L Standards (2L
Standards) to evaluate compliance with NCDEQ groundwater quality standards. In one or more wells, pH
measurements were reported outside of the 2L Standard pH range. No other exceedances of 2L Standards were
reported for groundwater samples collected during the June 2022 sampling event.
A summary of field data parameters recorded prior to sample collection is presented in Table 3 in Appendix II. A
summary of groundwater analytical results for the current sampling event is presented in Table 4 in Appendix II.
A summary of the groundwater analytical results that equal or exceed the 2L Standards and a comparison to
historical concentration ranges are presented in Table 5 in Appendix II.
3.2.2 Surface Water
Laboratory results for the surface water samples (SW-1 and SW-2) were compared to the Title 15A NCAC
Subchapter 2B Standards (213 Standards) for Class WS-IV waters to evaluate compliance with established criteria.
No constituents exceeded 2B Standards in the surface water samples collected during the June 2022 sampling
event. A summary of field data parameters recorded prior to sample collection is presented in Table 3 in
October 11, 2022 4

Semi -Annual Water Quality Monitoring Report — June 2022 Sampling Event
Duke Energy Carolinas, McGuire, Landfill No. 2 �r
(Synthetically Lined) Permit No. 6004-INDUS
S&ME Project No. 21350075, Ph. 05
Appendix II. A summary of surface water analytical results for the June 2022 sampling event is presented in Table
6 in Appendix II.
3.2.3 Leachate
The leachate sample was collected from the in -flow pipe which conveys leachate from the landfill into the leachate
pond. A summary of field data parameters recorded at the time of sample collection is presented in Table 3 in
Appendix II. A summary of analytical results for the June 2022 sampling event is presented in Table 7 in
Appendix II. Monthly rainfall data for McGuire Nuclear Station and leachate generation rates (for January 2022
through June 2022) were provided by Duke Energy and are located in Appendix V. S&ME did not evaluate the
monthly rainfall and leachate generation data.
3.2.4 Radiological Samples
The results of the radiological analyses are presented in Table 8 in Appendix II. A copy of the laboratory report
has been submitted to the North Carolina Department of Health and Human Services Radiation Protection Section
for reference and is also included in this report in Appendix IV. S&ME did not evaluate this data.
3.2.5 Quality Assurance / Quality Control
Field -performed quality assurance and quality control (QA/QC) consisted of the collection and analysis of two field
blanks (one on each day of sampling) to evaluate if contamination was imparted to the samples by the sample
container, preservative, or other exogenous sources. Samples for the monitoring wells, surface water locations,
and leachate were submitted to Duke Energy Analytical Laboratories on June 29, 2022.
The 1,4 dioxane internal standard solution was expired when used for the analysis of this sample set. The internal
standard recovery passed when checked against the initial calibration that was analyzed prior to expiration. The
data for the samples, per Pace, should not be impacted.
Trans-1,4 dichloro-2-butene LCS/LCSD recoveries were outside the QC limits. Per Pace laboratory's SOP, it allows
for 10% of analytes to recover outside criteria. (see Pace's case narrative located in Appendix IV) The samples
impacted were MW-8, MW-8A, MW-9, MW-9A.
Bromomethane and vinyl chloride LCS recovery was outside the QC limits. The associated samples MW-8, MW-8A,
MW-9, and MW-9A were non -detect for these analytes.
The following alkalinity samples were analyzed outside the holding time due to instrumentation error during the
analysis: MW-8, MW-8A, MW-9, MW-9A, SW-1, SW-2, FB-20220628-1430 and FD-20220628-1. See Pace's case
narrative for details. Additional QA/QC data, laboratory analyses, and chain -of -custody forms are included in
Appendix IV.
October 11, 2022

Appendices

Appendix I - Figures

Appendix II - Tables

Table 1: Well Construction Information
Landfill No. 2 (Synthetically Lined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 21350075, Ph. 05
La
III
Well ID
MW-5R
Install •.
..TOC)
10/10/16
GPS Coordinates
Latitude
35.41504
Longitude
-80.94525
Survey Elevations
Ground
764.93
•C
767.38
Height
Ground
Surface
2.45
June 28 -
DTW - TOC
60.92
29, 202
GW ELEV.
706.46
DepthWell Total Well
Top of
Casing
76.35
Screen Interval
0.010 Slot,
59.35 to
Sch. 40
76.35
Geology in
Interval
SAP
Well
(inches)
2
Type
Sch.
40
PVC
MW-5A
01/14/92
35.41518
-80.94505
766.45
768.42
1.97
62.35
706.07
96.00
82.00
to
96.00
NR
2
Sch.
40
PVC
MW-6
02/21/92
35.41691
-80.94505
726.79
728.45
1.66
32.20
696.25
37.20
23.20
to
37.20
SAP
2
Sch.
40
PVC
MW-6A
02/20/92
35.41692
-80.94510
727.54
728.98
1.44
31.50
697.48
47.90
33.90
to
47.90
SAP
2
Sch.
40
PVC
MW-7R
10/11/16
35.41635
-80.94729
723.53
726.16
2.63
34.10
692.06
48.89
33.89
to
48.89
SAP
2
Sch.
40
PVC
MW-7A
1 02/12/92
35.416.26
-80.94732
722.74
724.66
1 1.92
31.87
692.79
59.40
1 45.40
to
59.40
SAP
2
Sch.
40
PV
MW-8
02/03/92
35.41687
-80.94626
757.30
759.60
2.30
61.98
697.62
71.50
57.50
to
71.50
SAP
2
Sch.
40
PVC
MW-8A
02/11/92
35.41684
-80.94622
757.61
759.68
2.07
61.95
697.73
84.40
70.40
to
84.40
SAP
2
Sch.
40
PVC
MW-9
02/19/92
35.41590
-80.94793
710.27
711.87
1.60
25.19
686.68
30.80
16.80
to
30.80
SAP
2
Sch.
40
PVC
MW-9A
02/18/92
35.41586
-80.94794
710.30
712.13
1.83
25.58
686.55
47.80
33.80
to
47.80
SAP
2
Sch.
40
PVC
MW-10A
01/16/01
1 35.441609
-80.94448
753.87
1 755.78
1.91
51.76
704.02
1 59.23
44.23
to
59.23
SAP
2
Sch.
40
PVC
Notes•
(1)
0.010 Slot
0.010-Inch Machine -Slotted Pipe
(2)
DTW
Depth to Water
(3)
Ground
Ground Surface
(4)
GW ELEV.
Groundwater Elevation
(5)
NR
Not Reported
(6)
PVC
Polyvinyl Chloride
(7)
PWR
Partially Weathered Rock
(8)
TOC
Top of Casing
(9)
SAP
Saprolite
(10)
Sch. 40
Schedule 40 Pipe
(11) Elevations based on NAVD88 vertical datum.
(12) Horizontal coordinates based on NAD27 datum.
(13) Survey and well construction data provided by Duke Energy.

Table 2: Groundwater Flow Velocities
s
Landfill No. 2 (Synthetically Lined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 21350075, Ph. 05
MW-8
700
695
340
0.01
0.44
0.22
5
MW-9
690
686.68
145
0.02
0.44
0.22
8
Notes•
(1) Hydraulic gradient calculated by measuring linear distance through monitoring wells (generally perpendicular) from selected
groundwater contours.
(2) Monitoring wells are not listed where insufficient groundwater contour information is available to calculate velocity.
(3) Hydraulic gradients and groundwater velocities are approximate.
(4) Hydraulic Conductivity and effective porosity are mean values for soil/saprolite taken from "Groundwater Protection Initiative Site
Characterization Report" for McGuire Nuclear Station dated June 30, 2008 by S&ME, Inc.
(5) Seepage velocity equation used to calculate groundwater flow velocity v = (K*i)/ne

able 3: Field Data Parameters
Landfill No. 2 (Synthetically Lined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 21350075, Ph. 05
Well ID
MW-5R
D.rAppearanceDepth
6/28/2022
Well
Below
•
76.35
Depth to
Water
Below •
60.92
roundwater
706.46 Normal
Odor
None
Purge
..
LF
Average
Pump Rate
330
Well
Volume
2.52
EVAC
Volume
2.05
EVAC
NA
Temperature
19.55
Specific
Conductivity
13
7.57
Turbidity
2.0
ORP
400
Dissolved
OxygenPH
7.71
MW-5A
6/28/2022
96.00
62.35
706.07
Normal
None
LF
300
5.49
1.95
NA
18.76
42
7.37
1.2
343
7.86
MW-6
6/29/2022
37.20
32.20
696.25
Normal
None
EOP
NA
0.82
0.50
NA
21.13
34
5.98
3.6
351
7.70
MW-6A
6/29/2022
47.90
31.50
697.48
Normal
None
LF
330
2.67
2.00
NA
18.39
48
5.40
3.1
377
7.64
MW-7R
6/28/2022
48.89
34.10
692.06
Normal
None
LF
280
2.41
1.45
NA
18.30
47
5.70
3.0
363
7.67
MW-7A
6/28/2022
59.40
31.87
692.79
Normal
None
LF
360
4.49
1.60
NA
18.22
114
6.41
7.8
331
7.39
MW-8
6/28/2022
71.50
61.98
697.62
Normal
None
EOP
NA
1.55
0.60
NA
19.89
107
6.48
3.2
366
8.66
MW-8A
6/28/2022
84.40
61.95
697.73
Normal
None
LF
400
3.66
2.55
NA
17.55
84
6.68
0.7
378
7.46
MW-9
6/28/2022
30.80
25.19
686.68
Normal
None
EOP
NA
0.91
0.35
NA
19.74
99
5.69
3.4
360
3.90
MW-9A
6/28/2022
47.80
25.58
686.55
Normal
None
LF
330
3.62
1.55
NA
18.48
113
6.13
2.1
332
4.94
MW-10A
6/29/2022
59.23
51.76
704.02
Normal
None
EOP
NA
1.22
0.50
NA
19.55
33
7.80
9.1
365
6.08
SW-1
6/28/2022
NA
NA
NA
Normal
None
SWS
NA
NA
NA
NA
21.91
95
7.19
34.7
244
7.21
SW-2
6/28/2022
NA
NA
NA
Normal
None
SWS
NA
NA
NA
NA
21.51
98
6.86
8.7
274
7.81
Leachate
6/28/2022
NA
NA
NA
Normal
None
SWS
NA
NA
NA
NA
20.22
877
7.34
7.0
305
7.29
Notes-
(1)
°C
degrees Celsius
(2)
ft
feet
(3)
gal
gallons
(4)
µU/cm
micromhos per centimeter
(5)
mg/L
milligrams per liter
(6)
mL/min
milliliters per minute
(7)
mV-NHE
millivolts - normal hydrogen electrode
(8)
NA
not applicable
(9)
NTU
nephelometric turbidity unit
(10)
SU
standard units
(11)
TOC
top of casing
(12) Elevations based on NAVD88 vertical datum.
(13) Purge methods: LF = Low Flow; CP = Conventional Purge (3-5 well volumes); EOP = Equipment Only Purge; SWS = Surface Water Sample; average pump rate applicable to
LF purging only.
(14) EVAC indicates whether the water level in the well was drawn down to the level of the pump during purging and also the total amount purged from the well.
(15) Field sampling performed by Duke Energy Groundwater Science Group.

Table 4: Groundwater Field and Analytical Results
Landfill No. 2 (Synthetically Lined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 21350075, Ph. 05
III
1W
-WM
Field pH
=I"
SU
Mir
7.57
7.37
5.98
5.40
June
5.70
28 - 29, 2022
6.41
6.48
6.68
5.69
6.13
7.80
„.
- - -
SWS I
Groundwater
Protection
NE
aLedl,
- 8.5
Federal
6.5 - 8.5*
Specific Conductance
µU/cm
13
42
34
48
47
114
107
84
99
113
33
- - -
NET17NE
NE
Temperature
°C
19.55
18.76
21.13
18.39
18.30
18.22
19.89
17.55
19.74
18.48
19.55
- - -
NE
NE
NE
•
.
Volatile Organic Compounds were not detected during the June 2022 Sampling Event
TPH-DRO
µg/L
180 BJ
190 BJ
170 BJ
230 B
180 BJ
140 BJ
150 BJ
170 BJ
190 BJ
140 BJ
160 BJ
130
NE
NE
NE
Alkalinity (CaCO3)
Pg/L
<20
25
37
<20
22
62
68 H
53 H
38 H
61 H
<20
1700
NE
NE
NE
Chloride
hg/L
1200
1300
8000
5500
2600
1200
1400
2300
2200
1700
1300
15.4
NE
1 250000
1250000*
Sulfate
Pg/L
80
2700
290
50J
90J
290
1500
1 1400
1 170
L 220
460
440.0
NE
250000
250000*
MMlethod EPA 7470A
'Mil
Mercury
Total Recoverable Metals Method
Arsenic
SW .00:
I µg/L
µg/L
I
0.111
0.651 J
0.111 U
Mercury was not detected during the June 2022 Sampling Event
0.111 U 0.111 U 0.114 J 0.111 U 0.111 U 0.122 J
0.111 U
0.111 U
1 0.01
0.111
NE
NE
1
10
2
10
Chromium
µg/L
0.797
0.668 J
2.28
1.330
0.594J
0.553J
0.788J
0.604J
1.22
1.98
0.866 J
0.185
NE
10
100
Lead
µg/L
0.292
0.048 J
0.037 U
0.037 J
0.054 J
0.037 U
0.064 J
0.037 U
0.037 U
0.037 U
0.297 J
0.037
I
NE
15
15
Silver
Total Recoverable Metals Method
Barium
SW 0.
µg/L
µg/L
0.035
16
0.321 J
26
0.035 U
40
0.035 U
52
0.035 U
25
0.035 U
4J
0.035 U
15
0.035 U
30
0.035 U
18
0.035 U
10
0.035 U
32
0.035
2
NE
NE
20
700
100*
2000
Calcium
µg/L
688
3050
8640
4780
3770
14700
16400
11300
7300
11600
1590
12
NE
NE
NE
Magnesium
µg/L
657
1270
3540
1480
2900
3740
3260
3500
3150
4800
1670
8
NE
NE
NE
Potassium
µg/L
653
971
438
259
253
446
896
1320
409
538
777
31
NE
NE
NE
Sodium
µg/L
841
6530
3460
3730
1230
3850
6520
4660
3550
5120
1790
17
NE
NE
NE
Notes:
(1) Samples were collected by Duke Energy Groundwater Sciences Group.
(2) MDL refers to the laboratory Method Detection Limit.
(3) SWS Groundwater Protection Standard (GWPS) refers to the North Carolina Groundwater Protected Standards calculated by North Carolina Department of Environmental Quality (NCDEQ), Solid Waste Section (SWS) for constituents with no
established 15A NCAC 2L Standard (last amended on October 15, 2018).
(4) 15A NCAC 2L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards (last amended on April 1, 2022).
(5) Federal Maximum Contaminant Level (MCL) as found in National Primary Drinking Water Regulations, 40 CFR, Subpart G, §141.62.
(6) * Concentration listed is a secondary MCL (MCL) as found in National Secondary Drinking Water Regulations, 40 CFR, Subpart A, §143.3.
(7) NE = Not Established.
(8) Yellow highlighted cells indicate concentrations equal to or greater than the 15A NCAC 2L Standard (for pH yellow highlighting indicates a measurement outside the 15A NCAC 2L range).
(9) Bolded values indicate concentrations equal to or greater than the Federal MCL (for pH bolded values indicate a measurement outside of the Federal MCL range)
(10) J = estimated concentrations which are greater than the MDL but are less than the laboratory Method Reporting Limit (MRL).
(11) B = constituent detected within laboratory method blank.
(12) H = samples analyzed outside of hold time due to laboratory instrumentation error.
(13) U = constituent detected at or below the laboratory MDL.
(14) SU = Standard Units.
05) µU/cm = micromhos per centimeter.
(16) °C = degrees Celsius.
(17) µg/L = micrograms per liter.

Table 5: Results that Equal or Exceed 15A NCAC 2L Groundwater Standards
Landfill No. 2 (Synthetically Lined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station I' I
S&ME Project No: 21350075, Ph. 05
Notes•
(1) 15A NCAC 2L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards (last amended on April 1, 2022).
(2) Historical Concentration Range based on data in Duke Energy Carolinas, LLC (Duke Energy) analytical results database.
(3) SU = Standard units.
(4) pg/L = micrograms per liter.

Table 6: Surface Water Field and Analytical Results
Landfill No. 2 (Synthetically Lined) Permit No. 6004-INDUS _
Duke Energy Carolinas McGuire Nuclear Station I 1
S&ME Project No: 21350075, Ph. 05
Parameter
leld Parameters
June 28, 20="�
MDL
Field pH SU
7.19
6.86
- - - 6.0 - 9.0
6.5 - 8.5*
Specific Conductance PO/Cm
95
98
- - - NE
NE
Temperature °C
21.91
21.51
- - - NE
NE
•
aw1
r
Volatile Organic Compounds were not detected during the June 2022 Sampling Event
TPH-DRO µg/L 150 BJ 170 BJ 130 NE NE
Alkalinity (CaCo,,) µg/L 62 H 62 H 1700 NE NE
Chloride µg/L 2300 2300 15.4 230000 250000*
Sulfate µg/L 960
,Mercury Method EPA 7470A WEEM1111MIll'
Mercury was not detected during the June 2022
Total Recoverable Metals Method SW .• •:
Arsenic µg/L 0.319 J
2300 42.8 250000 250000*
Sampling Event
0.176 J 0.111 10 10
Arsenic, dissolved
µg/L 0.195 J
0.162 J 0.111 150
10
Chromium
µg/L 0.786 J
0.625 J 0.185 183A
100
Lead
µg/L 0.433 J
0.124 J 0.037 14A
15
Lead, dissolved
µg/L 0.065 J
0.037 U 0.037 0.54A
15
Total Recoverable Metals Method SW • •D
Barium
µg/L
28
24
2
1000
2000
Calcium
µg/L
12400
1300
12
NE
NE
Magnesium
µg/L
4770
4760
8
NE
NE
Potassium
µg/L
1110
1320
31
NE
NE
Sodium
µg/L
5850
6000
17
NE
NE
Notes:
(1) Samples were collected by Duke Energy Groundwater Sciences Group.
(2) MDL refers to the laboratory Method Detection Limit.
(3) 15A NCAC 2B Standard (last amended on July 26, 2021) refers to 15A NCAC 02B 0.0211 Fresh Surface Water Quality
Standards for Class C Waters, and 15A NCAC 02B 0.0216 - Fresh Surface Water Quality Standards for Class WS-IV Waters.
(4) Federal Maximum Contaminant Level (MCL) as found in National Primary Drinking Water Regulations, 40 CFR, Subpart
G, §141.62.
(5) * Concentration listed is a secondary MCL (MCL) as found in National Secondary Drinking Water Regulations, 40 CFR,
Subpart A, §143.3.
(6) A = Hardness -dependent 15A NCAC 2B Standards derived using equations specified in the 15 NCAC 02B Standards
Table (last amended on July 26, 2021). The values shown rely upon an assumed in -stream default hardness of 25
milligrams per liter (mg/L) for the chronic standard. An exceedance of the criterion shown does not establish that an in -
steam exceedance has occurred.
(7) NE = Not Established.
(8) J = estimated concentrations which are greater than the MDL but are less than the laboratory Method Reporting Limit
(MRL).
(9) B = constituent detected within laboratory method blank.
(10) H = samples analyzed outside of hold time due to laboratory instrumentation error.
(11) U = constituent detected at or below the laboratory MDL.
(12) SU = Standard Units.
(13) µU/cm = micromhos per centimeter.
(14) °C = degrees Celsius.
(15) µg/L = micrograms per liter.

Table 7: Leachate Field and Analytical Results
Landfill No. 2 (Synthetically Lined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 21350075, Ph. 05
Parameter Units June 28, 2022
Field Parameters Leachate Pond
Field pH SU 7.34
Specific Conductance µO/cm 877
Temperature °C 20.22
EPA Appendix I Volatile Organic Compounds Method 8260B and 8260B Sl
Volatile Organic Compounds were not detected during the June 2022 Sampling Event
TPH-DRO
µg/L
4700 B
Alkalinity (CaCO3) mg/L 350
Chloride mg/L 58000
Sulfate mg/L 30000
Mercury was not detected during the June 2022 Sampling Event
Tota Recoverable Metals Method SW .0i
Arsenic µg/L 0.325 J
Chromium
µg/L
0.323 J
Lead
µg/L
0.04 J
Selenium
Total Recoverable Metals Method SW .�
Barium
µg/L
mg/L
0.224 J
106
Calcium
mg/L
98700
Magnesium
mg/L
17400
Potassium
mg/L
11800
Sodium
mg/L
1 59000
Notes:
(1) Samples were collected by Duke Energy Groundwater Sciences Group.
(2) J = estimated concentrations which are greater than the laboratory Method Detection Limit (MDL) but are less than the
laboratory Method Reporting Limit (MRL).
(3) B = constituent detected within laboratory method blank.
(4) SU = Standard Units.
(5) µZi/cm = micromhos per centimeter.
(6) °C = degrees Celsius.
(7) µg/L = micrograms per liter.
(8) mg/L = milligrams per liter.

Table 8: Radiological Analytical Results
Landfill No. 2 (Synthetically Lined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
S&ME Project No: 21350075, Ph. 05
Radiological D.
Measured in
Liter (pCi/L)
Alpha
0.795
< 0.456
0.564
-040ML.m
0.529
< 0.456
< 0.456
< 0.456
< 0.456
��Ei
mmwpqp-1
< 0.457
< 0.456
O.
< 0.554
SVFRWO
< 0.554
< 0.554
Leachate
Pond
0.702
Ba-La-140
< 5.79
<
5.97
<
7.42
< 6.36
< 7.27
<
4.01
< 7.06
< 5.18
<
7.22
<
5.81
< 5.58
< 8.73
< 6.64
< 6.48
Be7
< 41.4
<
37.9
<
44.8
< 39.0
< 37.0
<
50.1
< 44.5
< 43.7
<
46.7
<
40.4
< 47.8
< 41.0
< 52.0
< 44.3
Beta
4.64
<
3.25
4.84
3.52
< 3.25
<
3.25
< 3.25
< 3.25
4.36
<
3.25
< 3.21
< 3.21
3.21
13.0
Co58
< 5.37
<
5.54
<
5.29
< 5.55
< 6.16
<
4.59
< 5.46
< 7.10
<
6.94
<
5.91
< 4.78
< 4.69
< 6.29
< 5.56
Co60
< 6.83
<
5.94
<
7.02
< 7.37
< 7.96
<
4.44
< 6.64
< 7.62
<
5.92
<
5.78
< 7.19
< 7.01
< 5.50
< 4.92
Cs134
< 6.27
<
6.89
<
7.63
< 8.55
< 7.71
<
8.02
< 5.30
< 6.04
<
7.29
<
6.67
< 7.33
< 7.10
< 7.29
< 6.67
Cs137
< 4.21
<
6.16
<
6.16
< 7.16
< 6.05
<
5.80
< 6.35
< 4.60
<
6.83
<
4.21
< 6.54
< 5.97
< 6.52
< 5.96
Fe59
< 11.2
<
9.95
<
9.81
< 7.08
< 7.17
<
10.8
< 13.2
< 9.36
<
12.0
<
13.0
< 9.62
< 12.7
< 12.5
< 12.1
Tritium (H3GW)
< -110
< -94
< -55
< -47
< -94
< -88
< -50
< -110
<
9.44
< -76
< -92
< -85
< -49
754
1131
< 5.81
<
5.71
<
5.82
< 6.23
1 < 5.91
<
5.76
< 6.45
1 < 6.35
<
7.62
<
5.95
< 6.85
< 7.80
< 6.60
6.24
K40
135
228
102
< 128
79.6
195
113
159
221
76.6
162
133
245
189
Mn54
< 4.99
<
6.30
<
5.14
< 6.17
< 6.86
<
5.27
< 5.23
< 5.77
<
6.31
<
5.76
< 6.01
< 4.42
< 6.65
< 5.58
Nb95
< 5.73
<
5.18
<
6.14
< 6.21
< 5.98
<
5.66
< 5.08
< 6.13
<
6.74
<
5.57
< 5.38
< 6.11
< 6.90
< 5.61
Zn65
< 12.0
<
14.4
<
11.7
< 13.5
< 13.5
<
10.2
< 10.2
< 11.1
<
14.4
<
12.0
< 10.2
< 12.4
< 11.7
< 13.0
Zr95
< 6.98
<
11.2
<
10.5
< 8.91
< 12.4
<
9.13
< 9.07
< 11.5
1 <
11.5
1 <
8.63
< 9.04
1 < 11.3
1< 10.9
1 < 8.63
Notes.•
(1) pG/L = picocuries per liter
(2) < = less than

Appendix III - Field Sampling Forms

FIELD SAMPLING CALIBRATION FORM
STUDY:
MCGUIRE NUCLEAR STATION - NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
DATE (s):
June 28, 2022
SURFACE UNIT READER: EHS
COLLECTORS: EHS
SURFACE UNIT SERIAL M 950
ANALYZER MODELM ST MP
ANALYZER SERIAL M 877813
OTHER EQUIPMENT: TURIBIDIMETER NO.3 - WR-00070
WEATHER CONDITIONS:
60s-80s, overcast
HYDROLAB PROCEDURE #: 3210.7 VALIDATED BY:
EHS 6/29/22
Calibration Date / Time
DATE: 28-Jun-22
TIME: 7:00
DATE: 29-Jun-22
TIME: 7:00
CALIBRATION BP (mmHg)
739.52
CALIBRATION BP (mmHg)
742.17
Calibation
Instrument
Standard
Instrument
Standard
Parameter
Calibration Results
Calibration Results
Standard
Value
Value
Value
Value
SS
0.0 -►
0.0
INSTRUMENT ZEROED
0.0 -/-►
0.0
INSTRUMENT ZEROED
SPEC. COND.
SS
709.9 -►
720
CALIBRATION ACCEPTED
712.0 -►
720
CALIBRATION ACCEPTED
(US/cm)
SS
226.6 -/-►
227
CALIBRATION ACCEPTED
227.9 -/-►
227
1 CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
SS
-/-►
1410
-/-►
1410
CHECK (uS/cm)
SS
B (7.00)
7.05 -►
7.01
CALIBRATION ACCEPTED
7.02 -►
7.01
CALIBRATION ACCEPTED
pH
B (4.00)
4.00 -►
4.00
CALIBRATION ACCEPTED
4.00 -►
4.00
CALIBRATION ACCEPTED
(units)
B (10.00)
10.05 -/-►
10.03
CALIBRATION ACCEPTED
10.05 -/-►
10.03
CALIBRATION ACCEPTED
Buffer Temp.
21.52
Buffer Temp.
21.52
pH Check
B (7.00)
-►
Buffer Temp.
7.13
0.00
Time:
❑
441 -►
438
CALIBRATION ACCEPTED
435 -►
438
CALIBRATION ACCEPTED
ORP
N/A -/-►
N/A
N/A -/-►
N/A
Zobell's
ORP Temp.
21.12
ORP Temp.
21.23
0
TEMP(C°)
21.09
21.25
BP (mmHg)
739.52
742.17
COND
0.00
0.00
DO
100 % mg/L
8.70 -►
8.65
CALIBRATION ACCEPTED
8.72 -►
8.66
CALIBRATION ACCEPTED
(mg/L)
After Cal
8.68
100.30
After Cal % SAT
8.69
100.37
After Cal % SAT
LCS
8.68
100.30
CALIBRATION PASS
8.69
100.37
CALIBRATION PASS
LCSD
8.68
0.00
CALIBRATION PASS
8.69
0.00
CALIBRATION PASS
0 TURB
(ntu)
SS
10.0 -/-►
10.0
CALIBRATION ACCEPTED
9.9 -/-►
10.0
CALIBRATION ACCEPTED
Temp Cert Device #
TEMP
NISI
N/A -/-►
N/A
Adjustment Not Available
N/A -/-►
N/A
Adjustment Not Available
(deg C)
INSTRUMENT MAINTENANCE
DATE / TIME
Conductance Subsystem
pH Subsystem
❑
Cleaned Electrodes
❑ Cleaned Electrodes
❑
Tested - OK
❑ Replaced ref Electrode KCL
❑
See Notes
❑ Replaced Ref. Electrode
Tip
❑ Tested - OK
❑ See Notes
Oxidation Reduction Subsystem
Temperature Subsystem
❑
Cleaned Electrode
❑ Cleaned Electrode
❑
Tested - OK ❑
See Notes
❑ Tested - OK ❑
See Notes
Dissolved Oxygen Subsystem
❑
Replaced Teflon Membrane
❑ Cleaned Electrode
❑
Replaced DO electrolyte
❑ See Notes
Field Barometric Pressure
Beginning BP
(mmHg)
Ending BP
(mmHg)
KEY:
B = Buffer
LCS = Lab Control Standard -► = Adjusted To
SS = Standard solution
LCSD = Lab Control Standard Duplicate -/-►= Not Adjusted To
N/A = Not Applicable
W = Winkler
BP = Barometric Pressure
AW = Average Winkler
NOTES:
LOT #: E1721 B, K2820A, 202905, 260263, 205284, 2062

FIELD SAMPLING CALIBRATION FORM
STUDY:
MCGUIRE NUCLEAR STATION - NUCLEAR LANDFILL 2 GROUNDWATER MONITORING
PROGRAM
DATE (s):
June 28-29, 2022
SURFACE UNIT READER: CJZ, EHS
COLLECTORS:
CJZ, EHS
SURFACE UNIT SERIAL #: 3329
ANALYZER MODEL#:
ST MP
ANALYZER SERIAL #: 763574
OTHER EQUIPMENT:
TURBIDIMETER NO.5 - WR-00070
WEATHER CONDITIONS:
60s-80s, overcast
EHS 6/29/22
HYDROLAB PROCEDURE #: 1
3210.7
VALIDATED BY:
Calibration Date / Time
DATE: I 28-Jun-22
TIME: 8:00
DATE: 29-Jun-22
TIME: 7:45
CALIBRATION BP (mmHg)
747.77
CALIBRATION BP (mmHg)
748.98
Calibation
Instrument
Standard
Instrument
Standard
Parameter
Calibration Results
Calibration Results
Standard
Value
Value
Value
Value
SS
0.0 -►
0.0
INSTRUMENT ZEROED
0.0 -/-►
0.0
INSTRUMENT ZEROED
SPEC. COND.
SS
1414.5 -►
1410
CALIBRATION ACCEPTED
1417.1 -►
1410
CALIBRATION ACCEPTED
(US/cm)
SS
229.2 -/-►
227
1 CALIBRATION ACCEPTED
228.0 -/-►
227
CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
SS
-/-►
1410
-/-►
1410
CHECK (uS/cm)
SS
B (7.00)
7.08 -►
7.01
CALIBRATION ACCEPTED
7.05 -►
7.01
CALIBRATION ACCEPTED
pH
B (4.00)
3.94 -►
4.00
CALIBRATION ACCEPTED
4.08 -►
4.00
CALIBRATION ACCEPTED
(units)
B (10.00)
10.10 -/-►
10.03
CALIBRATION ACCEPTED
10.07 -/-►
10.02
CALIBRATION ACCEPTED
Buffer Temp.
22.40
Buffer Temp.
23.07
pH Check
B (7.00)
7.06 -►
Buffer Temp.
7.01
22.55
Calibration Accepted
Time:
❑
436 -►
435
CALIBRATION ACCEPTED
436 -►
435
CALIBRATION ACCEPTED
ORP
N/A _/-►
N/A
N/A -/-►
N/A
Zobell's
ORP Temp.
22.51
ORP Temp.
22.51
0
TEMP (Co)
22.25
23.36
BP (mmHg)
747.77
748.98
COND
0.00
0.00
DO
100 % mg/L
8.44 -►
8.56
CALIBRATION ACCEPTED
8.39 -►
8.39
CALIBRATION ACCEPTED
(mg/L)
After Cal
8.50
99.32
After Cal % SAT
8.39
99.96
After Cal % SAT
LCS
8.50
99.32
CALIBRATION PASS
8.39
99.96
CALIBRATION PASS
LCSD
8.50
0.00
CALIBRATION PASS
8.39
0.00
CALIBRATION PASS
0 TURB
(ntu)
SS
10.0 -/-►
10.0
CALIBRATION ACCEPTED
10.0 -/-0-10.0
CALIBRATION ACCEPTED
Temp Cert Device #
TEMP
NISI
N/A -/-0-N/A
Adjustment Not Available
N/A -/-►
N/A
Adjustment Not Available
(deg C)
INSTRUMENT MAINTENANCE
DATE / TIME
Conductance Subsystem
pH Subsystem
❑
Cleaned Electrodes
❑ Cleaned Electrodes
❑
Tested - OK
❑ Replaced ref Electrode KCL
❑
See Notes
❑ Replaced Ref. Electrode Tip
❑ Tested - OK
❑ See Notes
Oxidation Reduction Subsystem
Temperature Subsystem
❑
Cleaned Electrode
❑ Cleaned Electrode
❑
Tested - OK
❑
See Notes
❑ Tested - OK ❑
See Notes
Dissolved Oxygen Subsystem
❑
Replaced Teflon Membrane
❑ Cleaned Electrode
❑
Replaced DO electrolyte
❑ See Notes
Field Barometric Pressure
Beginning BP
(mmHg)
Ending BP
(mmHg)
KEY
B = Butter
= Lab ControlStandard -► _ Adjusted To
SS = Standard solution
LCSD = Lab Control Standard Duplicate -/-►= Not Adjusted To
N/A = Not Applicable
W = Winkler
BP = Barometric Pressure
AW = Average Winkler
NOTES:

FIELD SAMPLING CALIBRATION FORM
STUDY:
MCGUIRE NUCLEAR STATION - NUCLEAR LANDFILL 2 GROUNDWATER MONITORING
PROGRAM
DATE (s):
June 28-29, 2022
SURFACE UNIT READER: CJZ, EHS
COLLECTORS:
CJZ, EHS
SURFACE UNIT SERIAL #: 3329
ANALYZER MODEL#:
ST MP
ANALYZER SERIAL #: 763574
OTHER EQUIPMENT:
TURBIDIMETER NO.5 - WR-00070
WEATHER CONDITIONS:
60s-80s, overcast
EHS 6/29/22
HYDROLAB PROCEDURE #: 1
3210.7
VALIDATED BY:
Calibration Date / Time
DATE: I 29-Jun-22
TIME: 7:45
DATE: 29-Jun-22
TIME: 11:15
CALIBRATION BP (mmHg)
748.98
CALIBRATION BP (mmHg)
749.20
Calibation
Instrument
Standard
Instrument
Standard
Parameter
Calibration Results
Calibration Results
Standard
Value
Value
Value
Value
SS
0.0 -/-►
0.0
INSTRUMENT ZEROED
0.0 -/-►
0.0
INSTRUMENT ZEROED
SPEC. COND.
SS
1417.1 -►
1410
CALIBRATION ACCEPTED
1411.0 -/-►
1410
CALIBRATION ACCEPTED
(US/cm)
SS
228.0 -/-►
227
1 CALIBRATION ACCEPTED
226.5 -/-►
227
CALIBRATION ACCEPTED
Specifc conductance checkpoint (used if sampled well is outside of initial calibration range).
SPEC. COND.
SS
-/-►
1410
-/-►
1410
CHECK (uS/cm)
SS
B (7.00)
7.05 -►
7.01
CALIBRATION ACCEPTED
7.04 -/-►
7.00
CALIBRATION ACCEPTED
pH
B (4.00)
4.08 -►
4.00
CALIBRATION ACCEPTED
4.01 -/-►
4.00
CALIBRATION ACCEPTED
(units)
B (10.00)
10.07 -/-►
10.02
CALIBRATION ACCEPTED
10.03 -/-►
10.00
CALIBRATION ACCEPTED
Buffer Temp.
23.07
Buffer Temp.
25.10
pH Check
B (7.00)
7.04 -►
Buffer Temp.
7.01
23.11
Calibration Accepted
Time:
❑
436 -►
435
CALIBRATION ACCEPTED
427.4 -/-►
428
CALIBRATION ACCEPTED
ORP
N/A _/-►
N/A
N/A -/-►
N/A
Zobell's
ORP Temp.
22.51
ORP Temp.
25.60
0
TEMP (Co)
23.36
25.33
BP (mmHg)
748.98
749.20
COND
0.00
0.00
DO
100 % mg/L
8.39 -►
8.39
CALIBRATION ACCEPTED
8.11 -/-►
8.09
CALIBRATION ACCEPTED
(mg/L)
After Cal
8.39
99.96
After Cal % SAT
8.10
100.09
After Cal % SAT
LCS
8.39
99.96
CALIBRATION PASS
8.10
100.09
CALIBRATION PASS
LCSD
8.39
0.00
CALIBRATION PASS
8.10
0.00
CALIBRATION PASS
0 TURB
(ntu)
SS
10.0 -/-►
10.0
CALIBRATION ACCEPTED
10.0 -/-►
10.0
CALIBRATION ACCEPTED
Temp Cert Device #
TEMP
NISI
N/A -/-0-N/A
Adjustment Not Available
N/A -/-►
N/A
Adjustment Not Available
(deg C)
INSTRUMENT MAINTENANCE
DATE / TIME
Conductance Subsystem
pH Subsystem
❑
Cleaned Electrodes
❑ Cleaned Electrodes
❑
Tested - OK
❑ Replaced ref Electrode KCL
❑
See Notes
❑ Replaced Ref. Electrode Tip
❑ Tested - OK
❑ See Notes
Oxidation Reduction Subsystem
Temperature Subsystem
❑
Cleaned Electrode
❑ Cleaned Electrode
❑
Tested - OK
❑
See Notes
❑ Tested - OK ❑
See Notes
Dissolved Oxygen Subsystem
❑
Replaced Teflon Membrane
❑ Cleaned Electrode
❑
Replaced DO electrolyte
❑ See Notes
Field Barometric Pressure
Beginning BP
(mmHg)
Ending BP
(mmHg)
KEY
B = Butter
= Lab ControlStandard -► _ Adjusted To
SS = Standard solution
LCSD = Lab Control Standard Duplicate -/-►= Not Adjusted To
N/A = Not Applicable
W = Winkler
BP = Barometric Pressure
AW = Average Winkler
NOTES:

DUKE DUKE ENERGY 4n DUKE
ENERGYGROUNDWATER MONITORING DATA SHEET ENERGY.
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
CJZ, EHS
SAMPLING DATE(s) 28-Jun-2022 I 29-Jun-2022
WELL/LOCATION NAME
MW-5R
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
767.38
MIDDLE OF WETTED SCREEN (ft toc) 68.64
WELL DEPTH (ft TOC)
76.35
�GSELEV (ft msl)
764.93
PUMP INTAKE DEPTH (ft TOC) 75.35
SCREEN LENGTH (ft)
17
ELEV REF
I NAVD 88
SCREEN INTERVAL (ft TOC) 59.35 TO 76.35
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
SAMPLING EQUIPMENT QED 1200 TUBING DIAMETER (in) 1/2 OD
PUMP CONTROLLER SETTINGS
PRESSURE 1 45 (psi) RECHARGE 1 10 (sec) I DISCHARGE 10 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL 11
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
60.92
WATER COLUMN (ft)
15.43
WATER ELEVATION (ft msl)
706.46
WELL VOLUME I (gal)
2.52
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
DRIP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELLVOL
(recalculates on
current water level)
13:51
62.33
330
24.90
86
7.89
2.7
374
7.18
N/A
13:54
1 62.33
330
20.71
15
7.54
1.9
394
7.64
N/A
13:57
62.33
330
19.86
13
7.59
1.9
398
7.70
N/A
14:00
62.33
330
19.55
13
7.57
2.0
400
7.71
N/A
DRAW -DOWN
1.41
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.25
(gal)
SAMPLE COLLECTED BY
CJZ
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
2.05
(gal)
1 6/28/2022 @ 1405
0
Samp a EHS 6/29/22 preservation verified to pH
QC By: < ?
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA O1-13 ❑BORON ❑SR 89/90 EIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 0504,CL ❑ALPHA SPEC
OMETALS 2F_ALK ❑CO2 ❑RSK 175 OVOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: I NO
VVELL CAPS
Well cap in good conditon
VVELL CASING
Good Condition
4CCESS TO WELLS
Access cleared into well
PROTECTIVE CASING
Casing in good condition
FLUSH MOUNT WELLS
VVELL TAG
4CCESS AROUND WELL
VVELL SECURITY
VVELL LOCK CONDITION
Well tag in good condition
Access cleared around well
Well found locked
Lock in good condition
SAMPLING NOTES

DUKE DUKE ENERGY 4n DUKE
ENERGYGROUNDWATER MONITORING DATA SHEET ENERGY.
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
CJZ, EHS
SAMPLING DATE(s) 28-Jun-2022 I 29-Jun-2022
WELL/LOCATION NAME
MW-5A
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
768.42
MIDDLE OF WETTED SCREEN (ft toc) 89.00
WELL DEPTH (ft TOC)
96.00
GS ELEV (ft msl)
766.45
PUMP INTAKE DEPTH (ft TOC) 95.00
SCREEN LENGTH (ft)
14
ELEV REF
NGVD 27
SCREEN INTERVAL (ft TOC) 82.00 TO 96.00
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE 1 10 (sec) I DISCHARGE 10 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL 11
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
62.35
WATER COLUMN (ft)
33.65
WATER ELEVATION (ft msl)
706.07
WELL VOLUME (gal)
5.49
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
DRIP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELLVOL
(recalculates on
current water level)
12:30
65.22
300
21.44
48
7.41
0.9
323
8.63
N/A
12:33
65.90
300
19.26
43
7.38
1.2
335
7.94
N/A
12:36
65.90
300
18.88
42
7.38
0.8
341
7.89
N/A
12:39
65.90
300
18.76
42
7.37
1.2
343
7.86
N/A
DRAW -DOWN
3.55
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.20
(gal)
SAMPLE COLLECTED BY
CJZ
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
1.95
(gal)
6/28/2022 @ 1240
0
Samp a EHS 6/29/22 preservation verified to pH
QC By: < ?
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA O1-13 ❑BORON ❑SR 89/90 EIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 0504,CL ❑ALPHA SPEC
OMETALS 2F_ALK ❑CO2 ❑RSK 175 OVOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: I NO
VVELL CAPS
Well cap in good conditon
VVELL CASING
Good Condition
4CCESS TO WELLS
Access cleared into well
PROTECTIVE CASING
Casing in good condition
FLUSH MOUNT WELLS
VVELL TAG
4CCESS AROUND WELL
VVELL SECURITY
VVELL LOCK CONDITION
Well tag in good condition
Access cleared around well
Well found locked
Lock in good condition
SAMPLING NOTES

DUKE DUKE ENERGY
EMERY GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR EQUIPMENT PURGE ONLY SAMPLING
DUKE
ENERGY
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
CJZ, EHS
� � p
SAMPLING DATE(s) 28-Jun-2022 29-Jun-2022
WELL/LOCATION NAME
MW-6
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
728.45
MIDDLE OF WETTED SCREEN (ft toc)
34.70
WELL DEPTH (ft TOC)
37.20
GS ELEV (ft msl)
726.79
PUMP INTAKE DEPTH (ft TOC)
36.20
SCREEN LENGTH (ft)
14
ELEV REF
NGVD 27
SCREEN INTERVAL (ft TOC) 23.20 TO 37.20
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
SAMPLING EQUIPMENT
QED T1200
TUBING DIAMETER (in)
1/2 OD
PUMP CONTROLLER SETTINGS
PRESSURE 1 20 (psi) RECHARGE 1 10 1 (sec) I DISCHARGE 10 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICKUP WELL
MONITORING WELL Ell
NUCLEAR LANDFILL
Equip. Only Purge
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ftTOC)
32.20
WATER COLUMN (ft)
5.00
WATER ELEVATION (ft msl)
696.25
11WELL
VOLUME (gal)
0.82
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
INITIAL
WATER LEVEL
(ft)
FLOW
RATE
(ml/min)
FINAL
WATER LEVEL
(ft)
TEMP
(degC)
SPECIFIC
COND.
(umho/cm)
pH
(SU)
TURBIDITY
(NTU)
ORP
(mV-NEH)
DISSOLVED
OXYGEN
(mg/L)
32.20
420
33.41
21.13
34
5.98
3.6
351
7.70
N/A
If Evacuated And It Is Requiered To Return To Sample, Enter The Date, Time, And
Water Level To The Right Before Sampling to Determine Recharge.
DATE:
TIME:
WATER LEVEL:
Well Vol.:
Evacuated:
N/A
N/A
Sample:
Tubing Volume
786
(ml) INITIAL PURGE VOL. EQUIPMENT PURGE ONLY SAMPLE
CHLORINE (mg/1)
Pump (Bladder) Volume
495
(ml) 0.50 SAMPLE COLLECTED BY
(ml) I — 1 0.34 1 (gal) I CJZ
DATE TIME
Total Purge Volume
1281
6/29/2022 @ 1015
1 NA
:CtC:By]F--
EHS 6/29/22
Sample preservation verified to pH
< 2.0
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA 21-13 ❑BORON ❑SR 89/90 OGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 0504,CL ❑ALPHA SPEC
OMETALS OF_ALK ❑CO2 ❑RSK 175 OVOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION
.L PAD
Good Condition
.L CAPS
Well cap in good conditon
.L CASING
Good Condition
ESS TO WELLS
Access cleared into well
TECTIVE CASING
Casing in good condition
iH MOUNT WELLS
.L TAG
Well tag in good condition
ESS AROUND WELL
Access cleared around well
.L SECURITY
Well found locked
.L LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION NOTES
Itins: I NO

DUDE DUKE ENERGY ! DUKE
ENERGY GROUNDWATER MONITORING DATA SHEET ENERGY:
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
CJZ, EHS
SAMPLING DATE(s) 28-Jun-2022 I 29-Jun-2022
WELL/LOCATION NAME
MW-6A
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
728.98
MIDDLE OF WETTED SCREEN (ft toc) 40.90
WELL DEPTH (ft TOC)
47.90
GS ELEV (ft msl)
727.54
PUMP INTAKE DEPTH (ft TOC) 46.90
SCREEN LENGTH (ft)
14
ELEV REF
NGVD 27::j
SCREEN INTERVAL (ft TOC) 33.90 TO 47.90
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE 1 10 (sec) I DISCHARGE 10 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL 11
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
31.50
WATER COLUMN (ft)
16.40
WATER ELEVATION (ft msl)
697.48
WELL VOLUME (gal)
2.67
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
DRIP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (ga0
WELLVOL
(recalculates on
current water level)
10:29
32.40
330
19.34
55
5.88
3.4
371
7.71
N/A
10:32
1 32.40
330
1 18.70
47
5.45
2.8
375
7.80
N/A
10:35
32.40
330
18.42
48
5.42
3.0
375
7.69
N/A
10:38
32.40
330
18.39
48
5.40
3.1
377
7.64
N/A
DRAW -DOWN
0.90
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.20
(gal)
SAMPLE COLLECTED BY
CJZ
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
2.00
(gal)
1 6/29/2022 @ 1040
0
Samp a EHS 6/29/22 preservation verified to pH
QC By: < ?
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA O1-13 ❑BORON ❑SR 89/90 EIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 05O4,CL ❑ALPHA SPEC
OMETALS 2F_ALK ❑CO2 ❑RSK 175 OVOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, 5O4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: I NO
VVELL CAPS
Well cap in good conditon
VVELL CASING
Good Condition
4CCESS TO WELLS
Access cleared into well
PROTECTIVE CASING
Casing in good condition
FLUSH MOUNT WELLS
VVELL TAG
4CCESS AROUND WELL
VVELL SECURITY
VVELL LOCK CONDITION
Well tag in good condition
Access cleared around well
Well found locked
Lock in good condition
SAMPLING NOTES

'f� DUKE DUKE ENERGY DUKE
� ENERGY GROUNDWATER MONITORING DATA SHEET ENER+C
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(5)
28-Jun-2022 a LJ El
WELL/LOCATION NAME
MW-7R
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
726.16
723.53
I NAVD 88
MIDDLE OF WETTED SCREEN (ft toc)
41.50
WELL DEPTH (ft TOC)
48.89
GS ELEV (ft msl)
PUMP INTAKE DEPTH (ft TOC)
47.89
SCREEN LENGTH (ft)
15
ELEV REF
SCREEN INTERVAL (ft TOC) 33.89 1 TO 48.89
EQUIPMENT INFORMATION
LEVEL METER SERIAL# 1091-T2
SAMPLING EQUIPMENT QED 1200 TUBING DIAMETER (in) 1/2 OD
PUMP CONTROLLER SETTINGS
PRESSURE I (psi) I RECHARGE I (sec) I DISCHARGE I (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
34.10
WATER COLUMN (ft) 14.79
WATER ELEVATION (ft msl)
692.06
WELL VOLUME (gal) 2.41
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
TEMP
(deg Q
SPECIFIC
COND.
(umho/cm)
❑
pH
(Su)
❑
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
12:40
34.85
280
18.35
46
5.70
4.3
361
7.71
N/A
12:43
1 34.85
280
18.35
46
5.70
3.4
366
7.67
N/A
12:46
34.85
280
18.30
47
5.70
3.0
363
7.67
N/A
DRAW -DOWN
0.75
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.00
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
1.45
(gal)
6/28/2022 @ 1250
0
Sample preservation verified to pH
E
EHS 6/29/22 (units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
❑✓ GAMMA 0H3 ❑BORON ❑SR 89/90 ❑✓ GROSS ALPH/BETA ❑Fe 55 ❑Ni 63 [-]IODINE 131 OSO4,CL ❑ALPHA SPEC
❑� METALS ❑� F_ALK ❑CO2 ❑RSK 175 [Z/OC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS 7NC3-N, CL, SC4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
/ELL PAD
Good Condition
/ELL CAPS
Well cap in good conditon
/ELL CASING
Good Condition
CCESS TO WELLS
Access cleared into well
ROTECTIVE CASING
Casing in good condition
-USH MOUNT WELLS
/ELL TAG
Well tag in good condition
CCESS AROUND WELL
Access cleared around well
/ELL SECURITY
Well found locked
/ELL LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION P
II Impacted By Silting: 1 NO

'f� DUKE DUKE ENERGY t DUKE
ENERGY GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s)
28-Jun-2022 =u LJ ElWELL/LOCATION
NAME
MW-7A
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
724.66
MIDDLE OF WETTED SCREEN (ft toc)
52.40
WELL DEPTH (ft TOC)
59.40
GS ELEV (ft msl)
722.74
PUMP INTAKE DEPTH (ft TOC)
58.40
SCREEN LENGTH (ft)
14
ELEV REF
NGVD 27
SCREEN INTERVAL (ft TOC) 45.40 1 TO 59.40
EQUIPMENT INFORMATION
LEVEL METER SERIAL# 0965-T2
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
PUMP CONTROLLER SETTINGS
PRESSURE I (psi) I RECHARGE I (sec) I DISCHARGE I (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
31.87
WATER COLUMN (ft) 27.53
WATER ELEVATION (ft msl)
692.79
WELL VOLUME (gal) :44,::di
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
TEMP
(degQ
SPECIFIC
COND.
(umho/cm)
❑
pH
(Su)
LJ
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
11:39
33.41
360
17.96
113
6.44
9.4
331
7.39
N/A
11:42
1 33.41
360
18.20
114
6.43
8.3
331
7.40
N/A
11:45
33.41
360
18.22
114
6.41
7.8
331
7.39
N/A
DRAW -DOWN
1.54
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.00
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/I)
TOTAL PURGE VOLUME
1.60
(gal)
6/28/2022 @ 1150
0
Sample preservation verified to pH
E
EHS 6/29/22 (units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
❑✓ GAMMA 0H3 ❑BORON ❑SR 89/90 ❑✓ GROSS ALPH/BETA ❑Fe 55 ❑Ni 63 [-]IODINE 131 OSO4,CL ❑ALPHA SPEC
❑� METALS ❑� F_ALK ❑CO2 ❑RSK 175 [Z/OC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS 7NC3-N, CL, SC4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
/ELL PAD
Good Condition
/ELL CAPS
Well cap in good conditon
/ELL CASING
Good Condition
CCESS TO WELLS
Access cleared into well
ROTECTIVE CASING
Casing in good condition
-USH MOUNT WELLS
/ELL TAG
Well tag in good condition
CCESS AROUND WELL
Access cleared around well
/ELL SECURITY
Well found locked
/ELL LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION P
II Impacted By Silting: I NO

DUKE DUKE ENERGY
ENERGY GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR EQUIPMENT PURGE ONLY SAMPLING
DUKE
ENERGY
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
CJZ, EHS
� � p
SAMPLING DATE(s) 28-Jun-2022 29-Jun-2022
WELL/LOCATION NAME
MW-$
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
759.60
MIDDLE OF WETTED SCREEN (ft toc)
66.74
WELL DEPTH (ft TOC)
71.50
GS ELEV (ft msl)
757.30
PUMP INTAKE DEPTH (ft TOC)
70.50
SCREEN LENGTH (ft)
14
ELEV REF
NGVD 27
SCREEN INTERVAL (ft TOC) 57.50 TO 71.50
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
SAMPLING EQUIPMENT
QED T1200
TUBING DIAMETER (in)
1/2 OD
PUMP CONTROLLER SETTINGS
PRESSURE 1 35 (psi) I RECHARGE 1 10 1 (sec) I DISCHARGE 1 10 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICKUP WELL
MONITORING WELL Ell
NUCLEAR LANDFILL
Equip. Only Purge
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ftTOC)
61.98
WATER COLUMN (ft)
9.52
WATER ELEVATION (ft msl)
697.62
11WELL
VOLUME (gal)
1 1.55
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
INITIAL
WATER LEVEL
(ft)
FLOW
RATE
(ml/min)
FINAL
WATER LEVEL
(ft)
TEMP
(degC)
SPECIFIC
COND.
(umho/cm)
pH
(SU)
TURBIDITY
(NTU)
ORP
(mV-NEH)
DISSOLVED
OXYGEN
(mg/L)
61.98
360
64.32
19.89
107
6.48
3.2
366
8.66
N/A
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE:
TIME:
WATER LEVEL:
Well Vol.:
Evacuated:
N/A
N/A
Sampled:
Tubing Volume
1531
(ml) INITIAL PURGE VOL. EQUIPMENT PURGE ONLY SAMPLE
CHLORINE (mg/1)
Pump (Bladder) Volume
495
(ml) 0.60 SAMPLE COLLECTED BY
(ml) — 0.54 (gal) CJZ
DATE TIME
Total Purge Volume
2026
6/28/2022 1 @ 0915
0
:CtC:By]F--
EHS 6/29/22
Sample preservation verified to pH
< 2.0
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA 21-13 ❑BORON ❑SR 89/90 OGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 0504,CL ❑ALPHA SPEC
OMETALS OF_ALK ❑CO2 ❑RSK 175 OVOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION
.L PAD
Good Condition
.L CAPS
Well cap in good conditon
.L CASING
Good Condition
ESS TO WELLS
Access cleared into well
TECTIVE CASING
Casing in good condition
iH MOUNT WELLS
.L TAG
Well tag in good condition
ESS AROUND WELL
Access cleared around well
.L SECURITY
Well found locked
.L LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION NOTES
Itins: I NO

DUKE DUKE ENERGY 4n DUKE
ENERGYGROUNDWATER MONITORING DATA SHEET ENERGY.
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
CJZ, EHS
SAMPLING DATE(s) 28-Jun-2022 I 29-Jun-2022
WELL/LOCATION NAME
MN/-$Ja
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
759.68
MIDDLE OF WETTED SCREEN (ft toc) 77.40
WELL DEPTH (ft TOC)
84.40
GS ELEV (ft msl)
757.6111
PUMP INTAKE DEPTH (ft TOC) 83.40
SCREEN LENGTH (ft)
14
ELEV REF
NGVD 27
SCREEN INTERVAL (ft TOC) 70.40 TO 84.40
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
PUMP CONTROLLER SETTINGS
PRESSURE 1 45 (psi) RECHARGE 1 10 (sec) I DISCHARGE 10 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL 11
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
61.95
WATER COLUMN (ft)
22.45
WATER ELEVATION (ft msl)
697.73
WELL VOLUME (gal)
3.66
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(SU)
❑
TURBIDITY
(NTU)
❑
DRIP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELLVOL
(recalculates on
current water level)
8:35
62.36
390
20.00
82
7.58
0.5
382
6.78
N/A
8:38
62.45
400
18.12
83
6.72
0.7
381
7.36
N/A
8:41
62.45
400
17.76
84
6.69
1.0
380
7.42
N/A
8:44
62.45
400
17.55
84
6.68
0.7
378
7.46
N/A
DRAW -DOWN
0.50
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.60
(gal)
SAMPLE COLLECTED BY
GZ
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
2.55
(gal)
6/28/2022 @ 845
0
Samp a EHS 6/29/22 preservation verified to pH
QC By: < ?
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA O1-13 ❑BORON ❑SR 89/90 EIGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 0504,CL ❑ALPHA SPEC
OMETALS 2F_ALK ❑CO2 ❑RSK 175 OVOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD Good Condition Well Impacted By Silting: I NO
VVELL CAPS
Well cap in good conditon
VVELL CASING
Good Condition
4CCESS TO WELLS
Access cleared into well
PROTECTIVE CASING
Casing in good condition
FLUSH MOUNT WELLS
VVELL TAG
4CCESS AROUND WELL
VVELL SECURITY
VVELL LOCK CONDITION
Well tag in good condition
Access cleared around well
Well found locked
Lock in good condition
UP taken (#1)
SAMPLING NOTES

DUKE DUKE ENERGY
ENERGY GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR EQUIPMENT PURGE ONLY SAMPLING
DUKE
ENERGY
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s)
28-Jun-2022 � F1 p
WELL/LOCATION NAME
MW-9
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
711.87
MIDDLE OF WETTED SCREEN (ft toc)
28.00
WELL DEPTH (ft TOC)
30.80
GS ELEV (ft msl)
710.27
PUMP INTAKE DEPTH (ft TOC)
29.80
SCREEN LENGTH (ft)
14
ELEV REF
NGVD 27
SCREEN INTERVAL (ft TOC) 16.80 TO 30.80
EQUIPMENT INFORMATION
LEVEL METER SERIAL# I 0965-T2
SAMPLING EQUIPMENT
QED T1200
TUBING DIAMETER (in)
1/2 OD
PUMP CONTROLLER SETTINGS
PRESSURE 1 15 (psi) RECHARGE 1 8 (sec) DISCHARGE 7 (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
I WELL USE
PURGE METHOD
STICKUP WELL
MONITORING WELL �ElNUCLEAR
LANDFILL
Equip. Only Purge
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ftTOC)
25.19
WATER COLUMN (ft)
5.61
WATER ELEVATION (ft msl)
1 686.68
11WELL
VOLUME (gal)
0.91
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
INITIAL
WATER LEVEL
(ft)
FLOW
RATE
(ml/min)
FINAL
WATER LEVEL
(ft)
0
TEMP
(deg C)
0
SPECIFIC
COND.
(umho/cm)
0
pH
(SU)
0
TURBIDITY
(NTU)
❑
ORP
(mV -NEH)
❑
DISSOLVED
OXYGEN
(mg/L)
❑
25.19
320
26.09
19.74
99
5.69
3.4
360
3.90
N/A
If Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE:
TIME:
WATER LEVEL:
Well Vol.:
Evacuated:
N/A
N/A
Sample:
Tubing Volume
647
(ml) INITIAL PURGE . EQUIPMENT PURGE ONLY SAMPLE
CHLORINE (mg/I)
Pump (Bladder) Volume
495
(MI) 0.35 SAMPLE COLLECTED BY
(ml) - 0.30 l) EHS
�(g-
DATE TIME
Total Purge Volume
1142
1 6/28/2022 @ 1330
1 0
QC By: I EHS 6/29/22
Sample preservation verified to pH
< 2.0
(units)11
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
❑J GAMMA ❑� H3 ❑BORON ❑SR 89/90 ❑� GROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 ❑� SO4,CL ❑ALPHA SPEC
[,]METALS ❑✓ F_ALK ❑CO2 ❑RSK 175 [�]/OC's ❑TPWDRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION
PAD
Good Condition
CAPS
Well cap in good conditon
CASING
Good Condition
iS TO WELLS
Access cleared into well
=CTIVE CASING
Casing in good condition
I MOUNT WELLS
TAG
Well tag in good condition
iS AROUND WELL
Access cleared around well
SECURITY
Well found locked
LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION NOTES
I Impacted By Silting: I NO

'f� DUKE DUKE ENERGY t DUKE
ENERGY GROUNDWATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR LOW FLOW SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s)
28-Jun-2022 =u LJ ElWELL/LOCATION
NAME
MW-9A
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
712�27
710
NGV
MIDDLE OF WETTED SCREEN (ft toc)
40.80
WELL DEPTH (ft TOC)
47.80
GS ELEV (ft msl)
PUMP INTAKE DEPTH (ft TOC)
46.80
SCREEN LENGTH (ft)
14
ELEV REF
SCREEN INTERVAL (ft TOC) 33.80 1 TO 47.80
EQUIPMENT INFORMATION
LEVEL METER SERIAL# 0965-T2
SAMPLING EQUIPMENT QED T1200 TUBING DIAMETER (in) 1/2 OD
PUMP CONTROLLER SETTINGS
PRESSURE I (psi) I RECHARGE I (sec) I DISCHARGE I (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL
NUCLEAR LANDFILL
Low Flow
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
25.58
WATER COLUMN (ft) 22.22
WATER ELEVATION (ft msl)
686.S5
WELL VOLUME (gal) 3.62
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
TIME
(hh:mm)
WATER
LEVEL
(ft)
FLOWRATE
(ml/min)
TEMP
(deg C)
SPECIFIC
COND.
(umho/cm)
❑
pH
(su)
LJ
TURBIDITY
(NTU)
❑
ORP
(mV-NHE)
❑
DISSOLVED
OXYGEN
(mg/L)
❑ (gal)
WELL VOL
(recalculates on
current water level)
1:48
25.80
330
18.49
115
6.12
3.4
300
4.84
N/A
1:51
1 25.80
330
18.47
114
6.13
2.5
326
4.88
N/A
1:54
25.80
330
18.48
113
6.13
2.1
332
4.94
N/A
DRAW -DOWN
0.22
(ft)
COLLECT SAMPLE - SAMPLE CRITERIA SATISFIED
INITIAL PURGE VOLUME
1.00
(gal)
SAMPLE COLLECTED BY
EHS
DATE TIME
CHLORINE (mg/1)
TOTAL PURGE VOLUME
1.55
(gal)
6/28/2022 @ 1400
0
Sample preservation verified to pH
E
EHS 6/29/22 (units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
❑✓ GAMMA 0H3 ❑BORON ❑SR 89/90 ❑✓ GROSS ALPH/BETA ❑Fe 55 ❑Ni 63 [_]IODINE 131 OSO4,CL ❑ALPHA SPEC
❑� METALS ❑� F_ALK ❑CO2 ❑RSK 175 [Z/OC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS 7NC3-N, CL, SC4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
/ELL PAD
Good Condition
/ELL CAPS
Well cap in good conditon
/ELL CASING
Good Condition
CCESS TO WELLS
Access cleared into well
ROTECTIVE CASING
Casing in good condition
-USH MOUNT WELLS
/ELL TAG
Well tag in good condition
CCESS AROUND WELL
Access cleared around well
/ELL SECURITY
Well found locked
/ELL LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION P
II Impacted By Silting: I NO

DUDE DUKE ENERGY
ENERGY GROUNDWATER MONITORING DATA SHEET
SAMPLING PROCEDURE NO. 3175.4
FOR EQUIPMENT PURGE ONLY SAMPLING
ENERGY
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
CJZ, EHS
SAMPLING DATE(s) 28-Jun-2022 J 29-Jun-2022
WELL/LOCATION NAME
MW-10A
MONITORING WELL INFORMATION
WELL DIAMETER (in)
2.00
TOC ELEV (ft msl)
755.78
MIDDLE OF WETTED SCREEN (ft toc)
55.50
WELL DEPTH (ft TOC)
59.23
GS ELEV (ft msl)
753.87
PUMP INTAKE DEPTH (ft TOC)
58.23
SCREEN LENGTH (ft)
15
ELEV REF
NGVD 27
SCREEN INTERVAL (ft TOC) 44.23 TO 59.23
EQUIPMENT INFORMATION
LEVEL METER SERIAL#
SAMPLING EQUIPMENT
QED T1200
TUBING DIAMETER (in)
1/2 OD
PUMP CONTROLLER SETTINGS
PRESSURE (psi) RECHARGE (sec) DISCHARGE (sec)
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
STICK UP WELL
MONITORING WELL Ell
NUCLEAR LANDFILL
Equip. Only Purge
SAMPLING INFORMATION
INITIAL DEPTH TO WATER (ft TOC)
1 51.76
WATER COLUMN (ft)
7.47
WATER ELEVATION (ft msl)
704.02
WELL VOLUME (gal)
1.22
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
INITIAL
WATER LEVEL
(ft)
FLOW
RATE
(ml/min)
FINAL
WATER LEVEL
(ft)
61 61
TEMP SPECIFIC
COND.
(degC) (umho/cm)
61
pH
(SU)
ICI
TURBIDITY
(NTU)
I
ORP
(mV-NEH)
I I
DISSOLVED
OXYGEN
(mg/L)
I I
51.76
340
53.40
19.55 33
7.80
9.1
365
6.08
N/A
Evacuated And It Is Required To Return To Sample, Enter The Date, Time, And Water
Level To The Right Before Sampling to Determine Recharge.
DATE:
TIME:
WATER LEVEL:
Well Vol.:
Evacuated:
N/A
N/A
Sample:
Tubing Volume
1265
(ml) INITIAL PURGE VOL. EQUIPMENT PURGE ONLY SAMPLE
Pump (Bladder) Volume
495
(ml) 0.50 SAMPLE COLLECTED BY
(ml) — 0.46 (gal) CJZ
DATE TIME
CHLORINE (mg/1)
Total Purge Volume
1760
1 6/29/2022 @ 0840
1 0
::IF-- EHS 6/29/22
Sample preservation verified to pH
(units) 11
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA 2H3 ❑BORON ❑SR 89/90 OGROSS ALPH/BETA ❑Fe 55 ❑Ni 63 ❑IODINE 131 OSO4,CL ❑ALPHA SPEC
OMETALS OF_ALK ❑CO2 ❑RSK 175 OVOC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION
.L PAD
Good Condition
.L CAPS
Well cap in good conditon
.L CASING
Good Condition
ESS TO WELLS
Access cleared into well
TECTIVE CASING
Casing in good condition
iH MOUNT WELLS
.L TAG
Well tag in good condition
ESS AROUND WELL
Access cleared around well
.L SECURITY
Well found locked
.L LOCK CONDITION
Lock in good condition
SAMPLING NOTES
ADDITIONAL WELL CONDITION NOTES
Impacted By Silting: I NO

DUDE DUKE ENERGY DUKE
ENERGY SURFACE WATER MONITORING DATA SHEET ENERGY
SAMPLING PROCEDURE NO. 3175.4
FOR SURFACE WATER SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
SITE ID
N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
EHS
SAMPLING DATE(s)
28-Jun-2022 LJ L
WELL/LOCATION NAME
LEACHATE POND
SURFACE WATER LOCATION
INFORMATION
LOCATION TYPE:
LEACHATE/DRAINAGE
WAS WATER PRESENT:
I YES
WAS THERE A NOTICABLE FLOW: YES
SAMPLING METHOD:
GRAB
LOCATION ENVIRONMENT:
I PIPE
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
ELL USE
PURGE METHOD
EEEH—�-
Surface Water Sample
SAMPLING INFORMATION
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
DEPTH OF
INTAKE
(METERS)
I1
TEMP
(deg C)
I1
SPECIFIC
COND.
(umho/cm)
I1
pH
(SU)
I1
TURBIDITY
(NTU)
A
ORP
(mV-NEH)
A
DISSOLVED
OXYGEN
(mg/L)
11
0.01
20.22
877
7.34
7.0
305
7.29
N/A
FLOW
CONDITIONS:
PIPE DISCHARGE FLOW RATE = Si
SURFACE WATER SAMPLE
CHLORINE (mg/1)
1 0
SAMPLE COLLECTED BY
DATE TIME
EHS
6/28/2022 1 @ 1100
Q:C By: EHS 6/29/22
Sample preservation verified to pH
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
❑s GAMMA 7H3 [-]BORON ❑SR 89/90 [ZGROSS ALPH/BETA ❑Fe 55 [—]Ni 63 (IODINE 131 ❑✓ SO4,CL [-]ALPHA SPEC
[,]METALS ❑i F_ALK ❑CO2 ❑RSK 175 [,/]/OC's ❑TPH-DRO
❑METALS ❑NO3-N, CL, F, SO4, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
WELL PAD
WELL CAPS
WELL CASING
ACCESS TO WELLS
PROTECTIVE CASING
FLUSH MOUNT WELLS
WELL TAG
ACCESS AROUND WELL
WELL SECURITY
WELL LOCK CONDITION
Access cleared into well
Access cleared around well
SAMPLING NOTES
I Impacted By Silting: I NO

DUKE DUKE ENERGY DUKE
ENERGY SURFACE WATER MONITORING DATA SHEET E N E RY
SAMPLING PROCEDURE NO. 3175.4
FOR SURFACE WATER SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
1 SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
CJZ, EHS
� � p
SAMPLING DATE(s) 28-Jun-2022 29-Jun-2022
WELL/LOCATION NAME
SW-1
SURFACE WATER LOCATION
INFORMATION
LOCATION TYPE:
I STREAM
IWAS WATER PRESENT:
I YES
IWAS THERE A NOTICABLE FLOW:
YES
SAMPLING METHOD:
PERISTALTIC PUMP
ILOCATION ENVIRONMENT:
I WOODED
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
NUCLEAR LANDFILL
Surface Water Sample
SAMPLING INFORMATION
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
DEPTH OF
INTAKE
(METERS)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(Su)
o
TURBIDITY
(NTU)
0
ORP
(mV-NEH)
0
DISSOLVED
OXYGEN
(mg/L)
❑
0.01
21.91
95
7.19
34.7
244
7.21
N/A
FLOW
CONDITIONS:
flowing
SURFACE WATER SAMPLE
CHLORINE (mg/I)
0
SAMPLE COLLECTED BY
DATE TIME
CJZ
6/28/2022 @ 1135
QC By: EHS 6/29/22
Sample preservation verified to pH
< 2.0
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA OH3 ❑BORON ❑SR 89/90 OGROSS ALPH/BETA [:]Fe 55 ❑Ni 63 ❑IODINE 131 0504,CL ❑ALPHA SPEC
OMETALS OF_ALK ❑CO2 ❑RSK 175 OVOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, 504, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PAD
CAPS
CASING
iS TO WELLS Access cleared into well
ECTIVE CASING
I MOUNT WELLS
TAG
iS AROUND WELL Access cleared around well
SECURITY
LOCK CONDITION
SAMPLING NOTES
Iting: I NO

DUKE DUKE ENERGY DUKE
ENERGY SURFACE WATER MONITORING DATA SHEET E N E RY
SAMPLING PROCEDURE NO. 3175.4
FOR SURFACE WATER SAMPLING
SITE NAME
MCGUIRE NUCLEAR STATION
PERMIT #
60-04
1 SITE ID
I N/A
PROJECT NAME
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM
FIELD CREW
CJZ, EHS
SAMPLING DATE(s) 28-Jun-2022 29-Jun-2022 p
WELL/LOCATION NAME
$W-2
SURFACE WATER LOCATION
INFORMATION
LOCATION TYPE:
I STREAM
WAS WATER PRESENT:
I YES
WAS THERE A NOTICABLE FLOW:
YES
SAMPLING METHOD:
PERISTALTIC PUMP
LOCATION ENVIRONMENT:
I WOODED
WELL/SAMPLING INFORMATION
WELL TYPE
WELL INFORMATION
WELL USE
PURGE METHOD
NUCLEAR LANDFILL
Surface Water Sample
SAMPLING INFORMATION
DETECTED ODOR
None
ODOR STRENGTH
None
APPEARANCE
Normal
DEPTH OF
INTAKE
(METERS)
❑
TEMP
(deg C)
❑
SPECIFIC
COND.
(umho/cm)
❑
pH
(su)
o
TURBIDITY
(NTU)
0
ORP
(mV -NEH)
0
DISSOLVED
OXYGEN
(mg/L)
❑
0.01
21.51
98
6.86
8.7
274
7.81
N/A
FLOW
CONDITIONS:
flowing
SURFACE WATER SAMPLE
CHLORINE (mg/I)
0
SAMPLE COLLECTED BY
DATE TIME
CJZ
6/28/2022 @ 1020
QC By: EHS 6/29/22
Sample preservation verified to pH
< 2.0
(units)
SAMPLE LIST CHECK IF SAMPLES WERE COLLECTED
OGAMMA OH3 ❑BORON ❑SR 89/90 OGROSS ALPH/BETA [:]Fe 55 ❑Ni 63 ❑IODINE 131 0504,CL ❑ALPHA SPEC
OMETALS OF_ALK ❑CO2 ❑RSK 175 OVOC's OTPH-DRO
❑METALS ❑NO3-N, CL, F, 504, F_ALK ❑TDS
❑METALS ❑NO3-N, CL, SO4 ❑F_ALK ❑TDS/TSS ❑RADIUM 226/228
WELL CONDITION ADDITIONAL WELL CONDITION NOTES
PAD
CAPS
CASING
iS TO WELLS Access cleared into well
ECTIVE CASING
I MOUNT WELLS
TAG
iS AROUND WELL Access cleared around well
SECURITY
LOCK CONDITION
SAMPLING NOTES
Iting: I NO

NORTH CAROLINA GROUNDWATER SAMPLING SITE CHECK LIST
SITE: MCGUIRE NUCLEAR STATION SAMPLE DATE June 28-29, 2022
PROJECT: NUCLEAR LANDFILL 2 GROUNDWATER MONITORING PROGRAM FIELD CREW CJZ, EHS
SITE CONTACT John G. Ballard
WEATHER 6/28/2022 6/29/2022
PAGE 1 OF 1
MW-511
MW-5A
MW-6
MW-6A
MW-711
MW-7A
MW-8
MW-8A
MW-9
MW-9A
MW-10A
SW-1
SW-2
LEACH POND
ACCESS TO WELLS
Access cleared into well
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
Access cleared around well
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
Tall grass or weeds - needs mowing
Road washing out / muddy / needs grading
Fallen tree blocking access
WELL DEPTH
Well impacted by silting
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
N/A
N/A
N/A
WELL SECURITY
Well found locked
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
N/A
N/A
Well found unlocked
WELL LOCK CONDITION
Lock in good condition
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
N/A
N/A
Lock rusted, difficult to open / needs replacing
Replaced damaged lock
WELL CASINGS
Casing in good condition
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
N/A
N/A
Damaged casing / still functional
Damaged casing / repair required
CONCRETE PADS
Pad in good condition
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
N/A
N/A
Minor cracks
Major cracks / broken / repair required
Undermined / washing out
Fire ants around concrete pad
WELL PROTECTIVE CASINGS
Casing in good condition
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
N/A
N/A
Damaged casing / still functional
Damaged casing / repair required
Broken hinge on protective lid
Wasp nest inside protective casing
Ants inside protective casing
WELL CAPS
Well cap in good conditon
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
N/A
N/A
Damaged / needs replacement
Replaced damaged well cap
FLUSH MOUNT WELLS
Vault in good condition
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Water inside vault
Vault bolt holes broken or stripped
:N/A
Bolts stripped
Vault lid cracked or broken
WELL ID TAGS
Well tag in good condition
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
N/A
N/A
N/A
Well tag missing
Well tag damaged / illegible
Lacks required information - Driller Reg #
Lacks required information -Completion date
Lacks required information -Total well depth
Lacks required information - Depth to screen
Lacks required info - Casing depth / diam.
Lacks required information -Screen interval
Lacks required information - Static WL/date
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Lacks required information - Non potable tag
NOTE:

MCGUIRE NUCLEAR STATION
NUCLEAR LANDFILL 2 GROUNDWATER MONITORING
PROGRAM
GROUNDWATER MONITORING FIELD DATA
PERMIT # 60-04
Purge Methods
LF = Low Flow
C = Connventional
EOP = Equip. Only Purge
LO = Level Only NP = No Purge
LF(M) = Low Flow (Mod.)
* = Applicable to LF & LF(M) Purging Only
WELL
DEPTH TO
WATER
PUMP WELL EVAC
SPECIFIC
DATE
WELL
DEPTH
WATER
ELEV.
APPEARANCE
ODOR
PURGE RATE VOL. VOL.
EVAC
TEMP.
CONDUCTANCE
pH
TURBH)ITY
ORP
DO
NO
(ff - Toc>
(ft _ TOC)
(ft)
METHOD (nil/min) (gal) (gal)
(YES/NO)
(deg. C)
(umho/cm)
(snits)
(NTU's)
(mV-NHE)
(mg/L)
6/28/2022
MW-5R
76.35
60.92
706.46
Normal
None
LF 330.00 2.52 2.05
N/A
19.55
13
7.57
2.0
400
7.71
6/28/2022
MW-5A
96.00
62.35
706.07
Normal
None
LF 300.00 5.49 1.95
N/A
18.76
42
7.37
1.2
343
7.86
6/29/2022
MW-6
37.20
32.20
696.25
Normal
None
EOP N/A 0.82 0.50
N/A
21.13
34
5.98
3.6
351
7.70
6/29/2022
MW-6A
47.90
31.50
697.48
Normal
None
LF 330.00 2.67 2.00
N/A
18.39
48
5.40
3.1
377
7.64
6/28/2022
MW-7R
48.89
34.10
692.06
Normal
None
LF 280.00 2.41 1.45
N/A
18.30
47
5.70
3.0
363
7.67
6/28/2022
MW-7A
59.40
31.87
692.79
Normal
None
LF 360.00 4.49 1.60
N/A
18.22
114
6.41
7.8
331
7.39
6/28/2022
MW-8
71.50
61.98
697.62
Normal
None
EDP N/A 1.55 0.60
N/A
19.89
107
6.48
3.2
366
8.66
6/28/2022
MW-8A
84.40
61.95
697.73
Normal
None
LF 397.50 3.66 2.55
N/A
17.55
84
6.68
0.7
378
7.46
6/28/2022
MW-9
30.80
25.19
686.68
Normal
None
EDP N/A 0.91 0.35
N/A
19.74
99
5.69
3.4
360
3.90
6/28/2022
MW-9A
47.80
25.58
686.55
Normal
None
LF 330.00 3.62 1.55
N/A
18.48
113
6.13
2.1
332
4.94
6/29/2022
MW-10A
59.23
51.76
704.02
Normal
None
EDP N/A 1.22 0.50
N/A
19.55
33
7.80
9.1
365
6.08
6/28/2022
SW-1
0.00
Normal
None
SWS N/A N/A
N/A
21.91
95
7.19
34.7
244
7.21
6/28/2022
SW-2
0.00
Normal
None
SWS N/A N/A
N/A
21.51
98
6.86
8.7
274
7.81
6/28/2022
LEACHATE POND
0.00
Normal
None
SWS N/A N/A
N/A
0.00
0
0.00
0.0
0
0.00

Appendix IV - Laboratory Reports and Chain -of -Custody Forms

DUE
Analytical Laboratory
Y
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number:
J22060046
Project Name:
MCGUIRE - GW LF2
Task Code:
LF
Customer Name(s):
A Healy, C Murphy, B Moeller, J Stowe, E Smith
Customer Address:
McGuire Nuclear Station
13225 Hagers Ferry Rd
Mail Code: MG01CH
Huntersville, NC 28078-8985
Lab Contact:
Peggy Kendall Phone: [phone]
Report Authorized By:
Date: 7/22/2022
(Signature)
Peggy Kendall
Program Comments:
QC Note
Page 1 of 180
The 1 A dioxane internal standard solution was expired when used for the analysis of this sample set. The internal standard
recovery passed when checked against the initial calibration that was analyzed prior to expiration. The data for the samples, per
Pace, should not be impacted.
Trans-1,4 dichloro-2-butene LCS/LCSD recoveries were outside the QC limits. Per Pace laboratory's SOP, it allows for 10% of
analytes to recover outside criteria. (See Pace's case narrative) The samples impacted were MW-8, MW-8A, MW-9, MW-9A.
Bromomethane and vinyl chloride LCS recovery was outside the QC limits. The associated samples MW-8, MW-8A, MW-9, and
MW-9A were non -detect for these analytes.
The following alkalinity samples were analyzed outside the holding time due to instrumentation error during the analysis: MW-8,
MW-8A, MW-9, MW-9A, SW-1, SW-2, FB-20220628-1430 and FD-20220628-1. See Pace's case narrative for details.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions: Page 2 of 180
Sample ID
Plant/Station
Collection
Date and Time
Collected By
Sample Description
2022014425
MCGUIRE
28-Jun-22
2:05 PM
Connor Zahora
MNS MW-5R
2022014426
MCGUIRE
28-Jun-22
12:40 PM
Connor Zahora
MNS MW-5A
2022014427
MCGUIRE
29-Jun-22
10:15 AM
Connor Zahora
MNS MW-6
2022014428
MCGUIRE
29-Jun-22
10:40 AM
Connor Zahora
MNS MW-6A
2022014429
MCGUIRE
28-Jun-22
12:50 PM
Ethan Smith
MNS MW-7R
2022014430
MCGUIRE
28-Jun-22
11:50 AM
Ethan Smith
MNS MW-7A
2022014431
MCGUIRE
28-Jun-22
9:15 AM
Connor Zahora
MNS MW-8
2022014432
MCGUIRE
28-Jun-22
8:45 AM
Connor Zahora
MNS MW-8A
2022014433
MCGUIRE
28-Jun-22
1:30 PM
Ethan Smith
MNS MW-9
2022014434
MCGUIRE
28-Jun-22
2:00 PM
Ethan Smith
MNS MW-9A
2022014435
MCGUIRE
29-Jun-22
8:40 AM
Connor Zahora
MNS MW-10A
2022014436
MCGUIRE
28-Jun-22
11:35 AM
Connor Zahora
MNS SW-1
2022014437
MCGUIRE
28-Jun-22
10:20 AM
Connor Zahora
MNS SW-2
2022014438
MCGUIRE
28-Jun-22
11:00 AM
Ethan Smith
MNS LEACHATE POND
2022014439
MCGUIRE
28-Jun-22
2:30 PM
Ethan Smith
MNS FB-20220628-1430
2022014440
MCGUIRE
29-Jun-22
10:00 AM
Connor Zahora
MNS FB-20220629-1000
2022014441
MCGUIRE
28-Jun-22
8:00 AM
Ethan Smith
MNS TB-20220628-0800
2022014442
MCGUIRE
28-Jun-22
Connor Zahora
MNS FD-20220628-1
18 Total Samples

Page 3 of 180
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
d❑ Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
❑ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 7/22/2022

Certificate of Laboratory Analysis Page 4 of 180
This report shall not be reproduced, except in full.
Order # J22060046
Site: MNS MW-5R
Sample #: 2022014425
Collection Date: 06/28/2022 02:05 PM
Loc code: MNS
MW-5R
Matrix: GW
RCRA
Analyte Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
INORGANIC IONS BY IC - Q22070003
Chloride 1.2
mg/L
0.1
0.0154
1
EPA 9056A
07/01/2022 09:16
BGN9034
Sulfate 0.80
mg/L
0.1
0.0428
1
EPA 9056A
07/01/2022 09:16
BGN9034
MERCURY (COLD VAPOR) IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL RECOVERABLE METALS BY ICP - Q22070017
Barium (Ba) 0.016
mg/L
0.005
0.002
1
SW 6010D
07/07/2022 23:22
MHALL3
Calcium (Ca) 0.688
mg/L
0.05
0.012
1
SW 6010D
07/07/2022 23:22
MHALL3
Magnesium (Mg) 0.657
mg/L
0.02
0.008
1
SW 6010D
07/07/2022 23:22
MHALL3
Potassium (K) 0.653
mg/L
0.1
0.031
1
SW 6010D
07/07/2022 23:22
MHALL3
Sodium (Na) 0.841
mg/L
0.05
0.017
1
SW 6010D
07/07/2022 23:22
MHALL3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22070024
Arsenic (As) 0.111 U
ug/L
1
0.111
1
SW 6020B
07/08/2022 14:10
CWSPEN3
Cadmium (Cd) 0.032 U
ug/L
1
0.032
1
SW 6020B
07/08/2022 14:10
CWSPEN3
Chromium (Cr) 0.797 J
ug/L
1
0.185
1
SW 6020B
07/08/2022 14:10
CWSPEN3
Lead (Pb) 0.292 J
ug/L
1
0.037
1
SW 6020B
07/08/2022 14:10
CWSPEN3
Selenium (Se) 0.193 U
ug/L
1
0.193
1
SW 6020B
07/08/2022 14:10
CWSPEN3
Silver (Ag) 0.035 U
ug/L
1
0.035
1
SW 6020B
07/08/2022 14:10
CWSPEN3
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by
Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL PETROLEUM HYDROCARBONS - (Analysis Performed by Pace Laboratories)
DROs Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Benzene Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 5 of 180
This report shall not be reproduced, except in full.
Order # J22060046
Site: MNS MW-5A
Sample #: 2022014426
Collection Date: 06/28/2022 12:40 PM
Loc code: MNS
MW-5A
Matrix: GW
RCRA
Analyte Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
INORGANIC IONS BY IC - Q22070003
Chloride 1.3
mg/L
0.1
0.0154
1
EPA 9056A
07/01/2022 10:01
BGN9034
Sulfate 2.7
mg/L
0.1
0.0428
1
EPA 9056A
07/01/2022 10:01
BGN9034
MERCURY (COLD VAPOR) IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL RECOVERABLE METALS BY ICP - Q22070017
Barium (Ba) 0.026
mg/L
0.005
0.002
1
SW 6010D
07/07/2022 23:35
MHALL3
Calcium (Ca) 3.05
mg/L
0.05
0.012
1
SW 6010D
07/07/2022 23:35
MHALL3
Magnesium (Mg) 1.27
mg/L
0.02
0.008
1
SW 6010D
07/07/2022 23:35
MHALL3
Potassium (K) 0.971
mg/L
0.1
0.031
1
SW 6010D
07/07/2022 23:35
MHALL3
Sodium (Na) 6.53
mg/L
0.05
0.017
1
SW 6010D
07/07/2022 23:35
MHALL3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22070024
Arsenic (As) 0.651 J
ug/L
1
0.111
1
SW 6020B
07/08/2022 13:32
CWSPEN3
Cadmium (Cd) 0.032 U
ug/L
1
0.032
1
SW 6020B
07/08/2022 13:32
CWSPEN3
Chromium (Cr) 0.668 J
ug/L
1
0.185
1
SW 6020B
07/08/2022 13:32
CWSPEN3
Lead (Pb) 0.048 J
ug/L
1
0.037
1
SW 6020B
07/08/2022 13:32
CWSPEN3
Selenium (Se) 0.193 U
ug/L
1
0.193
1
SW 6020B
07/08/2022 13:32
CWSPEN3
Silver (Ag) 0.321 J
ug/L
1
0.035
1
SW 6020B
07/08/2022 13:32
CWSPEN3
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by
Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL PETROLEUM HYDROCARBONS - (Analysis Performed by Pace Laboratories)
DROs Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Benzene Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 6 of 180
This report shall not be reproduced, except in full.
Order # J22060046
Site: MNS MW-6
Sample #: 2022014427
Collection Date: 06/29/2022 10:15 AM
Loc code:
MNS MW-6
Matrix: GW
RCRA
Analyte Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
INORGANIC IONS BY IC - Q22070003
Chloride 8.0
mg/L
0.1
0.0154
1
EPA 9056A
07/01/2022 16:28
BGN9034
Sulfate 0.29
mg/L
0.1
0.0428
1
EPA 9056A
07/01/2022 16:28
BGN9034
MERCURY (COLD VAPOR) IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL RECOVERABLE METALS BY ICP - Q22070017
Barium (Ba) 0.040
mg/L
0.005
0.002
1
SW 6010D
07/07/2022 23:40
MHALL3
Calcium (Ca) 8.64
mg/L
0.05
0.012
1
SW 6010D
07/07/2022 23:40
MHALL3
Magnesium (Mg) 3.54
mg/L
0.02
0.008
1
SW 6010D
07/07/2022 23:40
MHALL3
Potassium (K) 0.438
mg/L
0.1
0.031
1
SW 6010D
07/07/2022 23:40
MHALL3
Sodium (Na) 3.46
mg/L
0.05
0.017
1
SW 6010D
07/07/2022 23:40
MHALL3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22070024
Arsenic (As) 0.111 U
ug/L
1
0.111
1
SW 6020B
07/08/2022 14:19
CWSPEN3
Cadmium (Cd) 0.032 U
ug/L
1
0.032
1
SW 6020B
07/08/2022 14:19
CWSPEN3
Chromium (Cr) 2.28
ug/L
1
0.185
1
SW 6020B
07/08/2022 14:19
CWSPEN3
Lead (Pb) 0.037 U
ug/L
1
0.037
1
SW 6020B
07/08/2022 14:19
CWSPEN3
Selenium (Se) 0.193 U
ug/L
1
0.193
1
SW 6020B
07/08/2022 14:19
CWSPEN3
Silver (Ag) 0.035 U
ug/L
1
0.035
1
SW 6020B
07/08/2022 14:19
CWSPEN3
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by
Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL PETROLEUM HYDROCARBONS - (Analysis Performed by Pace Laboratories)
DROs Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Benzene Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 7 of 180
This report shall not be reproduced, except in full.
Order # J22060046
Site: MNS MW-6A
Sample #: 2022014428
Collection Date: 06/29/2022 10:40 AM
Loc code: MNS
MW-6A
Matrix: GW
RCRA
Analyte Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
INORGANIC IONS BY IC - Q22070003
Chloride 5.5
mg/L
0.1
0.0154
1
EPA 9056A
07/01/2022 13:59
BGN9034
Sulfate 0.05 J
mg/L
0.1
0.0428
1
EPA 9056A
07/01/2022 13:59
BGN9034
MERCURY (COLD VAPOR) IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL RECOVERABLE METALS BY ICP - Q22070017
Barium (Ba) 0.052
mg/L
0.005
0.002
1
SW 6010D
07/07/2022 23:44
MHALL3
Calcium (Ca) 4.78
mg/L
0.05
0.012
1
SW 6010D
07/07/2022 23:44
MHALL3
Magnesium (Mg) 1.48
mg/L
0.02
0.008
1
SW 6010D
07/07/2022 23:44
MHALL3
Potassium (K) 0.259
mg/L
0.1
0.031
1
SW 6010D
07/07/2022 23:44
MHALL3
Sodium (Na) 3.73
mg/L
0.05
0.017
1
SW 6010D
07/07/2022 23:44
MHALL3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22070024
Arsenic (As) 0.111 U
ug/L
1
0.111
1
SW 6020B
07/08/2022 14:29
CWSPEN3
Cadmium (Cd) 0.032 U
ug/L
1
0.032
1
SW 6020B
07/08/2022 14:29
CWSPEN3
Chromium (Cr) 1.33
ug/L
1
0.185
1
SW 6020B
07/08/2022 14:29
CWSPEN3
Lead (Pb) 0.037 J
ug/L
1
0.037
1
SW 6020B
07/08/2022 14:29
CWSPEN3
Selenium (Se) 0.193 U
ug/L
1
0.193
1
SW 6020B
07/08/2022 14:29
CWSPEN3
Silver (Ag) 0.035 U
ug/L
1
0.035
1
SW 6020B
07/08/2022 14:29
CWSPEN3
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by
Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL PETROLEUM HYDROCARBONS - (Analysis Performed by Pace Laboratories)
DROs Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Benzene Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 8 of 180
This report shall not be reproduced, except in full.
Order # J22060046
Site: MNS MW-7R
Sample #: 2022014429
Collection Date: 06/28/2022 12:50 PM
Loc code: MNS
MW-7R
Matrix: GW
RCRA
Analyte Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
INORGANIC IONS BY IC - Q22070003
Chloride 2.6
mg/L
0.1
0.0154
1
EPA 9056A
07/01/2022 10:16
BGN9034
Sulfate 0.09 J
mg/L
0.1
0.0428
1
EPA 9056A
07/01/2022 10:16
BGN9034
MERCURY (COLD VAPOR) IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL RECOVERABLE METALS BY ICP - Q22070017
Barium (Ba) 0.025
mg/L
0.005
0.002
1
SW 6010D
07/07/2022 23:49
MHALL3
Calcium (Ca) 3.77
mg/L
0.05
0.012
1
SW 6010D
07/07/2022 23:49
MHALL3
Magnesium (Mg) 2.90
mg/L
0.02
0.008
1
SW 6010D
07/07/2022 23:49
MHALL3
Potassium (K) 0.253
mg/L
0.1
0.031
1
SW 6010D
07/07/2022 23:49
MHALL3
Sodium (Na) 1.23
mg/L
0.05
0.017
1
SW 6010D
07/07/2022 23:49
MHALL3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22070024
Arsenic (As) 0.111 U
ug/L
1
0.111
1
SW 6020B
07/08/2022 14:38
CWSPEN3
Cadmium (Cd) 0.032 U
ug/L
1
0.032
1
SW 6020B
07/08/2022 14:38
CWSPEN3
Chromium (Cr) 0.594 J
ug/L
1
0.185
1
SW 6020B
07/08/2022 14:38
CWSPEN3
Lead (Pb) 0.054 J
ug/L
1
0.037
1
SW 6020B
07/08/2022 14:38
CWSPEN3
Selenium (Se) 0.193 U
ug/L
1
0.193
1
SW 6020B
07/08/2022 14:38
CWSPEN3
Silver (Ag) 0.035 U
ug/L
1
0.035
1
SW 6020B
07/08/2022 14:38
CWSPEN3
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by
Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL PETROLEUM HYDROCARBONS - (Analysis Performed by Pace Laboratories)
DROs Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Benzene Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 9 of 180
This report shall not be reproduced, except in full.
Order # J22060046
Site: MNS MW-7A
Sample #: 2022014430
Collection Date: 06/28/2022 11:50 AM
Loc code: MNS
MW-7A
Matrix: GW
RCRA
Analyte Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
INORGANIC IONS BY IC - Q22070003
Chloride 1.2
mg/L
0.1
0.0154
1
EPA 9056A
07/01/2022 10:31
BGN9034
Sulfate 0.29
mg/L
0.1
0.0428
1
EPA 9056A
07/01/2022 10:31
BGN9034
MERCURY (COLD VAPOR) IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL RECOVERABLE METALS BY ICP - Q22070017
Barium (Ba) 0.004 J
mg/L
0.005
0.002
1
SW 6010D
07/07/2022 23:53
MHALL3
Calcium (Ca) 14.7
mg/L
0.05
0.012
1
SW 6010D
07/07/2022 23:53
MHALL3
Magnesium (Mg) 3.74
mg/L
0.02
0.008
1
SW 6010D
07/07/2022 23:53
MHALL3
Potassium (K) 0.446
mg/L
0.1
0.031
1
SW 6010D
07/07/2022 23:53
MHALL3
Sodium (Na) 3.85
mg/L
0.05
0.017
1
SW 6010D
07/07/2022 23:53
MHALL3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22070024
Arsenic (As) 0.114 J
ug/L
1
0.111
1
SW 6020B
07/08/2022 14:47
CWSPEN3
Cadmium (Cd) 0.032 U
ug/L
1
0.032
1
SW 6020B
07/08/2022 14:47
CWSPEN3
Chromium (Cr) 0.553 J
ug/L
1
0.185
1
SW 6020B
07/08/2022 14:47
CWSPEN3
Lead (Pb) 0.037 U
ug/L
1
0.037
1
SW 6020B
07/08/2022 14:47
CWSPEN3
Selenium (Se) 0.193 U
ug/L
1
0.193
1
SW 6020B
07/08/2022 14:47
CWSPEN3
Silver (Ag) 0.035 U
ug/L
1
0.035
1
SW 6020B
07/08/2022 14:47
CWSPEN3
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by
Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL PETROLEUM HYDROCARBONS - (Analysis Performed by Pace Laboratories)
DROs Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Benzene Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 10 of 180
This report shall not be reproduced, except in full.
Order # J22060046
Site: MNS MW-8
Sample #: 2022014431
Collection Date: 06/28/2022 09:15 AM
Loc code:
MNS MW-8
Matrix: GW
RCRA
Analyte Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
INORGANIC IONS BY IC - Q22070003
Chloride 1.4
mg/L
0.1
0.0154
1
EPA 9056A
07/01/2022 10:46
BGN9034
Sulfate 1.5
mg/L
0.1
0.0428
1
EPA 9056A
07/01/2022 10:46
BGN9034
MERCURY (COLD VAPOR) IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL RECOVERABLE METALS BY ICP - Q22070017
Barium (Ba) 0.015
mg/L
0.005
0.002
1
SW 6010D
07/07/2022 23:57
MHALL3
Calcium (Ca) 16.4
mg/L
0.05
0.012
1
SW 6010D
07/07/2022 23:57
MHALL3
Magnesium (Mg) 3.26
mg/L
0.02
0.008
1
SW 6010D
07/07/2022 23:57
MHALL3
Potassium (K) 0.896
mg/L
0.1
0.031
1
SW 6010D
07/07/2022 23:57
MHALL3
Sodium (Na) 6.52
mg/L
0.05
0.017
1
SW 6010D
07/07/2022 23:57
MHALL3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22070024
Arsenic (As) 0.111 U
ug/L
1
0.111
1
SW 6020B
07/08/2022 14:57
CWSPEN3
Cadmium (Cd) 0.032 U
ug/L
1
0.032
1
SW 6020B
07/08/2022 14:57
CWSPEN3
Chromium (Cr) 0.788 J
ug/L
1
0.185
1
SW 6020B
07/08/2022 14:57
CWSPEN3
Lead (Pb) 0.064 J
ug/L
1
0.037
1
SW 6020B
07/08/2022 14:57
CWSPEN3
Selenium (Se) 0.193 U
ug/L
1
0.193
1
SW 6020B
07/08/2022 14:57
CWSPEN3
Silver (Ag) 0.035 U
ug/L
1
0.035
1
SW 6020B
07/08/2022 14:57
CWSPEN3
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by
Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL PETROLEUM HYDROCARBONS - (Analysis Performed by Pace Laboratories)
DROs Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Benzene Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 11 of 180
This report shall not be reproduced, except in full.
Order # J22060046
Site: MNS MW-8A
Sample #: 2022014432
Collection Date: 06/28/2022 08:45 AM
Loc code: MNS
MW-8A
Matrix: GW
RCRA
Analyte Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
INORGANIC IONS BY IC - Q22070003
Chloride 2.3
mg/L
0.1
0.0154
1
EPA 9056A
07/01/2022 11:01
BGN9034
Sulfate 1.4
mg/L
0.1
0.0428
1
EPA 9056A
07/01/2022 11:01
BGN9034
MERCURY (COLD VAPOR) IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL RECOVERABLE METALS BY ICP - Q22070017
Barium (Ba) 0.030
mg/L
0.005
0.002
1
SW 6010D
07/08/2022 00:02
MHALL3
Calcium (Ca) 11.3
mg/L
0.05
0.012
1
SW 6010D
07/08/2022 00:02
MHALL3
Magnesium (Mg) 3.50
mg/L
0.02
0.008
1
SW 6010D
07/08/2022 00:02
MHALL3
Potassium (K) 1.32
mg/L
0.1
0.031
1
SW 6010D
07/08/2022 00:02
MHALL3
Sodium (Na) 4.66
mg/L
0.05
0.017
1
SW 6010D
07/08/2022 00:02
MHALL3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22070024
Arsenic (As) 0.111 U
ug/L
1
0.111
1
SW 6020B
07/08/2022 15:06
CWSPEN3
Cadmium (Cd) 0.032 U
ug/L
1
0.032
1
SW 6020B
07/08/2022 15:06
CWSPEN3
Chromium (Cr) 0.604 J
ug/L
1
0.185
1
SW 6020B
07/08/2022 15:06
CWSPEN3
Lead (Pb) 0.037 U
ug/L
1
0.037
1
SW 6020B
07/08/2022 15:06
CWSPEN3
Selenium (Se) 0.193 U
ug/L
1
0.193
1
SW 6020B
07/08/2022 15:06
CWSPEN3
Silver (Ag) 0.035 U
ug/L
1
0.035
1
SW 6020B
07/08/2022 15:06
CWSPEN3
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by
Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL PETROLEUM HYDROCARBONS - (Analysis Performed by Pace Laboratories)
DROs Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Benzene Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 12 of 180
This report shall not be reproduced, except in full.
Order # J22060046
Site: MNS MW-9
Sample #: 2022014433
Collection Date: 06/28/2022 01:30 PM
Loc code:
MNS MW-9
Matrix: GW
RCRA
Analyte Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
INORGANIC IONS BY IC - Q22070003
Chloride 2.2
mg/L
0.1
0.0154
1
EPA 9056A
07/01/2022 11:16
BGN9034
Sulfate 0.17
mg/L
0.1
0.0428
1
EPA 9056A
07/01/2022 11:16
BGN9034
MERCURY (COLD VAPOR) IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL RECOVERABLE METALS BY ICP - Q22070017
Barium (Ba) 0.018
mg/L
0.005
0.002
1
SW 6010D
07/08/2022 00:06
MHALL3
Calcium (Ca) 7.30
mg/L
0.05
0.012
1
SW 6010D
07/08/2022 00:06
MHALL3
Magnesium (Mg) 3.15
mg/L
0.02
0.008
1
SW 6010D
07/08/2022 00:06
MHALL3
Potassium (K) 0.409
mg/L
0.1
0.031
1
SW 6010D
07/08/2022 00:06
MHALL3
Sodium (Na) 3.55
mg/L
0.05
0.017
1
SW 6010D
07/08/2022 00:06
MHALL3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22070024
Arsenic (As) 0.122 J
ug/L
1
0.111
1
SW 6020B
07/08/2022 15:44
CWSPEN3
Cadmium (Cd) 0.032 U
ug/L
1
0.032
1
SW 6020B
07/08/2022 15:44
CWSPEN3
Chromium (Cr) 1.22
ug/L
1
0.185
1
SW 6020B
07/08/2022 15:44
CWSPEN3
Lead (Pb) 0.037 U
ug/L
1
0.037
1
SW 6020B
07/08/2022 15:44
CWSPEN3
Selenium (Se) 0.193 U
ug/L
1
0.193
1
SW 6020B
07/08/2022 15:44
CWSPEN3
Silver (Ag) 0.035 U
ug/L
1
0.035
1
SW 6020B
07/08/2022 15:44
CWSPEN3
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by
Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL PETROLEUM HYDROCARBONS - (Analysis Performed by Pace Laboratories)
DROs Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Benzene Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 13 of 180
This report shall not be reproduced, except in full.
Order # J22060046
Site: MNS MW-9A
Sample #: 2022014434
Collection Date: 06/28/2022 02:00 PM
Loc code: MNS
MW-9A
Matrix: GW
RCRA
Analyte Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
INORGANIC IONS BY IC - Q22070003
Chloride 1.7
mg/L
0.1
0.0154
1
EPA 9056A
07/01/2022 12:30
BGN9034
Sulfate 0.22
mg/L
0.1
0.0428
1
EPA 9056A
07/01/2022 12:30
BGN9034
MERCURY (COLD VAPOR) IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL RECOVERABLE METALS BY ICP - Q22070017
Barium (Ba) 0.010
mg/L
0.005
0.002
1
SW 6010D
07/08/2022 00:18
MHALL3
Calcium (Ca) 11.6
mg/L
0.05
0.012
1
SW 6010D
07/08/2022 00:18
MHALL3
Magnesium (Mg) 4.80
mg/L
0.02
0.008
1
SW 6010D
07/08/2022 00:18
MHALL3
Potassium (K) 0.538
mg/L
0.1
0.031
1
SW 6010D
07/08/2022 00:18
MHALL3
Sodium (Na) 5.12
mg/L
0.05
0.017
1
SW 6010D
07/08/2022 00:18
MHALL3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22070024
Arsenic (As) 0.111 U
ug/L
1
0.111
1
SW 6020B
07/08/2022 15:53
CWSPEN3
Cadmium (Cd) 0.032 U
ug/L
1
0.032
1
SW 6020B
07/08/2022 15:53
CWSPEN3
Chromium (Cr) 1.98
ug/L
1
0.185
1
SW 6020B
07/08/2022 15:53
CWSPEN3
Lead (Pb) 0.037 U
ug/L
1
0.037
1
SW 6020B
07/08/2022 15:53
CWSPEN3
Selenium (Se) 0.193 U
ug/L
1
0.193
1
SW 6020B
07/08/2022 15:53
CWSPEN3
Silver (Ag) 0.035 U
ug/L
1
0.035
1
SW 6020B
07/08/2022 15:53
CWSPEN3
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by
Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL PETROLEUM HYDROCARBONS - (Analysis Performed by Pace Laboratories)
DROs Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Benzene Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 14 of 180
This report shall not be reproduced, except in full.
Order # J22060046
Site: MNS MW-10A
Sample #: 2022014435
Collection Date: 06/29/2022 08:40 AM
Loc code:
MNS MW-10A
Matrix: GW
RCRA
Analyte Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
INORGANIC IONS BY IC - Q22070003
Chloride 1.3
mg/L
0.1
0.0154
1
EPA 9056A
07/01/2022 14:14
BGN9034
Sulfate 0.46
mg/L
0.1
0.0428
1
EPA 9056A
07/01/2022 14:14
BGN9034
MERCURY (COLD VAPOR) IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL RECOVERABLE METALS BY ICP - Q22070017
Barium (Ba) 0.032
mg/L
0.005
0.002
1
SW 6010D
07/08/2022 00:23
MHALL3
Calcium (Ca) 1.59
mg/L
0.05
0.012
1
SW 6010D
07/08/2022 00:23
MHALL3
Magnesium (Mg) 1.67
mg/L
0.02
0.008
1
SW 6010D
07/08/2022 00:23
MHALL3
Potassium (K) 0.777
mg/L
0.1
0.031
1
SW 6010D
07/08/2022 00:23
MHALL3
Sodium (Na) 1.79
mg/L
0.05
0.017
1
SW 6010D
07/08/2022 00:23
MHALL3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22070024
Arsenic (As) 0.111 U
ug/L
1
0.111
1
SW 6020B
07/08/2022 16:03
CWSPEN3
Cadmium (Cd) 0.032 U
ug/L
1
0.032
1
SW 6020B
07/08/2022 16:03
CWSPEN3
Chromium (Cr) 0.866 J
ug/L
1
0.185
1
SW 6020B
07/08/2022 16:03
CWSPEN3
Lead (Pb) 0.297 J
ug/L
1
0.037
1
SW 6020B
07/08/2022 16:03
CWSPEN3
Selenium (Se) 0.193 U
ug/L
1
0.193
1
SW 6020B
07/08/2022 16:03
CWSPEN3
Silver (Ag) 0.035 U
ug/L
1
0.035
1
SW 6020B
07/08/2022 16:03
CWSPEN3
Miscellaneous Tests bV a Vendor Laboratory - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL PETROLEUM HYDROCARBONS - (Analysis Performed by Pace Laboratories)
DROs Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Benzene Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 15 of 180
This report shall not be reproduced, except in full.
Order # J22060046
Site: MNS SW-1
Sample #: 2022014436
Collection Date: 06/28/2022 11:35 AM
Loc code:
MNS SW-1
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
INORGANIC IONS BY IC - Q22070003
Chloride
2.3
mg/L
0.1
0.0154
1
EPA 9056A
07/01/2022 12:45
BGN9034
Sulfate
0.96
mg/L
0.1
0.0428
1
EPA 9056A
07/01/2022 12:45
BGN9034
MERCURY (COLD VAPOR) IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q22070015
Barium (Ba)
0.023
mg/L
0.005
0.002
1
SW 6010D
07/08/2022 01:20
MHALL3
TOTAL RECOVERABLE METALS BY ICP - Q22070017
Barium (Ba)
0.028
mg/L
0.005
0.002
1
SW 6010D
07/08/2022 00:27
MHALL3
Calcium (Ca)
12.4
mg/L
0.05
0.012
1
SW 6010D
07/08/2022 00:27
MHALL3
Magnesium (Mg)
4.77
mg/L
0.02
0.008
1
SW 6010D
07/08/2022 00:27
MHALL3
Potassium (K)
1.11
mg/L
0.1
0.031
1
SW 6010D
07/08/2022 00:27
MHALL3
Sodium (Na)
5.85
mg/L
0.05
0.017
1
SW 6010D
07/08/2022 00:27
MHALL3
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22070021
Arsenic (As)
0.195 J
ug/L
1
0.111
1
SW 6020B
07/08/2022 21:33
CWSPEN3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
07/08/2022 21:33
CWSPEN3
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
SW 6020B
07/08/2022 21:33
CWSPEN3
Lead (Pb)
0.065 J
ug/L
1
0.037
1
SW 6020B
07/08/2022 21:33
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
07/08/2022 21:33
CWSPEN3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22070024
Arsenic (As)
0.319 J
ug/L
1
0.111
1
SW 6020B
07/08/2022 16:12
CWSPEN3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
07/08/2022 16:12
CWSPEN3
Chromium (Cr)
0.786 J
ug/L
1
0.185
1
SW 6020B
07/08/2022 16:12
CWSPEN3
Lead (Pb)
0.433 J
ug/L
1
0.037
1
SW 6020B
07/08/2022 16:12
CWSPEN3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
07/08/2022 16:12
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
07/08/2022 16:12
CWSPEN3
Miscellaneous Tests by
a Vendor Laboratory - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
TOTAL PETROLEUM HYDROCARBONS - (Analysis Performed by Pace Laboratories)
DROs
Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Benzene
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 16 of 180
This report shall not be reproduced, except in full.
Order # J22060046
Site: MNS SW-2
Sample #: 2022014437
Collection Date: 06/28/2022 10:20 AM
Loc code:
MNS SW-2
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
INORGANIC IONS BY IC - Q22070003
Chloride
2.3
mg/L
0.1
0.0154
1
EPA 9056A
07/01/2022 13:00
BGN9034
Sulfate
2.3
mg/L
0.1
0.0428
1
EPA 9056A
07/01/2022 13:00
BGN9034
MERCURY (COLD VAPOR) IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q22070015
Barium (Ba)
0.021
mg/L
0.005
0.002
1
SW 6010D
07/08/2022 01:33
MHALL3
TOTAL RECOVERABLE METALS BY ICP - Q22070017
Barium (Ba)
0.024
mg/L
0.005
0.002
1
SW 6010D
07/08/2022 00:31
MHALL3
Calcium (Ca)
13.0
mg/L
0.05
0.012
1
SW 6010D
07/08/2022 00:31
MHALL3
Magnesium (Mg)
4.76
mg/L
0.02
0.008
1
SW 6010D
07/08/2022 00:31
MHALL3
Potassium (K)
1.32
mg/L
0.1
0.031
1
SW 6010D
07/08/2022 00:31
MHALL3
Sodium (Na)
6.00
mg/L
0.05
0.017
1
SW 6010D
07/08/2022 00:31
MHALL3
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22070021
Arsenic (As)
0.162 J
ug/L
1
0.111
1
SW 6020B
07/08/2022 21:04
CWSPEN3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
07/08/2022 21:04
CWSPEN3
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
SW 6020B
07/08/2022 21:04
CWSPEN3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
07/08/2022 21:04
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
07/08/2022 21:04
CWSPEN3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22070024
Arsenic (As)
0.176 J
ug/L
1
0.111
1
SW 6020B
07/08/2022 16:21
CWSPEN3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
07/08/2022 16:21
CWSPEN3
Chromium (Cr)
0.625 J
ug/L
1
0.185
1
SW 6020B
07/08/2022 16:21
CWSPEN3
Lead (Pb)
0.124 J
ug/L
1
0.037
1
SW 6020B
07/08/2022 16:21
CWSPEN3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
07/08/2022 16:21
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
07/08/2022 16:21
CWSPEN3
Miscellaneous Tests by
a Vendor Laboratory - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
TOTAL PETROLEUM HYDROCARBONS - (Analysis Performed by Pace Laboratories)
DROs
Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Benzene
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 17 of 180
This report shall not be reproduced, except in full.
Order # J22060046
Site: MNS LEACHATE POND
Sample #: 2022014438
Collection Date: 06/28/2022 11:00 AM
Loc code: MNS
LEACHATE POND
Matrix: GW
RCRA
Analyte Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
INORGANIC IONS BY IC - Q22070003
Chloride 58
mg/L
2
0.0154
20
EPA 9056A
07/01/2022 13:15
BGN9034
Sulfate 30
mg/L
2
0.0428
20
EPA 9056A
07/01/2022 13:15
BGN9034
MERCURY (COLD VAPOR) IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL RECOVERABLE METALS BY ICP - Q22070017
Barium (Ba) 0.106
mg/L
0.005
0.002
1
SW 6010D
07/08/2022 00:36
MHALL3
Calcium (Ca) 98.7
mg/L
0.05
0.012
1
SW 6010D
07/08/2022 00:36
MHALL3
Magnesium (Mg) 17.4
mg/L
0.02
0.008
1
SW 6010D
07/08/2022 00:36
MHALL3
Potassium (K) 11.8
mg/L
0.1
0.031
1
SW 6010D
07/08/2022 00:36
MHALL3
Sodium (Na) 59.0
mg/L
0.05
0.017
1
SW 6010D
07/08/2022 00:36
MHALL3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22070024
Arsenic (As) 0.325 J
ug/L
1
0.111
1
SW 6020B
07/08/2022 16:31
CWSPEN3
Cadmium (Cd) 0.032 U
ug/L
1
0.032
1
SW 6020B
07/08/2022 16:31
CWSPEN3
Chromium (Cr) 0.323 J
ug/L
1
0.185
1
SW 6020B
07/08/2022 16:31
CWSPEN3
Lead (Pb) 0.04 J
ug/L
1
0.037
1
SW 6020B
07/08/2022 16:31
CWSPEN3
Selenium (Se) 0.224 J
ug/L
1
0.193
1
SW 6020B
07/08/2022 16:31
CWSPEN3
Silver (Ag) 0.035 U
ug/L
1
0.035
1
SW 6020B
07/08/2022 16:31
CWSPEN3
Miscellaneous Tests bV a Vendor Laboratory - (Analysis Performed by
Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL PETROLEUM HYDROCARBONS - (Analysis Performed by Pace Laboratories)
DROs Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Benzene Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 18 of 180
This report shall not be reproduced, except in full.
Order # J22060046
Site: MNS FB-20220628-1430 Field Blank Sample #: 2022014439
Collection Date: 06/28/2022 02:30 PM Loc code: MNS QA Matrix: GW RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
INORGANIC IONS BY IC - Q22070003
Chloride
0.0154 U
mg/L
0.1
0.0154
1
EPA 9056A
07/01/2022 13:30
BGN9034
Sulfate
0.0428 U
mg/L
0.1
0.0428
1
EPA 9056A
07/01/2022 13:30
BGN9034
MERCURY (COLD VAPOR) IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
TOTAL RECOVERABLE METALS BY ICP - Q22070017
Barium (Ba)
0.002 U
mg/L
0.005
0.002
1
SW 6010D
07/08/2022 00:40
MHALL3
Calcium (Ca)
0.012 U
mg/L
0.05
0.012
1
SW 6010D
07/08/2022 00:40
MHALL3
Magnesium (Mg)
0.008 U
mg/L
0.02
0.008
1
SW 6010D
07/08/2022 00:40
MHALL3
Potassium (K)
0.031 U
mg/L
0.1
0.031
1
SW 6010D
07/08/2022 00:40
MHALL3
Sodium (Na)
0.017 U
mg/L
0.05
0.017
1
SW 6010D
07/08/2022 00:40
MHALL3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22070024
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
07/08/2022 16:40
CWSPEN3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
07/08/2022 16:40
CWSPEN3
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
SW 6020B
07/08/2022 16:40
CWSPEN3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
07/08/2022 16:40
CWSPEN3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
07/08/2022 16:40
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
07/08/2022 16:40
CWSPEN3
Miscellaneous Tests by
a Vendor Laboratory - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
TOTAL PETROLEUM HYDROCARBONS - (Analysis Performed by Pace Laboratories)
DROs
Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Benzene
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 19 of 180
This report shall not be reproduced, except in full.
Order # J22060046
Site: MNS FB-20220629-1000
Field Blank
Sample #: 2022014440
Collection Date: 06/29/2022 10:00 AM
Loc code: MNS QA
Matrix: GW
RCRA
Analyte Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
INORGANIC IONS BY IC - Q22070003
Chloride 0.0154 U
mg/L
0.1
0.0154
1
EPA 9056A
07/01/2022 14:29
BGN9034
Sulfate 0.0428 U
mg/L
0.1
0.0428
1
EPA 9056A
07/01/2022 14:29
BGN9034
MERCURY (COLD VAPOR) IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL RECOVERABLE METALS BY ICP - Q22070017
Barium (Ba) 0.002 U
mg/L
0.005
0.002
1
SW 6010D
07/08/2022 00:45
MHALL3
Calcium (Ca) 0.012 U
mg/L
0.05
0.012
1
SW 6010D
07/08/2022 00:45
MHALL3
Magnesium (Mg) 0.008 U
mg/L
0.02
0.008
1
SW 6010D
07/08/2022 00:45
MHALL3
Potassium (K) 0.031 U
mg/L
0.1
0.031
1
SW 6010D
07/08/2022 00:45
MHALL3
Sodium (Na) 0.017 U
mg/L
0.05
0.017
1
SW 6010D
07/08/2022 00:45
MHALL3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22070024
Arsenic (As) 0.111 U
ug/L
1
0.111
1
SW 6020B
07/08/2022 16:50
CWSPEN3
Cadmium (Cd) 0.032 U
ug/L
1
0.032
1
SW 6020B
07/08/2022 16:50
CWSPEN3
Chromium (Cr) 0.185 U
ug/L
1
0.185
1
SW 6020B
07/08/2022 16:50
CWSPEN3
Lead (Pb) 0.037 U
ug/L
1
0.037
1
SW 6020B
07/08/2022 16:50
CWSPEN3
Selenium (Se) 0.193 U
ug/L
1
0.193
1
SW 6020B
07/08/2022 16:50
CWSPEN3
Silver (Ag) 0.035 U
ug/L
1
0.035
1
SW 6020B
07/08/2022 16:50
CWSPEN3
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by
Pace Laboratories)
Vendor Parameter Complete
Vendor Method
V_PACE
TOTAL PETROLEUM HYDROCARBONS - (Analysis Performed by Pace Laboratories)
DROs Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Benzene Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22060046
Site: MNS_TB-20220628-0800 Trip Blank
Collection Date: 06/28/2022 08:00 AM Loc code: MNS TB
Analyte Result Units Qualifiers RDL MDL DF
Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
VOLATILES - (Analysis Performed by Pace Laboratories)
Benzene Complete
Page 20 of 180
Sample #: 2022014441
Matrix: GW RCRA
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis Page 21 of 180
This report shall not be reproduced, except in full.
Order # J22060046
Site: MNS_FD-20220628-1 Duplicate Sample #: 2022014442
Collection Date: 06/28/2022 Loc code: MNS FD Matrix: GW RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
INORGANIC IONS BY IC - Q22070003
Chloride
2.2
mg/L
0.1
0.0154
1
EPA 9056A
07/01/2022 16:13
BGN9034
Sulfate
1.4
mg/L
0.1
0.0428
1
EPA 9056A
07/01/2022 16:13
BGN9034
MERCURY (COLD VAPOR) IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
TOTAL RECOVERABLE METALS BY ICP - Q22070017
Barium (Ba)
0.030
mg/L
0.005
0.002
1
SW 6010D
07/08/2022 00:49
MHALL3
Calcium (Ca)
11.4
mg/L
0.05
0.012
1
SW 6010D
07/08/2022 00:49
MHALL3
Magnesium (Mg)
3.54
mg/L
0.02
0.008
1
SW 6010D
07/08/2022 00:49
MHALL3
Potassium (K)
1.34
mg/L
0.1
0.031
1
SW 6010D
07/08/2022 00:49
MHALL3
Sodium (Na)
4.71
mg/L
0.05
0.017
1
SW 6010D
07/08/2022 00:49
MHALL3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22070024
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
07/08/2022 16:59
CWSPEN3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
07/08/2022 16:59
CWSPEN3
Chromium (Cr)
0.517 J
ug/L
1
0.185
1
SW 6020B
07/08/2022 16:59
CWSPEN3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
07/08/2022 16:59
CWSPEN3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
07/08/2022 16:59
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
07/08/2022 16:59
CWSPEN3
Miscellaneous Tests by
a Vendor Laboratory - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
TOTAL PETROLEUM HYDROCARBONS - (Analysis Performed by Pace Laboratories)
DROs
Complete
Vendor Method
V_PACE
VOLATILES - (Analysis Performed by Pace Laboratories)
Benzene
Complete
Vendor Method
V_PACE
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22060046
Level II QC Summary
Q22070003 Dionex INORGANIC IONS BY IC
Blank # 1
Page 22 of 180
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Sulfate
0
0
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Chloride
5.33
5.33
mg/L
1
0.0154
5
105
80
120
Sulfate
5.01
5.01
mg/L
1
0.0428
5
99.1
80
120
MS # 1
Parent Sample:
J22060046 -- 2022014425
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Chloride
3.37
3.37
mg/L
1
0.0154
2
111
80
120
Sulfate
2.81
2.81
mg/L
1
0.0428
2
101
80
120
MSD # 1
Parent Sample:
J22060046 -- 2022014425
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Chloride
3.35
3.35
mg/L
1
0.0154
2
110
80
120 0.769
Sulfate
2.78
2.78
mg/L
1
0.0428
2
99.3
80
120 1.45
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 23 of 180
This report shall not be reproduced, except in full.
Order # J22060046
Level II QC Summary
Q22070015 ICP_DIS_TRM TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
-0.00114
-0.00114
mg/L
1
0.002
0.005
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5.21
5.21
mg/L
1
0.002
5
104
80
120
MS # 1
Parent Sample:
J22060046 -- 2022014436
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5.15
5.15
mg/L
1
0.002
5
103
70
130
MSD # 1
Parent Sample:
J22060046 -- 2022014436
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Barium (Ba)
5.15
5.15
mg/L
1
0.002
5
103
70
130 0.0194
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 24 of 180
This report shall not be reproduced, except in full.
Order # J22060046
Level II QC Summary
Q22070017 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units
Barium (Ba)
-0.00113
-0.00113
mg/L
Calcium (Ca)
0.00187
0.00187
mg/L
Magnesium (Mg)
0.00234
0.00234
mg/L
Potassium (K)
0.00284
0.00284
mg/L
Sodium (Na)
0.00267
0.00267
mg/L
LCS # 1
MS # 1
Parameter
Measured
Final
Units
Barium (Ba)
5.15
5.15
mg/L
Calcium (Ca)
5.09
5.09
mg/L
Magnesium (Mg)
5.02
5.02
mg/L
Potassium (K)
5.01
5.01
mg/L
Sodium (Na)
5
5
mg/L
Parameter
Measured
Final
Units
Barium (Ba)
5.24
5.24
mg/L
Calcium (Ca)
5.82
5.82
mg/L
Magnesium (Mg)
5.72
5.72
mg/L
Potassium (K)
5.7
5.7
mg/L
Sodium (Na)
5.87
5.87
mg/L
MSD # 1
Parameter
Measured
Final
Units
Barium (Ba)
5.18
5.18
mg/L
Calcium (Ca)
5.77
5.77
mg/L
Magnesium (Mg)
5.68
5.68
mg/L
Potassium (K)
5.67
5.67
mg/L
Sodium (Na)
5.82
5.82
mg/L
Dil
MDL
RDL
Relative Concentration
1
0.002
0.005
< MDL
1
0.012
0.05
< MDL
1
0.008
0.02
< MDL
1
0.031
0.1
< MDL
1
0.017
0.05
< MDL
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.002
5
103
80
120
1
0.012
5
102
80
120
1
0.008
5
100
80
120
1
0.031
5
100
80
120
1
0.017
5
99.9
80
120
Parent Sample:
J22060046 -- 2022014425
Dil
MDL
S ike
% Recovery
LCL
UCL
1
0.002
5
105
75
125
1
0.012
5
103
75
125
1
0.008
5
101
75
125
1
0.031
5
101
75
125
1
0.017
5
101
75
125
Parent Sample:
J22060046 -- 2022014425
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
1
0.002
5
103
75
125
1.21
1
0.012
5
102
75
125
0.845
1
0.008
5
101
75
125
0.579
1
0.031
5
100
75
125
0.51
1
0.017
5
99.5
75
125
0.856
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 25 of 180
This report shall not be reproduced, except in full.
Order # J22060046
Level II QC Summary
Q22070021 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Blank # 1
LCS # 1
MS # 1
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Arsenic (As)
-0.002
-0.002
ug/L
1
0.111
1
< MDL
Cadmium (Cd)
-0.016
-0.016
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.029
0.029
ug/L
1
0.185
1
< MDL
Lead (Pb)
-0.011
-0.011
ug/L
1
0.037
1
< MDL
Silver (Ag)
-0.001
-0.001
ug/L
1
0.035
1
< MDL
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Arsenic (As)
48.2
48.2
ug/L
1
0.111
50
96.4
80
120
Cadmium (Cd)
49.7
49.7
ug/L
1
0.032
50
99.3
80
120
Chromium (Cr)
50.8
50.8
ug/L
1
0.185
50
102
80
120
Lead (Pb)
50.5
50.5
ug/L
1
0.037
50
101
80
120
Silver (Ag)
51.1
51.1
ug/L
1
0.035
50
102
80
120
Parent Sample:
J22060046 -- 2022014437
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Arsenic (As)
49.2
49.2
ug/L
1
0.111
50
98
75
125
Cadmium (Cd)
50.7
50.7
ug/L
1
0.032
50
101
75
125
Chromium (Cr)
51.4
51.4
ug/L
1
0.185
50
102
75
125
Lead (Pb)
51.4
51.4
ug/L
1
0.037
50
103
75
125
Silver (Ag)
51.7
51.7
ug/L
1
0.035
50
103
75
125
Parent Sample:
J22060046 -- 2022014437
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
Arsenic (As)
49
49
ug/L
1
0.111
50
97.7
75
125
0.262
Cadmium (Cd)
50.6
50.6
ug/L
1
0.032
50
101
75
125
0.0869
Chromium (Cr)
51
51
ug/L
1
0.185
50
102
75
125
0.653
Lead (Pb)
50.8
50.8
ug/L
1
0.037
50
102
75
125
0.993
Silver (Ag)
51.4
51.4
ug/L
1
0.035
50
103
75
125
0.563
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 26 of 180
This report shall not be reproduced, except in full.
Order # J22060046
Level II QC Summary
Q22070024 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
LCS # 1
MS # 1
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Arsenic (As)
-0.006
-0.006
ug/L
1
0.111
1
< MDL
Cadmium (Cd)
-0.013
-0.013
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.045
0.045
ug/L
1
0.185
1
< MDL
Lead (Pb)
-0.019
-0.019
ug/L
1
0.037
1
< MDL
Selenium (Se)
-0.043
-0.043
ug/L
1
0.193
1
< MDL
Silver (Ag)
0.001
0.001
ug/L
1
0.035
1
< MDL
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Arsenic (As)
50.5
50.5
ug/L
1
0.111
50
101
80
120
Cadmium (Cd)
50.2
50.2
ug/L
1
0.032
50
100
80
120
Chromium (Cr)
50.3
50.3
ug/L
1
0.185
50
101
80
120
Lead (Pb)
50.8
50.8
ug/L
1
0.037
50
102
80
120
Selenium (Se)
46.3
46.3
ug/L
1
0.193
50
92.5
80
120
Silver (Ag)
51.3
51.3
ug/L
1
0.035
50
103
80
120
Parent Sample:
J22060046 -- 2022014426
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Arsenic (As)
50.3
50.3
ug/L
1
0.111
50
99.3
75
125
Cadmium (Cd)
50.9
50.9
ug/L
1
0.032
50
102
75
125
Chromium (Cr)
51.5
51.5
ug/L
1
0.185
50
102
75
125
Lead (Pb)
51.3
51.3
ug/L
1
0.037
50
103
75
125
Selenium (Se)
45.5
45.5
ug/L
1
0.193
50
91
75
125
Silver (Ag)
51.8
51.8
ug/L
1
0.035
50
103
75
125
Parent Sample:
J22060046 -- 2022014426
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Arsenic (As)
49.6
49.6
ug/L
1
0.111
50
97.9
75
125
1.45
Cadmium (Cd)
49.7
49.7
ug/L
1
0.032
50
99.4
75
125
2.35
Chromium (Cr)
50.9
50.9
ug/L
1
0.185
50
100
75
125
1.31
Lead (Pb)
50.5
50.5
ug/L
1
0.037
50
101
75
125
1.5
Selenium (Se)
45.1
45.1
ug/L
1
0.193
50
90.2
75
125
0.797
Silver (Ag)
50.8
50.8
ug/L
1
0.035
50
101
75
125
2.08
Qualifier
Qualifier
Qualifier
Qualifier

lceAnalyilcal
www.pacelabs.com
Pace Analytical Services, LLC
pdagl�irpy&e. Suite 100
��JJ Huntersville, NC 28078
[phone]
July 20, 2022
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on June 30, 2022. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Nicole D'Oleo
nicole.d'[e-mail]
[phone]
Project Manager
Enclosures
cc: Program Manager, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
P36g0Air6fy&e. Suite 100
Huntersville, NC 28078
[phone]
CERTIFICATIONS
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804 South Carolina Laboratory ID: 99030
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
North Carolina Drinking Water Certification #: 37712 Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
PdagohrwYke. Suite 100
�J Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92612702001
2022014425
Water
06/28/22 14:05
06/30/22 14:00
92612702002
2022014426
Water
06/28/22 12:40
06/30/22 14:00
92612702003
2022014427
Water
06/29/22 10:15
06/30/22 14:00
92612702004
2022014428
Water
06/29/22 10:40
06/30/22 14:00
92612702005
2022014429
Water
06/28/22 12:50
06/30/22 14:00
92612702006
2022014430
Water
06/28/2211:50
06/30/22 14:00
92612702007
2022014431
Water
06/28/22 09:15
06/30/22 14:00
92612702008
2022014432
Water
06/28/22 08:45
06/30/22 14:00
92612702009
2022014433
Water
06/28/22 13:30
06/30/22 14:00
92612702010
2022014434
Water
06/28/22 14:00
06/30/22 14:00
92612702011
2022014435
Water
06/29/22 08:40
06/30/22 14:00
92612702012
2022014436
Water
06/28/2211:35
06/30/22 14:00
92612702013
2022014437
Water
06/28/22 10:20
06/30/22 14:00
92612702014
2022014438
Water
06/28/2211:00
06/30/22 14:00
92612702015
2022014439
Water
06/28/22 14:30
06/30/22 14:00
92612702016
2022014440
Water
06/29/22 10:00
06/30/22 14:00
92612702017
2022014442
Water
06/28/22 00:00
06/30/22 14:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
Pdag03Ibirwyke. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J22060046 MNS LF #2
92612702
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92612702001
2022014425
EPA 7470A
NMP
1
PASI-A
92612702002
2022014426
EPA 7470A
NMP
1
PASI-A
92612702003
2022014427
EPA 7470A
NMP
1
PASI-A
92612702004
2022014428
EPA 7470A
NMP
1
PASI-A
92612702005
2022014429
EPA 7470A
NMP
1
PASI-A
92612702006
2022014430
EPA 7470A
NMP
1
PASI-A
92612702007
2022014431
EPA 7470A
NMP
1
PASI-A
92612702008
2022014432
EPA 7470A
NMP
1
PASI-A
92612702009
2022014433
EPA 7470A
NMP
1
PASI-A
92612702010
2022014434
EPA 7470A
NMP
1
PASI-A
92612702011
2022014435
EPA 7470A
NMP
1
PASI-A
92612702012
2022014436
EPA 7470A
NMP
1
PASI-A
92612702013
2022014437
EPA 7470A
NMP
1
PASI-A
92612702014
2022014438
EPA 7470A
NMP
1
PASI-A
92612702015
2022014439
EPA 7470A
NMP
1
PASI-A
92612702016
2022014440
EPA 7470A
NMP
1
PASI-A
92612702017
2022014442
EPA 7470A
NMP
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
Pdag0�fir6fYke. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Method: EPA 7470A
Description: 7470 Mercury
Client: Duke Energy
Date: July 20, 2022
General Information:
17 samples were analyzed for EPA 7470A by Pace Analytical Services Asheville. All samples were received in acceptable condition
with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end
of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7470A with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
PdagOgrwyke. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Sample: 2022014425 Lab ID: 92612702001 Collected: 06/28/22 14:05 Received: 06/30/22 14:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
Mercury ND ug/L 0.20 0.12 1 07/02/2218:57 07/08/2215:24 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/20/2022 12:25 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
PdagOgrwyke. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Sample: 2022014426 Lab ID: 92612702002 Collected: 06/28/22 12:40 Received: 06/30/22 14:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
Mercury ND ug/L 0.20 0.12 1 07/02/2218:57 07/08/2215:32 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/20/2022 12:25 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
Pdag0Aiirpy&e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Sample: 2022014427 Lab ID: 92612702003 Collected: 06/29/22 10:15 Received: 06/30/22 14:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
Mercury ND ug/L 0.20 0.12 1 07/02/2218:57 07/08/2215:40 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/20/2022 12:25 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
PARQArwyke. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Sample: 2022014428 Lab ID: 92612702004 Collected: 06/29/22 10:40 Received: 06/30/22 14:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
Mercury ND ug/L 0.20 0.12 1 07/02/2218:57 07/08/2215:42 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/20/2022 12:25 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
P9891*rwyke. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Sample: 2022014429 Lab ID: 92612702005 Collected: 06/28/22 12:50 Received: 06/30/22 14:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
Mercury ND ug/L 0.20 0.12 1 07/02/2218:57 07/08/2215:44 7439-97-6
Date: 07/20/2022 12:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
P9891*rwyke. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Sample: 2022014430 Lab ID: 92612702006 Collected: 06/28/22 11:50 Received: 06/30/22 14:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
Mercury ND ug/L 0.20 0.12 1 07/02/2218:57 07/08/2215:46 7439-97-6
Date: 07/20/2022 12:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
PAR0Arwyke. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Sample: 2022014431 Lab ID: 92612702007 Collected: 06/28/22 09:15 Received: 06/30/22 14:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
Mercury ND ug/L 0.20 0.12 1 07/02/2218:57 07/08/2215:48 7439-97-6
Date: 07/20/2022 12:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
Pdaglq irwyke. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Sample: 2022014432 Lab ID: 92612702008 Collected: 06/28/22 08:45 Received: 06/30/22 14:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
Mercury ND ug/L 0.20 0.12 1 07/02/2218:57 07/08/2215:50 7439-97-6
Date: 07/20/2022 12:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
P989041 WY&e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Sample: 2022014433 Lab ID: 92612702009 Collected: 06/28/22 13:30 Received: 06/30/22 14:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
Mercury ND ug/L 0.20 0.12 1 07/02/2218:57 07/08/2215:56 7439-97-6
Date: 07/20/2022 12:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 14 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
P98904ir6fYke. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Sample: 2022014434 Lab ID: 92612702010 Collected: 06/28/22 14:00 Received: 06/30/22 14:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
Mercury ND ug/L 0.20 0.12 1 07/02/2218:57 07/08/2215:59 7439-97-6
Date: 07/20/2022 12:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
P989041 WeYke. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Sample: 2022014435 Lab ID: 92612702011 Collected: 06/29/22 08:40 Received: 06/30/22 14:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
Mercury ND ug/L 0.20 0.12 1 07/02/2218:57 07/08/2216:01 7439-97-6
Date: 07/20/2022 12:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 16 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
P989041 WeYke. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Sample: 2022014436 Lab ID: 92612702012 Collected: 06/28/22 11:35 Received: 06/30/22 14:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
Mercury ND ug/L 0.20 0.12 1 07/02/2218:57 07/08/2216:03 7439-97-6
Date: 07/20/2022 12:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
P989041 WY&e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Sample: 2022014437 Lab ID: 92612702013 Collected: 06/28/22 10:20 Received: 06/30/22 14:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
Mercury ND ug/L 0.20 0.12 1 07/02/2218:57 07/08/2216:05 7439-97-6
Date: 07/20/2022 12:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
P989041� Yke. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Sample: 2022014438 Lab ID: 92612702014 Collected: 06/28/22 11:00 Received: 06/30/22 14:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
Mercury ND ug/L 0.20 0.12 1 07/02/2218:57 07/08/2216:07 7439-97-6
Date: 07/20/2022 12:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 19 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
Pdag041� y&e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Sample: 2022014439 Lab ID: 92612702015 Collected: 06/28/22 14:30 Received: 06/30/22 14:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
Mercury ND ug/L 0.20 0.12 1 07/02/2218:57 07/08/2216:09 7439-97-6
Date: 07/20/2022 12:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 20 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
P989041 WeYke. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Sample: 2022014440 Lab ID: 92612702016 Collected: 06/29/22 10:00 Received: 06/30/22 14:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
Mercury ND ug/L 0.20 0.12 1 07/02/2218:57 07/08/2216:11 7439-97-6
Date: 07/20/2022 12:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 21 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
P989041 WeYke. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Sample: 2022014442 Lab ID: 92612702017 Collected: 06/28/22 00:00 Received: 06/30/22 14:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
Mercury ND ug/L 0.20 0.12 1 07/02/2218:57 07/08/2216:13 7439-97-6
Date: 07/20/2022 12:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 22 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
P9890AYke. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
QC Batch: 708508 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92612702001, 92612702002, 92612702003, 92612702004, 92612702005, 92612702006, 92612702007,
92612702008,92612702009,92612702010,92612702011,92612702012,92612702013,92612702014,
92612702015,92612702016,92612702017
METHOD BLANK: 3695190 Matrix: Water
Associated Lab Samples: 92612702001, 92612702002, 92612702003, 92612702004, 92612702005, 92612702006, 92612702007,
92612702008,92612702009,92612702010,92612702011,92612702012,92612702013,92612702014,
92612702015,92612702016,92612702017
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Mercury ug/L ND 0.20 0.12 07/08/2215:15
LABORATORY CONTROL SAMPLE: 3695191
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 2.5 2.8 111 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3695192 3695193
MS MSD
92612702001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND 2.5 2.5 2.7 2.6 109 106 75-125 3 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/20/2022 12:25 PM without the written consent of Pace Analytical Services, LLC.
Page 23 of 29

lacieAnalj&al
www,pacelabs.com
Pace Analytical Services, LLC
PAR05k wyke. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/20/2022 12:25 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 29

laceAnalytical"'
www,pacelabs.com
Pace Analytical Services, LLC
p�ag%�irfyke. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J22060046 MNS LF #2
Pace Project No.: 92612702
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Analytical
Batch
92612702001
2022014425
EPA
7470A
708508
EPA
7470A
708523
92612702002
2022014426
EPA
7470A
708508
EPA
7470A
708523
92612702003
2022014427
EPA
7470A
708508
EPA
7470A
708523
92612702004
2022014428
EPA
7470A
708508
EPA
7470A
708523
92612702005
2022014429
EPA
7470A
708508
EPA
7470A
708523
92612702006
2022014430
EPA
7470A
708508
EPA
7470A
708523
92612702007
2022014431
EPA
7470A
708508
EPA
7470A
708523
92612702008
2022014432
EPA
7470A
708508
EPA
7470A
708523
92612702009
2022014433
EPA
7470A
708508
EPA
7470A
708523
92612702010
2022014434
EPA
7470A
708508
EPA
7470A
708523
92612702011
2022014435
EPA
7470A
708508
EPA
7470A
708523
92612702012
2022014436
EPA
7470A
708508
EPA
7470A
708523
92612702013
2022014437
EPA
7470A
708508
EPA
7470A
708523
92612702014
2022014438
EPA
7470A
708508
EPA
7470A
708523
92612702015
2022014439
EPA
7470A
708508
EPA
7470A
708523
92612702016
2022014440
EPA
7470A
708508
EPA
7470A
708523
92612702017
2022014442
EPA
7470A
708508
EPA
7470A
708523
Date: 07/20/2022 12:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 25 of 29

1+( � �-- +�t� -r tti�•t^� tvly a vvo+? vu i—acaml7ie urinnitlon upon Receipt
N"IFYI+
Effective Date: OS V202205/12/2022
52 of 180
Laboratory receiving samples:
Asheville Eden[) Greenwood ❑ Nuntersville Imo' RaleigfiLl
Client Name: om Pry;
Courier: ❑Fed Ex ❑UP5 ❑USPS r
❑Commercial ❑_Bent
""fir// ❑Others
ftistody ScaMrertt--[�fes kffN0' ea s inf tact?
Packing Material: ❑BUbble Wrap ❑bubble Bags
Thermometer
R Gun iU: v
Tvpe of Ice:
Correction Factor: ,
Cooler Temp; Add/Subtract mi LJ
one ❑ Other
Mecltaniesville❑ Atlanta❑ Kernersv]Ile❑
WO# : 92612702
1111111111111111111111
92612702
� �
Oate/InRso lals Pern Examining Con lanis; +- l
Biological Tissue Ewen?
Dyes ONO N/A
�1001ue ❑None
Cooler Temp Corrected ('Cl:
USDA Regulated Soil { /A, avatar sample]
Did samples onelnate In a quarantine cone within the United states; CA, NY, arSC
(check maps]? []Yes (]No
Chain of Custody Present?
Samples thrived within Hold Time?
Short Hold Time Analysis (c72 hr.)?
Rush Turn Around Time Requested?
5ufficlent Volume?
Correct Containers Used?
-Pace Contalne(S Used?
Containeislntact?
Dissolved analysis: Samples Field Filtered?
Sample Labels Match coC?
Includes pate/11 a/ID/Anolysls
Head -space in VOA Vials ()-5.6mm)?
Trip Blank Present?
Trip Blank Ctatody Seals Present?
COMMENTS/SAMPLE DISCREPANCY
❑Na
❑N/A
Dyes C;K'
❑NfA
ei ❑NO
❑�Y/A
❑Yes a
❑N/A
es [IN.
❑N/A
Lw.'Ad
❑Yes ❑NQ 1]K/"A
E]Yes CINU 0 /A
❑Samples nut of temp Criteria. samples on ice, cooling process
has begun
Clid urnplesoriginate from a romfgn source (internationally,
mcfuding Hawaii and Puerto Rico!? ❑Yes ❑No
Field Data Required? []Yes
---CLtCcW�NDFIHC-friiE3MfRE5�ttiT10N ___ I-O[ fD of 3plltconialn@(S: _ _ _
Person contacted-,
-Prclect Managet-SCURFReview:--
——�l�td4lanagar�R� �eview:�
Date/Time:
Date:
QUaltraX 0' 69614 Page 26 of 29
Page I :,'

7 Face - . _ _ _ . ,.... -w— to }_,,Qrtwrer ti,wiuinon upon Koceipt
Page 53 of 180
Effective Date: 05/1212022OS/12/2022
"Check mark top half of box if pH and/or dechlorinatfan Is verified and Project WO# , 92612702 �
Within the acceptance range for preservation samples, �� t E-Wtons: VOA, coliform. TUC, Oil and Grease, OR018015 iwaterj DOC, LLHA Dina b"G t 07y9811
"Bottom half of box is to list number of bottles CLIENTI 12-iRLrke I nir
'Check all unpreserved Nitrates for chlorine
a
G A m
x u v a 4
z 2 u O
9 t7 2 iV r+1 14 c z M U ¢ 2 N N n 2 ;
p y3� N \
L Z zto
v rh CV ? in
c c c O d O M Y a a O 2 x _ if b d
a
�+ N u ? u %j Z 7 ` w` z Z ij c m `a 4 `a 2
10
nM IL E d d� o a o m E
�E E E -� a a a ¢ 1 > > y > a � ut a >:
4 O ) E L :_.� :: v it J J
uN0i M ,a O o a d a E E lc E o E E
IE v In rOi .Oi ry dt 9 7 Jr _ 5 V ry P p o q
V.ro m m m m m 3l'�7 ch
L7 °' C" m ka
ka c chi
o M v m o o
1
2-
3
4
5
ti
i
8
9
10
11
12
pH Adjustment Log for Preserved Samples
Sample lt) Type of Preservative pH upon receipt hate pret;ervatian adjusted Time preserwtion Amount or Preservative
Lot N
adjusted added
Not@:"Vllt10-=1rthere -c a n7c�ron�prf g{fem ly,�u� rGri..p�nplluGi� ie,�lNl�s, a 4upy of shl� roan w li ee feet to the Harth Caralfna OENR CerllflcaNan l7fr
Out of hold, incorrect preservaNJe, out of temp, incorrect container;,
QUallraX ID; 0614 !'age Z of 2 Page 27 of 29

• . .•... ..+r., wV t .-Y;r1,11JIV s..utsUM011 Upull mucap
EFFeativo Onto: 05112l20220S/12/2027
*Check mark top half of box if pkl and/or dechlorination is verified and
within the acceptance range for preservation samples.
Ertwptfcns: VOA, Celiforin, TOG, Oil and Groaso, oRO/8ol5 (water) DOC, llllg
*'"Bottom half of box Is to list number of bottles
***Check0 unpreserued Nitrates for chlorine
z
z
z
w
u
n
7
a
E
a
^
n
V
`a
E
w
to
IVU
a
u
a
E
a
c
A
a
M
V
=
&
O
0
x
V
a
LA
m
m
m
m
1
2
3
d
5
6
7
e
9
to
1]
age 54 of 180
Wog: 9261127
Project 1! ��
PM: khfG Due Dale; 07/08/22
CLIENT: 92-Duke Ener
V
'�
M
O
1Y1
m
m
C
p
q
rw
aIL
F
r
m
C7
M
�+
0
z
E
lit
m
C
N
o
13
E
n
c
v
v
a
`a
.��.
a
q
rJ
IQ'II
a
eu
�V^.
x04
4
a
Q
Q
rw
O
t:
w
4
x
S
'�
a
E
Q
2
f=
a
E
Z
o
�C
G
Q
0
1cc
G
Y
J
t:
0
�CC
C
a
o
o
1
E
a
>
b
a
i
Yir
�C
G
h
i
�.
ti
Wr
E
�
n
x
y�
m
"
a
Qs
a
z
J
�'
t
z
a
gg
J
❑
PH Adjustment log for Preserved Samples
Sampfe !D Yype aF Preservative pH upon recetp! pate presetvallan adjusted Time presrrrwfion Amount of Viaervative
adlusied added
Out of hold, incorrect proseraative, out of temp, incortett con IMAM.
Lot N
A ropy Of t101 torn) wld be Amt to t11e Narth Gsrglina OEN CCeHil1cat(pr10111, tl-e-
Pa e 28 of 29
Quallrax IQ: 69614 1]8yA 2 of g

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FQRM Page 55 of 180
_
/.� UUKt sei0ere,slacilu{emmnal+aeY
ENERGY lsaen�.nr.tN,
jarderK J22D60046
Nlalft WA71;R
>wC x
�`
Raye_Y_al i-0
u¢tanrwu, n. c. tserr
PLl, as•au
lLuae� av pel. a 11nn
SAMPLE PROGRAM
-'
ORfr.KAL
!
tt LAri ccw4 is
CLIENT a)
•Pralel:r Nema MNS LANDFILL 02 PC-IWFTN Gp rn. s
�v�tm wa. cn+vmblr
�. '�.
Onnk g Waler x—
RCRA Wale
fIP
- jj,,��
Client Ethan Smith
i Bryan Elowle►l
L
;Pc
e�
cooTtsimP [CI
Couttnoy Mur�fiY l /lshie�l Hea!
i 1
F+Irratlon t4.45 I,m}
Unfihared
!1
Flt{nrad
OPerali Unit:
'�
Pmene: $LOFLti v Aeanun!. —
Po # 9112111
PrFsetvalive X* Ila
I[F ICE
ICE
Ibg. KOL
PrairFe:
Au1Mty Mi Faeility ID:
G0�—_
__
Cantaimrr Volume ImL} 4o ml
500IM ]p0 ml 300 rn1
1000 ml
40 ml
50D ml
_
P"rxm! EUWeB taw code- qub-Vrngr.mlT2" Cade:
Cunlainer Type
A
4
��
z
Sample Description or fD
Costumer td carapure ago aylpraprralr aona0mwo ar.,rs
a s..y
�d tl a
ft ao^ci w w
gr�
,c d F a > ' i
�m
s
a
`343.
_ SAMPLE IO i
1r W CaP
g
ar_ K
T
_
Y'
NUMBER
Date Tula d ��rllrelllYn Si
pn
ar1aE [i O? m J
�. B r i m < V O
e 6 W
M U
V
•C
C2w,
2022�0144 $
MNs MVJSr,
(g 7 !AQ
a 4� w
x
a
1
1
t
3
I
2=0144215 i
MNS_MWSA
MNE_MW�5
1c
-�%7"�
{
t.aI101'
A,
-
it
x
3
3
i
1
s
1
1
3
3
—
I
—
y
f
4
? 20220144271
i 202201, za ,
MM5_MW-6n
�Z %,�
1046
CO 11_lafn
.Gr a1101C1
S 2022014429
MNS kflA/-7p
�1 L'j 7X
I-Z 50
&jkLvl SM,IAA,
X
3
1
1
1
3
}
!
2022014430 1
MNS_MW-TA
14,129AZ
r" t,
T FiCVI
—
2022014431
MNS_MW-8
1 gl7fidr 1:0 16 c.
`�
x
9
`
2022014432 {
�
MN5_Mvv eA
��� l;
r rr
� 7
a -,
e.iirlGf
r
lt:
S
1
1
1
3
�•
!
202201"33
Miles MW-s
-
T4'4w sr. Rh
x
3
1
t
1
3
1
<.
F 2022014434
MN5 MW-3A
{p 2_7
Q
1LQ_
j 41 F�+
X
3
i
1
1
3
I
!
i 202201"35
MNS_Mw-$OA
j9
�} _
r
$�i11'cL
x
3
1
1
1
a
1
!
2022014436 i
MNS SW-1
y
?
2022014437 i
MNS_SW-2
6 2Y
10 kO
-
i 202MI4438
MN� LFACNATE POND
Q{]
LV5
•�
— -
x
a
1
1
1
3
1
T
2022014439!
MN§_FE-'aiZOU,4-14,50
I?
1u30
x
3
1
1
1
9
1
2ox20144401
MNS Fe-� 1y2� - I b4�
WU2
1000
DMpai ZAhhfA
x
s
` 202J a
MNS TO - 2a ZZ GwZ4' U%G0
j 2022014442 [
r;
MN5_FO .
- 1
TOTALdCONTAINERS
64
17
15
2
i7
Sd
0
0
0
d
y{
4 r5lprtl. r tG s, n n to nw
IMYI�07
C Gatemawe
t %f
y
AtcePlad Bsfoo, � p !U �� 13.-1. 11 �'
�j�TJ—��efi�+
..
m e
v a
F7er{i,estctl
2v ileys
Tor*aaraund
Total
L
Rellnaruisne Sy 0alelTmae
�!13L"
_ _
Aeespled $y: ��
a
d
r1sllnllYlel+ed a
ff rti
F A-
--
OateriE
� � � �
14 Qal,
�rr
5vaua+taled By
-- meerrave
r
SealediLocrr OPe"ed By
Dar kMRae
° �
Em
�a
•7 D3ys
Cwnmerits
m
Q
'Olhar
Ad! Cosl Will Apply

Page 56 of 180
0
aceAnalytical
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Peggy Kendall
Project Name: MNS LANDFILL #2 PERMIT 60-04
Project Number: J22060046
Lot Number:XF30056
Date Completed:07/15/2022
Revision Date: 07/22/2022
07/22/2022 11:13 AM
Approved and released by:
Project Manager II: Cathy S. Dover
In
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 123

Page 57 of 180
PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: XF30056
Report Revision 07/22/2022: This PDF report has been revised to update the alkalinity section of the narrative. All
other sample results are as reported in the original PDF report. This report supersedes and replaces any prior
reports issued under this lot number.
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case
Narrative. The sample receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted
by the client, results relate to the accuracy of the information provided, and as the samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The
NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating
procedures (SOPs), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPs or
policies are qualified on the results page or discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of
accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-dichloroethane) EPA 524.2, E. coli and
Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water:
SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and
Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 601 OD, VOC SM 6200 B-
2011, Fecal Coliform Colilert-18.
VOA 8260D
Due to the large number of spiked analytes, there is a high probability that one or more analytes will recover outside
acceptance limits. The laboratory's SOP allows for 10% of analytes to recover marginally outside criteria. The following
analytes recovered marginally outside LCS/LCSD criteria: trans-1,4-Dicloro-2-butene. Associated samples: XF30056-007
(2022014431), XF30056-008 (2022014432), XF30056-009 (2022014433) and XF30056-010 (2022014434).
The LCS for batch 47142 recovered marginally loutish the upper control limit for Bromomethane and Vinyl Chloride. The
associated samples (XF30056-007 (2022014431), XF30056-008 (2022014432), XF30056-009 (2022014433) and
XF30056-010 (2022014434)) were non -detect for these target analytes.
The matrix spike and matrix spike duplicate (MS/MSD) were not reported in batch 47437 due to instrument error. The
sample affected: XF30056-017 (2022014441). The CCV and LCS associated with batch 47437 passed acceptance criteria,
therefore the data has been reported.
1,4-dioxane SIM 8260D
An LCS/LCSD was run in lieu of an MS/MSD for analytical batch 46898 & 47557.
It was found after analysis was completed, that the internal standard solution used had expired on 6/30/22. The internal
standard recovery passed compared to the ICAL that was analyzed prior to expiration, therefore the data for associated
samples is not believed to be impacted:
XF30056-001 (2022014425) (Run 1) (Analysis Batch 46898) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
XF30056-002 (2022014426) (Run 1) (Analysis Batch 46898) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
XF30056-003 (2022014427) (Run 1) (Analysis Batch 46898) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
XF30056-004 (2022014428) (Run 1) (Analysis Batch 46898) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
XF30056-005 (2022014429) (Run 1) (Analysis Batch 46898) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
XF30056-006 (2022014430) (Run 1) (Analysis Batch 46898) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
XF30056-007 (2022014431) (Run 1) (Analysis Batch 46898) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
XF30056-008 (2022014432) (Run 1) (Analysis Batch 46898) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
XF30056-009 (2022014433) (Run 1) (Analysis Batch 46898) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
XF30056-010 (2022014434) (Run 1) (Analysis Batch 46898) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 2 of 123

Page 58 of 180
PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
XF30056-011 (2022014435) (Run 1) (Analysis Batch 46898) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
XF30056-012 (2022014436) (Run 1) (Analysis Batch 46898) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
XF30056-013 (2022014437) (Run 1) (Analysis Batch 46898) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
XF30056-014 (2022014438) (Run 1) (Analysis Batch 46898) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
XF30056-015 (2022014439) (Run 1) (Analysis Batch 46898) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
XF30056-016 (2022014440) (Run 1) (Analysis Batch 46898) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
XF30056-017 (2022014441) (Run 1) (Analysis Batch 47557) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
XF30056-018 (2022014442) (Run 1) (Analysis Batch 46898) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
TPH-DRO 8015C
The DRO sample containers were received unpreserved for this project. The following samples were preserved with 1:1
HCL prior to extraction: XF30056-001, XF30056-002, XF30056-003, XF30056-004, XF30056-005, XF30056-006, XF30056-
007, XF30056-008, XF30056-009, XF30056-010, XF30056-011, XF30056-012, XF30056-013, XF30056-014, XF30056-015,
XF30056-016, and XF30056-018.
XF30056-001 (2022014425) (Run 1) (Analysis Batch 47674) (Prep Batch 47018) TPH-DRO (RVE)
XF30056-002 (2022014426) (Run 1) (Analysis Batch 47674) (Prep Batch 47018) TPH-DRO (RVE)
XF30056-003 (2022014427) (Run 1) (Analysis Batch 47674) (Prep Batch 47018) TPH-DRO (RVE)
XF30056-004 (2022014428) (Run 1) (Analysis Batch 47674) (Prep Batch 47018) TPH-DRO (RVE)
XF30056-005 (2022014429) (Run 1) (Analysis Batch 47674) (Prep Batch 47018) TPH-DRO (RVE)
XF30056-006 (2022014430) (Run 1) (Analysis Batch 47674) (Prep Batch 47018) TPH-DRO (RVE)
XF30056-007 (2022014431) (Run 1) (Analysis Batch 47674) (Prep Batch 47018) TPH-DRO (RVE)
XF30056-008 (2022014432) (Run 1) (Analysis Batch 47674) (Prep Batch 47018) TPH-DRO (RVE)
XF30056-009 (2022014433) (Run 1) (Analysis Batch 47674) (Prep Batch 47018) TPH-DRO (RVE)
XF30056-010 (2022014434) (Run 1) (Analysis Batch 47674) (Prep Batch 47018) TPH-DRO (RVE)
XF30056-011 (2022014435) (Run 1) (Analysis Batch 47674) (Prep Batch 47018) TPH-DRO (RVE)
XF30056-012 (2022014436) (Run 1) (Analysis Batch 47674) (Prep Batch 47018) TPH-DRO (RVE)
XF30056-013 (2022014437) (Run 1) (Analysis Batch 47674) (Prep Batch 47018) TPH-DRO (RVE)
XF30056-014 (2022014438) (Run 1) (Analysis Batch 47674) (Prep Batch 47018) TPH-DRO (RVE)
XF30056-015 (2022014439) (Run 1) (Analysis Batch 47674) (Prep Batch 47018) TPH-DRO (RVE)
XF30056-016 (2022014440) (Run 1) (Analysis Batch 47674) (Prep Batch 47018) TPH-DRO (RVE)
XF30056-018 (2022014442) (Run 1) (Analysis Batch 47674) (Prep Batch 47018) TPH-DRO (RVE)
The method blank associated with batch 47018 had TPH-DRO detected at a concentration that was above the DL but below
the LOQ. All samples associated with this method blank that have detections for TPH-DRO have been flagged with a "B".
Alkalinity
The following samples was analyzed outside of analytical holding time due to calibration failures with the auto titrator:
XF30056-007, XF30056-008, XF30056-009, XF30056-010, XF30056-012, XF30056-013, XF30056-015 and XF30056-018
(2022014442). The auto titrator issue on the instrument was fixed as soon as noticed and these samples were finally
analyzed from 3 minutes to 1 hour and 15 minutes after the 14 day from collection.
XF30056-007 (2022014431) (Run 1) (Analysis Batch 47848) Alkalinity @ pH 4.5 su
XF30056-008 (2022014432) (Run 1) (Analysis Batch 47848) Alkalinity @ pH 4.5 su
XF30056-009 (2022014433) (Run 1) (Analysis Batch 47848) Alkalinity @ pH 4.5 su
XF30056-010 (2022014434) (Run 1) (Analysis Batch 47848) Alkalinity @ pH 4.5 su
XF30056-012 (2022014436) (Run 1) (Analysis Batch 47848) Alkalinity @ pH 4.5 su
XF30056-013 (2022014437) (Run 1) (Analysis Batch 47848) Alkalinity @ pH 4.5 su
XF30056-015 (2022014439) (Run 1) (Analysis Batch 47848) Alkalinity @ pH 4.5 su
XF30056-018 (2022014442) (Run 1) (Analysis Batch 47851) Alkalinity @ pH 4.5 su
If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 123

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Duke Energy
Lot Number: XF30056
Project Name: MNS LANDFILL #2 PERMIT 60-04
Project Number: J22060046
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
2022014425
Aqueous
06/28/20221405
06/30/2022
002
2022014426
Aqueous
06/28/20221240
06/30/2022
003
2022014427
Aqueous
06/29/20221015
06/30/2022
004
2022014428
Aqueous
06/29/20221040
06/30/2022
005
2022014429
Aqueous
06/28/20221250
06/30/2022
006
2022014430
Aqueous
06/28/20221150
06/30/2022
007
2022014431
Aqueous
06/28/2022 0915
06/30/2022
008
2022014432
Aqueous
06/28/2022 0845
06/30/2022
009
2022014433
Aqueous
06/28/20221330
06/30/2022
010
2022014434
Aqueous
06/28/20221400
06/30/2022
011
2022014435
Aqueous
06/29/2022 0840
06/30/2022
012
2022014436
Aqueous
06/28/20221135
06/30/2022
013
2022014437
Aqueous
06/28/20221020
06/30/2022
014
2022014438
Aqueous
06/29/20221100
06/30/2022
015
2022014439
Aqueous
06/28/20221430
06/30/2022
016
2022014440
Aqueous
06/29/20221000
06/30/2022
017
2022014441
Aqueous
06/28/2022 0800
06/30/2022
018
2022014442
Aqueous
06/28/2022
06/30/2022
(18 samples)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 123

PACE ANALYTICAL SERVICES, LLC
Detection Summary
Duke Energy
Lot Number: XF30056
Project Name: MNS LANDFILL #2 PERMIT 60-04
Project Number: J22060046
Sample Sample ID
Matrix
Parameter
Method
Result
Q
Units
Page
001
2022014425
Aqueous
TPH-DRO
8015C
180
BJ
ug/L
10
002
2022014426
Aqueous
Alkalinity @ pH 4.5 su
SM 232013-
25
mg CaCO3/L
11
002
2022014426
Aqueous
TPH-DRO
8015C
190
BJ
ug/L
15
003
2022014427
Aqueous
Alkalinity @ pH 4.5 su
SM 232013-
37
mg CaCO3/1-
16
003
2022014427
Aqueous
TPH-DRO
8015C
170
BJ
ug/L
20
004
2022014428
Aqueous
TPH-DRO
8015C
230
B
ug/L
25
005
2022014429
Aqueous
Alkalinity @ pH 4.5 su
SM 232013-
22
mg CaCO3/L
26
005
2022014429
Aqueous
TPH-DRO
8015C
180
BJ
ug/L
30
006
2022014430
Aqueous
Alkalinity @ pH 4.5 su
SM 232013-
62
mg CaCO3/L
31
006
2022014430
Aqueous
TPH-DRO
8015C
140
BJ
ug/L
35
007
2022014431
Aqueous
Alkalinity @ pH 4.5 su
SM 232013-
68
H
mg CaCO3/1-
36
007
2022014431
Aqueous
TPH-DRO
8015C
150
BJ
ug/L
40
008
2022014432
Aqueous
Alkalinity @ pH 4.5 su
SM 232013-
53
H
mg CaCO3/L
41
008
2022014432
Aqueous
TPH-DRO
8015C
170
BJ
ug/L
45
009
2022014433
Aqueous
Alkalinity @ pH 4.5 su
SM 232013-
38
H
mg CaCO3/1-
46
009
2022014433
Aqueous
TPH-DRO
8015C
190
BJ
ug/L
50
010
2022014434
Aqueous
Alkalinity @ pH 4.5 su
SM 232013-
61
H
mg CaCO3/L
51
010
2022014434
Aqueous
TPH-DRO
8015C
140
BJ
ug/L
55
011
2022014435
Aqueous
TPH-DRO
8015C
160
BJ
ug/L
60
012
2022014436
Aqueous
Alkalinity @ pH 4.5 su
SM 232013-
62
H
mg CaCO3/L
61
012
2022014436
Aqueous
TPH-DRO
8015C
150
BJ
ug/L
65
013
2022014437
Aqueous
Alkalinity @ pH 4.5 su
SM 232013-
62
H
mg CaCO3/L
66
013
2022014437
Aqueous
TPH-DRO
8015C
170
BJ
ug/L
70
014
2022014438
Aqueous
Alkalinity @ pH 4.5 su
SM 232013-
350
mg CaCO3/L
71
014
2022014438
Aqueous
TPH-DRO
8015C
4700
B
ug/L
75
015
2022014439
Aqueous
TPH-DRO
8015C
150
BJ
ug/L
80
016
2022014440
Aqueous
Acetone
8260D
6.9
J
ug/L
82
016
2022014440
Aqueous
TPH-DRO
8015C
130
BJ
ug/L
85
018
2022014442
Aqueous
Alkalinity @ pH 4.5 su
SM 232013-
52
H
mg CaCO3/L
89
018
2022014442
Aqueous
TPH-DRO
8015C
130
BJ
ug/L
93
(30 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 123

Inorganic non-metals
Client: Duke Energy Laboratory ID:XF30056-001
Description: 2022014425 Matrix: Aqueous
Date Sampled:06/28/2022 1405 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity @) SM 2320B-2011 1 07/12/2022 2315 TAD 47848
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Alkalinity @ pH 4.5 su SM 2320B-2011 ND 20 20 mg CaCO3/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-001
Description: 2022014425 Matrix: Aqueous
Date Sampled:06/28/2022 1405 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 07/06/20221655 BBW
47150
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
ND
20
5.0
ug/L
1
Acrylonitrile
107-13-1
8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2
8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2
8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
ND
1.0
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
ND
1.0
0.40
ug/L
1
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
1
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
1
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
1
Toluene
108-88-3
8260D
ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-001
Description: 2022014425 Matrix: Aqueous
Date Sampled:06/28/2022 1405 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D 1 07/06/20221655 BBW
47150
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units Run
Vinyl acetate
108-05-4 8260D
ND
5.0
1.2
ug/L 1
Vinyl chloride
75-01-4 8260D
ND
1.0
0.40
ug/L 1
Xylenes (total)
1330-20-7 8260D
ND
1.0
0.40
ug/L 1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
95 70-130
1,2-Dichloroethane-d4
102 70-130
Toluene-d8
100 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 123

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:XF30056-001
Description: 2022014425 Matrix: Aqueous
Date Sampled:06/28/2022 1405 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 07/01/2022 2203 SDC 46898
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
83 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 123

TPH-DRO
Client: Duke Energy Laboratory ID:XF30056-001
Description: 2022014425 Matrix: Aqueous
Date Sampled:06/28/2022 1405 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 07/11/2022 1747 NCM 07/05/2022 1205 47018
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C 180 BJ 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
114 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 123

Inorganic non-metals
Client: Duke Energy Laboratory ID:XF30056-002
Description: 2022014426 Matrix: Aqueous
Date Sampled:06/28/2022 1240 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity @) SM 2320B-2011 1 07/12/2022 2320 TAD 47848
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Alkalinity @ pH 4.5 su SM 2320B-2011 25 20 20 mg CaCO3/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-002
Description: 2022014426 Matrix: Aqueous
Date Sampled:06/28/2022 1240 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 07/06/20221720 BBW
47150
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
ND
20
5.0
ug/L
1
Acrylonitrile
107-13-1
8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2
8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2
8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
ND
1.0
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
ND
1.0
0.40
ug/L
1
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
1
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
1
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
1
Toluene
108-88-3
8260D
ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 12 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-002
Description: 2022014426 Matrix: Aqueous
Date Sampled:06/28/2022 1240 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D 1 07/06/20221720 BBW
47150
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units Run
Vinyl acetate
108-05-4 8260D
ND
5.0
1.2
ug/L 1
Vinyl chloride
75-01-4 8260D
ND
1.0
0.40
ug/L 1
Xylenes (total)
1330-20-7 8260D
ND
1.0
0.40
ug/L 1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
94 70-130
1,2-Dichloroethane-d4
100 70-130
Toluene-d8
99 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 13 of 123

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:XF30056-002
Description: 2022014426 Matrix: Aqueous
Date Sampled:06/28/2022 1240 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 07/01/2022 2227 SDC 46898
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
81 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 14 of 123

TPH-DRO
Client: Duke Energy Laboratory ID:XF30056-002
Description: 2022014426 Matrix: Aqueous
Date Sampled:06/28/2022 1240 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 07/11/2022 1814 NCM 07/05/2022 1205 47018
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C 190 BJ 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
110 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 15 of 123

Inorganic non-metals
Client: Duke Energy Laboratory ID:XF30056-003
Description: 2022014427 Matrix: Aqueous
Date Sampled:06/29/2022 1015 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity @) SM 2320B-2011 1 07/12/2022 2325 TAD 47848
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Alkalinity @ pH 4.5 su SM 2320B-2011 37 20 20 mg CaCO3/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 16 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-003
Description: 2022014427 Matrix: Aqueous
Date Sampled:06/29/2022 1015 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 07/06/20221745 BBW
47150
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
ND
20
5.0
ug/L
1
Acrylonitrile
107-13-1
8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2
8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2
8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
ND
1.0
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
ND
1.0
0.40
ug/L
1
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
1
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
1
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
1
Toluene
108-88-3
8260D
ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 17 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-003
Description: 2022014427 Matrix: Aqueous
Date Sampled:06/29/2022 1015 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D 1 07/06/20221745 BBW
47150
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units Run
Vinyl acetate
108-05-4 8260D
ND
5.0
1.2
ug/L 1
Vinyl chloride
75-01-4 8260D
ND
1.0
0.40
ug/L 1
Xylenes (total)
1330-20-7 8260D
ND
1.0
0.40
ug/L 1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
89 70-130
1,2-Dichloroethane-d4
99 70-130
Toluene-d8
96 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 18 of 123

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:XF30056-003
Description: 2022014427 Matrix: Aqueous
Date Sampled:06/29/2022 1015 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 07/01/2022 2251 SDC 46898
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
80 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 19 of 123

TPH-DRO
Client: Duke Energy Laboratory ID:XF30056-003
Description: 2022014427 Matrix: Aqueous
Date Sampled:06/29/2022 1015 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 07/11/2022 1823 NCM 07/05/2022 1205 47018
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C 170 BJ 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
113 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 20 of 123

Inorganic non-metals
Client: Duke Energy Laboratory ID:XF30056-004
Description: 2022014428 Matrix: Aqueous
Date Sampled:06/29/2022 1040 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity @) SM 2320B-2011 1 07/12/2022 2339 TAD 47848
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Alkalinity @ pH 4.5 su SM 2320B-2011 ND 20 20 mg CaCO3/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 21 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-004
Description: 2022014428 Matrix: Aqueous
Date Sampled:06/29/2022 1040 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 07/06/20221809 BBW
47150
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
ND
20
5.0
ug/L
1
Acrylonitrile
107-13-1
8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2
8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2
8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
ND
1.0
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
ND
1.0
0.40
ug/L
1
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
1
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
1
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
1
Toluene
108-88-3
8260D
ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 22 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-004
Description: 2022014428 Matrix: Aqueous
Date Sampled:06/29/2022 1040 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D 1 07/06/20221809 BBW
47150
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units Run
Vinyl acetate
108-05-4 8260D
ND
5.0
1.2
ug/L 1
Vinyl chloride
75-01-4 8260D
ND
1.0
0.40
ug/L 1
Xylenes (total)
1330-20-7 8260D
ND
1.0
0.40
ug/L 1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
85 70-130
1,2-Dichloroethane-d4
88 70-130
Toluene-d8
91 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 23 of 123

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:XF30056-004
Description: 2022014428 Matrix: Aqueous
Date Sampled:06/29/2022 1040 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 07/01/2022 2315 SDC 46898
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
84 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 24 of 123

TPH-DRO
Client: Duke Energy Laboratory ID:XF30056-004
Description: 2022014428 Matrix: Aqueous
Date Sampled:06/29/2022 1040 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 07/11/2022 1832 NCM 07/05/2022 1205 47018
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C 230 B 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
112 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 25 of 123

Inorganic non-metals
Client: Duke Energy Laboratory ID:XF30056-005
Description: 2022014429 Matrix: Aqueous
Date Sampled:06/28/2022 1250 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity @) SM 2320B-2011 1 07/12/2022 2344 TAD 47848
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Alkalinity @ pH 4.5 su SM 2320B-2011 22 20 20 mg CaCO3/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 26 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-005
Description: 2022014429 Matrix: Aqueous
Date Sampled:06/28/2022 1250 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 07/06/20221210 BBW
47152
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
ND
20
5.0
ug/L
1
Acrylonitrile
107-13-1
8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2
8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2
8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
ND
1.0
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
ND
1.0
0.40
ug/L
1
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
1
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
1
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
1
Toluene
108-88-3
8260D
ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 27 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-005
Description: 2022014429 Matrix: Aqueous
Date Sampled:06/28/2022 1250 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D 1 07/06/20221210 BBW
47152
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units Run
Vinyl acetate
108-05-4 8260D
ND
5.0
1.2
ug/L 1
Vinyl chloride
75-01-4 8260D
ND
1.0
0.40
ug/L 1
Xylenes (total)
1330-20-7 8260D
ND
1.0
0.40
ug/L 1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
92 70-130
1,2-Dichloroethane-d4
99 70-130
Toluene-d8
96 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 28 of 123

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:XF30056-005
Description: 2022014429 Matrix: Aqueous
Date Sampled:06/28/2022 1250 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 07/01/2022 2340 SDC 46898
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
82 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 29 of 123

TPH-DRO
Client: Duke Energy Laboratory ID:XF30056-005
Description: 2022014429 Matrix: Aqueous
Date Sampled:06/28/2022 1250 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 07/11/2022 1841 NCM 07/05/2022 1205 47018
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C 180 BJ 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
115 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 30 of 123

Inorganic non-metals
Client: Duke Energy Laboratory ID:XF30056-006
Description: 2022014430 Matrix: Aqueous
Date Sampled:06/28/2022 1150 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity @) SM 2320B-2011 1 07/12/2022 2356 TAD 47848
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Alkalinity @ pH 4.5 su SM 2320B-2011 62 20 20 mg CaCO3/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 31 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-006
Description: 2022014430 Matrix: Aqueous
Date Sampled:06/28/2022 1150 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 07/06/20221233 BBW
47152
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
ND
20
5.0
ug/L
1
Acrylonitrile
107-13-1
8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2
8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2
8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
ND
1.0
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
ND
1.0
0.40
ug/L
1
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
1
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
1
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
1
Toluene
108-88-3
8260D
ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 32 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-006
Description: 2022014430 Matrix: Aqueous
Date Sampled:06/28/2022 1150 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D 1 07/06/20221233 BBW
47152
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units Run
Vinyl acetate
108-05-4 8260D
ND
5.0
1.2
ug/L 1
Vinyl chloride
75-01-4 8260D
ND
1.0
0.40
ug/L 1
Xylenes (total)
1330-20-7 8260D
ND
1.0
0.40
ug/L 1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
90 70-130
1,2-Dichloroethane-d4
98 70-130
Toluene-d8
94 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 33 of 123

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:XF30056-006
Description: 2022014430 Matrix: Aqueous
Date Sampled:06/28/2022 1150 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 07/02/2022 0004 SDC 46898
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
82 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 34 of 123

TPH-DRO
Client: Duke Energy Laboratory ID:XF30056-006
Description: 2022014430 Matrix: Aqueous
Date Sampled:06/28/2022 1150 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 07/11/2022 1850 NCM 07/05/2022 1205 47018
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C 140 BJ 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
113 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 35 of 123

Inorganic non-metals
Client: Duke Energy Laboratory ID:XF30056-007
Description: 2022014431 Matrix: Aqueous
Date Sampled:06/28/2022 0915 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity @) SM 2320B-2011 1 07/13/2022 0003 TAD 47848
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Alkalinity @ pH 4.5 su SM 2320B-2011 68 H 20 20 mg CaCO3/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 36 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-007
Description: 2022014431 Matrix: Aqueous
Date Sampled:06/28/2022 0915 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 07/06/20221539 JWO
47142
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
ND
20
5.0
ug/L
1
Acrylonitrile
107-13-1
8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2
8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2
8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
ND L
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
ND
1.0
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
ND
1.0
0.40
ug/L
1
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
1
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND L
2.0
0.50
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
1
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
1
Toluene
108-88-3
8260D
ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 37 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-007
Description: 2022014431 Matrix: Aqueous
Date Sampled:06/28/2022 0915 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 07/06/20221539 JWO 47142
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1
Vinyl chloride 75-01-4 8260D ND L 1.0 0.40 ug/L 1
Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
96 70-130
86 70-130
92 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 38 of 123

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:XF30056-007
Description: 2022014431 Matrix: Aqueous
Date Sampled:06/28/2022 0915 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 07/02/2022 0028 SDC 46898
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
84 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 39 of 123

TPH-DRO
Client: Duke Energy Laboratory ID:XF30056-007
Description: 2022014431 Matrix: Aqueous
Date Sampled:06/28/2022 0915 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 07/11/2022 1859 NCM 07/05/2022 1205 47018
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C 150 BJ 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
114 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 40 of 123

Inorganic non-metals
Client: Duke Energy Laboratory ID:XF30056-008
Description: 2022014432 Matrix: Aqueous
Date Sampled:06/28/2022 0845 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity @) SM 2320B-2011 1 07/13/2022 0009 TAD 47848
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Alkalinity @ pH 4.5 su SM 2320B-2011 53 H 20 20 mg CaCO3/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 41 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-008
Description: 2022014432 Matrix: Aqueous
Date Sampled:06/28/2022 0845 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 07/06/20221605 JWO
47142
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
ND
20
5.0
ug/L
1
Acrylonitrile
107-13-1
8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2
8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2
8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
ND L
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
ND
1.0
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
ND
1.0
0.40
ug/L
1
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
1
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND L
2.0
0.50
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
1
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
1
Toluene
108-88-3
8260D
ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 42 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-008
Description: 2022014432 Matrix: Aqueous
Date Sampled:06/28/2022 0845 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 07/06/20221605 JWO 47142
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1
Vinyl chloride 75-01-4 8260D ND L 1.0 0.40 ug/L 1
Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
96 70-130
84 70-130
92 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 43 of 123

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:XF30056-008
Description: 2022014432 Matrix: Aqueous
Date Sampled:06/28/2022 0845 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 07/02/2022 0052 SDC 46898
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
80 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 44 of 123

TPH-DRO
Client: Duke Energy Laboratory ID:XF30056-008
Description: 2022014432 Matrix: Aqueous
Date Sampled:06/28/2022 0845 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 07/11/2022 1908 NCM 07/05/2022 1205 47018
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C 170 BJ 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
113 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 45 of 123

Inorganic non-metals
Client: Duke Energy Laboratory ID:XF30056-009
Description: 2022014433 Matrix: Aqueous
Date Sampled:06/28/2022 1330 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity @) SM 2320B-2011 1 07/13/2022 0014 TAD 47848
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Alkalinity @ pH 4.5 su SM 2320B-2011 38 H 20 20 mg CaCO3/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 46 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-009
Description: 2022014433 Matrix: Aqueous
Date Sampled:06/28/2022 1330 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 07/06/20221630 JWO
47142
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
ND
20
5.0
ug/L
1
Acrylonitrile
107-13-1
8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2
8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2
8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
ND L
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
ND
1.0
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
ND
1.0
0.40
ug/L
1
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
1
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND L
2.0
0.50
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
1
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
1
Toluene
108-88-3
8260D
ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 47 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-009
Description: 2022014433 Matrix: Aqueous
Date Sampled:06/28/2022 1330 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 07/06/20221630 JWO 47142
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1
Vinyl chloride 75-01-4 8260D ND L 1.0 0.40 ug/L 1
Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
93 70-130
100 70-130
95 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 48 of 123

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:XF30056-009
Description: 2022014433 Matrix: Aqueous
Date Sampled:06/28/2022 1330 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 07/02/2022 0116 SDC 46898
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
84 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 49 of 123

TPH-DRO
Client: Duke Energy Laboratory ID:XF30056-009
Description: 2022014433 Matrix: Aqueous
Date Sampled:06/28/2022 1330 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 07/11/2022 1917 NCM 07/05/2022 1205 47018
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C 190 BJ 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
114 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 50 of 123

Inorganic non-metals
Client: Duke Energy Laboratory ID:XF30056-010
Description: 2022014434 Matrix: Aqueous
Date Sampled:06/28/2022 1400 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity @) SM 2320B-2011 1 07/13/2022 0020 TAD 47848
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Alkalinity @ pH 4.5 su SM 2320B-2011 61 H 20 20 mg CaCO3/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 51 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-010
Description: 2022014434 Matrix: Aqueous
Date Sampled:06/28/2022 1400 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 07/06/20221656 JWO
47142
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
ND
20
5.0
ug/L
1
Acrylonitrile
107-13-1
8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2
8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2
8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
ND L
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
ND
1.0
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
ND
1.0
0.40
ug/L
1
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
1
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND L
2.0
0.50
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
1
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
1
Toluene
108-88-3
8260D
ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 52 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-010
Description: 2022014434 Matrix: Aqueous
Date Sampled:06/28/2022 1400 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 07/06/20221656 JWO 47142
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1
Vinyl chloride 75-01-4 8260D ND L 1.0 0.40 ug/L 1
Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
93 70-130
103 70-130
94 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 53 of 123

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:XF30056-010
Description: 2022014434 Matrix: Aqueous
Date Sampled:06/28/2022 1400 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 07/02/2022 0140 SDC 46898
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
81 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 54 of 123

TPH-DRO
Client: Duke Energy Laboratory ID:XF30056-010
Description: 2022014434 Matrix: Aqueous
Date Sampled:06/28/2022 1400 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 07/11/2022 1926 NCM 07/05/2022 1205 47018
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C 140 BJ 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
114 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 55 of 123

Inorganic non-metals
Client: Duke Energy Laboratory ID:XF30056-011
Description: 2022014435 Matrix: Aqueous
Date Sampled:06/29/2022 0840 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity @) SM 2320B-2011 1 07/13/2022 0025 TAD 47848
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Alkalinity @ pH 4.5 su SM 2320B-2011 ND 20 20 mg CaCO3/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 56 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-011
Description: 2022014435 Matrix: Aqueous
Date Sampled:06/29/2022 0840 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 07/06/20221257 BBW
47152
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
ND
20
5.0
ug/L
1
Acrylonitrile
107-13-1
8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2
8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2
8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
ND
1.0
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
ND
1.0
0.40
ug/L
1
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
1
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
1
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
1
Toluene
108-88-3
8260D
ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 57 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-011
Description: 2022014435 Matrix: Aqueous
Date Sampled:06/29/2022 0840 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D 1 07/06/20221257 BBW
47152
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units Run
Vinyl acetate
108-05-4 8260D
ND
5.0
1.2
ug/L 1
Vinyl chloride
75-01-4 8260D
ND
1.0
0.40
ug/L 1
Xylenes (total)
1330-20-7 8260D
ND
1.0
0.40
ug/L 1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
90 70-130
1,2-Dichloroethane-d4
99 70-130
Toluene-d8
95 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 58 of 123

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:XF30056-011
Description: 2022014435 Matrix: Aqueous
Date Sampled:06/29/2022 0840 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 07/02/2022 0204 SDC 46898
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
83 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 59 of 123

TPH-DRO
Client: Duke Energy Laboratory ID:XF30056-011
Description: 2022014435 Matrix: Aqueous
Date Sampled:06/29/2022 0840 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 07/11/2022 1935 NCM 07/05/2022 1205 47018
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C 160 BJ 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
114 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 60 of 123

Inorganic non-metals
Client: Duke Energy Laboratory ID:XF30056-012
Description: 2022014436 Matrix: Aqueous
Date Sampled:06/28/2022 1135 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity @) SM 2320B-2011 1 07/13/2022 0031 TAD 47848
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Alkalinity @ pH 4.5 su SM 2320B-2011 62 H 20 20 mg CaCO3/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 61 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-012
Description: 2022014436 Matrix: Aqueous
Date Sampled:06/28/2022 1135 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 07/06/20221320 BBW
47152
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
ND
20
5.0
ug/L
1
Acrylonitrile
107-13-1
8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2
8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2
8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
ND
1.0
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
ND
1.0
0.40
ug/L
1
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
1
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
1
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
1
Toluene
108-88-3
8260D
ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 62 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-012
Description: 2022014436 Matrix: Aqueous
Date Sampled:06/28/2022 1135 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D 1 07/06/20221320 BBW
47152
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units Run
Vinyl acetate
108-05-4 8260D
ND
5.0
1.2
ug/L 1
Vinyl chloride
75-01-4 8260D
ND
1.0
0.40
ug/L 1
Xylenes (total)
1330-20-7 8260D
ND
1.0
0.40
ug/L 1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
90 70-130
1,2-Dichloroethane-d4
99 70-130
Toluene-d8
95 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 63 of 123

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:XF30056-012
Description: 2022014436 Matrix: Aqueous
Date Sampled:06/28/2022 1135 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 07/02/2022 0228 SDC 46898
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
83 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 64 of 123

TPH-DRO
Client: Duke Energy Laboratory ID:XF30056-012
Description: 2022014436 Matrix: Aqueous
Date Sampled:06/28/2022 1135 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 07/11/2022 1944 NCM 07/05/2022 1205 47018
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C 150 BJ 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
106 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 65 of 123

Inorganic non-metals
Client: Duke Energy Laboratory ID:XF30056-013
Description: 2022014437 Matrix: Aqueous
Date Sampled:06/28/2022 1020 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity @) SM 2320B-2011 1 07/13/2022 0044 TAD 47848
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Alkalinity @ pH 4.5 su SM 2320B-2011 62 H 20 20 mg CaCO3/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 66 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-013
Description: 2022014437 Matrix: Aqueous
Date Sampled:06/28/2022 1020 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 07/06/20221345 BBW
47152
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
ND
20
5.0
ug/L
1
Acrylonitrile
107-13-1
8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2
8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2
8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
ND
1.0
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
ND
1.0
0.40
ug/L
1
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
1
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
1
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
1
Toluene
108-88-3
8260D
ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 67 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-013
Description: 2022014437 Matrix: Aqueous
Date Sampled:06/28/2022 1020 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D 1 07/06/20221345 BBW
47152
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units Run
Vinyl acetate
108-05-4 8260D
ND
5.0
1.2
ug/L 1
Vinyl chloride
75-01-4 8260D
ND
1.0
0.40
ug/L 1
Xylenes (total)
1330-20-7 8260D
ND
1.0
0.40
ug/L 1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
93 70-130
1,2-Dichloroethane-d4
100 70-130
Toluene-d8
97 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 68 of 123

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:XF30056-013
Description: 2022014437 Matrix: Aqueous
Date Sampled:06/28/2022 1020 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 07/02/2022 0252 SDC 46898
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
82 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 69 of 123

TPH-DRO
Client: Duke Energy Laboratory ID:XF30056-013
Description: 2022014437 Matrix: Aqueous
Date Sampled:06/28/2022 1020 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 07/11/2022 1953 NCM 07/05/2022 1205 47018
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C 170 BJ 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
110 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 70 of 123

Inorganic non-metals
Client: Duke Energy Laboratory ID:XF30056-014
Description: 2022014438 Matrix: Aqueous
Date Sampled:06/29/2022 1100 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity @) SM 2320B-2011 1 07/13/2022 0051 TAD 47848
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Alkalinity @ pH 4.5 su SM 2320B-2011 350 20 20 mg CaCO3/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 71 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-014
Description: 2022014438 Matrix: Aqueous
Date Sampled:06/29/2022 1100 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 07/06/20221408 BBW
47152
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
ND
20
5.0
ug/L
1
Acrylonitrile
107-13-1
8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2
8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2
8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
ND
1.0
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
ND
1.0
0.40
ug/L
1
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
1
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
1
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
1
Toluene
108-88-3
8260D
ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 72 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-014
Description: 2022014438 Matrix: Aqueous
Date Sampled:06/29/2022 1100 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D 1 07/06/20221408 BBW
47152
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units Run
Vinyl acetate
108-05-4 8260D
ND
5.0
1.2
ug/L 1
Vinyl chloride
75-01-4 8260D
ND
1.0
0.40
ug/L 1
Xylenes (total)
1330-20-7 8260D
ND
1.0
0.40
ug/L 1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
91 70-130
1,2-Dichloroethane-d4
97 70-130
Toluene-d8
95 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 73 of 123

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:XF30056-014
Description: 2022014438 Matrix: Aqueous
Date Sampled:06/29/2022 1100 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 07/02/2022 0317 SDC 46898
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
82 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 74 of 123

TPH-DRO
Client: Duke Energy Laboratory ID:XF30056-014
Description: 2022014438 Matrix: Aqueous
Date Sampled:06/29/2022 1100 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 07/11/2022 2002 NCM 07/05/2022 1205 47018
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C 4700 B 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
104 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 75 of 123

Inorganic non-metals
Client: Duke Energy Laboratory ID:XF30056-015
Description: 2022014439 Matrix: Aqueous
Date Sampled:06/28/2022 1430 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity @) SM 2320B-2011 1 07/13/2022 0056 TAD 47848
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Alkalinity @ pH 4.5 su SM 2320B-2011 ND H 20 20 mg CaCO3/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 76 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-015
Description: 2022014439 Matrix: Aqueous
Date Sampled:06/28/2022 1430 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 07/06/20221431 BBW
47152
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
ND
20
5.0
ug/L
1
Acrylonitrile
107-13-1
8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2
8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2
8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
ND
1.0
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
ND
1.0
0.40
ug/L
1
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
1
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
1
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
1
Toluene
108-88-3
8260D
ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 77 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-015
Description: 2022014439 Matrix: Aqueous
Date Sampled:06/28/2022 1430 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D 1 07/06/20221431 BBW
47152
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units Run
Vinyl acetate
108-05-4 8260D
ND
5.0
1.2
ug/L 1
Vinyl chloride
75-01-4 8260D
ND
1.0
0.40
ug/L 1
Xylenes (total)
1330-20-7 8260D
ND
1.0
0.40
ug/L 1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
91 70-130
1,2-Dichloroethane-d4
98 70-130
Toluene-d8
95 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 78 of 123

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:XF30056-015
Description: 2022014439 Matrix: Aqueous
Date Sampled:06/28/2022 1430 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 07/02/2022 0341 SDC 46898
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
81 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 79 of 123

TPH-DRO
Client: Duke Energy Laboratory ID:XF30056-015
Description: 2022014439 Matrix: Aqueous
Date Sampled:06/28/2022 1430 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 07/11/2022 2011 NCM 07/05/2022 1205 47018
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C 150 BJ 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
110 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 80 of 123

Inorganic non-metals
Client: Duke Energy Laboratory ID:XF30056-016
Description: 2022014440 Matrix: Aqueous
Date Sampled:06/29/2022 1000 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity @) SM 2320B-2011 1 07/13/2022 0108 TAD 47851
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Alkalinity @ pH 4.5 su SM 2320B-2011 ND 20 20 mg CaCO3/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 81 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-016
Description: 2022014440 Matrix: Aqueous
Date Sampled:06/29/2022 1000 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 07/06/20221455 BBW
47152
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
6.9 J
20
5.0
ug/L
1
Acrylonitrile
107-13-1
8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2
8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2
8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
ND
1.0
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
ND
1.0
0.40
ug/L
1
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
1
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
1
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
1
Toluene
108-88-3
8260D
ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 82 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-016
Description: 2022014440 Matrix: Aqueous
Date Sampled:06/29/2022 1000 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D 1 07/06/20221455 BBW
47152
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units Run
Vinyl acetate
108-05-4 8260D
ND
5.0
1.2
ug/L 1
Vinyl chloride
75-01-4 8260D
ND
1.0
0.40
ug/L 1
Xylenes (total)
1330-20-7 8260D
ND
1.0
0.40
ug/L 1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
91 70-130
1,2-Dichloroethane-d4
99 70-130
Toluene-d8
96 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 83 of 123

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:XF30056-016
Description: 2022014440 Matrix: Aqueous
Date Sampled:06/29/2022 1000 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 07/02/2022 0405 SDC 46898
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
83 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 84 of 123

TPH-DRO
Client: Duke Energy Laboratory ID:XF30056-016
Description: 2022014440 Matrix: Aqueous
Date Sampled:06/29/2022 1000 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 07/11/2022 2020 NCM 07/05/2022 1205 47018
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C 130 BJ 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
112 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 85 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-017
Description: 2022014441 Matrix: Aqueous
Date Sampled:06/28/2022 0800 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 07/08/20221721 JWO
47437
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
ND
20
5.0
ug/L
1
Acrylonitrile
107-13-1
8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2
8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2
8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
ND
1.0
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
ND
1.0
0.40
ug/L
1
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
1
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
1
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
1
Toluene
108-88-3
8260D
ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 86 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-017
Description: 2022014441 Matrix: Aqueous
Date Sampled:06/28/2022 0800 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D 1 07/08/20221721 JWO
47437
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units Run
Vinyl acetate
108-05-4 8260D
ND
5.0
1.2
ug/L 1
Vinyl chloride
75-01-4 8260D
ND
1.0
0.40
ug/L 1
Xylenes (total)
1330-20-7 8260D
ND
1.0
0.40
ug/L 1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
109 70-130
1,2-Dichloroethane-d4
102 70-130
Toluene-d8
103 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 87 of 123

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:XF30056-017
Description: 2022014441 Matrix: Aqueous
Date Sampled:06/28/2022 0800 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 07/11/2022 1132 JM1 47557
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
84 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 88 of 123

Inorganic non-metals
Client: Duke Energy Laboratory ID:XF30056-018
Description: 2022014442 Matrix: Aqueous
Date Sampled:06/28/2022 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity @) SM 2320B-2011 1 07/13/2022 0115 TAD 47851
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Alkalinity @ pH 4.5 su SM 2320B-2011 52 H 20 20 mg CaCO3/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 89 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-018
Description: 2022014442 Matrix: Aqueous
Date Sampled:06/28/2022 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 07/06/20221518 BBW
47152
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
ND
20
5.0
ug/L
1
Acrylonitrile
107-13-1
8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2
8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2
8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
ND
1.0
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
ND
1.0
0.40
ug/L
1
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
1
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
1
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
1
Toluene
108-88-3
8260D
ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 90 of 123

Volatile Organic Compounds by GC/MS
Client: Duke Energy Laboratory ID:XF30056-018
Description: 2022014442 Matrix: Aqueous
Date Sampled:06/28/2022 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D 1 07/06/20221518 BBW
47152
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units Run
Vinyl acetate
108-05-4 8260D
ND
5.0
1.2
ug/L 1
Vinyl chloride
75-01-4 8260D
ND
1.0
0.40
ug/L 1
Xylenes (total)
1330-20-7 8260D
ND
1.0
0.40
ug/L 1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
90 70-130
1,2-Dichloroethane-d4
98 70-130
Toluene-d8
95 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 91 of 123

Volatile Organic Compounds by GC/MS (SIM)
Client: Duke Energy Laboratory ID:XF30056-018
Description: 2022014442 Matrix: Aqueous
Date Sampled:06/28/2022 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 07/02/2022 0429 SDC 46898
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
80 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 92 of 123

TPH-DRO
Client: Duke Energy Laboratory ID:XF30056-018
Description: 2022014442 Matrix: Aqueous
Date Sampled:06/28/2022 Project Name: MINIS LANDFILL #2 PERMIT 60-
Date Received:06/30/2022 Project Number: J22060046
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8015C 1 07/11/2022 2029 NCM 07/05/2022 1205 47018
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
TPH-DRO 8015C 130 BJ 200 130 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
o - Terphenyl
114 53-118
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 93 of 123

QC Summary
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: XF30056
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 94 of 123

Inorganic non-metals - LCS
Sample ID: XQ47848-002 Matrix: Aqueous
Batch:47848
Analytical Method: SM 2320B-2011
Spike
Amount Result %Rec
Parameter (mg CaCO3/L) (mg CaCO3/L) Q Dil % Rec Limit Analysis Date
Alkalinity @ pH 4.5 su 100 100 1 105 90-110 07/12/2022 2244
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 95 of 123
QC Data for Lot Number: XF30056

Inorganic non-metals - Duplicate
Sample ID: XF30056-005DU Matrix: Aqueous
Batch:47848
Analytical Method: SM 2320B-2011
Sample
Amount Result %RPD
Parameter (mg CaCO3/L) (mg CaCO3/L) Q Dil % RPD Limit Analysis Date
Alkalinity @ pH 4.5 su 22 22 1 1.0 20 07/12/2022 2350
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 96 of 123
QC Data for Lot Number: XF30056

Inorganic non-metals - LCS
Sample ID: XQ47851-002 Matrix: Aqueous
Batch: 47851
Analytical Method: SM 2320B-2011
Spike
Amount Result %Rec
Parameter (mg CaCO3/L) (mg CaCO3/L) Q Dil % Rec Limit Analysis Date
Alkalinity @ pH 4.5 su 100 100 1 104 90-110 07/13/2022 0104
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 97 of 123
QC Data for Lot Number: XF30056

Volatile Organic Compounds by GC/MS (SIM) - MB
Sample ID: XQ46898-001 Matrix: Aqueous
Batch:46898 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Parameter Result Q Dil LOQ DL Units Analysis Date
1,4-Dioxane ND 1 3.0 1.0 ug/L 07/01/2022 2102
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
82 40-170
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 98 of 123
QC Data for Lot Number: XF30056

Volatile Organic Compounds by GC/MS (SIM) - LCS
Sample ID: XQ46898-002 Matrix: Aqueous
Batch:46898 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
1,4-Dioxane 50 47 1 95 70-130 07101120221932
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
100 40-170
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 99 of 123
QC Data for Lot Number: XF30056

Volatile Organic Compounds by GC/MS (SIM) - LCSD
Sample ID: XQ46898-003 Matrix: Aqueous
Batch:46898 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Spike
Amount Result %Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
1,4-Dioxane 50 50 1 101 5.9 70-130 20 07/01/2022 2014
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
110 40-170
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 100 of 123
QC Data for Lot Number: XF30056

Volatile Organic Compounds by GC/MS - MB
Sample ID: XQ47142-001 Matrix: Aqueous
Batch:47142 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
ND
1
20
5.0
ug/L
07/06/2022 1001
Acrylonitrile
ND
1
20
0.80
ug/L
07/06/2022 1001
Benzene
ND
1
1.0
0.40
ug/L
07/06/2022 1001
Bromochloromethane
ND
1
1.0
0.40
ug/L
07/06/2022 1001
Bromodichloromethane
ND
1
1.0
0.40
ug/L
07/06/2022 1001
Bromoform
ND
1
1.0
0.40
ug/L
07/06/2022 1001
Bromomethane (Methyl bromide)
ND
1
2.0
0.40
ug/L
07/06/2022 1001
2-Butanone (MEK)
ND
1
10
2.0
ug/L
07/06/2022 1001
Carbon disulfide
ND
1
1.0
0.40
ug/L
07/06/2022 1001
Carbon tetrachloride
ND
1
1.0
0.40
ug/L
07/06/2022 1001
Chlorobenzene
ND
1
1.0
0.40
ug/L
07/06/2022 1001
Chloroethane
ND
1
2.0
0.40
ug/L
07/06/2022 1001
Chloroform
ND
1
1.0
0.40
ug/L
07/06/2022 1001
Chloromethane (Methyl chloride)
ND
1
1.0
0.50
ug/L
07/06/2022 1001
1,2-Dibromo-3-chloropropane (DBCP)
ND
1
1.0
0.40
ug/L
07/06/2022 1001
Dibromochloromethane
ND
1
1.0
0.40
ug/L
07/06/2022 1001
1,2-Dibromoethane (EDB)
ND
1
1.0
0.40
ug/L
07/06/2022 1001
Dibromomethane (Methylene bromide)
ND
1
1.0
0.40
ug/L
07/06/2022 1001
trans- 1,4-Dichloro-2-butene
ND
1
2.0
0.50
ug/L
07/06/2022 1001
1,2-Dichlorobenzene
ND
1
1.0
0.40
ug/L
07/06/2022 1001
1,4-Dichlorobenzene
ND
1
1.0
0.40
ug/L
07/06/2022 1001
1,1-Dichloroethane
ND
1
1.0
0.40
ug/L
07/06/2022 1001
1,2-Dichloroethane
ND
1
1.0
0.40
ug/L
07/06/2022 1001
1,1-Dichloroethene
ND
1
1.0
0.40
ug/L
07/06/2022 1001
cis- 1,2-Dichloroethene
ND
1
1.0
0.40
ug/L
07/06/2022 1001
trans- 1,2-Dichloroethene
ND
1
1.0
0.40
ug/L
07/06/2022 1001
1,2-Dichloropropane
ND
1
1.0
0.40
ug/L
07/06/2022 1001
cis- 1,3-Dichloropropene
ND
1
1.0
0.40
ug/L
07/06/2022 1001
trans- 1,3-Dichloropropene
ND
1
1.0
0.40
ug/L
07/06/2022 1001
Ethylbenzene
ND
1
1.0
0.40
ug/L
07/06/2022 1001
2-Hexanone
ND
1
10
2.0
ug/L
07/06/2022 1001
Methyl iodide (lodomethane)
ND
1
5.0
0.40
ug/L
07/06/2022 1001
4-Methyl-2-pentanone
ND
1
10
2.0
ug/L
07/06/2022 1001
Methylene chloride
ND
1
1.0
0.40
ug/L
07/06/2022 1001
Styrene
ND
1
1.0
0.41
ug/L
07/06/2022 1001
1,1,1,2-Tetrachloroethane
ND
1
1.0
0.40
ug/L
07/06/2022 1001
1,1,2,2-Tetrachloroethane
ND
1
1.0
0.40
ug/L
07/06/2022 1001
Tetrachloroethene
ND
1
1.0
0.40
ug/L
07/06/2022 1001
Toluene
ND
1
1.0
0.40
ug/L
07/06/2022 1001
1,1,1-Trichloroethane
ND
1
1.0
0.40
ug/L
07/06/2022 1001
1,1,2-Trichloroethane
ND
1
1.0
0.40
ug/L
07/06/2022 1001
Trichloroethene
ND
1
1.0
0.40
ug/L
07/06/2022 1001
Trichlorofluoromethane
ND
1
1.0
0.40
ug/L
07/06/2022 1001
1,2,3-Trichloropropane
ND
1
1.0
0.40
ug/L
07/06/2022 1001
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 101 of 123
QC Data for Lot Number: XF30056

Volatile Organic Compounds by GC/MS - MB
Sample ID: XQ47142-001 Matrix: Aqueous
Batch:47142 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q Dil
LOQ
DL
Units
Analysis Date
Vinyl acetate
ND
1
5.0
1.2
ug/L
07/06/2022 1001
Vinyl chloride
ND
1
1.0
0.40
ug/L
07/06/2022 1001
Xylenes (total)
ND
1
1.0
0.40
ug/L
07/06/2022 1001
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 100 70-130
1,2-Dichloroethane-d4 87 70-130
Toluene-d8 96 70-130
LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: XF30056
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 102 of 123

Volatile Organic Compounds by GC/MS - LCS
Sample ID: XQ47142-002
Matrix: Aqueous
Batch:47142
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
100
98
1
98
60-140
07/06/2022 0847
Acrylonitrile
100
98
1
98
70-130
07/06/2022 0847
Benzene
50
50
1
99
70-130
07/06/2022 0847
Bromochloromethane
50
46
1
91
70-130
07/06/2022 0847
Bromodichloromethane
50
43
1
87
70-130
07/06/2022 0847
Bromoform
50
39
1
79
70-130
07/06/2022 0847
Bromomethane (Methyl bromide)
50
66
N 1
131
70-130
07/06/2022 0847
2-Butanone (MEK)
100
110
1
114
70-130
07/06/2022 0847
Carbon disulfide
50
45
1
90
70-130
07/06/2022 0847
Carbon tetrachloride
50
41
1
82
70-130
07/06/2022 0847
Chlorobenzene
50
48
1
96
70-130
07/06/2022 0847
Chloroethane
50
56
1
112
70-130
07/06/2022 0847
Chloroform
50
43
1
86
70-130
07/06/2022 0847
Chloromethane (Methyl chloride)
50
51
1
101
60-140
07/06/2022 0847
1,2-Dibromo-3-chloropropane (DBCP)
50
38
1
76
70-130
07/06/2022 0847
Dibromochloromethane
50
41
1
83
70-130
07/06/2022 0847
1,2-Dibromoethane (EDB)
50
45
1
91
70-130
07/06/2022 0847
Dibromomethane (Methylene bromide)
50
49
1
98
70-130
07/06/2022 0847
trans- 1,4-Dichloro-2-butene
50
33
N 1
66
70-130
07/06/2022 0847
1,2-Dichlorobenzene
50
51
1
102
70-130
07/06/2022 0847
1,4-Dichlorobenzene
50
47
1
93
70-130
07/06/2022 0847
1,1-Dichloroethane
50
45
1
90
70-130
07/06/2022 0847
1,2-Dichloroethane
50
41
1
81
70-130
07/06/2022 0847
1,1-Dichloroethene
50
48
1
97
70-130
07/06/2022 0847
cis- 1,2-Dichloroethene
50
46
1
92
70-130
07/06/2022 0847
trans- 1,2-Dichloroethene
50
48
1
96
70-130
07/06/2022 0847
1,2-Dichloropropane
50
49
1
97
70-130
07/06/2022 0847
cis- 1,3-Dichloropropene
50
45
1
90
70-130
07/06/2022 0847
trans- 1,3-Dichloropropene
50
42
1
85
70-130
07/06/2022 0847
Ethylbenzene
50
48
1
95
70-130
07/06/2022 0847
2-Hexanone
100
82
1
82
70-130
07/06/2022 0847
Methyl iodide (lodomethane)
50
47
1
93
70-130
07/06/2022 0847
4-Methyl-2-pentanone
100
90
1
90
70-130
07/06/2022 0847
Methylene chloride
50
46
1
93
70-130
07/06/2022 0847
Styrene
50
48
1
96
70-130
07/06/2022 0847
1,1,1,2-Tetrachloroethane
50
46
1
91
70-130
07/06/2022 0847
1,1,2,2-Tetrachloroethane
50
45
1
91
70-130
07/06/2022 0847
Tetrachloroethene
50
51
1
102
70-130
07/06/2022 0847
Toluene
50
48
1
95
70-130
07/06/2022 0847
1,1,1-Trichloroethane
50
41
1
81
70-130
07/06/2022 0847
1,1,2-Trichloroethane
50
48
1
96
70-130
07/06/2022 0847
Trichloroethene
50
48
1
96
70-130
07/06/2022 0847
Trichlorofluoromethane
50
50
1
99
70-130
07/06/2022 0847
1,2,3-Trichloropropane
50
44
1
88
70-130
07/06/2022 0847
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 103 of 123
QC Data for Lot Number: XF30056

Volatile Organic Compounds by GC/MS - LCS
Sample ID: XQ47142-002
Matrix: Aqueous
Batch:47142
Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec
Limit
Analysis Date
Vinyl acetate
50
50
1 100
60-140
07/06/2022 0847
Vinyl chloride
50
69 N
1 138
70-130
07/06/2022 0847
Xylenes (total)
100
96
1 96
70-130
07/06/2022 0847
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 97 70-130
1,2-Dichloroethane-d4 78 70-130
Toluene-d8 89 70-130
LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: XF30056
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 104 of 123

Volatile Organic Compounds by GC/MS - MB
Sample ID: XQ47150-001 Matrix: Aqueous
Batch:47150 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
ND
1
20
5.0
ug/L
07/06/2022 1020
Acrylonitrile
ND
1
20
0.80
ug/L
07/06/2022 1020
Benzene
ND
1
1.0
0.40
ug/L
07/06/2022 1020
Bromochloromethane
ND
1
1.0
0.40
ug/L
07/06/2022 1020
Bromodichloromethane
ND
1
1.0
0.40
ug/L
07/06/2022 1020
Bromoform
ND
1
1.0
0.40
ug/L
07/06/2022 1020
Bromomethane (Methyl bromide)
ND
1
2.0
0.40
ug/L
07/06/2022 1020
2-Butanone (MEK)
ND
1
10
2.0
ug/L
07/06/2022 1020
Carbon disulfide
ND
1
1.0
0.40
ug/L
07/06/2022 1020
Carbon tetrachloride
ND
1
1.0
0.40
ug/L
07/06/2022 1020
Chlorobenzene
ND
1
1.0
0.40
ug/L
07/06/2022 1020
Chloroethane
ND
1
2.0
0.40
ug/L
07/06/2022 1020
Chloroform
ND
1
1.0
0.40
ug/L
07/06/2022 1020
Chloromethane (Methyl chloride)
ND
1
1.0
0.50
ug/L
07/06/2022 1020
1,2-Dibromo-3-chloropropane (DBCP)
ND
1
1.0
0.40
ug/L
07/06/2022 1020
Dibromochloromethane
ND
1
1.0
0.40
ug/L
07/06/2022 1020
1,2-Dibromoethane (EDB)
ND
1
1.0
0.40
ug/L
07/06/2022 1020
Dibromomethane (Methylene bromide)
ND
1
1.0
0.40
ug/L
07/06/2022 1020
trans- 1,4-Dichloro-2-butene
ND
1
2.0
0.50
ug/L
07/06/2022 1020
1,2-Dichlorobenzene
ND
1
1.0
0.40
ug/L
07/06/2022 1020
1,4-Dichlorobenzene
ND
1
1.0
0.40
ug/L
07/06/2022 1020
1,1-Dichloroethane
ND
1
1.0
0.40
ug/L
07/06/2022 1020
1,2-Dichloroethane
ND
1
1.0
0.40
ug/L
07/06/2022 1020
1,1-Dichloroethene
ND
1
1.0
0.40
ug/L
07/06/2022 1020
cis- 1,2-Dichloroethene
ND
1
1.0
0.40
ug/L
07/06/2022 1020
trans- 1,2-Dichloroethene
ND
1
1.0
0.40
ug/L
07/06/2022 1020
1,2-Dichloropropane
ND
1
1.0
0.40
ug/L
07/06/2022 1020
cis- 1,3-Dichloropropene
ND
1
1.0
0.40
ug/L
07/06/2022 1020
trans- 1,3-Dichloropropene
ND
1
1.0
0.40
ug/L
07/06/2022 1020
Ethylbenzene
ND
1
1.0
0.40
ug/L
07/06/2022 1020
2-Hexanone
ND
1
10
2.0
ug/L
07/06/2022 1020
Methyl iodide (lodomethane)
ND
1
5.0
0.40
ug/L
07/06/2022 1020
4-Methyl-2-pentanone
ND
1
10
2.0
ug/L
07/06/2022 1020
Methylene chloride
ND
1
1.0
0.40
ug/L
07/06/2022 1020
Styrene
ND
1
1.0
0.41
ug/L
07/06/2022 1020
1,1,1,2-Tetrachloroethane
ND
1
1.0
0.40
ug/L
07/06/2022 1020
1,1,2,2-Tetrachloroethane
ND
1
1.0
0.40
ug/L
07/06/2022 1020
Tetrachloroethene
ND
1
1.0
0.40
ug/L
07/06/2022 1020
Toluene
ND
1
1.0
0.40
ug/L
07/06/2022 1020
1,1,1-Trichloroethane
ND
1
1.0
0.40
ug/L
07/06/2022 1020
1,1,2-Trichloroethane
ND
1
1.0
0.40
ug/L
07/06/2022 1020
Trichloroethene
ND
1
1.0
0.40
ug/L
07/06/2022 1020
Trichlorofluoromethane
ND
1
1.0
0.40
ug/L
07/06/2022 1020
1,2,3-Trichloropropane
ND
1
1.0
0.40
ug/L
07/06/2022 1020
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 105 of 123
QC Data for Lot Number: XF30056

Volatile Organic Compounds by GC/MS - MB
Sample ID: XQ47150-001 Matrix: Aqueous
Batch:47150 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q Dil
LOQ
DL
Units
Analysis Date
Vinyl acetate
ND
1
5.0
1.2
ug/L
07/06/2022 1020
Vinyl chloride
ND
1
1.0
0.40
ug/L
07/06/2022 1020
Xylenes (total)
ND
1
1.0
0.40
ug/L
07/06/2022 1020
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 91 70-130
1,2-Dichloroethane-d4 100 70-130
Toluene-d8 95 70-130
LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: XF30056
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 106 of 123

Volatile Organic Compounds by GC/MS - LCS
Sample ID: XQ47150-002
Matrix: Aqueous
Batch:47150
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
100
120
1
124
60-140
07/06/2022 0916
Acrylonitrile
100
130
1
129
70-130
07/06/2022 0916
Benzene
50
51
1
101
70-130
07/06/2022 0916
Bromochloromethane
50
54
1
108
70-130
07/06/2022 0916
Bromodichloromethane
50
50
1
100
70-130
07/06/2022 0916
Bromoform
50
46
1
93
70-130
07/06/2022 0916
Bromomethane (Methyl bromide)
50
62
1
125
70-130
07/06/2022 0916
2-Butanone (MEK)
100
110
1
110
70-130
07/06/2022 0916
Carbon disulfide
50
55
1
110
70-130
07/06/2022 0916
Carbon tetrachloride
50
50
1
101
70-130
07/06/2022 0916
Chlorobenzene
50
47
1
94
70-130
07/06/2022 0916
Chloroethane
50
58
1
116
70-130
07/06/2022 0916
Chloroform
50
53
1
107
70-130
07/06/2022 0916
Chloromethane (Methyl chloride)
50
61
1
121
60-140
07/06/2022 0916
1,2-Dibromo-3-chloropropane (DBCP)
50
53
1
106
70-130
07/06/2022 0916
Dibromochloromethane
50
48
1
96
70-130
07/06/2022 0916
1,2-Dibromoethane (EDB)
50
49
1
97
70-130
07/06/2022 0916
Dibromomethane (Methylene bromide)
50
50
1
100
70-130
07/06/2022 0916
trans- 1,4-Dichloro-2-butene
50
57
1
114
70-130
07/06/2022 0916
1,2-Dichlorobenzene
50
49
1
99
70-130
07/06/2022 0916
1,4-Dichlorobenzene
50
46
1
92
70-130
07/06/2022 0916
1,1-Dichloroethane
50
56
1
113
70-130
07/06/2022 0916
1,2-Dichloroethane
50
53
1
105
70-130
07/06/2022 0916
1,1-Dichloroethene
50
54
1
108
70-130
07/06/2022 0916
cis- 1,2-Dichloroethene
50
52
1
105
70-130
07/06/2022 0916
trans- 1,2-Dichloroethene
50
53
1
105
70-130
07/06/2022 0916
1,2-Dichloropropane
50
52
1
103
70-130
07/06/2022 0916
cis- 1,3-Dichloropropene
50
53
1
106
70-130
07/06/2022 0916
trans- 1,3-Dichloropropene
50
53
1
107
70-130
07/06/2022 0916
Ethylbenzene
50
48
1
96
70-130
07/06/2022 0916
2-Hexanone
100
100
1
104
70-130
07/06/2022 0916
Methyl iodide (lodomethane)
50
51
1
101
70-130
07/06/2022 0916
4-Methyl-2-pentanone
100
110
1
111
70-130
07/06/2022 0916
Methylene chloride
50
56
1
112
70-130
07/06/2022 0916
Styrene
50
51
1
101
70-130
07/06/2022 0916
1,1,1,2-Tetrachloroethane
50
48
1
97
70-130
07/06/2022 0916
1,1,2,2-Tetrachloroethane
50
54
1
108
70-130
07/06/2022 0916
Tetrachloroethene
50
45
1
91
70-130
07/06/2022 0916
Toluene
50
50
1
101
70-130
07/06/2022 0916
1,1,1-Trichloroethane
50
50
1
101
70-130
07/06/2022 0916
1,1,2-Trichloroethane
50
49
1
99
70-130
07/06/2022 0916
Trichloroethene
50
44
1
88
70-130
07/06/2022 0916
Trichlorofluoromethane
50
53
1
106
70-130
07/06/2022 0916
1,2,3-Trichloropropane
50
50
1
101
70-130
07/06/2022 0916
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 107 of 123
QC Data for Lot Number: XF30056

Volatile Organic Compounds by GC/MS - LCS
Sample ID: XQ47150-002
Matrix: Aqueous
Batch:47150
Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec
Limit
Analysis Date
Vinyl acetate
50
57
1 115
60-140
07/06/2022 0916
Vinyl chloride
50
62
1 125
70-130
07/06/2022 0916
Xylenes (total)
100
98
1 98
70-130
07/06/2022 0916
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 97 70-130
1,2-Dichloroethane-d4 103 70-130
Toluene-d8 97 70-130
LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: XF30056
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 108 of 123

Volatile Organic Compounds by GC/MS - MB
Sample ID: XQ47152-001 Matrix: Aqueous
Batch:47152 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
ND
1
20
5.0
ug/L
07/06/2022 1050
Acrylonitrile
ND
1
20
0.80
ug/L
07/06/2022 1050
Benzene
ND
1
1.0
0.40
ug/L
07/06/2022 1050
Bromochloromethane
ND
1
1.0
0.40
ug/L
07/06/2022 1050
Bromodichloromethane
ND
1
1.0
0.40
ug/L
07/06/2022 1050
Bromoform
ND
1
1.0
0.40
ug/L
07/06/2022 1050
Bromomethane (Methyl bromide)
ND
1
2.0
0.40
ug/L
07/06/2022 1050
2-Butanone (MEK)
ND
1
10
2.0
ug/L
07/06/2022 1050
Carbon disulfide
ND
1
1.0
0.40
ug/L
07/06/2022 1050
Carbon tetrachloride
ND
1
1.0
0.40
ug/L
07/06/2022 1050
Chlorobenzene
ND
1
1.0
0.40
ug/L
07/06/2022 1050
Chloroethane
ND
1
2.0
0.40
ug/L
07/06/2022 1050
Chloroform
ND
1
1.0
0.40
ug/L
07/06/2022 1050
Chloromethane (Methyl chloride)
ND
1
1.0
0.50
ug/L
07/06/2022 1050
1,2-Dibromo-3-chloropropane (DBCP)
ND
1
1.0
0.40
ug/L
07/06/2022 1050
Dibromochloromethane
ND
1
1.0
0.40
ug/L
07/06/2022 1050
1,2-Dibromoethane (EDB)
ND
1
1.0
0.40
ug/L
07/06/2022 1050
Dibromomethane (Methylene bromide)
ND
1
1.0
0.40
ug/L
07/06/2022 1050
trans- 1,4-Dichloro-2-butene
ND
1
2.0
0.50
ug/L
07/06/2022 1050
1,2-Dichlorobenzene
ND
1
1.0
0.40
ug/L
07/06/2022 1050
1,4-Dichlorobenzene
ND
1
1.0
0.40
ug/L
07/06/2022 1050
1,1-Dichloroethane
ND
1
1.0
0.40
ug/L
07/06/2022 1050
1,2-Dichloroethane
ND
1
1.0
0.40
ug/L
07/06/2022 1050
1,1-Dichloroethene
ND
1
1.0
0.40
ug/L
07/06/2022 1050
cis- 1,2-Dichloroethene
ND
1
1.0
0.40
ug/L
07/06/2022 1050
trans- 1,2-Dichloroethene
ND
1
1.0
0.40
ug/L
07/06/2022 1050
1,2-Dichloropropane
ND
1
1.0
0.40
ug/L
07/06/2022 1050
cis- 1,3-Dichloropropene
ND
1
1.0
0.40
ug/L
07/06/2022 1050
trans- 1,3-Dichloropropene
ND
1
1.0
0.40
ug/L
07/06/2022 1050
Ethylbenzene
ND
1
1.0
0.40
ug/L
07/06/2022 1050
2-Hexanone
ND
1
10
2.0
ug/L
07/06/2022 1050
Methyl iodide (lodomethane)
ND
1
5.0
0.40
ug/L
07/06/2022 1050
4-Methyl-2-pentanone
ND
1
10
2.0
ug/L
07/06/2022 1050
Methylene chloride
ND
1
1.0
0.40
ug/L
07/06/2022 1050
Styrene
ND
1
1.0
0.41
ug/L
07/06/2022 1050
1,1,1,2-Tetrachloroethane
ND
1
1.0
0.40
ug/L
07/06/2022 1050
1,1,2,2-Tetrachloroethane
ND
1
1.0
0.40
ug/L
07/06/2022 1050
Tetrachloroethene
ND
1
1.0
0.40
ug/L
07/06/2022 1050
Toluene
ND
1
1.0
0.40
ug/L
07/06/2022 1050
1,1,1-Trichloroethane
ND
1
1.0
0.40
ug/L
07/06/2022 1050
1,1,2-Trichloroethane
ND
1
1.0
0.40
ug/L
07/06/2022 1050
Trichloroethene
ND
1
1.0
0.40
ug/L
07/06/2022 1050
Trichlorofluoromethane
ND
1
1.0
0.40
ug/L
07/06/2022 1050
1,2,3-Trichloropropane
ND
1
1.0
0.40
ug/L
07/06/2022 1050
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 109 of 123
QC Data for Lot Number: XF30056

Volatile Organic Compounds by GC/MS - MB
Sample ID: XQ47152-001 Matrix: Aqueous
Batch:47152 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q Dil
LOQ
DL
Units
Analysis Date
Vinyl acetate
ND
1
5.0
1.2
ug/L
07/06/2022 1050
Vinyl chloride
ND
1
1.0
0.40
ug/L
07/06/2022 1050
Xylenes (total)
ND
1
1.0
0.40
ug/L
07/06/2022 1050
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 93 70-130
1,2-Dichloroethane-d4 98 70-130
Toluene-d8 95 70-130
LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: XF30056
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 110 of 123

Volatile Organic Compounds by GC/MS - LCS
Sample ID: XQ47152-002
Matrix: Aqueous
Batch:47152
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
100
110
1
107
60-140
07/06/2022 0946
Acrylonitrile
100
100
1
101
70-130
07/06/2022 0946
Benzene
50
52
1
103
70-130
07/06/2022 0946
Bromochloromethane
50
55
1
110
70-130
07/06/2022 0946
Bromodichloromethane
50
52
1
103
70-130
07/06/2022 0946
Bromoform
50
50
1
100
70-130
07/06/2022 0946
Bromomethane (Methyl bromide)
50
59
1
119
70-130
07/06/2022 0946
2-Butanone (MEK)
100
120
1
120
70-130
07/06/2022 0946
Carbon disulfide
50
45
1
91
70-130
07/06/2022 0946
Carbon tetrachloride
50
49
1
99
70-130
07/06/2022 0946
Chlorobenzene
50
50
1
99
70-130
07/06/2022 0946
Chloroethane
50
60
1
120
70-130
07/06/2022 0946
Chloroform
50
53
1
106
70-130
07/06/2022 0946
Chloromethane (Methyl chloride)
50
50
1
101
60-140
07/06/2022 0946
1,2-Dibromo-3-chloropropane (DBCP)
50
48
1
95
70-130
07/06/2022 0946
Dibromochloromethane
50
51
1
102
70-130
07/06/2022 0946
1,2-Dibromoethane (EDB)
50
51
1
102
70-130
07/06/2022 0946
Dibromomethane (Methylene bromide)
50
53
1
106
70-130
07/06/2022 0946
trans- 1,4-Dichloro-2-butene
50
45
1
90
70-130
07/06/2022 0946
1,2-Dichlorobenzene
50
50
1
100
70-130
07/06/2022 0946
1,4-Dichlorobenzene
50
49
1
99
70-130
07/06/2022 0946
1,1-Dichloroethane
50
49
1
98
70-130
07/06/2022 0946
1,2-Dichloroethane
50
52
1
104
70-130
07/06/2022 0946
1,1-Dichloroethene
50
47
1
93
70-130
07/06/2022 0946
cis- 1,2-Dichloroethene
50
51
1
102
70-130
07/06/2022 0946
trans- 1,2-Dichloroethene
50
51
1
102
70-130
07/06/2022 0946
1,2-Dichloropropane
50
51
1
101
70-130
07/06/2022 0946
cis- 1,3-Dichloropropene
50
51
1
103
70-130
07/06/2022 0946
trans- 1,3-Dichloropropene
50
51
1
103
70-130
07/06/2022 0946
Ethylbenzene
50
50
1
100
70-130
07/06/2022 0946
2-Hexanone
100
95
1
95
70-130
07/06/2022 0946
Methyl iodide (lodomethane)
50
46
1
91
70-130
07/06/2022 0946
4-Methyl-2-pentanone
100
100
1
100
70-130
07/06/2022 0946
Methylene chloride
50
47
1
94
70-130
07/06/2022 0946
Styrene
50
51
1
102
70-130
07/06/2022 0946
1,1,1,2-Tetrachloroethane
50
51
1
103
70-130
07/06/2022 0946
1,1,2,2-Tetrachloroethane
50
54
1
108
70-130
07/06/2022 0946
Tetrachloroethene
50
48
1
96
70-130
07/06/2022 0946
Toluene
50
51
1
101
70-130
07/06/2022 0946
1,1,1-Trichloroethane
50
51
1
102
70-130
07/06/2022 0946
1,1,2-Trichloroethane
50
51
1
101
70-130
07/06/2022 0946
Trichloroethene
50
49
1
97
70-130
07/06/2022 0946
Trichlorofluoromethane
50
52
1
104
70-130
07/06/2022 0946
1,2,3-Trichloropropane
50
49
1
98
70-130
07/06/2022 0946
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 111 of 123
QC Data for Lot Number: XF30056

Volatile Organic Compounds by GC/MS - LCS
Sample ID: XQ47152-002
Matrix: Aqueous
Batch:47152
Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec
Limit
Analysis Date
Vinyl acetate
50
53
1 106
60-140
07/06/2022 0946
Vinyl chloride
50
61
1 122
70-130
07/06/2022 0946
Xylenes (total)
100
100
1 100
70-130
07/06/2022 0946
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 96 70-130
1,2-Dichloroethane-d4 107 70-130
Toluene-d8 102 70-130
LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: XF30056
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 112 of 123

Volatile Organic Compounds by GC/MS - MB
Sample ID: XQ47437-001 Matrix: Aqueous
Batch:47437 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
ND
1
20
5.0
ug/L
07/08/2022 1150
Acrylonitrile
ND
1
20
0.80
ug/L
07/08/2022 1150
Benzene
ND
1
1.0
0.40
ug/L
07/08/2022 1150
Bromochloromethane
ND
1
1.0
0.40
ug/L
07/08/2022 1150
Bromodichloromethane
ND
1
1.0
0.40
ug/L
07/08/2022 1150
Bromoform
ND
1
1.0
0.40
ug/L
07/08/2022 1150
Bromomethane (Methyl bromide)
ND
1
2.0
0.40
ug/L
07/08/2022 1150
2-Butanone (MEK)
ND
1
10
2.0
ug/L
07/08/2022 1150
Carbon disulfide
ND
1
1.0
0.40
ug/L
07/08/2022 1150
Carbon tetrachloride
ND
1
1.0
0.40
ug/L
07/08/2022 1150
Chlorobenzene
ND
1
1.0
0.40
ug/L
07/08/2022 1150
Chloroethane
ND
1
2.0
0.40
ug/L
07/08/2022 1150
Chloroform
ND
1
1.0
0.40
ug/L
07/08/2022 1150
Chloromethane (Methyl chloride)
ND
1
1.0
0.50
ug/L
07/08/2022 1150
1,2-Dibromo-3-chloropropane (DBCP)
ND
1
1.0
0.40
ug/L
07/08/2022 1150
Dibromochloromethane
ND
1
1.0
0.40
ug/L
07/08/2022 1150
1,2-Dibromoethane (EDB)
ND
1
1.0
0.40
ug/L
07/08/2022 1150
Dibromomethane (Methylene bromide)
ND
1
1.0
0.40
ug/L
07/08/2022 1150
trans- 1,4-Dichloro-2-butene
ND
1
2.0
0.50
ug/L
07/08/2022 1150
1,2-Dichlorobenzene
ND
1
1.0
0.40
ug/L
07/08/2022 1150
1,4-Dichlorobenzene
ND
1
1.0
0.40
ug/L
07/08/2022 1150
1,1-Dichloroethane
ND
1
1.0
0.40
ug/L
07/08/2022 1150
1,2-Dichloroethane
ND
1
1.0
0.40
ug/L
07/08/2022 1150
1,1-Dichloroethene
ND
1
1.0
0.40
ug/L
07/08/2022 1150
cis- 1,2-Dichloroethene
ND
1
1.0
0.40
ug/L
07/08/2022 1150
trans- 1,2-Dichloroethene
ND
1
1.0
0.40
ug/L
07/08/2022 1150
1,2-Dichloropropane
ND
1
1.0
0.40
ug/L
07/08/2022 1150
cis- 1,3-Dichloropropene
ND
1
1.0
0.40
ug/L
07/08/2022 1150
trans- 1,3-Dichloropropene
ND
1
1.0
0.40
ug/L
07/08/2022 1150
Ethylbenzene
ND
1
1.0
0.40
ug/L
07/08/2022 1150
2-Hexanone
ND
1
10
2.0
ug/L
07/08/2022 1150
Methyl iodide (lodomethane)
ND
1
5.0
0.40
ug/L
07/08/2022 1150
4-Methyl-2-pentanone
ND
1
10
2.0
ug/L
07/08/2022 1150
Methylene chloride
ND
1
1.0
0.40
ug/L
07/08/2022 1150
Styrene
ND
1
1.0
0.41
ug/L
07/08/2022 1150
1,1,1,2-Tetrachloroethane
ND
1
1.0
0.40
ug/L
07/08/2022 1150
1,1,2,2-Tetrachloroethane
ND
1
1.0
0.40
ug/L
07/08/2022 1150
Tetrachloroethene
ND
1
1.0
0.40
ug/L
07/08/2022 1150
Toluene
ND
1
1.0
0.40
ug/L
07/08/2022 1150
1,1,1-Trichloroethane
ND
1
1.0
0.40
ug/L
07/08/2022 1150
1,1,2-Trichloroethane
ND
1
1.0
0.40
ug/L
07/08/2022 1150
Trichloroethene
ND
1
1.0
0.40
ug/L
07/08/2022 1150
Trichlorofluoromethane
ND
1
1.0
0.40
ug/L
07/08/2022 1150
1,2,3-Trichloropropane
ND
1
1.0
0.40
ug/L
07/08/2022 1150
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 113 of 123
QC Data for Lot Number: XF30056

Volatile Organic Compounds by GC/MS - MB
Sample ID: XQ47437-001 Matrix: Aqueous
Batch:47437 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q Dil
LOQ
DL
Units
Analysis Date
Vinyl acetate
ND
1
5.0
1.2
ug/L
07/08/2022 1150
Vinyl chloride
ND
1
1.0
0.40
ug/L
07/08/2022 1150
Xylenes (total)
ND
1
1.0
0.40
ug/L
07/08/2022 1150
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 112 70-130
1,2-Dichloroethane-d4 104 70-130
Toluene-d8 105 70-130
LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: XF30056
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 114 of 123

Volatile Organic Compounds by GC/MS - LCS
Sample ID: XQ47437-002
Matrix: Aqueous
Batch:47437
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
100
92
1
92
60-140
07/08/2022 0819
Acrylonitrile
100
100
1
102
70-130
07/08/2022 0819
Benzene
50
47
1
93
70-130
07/08/2022 0819
Bromochloromethane
50
49
1
99
70-130
07/08/2022 0819
Bromodichloromethane
50
49
1
98
70-130
07/08/2022 0819
Bromoform
50
49
1
98
70-130
07/08/2022 0819
Bromomethane (Methyl bromide)
50
49
1
98
70-130
07/08/2022 0819
2-Butanone (MEK)
100
98
1
98
70-130
07/08/2022 0819
Carbon disulfide
50
51
1
102
70-130
07/08/2022 0819
Carbon tetrachloride
50
53
1
106
70-130
07/08/2022 0819
Chlorobenzene
50
45
1
90
70-130
07/08/2022 0819
Chloroethane
50
47
1
95
70-130
07/08/2022 0819
Chloroform
50
47
1
94
70-130
07/08/2022 0819
Chloromethane (Methyl chloride)
50
47
1
94
60-140
07/08/2022 0819
1,2-Dibromo-3-chloropropane (DBCP)
50
56
1
113
70-130
07/08/2022 0819
Dibromochloromethane
50
42
1
84
70-130
07/08/2022 0819
1,2-Dibromoethane (EDB)
50
49
1
98
70-130
07/08/2022 0819
Dibromomethane (Methylene bromide)
50
47
1
95
70-130
07/08/2022 0819
trans- 1,4-Dichloro-2-butene
50
41
1
81
70-130
07/08/2022 0819
1,2-Dichlorobenzene
50
47
1
93
70-130
07/08/2022 0819
1,4-Dichlorobenzene
50
44
1
88
70-130
07/08/2022 0819
1,1-Dichloroethane
50
47
1
95
70-130
07/08/2022 0819
1,2-Dichloroethane
50
48
1
97
70-130
07/08/2022 0819
1,1-Dichloroethene
50
50
1
100
70-130
07/08/2022 0819
cis- 1,2-Dichloroethene
50
48
1
97
70-130
07/08/2022 0819
trans- 1,2-Dichloroethene
50
48
1
96
70-130
07/08/2022 0819
1,2-Dichloropropane
50
46
1
93
70-130
07/08/2022 0819
cis- 1,3-Dichloropropene
50
45
1
91
70-130
07/08/2022 0819
trans- 1,3-Dichloropropene
50
42
1
84
70-130
07/08/2022 0819
Ethylbenzene
50
47
1
95
70-130
07/08/2022 0819
2-Hexanone
100
83
1
83
70-130
07/08/2022 0819
Methyl iodide (lodomethane)
50
52
1
104
70-130
07/08/2022 0819
4-Methyl-2-pentanone
100
95
1
95
70-130
07/08/2022 0819
Methylene chloride
50
47
1
94
70-130
07/08/2022 0819
Styrene
50
50
1
100
70-130
07/08/2022 0819
1,1,1,2-Tetrachloroethane
50
51
1
102
70-130
07/08/2022 0819
1,1,2,2-Tetrachloroethane
50
48
1
95
70-130
07/08/2022 0819
Tetrachloroethene
50
46
1
92
70-130
07/08/2022 0819
Toluene
50
47
1
94
70-130
07/08/2022 0819
1,1,1-Trichloroethane
50
49
1
97
70-130
07/08/2022 0819
1,1,2-Trichloroethane
50
46
1
92
70-130
07/08/2022 0819
Trichloroethene
50
49
1
98
70-130
07/08/2022 0819
Trichlorofluoromethane
50
52
1
103
70-130
07/08/2022 0819
1,2,3-Trichloropropane
50
46
1
91
70-130
07/08/2022 0819
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 115 of 123
QC Data for Lot Number: XF30056

Volatile Organic Compounds by GC/MS - LCS
Sample ID: XQ47437-002
Matrix: Aqueous
Batch:47437
Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec
Limit
Analysis Date
Vinyl acetate
50
50
1 100
60-140
07/08/2022 0819
Vinyl chloride
50
48
1 97
70-130
07/08/2022 0819
Xylenes (total)
100
96
1 96
70-130
07/08/2022 0819
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 93 70-130
1,2-Dichloroethane-d4 90 70-130
Toluene-d8 89 70-130
LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: XF30056
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 116 of 123

Volatile Organic Compounds by GC/MS (SIM) - MB
Sample ID: XQ47557-001 Matrix: Aqueous
Batch:47557 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Parameter Result Q Dil LOQ DL Units Analysis Date
1,4-Dioxane ND 1 3.0 1.0 ug/L 07111120221108
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
84 40-170
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 117 of 123
QC Data for Lot Number: XF30056

Volatile Organic Compounds by GC/MS (SIM) - LCS
Sample ID: XQ47557-002 Matrix: Aqueous
Batch:47557 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
1,4-Dioxane 50 47 1 94 70-130 07/11/2022 0857
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
90 40-170
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 118 of 123
QC Data for Lot Number: XF30056

Volatile Organic Compounds by GC/MS (SIM) - LCSD
Sample ID: XQ47557-003 Matrix: Aqueous
Batch:47557 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Spike
Amount Result %Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
1,4-Dioxane 50 50 1 99 5.8 70-130 20 07/11/2022 0921
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
102 40-170
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 119 of 123
QC Data for Lot Number: XF30056

TPH-DRO - MB
Sample ID: XQ47018-001 Matrix: Aqueous
Batch:47018 Prep Method: 3520C
Analytical Method: 8015C Prep Date: 07/05/2022 1205
Parameter Result Q Dil LOQ DL Units Analysis Date
TPH-DRO 150 J 1 200 130 ug/L 07/11/20221729
Surrogate
o - Terphenyl
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
115 53-118
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 120 of 123
QC Data for Lot Number: XF30056

TPH-DRO - LCS
Sample ID: XQ47018-002
Matrix: Aqueous
Batch:47018
Prep Method: 3520C
Analytical Method: 8015C
Prep Date: 07/05/2022 1205
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec Limit Analysis Date
TPH-DRO
2000
1800
1 92 70-130 07111120221738
Surrogate
Q % Rec
Acceptance
Limit
o - Terphenyl
LOQ = Limit of Quantitation
DL = Detection Limit
113 53-118
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 121 of 123
QC Data for Lot Number: XF30056

TPH-DRO - MS
Sample ID: XF30056-001 MS
Matrix: Aqueous
Batch:47018
Prep Method: 3520C
Analytical Method: 8015C
Prep Date: 07/05/2022 1205
Sample
Spike
Amount
Amount
Result %Rec
Parameter
(ug/L)
(ug/L)
(ug/L) Q Dil % Rec Limit Analysis Date
TPH-DRO
180
4000
3600 1 87 70-130 07111120221756
Surrogate
o - Terphenyl
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
112 53-118
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 122 of 123
QC Data for Lot Number: XF30056

TPH-DRO - MSD
Sample ID: XF30056-001 MD
Matrix: Aqueous
Batch:47018
Prep Method: 3520C
Analytical Method: 8015C
Prep Date: 07/05/2022 1205
Sample
Spike
Amount
Amount
Result %Rec % RPD
Parameter
(ug/L)
(ug/L)
(ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
TPH-DRO
180
4000
3700 1 89 2.4 70-130 20 07111120221805
Surrogate
o - Terphenyl
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
115 53-118
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 123 of 123
QC Data for Lot Number: XF30056

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
Duke Energy Analytical Laboratory i ! Analytical LaboratoryUse Onlyrage I r V I I Ov
Page of
_1 _
_1_ IB
-` Mtll Code MG02A2 (BulMing 7405) I Matrix WATER NC_X—
DUKE .Order# J22060046 s.moi..olon•ooer„m DISTRIBUTION
11538 MaFerry Rd 9C_
Ben
ORIGINAL to LAB, COPY to
ENERGY Hunt«evlllt, N.C. 28075 i !Lagged
By DeteITime
[phone] i i SAMPLE PROGRAM i CLIENT
i._._._._._._._._._._._._._._._._._. ............ m:ata) nssoLR._._.___.___I Ground Water _X_ NPDES
Project Name MNS LANDFILL #2 PERMIT# 60- Phone No: !Vendor: Pow -Columbia 1 Drinking Water_ UST_
l RCRA Waste
t— ......... _ ._.._.. Coo.g.T.lmE.(CD...................................................... . ..............................
Client Ethan Smith / Bryan Moeller / 'Pc pace d
i Filtration (0.45 um) b Unfiltered b Filtere
Courtney Murphy / Ashle Heal
Operating Unit: Process: BLDFLGN Recount: ! PO # 9172712 ! Preservative � _ ICE ICE ICE ICE, HCL
-.. .....................
Project: Activity ID: Facility to: Container Volume (ml-) 40 ml 500 ml 300 ml 300 ml 1000 ml 40 ml 500 ml
Mcoa
Program I EQuiS Task Code: Sub-ProgramlTask Code: Container Type n
�mcoz =eoa O 0 =aH f "-
v c drooU K vi
a c
Customer to complete all appropriate non -shaded areas. < m rc a u y d '4 2 v '4 d LL o ee. u q c o . w rT 8 a^ a o
Sample Description or ID W a a" w as v x ^ 0. c x E m a Z -m >x
maa ew Ax4' J... LL.-. E o as E
u m n a O m a :4 y Y a' O
i SAMPLE ID i u IL Collection Information TE-
a U tl�f c.a J- J- O K O 4 O S Leo O
NUMBER i Date Time Printed Name Si nature >- Z f e m ^.c a m et 0 a 0 m 0 0 m W 0 u +C LL E S u, G
I—�
2022014425 ;
MNS_MW-5R
��L
�S
aud�
(p
X
3
1
1
1
3
(
9
2022014426 !
MNS_MW-5A
(�l{�
onnor C GlkOt'A
X
3
1
1
1
3
)
9
2022014427
MNS_Mw-6
Ir 29 ZL
101
NnnoY Zthafk
X
3
1
1
1
3
9
•. 2022014428 !.
MNS_MW-5A
Lq u
(046
cohnoir ZLkwi,
x
3
1
1
1
3
1
9
2022014429 !
MNS_MW-7R
(0 ZS ZZ
1250
Gthcn mt�,
x
3
1
1
1
3
)
9
2022014430 i
MNS_MW-7A
I0124/Z2
I1 Sb
II"'-14i
(}� m(-K
X
3
1
1
1
3
(
9
2022014431 ;
MNS_MW-8
1p 2S
0 9 �j
Comm, a{td
X
3
1
1
1
3
)
9
2022014432 !
MNS_Mw 8A
(0 2 lZ
0M 5
J nor Zc. ✓�
X
3
1
1
1
3
s
2022014433 !
MNS_MW-9
(p 2Z
330
15+ku^ SIVIRk
X
3
1
1
1
3
1
9
i 2022014434 ;
MNS_MW-9A
l0 2 11
0
X
3
1
1
1
3
1
9
2022014435 !
i�
MNS_MW-1DA
jp Zq
0
pnnb( zakillra
X
3
1
1
1
3
1
9
i 2022014436 i
MNS_SW-1
(y 2 1b
113'sT
4�0yix
X
3
1
1
1
3
1
1
10
i 2022�-014437 i
MNS_SW-2
V2 u"
102V
LG%1,ov Zeno /t
X
3
1
1
1
3
)
1
10
2022014438 ;
MNS_LEACHATE POND
oo
X
3
1
1
1
3
1
9
2022014439 !
MNS_FB-20t201o,ZQ-1Lf jj
-7Z
ml
x
3
1
1
1
3
t
9
• 2022014440
MNS_FB--LD k42G1_ 160D
( Z ZZ
1000Cann(
ZADYA
X
3
1
1
1
3
r
(
9
! 2022014441 !
MNS_TB-2DZZ0(/ZQ-L)%00
L- 2 IL
ayoo
ej�W 5M
X
3
p
}.t•z1,
3
6
2022014442 i
MNS FD - 202261PZI— I
1p
�'
jj
(Oytl/(h zpftr)l:%�
x
3
1
1
3
I
9
--i
TOTAL A CONTAINERS
64
17
15
2
17
54
0
0
0
2
0
161
Ral' ui B
Date/Time
Accepted By
Datelrime
°�
�1 SMi % 2 1 Z //YLAC&
4 Li
ad2si
a
Requested Turnaround
Relinquishe By
Datairime
Acceptedey:
telT"i e
-
N c
21 Days
9
Relinquished
Da m
Accepted By:
Dateirme
c
. E
14 Days
v
�a
SeallL
DateMme
Sealed/Lock Opened By
Daternme
o v
a
'7 Days
E"
Comments
`m
E
"Other
' Add. Cost Will Apply
U
Total E

Page 180 of 180
McGuire Landfill #2
COMPOUNDS REQUIRED FOR 8260 ANALYSES
" MRL must meet or be below the SWSL Std.
NC SWSL Std.
COMPOUND
CASSNo.
squired MRL*
Acetone
67-64-1
100
Acrylonitrile
107-13-1
200
Benzene
71-43-2
1
Bromochloromethane
74-97-5
3
Bromodichloromethane
75-27-4
1
Bromoform; Tribromomethane
75-25-2
3
Carbon disulfide
75-15-0
100
Carbon tetrachloride
56-23-5
1
Chlorobenzene
108-90-7
3
Chloroethane; Ethyl chloride
75-00-3
10
Chloroform; Trichloromethane
67-66-3
5
Dibromochloromethane; Chlorodibromomethane
124-48-1
1
1,2-Dibromo-3-chlorpropane; DBCP
96-12-8
1
1,2-Dibromoethane; Ethylene dibromide; EDB
106-93-4
1
o-Dichlorobenzene; 1,2-Dichlorobenzene
95-50-1
5
p-Dichlorobenzene; 1,4-Dichlorobenzene
106-46-7
1
Vans-1,4-Dichloro-2-butene
110-57-6
100
1,1-Dichloroethane; Ethylidene chloride
75-34-3
5
1,2-Dichloroethane; Ethlyene dichloride
107-06-2
1
1, 1 -Dichloroethylene; 1 -1 -Dichloroethene; Vinylidene chloride
75-35-4
5
cis- 1,2-Dichloroethylene; cis- 1,2-Dichloroethene
156-59-2
5
trans-1,2-Dichloroethylene; trans- 1,2-Dichloroethene
156-60-5
5
1,2-Dichlorpropane; Propylene dichloride
78-87-5
1
cis- 1,3-Dichlorpropene
10061-01-5
1
trans- 1,3-Dichlorpropene
10061-02-6
1
Ethylbenzene
100-41-4
1
2-hexanone; Methyl butyl ketone
591-78-6
50
Methyl bromide; Bromomethane
74-83-9
10
Methyl chloride; Chloromethane
74-87-3
1
Methylene bromide Dibromomethane
74-95-3
10
Methylene chloride; Dichloromethane
75-09-2
1
Methyl ethyl ketone; MEK; 2-Butanone
78-93-3
100
Methyl iodide; lodomethane
74-88-4
10
4-Methyl-2-pentanone; Methyl isobutyl isobutyl ketone
108-10-1
100
Styrene
100-42-5
1
1,1,1,2-Tetrachloroethane
630-20-6
5
1,1,2,2-Tetrachloroethane
79-34-5
1
Tetrachloroethylene; Tetracholorethene; Perch loroethylene
127-18-4
1
Toluene
108-88-3
1
1, 1, 1 -Trochlorethane; Methylchloroform
71-55-6
1
1,1,2-Trichloroethane
79-00-5
5
Trichloroethylene; Trichlorethene
79-01-6
1
Trichlorofluoromethane; CFC-11
75-69-4
1
1,2,3-Trichloropropane
96-18-4
1
Vinyl acetate
108-05-4
50
Vinyl chloride
75-01-4
1
xylenes
1330-20-7
4

E n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 568717
Location: MNS_MW-5R
[ MNS Landfill 2 / MW-5R
(LANDFILL)]
Collection
Start: 6/28/2022
14:05:00
Job: MNSGW202219
Collection
End: 6/28/2022
14:05:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
7.95E-01
6.93E-01
4.57E-01
<3
LLD OK
Beta
4.64E+00
4.36E+00
3.25E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<4.99E+00
0.00E+00
4.99E+00
<15
<1000
LLD OK
Co-58
<5.37E+00
0.00E+00
5.37E+00
<15
<1000
LLD OK
Fe-59
<1.12E+01
0.00E+00
1.12E+01
<30
<400
LLD OK
Co-60
<6.83E+00
0.00E+00
6.83E+00
<15
<300
LLD OK
Zn-65
<1.20E+01
0.00E+00
1.20E+01
<30
<300
LLD OK
Zr-95
<6.98E+00
0.00E+00
6.98E+00
<15
<400
LLD OK
Nb-95
<5.73E+00
0.00E+00
5.73E+00
<15
<400
LLD OK
1-131
<5.81 E+00
0.00E+00
5.81 E+00
<15
LLD OK
Cs-134
<6.27E+00
0.00E+00
6.27E+00
<15
<30
LLD OK
Cs-137
<4.21 E+00
0.00E+00
4.21 E+00
<18
<50
LLD OK
Bala-140
<5.79E+00
0.00E+00
5.79E+00
<15
<200
LLD OK
Be-7
<4.14E+01
0.00E+00
4.14E+01
K-40
1.35E+02
5.96E+01
6.86E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-1.1E+02
0.00E+00
1.90E+02
<250
<20000
LLD OK
Report Generated @ 8/1/2022 11:03:35
job_report_grouped_by_media
EnRad Laboratory
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
Page 1 of 14
EnRad Laboratories Page Page 1 of 15 08/01/2022

E n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 568718
Location: MNS_MW-5A [ MNS Landfill 2 / MW-5A
(LANDFILL)]
Collection
Start: 6/28/2022
12:40:00
Job: MNSGW202219
Collection
End: 6/28/2022
12:40:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.56E-01
0.00E+00
4.56E-01
<3
LLD OK
Beta
<3.25E+00
0.00E+00
3.25E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.30E+00
0.00E+00
6.30E+00
<15
<1000
LLD OK
Co-58
<5.54E+00
0.00E+00
5.54E+00
<15
<1000
LLD OK
Fe-59
<9.95E+00
0.00E+00
9.95E+00
<30
<400
LLD OK
Co-60
<5.94E+00
0.00E+00
5.94E+00
<15
<300
LLD OK
Zn-65
<1.44E+01
0.00E+00
1.44E+01
<30
<300
LLD OK
Zr-95
<1.12E+01
0.00E+00
1.12E+01
<15
<400
LLD OK
Nb-95
<5.18E+00
0.00E+00
5.18E+00
<15
<400
LLD OK
1-131
<5.71 E+00
0.00E+00
5.71 E+00
<15
LLD OK
Cs-134
<6.89E+00
0.00E+00
6.89E+00
<15
<30
LLD OK
Cs-137
<6.16E+00
0.00E+00
6.16E+00
<18
<50
LLD OK
Bala-140
<5.97E+00
0.00E+00
5.97E+00
<15
<200
LLD OK
Be-7
<3.79E+01
0.00E+00
3.79E+01
K-40
2.28E+02
7.10E+01
6.00E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-9.4E+01
0.00E+00
1.90E+02
<250
<20000
LLD OK
Report Generated @ 8/1/2022 11:03:35
job_report_grouped_by_media
EnRad Laboratory
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
Page 2 of 14
EnRad Laboratories Page Page 2 of 15 08/01/2022

E n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 568719
Location: MNS_MW-6 [ MNS Landfill 2 / MW-6 (LANDFILL)]
Collection
Start: 6/29/2022
10:15:00
Job: MNSGW202219
Collection
End: 6/29/2022
10:15:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
5.64E-01
6.59E-01
4.57E-01
<3
LLD OK
Beta
4.84E+00
4.36E+00
3.25E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.14E+00
0.00E+00
5.14E+00
<15
<1000
LLD OK
Co-58
<5.29E+00
0.00E+00
5.29E+00
<15
<1000
LLD OK
Fe-59
<9.81 E+00
0.00E+00
9.81 E+00
<30
<400
LLD OK
Co-60
<7.02E+00
0.00E+00
7.02E+00
<15
<300
LLD OK
Zn-65
<1.17E+01
0.00E+00
1.17E+01
<30
<300
LLD OK
Zr-95
<1.05E+01
0.00E+00
1.05E+01
<15
<400
LLD OK
Nb-95
<6.14E+00
0.00E+00
6.14E+00
<15
<400
LLD OK
1-131
<5.82E+00
0.00E+00
5.82E+00
<15
LLD OK
Cs-134
<7.63E+00
0.00E+00
7.63E+00
<15
<30
LLD OK
Cs-137
<6.16E+00
0.00E+00
6.16E+00
<18
<50
LLD OK
Bala-140
<7.42E+00
0.00E+00
7.42E+00
<15
<200
LLD OK
Be-7
<4.48E+01
0.00E+00
4.48E+01
K-40
1.02E+02
6.60E+01
9.49E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-5.5E+01
0.00E+00
1.91 E+02
<250
<20000
LLD OK
Report Generated @ 8/1/2022 11:03:35
job_report_grouped_by_media
EnRad Laboratory
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
Page 3 of 14
EnRad Laboratories Page Page 3 of 15 08/01/2022

E n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 568720
Location: MNS_MW-6A [ MNS Landfill 2 / MW-6A
(LANDFILL)]
Collection
Start: 6/29/2022
10:40:00
Job: MNSGW202219
Collection
End: 6/29/2022
10:40:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
5.29E-01
6.53E-01
4.57E-01
<3
LLD OK
Beta
3.52E+00
4.33E+00
3.25E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.17E+00
0.00E+00
6.17E+00
<15
<1000
LLD OK
Co-58
<5.55E+00
0.00E+00
5.55E+00
<15
<1000
LLD OK
Fe-59
<7.08E+00
0.00E+00
7.08E+00
<30
<400
LLD OK
Co-60
<7.37E+00
0.00E+00
7.37E+00
<15
<300
LLD OK
Zn-65
<1.35E+01
0.00E+00
1.35E+01
<30
<300
LLD OK
Zr-95
<8.91 E+00
0.00E+00
8.91 E+00
<15
<400
LLD OK
Nb-95
<6.21 E+00
0.00E+00
6.21 E+00
<15
<400
LLD OK
1-131
<6.23E+00
0.00E+00
6.23E+00
<15
LLD OK
Cs-134
<8.55E+00
0.00E+00
8.55E+00
<15
<30
LLD OK
Cs-137
<7.16E+00
0.00E+00
7.16E+00
<18
<50
LLD OK
Bala-140
<6.36E+00
0.00E+00
6.36E+00
<15
<200
LLD OK
Be-7
<3.90E+01
0.00E+00
3.90E+01
K-40
<1.28E+02
0.00E+00
1.28E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-4.7E+01
0.00E+00
1.89E+02
<250
<20000
LLD OK
Report Generated @ 8/1/2022 11:03:35
job_report_grouped_by_media
EnRad Laboratory
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
Page 4 of 14
EnRad Laboratories Page Page 4 of 15 08/01/2022

E n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 568721
Location: MNS_MW-7R
[ MNS Landfill 2 / MW-7R
(LANDFILL)]
Collection
Start: 6/28/2022
12:50:00
Job: MNSGW202219
Collection
End: 6/28/2022
12:50:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.56E-01
0.00E+00
4.56E-01
<3
LLD OK
Beta
<3.25E+00
0.00E+00
3.25E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.86E+00
0.00E+00
6.86E+00
<15
<1000
LLD OK
Co-58
<6.16E+00
0.00E+00
6.16E+00
<15
<1000
LLD OK
Fe-59
<7.17E+00
0.00E+00
7.17E+00
<30
<400
LLD OK
Co-60
<7.96E+00
0.00E+00
7.96E+00
<15
<300
LLD OK
Zn-65
<1.35E+01
0.00E+00
1.35E+01
<30
<300
LLD OK
Zr-95
<1.24E+01
0.00E+00
1.24E+01
<15
<400
LLD OK
Nb-95
<5.98E+00
0.00E+00
5.98E+00
<15
<400
LLD OK
1-131
<5.91 E+00
0.00E+00
5.91 E+00
<15
LLD OK
Cs-134
<7.71 E+00
0.00E+00
7.71 E+00
<15
<30
LLD OK
Cs-137
<6.05E+00
0.00E+00
6.05E+00
<18
<50
LLD OK
Bala-140
<7.27E+00
0.00E+00
7.27E+00
<15
<200
LLD OK
Be-7
<3.70E+01
0.00E+00
3.70E+01
K-40
7.96E+01
6.70E+01
1.03E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-9.4E+01
0.00E+00
1.90E+02
<250
<20000
LLD OK
Report Generated @ 8/1/2022 11:03:35
job_report_grouped_by_media
EnRad Laboratory
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
Page 5 of 14
EnRad Laboratories Page Page 5 of 15 08/01/2022

E n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 568722
Location: MNS_MW-7A [ MNS Landfill 2 / MW-7A
(LANDFILL)]
Collection
Start: 6/28/2022
11:50:00
Job: MNSGW202219
Collection
End: 6/28/2022
11:50:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.56E-01
0.00E+00
4.56E-01
<3
LLD OK
Beta
<3.25E+00
0.00E+00
3.25E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.27E+00
0.00E+00
5.27E+00
<15
<1000
LLD OK
Co-58
<4.59E+00
0.00E+00
4.59E+00
<15
<1000
LLD OK
Fe-59
<1.08E+01
0.00E+00
1.08E+01
<30
<400
LLD OK
Co-60
<4.44E+00
0.00E+00
4.44E+00
<15
<300
LLD OK
Zn-65
<1.02E+01
0.00E+00
1.02E+01
<30
<300
LLD OK
Zr-95
<9.13E+00
0.00E+00
9.13E+00
<15
<400
LLD OK
Nb-95
<5.66E+00
0.00E+00
5.66E+00
<15
<400
LLD OK
1-131
<5.76E+00
0.00E+00
5.76E+00
<15
LLD OK
Cs-134
<8.02E+00
0.00E+00
8.02E+00
<15
<30
LLD OK
Cs-137
<5.80E+00
0.00E+00
5.80E+00
<18
<50
LLD OK
Bala-140
<4.01 E+00
0.00E+00
4.01 E+00
<15
<200
LLD OK
Be-7
<5.01 E+01
0.00E+00
5.01E+01
K-40
1.95E+02
7.14E+01
7.75E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-8.8E+01
0.00E+00
1.91 E+02
<250
<20000
LLD OK
Report Generated @ 8/1/2022 11:03:35
job_report_grouped_by_media
EnRad Laboratory
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
Page 6 of 14
EnRad Laboratories Page Page 6 of 15 08/01/2022

E n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 568723
Location: MNS_MW-8 [ MNS Landfill 2 / MW-8 (LANDFILL)]
Collection
Start: 6/28/2022
09:15:00
Job: MNSGW202219
Collection
End: 6/28/2022
09:15:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.56E-01
0.00E+00
4.56E-01
<3
LLD OK
Beta
<3.25E+00
0.00E+00
3.25E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.23E+00
0.00E+00
5.23E+00
<15
<1000
LLD OK
Co-58
<5.46E+00
0.00E+00
5.46E+00
<15
<1000
LLD OK
Fe-59
<1.32E+01
0.00E+00
1.32E+01
<30
<400
LLD OK
Co-60
<6.64E+00
0.00E+00
6.64E+00
<15
<300
LLD OK
Zn-65
<1.02E+01
0.00E+00
1.02E+01
<30
<300
LLD OK
Zr-95
<9.07E+00
0.00E+00
9.07E+00
<15
<400
LLD OK
Nb-95
<5.08E+00
0.00E+00
5.08E+00
<15
<400
LLD OK
1-131
<6.45E+00
0.00E+00
6.45E+00
<15
LLD OK
Cs-134
<5.30E+00
0.00E+00
5.30E+00
<15
<30
LLD OK
Cs-137
<6.35E+00
0.00E+00
6.35E+00
<18
<50
LLD OK
Bala-140
<7.06E+00
0.00E+00
7.06E+00
<15
<200
LLD OK
Be-7
<4.45E+01
0.00E+00
4.45E+01
K-40
1.13E+02
6.09E+01
7.84E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-5.0E+01
0.00E+00
1.90E+02
<250
<20000
LLD OK
Report Generated @ 8/1/2022 11:03:35
job_report_grouped_by_media
EnRad Laboratory
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
Page 7 of 14
EnRad Laboratories Page Page 7 of 15 08/01/2022

E n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 568724
Location: MNS_MW-8A [ MNS Landfill 2 / MW-8A
(LANDFILL)]
Collection
Start: 6/28/2022 08:45:00
Job: MNSGW202219
Collection
End: 6/28/2022 08:45:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.56E-01
0.00E+00
4.56E-01
<3
LLD OK
Beta
<3.25E+00
0.00E+00
3.25E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.77E+00
0.00E+00
5.77E+00
<15
<1000
LLD OK
Co-58
<7.10E+00
0.00E+00
7.10E+00
<15
<1000
LLD OK
Fe-59
<9.36E+00
0.00E+00
9.36E+00
<30
<400
LLD OK
Co-60
<7.62E+00
0.00E+00
7.62E+00
<15
<300
LLD OK
Zn-65
<1.11 E+01
0.00E+00
1.11E+01
<30
<300
LLD OK
Zr-95
<1.15E+01
0.00E+00
1.15E+01
<15
<400
LLD OK
Nb-95
<6.13E+00
0.00E+00
6.13E+00
<15
<400
LLD OK
1-131
<6.35E+00
0.00E+00
6.35E+00
<15
LLD OK
Cs-134
<6.04E+00
0.00E+00
6.04E+00
<15
<30
LLD OK
Cs-137
<4.60E+00
0.00E+00
4.60E+00
<18
<50
LLD OK
Bala-140
<5.18E+00
0.00E+00
5.18E+00
<15
<200
LLD OK
Be-7
<4.37E+01
0.00E+00
4.37E+01
K-40
1.59E+02
6.48E+01
7.25E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-1.1E+02
0.00E+00
1.89E+02
<250
<20000
LLD OK
Report Generated @ 8/1/2022 11:03:35
job_report_grouped_by_media
EnRad Laboratory
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
Page 8 of 14
EnRad Laboratories Page Page 8 of 15 08/01/2022

E n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 568725
Location: MNS_MW-9 [ MNS Landfill 2 / MW-9 (LANDFILL)]
Collection
Start: 6/28/2022
13:30:00
Job: MNSGW202219
Collection
End: 6/28/2022 13:30:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.57E-01
0.00E+00
4.57E-01
<3
LLD OK
Beta
4.36E+00
4.35E+00
3.25E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.31 E+00
0.00E+00
6.31 E+00
<15
<1000
LLD OK
Co-58
<6.94E+00
0.00E+00
6.94E+00
<15
<1000
LLD OK
Fe-59
<1.20E+01
0.00E+00
1.20E+01
<30
<400
LLD OK
Co-60
<5.92E+00
0.00E+00
5.92E+00
<15
<300
LLD OK
Zn-65
<1.44E+01
0.00E+00
1.44E+01
<30
<300
LLD OK
Zr-95
<1.15E+01
0.00E+00
1.15E+01
<15
<400
LLD OK
Nb-95
<6.74E+00
0.00E+00
6.74E+00
<15
<400
LLD OK
1-131
<7.62E+00
0.00E+00
7.62E+00
<15
LLD OK
Cs-134
<7.29E+00
0.00E+00
7.29E+00
<15
<30
LLD OK
Cs-137
<6.83E+00
0.00E+00
6.83E+00
<18
<50
LLD OK
Bala-140
<7.22E+00
0.00E+00
7.22E+00
<15
<200
LLD OK
Be-7
<4.67E+01
0.00E+00
4.67E+01
K-40
2.21 E+02
8.30E+01
9.96E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<9.44E+00
0.00E+00
1.90E+02
<250
<20000
LLD OK
Report Generated @ 8/1/2022 11:03:35
job_report_grouped_by_media
EnRad Laboratory
MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
Page 9 of 14
EnRad Laboratories Page Page 9 of 15 08/01/2022

E n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 568726
Location: MNS_MW-9A [ MNS Landfill 2 / MW-9A
(LANDFILL)]
Collection
Start: 6/28/2022
14:00:00
Job: MNSGW202219
Collection
End: 6/28/2022
14:00:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<4.56E-01
0.00E+00
4.56E-01
<3
LLD OK
Beta
<3.25E+00
0.00E+00
3.25E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.76E+00
0.00E+00
5.76E+00
<15
<1000
LLD OK
Co-58
<5.91 E+00
0.00E+00
5.91 E+00
<15
<1000
LLD OK
Fe-59
<1.30E+01
0.00E+00
1.30E+01
<30
<400
LLD OK
Co-60
<5.78E+00
0.00E+00
5.78E+00
<15
<300
LLD OK
Zn-65
<1.20E+01
0.00E+00
1.20E+01
<30
<300
LLD OK
Zr-95
<8.63E+00
0.00E+00
8.63E+00
<15
<400
LLD OK
Nb-95
<5.57E+00
0.00E+00
5.57E+00
<15
<400
LLD OK
1-131
<5.95E+00
0.00E+00
5.95E+00
<15
LLD OK
Cs-134
<6.67E+00
0.00E+00
6.67E+00
<15
<30
LLD OK
Cs-137
<4.21 E+00
0.00E+00
4.21 E+00
<18
<50
LLD OK
Bala-140
<5.81 E+00
0.00E+00
5.81 E+00
<15
<200
LLD OK
Be-7
<4.04E+01
0.00E+00
4.04E+01
K-40
7.66E+01
5.40E+01
7.73E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-7.6E+01
0.00E+00
1.90E+02
<250
<20000
LLD OK
Report Generated @ 8/1/2022 11:03:35 EnRad Laboratory Page 10 of 14
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories Page Page 10 of 15 08/01/2022

E n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 568727
Location: MNS_MW-10A
[ MNS Landfill 2 / MW-10A (LANDFILL)]
Collection
Start: 6/29/2022
08:40:00
Job: MNSGW202219
Collection
End: 6/29/2022
08:40:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<5.54E-01
0.00E+00
5.54E-01
<3
LLD OK
Beta
<3.21 E+00
0.00E+00
3.21 E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.01 E+00
0.00E+00
6.01 E+00
<15
<1000
LLD OK
Co-58
<4.78E+00
0.00E+00
4.78E+00
<15
<1000
LLD OK
Fe-59
<9.62E+00
0.00E+00
9.62E+00
<30
<400
LLD OK
Co-60
<7.19E+00
0.00E+00
7.19E+00
<15
<300
LLD OK
Zn-65
<1.02E+01
0.00E+00
1.02E+01
<30
<300
LLD OK
Zr-95
<9.04E+00
0.00E+00
9.04E+00
<15
<400
LLD OK
Nb-95
<5.38E+00
0.00E+00
5.38E+00
<15
<400
LLD OK
1-131
<6.85E+00
0.00E+00
6.85E+00
<15
LLD OK
Cs-134
<7.33E+00
0.00E+00
7.33E+00
<15
<30
LLD OK
Cs-137
<6.54E+00
0.00E+00
6.54E+00
<18
<50
LLD OK
Bala-140
<5.58E+00
0.00E+00
5.58E+00
<15
<200
LLD OK
Be-7
<4.78E+01
0.00E+00
4.78E+01
K-40
1.62E+02
6.77E+01
7.99E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-9.2E+01
0.00E+00
1.90E+02
<250
<20000
LLD OK
Report Generated @ 8/1/2022 11:03:35 EnRad Laboratory Page 11 of 14
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories Page Page 11 of 15 08/01/2022

E n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 568728
Location: MNS-SW-1 [ MNS Landfill
2/SW-1 (LANDFILL)]
Collection
Start: 6/28/2022
11:35:00
Job: MNSGW202219
Collection
End: 6/28/2022
11:35:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<5.54E-01
0.00E+00
5.54E-01
<3
LLD OK
Beta
<3.21 E+00
0.00E+00
3.21 E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<4.42E+00
0.00E+00
4.42E+00
<15
<1000
LLD OK
Co-58
<4.69E+00
0.00E+00
4.69E+00
<15
<1000
LLD OK
Fe-59
<1.27E+01
0.00E+00
1.27E+01
<30
<400
LLD OK
Co-60
<7.01 E+00
0.00E+00
7.01 E+00
<15
<300
LLD OK
Zn-65
<1.24E+01
0.00E+00
1.24E+01
<30
<300
LLD OK
Zr-95
<1.13E+01
0.00E+00
1.13E+01
<15
<400
LLD OK
Nb-95
<6.11 E+00
0.00E+00
6.11 E+00
<15
<400
LLD OK
1-131
<7.80E+00
0.00E+00
7.80E+00
<15
LLD OK
Cs-134
<7.10E+00
0.00E+00
7.10E+00
<15
<30
LLD OK
Cs-137
<5.97E+00
0.00E+00
5.97E+00
<18
<50
LLD OK
Bala-140
<8.73E+00
0.00E+00
8.73E+00
<15
<200
LLD OK
Be-7
<4.10E+01
0.00E+00
4.10E+01
K-40
1.33E+02
6.75E+01
8.76E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-8.5E+01
0.00E+00
1.90E+02
<250
<20000
LLD OK
Report Generated @ 8/1/2022 11:03:35 EnRad Laboratory Page 12 of 14
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories Page Page 12 of 15 08/01/2022

E n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 568729
Location: MNS-SW-2 [ MNS Landfill
2/SW-2 (LANDFILL)]
Collection
Start: 6/28/2022
10:20:00
Job: MNSGW202219
Collection
End: 6/28/2022
10:20:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
<5.54E-01
0.00E+00
5.54E-01
<3
LLD OK
Beta
<3.21 E+00
0.00E+00
3.21 E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<6.65E+00
0.00E+00
6.65E+00
<15
<1000
LLD OK
Co-58
<6.29E+00
0.00E+00
6.29E+00
<15
<1000
LLD OK
Fe-59
<1.25E+01
0.00E+00
1.25E+01
<30
<400
LLD OK
Co-60
<5.50E+00
0.00E+00
5.50E+00
<15
<300
LLD OK
Zn-65
<1.17E+01
0.00E+00
1.17E+01
<30
<300
LLD OK
Zr-95
<1.09E+01
0.00E+00
1.09E+01
<15
<400
LLD OK
Nb-95
<6.90E+00
0.00E+00
6.90E+00
<15
<400
LLD OK
1-131
<6.60E+00
0.00E+00
6.60E+00
<15
LLD OK
Cs-134
<7.29E+00
0.00E+00
7.29E+00
<15
<30
LLD OK
Cs-137
<6.52E+00
0.00E+00
6.52E+00
<18
<50
LLD OK
Bala-140
<6.64E+00
0.00E+00
6.64E+00
<15
<200
LLD OK
Be-7
<5.20E+01
0.00E+00
5.20E+01
K-40
2.45E+02
8.77E+01
1.04E+02
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
<-4.9E+01
0.00E+00
1.89E+02
<250
<20000
LLD OK
Report Generated @ 8/1/2022 11:03:35 EnRad Laboratory Page 13 of 14
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories Page Page 13 of 15 08/01/2022

E n Radiological Data for MCGUIRE
Station: MCGUIRE
Sample #: 568730
Location: MNS_LEACHP [ MNS Landfill 2 / Leachate Pond ( LANDFILL) ] Collection
Start: 6/28/2022
11:00:00
Job: MNSGW202219
Collection
End: 6/28/2022
11:00:00
GW Ground Water
ALPHABETA
Gross Alpha / Beta Analysis in Water and Effluent
Filters
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Alpha
7.02E-01
7.95E-01
5.59E-01
<3
LLD OK
Beta
1.30E+01
4.48E+00
3.21 E+00
<4
LLD OK
GAMMAGW
Gamma Spectroscopy Ground Water Analysis
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
Mn-54
<5.58E+00
0.00E+00
5.58E+00
<15
<1000
LLD OK
Co-58
<5.56E+00
0.00E+00
5.56E+00
<15
<1000
LLD OK
Fe-59
<1.21 E+01
0.00E+00
1.21E+01
<30
<400
LLD OK
Co-60
<4.92E+00
0.00E+00
4.92E+00
<15
<300
LLD OK
Zn-65
<1.30E+01
0.00E+00
1.30E+01
<30
<300
LLD OK
Zr-95
<8.63E+00
0.00E+00
8.63E+00
<15
<400
LLD OK
Nb-95
<5.61 E+00
0.00E+00
5.61 E+00
<15
<400
LLD OK
1-131
<6.24E+00
0.00E+00
6.24E+00
<15
LLD OK
Cs-134
<6.67E+00
0.00E+00
6.67E+00
<15
<30
LLD OK
Cs-137
<5.96E+00
0.00E+00
5.96E+00
<18
<50
LLD OK
Bala-140
<6.48E+00
0.00E+00
6.48E+00
<15
<200
LLD OK
Be-7
<4.43E+01
0.00E+00
4.43E+01
K-40
1.89E+02
7.10E+01
7.90E+01
H3
Tritium Analysis of Water
Units: pCi/I
Activity
2 Sigma Error
Calculated MDA
SLC/ODCM LLD
Fraction SLC/ODCM RPT LVL
H3GW
7.54E+02
1.33E+02
1.89E+02
<250
<20000
LLD OK
Report Generated @ 8/1/2022 11:03:35 EnRad Laboratory Page 14 of 14
job_report_grouped_by_media MNS Building 7405 (MG03A2)
13339 Haqers Ferry Road
Huntersville, NC 28078
[phone]
EnRad Laboratories Page Page 14 of 15 08/01/2022

Appendix V - Rainfall Data and Leachate Generation Rates
(January 2022 through June 2022)

Leachate Collection System (LCS) and Leak Detection System (LDS) Tracking: January 2022 through June 2022)
Landfill No. 2 (Synthetically Lined) Permit No. 6004-INDUS
Duke Energy Carolinas McGuire Nuclear Station
Landfill No. 2 (Cells 1 through 4)
Landfill No. 2
Monthly
Leachate Collection System (LCS)
Leachate Pond Leak Detection System (LDS)
Comments
Duration
(notes for anything unusuaVdifferent in
Month
(days)
Rainfall*
(inches)
operations or Site conditions; e.g. system
Total Gallons
Mont Y
Leachate
Total Gallons
Mont Y
Exceeds
Exceeds ALR:
Pumped
Gallons
Average
Area
Generation
Pumped
Gallons
Area
Leakage
grad
downtimes, significant weather/storms, etc.]
Pumped
Flow (gpm)
(acres)
Pumped
(acres)
Rate (gpad)pad421
:IRLR:30j
(gal)
(nail
Rate (gpad)
(gal)
U
(Yes or No)
January-22
21
4.76
2,046,216
99,575
3.29
5
948.33
1,801
0
0.2
0.00
No
No
February-22
26
2.54
2,106,129
59,913
1.60
5
460.87
1,801
0
0.2
0.02
No
No
March-22
29
5.75
230,936
230,936
5.53
5
1,592.66
17
17
0.2
2.93
No
No
Software update reset Totalizers
April-22
37
4.46
212,286
212,286
3.98
5
1,147.49
264
264
0.2
35.68
No
No
Totalizers reset
May-22
20
3.13
258,037
45,751
1.59
5
457.51
297
33
0.2
8.19
No
No
June-22
40
1.35
330,682
72,645
1.26
5
363.23
325
28
0.2
3.53
No
No
Notes:
*Monthly rainfall data from Duke Meteorological Rain Gage on the McGuire Island
gal - gallons
gpm - gallons per minute
gpad - gallons per acre per day