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HomeMy WebLinkAbout8102_Rutherford_South_MSWLF_May2022GW_FID1738008_20221006dEfflommid ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR I I Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: • Prepare one form for each individually monitored unit. • Please type or print legibly. • Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). • Attach a notification table of any groundwater or surface water values that equal or, exceed the reporting limits. • Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 136 .1629 (4)(a)(i). • Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. d Name of entity submitting data (laboratory, consultant, facility owner): SCARLETT GEOPHYSICAL CONSULTING, PC Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: E. W. SCARLETT, JR. E-mail: wes-scarlett(ilnc.rr.com Phone: 919-452-1236 NC Landfill Rule: Facility name: Facility Address: Facility Permit # (.0500 or .1600) RUTHERFORD COUNTY SR 2138 L81-02 .0500 SOUTH LANDFILL FOREST CITY, NC Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑ Detection Monitoring of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data Surface water monitoring data ❑ Assessment Monitoring Methane gas monitoring data Corrective action data (specify) Other(specify) FOR Actual sampling dates (e.g., October 20-24, 2006) MAY 27, 2022 Corrective Action Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. E. W. SCARLETT, JR. PG 919-452-1236 Facility RepresNtative NameJPrint�, Title (Area Code) Telephone Number 500 HEPOWIL TRACE, HILLSBOROUGH, NC 27278 Facility Representative Address NC PE Firm License Number (if applicable effective May 1, Revised 6/2009 SEPT 30, 2022 Affix NC Licensed/ Professional Geologist Seal Date 4e4,O v,CAR,9 �oo9beo � A�Ly ads, \!v�:�\�Gri���•�v,r"7 a SE At o 681 w y o.A a i u w.e .%3 pl OG ; ®"°� S�ARLVO' RESULTS OF WATER QUALITY SAMPLING RUTHERFORD COUNTY SOUTH LANDFILL RUTHERFORD COUNTY, N.C. PERMIT # 81-02 MAY 2022 SGC PROJECT NUMBER 0001.002 PREPARED FOR RUTHERFORD COUNTY AUGUST 31, 2022 SCARLETT GEOPHYSICAL CONSULTING, P.C. 500 Hepowil Trace Telephone: 919-477-9519 Hillsborough, NC 27278 Website: www.searlettgeophysics.com RESULTS OF WATER QUALITY SAMPLING RUTHERFORD COUNTY SOUTH LANDFILL PERMIT # 81-02 AUGUST 2022 I hereby certify this 31 st day of August, 2022, that this report was prepared by me or under my direct supervision. E.W. Scarlett, Jr., P.G. Principal TABLE OF CONTENTS 1.0 EXECUTIVE SUMMARY.................................................................................................1 2.0 INTRODUCTION..............................................................................................................2 3.0 SCOPE OF WORK.............................................................................................................2 4.0 METHODS EMPLOYED...................................................................................................2 4.1 Monitoring Well Sampling......................................................................................2 4.2 Stream Sampling.....................................................................................................3 5.0 RESULTS..........................................................................................................................3 5.1 Groundwater...........................................................................................................3 5.2 Surface Water.........................................................................................................6 6.0 REFERENCES................................................................................................................... 8 TABLES Table 1 Summary of Monitoring Well Data Table 2 Ground and Surface Water Sampling Field Data, Rutherford County South Landfill, May 27, 2022 Table 3 Ground and Surface Water Sampling Results, RCRA Metals, Rutherford County South Landfill, May 27, 2022 Table 4 Ground and Surface Water Sampling Results, Appendix I Volatile Organics by SW- 846 Method 8260, Rutherford County South Landfill, May 27, 2022 Table 5 Notification Table FIGURES Figure 1 Site Location Map Figure 2 Site Map with Groundwater Contours APPENDICES Appendix A Ground and Surface Water Sampling Field Data Sheets Appendix B Laboratory Reports RESULTS OF WATER QUALITY SAMPLING RUTHERFORD COUNTY SOUTH LANDFILL PERMIT # 81-02 MAY 2022 1.0 EXECUTIVE SUMMARY Nine monitoring wells and two stream locations at the Rutherford County South Landfill were sampled on May 27, 2022. Monitoring well 8102-MW-3 was dry on the day that samples were collected. All sampling was conducted in accordance with North Carolina Solid Waste Management Guidelines. The samples were submitted to a North Carolina certified laboratory and tested for the Federal Appendix I list of volatile organic constituents for detection monitoring; 1,4- dioxane; and the eight RCRA metals. Results from nine monitoring well sample analyses show that the concentrations of four RCRA metals (arsenic in 8102-MW-2; chromium in 8102-MW-1, 8102-MW-2A, 8102-MW-4A, and 8102- MW-7; lead in 8102-MW-4A and 8102-MW-8; and mercury in 8102-MW-1 and 8102-MW-8) exceeded the 15A NCAC 2L (2L) Standard for Class GA groundwater on the date that the samples were collected. Arsenic, barium, cadmium, chromium, lead, and mercury were detected in one or more of the monitoring well samples at concentrations that did not exceed the 2L Standards. Results from nine monitoring well sample analyses show that concentrations of four Appendix I volatile organic constituents (1,1-dichloroethane in 8102-MW-1; benzene in 8102-MW-1 and 8102-MW-6; methylene chloride in 8102-MW-1; and vinyl chloride in 8102-MW-5) exceeded the 2L Standards on the date that the samples were collected. Concentrations of 1,4-dioxane exceeded the 2L Standard in 8102-MW-2A, 8102-MW-5, 8102-MW-6, and 8102-MW-7 on the date that samples were collected. The following Appendix I volatile organic constituents (1,1- dichloroethane; 1,1-dichloroethene; 1,2 -dichloro ethane; 1,4-diclorobenzene; benzene; carbon disulfide; chlorobenzene; chloroethane; chloroform; cis-1,2-dichloroethene; total xylenes; and trichloroethene) were detected in one or more of the monitoring well samples at concentrations that did not exceed the 2L or NC Groundwater Protection (NCGP) Standards. May 2022 Sampling Report August 31, 2022 Rutherford County South Landfill Page 1 No RCRA metals were detected at concentrations that exceeded the 15A NCAC 2B Standard for Class B/C Surface Waters (213) in the surface water samples collected from the creek that flows along the northeast boundary of the landfill property. One RCRA metal that does not have an established 2B standard (barium) was detected in both surface water samples. No Appendix I volatile organic constituents were detected in either surface water sample. 1,4-Dioxane was detected in 8102-SW-2 at 5.3 ppb. 2.0 INTRODUCTION Scarlett Geophysical Consulting, P.C. (SGC) was contracted by Rutherford County, North Carolina, to sample the ground and surface water at ten monitoring wells and two surface water locations on or adjacent to the South Landfill property. The site location is shown on Figure 1. 3.0 SCOPE OF WORK The scope of work for this sampling event was to sample ten monitoring wells and two stream locations for Federal Appendix I volatile organic constituents as listed in 40 CFR, Part 258, and the eight RCRA metals, and to prepare and submit reports to the client and NC Division of Solid Waste Management documenting the sample collection procedures and analytical results. 4.0 METHODS EMPLOYED 4.1 Monitoring Well Sampling Groundwater sampling took place on May 27, 2022. Water levels were measured in each well to provide data for water volume calculations (Table 1). The wells were then purged by removing a minimum of three well volumes or bailing the wells dry prior to obtaining water samples. The water samples were collected using properly decontaminated Teflon bailers. Immediately upon collection, the water samples were field tested for temperature, specific conductance, and pH. These data are summarized in Table 2. Field data sheets are included as Appendix A. Samples were placed in laboratory cleaned and supplied containers, packed on ice, and placed under chain - of -custody. Samples were shipped to the laboratory under chain -of -custody upon completion of May 2022 Sampling Report August 31, 2022 Rutherford County South Landfill Page 2 the field work. Analyses were conducted by Pace Analytical, a North Carolina certified laboratory. The monitoring well locations are shown on Figure 2. 4.2 Stream Sampling Surface water sampling took place on May 27, 2022. Samples 8102-SW-1 and 8102-SW-2 were collected from a stream that flows southeastward along the northeast boundary of the South Landfill property. This stream flows into the Second Broad River, which bounds the landfill to the east. All stream samples were analyzed for the same parameters as the ground water samples. The stream sample locations are shown on Figure 2. 5.0 RESULTS The results of the laboratory analyses are summarized in Tables 3 and 4, and the complete laboratory reports are included as Appendix B. 5.1 Groundwater The groundwater sample analyses revealed nine constituents that had concentrations at or above the 2L Standards in one or more of the nine wells sampled. These analytical results are listed below and shown in the Notification Table (Table 5). • Arsenic was detected in 8102-MW-1 at 19.1 ppb. The 2L Standard is 10.0 ppb. • Chromium was detected in 8102-MW-1 at 12.8 ppb, 8102-MW-2A at 22.0 ppb, 8102-MW- 4A at 74.3 ppb, and 8102-MW-7 at 38.4 ppb. The 2L Standard is 10.0 ppb. • Lead was detected in 8102-MW-4A at 16.6 ppb and 8102-MW-8 at 19.3 ppb. The 2L Standard is 15.0 ppb. • Mercury was detected in 8102-MW-1 at 1.00 ppb and 8102-MW-8 at 4.00 ppb. The 2L Standard is 1.0 ppb. • 1,1-Dichloroethane was detected in 8102-MW-1 at 47.9 ppb. The 2L Standard is 6.0 ppb. May 2022 Sampling Report August 31, 2022 Rutherford County South Landfill Page 3 • 1,4-Dioxane was detected in 8102-MW-2A at 13.0 ppb, 8102-MW-5 at 21.3 ppb, 8102- MW-6 at 37.7 ppb, and 8102-MW-7 at 5.0 ppb. The 2L Standard is 3.0 ppb. • Benzene was detected in 8102-MW-1 at 1.7 ppb and 8102-MW-6 at 1.2 ppb. The 2L Standard is 1.0 ppb. • Methylene Chloride was detected in 8102-MW-1 at 14.6 ppb. The 2L Standard is 5.0 ppb. • Vinyl chloride was detected in 8102-MW-5 at 0.39 ppb. The 2L Standard is 0.03 ppb. The volatile organic constituents present in the groundwater samples are likely due to past waste disposal; however, contributions by ongoing farming activities immediately north and south of the old property boundaries and vehicles involved in active maintenance of the landfill cover cannot be ruled out. Groundwater flow direction data indicate that all groundwater from the disposal area is intercepted by perennial streams to the north, south, and east. There is no direct evidence indicating that Appendix I volatile organic constituent concentrations resulting from waste disposal at South Landfill currently exceed the 2L or NCGP Standards at locations beyond the property boundaries. The interval since the last waste disposal suggests that significant impacts on groundwater contamination from the source area are unlikely to increase in the future. The inorganic constituents present in the groundwater samples may have been influenced by past waste disposal, but it is likely that local geology also has an impact. 8102-MW-4A, which is upgradient from the waste disposal area (see Figure 2), shows minimal volatile organic impact, yet historically has shown inorganic constituent concentrations that are similar to those in the downgradient monitoring wells. The presence of measurable concentrations of barium in the upgradient surface water sample for this event in addition to cadmium, chromium, lead, mercury, silver, and selenium during prior events suggests the likely influence of contributions from off site sources (local geological and/or cultural). 5.2 Surface Water The surface water sample analyses did not reveal any constituents that had concentrations at or above the 2B Standards. May 2022 Sampling Report August 31, 2022 Rutherford County South Landfill Page 4 Two constituents (listed below) for which no 2B Standard has been established were detected at concentrations above the PQL. Barium in 8102-SW-1 and 8102-SW-2. 1,4-Dioxane in 8102-SW-2. May 2022 Sampling Report August 31, 2022 Rutherford County South Landfill Page 5 6.0 REFERENCES Department of Environment, Health and Natural Resources, Division of Solid Waste Management, Solid Waste Section, NC Solid Waste Program, Environmental Monitoring Constituent List (downloaded June 1, 2012). North Carolina Administrative Code, Title 15A, Department of Environment and Natural Resources, Division of Water Quality, Subchapter 2L, Sections .0100, .0200, and .0300, Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina, (April 1, 2005, Amended July 1, 2021); from the Environmental Management Commission, Raleigh, North Carolina. North Carolina Administrative Code Section: 15A NCAC 2B .0200, Department of Environment, and Natural Resources, Division of Water Quality, Classifications and Water Quality Standards Applicable to Surface Waters and Wetlands of North Carolina, Section .0200 (May 1, 2007); from the Environmental Management Commission, Raleigh, North Carolina. North Carolina Administrative Code, Title 15A, Department of Environment, Health and Natural Resources, Division of Solid Waste Management, Subchapter 13B, Solid Waste Management, Section .1600 (August 27, 2001). North Carolina Solid Waste Section Memorandum Regarding New Guidelines for Electronic Submittal of Environmental Data, October 27, 2006. Addendum to October 27, 2006, North Carolina Solid Waste Section Memorandum Regarding New Guidelines for Electronic Submittal of Environmental Data, February 23, 2007. North Carolina Water Quality Monitoring Guidance Document for Solid Waste Facilities, Department of Environment, Health and Natural Resources, Division of Solid Waste Management, Solid Waste Section, (January 2000), Download from NCSW Web Site. May 2022 Sampling Report August 31, 2022 Rutherford County South Landfill Page 6 North Carolina Solid Waste Section Memorandum, 1,4-Dioxane Analysis, Solid Waste Section Limits and Laboratory Analytical Methods, May 29, 2018. RESULTS OF WATER QUALITY SAMPLING RUTHERFORD COUNTY SOUTH LANDFILL PERMIT # 81-02 AUGUST 2022 I hereby certify this 31 st day of August, 2022, that this report was prepared by me or under my direct supervision. AA •y� �e ,C NgFo.�067 SEAL 681 E.W. Scarlett, Jr., P.G. 'r otv������'Z� Principal N a; a z O Z N no 0. � 3aN LLl rn U \ o .ir ``��C'xi ri'r`•> /ir1/ j , /! j'; i SECOND BROAD RIVERIt . -... - ', ti '!., �', :r �' r 1 i'f •!' 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SITE LOCATION MAP FIGURE I I TABLE 1 SUMMARY OF MONITORING WELL DATA RUTHERFORD COUNTY SOUTH LANDFILL RUTHERFORD COUNTY, NORTH CAROLINA Well Number Elevation (ft)' Top of Casing Depth of Well (ft)2 Static Water Levels May 27, 2022 Depth (ft)2 Elevation (ft) 8102-MW-1 811.88 37.58 31.12 780.76 8102-MW-2A 790.40 45.21 34.15 756.25 8102-MW-3 783.42 19.00 >19.00 >764.42 8102-MW-4A 845.17 30.35 27.30 817.87 8102-MW-5 765.32 20.13 11.50 753.82 8102-MW-6 801.87 37.00 29.49 772.38 8102-MW-7 770.68 30.30 16.22 754.46 8102-MW-8 813.03 42.30 33.09 779.94 8102-MW-9D 1 764.28 1 67.70 6.12 1 758.16 8102-MW-9S 1 763.93 1 24.85 6.64 1 757.29 Notes: ' Elevations determined by survey: Burnt Chimney Surveying, Forest City, NC 2 Depths measured from top of casing by Scarlett Geophysical Consulting, P.C. RuthSouthTables-0522 TABLE 2 GROUND AND SURFACE WATER SAMPLING FIELD DATA RUTHERFORD COUNTY SOUTH LANDFILL MAY 27, 2022 Sample No. Field Parameter 8102-MW-1 8102-MW-2A 8102-MW-3 8102-MW-4A 8102-MW-5 8102-MW-6 8102-MW-7 8102-MW-8 Temperature 18.0°C 17.2°C Dry Well 17.4°C 16.0°C 18.1°C 18.0°C 17.1°C Specific Conductance 51.3 pmhos/cm 367.0 pmhos/cm - 80.7 pmhos/cm 274.0 pmhos/cm 828.0 pmhos/cm 77.4 pmhos/cm 38.2 pmhos/cm pH 1 5.10 6.38 - 5.36 6.49 6.40 5.24 5.28 Field Parameter Sample No. 8102-MW-9D 8102-MW-9S 8102-SW-1 8102SW-2 Temperature 16.1°C 15.3°C 19.2°C 20.8°C Specific Conductance 45.3 pmhos/cm 40.0 pmhos/cm 60.5 pmhos/cm 66.0 pmhos/cm pH 1 6.28 5.54 7.30 6.49 Ruth SouthTables-0522 TABLE 3 GROUND AND SURFACE WATER SAMPLING RESULTS RCRA METALS RUTHERFORD COUNTY SOUTH LANDFILL PERMIT # 81-02 MAY 27. 2022 Sam Is No. 15A NCAC 2L Standards for Class 15A NCAC 2B Standards for Class Compound 8102-MW-1 8102-MW-2A 8102-MW-3 8102-MW-4A 8102MW-5 8102-MW-6 8102-MW-7 8102-MW-8 8102-MW-9D 8102-MW-9S 8102-SW-1 8102-SW-2 GA Ground Water B, C Surface Waters Arsenic, Total BQL 19.1 NS 4.70 4.70 BQL BQL BQL BQL BQL BQL BQL 10.0 50.0 Barium, Total 180.00 207.00 NS 199.00 163.00 65.00 123.00 335.00 59.90 26.80 27.00 35.40 700.0 Cadmium, Total BQL 0.40 NS 1.10 0.40 0.40 0.40 0.40 BQL BQL BQL BQL 2.0 2.0 Chromium, Total 12.80 22.00 NS 74.30 3.70 7.10 38.40 9.10 BQL BQL BQL BQL 10.0 50.0 Lead, Total BQL 5.50 NS 16.60 BQL BQL 11.40 19.30 BQL BQL BQL BQL 15.0 25.0 Mercury, Total 1.00 BQL NS 0.23 BQL BQL 0.53 4.00 BQL BQL BQL BQL 1.0 0.012 Selenium, Total BQL BQL NS BQL BQL BQL BQL BQL BQL BQL BQL BQL 20.0 5.0 Silver, Total BQL BQL NS BQL BQL BQL BQL BQL BQL BQL BQL BQL 20.0 0.061�1 Notes: • All results in parts per billion (ppb) • BQL - Below Method Detection Limit • J - Estimated results. Present but below reporting limit • Shaded cells denote concentrations that exceed 15A NCAC 2L Standards for Class GA Groundwater (MW data) or 15A NCAC 2B Standards for Class B surface waters (SW data) •' - Standard not established • n] - Action Level RuthSouthTa bles-0522 TABLE 4 GROUND AND SURFACE WATER SAMPLING RESULTS APPENDIX I VOLATILE ORGANICS BY SW-846 METHOD 8260 RUTHERFORD COUNTY SOUTH LANDFILL PERMIT # 81-02 MAY 27, 2022 COMPOUND Sam Is No. 15A NCAC 2L Standards for Class GA Ground Water NC Groundwater Protection Standards 15A NCAC 2B Standards for Class B, CSurface Water, 8102-MW-1 8102-MW-2A 8102-MW-3 8102-MW-!.A 8102-MW-5 8102-MW-6 8102-MW-7 8102-MW-8 8102-MW-9D 8102-MW-9S 8102-SW-1 8102-SW-2 1, 1, 1,2-Tetmchloroethane BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 1.0 ` 1, 1, 1-Trichloroethane BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 200.0 1, 1,2,2-Tetmchloroethane BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 1.0 1, 1,2-Trichloroethane BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.6 ' 1,1-Dichloroethane 47.90 0.37 INS BQL 2.70 0.37 BQL 4.90 BQL BQL BQL BQL 6.0 ' 1,1-Dichloroethene' 1.00 BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 350.0 ' 1,2,3-Trichloro ro ane BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.005 ' 1,2-Dibromo-3-Chloro ro ane BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.04 ' 1,2-Dibromoethane' BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.02 ' 1,2-Dichlorobenzene' BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 20.0 ' 1,2-Dichloroethane' 0.32 BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.4 1,2-Dichloropropane' BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.6 1,4-Dichlorobenzene' 1.80 2.00 INS BQL 2.10 1.50 0.33 BQL BQL BQL BQL BQL 6.0 1,4-Dioxane 0.86 13.00 INS BQL 21.30 37.70 5.00 BQL BQL BQL BQL 5.30 3.0 ' 2 - Butanone MEK BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 4,000.0 ' 2-Hexanone' BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 40.0 ' 4-Methyl-2-pentanone' BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 560.0 ' Acetone BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 6,000.0 ' Acrylonitrile BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL Benzene 1.70 0.34 INS BQL 0.34 1.20 BQL BQL BQL BQL BQL BQL 1.0 ' Bromochloromethane BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.6 ` Bromodichloromethane BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.6 ' Bromoform BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 4.0 Bromomethane' BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 10.0 ' Carbon Disulfide BQL BQL INS BQL 0.36 0.36 BQL BQL BQL BQL BQL BQL 700.0 ' Carbon Tetrachloride BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.3 Chlorobenzene 2.00 5.00 INS BQL 1.60 2.50 0.28 BQL BQL BQL BQL BQL 50.0 ' Chloroethane 6.40 BQL INS BQL 1.40 BQL BQL BQL BQL BQL BQL BQL 3,000.0 Chloroform 0.43 BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 70.0 ' Chloromethane' BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 3.0 ' cis-1,2-Dichloroethene 5.30 0.38 INS BQL 6.70 1.60 BQL BQL BQL BQL BQL BQL 70.0 ' cis-1,3-Dichloro ro ene BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.4 ' Dibromochloromethane' BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.4 0.41 ' Dibromomethane' BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 70.0 ' Eth (benzene BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 600.0 ' Methyl iodide BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL ' Methylene Chloride 14.60 BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 5.0 Styrene BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 70.0 ' Tetrachloroethene BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.7 Toluene BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 600.0 11.0 Total X lenes 3.70 BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 500.0 ' trans-1,2-Dichloroethene BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 100.0 ' trans-1,3-Dichloro ro ene BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.4 trans-14-Dichloro-2-bulene BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL ' Tdchloroethene 0.38 BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 3.0 Tdchlorofluoromethane' BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 2,000.0 ' Vin I acetate BQL BQL INS BQL BQL BQL BQL BQL BQL BQL BQL BQL 88.0 ' Vin I chloride BQL BQL INS BQL 0.39 BQL BQL BQL BQL BQL BQL BQL 0.03 ' Notes: • All results in parts per billion (ppb) • BQL - Below Method Detection Limit • J - Estimated results. Present but below reporting limit • * - Standard not established Shaded cells denote concentrations that equal or exceed 2L, Groundwater Protection, or 2B (Class BIC) Standards • For constituents that are not naturally occuring and have no established standards, the SWS limits are the Standards ' Synonyms: 1,1-Dichloroethene = Vinylidene Chloride 1,2-Dibromoethane = Ethylene Dibromide 12-Dichlorobenzene = o Dichlorobenzene 1,2-Dichloroethane = Ethylene Dichloride 1,2-Dichloropropane = Propylene Dichloride 1,4-Dichlorobenzene = p Dichlorobenzene 2-Hexanone = Methyl Butyl Ketone 4-Methyl-2-Pentanone = Methyl Isobully Keytone Bromomethane - Methyl Bromide Chloromethane = Methyl Chloride Dibromochloromethane = Chlorodibromomethane Dibromomethane = Methylene Bromide Methylene Chloride = Dichloromethane Trichlorofluoromethane = CFC-11 RuthSouthTables-0522 TABLE 5 NOTIFICATION TABLE CONSTITUENTS DETECTED AT OR ABOVE GROUND AND SURFACE WATER STANDARDS RUTHERFORD COUNTY SOUTH LANDFILL (PERMIT # 81-02) MAY 27, 2022 COMPOUND Sample Location 15A NCAC 2L Standards for Class GA Ground Water NC Groundwater Protection Standards 15A NCAC 2B Standards for Class B, C Surface Water 8102-MW-1 8102-MW-2A 8102-MW-3 8102-MW-4A 8102-MW-5 8102-MW-6 8102-MW-7 8102-MW-8 8102-MW-9D 8102-MW-9S 8102-SW-1 8102-SW-2 Arsenic 19.1 10.0 50.0 Chromium, Total 12.8 22.0. 74.3 38.4 10.0 50.0 Lead 16.6 19.3 15.0 25.0 Mercury, Total 1.00 4.00 1.0 0.012 1,1-Dichloroethane 47.9 6.0 1,4-Dioxane 13.0 21.3 37.7 1 5.0 1 3.0 Benzene 1.7 1.2 1.0 Meth lene chloride 14.6 5.0 Vin l chloride 0.39 0.03 Notes: All results in parts per billion (ppb) J - Estimated results. Present but below reporting limit Standard not established • Shaded cells denote concentrations that equal or exceed 2L, Groundwater Protection, or 2B Standards • I'I - Action Level R uthSouthTa bles-0522 SCARLETT GEOPHYSICAL CONSULTING, P. C. GROUNDWATER SAMPLING FIELD DATA Location: Rutherford County South Source/Well: 8102-MW-1 Locked: Yes X No PVC X Steel Stainless Steel Measuring point description: Top of PVC Casing Water Level and Well Data 1) Depth to water from measuring point 2) Depth to well bottom from measuring point 3) Height of water column (h) Well Purging and Sample Collection 1) Purge Method 2) Sample Method 3) Volume of water in well 1" well .... (v = 0.041 x h) X 2" well .... (v = 0.163 x h) 4" well .... (v = 0.651 x h) 6" well .... (v = 1.5 x h) 4) Volume of water removed prior to sampling 5) Was well purged DRY? Field Analysis 1) Temperature 2) Specific Conductance 3) pH 4) Physical Appearance and Odor Purge Date: May 27, 2022 Purge Time: 1130 to 1145 Sample Date: May 27, 2022 Sample Time: 1150 Sampled by: P. A. Miller Weather: Partl,, cam, 31.12 ft. 3 7.5 8 ft. 6.46 ft. Teflon bailer Teflon bailer 1.05 gal. 3.2 gal. YES: _ NO: X 18.0°C 51.3 µmhos/cm 5.10 Cloudy, no odor SCARLETT GEOPHYSICAL CONSULTING, P. C. GROUNDWATER SAMPLING FIELD DATA Location: Rutherford County South Purge Date: May 27, 2022 Source/Well: 8102-MW-2A Purge Time: 1450 to 1505 Locked: Yes X No _ Sample Date: May 27, 2022 PVC X Steel _ Stainless Steel _ Sample Time: 1525 Measuring point description: Top of PVC Casing Water Level and Well Data 1) Depth to water from measuring point 2) Depth to well bottom from measuring point 3) Height of water column (h) Well Purging and Sample Collection 1) Purge Method 2) Sample Method 3) Volume of water in well 1" well .... (v = 0.041 x h) X 2" well .... (v = 0.163 x h) 4" well .... (v = 0.651 x h) 6" well .... (v = 1.5 x h) 4) Volume of water removed prior to sampling 5) Was well purged DRY? Field Analysis 1) Temperature 2) Specific Conductance 3) pH 4) Physical Appearance and Odor Sampled by: P. A. Miller Weather: Sunny, 78°F 34.15 ft. 45.21 ft. 11.06 ft. Teflon bailer Teflon bailer 1.8 gal. 5.4 gal. YES _ NO X 17.2°C 367.0 µmhos/cm 6.38 Cloud gray, septic odor SCARLETT GEOPHYSICAL CONSULTING, P. C. GROUNDWATER SAMPLING FIELD DATA Location: Rutherford County South Source/Well: 8102-MW-3 Locked: Yes X No PVC X Steel Stainless Steel Measuring point description: Top of PVC Casing Water Level and Well Data 1) Depth to water from measuring point 2) Depth to well bottom from measuring point 3) Height of water column (h) Well Purging and Sample Collection 1) Purge Method 2) Sample Method 3) Volume of water in well 1" well .... (v = 0.041 x h) X 2" well .... (v = 0.163 x h) 4" well .... (v = 0.651 x h) 6" well .... (v = 1.5 x h) 4) Volume of water removed prior to sampling 5) Was well purged DRY? Field Analysis 1) Temperature 2) Specific Conductance 3) pH 4) Physical Appearance and Odor Note: Dry Well Purge Date: May 27, 2022 Purge Time: - to - Sample Date: May 27, 2022 Sample Time: - Sampled by: E. W. Scarlett Weather: Sunny, 78°F - ft. 19.00 ft. - ft. Teflon bailer Teflon bailer gal. - gal. YES X NO - °C - µmhos/cm SCARLETT GEOPHYSICAL CONSULTING, P. C. GROUNDWATER SAMPLING FIELD DATA Location: Rutherford County South Source/Well: 8102-MW-4A Locked: Yes X No PVC X Steel Stainless Steel Measuring point description: Top of PVC Casing Water Level and Well Data 1) Depth to water from measuring point 2) Depth to well bottom from measuring point 3) Height of water column (h) Well Purging and Sample Collection 1) Purge Method 2) Sample Method 3) Volume of water in well 1" well .... (v = 0.041 x h) X 2" well .... (v = 0.163 x h) 4" well .... (v = 0.651 x h) 6" well .... (v = 1.5 x h) 4) Volume of water removed prior to sampling 5) Was well purged DRY? Field Analysis 1) Temperature 2) Specific Conductance 3) pH 4) Physical Appearance and Odor Purge Date: May 27, 2022 Purge Time: 1335 to 1340 Sample Date: May 27, 2022 Sample Time: 1400 Sampled by: E. W. Scarlett Weather: Partly Cloudy, 78OF 27.30 ft. 3 0.3 5 ft. 3.05 ft. Teflon bailer Teflon bailer 0.50 gal. 0.75 gal. YES X NO 17.4 °C 80.7 µmhos/cm 5.36 Cloudy, tan, no odor SCARLETT GEOPHYSICAL CONSULTING, P. C. GROUNDWATER SAMPLING FIELD DATA Location: Rutherford County South Source/Well: 8102-MW-5 Locked: Yes X No PVC X Steel Stainless Steel Measuring point description: Top of PVC Casing Water Level and Well Data 1) Depth to water from measuring point 2) Depth to well bottom from measuring point 3) Height of water column (h) Well Purging and Sample Collection 1) Purge Method 2) Sample Method 3) Volume of water in well 1" well .... (v = 0.041 x h) X 2" well .... (v = 0.163 x h) 4" well .... (v = 0.651 x h) 6" well .... (v = 1.5 x h) 4) Volume of water removed prior to sampling 5) Was well purged DRY? Field Analysis 1) Temperature 2) Specific Conductance 3) pH 4) Physical Appearance and Odor Purge Date: May 27, 2022 Purge Time: 0940 to 0950 Sample Date: May 27, 2022 Sample Time: 0955 Sampled by: P. A. Miller Weather: Partl,, cry, 69°F 11.50 ft. 20.13 ft. 8.63 ft. Teflon bailer Teflon bailer 1.41 gal. 4.2 gal. YES _ NO X 16.0°C 274.0 µmhos/cm 6.49 hazy, slight septic odor SCARLETT GEOPHYSICAL CONSULTING, P. C. GROUNDWATER SAMPLING FIELD DATA Location: Rutherford County South Source/Well: 8102-MW-6 Locked: Yes X No PVC X Steel Stainless Steel Measuring point description: Top of PVC Casing Water Level and Well Data 1) Depth to water from measuring point 2) Depth to well bottom from measuring point 3) Height of water column (h) Well Purging and Sample Collection 1) Purge Method 2) Sample Method 3) Volume of water in well 1" well .... (v = 0.041 x h) X 2" well .... (v = 0.163 x h) 4" well .... (v = 0.651 x h) 6" well .... (v = 1.5 x h) 4) Volume of water removed prior to sampling 5) Was well purged DRY? Field Analysis 1) Temperature 2) Specific Conductance 3) pH 4) Physical Appearance and Odor Purge Date: May 27, 2022 Purge Time: 1330 to 1340 Sample Date: May 27, 2022 Sample Time: 1345 Sampled by: P. A. Miller Weather: Sunny, 76°F 29.49 ft. 37.00 ft. 7.51 ft. Teflon bailer Teflon bailer 1.22 gal. 3.7 gal. YES NO X 18.1°C 828.0 µmhos/cm 6.40 Foamy, no odor SCARLETT GEOPHYSICAL CONSULTING, P. C. GROUNDWATER SAMPLING FIELD DATA Location: Rutherford County South Source/Well: 8102-MW-7 Locked: Yes X No PVC X Steel Stainless Steel Measuring point description: Top of PVC Casing Water Level and Well Data 1) Depth to water from measuring point 2) Depth to well bottom from measuring point 3) Height of water column (h) Well Purging and Sample Collection 1) Purge Method 2) Sample Method 3) Volume of water in well 1" well .... (v = 0.041 x h) X 2" well .... (v = 0.163 x h) 4" well .... (v = 0.651 x h) 6" well .... (v = 1.5 x h) 4) Volume of water removed prior to sampling 5) Was well purged DRY? Field Analysis 1) Temperature 2) Specific Conductance 3) pH 4) Physical Appearance and Odor Purge Date: May 27, 2022 Purge Time: 1245 to 1255 Sample Date: May 27, 2022 Sample Time: 1300 Sampled by: E. W. Scarlett Weather: Sunny, 77°F 16.22 ft. 3 0.3 0 ft. 14.08 ft. Teflon bailer Teflon bailer 2.30 gal. 6.9 gal. YES _ NO X 18.0°C 77.4 µmhos/cm 5.24 Cloudy, tan, no odor SCARLETT GEOPHYSICAL CONSULTING, P. C. GROUNDWATER SAMPLING FIELD DATA Location: Rutherford County South Source/Well: 8102-MW-8 Locked: Yes X No PVC X Steel Stainless Steel Measuring point description: Top of PVC Casing Water Level and Well Data 1) Depth to water from measuring point 2) Depth to well bottom from measuring point 3) Height of water column (h) Well Purging and Sample Collection 1) Purge Method 2) Sample Method 3) Volume of water in well 1" well .... (v = 0.041 x h) X 2" well .... (v = 0.163 x h) 4" well .... (v = 0.651 x h) 6" well .... (v = 1.5 x h) 4) Volume of water removed prior to sampling 5) Was well purged DRY? Field Analysis 1) Temperature 2) Specific Conductance 3) pH 4) Physical Appearance and Odor Purge Date: May 27, 2022 Purge Time: 1130 to 1145 Sample Date: May 27, 2022 Sample Time: 1150 Sampled by: E, W. Scarlett Weather: Partl,, cry, 74°F 33.09 ft. 42.30 ft. 9.21 ft. Teflon bailer Teflon bailer 1.50 gal. 4.5 gal. YES _ NO X 17.10C 38.2 µmhos/cm 5.28 Muddy, brown, septic odor SCARLETT GEOPHYSICAL CONSULTING, P. C. GROUNDWATER SAMPLING FIELD DATA Location: Rutherford County South Source/Well: 8102-MW-9D Locked: Yes X No PVC X Steel Stainless Steel Measuring point description: Top of PVC Casing Water Level and Well Data 1) Depth to water from measuring point 2) Depth to well bottom from measuring point 3) Height of water column (h) Well Purging and Sample Collection 1) Purge Method 2) Sample Method 3) Volume of water in well 1" well .... (v = 0.041 x h) X 2" well .... (v = 0.163 x h) 4" well .... (v = 0.651 x h) 6" well .... (v = 1.5 x h) 4) Volume of water removed prior to sampling 5) Was well purged DRY? Field Analysis 1) Temperature 2) Specific Conductance 3) pH 4) Physical Appearance and Odor Purge Date: May 27, 2022 Purge Time: 0940 to 1010 Sample Date: May 27, 2022 Sample Time: 1010 Sampled by: E. W. Scarlett Weather: Partl,, cry, 71°F 6.12 ft. 67.70 ft. 61.58 ft. Pump Teflon bailer 10.04 gal. 30+ gal. YES _ NO X 16.1 °C 45.3 µmhos/cm 6.28 Clear. No odor. SCARLETT GEOPHYSICAL CONSULTING, P. C. GROUNDWATER SAMPLING FIELD DATA Location: Rutherford County South Source/Well: 8102-MW-9S Locked: Yes X No PVC X Steel Stainless Steel Measuring point description: Top of PVC Casing Water Level and Well Data 1) Depth to water from measuring point 2) Depth to well bottom from measuring point 3) Height of water column (h) Well Purging and Sample Collection 1) Purge Method 2) Sample Method 3) Volume of water in well 1" well .... (v = 0.041 x h) X 2" well .... (v = 0.163 x h) 4" well .... (v = 0.651 x h) 6" well .... (v = 1.5 x h) 4) Volume of water removed prior to sampling 5) Was well purged DRY? Field Analysis 1) Temperature 2) Specific Conductance 3) pH 4) Physical Appearance and Odor Purge Date: May 27, 2022 Purge Time: 0950 to 1005 Sample Date: May 27, 2022 Sample Time: 1015 Sampled by: E. W. Scarlett Weather: Partl,, cry, 71°F 6.64 ft. 24.85 ft. 18.21 ft. Teflon bailer Teflon bailer 2.97 gal. 8.9 gal. YES _ NO X 15.3°C 40.0 µmhos/cm 5.54 Cloudy, tan, no odor SCARLETT GEOPHYSICAL CONSULTING, P. C. SURFACE WATER SAMPLING FIELD DATA Location: Rutherford County South Sample Date: May 27, 2022 Source/Well: 8102-SW-1 Sample Time: 1045 Sampled by: E. W. Scarlett Weather: Partl,, cry, 71°F Field Analvsis 1) Temperature 19.2°C 2) Specific Conductance 60.5 µmhos/cm 3) pH 7.30 4) Physical Appearance and Odor Cloudy, no odor SCARLETT GEOPHYSICAL CONSULTING, P. C. SURFACE WATER SAMPLING FIELD DATA Location: Rutherford County South Sample Date: May 27, 2022 Source/Well: 8102-SW-2 Sample Time: 1510 Sampled by: E. W. Scarlett Weather: Partly Cloudy, 78°F Field Analvsis 1) Temperature 20.8°C 2) Specific Conductance 66.0 µmhos/cm 3) pH 6.49 4) Physical Appearance and Odor Murky, no odor leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 July 01, 2022 Wes Scarlett Scarlett Geophysical 500 Heporwil Trace Hillsborough, NC 27278 RE: Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Dear Wes Scarlett: Enclosed are the analytical results for sample(s) received by the laboratory on June 01, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 39 lacmnalyfica(' www,pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Scarlett Geo South Landfill 92607341 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92607341001 8103-MW-1 EPA 6010D SBW 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92607341002 8103-MW-2A EPA 6010D SBW 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92607341003 8103-MW-4A EPA 6010D SBW 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92607341004 8103-MW-5 EPA 6010D RDT 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92607341005 8103-MW-6 EPA 6010D RDT 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92607341006 8103-MW-7 EPA 6010D SBW 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92607341007 8103-MW-8 EPA 6010D SBW 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92607341008 8103-MW-9S EPA 6010D SBW 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92607341009 8103-MW-9D EPA 6010D SBW 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92607341010 8103-SW-1 EPA 6010D SBW 7 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92607341011 8103-SW-2 EPA 6010D SBW 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-MW-1 Lab ID: 92607341001 Collected: 05/27/22 11:50 Received: 06/01/22 13:15 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic <4.7 ug/L 4.7 1 06/28/2216:16 06/29/2219:05 7440-38-2 Barium 180 ug/L 3.5 1 06/28/2216:16 06/29/2219:05 7440-39-3 Cadmium <0.40 ug/L 0.40 1 06/28/2216:16 06/29/2219:05 7440-43-9 Chromium 12.8 ug/L 3.7 1 06/28/2216:16 06/29/2219:05 7440-47-3 Lead <4.5 ug/L 4.5 1 06/28/2216:16 06/29/2219:05 7439-92-1 Selenium <4.7 ug/L 4.7 1 06/28/2216:16 06/29/2219:05 7782-49-2 Silver <2.5 ug/L 2.5 1 06/28/2216:16 06/29/2219:05 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury 1.0 ug/L 0.12 1 06/14/2214:15 06/20/2212:03 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 06/02/22 21:35 67-64-1 Acrylonitrile <1.8 ug/L 1.8 1 06/02/22 21:35 107-13-1 M1 Benzene 1.7 ug/L 0.34 1 06/02/22 21:35 71-43-2 M1 Bromochloromethane <0.47 ug/L 0.47 1 06/02/22 21:35 74-97-5 M1 Bromodichloromethane <0.31 ug/L 0.31 1 06/02/22 21:35 75-27-4 M1 Bromoform <0.34 ug/L 0.34 1 06/02/22 21:35 75-25-2 Bromomethane <1.7 ug/L 1.7 1 06/02/22 21:35 74-83-9 v2 2-Butanone (MEK) <4.0 ug/L 4.0 1 06/02/22 21:35 78-93-3 M1 Carbon disulfide <0.36 ug/L 0.36 1 06/02/22 21:35 75-15-0 L2,M0 Carbon tetrachloride <0.33 ug/L 0.33 1 06/02/22 21:35 56-23-5 M1 Chlorobenzene 2.0 ug/L 0.28 1 06/02/22 21:35 108-90-7 M1 Chloroethane 6.4 ug/L 0.65 1 06/02/22 21:35 75-00-3 Chloroform 0.43 ug/L 0.43 1 06/02/22 21:35 67-66-3 M1 Chloromethane <0.54 ug/L 0.54 1 06/02/22 21:35 74-87-3 M1,v2 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 06/02/22 21:35 96-12-8 M1 Dibromochloromethane <0.36 ug/L 0.36 1 06/02/22 21:35 124-48-1 M1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 06/02/22 21:35 106-93-4 M1 Dibromomethane <0.39 ug/L 0.39 1 06/02/22 21:35 74-95-3 M1 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 06/02/22 21:35 95-50-1 M1 1,4-Dichlorobenzene 1.8 ug/L 0.33 1 06/02/22 21:35 106-46-7 M1 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 06/02/22 21:35 110-57-6 1,1-Dichloroethane 47.9 ug/L 0.37 1 06/02/22 21:35 75-34-3 M1 1,2-Dichloroethane 0.32 ug/L 0.32 1 06/02/22 21:35 107-06-2 M1 1,1-Dichloroethene 1.0 ug/L 0.35 1 06/02/22 21:35 75-35-4 M1 cis-1,2-Dichloroethene 5.3 ug/L 0.38 1 06/02/22 21:35 156-59-2 M1 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 06/02/22 21:35 156-60-5 M1 1,2-Dichloropropane <0.36 ug/L 0.36 1 06/02/22 21:35 78-87-5 M1 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 21:35 10061-01-5 M1 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 21:35 10061-02-6 M1 Ethylbenzene <0.30 ug/L 0.30 1 06/02/22 21:35 100-41-4 M1 2-Hexanone <0.48 ug/L 0.48 1 06/02/22 21:35 591-78-6 M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01 /2022 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-MW-1 Lab ID: 92607341001 Collected: 05/27/22 11:50 Received: 06/01/22 13:15 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte lodomethane <9.7 ug/L 9.7 1 06/02/22 21:35 74-88-4 Methylene Chloride 14.6 ug/L 2.0 1 06/02/22 21:35 75-09-2 M1 4-Methyl-2-pentanone (MIBK) <2.7 ug/L 2.7 1 06/02/22 21:35 108-10-1 M1 Styrene <0.29 ug/L 0.29 1 06/02/22 21:35 100-42-5 M1 1,1,1,2-Tetrachloroethane <0.31 ug/L 0.31 1 06/02/22 21:35 630-20-6 M1 1,1,2,2-Tetrachloroethane <0.22 ug/L 0.22 1 06/02/22 21:35 79-34-5 M1 Tetrachloroethene <0.29 ug/L 0.29 1 06/02/22 21:35 127-18-4 M1 Toluene <0.48 ug/L 0.48 1 06/02/22 21:35 108-88-3 1,1,1-Trichloroethane <0.33 ug/L 0.33 1 06/02/22 21:35 71-55-6 M1 1,1,2-Trichloroethane <0.32 ug/L 0.32 1 06/02/22 21:35 79-00-5 M1 Trichloroethene 0.38 ug/L 0.38 1 06/02/22 21:35 79-01-6 M1 Trichlorofluoromethane <0.30 ug/L 0.30 1 06/02/22 21:35 75-69-4 1,2,3-Trichloropropane <0.26 ug/L 0.26 1 06/02/22 21:35 96-18-4 M1 Vinyl acetate <1.3 ug/L 1.3 1 06/02/22 21:35 108-05-4 Vinyl chloride <0.39 ug/L 0.39 1 06/02/22 21:35 75-01-4 M1 Xylene (Total) 3.7 ug/L 0.34 1 06/02/22 21:35 1330-20-7 MS m&p-Xylene <0.71 ug/L 0.71 1 06/02/22 21:35 179601-23-1 o-Xylene 3.7 ug/L 0.34 1 06/02/22 21:35 95-47-6 M1 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 06/02/22 21:35 460-00-4 1,2-Dichloroethane-d4 (S) 101 % 70-130 1 06/02/22 21:35 17060-07-0 Toluene-d8 (S) 102 % 70-130 1 06/02/22 21:35 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) 0.86 ug/L 0.86 1 06/02/22 16:41 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 06/02/22 16:41 17060-07-0 Toluene-d8 (S) 90 % 70-130 1 06/02/22 16:41 2037-26-5 Date: 07/01 /2022 06:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-MW-2A Parameters ANALYTICAL RESULTS Lab ID: 92607341002 Collected: 05/27/22 15:25 Received: 06/01/22 13:15 Matrix: Water Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic 19.1 ug/L 4.7 1 06/28/2216:16 06/29/2219:08 7440-38-2 Barium 207 ug/L 3.5 1 06/28/2216:16 06/29/2219:08 7440-39-3 Cadmium 0.40 ug/L 0.40 1 06/28/2216:16 06/29/2219:08 7440-43-9 Chromium 22.0 ug/L 3.7 1 06/28/2216:16 06/29/2219:08 7440-47-3 Lead 5.5 ug/L 4.5 1 06/28/2216:16 06/29/2219:08 7439-92-1 Selenium <4.7 ug/L 4.7 1 06/28/2216:16 06/29/2219:08 7782-49-2 Silver <2.5 ug/L 2.5 1 06/28/2216:16 06/29/2219:08 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury <0.12 ug/L 0.12 1 06/14/2214:15 06/20/2212:05 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 06/02/22 21:53 67-64-1 Acrylonitrile <1.8 ug/L 1.8 1 06/02/22 21:53 107-13-1 Benzene 0.34 ug/L 0.34 1 06/02/22 21:53 71-43-2 Bromochloromethane <0.47 ug/L 0.47 1 06/02/22 21:53 74-97-5 Bromodichloromethane <0.31 ug/L 0.31 1 06/02/22 21:53 75-27-4 Bromoform <0.34 ug/L 0.34 1 06/02/22 21:53 75-25-2 Bromomethane <1.7 ug/L 1.7 1 06/02/22 21:53 74-83-9 2-Butanone (MEK) <4.0 ug/L 4.0 1 06/02/22 21:53 78-93-3 Carbon disulfide <0.36 ug/L 0.36 1 06/02/22 21:53 75-15-0 Carbon tetrachloride <0.33 ug/L 0.33 1 06/02/22 21:53 56-23-5 Chlorobenzene 5.0 ug/L 0.28 1 06/02/22 21:53 108-90-7 Chloroethane <0.65 ug/L 0.65 1 06/02/22 21:53 75-00-3 Chloroform <0.43 ug/L 0.43 1 06/02/22 21:53 67-66-3 Chloromethane <0.54 ug/L 0.54 1 06/02/22 21:53 74-87-3 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 06/02/22 21:53 96-12-8 Dibromochloromethane <0.36 ug/L 0.36 1 06/02/22 21:53 124-48-1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 06/02/22 21:53 106-93-4 Dibromomethane <0.39 ug/L 0.39 1 06/02/22 21:53 74-95-3 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 06/02/22 21:53 95-50-1 1,4-Dichlorobenzene 2.0 ug/L 0.33 1 06/02/22 21:53 106-46-7 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 06/02/22 21:53 110-57-6 1,1-Dichloroethane 0.37 ug/L 0.37 1 06/02/22 21:53 75-34-3 1,2-Dichloroethane <0.32 ug/L 0.32 1 06/02/22 21:53 107-06-2 1,1-Dichloroethene <0.35 ug/L 0.35 1 06/02/22 21:53 75-35-4 cis-1,2-Dichloroethene 0.38 ug/L 0.38 1 06/02/22 21:53 156-59-2 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 06/02/22 21:53 156-60-5 1,2-Dichloropropane <0.36 ug/L 0.36 1 06/02/22 21:53 78-87-5 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 21:53 10061-01-5 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 21:53 10061-02-6 Ethylbenzene <0.30 ug/L 0.30 1 06/02/22 21:53 100-41-4 2-Hexanone <0.48 ug/L 0.48 1 06/02/22 21:53 591-78-6 REPORT OF LABORATORY ANALYSIS v2 L2 v2 This report shall not be reproduced, except in full, Date: 07/01 /2022 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-MW-2A Lab ID: 92607341002 Collected: 05/27/22 15:25 Received: 06/01/22 13:15 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte lodomethane <9.7 ug/L 9.7 1 06/02/22 21:53 74-88-4 Methylene Chloride <2.0 ug/L 2.0 1 06/02/22 21:53 75-09-2 4-Methyl-2-pentanone (MIBK) <2.7 ug/L 2.7 1 06/02/22 21:53 108-10-1 Styrene <0.29 ug/L 0.29 1 06/02/22 21:53 100-42-5 1,1,1,2-Tetrachloroethane <0.31 ug/L 0.31 1 06/02/22 21:53 630-20-6 1,1,2,2-Tetrachloroethane <0.22 ug/L 0.22 1 06/02/22 21:53 79-34-5 Tetrachloroethene <0.29 ug/L 0.29 1 06/02/22 21:53 127-18-4 Toluene <0.48 ug/L 0.48 1 06/02/22 21:53 108-88-3 1,1,1-Trichloroethane <0.33 ug/L 0.33 1 06/02/22 21:53 71-55-6 1,1,2-Trichloroethane <0.32 ug/L 0.32 1 06/02/22 21:53 79-00-5 Trichloroethene <0.38 ug/L 0.38 1 06/02/22 21:53 79-01-6 Trichlorofluoromethane <0.30 ug/L 0.30 1 06/02/22 21:53 75-69-4 1,2,3-Trichloropropane <0.26 ug/L 0.26 1 06/02/22 21:53 96-18-4 Vinyl acetate <1.3 ug/L 1.3 1 06/02/22 21:53 108-05-4 Vinyl chloride <0.39 ug/L 0.39 1 06/02/22 21:53 75-01-4 Xylene (Total) <0.34 ug/L 0.34 1 06/02/22 21:53 1330-20-7 m&p-Xylene <0.71 ug/L 0.71 1 06/02/22 21:53 179601-23-1 o-Xylene <0.34 ug/L 0.34 1 06/02/22 21:53 95-47-6 Surrogates 4-Bromofluorobenzene (S) 97 % 70-130 1 06/02/22 21:53 460-00-4 1,2-Dichloroethane-d4 (S) 106 % 70-130 1 06/02/22 21:53 17060-07-0 Toluene-d8(S) 103 % 70-130 1 06/02/22 21:53 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) 13.0 ug/L 0.86 1 06/02/22 17:00 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 91 % 70-130 1 06/02/22 17:00 17060-07-0 Toluene-d8 (S) 87 % 70-130 1 06/02/22 17:00 2037-26-5 Date: 07/01 /2022 06:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-MW-4A Parameters ANALYTICAL RESULTS Lab ID: 92607341003 Collected: 05/27/22 14:00 Received: 06/01/22 13:15 Matrix: Water Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic 4.7 ug/L 4.7 1 06/28/2216:16 06/29/2219:12 7440-38-2 Barium 199 ug/L 3.5 1 06/28/2216:16 06/29/2219:12 7440-39-3 Cadmium 1.1 ug/L 0.40 1 06/28/2216:16 06/29/2219:12 7440-43-9 Chromium 74.3 ug/L 3.7 1 06/28/2216:16 06/29/2219:12 7440-47-3 Lead 16.6 ug/L 4.5 1 06/28/2216:16 06/29/2219:12 7439-92-1 Selenium <4.7 ug/L 4.7 1 06/28/2216:16 06/29/2219:12 7782-49-2 Silver <2.5 ug/L 2.5 1 06/28/2216:16 06/29/2219:12 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury 0.23 ug/L 0.12 1 06/14/2214:15 06/20/2212:07 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 06/02/22 19:45 67-64-1 Acrylonitrile <1.8 ug/L 1.8 1 06/02/22 19:45 107-13-1 Benzene <0.34 ug/L 0.34 1 06/02/22 19:45 71-43-2 Bromochloromethane <0.47 ug/L 0.47 1 06/02/22 19:45 74-97-5 Bromodichloromethane <0.31 ug/L 0.31 1 06/02/22 19:45 75-27-4 Bromoform <0.34 ug/L 0.34 1 06/02/22 19:45 75-25-2 Bromomethane <1.7 ug/L 1.7 1 06/02/22 19:45 74-83-9 2-Butanone (MEK) <4.0 ug/L 4.0 1 06/02/22 19:45 78-93-3 Carbon disulfide <0.36 ug/L 0.36 1 06/02/22 19:45 75-15-0 Carbon tetrachloride <0.33 ug/L 0.33 1 06/02/22 19:45 56-23-5 Chlorobenzene <0.28 ug/L 0.28 1 06/02/22 19:45 108-90-7 Chloroethane <0.65 ug/L 0.65 1 06/02/22 19:45 75-00-3 Chloroform <0.43 ug/L 0.43 1 06/02/22 19:45 67-66-3 Chloromethane <0.54 ug/L 0.54 1 06/02/22 19:45 74-87-3 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 06/02/22 19:45 96-12-8 Dibromochloromethane <0.36 ug/L 0.36 1 06/02/22 19:45 124-48-1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 06/02/22 19:45 106-93-4 Dibromomethane <0.39 ug/L 0.39 1 06/02/22 19:45 74-95-3 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 06/02/22 19:45 95-50-1 1,4-Dichlorobenzene <0.33 ug/L 0.33 1 06/02/22 19:45 106-46-7 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 06/02/22 19:45 110-57-6 1,1-Dichloroethane <0.37 ug/L 0.37 1 06/02/22 19:45 75-34-3 1,2-Dichloroethane <0.32 ug/L 0.32 1 06/02/22 19:45 107-06-2 1,1-Dichloroethene <0.35 ug/L 0.35 1 06/02/22 19:45 75-35-4 cis-1,2-Dichloroethene <0.38 ug/L 0.38 1 06/02/22 19:45 156-59-2 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 06/02/22 19:45 156-60-5 1,2-Dichloropropane <0.36 ug/L 0.36 1 06/02/22 19:45 78-87-5 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 19:45 10061-01-5 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 19:45 10061-02-6 Ethylbenzene <0.30 ug/L 0.30 1 06/02/22 19:45 100-41-4 2-Hexanone <0.48 ug/L 0.48 1 06/02/22 19:45 591-78-6 REPORT OF LABORATORY ANALYSIS v2 L2 v2 This report shall not be reproduced, except in full, Date: 07/01 /2022 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-MW-4A Lab ID: 92607341003 Collected: 05/27/22 14:00 Received: 06/01/22 13:15 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/01 /2022 06:14 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte <9.7 ug/L <2.0 ug/L <2.7 ug/L <0.29 ug/L <0.31 ug/L <0.22 ug/L <0.29 ug/L <0.48 ug/L <0.33 ug/L <0.32 ug/L <0.38 ug/L <0.30 ug/L <0.26 ug/L <1.3 ug/L <0.39 ug/L <0.34 ug/L <0.71 ug/L <0.34 ug/L 99 % 97 % 101 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte <0.86 ug/L 95 % 86 % 9.7 1 06/02/22 19:45 74-88-4 2.0 1 06/02/22 19:45 75-09-2 2.7 1 06/02/22 19:45 108-10-1 0.29 1 06/02/22 19:45 100-42-5 0.31 1 06/02/22 19:45 630-20-6 0.22 1 06/02/22 19:45 79-34-5 0.29 1 06/02/22 19:45 127-18-4 0.48 1 06/02/22 19:45 108-88-3 0.33 1 06/02/22 19:45 71-55-6 0.32 1 06/02/22 19:45 79-00-5 0.38 1 06/02/22 19:45 79-01-6 0.30 1 06/02/22 19:45 75-69-4 0.26 1 06/02/22 19:45 96-18-4 1.3 1 06/02/22 19:45 108-05-4 0.39 1 06/02/22 19:45 75-01-4 0.34 1 06/02/22 19:45 1330-20-7 0.71 1 06/02/22 19:45 179601-23-1 0.34 1 06/02/22 19:45 95-47-6 70-130 1 70-130 1 70-130 1 [e1E:I:i 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 06/02/22 19:45 460-00-4 06/02/22 19:45 17060-07-0 06/02/22 19:45 2037-26-5 06/02/22 17:19 17060-07-0 06/02/2217:19 2037-26-5 Page 10 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-MW-5 Parameters ANALYTICAL RESULTS Lab ID: 92607341004 Collected: 05/27/22 09:55 Received: 06/01/22 13:15 Matrix: Water Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic 4.7 ug/L 4.7 1 06/28/2216:16 06/30/2217:07 7440-38-2 Barium 163 ug/L 3.5 1 06/28/2216:16 06/30/2217:07 7440-39-3 Cadmium 0.40 ug/L 0.40 1 06/28/2216:16 06/30/2217:07 7440-43-9 Chromium 3.7 ug/L 3.7 1 06/28/2216:16 06/30/2217:07 7440-47-3 Lead <4.5 ug/L 4.5 1 06/28/2216:16 06/30/2217:07 7439-92-1 Selenium <4.7 ug/L 4.7 1 06/28/2216:16 06/30/2217:07 7782-49-2 Silver <2.5 ug/L 2.5 1 06/28/2216:16 06/30/2217:07 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury <0.12 ug/L 0.12 1 06/14/2214:15 06/20/2212:14 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 06/02/22 22:11 67-64-1 Acrylonitrile <1.8 ug/L 1.8 1 06/02/22 22:11 107-13-1 Benzene 0.34 ug/L 0.34 1 06/02/22 22:11 71-43-2 Bromochloromethane <0.47 ug/L 0.47 1 06/02/22 22:11 74-97-5 Bromodichloromethane <0.31 ug/L 0.31 1 06/02/22 22:11 75-27-4 Bromoform <0.34 ug/L 0.34 1 06/02/22 22:11 75-25-2 Bromomethane <1.7 ug/L 1.7 1 06/02/22 22:11 74-83-9 2-Butanone (MEK) <4.0 ug/L 4.0 1 06/02/22 22:11 78-93-3 Carbon disulfide 0.36 ug/L 0.36 1 06/02/22 22:11 75-15-0 Carbon tetrachloride <0.33 ug/L 0.33 1 06/02/22 22:11 56-23-5 Chlorobenzene 1.6 ug/L 0.28 1 06/02/22 22:11 108-90-7 Chloroethane 1.4 ug/L 0.65 1 06/02/22 22:11 75-00-3 Chloroform <0.43 ug/L 0.43 1 06/02/22 22:11 67-66-3 Chloromethane <0.54 ug/L 0.54 1 06/02/22 22:11 74-87-3 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 06/02/22 22:11 96-12-8 Dibromochloromethane <0.36 ug/L 0.36 1 06/02/22 22:11 124-48-1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 06/02/22 22:11 106-93-4 Dibromomethane <0.39 ug/L 0.39 1 06/02/22 22:11 74-95-3 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 06/02/22 22:11 95-50-1 1,4-Dichlorobenzene 2.1 ug/L 0.33 1 06/02/22 22:11 106-46-7 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 06/02/22 22:11 110-57-6 1,1-Dichloroethane 2.7 ug/L 0.37 1 06/02/22 22:11 75-34-3 1,2-Dichloroethane <0.32 ug/L 0.32 1 06/02/22 22:11 107-06-2 1,1-Dichloroethene <0.35 ug/L 0.35 1 06/02/22 22:11 75-35-4 cis-1,2-Dichloroethene 6.9 ug/L 0.38 1 06/02/22 22:11 156-59-2 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 06/02/22 22:11 156-60-5 1,2-Dichloropropane <0.36 ug/L 0.36 1 06/02/22 22:11 78-87-5 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 22:11 10061-01-5 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 22:11 10061-02-6 Ethylbenzene <0.30 ug/L 0.30 1 06/02/22 22:11 100-41-4 2-Hexanone <0.48 ug/L 0.48 1 06/02/22 22:11 591-78-6 REPORT OF LABORATORY ANALYSIS v2 L2 v2 This report shall not be reproduced, except in full, Date: 07/01 /2022 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-MW-5 Lab ID: 92607341004 Collected: 05/27/22 09:55 Received: 06/01/22 13:15 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/01 /2022 06:14 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte <9.7 ug/L <2.0 ug/L <2.7 ug/L <0.29 ug/L <0.31 ug/L <0.22 ug/L <0.29 ug/L <0.48 ug/L <0.33 ug/L <0.32 ug/L <0.38 ug/L <0.30 ug/L <0.26 ug/L <1.3 ug/L 0.39 ug/L <0.34 ug/L <0.71 ug/L <0.34 ug/L 98 % 100 % 105 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 21.3 ug/L 91 % 89 % 9.7 1 06/02/22 22:11 74-88-4 2.0 1 06/02/22 22:11 75-09-2 2.7 1 06/02/22 22:11 108-10-1 0.29 1 06/02/22 22:11 100-42-5 0.31 1 06/02/22 22:11 630-20-6 0.22 1 06/02/22 22:11 79-34-5 0.29 1 06/02/22 22:11 127-18-4 0.48 1 06/02/22 22:11 108-88-3 0.33 1 06/02/22 22:11 71-55-6 0.32 1 06/02/22 22:11 79-00-5 0.38 1 06/02/22 22:11 79-01-6 0.30 1 06/02/22 22:11 75-69-4 0.26 1 06/02/22 22:11 96-18-4 1.3 1 06/02/22 22:11 108-05-4 0.39 1 06/02/22 22:11 75-01-4 0.34 1 06/02/22 22:11 1330-20-7 0.71 1 06/02/22 22:11 179601-23-1 0.34 1 06/02/22 22:11 95-47-6 70-130 1 70-130 1 70-130 1 [e1E:I:i 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 06/02/22 22:11 460-00-4 06/02/22 22:11 17060-07-0 06/02/22 22:11 2037-26-5 [eIyLeYaf�l►�i r1 Ec�Zi N�c�;S Qi 06/02/22 17:39 17060-07-0 06/02/2217:39 2037-26-5 Page 12 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-MW-6 Parameters ANALYTICAL RESULTS Lab ID: 92607341005 Collected: 05/27/22 13:45 Received: 06/01/22 13:15 Matrix: Water Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic <4.7 ug/L 4.7 1 06/28/2216:16 06/30/2217:10 7440-38-2 Barium 65.0 ug/L 3.5 1 06/28/2216:16 06/30/2217:10 7440-39-3 Cadmium 0.40 ug/L 0.40 1 06/28/2216:16 06/30/2217:10 7440-43-9 Chromium <3.7 ug/L 3.7 1 06/28/2216:16 06/30/2217:10 7440-47-3 Lead <4.5 ug/L 4.5 1 06/28/2216:16 06/30/2217:10 7439-92-1 Selenium <4.7 ug/L 4.7 1 06/28/2216:16 06/30/2217:10 7782-49-2 Silver <2.5 ug/L 2.5 1 06/28/2216:16 06/30/2217:10 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury <0.12 ug/L 0.12 1 06/14/2214:15 06/20/2212:16 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 06/02/22 22:30 67-64-1 Acrylonitrile <1.8 ug/L 1.8 1 06/02/22 22:30 107-13-1 Benzene 1.2 ug/L 0.34 1 06/02/22 22:30 71-43-2 Bromochloromethane <0.47 ug/L 0.47 1 06/02/22 22:30 74-97-5 Bromodichloromethane <0.31 ug/L 0.31 1 06/02/22 22:30 75-27-4 Bromoform <0.34 ug/L 0.34 1 06/02/22 22:30 75-25-2 Bromomethane <1.7 ug/L 1.7 1 06/02/22 22:30 74-83-9 2-Butanone (MEK) <4.0 ug/L 4.0 1 06/02/22 22:30 78-93-3 Carbon disulfide 0.36 ug/L 0.36 1 06/02/22 22:30 75-15-0 Carbon tetrachloride <0.33 ug/L 0.33 1 06/02/22 22:30 56-23-5 Chlorobenzene 2.5 ug/L 0.28 1 06/02/22 22:30 108-90-7 Chloroethane <0.65 ug/L 0.65 1 06/02/22 22:30 75-00-3 Chloroform <0.43 ug/L 0.43 1 06/02/22 22:30 67-66-3 Chloromethane <0.54 ug/L 0.54 1 06/02/22 22:30 74-87-3 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 06/02/22 22:30 96-12-8 Dibromochloromethane <0.36 ug/L 0.36 1 06/02/22 22:30 124-48-1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 06/02/22 22:30 106-93-4 Dibromomethane <0.39 ug/L 0.39 1 06/02/22 22:30 74-95-3 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 06/02/22 22:30 95-50-1 1,4-Dichlorobenzene 1.5 ug/L 0.33 1 06/02/22 22:30 106-46-7 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 06/02/22 22:30 110-57-6 1,1-Dichloroethane 0.37 ug/L 0.37 1 06/02/22 22:30 75-34-3 1,2-Dichloroethane <0.32 ug/L 0.32 1 06/02/22 22:30 107-06-2 1,1-Dichloroethene <0.35 ug/L 0.35 1 06/02/22 22:30 75-35-4 cis-1,2-Dichloroethene 1.6 ug/L 0.38 1 06/02/22 22:30 156-59-2 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 06/02/22 22:30 156-60-5 1,2-Dichloropropane <0.36 ug/L 0.36 1 06/02/22 22:30 78-87-5 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 22:30 10061-01-5 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 22:30 10061-02-6 Ethylbenzene <0.30 ug/L 0.30 1 06/02/22 22:30 100-41-4 2-Hexanone <0.48 ug/L 0.48 1 06/02/22 22:30 591-78-6 REPORT OF LABORATORY ANALYSIS v2 L2 v2 This report shall not be reproduced, except in full, Date: 07/01 /2022 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-MW-6 Lab ID: 92607341005 Collected: 05/27/22 13:45 Received: 06/01/22 13:15 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/01 /2022 06:14 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte <9.7 ug/L <2.0 ug/L <2.7 ug/L <0.29 ug/L <0.31 ug/L <0.22 ug/L <0.29 ug/L <0.48 ug/L <0.33 ug/L <0.32 ug/L <0.38 ug/L <0.30 ug/L <0.26 ug/L <1.3 ug/L <0.39 ug/L <0.34 ug/L <0.71 ug/L <0.34 ug/L 99 % 103 % 103 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 37.7 ug/L 96 % 86 % 9.7 1 06/02/22 22:30 74-88-4 2.0 1 06/02/22 22:30 75-09-2 2.7 1 06/02/22 22:30 108-10-1 0.29 1 06/02/22 22:30 100-42-5 0.31 1 06/02/22 22:30 630-20-6 0.22 1 06/02/22 22:30 79-34-5 0.29 1 06/02/22 22:30 127-18-4 0.48 1 06/02/22 22:30 108-88-3 0.33 1 06/02/22 22:30 71-55-6 0.32 1 06/02/22 22:30 79-00-5 0.38 1 06/02/22 22:30 79-01-6 0.30 1 06/02/22 22:30 75-69-4 0.26 1 06/02/22 22:30 96-18-4 1.3 1 06/02/22 22:30 108-05-4 0.39 1 06/02/22 22:30 75-01-4 0.34 1 06/02/22 22:30 1330-20-7 0.71 1 06/02/22 22:30 179601-23-1 0.34 1 06/02/22 22:30 95-47-6 70-130 1 70-130 1 70-130 1 [e1E:I:i 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 06/02/22 22:30 460-00-4 06/02/22 22:30 17060-07-0 06/02/22 22:30 2037-26-5 06/02/22 17:58 17060-07-0 06/02/2217:58 2037-26-5 Page 14 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-MW-7 Parameters ANALYTICAL RESULTS Lab ID: 92607341006 Collected: 05/27/22 13:00 Received: 06/01/22 13:15 Matrix: Water Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic <4.7 ug/L 4.7 1 06/28/2216:16 06/29/2219:41 7440-38-2 Barium 123 ug/L 3.5 1 06/28/2216:16 06/29/2219:41 7440-39-3 Cadmium 0.40 ug/L 0.40 1 06/28/2216:16 06/29/2219:41 7440-43-9 Chromium 38.4 ug/L 3.7 1 06/28/2216:16 06/29/2219:41 7440-47-3 Lead 11.4 ug/L 4.5 1 06/28/2216:16 06/29/2219:41 7439-92-1 Selenium <4.7 ug/L 4.7 1 06/28/2216:16 06/29/2219:41 7782-49-2 Silver <2.5 ug/L 2.5 1 06/28/2216:16 06/29/2219:41 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury 0.53 ug/L 0.12 1 06/14/2214:15 06/20/2212:18 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 06/02/22 22:48 67-64-1 Acrylonitrile <1.8 ug/L 1.8 1 06/02/22 22:48 107-13-1 Benzene <0.34 ug/L 0.34 1 06/02/22 22:48 71-43-2 Bromochloromethane <0.47 ug/L 0.47 1 06/02/22 22:48 74-97-5 Bromodichloromethane <0.31 ug/L 0.31 1 06/02/22 22:48 75-27-4 Bromoform <0.34 ug/L 0.34 1 06/02/22 22:48 75-25-2 Bromomethane <1.7 ug/L 1.7 1 06/02/22 22:48 74-83-9 2-Butanone (MEK) <4.0 ug/L 4.0 1 06/02/22 22:48 78-93-3 Carbon disulfide <0.36 ug/L 0.36 1 06/02/22 22:48 75-15-0 Carbon tetrachloride <0.33 ug/L 0.33 1 06/02/22 22:48 56-23-5 Chlorobenzene 0.28 ug/L 0.28 1 06/02/22 22:48 108-90-7 Chloroethane <0.65 ug/L 0.65 1 06/02/22 22:48 75-00-3 Chloroform <0.43 ug/L 0.43 1 06/02/22 22:48 67-66-3 Chloromethane <0.54 ug/L 0.54 1 06/02/22 22:48 74-87-3 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 06/02/22 22:48 96-12-8 Dibromochloromethane <0.36 ug/L 0.36 1 06/02/22 22:48 124-48-1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 06/02/22 22:48 106-93-4 Dibromomethane <0.39 ug/L 0.39 1 06/02/22 22:48 74-95-3 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 06/02/22 22:48 95-50-1 1,4-Dichlorobenzene 0.33 ug/L 0.33 1 06/02/22 22:48 106-46-7 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 06/02/22 22:48 110-57-6 1,1-Dichloroethane <0.37 ug/L 0.37 1 06/02/22 22:48 75-34-3 1,2-Dichloroethane <0.32 ug/L 0.32 1 06/02/22 22:48 107-06-2 1,1-Dichloroethene <0.35 ug/L 0.35 1 06/02/22 22:48 75-35-4 cis-1,2-Dichloroethene <0.38 ug/L 0.38 1 06/02/22 22:48 156-59-2 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 06/02/22 22:48 156-60-5 1,2-Dichloropropane <0.36 ug/L 0.36 1 06/02/22 22:48 78-87-5 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 22:48 10061-01-5 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 22:48 10061-02-6 Ethylbenzene <0.30 ug/L 0.30 1 06/02/22 22:48 100-41-4 2-Hexanone <0.48 ug/L 0.48 1 06/02/22 22:48 591-78-6 REPORT OF LABORATORY ANALYSIS v2 L2 v2 This report shall not be reproduced, except in full, Date: 07/01 /2022 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-MW-7 Lab ID: 92607341006 Collected: 05/27/22 13:00 Received: 06/01/22 13:15 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/01 /2022 06:14 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte <9.7 ug/L <2.0 ug/L <2.7 ug/L <0.29 ug/L <0.31 ug/L <0.22 ug/L <0.29 ug/L <0.48 ug/L <0.33 ug/L <0.32 ug/L <0.38 ug/L <0.30 ug/L <0.26 ug/L <1.3 ug/L <0.39 ug/L <0.34 ug/L <0.71 ug/L <0.34 ug/L 98 % 101 % 103 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 5.0 ug/L 92 % 88 % 9.7 1 06/02/22 22:48 74-88-4 2.0 1 06/02/22 22:48 75-09-2 2.7 1 06/02/22 22:48 108-10-1 0.29 1 06/02/22 22:48 100-42-5 0.31 1 06/02/22 22:48 630-20-6 0.22 1 06/02/22 22:48 79-34-5 0.29 1 06/02/22 22:48 127-18-4 0.48 1 06/02/22 22:48 108-88-3 0.33 1 06/02/22 22:48 71-55-6 0.32 1 06/02/22 22:48 79-00-5 0.38 1 06/02/22 22:48 79-01-6 0.30 1 06/02/22 22:48 75-69-4 0.26 1 06/02/22 22:48 96-18-4 1.3 1 06/02/22 22:48 108-05-4 0.39 1 06/02/22 22:48 75-01-4 0.34 1 06/02/22 22:48 1330-20-7 0.71 1 06/02/22 22:48 179601-23-1 0.34 1 06/02/22 22:48 95-47-6 70-130 1 70-130 1 70-130 1 [e1E:I:i 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 06/02/22 22:48 460-00-4 06/02/22 22:48 17060-07-0 06/02/22 22:48 2037-26-5 [eI:ILeYaf ���i E 3 fi �ti f ��c� ;S Qi 06/02/22 18:17 17060-07-0 06/02/2218:17 2037-26-5 Page 16 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-MW-8 Parameters ANALYTICAL RESULTS Lab ID: 92607341007 Collected: 05/27/22 11:50 Received: 06/01/22 13:15 Matrix: Water Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic <4.7 ug/L 4.7 1 06/28/2216:16 06/29/2219:51 7440-38-2 Barium 335 ug/L 3.5 1 06/28/2216:16 06/29/2219:51 7440-39-3 Cadmium 0.40 ug/L 0.40 1 06/28/2216:16 06/29/2219:51 7440-43-9 Chromium 9.1 ug/L 3.7 1 06/28/2216:16 06/29/2219:51 7440-47-3 Lead 19.3 ug/L 4.5 1 06/28/2216:16 06/29/2219:51 7439-92-1 Selenium <4.7 ug/L 4.7 1 06/28/2216:16 06/29/2219:51 7782-49-2 Silver <2.5 ug/L 2.5 1 06/28/2216:16 06/29/2219:51 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury 4.0 ug/L 0.61 5 06/14/2214:15 06/20/2212:43 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 06/02/22 20:04 67-64-1 Acrylonitrile <1.8 ug/L 1.8 1 06/02/22 20:04 107-13-1 Benzene <0.34 ug/L 0.34 1 06/02/22 20:04 71-43-2 Bromochloromethane <0.47 ug/L 0.47 1 06/02/22 20:04 74-97-5 Bromodichloromethane <0.31 ug/L 0.31 1 06/02/22 20:04 75-27-4 Bromoform <0.34 ug/L 0.34 1 06/02/22 20:04 75-25-2 Bromomethane <1.7 ug/L 1.7 1 06/02/22 20:04 74-83-9 2-Butanone (MEK) <4.0 ug/L 4.0 1 06/02/22 20:04 78-93-3 Carbon disulfide <0.36 ug/L 0.36 1 06/02/22 20:04 75-15-0 Carbon tetrachloride <0.33 ug/L 0.33 1 06/02/22 20:04 56-23-5 Chlorobenzene <0.28 ug/L 0.28 1 06/02/22 20:04 108-90-7 Chloroethane <0.65 ug/L 0.65 1 06/02/22 20:04 75-00-3 Chloroform <0.43 ug/L 0.43 1 06/02/22 20:04 67-66-3 Chloromethane <0.54 ug/L 0.54 1 06/02/22 20:04 74-87-3 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 06/02/22 20:04 96-12-8 Dibromochloromethane <0.36 ug/L 0.36 1 06/02/22 20:04 124-48-1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 06/02/22 20:04 106-93-4 Dibromomethane <0.39 ug/L 0.39 1 06/02/22 20:04 74-95-3 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 06/02/22 20:04 95-50-1 1,4-Dichlorobenzene <0.33 ug/L 0.33 1 06/02/22 20:04 106-46-7 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 06/02/22 20:04 110-57-6 1,1-Dichloroethane 4.9 ug/L 0.37 1 06/02/22 20:04 75-34-3 1,2-Dichloroethane <0.32 ug/L 0.32 1 06/02/22 20:04 107-06-2 1,1-Dichloroethene <0.35 ug/L 0.35 1 06/02/22 20:04 75-35-4 cis-1,2-Dichloroethene <0.38 ug/L 0.38 1 06/02/22 20:04 156-59-2 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 06/02/22 20:04 156-60-5 1,2-Dichloropropane <0.36 ug/L 0.36 1 06/02/22 20:04 78-87-5 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 20:04 10061-01-5 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 20:04 10061-02-6 Ethylbenzene <0.30 ug/L 0.30 1 06/02/22 20:04 100-41-4 2-Hexanone <0.48 ug/L 0.48 1 06/02/22 20:04 591-78-6 REPORT OF LABORATORY ANALYSIS v2 L2 v2 This report shall not be reproduced, except in full, Date: 07/01 /2022 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-MW-8 Lab ID: 92607341007 Collected: 05/27/22 11:50 Received: 06/01/22 13:15 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/01 /2022 06:14 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte <9.7 ug/L <2.0 ug/L <2.7 ug/L <0.29 ug/L <0.31 ug/L <0.22 ug/L <0.29 ug/L <0.48 ug/L <0.33 ug/L <0.32 ug/L <0.38 ug/L <0.30 ug/L <0.26 ug/L <1.3 ug/L <0.39 ug/L <0.34 ug/L <0.71 ug/L <0.34 ug/L 99 % 98 % 101 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte <0.86 ug/L 100 % 91 % 9.7 1 06/02/22 20:04 74-88-4 2.0 1 06/02/22 20:04 75-09-2 2.7 1 06/02/22 20:04 108-10-1 0.29 1 06/02/22 20:04 100-42-5 0.31 1 06/02/22 20:04 630-20-6 0.22 1 06/02/22 20:04 79-34-5 0.29 1 06/02/22 20:04 127-18-4 0.48 1 06/02/22 20:04 108-88-3 0.33 1 06/02/22 20:04 71-55-6 0.32 1 06/02/22 20:04 79-00-5 0.38 1 06/02/22 20:04 79-01-6 0.30 1 06/02/22 20:04 75-69-4 0.26 1 06/02/22 20:04 96-18-4 1.3 1 06/02/22 20:04 108-05-4 0.39 1 06/02/22 20:04 75-01-4 0.34 1 06/02/22 20:04 1330-20-7 0.71 1 06/02/22 20:04 179601-23-1 0.34 1 06/02/22 20:04 95-47-6 70-130 1 70-130 1 70-130 1 [e1E:I:i 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 06/02/22 20:04 460-00-4 06/02/22 20:04 17060-07-0 06/02/22 20:04 2037-26-5 [eI:ILeYaf ���i E:3 Ec�ti f ��c� ;S Qi 06/02/22 18:37 17060-07-0 06/02/2218:37 2037-26-5 Page 18 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-MW-9S Parameters ANALYTICAL RESULTS Lab ID: 92607341008 Collected: 05/27/22 10:15 Received: 06/01/22 13:15 Matrix: Water Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic <4.7 ug/L 4.7 1 06/28/22 16:16 06/29/22 20:04 7440-38-2 Barium 59.9 ug/L 3.5 1 06/28/22 16:16 06/29/22 20:04 7440-39-3 Cadmium <0.40 ug/L 0.40 1 06/28/22 16:16 06/29/22 20:04 7440-43-9 Chromium <3.7 ug/L 3.7 1 06/28/22 16:16 06/29/22 20:04 7440-47-3 Lead <4.5 ug/L 4.5 1 06/28/22 16:16 06/29/22 20:04 7439-92-1 Selenium <4.7 ug/L 4.7 1 06/28/22 16:16 06/29/22 20:04 7782-49-2 Silver <2.5 ug/L 2.5 1 06/28/22 16:16 06/29/22 20:04 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury <0.12 ug/L 0.12 1 06/14/2214:15 06/20/2212:22 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 06/02/22 20:22 67-64-1 Acrylonitrile <1.8 ug/L 1.8 1 06/02/22 20:22 107-13-1 Benzene <0.34 ug/L 0.34 1 06/02/22 20:22 71-43-2 Bromochloromethane <0.47 ug/L 0.47 1 06/02/22 20:22 74-97-5 Bromodichloromethane <0.31 ug/L 0.31 1 06/02/22 20:22 75-27-4 Bromoform <0.34 ug/L 0.34 1 06/02/22 20:22 75-25-2 Bromomethane <1.7 ug/L 1.7 1 06/02/22 20:22 74-83-9 2-Butanone (MEK) <4.0 ug/L 4.0 1 06/02/22 20:22 78-93-3 Carbon disulfide <0.36 ug/L 0.36 1 06/02/22 20:22 75-15-0 Carbon tetrachloride <0.33 ug/L 0.33 1 06/02/22 20:22 56-23-5 Chlorobenzene <0.28 ug/L 0.28 1 06/02/22 20:22 108-90-7 Chloroethane <0.65 ug/L 0.65 1 06/02/22 20:22 75-00-3 Chloroform <0.43 ug/L 0.43 1 06/02/22 20:22 67-66-3 Chloromethane <0.54 ug/L 0.54 1 06/02/22 20:22 74-87-3 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 06/02/22 20:22 96-12-8 Dibromochloromethane <0.36 ug/L 0.36 1 06/02/22 20:22 124-48-1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 06/02/22 20:22 106-93-4 Dibromomethane <0.39 ug/L 0.39 1 06/02/22 20:22 74-95-3 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 06/02/22 20:22 95-50-1 1,4-Dichlorobenzene <0.33 ug/L 0.33 1 06/02/22 20:22 106-46-7 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 06/02/22 20:22 110-57-6 1,1-Dichloroethane <0.37 ug/L 0.37 1 06/02/22 20:22 75-34-3 1,2-Dichloroethane <0.32 ug/L 0.32 1 06/02/22 20:22 107-06-2 1,1-Dichloroethene <0.35 ug/L 0.35 1 06/02/22 20:22 75-35-4 cis-1,2-Dichloroethene <0.38 ug/L 0.38 1 06/02/22 20:22 156-59-2 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 06/02/22 20:22 156-60-5 1,2-Dichloropropane <0.36 ug/L 0.36 1 06/02/22 20:22 78-87-5 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 20:22 10061-01-5 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 20:22 10061-02-6 Ethylbenzene <0.30 ug/L 0.30 1 06/02/22 20:22 100-41-4 2-Hexanone <0.48 ug/L 0.48 1 06/02/22 20:22 591-78-6 REPORT OF LABORATORY ANALYSIS v2 L2 v2 This report shall not be reproduced, except in full, Date: 07/01 /2022 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-MW-9S Lab ID: 92607341008 Collected: 05/27/22 10:15 Received: 06/01/22 13:15 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/01 /2022 06:14 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte <9.7 ug/L <2.0 ug/L <2.7 ug/L <0.29 ug/L <0.31 ug/L <0.22 ug/L <0.29 ug/L <0.48 ug/L <0.33 ug/L <0.32 ug/L <0.38 ug/L <0.30 ug/L <0.26 ug/L <1.3 ug/L <0.39 ug/L <0.34 ug/L <0.71 ug/L <0.34 ug/L 98 % 99 % 102 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte <0.86 ug/L 95 % 89 % 9.7 1 06/02/22 20:22 74-88-4 2.0 1 06/02/22 20:22 75-09-2 2.7 1 06/02/22 20:22 108-10-1 0.29 1 06/02/22 20:22 100-42-5 0.31 1 06/02/22 20:22 630-20-6 0.22 1 06/02/22 20:22 79-34-5 0.29 1 06/02/22 20:22 127-18-4 0.48 1 06/02/22 20:22 108-88-3 0.33 1 06/02/22 20:22 71-55-6 0.32 1 06/02/22 20:22 79-00-5 0.38 1 06/02/22 20:22 79-01-6 0.30 1 06/02/22 20:22 75-69-4 0.26 1 06/02/22 20:22 96-18-4 1.3 1 06/02/22 20:22 108-05-4 0.39 1 06/02/22 20:22 75-01-4 0.34 1 06/02/22 20:22 1330-20-7 0.71 1 06/02/22 20:22 179601-23-1 0.34 1 06/02/22 20:22 95-47-6 70-130 1 70-130 1 70-130 1 [e1E:I:i 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 06/02/22 20:22 460-00-4 06/02/22 20:22 17060-07-0 06/02/22 20:22 2037-26-5 06/02/22 18:56 17060-07-0 06/02/2218:56 2037-26-5 Page 20 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-MW-9D Parameters ANALYTICAL RESULTS Lab ID: 92607341009 Collected: 05/27/22 10:10 Received: 06/01/22 13:15 Matrix: Water Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic <4.7 ug/L 4.7 1 06/28/22 16:16 06/29/22 20:08 7440-38-2 Barium 26.8 ug/L 3.5 1 06/28/22 16:16 06/29/22 20:08 7440-39-3 Cadmium <0.40 ug/L 0.40 1 06/28/22 16:16 06/29/22 20:08 7440-43-9 Chromium <3.7 ug/L 3.7 1 06/28/22 16:16 06/29/22 20:08 7440-47-3 Lead <4.5 ug/L 4.5 1 06/28/22 16:16 06/29/22 20:08 7439-92-1 Selenium <4.7 ug/L 4.7 1 06/28/22 16:16 06/29/22 20:08 7782-49-2 Silver <2.5 ug/L 2.5 1 06/28/22 16:16 06/29/22 20:08 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury <0.12 ug/L 0.12 1 06/14/2214:15 06/20/2212:24 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 06/02/22 20:40 67-64-1 Acrylonitrile <1.8 ug/L 1.8 1 06/02/22 20:40 107-13-1 Benzene <0.34 ug/L 0.34 1 06/02/22 20:40 71-43-2 Bromochloromethane <0.47 ug/L 0.47 1 06/02/22 20:40 74-97-5 Bromodichloromethane <0.31 ug/L 0.31 1 06/02/22 20:40 75-27-4 Bromoform <0.34 ug/L 0.34 1 06/02/22 20:40 75-25-2 Bromomethane <1.7 ug/L 1.7 1 06/02/22 20:40 74-83-9 2-Butanone (MEK) <4.0 ug/L 4.0 1 06/02/22 20:40 78-93-3 Carbon disulfide <0.36 ug/L 0.36 1 06/02/22 20:40 75-15-0 Carbon tetrachloride <0.33 ug/L 0.33 1 06/02/22 20:40 56-23-5 Chlorobenzene <0.28 ug/L 0.28 1 06/02/22 20:40 108-90-7 Chloroethane <0.65 ug/L 0.65 1 06/02/22 20:40 75-00-3 Chloroform <0.43 ug/L 0.43 1 06/02/22 20:40 67-66-3 Chloromethane <0.54 ug/L 0.54 1 06/02/22 20:40 74-87-3 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 06/02/22 20:40 96-12-8 Dibromochloromethane <0.36 ug/L 0.36 1 06/02/22 20:40 124-48-1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 06/02/22 20:40 106-93-4 Dibromomethane <0.39 ug/L 0.39 1 06/02/22 20:40 74-95-3 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 06/02/22 20:40 95-50-1 1,4-Dichlorobenzene <0.33 ug/L 0.33 1 06/02/22 20:40 106-46-7 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 06/02/22 20:40 110-57-6 1,1-Dichloroethane <0.37 ug/L 0.37 1 06/02/22 20:40 75-34-3 1,2-Dichloroethane <0.32 ug/L 0.32 1 06/02/22 20:40 107-06-2 1,1-Dichloroethene <0.35 ug/L 0.35 1 06/02/22 20:40 75-35-4 cis-1,2-Dichloroethene <0.38 ug/L 0.38 1 06/02/22 20:40 156-59-2 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 06/02/22 20:40 156-60-5 1,2-Dichloropropane <0.36 ug/L 0.36 1 06/02/22 20:40 78-87-5 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 20:40 10061-01-5 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 20:40 10061-02-6 Ethylbenzene <0.30 ug/L 0.30 1 06/02/22 20:40 100-41-4 2-Hexanone <0.48 ug/L 0.48 1 06/02/22 20:40 591-78-6 REPORT OF LABORATORY ANALYSIS v2 L2 v2 This report shall not be reproduced, except in full, Date: 07/01 /2022 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-MW-9D Lab ID: 92607341009 Collected: 05/27/22 10:10 Received: 06/01/22 13:15 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/01 /2022 06:14 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte <9.7 ug/L <2.0 ug/L <2.7 ug/L <0.29 ug/L <0.31 ug/L <0.22 ug/L <0.29 ug/L <0.48 ug/L <0.33 ug/L <0.32 ug/L <0.38 ug/L <0.30 ug/L <0.26 ug/L <1.3 ug/L <0.39 ug/L <0.34 ug/L <0.71 ug/L <0.34 ug/L 94 % 101 % 101 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte <0.86 ug/L 96 % 90 % 9.7 1 06/02/22 20:40 74-88-4 2.0 1 06/02/22 20:40 75-09-2 2.7 1 06/02/22 20:40 108-10-1 0.29 1 06/02/22 20:40 100-42-5 0.31 1 06/02/22 20:40 630-20-6 0.22 1 06/02/22 20:40 79-34-5 0.29 1 06/02/22 20:40 127-18-4 0.48 1 06/02/22 20:40 108-88-3 0.33 1 06/02/22 20:40 71-55-6 0.32 1 06/02/22 20:40 79-00-5 0.38 1 06/02/22 20:40 79-01-6 0.30 1 06/02/22 20:40 75-69-4 0.26 1 06/02/22 20:40 96-18-4 1.3 1 06/02/22 20:40 108-05-4 0.39 1 06/02/22 20:40 75-01-4 0.34 1 06/02/22 20:40 1330-20-7 0.71 1 06/02/22 20:40 179601-23-1 0.34 1 06/02/22 20:40 95-47-6 70-130 1 70-130 1 70-130 1 [e1E:I:i 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 06/02/22 20:40 460-00-4 06/02/22 20:40 17060-07-0 06/02/22 20:40 2037-26-5 [eIyLeYaf��►�i fNlfi F'><i ���1i Qi 06/02/22 19:15 17060-07-0 06/02/2219:15 2037-26-5 Page 22 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-SW-1 Parameters ANALYTICAL RESULTS Lab ID: 92607341010 Collected: 05/27/22 10:45 Received: 06/01/22 13:15 Matrix: Water Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic <4.7 ug/L 4.7 1 06/28/22 16:16 06/29/22 20:11 7440-38-2 Barium 27.0 ug/L 3.5 1 06/28/22 16:16 06/29/22 20:11 7440-39-3 Cadmium <0.40 ug/L 0.40 1 06/28/22 16:16 06/29/22 20:11 7440-43-9 Chromium <3.7 ug/L 3.7 1 06/28/22 16:16 06/29/22 20:11 7440-47-3 Lead <4.5 ug/L 4.5 1 06/28/22 16:16 06/29/22 20:11 7439-92-1 Selenium <4.7 ug/L 4.7 1 06/28/22 16:16 06/29/22 20:11 7782-49-2 Silver <2.5 ug/L 2.5 1 06/28/22 16:16 06/29/22 20:11 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury <0.12 ug/L 0.12 1 06/14/2214:15 06/20/2212:26 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 06/02/22 23:06 67-64-1 Acrylonitrile <1.8 ug/L 1.8 1 06/02/22 23:06 107-13-1 Benzene <0.34 ug/L 0.34 1 06/02/22 23:06 71-43-2 Bromochloromethane <0.47 ug/L 0.47 1 06/02/22 23:06 74-97-5 Bromodichloromethane <0.31 ug/L 0.31 1 06/02/22 23:06 75-27-4 Bromoform <0.34 ug/L 0.34 1 06/02/22 23:06 75-25-2 Bromomethane <1.7 ug/L 1.7 1 06/02/22 23:06 74-83-9 2-Butanone (MEK) <4.0 ug/L 4.0 1 06/02/22 23:06 78-93-3 Carbon disulfide <0.36 ug/L 0.36 1 06/02/22 23:06 75-15-0 Carbon tetrachloride <0.33 ug/L 0.33 1 06/02/22 23:06 56-23-5 Chlorobenzene <0.28 ug/L 0.28 1 06/02/22 23:06 108-90-7 Chloroethane <0.65 ug/L 0.65 1 06/02/22 23:06 75-00-3 Chloroform <0.43 ug/L 0.43 1 06/02/22 23:06 67-66-3 Chloromethane <0.54 ug/L 0.54 1 06/02/22 23:06 74-87-3 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 06/02/22 23:06 96-12-8 Dibromochloromethane <0.36 ug/L 0.36 1 06/02/22 23:06 124-48-1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 06/02/22 23:06 106-93-4 Dibromomethane <0.39 ug/L 0.39 1 06/02/22 23:06 74-95-3 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 06/02/22 23:06 95-50-1 1,4-Dichlorobenzene <0.33 ug/L 0.33 1 06/02/22 23:06 106-46-7 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 06/02/22 23:06 110-57-6 1,1-Dichloroethane <0.37 ug/L 0.37 1 06/02/22 23:06 75-34-3 1,2-Dichloroethane <0.32 ug/L 0.32 1 06/02/22 23:06 107-06-2 1,1-Dichloroethene <0.35 ug/L 0.35 1 06/02/22 23:06 75-35-4 cis-1,2-Dichloroethene <0.38 ug/L 0.38 1 06/02/22 23:06 156-59-2 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 06/02/22 23:06 156-60-5 1,2-Dichloropropane <0.36 ug/L 0.36 1 06/02/22 23:06 78-87-5 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 23:06 10061-01-5 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 23:06 10061-02-6 Ethylbenzene <0.30 ug/L 0.30 1 06/02/22 23:06 100-41-4 2-Hexanone <0.48 ug/L 0.48 1 06/02/22 23:06 591-78-6 REPORT OF LABORATORY ANALYSIS v2 L2 v2 This report shall not be reproduced, except in full, Date: 07/01 /2022 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-SW-1 Lab ID: 92607341010 Collected: 05/27/22 10:45 Received: 06/01/22 13:15 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/01 /2022 06:14 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte <9.7 ug/L <2.0 ug/L <2.7 ug/L <0.29 ug/L <0.31 ug/L <0.22 ug/L <0.29 ug/L <0.48 ug/L <0.33 ug/L <0.32 ug/L <0.38 ug/L <0.30 ug/L <0.26 ug/L <1.3 ug/L <0.39 ug/L <0.34 ug/L <0.71 ug/L <0.34 ug/L 97 % 103 % 103 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte <0.86 ug/L 99 % 91 % 9.7 1 06/02/22 23:06 74-88-4 2.0 1 06/02/22 23:06 75-09-2 2.7 1 06/02/22 23:06 108-10-1 0.29 1 06/02/22 23:06 100-42-5 0.31 1 06/02/22 23:06 630-20-6 0.22 1 06/02/22 23:06 79-34-5 0.29 1 06/02/22 23:06 127-18-4 0.48 1 06/02/22 23:06 108-88-3 0.33 1 06/02/22 23:06 71-55-6 0.32 1 06/02/22 23:06 79-00-5 0.38 1 06/02/22 23:06 79-01-6 0.30 1 06/02/22 23:06 75-69-4 0.26 1 06/02/22 23:06 96-18-4 1.3 1 06/02/22 23:06 108-05-4 0.39 1 06/02/22 23:06 75-01-4 0.34 1 06/02/22 23:06 1330-20-7 0.71 1 06/02/22 23:06 179601-23-1 0.34 1 06/02/22 23:06 95-47-6 70-130 1 70-130 1 70-130 1 [e1E:I:i 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 06/02/22 23:06 460-00-4 06/02/22 23:06 17060-07-0 06/02/22 23:06 2037-26-5 [eI:ILeYaf ���i PIXY, 1111111 Ill ��c� ;S Qi 06/02/22 19:34 17060-07-0 06/02/2219:34 2037-26-5 Page 24 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-SW-2 Parameters ANALYTICAL RESULTS Lab ID: 92607341011 Collected: 05/27/22 15:10 Received: 06/01/22 13:15 Matrix: Water Results Units PQL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic <4.7 ug/L 4.7 1 06/28/22 16:16 06/29/22 20:21 7440-38-2 Barium 35.4 ug/L 3.5 1 06/28/22 16:16 06/29/22 20:21 7440-39-3 Cadmium <0.40 ug/L 0.40 1 06/28/22 16:16 06/29/22 20:21 7440-43-9 Chromium <3.7 ug/L 3.7 1 06/28/22 16:16 06/29/22 20:21 7440-47-3 Lead <4.5 ug/L 4.5 1 06/28/22 16:16 06/29/22 20:21 7439-92-1 Selenium <4.7 ug/L 4.7 1 06/28/22 16:16 06/29/22 20:21 7782-49-2 Silver <2.5 ug/L 2.5 1 06/28/22 16:16 06/29/22 20:21 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury <0.12 ug/L 0.12 1 06/14/2214:15 06/20/2212:28 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone <5.1 ug/L 5.1 1 06/02/22 20:59 67-64-1 Acrylonitrile <1.8 ug/L 1.8 1 06/02/22 20:59 107-13-1 Benzene <0.34 ug/L 0.34 1 06/02/22 20:59 71-43-2 Bromochloromethane <0.47 ug/L 0.47 1 06/02/22 20:59 74-97-5 Bromodichloromethane <0.31 ug/L 0.31 1 06/02/22 20:59 75-27-4 Bromoform <0.34 ug/L 0.34 1 06/02/22 20:59 75-25-2 Bromomethane <1.7 ug/L 1.7 1 06/02/22 20:59 74-83-9 2-Butanone (MEK) <4.0 ug/L 4.0 1 06/02/22 20:59 78-93-3 Carbon disulfide <0.36 ug/L 0.36 1 06/02/22 20:59 75-15-0 Carbon tetrachloride <0.33 ug/L 0.33 1 06/02/22 20:59 56-23-5 Chlorobenzene <0.28 ug/L 0.28 1 06/02/22 20:59 108-90-7 Chloroethane <0.65 ug/L 0.65 1 06/02/22 20:59 75-00-3 Chloroform <0.43 ug/L 0.43 1 06/02/22 20:59 67-66-3 Chloromethane <0.54 ug/L 0.54 1 06/02/22 20:59 74-87-3 1,2-Dibromo-3-chloropropane <0.34 ug/L 0.34 1 06/02/22 20:59 96-12-8 Dibromochloromethane <0.36 ug/L 0.36 1 06/02/22 20:59 124-48-1 1,2-Dibromoethane (EDB) <0.27 ug/L 0.27 1 06/02/22 20:59 106-93-4 Dibromomethane <0.39 ug/L 0.39 1 06/02/22 20:59 74-95-3 1,2-Dichlorobenzene <0.34 ug/L 0.34 1 06/02/22 20:59 95-50-1 1,4-Dichlorobenzene <0.33 ug/L 0.33 1 06/02/22 20:59 106-46-7 trans-1,4-Dichloro-2-butene <0.56 ug/L 0.56 1 06/02/22 20:59 110-57-6 1,1-Dichloroethane <0.37 ug/L 0.37 1 06/02/22 20:59 75-34-3 1,2-Dichloroethane <0.32 ug/L 0.32 1 06/02/22 20:59 107-06-2 1,1-Dichloroethene <0.35 ug/L 0.35 1 06/02/22 20:59 75-35-4 cis-1,2-Dichloroethene <0.38 ug/L 0.38 1 06/02/22 20:59 156-59-2 trans-1,2-Dichloroethene <0.40 ug/L 0.40 1 06/02/22 20:59 156-60-5 1,2-Dichloropropane <0.36 ug/L 0.36 1 06/02/22 20:59 78-87-5 cis-1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 20:59 10061-01-5 trans- 1,3-Dichloropropene <0.36 ug/L 0.36 1 06/02/22 20:59 10061-02-6 Ethylbenzene <0.30 ug/L 0.30 1 06/02/22 20:59 100-41-4 2-Hexanone <0.48 ug/L 0.48 1 06/02/22 20:59 591-78-6 REPORT OF LABORATORY ANALYSIS v2 L2 v2 This report shall not be reproduced, except in full, Date: 07/01 /2022 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Sample: 8103-SW-2 Lab ID: 92607341011 Collected: 05/27/22 15:10 Received: 06/01/22 13:15 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/01 /2022 06:14 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte <9.7 ug/L <2.0 ug/L <2.7 ug/L <0.29 ug/L <0.31 ug/L <0.22 ug/L <0.29 ug/L <0.48 ug/L <0.33 ug/L <0.32 ug/L <0.38 ug/L <0.30 ug/L <0.26 ug/L <1.3 ug/L <0.39 ug/L <0.34 ug/L <0.71 ug/L <0.34 ug/L 99 % 103 % 101 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 5.3 ug/L 93 % 89 % 9.7 1 06/02/22 20:59 74-88-4 2.0 1 06/02/22 20:59 75-09-2 2.7 1 06/02/22 20:59 108-10-1 0.29 1 06/02/22 20:59 100-42-5 0.31 1 06/02/22 20:59 630-20-6 0.22 1 06/02/22 20:59 79-34-5 0.29 1 06/02/22 20:59 127-18-4 0.48 1 06/02/22 20:59 108-88-3 0.33 1 06/02/22 20:59 71-55-6 0.32 1 06/02/22 20:59 79-00-5 0.38 1 06/02/22 20:59 79-01-6 0.30 1 06/02/22 20:59 75-69-4 0.26 1 06/02/22 20:59 96-18-4 1.3 1 06/02/22 20:59 108-05-4 0.39 1 06/02/22 20:59 75-01-4 0.34 1 06/02/22 20:59 1330-20-7 0.71 1 06/02/22 20:59 179601-23-1 0.34 1 06/02/22 20:59 95-47-6 70-130 1 70-130 1 70-130 1 [e1E:I:i 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 06/02/22 20:59 460-00-4 06/02/22 20:59 17060-07-0 06/02/22 20:59 2037-26-5 06/02/22 19:56 17060-07-0 06/02/2219:56 2037-26-5 Page 26 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Scarlett Geo South Landfill Pace Project No.: 92607341 QC Batch: 704293 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92607341001, 92607341002, 92607341003, 92607341004, 92607341005, 92607341006, 92607341007, 92607341008,92607341009,92607341010,92607341011 METHOD BLANK: 3675078 Matrix: Water Associated Lab Samples: 92607341001, 92607341002, 92607341003, 92607341004, 92607341005, 92607341006, 92607341007, 92607341008,92607341009,92607341010,92607341011 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L <0.12 0.12 06/20/2211:49 LABORATORY CONTROL SAMPLE: 3675079 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.5 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3675080 3675081 MS MSD 92608359001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Mercury ug/L ND 2.5 2.5 2.5 3.0 99 118 75-125 18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01 /2022 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Scarlett Geo South Landfill Pace Project No.: 92607341 QC Batch: 706214 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92607341001, 92607341002, 92607341003, 92607341004, 92607341005, 92607341006 METHOD BLANK: 3684254 Matrix: Water Associated Lab Samples: 92607341001, 92607341002, 92607341003, 92607341004, 92607341005, 92607341006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Arsenic ug/L <4.7 4.7 06/29/2217:52 Barium ug/L <3.5 3.5 06/29/2217:52 Cadmium ug/L <0.40 0.40 06/29/2217:52 Chromium ug/L <3.7 3.7 06/29/2217:52 Lead ug/L <4.5 4.5 06/29/2217:52 Selenium ug/L <4.7 4.7 06/29/2217:52 Silver ug/L <2.5 2.5 06/29/2217:52 LABORATORY CONTROL SAMPLE: 3684255 Parameter Units Arsenic ug/L Barium ug/L Cadmium ug/L Chromium ug/L Lead ug/L Selenium ug/L Silver ug/L Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 500 462 92 80-120 500 470 94 80-120 500 470 94 80-120 500 477 95 80-120 500 480 96 80-120 500 475 95 80-120 250 233 93 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3684256 3684257 MS MSD 92606390001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Arsenic ug/L 4.7 500 500 492 493 97 97 75-125 0 Barium ug/L 107 500 500 581 584 95 96 75-125 0 Cadmium ug/L <0.40 500 500 470 473 94 95 75-125 1 Chromium ug/L <3.7 500 500 489 491 97 98 75-125 0 Lead ug/L <4.5 500 500 476 479 95 95 75-125 1 Selenium ug/L <4.7 500 500 512 512 102 102 75-125 0 Silver ug/L <2.5 250 250 240 242 96 97 75-125 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01 /2022 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Scarlett Geo South Landfill Pace Project No.: 92607341 QC Batch: 706216 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92607341007, 92607341008, 92607341009, 92607341010, 92607341011 METHOD BLANK: 3684268 Matrix: Water Associated Lab Samples: 92607341007, 92607341008, 92607341009, 92607341010, 92607341011 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Arsenic ug/L <4.7 4.7 06/30/2215:17 Barium ug/L <3.5 3.5 06/30/2215:17 Cadmium ug/L <0.40 0.40 06/30/2215:17 Chromium ug/L <3.7 3.7 06/30/2215:17 Lead ug/L <4.5 4.5 06/30/2215:17 Selenium ug/L <4.7 4.7 06/30/2215:17 Silver ug/L <2.5 2.5 06/30/2215:17 LABORATORY CONTROL SAMPLE: 3684269 Parameter Units Arsenic ug/L Barium ug/L Cadmium ug/L Chromium ug/L Lead ug/L Selenium ug/L Silver ug/L Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 500 464 93 80-120 500 476 95 80-120 500 477 95 80-120 500 478 96 80-120 500 486 97 80-120 500 480 96 80-120 250 234 94 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3684270 3684271 MS MSD 92607341007 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Arsenic ug/L <4.7 500 500 406 403 81 80 75-125 1 Barium ug/L 335 500 500 745 740 82 81 75-125 1 Cadmium ug/L 0.40 500 500 421 421 84 84 75-125 0 Chromium ug/L 9.1 500 500 424 423 83 83 75-125 0 Lead ug/L 19.3 500 500 437 434 84 83 75-125 1 Selenium ug/L <4.7 500 500 425 423 85 85 75-125 0 Silver ug/L <2.5 250 250 210 209 84 84 75-125 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01 /2022 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Scarlett Geo South Landfill Pace Project No.: 92607341 QC Batch: 701889 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92607341001, 92607341002, 92607341003, 92607341004, 92607341005, 92607341006, 92607341007, 92607341008,92607341009,92607341010,92607341011 METHOD BLANK: 3663215 Matrix: Water Associated Lab Samples: 92607341001, 92607341002, 92607341003, 92607341004, 92607341005, 92607341006, 92607341007, 92607341008,92607341009,92607341010,92607341011 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L <0.31 0.31 06/02/22 19:27 1,1,1-Trichloroethane ug/L <0.33 0.33 06/02/22 19:27 1,1,2,2-Tetrachloroethane ug/L <0.22 0.22 06/02/22 19:27 1,1,2-Trichloroethane ug/L <0.32 0.32 06/02/22 19:27 1,1-Dichloroethane ug/L <0.37 0.37 06/02/22 19:27 1,1-Dichloroethene ug/L <0.35 0.35 06/02/22 19:27 1,2,3-Trichloropropane ug/L <0.26 0.26 06/02/22 19:27 1,2-Dibromo-3-chloropropane ug/L <0.34 0.34 06/02/22 19:27 1,2-Dibromoethane (EDB) ug/L <0.27 0.27 06/02/22 19:27 1,2-Dichlorobenzene ug/L <0.34 0.34 06/02/22 19:27 1,2-Dichloroethane ug/L <0.32 0.32 06/02/22 19:27 1,2-Dichloropropane ug/L <0.36 0.36 06/02/22 19:27 1,4-Dichlorobenzene ug/L <0.33 0.33 06/02/22 19:27 2-Butanone (MEK) ug/L <4.0 4.0 06/02/22 19:27 2-Hexanone ug/L <0.48 0.48 06/02/22 19:27 4-Methyl-2-pentanone (MIBK) ug/L <2.7 2.7 06/02/22 19:27 Acetone ug/L <5.1 5.1 06/02/22 19:27 Acrylonitrile ug/L <1.8 1.8 06/02/22 19:27 Benzene ug/L <0.34 0.34 06/02/22 19:27 Bromochloromethane ug/L <0.47 0.47 06/02/22 19:27 Bromodichloromethane ug/L <0.31 0.31 06/02/22 19:27 Bromoform ug/L <0.34 0.34 06/02/22 19:27 Bromomethane ug/L <1.7 1.7 06/02/22 19:27 Carbon disulfide ug/L <0.36 0.36 06/02/22 19:27 Carbon tetrachloride ug/L <0.33 0.33 06/02/22 19:27 Chlorobenzene ug/L <0.28 0.28 06/02/22 19:27 Chloroethane ug/L <0.65 0.65 06/02/22 19:27 Chloroform ug/L <0.43 0.43 06/02/22 19:27 Chloromethane ug/L <0.54 0.54 06/02/22 19:27 cis-1,2-Dichloroethene ug/L <0.38 0.38 06/02/22 19:27 cis-1,3-Dichloropropene ug/L <0.36 0.36 06/02/22 19:27 Dibromochloromethane ug/L <0.36 0.36 06/02/22 19:27 Dibromomethane ug/L <0.39 0.39 06/02/22 19:27 Ethylbenzene ug/L <0.30 0.30 06/02/22 19:27 lodomethane ug/L <9.7 9.7 06/02/22 19:27 m&p-Xylene ug/L <0.71 0.71 06/02/22 19:27 Methylene Chloride ug/L <2.0 2.0 06/02/22 19:27 o-Xylene ug/L <0.34 0.34 06/02/22 19:27 Styrene ug/L <0.29 0.29 06/02/22 19:27 v2 v2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01 /2022 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Scarlett Geo South Landfill Pace Project No.: 92607341 METHOD BLANK: 3663215 Matrix: Water Associated Lab Samples: 92607341001, 92607341002, 92607341003, 92607341004, 92607341005, 92607341006, 92607341007, 92607341008,92607341009,92607341010,92607341011 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Tetrachloroethene ug/L <0.29 0.29 06/02/22 19:27 Toluene ug/L <0.48 0.48 06/02/22 19:27 trans-1,2-Dichloroethene ug/L <0.40 0.40 06/02/22 19:27 trans- 1,3-Dichloropropene ug/L <0.36 0.36 06/02/22 19:27 trans-1,4-Dichloro-2-butene ug/L <0.56 0.56 06/02/22 19:27 Trichloroethene ug/L <0.38 0.38 06/02/22 19:27 Trichlorofluoromethane ug/L <0.30 0.30 06/02/22 19:27 Vinyl acetate ug/L <1.3 1.3 06/02/22 19:27 Vinyl chloride ug/L <0.39 0.39 06/02/22 19:27 Xylene (Total) ug/L <0.34 0.34 06/02/22 19:27 1,2-Dichloroethane-d4 (S) % 101 70-130 06/02/22 19:27 4-Bromofluorobenzene (S) % 98 70-130 06/02/22 19:27 Toluene-d8 (S) % 105 70-130 06/02/22 19:27 LABORATORY CONTROL SAMPLE: Parameter 3663216 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 54.5 109 70-130 1,1,1-Trichloroethane ug/L 50 45.5 91 70-130 1,1,2,2-Tetrachloroethane ug/L 50 53.5 107 70-130 1,1,2-Trichloroethane ug/L 50 51.6 103 70-130 1,1-Dichloroethane ug/L 50 42.3 85 70-130 1,1-Dichloroethene ug/L 50 39.2 78 70-132 1,2,3-Trichloropropane ug/L 50 53.8 108 70-130 1,2-Dibromo-3-chloropropane ug/L 50 54.0 108 70-132 1,2-Dibromoethane (EDB) ug/L 50 52.8 106 70-130 1,2-Dichlorobenzene ug/L 50 53.9 108 70-130 1,2-Dichloroethane ug/L 50 48.1 96 70-130 1,2-Dichloropropane ug/L 50 50.2 100 70-130 1,4-Dichlorobenzene ug/L 50 52.5 105 70-130 2-Butanone (MEK) ug/L 100 107 107 70-133 2-Hexanone ug/L 100 119 119 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 115 115 70-130 Acetone ug/L 100 84.8 85 70-144 Acrylonitrile ug/L 250 232 93 70-130 Benzene ug/L 50 43.0 86 70-130 Bromochloromethane ug/L 50 45.3 91 70-130 Bromodichloromethane ug/L 50 52.8 106 70-130 Bromoform ug/L 50 56.4 113 70-131 Bromomethane ug/L 50 32.1 64 30-177 v3 Carbon disulfide ug/L 50 34.3 69 70-133 L2 Carbon tetrachloride ug/L 50 44.8 90 70-130 Chlorobenzene ug/L 50 51.9 104 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01 /2022 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Scarlett Geo South Landfill Pace Project No.: 92607341 LABORATORY CONTROL SAMPLE: Parameter 3663216 Units Spike Conc. LCS LCS Result % Rec Chloroethane ug/L 50 36.7 Chloroform ug/L 50 49.6 Chloromethane ug/L 50 35.5 cis-1,2-Dichloroethene ug/L 50 45.6 cis-1,3-Dichloropropene ug/L 50 52.3 Dibromochloromethane ug/L 50 54.2 Dibromomethane ug/L 50 49.3 Ethylbenzene ug/L 50 52.1 lodomethane ug/L 100 78.7 m&p-Xylene ug/L 100 107 Methylene Chloride ug/L 50 40.2 o-Xylene ug/L 50 53.3 Styrene ug/L 50 55.0 Tetrachloroethene ug/L 50 52.9 Toluene ug/L 50 48.4 trans-1,2-Dichloroethene ug/L 50 41.3 trans- 1,3-Dichloropropene ug/L 50 52.8 trans-1,4-Dichloro-2-butene ug/L 50 58.5 Trichloroethene ug/L 50 47.8 Trichlorofluoromethane ug/L 50 35.9 Vinyl acetate ug/L 100 98.8 Vinyl chloride ug/L 50 36.7 Xylene (Total) ug/L 150 160 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % % Rec Limits Qualifiers 73 46-131 99 70-130 71 49-130 v3 91 70-130 105 70-130 108 70-130 99 70-130 104 70-130 79 47-140 107 70-130 80 68-130 107 70-130 110 70-130 106 70-130 97 70-130 83 70-130 106 70-130 117 25-200 96 70-130 72 61-130 99 70-140 73 59-142 107 70-130 101 70-130 99 70-130 100 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3663217 MS 92607341001 Spike Parameter Units Result Conc. MSD Spike Conc. 3663218 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Qual 1,1,1,2-Tetrachloroethane ug/L <0.31 20 20 30.0 30.3 150 151 70-135 1 M1 1,1,1-Trichloroethane ug/L <0.33 20 20 32.3 32.3 162 161 70-148 0 M1 1,1,2,2-Tetrachloroethane ug/L <0.22 20 20 31.9 31.2 160 156 70-131 2 M1 1,1,2-Trichloroethane ug/L <0.32 20 20 32.1 32.0 160 160 70-136 0 M1 1,1-Dichloroethane ug/L 47.9 20 20 86.9 87.0 195 196 70-147 0 M1 1,1-Dichloroethene ug/L 1.0 20 20 35.6 36.1 173 175 70-158 1 M1 1,2,3-Trichloropropane ug/L <0.26 20 20 30.8 30.7 154 154 67-137 0 M1 1,2-Dibromo-3-chloropropane ug/L <0.34 20 20 28.2 27.9 141 140 69-136 1 M1 1,2-Dibromoethane (EDB) ug/L <0.27 20 20 32.0 31.7 160 158 70-137 1 M1 1,2-Dichlorobenzene ug/L <0.34 20 20 29.9 29.5 149 148 70-133 1 M1 1,2-Dichloroethane ug/L 0.32 20 20 31.8 31.7 157 157 67-138 0 M1 1,2-Dichloropropane ug/L <0.36 20 20 33.0 32.7 165 163 70-138 1 M1 1,4-Dichlorobenzene ug/L 1.8 20 20 31.2 30.8 147 145 70-133 1 M1 2-Butanone (MEK) ug/L <4.0 40 40 62.9 63.6 157 159 61-147 1 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01 /2022 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Scarlett Geo South Landfill Pace Project No.: 92607341 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3663217 3663218 MS MSD 92607341001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 2-Hexanone ug/L <0.48 40 40 61.6 60.0 154 150 67-139 3 M1 4-Methyl-2-pentanone (MIBK) ug/L <2.7 40 40 59.3 57.4 148 144 67-136 3 M1 Acetone ug/L <5.1 40 40 60.2 58.3 151 146 55-159 3 Acrylonitrile ug/L <1.8 100 100 164 161 164 161 68-140 2 M1 Benzene ug/L 1.7 20 20 33.3 33.2 158 158 67-150 0 M1 Bromochloromethane ug/L <0.47 20 20 34.3 34.6 172 173 70-146 1 M1 Bromodichloromethane ug/L <0.31 20 20 30.9 30.6 154 153 70-138 1 M1 Bromoform ug/L <0.34 20 20 27.4 26.9 137 134 57-138 2 IK Bromomethane ug/L <1.7 20 20 26.0 26.6 130 133 10-200 2 Carbon disulfide ug/L <0.36 20 20 36.2 35.9 181 180 70-152 1 M0,v1 Carbon tetrachloride ug/L <0.33 20 20 29.5 29.2 148 146 70-147 1 M1 Chlorobenzene ug/L 2.0 20 20 34.0 33.9 160 159 70-137 0 M1 Chloroethane ug/L 6.4 20 20 38.6 39.2 161 164 51-166 2 Chloroform ug/L 0.43 20 20 34.4 34.1 167 166 70-144 1 M1 Chloromethane ug/L <0.54 20 20 34.4 34.6 172 173 24-161 1 M1 cis-1,2-Dichloroethene ug/L 5.3 20 20 39.9 39.6 173 172 67-148 1 M1 cis-1,3-Dichloropropene ug/L <0.36 20 20 31.7 31.7 158 158 70-142 0 M1 Dibromochloromethane ug/L <0.36 20 20 29.6 29.4 148 147 68-138 1 M1 Dibromomethane ug/L <0.39 20 20 30.2 29.8 151 149 70-134 1 M1 Ethylbenzene ug/L <0.30 20 20 31.4 30.9 157 155 68-143 1 M1 lodomethane ug/L <9.7 40 40 48.5 50.5 121 126 20-161 4 m&p-Xylene ug/L <0.71 40 40 62.9 62.2 157 155 53-157 1 Methylene Chloride ug/L 14.6 20 20 48.3 48.0 169 167 64-148 1 M1 o-Xylene ug/L 3.7 20 20 35.1 35.2 157 157 68-143 0 M1 Styrene ug/L <0.29 20 20 32.5 32.3 163 161 70-136 1 M1 Tetrachloroethene ug/L <0.29 20 20 28.6 28.7 143 144 70-139 0 M1 Toluene ug/L <0.48 20 20 31.4 31.4 157 157 47-157 0 trans-1,2-Dichloroethene ug/L <0.40 20 20 34.6 34.8 173 174 70-149 0 M1 trans- 1,3-Dichloropropene ug/L <0.36 20 20 31.1 30.7 155 154 70-138 1 M1 trans-1,4-Dichloro-2-butene ug/L <0.56 20 20 26.4 25.5 132 127 31-145 3 Trichloroethene ug/L 0.38 20 20 31.6 31.6 155 155 70-149 0 M1 Trichlorofluoromethane ug/L <0.30 20 20 29.7 29.7 148 149 61-154 0 Vinyl acetate ug/L <1.3 40 40 55.3 53.9 138 135 48-156 3 Vinyl chloride ug/L <0.39 20 20 34.4 34.5 172 173 55-172 0 M1 Xylene (Total) ug/L 3.7 60 60 98.1 97.3 157 156 66-145 1 MS 1,2-Dichloroethane-d4 (S) % 101 101 70-130 4-Bromofluorobenzene (S) % 98 97 70-130 Toluene-d8(S) % 99 99 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01 /2022 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Scarlett Geo South Landfill Pace Project No.: 92607341 QC Batch: 701451 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92607341001, 92607341002, 92607341003, 92607341004, 92607341005, 92607341006, 92607341007, 92607341008,92607341009,92607341010,92607341011 METHOD BLANK: 3661441 Matrix: Water Associated Lab Samples: 92607341001, 92607341002, 92607341003, 92607341004, 92607341005, 92607341006, 92607341007, 92607341008,92607341009,92607341010,92607341011 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L <0.86 0.86 06/02/22 11:33 1,2-Dichloroethane-d4 (S) % 102 70-130 06/02/22 11:33 Toluene-d8 (S) % 92 70-130 06/02/22 11:33 LABORATORY CONTROL SAMPLE: 3661442 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 19.4 97 70-130 1,2-Dichloroethane-d4 (S) % 91 70-130 Toluene-d8 (S) % 88 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3661443 3661444 MS MSD 92606634001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 17.5 17.4 85 84 63-136 1 1,2-Dichloroethane-d4 (S) % 96 104 70-130 Toluene-d8(S) % 90 93 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01 /2022 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 39 Pace Analytical Services, LLC leac,yficalAnal1377 South Park Drive Kernersville, NC 27284 www.pacelabs.com (704)977-0981 QUALIFIERS Project: Scarlett Geo South Landfill Pace Project No.: 92607341 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. L2 Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated samples may be biased low. MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. MS Analyte recovery in the matrix spike was outside QC limits for one or more of the constituent analytes used in the calculated result. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01 /2022 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 39 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Scarlett Geo South Landfill Pace Project No.: 92607341 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92607341001 8103-MW-1 EPA 3010A 706214 EPA 6010D 707497 92607341002 8103-MW-2A EPA 3010A 706214 EPA 6010D 707497 92607341003 8103-MW-4A EPA 3010A 706214 EPA 6010D 707497 92607341004 8103-MW-5 EPA 3010A 706214 EPA 6010D 707497 92607341005 8103-MW-6 EPA 3010A 706214 EPA 6010D 707497 92607341006 8103-MW-7 EPA 3010A 706214 EPA 6010D 707497 92607341007 8103-MW-8 EPA 3010A 706216 EPA 6010D 707493 92607341008 8103-MW-9S EPA 3010A 706216 EPA 6010D 707493 92607341009 8103-MW-9D EPA 3010A 706216 EPA 6010D 707493 92607341010 8103-SW-1 EPA 3010A 706216 EPA 6010D 707493 92607341011 8103-SW-2 EPA 3010A 706216 EPA 6010D 707493 92607341001 8103-MW-1 EPA 7470A 704293 EPA 7470A 704663 92607341002 8103-MW-2A EPA 7470A 704293 EPA 7470A 704663 92607341003 8103-MW-4A EPA 7470A 704293 EPA 7470A 704663 92607341004 8103-MW-5 EPA 7470A 704293 EPA 7470A 704663 92607341005 8103-MW-6 EPA 7470A 704293 EPA 7470A 704663 92607341006 8103-MW-7 EPA 7470A 704293 EPA 7470A 704663 92607341007 8103-MW-8 EPA 7470A 704293 EPA 7470A 704663 92607341008 8103-MW-9S EPA 7470A 704293 EPA 7470A 704663 92607341009 8103-MW-9D EPA 7470A 704293 EPA 7470A 704663 92607341010 8103-SW-1 EPA 7470A 704293 EPA 7470A 704663 92607341011 8103-SW-2 EPA 7470A 704293 EPA 7470A 704663 92607341001 8103-MW-1 EPA 8260D 701889 92607341002 8103-MW-2A EPA 8260D 701889 92607341003 8103-MW-4A EPA 8260D 701889 92607341004 8103-MW-5 EPA 8260D 701889 92607341005 8103-MW-6 EPA 8260D 701889 92607341006 8103-MW-7 EPA 8260D 701889 92607341007 8103-MW-8 EPA 8260D 701889 92607341008 8103-MW-9S EPA 8260D 701889 92607341009 8103-MW-9D EPA 8260D 701889 92607341010 8103-SW-1 EPA 8260D 701889 92607341011 8103-SW-2 EPA 8260D 701889 92607341001 8103-MW-1 EPA 8260D Mod. 701451 92607341002 8103-MW-2A EPA 8260D Mod. 701451 92607341003 8103-MW-4A EPA 8260D Mod. 701451 92607341004 8103-MW-5 EPA 8260D Mod. 701451 92607341005 8103-MW-6 EPA 8260D Mod. 701451 92607341006 8103-MW-7 EPA 8260D Mod. 701451 92607341007 8103-MW-8 EPA 8260D Mod. 701451 92607341008 8103-MW-9S EPA 8260D Mod. 701451 92607341009 8103-MW-9D EPA 8260D Mod. 701451 92607341010 8103-SW-1 EPA 8260D Mod. 701451 92607341011 8103-SW-2 EPA 8260D Mod. 701451 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/01 /2022 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 39 L; DC# —Title: EW-FRM-HUM-0083 vO1 Sample Condition Upon Receipt 11106, I ivirnrJLss¢rxer — Effective Date.; QW1212022 Laboratory roc ing sarnples Mhe" We4fJEdOrt[] Greenwood 0 Huntersville [] Raleigh❑ Mer Sample Con4ition Client Marne; Upon Receipt Project n: Courier: ❑Fed Ex ❑UPS ❑US['S ❑Client Commercial ��ce []Oth�:r:. CustodySea[Present? ,Dyes '[:]Np Seals Intact? ❑Ves: ❑too Pac€cing-Mhterlak, PEAbble Wrdp Thermometer: Ip: C? 3 G 7 ( Type of Ice: —XI ❑Blue 'Correction Factor; L--.. — Adel/Subtract ('Q y�T Cooler Temp Corrected = USDA Regulated Soil (4 N/A; water sarnp[ei Dtdsamples originate in a.quatantine zone within the United State;: CA, NY, grSC u� f,ble [lags ❑None ❑ Other hanicsvilfeU AtlalntaLJ Ke'rnersv111eL J DaWfInitials Person Examining.Contentr.A^�Z Biological Tissue F xei? []Yes []No NIA []None Temp should he above freezing to 6°C: ❑Sampies out oftemp criteria. S.amp[es on fee; cooling process has begurt - Did samples-orlginate from a foreign source (Internationally, iciteck maps} e eyes LJNO _ inciuuing rsawaiI ano rverw-rmwir u+es t,,,JNW _ £szmmertts/'Ji'screpanCjFr _ Chainpf Custody Present? �O�es ❑No (3NIA _ ?. _ Samples Arrived within Ftp)d Tlnler ,1 ❑No ❑N/A 2. Short Hold Time Ana[ysis (<72 hr.)? Yes r No _NIA 3, Rush Turn Around Time Requested_e 1_jyt_s .r o [I N/A 4. Sufficient Volume? Y//es (_]Nu ❑NIA S. Correct Containers Used? -Pace Containers Used i2j<, T 2 6s ❑No ❑No ❑N/A ❑N/A 6. Contairrer5Intact? ©Yc. ❑No ©N/.-A Dissolved analysis: Sarnples Field Frlt::re0 _ ❑Y,, ❑No < /� 17. 8 5af,Aple Labels Match CDC? -includes Date/Tiirie/ID/Analysis Matrik:___ r'u'+'es ONo []NIA 9 Headspace In VOA Vials (}S-Gmml? ❑'des - No ❑N;A 1D. - Trip blank Present? Trip Blank Custody Seals Present.? ❑Ye> ❑Yas �DNo. k. ❑NIA NIA 11, COMMENTS/SAMPLE. Qi5CREPANCY CUENT NOTIFICATION/RESoWTIDN Pe(5Dn Contacted; project Hlanai;er SCURF Review: project Manager SRF Review. Lot ID o.f split containers: Date/Time: Date: Date: rreia uaza negwraw sites Urva r .._r+-..•. In. nne 4 A [D—o 1 of 7 Page 38 Of 39 DC#_Title.: ENV-FRM-HUN1-0083 vpll Sample Condition Upon Receipt Effective Date: 05Ii 42022 *Check marktop half of box:if pH and/or dechlorinatlon is verifled.and vvith(rrthe acceptance range for preservation samples, ExCeptlons: tiO.1,.C61iform=Tac, QI! and Grease, DR018015 (uratcrj DOC, Uri "Bottom half of box -is to fist number of bottles **'*Check all unpreserved Nitrates for chlorine Project # w Q S _ 4 V x 0 � 51 c, T a 'Z.- Q ? V v °� N h 41 a W m 0 yyyry��} �p � U ti S o -- L . 0. I.S m a LSD vG' ti U lyny a �. U �, q a V, a .� q. 4 •p a Z. -1 c � a w a E a a E S `a o Z a E ¢ a 4 = 4 O > z < p O+' > x q > Q > 4r m. ° V a A @ s dE. E cr E a N E 0 E ry 6 o E E v� u r, y = .y E M ,1 E Ln ry t n N & E r o, c� - E a' E a rt ' E La £ ; Ln t E. .i o is q� - 9' a 7 rn P- N Q .�..i 4 'm vl C a m ❑. e;r q a Ct! 'V' a u, l7 y L7 T ,-r U J m L7 L7 to M 47' Vs l7 Y of tD N . O� t7 ai IJ m U A '91 0 >c Ci }.�. to 'M 1cN=+�1' tErtr�R J 3 l7 tC = to MMM m �( Q Q Q > > O i to vl 06. Q > G //O �. rr C7 4 { l I IN 7. $ �r C 11 � �• - 7_2 \XN 7N pH Acdjustmeot Log for Preserved Samples 5ampl.• iD TypeWreacrvative pH upon receipt �� Date prascwolion adju5tud Time prescrvatian adjustcrf Amount of Preservative added Lotff E Note; `N lane ar there is a discrepancy affecting North Caroli .a cornplianc sampfes, a cagy or this furm will he sent to the Noah Carolina DENR Certlfitalion Office {j,e, Out ,=f hn';l, iatc rnxt preservat;ve, out ❑f temp, iro-carrect cone mars. Clrraltrav In- f,QA1A Pang 2 of?- Page 39 of 39