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HomeMy WebLinkAbout1201_Burke_KirkseyDrive_MSWLF_May22GW_FID1718090_20220914ENR USE ONLY: ❑Pa er Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: _ NC DENR I I Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: • Prepare one form for each individually monitored unit. • Please type or print legibly. • Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 28 surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). • Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): La Bella Associates (Joyce Engineering) Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: M Vazquez, P.G. Phone: (336) 323-0092 E-mail: M Vazquez@labellapc.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Burke Co. - Kirksey Dr. Landfill Kirksey Drive 12-01 .0500 May 17, 2022 Morganton, NC Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑X Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data Surface water monitoring data ❑ Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. M Vazquez, P.G. Sr. Technical Consultant (336) 323-0092 Z ility Representati Nalie (Print Title (Area Cod 1 0 CAI t-A-u -L2 Sig 12-D Oak Branch Dr., Greensboro, NC 27407 Facility Representative Address C-0782 NC PE Firm License Number (if applicable effective May 1, 2009) P—i—A a100no Date Telephone Number Aix NC :::;� N e�� y��::.logist Seal •• •; 7 . �. ENSFo SEAL 1862 •;� �: �c Ot 0 ••��'`•A..vP�'��� LaBeLLa Powered by partnership. September 13, 2022 Ms. Jackie Drummond North Carolina Department of Environmental Quality Division of Waste Management, Solid Waste Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Via Email: jaclynne.drummond@ncdenr.gov RE: May 2022 Water Quality Monitoring Report Burke County Kirksey Drive Landfill, Permit No. 12-01 Project No. 2212740 Dear Ms. Drummond: Please find the attached May 2022 Groundwater Monitoring Report for the Burke County Kirksey Drive Landfill (Permit No. 12-01). Attached are electronic versions of the complete report and all appendices for the May 2022 monitoring event. Also attached is the North Carolina Environmental Monitoring Reporting Form and the EQuIS EDD. If you wish to have a hard copy of the report, drawings, or appendices, we will be happy to provide them upon your request. Please feel free to contact me at (336) 323-0092 if you have any questions regarding this report. Respectfully submitted, LaBella Associates Van Burbach, Ph.D., P.G. Sr. Technical Consultant Enclosure cc: Mark Delehant, Burke County 12-D Oak Branch Drive Greensboro, NC 27407 P (336) 323-0092 www.LabeLLapc.com Prepared For: BOARD OF COMMISSIONERS COUNTY OF BURKE P.O. BOX 1486 MORGANTON, NORTH CAROLINA 28680 � gtiHKE yti �Trr cmko Submitted by: LaBella Associates (Joyce Engineering) 12-D Oak Branch Drive Greensboro, NC 27407 (336) 323-00g2 NC License No. C-0782 LaBeRa Powered by partnership. MAY 2022 WATER QUALITY MONITORING REPORT KI RKSEY DRIVE LANDFILL Permit No. 12-01 SEPTEMBER 2022 PROJECT NO. 2212740 May 2022 Water Quality Monitoring Report Kirksey Drive Landfill Burke County, North Carolina TABLE OF CONTENTS 1.0 INTRODUCTION.............................................................................................................................1 1.1 Site Information.............................................................................................................................1 1.2 Site Geology.....................................................................................................................................1 1.3 Regulatory Status............................................................................................................................1 2.0 FACILITY MONITORING PROGRAM...............................................................................................2 2.1 Groundwater Monitoring Program.................................................................................................2 2.2 Surface Water Monitoring Program...............................................................................................2 3.0 MAY 2022 MONITORING EVENT..................................................................................................3 3.1 Field Work........................................................................................................................................3 3.2 Laboratory Analysis and Quality Control........................................................................................3 4.0 HYDROGEOLOGY..........................................................................................................................4 5.0 DATA ANALYSIS.............................................................................................................................5 5.1 Analytical Results and Comparison to Standards.........................................................................5 5.1.1 Groundwater........................................................................................................................5 5.1.2 Surface Water.......................................................................................................................6 6.0 CONCLUSION................................................................................................................................7 7.0 REFERENCES................................................................................................................................7 Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2022 Water Quality Monitoring Report September 2022 May 2022 Water Quality Monitoring Report Kirksey Drive Landfill Burke County, North Carolina TABLE OF CONTENTS CONTINUED Tables Table 1 Groundwater Elevations (May 2022) Table 2 Hydraulic Gradients and Velocities (May 2022) Table 3 Detected Constituents (May 2022) Table 4 Exceedances of Standards (May 2022) Table 5 Field Parameters (May 2022) Figure Figure 1 Site Location Map Drawing Drawing 1 Groundwater Potentiometric Surface Map (May 2022) Appendices Appendix 1 Laboratory Analytical Reports and Field Logs Appendix 2 Historical Data Table A2-1 Historical Groundwater Elevations Table A2-2 Historical Groundwater Constituents Table A2-3 Historical Groundwater Field Parameters Table A2-4 Historical Surface Water Constituents Table A2-5 Historical Surface Water Field Parameters Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2022 Water Quality Monitoring Report September 2022 1.0 INTRODUCTION 1.1 Site Information The Kirksey Drive Sanitary Landfill, Permit No. 12-01, is located in Burke County, North Carolina, approximately two miles northwest of downtown Morganton, North Carolina. The Landfill is on Kirksey Drive, which is accessed by U.S. Highway 70 (Figure 1). The landfill was operated by Burke County as a municipal solid waste (MSW) landfill between 1968 and 1985 but has been closed since 1985. 1.2 Site Geology The Kirksey Drive Landfill is located in the Inner Piedmont Belt of the Piedmont Physiographic Province in western North Carolina. The Inner Piedmont Belt is separated from the Blue Ridge Belt to the northwest by the Brevard Fault Zone and from the Charlotte and Milton Belts to the east by the Kings Mountain Shear Zone. The Inner Piedmont Belt consists primarily of amphibolite facies metamorphic rock. The rocks are predominantly thinly layered mica schist and biotite gneiss interlayered with lesser amounts of amphibolite, calc-silicate rock, hornblende gneiss, quartzite, and in rare instances, marble (Goldsmith, et. al., 1989). Protoliths of the Inner Piedmont Belt rocks were mostly sedimentary (greywacke) with intermediate volcanic flows and tuffs. Numerous large and small bodies of granite and granodiorite and a few quartz diorite bodies are scattered throughout the Inner Piedmont. The history of emplacement of igneous intrusives and of structural deformation in the Inner Piedmont is complex. The rocks have been extensively folded, sheared, and faulted. Granite dikes and larger granite masses have been emplaced along shear zones and discordances. A major east -west trending lineament coincides with the course of the Catawba River in Caldwell, Burke, and Alexander Counties, but no offset has been documented. According to Goldsmith et al. (1978), the site is located in an area underlain by a rock unit comprised of gneisses and schists of various compositions, calc-silicates, and felsic metavolcanics. This unit occupies the nose of a northeast -plunging broad synclinal feature, surrounded by a unit mapped as foliated -to -massive migmatitic granitic gneiss with biotite gneiss and amphibolite, approximately three miles to the northwest and one mile to the south. Map patterns suggest that regional metamorphic foliation near the site would be generally east -west, with gentle dips. Outcrop foliations are likely to have steeper dips, with northeast -trending strikes parallel to the map -scale folds shown on the regional map of Goldsmith, et al. Approximately three miles to the east of the site is a small area around Rhodhiss Lake that has been mapped as metamorphosed granitic rock. A major diabase dike system, oriented northwest -southeast, has been mapped over a distance of more than 40 miles and passes approximately two miles to the northeast of the site. 1.3 Regulatory Status The landfill is regulated under Rules .0500 and .0600 of the North Carolina Solid Waste Management Regulations (NCSWMR) for MSW landfills closed prior to October 9, 1993. The Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2022 Water Quality Monitoring Report September 2022 County monitors groundwater at the landfill in accordance with criteria set forth in Rule .0600 of the NCSWMR. 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program Groundwater monitoring at the Kirksey Drive Landfill is completed in accordance with the monitoring requirements of Rule .0600 of the NCSWMR. Eight active groundwater monitoring wells comprise the groundwater monitoring network at the Kirksey Drive Landfill and groundwater samples are collected semiannually. The current compliance network consists of the following monitoring wells: MW-1 (background), MW-2, MW-3D, MW-3S, MW- 4, MW-5, MW-6D, and MW-6S. Well classification and monitored geologic unit of the upper most aquifer is summarized in the table below. A site plan indicating the facility and waste boundaries in addition to monitoring well locations can be found in Drawing 1. All monitoring wells are monitored the constituents listed in Appendix I of 40 CFR Part 258 (NC Appendix 1) plus 1,4-dioxane. Monitorin g Well Date Installed Classificatio n Monitorin g Program Total Depth from TOC (feet) Lithology of Screened Interval MW-1 1992 Background .0600 35.65 Saprolite MW-2 1992 Compliance .0600 45.70 Saprolite MW-3D Feb.27, Compliance .0600 78.40 Bedrock 1998 MW-3S 1992 Compliance .0600 26.69 Bedrock MW-4 Feb.24, Compliance .0600 29.50 Saprolite 1998 MW-5 Feb.24, Compliance .0600 49.80 Saprolite 1998 MW-6D Apr. 7, 2000 Compliance .0600 60.00 Bedrock MW-6S Apr. 6, 2000 Compliance .0600 25.00 Saprolite 2.2 Surface Water Monitoring Program Surface water monitoring at the Kirksey Drive Landfill is completed in accordance with the monitoring requirements of Rule .0600 of the NCSWMR. Three surface water monitoring points (SMP-1, SMP-2, and SMP-3) comprise the surface water monitoring program for the Kirksey Drive Landfill. The locations of the monitoring points are shown on Drawing 1. The INC Division of Water Resources has classified the surface water at the Kirksey Drive landfill as water supply WS-IV. All surface water monitoring points are monitored semiannually for the INC Appendix I list of constituents plus 1,4-dioxane. Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2022 Water Quality Monitoring Report September 2022 2 Surface Point Classification Monitoring Location Program SW-1 (SMP-1) Compliance .0600 Upstream of bridge on Quarry Rd. SW-2 (SMP-2) Compliance .0600 Downstream of SW-3 SW-3 (SMP-3) Compliance .0600 24" pipe @ base of landfill along river 3.0 MAY 2022 MONITORING EVENT 3.1 Field Work On May 17, 2022, personnel from LaBella visited the Kirksey Drive Landfill to purge and sample monitoring wells MW-1, MW-2, MW-3D, MW-3S, MW-4, MW-5, MW-6D, and MW-6S and collect surface water samples from surface water monitoring points SMP-1, SMP-2, and SMP-3 (May 2022 Monitoring Event). Depth -to -water measurements were obtained to the nearest 0.01 foot using an electronic water level indicator for all monitoring wells in the compliance network prior to purging. Groundwater elevations for the May 2022 monitoring event can be found in Table 1. Monitoring wells were purged using either disposable bailers or a 12-volt submersible pump. Measurements of temperature, pH, specific conductivity, dissolved oxygen, oxidation- reduction potential, and turbidity were recorded in the site logbook and on field log forms prior to purging, after each purge volume, and at the time of sampling. Field data logs are included in Appendix 1. Prior to sampling, laboratory -supplied containers were prepared with the following information: • Monitoring well number (completed by field personnel); • Date and time of sample collection (completed by field personnel); • Initials of sampling personnel (completed by field personnel); • Project name and number (completed by the laboratory); • Chemical preservative (completed by the laboratory); and • Requested chemical analysis (completed by the laboratory). Groundwater samples from each monitoring well were collected either directly from the disposable bailers or directly from the pump discharge tube in the provided laboratory containers either immediately after purging or within 24 hours of the final purge volume. Immediately after collection, the samples were placed on ice in a cooler. Surface monitoring points SW-1, SW-2 and SW-3 were sampled during the May 2022 Monitoring Event. The surface water samples were collected directly from the stream by lowering a clean, unpreserved sample container into the stream flow and dispensing the water into laboratory -prepared sample containers. Care was taken to avoid sample -induced turbidity. At the time of sampling, surface water was also measured for temperature, pH, specific conductivity, dissolved oxygen, oxidation-reduction potential, and turbidity and recorded in the site logbook. Immediately after sample collection, the samples were placed on ice in a laboratory -provided cooler. Field sampling logs are provided in Appendix 1. 3.2 Laboratory Analysis and Quality Control The May 2022 groundwater and surface water samples were submitted to Pace Analytical Services, Inc. of Huntersville, North Carolina under chain -of -custody control for analysis. Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2022 Water Quality Monitoring Report September 2022 3 LaBella requested a Level II data report for the final laboratory report. According to laboratory sample receipts, the samples were received by the laboratory in good condition, properly preserved, at proper temperature, and within analysis hold times. The sampling data report was received from Pace Analytical Services on May 19, 2022. The laboratory grade deionized water was not available for the Field Blank, therefore, a Field Blank was not collected by LaBella personnel as part of the sampling event. However, a Trip Blank was prepared by the laboratory to accompany the volatile sampling during shipment. The Trip Blank was analyzed for NC Appendix I VOCs and 1,4-dioxane. Upon receipt of the laboratory data package, the data was reviewed by LaBella personnel for the following: • General typographical errors; • Correct analyses performed and within method specified hold times; • Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate, and Laboratory Control Samples; • Blank qualified data (B-flags); • Detections above the Method Reporting Limits (MRL); • Detections above the 15A NCAC 2L Groundwater Standards (NC2L), 15A NCAC 2B Surface Water Standards (NC2B), or NC In -stream Target Values (ISTV); and • Detections that are above historical levels. A review of the laboratory analytical reports indicated that the laboratory data package was acceptable. The complete analytical data packages and chains -of -custody are included in Appendix 1. 4.0 HYDROGEOLOGY The surficial aquifer is believed to include the regolith and the underlying fractured metamorphic bedrock. The regolith consists of residual soils, saprolite, and highly fractured/weathered metamorphic rock. Beneath the regolith is fractured metamorphic rock that is typically well connected to the regolith but has less porosity and storativity. The fractured bedrock portion of the aquifer tends to be more heterogeneous and anisotropic than the regolith. Groundwater discharges into Hunting Creek to the east of the site, which flows northward to the Catawba River. A groundwater potentiometric surface map, developed from static water level data obtained in May 2022, is presented as Drawing 1. Horizontal groundwater gradients along representative flow paths were estimated from the May 2022 groundwater contours shown on Drawing 1 and are summarized in Tabie 2. Horizontal gradients across the site ranged from 0.0391 to 0.0629, with an average of approximately 0.0486. Linear groundwater flow velocities for wells screened in saprolite were computed using the modified Darcy equation: V = KI/ne. Where: Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2022 Water Quality Monitoring Report September 2022 4 V = average linear velocity; K = hydraulic conductivity; i = horizontal hydraulic gradient; and ne = effective porosity. The mean of hydraulic conductivities from slug -tests conducted at the Burke County John's River facility (K = 3.28 ft/day) was used in these calculations, along with an estimated effective porosity of ne = 0.20 (20%) for regolith. The estimated linear groundwater flow velocity under the facility ranged from 234 to 377 feet/year, with an average flow velocity of approximately 291 feet/year (Table 2). Because of our conservative estimate of effective porosity, actual groundwater velocities may be significantly less than those calculated. Also, the modified Darcy equation makes the simplifying assumptions of a homogeneous and isotropic aquifer, which may yield inaccurate results when applied to heterogeneous and/or anisotropic conditions such as are believed to exist at this site. Migration of groundwater contaminants are expected to follow the general groundwater flow paths and there are no known barriers to groundwater flow that could significantly affect plume migration or the effectiveness of the groundwater monitoring network to monitoring plume migration. The current groundwater monitoring network remains sufficient for monitoring the groundwater at this facility. 5.0 DATA ANALYSIS 5.1 Analytical Results and Comparison to Standards 5.1.1 Groundwater Inorganic and organic constituents detected in the groundwater during the May 2022 Monitoring Event are listed in Table 3. Results with quantified concentrations above their respective NC21- are presented in Table 4. Field parameter data from the May 2022 event are summarized in Table 5. Historically detected groundwater constituents can be found in Appendix 2 (Table A2-2), and historical groundwater field parameters can be found in Appendix 2 (Table A2-3). During the May 2022 monitoring event, the inorganic constituents detected at quantified concentrations above the MRL in the groundwater samples included: • barium (MW-1,MW-2, MW-3D, MW-3S, MW-4, MW-5, MW-6D, and MW-6S); • cobalt (MW-1, MW-2, MW-3S); • nickel (MW-2, MW-3D); • zinc (MW-1) • vanadium (MW-2, MW-3S, MW-4, MW-5). The inorganic constituents detected at quantified concentrations in exceedance of their respective NC21- during the May 2022 Monitoring Event include: • barium (MW-2); and Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2022 Water Quality Monitoring Report September 2022 5 • cobalt (MW-1, MW-2, and MW-3S). The organic constituents detected in groundwater monitoring wells at quantified concentrations above the MRL in the groundwater samples included: • benzene (MW-2, MW-3D, MW-3S); • chlorobenzene (MW-2, MW-3D, MW-3S); • chloroethane (MW-3S); • 1,1-dichloroethane (MW-3D); • 1,2-dichlorobenzene (MW-2); • 1,4-dichlorobenzene (MW-2, MW-3D, MW-3S); • cis-1,2-dichlorethene (MW-3D, MW-4); • 1,4-dioxane (MW-2, MW-31D, MW-3S); • ethylbenzene (MW-2); • tetrachloroethene (MW-3D); • trichloroethene (MW-3D); • toluene (MW-2); • vinyl chloride (MW-3D); and • xylene (MW-2, MW-3S). The organic constituents detected at quantified concentrations in exceedance of their respective NC21- during the May 2022 Monitoring Event include: • benzene (MW-2, MW-31D, MW-3S); • 1,4-dichlorobenzene (MW-2, MW-3S); • 1,4-dioxane (MW-2, MW-31D, MW-3S); • tetrachloroethene (MW-3D); • trichloroethene (MW-3D); and • vinyl chloride (MW-3D). In general, these results are consistent with historical data for the site (Appendix 2, Table A2- 2). 5.1.2 Surface Water Constituents detected in the surface water during the May 2022 monitoring event are presented in Table 3. Historically detected surface water constituents can be found in Appendix 2 (Table A2-4), and historical surface water field parameters can be found in Appendix 2 (Table A2-5). Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2022 Water Quality Monitoring Report September 2022 6 Barium was the only constituent detected at quantified concentrations above the MRL in any of the surface water samples during the May 2022 Monitoring Event. The NC Division of Water Resources has classified the surface water at the Kirksey Drive landfill as Water Supply IV. There were no organic or inorganic constituents detected at quantified concentrations above their respective NC213 Standards or ISTV for class WS-IV waters during this sampling event. L�L�*[9L The Burke County Kirksey Drive Landfill will continue monitoring groundwater in accordance with criteria set forth in Rules .0500 and .0600 of the NCSWMR for MSW landfills closed prior to October 9, 1993. The next scheduled semiannual sampling event is tentatively scheduled for November 2022. 7.0 REFERENCES Goldsmith, R., Milton, D.J., and Wilson, F.A., 1978, Preliminary geologic map, geologic map index, and annotated bibliography, Charlotte 1x2 degree sheet, North and South Carolina, U.S.G.S. Open File Report 78-590. Goldsmith, R., Milton, D.J., and Horton J.W., 1989, Geology of the Charlotte 1x2 degree quadrangle, in Gair, J.E., eds., Mineral resources of the Charlotte 1x2 degree quadrangle, North and South Carolina: U.S.G.S. Professional Paper 1462. Harned, Douglas A., 1989, The Hydrogeologic Framework and a Reconnaissance of Ground Water Quality in the Piedmont Province of North Carolina, U.S. Geological Survey, Water Resources Investigations Report 88-4130 Heath, R.C., 1989, The Piedmont ground -water system, in Ground Water in the Piedmont; Edited by Daniel, C.,White, R., and Stone, P., Proceedings published by Clemson University, pp. 1-13. Joyce Engineering, Inc., October 29, 1999. Water Quality Assessment Plan. Prepared for Burke County Kirksey Drive Landfill. LeGrand, Harry E. Sr., 1989, A Conceptual Model of Ground Water Settings in the Piedmont Region, Conference on Ground Water in the Piedmont, Charlotte, North Carolina North Carolina Dept. Environment, Health, and Natural Resources (NCDEHNR), 1995, N.C. Water Quality Monitoring Guidance Document for Solid Waste Facilities. Sumsion, C.T., and Laney, R.L., 1967, Geology and ground -water resources of the Morganton area North Carolina, N.C. Department of Water Resources, Ground Water Bulletin No. 12, p. 119 Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2022 Water Quality Monitoring Report September 2022 TABLES Table 1 Table 2 Table 3 Table 4 Table 5 Groundwater Elevations (May 2022) Hydraulic Gradients and Velocities (May 2022) Detected Constituents (May 2022) Exceedances of Standards (November y 2021) Field Parameters (May 2022) TABLE 1: Groundwater Elevations (May 2022) Location TOC Elevation (Ft-AMSL) Depth to Groundwater (Ft-BTOC) Lithology Well Depth (Ft-BTOC) Groundwater Elevation (Ft-AMSL) MW-1 1119.82 31.68 Saprolite 35.51 1088.14 MW-2 1077.23 26.54 Saprolite 45.25 1050.69 MW-3S 1022.76 6.11 Bedrock 26.95 1016.65 MW-3D 1021.90 0.00 Bedrock 76.15 1021.90 MW-4 1054.99 22.10 Saprolite 29.60 1032.89 MW-5 1137.43 39.67 Saprolite 50.80 1097.76 MW-6S 1065.00 10.31 Bedrock 27.56 1054.69 MW-6D 1065.00 12.8 Saprolite 63.15 1052.20 Notes: TOC = Top of casing Ft-BTOC = Feet below TOC Ft-AMSL = Feet above mean sea level Water Levels measured November 17, 2022 --- = well damaged, not sampled. Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 TABLE 2: Hydraulic Gradients and Velocities (May 2022) Water Levels Measured: November 1-2, 2021 GRADIENT CALCULATION SEGMENT FLOW LINE LENGTH (feet) FLOW DIRECTION GROUNDWATER ELEVATION (feet) HORIZONTAL GRADIENT 1 HYDRAULIC CONDUCTIVITY K (feet/day) EFFECTIVE POROSITY n LINEAR VELOCITY V (feet/year) 1095 11 1,271 E 0.0629 3.28E+00 0.20 377 1015 1085 12 1,278 SE 0.0391 3.28E+00 0.20 234 1035 AVERAGE: 10.0486 _JFAVERAGE: 291 Notes: The mean of Kestimates from individual well Is tests from the Burke Co. John's River facility was used to calculate the hydraulic conductivity. Velocity: V= Kiln; assumes homogeneous isotropic porous aquifer and an effective porosity of 20% (0.20). Gradient segments based on the December 03, 2018 groundwater potentiometric surface map (Drawing 1). Burke County, Kirksey Drive Landfill Permit No. 12-01 LaBella Associates TABLE 3: Detected Constituents (May 2022) SAMPLE ID PARAMETER RESULT METHOD I MDL MRL STANDARD SOURCE UNITS COLLECT DATE Groundwater Barium 91.9 EPA 6020E 0.67 5 700 NC 2L µg/L Cobalt 9.7 EPA 6020E 0.39 5 1 NC 2L µg/L 1201-MW1 Copper 2.4 J EPA 6020E 1 5 1000 NC 2L µg/L 5/17/2022 Nickel 1.9 J EPA 6020E 0.71 5 100 NC 2L µg/L Zinc 81.5 EPA 6020E 7 10 1000 NC 2L µg/L Acetone 15.1 J EPA 8260D 5.1 25 6000 NC 2L µg/L Barium 1620 EPA 6020B 3.4 25 700 NC 2L µg/L Chromium 1.5 J EPA 6020E 1.1 5 10 NC 2L µg/L Cobalt 114 EPA 6020B 0.39 5 1 NC 2L µg/L Nickel 18.8 EPA 6020E 0.71 5 100 NC 2L µg/L 1,1-Dichloroethane 0.38 J EPA 8260D 0.37 1 6 NC 2L µg/L 1,2-Dichlorobenzene 2.2 EPA 8260D 0.34 1 20 NC 2L µg/L 1201-MW2 1,4-Dichlorobenzene 37.5 EPA 8260D 0.33 1 6 NC 2L µg/L 5/17/2022 1,4-Dioxane (p-Dioxane) 275 EPA 8260D Mod. 4.3 10 3 NC 2L µg/L Benzene 7.6 EPA 8260D 0.34 1 1 NC 2L µg/L Chlorobenzene 27.2 EPA 8260D 0.28 1 50 NC 2L µg/L Ethylbenzene 8.4 EPA 8260D 0.3 1 600 NC 2L µg/L Toluene 1 EPA 8260D 0.48 1 600 NC 2L µg/L Xylene (Total) 16 EPA 8260D 0.34 1 500 NC 2L µg/L Barium 177 EPA 6020E 0.67 5 700 NC 2L µg/L Cadmium 0.12 J EPA 6020E 0.11 0.5 2 NC 2L µg/L Cobalt 1.1 J EPA 6020E 0.39 5 1 NC 2L µg/L Nickel 27 EPA 6020E 0.71 5 100 NC 2L µg/L 1,1-Dichloroethane 4.4 EPA 8260D 0.37 1 6 NC 2L µg/L 1,2-Dichloropropane 0.75 J EPA 8260D 0.36 1 0.6 NC 2L µg/L 1,4-Dichlorobenzene 3.8 EPA 8260D 0.33 1 6 NC 2L µg/L 1201-MW3D 1,4-Dioxane (p-Dioxane) 95.9 EPA 8260D Mod. 1.7 4 3 NC 2L µg/L 5/17/2022 Benzene 1.4 EPA 8260D 0.34 1 1 NC 2L µg/L Chlorobenzene 9 EPA 8260D 0.28 1 50 NC 2L µg/L cis-1,2-Dichloroethene 22.1 EPA 8260D 0.38 1 70 NC 2L µg/L Tetrachloroethene 9.1 EPA 8260D 0.29 1 0.7 NC 2L µg/L Trichloroethene 6.4 EPA 8260D 0.38 1 3 NC 2L µg/L Vinyl chloride 1.1 EPA 8260D 0.39 1 0.03 NC 2L µg/L Barium 412 EPA 6020B 0.67 5 700 NC 2L µg/L Beryllium 0.1 J EPA 6020E 0.054 0.5 4 NC 2L µg/L Cadmium 0.26 J EPA 6020E 0.11 0.5 2 NC 2L µg/L Chromium 1.6 J EPA 6020E 1.1 5 10 NC 2L µg/L Cobalt 15.8 EPA 6020E 0.39 5 1 NC 2L µg/L Copper 3.4 J EPA 6020E 1 5 1000 NC 2L µg/L Nickel 4.3 J EPA 6020E 0.71 5 100 NC 2L µg/L Vanadium 2.3 J EPA 6020E 1.9 10 7 NC 2L µg/L 1201-MW3S Zinc 7.3 J EPA 6020E 7 10 1000 NC 2L µg/L 5/17/2022 1,2-Dichlorobenzene 0.54 J EPA 8260D 0.34 1 20 NC 2L µg/L 1,4-Dichlorobenzene 10.6 EPA 8260D 0.33 1 6 NC 2L µg/L 1,4-Dioxane (p-Dioxane) 23.2 EPA 8260D Mod. 0.86 2 3 NC 2L µg/L Benzene 3.7 EPA 8260D 0.34 1 1 NC 2L µg/L Chlorobenzene 33.8 EPA 8260D 0.28 1 50 NC 2L µg/L Chloroethane 1.1 EPA 8260D 0.65 1 3000 NC 2L µg/L Ethylbenzene 0.42 J EPA 8260D 0.3 1 600 NC 2L µg/L Xylene (Total) 43.1 EPA 8260D 0.34 1 500 NC 2L µg/L Barium 71.6 EPA 6020E 0.67 5 700 NC 2L µg/L Beryllium 0.061 J EPA 6020E 0.054 0.5 4 NC 2L µg/L 1201-MW4 Chromium 1.2 J EPA 6020E 1.1 5 10 NC 2L µg/L 5/17/2022 Cobalt 0.76 J EPA 6020E 0.39 5 1 NC 2L µg/L Nickel 1.7 J EPA 6020E 0.71 5 100 NC 2L µg/L 1,1-Dichloroethane 0.39 J EPA 8260D 0.37 1 6 NC 2L µg/L cis-1,2-Dichloroethene 2.6 1 EPA 8260D 0.38 1 70 NC 2L µg/L Burke Co. - Kirksey Dr. Landfill Permit # 12-01 Page 1 of 2 LaBella Associates TABLE 3: Detected Constituents (May 2022) SAMPLE ID PARAMETER RESULT METHOD MDL MRL STANDARD SOURCE UNITS COLLECT DATE Barium 26.7 EPA 6020E 0.67 5 700 NC 2L µg/L 1201-MWS Beryllium 0.064 J EPA6020B 0.054 0.5 4 NC 2L µg/L 5/17/2022 Cobalt 0.47 J EPA 6020E 0.39 5 1 NC 2L µg/L 1201-MW6D Barium 12.1 EPA 6020E 0.67 5 700 NC 2L µg/L 5/17/2022 Barium 38.9 EPA 6020B 0.67 5 700 NC 2L µg/L 1201-MW6S Cobalt 0.88 J EPA 6020E 0.39 5 1 NC 2L µg/L 5/17/2022 Chloroform 0.89 J EPA 8260D 0.43 1 70 NC 2L µg/L Surface Water Barium 34.2 EPA 6020E 0.67 5 21000 ISTV µg/L 1201-SW1 Vanadium 2.5 J EPA6020B 1.9 10 NE NE µg/L 5/17/2022 Barium 30.9 EPA 6020E 0.67 5 21000 ISTV µg/L 1201-SW2 Vanadium 2.9 J EPA 6020E 1.9 10 NE NE µg/L 5/17/2022 Barium 34.2 EPA 6020E 0.67 5 21000 ISTV µg/L 1201-SW3 Vanadium 3.2 J EPA 60206 1.9 10 NE NE /L 5/17/2022 Notes: pg/L= micrograms per liter. NC2L = NC Groundwater Standard from 15A NCAC 2L.0202 MDL = Method Detection Limit NUB = NC Surface Water Standard from15A NCAC 2B MRL = Method Reporting Limit ISTV = NC In -Stream Target Values J = Estimated concentration below the MRL Bold = Quantified detections above the Standard Burke Co. - Kirksey Dr. Landfill Permit # 12-01 Page 2 of 2 LaBella Associates TABLE 4: Exceedances of Standards (May 2022) SAMPLE ID PARAMETER RESULT METHOD I MDL MRL STANDARD SOURCE UNITS COLLECT DATE Groundwater 1201-MW1 Cobalt 9.7 EPA 6020E 0.39 5 1 NC 2L µg/L 5/17/2022 1201-MW2 Barium 1620 EPA 6020E 3.4 25 700 NC 2L µg/L 5/17/2022 Cobalt 114 EPA 6020E 0.39 5 1 NC 2L µg/L 1,4-Dichlorobenzene 37.5 EPA 8260D 0.33 1 6 NC 2L µg/L 1,4-Dioxane (p-Dioxane) 275 EPA 8260D Mod. 4.3 10 3 NC 2L µg/L Benzene 7.6 EPA 8260D 0.34 1 1 NC 2L µg/L 1201-MW3D 1,4-Dioxane (p-Dioxane) 95.9 EPA 8260D Mod. 1.7 4 3 NC 2L µg/L 5/17/2022 Benzene 1.4 EPA 8260D 0.34 1 1 NC 2L µg/L Tetrachloroethene 9.1 EPA 8260D 0.29 1 0.7 NC 2L µg/L Trichloroethene 6.4 EPA 8260D 0.38 1 3 NC 2L µg/L Vinyl chloride 1.1 EPA 8260D 0.39 1 0.03 NC 2L µg/L 1201-M W3S Cobalt 15.8 EPA 6020E 0.39 5 1 NC 2L µg/L 5/17/2022 1,4-Dichlorobenzene 10.6 EPA 8260D 0.33 1 6 NC 2L µg/L 1,4-Dioxane (p-Dioxane) 23.2 EPA 8260D Mod. 0.86 2 3 NC 2L µg/L Benzene 3.7 EPA 8260D 0.34 1 1 NC 2L µg/L Notes: pg/L= micrograms per liter. MDL = Method Detection Limit MRL = Method Reporting Limit NC21L = NC Groundwater Standard from 15A NCAC 2L.0202 Burke Co. Kirksey Dr. Landfill Permit # 12-01 La Bella Associates TABLE 5: Field Parameters (May 2022) Parameter Units Sample Date GW Upgradient Groundwater Downgradient Surface Water MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D SW-1 SW-2 SW-3 Well Depth Ft. 5/17/2022 35.51 45.25 26.95 76.15 29.60 50.8 27.56 63.15 -- -- -- pH S.U. 5/17/2022 5.86 5.95 6.12 6.29 6.64 6.69 6.34 6.21 6.99 6.99 7.10 Temperature °C 5/17/2022 16.50 17.1 16.7 16.9 16.9 17.6 14.6 15.4 20.2 19.5 19.9 Conductivity pS/cm 5/17/2022 4420 2781 881 890 99.3 19.7 77.3 109.9 92 110.3 112.9 Dissolved Oxygen mg/L 5/17/2022 5.24 2.33 1.89 5.09 7.1 9.63 7.92 1.71 6.47 7.3 6.72 Oxidation Reduction Potential my 5/17/2022 163.40 76.1 51.1 62.2 116.4 121.5 138 115.3 87.6 94.9 45.5 Turbidity NTU 5/17/2022 26.10 576 14.7 2.54 10.3 26.1 7.8 2.65 9.94 11.60 8.30 Static Water Level Ft. 5/17/2022 31.68 26.54 6.11 0.00 22.10 39.67 10.31 12.8 -- -- -- Notes: °C = degrees Centigrade S.U. = Standard Units pS/cm = microSemens per centimeter my = millivolts NTU = Nephelometric Turbidity Units Ft = feet NS = Not sampled due to broken casing Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 FIGURE Figure 1 Site Location Map ------ tj 16V 1000 CP APPROXIMATE LOCATION OF PROPERTY LINE i---------- rx X, IF lef' 44,0 .10410 ISSUED FOR: 03 LaBeRa GROUNDWATER MONITORING REPORT Powered by partnership. DRAWING NAME: DRAWN BY: DATE: PROJECT NO.: SITE LOCATION MAP RVVH 02/27/19 2192621 2211 WEST MEADOW'VIEW ROAD GREENSBORO, N.C. 27407 PHONE: (336) 323-0092 PROJECT NAME: DRAWING NUMBER: KIRKSEY DRIVE LANDFILL 1 labellapc.com (D 2020 LaBella Associates BURKE COUNTY, NORTH CAROLINA N:\Pwgs\Drawhgs—rui­nt\8URKE\GW EVENT MAPS\, SITE LOCATION MAP KIRKSEY DRIVE 2020.4wg DRAWING Drawing 1 Groundwater Potentiometric Surface Map (May 2022) O SMP-joo, / — _'Ileyc �! — _ / - \ � I I LIMITS OF WASTE / /i�� 10506� �=.9 ` \� \\ �03SI \MPSMP-3 0 021 90 1� ' S .0000, GIN51 10 5�J / j i2oi i erg / 00 W-1 8.14/ ALN f A> 11 o97i6_ 709 �Od, \ \��� i / / 706� — _ �pss LEGEND NOTES 1. TOPOGRAPHIC CONTOUR INTERVAL = 20 FEET. I 1 MW-6S • 1054.69 MW-6D — — _ 052.20 7oQi - GRAPHI� SCALE 0 150 / 600 (FEET) 1080 EXISTING 100' TOPOGRAPHIC CONTOUR EXISTING ROAD 2• GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET. EXISTING 20' TOPOGRAPHIC CONTOUR APPROXIMATE LIMITS OF WASTE 3. STATIC WATER LEVELS MEASURED ON MAY 17, 2022. GROUNDWATER SURFACE CONTOUR [FEET CENTERLINE OF STREAM GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION 1080 — — — — — ABOVE MEAN SEA LEVEL (AMSL)] COMPLIANCE WELL LOCATION AND 4. BETWEEN AND EXTRAPOLATION FROM KNOWN DATA, - MW-5 IDENTIFICATION WITH STATIC WATER TOPOGRAPHIC CONTOURS, AND KNOWN FIELD CONDITIONS. PROPERTY LINE ELEV LEVEL ELEVATION (FEET AMSL) GROUNDWATER FLOW PATHWAY USED TO SURFACE MONITORING POINT LOCATION FLOW PATH LENGTH CALCULATE HYDRAULIC GRADIENT SW-2 AND IDENTIFICATION Z1 SEGMENT USED FOR GRADIENT CALCULATION 0 1,271 LF O1,278 LF 2 0.3 LaBella Powered by partnership. 2211 WEST MEADOWVIEW, SUITE 101 GREENSBORO, NC 27407 (336) 323-0092 labellapc.com T T T L F T L -L C 2022 LaBelle Associates KIRKSEY DRIVE LANDFILL BURKE COUNTY, NORTH CAROLINA NO. DATE'. DESCRIPTION. Revisions PROJECT NUMBER: 2212740.00 DRAWN BY: RH REVIEWED BY KE ISSUED FOR: GROUNDWATER REPORT DATE: 07/07/22 DRAWING NAME: PERMIT NO. 12-01 GROUNDWATER POTENTIOMETRIC SURFACE MAP MAY 17, 2022 DRAWING NUMBER: 1 APPENDICES Appendix 1 Field Logs and Laboratory Analytical Reports Appendix 2 Historical Data Appendix 1 Field Logs and Laboratory Analytical Reports DATE: I Y Iu- jl I aPal la ... Tj � K, r k44UND WATER SAMPLING LOG Project Name: Project No. �/Ta k No.: ZZ i Z? q0.0 7 en i Well ID: "�� � �� Sampler(s): Well Location: �C'hnc� ck c4�te� �ti,Era,nc� Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled with: 2 inches 31, feet �5 feet Sf M feet [DTB-DTW] _ gallons _ gallons = I •C6 gallons 0,0 _gallons Other: Other: Depth to Water before Sampling: _ `ZI , I -Z, feet Gallons Time Temp (OC) pH (S.U.) Cond. (pS/cm) Dis.02 (mg/L) ORP (mV) Turb. (NTU) Initials C)•4� ,� ,2 (.00 Date of sample: Before Sampling: 3 , l �� S �� 4`i2V z- 1 ��,N �P• c�! Comments (weather conditions, odor, color, silt, etc.): `S e Signature: Date: QA/QC Sign Off: Date: r, DATE: 2� LaBeUa Povierari by pad,ne.5F, GROUND WATER SAMPLING LOG Project Name: � - I Y Project No. /Task No.: q-LI 0 °� 1- Well ID: W-2 Sampler(s): 1 i 6, 4e, Well Location: D .dr- )F hk I � d ow n QuoarC Rs 0/1 r& Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled witl Depth to Water before Sampling: 2 inches A, -___feet LIT, feet 1 Q. 16 feet [DTB-DTW] gallons gallons -gallons a • gallons '�- feet Gallons Time Temp (OC) pH (S.U.) Cond. (pS/cm) Dis.02 (mg/L) ORP (mV) Turb. (NTU) Initials 1 Ge I 1 �: � �.03 2� s� 31� ' I �• � � . 1� ) J. S . Z 2 q-2) IbW 3 -4 �. Date of sample: Before Sampling: Comments (weather conditions, odor, color, silt, etc.): ."'P A.- 'O--s _'� Z' kLK- Signature: Dat QA/QC Sign Off: Date: No NSL �v V R3 DATE: '-�_ 11 1 f� LaBeUa Az- Povvex-.i bypc fnersh GROUND WATER SAMPLING LOG Project Name: ,1,ii& - ( Project No. /Task No.:-"Z-122�L0 oz.., Well ID: _ IA LU-35 Sampler(s): Well Location: �oc�N Rd �,r� � � j c�,�, �� on Qcrdrr-u Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): 2 inches (• I feet a (c. (og1 feet QV , 6b feet [DTB-DTW] Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 = 3. 3 gallons For 4" Well: WCT X 0.653 gallons For THREE Well Volumes: WV X 3 = . �! _ gallons Actual Amount Purged/Bailed: �'•� gallons Purged with: frai er Pump Other: Sampled with: Depth to Water before Sampling: — feet Gallons Time Temp (°C) pH (S.U.) Cond. (pS/cm) Dis.02 (mg/L) ORP (mV) Turb. (NTU) Initials 11S4 lG g(o l (n IS12 lS`j b,2,5' e>13C3 I G (D. f) Date of sample: SwlPteJ// Before Sampling. Comments (weather conditions, odor, color, silt, etc.):_ Signature: Z , -36hn Date: QA/QC Sign Off: Date: - _75 / 02 %/ Za ZZ. DATE: 57 LaBelLa GROUND WATER SAMPLING LOG Project Name: KW Y < Project No. /Task No.: Well ID: ,o Sampler(s):_ Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled with: 2 inches `T171G feet tb- qQ feet yfeet [DTB-DTW] = gallons gallons = 36Aallons gallons Depth to Water before Sampling: feet Gallons Time Temp (OC) pH (S.U.) Cond. (NS/cm) Dis.02 (mg/L) ORP (mV) Turb. (NTU) Initials 601 3, L J 121 s 1, Date of sample: im6u Before Sampling: Comments (weather conditions, odor, color, silt, etc.): Signature: QA/QC Sign Off: Date: DATE: � aT 0, LaBeRa r.J F10' iNeidby pelf l eE Ship GROUND WATER SAMPLING LOG Project Name: 5& — K, i' IaUA Project No. /Task No.: Well ID: P/1W—LI Sampler(s): Well Location:_FluSh fnounf on , Q'R: RA Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: For 4" Well: For THREE Well Volumes: Actual Amount Purged Purged with: i Sampled with: Depth to Water before WCT X 0.163 WCT X 0.653 WV X 3 ailed: Pum 2 inches L) feet SU feet y feet [DTB-DTW] `�- gallons gallons 31 gallons �(o gallons Other: Other: mpling: 27-.t4Z- feet Gallons Time Temp (°C) pH (S.U.) Cond. (pS/cm) Dis.02 (mVQ ORP (mV) Turb. (NTU) Initials 0 l� 33 i s U q 3 ��4�. 3 413 y r Ll --I-,/ i I V .7- 11�35 6 61/ -3, sa �-3. S'os-- 2 A 1V3�0 1" 3, cp ib&& 1 Sq (apq gq-.3, 41. oq q-7 IyS Date of sample:Before Sampling: �(p �� ���7-f 3 1 L) Comments (weather conditions, odor, color, silt, etc.): e-,S �C.G Signature: QA/QC Sign Off: Date: :�5YZ?/zozz DATE: IT 2, LaBetta GROUND WATER SAMPLING LOG Project Name: K , 5 ProJ /T 'ec No. ask No.: Well ID: ov� Sampler(s): Well Location:- O'V A(-Mcor Ark,, tiQ Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled witt 2 inches 39' (6feet u q ` O(D feet 0 1 13 feet [DTB-DTW] = i gallons _ gallons = S' gallons S' ( gallons Depth to Water before Sampling: 3"I. '75 feet Gallons Time Temp (OC) pH (S.U.) Cond. (pS/cm) Dis.02 (mg/L) ORP (mV) Turb. (NTU) Initials i'M(v I , ► L9t4� 42- 0 5s 6 .3 t �, 10 (3 q, Date of sample: Before Sampling: �7�(3 .% (q.%9 -i 9.6s Comments (weather conditions, odor, color, silt, etc.): t i Signature: _ . Date: - f Z0 QA/QC Sign Off• Date: - Z 71Z0 ZL DATE: 1� 0-l�d B�ll� ,S )/ GROUND WATER SAMPLING LOG Project Name: — Ki r Lsea4 Project No. /Task No.: '22 ) Z"� y Well ID: VW - 6 3 Sampler(s): Well Location: n cacr05-> "SM 14+Fk5e Q( Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) Calculation for One Well Volume (WV): For 2" Well: For 4" Well: For THREE Well Volumes: Actual Amount Puri Purged with: Sampled with: WCT X 0.163 WCT X 0.653 WVX3 2 inches Io.-'; ) feet a 00 feet _IL4-Uq feet [DTB-DTW] gallons gallons _.� gallons .Z gallons Other: Depth to Water before Sampling: (Q• 3) feet Gallons Time Temp (OC) pH (S.U.) Cond. (pS/cm) Dis.02 (mg/L) ORP (mV) Turb. (NTU) Initials 1 3 js) 6,qS 5,2o gc1,,B aq4, z : Ll R04 b, 90 16M 4, te. 3 5 q. a1b A to VS jt.p 5.ca3 /I , ) Ll,�Y- b A� Date of sample: �2 Before Sampling: ,� p I�►% �,3`� W. 01 �•�� �p Comments (weather conditions, odor, color, silt, etc.): r Signature: Date: -C, QA/QC Sign Off: Date: 5 / 27 / zd ` z DATE: S f zZ LaBelLa Povie{,i,; y_pa:tne.ship GROUND WATER SAMPLING LOG Project Name: r3, r Project No. /T sk No.: �2 / Z3-QP �bz WeIIID: MW: Sampler(s): k,, Well Location: Next to Mw-fo5 Well Diameter: 2 inches Initial Depth to Water (DTW): �a.,Qj et Depth to Bottom (DTB): W'0 eet Water Column Thickness (WCT): feet [DTB-DTW] Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled wit[ Depth to Water before Sampling: 4,"6 gallons gallons 3R' 1 gallons •`� gallons feet Gallons Time Temp (OC) pH (S.U.) Cond. (pS/cm) Dis.02 (mg/L) ORP (mV) Turb. (NTU) Initials 0 1--TOC) I b, Z (. 71 1 sto, ) -1, 6S J «. � $q-, b l­!�,v to qf� 11 j3, L1 11gD R � �9 4, 10 �. I--TrT 63 6 Ltq I rs, o Z r, s << r;a la --I Intl 09,�s' Date of sample: Before Sampling: Comments (weather conditions, odor, color, silt, etc.): S Signature: Dat QA/QC Sign Off: Date: SS, �' /Z-7/0OzZ- 0 LaBetta s� - Project Name - Surface Point ID: Sw-y Field Parameters: Time of Sampling: pH: Temperature: Conductivity: Turbidity: DATE: 5 1 2-Z- SURFACE WATER MONITORING LOG -I ►' Project/Tas No.: Z--Z-D oz- Sampler(s): Dissolved Oxygen Oxidation -Reduction Potential '70' Z (aC) 921y (US/CM) �. qq (ntu) q-q (mg/L) O_(o _ (mv) Comments/Sample Description (weather conditions, odor, color, silt, etc.): 40-S SccnM Summary/Sketch of Sampling Lo ion 1 1 Signature: 1-� Date: S� QA/QC Sign Off: Date: 5 Z 7 za z r- P,-., LaBe La DATE: �' SURFACE WATER MONITORING LOG Project Name: Y -Project/Task No.: Surface Point ID:. SU) -2 Sampler(s): Location:"AAIA�_J'wP-� a� Field Parameters: Time of Sampling: �ss pH: Temperature: Conductivity: 0.3 (US/cm) Turbidity: (ntu) Dissolved Oxygen _-4 1 Q (mg/L) Oxidation -Reduction Potential 6 41+ (mv) Comments/Sample Description weather conditions, odor, color, silt, etc.): c _ I Signature:Date: YI2A',1I2-"2_ QA/QC Sign Off: Date:z- P, LaB( tta DATE: SURFACE WATER MONITORING LOG Project Name: — 16 (kkL�—Project/Task No.: Surface Point ID: Sampler(s)• k• Location: Field Parameters: Time of Sampling: 1340 pH: I r �0 Temperature: 1 q (° C) Conductivity: (1 (US/cm) Turbidity: 8• 36 (ntu) Dissolved Oxygen • -3-2- (mg/L) Oxidation -Reduction Potential L451 S� (mv) Comments/Sample Description (weather conditions, odor, color, silt, etc.): 46) "5 a4li Signature: F_. /_V+tx_ Date: C-'7 0 (-2-Z QA/QC Sign Off: Date:_ ?! Z Z- 2q''p.� leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 May 26, 2022 Mr. Van Burbach LaBella Associates, D.P.C. 12-D Oak Branch Drive Greensboro, NC 27407 RE: Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on May 19, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Charlotte • Pace Analytical Services - Peachtree Corners, GA If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Van Burbach, LaBella Associates, DPC Kandice Estes, Labella Associates Miguel Vazquez, Joyce Engineering Elina Wright, LaBella Associates, D.P.C. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 52 lacmnalyfica(' www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Peachtree Corners 110 Technology Pkwy, Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 North Carolina Certification #: 381 South Carolina Certification #: 98011001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Lab ID Sample ID Matrix Date Collected Date Received 92605500001 1201-MW1 Water 05/17/2213:03 05/19/2210:00 92605500002 1201-MW2 Water 05/17/2216:20 05/19/2210:00 92605500003 1201-MW3S Water 05/17/2215:00 05/19/2210:00 92605500004 1201-MW3D Water 05/17/2215:25 05/19/2210:00 92605500005 1201-MW4 Water 05/17/2213:26 05/19/2210:00 92605500006 1201-MW5 Water 05/17/2217:43 05/19/2210:00 92605500007 1201-MW6S Water 05/17/2218:36 05/19/2210:00 92605500008 1201-MW6D Water 05/17/2217:28 05/19/2210:00 92605500009 1201-SW1 Water 05/17/2213:55 05/19/2210:00 92605500010 1201-SW2 Water 05/17/2214:55 05/19/2210:00 92605500011 1201-SW3 Water 05/17/2213:40 05/19/2210:00 92605500012 1201-TRIPBLANK Water 05/17/22 01:00 05/19/22 10:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: BURKE CO KIRKSEY DRIVE 92605500 Analytes Lab lD Sample ID Method Analysts Reported Laboratory 92605500001 1201-MW1 EPA6020B KH 15 PASI-GA EPA 8260D SAS 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92605500002 1201-MW2 EPA6020B CW1, KH 15 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92605500003 1201-MW3S EPA6020B KH 15 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92605500004 1201-MW3D EPA6020B KH 15 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92605500005 1201-MW4 EPA6020B KH 15 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92605500006 1201-MW5 EPA6020B KH 15 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92605500007 1201-MW6S EPA6020B KH 15 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92605500008 1201-MW6D EPA6020B KH 15 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92605500009 1201-SW1 EPA6020B KH 15 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92605500010 1201-SW2 EPA6020B KH 15 PASI-GA EPA 8260D SAS 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92605500011 1201-SW3 EPA6020B KH 15 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92605500012 1201-TRIPBLANK EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C PASI-C = Pace Analytical Services - Charlotte PASI-GA = Pace Analytical Services - Peachtree Corners, GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92605500001 1201-MW1 EPA 6020B Barium 91.9 ug/L 5.0 05/24/22 16:03 EPA 6020B Cobalt 9.7 ug/L 5.0 05/24/22 16:03 EPA 6020B Copper 2AJ ug/L 5.0 05/24/22 16:03 EPA 6020B Nickel 1.91 ug/L 5.0 05/24/22 16:03 EPA 6020B Zinc 81.5 ug/L 10.0 05/24/22 16:03 EPA 8260D Acetone 15.1 J ug/L 25.0 05/21/22 06:45 92605500002 1201-MW2 EPA 6020B Barium 1620 ug/L 25.0 05/26/22 02:19 EPA 6020B Chromium 1.5J ug/L 5.0 05/24/22 16:23 EPA 6020B Cobalt 114 ug/L 5.0 05/24/22 16:23 EPA 6020B Nickel 18.8 ug/L 5.0 05/24/22 16:23 EPA 8260D Benzene 7.6 ug/L 1.0 05/20/22 07:40 EPA 8260D Chlorobenzene 27.2 ug/L 1.0 05/20/22 07:40 EPA 8260D 1,2-Dichlorobenzene 2.2 ug/L 1.0 05/20/22 07:40 EPA 8260D 1,4-Dichlorobenzene 37.5 ug/L 1.0 05/20/22 07:40 EPA 8260D 1,1-Dichloroethane 0.38J ug/L 1.0 05/20/22 07:40 EPA 8260D Ethylbenzene 8.4 ug/L 1.0 05/20/22 07:40 EPA 8260D Toluene 1.0 ug/L 1.0 05/20/22 07:40 EPA 8260D Xylene (Total) 16.0 ug/L 1.0 05/20/22 07:40 EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 275 ug/L 10.0 05/21/22 11:50 92605500003 1201-MW3S EPA 6020B Barium 412 ug/L 5.0 05/24/22 16:29 EPA 6020B Beryllium 0.10J ug/L 0.50 05/24/22 16:29 EPA 6020B Cadmium 0.26J ug/L 0.50 05/24/22 16:29 EPA 6020B Chromium 1.6J ug/L 5.0 05/24/22 16:29 EPA 6020B Cobalt 15.8 ug/L 5.0 05/24/22 16:29 EPA 6020B Copper 3AJ ug/L 5.0 05/24/22 16:29 EPA 6020B Nickel 4.3J ug/L 5.0 05/24/22 16:29 EPA 6020B Vanadium 2.3J ug/L 10.0 05/24/22 16:29 EPA 6020B Zinc 7.3J ug/L 10.0 05/24/22 16:29 EPA 8260D Benzene 3.7 ug/L 1.0 05/20/22 07:21 EPA 8260D Chlorobenzene 33.8 ug/L 1.0 05/20/22 07:21 EPA 8260D Chloroethane 1.1 ug/L 1.0 05/20/22 07:21 EPA 8260D 1,2-Dichlorobenzene 0.54J ug/L 1.0 05/20/22 07:21 EPA 8260D 1,4-Dichlorobenzene 10.6 ug/L 1.0 05/20/22 07:21 EPA 8260D Ethylbenzene 0.42J ug/L 1.0 05/20/22 07:21 EPA 8260D Xylene (Total) 43.1 ug/L 1.0 05/20/22 07:21 EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 23.2 ug/L 2.0 05/21/22 07:40 92605500004 1201-MW3D EPA 6020B Barium 177 ug/L 5.0 05/24/22 16:35 EPA 6020B Cadmium 0.12J ug/L 0.50 05/24/22 16:35 EPA 6020B Cobalt 1.1 J ug/L 5.0 05/24/22 16:35 EPA 6020B Nickel 27.0 ug/L 5.0 05/24/22 16:35 EPA 8260D Benzene 1.4 ug/L 1.0 05/20/22 09:30 EPA 8260D Chlorobenzene 9.0 ug/L 1.0 05/20/22 09:30 EPA 8260D 1,4-Dichlorobenzene 3.8 ug/L 1.0 05/20/22 09:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Lab Sample ID Method Client Sample ID Parameters 92605500004 1201-MW3D EPA 8260D 1,1-Dichloroethane EPA 8260D cis-1,2-Dichloroethene EPA 8260D 1,2-Dichloropropane EPA 8260D Tetrachloroethene EPA 8260D Trichloroethene EPA 8260D Vinyl chloride EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 92605500005 1201-MW4 EPA 6020B Barium EPA 6020B Beryllium EPA 6020B Chromium EPA 6020B Cobalt EPA 6020B Nickel EPA 8260D 1,1-Dichloroethane EPA 8260D cis-1,2-Dichloroethene 92605500006 1201-MW5 EPA 6020B Barium EPA 6020B Beryllium EPA 6020B Cobalt 92605500007 1201-MW6S EPA 6020B Barium EPA 6020B Cobalt EPA 8260D Chloroform 92605500008 1201-MW6D EPA 6020B Barium 92605500009 1201-SW1 EPA 6020B Barium EPA 6020B Vanadium 92605500010 1201-SW2 EPA 6020B Barium EPA 6020B Vanadium 92605500011 1201-SW3 EPA 6020B Barium EPA 6020B Vanadium SUMMARY OF DETECTION Result Units Report Limit Analyzed 4.4 ug/L 1.0 05/20/22 09:30 22.1 ug/L 1.0 05/20/22 09:30 0.75J ug/L 1.0 05/20/22 09:30 9.1 ug/L 1.0 05/20/22 09:30 6.4 ug/L 1.0 05/20/22 09:30 1.1 ug/L 1.0 05/20/22 09:30 95.9 ug/L 4.0 05/21/2211:31 71.6 ug/L 5.0 05/24/2216:41 0.061 J ug/L 0.50 05/24/22 16:41 1.2J ug/L 5.0 05/24/2216:41 0.76J ug/L 5.0 05/24/2216:41 1.7J ug/L 5.0 05/24/2216:41 0.39J ug/L 1.0 05/20/22 09:48 2.6 ug/L 1.0 05/20/22 09:48 26.7 ug/L 5.0 05/24/2216:47 0.064J ug/L 0.50 05/24/2216:47 0.47J ug/L 5.0 05/24/2216:47 38.9 ug/L 5.0 05/24/2216:53 0.88J ug/L 5.0 05/24/2216:53 0.891 ug/L 1.0 05/20/22 08:35 12.1 ug/L 5.0 05/24/2216:59 34.2 ug/L 5.0 05/24/2217:05 2.5J ug/L 10.0 05/24/2217:05 30.9 ug/L 5.0 05/24/2217:11 2.9J ug/L 10.0 05/24/2217:11 34.2 ug/L 5.0 05/24/2217:17 3.2J ug/L 10.0 05/24/2217:17 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Qualifiers Page 6 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-MW1 Lab ID: 92605500001 Collected: 05/17/22 13:03 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 05/24/2210:30 05/24/2216:03 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 05/24/2210:30 05/24/2216:03 7440-38-2 Barium 91.9 ug/L 5.0 0.67 1 05/24/2210:30 05/24/2216:03 7440-39-3 Beryllium ND ug/L 0.50 0.054 1 05/24/2210:30 05/24/2216:03 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 05/24/2210:30 05/24/2216:03 7440-43-9 Chromium ND ug/L 5.0 1.1 1 05/24/2210:30 05/24/2216:03 7440-47-3 Cobalt 9.7 ug/L 5.0 0.39 1 05/24/2210:30 05/24/2216:03 7440-48-4 Copper 2.4J ug/L 5.0 1.0 1 05/24/2210:30 05/24/2216:03 7440-50-8 Lead ND ug/L 1.0 0.89 1 05/24/2210:30 05/24/2216:03 7439-92-1 Nickel 1.91 ug/L 5.0 0.71 1 05/24/2210:30 05/24/2216:03 7440-02-0 Selenium ND ug/L 5.0 1.4 1 05/24/2210:30 05/24/2216:03 7782-49-2 Silver ND ug/L 5.0 0.44 1 05/24/2210:30 05/24/2216:03 7440-22-4 Thallium ND ug/L 1.0 0.18 1 05/24/2210:30 05/24/2216:03 7440-28-0 Vanadium ND ug/L 10.0 1.9 1 05/24/2210:30 05/24/2216:03 7440-62-2 Zinc 81.5 ug/L 10.0 7.0 1 05/24/2210:30 05/24/2216:03 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone 15.1J ug/L 25.0 5.1 1 05/21/22 06:45 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 05/21/22 06:45 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/21/22 06:45 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 05/21/22 06:45 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/21/22 06:45 75-27-4 Bromoform ND ug/L 1.0 0.34 1 05/21/22 06:45 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 05/21/22 06:45 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 05/21/22 06:45 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 05/21/22 06:45 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/21/22 06:45 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 05/21/22 06:45 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 05/21/22 06:45 75-00-3 Chloroform ND ug/L 1.0 0.43 1 05/21/22 06:45 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/21/22 06:45 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 05/21/22 06:45 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 05/21/22 06:45 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 05/21/22 06:45 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 05/21/22 06:45 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 05/21/22 06:45 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 05/21/22 06:45 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 05/21/22 06:45 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 05/21/22 06:45 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/21/22 06:45 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 05/21/22 06:45 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 05/21/22 06:45 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 05/21/22 06:45 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 05/21/22 06:45 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-MW1 Lab ID: 92605500001 Collected: 05/17/22 13:03 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/26/2022 12:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 98 % 70-130 93 % 70-130 106 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 96 % 70-130 90 % 70-130 0.36 1 05/21/22 06:45 10061-01-5 0.36 1 05/21/22 06:45 10061-02-6 0.30 1 05/21/22 06:45 100-41-4 0.48 1 05/21/22 06:45 591-78-6 9.7 1 05/21/22 06:45 74-88-4 2.0 1 05/21/22 06:45 75-09-2 2.7 1 05/21/22 06:45 108-10-1 0.29 1 05/21/22 06:45 100-42-5 0.31 1 05/21/22 06:45 630-20-6 0.22 1 05/21/22 06:45 79-34-5 0.29 1 05/21/22 06:45 127-18-4 0.48 1 05/21/22 06:45 108-88-3 0.33 1 05/21/22 06:45 71-55-6 0.32 1 05/21/22 06:45 79-00-5 0.38 1 05/21/22 06:45 79-01-6 0.30 1 05/21/22 06:45 75-69-4 0.26 1 05/21/22 06:45 96-18-4 1.3 1 05/21/22 06:45 108-05-4 0.39 1 05/21/22 06:45 75-01-4 0.34 1 05/21/22 06:45 1330-20-7 1 05/21/22 06:45 460-00-4 1 05/21/22 06:45 17060-07-0 1 05/21/22 06:45 2037-26-5 0.86 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/21/22 04:27 123-91-1 05/21/22 04:27 17060-07-0 05/21/22 04:27 2037-26-5 IK Page 8 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-MW2 Lab ID: 92605500002 Collected: 05/17/22 16:20 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 05/24/2210:30 05/24/2216:23 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 05/24/2210:30 05/24/2216:23 7440-38-2 Barium 1620 ug/L 25.0 3.4 5 05/24/22 10:30 05/26/22 02:19 7440-39-3 Beryllium ND ug/L 0.50 0.054 1 05/24/2210:30 05/24/2216:23 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 05/24/2210:30 05/24/2216:23 7440-43-9 Chromium 1.5J ug/L 5.0 1.1 1 05/24/2210:30 05/24/2216:23 7440-47-3 Cobalt 114 ug/L 5.0 0.39 1 05/24/2210:30 05/24/2216:23 7440-48-4 Copper ND ug/L 5.0 1.0 1 05/24/2210:30 05/24/2216:23 7440-50-8 Lead ND ug/L 1.0 0.89 1 05/24/2210:30 05/24/2216:23 7439-92-1 Nickel 18.8 ug/L 5.0 0.71 1 05/24/2210:30 05/24/2216:23 7440-02-0 Selenium ND ug/L 5.0 1.4 1 05/24/2210:30 05/24/2216:23 7782-49-2 Silver ND ug/L 5.0 0.44 1 05/24/2210:30 05/24/2216:23 7440-22-4 Thallium ND ug/L 1.0 0.18 1 05/24/2210:30 05/24/2216:23 7440-28-0 Vanadium ND ug/L 10.0 1.9 1 05/24/2210:30 05/24/2216:23 7440-62-2 Zinc ND ug/L 10.0 7.0 1 05/24/2210:30 05/24/2216:23 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 05/20/22 07:40 67-64-1 v2 Acrylonitrile ND ug/L 10.0 1.8 1 05/20/22 07:40 107-13-1 Benzene 7.6 ug/L 1.0 0.34 1 05/20/22 07:40 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 05/20/22 07:40 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/20/22 07:40 75-27-4 Bromoform ND ug/L 1.0 0.34 1 05/20/22 07:40 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 05/20/22 07:40 74-83-9 v2 2-Butanone (MEK) ND ug/L 5.0 4.0 1 05/20/22 07:40 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 05/20/22 07:40 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/20/22 07:40 56-23-5 Chlorobenzene 27.2 ug/L 1.0 0.28 1 05/20/22 07:40 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 05/20/22 07:40 75-00-3 Chloroform ND ug/L 1.0 0.43 1 05/20/22 07:40 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/20/22 07:40 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 05/20/22 07:40 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 05/20/22 07:40 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 05/20/22 07:40 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 05/20/22 07:40 74-95-3 1,2-Dichlorobenzene 2.2 ug/L 1.0 0.34 1 05/20/22 07:40 95-50-1 1,4-Dichlorobenzene 37.5 ug/L 1.0 0.33 1 05/20/22 07:40 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 05/20/22 07:40 110-57-6 1,1-Dichloroethane 0.38J ug/L 1.0 0.37 1 05/20/22 07:40 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/20/22 07:40 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 05/20/22 07:40 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 05/20/22 07:40 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 05/20/22 07:40 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 05/20/22 07:40 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-MW2 Lab ID: 92605500002 Collected: 05/17/22 16:20 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/26/2022 12:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.36 1 05/20/22 07:40 10061-01-5 ND ug/L 1.0 0.36 1 05/20/22 07:40 10061-02-6 8.4 ug/L 1.0 0.30 1 05/20/22 07:40 100-41-4 ND ug/L 5.0 0.48 1 05/20/22 07:40 591-78-6 ND ug/L 20.0 9.7 1 05/20/22 07:40 74-88-4 ND ug/L 5.0 2.0 1 05/20/22 07:40 75-09-2 v2 ND ug/L 5.0 2.7 1 05/20/22 07:40 108-10-1 ND ug/L 1.0 0.29 1 05/20/22 07:40 100-42-5 ND ug/L 1.0 0.31 1 05/20/22 07:40 630-20-6 ND ug/L 1.0 0.22 1 05/20/22 07:40 79-34-5 ND ug/L 1.0 0.29 1 05/20/22 07:40 127-18-4 1.0 ug/L 1.0 0.48 1 05/20/22 07:40 108-88-3 ND ug/L 1.0 0.33 1 05/20/22 07:40 71-55-6 ND ug/L 1.0 0.32 1 05/20/22 07:40 79-00-5 ND ug/L 1.0 0.38 1 05/20/22 07:40 79-01-6 ND ug/L 1.0 0.30 1 05/20/22 07:40 75-69-4 ND ug/L 1.0 0.26 1 05/20/22 07:40 96-18-4 ND ug/L 2.0 1.3 1 05/20/22 07:40 108-05-4 ND ug/L 1.0 0.39 1 05/20/22 07:40 75-01-4 16.0 ug/L 1.0 0.34 1 05/20/22 07:40 1330-20-7 93 % 70-130 1 05/20/22 07:40 460-00-4 86 % 70-130 1 05/20/22 07:40 17060-07-0 100 % 70-130 1 05/20/22 07:40 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 275 ug/L 10.0 4.3 5 05/21/2211:50 123-91-1 103 % 70-130 5 05/21 /22 11:50 17060-07-0 87 % 70-130 5 05/21 /22 11:50 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-MW3S Lab ID: 92605500003 Collected: 05/17/22 15:00 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 05/24/2210:30 05/24/2216:29 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 05/24/2210:30 05/24/2216:29 7440-38-2 Barium 412 ug/L 5.0 0.67 1 05/24/2210:30 05/24/2216:29 7440-39-3 Beryllium 0.10J ug/L 0.50 0.054 1 05/24/2210:30 05/24/2216:29 7440-41-7 Cadmium 0.26J ug/L 0.50 0.11 1 05/24/2210:30 05/24/2216:29 7440-43-9 Chromium 1.6.1 ug/L 5.0 1.1 1 05/24/2210:30 05/24/2216:29 7440-47-3 Cobalt 15.8 ug/L 5.0 0.39 1 05/24/2210:30 05/24/2216:29 7440-48-4 Copper 3.4J ug/L 5.0 1.0 1 05/24/2210:30 05/24/2216:29 7440-50-8 Lead ND ug/L 1.0 0.89 1 05/24/2210:30 05/24/2216:29 7439-92-1 Nickel 4.3.1 ug/L 5.0 0.71 1 05/24/2210:30 05/24/2216:29 7440-02-0 Selenium ND ug/L 5.0 1.4 1 05/24/2210:30 05/24/2216:29 7782-49-2 Silver ND ug/L 5.0 0.44 1 05/24/2210:30 05/24/2216:29 7440-22-4 Thallium ND ug/L 1.0 0.18 1 05/24/2210:30 05/24/2216:29 7440-28-0 Vanadium 2.3J ug/L 10.0 1.9 1 05/24/2210:30 05/24/2216:29 7440-62-2 Zinc 7.3J ug/L 10.0 7.0 1 05/24/2210:30 05/24/2216:29 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 05/20/22 07:21 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 05/20/22 07:21 107-13-1 Benzene 3.7 ug/L 1.0 0.34 1 05/20/22 07:21 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 05/20/22 07:21 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/20/22 07:21 75-27-4 Bromoform ND ug/L 1.0 0.34 1 05/20/22 07:21 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 05/20/22 07:21 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 05/20/22 07:21 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 05/20/22 07:21 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/20/22 07:21 56-23-5 Chlorobenzene 33.8 ug/L 1.0 0.28 1 05/20/22 07:21 108-90-7 Chloroethane 1.1 ug/L 1.0 0.65 1 05/20/22 07:21 75-00-3 Chloroform ND ug/L 1.0 0.43 1 05/20/22 07:21 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/20/22 07:21 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 05/20/22 07:21 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 05/20/22 07:21 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 05/20/22 07:21 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 05/20/22 07:21 74-95-3 1,2-Dichlorobenzene 0.54J ug/L 1.0 0.34 1 05/20/22 07:21 95-50-1 1,4-Dichlorobenzene 10.6 ug/L 1.0 0.33 1 05/20/22 07:21 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 05/20/22 07:21 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 05/20/22 07:21 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/20/22 07:21 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 05/20/22 07:21 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 05/20/22 07:21 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 05/20/22 07:21 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 05/20/22 07:21 78-87-5 REPORT OF LABORATORY ANALYSIS v2 v2 This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-MW3S Lab ID: 92605500003 Collected: 05/17/22 15:00 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/26/2022 12:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 0.42J ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 43.1 ug/L 1.0 94 % 70-130 86 % 70-130 103 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 23.2 ug/L 2.0 86 % 70-130 86 % 70-130 0.36 1 05/20/22 07:21 10061-01-5 0.36 1 05/20/22 07:21 10061-02-6 0.30 1 05/20/22 07:21 100-41-4 0.48 1 05/20/22 07:21 591-78-6 9.7 1 05/20/22 07:21 74-88-4 2.0 1 05/20/22 07:21 75-09-2 v2 2.7 1 05/20/22 07:21 108-10-1 0.29 1 05/20/22 07:21 100-42-5 0.31 1 05/20/22 07:21 630-20-6 0.22 1 05/20/22 07:21 79-34-5 0.29 1 05/20/22 07:21 127-18-4 0.48 1 05/20/22 07:21 108-88-3 0.33 1 05/20/22 07:21 71-55-6 0.32 1 05/20/22 07:21 79-00-5 0.38 1 05/20/22 07:21 79-01-6 0.30 1 05/20/22 07:21 75-69-4 0.26 1 05/20/22 07:21 96-18-4 1.3 1 05/20/22 07:21 108-05-4 0.39 1 05/20/22 07:21 75-01-4 0.34 1 05/20/22 07:21 1330-20-7 1 05/20/22 07:21 460-00-4 1 05/20/22 07:21 17060-07-0 1 05/20/22 07:21 2037-26-5 0.86 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/21 /22 07:40 123-91-1 05/21 /22 07:40 17060-07-0 05/21 /22 07:40 2037-26-5 Page 12 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-MW3D Lab ID: 92605500004 Collected: 05/17/22 15:25 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 05/24/2210:30 05/24/2216:35 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 05/24/2210:30 05/24/2216:35 7440-38-2 Barium 177 ug/L 5.0 0.67 1 05/24/2210:30 05/24/2216:35 7440-39-3 Beryllium ND ug/L 0.50 0.054 1 05/24/2210:30 05/24/2216:35 7440-41-7 Cadmium 0.12.1 ug/L 0.50 0.11 1 05/24/2210:30 05/24/2216:35 7440-43-9 Chromium ND ug/L 5.0 1.1 1 05/24/2210:30 05/24/2216:35 7440-47-3 Cobalt 1.1.1 ug/L 5.0 0.39 1 05/24/2210:30 05/24/2216:35 7440-48-4 Copper ND ug/L 5.0 1.0 1 05/24/2210:30 05/24/2216:35 7440-50-8 Lead ND ug/L 1.0 0.89 1 05/24/2210:30 05/24/2216:35 7439-92-1 Nickel 27.0 ug/L 5.0 0.71 1 05/24/2210:30 05/24/2216:35 7440-02-0 Selenium ND ug/L 5.0 1.4 1 05/24/2210:30 05/24/2216:35 7782-49-2 Silver ND ug/L 5.0 0.44 1 05/24/2210:30 05/24/2216:35 7440-22-4 Thallium ND ug/L 1.0 0.18 1 05/24/2210:30 05/24/2216:35 7440-28-0 Vanadium ND ug/L 10.0 1.9 1 05/24/2210:30 05/24/2216:35 7440-62-2 Zinc ND ug/L 10.0 7.0 1 05/24/2210:30 05/24/2216:35 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 05/20/22 09:30 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 05/20/22 09:30 107-13-1 Benzene 1.4 ug/L 1.0 0.34 1 05/20/22 09:30 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 05/20/22 09:30 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/20/22 09:30 75-27-4 Bromoform ND ug/L 1.0 0.34 1 05/20/22 09:30 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 05/20/22 09:30 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 05/20/22 09:30 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 05/20/22 09:30 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/20/22 09:30 56-23-5 Chlorobenzene 9.0 ug/L 1.0 0.28 1 05/20/22 09:30 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 05/20/22 09:30 75-00-3 Chloroform ND ug/L 1.0 0.43 1 05/20/22 09:30 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/20/22 09:30 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 05/20/22 09:30 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 05/20/22 09:30 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 05/20/22 09:30 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 05/20/22 09:30 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 05/20/22 09:30 95-50-1 1,4-Dichlorobenzene 3.8 ug/L 1.0 0.33 1 05/20/22 09:30 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 05/20/22 09:30 110-57-6 1,1-Dichloroethane 4.4 ug/L 1.0 0.37 1 05/20/22 09:30 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/20/22 09:30 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 05/20/22 09:30 75-35-4 cis-1,2-Dichloroethene 22.1 ug/L 1.0 0.38 1 05/20/22 09:30 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 05/20/22 09:30 156-60-5 1,2-Dichloropropane 0.75J ug/L 1.0 0.36 1 05/20/22 09:30 78-87-5 REPORT OF LABORATORY ANALYSIS v2 v2 This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-MW3D Lab ID: 92605500004 Collected: 05/17/22 15:25 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/26/2022 12:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 9.1 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 6.4 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 1.1 ug/L 1.0 ND ug/L 1.0 93 % 70-130 93 % 70-130 102 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 95.9 ug/L 4.0 105 % 70-130 90 % 70-130 0.36 1 05/20/22 09:30 10061-01-5 0.36 1 05/20/22 09:30 10061-02-6 0.30 1 05/20/22 09:30 100-41-4 0.48 1 05/20/22 09:30 591-78-6 9.7 1 05/20/22 09:30 74-88-4 2.0 1 05/20/22 09:30 75-09-2 v2 2.7 1 05/20/22 09:30 108-10-1 0.29 1 05/20/22 09:30 100-42-5 0.31 1 05/20/22 09:30 630-20-6 0.22 1 05/20/22 09:30 79-34-5 0.29 1 05/20/22 09:30 127-18-4 0.48 1 05/20/22 09:30 108-88-3 0.33 1 05/20/22 09:30 71-55-6 0.32 1 05/20/22 09:30 79-00-5 0.38 1 05/20/22 09:30 79-01-6 0.30 1 05/20/22 09:30 75-69-4 0.26 1 05/20/22 09:30 96-18-4 1.3 1 05/20/22 09:30 108-05-4 0.39 1 05/20/22 09:30 75-01-4 0.34 1 05/20/22 09:30 1330-20-7 1 05/20/22 09:30 460-00-4 1 05/20/22 09:30 17060-07-0 1 05/20/22 09:30 2037-26-5 1.7 2 2 2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/21 /22 11:31 123-91-1 05/21 /22 11:31 17060-07-0 05/21 /22 11:31 2037-26-5 Page 14 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-MW4 Lab ID: 92605500005 Collected: 05/17/22 13:26 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 05/24/2210:30 05/24/2216:41 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 05/24/2210:30 05/24/2216:41 7440-38-2 Barium 71.6 ug/L 5.0 0.67 1 05/24/2210:30 05/24/2216:41 7440-39-3 Beryllium 0.061J ug/L 0.50 0.054 1 05/24/2210:30 05/24/2216:41 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 05/24/2210:30 05/24/2216:41 7440-43-9 Chromium 1.2.1 ug/L 5.0 1.1 1 05/24/2210:30 05/24/2216:41 7440-47-3 Cobalt 0.76J ug/L 5.0 0.39 1 05/24/2210:30 05/24/2216:41 7440-48-4 Copper ND ug/L 5.0 1.0 1 05/24/2210:30 05/24/2216:41 7440-50-8 Lead ND ug/L 1.0 0.89 1 05/24/2210:30 05/24/2216:41 7439-92-1 Nickel 1.7.1 ug/L 5.0 0.71 1 05/24/2210:30 05/24/2216:41 7440-02-0 Selenium ND ug/L 5.0 1.4 1 05/24/2210:30 05/24/2216:41 7782-49-2 Silver ND ug/L 5.0 0.44 1 05/24/2210:30 05/24/2216:41 7440-22-4 Thallium ND ug/L 1.0 0.18 1 05/24/2210:30 05/24/2216:41 7440-28-0 Vanadium ND ug/L 10.0 1.9 1 05/24/2210:30 05/24/2216:41 7440-62-2 Zinc ND ug/L 10.0 7.0 1 05/24/2210:30 05/24/2216:41 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 05/20/22 09:48 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 05/20/22 09:48 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/20/22 09:48 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 05/20/22 09:48 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/20/22 09:48 75-27-4 Bromoform ND ug/L 1.0 0.34 1 05/20/22 09:48 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 05/20/22 09:48 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 05/20/22 09:48 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 05/20/22 09:48 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/20/22 09:48 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 05/20/22 09:48 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 05/20/22 09:48 75-00-3 Chloroform ND ug/L 1.0 0.43 1 05/20/22 09:48 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/20/22 09:48 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 05/20/22 09:48 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 05/20/22 09:48 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 05/20/22 09:48 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 05/20/22 09:48 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 05/20/22 09:48 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 05/20/22 09:48 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 05/20/22 09:48 110-57-6 1,1-Dichloroethane 0.39J ug/L 1.0 0.37 1 05/20/22 09:48 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/20/22 09:48 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 05/20/22 09:48 75-35-4 cis-1,2-Dichloroethene 2.6 ug/L 1.0 0.38 1 05/20/22 09:48 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 05/20/22 09:48 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 05/20/22 09:48 78-87-5 REPORT OF LABORATORY ANALYSIS v2 v2 This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-MW4 Lab ID: 92605500005 Collected: 05/17/22 13:26 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/26/2022 12:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 93 % 70-130 89 % 70-130 101 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 102 % 70-130 91 % 70-130 0.36 1 05/20/22 09:48 10061-01-5 0.36 1 05/20/22 09:48 10061-02-6 0.30 1 05/20/22 09:48 100-41-4 0.48 1 05/20/22 09:48 591-78-6 9.7 1 05/20/22 09:48 74-88-4 2.0 1 05/20/22 09:48 75-09-2 v2 2.7 1 05/20/22 09:48 108-10-1 0.29 1 05/20/22 09:48 100-42-5 0.31 1 05/20/22 09:48 630-20-6 0.22 1 05/20/22 09:48 79-34-5 0.29 1 05/20/22 09:48 127-18-4 0.48 1 05/20/22 09:48 108-88-3 0.33 1 05/20/22 09:48 71-55-6 0.32 1 05/20/22 09:48 79-00-5 0.38 1 05/20/22 09:48 79-01-6 0.30 1 05/20/22 09:48 75-69-4 0.26 1 05/20/22 09:48 96-18-4 1.3 1 05/20/22 09:48 108-05-4 0.39 1 05/20/22 09:48 75-01-4 0.34 1 05/20/22 09:48 1330-20-7 1 05/20/22 09:48 460-00-4 1 05/20/22 09:48 17060-07-0 1 05/20/22 09:48 2037-26-5 0.86 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/21 /22 07:59 123-91-1 05/21 /22 07:59 17060-07-0 05/21 /22 07:59 2037-26-5 Page 16 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-MW5 Lab ID: 92605500006 Collected: 05/17/22 17:43 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 05/24/2210:30 05/24/2216:47 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 05/24/2210:30 05/24/2216:47 7440-38-2 Barium 26.7 ug/L 5.0 0.67 1 05/24/2210:30 05/24/2216:47 7440-39-3 Beryllium 0.064J ug/L 0.50 0.054 1 05/24/2210:30 05/24/2216:47 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 05/24/2210:30 05/24/2216:47 7440-43-9 Chromium ND ug/L 5.0 1.1 1 05/24/2210:30 05/24/2216:47 7440-47-3 Cobalt 0.47J ug/L 5.0 0.39 1 05/24/2210:30 05/24/2216:47 7440-48-4 Copper ND ug/L 5.0 1.0 1 05/24/2210:30 05/24/2216:47 7440-50-8 Lead ND ug/L 1.0 0.89 1 05/24/2210:30 05/24/2216:47 7439-92-1 Nickel ND ug/L 5.0 0.71 1 05/24/2210:30 05/24/2216:47 7440-02-0 Selenium ND ug/L 5.0 1.4 1 05/24/2210:30 05/24/2216:47 7782-49-2 Silver ND ug/L 5.0 0.44 1 05/24/2210:30 05/24/2216:47 7440-22-4 Thallium ND ug/L 1.0 0.18 1 05/24/2210:30 05/24/2216:47 7440-28-0 Vanadium ND ug/L 10.0 1.9 1 05/24/2210:30 05/24/2216:47 7440-62-2 Zinc ND ug/L 10.0 7.0 1 05/24/2210:30 05/24/2216:47 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 05/20/22 08:16 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 05/20/22 08:16 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/20/22 08:16 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 05/20/22 08:16 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/20/22 08:16 75-27-4 Bromoform ND ug/L 1.0 0.34 1 05/20/22 08:16 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 05/20/22 08:16 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 05/20/22 08:16 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 05/20/22 08:16 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/20/22 08:16 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 05/20/22 08:16 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 05/20/22 08:16 75-00-3 Chloroform ND ug/L 1.0 0.43 1 05/20/22 08:16 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/20/22 08:16 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 05/20/22 08:16 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 05/20/22 08:16 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 05/20/22 08:16 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 05/20/22 08:16 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 05/20/22 08:16 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 05/20/22 08:16 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 05/20/22 08:16 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 05/20/22 08:16 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/20/22 08:16 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 05/20/22 08:16 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 05/20/22 08:16 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 05/20/22 08:16 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 05/20/22 08:16 78-87-5 REPORT OF LABORATORY ANALYSIS v2 v2 This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-MW5 Lab ID: 92605500006 Collected: 05/17/22 17:43 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/26/2022 12:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 93 % 70-130 87 % 70-130 101 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 101 % 70-130 92 % 70-130 0.36 1 05/20/22 08:16 10061-01-5 0.36 1 05/20/22 08:16 10061-02-6 0.30 1 05/20/22 08:16 100-41-4 0.48 1 05/20/22 08:16 591-78-6 9.7 1 05/20/22 08:16 74-88-4 2.0 1 05/20/22 08:16 75-09-2 v2 2.7 1 05/20/22 08:16 108-10-1 0.29 1 05/20/22 08:16 100-42-5 0.31 1 05/20/22 08:16 630-20-6 0.22 1 05/20/22 08:16 79-34-5 0.29 1 05/20/22 08:16 127-18-4 0.48 1 05/20/22 08:16 108-88-3 0.33 1 05/20/22 08:16 71-55-6 0.32 1 05/20/22 08:16 79-00-5 0.38 1 05/20/22 08:16 79-01-6 0.30 1 05/20/22 08:16 75-69-4 0.26 1 05/20/22 08:16 96-18-4 1.3 1 05/20/22 08:16 108-05-4 0.39 1 05/20/22 08:16 75-01-4 0.34 1 05/20/22 08:16 1330-20-7 1 05/20/22 08:16 460-00-4 1 05/20/22 08:16 17060-07-0 1 05/20/22 08:16 2037-26-5 0.86 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/21 /22 08:18 123-91-1 05/21 /22 08:18 17060-07-0 05/21 /22 08:18 2037-26-5 Page 18 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-MW6S Lab ID: 92605500007 Collected: 05/17/22 18:36 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 05/24/2210:30 05/24/2216:53 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 05/24/2210:30 05/24/2216:53 7440-38-2 Barium 38.9 ug/L 5.0 0.67 1 05/24/2210:30 05/24/2216:53 7440-39-3 Beryllium ND ug/L 0.50 0.054 1 05/24/2210:30 05/24/2216:53 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 05/24/2210:30 05/24/2216:53 7440-43-9 Chromium ND ug/L 5.0 1.1 1 05/24/2210:30 05/24/2216:53 7440-47-3 Cobalt 0.881 ug/L 5.0 0.39 1 05/24/2210:30 05/24/2216:53 7440-48-4 Copper ND ug/L 5.0 1.0 1 05/24/2210:30 05/24/2216:53 7440-50-8 Lead ND ug/L 1.0 0.89 1 05/24/2210:30 05/24/2216:53 7439-92-1 Nickel ND ug/L 5.0 0.71 1 05/24/2210:30 05/24/2216:53 7440-02-0 Selenium ND ug/L 5.0 1.4 1 05/24/2210:30 05/24/2216:53 7782-49-2 Silver ND ug/L 5.0 0.44 1 05/24/2210:30 05/24/2216:53 7440-22-4 Thallium ND ug/L 1.0 0.18 1 05/24/2210:30 05/24/2216:53 7440-28-0 Vanadium ND ug/L 10.0 1.9 1 05/24/2210:30 05/24/2216:53 7440-62-2 Zinc ND ug/L 10.0 7.0 1 05/24/2210:30 05/24/2216:53 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 05/20/22 08:35 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 05/20/22 08:35 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/20/22 08:35 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 05/20/22 08:35 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/20/22 08:35 75-27-4 Bromoform ND ug/L 1.0 0.34 1 05/20/22 08:35 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 05/20/22 08:35 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 05/20/22 08:35 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 05/20/22 08:35 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/20/22 08:35 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 05/20/22 08:35 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 05/20/22 08:35 75-00-3 Chloroform 0.891 ug/L 1.0 0.43 1 05/20/22 08:35 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/20/22 08:35 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 05/20/22 08:35 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 05/20/22 08:35 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 05/20/22 08:35 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 05/20/22 08:35 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 05/20/22 08:35 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 05/20/22 08:35 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 05/20/22 08:35 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 05/20/22 08:35 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/20/22 08:35 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 05/20/22 08:35 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 05/20/22 08:35 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 05/20/22 08:35 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 05/20/22 08:35 78-87-5 REPORT OF LABORATORY ANALYSIS v2 v2 This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-MW6S Lab ID: 92605500007 Collected: 05/17/22 18:36 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/26/2022 12:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 94 % 70-130 91 % 70-130 101 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 95 % 70-130 90 % 70-130 0.36 1 05/20/22 08:35 10061-01-5 0.36 1 05/20/22 08:35 10061-02-6 0.30 1 05/20/22 08:35 100-41-4 0.48 1 05/20/22 08:35 591-78-6 9.7 1 05/20/22 08:35 74-88-4 2.0 1 05/20/22 08:35 75-09-2 v2 2.7 1 05/20/22 08:35 108-10-1 0.29 1 05/20/22 08:35 100-42-5 0.31 1 05/20/22 08:35 630-20-6 0.22 1 05/20/22 08:35 79-34-5 0.29 1 05/20/22 08:35 127-18-4 0.48 1 05/20/22 08:35 108-88-3 0.33 1 05/20/22 08:35 71-55-6 0.32 1 05/20/22 08:35 79-00-5 0.38 1 05/20/22 08:35 79-01-6 0.30 1 05/20/22 08:35 75-69-4 0.26 1 05/20/22 08:35 96-18-4 1.3 1 05/20/22 08:35 108-05-4 0.39 1 05/20/22 08:35 75-01-4 0.34 1 05/20/22 08:35 1330-20-7 1 05/20/22 08:35 460-00-4 1 05/20/22 08:35 17060-07-0 1 05/20/22 08:35 2037-26-5 0.86 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/21 /22 08:37 123-91-1 05/21 /22 08:37 17060-07-0 05/21 /22 08:37 2037-26-5 Page 20 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-MW6D Lab ID: 92605500008 Collected: 05/17/22 17:28 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 05/24/2210:30 05/24/2216:59 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 05/24/2210:30 05/24/2216:59 7440-38-2 Barium 12.1 ug/L 5.0 0.67 1 05/24/2210:30 05/24/2216:59 7440-39-3 Beryllium ND ug/L 0.50 0.054 1 05/24/2210:30 05/24/2216:59 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 05/24/2210:30 05/24/2216:59 7440-43-9 Chromium ND ug/L 5.0 1.1 1 05/24/2210:30 05/24/2216:59 7440-47-3 Cobalt ND ug/L 5.0 0.39 1 05/24/2210:30 05/24/2216:59 7440-48-4 Copper ND ug/L 5.0 1.0 1 05/24/2210:30 05/24/2216:59 7440-50-8 Lead ND ug/L 1.0 0.89 1 05/24/2210:30 05/24/2216:59 7439-92-1 Nickel ND ug/L 5.0 0.71 1 05/24/2210:30 05/24/2216:59 7440-02-0 Selenium ND ug/L 5.0 1.4 1 05/24/2210:30 05/24/2216:59 7782-49-2 Silver ND ug/L 5.0 0.44 1 05/24/2210:30 05/24/2216:59 7440-22-4 Thallium ND ug/L 1.0 0.18 1 05/24/2210:30 05/24/2216:59 7440-28-0 Vanadium ND ug/L 10.0 1.9 1 05/24/2210:30 05/24/2216:59 7440-62-2 Zinc ND ug/L 10.0 7.0 1 05/24/2210:30 05/24/2216:59 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 05/20/22 09:11 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 05/20/22 09:11 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/20/22 09:11 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 05/20/22 09:11 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/20/22 09:11 75-27-4 Bromoform ND ug/L 1.0 0.34 1 05/20/22 09:11 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 05/20/22 09:11 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 05/20/22 09:11 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 05/20/22 09:11 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/20/22 09:11 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 05/20/22 09:11 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 05/20/22 09:11 75-00-3 Chloroform ND ug/L 1.0 0.43 1 05/20/22 09:11 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/20/22 09:11 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 05/20/22 09:11 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 05/20/22 09:11 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 05/20/22 09:11 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 05/20/22 09:11 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 05/20/22 09:11 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 05/20/22 09:11 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 05/20/22 09:11 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 05/20/22 09:11 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/20/22 09:11 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 05/20/22 09:11 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 05/20/22 09:11 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 05/20/22 09:11 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 05/20/22 09:11 78-87-5 REPORT OF LABORATORY ANALYSIS v2 v2 This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-MW6D Lab ID: 92605500008 Collected: 05/17/22 17:28 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/26/2022 12:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 92 % 70-130 86 % 70-130 100 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 102 % 70-130 93 % 70-130 0.36 1 05/20/22 09:11 10061-01-5 0.36 1 05/20/22 09:11 10061-02-6 0.30 1 05/20/22 09:11 100-41-4 0.48 1 05/20/22 09:11 591-78-6 9.7 1 05/20/22 09:11 74-88-4 2.0 1 05/20/22 09:11 75-09-2 v2 2.7 1 05/20/22 09:11 108-10-1 0.29 1 05/20/22 09:11 100-42-5 0.31 1 05/20/22 09:11 630-20-6 0.22 1 05/20/22 09:11 79-34-5 0.29 1 05/20/22 09:11 127-18-4 0.48 1 05/20/22 09:11 108-88-3 0.33 1 05/20/22 09:11 71-55-6 0.32 1 05/20/22 09:11 79-00-5 0.38 1 05/20/22 09:11 79-01-6 0.30 1 05/20/22 09:11 75-69-4 0.26 1 05/20/22 09:11 96-18-4 1.3 1 05/20/22 09:11 108-05-4 0.39 1 05/20/22 09:11 75-01-4 0.34 1 05/20/22 09:11 1330-20-7 1 05/20/22 09:11 460-00-4 1 05/20/22 09:11 17060-07-0 1 05/20/22 09:11 2037-26-5 0.86 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/21 /22 08:57 123-91-1 05/21 /22 08:57 17060-07-0 05/21 /22 08:57 2037-26-5 Page 22 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-SW1 Lab ID: 92605500009 Collected: 05/17/22 13:55 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 05/24/2210:30 05/24/2217:05 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 05/24/2210:30 05/24/2217:05 7440-38-2 Barium 34.2 ug/L 5.0 0.67 1 05/24/2210:30 05/24/2217:05 7440-39-3 Beryllium ND ug/L 0.50 0.054 1 05/24/2210:30 05/24/2217:05 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 05/24/2210:30 05/24/2217:05 7440-43-9 Chromium ND ug/L 5.0 1.1 1 05/24/2210:30 05/24/2217:05 7440-47-3 Cobalt ND ug/L 5.0 0.39 1 05/24/2210:30 05/24/2217:05 7440-48-4 Copper ND ug/L 5.0 1.0 1 05/24/2210:30 05/24/2217:05 7440-50-8 Lead ND ug/L 1.0 0.89 1 05/24/2210:30 05/24/2217:05 7439-92-1 Nickel ND ug/L 5.0 0.71 1 05/24/2210:30 05/24/2217:05 7440-02-0 Selenium ND ug/L 5.0 1.4 1 05/24/2210:30 05/24/2217:05 7782-49-2 Silver ND ug/L 5.0 0.44 1 05/24/2210:30 05/24/2217:05 7440-22-4 Thallium ND ug/L 1.0 0.18 1 05/24/2210:30 05/24/2217:05 7440-28-0 Vanadium 2.5.1 ug/L 10.0 1.9 1 05/24/2210:30 05/24/2217:05 7440-62-2 Zinc ND ug/L 10.0 7.0 1 05/24/2210:30 05/24/2217:05 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 05/20/22 06:44 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 05/20/22 06:44 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/20/22 06:44 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 05/20/22 06:44 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/20/22 06:44 75-27-4 Bromoform ND ug/L 1.0 0.34 1 05/20/22 06:44 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 05/20/22 06:44 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 05/20/22 06:44 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 05/20/22 06:44 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/20/22 06:44 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 05/20/22 06:44 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 05/20/22 06:44 75-00-3 Chloroform ND ug/L 1.0 0.43 1 05/20/22 06:44 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/20/22 06:44 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 05/20/22 06:44 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 05/20/22 06:44 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 05/20/22 06:44 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 05/20/22 06:44 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 05/20/22 06:44 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 05/20/22 06:44 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 05/20/22 06:44 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 05/20/22 06:44 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/20/22 06:44 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 05/20/22 06:44 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 05/20/22 06:44 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 05/20/22 06:44 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 05/20/22 06:44 78-87-5 REPORT OF LABORATORY ANALYSIS v2 v2 This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-SW1 Lab ID: 92605500009 Collected: 05/17/22 13:55 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/26/2022 12:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 92 % 70-130 86 % 70-130 101 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 92 % 70-130 89 % 70-130 0.36 1 05/20/22 06:44 10061-01-5 0.36 1 05/20/22 06:44 10061-02-6 0.30 1 05/20/22 06:44 100-41-4 0.48 1 05/20/22 06:44 591-78-6 9.7 1 05/20/22 06:44 74-88-4 2.0 1 05/20/22 06:44 75-09-2 v2 2.7 1 05/20/22 06:44 108-10-1 0.29 1 05/20/22 06:44 100-42-5 0.31 1 05/20/22 06:44 630-20-6 0.22 1 05/20/22 06:44 79-34-5 0.29 1 05/20/22 06:44 127-18-4 0.48 1 05/20/22 06:44 108-88-3 0.33 1 05/20/22 06:44 71-55-6 0.32 1 05/20/22 06:44 79-00-5 0.38 1 05/20/22 06:44 79-01-6 0.30 1 05/20/22 06:44 75-69-4 0.26 1 05/20/22 06:44 96-18-4 1.3 1 05/20/22 06:44 108-05-4 0.39 1 05/20/22 06:44 75-01-4 0.34 1 05/20/22 06:44 1330-20-7 1 05/20/22 06:44 460-00-4 1 05/20/22 06:44 17060-07-0 1 05/20/22 06:44 2037-26-5 0.86 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/21 /22 09:16 123-91-1 05/21 /22 09:16 17060-07-0 05/21 /22 09:16 2037-26-5 Page 24 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-SW2 Lab ID: 92605500010 Collected: 05/17/22 14:55 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 05/24/2210:30 05/24/2217:11 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 05/24/2210:30 05/24/2217:11 7440-38-2 Barium 30.9 ug/L 5.0 0.67 1 05/24/2210:30 05/24/2217:11 7440-39-3 Beryllium ND ug/L 0.50 0.054 1 05/24/2210:30 05/24/2217:11 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 05/24/2210:30 05/24/2217:11 7440-43-9 Chromium ND ug/L 5.0 1.1 1 05/24/2210:30 05/24/2217:11 7440-47-3 Cobalt ND ug/L 5.0 0.39 1 05/24/2210:30 05/24/2217:11 7440-48-4 Copper ND ug/L 5.0 1.0 1 05/24/2210:30 05/24/2217:11 7440-50-8 Lead ND ug/L 1.0 0.89 1 05/24/2210:30 05/24/2217:11 7439-92-1 Nickel ND ug/L 5.0 0.71 1 05/24/2210:30 05/24/2217:11 7440-02-0 Selenium ND ug/L 5.0 1.4 1 05/24/2210:30 05/24/2217:11 7782-49-2 Silver ND ug/L 5.0 0.44 1 05/24/2210:30 05/24/2217:11 7440-22-4 Thallium ND ug/L 1.0 0.18 1 05/24/2210:30 05/24/2217:11 7440-28-0 Vanadium 2.9.1 ug/L 10.0 1.9 1 05/24/2210:30 05/24/2217:11 7440-62-2 Zinc ND ug/L 10.0 7.0 1 05/24/2210:30 05/24/2217:11 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 05/21/22 06:27 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 05/21/22 06:27 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/21/22 06:27 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 05/21/22 06:27 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/21/22 06:27 75-27-4 Bromoform ND ug/L 1.0 0.34 1 05/21/22 06:27 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 05/21/22 06:27 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 05/21/22 06:27 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 05/21/22 06:27 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/21/22 06:27 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 05/21/22 06:27 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 05/21/22 06:27 75-00-3 Chloroform ND ug/L 1.0 0.43 1 05/21/22 06:27 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/21/22 06:27 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 05/21/22 06:27 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 05/21/22 06:27 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 05/21/22 06:27 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 05/21/22 06:27 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 05/21/22 06:27 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 05/21/22 06:27 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 05/21/22 06:27 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 05/21/22 06:27 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/21/22 06:27 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 05/21/22 06:27 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 05/21/22 06:27 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 05/21/22 06:27 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 05/21/22 06:27 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-SW2 Lab ID: 92605500010 Collected: 05/17/22 14:55 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/26/2022 12:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 101 % 70-130 88 % 70-130 105 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 96 % 70-130 90 % 70-130 0.36 1 05/21/22 06:27 10061-01-5 0.36 1 05/21/22 06:27 10061-02-6 0.30 1 05/21/22 06:27 100-41-4 0.48 1 05/21/22 06:27 591-78-6 9.7 1 05/21/22 06:27 74-88-4 2.0 1 05/21/22 06:27 75-09-2 2.7 1 05/21/22 06:27 108-10-1 0.29 1 05/21/22 06:27 100-42-5 0.31 1 05/21/22 06:27 630-20-6 0.22 1 05/21/22 06:27 79-34-5 0.29 1 05/21/22 06:27 127-18-4 0.48 1 05/21/22 06:27 108-88-3 0.33 1 05/21/22 06:27 71-55-6 0.32 1 05/21/22 06:27 79-00-5 0.38 1 05/21/22 06:27 79-01-6 0.30 1 05/21/22 06:27 75-69-4 0.26 1 05/21/22 06:27 96-18-4 1.3 1 05/21/22 06:27 108-05-4 0.39 1 05/21/22 06:27 75-01-4 0.34 1 05/21/22 06:27 1330-20-7 1 05/21/22 06:27 460-00-4 1 05/21/22 06:27 17060-07-0 1 05/21/22 06:27 2037-26-5 0.86 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/21/22 09:35 123-91-1 05/21/22 09:35 17060-07-0 05/21/22 09:35 2037-26-5 IK Page 26 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-SW3 Lab ID: 92605500011 Collected: 05/17/22 13:40 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 05/24/2210:30 05/24/2217:17 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 05/24/2210:30 05/24/2217:17 7440-38-2 Barium 34.2 ug/L 5.0 0.67 1 05/24/2210:30 05/24/2217:17 7440-39-3 Beryllium ND ug/L 0.50 0.054 1 05/24/2210:30 05/24/2217:17 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 05/24/2210:30 05/24/2217:17 7440-43-9 Chromium ND ug/L 5.0 1.1 1 05/24/2210:30 05/24/2217:17 7440-47-3 Cobalt ND ug/L 5.0 0.39 1 05/24/2210:30 05/24/2217:17 7440-48-4 Copper ND ug/L 5.0 1.0 1 05/24/2210:30 05/24/2217:17 7440-50-8 Lead ND ug/L 1.0 0.89 1 05/24/2210:30 05/24/2217:17 7439-92-1 Nickel ND ug/L 5.0 0.71 1 05/24/2210:30 05/24/2217:17 7440-02-0 Selenium ND ug/L 5.0 1.4 1 05/24/2210:30 05/24/2217:17 7782-49-2 Silver ND ug/L 5.0 0.44 1 05/24/2210:30 05/24/2217:17 7440-22-4 Thallium ND ug/L 1.0 0.18 1 05/24/2210:30 05/24/2217:17 7440-28-0 Vanadium 3.2.1 ug/L 10.0 1.9 1 05/24/2210:30 05/24/2217:17 7440-62-2 Zinc ND ug/L 10.0 7.0 1 05/24/2210:30 05/24/2217:17 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 05/20/22 07:03 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 05/20/22 07:03 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/20/22 07:03 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 05/20/22 07:03 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/20/22 07:03 75-27-4 Bromoform ND ug/L 1.0 0.34 1 05/20/22 07:03 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 05/20/22 07:03 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 05/20/22 07:03 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 05/20/22 07:03 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/20/22 07:03 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 05/20/22 07:03 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 05/20/22 07:03 75-00-3 Chloroform ND ug/L 1.0 0.43 1 05/20/22 07:03 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/20/22 07:03 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 05/20/22 07:03 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 05/20/22 07:03 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 05/20/22 07:03 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 05/20/22 07:03 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 05/20/22 07:03 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 05/20/22 07:03 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 05/20/22 07:03 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 05/20/22 07:03 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/20/22 07:03 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 05/20/22 07:03 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 05/20/22 07:03 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 05/20/22 07:03 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 05/20/22 07:03 78-87-5 REPORT OF LABORATORY ANALYSIS v2 v2 This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-SW3 Lab ID: 92605500011 Collected: 05/17/22 13:40 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/26/2022 12:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 94 % 70-130 91 % 70-130 101 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 99 % 70-130 90 % 70-130 0.36 1 05/20/22 07:03 10061-01-5 0.36 1 05/20/22 07:03 10061-02-6 0.30 1 05/20/22 07:03 100-41-4 0.48 1 05/20/22 07:03 591-78-6 9.7 1 05/20/22 07:03 74-88-4 2.0 1 05/20/22 07:03 75-09-2 v2 2.7 1 05/20/22 07:03 108-10-1 0.29 1 05/20/22 07:03 100-42-5 0.31 1 05/20/22 07:03 630-20-6 0.22 1 05/20/22 07:03 79-34-5 0.29 1 05/20/22 07:03 127-18-4 0.48 1 05/20/22 07:03 108-88-3 0.33 1 05/20/22 07:03 71-55-6 0.32 1 05/20/22 07:03 79-00-5 0.38 1 05/20/22 07:03 79-01-6 0.30 1 05/20/22 07:03 75-69-4 0.26 1 05/20/22 07:03 96-18-4 1.3 1 05/20/22 07:03 108-05-4 0.39 1 05/20/22 07:03 75-01-4 0.34 1 05/20/22 07:03 1330-20-7 1 05/20/22 07:03 460-00-4 1 05/20/22 07:03 17060-07-0 1 05/20/22 07:03 2037-26-5 0.86 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/21 /22 09:54 123-91-1 05/21 /22 09:54 17060-07-0 05/21 /22 09:54 2037-26-5 Page 28 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-TRIPBLANK Lab ID: 92605500012 Collected: 05/17/22 01:00 Received: 05/19/22 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Date: 05/26/2022 12:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 5.1 1 05/20/22 00:39 67-64-1 v2 ND ug/L 10.0 1.8 1 05/20/22 00:39 107-13-1 ND ug/L 1.0 0.34 1 05/20/22 00:39 71-43-2 ND ug/L 1.0 0.47 1 05/20/22 00:39 74-97-5 ND ug/L 1.0 0.31 1 05/20/22 00:39 75-27-4 ND ug/L 1.0 0.34 1 05/20/22 00:39 75-25-2 ND ug/L 2.0 1.7 1 05/20/22 00:39 74-83-9 v2 ND ug/L 5.0 4.0 1 05/20/22 00:39 78-93-3 ND ug/L 2.0 0.36 1 05/20/22 00:39 75-15-0 ND ug/L 1.0 0.33 1 05/20/22 00:39 56-23-5 ND ug/L 1.0 0.28 1 05/20/22 00:39 108-90-7 ND ug/L 1.0 0.65 1 05/20/22 00:39 75-00-3 ND ug/L 1.0 0.43 1 05/20/22 00:39 67-66-3 ND ug/L 1.0 0.54 1 05/20/22 00:39 74-87-3 ND ug/L 2.0 0.34 1 05/20/22 00:39 96-12-8 ND ug/L 1.0 0.36 1 05/20/22 00:39 124-48-1 ND ug/L 1.0 0.27 1 05/20/22 00:39 106-93-4 ND ug/L 1.0 0.39 1 05/20/22 00:39 74-95-3 ND ug/L 1.0 0.34 1 05/20/22 00:39 95-50-1 ND ug/L 1.0 0.33 1 05/20/22 00:39 106-46-7 ND ug/L 1.0 0.56 1 05/20/22 00:39 110-57-6 ND ug/L 1.0 0.37 1 05/20/22 00:39 75-34-3 ND ug/L 1.0 0.32 1 05/20/22 00:39 107-06-2 ND ug/L 1.0 0.35 1 05/20/22 00:39 75-35-4 ND ug/L 1.0 0.38 1 05/20/22 00:39 156-59-2 ND ug/L 1.0 0.40 1 05/20/22 00:39 156-60-5 ND ug/L 1.0 0.36 1 05/20/22 00:39 78-87-5 ND ug/L 1.0 0.36 1 05/20/22 00:39 10061-01-5 ND ug/L 1.0 0.36 1 05/20/22 00:39 10061-02-6 ND ug/L 1.0 0.30 1 05/20/22 00:39 100-41-4 ND ug/L 5.0 0.48 1 05/20/22 00:39 591-78-6 ND ug/L 20.0 9.7 1 05/20/22 00:39 74-88-4 ND ug/L 5.0 2.0 1 05/20/22 00:39 75-09-2 v2 ND ug/L 5.0 2.7 1 05/20/22 00:39 108-10-1 ND ug/L 1.0 0.29 1 05/20/22 00:39 100-42-5 ND ug/L 1.0 0.31 1 05/20/22 00:39 630-20-6 ND ug/L 1.0 0.22 1 05/20/22 00:39 79-34-5 ND ug/L 1.0 0.29 1 05/20/22 00:39 127-18-4 ND ug/L 1.0 0.48 1 05/20/22 00:39 108-88-3 ND ug/L 1.0 0.33 1 05/20/22 00:39 71-55-6 ND ug/L 1.0 0.32 1 05/20/22 00:39 79-00-5 ND ug/L 1.0 0.38 1 05/20/22 00:39 79-01-6 ND ug/L 1.0 0.30 1 05/20/22 00:39 75-69-4 ND ug/L 1.0 0.26 1 05/20/22 00:39 96-18-4 ND ug/L 2.0 1.3 1 05/20/22 00:39 108-05-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 29 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 Sample: 1201-TRIPBLANK Parameters Lab ID: 92605500012 Collected: Report Results Units Limit 05/17/22 01:00 MDL DF Received: 05/19/22 10:00 Matrix: Water Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Vinyl chloride ND ug/L 1.0 0.39 1 05/20/22 00:39 75-01-4 Xylene (Total) ND ug/L 1.0 0.34 1 05/20/22 00:39 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 93 % 70-130 1 05/20/22 00:39 460-00-4 1,2-Dichloroethane-d4 (S) 86 % 70-130 1 05/20/22 00:39 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 05/20/22 00:39 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 0.86 1 05/21/22 07:20 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 99 % 70-130 1 05/21/22 07:20 17060-07-0 Toluene-d8 (S) 95 % 70-130 1 05/21/22 07:20 2037-26-5 Date: 05/26/2022 12:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 30 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 QC Batch: 700090 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020 MET Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92605500001, 92605500002, 92605500003, 92605500004, 92605500005, 92605500006, 92605500007, 92605500008,92605500009,92605500010,92605500011 METHOD BLANK: 3654312 Matrix: Water Associated Lab Samples: 92605500001, 92605500002, 92605500003, 92605500004, 92605500005, 92605500006, 92605500007, 92605500008,92605500009,92605500010,92605500011 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 3.0 0.78 05/24/2215:09 Arsenic ug/L ND 5.0 2.2 05/24/2215:09 Barium ug/L ND 5.0 0.67 05/24/2215:09 Beryllium ug/L ND 0.50 0.054 05/24/2215:09 Cadmium ug/L ND 0.50 0.11 05/24/2215:09 Chromium ug/L ND 5.0 1.1 05/24/2215:09 Cobalt ug/L ND 5.0 0.39 05/24/2215:09 Copper ug/L ND 5.0 1.0 05/24/2215:09 Lead ug/L ND 1.0 0.89 05/24/2215:09 Nickel ug/L ND 5.0 0.71 05/24/2215:09 Selenium ug/L ND 5.0 1.4 05/24/2215:09 Silver ug/L ND 5.0 0.44 05/24/2215:09 Thallium ug/L ND 1.0 0.18 05/24/2215:09 Vanadium ug/L ND 10.0 1.9 05/24/2215:09 Zinc ug/L ND 10.0 7.0 05/24/2215:09 LABORATORY CONTROL SAMPLE: Parameter 3654313 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 100 101 101 80-120 Arsenic ug/L 100 97.2 97 80-120 Barium ug/L 100 99.8 100 80-120 Beryllium ug/L 100 103 103 80-120 Cadmium ug/L 100 100 100 80-120 Chromium ug/L 100 103 103 80-120 Cobalt ug/L 100 99.2 99 80-120 Copper ug/L 100 99.9 100 80-120 Lead ug/L 100 96.4 96 80-120 Nickel ug/L 100 100 100 80-120 Selenium ug/L 100 94.9 95 80-120 Silver ug/L 100 101 101 80-120 Thallium ug/L 100 98.1 98 80-120 Vanadium ug/L 100 105 105 80-120 Zinc ug/L 100 112 112 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: BURKE CO KIRKSEY DRIVE 92605500 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3654314 3654315 MS MSD 92605866001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 101 97.3 101 97 75-125 4 20 Arsenic ug/L ND 100 100 99.1 99.1 98 98 75-125 0 20 Barium ug/L 111 100 100 196 189 86 78 75-125 4 20 Beryllium ug/L ND 100 100 106 104 106 104 75-125 2 20 Cadmium ug/L ND 100 100 98.3 98.9 98 99 75-125 1 20 Chromium ug/L 8.3 100 100 108 106 100 98 75-125 2 20 Cobalt ug/L ND 100 100 96.6 95.8 96 96 75-125 1 20 Copper ug/L 8.4 100 100 102 106 94 97 75-125 3 20 Lead ug/L ND 100 100 96.5 96.2 96 96 75-125 0 20 Nickel ug/L 3.9J 100 100 99.8 101 96 97 75-125 1 20 Selenium ug/L ND 100 100 93.9 93.1 94 93 75-125 1 20 Silver ug/L ND 100 100 102 98.7 102 99 75-125 4 20 Thallium ug/L ND 100 100 99.2 96.9 99 97 75-125 2 20 Vanadium ug/L 10.1 100 100 115 115 105 104 75-125 1 20 Zinc ug/L ND 100 100 110 111 106 107 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 QC Batch: 699412 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92605500012 METHOD BLANK: 3651424 Associated Lab Samples: 92605500012 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 05/20/22 00:20 1,1,1-Trichloroethane ug/L ND 1.0 0.33 05/20/22 00:20 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 05/20/22 00:20 1,1,2-Trichloroethane ug/L ND 1.0 0.32 05/20/22 00:20 1,1-Dichloroethane ug/L ND 1.0 0.37 05/20/22 00:20 1,1-Dichloroethene ug/L ND 1.0 0.35 05/20/22 00:20 1,2,3-Trichloropropane ug/L ND 1.0 0.26 05/20/22 00:20 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 05/20/22 00:20 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 05/20/22 00:20 1,2-Dichlorobenzene ug/L ND 1.0 0.34 05/20/22 00:20 1,2-Dichloroethane ug/L ND 1.0 0.32 05/20/22 00:20 1,2-Dichloropropane ug/L ND 1.0 0.36 05/20/22 00:20 1,4-Dichlorobenzene ug/L ND 1.0 0.33 05/20/22 00:20 2-Butanone (MEK) ug/L ND 5.0 4.0 05/20/22 00:20 2-Hexanone ug/L ND 5.0 0.48 05/20/22 00:20 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 05/20/22 00:20 Acetone ug/L ND 25.0 5.1 05/20/22 00:20 v2 Acrylonitrile ug/L ND 10.0 1.8 05/20/22 00:20 Benzene ug/L ND 1.0 0.34 05/20/22 00:20 Bromochloromethane ug/L ND 1.0 0.47 05/20/22 00:20 Bromodichloromethane ug/L ND 1.0 0.31 05/20/22 00:20 Bromoform ug/L ND 1.0 0.34 05/20/22 00:20 Bromomethane ug/L ND 2.0 1.7 05/20/22 00:20 v2 Carbon disulfide ug/L ND 2.0 0.36 05/20/22 00:20 Carbon tetrachloride ug/L ND 1.0 0.33 05/20/22 00:20 Chlorobenzene ug/L ND 1.0 0.28 05/20/22 00:20 Chloroethane ug/L ND 1.0 0.65 05/20/22 00:20 Chloroform ug/L ND 1.0 0.43 05/20/22 00:20 Chloromethane ug/L ND 1.0 0.54 05/20/22 00:20 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 05/20/22 00:20 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 05/20/22 00:20 Dibromochloromethane ug/L ND 1.0 0.36 05/20/22 00:20 Dibromomethane ug/L ND 1.0 0.39 05/20/22 00:20 Ethylbenzene ug/L ND 1.0 0.30 05/20/22 00:20 lodomethane ug/L ND 20.0 9.7 05/20/22 00:20 Methylene Chloride ug/L ND 5.0 2.0 05/20/22 00:20 v2 Styrene ug/L ND 1.0 0.29 05/20/22 00:20 Tetrachloroethene ug/L ND 1.0 0.29 05/20/22 00:20 Toluene ug/L ND 1.0 0.48 05/20/22 00:20 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 05/20/22 00:20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 METHOD BLANK: 3651424 Associated Lab Samples: 92605500012 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 05/20/22 00:20 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 05/20/22 00:20 Trichloroethene ug/L ND 1.0 0.38 05/20/22 00:20 Trichlorofluoromethane ug/L ND 1.0 0.30 05/20/22 00:20 Vinyl acetate ug/L ND 2.0 1.3 05/20/22 00:20 Vinyl chloride ug/L ND 1.0 0.39 05/20/22 00:20 Xylene (Total) ug/L ND 1.0 0.34 05/20/22 00:20 1,2-Dichloroethane-d4 (S) % 82 70-130 05/20/22 00:20 4-Bromofluorobenzene (S) % 93 70-130 05/20/22 00:20 Toluene-d8 (S) % 100 70-130 05/20/22 00:20 LABORATORY CONTROL SAMPLE: Parameter 3651425 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 52.3 105 70-130 1,1,1-Trichloroethane ug/L 50 46.4 93 70-130 1,1,2,2-Tetrachloroethane ug/L 50 47.5 95 70-130 1,1,2-Trichloroethane ug/L 50 50.0 100 70-130 1,1-Dichloroethane ug/L 50 42.7 85 70-130 1,1-Dichloroethene ug/L 50 43.6 87 70-132 1,2,3-Trichloropropane ug/L 50 48.2 96 70-130 1,2-Dibromo-3-chloropropane ug/L 50 52.2 104 70-132 1,2-Dibromoethane (EDB) ug/L 50 50.4 101 70-130 1,2-Dichlorobenzene ug/L 50 50.2 100 70-130 1,2-Dichloroethane ug/L 50 41.0 82 70-130 1,2-Dichloropropane ug/L 50 46.2 92 70-130 1,4-Dichlorobenzene ug/L 50 48.6 97 70-130 2-Butanone (MEK) ug/L 100 87.4 87 70-133 2-Hexanone ug/L 100 87.2 87 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 88.0 88 70-130 Acetone ug/L 100 79.1 79 70-144 v3 Acrylonitrile ug/L 250 226 90 70-130 Benzene ug/L 50 44.7 89 70-130 Bromochloromethane ug/L 50 48.7 97 70-130 Bromodichloromethane ug/L 50 48.0 96 70-130 Bromoform ug/L 50 56.5 113 70-131 Bromomethane ug/L 50 39.8 80 30-177 v3 Carbon disulfide ug/L 50 48.2 96 70-133 Carbon tetrachloride ug/L 50 49.3 99 70-130 Chlorobenzene ug/L 50 49.7 99 70-130 Chloroethane ug/L 50 41.4 83 46-131 Chloroform ug/L 50 46.1 92 70-130 Chloromethane ug/L 50 48.3 97 49-130 cis-1,2-Dichloroethene ug/L 50 42.5 85 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 52 Pace Analytical Services, LLC lac, Analyilcal ® 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 LABORATORY CONTROL SAMPLE: Parameter 3651425 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 49.9 100 70-130 Dibromochloromethane ug/L 50 52.3 105 70-130 Dibromomethane ug/L 50 53.4 107 70-130 Ethylbenzene ug/L 50 47.1 94 70-130 lodomethane ug/L 100 107 107 47-140 Methylene Chloride ug/L 50 39.0 78 68-130 v3 Styrene ug/L 50 52.0 104 70-130 Tetrachloroethene ug/L 50 52.0 104 70-130 Toluene ug/L 50 47.0 94 70-130 trans-1,2-Dichloroethene ug/L 50 42.1 84 70-130 trans- 1,3-Dichloropropene ug/L 50 49.2 98 70-130 trans-1,4-Dichloro-2-butene ug/L 50 46.4 93 25-200 Trichloroethene ug/L 50 52.3 105 70-130 Trichlorofluoromethane ug/L 50 46.8 94 61-130 Vinyl acetate ug/L 100 85.3 85 70-140 Vinyl chloride ug/L 50 47.8 96 59-142 Xylene (Total) ug/L 150 145 97 70-130 1,2-Dichloroethane-d4 (S) % 81 70-130 4-Bromofluorobenzene (S) % 93 70-130 Toluene-d8 (S) % 96 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3651426 MS 92605410002 Spike Parameter Units Result Conc. MSD Spike Conc. 3651427 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 25.1 23.4 125 117 70-135 7 30 1,1,1-Trichloroethane ug/L ND 20 20 22.1 20.2 110 101 70-148 9 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 22.8 22.1 114 110 70-131 3 30 1,1,2-Trichloroethane ug/L ND 20 20 20.5 22.2 102 111 70-136 8 30 1,1-Dichloroethane ug/L ND 20 20 20.7 18.5 104 92 70-147 12 30 1,1-Dichloroethene ug/L ND 20 20 21.6 19.6 108 98 70-158 10 30 1,2,3-Trichloropropane ug/L ND 20 20 22.6 21.8 113 109 67-137 3 30 1,2-Dibromo-3- ug/L ND 20 20 25.2 24.8 126 124 69-136 2 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 24.5 23.4 123 117 70-137 5 30 1,2-Dichlorobenzene ug/L ND 20 20 24.8 23.3 124 117 70-133 6 30 1,2-Dichloroethane ug/L ND 20 20 19.3 18.6 97 93 67-138 4 30 1,2-Dichloropropane ug/L ND 20 20 22.8 22.3 114 111 70-138 2 30 1,4-Dichlorobenzene ug/L 1.9 20 20 25.4 24.2 117 112 70-133 5 30 2-Butanone (MEK) ug/L ND 40 40 39.9 36.9 100 92 61-147 8 30 2-Hexanone ug/L ND 40 40 45.5 42.3 114 106 67-139 7 30 4-Methyl-2-pentanone ug/L ND 40 40 38.9 40.4 97 101 67-136 4 30 (MIBK) Acetone ug/L ND 40 40 37.8 34.0 94 85 55-159 11 30 Acrylonitrile ug/L ND 100 100 107 94.0 107 94 68-140 13 30 Benzene ug/L ND 20 20 21.9 20.9 108 103 67-150 5 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3651426 MS 92605410002 Spike Parameter Units Result Conc. MSD Spike Conc. 3651427 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Bromochloromethane ug/L ND 20 20 22.6 20.2 113 101 70-146 12 30 Bromodichloromethane ug/L ND 20 20 23.0 21.3 115 106 70-138 8 30 Bromoform ug/L ND 20 20 24.8 23.7 124 119 57-138 4 30 Bromomethane ug/L ND 20 20 21.4 19.0 107 95 10-200 12 30 Carbon disulfide ug/L ND 20 20 26.0 22.7 130 114 70-152 13 30 Carbon tetrachloride ug/L ND 20 20 23.2 21.1 116 105 70-147 10 30 Chlorobenzene ug/L 11.7 20 20 35.3 34.3 118 113 70-137 3 30 Chloroethane ug/L ND 20 20 25.4 22.4 127 112 51-166 13 30 Chloroform ug/L ND 20 20 21.3 19.7 107 99 70-144 8 30 Chloromethane ug/L ND 20 20 20.2 19.0 101 95 24-161 6 30 cis-1,2-Dichloroethene ug/L ND 20 20 21.1 18.8 106 94 67-148 12 30 cis-1,3-Dichloropropene ug/L ND 20 20 22.6 21.7 113 109 70-142 4 30 Dibromochloromethane ug/L ND 20 20 23.7 22.3 118 111 68-138 6 30 Dibromomethane ug/L ND 20 20 25.1 23.6 126 118 70-134 6 30 Ethylbenzene ug/L ND 20 20 24.4 23.5 122 117 68-143 4 30 lodomethane ug/L ND 40 40 43.8 41.0 110 103 20-161 7 30 Methylene Chloride ug/L ND 20 20 17.5 16.1 88 80 64-148 9 30 Styrene ug/L ND 20 20 25.5 24.6 127 123 70-136 3 30 Tetrachloroethene ug/L ND 20 20 24.9 23.1 125 116 70-139 7 30 Toluene ug/L ND 20 20 20.4 21.0 102 105 47-157 3 30 trans-1,2-Dichloroethene ug/L ND 20 20 21.3 19.1 106 95 70-149 11 30 trans-1,3-Dichloropropene ug/L ND 20 20 21.6 22.9 108 114 70-138 6 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 22.0 20.8 110 104 31-145 6 30 Trichloroethene ug/L ND 20 20 24.2 22.9 121 115 70-149 5 30 Trichlorofluoromethane ug/L ND 20 20 21.3 19.6 106 98 61-154 8 30 Vinyl acetate ug/L ND 40 40 40.6 35.7 101 89 48-156 13 30 Vinyl chloride ug/L ND 20 20 22.8 21.7 114 108 55-172 5 30 Xylene (Total) ug/L ND 60 60 74.2 70.8 124 118 66-145 5 30 1,2-Dichloroethane-d4 (S) % 81 82 70-130 4-Bromofluorobenzene (S) % 98 98 70-130 Toluene-d8 (S) % 87 91 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 QC Batch: 699413 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92605500002, 92605500003, 92605500004, 92605500005, 92605500006, 92605500007, 92605500008, 92605500009,92605500011 METHOD BLANK: 3651456 Matrix: Water Associated Lab Samples: 92605500002, 92605500003, 92605500004, 92605500005, 92605500006, 92605500007, 92605500008, 92605500009,92605500011 Parameter Units Blank Result Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 05/20/22 00:02 1,1,1-Trichloroethane ug/L ND 1.0 0.33 05/20/22 00:02 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 05/20/22 00:02 1,1,2-Trichloroethane ug/L ND 1.0 0.32 05/20/22 00:02 1,1-Dichloroethane ug/L ND 1.0 0.37 05/20/22 00:02 1,1-Dichloroethene ug/L ND 1.0 0.35 05/20/22 00:02 1,2,3-Trichloropropane ug/L ND 1.0 0.26 05/20/22 00:02 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 05/20/22 00:02 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 05/20/22 00:02 1,2-Dichlorobenzene ug/L ND 1.0 0.34 05/20/22 00:02 1,2-Dichloroethane ug/L ND 1.0 0.32 05/20/22 00:02 1,2-Dichloropropane ug/L ND 1.0 0.36 05/20/22 00:02 1,4-Dichlorobenzene ug/L ND 1.0 0.33 05/20/22 00:02 2-Butanone (MEK) ug/L ND 5.0 4.0 05/20/22 00:02 2-Hexanone ug/L ND 5.0 0.48 05/20/22 00:02 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 05/20/22 00:02 Acetone ug/L ND 25.0 5.1 05/20/22 00:02 Acrylonitrile ug/L ND 10.0 1.8 05/20/22 00:02 Benzene ug/L ND 1.0 0.34 05/20/22 00:02 Bromochloromethane ug/L ND 1.0 0.47 05/20/22 00:02 Bromodichloromethane ug/L ND 1.0 0.31 05/20/22 00:02 Bromoform ug/L ND 1.0 0.34 05/20/22 00:02 Bromomethane ug/L ND 2.0 1.7 05/20/22 00:02 Carbon disulfide ug/L ND 2.0 0.36 05/20/22 00:02 Carbon tetrachloride ug/L ND 1.0 0.33 05/20/22 00:02 Chlorobenzene ug/L ND 1.0 0.28 05/20/22 00:02 Chloroethane ug/L ND 1.0 0.65 05/20/22 00:02 Chloroform ug/L ND 1.0 0.43 05/20/22 00:02 Chloromethane ug/L ND 1.0 0.54 05/20/22 00:02 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 05/20/22 00:02 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 05/20/22 00:02 Dibromochloromethane ug/L ND 1.0 0.36 05/20/22 00:02 Dibromomethane ug/L ND 1.0 0.39 05/20/22 00:02 Ethylbenzene ug/L ND 1.0 0.30 05/20/22 00:02 lodomethane ug/L ND 20.0 9.7 05/20/22 00:02 Methylene Chloride ug/L ND 5.0 2.0 05/20/22 00:02 Styrene ug/L ND 1.0 0.29 05/20/22 00:02 Tetrachloroethene ug/L ND 1.0 0.29 05/20/22 00:02 Toluene ug/L ND 1.0 0.48 05/20/22 00:02 v2 v2 v2 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 METHOD BLANK: 3651456 Matrix: Water Associated Lab Samples: 92605500002, 92605500003, 92605500004, 92605500005, 92605500006, 92605500007, 92605500008, 92605500009,92605500011 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.40 05/20/22 00:02 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 05/20/22 00:02 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 05/20/22 00:02 Trichloroethene ug/L ND 1.0 0.38 05/20/22 00:02 Trichlorofluoromethane ug/L ND 1.0 0.30 05/20/22 00:02 Vinyl acetate ug/L ND 2.0 1.3 05/20/22 00:02 Vinyl chloride ug/L ND 1.0 0.39 05/20/22 00:02 Xylene (Total) ug/L ND 1.0 0.34 05/20/22 00:02 1,2-Dichloroethane-d4 (S) % 83 70-130 05/20/22 00:02 4-Bromofluorobenzene (S) % 92 70-130 05/20/22 00:02 Toluene-d8 (S) % 100 70-130 05/20/22 00:02 LABORATORY CONTROL SAMPLE: Parameter 3651457 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 52.8 106 70-130 1,1,1-Trichloroethane ug/L 50 45.4 91 70-130 1,1,2,2-Tetrachloroethane ug/L 50 48.6 97 70-130 1,1,2-Trichloroethane ug/L 50 50.5 101 70-130 1,1-Dichloroethane ug/L 50 42.6 85 70-130 1,1-Dichloroethene ug/L 50 43.7 87 70-132 1,2,3-Trichloropropane ug/L 50 48.4 97 70-130 1,2-Dibromo-3-chloropropane ug/L 50 54.1 108 70-132 1,2-Dibromoethane (EDB) ug/L 50 51.3 103 70-130 1,2-Dichlorobenzene ug/L 50 52.0 104 70-130 1,2-Dichloroethane ug/L 50 40.4 81 70-130 1,2-Dichloropropane ug/L 50 46.2 92 70-130 1,4-Dichlorobenzene ug/L 50 50.4 101 70-130 2-Butanone (MEK) ug/L 100 86.7 87 70-133 2-Hexanone ug/L 100 88.1 88 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 86.8 87 70-130 Acetone ug/L 100 79.5 80 70-144 v3 Acrylonitrile ug/L 250 224 90 70-130 Benzene ug/L 50 45.6 91 70-130 Bromochloromethane ug/L 50 46.7 93 70-130 Bromodichloromethane ug/L 50 48.2 96 70-130 Bromoform ug/L 50 57.5 115 70-131 Bromomethane ug/L 50 40.9 82 30-177 v3 Carbon disulfide ug/L 50 48.2 96 70-133 Carbon tetrachloride ug/L 50 51.0 102 70-130 Chlorobenzene ug/L 50 50.7 101 70-130 Chloroethane ug/L 50 41.5 83 46-131 Chloroform ug/L 50 44.8 90 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 LABORATORY CONTROL SAMPLE: Parameter 3651457 Units Spike LCS Conc. Result Chloromethane ug/L 50 cis-1,2-Dichloroethene ug/L 50 cis-1,3-Dichloropropene ug/L 50 Dibromochloromethane ug/L 50 Dibromomethane ug/L 50 Ethylbenzene ug/L 50 lodomethane ug/L 100 Methylene Chloride ug/L 50 Styrene ug/L 50 Tetrachloroethene ug/L 50 Toluene ug/L 50 trans-1,2-Dichloroethene ug/L 50 trans- 1,3-Dichloropropene ug/L 50 trans-1,4-Dichloro-2-butene ug/L 50 Trichloroethene ug/L 50 Trichlorofluoromethane ug/L 50 Vinyl acetate ug/L 100 Vinyl chloride ug/L 50 Xylene (Total) ug/L 150 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LCS % Rec % Rec Limits Qualifiers 48.3 97 49-130 42.5 85 70-130 50.3 101 70-130 53.2 106 70-130 53.2 106 70-130 48.2 96 70-130 108 108 47-140 39.2 78 68-130 v3 52.9 106 70-130 53.1 106 70-130 46.9 94 70-130 43.0 86 70-130 49.8 100 70-130 45.0 90 25-200 53.0 106 70-130 45.4 91 61-130 84.9 85 70-140 47.7 95 59-142 149 99 70-130 79 70-130 94 70-130 96 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3651458 MS 92605500005 Spike Parameter Units Result Conc. MSD Spike Conc. 3651459 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 21.8 21.2 109 106 70-135 3 30 1,1,1-Trichloroethane ug/L ND 20 20 20.2 20.0 101 100 70-148 1 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.2 20.7 106 104 70-131 2 30 1,1,2-Trichloroethane ug/L ND 20 20 21.5 21.6 108 108 70-136 0 30 1,1-Dichloroethane ug/L 0.39J 20 20 20.3 19.7 99 96 70-147 3 30 1,1-Dichloroethene ug/L ND 20 20 21.8 20.8 109 104 70-158 5 30 1,2,3-Trichloropropane ug/L ND 20 20 20.8 20.4 104 102 67-137 2 30 1,2-Dibromo-3- ug/L ND 20 20 22.4 21.5 112 107 69-136 4 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 22.2 21.2 111 106 70-137 5 30 1,2-Dichlorobenzene ug/L ND 20 20 21.8 21.2 109 106 70-133 3 30 1,2-Dichloroethane ug/L ND 20 20 18.0 17.4 90 87 67-138 4 30 1,2-Dichloropropane ug/L ND 20 20 21.4 20.4 107 102 70-138 5 30 1,4-Dichlorobenzene ug/L ND 20 20 21.5 20.7 107 104 70-133 4 30 2-Butanone (MEK) ug/L ND 40 40 38.5 40.0 96 100 61-147 4 30 2-Hexanone ug/L ND 40 40 41.3 39.4 103 99 67-139 5 30 4-Methyl-2-pentanone ug/L ND 40 40 39.5 40.3 99 101 67-136 2 30 (MIBK) Acetone ug/L ND 40 40 36.2 35.1 91 88 55-159 3 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result Date: 05/26/2022 12:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 39 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3651458 3651459 MS MSD 92605500005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acrylonitrile ug/L ND 100 100 105 101 105 101 68-140 3 30 Benzene ug/L ND 20 20 19.4 20.8 97 104 67-150 7 30 Bromochloromethane ug/L ND 20 20 20.9 21.2 104 106 70-146 2 30 Bromodichloromethane ug/L ND 20 20 20.8 20.0 104 100 70-138 4 30 Bromoform ug/L ND 20 20 22.7 21.2 114 106 57-138 7 30 Bromomethane ug/L ND 20 20 21.7 21.6 109 108 10-200 1 30 Carbon disulfide ug/L ND 20 20 24.5 23.2 122 116 70-152 5 30 Carbon tetrachloride ug/L ND 20 20 20.4 21.6 102 108 70-147 5 30 Chlorobenzene ug/L ND 20 20 22.2 21.5 111 107 70-137 3 30 Chloroethane ug/L ND 20 20 24.3 23.9 122 120 51-166 2 30 Chloroform ug/L ND 20 20 19.8 20.2 99 101 70-144 2 30 Chloromethane ug/L ND 20 20 19.7 18.9 99 94 24-161 5 30 cis-1,2-Dichloroethene ug/L 2.6 20 20 22.1 22.5 97 99 67-148 2 30 cis-1,3-Dichloropropene ug/L ND 20 20 22.1 21.2 111 106 70-142 4 30 Dibromochloromethane ug/L ND 20 20 22.4 20.5 112 103 68-138 9 30 Dibromomethane ug/L ND 20 20 22.9 22.3 114 111 70-134 3 30 Ethylbenzene ug/L ND 20 20 21.9 21.4 109 107 68-143 2 30 Iodomethane ug/L ND 40 40 43.7 39.9 109 100 20-161 9 30 Methylene Chloride ug/L ND 20 20 17.3 16.8 86 84 64-148 3 30 Styrene ug/L ND 20 20 23.2 22.2 116 111 70-136 4 30 Tetrachloroethene ug/L ND 20 20 23.7 22.3 119 111 70-139 6 30 Toluene ug/L ND 20 20 21.3 21.1 107 106 47-157 1 30 trans-1,2-Dichloroethene ug/L ND 20 20 20.6 19.9 103 100 70-149 3 30 trans-1,3-Dichloropropene ug/L ND 20 20 21.7 22.3 108 112 70-138 3 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 19.9 18.4 99 92 31-145 7 30 Trichloroethene ug/L ND 20 20 22.5 20.9 112 105 70-149 7 30 Trichlorofluoromethane ug/L ND 20 20 20.9 20.1 104 101 61-154 4 30 Vinyl acetate ug/L ND 40 40 37.8 36.6 94 92 48-156 3 30 Vinyl chloride ug/L ND 20 20 21.8 21.6 109 108 55-172 1 30 Xylene (Total) ug/L ND 60 60 66.1 64.4 110 107 66-145 3 30 1,2-Dichloroethane-d4 (S) % 85 85 70-130 4-Bromofluorobenzene (S) % 98 98 70-130 Toluene-d8 (S) % 98 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 QC Batch: 699628 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92605500001, 92605500010 METHOD BLANK: 3652459 Associated Lab Samples: 92605500001, 92605500010 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 05/20/22 23:09 1,1,1-Trichloroethane ug/L ND 1.0 0.33 05/20/22 23:09 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 05/20/22 23:09 1,1,2-Trichloroethane ug/L ND 1.0 0.32 05/20/22 23:09 1,1-Dichloroethane ug/L ND 1.0 0.37 05/20/22 23:09 1,1-Dichloroethene ug/L ND 1.0 0.35 05/20/22 23:09 1,2,3-Trichloropropane ug/L ND 1.0 0.26 05/20/22 23:09 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 05/20/22 23:09 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 05/20/22 23:09 1,2-Dichlorobenzene ug/L ND 1.0 0.34 05/20/22 23:09 1,2-Dichloroethane ug/L ND 1.0 0.32 05/20/22 23:09 1,2-Dichloropropane ug/L ND 1.0 0.36 05/20/22 23:09 1,4-Dichlorobenzene ug/L ND 1.0 0.33 05/20/22 23:09 2-Butanone (MEK) ug/L ND 5.0 4.0 05/20/22 23:09 2-Hexanone ug/L ND 5.0 0.48 05/20/22 23:09 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 05/20/22 23:09 Acetone ug/L ND 25.0 5.1 05/20/22 23:09 Acrylonitrile ug/L ND 10.0 1.8 05/20/22 23:09 Benzene ug/L ND 1.0 0.34 05/20/22 23:09 Bromochloromethane ug/L ND 1.0 0.47 05/20/22 23:09 Bromodichloromethane ug/L ND 1.0 0.31 05/20/22 23:09 Bromoform ug/L ND 1.0 0.34 05/20/22 23:09 Bromomethane ug/L ND 2.0 1.7 05/20/22 23:09 Carbon disulfide ug/L ND 2.0 0.36 05/20/22 23:09 Carbon tetrachloride ug/L ND 1.0 0.33 05/20/22 23:09 Chlorobenzene ug/L ND 1.0 0.28 05/20/22 23:09 Chloroethane ug/L ND 1.0 0.65 05/20/22 23:09 Chloroform ug/L ND 1.0 0.43 05/20/22 23:09 Chloromethane ug/L ND 1.0 0.54 05/20/22 23:09 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 05/20/22 23:09 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 05/20/22 23:09 Dibromochloromethane ug/L ND 1.0 0.36 05/20/22 23:09 Dibromomethane ug/L ND 1.0 0.39 05/20/22 23:09 Ethylbenzene ug/L ND 1.0 0.30 05/20/22 23:09 lodomethane ug/L ND 20.0 9.7 05/20/22 23:09 Methylene Chloride ug/L ND 5.0 2.0 05/20/22 23:09 Styrene ug/L ND 1.0 0.29 05/20/22 23:09 Tetrachloroethene ug/L ND 1.0 0.29 05/20/22 23:09 Toluene ug/L ND 1.0 0.48 05/20/22 23:09 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 05/20/22 23:09 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 METHOD BLANK: 3652459 Associated Lab Samples: 92605500001, 92605500010 Parameter Units Matrix: Blank Result Water Reporting Limit MDL trans- 1,3-Dichloropropene ug/L ND 1.0 trans-1,4-Dichloro-2-butene ug/L ND 1.0 Trichloroethene ug/L ND 1.0 Trichlorofluoromethane ug/L ND 1.0 Vinyl acetate ug/L ND 2.0 Vinyl chloride ug/L ND 1.0 Xylene (Total) ug/L ND 1.0 1,2-Dichloroethane-d4 (S) % 90 70-130 4-Bromofluorobenzene (S) % 102 70-130 Toluene-d8(S) % 104 70-130 Analyzed 0.36 05/20/22 23:09 0.56 05/20/22 23:09 0.38 05/20/22 23:09 0.30 05/20/22 23:09 1.3 05/20/22 23:09 0.39 05/20/22 23:09 0.34 05/20/22 23:09 05/20/22 23:09 05/20/22 23:09 05/20/22 23:09 LABORATORY CONTROL SAMPLE: Parameter 3652460 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 55.2 110 70-130 1,1,1-Trichloroethane ug/L 50 50.0 100 70-130 1,1,2,2-Tetrachloroethane ug/L 50 52.0 104 70-130 1,1,2-Trichloroethane ug/L 50 53.1 106 70-130 1,1-Dichloroethane ug/L 50 46.8 94 70-130 1,1-Dichloroethene ug/L 50 48.7 97 70-132 1,2,3-Trichloropropane ug/L 50 51.8 104 70-130 1,2-Dibromo-3-chloropropane ug/L 50 53.6 107 70-132 1,2-Dibromoethane (EDB) ug/L 50 55.2 110 70-130 1,2-Dichlorobenzene ug/L 50 51.2 102 70-130 1,2-Dichloroethane ug/L 50 46.8 94 70-130 1,2-Dichloropropane ug/L 50 53.2 106 70-130 1,4-Dichlorobenzene ug/L 50 49.2 98 70-130 2-Butanone (MEK) ug/L 100 107 107 70-133 2-Hexanone ug/L 100 113 113 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 109 109 70-130 Acetone ug/L 100 95.8 96 70-144 Acrylonitrile ug/L 250 255 102 70-130 Benzene ug/L 50 50.0 100 70-130 Bromochloromethane ug/L 50 46.1 92 70-130 Bromodichloromethane ug/L 50 51.7 103 70-130 Bromoform ug/L 50 53.7 107 70-131 Bromomethane ug/L 50 44.7 89 30-177 Carbon disulfide ug/L 50 48.2 96 70-133 Carbon tetrachloride ug/L 50 51.3 103 70-130 Chlorobenzene ug/L 50 51.6 103 70-130 Chloroethane ug/L 50 49.0 98 46-131 Chloroform ug/L 50 47.4 95 70-130 Chloromethane ug/L 50 45.9 92 49-130 cis-1,2-Dichloroethene ug/L 50 46.0 92 70-130 Qualifiers I:/ Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 52 Pace Analytical Services, LLC lac, Analyilcal ® 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 LABORATORY CONTROL SAMPLE: Parameter 3652460 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 56.2 112 70-130 Dibromochloromethane ug/L 50 55.6 111 70-130 Dibromomethane ug/L 50 50.4 101 70-130 Ethylbenzene ug/L 50 50.8 102 70-130 lodomethane ug/L 100 92.2 92 47-140 Methylene Chloride ug/L 50 47.3 95 68-130 Styrene ug/L 50 51.9 104 70-130 Tetrachloroethene ug/L 50 51.5 103 70-130 Toluene ug/L 50 47.3 95 70-130 trans-1,2-Dichloroethene ug/L 50 49.9 100 70-130 trans- 1,3-Dichloropropene ug/L 50 55.1 110 70-130 trans-1,4-Dichloro-2-butene ug/L 50 51.7 103 25-200 Trichloroethene ug/L 50 54.1 108 70-130 Trichlorofluoromethane ug/L 50 42.9 86 61-130 Vinyl acetate ug/L 100 100 100 70-140 IK Vinyl chloride ug/L 50 46.9 94 59-142 Xylene (Total) ug/L 150 151 100 70-130 1,2-Dichloroethane-d4 (S) % 90 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 95 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3652461 MS 92605500010 Spike Parameter Units Result Conc. MSD Spike Conc. 3652462 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 22.9 19.6 114 98 70-135 15 30 1,1,1-Trichloroethane ug/L ND 20 20 23.3 20.1 117 101 70-148 15 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.7 18.6 109 93 70-131 15 30 1,1,2-Trichloroethane ug/L ND 20 20 22.0 19.4 110 97 70-136 13 30 1,1-Dichloroethane ug/L ND 20 20 22.9 20.2 114 101 70-147 12 30 1,1-Dichloroethene ug/L ND 20 20 25.2 21.4 126 107 70-158 16 30 1,2,3-Trichloropropane ug/L ND 20 20 19.0 18.4 95 92 67-137 3 30 1,2-Dibromo-3- ug/L ND 20 20 22.2 18.4 111 92 69-136 19 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 22.7 19.4 113 97 70-137 16 30 1,2-Dichlorobenzene ug/L ND 20 20 20.9 18.1 105 90 70-133 15 30 1,2-Dichloroethane ug/L ND 20 20 22.5 19.9 112 99 67-138 12 30 1,2-Dichloropropane ug/L ND 20 20 21.9 20.0 109 100 70-138 9 30 1,4-Dichlorobenzene ug/L ND 20 20 20.3 18.2 101 91 70-133 11 30 2-Butanone (MEK) ug/L ND 40 40 45.2 44.8 113 112 61-147 1 30 2-Hexanone ug/L ND 40 40 42.1 37.4 105 94 67-139 12 30 4-Methyl-2-pentanone ug/L ND 40 40 41.6 38.1 104 95 67-136 9 30 (MIBK) Acetone ug/L ND 40 40 43.8 40.6 109 102 55-159 8 30 Acrylonitrile ug/L ND 100 100 115 100 115 100 68-140 14 30 Benzene ug/L ND 20 20 20.7 19.1 104 96 67-150 8 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3652461 MS 92605500010 Spike Parameter Units Result Conc. MSD Spike Conc. 3652462 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Bromochloromethane ug/L ND 20 20 24.2 21.0 121 105 70-146 14 30 Bromodichloromethane ug/L ND 20 20 22.4 19.9 112 100 70-138 12 30 Bromoform ug/L ND 20 20 21.2 18.6 106 93 57-138 13 30 Bromomethane ug/L ND 20 20 22.9 20.7 115 103 10-200 10 30 Carbon disulfide ug/L ND 20 20 23.2 20.2 116 101 70-152 14 30 Carbon tetrachloride ug/L ND 20 20 23.2 20.9 116 104 70-147 11 30 Chlorobenzene ug/L ND 20 20 22.0 18.9 110 94 70-137 15 30 Chloroethane ug/L ND 20 20 26.9 23.7 135 118 51-166 13 30 Chloroform ug/L ND 20 20 23.1 20.7 116 104 70-144 11 30 Chloromethane ug/L ND 20 20 24.2 21.4 121 107 24-161 13 30 cis-1,2-Dichloroethene ug/L ND 20 20 23.5 21.0 118 105 67-148 11 30 cis-1,3-Dichloropropene ug/L ND 20 20 22.4 19.9 112 99 70-142 12 30 Dibromochloromethane ug/L ND 20 20 22.7 19.0 113 95 68-138 18 30 Dibromomethane ug/L ND 20 20 22.4 19.7 112 99 70-134 13 30 Ethylbenzene ug/L ND 20 20 22.3 19.1 111 96 68-143 15 30 lodomethane ug/L ND 40 40 44.8 39.7 112 99 20-161 12 30 Methylene Chloride ug/L ND 20 20 20.8 18.6 104 93 64-148 11 30 Styrene ug/L ND 20 20 21.2 18.3 106 91 70-136 15 30 Tetrachloroethene ug/L ND 20 20 23.4 19.6 117 98 70-139 18 30 Toluene ug/L ND 20 20 21.4 19.0 107 95 47-157 12 30 trans-1,2-Dichloroethene ug/L ND 20 20 24.0 20.9 120 104 70-149 14 30 trans-1,3-Dichloropropene ug/L ND 20 20 22.3 19.5 111 98 70-138 13 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 19.6 16.7 98 83 31-145 16 30 Trichloroethene ug/L ND 20 20 22.5 19.9 113 99 70-149 13 30 Trichlorofluoromethane ug/L ND 20 20 22.7 19.9 113 100 61-154 13 30 Vinyl acetate ug/L ND 40 40 44.0 39.1 110 98 48-156 12 30 Vinyl chloride ug/L ND 20 20 25.2 21.9 126 109 55-172 14 30 Xylene (Total) ug/L ND 60 60 66.9 57.1 112 95 66-145 16 30 1,2-Dichloroethane-d4 (S) % 100 99 70-130 4-Bromofluorobenzene (S) % 102 100 70-130 Toluene-d8 (S) % 98 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 QC Batch: 699668 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92605500001 METHOD BLANK: 3652743 Matrix: Water Associated Lab Samples: 92605500001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 05/20/22 18:30 1,2-Dichloroethane-d4 (S) % 85 70-130 05/20/22 18:30 Toluene-d8 (S) % 86 70-130 05/20/22 18:30 LABORATORY CONTROL SAMPLE: 3652744 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 17.3 86 70-130 1,2-Dichloroethane-d4 (S) % 97 70-130 Toluene-d8 (S) % 87 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3652745 3652746 MS MSD 92605500001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 15.2 17.1 76 85 63-136 12 30 1,2-Dichloroethane-d4 (S) % 93 101 70-130 30 Toluene-d8 (S) % 88 90 70-130 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 QC Batch: 699670 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92605500002, 92605500003, 92605500004, 92605500005, 92605500006, 92605500007, 92605500008, 92605500009,92605500010,92605500011,92605500012 METHOD BLANK: 3652749 Matrix: Water Associated Lab Samples: 92605500002, 92605500003, 92605500004, 92605500005, 92605500006, 92605500007, 92605500008, 92605500009,92605500010,92605500011,92605500012 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 05/21/22 06:42 1,2-Dichloroethane-d4 (S) % 100 70-130 05/21/22 06:42 Toluene-d8 (S) % 94 70-130 05/21/22 06:42 LABORATORY CONTROL SAMPLE: 3652750 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 16.2 81 70-130 1,2-Dichloroethane-d4 (S) % 100 70-130 Toluene-d8 (S) % 90 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3652751 3652752 Parameter 1,4-Dioxane (p-Dioxane) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) MS 92605559004 Spike Units Result Conc. ug/L ND 20 MSD Spike MS MSD MS MSD % Rec Max Conc. Result Result % Rec % Rec Limits RPD RPD Qual 20 16.1 17.4 81 87 63-136 8 30 101 100 70-130 30 94 89 70-130 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 46 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: BURKE CO KIRKSEY DRIVE Pace Project No.: 92605500 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/26/2022 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: BURKE CO KIRKSEY DRIVE 92605500 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92605500001 1201-MW1 EPA 3005A 700090 EPA 6020B 700190 92605500002 1201-MW2 EPA 3005A 700090 EPA 6020B 700190 92605500003 1201-MW3S EPA 3005A 700090 EPA 6020B 700190 92605500004 1201-MW3D EPA 3005A 700090 EPA 6020B 700190 92605500005 1201-MW4 EPA 3005A 700090 EPA 6020B 700190 92605500006 1201-MW5 EPA 3005A 700090 EPA 6020B 700190 92605500007 1201-MW6S EPA 3005A 700090 EPA 6020B 700190 92605500008 1201-MW6D EPA 3005A 700090 EPA 6020B 700190 92605500009 1201-SW1 EPA 3005A 700090 EPA 6020B 700190 92605500010 1201-SW2 EPA 3005A 700090 EPA 6020B 700190 92605500011 1201-SW3 EPA 3005A 700090 EPA 6020B 700190 92605500001 1201-MW 1 EPA 8260D 699628 92605500002 1201-MW2 EPA 8260D 699413 92605500003 1201-MW3S EPA 8260D 699413 92605500004 1201-MW3D EPA 8260D 699413 92605500005 1201-MW4 EPA 8260D 699413 92605500006 1201-MW5 EPA 8260D 699413 92605500007 1201-MW6S EPA 8260D 699413 92605500008 1201-MW6D EPA 8260D 699413 92605500009 1201-SW1 EPA 8260D 699413 92605500010 1201-SW2 EPA 8260D 699628 92605500011 1201-SW3 EPA 8260D 699413 92605500012 1201-TRIPBLAN K EPA 8260D 699412 92605500001 1201-MW1 EPA 8260D Mod. 699668 92605500002 1201-MW2 EPA 8260D Mod. 699670 92605500003 1201-MW3S EPA 8260D Mod. 699670 92605500004 1201-MW3D EPA 8260D Mod. 699670 92605500005 1201-MW4 EPA 8260D Mod. 699670 92605500006 1201-MW5 EPA 8260D Mod. 699670 92605500007 1201-MW6S EPA 8260D Mod. 699670 92605500008 1201-MW6D EPA 8260D Mod. 699670 92605500009 1201-SW1 EPA 8260D Mod. 699670 92605500010 1201-SW2 EPA 8260D Mod. 699670 92605500011 1201-SW3 EPA 8260D Mod. 699670 92605500012 1201-TRIPBLANK EPA 8260D Mod. 699670 Date: 05/26/2022 12:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 48 of 52 1 ixa.<-u;RMt Effective Date: 05/12/202205/12/2022 Laboratory receiving samples: Asheville ❑' Eden[-] Greenwood ❑ Hlfntersviile'❑ /taleigh❑ Mechanicsville[] Atlanta❑ Kernersvillpr-1 • Client Name: — — ` -- — Courier:. ❑Fed Ex- ' ❑Ops ❑LISPS ❑Client ❑ Commercial P e []Other: — Custody Sea[ Present? ❑Yes hko Seals Intact? ❑Yes Packing Material: B ie Wrap \a 01e Bags ❑[None ❑ Other meter: Thermo�..� GunlD'. (� ❑ Type: of Ice -et Blue Correction Factor: Cooler Temp. _ ` Add/SubtractI'Q,,�y Cooler Temp Correct�A, (°C): ,y USDA Regulated Sail water sample) Did samples originate in a quarantine zone within the united States-. CA, NY, or SC (check maps)? ❑Yes FIND �9 1111111111111111111111 92605500 Date/Initials Person Examining-Contents:.� Biologfcai Tissue Frozen? ❑Yes ❑No `� Done Temp should be above freezing to 6°C 05almpres out of temp criteria. Samples on ice. coaling process hasbegun Did samples originate from a foreign source Unternatjori fy, including Hawaiiand Puerto Rfcol? ❑lies ONO Chain of Custody Present? - es ❑Na ❑N/A 1. 5amplesArrivedwithin.iloldTime? es, ON. ❑N(A 2. Short Hold Time Analysis (<72 hr.)? ❑Yes- ❑N/A 1.31 Rush Turn Around Time Requested? ❑Yes o ❑N/A 4: Sufficient Volume? ❑No ❑N/A 5. Correct Containers Used? Ye ❑No ❑N/A 6. -Pace Containers Used? es ❑No ❑N/A Containers Intact? ❑Nto, ❑N/A 7. Dissolver) analysis: Samples Field Filtered? ❑Yes No ❑N/ 9. 5ample.Labels Match COC? 11Y ❑No /A 9. -includes DateMme/.1D/P Headspace in VOA Via ls(>5- Trip Blank Present? Trip Blank CustodySeafs Pre COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESQLLITION VVT [:]No ❑VA 1 11. Lot ID of split containers: Person contacted: Date/Time-, Project Manager SCURF Review; bate: Project Manalger.SRFReview: Data; Field Data Required? []Yes ❑No Qualtrax ID: 69614 Page 1 of 2 Page 49 of 52 Effective Date: 051121202205/12/2022 *Check marls top half of box if pH'and%or dechlorination is verified and. within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, 6R018015 t#aterj. DOC LLHg *" i3ottorn half of box is to list.number of bottles ***Check all unpreserved Nitrates for chlorine Project 9 w011: 92605500 PM: AM Due Date: 06/03/22 -GLiEP' 92-9oyceEng E _ Z ar y G a. E ri v a CO -to z W W C E N A n. z u QFW. - C a E o !!�'1 ry K cctoco ` 0. C R. �, = ri .r a V a E n �..�_ ul v d V O - z G E in r1r Z m d m ma u% Z N 6, J E r'"v v A x O Z d J E ,{ oQ a a m V io {J C I �' 3 i � u. L3 3 Z y N. 2 7 a as _ �" r 7 •s C7 a v a V I �.' a ;; - rr S K C7 a ro m a C Q = m t3 a N cL 0 , N E Q �; = ri' W a [V - fV S �. -. G. J E u0r tY of m- t a U. a i �. l= a J E ui N v m W o �. _ Q 1 E p S: m L7 O, N In N: LJ ~! E o. Is != m > n m C 4 J E a 'Q rn Q �_ 4 J E o � 7 a+ W c d to 4 `l E a a u1 m 0 o> 2_ d 7 4 N' � ' x 1} M v1 J E '^ N h in a V1 u �, d V) E o F^ N a vi G7 h N, Z. 4 - 1 E t[o� M M M, m L t �' Q a Q. 7 C C7 c ,a C O V E Q Vi > •� W y 4 C D o j Rf o 1 �. 3 F42 5 7 \NN \N- N 8 XD lI 12 PH Adjustment tog for Preserved Samples Sample ID I Type of Preservative pH upon receipt Date preservation adjusted Tune preservation Amount of Preservative Lot 9 I J adjusted I added lvaterVlih4nev theie rs rscrepancy arresting iwth Ca ruiirsa eQmpiiance SamQies, a copy of this form will to sent to the Xorth Carolina DENR Out of hold, incorrect preservative, out of temp, incorrect containers. Qualtrax ID: 69614 Page 2 of 2 Page 50 of 52 N LO O CHAIN -OF -CUSTODY 1 Analytical Request Document -" ace i The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. ubmitting a sample via this chain of custody constitutes acknowledgment and acceptance of She Paco Terms and Conditions found at https:ilinfo.pacelabs.com/hubfs/pas-standard-lerms.pdf. � Section A Section B Section C Required Client Information: Required Project Information: invoice Information: Page: 1 Of Company: LaBelle Assod tes, D.P.C. - NC Reporl To: Van Burbach ttention: 1 Address: 12-0 Oak Bran h Drive Copy To: ompany Name: Greensboro, NC 27407 EAA ddress: vburbach@Iabellapc. Dm Purchase Order #: ace quote: Re ulato A encEmail: Phene: (336)323-0092 Fax PrOlect Name: Burke Co_-Kirksey Driveace Projec[ Manager: angela.baioni@pacelabs.com,State! Location �J Requested Due Date: Preiecl #: ....., 13-1- «. ---- SAMPLE ID One Charact r per box. (A-Z. 0 1, -) :th Sample Ids m ist be unique W i 11201-MW1 2 11201-MW2 3 1201-MW3S 4 1 1201-MW3D 5 1201-MW4 B 1201-MW5 7 1201-MW6S 8 1201-MW6D 9 1 1201-SW1 10 1201-SW2 11 1201-SW3 COMMENTS a MATRIX CODE — U COL Qrdrkirq Water DW i U Wete, W-t. Wale, WT W W 9 m Q I'mduct P i K Sodl .lid SL START 0,,OL wive WP w AI, Olhm AR OT O Ti.. T5 X Ld a < N DATE TIME WT IT WT IT WT - IT WT WT IT f IT l RELINQUISHED BY l AFFILIATION z 0 [~J Preservatives Z END J o 4 W in W m — N ? z a Z M }. 0 .- z w O v c a [J j, W It C) _ 0 to L a lzz_�E ¢ O m TIME u C N Z x U x z N z N 2 L O r) U P n M DATE xTIM`E NAME AND SIGNATURE ACCEPTED BY I AFFILIATION DATE Signed: DATE / TIME I QO& N �l d SAMPLE CONDITIONS U o C N T N ZLY� w a d z o z ey m z CHAIN -OF -CUSTODY 1 Analytical Request Document - aCi The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. S Ihmittinn a camnle via I is Chain of custndv constitutes acknnwledoment and acceptance ofthe Pace Terms and Conditions found at httcs:Ilinfn_oacelabs.comlhubfsloas-standard-terms.Ddf. Section A Section B Section C Required Client Information: Required Project Information: Invoice Information: Page : 2 Of 2 D.P.C. - NC Report To: Van Burbach Attention: Drive Copy Tc: Company Name: Company: LaBella Associates, Al 12-D Oak i Greensboro. NC 27407 Address: Regulatory Agency Email: vburbach@labelfapc-c m Purchase Order #; Pace Quote: 1 Phone: (331 11 Project Name: Burke Co.-Kirksey Drive Pace Project Manager: an ela.baioni@pace1abs.cem. State I Location Requested Due Date: Project #: Pace Profile #: 2327 NC Re uested Anal sls Filtered YIN m o Z MATRIX CODE V COLLECTED Preservatives Orink,w WaIW DW Wdtrn WT U O U Wasto Wator WW Pradvct P — m y Z SAMPLE 5dih5dhd 5L 1D [7 L� START END U U d r u } o il of ... One Charect {A-Z. D- r per box. Wi wP AR I , -) Oth. CT O w } a i ~ m oAl, > w z -a U Sample Ids m st be unique Tissue T5 a a a o0 m O z ° 0 'o `a N DATE TIME DATE TIME N o x N z z c� x z z Q z z r o: e^' Z 13 121nk WT ILl X 14 15 1fi 17 18 19 20 21 22 23 24 AVOLTIOIIALCOMMFNTS RELINQUISHED BY I AFFILIATION DATE TIME ACCEPTED BY I AFFILIATION DATE TIME SAMPLE CONDITIONS SAMPLER NAME AND SIGNATURE U � z_ �� o z t1 z SIGNATURE of SANJ!?LE �L n �T GATE Signed: ,y Z Lu N Lo O N to a� d Appendix 2 Historical Data Table A2-1 Historical Groundwater Elevations Table A2-2 Historical Groundwater Constituents Table A2-3 Historical Groundwater Field Parameters Table A2-4 Historical Surface Water Constituents Table A2-5 Historical Surface Water Field Parameters TABLE A2-1: Historical Groundwater Elevations Location Background Downgradient MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6S MW-61D TOC Elevation: 1119.82 1077.23 1021.90 1022.76 1054.99 1137.43 1065.00 1065.00 Well Depth: 35.51 45.25 26.95 76.15 29.60 50.80 27.56 63.15 31-Oct-06 1086.68 1049.61 1014.16 1022.76 1030.93 1096.03 1054.60 1053.22 29-May-07 1087.59 1050.65 1015.08 1022.76 1032.01 1096.91 1054.24 1053.12 27-Nov-07 1085.59 1049.67 1014.06 1022.76 1029.75 1095.15 1054.31 1053.15 27-May-08 1085.56 1049.57 1014.24 1022.76 1030.43 1093.61 1054.21 1053.05 05-Nov-08 1085.12 1049.59 1013.66 1022.46 1029.28 1092.43 1054.23 1053.00 01-Jun-09 1085.94 1050.03 1014.99 1022.76 1032.62 1092.41 1054.85 1053.55 19-Nov-09 1086.91 1050.06 1015.18 1022.76 1032.27 1094.75 1054.84 1053.44 14-Jun-10 1089.98 1050.93 1015.53 1022.76 1033.36 1100.14 1054.33 1053.09 29-Nov-10 1087.62 1050.02 1014.63 1022.76 1030.43 1098.45 1054.53 1053.02 31-May-11 1087.43 1050.02 1014.86 1022.76 1031.78 1096.47 1054.31 1053.06 19-Dec-11 1085.70 1049.85 1014.33 1022.76 1030.57 1094.41 1053.78 1053.00 30-May-12 1086.81 1050.13 1014.99 1022.76 1032.28 1094.12 1054.44 1053.05 03-Dec-12 1085.72 1052.89 1014.46 1022.76 1030.11 1092.06 1054.29 1052.88 11-Jun-13 1088.62 1050.98 1016.30 1022.76 1035.70 1096.08 1058.81 1054.43 29-Oct-13 1090.35 1050.82 1015.75 1022.76 1033.21 1100.48 1054.50 1053.10 05-May-14 1090.34 1031.53 1015.96 1022.76 1034.94 1101.05 1054.76 1053.36 20-Oct-14 1089.05 1050.36 1015.37 1022.76 1032.09 1100.06 1054.57 1044.10 19-May-15 1088.08 1050.25 1015.64 1022.76 1032.77 1097.66 1054.30 1053.05 7-Dec-15 1088.07 1050.26 1014.93 1022.76 1033.54 1096.38 1055.20 1053.55 2-May-16 1090.09 1050.09 1015.40 1022.76 1031.24 1100.12 1054.00 1052.75 12-Dec-16 1087.07 1050.26 1014.80 1022.76 1029.99 1097.68 1054.15 1052.83 26-Jun-17 1086.82 1050.03 1015.10 1022.76 1031.89 1095.63 1053.84 1052.30 14-Dec-17 - 1050.18 1015.15 1022.76 1030.75 1094.65 1054.55 1053.07 16-May-18 - 1050.98 1015.88 1022.76 1033.79 1095.32 1055.10 1053.60 3-Dec-18 1098.92 1050.53 1016.07 1022.76 1034.70 1098.14 1055.09 1053.34 6-May-19 1095.28 1051.26 1016.20 1022.76 1037.20 1104.22 1055.05 1053.44 4-Nov-19 1089.96 1051.23 1016.22 1022.76 1036.09 1101.77 1054.90 1053.09 6-May-20 - 1051.23 1017.08 1022.76 1036.09 1101.77 1055.25 1053.38 9-Nov-20 - 1051.08 1016.18 1022.76 1036.31 1102.20 1055.16 1053.30 4-May-21 - 1051.62 1016.35 1022.76 1037.38 1105.08 1055.35 1053.67 2-Nov-21 - 1051.02 1015.61 1022.76 1032.37 1101.29 1054.75 1053.00 3-Nov-21 1084.31 1031.98 994.95 946.61 1025.39 1086.63 1037.44 1001.85 Notes: TOC = Top of Casing. All elevations are referenced as feet above mean sea level. All depths measured in feet below TOC. MW-6S and MW-6D TOC Elevations are estimated. MW-3D exhibits artesian conditions. MW-1 Fixed 2022 Burke County, Kirksey Drive Landfill Permit No. 12-01 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks INORGANICS Antimony 28-Apr-94 NR 1 1.0 ND 4.0 NI NI NI NI NI NA 3-May-00 NR 30 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 30 NA ND ND ND ND ND ND ND NA 29-May-01 NR 30 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 30 NA ND ND ND ND ND ND ND ND 21-May-02 NR 30 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 30 NA ND ND ND ND ND ND ND ND 14-May-03 NR 30 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 30 ND ND ND ND ND ND ND ND ND 5-May-04 NR 30 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 30 ND ND ND ND ND ND ND ND ND 25-May-05 NR 30 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 30 ND ND ND ND ND ND ND ND ND 24-May-06 NR 30 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 30 ND ND ND ND ND ND ND ND ND 29-May-07 NR 6 ND ND ND ND ND ND ND ND ND GWPS = 1.4 pg/L (10/23/07) 28-Nov-07 NR 6 ND ND ND ND ND ND ND ND ND 28-May-08 2.7 6.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 2.6 6.0 Dry 14.1 3.8 J ND ND ND ND ND ND 2-Jun-09 2.6 6.0 ND 2.9 J ND ND ND ND ND ND ND 19-Nov-09 2.6 6.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 2.6 6.0 ND ND ND ND ND ND ND ND ND GWPS = 1 pg/L (8/1/10) 29-Nov-10 2.6 6.0 ND ND ND ND ND ND ND ND ND 31-May-11 2.6 6.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 5.0 6.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 6.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 6.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 6.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 6.0 6.5 7.6 ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 6.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 6.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 3.8 6.0 ND 7.1 ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 3.8 6.0 ND 4.9 J ND ND ND ND ND ND ND 2-May-16 EPA 6010 3.8 6.0 ND 6.4 ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 3.8 6.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 3.9 6.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 3.9 6.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 3.9 6.0 NS ND ND ND ND ND ND ND ND IMAC = 1 pg/L 4-Dec-18 EPA 6010D 3.9 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 3.9 5.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 3.0 5.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 6010D 3.0 5.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 6010D 3.0 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6010D 3.0 5.0 NS 3 J ND ND ND ND ND ND ND 2-Nov-21 EPA 6010D 3.0 5.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 6020B 0.8 3.0 ND ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 1 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Arsenic 6-Oct-94 NR 5 ND ND 5.0 NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 2.9 J 2.5 J ND 4.1 J 3.0 J ND NC2L = 50 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND ND 28-May-08 2.6 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 2.7 10.0 Dry ND 6.0 B ND ND 3.3 B ND ND 4.8 J 2-Jun-09 2.7 10.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 2.7 10.0 3.0 J ND 5.9 J ND ND ND ND ND ND NC2L = 10 pg/L (01/01/10) 15-Jun-10 2.7 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 2.7 10.0 ND ND 4.9 J ND ND ND ND ND ND 31-May-11 2.7 10.0 3.3 J 3.0 J 9.9 J ND ND ND ND ND ND 19-Dec-11 5.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND 3.4 J ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND 5.2 J ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 3.4 J ND 6.8 J ND ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 NS ND 5.1 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6O10D 5.0 10.0 NS ND 5.1 J ND ND ND ND ND ND 6-May-19 EPA 6O10D 5.0 10.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6O10D 4.7 10.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 6O10D 4.7 10.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 6O10D 4.7 10.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6O10D 4.7 10.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 6O10D 4.7 10.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 602OB 2.2 5.0 ND ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 2 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Barium 28-Apr-94 NR 100 110 840 590 NI NI NI NI NI NA 3-May-00 NR 500 NA 870 550 ND ND ND ND ND ND 8-Nov-00 NR 500 NA 810 ND ND ND ND ND ND ND 29-May-01 NR 500 NA 890 540 ND ND ND ND ND ND 6-Nov-01 NR 500 NA 790 ND ND ND ND ND ND ND 21-May-02 NR 500 NA 800 510 ND ND ND ND ND ND 13-Nov-02 NR 500 NA 650 ND ND ND ND ND ND ND 14-May-03 NR 500 ND 690 530 ND ND ND ND ND ND 19-Nov-03 NR 500 ND 780 ND ND ND ND ND ND ND 5-May-04 NR 500 ND 810 ND ND ND ND ND ND ND 9-Nov-04 NR 500 ND 890 ND ND ND ND ND ND ND 25-May-05 NR 500 ND 730 ND ND ND ND ND ND ND 2-Nov-05 NR 500 ND 930 ND ND ND ND ND ND ND 24-May-06 NR 500 ND 915 ND ND ND ND ND ND ND 1-Nov-06 NR 500 ND 937 ND ND ND ND ND ND ND 29-May-07 NR 100 107 882 484 127 94.9 J 29.9 J 33.0 J 15.1 J ND NC2L = 2,000 pg/L (10/23/07) 28-Nov-07 NR 100 159 945 434 132 128 34.5 J 25.0 J 16.9 J 0.30 J 28-May-08 0.2 100 Dry 812 394 124 101 31.0 J 37.0 J 13.8 J 0.33 J 5-Nov-08 0.20 100 Dry 773 385 119 88.4 J 22.6 B 74.4 J 13.0 B 10.5 J 2-Jun-09 0.20 100 80.4 J 795 432 118 90.8 J 20.8 B 85.4 J 10.5 B 15.2 J 19-Nov-09 0.20 100 114 758 464 138 103 32.6 B 106 12.5 B 19.8 J NC2L = 700 pg/L (01/01/10) 15-Jun-10 0.20 100 141 751 495 162 163 43.1 B 72.8 B 13.1 B 26.3 J 29-Nov-10 0.20 100 89.0 J 843 416 169 128 36.2 J 71.8 J 11.9 J ND 31-May-11 0.20 100 92.4 J 949 464 190 103 30.8 J 33.5 J 13.9 J ND 19-Dec-11 5.0 100 126 809 435 164 214 39.5 J 39.7 J 13.0 J ND 30-May-12 5.0 100 64.7 J 905 475 175 151 27.9 J 26.3 J 13.1 J ND 3-Dec-12 5.0 100 107 739 431 177 97.8 J 25.3 J 51.9 J 14.7 J ND 11-Jun-13 5.0 100 136 662 539 NS 96.2 J 35.6 B 55.9 B 12.0 B 13.7 J 29-Oct-13 5.0 100 135 906 534 199 88.8 J 34.5 J 23.9 J 12.6 J ND 6-May-14 EPA 6010 5.0 100 81.4 J 772 439 186 110 31.9 J 45.2 J 12.4 J ND 21-Oct-14 EPA 6010 5.0 100 82.2 J 1,050 415 194 86.2 J 29.2 J 22.4 J 11.8 J ND 19-May-15 EPA 6010 2.5 100 94.0 J 421 192 85.6 J 32.9 J 43.6 J 12.2 J ND 7-Dec-15 EPA 6010 2.5 100 109.0 1,210 470 205 157 44.7 J 43.6 J 12.3 J ND 2-May-16 EPA 6010 2.5 100 100.0 J 1,060 497 186 73.2 J 38.5 J 59.8 J 11.4 J ND 12-Dec-16 EPA 6010 2.5 100 78.7 J 1,040 388 167 82.0 J 28.0 J 16.3 J 8.1 J ND 26-Jun-17 EPA 6010 2.5 100 NS 1,470 547 218 89.3 J 35.4 J 29.3 J 12.8 J 2.5 J 14-Dec-17 EPA 6010 2.5 100 NS 1,240 498 212 87.8 J 27.7 J 62.2 J 12.8 J ND 14-May-18 EPA 6010 2.5 100 NS 888 566 206 75.5 J 40.4 J 214 12.0 J ND 4-Dec-18 EPA 6O10D 2.5 5 NS 1,160 507 205 82.0 27.1 42.6 12.8 ND 6-May-19 EPA 6O10D 2.5 5 NS 1,040 454 181 82.6 37.5 43.7 12.2 ND 5-Nov-19 EPA 6O10D 2.5 5 NS 1,370 448 219 130 46.5 35.6 17.0 --- 6-May-20 EPA 6O10D 3.5 5 NS 1,160 486 194 71.2 55.4 27.2 12.8 --- 9-Nov-20 EPA 6O10D 3.5 5 NS 1,390 489 200 75.3 36.6 30.0 13.9 ND 4-May-21 EPA 6O10D 3.5 5 NS 1,190 478 201 91.2 121 26.5 13.4 ND 2-Nov-21 EPA 6O10D 3.5 5 NS 1,550 467 202 110 46.5 26.2 13.5 ND 17-May-22 EPA 602OB 0.7 5 91.9 1,620 412 177 71.6 26.7 38.9 34.2 --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 3 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Beryllium 12-May-99 NR 2 ND 2.0 ND ND 2.0 2.1 NI NI ND 19-Oct-99 NR 2 ND ND ND ND ND 4.0 NI NI ND 3-May-00 NR 2 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 2 NA ND ND ND ND 2.0 ND ND ND 29-May-01 NR 2 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 2 NA ND ND ND ND ND ND ND ND 21-May-02 NR 2 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 2 NA 2.4 2.3 2.1 ND ND ND ND ND 14-May-03 NR 2 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 2 ND ND ND ND ND ND ND ND ND 5-May-04 NR 2 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 2 ND ND ND ND ND ND ND ND ND 25-May-05 NR 2 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 2 ND ND ND ND ND ND ND ND ND 24-May-06 NR 2 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 2 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND GWPS = 4 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND ND ND ND ND ND 28-May-08 0.10 1.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.10 1.0 Dry ND ND ND ND 0.11 J 0.17 J ND ND 2-Jun-09 0.10 1.0 ND ND ND ND ND ND 0.18 J ND ND 19-Nov-09 0.10 1.0 ND ND ND ND ND ND 0.11 J ND ND 15-Jun-10 0.10 1.0 ND ND ND ND 0.26 J 0.18 J ND ND ND 29-Nov-10 0.10 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.10 1.0 ND ND 0.21 J ND ND 0.24 J ND ND ND 19-Dec-11 1.0 1.0 ND ND ND ND ND ND ND ND ND 30-May-12 1.0 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 1.0 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 1.0 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 1.0 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 0.5 1.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 0.5 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 0.5 1.0 NS ND ND ND ND ND ND ND ND IMAC = 4 pg/L (10/23/07) 4-Dec-18 EPA 6O10D 0.5 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6O10D 0.5 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6O10D 0.2 1.0 NS ND ND ND ND 0.23 J ND ND --- 6-May-20 EPA 6O10D 0.7 1.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 6O10D 0.7 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6O10D 0.7 1.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 6O10D 0.7 1.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 602OB 0.1 0.5 ND ND 0.1 J ND 0.061 J 0.064 J ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 4 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Cadmium 28-Apr-94 NR 1 ND ND ND NI NI NI NI NI NA 3-May-00 NR 1 NA 8.0 4.0 J 2.0 J 2.0 J 2.0 J 2.0 J ND ND 8-Nov-00 NR 1 NA 13.0 4.0 ND ND 4.0 1.0 ND ND 29-May-01 NR 1 NA 13.0 5.0 ND ND 2.0 J 1.0 J ND ND 6-Nov-01 NR 1 NA 10.0 3.6 ND ND ND ND ND ND 21-May-02 NR 1 NA 7.9 3.0 ND ND ND ND ND ND 13-Nov-02 NR 1 NA 11.0 4.7 1.5 ND ND ND 1.1 ND 14-May-03 NR 1 11.0 12.0 7.1 ND ND ND ND ND ND 19-Nov-03 NR 1 ND ND ND ND ND 2.3 1.1 ND ND 5-May-04 NR 1 ND 1.6 ND ND ND ND ND ND ND 9-Nov-04 NR 1 2.2 13.0 4.5 ND ND ND ND ND ND 25-May-05 NR 1 ND ND ND ND 16.0 ND ND ND ND 2-Nov-05 NR 1 ND ND ND ND 11.0 ND ND ND ND 24-May-06 NR 1 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 1 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND NC2L = 1.75 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND ND ND ND ND ND 28-May-08 0.5 1.0 Dry 1.7 ND ND 2.6 ND ND ND ND 5-Nov-08 0.50 1.0 Dry 0.50 J ND ND ND ND ND ND ND 1-Jun-09 0.50 1.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.50 1.0 ND ND ND ND ND 1.3 ND ND ND NC2L = 2 pg/L (01/01/10) 15-Jun-10 0.50 1.0 ND ND ND ND 1.1 ND ND ND ND 29-Nov-10 0.50 1.0 ND ND ND ND ND 0.80 J ND ND ND 31-May-11 0.50 1.0 ND 0.78 J ND ND ND ND ND ND ND 19-Dec-11 1.0 1.0 ND 1.6 ND ND ND 6.6 ND ND ND 30-May-12 1.0 1.0 ND 5.0 ND ND ND ND ND ND ND 3-Dec-12 1.0 1.0 ND 2.3 ND ND ND ND ND ND ND 11-Jun-13 1.0 1.0 ND 2.0 ND NS ND ND ND ND ND 29-Oct-13 1.0 1.0 ND 4.5 ND 2.0 ND ND ND ND ND 6-May-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 0.5 1.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 0.5 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 0.5 1.0 NS 0.91 J ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 0.5 1.0 NS 2.0 0.78 J ND ND ND ND ND ND 6-May-19 EPA 6010D 0.5 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 0.4 1.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 6010D 0.4 1.0 NS ND 0.51 J ND ND ND ND ND --- 9-Nov-20 EPA 6010D 0.4 1.0 NS ND ND 0.62 J 0.58 J ND ND ND ND 4-May-21 EPA 6010D 0.4 1.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 6010D 0.4 1.0 NS ND ND ND ND ND 0.65 J ND ND 17-May-22 EPA 6020B 0.1 0.5 ND ND 0.26 J 0.12 J ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 5 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Chromium 28-Apr-94 NR 20 ND ND ND NI NI NI NI NI NA 3-May-00 NR 10 NA 16.0 ND ND 14.0 14.0 12.0 ND ND 8-Nov-00 NR 10 NA 17.0 ND ND ND 20.0 ND ND ND 29-May-01 NR 10 NA 12.0 J ND ND ND 10.0 J ND ND ND 6-Nov-01 NR 10 NA 12.0 ND ND ND ND ND ND ND 21-May-02 NR 10 NA 10.0 J ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 12.0 ND ND ND ND ND ND ND 14-May-03 NR 10 12.0 ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND ND ND ND ND NC2L = 50 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND 2.9 J ND ND ND ND 28-May-08 0.4 10.0 Dry ND ND ND 2.3 B 0.80 B ND ND 0.85 J 5-Nov-08 0.40 10.0 Dry ND ND ND ND 0.46 J 0.59 J ND ND 2-Jun-09 0.40 10.0 ND ND ND ND 2.8 J 0.42 J 0.65 J ND ND 19-Nov-09 0.40 10.0 N D 1.8 B 0.65 B N D 2.7 B N D N D N D 1.1 J NC2L = 10 pg/L (01/01/10) 15-Jun-10 0.40 10.0 ND 0.89 J 2.0 J 1.7 J 12.6 1.9 J 1.3 J ND ND 29-Nov-10 0.40 10.0 ND 3.8 J 3.5 J 1.2 J 5.1 J 0.88 J ND ND ND 31-May-11 0.40 10.0 1.4 B 2.1 B 8.4 J 1.3 B 3.6 B 2.1 B 2.2 B 2.5 B 0.73 J 19-Dec-11 5.0 10.0 ND ND ND ND 15.4 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 8.3 J ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS 5.2 J ND ND 6.2 J ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 8.8 J ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND 2.8 J ND ND 4.2 J ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 3.7 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 NS 3.1 J ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6O10D 2.5 5.0 NS ND ND ND 3.4 J ND ND ND ND 6-May-19 EPA 6O10D 2.5 5.0 NS 2.5 J ND ND ND ND ND ND ND 5-Nov-19 EPA 6O10D 1.0 5.0 NS ND ND ND 5.9 1.8 J ND ND --- 6-May-20 EPA 6O10D 3.7 5.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 6O10D 3.7 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6O10D 3.7 5.0 NS ND ND ND ND 8 ND ND ND 2-Nov-21 EPA 6O10D 3.7 5.0 NS ND ND ND 4.3 J ND ND ND ND 17-May-22 EPA 602OB 1.1 5.0 ND 1.5 J 1.6 J ND 1.2 J ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 6 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Cobalt 6-Oct-94 NR 10 32.0 172 35.0 NI NI NI NI NI NA 3-May-00 NR 10 NA 110 26.0 ND ND 18.0 21.0 ND ND 8-Nov-00 NR 10 NA 110 ND ND ND 25.0 11.0 ND ND 29-May-01 NR 10 NA 130 21.0 ND ND 12.0 ND ND ND 6-Nov-01 NR 10 NA 110 14.0 ND ND ND ND ND ND 21-May-02 NR 10 NA 110 15.0 ND ND ND ND ND ND 13-Nov-02 NR 10 NA 110 15.0 12.0 ND ND ND ND ND 14-May-03 NR 10 140 100 26.0 ND ND ND ND ND ND 19-Nov-03 NR 10 150 110 27.0 ND ND ND ND ND ND 5-May-04 NR 10 51.0 110 17.0 13.0 ND ND ND ND ND 9-Nov-04 NR 10 54.0 100 ND ND ND ND ND ND ND 25-May-05 NR 10 79.0 95.0 15.0 ND ND ND ND ND ND 2-Nov-05 NR 10 47.0 100 ND ND ND ND ND ND ND 24-May-06 NR 10 62.9 116 10.0 ND ND 10.4 ND ND ND 1-Nov-06 NR 10 63.2 114 ND ND ND ND ND ND ND 29-May-07 NR 10 60.1 105 6.3 J 10.7 ND ND 2.4 J ND ND GWPS = 70 pg/L (10/23/07) 28-Nov-07 NR 10 43.1 110 3.6 J 5.1 J ND ND ND ND ND 28-May-08 0.6 10.0 Dry ND ND 8.8 J ND ND ND ND ND 5-Nov-08 0.60 10.0 Dry 35.7 ND 9.4 B 0.86 B 3.9 B 5.3 B 1.6 B 3.5 J 1-J u n-09 0.60 10.0 158 158 52.8 10.9 B 12.3 B 7.8 B 14.9 B 6.8 B 3.3 J 19-Nov-09 0.60 10.0 126 87.7 18.7 4.5 J ND 0.96 J 5.9 J ND ND 15-Jun-10 0.60 10.0 155 186 53.3 2.9 J 5.2 J 2.2 J 2.9 J 2.3 J ND GWPS = 1 pg/L (10/1/10) 29-Nov-10 0.60 10.0 110 233 67.3 0.69 J ND 1.2 J 3.9 J 3.7 J ND 31-May-11 0.60 10.0 38.6 111 19.2 19.3 1.3 J ND 1.1 J ND ND 19-Dec-11 5.0 10.0 ND 63.8 ND ND ND ND ND ND ND 30-May-12 5.0 10.0 85.6 144 38.4 5.2 J ND ND ND ND ND 3-Dec-12 5.0 10.0 36.0 92.9 10.4 5.2 J ND ND ND ND ND 11-Jun-13 5.0 10.0 178 220 85.7 NS 5.4 J ND 7.1 J 5.8 J ND 29-Oct-13 5.0 10.0 226 267 96.1 ND ND ND ND 6.6 J ND 6-May-14 EPA 6010 5.0 10.0 39.0 65.2 ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 43.8 118 9.1 J ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 47.7 117 10.7 ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 52.0 126 13.9 ND ND ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 56.2 120 15.6 ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 24.6 99.8 7.1 J ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 NS 137 12.4 ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 NS 114 11.0 ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 NS 102 20.2 ND ND ND 4.2 J ND ND IMAC = 1 pg/L (10/1/10) 4-Dec-18 EPA 6010D 2.5 5.0 NS 120 17.3 2.6 J ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 NS 107 14.4 ND ND ND ND ND ND 5-Nov-19 EPA 6010D 1.1 5.0 NS 119 12.3 ND 1.6 J 1.3 J ND ND --- 6-May-20 EPA 6010D 3.6 5.0 NS 106 16.8 ND ND ND ND ND --- 9-Nov-20 EPA 6010D 3.6 5.0 NS 122 14.2 ND ND ND ND ND ND 4-May-21 EPA 6010D 3.6 5.0 NS 95.4 13.7 ND ND 8.7 ND ND ND 2-Nov-21 EPA 6010D 3.6 5.0 NS 116 12.4 ND ND ND ND ND ND 17-May-22 EPA 6020B 0.4 5.0 9.7 114 15.8 1.1 J 0.76 J 0.47 J 0.88 J ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 7 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Copper 12-May-99 NR 5 13.0 22.0 ND ND 45.0 5.1 NI NI ND 19-Oct-99 NR 200 ND ND ND ND ND ND NI NI ND 3-May-00 NR 200 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 200 NA ND ND ND ND ND ND ND ND 29-May-01 NR 200 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 200 NA ND ND ND ND ND ND ND ND 21-May-02 NR 200 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 200 NA ND ND ND ND ND ND ND ND 14-May-03 NR 200 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 200 ND ND ND ND ND ND ND ND ND 5-May-04 NR 200 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 200 ND ND ND ND ND ND ND ND ND 25-May-05 NR 200 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 200 ND ND ND ND ND ND ND ND ND 24-May-06 NR 200 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 200 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 1.7 J ND ND 1.6 J ND ND NC2L = 1,000 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND 3.30 J ND ND ND ND 28-May-08 0.3 10 Dry 0.49 B ND ND 2.8 J 0.76 B 0.50 B ND 0.38 J 5-Nov-08 0.30 10 Dry 0.89 B ND ND ND ND 0.72 B ND 0.94 J 2-Jun-09 0.30 10 9.7 J ND ND ND 1.5 J ND ND ND ND 19-Nov-09 0.30 10 5.3 J ND 0.35 J ND 2.1 J 0.41 J 1.0 J ND ND 15-Jun-10 0.30 10 13.9 ND ND ND 11.0 5.9 J 1.4 J ND ND 29-Nov-10 0.30 10 2.0 J ND 2.6 J 0.31 J 6.0 J 1.2 J 1.2 J ND ND 31-May-11 0.30 10 4.5 J 5.1 J 13.2 ND 0.98 J ND ND ND ND 19-Dec-11 5.0 10 10.9 ND 5.5 J ND 14.1 ND ND ND ND 30-May-12 5.0 10 ND ND ND ND 10.8 ND ND ND ND 3-Dec-12 5.0 10.0 5.2 J ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 13.1 B 5.1 B ND NS ND ND ND ND 10.8 29-Oct-13 5.0 10.0 10.2 ND ND 8.9 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 5.2 J 3.7 J ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 7.9 J 7.7 J 3.6 J ND 7.4 J ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 5.8 J ND ND ND 3.6 J ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 7.9 J ND ND 3.2 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 NS 5.9 J 2.8 J 51.3 ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6O10D 2.5 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6O10D 2.5 5.0 NS 8.3 5.8 3.2 J ND 3.1 J ND ND ND 5-Nov-19 EPA 6O10D 2.1 5.0 NS 3.3 J ND ND 4.6 J ND ND ND --- 6-May-20 EPA 6O10D 4.3 5.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 6O10D 4.3 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6O10D 4.3 5.0 NS ND ND ND ND 6.2 ND ND ND 2-Nov-21 EPA 6O10D 4.3 5.0 NS ND ND ND 4.5 J ND ND ND ND 17-May-22 EPA 602OB 1.0 5.0 2.4 J ND 3.4 J ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 8 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Lead 28-Apr-94 NR 1 6.0 5.0 2.0 NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND 12.0 ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND 31.0 10.0 ND ND 29-May-01 NR 10 NA 12.0 J ND ND ND 12.0 J ND ND ND 6-Nov-01 NR 10 NA 11.0 ND ND ND ND ND ND ND 21-May-02 NR 10 NA 10.0 J ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 14.0 ND ND ND ND ND ND ND 14-May-03 NR 10 38.0 10.0 J ND ND ND ND ND ND ND 19-Nov-03 NR 10 16.0 ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND 14.0 ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND 11.7 ND ND ND 22.6 ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 2.5 B 4.2 B 3.5 B 4.6 B 6.0 B 4.5 B 2.9 B ND 6.1 J NC2L = 15 pg/L (10/23/07) 28-Nov-07 NR 10 9.8 J 7.4 J 2.0 J ND ND ND ND ND ND 28-May-08 4 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 4.0 10.0 Dry ND ND ND ND ND ND ND ND 1-Jun-09 4.0 10.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 4.0 10.0 4.6 J ND ND ND ND ND ND ND ND 15-Jun-10 4.0 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 4.0 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 4.0 10.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 5.0 10.0 6.1 J ND ND ND 5.4 J ND ND ND ND 30-May-12 5.0 10.0 ND 5.9 J ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 10.0 6.7 J ND ND 5.4 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND 5.1 J ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 2.9 J 6.2 J ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 4.6 J 6.6 J 2.9 J 4.4 J 2.6 J 3.0 J ND ND ND 2-May-16 EPA 6010 2.5 10.0 4.4 J 5 J ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 6.1 J 6.1 J ND 3.9 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 NS 6.8 J 2.6 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 NS 5.4 J ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 NS ND ND ND ND 3.5 J 4.1 J ND ND 4-Dec-18 EPA 6O10D 2.5 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6O10D 2.5 5.0 NS 4.9 J 3.2 J ND ND ND ND ND ND 5-Nov-19 EPA 6O10D 1.6 5.0 NS 5.2 2.0 J ND ND ND ND ND --- 6-May-20 EPA 6O10D 4.5 5.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 6O10D 4.5 5.0 NS 9.3 ND ND ND ND ND ND ND 4-May-21 EPA 6O10D 4.5 5.0 NS ND ND ND ND 10.4 ND ND ND 2-Nov-21 EPA 6O10D 4.5 5.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 602OB 0.9 1.0 ND ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 9 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Nickel 12-May-99 NR 5 11.0 36.0 11.0 NA 23.0 30.0 NI NI ND 19-Oct-99 NR 50 ND ND ND ND ND 59.0 NI NI ND 3-May-00 NR 50 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 50 NA ND ND ND ND ND ND ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND ND ND ND ND 5-May-04 NR 50 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 50 ND ND ND 21.3 J ND ND ND ND ND NC2L = 100 pg/L (10/23/07) 28-Nov-07 NR 50 ND 2.4 J ND 20.4 J 2.5 J ND ND ND ND 28-May-08 1.7 50.0 Dry 9.1 J 10.5 J 31.9 J 2.1 J ND ND ND ND 5-Nov-08 1.7 50.0 Dry 11.6 J 5.9 B 26.3 J 2.8 B ND ND ND 2.2 J 2-Jun-09 1.7 50.0 14 J 8.9 J 3.8 J 21.8 J 2.3 J ND ND ND ND 19-Nov-09 1.7 50.0 10.3 B 8.6 B 3.1 B 19.8 J 2.3 B N D N D N D 2.2 J 15-Jun-10 1.7 50.0 5.9 J 6.7 J ND 14.5 J 4.8 J ND ND ND ND 29-Nov-10 1.7 50.0 4.7 J 7.6 J ND 17.3 J ND ND ND ND ND 31-May-11 1.7 50.0 3.5 B 15.9 J 11.8 J 23.0 J 2.8 B ND ND ND 2.3 J 19-Dec-11 5.0 50.0 ND 8.8 J ND 18.9 J ND ND ND ND ND 30-May-12 5.0 50.0 ND 9.4 J ND 19.9 J ND ND ND ND ND 3-Dec-12 5.0 50.0 ND 7.5 J ND 20.8 J ND ND ND ND ND 11-Jun-13 5.0 50.0 ND 6.8 J ND NS ND ND ND ND ND 29-Oct-13 5.0 50.0 ND 7.1 J ND 20.6 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 50.0 ND 10.1 J ND 21.1 J ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 50.0 ND 16.9 J ND 24.3 J ND ND ND ND ND 19-May-15 EPA 6010 2.5 50.0 ND 15.8 J 3.1 J 23.8 J ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 50.0 2.6 J 17.0 J 4.3 J 26.4 J 3.8 J ND ND ND ND 2-May-16 EPA 6010 2.5 50.0 ND 14.9 J 3.8 J 23.3 J ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 50.0 2.6 J 14.6 J 3.5 J 21.0 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 50.0 NS 20.9 J 4.6 J 25.6 J ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 50.0 NS 17.6 J 3.6 J 26.6 J ND ND ND ND ND 14-May-18 EPA 6010 2.5 50.0 NS 13.9 J 5.1 J 27.9 J ND ND ND ND ND 4-Dec-18 EPA 6O10D 2.5 5.0 NS 17.2 4.3 J 26.3 ND ND ND ND ND 6-May-19 EPA 6O10D 2.5 5.0 NS 14.5 4.4 J 25.7 3.0 J ND ND ND ND 5-Nov-19 EPA 6O10D 0.9 5.0 NS 16.8 3.3 J 28.7 2.4 J 1.0 J ND ND --- 6-May-20 EPA 6O10D 3.5 5.0 NS 14.4 5.4 24.1 ND ND ND ND --- 9-Nov-20 EPA 6O10D 3.5 5.0 NS 21.7 4.9 J 27.1 ND ND ND ND ND 4-May-21 EPA 6O10D 3.5 5.0 NS 14.4 ND 26.9 ND 5.6 ND ND ND 2-Nov-21 EPA 6O10D 3.5 5.0 NS 20.5 5.3 28.9 ND ND ND ND ND 17-May-22 EPA 602OB 0.7 5.0 1.9 J 18.8 4.3 J 27.0 1.7 J ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 10 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Selenium 12-May-97 NR 5 ND ND ND NI NI NI NI NI NA 3-May-00 NR 20 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 20 NA ND ND ND ND ND ND ND ND 29-May-01 NR 20 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 20 NA ND ND ND ND ND ND ND ND 21-May-02 NR 20 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 20 NA ND ND ND ND ND ND ND ND 14-May-03 NR 20 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 20 ND ND ND ND ND ND ND ND ND 5-May-04 NR 20 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 20 ND ND ND ND ND ND ND ND ND 25-May-05 NR 20 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 20 ND ND ND ND ND ND ND ND ND 24-May-06 NR 20 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 20 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND 2.5 J 4.6 J ND ND ND NC2L = 50 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND 2.4 J 28-May-08 3.8 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 3.8 10.0 Dry 29.6 12.3 B ND ND 5.6 B ND 5.1 B 4.2 J 2-Jun-09 3.8 10.0 ND 5.6 J ND ND ND ND ND ND ND 19-Nov-09 3.8 10.0 ND 5.6 J ND ND ND 5.5 J 5.0 J ND ND NC2L = 20 pg/L (01/01/10) 15-Jun-10 3.8 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 3.8 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 3.8 10.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 10.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 10.0 10.0 11.5 16.8 ND ND ND ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 10.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 10.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 10.0 10.0 ND ND ND 16.2 ND ND ND ND ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 5.0 10.0 ND 5.2 J 5.7 J ND ND ND ND ND ND 12-Dec-16 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6O10D 5.0 10.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6O10D 5.0 10.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6O10D 4.7 10.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 6O10D 4.7 10.0 NS 9.2 J ND ND ND 7.2 J ND ND --- 9-Nov-20 EPA 6O10D 4.7 10.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6O10D 4.7 10.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 6O10D 4.7 10.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 602OB 1.4 5.0 ND ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 11 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Silver 28-Apr-94 NR 1 ND ND ND NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10.0 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 2.5 J ND ND 2.2 J ND ND NC2L = 17.5 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND ND 28-May-08 0.1 10.0 Dry 1.4 J 0.41 J 0.54 J ND ND ND ND ND 5-Nov-08 0.10 10.0 Dry 2.4 J 0.86 B 0.87 B 0.12 B 0.15 B 0.18 B 0.18 B 0.20 J 2-Jun-09 0.10 10.0 ND 0.90 J ND 0.37 J ND ND ND ND ND 19-Nov-09 0.10 10.0 0.68 J 1.7 J 0.86 J 1.0 J 0.19 J 0.22 J 0.30 J 0.30 J ND NC2L = 20 pg/L (01/01/10) 15-Jun-10 0.10 10.0 ND 0.25 J 0.31 J 0.50 J 0.15 J ND ND 0.14 J ND 29-Nov-10 0.10 10.0 ND 0.58 J 0.11 J 0.59 J ND ND ND ND ND 31-May-11 0.10 10.0 0.91 J 2.9 J 0.81 J 0.71 J ND 0.11 J 0.30 J ND ND 19-Dec-11 5.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6O10D 2.5 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6O10D 2.5 5.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6O10D 2.5 5.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 6O10D 2.5 5.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 6O10D 2.5 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6O10D 2.5 5.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 6O10D 2.5 5.0 NS 5.6 2.6 J ND ND ND ND ND ND 17-May-22 EPA 602OB 0.4 5.0 ND ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 12 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Thallium 19-Oct-99 NR 10 ND ND ND ND ND ND NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND NA 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 26.0 ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 10.0 ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 13.0 16.0 12.0 ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5.5 ND ND ND ND ND 0.066 ND ND ND GWPS = 0.28 pg/L (10/23/07) 28-Nov-07 NR 5.5 0.215 J ND ND ND 0.155 J 0.074 J ND ND ND 28-May-08 3 5.5 Dry ND ND ND 3.8 J ND ND ND ND 5-Nov-08 3.0 5.5 Dry 3.1 J ND ND ND ND ND ND ND 2-Jun-09 3.0 5.5 ND ND ND ND ND ND ND ND ND 19-Nov-09 3.0 5.5 ND ND ND ND ND 3.5 J ND ND ND 15-Jun-10 3.0 5.5 5.5 B 7.8 B 4.2 B ND ND 7.0 B ND ND 3 J GWPS = 0.2 pg/L (10/1/10) 29-Nov-10 3.0 5.5 4.6 B 4.1 B 4.1 B ND ND {4.8} J ND ND 4.0 {ND} J 31-May-11 3.0 5.5 ND ND ND ND ND ND ND ND ND 19-Dec-11 5.4 5.5 ND ND ND ND ND ND ND ND ND 30-May-12 5.4 5.5 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.4 5.5 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.4 5.5 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.4 5.5 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.4 5.5 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.4 5.5 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 5.0 5.5 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 5.0 5.5 6.9 7.5 ND ND ND ND ND ND ND 2-May-16 EPA 6010 5.0 5.5 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 5.0 5.5 8.3 B ND ND ND ND ND ND ND 5.5 J 26-Jun-17 EPA 602OB 0.0 5.5 NS ND ND ND ND 0.075 J ND ND ND 14-Dec-17 EPA 602OB 0.03 0.1 NS ND ND ND ND 0.061 J ND ND ND 14-May-18 EPA 6020 0.50 5.5 NS ND ND ND ND ND ND ND ND IMAC = 0.2 pg/L (10/1/10) 4-Dec-18 EPA 602OB 0.06 0.1 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 602OB 0.06 0.1 NS ND ND ND ND 0.087 J ND ND ND 5-Nov-19 EPA 602OB 0.06 0.1 NS ND ND 0.061 J 0.060 J 0.16 ND ND --- 6-May-20 EPA 602OB 0.12 0.2 NS ND ND ND ND 0.20 ND ND --- Resample -> 16-Jul-20 EPA 602OB 0.12 0.2 NS NS NS NS NS ND NS NS --- 9-Nov-20 EPA 602OB 0.05 0.1 NS ND ND ND ND 0.11 ND ND ND 4-May-21 EPA 602OB 0.05 1 NS ND ND ND 0.058 J 0.67 J ND ND ND 2-Nov-21 EPA 602OB 0.05 0.47 NS ND ND ND ND 0.15 J ND ND ND 17-May-22 EPA 602OB 0.18 1 ND ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 13 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Vanadium 19-Oct-99 NR 40 110 51.0 ND ND 61.0 210 NI NI ND 3-May-00 NR 40 NA 61.0 ND ND ND 49.0 ND ND ND 8-Nov-00 NR 40 NA ND ND ND ND 69.0 ND ND ND 29-May-01 NR 40 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 40 NA ND ND ND ND ND ND ND ND 21-May-02 NR 40 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 40 NA ND ND ND ND ND ND ND ND 14-May-03 NR 40 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 40 ND ND ND ND ND ND ND ND ND 5-May-04 NR 40 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 40 ND ND ND ND ND ND ND ND ND 25-May-05 NR 40 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 40 ND ND ND ND ND ND ND ND ND 24-May-06 NR 40 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 40 ND ND ND ND ND ND ND ND ND 29-May-07 NR 25 ND ND ND ND ND ND 1.5 J ND ND GWPS = 3.5 pg/L (10/23/07) 28-Nov-07 NR 25 ND ND ND ND 10.0 J 1.1 J ND ND ND 28-May-08 0.2 25.0 Dry 0.75 J 0.90 J ND 5.5 J 2.5 J 1.2 J 0.22 J ND 5-Nov-08 0.20 25.0 Dry 1.2 B 0.78 B ND 0.86 B 0.82 B 1.5 B ND 0.85 J 2-J u n-09 0.20 25.0 1.0 B 3.1 B 1.8 B 1.0 B 9.5 J 1.3 B 2.4 B 0.41 B 1.2 J 19-Nov-09 0.20 25.0 0.74 B 2.2 B 2.9 B 0.86 B 6.6 J 1.2 B 2.0 B 0.25 B 0.58 J 15-Jun-10 0.20 25.0 2.0 B 1.4 B 1.3 B 0.34 B 27.4 5.0 B 2.2 B ND 1.2 J GWPS = 0.3 pg/L (10/1/10) 29-Nov-10 0.20 25.0 ND 1.3 J 5.4 J 1.6 J 9.4 J 1.4 J 0.45 J ND ND 31-May-11 0.20 25.0 ND ND 12.0 J 3.3 J 6.1 J 2.2 J 0.85 J 0.31 J ND 19-Dec-11 5.0 25.0 6.6 J ND 6.2 J ND 24.3 J 6.3 J ND ND ND 30-May-12 5.0 25.0 ND ND ND ND 19.3 J ND ND ND ND 3-Dec-12 5.0 25.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 25.0 ND ND ND NS 13.2 J ND ND ND ND 29-Oct-13 5.0 25.0 ND ND ND ND 7.5 J ND ND ND ND 6-May-14 EPA 6010 5.0 25.0 ND ND ND ND 7.6 J ND ND ND ND 21-Oct-14 EPA 6010 5.0 25.0 ND 5.4 J ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 25.0 5.7 J 13.0 J 5.3 J ND 4.3 J ND ND ND ND 7-Dec-15 EPA 6010 2.5 25.0 8.3 J 16.6 J 7.3 J ND 19.4 J 5.6 J ND ND ND 2-May-16 EPA 6010 2.5 25.0 3.9 J 5.0 J 3.7 J ND 7.9 J 3.4 J ND ND ND 12-Dec-16 EPA 6010 2.5 25.0 6.0 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 25.0 NS 4.2 J 3.3 J ND ND 2.9 J ND ND ND 14-Dec-17 EPA 6010 2.5 25.0 NS 5.1 J ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 25.0 NS 3.6 J ND ND 2.5 J 5.8 J 2.7 J ND ND IMAC = 0.3 pg/L (10/1/10) 4-Dec-18 EPA 6010D 2.5 5.0 NS ND 3.0 J ND 6.0 ND ND ND ND Resample --> 8-Feb-19 EPA 6010D 2.5 5.0 NS --- --- --- ND --- --- --- --- 6-May-19 EPA 6010D 2.5 5.0 NS 4.1 J ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 1.3 5.0 NS 5.3 1.8 J ND 10.0 3.8 J ND ND --- Resample --> 23-Jan-20 EPA 6010D 1.3 5.0 NS 5.1 --- --- 2.3 J --- --- --- --- 6-May-20 EPA 6010D 3.9 5.0 NS ND ND ND ND 7.2 ND ND --- Resample --> 16-Jul-20 EPA 6010D 3.9 5.0 NS NS NS NS NS ND NS NS --- 9-Nov-20 EPA 6010D 3.9 5.0 NS --- 9.5 ND ND ND ND ND ND Resample --> 27-Jan-21 EPA 6010D 3.9 5.0 NS --- ND --- --- --- --- --- --- 4-May-21 EPA 6010D 3.9 5.0 NS 7.3 ND ND 7.9 19.4 ND ND ND 2-Nov-21 EPA 6010D 3.9 5.0 NS 59.9 23.3 ND 9.9 5.1 ND ND ND 17-May-22 EPA 6020B 1.9 10.0 ND ND 2.3 J ND ND ND ND 2.5 J --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 14 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Zinc 28-Apr-94 NR 10 12.0 ND ND NI NI NI NI NI NA 3-May-00 NR 50 NA ND ND 81.0 50.0 J ND ND ND ND 8-Nov-00 NR 50 NA 50.0 ND ND 50.0 100 50.0 ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND 80.0 ND ND ND 5-May-04 NR 50 110 ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 5.1 B ND ND 7.9 B 5.0 B 4.5 B 3.2 B 4.7 B 2.0 J NC2L = 1,050 pg/L (10/23/07) 28-Nov-07 NR 10 26.3 ND 4.5 J 8.4 J 6.7 J 5.8 J ND 4.2 J ND 28-May-08 0.4 10.0 Dry 18.9 2.9 B 93.9 5.7 B 7.0 B 5.5 B 4.9 B 2.1 J 5-Nov-08 0.40 10.0 Dry ND ND 5.2 B ND 2.7 B 2.2 B 1.4 B 8.9 J 2-J u n-09 0.40 10.0 19.1 B 0.48 B N D 6.5 B 8.2 B 4.8 B 3.2 B 0.65 B 83.0 19-Nov-09 0.40 10.0 20.4 7.4 B 12.1 B 15.4 B 6.7 B 11.2 B 5.6 B 5.6 B 3.5 J NC2L = 1,000 pg/L (01/01/10) 15-Jun-10 0.40 10.0 16.9 0.50 J ND 2.3 J 15.0 9.2 J 3.8 J ND ND 29-Nov-10 0.40 10.0 9.6 J 15.3 8.8 J 2.9 J 6.0 J 13.8 1.1 J ND ND 31-May-11 0.40 10.0 6.5 B 11.9 B 47.1 B 12.5 B 12.0 B 10.4 B 9.9 B 4.8 B 13.7 19-Dec-11 10.0 10.0 47.0 ND 13.7 183 24.6 15.6 ND ND ND 30-May-12 10.0 10.0 ND 12.1 ND ND 12.0 ND 13.8 ND ND 3-Dec-12 10.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 10.0 10.0 17.9 B 12.0 B 14.8 B NS ND ND ND ND 76.3 29-Oct-13 10.0 10.0 12.9 ND ND 118 10.1 ND ND ND ND 6-May-14 EPA 6010 10.0 10.0 ND ND ND 17.5 ND ND ND ND ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND ND 19.7 ND ND ND ND ND 19-May-15 EPA 6010 5.0 10.0 ND ND ND 6.1 J ND 5.7 J ND 5.5 J ND 7-Dec-15 EPA 6010 5.0 10.0 6.5 B ND 8.7 B 5.2 B 16.3 B 11.2 B ND ND 7.2 J 2-May-16 EPA 6010 5.0 10.0 6.0 J ND 7.6 J 10.2 7.1 J 6.5 J ND ND ND 12-Dec-16 EPA 6010 5.0 10.0 9.2 J ND 27.8 26.3 ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 NS ND 5.9 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 NS ND ND 28.8 ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 NS 6.2 J ND 5.4 J ND 9.7 J 11.5 ND ND 4-Dec-18 EPA 6O10D 5.0 10.0 NS ND 12.7 ND 5.3 J ND ND ND ND 6-May-19 EPA 6O10D 5.0 10.0 NS ND 5.9 J ND ND 7.5 J ND 7.6 J ND 5-Nov-19 EPA 6O10D 3.9 10.0 NS ND ND ND 15.4 7.5 J ND 7.0 J --- 6-May-20 EPA 6O10D 9.5 10.0 NS ND ND ND ND 12.6 ND ND --- 9-Nov-20 EPA 6O10D 9.5 10.0 NS ND 14.7 ND ND ND ND ND ND 4-May-21 EPA 6O10D 9.5 10.0 NS ND ND ND 10.6 34.6 ND ND ND 2-Nov-21 EPA 6O10D 9.5 10.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 602OB 7.0 10.0 81.5 ND 7.3 J ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 15 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Organics Acetone 28-Apr-94 NR 100 200 2000 ND NI NI NI NI NI NA 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 390 600 ND ND ND ND ND ND ND 19-Nov-03 NR 100 4900 180 ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 230 ND ND ND ND ND ND ND ND 25-May-05 NR 100 580 ND ND ND ND ND ND ND ND 2-Nov-05 NR 100 450 ND ND ND ND ND ND ND ND 24-May-06 NR 100 1380 D ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 340 ND ND ND ND ND ND ND ND 29-May-07 NR 100 1070 28.0 J ND ND ND ND ND ND ND NC2L = 700 pg/L (10/23/07) 28-Nov-07 NR 100 690 D ND ND ND 2.8 B 2.5 B ND 2.7 B 4.3 J 28-May-08 20 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 20.0 100 Dry 34.4 J ND ND ND ND ND ND ND 2-Jun-09 2.2 100 13.3 B 45.7 J ND ND 3.9 B ND ND ND 3.2 J 19-Nov-09 2.2 100 3.1 B N D N D 159 50.0 J 5.4 B N D N D 3.8 J NC2L = 6,000 pg/L (01/01/10) 15-Jun-10 2.2 100 193 101 5.7 B 5.4 B ND ND ND ND 9.8 J 29-Nov-10 2.2 100 123 15.7 B ND ND ND ND ND ND 4.3 J 31-May-11 2.2 100 26.3 B ND ND 10.3 B ND ND ND ND 3.9 J 19-Dec-11 2.2 100 24.4 B ND ND ND ND ND ND ND 6.6 J 30-May-12 2.2 100 283 91.3 J ND ND ND ND ND ND ND 3-Dec-12 10.0 100 43.4 J 46.8 J ND ND ND ND ND ND ND 11-Jun-13 10.0 100 763 1190 J ND NS ND ND ND ND ND 29-Oct-13 50.0 500 611 32.9 J ND ND ND ND ND ND ND 6-May-14 EPA 8260 10.0 100 104 109 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 10.0 100 91.2 J ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 10.0 100 239 J ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 10.0 100 118 21.8 J ND ND ND ND ND ND ND 2-May-16 EPA 8260 10.0 100 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 10.0 100 69.0 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 10.0 100 NS ND ND ND 10.6 J 23.6 J 12.5 J 20.7 J 23.0 J 14-Dec-17 EPA 8260 10.0 100 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 10.0 100 NS 484 ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 10.0 25 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 8.2 25 NS 299 ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 6.2 25 NS 105 ND ND ND ND ND ND --- 6-May-20 EPA 8260D 6.2 25 NS 255 ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 6.2 25 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 25.6 125 NS 1160 M ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 5.1 25 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 8260D 5.1 25 15.1 J ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 16 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Benzene 28-Apr-94 NR 5 ND 15.0 8.7 NI NI NI NI NI NA 3-May-00 NR 5 NA 9.2 10.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 9.4 6.3 ND ND ND ND ND ND 29-May-01 NR 5 NA 9.4 7.4 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 7.3 6.4 ND ND ND ND ND ND 21-May-02 NR 5 NA 9.2 8.4 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 7.6 6.8 ND ND ND ND ND ND 14-May-03 NR 5 ND ND 8.6 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 8.9 6.4 ND ND ND ND ND ND 5-May-04 NR 5 ND 7.3 6.4 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 8.4 6.4 ND ND ND ND ND ND 25-May-05 NR 5 ND 9.0 6.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 6.0 ND ND ND ND ND ND ND 24-May-06 NR 5 ND 5.5 ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND 7.5 ND ND ND ND ND ND ND 29-May-07 NR 1 1.1 8.3 5.5 3.0 ND ND ND ND ND NC2L = 1 pg/L (10/23/07) 28-Nov-07 NR 1 ND 7.0 3.9 ND ND ND ND ND ND 28-May-08 0.3 1.0 Dry 6.4 5.1 2.5 0.78 J ND ND ND ND 5-Nov-08 0.25 1.0 Dry 5.8 4.0 2.3 1.1 ND ND ND ND 2-Jun-09 0.25 1.0 1.2 6.4 6.6 2.1 0.58 J ND ND ND ND 19-Nov-09 0.25 1.0 ND ND ND 0.82 J 6.5 5.9 ND ND ND 15-Jun-10 0.25 1.0 1.1 7.9 5.1 1.9 ND ND ND ND ND 29-Nov-10 0.25 1.0 ND 7.1 4.2 2.2 ND ND ND ND ND 31-May-11 0.25 1.0 0.45 J 7.6 4.6 2.0 0.60 J ND ND ND ND 19-Dec-11 0.25 1.0 0.77 J 7.4 4.9 2.2 0.89 J ND ND ND ND 30-May-12 0.25 1.0 0.5 J 6.6 ND 1.6 ND ND ND ND ND 3-Dec-12 0.25 1.0 0.31 J 6.9 4.5 1.6 ND ND ND ND ND 11-Jun-13 0.25 1.0 1.5 8.9 5.7 NS ND ND ND ND ND 29-Oct-13 0.25 1.0 0.81 J 8.7 4.5 1.4 ND ND ND ND ND 6-May-14 EPA 8260 0.25 1.0 0.37 J 9.5 5.4 1.6 ND ND ND ND ND 21-Oct-14 EPA 8260 0.25 1.0 ND 8.4 3.9 1.3 ND ND ND ND ND 19-May-15 EPA 8260 0.25 1.0 ND 7.2 4.1 1.3 ND ND ND ND ND 7-Dec-15 EPA 8260 0.25 1.0 ND 7.7 4.3 1.3 ND ND ND ND ND 2-May-16 EPA 8260 0.25 1.0 0.48 J 9.1 3.9 1.2 ND ND ND ND ND 12-Dec-16 EPA 8260 0.25 1.0 ND 8.0 3.5 1.3 ND ND ND ND ND 26-Jun-17 EPA 8260 0.25 1.0 NS 6.7 3.7 1.3 ND ND ND ND ND 14-Dec-17 EPA 8260 0.25 1.0 NS 6.3 3.9 1.2 ND ND ND ND ND 14-May-18 EPA 8260 0.25 1.0 NS 6.2 3.9 1.1 ND ND ND ND ND 4-Dec-18 EPA 8260B 0.25 1.0 NS 7.5 3.8 1.3 ND ND ND ND ND 6-May-19 EPA 8260D 0.20 1.0 NS 10.4 4.6 1.7 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.15 1.0 NS 8.3 3.4 1.3 ND ND ND ND --- 6-May-20 EPA 8260D 0.15 1.0 NS 9.6 3.7 1.4 ND ND ND ND --- 9-Nov-20 EPA 8260D 0.15 1.0 NS 10.4 3.5 1.4 ND ND ND ND ND 4-May-21 EPA 8260D 0.34 1.0 NS 9.7 3.6 1.6 ND ND ND ND ND 2-Nov-21 EPA 8260D 0.34 1.0 NS 8.9 3.1 1.5 ND ND ND ND ND 17-May-22 EPA 8260D 0.34 1.0 ND 7.6 3.7 1.4 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 17 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Carbon disulfide 27-May-98 NR 5 ND ND 8.2 ND ND ND NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND ND ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 ND ND ND ND ND ND ND ND ND NC2L = 700 pg/L (10/23/07) 28-Nov-07 NR 100 ND ND ND ND ND ND ND ND ND 28-May-08 1.2 101 Dry ND ND ND ND ND ND ND ND 5-Nov-08 1.2 100 Dry ND ND ND ND ND ND ND ND 2-Jun-09 1.2 100 ND ND ND ND ND ND ND ND ND 19-Nov-09 1.2 100 ND ND ND ND ND ND ND ND ND 15-Jun-10 1.2 100 ND ND ND ND ND ND ND ND ND 29-Nov-10 1.2 100 ND ND ND ND ND ND ND ND ND 31-May-11 1.2 100 ND ND ND ND ND ND ND ND ND 19-Dec-11 1.2 100 ND ND ND ND ND ND ND ND ND 30-May-12 1.2 100 ND ND ND ND ND ND ND ND ND 3-Dec-12 1.2 100 ND ND ND ND ND ND ND ND ND 11-Jun-13 1.2 100 ND ND ND NS ND ND ND ND ND 29-Oct-13 1.2 100 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 1.2 100 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 1.2 100 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 1.2 100 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 826OB 1.2 2 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.8 10 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.4 2 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 0.4 2 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.4 2 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 3.6 10 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.7 2 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 8260D 0.4 2 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 18 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Chlorobenzene 28-Apr-94 NR 5 ND 5.4 12.0 NI NI NI NI NI NA 3-May-00 NR 5 NA 8.8 16.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 8.5 19.0 ND ND ND ND ND ND 29-May-01 NR 5 NA 9.3 18.0 ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND 17.0 ND ND ND ND ND ND 21-May-02 NR 5 NA ND 20.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND 17.0 ND ND ND ND ND ND 14-May-03 NR 5 ND ND 19.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 10.0 21.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 11.0 20.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 12.0 24.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 13.0 24.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 15.0 29.0 ND ND ND ND ND ND 24-May-06 NR 5 ND 11.3 24.3 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 15.0 29.0 ND ND ND ND ND ND 29-May-07 NR 3 0.47 J 16.0 31.0 4.9 0.28 J ND ND ND ND NC2L = 50 pg/L (10/23/07) 28-Nov-07 NR 3 ND 13.0 28.0 4.1 ND ND ND ND ND 28-May-08 0.23 3.0 Dry 13.7 24.3 4.0 0.67 J ND ND ND ND 5-Nov-08 0.23 3.0 Dry 13.5 21.6 4.0 0.89 J ND ND ND ND 2-J u n-09 0.23 3.0 0.30 J 15.0 24.7 3.9 0.49 J N D N D N D N D 19-Nov-09 0.23 3.0 ND ND 1.7 J 0.30 J 14.9 27.0 ND ND ND 15-Jun-10 0.23 3.0 0.31 J 15.5 25.7 4.0 ND ND ND ND ND 29-Nov-10 0.23 3.0 ND 15.4 28.8 5.2 0.76 J ND ND ND ND 31-May-11 0.23 3.0 ND 17.9 26.8 5.7 0.43 J ND ND ND ND 19-Dec-11 0.23 3.0 ND 17.4 28.2 5.7 0.65 J ND ND ND ND 30-May-12 0.23 3.0 0.26 J 17.8 27.6 5.4 ND ND ND ND ND 3-Dec-12 0.23 3.0 ND 18.9 29.0 5.7 ND ND ND ND ND 11-Jun-13 0.23 3.0 0.56 J 18.2 28.4 NS ND ND ND ND ND 29-Oct-13 0.23 3.0 ND 19.0 30.0 5.9 ND ND ND ND ND 6-May-14 EPA 8260 0.23 3.0 ND 19.5 32.1 6.4 ND ND ND ND ND 21-Oct-14 EPA 8260 0.23 3.0 ND 20.5 33.8 6.8 0.32 J ND ND ND ND 19-May-15 EPA 8260 0.23 3.0 ND 21.5 31.5 7.0 ND ND ND ND ND 7-Dec-15 EPA 8260 0.23 3.0 ND 20.6 33.2 7.0 ND ND ND ND ND 2-May-16 EPA 8260 0.23 3.0 0.31 J 24.2 31.1 6.6 ND ND ND ND ND 12-Dec-16 EPA 8260 0.23 3.0 ND 19.9 32.3 7.0 0.27 J ND ND ND ND 26-Jun-17 EPA 8260 0.23 3.0 NS 21.4 29.0 7.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.23 3.0 NS 22.2 30.5 6.9 ND ND ND ND ND 14-May-18 EPA 8260 0.23 3.0 NS 20.4 29.3 6.7 ND ND ND ND ND 4-Dec-18 EPA 826OB 0.23 1.0 NS 23.7 34.4 7.1 ND ND ND ND ND 6-May-19 EPA 8260D 0.53 1.0 NS 26.6 36.4 8.7 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.23 1.0 NS 22.5 32.7 7.5 ND ND 0.28 J ND --- 6-May-20 EPA 8260D 0.23 1.0 NS 26.7 32.3 8.2 ND ND ND ND --- 9-Nov-20 EPA 8260D 0.23 1.0 NS 24.7 32.7 8.0 ND ND ND ND ND 4-May-21 EPA 8260D 0.28 1.0 NS 22.1 35.9 8.7 ND ND ND ND ND 2-Nov-21 EPA 8260D 0.28 1.0 NS 24.5 32.3 8.8 ND ND ND ND ND 17-May-22 EPA 8260D 0.28 1.0 ND 27.2 33.8 9.0 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 19 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Chloroethane 12-May-99 NR 10 ND ND ND ND ND ND NI NI ND 19-Oct-99 NR 10 ND ND ND ND ND ND NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND NA ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND NA ND NA 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND ND ND ND ND NC2L = 2,800 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND 3.4 J ND ND ND ND ND ND 28-May-08 0.54 10.0 Dry ND 2.5 J ND ND ND ND ND ND 5-Nov-08 0.54 10.0 Dry ND 2.3 J ND ND ND ND ND ND 2-Jun-09 0.54 10.0 ND ND 2.7 J ND ND ND ND ND ND 19-Nov-09 0.54 10.0 ND ND ND ND 0.81 J ND ND ND ND NC2L = 3,000 pg/L (01/01/10) 15-Jun-10 0.54 10.0 ND 0.86 J 2.1 J ND ND ND ND ND ND 29-Nov-10 0.54 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.54 10.0 ND ND 4.1 J ND ND ND ND ND ND 19-Dec-11 0.54 10.0 ND 0.58 J ND 0.56 J ND ND ND ND ND 30-May-12 0.54 10.0 ND ND 1.9 J ND ND ND ND ND ND 3-Dec-12 0.54 10.0 ND 0.60 J 2.8 J ND ND ND ND ND ND 11-Jun-13 0.54 10.0 ND ND 1.2 J NS ND ND ND ND ND 29-Oct-13 0.54 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.54 10.0 ND ND 1.7 J ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.54 10.0 ND ND 2.5 J ND ND ND ND ND ND 19-May-15 EPA 8260 0.54 10.0 ND ND 2.1 J ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.54 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.54 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.54 10.0 ND ND 2.6 J ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.54 10.0 NS ND 2.0 J ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.54 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.54 10.0 NS ND 1.2 J ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.54 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.52 1.0 NS ND 1.8 0.56 J ND ND ND ND ND 5-Nov-19 EPA 8260D 0.49 1.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 0.49 1.0 NS ND 1.6 ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.49 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 3.20 5.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.65 1.0 NS ND 1.7 ND ND ND ND ND ND 17-May-22 EPA 8260D 0.65 1.0 ND ND 1.1 ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 20 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Chloroform 19-Nov-09 0.14 5.0 ND ND 0.21 J ND ND ND ND ND ND NC2L = 70 pg/L (10/23/07) 15-Jun-10 0.14 5.0 ND ND ND ND ND ND 0.33 B ND 0.28 J 29-Nov-10 0.14 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.14 5.0 ND ND ND ND ND ND 0.35 B ND 0.63 J 19-Dec-11 0.14 5.0 ND ND ND ND ND ND 0.44 J ND ND 30-May-12 0.14 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.14 5.0 ND ND ND ND ND ND 0.37 J ND ND 11-Jun-13 0.14 5.0 ND ND ND NS ND ND ND ND 42.4 29-Oct-13 0.14 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.14 5.0 ND ND ND ND ND ND 0.18 J ND ND 21-Oct-14 EPA 8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.14 5.0 ND ND ND ND ND ND 0.20 J ND NA 7-Dec-15 EPA 8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.14 5.0 ND ND ND ND ND ND 0.56 J ND ND 26-Jun-17 EPA 8260 0.14 5.0 NS ND ND ND ND ND 0.56 J ND ND 14-Dec-17 EPA 8260 0.14 5.0 NS ND ND ND ND ND 0.31 J ND ND 14-May-18 EPA 8260 0.14 5.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.14 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.58 1.0 NS ND ND ND ND ND 0.67 J ND ND 5-Nov-19 EPA 8260D 2.30 5.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 2.30 5.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 2.30 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 7.80 25.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.43 1.0 NS ND ND ND ND ND 0.88 J ND ND 17-May-22 EPA 8260D 0.43 1.0 ND ND ND ND ND ND 0.89 J ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 21 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Chloromethane 2-Jun-09 0.11 1.0 ND ND 0.28 J ND ND ND ND 0.17 J ND NC2L = 2.6 pg/L (10/23/07) 19-Nov-09 0.11 1.0 ND ND ND ND ND ND ND ND ND NC2L = 3 pg/L (01/01/10) 15-Jun-10 0.11 1.0 ND ND ND ND ND ND ND 0.14 B 0.15 J 29-Nov-10 0.11 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.11 1.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.11 1.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.11 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.11 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.11 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.11 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.11 1.0 0.33 J ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND 0.36 J 26-Jun-17 EPA 8260 0.11 1.0 NS 0.26 J 0.16 J ND 0.30 J 1 J 0.33 J 0.45 J ND 14-Dec-17 EPA 8260 0.11 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.11 1.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.11 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.38 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.39 1.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 0.39 1.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.39 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 2.70 5.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.54 1.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 8260D 0.54 1.0 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 22 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,2-Dichlorobenzene 28-Apr-94 NR 5 ND ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND 1.1 J ND ND ND ND ND ND ND NC2L = 24 pg/L (10/23/07) 28-Nov-07 NR 5 ND 2.8 J 0.63 J ND 0.74 J ND ND ND ND 28-May-08 0.3 5.0 Dry 2.6 J 0.66 J ND 0.49 J ND ND ND ND 5-Nov-08 0.30 5.0 Dry 2.2 J 0.51 J ND 0.61 J ND ND ND ND 2-Jun-09 0.30 5.0 ND 2.5 J 0.79 J ND 0.34 J ND ND ND ND 19-Nov-09 0.30 5.0 ND ND ND ND 2.7 J 1.2 J ND ND ND NC2L = 20 pg/L (01/01/10) 15-Jun-10 0.30 5.0 ND 2.3 J 1.1 J 0.33 J ND ND ND ND ND 29-Nov-10 0.30 5.0 ND 2.3 J 0.63 J ND ND ND ND ND ND 31-May-11 0.30 5.0 ND 2.2 J 0.51 J ND ND ND ND ND ND 19-Dec-11 0.30 5.0 ND 2.4 J 0.67 J ND ND ND ND ND ND 30-May-12 0.30 5.0 ND 2.3 J 0.72 J ND ND ND ND ND ND 3-Dec-12 0.30 5.0 ND 2.2 J 0.85 J 0.32 J ND ND ND ND ND 11-Jun-13 0.30 5.0 ND 2.2 J 0.91 J NS ND ND ND ND ND 29-Oct-13 0.30 5.0 ND 2.4 J 1.1 J ND ND ND ND ND ND 6-May-14 EPA 8260 0.30 5.0 ND 2.3 J 0.77 J ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.30 5.0 ND 2.5 J 0.64 J ND ND ND ND ND ND 19-May-15 EPA 8260 0.30 5.0 ND ND 0.6 J 0.3 J ND ND ND ND ND 7-Dec-15 EPA 8260 0.30 5.0 ND 2.5 J 0.57 J ND ND ND ND ND ND 2-May-16 EPA 8260 0.30 5.0 ND 2.7 J 0.7 J ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.30 5.0 ND 2.3 J 0.58 J ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.30 5.0 NS 2.4 J 0.45 J 0.33 J ND ND ND ND ND 14-Dec-17 EPA 8260 0.30 5.0 NS 2.2 J 0.66 J 0.31 J ND ND ND ND ND 14-May-18 EPA 8260 0.30 5.0 NS 1.7 J 0.79 J ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.30 1.0 NS 2.2 0.91 J ND ND ND ND ND ND 6-May-19 EPA 8260D 0.49 1.0 NS 2.4 0.88 J ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.29 1.0 NS 2.2 0.6 J ND ND ND ND ND --- 6-May-20 EPA 8260D 0.29 1.0 NS 2.2 0.64 J ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.29 1.0 NS 2.2 0.62 J ND ND ND ND ND ND 4-May-21 EPA 8260D 1.70 5.0 NS 1.7 J 0.66 J ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.34 1.0 NS 2.1 0.49 J ND ND ND ND ND ND 17-May-22 EPA 8260D 0.34 1.0 ND 2.2 0.54 J ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 23 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,4-Dichlorobenzene 28-Apr-94 NR 5 ND 34.0 22.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 50.0 12.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 54.0 13.0 ND ND ND ND ND ND 29-May-01 NR 5 NA 58.0 12.0 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 57.0 15.0 ND ND ND ND ND ND 21-May-02 NR 5 NA 59.0 14.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 52.0 13.0 ND ND ND ND ND ND 14-May-03 NR 5 ND 50.0 15.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 50.0 19.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 48.0 18.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 53.0 14.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 59.0 13.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 57.0 14.0 5.0 ND ND ND ND ND 24-May-06 NR 5 ND 42.9 11.2 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 57.0 10.0 ND ND ND ND ND ND 29-May-07 NR 1 2.3 60.0 16.0 4.7 1.1 ND ND ND ND NC2L = 1.4 pg/L (10/23/07) 28-Nov-07 NR 1 ND 48.0 10.0 ND 3.3 ND ND ND ND 28-May-08 0.33 1.0 Dry 52.9 9.5 3.8 2.5 ND ND ND ND 5-Nov-08 0.33 1.0 Dry 48.6 8.1 3.7 3.2 ND ND ND ND 2-J u n-09 0.33 1.0 1.9 58.2 12.0 4.2 2.1 N D N D N D N D 19-Nov-09 0.33 1.0 N D N D N D 2.4 49.2 18.5 N D N D N D NC2L = 6 pg/L (01/01/10) 15-Jun-10 0.33 1.0 2.1 46.2 16.4 4.2 0.93 J ND ND ND ND 29-Nov-10 0.33 1.0 1.2 45.8 12.0 4.4 1.8 ND ND ND ND 31-May-11 0.33 1.0 1.2 47.6 8.3 4.2 1.3 ND ND ND ND 19-Dec-11 0.33 1.0 2.1 44.8 10.8 4.3 1.3 ND ND ND ND 30-May-12 0.33 1.0 1.4 47.1 12.0 4.4 0.71 J ND ND ND ND 3-Dec-12 0.33 1.0 0.99 J 47.9 13.1 4.6 0.52 J ND ND ND ND 11-Jun-13 0.33 1.0 1.6 50.0 15.3 NS 0.46 J ND ND ND ND 29-Oct-13 0.33 1.0 1.4 48.3 19.2 5.0 0.48 J ND ND ND ND 6-May-14 EPA 8260 0.33 1.0 0.95 J 47.6 14.2 5.0 0.37 J ND ND ND ND 21-Oct-14 EPA 8260 0.33 1.0 1.2 45.2 12.3 5.0 0.99 J ND ND ND ND 19-May-15 EPA 8260 0.33 1.0 0.56 J 47.5 11.2 4.9 0.54 J ND ND ND ND 7-Dec-15 EPA 8260 0.33 1.0 0.81 J 47.1 11.2 4.3 ND ND ND ND ND 2-May-16 EPA 8260 0.33 1.0 0.97 J 50.5 14.7 4.4 ND ND ND ND ND 12-Dec-16 EPA 8260 0.33 1.0 0.47 J 39.7 10.1 4.9 0.69 J ND ND ND ND 26-Jun-17 EPA 8260 0.33 1.0 NS 42.6 10.5 ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.33 1.0 NS 41.6 11.5 4.5 0.69 J ND ND ND ND 14-May-18 EPA 8260 0.33 1.0 NS 35.9 13.7 4.4 0.41 J ND ND ND ND 4-Dec-18 EPA 826OB 0.33 1.0 NS 39.9 14.8 ND ND ND ND ND ND 6-May-19 EPA 8260D 0.58 1.0 NS 47.3 14.6 4.8 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.26 1.0 NS 38.6 10.7 4.2 0.48 J ND ND ND --- 6-May-20 EPA 8260D 0.26 1.0 NS 39.0 10.7 4.1 ND ND ND ND --- 9-Nov-20 EPA 8260D 0.26 1.0 NS 37.7 10.9 3.9 ND ND ND ND ND 4-May-21 EPA 8260D 0.33 1.0 NS 38.4 10.4 3.9 ND ND ND ND ND 2-Nov-21 EPA 8260D 0.33 1.0 NS 33.7 9.0 3.9 ND ND ND ND ND 17-May-22 EPA 8260D 0.33 1.0 ND 37.5 10.6 3.8 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 24 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,1-Dichloroethane 28-Apr-94 NR 5 14.0 ND 8.4 NI NI NI NI NI ND 3-May-00 NR 5 NA ND 8.4 J 7.6 J 6.1 J ND ND ND ND 8-Nov-00 NR 5 NA ND 7.0 10.0 8.1 ND ND ND ND 29-May-01 NR 5 NA ND 8.7 11.0 9.9 ND ND ND ND 6-Nov-01 NR 5 NA ND 7.3 12.0 7.0 ND ND ND ND 21-May-02 NR 5 NA ND 7.4 12.0 8.9 ND ND ND ND 13-Nov-02 NR 5 NA ND 5.4 11.0 9.0 ND ND ND ND 14-May-03 NR 5 ND ND ND 8.1 5.4 ND ND ND ND 19-Nov-03 NR 5 ND ND ND 7.9 5.3 ND ND ND ND 5-May-04 NR 5 ND ND ND 7.8 7.1 ND ND ND ND 9-Nov-04 NR 5 ND ND ND 7.5 7.0 ND ND ND ND 25-May-05 NR 5 ND ND ND 8.0 6.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND 7.0 5.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 2.8 J 2.6 J 2.7 J 8.8 11.0 ND ND ND ND NC2L = 70 pg/L (10/23/07) 28-Nov-07 NR 5 ND 0.76 J 1.2 J 5.7 11.0 ND ND ND ND 28-May-08 0.32 5.0 Dry 0.87 J 2.0 J 6.6 10.6 ND ND ND ND 5-Nov-08 0.32 5.0 Dry 0.85 J 1.9 J 6.3 11.3 ND ND ND ND 2-Jun-09 0.32 5.0 1.3 J 0.98 J 2.3 J 6.5 8.6 ND ND ND ND 19-Nov-09 0.32 5.0 ND ND ND 0.51 J 1.0 J 1.5 J ND ND ND NC2L = 6 pg/L (01/01/10) 15-Jun-10 0.32 5.0 1.3 J 1.2 J 0.93 J 5.6 3.7 J ND ND ND ND 29-Nov-10 0.32 5.0 ND ND 1.4 J 6.2 8.0 ND ND ND ND 31-May-11 0.32 5.0 0.42 J 1.3 J 2.1 J 6.3 7.8 ND ND ND ND 19-Dec-11 0.32 5.0 0.58 J 1.2 J 1.8 J 5.9 6.7 ND ND ND ND 30-May-12 0.32 5.0 ND 1.0 J 1.2 J 5.4 4.1 J ND ND ND ND 3-Dec-12 0.32 5.0 ND 1.1 J 1.4 J 4.7 J 2.1 J ND ND ND ND 11-Jun-13 0.32 5.0 0.37 J 1.1 J 1.1 J NS 2.2 J ND ND ND ND 29-Oct-13 0.32 5.0 ND 1.1 J 0.67 J 5.1 3 J ND ND ND ND 6-May-14 EPA 8260 0.32 5.0 0.34 J 0.98 J 0.81 J 5.2 2.4 J ND ND ND ND 21-Oct-14 EPA 8260 0.32 5.0 ND 0.90 J 0.83 J 4.2 J 4.6 J ND ND ND ND 19-May-15 EPA 8260 0.32 5.0 ND 0.79 J 0.64 J 4.4 J 2.5 J ND ND ND ND 7-Dec-15 EPA 8260 0.32 5.0 ND 0.59 J 0.75 J 4.9 J 1.9 J ND ND ND ND 2-May-16 EPA 8260 0.32 5.0 ND 0.43 J 0.65 J 4.3 J 0.72 J ND ND ND ND 12-Dec-16 EPA 8260 0.32 5.0 ND 0.71 J 0.87 J 4.9 J 3.1 J ND ND ND ND 26-Jun-17 EPA 8260 0.32 5.0 NS 0.71 J 0.83 J 4.5 J 2.1 J ND ND ND ND 14-Dec-17 EPA 8260 0.32 5.0 NS 0.59 J 0.68 J 4.6 J 2.2 J ND ND ND ND 14-May-18 EPA 8260 0.32 5.0 NS ND 0.5 J 4.3 J 1.3 J ND ND ND ND 4-Dec-18 EPA 8260B 0.32 1.0 NS 0.37 J 0.46 J 4.0 1.1 ND ND ND ND 6-May-19 EPA 8260D 0.41 1.0 NS 0.68 J ND 6.1 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.27 1.0 NS 0.57 J 0.43 J 4.7 1.5 ND ND ND --- 6-May-20 EPA 8260D 0.27 1.0 NS 0.61 J ND 4.8 0.48 J ND ND ND --- 9-Nov-20 EPA 8260D 0.27 1.0 NS ND ND 5.5 ND ND ND ND ND 4-May-21 EPA 8260D 1.80 5.0 NS ND ND 5.8 ND ND ND ND ND 2-Nov-21 EPA 8260D 0.37 1.0 NS 0.49 J ND 5.5 0.65 J ND ND ND ND 17-May-22 EPA 8260D 0.37 1.0 ND 0.38 J ND 4.4 0.39 J ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 25 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,2-Dichloroethane 19-Nov-09 0.12 1.0 ND ND ND ND 0.15 J ND ND ND ND NC2L = 0.4 pg/L (01/01/10) 15-Jun-10 0.12 1.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.12 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.12 1.0 ND 0.14 J ND ND ND ND ND ND ND 19-Dec-11 0.12 1.0 ND 0.13 J ND ND ND ND ND ND ND 30-May-12 0.12 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.12 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.12 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.12 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.24 1.0 ND 0.25 J ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.24 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.24 1.0 ND 0.27 J ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.24 1.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.24 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.24 1.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.24 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.67 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.34 1.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 0.34 1.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.34 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 1.60 5.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.32 1.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 8260D 0.32 1.0 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 26 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,1-Dichloroethene 28-Apr-94 NR 5 ND ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND ND ND ND ND ND ND ND ND NC2L = 7 pg/L (10/23/07) 28-Nov-07 NR 5 ND ND ND ND ND ND ND ND ND 28-May-08 0.56 1.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.56 5.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.56 5.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 0.56 5.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.56 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.56 5.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.56 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.56 5.0 ND ND ND ND ND ND ND ND ND NC 2L = 350 pg/L (04/01/2013) 11-Jun-13 0.56 5.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.56 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.56 5.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.56 5.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.56 5.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.56 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.72 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 1.70 5.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.35 1.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 8260D 0.35 1.0 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 27 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,4-Dioxane (p-Dioxane) 4-Dec-18 EPA 8260B Mod. 9.5 10 ND 219 56.3 127 ND ND ND 4.0 ND NC 2L = 3 pg/L 6-May-19 EPA 8260D Mod. 5.8 10 NS 218 57.0 128 2.4 ND ND ND ND 5-Nov-19 EPA 8260D Mod. 1.2 2 3.0 236 36.4 269 2.7 ND ND ND --- 6-May-20 EPA 8260D Mod. 5.8 10 NS 213 33.3 111 ND ND ND ND --- 9-Nov-20 EPA 8260D Mod. 1.2 2 NS 260 49.6 114 ND ND ND ND ND 4-May-21 EPA 8260D Mod. 0.9 2 NS 187 41.5 110 ND ND ND ND ND 2-Nov-21 EPA 8260D Mod. 0.9 2 NS 279 34.1 95.7 ND ND ND ND ND 17-May-22 EPA 8260D Mod. 0.9 2 ND 275 23.2 95.9 ND ND ND ND ND cis-1,2-Dichloroethene 28-Apr-94 NR 5 40 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND 23.0 61.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND 31.0 69.0 ND ND ND ND 29-May-01 NR 5 NA ND ND 34.0 61.0 ND ND ND ND 6-Nov-01 NR 5 NA ND ND 34.0 56.0 ND ND ND ND 21-May-02 NR 5 NA ND ND 29.0 69.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND 25.0 75.0 ND ND ND ND 14-May-03 NR 5 46.0 ND ND 14.0 36.0 ND ND ND ND 19-Nov-03 NR 5 26.0 ND ND 13.0 38.0 ND ND ND ND 5-May-04 NR 5 10.0 ND ND 10.0 46.0 ND ND ND ND 9-Nov-04 NR 5 6.0 ND ND 9.1 47.0 ND ND ND ND 25-May-05 NR 5 6.0 ND ND 7.0 29.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND 11.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND 9.3 ND ND ND ND 1-Nov-06 NR 5 ND ND ND 6.8 2.1 ND ND ND ND 29-May-07 NR 5 8.3 ND ND 7.5 36.0 ND ND ND ND NC2L = 70 pg/L (10/23/07) 28-Nov-07 NR 5 ND ND ND 4.5 J 58.0 ND ND ND ND 28-May-08 0.19 5.0 Dry 0.31 J 0.29 J 5.1 56.3 ND ND ND ND 5-Nov-08 0.19 5.0 Dry ND 0.22 J 4.9 J 65.7 ND ND ND ND 2-J u n-09 0.19 5.0 17.3 0.33 J 0.44 J 5.3 47.6 N D N D N D N D 19-Nov-09 0.19 5.0 ND ND ND 9.1 0.31 B ND ND ND 0.26 J 15-Jun-10 0.19 5.0 9.9 0.45 J ND 6.2 20.9 ND ND ND ND 29-Nov-10 0.19 5.0 4.8 J 0.31 J ND 6.4 37.1 0.46 J ND ND ND 31-May-11 0.19 5.0 3.0 J 0.33 J ND 7.3 38.6 ND ND ND ND 19-Dec-11 0.19 5.0 3.1 J 0.41 J 0.25 J 6.8 30.3 ND ND ND ND 30-May-12 0.19 5.0 4 J ND ND 7.4 17.1 ND ND ND ND 3-Dec-12 0.19 5.0 0.96 J ND ND 7.0 9.2 ND ND ND ND 11-Jun-13 0.19 5.0 9.4 0.69 J 0.20 J NS 8.8 ND ND ND ND 29-Oct-13 0.19 5.0 4.0 J 0.32 J ND 8.1 12.2 ND ND ND ND 6-May-14 EPA 8260 0.19 5.0 2.2 J 0.40 J ND 7.9 9.3 ND ND ND ND 21-Oct-14 EPA 8260 0.19 5.0 1.1 J 0.30 J ND 7.3 21.4 ND ND ND ND 19-May-15 EPA 8260 0.19 5.0 1.1 J 0.34 J ND 7.7 11.3 ND ND ND ND 7-Dec-15 EPA 8260 0.19 5.0 2.1 J ND ND 8.9 8.9 ND ND ND ND 2-May-16 EPA 8260 0.19 5.0 1.7 J 0.38 J ND 7.8 3.6 J ND ND ND ND 12-Dec-16 EPA 8260 0.19 5.0 0.8 J 0.36 J ND 10.4 17.2 ND ND ND ND 26-Jun-17 EPA 8260 0.19 5.0 NS 0.31 J ND 10.0 10.7 ND ND ND ND 14-Dec-17 EPA 8260 0.19 5.0 NS 0.38 J 0.22 J 10.8 11.1 ND ND ND ND 14-May-18 EPA 8260 0.19 5.0 NS ND 0.22 J 10.7 6.9 ND ND ND ND 4-Dec-18 EPA 8260B 0.19 1.0 NS 0.30 J ND 10.8 5.8 ND ND ND ND 6-May-19 EPA 8260D 0.66 1.0 NS ND ND 18.7 1.2 ND ND ND ND 5-Nov-19 EPA 8260D 0.29 1.0 NS 0.33 J ND 14.6 J 8.0 ND ND ND --- 6-May-20 EPA 8260D 0.29 1.0 NS 0.41 J ND 16.4 2.6 ND ND ND --- 9-Nov-20 EPA 8260D 0.29 1.0 NS ND ND 21.2 3.5 ND ND ND ND 4-May-21 EPA 8260D 1.90 5.0 NS ND ND 21.3 2.1 ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 28 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 2-Nov-21 17-May-22 EPA 8260D EPA 8260D 0.38 0.38 1.0 1.0 NS ND ND ND ND ND 22.9 22.1 5.6 2.6 ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 29 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Trans-1,2-Dichloroethene 19-Oct-99 NR 5 ND ND ND ND ND ND NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND NA 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND ND ND ND 0.2 J ND ND ND ND NC2L = 100 pg/L (10/23/07) 28-Nov-07 NR 5 ND ND ND ND 0.43 J ND ND ND ND 28-May-08 0.49 5.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.49 5.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.49 5.0 ND ND 0.55 J ND ND ND ND ND ND 19-Nov-09 0.49 5.0 ND ND ND ND ND 0.54 J ND ND ND 15-Jun-10 0.49 5.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.49 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.49 5.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.49 5.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.49 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.49 5.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.49 5.0 ND ND 0.57 J NS ND ND ND ND ND 29-Oct-13 0.49 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.49 5.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.49 5.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.49 5.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.49 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.46 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.25 1.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 0.25 1.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.25 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 2.00 5.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.40 1.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 8260D 0.40 1.0 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 30 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,2-Dichloropropane 19-Oct-99 NR 5 ND ND ND ND ND ND NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND NA 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND 5.3 ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND 6.0 ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND 4.3 ND ND ND ND ND NC2L = 0.51 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 1.4 ND ND ND ND 28-May-08 0.27 1.0 Dry ND ND 2.5 1.2 ND ND ND ND 5-Nov-08 0.27 1.0 Dry ND ND 2.3 1.3 ND ND ND ND 2-Jun-09 0.27 1.0 ND ND ND 2.4 0.84 J ND ND ND ND 19-Nov-09 0.27 1.0 ND ND ND ND ND ND ND ND ND NC2L = 0.6 pg/L (01/01/10) 15-Jun-10 0.27 1.0 ND ND ND 2.3 0.30 J ND ND ND ND 29-Nov-10 0.27 1.0 ND ND ND 2.5 ND ND ND ND ND 31-May-11 0.27 1.0 ND ND ND 2.3 0.61 J ND ND ND ND 19-Dec-11 0.27 1.0 ND ND ND 2.1 0.66 J ND ND ND ND 30-May-12 0.27 1.0 ND ND ND 1.9 ND ND ND ND ND 3-Dec-12 0.27 1.0 ND ND ND 1.6 ND ND ND ND ND 11-Jun-13 0.27 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.27 1.0 ND ND ND 1.5 ND ND ND ND ND 6-May-14 EPA 8260 0.27 1.0 ND ND ND 1.5 ND ND ND ND ND 21-Oct-14 EPA 8260 0.27 1.0 ND ND ND 1.3 ND ND ND ND ND 19-May-15 EPA 8260 0.27 1.0 ND ND ND 1.2 ND ND ND ND ND 7-Dec-15 EPA 8260 0.27 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.27 1.0 ND ND ND 1.3 ND ND ND ND ND 12-Dec-16 EPA 8260 0.27 1.0 ND ND ND 1.1 0.37 J ND ND ND ND 26-Jun-17 EPA 8260 0.27 1.0 NS ND ND 0.92 J ND ND ND ND ND 14-Dec-17 EPA 8260 0.27 1.0 NS ND ND 0.92 J ND ND ND ND ND 14-May-18 EPA 8260 0.27 1.0 NS ND ND 0.87 J ND ND ND ND ND 4-Dec-18 EPA 826OB 0.27 1.0 NS ND ND 0.94 J ND ND ND ND ND 6-May-19 EPA 8260D 0.60 1.0 NS ND ND 1.1 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.19 1.0 NS ND ND 0.87 J ND ND ND ND --- 6-May-20 EPA 8260D 0.19 1.0 NS ND ND 0.84 J ND ND ND ND --- 9-Nov-20 EPA 8260D 0.19 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 0.36 1.0 NS ND ND 0.63 J ND ND ND ND ND 2-Nov-21 EPA 8260D 0.36 1.0 NS ND ND 0.72 J ND ND ND ND ND 17-May-22 EPA 8260D 0.36 1.0 ND ND ND 0.75 J ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 31 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Ethylbenzene 28-Apr-94 NR 50 ND 310 29.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 130 ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA 110 ND ND ND ND ND ND ND 29-May-01 NR 5 NA 120 ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA 89.0 ND ND ND ND ND ND ND 21-May-02 NR 5 NA 100 ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA 86.0 ND ND ND ND ND ND ND 14-May-03 NR 5 ND 160 11.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 66.0 ND ND ND ND ND ND ND 5-May-04 NR 5 ND 58.0 ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND 65.0 ND ND ND ND ND ND ND 25-May-05 NR 5 ND 80.0 ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND 75.0 ND ND ND ND ND ND ND 24-May-06 NR 5 ND 45.8 ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND 64.0 ND ND ND ND ND ND ND 29-May-07 NR 1 ND 59.1 ND ND ND ND ND ND ND NC2L = 550 pg/L (10/23/07) 28-Nov-07 NR 1 ND 39.0 ND ND 0.50 J ND ND ND ND 28-May-08 0.3 1.0 Dry 39.3 ND ND ND ND ND ND ND 5-Nov-08 0.30 1.0 Dry 30.8 ND ND ND ND ND ND ND 2-Jun-09 0.30 1.0 ND 28.7 1.2 ND ND ND ND ND ND 19-Nov-09 0.30 1.0 ND ND ND ND 27.2 0.42 J ND ND ND NC2L = 600 pg/L (01/01/10) 15-Jun-10 0.30 1.0 ND 39.0 0.32 J ND ND ND ND ND ND 29-Nov-10 0.30 1.0 ND 27.3 ND ND ND ND ND ND ND 31-May-11 0.30 1.0 ND 23.8 ND ND ND ND ND ND ND 19-Dec-11 0.30 1.0 ND 18.1 ND ND ND ND ND ND ND 30-May-12 0.30 1.0 ND 16.8 ND ND ND ND ND ND ND 3-Dec-12 0.30 1.0 ND 13.9 ND ND ND ND ND ND ND 11-Jun-13 0.30 1.0 ND 27.7 6.5 NS ND ND ND ND ND 29-Oct-13 0.30 1.0 ND 21.5 ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.30 1.0 ND 18.9 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.30 1.0 ND 16.5 ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.30 1.0 ND 14.2 ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.30 1.0 ND 16.2 0.41 J ND ND ND ND ND ND 2-May-16 EPA 8260 0.30 1.0 ND 22.2 ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.30 1.0 ND 13.9 ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.30 1.0 NS 12.7 ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.30 1.0 NS 10.5 ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.30 1.0 NS 10.5 3.9 ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.30 1.0 NS 10.7 ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.45 1.0 NS 24.1 ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.26 1.0 NS 12.1 ND ND ND ND ND ND --- 6-May-20 EPA 8260D 0.26 1.0 NS 17.0 ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.26 1.0 NS 10.9 ND ND ND ND ND ND ND 4-May-21 EPA 8260D 0.30 1.0 NS 20.3 ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.30 1.0 NS 10.7 ND ND ND ND ND ND ND 17-May-22 EPA 8260D 0.30 1.0 ND 8.4 0.42 J ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 32 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 2-Hexanone 19-Oct-99 NR 50 ND 80.0 ND ND ND ND NI NI ND 3-May-00 NR 50 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 50 NA ND ND ND ND ND ND ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND ND ND ND ND 5-May-04 NR 50 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 50 ND ND ND ND ND ND ND ND ND GWPS = 280 pg/L (10/23/07) 28-Nov-07 NR 50 ND ND ND ND ND ND ND ND ND 28-May-08 0.46 50.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.46 50.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.46 50.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.46 50.0 ND ND ND ND ND ND ND ND ND IMAC = 40 pg/L 15-Jun-10 0.46 50.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.46 50.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.46 50.0 ND 1.4 J ND ND ND ND ND ND ND 19-Dec-11 0.46 50.0 0.48 J ND ND ND ND 0.81 J ND ND ND 30-May-12 0.46 50.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.46 50.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.46 50.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.46 50.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.46 50.0 ND 1.6 J ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.46 50.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.46 50.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.46 50.0 NS 2.8 J ND ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.46 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.89 5.0 NS 8.0 ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.57 5.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 0.57 5.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.57 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 2.40 25.0 NS 6.4 J ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.48 5.0 --- ND ND ND ND ND ND ND ND 17-May-22 EPA 8260D 0.48 5.0 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 33 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks lodomethane 11-Jun-13 0.32 10.0 ND ND ND NS ND 7.4 J ND ND ND NC2L = NE pg/L (01/01/10) 29-Oct-13 0.32 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.32 10.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.32 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.32 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.32 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 3.10 10.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 12.50 20.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 12.50 20.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 12.50 20.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 48.60 100.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 9.70 20.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 8260D 9.70 20.0 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 34 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Methylene chloride 12-May-99 NR 5 ND ND ND ND 5.5 NI NI NI NA 19-Oct-99 NR 10 ND ND ND ND 12.0 B ND NI NI 21.0 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND 10.0 ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND 12.0 ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND NC2L = 4.6 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 2.7 ND ND ND ND 28-May-08 0.97 2.0 Dry ND ND ND ND ND ND ND 1.5 J 5-Nov-08 0.97 2.0 Dry ND ND ND 6.1 B ND ND ND 2.8 2-Jun-09 0.97 2.0 ND ND ND ND 18.8 ND ND ND ND 19-Nov-09 0.97 2.0 ND ND ND ND ND ND ND ND ND NC2L = 5 pg/L (01/01/10) 15-Jun-10 0.97 2.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.97 1.0 ND ND ND ND 2.9 B ND ND ND 1.2 31-May-11 0.97 1.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.97 1.0 ND ND ND ND 1.4 B ND ND ND 3.3 30-May-12 0.97 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.97 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.97 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.97 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND 2.6 21-Oct-14 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND 4.8 2-May-16 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.97 1.0 NS ND ND ND ND ND ND ND 1.3 J 14-Dec-17 EPA 8260 0.97 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.97 1.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.97 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.50 1.0 NS ND ND 0.63 J ND ND ND ND ND 5-Nov-19 EPA 8260D 3.70 5.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 3.70 5.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 3.70 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 9.80 25.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 2.00 5.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 8260D 2.00 5.0 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 35 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 2-Butanone (MEK) 28-Apr-94 NR 2000 ND 2500 ND NI NI NI NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND 1200 ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND 490 ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND 250 ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 26.0 J 81.0 J ND ND ND ND ND ND ND NC2L = 4,200 pg/L (10/23/07) 28-Nov-07 NR 100 18.0 J ND ND ND ND ND ND ND ND 28-May-08 0.96 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.96 100 Dry 17.5 J ND ND ND ND ND ND ND 2-Jun-09 0.96 100 ND 56.1 J ND ND ND ND ND ND ND 19-Nov-09 0.96 100 ND ND ND 24.2 J 17.8 J ND 1.5 J ND ND NC2L = 4,000 pg/L (01/01/10) 15-Jun-10 0.96 100 42.3 J 202 ND ND ND ND ND ND 1.4 J 29-Nov-10 0.96 100 60.6 J 1.9 J ND ND ND ND ND ND ND 31-May-11 0.96 100 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.96 100 1.9 J ND ND ND ND ND ND ND ND 30-May-12 0.96 100 8.1 J ND ND ND ND ND ND ND ND 3-Dec-12 0.96 100 2.2 J 29.5 J ND ND ND ND ND ND ND 11-Jun-13 0.96 100 14.0 J 1650 J 4.0 J NS ND ND ND ND ND 29-Oct-13 0.96 100 158 ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.96 100 13.3 J 128 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.96 100 9.1 J ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.96 100 6.4 J ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.96 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.96 100 ND 60.7 J ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.96 100 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.96 100 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.96 100 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.96 100 NS 268 ND ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.96 5 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 3.20 5 NS 448 ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 3.30 5 NS 14.8 ND ND ND ND ND ND --- 6-May-20 EPA 8260D 3.30 5 NS 222 ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 3.30 5 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 19.80 25 NS 1190 M1 ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 4.00 5 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 8260D 4.00 5 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 36 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 4-Methyl-2-pentanone (MIBK) 28-Apr-94 NR 500 ND 910 ND NI NI NI NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND 1200 ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND ND ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND 160 ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 ND ND ND ND ND ND ND ND ND GWPS = 560 pg/L (10/23/07) 28-Nov-07 NR 100 ND ND ND ND ND ND ND ND ND 28-May-08 0.33 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.33 100 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.33 100 ND 113 ND ND ND ND ND ND ND 19-Nov-09 0.33 100 ND ND ND ND 2.3 J ND ND ND ND IMAC = 100 pg/L 15-Jun-10 0.33 100 ND 56.0 J 0.88 J ND ND ND ND ND ND 29-Nov-10 0.33 100 ND ND ND ND ND ND ND ND ND 31-May-11 0.33 100 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.33 100 ND ND ND ND ND ND ND ND ND 30-May-12 0.33 100 ND 13.9 J ND ND ND ND ND ND ND 3-Dec-12 0.33 100 ND 1.9 J ND ND ND ND ND ND ND 11-Jun-13 0.33 100 ND 760 J 4.0 J NS ND ND ND ND ND 29-Oct-13 0.33 100 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.33 100 ND 41.4 J 0.44 J ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.33 100 ND 3.3 J ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.33 100 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.33 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.33 100 ND 61.6 J ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.33 100 ND 3.2 J ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.33 100 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.33 100 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.33 100 NS 169 J ND ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.33 5 NS 2.7 J ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.86 5 NS 311 ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 4.50 5 NS 11.2 ND ND ND ND ND ND --- 6-May-20 EPA 8260D 4.50 5 NS 187 ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 4.50 5 NS 7.0 ND ND ND ND ND ND ND 4-May-21 EPA 8260D 2.70 5 NS 616 ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 2.70 5 NS 5.0 ND ND ND ND ND ND ND 17-May-22 EPA 8260D 2.70 5 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 37 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Tetrachloroethene 28-Apr-94 NR 5 20.0 ND ND NI NI NI NI NI ND (PCE) 6-Oct-94 NR 5 16.0 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND 24.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND 21.0 ND ND ND ND 29-May-01 NR 5 NA ND ND ND 15.0 ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND 13.0 ND ND ND ND 21-May-02 NR 5 NA ND ND ND 17.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND 12.0 ND ND ND ND 14-May-03 NR 5 ND ND ND ND 10.0 ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND 10.0 ND ND ND ND 5-May-04 NR 5 ND ND ND ND 12.0 ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND 14.0 ND ND ND ND 25-May-05 NR 5 ND ND ND ND 12.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND 5.0 28.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND 10.2 ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND 7.0 ND ND ND ND 29-May-07 NR 1 ND ND ND 1.9 11.0 ND ND ND ND NC2L = 0.7 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND 1.2 13.0 ND ND ND ND 28-May-08 0.46 1.0 Dry ND ND 1.6 10.3 ND ND ND ND 5-Nov-08 0.46 1.0 Dry ND ND 1.6 13.1 ND ND ND ND 2-Jun-09 0.46 1.0 1.7 ND ND 1.2 9.1 ND ND ND ND 19-Nov-09 0.46 1.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 0.46 1.0 ND ND ND 0.79 J 4.8 ND ND ND ND 29-Nov-10 0.46 1.0 ND ND ND ND 11.0 ND ND ND ND 31-May-11 0.46 1.0 ND ND ND 0.75 J 6.2 ND ND ND ND 19-Dec-11 0.46 1.0 ND ND ND 0.95 J 8.4 ND ND ND ND 30-May-12 0.46 1.0 ND ND ND 1.3 4.7 ND ND ND ND 3-Dec-12 0.46 1.0 ND ND ND 1.8 3.2 ND ND ND ND 11-Jun-13 0.46 1.0 ND ND ND NS 2.6 ND ND ND ND 29-Oct-13 0.46 1.0 ND ND ND 3.5 3.3 ND ND ND ND 6-May-14 EPA 8260 0.46 1.0 ND ND ND 3.8 3.0 ND ND ND ND 21-Oct-14 EPA 8260 0.46 1.0 ND ND ND 3.9 5.9 ND ND ND ND 19-May-15 EPA 8260 0.46 1.0 ND ND ND 4.6 3.7 ND ND ND ND 7-Dec-15 EPA 8260 0.46 1.0 ND ND ND 3.5 1.9 ND ND ND ND 2-May-16 EPA 8260 0.46 1.0 ND ND ND 4.5 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.46 1.0 ND ND ND 4.7 2.1 ND ND ND ND 26-Jun-17 EPA 8260 0.46 1.0 NS ND ND 5.7 1.7 ND ND ND ND 14-Dec-17 EPA 8260 0.46 1.0 NS ND ND 5.0 2.0 ND ND ND ND 14-May-18 EPA 8260 0.46 1.0 NS ND ND 5.6 1.3 ND ND ND ND 4-Dec-18 EPA 8260B 0.46 1.0 NS ND ND 6.6 1.2 ND ND ND ND 6-May-19 EPA 8260D 0.78 1.0 NS ND ND 11.1 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.16 1.0 NS ND ND 6.5 1.8 ND ND ND --- 6-May-20 EPA 8260D 0.16 1.0 NS ND ND 8.1 0.69 J ND ND ND --- 9-Nov-20 EPA 8260D 0.16 1.0 NS ND ND 8.5 ND ND ND ND ND 4-May-21 EPA 8260D 1.50 5.0 NS ND ND 8.7 ND ND ND ND ND 2-Nov-21 EPA 8260D 0.29 1.0 NS ND ND 7.7 0.49 J ND ND ND ND 17-May-22 EPA 8260D 0.29 1.0 ND ND ND 9.1 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 38 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Toluene 28-Apr-94 NR 5 ND 55.0 10.0 NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND 5.6 ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND 2.8 0.39 B 0.26 B ND ND ND ND 0.52 J NC2L = 1,000 pg/L (10/23/07) 28-Nov-07 NR 1 ND 1.7 ND ND ND ND ND ND ND 28-May-08 0.26 1.0 Dry 2.0 0.35 J ND ND ND ND ND ND 5-Nov-08 0.26 1.0 Dry 1.5 0.44 J ND ND ND ND ND ND 2-Jun-09 0.26 1.0 ND 2.3 0.51 J ND ND ND ND ND ND 19-Nov-09 0.26 1.0 ND ND ND ND 1.6 0.26 J ND ND ND NC2L = 600 pg/L (01/01/10) 15-Jun-10 0.26 1.0 ND 2.4 ND ND ND ND ND ND ND 29-Nov-10 0.26 1.0 ND 1.6 ND ND ND ND ND ND ND 31-May-11 0.26 1.0 ND 1.5 ND ND ND ND ND ND ND 19-Dec-11 0.26 1.0 ND 1.9 ND ND ND ND ND ND ND 30-May-12 0.26 1.0 ND 1.4 0.38 J ND ND ND ND ND ND 3-Dec-12 0.26 1.0 ND 1.0 J 0.27 J ND ND ND ND ND ND 11-Jun-13 0.26 1.0 ND 4.1 2.7 NS ND ND ND ND ND 29-Oct-13 0.26 1.0 ND 1.3 ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.26 1.0 ND 1.6 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.26 1.0 ND 1.3 ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.26 1.0 ND 1.2 ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.26 1.0 ND 1.6 0.52 J ND ND ND ND ND --- 2-May-16 EPA 8260 0.26 1.0 ND 2.4 ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.26 1.0 ND 1.2 ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.26 1.0 NS 1.2 0.27 J ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.26 1.0 NS 1.1 ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.26 1.0 NS 1.7 J 0.48 J ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.26 1.0 NS 0.91 J ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.31 1.0 NS 4.8 ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.24 1.0 NS 1.1 ND ND ND ND ND ND --- 6-May-20 EPA 8260D 0.24 1.0 NS 2.5 ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.24 1.0 NS 0.90 J ND ND ND ND ND ND ND 4-May-21 EPA 8260D 0.48 1.0 NS 6.80 ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.48 1.0 NS 1.00 ND ND ND ND ND ND ND 17-May-22 EPA 8260D 0.48 1.0 ND 1.00 ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 39 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Trichloroethene 28-Apr-94 NR 5 11.0 ND ND NI NI NI NI NI ND (TCE) 6-Oct-94 NR 5 9.3 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND 12.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND 12.0 ND ND ND ND 29-May-01 NR 5 NA ND ND ND 8.6 ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND 11.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND 10.0 ND ND ND ND 14-May-03 NR 5 ND ND ND ND 7.5 ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND 7.1 ND ND ND ND 5-May-04 NR 5 ND ND ND ND 8.0 ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND 10.0 ND ND ND ND 25-May-05 NR 5 ND ND ND ND 6.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND 6.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 2.4 ND ND 2.6 8.3 ND ND ND ND NC2L = 2.8 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 12.0 ND ND ND ND 28-May-08 0.47 1 Dry ND ND 1.0 10.0 ND ND ND ND 5-Nov-08 0.47 1.0 Dry ND ND 1.1 9.7 ND ND ND ND 2-Jun-09 0.47 1.0 2.4 ND ND 1.4 7.9 ND ND ND ND 19-Nov-09 0.47 1.0 ND ND ND ND ND ND ND ND ND NC2L = 3 pg/L (01/01/10) 15-Jun-10 0.47 1.0 0.56 J ND ND 2.2 2.9 ND ND ND ND 29-Nov-10 0.47 1.0 ND ND ND 2.5 5.7 ND ND ND ND 31-May-11 0.47 1.0 ND ND ND 2.3 3.9 ND ND ND ND 19-Dec-11 0.47 1.0 1.4 ND ND 3.0 5.2 ND ND ND ND 30-May-12 0.47 1.0 0.49 J ND ND 2.8 2.4 ND ND ND ND 3-Dec-12 0.47 1.0 ND ND ND 2.5 1.4 ND ND ND ND 11-Jun-13 0.47 1.0 ND ND ND NS 1.1 ND ND ND ND 29-Oct-13 0.47 1.0 ND ND ND 2.6 1.4 ND ND ND ND 6-May-14 EPA 8260 0.47 1.0 ND ND ND 2.8 ND ND ND ND ND 21-Oct-14 EPA 8260 0.47 1.0 ND ND ND 2.6 2.6 ND ND ND ND 19-May-15 EPA 8260 0.47 1.0 ND ND ND 3.0 1.4 ND ND ND ND 7-Dec-15 EPA 8260 0.47 1.0 ND ND ND 2.5 0.62 J ND ND ND ND 2-May-16 EPA 8260 0.47 1.0 ND ND ND 3.3 ND ND ND ND ND 12-Dec-16 EPA 8260 0.47 1.0 ND ND ND 3.5 1.3 ND ND ND ND 26-Jun-17 EPA 8260 0.47 1.0 NS ND ND 3.3 0.76 J ND ND ND ND 14-Dec-17 EPA 8260 0.47 1.0 NS ND ND 3.7 0.86 J ND ND ND ND 14-May-18 EPA 8260 0.47 1.0 NS ND ND 3.6 0.52 J ND ND ND ND 4-Dec-18 EPA 8260B 0.47 1.0 NS ND ND 4.7 0.66 J ND ND ND ND 6-May-19 EPA 8260D 0.34 1.0 NS ND ND 5.9 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.22 1.0 NS ND ND 4.8 0.72 J ND ND ND --- 6-May-20 EPA 8260D 0.22 1.0 NS ND ND 5.0 ND ND ND ND --- 9-Nov-20 EPA 8260D 0.22 1.0 NS ND ND 5.4 ND ND ND ND ND 4-May-21 EPA 8260D 1.90 5.0 NS ND ND 6.2 ND ND ND ND ND 2-Nov-21 EPA 8260D 0.38 1.0 NS ND ND 5.7 ND ND ND ND ND 17-May-22 EPA 8260D 0.38 1.0 ND ND ND 6.4 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 40 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Vinyl Chloride 28-Apr-94 NR 10 ND ND ND NI NI NI NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 2.6 ND ND 2.7 0.52 J ND ND ND ND NC2L = 0.015 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND 1.8 1.9 ND ND ND ND 28-May-08 0.62 1.0 Dry ND ND 2.4 1.5 ND ND ND ND 5-Nov-08 0.62 1.0 Dry ND ND 2.1 1.9 ND ND ND ND 2-Jun-09 0.62 1.0 1.9 ND ND 2.4 0.80 J ND ND ND ND 19-Nov-09 0.62 1.0 ND ND ND 1.3 ND ND ND ND ND NC2L = 0.03 pg/L (01/01/10) 15-Jun-10 0.62 1.0 1.4 ND ND 2.3 ND ND ND ND ND 29-Nov-10 0.62 1.0 0.73 J ND ND 2.5 0.73 J ND ND ND ND 31-May-11 0.62 1.0 0.66 J ND ND 2.2 ND ND ND ND ND 19-Dec-11 0.62 1.0 2.8 ND ND 1.9 ND ND ND ND ND 30-May-12 0.62 1.0 1.2 ND ND 1.6 ND ND ND ND ND 3-Dec-12 0.62 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.62 1.0 1.7 ND ND NS ND ND ND ND ND 29-Oct-13 0.62 1.0 0.64 J ND ND 0.99 J ND ND ND ND ND 6-May-14 EPA 8260 0.62 1.0 ND ND ND 1.1 ND ND ND ND ND 21-Oct-14 EPA 8260 0.62 1.0 ND ND ND 0.91 J ND ND ND ND ND 19-May-15 EPA 8260 0.62 1.0 ND ND ND 0.89 J ND ND ND ND ND 7-Dec-15 EPA 8260 0.62 1.0 ND ND ND 1.1 ND ND ND ND ND 2-May-16 EPA 8260 0.62 1.0 ND ND ND 0.62 J ND ND ND ND ND 12-Dec-16 EPA 8260 0.62 1.0 ND ND ND 0.88 J ND ND ND ND ND 26-Jun-17 EPA 8260 0.62 1.0 NS ND ND 1.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.62 1.0 NS ND ND 1.1 ND ND ND ND ND 14-May-18 EPA 8260 0.62 1.0 NS ND ND 1.0 ND ND ND ND ND 4-Dec-18 EPA 8260B 0.62 1.0 NS ND ND 1.2 ND ND ND ND ND 6-May-19 EPA 8260D 0.60 1.0 NS ND ND 1.4 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 0.24 1.0 NS ND ND 0.88 J ND ND ND ND --- 9-Nov-20 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 1.90 5.0 NS ND ND 1.1 ND ND ND ND ND 2-Nov-21 EPA 8260D 0.39 1.0 NS ND ND 1.1 ND ND ND ND ND 17-May-22 EPA 8260D 0.39 1.0 ND ND ND 1.1 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 41 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Xylene (Total) 28-Apr-94 NR 5 6.2 330 80.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 120 34.0 ND ND ND ND ND ND 8-Nov-00 NR 5 120 7.2 ND ND ND ND ND ND NA 29-May-01 NR 5 NA 177 20 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 125 7.6 ND ND ND ND ND ND 21-May-02 NR 5 NA 149 18.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 126 21.0 ND ND ND ND ND ND 14-May-03 NR 5 7.0 222 65.9 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 107 29.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 90.0 41.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 106 41.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 152 46.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 209 39.0 ND ND ND ND ND ND 24-May-06 NR 10 ND 82.8 22.5 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 118 14.0 ND ND ND ND ND ND 29-May-07 NR 4 1.1 J 120 37.0 ND ND ND ND ND ND NC2L = 530 pg/L (10/23/07) 28-Nov-07 NR 5 ND 71.0 5.7 ND 2.0 J ND ND ND ND 28-May-08 0.89 5 Dry 76.1 14.4 ND 1.3 J ND ND ND ND 5-Nov-08 0.66 5 Dry 58.5 4.1 ND 2.5 ND ND ND ND 2-Jun-09 0.66 5 ND 56.5 24.6 ND 0.76 J ND ND ND ND 19-Nov-09 0.66 2.0 ND ND ND ND 50.6 29.4 ND ND ND NC2L = 500 pg/L (01/01/10) 15-Jun-10 0.66 2.0 ND 78.1 24.7 ND ND ND ND ND ND 29-Nov-10 0.66 2.0 ND 46.3 12.9 ND 0.72 J ND ND ND ND 31-May-11 0.66 2.0 ND 45.0 15.9 ND ND ND ND ND ND 19-Dec-11 0.66 2.0 ND 39.3 14.0 ND 0.74 J ND ND ND ND 30-May-12 0.66 2.0 ND 30.2 24.5 ND ND ND ND ND ND 3-Dec-12 0.66 2.0 ND 23.7 12.6 ND ND ND ND ND ND 11-Jun-13 0.66 5.0 ND 67.7 59.4 NS ND ND ND ND ND 29-Oct-13 0.66 5.0 ND 33.8 23.1 ND ND ND ND ND ND 6-May-14 EPA 8260 0.66 5.0 ND 42.7 32.6 ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.66 5.0 ND 37.1 15.4 ND ND ND ND ND ND 19-May-15 EPA 8260 0.66 5.0 ND 32.5 25.4 ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.66 5.0 ND 38.6 23.1 ND ND ND ND ND ND 2-May-16 EPA 8260 0.66 5.0 ND 43.2 21.1 ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.66 5.0 ND 31.3 8.10 ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.66 5.0 NS 28.0 15.20 ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.66 5.0 NS 23.3 16.90 ND ND ND ND ND ND 14-May-18 EPA 8260 0.66 5.0 NS 21.8 51.60 ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.66 1.0 NS 21.4 28.00 ND ND ND ND ND ND 6-May-19 EPA 8260D 1.50 2.0 NS 55.8 17.7 ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.63 1.0 NS 22.3 14.3 ND ND ND ND ND --- 6-May-20 EPA 8260D 0.63 1.0 NS 34.0 15.1 ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.63 1.0 NS 20.8 15.0 ND ND ND ND ND ND 4-May-21 EPA 8260D 0.34 1.0 NS 51.5 9.5 ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.34 1.0 NS 18.2 13.3 ND ND ND ND ND ND 17-May-22 EPA 8260D 0.34 1.0 ND 16.0 43.1 ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 42 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,1,2-Trichloroethane 11-Jun-13 0.29 1.0 ND 0.79 J ND NS ND ND ND ND ND IMAC = 1 pg/L 29-Oct-13 0.29 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.29 1.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.29 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.58 2.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.29 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.59 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 1.60 5.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.32 1.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 8260D 0.32 1.0 ND ND ND ND ND ND ND ND ND Notes: RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present). DL = Laboratory Detection Limit. ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006). J = Estimated concentration less than the RL but above the DL. B = Blank -Qualified Concentration (suspected to reflect laboratory or field contamination). NC2L = North Carolina Groundwater Standards from 15A NCAC 2L.0202. GWPS = Groundwater Protection Standards established by the SWS for constituents with no listed NC2L standard (no longer used). IMAC = Interim Maximum Allowable Concentration. Bold values are greater than the NC2L, GWPS, or IMAC. NA = No data available. NR = Not reported. NI = Not installed. NE = Not established. NS = Not sampled. Dry = Insufficient water column to sample. Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 43 of 43 Labella Associates TABLE A2-3: Historical Groundwater Field Parameters Parameter Collection Date Upgradient Downgradient MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Well Depth [ft] 50.55 45.70 26.69 78.40 29.50 49.80 25.00 60.00 Conductivity (at 25 °C) 11-Jun-13 233.1 1168.0 847 -- 56.9 14.2 62.8 74.1 [MS/CM] 28-Oct-13 326.9 1721.0 107.8 702 52.3 17.9 46.2 87.1 5-May-14 214.0 1161.0 828 687 70.6 28.8 65.3 102.3 20-Oct-14 376.0 1891.0 841 793 161.1 24.7 70.2 120.1 18-May-15 232.0 2160.0 878 823 99 19 66 106 7-Dec-15 273.0 2102.0 902 833 108 24 84 112 2-May-16 246.7 1873.0 936 746 69.8 18.4 64.9 86 12-Dec-16 176.7 2059.0 767 793 111 24.6 66.6 115.9 26-Jun-17 - 1937.0 791 791 100.4 24.1 72 107 14-Dec-17 - 2185.0 920 875 99 25 97 114 14-May-18 - 1658.0 1117 923 131 22.2 118 59 4-Dec-18 1604.0 776 661 70 48 64.3 92.8 Resample--> 8-Feb-19 - -- -- 55.9 - -- -- 6-May-19 1923 916 792 59.6 23.3 50.6 85.6 Resample-> 23-Jul-19 - -- 1454 -- - -- -- 4-Nov-19 2225 831 853 92.1 18.3 59.3 90 6-May-20 2226 913 842 59 19.2 80.4 101.5 Resample-> 16-Jul-20 - -- -- -- 16.6 -- -- 9-Nov-20 2044 803 752 72.8 15.8 53.5 88.5 Resample-> 27-Jan-21 - 757 -- -- - -- -- 4-May-21 1506.0 593 632.0 67.0 43.9 45.2 74.2 2-Nov-21 - 3069 931 1002 112.6 25.6 75.9 122.7 17-May-22 4420.0 2781 881 890 99.3 19.7 77.3 109.9 pH 11-Jun-13 5.9 6.1 6.36 -- 5.36 5.54 5.3 6.27 [standard units] 28-Oct-13 5.7 6.1 6.42 6.22 5.47 6.64 5.8 6.3 5-May-14 6.4 6.6 7.18 7.2 6.43 6.52 6.84 6.88 20-Oct-14 6.0 6.1 6.38 6.61 6.3 5.59 5.56 6.39 18-May-15 5.8 5.9 6.24 5.99 5.34 4.92 5.65 6.18 7-Dec-15 6.2 6.0 6.3 6.03 5.42 5.66 5.68 6.29 2-May-16 5.5 5.9 5.84 6.09 5.37 5.81 5.61 5.9 12-Dec-16 6.2 6.2 6.5 6.38 5.62 6.28 5.51 5.99 26-Jun-17 - 5.9 6.19 6.21 5.3 6.92 5.35 5.31 14-Dec-17 - 6.2 6.44 6.47 5.84 5.47 5.9 6.63 14-May-18 - 6.2 6.65 6.4 6.11 5.72 6.1 6.76 4-Dec-18 - 6.0 6.55 6.55 6.54 8.07 7.21 6.15 Resample-> 8-Feb-19 -- -- -- 5.64 - -- -- 6-May-19 - 6.01 6.49 6.17 6.66 5.86 6.56 6.08 Resample--> 23-Jul-19 - - -- 6.00 -- - -- -- 4-Nov-19 - 5.64 5.94 6.15 5.43 5.49 5.28 5.54 6-May-20 - 6 6.35 6.59 5.66 5.47 5.8 6.44 Resample--> 16-Jul-20 - - -- -- -- 5.55 -- -- 9-Nov-20 - 6.11 6.37 6.19 5.44 5.50 5.88 6.16 Resample--> 27-Jan-21 - - 6.65 -- -- - -- -- 4-May-21 - 5.8 5.96 6.0 6.5 7.2 6.3 5.76 2-Nov-21 - 5.14 6.12 5.05 5.77 5.89 5.85 5.96 17-May-22 5.9 5.95 6.12 6.29 6.64 6.69 6.34 6.21 Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 1 of 3 TABLE A2-3: Historical Groundwater Field Parameters Parameter Collection Date Upgradient Downgradient MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Temperature 11-Jun-13 17.0 17.4 15.2 -- 15.9 16.4 14 15.4 1° C] 28-Oct-13 15.9 16.0 16.6 15.8 15.3 15.1 15.7 15.7 5-May-14 16.4 17.9 15.4 16.7 16.7 16.2 14.6 15.6 20-Oct-14 14.5 15.0 16.3 15.2 12.7 15.0 14.5 13.2 18-May-15 22.5 17.1 15.7 16.1 17.3 21.0 16.1 17.1 7-Dec-15 14.7 16.1 15.9 15.7 14.9 14.6 15.7 14.9 2-May-16 17.7 16.8 15.7 17.0 16.8 17.0 14 15.6 12-Dec-16 15.0 15.9 16.6 15.6 15.2 15.5 15.6 14.8 26-Jun-17 -- 17.4 17.1 16.5 16 17.2 14.6 15 14-Dec-17 16.4 15.7 13.4 14.8 14.7 14.3 10.9 14-May-18 19.3 14.4 15.4 18.1 18.5 18.8 19.3 4-Dec-18 15.3 14.6 13.9 14 14 13.3 14.5 Resample--> 8-Feb-19 -- -- -- 15.2 -- -- -- 6-May-19 17.3 15.4 17.0 16.1 17.4 15.1 15.5 Resample--> 23-Jul-19 -- -- 17.3 -- -- -- -- 4-Nov-19 - 15.1 13 16.4 14.7 15.3 16.4 16.4 6-May-20 16 16 16.7 14.6 16 13.3 14.2 Resample--> 16-Jul-20 -- -- -- -- 20.9 -- -- 9-Nov-20 17.0 17.4 16.6 15.9 16.2 17.5 15.1 Resample-> 27 Jan-21 - - 15.1 - - - - - 4-May-21 16.9 14.9 16.4 15.6 16.1 13.8 15.6 2-Nov-21 -- 16.8 15.7 16.4 14.2 14.9 16.1 15.0 17-May-22 16.5 17.1 16.7 16.9 16.9 17.6 14.6 15.4 Dissolved Oxygen 6-May-19 -- 0.92 3.59 1.09 5.18 5.73 5.44 2.13 [mg/L] 23-Jul-19 -- -- 0.91 -- -- -- -- 4-Nov-19 1.63 1.85 4.39 3.99 4.36 3.55 2.89 6-May-20 5.06 4.71 5.14 6.7 1.85 5.74 4.33 Resample--> 16-Jul-20 -- -- -- -- 7.37 -- -- 9-Nov-20 1.65 1.29 1.21 3.66 9.03 6.00 1.19 Resample--> 27-Jan-21 -- 1.68 -- -- -- -- -- 4-May-21 1.4 1.97 1.2 7.1 10.3 9.07 0.98 2-Nov-21 -- 1.06 1.87 6.52 1.73 7.57 4.31 0.90 17-May-22 5.2 2.33 1.89 5.09 7.10 9.63 7.92 1.71 Oxidation Reduction Potential 6-May-19 -- 14.1 -4.6 222.3 165.4 235.3 183.1 126.9 [mv] 23-Jul-19 -- -- 210.5 -- - -- -- 4-Nov-19 33.3 85.4 180.3 199 146.4 208.3 -81.6 6-May-20 218.2 272.5 323 192.5 300.9 192 201.5 Resample--> 16-Jul-20 -- -- -- -- 282.3 -- -- 9-Nov-20 0.6 -24.7 1.4 199.9 202.3 230.1 63.1 Resample--> 27-Jan-21 -- -22.8 -- -- -- -- -- 4-May-21 40.4 60.8 194.8 98.3 164.7 127.5 109.6 2-Nov-21 -- -30.4 64.7 116.0 56.9 110.9 83.2 -43.1 17-May-22 163.4 76.1 51.1 62.2 116.4 121.5 138.0 115.3 Burke County, Kirksey Drive Landfill La Bella Associates Permit No. 12-01 2 of 3 TABLE A2-3: Historical Groundwater Field Parameters Parameter Collection Date Upgradient Downgradient MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Turbidity 11-Jun-13 27.4 4.50 3.65 -- 4.14 12.72 7.62 3.84 [NTU] 28-Oct-13 7.86 10.05 8.42 4.31 12.91 6.81 6.08 5.91 5-May-14 13.90 9.25 18.12 7.68 24.30 6.99 6.98 10.55 20-Oct-14 10.50 6.13 11.75 6.03 4.89 7.67 25.10 4.82 18-May-15 15.30 4.09 6.14 4.65 21.10 15.30 14.60 5.57 7-Dec-15 21.90 3.93 7.11 5.15 17.70 13.33 26.10 6.71 2-May-16 12.55 4.44 4.05 7.05 19.85 22.06 24.80 25.75 12-Dec-16 13.12 9.29 7.33 6.75 4.45 8.11 3.39 1.38 26-Jun-17 - 7.55 7.15 6.15 9.15 12.13 6.58 6.87 14-Dec-17 - 10.05 4.75 2.26 12.01 20.15 12.75 5.21 14-May-18 - 2.79 0.24 0.00 20.90 36.92 3.30 0.00 4-Dec-18 - 8.39 29.40 4.31 31.00 10.30 6.71 4.17 Resample--> 8-Feb-19 - - -- -- 7.96 - -- -- 6-May-19 - 5.29 11.5 0.65 5.71 17.8 22.1 5.08 Resample--> 23-Jul-19 - - -- 3.12 -- - -- -- 4-Nov-19 - 4.79 9 3.01 35.17 41.15 8.49 30.39 6-May-20 - 8.25 8.12 12.17 97.58 356.5 79.08 3.74 Resample-> 16-Jul-20 - - -- -- -- 13.23 -- -- 9-Nov-20 - 6.18 14.0 6.26 8.57 11.4 4.82 8.84 Resample--> 27-Jan-21 - - 8.5 -- -- - -- -- 4-May-21 - 8.7 8 4.0 30.1 91.6 20.4 5.25 2-Nov-21 - 6.93 33.7 1.55 65.5 150 18.6 2.23 17-May-22 26.1 576.00 14.7 2.54 10.3 26 7.8 2.65 Notes: °C= degrees Centigrade mg/L = milligrams per liter S.U.= Standard Units my = millivolts pS = microSemens per cm NTU = Nephelometric Turbidity Units ft = feet Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 3 of 3 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks INORGANICS Arsenic 25-Oct-95 NR 5 ND ND 10.0 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 5 ND ND ND NA 12-May-97 NR 5 ND ND ND NA 19-Nov-97 NR 5 ND ND ND NA 27-May-98 NR 5 ND ND ND NA 24-Nov-98 NR 5 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND ND ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND 3.1 J Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 2.6 10.0 ND ND Dry ND 5-Nov-08 2.7 10.0 ND ND Dry 4.8 J 2-Jun-09 2.7 10.0 ND ND ND ND 19-Nov-09 2.7 10.0 ND ND ND ND NC2B = 10 pg/L (05/01/2007) 14-Jun-10 2.7 10.0 ND ND Dry ND 29-Nov-10 2.7 10.0 ND ND Dry ND 31-May-11 2.7 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 5.0 10.0 ND ND ND ND 14-Dec-17 5.0 10.0 ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 ND ND ND ND 4-Dec-18 EPA 6010D 5.0 10.0 ND ND ND ND 6-May-19 EPA 6010D 5.0 10.0 ND ND 5.2 J ND 5-Nov-19 EPA 6010D 5.0 10.0 ND ND ND --- 6-May-20 EPA 6010D 4.7 10.0 ND ND ND --- 9-Nov-20 EPA 6010D 4.7 10.0 ND ND ND ND 4-May-21 EPA 6010D 4.7 10.0 ND ND ND ND 2-Nov-21 EPA 6010D 4.7 10.0 ND ND ND ND 17-May-22 EPA 6020B 2.2 5.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 1 of 20 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Barium 28-Apr-94 NR 100 ND ND 550 NA 6-Oct-94 NR 100 ND ND 356 NA 28-Jun-95 NR 100 ND ND 32.0 NA 25-Oct-95 NR 100 ND ND 301 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 100 ND ND 540 NA 12-May-97 NR 100 ND ND 480 NA 19-Nov-97 NR 100 ND ND 400 NA 27-May-98 NR 100 ND 2,000 500 NA 24-Nov-98 NR 100 ND ND 430 NA 12-May-99 NR 10.0 32.0 30.0 370 ND 19-Oct-99 NR 500 ND ND NA ND 3-May-00 NR 500 ND ND ND ND 8-Nov-00 NR 500 ND ND ND ND 29-May-01 NR 500 ND ND ND ND 6-Nov-01 NR 500 ND ND ND ND 21-May-02 NR 500 ND ND ND ND 13-Nov-02 NR 500 ND ND ND ND 14-May-03 NR 500 ND ND ND ND 19-Nov-03 NR 500 ND ND ND ND 5-May-04 NR 500 ND ND ND ND 9-Nov-04 NR 500 ND ND ND ND 25-May-05 NR 500 ND ND Dry ND 2-Nov-05 NR 500 ND ND Dry ND 24-May-06 NR 500 ND ND Dry ND 1-Nov-06 NR 500 ND ND ND ND 29-May-07 NR 100 33.6 J 35.2 J Dry ND 28-Nov-07 NR 100 31.9 J 32.3 J Dry 0.30 J 28-May-08 0.2 100 40.2 J 40.4 J Dry 0.33 J 5-Nov-08 0.20 100 33.8 B 35.0 B Dry 10.50 J 2-Jun-09 0.20 100 29.6 B 32.6 B 320 15.20 J 19-Nov-09 0.20 100 36.3 B 41.2 B 364 19.80 J NUB = 1,000 pg/L (05/01/2007) 14-Jun-10 0.20 100 31.0 B 32.5 B Dry 26.30 J 29-Nov-10 0.20 100 28.2 J 29.0 J Dry ND 31-May-11 0.20 100 30.1 J 29.9 J Dry ND 19-Dec-11 5.0 100 32.4 J 41.4 J 558 ND 30-May-12 5.0 100 33.1 J 33.7 J 34.2 J ND 3-Dec-12 5.0 100 31.0 J 28.9 J ND ND 11-Jun-13 5.0 100 43.8 B 45.7 B 261 13.70 J 29-Oct-13 5.0 100 31.4 J 33.1 J Dry ND 5-May-14 EPA 6010 5.0 100 31.0 J 33.1 J 301 ND 21-Oct-14 EPA 6010 5.0 100 33.6 J 34.3 J 343 ND 19-May-15 EPA 6010 2.5 100 33.6 J 34.1 J Dry NA 7-Dec-15 EPA 6010 2.5 100 36.5 J 37.8 J 350 ND 2-May-16 EPA 6010 2.5 100 32.5 J 32.9 J 766 ND 12-Dec-16 EPA 6010 2.5 100 22.8 J 82.1 J NS ND 26-Jun-17 EPA 6010 2.5 100 38.1 J 38.0 J 301 2.50 J 14-Dec-17 2.5 100 36.0 J 36.8 J 282 ND 14-May-18 EPA 6010 2.5 100 32.9 J 33.5 J 32.9 J ND 4-Dec-18 EPA 6O1OD 2.5 5 33.1 32.0 267 ND 6-May-19 EPA 6O1OD 2.5 5 26.4 26.2 239 ND 5-Nov-19 EPA 6O1OD 2.5 5 34.5 35.9 34.8 --- 6-May-20 EPA 6O1OD 3.5 5 31.9 28.7 32.3 --- 9-Nov-20 EPA 6O1OD 3.5 5 34.0 33.7 32.0 ND 4-May-21 EPA 6O1OD 3.5 5 34.1 38.6 36.1 ND 2-Nov-21 EPA 6O1OD 3.5 5 30.5 31.8 30.8 ND 17-May-22 EPA 6O2OB 0.7 5 34.2 30.9 34.2 --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 2 of 20 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Cadmium 28-Jun-95 NR 1 2.0 2.0 4.0 NA 25-Oct-95 NR 1 1.0 ND 1.0 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 1 ND ND ND NA 12-May-97 NR 1 ND ND ND NA 19-Nov-97 NR 1 ND ND ND NA 27-May-98 NR 1 ND ND ND NA 24-Nov-98 NR 1 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 1 ND ND NA ND 3-May-00 NR 1 ND ND ND ND 8-Nov-00 NR 1 ND ND ND ND 29-May-01 NR 1 ND ND ND ND 6-Nov-01 NR 1 ND ND ND ND 21-May-02 NR 1 ND ND ND ND 13-Nov-02 NR 1 ND ND ND ND 14-May-03 NR 1 ND ND ND ND 19-Nov-03 NR 1 ND ND ND ND 5-May-04 NR 1 ND ND ND ND 9-Nov-04 NR 1 ND ND ND ND 25-May-05 NR 1 ND ND Dry ND 2-Nov-05 NR 1 ND ND Dry ND 24-May-06 NR 1 ND ND Dry ND 1-Nov-06 NR 1 ND ND ND ND 29-May-07 NR 1 ND ND Dry ND 28-Nov-07 NR 1 ND ND Dry ND 28-May-08 0.5 1.0 ND ND Dry ND 5-Nov-08 0.50 1.0 ND ND Dry ND 2-Jun-09 0.50 1.0 ND ND ND ND 19-Nov-09 0.50 1.0 ND ND ND ND NC2B = 2 pg/L (05/01/2007) 14-Jun-10 0.50 1.0 ND ND Dry ND 29-Nov-10 0.50 1.0 ND ND Dry ND 31-May-11 0.50 1.0 ND ND Dry ND 19-Dec-11 1.0 1.0 ND ND ND ND 30-May-12 1.0 1.0 ND ND ND ND 3-Dec-12 1.0 1.0 ND ND ND ND 11-Jun-13 1.0 1.0 ND ND ND ND 29-Oct-13 1.0 1.0 ND ND Dry ND 5-May-14 EPA 6010 1.0 1.0 ND ND ND ND 21-Oct-14 EPA 6010 1.0 1.0 ND ND ND ND 19-May-15 EPA 6010 0.5 1.0 ND ND Dry NA 7-Dec-15 EPA 6010 0.5 1.0 ND ND ND ND 2-May-16 EPA 6010 0.5 1.0 ND ND ND ND 12-Dec-16 EPA 6010 0.5 1.0 ND ND NS ND 26-Jun-17 EPA 6010 0.5 1.0 ND ND ND ND 14-Dec-17 0.5 1.0 ND ND ND ND 14-May-18 EPA 6010 0.5 1.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 0.5 1.0 ND ND ND ND 6-May-19 EPA 6O1OD 0.5 1.0 ND ND ND ND 5-Nov-19 EPA 6O1OD 0.5 1.0 ND ND ND --- 6-May-20 EPA 6O1OD 0.4 1.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 0.4 1.0 ND ND ND ND 4-May-21 EPA 6O1OD 0.4 1.0 ND ND ND ND 2-Nov-21 EPA 6O1OD 0.4 1.0 ND ND ND ND 17-May-22 EPA 6O2OB 0.1 0.5 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 3 of 20 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Chromium 12-May-97 NR 1 2.0 1.0 2.0 NA 19-Nov-97 NR 1 ND ND ND NA 27-May-98 NR 1 ND ND ND NA 24-Nov-98 NR 1 ND ND 1.00 NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND 12.0 ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 24.0 22.0 24.0 ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND ND Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.4 10.0 0.87 J 1.0 J Dry 0.85 J 5-Nov-08 0.40 10.0 0.76 J 0.76 J Dry ND 2-Jun-09 0.40 10.0 0.45 J 0.48 J 4.7 J ND 19-Nov-09 0.40 10.0 0.67 B 0.66 B 2.2 B 1.1 J NC2B = 20 pg/L (05/01/2007) 14-Jun-10 0.40 10.0 0.75 J 1.0 J Dry ND 29-Nov-10 0.40 10.0 ND 0.80 J Dry ND 31-May-11 0.40 10.0 1.2 B 0.84 B Dry 0.73 J 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND 7.4 J ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND 6.3 J ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND 3.3 J ND 2-May-16 EPA 6010 2.5 10.0 ND ND 3.8 J ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND 7.7 J ND 14-Dec-17 2.5 10.0 ND ND 4.6 J ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 ND ND 2.8 J ND 6-May-19 EPA 6O1OD 2.5 5.0 ND ND 4.4 J ND 5-Nov-19 EPA 6O1OD 2.5 5.0 ND ND ND --- 6-May-20 EPA 6O1OD 3.7 5.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 3.7 5.0 ND ND ND ND 4-May-21 EPA 6O1OD 3.7 5.0 ND ND ND ND 2-Nov-21 EPA 6O1OD 3.7 5.0 ND ND ND ND 17-May-22 EPA 6O2OB 1.1 5.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 4 of 20 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Cobalt 28-Jun-95 NR 10 ND ND 13.0 NA 25-Oct-95 NR 10 ND ND 12.0 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 10 ND ND 20.0 NA 12-May-97 NR 6 ND ND 11.0 NA 19-Nov-97 NR 5 ND ND 13.0 NA 27-May-98 NR 1 2.0 ND 13.0 NA 24-Nov-98 NR 1 ND ND 11.0 NA 12-May-99 NR 10 ND ND 6.9 ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND 23.0 ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND ND Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.6 10.0 ND ND Dry ND 5-Nov-08 0.60 10.0 4.0 B 3.4 B Dry 3.5 J 2-Jun-09 0.60 10.0 4.8 B 7.0 B 8.6 B 3.3 J 19-Nov-09 0.60 10.0 ND ND 1.1 J ND NC213 = NE (05/01/2007) 14-Jun-10 0.60 10.0 ND ND Dry ND 29-Nov-10 0.60 10.0 ND ND Dry ND 31-May-11 0.60 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND 7.9 J ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND 6 J ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND 9.6 J NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND 7.5 J ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 ND ND 3.6 J ND 6-May-19 EPA 6O1OD 2.5 5.0 ND ND 4.2 J ND 5-Nov-19 EPA 6O1OD 2.5 5.0 ND ND ND --- 6-May-20 EPA 6O1OD 3.6 5.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 3.6 5.0 ND ND ND ND 4-May-21 EPA 6O1OD 3.6 5.0 ND ND ND ND 2-Nov-21 EPA 6O1OD 3.6 5.0 ND ND ND ND 17-May-22 EPA 6O2OB 0.4 5.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 5 of 20 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Copper 28-May-08 0.3 10 2.1 J 2.2 J Dry 0.38 J 5-Nov-08 0.30 10 1.4 B 0.71 B Dry 0.94 J 2-Jun-09 0.30 10 ND ND 1.8 J ND 19-Nov-09 0.30 10 1.5 J 1.9 J 1.9 J ND NC2B = 7 pg/L (05/01/2007)* 14-Jun-10 0.30 10 0.95 J 1.1 J Dry ND 29-Nov-10 0.30 10 ND 0.39 J Dry ND 31-May-11 0.30 10 ND 1.3 J Dry ND 19-Dec-11 5.0 10 ND ND 8.6 J ND 30-May-12 5.0 10 ND ND ND ND 3-Dec-12 5.0 10 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND 10.8 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND 5.5 J ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND 6.4 J ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND 3.0 J ND 2-May-16 EPA 6010 2.5 10.0 ND ND 12.1 * ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND 6.4 J ND 14-Dec-17 2.5 10.0 ND ND 4.7 J ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 ND ND ND ND 6-May-19 EPA 6O1OD 2.5 5.0 ND ND ND ND 5-Nov-19 EPA 6O1OD 2.5 5.0 ND ND ND --- 6-May-20 EPA 6O1OD 4.3 5.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 4.3 5.0 ND ND ND ND 4-May-21 EPA 6O1OD 4.3 5.0 ND ND ND ND 2-Nov-21 EPA 6O1OD 4.3 5.0 ND ND ND ND 17-May-22 EPA 6O2OB 1.0 5.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 6 of 20 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Lead 28-Apr-94 NR 1 1.0 ND ND NA 6-Oct-94 NR 5 ND ND ND NA 28-Jun-95 NR 5 ND ND ND NA 25-Oct-95 NR 5 ND ND ND NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 5 ND ND ND NA 12-May-97 NR 5 ND ND ND NA 19-Nov-97 NR 5 ND ND ND NA 27-May-98 NR 5 ND ND ND NA 24-Nov-98 NR 5 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND ND ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 16.0 14.0 16.0 ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 2.3 B 2.5 B Dry 6.1 J 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 4 10.0 ND ND Dry ND 5-Nov-08 4.0 10.0 ND ND Dry ND 2-Jun-09 4.0 10.0 ND ND ND ND 19-Nov-09 4.0 10.0 ND ND ND ND NC2B = 25 pg/L (05/01/2007) 14-Jun-10 4.0 10.0 ND ND Dry ND 29-Nov-10 4.0 10.0 ND ND Dry ND 31-May-11 4.0 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND ND ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 4.1 J ND ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 ND ND ND ND 6-May-19 EPA 6O1OD 2.5 5.0 ND ND ND ND 5-Nov-19 EPA 6O1OD 2.5 5.0 ND ND ND --- 6-May-20 EPA 6O1OD 4.5 5.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 4.5 5.0 ND ND ND ND 4-May-21 EPA 6O1OD 4.5 5.0 ND ND ND ND 2-Nov-21 EPA 6O1OD 4.5 5.0 ND ND ND ND 17-May-22 EPA 6O2OB 0.9 1.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 7 of 20 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Nickel 12-May-99 NR 5 ND ND 5.6 ND 19-Oct-99 NR 50 ND ND NA ND 3-May-00 NR 50 ND ND ND ND 8-Nov-00 NR 50 ND ND ND ND 29-May-01 NR 50 ND ND ND ND 6-Nov-01 NR 50 ND ND ND ND 21-May-02 NR 50 ND ND ND ND 13-Nov-02 NR 50 ND ND ND ND 14-May-03 NR 50 ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND 5-May-04 NR 50 ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND 25-May-05 NR 50 ND ND Dry ND 2-Nov-05 NR 50 ND ND Dry ND 24-May-06 NR 50 ND ND Dry ND 1-Nov-06 NR 50 ND ND ND ND 29-May-07 NR 50 ND ND Dry ND 28-Nov-07 NR 50 ND ND Dry ND 28-May-08 1.7 50.0 ND ND Dry ND 5-Nov-08 1.7 50.0 ND ND Dry 2.2 J 2-Jun-09 1.7 50.0 ND ND 9.4 J ND 19-Nov-09 1.7 50.0 ND ND 4.6 B 2.2 J NC213 = 25 pg/L (05/01/2007) 14-Jun-10 1.7 50.0 ND ND Dry ND 29-Nov-10 1.7 50.0 ND ND Dry ND 31-May-11 1.7 50.0 ND ND Dry 2.3 J 19-Dec-11 5.0 50.0 ND ND 10.2 J ND 30-May-12 5.0 50.0 ND ND ND ND 3-Dec-12 5.0 50.0 ND ND ND ND 11-Jun-13 5.0 50.0 ND ND 5.8 J ND 29-Oct-13 5.0 50.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 50.0 ND ND 9.6 J ND 21-Oct-14 EPA 6010 5.0 50.0 ND ND 10.4 J ND 19-May-15 EPA 6010 2.5 50.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 50.0 ND ND 5.1 J ND 2-May-16 EPA 6010 2.5 50.0 ND ND 10.2 J ND 12-Dec-16 EPA 6010 2.5 50.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 50.0 ND ND 14.4 J ND 14-Dec-17 2.5 50.0 ND ND 8.7 J ND 14-May-18 EPA 6010 2.5 50.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 ND ND 5.9 ND 6-May-19 EPA 6O1OD 2.5 5.0 ND ND 6.3 ND 5-Nov-19 EPA 6O1OD 2.5 5.0 ND ND ND --- 6-May-20 EPA 6O1OD 3.5 5.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 3.5 5.0 ND ND ND ND 4-May-21 EPA 6O1OD 3.5 5.0 ND ND ND ND 2-Nov-21 EPA 6O1OD 3.5 5.0 ND ND ND ND 17-May-22 EPA 6O2OB 0.7 5.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 8 of 20 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Selenium 29-May-07 NR 10 ND 4.5 J Dry ND 28-Nov-07 NR 10 ND ND Dry 2.4 J 28-May-08 3.8 10.0 ND ND Dry ND 5-Nov-08 3.8 10.0 ND 4.3 B Dry 4.2 J 2-Jun-09 3.8 10.0 ND ND ND ND 19-Nov-09 3.8 10.0 4.5 J ND ND ND NC213 = 5 pg/L (05/01/2007) 14-Jun-10 3.8 10.0 ND ND Dry ND 29-Nov-10 3.8 10.0 ND ND Dry ND 31-May-11 3.8 10.0 ND ND Dry ND 19-Dec-11 10.0 10.0 ND ND ND ND 30-May-12 10.0 10.0 ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND 11-Jun-13 10.0 10.0 ND ND ND ND 29-Oct-13 10.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 10.0 10.0 ND ND ND ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND ND ND 19-May-15 EPA 6010 5.0 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 5.0 10.0 ND ND ND ND 2-May-16 EPA 6010 5.0 10.0 ND ND ND ND 12-Dec-16 EPA 6010 5.0 10.0 ND ND NS ND 26-Jun-17 EPA 6010 5.0 10.0 ND ND ND ND 14-Dec-17 5.0 10.0 ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 5.0 10.0 ND ND ND ND 6-May-19 EPA 6O1OD 5.0 10.0 ND ND ND ND 5-Nov-19 EPA 6O1OD 5.0 10.0 ND ND ND --- 6-May-20 EPA 6O1OD 4.7 10.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 4.7 10.0 ND ND ND ND 4-May-21 EPA 6O1OD 4.7 10.0 ND ND ND ND 2-Nov-21 EPA 6O1OD 4.7 10.0 ND ND ND ND 17-May-22 EPA 6O2OB 1.4 5.0 ND ND ND --- Silver 5-Nov-08 0.1 10.0 0.17 B 0.11 B Dry 0.20 J 2-Jun-09 0.10 10.0 ND ND ND ND 19-Nov-09 0.10 10.0 0.17 J 0.21 J 0.38 J ND NC213 = 0.06 pg/L (05/01/2007) 14-Jun-10 0.10 10.0 ND ND ND ND 29-Nov-10 0.10 10.0 ND ND Dry ND 31-May-11 0.10 10.0 ND 0.30 J Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND ND ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 ND ND ND ND 6-May-19 EPA 6O1OD 2.5 5.0 ND ND ND ND 5-Nov-19 EPA 6O1OD 2.5 5.0 ND ND ND --- 6-May-20 EPA 6O1OD 2.5 5.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 2.5 5.0 ND ND ND ND 4-May-21 EPA 6O1OD 2.5 5.0 ND ND ND ND 2-Nov-21 EPA 6O1OD 2.5 5.0 ND ND ND ND 17-May-22 EPA 6O2OB 0.4 5.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 9 of 20 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Thallium 4-Dec-18 EPA 6O2OB 0.1 0.1 ND ND 0.077 J --- 6-May-19 EPA 6O2OB 0.1 0.1 ND ND 0.11 ND 5-Nov-19 EPA 6O2OB 0.1 0.1 ND ND ND --- 6-May-20 EPA 6O2OB 0.1 0.1 ND ND ND --- 9-Nov-20 EPA 6O2OB 0.1 0.1 ND ND ND ND 4-May-21 EPA 6O2OB 0.1 1.0 ND ND ND ND 2-Nov-21 EPA 6O2OB 0.1 0.5 ND ND ND ND 17-May-22 EPA 6O2OB 0.2 1.0 ND ND ND --- Vanadium 19-Nov-03 NR 40.0 62.00 56.00 60.00 ND 5-May-04 NR 40 ND ND ND ND 9-Nov-04 NR 40 ND ND ND ND 25-May-05 NR 40 ND ND Dry ND 2-Nov-05 NR 40 ND ND Dry ND 24-May-06 NR 40 ND ND Dry ND 1-Nov-06 NR 40 ND ND ND ND 29-May-07 NR 25 ND ND Dry ND 28-Nov-07 NR 25 ND ND Dry ND 28-May-08 0.2 25.0 3.2 J 4.1 J Dry ND 5-Nov-08 0.20 25.0 0.63 B 0.78 B Dry 0.85 J 2-Jun-09 0.20 25.0 1.9 B 2.1 B 1.1 B 1.2 J 19-Nov-09 0.20 25.0 2.6 B 3.0 J 0.95 B 0.58 J NUB = NE (05/01/2007) 14-Jun-10 0.20 25.0 2.3 B 2.2 B Dry 1.2 J 29-Nov-10 0.20 25.0 ND ND Dry ND 31-May-11 0.20 25.0 1.7 J 1.7 J Dry ND 19-Dec-11 5.0 25.0 ND ND ND ND 30-May-12 5.0 25.0 ND ND ND ND 3-Dec-12 5.0 25.0 ND ND ND ND 11-Jun-13 5.0 25.0 8.5 J 8 J ND ND 29-Oct-13 5.0 25.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 25.0 ND ND ND ND 21-Oct-14 EPA 6010 5.0 25.0 ND ND ND ND 19-May-15 EPA 6010 2.5 25.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 25.0 ND ND ND ND 2-May-16 EPA 6010 2.5 25.0 3.3 J 3.1 J ND ND 12-Dec-16 EPA 6010 2.5 25.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 25.0 4 J 4.4 J 4.1 J ND 14-Dec-17 2.5 25.0 ND ND ND ND 14-May-18 EPA 6010 2.5 25.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 ND ND ND ND 6-May-19 EPA 6O1OD 2.5 5.0 ND ND ND ND 5-Nov-19 EPA 6O1OD 1.3 5.0 1.4 J 1.5 J 1.5 J --- 6-May-20 EPA 6O1OD 3.9 5.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 3.9 5.0 ND ND ND ND 4-May-21 EPA 6O1OD 3.9 5.0 5.40 6.40 5.70 ND 2-Nov-21 EPA 6O1OD 3.9 5.0 ND ND ND ND 17-May-22 EPA 6O2OB 1.9 10.0 2.50 J 2.90 J 3.20 J --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 10 of 20 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Zinc 6-Oct-94 NR 10 ND ND 11.0 NA 28-Jun-95 NR 10 17.0 21.0 60.0 NA 25-Oct-95 NR 10 28.0 ND ND NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 10 18.0 ND 34.0 NA 12-May-97 NR 10 50.0 30.0 30.0 NA 19-Nov-97 NR 10 ND ND ND NA 27-May-98 NR 10 ND 20.0 10.0 NA 24-Nov-98 NR 10 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 50 ND ND NA ND 3-May-00 NR 50 ND ND ND ND 8-Nov-00 NR 50 ND ND ND ND 29-May-01 NR 50 ND ND ND ND 6-Nov-01 NR 50 ND ND ND ND 21-May-02 NR 50 ND ND ND ND 13-Nov-02 NR 50 ND ND ND ND 14-May-03 NR 50 ND ND ND ND 19-Nov-03 NR 50 70.0 60.0 70.0 ND 5-May-04 NR 50 ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND 25-May-05 NR 50 ND ND Dry ND 2-Nov-05 NR 50 ND ND Dry ND 24-May-06 NR 50 ND ND Dry ND 1-Nov-06 NR 50 ND ND ND ND 29-May-07 NR 10 3.2 B 3.3 B Dry 2.0 J 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.4 10.0 2.4 B 3.5 B Dry 2.1 J 5-Nov-08 0.40 10.0 2.8 B 1.6 B Dry 8.9 J 2-Jun-09 0.40 10.0 0.70 B 2.7 B 3.9 B 83.0 19-Nov-09 0.40 10.0 6.7 B 8.0 B 14.5 B 3.5 J NC2B = 50 pg/L (05/01/2007) 14-Jun-10 0.40 10.0 ND ND Dry ND 29-Nov-10 0.40 10.0 ND ND Dry ND 31-May-11 0.40 10.0 14.9 B 11.6 B Dry 13.7 19-Dec-11 10.0 10.0 ND ND 181 ND 30-May-12 10.0 10.0 ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND 11-Jun-13 10.0 10.0 11.8 B 13 B 11.7 B 76.3 29-Oct-13 10.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 10.0 10.0 ND ND 10.3 ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND 18.0 ND 19-May-15 EPA 6010 5.0 10.0 ND 10.4 Dry NA 7-Dec-15 EPA 6010 5.0 10.0 ND ND 15.7 B 7.2 J 2-May-16 EPA 6010 5.0 10.0 ND 5.9 J 49.2 ND 12-Dec-16 EPA 6010 5.0 10.0 ND 8.0 J NS ND 26-Jun-17 EPA 6010 5.0 10.0 ND ND 29.9 ND 14-Dec-17 5.0 10.0 ND ND 13.5 ND 14-May-18 EPA 6010 5.0 10.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 5.0 10.0 ND ND 7.4 J ND 6-May-19 EPA 6O1OD 5.0 10.0 ND ND ND ND 5-Nov-19 EPA 6O1OD 5.0 10.0 ND ND ND --- 6-May-20 EPA 6O1OD 9.5 10.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 9.5 10.0 ND ND ND ND 4-May-21 EPA 6O1OD 9.5 10.0 ND ND ND ND 2-Nov-21 EPA 6O1OD 9.5 10.0 ND ND ND ND 17-May-22 EPA 6O2OB 7.0 10.0 ND ND ND --- Beryllium 5-Nov-19 EPA 6O1OD 0.2 1.0 ND 0.24 J ND --- 6-May-20 EPA 6O1OD 0.7 1.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 0.7 1.0 ND ND ND ND 4-May-21 EPA 6O1OD 0.7 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 11 of 20 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks 2-Nov-21 17-May-22 EPA 6010D EPA 6020B 0.7 0.1 1.0 0.5 ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 12 of 20 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks ORGANICS Acetone 28-Nov-07 NR 100 3.0 B 3.3 B Dry 4.3 J 28-May-08 20 100 ND ND Dry ND 5-Nov-08 20.0 100 ND ND Dry ND 2-Jun-09 2.2 100 ND ND 6.0 B 3.2 J 19-Nov-09 2.2 100 4.0 B ND ND 3.8 J NC2B = NE (05/01/2007) 14-Jun-10 2.2 100 ND ND Dry 9.8 J 29-Nov-10 2.2 100 ND ND Dry 4.3 J 31-May-11 2.2 100 ND ND Dry 3.9 J 19-Dec-11 2.2 100 ND ND ND 6.6 J 30-May-12 2.2 100 ND ND ND ND 3-Dec-12 2.2 100 ND ND ND ND 11-Jun-13 2.2 100 ND ND ND ND 29-Oct-13 50.0 500 ND ND Dry ND 5-May-14 EPA 8260 10.0 100 ND ND 17.6 J ND 21-Oct-14 EPA 8260 10.0 100 ND ND ND ND 19-May-15 EPA 8260 10.0 100 ND ND Dry NA 7-Dec-15 EPA 8260 10.0 100 ND ND ND ND 2-May-16 EPA 8260 10.0 100 ND ND ND ND 12-Dec-16 EPA 8260 10.0 100 ND ND NS ND 26-Jun-17 EPA 8260 10.0 100 10.8 J 26.9 J 13.4 J 23.0 J 14-Dec-17 10.0 100 ND ND ND ND 14-May-18 EPA 8260 10.0 100 ND ND ND ND 4-Dec-18 EPA 8260B 10.0 25 ND ND ND ND 6-May-19 EPA 8260D 8.2 25 ND ND ND ND 5-Nov-19 EPA 8260D 6.2 25 ND ND ND --- 6-May-20 EPA 8260D 6.2 25 ND ND ND ND 9-Nov-20 EPA 8260D 6.2 25 ND ND ND ND 4-May-21 EPA 8260D 5.1 25 ND ND ND ND 2-Nov-21 EPA 8260D 5.1 25 ND ND ND ND 17-May-22 EPA 8260D 5.1 25 ND ND ND ND Benzene 19-Nov-09 0.25 1.0 2.1 0.48 J ND ND Resample> 15-Feb-10 0.25 1.0 ND NS NS ND NC2B = 1.19 pg/L (05/01/2007) 14-Jun-10 0.25 1.0 ND ND Dry ND 29-Nov-10 0.25 1.0 ND ND Dry ND 31-May-11 0.25 1.0 ND ND Dry ND 19-Dec-11 0.25 1.0 ND ND ND ND 30-May-12 0.25 1.0 ND ND ND ND 3-Dec-12 0.25 1.0 ND ND ND ND 11-Jun-13 0.25 1.0 ND ND ND ND 29-Oct-13 0.25 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.25 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.25 1.0 ND ND ND ND 19-May-15 EPA 8260 0.25 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.25 1.0 ND ND ND ND 2-May-16 EPA 8260 0.25 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.25 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.25 1.0 ND ND ND ND 14-Dec-17 0.25 1.0 ND ND ND ND 14-May-18 EPA 8260 0.25 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.25 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.20 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.15 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.15 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.15 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.34 1.0 ND ND ND ND 2-Nov-21 EPA 8260D 0.34 1.0 ND ND ND ND 17-May-22 EPA 8260D 0.34 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 13 of 20 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Bromomethane 5-May-14 EPA 8260 0.29 10.0 ND ND 4.6 J ND NC2B = NE (05/01/2007) 21-Oct-14 EPA 8260 0.29 10.0 ND ND 0.41 J ND 19-May-15 EPA 8260 0.29 10.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.29 10.0 ND ND ND ND 2-May-16 EPA 8260 0.29 10.0 ND ND ND ND 12-Dec-16 EPA 8260 0.29 10.0 ND ND NS ND 26-Jun-17 EPA 8260 0.29 10.0 ND ND ND ND 14-Dec-17 0.29 10.0 ND ND ND ND 14-May-18 EPA 8260 0.29 10.0 ND ND ND ND 4-Dec-18 EPA 826OB 0.29 2.0 ND ND ND ND 6-May-19 EPA 826OD 0.95 2.0 ND ND 1.5 J ND 5-Nov-19 EPA 826OD 0.62 2.0 ND ND ND --- 6-May-20 EPA 826OD 0.62 2.0 ND ND ND ND 9-Nov-20 EPA 826OD 0.62 2.0 ND ND ND ND 4-May-21 EPA 826OD 1.70 2.0 ND ND ND ND 2-Nov-21 EPA 826OD 1.70 2.0 ND ND ND ND 17-May-22 EPA 826OD 1.70 2.0 ND ND ND ND Chlorobenzene 19-Nov-09 0.23 3.0 4.2 0.44 J ND ND NC2B = 488 pg/L (05/01/2007) 14-Jun-10 0.23 3.0 ND ND Dry ND 29-Nov-10 0.23 3.0 ND ND Dry ND 31-May-11 0.23 3.0 ND ND Dry ND 19-Dec-11 0.23 3.0 ND 0.58 J ND ND 30-May-12 0.23 3.0 ND ND ND ND 3-Dec-12 0.23 3.0 ND ND ND ND 11-Jun-13 0.23 3.0 ND ND ND ND 29-Oct-13 0.23 3.0 ND ND Dry ND 5-May-14 EPA 8260 0.23 3.0 ND ND ND ND 21-Oct-14 EPA 8260 0.23 3.0 ND ND ND ND 19-May-15 EPA 8260 0.23 3.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.23 3.0 ND ND ND ND 2-May-16 EPA 8260 0.23 3.0 ND ND ND ND 12-Dec-16 EPA 8260 0.23 3.0 ND ND NS ND 26-Jun-17 EPA 8260 0.23 3.0 ND ND ND ND 14-Dec-17 0.23 3.0 ND ND ND ND 14-May-18 EPA 8260 0.23 3.0 ND ND ND ND 4-Dec-18 EPA 826OB 0.23 1.0 ND ND ND ND 6-May-19 EPA 826OD 0.53 1.0 ND ND ND ND 5-Nov-19 EPA 826OD 0.23 1.0 ND ND ND --- 6-May-20 EPA 826OD 0.23 1.0 ND ND ND ND 9-Nov-20 EPA 826OD 0.23 1.0 ND ND ND ND 4-May-21 EPA 826OD 0.28 1.0 ND ND ND ND 2-Nov-21 EPA 826OD 0.28 1.0 ND ND ND ND 17-May-22 EPA 826OD 0.28 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 14 of 20 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Chloromethane 14-Jun-10 0.11 1.0 0.14 B 0.17 B Dry 0.15 J NC2B = NE (05/01/2007) 29-Nov-10 0.11 1.0 ND ND Dry ND 31-May-11 0.11 1.0 ND ND Dry ND 19-Dec-11 0.11 1.0 ND ND ND ND 30-May-12 0.11 1.0 ND ND ND ND 3-Dec-12 0.11 1.0 ND ND ND ND 11-Jun-13 0.11 1.0 ND ND ND ND 29-Oct-13 0.11 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.11 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.11 1.0 ND ND 0.19 J ND 19-May-15 EPA 8260 0.11 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.11 1.0 ND ND ND ND 2-May-16 EPA 8260 0.11 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.11 1.0 ND ND ND 0.36 J 26-Jun-17 EPA 8260 0.11 1.0 ND 0.28 J 0.54 J ND 14-Dec-17 0.11 1.0 ND ND ND ND 14-May-18 EPA 8260 0.11 1.0 ND ND ND ND 4-Dec-18 EPA 826OB 0.11 1.0 ND ND ND ND 6-May-19 EPA 826OD 0.38 1.0 ND ND ND ND 5-Nov-19 EPA 826OD 0.39 1.0 ND ND ND --- 6-May-20 EPA 826OD 0.39 1.0 ND ND ND ND 9-Nov-20 EPA 826OD 0.39 1.0 ND ND ND ND 4-May-21 EPA 826OD 0.54 1.0 ND ND ND ND 2-Nov-21 EPA 826OD 0.54 1.0 ND ND ND ND 17-May-22 EPA 826OD 0.54 1.0 ND ND ND ND 1,2-Dichlorobenzene 19-Nov-09 0.30 5.0 0.31 J 0.34 J ND ND NC2B = 488 pg/L (05/01/2007) 14-Jun-10 0.30 5.0 ND ND Dry ND 29-Nov-10 0.30 5.0 ND ND Dry ND 31-May-11 0.30 5.0 ND ND Dry ND 19-Dec-11 0.30 5.0 ND ND ND ND 30-May-12 0.30 5.0 ND ND ND ND 3-Dec-12 0.30 5.0 ND ND ND ND 11-Jun-13 0.30 5.0 ND ND ND ND 29-Oct-13 0.30 5.0 ND ND Dry ND 5-May-14 EPA 8260 0.30 5.0 ND ND ND ND 21-Oct-14 EPA 8260 0.30 5.0 ND ND ND ND 19-May-15 EPA 8260 0.30 5.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.30 5.0 ND ND ND ND 2-May-16 EPA 8260 0.30 5.0 ND ND ND ND 12-Dec-16 EPA 8260 0.30 5.0 ND ND NS ND 26-Jun-17 EPA 8260 0.30 5.0 ND ND ND ND 14-Dec-17 0.30 5.0 ND ND ND ND 14-May-18 EPA 8260 0.30 5.0 ND ND ND ND 4-Dec-18 EPA 826OB 0.30 1.0 ND ND ND ND 6-May-19 EPA 826OD 0.49 1.0 ND ND ND ND 5-Nov-19 EPA 826OD 0.29 1.0 ND ND ND --- 6-May-20 EPA 826OD 0.29 1.0 ND ND ND ND 9-Nov-20 EPA 826OD 0.29 1.0 ND ND ND ND 4-May-21 EPA 826OD 0.34 1.0 ND ND ND ND 2-Nov-21 EPA 826OD 0.34 1.0 ND ND ND ND 17-May-22 EPA 826OD 0.34 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 15 of 20 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks 1,4-Dichlorobenzene 19-Nov-09 0.33 1.0 4.5 1.9 ND ND NC2B = 488 pg/L (05/01/2007) 14-Jun-10 0.33 1.0 ND ND Dry ND 29-Nov-10 0.33 1.0 ND ND Dry ND 31-May-11 0.33 1.0 ND ND Dry ND 19-Dec-11 0.33 1.0 ND ND ND ND 30-May-12 0.33 1.0 ND ND ND ND 3-Dec-12 0.33 1.0 ND ND ND ND 11-Jun-13 0.33 1.0 ND ND ND ND 29-Oct-13 0.33 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.33 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.33 1.0 ND ND ND ND 19-May-15 EPA 8260 0.33 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.33 1.0 ND ND ND ND 2-May-16 EPA 8260 0.33 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.33 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.33 1.0 ND ND ND ND 14-Dec-17 0.33 1.0 ND ND ND ND 14-May-18 EPA 8260 0.33 1.0 ND ND ND ND 4-Dec-18 EPA 826OB 0.33 1.0 ND ND ND ND 6-May-19 EPA 826OD 0.58 1.0 ND ND ND ND 5-Nov-19 EPA 826OD 0.26 1.0 ND ND ND --- 6-May-20 EPA 826OD 0.26 1.0 ND ND ND ND 9-Nov-20 EPA 826OD 0.26 1.0 ND ND ND ND 4-May-21 EPA 826OD 0.33 1.0 ND ND ND ND 2-Nov-21 EPA 826OD 0.33 1.0 ND ND ND ND 17-May-22 EPA 826OD 0.33 1.0 ND ND ND ND 1,1-Dichloroethane 19-Nov-09 0.32 5.0 6.3 7.8 ND ND NUB = NE (05/01/2007) 14-Jun-10 0.32 5.0 ND ND Dry ND 29-Nov-10 0.32 5.0 ND ND Dry ND 31-May-11 0.32 5.0 ND ND Dry ND 19-Dec-11 0.32 5.0 ND ND ND ND 30-May-12 0.32 5.0 ND ND ND ND 3-Dec-12 0.32 5.0 ND ND ND ND 11-Jun-13 0.32 5.0 ND ND ND ND 29-Oct-13 0.32 5.0 ND ND Dry ND 5-May-14 EPA 8260 0.32 5.0 ND ND ND ND 21-Oct-14 EPA 8260 0.32 5.0 ND ND ND ND 19-May-15 EPA 8260 0.32 5.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.32 5.0 ND ND ND ND 2-May-16 EPA 8260 0.32 5.0 ND ND ND ND 12-Dec-16 EPA 8260 0.32 5.0 ND ND NS ND 26-Jun-17 EPA 8260 0.32 5.0 ND ND ND ND 14-Dec-17 0.32 5.0 ND ND ND ND 14-May-18 EPA 8260 0.32 5.0 ND ND ND ND 4-Dec-18 EPA 826OB 0.32 1.0 ND ND ND ND 6-May-19 EPA 826OD 0.41 1.0 ND ND ND ND 5-Nov-19 EPA 826OD 0.27 1.0 ND ND ND --- 6-May-20 EPA 826OD 0.27 1.0 ND ND ND ND 9-Nov-20 EPA 826OD 0.27 1.0 ND ND ND ND 4-May-21 EPA 826OD 0.37 1.0 ND ND ND ND 2-Nov-21 EPA 826OD 0.37 1.0 ND ND ND ND 17-May-22 EPA 826OD 0.37 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 16 of 20 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks cis-1,2-Dichloroethene 19-Nov-09 0.19 5.0 5.5 43.8 ND 0.26 J NC2B = NE (05/01/2007) 14-Jun-10 0.19 5.0 ND ND Dry ND 29-Nov-10 0.19 5.0 ND ND Dry ND 31-May-11 0.19 5.0 ND ND Dry ND 19-Dec-11 0.19 5.0 ND ND ND ND 30-May-12 0.19 5.0 ND ND ND ND 3-Dec-12 0.19 5.0 ND ND ND ND 11-Jun-13 0.19 5.0 ND ND ND ND 29-Oct-13 0.19 5.0 ND ND Dry ND 5-May-14 EPA 8260 0.19 5.0 ND ND ND ND 21-Oct-14 EPA 8260 0.19 5.0 ND ND ND ND 19-May-15 EPA 8260 0.19 5.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.19 5.0 ND ND ND ND 2-May-16 EPA 8260 0.19 5.0 ND ND ND ND 12-Dec-16 EPA 8260 0.19 5.0 ND ND NS ND 26-Jun-17 EPA 8260 0.19 5.0 ND ND ND ND 14-Dec-17 0.19 5.0 ND ND ND ND 14-May-18 EPA 8260 0.19 5.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.19 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.66 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.29 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.29 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.29 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.38 1.0 ND ND ND ND 2-Nov-21 EPA 8260D 0.38 1.0 ND ND ND ND 17-May-22 EPA 8260D 0.38 1.0 ND ND ND ND 1,2-Dichloropropane 19-Nov-09 0.27 1.0 2.3 1.0 ND ND Resample> 15-Feb-10 0.27 1.0 ND ND NS ND NC2B = NE (05/01/2007) 14-Jun-10 0.27 1.0 ND ND Dry ND 29-Nov-10 0.27 1.0 ND ND Dry ND 31-May-11 0.27 1.0 ND ND Dry ND 19-Dec-11 0.27 1.0 ND ND ND ND 30-May-12 0.27 1.0 ND ND ND ND 3-Dec-12 0.27 1.0 ND ND ND ND 11-Jun-13 0.27 1.0 ND ND ND ND 29-Oct-13 0.27 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.27 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.27 1.0 ND ND ND ND 19-May-15 EPA 8260 0.27 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.27 1.0 ND ND ND ND 2-May-16 EPA 8260 0.27 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.27 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.27 1.0 ND ND ND ND 14-Dec-17 0.27 1.0 ND ND ND ND 14-May-18 EPA 8260 0.27 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.27 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.60 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.19 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.19 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.19 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.36 1.0 ND ND ND ND 2-Nov-21 EPA 8260D 0.36 1.0 ND ND ND ND 17-May-22 EPA 8260D 0.36 1.0 ND ND ND ND 1,4-Dioxane (p-Dioxane) 4-Dec-18 EPA 8260B 1.90 2.0 ND ND 10.5 ND 6-May-19 EPA 8260D 1.20 2.0 ND ND 7.6 ND 5-Nov-19 EPA 8260D 1.20 2.0 ND ND ND --- 6-May-20 EPA 8260D 1.20 2.0 ND ND ND ND 9-Nov-20 EPA 8260D 1.20 2.0 ND ND ND ND 4-May-21 EPA 8260D 0.86 2.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 17 of 20 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks 2-Nov-21 17-May-22 EPA 8260D EPA 8260D 0.86 0.86 2.0 2.0 ND ND 1.40 J ND ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 18 of 20 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Tetrachloroethene 19-Nov-09 0.46 1.0 0.58 J 8.8 ND ND Resample> 15-Feb-10 0.46 1.0 NS ND NS ND NUB = 0.7 pg/L (05/01/2007) 14-Jun-10 0.46 1.0 ND ND Dry ND 29-Nov-10 0.46 1.0 ND ND Dry ND 31-May-11 0.46 1.0 ND ND Dry ND 19-Dec-11 0.46 1.0 ND ND ND ND 30-May-12 0.46 1.0 ND ND ND ND 3-Dec-12 0.46 1.0 ND ND ND ND 11-Jun-13 0.46 1.0 ND ND ND ND 29-Oct-13 0.46 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.46 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.46 1.0 ND ND ND ND 19-May-15 EPA 8260 0.46 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.46 1.0 ND ND ND ND 2-May-16 EPA 8260 0.46 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.46 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.46 1.0 ND ND ND ND 14-Dec-17 0.46 1.0 ND ND ND ND 14-May-18 EPA 8260 0.46 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.46 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.78 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.16 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.16 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.16 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.29 1.0 ND ND ND ND 2-Nov-21 EPA 8260D 0.29 1.0 ND ND ND ND 17-May-22 EPA 8260D 0.29 1.0 ND ND ND ND Trichloroethene 19-Nov-09 0.47 1.0 2.1 6.9 ND ND Resample> 15-Feb-10 0.47 1.0 NS ND NS ND NUB = 2.5 pg/L (05/01/2007) 14-Jun-10 0.47 1.0 ND ND Dry ND 29-Nov-10 0.47 1.0 ND ND Dry ND 31-May-11 0.47 1.0 ND ND Dry ND 19-Dec-11 0.47 1.0 ND ND ND ND 30-May-12 0.47 1.0 ND ND ND ND 3-Dec-12 0.47 1.0 ND ND ND ND 11-Jun-13 0.47 1.0 ND ND ND ND 29-Oct-13 0.47 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.47 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.47 1.0 ND ND ND ND 19-May-15 EPA 8260 0.47 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.47 1.0 ND ND ND ND 2-May-16 EPA 8260 0.47 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.47 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.47 1.0 ND ND ND ND 14-Dec-17 0.47 1.0 ND ND ND ND 14-May-18 EPA 8260 0.47 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.47 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.34 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.22 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.22 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.22 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.38 1.0 ND ND ND ND 2-Nov-21 EPA 8260D 0.38 1.0 ND ND ND ND 17-May-22 EPA 8260D 0.38 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 19 of 20 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Vinyl Chloride 19-Nov-09 0.62 1.0 2.6 ND ND ND Resample> 15-Feb-10 0.62 1.0 ND NS NS ND NC213 = 0.025 pg/L (05/01/2007) 14-Jun-10 0.62 1.0 ND ND Dry ND 29-Nov-10 0.62 1.0 ND ND Dry ND 31-May-11 0.62 1.0 ND ND Dry ND 19-Dec-11 0.62 1.0 ND ND ND ND 30-May-12 0.62 1.0 ND ND ND ND 3-Dec-12 0.62 1.0 ND ND ND ND 11-Jun-13 0.62 1.0 ND ND ND ND 29-Oct-13 0.62 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.62 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.62 1.0 ND ND ND ND 19-May-15 EPA 8260 0.62 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.62 1.0 ND ND ND ND 2-May-16 EPA 8260 0.62 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.62 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.62 1.0 ND ND ND ND 14-Dec-17 0.62 1.0 ND ND ND ND 14-May-18 EPA 8260 0.62 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.62 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.60 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.24 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.24 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.24 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.39 1.0 ND ND ND ND 2-Nov-21 EPA 8260D 0.39 1.0 ND ND ND ND 17-May-22 EPA 8260D 0.39 1.0 ND ND ND ND Hardness, Total (SM 234013) 6-May-20 EPA 6010D 131.00 662.0 25,300 22,600 25,100 --- Notes: RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; SWSL for December 2006 - 2017, and MRL 2017-present.). DL = Laboratory Detection Limit. ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006). J = Estimated concentration less than the RL but above the DL. B = Blank -Qualified Concentration (suspected to reflect laboratory or field contamination). NC213 = 15A NCAC 2B Surface Water Standards. Dry = Surface water point was considered to be dry and no sample collected. Surface water has been classified as Water Supply IV - Highly Developed, Freshwater, Critical Area. Bold values are greater than the NC213. NA = No data available. NR = Not reported. NS = Not sampled. NE = Not established. Burke County, Kirksey Drive Landfil Permit No. 12-01 Page 20 of 20 Labella Associates TABLE A2-5: Historical Surface Water Field Parameters Parameter Collection Date SW-1 SW-2 SW-3 Conductivity (at 25 DC) 11-Jun-13 54.4 63.2 655 [MS/CM] 29-Oct-13 78.2 67.8 -- 5-May-14 90.0 115.9 1036 20-Oct-14 103.2 130.7 1099 18-May-15 92.0 97 -- 7-Dec-15 90.0 94 647 2-May-16 73.8 71 1391 12-Dec-16 95.8 506 -- 26-Jun-17 92.0 1152 1032 14-Dec-17 122.0 61 869 14-May-18 137.0 220 105 4-Dec-18 102.9 90.6 395.4 6-May-19 96.1 91.8 986 4-Nov-19 78 92.4 80.9 6-May-20 77.0 76.8 76.8 9-Nov-20 68.4 69.6 74.5 4-May-21 61.1 54 79.8 2-Nov-21 115.4 100.0 112.0 17-May-22 92 110.3 112.9 pH 11-Jun-13 7.8 8.25 7.81 [S.U.] 29-Oct-13 7.2 6.85 -- 5-May-14 8.1 8.42 8.17 20-Oct-14 7.0 7.38 7.8 18-May-15 7.0 6.87 -- 7-Dec-15 7.3 7.27 8.03 2-May-16 8.0 6.91 6.78 12-Dec-16 7.0 6.51 -- 26-Jun-17 7.2 5.64 7.36 14-Dec-17 8.3 8.26 8.3 14-May-18 7.6 7.61 7.14 4-Dec-18 7.4 7.36 6.78 6-May-19 6.60 6.98 7.92 4-Nov-19 6.60 6.78 6.63 6-May-20 7.5 7.43 7.43 9-Nov-20 6.32 7.09 7.18 4-May-21 6.93 6.62 6.76 2-Nov-21 7.32 6.86 6.22 17-May-22 6.99 6.99 7.10 Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 Page 1 of 3 TABLE A2-5: Historical Surface Water Field Parameters Parameter Collection Date SW-1 SW-2 SW-3 Temperature 11-Jun-13 19.2 18.1 19.7 [ ° C] 29-Oct-13 13.1 12.4 -- 5-May-14 19.2 19 17.9 20-Oct-14 14.3 14.1 13.8 18-May-15 19.1 19.5 -- 7-Dec-15 10.6 10.4 10.7 2-May-16 19.6 19.3 20.2 12-Dec-16 8.7 11 -- 26-Jun-17 20.0 19.9 19.8 14-Dec-17 6.2 6 6.8 14-May-18 12.4 19.9 19.4 4-Dec-18 11.5 11.7 6.3 6-May-19 20.1 19.4 18.5 4-Nov-19 10.07 10.6 10.7 6-May-20 14.4 17.2 17.2 9-Nov-20 16.2 17.1 17.1 4-May-21 16.2 16.2 16.5 2-Nov-21 11.6 13.6 13.9 17-May-22 20.2 19.5 19.9 Dissolved Oxygen 6-May-19 5.89 6.14 5.93 (mg/L) 4-Nov-19 7.23 6.56 7.27 6-May-20 5.2 4.89 4.89 9-Nov-20 7.86 7.82 6.65 4-May-21 9.35 8.79 7.62 2-Nov-21 8.52 7.23 6.88 17-May-22 6.47 7.3 6.72 Oxidation Reduction Potential 6-May-19 135.0 119.8 183.3 (mV) 4-Nov-19 147.6 43.4 99.9 6-May-20 326.9 214 214 9-Nov-20 219.9 37.8 7.1 4-May-21 30.1 43.9 4.7 2-Nov-21 -55.0 -17.1 -55.1 17-May-22 87.6 94.9 45.5 Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 Page 2 of 3 TABLE A2-5: Historical Surface Water Field Parameters Parameter Collection Date SW-1 SW-2 SW-3 Turbidity 11-Jun-13 48.10 34.60 19.71 [NTU] 29-Oct-13 7.34 4.89 -- 5-May-14 15.50 16.70 15.80 20-Oct-14 12.02 11.85 20.40 18-May-15 8.63 6.09 -- 7-Dec-15 6.75 5.25 4.86 2-May-16 7.05 8.75 7.85 12-Dec-16 8.05 9.20 -- 26-Jun-17 15.05 8.70 9.01 14-Dec-17 61.00 4.04 4.34 14-May-18 0.40 0.00 0.40 4-Dec-18 12.30 20.60 7.37 6-May-19 11.1 10.2 17.5 4-Nov-19 11.6 10.4 10.0 6-May-20 15.6 15.6 15.6 9-Nov-20 7.5 9.13 9.24 4-May-21 47.4 77.90 47.40 2-Nov-21 6.37 6.19 5.72 17-May-22 9.94 11.60 8.30 Notes: °C= degrees Centigrade pS/cm = microSemens per centimeter S.U.= Standard Units NTU = Nephelometric Turbidity Units my = millivolts mg/L - milligrams per liter Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 Page 3 of 3