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HomeMy WebLinkAbout5002_JacksonCounty_MSWLF_March22GW_FID1695532_20220714DENR USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Anchor QEA of North Carolina, PLLC Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Chuck E-mail: cpippin@anchorgea.com Phone: 828-281-3350 NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Jackson County Municipal Solid US Highway 441 50-02 .1600 March 7 & 8, 2022 Waste Landfill Dillsboro, North Carolina 28725 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑X Detection Monitoring ❑ Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data El water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Chuck Pippin, PG Project Manager Facility Representai_ON Title Signature 231 Haywood Street Asheville, North Carolina 28801 Facility Representative Address P-1649 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 828-281-3350 (Area Code) Telephone Number 07/14/2022 Affix NC Licensed/ Professional Geologist Seal Date CA 0l, a 1587 "'•y9,Q�OL0 • Q�Q,. F r l l i July 2022 ANCHOR Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 INZ Q E A `'`'" Spring 2022 Semiannual Water Quality Monitoring Report Prepared for Jackson County Solid Waste Department July 2022 Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 Spring 2022 Semiannual Water Quality Monitoring Report Prepared for Jackson County Solid Waste Department 401 Grindstaff Cove Road Sylva, North Carolina 28779 Prepared by Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Katie Pressley, PG Staff Scientist Project Number: C01480-01.02 \\athena\Asheville\Projects\Jackson County\, -Reports - Groundwater\2022\01-Spring 2022\Text\Jackson County_ Semiannual Water Quality Report_S pri ng_2022.docx Table of Contents Table of Contents Abbreviations 1 Introduction 1 2 Semiannual Monitoring...........................................................................................................3 2.1 Groundwater, Surface Water, Domestic Well, and Leachate Sampling..........................................3 2.1.1 Monitoring Well Purging and Sampling Methods.................................................................3 2.1.2 Surface Water Sampling Methods................................................................................................4 2.1.3 Leachate Sampling Methods..........................................................................................................5 2.1.4 Domestic Well Sampling Methods...............................................................................................5 2.2 Sample Handling, Documentation, and Analysis....................................................................................5 3 Findings........................................................................................................................................7 3.1 Groundwater.........................................................................................................................................................7 3.1.1 Field Parameters..................................................................................................................................8 3.1.2 Appendix I Metals (Total).................................................................................................................8 3.1.3 Appendix I Metals (Dissolved)........................................................................................................9 3.1.4 Appendix I VOCs and 1,4-Dioxane...............................................................................................9 3.2 Surface Water....................................................................................................................................................10 3.2.1 Field Parameters...............................................................................................................................10 3.2.2 Appendix I Metals............................................................................................................................ 10 3.2.3 Appendix I VOCs and 1,4-Dioxane............................................................................................11 3.3 Leachate...............................................................................................................................................................11 3.4 Domestic Well.................................................................................................................................................... 11 3.4.1 Field Parameters...............................................................................................................................11 3.4.2 VOCs...................................................................................................................................................... 12 3.5 Groundwater Flow Directions...................................................................................................................... 12 4 Summary....................................................................................................................................13 4.1 Groundwater Quality....................................................................................................................................... 13 4.1.1 Appendix I Metals............................................................................................................................ 13 4.1.2 Appendix I Volatile Organic Compounds and 1,4-Dioxane............................................. 13 4.1.3 Field Parameters and Other Constituents............................................................................... 13 4.2 Surface Water Quality..................................................................................................................................... 13 Spring 2022 Semiannual Water Quality Monitoring Report i July 2022 4.3 Leachate Quality............................................................................................................................................... 14 4.4 Domestic Well Water Quality......................................................................................................................14 5 Future Activities 6 References TABLES Table 1 Summary of Laboratory Analyses Performed on Samples Table 2 Well Construction Details and Corresponding Elevations Table 3 Analytical Summary Table 4 Mass Removal Calculations for VOCs Detected in the Leachate Sample (LT-01) FIGURES Figure 1 Site Location Map Figure 2 Site Layout Map Figure 3 Generalized Groundwater Flow Direction Figure 4 Hydrograph and Constituents of Concern Versus Time — MW-01 Figure 5 Hydrograph and Constituents of Concern Versus Time — MW-02 Figure 6 Hydrograph and Constituents of Concern Versus Time — MW-03 Figure 7 Hydrograph and Constituents of Concern Versus Time — MW-04 Figure 8 Hydrograph and Constituents of Concern Versus Time — MW-05R Figure 9 Hydrograph and Constituents of Concern Versus Time — MW-06 Figure 10 Hydrograph and Constituents of Concern Versus Time — MW-07 APPENDICES Appendix A Well Sampling Logs, and Equipment Documentation and Instrument Calibration Data Sheets Appendix B Reports of Laboratory Analysis, Chain -of -Custody Documentation, and Certificates of Analysis 15 i C-1 Spring 2022 Semiannual Water Quality Monitoring Report ii July 2022 Abbreviations pg/L micrograms per liter pmhos/cm micromhos per centimeter 2L standard 15A NCAC 2L.0202 Groundwater Standard CAER Five -Year Corrective Action Evaluation Report CAP Corrective Action Plan DEQ North Carolina Department of Environmental Quality DO dissolved oxygen EPA U.S. Environmental Protection Agency IMAC interim maximum allowable concentration J joule MDL method detection limit mg/L milligrams per liter MNA monitored natural attenuation mV millivolts NCAC North Carolina Administrative Code NTU nephelometric turbidity unit ORP oxidation reduction potential PWR partially weathered rock SC specific conductivity Site closed Municipal Solid Waste Landfill SM Standard Method SU standard unit SWS Solid Waste Section TWSA Tuckasegee Water & Sewer Authority VOC volatile organic compound Spring 2022 Semiannual Water Quality Monitoring Report iii July 2022 Introduction The Jackson County Solid Waste Department maintains a closed Municipal Solid Waste Landfill (Site) approximately 0.75 mile west of Dillsboro, North Carolina, on the northeast side of Old Dillsboro Road (Old U.S. Highway 74; Figure 1). Water quality monitoring at the landfill is governed by the North Carolina Department of Environmental Quality (DEQ), Division of Waste Management, Solid Waste Section (SWS), under Permit No. 50-02 issued to Jackson County. The landfill permit requires semiannual monitoring of groundwater and surface water quality. Since October 2007, when Anchor QEA of North Carolina, PLLC, began performing water quality monitoring events at the Site, groundwater quality monitoring has indicated persistent low-level concentrations of constituents that exceeded groundwater quality standards. In response to the continued exceedances of the analyzed constituents, an Assessment of Corrective Measures was submitted to the North Carolina Department of Environment and Natural Resources (now DEQ) on September 7, 2010 (Altamont 2010). A Corrective Action Plan (CAP; Altamont 2011) was implemented upon approval by the North Carolina Department of Environmental and Natural Resources, as recorded in the September 1, 2011 letter regarding "Approval of the County's Corrective Action Plan" (DENR 2011). The implemented remedy includes the extraction of leachate through dedicated submersible pumps installed within landfill gas extraction wells and disposal of the leachate into the Tuckasegee Water & Sewer Authority (TWSA) collection system. In addition to the leachate extraction, groundwater natural attenuation parameters are monitored, and natural attenuation processes are evaluated. As discussed in the CAP, a corrective action evaluation report is prepared every 5 years. The evaluation report analyzes the progress of the approved corrective action remedy based on semiannual water quality monitoring data. The remedy was implemented in a phased approach, with full implementation occurring on September 6, 2013. The first Five -Year Corrective Action Evaluation Report (CAER), submitted by Altamont on October 31, 2016 (Altamont 2016), concluded that the current conditions of the monitored natural attenuation (MNA) parameters and Site geochemical parameters allow for the slow degradation of the select contaminants identified in the CAER. The second CAER was submitted by Anchor QEA on January 13, 2022, and concluded that the leachate extraction system has improved but still does not align with the anticipated performance as modeled in the CAP. This report serves as the first semiannual water quality monitoring report for 2022. The report provides an evaluation of groundwater and surface water quality. The water quality monitoring network is presented in Figure 2. The generalized groundwater flow direction in the upper parts of the underlying aquifer system is provided in Figure 3. In addition to groundwater and surface water monitoring, this report includes analysis of the extracted leachate and two domestic water wells. The water samples collected from selected monitoring points during the spring sampling event were analyzed for a range of parameters, as presented in Section 2.2 and Table 1. The spring 2022 Spring 2022 Semiannual Water Quality Monitoring Report 1 July 2022 sampling event was performed on March 7 and 8, 2022, and is being reported in accordance with requirements stipulated in the DEQ Solid Waste Management Rules codified under Title 15A, Subchapter 13B of the North Carolina Administrative Code (NCAC). Spring 2022 Semiannual Water Quality Monitoring Report 2 July 2022 2 Semiannual Monitoring 2.1 Groundwater, Surface Water, Domestic Well, and Leachate Sampling The Site monitoring wells (MW-01, MW-02, MW-03, MW-04, MW-05R, MW-06, and MW-07), surface water sample locations (SW-01, SW-02, and SW-03), leachate sample location (LT-01), and domestic wells (DW-01 and DW-02) were sampled on March 7 and 8, 2022, by Anchor QEA. Surface water sample location, SW-03, was added during the spring 2022 sampling event following a request by DEQ to include one additional new surface water sampling location between SW-01 and SW-02 to further monitor 1,4-dioxane. The request was included in the letter to Jackson County from DEQ regarding review and approval of the Five Year Corrective Action Evaluation Report, dated February 3, 2022. Static groundwater level measurements and field parameter data are included on the sampling logs presented in Appendix A. Field equipment calibration logs for the YSI Professional Plus Multiparameter Water Quality Meter and the Hach 2100Q Turbidimeter are also provided in Appendix A. The full suite of groundwater and surface water laboratory analytical results is presented in the laboratory analysis reports in Appendix B. Monitoring wells MW-01 and MW-06 are considered to be the Site's upgradient monitoring wells; MW-03 and MW-05R are located in the midgradient portion of the Site; and MW-02, MW-04, and MW-07 monitor downgradient portions of the Site. As summarized in Table 2, the total depths of the monitoring wells range from 40 to 110 feet below ground surface. The geology of the screened intervals of the monitoring wells is as follows: • Saprolite': MW-04 and MW-05R • Partially weathered rock (PWR)Z: MW-03 • Bedrock 3: MW-01, MW-02, MW-06, and MW-07 The locations of the monitoring wells, surface water samples, leachate, and domestic well sample locations are shown in Figure 2. 2.7. 7 Monitoring Well Purging and Sampling Methods Before the monitoring wells were sampled, the static water level was gauged in each well, and an initial round of field parameters was measured (consisting of pH, specific conductivity [SC], dissolved oxygen [DO], turbidity, temperature, and oxidation reduction potential [ORP]). Saprolite is the result of in -place weathering that produces soil -like material that retains relict features of the parent rock. z PWR is generally found above the bedrock and is softer than bedrock, but not as soft as saprolite. s Bedrock is solid competent rock that underlies saprolite and partially weathered rock. Spring 2022 Semiannual Water Quality Monitoring Report 3 July 2022 Anchor QEA personnel used either low -flow techniques or disposable bailers to purge the monitoring wells and collect groundwater samples. The total depth, condition of the casing, and groundwater recharge rate determined the purging and sample collection method employed at each monitoring well. Four of the monitoring wells (MW-03, MW-04, MW-06, and MW-07) were purged using low -flow techniques in accordance with the procedures described by the U.S. Environmental Protection Agency (EPA) in Low -Flow (Minimal Drawdown) Ground -Water Sampling Procedures (EPA 1996). During purging, the field parameters (pH, SC, DO, ORP, turbidity, and temperature) were measured and recorded approximately every 3 minutes. Well purging continued until these parameters had generally stabilized for three consecutive readings. The required stabilization criteria are determined by the EPA Region 4 Science and Ecosystem Support Division in Operating Procedure: Groundwater Sampling (EPA 2017) and are summarized as follows: • pH values within ±0.1 standard unit (SU) • SC values within ±5% • Temperature, DO, and turbidity values within ±10% • ORP values within ±10 millivolts (mV) Once the parameters had stabilized, a groundwater sample was collected by field personnel wearing a new pair of nitrile gloves, using laboratory -supplied sample containers. Because of their slow recharge rates, monitoring wells MW-01, MW-02, and MW-05R were purged and sampled using disposable bailers. The wells were purged of three successive well volumes or purged dry, whichever occurred first. Monitoring well MW-02 was purged dry on March 7 and sampled on March 8, 2022, after the well had sufficient time to recharge. Monitoring well MW-05R was purged dry in the morning on March 7, 2022, and sampled later that day after the well had sufficient time to recharge. Monitoring well MW-01 was purged and sampled on March 8, 2022. A round of field parameters was measured and recorded at the start of purging and after each consecutive well volume had been purged. Field parameter data are shown in the well sampling logs included in Appendix A. 2.1.2 Surface Water Sampling Methods Surface water samples SW-01, SW-02, and SW-03 were collected on March 7, 2022, at designated locations from the Tuckasegee River, which is adjacent to and southwest of the landfill (Figure 2). Sampling location SW-01 is assumed to represent surface water quality upstream of the landfill, and sampling location SW-02 is assumed to represent surface water quality downstream of the landfill. SW-03 is assumed to represent surface water quality adjacent to the landfill. One round of field parameters was measured and recorded at each surface water sampling location immediately prior Spring 2022 Semiannual Water Quality Monitoring Report 4 July 2022 to collecting the sample (Appendix A). The surface water samples were collected in laboratory -provided sample containers by a technician wearing a new pair of nitrile gloves. 2. 7.3 Leachate Sampling Methods Dedicated bottom -loading air -powered pumps, air pressure lines, and a leachate force main collection system are installed at the landfill. Pumps are installed in landfill gas extraction wells EW-1 R, EW-2R, EW-3R, EW-4, EW-5, EW-6, EW-7, EW-8, EW-9, and EW-10. The gas extraction well locations are presented in Figure 2. The leachate is pumped from the wells into a flow equalization tank, which is connected to the TWSA wastewater collection system. The flow equalization tank is east of the landfill, adjacent to the existing landfill gas flare. A grab sample of leachate (LT-01) was acquired on March 7, 2022, by collecting a sample as the leachate entered the flow equalization tank. One round of field parameters was measured and recorded after the sample was collected (Appendix A). 2.1.4 Domestic Well Sampling Methods The domestic well water samples (DW-01 and DW-02) were collected on March 8, 2022, from an outside spigot at the residence located at 318 Joe Wilkey Road (DW-01) and 138 Joe Wilkey Road (DW-02), bordering the northern boundary of the landfill (Figure 2). The wells were purged of 30 gallons prior to sample collection. One round of field parameters was measured and recorded after the 30 gallons had been purged. The domestic well water samples were collected in laboratory -provided sample containers by field personnel wearing new nitrile gloves. 2.2 Sample Handling, Documentation, and Analysis It should be noted that during most semiannual sampling events at the Jackson County Landfill, water quality samples are submitted for Appendix I parameters only. A larger suite of Appendix II parameters are analyzed for during the fall sampling event only on a biannual basis. The larger suite was not analyzed for during the spring 2022 sampling event. Field parameters and additional observations pertaining to the Site sampling locations are provided in the sampling logs (Appendix A). Following sample collection, each groundwater, surface water, leachate, and domestic well water sample was immediately placed on ice in a sample cooler for transport to Waypoint Analytical Laboratories, a North Carolina -certified laboratory in Charlotte, North Carolina. The groundwater samples collected from the monitoring wells were analyzed for the following parameters (Table 1): • Appendix I metals, including mercury, using EPA Methods 6020B and 7470A • Appendix I volatile organic compounds (VOCs) using EPA Method 8260D Spring 2022 Semiannual Water Quality Monitoring Report 5 July 2022 • 1,4-dioxane using EPA Method 8260DSIM The surface water samples were analyzed for the following parameters: • Appendix I metals, including mercury, using EPA Methods 6020B and 7470A • Appendix I VOCs using EPA Method 8260D • 1,4-dioxane using EPA Method 8260DSIM • Hardness using SM2340C The leachate sample was analyzed for the following parameters: • Appendix I VOCs, using EPA Method 8260D • 1,4-dioxane, using EPA Method 8260DSIM • Appendix I metals using EPA Method 6020B The domestic well samples were analyzed for the following parameters: • VOCs using EPA Method 524.2 Proper chain -of -custody documentation procedures were followed during collection and transportation of each sample (Appendix B). Two trip blank samples for quality control/quality assurance purposes were included in the sample coolers and analyzed for Appendix I VOCs when applicable. The reports of the laboratory analyses are provided in Appendix B. Laboratory analyses performed on the samples are summarized in Table 1. Spring 2022 Semiannual Water Quality Monitoring Report 6 July 2022 3 Findings The field parameter data and laboratory analytical results for the groundwater samples (from monitoring wells MW-01 through MW-07), surface water samples (SW-01, SW-02, and SW-03), leachate sample (LT-01), and domestic well samples (DW-01 and DW-02) collected at the landfill are included in Appendices A and B. The results are also submitted separately to the DEQ Division of Waste Management SWS in the Electronic Data Deliverable format (DEQ 2020). The laboratory analytical results were reported and appropriately qualified as follows: • Non -Detections: Non -detections are values reported by the laboratory as less than the method detection limits (MDLs). They are tabulated in Table 3 and flagged with a "U" qualifier. The MDL is the minimum concentration of a substance that can be measured and reported by a laboratory with 99% confidence that the constituent concentration is greater than zero. • Estimated or "J" Qualified: A "Y' qualifier is used by the laboratory for parameters that are detected at estimated concentrations greater than the MDL but less than the laboratory's method reporting limit. The method reporting limit is the minimum concentration of a target analyte that can be accurately determined by the referenced method. • Groundwater Quality Standard: Detected concentrations of constituents in groundwater samples were compared to applicable North Carolina groundwater quality standards. For most constituents, this standard is defined in the 15A NCAC 2L.0202 Groundwater Standard 15A NCAC 2L.0202 (2L standard). Detected concentrations of analytes in groundwater with no established 2L standard were compared to the interim maximum allowable concentrations (IMACs) for Class GA and GSA groundwater (in accordance with 15A NCAC 02L.0202 [c]). For the purposes of this report, groundwater standards were taken from the October 15, 2018 list published by the North Carolina SWS (DEQ 2018). • 2B Standard: Detections of analytes in surface water samples were compared to the surface water quality standards defined in 15A NCAC 2B (213 standards). Hardness -dependent 2B surface water standards were calculated using the average analyzed hardness value (calculated from the upstream and downstream surface water sampling location results) via the most stringent hardness -dependent metal calculation. Table 3 summarizes detected concentrations of analytes that exceeded their respective 2L standard, IMAC, or 2B standard. 3.1 Groundwater Measured field parameters and analytical results for groundwater samples collected from the monitoring wells during the spring 2022 sampling event are discussed in the following sections and summarized in Table 3. Spring 2022 Semiannual Water Quality Monitoring Report 7 July 2022 3.7. 7 Field Parameters Field parameter measurements were obtained from all Site monitoring wells (MW-01, MW-02, MW-03, MW-04, MW-05R, MW-06, and MW-07). Field parameters are presented in Table 3 and summarized below: • pH: The pH readings ranged from 5.4 SU in MW-06 to 7.2 SU in MW-05R. Of these monitoring wells, the pH values for MW-01, MW-02, MW-04, MW-06, and MW-07 were less than the 2L standard pH range of 6.5 to 8.5 SU. The pH values for MW-03 (7.1 SU) and MW-05R (7.2 SU) were within the 2L standard pH range. • Turbidity: Turbidity ranged from 1.71 nephelometric turbidity units (NTUs) in MW-04 to > 1,000 NTU in MW-02. Generally, the higher values were measured at the monitoring wells (MW-01, MW-02, and MW-05R) that were purged and sampled using the bailer method (Section 2.1.1). The bailers were lowered gently to minimize water column disturbance when the samples were collected. • Dissolved Oxygen (DO): DO concentrations at the Site ranged from 0.80 milligram per liter (mg/L) in monitoring well MW-01 to 8.61 mg/L in monitoring well MW-03. • SC: SC concentrations at the Site ranged from 63.9 micromhos per centimeter (pmhos/cm) in monitoring well MW-06 to 829 pmhos/cm in monitoring well MW-07. • Oxidation/Reduction Potential: ORP concentrations at the Site ranged from -98.3 mV in monitoring well MW-05R to 528.4 mV in monitoring well MW-04. 3.7.2 Appendix 1 Metals (Total) Eleven metals were detected in one or more of the monitoring well samples. Three of these metals (chromium, cobalt, and vanadium) were detected at concentrations above their respective 2L water quality standards in one or more of the groundwater samples. A summary of the detections is provided below. • Chromium (21- standard of 10 pg/L): Chromium was detected in MW-02 at a concentration of 44.0 pg/L. • Cobalt (21- standard of 1 pg/L): Cobalt was detected in MW-01, MW-02, MW-03, MW-04, MW-05R, MW-06, and MW-07. Cobalt concentrations in these samples ranged from 2.12 pg/L (MW-07) to 112 pg/L (MW-01). As noted in Section 2.1, monitoring well MW-01 is considered to represent upgradient conditions. The second upgradient well (MW-06) also showed an exceedance of cobalt (15.8 pg/L). Historically, cobalt has been present at concentrations that exceeded its applicable water quality standard in groundwater samples from each of the seven monitoring wells. • Vanadium (21- standard of 7 pg/L): Vanadium was detected in MW-02 at a concentration of 53.9 pg/L. Spring 2022 Semiannual Water Quality Monitoring Report 8 July 2022 These metals have historically been present at concentrations exceeding their water quality standard in samples collected from multiple groundwater monitoring wells at the Site. 3. 7.3 Appendix I Metals (Dissolved) Laboratory -filtered analysis of Appendix I metals were performed for monitoring well samples MW-01, MW-02, MW-03, and MW-05R because of their elevated turbidity readings (17, 15.6, 14.4, and 17 NTU, respectively) during sample collection. The reported concentrations for the dissolved metals were consistently lower than the total unfiltered metals analytical results in all monitoring wells. The only exceedances for a laboratory -filtered analysis was for cobalt (Table 3). 3.1.4 Appendix I VOCs and 1,4-Dioxane Fifteen VOCs were detected in one or more of the monitoring wells (Table 3). Four of these VOCs (1,4-dioxane; benzene; vinyl chloride, and 1,4-dichlorbenzene) were detected at concentrations that exceeded their respective 2L standards in the groundwater samples collected from one or more monitoring wells. Concentration -versus -time graphs (trend plots) were created for the monitoring wells that have historically exhibited the following VOC concentrations that exceeded the associated 2L standards (Figures 4 through 10): • 1-4-dichlorobenzene (2L standard of 6 pg/L): The detected concentration of 1,4-dichlorobenzene exceeded its 2L standard in monitoring wells MW-01 (7.44 pg/L) and MW-05R (7.93 pg/L). The historical 1,4-dichlorobenzene concentration trend in MW-01 remains relatively stable (Figure 4). Historical 1,4-dichlorobenzene concentrations in MW-05R have consistently fluctuated (Figure 8). • 1,4-dioxane (21- standard of 3 pg/L): The detected concentrations of 1,4-dioxane exceeded its 2L standard in MW-02 (3.04 mg/L), MW-04 (6.29 pg/L), MW-05R (6.50 pg/L), and MW-07 (20.2 pg/L). 1,4-dioxane was not detected in monitoring wells MW-01, MW-03, or MW-06. The trend plot for 1,4-dioxane concentrations in MW-07 shows declining concentrations since sampling for this compound began in October 2018 through fall 2021 (Figure 10). The 20.2 pg/L result is the highest observed since monitoring began. • Benzene (2L standard of 1 pg/L): Benzene was detected at concentrations that exceeded its 2L standard in MW-05R (2.06 pg/L) and MW-07 (1.52 pg/L). Benzene has historically been reported with exceedances in MW-01, MW-5R, and MW-07. Overall, benzene concentrations in monitoring well MW-01 have shown a generalized downward trend since April 2007 (Figure 4) and for this sampling event it was below the 2L standard. Benzene concentrations at MW-5R have fluctuated since 2012 (Figure 8). Benzene concentrations at MW-07 have been relatively stable since 2011 (Figure 10). • Vinyl chloride (2L standard of 0.03 pg/L): The concentration of vinyl chloride in the sample collected from one monitoring well, MW-05R (1.01 pg/L), exceeded the compound's Spring 2022 Semiannual Water Quality Monitoring Report 9 July 2022 2L standard. A trend plot for vinyl chloride concentrations in MW-05R shows fluctuating concentrations (Figure 8). A review of historical groundwater data indicates the VOCs (1,4-dichlorobenzene; 1,4-dioxane; benzene; and vinyl chloride) exhibiting concentrations that exceeded the 2L standards during the spring 2022 sampling event have been detected at relatively similar concentrations for the past several years. As described in Section 3.2.3, historical surface water samples from the Tuckasegee River, which may receive discharge from the saprolite groundwater -bearing zone, have consistently shown no detections of these compounds, or other VOCs. 3.2 Surface Water The following sections summarize the measured field parameters and analytical results associated with the two surface water samples collected during the spring 2022 sampling event. 3.2.7 Field Parameters Field parameters are presented in Table 3 and summarized below: • pH: The pH readings for the upstream (SW-01), and midstream (SW-03), downstream (SW-02) surface water samples collected during the spring 2022 sampling event were 7.3, 7.6, and 7.1 SU, respectively. The pH readings for all three surface water samples were within the 2B standard range of 6.0 to 9.0 SU. • Turbidity: The turbidity values measured in SW-01 (5.47 NTU), SW-03 (5.93 NTU), and SW-02 (6.94 NTU) were less than the 2B standard, which is established at less than or equal to 50 NTU for the receiving water in streams not designated as trout waters. • DO: DO was measured at a concentration of 11.05 mg/L in SW-01, 12.79 mg/L in SW-03, and 13.05 mg/L in SW-02. The 2B standard is established as greater than or equal to 6 mg/L; thus, each sample is within the acceptable DO range. • SC: SC concentrations in surface water samples SW-01, SW-03, and SW-02 were recorded at 29.5, 26.6, 26.6 and pmhos/cm, respectively. These concentrations of SC are consistent with historical data for both surface water samples. • ORP: ORP values for SW-01, SW-03,and SW-02 were 386.4, 236.2, 190.6 mV, respectively. Compared to historical surface water samples, the concentrations of ORP for SW-01 are elevated by approximately 100 mV. The concentrations of ORP for SW-02 are consistent with historical data. 3.2.2 Appendix I Metals Seven metals were detected in three surface water sampling locations. Of these metals, concentrations of copper and lead exceeded applicable 2B standards. Copper was reported with concentrations greater than 2B standards (0.81 pg/L) in SW-1 (1.22 J pg/L) and SW-2 (1.00 J pg/L). Spring 2022 Semiannual Water Quality Monitoring Report 10 July 2022 Lead was reported with a concentration greater than NC213 (0.11 pg/L) in SW-1 (0.501 J pg/L). Lead has historically been detected above 2B standards at both the upstream and downstream sampling locations. In fall 2021, lead was a non -detect in surface water samples SW-01 and SW-02. Copper exceeded 2B standards in fall 2013 in SW-1, spring 2017 in SW-2, and spring 2019 in both surface water samples. The presence of both lead and copper in both the upstream and downstream samples suggests that the exceedance is not related to impacts from the landfill. 3.2.3 Appendix 1 VOCs and 1,4-Dioxane Acetone was the only VOC detected in the surface water samples and was also detected in similar concentrations in the trip blank sample included with the surface water samples. 3.3 Leachate Eight metals (arsenic [3.7 pg/L], barium [309 pg/L], chromium [4.7 pg/L], cobalt [6.34 pg/L], copper [2.34 pg/L], nickel [30.5 pg/L], vanadium [4.46 J pg/L], and zinc [4.29 J pg/L]) were detected in the leachate sample (LT-01). Six VOCs (1,4-dichlorobenzene [1.68 pg/L]; 1,4-dioxane [106 pg/L]; acetone [6.41 pg/L]; benzene [1.48 pg/L]; chlorobenzene [4.18 pg/L]; and tetrahydrofuran [168 pg/L]) were detected in the leachate sample (LT-01). On September 1, 2012, leachate extraction was initiated following installation of leachate extraction pumps in the 10 landfill gas extraction wells at the Site (Figure 2). Based on readings taken from the leachate totalizer during the March 2022 monitoring events, approximately 8,035 gallons of leachate were discharged through a permanent connection to the TWSA between October 20, 2021, and March 7, 2022. In fall 2013, the active portion of the approved corrective action remedy was initiated. Based on the leachate analytical results for the sample collected on March 7, 2022, Anchor QEA estimates that approximately 0.0193 pounds of VOCs were removed with the extracted leachate between the October 2021 and March 2022 sampling events. Mass removal calculations through March 2022 are included in Table 4. 3.4 Domestic Well The following sections summarize measured field parameters and analytical results associated with the domestic well water sample collected during the spring 2022 sampling event. 3.4. 7 Field Parameters The pH reading for the domestic well samples for DW-01 and DW-02 were 6.8 and 6.9 SU, respectively, which are within the 2L standard range of 6.5 to 8.5 SU. Spring 2022 Semiannual Water Quality Monitoring Report 11 July 2022 Turbidity measured in DW-01 was 11.8 NTU. DO was measured at a concentration of 4.97 mg/L in DW-01. SC and ORP values in DW-01 were recorded at 64.6 pmhos/cm and 142.1 mV, respectively. Turbidity measured in DW-02 was 3.5 NTU. DO was measured at a concentration of 12.66 mg/L in DW-02. SC and ORP values in DW-02 were recorded at 122.3 pmhos/cm and 182 mV, respectively. These parameters do not have established water quality standards. 3.4.2 VOCs No VOCs were detected at concentrations that exceeded their respective MDLs in the domestic well water samples. 3.5 Groundwater Flow Directions Groundwater levels in the saprolite, PWR, and bedrock are monitored at the Site. Three of the bedrock monitoring wells (MW-01, MW-02, and MW-06) are located in the northern and northwestern portions of the Site (Figure 3; Table 2). The fourth bedrock monitoring well (MW-07) is located southwest of the landfill (Figure 3). PWR monitoring well MW-03 and saprolite monitoring wells MW-04 and MW-05R (Figure 3) are located in the south-central and southern parts of the landfill, respectively. The spring 2022 water level data collected from the Site wells is presented in Figure 3. These data were used to determine the generalized groundwater flow direction for all aquifer zones, which is to the southwest (Figure 3). Spring 2022 Semiannual Water Quality Monitoring Report 12 July 2022 4 Summary The first semiannual water quality monitoring event of 2022 for the Site was performed on March 7 and 8, 2022. Appendices A and B and Table 3 provide detailed analytical results and field data summarizing the groundwater, surface water, and leachate quality at the landfill. 4.1 Groundwater Quality 4. 7.1 Appendix 1 Metals Three metals (chromium, cobalt, and vanadium) were detected at concentrations that exceeded their associated groundwater quality standards in one or more of the monitoring wells (Table 3). Chromium concentrations exceeded their 2L standard in MW-02. Cobalt concentrations exceeded their 2L standard in all the collected groundwater samples. Vanadium exceeded its 2L concentration in MW-02. These results are consistent with historical data. The results for groundwater samples from MW-01, MW-02, MW-03, and MW-05R, submitted for dissolved filtered metals, show consistently lower metals concentrations than the total unfiltered samples, indicating turbidity likely affects metal concentrations in these wells. 4. 7.2 Appendix 1 Volatile Organic Compounds and 1,4-Dioxane Four VOCs (1,4-dichlorobenzene; benzene; vinyl chloride; and 1,4-dioxane) were detected at concentrations that exceeded their respective 2L standards (Table 3) in one or more monitoring wells, including 1,4-dichlorobenzene, in the upgradient monitoring well MW-01. Trend plots for samples from monitoring wells that had VOC concentrations that exceeded their 2L standards (Figures 4 through 10) show relatively stable or declining concentrations with time. 4. 7.3 Field Parameters and Other Constituents Five of the seven samples collected from the monitoring wells had pH readings outside of the 2L standard range (6.5 to 8.5 SU). These results are consistent with historical data and are characteristic of the natural groundwater quality of the region. Turbidity readings ranged from 1.71 NTU (MW-04) to >1,000 NTU (MW-02). 4.2 Surface Water Quality Concentrations of copper greater than 2B standards were detected in surface water samples SW-01 (upstream) and SW-02 (downstream). Lead was detected in SW-01 at a concentration greater than its 2B standard. These metals are naturally occurring and the detections were reported for both surface water samples, suggesting that the exceedances are not associated with contamination from the landfill. The new surface water location, SW-03, which is midway between SW-01 and SW-02, did not have sample results that indicated 2B standards were exceeded. Field parameters measured in all Spring 2022 Semiannual Water Quality Monitoring Report 13 July 2022 surface water samples, including turbidity and DO, were within the 2B standards established for these parameters. The pH measured at all surface water locations were within the range of 2B standards. Based on these data, the groundwater migrating from the landfill toward the Tuckasegee River does not appear to be impacting surface water quality with regard to metals and VOCs. 4.3 Leachate Quality The leachate sample (LT-01) was collected from the flow equalization tank and analyzed for Appendix I VOCs and 1,4-dioxane. Six VOCs were detected in the leachate sample (Table 3). There are no established water quality standards for leachate. 1,4-dioxane was detected at 106 pg/L, which is higher than the detected concentrations of the compound in the monitoring well groundwater samples. This is the fourth sampling event where 1,4 dioxane was analyzed for in the leachate. 4.4 Domestic Well Water Quality No VOCs were detected at concentrations that exceeded their respective MDLs in the domestic well water samples. Spring 2022 Semiannual Water Quality Monitoring Report 14 July 2022 5 Future Activities Anchor QEA will continue to monitor the water quality on a semiannual basis at the Site. During fall 2022, domestic well owners will be contacted, and groundwater samples will be collected from domestic wells if permitted by the well owner, and if possible, based on well pump operability. Domestic well samples will be analyzed for VOCs only. Samples will be collected from the monitoring wells, surface water monitoring points, and leachate flow equalization tank during fall 2022 and spring 2023. MNA parameters were added to the monitoring requirements as part of the CAP (Altamont 2011). Approval to collect the MNA parameters on a biennial basis was provided on February 3, 2022, by DEQ (DEQ 2022). MNA parameters were collected during the fall 2021 sampling event; therefore, the next sampling event where MNA parameters will be collected is scheduled for fall 2023. The analytical suites associated with the current and future sampling events are outlined in the 2011 CAP (Altamont 2011), the first CAER (Altamont 2016), and the second CAER (Anchor QEA 2022). The upcoming sampling event parameters are as follows: Sampling Event Analytical Suite (not inclusive of natural attenuation parameters) Appendix II VOCs (including 1,4-dioxane) Appendix II Metals Fall 2022 Appendix II semivolatile organic compounds Appendix II herbicides Appendix II pesticides Appendix I VOCs (including 1,4-dioxane) Spring 2023 Appendix I Metals Spring 2022 Semiannual Water Quality Monitoring Report 15 July 2022 6 References Altamont (Altamont Environmental, Inc.), 2010. Assessment of Corrective Measures. Prepared for North Carolina Department of Environment and Natural Resources. September 7, 2010. Altamont, 2011. Corrective Action Plan. Prepared for North Carolina Department of Environment and Natural Resources. June 30, 2011. Altamont, 2016. Five -Year Corrective Action Evaluation Report. Prepared for North Carolina Department of Environmental Quality. October 31, 2016. Anchor QEA (Anchor QEA of North Carolina, PLLC), 2020. Spring 2020 Semiannual Water Quality Monitoring Report. Prepared for Jackson County Solid Waste Department. June 2020. Anchor QEA, 2022. Five -Year Corrective Action Evaluation Report. Prepared for North Carolina Department of Environmental Quality. January 13, 2022. DENR (North Carolina Department of Environmental and Natural Resources), 2011. Letter to: Altamont Environmental, Inc. Regarding: Approval of the County's Corrective Action Plan. September 1, 2011. DEQ, 2018. "Groundwater Protection Compliance Standards — Constituents List." Last modified October 15, 2018. Available at: https:Hedocs.deq.nc.gov/WasteManagement/0/edoc/l257181/SWS_EnviroMonitoring_Const ituents_List.pdf?searchid=13f8efbl -eel 1-485a-b03f-718f2287b271. DEQ, 2020. Memorandum to: Solid Waste Directors, Landfill Owners/Operators, and North Carolina Certified Laboratories. Regarding: New Electronic Data Deliverable (EDD) Format. July 20, 2020. DEQ, 2022. Letter to Jackson County from DEQ regarding review and approval of the Five -Year Corrective Action Evaluation Report. EPA (U.S. Environmental Protection Agency), 1996. Low -Flow (Minimal Drowdown) Ground -Water Sampling Procedures. Office of Land and Emergency Management, EPA/540/5-95/504. EPA, 2017. Science and Ecosystem Support Division. Operating Procedure: Groundwater Sampling. April 26, 2017. Spring 2022 Semiannual Water Quality Monitoring Report 16 July 2022 Tables Table 1 Summary of Laboratory Analyses Performed on Samples Groundwater Samples Location ID Date Collected Sample ID Appendix I VOCs 1,4-Dioxane Appendix I Metals Mercury EPA 8260D EPA 8260D SIM EPA 6020B EPA 7470A MW-01 3/8/2022 MW-01-20220308 X X X' X MW-02 3/8/2022 MW-02-20220308 X X X' X MW-03 3/8/2022 MW-03-20220308 X X X' X MW-04 3/7/2022 MW-04-20220307 X X X X MW-05R 3/7/2022 MW-05R-20220307 X X X' X MW-06 3/8/2022 MW-06-20220308 X X X X MW-07 3/7/2022 MW-07-20220307 X X X X Surface Water, Leachate, Domestic Well, and Quality Control Samples Location ID Date Collected Sample ID Appendix II VOCs 1,4-Dioxane Appendix II Metals Mercury Calcium, Magnesium, and Hardness Appendix II SVOCs VOCs EPA 8260D EPA 8260D SIM EPA 6020B EPA 7470A EPA 200.7 EPA 8270D EPA S24.2 DW-01 3/8/2022 DW-01-20220308 X DW-02 3/8/2022 DW-02-20220308 X LT-01 3/7/2022 LT-01-20220307 X X X SW-01 3/7/2022 SW-01-20220307 X X X X X X SW-02 3/7/2022 SW-02-20220307 X X X X X X SW-03 3/7/2022 SW-03-20220307 X X X X X X Trip Blank 3/7/2022 TB-20220307 X Trip Blank 3/8/2022 TB-20220308 X Domestic Well Trip Blank 3/8/2022 TB-DW-20220308 X Notes: 1: An additional sample was collected for a laboratory -filtered dissolved metals analysis. Appendix I constituents were analyzed per Title 40 Code of Federal Regulations, Part 258. Blank cell: Analysis was not performed on that sample. EPA: U.S. Environmental Protection Agency (method) SIM: selective ion monitoring TB: trip blank VOC: volatile organic compound Spring 2022 Semiannual Water Quality Monitoring Report Page 1 of 1 Jackson County Closed Municipal Solid Waste Landfill July 2022 Table 2 Well Construction Details and Corresponding Elevations Stick Up Depth to Depth to Elevation of Ground (feet Depth to Approximate Approximate Top of Bottom of Top Elevation Bottom of Surface TOC above Total Well Water Depth to Top of Bedrock Screened Screened of Screened Screened Geology of Source of Well Facility Elevation Elevation ground Depth (feet below Groundwater Bedrock Elevation Interval Interval Interval Interval Screened Construction Permit Well ID Date Drilled (feet) (feet) surface) (feet bgs) TOC) Elevation (feet) (feet bgs) (feet) (feet bgs) (feet bgs) (feet) (feet) Interval Information MW-01 4/23/1992 2,169.40 2,171.42 1 2.0 110.5 98.33 2,073.09 83.0 2,086.40 95.0 110.0 2,074.40 2,059.40 Bedrock MW-02 4/22/1992 2,013.15 2,015.38 2.3 60.7 40.14 1,975.24 13.0 2,000.15 45.0 60.0 1,968.15 1,953.15 Bedrock Partially S&ME, Inc. MW-03 4/21/1992 2,044.16 2,045.53 1.3 65.5 44.43 2,001.10 57.0 1,987.16 48.5 63.5 1,995.66 1,980.66 50-02 weathered rock MW-04 4/21/1992 1,978.68 1,980.77 2.0 43.0 25.03 1,955.74 NA NA 25.0 40.0 1,953.68 1,938.68 Saprolite MW-05R 1/26/2012 2,027.98 2,030.95 2.8 54.0 47.24 1,983.71 NA NA 44.0 54.0 1,983.98 1,973.98 Saprolite MW-06 3/23/2004 2,136.58 2,139.57 3.0 94.0 83.37 2,056.20 47.6 2,088.98 84.6 94.6 2,051.98 2,041.98 Bedrock Altamont Environmental, Inc. MW-07 7/30/2010 1,978.71 1,981.29 2.6 95.0 31.33 1,949.96 44.0 1,935.00 70.0 95.0 1,908.71 1,883.71 Bedrock Notes: Elevations associated with wells MW-01, MW-02, MW-03, MW-04, and MW-06 are measured relative to mean sea level and are based on surveying completed by Davenport & Associates, Inc. Elevations associated with wells MW-05R and MW-07 are measured relative to horizontal North American Datum 83 and are based on surveying completed by Wes Cole Land Surveying, PA. Depth to water was measured on March 7 and 8, 2022 (Appendix A). Depth to bedrock and screened interval for MW-01 through MW-04 was taken from S&ME, Inc., with boring logs completed on April 21 through 23, 1992. Depth to bedrock and screened interval for MW-06 was taken from Altamont Environmental, Inc., with boring log completed on March 23, 2004. Depth to bedrock and screened interval for MW-07 was taken from Altamont Environmental, Inc., with boring log completed on July 30, 2010. Depth to bedrock and screened interval for MW-05R was taken from Altamont Environmental, Inc., with boring log completed on January 26, 2012. Monitoring well MW-05 was abandoned on January 26, 2012, by NYEG Drilling, LLC. Monitoring well MW-05R was installed by NYEG Drilling, LLC, on January 26, 2012, as a replacement to MW-05. Monitoring well MW-05R was surveyed by Wes Cole Land Surveying, PA, on September 28, 2012. bgs: below ground surface NA: not applicable TOC: top of casing Spring 2022 Semiannual Water Quality Monitoring Report Page 1 of 1 Jackson County Closed Municipal Solid Waste Landfill July 2022 Table 3 Analytical Summary Location ID DW-01 DW-02 LT-01 MW-01 MW-02 MW-03 MW-04 MW-0511 MW-06 MW-07 SW-01 SW-02 SW-03 FieldQC FieIdQC FieIdQC Sample ID DW-01- 20220308 DW-02- 20220308 LT-01- 20220307 MW-01- 20220308 MW-02- 20220308 MW-03- 20220308 MW-04- 20220307 MW-OSR- 20220307 MW-06- 20220308 MW-07- 20220307 SW-01- 20220307 SW-02- 20220307 SW-03- 20220307 TB-20220307 TB-20220308 TB-DW- 20220308 Sample Date 3/8/2022 3/8/2022 3/7/2022 3/8/2022 3/8/2022 3/8/2022 3/7/2022 3/7/2022 3/8/2022 3/7/2022 3/7/2022 3/7/2022 3/7/2022 3/7/2022 3/8/2022 3/8/2022 Sample Type N N N N N N N N N N N N N TB TB N Matrix WG WG WG WG WG WG WG WG WG WG WS WS WS WQ WQ WG NC2L NC21- IMAC NC 2B Chemical Method (2022) (2022) (2021) Conventional Parameters Water level depth (feet) Field -- -- -- -- -- -- 98.33 40.14 44.43 25.03 47.24 83.37 31.33 -- -- -- Temperature (°C) Field -- 14.6 13.2 13.9 17.0 15.6 14.4 15.6 17.0 14.8 16.8 11.7 12.3 12.4 Dissolved oxygen (field) Field >_6 4.97 12.66 3.80 0.80 4.18 8.61 1.27 1.80 1.57 1.04 11.05 13.05 12.79 Specific conductivity (field) Field -- 64.6 122.3 5322 214.8 216.9 401.4 589.2 661 63.9 829 29.5 26.6 26.6 H (SU) Field 6.5-8.5 6.0-9.0 6.8 6.9 8.1 J 5.9 6.2 7.1 5.7 7.2 5.4 6.1 7.3 7.1 7.6 ORP (mV) Field -- 142.1 182 168.1 -2.1 163.8 220.2 528.4 -98.3 278.5 152.6 386.4 190.6 236.2 Turbidity (NTU) Field <10 11.8 3.5 7.59 11.0 >1000 10.3 1.71 37.7 J 5.16 6.3 55.47 6.94 5.93 -- Hardness as Ca and Mg (nncj SM2340C I -- I I - - 9 1 6 1 6 Metals (pg/L) Arsenic SW6020 10 10 3.70 0.490 U 6.36 0.663 J 0.490 U 0.490 U 0.490 U 0.490 U 0.490 U 0.490 U 0.490 U Barium SW6020 700 21000 309 113 222 120 67.6 119 46.8 405 20.6 18.6 13.9 Cadmium SW6020 2 *0.05 0.150 U 0.687 J 0.750 U 0.150 U 0.370 J 0.150 U 0.150 U 0.150 U 0.750 U 0.750 U 0.750 U Chromium SW6020 10 *7.40 4.70 1.21 J 44.0 1.75 J 1.00 U 1.00 U 1.00 U 1.00 U 1.52 J 1.36 J 1.00 U Cobalt SW6020 1 1.6 6.34 112 40.4 2.82 2.99 12.7 15.8 2.12 0.595 J 0.460 J 0.200 J Copper SW6020 1000 *0.81 2.34 3.25 47.9 4.12 0.890 U 0.890 U 0.906 J 0.890 U 1.22 J 1.00 J 0.890 U Lead SW6020 15 *0.11 0.500 U 0.500 U 11.5 0.500 U 0.500 U 0.500 U 0.500 U 0.500 U 0.501 J 0.500 U 0.500 U Mercury SW7470 1 0.12 0.0700 U 0.0700 U 0.0700 U 0.0700 U 0.120 J 0.0700 U 0.130 J 0.0700 U 0.0700 U 0.0700 U 0.0700 U Nickel SW6020 100 *4.81 30.5 15.3 33.7 1.77 J 2.07 2.65 4.93 7.92 1.59 J 0.720 U 0.720 U Thallium SW6020 2 2 0.280 U 0.553 J 1.40 U 0.280 U 0.280 U 0.280 U 0.308 J 0.280 U 0.280 U 0.280 U 0.280 U Vanadium SW6020 7 -- 4.46 J 2.10 U 53.9 2.70 U 2.70 U 2.70 U 2.70 U 2.70 U 3.02 J 2.64 J 2.11 J Zinc SW6020 1000 *10.8 4.29 J 37.5 102 5.68 J 5.39 J 3.90 U 16.5 J 7.69 J 3.90 U 3.90 U 3.90 U Metals Dissolved L Barium SW6020 700 21000 -- 108 34.6 112 -- 81.8 -- -- -- -- -- Cobalt SW6020 1 1.6 106 9.49 0.14 J 11.3 Copper SW6020 1000 *0.81 0.890 U 0.890 U 1.96 J 0.890 U Nickel SW6020 100 *4.81 13.8 7.11 0.744 J 2.25 J Thallium SW6020 2 2 0.717 J 0.280 U 0.280 U 0.280 U Zinc SW6020 1000 *10.80 15.2 J 3.90 U 3.90 U 3.90 U Spring 2022 Semiannual Water Quality Monitoring Report 1 of 2 Jackson County Closed Municipal Solid Waste Landfill July 2022 Table 3 Analytical Summary Location ID DW-01 DW-02 LT-01 MW-01 MW-02 MW-03 MW-04 MW-05R MW-06 MW-07 SW-01 SW-02 SW-03 FieldQC FieIdQC FieIdQC SamplelD DW-01- 20220308 DW-02- 20220308 LT-01- 20220307 MW-01- 20220308 MW-02- 20220308 MW-03- 20220308 MW-04- 20220307 MW-0511- 20220307 MW-06- 20220308 MW-07- 20220307 SW-01- 20220307 SW-02- 20220307 SW-03- 20220307 TB-20220307 TB-20220308 TB-DW- 20220308 Sample Date 3/8/2022 3/8/2022 3/7/2022 3/8/2022 3/8/2022 3/8/2022 3/7/2022 3/7/2022 3/8/2022 3/7/2022 3/7/2022 3/7/2022 3/7/2022 3/7/2022 3/8/2022 3/8/2022 Sample Type N N N N N N N N N N N N N TB TB N Matrix WG WG WG WG WG WG WG WG WG WG WS WS WS WQ WQ WG NC2L IMAC NC 2B Chemical Method (2022) (2022) (2021) Volatile Or anics L 1,1-Dichloroethane SW8260 6 100 0.240 U 1.80 0.348 J 0.240 U 0.240 U 0.240 U 0.977 0.240 U 0.240 U 0.240 U 0.240 U 0.240 U 0.240 U 0.00050 U 1,2-Dichloroethene, cis- SW8260 70 720 0.00050 U 0.00050 U 0.200 U 2.17 0.200 U 0.200 U 0.645 1.88 0.942 1.89 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U 0.00050 U 1,4-Dioxane SW8260SIM 3 80 106 0.139 U 3.04 0.139 U 6.29 6.50 0.139 U 20.2 0.139 U 0.139 U 0.139 U Acetone SW8260 6000 2000 6.41 3.07 J 2.73 J 3.08 J 2.41 J 2.36 J 3.55 J 1.80 U 2.01 J 2.06 J 2.12 J 1.80 U 1.80 U Benzene SW8260 1 51 0.00050 U 0.00050 U 1.48 0.721 0.180 U 0.180 U 0.226 J 2.06 0.180 U 1.52 0.180 U 0.180 U 0.180 U 0.180 U 0.180 U 0.00050 U Chlorobenzene SW8260 50 800 0.00050 U 0.00050 U 4.18 0.190 U 0.190 U 0.190 U 0.190 U 8.04 0.190 U 4.47 0.190 U 0.190 U 0.190 U 0.190 U 0.190 U 0.00050 U Chloroethane SW8260 3000 0.430 U 0.430 U 0.430 U 0.430 U 0.430 U 0.505 J 0.430 U 0.430 U 0.430 U 0.430 U 0.430 U 0.430 U 0.430 U Methylene Chloride SW8260 0.0010 U 0.0010 U 0.330 U 0.330 U 0.330 U 0.330 U 0.330 U 0.330 U 0.330 U 0.330 U 0.330 U 0.330 U 0.330 U 0.330 U 0.330 U 0.0032 m, -X lene SW8260 500 130 0.420 U 0.420 U 0.420 U 0.420 U 0.420 U 0.420 U 0.548 J 0.420 U 0.420 U 0.420 U 0.420 U 0.420 U 0.420 U Tetrachloroethene (PCE) SW8260 0.7 3.3 0.00050 U 0.00050 U 0.220 U 0.390 J 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U 0.00050 U Tetrah drofuran SW8260 2000 110000 168 1.50 U 1.50 U 1.50 U 1.50 U 2.28 J 1.50 U 1.50 U 1.50 U 1.50 U 1.50 U 1.50 U 1.50 U Total X lene SW8260 500 450 0.0010 U 0.0010 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.548 J 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.0010 U Trichloroethene (TCE) SW8260 3 30 0.00050 U 0.00050 U 0.180 U 0.350 J 0.180 U 0.180 U 0.180 U 0.180 U 0.180 U 0.180 U 0.180 U 0.180 U 0.180 U 0.180 U 0.180 U 0.00050 U Vinyl chloride SW8260 0.03 2.4 0.00050 U 0.00050 U 0.770 U 0.770 U 0.770 U 0.770 U 0.770 U 1.01 0.770 U 0.770 U 0.170 U 0.170 U 0.170 U 0.170 U 0.170 U 0.00050 U 1,2-Dichlorobenzene SW8270 20 79 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U 0.335 J 0.220 U 0.304 J 0.220 U 0.220 U 0.220 U 1,4-Dichlorobenzene SW8267 6 56 1.68 7.44 0.210 U 0.210 U 2.20 7.93 1.41 5.54 0.210 U 0.210 U 0.210 U Notes: indicates the detected concentration is greater than the NC21L (2022) or NC2L IMAC (2022) screening level. indicates the detected concentration is greater than the NC215 (2021) screening level. Bold indicates a detected result. Italicized indicates non -detected concentration is above one or more identified screening levels *: 2B surface water standard calculated using average analyzed hardness value (calculated from the upstream and downstream sampling location results) via the most stringent hardness -dependent metal calculation per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B - Surface Water and Wetland Standards (last amended September 2017). All nondetect results are reported at the method detection limit. Horizontal coordinate datum is North American Datum of 1983 State Plane North Carolina FIPS 3200 (US Survev Feet). --: compound not analyzed for the sample ug/L: micrograms per liter 2B: surface water standard per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B - Surface Water and Wetland Standards (last amended in June 2022) or the standard obtained from the U.S. Environmental Protection Agency Nationally Recommended Water Quality Criteria for Aquatic Life and Human Health 2L: Subchapter 2L - Groundwater Classifications and Standards, Department of Environmental Quality (Amended April 1, 2022); groundwater standard from North Carolina Administrative Code, Title 15A IMAC: interim maximum allowable concentration (listed in 2L Appendix 1) J: estimated value mg/L: milligrams per liter mV: millivolts N: normal environmental sample NTU: nephelometric turbidity unit ORP: oxidation reduction potential PCE: perch loroethylene SM: Standard Method su: standard units TB: trip blank U: compound analyzed for but not detected above detection limit umhos/cm: microsiemens per centimeter Spring 2022 Semiannual Water Quality Monitoring Report 2 of 2 Jackson County Closed Municipal Solid Waste Landfill July 2022 Table 4 Mass Removal Calculations for VOCs Detected in the Leachate Sample (LT-01) Sample Dates Detected VOCs cuncen- tration in LT-01 (mg/L) Cumulative Flow at Gauge (gal) Differential Flow (gal) Mass Removed (lb) Estimated Cumulative Mass Removed (lb) Beginning Ending 9/1/2012 10/25/2012 1,4-dichlorobenzene 0.0034 11,500 J J J J 1 11,500 0.00033 4-meth I-2- entanone (MIBK) 0.0021 0.00020 Acetone 0.0292 0.00280 Benzene 0.0021 0.00020 Chlorobenzene 0.0029 0.00028 cis- 1,2-dichloroethene 0.00063 0.00006 Dichlorodifluoro-methane 0.00093 0.00009 Eth (benzene 0.0102 0.00098 Naphthalene 10.0069 0.00066 Styrene 10.00033 0.00003 Toluene 10.003 0.00029 Total x lenes 10.0094 1 0.00090 Total: 0.00681 0.00681 10/26/2012 4/11/2013 1,4-dichlorobenzene 0.006 65,500 J J J J 54,000 0.00270 Acetone 0.012 0.00540 Benzene 0.0011 0.00049 Carbon disulfide 0.0067 0.00301 Chlorobenzene 0.0024 0.00108 cis- 1,2-dichloroethene 0.00058 IJI 0.00026 Eth (benzene 0.0083 0.00373 Toluene 0.00059 0.00027 Total x lenes 0.0078 0.00351 Total: 0.02045 0.02726 4/12/2013 10/8/2013 1,4-dichlorobenzene 0.0055 114,737 J J 49,237 0.00226 4-meth I-2- entanone (MIBK) 0.0012 0.00049 Benzene 0.0020 0.00082 Chlorobenzene 0.0039 0.00160 cis- 1,2-dichloroethene 0.00080 0.00033 Eth (benzene 0.0151 0.00619 Naphthalene 10.0184 0.00754 Toluene 10.0012 0.00049 Total x lenes 10.0090 0.00369 Total: 0.02341 0.05067 10/9/2013 4 8 2014' 1,4-dichlorobenzene 0.0056 164,437 J J J 49,700 0.00232 Benzene 0.0018 0.00075 Chlorobenzene 0.0051 0.00211 cis- 1,2-dichloroethene 0.00049 0.00020 Eth (benzene 0.0047 0.00195 Toluene 10.00041 0.00017 Total x lenes 10.0021 0.00087 Total: 0.00836 0.05903 4/8/2014 10 23 2014' 1,4-dichlorobenzene 0.0053 200,148 J J J 35,710 0.00158 Benzene 0.0014 0.00042 Chlorobenzene 0.003 0.00089 cis- 1,2-dichloroethene 0.00049 0.00015 Eth (benzene 0.0027 0.00080 Toluene 0.00051 0.00015 Total x lenes 0.0014 0.00042 Total: 0.00440 0.06343 10/23/2014 4/21/2015 1,2,3-trimethyl benzene 0.00062 241,700 J J 41,552 0.00021 1,2,4-trimethyl benzene 0.00076 2-chlorotoluene 0.00067 1,4-dichlorobenzene 0.0059 Acetone 0.00790 Benzene 0.0022 0.00076 Chlorobenzene 0.003 4 Eth (benzene 0.0056 _U77947- Isopropylbenzene 0.0013 45 Methy tert-but I -ether 0.0013 0.00045 Na thalene 0.024 n-propylbenzene 0.00088 Tetrah drofuran 0.089 Toluene 0.00054 Vin I chloride 10.00038 Total x lenes 10.0030 4 Total: 0.05089 UTRM 4/21/2015 10/13/2015 1,4-dichlorobenzene 0.00600 278,420 J 36,720 0.00183 2-butanone 0.00960 0.00294 Benzene 0.00210 0.00064 Chlorobenzene 0.0040 0.00122 Eth (benzene 0.00710 0.00217 Naphthalene 0.021 0.00642 Tetrah drofuran 0.062 0.01896 Toluene 0.00058 fJ 0.00018 Total x lenes 0.0031 0.00095 Total: 0.03531 0.14963 10/13/2015 4/5/2016 1,4-dichlorobenzene 0.00590 337,398 J 58,978 0.00290 Benzene 0.00170 0.00083 Chlorobenzene 0.0038 0.00187 Eth (benzene 0.00500 0.00246 Toluene 0.00063 0.00031 Total x lenes 10.0025 1.11 0.00123 Total: 0.00959 0.15922 4/5/2016 10 11 20162 No detected compounds 352,745 15,347 0.00000 Total:j 0.00000 1 0.15922 Spring 2022 Semiannual Water Quality Monitoring Report Page 1 of 3 Jackson County Closed Municipal Solid Waste Landfill July 2022 Table 4 Mass Removal Calculations for VOCs Detected in the Leachate Sample (LT-01) Sample Dates Detected VOCs cuncen- tration in LT-01 (mg/L) Cumulative Flow at Gauge (gal) Differential Flow (gal) Mass Removed (lb) Estimated Cumulative Mass Removed (lb) Beginning Ending 10/11/2016 3/21/2017 1,4-dichlorobenzene 0.0046 355,947 3,202 0.00012 Acetone 0.0094 J 0.00025 Benzene 0.0015 0.00004 Chlorobenzene 0.0043 0.00011 Eth (benzene 10.0014 0.00004 Tetrah drofuran 10.066 0.00176 Total x lenes 0.0015 Hi 0.00004 Total: 0.00237 0.16159 3/21/2017 10/11/2017 1,4-dichlorobenzene 0.0041 386,495 30,548 0.00104 Acetone 0.0067 J J 0. 0 0 7 Acetonitrile 0.008 4 Benzene 0.00061 Chlorobenzene 10.0012 Eth (benzene 10.00087 Naphthalene 10.0012 Tetrah drofuran 10.12 5 Total: 0.03630 0.19789 10/12/2017 10 18 20183 1,4-dichlorobenzene 0.0028 398,872 12,377 0.00029 Acetone 0.017 J 0.00175 Benzene 0.0012 0.00012 Chlorobenzene 0.0024 0.00025 Eth (benzene 10.0018 1 0.00019 Methylene chloride 10.00034 0.00004 Total x lenes 10.00098 jil 0.00010 Total: 0.0027 0.20062 10/18/2018 10 22 20193 1,4-dichlorobenzene 0.0037 407,807 8,936 0.00028 Acetone 0.006 J J 0.00045 Benzene 0.0017 0.00013 Chlorobenzene 0.0038 0.00028 Eth (benzene 0.0016 0.00012 Toluene 10.00039 0.00003 Total x lenes 10.0017 0.00013 Total: 0.0014 0.20203 10/22/2019 3 18 20203 1,4-dichlorobenzene 0.0056 539,644 131,836 0.00615 1,4-dioxane 0.06 J J 0.06585 Acetone 0.0064 0.00702 Benzene 0.0013 0.00143 Chlorobenzene 0.0032 1 0.00351 Eth (benzene 0.0027 0.00296 Methyl isobutyl ketone 0.00079 0.00087 Toluene 0.00070 0.00077 Total x lenes 10.00209 0.00229 Total: 0.0886 0.29058 3/18/2020 10 14 20203 1,2-dichloroethene, cis- 0.00029 J 639,343 99,699 0.00024 1,3-dichlorobenzene 0.00027 J J J H 0.00022 1,4-dichlorobenzene 0.0048 0.00398 1,4-dioxane 0.058 0.04814 Acetone 0.011 1 0.00913 Acetonitri a (et anenitri e) 0.0047 0.00390 Benzene 0.0024 0.00199 Chlorobenzene 0.0044 0.00365 Chloroethane 0.00047 0.00039 Eth (benzene 0.0018 0.00149 Naphthalene 0.013 0.01079 Tetrah drofuran 0.094 0.07802 Toluene 0.00079 0.00066 Total x lenes 0.0037 0.00307 Vin I chloride 10.00022 0.00018 Total: 0.1659 0.45645 10 14 20204 10/20/2021 1,4-dichlorobenzene 0.00385 701,994 62,651 0.00201 1,4-dioxane 4 54 Acetone 4 0.00425 Benzene TMT45 0.00128 Chlorobenzene 0.00428 Eth (benzene 0.000838 MGM-4 Naphthalene0.00710 Tetrah drofuran T 5 Total x lenes 47 Total: 0.1501 0.60659 10/20/2021 3/7/2022 1,4-dichlorobenzene 0.00168 710,029 8,035 0.00011 1,4-dioxane 0.106 0.00709 Acetone 0.00641 0.00043 Benzene 0.00148 0.00010 Chlorobenzene 0.00418 0.00028 Tetra hyd rofu ra n 0.168 0.01124 Total: 0.0193 0.62584 Notes: Total xylenes represent the sum of m,p-xylenes and o-xylenes. Only detected VOCs in leachate sample LT-01 are included in the mass removal calculation. Leachate extraction at the landfill was initiated on September 1, 2012. Connection to the TWSA sewer was completed on September 6, 2013. Up until the connection to the TWSA sewer, leachate was pumped into a temporary collection tank and then hauled off site. Extraction volume measurements for leachate hauled off site were recorded and provided by Jackson Countv staff. Anchor QEA bases mass removal calculations on the assumption that the VOCs concentration in one sampling event is representative of leachate quality until the next sampling event occurs and that the leachate removal system has a 100% removal and treatment efficiencv. Spring 2022 Semiannual Water Quality Monitoring Report Page 2 of 3 Jackson County Closed Municipal Solid Waste Landfill July 2022 Table 4 Mass Removal Calculations for VOCs Detected in the Leachate Sample (LT-01) Loncen- tration in Cumulative Mass Sample Dates LT-01 Flow at Gauge Differential Removed Estimated Cumulative Detected VOCs (mg/L) (gal) Flow (gal) (lb) Mass Removed (lb) Beginning Ending Differential flow represents the total flow between the LT-01 sample dates. Estimated cumulative mass removed and treated is estimated based upon a conversion of milligrams to pounds and liters to gallons and the multiplication of the concentration 1. Totalizer readings were not recorded during the sampling event, and the differential flow was calculated based on an interpolated totalizer reading using monthly readings taken by TWSA for 3 months before and after the sample date. 2. No VOCs were detected in the leachate sample collected during the October 2016 sampling event. 3. In March 2018, the totalizer at the TWSA connection was replaced. During the March 2018 sampling event, Anchor QEA began reading an incorrect totalizer for the volume of extracted the leachate. Differential flow was calculated for the sample dates in the same manner as Note 1. This table has been updated to reflect the updated totalizer readings from previous groundwater monitoring reports. 4. Totalizer buried during March 2021 monitoring event, due to on -Site construction. Therefore a totalizer reading was not obtained. gal: gallon J: indicates laboratory estimated concentration is above the adjusted method detection limit and below the adjusted reporting limit lb: pound mg/L: milligrams per liter TWSA: Tuckaseigee Water and Sewer Authority VOC: volatile organic compound Spring 2022 Semiannual Water Quality Monitoring Report Page 3 of 3 Jackson County Closed Municipal Solid Waste Landfill July 2022 Figures Z. d nr CFO I t _ X R r -41 14 {�;� .. `.� Y : #'`�-� rid ii 2 • � ~, I f' mil} '� � � - -'� � til.• O 'J--. 1� - - 1 � i . h _ I ..'1 I .' �- _ � 1 ��; ;ram � =�i.r� • � �_' Yf .ram' � f ��• t - LEGEND: SOURCES: 1. BasemaU.S. Geological Survey Topographic ® Site Parcel Boundary Maps - Gree ens Creek and Whittier 7.5-minute Quadrangles 0 2. Parcel. Jackson County GIS 0 2,000 Feet Publish Date: 2022/04/22, 3:58 PM I User: kpressleybernal Filepath: Q:\Jobs\JacksonCounty_NC_1480\Maps\2022\Spring WQWQ_Fig01_JacksonCounty_SpringWQ2022_Sitel-ocationMap.nnxcl kzANCHOR Figure 1 QEA Site Location Map Anchor QEA of North Carolina, PLLC Spring 2022 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill LEGEND: DW-02 Saprolite Monitoring Well ® PWR Monitoring Well ® Bedrock Monitoring Well Domestic Well Sampling Location Leachate Sample Location and Flow Equalization Tank ® Surface Water Sample Location + Leachate/Landfill Gas Extraction Well Compliance Boundary SW-02 F� • • • Edge of Waste a — Stream Q Property Boundary MW-06 — Road ® MW-01 DW 01 — Elevation Contour (20-Foot Interval) woo ` EW-7 ` EW-5 MW-02 1 EW-3111 ® ` EW 1R. v` EW-9�� ••�� EW-2R ••' ` EW-10 ♦� ,` ZQ Rio �pQ� � ZZ MW-03 ; • '• LT-01 NOTES: O • SW-03 ® EW-4 1.Contours, roads, and parcel boundaries are • from Jackson County GIS. /rPc�i •.•• i 2. Monitoring well locations are approximate. 012 ` '•, 3. Basemap provided by Esri. ` 4. PWR: Partially Weathered Rock �6 -A MW-OSR100, , MW-07 (N MW-04 � I Publish Date: 2022/06/01, 2:56 PM I User: kpressleybernal Filepath: Q:\Jobs\JacksonCounty_NC_1480\Maps\2022\Spring WQ\AQ_Fig02_JacksonCounty_SpringWQ2022_SampleLocationMap.mxd kZANCHOR QEA Anchor QEA of North Carolina, PLLC SW-01 L - �pOO y0 APR 0 300 Feet Figure 2 Site Layout Map Spring 2022 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill ilm.1106"6.14) 060 2 V 2 �♦ `� `� ♦ ♦ 2�Qo ` / ♦ `� ♦♦ ♦♦ ` -10 2020` ♦ O •` 0 ♦ ♦ �41 MW`03 •: ` 10 . ` �° s' -� (2 0001%6,1) POD 012 C9 4�° �980 nib �,9, ` ` ` ` •., ` '. ` ♦ ` % ` 7960`. • •MW-05 MW-07 (1,949.41) ( Q�7 MW-04 (1,955.32) Publish Date: 2022/06/29, 10:19 AM I User: kpressleybernal Filepath: Q:\Jobs\JacksonCounty_NC_1480\Maps\2022\Spring WQ\AQ_Fig03_JacksonCounty_SpringWQ2022_GroundwaterElevationMap.mxd kZANCHOR QEA e� 1) LEGEND: ® Saprolite Monitoring Well ® PWR Monitoring Well Bedrock Monitoring Well Generalized Groundwater Elevation Contour (10-Foot Interval) ■Leachate Sample Location and Flow Equalization Tank • • • • Edge of Waste — Stream QProperty Boundary Road Elevation Contour (20-Foot Interval) NOTES: 1.Contours, roads, and parcel boundaries are from Jackson County GIS. 2. Monitoring well locations are approximate. 3. Groundwater elevations and flow direction are updated on a semiannual basis every April and October following the sample collection events. 4. Groundwater flow direction is based on groundwater elevations in feet in monitoring wells MW-01, MW-02, MW-03, MW-04, MW- 05R, MW-06, and MW-07. Direction is calculated based on depth to water measured on March 7 and 8, 2022. 5. Last names of property owners are shown in parcels that border the landfill property. 6. GW: Groundwater 7. PWR: Partially Weathered Rock 0 0 200 Feet Figure 3 Generalized Groundwater Flow Direction Spring 2022 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill Appendix A Well Sampling Logs, and Equipment Documentation and Instrument Calibration Data Sheets ANCHOR kL QEA Anchor QEA Of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Well Sampling Log IWO ID: MW-01 Project Name: Jackson County Landfill Date: 0 Project Number. C11480-01.02 Weather: S d Project Location: Dillsboro, NC Facility ID or Permit # (if applicable): 50-02 Sample Collector(s): Sample ID (on COC): MW-01- t%aZ G�G S Well Diameter. 2 in Sample Time: Screen Interval: N/A ft bgs Measuring Point: TOC Well Depth (WD): 110.5 ft TOC Well Type: AStick Up ❑Flush Mount Water Level in Feet (WL): 4 Jv 3 ft TOC Comments: ; ' Length of Water Column (LWC): ft; (WD - WL) One Casing Volume: ,�� gallons; (LWC x WCV) Three Casing Volumes: �f �(� gallons Actual Volume Purged: 1 no gallons Tagged Bottom: I I - t I ft at (time): j'Aso Three Casing Volumes: gallons Well Casing Volumes (WCV) 1" = 0.04 Gal/Ft 2" = 0.16 Gal/F 3" = 0.37 Gal/Ft 4" = 0.65 Gal/Ft 6" = 1.47 Gal/Ft 8" = 2.61 Gal/Ft 12" = 5.87 Gal/Ft Purge Method: Bailer-Dis Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other: Bailer-Dis Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other. Sample Method: Oxidation Dissolved Specific pH (S.U.) Reduction Gallons Temperature Oxygen Conductivity reportto 0.1 Potential Turbidity Reading Time Purged VQ (mg/L) (pmhos/cm) S.U. (m1) (NTU) Comments 1 12 ui 0725- i7, 6 3 5 I1 i - ,»t- I�i 4 17 J n r n 3r�( - �T = 5 i Lam. 6 7 8 9 10 Sampling Container I Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic em IS 125 mL Plastic 40 mL Glass QS 1 L Glass Other Protective Casing:_ Pad: Lock: vegetation:_ Access: Sample Analysts ^ Signature: f, g 1 Sample Analysts Cam/ t f p p [� l � A Date: 03 pf Name: '<0LI as Notes: 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% and turbidity, +/- 3% Conductivity, +/- 0.7 pH unit; +/- mV forORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 ,ter, I I� � C) )O� UAW (, Abbreviations: Method Reference: 1 fil.v t— eddo °C: degrees Celsius S.U.: standard units Temperature: SM 2550 B-2010 r t� v' pmhos/cm: micromhos per centimeter ft: feet Specific conductivity: EPA Method 120.1, Rev. 1982 �vc mg/L: milligrams per liter in: inches DO: SM 4500 O G-2011 mV: millivolt bgs: below ground surface pH: SM 4500-11' B-2011 11 NTU: nephelometric turbidity units TOC: top of casing Turbidity: SM 2130 B-,2{0S� e L ` L�'3 (- 1 Page 1 of 1 ton ia, l �`' - J �e �Y rc c I`w ov uI/� � ��1 MD C CaVyl�t%' GL ( JCrv`niyu SJct b r r�h� 531oiu .- ANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Well Sampling Log Well ID: MW-02 Project Name: Jackson County Landfill Date: 1 3 _1 al' Project Number. C11480-01.02 Weather. SVIZ f Project Location: Dillsboro, NC Facility ID or Permit # (if applicable): 50-02 Sample Collector(s): S G/ K- P Sample ID (on COQ: MW-02-�,6,a -A O�d� Well Diameter. 2 in Sample Time: I D 0 Screen Interval: N/A ft bgs Measuring Point TOC Well Depth (WD): 60.7 ft TOC Well Type: AStick Up ❑Flush Mount Water Level in Feet (WL): r-10 , 1 1 ft TOC Comments: Length of Water Column (LWQ: C90 , S( 0ft; (WD - WL) One Casing Volume: �j, ' +�F gallons; (LWC x WCV) Three Casing Volumes: , gallons Lit)Ls Actual Volume Purged: fl gallons Tagged Bottom: (pa at (time): Three Casing Volumes: gallons 1fi Well Casing Volumes (WCV) 1" = 0.04 Gal/Ft 2" = 0.16 Gal/Ft 3" = 0.37 Gal/Ft 4" = 0.65 Gal/Ft 6" = 1.47 Gal/Ft 8" = 2.61 Gal/Ft 12" = 5.87 Gal/Ft Purge Method: rBailer-Disp. Bailer -Teflon Dedicated Pump Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Whale Pump Grundfos Other. Other. Sample Method: Oxidation Dissolved Specific pH (S.U.) Reduction Gallons Temperature Oxygen Conductivity reportto 0.1 Potential Turbidity Reading Time Purged CQ (mg/L) (Nmhos/cm) S.U. (m1) (NTU) Comments 0 36 o, �s tr ; , i 1 /TO, 7 6:z,o y 66 2 Del'-'7 /�5 . Z 6 I go, S. 9 3-.7, 3 0 3 OF's-'q � D ! , y a 17, Z 2- 4 ©y�7 ? ! S-- c� / 22�y, O 4,,o ,570..5- ?& S- 5 U` ql 1J r oA. 70 i ci .3 3-5/, 6 — o. _ 9L* 6 1S)40 1 169 q. 1F wto - ti, iZ 7 8 9 10 Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic /ljj Q y�y [ , L k.;, r" tr r. i 125 mL Plastic 40 mL Glass O-i d 92-60 1 L Glass Other Protective Casing: K Pad: Qk'_ Lock: W_ Vegetation: t*- Access: DA:� Sample Analysts � Sample Analysts Signature. �� Date: �� Name: Notes: ' 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity,, +/- 3% Conductivity, +/- 0.1 pH unit; +/- 70 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation errors are to be crossed out with a single line, so the original tent is still legible, followed by the staff members initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 Abbreviations: °C: degrees Celsius S.U.: standard units ymhos/cm: micromhos per centimeter ft: feet mg/L milligrams per liter in: inches mv: millivolt bgs: below ground surface NTU: nephelometric turbidity units TOC: top of casing Method Reference: Temperature: SM 2550 B-2010 Specific conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 0 G-2011 pH: SM 4500-H' B-2011 Turbidity: SM 2130 B-2011 Page 1 of 1 ,� ANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 `.ow -Flow Sampling Log Poll ID: MW-03 Project Name: Jackson County Landfill Project Number: C11480-01.02 Project Location: Dillsboro, NC Sample Collector(s): S Well Diameter: 2 Screen Interval: 48.5-63.5 Well Depth (as constructed): 65.5 Depth to Water. r1K +3 Measuring Point: TOC Depth of Pump Intake: 50 Pump Used (circle): Peristaltic Bladder Comments: ICFOSee12: 5�C{d-RilEF99CCp: Date: h I Gp f 'A 0% � Weather.' Facility ID or Permit # (if applicable): 50-02 Sample ID (on COQ: MW-03- 204a PAID in Arrive at Well: Z ft bgs Start Time: 01JI it bgs Sample Time: rr ft Leave Well: Well Type: XStick Up ❑Flush Mount it Tagged Bottom: p� , ft at (time): b a' Other (describe): Purge Rate: / SJ 6 in (a) t)!q L� Total Volume Purged: �Of�U C�} —I,-" Pump Speed: L I U 1 � } Time DTW (feet) Temperature (°C) Dissolved Oxygen (mg/L) Specific Conductivity (pmhos/cm) pH (S.U.) report to 0.1 S.U. Oxidation Reduction Potential (mV) Turbidity (NTU) ©q I , f l `1 O y o3, S- v 2-q1: p q.1Z ., 93 / `I.1 il, YS 40J.1 �'. l Z73 Is -"I oq). `-i,93 f :3 7d- 1--(oa.S 9, Z, �: y 1y. if o %).9 1'fly 61 `-6o!r7 ? Y 3,rr (09 1 `11,13 t '' q S,qo -fOr, T___j7, 23Y I'! 7 0 1 !,?qlU H , y,o2r0 S'.S 2- "1 037 f, i , y 9, '�' yo(, ;L FIS Zz6, 9 9,61 `l(9(r ZZU Z 10- Sample Analyst Signature:' - Sample Analyst Name: i Mfw Date: �y i Notes: w 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity,' +/- 3% Conductivity; +/- 0.7 pH unit; +/- 70 mV (or ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 5. 1 pmho/cm = 1 pS/cm Abbreviations: Method Reference: 'C: degrees Celsius S.U: standard units Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter ft: feet Specific conductivity: EPA Method 120.1, Rev. 1982 mg/L: milligrams per liter in: inches DO: SM 4500 O G-2011 mV: millivolt bgs: below ground surface pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units TOC: top of casing Turbidity: SM 2130 B-2011 yin_ �t-SL��ec� L✓� l�}-ct.��t e{�Q (.6 � �, l-{- �/ale Page 1 of 1 ANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 ' ow -Flow Sampling Log Well ID, MW-04 Project Name: Jackson County Landfill ProjectNumber. C11480-01.02 Project Location: Dillsboro, NC Sample Collector(s): Well Diameter. 2 Screen Interval: 25 - 40 Well Depth (as constructed): 43 Depth to Water. o� S 03 Measuring Point: TOC Depth of Pump Intake: 35 Pump Used (circle): Peristaltic Bladder Comments: -gt Date: - Weather. O Facility ID or Permit * (if applicable): 50-02 Sample ID (on COC): MW-04- _� L;a,� in Arrive at Well: O 05 ft bgs Start Time: ft bgs Sample Time: ft Leave Well: Well Type: HStick Up ft Tagged Bottom: yam, y� Other (describe): p t �yeX• 1)3D ] a ❑Flush Mount ft at (time): /b/ q Purge Rate: 91W ry'Hmlll Total Volume Purged: 8 Pump Speed: Time Cu I ✓ w 1GL�C�LY U�fw DTW (feet) -v Temperature (°C) Dissolved Oxygen (mg/L) Speck Conductivity mhos/cm (p ) pH (S.U.) report to 0.1 S.U. re p Oxidation Reduction Potential (m10 Turbidity (NTU) �t {{ li r S, i J21 1r t1 41' l S S �i. 14 5.( r T, 10 4S 1_5�iLol 1 1 n tp l �, �t< ; T► 5 �° Spa. Db S .{' 5 LLD 52 IL 4 1, 21 Sample Analyst Signature:,��l Jqy Sample Analyst Name: j (e SS C Date: a L)�d Notes: 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity,' +/- 3% Conductivity., +/- 0.1 pH unit +/- 10 mV (or ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 S. 1 pmho/cm = 1 pS/cm Abbreviations: Method Reference: °C: degrees Celsius S.U.: standard units Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter ft: feet Specific conductivity: EPA Method 120.1, Rev. 1982 mg/L: milligrams per liter in: inches DO: SM 4500 O G-2011 mv: millivolt bgs: below ground surface pH: SM 4500-11' B-2011 NTU: nephelometric turbidity units TOC: top of casing Turbidity: SM 2130 B-2011 Oh -IFrC @ *913 Page 1 of 1 ANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Well Sampling Log Well ID: MW-05R Project Name: Jackson County Landfill Date: ' ) Project Number. C11480-01.02 Weather: QOF Fa Project Location: Dillsboro, NC Facility ID or Permit # (if applicable): 50-02 Sample Collector(s): S C Sample ID (on COQ: MW-05R- —ID A A O V 4 Well Diameter. 2 in Sample Time: / Lj/0 Screen Interval: N/A ft bgs Measuring Point: TOC Well Depth (WD): 54 ft TOC Well Type: KStick Up ❑Flush Mount Water Level in Feet (WL): ft TOC Comments: Length of Water Column (LWQ: ft; (WD - WL) One Casing Volume: gallons; (LWC x WCV) Three Casing Volumes: , a L f gallons 13 jp LC Actual Volume Purged: gallons Tagged Bottom: S E'�ft at (time): L,L l Three Casing Volumes: gallons Well Casing Volumes (WCV) 1" = 0.04 Gal/FA al/F 2" = 0.16 Gal/Ft 3" = 0.37 Gal/Ft 4" = 0.65 Gal/Ft 6" = 1.47 Gal/Ft 8" = 2.61 Gal/Ft 12" = 5.87 Gal/Ft Purge Method: Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other: Sample Method: Bailer-Disp, Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other. Oxidation Dissolved Specific pH (S.U.) Reduction Gallons Temperature Oxygen Conductivity report to 0.1 Potential Turbidity Reading Time Purged VQ (mg/L) (pmhos/cm) S.U. (mv) (NTU) Comments 2 , 3 ! a 5 6 7 8 9 10 Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic 125 mL Plastic 40 mL Glass 1 L Glass Other Protective Casing: . Pad: Lock: Vegetation: Access: t Sample Analysts Signaturetiz RMP-t, Sample Analysts Qtgsl Date: f -1f Name7!K CA& S Notes: 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% 0 and turbidity,• +/- 3%Conductivity,' +/- 0.1 pH unit' +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 Abbreviations: °C: degrees Celsius S.U.: standard units pmhos/cm: micromhos per centimeter ft: feet mg/L• milligrams per liter in: inches mv: millivolt bgs: below ground surface NTU: nephelometric turbidity units TOC: top of casing Method Reference: Temperature: SM 2550 B-2010 Specific conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 O G-2011 pH: SM 4500-H' B-2011 Turbidity: SM 2130 B-2011 Page 1 of 1 _}!/\J ® 9 �1� c ANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville. North Carolina 28801. '�,ow-Flow Sampling Log IWO ID: MW-06 Project Name: Jackson County Landfill Date: �[ 1 Project Number: C11480-01.02 Wea1h' r.. qLA V, Project Location: Dillsboro, NC Facility ID or Permit # (if applicable): 50-02 Sample Collector(s): sC, Sample ID (on COC): MW-06--2 ,% -1❑ Well Diameter: 2 in Arrive at Well: i c)4 Screen Interval: 84-94 ft bgs Start Time: i1 Well Depth (as constructed): 94 ft bgs Sample Time: t 3 Depth to Water. '$3, 3-7 ft Leave Well: . Measuring Point: TOC Well Type: HStick Up ❑Flush Mount Depth of Pump Intake: 91 ft Tagged Bottom: y %-D ft at (time): Pump Used (circle): Peristaltic Bladder Other (describe): Purge Rate: Comments: s fOG 2 :: r(l�{•-� �� Total Volume Purged: iZC>uCl OS9By= rrI 4Pump Speed: �QSZ CN (, ( YI 1. Time DTW (feet) Temperature (°C) Dissolved Oxygen (mg/L) Specific Conductivity (pmhos/cm) pH (S.U.) report to 0.1 S.U. Oxidation Reduction Potential (mV) Turbidity (NTU) k s. i co ia5: �t (o K a . 3, 5 iq. a =" 1y,8' Sample Analyst Signature: - Sample Analyst Name: v Date: o3 bpia ;r Notes: L 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity,' +/- 3% Conductivity, +/- 0.7 pH unit, +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation errors are to be crossed out with a single line. so the original text is still legible. followed by the staff members initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 5. 1 pmho/cm = 1 pS/cm Abbreviations: Method Reference: °C: degrees Celsius S.U.: standard units Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter ft: feet Specific conductivity: EPA Method 120.1, Rev. 1982 mg/L: milligrams per liter in: inches DO: SM 4500 O G-2011 mv: millivolt bgs: below ground surface pH: SM 4500-H` B-2011 NTU: nephelometric turbidity units TOC: top of casing Turbidity: SM 2130 B-2011 q S1 w J usl f­v�m e d 0 n. K LP P t) �J H ack-) `5, q S Lc Lo 113 Co - KL_-P S Page 1 of 1 ANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 ow -Flow Sampling Log Well ID: MW-07 Project Name: Jackson County Landfill Project Number. C11480-01.02 Project Location: Dillsboro, NC Sample Collector(s): `_KE Well Diameter. 2 Screen Interval: 70 - 95 Well Depth (as constructed): 95 Depth to Water.:11:133 Measuring Point: TOC Depth of Pump Intake: 85 Pump Used (circle): Peristaltic Comments: .8t&FWq 0FBSeejq-.-Flo—, gtpp-(gy{O(rp� Date: 3 0) Weather: V Facility ID or Permit # (if applicable): 50-02 Sample ID (on COC): MW-07- Cl2Z O a7 0 7 in Arrive at Well: 3 ft bgs Start Time: ft bgs Sample Time: ft Leave Well: Well Type: Stick Upr ❑Flush Mount ft Tagged Bottom: (PC) ft at (time): Bladder Other (describe): Purge Rate: obs-er.%W P j O® Total volume Purged: Pump Speed: j l 7 - -st `7✓h, Time DTW (feet) Temperature (*Q Dissolved Oxygen (mg/L) Specific Conductivity (pmhos/cm) pH (S.U.) report to 0.1 S.U. Oxidation Reduction Potential (m1) Turbidity (NTU) 3f, 7-3 V16 . ol J-Z , ZQ 7J__ 4 Z o 31, e6 _. , f 11610 F. `xa Z 1 i 8Y 17, 3.5` �'A 7 7, 7 t 1, TO (,A 93o t v S>J0 ►�z $ 16. ,v°f Sample Analyst Signature: Sample Analyst Name:° i ' I . ,1 G Date: Notes: 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity,, +/- 3% Conductivity, +/- 0.1 pH unit +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 5. 1 pmho/cm = 1 pS/cm Abbreviations: Method Reference: . °C: degrees Celsius S.0 : standard units Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter ft: feet Specific conductivity: EPA Method 120.1, Rev. 1982 mg/L: milligrams per liter in: inches DO: SM 4500 O G-2011 mv: millivolt bgs: below ground surface pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units TOC: top of casing Turbidity: SM 2130 B-2011 Page 1 of 1 ANCHOR ` QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 iampling Log - Grab Location ID- LT-01 Project Name: Project Number. Project Location: Sample Collector(s): Comments: Jackson County Landfill Date: C11480-01.02 Weather. Dillsboro, NC Facility ID or Permit # (if applicable): Sample ID (on COC): 50-02 LT-01- Sample Method (circle one): Grab Syringe Pump Bailer-Disp. Other. Time Temperature (°C) Dissolved Oxygen (mg Specific Conductivity (ymhos/cm) pH (S.U.) reportto 0.T S.U. Oxidation Reduction Potential (mV) Turbidity (NTU) Comments 1 ^ Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic 125 mL Plastic 40 mL Glass 1 L Glass Other Vegetation: Access: _ Sample Analyst Sample Analyst Signature: jVaLVA4\ Name: %r eM ru Date: +� ! Vi-x Notes: 1. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 2. Samples are analyzed immediately upon collection. 3. NC Field Laboratory Certificate Number 5445 Abbreviations: °C: degrees Celsius pmhos/cm: micromhos per centimeter mg/L: milligrams per liter mv: millivolt NTU: nephelometric turbidity units S.U.: standard units Method Reference: Temperature: SM 2550 B-2010 Specific conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 O G-2011 pH: SM 4500-H' B-2011 Turbidity: SM 2130 B-2011 Page 1 of 1 ANCHOR QEA u Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Surface Water Sampling Log Location ID: SW-01 Project Name: Jackson County Landfill Date: 2a O Project Number: C11480-01.02 Weather: -:LV� 1 T Project Location: Dillsboro, NC Facility ID or Permit # (if applicable): 50-02 Sample Collector(s): SC/ Sample ID (on COC): SW-01- a alfJo �i— Comments: Upstream of landfill Sample Method (circle one): Grab Syringe Pump Bailer Disp. Other: Specific Oxidation Temperature Dissolved Conductivity pH (S.U.) Reduction Turbidity Time VQ Oxygen (mg/L) (pmhos/cm) report to 0.1 S.U. Potential (m1) (NTU) Comments �i.o5 aa,5�s-�-�- M1t 1 ©� Sampling Container Number of Containers Requested Analysis 500 mL Plastic 4 _ f1L7JtZ+p-}{S I� 250 mL Plastic 125 mL Plastic 40 mL Glass ! 0 1 L Glass Other Vegetation: Q Sample Analyst Signature: Sample Analyst Name: Access: S-�e Q b S I fn StvG( m Date: 1. Documentation errors are to be crossed out with a sinale line, so the original text is still legible, followed by the staff members initials and date 2. Samples are analyzed immediately upon collection. 3. NC Field Laboratory Certificate Number 5445 Abbreviations: 'C: degrees Celsius pmhos/cm: micromhos per centimeter mg/L: milligrams per liter mV: millivolt NTU: nephelometric turbidity units S.U.: standard units Method Reference: Temperature: SM 2550 B-2010 Specific conductivity. EPA Method 120.1, Rev. 1982 DO: SM 4500 O G-2011 pH: SM 4500-H' B-2011 Turbiditv: SM 2130 B-2011 :3///Zv2Z Page 1 of 1 ANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Surface Water Sampling Log Location ID: SW-02 Project Name: Jackson County Landfill Date: Project Number: C11480-01.02 Weather. Project Location: Dillsboro, NC Facility ID or Permit # (if applicable): 50-02 Sample Collector(s): Sample ID (on COQ SW-02- ';Oct a 03 Comments: Downstream of landfill Sample Method (circle Grab Syringe Pump Bailer-Disp. Other: one): Specific Oxidation Temperature Dissolved Conductivity pH (S.U.) Reduction Turbidity Time VC) Oxygen (mg/L) (pmhos/cm) reportto 0.7 S.U. Potential (m1) (NTU) Comments Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic ty 125 mL Plastic 40 mL Glass V 0 CS 1 L Glass Other Vegetation: g !0101a r bovb Access: Zft,ve Sample Analyst _ Sample Analyst Signature: Name: Date: �r I Notes: 1. Documentation errors are to be crossed out with a sinale line. so the oriainal text is still leoible, followed by the staff members initials and date 2. Samples are analyzed immediately upon collection. 3. NC Field Laboratory Certificate Number 5445 Abbreviations: Method Reference: °C: degrees Celsius Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter Specific conductivity: EPA Method 120.1, Rev. 1982 mg/L milligrams per liter DO: SM 4500 O G-2011 mV: millivolt pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units Turbidity: SM 2130 B-2011 S.U.: standard units Page 1 of 1 ANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Surface Water Sampling Log Location ID: Project Name: 1CQJ� .{ J-� ( �0 I" i Date: Project Number: C! I - I d Weather: �` Project Location: _�I �1g'j �JL Facility ID or Permit # (if applicable): Sample Collector(s): IZ) t! p Sample ID (on COC): � b -(D S ' Jb�A"D 30 Comments: Sample Method (circle one): = `, Grabs Syringe Pump Bailer-Disp. Other: Time Temperature VQ Dissolved Oxygen (mg/L) Specific Conductivity (pmhos/cm) pH (S.U.) report to 0.1 S.U. Oxidation Reduction Potential (mV) Turbidity (NTU) Comments J3g1 ay '(0 (o Sampling Container Number of Containers Requested Analysis 500 mL Plastic - lat - - 250 mL Plastic r_�{....� ► -OWMSE 125 mL Plastic 40 mL Glass 1 L Glass Other Vegetation: rm.1 Pi l ( L ` V �l �N l )1 I Access: � rt'� YIl (,1 ('C (2 Sample Analyst Sample Analyst Signature: Name: -) Date: Notes: 1. Documentation errors are to be crossed out with a sinole line, so the orioinal text is still leoible, followed by the staff members initials and date 2. Samples are analyzed immediately upon collection. 3. NC Field Laboratory Certificate Number 5445 Abbreviations: Method Reference: 'C: degrees Celsius Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter Specific conductivity: EPA Method 120.1, Rev. 1982 mg/L: milligrams per liter DO: SM 4500 0 G-2011 mv: millivolt pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units Turbiditv: SM 2130 B-2011 S.U.: standard units Page 1 of 1 4-9 ANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 >ampling Log - Grab Location ID: DW-01 Project Name: Project Number. Project Location: Sample Collector(s): Comments: Jackson County Landfill Date: C11480-01.02 Weather. Dillsboro, INC Facility ID or Permit # (if applicable): Sc Sample ID (on COC): Purged 30 gallons prior to sampling. Wilkey residence. Z 3 Lib r CU)n 50-02 DW-01- 6)7 Z 03 !� Sample Method (circle one): Grab Syringe Pump Bailer-Disp. Other. Time Temperature VQ Dissolved Oxygen (mg/L) Specific Conductivity (pmhos/cm) pH (S.U.) reportto 0.1 S.U. Oxidation Reduction Potential (m1) Turbidity (NTU) Comments LL Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic 125 mL Plastic 40 mL Glass 1 L Glass Other Vegetation: ]I R Access: 2 Dc—OL Sample Analyst Sample Analyst Signature: me: Date: ! 1` Notes: ii 1. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 2. Samples are analyzed immediately upon collection. 3. NC Field Laboratory Certificate Number 5445 Abbreviations: °C: degrees Celsius pmhos/cm: micromhos per centimeter mg/L: milligrams per liter mv: millivolt NTU: nephelometric turbidity units S.U.: standard units Method Reference. Temperature: SM 2550 B-2010 Specific conductivity. EPA Method 120.1, Rev. 1982 DO: SM 4500 O G-2011 PH: SM 4500-H# B-2011 Turbidity. SM 2130 B-2011 Page 1 of 1 ANCHOR QE Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Well Sampling Log Palm c7 W _6 "`4 Project Name: �(�( h rA (� Q rn ju& Date: Og "�j Project Number. v UA=Weather. ' d 0 . Project Location: � , I Facility ID or Permit # (if applicable): Sample Collector(s): Sample ID (on COC): Well Diameter. in Sample Time: Screen Interval: ft bgs Measuring Point: Well Depth (WD): ft TOC Well Type: oStick Up ❑Flush Mount Water Level in Feet (WL): ft TOC Comments: Length of Water Column (LWQ: ft; (WD - WL) �m � YV t If.K)_-�- L,gl � � Lt�r�. One Casing Volume: gallons; (LWC x WCV) J Three Casing Volumes: gallons Actual Volume Purged: gallons Tagged Bottom: ft at (time): Three Casing Volumes: gallons Well Casing Volumes (WCV) 1" = 0.04 Gal/Ft 2" = 0.16 GaVFt 3" = 0.37 Gal/Ft 4" = 0.65 Gal/Ft 6" = 1.47 Gal/Ft 8" = 2.61 Gal/Ft 12" = 5.87 Gal/Ft Purge Method: Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other. Sample Method: Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other. Oxidation Dissolved Specific pH (S.U.) Reduction Gallons Temperature Oxygen Conductivity report to 0.1 Potential Turbidity Reading Time Purged VQ (mg/L) (pmhos/cm) S.U. (mV) (NTU) Comments 1 r 2 3 4 5 6 7 8 9 10 Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic 125 mL Plastic 40 mL Glass 1 L Glass Other Protective Casing: Pad: Lock Vegetation: Access: Sample Analysts Signature: Sample Analysts ! I �_ Date: !OUAAAAAAe Name: _ v Notes: I L/ V 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity, +/- 3% Conductivity; +/- 0.7 pH unit; +/- 70 mV fbrORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 Abbreviations: °C: degrees Celsius S.U.: standard units pmhos/cm: micromhos per centimeter ft: feet mg/L: milligrams per liter in: inches mV: millivolt bgs: below ground surface NTU: nephelometric turbidity units TOC: top of casing Method Reference: Temperature: SM 2550 B-2010 Specific conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 O G-2011 pH: SM 4500-H' B-2011 Turbidity: SM 2130 B-2011 Page 1 of 1 ANCHOR QEA Equipment Documentation and Instrument Calibration Data Sheet Project Name: Jackson County Landfill Analyst Conducting Calibration:; Project Number. C11480-01.02 Date of Calibration: - Project Location: Dillsboro, NC Dare of Field Measureme,�1. Facility ID or Permit # (if applicable): 50-02 EQUIPMENT DOCUMENTATION Rental sample analysis equipment or meters used to take measurements: Equipment Type Brand Serial Number Date of Use Rental Company Select Turb(dimeter.F:X� Hach 2100Q (s/n 151006045207) HF Scientific MicroTPW (s/n 200601045) Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 -3 -4issce a�a 31-4I t7A Instrument Readings (Hach 2100Q) Instrument Readings (HF Scientific MicroTPVII) Cal Std Information 10 NTU 20 NTU 100 NTU 800 NTU 1,000 NTU 10.0 NTU 0.02 TU Lot #: i 1 Expiration Date: - 3 Cal (NTU): n f, Cal (NTU : Cal (N>1. G Q P'j. Cal (NTU): Cal (NTU): Cal (NTU): Time:W Time- n� Time: �(Jr1 f l Time: Time: Time: Calibration Verification: •Pre -Analysis Check (10 NTU): Resul NTU : Z ✓ Time: �f a W �O "Pre -Analysis Check (10 TU): Resuft (NTU): Time: "Post -Analysis Check (10 NTU): U): Result (To ('11 r Time: by �� •Pos nalysis Check 00 NTU): Result (NTU): Time: YSI Professional Plus Multiparameter Meter (s/n 1811101802) Instrument Readings Cal Std Information Lot # Date Opened P .Date Dissolved Oxygen (% saturation) Initial (%): Cal (%): mmHg: [� r 5 ( Temperature CC): �S� rb Time: ((,� b ;0 DO (Site #2, if a licablel" Initial (%): Cal (%): mmHg: Temperature (°C): Time: QC" Check: D O Ti iI Result Ti me Result Time, Result PH7S.U. report to0.1 S.U. Initial: - l pHm Cal (S.U.)-. �+^ pHmV: `? Time, /yl (f 1�Ia` b(p Ia3 PH 4 S.U. report to0.7S.0 Initial: pHmV: �'" —I r Cal (S.U.): pHmV: (4 'ct Time: «� Ota " ��! �� 0� W PH 10 S.U. report to0.15.U. Initial: t pH mV:' tq _1 Cal (S.U.): . pHmV: r� Time: �j 1� f6 r QC** pH 7 S.U. ref ort to a SU. Time: 'i � Result (S.U.):11 r t Time: r Result (S.U.)(�•� 11- Si Time: Result (S.U.): ( I ,� I rt3 K Spec.Cond. 1,000 p mhos/cm Initial: �( v Cal(pmhs/cin): to 1� �,J Time: 0(0 ` �L1IR a % Recovery= QC" Spec Cond. 1,000 pmhos/cm Time: ( ' i Result (pmhos/cm): Li Time: �i r Result (pmhos/i:2) I V ime: f Result (pmhos/cm): i a5 I a-1 a� % Recovery= ORP 200 mV Initial: Cal: Temperature (°C): 1 l f Time: r 7(I a r wS a� _ ', t Analyst Signature: Analyst Name: fi, C - V. 1 Date: .� Notes: 0 0 Revision 6, 12/20/20, MAK 1. Instruments shall be calibrated in accordance with the manufacturers operation manual. 2. Specific Conductivity should be calibrated according to values representative of historic range. 3. Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, QC checks. 4. •When performing DO analyses at multiple sample sites (i.e. project/facility locations), the DO probe must be calibrated at each sample site prior to analysis. 5. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated. 6.'• QC check must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be performed with calibration standard from a separate lot # as the initial QC 7. % Recovery = (Value Obtained, pmhos/cm : True Value, pmhos/cm) x 100 8. NC Field Laboratory Certificate Number 5445 9. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 opt Salinity. 11. 1 pmho/cm = 1 pS/cm Abbreviations: Method Reference: pmhos/cm: micromhos per centimeter NTU: nephelometric turbidity units Temperature: SM 2550 B-2010 'C: degrees Celsius ORP: oxidation reduction potential Specific conductivity EPA Method 120.1, Rev. 1982 DO: dissolved oxygen s/n: serial number DO: SM 45000 G-2011 mg/L milligrams per liter S.U.: standard units pH: SM 4500-H' B-2011 mV: millivolt Spec. Cond.: Specific Conductivity Turbidity. SM 2130 B-2011 Pq I GC aryl D O� 31_1 L0 C�� fir+ ('vl PEA q OUCY(AfV-1 r Page 1 of 1 )34 q or) 391� a•a1 ANCHOR QEA Equipment Documentation and Instrument Calibration Data Sheet Project Name: Jackson CountyLandfill Analyst Conducting Calibration: Project Number: C11480-01.02 Date of Calibration: Project Location: Dillsboro, NC Date of Field Measurements: _ Facility ID or Permit # ('rf applicable): 50-02 EQUIPMENT DOCUMENTATION Rental sample analysis equipment or meters used to take measurements: Equipment Type Brand Serial Number Date of Use Rental Company Select Turbidimeter.® Hach 2100Q (s/n 151006045207) HF Scientific MicroTPW (s/n 200601045) Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Instrument Readings Instrument Readings (Hach 2100Q) (HF Scientific MicroTPW) Cal Std Information 10 NTU 20 NTU 100 NTU 800 NTU 1,000 NTU 10.0 NTU 0-02 NTU Lot Expiration Date: Cal (NT,l (D -i J,�J 1 Cal (N ) 1(� b Cal (NTU): Cal (NTU): Cal (NTU): Cal (NIT Time: r 3 Time- qc, Timer• 5 Time: Time: _ ime: �d Calibration "Pre -Analysis Result (NTU): Time: rVV1l *Pre -Analysis R .5kA TU): Time: Verification• Check (10 NTU): l Check (10 NTU): *Post -Analysis Result NTU : /�`�A `mil Time: b *Post -Analysis Result (NTU): Time: Check (10 NTU): i / Check (10 NTU): YSI Professional Plus Multiparameter Meter (s/n '186101802) Cal Still Information Instrument Readings Date Lot # Opened Exp. Date Dissolved Oxygen Initial (%): Cal (%): mmHg: Temperature (°4): Time: -13 (% saturation) l D ) 0 0^-/ l 0 DO (Site #2, Initial (%): Cal (%): mmHg: Temperature CC): Time: ifapplicablei QC** Check DO Time:/Q q Result (%): 103, D Time Result r Time: Result (%): PH 7 S.U. Initial: pHmV_ ,� ; n Cal (S.U.): pHmV: Time: k i 1 if a ( (v I Q3 report to 0.1 S.U. ,�•L� - + PH 4 S.U. ]Time:, Initial: �1 pHmV: ", Cal IS.U.): I� pHmV: Time: /J i�Ia� '''�•� report to0.1S.U. 1:J Jll�'Y/ � PH 10 Initi :� ( pHmmV: 2 � ^ Cal ( 11!!10 o pHmV: Time: (. report to 0.7 S.U. 0.7 S. :JJ tub r il- QC** Result (S.U.): �-� Time: Result (S.U.): Time: Result (S.U.): ivc �,I �a �� 3 report to 0. S U. Spec Cond. Initial: �� Cal (pmhos/cm): Time: � l a� (�� a 1,000 mhos/cm l I��� '✓�.✓�`u T• % Recovery= QC** Spec. Cond. Time: Result (pmhos/cm): Time:'j. Result (pmhos/cm): Time: Result (pmhos/cm): 1,000 pmhos/cm % Recovery= ORP 200 Initial: Cal: G Teture (°C): Time t 3f�l 5 Arrlys! 3 � AnalystSigltature: Date: Notes:rwia_,�L_ �rif Revision 6, 12/20/20, MAK 1. Instruments shall be calibrated in accordance with the manufacturer's operaC anual. c 2. Speific Conductivity should be calibrated according to values representative of historic range. 3. Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, QC checks. 4. *When performing DO analyses at multiple sample sites (i.e. project/facility locations), the DO probe must be calibrated at each sample site prior to analysis. 5. QC Acceptable Ranges: PH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated. 6. •* QC check must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be performed with calibration standard from a separate lot # as the initial QC. 7. % Recovery = (Value Obtained, pmhos/cm -. True Value, pmhos/cm) x 100 8. NC Field Laboratory Certificate Number 5445 9. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity. 11. 1 pmho/cm = 1 pS/cm Abbreviations: - Method Reference. pmhos/cm: micromhos per centimeter NTU: nephelometric turbidity units Temperature: SM 2550 B-2010 °C: degrees Celsius ORP: oxidation reduction potential Specific conductivity. EPA Method 120.1, Rev. 1982 DC: dissolved oxygen s/n: serial number DO: SM 45000 G-2011 mg/L: milligrams per liter S.U.: standard units pH: SM 4500-H' 0-2011 mV: millivolt 5 ec. Cond: Specific Conductivity Turbidity: SM 2130 B-2011 - 0A s� 11 -� I a s (L). . :�,Ce tiC&N CGJ Ecikef-1111 . Page 1 of 1 Is■ C E a ._ cr aj c � C c m � \ v 0 E t` u° .° v m 'p_ M ^ �w p wCL O w c t'i' — C'� <•6 m a w Y R� CT j ew O v M M p � — x_ J r A � m u U r+ v µ ai ? a M 1}' m W Z a O +I V1 00 � v )' E 1 a x � a j + Q a m N w m E w m 2 Z5 a = N a O Y u Y u t9 U U U v U n t� HA u � a `w I o ����� 2 u a E ;r i F i w L a00 ei C M E a .7 W C w � m C Y C Y m g 0 \ c w O N r � m ' X W w c w N a O c m = a ID j Q u z 0 J m � = E m m Z cL a_ o n+1 N co N E g E a a u � j a C N w m O U a y F- cC a m 3 ate+ Q O Y Y c u u y U U U v u a v 0 u a a `w m O o = U a w i E i i w L C E a .j w w u N m C Y C_ Y � m g 0 \ c w o N M' In X W w c a^ O w v w j w u cu of u 0 J m y O a E C M m j Z a a +1 O 0 N � w g E a 2 CL u j � X C7 C U a u m a m 7 Q p Y 0 U U U s CJ U U a u U a-+ tn v ° 0 `w mo����� 2 V a w � E i i w L a a � c L L v 3 `1 .6 w m O � C E w 00 w E w � y � U N � s o w +I « c � L O a 72 O m N u d O C y a w w 3 u m « w bo41 Y u lo °� u c o � c y a � C N m � E � c Ew a G u E w 2 V C ++1 w « w m 0a m41 o = w o O w £ •- Y Yy� N Y Q! 8( fl C C m ' 3 m O m c 3 w A 0. u �- m w � z oz w m N a luu 7 d T O m � = y O m R o d• G r A w w r M c u O w a N L 3 o w E 15 x c cc y o. y O u OO t +1 t ai � c a s 3 y z m u u c L � w L a0+ = y C w O y Y N � c u d O a £ O C t o $ w i j2 c 3 Ou G � F 4 Appendix B Reports of Laboratory Analysis, Chain -of -Custody Documentation, and Certificates of Analysis Waypointo ANALYTICAL 3/25/2022 Anchor QEA of North Carolina, PLLC Chuck Pippin 231 Haywood Street Asheville, NC, 28801 449 5pringbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Ref: Analytical Testing Lab Report Number: 22-069-0032 Client Project Description: Jackson County Landfill GW C11480-01.02 Task 02 Site: 58-02 Project Number: 58-02 Dear Chuck Pippin: Waypoint Analytical, LLC (Charlotte) received sample(s) on 3/10/2022 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, J* 11 OA-2�— Kyle N. Collins General Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 17 Waypoint.0 ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date North Carolina State Program 37735 07/31/2022 North Carolina State Program 402 12/31/2022 South Carolina State Program 99012 07/31/2022 South Carolina State Program 99012 12/31/2022 Page 1 of 1 00016/22-069-0032 Page 2 of 17 Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointana lyti ca I som Sample Summary Table Report Number: 22-069-0032 Client Project Description: Jackson County Landfill GW C11480-01.02 Task 02 Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 95864 DW-01-20220308 Aqueous 03/08/2022 16:05 03/10/2022 11:15 524.2 95865 DW-02-20220308 Aqueous 03/08/2022 16:30 03/10/2022 11:15 524.2 95866 TB-DW-20220308 Aqueous 03/08/2022 03/10/2022 11:15 524.2 Pace Analytical - Huntersville, NC, Huntersville, NC Page 3 of 17 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, INC 28078 (704)875-9092 March 18, 2022 Angela Overcash Waypoint Analytical 449 Springbrook Rd Charlotte, NC 28217 RE: Project: 1433EXP-Revised Report Pace Project No.: 92593013 Dear Angela Overcash: Enclosed are the analytical results for sample(s) received by the laboratory on March 11, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Ormond Beach This revision was issued on 03/18/22 to update the report recipient on the cover page, per client request. If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Robbi A. Jones, Prism Laboratories, Inc. b2 � .%I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 9 without the written consent of Pace Analytical Services, LLC. Page 4 of 17 Page 1 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, INC 28078 (704)875-9092 CERTIFICATIONS Project: 1433EXP-Revised Report Pace Project No.: 92593013 Pace Analytical Services Ormond Beach 8 East Tower Circle, Ormond Beach, FL 32174 Montana Certification #: Cert 0074 Alaska DEC- CS/UST/LUST Nebraska Certification: NE-OS-28-14 Alabama Certification #: 41320 New Hampshire Certification #: 2958 Colorado Certification: FL NELAC Reciprocity New Jersey Certification #: FL022 Connecticut Certification M PH-0216 New York Certification #: 11608 Delaware Certification: FL NELAC Reciprocity North Carolina Environmental Certificate #: 667 Florida Certification #: E83079 North Carolina Certification #: 12710 Georgia Certification #: 955 North Dakota Certification #: R-216 Guam Certification: FL NELAC Reciprocity Ohio DEP 87780 Hawaii Certification: FL NELAC Reciprocity Oklahoma Certification #: D9947 Illinois Certification #: 200068 Pennsylvania Certification #: 68-00547 Indiana Certification: FL NELAC Reciprocity Puerto Rico Certification #: FLO1264 Kansas Certification M E-10383 South Carolina Certification: #96042001 Kentucky Certification #: 90050 Tennessee Certification #: TN02974 Louisiana Certification #: FL NELAC Reciprocity Texas Certification: FL NELAC Reciprocity Louisiana Environmental Certificate M 05007 US Virgin Islands Certification: FL NELAC Reciprocity Maine Certification #: FLO1264 Virginia Environmental Certification #: 460165 Maryland Certification: #346 West Virginia Certification #: 9962C Michigan Certification #: 9911 Wisconsin Certification #: 399079670 Mississippi Certification: FL NELAC Reciprocity Wyoming (EPA Region 8): FL NELAC Reciprocity Missouri Certification M 236 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 17 Page 2 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, INC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: 1433EXP-Revised Report Pace Project No.: 92593013 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92593013001 DW-01-20220308 EPA 524.2 CLT 24 PASI-0 92593013002 DW-02-20220308 EPA 524.2 CLT 24 PASI-0 92593013003 TB-DW-20220308 EPA 524.2 CLT 24 PASI-0 PASI-O = Pace Analytical Services - Ormond Beach REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 12 Page 6 of 17 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, INC 28078 (704)875-9092 ANALYTICAL RESULTS Project: 1433EXP-Revised Report Pace Project No.: 92593013 Sample: DW-01-20220308 Lab ID: 92593013001 Collected: 03/08/22 16:05 Received: 03/11/22 10:55 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 524.2 MSV Analytical Method: EPA 524.2 Pace Analytical Services - Ormond Beach Benzene ND mg/L 0.00050 1 03/16/22 15:50 71-43-2 Carbon tetrachloride ND mg/L 0.00050 1 03/16/22 15:50 56-23-5 Chlorobenzene ND mg/L 0.00050 1 03/16/22 15:50 108-90-7 1,2-Dichlorobenzene ND mg/L 0.00050 1 03/16/22 15:50 95-50-1 1,4-Dichlorobenzene ND mg/L 0.00050 1 03/16/22 15:50 106-46-7 1,2-Dichloroethane ND mg/L 0.00050 1 03/16/22 15:50 107-06-2 1,1-Dichloroethene ND mg/L 0.00050 1 03/16/22 15:50 75-35-4 cis-1,2-Dichloroethene ND mg/L 0.00050 1 03/16/22 15:50 156-59-2 trans- 1,2-Dichloroethene ND mg/L 0.00050 1 03/16/22 15:50 156-60-5 1,2-Dichloropropane ND mg/L 0.00050 1 03/16/22 15:50 78-87-5 Ethylbenzene ND mg/L 0.00050 1 03/16/22 15:50 100-41-4 Methylene Chloride ND mg/L 0.0010 1 03/16/22 15:50 75-09-2 Styrene ND mg/L 0.00050 1 03/16/22 15:50 100-42-5 Tetrachloroethene ND mg/L 0.00050 1 03/16/22 15:50 127-18-4 Toluene ND mg/L 0.00050 1 03/16/22 15:50 108-88-3 1,2,4-Trichlorobenzene ND mg/L 0.00050 1 03/16/22 15:50 120-82-1 1,1,1-Trichloroethane ND mg/L 0.00050 1 03/16/22 15:50 71-55-6 1,1,2-Trichloroethane ND mg/L 0.00050 1 03/16/22 15:50 79-00-5 Trichloroethene ND mg/L 0.00050 1 03/16/22 15:50 79-01-6 Vinyl chloride ND mg/L 0.00050 1 03/16/22 15:50 75-01-4 Xylene (Total) ND mg/L 0.0010 1 03/16/22 15:50 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 102 % 70-130 1 03/16/22 15:50 460-00-4 Toluene-d8 (S) 95 % 70-130 1 03/16/22 15:50 2037-26-5 1,2-Dichlorobenzene-d4 (S) 107 % 70-130 1 03/16/22 15:50 2199-69-1 Sample: DW-02-20220308 Lab ID: 92593013002 Collected: 03/08/22 16:30 Received: 03/11/22 10:55 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 524.2 MSV Analytical Method: EPA 524.2 Pace Analytical Services - Ormond Beach Benzene ND mg/L 0.00050 1 03/16/22 16:14 71-43-2 Carbon tetrachloride ND mg/L 0.00050 1 03/16/22 16:14 56-23-5 Chlorobenzene ND mg/L 0.00050 1 03/16/22 16:14 108-90-7 1,2-Dichlorobenzene ND mg/L 0.00050 1 03/16/22 16:14 95-50-1 1,4-Dichlorobenzene ND mg/L 0.00050 1 03/16/22 16:14 106-46-7 1,2-Dichloroethane ND mg/L 0.00050 1 03/16/22 16:14 107-06-2 1,1-Dichloroethene ND mg/L 0.00050 1 03/16/22 16:14 75-35-4 cis-1,2-Dichloroethene ND mg/L 0.00050 1 03/16/22 16:14 156-59-2 trans- 1,2-Dichloroethene ND mg/L 0.00050 1 03/16/22 16:14 156-60-5 1,2-Dichloropropane ND mg/L 0.00050 1 03/16/22 16:14 78-87-5 Ethylbenzene ND mg/L 0.00050 1 03/16/22 16:14 100-41-4 Methylene Chloride ND mg/L 0.0010 1 03/16/22 16:14 75-09-2 Styrene ND mg/L 0.00050 1 03/16/22 16:14 100-42-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2022 10:20 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 12 Page 7 of 17 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, INC 28078 (704)875-9092 ANALYTICAL RESULTS Project: 1433EXP-Revised Report Pace Project No.: 92593013 Sample: DW-02-20220308 Lab ID: 92593013002 Collected: 03/08/22 16:30 Received: 03/11/22 10:55 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 524.2 MSV Tetrachloroethene Toluene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) Toluene-d8 (S) 1,2-Dichlorobenzene-d4 (S) Analytical Method: EPA 524.2 Pace Analytical Services - Ormond Beach ND mg/L 0.00050 ND mg/L 0.00050 ND mg/L 0.00050 ND mg/L 0.00050 ND mg/L 0.00050 ND mg/L 0.00050 ND mg/L 0.00050 ND mg/L 0.0010 104 % 70-130 98 % 70-130 105 % 70-130 1 03/16/22 16:14 127-18-4 1 03/16/22 16:14 108-88-3 1 03/16/22 16:14 120-82-1 1 03/16/22 16:14 71-55-6 1 03/16/22 16:14 79-00-5 1 03/16/22 16:14 79-01-6 1 03/16/22 16:14 75-01-4 1 03/16/22 16:14 1330-20-7 1 03/16/22 16:14 460-00-4 1 03/16/22 16:14 2037-26-5 1 03/16/22 16:14 2199-69-1 Sample: TB-DW-20220308 Lab ID: 92593013003 Collected: 03/08/22 00:00 Received: 03/11/22 10:55 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 524.2 MSV Analytical Method: EPA 524.2 Pace Analytical Services - Ormond Beach Benzene ND mg/L 0.00050 1 03/16/22 16:38 71-43-2 Carbon tetrachloride ND mg/L 0.00050 1 03/16/22 16:38 56-23-5 Chlorobenzene ND mg/L 0.00050 1 03/16/22 16:38 108-90-7 1,2-Dichlorobenzene ND mg/L 0.00050 1 03/16/22 16:38 95-50-1 1,4-Dichlorobenzene ND mg/L 0.00050 1 03/16/22 16:38 106-46-7 1,2-Dichloroethane ND mg/L 0.00050 1 03/16/22 16:38 107-06-2 1,1-Dichloroethene ND mg/L 0.00050 1 03/16/22 16:38 75-35-4 cis-1,2-Dichloroethene ND mg/L 0.00050 1 03/16/22 16:38 156-59-2 trans- 1,2-Dichloroethene ND mg/L 0.00050 1 03/16/22 16:38 156-60-5 1,2-Dichloropropane ND mg/L 0.00050 1 03/16/22 16:38 78-87-5 Ethylbenzene ND mg/L 0.00050 1 03/16/22 16:38 100-41-4 Methylene Chloride 0.0032 mg/L 0.0010 1 03/16/22 16:38 75-09-2 Styrene ND mg/L 0.00050 1 03/16/22 16:38 100-42-5 Tetrachloroethene ND mg/L 0.00050 1 03/16/22 16:38 127-18-4 Toluene ND mg/L 0.00050 1 03/16/22 16:38 108-88-3 1,2,4-Trichlorobenzene ND mg/L 0.00050 1 03/16/22 16:38 120-82-1 1,1,1-Trichloroethane ND mg/L 0.00050 1 03/16/22 16:38 71-55-6 1,1,2-Trichloroethane ND mg/L 0.00050 1 03/16/22 16:38 79-00-5 Trichloroethene ND mg/L 0.00050 1 03/16/22 16:38 79-01-6 Vinyl chloride ND mg/L 0.00050 1 03/16/22 16:38 75-01-4 Xylene (Total) ND mg/L 0.0010 1 03/16/22 16:38 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 104 % 70-130 1 03/16/22 16:38 460-00-4 Toluene-d8 (S) 99 % 70-130 1 03/16/22 16:38 2037-26-5 1,2-Dichlorobenzene-d4 (S) 104 % 70-130 1 03/16/22 16:38 2199-69-1 Date: 03/18/2022 10:20 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 12 Page 8 of 17 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, INC 28078 (704)875-9092 QUALITY CONTROL DATA Project: 1433EXP-Revised Report Pace Project No.: 92593013 QC Batch: 808340 Analysis Method: EPA 524.2 QC Batch Method: EPA 524.2 Analysis Description: 524.2 MSV Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 92593013001, 92593013002, 92593013003 METHOD BLANK: 4438520 Matrix: Associated Lab Samples: 92593013001, 92593013002, 92593013003 Blank Parameter Units Result Water Reporting Limit Analyzed Qualifiers 1,1,1-Trichloroethane mg/L ND 0.00050 03/16/22 14:37 1,1,2-Trichloroethane mg/L ND 0.00050 03/16/22 14:37 1,1-Dichloroethene mg/L ND 0.00050 03/16/22 14:37 1,2,4-Trichlorobenzene mg/L ND 0.00050 03/16/22 14:37 1,2-Dichlorobenzene mg/L ND 0.00050 03/16/22 14:37 1,2-Dichloroethane mg/L ND 0.00050 03/16/22 14:37 1,2-Dichloropropane mg/L ND 0.00050 03/16/22 14:37 1,4-Dichlorobenzene mg/L ND 0.00050 03/16/22 14:37 Benzene mg/L ND 0.00050 03/16/22 14:37 Carbon tetrachloride mg/L ND 0.00050 03/16/22 14:37 Chlorobenzene mg/L ND 0.00050 03/16/22 14:37 cis-1,2-Dichloroethene mg/L ND 0.00050 03/16/22 14:37 Ethylbenzene mg/L ND 0.00050 03/16/22 14:37 Methylene Chloride mg/L ND 0.0010 03/16/22 14:37 Styrene mg/L ND 0.00050 03/16/22 14:37 Tetrachloroethene mg/L ND 0.00050 03/16/22 14:37 Toluene mg/L ND 0.00050 03/16/22 14:37 trans- 1,2-Dichloroethene mg/L ND 0.00050 03/16/22 14:37 Trichloroethene mg/L ND 0.00050 03/16/22 14:37 Vinyl chloride mg/L ND 0.00050 03/16/22 14:37 Xylene (Total) mg/L ND 0.0010 03/16/22 14:37 1,2-Dichlorobenzene-d4 (S) % 106 70-130 03/16/22 14:37 4-Bromofluorobenzene (S) % 96 70-130 03/16/22 14:37 Toluene-d8 (S) % 98 70-130 03/16/22 14:37 LABORATORY CONTROL SAMPLE & LCSD: Parameter 4438521 Units Spike Conc. 4438522 LCS LCSD Result Result LCS LCSD % Rec % Rec % Rec Limits RPD Max RPD Qualifiers 1,1,1-Trichloroethane mg/L 0.01 0.0086 0.0084 86 84 70-130 2 20 1,1,2-Trichloroethane mg/L 0.01 0.0092 0.0091 92 91 70-130 1 20 1,1-Dichloroethene mg/L 0.01 0.0082 0.0083 82 83 70-130 1 20 1,2,4-Trichlorobenzene mg/L 0.01 0.0089 0.0087 89 87 70-130 2 20 1,2-Dichlorobenzene mg/L 0.01 0.0086 0.0087 86 87 70-130 1 20 1,2-Dichloroethane mg/L 0.01 0.0095 0.0094 95 94 70-130 1 20 1,2-Dichloropropane mg/L 0.01 0.0089 0.0090 89 90 70-130 2 20 1,4-Dichlorobenzene mg/L 0.01 0.0088 0.0085 88 85 70-130 3 20 Benzene mg/L 0.01 0.0089 0.0086 89 86 70-130 4 20 Carbon tetrachloride mg/L 0.01 0.0084 0.0085 84 85 70-130 2 20 Chlorobenzene mg/L 0.01 0.0089 0.0086 89 86 70-130 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2022 10:20 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 12 Page 9 of 17 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, INC 28078 (704)875-9092 QUALITY CONTROL DATA Project: 1433EXP-Revised Report Pace Project No.: 92593013 LABORATORY CONTROL SAMPLE & LCSD: 4438521 4438522 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers cis-1,2-Dichloroethene mg/L 0.01 0.0087 0.0086 87 86 70-130 0 20 Ethylbenzene mg/L 0.01 0.0084 0.0082 84 82 70-130 3 20 Methylene Chloride mg/L 0.01 0.0095 0.0096 95 96 70-130 1 20 Styrene mg/L 0.01 0.0084 0.0083 84 83 70-130 2 20 Tetrachloroethene mg/L 0.01 0.0088 0.0087 88 87 70-130 1 20 Toluene mg/L 0.01 0.0084 0.0084 84 84 70-130 0 20 trans-1,2-Dichloroethene mg/L 0.01 0.0085 0.0085 85 85 70-130 0 20 Trichloroethene mg/L 0.01 0.0084 0.0085 84 85 70-130 1 20 Vinyl chloride mg/L 0.01 0.0082 0.0088 82 88 70-130 7 20 Xylene (Total) mg/L 0.03 0.025 0.024 82 81 70-130 1 20 1,2-Dichlorobenzene-d4(S) % 101 98 70-130 4-Bromofluorobenzene (S) % 99 99 70-130 Toluene-d8(S) % 97 99 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2022 10:20 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 12 Page 10 of 17 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: 1433EXP-Revised Report Pace Project No.: 92593013 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2022 10:20 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 12 Page 11 of 17 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, INC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 1433EXP-Revised Report Pace Project No.: 92593013 Lab ID Sample ID QC Batch Method QC Batch 92593013001 DW-01-20220308 EPA 524.2 808340 92593013002 DW-02-20220308 EPA 524.2 808340 92593013003 TB-DW-20220308 EPA 524.2 808340 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2022 10:20 AM without the written consent of Pace Analytical Services, LLC. Analytical Analytical Method Batch Page 9 of 12 Page 12 of 17 Document Name: Document Revised: November 15, 2021 aceAnalytiea! Sample Condition Upon Receipt ($CUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.08 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville*Q Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville❑ Sample Condition . Client Name:'V4 " CftAk- J'sh �'I 1K & -1 Qr� Upon Receipt L L-C Project 0: 011 . 92'.593Q 13 ❑Courier: [—]Fed Ex ❑UPS OUSPS _ CHent I I I III � I IIII I III III I III Commercial ❑Pate [3Other: 11 92593013 Custody Seal Present? []Yes-E]rNo Sealslntact7 ❑yes ❑No + Date/Initials Person Examining Contents: 3/�71 7- 2- Packing Material: ❑Bubble Wrap ❑Bubble Bags ❑None � Other 4V (I- ",'� ` 1 B[olagical Tissue Frozen? Thermometer: Dyes ❑No [poh ❑ IR Gun ID: (11 7 TL: �, �� pvuet []Blue ❑None Type of Ice: Correction Factor: Cooler Temp: L' Add/Subtract ('Cj C % Temp should be above freezing to 6°C []Samples out of temp criteria. Samples on ice, cooling process Cooler-Femp-C-orrected 11 - as gu USDA Regulated Soll (-❑-MrA. water sample] Did samples originate in a quarantine zone within the United States: CA, NY, or SC {check maps)? Did samples originate from a Foreign source (internationally, I—IYac MrJn Comments/Discrepancy: u Chain of Custody Present? --f]Yes ❑No [I N/A 1. Samples Arrived within Hold Time? — BYes []NO ❑N/A 2. Short Hold Time Analysis (02 hr.)? ❑Yes ON-0 N/A 3. Rush Turn Around Time Requested? DYes ❑NU- N/A 4. Sufficient Volume? Ores MNo CINIA 5. Correct Containers Used? -Pace Containers Used? _QYEes []Yes ❑No Nd [-]N/A ❑N/A 6. Containers Intact? .QVes []No N/A 7. Dissolved analysis: Samptes Field Filtered? ❑Yes []No /fr 8, Sample Labels Match COC7 Inciudes Date/Time/10/Analysis MatriK: ZY—es w , ❑No ❑N/A ^►� 9. 1 Headspace In VOA Vials (>S-6mm)? Yes o ❑N/A 10. 1 a C' t [ p .� Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes []Yes (]No []No ❑N/A N/A 11. COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Lot ID of split containers: Date/Time; Date: Date: Field Data Required? ❑Yes []NO Page 13 of 17 Page 10 of 12 e _ accAnalXical Document Name: Sample Conditlon Upon Recelpt (SCUR) Document Revised: November 15, 2021 Page 2 of 2 Document No.: F-CAR-CS-033-Rev.08 Issuing Authority: Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottles Project P '� wv11 PM : M14B CLIENT: 9^1593013 Due Date: 03/18/22 92-Pt- i sm Z x a ¢ z n ? Z Z 2 z w a ,, a z .r _ „� Q v c v v v ea "' _ v `" v a Z ~• I i °' a ` ro y v a -- z c C r N a O '^ Z ¢ Y O m a — c -O O ry a E Q _z.. m w -- 4U m o r a' ,U-_, r✓ ry >= n? c c n 7 7 7 c = = N z v m � 2 ry 2 — Q — ry a c rL y a a _ 7 H A J p m E er A E a E 4 y r E E d E x Q y O � O O Q d q E E ! 7 y > 7 Q .n ¢ E E E y E E E E m v v E M E E E E 6 E E E E E E N .� M N O - .� ry ,. in N ry 3 •_ .. _ N ry = N U' c O Y p q C Y o Y M - n eN ry, a N N O o O y 29 H T m o L rn E M rn m m m m 4 c� a a a a a a a CL l9 U L? l7 U Q U U L7 Q O V LM a a a [7 us �7 m m m m m m m m 1 d Q Q Q Q d 0 } > a } } ut y m Q ? 2 3 4 5 6 . 7 8 9 10 11 12 pH Adjustment Log for Preserved Samples Sample ID Typeof Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot 4 Note: Whenever there is a discrepancy affecting North Carolina compllance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (I.E. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 11 of 12 Page 14 of 17 CL tA a, a v CD O L N N to 41 ,y } NQ0U N f17 � N �C Z o aQ Q Y d (Cull CL l� V u v O IL x W M ir} L � a CL.. &i0 to r r N m ym y L ! CL C. O W W w D C,n c� Q m L u J IJpp � U � N Y 0CO u CL [%1 0 Ln U o� G li z •� a rr C 3 n N co N i 11 u Q' z N 7 67 O C Q Y h 00 0. OD = n —� O fi cJ O o � � I v i a I i r — N t— y� J 7 7 c r- c cm c y .� .0 C •C c a a r`a u N^ N m N m GI N= N= N= W Ln�n �- V) .�. z G N N N a a a a z° Ln J rn rn rn t H d z 19 L Ct O O N E:o o a H v o i7 0 0 LO o N N N iv r a Q co co h M M iA v v v O NO C) fn m a o 0 0 O N N N z. CD col O t O O O O w to � N N N O O w An 3 W CY w 0 u z v v z racu ' e E ,� 0 0 � c c i � v T v W n, O c E E N a L Ln o E E a F L Y ate+ amo rn .v m 11 m m �i cbir d E m 6 C Q G in Floge 12 of 12 Page 15 of 17 WayPAoint. NALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Shipment Receipt Form Customer Number: 01015 Customer Name: Anchor QEA of North Carolina, PLLC Report Number: 22-069-0032 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client # Courier 0 Other: Thermometer ID: IRT-15 2.3C Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers/boxes received F Custody seals intact on shipping container/cooler? 0 Yes 0 No # Not Present Custody seals intact on sample bottles? 0 Yes 0 No # Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample Iabel(s)? # Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? U Yes 0 No Sample containers intact? 0 Yes 0 No Sufficient sample volume for indicated test(s)? U Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? 0 Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. U Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No 0 N/A Water - VOA vials free of headspace 0 Yes 0 No 0 N/A Trip Blanks received with VOAs 0 Yes 0 No 0 N/A Soil VOA method 5035 — compliance criteria met F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) Special precautions or instructions included? Comments: 0 Yes 0 No U N/A F Low concentration EnCore samplers (48 hr) Low conc pre -weighed vials (Sod Bis -14 d) 0Yes ONo Signature: Sarah J. Locklear Date & Time: 03/10/2022 15:06:29 Page 16 of 17 u C L a N i 1 m 0 3 3 fFl nG N � C%' 3 OR _ x nm l N� �1 O vmva —i 7 � mp ---t- I r-- I -,;-, T �E m fA a a?u?mm_7 [D 0 p 5i O I^ r m C W 0 a o4 -0 i 11 0 h x n U a C _ 3 3 a A z j N V1 a-" mT, m 77 0. v m w a� ° ❑ m 0 cf^ m mT�� z 0 K�1 L L7 p 2 z' o m 0 R! Z qe 5w i n er w L z❑ tD y m N m a N 0 ` 0 EL a z. L W [G rz a n r � nm rlx Q ❑ OU:T C y N 1 S C m P m m HT D C VnH maw r� m � a�Lj a N r m051 cn 0 a oCL ti w µ N G w W � V! `C � � n rn `v n o = Q � v m a o' r , m v_ Q Z m. ❑ m rn f10 C x 14 m Z N (mar- z' d x Q M rn x 03 0 z Z T v G M m n 4 O O M r d 3 3 n ( n Ir 0 a � m w y"3 f° ID a. o� ^y M n� ti n >0 do s > fop 153 C\�'1 151p @. Nz �n 1 ! Iw N • P.M z O z 'a Page 17 of 17 Waypointo ANALYTICAL 3/22/2022 Anchor QEA of North Carolina, PLLC Chuck Pippin 231 Haywood Street Asheville, NC, 28801 449 5pringbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Ref: Analytical Testing Lab Report Number: 22-069-0024 Client Project Description: Jackson County Landfill GW C11460-01.02 Task 02 Site: 58-02 Project Number: 58-02 Dear Chuck Pippin: Waypoint Analytical, LLC (Charlotte) received sample(s) on 3/10/2022 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, a,j Angela D Overcash Senior Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 84 Waypoint.0 ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date North Carolina State Program 37735 07/31/2022 North Carolina State Program 402 12/31/2022 South Carolina State Program 99012 07/31/2022 South Carolina State Program 99012 12/31/2022 Page 1 of 1 00016/22-069-0024 Page 2 of 84 Waypoint.(2) ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Sample Summary Table Report Number: 22-069-0024 Client Project Description: Jackson County Landfill GW C11460-01.02 Task 02 Lab No Client Sample ID Matrix Date Collected Date Received 95874 MW-01-20220308 Aqueous 03/08/2022 15:08 03/10/2022 11:15 95875 MW-02-20220308 Aqueous 03/08/2022 15:40 03/10/2022 11:15 95876 MW-03-20220308 Aqueous 03/08/2022 09:40 03/10/2022 11:15 95877 MW-04-20220307 Aqueous 03/07/2022 11:05 03/10/2022 11:15 95878 MW-05R-20220307 Aqueous 03/07/2022 14:40 03/10/2022 11:15 95879 MW-06-20220308 Aqueous 03/08/2022 11:31 03/10/2022 11:15 95880 MW-07-20220307 Aqueous 03/07/2022 12:21 03/10/2022 11:15 95881 SW-01-20220307 Aqueous 03/07/2022 11:02 03/10/2022 11:15 95882 SW-02-20220307 Aqueous 03/07/2022 13:20 03/10/2022 11:15 95883 SW-03-20220307 Aqueous 03/07/2022 13:43 03/10/2022 11:15 95884 LT-01-20220307 Aqueous 03/07/2022 14:23 03/10/2022 11:15 95885 TB-20220307 Aqueous 03/07/2022 03/10/2022 11:15 95886 TB-20220308 Aqueous 03/07/2022 03/10/2022 11:15 Page 3 of 84 (2) Waypoint. 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointana lyti ca I som Summary of Detected Analytes Project: Jackson County Landfill GW Report Number: 22-069-0024 Client Sample ID Lab Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers MW-01-20220308 V 95874 6020B Barium 113 pq/L 3.40 03/15/202219:14 6020B Dissolved Barium 108 Ng/L 3.40 03/15/2022 20:53 6020B Cadmium 0.687 uq/L 0.150 03/15/202219:14 1 6020B Chromium 1.21 Ng/L 1.00 03/15/202219:14 1 6020B Cobalt 112 uq/L 0.080 03/15/202219:14 6020B Dissolved Cobalt 106 Ng/L 0.080 03/15/2022 20:53 6020B Copper 3.25 uq/L 0.890 03/15/202219:14 6020B Dissolved Nickel 13.8 pg/L 0.720 03/15/2022 20:53 6020B Nickel 15.3 uq/L 0.720 03/15/202219:14 6020B Thallium 0.553 pg/L 0.280 03/15/202219:14 1 6020B Dissolved Thallium 0.717 pq/L 0.280 03/15/2022 20:53 1 6020B Zinc 37.5 Ng/L 3.90 03/15/202219:14 6020B Dissolved Zinc 15.2 pq/L 3.90 03/15/2022 20:53 1 8260D Acetone 3.07 pg/L 1.80 03/14/2022 20:51 1 8260D Benzene 0.721 uq/L 0.180 03/14/2022 20:51 8260D 1,4-Dichlorobenzene 7.44 Ng/L 0.210 03/14/2022 20:51 8260D 1,1-Dichloroethane 1.80 pq/L 0.240 03/14/2022 20:51 8260D cis-1,2-Dichloroethene 2.17 pg/L 0.200 03/14/2022 20:51 8260D Tetrachloroethene 0.390 uq/L 0.220 03/14/2022 20:51 1 8260D Trichloroethene 0.350 Ng/L 0.180 03/14/2022 20:51 1 MW-02-20220308 V 95875 6020B Arsenic 6.36 pq/L 2.45 03/15/202219:21 6020B Barium 222 Ng/L 17.0 03/15/202219:21 6020B Dissolved Barium 34.6 uq/L 3.40 03/15/2022 21:39 6020B Beryllium 1.50 Ng/L 1.20 03/15/202219:21 1 6020B Chromium 44.0 uq/L 5.00 03/15/202219:21 6020B Cobalt 40.4 Ng/L 0.400 03/15/202219:21 6020B Dissolved Cobalt 9.49 uq/L 0.080 03/15/2022 21:39 6020B Copper 47.9 Ng/L 4.45 03/15/202219:21 6020B Lead 11.5 uq/L 2.50 03/15/202219:21 6020B Dissolved Nickel 7.11 Ng/L 0.720 03/15/2022 21:39 6020B Nickel 33.7 uq/L 3.60 03/15/202219:21 6020B Vanadium 53.9 Ng/L 10.5 03/16/202217:04 6020B Zinc 102 uq/L 19.5 03/15/202219:21 8260D Acetone 2.73 Ng/L 1.80 03/14/2022 21:18 1 8260D 1,1-Dichloroethane 0.348 pg/L 0.240 03/14/2022 21:18 1 Page 4 of 84 Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointana lyti ca I som Summary of Detected Analytes Project: Jackson County Landfill GW Report Number: 22-069-0024 Client Sample ID Lab Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers MW-02-20220308 V 95875 8260D SIM 1,4-Dioxane 3.04 pq/L 0.139 03/11/2022 15:30 MW-03-20220308 V 95876 6020B Arsenic 0.663 Ng/L 0.490 03/15/202219:27 1 6020B Barium 120 pq/L 3.40 03/15/202219:27 6020B Dissolved Barium 112 Ng/L 3.40 03/15/2022 21:45 6020B Chromium 1.75 uq/L 1.00 03/15/202219:27 1 6020B Cobalt 2.82 Ng/L 0.080 03/15/202219:27 6020B Dissolved Cobalt 0.140 uq/L 0.080 03/15/2022 21:45 1 6020B Copper 4.12 Ng/L 0.890 03/15/202219:27 6020B Dissolved Copper 1.96 uq/L 0.890 03/15/2022 21:45 1 6020B Dissolved Nickel 0.744 Ng/L 0.720 03/15/2022 21:45 1 6020B Nickel 1.77 uq/L 0.720 03/15/202219:27 1 6020B Zinc 5.68 Ng/L 3.90 03/15/202219:27 1 8260D Acetone 3.08 pq/L 1.80 03/14/202216:21 1 MW-04-20220307 V 95877 6020B Barium 67.6 Ng/L 3.40 03/15/202219:34 6020B Cadmium 0.370 pq/L 0.150 03/15/202219:34 1 6020B Cobalt 2.99 Ng/L 0.080 03/15/202219:34 6020B Nickel 2.07 uq/L 0.720 03/15/202219:34 6020B Zinc 5.39 Ng/L 3.90 03/15/202219:34 1 7470A Mercury (Total) 0.120 uq/L 0.0700 03/16/2022 18:26 1 8260D Acetone 2.41 Ng/L 1.80 03/14/2022 20:24 1 8260D Benzene 0.226 uq/L 0.180 03/14/2022 20:24 1 8260D 1,4-Dichlorobenzene 2.20 pq/L 0.210 03/14/2022 20:24 8260D cis-1,2-Dichloroethene 0.645 pq/L 0.200 03/14/2022 20:24 8260D SIM 1,4-Dioxane 6.29 Ng/L 0.139 03/11/2022 16:21 MW-05R-20220307 V 95878 6020B Barium 119 pq/L 3.40 03/15/202219:40 6020B Dissolved Barium 81.8 Ng/L 3.40 03/15/2022 21:52 6020B Cobalt 12.7 uq/L 0.080 03/15/202219:40 6020B Dissolved Cobalt 11.3 Ng/L 0.080 03/15/2022 21:52 6020B Dissolved Nickel 2.25 uq/L 0.720 03/15/2022 21:52 1 6020B Nickel 2.65 Ng/L 0.720 03/15/202219:40 8260D Acetone 2.36 uq/L 1.80 03/14/202216:48 1 8260D Benzene 2.06 Ng/L 0.180 03/14/202216:48 Page 5 of 84 Waypoint.(2) ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lytica Isom Summary of Detected Project: Jackson County Landfill GW Report Number: 22-069-0024 Client Sample ID Lab Sample ID Method Parameters Result Units Report Limit Analyzed MW-05R-20220307 V 95878 8260D Chlorobenzene 8.04 pq/L 0.190 03/14/202216:48 8260D Chloroethane 0.505 Ng/L 0.430 03/14/202216:48 8260D 1,2-Dichlorobenzene 0.335 uq/L 0.220 03/14/202216:48 8260D 1,4-Dichlorobenzene 7.93 Ng/L 0.210 03/14/202216:48 8260D cis- 1,2-Dichloroethene 1.88 uq/L 0.200 03/14/202216:48 8260D Tetrahydrofuran 2.28 Ng/L 1.50 03/14/202216:48 8260D Vinyl Chloride 1.01 pg/L 0.170 03/14/2022 16:48 8260D SIM 1,4-Dioxane 6.50 Ng/L 0.139 03/11/2022 16:46 MW-06-20220308 V 95879 6020B Barium 46.8 pq/L 3.40 03/15/202219:47 6020B Cobalt 15.8 Ng/L 0.080 03/15/202219:47 6020B Copper 0.906 uq/L 0.890 03/15/202219:47 6020B Nickel 4.93 Ng/L 0.720 03/15/202219:47 6020B Thallium 0.308 uq/L 0.280 03/15/202219:47 6020B Zinc 16.5 Ng/L 3.90 03/15/202219:47 7470A Mercury (Total) 0.130 uq/L 0.0700 03/16/2022 18:38 8260D Acetone 3.55 Ng/L 1.80 03/14/202217:15 8260D 1,4-Dichlorobenzene 1.41 uq/L 0.210 03/14/202217:15 8260D 1,1-Dichloroethane 0.977 Ng/L 0.240 03/14/202217:15 8260D cis- 1,2-Dichloroethene 0.942 uq/L 0.200 03/14/202217:15 8260D m,p-Xylene 0.548 Ng/L 0.420 03/14/202217:15 8260D Xylene (Total) 0.548 pq/L 0.210 03/14/2022 17:15 MW-07-20220307 V 95880 6020B Barium 405 Ng/L 3.40 03/15/2022 20:07 6020B Cobalt 2.12 uq/L 0.080 03/15/2022 20:07 6020B Nickel 7.92 pg/L 0.720 03/15/2022 20:07 6020B Zinc 7.69 pq/L 3.90 03/15/2022 20:07 8260D Benzene 1.52 Ng/L 0.180 03/14/202217:42 8260D Chlorobenzene 4.47 pq/L 0.190 03/14/202217:42 8260D 1,2-Dichlorobenzene 0.304 pg/L 0.220 03/14/202217:42 8260D 1,4-Dichlorobenzene 5.54 uq/L 0.210 03/14/202217:42 8260D cis- 1,2-Dichloroethene 1.89 Ng/L 0.200 03/14/202217:42 8260D 1,4-Dioxane 17.1 pq/L 16.0 03/14/202217:42 8260D SIM 1,4-Dioxane 20.2 Ng/L 0.139 03/11/2022 17:36 Qualifiers I J 0 I I J 0 0 Page 6 of 84 Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointana lyti ca I som Summary of Detected Analytes Project: Jackson County Landfill GW Report Number: 22-069-0024 Client Sample ID Lab Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers SW-01-20220307 V 95881 2340C-2011 Hardness 9000 pq/L 570 03/18/202212:50 6020B Barium 20.6 Ng/L 3.40 03/15/2022 20:13 6020B Chromium 1.52 uq/L 1.00 03/15/2022 20:13 1 6020B Cobalt 0.595 Ng/L 0.080 03/15/2022 20:13 1 6020B Copper 1.22 uq/L 0.890 03/15/2022 20:13 1 6020B Lead 0.501 Ng/L 0.500 03/15/2022 20:13 1 6020B Nickel 1.59 uq/L 0.720 03/15/2022 20:13 1 6020B Vanadium 3.02 pg/L 2.10 03/16/202217:43 1 8260D Acetone 2.01 pg/L 1.80 03/14/202218:09 1 SW-02-20220307 V 95882 2340C-2011 Hardness 6000 Ng/L 570 03/18/202212:50 6020B Barium 18.6 uq/L 3.40 03/15/2022 20:20 6020B Chromium 1.36 Ng/L 1.00 03/15/2022 20:20 1 6020B Cobalt 0.460 uq/L 0.080 03/15/2022 20:20 1 6020B Copper 1.00 Ng/L 0.890 03/15/2022 20:20 1 6020B Vanadium 2.64 uq/L 2.10 03/16/202217:50 1 8260D Acetone 2.06 Ng/L 1.80 03/14/202218:36 1 SW-03-20220307 V 95883 2340C-2011 Hardness 6000 pq/L 570 03/18/202212:50 6020B Barium 13.9 Ng/L 3.40 03/15/2022 20:26 6020B Cobalt 0.200 uq/L 0.080 03/15/2022 20:26 1 6020B Vanadium 2.11 Ng/L 2.10 03/16/202218:09 1 8260D Acetone 2.12 pg/L 1.80 03/14/202219:03 1 LT-01-20220307 V 95884 6020B Arsenic 3.70 Ng/L 0.490 03/15/2022 20:33 6020B Barium 309 uq/L 3.40 03/15/2022 20:33 6020B Chromium 4.70 Ng/L 1.00 03/15/2022 20:33 6020B Cobalt 6.34 uq/L 0.080 03/15/2022 20:33 6020B Copper 2.34 Ng/L 0.890 03/15/2022 20:33 6020B Nickel 30.5 uq/L 0.720 03/15/2022 20:33 6020B Vanadium 4.46 Ng/L 2.10 03/16/202218:16 1 6020B Zinc 4.29 uq/L 3.90 03/15/2022 20:33 1 8260D Acetone 6.41 Ng/L 1.80 03/14/202219:30 8260D Benzene 1.48 uq/L 0.180 03/14/202219:30 8260D Chlorobenzene 4.18 Ng/L 0.190 03/14/202219:30 Page 7 of 84 Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointana lyti ca I som Summary of Detected Analytes Project: Jackson County Landfill GW Report Number: 22-069-0024 Client Sample ID Lab Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers LT-01-20220307 V 95884 8260D 1,4-Dichlorobenzene 8260D 1,4-Dioxane 8260D Tetra hyd rofu ra n 8260D SIM 1,4-Dioxane 1.68 pq/L 0.210 03/14/202219:30 107 Ng/L 16.0 03/14/202219:30 168 uq/L 15.0 03/16/202215:37 106 pg/L 0.139 03/11/202219:17 0 Page 8 of 84 Waypointo ANALYTICAL Client: Anchor QEA of North Carolina, PLLC Project: Jackson County Landfill GW Lab Report Number: 22-069-0024 Date: 3/21 /2022 449 5pringbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Metals Analyses Method 6020B Sample 95880 (MW-07-20220307) Analyte: Silver QC Batch No: V16151/V16097 CCB failed high. Sample concentration BRL. Results not affected. Sample 95881 (SW-01-20220307) Analyte: Silver QC Batch No: V16151/V16097 CCB failed high. Sample concentration BRL. Results not affected. Sample 95882 (SW-02-20220307) Analyte: Silver QC Batch No: V16151/V16097 CCB failed high. Sample concentration BRL. Results not affected. Sample 95883 (SW-03-20220307) Analyte: Silver QC Batch No: V16151/V16097 CCB failed high. Sample concentration BRL. Results not affected. Sample 95884 (LT-01-20220307) Analyte: Silver QC Batch No: V16151/V16097 CCB failed high. Sample concentration BRL. Results not affected. CASE NARRATIVE Sample 95757 (UT1-6-WS-030822) Analyte: Zinc QC Batch No: V16291/V16097 The MS/MSD recoveries are outside QC limits due to the level of analyte present in the parent sample relative to the spike level. RPD is based on the MS/MSD results and should be evaluated as laboratory duplicates. Sample 95875 (MW-02-20220308) QC Batch No: V16151/V16136/V16055 The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly. Sample 95875 (MW-02-20220308) QC Batch No: V16227/V16136/V16055 The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly. Sample 95874 (MW-01-20220308) QC Batch No: V16397/V16136/V16055 The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly. Sample 95875 (MW-02-20220308) Page 9 of 84 Waypointo ANALYTICAL 449 5pringbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com QC Batch No: V16397/V16136/V16055 The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly. Analyte: Silver QC Batch No: V16152/V16136/V16055 CCB failed high. Sample concentration BRL or 10X concentration. Results not affected. Analyte: Vanadium QC Batch No: V16152/V16136/V16055 LLICV failed high. Sample concentration BRL. Results not affected. Analyte: Antimony QC Batch No: V16151/V16396/V16395 LLICV failed high. Sample concentration BRL. Results not affected. Analyte: Antimony QC Batch No: V16397/V16396/V16395 CCB failed high. Sample concentraiton BRL. Results not affected. Page 10 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95874 Matrix: Aqueous Sample ID: MW-01-20220308 Sampled: 3/8/2022 15:08 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane <0.139 N9/L 0.139 2.00 1 03/11/22 15:05 TBL 8260D SIM Antimony <0.680 u9/L 0.680 2.00 1 03/15/22 19:14 EDV 6020B Dissolved Antimony <3.40 N9/L 3.40 10.0 5 03/21/22 16:12 EDV 6020E Arsenic <0.490 u9/L 0.490 1.00 1 03/15/22 19:14 EDV 6020B Dissolved Arsenic <0.490 N9/L 0.490 1.00 1 03/15/22 20:53 EDV 6020E Barium 113 u9/L 3.40 10.0 1 03/15/22 19:14 EDV 6020B Dissolved Barium 108 N9/L 3.40 10.0 1 03/15/22 20:53 EDV 6020E Beryllium <0.240 u9/L 0.240 1.00 1 03/15/22 19:14 EDV 6020B Dissolved Beryllium <0.240 N9/L 0.240 1.00 1 03/15/22 20:53 EDV 6020E Cadmium 0.687 J u9/L 0.150 1.00 1 03/15/22 19:14 EDV 6020B Dissolved Cadmium <0.150 N9/L 0.150 1.00 1 03/15/22 20:53 EDV 6020E Chromium 1.21 J u9/L 1.00 2.00 1 03/15/22 19:14 EDV 6020B Dissolved Chromium <1.00 N9/L 1.00 2.00 1 03/15/22 20:53 EDV 6020E Cobalt 112 u9/L 0.080 1.00 1 03/15/22 19:14 EDV 6020B Dissolved Cobalt 106 N9/L 0.080 2.00 1 03/15/22 20:53 EDV 6020E Copper 3.25 u9/L 0.890 2.00 1 03/15/22 19:14 EDV 6020B Dissolved Copper <0.890 N9/L 0.890 10.0 1 03/15/22 20:53 EDV 6020E Lead <0.500 u9/L 0.500 1.00 1 03/15/22 19:14 EDV 6020B Dissolved Lead <0.500 N9/L 0.500 1.00 1 03/15/22 20:53 EDV 6020E Mercury (Total) <0.0700 u9/L 0.0700 0.200 1 03/16/22 18:01 EDV 7470A Dissolved Mercury <0.0700 N9/L 0.0700 0.200 1 03/15/22 15:13 EDV 7470A Dissolved Nickel 13.8 u9/L 0.720 3.00 1 03/15/22 20:53 EDV 6020B Nickel 15.3 N9/L 0.720 2.00 1 03/15/22 19:14 EDV 6020B Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 11 of 84 • Waypdint0 449 Springbrook Rd, Charlotte, .5 282& Main 704.529.636� ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Chuck Pippin 231 Haywood Street Asheville , NC 28801 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill GW Report Date : 03/22/2022 Information : C11460-01.02 Task 02 Received : 03/10/2022 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95874 Sample ID: MW-01-20220308 Matrix: Aqueous Sampled: 3/8/2022 15:08 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Selenium <2.30 Ng/L 2.30 5.00 1 03/15/2219:14 EDV 6020B Dissolved Selenium <2.30 pg/L 2.30 5.00 1 03/15/22 20:53 EDV 6020B Silver <0.130 N9/L 0.130 1.00 1 03/15/2219:14 EDV 6020B Dissolved Silver <0.130 u9/L 0.130 1.00 1 03/15/22 20:53 EDV 6020B Thallium 0.5533 N9/L 0.280 2.00 1 03/15/22 19:14 EDV 6020B Dissolved Thallium 0.7173 u9/L 0.280 2.00 1 03/15/22 20:53 EDV 6020B Vanadium <2.10 N9/L 2.10 5.00 1 03/16/2216:58 EDV 6020B Dissolved Vanadium <2.10 u9/L 2.10 5.00 1 03/15/22 20:53 EDV 6020B Zinc 37.5 N9/L 3.90 20.0 1 03/15/2219:14 EDV 6020B Dissolved Zinc 15.23 u9/L 3.90 20.0 1 03/15/22 20:53 EDV 6020B Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit J Estimated value Page 12 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95874 Matrix: Aqueous Sample ID: MW-01-20220308 Sampled: 3/8/2022 15:08 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 3.073 Ng/L 1.80 5.00 1 03/14/22 20:51 JLB V16104 Acrylonitrile <0.230 u9/L 0.230 5.00 1 03/14/22 20:51 JLB V16104 Benzene 0.721 N9/L 0.180 0.500 1 03/14/22 20:51 JLB V16104 Bromochloromethane <0.420 u9/L 0.420 1.00 1 03/14/22 20:51 JLB V16104 Bromodichloromethane <0.160 N9/L 0.160 0.500 1 03/14/22 20:51 JLB V16104 Bromoform <1.50 u9/L 1.50 5.00 1 03/14/22 20:51 JLB V16104 Bromomethane <0.280 N9/L 0.280 1.00 1 03/14/22 20:51 JLB V16104 Carbon Disulfide <0.150 u9/L 0.150 5.00 1 03/14/22 20:51 JLB V16104 Carbon Tetrachloride <0.180 N9/L 0.180 0.500 1 03/14/22 20:51 JLB V16104 Chlorobenzene <0.190 u9/L 0.190 0.500 1 03/14/22 20:51 JLB V16104 Chlorodibromomethane <0.190 N9/L 0.190 0.500 1 03/14/22 20:51 JLB V16104 Chloroethane <0.430 u9/L 0.430 1.00 1 03/14/22 20:51 JLB V16104 Chloroform <0.220 N9/L 0.220 0.500 1 03/14/22 20:51 JLB V16104 Chloromethane <0.220 u9/L 0.220 0.500 1 03/14/22 20:51 JLB V16104 Di -Isopropyl Ether (DIPE) <0.960 N9/L 0.960 5.00 1 03/14/22 20:51 JLB V16104 1,2-Dibromo-3-Chloropropane <1.10 u9/L 1.10 2.00 1 03/14/22 20:51 JLB V16104 1,2-Dibromoethane <0.200 N9/L 0.200 0.500 1 03/14/22 20:51 JLB V16104 Dibromomethane <0.230 u9/L 0.230 0.500 1 03/14/22 20:51 JLB V16104 trans-1,4-Dichloro-2-butene <1.30 N9/L 1.30 10.0 1 03/14/22 20:51 JLB V16104 1,2-Dichlorobenzene <0.220 u9/L 0.220 0.500 1 03/14/22 20:51 JLB V16104 1,4-Dichlorobenzene 7.44 N9/L 0.210 0.500 1 03/14/22 20:51 JLB V16104 Dichlorodifluoromethane <1.20 u9/L 1.20 5.00 1 03/14/22 20:51 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 13 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95874 Matrix: Aqueous Sample ID: MW-01-20220308 Sampled: 3/8/2022 15:08 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane 1.80 Ng/L 0.240 0.500 1 03/14/22 20:51 JLB V16104 1,2-Dichloroethane <0.150 u9/L 0.150 0.500 1 03/14/22 20:51 JLB V16104 1,1-Dichloroethene <0.150 N9/L 0.150 0.500 1 03/14/22 20:51 JLB V16104 cis- 1,2-Dich loroethene 2.17 u9/L 0.200 0.500 1 03/14/22 20:51 JLB V16104 trans-1,2-Dichloroethene <0.180 N9/L 0.180 0.500 1 03/14/22 20:51 JLB V16104 1,2-Dichloropropane <0.190 u9/L 0.190 0.500 1 03/14/22 20:51 JLB V16104 cis- 1,3-Dich loropropene <0.210 N9/L 0.210 0.500 1 03/14/22 20:51 JLB V16104 trans-1,3-Dichloropropene <0.150 u9/L 0.150 0.500 1 03/14/22 20:51 JLB V16104 1,4-Dioxane <16.0 N9/L 16.0 150 1 03/14/22 20:51 JLB V16104 Ethylbenzene <0.170 u9/L 0.170 0.500 1 03/14/22 20:51 JLB V16104 2-Hexanone <0.380 N9/L 0.380 5.00 1 03/14/22 20:51 JLB V16104 Methyl Ethyl Ketone (MEK) <0.710 u9/L 0.710 5.00 1 03/14/22 20:51 JLB V16104 4-Methyl-2-Pentanone <1.00 N9/L 1.00 5.00 1 03/14/22 20:51 JLB V16104 Methylene Chloride <0.330 u9/L 0.330 1.00 1 03/14/22 20:51 JLB V16104 Styrene <0.220 N9/L 0.220 0.500 1 03/14/22 20:51 JLB V16104 1,1,1,2-Tetrachloroethane <0.160 u9/L 0.160 0.500 1 03/14/22 20:51 JLB V16104 1,1,2,2-Tetrachloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 20:51 JLB V16104 Tetrachloroethene 0.3903 u9/L 0.220 0.500 1 03/14/22 20:51 JLB V16104 Tetrahydrofuran <1.50 N9/L 1.50 10.0 1 03/14/22 20:51 JLB V16104 Toluene <0.220 u9/L 0.220 0.500 1 03/14/22 20:51 JLB V16104 1,1,1-Trichloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 20:51 JLB V16104 1,1,2-Trichloroethane <0.096 u9/L 0.096 0.500 1 03/14/22 20:51 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 14 of 84 • Waypdint0 449 Springbrook Rd, Charlotte, .5 282& Main 704.529.636� ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Chuck Pippin 231 Haywood Street Asheville , NC 28801 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill GW Report Date : 03/22/2022 Information : C11460-01.02 Task 02 Received : 03/10/2022 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95874 Matrix: Aqueous Sample ID: MW-01-20220308 Sampled: 3/8/2022 15:08 Analytical Method: 8260D Prep Method: 5030E Test Results Trichloroethene 0.3503 Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Prep Batch(es): V16102 03/14/22 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.180 0.500 Ng/L 0.270 1.00 Pg/L 1.00 2.00 Ng/L 0.170 0.500 Pg/L 0.210 0.500 Ng/L 0.420 1.00 Pg/L 0.210 0.500 107 Limits: 80-124% 95.4 Limits: 75-129% 98.0 Limits: 63-136% 95.2 Limits: 77-123% 1 03/14/22 20:51 JLB V16104 1 03/14/22 20:51 JLB V16104 1 03/14/22 20:51 JLB V16104 1 03/14/22 20:51 JLB V16104 1 03/14/22 20:51 JLB V16104 1 03/14/22 20:51 JLB V16104 1 03/14/22 20:51 JLB V16104 1 03/14/22 20:51 V16104 1 03/14/22 20:51 JLB V16104 1 03/14/22 20:51 JLB V16104 1 03/14/22 20:51 JLB V16104 1 03/14/22 20:51 JLB V16104 J Estimated value Page 15 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95875 Matrix: Aqueous Sample ID: MW-02-20220308 Sampled: 3/8/2022 15:40 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane 3.04 Ng/L 0.139 2.00 1 03/11/22 15:30 TBL 8260D SIM Antimony <3.40 ug/L 3.40 10.0 5 03/15/22 19:21 EDV 6020B Dissolved Antimony <3.40 Ng/L 3.40 10.0 5 03/21/22 16:22 EDV 6020B Arsenic 6.36 ug/L 2.45 5.00 5 03/15/22 19:21 EDV 6020B Dissolved Arsenic <0.490 Ng/L 0.490 1.00 1 03/15/22 21:39 EDV 6020B Barium 222 ug/L 17.0 50.0 5 03/15/22 19:21 EDV 6020B Dissolved Barium 34.6 Ng/L 3.40 10.0 1 03/15/22 21:39 EDV 6020B Beryllium 1.503 ug/L 1.20 5.00 5 03/15/22 19:21 EDV 6020B Dissolved Beryllium <0.240 Ng/L 0.240 1.00 1 03/17/22 18:40 EDV 6020B Cadmium <0.750 ug/L 0.750 5.00 5 03/15/22 19:21 EDV 6020B Dissolved Cadmium <0.150 Ng/L 0.150 1.00 1 03/15/22 21:39 EDV 6020B Chromium 44.0 ug/L 5.00 10.0 5 03/15/22 19:21 EDV 6020B Dissolved Chromium <1.00 Ng/L 1.00 2.00 1 03/15/22 21:39 EDV 6020B Cobalt 40.4 ug/L 0.400 5.00 5 03/15/22 19:21 EDV 6020B Dissolved Cobalt 9.49 Ng/L 0.080 2.00 1 03/15/22 21:39 EDV 6020B Copper 47.9 ug/L 4.45 10.0 5 03/15/22 19:21 EDV 6020B Dissolved Copper <0.890 Ng/L 0.890 10.0 1 03/15/22 21:39 EDV 6020B Lead 11.5 ug/L 2.50 5.00 5 03/15/22 19:21 EDV 6020B Dissolved Lead <0.500 Ng/L 0.500 1.00 1 03/15/22 21:39 EDV 6020B Mercury (Total) <0.0700 ug/L 0.0700 0.200 1 03/16/22 18:21 EDV 7470A Dissolved Mercury <0.0700 Ng/L 0.0700 0.200 1 03/15/22 15:16 EDV 7470A Dissolved Nickel 7.11 ug/L 0.720 3.00 1 03/15/22 21:39 EDV 6020B Nickel 33.7 Ng/L 3.60 10.0 5 03/15/22 19:21 EDV 6020B Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 16 of 84 • Waypdint0 449 Springbrook Rd, Charlotte, .5 282& Main 704.529.636� ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Chuck Pippin 231 Haywood Street Asheville , NC 28801 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill GW Report Date : 03/22/2022 Information : C11460-01.02 Task 02 Received : 03/10/2022 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95875 Sample ID: MW-02-20220308 Matrix: Aqueous Sampled: 3/8/2022 15:40 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Selenium <11.5 Ng/L 11.5 25.0 5 03/15/2219:21 EDV 6020B Dissolved Selenium <2.30 pg/L 2.30 5.00 1 03/15/22 21:39 EDV 6020B Silver <0.650 N9/L 0.650 5.00 5 03/15/2219:21 EDV 6020B Dissolved Silver <0.130 u9/L 0.130 1.00 1 03/15/22 21:39 EDV 6020B Thallium <1.40 N9/L 1.40 10.0 5 03/15/2219:21 EDV 6020B Dissolved Thallium <0.280 u9/L 0.280 2.00 1 03/15/22 21:39 EDV 6020B Vanadium 53.9 N9/L 10.5 25.0 5 03/16/2217:04 EDV 6020B Dissolved Vanadium <2.10 u9/L 2.10 5.00 1 03/15/22 21:39 EDV 6020B Zinc 102 N9/L 19.5 100 5 03/15/2219:21 EDV 6020B Dissolved Zinc <3.90 u9/L 3.90 20.0 1 03/15/22 21:39 EDV 6020B Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit J Estimated value Page 17 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95875 Matrix: Aqueous Sample ID: MW-02-20220308 Sampled: 3/8/2022 15:40 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 2.733 Ng/L 1.80 5.00 1 03/14/22 21:18 JLB V16104 Acrylonitrile <0.230 u9/L 0.230 5.00 1 03/14/22 21:18 JLB V16104 Benzene <0.180 N9/L 0.180 0.500 1 03/14/22 21:18 JLB V16104 Bromochloromethane <0.420 u9/L 0.420 1.00 1 03/14/22 21:18 JLB V16104 Bromodichloromethane <0.160 N9/L 0.160 0.500 1 03/14/22 21:18 JLB V16104 Bromoform <1.50 u9/L 1.50 5.00 1 03/14/22 21:18 JLB V16104 Bromomethane <0.280 N9/L 0.280 1.00 1 03/14/22 21:18 JLB V16104 Carbon Disulfide <0.150 u9/L 0.150 5.00 1 03/14/22 21:18 JLB V16104 Carbon Tetrachloride <0.180 N9/L 0.180 0.500 1 03/14/22 21:18 JLB V16104 Chlorobenzene <0.190 u9/L 0.190 0.500 1 03/14/22 21:18 JLB V16104 Chlorodibromomethane <0.190 N9/L 0.190 0.500 1 03/14/22 21:18 JLB V16104 Chloroethane <0.430 u9/L 0.430 1.00 1 03/14/22 21:18 JLB V16104 Chloroform <0.220 N9/L 0.220 0.500 1 03/14/22 21:18 JLB V16104 Chloromethane <0.220 u9/L 0.220 0.500 1 03/14/22 21:18 JLB V16104 Di -Isopropyl Ether (DIPE) <0.960 N9/L 0.960 5.00 1 03/14/22 21:18 JLB V16104 1,2-Dibromo-3-Chloropropane <1.10 u9/L 1.10 2.00 1 03/14/22 21:18 JLB V16104 1,2-Dibromoethane <0.200 N9/L 0.200 0.500 1 03/14/22 21:18 JLB V16104 Dibromomethane <0.230 u9/L 0.230 0.500 1 03/14/22 21:18 JLB V16104 trans-1,4-Dichloro-2-butene <1.30 N9/L 1.30 10.0 1 03/14/22 21:18 JLB V16104 1,2-Dichlorobenzene <0.220 u9/L 0.220 0.500 1 03/14/22 21:18 JLB V16104 1,4-Dichlorobenzene <0.210 N9/L 0.210 0.500 1 03/14/22 21:18 JLB V16104 Dichlorodifluoromethane <1.20 u9/L 1.20 5.00 1 03/14/22 21:18 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 18 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95875 Matrix: Aqueous Sample ID: MW-02-20220308 Sampled: 3/8/2022 15:40 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane 0.3483 Ng/L 0.240 0.500 1 03/14/22 21:18 JLB V16104 1,2-Dichloroethane <0.150 u9/L 0.150 0.500 1 03/14/22 21:18 JLB V16104 1,1-Dichloroethene <0.150 N9/L 0.150 0.500 1 03/14/22 21:18 JLB V16104 cis- 1,2-Dich loroethene <0.200 u9/L 0.200 0.500 1 03/14/22 21:18 JLB V16104 trans-1,2-Dichloroethene <0.180 N9/L 0.180 0.500 1 03/14/22 21:18 JLB V16104 1,2-Dichloropropane <0.190 u9/L 0.190 0.500 1 03/14/22 21:18 JLB V16104 cis- 1,3-Dich loropropene <0.210 N9/L 0.210 0.500 1 03/14/22 21:18 JLB V16104 trans-1,3-Dichloropropene <0.150 u9/L 0.150 0.500 1 03/14/22 21:18 JLB V16104 1,4-Dioxane <16.0 N9/L 16.0 150 1 03/14/22 21:18 JLB V16104 Ethylbenzene <0.170 u9/L 0.170 0.500 1 03/14/22 21:18 JLB V16104 2-Hexanone <0.380 N9/L 0.380 5.00 1 03/14/22 21:18 JLB V16104 Methyl Ethyl Ketone (MEK) <0.710 u9/L 0.710 5.00 1 03/14/22 21:18 JLB V16104 4-Methyl-2-Pentanone <1.00 N9/L 1.00 5.00 1 03/14/22 21:18 JLB V16104 Methylene Chloride <0.330 u9/L 0.330 1.00 1 03/14/22 21:18 JLB V16104 Styrene <0.220 N9/L 0.220 0.500 1 03/14/22 21:18 JLB V16104 1,1,1,2-Tetrachloroethane <0.160 u9/L 0.160 0.500 1 03/14/22 21:18 JLB V16104 1,1,2,2-Tetrachloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 21:18 JLB V16104 Tetrachloroethene <0.220 u9/L 0.220 0.500 1 03/14/22 21:18 JLB V16104 Tetrahydrofuran <1.50 N9/L 1.50 10.0 1 03/14/22 21:18 JLB V16104 Toluene <0.220 u9/L 0.220 0.500 1 03/14/22 21:18 JLB V16104 1,1,1-Trichloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 21:18 JLB V16104 1,1,2-Trichloroethane <0.096 u9/L 0.096 0.500 1 03/14/22 21:18 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 19 of 84 • Waypdint0 449 Springbrook Rd, Charlotte, .5 282& Main 704.529.636� ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Chuck Pippin 231 Haywood Street Asheville , NC 28801 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill GW Report Date : 03/22/2022 Information : C11460-01.02 Task 02 Received : 03/10/2022 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95875 Matrix: Aqueous Sample ID: MW-02-20220308 Sampled: 3/8/2022 15:40 Analytical Method: 8260D Prep Method: 5030E Test Results Trichloroethene <0.180 Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Prep Batch(es): V16102 03/14/22 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.180 0.500 Ng/L 0.270 1.00 Pg/L 1.00 2.00 Ng/L 0.170 0.500 Pg/L 0.210 0.500 Ng/L 0.420 1.00 Pg/L 0.210 0.500 109 Limits: 80-124% 93.6 Limits: 75-129% 97.0 Limits: 63-136% 93.4 Limits: 77-123% 1 03/14/22 21:18 JLB V16104 1 03/14/22 21:18 JLB V16104 1 03/14/22 21:18 JLB V16104 1 03/14/22 21:18 JLB V16104 1 03/14/22 21:18 JLB V16104 1 03/14/22 21:18 JLB V16104 1 03/14/22 21:18 JLB V16104 1 03/14/22 21:18 V16104 1 03/14/22 21:18 JLB V16104 1 03/14/22 21:18 JLB V16104 1 03/14/22 21:18 JLB V16104 1 03/14/22 21:18 JLB V16104 J Estimated value Page 20 of 84 WavDdibnto ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Chuck Pippin 231 Haywood Street Asheville , NC 28801 Report Number : 22-069-0024 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill GW Information : C11460-01.02 Task 02 REPORT OF ANAL YSIS Report Date : 03/22/2022 Received : 03/10/2022 Lab No : 95876 Matrix: Aqueous Sample ID: MW-03-20220308 Sampled: 3/8/2022 9:40 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane <0.139 N9/L 0.139 2.00 1 03/11/22 15:56 TBL 8260D SIM Antimony <0.680 u9/L 0.680 2.00 1 03/15/22 19:27 EDV 6020B Dissolved Antimony <0.680 N9/L 0.680 2.00 1 03/21/22 16:28 EDV 6020E Arsenic 0.6633 u9/L 0.490 1.00 1 03/15/22 19:27 EDV 6020B Dissolved Arsenic <0.490 N9/L 0.490 1.00 1 03/15/22 21:45 EDV 6020E Barium 120 u9/L 3.40 10.0 1 03/15/22 19:27 EDV 6020B Dissolved Barium 112 N9/L 3.40 10.0 1 03/15/22 21:45 EDV 6020E Beryllium <0.240 u9/L 0.240 1.00 1 03/15/22 19:27 EDV 6020B Dissolved Beryllium <0.240 N9/L 0.240 1.00 1 03/17/22 18:47 EDV 6020E Cadmium <0.150 u9/L 0.150 1.00 1 03/15/22 19:27 EDV 6020B Dissolved Cadmium <0.150 N9/L 0.150 1.00 1 03/15/22 21:45 EDV 6020E Chromium 1.75 J ug/L 1.00 2.00 1 03/15/22 19:27 EDV 6020B Dissolved Chromium <1.00 N9/L 1.00 2.00 1 03/15/22 21:45 EDV 6020E Cobalt 2.82 ug/L 0.080 1.00 1 03/15/22 19:27 EDV 6020B Dissolved Cobalt 0.140 J N9/L 0.080 2.00 1 03/15/22 21:45 EDV 6020E Copper 4.12 ug/L 0.890 2.00 1 03/15/22 19:27 EDV 6020B Dissolved Copper 1.96 J N9/L 0.890 10.0 1 03/15/22 21:45 EDV 6020E Lead <0.500 u9/L 0.500 1.00 1 03/15/22 19:27 EDV 6020B Dissolved Lead <0.500 N9/L 0.500 1.00 1 03/15/22 21:45 EDV 6020E Mercury (Total) <0.0700 u9/L 0.0700 0.200 1 03/16/22 18:24 EDV 7470A Dissolved Mercury <0.0700 N9/L 0.0700 0.200 1 03/15/22 14:49 EDV 7470A Dissolved Nickel 0.744 J ug/L 0.720 3.00 1 03/15/22 21:45 EDV 6020B Nickel 1.77 J N9/L 0.720 2.00 1 03/15/22 19:27 EDV 6020E Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 21 of 84 • Waypdint0 449 Springbrook Rd, Charlotte, .5 282& Main 704.529.636� ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Chuck Pippin 231 Haywood Street Asheville , NC 28801 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill GW Report Date : 03/22/2022 Information : C11460-01.02 Task 02 Received : 03/10/2022 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95876 Sample ID: MW-03-20220308 Matrix: Aqueous Sampled: 3/8/2022 9:40 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Selenium <2.30 Ng/L 2.30 5.00 1 03/15/2219:27 EDV 6020B Dissolved Selenium <2.30 pg/L 2.30 5.00 1 03/15/22 21:45 EDV 6020B Silver <0.130 N9/L 0.130 1.00 1 03/15/2219:27 EDV 6020B Dissolved Silver <0.130 u9/L 0.130 1.00 1 03/15/22 21:45 EDV 6020B Thallium <0.280 N9/L 0.280 2.00 1 03/15/2219:27 EDV 6020B Dissolved Thallium <0.280 u9/L 0.280 2.00 1 03/15/22 21:45 EDV 6020B Vanadium <2.10 N9/L 2.10 5.00 1 03/16/2217:11 EDV 6020B Dissolved Vanadium <2.10 u9/L 2.10 5.00 1 03/15/22 21:45 EDV 6020B Zinc 5.683 Ng/L 3.90 20.0 1 03/15/22 19:27 EDV 6020B Dissolved Zinc <3.90 u9/L 3.90 20.0 1 03/15/22 21:45 EDV 6020B Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit J Estimated value Page 22 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95876 Matrix: Aqueous Sample ID: MW-03-20220308 Sampled: 3/8/2022 9:40 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 3.083 Ng/L 1.80 5.00 1 03/14/22 16:21 JLB V16104 Acrylonitrile <0.230 u9/L 0.230 5.00 1 03/14/22 16:21 JLB V16104 Benzene <0.180 N9/L 0.180 0.500 1 03/14/22 16:21 JLB V16104 Bromochloromethane <0.420 u9/L 0.420 1.00 1 03/14/22 16:21 JLB V16104 Bromodichloromethane <0.160 N9/L 0.160 0.500 1 03/14/22 16:21 JLB V16104 Bromoform <1.50 u9/L 1.50 5.00 1 03/14/22 16:21 JLB V16104 Bromomethane <0.280 N9/L 0.280 1.00 1 03/14/22 16:21 JLB V16104 Carbon Disulfide <0.150 u9/L 0.150 5.00 1 03/14/22 16:21 JLB V16104 Carbon Tetrachloride <0.180 N9/L 0.180 0.500 1 03/14/22 16:21 JLB V16104 Chlorobenzene <0.190 u9/L 0.190 0.500 1 03/14/22 16:21 JLB V16104 Chlorodibromomethane <0.190 N9/L 0.190 0.500 1 03/14/22 16:21 JLB V16104 Chloroethane <0.430 u9/L 0.430 1.00 1 03/14/22 16:21 JLB V16104 Chloroform <0.220 N9/L 0.220 0.500 1 03/14/22 16:21 JLB V16104 Chloromethane <0.220 u9/L 0.220 0.500 1 03/14/22 16:21 JLB V16104 Di -Isopropyl Ether (DIPE) <0.960 N9/L 0.960 5.00 1 03/14/22 16:21 JLB V16104 1,2-Dibromo-3-Chloropropane <1.10 u9/L 1.10 2.00 1 03/14/22 16:21 JLB V16104 1,2-Dibromoethane <0.200 N9/L 0.200 0.500 1 03/14/22 16:21 JLB V16104 Dibromomethane <0.230 u9/L 0.230 0.500 1 03/14/22 16:21 JLB V16104 trans-1,4-Dichloro-2-butene <1.30 N9/L 1.30 10.0 1 03/14/22 16:21 JLB V16104 1,2-Dichlorobenzene <0.220 u9/L 0.220 0.500 1 03/14/22 16:21 JLB V16104 1,4-Dichlorobenzene <0.210 N9/L 0.210 0.500 1 03/14/22 16:21 JLB V16104 Dichlorodifluoromethane <1.20 u9/L 1.20 5.00 1 03/14/22 16:21 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 23 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95876 Matrix: Aqueous Sample ID: MW-03-20220308 Sampled: 3/8/2022 9:40 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 N9/L 0.240 0.500 1 03/14/22 16:21 JLB V16104 1,2-Dichloroethane <0.150 u9/L 0.150 0.500 1 03/14/22 16:21 JLB V16104 1,1-Dichloroethene <0.150 N9/L 0.150 0.500 1 03/14/22 16:21 JLB V16104 cis- 1,2-Dich loroethene <0.200 u9/L 0.200 0.500 1 03/14/22 16:21 JLB V16104 trans-1,2-Dichloroethene <0.180 N9/L 0.180 0.500 1 03/14/22 16:21 JLB V16104 1,2-Dichloropropane <0.190 u9/L 0.190 0.500 1 03/14/22 16:21 JLB V16104 cis- 1,3-Dich loropropene <0.210 N9/L 0.210 0.500 1 03/14/22 16:21 JLB V16104 trans-1,3-Dichloropropene <0.150 u9/L 0.150 0.500 1 03/14/22 16:21 JLB V16104 1,4-Dioxane <16.0 N9/L 16.0 150 1 03/14/22 16:21 JLB V16104 Ethylbenzene <0.170 u9/L 0.170 0.500 1 03/14/22 16:21 JLB V16104 2-Hexanone <0.380 N9/L 0.380 5.00 1 03/14/22 16:21 JLB V16104 Methyl Ethyl Ketone (MEK) <0.710 u9/L 0.710 5.00 1 03/14/22 16:21 JLB V16104 4-Methyl-2-Pentanone <1.00 N9/L 1.00 5.00 1 03/14/22 16:21 JLB V16104 Methylene Chloride <0.330 u9/L 0.330 1.00 1 03/14/22 16:21 JLB V16104 Styrene <0.220 N9/L 0.220 0.500 1 03/14/22 16:21 JLB V16104 1,1,1,2-Tetrachloroethane <0.160 u9/L 0.160 0.500 1 03/14/22 16:21 JLB V16104 1,1,2,2-Tetrachloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 16:21 JLB V16104 Tetrachloroethene <0.220 u9/L 0.220 0.500 1 03/14/22 16:21 JLB V16104 Tetrahydrofuran <1.50 N9/L 1.50 10.0 1 03/14/22 16:21 JLB V16104 Toluene <0.220 u9/L 0.220 0.500 1 03/14/22 16:21 JLB V16104 1,1,1-Trichloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 16:21 JLB V16104 1,1,2-Trichloroethane <0.096 u9/L 0.096 0.500 1 03/14/22 16:21 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 24 of 84 • Waypdint0 449 Springbrook Rd, Charlotte, .5 282& Main 704.529.636� ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Chuck Pippin 231 Haywood Street Asheville , NC 28801 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill GW Report Date : 03/22/2022 Information : C11460-01.02 Task 02 Received : 03/10/2022 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95876 Matrix: Aqueous Sample ID: MW-03-20220308 Sampled: 3/8/2022 9:40 Analytical Method: 8260D Prep Method: 5030E Test Results Trichloroethene <0.180 Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Prep Batch(es): V16102 03/14/22 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.180 0.500 Ng/L 0.270 1.00 Pg/L 1.00 2.00 Ng/L 0.170 0.500 Pg/L 0.210 0.500 Ng/L 0.420 1.00 Pg/L 0.210 0.500 108 Limits: 80-124% 94.0 Limits: 75-129% 93.2 Limits: 63-136% 95.6 Limits: 77-123% 1 03/14/22 16:21 JLB V16104 1 03/14/22 16:21 JLB V16104 1 03/14/22 16:21 JLB V16104 1 03/14/22 16:21 JLB V16104 1 03/14/22 16:21 JLB V16104 1 03/14/22 16:21 JLB V16104 1 03/14/22 16:21 JLB V16104 1 03/14/22 16:21 V16104 1 03/14/22 16:21 JLB V16104 1 03/14/22 16:21 JLB V16104 1 03/14/22 16:21 JLB V16104 1 03/14/22 16:21 JLB V16104 J Estimated value Page 25 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95877 Matrix: Aqueous Sample ID: MW-04-20220307 Sampled: 3/7/2022 11:05 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane 6.29 Ng/L 0.139 2.00 1 03/11/22 16:21 TBL 8260D SIM Antimony <0.680 u9/L 0.680 2.00 1 03/15/22 19:34 EDV 6020B Arsenic <0.490 Ng/L 0.490 1.00 1 03/15/22 19:34 EDV 6020B Barium 67.6 u9/L 3.40 10.0 1 03/15/22 19:34 EDV 6020B Beryllium <0.240 Ng/L 0.240 1.00 1 03/15/22 19:34 EDV 6020B Cadmium 0.3703 u9/L 0.150 1.00 1 03/15/22 19:34 EDV 6020B Chromium <1.00 N9/L 1.00 2.00 1 03/15/22 19:34 EDV 6020E Cobalt 2.99 u9/L 0.080 1.00 1 03/15/22 19:34 EDV 6020B Copper <0.890 N9/L 0.890 2.00 1 03/15/22 19:34 EDV 6020E Lead <0.500 u9/L 0.500 1.00 1 03/15/22 19:34 EDV 6020B Mercury (Total) 0.1203 N9/L 0.0700 0.200 1 03/16/22 18:26 EDV 7470A Nickel 2.07 u9/L 0.720 2.00 1 03/15/22 19:34 EDV 6020B Selenium <2.30 N9/L 2.30 5.00 1 03/15/22 19:34 EDV 6020E Silver <0.130 u9/L 0.130 1.00 1 03/15/22 19:34 EDV 6020B Thallium <0.280 N9/L 0.280 2.00 1 03/15/22 19:34 EDV 6020B Vanadium <2.10 u9/L 2.10 5.00 1 03/16/2217:17 EDV 6020B Zinc 5.393 N9/L 3.90 20.0 1 03/15/22 19:34 EDV 6020B Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit J Estimated value Page 26 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95877 Matrix: Aqueous Sample ID: MW-04-20220307 Sampled: 3/7/2022 11:05 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 2.413 Ng/L 1.80 5.00 1 03/14/22 20:24 JLB V16104 Acrylonitrile <0.230 u9/L 0.230 5.00 1 03/14/22 20:24 JLB V16104 Benzene 0.2263 N9/L 0.180 0.500 1 03/14/22 20:24 JLB V16104 Bromochloromethane <0.420 u9/L 0.420 1.00 1 03/14/22 20:24 JLB V16104 Bromodichloromethane <0.160 N9/L 0.160 0.500 1 03/14/22 20:24 JLB V16104 Bromoform <1.50 u9/L 1.50 5.00 1 03/14/22 20:24 JLB V16104 Bromomethane <0.280 N9/L 0.280 1.00 1 03/14/22 20:24 JLB V16104 Carbon Disulfide <0.150 u9/L 0.150 5.00 1 03/14/22 20:24 JLB V16104 Carbon Tetrachloride <0.180 N9/L 0.180 0.500 1 03/14/22 20:24 JLB V16104 Chlorobenzene <0.190 u9/L 0.190 0.500 1 03/14/22 20:24 JLB V16104 Chlorodibromomethane <0.190 N9/L 0.190 0.500 1 03/14/22 20:24 JLB V16104 Chloroethane <0.430 u9/L 0.430 1.00 1 03/14/22 20:24 JLB V16104 Chloroform <0.220 N9/L 0.220 0.500 1 03/14/22 20:24 JLB V16104 Chloromethane <0.220 u9/L 0.220 0.500 1 03/14/22 20:24 JLB V16104 Di -Isopropyl Ether (DIPE) <0.960 N9/L 0.960 5.00 1 03/14/22 20:24 JLB V16104 1,2-Dibromo-3-Chloropropane <1.10 u9/L 1.10 2.00 1 03/14/22 20:24 JLB V16104 1,2-Dibromoethane <0.200 N9/L 0.200 0.500 1 03/14/22 20:24 JLB V16104 Dibromomethane <0.230 u9/L 0.230 0.500 1 03/14/22 20:24 JLB V16104 trans-1,4-Dichloro-2-butene <1.30 N9/L 1.30 10.0 1 03/14/22 20:24 JLB V16104 1,2-Dichlorobenzene <0.220 u9/L 0.220 0.500 1 03/14/22 20:24 JLB V16104 1,4-Dichlorobenzene 2.20 N9/L 0.210 0.500 1 03/14/22 20:24 JLB V16104 Dichlorodifluoromethane <1.20 u9/L 1.20 5.00 1 03/14/22 20:24 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 27 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95877 Matrix: Aqueous Sample ID: MW-04-20220307 Sampled: 3/7/2022 11:05 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 N9/L 0.240 0.500 1 03/14/22 20:24 JLB V16104 1,2-Dichloroethane <0.150 u9/L 0.150 0.500 1 03/14/22 20:24 JLB V16104 1,1-Dichloroethene <0.150 N9/L 0.150 0.500 1 03/14/22 20:24 JLB V16104 cis- 1,2-Dich loroethene 0.645 u9/L 0.200 0.500 1 03/14/22 20:24 JLB V16104 trans-1,2-Dichloroethene <0.180 N9/L 0.180 0.500 1 03/14/22 20:24 JLB V16104 1,2-Dichloropropane <0.190 u9/L 0.190 0.500 1 03/14/22 20:24 JLB V16104 cis- 1,3-Dich loropropene <0.210 N9/L 0.210 0.500 1 03/14/22 20:24 JLB V16104 trans-1,3-Dichloropropene <0.150 u9/L 0.150 0.500 1 03/14/22 20:24 JLB V16104 1,4-Dioxane <16.0 N9/L 16.0 150 1 03/14/22 20:24 JLB V16104 Ethylbenzene <0.170 u9/L 0.170 0.500 1 03/14/22 20:24 JLB V16104 2-Hexanone <0.380 N9/L 0.380 5.00 1 03/14/22 20:24 JLB V16104 Methyl Ethyl Ketone (MEK) <0.710 u9/L 0.710 5.00 1 03/14/22 20:24 JLB V16104 4-Methyl-2-Pentanone <1.00 N9/L 1.00 5.00 1 03/14/22 20:24 JLB V16104 Methylene Chloride <0.330 u9/L 0.330 1.00 1 03/14/22 20:24 JLB V16104 Styrene <0.220 N9/L 0.220 0.500 1 03/14/22 20:24 JLB V16104 1,1,1,2-Tetrachloroethane <0.160 u9/L 0.160 0.500 1 03/14/22 20:24 JLB V16104 1,1,2,2-Tetrachloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 20:24 JLB V16104 Tetrachloroethene <0.220 u9/L 0.220 0.500 1 03/14/22 20:24 JLB V16104 Tetrahydrofuran <1.50 N9/L 1.50 10.0 1 03/14/22 20:24 JLB V16104 Toluene <0.220 u9/L 0.220 0.500 1 03/14/22 20:24 JLB V16104 1,1,1-Trichloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 20:24 JLB V16104 1,1,2-Trichloroethane <0.096 u9/L 0.096 0.500 1 03/14/22 20:24 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 28 of 84 • Waypdint0 449 Springbrook Rd, Charlotte, .5 282& Main 704.529.636� ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Chuck Pippin 231 Haywood Street Asheville , NC 28801 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill GW Report Date : 03/22/2022 Information : C11460-01.02 Task 02 Received : 03/10/2022 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95877 Matrix: Aqueous Sample ID: MW-04-20220307 Sampled: 3/7/2022 11:05 Analytical Method: 8260D Prep Method: 5030E Test Results Trichloroethene <0.180 Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Prep Batch(es): V16102 03/14/22 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.180 0.500 Ng/L 0.270 1.00 Pg/L 1.00 2.00 Ng/L 0.170 0.500 Pg/L 0.210 0.500 Ng/L 0.420 1.00 Pg/L 0.210 0.500 109 Limits: 80-124% 94.0 Limits: 75-129% 97.4 Limits: 63-136% 94.2 Limits: 77-123% 1 03/14/22 20:24 JLB V16104 1 03/14/22 20:24 JLB V16104 1 03/14/22 20:24 JLB V16104 1 03/14/22 20:24 JLB V16104 1 03/14/22 20:24 JLB V16104 1 03/14/22 20:24 JLB V16104 1 03/14/22 20:24 JLB V16104 1 03/14/22 20:24 V16104 1 03/14/22 20:24 JLB V16104 1 03/14/22 20:24 JLB V16104 1 03/14/22 20:24 JLB V16104 1 03/14/22 20:24 JLB V16104 J Estimated value Page 29 of 84 WavDdibnto ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Chuck Pippin 231 Haywood Street Asheville , NC 28801 Report Number : 22-069-0024 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill GW Information : C11460-01.02 Task 02 REPORT OF ANAL YSIS Report Date : 03/22/2022 Received : 03/10/2022 Lab No : 95878 Matrix: Aqueous Sample ID: MW-05R-20220307 Sampled: 3/7/2022 14:40 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane 6.50 Ng/L 0.139 2.00 1 03/11/22 16:46 TBL 8260D SIM Antimony <0.680 ug/L 0.680 2.00 1 03/15/22 19:40 EDV 6020B Dissolved Antimony <0.680 Ng/L 0.680 2.00 1 03/21/22 16:35 EDV 6020B Arsenic <0.490 ug/L 0.490 1.00 1 03/15/22 19:40 EDV 6020B Dissolved Arsenic <0.490 Ng/L 0.490 1.00 1 03/15/22 21:52 EDV 6020B Barium 119 ug/L 3.40 10.0 1 03/15/22 19:40 EDV 6020B Dissolved Barium 81.8 Ng/L 3.40 10.0 1 03/15/22 21:52 EDV 6020B Beryllium <0.240 pg/L 0.240 1.00 1 03/15/22 19:40 EDV 6020B Dissolved Beryllium <0.240 Ng/L 0.240 1.00 1 03/17/22 18:53 EDV 6020B Cadmium <0.150 pg/L 0.150 1.00 1 03/15/22 19:40 EDV 6020B Dissolved Cadmium <0.150 Ng/L 0.150 1.00 1 03/15/22 21:52 EDV 6020B Chromium <1.00 ug/L 1.00 2.00 1 03/15/22 19:40 EDV 6020B Dissolved Chromium <1.00 Ng/L 1.00 2.00 1 03/15/22 21:52 EDV 6020E Cobalt 12.7 ug/L 0.080 1.00 1 03/15/22 19:40 EDV 6020B Dissolved Cobalt 11.3 Ng/L 0.080 2.00 1 03/15/22 21:52 EDV 6020E Copper <0.890 ug/L 0.890 2.00 1 03/15/22 19:40 EDV 6020B Dissolved Copper <0.890 Ng/L 0.890 10.0 1 03/15/22 21:52 EDV 6020E Lead <0.500 ug/L 0.500 1.00 1 03/15/22 19:40 EDV 6020B Dissolved Lead <0.500 Ng/L 0.500 1.00 1 03/15/22 21:52 EDV 6020E Mercury (Total) <0.0700 ug/L 0.0700 0.200 1 03/16/22 18:36 EDV 7470A Dissolved Mercury <0.0700 Ng/L 0.0700 0.200 1 03/15/22 15:18 EDV 7470A Dissolved Nickel 2.25 J ug/L 0.720 3.00 1 03/15/22 21:52 EDV 6020B Nickel 2.65 Ng/L 0.720 2.00 1 03/15/22 19:40 EDV 6020B Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 30 of 84 • Waypdint0 449 Springbrook Rd, Charlotte, .5 282& Main 704.529.636� ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Chuck Pippin 231 Haywood Street Asheville , NC 28801 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill GW Report Date : 03/22/2022 Information : C11460-01.02 Task 02 Received : 03/10/2022 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95878 Sample ID: MW-05R-20220307 Matrix: Aqueous Sampled: 3/7/2022 14:40 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Selenium <2.30 Ng/L 2.30 5.00 1 03/15/2219:40 EDV 6020B Dissolved Selenium <2.30 pg/L 2.30 5.00 1 03/15/22 21:52 EDV 6020B Silver <0.130 N9/L 0.130 1.00 1 03/15/2219:40 EDV 6020B Dissolved Silver <0.130 u9/L 0.130 1.00 1 03/15/22 21:52 EDV 6020B Thallium <0.280 N9/L 0.280 2.00 1 03/15/2219:40 EDV 6020B Dissolved Thallium <0.280 u9/L 0.280 2.00 1 03/15/22 21:52 EDV 6020B Vanadium <2.10 N9/L 2.10 5.00 1 03/16/2217:24 EDV 6020B Dissolved Vanadium <2.10 u9/L 2.10 5.00 1 03/15/22 21:52 EDV 6020B Zinc <3.90 N9/L 3.90 20.0 1 03/15/2219:40 EDV 6020B Dissolved Zinc <3.90 u9/L 3.90 20.0 1 03/15/22 21:52 EDV 6020B Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit J Estimated value Page 31 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95878 Matrix: Aqueous Sample ID: MW-05R-20220307 Sampled: 3/7/2022 14:40 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 2.363 Ng/L 1.80 5.00 1 03/14/22 16:48 JLB V16104 Acrylonitrile <0.230 u9/L 0.230 5.00 1 03/14/22 16:48 JLB V16104 Benzene 2.06 N9/L 0.180 0.500 1 03/14/22 16:48 JLB V16104 Bromochloromethane <0.420 u9/L 0.420 1.00 1 03/14/22 16:48 JLB V16104 Bromodichloromethane <0.160 N9/L 0.160 0.500 1 03/14/22 16:48 JLB V16104 Bromoform <1.50 u9/L 1.50 5.00 1 03/14/22 16:48 JLB V16104 Bromomethane <0.280 N9/L 0.280 1.00 1 03/14/22 16:48 JLB V16104 Carbon Disulfide <0.150 u9/L 0.150 5.00 1 03/14/22 16:48 JLB V16104 Carbon Tetrachloride <0.180 N9/L 0.180 0.500 1 03/14/22 16:48 JLB V16104 Chlorobenzene 8.04 u9/L 0.190 0.500 1 03/14/22 16:48 JLB V16104 Chlorodibromomethane <0.190 N9/L 0.190 0.500 1 03/14/22 16:48 JLB V16104 Chloroethane 0.5051 u9/L 0.430 1.00 1 03/14/22 16:48 JLB V16104 Chloroform <0.220 N9/L 0.220 0.500 1 03/14/22 16:48 JLB V16104 Chloromethane <0.220 u9/L 0.220 0.500 1 03/14/22 16:48 JLB V16104 Di -Isopropyl Ether (DIPE) <0.960 N9/L 0.960 5.00 1 03/14/22 16:48 JLB V16104 1,2-Dibromo-3-Chloropropane <1.10 u9/L 1.10 2.00 1 03/14/22 16:48 JLB V16104 1,2-Dibromoethane <0.200 N9/L 0.200 0.500 1 03/14/22 16:48 JLB V16104 Dibromomethane <0.230 u9/L 0.230 0.500 1 03/14/22 16:48 JLB V16104 trans-1,4-Dichloro-2-butene <1.30 N9/L 1.30 10.0 1 03/14/22 16:48 JLB V16104 1,2-Dichlorobenzene 0.3353 u9/L 0.220 0.500 1 03/14/22 16:48 JLB V16104 1,4-Dichlorobenzene 7.93 N9/L 0.210 0.500 1 03/14/22 16:48 JLB V16104 Dichlorodifluoromethane <1.20 u9/L 1.20 5.00 1 03/14/22 16:48 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 32 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95878 Matrix: Aqueous Sample ID: MW-05R-20220307 Sampled: 3/7/2022 14:40 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 N9/L 0.240 0.500 1 03/14/22 16:48 JLB V16104 1,2-Dichloroethane <0.150 u9/L 0.150 0.500 1 03/14/22 16:48 JLB V16104 1,1-Dichloroethene <0.150 N9/L 0.150 0.500 1 03/14/22 16:48 JLB V16104 cis- 1,2-Dich loroethene 1.88 u9/L 0.200 0.500 1 03/14/22 16:48 JLB V16104 trans-1,2-Dichloroethene <0.180 N9/L 0.180 0.500 1 03/14/22 16:48 JLB V16104 1,2-Dichloropropane <0.190 u9/L 0.190 0.500 1 03/14/22 16:48 JLB V16104 cis- 1,3-Dich loropropene <0.210 N9/L 0.210 0.500 1 03/14/22 16:48 JLB V16104 trans-1,3-Dichloropropene <0.150 u9/L 0.150 0.500 1 03/14/22 16:48 JLB V16104 1,4-Dioxane <16.0 N9/L 16.0 150 1 03/14/22 16:48 JLB V16104 Ethylbenzene <0.170 u9/L 0.170 0.500 1 03/14/22 16:48 JLB V16104 2-Hexanone <0.380 N9/L 0.380 5.00 1 03/14/22 16:48 JLB V16104 Methyl Ethyl Ketone (MEK) <0.710 u9/L 0.710 5.00 1 03/14/22 16:48 JLB V16104 4-Methyl-2-Pentanone <1.00 N9/L 1.00 5.00 1 03/14/22 16:48 JLB V16104 Methylene Chloride <0.330 u9/L 0.330 1.00 1 03/14/22 16:48 JLB V16104 Styrene <0.220 N9/L 0.220 0.500 1 03/14/22 16:48 JLB V16104 1,1,1,2-Tetrachloroethane <0.160 u9/L 0.160 0.500 1 03/14/22 16:48 JLB V16104 1,1,2,2-Tetrachloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 16:48 JLB V16104 Tetrachloroethene <0.220 u9/L 0.220 0.500 1 03/14/22 16:48 JLB V16104 Tetrahydrofuran 2.28 3 N9/L 1.50 10.0 1 03/14/22 16:48 JLB V16104 Toluene <0.220 u9/L 0.220 0.500 1 03/14/22 16:48 JLB V16104 1,1,1-Trichloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 16:48 JLB V16104 1,1,2-Trichloroethane <0.096 u9/L 0.096 0.500 1 03/14/22 16:48 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 33 of 84 • Waypdint0 449 Springbrook Rd, Charlotte, .5 282& Main 704.529.636� ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Chuck Pippin 231 Haywood Street Asheville , NC 28801 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill GW Report Date : 03/22/2022 Information : C11460-01.02 Task 02 Received : 03/10/2022 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95878 Matrix: Aqueous Sample ID: MW-05R-20220307 Sampled: 3/7/2022 14:40 Analytical Method: 8260D Prep Method: 5030E Test Results Trichloroethene <0.180 Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride 1.01 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Prep Batch(es): V16102 03/14/22 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.180 0.500 Ng/L 0.270 1.00 Pg/L 1.00 2.00 Ng/L 0.170 0.500 Pg/L 0.210 0.500 Ng/L 0.420 1.00 Pg/L 0.210 0.500 104 Limits: 80-124% 93.0 Limits: 75-129% 93.6 Limits: 63-136% 96.2 Limits: 77-123% 1 03/14/22 16:48 JLB V16104 1 03/14/22 16:48 JLB V16104 1 03/14/22 16:48 JLB V16104 1 03/14/22 16:48 JLB V16104 1 03/14/22 16:48 JLB V16104 1 03/14/22 16:48 JLB V16104 1 03/14/22 16:48 JLB V16104 1 03/14/22 16:48 V16104 1 03/14/22 16:48 JLB V16104 1 03/14/22 16:48 JLB V16104 1 03/14/22 16:48 JLB V16104 1 03/14/22 16:48 JLB V16104 J Estimated value Page 34 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95879 Matrix: Aqueous Sample ID: MW-06-20220308 Sampled: 3/8/2022 11:31 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane <0.139 N9/L 0.139 2.00 1 03/11/22 17:11 TBL 8260D SIM Antimony <0.680 u9/L 0.680 2.00 1 03/15/22 19:47 EDV 6020B Arsenic <0.490 N9/L 0.490 1.00 1 03/15/22 19:47 EDV 6020E Barium 46.8 u9/L 3.40 10.0 1 03/15/22 19:47 EDV 6020B Beryllium <0.240 N9/L 0.240 1.00 1 03/15/22 19:47 EDV 6020E Cadmium <0.150 u9/L 0.150 1.00 1 03/15/22 19:47 EDV 6020B Chromium <1.00 N9/L 1.00 2.00 1 03/15/22 19:47 EDV 6020E Cobalt 15.8 u9/L 0.080 1.00 1 03/15/22 19:47 EDV 6020B Copper 0.9063 N9/L 0.890 2.00 1 03/15/22 19:47 EDV 6020E Lead <0.500 u9/L 0.500 1.00 1 03/15/22 19:47 EDV 6020B Mercury (Total) 0.1303 N9/L 0.0700 0.200 1 03/16/22 18:38 EDV 7470A Nickel 4.93 u9/L 0.720 2.00 1 03/15/22 19:47 EDV 6020B Selenium <2.30 N9/L 2.30 5.00 1 03/15/22 19:47 EDV 6020B Silver <0.130 u9/L 0.130 1.00 1 03/15/22 19:47 EDV 6020B Thallium 0.3083 N9/L 0.280 2.00 1 03/15/22 19:47 EDV 6020B Vanadium <2.10 u9/L 2.10 5.00 1 03/16/2217:30 EDV 6020B Zinc 16.53 N9/L 3.90 20.0 1 03/15/22 19:47 EDV 6020B Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit J Estimated value Page 35 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95879 Matrix: Aqueous Sample ID: MW-06-20220308 Sampled: 3/8/2022 11:31 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 3.553 Ng/L 1.80 5.00 1 03/14/22 17:15 JLB V16104 Acrylonitrile <0.230 u9/L 0.230 5.00 1 03/14/22 17:15 JLB V16104 Benzene <0.180 N9/L 0.180 0.500 1 03/14/22 17:15 JLB V16104 Bromochloromethane <0.420 u9/L 0.420 1.00 1 03/14/22 17:15 JLB V16104 Bromodichloromethane <0.160 N9/L 0.160 0.500 1 03/14/22 17:15 JLB V16104 Bromoform <1.50 u9/L 1.50 5.00 1 03/14/22 17:15 JLB V16104 Bromomethane <0.280 N9/L 0.280 1.00 1 03/14/22 17:15 JLB V16104 Carbon Disulfide <0.150 u9/L 0.150 5.00 1 03/14/22 17:15 JLB V16104 Carbon Tetrachloride <0.180 N9/L 0.180 0.500 1 03/14/22 17:15 JLB V16104 Chlorobenzene <0.190 u9/L 0.190 0.500 1 03/14/22 17:15 JLB V16104 Chlorodibromomethane <0.190 N9/L 0.190 0.500 1 03/14/22 17:15 JLB V16104 Chloroethane <0.430 u9/L 0.430 1.00 1 03/14/22 17:15 JLB V16104 Chloroform <0.220 N9/L 0.220 0.500 1 03/14/22 17:15 JLB V16104 Chloromethane <0.220 u9/L 0.220 0.500 1 03/14/22 17:15 JLB V16104 Di -Isopropyl Ether (DIPE) <0.960 N9/L 0.960 5.00 1 03/14/22 17:15 JLB V16104 1,2-Dibromo-3-Chloropropane <1.10 u9/L 1.10 2.00 1 03/14/22 17:15 JLB V16104 1,2-Dibromoethane <0.200 N9/L 0.200 0.500 1 03/14/22 17:15 JLB V16104 Dibromomethane <0.230 u9/L 0.230 0.500 1 03/14/22 17:15 JLB V16104 trans-1,4-Dichloro-2-butene <1.30 N9/L 1.30 10.0 1 03/14/22 17:15 JLB V16104 1,2-Dichlorobenzene <0.220 u9/L 0.220 0.500 1 03/14/22 17:15 JLB V16104 1,4-Dichlorobenzene 1.41 N9/L 0.210 0.500 1 03/14/22 17:15 JLB V16104 Dichlorodifluoromethane <1.20 u9/L 1.20 5.00 1 03/14/22 17:15 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 36 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95879 Matrix: Aqueous Sample ID: MW-06-20220308 Sampled: 3/8/2022 11:31 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane 0.977 Ng/L 0.240 0.500 1 03/14/22 17:15 JLB V16104 1,2-Dichloroethane <0.150 u9/L 0.150 0.500 1 03/14/22 17:15 JLB V16104 1,1-Dichloroethene <0.150 N9/L 0.150 0.500 1 03/14/22 17:15 JLB V16104 cis- 1,2-Dich loroethene 0.942 u9/L 0.200 0.500 1 03/14/22 17:15 JLB V16104 trans-1,2-Dichloroethene <0.180 N9/L 0.180 0.500 1 03/14/22 17:15 JLB V16104 1,2-Dichloropropane <0.190 u9/L 0.190 0.500 1 03/14/22 17:15 JLB V16104 cis- 1,3-Dich loropropene <0.210 N9/L 0.210 0.500 1 03/14/22 17:15 JLB V16104 trans-1,3-Dichloropropene <0.150 u9/L 0.150 0.500 1 03/14/22 17:15 JLB V16104 1,4-Dioxane <16.0 N9/L 16.0 150 1 03/14/22 17:15 JLB V16104 Ethylbenzene <0.170 u9/L 0.170 0.500 1 03/14/22 17:15 JLB V16104 2-Hexanone <0.380 N9/L 0.380 5.00 1 03/14/22 17:15 JLB V16104 Methyl Ethyl Ketone (MEK) <0.710 u9/L 0.710 5.00 1 03/14/22 17:15 JLB V16104 4-Methyl-2-Pentanone <1.00 N9/L 1.00 5.00 1 03/14/22 17:15 JLB V16104 Methylene Chloride <0.330 u9/L 0.330 1.00 1 03/14/22 17:15 JLB V16104 Styrene <0.220 N9/L 0.220 0.500 1 03/14/22 17:15 JLB V16104 1,1,1,2-Tetrachloroethane <0.160 u9/L 0.160 0.500 1 03/14/22 17:15 JLB V16104 1,1,2,2-Tetrachloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 17:15 JLB V16104 Tetrachloroethene <0.220 u9/L 0.220 0.500 1 03/14/22 17:15 JLB V16104 Tetrahydrofuran <1.50 N9/L 1.50 10.0 1 03/14/22 17:15 JLB V16104 Toluene <0.220 u9/L 0.220 0.500 1 03/14/22 17:15 JLB V16104 1,1,1-Trichloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 17:15 JLB V16104 1,1,2-Trichloroethane <0.096 u9/L 0.096 0.500 1 03/14/22 17:15 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 37 of 84 • Waypdint0 449 Springbrook Rd, Charlotte, .5 282& Main 704.529.636� ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Chuck Pippin 231 Haywood Street Asheville , NC 28801 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill GW Report Date : 03/22/2022 Information : C11460-01.02 Task 02 Received : 03/10/2022 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95879 Matrix: Aqueous Sample ID: MW-06-20220308 Sampled: 3/8/2022 11:31 Analytical Method: 8260D Prep Method: 5030E Test Results Trichloroethene <0.180 Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene 0.5483 Xylene (Total) 0.5483 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Prep Batch(es): V16102 03/14/22 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.180 0.500 Ng/L 0.270 1.00 Pg/L 1.00 2.00 Ng/L 0.170 0.500 Pg/L 0.210 0.500 Ng/L 0.420 1.00 Pg/L 0.210 0.500 108 Limits: 80-124% 94.2 Limits: 75-129% 96.4 Limits: 63-136% 96.8 Limits: 77-123% 1 03/14/22 17:15 JLB V16104 1 03/14/22 17:15 JLB V16104 1 03/14/22 17:15 JLB V16104 1 03/14/22 17:15 JLB V16104 1 03/14/22 17:15 JLB V16104 1 03/14/22 17:15 JLB V16104 1 03/14/22 17:15 JLB V16104 1 03/14/22 17:15 V16104 1 03/14/22 17:15 JLB V16104 1 03/14/22 17:15 JLB V16104 1 03/14/22 17:15 JLB V16104 1 03/14/22 17:15 JLB V16104 J Estimated value Page 38 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95880 Matrix: Aqueous Sample ID: MW-07-20220307 Sampled: 3/7/2022 12:21 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane 20.2 Ng/L 0.139 2.00 1 03/11/22 17:36 TBL 8260D SIM Antimony <0.680 u9/L 0.680 2.00 1 03/15/22 20:07 EDV 6020B Arsenic <0.490 Ng/L 0.490 1.00 1 03/15/22 20:07 EDV 6020B Barium 405 u9/L 3.40 10.0 1 03/15/22 20:07 EDV 6020B Beryllium <0.240 N9/L 0.240 1.00 1 03/15/22 20:07 EDV 6020B Cadmium <0.150 u9/L 0.150 1.00 1 03/15/22 20:07 EDV 6020B Chromium <1.00 Ng/L 1.00 2.00 1 03/15/22 20:07 EDV 6020B Cobalt 2.12 u9/L 0.080 1.00 1 03/15/22 20:07 EDV 6020B Copper <0.890 N9/L 0.890 2.00 1 03/15/22 20:07 EDV 6020B Lead <0.500 u9/L 0.500 1.00 1 03/15/22 20:07 EDV 6020B Mercury (Total) <0.0700 N9/L 0.0700 0.200 1 03/16/22 18:41 EDV 7470A Nickel 7.92 u9/L 0.720 2.00 1 03/15/22 20:07 EDV 6020B Selenium <2.30 N9/L 2.30 5.00 1 03/15/22 20:07 EDV 6020E Silver <0.130 u9/L 0.130 1.00 1 03/15/22 20:07 EDV 6020B Thallium <0.280 N9/L 0.280 2.00 1 03/15/22 20:07 EDV 6020B Vanadium <2.10 u9/L 2.10 5.00 1 03/16/2217:37 EDV 6020B Zinc 7.693 N9/L 3.90 20.0 1 03/15/22 20:07 EDV 6020B Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit J Estimated value Page 39 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95880 Matrix: Aqueous Sample ID: MW-07-20220307 Sampled: 3/7/2022 12:21 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 03/14/22 17:42 JLB V16104 Acrylonitrile <0.230 ug/L 0.230 5.00 1 03/14/22 17:42 JLB V16104 Benzene 1.52 Ng/L 0.180 0.500 1 03/14/22 17:42 JLB V16104 Bromochloromethane <0.420 ug/L 0.420 1.00 1 03/14/22 17:42 JLB V16104 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 03/14/22 17:42 JLB V16104 Bromoform <1.50 ug/L 1.50 5.00 1 03/14/22 17:42 JLB V16104 Bromomethane <0.280 Ng/L 0.280 1.00 1 03/14/22 17:42 JLB V16104 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 03/14/22 17:42 JLB V16104 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 03/14/22 17:42 JLB V16104 Chlorobenzene 4.47 ug/L 0.190 0.500 1 03/14/22 17:42 JLB V16104 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 03/14/22 17:42 JLB V16104 Chloroethane <0.430 ug/L 0.430 1.00 1 03/14/22 17:42 JLB V16104 Chloroform <0.220 Ng/L 0.220 0.500 1 03/14/22 17:42 JLB V16104 Chloromethane <0.220 ug/L 0.220 0.500 1 03/14/22 17:42 JLB V16104 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 03/14/22 17:42 JLB V16104 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 03/14/22 17:42 JLB V16104 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 03/14/22 17:42 JLB V16104 Dibromomethane <0.230 ug/L 0.230 0.500 1 03/14/22 17:42 JLB V16104 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 03/14/22 17:42 JLB V16104 1,2-Dichlorobenzene 0.3041 ug/L 0.220 0.500 1 03/14/22 17:42 JLB V16104 1,4-Dichlorobenzene 5.54 Ng/L 0.210 0.500 1 03/14/22 17:42 JLB V16104 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 03/14/22 17:42 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 40 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95880 Matrix: Aqueous Sample ID: MW-07-20220307 Sampled: 3/7/2022 12:21 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 N9/L 0.240 0.500 1 03/14/22 17:42 JLB V16104 1,2-Dichloroethane <0.150 u9/L 0.150 0.500 1 03/14/22 17:42 JLB V16104 1,1-Dichloroethene <0.150 N9/L 0.150 0.500 1 03/14/22 17:42 JLB V16104 cis- 1,2-Dich loroethene 1.89 u9/L 0.200 0.500 1 03/14/22 17:42 JLB V16104 trans-1,2-Dichloroethene <0.180 N9/L 0.180 0.500 1 03/14/22 17:42 JLB V16104 1,2-Dichloropropane <0.190 u9/L 0.190 0.500 1 03/14/22 17:42 JLB V16104 cis- 1,3-Dich loropropene <0.210 N9/L 0.210 0.500 1 03/14/22 17:42 JLB V16104 trans-1,3-Dichloropropene <0.150 u9/L 0.150 0.500 1 03/14/22 17:42 JLB V16104 1,4-Dioxane 17.13 N9/L 16.0 150 1 03/14/22 17:42 JLB V16104 Ethylbenzene <0.170 u9/L 0.170 0.500 1 03/14/22 17:42 JLB V16104 2-Hexanone <0.380 N9/L 0.380 5.00 1 03/14/22 17:42 JLB V16104 Methyl Ethyl Ketone (MEK) <0.710 u9/L 0.710 5.00 1 03/14/22 17:42 JLB V16104 4-Methyl-2-Pentanone <1.00 N9/L 1.00 5.00 1 03/14/22 17:42 JLB V16104 Methylene Chloride <0.330 u9/L 0.330 1.00 1 03/14/22 17:42 JLB V16104 Styrene <0.220 N9/L 0.220 0.500 1 03/14/22 17:42 JLB V16104 1,1,1,2-Tetrachloroethane <0.160 u9/L 0.160 0.500 1 03/14/22 17:42 JLB V16104 1,1,2,2-Tetrachloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 17:42 JLB V16104 Tetrachloroethene <0.220 u9/L 0.220 0.500 1 03/14/22 17:42 JLB V16104 Tetrahydrofuran <1.50 N9/L 1.50 10.0 1 03/14/22 17:42 JLB V16104 Toluene <0.220 u9/L 0.220 0.500 1 03/14/22 17:42 JLB V16104 1,1,1-Trichloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 17:42 JLB V16104 1,1,2-Trichloroethane <0.096 u9/L 0.096 0.500 1 03/14/22 17:42 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 41 of 84 • Waypdint0 449 Springbrook Rd, Charlotte, .5 282& Main 704.529.636� ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Chuck Pippin 231 Haywood Street Asheville , NC 28801 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill GW Report Date : 03/22/2022 Information : C11460-01.02 Task 02 Received : 03/10/2022 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95880 Matrix: Aqueous Sample ID: MW-07-20220307 Sampled: 3/7/2022 12:21 Analytical Method: 8260D Prep Method: 5030E Test Results Trichloroethene <0.180 Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Prep Batch(es): V16102 03/14/22 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.180 0.500 Ng/L 0.270 1.00 Pg/L 1.00 2.00 Ng/L 0.170 0.500 Pg/L 0.210 0.500 Ng/L 0.420 1.00 Pg/L 0.210 0.500 108 Limits: 80-124% 94.0 Limits: 75-129% 97.4 Limits: 63-136% 98.2 Limits: 77-123% 1 03/14/22 17:42 JLB V16104 1 03/14/22 17:42 JLB V16104 1 03/14/22 17:42 JLB V16104 1 03/14/22 17:42 JLB V16104 1 03/14/22 17:42 JLB V16104 1 03/14/22 17:42 JLB V16104 1 03/14/22 17:42 JLB V16104 1 03/14/22 17:42 V16104 1 03/14/22 17:42 JLB V16104 1 03/14/22 17:42 JLB V16104 1 03/14/22 17:42 JLB V16104 1 03/14/22 17:42 JLB V16104 J Estimated value Page 42 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95881 Matrix: Aqueous Sample ID: SW-01-20220307 Sampled: 3/7/2022 11:02 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Hardness 9000 Ng/L 570 5000 1 03/18/22 12:50 CLB 2340C-2011 1,4-Dioxane <0.139 u9/L 0.139 2.00 1 03/11/22 18:01 TBL 8260D SIM Antimony <0.680 N9/L 0.680 2.00 1 03/15/22 20:13 EDV 6020B Arsenic <0.490 u9/L 0.490 1.00 1 03/15/22 20:13 EDV 6020B Barium 20.6 N9/L 3.40 10.0 1 03/15/22 20:13 EDV 6020B Beryllium <0.240 u9/L 0.240 1.00 1 03/15/22 20:13 EDV 6020B Cadmium <0.150 N9/L 0.150 1.00 1 03/15/22 20:13 EDV 6020B Chromium 1.523 u9/L 1.00 2.00 1 03/15/22 20:13 EDV 6020B Cobalt 0.5953 N9/L 0.080 1.00 1 03/15/22 20:13 EDV 6020B Copper 1.223 u9/L 0.890 2.00 1 03/15/22 20:13 EDV 6020B Lead 0.5013 N9/L 0.500 1.00 1 03/15/22 20:13 EDV 6020B Mercury (Total) <0.0700 u9/L 0.0700 0.200 1 03/16/22 18:43 EDV 7470A Nickel 1.593 N9/L 0.720 2.00 1 03/15/22 20:13 EDV 6020B Selenium <2.30 u9/L 2.30 5.00 1 03/15/22 20:13 EDV 6020B Silver <0.130 N9/L 0.130 1.00 1 03/15/22 20:13 EDV 6020B Thallium <0.280 u9/L 0.280 2.00 1 03/15/22 20:13 EDV 6020B Vanadium 3.023 N9/L 2.10 5.00 1 03/16/22 17:43 EDV 6020B Zinc <3.90 u9/L 3.90 20.0 1 03/15/22 20:13 EDV 6020B Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit J Estimated value Page 43 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95881 Matrix: Aqueous Sample ID: SW-01-20220307 Sampled: 3/7/2022 11:02 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 2.013 Ng/L 1.80 5.00 1 03/14/22 18:09 JLB V16104 Acrylonitrile <0.230 u9/L 0.230 5.00 1 03/14/22 18:09 JLB V16104 Benzene <0.180 N9/L 0.180 0.500 1 03/14/22 18:09 JLB V16104 Bromochloromethane <0.420 u9/L 0.420 1.00 1 03/14/22 18:09 JLB V16104 Bromodichloromethane <0.160 N9/L 0.160 0.500 1 03/14/22 18:09 JLB V16104 Bromoform <1.50 u9/L 1.50 5.00 1 03/14/22 18:09 JLB V16104 Bromomethane <0.280 N9/L 0.280 1.00 1 03/14/22 18:09 JLB V16104 Carbon Disulfide <0.150 u9/L 0.150 5.00 1 03/14/22 18:09 JLB V16104 Carbon Tetrachloride <0.180 N9/L 0.180 0.500 1 03/14/22 18:09 JLB V16104 Chlorobenzene <0.190 u9/L 0.190 0.500 1 03/14/22 18:09 JLB V16104 Chlorodibromomethane <0.190 N9/L 0.190 0.500 1 03/14/22 18:09 JLB V16104 Chloroethane <0.430 u9/L 0.430 1.00 1 03/14/22 18:09 JLB V16104 Chloroform <0.220 N9/L 0.220 0.500 1 03/14/22 18:09 JLB V16104 Chloromethane <0.220 u9/L 0.220 0.500 1 03/14/22 18:09 JLB V16104 Di -Isopropyl Ether (DIPE) <0.960 N9/L 0.960 5.00 1 03/14/22 18:09 JLB V16104 1,2-Dibromo-3-Chloropropane <1.10 u9/L 1.10 2.00 1 03/14/22 18:09 JLB V16104 1,2-Dibromoethane <0.200 N9/L 0.200 0.500 1 03/14/22 18:09 JLB V16104 Dibromomethane <0.230 u9/L 0.230 0.500 1 03/14/22 18:09 JLB V16104 trans-1,4-Dichloro-2-butene <1.30 N9/L 1.30 10.0 1 03/14/22 18:09 JLB V16104 1,2-Dichlorobenzene <0.220 u9/L 0.220 0.500 1 03/14/22 18:09 JLB V16104 1,4-Dichlorobenzene <0.210 N9/L 0.210 0.500 1 03/14/22 18:09 JLB V16104 Dichlorodifluoromethane <1.20 u9/L 1.20 5.00 1 03/14/22 18:09 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 44 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95881 Matrix: Aqueous Sample ID: SW-01-20220307 Sampled: 3/7/2022 11:02 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 N9/L 0.240 0.500 1 03/14/22 18:09 JLB V16104 1,2-Dichloroethane <0.150 u9/L 0.150 0.500 1 03/14/22 18:09 JLB V16104 1,1-Dichloroethene <0.150 N9/L 0.150 0.500 1 03/14/22 18:09 JLB V16104 cis- 1,2-Dich loroethene <0.200 u9/L 0.200 0.500 1 03/14/22 18:09 JLB V16104 trans-1,2-Dichloroethene <0.180 N9/L 0.180 0.500 1 03/14/22 18:09 JLB V16104 1,2-Dichloropropane <0.190 u9/L 0.190 0.500 1 03/14/22 18:09 JLB V16104 cis- 1,3-Dich loropropene <0.210 N9/L 0.210 0.500 1 03/14/22 18:09 JLB V16104 trans-1,3-Dichloropropene <0.150 u9/L 0.150 0.500 1 03/14/22 18:09 JLB V16104 1,4-Dioxane <16.0 N9/L 16.0 150 1 03/14/22 18:09 JLB V16104 Ethylbenzene <0.170 u9/L 0.170 0.500 1 03/14/22 18:09 JLB V16104 2-Hexanone <0.380 N9/L 0.380 5.00 1 03/14/22 18:09 JLB V16104 Methyl Ethyl Ketone (MEK) <0.710 u9/L 0.710 5.00 1 03/14/22 18:09 JLB V16104 4-Methyl-2-Pentanone <1.00 N9/L 1.00 5.00 1 03/14/22 18:09 JLB V16104 Methylene Chloride <0.330 u9/L 0.330 1.00 1 03/14/22 18:09 JLB V16104 Styrene <0.220 N9/L 0.220 0.500 1 03/14/22 18:09 JLB V16104 1,1,1,2-Tetrachloroethane <0.160 u9/L 0.160 0.500 1 03/14/22 18:09 JLB V16104 1,1,2,2-Tetrachloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 18:09 JLB V16104 Tetrachloroethene <0.220 u9/L 0.220 0.500 1 03/14/22 18:09 JLB V16104 Tetrahydrofuran <1.50 N9/L 1.50 10.0 1 03/14/22 18:09 JLB V16104 Toluene <0.220 u9/L 0.220 0.500 1 03/14/22 18:09 JLB V16104 1,1,1-Trichloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 18:09 JLB V16104 1,1,2-Trichloroethane <0.096 u9/L 0.096 0.500 1 03/14/22 18:09 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 45 of 84 • Waypdint0 449 Springbrook Rd, Charlotte, .5 282& Main 704.529.636� ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Chuck Pippin 231 Haywood Street Asheville , NC 28801 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill GW Report Date : 03/22/2022 Information : C11460-01.02 Task 02 Received : 03/10/2022 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95881 Matrix: Aqueous Sample ID: SW-01-20220307 Sampled: 3/7/2022 11:02 Analytical Method: 8260D Prep Method: 5030E Test Results Trichloroethene <0.180 Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Prep Batch(es): V16102 03/14/22 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.180 0.500 Ng/L 0.270 1.00 Pg/L 1.00 2.00 Ng/L 0.170 0.500 Pg/L 0.210 0.500 Ng/L 0.420 1.00 Pg/L 0.210 0.500 109 Limits: 80-124% 93.6 Limits: 75-129% 94.6 Limits: 63-136% 94.2 Limits: 77-123% 1 03/14/22 18:09 JLB V16104 1 03/14/22 18:09 JLB V16104 1 03/14/22 18:09 JLB V16104 1 03/14/22 18:09 JLB V16104 1 03/14/22 18:09 JLB V16104 1 03/14/22 18:09 JLB V16104 1 03/14/22 18:09 JLB V16104 1 03/14/22 18:09 V16104 1 03/14/22 18:09 JLB V16104 1 03/14/22 18:09 JLB V16104 1 03/14/22 18:09 JLB V16104 1 03/14/22 18:09 JLB V16104 J Estimated value Page 46 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95882 Matrix: Aqueous Sample ID: SW-02-20220307 Sampled: 3/7/2022 13:20 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Hardness 6000 Ng/L 570 5000 1 03/18/22 12:50 CLB 2340C-2011 1,4-Dioxane <0.139 u9/L 0.139 2.00 1 03/11/22 18:27 TBL 8260D SIM Antimony <0.680 N9/L 0.680 2.00 1 03/15/22 20:20 EDV 6020B Arsenic <0.490 u9/L 0.490 1.00 1 03/15/22 20:20 EDV 6020B Barium 18.6 N9/L 3.40 10.0 1 03/15/22 20:20 EDV 6020B Beryllium <0.240 u9/L 0.240 1.00 1 03/15/22 20:20 EDV 6020B Cadmium <0.150 N9/L 0.150 1.00 1 03/15/22 20:20 EDV 6020B Chromium 1.363 u9/L 1.00 2.00 1 03/15/22 20:20 EDV 6020B Cobalt 0.4603 N9/L 0.080 1.00 1 03/15/22 20:20 EDV 6020B Copper 1.003 u9/L 0.890 2.00 1 03/15/22 20:20 EDV 6020B Lead <0.500 N9/L 0.500 1.00 1 03/15/22 20:20 EDV 6020B Mercury (Total) <0.0700 u9/L 0.0700 0.200 1 03/16/22 18:46 EDV 7470A Nickel <0.720 N9/L 0.720 2.00 1 03/15/22 20:20 EDV 6020B Selenium <2.30 u9/L 2.30 5.00 1 03/15/22 20:20 EDV 6020B Silver <0.130 N9/L 0.130 1.00 1 03/15/22 20:20 EDV 6020B Thallium <0.280 u9/L 0.280 2.00 1 03/15/22 20:20 EDV 6020B Vanadium 2.643 N9/L 2.10 5.00 1 03/16/22 17:50 EDV 6020B Zinc <3.90 u9/L 3.90 20.0 1 03/15/22 20:20 EDV 6020B Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit J Estimated value Page 47 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95882 Matrix: Aqueous Sample ID: SW-02-20220307 Sampled: 3/7/2022 13:20 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 2.063 Ng/L 1.80 5.00 1 03/14/22 18:36 JLB V16104 Acrylonitrile <0.230 ug/L 0.230 5.00 1 03/14/22 18:36 JLB V16104 Benzene <0.180 Ng/L 0.180 0.500 1 03/14/22 18:36 JLB V16104 Bromochloromethane <0.420 ug/L 0.420 1.00 1 03/14/22 18:36 JLB V16104 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 03/14/22 18:36 JLB V16104 Bromoform <1.50 ug/L 1.50 5.00 1 03/14/22 18:36 JLB V16104 Bromomethane <0.280 Ng/L 0.280 1.00 1 03/14/22 18:36 JLB V16104 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 03/14/22 18:36 JLB V16104 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 03/14/22 18:36 JLB V16104 Chlorobenzene <0.190 ug/L 0.190 0.500 1 03/14/22 18:36 JLB V16104 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 03/14/22 18:36 JLB V16104 Chloroethane <0.430 ug/L 0.430 1.00 1 03/14/22 18:36 JLB V16104 Chloroform <0.220 Ng/L 0.220 0.500 1 03/14/22 18:36 JLB V16104 Chloromethane <0.220 ug/L 0.220 0.500 1 03/14/22 18:36 JLB V16104 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 03/14/22 18:36 JLB V16104 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 03/14/22 18:36 JLB V16104 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 03/14/22 18:36 JLB V16104 Dibromomethane <0.230 ug/L 0.230 0.500 1 03/14/22 18:36 JLB V16104 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 03/14/22 18:36 JLB V16104 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 03/14/22 18:36 JLB V16104 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 03/14/22 18:36 JLB V16104 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 03/14/22 18:36 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 48 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95882 Matrix: Aqueous Sample ID: SW-02-20220307 Sampled: 3/7/2022 13:20 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 N9/L 0.240 0.500 1 03/14/22 18:36 JLB V16104 1,2-Dichloroethane <0.150 u9/L 0.150 0.500 1 03/14/22 18:36 JLB V16104 1,1-Dichloroethene <0.150 N9/L 0.150 0.500 1 03/14/22 18:36 JLB V16104 cis- 1,2-Dich loroethene <0.200 u9/L 0.200 0.500 1 03/14/22 18:36 JLB V16104 trans-1,2-Dichloroethene <0.180 N9/L 0.180 0.500 1 03/14/22 18:36 JLB V16104 1,2-Dichloropropane <0.190 u9/L 0.190 0.500 1 03/14/22 18:36 JLB V16104 cis- 1,3-Dich loropropene <0.210 N9/L 0.210 0.500 1 03/14/22 18:36 JLB V16104 trans-1,3-Dichloropropene <0.150 u9/L 0.150 0.500 1 03/14/22 18:36 JLB V16104 1,4-Dioxane <16.0 N9/L 16.0 150 1 03/14/22 18:36 JLB V16104 Ethylbenzene <0.170 u9/L 0.170 0.500 1 03/14/22 18:36 JLB V16104 2-Hexanone <0.380 N9/L 0.380 5.00 1 03/14/22 18:36 JLB V16104 Methyl Ethyl Ketone (MEK) <0.710 u9/L 0.710 5.00 1 03/14/22 18:36 JLB V16104 4-Methyl-2-Pentanone <1.00 N9/L 1.00 5.00 1 03/14/22 18:36 JLB V16104 Methylene Chloride <0.330 u9/L 0.330 1.00 1 03/14/22 18:36 JLB V16104 Styrene <0.220 N9/L 0.220 0.500 1 03/14/22 18:36 JLB V16104 1,1,1,2-Tetrachloroethane <0.160 u9/L 0.160 0.500 1 03/14/22 18:36 JLB V16104 1,1,2,2-Tetrachloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 18:36 JLB V16104 Tetrachloroethene <0.220 u9/L 0.220 0.500 1 03/14/22 18:36 JLB V16104 Tetrahydrofuran <1.50 N9/L 1.50 10.0 1 03/14/22 18:36 JLB V16104 Toluene <0.220 u9/L 0.220 0.500 1 03/14/22 18:36 JLB V16104 1,1,1-Trichloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 18:36 JLB V16104 1,1,2-Trichloroethane <0.096 u9/L 0.096 0.500 1 03/14/22 18:36 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 49 of 84 • Waypdint0 449 Springbrook Rd, Charlotte, .5 282& Main 704.529.636� ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Chuck Pippin 231 Haywood Street Asheville , NC 28801 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill GW Report Date : 03/22/2022 Information : C11460-01.02 Task 02 Received : 03/10/2022 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95882 Matrix: Aqueous Sample ID: SW-02-20220307 Sampled: 3/7/2022 13:20 Analytical Method: 8260D Prep Method: 5030E Test Results Trichloroethene <0.180 Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Prep Batch(es): V16102 03/14/22 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.180 0.500 Ng/L 0.270 1.00 Pg/L 1.00 2.00 Ng/L 0.170 0.500 Pg/L 0.210 0.500 Ng/L 0.420 1.00 Pg/L 0.210 0.500 108 Limits: 80-124% 94.2 Limits: 75-129% 95.0 Limits: 63-136% 96.2 Limits: 77-123% 1 03/14/22 18:36 JLB V16104 1 03/14/22 18:36 JLB V16104 1 03/14/22 18:36 JLB V16104 1 03/14/22 18:36 JLB V16104 1 03/14/22 18:36 JLB V16104 1 03/14/22 18:36 JLB V16104 1 03/14/22 18:36 JLB V16104 1 03/14/22 18:36 V16104 1 03/14/22 18:36 JLB V16104 1 03/14/22 18:36 JLB V16104 1 03/14/22 18:36 JLB V16104 1 03/14/22 18:36 JLB V16104 J Estimated value Page 50 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95883 Matrix: Aqueous Sample ID: SW-03-20220307 Sampled: 3/7/2022 13:43 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Hardness 6000 Ng/L 570 5000 1 03/18/22 12:50 CLB 2340C-2011 1,4-Dioxane <0.139 u9/L 0.139 2.00 1 03/11/22 18:52 TBL 8260D SIM Antimony <0.680 N9/L 0.680 2.00 1 03/15/22 20:26 EDV 6020B Arsenic <0.490 u9/L 0.490 1.00 1 03/15/22 20:26 EDV 6020B Barium 13.9 N9/L 3.40 10.0 1 03/15/22 20:26 EDV 6020B Beryllium <0.240 u9/L 0.240 1.00 1 03/15/22 20:26 EDV 6020B Cadmium <0.150 N9/L 0.150 1.00 1 03/15/22 20:26 EDV 6020B Chromium <1.00 u9/L 1.00 2.00 1 03/15/22 20:26 EDV 6020B Cobalt 0.2003 N9/L 0.080 1.00 1 03/15/22 20:26 EDV 6020B Copper <0.890 u9/L 0.890 2.00 1 03/15/22 20:26 EDV 6020B Lead <0.500 N9/L 0.500 1.00 1 03/15/22 20:26 EDV 6020B Mercury (Total) <0.0700 u9/L 0.0700 0.200 1 03/16/22 18:48 EDV 7470A Nickel <0.720 N9/L 0.720 2.00 1 03/15/22 20:26 EDV 6020B Selenium <2.30 u9/L 2.30 5.00 1 03/15/22 20:26 EDV 6020B Silver <0.130 N9/L 0.130 1.00 1 03/15/22 20:26 EDV 6020B Thallium <0.280 u9/L 0.280 2.00 1 03/15/22 20:26 EDV 6020B Vanadium 2.113 N9/L 2.10 5.00 1 03/16/2218:09 EDV 6020B Zinc <3.90 u9/L 3.90 20.0 1 03/15/22 20:26 EDV 6020B Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit J Estimated value Page 51 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95883 Matrix: Aqueous Sample ID: SW-03-20220307 Sampled: 3/7/2022 13:43 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 2.123 Ng/L 1.80 5.00 1 03/14/22 19:03 JLB V16104 Acrylonitrile <0.230 u9/L 0.230 5.00 1 03/14/22 19:03 JLB V16104 Benzene <0.180 N9/L 0.180 0.500 1 03/14/22 19:03 JLB V16104 Bromochloromethane <0.420 u9/L 0.420 1.00 1 03/14/22 19:03 JLB V16104 Bromodichloromethane <0.160 N9/L 0.160 0.500 1 03/14/22 19:03 JLB V16104 Bromoform <1.50 u9/L 1.50 5.00 1 03/14/22 19:03 JLB V16104 Bromomethane <0.280 N9/L 0.280 1.00 1 03/14/22 19:03 JLB V16104 Carbon Disulfide <0.150 u9/L 0.150 5.00 1 03/14/22 19:03 JLB V16104 Carbon Tetrachloride <0.180 N9/L 0.180 0.500 1 03/14/22 19:03 JLB V16104 Chlorobenzene <0.190 u9/L 0.190 0.500 1 03/14/22 19:03 JLB V16104 Chlorodibromomethane <0.190 N9/L 0.190 0.500 1 03/14/22 19:03 JLB V16104 Chloroethane <0.430 u9/L 0.430 1.00 1 03/14/22 19:03 JLB V16104 Chloroform <0.220 N9/L 0.220 0.500 1 03/14/22 19:03 JLB V16104 Chloromethane <0.220 u9/L 0.220 0.500 1 03/14/22 19:03 JLB V16104 Di -Isopropyl Ether (DIPE) <0.960 N9/L 0.960 5.00 1 03/14/22 19:03 JLB V16104 1,2-Dibromo-3-Chloropropane <1.10 u9/L 1.10 2.00 1 03/14/22 19:03 JLB V16104 1,2-Dibromoethane <0.200 N9/L 0.200 0.500 1 03/14/22 19:03 JLB V16104 Dibromomethane <0.230 u9/L 0.230 0.500 1 03/14/22 19:03 JLB V16104 trans-1,4-Dichloro-2-butene <1.30 N9/L 1.30 10.0 1 03/14/22 19:03 JLB V16104 1,2-Dichlorobenzene <0.220 u9/L 0.220 0.500 1 03/14/22 19:03 JLB V16104 1,4-Dichlorobenzene <0.210 N9/L 0.210 0.500 1 03/14/22 19:03 JLB V16104 Dichlorodifluoromethane <1.20 u9/L 1.20 5.00 1 03/14/22 19:03 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 52 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95883 Matrix: Aqueous Sample ID: SW-03-20220307 Sampled: 3/7/2022 13:43 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 N9/L 0.240 0.500 1 03/14/22 19:03 JLB V16104 1,2-Dichloroethane <0.150 u9/L 0.150 0.500 1 03/14/22 19:03 JLB V16104 1,1-Dichloroethene <0.150 N9/L 0.150 0.500 1 03/14/22 19:03 JLB V16104 cis- 1,2-Dich loroethene <0.200 u9/L 0.200 0.500 1 03/14/22 19:03 JLB V16104 trans-1,2-Dichloroethene <0.180 N9/L 0.180 0.500 1 03/14/22 19:03 JLB V16104 1,2-Dichloropropane <0.190 u9/L 0.190 0.500 1 03/14/22 19:03 JLB V16104 cis- 1,3-Dich loropropene <0.210 N9/L 0.210 0.500 1 03/14/22 19:03 JLB V16104 trans-1,3-Dichloropropene <0.150 u9/L 0.150 0.500 1 03/14/22 19:03 JLB V16104 1,4-Dioxane <16.0 N9/L 16.0 150 1 03/14/22 19:03 JLB V16104 Ethylbenzene <0.170 u9/L 0.170 0.500 1 03/14/22 19:03 JLB V16104 2-Hexanone <0.380 N9/L 0.380 5.00 1 03/14/22 19:03 JLB V16104 Methyl Ethyl Ketone (MEK) <0.710 u9/L 0.710 5.00 1 03/14/22 19:03 JLB V16104 4-Methyl-2-Pentanone <1.00 N9/L 1.00 5.00 1 03/14/22 19:03 JLB V16104 Methylene Chloride <0.330 u9/L 0.330 1.00 1 03/14/22 19:03 JLB V16104 Styrene <0.220 N9/L 0.220 0.500 1 03/14/22 19:03 JLB V16104 1,1,1,2-Tetrachloroethane <0.160 u9/L 0.160 0.500 1 03/14/22 19:03 JLB V16104 1,1,2,2-Tetrachloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 19:03 JLB V16104 Tetrachloroethene <0.220 u9/L 0.220 0.500 1 03/14/22 19:03 JLB V16104 Tetrahydrofuran <1.50 N9/L 1.50 10.0 1 03/14/22 19:03 JLB V16104 Toluene <0.220 u9/L 0.220 0.500 1 03/14/22 19:03 JLB V16104 1,1,1-Trichloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 19:03 JLB V16104 1,1,2-Trichloroethane <0.096 u9/L 0.096 0.500 1 03/14/22 19:03 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 53 of 84 • Waypdint0 449 Springbrook Rd, Charlotte, .5 282& Main 704.529.636� ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Chuck Pippin 231 Haywood Street Asheville , NC 28801 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill GW Report Date : 03/22/2022 Information : C11460-01.02 Task 02 Received : 03/10/2022 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95883 Matrix: Aqueous Sample ID: SW-03-20220307 Sampled: 3/7/2022 13:43 Analytical Method: 8260D Prep Method: 5030E Test Results Trichloroethene <0.180 Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Prep Batch(es): V16102 03/14/22 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.180 0.500 Ng/L 0.270 1.00 Pg/L 1.00 2.00 Ng/L 0.170 0.500 Pg/L 0.210 0.500 Ng/L 0.420 1.00 Pg/L 0.210 0.500 107 Limits: 80-124% 95.4 Limits: 75-129% 98.2 Limits: 63-136% 96.2 Limits: 77-123% 1 03/14/22 19:03 JLB V16104 1 03/14/22 19:03 JLB V16104 1 03/14/22 19:03 JLB V16104 1 03/14/22 19:03 JLB V16104 1 03/14/22 19:03 JLB V16104 1 03/14/22 19:03 JLB V16104 1 03/14/22 19:03 JLB V16104 1 03/14/22 19:03 V16104 1 03/14/22 19:03 JLB V16104 1 03/14/22 19:03 JLB V16104 1 03/14/22 19:03 JLB V16104 1 03/14/22 19:03 JLB V16104 J Estimated value Page 54 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95884 Matrix: Aqueous Sample ID: LT-01-20220307 Sampled: 3/7/2022 14:23 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane 106 N9/L 0.139 2.00 1 03/11/22 19:17 TBL 8260D SIM Antimony <0.680 u9/L 0.680 2.00 1 03/15/22 20:33 EDV 6020B Arsenic 3.70 Ng/L 0.490 1.00 1 03/15/22 20:33 EDV 6020B Barium 309 u9/L 3.40 10.0 1 03/15/22 20:33 EDV 6020B Beryllium <0.240 Ng/L 0.240 1.00 1 03/15/22 20:33 EDV 6020E Cadmium <0.150 u9/L 0.150 1.00 1 03/15/22 20:33 EDV 6020B Chromium 4.70 Ng/L 1.00 2.00 1 03/15/22 20:33 EDV 6020E Cobalt 6.34 u9/L 0.080 1.00 1 03/15/22 20:33 EDV 6020B Copper 2.34 N9/L 0.890 2.00 1 03/15/22 20:33 EDV 6020E Lead <0.500 u9/L 0.500 1.00 1 03/15/22 20:33 EDV 6020B Mercury (Total) <0.0700 N9/L 0.0700 0.200 1 03/16/22 18:51 EDV 7470A Nickel 30.5 u9/L 0.720 2.00 1 03/15/22 20:33 EDV 6020B Selenium <2.30 N9/L 2.30 5.00 1 03/15/22 20:33 EDV 6020E Silver <0.130 u9/L 0.130 1.00 1 03/15/22 20:33 EDV 6020B Thallium <0.280 N9/L 0.280 2.00 1 03/15/22 20:33 EDV 6020B Vanadium 4.46 J u9/L 2.10 5.00 1 03/16/22 18:16 EDV 6020B Zinc 4.29 J N9/L 3.90 20.0 1 03/15/22 20:33 EDV 6020B Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit J Estimated value Page 55 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95884 Matrix: Aqueous Sample ID: LT-01-20220307 Sampled: 3/7/2022 14:23 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 V16327 03/16/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 6.41 Ng/L 1.80 5.00 1 03/14/22 19:30 JLB V16104 Acrylonitrile <0.230 u9/L 0.230 5.00 1 03/14/22 19:30 JLB V16104 Benzene 1.48 Ng/L 0.180 0.500 1 03/14/22 19:30 JLB V16104 Bromochloromethane <0.420 u9/L 0.420 1.00 1 03/14/22 19:30 JLB V16104 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 03/14/22 19:30 JLB V16104 Bromoform <1.50 u9/L 1.50 5.00 1 03/14/22 19:30 JLB V16104 Bromomethane <0.280 Ng/L 0.280 1.00 1 03/14/22 19:30 JLB V16104 Carbon Disulfide <0.150 u9/L 0.150 5.00 1 03/14/22 19:30 JLB V16104 Carbon Tetrachloride <0.180 N9/L 0.180 0.500 1 03/14/22 19:30 JLB V16104 Chlorobenzene 4.18 u9/L 0.190 0.500 1 03/14/22 19:30 JLB V16104 Chlorodibromomethane <0.190 N9/L 0.190 0.500 1 03/14/22 19:30 JLB V16104 Chloroethane <0.430 u9/L 0.430 1.00 1 03/14/22 19:30 JLB V16104 Chloroform <0.220 Ng/L 0.220 0.500 1 03/14/22 19:30 JLB V16104 Chloromethane <0.220 u9/L 0.220 0.500 1 03/14/22 19:30 JLB V16104 Di -Isopropyl Ether (DIPE) <0.960 N9/L 0.960 5.00 1 03/14/22 19:30 JLB V16104 1,2-Dibromo-3-Chloropropane <1.10 u9/L 1.10 2.00 1 03/14/22 19:30 JLB V16104 1,2-Dibromoethane <0.200 N9/L 0.200 0.500 1 03/14/22 19:30 JLB V16104 Dibromomethane <0.230 u9/L 0.230 0.500 1 03/14/22 19:30 JLB V16104 trans-1,4-Dichloro-2-butene <1.30 N9/L 1.30 10.0 1 03/14/22 19:30 JLB V16104 1,2-Dichlorobenzene <0.220 u9/L 0.220 0.500 1 03/14/22 19:30 JLB V16104 1,4-Dichlorobenzene 1.68 N9/L 0.210 0.500 1 03/14/22 19:30 JLB V16104 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 03/14/22 19:30 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 56 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95884 Matrix: Aqueous Sample ID: LT-01-20220307 Sampled: 3/7/2022 14:23 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 V16327 03/16/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 03/14/22 19:30 JLB V16104 1,2-Dichloroethane <0.150 u9/L 0.150 0.500 1 03/14/22 19:30 JLB V16104 1,1-Dichloroethene <0.150 N9/L 0.150 0.500 1 03/14/22 19:30 JLB V16104 cis- 1,2-Dich loroethene <0.200 u9/L 0.200 0.500 1 03/14/22 19:30 JLB V16104 trans-1,2-Dichloroethene <0.180 N9/L 0.180 0.500 1 03/14/22 19:30 JLB V16104 1,2-Dichloropropane <0.190 u9/L 0.190 0.500 1 03/14/22 19:30 JLB V16104 cis- 1,3-Dich loropropene <0.210 N9/L 0.210 0.500 1 03/14/22 19:30 JLB V16104 trans-1,3-Dichloropropene <0.150 u9/L 0.150 0.500 1 03/14/22 19:30 JLB V16104 1,4-Dioxane 1073 N9/L 16.0 150 1 03/14/22 19:30 JLB V16104 Ethylbenzene <0.170 u9/L 0.170 0.500 1 03/14/22 19:30 JLB V16104 2-Hexanone <0.380 N9/L 0.380 5.00 1 03/14/22 19:30 JLB V16104 Methyl Ethyl Ketone (MEK) <0.710 u9/L 0.710 5.00 1 03/14/22 19:30 JLB V16104 4-Methyl-2-Pentanone <1.00 N9/L 1.00 5.00 1 03/14/22 19:30 JLB V16104 Methylene Chloride <0.330 u9/L 0.330 1.00 1 03/14/22 19:30 JLB V16104 Styrene <0.220 N9/L 0.220 0.500 1 03/14/22 19:30 JLB V16104 1,1,1,2-Tetrachloroethane <0.160 u9/L 0.160 0.500 1 03/14/22 19:30 JLB V16104 1,1,2,2-Tetrachloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 19:30 JLB V16104 Tetrachloroethene <0.220 u9/L 0.220 0.500 1 03/14/22 19:30 JLB V16104 Tetrahydrofuran 168 N9/L 15.0 100 10 03/16/2215:37 JLB V16328 Toluene <0.220 u9/L 0.220 0.500 1 03/14/22 19:30 JLB V16104 1,1,1-Trichloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 19:30 JLB V16104 1,1,2-Trichloroethane <0.096 u9/L 0.096 0.500 1 03/14/22 19:30 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 57 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95884 Matrix: Aqueous Sample ID: LT-01-20220307 Sampled: 3/7/2022 14:23 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 V16327 03/16/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Trichloroethene <0.180 Ng/L 0.180 0.500 1 03/14/22 19:30 JLB V16104 Trichlorofluoromethane <0.180 ug/L 0.180 0.500 1 03/14/22 19:30 JLB V16104 1,2,3-Trichloropropane <0.270 Ng/L 0.270 1.00 1 03/14/22 19:30 JLB V16104 Vinyl Acetate <1.00 ug/L 1.00 2.00 1 03/14/22 19:30 JLB V16104 Vinyl Chloride <0.170 Ng/L 0.170 0.500 1 03/14/22 19:30 JLB V16104 o-Xylene <0.210 ug/L 0.210 0.500 1 03/14/22 19:30 JLB V16104 m,p-Xylene <0.420 Ng/L 0.420 1.00 1 03/14/22 19:30 JLB V16104 Xylene (Total) <0.21 ug/L 0.210 0.500 1 03/14/22 19:30 V16104 Surrogate:4-Bromofluorobenzene 105 Limits:80-124% 1 03/14/22 19:30 JLB V16104 Surrogate: Dibromofluoromethane 92.0 Limits: 75-129% 1 03/14/22 19:30 JLB V16104 Surrogate: 1,2-Dichloroethane - d4 101 Limits: 63-136% 1 03/14/22 19:30 JLB V16104 Surrogate: Toluene-d8 97.6 Limits: 77-123% 1 03/14/22 19:30 JLB V16104 Surrogate:4-Bromofluorobenzene 104 Limits: 80-124% 10 03/16/22 15:37 JLB V16328 Surrogate: Dibromofluoromethane 94.6 Limits: 75-129% 10 03/16/22 15:37 JLB V16328 Surrogate: 1,2-Dichloroethane - d4 97.8 Limits: 63-136% 10 03/16/22 15:37 JLB V16328 Surrogate: Toluene-d8 95.2 Limits: 77-123% 10 03/16/22 15:37 JLB V16328 Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit J Estimated value Page 58 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95885 Matrix: Aqueous Sample ID : TB-20220307 Sampled: 3/7/2022 0:00 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 03/14/22 19:57 JLB V16104 Acrylonitrile <0.230 u9/L 0.230 5.00 1 03/14/22 19:57 JLB V16104 Benzene <0.180 N9/L 0.180 0.500 1 03/14/22 19:57 JLB V16104 Bromochloromethane <0.420 u9/L 0.420 1.00 1 03/14/22 19:57 JLB V16104 Bromodichloromethane <0.160 N9/L 0.160 0.500 1 03/14/22 19:57 JLB V16104 Bromoform <1.50 u9/L 1.50 5.00 1 03/14/22 19:57 JLB V16104 Bromomethane <0.280 N9/L 0.280 1.00 1 03/14/22 19:57 JLB V16104 Carbon Disulfide <0.150 u9/L 0.150 5.00 1 03/14/22 19:57 JLB V16104 Carbon Tetrachloride <0.180 N9/L 0.180 0.500 1 03/14/22 19:57 JLB V16104 Chlorobenzene <0.190 u9/L 0.190 0.500 1 03/14/22 19:57 JLB V16104 Chlorodibromomethane <0.190 N9/L 0.190 0.500 1 03/14/22 19:57 JLB V16104 Chloroethane <0.430 u9/L 0.430 1.00 1 03/14/22 19:57 JLB V16104 Chloroform <0.220 N9/L 0.220 0.500 1 03/14/22 19:57 JLB V16104 Chloromethane <0.220 u9/L 0.220 0.500 1 03/14/22 19:57 JLB V16104 Di -Isopropyl Ether (DIPE) <0.960 N9/L 0.960 5.00 1 03/14/22 19:57 JLB V16104 1,2-Dibromo-3-Chloropropane <1.10 u9/L 1.10 2.00 1 03/14/22 19:57 JLB V16104 1,2-Dibromoethane <0.200 N9/L 0.200 0.500 1 03/14/22 19:57 JLB V16104 Dibromomethane <0.230 u9/L 0.230 0.500 1 03/14/22 19:57 JLB V16104 trans-1,4-Dichloro-2-butene <1.30 N9/L 1.30 10.0 1 03/14/22 19:57 JLB V16104 1,2-Dichlorobenzene <0.220 u9/L 0.220 0.500 1 03/14/22 19:57 JLB V16104 1,4-Dichlorobenzene <0.210 N9/L 0.210 0.500 1 03/14/22 19:57 JLB V16104 Dichlorodifluoromethane <1.20 u9/L 1.20 5.00 1 03/14/22 19:57 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 59 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95885 Matrix: Aqueous Sample ID : TB-20220307 Sampled: 3/7/2022 0:00 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 03/14/22 19:57 JLB V16104 1,2-Dichloroethane <0.150 u9/L 0.150 0.500 1 03/14/22 19:57 JLB V16104 1,1-Dichloroethene <0.150 N9/L 0.150 0.500 1 03/14/22 19:57 JLB V16104 cis- 1,2-Dich loroethene <0.200 u9/L 0.200 0.500 1 03/14/22 19:57 JLB V16104 trans-1,2-Dichloroethene <0.180 N9/L 0.180 0.500 1 03/14/22 19:57 JLB V16104 1,2-Dichloropropane <0.190 u9/L 0.190 0.500 1 03/14/22 19:57 JLB V16104 cis- 1,3-Dich loropropene <0.210 N9/L 0.210 0.500 1 03/14/22 19:57 JLB V16104 trans-1,3-Dichloropropene <0.150 u9/L 0.150 0.500 1 03/14/22 19:57 JLB V16104 1,4-Dioxane <16.0 N9/L 16.0 150 1 03/14/22 19:57 JLB V16104 Ethylbenzene <0.170 u9/L 0.170 0.500 1 03/14/22 19:57 JLB V16104 2-Hexanone <0.380 N9/L 0.380 5.00 1 03/14/22 19:57 JLB V16104 Methyl Ethyl Ketone (MEK) <0.710 u9/L 0.710 5.00 1 03/14/22 19:57 JLB V16104 4-Methyl-2-Pentanone <1.00 N9/L 1.00 5.00 1 03/14/22 19:57 JLB V16104 Methylene Chloride <0.330 u9/L 0.330 1.00 1 03/14/22 19:57 JLB V16104 Styrene <0.220 N9/L 0.220 0.500 1 03/14/22 19:57 JLB V16104 1,1,1,2-Tetrachloroethane <0.160 u9/L 0.160 0.500 1 03/14/22 19:57 JLB V16104 1,1,2,2-Tetrachloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 19:57 JLB V16104 Tetrachloroethene <0.220 u9/L 0.220 0.500 1 03/14/22 19:57 JLB V16104 Tetrahydrofuran <1.50 N9/L 1.50 10.0 1 03/14/22 19:57 JLB V16104 Toluene <0.220 u9/L 0.220 0.500 1 03/14/22 19:57 JLB V16104 1,1,1-Trichloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 19:57 JLB V16104 1,1,2-Trichloroethane <0.096 u9/L 0.096 0.500 1 03/14/22 19:57 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 60 of 84 • Waypdint0 449 Springbrook Rd, Charlotte, .5 282& Main 704.529.636� ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Chuck Pippin 231 Haywood Street Asheville , NC 28801 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill GW Report Date : 03/22/2022 Information : C11460-01.02 Task 02 Received : 03/10/2022 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95885 Matrix: Aqueous Sample ID : TB-20220307 Sampled: 3/7/2022 0:00 Analytical Method: 8260D Prep Method: 5030E Test Results Trichloroethene <0.180 Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Prep Batch(es): V16102 03/14/22 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.180 0.500 Ng/L 0.270 1.00 Pg/L 1.00 2.00 Ng/L 0.170 0.500 Pg/L 0.210 0.500 Ng/L 0.420 1.00 Pg/L 0.210 0.500 103 Limits: 80-124% 95.8 Limits: 75-129% 100 Limits: 63-136% 93.2 Limits: 77-123% 1 03/14/22 19:57 JLB V16104 1 03/14/22 19:57 JLB V16104 1 03/14/22 19:57 JLB V16104 1 03/14/22 19:57 JLB V16104 1 03/14/22 19:57 JLB V16104 1 03/14/22 19:57 JLB V16104 1 03/14/22 19:57 JLB V16104 1 03/14/22 19:57 V16104 1 03/14/22 19:57 JLB V16104 1 03/14/22 19:57 JLB V16104 1 03/14/22 19:57 JLB V16104 1 03/14/22 19:57 JLB V16104 J Estimated value Page 61 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95886 Matrix: Aqueous Sample ID : TB-20220308 Sampled: 3/7/2022 0:00 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 03/14/22 14:05 JLB V16104 Acrylonitrile <0.230 u9/L 0.230 5.00 1 03/14/22 14:05 JLB V16104 Benzene <0.180 N9/L 0.180 0.500 1 03/14/22 14:05 JLB V16104 Bromochloromethane <0.420 u9/L 0.420 1.00 1 03/14/22 14:05 JLB V16104 Bromodichloromethane <0.160 N9/L 0.160 0.500 1 03/14/22 14:05 JLB V16104 Bromoform <1.50 u9/L 1.50 5.00 1 03/14/22 14:05 JLB V16104 Bromomethane <0.280 N9/L 0.280 1.00 1 03/14/22 14:05 JLB V16104 Carbon Disulfide <0.150 u9/L 0.150 5.00 1 03/14/22 14:05 JLB V16104 Carbon Tetrachloride <0.180 N9/L 0.180 0.500 1 03/14/22 14:05 JLB V16104 Chlorobenzene <0.190 u9/L 0.190 0.500 1 03/14/22 14:05 JLB V16104 Chlorodibromomethane <0.190 N9/L 0.190 0.500 1 03/14/22 14:05 JLB V16104 Chloroethane <0.430 u9/L 0.430 1.00 1 03/14/22 14:05 JLB V16104 Chloroform <0.220 N9/L 0.220 0.500 1 03/14/22 14:05 JLB V16104 Chloromethane <0.220 u9/L 0.220 0.500 1 03/14/22 14:05 JLB V16104 Di -Isopropyl Ether (DIPE) <0.960 N9/L 0.960 5.00 1 03/14/22 14:05 JLB V16104 1,2-Dibromo-3-Chloropropane <1.10 u9/L 1.10 2.00 1 03/14/22 14:05 JLB V16104 1,2-Dibromoethane <0.200 N9/L 0.200 0.500 1 03/14/22 14:05 JLB V16104 Dibromomethane <0.230 u9/L 0.230 0.500 1 03/14/22 14:05 JLB V16104 trans-1,4-Dichloro-2-butene <1.30 N9/L 1.30 10.0 1 03/14/22 14:05 JLB V16104 1,2-Dichlorobenzene <0.220 u9/L 0.220 0.500 1 03/14/22 14:05 JLB V16104 1,4-Dichlorobenzene <0.210 N9/L 0.210 0.500 1 03/14/22 14:05 JLB V16104 Dichlorodifluoromethane <1.20 u9/L 1.20 5.00 1 03/14/22 14:05 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 62 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill GW Chuck Pippin Report Date : 03/22/2022 231 Haywood Street Information : C11460-01.02 Task 02 Received : 03/10/2022 Asheville , NC 28801 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95886 Matrix: Aqueous Sample ID : TB-20220308 Sampled: 3/7/2022 0:00 Analytical Method: 8260D Prep Batch(es): V16102 03/14/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 N9/L 0.240 0.500 1 03/14/22 14:05 JLB V16104 1,2-Dichloroethane <0.150 u9/L 0.150 0.500 1 03/14/22 14:05 JLB V16104 1,1-Dichloroethene <0.150 N9/L 0.150 0.500 1 03/14/22 14:05 JLB V16104 cis- 1,2-Dich loroethene <0.200 u9/L 0.200 0.500 1 03/14/22 14:05 JLB V16104 trans-1,2-Dichloroethene <0.180 N9/L 0.180 0.500 1 03/14/22 14:05 JLB V16104 1,2-Dichloropropane <0.190 u9/L 0.190 0.500 1 03/14/22 14:05 JLB V16104 cis- 1,3-Dich loropropene <0.210 N9/L 0.210 0.500 1 03/14/22 14:05 JLB V16104 trans-1,3-Dichloropropene <0.150 u9/L 0.150 0.500 1 03/14/22 14:05 JLB V16104 1,4-Dioxane <16.0 N9/L 16.0 150 1 03/14/22 14:05 JLB V16104 Ethylbenzene <0.170 u9/L 0.170 0.500 1 03/14/22 14:05 JLB V16104 2-Hexanone <0.380 N9/L 0.380 5.00 1 03/14/22 14:05 JLB V16104 Methyl Ethyl Ketone (MEK) <0.710 u9/L 0.710 5.00 1 03/14/22 14:05 JLB V16104 4-Methyl-2-Pentanone <1.00 N9/L 1.00 5.00 1 03/14/22 14:05 JLB V16104 Methylene Chloride <0.330 u9/L 0.330 1.00 1 03/14/22 14:05 JLB V16104 Styrene <0.220 N9/L 0.220 0.500 1 03/14/22 14:05 JLB V16104 1,1,1,2-Tetrachloroethane <0.160 u9/L 0.160 0.500 1 03/14/22 14:05 JLB V16104 1,1,2,2-Tetrachloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 14:05 JLB V16104 Tetrachloroethene <0.220 u9/L 0.220 0.500 1 03/14/22 14:05 JLB V16104 Tetrahydrofuran <1.50 N9/L 1.50 10.0 1 03/14/22 14:05 JLB V16104 Toluene <0.220 u9/L 0.220 0.500 1 03/14/22 14:05 JLB V16104 1,1,1-Trichloroethane <0.160 N9/L 0.160 0.500 1 03/14/22 14:05 JLB V16104 1,1,2-Trichloroethane <0.096 u9/L 0.096 0.500 1 03/14/22 14:05 JLB V16104 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 63 of 84 • Waypdint0 449 Springbrook Rd, Charlotte, .5 282& Main 704.529.636� ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Chuck Pippin 231 Haywood Street Asheville , NC 28801 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill GW Report Date : 03/22/2022 Information : C11460-01.02 Task 02 Received : 03/10/2022 Report Number : 22-069-0024 REPOR T OF A NA L YSIS Lab No : 95886 Matrix: Aqueous Sample ID : TB-20220308 Sampled: 3/7/2022 0:00 Analytical Method: 8260D Prep Method: 5030E Test Results Trichloroethene <0.180 Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Prep Batch(es): V16102 03/14/22 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.180 0.500 Ng/L 0.270 1.00 Pg/L 1.00 2.00 Ng/L 0.170 0.500 Pg/L 0.210 0.500 Ng/L 0.420 1.00 Pg/L 0.210 0.500 107 Limits: 80-124% 93.0 Limits: 75-129% 91.2 Limits: 63-136% 96.2 Limits: 77-123% 1 03/14/22 14:05 JLB V16104 1 03/14/22 14:05 JLB V16104 1 03/14/22 14:05 JLB V16104 1 03/14/22 14:05 JLB V16104 1 03/14/22 14:05 JLB V16104 1 03/14/22 14:05 JLB V16104 1 03/14/22 14:05 JLB V16104 1 03/14/22 14:05 V16104 1 03/14/22 14:05 JLB V16104 1 03/14/22 14:05 JLB V16104 1 03/14/22 14:05 JLB V16104 1 03/14/22 14:05 JLB V16104 J Estimated value Page 64 of 84 • Waypoint, 449 Springbrook Charlotte, NC 28217 Rd, Ch Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill GW Report No: 22-069-0024 QC Analytical Batch: V16256 Analysis Method: 2340C-2011 Analysis Description: Total Hardness Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 95881, 95882, 95883 Blank MDL MQL Analyzed Parameter Units Result Hardness pg/L <570 570 5000 03/18/22 12:50 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Hardness pg/L 50000 50000 100 90-110 Duplicate V 95769-DUP Result DUP RPD Max RPD Analyzed Parameter Units Result Hardness pg/L <5000 <5000 0.0 20 03/18/22 12:50 Matrix Spike & Matrix Spike Duplicate V 95867-MS V 95867-MSD MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Hardness pg/L 24000 20000 20000 44000 44000 100 100 80-120 0.0 20 Date: 03/22/2022 01:46 PM Page 1 of 17 Page 65 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill GW Report No: 22-069-0024 QC Prep: V16097 QC Prep Batch Method: 3005A QC Analytical Batch(es): V16151,V16227,V16291 Analysis Method: 6020B Analysis Description: Metals Analyses Lab Reagent Blank LRB-V16097 Matrix: AQU Associated Lab Samples: 95874, 95875, 95876, 95877, 95878, 95879, 95880, 95881, 95882, 95883, 95884 Blank MDL MQL Analyzed Parameter Units Result Antimony pg/L <0.680 0.680 2.00 03/15/22 17:29 Arsenic pg/L <0.490 0.490 1.00 03/15/22 17:29 Barium pg/L <3.40 3.40 10.0 03/15/22 17:29 Beryllium pg/L <0.240 0.240 1.00 03/15/22 17:29 Cadmium pg/L <0.150 0.150 1.00 03/15/22 17:29 Chromium pg/L <1.00 1.00 2.00 03/15/22 17:29 Cobalt pg/L <0.080 0.080 1.00 03/15/22 17:29 Copper pg/L <0.890 0.890 2.00 03/15/22 17:29 Lead pg/L <0.500 0.500 1.00 03/15/22 17:29 Nickel pg/L <0.720 0.720 2.00 03/15/22 17:29 Selenium pg/L <2.30 2.30 5.00 03/15/22 17:29 Silver pg/L <0.130 0.130 1.00 03/15/22 17:29 Thallium pg/L <0.280 0.280 2.00 03/15/22 17:29 Vanadium pg/L <2.10 2.10 5.00 03/16/2215:54 Zinc pg/L <3.90 3.90 20.0 03/15/22 17:29 Laboratory Control Sample LCS-V16097 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Antimony pg/L 100 107 107 80-120 Arsenic pg/L 100 96.8 97.0 80-120 Barium pg/L 100 97.0 97.0 80-120 Beryllium pg/L 100 96.3 96.0 80-120 Cadmium pg/L 100 97.0 97.0 80-120 Chromium pg/L 100 95.7 96.0 80-120 Cobalt pg/L 100 99.4 99.0 80-120 Copper pg/L 100 99.1 99.0 80-120 Date: 03/22/2022 01:46 PM Page 2 of 17 Page 66 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill GW Report No: 22-069-0024 QC Prep: V16097 QC Prep Batch Method: 3005A Laboratory Control Sample LCS-V16097 QC Analytical Batch(es): V16151,V16227,V16291 Analysis Method: 6020B Analysis Description: Metals Analyses Parameter Units Spike Conc. LCS Result LCS %Rec % Rec Limits Lead pg/L 100 97.0 97.0 80-120 Nickel pg/L 100 99.0 99.0 80-120 Selenium pg/L 100 99.2 99.0 80-120 Silver pg/L 100 98.2 98.0 80-120 Thallium pg/L 100 89.9 90.0 80-120 Vanadium pg/L 100 97.0 97.0 80-120 Zinc pg/L 100 98.2 98.0 80-120 Matrix Spike & Matrix Spike Duplicate Parameter Units V 95757-MS-V16097 MS Spike Result Conc. V 95757-MSD-V16097 MSD MS Result Spike Conc. MSD Result MS %Rec MSD %Rec %Rec Limits RPD Max RPD Antimony pg/L < 0.680 100 100 109 107 109 107 75-125 1.8 20.0 Arsenic pg/L 1.11 100 100 96.6 95.9 95.0 95.0 75-125 0.7 20.0 Barium pg/L 73.8 100 100 165 164 91.0 90.0 75-125 0.6 20.0 Beryllium pg/L 0.656 100 100 93.5 95.5 93.0 95.0 75-125 2.1 20.0 Cadmium pg/L 318 100 100 419 408 101 90.0 75-125 2.6 20.0 Chromium pg/L < 1.00 100 100 91.6 93.0 92.0 93.0 75-125 1.5 20.0 Cobalt pg/L 99.5 100 100 192 192 93.0 93.0 75-125 0.0 20.0 Copper pg/L 25.1 100 100 120 119 95.0 94.0 75-125 0.8 20.0 Lead pg/L < 0.500 100 100 99.4 97.8 99.0 98.0 75-125 1.6 20.0 Nickel pg/L 13.3 100 100 107 105 94.0 92.0 75-125 1.8 20.0 Selenium pg/L < 2.30 100 100 103 104 103 104 75-125 0.9 20.0 Silver pg/L < 0.130 100 100 97.7 96.7 98.0 97.0 75-125 1.0 20.0 Thallium pg/L 0.744 100 100 92.9 91.4 92.0 91.0 75-125 1.6 20.0 Vanadium pg/L < 2.10 100 100 96.9 93.0 97.0 93.0 75-125 4.1 20.0 Zinc pg/L 8980 100 100 9150 8940 170* -40* 75-125 2.3 20.0 * QC Fail Date: 03/22/2022 01:46 PM Page 3 of 17 Page 67 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill GW Report No: 22-069-0024 QC Prep: V16097 QC Prep Batch Method: 3005A Post Digestion Spike Parameter Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium QC Analytical Batch(es): V16151,V16227,V16291 Analysis Method: 6020B Analysis Description: Metals Analyses V 95757-PDS-V16097 Units PDS Result 0/0 Recovery pg/L 55.8 112 pg/L 51.3 101 pg/L 85.7 99.0 pg/L 47.8 95.0 pg/L 211 101 pg/L 47.3 95.0 pg/L 100 100 pg/L 63.0 101 pg/L 50.1 100 pg/L 56.0 99.0 pg/L 51.8 104 pg/L 50.6 101 pg/L 48.6 96.0 pg/L 50.3 101 Analyzed 03/15/22 18:02 03/15/22 18:02 03/15/22 18:02 03/15/22 18:02 03/15/22 18:02 03/15/22 18:02 03/15/22 18:02 03/15/22 18:02 03/15/22 18:02 03/15/22 18:02 03/15/22 18:02 03/15/22 18:02 03/15/22 18:02 03/16/22 16:26 Date: 03/22/2022 01:46 PM Page 4 of 17 Page 68 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill GW Report No: 22-069-0024 QC Prep: V16136 QC Prep Batch Method: 3005A QC Analytical Batch(es): V16152,V16291 Analysis Method: 6020B Analysis Description: Metals Analyses Lab Reagent Blank LRB-V16136 Matrix: AQU Associated Lab Samples: 95874, 95875, 95876, 95878 Blank MDL MQL Analyzed Parameter Units Result Dissolved Arsenic pg/L <0.490 0.490 1.00 03/15/22 20:40 Dissolved Barium pg/L <3.40 3.40 10.0 03/15/22 20:40 Dissolved Beryllium pg/L <0.240 0.240 1.00 03/15/22 20:40 Dissolved Cadmium pg/L <0.150 0.150 1.00 03/15/22 20:40 Dissolved Chromium pg/L <1.00 1.00 2.00 03/15/22 20:40 Dissolved Cobalt pg/L <0.080 0.080 1.00 03/15/22 20:40 Dissolved Copper pg/L <0.890 0.890 2.00 03/15/22 20:40 Dissolved Lead pg/L <0.500 0.500 1.00 03/15/22 20:40 Dissolved Nickel pg/L <0.720 0.720 2.00 03/15/22 20:40 Dissolved Selenium pg/L <2.30 2.30 5.00 03/15/22 20:40 Dissolved Silver pg/L <0.130 0.130 1.00 03/15/22 20:40 Dissolved Thallium pg/L <0.280 0.280 2.00 03/15/22 20:40 Dissolved Vanadium pg/L <2.10 2.10 5.00 03/15/22 20:40 Dissolved Zinc pg/L <3.90 3.90 20.0 03/15/22 20:40 Laboratory Control Sample LCS-V16136 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Dissolved Arsenic pg/L 100 92.0 92.0 80-120 Dissolved Barium pg/L 100 95.7 96.0 80-120 Dissolved Beryllium pg/L 100 86.8 87.0 80-120 Dissolved Cadmium pg/L 100 96.0 96.0 80-120 Dissolved Chromium pg/L 100 88.6 89.0 80-120 Dissolved Cobalt pg/L 100 92.7 93.0 80-120 Dissolved Copper pg/L 100 91.7 92.0 80-120 Dissolved Lead pg/L 100 95.3 95.0 80-120 Dissolved Nickel pg/L 100 91.5 92.0 80-120 Date: 03/22/2022 01:46 PM Page 5 of 17 Page 69 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill GW Report No: 22-069-0024 QC Prep: V16136 QC Analytical Batch(es): V16152,V16291 QC Prep Batch Method: 3005A Analysis Method: 6020B Analysis Description: Metals Analyses Laboratory Control Sample LCS-V16136 Parameter Units Spike Conc. LCS Result LCS %Rec % Rec Limits Dissolved Selenium pg/L 100 106 106 80-120 Dissolved Silver pg/L 100 93.9 94.0 80-120 Dissolved Thallium pg/L 100 94.4 94.0 80-120 Dissolved Vanadium pg/L 100 89.2 89.0 80-120 Dissolved Zinc pg/L 100 93.7 94.0 80-120 Matrix Spike & Matrix Spike Duplicate Parameter Units V 95874-V16055-MS-V16136 MS Spike MSD Result Conc. Spike Conc. V 95874-V16055-MSD-V16136 MS Result MSD MS Result %Rec MSD %Rec %Rec Limits RPD Max RPD Dissolved Arsenic pg/L < 0.490 100 100 94.0 92.5 94.0 93.0 75-125 1.6 20.0 Dissolved Barium pg/L 108 100 100 197 204 89.0 96.0 75-125 3.4 20.0 Dissolved Beryllium pg/L < 0.240 100 100 89.3 92.7 89.0 93.0 75-125 3.7 20.0 Dissolved Cadmium pg/L < 0.150 100 100 94.4 95.2 94.0 95.0 75-125 0.8 20.0 Dissolved Chromium pg/L < 1.00 100 100 90.5 89.7 91.0 90.0 75-125 0.8 20.0 Dissolved Cobalt pg/L 106 100 100 198 197 92.0 91.0 75-125 0.5 20.0 Dissolved Copper pg/L < 0.890 100 100 92.0 92.4 92.0 92.0 75-125 0.4 20.0 Dissolved Lead pg/L < 0.500 100 100 94.0 93.3 94.0 93.0 75-125 0.7 20.0 Dissolved Nickel pg/L 13.8 100 100 105 104 91.0 90.0 75-125 0.9 20.0 Dissolved Selenium pg/L < 2.30 100 100 109 106 109 106 75-125 2.7 20.0 Dissolved Silver pg/L < 0.130 100 100 94.1 107 94.0 107 75-125 12.8 20.0 Dissolved Thallium pg/L 0.717 100 100 92.0 92.9 91.0 92.0 75-125 0.9 20.0 Dissolved Vanadium pg/L < 2.10 100 100 89.4 88.7 89.0 89.0 75-125 0.7 20.0 Dissolved Zinc pg/L 15.2 100 100 108 107 93.0 92.0 75-125 0.9 20.0 Date: 03/22/2022 01:46 PM Page 6 of 17 Page 70 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill GW Report No: 22-069-0024 QC Prep: V16136 QC Analytical Batch(es): V16152,V16291 QC Prep Batch Method: 3005A Analysis Method: 6020B Analysis Description: Metals Analyses Post Digestion Spike V 95874-V16055-PDS-V16136 Parameter Units PDS Result % Recovery Analyzed Dissolved Arsenic Ng/L 50.6 101 03/15/22 21:25 Dissolved Barium pg/L 105 101 03/15/22 21:25 Dissolved Beryllium pg/L 51.1 102 03/17/22 18:27 Dissolved Cadmium pg/L 50.1 100 03/15/22 21:25 Dissolved Chromium pg/L 49.1 98.0 03/15/22 21:25 Dissolved Cobalt pg/L 102 99.0 03/15/22 21:25 Dissolved Copper pg/L 50.7 101 03/15/22 21:25 Dissolved Lead Ng/L 50.9 102 03/15/22 21:25 Dissolved Nickel pg/L 56.7 100 03/15/22 21:25 Dissolved Selenium pg/L 51.8 104 03/15/22 21:25 Dissolved Silver pg/L 47.5 95.0 03/15/22 21:25 Dissolved Thallium pg/L 49.6 98.0 03/15/22 21:25 Dissolved Vanadium pg/L 47.4 95.0 03/15/22 21:25 Dissolved Zinc Ng/L 58.8 102 03/15/22 21:25 Date: 03/22/2022 01:46 PM Page 7 of 17 Page 71 of 84 • Waypoint, 449 Springbrook Rd, Ch Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill GW Report No: 22-069-0024 QC Prep: V16396 QC Analytical Batch(es): V16397,V16408 QC Prep Batch Method: 3005A Analysis Method: 6020B Analysis Description: Metals Analyses Lab Reagent Blank LRB-V16396 Matrix: AQU Associated Lab Samples: 95874, 95875, 95876, 95878 Blank MDL MQL Analyzed Parameter Units Result Dissolved Antimony pg/L <0.680 0.680 2.00 03/21/22 15:52 Laboratory Control Sample LCS-V16396 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Dissolved Antimony pg/L 100 88.6 89.0 80-120 Matrix Spike & Matrix Spike Duplicate V 95876-V16395-MS-V16396 V 95876-V16395-MSD-V16396 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Dissolved Antimony pg/L < 0.680 100 100 98.0 102 98.0 102 75-125 4.0 20.0 Post Digestion Spike V 95876-V16395-PDS-V16396 PDS % Analyzed Parameter Units Result Recovery Dissolved Antimony pg/L 46.3 93.0 03/21/22 20:29 Date: 03/22/2022 01:46 PM Page 8 of 17 Page 72 of 84 • Waypoint, 449 Springbrook Rd, Ch Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill GW Report No: 22-069-0024 QC Prep: V16057 QC Analytical Batch(es): V16141 QC Prep Batch Method: 7470A Analysis Method: 7470A Analysis Description: Total Aqueous Mercury Analysis - CVAA Lab Reagent Blank LRB-V16057 Matrix: AQU Associated Lab Samples: 95874, 95875, 95876, 95878 Blank MDL MQL Analyzed Parameter Units Result Dissolved Mercury pg/L 0.000 0.000 0.200 03/15/22 14:42 Laboratory Control Sample LCS-V16057 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Dissolved Mercury pg/L 9.38 9.46 101 80-120 Matrix Spike & Matrix Spike Duplicate V 95876-V16055-MS-V16057 V 95876-V16055-MSD-V16057 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Dissolved Mercury pg/L <0.0700 9.38 9.38 9.51 9.39 101 100 80-120 1.2 20 Post Digestion Spike V 95876-V16055-PDS-V16057 PDS % Analyzed Parameter Units Result Recovery Dissolved Mercury pg/L 4.64 99.0 03/15/22 15:00 Date: 03/22/2022 01:46 PM Page 9 of 17 Page 73 of 84 • Waypoint, 449 Springbrook Rd, Ch Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill GW Report No: 22-069-0024 QC Prep: V16157 QC Analytical Batch(es): V16240 QC Prep Batch Method: 7470A Analysis Method: 7470A Analysis Description: Total Aqueous Mercury Analysis - CVAA Lab Reagent Blank LRB-V16157 Matrix: AQU Associated Lab Samples: 95874, 95875, 95876, 95877, 95878, 95879, 95880, 95881, 95882, 95883, 95884 Blank MDL MQL Analyzed Parameter Units Result Mercury (Total) pg/L <0.0700 0.0700 0.200 03/16/22 17:54 Laboratory Control Sample LCS-V16157 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Mercury (Total) pg/L 9.38 9.61 103 80-120 Matrix Spike & Matrix Spike Duplicate V 95874-MS-V16157 V 95874-MSD-V16157 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Mercury (Total) pg/L <0.0700 9.38 9.38 7.77 7.62 83.0 81.0 80-120 1.9 20 Post Digestion Spike V 95874-PDS-V16157 PDS % Analyzed Parameter Units Result Recovery Mercury (Total) pg/L 4.25 91.0 03/16/22 18:14 Date: 03/22/2022 01:46 PM Page 10 of 17 Page 74 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill GW Report No: 22-069-0024 QC Prep: V16012 QC Analytical Batch(es): V16014 QC Prep Batch Method: 5030B Analysis Method: 8260D SIM Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V16012 Matrix: AQU Associated Lab Samples: 95874, 95875, 95876, 95877, 95878, 95879, 95880, 95881, 95882, 95883, 95884 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,4-Dioxane pg/L <0.139 0.139 2.00 03/11/2214:40 4-Bromofluorobenzene (S) 03/11/22 14:40 106 70-130 Laboratory Control Sample LCS-V16012 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits 1,4-Dioxane pg/L 50.0 53.4 107 70-130 4-Bromofluorobenzene (S) 126 70-130 Matrix Spike & Matrix Spike Duplicate V 95884-MS-V16012 V 95884-MSD-V16012 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD Conc. 1,4-Dioxane pg/L 106 50.0 50.0 134 132 56.0* 52.0* 70-130 4-Bromofluorobenzene (S) 135* 136* 70-130 * QC Fail Date: 03/22/2022 01:46 PM Page 11 of 17 Page 75 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill GW Report No: 22-069-0024 QC Prep: V16102 QC Prep Batch Method: 5030B QC Analytical Batch(es): V16104 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V16102 Matrix: AQU Associated Lab Samples: 95874, 95875, 95876, 95877, 95878, 95879, 95880, 95881, 95882, 95883, 95884, 95885, 95886 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Acetone pg/L <1.80 1.80 5.00 03/14/22 13:38 Acrylonitrile pg/L <0.230 0.230 5.00 03/14/22 13:38 Benzene pg/L <0.180 0.180 0.500 03/14/22 13:38 Bromochloromethane pg/L <0.420 0.420 1.00 03/14/22 13:38 Bromodichloromethane pg/L <0.160 0.160 0.500 03/14/22 13:38 Bromoform pg/L <1.50 1.50 5.00 03/14/22 13:38 Bromomethane pg/L <0.280 0.280 1.00 03/14/22 13:38 Carbon Disulfide pg/L <0.150 0.150 5.00 03/14/22 13:38 Carbon Tetrachloride pg/L <0.180 0.180 0.500 03/14/22 13:38 Chlorobenzene pg/L <0.190 0.190 0.500 03/14/22 13:38 Chlorodibromomethane pg/L <0.190 0.190 0.500 03/14/22 13:38 Chloroethane pg/L <0.430 0.430 1.00 03/14/22 13:38 Chloroform pg/L <0.220 0.220 0.500 03/14/22 13:38 Chloromethane pg/L <0.220 0.220 0.500 03/14/22 13:38 Di -Isopropyl Ether (DIPE) pg/L <0.960 0.960 5.00 03/14/22 13:38 1,2-Dibromo-3-Chloropropane pg/L <1.10 1.10 2.00 03/14/22 13:38 1,2-Dibromoethane pg/L <0.200 0.200 0.500 03/14/22 13:38 Dibromomethane pg/L <0.230 0.230 0.500 03/14/22 13:38 trans-1,4-Dichloro-2-butene pg/L < 1.30 1.30 10.0 03/14/22 13:38 1,2-Dichlorobenzene pg/L <0.220 0.220 0.500 03/14/22 13:38 1,4-Dichlorobenzene pg/L <0.210 0.210 0.500 03/14/22 13:38 Dichlorodifluoromethane pg/L <1.20 1.20 5.00 03/14/22 13:38 1,1-Dichloroethane pg/L <0.240 0.240 0.500 03/14/22 13:38 1,2-Dichloroethane pg/L <0.150 0.150 0.500 03/14/22 13:38 1,1-Dichloroethene pg/L <0.150 0.150 0.500 03/14/22 13:38 cis-1,2-Dichloroethene pg/L <0.200 0.200 0.500 03/14/22 13:38 trans-1,2-Dichloroethene pg/L <0.180 0.180 0.500 03/14/22 13:38 Date: 03/22/2022 01:46 PM Page 12 of 17 Page 76 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill GW Report No: 22-069-0024 QC Prep: V16102 QC Prep Batch Method: 5030B QC Analytical Batch(es): V16104 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V16102 Matrix: AQU Associated Lab Samples: 95874, 95875, 95876, 95877, 95878, 95879, 95880, 95881, 95882, 95883, 95884, 95885, 95886 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,2-Dichloropropane pg/L <0.190 0.190 0.500 03/14/22 13:38 cis-1,3-Dichloropropene pg/L <0.210 0.210 0.500 03/14/22 13:38 trans-1,3-Dichloropropene pg/L <0.150 0.150 0.500 03/14/22 13:38 1,4-Dioxane pg/L <16.0 16.0 150 03/14/22 13:38 Ethylbenzene pg/L <0.170 0.170 0.500 03/14/22 13:38 2-Hexanone pg/L <0.380 0.380 5.00 03/14/22 13:38 Methyl Ethyl Ketone (MEK) pg/L <0.710 0.710 5.00 03/14/22 13:38 4-Methyl-2-Pentanone pg/L <1.00 1.00 5.00 03/14/22 13:38 Methylene Chloride pg/L <0.330 0.330 1.00 03/14/22 13:38 Styrene pg/L <0.220 0.220 0.500 03/14/22 13:38 1,1,1,2-Tetrachloroethane pg/L <0.160 0.160 0.500 03/14/22 13:38 1,1,2,2-Tetrachloroethane pg/L <0.160 0.160 0.500 03/14/22 13:38 Tetrachloroethene pg/L <0.220 0.220 0.500 03/14/22 13:38 Tetrahydrofuran pg/L <1.50 1.50 10.0 03/14/22 13:38 Toluene pg/L <0.220 0.220 0.500 03/14/22 13:38 1,1,1-Trichloroethane pg/L <0.160 0.160 0.500 03/14/22 13:38 1,1,2-Trichloroethane pg/L <0.096 0.096 0.500 03/14/22 13:38 Trichloroethene pg/L <0.180 0.180 0.500 03/14/22 13:38 Trichlorofluoromethane pg/L <0.180 0.180 0.500 03/14/22 13:38 1,2,3-Trichloropropane pg/L <0.270 0.270 1.00 03/14/22 13:38 Vinyl Acetate pg/L <1.00 1.00 2.00 03/14/22 13:38 Vinyl Chloride pg/L <0.170 0.170 0.500 03/14/22 13:38 o-Xylene pg/L <0.210 0.210 0.500 03/14/22 13:38 m,p-Xylene pg/L <0.420 0.420 1.00 03/14/22 13:38 4-Bromofluorobenzene (S) 03/14/22 13:38 109 80-124 Dibromofluoromethane (S) 03/14/22 13:38 89.8 75-129 1,2-Dichloroethane - d4 (S) 03/14/22 13:38 89.8 63-136 Date: 03/22/2022 01:46 PM Page 13 of 17 Page 77 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill GW Report No: 22-069-0024 QC Prep: V16102 QC Prep Batch Method: 5030B QC Analytical Batch(es): V16104 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V16102 Matrix: AQU Associated Lab Samples: 95874, 95875, 95876, 95877, 95878, 95879, 95880, 95881, 95882, 95883, 95884, 95885, 95886 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Toluene-d8 (S) 03/14/22 13:38 96.6 77-123 Laboratory Control Sample & LCSD Parameter Units LCS-V16102 Spike Conc. LCSD-V16102 LCS Result LCSD Result LCS %Rec LCSD a/o Rec % Rec Limits RPD Max RPD Acetone pg/L 40.0 38.1 36.3 95.2 90.7 40-166 4.8 20.0 Acrylonitrile pg/L 40.0 40.1 40.7 100 102 81-127 1.4 20.0 Benzene pg/L 20.0 19.9 19.4 99.5 97.0 77-128 2.5 20.0 Bromochloromethane pg/L 20.0 20.8 19.1 104 95.5 78-135 8.5 20.0 Bromodichloromethane pg/L 20.0 19.4 18.7 97.0 93.5 76-138 3.6 20.0 Bromoform pg/L 20.0 20.6 21.3 103 107 71-135 3.3 20.0 Bromomethane pg/L 20.0 19.0 18.6 95.0 93.0 41-168 2.1 20.0 Carbon Disulfide pg/L 20.0 18.2 16.4 91.0 82.0 59-135 10.4 20.0 Carbon Tetrachloride pg/L 20.0 21.4 18.4 107 92.0 72-142 15.0 20.0 Chlorobenzene pg/L 20.0 19.3 19.4 96.5 97.0 78-119 0.5 20.0 Chlorodibromomethane pg/L 20.0 19.8 19.9 99.0 99.5 75-134 0.5 20.0 Chloroethane pg/L 20.0 22.2 20.9 111 105 57-142 6.0 20.0 Chloroform pg/L 20.0 19.7 18.6 98.5 93.0 77-130 5.7 20.0 Chloromethane pg/L 20.0 20.5 19.6 103 98.0 47-145 4.4 20.0 Di -Isopropyl Ether (DIPE) pg/L 20.0 19.3 19.0 96.5 95.0 60-154 1.5 20.0 1,2-Dibromo-3-Chloropropane pg/L 20.0 21.9 22.5 110 113 63-134 2.7 20.0 1,2-Dibromoethane pg/L 20.0 19.7 20.1 98.5 101 77-135 2.0 20.0 Dibromomethane pg/L 20.0 20.0 19.6 100 98.0 76-138 2.0 20.0 trans-1,4-Dichloro-2-butene pg/L 20.0 21.9 23.2 110 116 70-130 5.7 20.0 1,2-Dichlorobenzene pg/L 20.0 21.8 20.3 109 102 78-128 7.1 20.0 1,4-Dichlorobenzene pg/L 20.0 19.8 19.0 99.0 95.0 75-126 4.1 20.0 Date: 03/22/2022 01:46 PM Page 14 of 17 Page 78 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill GW Report No: 22-069-0024 QC Prep: V16102 QC Analytical Batch(es): V16104 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V16102 LCSD-V16102 Parameter Units Spike Conc. LCS Result LCSD Result LCS %Rec LCSD % Rec % Rec Limits RPD Max RPD Dichlorodifluoromethane pg/L 20.0 23.0 21.6 115 108 28-163 6.2 20.0 1,1-Dichloroethane pg/L 20.0 20.1 18.8 101 94.0 70-130 6.6 20.0 1,2-Dichloroethane pg/L 20.0 18.3 17.6 91.5 88.0 68-131 3.8 20.0 1,1-Dichloroethene pg/L 20.0 19.8 18.4 99.0 92.0 70-154 7.3 20.0 cis-1,2-Dichloroethene pg/L 20.0 19.9 18.9 99.5 94.5 76-141 5.1 20.0 trans-1,2-Dichloroethene pg/L 20.0 19.5 18.8 97.5 94.0 76-135 3.6 20.0 1,2-Dichloropropane pg/L 20.0 19.7 19.0 98.5 95.0 77-130 3.6 20.0 cis-1,3-Dichloropropene pg/L 20.0 19.5 18.9 97.5 94.5 65-140 3.1 20.0 trans-1,3-Dichloropropene pg/L 20.0 19.5 18.9 97.5 94.5 67-140 3.1 20.0 1,4-Dioxane pg/L 200 212 187 106 93.5 70-130 12.5 20.0 Ethylbenzene pg/L 20.0 18.2 17.7 91.0 88.5 80-127 2.7 20.0 2-Hexanone pg/L 20.0 19.7 20.4 98.5 102 64-137 3.4 20.0 Methyl Ethyl Ketone (MEK) pg/L 20.0 22.3 20.9 112 105 71-134 6.4 20.0 4-Methyl-2-Pentanone pg/L 20.0 19.3 19.0 96.5 95.0 69-134 1.5 20.0 Methylene Chloride pg/L 20.0 18.4 18.0 92.0 90.0 73-131 2.1 20.0 Styrene pg/L 20.0 18.1 18.9 90.5 94.5 78-129 4.3 20.0 1,1,1,2-Tetrachloroethane pg/L 20.0 18.9 18.5 94.5 92.5 79-134 2.1 20.0 1,1,2,2-Tetrachloroethane pg/L 20.0 21.9 21.2 110 106 62-127 3.2 20.0 Tetrachloroethene pg/L 20.0 19.4 18.3 97.0 91.5 80-129 5.8 20.0 Tetrahydrofuran pg/L 20.0 18.4 18.1 92.0 90.5 70-130 1.6 20.0 Toluene pg/L 20.0 19.1 18.6 95.5 93.0 76-131 2.6 20.0 1,1,1-Trichloroethane pg/L 20.0 20.7 19.0 104 95.0 75-135 8.5 20.0 1,1,2-Trichloroethane pg/L 20.0 19.7 19.8 98.5 99.0 70-140 0.5 20.0 Trichloroethene pg/L 20.0 19.4 18.6 97.0 93.0 77-133 4.2 20.0 Trichlorofluoromethane pg/L 20.0 20.6 19.1 103 95.5 62-148 7.5 20.0 1,2,3-Trichloropropane pg/L 20.0 24.1 23.0 121 115 71-127 4.6 20.0 Date: 03/22/2022 01:46 PM Page 15 of 17 Page 79 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill GW Report No: 22-069-0024 QC Prep: V16102 QC Analytical Batch(es): V16104 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V16102 LCSD-V16102 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD Vinyl Acetate pg/L 20.0 20.8 20.7 104 104 34-167 0.4 20.0 Vinyl Chloride pg/L 20.0 21.4 18.4 107 92.0 57-141 15.0 20.0 o-Xylene pg/L 20.0 18.0 18.0 90.0 90.0 78-128 0.0 20.0 m,p-Xylene pg/L 40.0 37.9 37.0 94.7 92.5 77-133 2.4 20.0 4-Bromofluorobenzene (S) 109 107 80-124 Dibromofluoromethane (S) 92.4 91.2 75-129 1,2-Dichloroethane - d4 (S) 91.0 90.2 63-136 Toluene-d8 (S) 95.6 98.0 77-123 Date: 03/22/2022 01:46 PM Page 16 of 17 Page 80 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill GW Report No: 22-069-0024 QC Prep: V16327 QC Analytical Batch(es): V16328 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V16327 Matrix: AQU Associated Lab Samples: 95884 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Tetrahydrofuran pg/L <1.50 1.50 10.0 03/16/22 13:49 4-Bromofluorobenzene (S) 03/16/22 13:49 107 80-124 Dibromofluoromethane (S) 03/16/22 13:49 94.0 75-129 1,2-Dichloroethane - d4 (S) 03/16/22 13:49 97.4 63-136 Toluene-d8 (S) 03/16/22 13:49 94.6 77-123 Laboratory Control Sample & LCSD LCS-V16327 LCSD-V16327 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD Tetrahydrofuran pg/L 20.0 17.2 17.4 86.0 87.0 70-130 1.1 20.0 4-Bromofluorobenzene (S) 105 106 80-124 Dibromofluoromethane (S) 94.4 92.6 75-129 1,2-Dichloroethane - d4 (S) 96.6 96.4 63-136 Toluene-d8 (S) 95.8 96.2 77-123 Date: 03/22/2022 01:46 PM Page 17 of 17 Page 81 of 84 WayPAoint. NALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Shipment Receipt Form Customer Number: 01015 Customer Name: Anchor QEA of North Carolina, PLLC Report Number: 22-069-0024 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client # Courier 0 Other: Thermometer ID: IRT-15 0AC Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers/boxes received 2 Custody seals intact on shipping container/cooler? Yes 0 No 0 Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample Iabel(s)? (0) Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? U Yes 0 No Sample containers intact? 0 Yes 0 No Sufficient sample volume for indicated test(s)? U Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? 0 Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. U Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No 0 N/A Water - VOA vials free of headspace 0 Yes 0 No 0 N/A Trip Blanks received with VOAs 0 Yes 0 No 0 N/A Soil VOA method 5035 — compliance criteria met F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) Special precautions or instructions included? Comments: 0 Yes 0 No U N/A F Low concentration EnCore samplers (48 hr) Low conc pre -weighed vials (Sod Bis -14 d) 0Yes ONo Signature: Sarah J. Locklear Date & Time: 03/10/2022 16:36:30 Page 82 of 84 CZ Im mn N r n m m 9r �n ng r m A a N xx a o0 r fl Mm m �o n cn ^rm ` mm o R N m f-10 N xm m m -ono CLL n _: 0 V.- U 3 ('O m z i 0(nmmT m cp D w 0 r r = ❑ ❑ a n n m ° a ❑ O m n y -0 Z n G � m _ n- CL m 4 =3o c: ao Ol °� ma y�mm Y. o x�mY it n I>t Ix Ix I`- r- IA Ix IxIx IA Ix )'C' r n Epp: m T c r� m yam m G 3 d +„ m Sm to m mm at➢ a Y- �2 a y C] v�3 �-� c❑Q vmN y m R m;� F x �I ❑ Ll 0 za o o 9 ti- 1 w 2. x W N- •C (Q yn� �mmy L y❑ y N ,r y x aC ~ fD N n N N N L FRa w rm-� 0> CL r S A9 1CFn 4 J w 31.m 8.. a N n = x N N r G7 rn y �[ a<m H a C x cn m 0 R �c o c n Ic 0 A d � 2 a CL O w a C m � CL a an„ 7 T•.'Z w j p i C (� Q 7� m m V ] m 0 } n 9 O m TvN W � 1 r 0 �. n 9 <� m Ji X � o a= ❑ r � • • m m 5= 0-9 rn d m ml,¢nm l,m m r a A a 00 -a Uf OM `-02 MM CD i a a 1 1 C . Z o a 0 �p O 7- m M, rn _ m p Z0> 3 y G Y ❑ =wLFn to )0) � _• ❑ i q � N 14 �� qO a m XC y z0 \ m n fn fI ° m o I I! 1 a T ,! n Page 83 of 84 C C� rZ L n a 3 3 CD f � 1 a [9 4 V m n ca �2 a d z m 1� Timm'IV ��C ro am a om a,� yW �t ,_ c G CL to n 7 y t' L7. 7 0 N U) Z: N n x C rrr- x m a m , . I{m� I3 It'l"- � N _b o r-a r:1 fro n. m. N��m 3 E' a fn �m :r C `.7 m U � Nunn k 1'� x w N man m m I" mP am 1D vMm. Q 0 C f" m M n m m 0 co p N W �° Z ? i m L L a�m s x a�o�a= Fn ° H C 0 z �' N p N p o a v n_ r0C m O UP-` �aa� a "A � jx Hm➢gym r' w c o L: r� ma ° s N 0 C3 M m n m 1 0 n anm i 3 �❑ L1 D q r n O_ m c a D n a �� m � 0 1t o m �r O = x y rn 0 3 r G) 0 m m cn 0 z a m r > ° ti s a' a Q C D �• m 0 ro n y " m m o m N � N aca7710 �,I� o N a C CD_ m mn D � 3 m r m 'm n CD rn C M m r� 0 m � xa � v In �M\MNNW I 1 I I I ° �I4111IIn Page 84 of 84 Tetrachloroethene (PCE) 5 4 1 1 I 1 �3 c 0 M I c 2 c 0 v 1 0 I q CJ" 1 20082010201220142016201820202022 Date 14 12 10 c 0 8 M c (tj 6 c 0 V 4 2 0 z11r�; 2077 2075 $ c 0 2073 a'>i w 2071 3 2069 0 ti� 2067 2065 Trichloroethene (TCE) 6 5 J 4 \ c 0 3 c v o 2 V is 20082010201220142016201820202022 Date 2079 ZU.0 2077 17.5 15.0 2075 � o .2 J \ 0) 12.5 2073 T w 2 10.0 2071 c 7.5 2069 0 v �7 5.0 2067 2.5 2065 0.0 20082010201220142016201820202022 20082010201220142016201820202022 Date Date Benzene 1,4-Dichlorobenzene Notes: 1. Dashed horizontal lines represent the 2L groundwater standard. 2. Dashed vertical lines represent the start of leachate extraction. 3. Non -detects are plotted as an open symbol at the method detection limit. 4. Data presented are from semiannual sampling events from 2007 to Spring 2022. µg/L: micrograms per liter ft:feet Publish Date: 06/01/2022 13:44 PM I User: SYR-SCOL File Path: \\athena\Asheville\Projects\Jackson County`Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py kZANCHOR QEA IKIg' 2077 2075 $ 01 2073 v w 2071 3 2069 0 A, 2067 2065 40 35 30 J 25 c 20 c c 15 0 V 10 5 0 Cis- 1,2-Dichloroethene 20082010201220142016201820202022 Date 2079 20.0 2077 17.5 1 1 2075 o 15.0 0 1 2073 v E c 12.5 L, 0 �y=, 1 I 2071 u � 10.0 1 v 1 2069 c 0 U 7.5 , i 5.0 1 1 ; 2067 2.5 2065 0.0 20082010201220142016201820202022 Date 1,4-Dioxane 2079 101 2077 2075 $ � o J 2073 =L 100 a' , w 2071 v c U 0 2069 Do 10-1 2067 2065 79 77 75 c 0 73 rO v w 71 3 69 0 y 67 65 Vinyl Chloride i I 1 1 1 1 1 I 1 � -7 v ----- ------- ---------------------- 20082010201220142016201820202022 Date Constituent Key with 2L Standards f Tetrachloroethene (PCE) (0.70 µg/L) Trichloroethene (TCE) (3 µg/L) cis-1,2-Dichloroethene (70 µg/L) f Vinyl Chloride (0.03 µg/L) f Benzene (1 µg/L) f 1,4-Dichlorobenzene (6 µg/L) 1,4-Dioxane (3 µg/L) Groundwater Elevation (ft) -- Leachate Extraction Start Date 2079 2077 2075 $ c 0 2073 w 2071 3 2069 0 6 2067 2065 Figure 4 Hydrograph and Constituents of Concern Versus Time - MW-01 Spring 2022 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landifll 5 4 �3 c 0 M c 2 c 0 U 1 a 14 12 10 c 0 8 c 0 6 c 0 U 4 2 0 20082010201220142016201820202022 Date Benzene Tetrachloroethene (PCE) 1 I I I 1 I 1 i 1 I 1 I 1 1 1 1 i 20082010201220142016201820202022 Date Notes: 1. Dashed horizontal lines represent the 2L groundwater standard. 2. Dashed vertical lines represent the start of leachate extraction. 3. Non -detects are plotted as an open symbol at the method detection limit. 4. Data presented are from semiannual sampling events from 2007 to Spring 2022. µg/L: micrograms per liter ft:feet 1990 1988 1986 1984 1982 0 1980 > 1978 1976 1974 O 1972 1970 1968 1966 J \ c 0 c v c 0 U 6 5 1 0 20082010201220142016201820202022 Date 90 ZU.0 88 17.5 86 84 15.0 82 .0 M 12.5 80 a', w 78 — 10.0 76 0 74 0 7.5 0 U 72 17 5.0 70 68 2.5 66 0.0 Publish Date: 06/01/2022 13:44 PM I User: SYR-SCOL File Path: \\athena\Asheville\Projects\Jackson County`Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py kZANCHOR QEA 20082010201220142016201820202022 Date 1,4-Dichlorobenzene 190 188 186 184 !82 o 180 v !78 v 176 3 174 O 172 170 168 166 40 35 30 J 25 c 0 20 c c 15 0 U 10 5 0 Cis- 1,2-Dichloroethene 20082010201220142016201820202022 Date 1990 I 1988 20.0 1986 17.5 ' 1 1984 ' 1982 15.0 .o 0) 1980 v c 12.5 LU o I 1978 10.0 1976 3 v 1 1974 0 7.5 O U I 1972 ' 5.0 1970 1968 2.5 ---- - -� 1966 0.0 20082010201220142016201820202022 Date 1,4-Dioxane 1990 1( 1988 1986 1984 1982 � .0 J 1980 v 1( w O 1978 1976 1974 0 U 0 O U 1972 10 1970 1968 1966 184 182 0 ra 180 v w 178 176 174 O 172 170 168 166 Date Constituent Key with 2L Standards f Tetrachloroethene (PCE) (0.70 µg/L) Trichloroethene (TCE) (3 µg/L) cis-1,2-Dichloroethene (70 µg/L) f Vinyl Chloride (0.03 µg/L) f Benzene (1 µg/L) f 1,4-Dichlorobenzene (6 µg/L) 1,4-Dioxane (3 µg/L) Groundwater Elevation (ft) -- Leachate Extraction Start Date 190 188 186 184 182 0 180 a'� 178 176 174 0 172 170 168 166 Figure 5 Hydrograph and Constituents of Concern Versus Time - MW-02 Spring 2022 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landifll 5 4 J �3 c 0 M c 2 c 0 U 1 H 14 12 10 c 0 8 M c (tj 6 c 0 U 4 2 0 Tetrachloroethene (PCE) I I I I 1 1 I i 1 I 1 I 1 1 1 1 1 - - ------ --------------------- 20082010201220142016201820202022 Date 2009 2007 2005 $ 2003 0 2001 a') w 1999 a5 1997 c 1995 0 6 1993 1991 1989 Trichloroethene (TCE) 6 I II I I 5 J 4 c 0 3 c v o 2 U 1141M1 44 Re• •o* �o 1 � t�t��l[�(� LU.0 2009 2007 17.5 2005 15.0 2003 0 .2 12.5 2001 > > 0) � w o 1999 a5 a 10.0 1997 � c c 7.5 1995 0 0 U �7 5.0 1993 1991 2.5 1989 0.0 20082010201220142016201820202022 20082010201220142016201820202022 Date Date Benzene 1,4-Dichlorobenzene Notes: 1. Dashed horizontal lines represent the 2L groundwater standard. 2. Dashed vertical lines represent the start of leachate extraction. 3. Non -detects are plotted as an open symbol at the method detection limit. 4. Data presented are from semiannual sampling events from 2007 to Spring 2022. µg/L: micrograms per liter ft:feet Publish Date: 06/01/2022 13:44 PM I User: SYR-SCOL File Path: \\athena\Asheville\Projects\Jackson County`Reports - Groundwater\python\JacksonCounty_GW_Evaluation.py kZANCHOR QEA 2009 2007 2005 $ 2003 0 M 2001 v w 1999 v 1997 c 1995 0 0 1993 1991 1989 40 35 30 25 c 0 20 c a� c 15 0 U 10 5 0 Cis- 1,2-Dichloroethene 20082010201220142016201820202022 Date 2009 20.0 2007 2005 , 17.5 2003 0 15.0 2001 > c 12.5 ' 1 I I 1999 10.0 1997 3: v 1 0 7.5 1995 0 U 5.0 1993 1 1991 2.5 1 -- --- -- I 1989 0.0 20082010201220142016201820202022 Date 1,4-Dioxane 2009 101 2007 2005 $ 2003 0 100 2001 > rZ w2 0 1999 a, P � 1997 c c 0 1995 0 U 10-1 1993 1991 1989 09 07 05 03 0 01 '0 v w 99 }, 97 c 95 0 0 0% 91 89 Vinyl Chloride I ----------------------. I 20082010201220142016201820202022 Date Constituent Key with 2L Standards f Tetrachloroethene (PCE) (0.70 µg/L) Trichloroethene (TCE) (3 µg/L) cis-1,2-Dichloroethene (70 µg/L) f Vinyl Chloride (0.03 µg/L) f Benzene (1 µg/L) f 1,4-Dichlorobenzene (6 µg/L) 1,4-Dioxane (3 µg/L) Groundwater Elevation (ft) -- Leachate Extraction Start Date 2009 2007 2005 $ 2003 0 2001 w 1999 1997 c 1995 0 1993 1991 1989 Figure 6 Hydrograph and Constituents of Concern Versus Time - MW-03 Spring 2022 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landifll 5 4 J �3 c O M c 2 c O U 1 a 14 12 10 c 0 8 M c 0 6 c 0 U 4 2 0 Tetrachloroethene (PCE) 20082010201220142016201820202022 Date 1989 1987 1985 0 a� 1983 w a� 3 1981 S O ti� 1979 1977 J 4 c O 3 c v o 2 U 1 0 I yjbj LU.0 17.5 1987 15.0 1985 0 .2 12.5 a>i 0) � 1983 10.0 3 Qj 1981 _0 c 0 7.5 O U �7 5.0 1979 2.5 1977 0.0 Trichloroethene (TCE) 20082010201220142016201820202022 Date 20082010201220142016201820202022 20082010201220142016201820202022 Date Date Benzene 1,4-Dichlorobenzene Notes: 1. Dashed horizontal lines represent the 2L groundwater standard. 2. Dashed vertical lines represent the start of leachate extraction. 3. Non -detects are plotted as an open symbol at the method detection limit. 4. Data presented are from semiannual sampling events from 2007 to Spring 2022. µg/L: micrograms per liter ft:feet Publish Date: 06/01/2022 13:44 PM I User: SYR-SCOL File Path: \\athena\Asheville\Projects\Jackson County`Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py kZANCHOR QEA Cis- 1,2-Dichloroethene 1989 1987 1985 0 v 1983 w v 3 1981 O A, 1979 1977 40 35 30 25 c 0 20 c c 15 0 U 10 5 0 20082010201220142016201820202022 Date .;. 20.0 1987 17.5 1985 0 15.0 v c 12.5 LU 0 1983 10.0 3 v 1981 0 7.5 O 5.0 1979 2.5 1977 0.0 20082010201220142016201820202022 Date 1,4-Dioxane 1989 1 1987 1985 0 w O 1983 0 1981 S rZ rZ 0 O 1C 1979 1977 87 85 c O 83 w 79 Date Constituent Key with 2L Standards f Tetrachloroethene (PCE) (0.70 µg/L) Trichloroethene (TCE) (3 µg/L) cis-1,2-Dichloroethene (70 µg/L) f Vinyl Chloride (0.03 µg/L) f Benzene (1 µg/L) f 1,4-Dichlorobenzene (6 µg/L) 1,4-Dioxane (3 µg/L) Groundwater Elevation (ft) -- Leachate Extraction Start Date 89 87 85 0 a� 83 w a� 81 ZS O 79 77 Figure 8 Hydrograph and Constituents of Concern Versus Time - MW-05R Spring 2022 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landifll 5 4 J �3 c O M 0 14 12 10 c O 8 M c (tj 6 c O U 4 2 0 Tetrachloroethene (PCE) 1958 6 5 1956 $ o 4 a>i � 1954LU 3 � 3 c v 0 U O 2 O U 1952 1 1950 0 Trichloroethene (TCE) 20082010201220142016201820202022 20082010201220142016201820202022 Date Date 1958 20.0 17.5 1956_ 15.0 � o J \ 0) 12.5 a>i � 1954 — 10.0 � c U 7.5 O o U 1952 5.0 2.5 1950 0.0 20082010201220142016201820202022 20082010201220142016201820202022 Date Date Benzene 1,4-Dichlorobenzene Notes: 1. Dashed horizontal lines represent the 2L groundwater standard. 2. Dashed vertical lines represent the start of leachate extraction. 3. Non -detects are plotted as an open symbol at the method detection limit. 4. Data presented are from semiannual sampling events from 2007 to Spring 2022. µg/L: micrograms per liter ft:feet Publish Date: 06/01/2022 13:44 PM I User: SYR-SCOL File Path: \\athena\Asheville\Projects\Jackson County`Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py kZANCHOR QEA Cis- 1,2-Dichloroethene 1958 40 35 1956 $_ 30 c O 25 (U 1954 20 � c c O 15 O U 1952 10 5 1950 0 20082010201220142016201820202022 Date 1958 20.0 17.5 1956 0 15.0 0) v 0 12.5 1954 v .� c 10.0 3 v 0 7.5 0 O U 1952 0 5.0 2.5 1950 0.0 2008201020122014201620182020202; Date 1,4-Dioxane 1958 101 1956 $_ c O � > 100 v � 1954 � 3 c U � C U 0 O 1952 6 U 10-1 1950 f: c O �2 0 6 Vinyl Chloride ------------ ' ----------------- 20082010201220142016201820202022 Date Constituent Key with 2L Standards f Tetrachloroethene (PCE) (0.70 µg/L) Trichloroethene (TCE) (3 µg/L) cis-1,2-Dichloroethene (70 µg/L) f Vinyl Chloride (0.03 µg/L) f Benzene (1 µg/L) f 1,4-Dichlorobenzene (6 µg/L) 1,4-Dioxane (3 µg/L) Groundwater Elevation (ft) -- Leachate Extraction Start Date 1958 1956_ c O a� 1954 3 C Z) O 1952 6 1950 Figure 7 Hydrograph and Constituents of Concern Versus Time - MW-04 Spring 2022 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landifll 5 4 >s �3 c O M c 2 c O U 1 0 14 12 10 c 0 8 c 6 c 0 U 4 2 0 20082010201220142016201820202022 Date Benzene Tetrachloroethene (PCE) -- - ------- ----------------- 20082010201220142016201820202022 Date Notes: 1. Dashed horizontal lines represent the 2L groundwater standard. 2. Dashed vertical lines represent the start of leachate extraction. 3. Non -detects are plotted as an open symbol at the method detection limit. 4. Data presented are from semiannual sampling events from 2007 to Spring 2022. µg/L: micrograms per liter ft:feet 2066 6 Trichloroethene (TCE) 2066 40 cis- 1,2-Dichloroethene 2066 101 2064 2064 2064 35 2062 5 2062 2062 2060 $ 2060 $ 30 2060 $ o 4 0 25 o 2058 2058 2058 0 10 o a'� v i v 2056 "' .° m 3 ------ -- ---T --- -- - ---- - ______. 2056 "' 0 20 2056 "' 2054 3 v 2054 3 2054 _0 c 0 2 ' c 0 15 ' c 2052 o U 2052 o U 2052 U 0 2050 2050 10 2050 10-1 1 2048 2048 5 2048 2046 �p 2046 2046 0 0 20082010201220142016201820202022 20082010201220142016201820202022 Date Date DO LU.0 i 64 17.5 ' 52 15.0 60 58 a 12.5 1 i w 56 o10.0 c 54 c 7.5 52 o v 50 5.0 48 2.5 46 0.0 20082010201220142016201820202022 Date 1,4-Dichlorobenzene Publish Date: 06/01/2022 13:44 PM I User: SYR-SCOL File Path: \\athena\Asheville\Projects\Jackson County`Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py kZANCHOR QEA 2066 2064 20.0 2062 17.5 ' 2060 0 15.0 2058 E v c 12.5 2056 Lu 10.0 2054 'u � 2052 0 v 0 7.5 2050 5.0 2048-------- 2.5 --- 2046 0.0 20082010201220142016201820202022 Date 1,4-Dioxane 64 62 60 58 56 54 52 O 50 48 46 Vinyl Chloride ' m ----- ----------------- ------- ----- 20082010201220142016201820202022 Date Constituent Key with 2L Standards f Tetrachloroethene (PCE) (0.70 µg/L) Trichloroethene (TCE) (3 µg/L) cis-1,2-Dichloroethene (70 µg/L) f Vinyl Chloride (0.03 µg/L) f Benzene (1 µg/L) f 1,4-Dichlorobenzene (6 µg/L) 1,4-Dioxane (3 µg/L) Groundwater Elevation (ft) -- Leachate Extraction Start Date 2066 2064 2062 2060 0 2058 a� 2056 "' a� 2054 3 2052 0 2050 2048 2046 Figure 9 Hydrograph and Constituents of Concern Versus Time - MW-06 Spring 2022 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landifll 5 4 J �3 c O M c 2 c O U 1 0 14 12 10 c O 8 M c (tj 6 c O U 4 2 0 Tetrachloroethene (PCE) i i -------- - - i------- - ----- - ---- 1954 6 5 1952 0 4 a>i � w O 3 3 qj v 1950 � rZ 2 0 1 1948 0 Trichloroethene (TCE) 20082010201220142016201820202022 20082010201220142016201820202022 Date Date 1954 20.0 17.5 15.0 1952 0 .2 12.5 a>i 0) � 10.0 3 0 1950 u 0 7.5 O U �7 5.0 2.5 1948 0.0 Cis- 1,2-Dichloroethene 1954 40 35 $ 30 1952 0 .Z_ 25 w O v � 20 3 1950 0 15 O U C7 10 5 1948 0 20082010201220142016201820202022 Date 1954 20.0 17.5 1952 0 15.0 v c 12.5 w .0 v � 10.0 3 v 1950 � u 0 7.5 O U 5.0 2.5 1948 0.0 20082010201220142016201820202022 20082010201220142016201820202022 20082010201220142016201820202022 Date Date Date Benzene 1,4-Dichlorobenzene 1,4-Dioxane Notes: 1. Dashed horizontal lines represent the 2L groundwater standard. 2. Dashed vertical lines represent the start of leachate extraction. 3. Non -detects are plotted as an open symbol at the method detection limit. 4. Data presented are from semiannual sampling events from 2007 to Spring 2022. µg/L: micrograms per liter ft:feet Publish Date: 06/01/2022 13:44 PM I User: SYR-SCOL File Path: \\athena\Asheville\Projects\Jackson County`Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py ANCHOR QEA 1954 101 1952 0 > 100 v w rZ O 3 0 1950 � u 0 0 O U 6 10-1 1948 1952 c O Y 1948 Vinyl Chloride 20082010201220142016201820202022 Date Constituent Key with 2L Standards f Tetrachloroethene (PCE) (0.70 µg/L) Trichloroethene (TCE) (3 µg/L) cis-1,2-Dichloroethene (70 µg/L) f Vinyl Chloride (0.03 µg/L) f Benzene (1 µg/L) f 1,4-Dichlorobenzene (6 µg/L) 1,4-Dioxane (3 µg/L) Groundwater Elevation (ft) -- Leachate Extraction Start Date 1954 F_ 1952 0 1948 a� w Me Figure 10 Hydrograph and Constituents of Concern Versus Time - MW-07 Spring 2022 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landifll