9202_Wake_EastWake_MSWLF_March22GW_FID1678529_20220524

East Wake Landfill
Facility Permit No. 9202-
MSWLF-1981
Semi -Annual Sampling Report
(March 2022 Sampling Event)
Wake County
Report
Prepared May 2022
WAKE
COUNTY
NORTH CAROLI NA

LpF14RUSEONLY 1 OPaper Repon i]Eleclm is Date -Emil CD(data loaded:Yes/ No) DOGEvert#.
' P1C DENR -- Environmental Monitoring
Division of Waste Management -Solid Waste Reporting Form
Nobcs: This form and ay nudomafion attached to It are •Public Records" m defined in NC General Stabile 132-1. As such, Ruse commends am
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instruction:
• Prepare one form for each individually monitored unit.
• Please type or print legibly.
ARach a notification table with values mat attain or exceed NC 2L groundwater Standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each "We. (e.g. naNmlhy Occurring, off -she source, pm-exisgng
condition, etc.).
Attach a notification table of any groundwater or surface watervalues that equal or exceed the reporting limits.
• Attach a notificatim table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
• Send the original signed and sealed Warn, any tables, and Electronic Data Deliverable m: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility Owner)
Consultant - CDM Smith Inc.
Contact for questions about data Forwarding. Include data preparees name, telephone number and E-mail address:
Name: Mathew F. Colons Pion: (919) 325a500
E-mail: colma minfi cdmsmith.com
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility permit At (.050) or.46n01 Orimer 20-24. 20nfu
East Wake Landfill - Rigsbee
Three Sisters Road
9202-MSWLF-L717771
Property
Knghtdale, North Carolina 27545
1981
Environmental Staters: (Check all that apply)
InitorRackgrourd Monitoring �x Detection Monitoring Assessment Mmhonng Corrective Action
Tyyyof data submitted: (Check all that apply)
X Groundwater monitoring data from monitoring wells Methane gas monitoring data
IIII--yell Groundwater monitoring data from private water supply wells Corrective action data (specify)
Leachate monitoring data
Surface water monitoring data ❑ Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
mrlitonrlg points, dates, analytical values. INC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
my R axerna ge, me Inromranen repone0 ano samema m meant On MIS data SOOrnitral and attachments am true and cormat.
Furthenrwre, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and signficance of concentrations exceeding groundwater standards. 1 am aware that there
are significant penalties for making any false slalenwM, representation, or certiffication including the possibility of a fine and imprisonment.
sig,owas
5400 Glenwood Avenue Suite 400 Raleigh North Carolina 27612
Facility Representative Address
Date
IC.
Seal
F-N12
INC PE Firm License Number (ff applicable effective May 1, 2009)
Revised 612009

Smith
5400 Glenwood Avenue, Suite 400
Raleigh, North Carolina 27612
tel: [phone]
fax: [phone]
May 24, 2022
Ms. Jaclynne Drummond
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
2090 U.S. 70 Highway
Swannanoa, North Carolina 28778
Subject: March 2022 (Spring) Semi -Annual Groundwater Sampling Report
East Wake Landfill - Rigsbee Property
Facility Permit No. 9202-MSWLF-1981
Dear Ms. Drummond:
CDM Smith Inc. (CDM Smith), on behalf of Wake County (County), is submitting an electronic copy of
the March 2022 semi-annual sampling event report for the East Wake Landfill - Rigsbee Property
(Site). This letter report presents the results of the most recent semi-annual sampling event and
constitutes the first semi-annual sampling event for 2022. The approved groundwater monitoring
network consists of one background well (i.e., MW-01), and five downgradient monitoring wells (i.e.,
MW-02, -03, -04S, -04D, and -07). Field activities and sampling results are discussed below.
Background
The Site is located on two parcels. One of the parcels as shown on Figure 1 is owned by Carolyn
Properties, LLC and contains approximately 27 acres of waste. This parcel is referred to as the J.T.
Knott property and is currently part of the North Carolina Department of Environmental Quality's
Special Remediation Branch's Pre -Regulatory Landfill program. The background monitoring well for
the portion of the landfill located on the James Ervin Rigsbee (Rigsbee) property, MW-01, is located on
this parcel along with a private airport and several businesses.
The parcel owned by Mr. Rigsbee contains approximately 46 acres of waste located in two separate
areas as shown on Figure 1. This parcel borders the J.T. Knott property to the south and west. A large
portion of the parcel is used for cattle pasture and includes an explosive storage company and
associated storage and office trailers, a home with a detached garage and two barns, and a storage
area for abandoned automobiles. All monitoring wells for the Site, except for the background well, are
located on this parcel. This portion of the Site operated under Permit Number 92-02 until the two
waste disposal areas ceased operations in 1983 (Area C) and 1985 (Area D).
The two areas of waste located on the Rigsbee property are known as Areas C and D as shown on
Figure 1. Groundwater assessment for Area C is being conducted under the supervision of the Special
tD
WATER + ENVIRONMENT +TRANSPORTATION + ENERGY + FACILITIES

Smith
Ms. Jaclynne Drummond
May 24, 2022
Page 2
Remediation Branch's Pre -Regulatory Landfill Unit after this area of waste was determined to be
eligible for the program in the fall of 2012.
Beginning in 2012, the County voluntarily collected groundwater samples semi-annually from the Area
C monitoring wells (i.e., MW-5, -6, -8, -9, and -10). On September 13, 2018, the Solid Waste Section
(SWS) approved the discontinuation of the groundwater monitoring of Area C, beginning with the fall
2018 sampling event.
On May 3, 2022, the SWS approved the removal of MW-2 and -7 from the groundwater monitoring
network. Additionally, the sample frequency for the remaining monitoring wells was reduced from
semi-annually to annually. Samples will be collected from MW-1, -3, -4S and -41) during the spring. A
copy of the approval letter from the SWS is provided in Appendix A.
Field Activities
Groundwater samples were collected on March 21-22, 2022, by use of disposable, laboratory
decontaminated bailers. Monitoring well sampling locations are presented on Figure 1. Well
construction details are provided in Table 1.
Groundwater elevations were measured at each well on March 21, 2022, prior to sampling and are
presented in Table 2. These groundwater elevations were used to construct potentiometric contours
for this sampling event and are presented on Figure 1. The groundwater elevations and
potentiometric contours were used to estimate the groundwater velocity at each well. Groundwater
velocity values are provided in Table 3.
After depth to groundwater was determined, three well volumes of water were removed from each
well prior to sampling to provide fresh formation water within the well water column. Each well
volume was measured for pH, conductivity, temperature, turbidity, dissolved oxygen, and
oxidation-reduction potential using a YSI-556 multi -parameter water quality meter and a HANNA HI
98703 turbidity meter. Wells with elevated turbidity (i.e., greater than 10 Nephelometric Turbidity
Units (NTUs)) were allowed to stabilize prior to sample collection. The water quality parameters at the
time of sampling are presented in Table 2.
Alternate Source Demonstration
On August 17, 2020, CDM Smith submitted an Alternate Source Demonstration (ASD) for the Site on
behalf of the County. The purpose of the ASD was to demonstrate that metals exceeding the 15A
NCAC 02L .0202 (NC 2L) Groundwater Standards or Interim Maximum Allowable Concentrations
(IMACs) are naturally occurring and not related to a release from the landfill. The ASD was prepared
using analytical data from the background monitoring well, MW-01, that was collected on a quarterly
basis from January 2018 to February 2020 to develop upper tolerance limits (UTLs) for specific
analytes that historically exceeded their respective NC 2L Groundwater Standard or IMAC. Based on
tD

Smith
Ms. Jaclynne Drummond
May 24, 2022
Page 3
statistical analysis, a UTL of 2.82 parts per billion (ppb) was proposed for cobalt and a UTL of 2 ppb
was proposed for vanadium. The SWS approved these proposed UTLs on August 20, 2020.
On April 1, 2022, the SWS updated the NC 2L Groundwater Standards and IMACs. The updated NC 2L
Groundwater Standard for vanadium is 7 ppb, which is greater than the UTL. The NC 2L Groundwater
Standard for vanadium will be used instead of the UTL.
Sampling Results
Pace Analytical Services, LLC, located in West Columbia, South Carolina, analyzed the groundwater
samples for the North Carolina Appendix I volatile organic compounds and Appendix I metals. In a
letter dated May 29, 2018, the SWS stated that all groundwater and surface water samples collected
from landfills be analyzed for 1,4-dioxane after July 1, 2018. On June 26, 2019, the SWS approved the
removal of 1,4-dioxane from the sampling program for all monitoring wells, with the exceptions of
MW-03, -04S, and -4D, due to two consecutive non -detect events (October 2018 and April 2019).
Samples were collected from the wells requiring the 1,4-dioxane analysis during the March 2022 semi-
annual sampling event. Sample results are provided below.
The analytical results were reported to the laboratory specific method detection limit (MDL) and are
quantifiable at or below the laboratory limit of quantitation (LOQ). All monitoring wells for the Site
had detections of analytes above the MDL but below the LOQ that were qualified as estimated or "J"
flags.
The following list indicates the analytes detected above the LOQ at each sampling location. There
were no "J" flag detections above the standards. Underlined analytes exceeded the NC 2L
Groundwater Standard or UTL. A complete summary of all detected and estimated concentrations for
the March 2022 sampling event is provided in Table 4. The laboratory analytical data report is
provided in Appendix B.
MW-01 (Background)
Metals:
Volatile Organic Compounds
AREA D
MW-02
Metals:
Volatile Organic Compounds
MW-03
Metals:
Barium, Beryllium
None Detected
Barium, Copper, Lead, Zinc
None Detected
Barium
Volatile Organic Compounds: Chlorobenzene, 1,4-Dichlorobenzene, 1,4-Dioxane
0

Smith
Ms. Jaclynne Drummond
May 24, 2022
Page 4
MW-04S
Metals:
Volatile Organic Compounds
MW-04D
Metals:
Volatile Organic Compounds
Barium, Cobalt, Copper, Nickel
Benzene, Chlorobenzene, 1,4-Dichlorobenzene, 1,4-Dioxane
Barium, Cobalt, Nickel
Chlorobenzene, 1,4-Dichlorobenzene, 1,4-Dioxane
MW-07
Metals: Barium, Beryllium, Cadmium, Zinc
Volatile Organic Compounds: None Detected
An equipment blank, trip blank, and duplicate sample were analyzed for quality control. Copper and 2-
butanone were detected as estimated concentrations in the equipment blank below their NC 2L
Groundwater Standards. Methylene chloride was detected in the trip blank below its NC 2L
Groundwater Standard. The duplicate sample, identified as DUP, was collected from MW-02 and had
similar analyte concentrations as those detected in MW-02. Table 5 presents a summary of all
parameters detected during the March 2022 sampling event that exceeded the NC 2L Groundwater
Standards or UTLs.
Additional metals samples were collected from MW-01, -03, -04S, and -04D during the March 2022
sampling event for the laboratory to filter and analyze due to elevated turbidity (i.e., greater than 10
NTUs). Total metals that exceeded the NC 2L Groundwater Standards or UTLs in MW-04S and -04D
were analyzed for dissolved metals to determine if turbidity was a contributing factor to total
reported metals.
Cobalt was detected in the dissolved metals samples collected from MW-04S and -04D above its UTL.
Barium was also detected in the dissolved metal sample collected from MW-04D above the NC 2L
Groundwater Standard. Based on qualitative and quantitative evaluation of current and historic
groundwater sampling data, the NC 2L Groundwater Standard and UTL metal exceedances from the
March 2022 sampling event were determined to be indicative of naturally occurring background
concentrations as opposed to a release from the landfill. Dissolved metal sample results are provided
in Table 4 and the laboratory report is provided in Appendix B.
The County will begin annual sampling of the updated groundwater monitoring network for Area D
(i.e., MW-1, -3, -045, and -04D). The concentration of 1,4-dioxane will continue to be monitored in
MW-03, -045, and -04D. The next sampling event will be completed in the spring of 2023.
0

Smith
Ms. Jaclynne Drummond
May 24, 2022
Page 5
If you have any questions or require further explanation, do not hesitate to call me at [phone].
Very truly yours,
Mathew F. Colone, P.G.
CDM Smith Inc.
cc: John Roberson, WCSWM
Elliott Cornell, WCSWM
0

Notes:
1. bgs - Below Ground Surface
2. AMSL - Above Mean Sea Level
3. TOC - Top of Casing
4. Latitude and longitude - World Geodetic System 1984
CDIII�
Smith
Table 1
Well Construction Summary
East Wake landfill - Area D
Permit Number 9202-MSWLF-1981
Page 1 of 1
May 2022

Table 2
Water Quality Parameters
March 2022 Semi -Annual Sampling Event
East Wake Landfill - Area D
Permit Number 9202-MSWLF-1981
Facility Permit
Number
Water Quality Parameters
Monitoring Well Code pH Conductivity Temperature Turbidity DO ORP
(S.U.) (PS/cm) (deg. C) (NTUs) (mg/L) (mVs)
Groundwater Elevations - Measured 3/21/2022
Depth to Groundwater
TOC Elevation
Groundwater Elevation
(feet AMSL) (feet bgs) (feet AMSL)
INWITIVIEWN, .
Notes:
1. Water levels and water quality measurements were collected on March 21-22, 2022.
2. AMSL - Above Mean Sea Level
3. TOC - Top of Casing
4. bgs - Below Ground Surface
5. µS/cm - Microsiemens per centimeter
6. mg/L - Milligrams per liter
7. ORP - Oxidation -Reduction Potential
8. NTUs - Nephelometric Turbidity Units
9. mvs - Millivolts
10. S.U. - Standard Units
11. DO - Dissolved Oxygen
12. Monitoring wells with high turbidity were allowed to settle prior to sampling; turbidity shown in table was recorded at the time of sampling.
Smith Page 1 of 1 May 2022

Table 3
Summary of Calculated Groundwater Flow Velocities
March 2022 Semi -Annual Sampling Event
East Wake Landfill - Area D
Permit Number 9202-MSWLF-1981
Facility Permit
Number
9202-MSWLF-1981
Monitoring
Well Code
MW-01
Hydraulic Conductivity
(feet/day)
0.4927
Gradient
0.0195
Effective
Porosity
0.3
Average Linear Velocity
(feet/day)
3.21E-02
9202-MSWLF-1981
MW-02
0.4927
0.0234
0.3
3.85E-02
9202-MSWLF-1981
MW-03
0.4927
0.0233
0.3
3.82E-02
9202-MSWLF-1981
MW-04S
0.4927
0.0191
0.3
3.13E-02
9202-MSWLF-1981
MW-04D
0.4927
0.0190
0.3
3.13E-02
9202-MSWLF-1981
MW-07
0.4927
0.0128
0.3
2.10E-02
Notes:
1. Hydraulic conductivity and porosity are values from HDR's 2014 Fall Semi -Annual Report.
2. Hydraulic gradient was calculated using MW-1.
Smith Page 1 of 1 May 2022

Table 4
Detected Groundwater Constituents
March 2022 Semi -Annual Sampling Event
East Wake Landfill - Area D
Permit Number 9202-MSWLF-1981
Monitoring.
Parameter
Code
Result Qualifier
or UTL
Barium
120 700 1.3 µg/L
MW-01 Beryllium
0.54 4 0.15 µg/L
Zinc
7.1 J 1,000 2.5 µg/L
Barium
34
700
1.3
µg/L
Beryllium
0.37
J
4
0.15
µg/L
Chromium
2.2
J
10
1.3
µg/L
Copper
5.2
1,000
1.3
µg/L
MW-02
Lead
9.6
15
0.25
µg/L
Nickel
1.3
J
100
1.3
µg/L
Vanadium
3.1
J
7
2.5
µg/L
Zinc
27
1,000
2.5
µg/L
Barium
33
700
1.3
µg/L
Beryllium
0.31
J
4
0.15
µg/L
Chromium
2.2
J
10
1.3
µg/L
MW-02 (dup)
Copper
4.4
J
1,000
1.3
µg/L
Lead
7.0
15
0.25
µg/L
Nickel
1.4
J
100
1.3
µg/L
Vanadium
2.5
J
7
2.5
µg/L
Zinc
24
1,000
2.5
µg/L
Barium
400
700
1.3
µg/L
Copper
2.0
J
1,000
1.3
µg/L
Lead
0.96
J
15
0.25
µg/L
Nickel
3.3
J
100
1.3
µg/L
MW-03
Zinc
3.4
J
1,000
2.5
µg/L
Chlorobenzene
3.8
50
0.40
µg/L
1,4-Dichlorobenzene
0.68
6
0.40
µg/L
1,4-Dioxane
15
3
1.0
µg/L
Barium
850
700
6.3
µg/L
Barium (dissolved)
700
1.3
µg/L
Cobalt
25
2.82*
1.3
µg/L
Cobalt (dissolved)
22
2.82*
1.3
µg/L
Copper
8.9
1,000
1.3
µg/L
Lead
0.45
J
15
0.25
µg/L
MW-04S
Nickel
13
100
1.3
µg/L
Zinc
6.4
J
1,000
2.5
µg/L
Benzene
0.85
1
0.40
µg/L
Chlorobenzene
6.9
50
0.40
µg/L
1,4-Dichlorobenzene
1.7
6
0.40
µg/L
1,4-Dioxane
40
3
1.0
µg/L
C DM Page 1 of 2 May 2022
Smith

Table 4
Detected Groundwater Constituents
March 2022 Semi -Annual Sampling Event
East Wake Landfill - Area D
Permit Number 9202-MSWLF-1981
Notes•
1. All units are in micrograms per liter (parts per billion, µg/L).
2. Samples were collected on March 21-22, 2022.
4. * - The Upper Tolerance Limits (UTL) were calculated as part of the East Wake Alternate Source Demonstration
and were approved by the Solid Waste Section on August 20, 2020.
4. MDL- Method Detection Limit
5. dup - Duplicate Sample
6. J - Indicates the analytical result is an estimated concentration between the method detection limit and the limit
of quantitation.
7. Dissolved metals samples were collected to evaluate the influence of turbidity on total metal concentrations.
8. (-) Indicates the result is below the detection limit.
Concentration exceeds the 15A NCAC 02L .0202 (North Carolina 2L) or UTL.
C DM Page 2 of 2 May 2022
Smith

Table 5
Constituents Detected Above Standards
March 2022 Semi -Annual Sampling Event
East Wake Landfill - Area D
Permit Number 9202-MSWLF-1981
UpperFacility Permit Monitoring Well Code March 2022 Constituents Exceeding the
Number I I North Carolina 2L or
9202-MSWLF-1981 MW-01 None
9202-MSWLF-1981
MW-02
None
9202-MSWLF-1981
MW-03
1,4-Dioxane
9202-MSWLF-1981
MW-04S
Barium, Cobalt*, 1,4-Dioxane
9202-MSWLF-1981
MW-04D
Barium, Cobalt*, 1,4-Dioxane
9202-MSWLF-1981
MW-07
Cadmium
Notes:
1. * - The Upper Tolerance Limits were calculated as part of the East Wake Alternate Source Demonstration approved by
the Solid Waste Section on August 20, 2020.
CDNI
Smith Page 1 of 1 May 2022

a 1 Yi-.PC V
\
MW-02,
243.14 c
\
O\
MW-03
231.32 ,
N \
o � ,
1 Area D
\
MW-04S
229.34 L'
MW-04D
229.43
i
Notes'
1. Groundwater elevations were measured on
2. Potentiometric contours are derived from p
and adjusted based on the recent ground,
Map Data Source: February 2021 Aerial Photo
I OV /
Carolyn Properties, LLC
t (J.T. Knott Propertyl
\ MW-07
247.56
N I !Cq,
Plty:
Eatranee
Area C U` I LEGEND
,tJ� Groundwater Monitoring Well
Yrwmmwm� ,*Y 243.52 Groundwater Elevation
R' Potentiometric Contour
/ 240 — Contour Interval =10 feet
irch 21, 2022. (dashed where inferred)
s'a in mvestigetions _.._ Property Line
G she
ip County, North Carolina OneMap.

Appendix A
Solid Waste Section — Modification of Sampling Plan Approval Letter

ROY COOPER
Govemor
ELIZABETH S. BISER
Secretary
MICHAEL SCOTT
Director
NORTH CAROLINA
Fnyfronmental Quality
May 3, 2022
Sent Via Email ,=[e-mail]
Mr. John Roberson
Wake County Solid Waste Director
336 Fayetteville Street
Raleigh, NC 27602
Re: Modification of Sampling Plan
East Wake Closed and Unlined Landfill - Rigsbee Property
Area D
Wake County
Solid Waste Permit Number 9202-MSWLF-1981
1Ul1112009i1c311
Dear Mr. Roberson,
The Solid Waste Section (Section) has completed a review of the document titled Modification of
Sampling Plan dated April 19, 2022 (FID 1664861) and was submitted on your behalf by C D M Smith
forthe East Wake Closed and Unlined Landfill Area D, Solid Waste Permit Number 9202-MSWLF-1981.
The County is requesting to modify the water quality sampling plan by the following:
• Abandon groundwater monitoring wells MW-2 and MW-7. Based upon groundwater flow, both
groundwater monitoring wells d❑ not monitor Area D, MW-2 is dry, and there is a lack of
detections in both MW-2 and MW-7, and
• Reduce the frequency of monitoring groundwater monitoring wells MW-1, MW-3, MW-4S, and
MW-4D from semiannual to annual.
Based upon a review of the Modification of Sampling Plan, the Section approves the requests as
written at this time. After the wells have been abandoned, please submit well abandonment records
(GW-30 Form) in accordance with 15A NCAC 2C .0114. If you have any questions or concerns
regarding this response letter, please feel free to contact me by phone at 828.296.4500 or by email
at [e-mail].
Sincerely,
Jae.
n_ Digitally signed by
Ja,4mtie Drummond
❑ate:022.05.03D Umon
Jacynne 13:39:11-04'00'
Hydrogeologist
Solid Waste Section, Division of Waste Management
NCD£Q
cc sent via email: Elliott Cornell, Wake County
Perry Sugg, SW Environmental Compliance Branch Head
Jason Watkins, SW Field Operations Branch Head
M
� North Carolina Department of Environmental Quality I Division of Waste Management
EAsheville Regional office 1 2090 U.S. Highway 70 1 Swennanoa, North Carolina 28778
NQMT i:JJip.iNV
Do-01-as A+u.. 828.2996,4500

Drew Hammonds, SW Eastern District Supervisor
Sherri Stanley, SW Permitting Branch Head
Tim Davis, SW Environmental Senior Specialist
Diana Felix, SW Permitting Engineer
Mat Colone, CDM Smith
Kevin Kelt, NC Pre -Regulatory Landfill Unit
Qw"j North Carolina Department of Environmental Quality I Division of Waste Management
Asheville Regional office 1 2090 Ul5. Highway 70 1 Swannanoa, North Carolina 28778
it
u an .a inu�
=.' � 828.296A500

Appendix B
Laboratory Analytical Reports

aceAnalytical
Report of Analysis
CDM Smith
5400 Glenwood Avenue
Suite 400
Raleigh, NC 27612
Attention: Mathew Colone
Project Name: East Wake Landfill
Lot Number:XC24015
Date Completed:03/31/2022
04/08/2022 11:52 AM
Approved and released by:
Project Manager II: Cathy S. Dover
=w�q a[cArFo f�
/716
TN I
AM Nauvue Acm^r mn BuaN
11 �
eOfFAi�
A C C R E D I T E D
TESTINGL aORlTOAY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 46

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
CDM Smith
Lot Number: XC24015
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
1,4-dioxane SIM 8260D
The matrix spike and matrix spike duplicate (MS/MSD) were not reported in batch 36636 due to
instrument foam error. The associated samples for this batch are: XC24015-003 (MW-03), XC24015-004
(MW-04S), XC24015-005 (MW-04D), XC24015-008 (TRIP BLANK), and XC24015-009 (EQ BLANK). The
CCV and LCS associated with batch 36636 passed acceptance criteria, therefore the data has been
reported.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 2 of 46

PACE ANALYTICAL SERVICES, LLC
Sample Summary
CDM Smith
Lot Number: XC24015
Project Name: East Wake Landfill
Project Number:
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
MW-01
Aqueous
03/22/2022 0800
03/24/2022
002
MW-02
Aqueous
03/21/20221230
03/24/2022
003
MW-03
Aqueous
03/22/2022 0820
03/24/2022
004
MW-04S
Aqueous
03/22/2022 0845
03/24/2022
005
MW-04D
Aqueous
03/22/2022 0835
03/24/2022
006
MW-07
Aqueous
03/22/2022 0910
03/24/2022
007
DUP
Aqueous
03/21/2022 0800
03/24/2022
008
TRIP BLANK
Aqueous
03/21/2022
03/24/2022
009
EQ BLANK
Aqueous
03/21/2022 1500
03/24/2022
(9 samples)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 46

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:XC24015-001
Description: MW-01 Matrix: Aqueous
Date Sampled:03/22/2022 0800 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 03/28/20221544 BWS
36262
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 46

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:XC24015-001
Description: MW-01 Matrix: Aqueous
Date Sampled:03/22/2022 0800 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 03/28/20221544 BWS 36262
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
96 70-130
96 70-130
97 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 46

ICP-MS Metals
Client:CDM Smith Laboratory ID:XC24015-001
Description: MW-01 Matrix: Aqueous
Date Sampled:03/22/2022 0800 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 03/28/2022 1959 BPK
Prep Date Batch
03/28/2022 0111 36188
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
120
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.54
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0
U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
7.1
J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 46

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:XC24015-002
Description: MW-02 Matrix: Aqueous
Date Sampled:03/21/2022 1230 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 03/28/20221607 BWS
36262
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 46

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:XC24015-002
Description: MW-02 Matrix: Aqueous
Date Sampled:03/21/2022 1230 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 03/28/20221607 BWS 36262
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
101 70-130
99 70-130
98 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 46

ICP-MS Metals
Client:CDM Smith Laboratory ID:XC24015-002
Description: MW-02 Matrix: Aqueous
Date Sampled:03/21/2022 1230 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 03/28/2022 2003 BPK
Prep Date Batch
03/28/2022 0111 36188
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
34
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.37
J
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
2.2
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.2
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
9.6
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
1.3
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
3.1
J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
27
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 46

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:XC24015-003
Description: MW-03 Matrix: Aqueous
Date Sampled:03/22/2022 0820 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 03/28/20221629 BWS
36262
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
3.8
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.68
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 46

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:XC24015-003
Description: MW-03 Matrix: Aqueous
Date Sampled:03/22/2022 0820 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 03/28/20221629 BWS 36262
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
97 70-130
98 70-130
98 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 46

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:XC24015-003
Description: MW-03 Matrix: Aqueous
Date Sampled:03/22/2022 0820 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 03/30/2022 2359 SDC 36636
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 15 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
101 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 12 of 46

ICP-MS Metals
Client:CDM Smith Laboratory ID:XC24015-003
Description: MW-03 Matrix: Aqueous
Date Sampled:03/22/2022 0820 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 03/28/2022 2013 BPK
Prep Date Batch
03/28/2022 0111 36188
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
400
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
2.0
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.96
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
3.3
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
3.4
J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 13 of 46

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:XC24015-004
Description: MW-04S Matrix: Aqueous
Date Sampled:03/22/2022 0845 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 03/28/20221652 BWS
36262
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.85
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
6.9
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
1.7
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 14 of 46

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:XC24015-004
Description: MW-04S Matrix: Aqueous
Date Sampled:03/22/2022 0845 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 03/28/20221652 BWS 36262
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
105 70-130
100 70-130
100 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 15 of 46

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:XC24015-004
Description: MW-04S Matrix: Aqueous
Date Sampled:03/22/2022 0845 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 03/31/2022 0024 SDC 36636
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 40 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
99 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 16 of 46

ICP-MS Metals
Client:CDM Smith Laboratory ID:XC24015-004
Description: MW-04S Matrix: Aqueous
Date Sampled:03/22/2022 0845 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 03/28/2022 2016 BPK
Prep Date Batch
03/28/2022 0111 36188
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
850
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
25
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
8.9
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.45
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
13
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
6.4
J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 17 of 46

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:XC24015-005
Description: MW-04D Matrix: Aqueous
Date Sampled:03/22/2022 0835 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 03/28/20221716 BWS
36262
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
4.3
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
1.3
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 18 of 46

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:XC24015-005
Description: MW-04D Matrix: Aqueous
Date Sampled:03/22/2022 0835 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 03/28/20221716 BWS 36262
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
100 70-130
100 70-130
98 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 19 of 46

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:XC24015-005
Description: MW-04D Matrix: Aqueous
Date Sampled:03/22/2022 0835 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 03/31/2022 0048 SDC 36636
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 28 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
102 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 20 of 46

ICP-MS Metals
Client:CDM Smith Laboratory ID:XC24015-005
Description: MW-04D Matrix: Aqueous
Date Sampled:03/22/2022 0835 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 03/28/2022 2020 BPK
Prep Date Batch
03/28/2022 0111 36188
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
780
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
21
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
4.0
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.29
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
16
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
5.5
J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 21 of 46

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:XC24015-006
Description: MW-07 Matrix: Aqueous
Date Sampled:03/22/2022 0910 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 03/28/20221739 BWS
36262
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 22 of 46

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:XC24015-006
Description: MW-07 Matrix: Aqueous
Date Sampled:03/22/2022 0910 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 03/28/20221739 BWS 36262
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
102 70-130
100 70-130
99 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 23 of 46

ICP-MS Metals
Client:CDM Smith Laboratory ID:XC24015-006
Description: MW-07 Matrix: Aqueous
Date Sampled:03/22/2022 0910 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 03/28/2022 2023 BPK
Prep Date Batch
03/28/2022 0111 36188
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
74
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.69
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
2.2
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
1.5
J
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.26
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0
U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
52
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 24 of 46

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:XC24015-007
Description: DUP Matrix: Aqueous
Date Sampled:03/21/2022 0800 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 03/28/20221802 BWS
36262
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 25 of 46

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:XC24015-007
Description: DUP Matrix: Aqueous
Date Sampled:03/21/2022 0800 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 03/28/20221802 BWS 36262
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
95 70-130
98 70-130
100 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 26 of 46

ICP-MS Metals
Client:CDM Smith Laboratory ID:XC24015-007
Description: DUP Matrix: Aqueous
Date Sampled:03/21/2022 0800 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 03/28/2022 2027 BPK
Prep Date Batch
03/28/2022 0111 36188
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
33
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.31
J
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
2.2
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
4.4
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
7.0
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
1.4
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
2.5
J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
24
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 27 of 46

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:XC24015-008
Description: TRIP BLANK Matrix: Aqueous
Date Sampled:03/21/2022 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 03/28/20221238 BWS
36262
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.84
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 28 of 46

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:XC24015-008
Description: TRIP BLANK Matrix: Aqueous
Date Sampled:03/21/2022 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 03/28/20221238 BWS 36262
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
98 70-130
97 70-130
98 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 29 of 46

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:XC24015-008
Description: TRIP BLANK Matrix: Aqueous
Date Sampled:03/21/2022 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 03/31/2022 0112 SDC 36636
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
99 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 30 of 46

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:XC24015-009
Description: EQ BLANK Matrix: Aqueous
Date Sampled:03/21/2022 1500 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 03/28/20221301 BWS
36262
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
4.2
J
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 31 of 46

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:XC24015-009
Description: EQ BLANK Matrix: Aqueous
Date Sampled:03/21/2022 1500 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 03/28/20221301 BWS 36262
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
101 70-130
98 70-130
98 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 32 of 46

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:XC24015-009
Description: EQ BLANK Matrix: Aqueous
Date Sampled:03/21/2022 1500 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 03/31/2022 0136 SDC 36636
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
102 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 33 of 46

ICP-MS Metals
Client:CDM Smith Laboratory ID:XC24015-009
Description: EQ BLANK Matrix: Aqueous
Date Sampled:03/21/2022 1500 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 03/28/2022 2030 BPK
Prep Date Batch
03/28/2022 0111 36188
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
5.0
U
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
1.3
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0
U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10
U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 34 of 46

QC Summary
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: XC24015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 35 of 46

Volatile Organic Compounds by GC/MS - MB
Sample ID: XQ36262-001 Matrix: Aqueous
Batch: 36262 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
10
U
1
10
4.0
ug/L
03/28/2022 1009
Acrylonitrile
5.0
U
1
5.0
0.80
ug/L
03/28/2022 1009
Benzene
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
Bromochloromethane
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
Bromodichloromethane
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
Bromoform
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
Bromomethane (Methyl bromide)
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
2-Butanone (MEK)
10
U
1
10
2.0
ug/L
03/28/2022 1009
Carbon disulfide
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
Carbon tetrachloride
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
Chlorobenzene
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
Chloroethane
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
Chloroform
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
Chloromethane (Methyl chloride)
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
1,2-Dibromo-3-chloropropane (DBCP)
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
Dibromochloromethane
0.50
u
1
0.50
0.40
ug/L
03/28/2022 1009
1,2-Dibromoethane (EDB)
0.50
u
1
0.50
0.40
ug/L
03/28/2022 1009
Dibromomethane (Methylene bromide)
0.50
u
1
0.50
0.40
ug/L
03/28/2022 1009
trans- 1,4-Dichloro-2-butene
2.0
u
1
2.0
0.40
ug/L
03/28/2022 1009
1,2-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
03/28/2022 1009
1,4-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
03/28/2022 1009
1,1-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
03/28/2022 1009
1,2-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
03/28/2022 1009
1,1-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
cis- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
trans- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
1,2-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
1,3-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
cis- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
trans- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
Ethylbenzene
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
2-Hexanone
10
U
1
10
2.0
ug/L
03/28/2022 1009
Methyl iodide (lodomethane)
5.0
U
1
5.0
0.40
ug/L
03/28/2022 1009
4-Methyl-2-pentanone
10
U
1
10
2.0
ug/L
03/28/2022 1009
Methylene chloride
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
Styrene
0.50
U
1
0.50
0.41
ug/L
03/28/2022 1009
1,1,1,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
1,1,2,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
Tetrachloroethene
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
Toluene
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
1,1,1-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
1,1,2-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
Trichloroethene
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
Trichlorofluoromethane
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 36 of 46
QC Data for Lot Number: XC24015

Volatile Organic Compounds by GC/MS - MB
Sample ID: XQ36262-001 Matrix: Aqueous
Batch:36262 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
1,2,3-Trichloropropane
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
1,2,4-Trimethylbenzene
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
1,3,5-Trimethylbenzene
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
Vinyl acetate
5.0
U
1
5.0
1.2
ug/L
03/28/2022 1009
Vinyl chloride
0.50
U
1
0.50
0.40
ug/L
03/28/2022 1009
Xylenes (total)
1.0
U
1
1.0
0.40
ug/L
03/28/2022 1009
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 99 70-130
1,2-Dichloroethane-d4 97 70-130
Toluene-d8 97 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: XC24015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 37 of 46

Volatile Organic Compounds by GC/MS - LCS
Sample ID: XQ36262-002
Matrix: Aqueous
Batch: 36262
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
100
110
1
109
60-140
03/28/2022 0922
Acrylonitrile
100
98
1
98
70-130
03/28/2022 0922
Benzene
50
49
1
98
70-130
03/28/2022 0922
Bromochloromethane
50
46
1
93
70-130
03/28/2022 0922
Bromodichloromethane
50
50
1
100
70-130
03/28/2022 0922
Bromoform
50
45
1
90
70-130
03/28/2022 0922
Bromomethane (Methyl bromide)
50
47
1
93
70-130
03/28/2022 0922
2-Butanone (MEK)
100
100
1
104
70-130
03/28/2022 0922
Carbon disulfide
50
52
1
104
70-130
03/28/2022 0922
Carbon tetrachloride
50
49
1
97
70-130
03/28/2022 0922
Chlorobenzene
50
48
1
95
70-130
03/28/2022 0922
Chloroethane
50
47
1
94
70-130
03/28/2022 0922
Chloroform
50
47
1
94
70-130
03/28/2022 0922
Chloromethane (Methyl chloride)
50
52
1
105
60-140
03/28/2022 0922
1,2-Dibromo-3-chloropropane (DBCP)
50
55
1
110
70-130
03/28/2022 0922
Dibromochloromethane
50
53
1
106
70-130
03/28/2022 0922
1,2-Dibromoethane (EDB)
50
52
1
104
70-130
03/28/2022 0922
Dibromomethane (Methylene bromide)
50
49
1
98
70-130
03/28/2022 0922
trans- 1,4-Dichloro-2-butene
50
49
1
97
70-130
03/28/2022 0922
1,2-Dichlorobenzene
50
52
1
104
70-130
03/28/2022 0922
1,4-Dichlorobenzene
50
52
1
104
70-130
03/28/2022 0922
1,1-Dichloroethane
50
48
1
97
70-130
03/28/2022 0922
1,2-Dichloroethane
50
48
1
96
70-130
03/28/2022 0922
1,1-Dichloroethene
50
50
1
101
70-130
03/28/2022 0922
cis- 1,2-Dichloroethene
50
46
1
92
70-130
03/28/2022 0922
trans- 1,2-Dichloroethene
50
48
1
96
70-130
03/28/2022 0922
1,2-Dichloropropane
50
48
1
97
70-130
03/28/2022 0922
1,3-Dichloropropane
50
50
1
100
70-130
03/28/2022 0922
cis- 1,3-Dichloropropene
50
52
1
105
70-130
03/28/2022 0922
trans- 1,3-Dichloropropene
50
55
1
109
70-130
03/28/2022 0922
Ethylbenzene
50
49
1
97
70-130
03/28/2022 0922
2-Hexanone
100
110
1
107
70-130
03/28/2022 0922
Methyl iodide (lodomethane)
50
47
1
94
70-130
03/28/2022 0922
4-Methyl-2-pentanone
100
100
1
104
70-130
03/28/2022 0922
Methylene chloride
50
45
1
90
70-130
03/28/2022 0922
Styrene
50
53
1
106
70-130
03/28/2022 0922
1,1,1,2-Tetrachloroethane
50
53
1
106
70-130
03/28/2022 0922
1,1,2,2-Tetrachloroethane
50
54
1
108
70-130
03/28/2022 0922
Tetrachloroethene
50
48
1
96
70-130
03/28/2022 0922
Toluene
50
50
1
100
70-130
03/28/2022 0922
1,1,1-Trichloroethane
50
48
1
96
70-130
03/28/2022 0922
1,1,2-Trichloroethane
50
51
1
101
70-130
03/28/2022 0922
Trichloroethene
50
47
1
95
70-130
03/28/2022 0922
Trichlorofluoromethane
50
47
1
94
70-130
03/28/2022 0922
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 38 of 46
QC Data for Lot Number: XC24015

Volatile Organic Compounds by GC/MS - LCS
Sample ID: XQ36262-002
Matrix: Aqueous
Batch:36262
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil
% Rec
Limit
Analysis Date
1,2,3-Trichloropropane
50
52
1
105
70-130
03/28/2022 0922
1,2,4-Trimethylbenzene
50
53
1
106
70-130
03/28/2022 0922
1,3,5-Trimethylbenzene
50
52
1
105
70-130
03/28/2022 0922
Vinyl acetate
50
45
1
90
60-140
03/28/2022 0922
Vinyl chloride
50
51
1
102
70-130
03/28/2022 0922
Xylenes (total)
100
100
1
100
70-130
03/28/2022 0922
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 105 70-130
1,2-Dichloroethane-d4 93 70-130
Toluene-d8 96 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: XC24015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 39 of 46

Volatile Organic Compounds by GC/MS (SIM) - MB
Sample ID: XQ36636-001 Matrix: Aqueous
Batch:36636 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Parameter Result Q Dil LOQ DL Units Analysis Date
1,4-Dioxane 3.0 U 1 3.0 1.0 ug/L 03/30/2022 2237
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
100 40-170
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 40 of 46
QC Data for Lot Number: XC24015

Volatile Organic Compounds by GC/MS (SIM) - LCS
Sample ID: XQ36636-002 Matrix: Aqueous
Batch:36636 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
1,4-Dioxane 50 55 1 111 70-130 03/30/2022 2133
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
113 40-170
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 41 of 46
QC Data for Lot Number: XC24015

ICP-MS Metals - MB
Sample ID: XQ36188-001 Matrix: Aqueous
Batch: 36188 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 03/28/2022 0111
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Antimony
2.0
U
1
2.0
0.50
ug/L
03/28/20221901
Arsenic
2.0
U
1
2.0
1.3
ug/L
03/28/20221901
Barium
5.0
U
1
5.0
1.3
ug/L
03/28/20221901
Beryllium
0.40
U
1
0.40
0.15
ug/L
03/28/20221901
Cadmium
0.50
U
1
0.50
0.13
ug/L
03/28/20221901
Chromium
5.0
U
1
5.0
1.3
ug/L
03/28/20221901
Cobalt
5.0
U
1
5.0
1.3
ug/L
03/28/20221901
Copper
5.0
U
1
5.0
1.3
ug/L
03/28/20221901
Lead
1.0
U
1
1.0
0.25
ug/L
03/28/20221901
Nickel
5.0
U
1
5.0
1.3
ug/L
03/28/20221901
Selenium
5.0
U
1
5.0
1.3
ug/L
03/28/20221901
Silver
1.0
U
1
1.0
0.25
ug/L
03/28/20221901
Thallium
0.50
U
1
0.50
0.15
ug/L
03/28/20221901
Vanadium
5.0
U
1
5.0
2.5
ug/L
03/28/20221901
Zinc
10
U
1
10
2.5
ug/L
03/28/20221901
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 42 of 46
QC Data for Lot Number: XC24015

ICP-MS Metals - LCS
Sample ID: XQ36188-002
Matrix: Aqueous
Batch: 36188
Prep Method:
3005A
Analytical Method: 6020B
Prep Date:
03/28/2022 0111
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Antimony
100
97
1
97
80-120
03/28/20221904
Arsenic
100
97
1
97
80-120
03/28/20221904
Barium
100
94
1
94
80-120
03/28/20221904
Beryllium
100
96
1
96
80-120
03/28/20221904
Cadmium
100
96
1
96
80-120
03/28/20221904
Chromium
100
97
1
97
80-120
03/28/20221904
Cobalt
100
96
1
96
80-120
03/28/20221904
Copper
100
99
1
99
80-120
03/28/20221904
Lead
100
95
1
95
80-120
03/28/20221904
Nickel
100
98
1
98
80-120
03/28/20221904
Selenium
100
94
1
94
80-120
03/28/20221904
Silver
100
90
1
90
80-120
03/28/20221904
Thallium
100
93
1
93
80-120
03/28/20221904
Vanadium
100
98
1
98
80-120
03/28/20221904
Zinc
100
96
1
96
80-120
03/28/20221904
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 43 of 46
QC Data for Lot Number: XC24015

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 44 of 46

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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 45 of 46

PACE ANALYTICAL SERVICES, LLC
SamplesKeUipt Chaeklist (,;RC) (mEgoiRC-].S)
aCRAPRl4k l Q20
Issuir, Atrltorlty: pace ENV -4v00L Revised:S/79y
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9_ Was collection rate & tiruy llstad on ali sample g4ntainers?
] 0_ F)irl 9=1 c0rdnina label iilfwmatiwCD, date, tiro) BgH6 with tha C C?
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Fzryes 12, Did r-I I sam p:r� arrive in tltc pi per Cantvincrs for e�clt test arub'ct: in P. Drl C-Onditi(Al
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 46 of 46

aceAnalytical
Report of Analysis
CDM Smith
5400 Glenwood Avenue
Suite 400
Raleigh, NC 27612
Attention: Mathew Colone
Project Name: East Wake Landfill
Lot Number:XC24018
Date Completed:04/26/2022
04/27/2022 10:54 AM
Approved and released by:
Project Manager II: Cathy S. Dover
=w�q a[cArFo f�
AM
TN I
AM Nauvue Acm^r mn BuaN
11 �
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A C C R E D I T E D
TESTINGL aORlTOAY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 11

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
CDM Smith
Lot Number: XC24018
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Dissolved 6020B Metals
The following dissolved metals samples were taken off hold for particular elements per client:
XC24018-003 (MW-04S) for dissolved Cobalt
XC24018-004 (MW-04D) for dissolved Barium and Cobalt
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
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Page 2 of 11

PACE ANALYTICAL SERVICES, LLC
Sample Summary
CDM Smith
Lot Number: XC24018
Project Name: East Wake Landfill
Project Number:
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
MW-01
Aqueous
03/22/2022 0800
03/24/2022
002
MW-03
Aqueous
03/22/2022 0820
03/24/2022
003
MW-04S
Aqueous
03/22/2022 0845
03/24/2022
004
MW-04D
Aqueous
03/22/2022 0835
03/24/2022
(4 samples)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 3 of 11

ICP-MS
Client:CDM Smith Laboratory ID:XC24018-003
Description: MW-04S Matrix: Aqueous
Date Sampled:03/22/2022 0845 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 04/25/2022 1636 BPK 04/22/2022 1104 39045
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Cobalt
7440-48-4 6020B 22 5.0 1.3 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 11

ICP-MS
Client:CDM Smith Laboratory ID:XC24018-004
Description: MW-04D Matrix: Aqueous
Date Sampled:03/22/2022 0835 Project Name: East Wake Landfill
Date Received:03/24/2022 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 04/25/2022 1647 BPK 04/22/2022 1104 39045
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved
Barium
7440-39-3
6020B
800
Dissolved
Cobalt
7440-48-4
6020B
32
5.0 1.3 ug/L 1
5.0 1.3 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 11

QC Summary
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: XC24018
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 11

ICP-MS - MB
Sample ID: XQ39045-001 Matrix: Aqueous
Batch: 39045 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 04/22/2022 1104
Parameter Result Q Dil LOQ DL Units Analysis Date
Dissolved Barium 5.0 U 1 5.0 1.3 ug/L 04/25/2022 1612
Dissolved Cobalt 5.0 U 1 5.0 1.3 ug/L 04/25/2022 1612
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 11
QC Data for Lot Number: XC24018

ICP-MS - LCS
Sample ID: XQ39045-002
Matrix: Aqueous
Batch: 39045
Prep Method: 3005A
Analytical Method: 6020B
Prep Date: 04/22/2022 1104
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil % Rec
Limit Analysis Date
Dissolved Barium
100
91
1 91
80-120 04/25/2022 1615
Dissolved Cobalt
100
98
1 98
80-120 04/25/2022 1615
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 11
QC Data for Lot Number: XC24018

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 11

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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 11

PACE ANALYTICAL SERVICES, LLC
5ampresReceipt CheckllM (SRcI I KA-FAU 1EIC-15 �avlwd,91291a020
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No, 11. We:-g tests w bo perfgrmed listed on inn COC.?
❑ No 12. Did all rar_eples arrive in dl� 13fl-Oper containers far each x9t andAar in good oonditiM
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Ci,Sllnien-s:
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 11